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BUSINESS PLAN 1/12/2000
Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE This permit is issued for the following: [] Hazardous Materials Plan [] Underground Storage of Hazardous Materials Permit ID #:: 015-000-000767 [] Risk Management Program TECHNICAL WIRELINE SERV [] Hazardous Waste On-Site Treatment LOCATION: 5501 ALDRIN CT E /~.~'~:' ':' ~IELD f. :.. ..-~ ~. .~ ~..~ . - ~:il' '! . ; '. ? ~¥;' ?~ · · ~%. ;;.,.. ... OFFICE OF EN~R ONMENTAL SER VICES ' 1715 Chester Ave., 3rd Floor Approved by: vC~Ip~Huey[~~2 issue ~te Bakersfield, CA 93301 omceorE~s~ic~ Voice (661) 326-3979 F~ (661) 326-0576 Exp~tion Date: Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE This permit is issued for the following' .... ,,~??.!, Materials Plan PERMIT ID# 015-021~00767 Iround Storage of Hazardous Materials .,,~?i, Program TECHNICAL WIRELINE SERV ..... Waste LOCATION 5501 ALDRIN ?)? BA ..... CA Issu~ by: B~ersfield F~e D~a~ment 1715 Chewer Ave., 3rd Floor / ~ph Hu~,~7 B~e~fiel~ CA 93301 ~ O~ce of ~n~i S~ Voice (805) 32~3979 F~ (805) 326-0576 Expiration Date: TECHNICAL WIRELINE SERVICE INC. December 30, 1993 Fire Station #3 Attn: R. Rapp 6915 Stine Road Bakersfield, CA 93313 Attention R. Rapp: Regarding your last inspection of Technical Wireline Services, we have enclosed the corrections you requested. 1) The fire extinguishers have all been properly charged. We have also documented the date of service in our computer as a record to notify us of the yearly maintenance needed. 2) ~;e have added the bulk motor oil and vaste drum to our inventory. We have supplied you with the updated material form, as well as, the floor plan of our establishment. If you have any further questions, please call anytime. Thank You, j Phil Ke er k_ ~ Vice President T.W. ~ ~ ~ Phil Keeler Vice President FAX (805) 832-1415 (805) 832-2996 STEAM SPECIALISTS DIGITAL pAGER (805) 329-6878 pRODUCTION suRVEYS 5501 ALE)RI N CT., sUITE E ENHANCEMENT CH EMiCALS BAKERSFIELD, CA 93313 RO. BOX 40338 · BAKERSFIELD, CA 93384-0338 · 805-832-2996 T£CH~VICAL ~I~IRELLVE ~ ER~ !~,c 550~'. ALDRIN CT SUITE E BAKERSFIELD, CALIF LOCATION ALL~Y ENTRY ROLL UP DOOR · SAF~ ~HOP AR~A ~TAL BU1LDING OFFIC~ OPFIOB S~LIOHTS Oo Ht4~o~z ,. RESTR~M = , OFFIC~ OFFIG$ ROLL UP E~RY 5~0~ ALDRIN TECHNICAL ~IRELINE SER. Ir~c 660! ALDRIN CT SUITE £ LOCATION "'- E SITE/FACILITY DIAGRA~'I FORM 5 NORTH SCALE: 81$SI.NES$ NAME:~..~_a,~,-~_,~~ ~.~Rm~-- FLOOR:I O~ I DATE:~/~q/~FACILITY N~ME: UNIT =: 0F ~+~ i o (CHECK ON'E) SITE DIAGR.~%[ ~ FACILITY DIAGR.%%[ ~ Inspector's Comments): -OFFICIAL USE ONLY- - 5A - gOr,~, UP ~0~ BHOP ~A BUILDING ~AL BUI~IN~ OF~lC~ E~Y 6501 ~LDRIN ~ ~UITB ~ TECHNICAL W!RELINE SER. [nc S60 ~" ' AL-_DRIN CT " SUITE E BAKERSFIELD, CALIF ...... 93313 '" YAI~D ELECTR C.-A~/ WATER .~'" SEE FLOOR PLAN ~ ~ ~ C B A _ mc~rm~ S II ~ N E I~Y~,S'T KEROSENE (66 GAL) I-~ (6oo ~) CABIHET (C~YOGEN1CS ) LIQUID ~0~0~ OIL (55 ~AL~S) SHOP AR~A (4z BRUM 66 AIROONDI~IONINO ON ROOF COMPLETE OVERHEAD .., OFFICE SOUTH E XTINGUIS HE~ M~TAL BUILD1N~ / u NO~TH S~L1G~S 0 Uooo RESTROOM , n~,wrr,~ OFFICE II-~ II '"~' ~' '"'~' I ' - I EAST PA~NC 550~ ALDRIN CT SUITE E TECHNICAL WIRELINE SER. I'n,c 5501 ALDRIN CT SUITE E BAKERSFIELD, CALIF 93313 YARD .--~ SEE FLOOR;LAN F ~ O C B mc~no~ S I ~ N ;~~7' TECHNICAL WIRELINE SERVICE INC. Phil Keeler Vice President (805) 832.2996 STEAM SPECIALISTS P.O. BOX 1973 PRODUCTION SURVEYS BAKERSFIELD, CA 93303 ENHANCEMENT CHEMICALS · . -Phil Keeler Vice President (805) 832-2996 STEAM SPECIALISTS 5501 ALDRIN CT. PRODUCTION SURVEYS BAKERSFIELD, CA 93313 ENHANCEMENT CHEMICALS TECHNICAL WIRELINE SERVICESj~}~,*'~ (~-~[V.~_~,~:~ SitelD:~t 215-000-000767 Manager : I JAN 2tm000 .I BusPhone: {g~5) 832-2996 Location: 5501 ALDRIN CT E Map : 123 CommHaz : Moderate City : BAKERSFIELD jBy: ..~ ..... ![ Grid: 15D FacUnits: 1 AOV: CommCode: Bg_KERSFIELD STATION 13 SIC Code:1389 EPA Numb: DunnBrad:95-301-8476 Emergency Contact / Title Emergency Contact / Title VIC GIFFORD ~ / PRESIDENT PHIL KEELER f~l/ VICE PRESIDENT Business Phone: (8~N~) 832-2996x Business Phone: (8~ 832-2996x 24-Hour Phone : (~3) ~x~-?~ 24-Hour Phone : ~-~O5} ~32 901~x~ Pager Phone : (&~l) _ x Pager Phone (fif~) ~7-~05~x~' Hazmat Hazards: Fire Press ImmHlth DelHlth Contact : Phone: ( ) - x MailAddr: 5501 ALDRIN CT E State: CA City : BAKERSFIELD Zip : 93313 Owner TECHNICAL WIRELINE SERVICES INC 'Phone: ~ 832-2996x Address : 5501 ALDRIN #E CT State: CA City : BAKERSFIELD Zip : 93313 Period : to TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: No Emergency Directives:. ~ Hazmat Inventory One Unified List 9 -- MCP+DailyMax Order Ail Materials at Site ~ Hazmat Common Name... ISpooHazlEPA HazardsI Frm DailyMax IUnitlMCP ACETYLENE F P IH G 55.00 FT3 Hi MINERAL SPIRITS F IH DH L 55.00 GAL Mod OXYGEN F P IH G 150.00 FT3 Low WASTE OIL F DH L 110.00 GAL Low KEROSENE F DH L 55.00 GAL Low NITROGEN ' -'~ F P DH G 1000.00 FT3 Min MOTOR OIL NiTRO~M~v~z~ --~' F DH L 55.00 G~ Min LIQUID ~7~ or p~m ~) ' -1- 12/21/1999 TECHNICAL WIRELINE SERVICES INC SiteID: 215-000-000767 ~ Inventory Item 0003 Facility Unit: Fixed Containers on Site ACETYLENE~/ Days On Site 365 Location within this Facility Unit Map~: Grid: SOUTH WALL CAS# 74-86-2 F STATE I TYPE PRESSURE ~ TEMPERATURE , CONTAINER TYPE PureI FIXED PRESS CYLINDER lGas Above Ambient I Ambient . AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average FT3I 55.00 FT3 55.00 FT3 HAZARDOUS COMPONENTS %Wt. Ry~oR8~ CAS# 100.00 Acetylene 74862 HAZARD AssESSMENTS TSecretNo N~S I BioHaz I Radioactive/Amount IEPA HazardsNo . No/ Curies F P IH NFPA/// IuSDOT# HiMCP = Inventory Item 0004 Facility Unit: Fixed Containers on Site MINERAL SPIRITS ~ Days On Site 365 Location within this Facility Unit Map: Grid: SOUTH WALL CAS# F STATE ~ TYPE PRESSURE i TEMPERATURE CONTAINER TYPE Liquid /Pure Ambient Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average GAL[ 55.00 GAL 55.00 GAL HAZARDOUS COMPONENTS I 100.00 Mineral Spirits N 8030306 HAZARD ASSESSMENTS TSoorotl oRS BioHa.z Radioactive/Amount I EPA Hazards NFPA I USDOT# MOP No N No No/ Curies F IH DH / / / Mod -2- 12/21/1999 TECHNICAL WIRELINE SERVICES INC SiteID: 215-000-000767 ~ Inventory Item 0002 Facility Unit: Fixed Containers on Site ~Vl~ ~vl~ / ~ ~Z~/~ ~vl~ OXYGEN~/ Days On Site 365 Location.within this Facility Unit Map: Grid: SOUTH WALL CAS# 7782-44-7 Gas Pure .Above Ambient Ambient FIXED PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum I Daily Average FT3I 150.00 FT3I 150.00 FT3 HAZARDOUS COMPONENTS %Wt S CAS# 100.00 Oxygen, Compressed N 7782447 HAZARD ASSESSMENTS TSecret ~SIBioHazI Radioactive/Amount I EPA Hazards NFPA I USDOT# MCP No N No No/ Curies F P IH / / / Low -- Inventory Item 0008 Facility Unit: Fixed Containers on Site ~.21vUVlUl~J JN,~tviJ~ / ~I"I~IVI.L~L[J /~J~/VlJ~ WASTE OIL / Days On Site 365 Location within this Facility Unit Map: Grid: SOUTH WALL CAS# 221 F STATE ~ TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid I Waste Ambient I Ambient DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average GAL 110.00 GAL 110.00 GAL HAZARDOUS COMPONENTS Waste Oil, Petroleum Based N HAZARD ASSESSMENTS ITSocrot NoRSIBioHaz Radioactive~Amount I EPA Hazards I NFPA USDOT# MCP No No No/ Curies F DH / / / Low 3 .12/21/1999 TECHNICAL WIRELINE SERVICES INC SiteID: 215-000-000767 ~ Inventory Item 0005 Facility Unit: Fixed Containers on Site ~lVUVl~ ~Vl~ / ~l~.~J.J ~Vl~ KEROSENE~/ Days On Site 365 Location within this Facility Unit Map: Grid: SOUTH WALL CAS# 8008-20-6 F STATE ~ TYPE PRESSURE TEMPERATuRE CONTAINER TYPE Liquid /Pure I Ambient I Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average GAL[ 55.00 GAL 55.00 GAL HAZARDOUS COMPONENTS 100.00 Kerosene N 70892103 HAZARD ASSESSMENTS TSeoretI~sIBioHaz Radioactive/Amount EPAHazardsI NFPA USDOT# MCP No N No No/ Curies F DH / / / Low = Inventory Item 0001 Facility Unit: Fixed Containers on Site 9 ~UiV~VlU~ ~Vl~ / ~£~.l~ ~Vl~ NITROGEN/ Days On Site 365 Location within this Facility Unit Map: Grid: ON TRAILER - SOUTH SIDE CAS# 7727379 Gas Pure Above Ambient Ambient FIXED PRESS. CYLINDER AMOUNTS AT THIS LOCATION l Largest Container I Daily MaximumI Daily Average FT3 1000.00 FT3 1000.00 FT3 HAZARDOUS COMPONENTS 100.00 Nitrogen ' 7727379 i TSecret RS BioHazI HAZARD ASSESSMENTS ) Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P DH / / / Min -4- 12/21/1999 TECHNICAL WIRELINE SERVICES INC SiteID: 215-000-000767 = Inventory Item 0007 Facility Unit: Fixed Containers on Site -- COMMON NAME / CHEMICAL NAME MOTOR OIL p/ Days On Site 365 Location within this Facility Unit Map: Grid: SOUTH WALL. CAS# 8020835 FSTATE TYPE PRESSURE i TEMPERATURE CONTAINER TYPE Liquid Pure I Ambient Ambient DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average GAL 55.00 GAL 55.00 GAL HAZARDOUS COMPONENTS Motor Oil, Petroleum Based N 8020835 HAZARD ASSESSMENTS TSecret ~SIBioHaz Radioactive/Amount[EPAHazardsI NFPA USDOT# MCP No N No No/ Curies F DH / / / Mit = Inventory. Item 0006 Facility Unit: Fixed Containers on Site ~ -- COMMON NAME ~CH~MICAL NAME LIQUID NITROGEN/ Days On Site 365 Location within this Facility Unit Map: Grid: NW RA ROOM 'CAS# 7727-37-9 F STATE ~ TYPE PRESSURE ~ TEMPERATURE CONTAINER TYPE Gas /Pure Above Ambient Cryogenic INSUL.TANK / CRYOGENIC AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average GAL[ 42.00 GAL 42.00 GAL HAZARDOUS COMPONENTS %wt. ~s CAS# 100.00 Nitrogen N 7727379 HAZARD ASSESSMENTS TSecretNo N~S I Bi°Hat[NO Radioactive/AmountNo/ Curies EPAF P HazardsiH NFPA/// I USDOT# IMcpMis -5- 12/21/1999 F TECHNICAL WIRELINE SERVICES INC SiteID: 215-000-000767 Fast Format ~ Notif./Evacuation/Medical Overall Site ---Agency Notification 09/03/1992 CALL 911 Employee Notif./Evacuation 09/03/1992 IF HAZARD OCCURS: DEFINE HAZARD AREA, CLEAR HAZARD AREA, NOTIFY PERSONNEL THAT WOULD HANDLE HAZARD. Public Notif./Evacuation 09/03/1992 DIRECTED BY VIC GIFFORD AND/OR PHIL KEELER AND DEPARTMENT OF HEALTH SERVICES Emergency Medical Plan 09/03/1992 LOCAL HOSPITALS. -6- 12/21/1999 F TECHNICAL WIRELINE SERVICES INC SiteID: 215-000-000767 Fast Format ~ Mitigation/Prevent/Abatemt Overall Site --Release Prevention 02/28/1991 ALL MATERIALS ARE KEPT'IN APPROVED CONTAINERS. RADIOACTIVE MATERIALS ARE CONFINED TO A FI/ME HOOD AND ANY SPILLS WOULD BE CONTAINED IN THE HOOD. -- Release Containment 02/28/1991 RA MATERIALS ARE CONFINED TO FUME HOODS AND WOULD CONTAIN ANY SPILLS. -- Clean Up 02/28/1991 DEFINE HAZARD AREA CLEAN HAZARDAREA NOTIFY PERSONNAL THAT WOULD HANDLE HAZARD Other'Resource Activation -7- 12/21/1999 F TECHNICAL WIRELINE SERVICES INC SiteID: 215-000-000767 Fast Format -- Site Emergency Factors Overall Site -- Special Hazards 09/03/1992 RADIOISATOPES ON HAND. RADIATION HAZARD. --Utility Shut-Offs 09/03/1992 A) GAS - NORTHWEST - BUILDING FRONT B) ELECTRICAL - NORTHWEST - BUILDING FRONT C) WATER - NORTH BUILDING FRONT D) SPECIAL - NONE E) LOCK BOX - NO Fire Protec./Avail. Water 09/03/1992 PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND SPRINKLER SYSTEM FIRE HYDRANT - IN FRONT OF COMPLEX ON ALDRIN CT. Building Occupancy Level 8 12/21/1999 TECHNICAL WIRELINE SERVICES INC SiteID: 215-000-000767 Fast Format ~ Training Overall Site -- Employee Training 02/13/1996 WE HAVE EMPLOYEES AT THIS FACILITY. WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE. BRIEF SUMMARY OF TRAINING: WEEKLY SAFETY MEETINGS COVERING FIRST AID HAZARDOUS MATERIALS SAFETY EQUIPMENT EMERGENCY PROCEDURES Page 2 Held for Future Use Held for Future Use I 9 12/21/1999 01/19/96 TECHNICAL WIRELINE SERVICES INC 215-000-0~ Overall Site with 1 Fac. Unit General Information Location: 5501 ALDRIN CT E Map:123 Haz:3 Type: 3 City : BAKERSFIELD Grid: 15D F/U: 1 AOV: 0.0 Contact Name Title F--~-Contact Name Title VIC GIFFORD / PRESIDENT IPHIL KEELER / VICE PRESIDENT Business Phone: (805) 832-2996x I Business Phone: (805) 832-2996x 24-Hour Phone : (805) 832-3628x I 24-Hour Phone : (805) 832-9014x Pager Phone : ( ) - x I Pager Phone : ( ) - x Administrative Data Mail Addrs: 5501 ALDRIN CT E D&B Number: 95-301-8476 City: BAKERSFIELD State: CA Zip: 93313- Comm Code: 215-013 BAKERSFIELD STATION 13 SIC Code: 1389 Owner: TECHNICAL WIRELINE SERVICES INC Phone: (805) 832-2996 Address: 5501 ALDRIN CT #E State: CA City: BAKERSFIELD Zip: 93313- Summary I,'~'~H,L ~'eE-LiS. t;~ O0 hereby certify that I have .... fryP~ ~.p~nt~mo) -- reviewed the attached hazardous materials manage- merit plan fo[ ~<~,~,~-z~,.,~ and that it along with (Name of Bu~ine~) : -- any corrections constitute a complete and correct man- agement plan for my facility; 01/19/96 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-003 ACETYLENE Gas 55 High · Fire, Pressure, Immed Hlth FT3 02-004 MINERAL SPIRITS Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-002 OXYGEN Gas 150 Low · Fire, Pressure, Immed Hlth FT3 02-005 KEROSENE Liquid 55 Low · Fire, Delay Hlth GAL 02-008 WASTE OIL Liquid ~O ~ Low · Fire,~Delay Hlth GAL 02-001 NITROGEN Gas 1000 Minimal · Fire, Pressure, Delay Hlth FT3 02-006 LIQUID NITROGEN Gas 42 Minimal · Fire, Pressure, Immed Hlth GAL 02-007 MOTOR OIL Liquid 55 Minimal · Fire, Delay Hlth GAL 01/19/96 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Paqe 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-003 ACETYLENE Gas 55 High ~· Fire, Pressure, Immed Hlth FT3 CAS #: ~4-86-2 Trade Secret: No Form: Gas Type: pUre Days: 365 Use: WELDING SOLDERING Daily Max FT3 I Daily Average FT3 I Annual Amount FT3 55 i 55.00 110.00 Storage ~ Press T Temp~ Location FIXED PRESS. CYLINDER IAbove I AmbientlSOUTH WALL -- Conc Components MCP ---~uide 100.0% IAcetylene IHigh ~ 17 02-004 MINERAL SPIRITS Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: CLEANING Daily Max GAL I Daily Average GAL I Annual Amount GAL 55 ~ 55.00 110.00 Storage Press T Temp Location ABOVE GROUND TANK I Ambient~Ambient I SOUTH WALL -- Conc Components MCP ---TGuide ~ 100.0% IMineral Spirits IModeratel 27 02-002 OXYGEN Gas 150 Low · Fire, Pressure, Immed Hlth FT3 CAS #: 7782-44-7 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELDING SOLDERING Daily Max FT3 I Daily Average FT3 1 Annual Amount FT3 150 ~ 150.00 300.00 Storage ~ Press T Temp~ Location FIXED PRESS. CYLINDER I above ~Ambient I SOUTH WALL -- Conc Components t MCP ---~uide 100.0% IOxygen, Compressed ~Low ~ 14 01/19/96 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Paqe 4 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-005 KEROSENE Liquid 55 Low · Fire, Delay Hlth GAL CAS #: 8008-20-6 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: FUEL Daily Max GAL I Daily Average GAL I Annual Amount GAL 55 ~ 55.00 110.00 Storage ~~Press T Temp Location ABOVE GROUND TANK IAmbient]AmbientlSOUTH WALL -- Conc Components MCP ---~uide 100.0% I Kerosene I Moderate I 27 02-008 WASTE OIL Liquid 55 Low · Fire, Delay Hlth GAL CAS #: 221 Trade Secret: No Form: Liquid Type: Waste Days: 365 Use: WASTE Daily Max GAL ~ Daily Average GAL ~ Annual Amount GAL ~ [ ~ ~ I 220.00 Storage Press T Temp Location DRUM/BARREL-METALLIC IAnlbientlAmbientlSOUTH WALL -- Conc, Components ~ MCP ---~uide 0.0% IWaste Oil, Petroleum Based ILow [ 27 02-001 NITROGEN Gas 1000 Minimal · Fire, Pressure, Delay Hlth FT3 CAS #: 7727379 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELL INJECTION OR SERVICE Daily Max FT3 Daily Average FT3 Annual Amount FT3 1,000 I 1,000.00 I 10,000.00 StorageI Press T TempI Location FIXED PRESS. CYLINDER IAbove [AmbientlON TRAILER - SOUTH SIDE -- Conc Components MCP ---~uide 100.0% INitrogen [Low [ 12 ¢ 01/19/96 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Paqe 5 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-006 LIQUID NITROGEN Gas 42 Minimal · Fire, Pressure, Immed Hlth GAL CAS #: 7727-37-9 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: COOLING Daily Max GAL I Daily Average GAL I Annual Amount GAL 42 ~ 42.00 . 420.00 Storage ~ Press T Temp Location INSUL.TANK / CRYOGENICIAbove ~CryogenlNW RA ROOM -- Conc Components MCP ---TGuide 100.0% INitrogen ILOw / 12 02-007 MOTOR OIL Liquid 55 Minimal · Fire, Delay Hlth GAL CAS #: 8020835 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: LUBRICANT -- Daily Max GALI Daily Average GAL I Annual Amount GAL 55 ~ 55.00 220.00 Storage Press T Temp Location DRUM/BARREL-METALLIC IAmbient~AmbientlSOUTH WALL -- Conc~ Components MCP ---~uide 0.0% IMotor Oil, Petroleum Based Minimal I 27 01/19/96, TECHNICAL WIRELINE SERVICES INC 215-000-000767 Paq~ 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation IF HAZARD OCCURS: DEFINE HAZARD AREA, CLEAR HAZARD AREA, NOTIFY PERSONNEL THAT WOULD HANDLE HAZARD. <3> Public Notif%~Evacuation DIRECTED BY VIC GIFFORD AND/OR PHIL KEELER AND DEPARTMENT OF HEALTH SERVICES <4> Emergency Medical Plan LOCAL HOSPITALS. 01/19/96 TECHNICAL WIRELINE SERVICES INC 215-000-0007§7 Paq~ 7 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention ALL MATERIALS ARE KEPT IN APPROVED CONTAINERS. RADIOACTIVE MATERIALS ARE CONFINED TO A FUME HOOD AND ANY SPILLS WOULD BE CONTAINED IN THE HOOD. <2> Release Containment RA MATERIALS ARE CONFINED TO FUME HOODS AND WOULD CONTAIN ANY SPILLS. <3> Clean Up DEFINE HAZARD AREA CLEAN HAZARD AREA NOTIFY PERSONNAL THAT WOULD HANDLE HAZARD <4> Other Resource Activation 01/19/96 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Page 8 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards RADIOISATOPES ON HAND. RADIATION HAZARD. <2> Utility Shut-Offs A) GAS - NORTHWEST - BUILDING FRONT B) ELECTRICAL - NORTHWEST - BUILDING FRONT C) WATER - NORTH BUILDING FRONT D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND SPRINKLER SYSTEM FIRE HYDRANT -biN FRONT OF COMPLEX ON ALDRIN CT. <4> Building Occupancy Level 01/19/96 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Page 9 00 - Overall Site <G> Training <1> Employee Training WE HAVE=~EMPLOYEES AT THIS FACILITY 5 WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: WEEKLY SAFETY MEETINGS COVERING FIRST AID HAZARDOUS MATERIALS SAFETY EQUIPMENT EMERGENCY PROCEDURES <2> Page 2 <3> Held for Future Use <4> Held for Future Use HAZARDOUS MATERIALS DIVISION Date Completed Business Name: ~c~,,,~/~zl~_. ~,~J-~/~ Location: ,z.)-~ O [ ,~ [ ~ ¢,'~ ~'~ ~ ~ Business Identification No. 215-000 CO0 "7 ~,~ (Top of Business Plan) Station No. I '~ Shift ~ Inspector \ ~ %0 Adequate Inadequate .-.-~,,~, ~'¢~\ \ 5z~5 Verificationoflnventoryaaterials ~,,,..,> i5~ Verification of Quantities Verification of Location Proper Segregation of Material Comments: Verification of MSDS Availablity Number of Employees Verification of Haz Mat Training comments: Verification of Abatement Supplies & Procedures Comments: Emergency Procedures Posted Containers Properly Labeled Comments: Verification of Facility Diagram Special Hazards Associated with this Facility: "~ P ~-~' n~ All Items O.K. I~ Correction Needed ~ Business Owne~r~"l~a FD 1652 (Rev, 1-90) White-Haz Mat Dh/, Yellow-Station Copy, Pink-Business Copy ~X./~.ARDOUS iMATERIAL$ DIVISION. 'Date Location: Nb~- , .... ,. ~ .. .. ~I . '.'- -' Ver~cation of, E~i · · A~ooi~ed' wflh',~hi~"Fa~ii~y~ Agrt~lture ~St~dard ~usi~ss ' Page of ~ 5 6 7 8 9 10 11 ~ 13 14 ~ A~a~ ~u~ ~e 9 Da~ Con= C~t ~n= Use ~on ~e~ ~ ~ N~s of ~/C~nen~ of 9r~s~ H~l=~ H~i~ co~on~; 3 N~ & C.A.S. N~ apply) ' I I I I I I I I I 08/18/92 TECHNICAL WIRELINE SERVICES INC~ 215-000-000767 Page 1 Overall Site with 1 Fac. 