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HomeMy WebLinkAboutBUSINESS PLAN 9/9/2003 '5 Hazardous Materials/Hazardous Waste:?iUnified Permit CONDITIONS .OF .PERMIT'ON REVERSE,SIDE . "' ~. .', -' ~:~ · This permit is iSSued for the folloWing: E~ Hazardous Material. s. Plan · r ~ Underground 'Storage of Hazardous Materials Permit ID #:: 015-000-000354 E] Risk Management Program NEW CITY CLEANERS [] Hazardous Waste On:SiteTreatment LOCATION: 1021 8TH ST -..,. . -:.~ - ' .' ". '.. : .. OFFICE OF ENV1R ONMENTAL SER VICES- ' .~~ 1715 Chester Ave., 3rd Floor Approved by: FIIIE ~ vmce m ~vu~m~nm~ ~erv~ces ,~.~...~ll~ Voice (661) 326-3979 ~',,.,~-,t.,.~,--,.~-FAX (661) 326-0576 Expiration Date: '.lun~ RO) Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE .............. ~,~,,~,:~=:,..~-,:,:.,~:,:~:, ................ This permit is issued for the following: , :-~:.~'~:?:"! ~,~:::~:??':':~':::;!ii :,;:i:~!ili~=, iii~i'~:?':i::?~:~:~D;iU~erground storage of Hazardous Materials ~?,. ",. ": i¢:=!i~iii~ ....... ¢¥" . .............. i! .? ~ '='"::['~ .. -,~i¢iii!~''~i'' :.-:::~ ' $: ......... % '~':;, ,~.~, ?.,.-_~ '.,¢, % '. ,~ . '%. ':..% %*.. ..,,'.~ '~"'~-. ' ~r...'~,..~ ~:3,'~..." '~ ~ ~ E:~ ",-,'"~;,,~¢:;~.. "% "":':::%.; :;~8~ ,~i¢' i~";?,.LE; ;"~"["?'::::~;,.~,.?:~ :41~ ii~<="~¢" '~;.....- "..'% :""~.4 ' .~ ~"~'.i' '.;' ';~ ~,,,~;~" ~i&'~2,~ ..... _,.¢'"~' ' '~E;~.- "..." .. '" :'"':'~,=,:,=~....::::2,,....~,:.;:~.,..,~,.¢~' ':" ~' z' i i .C~¢~ .... B~ersfield Fke D~ment Approv~ by: O~CE OF f~R ON~AL S~ ~CES 1715 Chewer Ave., 3rd Floor ~ O~ce ~ ~ml S~i~ B~e~el~ CA 93301 Voice (805) 32~3979 F~ (80S)~26-0S76 Expiration Date: CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3rd Floor, Bakersfield, CA 93301 ADDRESS /6Z] ~ · PHONE NO. ~7.~-/~6//¥ FACILITY CONTACT L~' JdtO~f BUSINESS ID NO. 15-210- ~5 INSPECTION TIME /,~ NUMBER OF EMPLOYEES Section 1: Business Plan and Inventory Program ~Routine [~ Combined [~ Joint Agency [~ Multi-Agency ~ Complaint [~ Re-inspection OPERATION C V COMMENTS Appropriate permit on hand ~" ~'~ Business plan contact information accurate Visible address /' Correct occupancy v/ Verification of inventory materials qr Verification of quantities 4 Verification of location 7 ~4.~k~i.~/~ ~ Proper segregation of material d "~ Verification of MSDS availability ~ Verification of Haz Mat training , Verification of abatement supplies and procedures Emergency procedures adequate Containers properly labeled / Housekeeping / Fire Protection / ~'~ Site Diagram Adequate & On Hand / Ques~g this inspection? Please callus at (~61) ~ I~us'mess :t~e Responsible pan~ White - Env.~qrSvc~...__. Yellow- Station Copy ~Fnk- Business Copy Inspector: C~. CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., ya Floor, Bakersfield, CA 93301 FACILITY NAME Pd~l~o/ C4 ~ ~//,,eTr~.~ INSPECTION DATE Al)DRESS {OZ..{ ~_.~4 ~ PHONE NO. ~7-~/"-~'t// FACILITY CONTACT ~"~,g00~- C'"~p BUSINESS ID NO. 15-210- a9 ~5-¥ INSPECTION TIME ~70 t~H~a~ NUMBER OF EMPLOYEES Section 1: Business Plan and Inventory Program ~/Routine 1~ Combined [21 Joint Agency t~ Multi-Agency ~ Complaint [2] Re-inspection OPERATION C V COMMENTS Appropriate permit on hand d Business plan contact information accurate Visible address V/ Correct occupancy Verification of inventory materials Verification of quantities Verification of location / Proper segregation of material v/ Verification of MSDS availability Verification of Haz Mat training Verification of abatement supplies and procedures Emergency procedures adequate / Containers properly labeled qr Housekeeping Fire Protection Site Diagram Adequate & On Hand C=Compliance V=Violation Any hazardous waste on site?: ~Yes [~ No Questions regarding this inspection. Please cull us at (66 I) 326-3979 usi~less Site Responsible Party White- Env. Svcs. Yellow - Station Copy Pink- Business Copy Inspecto~/~' .~ NEW CITY CLEANERS '-~ ~ SiteID: 015-021-000354 BusPhone: 324-9414 Manager : ~P~ 6~000Grid: 3lA FacUnits: 1 AOV: Location: 1021 8TH ST Map : 103 CommHaz : Moderate City : BAKERSFIELD ~Vl~ Ogf'~RV]C~S SIC Code: CommCode: BJ~ERSFIELD. STATION 06 EPA Numb: DunnBrad: Emergency Contact /. Title Emergency Contact / Title JARRELL L. EPP ~&~/~ 0¢.~.~ IIENRY F. BRANDT '~,~r~ Business Phone: (80~) 324-9414x Business Pho~~8~ 324-9414x 24-Hour Phone : (805) 329 371Dx 24-Hour Phone : (005) 871-3076x ;~1 Phone : (~61)~O3 -~,~x %a~cr~ll Phone : (~/) 7~6 -3~x Hazmat Hazards: Fire Contact : Phone: ( ) - x MailAddr: 1021 8TH ST State: City : B~ERSFIELD Zip : 93304 O~er J~RELL L. EPP Phone: : .9500 V~LEY ~( CT /~ --~f~l ~.~ ~gf. State: CA Address City : B~ERSFIELD Zip : ~3311 Period : to -TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: No Emergency Directives: ~ Hazmat Inventory One Unified List ~ ~--- As Designated Order Ail Materials at Site ~ Hazmat Common Name... ISpecHazlEPA Hazardsl. Frm DailyMax IUnitlMcP CHEVRON THINNER 325 F L 500.00 GAL Mod C~NFIDE~CE ~iC- % L ,500.00 ~AL Iii ], C_J"--~,.,.,/f ~t~ Do hereby certify that ! have (Type or print name) reviewed the attached hazardous materials manage- ment ptan 1or/~¢~d ~'~ C/~'~a,,~.nd that it .along with (Name of/ausine~s) any corrections constitute a complete and correct man- agement plan for my facility. -1- 08/18/2000 i NEW CITY CLEANERS ~~/5~~/5~~5~ SiteID: 015-021-000354 i~ Invento~ Item 0001 ~~~ Facility Unit: Fixed Containers on Site i~ COMMON NAME / CHEMICAL NAME o CHEVRON THINNER 325 o Days On Site o o o 365 o . .o Location within ~is Facility U~t Map: Grid: o ABOVE GROUND TANK o CASff o o o 64742-47-8 o i~ STATE Ei~ TYPE ~i~ P~SSURE ~i TEMPE~T~ ~i~ CONTAINER TYPE o Liquid o Mixture o Ambient o Ambient o ABOVE GROUND TANK o i~~~~i AMOUNTS AT THIS LOCATION o Largest Container o Daily Maximin o Daily Average o o GAL o 500.00 GAL o 500.00 GAL i~i~~ ~ZA~OUS COMPONENTS o %Wt. o oRSo CAS~ o o 99.00Opetroleum Naph~a ONo o 8030306° o 1.00° 1,3,5-Tr~e~ylbemene ONo o 108678° i~i~i~i~~ ~ZA~ ASSESSMENTS ~i~~i~~ °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT~ o MCP o o No ONoONo o No/ Curies°F o /// o OModO 0002 ~~~ Facility Unit: Fixed Comainers' on i~ CC / CHEMICAL NAME CC ~IC o Days On S o 365 Location within acility Unit Map: Grid: BOILER ROOM o o O f~ STATE ~i~ TYPE ~i~ ~i ~i~ CONTAINER TYPE Liquid o Mixture o Ambient o DRUM/BARREL-NONMETAL o i~~~~i THIS LOCATION Largest Comainer o o Daily Average o GAL o GAL 400.00 GAL o i~6~i'~-66~.~ HAl ~US C£ ~~i~i~~~i %Wt. o o RSo o 8.00OPotassium ONo 1310583° 4.00oSodium ,xide °No ° t0732° 3. ONo o ~78o HAZARD ASSESSMENTS oTSecret' ',°BioHaz° Radioactive/Amount o EPA Hazards ° NFPA o o MCP ° No ONo o No/ Curies° o /// o OHio -2- 08/18/2000 NEW CITY CLEANERS i8 Notif./Evacuation/Medical i88 Agency Notification O CALL 911 O i88~ Employee Notif./Evacuation O NEW CITY CLEANERS EVACUATION PROCEDURE CONSISTS OF ONE PERSON OF THE FIVE o PEOPLE IN PRIVATE RESPONSE TEAM VERBALLY TELLING EACH EMPLOYEE TO EVACUATE o THE BUILDING AT THE NEAREST EXIT AND TO HEAD EAST ON 8TH STREET AS QUICKLY o AS POSSIBLE. ALSO DURING THIS TIME A SECOND PERSON ON THE RESPONSE TEAM o WOULD BE CALLING 911 AND EXPLAINING oUR EMERGENCY. o O f8888 Public Notif./Evacuation 888888888888888888888888888888888888 06/03/1997 o IN CASE OF EMERGENCY NEW CITY CLEANERS HAS A CHAIN OF COMMAND OF FIVE o PEOPLE WHO KNOW OUR OPERATION WELL. EACH ONE KNOWS THEIR RESPONSIBILITY o IF AN EMERGENCY DOES ARISE. ONE PERSON EVACUATES THE BUILDING INCLUDING o EMPLOYEES AND CUSTOMERS WHILE ANOTHER CALLS 911. I HAVE TWO BACKUPS FOR o EACH PERSON. THIS COORDINATION BETWEEN OUR STAFF SHOULD LEAD TO PROPER o NOTIFICATION AND EVACUATION OF OUR BUILDING. o o i88888 Emergency Medical Plan 8888888888888888888888888888888888888 01/07/1990 O IN CASE THE MEDICAL EMERGENCY IS MINOR WE HAVE A FIRST AID KIT IN OUR REST o AREA. IF THE INJURY IS MORE SERIOUS WE WOULD CALL HALL AMBULANCE OR GOLDEN o EMPIRE AMBULANCE. THESE TWO NUMBERS ARE POSTED BY OUR PHONES. o -3- 08/18/2000 i NEW CITY CLEANERS 8888888888888~88888888E~EE~OEEEEEE SiteID: 015-021-000354 i8 Mitigation/Prevent/Abatemt 8~8~88~8~88~8~ Overall Site i~ Release Prevention ~8~8~8~8~8~8~88~8~ 11/20/1995 o O ° OUR PREVENTION PROCEDURES CONSIST OF GOOD HOUSEKEEPING & PREVENTIVE ° o MAINTENANCE ON OUR MACHINES & EQUIPMENT. OUR CHEMICALS ARE KEPT IN AN o o ORDERLY MANNER WITH THEIR LIDS ALWAYS ON. THE MACHINES ARE KEPT UP DAILY o o AND OUR VALVES TO OUR TANKS ARE CLOSED UNLESS IN OPERATION. WE HAVE A NO o o SMOKING POLICY. IN ADDITION NEW CITY CLEANERS HAS 12 INCH MASONARY WALLS o ° AROUND THE CLEANING ROOM AND TUMBLER ROOM. THESE TWO ROOMS ALSO HAVE DOORS o o THAT AUTOMATICALLY CLOSE IN CASE OF FIRE. o O O i8~ Release Containment ~8~8~8~8~8~8~8~8~88~8~ 11/20/1995 i O O o OUR RELEASE CONTAINMENT PREVENTIVE MEASURES INCLUDE CLOSED VALVES AND DOORS ° o TO DRY CLEANING MACHINES AND ABOVEGROUND STORAGE TANK WHEN NOT IN USE, o o CEMENT BARRIERS TO HOLD ANY SOLVENT IN DRY CLEANING ROOM SO IT CAN BE ° o QUICKLY CLEANED UP, AND 12" MASONARY WALLS, CEILING AND FLOOR IN OUR o o DRYCLEANING ROOM. BOTH DOORS TO THIS ROOM HAVE SENSORS WHICH WILL CLOSE THE o o DOORS AUTOMATICALLY IN CASE OF FIRE. o O o i~88~ Clean Up ~8~EEE/~E~8~8~EE~86~8~8~/~888~SEE~ES~ 11/20/1995 O O o NEW CITY CLEANERS CLEAN UP PROCEDURE IN CASE OF A SPILL IS TO GET TOWELS AND o o OLD DRAPERY LININGS AND MOP UP THE SOLVENT WITH THEM. THESE TOWELS AND o o LININGS ARE THEN THOROUGHLY EXTRACTED IN OUR DRYCLEANING MACHINES TO SAVE o o THE SOLVENT. THIS PROCESS IS REPEATED UNTIL THE SPILL AREA IS COMPLETELY o O o f8~88/~ Other Resource Activation o 0 0 0 -4- 08/18/2000 i NEW CITY CLEANERS ~gg~~/~~~gg SitelD: 015-021-000354 i i~ Site Emergency Factors ~~~~~~ Overall Site i i~ Special Hazards.~/~/~/~/~~~~~~~i O O O O iE~ Utility Shut-Offs E~EE~EEEEEEEEEEEEEEEEEEEEEEEEEE/~EE~EEEEEE~ 06/26/1992 i O O o A) GAS - OUTSIDE BUILDING BETWEEN CUSTOMER/EMPLOYEE PARKING o o B) ELECTRICAL - BOILER ROOM o o C) WATER - NORTHWWEST CORNER OF PROPERTY ON 8TH STREET o o D) SPECIAL - NONE o o E) LOCK BOX - NO o O o i~ Fire Protec./Avail. Water ~~~~~ 06/26/1992 i O O o PRIVATE FIRE PROTECTION - OUR FIRE PROTECTION CONSISTS OF FIRE DOORS ON OUR o o CLEANING ROOM, DRYING ROOM, AND BOILER ROOM. THESE DOORS ARE ACTIVATED o o BY THERMAL BREAKERS WHICH BREAK IN CASE OF FIRE. NEW CITY CLEANERS ALSO o o HAS FIRE EXTINGUISHERS AT OUR CLEANING ROOM DOOR, DRYING ROOM DOOR AND IN o THE MIDDLE OF OUR PLANT. : o O O O O ° FIRE HYDRANT - SOUTHWEST CORNER OF 8TH ST AND N ST. o O o i~ Building Occupancy Level o O O O -5- 08/18/2000 NEW CITY CLEANERS ~/5~6~i~5/~i~66/~5~66~6~6~ SiteID: 015-021-000354 i i~ Trai~ng ~~~~~~~~ Overall Site i i~ Employee Trai~ng ~~~~~~~ 06/03/1997 i O WE ~VE 20 EMPLOYEES AT T~S FACILITY o O WE ~VE ~TE~AL SAFETY DATA SHEETS ON FILE. B~EF SUM~RY OF T~INING PROG~M: ~ZA~OUS MATE~AL T~NING MEETINGS A~ o DONE ONCE A YEAR ~TH OUR EMPLOYEES. NEW EMPLOYEES A~ GIVEN T~INING DU~NG THEIR FIRST WEEK OF EMPLOYMENT. THE T~NING CONSISTS OF ~ING THROUGH OUR EMPLOYEE BINDER WHICH INCLUDES ~TE~AL SAFETY DATA SHEETS, o EVACUATION PROCEDU~S, AND EMERGENCY PROCEDU~S. THE BINDER IS LEFT IN OUR o EMPLOYEE B~AK ROOM FOR THEM TO STUDY. o O O O i~ Held for Fumre Use o O i~ Held for Fumre Use O O -6- 08/18/2000 I'E~.ti~.!.Du~'an";' Fi'~Z'Mat !nsp%ti0r~s ................................................... P~.~' 1.,l From: Greg Moore To: Esther Duran Date: Thu, Aug 31, 2000 6:32 PM Subject: Haz Mat Inspections Hey girl what's happenin'? How come you don't ever stay in touch? What's up with you girl? How are you and Derrick doing anyway? Hey, I did some HM inspections and made some changes. They couldn't all be put on the inspection triplicate form so I thought I would just send them to you via email and let you make them in your office. ~,,~. ~ ~_____.~¥1'~e changes will be for:-'"---~ ~ 1- New City Cleaners 1021.~.~h Street. Remove Henry Brandts information and add Larry Morris as the ~-----=~_ second em~.rgoncy ~;on[act. Home phone is 872-2036 Cell is 706-3455. Change Mr Jarrell E. Epps info to: home- 12308 April Ann Ave 93312 home- 589-9101 Cell- 203-4407. 2~~- BS&E 1220 Brundage Ln. Waste oil at the facility has been moved to another location. Eastside ~)I~/''' behind_shop. Can I continue to send you information of this nature for Haz Mat inspections, this way? Thanks GM. = NE~ CITY CLEANERS k.