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Home My WebLink AboutBUSINESS PLAN (2) BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY iD# BUSINESS NAME: BUS I NESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS iN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. FACILI~ b~IT# FACILI~ b~IT N~: SECTION 1: MITIGATIONr PRE~ION, ABATEMENT PROCEDb~ES SECTION 2: NOTIFICATION .~%q] EVACUATION PROCEDL~ES AT THIS L~IT ONLY BUSINESS PLAN AS A WHOLE FORM ~A 1. To avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDE~IFICATION DATA SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7560 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required'by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS. SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: B. ELECTRICAL: ' ~'~--~ C. WATER: ~ D. SPECIAL: ~o~~ E. LOCK BOX: YES ~IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / N0 MSDSS? YES / N0 FLOOR PLANS? YES / NO KEYS? YES / NO - 2A - SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE SECTION 6: EMPLOYEE T~INING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES.WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. NO NO ~TERIALS:...' .................................... B. PROCEDURES FOR COORDINATING ACTIVITIES C. PROPER USE OF SAFETY EQUIPMENT: .................. NO ' NO D. EMERGENCY EVACUATION PROCEDURES: ................. NO NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... NO NO SECTION 7: ~Z~d~I)OUS ~TERI~ CIRCLE~OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS ~TERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES ~) I,~o~-7~ ~~-~ , certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. SIGNATUR TITLE ~ DATE ~---/~~ ~ - 2B - BAKERSFIELD CITY FIRE DEPARTMENT ,- "' '.. NON--TRADE SECRETS HAZARDOUS I~IATER I ALS I NV~ENTORY ' BUSINESS NAME:'-~ L, ~. '~o~%' a~[o~Qt~e_. OWNER NAME:~o~r ~o~i~ FACILITY UNIT ADDRESS: ~OO ~, ~ ~W ADDRESS: ~~ddzo ~g~2. FACILITY UNIT NAME: ~X,~,. 1 2 3 4 5 6 7 8 [ 9 10 TYPE MAX ANNUAL CUNT USE; LOCATION IN THIS · BY ~ [lAZARD D.O.T ~CODE AMOUNT AMOUNT UNIT CODE coDE FACILITY UNIT WT. CHEMI~A~L OR COMMON NAME CODE GUIDE EMERGENCY CONTACT: :~-~ ~~ TITLE: ~~ PHONE · BU~OURS: E~ERGENCY CONTACT:/--~~ ~~. TITLE' O~~ .~ PHONE ~ BUS BOURS: PRINCIPAL BUSINESS ACTIVITY: ~,,~,~'~A~ ~ AFTER BUS HRS: - 4A-1 - MATERIAL Section V-~ HEALTH HAZARD DATA SAFETY DATA SHEET DATE OF PREP. 05-28-87 THRESHOLDUMITVAJ.UE See~lL ' / EFFECTSOFOVEREXPOSURE ACUTE: In~ala~on--J~le~he~.. Irrlin~onofre~oraeutone~-m~sy~tom MANUFACTURER BA~F CORPORATION Inment Div~0~, ~12~ ~ Pat~eay, PO Box 2757, WhitaBou~e, ONo 43~71 ~ ee~agt may m~ult In inflation. EMERGENCY TELEPHONE N°. (~00) 42a"~0 (CHE~ IN FORMATION TELEPHONE NO. (419) ~T/.5~ Eye ~mt~ t~dll I~t~to. ' / I TRADE NAME PNT 90a EME .R.G.E..NCY .AND FIRST AID PROCEDURES, Yalmr Inhalq~ -- I~ IweathM~ I:lmmwe to Itea~ a/a'. Keep wam, t and q. int. ~mmy a imy~el~n. EYe C~et -- R~ah ImmaBia~ ?lth _ _~,~-~__ _~_ amounto of nmnln~ wat~ lot at leaet 15 mlm~e~. sc-crooN #. H~.ANIX~US INeREmEmS : ,c~ ~LV Section VI -- REACTIVITY DATA Toluene 108-88-3 100 375 200 STABILITY STABLE CONDmONS TO AVOIDHeat, elam flamee, eingUtgM a~l MMIC ~c,'~-~e. [sopmpanol 67-63-0 400 980 400 ~NCO~PATIe~UTY(Ma~O av~e) mro~ ~, ~ ~ o~ Proflylene Glycol Methyl Ether Acetate 108-65-6 N/A N/A N/A ~U~-AR[X)US ~ECO~POSmON PROOUCTS Uramo~ OU~ man CO= ~ po~Uy CO an~ ~mo~ mm~. ; ?~.g Range VM + P Naphtha ' 8032-32-4 150 N/A 500 ,~,y~ene 1330-20-7 100 435 100 H~ARDOUS POLYMERIZATION: WILL NOT OCCUR Acetoae 67-(~-1 750 1780 1000 ~mbutyl Aceta~ 7. 110-19-0 150 700 200 Section VII -- SPILL OR LEAK PROCEDURES Elhylene Glycol Butyl E{hcr Acetate 112-07-2 N/A N/A N/A STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED V~,~;~ ama. Remo~e aB t WASTEDISPOSAJ. METHOD D~ofln~t~hle~al,~toto,&f~l~Mm~ L~ndflllorlm:J~em~in Section VIII -- SPECIAL PROTECTION INFORMATION * ?PM ~css othenvisc noted RESP~R~:X~Y PSOTEC~ON ~RAN~°- 381~F* VAPOR PRESSURE 37.4mm HO PER CENT VOCATILE WEk~HT PSR ~* '. BY V(~.UME 100 GALLOR 7.01~. PROTECTIVE GLOVES VOC (MAXIMUM AS pACKAGED) 7.01 Ibe/Gal __ O~HER PROTECTIVE EQUIPMENT Pm~mtt I~ Md~ eont~t to ce~amJnataB c~ [? . ~ECTION IV - fiRE AND EXPLOSION HAZARD DATA t Section IX ~ SPECIAL PRECAUTIONS I=LAMMA~}~'r~CLASSIFICATION Flammat~lB FLASHPO~NT15°+5°F.S.C.C. FLAMMABLEUMITSINAIRO.5-12.8% PSECA~TOBETAKENINHANDL~NGANDSTORiNG Do not Mom ov~12~F. ~to~qum~Utle~,Momin SPECIAJ. RRE FIGHTfNG PROCEDURES F'al prot~lve equl~ hteludlng a~ff-¢~xtt~ned u~.n'~ r=o~ ~s~s~o~ frs ~.,~C~N. m~s ~--om~*no~ S~O~L~ e~ US~ n-i¥1 RMInlshlno Products Section V-- HEALTH HAZARD DATA MATERIAL SAFETY THRES.~D,U~V~UE S.S.~". DATA SHEET DATE OF PREP. 6-1~87 EFFECTSOFOVEREXPOSURE ACUTE: ~ __ MANUFACTURER B~SF CORPORATION Inmont Divisim, 6125 ~ Pmu~my, PO Box 2757, Whtt~e~e, ONe 43571 Sldn eomad may ~ In Irrltatl~. EMERGENCY TELEPHONE NO. (800) 424-~300 (CHF. I~rREC) INFORMATION TELEPHONE NO. (419) 877~31~ Eye conlaet ~ D.O.T. DESI~NATION PaintRMatedMateHalNA1263 PRODUCTION CODE QI7CR021 W~temeha~g~. EMERGENCY AND FIRST AID PROCEDURES Vap~ bthalatlee -- ReMora ~ Rem~m to freMt air ~ wmm and quiet. TRADENAME PNT~0Califomia HoiNylph~ Ey~(~~ F~ ImPeriallY t c.o.