'Unit General Information Location: 5501ALDRIN CT E Map: 123 Hazard: Moderate Community: BAKERSFIELD STATION 13 Grid: 15D F/U: 1 AOV: 0.0 Contact Name Title Business Phone , 24-Hour Phone- PHIL KEELER VICE PRESIDENT (805) 832-2996 x 1(805)~ Administrative Data Mail Addrs: 5501-E ALDRIN CT D&B Number: 95-301-8476 City: BAKERSFIELD .State: CA Zip: 93313- Comm Code: 215-013 BAKERSFIELD STATION 13 SIC Code: 1389 Owner: TECHNICAL WIRELINE SERVICES INC Phone: (805) 832-2996 Address: 5501ALDRIN CT #E State: CA City: BAKERSFIELD Zip: 93313- Summary 08/18/92 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Page 2 02 - Fixed Containers on Site· Hazmat Inventory Detail in Reference Number Order 02-001 NITROGEN Gas 1000 Minimal · Fire, Pressure, Delay Hlth FT3 CAS #: 7727379 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELL INJECTION OR SERVICE Daily Max FT3I Daily Average FT3 ~ Annual Amount FT3 -- 1,000 I 1,000.00 10,000.00 Storage Press T Temp~ Location FIXED PRESS.· CYLINDER Above I AmbientlON TRAILER - SOUTH SIDE -- Conc Components MCP List 100.0% INitrogen Low I 02-002 oXyGEN Gas 150 Low · Fire, Pressure, Immed Hlth ~ FT3 CAS #: 7782-44-7 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELDING SOLDERING Daily Max FT3150 I Daily Average150.00FT3 I Annual Amount300.00FT3 m Storage ~ Press T Temp~ Location FIXED PRESS. CYLINDER IAbove ~AmbientlSOUTH WALL -- Conc Components MCP ----TList 100.0% Ioxygen, Compressed ILow 02-003 ACETYLENE Gas 55 High · Fire, Pressure, Immed Hlth FT3 CAS #: 74~86-2 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELDING SOLDERING Daily Max FT3~ Daily Average FT3 I Annual Amount FT3 55 ! 55.00 110.00 Storage ~ Press T Temp ~ Location FIXED PRESS. CYLINDERlAb°ye ~AmbientlSOUTH WALL -- Conc Components . MCP List 100.0% IAcetylene IHigh 08/18/92 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-004 MINERAL SPIRITS Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: CLEANING Daily Max GALI Daily Average GAL I Annual Amount GAL 55 ~ 55.00 110.00 StorageIIPress T Temp Location ABOVE GROUND TANK IAmbient~AmbientlSOUTH WALL -- Conc Components ' MCP 100.0% IMineral Spirits Moderatel.List 02-005 KEROSENE Liquid 55 Low · Fire, Delay Hlth GAL CAS #: 8008-20-6 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: FUEL Daily Max GALI Daily Average GAL I Annual Amount GAL 55 ~ 55.00 110.00 Storage I Press T Temp .~ Location ABOVE GROUND TANK IAmbient~AmbientlSOUTH WALL -- Conc Components MCP List 100.0% IKerosene ModerateI 02-006 LIQUID NITROGEN Gas 42 Minimal · Fire, Pressure, Immed Hlth GAL CAS #: 7727-37-9 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: COOLING Daily Max GALI Daily Average GAL I Annual Amount GAL 42 ~ 42.00 420.00 Storage Press T Temp Location INSUL.TANK / CRYOGENICIAbovo /CryogenlNw RA ROOM --.Conc Components MCP List 100.0% INitrogen ILow --~ 09/03/92 TECHNICAL WIRELINE SERVICES INC 215-000-000767 .Page· 1 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation IF HAZARD OCCURS: DEFINE HAZARD AREA, CLEAR HAZARD AREA, NOTIFY PERSONNEL THAT WOULD HANDLE HAZARD. <3> Public Notif./Evacuation DIRECTED BY VIC GIFFORD AND/OR PHIL KEELER AND DEPARTMENT OF HEALTH SERVICES <4> Emergency Medical Plan LOCAL HOSPITALS. 09/03/92 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Page 2 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention ALL MATERIALS ARE KEPT IN APPROVED CONTAINERS. RADIOACTIVE MATERIALS ARE CONFINED TO A FUME HOOD AND ANY SPILLS WOULD BE CONTAINED IN THE HOOD. <2> Release Containment RA MATERIALS ARE CONFINED TO FUME HOODS AND WOULD CONTAIN ANY SPILLS. <3> Clean Up DEFINE HAZARD AREA CLEAN HAZARD AREA NOTIFY PERSONNAL THAT WOULD HANDLE HAZARD <4> Other Resource Activation 09/03/92 TECHNICAL WIRELINE SERVICES INC 215-000-000767 Page 3 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards RADIOISOTOPES ON HAND. RADIATION HAZARD. <2> Utility Shut-Offs A) GAS - NORTHWEST - BUILDING FRONT B) ELECTRICAL - NORTHWEST - BUILDING FRONT C) WATER - NORTH BUILDING FRONT D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND SPRINKLER SYSTEM FIRE HYDRANT - IN FRONT OF COMPLEX ON ALDRIN CT. <4> Building Occupancy Level 09/03/92 TECHNICAL WIRELINE SERVICES INC .215-000-000767 Page 4 00 - Overall Site <G> Training <1> Page 1 WE HAVE 4 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: WEEKLY SAFETY MEETINGS COVERING FIRST AID HAZARDOUS MATERIALS SAFETY EQUIPMENT EMERGENCY PROCEDURES <2> Page 2 as needed <3> Held for Future Use. <4> Held for Future Use The best way to find out who we are is to know some of the things we do! If you're looking for answers instead of just numbers, we are the Technical group you' ve been looking for... Technical Wireline Service, Inc. is a Logging and Associated Consulting group with more than 18 years of experience. Our staff consists of highly skilled engineers and technical personnel. We are specialists in the field of thermal recovery and have the capability of setting up a steam drive system and monitoring it with our surface equipment and downhole instruments. TWS, Inc. is based in Bakersfield, ~.~ .~ ~ ~ ~ ~ ~ ~--~ California, where steam injection was first introduced to the oil industry. We have worked for all the major oil companies and have acquired a Production Logging Equipment tremendous amount of technical data. This specialized data we generate TWS, Inc. utilizes Krypton-85 gas tracer for a project, allows the oil company engineer to best utilize his time and with dual gamma ray detectors to define heat flow into oil reservoirs. optimize project performance. Technical Wireline Service, Inc. also has a manufacturing Division. We are capable of building computerized Production Logging units with state-of-the-art equipment. Our equipment and techniques for profiling steam injection wells are the most sophisticated on the market today. Remember, for all your thermal recovery needs; from drilling, facilities, distribution and downhole Thermal Flow Analyzer monitoring, TWS, Inc. is the company to call. The thermal flow analyzer measures heat and mass flow to accurately define (805) 832-2996 distribution inconsistencies throughout the Fax (805) 832-1415 surface facility. 6611 Kane Way · Bakersfield, CA 93309 O .. Bakersfield Fire Dept. Hazardous Materials Division 2130 "G" Street Bakersfield, CA. 93301 HAZARDOUS MATERIALS MANAGEMENT PLAN INSTRUCTIONS: ~ 1. To avoid further action, return this form within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer t~e questions I~elow for the business as a whole. 4. Be I~rlef anti concise as possil~le. SECTION ~: BUS~NESS ~DENT~C^TIO. BUSINESS NAME:' '7'~-~f~-A//~t~__ /.4~,~'_~_.v'~'~_ LOCATION: ~OI ~~/X/ ~ MAILING ADDRESS: ~ {l ~N~ ~~ CI~: ~~~/~ STATE: ~ ZIP: ~~ DUN · BRADSTREET NUMBER' ~-~0{~~ SIC CODE: PRIMARY ACTIVITY: ~/~~. OWN~: ~/~ ~/f~P / ~~ MAILING ADDRESS: ~. SECTION 2: EMERGENCY NOTIFICATION: CONTACT TITLE BUS. PHONE 24 HR. PHONE " " Bakersfield Fire Dept. Hazardou~ Material8 Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 3: TRAINING: NUMBER OF EMPLOYESS: MATERIAL SAFETY DATA SHEETS ON FILE: BRIEF SUMMARY OF TRAINING PROGRAM' 7, SECTION 4: EXEMPTION REgUEST: I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAPTER 6.95 OF THE "CALIFORNIA HEALTH & SAFETY CODE" FOR THE FOLLOWING REASONS: WE 'DO NOT HANDLE HAZARDOUS MATERIALS. WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIMEEXCEED THE MINIMUM REPORTING QUANTITIES. OTHER (SPECIFY REASON) SECTION 5: CERTIFICATION: I. ' "~x~ ~_~'~.,~-._,~ CERTIFY THAT THE ABOVE INFOR- MATION IS ACCURATE. I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIV. 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT INACCURATE INFORMATION CONSTITUTES PERJURY. SIG~ATUI~ TITLE DATE .. 2. Bakersfield Fire Dept. Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN Facility Unit Name: -~--~q_~x//~-C /~-~/~/~ SE~;TION 6: NOTIFICATION AND EVACUATION PROCEDURES: A. AGENCY NOTIFICATION PROCEDURES: B. EMPLOYEE NOTIFICATION AND EVACUATION: C. PUBLIC EVACUATION: , D. EMERGENCY MEDICAL PLAN: ~.o~ u ~ ~/~? , r,~. ~ Bakersfield Fire Dept. Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 7: MITIGATION, PREVENTION AND ABATEME.~i¥ PLAN: A. RELEASE PREVENTION STEPS: , B. RELEASE CONTAINMENT AND/OR MINIMIZATION: C. CLEAN-UP PROCEDURES: -~~_ //~ SECTION 8: UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FACILITY): ELECTRICAL: SPECIAL: LOCK BOX: YES/~ IF YES, LOCATION' SECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABILITY: A. PRIVATE FIRE PROTECTION: B. WATER AVAILABILITY (FIRE HYDRANT): ACCIDENT PREVENTION POLICY Technical Wireline Service, Inc. is vitally interested and concerned about the health and safety of its employees both on and off the job. This concern is paramount and it takes precedence over expedience in the conduct of business. It is Technical Wireline Service's responsibility to provide and maintain safe and healthful working conditions in conformity with all applicable laws, regulations and company standards. It is also our intent to promote off-the-job safety to assist employees in protecting themselves and their families. With the aim to reduce injuries and property damage to a minimum: Management will maintain safe working conditions, providing proper knowledge, training, tools and facilities to conduct its affairs so as to prevent injuries or impairments to health of employees present at all facilities, and to prevent property damage. Each employee will work safely as a condition of employment, accepting responsibility for his personal safety performance and his job performance as it affects the safety of others. Each employee will encourage others to work safely, sharing responsibility for the safe actions of his fellow workers. Safety performance comments will be included in performance appraisals of all employees. Vic Gifford~ ~re~ideht ~-' TF~CHNICAL WIRELINE~ SERVICE, INC. §611 KANE.WAY · BAKERSFIELD, CA 93309 · 805-832-2996 ECHNICAL ~IRELINE SERVICE Inc. SAFETY REGULATIONS PRODUCTION LOGGING DEPT. 5501 E ALDRIN Ct BAKERSFIELD, CALIF. 93313 (805) 832-2996 Standard Equipment on Technical Wireline Service, Inc. Vehicle Scott Air Pack HzS Monitor Fire Extinguisher Hard Hats Safety Glasses Face Shields Geiger Counters Steam Gloves Hearing Protectors Voice Activated 2-Way Walkie-Talkies First-Aid Kit All employees are trained and certified for proper use of this equipment. Section I-Safety Responsibilities A. Company and Government Orders Ail equipment shall be installed and operated in accordance with company standards and applicable local, state and federal codes and regulations. B. Supervisor Responsibilities 1. Ail supervisors shall see that instruction and guidance in correct work procedures is given to all employees under their direct supervision. 2. Ail supervisors shall inspect working conditions to ascertain that there are no safety hazards. 3. Ail supervisors shall enforce the regulations contained herein which apply to the work operation for which they are responsible. 4. Ail supervisors shall assure routine inspection and servicing for all safety equipment (including fire extinguishers, gas testing equipment and eye wash facilities, emergency shutdown systems, supplied air breathing equipment, etc.). Records of the inspections shall be maintained. C. Employee Responsibilities 1. Each employee shall read and abide by the regulations contained in this booklet. 2. Each employee shall follow company written and oral instructions to safely perform his job. 3. When the employee has any doubt regarding his job procedure or the safety involved, he should consult his supervisor before proceeding. 4. Each employee shall correct or report any unsafe tools, equip- ment, condition or practice he observes. 5. Ail injuries whether or not requiring services of a doctor, shall be reported to the immediate supervisor on the day of the occurence. Before seeking non-emergency medical treatment, the supervisor must be notified and he will arrange for assistance by a company designated doctor. 6. Each employee shall be familiar with emergency procedures applicable to the job, including response to fires and/or injuries. 7. Each employee in the course of his work shall keep tools, equipment, facilities, and his work area clean and orderly. Tools, rags, and other equipment shall not be left lying on the floor, stairs, ladders, or decking where they present a hazard. -1- D. Disciplinary Policy Failure to follow any safety practice or policy described in this manual shall subject the employee to disciplinary procdures up to and including termination. E. Visitor Safety Responsibilities 1. Ail visits must be approved by appropriate management. 2. Visitors shall be advised of Technical Wireline Service, Inc.'s safety requirements expressed or implied. Adherence to safety rules, regulations and standards is a condition of visitation. 3. Visitors must be accompanied at all times by a Technical Wireline Service authorized guide familiar with the safety requirements of the facility to be visited. The guide shall ensure that operations are not disrupted and the visitor is not exposed to known hazards or undue risk. Section II-General Safety Practices A. Safe Conduct Requirements 1. Ail forms of horseplay are prohibited. 2. Never enter a designated chemical handling area without adequate protective equipment and training. 3. Do not reach into any enclosure until you have assured yourself that it does not contain black widow spiders or snakes. 4. Look for and observe all warning, caution or danger signs. 5. Do not climb any structures except on established ladders, stair- wells, or walking surfaces, unless appropriate safeguards, e.g., lifelines, safety nets, etc., are used. Do not walk or climb on piping, valves, fittings or any other equipment not designed as a walking surface. 6. Step or,climb down from all elevated locations. Do not jump down! 7. Keep wind direction and ground slope in mind at all times when H2S areas or around LPG storage vessels. In the event of fire or an unexpected diSchacge, your best route of escape is away from the problem in an uphill'and upwind direction. 8. Keep out of the path of moving or movable objects. 9. Do not remove, displace, temper with, or destroy any safety devices, safeguards, notices or warnings unless duly authorized. -2- 10. Do not walk under loads being lifted by crane, winch, etc. 11. Flammable liquids shall not be used for cleaning. B. Smoking 1. Smoking is prohibited on the job at Technical Wireline Service, Inc. 2. Discarding matches, cigarettes, cigars, etc. from any vehicle is prohibited. C. Drugs~ Alcohol and Weapons 1. Possession and/or use of illegal or unauthorized drugs, drug paraphenalia, firearms or other weapons is prohibited while on company premises, in company vehicles or on any Oil Co.'s properties. 2. The use or possession of alcohol or drugs is prohibited on company premises or during working hours. Vehicles and/or equipment shall not be operated by anyone under the influence of alcohol or drugs. Violators shall be subject to termination, PERIOD! 3. Employees shall notify their supervisor when using prescription drugs authorized by a doctor. D. Safety Equipment Ail safety equipment including, but not limited to, hard hats, safety glasses, gas testers, monitors, respirators, hearing protectors, fire fighting equipment, etc., shall be approved by the Safety Engineer prior to purchase and use. E. Office Safety Precautions 1. Ail office employees should be familiar with the evacuation procedures for their building and with reporting procedures for emergencies. 2. Avoid office clutter which would impede, egress or cause trapping hazards. 3. Do not open more than one filing cabinet drawer at a time. Close all drawers immediately after use. 4. Safely position telephone cords or flexible cables so that they do not become a tripping hazard. Report frayed or damaged electical cables or cords to your immediate supervisor. F. Proper Lifting In order to make a proper lift: 1. Bend the legs at the knees, bend torso at waist with the back straight, body as close to the object as possible, and feet apart -3- but no further than shoulder width. 2. Take a fim hold and straighten knees. Back should be straight and the chin level. 3.Pull the load close to the body and lean back slightly to keep the center of gravity over the feet. 4. When lifting or carrying, avoid twisting the body. 5. Never overexert yourself. Get help before attempting to lift anything that cannot be handled easily. 6. When you are handling material with other people, all shall agree on who will act as leader and give the signals. Do not release loads until everyone is ready. Teamwork is important! G. ~mergencies 1. Ail personnel shall familiarize themselves with the emergency procedures and be prepared to take proper action quickly and orderly. 2. Notify supervisors of an emergency as soon as practicable. 3. Ail manned facilities shall annually conduct and document hypothetical emergency drills. Section III-Personal Protective Equipment A. General 1. All employees shall be clothed in a manner which will not impair their safety. 2. Shirts shall be worn on the job. Cotton and wool clothing is preferable due to its fire-resistant qualities. Shirts should be buttoned up the front and at the cuff and shirttails kept in the trousers. Shirt sleeves may be rolled up. Short sleeves are acceptable. Tank tops, short tops or sleeveless shirts are not allowed. 3. Full length pants are required. No shorts or cut off jeans are allowed. 4. Loose or ragged clothing or defective shoes should not be worn. 5. Clothing (including shoes) saturated with light petrole~n products shall be removed immediately to prevent skin irritation and possible ignition. Change such clothing out of doors and away from sources of ignition. B. Head Protection Hard hats shall be worn by Technical Wireline Service, Inc. employees at all times in field operations except when traveling to and from job site. C. Eye Protection Any place eye hazards exist, employees shall use appropriate eye protection. 1. Safety galsses or full-face shields must be worn while working around steam injection wells. D. Foot Protection Work boots are mandatory at all field locations for all employees. E. Hand ProteCtion 1. Rings are to be removed while at work in the field. Rings and wrist watches shall always be removed when working in areas where they could catch on moving objects or sharp protrusions or come in contact with electrical circuits. 2. Approved gloves shall be worn for appropriate jobs. F. Hearing Protection Approved earplugs or earmuffs shall be used in areas where the noise level exceeds 90 dBA or where the premises are posted to this effect. Employees who are a part of a hearing conservation program shall have annual training. Section IV-Chemical t~azard Protection A. General 1. Chemicals shall be handled with caution as outlined in the Material Safety Data Sheets (MSDS) and according to directions for appropriate use. Proper personal protective equipment shall be worn by personnel working with potentially hazardous substances. 2. Chemical containers shall be properly labeled. 