~ ~'~~%! SiteID: 215-000-000354 Manager : ,i JUN 2.1997 J/Il BusPhone: (805) 324-9414 Location: 1021 8TH ST ' ~I Map : 103 CommHaz : Moderate City : BAKERSFIELD "By.. ....... Grid: 3lA FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 06 SIC Code: EPA Numb: DunnBrad: Emergency Contact / Title Emergency Contact / Title JARRELL L. EPP / HENRY F. BRANDT / Business Phone: (805) 324-9414x Business Phone: (805) 324-9414x 24-Hour Phone : (805) 329-3713x 24-Hour Phone : (805) 871-3076x Pager Phone : ( ) - x Pager Phone : ( ) - x Hazmat Hazards: Fire Agency-Defined Topic Title ~ Hazmat Inventory One Unified List MCP+DailyMax Order Ail Materials at Site Hazmat Common Name... ISpooHazlEPA HazardsI Frm DailyMax lUnitlMCP CONFIDENCE 41C L 500 GAL Hi CHEVRON THINNER 325 F L 500 GAL Mod reviewe¢ the attached hazardous rnateri~s mer,t ~.~ian for ~ ~ ~~d that ~t ~ong ~ith (N~ of any corre~ions ~nstitut~ a complst~ agement pla~ ~r ~y -1- NEW CITY CLEANERS SiteID: 215-000-000354 ~ Inventory Item 0002 Facility Unit: Fixed Containers on Site COMMON NAME / CHEMICAL NAME CONFIDENCE 41C Days On Site 365 Location within this Facility Unit BOILER ROOM CAS# STATE TYPE PRESSURE --~ TEMPERATURE CONTAINER TYPE Liquid Mixture I Ambient Ambient [DRUM/BARREL-NONMETAL AMOUNTS STORED AND IN USE Lrgst Cont.this Loc GAL DailyMax this Loc GAL DailyAvg this Loc GAL 500.00 400.00 DailyMax Stored GAL DailyMax Open Use GAL DailyMax Closed Use GAL HAZARDOUS COMPONENTS %Wt. EHS CAS# 8.00 Potassium Hydroxide No 1310583 4.00 Sodium Hydroxide No 1310732 3.00 Diethylaminoethanol No 100378 F NEW CITY CLEANERS SiteID: 215-000-000354 ~ Inventory Item 0001 Facility Unit: Fixed Containers on Site --COMMON NAME / CHEMICAL NAME CHEVRON THINNER 325 Days On Site 365 Location within this Facility Unit ABOVE GROUND TANK CAS# 64742-47-8 FSTATE~TYPEI PRESSURE I TEMPERATURE I CONTAINERTYPETANK Liquid Mixture Ambient Ambient ABOVE GROUND AMOUNTS STORED AND IN USE Lrgst Cont.this Loc GAL DailyMax this Loc GAL DailyAvg this Loc GAL 500.00 500.00 DailyMax Stored GAL DailyMax Open Use GAL DailyMax Closed Use GAL HAZARDOUS COMPONENTS %Wt. EH$ CAS# 99.00 Petroleum Naphtha No 8030306 1.00 1,3,5-Trimethylbenzene No 108678 -3- NEW CITY CLEANERS SiteID: 215-000-000354 Fast Format ~ Notif./Evacuation/Medical Overall Site Agency Notification 01/07/1990 CALL 911 Employee Notif./Evacuation 01/07/1990 NEW CITY CLEANERS EVACUATION PROCEDURE CONSISTS OF ONE PERSON OF THE FIVE PEOPLE IN PRIVATE RESPONSE TEAM VERBALLY TELLING EACH EMPLOYEE TO EVACUATE THE BUILDING AT THE NEAREST EXIT AND TO HEAD EAST ON 8TH STREET AS QUICKLY AS POSSIBLE. ALSO DURING THIS TIME A SECOND PERSON ON THE RESPONSE TEAM WOULB BE CALLING 911 AND EXPLAINING OUT EMERGENCY. Public Notif./Evacuation 01/07/1990 IN CASE OF EMERGENCY nEW cITY cLEANERS HAS A CHAIN OF COMMAND OF FIVE PEOPLE WHO KNOW OUR OPERATION WELL. EACH ONE KNOWS THEIR RESPONSIBILITY IF AN EMERGENCY DOES ARISE. ONE PERSON EVACUATES THE BUILDING INCLUDING EMPLOYEES AND CUSTOMERS WHILE ANOTHER CALLS 911. I HAVE TWO BACKUPS FOR EACH PERSON. THIS COORDINATION BETWEEN OUR STAFF SHOULD LEAD TO PROPER NOTIFICATION AND EVACUATION OF OUR BUILDING. Emergency Medical Plan 01/07/1990 IN CASE THE MEDICAL EMERGENCY IS MINOR WE HAVE A FIRST AID KIT IN OUR REST AREA. IF THE INJURY IS MORE SERIOUS WE WOULD CALL HALL AMBULANCE OR GOLDEN EMPIRE AMBULANCE. THESE TWO NUMBERS ARE POSTED BY OUR PHONES. -4- NEW CITY CLEANERS SiteID: 215-000-000354 Fast Format F Mitigation/Prevent/Abatemt Overall Site Release Prevention 11/20/1995 OUR PREVENTION PROCEDURES CONSIST OF GOOD HOUSEKEEPING & PREVENTIVE MAINTENANCE ON OUR MACHINES & EQUIPMENT. OUR CHEMICALS ARE KEPT IN AN ORDERLY MANNER WITH THEIR LIDS ALWAYS ON. THE MACHINES ARE KEPT UP DAILY AND OUR VALVES TO OUR TANKS ARE CLOSED UNLESS IN OPERATION. WE HAVE A NO SMOKING POLICY. IN ADDITION NEW CITY CLEANERS HAS 12 INCH MASONARY WALLS AROUND THE CLEANING ROOM AND TUMBLER ROOM. THESE TWO ROOMS ALSO HAVE DOORS THAT AUTOMATICALLY CLOSE IN CASE OF FIRE. Release Containment 11/20/1995 OUR RELEASE CONTAINMENT PREVENTIVE MEASURES INCLUDE CLOSED VALVES AND DOORS TO DRY CLEANING MACHINES AND ABOVEGROUND STORAGE TANK WHEN NOT IN USE, CEMENT BARRIERS TO HOLD ANY SOLVENT IN DRY CLEANING ROOM SO IT CAN BE QUICKLY CLEANED UP, AND 12" MASONARY WALLS, CEILING AND FLOOR IN OUR DRYCLEANING ROOM. BOTH DOORS TO THIS ROOM HAVE SENSORS WHICH WILL CLOSE THE DOORS AUTOMATICALLY IN CASE OF FIRE. Clean Up 11/20/1995 NEW CITY CLEANERS CLEAN UP PROCEDURE IN CASE OF A SPILL IS TO GET TOWELS AND OLD DRAPERY LININGS AND MOP UP THE SOLVENT WITH THEM. THESE TOWELS AND LININGS ARE THEN THOROUGHLY EXTRACTED IN OUR DRYCLEANING MACHINES TO SAVE THE SOLVENT. THIS PROCESS IS REPEATED UNTIL THE SPILL AREA IS COMPLETELY Other Resource Activation -5- NEW CITY CLEANERS SiteID: 215-000-000354 Fast Format F Site Emergency Factors Overall Site Special Hazards Utility Shut-Offs 06/26/1992 A) GAS - OUTSIDE BUILDING BETWEEN CUSTOMER/EMPLOYEE PARKING B) ELECTRICAL - BOILER ROOM C) WATER - NORTHWWEST CORNER OF PROPERTY ON 8TH STREET D) SPECIAL - NONE E) LOCK BOX - NO Fire Protec./Avail. Water 06/26/1992 PRIVATE FIRE PROTECTION - OUR FIRE PROTECTION CONSISTS OF FIRE DOORS ON OUR CLEANING ROOM, DRYING ROOM, AND BOILER ROOM. THESE DOORS ARE ACTIVATED BY THERMAL BREAKERS WHICH BREAK IN CASE OF FIRE. NEW CITY CLEANERS ALSO HAS FIRE EXTINGUISHERS AT OUR CLEANING ROOM DOOR, DRYING ROOM DOOR AND IN THE MIDDLE OF OUR PLANT. FIRE HYDRANT - SOUTHWEST CORNER OF 8TH ST AND N ST. Building Occupancy Level -6- NEW CITY CLEANERS SiteID: 215-000-000354 Fast Format ~.,Training Overall Site Employee Training 12/20/1990 WE HAVE 20 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE. HAZARDOUS MATERIAL TRAINING MEETINGS ARE DONE ONCE A YEAR WITH OUR EMPLOYEES. NEW EMPLOYEES ARE GIVEN TRAINING DURING THEIR FIRST WEEK OF EMPLOYMENT. THE TRAINING CONSSISTS OF GOING THROUGH OUR EMPLOYEE BINDER WHICH INCLUDES MATERIAL SAFETY DATA SHEETS, EVACUATION PROCEDURES, AND EMERGENCY PROCEDURES. THE BINDER IS LEFT IN OUR EMPLOYEE BREAK ROOM FOR THEM TO STUDY. Page 2 Held for Future Use Held for Future Use -7- NEW CITY CLEANERS 215-000-000354 Page 1 Overali Site with 1 Fac. Unit General Information Location: 1021 8TH ST Map:103 Haz:3 Type: 3 City : BAKERSFIELD Grid: 31A F/U: i AOV: 0.0 Contact Name Title -- Contact Name T~tle JARRELL L. EPP / HENRY F. BRANDT / Business Phone: (805) 324-9414x Business Phone: (805) 324-9414x 24-Hour Phone .' (805) 329-3713x 24-Hour Phone : (805) 871-3076x Pager Phone : ( ) - x Pager Phone : ( ) - x Administrative Data Mail Addrs: 1021 8TH ST D&B Number: City: BAKERSFIELD State: CA Zip: 93304- Comm Code: 215-006 BAKERSFIELD STATION 06 SIC Code: Owner: JARRELL L. EPP Phone: (805) 664-9101 Address: 9500 VALLEY OAK CT State: CA City: BAKERSFIELD Zip: 93311- Summary ,, ~-~ r,,/I L. 6'.~ Do hereby certify that I have reviewed the a~ached hazardous materials manage- ment plan for ~w6/¢vC.i,o,~,,~and that it along with (Nm~e any oo~ec~ons OOn~e a ~ompl~e a~d oo~e~ agemem plan ~r ~ ~. 8/14/95~ NEW CITY CLEANERS 215-000-000354 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site 'ln-Ref Name/Hazards Form Max Qty MCP 02-002 CONFIDENCE 41C Liquid · GAL 02-001 CHEVRON THINNER 325 Liquid 500 Moderate · Fire GAL )8/t4/95~ NEW CITY CLEANERS 215-000-000354 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-002 CONFIDENCE 41C Liquid ~'~ High · GAL CAS #: Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING Daily Max GAL Daily Average GAL Annual Amount GAL -- 500 I 400.00 [ 500.00 Storage ! Press T Temp Location DRUM/BARREL-NONMETAL IAmbient[Ambient[BOILER ROOM -- Conc Components MCP Guide 8.0% Potassium Hydroxide Moderate 60 4.0% Sodium Hydroxide Moderate 60 3.0% Diethylaminoethanol High 29 02-001 CHEVRON THINNER 325 Liquid 500 Moderate · Fire GAL CAS #: 64742-47-8 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING -- Daily Max GAL Daily Average GAL Annual Amount GAL 500 [ 500.00 [ 4,800.00 Storage I Press T TempI Location ABOVE GROUND TANK [Ambtent[Ambtent~ABOVE GROUND TANK -- Conc Components MCP ~uide 99.0% Petroleum Naphtha Moderate 27 1.0% 1,3,5-Trimethylbenzene Moderate 26 8/r4/95' NEW CITY CLEANERS 215-000-000354 Page 4 00 - Overall Site <D> Notif./Evacuation/Medical 1> Agency Notification CALL 911 2> Employee Notif./Evacuation NEW CITY CLEANERS EVACUATION PROCEDURE CONSISTS OF ONE PERSON OF THE FIVE PEOPLE IN PRIVATE RESPONSE TEAM VERBALLY TELLING EACH EMPLOYEE TO EVACUATE THE BUILDING AT THE NEAREST EXIT AND TO HEAD EAST ON 8TH STREET AS QUICKLY AS POSSIBLE. ALSO DURING THIS TIME A SECOND PERSON ON THE RESPONSE TEAM WOUL~ BE CALLING 911 AND EXPLAINING OUT EMERGENCY. 3> Public Notif./Evacuation IN CASE OF EMERGENCY ~EW dITY ~LEANERS HAS A CHAIN OF COMMAND OF FIVE PEOPLE WHO KNOW OUR OPERATION WELL. EACH ONE KNOWS THEIR RESPONSIBILITY IF AN EMERGENCY DOES ARISE. ONE PERSON EVACUATES THE BUILDING INCLUDING EMPLOYEES AND CUSTOMERS WHILE ANOTHER CALLS 911. I HAVE TWO BACKUPS FOR EACH PERSON. THIS COORDINATION BETWEEN OUR STAFF SHOULD LEAD TO PROPER NOTIFICATION AND EVACUATION OF OUR BUILDING. 4> Emergency Medical Plan IN CASE THE MEDICAL EMERGENCY IS MINOR WE HAVE A FIRST AID KIT IN OUR REST AREA. IF THE INJURY IS MORE SERIOUS WE WOULD CALL HALL AMBULANCE OR GOLDEN EMPIRE AMBULANCE. THESE TWO NUMBERS ARE POSTED BY OUR PHONES, ,8/14/95' NEW CITY CLEANERS 215-000-000354 Page 5 00 - Overall Site <E> Mitigation/Prevent/Abatemt ~1> Release Prevention OUR PREVENTION PROCEDURES CONSIST OF GOOD HOUSEKEEPING & PREVENTIVE MAINTENANCE ON OUR MACHINES & EQUIPMENT. OUR CHEMICALS ARE KEPT IN AN ORDERLY MANNER WITH THEIR LIDS ALWAYS ON. THE MACHINES ARE KEPT UP DAILY AND OUR VALVES'TO OUR TANKS ARE CLOSED UNLESS IN OPERATION. WE HAVE A NO SMOKING POLICY, EX~EPT IN ~I~ LUNCII ROOM ~IICII It ACROCS ~I~ PLANT FROM OUR ~li~M~C2%'~. IN ADDITION NEW CITY CLEANERS HAS 12 INCH MASONARY WALLS AROUND THE CLEANING ROOM AND TUMBLER ROOM. THESE TWO ROOMS ALSO HAVE DOORS THAT AUTOMATICALLY CLOSE IN CASE OF FIRE. 2>.Release Containment OUR RELEASE CONTAINMENT PREVENTIVE MEASURES INCLUDE CLOSED VALVES AND DOORS TO DRY CLEANING MACHINES AND ABOVEGROUND STORAGE TANK WHEN NOT IN USE, CEMENT BARRIERS TO HOLD ANY SOLVENT IN DRY CLEANING ROOM SO IT CAN BE QUICKLY CLEANED UP, AND 12" MASONARY WALLS, CEILING AND FLOOR IN OUR DRYCLEANING ROOM. BOTH DOORS TO THIS ROOM HAVE SENSORS WHICH WILL CLOSE THE DOORS AUTOMATICALLY IN CASE OF FIRE. 3> Clean Up NEW CITY CLEANERS CLEAN UP PROCEDURE IN CASE OF A SPILL IS TO GET TOWELS AND OLD DRAPERY LININGS AND MOP UP THE SOLVENT WITH THEM. THESE TOWELS AND LININGS ARE THEN THOROUGHLY EXTRACTED IN OUR DRYCLEANING MACHINES TO SAVE THE SOLVENT. THIS PROCESS IS REPEATED UNTIL THE SPILL AREA IS COMPLETELY DRY. Other Resource Activation }8/14/95, NEW CITY CLEANERS 215-000-000354 Page 6 00 - Overall Site <F> Site Emergency Factors Special Hazards 2> Utility Shut-Offs A) GAS - OUTSIDE BUILDING BETWEEN CUSTOMER/EMPLOYEE PARKING B) ELECTRICAL - BOILER ROOM C) WATER - NORTHWWEST CORNER OF PROPERTY ON 8TH STREET D) SPECIAL - NONE E) LOCK BOX - NO 3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - OUR FIRE PROTECTION CONSISTS OF FIRE DOORS ON OUR CLEANING ROOM, DRYING ROOM, AND BOILER ROOM. THESE DOORS ARE ACTIVATED BY THERMAL BREAKERS WHICH BREAK IN CASE OF FIRE. NEW CITY CLEANERS ALSO HAS FIRE EXTINGUISHERS AT OUR CLEANING ROOM DOOR, DRYING ROOM DOOR AND IN THE MIDDLE OF OUR PLANT. FIRE HYDRANT - SOUTHWEST CORNER OF 8TH ST AND N ST. ~> Building Occupancy Level 8/1~4/g5~ NEW CITY CLEANERS 215-000-000354 Page 7 00 - Overall Site <G> Training 1> Employee Training WE HAVE 20 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE. HAZARDOUS MATERIAL TRAINING MEETINGS ARE DONE ONCE A YEAR WITH OUR EMPLOYEES. NEW EMPLOYEES ARE GIVEN TRAINING DURING THEIR FIRST WEEK OF EMPLOYMENT. THE TRAINING CONSSISTS OF GOING THROUGH OUR EMPLOYEE BINDER WHICH INCLUDES MATERIAL SAFETY DATA SHEETS, EVACUATION PROCEDURES, AND EMERGENCY PROCEDURES. THE BINDER IS LEFT IN OUR EMPLOYEE BREAK ROOM FOR THEM TO STUDY. 