~ua m ~b,/~dan. egeea~ -- oo ~OT ~OUCE vo~rm~ SECTION II - HAZARDOUS INGREDIENTS CAS T~V Section VI- REACTIVITY DATA INGREDIENT NUMBER PPM mg/M3 PEL' STABILITY STABLE CONDmONSTOAVOID I~ ~ f~ ~ led ~ dlldtBEg~ [sopropanol 67-63-0 400 980 400 Propylene Glycol Methyl Ether Acetate 108-65-6 N/A N/A N/A _m~7,O~A'nSn.m¢ I~sm a~ ~ Long Range VM&P Naphtha 8032-32-4 150 N/A 500 .~.~q~x~s OECO~SmoR PRO~UOTS Tolucn~ 1 08-88-3 100 375 200 H~e.~tx:~s ~OLV~R~,T~: m NOV Isobutyl Acetate 110-19-0 150 700 200 Acetone 67-64-1 750 1780 1000 Ethylene Glycol Butyl Ether Acetate 112-07-2 ~ ~ ~ ?~.'flon ~1! ~ $~ILL OR LEAK P~O~£DUR£$ Xylcne 1330-20-7 100 435 100 WASTE D~MEM'IOD DlalOOee M m lemy/dmtee with Ira;Il, m, & Mdmal mgulallmm. Sec. on viii -- SPECL~L PROTEC11ON INFORMATION RESPIRATORY pRGTEC~nON UMW TC~C CtmaM~klkdm~M t~ae ~ ~ to mme~ · eemak~k~ M PPM Unless othel~visc I VENTILATION Uee M ventllltk~ I~ v(31ume Ired Ile~em to kee~ TLV'$ I~d I~-L'I (~letl°n ii) W W SECTION III - PHYSICAL DATA kr~m, andembkaW~MT(wnowu~MWwWWerM. BOILING RANGE 134°-370~F. VAPORPRESSURE 40.75mmHg PERCENTVOL~TILE WEIGHTPER BY VOLUME 100 GALLON 7.07 l~s. pROTECTIVE GLOVES TO i~evenl I~ m~e~um, u~e ~ glmm~ VAPO~ DENSITY HEAVIER THAN AIR EVAPORATIOR RATE SLOWER THAN ETHE~ EYE PROTECTION SMIty ~ er ~ OTHER PROTECTIV~ EC~IPMENT I=mve~t VOC (MAXIMUM AS pACKAGED) 7.07 Ibe/gaL / Section IX ~ SPECIAL PRECAUTIONS SECT1ON IV - FIRE AND EXPLOSION HAZARD DATA PRECAUTIONS TO RE TAKEN iN HANDLING AND STORING Do n~ ~ ~ 1~. Whe~ Itmf. lg I1~ ~ ~ In FLAMMABILITYC2,ASSIFICA~ON FlammablelB FLASHPOINT 15°~5°F.S.C.C. FLAMMASLEUMr~SINAIR 0.~12.8% bull~eatgMdand pmto~edagMn.tllammable[~.__~__ U~M~lcllne~m~amllm~mMm~l. Do not alk~ matm~l to frae MI mere then five (S) Im~e~ EX'rlNGUISHING MEDIA F~m - C~ Dlox~ - C~I~iI POqllKISr OTHER PRECAUTIONS "FOIl ~ producta may cause a health hazard with no symptoms ImmedlatMy .ppamnt. BEUEVE TO BE REUAe~ .OWe/ER, S~ THE coNorr~ U~OER W~CH T.~S ~ ~ ~it~l~JO~, BASF ~ LIABILII~ FOR RESLIL~ OF ~rs A~!.IGAT~. THIS tNFOFa/AI1ON ~OULD BE USeD peevent prl~um bulk~up due to examine nero. ~sos MATERIAL ~ V-- HEALTH HAZARD DATA SAFETY ~-~S~LMTVALUE ..~. DATA SHEET DATE OF PREP. 05-28-87 ~- ..... : :-,'~,,~, . EMERGENCY 'I'~LEPHONE NO. (1~0) 4~ (CH~MTREC) INF~TION TELEI~IONE NO. (419) IT/'.~ SECTION II - HAZAR~ ING~ CAS ~.v Section VI -- REACTIVITY DATA lsobuiyl Acelate 110-19-0 I.~0 700 200 L~p~ YM + P NaphGm 8032-32-4 1.50 N/A .500 67-63-0 400 980 400 Toluene 108-88-3 IIX) 375 200 HAZAROCX~S POL'n4E'~mA'nON: WeJ. l,3T OCC~ Pmpylene Glycol Methyl ~ Acetate 101t.-65.-6 N/A N/A N/A Acemae 67-64-1 7,,~O 1780 1000 ~ VII ~ SPILL OR LEAK PROCEDURES Xylme 1330-20-7 100 435 100 SeCtion VIII -- SPECIAL PROTECTION INFORMATION BOILING RN~G~ 134o - 381 ~F, VAPOR PflESSURE 47.5~ Hg PER CENT VOLATILE WEIGHT PER BY VOLUME 100 GALLON 6.911~, PROTECTIVE GLOVES VOC (MAXIMUM AS PA~) 6.91 , Section IX -- SPECIAL PRECALrl~3NS S~CllON IV. FIRE AND EXPLOSION HAZARD DATA PR~CAUTK3NSTOBETA.KENINHANDUN~ANDSTORIN~ ~noll~ovlrl~l: V~ll~l~lll~lqu~ntltle~,tm~kl ~CLAS~FICi~TION FlammaW~lB FLA~4POINT15°:~5°F.S.C.C. R. AMMABLELIMITSINAIRI.0-12.8~ ~_ _~,~14lltgn~l~ad I,'~ld I~ll~mnlble__~_.,~___ U~ I~tlc Ilnllwt~n mixing In~ blnl~erCmg nlat~L UNUSUALFIREANDEX~I. OSIONHAZARDS I<~p~=~ntMnertlg~cio~e4. Avoidh~t,~l~n OTHER PRECAUTIONS "FORlIXI81RIALUS~O~.y.- Donmt~e~m.m~l,/. #~.~.4, DO NOT Imlu~ ~mlltlng -- .--__.--.....--h.--"''''''----''--'--------' BASF -- MATERIAL SAFETY DATA SHEET SECTION I PRODUCT NAME OR NUMBER (AS IT APPEARS ON LABEL) - HIGH EFFICIENCY THINNER #1516, MEDIUM MANUFACTURER'S NAME [EMERGENCY TELEPHONE NO. GROW GROUP, INC. 1313 - 643-4600 ADDRESS .(NUMBER, STREET, CITY, STATE AND ZIP CODE) 3155 WEST BIG BEAVER ROAD, SUITE 200 P.O. BOX 7026, TROY, MICHIGAN 48007-7026 MAnuFACTURER'S D-U-N-S NO. 00-532-0551 HAZARDOUS MATERIALS DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS ID NO. PAINT RELATED MATERIAL NA-1263 ADDITIONAL ItAZARD CLASSES (AS APPLICABLE) i FLAMMABLE LIQUID CHEMICAL FAMILY 'FORMULA SOLVENT BLEND SOLVENT BLEND SECTION II - INGREDIENTS ExpOsuRE LIMITS IN AIR ] LISTED AS A CAS · (UNITS IN PPM) CARCINOGEN REGISTRY NO. CI~ICAL NAMES I IN NTP IARC ACGIH OSHA VENDOR OR OSHA 1910 64742-89-4 GS-260 HYDROCARBON PETROLEUM 400 400 400' I NO DISTILLATE OR NAPHTHA I 67-56-I METHANOL (METHYL ALCOHOL) SKIN 200 200 200 I NO 67-63-0 tSOPROPYL ALCOHOL 400 400 400 I NO 67-64-1 ACETONE 750 1000 1000 [ NO 108-88-3 TOLUOL 100 100 100 I NO 1330-20-7 XYLOL 100 200 100 I NO 123-86-4 N-BUTYL ACETATE 150 150 150 [ NO 108-65-6 P.M. ACETATE (PROPYLENE GLYCOL 100 --- 100 [ NO MONOMETHYL ETHER ACETATE) [ 1119-40-0 DIBAS.______~IC ESTERS (DIMETHYL 50 --- 10/100 I NO ~----_.