3. MSDS shall be readily available for chemicals handled, stored or produced at each location where employees report for work. ~ese publications include information on health, emergency care, first aid procedures, special precautions, fire and environmental protection. MSDS also contain information on handling the chemicals and the proper personal protective equipment to wear. B. HydroRen Sulfide (H2S) Requirements 1. Supervisors shall arrange to periodically test for the presence of H2S in all operating facilities. The frequency of testing shall be based on the concentration of H2S, operating pressures, type of equipment and maintenance/operating practices. Ail facilities containing H2S at concentrations less than 200 ppm, shall be tested annually until a sufficient history has been developed to -5- assure that the HzS concentrations are not increasing. Consult with the Safety Engineer in setting up test schedule. 2.Ail personnel required to work in areas with H2S shall be trained on: a. The characteristics and hazards of H2S, b. Approved methods for detecting and monitoring H2S, c. Use of supplied air breathing apparatus (SABA) and requirements for a standby, d. Safety procedures for performing their work in H2S areas, and e. F~nergency methods of rescue and first aid for personnel overcome by R2s. Refresher training is required annually or more frequently if necessary. 3. Ail facilities with equipment containing more than 200 ppm H2S, shall be posted and the equi~nent shall be labeled. a. Entries to the property shall be posted with a sign stating "Notice - Entering Potential H2S Poisonous Gas Area". b. Ail facilities without fixed monitors shall be posted with a sign stating, "Caution - "H2S Poisonous Gas May Be Present, Continuous Monitors Must Be Worn Beyond This Point". c. Ail equipment containing more than 200 ppmH2S shall be labeled, "Danger - Deadly Levels of H2S Are In This Equipment, Supplied Air Breathing Apparatus Must Be Worn When Opening Any Part". 4. Ail sites containing more than 200 ppm H2S in the equipment shall have fixed monitors and alarms or employees shall carry portable monitors. Ail employees not wearing supplied air breathing apparatus shall evacuate any area when the monitors alarm at 20 ppm or more in the atmosphere (except offshore platforms and gas plants shall have fixed monitors set to alarm at 10 ppm). 5.The minimum safety requirements for opening any piece of equipment containing more than 200 ppmHzS is: a. The wearing of a continuous monitor and SABA by the person opening the equipment and, b. The~attendance of at least one other SABA qualified and equipped person until the equipment is open and acceptable levels of H2S are verified. After verification of safe working levels, the second person may be released and SABA is no longer required of the first person. (The only exception from wearing SABA and having a backup is during routine opening sample valves 1" or smaller on crude oil storage ta~s provided a continuous monitor is uSed and there is no more than 20 ppmH2S in the breathing zone.) -6- C. Acid-Caustic Requirements 1. Personnel handling acids or caustics must wear chemical goggles, face shields, and rubber gloves. When breaking lines, opening equipment, etc., rubber suits and boots are also required. Z. When high concentrations of vapors may be present, approved resiratory protection must be worn. 3. Before~working with acid or caustic facilities, personnel shall locate the safety shower and eyewash stations. Section V-Operating Motor Vehicles A. Driver Responsibilities 1. The driver of a company vehicle (including owned, leased, rented or otherwise designated company vehicle including personal vehicles used for company business) is responsible for: a. Operating the vehicle in a safe manner b. Using the vehicle only for the purposes for which designed. c. The safety of his passengers or helpers. 2. The driver of a company vehicle is also responsible for the safety of employees helping load or unload, or otherwise working on or around the vehicles, unless a supervisor is in complete charge of the loading-unloading operations. 3. Ail drivers shall drive company equipment in accordance with the law and maintain a valid driver's license. Drivers are personally responsible for the consequences of violations. 4. Drivers of assigned company vehicles should routinely check the condition and operation of the following: seat belts, tires, horn, brakes, windshield wipers, steering gear, windshields, headlights, taillights, turn signals, stop light, gasoline, oil radiator, transmission and battery fluid levels. 5. Drivers shall not operate company equipment which is defective or not in compliance with the law. B. Safe Driving Principles 1. ~Mnployees shall operate company vehicles in a defensive manner, i.e., being always on the alert and trying to anticipate what might occur under the existing conditions and driving in such a manner as to avoid hazards, j 2. Employees operating company vehicles shall be considerate of, and courteous to, the travelling public and/or pedestrians and shall yield the right-of-way to avoid accidents. -7- 3. Employees shall drive at speeds consistent with surrounding conditions, such as weather, ranging cattle, etc. 4. Drive at all times with sufficient space around your vehicle to provide time to see conflicts arising, Go react quickly and to stop. c. Safe Starting i. Employees should walk around company vehicles before starting them to check for possible obstructions or unfavorable conditions. D. Safe Parking. 1. Do not park behind another vehicle, or in such a position that places your vehicle in another vehicle's "blindspot". 2. Vehicles are to be parked off the roadway where they will not be an obstruction to other vehicles or traffic. 3. Doors are to be closed. 4. For vehicles parked on decline or incline; a. Front wheels properly turned to curb or bank, and b. Pickups, i.e., field operators, welders, etc., shall have rear wheels properly - "choked". 5. For vehicles without air or electric brakes - unattended; a. Turn ignition "off", b. Place automatic transmission in "park" position, or standard transmission in "lowest gear" opposite the direction of incline, and c. Set parking brake. 6. For vehicles with air or electric brake with power take off in use; a. Set parking brake and micro-brake (if so equipped), and b. Properly chock rear wheels. 7. For vehicle with air or electric brakes, power takeoff not in use-unattended; a. Turn ignition "off", and b. Place transmission in "lowest gear", and c. Set parking brake or micro-brake (if so equipped). D. Safe Braking 1. When entering a field facility or location make every attempt to park where you do not have to backup. Exception is madewhen parking in a designated parking lot. -8- 2. If a facility/location has access that prohibits turning around without backing-up, park off the main road and cover the facility on foot. 3. If you must back up, do the following: a. Walk behind your vehicle first making sure there are no obstacles in your intended route of travel. b. Obtain a flagman if necessary, to avoid hazards. c. While backing, continually check clearances. d. Back slowly. F. Seat Belt Usage The driver and all passengers shall have their seat belt fastened whenever a company vehicle is in motion. The driver is responsible for the passenger's seat belts being fastened. G. Safe Operation 1. Tools, equipment, paper, etc., shall not be left loose in the cab of trucks or passenger compartments of cars. Use chart holders or clipboards for paper. 2. Loading a. Trucks or other vehicles shall not be loaded above the posted load limit with materials or passengers. b. Ail vehicle loads shall be properly placed and secured, and rear projections four (4) feet beyond the body of the vehicle shall be flagged with a red flag. c. Explosives, pesticides, flammable and combustible liquids shall be carried in safe containers outside the vehicle passenger compartments. Ail legal requirements for containers, placards, labels, manifests, etc., shall be followed. 3. Breakdowns a. In the event of a breakdown, vehicles shall be parked with all wheels off the main roadway, if possible. b. If disablement occurs within 500 feet of a curve, crest of a hill or other obstruction to view, the driver shall place the warning devices (i.e. reflective triangles or flares) in that direction to give traffic ample warning. Warning devices shall be placed no less than 100 feet or more than 500 feet from the disabled vehicle. c. If disablement occurs on a divided or one-way highway, the warning devices shall be placed so that one is 200 feet and another 100 feet to the rear and the third not more than 10 feet to the rear and in no case less than 2 feet to the roadside of the widest portion of the vehicle or load. -9- 4., Passengers a. Employees shall ride in the cab of trucks, where possible. b. When employees must ride in the back of flatbed trucks, dump trucks or pickup trucks, they shall sit on the truck bed. H. Accidents Employees shall report vehicle accidents to their supervisors as soon as possible. 1. Insurance forms are carried in the glove compartments of company vehicles, should be used to gather essential information at the scene of the accident. 2. When a vehicle accident occurs, the employee shall: a. Pull off the road, if possible, to avoid obstructing traffic. b. Place warning reflectors or flares on the road as necessary. c. Render aid to injured persons. d. Report the accident to police, and e. Report accident to supervisor as soon as possible. f. .Not enter into an argument with other persons involved, and g. Not make admission of liability or offer settlement of claims. h. Only leave the scene to report the accident to police or to obtain medical help if no one else is available. Section VI-Tools and Maintenance Equipment A. General Hand Tool Practices 1. There is a proper tool for every job. The proper tool shall be used at the appropriate time. 2. Do not use defective tools. Tools should be inspected by employee before being used to determine if they are the proper size and in good condition. If they are not in good condition, report this fact to your supervisor. 3. Do not carry sharp tools in pockets. 4. Upon completion of a job, tools should be cleaned and returned to the tool box or storage area. 5. Wrenches shall have a good bite before pressure is applied. Brace yourself by placing your body in the proper position so that in case the tool slips, you will not fall. Make sure hands and fingers have sufficient clearance in the event the tool slips. When possible pull on a wrench. 6. Never use a wrench as a ha, met. 7. Never use a tool with a "mushroom" head. 8. Never use a screwdriver for a chisel. 9. Pressure equipment such as grease guns, paint and garden sprayers shall be directed away from the body and other personnel in the area. The person operating any equipment such as this, which has a potential for eye injury shall wear protective goggles. B. Snipes (Cheaters) 1. Mmployees using snipes shall exercise care and judgement, making sure that both snipe and wrench are suitable for the job at hand. 2. Snipes shall not be used on spanner wrenches. 3. Snipes shall be less than twice the length of the wrench handle and shall fit the wrench handle closely over its entire length. 4. Longer snipes may be used on specialty tools made of forged steel such as box end hammer wrenches. 5. Employees shall not stand or jump on tools or snipes when breaking or making up connections. C. Portable and Stationary Grinding Wheels 1. Grinding wheels should always be handled with care and never dropped or bumped.. 2. A grinding wheel shall never be run at a speed greater than the maximum speed marked on the wheel or specified by the manufacturer - check rating before installing. 3. Approved and trained personnel shall mount grounding wheel. 4. Onlywheels designed for side grinding shall be used for this type of operation. 5. Never make adjustments while thew heel is in motion. 6. Goggles shall always be worn when grinding and a full face shield when necessary. 7. Grinders shall have eye shields and properly adjusted tool rests. D. Ladders 1. Before using a ladder, visually inspect it; a defective ladder shall be reported to your Supervisor and shall not be used. 2. When ascending or descending, always face the ladder and have both hands free for climbing. Tools should be carried in a belt or raised/lowered by rope. 3. When working on or near electrical equipment, never use metal ladders. -11- 4. Ladders shall be set at the correct angle. The base should be out one-fourth the distance of the height. 5. Ladders shall be set on a firm base and tied at the top. Ladders should be equipped with anti-slip safety feet. Someone should steady the ladder, if needed. 6. When working from a ladder, both feet should be kept on the rungs. 7. Long reaches should be avoided; move the ladder first so as to keep hips between the ladder side rails. 8. Never stand on top step of step ladders. 9. Wood ladders shall not be painted. Paint covers cracks and other defects. E. Heavy Equipment 1. Drivers of heavy equipment shall: a. Request instruction, if operational procedures are not understood. b. Choose gears to avoid lugging the engine. c. ~en descending grades, select a lower gear to assist in checking speed. In general, the gear selected should be the same gear that would be necessary in climbing such grades. d. Use brakes to control speed and ensure that the engine does not exceed the maximum allowable rpm. 2. Repairs must not be made to powered equipment until workers are protected from movement of the equipment or its parts. Safety Meetings It is the policy of this company to hold monthly safety meetings to the personnel involved in the job. The meetings explain: a. The steps involved in the job, b. Potential hazards and safeguards to control the hazards, c. Special personal protective equipment to be used, d. Gas testing requirements, e. Availability of fire fighting equipment and its use, f. The need for responsibilities, and training of standbys, fire watches, etc., and g. Emergency and rescue procedures. -12- ' FIRE DEPARTMENT ~TO: ~ j FIRM OR D.B.A. CORRECT ALL tO~E O~TION VIO~TIONS I CHECKED BELOW Violation No. REQUIREMENTS .': Combustible waste / 1 Remove and safely dispose of all hazardous refuse and d~y vegetation on th~ above premises (U. FC.) dry vegetation 2 Provide noncombustible containers wit~~s~ for the storage of combustible waste and rubbish pending its safe disposal. (U. FC.) Combustible Storage' 3 Relocate combustible sro,age to pro feet c~ around moro, tuse bonfire door .......................... (NEC.) (U.F.C. , hen In on brackets will, the t~,e extingUlshern°'~;;; feet above the floor ,F PA ~ ,O ; Extin0uishers 4 Relocate fir. extin,~q s) so.t~ ~.~ey will be in a~p.ciou~atio , O' g p . g' . { .... 5 = Provide and ~a~l~ ~ ] ~ ~ ~appr0ved ........................ (type ~ s'ze) podab ' , ' g ' ~ be ~m a~ately accessible for use ................................................. (area). ( . .C. Signs 7 Provide and maintain "EXIT" sign{s)~t~s 5 ~h~ in height over each required exit (door/window) to fire escape. (U.F.C.) 8 Provide and maintain appropriate numbers on a contrastin9 background and .visible from the street to indicate the correct address of the building, (B. MC.) (U.F.C.) Fire doors/fire Separations, 9 Repair ali (cracks/hole~openings) in plaster in (location), Plastering shall [etum the su~ace to its original fire resistive co.trion. (U.B.C, Remov~Repair) (item merchanical device, or by an approved smoke and heat sensitive device, Serf-closing doors shall have no aUachments capable of preventing the operation of ~e closin9 device. (U. FC. Exits Remove all obstruction from hal~ays. Maintain all means of egress free of any storage. (UF.C.) 2 Provide a contrasting colored and permanently i~talled electric light ~er of near required exit (location)_ to cleady i~icate it as an ex~ {U.F.C.) Storage 3 Remove ali storage ancot other obstructions from ( fire ~ca~ landings and stai~ays stair shafts). (Fire escape~stai; shafts are to be maintained frm from obs~uctions at all times.) ( U, F. C. Electrical Appliances 14 Extension cords shall not be used in lieu of permanent approved widn9. Install additional approved electrical outlels where n~ed. (N.E.C.) (U.F.C.) 5 Remove muli~ple aUachment co~s from specified electrical convenience outlet (one plug per outlet). (N.E.C.) (U.F.C.) 'D~er I ~ REQUIREMENT ON I / ~ /19~N ,NSPE~ION WILL BE MAD~ IF .O COMPUANC~ r. ~ SignOre THIS NOTICE BY MAIL OR IN PERSON, TO: ~. ~PECT~R INSPECTOR ~im ~llen ~13 LEGEN~ U.F.C. Uniform Fire Code ~91~ Sane ~oaa u...c. Uniform Building Code Bake~i~d, CA ~13 B.M.C. Bakersfield Municipal Code N.F.P.A. National Fire Protection Association Phen~ 3~-8159 N...c National Electric Code Plan I ;' -.,'.' ~J '.'.:.- '- . .' c~.. "-.L c:, .... '.. ~..::. '' ' .,-.':'"..-' .'~ ': ' : ,, CITY of BAKERS:FIELD Far. and Agriculture 1-] Standard Business ELHAZARDOUS HATER'I'ALS 'rNVENTORY NON--TRADE SECRETS Pqe z_. ~f~ BUSINESS NAME:"F-~--4~W/V~4-- .~_...,'/,~,,~_.~_4/,~_ OWNER. NAHE: NAME OF THIS FACILITY: CITY, ZIP: ~,~'.3",~ ~.5'.~,/~ CITY, ZIP: DUN AND BRADSTREET NUMBER ............ ' '-'-~ - ~REFER TO-'iNSTRUUT'ION,5 FUR PROPER CODES -- 1tins !~Ra I~x Xvtrp~e Annual R.e. asure I GoflL Gont; ~so~~ Code coo~ Aat Amc Est units off e ~yPe $ /emp Storea tn Iici/try Sge lnstructlon~.. Physical and HeBith Hazard C,A,S, Humber Component tl Nile I C,A,S, Humber .. (Check all Lh8[ 8pplyl CoBpon~n[ I~ Msim & C,A,S, Kuaber ~ Fire Hazlrd ~ Re8ctiviti ~ Delayed B ~uddefl Release ~ Immediate Phviicli lad P~llth Pl~ard C,X,S. Number Component II Jl~ I C,A,S, ColponmnL Nulber He~/th of Pressurt la He~ith COlpOneAt 13 NIne I C.A.S. Number PhysicBI Ind ~ellth HIzBrd C.A.S, Number Component I! Nile I C,A,S, Nulber tCheck 811 that Bpply) I ~ire Hazard ~ Reactivity ~ 0el8yed ~ SuddBn Release ~ llmedi4te Component Nile C.A.S. Number Health of Pressure Health Component 13 Nile I C.i.S. Number Physical Ind Health Hlzlrd C,A,S, Humber. Componen~ II NI~o t C,A,S, Number (Check all ~hat lpply} ~ire H~zard ~ Reactivity ~ Delayed ~ Sudden Release ~ Component 12 Nile Number HealTh of Pressure Hei Coaponefl& 13 Name & C,A,S. Number QBe ' Phone N~me erLifi,tioq (Re~d ~nd sfgn a~c compl~Cfpg.a~ secCfpnq) .cerHty under pen~R~ of)8p thqt l hBvepersonqly, ex~alnqQlqo p taailla[VitbLhe/nlo[BBHpn ~ubliLtpd iff this Ind 811 ac~4¢ned.dQctBefl[~, I,~ ~[ oased off. By ~flquiry 9r.cnose ~nomouafs responsible tot ob~llfllfl9 [A~ lArorllcIofl. I believe [hl[ [he SUB,trico, hi OrB lit Off 1, true, ICC UtiLe, ,no COB piece. e e,~ ofici~l ctcle dt ovner/ooerlcor u, ovflertoper,zor's authorized represeflclcive ~ignacure CITY of BAKERSFIELD Farm ama Aeticulture ~ Standard Business I~HAZARDOUS MATERIALS INVENTORY NON--TRADE SECRETS ON; ~ ~~ ~ ~ '- ADDRESS: STANDARD IND. CLASS CODE: ..... ~IP:~~ ~~/~ CITY. ZIP: DUN AND BRADSTREET NUMBER .............. ' ~- REFER TO~NS~UC~DNS~RDP~ CODES -- 1rams tyre ~ax Av9rHe Annual ~asure I ~ont gont ~ont Usee Location.~he[e ~JxturelCoeoonents Code come AeC Aec Est units an e ~yge ~rass ~ema ~torf~ In facility See Instructions Physical and ~ealth Hazard C.A,S. Number Component II Name I C.i.S. Number ~ .. (Check ali LhaL apply) · ' Component I~ Name & C.A.S, Number ~re Hazard ~ Reactivity ~ Delayed ~ Sudden Release ~ Immediate Health of Pressure Health Component 13 Hame i C.k,S. Number ~ Fire Hazard ~ Reactivity ~ Delayed ~ Sudden Release ~ Immediate Component Il Nike I C.l.l. Number Hem/Lb of Pressure Hca i th Component 13 N,me I C,A.I, Humber Physical ond ~e~l[h Hszud C.i.S. HuBber CoBpo~en[ II JIBe I C3,~, Number Hem Ith of Pressure He41 th Component 13 Nile i C,A.S, Number Hem l~h of Pressure Health Component 13 Name I C.A.S. Number a~e ' Title" Z4 fir Phone' Name erti[i{atioq .