2> Page 2 Held for Future Use Held for Future Use 04/14/92 NEW CITY CLEANERS 215-000-000354 ~EC£1VED Page Overall Site with 1 Fac. Unit General Information' ~UN 0 I ~"~ Location: 1021 8TH ST Map: 103. Hazard: Moderate Community: BAKERSFIELD STATION 06 Grid: 3lA F/U: 1AOV: 0.0 ~ Contact Name Title .Business Phone ~ 24-Hour Phone- JARRELL L. EPP (805) 324-9414 x (805) 396-9080 HENRY F. BRANDT (805) 324-9414 x (805) 871-3076 Administrative Data Mail Addrs: 1021 8TH ST D&B Number: City: BAKERSFIELD State: CA Zip: 93304- · Comm Code: 215-006.BAKERSFIELD STATION 06 SIC Code: Owner: JARRELL L. EPP · Phone: (~O3~&6~-~/O~ Address· 5100 MI~C #A 12 $~o0 ~[;~y O~ C~. State: CA City: BAKERSFIELD ' Z/p: 9330{ 9~/; Summary for ~ C,~/0~, and ~ha~ J~ along ~rr~lon~ ~ns~u~ ~ comp~e and correct man- 04/14/92 NEW CITY CLEANERS 215-000-000354 " " Page 2 ~ 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-001 CHEVRON THINNER 325 Liquid 500 Moderate ~ Fire GAL CAS #: 64742-47-8 Trade Secret: No Form: Liquid Type: Mixture. Days: 365 uSe: CLEANING Daily Max GAL Daily Average GAL Annual Amount GAL -- 500 I 500.00 I 4,800.00 Storage I~Press T Temp Location ABOVE GROUND TANK I Ambient~AmbientlABOVE GROUND TANK --.Conc Components MCP List /0o~98.0-%' Petroleum Naphtha Moderate ,~ %~--t-_onc ~,, ~_~-~,3D~- Moderate 02-002 CONFIDENCE 410 Liquid 500 High GAL CAS #: Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING Daily Max GAL Daily Average GAL Annual Amount GAL 500 .I 400.00 I 500.00 Storage Press T Temp Location DRUM/BARREL-NONMETAL Ambient/AmbientlBOILER ROOM -- Conc Components MCP List 8.0% Potassium Hydroxide Moderate 4.0% Sodium'Hydroxide Moderate 3.0% Diethylaminoethanol High 04/14/92 NEW CITY CLEANERS 215-000-000354 Page 3 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation NEW CITY CLEANERS EVACUATION PROCEDURE CONSISTS OF ONE PERSON OF THE FIVE PEOPLE IN PRIVATE RESPONSE TEAM VERBALLY TELLING EACH EMPLOYEE TO EVACUATE THE BUILDING AT THE NEAREST EXIT AND TO HEAD EAST ON 8TH STREET AS QUICKLY AS POSSIBLE. ALSO DURING THIS TIME A SECOND PERSON ON THE RESPONSE TEAM , WOULB BE CALLING 911 AND EXPLAINING OUT EMERGENCY. <3> Public Notif./Evacuation IN CASE OF EMERGENCY nEW cITY cLEANERS HAS A CHAIN OF COMMAND OF FIVE PEOPLE WHO KNOW OUR OPERATION WELL. EACH ONE KNOWS THEIR RESPONSIBILITY IF AN EMERGENCY DOES ARISE. ONE PERSON EVACUATES THE BUILDING INCLUDING EMPLOYEES AND CUSTOMERS WHILE ANOTHER CALLS 911. I HAVE TWO,BACKUPS FOR EACH PERSON. THIS COORDINATION BETWEEN OUR STAFF SHOULD LEAD TO PROPER NOTIFICATION AND EVACUATION OF OUR BUILDING. <4> Emergency Medical Plan IN CASE THE MEDICAL EMERGENCY IS MINOR WE HAVE A FIRST AID KIT IN OUR REST AREA. IF THE INJURY IS MORE SERIOUS WE WOULD CALL H%LL AMBULANCE OR GOLDEN EMPIRE AMBULANCE. THESE TWO NUMBERS ARE POSTED BY OUR PHONES. 04/14/92 NEW CITY CLEANERS 215-000-000354 Page 4 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention OUR PREVENTION PROCEDURES CONSIST OF GOOD HOUSEKEEPING & PREVENTIVE MAINTENANCE ON OUR MACHINES & EQUIPMENT. OUR CHEMICALS ARE KEPT IN AN ORDERLY MANNER WITH THEIR LIDS ALWAYS ON. THE MACHINES ARE KEPT UP DAILY AND OUR VALVES TO OUR TANKS ARE CLOSED UNLESS IN OPERATION. WE HAVE A NO SMOKING POLICY EXCEPT IN THE LUNCH ROOM WHICH IS ACROSS THE PLANT FROM OUR CHEMICALS. IN ADDITION NEW CITY CLEANERS HAS 12 INCH MASONARY WALLS AROUND THE CLEANING ROOM AND TUMBLER ROOM. THESE TWO ROOMS ALSO HAVE DOORS THAT AUTOMATICALLY CLOSE IN CASE OF FIRE. <2> Release Containment 0~,,- ,-~i~..s~ co,~4~,~,.~.4 ~,o,,.4,'~ ,~,~s~.~ /,,el~d~ closed <3> Clean Up ~ew c,'+? cl~.,,.,-.,- cl~..,., ,.,/,. ,o,.-o~,o,,.,,.' ,',., c.~,~ o,~ ,~ .~?,'n ,'~ 4o <4> Other Resource Activation 04/14/92 NEW CITY CLEANERS 215-000-000354 Page 5 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - OUTSIDE BUILDING BETWEEN CUSTOMER/EMPLOYEE PARKING B) ELECTRICAL - BOILER ROOM C) WATER - NORTHWWEST CORNER OF PROPERTY ON 8TH STREET D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - OUR FIRE PROTECTION CONSISTS OF FIRE DOORS ON OUR CLEANING ROOM, DRYING ROOM, .AND BOILER ROOM. THESE DOORS ARE ACTIVATED BY THERMAL BREAKERS WHICH BREAK IN CASE OF FIRE. NEW CITY CLEANERS ALSO HAS FIRE EXTINGUISHERS AT OUR CLEANING ROOM DOOR, DRYING ROOM DOOR AND IN THE MIDDLE OF OUR PLANT. <4> Building Occupancy Level 04/14/92 NEW CITY CLEANERS 215-000-000354 Page 6 00 - Overall Site <G> Training <1> Page 1 WE HAVE 20 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA'SHEETS ON FILE. HAZARDOUS MATERIAL TRAINING MEETINGS ARE DONE ONCE A YEAR WITH OUR EMPLOYEES. NEW EMPLOYEES ARE GIVEN TRAINING ~URING THEIR FIRST WEEK OF EMPLOYMENT. THE TRAINING CONSSISTS OF GOING THROUGH OUR EMPLOYEE BINDER WHICH INCLUDES MATERIAL SAFETY DATA SHEETS, EVACUATION PROCEDURES, AND EMERGENCY PROCEDURES. THE BINDER IS LEFT IN OUR EMPLOYEE BREAK ROOM FOR THEM TO STUDY. <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use " ' DO NOT REMOVE Chevron C~VRON Thinner 325 6PS218223 Page ~ o~ 7 This Material safety Data Sheet contains envtronmenta%, health and ~nxicoiogy infor~.ation fo.' your employees. Please make sure information ~s g~ven to them. ~ also contains ~nforma~on to help · yo~ meet c~un ity" r ~ght-t~knov/~rgen~ ~~e T~or~ ing requirements under S~ Title III and many o~her laws. I~ you'.resell this p~uct, th~s MSDS must be given to the buyer or the information ~ncor~orated in you= MSDS. D~scard any previo~ edition of this MSDS. 1. PKODOCT ID=~FICATION C~VaON Thinner 3~5 - ~P~T=D ~ PROLONGED B~ATHING OF VAPOR OR'C~ACT WI~ SKIN ~Y BE - ~Y ~USE SKIH I~ITATION -- CO~STI8~ · ~RODUCT k~ER(S): CPS218223 PRODUCT INFO~TION: (800)582-3835 '( Revision Nu~be£: '1~4 '"-' Revision Date:' 04/24/90 M~DS Number; '000047 · ;.':'~-a. NDA - No Data Available NA - Not; Applicable ...... t~tepare~ According to t~e ~i~ Hazard ~icaCioa Sta~m~d (29 C~ xgxo.x2OO) ~ the chevron ~viro~L , X-OOS~I (~-89) ~0'~ ~O0'ON ~:Z ~6'S~ [nf S~9~S~'ON q31' 3H33 CHEVRON Thinner 325 Page 2 o! 7 2. FIRST AID - EK~RGENcY PHONE NUMBER (800) &57-2022 ..... . ........... E~E COIT~AC?= ~o ~rst a£d procedures are required. Hoveve~o as a precaution ~lush e~es with fresh water for 15 minutes. Remove contact lenses if worn. SKIN Remove contaminated clothing. Wash skin thoroughly with soap and wa~er. See a doctor i~ any signs or symptoms described in ~his documen~ occur. Discard contaminated non-waterproof shoes and boots, wash coat~u~inated clothing. l~ an2 signs or s~pto~ as described in this doc~ent occur, move the person to ~resh a~r. If an~ og these eggec~s continue, sea a doctor. INGESTION= If swallowed, give water ~ m~lk ~o drink and ~elephone for medical advice. DO NOT make parsom vomi~ unless directed ~o do so bM medica~ .. personnel.. ~Z medina ~vice ~aot be ~i~ed,.then ~ake the person and ....... produ~ ~ntainmr to ~he nearest ~edical emergen~ treatment ~nte~ '. hospital. Note ~o Ph2s~cian: Inges~ion of ~his product or subse~en~ vomiting can resvl~ in aspiration o~ light hMdrocarbon liquid which cause pne~onit is. · . X~DIATE HE~E E~EC~S - (ALSO SEE SECTIONS 1~ ~ 12) EYE CO~A~ = "~.~ · ~S su~nca is ~o~ expected ~o c~usa p~olonged o~ signi~ican~ T~e sk~ ~FF~a~o~ po~en~ia~ o~ ~s svbs~ance has no~.be~n de~eFmined. However, i~ ma~ be a m~era~e skin irritant so contact with ~he sk~n could cause prolonged (dazs) injury to the agfected area. The degree of will depend on the ~oun~ o[ ~erial that gets om the ~kin and the speed ~nclude pain or a feelin~ of heat,'discolo~Lion, swelling, and blts~e~ing. T~is h~ar~ eval~ti~ ~s ~sed on da~a materials. DE~ ~XIClTY= I~ absorbed through ~he ~kin, ~his su~kance is considered Practicall~ non-toxic to internal or~ns. Th~s hazard evaluation is ~aed on data · ~rom similar ~aterials. Bre2thing the va~rs at concentrations a~ve the reco~ended · standard can cause central nervous system efEects.., s~gns and s~pto~ o~.. central nervovs system e~fec~s ma~ incLvde one or more o~ the foLLo~ng~ headache~ dizziness~ Los~ of appeti~e, ~ea~ness and loss o~ coordination. This hazard evaluation i~ based on da~a [r~ similar materi~ls.' Read the Add~tionaL.Hea~th Data section (12) of this doc~ent for more information. ~ IN6ESTION~ ............. ..,~ ~A - No Data Available NA - Not Applicabla · £0'~ ~O0'ON ~:~ ~6'£~ [nC S~9~£~S~'ON ~3L. CHEVRON Thinner 32~ Page ~ of 7 The systemic toxicity of this substance has not been determined. ~owever, it should be practically non-toxic to ~n~e=na~ organs if swallowed. Because of the low viscosity of this substance, it can directly enter the ..'" lungs if it i~ swallowed (this is called aspiration). This can occur during ~he act of swallow~ng or when vomiting the substance. Once in =he lungs, the substance is very dlfficu!~ to remove and can cause severe injury to the lungs and death. This hazard evaluation Is based on data from similar mate=~als. &. PROTECTIVE EQUIPMENT E~E PROTECTIONt SKIN PROTECTION= Avoid contact with skin or clothing. Skin contact shoula be minimized by wearing protective tlothing including gl0ves. RESPIRATORY PROTECTION: Wear approved respiratory pro~ec~on when working wihh. this material .'. '"' unless ventilation ~s adequate to keep aiTborne cUm:entrat~ons below - recommended exposure standards. ... VENTILATION= " "'' Use adequate ventilatio~ to keep the airborne concentrations of this mater~al below the recommended exposure standard. 5. FIRE. PROTECTION : ;,~.~ ...... FLASH POINT= (TCC) 105F (~1C) AUTOI~NIT~ON[ 260C (500F) FLAMI~ABiLITY= 1.0 - 6.0% EXTINGUISHING MEDIA= ¢02, Dry Chemical, Foam and Water Fog. NFPA RATINGS= Health 1~ Flammability 2~ Reac~ivl~ 0~ Sp'sc~al NDA~ I~MIS RATING$~ Health 15 Flammability 2~ Reactivity 0] Other NDA~ (Least-O, slight-i, Moderate-2, H~gh-3, Extreme-4). These values are .'obtained using the gu~del/nes or .published evaluations prepared by the National Fire Protection Association or, if applicable, the National Pain~ and Coating Association, and do not necessarily reflect'the hazard evaluation of the Chevron Environmental Health Center. Read the entire .. document and label befor~ .using this pro~t.~.. ........................ FIR~ FIGHTING PROCEDURES= Liquid evaporates and fo=ms vapo~ (fumes) wh'ich can catch f~re'and burn'' with explosive violence. Invisible vapor spreads easily and can be set on ~ire by many sources such as pilot lights, welding equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises above 86 F.. .......... '. · ................. w''. ............... For fir~s involving this mater~al, do ncc enter any enclosed or confined fire space without proper protective equipment. This may include self-contained breathing apparatus to protect against the hazardous ~ effects o~ normal products of combustion or oxygen deficiency. 'Read the ~::.% ......... -,. .. -,,, ~' Revision Number= 14 Revision Data: 04/24/90 MSD$ Number= 000047 NDA - NO Da~a Available NA - No~ A~plicable · X-00~ mi-sm CHEVRON Thinner 325 Page 4 o£ 7 entire document. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide and water vapor; incomplete -- - combustion can produce carbon monoxide. 6. STOItAGE, HANDLIHG, AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS: STABILITY: Stable. HAXARDOUS Pol~merization will not occur. INCOMP&TISILITY~ May react with str~ng oxldiz~ng agents, such as chlorates, nitrates, peroxides, etc. READ AND O~LT~VE ALL PRECAUTIONS ON PR~D~CT. LAAE~ DO .NOT .USS OR STORE " .... ne&r ~lame,-spaTks or hot surfaces. U~E ONlY IN WELL VENTILATED AREA. Eeep container closed. DO ~OT weld, heat or drill container. ~eplace cap · or bung. Emptied container s~ill contains hazardous or exp~osive vapor or liquid· CAUTION! Do no~ use pressure to empt~ drum of explosion may result. ' 7 · PHYSICAL PROPERTIES 8OLUBI~XT¥: ~oluble ~ hydrocarbon solventsl insoluble 'in water. APPEARANCE~ Colorless liquid. BOLLING POINT~ 163C (325F) 5% Rec, (Max.) MELTING POINT= NA .' EVAPORATION~ 0,22 (BU AC-l) '' , SPECIFIC GRAVlTY~ 0,788 ~ 15.6/15.6C VAPOR PRESSURE: 2.Bnv~ Mg @ 20C (68F) of VOC. ., PERCENT VOLATILE (VOLUME %): 99*% .... ' VOLATIL~'O~C, ANI~ COMPOUNDS (~OC) = 788 g/l[~er (Max,) , VA~Oa-DERS~TY'(A~-i)~ ~,8 " . .... VISCOSITY: 0.96 -cst ~ 37.BC .' ..... 8. F.NVIRONMENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL CHEMTREC E}fgRGENCY PHONE NUMBER-' (800) 424-~300 (24 hour). Certain geographical a~eas have air pollution restrictions concerning the use of ~terials i~ work situations which ~y release volatile components to the at.sphere. Air pollu~ion regulations should, be studied' ko dete~ine if..this ma~eria~ is regulated in the a~ea where it is to be Revision N~er= X& Revision Date: 00/24/g0 ~DS Numar: 000047 ND~ - N9 Da~a AvaiXable MA - Mo~ ~plicable · x-oo$~ (ff~ c:;O'd '[O0'ON ~'~':Z '1:6'£~: Inf' c;~:9~:£~:~'1:I;"ON 9:31, 3H33 CHEVRON Thinner 325 Page 5 of 7 Eliminate all open flame in vicinity of spill or released vapor. S~op the source og the leak or release. Clean up releases as soon as possible, "'.':: observing precautioils in Protective Equipment. Contain liquid to prevent ~'~ further contaminatiox~ of soil, surface water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding, to larger releases. DISPOSAL METHODS= Place contaminated materials in disposable containers and dlspos~ of in a manner consistent with applicable regulations. Contact local environmental or health author~ties for approved disposal of this materlal. 