__ SUCCINATE, GLUTARATE, ADIPATE) I SECTION III - PHYSICAL DATA ~,~. ~OILING RANGE 135~373 XX OF OC [SPECIFIC GRAVIT¥-(H20-1) 0.7949 VAPOR PRESSURE 112.4 PERCENTVOLATILE BY VOLUME 1001 680F 0c I @ XX MM HG PSI [PERCENT SOLID BY WEIGHT O~ VAPOR DENSITY (AIR-I) [EVAPORATION RATE SLOkrER THAN ETHER 2.56 SOLUBILITY IN WATER 50% IPH NOT APPLICABLE APPEARANCE AND ODOR WATER WHITE LIQUID IS NATERIAL: LIQUID XX SOLID ~, GAS PASTE POWDER SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT BELOW 0 OF OC METHOD USED LEL UEL T.C.C. FLAMMABLE LIMITS 0.9~ 36~ EXTINGUISHING MEDIA CO2, DRY CHEMICAL, FOAM, OR OTHER NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) APPROVED METHOD FOR TREATING A CLASS B FIRE. SPECIAL FIRE FIGHTING PROCEDURES SUMMON PROFESSIONAL FIREFIGHTERS. USE FULL PROTEC- TIVE EQUIPNENT INCLUDING SELF-CONTAINED BREATHING APPARATUS. WATER SPRAY MAY BE INEFFEC- TIVE. IF WATER IS USED, FOG NOZZLES.ARE PREFERABLE. IF EXPOSED TO FIRE OR EXTREME HEAT, WATER SHOULD BE USED TO COOL CLOSED CONTAINERS AND PREVENT PRESSURE BUILD-UP OR POSSIBLE AUTO-IGNITION. ~ UNUSUAL FIRE AND EXPLOSIOI~HAZARDS KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND FLAME. VAPORS MAY CAUSE FLASH' FIRE. VAPORS MAY :IGNITE EXPLOSIVELY. VAPORS MAY SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. DUE TO PRESSURE BUILD-UP, CLOSED CONTAINERS EXPOSED TO EXTREME HEAT MAY EXPLODE. NEVER USE A WELDING OR CUTTING TORCH ON OR NEAR CONTAINER (EVEN EMPTY) AS PRODUCT OR ITS RESIDUE MAY IGNITE. DURING EMERGENCY CONDITIONS' OVEREXPOSURE TO DECOMPOSITION'PRODUCTS MAY CAUSE A HEALTH RAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION. SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE 50 PPM (ACGIH) [OTHER LIMIT 10/100 PPM (VENDOR) PERMISSIBLE EXPOSURE LIMIT 50 PPM I EFFECTS OF OVEREXPOSURE ACUTE - BREATHING - IRRITATION OF THE RESPIRATORY TRACT; HEADACHE, NAUSEA, DIZZINESS, WEAKNESS AND FATIGUE. EXTREME EXPOSURE CAN RESULT IN UNCON- SCIOUSNESS AND EVEN RESPIRATORY ARREST. EYE CONTACT - SEVERE IRRITANT. SKIN CONTACT - PROLONGED AND REPEATED LIQUID CONTACT CAN CAUSE DEFATTING AND DRYING OF SKIN, WitXCH MAY RESULT IN SKIN IRRITATION AND DERMATITIS. SWALLOWING - VOMITING MAY R~SULT. PULMONARY ASPIRATION HAZARD IF VOMITING OCCURS. CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED'OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND "~ NERVOUS SYSTEM DAMAGE. PRXNARY ROUTES OF ENTRY INHALATION, SKIN CONTACT, SWALLOWING. ~. EMERGENCY AND FIRST AID PROCEDURES IF BREATHED - IF YOU EXPERIENCE DIFFICULTY'IN BREATflING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, SUMMON MEDICAL ASSISTANCE IMMEDIATELY. IF. BREATHING CEASES, RESTORE USING APPROVED CPR TECffNIQUES AND SU~MMON MEDICAL ASSISTANCE IMMEDIATELY. IF IN EYES - FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ASSISTANCE. IFON SKIN - WASH AFFECTED ,AREAS WITH SOAP AND WATER. REMOVE SOILED CLOTHING. GET MEDICAL ASSISTANCE IF IRRITATION PERSISTS. WASH CLOTHING BEFORE REUSE. IF SWALLOWED - DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN IMMEDIATELY. ASPIRATION OF FOMITUS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY OVEREXPOSURE NONE WHEN USED IN ACCORDANCE WITH SPECIAL PROTECTION INFORMATION (SECTION VIII). wARNING: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS M~Y BE'HARMFUL OR FATAL. SECTION VI - REACTIVITY DATA STABILITY [ UNSTABLE CONDITIONS TO AVOID HEAT, SPARKS, FLAME. STABLE XX INCOMPATIBILITY (MATERIALS TO AVOID) STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS THERMAL DECOMPOSITION MAy YIELD CARBON MONOXIDE AND CARBON DIOXIDE. flAZARDOUS MAY OCCUR CONDITIONS TO AVOID NOT APPLICABLE POLYMERIZATION WILL NOT OCCUR XX "SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, AND ELECTRICAL, STATIC OR FRICTIONAL SPARKS). DO NOT SMOKE. PREVENT BREATHING VAPORS. VENTILATE AREA. BEFORE ATTEMPTING CLEAN-UP, REFER TO flAZARD CAUTION INFORMATION IN OTHER SECTIONS OF THis MATERIAL SAFETY DATAFORM. DIKE AND CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. STORE IN CLOSED CONTAINER UNTIL PROPERLY DISPOSED OF. WASTE DISPOSAL ~ETHOD DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULA- TIONS. INCINERATE ONLY IN APPROVED FACILITY DO NOT INCINERATE CLOSED CONTAINERS. CERCLA (SUPERFUND) REPORTABLE qUANTITY (IN LBS) ONE POUND OR REFER TO SECTION 311 CLEAN WAT~ ACT. RCRA HAZARDOUS WASTE NO. (40 CFR 261.33) D-001, F-003, F-005 NOTE: NUMBERS APPLY TO THINNER BLEND ONLY. VOLATILE ORGANIC COMPOUND (VOC) (AS PACKAGED, MINUS WATER) 100% XX THEORETICAL 6.644 LB/GAL XX ANALYTICAL 6.618 LB/GAL . .SECTION VIII '- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTioN WHEN USED IN RESTRICTED VENTILATION AREAS, wEAR NIOSHJMSHA APPROVED Ci{EHICAL/I~ECHA~ICAL FILTERS DESIGNED TO REMOVE ACOHBINATION OF PARTICULATES AMD VAPOR. WHEN USeD IN CONFINED AREAS, WEAR NIOSH/MSHA APPROVED' ~IR SUPPLY RESPIRATORS OR HOODS. FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE. IF RESPIRATORS'ARE USED, A PROGRAM SHOULD BE ESTABLISHED TO ASSURE COMPLIANCE WITH OSHA STANDARD 2'9 CFR 1910.134. VENTILATION USE ONLY WITH ADEQUATE VENTILATION. USE EITHER LOCAL EXHAUST OR HECHANICA~ TO MEET TLr REQUIREMENTS. VENTILATION MUST BE SUFFICIENT TO LIMIT EMPLOYEE EXPOSURE AT, OR BELOW, OSHA TLr LIMIT. HEAVY SOLVENT VAPORS SHOULD BE REMOVED FROM LOMER LEVELS OF WORKAREA. PROTECTIVE GLOVES NEOPRENE OR EQUIVALENT. ~ EYE PROTECTION SOLVENT RESISTANT SAFETY EYEWEAR WIT!