(Re~d ~nd sfgn after comple:fog.all securing) - cer~t~y unoer pena~c~ oIUF that l have~ersonal~Lexaela~tqap taai~ac.~it~ the~n~oreaugn ~u~aittf~ in this.tN all at~ag~ed.d~cgeent~, an~ t~a[ eased on.el ~nquiry 9[.those ~no~vtoua~s responsiHe tot obtaining the tn~oraaHon. ] be~teve that the suoaltted Iflrorll[IOfl IS true, Iccurlte, Ina complete. CITY of BAKERSFIELD ~HAZARDOUS MAT ERIAL8 INVENTORY Carl and Agriculture 5~andard Business NON--TRADE SECRETS Page BUSINESS NAM£:~-~--~!~,~-~'/~,'~,~_ OWNER NAME: NAME OF THIS FACILITY:. LOCATION; ~ - ADDRESS: STANDARD IND. CLASS CODE:- CITY. ZIP: / CITY. ZIP: DUN AND BRADSTREE] NUMBER PHONE -- REFER 70~RS~OD~DN3 ~O. HROP~ CODES Code LOOm Ant Asr Est Un,ts on e [ype ~ress Physical and Health Hazard C.A.5. Number Component II Mate I C.A.~. ~utber ' (Check all tha~ ' Co=ponent I~ ,a,e I C.A.5. Number ~ Fire Hazlrd ~ Reactivit~ ~ Delayed ~ Sudden Release Health of Pressure Health Co,~onenL 13 Name I C.A.S. Number Physicll I~d Health 8~z~rd C.A.5. Number Componen~ II ll~! t C.A.8. lumber Co,ponenL I~ ,m I C.A.S. ,umber ~ Fire ~azard ~ Reactivity ~ Delayed ~ Sudan Release Hen I~h of Pressure Coa~onent 13 Nm S C.A.S. ,umber Physical ~nd Health Hazard C.A.5. Number Component II h,e I C.A.S. Number [Che:~ all that a~ly) Component I~ Name S C.A.5. ,u,ber ~ Fire Hazard ~ Reactivity ~ Delayed ~ ~udden Release ~ ]a,ediate Health of Pressure Health Component 13 Name I C.A.5. Number Physical ~nd Health Hazard C.i.S. Number. Component II Na~, I C.A.5. Number ~ (Check ail ~hat applyl Component I~ Na~s I C.A.i. Nu,ber ~ Fire Hazard ~ Reactivity . ~ ~elayed ~ Sudden Release ~ laaediate Health of Pressure Health Co,ponent 13 Naae I C,A,5. Nu,ber .cerH~y.unoer penney o~y ~h~c l naveperson~.eXaaln~g~qo ta a~a~ngd.o~cveen~, anG t~t based on.my mquiry ~.cnose momouats respons~ute ~r obtaining cna ~mormac~on. ] betleve ~haL ~he L-4638-A MATERIAL SAFETY DATA SHEET September 1985 An explanation of the terms used herein may be found in OSHA ?9 CFR 1910.1200, available from OSHA regional or area offices. (Essentially similar to U.S. Department of Labor Form OSHA-20 and generally accepted In Canada for Information purposes) .' Do Not Duplicate This Form. Request an Original, PRODUCT Oxygen CHEMICAL NAME Oxygen SYNONYMS Not applicable FORMULA O; CHEMICAL FAMILY Not applicable MOLECULAR WEIGHT 32.00 TRADE NAME Oxygen For mixtures of this product request the respective component Material Safety Data Sheets. See Section IX. MATERIAL (CAS NO.) Wt (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Oxygen (7782-44-7) 100 None currently established (None currently established) BOILING POINT, 760 mm. Hg -183°C (-297.4°F) FREEZING POINT -218.4°C (-361.1 °F) SPECIFIC GRAVITY (H20 = 1) Gas VAPOR PRESSURE AT 20°C. Gas VAPOR DENSITY (air = 1) 1.105 @ 25°C SOLUBILITY IN Negligible WATER, Fo by wt. 'EVAPORATION RATE PERCENT VOLATILES 100 Not applicable BY VOLUME (Butyl Acetate = 1) APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure. IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 1-800-UCC-HELP (1-800-822-4357) In Canada 514 -- 640~6400 For routine information contact your local supplier Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION [] LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION Copyright © 1985 Union Carbide Corporation Page 1 o! 4 PRODUCT: Oxygen L-4638-A September 1985 THRESHOLD LIMIT VALUE: None currently established. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING -- No evidence of adverse effects from available information. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- Breathing 80% or more oxygen at atmospheric pressure for more than a few hours may cause nasal stuffiness, cough, sore throat, chest pain and breathing difficulty. Breathing oxygen at higher pressure increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause lung damage and also central nervous system effects resulting in dizziness, poor coordination, tingling sensation, visual and hearing disturbances, muscular twitching, unconsciousness and convulsions. Breathing oxygen under pressure may cause prolongation of adaptation to darkness and reduced peripheral vision. SKIN CONTACT -- No evidence of adverse effects from available information. EYE CONTACT -- No evidence of adverse effects from available information. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: See "Notes to Physician." MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: See "Notes to Physician." SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY ANO FIRST AID PROCEDURES: SWALLOWING -- This product is a gas at normal temperature and pressure. SKIN -- No emergency care anticipated. INHALATION -- Remove to fresh air. Give artificial respiration if not breathing. Keep victim warm and at rest. Call a physician. EYES -- No emergency care anticipated. NOTES TO PHYSICIAN: Supportive treatment should include immediate sedation, anti-convulsive therapy if needed, and rest. Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, increases the susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate that vitamin E deficiency may increase susceptibility to oxygen toxicity. Airway obstruction during high oxygen tension may cause alveolar collapse following absorption of the oxygen. Similarly, occlusion of the eustachian tubes may cause retraction of the eardrum and obstruction of the paranasal sinuses may produce "vacuum-type" headache. Newborn premature infants exposed to high oxygen concentrations may suffer delayed retinal damage which can progress to retinal detachment and blindness (retrolental fibroplasia). Retinal damage can also occur in adults exposed to 100% oxygen under greater than atmospheric pressure, particularly in individuals whose retinal circulation has been previously compromised. All individuals exposed for long periods to oxygen at high pressure and all who exhibit overt oxygen toxicity should have ophthalmologic examinations. WHEN USED IN WELDING AND CUTTING: Read and understand the manufacturer's instructions and the precautionary label on the product. See American Standard Z49.1 "Safety In Welding and Cutting" published by the American Welding Society, RO. Box 351040, Miami, Florida 33135 and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail. For further SAFETY AND HEALTH information, refer to Linde's free publication, L-52-529, "Precautions and Safe Practices for Electric Welding and Cutting", as well as L-2035, "Precautions and Safe Practices for Gas Welding, Cutting, and Heating." You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Linde Division, Communications Department, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. NOTE: Suitability for use as a component in underwater breathing gas mixtures is to be determined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the effects, methods, frequency and duration of use, hazards, side effects and precautions to be taken. Fage 2 of 4 PRODUCT: Oxygen L-4638-A September 1985 FLASH POINT [ AUTOIGNITION Not applicable (test method) Not applicable TEMPERATURE I FLAMMABLE LIMITS LOWER Not applicable UPPER Not applicable IN AIR, % by volume EXTINGUISHING MEDIA: Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (i.e. safety shower) is the preferred extinguishing media for clothing fires. SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately cool containers with' water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxidizing agent, vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion. Container may rupture due tO heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125°F). Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. Smoking, flames and electric sparks in the presence of enriched oxygen atmospheres are potential explosion hazards. STABILITY CONDITIONS TO AVOID: See Section IX. UNSTABLE STABLE X INCOMPATIBILITY (materials to avoid): Combustible materials, asphalt, flammable materials, especially oils and greases. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: None currently known. May Occur I Will not Occur I X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area. Remove all flammable materials from vicinity. Oxygen must never be permitted to strike an oily surface, greasy clothes, or other combustible material. WASTE DISPOSAL METHOD: Slowly release into atmosphere, in an open, outdoors area. Remove all flammable materials from vicinity. Page 3 of 4 PRODUCT: Oxygen L-4638-A September 1985 RESPIRATORY PROTECTION (specify type}: Not required. LOCAL EXHAUST -- Not applicable. MECHANICAL (general) -- Acceptable. VENTILATION SPECIAL -- Not applicable. OTHER -- Not applicable. PROTECTIVE GLOVES: Preferred for cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. WARNING: High pressure gas. Vigorously accelerates combustion. Avoid contact with oils, greases and other flammable materials. Never use manifolds for oxygen cylinders unless specifically designed for such use. Use only with equipment conditioned for oxygen service. Use piping and equipment adequately designed to withstand pressures to be encountered. Protect container against physical damage. Isolate from combustible gas installations and combustible materials by adequate distance or by gas-tight, fire-resistive barriers. Protect against over-heating. Never use an oxygen jet for cleaning purposes of any sort, especially clothing, as it increases the likelihood of an engulfing fire. Note: Reverse flow into cylinder may cause rupture. Use a check valve or other protective apparatus in any line or piping from the cylinder to prevent reverse flow. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all labels and other instructions supplied with all containers of this product. NOTE: Compatibility with plastics should be confirmed prior to use. For safety information on general handling of compressed gas cylinders, obtain a copy of pamphlet P- 1, "Safe Handling of Compressed Gases in Containers" from the Compressed Gas Association, Inc., 1235 Jefferson Davis Highway, Arlington, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. Never lubricate oxygen valves, regulators, etc., with any combustible substance. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. . LINDE o .c s IN THE USA: IN CANADA: e UNION CARelL~E Union Carbide Corporation Union Carbide Canada Limited Linde Division Linde Division 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P 1J3 _.~ Other offices in principal cities all over the world. L-4638-A 85-0928 9/85 45M Lithographed in U~S.A. Page 4 of 4 MATERIAL SAFETY DATA SHEET Shell MSDS NUMBER ~ 60, ] ]0-~ PAGE 97367 SHELL: 713-473-9461 CHEMTREC: 800-424-9300 SHELL: 713-241-4819, SA '- , I READ OUR PRODUCT ~¢UTE HEARTH , FlEE REACTIV'IT¥ ~AFETY INFORMATION PASS IT ON ,, HIGH ' 3 EXTREME ' d.~/M:IP/~.ODUCTLU~IILITYI,.A~ #For acute and chronic health effects refer to the discussion in Section III / · SHELL MOTOR O[L 30 PRODUCT CHEMICAL MIXTURE (SEE SECTION II-A) NAME ~ CHEMICAL ~1, PETROLEUM HYDROCARBON; MOTOR 01'L FAMILY -~HELL ~ 52033 CODE SECTTON :[T-A PRODUCT/ZNGREDZ ENT NO. COMPOSZTZON CAS NUMBER PERCENT P SHELL MOTOR OZL 30 M]~XTURE t00 * ' 1 SOL. REF., HYDROTREATED HEAVY PARAFFTN~C D~ST. 64742-54-7 50-75 2 SOL. REFINED, HYDRDTREATED ACID TREATED HEAVY NAPHTHENIC DIST. 64'742-18-3 0-50 3 SEVERELY HYDROTREATED HEAVY NAPHTHEN1~C DTST. 64742-52-5 0-20 4 SOL, REF., HYDROTREATED RES[DUAL OIL 64742-57-0 0-35 5 MINOR ADDITIVES MIXTURE <2 SECTI'ON XZ-B ACUTE TOX:~CZTY DATA NO. ACUTE ORAL LDSO ACUTE DERMAL LDSO ACUTE ZNHALAT]:ON LC50 P NI~T AVA[ LABLE BASED UPON DATA AVA~.LAELE TO SHELL, COMPONENT 5 [N TH]:S PRODUCT ]:S NOT HAZARDOUS UNDER OSHA HAZARD COMMUN~'CAT[ON (29 CFR 1910.1200). SECTZON ZZZ HEALTH ZNFORMATZON THE HEALTH EFFECTS NOTED BELOW ARE CONSTSTENT IdTTH REOUZREHENTS UNDER THE OSHA HAZARD COMMUN]'CATZON STANDARD (29 CFR 1910.1200), EYE CONTACT LUBR1~CAT:[NG 01'LS ARE GENERALLY CONSZDERED NO MORE THAN M1~NZMALLY 1'RRTTAT]~NG TO THE EYES. SKZN CONTACT LUBR]'CAT]NG OTL$ ARE GENERALLY CONSTDERED NO MORE THAN MZLDLY ]~RR1'TATTNG TO THE SKI'N. PROLONGED AND REPEATED CONTACT MAY RESULT TN VAR1~OUS SKIN D:[SORDERS SUCH AS DERMAT1'T~rS, FOLL:[CULTTZS OR ACNE. ZNHALATZON ...... : ~NHALAT]~ON OF VAPOR (GENERATED AT H:[GH TEMPERATURES ONLY) OR O[L MIST FROM THINS PRODUCT MAY RESULT TN MZLD [RR[rTATTON.OF,.THE_~ UPPER RESP:[RATORY TRACT. NAME: SHELL MOTOR OZL 30 MSD$ ':,$0,.11.0...-4 PAGE '2 LUBRZCATZNG OZLS ARE GENERALLY CONSZDERED NO MORE THAN SLZGHTLY TOXZC ZF S~ALLO~ED. SZ~S ~D SYMPTOMS " ,~IRRITATION AS NOTED ABOVE. ' *~' 4 ~* : A~RAVATED HEDZCAL ~NDITION$ PREEXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. OTHER HEALTH EFFE~S THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER HAS DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE CARCZNOGENZCITY IN EXPERZMENTAL ANZ~ALS OF USED MOTOR OZLS. HANDLZNG PROCEDURES AND SAFETY .PRECAUTIONS [N THE ~SDS SHOULD BE FOLLOWED TO H[N[HZZE EMPLOYEE'S EXPOSURE TO THE USED PRODUCT. SE~ZON ZV OC~PATZO~L EXPOSURE LZM[T$ OTHER NO. PEL/T~A PEL/CE~ L;~ TLV/THA TLV/$TEL ~P 5 MG/M3* NONE 5 MG/M3* 10 MG/M3* NONE *OIL HIST, H~NERAL SE~ZON V EMERGE~Y ~ FZRST AZD PROCE~RE$ EYE ~A~ FLUSH ~ITH ~ATER FOR 15 M[NUTES ~HZLE HOLDING EYELIDS OPEN. GET MED[CAL ATTENT[ON. SKZN ~A~ REMOVE CONTAMINATED CLOTHING AND ~[PE EXCESS OFF. ~ASH ~[TH SOAP AND ~ATER OR A ~ATERLESS HAND CLEANER FOLLOWED BY SOAP AND ~AT~R. [F IRRITATION OCCURS, GET MED[CAL ATTENTION. Z ~ALAT Z ON REMOVE V~CT~ TO FRESH AZR AND PROVIDE OXYGEN ~F BREATHING ~S D~FF~CULT. GET ~ED~CAL ATTENTION. ZNGESTZON DO NOT [NDUCE VOMZT[NG. ZN GENERAL NO TREATMENT ZS NECESSARY UNLESS LARGE QUANTZTZES OF PRODUCT ARE ZNGESTED. HOWEVER, GET MEDICAL ATTENTION. ~TE TO IN GENERAL, EMESIS INDUCTION I'S UNNECESSARY IN HIGH VISCOSITY, LO~ VOLATILITY PRODUCTS, Z.E., MOST .OILS AND GREASES. SECTION Vl SUPPLEMENTAL HE~TH ZNFOE~TION NONE IDENTIFIED. SE~ZON VZZ P~S~ DATA BOZL[NG POINT: NOT AVA[CABLE SPEC[F[C GRAVITY: 0.9042 VAPOR PRESSURE: NOT (DEG F) (H20-1) (MM HG) ,MELT[NG POZNT: -5 (POUR POZNT) SOLUBZLZTY: NEGLZGZBLE VAPOR DENSZTY: NOT AVAILABLE (DEG F) (ZN ~ATER) (AZR-I) PRODUCT N/tHE: SHELL HOTOR OZL 30 , ,,HSDS 60,110~4 ~.~ ~ PAGE 3 EVAPORATION RATE (N-BUTYL ACETATE · 1): NOT AVAILABLE APPEARANCE AND ODOR: DARK AMBER LIQUID. SLIGHT HYDROCARBON ODOR. SECTZON VZZZ FZRE AND EXpLOSZON I'L~,ARDS .................... ...... ....... .... ....... .... r-: .... ,' FLASH POINT AND HETHOD: FLAHHABLE LIHZTS /% VOLUHE ZN AIR' 370 DEC F (PMCC) , ,: .... ~ LOWER: .N/AV U~PER: N/Ay. EXTINGUISHING HEDZA USE WATER FOG, FOAM, DRY CHEMICAL DR C02. DO NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER. SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE-SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD. BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE-PRESSURE NIOSH-APPROVED SELF-CON~AINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. SECTION ZX REACTZVZTY STABILITY: STABLE HAZARDOUS POLYHERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: AVOID HEAT, OPEN FLAMES AND OXIDIZING MATERIALS. HAZARDOUS DECOMPOSITION PRODUCTS THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE SOLID. LIQUID, PARTICULATES AND GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS DR COMBUSTION. CARBON MONOXIDE AND OTHER UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON COMBUSTION. SECTION X EHPLOYEE PROTECTION RESPIRATORY PROTECTIONr' IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SECTION IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS AND PARTICULATES. PROTECTIVE CLOTHING WEAR CHEMICAL RESISTANT GLOVES AND OTHER PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE SKIN CONTACT. WEAR SAFETY GOGGLES TO AVOID EYE CONTACT. TEST DATA FROM PUBLISHED LITERATURE AND/OR GLOVE AND CLOTHING MANUFACTURERS INDICATE THE BEST PROTECTION IS PROVIDED BY NITRILE GLOVES. SECTZON X! ENVZRONHENTAL PROTECTZON SPILL OR LEAK PROCEDURES MAY BURN ALTHOUGH NO READILY IGNITABLE. USE CAUTIOUS dUDGMENT WHEN CLEANING UP LARGE SPILLS, *** LARGE SPILLS *** WEAR RESPIRATOR AND PROTECTIVE CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO, DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY. SAND. OR OTHER SUITABLE MATER[ALS; DISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. *** SMALL SPILLS *** TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY. WASTE DISPOSAL .[~ PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE WITH LOCAL REGULATIONS. ENVZRONHENTAL HAZARDS THIS PRODUCT IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN WATER ACT. SPILLS ENTERING (A) · · SURFACE WATERS OR (B) ANY WATER COURSES OR SEWERS ENTERING/LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER. 800-424-8602. PRODUCT..~.,E: SHELL 140TOR OZL 30 "' I~ISD$ ' ~O,1. tO~-4 'L'"",?- PAGE 4 .... . ,. ~ ,'~pl :. SECTION XZZ SPECZAL PREC~TZONS ~IN~MZZE SKiN CONTACT. WASH W~TH SOAP AND '~ATER"BEFORE~EAT~NG, DRiNKiNG, S~OK~NG OR USING TO~LET FACiLiTiES. LAUNDE~ CONTAMINATED CLOTHING BEFORE REUSE. PROPERLY D~SPOSE OF CONTAmiNATED LEATHER ARTICLES, ~NCLUD~NG SHOES, TNAT CANNOT SE DECOnTAMiNATED. STO~E IN A COOL, D~Y PLACE ~ITH ADEOUATE VENTiLATiON. KEEP A~AY FROM OPEN FLA~E$ AND N~GN TEMPERATURES. SE~[ON XZZZ T~SPORTATZON RE.IREnE.S DEPARTMENT OF T~ANSPORTATZON CCASSZFZCA'TZON: NOT HAZARDOUS BY D,0,T. REGU~ATZONS' SECTZON XZV OTHER REGULATORY CONTROLS THE COMPONENTS OF THZS PRODUCT ARE LISTED ON.THE EPA/TSCA INVENTORY OF CHEMZCAL SUBSTANCES. THE '[NFORMATTON CONTA~'NED HEREIN 1S BASED ON THE DATA AVATL'ABLE TO US AND :~S BEI'TEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR TMPL:[ED REGARDTNG THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTA][NED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSI'B1~LTTY FOR TNdURY FROM THE USE.OF THE.. PRODUCT DESCRY:BED HERETN. DATE PREPARED:OCTOBER 02, t985 ,.;~ .::.1.~,~ ~ dOHN P. SEPES! BE SAFE READ OUR PRODUCT SHELL OZL COHPANY SAFETY ZNFORIIATZON ., .AND PASS ~'T ON PRODUCT SAFETY AND COHPLJ:ANCE (PRODUCT LI'ABZLZTY LAW P. O. BOX 4320 · . REQUZRES 1~T), HOUSTON, TX 77210 ~" 'L;~'~"~)'''1 ; ~f' :~ ~ "~'" 1': - L-4559-E · MATERIAL SAFETY DATA SHEET Apr, 19s7 An explanation of the terms used herein may be found in OSHA 29 CFR 1910.1200, available from OSHA regional or area offices. " (Similar to U.S. Department of Labor Form OMB No. 1218-0072 and generally accepted In Canada for Information purposes) Do Not Duplicate This Form. Request an Original. PRODUCT Acetylene CHEMICAL NAME Acetylene ' SYNONYMS Acetylen, Ethine, Ethyne, Narcylene FORMULA CaH2 CHEMICAL FAMILY Alkyne MOLECULAR 26.038 WEIGHT TRADE NAME Acetylene (This product is intended for welding and cutting use.) This section covers the materials fro.m which this product is manufactured. The fumes and gases produced during welding and cutting with the normal use of this product are covered by Section VI. The term "hazardous" should be interpreted as a term required and defined in OSHA 29 CFR 1910.1200 and does not necessarily imply the existence of any hazard. MATERIAL (CAS NO.) Vol (%) 1986-1987 ACGIH TLV-TWA (OSHA-PEL) Acetylene (74-86-2) 100 Simple asphyxiant (None currently established) Acetylene cylinders are filled with a porous material containing acetone into which the acetylene is dissolved. ACGIH has established a TLV-TWA of 750 ppm for acetone and a STEL of 1000 ppm. BOILING POINT, 760 mm. Hg Not Applicable SUBLIMATION POINT -84°C (-119.2°F) @ ?60mm Hg SPECIFIC GRAVITY (H=O = 1) Not Applicable VAPOR PRESSURE AT 21 °C. 635 psig VAPOR DENSITY (air = 1) 0.91 SOLUBILITY IN Slight WATER, % by wt. EVAPORATION RATE PERCENT VOLATILES 100 Not Applicable BY VOLUME (Butyl Acetate = 1) APPEARANCE AND ODOR Colorless gas at normal temperature and pressure; garlic-like odor. IN CASE OF EMERGENCIES involving this material, further information is available at all times: uJ In the USA 1-800-UCC-HELP (1-800-822-4357) In Canada 514--640-6400 ¢~ For routine information contact your local supplier u3 Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product .~ hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors ~ of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its *~-- customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION [] LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION Copyright © 1985, 1986, 1987 Union Carbide Corporation Page 1 of 4 PRODUCT: Acetylene L-4559-E April 1987 THRESHOLD LIMIT VALUE: Acetylene - Simple asphyxiant ACGIH 1986-87; Acetone, 750ppm ACGIH 1986-87 EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE SWALLOWING -- An unlikely route of exposure, but frostbite of the lips and mouth may result from contact with the liquid. If the liquid is .swallowed, may cause nausea. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- Asphyxiant. Moderate concentrations of vapor may cause headache, drowsiness, dizziness, nausea, vomiting, excitation, excess salivation, and unconsciousness. SKIN CONTACT -- No harmful effects expected from vapor. Liquid may cause frostbite. EYE CONTACT -- Vapor may cause irritation. Liquid may cause irritation and frostbite. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: None currently known. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: A knowledge of the available toxicology information and of the physical and chemical properties of the material suggest that overexposure is unlikely to aggravate existing medical conditions. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING -- If liquid is swallowed, do not induce vomiting. Call a physician. SKIN -- For exposure to liquid, flush with water and warm frostbite area with warm water (not to exceed 105°F). In case of massive exposure, remove clothing while showering with warm water. Call a physician. INHALATION -- Remove to fresh air. If breathing has stopped, give artificial respiration; if breathing is difficult, oxygen may be given; call a physician. EYES -- In case of splash contamination, immediately flush eyes thoroughly with water for at least 15 minutes. Seek the advice of a physician, preferably an ophthalmologist, urgently. NOTES TO PHYSICIAN: Aspirated acetone may cause severe lung damage, ifa large quantity of material has been swallowed, stomach contents should be evacuated quickly in a manner which avoids aspiration. Otherwise, treatment should be directed at the control of symptoms and the clinical condition. No specific antidote is known. WORKING WITH WELDING AND CUTTING MAY CREATE ADDITIONAL HEALTH HAZARDS. FUMES AND GASES can be dangerous to your health and may cause serious lung disease.* Keep your head out of the fumes. Do n'ot breathe fumes and gases caused by the process. Use enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone and the general area. The type and amount of fumes and gases depend on the equipment and supplies used. Possibly dangerous materials may be found in fluxes, coatings, gases, metals etc. Get a Material Safety Data Sheet (MSDS) for every material used. Air samples can be used to find out what respiratory protection is needed. Short term overexposure to fumes may result in discomfort such as dizziness, nausea, or dryness or irritation of nose, throat, or eyes. *NOTES TO PHYSICIAN: Acute --Gases, fumes, and dusts may cause irritation to the eyes, lungs, nose, and throat. Some toxic gases associated with welding and related processes may cause pulmonary edema, asphyxiation, and death. Acute overexposure may include signs and symptoms such as watery eyes, nose and throat irritation, headache, dizziness, difficulty breathing, frequent coughing, or chest pains. Chronic --Protracted inhalation of air contaminants may lead to their accumulation in the lungs, a condition which may be seen as dense areas on chest x-rays. The severity of change is proportional to the length of exposure. The changes seen are not necessarily associated with symptoms or signs of reduced lung function or disease. In addition, the changes on x-rays may be caused by non-work related factors such as smoking, etc. A detailed description of the Health Hazards and their consequences may be found in Linde's free publication "Precautions and Safe Practices for Electric Welding and Cutting," L52-529. You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Linde Division, Communications Department, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. Page 2 of 4 PRODUCT: Acetylene L-4559-E April 1987 -- FLASH POINT -17.8°C (0°F)T.C.C. AUTOIGNITION 29g°c (571 °F) .. (test method) TEMPERATURE INFLAMMABLE LIMITS I LOWERAIR, % by volume 2'3% ]UPPER 100O/o EXTINGUISHING MEDIA See paragraphs below. : SPECIAL FIRE FIGHTING PROCEDURES Refer to CGA pamphlet SB-4, "Handling Acetylene Cylinders in Fire Situations." Evacuate all personnel from danger area. Immediately cool containers with water spray from maximum distance taking care not to extinguish flames. Remove ignition sources if without risk. If flames are accidentally extinguished, explosive re-ignition may occur. Use self-contained breathing apparatus. Stop flow of gas if without risk while contining cooling water spray. Remove all containers from area of fire if without risk. Allow fire to burn out. On-site fire brigades must comply with OSHA 29 CFR 1910.156. UNUSUAL FIRE AND EXPLOSION HAZARDS Extremely flammable gas. Forms explosive mixtures with air and oxidizing agents. Container may rupture due to heat of fire. Do not extinguish flames due to possibility of explosive re-ignition. Flammable vapors may spread from leak. Explosive atmospheres may linger. Before entering area, especially confined areas, check atmosphere with approved explosion meter. No part of a container should be subjected to a temperature higher than 52 °C (approximately 125 °F). All containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. Contact with copper, silver, or mercury or their alloys or halogens can cause explosion and be ignited by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static discharge or other ignition sources at locations distant from product handling point. STABILITY CONDITIONS TO AVOID I UNSTABLE STABLE Stable as shipped. Avoid use at pressures above 15 psig. X INCOMPATIBILITY (materials to avoid) Copper, silver, mercury or their alloys, oxidizing agents, acids, halogens, moisture. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition or burning may produce CO/CO2H2. The welding and cutting process may form reaction products such as carbon monoxide and carbon dioxide. Other decomposition products of normal operation originate from the volatilization, reaction or oxidation of the material being worked. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur I Will not Occur Elevated temperature and pressure and/or the presence of a catalyst. I X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Forms explosive mixtures with air (See Section V). Immediately evacuate all personnel from danger area. Use self-contained breathing apparatus where needed. Remove all sources of ignition if without risk. Reduce vapors with fog or fine water spray. Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area. Flammable gas may spread from leak. Before entering area, especially confined areas, check atmosphere with appropriate device. WASTE DISPOSAL METHOD: Prevent waste from contaminating surrounding environment. Keep personnel away. Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with Federal, State and local regulations. Page 3 of 4 PRODUCT: Acetylene L-4559-E April 1987 RESPIRATORY PROTECTION (specify type) -- Use respirable fume respirator or air supplied respirator when working in confined space or where local exhaust or ventilation does not keep exposure below TLV. Select as per OSHA29 CFR1910.134. LOCAL EXHAUST -- Use enough ventilation, local exhaust or both, to keep the fumes and gases below TLV's in the worker's breathing zone and the general area. Train the worker to keep his head out of the · fumes. MECHANICAL (general) ALWAYS WORK WITH ENOUGH VENTILATION VENTILATION SPECIAL Not applicable OTHER Depends on specific use conditions, and location. Use adequate ventilation or personal respiratory protection. See Section IX and OSHA29 CFR1910.252. PROTECTIVE GLOVES Welding gloves recommended EYE PROTECTION -- Wear goggles with filter lens selected as per ANSI Z49.1. Provide protective screens and goggles, if necessary, to protect others. Select as per OSHA29 CFR1910.133. OTHER PROTECTIVE EQUIPMENT -- As needed, wear hand, head, and body protection which help to prevent injury from radiation. and sparks. See ANSI Z49.1. At a minimum this includes welder's gloves and protective goggles, and may include arm protectors, aprons, hats, shoulder protection, as well as substantial clothing. Train the worker not to touch live electrical parts. Fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being worked, the process, procedure and electrodes used. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being worked (such as paint, plating, or galvanizing), the number of workers and the volume of the work area, the quality and amount of ventilation, the position of the worker's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample from inside the worker's helmet if worn or in the worker's breathing zone. See ANSI/AWS F1.1, available from the American Welding Society, 550 N.W. Le Jeune Rd., Miami, FL 33126. Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard Z49.1, "Safety In Welding And Cutting" published by the American Welding Society and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more details. For further safety and health information refer to Linde's free safety booklet L-2035. OTHER HANDLING AND STORAGE CONDITIONS Heat and sparks during use could be the source of ignition of combustible materials. Prevent fires. Refer to NFPA 51B "Cutting and Welding Processes" and NFPA 50 "Oxygen-Fuel Gas Systems." Use piping and equipment adequately designed to withstand pressures to be encountered. Gas can cause rapid suffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. Never work on a pressurized system. Do not strike arc on cylinder. The defect produced by an arc burn could lead to cylinder rupture. Do not ground cylinder. Store in cool, dry, well ventilated area. Do not store near open flames. Electrical equipment should be explosion proof. Do not store with oxygen or other oxidizers. Protect Cylinders from physical damage. Store cylinders in upright position secured to prevent falling over. Refer to CGA Pamphlets P-1 and G-1 for recommendations. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. { , LINDE o,:,=,c,:s IN THE USA: IN CANADA: O UNION CARBIDE Union Carbide Corporation Union Carbide Canada Limited Linde Division Linde Division 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P IJ3 Other offices in principal cities all over the world. L-4559-E 87-0928 4~87 30M Lithographed in U.S.A. Page 4 of 4 t ..... ... -:. L-4631-B '~ ' August 1985 MATERIAL SAFETY DATA SHEET ~ ~ available from OSHA regional or erea offices. (Essentially similar to U.S. Department of Labor Form OSHA-20 : ~ ii..: ..... and generally accepted In Canada for Information purposes) - Do Not Duplicate This Form. Request an Original. PRODUCT Nitrogen CHEMICAL Nitrogen SYNONYMS Not applicable NAME FORMULA N2 CHEMICAL Not applicable FAMILY MOLECULAR 28.01 WEIGHT TRADE NAME Nitrogen EF: .... . .~' '-:' ,:', - ..'.:~."':II. HAZARDOUS INGREDIENTS * ' '' " ", ' . ' ' ' "'~:'~. For mixtures of this product request the respective component Materiel Safety Data Sheets. See Section IX. MATERIAL (CAS NO.) Wt (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Nitrogen (7727-37-9) ,~ 00 Simple asphyxiant (None currently established) BOILING POINT, 760 mm. Hg - 195.8°C ( - 3~.~ FREEZING POINT - ~0°C ( - ~5.8~ .SPECIFIC GRAVITY (H=O · = 1) Gas VAPOR PRESSURE AT 20*C G~ VAPOR DENSITY (air = 1) 0.~7 SOLUBILITY IN WATER, ~ by ~. N~ligiMe PERCENT VOLATILES EVAPORATION RATE BY VOLUME 1~ (B~I Acetate = 1) Not appl~le APPEARANCE AND ODOR ~lo~e~, ~orle~ gas at no~al tem~ratum and pr~ure. .~ '~ ~ ~ ;~.. ..... . ..... ~-.,. ........ ~ '~" ~"~ ..... ' ~" ~. ~ ~ ~:~'~, ~ ?7' ': IN CASE OF EMERGENCIES involving this materi~, fu~her information is available at all times: In the USA ~--7~7 In Canada 514--~5-~11 For routine information ~nta~ your I~al supplier Union Carbide requests the users of this pr~uct to study this Material Safe~ Data Sheet (MSDS) and become aware of pr~uct h~ards and safety information. To promote safe use of this pr~uct a use~houId (1) noti~ its employees, agents and contractors of the information on this MSDS and any pr~uct h~ards and safety information, ~2) furnish this ~me information to each of its customem for the pr~uct, and (3) r~uest such customers to noti~ their employees and du~omers for the pr~uct of the same pr~uct h~ards and ~fety information. UNION CARBIDE CORPORATION ~ LINDE DIVISION UNION CARBIDE CANADA LIMITED ~ LINDE DIVISION ~yfight ~ 19~, 1985 Union Ca~ide ~ratlon P~ ~ ~f ~ PRODUCT: Nitrogen L-4631 -B August 1985 t'HRESHOLD LIMIT VALUE: See Section I1. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING--This product is a gas at normal temperature and pressure. SKIN ABSORPTION--No evidence of adverse effects from available information. INHALATION--Asphyxiant. Moderate concentrations may cause headache, drowsiness, dizziness, excitation, excess salivation, vomit- ing, and unconsciousness. Lack of oxygen can cause death. SKIN CONTACT--Ne harmful effect expected from vapor. Liquid may cause frostbite. EYE CONTACT--No harmful effect expected from vapor. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: Contact with liquid may cause frostbite. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: The toxicology and the physical and chemical properties of the material do not suggest that overexposure is likely to aggravate existing medical conditions. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None cur- rently known. EMERGENCY AND FIRST-AID PROCEDURES: SWALLOWING--This product is a gas at normal temperature and pressure. SKIN CONTACT--For exposure to liquid, immediately warm frostbite area with warm water (not to exceed 105~'F). In case of massive exposure, remove clothing while showering with warm water. Call a physician. INHALATION--Remove to fresh air. Give artificial respiration if not breathing. Give oxygen if breathing is difficult. Call a physician. EYE CONTACT--In case of splash contamination, immediately flush eyes thoroughly with water for at least 15 minutes. See a physician, preferably an ophthalmologist, immediately. NOTES TO PHYSICIAN: Them is no specific antidote. Treatment should be directed at the control of symptoms and the clinical condition. NOTE: ,~uitability for use as a component in underwater breathing gas mixtures is to be determined by or Under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the effects, methods, frequency and duration of use, hazards, side effects and precautions to be taken, I Page 2 of 4 PRODUCT: Nitrogen L-4631-B , August 1985 FLASH POINT AUTOIGNITION (test method) Not applicable TEMPERATURE Not applicable FLAMMABLE LIMITS LOWER Not applicable I UPPER Not applicable IN AIR, % by volume EXTINGUISHING MEDIA: Nitrogen cannot catch fire. Use media appropriate for surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately deluge containers with water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Gas cannot catch fire. Container may rupture due to heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125°F"). Most containers are designed to vent contents when they are exposed to elevated temperature. STABILITY I CONDITIONS TO AVOID: See Section IX. INCOMPATISlLITY {materials to avoid}: U~der certain conditions, nitrogen can react violently with lithium, neodymium, titanium, ozone. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: None cun'ently known. May Occur I Will not Occur X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Evacuate all personnel from danger area. Use self-contained breathing apparatus where needed. Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area· Test area, especially confined areas, for sufficient oxygen content prior to permitting re-entry of personnel. WASTE DISPOSAL METHOD: Slowly release into atmosphere. Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with Federal, state and local regulations. Page 3 o! 4 PRODUCT: Nitrogen L-4631 -~ August 19,85 RESPIRATORY PROTECTION (specify type): Select in accordance with OSHA 29 CFR 1910.134. Respirators shall be acceptable to MSHA and NIOSH. LOCAL EXHAUST--Preferred. MECHANICAL (general)--Acceptable. VENTILATION SPECIAL--Not applicable. OTHER--Not applicable. PROTECTIVE GLOVES: Preferred for cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. / CAUTION: High pressure gas. Use piping and equipment adequately designed to withstand pressures to be encountered. Can cause rapid ~,~.. ffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unex- pected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all labels and other instructions supplied with all containers of this product. For safety information on general handling of compressed gas cylinders, it is recommended that a copy of pamphlet P-l, "Safe Handling of Compressed Gases in Containers;' be obtained from the Compressed Gas Associati0'~, Inc., 1235 Jefferson Davis Highway, Arlington, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it i,,_s,the user's obligation to determine the conditions of safe use of the product. GENERAL OFFICES IN THE USA: IN CANADA: UnionLinde DivisionCarbide Corporation UnionLinde DivisionCarbide Canada Limited O UNION CARBIDE 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P U3 Other offices in principal cities all over the world. L-4~.3_.l~,B.. ~.5-0928 8/85 ~SM ~ Lithographed in U.S.A. Section V --- Reactivity DaM . °~ '~ ' ~ U~ " Co~l~toAvO~' "" · " ' " . . ,, ,:,,L.. None '" ~' ~'.., ~.~1 ~" '-,.' ..... I~tlbllily ~4,/411~4LI IO AvO~ N o n e None · ":..' 14izamoul May 0oo~ Ooa~om to Av~i~ _ .. Polym~zm~ None Wd Nm Ooc~' ........ ' '~-Ikm VI -- Health Hlzmrd .=ti ' -.. ,x :':Health hazards due to radioactive contam£nation may be chronic or acute . ,,.::i':-. :m,dependi,ng,__ upon the amount released and ingested. Normally acute and chronic '~",health hazards are minimal due ~o sma~ amoun~ o~ ~a'dioac~ive ~od~:~l"-'~: "?" ~..T~e~..o~qan is ~he ~hz~id ~land. Iodine is se~ec~ive~7 ~aken up by · ~hy~oid ~o be used ~o make ~hT~oxine and ~iiodo~hyonine. Thes'~ a~e hormones ~~ .......... ~~~~ ~ha~ control ~h~ basa~ metabolic ~a~e. . .-... I I ~ol~ow ~econ~amina~ion p~ocedu~s ~ ~ton VII ~ P~uUonB for hfe H~ndllng ~nd UBe ~'~ff~r to company i~-hous~ ~adia~ion saffe~y p~og~a~ ~ . Conditions .be speciffi~d in company ~adia~ion saff~y manua~ and ~icense, :4 Normal iff allowed ~o decay b~low limits speciffi.ed by NRC and/or ~~ ~ ~ T~ m ~ ~ ~ ' - ~ ' ,~.,. ~. ~n~amina~ion Haza~ (P~o~ec~ive c~o~hing, ~a~ex o~ ~ubbe~ gloves,, fface mask~/ .. ~..~nneL o~ syringe ~o~ ~ans-Ee~ o~' ~adioac~ive ~ace~ ~o instruments ) .. . . ~.. rr,:,,;;;""Ex,D,°su~e Hazard (su~.vey me~e~, TLD o~. ~i~m ba~ge, p~ac~ice p~inciples ' ~ectl0n VIII --'~ntml Mea~u~ c., .~u~i face masks ~ith excellent o~ganic ffi~e~. '"""" '.',~'. : ...' L. N/RI ~o~= wo~ upwind ~om ! ~i'~ N/A possible vapors ;" ~~ I ~N~ .... La~ex o~ ~ubbe~ g~ovesI P~ovlded wi~h ffu~ fface p~o~ec~ion i . · WOd,,/H~ Pf~'t~ces ' .~E. mplo~; all radiation safety principles and good hygiene. . t~i! t* "'erlll ,~fety Data Sheet U.S. Department of Labor · h.. 4. bi ~ I0 ~ with Occupltion~l ~fety Ind Hellth Adminiltrltl0n'~ .................. : (~'1 ~ C~ 8tm~dl~l, . {Non-M~ncMto~¥ Fern) ....................... _,,, ..- 28 CFR 1910.12lX), Sllndard must be Form Approved (:ontukd gm' I~ requirements. ." OMB No. 1218-0072 :: GNI/Gulf Nuclear, .Inc. 202 Medical Center Blvd. {915) 362-7471 -, Webster, Texas 77598 December 30, 1986 I ~ ~111~ II ~ ~ I I II I aa IH.B I I I Ul ~later soluble isotopic tracer Exposure limit is 5.0 REbI/ r " ' Sodium Iodide (NaI) soluble in water employee (NRC and Californ'ia' State-' ", Radioactive Iodine 131 Health Department) ..... 2120F .... ~.0 I ,. 55.3 (mmHg).' 32~F :, -I) 1.0 up to-21.2°F ~.1 .... ~ ~ w~ . zoo~ '. , ....... Red color due to Pylam Dye. Odo~ N.one ........... "~':: ..... ...~~ ~ -- ~ I~ ~plol~fl ~ ~ None ...... ' ........ .....lib ~<r. ~ ~ .......... ·, ~.~~'" ~~~ .......... .. , ..... .. u/a · ID NUMBER: 2982 MATERIAL: RADIOACTIVE MATERIAL, PAGE: 1 n.o.s. GUIDE NUMBER: 63 FIRE HAZARD: ° ..... th~ - .......... ~ th~m-i~Ji' '-zaadily Radioactivity does not change flammability or other properties of the materials. HEALTH HAZARD: EXTERNAL RADIATION hazard from unshielded radioactive materia1. INTERNAL RADIATION hazard from inhalation, ingestion or breaks in skin. RADIO- ACTIVE MATERIAL; degree of hazard will vary greatly, depending on type & quantity of radioactive material & type of pckging. Materials in Special Form or in Type B packagings are not expected to cause contamination in accidents. SOME radioactive materials cannot be detected by commonly available instrUments. Runoff from fire or dilution may cause pollution. EMERGENCY ACTION - GENERAL: Keep unnecessary people at least 150 ft. upwind of spill; greater .distances may be necessary for people downwind, or if advised by Radiation Authority. ISOLATE hazard area and deny entry. Response actions may be performed prior to any measurement of radiation; limit entry to shortest possible time. Positive pressure self-contained breathing apparatus (SCBA) and .structural firefighters' protective clothing will provide limited protection. Notify Radiation Authority of accident conditions. Detain uninjured persons, isolate equipment with suspected contamination and delay cleanup until instruction of Radiation Authority. If water pollution occurs, notify the appropriate authorities. CALL CHEMTREC AT 1-800-424-9300 FOR EMERGENCY ASSISTANCE. EMERGENCY ACTION - FIRE: Do not move damaged containers; move undamaged containers out of fire zone. SMALL FIRES: Dry chemical, CO2, water spray or regular foam. LARGE FIRES: Water spray, fog (flooding amounts). For massive fire in cargo area, use unmanned hose holder or monitor nozzles. EMERGENCY ACTION - SPILL OR LEAK: ~3 DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL. Damage to outer container may not affect primary inner container. SMALL LIQUID SPILLS: Take up with sand, earth or other noncombustible absorbent material. LARGE SPILLS: Dike far ahead to collect runoff water. EMERGENCY ACTION - FIRST AID: Use first aid treatment according to the nature of the injury. If not affecting injury, remove and isolate suspected contaminated clothing and shoes; wrap victim in sheet or blanket before transporting. If there is no injury, remove and isolate suspected contaminated clothing and shoes; assist person to shower with soap and water and notify Radiation Authority of action. Advise medical personnel that victim may be contaminated with radioactive material. . END OF DATA FOR MATERIAL (ID NUMBER:' 2982) MATERIAL SAFETY DATA SHEET Shell ...... ,,~, "MSDS NUMBER '"~ 7,570-5 PAGE ! ~ 97367 14- t~5) 24.:::HOUR:.EMERGE~,q¥:iASSISTANCEi:i:::i::::~::~:!~?:i:i!i::!;:.:::~i:i:~!'. GENERAI~:;.MSDS::ASSISTANCE:i~ ~B FE~ SHELL: 713-473-9461 CHEMTREC: 800-424-9300 SHELL: 713-241-4819 E SA '~ READ OUR PRODUCT I~ 2 ' HAZARD RATING [EAST -:0 $1.1GHT - I MODERATE ' 2 ...AND PASS IT HIGH - 3 EXTREME - 4 I%~ 13UC T 1. IA~ITII'f .For acute iand c. hronic health effects refer to the discussion in Section III S EECT ! O .N.. ~ ! ~?.!~.:':?? h~::~:~: ~:i:.~.:;:.:~:,?::'~::?~??i :::i::~ :~ :::~ ~:?:::~ :~:~:?: CHEMICAL NOT APPL! :ABLE ' NAME ~' CH~:MICAL ............. "' ~' ' ' FAMILY ~ H¥~DROCARBO,.. , SOLVENT SHELL )k 83063 ''" ......... CODE it ' SECT]ON ]]-A PEODUCT/ZNGRED]ENT '' NO, ' COMPOSI'T~'ON ' CAS NUMBER PERCENT P MINERAL SPi'RZTS t45'~EC ..... Mi'XTURE* 100 ;' I SOLVENT NAPHTHI (PETROLEUM). MEDIUM AL]PHAT]C : 64742-88-7 >90 ~ 2 SOLVENT NAPHTHI (PETROLEUM). LTGHT AROMATIC " 64742-95-6 '<10 ,'- ~' ......... TYP t'CAL DiSTRiBUTiON .................................... " PARAFF ]'NS II ~ NOT APPL, 52.9 NAPHTHENE$ ' ' AROMAT]C/I~! " ...... ' .... NOT APPL. 38.9 '~ ; .... ' :'' · ~ ~ ' '~1 '' ~ ' ' TOTAL ; ' NOT APPL. 8.2 (TR I'METHYLBENZENE ...... 2.3-2.7) ' 25551-13-7 -- (ETHYL'rOLUENEi ..... ~..,.~ 0.9-t,1). ! 25550-14-5 -- OLEF]NS ' NOT APPL. <0. · A COMPLEX COMB[NAT[ON OF PREDQMLNATELY C8-Ct2 HYDROCARBONS1 EXACT COMPOSITION ~[LL VARY. SECTZON ]]-B ! ACUTE TOXTC~TY DATA NO. ACUTE ORAL LDSO ACUTE DERMAL LD50 ACUTE ZNHRLAT[ON LC50 ................... ,,: ?;.: .?:~'"~"T"~T,~',''"":T"..":"T .... '. ....... ~ ...... '. .... ..",' ............ P NOT AVAILABLE I ~ ' : . 1' >25 ML/KG (RAI'I~ >4 ML/KG (RABBIT) . >700 PPM/4H (RAT) 2* 4.7 G/KG (RAT)Ii >4 ML/KG (RAT) >3670 PPM/SH (RAT) · BASED UPON TESTI'NG i~R E]THER PRODUCT OR ESSENTIALLY $]H]LAR PRODUCTS. .... '..,-. i..~"~ ~ ..,'~:.:;... '?[l/"'t !'"'~'"~"' "'~ ;"": ..... :' ..... '" ': ;~ ~'"":' :' ...... , ~.'~,:'i'? ,'.'.: ~ .... . ..... "~ '." "' ' ..... ~"' ........... SECTZON ]]Z:~ ...... " ..... ,' ......... . . 4~'.~"'~.~:..~. '.: !;'. ~'''' "*~'~'!:';''' ' HEALTH ZNFORMATZON ', .'7' ' :,, , .... , , , .:,,. : ..-. · ~. , .: . . ..... .. . . . ~ .. . -' THE HEALTH EFFECTS.NOTED BELOW ARE CONS]~TE~T.:¥ETH..REQUi. REMENTS UNDER THE OSHA HAZARD COMMUNiCATiON STANDARD:(29/'~FRit?IO;:t200).i,:;L,,'..:".'~ :: ':;: :,i.,'~,r~:' ";:.;./!.. ' ' ,.. ' ". r ' ' ' ' ........ · ~. ;'" "!t1':' ;.:" ~'"'" "~...F:*. .'..:..,.~.~ ./,:: :~;....: ~i.,: .. ',....'., .:.. . .., . EYE CONTACT {I "' ' . LI*QU]D iS M1rN]MALLY ~RR]TAT]NG TO THE EYES."' H]GH VAPOR CONCENTRATIONS MAY CAUSE iRRITATION. ~"~ : L~]K~uNI'D~:I]N~A~[,GH;;:Y~ !R,TATING'TO THE SKIN.~.'" PROLONGED OR REPEATED LI'QUTD CONTACT · DEFATTZNG.AND DRYING OF:.!.THE,SKIN ~/HICH MAY RESULT:i, IN.SK]N.IRRITATION AND.DERMAT!T]S,', · ', ' .'~:';.:'.'.'..:~;' ,.. *'.:.:':':'.:.i:,i. ... · ..,~ ... · . ,:, ,..' '/ ~..:.... ,~ ~!;:.;. ~ %: ..... , .....: . ..... . . -~-*::'~;:: ~.:'~*%-:'.'4.":.'~,~ :"~' ' : .... ..: .' : ':..'. :':'" ..' :... .' ;. .',:',-.~,~...;. =..'.,.: *. ..... -.,.,~.:, · ~PRODUCT NAHE: MZNERAL ;i PAGE 2 ~NHALAT~ON VAPORS MAY BE IRRITATING TO NOSE, THROAT AND RESPIRATORY TRACT. HIGH VAPOR CONCENTRATIONS MAY '~,i...~AUSE CNS DEPRESSION. ';NGESTZON INGESTION OF PRODUCT MAY RESULT IN VOMITING: ASPIRATION (BREATHING) OF VOMITUS INTO THE LUNGS MUST BE AVOIDED AS EVEN SMALL QUANTITIES MAY RESULT IN ASPIRATION PNEUMONITIS. .SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE~ EARLY TO MODERATE CNS (CENTRAL NERVOUS SYSTEM) DEPRESSION MAY BE EVIDENCED BY GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA; IN EXTREME CASES, UNCONCIOUSNESS AND DEATH MAY OCCUR. ASPIRATION PNEUMONITIS MAY BE EVIDENCED BY COUGHING, LABORED BREATHING AND CYANOSIS (BLUISH SKIN); IN SEVERE CASES DEATH MAY OCCUR. AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE, SKIN AND;RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SEE SECTION VI FOR SUPPLEMENTAL INFORMATION. SECTION ZV .! OCCUPATIONAL EXPOSURE LIMITS , OSHA i. ACG[H OTHER NO. PEL/TWA PEL/CE~LZNG TLV/TWA TLV/STEL *RECOMMEND THAT LIMITS FO~I( STODDARD SOLVENT BE USED AS A GUIDE. SECTZON V : EMERGENCY AND FZRST AID PROCEDURES EYE CONTACT *USH EYES WITH PLENTY OF;iWATER FOR '15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION, SKIN CONTACT REMOVE CONTAMINATED CLOTHING/SHOES. FLUSH SKIN WITH WATER. FOLLOW BY WASHING WITH SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. DO NOT REUSE CLOTHING UNTIL CLEANED. ZNHALAT t'ON REMOVE VICTIM TO FRESH AII~ AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION, ~NGEST~ON DO NOT INDUCE VOMITING. I~= VOMITING OCCURS SPONTANEOUSLY KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIOUID INTO THE LUNGS. GET MEDICAL ATTENT[I~N.* I NOTE TO PHYS,C,AN *IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED AND VOMITING HAS NOT OCCURRED, EMESIS SHOULD BE INDUCED WITH SUPERVISION. 'KEEP VICTIM'S HEAD BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSIONS OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS, GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE S~OULD BE CONSIDERED. SECTION V! SUPPLEMENTAL HEALTH ZNFORMATZON MALE RATS EXPOSED FOR 90 DAYS BY INHALATION TO VAPORS OF SOLVENTS SIMILAR TO COMPONENT t SHOWED EVIDENCE OF KIDNEY DAMAGE.'. THE RELEVANCE OF THIS EFFECT TO MAN IS UNKNOWN. IN ONE OF THE STUDIES A LOW GRADE ANEMIA WAS ALSO OBSERVED. RATS EXPOSED FOR 4 MONTHS TO 1700 PPM OF A SOLVENT SIMILAR TO COMPONENT .2 SHOWED EVIDENCE O~ MILD DAMAGE TO THE LIVER, LUNGS AND KIDNEYS. THESE EFFECTS WERE NOT SEEN XN RATS EXPOSED FOR 1 YEAR TO 350 PPM OF ANOTHER SIMILARi SOLVENT. PRODUCT NN4E: HINERAL SPiRiTS 145-EC MSDS 7,570. SECTION XZ ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES CAUTION. COMBUSTIBLE. *** LARGE SPILLS *** ELIMINATE POTENTIAL SOURCES OF IGNITION, WEAR APPROPRIATE RESPIRATOR AND OTHER PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE'WITH AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIAL; PLACE IN NON-LEAKING CONTAINERS AND SEAL TIGHTLY FOR PROPER DISPOSAL, FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLUTION AS ABOVE. *** SMALL SPILLS *** TAKE UP WITH AN ABSORBENT HATERIAL AND PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. NASTE DISPOSAL UNDER EPA - RCRA (40 CFR 261.21), IF THIS PRODUCT BECOMES A WASTE MATERIAL, IT WOULD BE IGNITABLE HAZARDOUS WASTE, HAZARDOUS WASTE NUMBER O00t. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. '1 ENV;RONHENTAL HAZARDS UNDER EPA-CWA, THIS PRODUCT IS CLASSIFIED AS AN OIL UNDER SECTION 311. SPILLS INTO OR LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER, 800-424-8802. EPA - COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT. UNDER EPA-CERCLA ("SUPERFUND") RELEASES TO AIR. LAND OR WATER MAY BE REPORTABLE TO THE NATIONAL RESPONSE CENTER, 800-424-8802 (CIRCUMSTANCES SURROUNDING THE RELEASE AND CLEANUP DETERMINE REPORTABILITY). SECTION Xli ~ SPECIAL PRECAUTIONS KEEP LIQUID AND VAPOR AWA~ FROM HEAT, SPARKS AND FLAME. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN LIQUID PRODUCT IN THE ABSENCE OF SPARKS OR FLAME. EXTINGUISH PILOT LIGHTS, CIGARETTES AND TURN OFF OTHER SOURCES OF IGNITION PRIOR TO USE AND UNTIL ALL VAPORS ARE GONE. VAPORS MAY ACCUMULATE AND TRAVEL TO ~GNITION SOURCES DISTANT FROM THE HANDLING SITE; FLASH-F/RE CAN RESULT. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, DRILL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS ON OR NEAR CONTAINERS. STATIC ELECTRICITY MAY ACCUMULATE AND CREATE A FIRE HAZARD. GROUND FIXED EQUIPMENT. BOND AND GROUND TRANSFER CONTAINERS AND EQUIPMENT. SECT;ON Xll! TRANSPORTATION REQUIREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION: COMBUSTIBLE LIQUID D.O.T. PROPER SHIPPING NAME: PETROLEUM NAPHTHA OTHER REQUIREMENTS: UN 1255. GUIDE SHEET 27J' SECTXON XlV I OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES ,i PRODUCT NAHE: MINERAL SPIRITS 145-EC MSDS 7,570-3 SECTION VII .~ PHYSICAL DATA BOILING POINT: 317-388 (DEG F) ~ (H20-1) (MM HG) IOO DEG. F MELTING POINT: NOT A~AILABLE SOLUBILITY: NEGLIGIBLE VAPOR DENSITY: 4.8* (DEG F) Ii (IN WATER) (AIR-I) EVAPORATION RATE (N-BUTYL ACETATE · 1): <O.l* * ESTIMATED APPEARANCE AND ODOR: tLIGHT COLORED LIOUID. HYDROCARBON ODOR. SECTION VIII ~ FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: FLAHHABLE LIMITS /% VOLUME ZN AIR t12 DEG. F (TCC) i: LOWER: t UPPER: 6 EXTINGUISHING MEDIA USE WATER FOG, FOAM,:DRY CHEMICAL OR CO2. DO NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE REIGN/TED ON SUFACE OF WATER. SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS CAUT/O~. COMBUSTIBLE. DO NOT ENTER CONF/NED F/RE SPACE WITHOUT FULL BUNKER GEAR (HELMET W/TH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSIT/VE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATR/NG APPARATUS. COOL F/RE EXPOSED CONTAINERS W/TH WATER. UNUSUAL FIRE AND EXPLOSION HAZARDS CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD*BE COOLED W/TH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT iN CONTA/NER RUPTURE. CONTAINER AREAS EXPOSED TO D/RECT FLAME CONTACT SHOULD BE COOLED W/TH LARGE QUANT/TIES OF WATER AS NEEDED TO PREVENT WEAKEN/NG OF CONTAINER STRUCTURE. SECTION IX ! REACTIVITY STAB/LITY: STABLE '1 HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: AVO/D HEAT, FLAME ANDICONTACT W/TH STRONG OXID/Z/NG AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE AND UNIDENTIF/ED ORGAN/C COMPOUNDS MAY BE FORMED DURING COMBUSTION. SECTION X ;I EMPLOYEE PROTECTION RESPIRATORY PROTECTI6N AVOID PROLONGED OR REPEATED BREATHING OF VAPORS. IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE L/M/TS (SEC.i' /V) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. /N ACCORD W/TH 2g CFR t910.134 USE E/THER AN ATMOSPHERE-SUPPLY/NG RESP/RATOR OR AN A/R-PUR/FY/NG RESPIRATOR FOR ORGANIC VAPORS. PROTECTIVE CLOTHING AVO/D CONTACT W/TH EYES. WEAR SAFETY GLASSES OR GOGGLES AS APPROPR/ATE. AVO/D PROLONGED OR REPEATED CONTACT W/TH SK/N. WEAR CHEMICAL-RES/STANT qLOVES AND OTHER CLOTH/NG AS REQUIRED TO MIN)MIZE CONTACT. ADDITIONAL PROTECTXVE MEASURES USE EXPLOSION-PROOF VENT/LAT/ON AS REOU/RED TO CONTROL VAPOR CONCENTRATIONS. AIR-DRY CONTAM/NATED CLOTH/NG IN A WELL VENTILATED AREA. THEN LAUNDER BEFORE REUSING. PRODUCT NAME: MZNERAL SPZRZTS 145-EC HSDS 7,570-3 PAGE 5 . ~ ,.,?:. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY. EXPRESSED OR IMPLIED REGARDZNG THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSZBZLZTY FOR ZNUURY FROM THE USE OF THE PRODUCT DESCRZBED HEREZN. DATE PREPARED:OCTOBER O4, t985 dOHN P. SEPES! BE SAFE READ OUR PRODUCT SHELL OZL COMPANY SAFETY INFORMATION ...AND PASS IT ON PRODUCT SAFETY AND COMPLZANCE (PRODUCT LXABXLITY LAW P. 0. BOX 4320 REQUXRES ZT) HOUSTON, TX 77210 BAKERSFIELD CI/"f FIRE DEPARTMENT 2130 "G" STREET AKERSFIELD, CA US INESS HAZ ~DOUS ~TERI ALS BUSINESS PLAN AS A WHOLE FORM INS~UCTIONS: 1. To avoid further action, return this form by Z. ~PE/PRINT ANSWERS IN ENGLISH. ~. Answer the questions below for the business as a whole. 4. Be as b~ief and concise as possible. SECTION 1: BUSI~SS IDE~IFICATION DATA A. BUSINESS NAME: 5501 ~RIN Ct Suite E B. LOCATION / STREET ADDRESS: ' ZIP: BUS.PHONE: ( 805 ) 832-2996 SECTION 2: ~RG~CY NOTIFICATIONS In case of an emergency involvin~ the release or threatened release of a .... hazardous material, call 9~1 and 1-800-852-7550 o~ 1-916-427-4341. 'This will notify your local fi~e department and the State Office of Eme~sency Services as ~equired by EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME A~ TITLE D~ING BUS. HRS. AFTER B~S. ~S. ~. Vic Gifford ~es. ~h~ 832-2996 ~h~ 832-2996 B. ~il Keeler V. ~es Ph~ 832-2996 Ph~ 832-2996 SECTION 3: LOCATION OF ~ILI~ S~-OFFS FOR BUSI~SS AS A ~OLE A. NAT. GAS/PROPANE: Street B. ELECTRICAL: C. WATER: D. SPECIAL: E. LOCK BOX: YES / ~O IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE Phil Keeler and/or Vic Gifford SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YO5~ BUSINESS AS A WHOLE Local Hospitals SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAZARDOUS .MATERIALS:...' .................................... ~ NO ~ NO B. PROCEDURES FOR COOROINATING ACTIVITIES WITH RESPONSE AGENCIES: .......................... ....... C. PROPER USE OF SAFETY EQUIPMENT: .................. NO NO D. EMERGENCY EVACUATION PROCEDURES: ................. - NO NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ~ NO NO SECTION 7: HAZARDOUS .MATERIAL CIRCLE YES -- NO - NONE DOES YOUR BUSINESS HANDLE HAZARDOUS ~RTERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES NO Phil Keeler I, , certify that the above information.is accurate. I understand that this information will-be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. Z0 Chapter 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. · SIGNATURE TITLE Vice Pres. DATE 5-15-88 BAKERSFIELD CITY FiRE DEPART.~,IENT 21.20 "G" STREET BAKERSFIELD, CA 93301 O?F~CZAL USE ID# BUS[NESS X'A.YE: BUS I NESS PLAN SINGLE FACILITY UNIT FORM aA INSTRUCT IONS I. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW ~. Be a~ BRIEF and C~NCIS£ as possible.' FACILITY UNIT~ Suite E FACILITY UNIT N~ME: SECTION I: MITIGATION, PREVENTION~ ABATEMENW ~ROCEDURES All Materials are kept in approved containers: Radioactive materials are confined to a fum& hood and any spills would be contained in the hood SECTION 2: NOTIFICATION A~ EVAC ..... N PROCEDL~ES AT THIS L%'iT OILY If hazard occurs: Define hazard area: Clear hazard area: Notify personal that would handle hazard: See attachment (on file) SECTION 3: HAZARDOUS MATERIALS FOR THIS b.'NiT ONlY A. Does this Facility Unit contain Hazardous Materials? ...... ~ XO If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES C~ if No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form =4A-l) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form :4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-Z. ~CT!O~ 4: PRIVATE FIRE PROTECT!O~ Fire Extinguishers , Sprinkler System SECTION S: LOCATION OF WATER SUPPLY FOR USE ElY EMERGENCY RESPONDERS Front of complex - Aldrin Ct SECTIO.Y 6: LOCATIO.Y OF UTILITY SHUT-OFFS AT TT[IS L~'!T O~'LY. A .YAT " ~'' '~ ' · . o.-l:>., P~,.OP.,~X~.. B. ELECTRICAL: Mains on street ( Aldrin Ct) C. WATER: D. SPECIAL: ~F YES, SiTE PLA:,:S? YES / XO MSDSs? '~'£S "¥0 FLOOR PLAXS? YES ." 1,;0 KEYS? YES "XO I.D. # FORH 4A-I Page ~of NON--TRADE SECRETS HAZARDOUS l%laTS m I ALS INVENTORY BUSINESS NAME: TECHNICAL WIRELINE SERVICES Inc OWNER NAME: n/a FACILITY UNIT ·: ADDRESS: 5501 Aldrin Ct Suite E ADDRESS: FACILITY' UNIT NAME: C I TY, Z I P: Bakersfield. 93313 c I TY, Z I P: PHONE ·: 805 832-299'6 PHONE #: ]OFFICIAL USE CF[RS CODE I O__NLT I 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD ~D.O.~ [ CODE AMOUNT AMOUNT UNIT CODE CQDE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE GUIDE P 284 2800 ft3 4 43' on trailer - so side 100% Nitrogen (n2) ~ ~ ~NFLG ~ 150 150 ft3 4 42 SO wall 100% Oxygen ~ ? ,NFLG P 55 55 ft3 4 42 so wall 100% Acetylene [~ q I FLGS M 55' 55 gal 6 8 so wall Mineral Spirits 145-EC ,~t>~,Q,Q 90% ~,lven~~phtha Medium Aliphate CMLQ [ 10% Solvent Naphtha Light Aromatic e4IO s 20 gal to 26 so wall t00 o Shell otor Oil 30 Oc( M M .2 1 gal 9 43 No west wall 100% Iodine 131-Water Soluble NaI RADI ( .5 2 curie -~ 5 5 curie 9 43 No west wall 100% Krypton - 85 ~AME: Phi~.Keeler TITLE: VP S ONATURE:_/~~~ DATE:D'-/xf-~'~ E. MERGENCY CONTACT: ,,~/"~c~. TITI, E: 'PHONE # BUS HOURS: ~$'Z-Z.