9. EXPOSUI~E STANDARDS, I~EGULATOR~ LIMITS AND COMPOSITION · coMPoS ~TION COMMENT: All the cu~ponents of th%s'matm~"~al are un the Toxic Substances Control Act Chemical substances Inven~ry. The percent compositlo~s are 9iven to allow for the various ranges of the components present in the whole product and may not equal 100%. PERCENT/CAS# COMPONENT/REGULATORY GIMITS 100.0 % CHEVRON Thinner 325 CONTAINING 100.0 % STODDARD SOLVF~qT .... CAS8052~1~ 100ppm AC~IH TLV 100p.c~ OSHA PEL , " 0.5 % L,2,4-TRIMETHYLBEN~ENE . _. CAS95G36 : . A toxic chemical subject to the reporti.~g requirements of ''Section'313 of Title 'III:of the super~undA~endments GAd Reauthorlzation Act of 1986.'and 4~ cFR Pa~t 372. SAF~3~2/30% ~Q- ~OUNDS TP~-10,000 POUNDS 0.2 % 1,3, $-TRIMETHYLB~ZENE .... CAS108678 .... :: .... . · .. ~...~ ...... TLV - Threshold L~it ~alu~ ........ P~L"- Permissible Exposure Limit STEL - Short-term Exposure Limit TPQ - Threshold Planninq Quantity RQ - Reportable Ouantlty CPS - CUSA Product Code CC -..Chevron Chemical Company .... :.CAS - Chemical Abstract Serv~c~ N~ber ............. 10. I~SGULATORY Ih-L~ORMATION .-. ~;~ Rtvisioa Nu~be~: 14 Revision Date: 04/24/90 .HSD5 Ntm~e~ 000047 NDA - No Data Available NA - No~ AppLicable 90'~ TOO?ON ~P:Z ~6'£C ln£ S~9~£CS~P'ON 931, 3H33 CHEVRON Thtnne= 325 Page 6 of 7 SARA 311 CATEgORIeS: ~, Inu~ediate (Acute) Health Effects; YES 2. Delayed (Ch=onic) Health Effects; YES 3. Fire Hazard; YES 4. Sudden Release o~ Pressure Bazard; NO 5. Reactivity Hazard; NO NHff~I ~ COHPONENT O~ THIS I~TERIAL IS SHO~ I~ ~HIS SECTION, REGULATORY LIST OH ~ICH IT APPLE IS INDICATED. 1,3,5-TRINST~LB~Z~E 02,26,28, STODD~ SOLVENT 02,10,11,14,17,28, ~2~4-TRIHST~LBENZE~E ... 0~-8A~ 3~3 .... · 02=~.~ 03-N~P ~r~nogen ... '07-IARC Group 2A 08-IARC Group 2~ 09-S~ 302/304 10"PA RTK 11"N~ R~ 12~CEKC~ 302.4 13-~ RTK 1%~ACGIH TLV 15-AC~IH 16-ACGIH Calculated TLV 17~OS~ PEL 18~OSHA 19-Chevron T~v 20-EPA Carcinogen 21-TSCA SECT 4 22-TSCA SECT 5 SNUR 23-TSCA SECT 6 RULE 2%-TSCA SE~ 12 EXPORT 28-TSCA SECT 8A CAIR 26~TSCA SECT SD ~PORT 27-TSCA SECT 8E 98-Canadlan ~IS 11. PRODUCT TOXZCOLOG~ DATA NDA.. The hazard evalua~{on was ~sed ~'da~a from s~mila= materials. SKIN I~ITATION~ v .- NDA. The hazard evaluation w~ based on '~a '~ s~r ~~0~/I~I~: ' ' ~A.' Th% bazar4 evaLuat$0n was base~ o~ 'aata' from similar ', : ~ ~.. ~..~'~ ~. %.' t' .~.. ..:-.~ .'.~..~ ~'.'- ........ 12."~DlTION~ ~ALTH DATA ..................... .... .. ... .. · ..... . .~ ... ,.,....~ ......... ~.. ..... ~ ..... :~~: 'Ra~orts have associated re~ea~ed and prolonged occupational overexposure to solvents with pe~nan~ b~a[n an~ nervous system d~a~e. re,=ted include fatigue, concentration difficulties, anxiety, depresslon,.~=. '. rap~d mo~ swings, a~d'sh0rt-te~~=~ '16ss. The re~r~s are ~ot clear .... ..... Revtsion Nu~ecz 14 .' Revision Date: 0&/24/90 ~DS H~eF: 000047 NDA - NO na~a Available NA - Ho~ Applic~le · , X-OO,,~(01-~l ZO'd IO0'ON ~:Z ~6'S~ In£ S~I9I£~I~'ON 931' 3H33 CHEVRON Thinner 325 Papa 7 of 7 with re~a~d to the types of solvents that may cause these symptoms, and =here is convrpversy amen9 sclentist~ vith re@etd to whether the condO=ion exists or is caused by this type of product, Since many other diseases cause some or all of these condition~, a doctor should be consulted if any · . appear, Always use this mate~al in strict accordance with the instructions on the label or ~n th~s document, The above information is based on the data of which we believed to be cocrect as et t;he date heceof. Since the information contained he=eifl may be applied under conditions beyond ouc con~=ol and wi~h which we may be vn~asiliar and since data made available subsequen~ to the da~e he=eo[ ma~ suggest Modtf~catlon o~ the information, we do assv~e any ~esponsibilit~ ~o~ ~he ~esvl~s o~ its use. This information ~ucn~shed upon condition ~ha~ the person receiving i~ shall make his own ..... purpose. Revision Number: 14 Revision Datel 04/24/90 MSDS Number: 0000~7 l~A - No Data Available HA - Not Applicable · X-OOSffil(~-ffi) 80'd I00'ON ~:Z I6'S~ [n£ s~IgI£~SI~'oN ~31, 3H33 ~! C~'i'Y of BAKERt:;i-/ELD Farm and.~.gtJculture ~1' Standard Business ~1~HAZARDOUS MAT ERTA'LS INVENTORY NON--TRADE SECRETS ~ Pa~j~ I of. Code ~ooe Amt ~a[ Est Un,ts on Type Press ~e~e Co~eStored ~n ~acl/Icl See Instruc~FIVF~ __ p I I : II .II lollI I I " (Check all that apply) ~ Component IZ Name I C.A.S. Number HAZ. MAT. DIV. Hazard ,~ Reactivity ~ Delayed ~ Sudden flelease ~ Immediate ~ Health of Pressure Health Component 13 Name I C.A.S. Number Physical and Health ~alard C.A.S. Number Component II Name t C,A.S. Number (Check all that apply) ~ Fire Hazard ~ ~ Reactivity ~ Delayed' ~ Sudden Release ~ la Component Name C.A.S. Nu~ber ,; HeR lth of Pressure ~ Component 13 Naee'l C.A.S. Number Physical and Healt~ Hazard C.A.S. Number Component II Name I C.A.S. Humber i. Component 12 Name I C.A.S. Number ~ Fire Hazard (~ Reactivity ~ Delayed ~ Sudden Release ~ le~i~ Hea ICh of Pressure [ , Component 13 Name I C,A.S. Number Physical'and Healt~ ~azard ~ C.A.S. Nueber CoaponenC II Naae I C.A.S. Nueber (Check all that apply) ~ Co~ponent I~ Naee I C.A.S. Nueber ~ Fire Hazard ~ aeac:ivit a Oela~edHealth a Suddenof Pressureaelease ~. l,~i~ ~ Componen~ 13 ~aee I C.A.S. Nueber .cern?fy unoer penalty o/laW thqt lhav~personal~Y, examln~;qotm tamil~ar,~it~ the jntormacton ~u~mitt~ in this,~nd all ~¢~ oflc.l!l t ~ o( nertop R o~ner~rator s author~led r~p~tative -- .,~. ~ ~.,~ C~TY of BAK£RSFI£LD 5¢q ~.x /~ ':,~ ~"- -~~ '~'~ "WE C. 4RE" ~c, ..._~ ....'~ ,... ~.. --.~ ..v 4~¢ ~ ~ ?~ '"'"" ..... " ~4 ~",i~ .......~~// ~ --z;: ,: ~;: ,' L (~roe o~ p~znz name) ~C~tVED ~o he-~b3- ee:t~v th&t ~ h~ve :evLewe~ the . '.'~I~-~ ~ - . ~ ~ ~ t 1989 ~n~.LL ....... attached Hazardous Materials business ~lan . , (n~e o~ business} and that it along with the attached additions or corrections constitute a comDlete and correct Business Plan for my facility. · ur- date BUSINESS NAME NEU CITY CLEANERS I~] NU~ 2)5-~O~-O4~gJ54 LOCATION 1452i 8TH ST HIGH HAZARD RATING 3 I. OVERVIEW LAST CHANGE 06/23/88 BY'ESTER JURIS CODE Z1S-..OCG JURI~ BAKERSFIELD STATION M~P PAGE 1¢3 GRID 3lA FACILITY'UNITS i HAZARD RATING RESPONSE SUMMARY ZA SEC 4.) NEW CITY CLEANERS HAS A CHAIN OF COMMAND OF FIVE PEOPLE WHO KNOW .. OUR OPERATION 'WELL. EACH ONE KNOWS THE PROPER PROCEDURES FOR COORDINATING ACTIVITIES WiTH RESPONSE-~GENCIES, USING SAFETY EQUIPMENT E EVACUATION PROCEDURES IN CASE OF ~N EMERGENCY. EMERGENCY CONTACTS ZA SEC Z) JARRELL L. EPP - 324--9414 OR 398-908¢ HENRY F. BRflNDT - 3Z4-9414 OR UTILITY.SHUTOFFS 2A SEC A) GAS - OUTSIDE BLOG BETWEEN CUSTOMER/EMPLOYEE PARKING 8) ELECTRICAL. - BOILER ROOM .C)'W~TER - NW CORNER OF PROPERTY'ON 8TH'ST O) SPECIAL - NONE E) LOCK BOX - NO 2. NOTIFICATION / PUBLIC EVACUATION LAST CHANGE / / BY < NO iNFORHATION RECORDED FOR THIS SECTION > In case of emergency New City Cleaners has a chain of command of five people who know our operation well. Each one knows their responsibility if an emerg,ency does arise, One person evacuates the building including employees and customers while another calls 911. I have two backups for each person. This coordination between our staff should lead'~t0~p,~p~e'~"notification and evacuation or our building. PBGE 1 1Z/ZJ/88 tZ."49 MATERIAL SRFEt'Y D~T~ SYSTEMS, INC. (805) [S48-G8¢0 BUSINESS NAME NEW CITY CLEANERS ID NUMBER Z1S~.f)~O-'~00354 LOCATION 18Zi 8TH ST HIGH HAZARD RATIN[) 3 3. HAZ MAT TRAINING SUMMARY LAST CHANGE / / BY < NO INFORMAl'ION RECORDED FOR THIS SECTION > Eazardoas material training meetings are done once a year with our emgloyees. New emgloyees are given training daring their first week of employment. The training Consists of going through our employee binder which includes Material Safety Data Sheets, evacuation ~rocedares~ a~d.'emergency procedures. The binder is left in oar employee brea~ room ~or them to study. 4. LOCAL EMERGENCY MEDICAL ASSISTANCE L.~ST CHANGE 0G/Z4/88 BY ESTER SEC S) IN CASE THE MEDICAL EHERGENC¥ IS MINOR WE HAVE A FIRST AID KIT IN OUR REST AREA~ iF THE INJURY IS MORE SERIOUS WE WOULD CALL_ HALL RMBULflNCE OR GOLDEN.EMPIRE ~MBU[.RNCE, THESE TWO NUMBERS ARE POSTEO BY OUR PHONES, PAGE Z ~2/Z5/88 1Z:49 MATERIAL SAFETY DATA SYSTEMS, INC, (80S) 648-G800 BUSINESS NAME NED CITY CLEANERS ID NUMBER Z!5-.0~--000354 LOCATION 1021 BTH ST HIGF~ HAZARD RATING 3 FACILITY UNIT R. OVERALL HAZARDOUS HATERtAL. S INVENTORY LAST CHANGE 0G/24/88 BY ESTER ID TYPE NAME MAX RMT UNIT H~Z~RD LOCATION CONI'RINMENT USE 1 MI×TURE CHEVRON THINNER 3ZS 10000 GAL EXTREME UNDERGROUND TANKS UNDERGROUND TANKS CLEANING ID PERCENT COMPONENTS H~Z~RD LIST 1203,01 98.0 PETROLEUM NRPHTHR EXTREME I00t,,~ 2.0 BENZENE HIGH FIRE PRDTECTION / W~TER SUPPLIES LAST CHANGE / / BY < NO INFQRMA. TION RECORDED FOR I'HtS SECTION > Our fire prot~ctibn cOnsists'~of' fire doors on' 'our c~eaning roo~n-,-drying room, and boiler room. These doors are activated by thermal breakers which break in case of fire. New City Cleaners also has fire extinguishers at our cleaning room door, drying room door and in the middle of our plant. P£~GE 3 1Z/Z3/88 12:4B MPITERIAL SAFETY DATA 'SYSTEMS, iNC. (805) G48--G800 B1JSINESS NAME NEW CITY CLEANERS ID NUMBER Z15-~-000354 LOC~TtON 10Z! 8t'H ST HiGH HAZARD RRi'ING D. EMPLOYEE NOTIFICATION / EVACUATION I_RST CHANGE ~G/Z4-/88 BY ESTER SEC Z) NEW CITY CLEANERS EVACUATION PROCEDURE CONSISTS OF ONE PERSON OF THE FIVE PEOPLE IN PRIVATE RESPONSE 'TEAM VERBALLY TELLING EACH EMPLOYEE TO EVACUATE THE BLOB ET THE NEAREST EXIT AND.TO HERD EAST ON 8TH ST RS QUICKLY RS POSSIBLE. ALSO DURING THiS TIME A SECOND PERSON ON THE RESPONSE TEAM WOULO BE CALLING 9ti AND EXPLAINING OUR EMERGENCY~ E. MITIGATION t PREVENTION ! ABATEMENT LAST CHANGE 0~/Z4/88 BY ESTER SEC 1) OUR PREVENTION PROCEDURES CONSIST OF GOOD HOUSEKEEPING & PREVENTIVE ' MGtlNTENRNCE ON OUR M~CHINES t{ EQUIPMENT. OUR CHEM!C~L.S PRE KEPT IN RN ORDERLY MANNER WITH T.HEIR LIDS ALWAYS ON.. THE MRCFtlNES ARE KEPT UP DRILY AND OUR VALVES TO OUR TANKS ARE CLOSED' UNLESS IN OPERATION. WE HAVE R NO SMOKING POLICY EXCEPT iN THE LUNCH ROOM ~IHICH iS ACROSS THE PLANT FROM OUR CHEMICALS. IN ADDITION NEW CITY CLEANERS HMS ~2 INCH HRSONRRY WALLS RROUNO I'HE CLEANING ROOM AND TUMBLER ROOM. THESE TQO ROOMS ALSO HAVE DOORS THAT AUTOMATICALLY CLOSE IN C~SE OF FIRE. PAGE 4 1Z/~/88 1Z:Z~9 MATERIAL SAFETY DR'FA SYSTEMS, tNC. (80S) G48-G81~ CITY of BAKERSFIELD NON--'FRAD E S E C R E TS ' ~'q'-L "f .... CITY, ZIP: ~,-r~[~ ~7~ CITY, ZIe: -~r~ ~ ~d~ DUN AND BRADSTREET .U.BER I 2 3 4 S S I I ! I! II 12 13 ?re~ TyI~ I~x Aver~je ~a~Jl! Msu~ I ~ ~t ~ ' ~t ~ L~ttm ~ t ~ ~ ~ N~xt~/~tl ~.~_J.___~__l B~._J_~_~. g~! o71 / I ~ I o~ ~, ~,,~%~~ .~o ~4,~+ : of Pm~ ~ith ' - ~lth of P~ ~lth -- ~_.~_I_~_~_L_.~._J soo ~d~~7J / ~C.,~-,.,~,.. ~.,.,.~ ~,,,--,~.,.,.~ ~ ~, · ~y~r~,~ - - ,_ ._. ._. ~,, ,.,~.A.,. ~ ~ ~j~ ~y~,~ ,~ Hfllthof P~su~~lth H~lth of Pr~su~ H~lth C~ttfic4ti~ (Read and sJ~ after co.pleting all sections) .. f~ obtlininQ t~ tnf~ttm. I ~lieve t~t t~ lu~itt~ inf~tim is t~, ~curltl, ~d c~pl~. ~ . '~ ~c~L ~ ~ ~ . ,', ~ - ' -' ' ~ - CITY of BAKERSFIELD ~re and '~gr~¢ultur~ '' Standard Ilusiness ~ ~"~J~II'ZJ~IL]:~'~)OT'~'~ ~vj,i~L~I~I~_R-E ~~ ~ ~~0~' NON--'tRADE SECRETS ' ~e ~ 'of .... BUSINESS NAME: OWNER NAME: NAMg OF T~ FACILITY: LOCATION: ADDRESS: STANDARD IND. CLASS CODE CITY, ZIP: . CITY, ZIP: · DUN AND BRADSTREET NUMBER PHONE I: PHON~ ~: --- - ___- ?ra~ Ty~ ~x A~r~ ~1 ~sum I ~ Cmt ~ ' ~t ~ L~tlm ~ %~ ~ ~ Mxt~/~ts ~c,~ ~ ..~th ~,,~ C.A.S. ~ ~, 8t ~ & c.a.s. ~ ~0 ' ' Fire Hazard u--~ R~ttvf~y hla~hu--J~lt ~ ~1= ~--~ I~llt/ ...... ..... [ 1 .... ............ 1 .............. 1 _1 ..... 1 ...... k_! ....... El. I .... (~k ~11 t~t ~pply) - r--~ r--~ r--~ r-~ ~t ~ ~&C.A.S. ~ ~lth of ~ ~lth ~ L_I_ .... L .......... 1_ II [ ! Ii ] (C~k ell t~t -- -- r--~ -- r--~ ~t~ ~&C.A.S. ~ [ ~ Fl~e Hazard [ ] R~ttvtty ~--~ ~1.