~ SPLASH GUARDS. OTHER PROTECTIVE EQUIPMENT EYE BATH AND SAFETY SHOWER. SOLVENT IMPERMEABLE CLOTHING TO PREVENT SKIN CONTACT. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORINC KEEP AWAY FROM HEAT, SPARKS AND FLAME. DO NOT SMOKE. EXTINGUISH ALL PILOT LIGHTS AND TURN OFF ALL SOURCES OF IGNITION INCLUDING HEATERS, FANS AND OTHER NON-EXPLOSION-PROOF ELECTRICAL EQUIPMENT, DURING USE' AMD UNTIL ALL vAPoRs ARE GONE. VAPORS HAY IGNITE EXPLOSIVELY. VAPORS HAy SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. PREVENT BUILD-UP OF VAPORS BY HAINTAINING CONTINUOUS FLOW OF FRESH AIR. DO NOT STORE ABOVE 120°F OR NEAR FIRE OR OPEN FLAME. STORE LARGE QUANTITIES IN BUILDINGS TO COMPLY WITH OSHA 1910.106~ KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO 'BOTTLES OR OTHER UNLABELED CONTAINERS. DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. NAME WALTER STUECKEN SIGNATURE TITLE LABORATORY I~AGER ACCURATE, BUT WE DO NOT ASSUME ANY LIABILITY FOR THE ACCURACY OF.THIS iNFORMATiON. WE FOR THE USE CONTEHPLATED BY ANY USER, THE PLANNER OF THAT USE AND WHETHER THERE IS ANY IMFRII~EHENT OF PATENTS, IS THE SOLE RESPONSIBILITY OF THE USER. FOR COATINGS. RESIN8 AND RELATED MATERIAL8 DATE OF PREP. (ADl~fOved by U.8. DeDettmenl el Libor "Elllnllllly 81miler# Ia Focm OSHA.ED) ' ~ecllon I MANUFACTURER'~ NAME GROW GROUP, INC, 6q -q600 PRODUCT MANUFACTURER8 CODE IDENTIFICATION Paint Related Material NA-1263 TRAOENAME High Efficiency Thinner #1556, Fast Section II ~- HAZARDOUS INGREDIENTS INOREOIENT ~ ~ CAS REG. NO. .,=.cE.~ VA.On ~ PRESSURE GS-260 Petroleum Distillate 64742-8g~8 30-40 " and/or Naphtha - 400 1:~ 122.§ mm Methanol 67-56-1 1- 3 200 ~a-'68 F Isopropyl Alcohol 67-63-0 Acetone ' 1- 5 400 Toluol. 67-64-1 30-40 750 Xylol 108-88-3 5-15 100 1330-20-7 1- 5 · 100 Normal Butyl Acetate 123-86-4 1-10 150 P.M. Acetate 108-65-6 1- 5 100 Section III -- PHYSICAL DATA HAIR EVAPORATION RATE ,~ FASTER ~ 8LOWER. THAN ETHER mvvoLuu= .. 100% o^LLo, 6. 523 $e.__.cUon IV -- FIRE AND EXPLOSION HAZARD DATA ootc^~,=oonv Flammable Liquid F~aHPO~m' Below O°F T.C.C. " tEL 1.0% EXTINGUISHING MEDIA .. Carbon dioxide and/or alcohol foam type extinguishers. UNUSUAL FIRE AND EXPLOSION HAZARDS Handle as extremely flammable material. Vapors ni~y spread. Prevent buildup of vapors. Extinguish all pilot lights and turn off heaters, non-explosion proof electrical equipment and other sources of ignition during use and until all .vapors are gone. ' 8'PECIAL F. IRK FIOHTINO PROCEDURE8 , Use NIOSH approved self contained breathing apparatus. Coo] exposed containers with water, ':i":',. ~ ' ..... i IDn V '.HEALTH HAZARD DATA mREs-6~orbrr.~tuE 100 ppm ,. , Severe eye' irritation, drying of skin leading to dermatitis. Excessive inhalation causes he. ada.che,' dizztnes.S, nausea *to unconsciousness. .. ...... .. EM~ROENCYANO..FmmTAIDPR~EOUREm Eye contact:. Flush with water; Skin contact: Wash with mild soap and water and apply skin cream. Inhalation:~ Remove to fresh air and call a physician; apply artificial respiration if necessary. Ingestion:. Do not induce vomiting; contact a physician. Secli0n VI -- REACTIVITY DATA mTAm,uTY r'"}UNSTAmtE [X]~mTAmcE CONmTIONSTOAVOIO Heat, sparks and flanms. 'NCOMPATAm'UTV~'":!'"~'"m* Strong oxtdtztqg agents. . ...... HAZARDOUS OECOM~81TION PRODUCT8 lhe~al decomposition may yield carbon ~noxtde. HAZARDOUS POLYMERIZATION ~ MAV~CUR ~ WmkkNOT~CUR CONDITION8 TO AVOID ' ~ 8ecUon VII -- SPILL OR LEAK PROCEDURES ml.~m~om,~,~m.~.c.m~,lmm.cmn~.~m~oons~c~o Flush'with water into retatntnq area ?r con'tainer. If spill ts ~ar~q, dike arep. Eva~uate area. ,U~e oroper resptratoEy pro~e~oQ, ayotp brpatblnq va~ors. Avoid exposure to spar~s, fire or hOC mbtam surtaces. ~move With inert aosoroen~ ' anU non-s rktn ~ ol . w,m,~o,s~,~m,,o~ ~c~serate under safe conditions or dispose of tn accordance with local,' state and federa)m regulations, m Sec~mon VIII -- SPECIAL PROTECTmON mNFO,MATmON RESPIRATORY PROTECTION Self Contained breathing apparatus for concentrations above TLV ltmt VENTILATIOH Use etther local exhaust or mechanical to neet TLV requtrements. Ventilation must be sufficten to limit empi.oyee exposure at, orbelow, OSHA TLV limit. PROTECT,VEaCOV~S Neoprene or equivalent. EYEPROTECTIO. Safety glasses or goggles. OT"ERPROTECT,VEEOU,P~ENT Eye bath and safety shower. Section IX -- SPECIAL PRECAUTIONS PRECAUTIO~S~OaETAKENIN.ANOUN~A~OSTORIt~O' Keep away from heat, sparks, open flame. Use with adequate ventilation. Do not breathe vapors, do not get tn eyes, on sktn or clothing. OTHER PRECAUTIONS Never use cutting or welding torch on or near conl:atners, even empty, as product or residue may tgflt te.. · IV cTERIA DAT ........ ESAFETY SHEET..: OR COATINGS, RESINS AND RELATED MATERIAL8 (Approved by U.8. Depldm®nl of Llb~"Elllfllllfiy 81miler" Ia From OSHA.~) :; , 4/]9/85 Septlon I MANUFACTURER'8 NAME · GRON GROUP, tHC, , a,a~.t~oo.