~_ AFTER BUS HRS: E~ERGENCY CONTACT: TITLE: PHONE · BUS HOURS: PRINCIPAL BUSINESS ACTIVITY: AFTER BUS HRS: 'TRICT 102-24 Bakersfielept. Hazardous Materials Inspection Date Completed /~L - ~_(~ -q~0 Business Name: "'-F-'~ ~ l.J~ \ ~ C_~-I Xf~ ~ q-.~" I. ~ ~ R~I=IVED Location: ~..~© 1 k L-OZ.~,o C_"T-. Plan ID # 215-O00Ocw~J (Top right comer Business Plan) ~a.o~.o. / ~ S~. ~Z ~p~ctor VtZZ! Adequate Inadequate Ve~.~on of tnv~n~ov Mat~als ~ ~ Verification of Quantities ~ Verification of Location ~oper Se~egafion of Matefifl Verification of MSDS Availabfliw N~ber of ~ployees ~Vefificafion of Haz Mat Trai~ng ~ Ve~cafion of Abatement SuppSes & Procedures Colnn'le_qls;: Emergency Procedures Posted Containers Properly Labeled ColTmlents: Verification of Facility Diagram ,~/e'"L~' ,~t'~t~3 ~/,4~4~A - ~ [--] Special Hazards Associated with this Facility: k'...C:,l ..,., ',~., 1 · ... :.~/ '~,?-"-'?~zZqll~~'' ,,;~ ':, ,,' ,~ ( ty~e or p~n~ name ) JAN 1 6 1989 Do hereby c=-t~Z~- that I have revi~ ' J~8'~.... ..... . :wea the ' ' ...... attached Hazardous Materials business plan (name of business) and that it along with the attached additions corrections consti~ ~ ~u~e a complete and correct Business Plan for my facility. . ~aate · BUSINESS NAME TE4 WtRELINE SERVICES INC ID ER LOCATION SSO;-E RL. ORIN CT HIGH HAZARO RATING 3 1. OVERVIEW LAST CHRNGE 10/07/88 BY ESTER ~URIS CODE Z15-009 ~URIS B~KERSFIELO STATION 09 MAP PAmE ~Z3 GRIO 1SD FACILITY UNITS 1 HAZAR[) RATING 3 RESPONSE SUMMARY 2A SEC 4) PHIL. KEELER OR VIC GIFFORO REOEIV~D EMERGENCY CONTACTS Z~ SEC Z) HAZ. MA~ VIC BIFFORD - 83Z-Z99B PHIL ~EELER - UTILITY SHUTOFFS' Z~ SEC n) GAS - STREET' B) ELECTRICal - STREET C) UATER- STREET O) SPECIAL - NONE E) LOCI BOX ~ NO NOTIFICATION / PUBLIC EVACUATION LAST CHANGE / / BY < NO INFORMATION RECORDED FOR THIS SECTION PAGE 1 12/Z8/88 1~:01 MATERIAL SAFETY D~TA SYSTEMS, INC. (805) B48-G800 LOCATION SSOt-E F)LDRIN CT HIGH HAZARD RATING 3. HRZ MAT TRAINING SUMMARY LAST CHANGE < NO INFORMATION RECORDED FOR THIS SECTION > LOCAL EMERGENCY MEDICAL ASSISTANCE L~ST CHANGE 07/0~/88 BY ESl'ER ZA SEC S) LOCAL HOSPITALS, PAGE Z tZ/ZB/BB IZ:O! MRTERI~L S~FETY D~T~ SYSTEMS, INC. (BOS) G48--G800 I BUSINESS NAME TECH WIRELINE SERVICES INC ID N0~ER Z15~OOO-O~767 LOCATION SSO1-E BLORIN CT HIGH HAZARD RATING 3 FACILITY UNIT 01 A. OVERALL HAZARDOUS MATERIALS INVENTORY LAST CHANGE 07/06/88 BY ESTER ID TYPE NAME MR>( AMT UNIT HAZARD LOCATION CONTAINMENT USE 1 PURE NITROGEN Z84 FT3 MODERATE ON TRAILER - SOUTH SIDE PORTABLE PRESS, CYL. WELL INJECTION ID PERCENT COMPONENTS HAZARD LIST Z324.00 1~Y~3.0 NITROGEN MOOERATE Z PURE OXYGEN 150 FT3 HIGH SOUTH WALL PORTABLE PRESS. CYL. WELDING/SOLDERING IO PERCENT COMPONENTS HAZRRD LIST 2359.00 1OO.O OXYGEN, COMPRESSED HIGH 3 PURE ACETYLENE SS FT3 EXTREME SOUTH WALL PORTABLE PRESS. CYL. WELDING/SOLDERING ID PERCENT COMPONENTS .HAZARD LIST 1241.00 100.0 ACETYLENE EXTREME 4 PURE MINERAL SPIRITS SS GAL EXTREME SOUTH WALL DRUMS OR BARRELS MET.. CLEANING ID PERCENT COMPONENTS HAZARD LIST 1203.02 100.0 NAPHTHA SOLVENT EXTREME B. FIRE PROTECTION / WATER SUPPLIES LAST CHANGE 07/0~/88 BY ESTER 3R SEC 4) FIRE EXTINGUISHERS AND SPRINKLER SYSTEM FOR FIRE PROTECTION. 3R SEC S) FIRE HYI]RANT IN FRONT OF COMPLEX ON ALDRIN CT, PAGE 3 lZ/ZG/88 lZ:01 MATERIAL SAFETY DATA SYSTEMS, INC, (805) G48.-6800 BUSINESS NAME TECHN YlRELINE SERVICES INC ID ZIS-OO(~-OOO?G? LOCATION SS01-E ALDRIN CT HIGH HAZRRO R~TING 3 D. EMPLOYEE NOTIFICATION / EVACUBTION L~ST CHANGE 07/OG/B8 BY ESTER SEC 2) IF HAZARD OCCURS: DEFINE HAZARD AREA, CLEAR HAZARD ~REA, NOTIFY PERSONNEL 'THAT WOULD H~NDLE HAZARD. E. MITIGATION / PREVENTION / ~BRTEMENT L~SI' CHANGE 07/0B/88 BY ESTER ~R SEU 1) ALL M~TERIRLS ARE KEPT IN APPROVED CON'r~INERS. R~DIOACTIVE MATERIALS ARE CONFINED TO ~ FUME HOOD AND ANY SPILLS WOULD BE CONTAINED IN THE HOOD. PAGE 4 12/Z8/88 1~:01 MATERIAL SAFETY DRTR SYSTEMS, INC. (805) G48-680~ " CITY of BAKERSFIELD NON--TRADE SECRETS ~us~.~ss N~ ............ ~-// ~~, c:~O'~ X LOCATION: ............ ~ ''r ~' OWNER NAME: ~/~ ~/~~ NA~E OF T~ ADDRESS: ~ STANDARD IND. CLASS ~{'--~l ' C l TY, ZIP: ~~ ~_~/~ CITY. ZI~: ~/~/~~ ~ DUN AND BRADSTREET NUMBER PnOnZ ~: - - P~o~ ~: ~ ~ ~Z-- ~ -~ - -~ - - ~C~e C~e Mt ~ Est ~ts m Site 1~ ~1 I~ ~ .. St~ iff F~tlity... ~ I~t~ti~ Ph~ic~l ~ H~lth ~za~ C.A.S. ~ ~t II ~ & C.A.S. ~ (C~k 411 t~t 4~ly) _-- _ ~lth of P~ ~lth ~.[~._l._.~, .... 1._2~.~ .... 1,~~ I~1~.1 ~ :~1 ~ 1 ~ !~1~o. ~ .... ~~ ,.. P~icll ~ bith Heze~ C.A.S. ~ ~t II ~ i C.A.S. ~ (C~k iii t~t I~Jy) .......... -] ~--] ~ ~ ~-] ~t~ ~&C.A.S.~ . ~lth of ~ ~lth /t 13 ~IC.l.l. W -~_~k_~.:_h~ ...... j ;,o 1~I~ I ~ I ~:!.7. I.~: 1.~ o~ c i ' ~ ~; ~~z~~ (C~k l}] t~t l~ly) H~ith of P~sum ~lth '' ~ d ......................... X~/~/~' ' c.,.,.- ) R]~ ................................... ~T~ .................. Irtificatim freed and sJ~ after co.pier,nE a J] sectJons) certify ~der ratty of 1~ t~t I ~ve ~rsmelly txam~ ~ la f~ilimr ~Jth t~ ~nf~t~m ~tt~ t. this ~ ell Itt~i ~ts. ~ t~t ~ m ~ i~t~ of t~e i~tvi~ls ~-~n~ 6TTici~l'TiTli'~T'~;~TGF'Ofl'~;76~T~;'~'~GT~Fi}~F~iF~TiEi~i Sl~[ure ........................... ~ ................. CITY of BAKERSFIELD F.r..nd ~4r~cult.re ~ St.n~rd m,s,..s ~ H~Z~RDO~S ~T~R~ A~S ~ ~V~~.OR~' NON--'ITRADE SECRETS BUSINgSS ............... ~ O~R NAMg: NAHg OF T~ LOCATION: .............. ~ ~ ADDRESS: STANDARD Z~. CLASS CODE C~TY, Z~ ~ / C~, Z~P: DUN AND B~DSTREET NUMBER r--~ ~ r--~ r-~ ~t ~ M&C.A.S. ~ H~lth of Prflsure ~lth " ~t 13 ~ iC.A.S. ~r erttficati~ freed and si~ after compJeting aJJ sections) or obtaini~ t~ int~tt~, I ~li~e t~t t~ ~u~itt~ into~ti~ i$ t~. accurate, ~d c~)ete. PROCEDURES A. Monitoring Job Site Before Initiation of Work 1. ~ Using a low level survey meter, and before work initiation, monitor the area. Record the observations on a sketch of the area. 2. Certify the area clean before commencing the job. B. Handling Equipment: The following items shall be worn at times when handling the radioactive materials while health physics problems are present: 1. Gloves* 2. Face masks** 3. Handling Tongs* 4. Protective Clothing* C. Pocket Dosimeters can be worn by personnel who are handling radioactive materials.-If, however, personnel also carry personal film badges, the option is present as to whether the pocket dosimeter be worn. The ad- vantage to the pocket dosimeter is direct reading, and if the radiation level is not excessive (generally 1 to 10 mCi of Iodine-131 will be handled per injection), then it should be the option of the field safety officer as to whether pocket dosimeters be worn. * These items will always be worn in handling radioactive materials, thus, preventing the possibility of contami- nation to the person who is actually handling the radio- active material. ** Face masks shall be worn at all times when a gaseous radioactive material is being used in a field study. The face mask shall be a type approved by the NBM and should contain an excellent organic filter agent. D. Film Badges: It will be mandatory for all personnel working in the restricted area (an area greater than 2 mR/hr) to wear a film badge. E. Tracer Packaging: Ail packages received from the suppliers containing radioactive materials shall be'monitored prior to their leaving their facilities. The dosage limits shall comply to the DOT shipping regulations which are a maximum of 200 mR/hr at the surface of a shipping container and a maximum-of 10 mR/hr at a distance of one meter from the surface of the container. F. Handling and Field Equ%~ment Check List: The specific application will require additional radi- ation detection equipment than that listed below, but, generally, the field equipment will consist of the following items: -First Aid Kit -Kim-Wipes (Industrial Type) -Sponges -Large and small polyethylene storage bags for containing contaminated equipment, sponges, etc. -Protective clothing -two remote handling tongs -Masking and plastic electrical tape -Plastic wash bottles -Rubber gloves -Labels for the return of radioactive waste -Dosimeter and charger -Film Badges -Concentrated wash solution -Low level survey meter G. Operating Procedures: 1. Pre-Job Knowledge and Planning-The Radiological Safety Supervisor must know: a. Types of radiation involved. b. Intensity of radiation. c. Relative hazard of each type of radiation. d. What the "Stay Time" is (maximum allowable exposure time). e. What the possible contamination problems are. f. Any internal contamination problems. g. What the industrial nuisance removable contami- nation will create. h. What controls must be dictated to protect personnel i. Plan methods for controlling access to radio- graphic area. 2. Specific Procedures will vary with the individual job applications. In general, the following pro- cedures should be followed: a. Plan the job in advance. b. Monitor the area and measure the background radiation level. c. Optimum mixing location should be selected. Radioactive material should be mixed with injection fluid as close to well head as possible. d. Define the area which is prohibited to un- authorized personnel. (2 mR/hr is the maximum allowable radiation to people not wearing film badges) e. Mix radioactive material with injection fluid with special consideration given to splashing, wind conditions, and any other outside influence which could interfere with the safe handling of the material. f. Plastic or rubber gloves should be worn at all times while handling radioactive materials. If wind velocity is sufficient to cause blowing, goggles and respirator should be used. g. Exposure time should be controlled. If exposure approaches the maximum permissible limit, personnel should be rotated. (See charts 9-2-2, 9-2-3) h. Allow no eating, smoking or drinking in the restricted area. ~i. Following the completion of the operation, the entire area should be monitored. j. Radioactive Contamination Inspection Sheet should be filled out and given to the customer. H. Emergenc~ Procedures: Emergencies vary greatly in their respec'~ive hazards. Sometimes these emergencies are in the form of spills, fires or explosions which consequently, result in the spread of radioactive contamination. Emer- gency procedures contained in the National Bureau of Standards, Handbook No. 48, are given here as a guide. It must be recognized that these procedures are general and any specific emergency would certainly involve addi- tional procedures not specifically covered in this out- line. 83 1. Spills involving no radiation hazard to personnel: a. Notify all personnel in the area at once. b. Permit only a minimum number of personnel in the vicinity of the spill. c. Confine the spill immediately. d. Notify the Radiation Protection Officer. e. Decontaminate. f. Monitor all personnel involved in the spill and cleaning. g. Permit no person to resume work in the area until it has been surveyed and approved by one of the approved individual users specified on the AEC and/or Agreement State Radioactive Material License. 2. Spills involving radiation hazard to personnel: a. Notify all personnel not involved in the spill to vacate the area at once. b. If the spill is liquid and the hands are pro- tected, upright the container. c. If the spill is on the skin, flush thoroughly. d. If the spill is on the clothing, discard outer or protective clothing at once. e. Switch off all fans. Vacate the room. f. Notify the Radiation Protection Officer as soon as possible. g. Take immediate steps to decontaminate personnel involved. h. Decontaminate the area. i. Permit no person to resume work in the area until a survey is made and approval of the Radiological Safety Officer is secured. j. Prepare a complete history of the accident, and give details in the EMERGENCY PROCEDURES REPORT. 3. Injuries to personnel involving radiation hazards: a. Wash minor wounds immediately under running water while spreading the edges of the gash. b. Call a physician, preferably one who is qualified to treat radiation injuries. c. Permit no person involved in a radiation injury to return to work without the approval of the attending physician. d. Report all radiation accidents (wounds, over- exposure, injestion, inhalation) to your super- visor. e. Prepare a complete history of the accident and give the details in the EMERGENCY PROCEDURES REPORT. 84 4. Fire and other major emergencies: a. Notify all personnel in the area at once. b. Attempt to put out all fires if radiation hazard is not immediately present. c. Notify the Fire Department. d. Notify the Radiological Safety Officer. e. Govern the fire fighting or other emergency activities by the restrictions of the Radiological Safety Officer. f. Following the emergency, monitor the area and determine the emergency devices necessary for safe decontamination. g. Decontaminate. h. Permit no person to resume work without approval of the Radiological Safety Officer. i. Monitor all persons involved in combating the emergency. ]. Prepare a complete history of the accident and give the details in the EMERGENCY'PRO- CEDURES REPORT. Contamination Survey TechniqUes 1. Surveying of Area and Equipment The ideal mixing and injection opeartion would have no spills and leave no residue of tracer material in any of the vessels of pipes through which~the tracer was injected. In practice such and ideal may not be realized, and a survey of the area'is necessary so that proper procedures may be followed, to assure that no remaining con- taminant can cause harm to company personnel, the customer's personnel or the general public. The survey meter must be used with the beta shield open to survey the entire area where mixing has been done and the pipes and associated components through which the mix was conducted to the well, to be sure that no concentration remains that may cause harm, either by external radiation or by possible contam- ination of food or water supplies. Contamination of the probe must be avoided completely. If any contact survey is made, the prove is to be protected with a sheet of paper between the object and probe. A contaminated probe and render the survey meter useless for low measurements. Spills should be cleaned up and, if possible, in- jected into the well with the main tracer unit. The area of the spill should then be surveyed with the probe approximately one inch above the surface. Any areas or items of equipment which indicate any amount of detectable radioactivity, above background, shall be considered contaminated and appropriate measures taken to'remove such concentrations. (See paragraph D). 2. Surveying of Individuals The greatest care in survey measurement is taken on items of personal equipment such as gloves, shoes, clothing and handling tools, as well as exposed portions of the body of personnel working with radio- active materials. This is because of the much greater probability of ingestion from such items. The survey meter should also be used with the beta shield open to read the radiation level of clothing worn by the individual performing the mixing operation or any other clothes suspected of contamination. This should be done immediately following the mixing operations. If any indication of radioactive con- tamination is found on items of clothing, equipment, etc., or on the person or personnel involved in the operation, every effort should be made to remove the activity. (See paragraph D for decontamination). 100 Decontamination Procedure The radioactive tracer preparations are down by factors 50 to 200 below the dangerous levels for external ra- diation hazards. The major hazard involved with these tracer preparations is the factor of ingestion. The ingestion tolerance is from one part per thousand to one part per ten thousand of the typical activities used. Thus, great care is exercised by company Per- sonnel to avoid contamination of hands, clothing and other personal items. Accidental concentrations of radioactive material are cleaned up, dispersed, or dis- posed of safely. Decontamination shall, in general, be accomplished by rinsing and flushing fresh water through the equipment, or washing and scrubbing of contaminated items of cloth- ing or portions of the individual's body. A detergent may be added to the water to aid this process. Portions of the equipment which cannot be decontaminated by this method shall be disassembled and scrubbed with water and detergent followed, if necessary, by steam cleaning. A 15% hydrochloric acid solution may be used to remove contamination from the surface of non-porous materials. Other chemicals may be had for decontamina- tion but their use should be limited, due to their toxic nature. Articles of clothing can be normally be easily decontam- inated by washing and scrubbing with water containing a strong detergent. This also applied to portions of the exposed individual's body. If efforts to decontaminate items of clothing on the job are unsuccessful, the cloth- ing should be removed immediately to be washed after returning to the home station nearest the job location. Contaminated articles of clothing, rags, etc.,should never be laundered in a home or commercial laundry. Such washing and scrubbing is restricted to the job site or the company base. If the contamination cannot be removed economically, the clothing shall be discarded and treated as radioactive waste. As indicated above (see Paragraph C-2) every effort should be made to decontaminate any contaminated area of the body. Scrubbings should be repeated until activity is removed. The same safety precautions shall be applied to the above operations as were applicable for tracer mixing and injec-~ tions in particular. 1. Rubber gloves shall be worn during decontamination. procedures involving~personal contact with the equipment. 2. Food, cigarettes, etc., shall be kept outside the cleanup area. Quantities of radioactive material which presents no hazard outside the body can be very dangerous if the same amount is internal. 101 3. The wash water shall be treated as radioactive waste. If wash water is discharged into sanitary sewerage system, the dilution of the activity by the sewerage must be such that the tolerance established for such disposal by the AEC and Agreement States are not ex- ceeded. Since we do not have the capability of assaying the wash water for the concentration of contaminant in microcuries per milliliter, we must use the amount of tracer material actually used on the job and the average daily water consumption at the base in determining that we are not exceeding tolerances. If the wash water is discharged into a septic tank, then the surface of the fluid in the septic tank shall be surveyed after each such decontamination operation, and if any activity above background is noted, the tank shall be posted with a radiation warning sign alerting every- one concerned of the possible hazard. If standard decontamination efforts are unsuccessful, procedures to be followed shall depend on the value and ownership of the items involved, the degree of contamina- tions, and the half-life of the contamination activity. Every effort shall be made to thoroughly decontaminate rented or borrowed equipment. If all efforts to de- contaminate items of equipment, clothing, etc. have failed to render the radioactive contamination to back- ground and the measurable activity is apparently "fixed", the user'in charge thas three alternatives. They are as follows: 4. If the "fixed" contamination measures less than 0.2 mR/hr at one centimeter, the item of equipment, articles of clothing, etc., can be returned to normal use. 5. If the "fixed" contamination measures more than 0.2 mR/hr at one centimeter, the item or items in question shall be treated as radioactive waste and disposed of accord- ingly. 6. If the item containing the "fixed" contamination (which measures more than 0.2 mR/hr at one centimeter) is such that it is continually used in tracer operations, e.g., parts of a dump bailer, tracer injector, etc., and will be used in no other operation, then it may continue to be used if it is labeled properly and treated as a radioactive source and if the radiation measures less than 2.0 mR/hr at three inches from the surface. More persistent activities remaining on injection apparatus, customers equipment, etc., are steam cleaned or chemically treated for contamination. 102 The user in charge shall be responsible for all contam- inated equipment. That is, for any equipment, waste, area, or wash water that falls within the above alter- native situations. The user in charge shall personally supervise if safe disposition either by staying on the job until the contamination is removed or transporting the equipment to the base where it may be stored waiting further decontamination efforts. 103 EMERGENCY PROCEDURES REPORT (CONTINUED) ~""~' 8. Were there any suspected over-exposures and if so, who: 1. 2o, 3., 4. 9, Personnel radiation survey, for those working in the Restricted Area: Name Head Face Body Hands Legs Feet 2. 3. 4. 5. 6. 10. On the sketch of the job site, mark the location of the exact spill: 11. Make an isodose chart if the level of the spill is greater than 10 mr @ 1 foot. a) one foot: b) three foot: c) six foot: 12. Check the air space for contamination: 13. Results of wipe tests after clean up emergency procedures are undertaken: 90 EMERGENCY PROCEDURES REPORT 1. Customer: 2, Customer's Supervisor: 3, Company Supervisor: 4, Cause of Emergency: 5. Source or Isotope: 6. Quantity of Isotope (curies) believed to have been spilled: ! 7. Safety precautions immediately enacted: EMERGENCY PROCEDURES REPORT (CONTINUED) .~_.~ (Item No. 13 continued) Position No. 1: (dpm) Position No. 2: (dpm) Position No. 3: (dpm) 14. Suggestions to future prevention of this accident: · .~ Radiologic Health Branch 744 P Street Sacramento, California 95814 STATEMENT OF TRAINING AND EXPERIENCE (Use additional sheets as necessary) Instruction: Every individual proposing to use radioactive material is required to submit a Statement of Training and Experience in duplicate to the address given above. Physicians should request Form RH 2000 A when applying for human ~se authorizations. 1. Name of proposed user: Vic 'G±fford Position title: President Address: P. O. Box 1973 City: Bakersfield~ CA Zip:93303 To be ineluded on Lic. No. 2759-15 innameof Technical Wireline Service: 2. Description of proposed use To conduct tracer studies in wellbores for oil and gas production 5. Training.: a. High School Graduate: Yes X No~ ' b. College or University: Name and location Bakersfield College Bakersfield, CA Years completed 2 Degree Course of study Busine s s c. Education specifically applicable to use of radioactive material Science Chemistry Physics 4. Experience: a. List experience with radioactivity beginning with most recent (1) Dates: From 1974 to 1988 Title and duties: President of Corp. Ov~rseeing operatio_n.s an~ _.~ ..safe usage _of-Radioactive Mm~rim]s Employer:.%..echnical Wireline ServJ~ktress: P.O. Box 1973, Bksfld,CA 93303) (2) Dates: From 1973 to 1974 Title and duties: Field Engineer . LoRding Wells. Conducting tracer studies in wellbores for oil and gas plToduction. E~p]oyer: McCollough Address: Bakersfield (Not Jn B,,.~,~.~.~) (3) Dates: From 1972 .to 1973 Title and duties: Field Engineer. Conducting tractor wellbores for oil and gas production Employer: Address: RH 2050 A (8/82) b. Radioactive materials previously used. Cite typical radioisotopes in appropriate box and key to Part 4.a above: Quantities Handled MiCrocuries Millicuries Curies Kilocuries Sealed sources Unsealed alpha emitters ' . · Unsealed beta- gamma eufitters 50 of 1-131 5 of KR-85 Neutron sources c. Describe. procedures similar to those proposed in Part 2 with which you have had experience. Indicate months or years for each and key to Part 4.a above. d. Indicate which types of facilities you have used and key to Part 4.a. ( ) Ordinary Chemical laboratories ( ) "Controlled Area" (Type B) laboratories ( ) Glove boxes (X) Shielded glove boxes ( ) Caves with remote manipulators (X) Field operations with portable equipment Certificate: I hereby certify that all information contained in this Statement is true and correct. -2- Radiologic Health Branch 744 P Street' Sacramento, California 95814 STATEMENT OF TRAINING AND EXPERIENCE (Usc additional sheets as necessary) Instruction: Every individual proposing to use radioactive material is required to submit a Statement of Training and Experience in duplicate to thc address given above. Physicians should request Form RH 2000 A when applying for human ~sc a~urhorizations. 1. Name of proposed user: Phil Keeler Position titlc: Vice President Address: 725 Paloma St City: Bakersfield Zip: 93304 To bc included on. Lic. No, 2759-15 in name of TF_CHNICAL WIRELINE SER, 2. Description of proposed use To conduct tracer studies in well bores for 0il and gas production 3. Training: " a. High School Graduate: Yes X No~ b. College or University: Name and location Bakersfield College Years completed 2 Degree A.S. Course of study Science c. Education specifically applicable to use of radioactive material On the job training with Technical Wireline. Radiation safety school for well loggers By Gulf Nuclear (Frank Malek) 4. Experience: a. List experience with radioactivity beginning with most recent (1) Dates: From 4-1-76 ,~. to. Present Title and duties: Vice President RSO Employer:, Technical Wireline Ser. Address: 5501 Aldrin Ct. "E" (2) Dates: From to Title and duties: Er~pioyer:, . Address: (5) Dates: From,. to Title and duties:. Employer: Address: 2050 A b. Radioactive materials previously used. Cite typical radioisotopes in appropriate box and key to Part 4.a above: Quantities Handled Mi ere tm ties Mi Iii curies Curies Kilo curie s Sealed sources Unsealed alpha emitters ' Unsealed beta- gamma emitters 50 of 1-131 5 of KR-85 Neutron sources c. Describe procedures similar to those proposed in Part 2 with which you have had experience. Indicate months or years for each and key to Part 4. a above. 1st 2 years of training under Vic gifford Pres. of TWS Radiation Logging school for the handling of Iodine-131 D.O.E. for the handling of Krypton-85. d. Indicate which types of facilities you have used and key to Part 4.a. ( ) Ordinary Chemical laboratories ( ) "Controlled Area" (Type B) laboratories ( ) Glove boxes (X) Shielded glove boxes ( ) Caves with remote manipulators (X) Field operations with portable equipment 5. Certificate: . I hereby certify that all information contained in this Statement is true and correct. re .of proposed user Date Radiologic Health Branch 744 P Street' Sacramento, California 95814 STATEMENT OF TRAINING AND EXPERIENCE (Use additional sheets as necessary) Instruction: Every individual propOsing to use radioactive material is required to submit a Statement of Training and Experience in duplicate to the address given above. Physicians should request Form RH 2000 A when applying for human ~se authorizations. 1. Name of proposed user: Kevin Ballew Position title: Field Tech Address: 6301 Victor SC City: Bakers£ield Zip: 93308 To be included on. Lic. No. 2759-15 ,in name of, Technical W±reline Service Inc. 2. Description of proposed use To Conduce Cracer scud±es in wellbores £or o±l and gas production 3. Training: a. High School Graduate: Yes x No " b. College or University: Name and location Years completed Degree, Course of study c. Education specifically applicable to use of radioactive material Navy-Electronics Training by RS0 4. Experience: a. List experience with radioactivity beginning with most recent (1)' Dates: From 6-17-88 to,., Present , Title and duties:, Field Tech. Injection of Isotopes Employer:, , Address: (2) Dates: From to, Title and duties: Employer:, . Ad&ess: (3) Dates: From t0J '. Title and duties: .. Employer: , . Address: RH 2050 A (8/82) b. Radioactive materials previously used. Cite typical radioisotopes in appropriate box and key to Part 4.a above: Quantities Handled Microcuries Millicuries 'Curies Kilocuries Sealed sources Unsealed alpha emitters · Unsealed beta- gamma errfitters 50 of 1-131 5 of Kr-85 Neutron sources c. Des~ibe procedures similar to those proposed in Part 2 with wMchyou have had expcrience. Indic~emonths or years for each andkey to Part 4.a above. Currently undergoing training by RSO Phil Keeler for the injection of Isotopes d. Indicate which types of facilities you have used and key to Part 4.a. ( ) Ordinary Chemical laboratories ( ) "Controlled Area" (Type B) laboratories (X) Glove boxes ( ) Shielded glove boxes ( ) Caves with remote manipulators (X) Field operations with portable equipment 5. Certificate: I hereby certify that all information contained in this Statement is true and correct. Signature of proposed user Date -2- Bakersfield City Fire Dep. R E C E ~ V ~ 0 5-16-88 2130 "G" Street MAY 18 198~ Bakersfield, Ca. 93301 ............ Notification of change of address for Technical Wireline Services Inc. Old Business address: 4609 New Horizon Suites Bakersfield, Calif, 93313 New Business address: 5501 Aldrin Ct Suite "E" Bakersfield, Calif, 93313 Enclosed is our new Hazardous Materials Business Plan for our new location. Phil Keeler Vice President (805) 832-2996 P.O. BOX 1973 STEAM SPECIALISTS PRODUCTION SURVEYs BAKERSFIELD, CA 93303 ENHANCEMENT CHEMICALS P.O. BOX 1973 ~; BAKERSFIELD, CALIFORNIA 93303 ~; TELEPHONE (805) 323-8846 ~"'~-~-O~J BAKERSFIELD CITY FIRE' DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 JUL 2 0 1987 (80 ) OFFICIAL USE ONLY BUSISESS HAZARDOUS MATERI ALS BUSINESS PLAN AS A WHOLE F O RlV[ 2A 000757 INSTRUCTIONS: 1. To avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: TECHNICAL WTRELINE SERVICES Inc. B. LOCATION / STREET ADDRESS: 4609 New Horizon Suite #4 CITY: Bakersfield ziP: 93309 BUS.PHONE: (805) 832-2996 SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS. A. Vic Gifford Pres. Ph# 832-2996 Ph# 832-2996 Phil Keeler V.?res. 832-2996 832-2996 B, Ph# Ph# SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: Street B. ELECTRICAL: C. WATER: " D. SPECIAL: E. LOCK BOX: YES / N~ IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 2A - SECTION 4: PRIVATE RESPONSE TEA~ FOR BUSINESS AS A WHOLE Phil Keeler and/or Vic Gifford SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE ~ Loca'l Hospitals SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAZARDOUS TERIALS:...- .................................... NO NO B. PROCEDURES FOR COOROINATING ACTIVITIES WITH RESPONSE AGENCIES: .......................... ~ NO ~ NO C. PROPER USE OF SAFETY EQUIPMENT: .................. ~_~ NO ~ NO D EMERGENCY EVACUATION PROCEDURES: ................. ~ NO ,,~ NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... ~ NO ~ NO SECTION ?: HAZARDOUS MATERIAL ~-~' CIRCLE YES OR NO t DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES NO I, Phil Keeter , certify that the above information is accurate. I understand that this information, will be used to fulfill my firm's .obligations undeu the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. BAKERSFIELD CITY FIRE DEPARTMENT 2130 "6" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID# BUSINESS NAME: BUSI NESS PLAN SINGLE FACILITY UNIT FORM SA INSTRUCTIONS 1. To avoid further action, this form must be retu,'ned 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions belm~ for THE FACILITY UNIT LISTED BEI. OW 4. Be as BRIEF and CONCISE as possible. FACILI~ UNIT~ ~ 4~ FACILI~ ~IT N~ME: SECTION 1: MITIGATION, PRE~NTION, ABATEMENT PROCEDURES SECTION 2: NOTIFICATION AND EVACUATION PROCEDURES AT THIS UXIT ONLY SECTION 3: HAZARDOUS MATERIALS FOR THIS UNIT ONLY A. Does this Facility Unit contain'Hazardous Materials? ...... O NO If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES ~ If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form ~4A-1) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form #4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION SECTION $: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS F o,44- - n o,z/z-o , SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY A. NAT. GAS/PROPANE: B. ELECTRICAL: c. WATER: D. SPECIAL: E. LOCK BOX: YES / N~.~ IF YES, LOCATION: IF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS? YES / NO KEYS? YES .,' NO - 8B -. HAZARDOUS MATER]] ALS . INVENTORY ADDRESS: ~O~ ~(~/~ ~ ADDRESS: FACILITY UNIT NAHE: .....I ONLY COOE A~OUNT AflOUNT UHIT CODE CODE. FACILITY UNIT ~T,.. CHEMICAL OR COMMON NA~E ... CODE OUIOE EHERUENCY CONTACT: ~1~ ~~ .... TITLE: ,~ PllONE { BUS IlOURS: EblEROENCV CONTACT: TITLE: PIIOffE ~ BUS llOUR8: PRINCIPAL BIJ~INES9 ACTIVITY: AFTER BUS. IlR9: BIOASSAYS We've been using Eberline Instrument Corporation in Albuquerque for our urine bioassays. A 2# hour sample of urine (700 to 1~000 m.l.) is taken every quarter. If dosimeter badge reports are higher than normal (of which they haven't been) then extra samples will be taken. We have recently set up a new program with Kern Radi,ology and Nuclear Medical Group~ Inc.~ here in Bakersfield~ which consists of a scintillation count of the thyroid as follows: I) Base line bioassay of employees handling radioactive material. 2) Weekly bioassay of any person who handles more than 50 millicuries of 1-131 at anyone time. 3) Bioassay of user if believed to have been exposed to more than 0.14 microcuries over one calender quarter. 4) Routine quarterly scans to compare with baseline. This program was established by Dr. Darwood B. Hance of Kern Radiology and Nuclear Medical Group, Inc. Listed below is our current outline for handling Iodine 1-131 ..... I. General A) No person shall handle radioactive materials unless authorized by the radiation safety officer. B) Persons handling radioactive materials are required to comply with state and/or federal radiation control regulations (whichever are applicable). II. Safety Precautions A) Before persons can be authorized to handle radioactive material, they must 1) Be instructed in the safe handling and use of isotopes (I-131 L..J [_,_,..J' .... ': _' ;. 2) Demonstrate understanding of and the familiarity with these instructions. 3) Demonstrate understanding and knowledge of applicable radiation control regulations. B) Persons handling radioactive materials are required to wear protective gear such as coveralls~ gloves~ gas mask~ lead apron~ or any other apparel specified by the radiation safety officer. C) The following will be on hand during operations involving radioactive materials. 1) Survey Meter 2) Work kit containing: a) Rubber gloves b) Aluminum foil or heavy plastic c) Wash bottle d) Absorbent material e) Empty container f) Pipette (hand held) g) Tongs h) Gas mask D) During field operations, radioactive materials are not to be han- dled inside any vehicle. If radioactive material must be trans- ferred from one container to another, heavy plastic or aluminum foil is to be placed under such containers and persons involved in transfer of material should stand up wind. E) Persons not involved with the operations will remain outside a restricted area determined by the radiation safety officer. F) On completion of an operation, the persons involved will survey themselves and the area around the well location. G) Radioactive material 1-131 will. be transported~.in__ , lead pigs with proper labels; ' ' ' H) All pipetting operations will be done with a hand held pipette. III. Operating Procedures A) Locations vary from well to well, therefore, the radiation safety officer must plan each operation in sufficient detail to avoid situations resulting in contamination of personnel or property. B) Define a restricted area prohibiting unauthorized personnel. C) No eating, smoking or drinking will be allowed in a restricted area. D) Rubber gloves and coveralls will be worn while handling radio- active materials. E) Operate quickly and safely to minimize exposure time. IV. Emergency Procedures A) Spills involving no hazards to personnel: 1) Notify all personnel in the area at once. 2) Permit only a minimum number of personnel in the area of the spill. 3) Confine the spill immediately. #) Notify the radiation safety officer. 5) Decontaminate. -2- 6) Monitor all personnel involved in the spill and subsequent clean up. 7) Permit no person to resume work in area until it has been sur- veyed and approved by the radiation safety officer. B) Spills involving radiation hazard to personnel: 1) Notify all personnel not involved in the spill to vacate the area at once. 2) If the spill is liquid and the hands are protected; right the con- tainer, seal it, and place it in its protective lead pig. 3) If the spill is on the skin; flush thoroughly with water and collect the rinse solution. 4) If the spill is on the clothing, discard outer or protective clothing at once. Turn off any fans and vacate room or area. 6)Notify radiation safety officer as soon as possible. 7)Begin decontamination of Personnel and area. 8) Permit no person to resume work in area until it has been sur- veyed and approved by the radiation safety officer. 9) Prepare a complete report of the incident. C) Iniuries to personnel involving radiation hazards: 1) Wash minor iniuries immediately under running water while spreading edges 0f gash. 2) Call a physician who is qualified to treat radiation iniuries. a) Darwood B. Hance, M.D. with Kern Radiology and Nuclear Medical Group, Inc. 3) Permit no person involved in a radiation injury to return to work without the approval of attending physician. 4) Prepare a complete report of the incident. D) Fire and other emergencies 1) Notify all personnel in the area at once. 2) Attempt to put out all fires if radiation hazard is not immediately present. 3) Notify fire department. 4) Notify radiation safety officer. 5) Govern the fire fighting and/or other emergency procedures making sure there are no hazards to personnel involved. 6) Following the emergency, monitor the area and begin safe decontamination. E) Monitoring techniques for personnel 1) Check hands (fingernails), shoes (soles and heels), and face (hair and-nostrils). -3- 2) Remove any contaminated clothing, placing it in the ~ decontamination bin. 3) Always check hands before eating, drinking, or smoking. Cleanse carefully of contamination (scrub with soap and water then check again). F) Miscellaneous 1) Upon receipt of radioactive shipment a) Remove packing slips. b) Log shipment in daily log book. c) File packing slip. d) Remove radioactive container and place in the safe until needed. e) Peel radioactive stickers off box and discard. 2) On completion of survey, log the date, well number, type of tracer, and amount used. 3) Film badges will be worn at all times, being clipped to the waist. I t A Bivisi~,n Of ~cal nc. I Su~'fac g Phil Keeler Vice President MOBILE (661) 303-9067 WEBSITE: Www. twsi.com (661) 832-2996 · FAX (661) 832-1415 EMAIL: DIGITAL PAGER (661) 329-6878 Philk@twsi.com STEAM SPECIALISTS 5501 ALDRIN C'l~, SUITE E PRODUCTION SURVEYS ,, BAKERSFIELD, CA 93313 ENHANCEMENT CHEMICALS