~ [ ] ~ Rei~e ~--~ I~tate ___t .......... L ............ i .......... 1 I__1 J.I 1__ I ..... P~ical ~ HHlth ~ll~ C.A.S. ~ Wt I1 h & C.A.S. ~ (C~k i11 t~t aNly) ; -~ ~-~ [-3 [Z] c~t ,2 .~ ~ C.A.S. ~ Ft~e Hazard u--~ ~t~v~ty ~1~ ~d~ blme [--~ HHIth of Pr~surl HHIth ~tl] hiC.A.S. ~ ~"ERGENCY C~TACTS I1 ~i~'[ ................................... fiTli ....................... ;I'flF'P~ ...... ~' Title ~r~ ...... CertificatJm (Reed and si~ after colpJetJnE ail sections) I certify ~der ~lty of 1~ tMt I ~ve ~rs~allye,~n~ ~ a. f~liae .1th t~ ~nf~Mtim su~ttM tn tht! ~ ail ettKM ~ts. ~ tMt ~s~ m for obta~nmg t~ tnf~mttm. I ~lteve t~t t~ suMJtt~ info. tim ~s t~. accurate, ~d cmalete. m~- jRa-6TTTTT]I-TiTli'GT'~G;~;;~T6;'OR'~G;7G~FiEGF'i';GT~;ii~';G;~T;Ei;i ST~;iTG;i ................. ' ............................ ~Ti'Si~R~ .................... ~.' BAKERSFIELD, CA 93301 (805) 326-3979 OFFICIAL USE ONLY BUSINESS NA~E HAZARDOUS ~L/kTER I ALS BUSINESS PLAN AS A WHOLE FORM 2A 1. T~ avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: New Citv cleaners B. LOCATION / STREET ADDRESS: 1021 8thSfrea~ CITY: Bakersfield, CA ZIP: 93304 BUS.PHONE: (805) 324-9414 SECTION 2: EI~ERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS. A. Jarrell L. Epp Owner Ph# 324-9414 Ph# 398-9080 B. Henry F. Brandt Consultant Ph~ 324-9414 Ph# 871-3076 SECTION 3: LOCATION OF UTILITY SfPJT-OFFS FOR BUSINESS AS A W~OLE A. NAT. GAS/PROPANE: Outside of building.betweencustomer and employee parkinq B. ELECTRICAL:_ Tn hn~l~r ~ c. WATER: Tn n~r~hwe~ cQ~ner of ~rop~rty on 8th ~t, D. SPECIAL: E. LOCK BOX: YES /~ IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 2A - SECTION 4: PRIVATE RESPONSE TEA~4 FOR BUSINESS AS A WHOLE New City Cleaners has a chain of cc~n~nnd of five people who knowour operation well. Each one knows the proper procedures for coordinating activities with response agencies, using safety equipment, and evacuation procedures incase of an emergency. SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE -~fT.~tnj~ase the medical emergency is minor we have a first aid kit in our rest-area. If the injury is more serious we would call Hall Ambulance or Golden Empire Ambulance. These two numbers are posted by our phones. SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAZARDOUS MATERIALS:...- .................................... ~ NO YES NO B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGENCIES: .......................... (~ NO YES NO C. PROPER USE OF SAFETY EQUIPMENT: .................. NO YES NO D. EMERGENCY EVACUATION PROCEDURES: ......... . ........ NO YES NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... NO YES NO SECTION 7: F~ZARDOUS ~ATERIAL CIRCLE YES OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, $§ GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES NO I, Jarrell L. Epp- , certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazar-dous Materials (Div. 20 Chapter 6.98 Sec. 28800 Et Al.) and that inaccurate information constitutes per3ury. BAKERSFIELD CITY FiRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 0FFIC[AL USE ONLY ID~ BUSINESS NA~IE: BUSI NESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as .possible. '. FACILITY UNIT# FACILITY UNIT NAME: New City Cleaners SECTION 1: MITIGATION, PREVENTION, ABATEMENT PROCEDb~RES Our prevention procedures consist of good housekeeping and Preventive mintenaince on our machines and equi~m~_nt. Our chemicals are kept in an orderly manner with their lids always on. The machines are kept up daily and our valves to our tanks are closed unless in operation. We have a no smoking policy except in the lunch rocm which is across the plant from our chemicals. In addition New City Cleaners has 12 inch masonary walls around the cleaning room and tumbler room. These two rooms also have doors 'that automatically close in case of fire~ SECTION 2: NOTIFICATION AND EVACUATION PROCED%~RES AT THIS b"NIT ONLY New City Cleaners evacuation procedure consists of one person of the five people in ~ivate response team verbally telling each employee to evacuate the building at the nearest exit and to head east on 8th. Street as quickly as possible, Also during this time a second person on the response team would be calling 911 and explaining our emergency. Section '1 .cont. · In case of a spill:of chemical we wipe the chemical up with rags and clean them in our cleaning machines to get the chemical back into our sy~ten% - SECTION 8: HAZARDOUS MATERIALS FOR THIS L~IT ONLY A. Does this Facility Unit ~ontain Hazardous MaterJa!s? ...... YES NO If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES NO If No, comPlete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form #4A-l) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form :4A~2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTIO~ 4: PRIVATE FIRE PROTECTION SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY E~4ERGENCY RESPONDERS SECTION 6: ~OCATION OF UTILI?f SHUT-OFFS AT THIS UNIT ONLY. A NAT ~,'~-~P~N~, B. ELECTRICAL: C. WATER: D. SPECIAi: E. LOCK BOX: YES ,." NO IF YES, LOCATION: IF %'ES, SITE PLANS9 %'ES / ~:0 MSDSs'? YES ,; NO , FLOOR PLANS? YES / NO KEYS? YES ..,' NO - 3B - BAKERSFIELD CITY FIRE'DEPARTMENT I.D_ # FORM 4A-1 Page / of NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY BUSINESS NAME: /6~d~J ~".[6Gr'lCfS OWNER NAME:' ~"of(dl/,L. ~ FACILITY UNIT ADDRESS: /D~; ~r,,~ ADDRESS: ~/dd~/nq~f/~ FACILITY UNIT NAME: PHONE {: .?~-q~/~ PHONE {: .~q/-Y040 {OFFICIAL USE CFIRS CODE { ONLY 1 2 3 4 5 6 .7 8 9 10 TYPE HAX ANNUAL COST USE LOCATION IN THIS ~ BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIOE Ch5//1-74-2 EMERGENCY CONTACT: rte[~ C, /f/ TITLE ~ PHONE { OURS: AFTER HRS: EMERGENCY CONTACT: ~'~rf ~ ~r~7 TITLE: C~n~/¢~¢- PHONE ' BUS HOURS: PRINCIPAL BUSINESS ACTIVITY: ' ~ry C/¢m~,~ AFTER BUS. HRS: 4A-1 - . . BAKERSFIELD CITY FIRE DEPARTMENT 17.D. ~ FORM 4A-1 Page ~.~ of NON--TRADE SECRETS HAZARDOUS MATERT ALS T NVENTORY BUSINESS NAME: OWNER NAME: FACILITY UNIT ADDRESS: ADDRESS: FACILITY UNIT NAHE: CITY, ZIP: CITY,ZIP: PHONE ~: PHONE ~: [OFFICIAL USE CFIRS CODE ONLY ' HAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O.T AHOUNT AHOUNT UNIT CODE CODE FACILITY UNIT ~T. CHEHICAL OR COHHON NA~E CODE GUIDE M, rkl CJ5 d f 7q -2q- NAHE: TITLE: SIGNATURE: DATE: EHERGENCY CONTACT: TITLE: PHONE ~ BUS HOURS: ' ' AFTER BUS HRS: EMERGENCY CONTACT: TITLE: .. PHONE ~ BUS HOURS: :PRINCIPAL BUSINESS ACTIVITY: AFTER BUS. HRS: 4A-1 - BAKERSFIELD CITY FIRE DEPARTMENT -.D.. ~ FORM 4A-1 Page 3 of NON--TRADE SECRETS '- HAZARDOUS IVIATER I ALS INVENTORY BUSINESS NAME: OWNER NAME: FACILITY UNIT #: ADDRESS: ADDRESS: FACILITY UNIT NAME: CITY, ZIP: CITY,ZIP: PHONE ~: PHONE #: {OFFICIAL USE CFIRS CODE { ONLY 1 2 3 4 5 6 ? 8 9 10 ~YPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT ~T. CHEMICAL OR COMMON NAME CODE GUIDE . ~AM~: T~TL~: S~GNAT~R~: DAT~: AFTER 8US H~S: 4A-~ - . BARERSFIEI, D CITY FIRE DEPARTMENT I.D. ~ .. FORM 4A-1 Page "7 of NON--TRADE SECRETS HAZARDOUS MATERI ALS I NVENTORY BUSINESS NAME: OWNER NAME: FACILITY UNIT #: ADDRESS: ADDRESS: FACILITY UNIT NAME: CITY, ZIP: CITY,ZIP: PHONE ~: PHONE #: [OFFICIAL USE CFIRS CODE ONLY 1 2 3 4 5 6 7 8 .. 9 10 . TYPE MAX ANNUAL CONT USE LOCATION IN THIS g BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE NAME: TitLE: S I GNATURE: DATE: EMERGENCY CONTACT: TITLE: PHONE 8 BUS MOURS: AFTER BUS MRS: EMERGENCY CONTACT: TITLE: PHONE 8 BUS MOURS: PRINCIPAL BUSINESS ACTIVITY: AFTER BUS. BRS: ~ - 4A-1 - . BAKERSFIELD CITY FIRE DEPARTMENT I.D. ~ '~/;' FORM 4A-1 Page ~of NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY BUSINESS NAME: OWNER NAME: FACILITY UNIT #: ADDRESS: ADDRESS: FACILITY UNIT NAME: CITY, ZIP: CITY,ZIP: PHONE ~: PHONE #: [OFFICIAL USE CFIRS CODE ONLY 1 2 3 4 5 6 ? 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CGDE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE NAME: TITLE: SIGNATURE: DATE: EMERGENCY CONTACT: TITLE: PHONE # BUS HOURS: AFTER BUS MRS: EMERGENCY CONTACT: TITLE: .. PHONE # BUS HOURS: PRINCIPAL BUSINESS ACTIVITY: AFTER BUS. MRS: 4A-1 - BAKERSFIELD CITY FIRE DEPARTMENT I.D. ~ FORM 4A-1 Page L~ .of NON--TRADE SECRE.TS HAZARDOUS I~IATER I ALS I NVENTORY BUSINESS NAME: OWNER NAME: FACILITY UNIT #: ADDRESS: ADDRESS: FACILITY UNIT NAME: CITY, ZIP: CITY,ZIP: PHONE 3: PHONE #: [OFFICIAL USE CFIRS CODE ! ONLY 1 2 3 4 5 6 7 8 9 lq_ TYPE MAX ANNUAL CONT USE LOCATION IN THIS ~; BY HAZARD D.O.T. CODE A~OUNT AMOUNT UNIT CODE CODE FACILITY UNIT · WT. CHEMICAL OR COMMON NAME CODE GUIDE ~ i J d~t /0oy 8~e ~oom .c~T ~.e NAME: TITLE: SIGNATURE: DATE: { EMERGENCY CONTACT: TITI, E: PHONE # BUS HOURS: AFTER BUS HRS: EMERGENCY CONTACT: TITLE: PHONE # BUS HOURS: { ' PRINCIPAL BUSINESS ACTIVITY:__ AFTER BUS. HRS: ; 4A-1 - . BAKERSFIELD CITY FIRE DEPARTMENT I.D. # FORM 4A-1 Page '/ of NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY BUSINESS NAME: OWNER NAME: FACILITY UNIT #: ADDRESS: ADDRESS: FACILITY UNIT NAME: CITY, _ZIP: CITY.ZIP: PHONE ~: ' PHONE #: {OFFICIAL USE CFIRS CODE ! ONLY 1 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE NAME: TITLE: SIONATURE: DATE: EMEROENCY CONTACT: TITLE: PHONE # BUS HOURS: ,AFTER BUS HRS: EMERGENCY CONTACT: TITLE: ,, PHONE # BUS HOURS: PRINCIPAL BUSINESS ACTIVITY: AFTER BUS. HRS: 4A-1 - BAKERSFIELD CITY FIRE DEPARTMENT ' I . D. · FORM 4A-2 page of':._-.. TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY ADDRESS: /02/ ~f/~ /_~. ADDRESS: ,~'/O0 ~,~.;'~ FACILITY UNIT NAME: CITY. ZIP: g f fz CITY.ZIP: PHONE #: 72-~/-~//9' PHONE #: .F~'o~'-F~F~ iOFFICIAL USE CFIRS CODE ONLY 1 2 3 4 5 6 7 8 9 TYPE ~AX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O~T CODE A~OUNT A~OUNT UNIT CODE CO~E FACILITY UNIT ~T. CHE'~ICAL' OR CO~ON NA~E CO~E GUIDE (Trade NAME: TITLE: SIGNATURE: DATE: EMERGENCY CONTACT: TITLE: PHONE # BUS HOURS: ,, AFTER BUS HRS: EMERGENCY CONTACT: TITLE: PHONE # BUS HOURS: PRINCIPAL BUSINESS ACTIVITY: AFTER BUS HRS: 4A-2 - LA/DLAW CORPORATION 'MATERI'AL SAFETY DATA SHEET (ACCEPTED BY O.'S.H.A. - AS ESSENTIALLY SIMILAR TO O.S.H.A. FORM 20) SECT[ON, I - PRODUCT I'DENTI'FrCAT~ON MANUFACTURER'S N~M~ " EMERGENCY TELEPHONE NUMBER 'LAIDLAW CORPORATION. .. (618) 524-9394 I212 E, 5TH STREET - METROPOLIS, IL. 62960' CHEMICAL ABSTRACT NUMBER.: MIXTURE' CHEMICAL FAMILY: ALBUMINOUS STAIN REMOVER TRADE NAME S SYNONYMS: RAPID SPOT REMOVER FORMULA: MIXTURE OF PHOSPHATE POWDERS AND PROTEOLYTIC ENZYME SECTION II - HAZARDOUS INGREDIENTS INGREDIENT C.A.S. # PERCENT _TL_V_ SPECIFIC CHD.1ICAL IDENTrTIES ARE BEING N~TRHELD AS A TRADE SECRET. SECTION III - PHYSICAL DATA 0 PROPERTY MEASUREMENT 3OILING POINT ( F) NA ~APOR PRESSURE ND VAPOR DENSITY ND SPECIFIC GRAVITY NA =ERCEHT VOLATI LES NOT VALAT! LE ~VAPORATION RATE NA SECTION IV'- FIRE & EXPLOSION DATA ~L~SH POINT (CLOSED CUP),: NA EXTINGUISHING MEDIA: NA tAZARDOUS DECOHPOSITION PRODUCTS: NONE [PECIAL FIREFIGHT[NG PROCEDURES: NONE JNUSUAL FI~E & EXP'LOSIONi HAZARDS' NONE SECTION V - HEALTH HAZARD DATA ~ERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED [FFECTS OF OVEREXPOSURE: .. · FOR PRODUCTS ~YES: LOCAL EYE IRRITATION MAY OCCUR FROM CONTACT WITH THE POWDER OR AOUEOS SOLUTION. ~KIN: SKIN CONTACT'WITHiPOWDER OR AQUEOUS SOLUTION MAY CAUSE LOCAL IRRITATION. ~REATHING: INHALATION OFf DUST OR MIST MAY RESULT IN NON-SPECIFIC IRRITATION OF THE UPPER RESPIRATORY TRACT. ~WALLOWI;.~G: REPEATED INGEST[ON OR THE INGESTION OF LARGE QUANTITIES MAY CAUSE DAMAGE TO THE MEMBRANCES OF THE MOUTH~ THROAT, AND GASTROINTESTINAL TRACT WHICH ThE MATERIAL CONTACTS. IF UNTREATED', TISSUE ULCERATION MAY RESULT. SECTION'V - HEALTH HAZARD DATA (CONTINUED) ESR I:IRST AID .... . .... IF ON SKIN: FLUSH AFFECTED AREA WITH WATER. OBTAIN MEDICAL ATTENTION IRRITATION PERSIST. IF IN EYES:' IMMEDIATELY FLUSH EYES'WITH COPIOUS QUANTITIES OF WATER FOR 15 ' MINUTES. HOLD EYELIDS APART DURING IRRIGATION TO ENSURE THOROUGH FLUSHINg. IF SWALLOWED: GIVE LARGE OUANTITIES OF WATER OR WARM SALTY WATER TO INDUCE :' VOHITING. MILK, EGGS, OR OLIVE OIL MAY BE GIVEN FOR SOOTHING EFFECT AFTER VOHITING HAS BEEN COHPLETED. OBTAIN MEDICAL ATTENTIO' IF ABDOMINAL DISCOMFORT PERSISTS. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICI;AL RESPIRATION. KEEP PERSON WARM, QUIET, AND GET MEDICALiATTENTION. SECTION VI - REACTIVITY..DATA HAZARDOUS :P,O:LY'I~R I~'~T~N~ NONE .. "-D:[SC~E'D'(E:~US.H-:TS'0RF'A:CE~'.TTH..~ATER) OR F.~USH Mt'TH WATER TO ~F~SH'!INTO :'~[WAG'E TS~EH ~[TH ~A~ER OR DI. SPOSE OF WITH MUNICIPAL ~ASTE '" (IF PERN['TTED BY' LOG'A:'~ REGULATIONS). SECT[ON V[[J - PROTECTIVE EQUIPMENT TO BE USED ~ESPJRATORY PROTECTION: ·DUST MASK 'RECOMMENDED. /ENTI~ATJ'DN: PROVIDE SUFFICIENT LOCAL EXHAUST =ROTECTJV[ GLOVES: 'FOR CONTINUOUS HANDLING OF THE PRODUCT ~YE PROTECTION: NOT NECESSARY (CONSULT YOUR SAFETY EQUIPHENT SUPPLIER). 3THER PROTECT[VE EQUIPMENT: NOT NECESSARY SECTION JX - SPECIAL PRECAUTIONS OR OTHER COHNENTS THE INFORNATION ACCUMULATED HEREIN IS BELIEVED TO-BE ACCURATE BUT ~S NOT · ~ARR.ANTED TD BE.~HETHER ORIGINATED WITH LA'JDLA~ OR NOT, ·RECIPIENTS ARE ...: ~OV~SED TO ~ONFIRH ~N A~VANCE OF NEED ·THAT THE ~NFORHATION IS CURRENT/ . ~PPL[CABLE~;~D.SUI.TABLE.TO THE[R CJRCUNSTANCES. .... . · "' " 5/86"' ' ...................... ........... ' ........ R~[S~D']I'] ARTHUR L. BOYKIN IF ON SKIN: Flush area with water.,~.'I. ". IF IN EYES: Flush wtth wnt.~.~ nn4 'nht-~ ~ed~¢~l ~ttontiea: IF SWALLOWED: Obtain medical attention. IF BREATHED: If affected, remove tndtvtdn~l en er~h =t~. 'If bre~thtnF t~ I d~fficult, administer oxygen. Obtatn medic2l ~tt~ntion I. wh~le keeoinK the oerson warm and culet. SECTION VI - REACTIVITY DATA HAZARDOUS POLYMERIZATION: Will not occur STABILITY: Stable INCOMPATABILITY: Heat and Open Flames SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED SMALL SPILL: 'F~u~h--into a munici~sewer if permitted by Iocal re~uIations, LARGE SPILL: - WASTE DISPOSAL METHOD: Check local, state. & federal regulations before dispos product. Do not gun-t-re or Incinerate can, SECT[ON VIII - PROTECTIVE EQUIPMENT TO BE USED RESPIRATORY PROTECTION: VENTILATION: 10C21 exhaust) venttl2tton to PROTECTIVE GLOVES: None b~lnw ~lv Required EYE PROTECTION: Chemical Sol~sh ~o~Fle~ ar~ ndvt~d I 'OTHER PROTECTIVE EQUIPMENT: 'SECTION IX - SPECIAL PRECAUTIONS OR OTHER COHHENTE THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT ~S NOT WARRANTED TO BE WHETHER ORIGINATED WITH LAIDLA~ OR NOT. RECIPIENTS ARE ADVISED TO-CONFIRM IN ADVANCE OF NEED THAT THE INFORHATION. IS CURRENT~ APPLICABLE~ AND SUITABLE TO THEIR CIRCUMSTANCES, 7/21/86 ARTHUR BOYK[N '"; CA~CEPTED BY O.S.H, ~ - AS ESSENTIALLY SIMILA~ikTO O.S.H.A. FORM 20) SECTION I - PRODUCT'IDENTIFtCATION .NUFACTURER'S NAME EMERGENCY TELEPHONE NUMBER .AIDLAW CORPORATION (6lB) 524-9394 212 E. 5TH STREET - MEYROPOLIS, IL. 62960.' :IEMICAL ABSTRACT NUMBER: Mixture ~EMICAL FAMILY: ~tn~ ~ADE NAME & SYNONYMS: _LAIDLAW RpRAy ~RMULA: MIXTURF DE. MODIFIED SQDIUM CARBOXY CELLULOSE. lUBRICANT. INHIBITORS & PERSERVATIVE IN WATER. SECTION II - HAZARDOUS INGREDIENTS INGREDIENT ' C.A.S. ~ ". PERCENT _T~V_ Specific Chemical Identifies are bein~ witheld as a Trade Secret SECTION III - PHYSICAL DATA .... PROPERTY ': i MEASUREMENT · )ILING POINT (0 F) N/A kP~R PRESSURE Not Determined ~POR DENSITY Not Determined ~ECIFIC GRAVITY 1.O62 :.RCENT VOLATILES N/A /APORATION RATE Not Determined I SECTION IV - FIRE $ EXPLOSION DATA (CLOSED CUP): NONE '<TINGUI SHING MEDIA: -~ZARDOUS DECOMPO5 I.TI ON PRODUCTS: NUT I)~'I'~.'J{~IN~J - IECIAL'FIREFIGHTING PROCEDURES: ~ooi ~:xposed container With W~ter '4USUAL FIRE ~ EXPLOSION HAZARDS: ~ressuTizeo cans are ~n explosion hazard when expose~ to ~ire. OD not puncture or incinera~e SECTION V - HEALTH HAZARD DATA iRMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED · -FECTS OF OVEREXPOSURE: FOR PRODUCTS ;ES: ----.'-CAb cause, eye ~rrlt~tion. Obtain medical attention. ~IN: PrOlOnged contact may cause minor skin irritation. 2EATHING: ulzz~ness, t~eadacae, Upper Respiratory Irritation. 4ALLOWING: Can cause ua~crolntes~lnai l~ltatlo~, consult .: LAIDLAW C0RPORATION '" '--"" MATERIAL. SAFETY DATA SHEET (ACCEPTED BY O.S.H.A. -..AS'ESSENTIALLY sIMILAR TO O.S.H.A. FORM 20) SECTION I - pRODucT IDENTIFI-CATION MANUFACTURER'S NAME EMERGENCY TELEPHONE 'NUMBER LAIDLAW CORPORATION .. (618) 524--9394 1212 E..5TH ST. - METROPOLIS, IL. 6.2960 CHEMICAL ABSTRACT NUMBER' MIXTURE CHEMICAL FAMILY: PLASTICIZER TRADE NAME & SYNONYMS: LAIDLAW PLASTICIZER FORMULA' MIXTURE OF PETROLEUM HYDROCARBON G DI · (2-ETHYLHEXYL) PHTHALATE SECTION II - HAZARDOUR INGREDIENTS INGREDIENT C.A.S. ~. PERCENT TLV SPECIFIC CHEMICAL IDENTITIES ARE BEING WITHHELD AS A TRADE SECRET. SECTION III - PHYSICAL DATA ~ ,~' PROPERTY MEASUREMENT BOILING POINT--(~ F) 284 VAPOR PRESSURE NOT DETERMINED VAPOR DENSITY NOT DETERMINED SPECIFIC GRAVITY 0.9300 PERCENT VOLATILES 21 · EVAPORATION RATE NOT DETERMINED SECTION IV - FIRE AND EXPLOSION DATA FLASH POINT (CLOSED CUP)' 164 EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL FOAM, REGULAR FOAM HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS: CARBON DIOXIDE, CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC. SPECIAL FIREFIGHTING PROCEDURES' SELF CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE PRESSURE.MODE. UNUSUAL FIRE & EXPLOSION HAZARDS: COMBUSTIBLE MATERIAL, BUT NO UNUSUAL HAZARDS ARE PRESENTED. SECTION V - HEALTH HAZARD DATA PERMISSIBLE EX.P.OSURE LEVEL: NONE ESTABLISHED EFFECTS OF OVEREXPOS~R[: FOR pRODUCTS EYES: CAN CAUSE SEVERE IRRITATION SKIN: CAN CAUSE SLIGHT IRRITATION WITH PROLONGED OR REPEATED CONTACT. BREATHING: EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL AND RESPIRATORY [RRITATIOH, DIZZINESS, WEAKNESS, FATIGUE, POSSIBLE UNCONSCIOUSNESS, AND EVEN ASPHYXIATION. SWALLOWING' CAN CAUSE GAS~ROINTESTI. NAL IRRITATION, NAUSEA, VOMITING, AND DIARRHEA. ASPIRATION OF MATERIAL INTO THE ~UNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. PLASTTCTZER ~J_ .... ~ SECTION V - HEALTH.HAZARD DATA (CONTINUED) FIRST AID IF'ON SKIN' THOROUGHLY WASH EXPOSED AR'EA WITH SOAP & WATER, REMOVE CONTAMINATED CLOTHING, LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH With COPIOUS AMOUNTS OF WATER, LIFTING UPPER & LOWER LIDS OCCASIONALLY, GET MEDICAL ATTENTION. iF SWALLOWED: DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET, & GEt MEDICAL ATTENTION.. ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNUEMONITIS WHICH CAN BE FATAL. IF BREATHED' IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM, QUIET 8 GET'MEDICAL ATTENTION. SECTION Y1 - REACTI.V~T¥ DATA HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITy: STABLE INCOMPATABILITY: AVOID CONTACT.WITH STRONG OXIDIZING AGENTS. SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL. LARGE SPILL: ELIMINATE ALL IGNITION SOURCES, PERSONS NOT WEARING PROTECTIVE -EQUIPMENT SHOULD BE'EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING PUMP LIOUID TO SALVAGE. TANK. REMAINING L'IOUID MAY BE TAKEN AND SHOVELED INTO CONTAINERS. WASTE DISPOSAL METHOD' CONTAMINATED ABSORBENT MAY BE OEPOSITED IN A LANDFILL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. DESTROY BY LIQUID INCINERATION. SECTION VIII - PROTECTIVE EQUIPMENT TO BE USED RESPIRATORY PROTECTION: IF TLr .OF THE PRODUCT OF ANY COMPONENT IS EXCEEDED. A NIOSH/OSHA APPROVED RESPIRATOR'Iq AhVT~Fh TN'ARqFNr~ OF PROPER ENVIRONMENTAL CONTROL. VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL VENTILATION TO MAINTAIN EXPOSURE BELOW TLr(S). PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS: NITRILE RUBBER EYE PROTECTION: CH.~MICAL SPLASH GOGG, LES IN COMPLIANCE WITH OSHA REGULATIONS ARE ADVISED' (CONSULT YOUR SAFETY EQUIPM~H~ SUPPLIER), OTHER PROTECTIVE EQUIPMENT'TO PREVEnt REPEATED OR PROLONGED SKiN CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS. SECTION IX - SPECIAL PRECAUTIONS OR OTHER COMMENTS ~-~FORMA~-~~TED HE~-IS BELIEVED TO B~ ACC4JRATE BUT IS NOT WARRANTED TO BE WHETHER ORIGinATED WITH LAIDLAW OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED 'THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCE~!J'. REVISED 1/15/86 ARTHUR L. BOYKIN ~'~ DATE PREPARED 10/85 '~,-: ~ P_A~'E-I No. 1-01800 .. .. MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairl. ng,.:shipbuildlng, and Shil3breaklng (29 CFR 1915, 1916, 19171 SECTION I MANUFACTURER'S NAME ~ EMERGENCY TELEPHONE NO. CALED SIGNAL CHEMICAL J 201 - 6~6-7575 ADDRESS .26 HANES DRIVE. WAYNE, N.J. 07470 -. CHF,~.llCAL NAME AND SYNONYMS ) TRADE NAME AND SYNONYMS MIXTU~(E -' I CWT CHEMICAL FAMILY .. ~ FOR~'vi, ULA AQUEOUS QUATERNARY SOLUTION' I MIXTURE SECTION II - HAZARDOUS INGREDIENTS INGREDIENTS CAS NUMBER % TLV. (Un,ts} Alkyl Dimethyl Benzylammonium Chloride (C8-C18) ND 4.5 NE Tributyl Tin Neodecanoate ND 2.5 N~ Alky~ Dimethyl Benzyl Ammonium Chloride (C12-C16) ND ,..- 2.25 NE Dimethyl Ethyl Ammonium Bromide ND .75 NE SPF_CIFICMATURE OF HAZARD/COMMF,NTS Registered as required by EPA. Product is not hazardous in normal use. Can cause eye irritation. SECTION III - PHYSICAL DATA Boiling Point (CF) 212 Specific Gravity (H.zO= 1) 1.0 ' Percent Volatile Vapor Pressure (mmHg.) ~ ' ' By Volume (%) ., 90 EvaDoration Rate ;,.. · ~:.: Vapor Density fAir · 11 ~ (Butyl' Ace -1i'-"' .': " Slower Solubility in W&tee' ~o~lp Le Ce Appea,anc, a.d OdD, ; 'Clemr. coi~rless liquid. No ad'Er ' ::' SECTION IV - FIRE AND EXPLOSION HAZARD DATA >210°F (Tag Closed Cup) ~ · EXTINGblSHING ~WaterlFo9 ~Foam ~Alcohol Foam ~Carbon DiDdle ~Orv Chemical ~Other MEDIA SPECIAL FIRE FIGHTI~JG PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZAHOS Non~ NAm NOt Applic,)ble ND = No Data Available NE = Not Established <,, Less Than ~= Greater Than " ' .... ~'~ SECTIONV - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE .' EFFECTSOF OVEREXPOSURE Skin and Eyes: Prolonged contact can cause irritation· Which may be severe. Ingestion: Probable mucosal damage and possible circulatory shock if large amounts ingested. Inhalation: Not a route of exposure. Mists. if inhaled would be similar to ingestion. , EMERGENCY AND FIRST AID PROCEDURES Eyes and Skin: Flush with water. Get medical attention. In~_estion: Drink large amounts of water, milk, egg whites,· or gelatin. Avoid alcohol. Call physician immediately. Note to physician: Mucosal damage may preclude gastric lauage. Treat for circulatory sh6ck, respiratory depression, aud convulsions as needed. SECTIONVI - REACTIVITY DATA CONOITIONSTO AVOID UNSTABLE' i~ , , STABILITY STABLE (~ None Known INCOMPATABILITY {MaterijIs to avo,d; O×idizinq a~ents HAZARDOUS DECOMPOSITION PRODUCTS Thermal: Carbon monoxide, ammonia, nitrous oxides, Hydrogen chloride. CONDITIONS TO AVOID MAY OCCUR [] .... HAZARDOUS POLYMERIZATION None Known WILL NOT OCCUR J~ SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED ORSPILi ['fO Flush with water and absorb with inert absorbant. " WASTE OISPOSALMETHOD. Sanitary land fill. Do not allow discharge into lakes, streams, ponds, .I or public waters. Comply with all Federal, State, and Local Regulations for chemical wastes. SECTION VIII · SPECIAL PROTECTION INFORMATION RESPIHAi'ORY PROTECTION ($~ec~/¥ rypel Not required in normal o.~eration .... . LOCAL EXHAUST SPECIAl.. . .. VENTILATION If mists are generated None MECHANICAL t(~tne~',~lJ O~TH. ER .47~-' ft.,'* - · ' '. Sufficient PROTECTIVE GLOVES ! EYE PROTECTION Rubber or ~lastic ! Goggles or face shields OTHER PROTECTIVE EQUIPMENT SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANOLING AND STORING GOOD INDUSTRIAL HYGEtNE SHOULD BE PRACTICED Do not store in steel or aluminum. Keep away from children. Do not freeze. Keep container closed. Avoid contact with skin and eyes. OTHERPRECAuTIONS Carefully read directions and warnings on labels. We believe the statements, tech,~ical information and recommendations contained herein a~e reliable, but given w'thO~l warranty or W~tI~ of any ki~. expte~ or ~mpiied. and we a~ume no re~onsibilty for any Ios~ dama~, or expend, dir~t or con~uental, ari~ng from cheer u~. Luidl w CoRpORATION 1212 EAST FIFTH STREET · METROPOLIS, ILLINOIS 62960 · (6 ! 8) 524-9394 SEPTEMBER 11, ].987 MR. RALPH E. HUEY HAZARDOUS HATE R I ALS COORD I NATOR ~ E ~-, E I ~ E II HAZARDOUS MATERIALS DIVISION SE~'1 j~ ~87 BAKERSFIELD FIRE DEPARTKENT 2130 "G" STREET ~'1~ ............ BAKERSFIELD, CALIFORNIA 93301 DEAR MR. HUEY, THE INFORMATION YOU REQUESTED CONCERNING LAIDLAW PRODUCTS IS A TRADE SECRET AND SHALL NOT BE DISCLOSED EXCEPT AS PROVIDED FOR IN CHAPTER 6.95, SECTION 25511 (D) 1,2. THE CHEMICAL BREAKDOWN FOR THE PRODUCTS IN QUESTION LIST ONLY THOSE ITEMS THAT ARE IDENTIFIED AS HAZARDOUS PURSUANT TO 29 CFR 1910. 1200 SUBPART Z; 40 CFR; NTP; ACGIH; AND IARC. LAIDLAW SPRAY SIZING SODIUM TETRABORATE DECAHYDRATE 3% PROPELLENT 5 % NON-HAZARDOUS I.NGREDI ENTS 92% LAIDLAW PLASTICIZER MINERAL SPIRITS 21% DI.OCTYL PHTHALATE 79% LAIDLAW RAPID SPOT REMOVER BACTERIAL PROTEASE SUBTILISIN 29% SODIUM PHOSPHATE, DIBASIC 32% NON-HAZARDOUS I NGREDI ENTS 39% I TRUST THAT THIS INFORMATION IS SUFFICIENT FOR YOUR EVALUATION. IF YOU HAVE ANY QUESTIONS, PLEASE LET ME KNOW. SINCERELY, CHEMICAL PRODUCT MANAGER LABO'R~ " U.S. DEPARTMENT OF OMB No. 44-R1387 Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET JANUARY 1987 · Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, ~nd Shipbreaking (29 CFR i915, 1916, 1917) INDCO SECTION I ~110 MANUEACTURER'S NAME I EMERGENC~ TELEPHONE ND. INDUSTRIAL CORPORATION I (415) 822-5070 ADDRF..~S [Number, Street, City, State, and ZIP Code) 2655 Tn~alls Street ,qan Fr~n~.~.~, PA qa] ?a CHEMICAL NAME AND SYNONYMS ' I TRADE NAME AND SYNONYMS Sodium Metas~] ~cat~/,qo~um Phosphate. I Aluminum H.T. C]ean~r CHEMICAL FAMILY -- Mixture / FORMULA . SECTION II - HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES, & SOLVENTS % ] TLV TLV (Unitl) ALLOYS AND METALLIC COATINGS % IUnit~) PIGMENT5 N/A BASE M~'TAI. C,~TALYST N/A ALLOYS N/A VEHICLE N/A METALLIC COATINGS N/A FILLER METAL SOLVENTS N/A PLUS COATING OR CORE FLUX N/A ADDITIVES N/A OTHERS N/A OTHERS N/A TLV · C.A. S. # HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % (UAitd 6834-92-0 Sodium Metas~l~c~t~ 45 N/A 533-96-0 Sod~ um Se~qu~ carbon~t~ ?0 N/A 7758-29-4 Sodium Tripoly Phosphate 30 N/A N/A Nor[y1 phenox~ypo] y (R~.~y] ~.n~nwy) P.~hann] 5 ~/A SECTION III - PHYSICAL DATA COILING POINT (oF'.) N/A SPECIFIC GRAVITY (H20=l) N/~ pERCENT, VOLATILE VAPOR PRESSURE (mm H9.} N/:A BY VOLUME (%) '..EVAPORATION RATE VAPOR DENSITY [AIR=!J N/A ( .... "[) .... N/A ~43LUalLITY IN WATER Complete ~PE~kRANCEAND ODOR White qranules, odorless. SECTION IV - FIRE AND EXPLOSION HAZARD DATA N/A ~ / EXTINGUISHING MEDIA. N/A ~EClAE FIRE FIGHTING PROCEDURES None. UNUSUAL FIRE AND EXPLOSION HAZARDS Non~ PAGE (1) (Continued on reverse side! Form OSHA-20 R~. M~¥ ~ ROUTE OF ENTRY: INGESTIO~ NOT A INGEN SECTION V - HEALTH HAZARD'DATA THRF--SHOLD LIMIT VALUE N/A EFFECTS OF OVEREXeOSU RE Dust may cause irratation of eyes and irritation of nose and throat. Repeated contact may cause redness and dry craked skin. EMERGENCY AND FIRST AID PROCEDURES RYR/SKTN: T~d~at~]y flush wth plenty of w~t~r for at ]~ast 15 m~n. for eyes, call a physican. INGESTION: Do not enduce vomiting. Give large quantities o~ water. ~ve at least I ounce vinegar ~n equal SECTION VI - REACTIVITY DATA ~TBILITY C~DITIONS TO AVOID UNSTABLE sTABLE X N / A INCOMPATABILI~ (Marcels to avoid) Acids ': ~ZAROQU~ DECOMPOSITION PRODUCTS None --COHDITIOHS-TO-~VO ID ~ ~zaaoous MA~ OCCU. Fla~ab. le Hydroqen Gas may'be~O- ~LYMERIZATION duCed on reacts .with acids, prolo~ed w~uu ~OT OCCUR X c~Lac. L wiLh alu.,inum, Lin, lard, ~nd zinc. SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL I$ RELEASED OR SPILLED Sweep, scoop, or vacuum spill. Neutralizing agent: Acetic Acid. W~TEOISPOSALMETHOO Preferred manner of disposal is in secured, landfill in accordance with local environmental regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION [Specify type) NIOSH dust respi'rator-' LOCAL EXHAUST SPECIAL VEJ~TI[~kTION General room dilution or local N/A ME.CH LNICAL (General/exhaust ven~ila~mn -N./-A PROTECTIVE GLOVES I EYE PROTECTION Rubber I Goggles OTHER PROTECTIVE EQUIPMENT Full c~ver clothing. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING DO not store near acids. 'Keep dry. OTHER PRECAUTIONS Wash. after use. PAGE (2! Form OSHA-20 GI'O ~:10.S40 Reqf. Mil, 7,1 AREA CODE 805 · PH. 324-9414 1021 EIGHTH STREET · BAKERSFIELD, CALIFORNIA 93304 RECEIVED NOV 3 1987 October 29, 1987 Ans0d ............. Bakersfield Fire Department Hazadous Material .Division 2130 "G" Street Bakersfield, California 93301 To Whc~ It May Concern, I am forwarding to your department copies of material safety data sheets for new chemicals we are using. In addition there are a few material safety data sheets that we just received for chemicals we have been using for sc~e time. The suppliers have been slow in passing this information on to us. Sincerely, Jarrell L. Epp Enclosed; Material Safety Data Sheets J~S/ams SECTION V - HEALTH HAZARD DATA ~.~LD LIHI[ VALU~ 25 PPM on a t[me-we/qnted averaoe b~s[s. See Title 8, sec. 51~5. L/quid couses ~evere burns, yopor extremely [rritat[nq. Soo section 8 Nanufactur[nq Chemists Associot ion Chemicol Dote Sheet SD-i3. Inhalation: Remove to fre,~h air. apDly artific[ol ro,~pirqtion, Got m~ical attention. Eye contact: Flush with ~'ater for at least 15 min~tos, Get ~ical attention. Skin contact: Flush ~ith water. SECTION VI - REACTIVITY DATA ' ~oLl[~s I0 wILL t~T ~R · X * SECTION Vii - SPILL OR LEAK PROCEDURES $1}.~ ~'O F~ TAXEN JN C. kSE I~ATER[AL [$ I~ELEA'iED OF{ SPILLED Fl(:.sh '~it/t .olenty n? wo]Zer. SECTION VIII- SPECIAL PROTECTION INFORMATION f~l"-Pi~IArOk'"r PI~ECTIGt4 (S,~ecity ~y~) C,hem/cal ccrtr/d~e respiratnr, cann/s?er mn,~+ .s~lf-r:nnt~in~ k~t ~UST SF~CIAL ~ ~Jct~ ~EO~I~L (~nornl) OB~R 'SECTION IX - SPECIAL PRECAUTIONS P.~£~r tn MqcrP'n~f':,'/n3 F'h,~n/.~'t.~ zl.~,nn. Ch~.m. S~Y~y £?~ta Shoot SD-I~. January 22, 19~, , /q WILLARD PRODUCTS P.O. 80X 249 a 70 CHEMICAL WAY · REOWOO0 CI~. CA g4064 a .{435~ 365-3300 Corrosive MATERIAL SAFETY DATA SHEET' · Iflformition on th~l form is lurnilhed tolely for the purpose of COmDliance w,th lhe OccuPational Safely end Health .... SECTION I '. ~SS (~r, S~r~t, City, Stnre, a~. ZZP ~e) ' 8ECTI~;II - HAZARDOUS INGREDIENTS '- TLV · ALLOYS AND METALLIC COATING~ PAI~, PRESERVA~VES, & ~OLVENT~ %' (Unil~) PlaNTS BA~ ~TAL ~TALYST ;~ ' ALLOYS . - ~EH[~E " ~TALL[C FILLER ~TAL ~L~NTS PLUS ~AT[~ OR ~. FL~ ' '0~ ......... "" '" ' ......~ . . TLV HA~RQOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, O~ GASES % (Units) SECTION ill - PHYSICAL DATA I~gILING POINT ('F) (~.~ ~'~O-- $1'ECIFIC GRAVITY (H20-1) VA~R ~SS~ (~) ~NT ~LATILE 7~mm dOOF ~.Tp~/~ [w VOL~ (~ __~ VA~R ~NSJ~ (AIR-I) .--. ~VAm~rl~ ~fE SECTION IV - FIRE AND EXPLOSION HAZARD DATA' ' None Ammon fa va~r · 1 Non-f/ammab/e u~Yer usual CO~[t [on~. Fnr ff[re~ [nvolv[n~ thJ~ m~fe~[~l, do not [.'~te~ without proper protect ive equipment. ~ fl~ ~ EXPLOSI~ ~o~e . MCKESSON CtlEMICAL COMPANY ONE POST STREET SAN FPJtNCISCO, CA 94104 E"MERGENCY ASSISTANCE FOR EMERGENCY ASSISTANCE INVOLVING CHEMICALS CALL CHEMTREC (800) 424-9800. FOR PRODUCT AND SALES INFOI~fATION CONTACT YOUR LOCAL MCKESSON CtlEMICAL COMPANY SERVICE CENTER 'L PRODUCT IDENTIFICATION .) :"D PRODUCT ME: SODIUM BISULFITE CAS NO.: MIXTURE COMMON NAMES/SYNONYMS: SODIUM ACID MCKESSON CODE: T1856 SULFITE;.SODIUM HYDROGEN SULFITE FORMULA: MIXTURE DATE ISSUED: 02/86 HAZARD RATING (NFPA 704) SUPERCEDES: 11/85 HEALTH: 2 HAZARD RATING SCALE: FIRE: 0 O=MINIMAL 8=SERIOUS REACTIVITY: 0 I=SLIGHT 4=SEVERE SPECIAL: NONE 2=MODERATE HAZARDOUS INGREDIENTS EXPOSURE LIMITS, PPM OSHA ACGIH OTHER COMPONENT % PEL TLV LIMIT HAZARD NA H S 03 UNKNOWN NONE 1 NONE IRRITANT NA2 S2 05 UNKNOWN NONE 1 NONE IRRITANT PHYSICAL PROPERTIES BOILING POINT, DEG F: N/A VAPOR PRESSURE, MM HG/20 DEG C: N/G MELTING POINT, DEG F: >'802 DECOMPOSES VAPOR DENSITY (AIR=l): N/G SPECIFIC GRAVITY (WATER=l): 1.48 WATER SOLUBILITY, %: 100 -'~=.j - APPEARANCE AND.ODOR: COARSE ........ EVAPORAT-ION.-RATE (BUTYL ACETATE=I):_N/G .......... · WHITE GRANULES; ODOR OF SULFUR DIOXIDE FIRST AID MEASURES :- '.. I l' .::.:i~ <~'.i,?,.5~'~.> ..<...i?--),' ~".~ .:.~.::~:!?ii.~!75,:<<,~.<-~....... ....... . ~ .'... : ...... --...~-'~'v-'... ,~ '..-<,~ · .'.' .... h' :'. '~.' !' ....~ .:.>...' 7 .i' :<' "" """ .' ..."' '.,. ';'< i'<~.<>ii>i.}i:i;!'- i.'SO~i~.i ~i~L~i'~ ~'"..}".i'; "i'. '.' J )~.>,-' '-.: "'''/""i""'"'<' "'. '>-' "'' .'i' REVIsION.oF}' 021i4/86 ?.:'.' ';'i N ;<:;'mmov :TO!'F Sa GIVE ARTIFICIAL SPI TION IF' ~ ~ gREgTHING;'~ET-I~EDIA~ MEDICAL A~NTION. · ' : · .' · : .2........ ,.'. .. .- - , '. .~ ..,[ . ',.'... : .... . ..'.-':'}."' "IN CASE OF. EYE CONTACT:' I~EDIATELY FLUSH EYES WI~ LOTS OF RUNNING · ::.-'~.-.<.' ~A~R FOR 15.MINUTES, LIFTING ~E UPPER AND LOWER EYELIDS OCCASIONALLY. GET I~EOlAI~ MEDIClL A~ENTION. '.?.(:~.~;:.'/-:'.,..":,.:'...,'.' .... ..::~.~.:;~>.:',."..:.>.'.,.'-.........-.,... .... - .....:,. ...... :~ ,~ ::~.. "' IN CtSE OF SKIN'CONTACT: I~EDIATELY WASH SKIN ~ITH LOTS OF SOAP AND 'WATER. R~OVE CONTAMINATED CLOTHING AND SIlOESI ~tSH BEFORE REUSE. GET ~OlCtL A~ENTION IF IRRITATION PERSISTS AFTER WISHING. IF ~ALLO~ED: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE LOTS OF WATER OR MILK. GET I~EDIATE MEDICAL ATTENTION. DO NOT GIVE ANYTHING BY · '.'".:..";.'.<. MOUTH TO AN UNCONSCIOUS OR CONVULSING PE~ON. .'. HEAL~I HAZARD PRIMARY ROU~S OF EXPOSURE: SKIN OR EIE CONTACT, INFLATION.' SIGNS t~D S~PTOMS OF EXPOSURE INfLaTION: BREATHING DUST MAY IRRITATE THE NOSE AND TIIROAT AND LUNGS. E~E CO~TACT~ DUSTS M~ IRRITATE T~E E~ES CAUSING REDNESS t~D P~IN. SKIN CONTACT: CONCENTRATED SOLUTIONS MAY BE IRRITATING TO THE SKIN. ~ALLOWED: ~ALLO~ING ~E LIQUI9 WIL CAUSE IRRITATION OF THE MOUTH, ESOPHAGUS AND STOMACH, RESULTING IN NAUSEA, VOMITING, HEADACHE AND ABDOMINAL PAIN. LARGE DOSES MAY BE FATAL. CHRONIC EFFECTS OF EXPOSURE: NO SPECIFIC INFO~A~ION AVAILabLE. MEDICAL CONDITIONS GENERALLY AGGRAVA~D BY EXPOSURE: SOME INDIVIDUALS ARE EXTR~L~ SENSITIVE TO MINUTE AMOUNTS OF INGESTED SULFIDES. SYMP- TOMS ~I INCLUDE BRONCHO CONSTRICTION, SIIOCK, GiSmO-INTESTINAL DISTUR- BANCES, ANGLO EDEMA, FLUSIIING, AND ~IN~LIN~ SENSATIONS. TOXICI~ O~L: .~T-LDSO = 2 G/KG DE~AL: NO DATA FOUND INFLATION: NO DITA FOUND CARCINOGENICITY: ~IS MATERIAL IS NOT CONSIDERED TO ~E i CARCINOGEN BY ~E NATIONAL TOXICOLOGY PROGRAM, THE IN~RNATIONAL AGENCY FOR RESEARCH ON CANCER, OR THE OCCUPATIONAL SAFE~ AND ~ALTH ADMINISTRATION OT~R DAT~: THIS M~TERIAL HAS BEEN FOUND TO BE EXPERI~NTALL~ M~TgGENIC PERSONAL PROTECTION " J I' ,' '.¢i O':'i.":'i"."VENTILATiON':''': LOCAL MECItANICAL ExHAUs~ VENTILATION'CAPABLE OF MINIMIZING":'::'.' "" .) :?.:,.'i~: '~ .:'..RESPIRATORY PROTECTION: NIOSH-APPROVED"DUST RESPIRATOR OR MASK IN T~ ================= ==== =: :. : . .'ABSENCE OF ADEQUATE ENVIRO~ENTAL CONTROLS ~T TIlE POINT OF ~SE. .. EYE PROTECTION: CHEMICAL GOGGLES AND HAR~ ~AT. ~. PROACTIVE CLO~ING: LONG-SLEEVED SIIIRT, TROUSERS, SAFE~ SHOES, . RESISTANT GLOVES AND ~CID-RESISTg~T gPRON. OTHER PROACTIVE MEASURES: ~N EYEWASH AN~ SAFETY StlOWER SHOULD gE · . NEARBY AND ~ADY FOR ~SE. -:.. ' · FIRE ~N~ EXPLOSION INFO~ATION FLASH POINT, DEG F~ NOT FLA~AgLE FLYABLE LIMITS IN ~IR, METHOD ~SE~: N/A LO~ER: N/A ~PPER: N/~ EXTINGUISHING~DXA: USE ANY APPROPRIATE ME~I~ FOR EXTINGUISHIN~ SURROUNDING FIRES. SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SHOULD WE~R SELF- CONTAINED BREATHING APPARATUS. USE WATER SPRAY TO COOL ~NUSUAL FIRE'fiND EXPLOSION HAZARDS: EXTINGUISH fiLL NEARB~ SOURCES OF IGNITION SINCE VAPORS DECOMPOSE TO TOXIC PRO~CTS AT tIIOB TEMPERATURES. HAZARDOUS REACTIVIT~ STABILI~: STRENGTH DIMINISHES SOMEWHAT WI~ AGE. GRADUALLY DECOMPOSES IN AIR TO S~LF~TE, GENERATING SULFUROUS fiCI~ POLYMERIZATION: ~ILL NOT OCCUR. ~ONDIIIONS TO AVOid: AIR, ~EAT (ABOVE 221DEG F). MATERIALS TO AVOID: ACI~S, OXIDIZING MATERIALS, ALUMINSM, WATER. B~ZgRDOUS DECOMPOSITION PRODUCTS: WILL LIBERATE OXIDES OF SULFUR AND SPILL, LEAK, ~ND DISPOSAL PROCEDURES ~ClIO~ I0 TAKE FOR SPILLS OR LEAKSt WEAR PROACTIVE E~UIPMENI ..... R~BBER BOOTS, RUBBER GLOVES, RUBBER ~PRON,.CII~ICAL GOGGLES, ~ND RESPIR- ~IOR~ PROTECTION. FOR SMALL SPILLS, SWEEP UP AND ~ISpOsE OF IN'DOT-' APPROVED W~S~ CONTAINERS. FOR LARGE SPILLS, SHOVEL INTO DOT-APPROVED was co az ns. CO PL WI n aLL a PLZCanL COVEn E aL- ECULA -ZO S .................. ON SPILL REPORTING, gN~ HANDLING AND DISPOSAL OF ~ASTE. -- DISPOSAL ME,ODS:' DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS ~SED ".'.'::i':'~,~ -:::"'i::'.:i~:. '":'.~'.'i':': :~.'i',":' "?""-..: -"~':: :'i:':'.. · ': ..... .? :-~... ....: .'. -:.'- -' '-: '. 1.' ..-~:"" '.'?-'":,-~':"~:",'-.":'¥:-:::".-: "?":....- '"-" :":--.":.: "'"'.~'. .'J '-...:'.': .:.i:..'. SODIUM .BiSULFiTE' :-.:.' ..?.'!.:". :..'.': ' ...". '.:. !':.!-:.... i~EViSiON'-OF~ CONSULT'APPROPRIATE FEDERAL, STATE AND LOCAL REGULATOR¥..AGENCIES TO. ~' ' '. '.. -' ""'-':- .':-~'. ASCERTAIN-pROPER DISPOSAL PROCEDURES.' ' ' ' .. '' ' ' "- ' "'""/'"'-.'i: ..... ' .... · NOTE:' EMPTM CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS"~ND ARE .- · ii'..~.'.....SUBJECT TO PROPER WASTE. DISPOSAL, AS ABOVE. .. '.: SPECIAL PRECAUTIONS ' ~ STORAGE AND HANDLING PRECAUTIONS: STORE'IN A COOL, DRY, WELL-VENTILATED PLACE. KEEP BAGS DRY AT ALL TIMES. WASH THOROUGIILY AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTtlING. REPAIR AND MAINTENANCE PRECAUTIONS: NONE. OTHER PRECAUTIONS: CONTAINERS, EVEN TIIOSE TIIAT HAVE BEEN EMPTIED, WILL " RETAIN-PRODUCT RESIDUE AND VAPORS.. ALWAYS.OBEYHAZARD WARNINGS AND'-. HANDLE EMPTY CONTAINERS AS IF THEY WERE FULL. FOR ADDITIONAL INFOrmATION CONTACT DOUGLAS EISNER, TECHNICAL DIRECTOR, MCKESSON CHEMICAL COMPANY DURING BUSINESS HOURS, PACIFIC TIME (415)958-9214 NOTICE . ALL INFORMATION, RECOmENDATIONS, AND SUGGESTIONS APPEARING HEREIN ~ CONCERNING THIS pRODUCT ARE BASED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECHNICAL SOURCES; HOWEVER, MCKESSON CHEMICAL COMPANY ("MCC") MAKES NO WARRANTY, REPRESENTATION OR GUARANTY AS TO THE ACCURACY, SUFFICIENCY. OR COMPLETENESS OF THE MATERIAL SET FORTH HEREIN. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SAFETY, TOXICITY AND SUITABILITY OF HIS OWN USE, HANDLING AND DISPOSAL OF THE PRODUCT. ADDITIONAL PRODUCT LITERATURE MAY BE AVAILABLE UPON REQUEST. SINCE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE BY MCC AS TO THE EFFECTS OF SUCH USE, THE RESULTS TO BE OBTAINED OR THE SAFETY AND TOXICITY OF THE PRODUCT, NOR DOES MCC ASSUME ANY LIABILITY ARISING OUT OF USE BY OTHERS OF THE PRODUCT REFERRED TO HEREIN. THE DATA IN THIS MSDS RELATE ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DO NOT RELATE TO USE IN COMBINATION WITH ANY OTIIER MATERIAL OR IN ANY PROCESS. REVISION 0000002 02/86: REVISED FIRST AID MEASURES. · ********* END OF MSDS · ..'..: ~.':..: ~-."'"':.:'.'-7.t~ ~. i "...-. ": :':.,::'.".-.i: . 'i ').:.... ,':'..;......-.- -... · ' ~ ',· ..' ..... "..-.: ... - '.,'.. :'..': :. '-. -'.'-2 · ." :-' .'. . MCKESSON CHEMICAL COMPANY .. '.. BAKERSFIELD WAREHOUSE '. .. ...., ..:.-:'.'. . . :)' :. · ! '.'..-."":' .. ',.. '.:, .. '.[ . . .... .... ._.~... .....' .- . . ::.'. :...'-:, . ~ ': 2983 16TH STREET ' BAKERSFIELD CA 93301 MCKESSON CHEMICAL COMPANY ONE POST STREET SAN FRANCISCO, CA 94104 EMERGENCY ASSISTANCE FOR EMERGENCY ASSISTANCE INVOLVING .CHEMICALS CALL CHEMTREC (800) 424-9300. FOR PRODUCT AND SALES INFORMATION CONTACT YOUR LOCAL MCKESSON CIlEMICAL COMPANY SERVICE CENTER PRODUCT IDENTIFICATION PRODUCT NAME: SODIUM HYDROSULFITE CAS NO.: 7775-14-6 COMMON NAMES/SYNONYMS: SODIUM DITHIONITE; MCKESSON CODE: Tll61 DITHIONOUS ACID, DISODIUM SALT; SODIUM SULFOXYLATE FORMULA: NA2 S2 04 DATE ISSUED: 02/86 ItAZARD-RATING (NFPA 704) SUPERCEDES: 11/85 HEALTH: 2 HAZARD RATING SCALE: FIRE: 8 O=MINIMAL 3=SERIOUS REACTIVITY: 2 I=SLIGHT 4=SEVERE SPECIAL: NO WATER 2=MODERATE HAZARDOUS INGREDIENTS EXPOSURE LIMITS, MG/M8 OSHA ACGIH OTHER COMPONENT % PEL TLV LIMIT HAZARD SODIUM HYDROSULFITE 85-90 NONE 10 NONE FLAMMABLE; IRRITANT PHYSICAL PROPERTIES BOILING POINT, DEG F: N/A VAPOR PRESSURE, MM HG/20 DEG C: N/A MELTING POINT, DEG F: 130 (DECOMPOSES) VAPOR DENSITY (AIR=l): N/A SPECIFIC GRAVITY (WATER=l): 2.2 WATER SOLUBILITY, %: 18 APPEARANCE AND ODOR: EVAPORATION RATE (BUTYL ACETATE=l): N/A WHITE TO GRAY WHITE CRYSTALLENE POWDER; SLIGIIT ODOR OF SULFUR DIOXIDE BREATHING. GET i~EDIATE MEDICAL ATTENTION. . "" IN CASE OF EYE CONTACT: IMMEDIATELY FLUSH E~ES WIT~ LOTS OF R~NI~C 'WATER FOR 15 MINUTES, LIFTING ~HE ~PPER AN~ LO~ER E~ELIDS OCCASIONALLY. IN CASE OF SKIN CONTACT; I~EDIATEL~ ~AS~ SKIN WITH LOTS OF SO~P AND · ~R. REMOVE CONTAMINATED CLOTHING AN~ StIOES; WASH BEFORE REUSE. GET MEDICAL ~E~TIO~ IF IRRIT~TIO~ PERSISTS AFTER IF ~ALLOWE~; DO ~OT INDUCE ~O~ITI~. IF CONSCIOUS, ~IVE LOTS OF SOAP~ '"'" WATER, MILK OR MILK OF ~GNESIA. GET I~E~I~ MEDICAL NOT GIVE h~THI~ B~ MO~T~ TO ~ ~NCONSClOUS OR CO~V~LSI~ PERSON. IIEALTH HAZARD I~FO~TIO~ PRIMAR~ ROUTES OF EXPOSURE; SKIN OR E~E CONTACT SIGNS AN~ S~MP~OMS OF EEPOS~RE INHALATION; ~UST ~AY IRRITATE THE NOSE, THROAT AND.RESPIRATOR~ TRACT. E~E CONTACT; D~STS WILL IRRITATE THE E~ES AN~ PROLONGED CONTACT MA~ BURN T~E E~ES. SKI~ CONTACT; CONTACT WIT~ SKIN M~ C~SE IRRITaTIOn. PROLONGED IRRIThTION MA~ C~SE SWALLOWED; ~ALLOWING T~E ~USTS OR SOLIDS M~I C~SE IRRIT~TIO~ B~RNS OF MOUTH, THROAT fiND MUCOUS MEMBRANES OF THE GASTROINTESTINAL TRACT, NAUSEA AND VOMITING. CHRONIC EFFECTS OF EXPOSURE' NO SPECIFIC INFO~ATION MEDICAL CONDITIONS GENERfiLL~ AGGRAVATED B~ EXPOSURE: NONE KNOWN. , TOXICIH DATA ORAL: NO DATA FOUND DE~AL: NO DATA FOUND iNHALATION: NO DATA FOUND CfiRCINOGENICI~: THIS MATERIAL IS NOT CONSIDERED TO BE fi CARCINOGEN B~ THE NATIONAL TOXICOLOG~ PROGRAM, THE INTERNATIONAL AGENC~ FOR RESEARCH ON CANCER, OR THE OCCUPATIONAL SAFETY fiND HEALTH fiDMINIST~TION PERSO~gL PROTECTION :~;~C:'~.:'~..'~.''.. "!ii.!:~?.':.'.'-i.~ :':-i::./.i!~ ~ ... :... ~: ;...:~... ..,-, .. ~.' ....... .-.' ~.-...': :', :...-'. :- :::~' ;-,,':'~ ','. ¥ :'..:~ _. .: '.. SODII~'I~DR'OsuLFITE'i'" "'' '" ' " · :. "-" REVisioN OF'~ 02/14/86' ' '~: i-i""~.~'i.~'.:'!'..':-':-:'.,.'i~.'..~,...-'i'-'''. '. :: -:'.:~ .': ..' ,.' i ., -'-:' .;...i'., ."..: ~" ...: .'.'i.-:'-".';: .' -' "" '. :"'~"::.':.":VE~TI~AiI~N: 'LoCAL':MECl~NICAL EXHAUS~ VENTILATION CAPABLE-'OF MINIMIZING'. -" DUST I~fISSIONS!AT.THE POINT OF USE, : .... RESPIrATORY.PROTECTION':' NIOSH-APPROVED DUST RESPInTOR OR VaSK.'.. E~E PRO~CTION:' CHEMICgL GOGGLES; PROaCtIVE CLOTHING:` LONG-SLEEVED SHIRT, TROUSERS, RUBBER BOOTS, RUBBER GLOVES, AND RUEBER APRON. OT~R PROACTIVE MEASURES: ~N E~EWASH AND SAFE~ SIIOWER SHOULD BE NEARB~ AND READ~ FOR USE. FIRE AND EXPLOSION INFO~ATION FL~SH POINT, DEC F: N/A FLA~ABLE LIMITS IN AIR, g METHOD USED: N/A LOWER: N/A UPPER: EXTINGUISHING MEDIA: FLOOD WITH WATER.' SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS SIIOULD WEAR SELF~ ~ CONTAINED BREATtlING APPARATUS AND GLOVES COATED WITH FABRIC OR RUBBER. USE WATER SPRA~ TO COOL NEARBY CONTAINERS ~ND STRUCTURES EXPOSED TO FIRE. UNUSUAL.FIRE AND EXPLOSION HAZARDS: MATERIAL CAN SPONTANEOUSL~ COMBUST. .. ~LL ~OO~S OF WATER OR CO~TACT WiTH n~CUL~ UO~I~ AIR CA~ CA~SE A ~I~E ) OR IGNITE NEARBY COMBUSTIBLE ~TERIALS. HAZARDOUS REACTIVIT~ STABILITY: STABLE POLYMERIZATION: ~ILL NOT OCCUR CONDITIONS TO AVOID:. MOISTURE, TEMPERATURES ABOVE 112 DEC F MATERIALS TO AVOID: ACIDS, OXIDIZING MA~RIALS, HOT ~ATER, soDIuM CHLORITE HAZARDOUS DECOMPOSITION PRODUCTS: WILLL LIBE~TE SULFUR DIOXIDE AND NA20. SPILL, LEAK, AND DISPOSAL PROCEDURES ACTION TO ~A~ FOR SPILLS OR LEAKS: ~AR PROACTIVE E~UIPMENT INCLUDING RUBBER BOOTS, RUBBER GLOVES, RUBBER APRON, AND CHEMICAL GOGGLES. COVER WITH SODA ASH OR LIME. FOR SMALL SPILLS, S~EEP UP AND DISPOSE OF IN DOT-APPROVED WASTE CONTAINERS. FOR LARGE SPILLS, SHOVEL INTO DOT- APPROVED ~ASTE CONTAINERS. COMPLY WITH ALL APPLICABLE GOVE~ENTAL REGULATIONS ON SPILL REPORTING, AND HANDLING AND DISPOSAL OF DISPOSAL METIIODS: DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEA~ING UP SPILLS OR LEAKS IN A MANNER APPROVED FOR THIS MA~RIAL. CONSULT AppROPRIATE FEDERAL, STATE A~D~LOCAL ~GULATORY"AGENCIES-TO ASCERTAIN PROPER DISPOSAL PROCEDURES. ~ NOTE: EMPT~ CONTAINERS CAN HAVE RESIDUES, GASES AND MISTS AND ARE SUBJECT TO PROPER WASTE DISPOSAL, AS ABOVE. I !?('.'i':.,.')'.'!".SoDiUM HyDROSuLFIiE'' "...'.j '.:.-..- .... .'. :.:' .'...:,--.!'..: 'REvlsiON'..oFi'02/i~80.'i..'.',' - ' ~iil i'. · :~'' :i . "i:. ': ;-: ~'.- ~.-'"~'~' ..... - .... '._. SPECIAL' PRECAUTIONS .:' . ~ .. ... .... :,:..". ~ :-- ...... · ;-.- STORAGE AND HANDLING PRECAUTIONS; STORE IN A COOL, DRY PLACE..'STORE '!/: '..'.'"' AWAY FROM OXIDIZING CHEMICALS AND ACIDS. KEEP CONTAINER TIGHTLY CLOSED .: , '":' WHEN NOT IN'USE. DO NOT USE'PRESSURE TO EMPTY CONTAINER.- WASH THOROUGHLY. AFTER HANDLING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. :-~ .... ': .... 'REPAIR 'AND MAINTENANCE PRECAUTIONS: "NONE. '" ''' '"' .... '-:'" O~IER PRECAUTIONS; CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT RESIDUE AND VAPORS. AL~A¥S OBEY HAZARD WARNINGS AND HANDLE EMPI~ CONTAINERS AS IF THEY WERE FULL. FOR ADDITIONAL INFOPJvfATION CONTACT DOUGLAS EISNER, TECIINICAL DIRECTOR, MCKESSON CtlEMICAL COMPANY DURING BUSINESS HOURS, PACIFIC TIME (41§)988-9214 NOTICE ALL INFORMATION, RECOMMENDATIONS, AND SUGGESTIONS APPEARING HEREIN CONCERNING TItIS PRODUCT ARE BASED UPON DATA OBTAINED FROM THE MANUFACTURER AND/OR RECOGNIZED TECIINICAL SOURCES; HOWEVER, MCKESSON CHEMICAL COMPANY ("MCC") MAKES NO WARRANTY, REPRESENTATION OR GUARANTY AS TO THE ACCURACY, SUFFICIENCY OR COMPLETENESS OF TIIEMATERIAL.SET .) FORTH HEREIN. IT IS USER'S RESPONSIBILITY TO DHTE INE THE SAFEU, . TOXICIT~ AND SUITABILITY OF HIS OWN USE, HANDLING AND DISPOSAL OF TtIE PRODUCT. ADDITIONAL PRODUCT LITERATURE MAY BE AVAILABLE UPON REQUEST. SINCE ACTUAL USE BY OTHERS IS BEYOND OUR CONTROL, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE BY MCC AS TO THE EFFECTS OF SUCH USE, THE RESULTS TO BE OBTAINED OR THE SAFETY AND TOXICITY OF THE PRODUCT, NOR DOES MCC ASSUME ANY LIABILITY ARISINO OUT OF USE BY OTHERS OF THE PRODUCT REFERRED TO HEREIN. THE DATA IN THIS MSDS RELATE ONLY TO TtlE SPECIFIC MATERIAL DESIGNATED HEREIN AND DO NOT RELATE TO USE IN COMBINATION WITH'- ANY OTHER MATERIAL OR IN ANY PROCESS. REVISION 0000002 02/86; REVISED FIRST AID MEASURES. · ********* END OF MSDs '.<. L'LFAP, iN',LN1 OF L=EOR -MATERIAL SAFETY DATA SHEET Requir~ under USDL Safety and HEalth RegJlallons for Ship Repairing. NOT OSHA Shipbuilding, ~nd $hipbreekin9 {29 CFR 1915, 1916. 1917) ~ZA~O~S SECTION I ~,ANUFACTUR~R'5 N~[ [ [MERG[NC~ T[L[PNONE NO. ROYACTOHS C~C~, CO., IHt. 1 918-663-~666 ~C'., -~uzsa, u~ 75145 'Hydrocarbon Emulsion - C~EMICA~ FAMILY . ~qu~ ~ dr~uls ion Aqueous HydrocarBon: ~ o~ ' SECIION II . HAZARDOUS INGREDIENTS ~AINTS. ~RES[RVA~IVES. & '~LVENTS TLV TLV CATALYST ALLOYS VEHICLE METALLIC COATINGS FILLER METAL SOLVENTS PLUS COATING OR CORE FLUX ADDITIVES' OT~ER$ TLV HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLID~, OR GASES ~is product does not contain any hazardous mat.erials based ~n current Department of Labor' Re~ula'tion~ as we interpret th~m. SECTION I!1 - PHYSICAL DATA BOILING I~OINT {'F.) . . 212° sp£c,F,c :RAy,Tv ,-,o-l) O. 94 ' pi RC[NT, VOLA'r,LE vA.oe .cENsoR[ (,~ HE.) H20 aY VOLUME (%) NA EVAPORATION RATE ~20 · VAPOR DENSITY (Ale=l) ~2o ( .1) ... SOLUBILITY IN WATER ~es ...**...Lt..Dodo. '~ite l~quid, m~ld no-residual odor. ,~,..o,~?,.,,.~..., .380o c~c i'~*'~'~'''''' 1. ~' ! ~' [x?,N~u,S.,NG --EO,A water Fog $PECIAL FIRE ~IGHTING PROCEDURES , UNUSUAL FIRE AND EXPLOSION HAZARDS None PAGE {1) ' (Continued on revere side} Form OSHA~.20 ~ECTION V - HEALTH HAZARD ~FF~CT~ O~ OVErexPOSUrE JOJg Skin and eves- flush with water Ingestion- Seek medical attention. SECT~ONV! - REACTIVITYOATA STABILITY COe~OlrlON$ TO AVO,O ua STA SeE Non e HAZ~ROOU~,O~O~POSITION,. PROOuCTS NO~ ~ONOI~IONS TO AVOID NAZA~OOU~ MAY OCCUR ~LYMERIZATION WILL NOT OCCUR ~ SECTION VII - SPILL OR LEAK PROCEDURES Dilute with water, mop up, use sand. WASTE: OI$I=OSAL. METHOO Landfill according to Federal, Sdate and local regulations. SECTION VIII - SPECIAL PROTECTION INFORMATION SPECIAL .-, VENTILATION LOCAL EXHAUST No None MECHAN,CAL. [Gener:J) None OT.ER None ' ' ~'~OTECT,vE ~I.OVES Impervious gloves I eY~ ~..or~cT,o~ Splash goggles OTHER PROTECTIVE EQuiPmENT None ' -SECTION IX - SPECIAL PRECAUTIONS PRECAUT'IONS TO aE TAI~EN IN HANOI. lNG ANO STORING Keep from· freezing. - OTHER PRECAUTIONS . None PAGE (2) Form OSHA-20 GI~0 "i ~.~40 Re~.Ma~ 7Z CITY of BAKERSFIELD FIRE DEPARTMENT ~~ 2130 G STREET R. E. HUEY~ B~ERSFIELD, 93301 HAZ MAT COORDINATOR 326-3979 Mt. Arthur Boykin Laidlow Corporation 1212 E. 5th Street MetroDolis, IL 62960 Dear Mr. Boykin: Per our conversation the Hazardous Materials Division, Bakersfield Fire Department, City of Bakersfield has been assigned as the administering agency for the "Hazardous Materials Release Response Plans and Inventory" -- Chapter $.95 of the California Health & Safety Code (enclosed). This along with the Federal "Superfund Amendments and Regulation Act of 1986" commonly known as (SARA) require the disclosure of trade secret information to a governmental administering agency. New City Cleaners in Bakersfield handle the following materials manufactured by your company: Laidlow Spray Sizing Laidlow Plasticizer RaDid Spot Remover Please send the Chemical breakdown by weight % for these materials to: Hazardous Materials Division Bakersfield Fire Department 2130 "G" Street Bakersfield, CA 93301 Thank you for your Cooperation. Sincerely yours, ~azardous Materials Coordinator REH/eg cc' Ne~ City Cleaners