~as ~5~ ~EST ~[G ~EAVER ~OAD TROY. ~[CHIGAN qS08q EMEROENCYTELEP ~ ~ , · : ; (313) 643 4600 ' -- * ' "," *~ 'I,. ~ ., ~ 1 PRODUCTC~S~ MANUFACTURERS CODE IDENTIFICATION ' . . ' ...... Paint Related Material NA-1263 ~1600 Biendz-A11, Color Biending Solvent TRADE NAME · ', .... ". , Section II -- HA~RDOUS INGREDIENTS ~NOR~D,~Ny CAS REG. NO. PERCENT TLV VAPOR LEL PRE~SURE PPM mg/M~' GS-295 VH&P flaphLha 64742'49-0., 300~ 1~ 68 n~ Hg Acetone 67-64-Z 750 , . ~ 68~F He,by1 ELh~I KeLone ' 78-93-3 200 Toluol ~08-88-3 ]00 , " Xylol ~330-20-7 ]00 Isopropyl Alcohol .67-63-0 " 400~' Methanol 67-56-1 200 :' P.M. Acetate 108-65-6 ~..~ 100 ,,. * :, ' ' DJ Bas ic Es ters 1119-40-0 50 Section III -- PHYSICAL DATA .O,.,.anA.a~ 143 - 391OF VAPO. DE..,TY IXXI.,,AVm. I' EVAPORATION RATE F'"IFASTER F~.SLOWER, THAN ETHER BY VOLUME 10O % DALI. ON 6.83 ' Soctlon IV - FIRE AND FXPLO$1ON HA~.RD DATA DOTCATEGORV Flammable Ltqutd FLASHPOINT 14°F T.C.C. .' ret 1.0% EXTINGUISHING MEDIA Carbon dioxtde and/or alcohol foam type extinguishers.., ~ , , li tlir UNUSUAL FIRE AND EXPLOSION HAZARDS Handle as extremely flammable material. Vapors may spreadi' Prevent buildup of vapors. : . Extinguish all ptlot ltghts and turn off heaters, non-explosion proof electrical equipment and other sources of tgnttton during use or unttl all vapors are gone. SPECIAL F. IRE FIGHTING PROCEDURE8 Use NIOSH approved self contained breathing apparatus. Coo1 exposed containers with water. HAZARD T'RESHOLDLIMITV^LUE 50 ppm. ., . EFFECTS OF OVEREXPOSURE : :' ' "" ~ .... :: .... f "~" Severe eye irritation, drying of skin 1eNding"to'dermatitis. Excessive inhalation causes headache, dizziness, nausea to unconsciousness. EMEnOENCYANDrmmT^IDpROcEDUREe Eye contact: Flush with water. .~: ,, Skin contact: . Wash with mild soap and water and apply skin cream. Inhalation: Remove to fresh air and'call a physt,c, tan~ apply artificial respiration if necessary,'~ Ingestion: Do not induce vomiting; contact a physician. Section VI - REACTIVITY DATA* * STABILITY II UHSTABLE iXXImltABCE CONOITIONaTOAVOIO Heat, sparks and fiats. INCOMPATABILITYI~eee,Ial, Ioavolel Strong oxidizing agents. HAZARDOUS. DECOMPOSITION. PRODUCTS.. . ~ . , · ..... ~ . ~ ! '; ·. ~ ...... . Themal decomposition may yield carbon monoxide. · HAZARDOUS POLYMERIZATION ['"1 MAY OCCUR ~ WILL NOT OCCUR ;; ' ' CONOI?ION,~! 1'O AVOID · Section VII -- SPILL OR LEAK PROCEDURES BTEPS lO BE TAKEN IN CASE MAIERIAL IB RELEASED OR ~PILLED FlUsh with Water into retain(no area .or container, if spill is large, dike area. Evacuate area. Use proper respiratory pro[ectton, avoid breathing vapors. Avoid exposure to sparks, fire or hilt nmtal surfaceSL Remove with inert absorbent and non-s;parktng tools.' ~ ~W^STED'mPOSALM;T,O0 Incinerate under safe conditions o~ dispose of in accordance with local,.. state and federal regulations. Seclion VIII -- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION Self contained breathing apparatus for concentrations above TLV limits: 'VENTILATION : ' Use either local exhaust or mechanical' to n~et TLV requirenents. Ventilation must be sufflcienl Lo limit employee exposure at, or below~ OSHA TLV 1tilt. IPROTECtlVEOLOVE8 Neoprene or equivalent. * E~PRmEC~,ON Safety glasses or goggles.' ' ':~' ~ 0THEnPRO?ECTIVE EOUIPMENT . Eye bath' and sa fety shower. Section IX -- SPECIAL PRECAUTIONS ~RECAUIIONS TO BE TAKEN IN HANDLIN(~I AND STORINO Keep away from heat, sparks, open flare. Use with adequate ventilation. Do not breathe vapors, do not get in eyes, on skin or clothing. Accidental contact should be washed away tn~edtatelv. ~. = ~.,; )THER PRECAUTIONm Never use cutting or welding torch on or near containers, even empty, as product or residue may t gnt re. ~ .' ~ . ~ ~, . : ; .~.~ ~.. ....... .~ · 'I ' . ,,., f.,, ',' .... MATERIAL SAFETY DATA SHEET COATINGS AND RESINS GROUP SECTION I-PRODUCT INFORMATION MANUFACTURER'S NAME: PPG INDUSTRIES INC. CODE/IDENTITY : DTRG02 (030684D) PRODUCT SAFETY LOC.: 260 KAPPA DRIVE TRADE NAME: DELSTARREDUCER PITTSBURGH, PA 15238 CHEMICAL FAMILY: $OLVENTBLEND MSDS CONTACT: MANAGER, INDUSTRIAL HYGIENE DOT CLS:PAINTRELATEDMATERIAL, FLAMMABLEUQUiD AND PRODUCT SAFETY DATE OF PREPARATION: 6/09/86 (412) 963-5822 CUSTOMER PART #: EMERGENCY TELEPHONE: (304) 843-1300 SECTION II -INGREDIENTS .rNQREDTENTS APPROX. E X P 0 % WT. OAS NO. ACQTH TLV OSHA PEL PPG ZPEL TOLUENE 25 le8--88--3 Ie~.~OPPM 2~,~PPM I~e.~PPM ACETONE 15 67-64-1 75~. ~PPM 1 ~'~. ~PPM 75~. ~PPM AROMATI'C HYDROCARBON 1~ 64742-95-6 I~.~PPM NOT EST, I~,~PPM AROMATTC HYDROCARBON 5 647~42-95--6 I~.~PPM NOT EST, .I~,~PPM VM&P NAPHTHA 35 64742-89-8 3~', ~PPM 5~, ~PPM 3~, ~PPM 2-BUTOXY ETHYL ACETATE 1~ I 12-~7-2 NOT EST, NO3' EST, NOT EST, SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING RANGE : 56 - 210 DEG.C SOLUBILITY ZN WATER: 14.6 VAPOR PRESSURE: 62.0 mmHg WT/GAL (LBS): 6.76 VAPOR DENSITY : HEAVIER THAN AIR pH: U/I % VOL/VOLUME : 100.0 ~ SOLID BY WEIGHT: .0 EVAP RATE(Bu0Ac=100): 397 SECTION IV - FIRE AND EXPLOSION HAZARD DATA DOT CATEGORY: EXTREIIELY FLAMHABLE FLASHPOINT: 17 DEG. ,F PMCC FLAHHABLE LIHITS: LEL 1.6 UEL U/I EXTINGUISHING HEDIA: USE NATIONAl. FIRE PROTECTION ASSOCIATION (NFPA) CLA88 B ExTINGuISHERS (CARBON DIOXIDE, DRY CHEMICAL, OR UNIVERSAL AOUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA CLASS tB FLAMIvIABLE LIOUID FIRES. UNUSUAL FIRE AND EXPLOSION HAZARDS: KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROIvl HEAT, ELECTRICAL. F:OUIPMENI', SPARKS, AND OPEN FLAMES. CLOSED COhFrAINER$ MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DC) NOT APPLY ON HOT SURFACES. TOXIC GASES UAY FORM WHEN PRODUCT I$ CONTACTED BY FLAME OR HOT SURFACES. SPECIAL FIRE FIGHTING PROCEDURES: WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. FIRE-FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. SECTION V - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR INCOMPATIBILITY (MATERIALS AND CONDITi'ONS TO AVOID): AVOID CONTACT WITH STRONG ALKALIES. STRONG MINERAL ACIDS, OR STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS: MAY PROOUCE HAZARDOUS DECOMPOSITION PRODUCTS WHEN HEATED, INCLUDING: Carbon Monoxide, SECTION VI - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASEO OR SPILLEO: Continued on Back of Page Continuation of Manufacturer's Code - DTRG02 DATE OF PREP: 6/09/86 v~ PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRATORY AND SKIN AND EYE PROTECTION SHOULD BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP ~" SPILLED MATERIAL WITH SAWDUST, VERMICULITE, OR OTHER ABSORBENT. MATERIAL AND PLACE INTO CONTAINERS FOR DISPOSAL. WASTE DISPOSAL NETHOD: WASTE MATERIN. MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, ANDJ.OCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT FACILTY. SECTION VII - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE FRON: INGESTION: HARMFUL OR FATAL IF SWALLOWED. EYE CONTACT: CAUSE8 SEVERE EYE IRRITATION. SKIN CONTACT: MAY CAUSE MODERATE SKIN IRRITATION. MAY BE ABSORBED THROUGH THE SKIN. I NHALAT I ON: VAPOR AND SPRAY MIST MAY BE HARMFUL IF INHALED. REPEATED EXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY CAUSE IRRITATION OF THE RESPIRATORY SYSTEM AND PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. CHRONIC OVEREXPOSURE: AVOID LONG-TERM AND REPEATED CONTACT. SIGNS AND SYNPTONS OF OVEREXPOSURE: EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, AND LOSS OF COORDINATION ARE INDICATIONS THAT SOLVENT LEVELS ARE TOO HIGH. REDNESS, ITCHING, BURNING SENSATIONS AND VISUAL DISTURBANCES MAY BE INDICATIONS THAT EXCESSIVE EYE CONTACT HAS OCCURED. DRYNESS, ITCHING, CRACKING, BURNING, REDNESS, AND SWELLING ARE CONDITIONS ASSOCIATED WITH ~ EXCESSIVE SKIN CONTACT. · ~ NEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NOTAPPLICABLE SECTION VIII - FIRST AID PROCEDURES INGESTION: I IF SWALLOWED, DO NOT IN~XJCE VOMITING. EYE CONTACT: iN CASE OF EYE CONTACT, FLUSH EYES IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN CONTACT: IN CASE OF SKIN CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOLLOWED BY WASHING WITH SOAP AND WATER. I NHALATI ON: IF AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST, REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION AND OTHER SUPPORTIVE MEASURES AS REQUIRED. 0THE R: IF ANY OF THE FOLLOWING OCCUR DURING OR FOLLOWING USE OF THIS PRODUCT, CONTACT A POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE MATERIAL SAFETY DATA SHEET INFORMATION AVAILABLE. *INGESTION 'EXCESSIVE EXPOSURE TO A CORROSIVE MATERIAL. · PERSISTENT SKIN/EYE IRRITATION OR BREATHING DIFFICULTIES. SECTION IX - PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPNENT FOR: EYE PROTECTION: WEAR CHEMICAL-TYPE SPLASH GOGGLES OR FULL FACE SHIELD. SKIN PROTECTION: WEAR PROTECTIVE CLOTHING, INCLUDING IMPERMEABLE APRON AND GLOVES CONSTRUCTED OF: NITRILE RUBBER, NEOPRENE RUBBER OR POLYVINYL ALCOHOL Continued on Page 2 '~' ~' PAG~* 2 Continuation of Manufacturer's Code - DTR602 DATE OF PREP: 6/09/86 RESPIRATORY PROTECTION: OVEREXPOSURE TO VAPORS MAY BE PREVENTED BY ENSURING VENTILATION CONTROLS, VAPOR EXHAUST OR FRESH AIR ENTRY. NIOSH/MSHA-APPROVED (TC-23C-) PAINT SPRAY OR AIR SUPPLIED (TC-19C-) RESPIRATORS MAY ALSO REDUCE EXPOSURE. IN ALL CASES, READ RESPIRATOR MANUFACTURER'S INSTRUCTIONS AND LITERATURE CAREFULLY TO DETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THE RESPIRATOR IS EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED. OTHER EQUIPMENT: CLEAN OR DISCARD CONTAMINATED CLOTHING AND SHOES. VENTILATION REQUIREMENTS: PROWDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME AND PR'I-TERN TO KEEP THE CONCENTRATION OF INGREDIENTS IN SECTION II BELOW THE LOWEST SUGGESTED EXPOSURE LIMIT, AND LEL IN SECTION IV BELOW STATED LIMIT. SECTION X -$PECIAL PRECAUTION8 HANOLING ANO STORAGE PRECAUTIONS: DO NOT STORE ABOVE 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS lB FLAMMABLE LIQUIDS. OTHER PRECAUTIONS: IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT COATING SYSTEM, READ THE MATERIAL SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES. ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH ALL APPLICABLE RULES OR ORDERS UNDER THE ENVIRONMENTAL PROTECTION AGENCY'S TOXIC SUBSTANCE CONTROL ACT. THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) UII = UNKNOWN INFORMATION NIA = NOT APPLICABLE NOT EST. = NOT ESTABLISHED LOCATION: M.qlERIAL SAFETY DATAIIHEET .Pc^ 1-72. FOR COATINGS, RESINS AND RELATED MATERIALS DATE OF PREP. 6/2 6/8 5 I . (Approved by U.8. D®pldmenl of LIbor"Eilenllilly 8,mlllr" to Form OSHA-2OI Section I MANUFACTURERS NAME 'GROW GROUP, 8TREETAOORE88 3155 WEST BIG BE[AVER ROADcnY'aT^T'"'^N°z'Pc°°' TROY/ ['IICHIGAN /4808/4 (313) 643-4600 PRODUCT Ct,.A~8 MANUFACTURER~ CODE IDENTIFICATION Propylene Glycol Monomethyl Ether Acetate' Multi-Purpose Retarder //4550 T.AO~.AU" N.O.S. Section II -- HAZ_a, RDOUS INGREDIENT8 VAPOR ,.o.~o,~., CAS REG. NO. PERCENI' ?LV LEI PPM mglMz P.M. Acetate 108-65-6 100 100 1.3% 3.~ ~F Hg $oction Ill - PHYSICal DAIA BOILING RANGE 284 - 290°F VA.OR DENSITY i Xx I HEAVIER i I LIGHTER. THAN AIR EVAPORATIONRAIE r~ FASTER I'~ISLOWER. THANETHER PERCENT VOLATILE WEIGHTPER aY VOLUME 100% GALLON 8.027 Section IV - FIRE AND EXPLOSION HAZARD DATA DOT CATEGORY Combustible Liquid FLASHPOINT l14°F Seta LEL 1.3% EXTINGUISHING MEDIA Carbon d~oxtde and/or chemical foam type extinguishers. UNUSUAL FIRE AND EXPLOSION HAZARDS None ~PECIAL F..~RE FIGHTING PIqOCEDURE~ Use NIOSH approved self contained breathing apparatus. Cool exposed containers with water. -- · ~ectlo'n V ~ HEALTH HAZARD DATA ''RES"O'OUMITVALUE 100 ppi EFFECT$ OF OVEREXPOSURE Severe eye irritation, drying of skin leading to dermatitis. 'Excessive inhalation causes headache, dizziness, nausea to unconsciousness. EMEROENCYANDFIR$,AIDPROCEDURE8 Eye contact: Flush with water. Skin contact: Wash with mild soap and water and apply skin cream. ' Inhalation: Remove to fresh air and call a physician; apply artificial respiration if necessary. Ingestion: Induce vomiting; contact a physician. Section VI -- REACTIVITY DATA STA",L,TY I---~U"S'^S'E II[XiST^"'E CO"O'T'O"STOAvO,O Heat, sparks and flanes. INCOMPATABILI?Y IMII/tlAI, tOlvO~! Strongoxt dt ztng agents. HAZARDOUS DECOMPOBITION PRODUC?S Thermal decomposition may. yield carbon monoxide. HAZARDOUS POLYMERIZATION r'"l MAYOCCUR ~ WILL NOT OCCUR CONDITION~) TO AVOID Section VII -- SPILL OR LEAK PROCEDURES STEPSTOBETAKENINCASEMATERIALI'~)RELEASEDORSPILLED Flush with water into retainina area or container If spill is ]argq, dike are~. Eva;uat~.area..U;e p['ol~er r~sptratoj~y pro(ect.ioQ; ayotl] brpa~bina vapors. Avoid exposure [o sparks, tire or no[ me[am surtaces. ~emove with ~ner[ a~soroen[ W^S~EO,SPOS[~MmT.o~anU non-s arkin t,p¢ol5 .tnc~h'erate under safe conditions or dispose of in accordance with local, state and federal regulations. Section VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION Self contained breathing apparatus for concentrations above TLV limtts~. VENTI,ATION Use either local exhaust or mechanical to meet TLV requirements. Ventilation must be sufficten to limit employee exposure at, or below, OSHA lLV limit. P"OTECT,VEOLOVES Neoprene or equivalent. EYE PROTECTION Safety glasses or goggles. OTHERPROTECT,VEEOU,PME,~ Eye bath and safety shower. Section IX -- SPECIAL PRECAUTIONS PRECAUIlONSTOBETAKENINHAND,INQANO$?ORINO Keep away from heat, sparks, open flame. Use with adequate ventilation. Do not breathe vapors, do not get in eyes, on skin or clothing. OTHER PRECAUTIONS) Never use cutting or welding torch on or near containers, even empty, as product or residue may ignite. MATERIAL SAFETY DATA SHEET COATINGS AND RESINS GROUP SECTION I- PRODUCT INFORMATION MANUFACTURER'~ NAME: PPG INDUSTRIES INC. CODE/IDENTITY : DTR$04 (030684D) PRODUCT SAFETY LOC.: 260 KAPPA DRIVE TRADE NAME: HOT WEATHER ACRYLIC ENAMEL REDUOER PITTSBURGH, PA 15238 CHEMICAL FAMILY: $OLVENTBLEND r4SDS CONTACT: MANAGER, INDUSTRIAL HYGIENE DOT CLS:PAINTRELATEDMATERIAL, FLAMMABLE AND PRODUCT SAFETY DATE OF PREPARATION: 6/09/86 (412) 963-5822 CUSTOMER pART. #: EMERGENCY TELEPHONE: (304) 843-1300 SECTION II- INGREDIENT8 ZNQREDZENT$ APPROX. E X P O $ U R E L Z M ! T $ % WT. CAS NO. AOQZH TLV OSHA PEL PPG ZPEL VM&P NAPHTHA 4.5 64742--89--8 3~. ~PPM 5~. ~PPM 3~.~PPM TOLUENE 15 1~8-68-3 I~.~PPM 2~.~PPM I~.~PPM XYLENE 5 133~-2~-7 I~.~PPM I~.~PPM I~.~PPM 2-8UTOXY ETHYL ACETATE 1~ t12-~7-2 NOT EST. NOT EST. NOT EST. N-BUTYL ACETATE 1~ 123-86-4 15~.~PPM 15~. ~PPM DIETHYLENE GLYCOL MONOBUTYL ETHER ACETATE 1~ 124-17-4 NOT EST. NOT EST. NOT EST. SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING RANGE : 110 -. 259 DEG.C SOLUBILITY IN WATER: 1.0 VAPOR PRESSURE: 5.8 mmHg WT/GAL (LBS): 6.91 VAPOR DENSITY : HEAVIER THAN AIR pH: U/I % VOL/VOLUHE : 100.0 % SOLID BY WEIGHT: .0 EVAP RATE(Bu0Ac=100): 94 SECTION IV - FIRE AND EXPLOSION HAZARD DATA DOT CATEGORY: FLAMMABLE FLASHPOINT: 50 DEG..F PMCC FLAHFIABLE LIHITS: LEL 1.2 UEL: U/I EXTINGUISHING HEDIA: USE NATIONAL FIRE PROTECTION A88OCIATION (NFPA) CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY CHEMICAL, OR UNIVERSAL AOUEOU8 FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA CLA88 lB FLAMMABLE LIQUID FIRES. UNUSUAL FIRE AND EXPLOSION HAZARDS: KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND OPEN FLAMES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY ON HOT SURFACES. TOXIC GASES MAY FORM WHEN PRODUCT IS CONTACTED BY FLAME OR HOT SURFACES. SPECIAL FIRE FIGHTING PROCEDURES: WATER 8PRAY MAY BE INEFFECTIVE. WATER SPRAY IvtAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER I$ USED, FOG NOZZLES ARE PREFERABLE. FIRE-FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS. SECTION V - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR TNC0~PATTB[LITY (~ATERIALS AND CONDIT[0NS TO AVOID): AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS, OR STRONG OXIDIZING AGENTS. HAZARDOUS DEC0~P0$IT[0N ,PRODUCTS: MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS WHEN HEATED, INCLUDING: Carbon Monoxide, SECTION VI - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ~Continued on Back of Page ContinUation of' Manufacturer's Code - DTR604 DATE OF PREP: 6/09/86 PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED WITH PROPER RESpiRATORY AND SKIN AND EYE PROTECTION SHOULD BE PERMI3"rED IN THE AREA. REMOVE ALL SOURCES OF~ IGNITION. TAKE UP .... ,~ SPILLED MATERIAL WITH SAWDUST, VERMICULITE, OR OTHER ABsoRBENT .MATERIAL AND PLACE INTO CONTAINERS FOR DISPOSAL. gASTE DISPOSAL HETHOD: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT FACILTY. SECTION VII - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE FRON: Z NGESTI ON: HARMFUL OR FATAL IF SWALLOWED. EYE CONTACT: CAUSES SEVERE EYE IRRITATION. SKIN CONTACT: MAY CAUSE MODERATE SKIN IRRITATION. MAY BE ABSORBED THROUGH THE SKIN. INHALATION: VAPOR AND SPRAY MIST MAY BE HARMFUL IF INHALED. REPEATED EXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY CAUSE IRRITATION OF THE RESPIRATORY SYSTEM AND PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR FATAL. CHRONIC OVEREXPOSURE: AVOID LONG-TERM AND REPEATED CONTACT. SIGNS AND SYMPTONS OF OVEREXPOSURE: EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, AND LOSS OF COORDINATION ARE INDICATIONS THAT SOLVENT LEVELS ARE TOO HIGH. REDNESS, ITCHING, BURNING SENSATIONS AND VISUAL DISTURBANCES MAY BE INDICATIONS THAT EXCESSIVE EYE CONTACT HAS OCCURED. DRYNESS, ITCHING, CRACKING, BURNING, REDNESS, AND SWELLING ARE CONDITIONS ASSOCIATED WITH EXCESSIVE SKIN CONTACT. FIEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NOT APPLICABLE SECTION VIII' FIRST AID PROCEDURES I NGESTI ON: IF SWALLOWED, DO NO'I"INDUCE VOMITING. EYE CONTACT: IN CASE OF EYE CONTACT, FLUSH EYES IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN CONTACT: tN CASE OF SKIN CONTACT, FLUSH IMMEDIATELY WITH PLENTY OF WATER FOLLOWED BY WASHING WITH SOAP AND WATER. INHALATION: IF AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST, REMOVE TO FRESH AIR, APPLY ARTIFICIAL RESPIRATION AND OTHER SUPPORTIVE MEASURES AS REQUIRED. OTHER: IF ANY OF THE FOLLOWING OCCUR DURING OR FOLLOWING USE OF THIS PRODUCT, CONTACT A POISON CONTROL CENTER. EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE MATERIAL SAFETY DATA SHEET INFORMATION AVAILABLE. 'INGESTION *EXCESSIVE EXPOSURE TO A CORROSIVE MATERIAL. ' PERSISTENT SKIN/EYE IRRITATION OR BREATHING DIFFICULTIES. SECTION IX- PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPNENT FOR: EYE PROTECTION: WEAR CHEMICAL-TYPE SPLASH GOGGLES OR FULL FACE SHIELD. SKIN PROTECTION: WEAR PROTECTIVE CLOTHING, INCLUDING IMPERMEABLE APRON AND GLovEs CONSTRUCTED OF: NITRILE RUBBER, NEOPRENE RUBBER OR POLYVINYL ALCOHOL .._ Cont*inued on Page 2 ' Continuation of Manufacturer's Code - 0TAG04 DATE OF PREP: 6/09/86 RESPIRATORY PROTECTION: OVEREXPOSURE TO VAPORS MAY BE PREVENTED BY ENSURING VENTILATION CONTROLS, VAPOR EXHAUST OR FRESH AIR ENTRY. NIOSHIMSHA-APPROVED (TC-23C-) PAINT SPRAY OR AIR SUPPLIED (TC-19G-) RESPIRATORS MAY ALSO REDUCE EXPOSURE. IN ALL CASES, READ RESPIRATOR MANUFACTURER'S INSTRUCTIONS AND LITERATURE CAREFULLY TO DETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THE RESPIRATOR IS EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED. OTHER EQUIPHENT: CLEAN OR DISCARD CONTAMINATED CLOTHING AND SHOES. VENTILATION REQUIRE)lENTS: PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO KEEP THE CONCENTRATION OF iNGREDIENTS IN SECTION II BELOW THE LOWEST SUGGESTED EXPOSURE LIMIT, AND LEE IN SECTION IV BELOW STATED LIMIT. SECTION X - SPECIAL PRECAUTIONS HANDLING AND STORAGE PRECAUTIONS: DO NOT STORE ABOVE 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS lB FLAMMABLE LIQUIDS. OTHER PRECAUT!ONS: IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT COATING SYSTEM, READ THE MATERIAL SAFETY DATA SHEET(S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES. ALL CHEMICAL SUBSTANCES IN THIS PRODUCT COMPLY WITH ALL APPLICABLE RULES OR ORDERS UNDER THE ENVIRONMENTAL PROTECTION AGENCY'S TOXIC SUBSTANCE CONTROL ACT. THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) UII - UNKNOWN INFORMATION NIA I NOT APPLICABLE NOT EST. - NOT ESTABLISHED LOCATION: