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BUSINESS PLAN 12/7/1994
WAREHOUSE 'C' EXISTING ~ uo EXISTING WAREHOUSE 'B' ...... : EXISTING ~ ALDRIN C~ IIHMMP PLA MAP " SITE DIAGRAM FACILITY DIAGRAM , · I I . ~ . ' '. .:: .: ' : I - I ~ ~"J ' ' I ~ ~ '' ~ = [--~' ~,~ .. .. .~,~ ~,,'~ I ~ ~-~q . , , . ~. ~ , . , - ~. :.~ . ~ I '~'~ ~. t I'~'~l~'"fl ~:~ · I I q ~O~l~ , ~n~, ,,,,,,,,,~n-l~~ ........... .... '~ ..... . . ,, ...... _.."'--'-""'.........................i,~,i~ '~-~&i-i-Li-i-~-~4~L~ j i i H-i i! i:Li:i i!!T!T~'~ ! F~!T!-~I'I:~~L~i-i i-L~-i-~i i i~ i ~ i~ ! i ! ~ ii i iii i iii i~ "' .o~ ' ~oJ~x~ ~H~ ..5.- SITE/FACILITY I AGRAM FORM (C~ECK 0~) SITE DIAG~ FACILI~ - 5A - SITE/FACILITY DIAGRAM FORM DATE~./I~/~ FACILITY NAME:--3(5~ -- UNIT -', OF (CHECK ONE) SITE DIAGRiM / FACILITY DIAG~ ~ ' · . / ~ ~ !' sss, ~:~c+, / l' / , ; ........... (Inspector's Comments): -OFFICIAL USE ONLY- - 5A - 4l HM~'IP PLA~ MAP SITE DIAGRAM FACILITY DIAGRAM ~3un-04-01 12:07P P.03 ~ YAL SOAP & CHEMICAL CO., I ~ 160b'7 FOOTHILL BLVD. IRWINDALE, CA 91702 (818) 3344299 24 HOUR D.O.T. AND EMERGENCY (800) 5:35-5053 Product Nome: LOYAL HEAVY DUTY DE(~REASER Code:3020 Chemicel or Common Name: HARD SURFACE CLEANER Date Issued:01/01196 Pcepa~ed By: JEFFERY ADLER Suoereedes:03/01/94 1. Hazardous Information ¢l~rnogal Name Cas Numbers Weight % E~$ure Information Sodium Slllca~ N 1~ 1~15 Non= ~u~b P~ t 3~ ~ 2-7 2 G~I Effier EB 111-?~2 ~ PELS~N ~ ~V S~N 2-7 2. Physlc~ Da~ Bailing P~nt: ND Vapor Dana~ {a~ = 1): ND Melti~ or ;reezi~ Point: ND Percent Volatile (By Wi): ND Viscosity:ND Va~or ~aure (MM HG); ND 3. Fire and Explosion Data Flash Po~t: ND Lower E~g~n L~: ND Upp~ Ex, esPn Limit: ND A~ ~ T~p: ND Extin~i~hi~ M~di~ ~m X C02 X Dry ~hE~ic~l X wet~¢ ~og X Other 8g~iel Rte Rg~ing ~edur~: Normal fire fighting pr~u~ may be us~. Cool and u~ caution wn~ approaching or handling fire ~poeed ¢on~inem. Unusuel Rte & ~olosion H~erdl: Corrosive material. ~n~iner may burst in heat or firs. 4. Healffi Data R~om~nded Health Guide ~A (Maximum Time Weighted Average Conoen~tion For An 8 Hour Work Pedo0). ND Effeats ef Overexposure: EYES: D~ ~M ~h ~ mn m~ ~gn. P~u~t ~y ~ jrristion and nausea if taken internally. ~rol~g~ m re~d con~ct of e~eGuate ~enffiat~n ia not em~oyed. Emergency and Rmt ~.,~- O~.L o', ', z :o~ ,~.o4 o~ i' ~. Reactivity Data Stability: STABLE Conditions To Avaid: NONE NOTED Ha;ardous Decomposition Produ=ts:Whefl exposed to fire, produces normal products of comt)ustion, Hazardous Polymerilation: WILL WILL OCCUR Conditions To Avid; NONE NOTED Inoompatability (Materials To Avoid}: STRONG ACIDS 6. Spill or Leak Procedure Steps to be taken If material Is released or spille{l: Dike large spills. Absorl~ with absorbent material. Swoop up ;ndContainerize. Rinse affected ares wi~ water, Waste Disposal Informetlon: FO~ undiluted material disposal is regulated under the Resource Conservation end Recovery act ee corrosive waste. Dispoeal for regulated quantities by neutralization accordance with ell Fecleral, State and Local regulations, 7. Special Protec'don Information Respiratory Protection {Specify Type): No aoeoial re;luiraments under normal uso. If mist/vapors are not adequately controlled by local ventilation, use ai)0rol3riate respiratory protection to pn=vent overexi)osure, Ventiletlon: Normal room ventilation should be Prate=tire Gloves: Rubber or PVC Eye Prote=tion: SI31ash proof goggles where eye contact may occur. Other Protective Information: If available 8. Special Precautions Precautionary Labeling: Keep out of the reach of children. Avoid eye contact. Wash hands after using materiel. Other Handling And Storage Conditions: Store In a cool dry ams. 9. Additional Information Containers, even those that have been emptied, will retain product residue and ValOrS. Always obey hazercl warnings and handle empty containers as If they are full. 10. Health Hazard Rating O-Insignificant 1 -Slight 2-Moclerate 3-Nigh C-Extreme Health 3 Fire 0 Reactivity 1 S~ecial 0 NA- Not Apl~licable ND- Not Determined All infom~lim, r~ogmmencl~ion~ end ~ ~ ~n ~ thb p~ ~ ~ u~ d~ ~ai~ ~om ~umr a~ or ~n~ ~1 ~u~; ~, R~ ~= & C~l~ C~, I~. ~ ~ ~, re~n~ or qulrin~ ~ ~ ~e ~, ~uff~y ~ *~T DE$CRII~ON: COMPOUND, CLUING LIQUID (~ODIUM HYDROXIDE), 8, NA 1760, II Page 2-2 (3020) 11/14/01 1.6:41 8661 326 0576 BFD HAZ MAT DIV ~]001 L D FIRE CHIEF RON FRA~IE This notice is meant to act as a that the California Health ADMINISTRATIVE SERVICES and Safety Code, Chapter 6.95, requires any handler of hazardous materials 2101 'H' Street to ~eir hazardous materials business plan w' ' 31I~___~~~ of any one Bakersfield, CA 93301 vO,CE;~x (s05,(8°5)395-,~n9szs'394' of the f_~g events: ~-_~ -7 ~R SUPPRESSION SERVICES 2101 'H'Str~t (1) A 100 per cent or more increase in the quantity of a. Bakersfield, CA 93301 material. VOICE (805) 326-3941 ~,rev,ous,.~-,,sc,ose,., PREVENTION SERViCES ny handling of a previously-undisclosed' hazardous 1715 Chester Ave. ~. material, subject to the inventory requirements of Chapter Bakersfield, CA 93301 VOICE (805) 326/3981 6.95. FAX (805) 326-0576 ~ (3) Change in business ownership. ENVIRONMENTAL SERVICES 1715 Chester Ave. Bakemfield, CA 93301 VOICE (805) 326-3979 (de) Change in business address. FAX (8O5) 326-O576 Tn~S.~.a o'~ns~ou (5) Change of business name. 5642 Victor Ave. Bakersfield, CA 93308 VOICE (805)399-4697 Any questions regarding these required revisions, please call the ;Ax (808) 3~-s753 . Hazardous Materials Division at (805) 326-3979. Sincerely yours, Director, Office of Environmental Services 'BAKERSFIELD FIRE DEPARTMENT .... :~-,. Iii llove.~ 1980 BUREAU OF FIRE PREVENTION Dote APPLICATION Application 'No. In conformity with provisions of pertinent ordinances, codes and/or regulations, apPlicatiOn' is~ made by: B~ker Send Control 5~01 Aldrtn Nome of Company Address to display, store, install, use, operate, sell or handle materials or processes involvinG] or creating con- ditions deemed hazardous to life or property os follows: ~f.a; (6) mouth remporeF3~ perud, t £o~ I - 1,000 IPtl aboveground 8~oolJ. ne rank and I - ls000 ~Jl abouel~*ound df. eee]. rauk Co be lrmralled 6 mOUths ulnderf~'ou.ud Can]~o. PenniCee i8 ~)auJ. d TayloT. ._ ........... ....... ............ O Bakersfield Fire Dept~_ HAZARDOUS MATERIALS DIVISION ' v// Date Completed Business Name: .~. ~P---J" ~C')t~11'1(,(('.on'j-to j Location: ,~J ~ ! ~ J"~-h. ~c-.~_...oc,.~ Business Identification No. 21~000 ~0~ ~op of Business Plan) Station No. i 3 Shi, B Inspector ~, ~r r~, ~. ~f, ~ ~ ~ ~ ~ ~ J o :3 o Adequate Inadequate ~0~ ~ ~ ~ ~' ~Verification oflnvento~ Materials ~ ~ ~ECEI~E~ ' Verificaion of Qu~tities ~ VerEicmion of Locmion ~ Proper Segregation of Materi~ ~ Comments: Verification of MSDS Availabli~ ~ ~umber of Employees Verification of H~ Mm Training ~ Oommems: Verificmion of Abmemem Supplies & Procedures ~ Comments: Emergency Procedures Posted ~ Containers Properly Labeled ~ Commems: Verificmion of Facility Diagr~ ~ 8p~ial H~ards Associmed with this Facility: ~ ~.,~,~ All Items O.K. ~ ~ ~. ,4,~ Correction Needed J~] ~ B"u~in~s Owner/Mafiager FD 1652 (Rev. 1-90) White-Haz Mat Div. Yellow-Station Copy Pink-Business Copy Overall Site with 1 Fac. Unit General Information Location: 5551 ALDRIN CT Map:123 Haz:3 Type: 3 City~~-~ Grid: 15D F/U: 1 AOV: 0.0 Contact Name / Title Contact Name Title STAN ~L~R_Name! / FIELD SUPERVISO RICK RELERFORD / SAFETY COORDINA Business Phone: ~805) 834-2844x Business Phone: (805) 834-2844x 24-Hour Phone :/(805) 589-4492x 24-Hour Phone : (805) 665-8108x Pager Phone /F ( ) - x Pager Phone : ( ) - x ~ ~ Administrative Data Mail Addrs: 5551 ALDRIN CT D&B Number: 09-357-7377 City:BAKERSFIELD State: CA Zip: 93313- Comm Code: 215-013 BAKERSFIELD STATION 13 SIC Code: 1389 Owner: BAKER SAND CG~ANY CG~P )~%~Y7 Phone: (805) 834-2844 ddress: 1010 RANKIN RD '~"~ ~mLi ~ state: CA City: HOUSTON 6 ~ ~--~ Zip: 77073- Summary CITY of BAKERSFIELD ~ ~' "WE CARE" ~~ M E M 0 R A N D U M FIRE DEPARTMENT 2101 H SREET D. S. NEEDHAM BAKERSFIELD, 93301 FIRE CHIEF 326-3911 ~2107194 STATUS - ON HAND BALANCES Page 11:15=10 Report OHPrt ALUHINUH STEARATE 25 LB 32600-0025P BO.O0 ~"~ ,~,1~) BO.O0 AQUAPAC R 50 LB 30790~0050P 326.00 ~ ~/x,j 326.00 AQUAPAC LV 50 LB 3079S-0050P 320.00 320.00 B~O-LOSE (DFE ~7) 50 LB 3070~-0050P 31.00 3~.00 ~LACK HAS~C SFT 55 LB 31706-0055P 440,00 440.00 CALC[UH CARBONATE 50 LB 30005-0050P 455.00 ~ 455.00 CAUSTIC SODA 50 LB 36029-0050P 1278.00 ~- 1278.00 CF DESCO 25 LB 304~-0025P 2tO,O0 2[0.00 CHRDHE FREE ~ 50 LB 304t3-OO50P 20,00 ,~ 20.00 DRZLL-THZN 25 L~ 30450-0025P 240,00 ~ 240,00 KD - 700 5 GAL 3]05J-00056 %,00 %.00 KD-700 5 GAL 87~99-0000P ~2B.O0 ' x~ 12B.00 H]L-BAR 100 LB 30012-OIOOP 8820.~0 BB20.O0 HXL-CEDAR PLU6 40 LB 3340G-OO40P 408.00 408.00 H~L-L~HE 50 LB 3GOG~-OOSOP tO0,O0 ~00,00 HXL-PAC R 50 LB 30748-0050P ~.00 ~I[-S[~[ ~[~I~ 40 [8 33343-0040~ 420.00 , 420.00 ~It-l[~ 50 [~ 304~-OOSOP 4~.00 40.00 ~I[$[[ 100 k~~O121-OlOOP 7840.00 HILGEL NT SUPER SAC SUPER 30124-0001P 91470.00 ~__ 91470.00 HILPARK HD 5 GAL 3231~-0005~ 17,00 ~'~0~~ 17,00 NEN-THfH 5 GAL 30435-00056 60.00 60.00 NE,-TRQL 50 LB 30756-0050P 160.00 ~ ~~~ 160,00 PALLETS EACH Pallet 10058- -87.00 -87.00 PALLETS PALLET 9Bl~l- 113.00 ~ 113.00 SANDUST 40 LB 33365-0040P 276.00 ~ 276.00 SHRINK NRAP SHRINK lO07B- -133.00 ~ .~ -133.00 SHRINK HRAPPING 98115- 5.00 ~ 5.00 SODA ASH 50 LB 36097-0050P 637,00 637.00 SODIUH BICARBONATE 50 LB 36100-0050P 196,00 196.00 SPECIAL NEAP 72X105 lOOflO- 65,00 65.00 SUPER-COL 50 LB 30135-0050P 108,00 108.00 N.D, 30 COARSE 50 LB 33737-0050P 240.00 240.00 N,O, 30 FINE 50 LB 33739-0050P 58.00 58,00 N.O. DEFBAH 5 6AL 33750-00056 22,00 22.00 XCD POLYHER 25 LB 30145-OO25P 5.00 5.00 09/07/94 BAKER SAND CONTROL 215-000-000759 Page 3 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-03~ TRANSMISSION FLUID Liquid 100 Low ~/ /· Fire, Immed Hlth, Delay Hlth GAL 02-0~ WASTE OIL (NA 9189) Liquid 300 Low · Fire, Immed Hlth, Delay Hlth GAL 02-040/ SODA ASH Solid 3000 Low · Fire, Immed Hlth LBS 02-042 S-60/DIESEL Liquid 100 Low · .Fire, Immed Hlth, Delay Hlth ~_~7~ GAL 02-00~/HYDROXYETHYL CELLULOSE Solid 10000 Minimal ~/· LBS 02-02~/MOTOR OIL Liquid 300 Minimal · Fire, Immed Hlth, Delay Hlth GAL 02-03/ POTASSIUM CHLORIDE Solid 15000 Minimal · Immed Hlth LBS 0~-0~SILICA SAND Solid 140~000 Minimal Q-~ · Immed Hlth, Delay Hlth ~ LBS 02-0~~ SODIUM CHLORIDE Solid 5000 Minimal · Immed Hlth LBS 02-0~ULFAMIC ACID Solid 800 Minimal ~ · Immed Hlth AU LBS · ~ ~v/ GAL 02-043 RDX/TRIMETHYLENE Solid 600 Unrated 02-045 ~NITROPYRI_~DINE ~ / Solid 600 Unrated 02-046 PRI.MADET_ ~K ,~ // Solid 600 Unrated · ~Fzre ~ LBS 02-005/~LYTEX Solid 1000 Unrated V · LBS 09/07/94 BAKER SAND CONTROL 215-000-000759 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-033/.~ACETYLENE Gas 400 High ~//· Fire, Pressure, Immed Hlth, Delay Hlth FT3 02-01~/FORMIC ACID Liquid 15 High · Fire, Reactive. Immed Hlth, Delay Hlth GAL 02-0~7 HYDROCHLORIC ACID Liquid 1000 High · Reactive, Immed Hlth GAL 02-0~ LIQUEFIED PETROLEUM GAS (PROPANE) Gas 430 High · Fire. Pressure, Immed Hlth GAL 02-00~ SODIUM HYPOCHLORITE' Liquid 115 High · Reactive, Immed Hlth GAL 02-044 CYCLOTRIMETHYLENE Solid 600 High 02-0~5/ A-100/CRONOX 265/ISOPROPANOL Liquid 55 Moderate ~,~//~, · Fire, Delay Hlth GAL 02-0~ BIOCIDE GLUTARALDEYDE Liquid 55 Moderate · Immed Hlth, Delay Hlth GAL 02-01~/DEFOAMER/POTASSIUM HYDROXIDE Liquid 55 Moderate %/· Immed Hlth GAL 02-02y'~ MAGNA All4/AROMATIC PETRO SOLVENT Liquid 55 Moderate · ~// · Fire. Immed Hlth. Delay Hlth GAL 02-091 SODIUM HYDROXIDE, FLAKE Solid 100 Moderate ~/~ · Fire, Immed Hlth, Delay Hlth LBS 02-039 SOLVENT/683 Liquid 200 Moderate · Fire, Immed Hlth, Delay Hlth ~-U~ GAL 0~-~F~i S-90 Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-0~ AMMONIUM CHLORIDE Solid 5000 Low LBS t./ /· Immed Hlth 02-03~/HYDRAULIC OIL Liquid 100 Low ~/ ~ire, Immed Hlt~, Delay Hlth GAL 02-Q26//KEROSENE Liquid 55 Low · Fire. Delay Hlth GAL 02-03~ OXYGEN Gas 900 Low · Pressure, Immed Hlth GAL ~0/12/93 BAKER SAND CONTROL .215-000-000759 Page 1 Overall Site with 1 Fac. Unit General Information Location: 5551 ALDRIN CT .~ Map: 123 HaZard: Moderate Community: BAKERSFIELD STATION 13 Grid: 15D F/U: 1AOV: 0.0 Contact Name Title Business Phone 24-Hour Phone- STAN MILLER FIELD SUPERVISOR (805) 834-2844 x (805) 589-4492 RICK RELERFORD SAFETY COORDINATOR (805) 834-2844 x (805) 665-8108 Administrative Data Mail Addrs: 5551 ALDRIN CT D&B Number: 09-357-7377 City: BAKERSFIELD State: CA Zip: 93313- Comm Code: 215-013 BAKERSFIELD STATION 13 SIC Code: 1389 Owner: BAKER SAND COMPANY CORP Phone: (805) 834-2844 Address: 1010 RANKIN RD State: CA City: HOUSTON Zip: 77073- Summary 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-033 ACETYLENE Gas 400 High · Fire, Pressure, Immed Hlth, Delay Hlth FT3 02-013 FORMIC ACID Liquid 15 High · Fire, Reactive, Immed Hlth, Delay Hlth GAL 02-017 HYDROCHLORIC ACID Liquid 1000 High · Reactive, Immed Hlth GAL 02-027 LIQUEFIED PETROLEUM GAS (PROPANE) Gas 430 High · Fire, Pressure, Immed Hlth GAL 02-007 SODIUM HYPOCHLORITE Liquid 115 High · Reactive, Immed Hlth GAL 02-044 CYCLOTRIMETHYLENE Solid 600 High · Fire .~ LBS 02-025 A-100/CRONOX 265/IsopROpANOL Liquid 55 Moderate · Fire, Delay Hlth GAL 02-018 BIOCIDE GLUTARALDEYDE Liquid 55 Moderate · Immed Hlth, Delay Hlth GAL 02-015 DEFOAMER/POTASSIUM HYDROXIDE Liquid 55 Moderate · Immed Hlth GAL 02-023 MAGNA All4/AROMATIC PETRO.SOLVENT Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-011 SODIUM HYDROXIDE, FLAKE Solid 100 Moderate · Fire, Immed Hlth, Delay Hlth LBS 02-039 SOLVENT/683 Liquid 200 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-041 S-90 Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-008 AMMONIUM CHLORIDE Solid 5000 Low · Immed Hlth LBS 02-030 HYDRAULIC OIL Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL 02-026 KEROSENE Liquid 55 Low · Fire, Delay Hlth ~ GAL 02-032 OXYGEN Gas 900 Low · Pressure, Immed Hlth GAL 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 3 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-031 TRANSMISSION FLUID Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL 02-028 WASTE OIL (NA 9189) Liquid 300 Low · Fire, Immed Hlth, Delay Hlth GAL 02-040 SODA ASH Solid 3000 Low · Fire, Immed Hlth LBS 02-042 S-60/DIESEL Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL 02-003 HYDROXYETHYL CELLULOSE Solid 10000 Minimal · LBS 02-029 MOTOR OIL Liquid 300 Minimal · Fire, Immed Hlth, Delay Hlth GAL 02-037 POTASSIUM CHLORIDE Solid 15000 Minimal · Immed Hlth LBS 02-035 SILICA SAND Solid 1400000 Minimal · Immed Hlth, Delay Hlth LBS 02-038 SODIUM CHLORIDE Solid 5000 Minimal · Immed Hlth LBS 02-009 SULFAMIC ACID Solid 800 Minimal · Immed Hlth LBS 02-020 UNION CARBIDE UCAR 310/AMINE/GLYCOL Liquid 200 Unrated · Immed Hlth GAL 02-043 RDX/TRIMETHYLENE Solid 600 Unrated · .~ LBS 02-045 DINITROPYRIDINE Solid 600 Unrated · Fire LBS 02-046 PRIMADET Solid 600 unrated · Fire LBS 02-005 POLYTEX Solid 1000 Unrated · LBS 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 4 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-033 ACETYLENE Gas 400 High · Fire, Pressure, Immed Hlth, Delay Hlth FT3 CAS #: 74-86-2 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: FABRICATION Daily Max FT3I Daily Average FT3 I Annual Amount FT3 -- 400 ~ 390.00 3,500.00 Storage Press T Temp~ Location PORT. PRESS. CYLINDER Above· I AmbientlSOUTHWEST CORNER -- Conc Components MCP ---TGuide 100.0% IAcetylene IHigh / 17 02-013 FORMIC ACID Liquid 15 High · Fire, Reactive, Immed Hlth, Delay Hlth GAL CAS #: 64186 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: DRILLING Daily Max GAL I Da~ly. Average GAL I Annual Amount GAL -- 15 ~ 15.00 15.00 Storage Press T TempI Location CARBOY Ambient~AmbientlSOUTH CHEMICAL WAREHOUSE -- Conc Components MCP ---7Guide 90.0% IFormic Acid IHigh / 60 02-017 HYDROCHLORIC ACID Liquid 1000 High · Reactive, Immed Hlth GAL CAS #: 7647-01-0 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: ADDITIVE Daily Maxl,000GALI~ Daily Average300.00GAL I Annual Amount6,000.00GAL -- Storage Press T TempI Location ABOVE GROUND TANK AmbientlAmbientlWAREHOUSE C, SOUTHWEST -- Conc Components MCP ---~uide 35.0% }Hydrochloric Acid IHigh ~ 15 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 5 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-027 LIQUEFIED PETROLEUM GAS (PROPANE) Gas 430 High · Fire, Pressure, Immed Hlth GAL CAS #: 74-98-6 Trade Secret: No .Form: Gas Type: Pure Days: 365 Use: FUEL Daily Max GAL430I~ Daily Average300.00GAL I Annual Amount1,800.00GAL -- Storage I Press T Temp I Location· FIXED PRESS. CYLINDER Above /Ambient OUTSIDE, WAREHOUSE A -- Conc~ '~ Components MCP ---TGuide 100.0% IPropane Extreme I 22 02-007 SODIUM HYPOCHLORITE Liquid 115 High · Reactive, Immed Hlth GAL CAS #: 7681-52-9 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: WATER TREATMENT Daily Max GALI Daily Average GAL 1 Annual Amount GAL Storage~~Press T Temp · Location PLASTIC CONTAINER IAmbientlAmbientlSOUTH CHEMICAL WAREHOUSE -- Conc Components MCP ---/Guide 15.0% Isodium Hypochlorite' IHigh ! 45 02-044 CYCLOTRIMETHYLENE Solid 600 High · Fire . LBS CAS #: 121824 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: BLASTING Daily Max LBS ~ Daily Average LBS T Annual Amount LBS 600 I 2.00 / 9,000.00 Storage I Press T TempI · Location OTHER - SPECIFY I Ambient I Ambient I WAREHOUSE B, SOUTH -- Conc Components . MCP ---~uide 100.0% ICyclonite IHigh ~ 46 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 6 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-025 A-100/CRONOX 265/ISOPROPANOL Liquid 55 Moderate · Fire, Delay Hlth '~ GAL CAS #: 67-63~0 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: FORMULATION/MANUFACTURING Daily Max GALI Daily Average GAL I Annual Amount GAL 55 ~ 55.00 55.00 Storage Press T Temp Location DRUM/BARREL-METALLIC IAmbient~AmbientlSOUTH CHEMICAL WAREHOUSE -- ConcI Components I MCP ----~uide 15.0% iISopropanol ModerateI 26 15.0%IEthyl OctynoiIL°w ! 27 ~' 10.0% Petroleum Distillate ModerateI 27 02-018 BIOCIDE GLUTARALDEYDE Liquid 55 Moderate · Immed Hlth, Delay Hlth GAL CAS #: 111-30-8 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: DRILLING Daily Max GAL Daily Average GAL I Annual Amount GAL -- 55 I 55.00~ 55.00 Storage~lPress T Temp Location PLASTIC CONTAINER IAmbieq~lAmbientlSOUTH CHEMICAL WAREHOUSE -- Conc Components MCP ---TGuide 25.0% IGlutaraldehyde IModeratel 58 02-015 DEFOAMER/POTASSIUM HYDROXIDE Liquid 55 Moderate · Immed Hlth GAL CAS #: 1310-58-3 Trade Secret: No Form: Liquid Type: Mixture' Days: 365 Use: WATER TREATMENT Daily Max GALI Daily Average GAL ] Annual Amount GAL 55 I 55.00 110.00 StorageIIPress T Temp Location DRUM/BARREL-NONMETAL IAmbient~AmbientlSOUTH CHEMICAL WAREHOUSE -- Conc~ Components I MCP ---~uide 3.0% ICaustic Potash IModeratel 60 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 7 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-023 MAGNA All4/AROMATIC PETRO SOLVENT Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: Trade Secret: No Form: Liquid. Type: Mixture~ Days: 365 Use: DRILLING Daily Max GALI Daily Average GAL I Annual Amount GAL -- 55 ~ 55.00 110.00 Storage Press T TempI Location DRUM/BARREL-METALLIC Ambient~AmbientlSOUTH CHEMICAL WAREHOUSE -- Conc~ Components MCP ---/Guide 44~0% INaphtha ModerateI 27 02-011 SODIUM HYDROXIDE, FLAKE Solid 100 Moderate · Fire, Immed Hlth, Delay Hlth LBS CAS #: 1310-73-2 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: CLEANING Daily Max LBS I Daily Average LBS I Annual Amount LBS 100 I 100.00 300.00 Storage Press T Temp~ Location DRUM/BARREL-NONMETAL Ambient IAmbient I SOUTH CHEMICAL WAREHOUSE -- Conc~ Components· MCP ---~uide 100.0% I Sodium Hydroxide ModerateI 60 02-039 SOLVENT/683 Liquid. 200 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: 8032-32-4 .Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING Daily Max GAL200I~ Daily Average200.00GAL I Annual Amount200.00GAL -- Storage Press T Temp~ Location METAL CONTAINR-NONDRUM AmbientlAmbientlWAREHOUSE A, WESTSIDE -- Conc Components MCP ---~uide 100.0% I.Cleaning Solvent .~ [Moderate~' 27 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 8 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-041 $-90 Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: 111-76-2 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: ADDITIVE Daily Max GALI Da~ly Average GAL I Annual Amount GAL 55 ~ 55.00 55.00 Storage Press T TempI Location DRUM/BARREL-NONMETAL Ambient~AmbientlSOUTH CHEMICAL WAREHOUSE -- Conc Components MCP ---TGuide 100.0% IEthylene Glycol Monobutyl Ether IModeratel 26 02r008 AMMONIUM CHLORIDE Solid 5000 Low · Immed Hlth LBS CAS #: 12125-02-9 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: DRILLING Daily Max LBSI Daily Average LBS ----~ Annual Amount LBS -- 5,000 I 5,000.00__ 20,000.00 Storage Press T TempI Location BAG Ambient~AmbientlWAREHOUSE C, NORTHWEST -- Conc Components MCP ---FGuide 100.0% IAmmonium Chloride ILow ~ 31 02-030 HYDRAULIC OIL Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL CAS #: 112345 Trade S6~ret: No Form: Liquid Type: Pure Days: 365 Use: LUBRICANT Daily Max GALI Daily Average GAL I Annual Amount GAL 100 ~ 50.00 200.00 Storage Press T TempI LocatiOn METAL CONTAINR-NONDRUM AmbientlAmbientlWAREHOUSE A, SOUTH -- Conc Components MCP ---/Guide 100.0% IHydraulic Brake Oil ILow ~ 27 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 9 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-026 KEROSENE Liquid 55 Low ~ Fire, Delay Hlth GAL CAS #: 8008-20-6 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: HEATING Daily Max GALI Daily Average GAL' I Annual Amount GAL 55 ~ 55.00 100.00 Storage Press T Temp 'Location DRUM/BARREL-METALLIC Ambient/AmbientlSOUTH.CHEMICAL WAREHOUSE -- Conc~ Components ~ MCP ---TGuide 100.0% IKerosene IModeratel 27 02-032 OXYGEN Gas 900 Low · Pressure, Immed Hlth GAL CAS #: 7782-44-7 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: FABRICATION Daily Max GALI Daily Average GAL I Annual Amount GAL 900 I '~ 840.00 4,500.00 Storage I Press T Temp I Location PORT. PRESS. CYLINDER Above /Ambient SOUTHWEST CORNER -- Conc Components MCP ---FGuide 100.0% [Oxygen, Compressed ILow ! 14 02-031 TRANSMISSION FLUID Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL CAS #: 0 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: LUBRICANT Daily Max GAL100I~ Daily Average50.00GAL [ Annual Amount200.00GAL -- Storage Press T TempI Location METAL CONTAINR-NONDRUM Ambient/AmbientlWAREHOUSE A, SOUTH -- Conc Components MCP --~Guide 100.0% ITransmission Fluid (Petroleum-Based) ILow ~ 27 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 10 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-028 WASTE OIL (NA 9189) Liquid 300 Low · Fire, Immed Hlth, Delay Hlth GAL CAS #: 221 Trade Secret: No Form: Liquid Type: Waste Days: 365 Use: WASTE Daily Max GALI Daily Average GAL I Annual Amount GAL 300 ~ 200.00 1,000.00 StorageIIPress T Temp Location ABOVE GROUND TANK IAmbientlAmbientlWaREHOUSE A, SOUTH -- ConcI ComponentsI MCP ---TGuide 100.0% IWaste Oil, Petroleum Based ILow ~ 27 02-040 SODA ASH Solid 3000 Low · Fire, Immed Hlth LBS CAS #: 497-19-8 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: WATER TREATMENT Daily Max LBSI Daily Average LBS I Annual Amount LBS m 3,000 ~ 3,000.00 1,000.00 Storage Press T TempI Location BAG Ambient~AmbientlWAREHOUSE C, NORTH -- Conc Components MCP ---TGuide 100.0% ISodium Carbonate ILow ! 60 02-042 S-60/DIESEL Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL CAS #: 68476-34-6 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: CLEANING Daily Max GAL I Daily Average GAL [ Annual Amount GAL 100 I 100.00 ~ 100.00 Storage Press T TempI - Location METAL CONTAINR-NONDRUM Ambient I Ambient I WAREHOUSE A, SOUTHWEST -- Conc Components MCP ---~uide 100.0% }Diesel Fuel No.2 IModerateI 27 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 11 02 - Fixed.Containers on Site Hazmat Inventory Detail in MCP Order 02-003 HYDROXYETHYL CELLULOSE Solid 10000 Minimal · .~ LBS CAS #: 9004-62-0 Trade Secret: No Form: Solid Type: Pure DayS: 365 Use: DRILLING Daily Max LBS I Daily Average LBS I Annual Amount LBS -- 10,000 i' 6,000.00 40,000.00 Storage Press_IT Temp Location BAG Ambient[AmbientlWAREHOUSE C, NORTH -- Conc Components MCP ----~uide 100.0%. [Hydroxyethyl Cellulose IMinimal I 1 02-029 MOTOR OIL Liquid 300 Minimal · Fire, Immed Hlth, Delay Hlth GAL CAS #: 8020835 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: LUBRICANT Daily Max GALI Daily Average GAL I Annual Amount GAL 300 ~ 200.00 600.00 Storage Press T Temp~ ' Location METAL CONTAINR-NONDRUM Ambient[AmbientlWAREHOUSE A, SOUTH -- Conc~ Components MCP ~Guide 100.0% IMotor Oil, Petroleum. Based Minimal ! 27 02-037 POTASSIUM CHLORIDE Solid 15000 Minimal · Immed Hlth LBS CAS #: 7447-40-7 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: DRILLING Daily Max LBS Daily Average LBS I Annual Amount LBS -- 15,000 I 8,000.00 100,000.00 Storage Press T Temp Location BAG Ambient[AmbientlWAREHOUSE C,·'NORTHWEST -- Conc Components i MCP ---~uide 95.0% IPotassium Chloride Minimal I · 7 10/12/93 BAKER SAND CONTROL' 215-000-000759 Page 12 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-035 SILICA SAND Solid 1400000 Minimal · Immed Hlth, Delay Hlth LBS CAS #: 14808-60-7 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: DRILLING Daily Max LBS Daily Average LBS Annual Amount LBS 1,400,000 I 1,000,000.00 I 1,400,000.00 Storage Press T Temp~ Location BAG AmbientlAmbientlWAREHOUSE B, NORTH -- Conc Components MCP ---TGuide 100.0% ISilicon Dioxide IMinimal I 7 02-038 SODIUM CHLORIDE Solid 5000 Minimal · Immed Hlth LBS CAS #: 7647-15-6 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: DRILLING Daily Max LBS I Daily Average LBS ] Annual Amount LBS 5,000 I 5,000.00 20,000.00 Storage Press T TempI Location BAG Ambient~Ambient IWAREHOUSE C, NORTHWEST -- ConcI Components I MCP ---~uide 95.0% ISodium Chloride IMinimal I 7 02-009 SULFAMIC ACID Solid 800 Minimal · Immed Hlth LBS CAS #: 5329-14-6 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: DRILLING Daily Max LBS800Ii . Daily Average400.00LBS I Annual Amount3,500.00LBS -- Storage Press T TempI Location BAG Ambient~AmbientlWAREHOUSE C, SOUTHWEST -- Conc Components MCP --~Guide 100.0% ISulfamic Acid IMinimal I 60 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 13 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-020 UNION CARBIDE UCAR 310/AMINE/GLYCOL Liquid 200 Unrated · Immed Hlth GAL CAS #: Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: DRILLING Daily Max GALI Daily Average GAL I Annual Amount GAL 200 ~ 150.00 200.00 Storage~~Press T Temp Location DRUM/BARREL-METALLIC IAmbientlAmbientlWaREHOUSE C, SOUTHWEST -- Conc ~ Components ~ MCP ~'uide 02-043 RDX/TRIMETHYLENE Solid 600 Unrated · . LBS CAS #: 0 Trade Secret: 'No' Form: Solid Type: Pure Days: 365 Use: BLASTING Daily Max LBSI Daily Average LBS I Annual Amount LBS -- 600 I 2.00 9,000.00 Storage Press T TempI Location OTHER - SPECIFY AmbientlAmbientlWAREHOUSE B, SOUTH -- Conc Components MCP ---~uide 100.0% IRDX/TRIMETHYLENE Iunrated I 0 02-045 DINITROPYRIDINE Solid 600 Unrated. · Fire LBS CAS #: Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: BLASTING Daily Max LBS 'I Daily Average LBS I Annual Amount LBS 600 ~ 2.00 2.00 Storage Press T Temp Location OTHER - SPECIFY I Ambient/Ambient I WAREHOUSE B, SOUTH -- Conc Components MCP ---~uide 100.0% IPYX/DINITROPYRIDINE. lunrated I 0 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 14 02 - Fixed COhtainers on Site Hazmat Inventory Detail in MCP Order 02-046 PRIMADET Solid 600 Unrated · Fire LBS' CAS #: Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: BLASTING Daily Max LBSI Daily Average LBS I Annual Amount LBS -- 600 ~ 2.00 2.00 Storage Press T TempI · Location OTHER - SPECIFY Ambient[Ambient[WAREHOUSE B, SOUTH -- Cone Components MCP ---TGuide 100.0% IPRIMADET Iunrated I 0 02-005 POLYTEX' Solid 1000 Unrated · LBS CAS #: 1309-48-4 Trade Secret: Yes Form: Solid Type: Pure Days: 365 Use: DRILLING -- Daily Max LBSI Daily Average LBS I Annual Amount LBS 1,000 i '~ 1,000.00 1,000.00 Storage I Press T Temp Location BAG IA mbientlAmbientlSOUTH CHEMICAL'WAREHOUSE -- Cone , Components ~ MCP ---TGuide 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 15 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation ALL EMPLOYEES KNOW AND ARE AWARE OF SITE EVACUATION PROCEDURES AND THE PROPER NOTIFICATION PROCEDURES IF THERE IS A HAZARDOUS RELEASE. THE FIRS.T STEP IS TO CALL 911 AND TO GIVE THEM ALL INFORMATION ABOUT THE RELEASE. CALL THE COMPANY RESPONSE TEAM AND TO CALL THE OFFICES OF EMERGENCY SERVICES WHEN AN EMERGENCY SITUATION PRESENTS ITSELF ALL EMPLOYEES WILL ASSEMBLE AT THE COFFEE BREAK AREA WHICH IS IN FRONT OF THE MECHANIC SHOP IN THE MAIN WAREHOUSE. SAFETY OFFICERS AND EMERGENCY RESPONSE TEAM WILL BE NOTIFIED. A PLAN OF ACTION WILL BE IMPLEMENTED. <3> Public Notif./Evacuation TO THE NORTH, WEST AND SOUTH OF OUR ESTABLISHMENT THE BUSINESSES STAY'UNDER THE SAME NAME, HOWEVER, TO THE EAST'AND SOUTHWEST, THE BUSINESSES HAVE CHANGED DURING TIME. I HAVE INFORMED CRAIG PARKER AND SEVERAL OTHER KEY PEOPLE AS TO THE NEED OF A PUBLIC EVACUATION PLAN. WE PLAN TO VERBALLY, IN PERSON, NOTIFY OUR NEIGHBORS IN THE CASE OF A THREATENING HAZARDOUS MATERIALS RELEASE. ADJACENT COMPANIES AROUND OUR FACILITY WILLBE NOTIFIED BY WORD OF MOUTH AND BY PHONE IF POSSIBLE. AT THIS TIME THE PROPER AUTHORITIES WILL ALSO BE NOTIFIED. <4> Emergency Medical Plan WE HAVE EYE WASH, SHOWER AND SMALL MEDICAL .KIT ON HAND. VALLEY MEDICAL CENTER - 5700 STOCKDALE HIGHWAY - 324-4014 MEMORIAL HOSPITAL - 420 34TH STREET - 327-1792 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 16 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> ReleaSe Prevention WE HANDLE ONLY SMALL AMONTS OF HAZARDOUS MATERIALS. USUALLY EITHER DRY IN 55 POUND SACKS OR LIQUID IN 55 GALLON DRUMS. WE HANDLE CHEMICALS CAREFULLY WITH THE PROPER EQUIPMENT. WE CAN HANDLE SMALL CLEAN UPS OF RELEASES WITH THE EQUIPMENT WE HAVE ON HAND. <2> Release Containment WE HAVE ASPHALT BERMS SEPARATING CHEMICALS. ALSO A CHEMICAL HANDLING AREA WHICH IS BERMED WITH A NON LEACHING SUMP. <3> Clean Up EVERYONE AT FACILITY IS TRAINED. WE HAVE CLEAN UP EQUIPMENT AT FACILITY; PILLOWS, DRY ABSORBENT, SAFETY GEAR, ETC. WE HAVE AN EMPLOYEE RESPONSE TEAM. MSDS ARE AVAILABLE TO PROVIDE~PROPER SPILL OR LEAK PROCEDURES AND SPECIAL PROTECTION INFORMATION. <4> Other Resource Activation 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 17 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards WASTE CONTAINERS MUST HAVE DATE 90 DAYS BETWEEN DISPOSAL. SOIL IN DRUMS NEEDS TO BE DATED 90 DAYS BETWEEN DISPOSAL. <2> Utility Shut-Offs A) GAS - NORTH CENTER PROPANE TANK - SOUTHEAST B) ELECTRICAL - NORTH CENTER IN MAIN BUILDING C) WATER - NORTH CENTER NEAR MAILBOX D) SPECIAL - NONE E) LOCK BOX - NO '<3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - THERE ARE FIRE EXTINGUISHERS AT ALL APPROPRIATE LOCATIONS. THERE ARE NO SPRINKLERS'OR FIRE ALARMS. THE RESPONSE TEAM WOULD BE THE SAME AS THE HAZARDOUS MATERIALS TEAM. FIRE HYDRANT - NORTH CENTER OF FACILITY ON ALDRIN COURT. VARIOUS FIRE STAND PIPE CONNECTIONS MOSTLY IN CENTER OF FACILITY. <4> Building Occupancy Level 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 18 00 - Overall site <G> Training <1> Page 1 WE HAVE 34 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE WE ARE IN COMPLIANCE WITH OSHA CFR1910.1200. WE DO HAVE AND USE A HAZARDOUS COMMUNICATION PROGRAM. THERE ARE MONTHLY SAFETY MEETINGS IN WHICH HAZARDOUS MATERIALS ARE ALWAYS DISCUSSED. ? <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 19 00 - Overall Site <M> Inspections 07/15/88 / / 08/15/88 FOLLOW UP - WASTE OIL MOVED AWAY FROM ACID AND / / PERRY 02/21/91 OK / / PERRY 08/26/92 OK / / PERRY 09/16/93 FOLLOW UP. / / HUEY 10/11/93 FOLLOW UP INSPECTION IN ONE MONTH. / / 10/12/93 BAKER SAND CONTROL 215-000-000759 Page 20 00 - Overall Site <M> Events "M" Overall List 07/15/88 / / 'INSTALL BARRIER AT BOTTOM OF WALL BETWEEN ROOMS IN SOUTH WAREHOUSE. REPACK BROKEN CONTAINERS. MOVE WASTE OIL AWAY FROM ACID AND AMMONI NITRATE. FOLLOW UP 8-15 08/15/88 FOLLOW UP - WASTE OIL MOVED AWAY FROM ACID AND / / S PERRY 02/21/91 OK / / $ PERRY 08/26/92 OK / / S PERRY 09/16/93 FOLLOW UP. / / R HUEY 10/11/93 FOLLOW UP INSPECTION IN ONE MONTH'. / / Business Name: ~/Z:~l~ ~-Z(~/7~' ....L~~? Location: ~ ~ ~[ ~~ ~/~ ~- Business Identification No. 215-000 ~00~ ~op of Business Plan) Station No. / ~ Shi~ /~ Inspector ~t~ /0 0 ~ Adequate Inadequate~ Verification of ,nven,o~ Materials ~r~/J~- /~ '~L -- 5~/~, ~ VerEication ~ Quantities Verification of Loc~ion ~ ~ ~ SEP ~ 0 1993 ~Y~- Proper Segregation of Uateri~ Comments: Verification of MSDS Availabli~ Number of Employees Verification of H~ Mat Training Comments: Verification of Abaement Supplies & Procedures Comments: Emergency Procedures Posted Containers Properly ~beled Comments: Verificaion of Facility Oiagram Special H~ards Associated with this Facility: Correction Needed ~ B ~ umness Owner/Manager FD 1~ (~v. 1-~) ~i~-H~ ~t D~. Yalow-S~n ~ Pink-Busine~ ~y 04109/93 . SAND CONTROL 215-000 075 Page 3 t Ir~verstory List ir~ ~CP Order 0~ - Fi~ed Containers on Site Plr~-Ref Nar~e/Hazard~ Forr~ ~ax Qty h~CP --(.~ 1 TRANSMISSION FLUID Liquid 100 Lc, w Fire, Ir~r~ed Hlth, Delay Hlth GAL "'~ ~-028 WASTE OIL (NA 9189) Liquid 300 Low V Fire, Ir~r~ed Hlth, Delay Hlth GAL ~~]~; SODA ASH Solid 3000 Low Fire, Irnr~ed Hlth LBS -04~ S-60/DI ESEL Liquid 100 Low Fire, Ir~'~rned Hlth, Delay Hlth GAL o~--(.]o~ HYDROXYETHYL CELLULOSE Sol id 10000 Mir~ir~al LBS ~¢ (.~D MOTOR OIL Liquid 300 Mir~ir~al Fire, Irn~d Hlth, Delay Hlth GAL o~.-~37 POTfiSSIUM CHLORIDE Sol id 15000 ~ir~ir~al I r~rned H 1 t h LBS ~-~.)~ SILICA SAND Sol id 1400¢[~00 Minir~al Ir,~rned Hlth, Delay Hlth / L~S ~038 SODIUM CHLORIDE '*,- ~ _, 1 i d 5000 M i r~ i r~a 1 I rnr~ed Hlth LBS -009 SULFAM I C AC I D ~-, ou 1 i d 800 M i r~ i r~a 1 I m~ed Hlth LBS ~~. BORAXDelay Hlth ¢~ ~%~--~ Sc, lid LEo~¢*'75 Ur~rated ~2-- G~C ~C, ~ ' I E- So I i d 220 Unrat ed Fire, Delay Hlth 9~ ~ LBS ~.}~<> UNION CARBIDE UCAR 310/AMINE/GLYCOL Liquid 200 Ur~rated I r~'irned H 1 t h GAL LBS ~-0.~ DINI ~ ROR ~RIDINE Sol id 600 Ur~rated Fire LBS ~.02-046. PR I MADET Sol id 600 Unrat ed Fire LBS ... POLYTEX id 02-0~]5 Sol 1000 U;'~r at ed LBS BAKER SAND CONTROL - 5551 ALDRIN COURT EXPLOSIVES REVIEW & INSPECTION March 4, 1993 I. Nature of Business & Process II. Classes of Explosives & Explosives Train III. Baker's Explosive Inventory IV. Facility Layout . V. Specific Hazards VI. Fire Suppression CLASSES OF EXPLOSIVES CLASS A - explosives which either detonate or present a maximum hazard in another way such as extreme sensitivity. Also know as high explosives. DETONATION- rapid, self-propagating decomposition accompanied by a high pressure shock wave. Occur at rates faster than the speed of sound. CLASS B - explosives which function by very rapid autocombustion. Also known as Iow explosives. DEFLAGRATION - decomposition occurs at rates slower than the speed of sound. CLASS C - explosives are those considered to present minimal hazard. They may contain Class A or B explosives but only in restricted amounts. EXPLOSIVES TRAIN DIAGRAM IGNITER PRIMER DETONATOR \' BOOSTER CHARGE / / / MAIN CHARGE PRIMARY/INITIATING EXPLOSIVES~ are much more sensitive to heat, shock, friction, static or flames than a main charge. BOOSTER/SECONDARY EXPLOSIVES- lie between the primary explosive and the main charge. The relatively weak shock of the primary is built up to ensure that a "high order" or complete detonation occurs in the insensitive main charge. MAIN CHARGE EXPLOSIVE- are less sensitive to provide some safety for handling laCger quantities. BAKER SAND CONTROL EXPLOSIVES INVENTORY RDX or Cyclonite (cylco- 1,3,5, trimethlyene-2,4,6 trinitramine) HMX (cyclotetramethylene tetranitramine) PYX [2,6-bis(picrylamino)-3,5-dinitropyridine] * solid shaped charges only used at Baker Sand * used as main charge * class A, high explosive * inhalation can result in respiratory system irregularity slightly toxic by ingestion * becomes unstable with exposure to extreme heat, impact or electrostatic discharge * burning or explosion produces hazardous nitrogen oxide fumes * soap and water should be used for decontamination Primadet nonelectric detonators (pentaerythritol tetranitrate, lead azide) * Aluminum shell with plastic tube attached * Used as initiator * Burning produces hazardous lead and nitrogen oxide fumes * Incompatible with acids and alkalies * Becomes unstable with exposure to heat, shock, friction or impact BAKER SAND CONTROL EXPLOSIVES INVENTORY (PG. 2) Teledyne primers (lead azide) * Stainless steel shell * Used as' initiator * Percussion actuated - no electronic detonators used by Baker Sand * Class C DOT designation due to small quantities per unit Bidirectional boosters (HMX or PYX) * Aluminum shell containing explosive and polyethylene end plug Primacord (80 grain RDX or HMX, nylon) * Detonator * 80 grains of explosive are contained per lineal foot * Class C DOT designation UP TO 600 POUNDS OF EXPLOSIVES & PRIMACORD MAY BE IN THE EXTERIOR MAGAZINE FOR DAY USE ONLY UP TO 2 POUNDS OF BLASTING CAPS MAY BE IN THE INTERIOR MAGAZINE ON A ROUTINE BASIS (2 pounds = net weight of explosive) LOADED GUNS MAY BE STORED IN THE INTERIOR BUNKER AREA DURING LOADING, PRIOR TO TRANSPORT FOR UP TO 5 DAYS. , EXISTING EXISTING WAREHOUSE 'A' WAREHOUSE 'B' .~- ~ ~ ...... : ...... [ EXISTING : ~: OFF I CE ~A%~L ~yOeR~T F.O.o., . , ~ ALORIN CT SPECIFIC HAZARDS OF EXPLOSIVES * Violent, explosive decomposition may be initiated by shock, heat, static or friction * Explosives become more sensitive to shock as heat increases. * High explosives do not always explode immediately upon heating. Initiation of an explosion is dependent upon degree of confinement, speed of heating and quantity. * Decomposition is usually signaled by evolution of brownish-orange nitrogen gases. * Explosives are self-oxidizing. They don't need air to burn. * Danger may still exist following a detonation. Low order or incomplete detonation may scatter pieces of still dangerous explosives. FIRE SUPPRESSION TACTICS No attempt shall be made to fight a fire that cannot be contained Or controlled before it. reaches explosive materials. In such cases, all personnel shall be immediately evacuated to a safe location, and the area shall be guarded from entry by spectatorS or intruders. NFPA 495, 2-1.1 Vehicle Accident - No Fire # Eliminate ignition sources Isolate area Wash spilled fuels into diked area away from explosives or foam spill until explosives can be removed Remove explosives from area ASAP Vehicle Accident - Fire # Contain fire if possible when it has not yet entered the area where explosives are. Thoroughly wet all explosives with water. Fire extinguishing media which exclude oxygen are not effective due to self oxidizing capacity of explosives. If fire involves a spillage of flammable liquids or unstable/reactive chemicals, effect of water cooling is minimal, evacuate area. # From Explosive & Toxic Hazardous Materials, James H. Meidl. Glenco Press, 1970. POTENTIAL HAZARDS FIRE OR EXPLOSION MAY EXPLODE AND THROW FRAGMENTS I MiLE OR MORE IF FIRE REACHES CARGO. HEALTH HAZARDS Fire may produce irritating or poisonous gases. EMERGENCY ACTION IF FIRE REACHES CARGO, DO NOT FIGHT FIRE. IF YOU KNOW OR SUSPECT THAT HEAVILY-ENCASED EXPLOSIVES, SUCH AS BOMBS OR ARTILLERY PROJECTILES ARE INVOLVED, STOP ALL TRAJ=FIC AND BEGIN TO EVACUATE ALL PERSONS, INCLUDING EMERGENCY RESPONDERS, FROM THE AREA IN ALL DIRECTIONS FOR 5000 FEET (1 MILE) FOR RAIL CAR OR 4000 FEET (3/4 MILE) FOR TRACTOR/TRAiLER. WHEN HEAVILY-ENCASED EXPLOSIVES ARE NOT INVOLVED, EVACUATE THE AREA FOR 2500 FEET (1/2 MILE) IN ALL DIRECTIONS. Positive pressure self-contained breathing apparatus (SCBA) and structural firefighters' protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, especially if there is no local hazardous materials team available. FIRE Carge Fires~ DO NOT FIGHT FIRE WHEN IT REACHES CARGO. Withdraw from area and let fire burn. Trv¢iz and Equipment liresz Try to prevent fire from reaching the explosive cargo compartment. Flood with water; if no water is available use CO2, dry chemical or earth. Promptly isolate the scene by removing all p~rse.~ from the vicinity of the incident if there is a fire. First, move people out of line-of-sight of the scene and away from windows. Then, obtain more information and specific guidance from competent authorities listed on the shipping papers. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area. Do not touch or walk through, spilled material. FIRST AID Call emergency medical care. Use first aid treatment according to the nature of the injury. MARiOAla VIIART ~=lVl3OJqX3 RBTIHr. OI R=iMIRCi ROTAHO'i~a / / ? 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Nature of Buisness & Process II. Classes of Explosives & Explosives Train III. Baker's Explosive Inventory IV. Facility Layout & Saftey V. Specific Hazards VI. Fire Supression CLASSES OF EXPLOSIVES CLASS A - explosives which either detonate or present a maximum hazard in another way such as extreme sensitivity. Also knorr/as high explosives. DETONATION- rapid, self-propagating decomposition accompanied by a 13Jgb pressure shock wave. Occur at rates faster than the speed of s°unc~.~ CLASS B - explosives which function by very rapid autocombustion. Also known as' Iow explosives. DEFLAGRATION - decomposition occurs at rates slower than the speed of sound. CLASS C - explosives are those considered to present minimal hazard. They may contain Class A or B explosives but only in restricted amounts. EXPLOSIVES TRAIN DIAGRAM IGNITER- (~o,~ PRIMER DETONATOR- -' MAIN CHARGE PRIMARY/INITIATING EXPLOSIVES- are much more sensitive to heat, shock, friction, static or flames than a main charge. BOOSTER/SECONDARY EXPLOSIVES- lie between the primary explosive and the main charge. The relatively weak shock of the primary is built up to ensure that a "high order" or complete detonation occurs in the insensitive main charge. MAIN CHARGE EXPLOSIVE- are less sensitive to provide some safety for '.LL handling lal:ger quantities. BAKER SAND CONTROL EXPLOSIVES INVENTORY RDX or Cyclonit[~' (cylco- 1,3,5, trimethlyene-2,4,6 trinitramine) H MX (cyclotetram ethyl ene tetran itramin e) %~(L~r~ ~(~* greypackagedPOWder or whitepound,CrystalSnet, (','¢.>' O * in 25-50 fiberboard drums · class A, high explosive · inhalation can result in respiratory system irregularity slightly toxic by ingestion · becomes unstable with exposure to extreme heat, impact or electrostatic discharge · burning or explosion produces hazardous nitrogen oxide fumes · soap and water should be used for decontamination [2,6-bis(picrylamino)-3,5-dinitropyridine] * yellow to orange crystalline substance * all other characteristics noted for HMX and RDX apply Primadet nonelectric detonators (pentaerythritol tetranitrate, lead azide) * Aluminum shell with plastic tube attached * Burning produces hazardous lead and nitrogen oxide fumes * IncomP~.tible with acids and alkalies * Becomes 'unstable with exposure to heat, shock, friction or impact BAKER SAND CONTROL EXPLOSIVES INVENTORY (PG. 2) Teledyne primers (lead azide) * Stainless steel shell % * Percussion actuated Bidirectional~(HUX or PYX) * Aluminum shell containing explosive and polyethylene end plug Primacord '(80 grain RDX or HMX, nylon) * 80 grains of explosive are contained per lineal foot UP TO 600 POUNDS OF EXPLOSIVES & PRIMACORD MAY BE IN THE EXTERIOR MAGAZINE FOR DAY USE ONLY (cz)lb UP TO 2 POUNDS OF BLASTING CAPS MAY BE IN THE INTERIOR MAGAZINE ON A ROUTINE BASIS (2 pounds = net weight of explosive) LOADED GUNS MAY BE STORED IN THE INTERIOR BUNKER AREA DURING LOADING, PRIOR TO TRANSPORT FOR UP TO 5 DAYS. 03/04/93 BAKER SAND CONTROL 215-000-000759 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Quantity MCP 02-033 ACETYLENE Gas 400 High · Fire, 'Pressure, Immed Hlth, Delay Hlth FT3 02-013 FORMIC ACID Liquid 15 High · Fire, Reactive, Immed.Hlth, Delay Hlth GAL 02-017 HYDROCHLORIC ACID Liquid 1000 High · Reactive, Immed Hlth' GAL 02-027 LIQUEFIED PETROLEUM GAS (PROPANE) Gas 430 High · Fire, Pressure, Immed Hlth GAL 02-007 SODIUM HYPOCHLORITE Liquid 115 High · Reactive, Immed Hlth GAL 02-044 CYCLOTRIMETHYLENE Solid 600 High · Fire LBS 02-025 A-100/CRONOX 265/ISOPROPANOL Liquid 55 Moderate · Fire, Delay Hlth GAL 02-018 BIOCIDE GLUTARALDEYDE Liquid 55 Moderate · Immed Hlth, Delay Hlth GAL 02-015 DEFOAMER/POTASSIUM HYDROXIDE Liquid 55 Moderate · Immed Hlth GAL 02-023 MAGNA All4/AROMATIC PETRO SOLVENT Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-011 SODIUM HYDROXIDE, FLAKE Solid 100 Moderate · Fire, Immed Hlth, Delay Hlth LBS 02-039 SOLVENT/683 Liquid 200 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-041 S-90 Liquid 55 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-008 AMMONIUM CHLORIDE Solid 5000 Low · Immed Hlth LBS 02-030 HYDRAULIC OIL Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL 02-026 KEROSENE Liquid 55 Low · Fire, Delay Hlth GAL 02-032 OXYGEN Gas 900 Low · Pressure, Immed Hlth GAL 03/04/93 BAKER SAND CONTROL 215-000-000759 Page 3 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Quantity MCP 02-031 TRANSMISSION FLUID Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL 02-028 WASTE OIL (NA 9189) Liquid 300 Low · Fire, Immed Hlth, Delay Hlth GAL 02-040 SODA ASH Solid' 3000 Low · Fire, Immed Hlth LBS 02-042 S-60/DIESEL Liquid 100 Low · Fire, Immed Hlth, Delay Hlth GAL 02-003 HYDROXYETHYL CELLULOSE Solid 10000 Minimal · LBS 02-029 MOTOR OIL Liquid 300 Minimal · Fire, Immed Hlth, Delay Hlth GAL 02-037 POTASSIUM CHLORIDE Solid 15000 Minimal · Immed Hlth LBS 02-035 SILICA SAND Solid 1400000 Minimal · Immed Hlth, Delay Hlth LBS 02-038 SODIUM CHLORIDE Solid 5000 Minimal · Immed Hlth LBS 02-009 SULFAMIC ACID Solid 800 Minimal · Immed Hlth LBS 02-004 BORAX Solid 75 Unrated · Delay Hlth LBS 02-002 MAGNESIUM OXIDE Solid 220 Unrated · Fire, Delay Hlth LBS 02-020 UNION CARBIDE UCAR 310/AMINE/GLYCOL Liquid 200 unrated · Immed Hlth GAL 02-043 RDX/TRIMETHYLENE Solid 600 Unrated · LBS 02-045 DINITROPYRIDINE Solid 600 unrated · Fire LBS 02-046 PRIMADET Solid 600 Unrated · Fire LBS SPECIFIC HAZARDS OF EXPLOSIVES * Violent, explosive decomposition may be initiated by shock, heat, static or friction * Explosives become more sensitive to shock as heat increases. * High explosives do not always explode immediately upon heating. Initiation of an .explosion is dependent upon. degree of confinement, speed of heating and quantity. * Decomposition is usually signaled by evolution of brownish-orange nitrogen gases. ~ ¢____..\~ ~ N~)M \ \ * Explosives are self-oxidizing. They don't need air to burn. * Danger may still exist following a detonation. Low order or incomplete detonation may scatter pieces of still dangerous explosives. FIRE SUPPRESSION TACTICS No attempt shall be made to fight a fire that cannot be contained or controlled. before it. reaches explosive materials. In such cases, all personnel shall be immediately evacuated to a safe location, and the area shall be guarded from entry by spectators or intruders. NFPA 495, 2-1.1 Vehicle Accident - No Fire # Eliminate ignition sources Isolate area Wash spilled fuels into diked area away from explosives or foam spill until explosives can be removed Remove explosives from area ASAP Vehicle Accident - Fire # %5¢.~ Contain fire if possible when it has not yet entered the area where explosives are. Thoroughly wet all explosives with water. Fire extinguishing media which exclude oxygen are not effective due to self oxidizing capacity of explosives. '-~.Or-,'4 If fire involves a spillage of flammable liquids or unstable/reactive chemicals, effect of water copling is minimal, evacuate area. # From Explosive & Toxic Hazardous Materials, James H. Meidl. Glenco Press, 1970. POTENTIAL HAZARDS FIRE OR EXPLOSION M~Y EXPLODE AND THROW FRAGMENTS 1 MILE OR MORE IF FIRE REACHES CARGO. HEALTH HAZARDS Fire may produce irritating or poisonous gases. EMERGENCY ACTION IF FIRE REACHES CARGO, DO NOT FIGHT FIRE. IF YOU KNOW OR SUSPECT THAT HEAVILY-ENCASED EXPLOSIVES, SUCH AS BOMBS OR ARTILLERY PROJECTILES ARE INVOLVED, STOP ALL TRAFFIC AND BEGIN TO EVACUATE ALL PERSONS, INCLUDING EMERGENCY "~n~_~.. o3aN~ c-~ ~-,lo~- RESPONDERS, FROM THE AREA IN ALL DIRECTIONS FOR 5000 FEET '~r'xc'ooo ~c-c;3'¢¢-d~s (1 MILE) FOR RAIL CAR OR 4000' FEET ('3/4 MILE) FOR TRACTOR/TRAILER. WHEN HEAViLY-ENCASED EXPLOSIVES ARE NOT INVOLVED, EVACUATE THE AREA FOR 2500 FEET (1/2 MILE) IN ALL DIRECTIONS. P~sitive pressure self-contained breathing apparatus'(SCBA) and structural firefighters' protective clothing will provide limited protection. CALL CHEMTREC AT 1-800-424-9300 AS SOON AS POSSIBLE, especially if there is no local hazardous materials team available. FIRE Carge Flresz DO NOT FIGHT FIRE WHEN IT REACHES CARGO. Withdraw from area and (et fire burn. Tru¢i(: and Equipment Fires: Try. to prevent fire from reaching the explosive cargo compartment. Flood with water; if no water is available use CO2, dry chemical or Promptly isolate the scene by removing' all p~rsenl from the vicinity of the incident if there is a fire. First, move people out of line-of-sight of the scene and. away from windows. Then, obtain more information and specific guidance from competent authorities listed on the shipping papers. SPILL OR LEAK Shut off ignition sources; no flares, smoking or flames in hazard area. Do not touch or walk through spilled material. FIRST AID Call emergency medical care. Use first aid treatment according to the nature of the injury. CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT 2101 H STREET S. D. JOHNSON November 9, 1992 BAKERSFIELD, 93301 FIRE CHIEF 326-3911 John Weirich Region Manager Baker Sand Control 5551 Aldrin Court Bakersfield, CA 93313 John: .I would like to thank you for the comprehensive facility tour that you provided for the B Shift fire companies on November 6. During the inspection three items of concern were discussed that warrant follow up action. 1. The lithium hypochlorite, an oXidizer, should not be stored with acids. It also is incompatible with flammable liquids. Per the Article 80 of the Uniform Fire Code, incompatible hazardous materials must be separated by a distance of at least 20 feet. 2. We reviewed the MSDS for A-100 and discovered that the existing hazardous materials inventory is incomplete. I have enclosed an inventory update based on the MSDS. Please review it for accuracy, sign and return it to me as soon as possible. 3. The firemen have requested that you label the exterior of the chemical supply building with the hazard classifications of the materials stored there. These classifications include flammable, corrosive and oxidizer. Please call me at 326-3979 if I'can be of any assistance regarding hazardous materials planning issues or code compliance. Sincerely, Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Captain Stan Perry Sand Control A Baker Hughes company 5551 ALDRtN COURT TELEPHONE (805) S34-2844 September 29, 1992 ~//~ ~. ~v ~(~ ,//~ City of Bakersfield 2101H Street Bakersfield, Ca. 93301 Dear Mr. Huey, In response to your letter dated, September 14, 1992. I have enclosed some information regarding the training of our Emergency Response Team. First, I should point out that all employees have been trained to initiate a response to a chemical release in the unlikely event of an incident. Each Baker Sand Control employee is provided access to Material Safety Data Sheets and related information. All employees know and are aware of site evacuation procedures and proper notification procedures if there is a hazardous release. The response team takes on a supervisory role in seeing to it that a plan of action be put into motion and that the proper authorities are notified. Baker'Sand Control has a vigorous safety program in place, but to summarize, here are some of the various training aids used they include: 1. Films 2. Handouts 3. Newspaper Articles 4. Safety Publications a) Hazardous Communication Program b) Chemical Hazard Communication c) "Working with Hazardous Waste?" d) "What is Hazardous Waste?" e) "An employees guide to HMIS" f) "Baker Sand Control Safety Guide" g) "Safe Practices Manual Policies & Guidelines" 5. Emergency Response Guide a) Chemical Release b) Fire c) Earthquake d) MSDS Sheets Page 2 The names of employees trained to respond to a chemical release: Stan Davis Neal Sampson Jeff Orton Chris Mulanax Dan Lehr Ricky Craighead Brian Duboise Emergency Response Team Members: Stan Miller Greg Horton Rick Relerford Andy Erberich I hope the information provided has beer helpful. If you have any further questions please do not hesitate to call. Sincerely yours, For Baker Sand Control Rick Relerford Pumping Specialist/Safety Coordinator RR/ep Enclosure BAKER MEMO TO: Ail Employees DATE: May 29, 1992 FROM: Rick Relerford SUBJECT: ~ous Materials Release andI COPIES TO: John Weirich ~ire Evacuation Planj Curt Cranford SAFETY OFFICERS PHONE NUMBERS PAGER NUMBERS Stan Miller 589-4492 321-2789 Rick Relerford 665-8108 321-2839 EMERGENCY (911) "'~' HAZARDOUS MATERIALS EMERGENCY SERVICES: CHEMTREC 1(800) 424-9300 - (include this on Bill of Lading) HAZARDOUS MATERIAL EMERGENCY RESPONSE TEAM: NAME PHONE NUMBER PAGER NUMBERS Stan Miller 589-4492 321-2789 Andy Erberich 835-8793 321-5387 Greg Horton 831-0855 321-2538 Rick Relerford 665-8108 321-2839 EMERGENCY PHONE NUMBERS: MINOR INJURIES Valley Industrial Medical 327-2225 Mon.- Fri. 8:00am - 5:00pm After 5:00pm take to Memorial Hospital or nearest hospital ACUTE INJURIES CALL AMBULANCE - 911 When an emergency situation presents itself all employees will assemble at the coffee break area which is in front of the mechanic shop in the main warehouse. Safety Officers and Emergency Response Team will be notified. A plan of action will be notified by word of mouth and by phone if possible. At this time the proper authorities will also be notified. FIRE DEPARTMENT 2101 H STREET S. D. JOHNSON September 11, 1992 By - ]AKERSFIELD,93301 FIRE CHIEF 326-3911 John Weirich Region Manager Baker Sand Control 5551 Aldrin Court Bakersfield, CA 93313 John: Enclosed is a set of instructions and a form to be used to revise the hazardous materials site map for the Baker Sand Control facility. As we discussed during our August inspection, the hazardous materials business plan amd map revisions must be submitted with in 30 days of the addition of new hazardous materials. I have also enclosed a request for certification of the training of Baker's emergency response team. After we receive the updated hazardous materials plans, I will contact you to schedule the tours of the facility for all of the responding fire companies. Please call me if l can be of any assistance. Sincerely, Barbara Brenner " .... '~"'"' Materials Planning T r, ir,'~ , ,,~., ,.,,.,,,-, , e,.,hn,,.,l_n cc: Ralph Huey September 14, 1992 Region Manager Baker Sand Control 5551 Aldrin Court Bakersfield, Ca. 93313 Dear Mr. Weirich: You have indicated in your management and Prevention Program that if a chemical release occurs at yoL facility your employees are trained to initiate an emergency response to that to incident. Please forward the of the employees who have been trained for this activity, a brief description, the individual, of his or her training level, hours of training and response capability, a copy of the documentation or certification of that training. This informatio~ of course, be essential in the unlikely event of an incident at your facility. Pleasethat information to our office by September 30, 1992. If you have any q need assistance please do not hesitate to call. Sincerely Yours, Ralph E. Huey Hazardous Materials Coordinator REH:vp CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT 2101 H STREET S. D. JOHNSON September 11, 1992 BAKERSFIELD, 93301 FIRE CHIEF 326-3911 John Weirich Region Manager Baker Sand Control 5551 Aldrin Court Bakersfield, CA 93313 John:. EncloSed is a set of instructionS and a form to be used to revise the hazardous materials site map for the Baker Sand Control facility. As we discussed during our August inspection, the hazardous materials business plan and map revisions must be submitted with in 30 days of the addition of new hazardous materials. I have also enclosed a request for certification of the training of Baker's emergency response team. After we receive the updated hazardous materials plans, I will contact you to schedule the tours of the facility for all of the responding fire companies. Please call me ill can be of any assistance. Sincerely, Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Q Bakersfield Fire Dept. ' Hazardous ~at. erials Division 2130 'G Street HAZARDOUS MATERIALS MANAGEMENT PLAN 1. 1o ovo~ fu~hor ocfion, to,urn ~hi~ form wl~hln 30 ~o~s o~ rocoipL 2. WPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below tot the business as a whole. 4. Be brief and cono~e as po~ible. SECTION 1' BUSINESS IDENTIFICATION DATA BUSINESS NAME: BAKER SAJ~TD CONTROL LOCATION: BAKERSFIELD MAILING ADDRESS: 5551 ALDRTN CT. BAKERSFIELD CA. 93313 834-2844 CITY: STATE:_ ZIP: PHONE: DUN & BRADSTREET NUMBER: 09-357-7377 SIC CODE: 1389 OIL & GAS WELL COMPLETIONS PRIMARY ACIIVIIY: OWNER: Baker Sand Control A-Division of .Baker Hughes Production Tools, Inc. MAILING ADDRESS: toro RANKIN RD., HOUSTON, TX. 77073 SECTION 2: EMERGENCY NOTIFICATION: CONTACT TITLE BUS. PHONE 2/('HR. PHONE 1. Staff Miller Field"Supervisor (805) '834-2844/(805) 589-4492 2. Rick Relerford Safety Coordinator: 834-2~4 / (805)"665-8108 !' ii? -.Bakersfield Fire Dept. HaZardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 7: MITIGATION, PREVENTION AND ABATEMENT PLAN: A. RELEASE PREVENTION STEPS: We handIe oniy smaii amounts of Hazardous MateriaIs usuaIly either dry in 50 pound sacks or iiqu±d in 55 §aiion drums. We handie chemicais carefuiiy with the proper equipment. We can handie smali ciean ups of releases with the equ±pment we have on hand. B. RELEASE CONTAINMENT AND/OR MINIMIZATION' We have asphalt berms separating chemicals. . Also a chemical handling area which is bermed with a non-leaching sump. C. CLEAN-UP PROCEDURES: / We have clean up.equipment at facility; pillow~, dry absorbent, safety gear, etc. We have an employee response team./MSDS sheets are available to provide proper spill or leak procedures a~d special protection information. SECTION 8: UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FA(~ILITY):: NATURAL GAS/PROPANE: Nat Gas-North Center Prooane - South~a,~t ELECTRICAL: North Center in main building WATER: North center near mailbox SPECIAL: None LOCK BOX: YES~ IF YES, LOCATION: SECTION 9: PRIVATE FlEE PROTECTION/WATER AVAILABILITY: A. PRIVATE FIRE PROTECTION: There are fire extinguishers at all appropriate locations. There are sprinklers and. a.,fire alarm in warehouse "B" ' B. WATER AVAILABILITY (FIRE HYDRANT): North Center of facility on Aldrin Ct. Various Fire stand pipe connections mostly in center of facility. SITE DIAGRAM' I----1 FACILITY DIAGRAM Business Name: . Business Address: ~,_~'1 ALO~EI./g For Office Use Only First In Station: Area M(~p # of Inspection Station: NORTH /% HAZARDOUS MATERIALS DIVISION Date Completed Business Name: Location: 5-~, ~ ~ j~\~,~.,.~. ~,..~_. AUG J I 1992 HAT.. It4AT. DiV. Business Identification No. 215-000 [~lS)"l~c{ (Top of Business Plan) Station No. "~ Shift ~ Inspector (}+,~'~'e-'~'~/E~n~. ~'t~ /¢,~. '~r.,.~'~' Adequate Inadequate Verification of Inventory Materials I~ Verification of Quantities Verification of Location Proper Segregation of Material Comments: Verification of MSDS Availablity Number of Employees! ~ Verification of Haz Mat Training comments: /~ '~-.-- Verification of Abatement Supplies & Procedures Comments: Emergency Procedures Posted Containers Properly Labeled Comments: Verificati°n °' Facility Diagram Special Hazards Associated with this Facility: ~,.,,,._._.~ / Violations: " All Items O.K. --~. Correction Needed F~652ess Owner/Manager (Rev. 1-90) W/~ite-Haz Mat Div. Yellow-Station Copy Pink-Business Copy CITY OF BAKERSFIELD HAZARDOUS MATERIALS INVE~RY Farm and Agriculture ~ Standard Business ' .!~ Page...2..of NON - TRADE SECRET ~SINESS NAMe.' Baker Sand Control OWNER NAME: R~'~r' .q~nd C~nt~l NAP[E OF THIS'FACILITY: Warehouse_A_ ,CATION: 5551 Ald'rin Ct. ADDRESS: 1010 Rankin Rd. STANDARD IND. CLASS CO5E:'1389 -- TY, ZIP: Bakersfield, Ca~ 9~ CITY, .ZIP: ~n,mrnn. T×. 77?Og DUN AND BRADSTREET NUMBER/FEDERAL ID # ONE #: (R~) RR/,-?8~4 . PHONE ~#~ ~(713) 443-7590 D ~ - ~ ~ 2 - REFER TO INSTRUCTIONS FOR PROPE~.~e~S-~,~ / ass Ty~e Max Average A~nual Measure f Daye Cent Cent Cent Use // Location Where ) % by/ Names of de ,,Code Amt Am~ Amt Unite on S~te T~ Press Tem~ Code _/ Stored ~n Yacilit~/ w~ See Instructions ~,Z ~ ~Z~h ~,,~ C.~.~. ~,r 7782-44-7 ~ '~ C.A.~. ~,r of Preeeure H~l%h Health f U.) P I 400 ] .390 13,500 lFt. 3 I 365 .1 04 ] 2 4 ]1 . 100 e ~ical and H~l~h ~za~ C.A.S. N~er 74-86-2 ~~ ~ '& C.A.8. N~er / (Che~k all t~ apply) /~ ...... , .~ ~~ Co~onent ~ 2 N~ & C.A.S. N~er / .: of Pressure ' ~lth H~lth Co~onent I 3 N~ & C,A,S, N~er I I I I I ,I I I I ,I I ., ~l~al ~nd B~l%h.~za~ C.A.S. U~er Componon~ I 1 ~a~ g C.A.8. (Check all t~t apply) .. Co.ones% ~ 2 Na~ i C.A.~. N~er O~ Pressure ~l~h ~lth Component [ 3 Na~ & C.A.~. N~er . ~ical 'and ~l~h ~zard C.A.S. N~r Component I [ ~ ~ C.A.~. [Check all ~% apply) Component ~ 2 Na~ & C.A.S. N~er of Preesure H~l~h H~lth Co~onen~ ~ 3 N~ & C.A.~. Nu~er :~RGEN'cY C~TACTS ~1 .Stan 'Miller ,. .Ffe!d Su~'ervisot 834-284.4 ~2 ~eI~r~ord' ~afety'Cor. ~34-Z~44 N~ Title 24 ~. Phone N~e Title 24 ~ Phone ifica~idn (~ ~ SIGN ~TER COMPLETING ~L SECTIONS) ~ify ~der p~ of 1~ %~ I ~ver ~onally ~n~ ~d ~ f~li~ w~%h the Info.aries su~itted in this ~d all attached d~en%s ~d ~at ~sed on ~ in~l~ riddle rea~le for obtai~ug the i~fo~tion, I believe that the eu~ltted info'aries is t~e, acc~ate, and c~plete. . " .... Ric~ g~!er~p[d S~.ty. Coordinator . "~ OFFICI~ TI~ OF ~OP~R OR ~OP~R'~ A~O~D ~P~M~TI~ Si~ / DA~ 8ZO~D :~; ' CITY OF BAKERSFIELD ~i%'::~'!'~;. HAZARDOUS MATERIALS INVENTORY !li?/.~,~__ Farm and Agriculture ~ Standard BusinessNON- TRADE'i SECRET Page I of_ ~:~SlNESS NAME~ Baker Sand Control OWNER NAME: B_ak..e.~r_Sa. nd Control NAME OF THIS<FACILITY:.Wareh°use A ~!?J0CATION: 5551 .. STANDARD IND. CLASS CO5E-~,-~3~9 ~ ADDRESS: ]niO.'P~_~ki~ ~d_ i~!]:'CITY,' ZIP:~=~=~=¢~=~ ~o · CITY, ZIP: H~u~t~n ~Tx 77D2g DUN AND BRADSTREET NUMBE~/FEDERAL ID :~ .................. 93313 ' :f;PHONE. #.' (flnSl flq/,-?R/,n PHONE ,#:: ~7~n~ .44_3=7p.9_0 _0 _9- 3 5 7-7 3 7 7 ~¥.:~',.: REFER TO INSTRUCTIONS FOR PROPER CODES ]! ~rans Typo MAX Average Annual Measure # Days Cont Cont Cont Use Location Where ~ by N~mes o£ MJ~cture/Cc~ponen:- ';~ Code Cods Ami Am: Amt Un/ts on SiCs Type Press Tem~ Code S~ored ~n Factltt~ .w:/ See Instructions ~: Ph~cal and ~tn Ha,a=d C.A.a. ~er 68476-'34-6 Component # I Name & C.A.S. Number~ : ' ' Component # 2 Name & C.A.-~. ~"~' of Pressure Health .... Health ; Component # 3 Name &. C.A.S. N~br~ Physics! and Health Hazard C.A.a. ,u~er 8032-32-4 Component I I Name :& C.A.S. r .- .!?(Check all that apply) x2," Component # 2 Name & C 8 er ,'.:]:]l:] ' P~:. Haz=d -"udden ~l.,s. ~eao~lvi~:y ~=ediate' ~elay~ . !~:,..! of Pressure" Health Health Component # 3 Name & C.A?8'. Number ,. Ph~s~ca~and Health ~azard C.A.80 ~u~be: Component # 1 ~a~e & C.A.8. ~un~er [~: (Check all that - : :':"L',.":' of Pressure Health Health Component # 3 Name & C.A.,~. Number P..~'~tcal:;a~ Bealth Hazard C.A.a. Number Component I i Name & C.A.8. Number · ~?. (Check 'ell tha~ apply) :!i ~/'~" ~ . Component # ~ Name & C.A.S. Number ~'~E~ Pl"'~' ~ EZ~ .udden ~.iea.. [] ~ea=tivity ~ ~=,,~late [] Oeiayed : ~ . re Hazard ,.,,;:!?...~:,.~..~,_ , , of Pressure Beal~h Health Component # 3 Name & C.A.8. Number ~.f', %~EMERGENCY~?: CONTACTS #1 , Start Miller Field S.umervisor -213A=2~J~__ #2 Rick Relerford 'Safety Cot. 83.4-'2844' ':~i?.' .... " ~'~ - -- -' - ....... ~ ............ -" ¥¢er~/fica~lon (READ AND SIGN AFTER COMPLETING ALL SECTIONS) .[.;Z. Oertify ,,,~er pea~lty of law :hat I hayer personally examined and am familiar w~th the informs:ion submitted in ?.his and all attached documents and %hat based on my inquiry of tho :~?!!:i. R-lck Relerford Safety Coordinator "., ~ .~.~lq.o/& {'.NAME'AND OFFICIAL TITLE OF OWNER/OPERATOR OR OWNER/OPERATOR'S AUThORIZeD REPRF~SENTATIVE ,qI~NA.TURE / DATE ;: ..!.:.: ,i' ! · 'M¢ ~,~:t' HAZARDOUS MATERIALS INVENTORY 1 2 ·~i Farm and Agriculture ~ Standard Business ' :',' Page of ~",~!~:!':'~ NON - TRADE SECRET ~'~'~6~INES$ NAME~ ·Baker Sand Control OWNER NA~E: Baker Sand Control NA/fE OF THIS"'FACILIT¥2 Warehouse A ~LOCATION~ 5551 Aidrin Ct. ADDRESS: '1010 Kankin Kd. . ~ STANDARD IND. CLASS COD~'.'_138~ ~:CITY, ZIP: Bakersfield, CA 93313 CITY, ZIP: ~n,~tnn. T¥ 777~R : DUN AND BRADSTREET NUMBER/FEDERAL I ~iP}{ONB #~ (,RnS) 'R_qA-O~AI~ PHONE .#: (7!3)443-7590 ~ 9 - t i I - L · L 7_ 4~77~- REFER TO INSTRUCTIONS FOR PRO CODES Trane ~e MAx Average Annual Measure ~ Days Cont Con% Con~ Use/ Location Where/ %~ Names of Mixture/C~mponen~s Code Code Am~ Am~ Amt Units on ~l~eT~ Press Temp Code /S~ored in Facilit~ See Instruc~ions 'Physloal and H~alth Hazard C.A.~. Number .8 Componmnt ~ 2 Na~e & C.A%4~'. Number [ /warehouse A = .... ~h~ical and H~alth ~azard C.A.S. ~umber Co.one & C.A.fl. ~umber .%:-~...{. F { lOo { 50 t 200 {Gal. ~ 394 ~ 13 ~ 1 ~ 4 ~ 26 ~ ~ ' ' Trap%mission Fluid . '~}~Check'all t~t apply) · / / · ~;,~ i P ] 300 .] ~0O { ~,000{' I Gal. I 365t 02l i 14 l~-~ouse A bo~ 100' W~ste~i~ '~(~'" "."" Componen~ ~ ~ N~ & C~A.S. N~er 'C~ic~iO~ (~ ~D SIGN AFTER COMPLETING ~L SECTIONS) ~?I'C~ti~y ~der p~lty o~ 1~ t~t % ~ver ~rs~ally ~in~ ~d ~ ~li~ with the in~o~ation su~itted In this ~d all attached d~t. ~d ~at ~s~d on ./,.~.~:~ ... .,...~:, ,;~. ' ,:-'."~ Rick RelerEord Sa~e~y Coordinator ~-~ CITY OF BAKERS~ I ELD ~ HAZARDOUS MATERIALS INVENTORY Farm and Agriculture ~ Standard Business .~' Page 1 of NON - TRADE SECRET ~INEs$ NAME: Baker Sand Control OWNER NAME: Baker Sa_n.d.. Control .. NAME OF THIS<FACILITY:~' Warehouse B~ 2ATION.' 5551"'Al'd.rin Ct. ADDRESS: 1010 .Rankin Rd. STANDARD IND. CLASS CODE: FY, zIP: Bakersfield, Ca: 93313 CITY,. ZIP.' Hn,,~nn. T×. 772D~ DUN AND BRADSTREET NUMBER/FEDERAL ID # )NE #: (?~) R~/,,?R/.~ PHONE .#: ~(713) ~&3-7.590 I /] S - ~ ~ 2 - 2 3 2 7 REFER TO INSTRUCTIONS FOR PROPER CODES ns Ty~e Max Average A~nual Measure ! Day~ cont Cont Con= Uae Location Where !yI Names of Mix%ute/Components e Code Ami Am~ Amt Units · on Site _Ty~e Press Temp Code Stored in Factlit~, --~5 See Instructions ~ical and ~ea~th ~a~ard C.A.S. ~er 68855-54~9 Component ~ ~ ~ '~ C.A Earth Check all that apply) · { ' = ~ ~ [~ Componen~ # 2 Name , C.A.S. ~r~ i : Fire Hazard Sudden Release R~activtty ,=edtate Delayed of Pre~eur~ H~lth H.~al%h Component ~ 3 Name & C.A.S.N.~mber ~i~al and ~eal~h Sazard C.A.S. Number . Component ~ 1 Name :& C.A.S. Number ~ :heck all ~hat apply) !N~ · [] Component~ 2 Name & C.A.B. of Pressure . Health Health Component {{ 3 Name & C.A.a. Number ~{.. P { 600 .2 { 9000 { lbs { 365 I 99 I 1 I 4 I 6 I Warehousg. ~, ,. B ~o~?!~... /Trimeth¥1~n~ ,teal and ~ealtg ~azard C.A.a. Number Component I 1 Name & C.A.S. Number :hock all that apply) of Pressure Health Health Component f 3 Name & .C.A.S. Number' ical 'and ~ealth ~azard C.A.S. Number N/A . Component # 1 Name & C.A.S. Number lheck all tho: apply) Component ~ 2 Name & C.A.S. Number ,'.'~."' of Pressure Health Health Component ~ ] Name & C.A.$. Number ~.RGENCY CONTACTS #1S~ta~.i.M~l~r:... Fi~,l~..Su~erv,~.smr 834-2844 #.,2 Rick' 'R~ie~f0r~ 'sat-et'~ c~r/'-- 834-2~44 Name Title 24 Hr. Phons/' Name---- Title 24 Hr Phone fi=a~ion · (READ AND SIGN AFTER COMP.LETING ALL SECTIONS)' { . ~ify %u%der peanlty of law that I hayer personally examined a~d am familiar with the information submitted ih this and all attached documents and that based on my inquiry of those ideals ras~onsible for obtain/ng the information. I believe that the submitted information is true, accurate, and complete. ~' Rick Re-l'erford :' . Safety Coordinator ~J ~/~ "" HAZARDOUS MA~ER IALS ~ Fa~ and Agriculture~ Standard Business ' ::' Paqe ~ .of NON - ~E SEC~T USI~SS N~ 'Baker Sand Control O~ER N~: 'Baker Sand Con ,re! N~ OF THIS"FACILITY' Outside ~arehous OCATION: 5~1 Al~w4n Ct_ ~D~SS: 1010.Kan~ln KO ~ ST~ IND. CLASS CODE~ ITY~ ZIPI g~k~l~; C~' 93313 CITY, ZIP: Nn,,~tnn: Ty.' 77~98 ': D~ ~D B~ST~ET N~BER/FEDE~ HONE ~: (805} ~3/:=28/:/: PHONE,~: (7lq) &&3-7590 ~9-- - ~7-- - ~'.' ~R ~ I~S~u~IONS ~R PROPER ~DES' r~S ~e ~ Average ~nual Measure ~ Days Cent Cent Cent Use ~cation ~ere % by/ N~s of M~ure/C~nents ode C~o ~t ~ ~t Units on ~ite ~ Press Temp. Code S~ed in Facili~ ~ flee Xnst~cttons U '[~ P t 430 , 300 I 1,~0O 'ga!. ' 365 ' 2 ' 4 [ ]'q'Outsi~a~,,~.A - __/~. h~t~al and ~lth Maza~ ~.A.8. ~.r 74-98-6 Co=pon.n~ ~ X ~ % C.~.S. N~ (Propane) (Check all that apply)~ ~ / ' ~ ~ ~ Co~onen~ ~ 2 N~ & C.A.B.N~ ~ : Of ~ressure H~lth . H~lth Componen~ ~ 3 Na~ & C.A.S. ~tcal and ~lth ~zard C.A.S. Nu~er ~ i N~ :& C.A.S. ~er (Check all :~= apply) {~..,~ · . . ,: 6f Pressu~ q. N~lth H~lth Co~onen~ ~ 3 N~ & C.A.S. N~er t~tcal~and ~lth.~za~ C.A.S. N~er ;' Co~onen~ ~ 1 N~ & C.A.S. N~er .(Check all %~t apply) . : -- '" Co~onent ~ 2 Na~ & C.A.S. of Pressure ~lth ~lth Co~onent ~ 3 Na~ & C.A.S. N~er ~ical~ ~lt~ ~za~ C.A.S. ~er Co~cnent ~ 1 N~ ~ C.A.S. N~er (Check all t~t ' · · Component ~ 2 N~ & C.A.~. .~:..:.,, .,.? .%q%. of Presaurm H~lth H~l%h, Co~onent ~ 3 ~ & C.A.S. N~er ~RGENCY C~TACTS Sl Stau Miller' Field Sup~'~v~sorB3d_yBd~ S2 ~iCk Eelerr.ord Safety der. ..: .. %~ ."- ...... ~% ...... 24 ~. Phone N~o TitlJ "' '- 24 ~ Phone :.~:: k{ck Relerford Safety Coordinator ' . " ~ficatioa (~ ~D SIGN AFTER COMPLETING ~L SECTIONS) ,~fy ~der p~nl~ of 1~ ~= I ~ver ~onally ~ln~ ~d ~ f~li~ with the info~ation su~itted in this ~d all attached d~en=s ~d ~a% ~sed .riddle res~le for ob~i~ng the info~ion. I believe ~ha= ~e su~tted info~a%ion is %~e, ac( ~e, and CITY OF BAKERSFIELD HAZARDOUS MATERIALS INVENTORY -] Farm and Agriculture ~ Standard Business ' ,~' ~ [ Page 2 of NON - TRADE SECRET ' , IU$INESS NAMe.' Baker Sand Control OWNER NAME: Baker Sand Cent ol. NA/~E OF THIS'FACILITY,Warehouse C ,OCATION.' 5551 Aldrin Ct. ADDRESS: 1010 Rankin Rd. I ~ STANDARD IND. CLASS cob-E.' 1-~-~-~ !ITY, ZIP.' Bakersfield~ Ca; ~1~ CITY, ZIP: Hm.~nn. T×. 772~8 ~ DUN AND BRADSTREET NUMBER/FEDERAL ID HONE #: (~DS) ~q4-?~/,/, PHONE,#: '(713) 443-7590 I /] ~ - ~ .5 2 - 2 3 2 7 REFER TO INSTRUCTIONS FOR .~:an. Type Max Average Annual Measure ! Days Cent Cent Cent Use / Lo?ation Where ~ % by. Names of Mlxture/Componsn~s :ode Code Amt ~ Am% Units ~s Tern Code Sto~ed in .Faci~it~ / w~ See Instructions U arehg, us~.e- C _ _ ~ 100 Soda ,h~ica! and S~l=h Hazard C.A.S. ,~er 497--19--~ . ~%~o~ponen~ ,~S. ~er / (Check all that apply) · ~ . ~ / -- Componen~ J.-T-Name & C.A.~ Numbe~ ~ : U ,[ °P 110,00016,000 [40,000 [ Lbs. [ 365 I 12 [ 1 ' [ 4 [ ]1l Wareh°Ese C Nn~%%_ / 90 .. _0/Hydre×ycthy! Ceil'alcan 'by, ica1 and S~alth Hazard C.A.S. Nu~er 9004-62-0 ~ componen~ ~ i Name &~.~. N?mber_ ·(ChecR all tha: apply)~ / ...... ~ Fire Hazard ~] Sudden 'R~lease [] Reactivity ~ Immedia:e [] Delayed ~'z . of Pressure Health H~alth / - O I m [ ZOO [ 150 I 50 I Gal. 1365 [06 I1 I 4 1111~a-c~.houle G ~o,,~-~¢~ WC350/Union Carbide ~10 hysical'and Health Hazard C.A.S. No=bet N/A N mine/Glycol Mixture ~ (Check all that apply) . V, ,,-..:, ! 'hysical 'and Health Hazard C.A.S. Nu~er Co~ponen,~ ~ ~ Na~ & C.A.S. N~er 15 Zlrrconium 0xychlortde 7699- - (Check all that apply) / "' Componen~ # 2 Name & C.A.S. Number ID Ha.ard ud .n ,el.a.e [] Reactivity · . of Pressure Health Health Componen~ # 3 Name & C.A.S. Number .E~ERGENCY CONTACTS #1.qt~n M4]]~ · V~H. 9,,~v4~r 834-284~ I #2 R4ak R~]~fnrd Safe¥ Got_ '_ ~34-2~44 ?:: Name Title ' 24 Hr. Phone Name Title 24 ~r Phone ~.l~ica~ion . (READ AND SIGN AFTER COMPLETING ALL SECTIONS) certify under peanl~, of law ~ha= I hayer personally examined and am familiar w~th the information subm~tt~ in th~s and all attached documents and that based on my i~qu~ry of those ~dl¥iduals responsible for obtaining the information. ! believe that the submitted informs%ion iA %rue, al:curate, and complete. "~ ..... Rick Reler_fo~d._ Safe~y Coordinator ~ ~~ %M]~'ARD OFFICIAL TITL~ OF OWNER/OPERA~OR OR OWNER/OP~TOR'S AUTHORIZED KEPP, EMENT3%TIVE SIG~NATURE / DATE BI=NED !i~:~. . . HAZARDOUS MATERIALS INVENTORY ~ Farm and Agriculture~ Standard Business '" S ~R~~ Page 4 of :~,.~k'": ' TRADE EC " iSiS?.' NON - Sand T BUSINESS NAME: Baker Sand Control OWNER NAMe: Baker Control NAME OP THIS'"FAClLITY._~_~C~_~%gu$£ "~ .... · . STANDARD IND. CLASS'cOD~E': 1~$~ <.,LOCATION. 5551 Aldrin Ct. ADDRESS: '1010_Rankinl Rd · :.~iTY, ZIP: Bakersfield. CA 933]3 CITY, ZIP: ~n,~nn: TYI 777~R : DU~N A-ND BR. ADSTREET NUMBER/FEDERAL (R~q~ R~/~_~8~ PHONE ,#:' ~7]'l:~/,~-7~Qh ~?'~.:. REFER TO INS~RUCTIONS FOR P Trane Type M~ Average Annual Measure ! Days Cont Cont Cont Use /I Location Where ~ % by N o~ Mixture/Components ". ~ 8 ~ 1.000~ 300 ~ 6,000[ Gal. [ 363 ~ [ 1 ~ & ~ 1~ Warehouse C ~~= W-3~l/Hydroaholi: A:id~ ~h~lcal and ~lth Hazard C.A.S. N~er N~ : '~ ~:. (Check all %ha~ apply) ~ '~??: Of Preasure ~lth H~lth Component ~ 3 Na~ & C.A.S. N~er ..:,~>' ~h~al and ~lth ~zard C.A.~. N~er Co orient ~ I N~ & C.A.B. N~er ~(Che~k all t~ apply) ~ ..... ~:,-. . . . Co onont J 2 N~ & C.A.8. N~er ~j~:~ .. ,: H~lth ~lth Co onent ~ 3 N~ '& C.A.S. N~ '~h~' H~l%h.~za~ C.A.S. N~er Corn onent I i N~ & C.A.8. N~er ~:~I... . Co onent ~?,:" o~ ~reseure H~lth H~lth ComPonent ~ 3 N~ & C.A.S. N~ . Component ~ 2 N~ & C.A.S, N~er ~:{~:~,,~. ,. :.../, . o~ Pressure ~lth H~lth -Co onent I 3 N~ A C.A.S. N~ .;:.~}~,.'~ <"<'..:.; ' '~ ',:~. .. ~. ,.. ~. '~ic~tion (~ ~D SIGN AFTER COMPLETING ~L SECTIONS) . :'I'c~i{y ~der p~ty o~ 1~ ~ I ~ver ~r~ally ~in~ ~d ~ ~li~ with the lnfo~tlon su~litted '.,.:.i~ivid~ls r~s~le for ob~i~ug the info~tion. I believe that ~e su~ltted info~ation is t~e, acc=ate, and c~plete. '' ~C [:: I ~:~;' ' Rick Relerford Safety Coordinator ~[~i~..~ CITY OF Bi~I(E RS F I ELD · :~.~ Fa~ and Agriculture ~ Standard Business ' :F Page 2 of', ~ ..'. ~"~.' NON - ~E SEC~T . ~;BUSI~SS N~ Baker Sand Control O~ER N~: Baker Sand Control N~ OF THIS"'F~CILIT~ Warehouse B '~OCATI'ON~ ' 5551 Aldrin Ct. ~D~SS: 1010 Rankin Rd. ~ ST~ IND. C~SS'C~i ;~CiTY, ZIP~ ~~ ~35~ CITY, ZIP: Un,mtnn: TX 77?aR : D~ ~D B~ST~ET ~BER/FEDE~ I ~;~::~,~. ~R ~ In~U~IONS ~R PROPER ~DES ~:..1 · 2' 3 4 5 6 7 8 9 l0 11 12 13' Tr~s ~e ~ Average ~nual Measure ~ Days Cent Cent Cent Use Locstion ~ere % ~ N~s of M~ure/C~nen~s Code C~e ~t ~ ~% Units on Site ~ Press Tem~ Code S~red iff Faclllt~ ~ 8es Inst~c:lons · 'A ~ P I 600 I '2 I 9.000 I lbs. I 365 I 99 ~ 1 I 4 [6. [ warehouse B ~. H~x¢lotetramethyle,-- ~: . . , '~h~&e~l ~nd ~l~h ~az,rd C.A.8. ~er Compon~n~ W 1 N~ ~ C.A.8. N~ - Component ~ 2 ~ & C.A.8. N~er ~,, ~:~;~. Fire ~az~d ~ Sudden ~lease ~ R~cttvity .~ I~ta~e ~ Delay~ ~:~,~%}':~{.~A "1. P I 600 1-:~2 I 9,000 {' lbs I 365 99 I 1 I 4 16 I Warehouse' B $ou~- YX/Dfnltropyridine }h~ioal and g~l%h ~zard C.A.8. N~or N/A Co~onmn% I 1 N~:& C.A.8. ~+~. · ~ . .. Co~onon[ I 2 ~ & C.A.B. '~?R'"I ..M I 600 [ '.2 I'~ --i ihs. "l .365 1 99 I' 1 I 4 1,6 I War'ehouse B ~,, Primaa,;et '~h~la~ ~nd H~l~h ~ C.A.a. N~er Component ~ 1 ~ & C,A,8,' N~er Componsn% I 3 N~ & C.A,~. ~ &~(Check"all;..t~t apply) ~' Component ~ 2 N~ & C,A,8. N~er · '.?i~::'%~ ~..~::.i';~. ? {.:~fication (~ ~D SIGN AFTER CO~ETING ~L SECTIONS) :::'%'C~ti~y ~der p~nlty o~ 1~ t~t Z ~ver ~r~ally ~in~ ~d ~ ~11~ with the info~tion su~it~ed in this ~d all attached d~ta ':~ivid~ls r~e~le for ob~i~n~ :he ~nfo~tion. I believe that ~O gu~ltted info~ation is t~e, acc~a%e, and c~plete. :?[~[::"~.. Rick Relerford Safety Coordinator '~.~'?":.:~ HAZARDOUS MATERIALS INVENTORY ..~ .Farm and Agriculture ~ Standard Business ' :: Page 1 of~ {~(~'::":' NON - TRADE SECRET ~:BUSINESS NAME: Baker Sand Control OWNER NAMe: Baker Sand Control NAP[E OF THIS"'FACILITY..~Warehouse C '~i~OCATI'ON: 5551 Aldrin Ct. ADDRESS: '1010 Rankin Rd. . , STANDARD IND. CLASs'dOD~'~ 1389 i~!~iTY, ZIP: Bakersfield. CA 93313 CITY, ZIP: ~o,,~rnn: T~ 77~O~ . ~;~HONE.. #: <RO5) 83~_~0/,~ PHONE ,#: : (713)/,'43_7590 .- O ~ - t i L - L ~ L L ,,~;~..:~::,~ REFER TO I TRUCTIONS FOR PROPER CODES Trane %'ype )~ax Average ~nnual Measure ! Dsy~ Cont Cont Cont Uae Location ~here % by Names of Mixture/Co~ponen!:s Code Code ~mt ~ Amt Untt~ on Site .,T~pe, Prees Tem? Code S~ored '"D~ I 0 I 0 I 0 { 0 .,1 0 I 0 I [ 0 I 0 lO [ Warehouse C Bridgesal '~hy~lcal and H~alth Hazard C.A.8. Number , Component t i Name '& C.A. : '~:: (Check all that apply) · ~a ,' ~lt'h.~za~ C.A.S. N~er Component ~ ~ N~ ~ C.A.B. N~er ~}"*' ' Co.orient t 2 N~ & C.A.S. N~ ?,:~' o~ PresBure ~lth H~lth Component ~ ] ~(Check all t~t apply) ~ .~..~. ,. Component ~ 2 N~ & C.A.8. N~er ':Vt*.{' ,. , og Pressure H~lth H~lth Co~onent ~ 3 N~ & C.A.~. N~ (~ ~D SI~N ~FTER COMPLETING ~L SECTIONS) '~-'Z*c~tity ~der p~nlty et 1~ t~t I ~ver ~r~lly ~'in~ ~d ~ tmll~ with the info~atton 8u~ttted tn thi~ .f~<~i:~ HAZARDOUS MATERIALS INVEN"PORY Farm and Agriculture ~ Standard Business ' :: Page 3 of 4 ~"~:." NON - TRADE SECRET .:~:?::'.-'.'~.. .~x~'BUSINESS NAME: Baker Sand Control OWNER NA/~E: Baker Sand Control NAME OF THIS"'FACILITY: Warehouse C :~LOCATION: 5551 Aldrin Ct. ADDRESS: 1010 Rankin Rd. , STANDARD IND. CLASS COD~E'~ 1389 i~]:CITY, ZIP: Bakersfield. CA 93313 CITY, ZIP: Mmm~n: TM 777(]R : DUN AND BRADSTREET NUMBER/FEDERAL ID !~:PHONE #: (R~) R~A-?~AA PHONE,#:' (7!3)4A3-7590 ~ 9 - 3 i 7_ - REFER TO INSTRUCTIONS FOR CODES' Tra~s Type Ma~ Average Annual Measure ~ Days Cent Cent Cent Use / Loca:ion Where ~ ,B/61 Names of Coda Code Amt Am~ Amt Units on Slta ~ Prass Tem~ Coda ! S~ored in Facility / w~ See Instr~¢tions · U I P I~,000 I 5.000 I~0,000 I l~s I 365 I I ~ I 4 I 1~1 W~rehouse C ~o~:~/ 99Z - 0/^m~onium ChZor±de ~h~loal and ~th aa~ard C.A..". M~ar 12125-02-9 :~[;i~'.l ~ I 8nn I 4nn I ~,.~nn I ~s. I ~ 1~ I1 I ~ I 11l 100 W~22/s,,l~ Ac~d ~D,:: ¢..; .. Ph~ical and H~lth ~zard C.A.S. N~er 5329-14-6 ~'~:~;: "" '~t.'l P I~s,ooo 8,000 I~oo,ooo ~b~. I ~6S 1~2 I '~ I 4 I~ I u house C ,~.~ 95 B-~O Por,ss~um Chloride ~h~toah"and ~l%h.~za~ C.A.a. N~er 7447--40--7 Co N~.r ::'~:.,' I P I ~,0001 :,oool :o,oool" ::~. I 36: I :: I: I ~ 1:: I ~:~:~ c ,~~/ ~ So,~um ~:~"~"~:~ '. ...,'. ," .,, . ' Compon.nt ~ 2 N~ ~ C.A.S. N~ / ,.~.~..,,... :.~. ,,.... , of Pressure H~lth H~lth Co~onont ~ 3 N~ & C.A.S. N~ ~%:'~'E~RGENCY'C~TACTS ~1 'Stun M41ler F~la ~,,n~,~o~ ~2 Rick Pelerford _c~"W~hl6 ~ Cor_ . '~? .[~: .... .: ". N~ Title 24 ~. Phone :.;C~1cation ' (~ ~D SION AFTER COHPL~TING ~L SECTIONS) ::'X'c~t{y ~der p~n~y of ~ t~ ~ ~var ~raonalXy ~n~ ~d ~ ~1~ with the tnfo~atton au~it~ed in ~hi* ~d all attached d~ta ~d ~at ~aed on ~ in~t~ o~ ~o, .~ivid~Xs r~e {or obeying the in~o~lon. X believe ~ ~e ,u~i~ed info~ation ia t~e~ icc~te~ ~n~c~plete. [~':':? Rick Relerford Safety Coordinator CITY of BAKERSFIELD Farm and Agriculture [~ Standard Business I~].HAZARDOUS MATERIALS TNVENTORY NON--TRADE SECRETS Paqe __.ET( .... 0f~_~_ BUSINESS NAME: ~)J~CV' ~r~",u[ 0~0 ~ OWNER NAME: ~=~ ~-~ ~/~( ~9~T~ F~p~T~2_~.~ C~_%_[___~S~ LOCATION; ~/ ~1~ ~- ADDRESS.; ~O ~k~ ~._ ~~UB~T~bNbR~ ........ ,~ ...... CITY. ZIP: ~mzS~ ~a. q3313 CITY. ZIP: ~~ ~ ~vOe3 PHONE "' -' '~ -- ~ ~ 3~- 9A 29 . I 2 3 4 . 5 6 7 8 9 I0 11 12 13 14 Trans lYre Hax Av~rpge Annual Heasure I gy~ Cont Cont Cont Us~ Location. WheEe ?Yc ~ames of uixture/Cc~o~encs Code coae Amt Amc Est Units on 5ace Type Press Tamp CoueStored tn Pacl/]ty See Instructions Physical~Che:k allandthatUea]thapply)Hazard .: C.X.S. ,umber ///-~g-2._. .... Component I~ Hame ~ C.A.S. Humber ' O0~ Component 12 Name ~ C.X,S, Humber [~Fire Hazard ~Reactivity, ~Detayed U Sudden Release J~.Immediate Hearth of Pressure Health , Component 13 Name & C.A.S. Number Physical IpdHealChHazard C,A.S, Humber Component II Name & C,A,S. Number (Check 8/1 that app]y) Component 12 Name I C.A.S. Number ~ Fire Hazard ~ Reactivity ~ Delayed ~ Sudden Release ~ Immediate' Health of Pressure Health Component 13 Name & C,A,S, Humber Physical and Health Hazard C,A,S. Hu~ber Component I1 Hame & C,A.S, Humber (Check all that apply) Component 12 Hame & C,A,S, Number ~ Fire Hazard ~ Reactivity ~ Delayed ~ Sudden Release ~ Immediate Health of Pressure Health Component 13 Hame A C,A,S. Number Physica'l 8hd Health Hazard C.A,S. Humber Component tl Name I C.A.S, Number (Check 8/1 that apply) Component 12 Hame & C,A.S. Number ~ Fire Hazard ~ Reactivity ~ Delayed ~ SuddenRelease ~ Immediate Health of Pressure Health Component 13 Name I C.A.S. Humber EHERGENCY CONTACTS ¢l~q~~/, ~O~TTCle ~5~ ~~e~~ fl2R~~ erti[igatioq ,(Re/lid an.d.~fgn a?tqf~r cornpl~Ci(]g,a11 secCi.ons.) ' cern)fy.unDer penafcZ p/)a~ thqc Jflavepersona/py examlnqO~qoQm rami)iar.yitb the )n[ormac)pn ~u~mitted in this 8nd all .aC~acned,oocvmenc~, an~nac oaseo on. my ~nquiry Qf. those inDiviDuals responsio(e Tor obtaining cna ~ntormatlon, I believe that t~ . sUe~ltteoj~lor~atlo~j) true, 8ccurBte, 8no complete, .~ ~ .. CITY of BAKERSFIELD : . .. HAZARDOUS MATERIALS INVENTORY ¢armandA¢iculture ri StandardBusiness Iii NON--TRADE SECRETS BUSlNESHS NAME:~:~'<-~-/",.~,g (~O~"~ro~. OWNER NAME: ~ ,%~ ~rO[ ~NAM F THIS FAClLIIY' ~', LOCAIIO ; ~5~ ~a~' ~. ADDRESS: /5lQ ~~ ~. ST ~D~RD ND. CLA S COD · 1'~ Q~.[~. ~IP': ~F~S'~ ~. ~J% ClTY. ZIPi, ~o, ~X ~oO~ ' DU~ AND B~ADSJRE~ E~~ ~ ~ - 1 2 3 4 . 5 6 I 8 9 I0. II 12 ' t~y ~4~es of Trees [yqe ~ax Av~r~De Annual ~easure I~[[e Cent Cent Cent ~e Location?ace Code coae Ami Amc Est UniCa off lype Press Iemo Stored In FaCiliTy See Instructions " D I-PI~ I~ I c: I~1 o I~ I~ I~ '1ol 0 ..... ~o~.,.~_,~+..+~ '- physicaland Health Hazard i C.A.S. Number Component ,I Name, C.A.S. Humber ~/ ~ Fire Hazard ~ Reactivity :~ ~ Delayed ~ Sudden Release ~ lmmedia[e CompoflenL 12 Name I C.A:S..Nupber ,. : .. ,~ Heal[h of Pressure He41[h Component I1 Name I.C.l.$...Number ~ - PhYsical led ~eal:h ~azard i. C,l.S. Number'. Componen: fl Name t C.A,S, Number .. ~.ch,c~ ,. ~h. ,.,~]: ? ., .. .- ~ o~ ~ Fire ~4zard , ~ Reactivity ~ Oelayed ~ Sudden Release 'U ]m~i~'c°'p°nenL 12 Name & C.A,S, Number . PI~ -~. ·-" " Health of Pressure " ' .... .. - .:, · .... }~ ' Componen~ 13 Name I C.A,S. Number '..' Physical'led Pellth'Galard .. .,... C.l.S.'Humber :'.Compon~flt:ll '.. Name.,& C,A~S;/NUmber.-':? ~:'.'. (Check. 8].l. Lha&'appfy/ ' .. ' ' "' -- '-':':.':' :: ' . :'?¢~0~'~[':": ' ': , _.:. :- .?..I . ':" :':: -:':": "' ' .... -Component 12,Namel'~,A,S,':N~mber,:: . . _ . . - -: ''r : -- . :,. ': :' * ', ~ : .. : . Health .....of Pressure Componen[ 13 N~me I C.A,$.'Number :' Physica'l a~d Health ~izard C.A.S. Number Component I1 Name I C.A.S. Number (Check all that app/yl ,, ,,~~ D Fire Hazard ~ Reactivity ~ Oelayed ~ Sudden Release ~ lm~i~ Componen~ 12 Name & C.A.a. Number ~J~- Heaffh of Pressure ; ComponenC 13 Name I C.A.a. Number erti[i~ati0q .(Re~ an~.~ign af¢~r compl~ti~?g.oll secti~n~) ' .cer~lt.y.unoer penal[l ol~aW thqc I nave personallL examlnqOeqo lm tamillar.~Jtb the j nlormaclon Su~mittpd in this.ted all .a~a~ne~CV~enC..~n~~~ase~n~my.nquiry~r~cn~se.n~.~.~ua~sresp~nsiD~e~r~bCa.ni~gLh~.~r~r'ac.~be~.e~e~s~.LLe~ ,~ormac,on.~,,% ,s~rue,~c~L~accuraTe, and complete.. . hJ~~ ,,. , .. BHAZAR_. DOUS HATERZALS- :ENVENTORY Farm and Agticult, ure [-I Standard Business NON--TRADE SECRETS. ,uSZ,ESS ,A.E: ~L,¢¢ .~ 0~-~o[ ~s~"E: ~~-&"~ 0~5~ '~:gL~U~ LOCATION: ,~.~ ~i~¢X~ ~, : '/~IQ ~1~ ¢~. ~u~u %~u. UL~b uuob: lrans Code ~ooe Ami AmC EsL Unlis on lype Press lemp CoueSLoreo In PaciiIcy See [nsCrucLIons t3'"l.o i'o Io I o Iol o IOlOlolo I' o 'Ox¢s~t ,/ '- Physical and Health Hazard . ~ C,A,S, Number ComponenL II Name I C,A,S, Number ComponenL t2 Na,e I C.A.5. Number ~ Fire Hazard ~ Reactivity;i ~ Delayed ~ Sudden Release ~ ' Health of Pressure 'i · Component 13 Ha~e I C.A.S. Number Physical and Health Pazard i, C.A.S. Number' Componen~ II Name I C.A.S. Number.~}~ ~_~ .... Co~po~e~t f~ Name I C.I.S. Number : ~ ~ire ,azard . ~ ~eactivity ~ Delayed ~ Sudden Release 'B lmme~.~e. .. .. ,ealth of Pressure,ealt~ .... . .... · ':" ':' ' Component 13 Name I C.A,S, Number " Phvsica,,check.all. the,and Health 'Hazard'apply, . - '--. C.A.S. ..Number' , "C0'P0n'"~' I~.: ,a,, '' C,A~ S :"~0'b,¢:',4 '' ''. . , "':"" '""'? :: ;:; ' :. "~ '~,0:~. :"': .... Hazard, . . .' :':"U RelcLivitl:''.... .:'U O, layedNealth U Sudden..ofPressureRelease U'~%~" .-Component,:.. ..'. %'~' * * ~ ':""' ' '~0 -- ']m "¢¢~ ll:Namel~;A,S,'Number': .' "- :'i. ';.-' ,".: ~'~ire , . Component 13 Name I C,A.5. Number,'. . Phfsicl'liC~ck aill~dt~atH"lthl¢¢/ll~il~rd C,A,S,. ~umber Component II I~lt I i,l,S, Number ~___~¢~, . Health 0f Pressure Health Component 13 Name I C,A,S, Number REde ~ zq Mr Phone erti[j~atioq ' .(Refd an~.~ign aT,pr compl~ti(tg.all.~ctifn~) ' .cer[~tf.unoer ~ena~[~ o~a~ th~c I nave personally, exa~in~otqo ~ tami~tar. ~i[O [ne jntor~aHpn ~uU~itteU in this.tnd all .,,,,,., .,0,,.,,,, ,,, .,. o,.,, ,,,,,,, ,,.,,os, ,,,,,,,.,, ,,s,on,,,,, ,or o,,,,,,,, ,,, ,,,or.,,o,., ,,,,,. i ,, ,.' ,. ~--~. ....... CITY of'BAKERSFZELD ,. ~. ~.. '~-- --~.....- HATERiALS INVENTORY...' . . . . ..,.. .. Farm and Agriculture 'lq Standard Business ElHAZARDOUS "" NON--TRADE SE.CRETS LOCATION; 5.~ / ~l~r~ e+. ADDRESS: I0~0 ~~ ~, O R [--~ ~ ........ - ' ' R~ TO~R~T~T~ 'kU~ PROPER CODES 1 2 3 4 5 6 I 8 9 10 11 12 Trans Names of Pixtljre/C:~ooeents Code ~ooe ~et ABC ESL Un l ts on /ype Press Tamp Co~e See [nstruct~ons S~ored Iff FaCility Physical and Health ~u~rd ~ C,~.S. ~uaber Co~onenL II ~a~e t C,~,S, ~u~r (Check all tha~ U Fire Hazard D Reactivity,; U 0cloyed ~ Sudden Release U l,~pd)~ ' Health of Pressure .,ea~n '~ '; 'Component 13 Name t C,A.S,.Number Physical Iod Health Hazard i' C.A.a. Number ~. Component I1 Name I C.A,S; Number. .... (.Check all that_applyJ ~; .... :..:. ~ Fire Hazard ~ Reactivity- ~ OelayedHealth ~ Suddenof PressureRelease .~ ]m~i~.Component 12 Name~ I C.A.SL Number - . ;, ' Component 13 Name I C,A,a, Number · ' ' D Fire Hazard:.":.g Reactivity:'; g Delayed U Sudden Release U le~i¢~ .- · '.:-- .. :'=..-...:.-.'? '... ': .':.....: :- - . ' ': ' ". ....... · Health - ;of Pressure . · '. D I 0'1 o-.I o I o, Io I o '1 o I' 'ol o I o I "¢' " Physica'l(check allaadthatHealthapplH"izard C,A,S,. Nu,ber Component" Name& C,A,S, Number Component 12 Na~e I C,A;S, Number U Fire Hazard U Reactivity U Oelayed U Sudden Release U Hem ffh of PressureHeal:h. Componen[ 13 Hame & C,A,S. Humber EHERGENCY CONTACTS fllRae~a__ fer:ia:ioq ' ,(Re~ an~.~fgn after cOmplgtf~]g,aZ? securing) ' .cerHty,unoer pena~[~ ol~a~ thqt ~'nave~ersona~y exaeln~lqole tami~ar.lit~ the ~nlor~aHpn Su~eitt~ tn this,end all q~e~.suoml t teda t~acneo .oOcvment~, o r~~une r ~ nror m~nanQIs t~attrue,Oaseo~fl, my/~t~k~o~ne~~r ~Dr ese nTa [~ ~c~ ate, ~no~nqui rYcomp/ece, Qf. Those inDiviDuals respons i Die for obca~ ni ng the ~ ntor mat] on. I. bel ~ eve that~the ~~~_ Oat e~1~es] ~ -//~ --' 03106/91 SAND CONTROL 215-000-(~759 Page 1 Ove~all Site with 1 Fac. Ur~it Get;et-al Ir, fot~rnat ior, ILocatior~: 5551 ALDRIN CT Map: 12S Haza~-d: Mode~--ate Ident Number: 215-000-Cx}0759 G~id: 15D A~ea of Vul: 0.0 Contact Name ....... ~ Title ~ .... Business Phc, ne ~ 24 Hc, u~~ Phone] CRAIG PARKER DISTRICT MANAGER I (805)'~ ~bx /(8.o) ~dn~ir, ist~ative Data ~ail ~dd~-s: 5551 ~LDRIN CT D~B Numbe~: 09-S57-'ZS7) City: B~ERSFIELD State: C~ Zip: 9SSiS- Comn~ Code: ~15-01~ B~ERSFIELD STATION 1S SIC Cc, de: ~SB9 ~dd~ess: 1010 ~N~IN ~D State: City: HOUSTON Zip: 7707S- 03/06/91 BAKER SAND CONTROL 215-000-000759 Page 2 Hazr~at Ir~ver~tory List irl MCP Order 02 - Fixed Cor~tair~ers ors Site Pln-Ref Nar~e/Hazards Forr~ Quar~t ity MCP 02-006 AMMONIUM NITRATE'~ ~ ~ ~ ~.k~ ? 4,000LBS Extrer~e 02-016 2-315/Z I RCONIUM 0 X Y~H~O R~i~ Liquid 150 High I~,~,~ed Hi th ~~~ GAL 02-033 ACETYLENE Gas 400 Hi gh Fire, Pressure, Ir~r~ed Hlt~, Delay Hlth FT3 02-013 FORMIC ACID ? 15 High GAL 02-017 HYDROCHLORIC ACID Liquid 1~000 High Reactive, Ir,~r~ed Hlth GAL 02-027 LIQUEFIED PETROLEUM GAS (PROPANE) Gas 430 High Fire, Pressure, Im~ed Hlth GAL 02-007 SODIUM HYPOCHLORITE 0 115 High GAL 02-025 A-iOO/CRONOX 265/ISOPROPANOL .o 55 Moderate GAL 02-018 B I OC I DE/GLUTARALDEHYDE ? 55 Moderate GAL 02-015 DEFOAMER/POTASS I UM HYDROXIDE ? 55 Moderate GAL 02-023 MAGNA Al l4/AROMATIC PETRO SOLVENT ? 55 Moderate GAL 02-024 MAGNA A117/I SOPROPANOL~ ~]~ ? 55GAL Moderate 02-021 NALCO ASP 162/PHOSPHATED ALCOHOL ~ ? 44(:) Moderate 02-039 SOLVENT/683 Liquid 200 Moderate Fire, Imr~ed Hlth, Delay Hlth GAL 02-008 AMMONIUM CHLORIDE Sol id 5,000 Low I ~ed H 1 t h LBS Fire, I~ed Hlth, Delay HlthV~-\\ ~'/ GAL 03/06/91 SAND CONTROL ~-' 15-000-0 59 Page Haz~at Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Na~e/Hazards For~ Quant ity MCP 02-030 HYDRAULIC OIL Liquid 100 Low Fire, I~ed Hlth, Delay Hlth GAL 02-026 KEROSENE ~ 55 Low GAL . ~ .) Low LBS 02-022 NALCO ASP 168/KEROSENE ~ ? 165 Low 02-014 NALCO ASP-~00/SOD~UM HYDROXIDE ? 55 Low 02-032 OXYGEN Gas 900 Low Pressure, Im~ed Hlth GAL 02-011 SODIUM HYDROXIDE, FLAKE ? 100 Low LBS 02-031 TRANSMISSION FLUID Liquid 100 Low Fire, Im~ed Hlth, Delay Hlth GAL 02-028 WASTE OIL (NA 9189) Liquid 300 Low Fire, I~ed Hlth~ Delay Hlth GAL O~-q o4 DIATOMACEOUS EARTH Sol id 75,000 Minir~al I~ed Hlth, Delay Hlth ~ LBS 02-029 MOTOR OIL Liquid 300 Mini~a 1 Fire~ I~ed Hlth, Delay Hlth GAL 02-037 POTASSIUM CHLORIDE Sol id 15,000 Mini~al I ~ed H 1 t h LBS 02-035 SILICA SAND Solid 1,400,000 Mini~al I~ed Hlth, Delay Hlth LBS 02-038 SODIUM CHLORIDE Solid 5,000 Mini~al I ~ed Hlth LBS 02-009 SULFAMIC ACID Sol id 800 Mir~i~al I ~ed H 1 t h LBS 02-040 SODA ASH Sol id 3,000 Unrated I ~ed H 1 t h LBS 02-004 BORAX ? 75 Unrated LBS 03/06/91 BAKER SAND CONTROL 215-000-000759 Page 4 Hazrllat IrJver~tory List irs MCP Order 02 - Fixed Containers on Site P 1 r~-Ref Name/Hazards F,:,rm Quant ity MCP 02-019 DOWFAX 2AO/MONO & DIDODEC~~ATED ? 330 Ur, rated GAL ' 02-003 ~YDROXYETHYL CELLULOSE Solid 10,000 Unrated LBS 02-002 MAGNES I UM OX I DE ~ ~z-~, - LBS 02-o20. ~ UNION CAR~IDE~ ~ ' UCAR 310/AMINE/GLYCOL Liquid 200 Ur~rated Im~ed H 1 t h GAL 03/06/91 SAND CONTROL 215-000-0~ 29 Page 5 0o - Overall Site <D> Not if. /Evacuatior~/Medical <1> Agency Notification CALL 911 <2) Er~ployee Notif./Evacuation ALL EMPLOYEES KNOW AND ARE AWARE OF SITE EVACUATION PROCEDURES AND THE PRQPER NOTIFICATION PRQCEDURES IF THERE IS A HAZARDOUS RELEASE. THE FIRST STEP IS TO CALL 911 AND TO GIVE '[HEM ALL INFORMATION ABOUT '[HE RELEASE. CALL THE COMPANY RESPONSE TEAM AND TO CALL THE OFFICES OF EMERGENCY SERVICES WHEN AN EMERGENCY SITUATION PRESENTS ITSELF ALL EMPLOYEES WILL ASSEMBLE AT ]'HE COFFEE BREAK AREA WHICH IS IN FRONT OF ]'HE MECHANIC SHOP IN THE MAIN WAREHOUSE. SAFETY OFFICERS AND EMERGENCY RESPONSE TEAM WILL BE NOTIFIED. A PLAN OF ACTION WILL BE IMPLEMENTED. <3> Public Notif. /EvacuatiorJ TO '[HE NORTH, WEST AND SOUTH OF OUR ESTABLISHMENT '[HE BUSINESSES STAY UNDER ]'HE SAME NAME, HOWEVER, 'TO ]'HE EAST AND SOUTHWEST, THE BUSINESSES HAVE CHANGED DURING TIME. I HAVE INFORMED CRAIG PARKER AND SEVERAL OTHER KEY PEOPLE AS TO THE NEED OF A PUBLIC EVACUATION PLAN. WE PLAN TO VERBALLY, IN PERSON, NOTIFY OUR NEIGHBORS IN '[HE CASE OF A THREATENING HAZARDOUS MATERIALS RELEASE. ADJACENT COMPANIES AROUND OUR FACILITY WILL BE NOTIFIED BY WORD OF MOUTH AND BY PHONE IF POSSIBLE. AT THIS TIME THE PROPER AUTHORITIES WILL ALSO BE NOTIFIED. <4> Emergency Medical Plan WE HAVE EYE WASH, SHOWER AND SMALL MEDICAL KIT ON HAND. VALLEY MEDICAL CENTER - 5700 STOCKDALE HIGHWAY - 324-4014 MEMORIAL HOSPITAL - 420 34TH STREET - 327-1792 03/06/91 BAKER SAND CONTROL 215-000-000759 Page 6 O0 - Overal 1 Site <E> Mit igat ior~/Prever~t/Abatemt <1> Release Prever, tion WE HANDLE ONLY SMALL AMONTS OF HAZARDOUS MATERIALS. USUALLY EITHER DRY IN 55 POUND SACKS OR LIQUID IN 55 GALLON DRUMS. WE HANDLE CHEMICALS CAREFULLY WITH THE PROPER EQUIPMENT. WE CAN HANDLE SMALL CLEAN UPS OF RELEASES WITH THE EQUIPMENT WE HAVE ON HAND. C,_,r, tain~ent <2> Release ~- WE HAVE ASPHALT BERMS SEPARATING CHEMICALS. ALSO A CHEMICAL HANDLING AREA WHICH IS BERMED WITH A NON LEACHING SUMP. <3> Clean Up EVERYONE AT FACILITY IS TRAINED. WE HAVE CLEAN UP EQUIPMENT AT FACILITY; PlU_OWS, DRY ABSORBENT, SAFETY GEAR, ETC. WE HAVE AN EMPLOYEE RESPONSE TEAM. <4> Othe~' Resou~'ce Activatior~ A3/06/91 SAND CONTROL 2" 15-000-0t Page 7 00 - Overall Site <F> Site Er~ergency Factors <1> Special Hazards WASTE CONTAINERS MUST HAVE DATE 90 DAYS BETWEEN DISPOSAL. SOIL IN DRUMS NEEDS TO BE DATED 90 DAYS BETWEEN DISPOSAL. <2> Utility Shut-Offs A) GAS - NORTH CENTERS PROPANE "rANK - SOUTHEAST B) ELECTRICAL - NORTH CENTER C) WATER - NORTH CENTER D) SPECIAL - NONE E) LOCK BOX - N[] <3> Fire Protec. /Avail. Water PRIVATE FIRE PROTECTION - THERE ARE FIRE EXTINGUISHERS AT ALL APPROPRIATE LOCATIONS. ]"HERE ARE NO SPRINKLERS OR FIRE ALARMS. THE RESPONSE TEAM WOULD BE 7'HE SAME AS THE HAZARDOUS MATERIALS TEAM. FIRE HYDRANT - NORTH CENTER OF FACILITY ON ALDRIN COURT. VARIOUS FIRE STAND PIPE CONNECTIONS MOSTLY IN CENTER OF' FACILITY. <4> Held for Future use )3/06/91 BAKER SAND CONTROL 215-000-000759 Page 8 O0 - Overall Site <G> T~airsir~g <1> Page 1 WE HAVE 34 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE WE ARE IN COMPLIANCE WITH OSHA CFRi910. 120(:. WE DO HAVE AND USE A HAZARDOUS COMMUNICATION PROGRAM. ]'HERE ARE MONTHLY SAFETY MEETINGS IN WHICH HAZARDOUS MATERIALS ARE ALWAYS DISCUSSED. Page 2 as r~eeded <3> Held f,-,r Future Use <4> Held for Future Use Rt~EivED #lift 1 ~ 1991, -. SAND CONTROL H Z. M E M 0 A Baker Hugh~ ~mpany TO: ~TE: ALL EMPLOYEES JANUARY 8, 1991 FROM: CRAIG PARKER SUBJECT: COPIES TO: HAZARDOUS MATERIALS RELEASE AND DON COBB FIRE EVACUATION PLAN CURT CRANFORD SAFETY OFFICERS PHONE NUMBER. PAGER NUMBER Craig Parker . ,/ /835-9056 321-5381 Bob Usher " ~0v~-~589-3502 321-5386 HAZARDOUS MATERIALS RELEASE OR EMERGENCY (911) !. HAZARDOUS MATERIALS RELEASE OFFICE OR EMERGENCY SERVICES: 800-852-7500 800-427-4341 HAZARDOUS MATERIAL EMERGENCY RESPONSE TEAM: NAME PHONE NUMBER PAGER NUMBER Craig Parker 835-9056 321-5381 Bob Usher 589-3502 321-5386 Stan Miller 589-4492 321-2789 Andy Erberich 835-8793 321-5387 David Escobar 832-6242 321-7544 EMERGENCY PHONE NUMBERS: Valley Industrial Medical 327-2225 Memorial Hospital .327-1792 Ambulance 327-4111 OR 911 Fire Department 397-8150 OR 911 Paramedic 397-8159 OR 911 Police 327m7111 OR 911 .When an emergency situation presents itself all employees will assemble at the coffee break area which is in front of the mechanic shod in the main warehouse. Safety Officers and Emergency Response Team will be notified. A plan of action will be notified by word of mouth and by phone if possible. At this time the proper authorities will also be notified. cP SAFETY. MEM1 Bakersfield Fire Dept. ~ HAZARDOUS MATERIALS DIVISION Date Completed Business Name: ~]'~))~.,/~!~.~. ~. ~.~.A,~ C~!'V'T?~t~I RECF_IVFD Location: ;~:~! ,.,'~r'L~lD,,-~/ C~,~O/~ FEB25 1991 Business Identification No. 215-000 ~7~"'C~ (Top of Businesses Plan) Station No. I ~ Shift ~) Inspector 5, ~ ~R, Y Adequate Inadequate Verification of Inventory Materials Verification of Quantities Verification of Location Proper Segregation of Material ~'Comments: Verification of MSDS Availablity Number of Employees ~'~ ~ Verification of Haz Mat Training Comments: .~~)~,~"T".~LY 5A F~7 ~ ~ ]::~T-.~]V ~.~...~ Verification of Abatement Supplies & Procedures Comments: o c-~,~' Emergency Procedures Posted ~mments: Containers Properly Labeled Verification of Facility Diagram Special Hazards Associated with this Facility: _ ... _.::..\ Correction Needed ~ B~ines{ Ownet'lManager FD 1652 (Rev. 1-90) White-Haz Mat Div. Yellow-Station Copy Pink-Business Copy 02/26/90 KER SAND CONTROL 215-0 000759 Page 1 Overall Site with 1 Fao. Unit General Information Location: 5551Aldrin Ct Map: 123 Hazard: Moderate Ident Number: 215-000-000759 Grid: lSD Area of Vul: Contact Name Title I ' Business Phone ---T 24 Hour Phoneq CRAIG PARKER DISTRICT MANAGER 1(805) 834-2844 x /(805) 835-90561 BOB USHER FIELD SUPERVISOR !(805) 834-2844 x ~(805) s89-ee4~l Administrative Data Mail Addrs: 5551ALDRIN CT D&B Number: 09-357-7377 City: BAKERSFIELD State: CA Zip: GeoSubDiv: 215-009 BAKERSFIELD STATION 09 SIC Code: 1389 Owner: BAKER SAND COMPANY CORP Phone: (805) 834-2844 Address: 1010 RANKIN RD State: CA City: HOUSTON Zip: 77073- Summary 02/26/90 A!KER SAND OONTROL 215-0 000759 Page 2 Hazmat Inventory List in Reference Number Order 02 - Fixed Containers on Site 02-001 MAGNESIUM CHLORIDE ? 286 Unrated A 02-002 MAGNESIUM OXIDE ? 220 Unrated LBS 2-005 HYDROXYETHYL CELLULOSE Solid 10,000 Unrated LBS 01 004 BORAX ? 75 Unrated LBS 02-O0_~MMONIUM NITRATE ? 4 000 Extreme 02-008 SODZU~ HYPOCHLORZTE ? 115 High GAL __//02-009 AMMONIUM CHLORIDE Solid 5,000 Low lmmed Hlth LBS ~ 02-010 SULFAMIC ACID Solid 800 Minimal Immed Hlth LBS 02-011 LIME~ ~~ ¢ 550 Low LBS ~¢02-0i2~ SODIUM HYDROXIDE, FLAKE 9 lO0 Low LBS 02-0i5 SODIUM HYDROXIDE, LIQUID ~ 150 Moderate ~ D~~ GAL 02-015 NALCO ASP-2OO/SODIUM HYDROXIDE 9 55 Low O~-01~ DEFOAMER/POTASSIUM HYDROXIDE ~ ~ Moderate ~ Immed Hlth ' GAL ~ ~ Reactive, Immed Hlth GAL ~/ 02-019 BIOCIDE/GLUTARALDEHYDE ? 55 Moderate GAL 02-020 DONFAX 2~MONO & DIDODECYL DISULFONATED ? ~30 Unmated % / GAL 02/26/90 BAKER SAND CONTROL 215-00~-000759 Pa9e 5 Hazmat Inventory List in Reference Number Order 02 - Fixed Containers on Site ~ ~2-021 UNION CARBIDE UOAR 510/AMINE/GLYCOL Liquid 200 Unrated Immed Hlth GAL 02-022 NALCO ASP 162/PHOSPHATED ALCOHOL ~ 440 Moderate ~ ~~-~ GAL 02-025 NALCO ASP 168/KEROSENE ~ 165 Low ~ ~ GAL ,-024 MAGNA All4/AROMATIC PETRO SOLVENT ~ 55 Moderate GAL 02-025 MAGNA AI17/ISOPROPANOL ~ 55 Moderate -------'-' b ~-~-~-- GAL 02-026 A-iOO/CRONOX 265/ISOPROPANOL ~ 55 Moderate GAL 0 ' KEROSENE ~ 55 Low GAL tL~-028 LIOUEFIED PETROLEUM GAS (PROPANE) Gas 450 High Fire, Pressure, Immed Hlth GAL n1,~-029 WASTE OIL (NA 9189) Liquid 500 Low Fire, Immed Hlth, Delay Hlth GAL ~/~02-050 MOTOR OIL Liquid 500 Minimal Fire, Immed Hith, Delay Hlth GAL 02-051 HYDRAULIO OIL Liquid 100 Low Fire, Immed Hlth, Delay Hlth GAL 0~2-052 TRANSMISSION FLUID Liquid 100 Low Fire, lmmed Hlth, Delay Hlth GAL b 0_2-055 OXYGEN Gas 900 ~ Low Pressure, Immed Hlth ,,,02-054ACETYLENE Gas 400 High Fire, Pressure, Immed Hlth, Delay Hlth FT5 02-055 DIATOMACEOUS EARTH Solid 75,000 Minimal ~ I~med Hlth, Delay Hlth ~~ LBS t~b~-056 SILIOA SAND Solid 1,400,000 Minimal Immed Hlth, Delay Hlth LBS 02-057DIESEL ~~LiquidlO0 Low -- ~, Immed Hlth, Delay Hlth GAL ~,~ 02-058 POTASSIUM CHLORIDE Solid 15,000 Mlnimal Immed Hith LBS 02/26/90 BAKER SAND CONTROL 215 3759 Page 4 Hazmat Inventory List in Reference Number Order 02 - Fixed Containers on Site ~lj 02-059~_~ SODIUMimmed HlthCHLORIDE Solid 5,000 LBS Minimal ~ 02-.040 SOLVENT/685 Liquid 200 Moderate Fire, Immed Hlth, Delay Hlth GAL S?...d Craig V. Parker District Manager 5551 Aldrin Court Bakersfield, CA 93313 (805) 834-2844 REGEIVED BIAKEE M EM 0 SAND CONTROL H,AZ. MAT. DIV.~c-*~^ A ~er Hugh~ ~m~y TO: DATE: FROM: ~- CRAIG PARKER SUBJECT: COPIES TO: HAZARDOUS MATERIALS RELEASE AND DON COBB FIRE EVACUATION PLAN CURT CRANFORD SAFETY OFFICERS PHONE NUMBER PAGER NUMBER Craig Parker .. 835-9056 321-5381 Bob Usher 589-3502 321-5386 ' HAZARDOUS MATERIALS RELEASE OR EMERGENCY (911) "' HAZARDOUS MATERIALS RELEASE OFFICE OR EMERGENCY SERVICES: 800-852-7500 800-427-4341 HAZARDOUS MATERIAL EMERGENCY RESPONSE TEAM: NAME PHONE NUMBER PAGER NUMBER Craig Parker 835-9056 321-5381 Bob Usher 589-3502 321-5386 Stan Miller 589-4492 321-2789 Andy Erberich 835-8793 321-5387 ' David Escobar 832-6242 321-7544 EMERGENCY PHONE NUMBERS: Valley Industrial Medical 327-2225 Memorial Hospital .327-179Z Ambulance 327-4111 OR 911 Fire Department 397-8150 OR 911 Paramedic 397-8159 O~ 911 Police 327-7111 OR 911 .When an' emergency situation presents itself all employees will assemble at the coffee break area which is in front of the mechanic shod in the main warehouse. Safety Officers and Emergency Response Team will be notified. A plan of action will be notified by word of mouth and by phone if possible. At this time the proper authorities will also be notified. CP SAFETY . MEM1 BAKI-:R MEMO SAND CONTROL A Baker Hughes company ~¢ S TO: ALL EMPLOYEES DATE: .JANUARY 12, 1990 FROM: CRAIG PARKER SUBJECT: HAZARDOUS MATERIALS RELEASE AND FIRE COPIESTO: EVACUATION PLAN SAFETY OFFICERS: PHONE NUMBER "PAGER NUMBER CRAIG PARKER 835-9056 321-538! BOB USHER 589-0647 321-5386 HAZARDOUS MATERIALS RELEASE OR EMERGENCY (911) HAZARDOUS MATERIALS RELEASE OFFICE OF EHERGENCY SERVICES: 1-800-852-7550 1-800-427-4341 HAZARDOUS MATERIAL EMERGENCY RESPONSE TEAM: PHONE NUMBER PAGER NUMBER 1. CRAIG PARKER 835-9056 321-5381 2. BOB USHER 589-0647 321-5386 3. STAN HILLER 589-4492 321-2789 4. RICK JEFFREY 398-7017 321-5384 5. STAN DAVIS 832 1792 321-2246 When an emergency situation presents itself all employees will assemble at the coffee break area which is in front of the mechanic shop in the main warehouse. Safety Officers and Emergency Response Team will be notified. A plan of action will be implemented. Adjacent companies around our facility will be notified by word of mouth and by phone if possible. At this time the proper authorities will also be notified. SAFETY.HERO 0 12/19/89 BAKER SAND CONTROL RECEIVED Page Site as a Whole JAN 9 1990 Ger, eral Inforrnation An~'d Location: 5551 Aldrir, Ct Map: 1::'3 Hazard: Moderate Ident Number: 215-000-000759 Grid:15D Area of Vul: Administrative Data Mail Addrs: 5551 ALDRIN CT D&B Number: 09-357-7377 City: BAKERSFIELD State: CA Zip: 93313- GeoSubdiv: BAKERSFIELD STATION 09 SIC Code: 1S89 Owner: BAKER SAND COMPANY CORP Phone: (805) 834-2844 Addrs: 1010 RANKIN RD State: CA City: HOUSTON Zip: 77073- Contact Title Business Phor, e 24 Hour Phone DON B. COBB DISTRICT MANAGER (805) 834-2844 x (805) 833-9'784 CRAIG PARKER FIELD SUPERVISOR (805) 834-2844 x (805) 835-9056 Summary: CONTACT TITLE BUSINESS PHONE 24 HOUR PHONE CRAIG PARKER DISTRICT MANAGER ~ (805) 834-2844 (805) 835-9056 BOB USHER FIELD SUPERVISOR (805) 834-2844 (805) 589-0647 mWewed ~e affached hazardoue m~nt p,~ ~a~ that ft ~bn9 ~ ~,. ~ny corre~Jons ~nsti~u~e s c~pb~e arid co~vc~ man. egement pt~n for my 12/19/89 BAKER SAND CONTROL Page 007 <D> Notif./Evacuatiorl/Medical fo~-: O0 - Site as a Whole <1> Agency Notification call 911 <2> Employee Notif./Evacuation ALL EMPLOYEES KNOW AND ARE AWARE OF SITE EVACUATION PROCEDURES AND THE PROPER NOTIFICATION PROCEDURES IF ]'HERE IS A HAZARDOUS RELEASE. THE FIRST STEP IS TO CALL 911 AND TO GIVE THEM ALL INFORMATION ABOUT THE RELEASE. CALL ]'HE COMPANY RESPONSE TEAM AND TO CALL THE OFFICES OF EMERGENCY SERVICES <3> Public Notif./Evacuation TO THE NORTH~ WEST' AND SOUTH OF' OUR ESTABLISHMENT' THE BUSINESSES STAY UNDER THE SAME NAME, HOWEVER~ TO THE EAST AND SOUTHWEST, THE BUSINESSES HAVE CHANGED DURING TIME. I HAVE INFORMED CRAIG PARKER AND SEVERAL OTHER KEY PEOPLE AS TO ]'HE NEED OF A PUBLIC EVACUATION PLAN. WE PLAN TO VERBALLY, IN PERSON, NOTIFY OUR NEIGHBORS IN THE CASE OF A THREATENING HAZARDOUS MATERIALS RELEASE. 12_/19/89 BAKER SAND CONTROL Page 008 <D> Notif./Evacuation/Medical for: O0 - Site as a Whole <4> Emerger, cy Medical Plat, WE HAVE EYE WASH, SHOWER AND SMALL MEDICAL KIT ON HAND. WHITE LANE MEDICAL CENTER - 5401 WHITE LANE - 832-2000 MEMORIAL HOSPI]'AL - 4~¢ 34TH STREET - 327-1792 VALLEY MEDICAL CENTER'- 5700 STOCKDALE HIGHWAY - 324-4014 12/19/89 BAKER SAND CONTROl_ Page 009 <E> Mitigatior~/Prever~t/Abatemt for: 00 - Site as a Whole <1> Release Prever, tior, WE HANDLE ONLY SMALL AMONTS OF HAZARDOUS MATERIALS. USUALLY EITHER DRY IN 55 POUND SACKS OR LIQUID IN 55 GALLON DRUMS. WE HANDLE CHEMICALS CAREFULLY WITH THE PROPER EQUIPMENT. WE CAN HANDLE SMALL CLEAN UPS OF RELEASES WITH THE EQUIPMENT WE HAVE ON HAND. <2> Release Corftair, mer~t We have asphalt Derms seperating chemicals. Also a chemical handling area which is bermed with a non leaching sump. <3> Clear, Up Everyone at facility is trained. We have clean up equipment at facility; pillows, dry absorbent, safety gear, etc. We have an employee response team. 12/19/89 BAKER SAND CONTROL Page <E> Mitigatir, r~/Prever~t/Abaten~t for: O0 - Site as a Whr, le <4> Othe~' Resource Activatior, 12/19/89 BAKER SAND CONTROL Page 011 <F> Site Emergerlcy Factors for: O0 - Site as a Whole <1> Special Hazards WASTE CONTAINERS MUST HAVE DATE 90 DAYS BETWEEN DISPOSAL. SOIL IN DRUMS NEEDS TO BE DATED 90 DAYS BETWEEN DISPOSAL. <2> Utility Shut-Offs A) GAS - NORTH CENTERS PROPANE TANK - SOUTHEAST B) ELECTRICAL - NORTH CENTER C) WATER - NORTH CENTER D> SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - THERE ARE FIRE EXTINGUISHERS AT ALL APPROPRIATE LOCATIONS. THERE ARE NO SPRINKLERS OR FIRE ALARMS. THE RESPONSE TEAM WOULD BE THE SAME AS 7'HE HAZARDOUS MATERIALS TEAM. FIRE HYDRANT - NORTH CENTER OF FACILITY ON ALDRIN COURT. VARIOUS FIRE STAND PIPE CONNECTIONS MOSTLY IN CENTER OF FACILITY. 12/19/89 BAKER SAND CONTROL Page 012 <F> Site Er~ergerscy Factors for: O0 - Site as a Whole <4> Held for Future use 12/19/8g BAKER SAND CONTROL Page 013 <G> Trairsir~g fo~: O0 - Site as a Whole <1> Page 1 WE HAVE ? EMPLOYEES AT THIS FACILITY lg DO YOU HAVE MATERIAL SAFETY DATA SHEETS ON FILE? YES WE ARE IN COMPLIANCE WITH OSHA CFR1910. 1200. WE DO HAVE AND USE A HAZARDOUS COMMUNICATION PROGRAM. 'THERE ARE MONTHLY SAFETY MEETINGS IN WHICH HAZARDOUS MATERIALS ARE ALWAYS DISCUSSED. <2> Page 2 as rseeded <3> Held for Future Use CITY of.BAKERSFIELU HAZARDOUS MATERIALS INVENTORY Farm and Agriculture [] 'Standard Business D NON--TRADE SECRETS USINESS NAME: BAKER SAND CONTROL OWNER NAME: BAKER SAND CONTROL NAME OF THIS FACILITY: OUTSIDE S.W. TI N' C~O'''' .~]~: '5651 ALDRIN COURT AODRESS: 1010 RANKIN RD. ST N AR0 IND CLASS COD BAEERSFLELD. CA 93-~1-3---- CZTY. ZIP~ HOg, TON, TX 77208 DU~ ~ND BRADgTREE! NUMB~ PHONE #: ~05-834-2844 PHONE #: -7--TT'~fAAq-~g~n CODES 0_9_ - ~7_ -Z.3~7_ _ REFER I 2 3 4 $ 6 I 8 9 I0 !I 1213 14 Tr'ans !,0e Hex AvgrHe Annual Heasure '""euit ~ont gont Con, Us~ Locqtion?e(e. ,-by, t Hames of ,ixture/C~eeonents Code code Amt Rmt Est Units on~ype Press lem~ Coue Stored In ~acll~ty See Instruct~ons Physical and Health Hazard C.A.S. Number 7647-01-0 Component II Name I C.A.S. Number (Check all that aPply) , ~ Fire Hazard ~ Reactivity [] Delayed ~ Sudan Release ~ immediate Component 12 Name I C.A,S. Number Health of Pressure Health Component 13 Name I C.A.S. Number ~ I w I ~oo I ~oo I ~,ooo I~1 ~o~ ,I o~ I ~ I 4 I 40 IOiTTS~PEg.W. CORNOR 1tiff WARTR OTT, Physical and Health Hazard C.A.S. Number N/A Component II Name I C.A,S, Number (Check al/ that apply) Component t2 Name I C.A.S. Number ~ Fire Hazard ~ Reactivity ~ Belayed [] Sudden Release ~ Health of Pressure Health Component 13 Name I C.A.S, Number Physical and Health Hazard C.A.$. Number Componen: I! Name a C.a.s. Number (Check ali that apply) Component 12 Name & C,A.S. Number ~ Fire Hazard [] Reactivity [] Belayed [] Sudden Release [] [mq~di~e Health of PressureHealth Component 13 Na~e I C.A.S. Number Il ll'll Physical and Health ~azard C.l.S. Number Component I! Name & C,A.S. Number (Check 411 that app/~l Component 12 Name & C.A.$. Number ~ Fire Hazard [] Reactivity [] ~leyed [] Sudden Release D ]'mq~di.a~e Health of Pressure Health Component 13 Name I C.A.S. Humber EMERGENCY CONTACTS #IN,metric PARWER ~RTCT MA~AC~t~~(~._._ #2BOB USHER ~[~ELD SUPERVISOR ~ N~e i ~rti[jgatioq ,(Re~ ~p~.~ign af~pr Compl~tipg..mll..~ecCipn~) .cer~lu.unaerpenalty ol~tnBtlnavepersonH~.examlnqqeqa~m ~mll~s[.gltB ~e~niormatlonBu~mitt~dinthis.~ndall ~t~acnea.aoc~ment~, an~ t~t oas, on.my ~nquiry 9Ltnose ~na~v~oua~s respons~mle ~or obtaining.the ~n~orma:~on. ! ben,eve that R~Ti:iai Tibia of o~nerioperator u~ O~ner/operator's authorized representative CITY of BAKERSFIELD HAZARDOUS HATERTALS TNVENTORY Farm and ~gticulture [] 'Standard Business [] NON--TRADE SECRETS Paqe 1 of',2 US[NESS NAME: BAKER 'SAND CONTROL 0,NER NAME: BAKER SAND CONTROL NAME OF THiS FACILI,Y: SOUTH CHEMICAL WHSE ~0TlgN' 5551ALDRIN COURT ADDRESS: '1010 RANKIN ROAD STANDARD IND. CLASS CODE,__~__.13_8~ C.._~. IP: BAKERSFIRI,B. CA q3313 LILY. ZIP: ROTISTON ~ 77?08 DUN AND BRADSTREEI NUMBER ....... PHONE fi: 805-83a-?gA~" PHONE #: --7'T*3~m-443zibgo 09_ - ~57 - 7377 REFER TO--IiVSTRUCTIONS-F'OR-PROPER CODES - - - I 2 3 4 5 6 7 8 9 I0 11 12/~ /ype Press Temp Cole Storea iff FaCility See Instructions ~ixture/C:~Donents Physical and Health Hazard C.A,S. Number 12125-02-9 Component II Name I C.A.a. Number ICheck all that apply) FI Fire Hazard [] Reactivity [] Delayed [] Sudden Release I~1 Immediatec°mp°nent ,2 Name I C.A.S; Number Health of PressureHealth ' Component 13 Name I C,A,S. Number , U J P I 800 I 400 I 3.500 ILBS I 365 ~l 12 I 1 I 4 } il ISOUWW CHEMTCAL WHSE. O0 W-3PP/ST~.¥AHTC ACID Physical and Health flazard C.A.$. Number 5329-14-6 Component II Name & C.A.S. Number [Check all that Component ~2 Name & C.A.S. Number ~ Fire Hazard [] Reactivity [] Oelayed [] Sudden Release El Im~di~.t~ Health of Pressure Healt~ Component 13 Name I C.A,S. Number Physical and geHth Hazard C.A.S. Number 7447-40-7 Component I1 Na~e & C,A.S. Number ICheck all that apply) Component 12 Name I C,A,S. Number I-] Fire Hazard [] Reactivity [] Oelayed I-] Sudden Release El Immedi~t~ Health of Pressure Health Component 13 Name I C.A.S. Number ~ · Physical and Health ~alard C,A.S. Number 7647-15-6 Component II Name I C.A.S, Number (Check a11 that apply! Component 12 Name I C.A.S. Number [] Fire Hazard [] Reactivity [] Oela~ed Fl Sudden Release Et ]'mmedi~.Ce Health of PressureHealth ,, Component 13 Name I C,A.$. Number EMERGENCY CONTACTS #INCRAIGPARKER--D3~TRTCT~f~TRle MANAGER_ g~A-?gAA #2 BOB USHER FIELD SUPERVISOR 834-2844 _Z4 Hr Phone N~e Title I ~rLi~i~atioq .~Refld ~p~.~ign af~pr compl~tipg.~ll secCi.on~) cerH~y under pena~[~ o/~aff [nqt ! navepersona~ eXamlnqqeqo~m rami~ta[.git~ the )n~ormac]pn 8u~aiLt¢~ in thisand I] SHOe,ireD ,A,ormaclon l$ [rue, accura[,, and COmp/eLm.CRAiG PARKER/DISTRICT MANAGER ~~~ ~i~fi¢iai ~i[ie of o~ner/operator oH oMner/operator's authorized representative ClTY of BAKER:SFIELD HAZARDOUS MATER]IALS ]iNVENTORY Farm And ADticu~ture I-1 Standard Ousiness [] NON--TRADE SECRETS PaDe 2 of' US[NESS NAHE: BAKER SAND CONTROL OWNER NAHE: BAKgR SAND CONTROL NANE OF THZS FACZL]TY: SOUTH CHgHICAL WHSg T! N' Ir'~fl$ !yne ,ax Av~rpDe Annual NeRvure ItYs ~oflt ~ont Coot Us tocation3heEe. ~by Hames of Code ~ooe AmC AmT Est Units on itu /ype Press Tamp ColeMt See Instruct~ons ~xture/Ce~onents Stored Iff facility Physical aod ~ealth HaNrd C,~.S, Number ~7-~-8 Component I1 Name I ¢,A,S, N~mber b// (Check ali that apply) [] Fire Hazard Fl Reactivity Fl Delayed D Sudden Release I~l Immediatec°"p°nent 12 Name I C.A.a. Number Health of PressureHealth Component 13 Name I C.A.S.' Number Physical lcd Health Hazard C.A.a. Number 9004-62-0 Component II Name I C.A.a. Number / ICheck 811 that Apply) Component 12 Name & C.A.S. Number F! Fire Hazard F! Reactivity [] Oelayed [] Sudden Release Fl [m~ediste Health of Pressure Health Component 13 Name I C.A.S. Number Physical and Health Hazard C.A.S. Number ~/A Component I1 Name i C.A.S. Number (Check ali that apply) AMINE/GLYCOL MIXTURE Component 12 Name & C.A.S. Number Fl Fire Hazard [] Reactivity I-I Delayed [] Sudden Release El lmmedi~!e Health of Pressure Health Component 13 Name I C.A.S. Number Physical and Health ~aNrd C.k.S. Number Component II Name I C.A.S. Number (Check all that app/yl ~5 ZI~CON~T_~ O.XTC~-~COR~ 769.9- Component 12 Name t C.A.S. Number E] Fire Hazard [] Reactivity I'1 Delayed [] Sudden Release E! ]mmedi~.t~ ~2 ~-r~oc~Lo~c ACID 7647-0~-0 Health · of PressureHealtn ' Component 13 Name I C.A.S. Number EHERGEHCY COHTACTS #1C~..~Id ~A~K~R ~STR~CT N_.~AOgR 834-2844 fl2 BOB USH~ ~I~L9 SU?~ISO~ 834-2844 Name T~ I e 2T-Rr-~e Na-Tie TIT 1 e ferti[i~a~ioq ,(Re~d an~.~fgn a£~ comp?~tf~g,~l? secCf.on~) .cern,fy unoer pena,Ty o,,F th,, jAave pe[sonaj~.examln,,eqo gm ~ami,,aL ,it~ the ,ntorm,T!pn ,u~mitt,~ in this.end a,! /~ 8t~acned.d~c~menc~, Afll t~ac oaseo on.my Inquiry qr. Tnose IflOlVlOUa/S responsible rot obtaining cna Information. I believe thstt~~/~~ --~' suomltteo information IS True, accurate, loc complete. CRAIG_~ARKER/DISTRICT MANAGER ' HT~F-T~-~fl~)a~ [~tIG Of ovnerloperator o~ ouner/oPerator's authorized representative SlTj~e CITY of BAKERSFIELD Farm and Agriculture [] Standard Business [:]HAZARDOUS MATERIALS INVENTORY NON--TRADE SECRETS Page i o~'}, , U~INESS NAME: BAKER SAND CONTROL OWNER NAME: BAKER SAND CONTROL NAME OF THIS FACILITY: OUTSIDE N.E WHSE TI N' ' : BAKERSFIELD. CA 9~3~_.__ CZ~Y. ~P:__HOJ2STON:i TX 77028 " DUN AND BRADSTREE! NUMBER ......... I 2 3 4 5 6 T 8 9 I0 11 12/3 14 [r'ans !y,e Hax Av~rpge Annual Heasure , ys ~ont ~ont Cont Us tocation.,he[e. ,-by ,ames Of ,ixture(Comoonents Code ~oae Amt Amc Est Un~&s on lie ~ype Press lemp ColeStgred ~n ~ac~cywc See Instructions ~ I~ I ~00 I ~00 I ~00 leAL I 36S 'l'"i~ ! ~ 14 los ]OUTSIDEN.E.WHSE 100 S-60/DIESEL ~h~$ical and Nealth Nazard C.~,S, Number 68476-34~6 Component II Name t C.i,S. Number / \ (Check ali that apply) [] Fire Hazard [~ Reactivity ~] BHayed I~ Sudden Release ~ ]mmediateC°mp°nent 12 Name ~ C.A,S. Number Health of Pressure Health Component 13 Name I C,A,S, Number / ,. ~ I ~ I ~oo I ~oo I ..... 200 I~ I ~, .I ~ "]1 ~. I,~ I' o~ I o~ ~.~. ~ ~oS Physical lad Health Hazard C,A.S, Number 8032-32-4 Component II Name I C,A,S. Number (Check al/ that apply| Component t2 Name & C,A,S, Number El Fire Hazard Fl Reactivity ~] Belayed [] Sudan Release ~ ]mmpdi~e Health of PressureHealth ... Component 13 Name I C,A,S, Number Physical and Health Hazard C,A,a. Number Component Il Name I C,A,So Number (Check a/1 that apply) Component 12 Name I C,k,S, Number [] Fire Hazard [] Reactivity [] Belayed [] Sudden Release [] Immpdi~e Health of Pressure Health Component t3 Name I C,A.a, Number Physical and Health Pazard C,A,S, Number Component Il Name I C,A,S, Number ICheck 411 that apply) Component 12 Name I C.A.S. Number ~ Fire Hazard [] Reactivity [] ~layed [] Sudan Release lq l'mm~di~e Health of PressureHealth .... Componen: 13 Name ~ C,A,a, Number EMERGENCY CONTACTS #1NameCRAIG PARKER.,..,. --~1~~~4. Hrg3A-2RAAPnone #21~~,._..._ TTgR~R , ~T~)~ BUPRRVTgQR ;erti[i~atioq .(Re~d and.~ign after compl~tipg.all sec~f,°n~) certify under ~enalt~ oI~ thqt [navepersonal~,examln~qlqola rami~ar, vitb the ~ntormatton ~u~mittfd in [his.lnd alIsl~~re~ ] believe that t .'~' ;uom, tteo,t,ached .doc~menthC~!I G PA~KER/BI STRIC Tlnf°rmatl°nan01s t.hattrue,OaseOaccurate,MA~AGEROn.m, ano'nquirYcompiete.gL those ,notvioua,s r espons 1 old ,or obtaining the In,ormat,on. ,ttJ~ . N~fitiAi titie Of ovnerioperator uR o~nerioperator:s authorized representative CiTY of BAKERSFIELD HAZARDOUS MATERIALS INVENTORY Farm and ~gticulture [] Standard Business [] NON--TRADE SECRETS Page 2 of' 2 USINESS NAME: BAKER SAND CONTROL OWNER NAME: BAKER SAND CONTROL NAME OF THIS FACILITY; NORTH EAST WHSE II N- ADDRESS: lOlO RANKIN RD STANDARD IND. CLASS CODEi 138~ BAWERSFI~I,D. CA q~.~l~ CITY. ZIP1 ~OTTgT~M Ty 777D8 DUN AND BRADSTREE! NUMBER -- PttON E #: ~u)-~J4-z~4~ 'R~E~ YO-"/~S TRUC'FZONS-F'OR-PROPER CODES Wans !yom ,ax Average Annual Heasure 'OYSe Code come Ami Amc Est Units on lamp Co.eStoredIn facility See lnst~c~ons (,] I P I 900 I 840 I 4,500 I~ ~1 ~ I04 I~ 14 I Z6 I~0~?~ EAST WHSE 10" OXYGEN //~ PhYSiCal a,d Health Hazard C.~,S, Number 7782-44-7 Component II Name ~ ¢,LS. Humber ICheck ail that apply) , ~ Fire Hazard ~ Reactivity ~ Oela~ed ~ Sud~, Re)ease ~ lmmedinte Component 12 Name ~ C.A.S. Number Health of Pressure Health Component I~ ~ame I C.~.S. Number Physical lad Health Hazard C,A.S. Number 74-86-2 Component II Name & C,A,S, Humber (Check all that app]y! .... Component t2 Name I C.A,S, Number [] Fire Hazard ~ Reactivity [] Belayed [] Sudden Release ~ Immediate Health of Pressure Health Component 13 Name I C,A.S, Number ~hy$ical and ~aith Hazard C.~.$. Number Component ~1 Na~ ~ C.A.S. Number (Check all thlt apply) ' Component 12 Name I C,A,S, Number [] Fire Hazard ~ Reactivity [] Belayed [] Sudden Release [] Health of Pressure Health Component 13 Name I C.A.S. Number Physical and Health 8alard C,l,S, Number Component II Name I C,A,S, Humber (Check 4/! that apply) Component 12 Name & C.A.$. Number ~ Fire Hazard [] Reactivity ~ Belayed [] Sudan Release [] l'mm~diAt, e Health of Pressure Health Component 13 Name I C.A.S. Number EMERGENCY CONTACTS #1CRA~ ~A_R~ER gZSTRZCT ~HA~ER 83~.28~4 #2~0~ gSHE~ ~ELg SU~ERWSOR 83~-284G Hake rf[~ z4 Hr PhoneR~e' ~TCle ~T~r-~'~-~-~---- .certify unbar genalcX o~ cn~t lhavePersonalg, exsmlnq~iqoim ramil~sr, yi~g ~e inlormac!pn ~uUmitt~d in this tnd all . ,L~acned.dgcwmenL~, an~ t~t oaseo on.my Inquiry 9t. cnose InOivlOUalS responsible for obtaining the Information, I believe that the / --' uomILtOOc~.,G_ ~A_K~E~/g~$TR~CTInt°rmaH°n IS ,rue, accura,e, ,no complete. ~~[t~lal T~zle ot o~nerloperator u~ buner/op~fJtor's authorized r~presentattve CITY of BAKi::RSFIELU Farm snd Agriculture D Stsndard Business D HAZARDOUS MATERIALS INVENTORY NON--TRADE SECRETS BUSINESS NAME: BAKER SAND CONTROL OWNER NAME' BAKER SAND CONTROL WHSE N' 1DlO RANKIN RD' STANDARD IND. CLASS CODE~ 1389 ' ADO~ESS: ' NAME OF THIS FACILITY: NORTH EAST BAEE~SFI~LU. CA ~33L3 tIT . ZIP'7'--'--~bTTSTON TX 7~208 DUN AND BRADSTREE! NUMBER PHONE #: (BbE)834-Z~44 ~ P ON #' - ' '- _ _ Ns~es of ~ixture/¢o~onen~ CodeTr'ans ~oue!Yfle AmCflax AvgrpgeARt AnnualEst Neasureun~Cs chi lyre ~ont ~ont Cont Us LocqLion. Xhece. . ~ype Press Tamp cole see lnstrucL~ons~// · Stored Iff PaclllCy PhYsical and Health Hazard C,A~S, Number Component II Hame I C,A,S Number iCheck ali that apply) ' Component 12 Name & C,A,S, Number [3: Fire Hazard B Reactivity [] Delayed B Sudden Release ~ Immediate Health of Pressure Health Component 13 Name S C.A.S. Humber Physical apd Health Hazard C,A,S. Number Component II Name & C,A,S, Number {Check all Chit apply! Component t~ Name I C,A,S, Number !:3: Fire Hazard ~ Reactivity ~ Delayed [] Sudden Release ~ Immediate Health of Pressure Health Component 13 Name & C,A,S, Number Physical lnd ~eslth ~aNrd C,A,S, Number Component Ii Name I C.A,S, Number ICheck all that applyl .... []: Fire Hazard. ~ Reactivity ~ Delayed [] Sudden Release [] lmmedi~t~C°mp°nent Health of Pressure Health Component 13 Name t C,A.S, Humber Phvsical lnd Health 8azard C,A,S, Number Component II Name I C,A,S, Number {Check all that apply! Component I~ Name & C.A,S. Number ~ Fire Hazard Fl Reactivity [] ~layed [] Sudden Release [] ['mmedi~t~ Hem ICh of PressureHealth .. Component 13 Name S C.A,S. Number EMERGENCY CONTACTS #1 CRAIG PARKER DISTRICT MANAGER 834-2844 #2 BOB USHER FIELD SUPERVISOR 834-2844 Raze TT[le ~ ~4 Hr Phone" N~e TlCle :erti[i~aCioq .(Re~ an~.'~ ign af~pr comp let i~9 ,~ 71 .~cCi.°n~) .cerHLy.unoer penalty o/~a~ th~c J navepe[sonal~.examin~tqo~m ~millat¥itocne.~n~ormaupfl ~u~mittfd in this.tnd all . ~t~acnee.o~c~menta, anl t~at cased on.my ~nqu~ry ~t. cnose ~no~v~ouats responsible Tor coca,hint cna ~nrormac~on. ] believe thatt/l~ / ? uom,tceoCRAIG'nt°rmac!°n ~A~ZaER/DIST~cT'S ,rue, accurate,~t/~AGER and comptete. S~u r el~:~/~,._.~~ ~Ti,~-/? , .....~_. '"' ~T.p~.................if~fiCiai cttle of ounertop~rltor uH o~nerloPerator's authorized representative " CiTY ot' BAKER EF.LFLU Farm andkgticulture ~ 'StandardRusiness q_]HAZARDOUS HATERTALS TNVENTORY NON--TRADE SECRETS PaDe 1 USINESS NAME: BAKER SAND CONTROL OWNER NAME: BAKER SAND CONTROL~ NAME OF THIS FACILITY: OUTSTOt~ S.E CORNOR ~TI~N~. ~ CT. ADDRESS; __.....L~RA-'~-'~f'N~ STANDARD IND. CLASS CODE~ ~'5o9 ' CJI . ZtF: BAKERSFIELD. CA 93313 CITY. ZIP: ~OU,~TON T¥ 779nR DUN AND BRADSTREE! NUMBER ......... PtiONE ~: 805-834-2g4&' PHONE ¢: - /~:~z1~O CODES Oj - ~ - ~7 ' REFER TO~S TRUCTfONS-~R-PROPER .... Code :oDe Act Aa: Est Un,ts on ~ype Press lemo CONeStored In eac~/~ty 5em Instructions Physical and 8ealth Hazard C.A.S. Number 74-98-6 Component 11 Hame I C.A.5. Humber (Check all that apply) ~ Fire Hazard ~ Reactivity ~ Belayed ~ Sudden Release ~ Immediate Componen: t2 Name I C,A,S, Number Hem ICh of PressureHealth . Component 13 Name ~ C.A.S. Number Physical lad ~ealth Hazard C,A,S, Number Component Il Name I C,A,S, Number (Check 4// that'app]~l Component I~ Name I C.A.S. Number ~ Fire Hazard ~ Reactivity ~ Belayed ~ Sudden Release ~ Immediate Health of Pressure Health Component 13 Name I C,A,S, Number Physical and Health Hazard C,A,S, Number Component Ii Name I C,A.a, Number ICheck a11 that apply) Componen~ I~ Name I C.A.S. Number ~ Fire Hazard ~ ReacLiviLy ~ Belayed .~ Sudden Release ~ Immediate Hem ICh of Pressure Health Component 13 Name I C,A,S. Number · Physical and Health 8alard C,A,a, Number Component II Name I C,A,S, Number lCheck 411 that appl'yl Component I~ Name & C.A.S. Number ~ Fire Hazard ~ Reactivity ~ Belayed ~ Sudden Release ~ l'mm~di~e Health of Pressure Heal:b Component 13 Name I C.A,S. Number rti[iGatioq .(Re~ and sfgn after c~mp7etfpg.~17 secCi~n~) .cerHty.unoer pena~t~ oT~aW thqt l havepersona/~Lexaelnq~lqolm tamil~aC. Vit~ the ]ntocmaupn ~u~mitt~ in this,lnd all ~~ri~i~i tide of o~nerlop~r/tor UH o~nerlopetator's authorized representative s~cure - CiTY of BAKER5FJ. FLU Farm and Agriculture F! Standard Business I-IHAZARDOUS HATERTALS 1' NVENTORY NON--TRADE SECRETS Page 1 'BUSINESS NAME: BAK~.R SA.ND CONTROT. OWNER NAME: BAKER SAl~TD CONTROL NAHE OF THIS FACILITY: SOUTH CHEM'rCAL ~-~SE BAKERSFIELD.. CA 93313 UI./Y. ZtH: .OUS'£ON. TX' 77208 '- DUN AND UliAOS/flkE/ NUMBkR ..... PHONE #: gQS-ggA-?R/,~,_. ' R~ER P ONE #',7,O__.ZNSFT3~--U~"~_FOR_7~ROPER----/-1-3= 5~ CODES .... 09_ - 3.57 - Z3Z7 !r'elns !ylle .~a.x AvfrpDe Annual Heasure IsitOYSe [;ont Gont Cont Us9 Location. Nhe~:e. ?Yt Names of ,ixture/Cee,onents /ype ~ress Tamp Coue See Instructions Stored In facility ,~oae cone xmt xmt Est Units on Physical and Health Hazard C,A,S. Number Component Il Name I C.A,S. Number ICheck ali that apply) FI Fire Hazard El Reactivity I-1 Delayed [:3 Sudden Release ~ immediate Component 12 Name I C.A.S. Number Health of Pressure Health ' '~' ' ' Component 13 Name I C.A,S, Number Physical end Health Hazard C,A.S. Number Component II Name & C,A.S. Number ICheck all that apply) 1309-48-4 Component 12 Name I C,A,S, Number FI Fire Hazard FI Reactivity FI Oelayed [] Sudden Release I-1 Imm..edi.a~e 9004-32-4 Hem Ith of PressureHealth .... Component 13 Name I C,A.S, Humber B ,1 ' 0 } 0 CHEMICAL PT,TTGgAT, Physical end Heslth Hazard C.A.S. Number Component II Name ~ C,A.S, Number ICheck ali that apply| Component 12 Name ~ C,A.$. Number FI Fire Hazard Fl Reactivity Fl Oelayed [] Sudden Release FI ]mm.edi.~.t.e Hem }th of Pressure Healc~ Component ~3 Name ~ C.A,S. Number Physical ~nd Health IJalard C.A,S, Number Component II Hame & C.A,S, Number (Cfleck 811 that apply} Component 12 Name & C.A.S. Number FI Fire Hazard F! Reactivity FI Oelayed [] Sudden Release [] ]'mm..edi.a.t.e Hem/th of Pressure Healtfl Component 13 Name I C.A.S, Number EMERGENCY COHTACTS #1 CRAIG PARKER%l~]T--'Iq~Ffq~-~e'DI~~284ZF #2NBOB~ USHER FIELD SUPERVISOR 834-284'4 aame . TITle ferti[iatioq .(Re~¢t an.d.~ign afl, pr compl~f:.fpg.¢lll sect;ions.) .ceqc~fy ufloer penalty of.~aW thqc l navepe~'sona/fy examln~qaQm ramil~a~'.vi~!] the ~n~o~'mac.Ipn ~ul~mitt.e~l in this.~nd all suoml Lteoa L~acned .d~cvmen,.s,, ntor ma t, ona°~,, t.ha,true,OaSeOaccurate,Ofl, my anolnqulr ¥comp/ete. ,f. those , no, v ,oua/s r espons, Die. ,or obta,n ,nD toe ,fl,ormat,on. , bel ,eve that th~.~._~ CRAIG PA~LKER/DISTRICT ~AGER R~Fi~iai [i[i~ of owneriop~ratOP uN owneriope~atof;s authorized r~pt~s~ntattve signature Ol[~T~neQ --'- CiTY of' BAKEH SFIELD HAZARDOUS MATERIALS INVENTORY Farm and Agriculture [] Standard Business [] NON--TRADE SECRETS PaDe I of' 1 USINESSNAME: BAKER SAND CONTROL OWNER NAME: BAKER SAND CONTROL NAME OF THIS FACILITY: WEST SAND WHSE 0CATION; 5551ALDR~N CT. 'ADDRESS: ]O--~'T-~--RA--~-~NRD--'~"~--- STANDARD IND. CLASS CODE'~4'-- CIIY. ZIP: RAW~RgFT~TB ~A q"~q' CITY. ZIP:-~STON. TX -$?0R ..... DUN AND BRADSTREEI NUMBE~ CodeTr'ans coue!Yqe Amt~ax AvtrpgeAmc AnnualEst HeasUreUfl~ts onlsmt~Y~e .[ypeG°nt PressG°nt Contiemp UScole tocation.Whece. , ?YL NameS.,se~Of vixture/Ceeoonefltstnstru:tt°fls Y \ Stored tn Paci/icy Physical(check ,llandthatHealthapply]Hazard C.A.S. Number 68055-54-9 Component 11 Hame, C.A.S. Humber / "Fire Hazard "Reactivity "Delayed "Sudan Release ~ ,m,~j~ Component ,2 Name I C.A..S. Number / I Heath of Pressure.ea~n Component 13 Name I C.A.S. Number Physical and ~ealth Hazard ~.A.S. ~ueber 14808-60-7 Component II ~a~e I :.A.S. ~u~ber / ~ ICheck all that appl~)/ ... Coeponen: tE Name I C,A.S. Number D Fire Hazard D Remctivity ~ Delayed U Sudden Release ~ lmm~di~[e Health of Pressure Health Component 13 Name I C.A.S. Number Physical arid pealth Hazard C,l.S, Number Component Il Name I C,A,S, Number ICheck all that apply) Component 12 Name I C,k,S. Number ~ Fire Hazard ~ Reactivity ~ Belayed ~ Sudden Release ~ Hearth of PressureHealth ....... Component 13 Name I C.A,S. Number Physical and Health ~a~ard C,A,S, Number Coaponent II Name I C,A,S, Number (Check 411 that app/yl Component I~ Name & C.A.S. Number D Fire Hazard ~ Reactivity ~ ~layed ~ Sudden Release ~ ]'mmedi.at~ ~a/th of Pressure Health Component 13 Name ~ C.A.S. Humber EMERGENCY CONTACTS fllRameC~IG PARKER " ~~~4. Hfg3A-28aA~one f12~ ITRMER ertifigatioq ,(Re~ an~.~f~n af~pr compleCfpg,all .cer~)Ly.unoer penalty olU~ that l navepe(sonajQ, examln~tqolm ~miJ)aLyitb ~e )ntormaupn fubmittpd in this. Qnd ail . at~acneo.oOc~meflt~, mnl t~c omseQ on.my Inquiry 9Ltnose InOIVlOUams responsible for obtmlnin9 the Information, I believe that ~e/ CRIAG PARKER/DISTRICT ~AGER ~~ri~fal titi~ of o~n~rioperator u~ owner~operator:S-authorized repr~e~tative *Vo es Too Small to Inventory SAND CONTROL BAKER OIL TOOLS COMPANY 5551 ALDRIN COURT BAKERSFIELD, CALIFORNIA 93813 TELEPHONE: (805) 834-2844 3anuary 5, 1989 CHEMICAL INVENTORY MAX ANNUAL HAZARD AMOUNT AMOUNT UNIT CHEMICAL CODE D.O.T. 55 55 GAL Magna All4/Aromatic Petro FLLQ 1993 Solvent 55 55 GAL A-lOO/Cronox 265/Isopropanol FLLQ 1993 55 55 GAL S-90 Ethyleneglycol Monobutyl FLLQ 1993 Ether 430 1,800 GAL Liquefied Petroleum Gas FLGS 1075 (Propane) 300 1,000 GAL Waste 0il (NA 9189) FLLQ 1270 550 1,000 GAL Hotor 0il, Hydraulic 0il FLLQ 1270 5,000 20,000 LBS Ammonium Chloride ORMA 9085 1,000 5,000 LBS Sulfamic Acid CRMT NONE 300 1,200 LBS Sodium Hydroxide, Bead CRMT 1823 I J 55 55 GAL Formic Acid CRMT 1779 I ~.| 25 400 GAL Defoamer CRMT 1760 150 150 GAL W-315 Zirconium Oxychloride CRMT 1760 1,000 8,000 GAL Hydro Chloric Acid CRMT 1789 I 55 55 GAL Boicide/Glutaraldehyde ORMA NONE 420 420 GAL Union Carbide Ucar 310/Amine/ ORMA NONE Glycol 30,000 200,000 LBS Potassium Chloride NONE NONE I 100 100 LBS Magnesium Oxide NONE NONE 10,000 35,000 LBS Hydroxethyl Cellulose NONE NONE 3,000 3,000 LBS Soda Ash NONE NONE 300 500 TON Cystalline Silica NONE NONE MATERIAi~AFETY DATA SHEET PRODUCT NALOD ASP-166 OIL C~,TFR NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION I PRODUCT IDENTIFICATION TRADE N~LME: ~~~: A bl~ of ~1 ~A 70~ ~i~fi~ l~li~t 2~~ SECTION 2 ~~US ING~DIE~S ~ ~Z~ ~ti~ of ~m~ti~ ~e, 29 ~~(s) ~~. ~ECTION 3 P~C~UTION~RY ~BEL INFO~TION W~: or ~ clX. ~.g~l~ or fa~ ~d ~ ~~. A~id p~lo~ or ~~ b~~ of ~r. U~ wi~ ad~ v~tilati~. ~ p~ly ~tio~. ~ECTION 4 FIRST AID INFO~TION ~ ~ ~ for 15 ~. ~1 a ~.ici~. ~: ~vi~ ~i~ of ~~ ~1 ~ ~ cl~ ~~. ~~: If ~i~, ~ ~le ~~ or ~ ~s~, ~ ~ ~ ~~ or give ~. SECTION ~ HEALTH EFFECTS INFO~TION ~ ~(S) OF ~ ~: ~y ~ ~i~ti~ ~ ~1~ ~~. ~ OF P~ 1 OF 6 I MATERIAL~AFETY DATA SHEET % PRODU ,,- ~,.gP-166 o"ri, NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION $ HEALTH EFFECTS INFORMATION ( CONTINUED ) AGGRAVATIQ~ OF ~ OC~D~: A review of available data does not identify any worsen~ of existir~ condign. SECTION 6 TOXICOLOGY INFORMATION SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Clear oolorless P~M: Liquid ODOR: Sweet DENSITY: 8.4 lbs/gal. SOI[3BILITY IN ~%TER: ~luble S~C GRAVITY: 1.01 @ 60 Degrees F VISOCSITY: 128 cps/127 cts/588 SUS @ 60 Dec3rees F AS']~ D-445 ~ POINT: Less than -20 Degrees F ~ D-97 ~ POINT: 157-Do~rees F (a~CC) ASm D-93 BY W~IG~T: Z @ 75 Decjre~ F SECTION S FXRE AND EXPLOSION INFO~TION FiAS~ POINT: 157 Degrees F (PMOC) ~ D-93 alcohol foam, carbon dioxide or other ext/n~g~ agent suitable for Class B fires. Use water to cool cc~cainezs exposed to fire. For large fires, use water spzay or fog, thu~y ~ the burning BECTION 9 REACTIVITY INFORMATION peroxi~, chroma~, nitric acid, perchlorates, concentrated oxygen, $~m~r~nates) which can generate heat, fires, explosions and the rel-~-~ of tox/c fumes. may be formed. Do not breathe m~ke or fumes. Wear suie~_le protective equi~nt. PAGE 2OF 6 MATERIAi AFETY DATA SHEET IPRODUCT AS[:'-166 OIL GELT. Z:R NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 10 PERSONAL PROTECTION EQUIPMENT r==ded. If significant mists or ~ls are general, w~ar a NIOSH apgroved or equ/valerfc respirator, (A~I Z 88.2, 1980 for l~qu/r~ments I~OTECTIVE E~IPHENT: Use ~le glc~es ar~ chemical ~plash goggles (ANSI Z 87.1 rec~'~eme~ts ar~ selectic~ of gloves, goggles, If clc~r~ is oontam/nat~__, remove clothing ar~ ~y w~-~h the affected area. Laura_er ~ted clothing before reuse. Discard SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF ~PO~/(IN ~, CA~L ~ 1~O~ 24-I~Y~R (3 20-1510) ~11 liquid spills: Contain with ~ mater~al, such as Saw dust, clay, soil or any ~_rc~l]y available ~t. Shovel reclaimed liquid ar~ abso~ into recovery or salvage drums for in Sec~/c~ 14. DISPOSAL: If this ~-~uct ~ & %~ce, it does r~t meet the cri~ of a hazardous waste as defined u~_er the l~mouroe O~senmtic~ and Reoovery Act f~mA) 40 CFR 261, since it does not have the chara~~cs of ~ ¢, (i.e. D001 thr~ _~h D017) ~or is it . listed under ~ D. As a r~n-hazardous liquid waste, it should be solidifisd before ~ ~ to a sanitary la=Ifil1. Can be incited in accordance with local, state and federal recjulati~. ~ 30F 6 NALCO CHEMICAL COMPANY ONE N,~I r,O CENTER · N~P~RVI[.I.~ I! ~ IN¢-~t~ ~_,1c~.~4 MATERIA SAFETY DATA SHEET PRODUCT · NALCO ASP-166 OIL C~T.'rFR NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) IIII SECTION 12 ENVIRONMENT/%L INFORMATION If rel~ into the envJ/x21ment, see CERCIA in Sectic~ 14. SECTION 13 TPJ%NSPORTATION INFORMATION DOT PR0~ SHIPPING }[~2tRD OODE - ~ LIQUID, N.O.S. NA 1993 SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. (M~{A'S HAZARD OC~4MUNICATI~ ~JLE, 29 CFR 1910.1200: _~ on our hazard evaluation, none of the ingredients in this product CERCIA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. TOXIC SUBSTANCES OONTROL ACT (TSCA): (40 71o). ~ C~~ AND R~ ~"r (Rf~), 40 CFR 261 SUBPA~r C & D: If this product beo~m~ a waste, it does not meet th~ criteria of a FEDERAL ~ POI/XrrI(N~ (IN~3L ACT, ~ ~TER ACT, 40 CFR 401.15 (for~-rly Sec. 307), 40 CFR 116 (fo~ae~_rly Sec. 311): None of the ~ents are s~ecifically listed. CLEAN AIR ACT, 40 CFR 60, S~'TI~ 111, 40 CFR 61, SECTIC~ 112: Critical Materials Re~. P~GE 4OF 6 MATERIAI~SAFETY DATA SHEET PRODUCT NALCO Emergency Telephone Number Medical (312) 920-1510(24 hours) BECTZON 1S ~,DDZTZON~L ZNFOI?.K,~TZON ~'~ . . BECTZON 16 UBER~ RESPONBZBZLZTY cur ~ li~~. ~vi~s ~ECTZO~ ~7 BZBLZOG~PHY ~l~c ~ ~~, ~ 33-~35855, 1983. N. Y., ~ ~~, 1980. ' ~~ ~ OF ~ ~, ~r, N. H., J. P. ~p~ ~, N.Y., 1981. ~ ~~'f,~ OF ~ N~ ~ld ~, N.Y., 6~ ~ti~, 1984. ~ ~ ~ ~ ~~ OF ~ ~ ~, 1972-~77. P~'S ~~~~~~, ~~, G. D., ~a~, F. ;., ~1, Nati~ ~i~ f~ ~~ ~e~ ~ ~, ~83 MATERIA[~SAFETY DATA SHEET , PRODUCT ~ ASP--166 OIL ~,T FR NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) 8ECTZON 17 BZBL/OGI~PHY ( CONTTNUED ) Gov~,.,.~-Wal ~ial I~ut~, C[-I. Z~TE ~: lO/23/85 mu'E ~THT]a): o9/19/86 PAGE 60F 6 Do he~eb~~ oer~ity that [ h~ve ~evie~,'ed the attached Hazardous ~!aterials business ~lan (name of business) and that it along with the attached additions em~ corrections consti~u~e ~o complete and correct Business Plan for mM facilit.v. ' si~na%ure date BUSINESS NAME BAKER SAND CONI'ROL ID NUMBER LOCATION SS~I ALDRIN CT HIGH HAZARD RATING 3 1. OVERVIEW LAST CHANGE O?/18/88 BY ESTER JURIS CODE 215-OO9 JURIS BAKERSFIELD STATION 09 MAP PAGE 123 GRiD 1SO FACILITY UNITS 1 HAZARD RATING ~ RESPONSE SUMMARY ~A SEC 4: EVERYONE fit FACILITY IS TRfllNEO. WE HAVE CLEAN UP EQUIPMENT RT FACILITY; PILLOWS, DRY ABSORBENT, SAFETY GEAR, ECT. WE HAVE AN EMPLOYEE RESPONSE TEAM. EMERGENCY CONTFtCTS ZA SEC 2: DON B. COBB, DISTRICT MANAGER - 834'-Z844 OR 833-9784 CRAIG PARKER, FIELD SUPERVISOR 834-2844 OR 835-9056 UTILITY SHUTOFFS ZR SEC 5: A~NAT. GAS - N CENTER; PROPANE TANK SE B) ELECTRICAL N CENTER; C) WATER - N CENTER; D) SPECIAL.- NONE; E) LOCK BOX - NO, 2. NOTIFICATION / PUBLIC EVACUATION LAST CHANGE / / BY To the North, West and'South of our establishment the businesses stay under the same name, however, to the East and Southwest, the businesses have changed during time. I have informed Craig Parker and sever&l other key people as to the need Of a public evacuation plan. We plan to verbally, in person, n6tify/our neighbors in the case of a threatening hazardous materials release. PAGE 1 12/28/88 11:44 MATERIAL. SAFETY DATA SYSTEMS, INC. (805) 648-G80~ BUSINESS NAME BAKER SAND CONTROL ID NUMBER 21S-~00-(~?S9 LDC6TION 5551ALDRIN Cl' HIGH HAZARD RATING 3. HAZ MAT TRAINING SUMM~RY LAST CHANGE / / BY We are in compliance with OSHA CFR1910.1200o We do have and use a hazardous commun,ication program._ There are monthly safety meetings in Which various hazardous meterials are always discussed. 4. LOCAL EMERGENCY MEDICAL ASSISTANCE LAST CHANGE (~6/Ml/88 BY TERRY SEC S: WE HAVE EYE WASH. SHOWER AND SMALL MEOICAL KIT ON HRND. WHITE LANE MEDICAL CENTER - 54~1 WHITE LANE - 832-Z(~ J MEMORIAL HOSPITAL - 420 34TH STREET - 327-179~ PAGE 2 12t28/88 ll:q4 MATERIAL SAFETY DRT~ SYSTEMS, INC. (805) 648-680~ CITY of BAKERSFIELD NON--'I?RADE SECRETS , ~ 1 of 2 BUSINESS NAME: BAKER SAND CONTROL 0k'NER NAHE: B~ER S~D CONTROL HAMg OF T~S FACILITY': NORTH EAST ~SE LOCATION: ~-'~~ .... ADDRESS: 1010 ~KIN RD/P.~-'~X 61486 STANDARD IND. CLASS CODE CITY, ZIP: B~ERSFIELD~ CA 93309 C~TY, ZXP: HOUSTON, TX 77208 DUS AND BRADSTRgET NUNBER PHOSE ": (805)824-2844 P~O~E e: (71~)443-1590 0~_ - 357 - 7377 (~ C~ ~ ~ Est ~its~ Site 1~ ~ T~ ~ St~ tn F~tltty~ ~ I~t~ti~ ~__l.~._J 3oo ] 200 l, 600 .G~ 3~ 13 i 26~~E. _~. :~O~O,R QYL~ .... P~ic~l ~ ~lth ~d C.l.S. ~ ~t II ~ ~ C.A.S. ~ IC~i all t~t ~ly) . ~ ....... ~-~ r-~ r-~ ~t~ ~&C.A.S.~ of P~ ~lth ~.-L~-J...~.~ .... J...~ ........ 1 200JGA~I365 1 13 '1 1 I 4 t 26 INo~r~ EAST ~SE. 100 HYD~IC OIL ~ r-~ r-~ ~] ~t ~ ~ i C.A.S. ~ · .f ~ ~l~h ' " .~_~'[ 100 [ 50 i 200 _IGAL~ 3fi~ } 13 I .1_.I 4 i 26 ~NORTH EAST ~SE. ~,. 99,T,~S}J~S~O~ FLOID k lil tMt Mly) i J i ..... [' J~J I .... , ......... ~ I I . (C~k iI1 t~t rely) ~t12 ~&C.A.S.~ Mlth of P~q ~)th '-- ......... ~t I] M&C.A.S. ~ -~E~Y ~T~/S I~ DON COBB DISTRICT ~NAGER 834-2844 ~ C~IG PA~ER FIELD supERVIsoR 834-2844 ~': ......................... ; ....... .fli ..................... ?l'Rr~ a .tli ~ ...... C~ttficeti~ (Read and sJ~ after coepletJng aJJ sections/ ,o. o..,.,. ,.,,_,.,,...,,,.,.,_,,..,_.._,._,.... I~a' ~8' Gtll~lil'tlili'iT'~~i~'~-~;~;~G;'i'~[~ii~ti~l~ StihTO;;' ' ......................... MATERIAL SAFETY PENNZOIL PRODUCTS DATA SHEET Manufacturer's Name PERIL ~ CAS Num~: MSDS C~e: ooo3~ Address P,O. ~ 8~ NFPA Hazard Identificati~ OIL C~ PE~YLV~A 16301~ D~r~ of Hazard Hazard Ratings 0 - Least Health: Z 1 - Slight Fire: I 2 - M~erate 3 - High Emergency Telephone No. { 713 ) ~6-60~ ReactiviW: o 4 - Extreme Trade Name PE~OIL L~ LIFE ~OR OIL ~ ~ Synonyms PE~LE~ L~C~. COMPONENT NAME H~RDOUS pERCENTAGE COMPONENT CAS NUMBER IN BLEND MIN M~ ~POSURE LIMITS UNITS ~SE LUBRICATING OZ~ OS~ PEL NO LZHZT MZ~RE ~ 8S.00 TO 95.00 ACGZH TLV ~ LIMIT P~R ~l~ DEPRESS~ OS~ PEL NO LINZT PROPRZET~Y ~ ¢ ~.00 ACGZH TLV OI~CL~IHER OF THE INFORMATION CONTAINED HEREIN IS BASED UPON DATA AVAILABLE TO US, AND REFLECTS OUR BEST PROFESSIONAL JUDGEMENT. HOWEVER, NO WARRANT~ OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY OTHER WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF SUCH DATA, THE RESULTS TO BE OBTAINED FROM THE USE THEREOF, OR THAT ANY SUCH USE DOES NOT INFRINGE ANY PATENT. SINCE THEINFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS OF USE BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR, WE DO NOT ASSUME ANY RESPONSIBILITY FOR THE RESULTS OF SUCH APPLICATION. THIS INFORMATION IS FURNISHED UPON THE CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR PURPOSE. REQUIRED UNDER USDL SAFETY AND HEALTH REGULATIONS FOR SHIP REPAIRING, SHIPBUILDING, AND SHIPBREAKING (29 CFR 19~5, 1916~ 1917). EYE CONTACT THIS PRODUCT ZS PRACTZCALLY NON-ZRRZTATZNG TO THE EYES UPON DIRECT CONTACT. SKIN CONTACT AVOID SKIN CONTACT. THIS PRODUCT HAS NOT BEEN TESTED FOR ACUTE DERNAL EFFECTS. THIS PRODUCT IS EXPECTED TO BE PRACTICALLY NON-TRRTTATZNG UPON DZRECT CONTACT. PROLONGED OR REPEATED CONTACT HAY RESULT ZN CONTACT DERHATZTZS NHZCH ZS CHARACTERIZED BY DRYNESS, : CHApp:TNG, AHD REDDENTNG. THTS COHDITION NAY HAKE THE SKTN NORE SUSCEPTIBLE TO OTHER ZRRTTAHTS, SENSITIZERS, AND DISEASE. PRoLor~ED OR REPEATED CONTACT HAY RESULT IN OTL ACNE NHICH IS CHARACTERTZED BY BLACKHEADS ~ITH POSSIBLE SECONDARY TNFECTION. ALLERGIC DERHATTTZS, USUALLY PRECEDED BY CONTACT DERMATITIS, NAY OCCUR AND SPREAD BEYOND AREAS OF DZRECT CONTACT. CONSTZTUENTS OF THZS PRODUCT HAVE BEEN ASSOCZATED NZTH PHOTOSENSZTZVZTY/. AN ABNORHAL SENSZTZVZTY OF SKIN TO SUNLZGHT. INHALATION THIS PRODUCT HAS A LON VAPOR PRESSURE AND IS NOT EXPECTED TO PRESENT AN INHALATION HAZARD AT AMBIENT CONDZTZONS. CAUTZON SHOULD BE TAKEN TO PREVENT AEROSOLZZATZON OR NZSTING OF THIS PRODUCT. THE PERHTSSABLE EXPOSURE LIMIT (PEL) AND THRESHOLD LIMIT VALUE (TLV) FOR THIS PRODUCT AS OIL HIST IS S NC/N3. EXPOSURES BELON $ NC/N3 APPEAR TO SE NITHOUT SIGNIFZCANT HEALTH RISK. INGESTION OD NOT ZNGEST. INGESTION IS REIATZVELY NON-TOXIC UNLESS ASPZRATZON OCCURS, THZS PRODUCT HAS LAXATIVE PROPERTIES AND HAY RESULT IN ABDOMINAL CRAMPS AND DZARRHEA. SEE HEALTH DATA SECTZON BELON. HEALTH DATA ON RARE OCCASIONS, PROLONGED AND REPEATED EXPOSURE TO OIL NZST POSES A RISK OF PULHONARY DISEASE SUCH AS CHRONIC LUNG ZNFL.AHHATZON. THZS CONDITZON ZS USUALLY ASYMPTOHATIC AS A RESULT OF REPEATED SNALL ASPZRATZONS. SHORTNESS OF BREATH AND COUGH ARE THE HOST CONHON SYHPTOHS. ASPZRATZON NAY LEAD TO CHENZCAL PNEUHONZTZS NHZCH ZS CHARACTERZZED BY PUL.HONARY EDEHA AND HEHORRHAGE, AND HAY BE FATAL. SZGNS OF LUNG INVOLVEMENT ZNCLUDE ZNCREASED RESPZRATZON RATE, ZNCREASED HEART RATE, AND A BLUZSN DZSCOLORATION OF THE SKZN. COUGHZNG, CHOKING, AND GAGGZNG ARE OFTEN NOTED AT THE TINE OF ASPIRATZON. GASTROZNTESTINAL DZSCOHFORT NAY DEVELOP, FOLLONED BY VOHZTTZNG, HZTH A FURTHER RZSK OF ASPZRATION. THZS PRODUCT CONTAINS ZINC DIALKYLDZTHZOPHOSPHATE (ZDDP). REPEATED AND PROLONGED DERNAL APPLZCATZON OF ZDDP TO THE SKIN OF LABORATORY RABSZTS RESULTED ZN SEVERE SKZN ZRRZTATZON, REDUCED FOOD ZNTAKE, AND SUBSTANTZAL HEIGHT LOSS. TESTZCULAR ATROPHY NAS OBSERVED IN THESE ANZNALS. THESE REACTZONS ARE SZHIL.AR TO THOSE EXPECTED BY REPEATED APPLICATZOH OF ANY CORROSZVE CHENZCAL. ZDDP HAS ALSO BEEN POUND TO BE HUTAGENZC IN A FEN SUBHANMALZAN TESTS. THE ACTZVIT¥ HAS BEEN ASCRIBED TO THE ZZNC COHPONENT, AN ESSENTIAL NUTRIENT FOR HUHANS. ZT ZS NOT SUSPECTED AS POSSESSZNG NUTAGENZC OR CARCINOGENIC ACTIVZTY ZN HUMANS AT LON LEVELS. ZDDP, ATT HE CONCENTRATIONS PRESENT IN THZS HZXTURE, ZS NZTHOUT SZGNIFZCANT RISK. EYE CONTACT THHED1'ATEI,,Y FLUSH EYES HZ'TH LARGE AHOUNTS OF tdATER AND CONTTNUE FLUSHTNG FOR 1,~ NZNUTESo TF HATER'rAt. 'rs HOT, TREAT FOR THERHAL BURNS AND TAKE V'rCTTH TO HOSp'rTAI- I'NHEDZATELY. REHOVE CONTAHZNATED CLOTH'rNG. NASH CONTAHZNATED AREA THOROUGHLY I4'rTH SOAP AND t,/ATER. ZF SKIN CONTACT NATER'rAL 'rS HOT, SUBHERGE TN, lURED AREA 'rN COLD NATER. 'rF VZCTZN ZS SEVERELY BURNED, RENOVE TO A HOSPZTAL 'rNNED'rATELY. TH'rS HATER'rAL HAS A LON VAPOR PREBBURE AND 'rS NOT EXPECTED TO PRESENT AN 'rNHALAT'rON INHALATION EXPOSURE AT AHB'rENT COND'rT.rONS. 'rF VAPOR OR N'tST 'rs GENERATED NHEN THE NATER'rAL 'rS HEATED OR HANDLED, REHOVE VZCT'rN FRON EXPOSURE. 'rF BREATHZNG HAS STOPPED OR 'rS TRREGULAR, ADN'rN'rSTER ART'rF'rC'rAL RESP'rRAT'rON AND SUPPLY OXYGEN 'rF 'rT 'rS AVA'rLABLEo 'rF VZCT'rN UNCONSC'rOUS, RENOVE TO FRESH A'rR AND SEEK NED'rCAL AI'TENT'rON. DO NOT 'rNDUCE VONZT'rNG. SEEK NED'rCAL AT"rENT'rON. INGESTION EYE EYE PROTECTZON ZS NOT RE(~II'RED UNDER CONDZTZONS OF NORMAL USE. ZF MATER3:AL ZS HANDLED SUCH PROTECTION THAT ZT COU~ BE SP~SHED Z~O EYES, NE~ P~STZC FACE SHZELD OR SP~SH*PR~F SAFE~ G~GLES. SKIN NO SKTN PROTECTZON ZS REQUZRED FOR SZNGLE, SHORT DURATZON EXPOSURES. FOR PROLONGED OR PROTECTION REPEATED EXPOSURES~ USE ZHPERVZOUS SYNTHETZC RUBBER CLOTHI'MG (BOOTS,, GLOVES, APRONS, ETC. ) OVER PARTS OF' THE BODY SUBJECT TO EXPOSURE. 'rF HANDL3:NG HOT HATER'rAL, USE ZNSUI. ATED PROTECTZVE CLOTHZNG (BOOTS, GLOVES, APRONS, ETC. ). RESPIRATOR. RESPZRATORY PROTECTZON ZS NOT REQUZRED UNDER CONDZTZONS OF NORMAL USE. ZF VAPOR OR MZST Z~ PROTECTION GENERATED HHEN THE HATERTAL ZS HEATED OR HANDLED, USE AN ORGANZC VAPOR RESp'rRATOR NZTH A DUST AND N'rST FZLTER. ALL RESPZRATORS MUST BE NZOSH CERTZF'rED. DO NOT USE COMPRESSED OXYGEN 'tN HYDROCARBON ATHOSPHERE$. VENTILATION ZF VAPOR OR NZST Z$ GENERATED t,/HENTHE NATERZAL Z$ HEATED OR HANDLED, ADEQUATE VENTZLATZON ZN ACCORDANCE NZTH GOOD ENGZNEERZNG PRACTZCE MUST BE PROVZDED TO MAZNTAZN CONCENTRATZONS BELON THE SPECZFZED EXPOSURE OR FLAHMABLE LZMZTS. OTHER CONSUHPTZON OF FOOD AND BEVERAGE SHOULD BE AVOZDED ZN WORK AREAS t/HERE HYDROCARBONS ARE PRESENT. ALHAYS HASH HANDS AND FACE HZ'IH SOAP AND HATER BEFORE EATZNG, DRZNKZNG, OR SMOKZNG. FLASH POINT 42oF TEST METHOD c.o.c. AUTOIGNITION TEMPERATURE · 9ooF " TEST METHOD NO DATA FLAMMABLE LIMITS IN AIR % BY VOL LOWER NO DATA UPPER NO DATA EXTINGUISHING USE DRY CHENZCAL, FOAN, OR CARBON DZOXZDE. MEDIA SPECIAL FIRE NATER HAY BE ZNEFFECTTVE BUT CAN BE USED TO COOL CONTAZNERS EXPOSED TO HEAT OR FLAHE. CAUTZON SHOULD BE EXERCZSED NHEN Us:~NG NATER OR FOAN AS FROTHTNG HAY OCCUR, ESPECTALt¥ ZF FIGHTING SPRAYED ZNTO CONTAINERS OF HOT, BURN:ZNG L.Z~UZD. PROCEDURES UNUSUAL FIRE DENSE SHOKE HAY BE GENERATED NHTLE BURNZNG. CARBON HONOXZDE~, GARBON DZOXZDE, AND OTHER AND EXPLOSIVE OXZDES NAY BE GENERATED AS PRODUCTS OF COHBUSTZON. CONDITIONS ~ ...... .............. ri'~i'~'~ .... ~;'?~" /~'~"Y*~ r~'~i''~ ......... ~ ..... '~ ~'~'~''~'i''~' ~*~ ~ir"~' "[ ~' ~';~"~'~'~"~'hi~' ~"~ ................. ~' ""~"~'" ......... ~ ..... STABILITY (THERMAI~ ~I'ABLE CONDITIONS TO NO~E LIGHT, ETC.) AVOID HAZARDOUS WZLL NOT OCCUR CONDITIONS TO NON£ POLYMERIZATION AVOID INCOMPATIBILITY NAY REACT WZTPI STRONG OXXDXZXNG AGENTS. MATERIALS TO AVOID HAZARDOUS DECOMPOSITION NONE PRODUCTS STEPS TO BE CONSULT HEALTH EFFECT TNFORMATZON ZN SECTTON ZZT, PERSONAL HEALTH PROTECTZON ZNFORMATTON TAKEN IF TN SECTTON V, FZRE PROTECTZON ZNFORMATTON TN SECTTON VZ, AND REACTZVZTY DATA TN SECTZON VZZ. NOTTFy APPROPRZATE AUTHORTTTES OF SPZLL. CONTAZN SPZLL ZHMEDZATELY. DO NOT ALLO~ MATERIAL IS SPZLL TO ENTER SENERS OR NATERCOURSES. REMOVE ALL SOURCES OF ZGNZT'rON. ABSORB t/ZTH RELEASED OR APPROPRZATE ZNERT MATERTAL SUCH AS SAND, CLAY, ETC.. LARGE SPZLL~ MAY BE PZCKED UP USZNG VACUUM PUMPS, SHOVEI..~, BUCKETS, OR OTHER MEANS AND PLACED I'N DRUMS OR OTHER SUTTABLE SPILLED CONTAZNERS. / , WASTE DISPOSAL ALL DZSPOSALS MUST COMPLY NZTH FEDERAL, STATE, AND LOCAL REGUIATTONSo THE NATERZAL, ZF METHOD SPZLLED OR DZSCARDED, NAY BE A REGULATED t/ASTE. REFER TO STATE AND LOCAL REGUIATZONS. CAUTZON! 'rF REGULATED SOLVENTS ARE USED TO CLEAN UP SPZLLED HATERZAL, THE RESULTTNG t/ASTE N'rXTURE HAY SE REGULATED. DEPARTHENT OF TRANSPORTATTON (DOT) REGUIATTONS NAY APPLY FOR TRANSPORTZNG THZS NATERZAL t/HEN SPTLLED. t/ASTE MATERTAL NAY BE LANDFZLLED OR ZNCZNERATED AT AN APPROVED FACZLZTY. NATERZALS SHOULD BE RECYCLED ZF POSSZBLE. HANDLING AND DO NOT 'TRANSFER TO UNMARKED CONTAZNERS. STORE 'tN CLOSED CONTA'rNERS At/AY FROH HEAT, SPARKS, STORAGE OPEN FLAME, OR OXZDTZZNG NATER'rALS. TH'rS PRODUCT ZS NOT CLASSZFZED AS HAZARDOUS UNDER DOT REGUIATZONS. FTRE EXTTNGUTSHERS SHOULD BE KEPT READZLY AVA'rLABLE. SEE NFPA 30 AND OSHA REOUIREMENTS 1910.106--FLAMMABLE AND CONBUSTZBLE L1'QU'rDS. ADDITIONAL THZS NZXTURENAY BE FORMULATED ZN PART NZTH COHPONENTS PURCHASED FROH OTHER CONPANZES. ZN INFORMATION N.~' ZNSTANCES, ESPECZALLY t/HEN PROPRZETARY OR TRADE SECRET NATERZALS ARE USED, PENNZOZL COMPANY MUST RELY UPON THE HAZARD EVALUATZON OF SUCH COMPONENT SUBHZT"rED TO PENNZOZL BY THAT PRODUCT'S HANUFACTURER OR ZNPORTER. BOLLING POINT · 900F PERCENT VOLATILE N/A MELTING POINT + zoF VAPOR DENSITY (AIR=l) APPEARANCE OPAC~JE - RED OREEN. EVAPORATION RATE (EE=I) ODOR NZLD LUBRTCATZNG OTL. SPECIFIC GRAVITY o. VAPOR PRESSURE N/A MOLECULAR WEIGHT VA~ZES SOLUBILITY SOLUBLE ZN HYDROCARBONS. ENULSZFZES 't'N MATER. MATERIAL SAFETY PENNZOIL PRODUCTS DATA SHEET Manufacturer's Name PEI~7.0TL COHPANY CAS Number: HI--RE MSDS C~e: Address P.O. ~X 808 NFPA Hazard Identification OZL CZ~ PE~YLV~A 16301~08 Degree of Hazard Hazard Ratings 0 - Least Health: I I - Slight Fire: I 2 - M~erate 3 - High ~ergency Telephone No. 171~) ~6-6~70 Reactivi~; 4 - ~treme Trade Name PE~OZL ~ZL~ ~D~ULZC OZL ~ Synonyms PETROLE~ L~RZC~S. COMPONENT HAME HAZARDOUS PERCENTAGE COMPONENT CAS NUMBER IN BLEND MIN M~ ~POSURE LIMITS UNITS BASE LUBRZCATZNG O/L~ OSHA PEL ~ LZHZT HZ~RE ~ 95.00 TO 100.00 ACGZH TLV NO LZHZT P~R ~Z~ DEPRESSA~ ~HA PEL NO PROPRZET~Y ~ < 1.O0 ACGZH TLV DISCLAIMER OF THE INFORMATION CONTAINED HEREIN IS BASED UPON DATA AVAILABLE TO US, AND REFLECTS OUR BEST PROFESSIONAL JUDGEMENT. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY OTHER WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF SUCH DATA, THE RESULTS TO BE OBTAINED FROM THE USE THEREOF, OR THAT ANY SUCH USE DOES NOT INFRINGE ANY PATENT. SINCE THEINFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS OF USE BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR, WE DO NOT ASSUME ANY RESPONSIBILITY FOR THE RESULTS OF SUCH APPLICATION. THIS INFORMATION IS FURNISHED UPON THE CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR PURPOSE. REQUIRED UNDER USDL SAFETY AND HEALTH REGULATIONS FOR SHIP REPAIRING, SHIPBUILDING, AND SHIPBREAKING (29 CFR 1915, 1916, 1917). EYE CONTACT THZS PRODUCT ZS PRACTZCALLV MON-ZRRZTATZNQ TO THE EYES UPON DZRECT CONTACT. BASED ON TESTZNG OF SZHZLA. R PRODUCTS AND/OR COMPONENTS. SKIN CONTACT AVOZD SKZN CONTACT'. THZS PRODUC'F ZS EXPECTED TO BE PRACTZCALLY NON-ZRRZTATZNG UPON DZRECT CONTACT. BASED ON TESTZNG OF SZMZLAR PRODUCTS AND/OR COHPONEMTS. PROLONGED OR REPEATED CONTACT MAY RESULT ZN CONTACT DERHATZT~S NHZCH ZS CHARACTERZZED BY DRYNESS, CHAPPZNG, AND REDDENZNG. THZS CONDZTZON MAY MAKE THE SKZN MORE SUSCEPTZBLE TO OTHER ZRRZTANTS~ SENEZTZZERS, AND DZSEASE. PROLONGED OR, REPEATED CONTACT NAY RESULT ZN OZL ACNE WHZCH ZS CHARACTERZZED BY BLACKHEADS NZ-I'H POSSZBLE SECONDARY ZNFECTZON, CONSTZTUENTS OF THZS PRODUCT HAVE SEEN ASSOCIATED t,/ZTH PHOTOSENSZTZVZT¥', AN ABNORMAL SENSZTZVZ'T'Y OF SKZN TO SUNLZGHTo THE ZNTERNATZONAL AGENCY FOR RESEARCH ON CANCER HAS CONCLUDED THERE ZS EZTHER NO EVZDENCE OR ZNADEQUATE EVZDENCE TO XNDZCATE THZS CLASS OF PETROLEUM PRODUCTS ZS CARCZNOGENZC TO EXPERZMENTALANZHALS. INHALATION THZS PRODUCT HAS A I.ON VAPOR PRESSURE AND ZS NOT EXPECTED TO PRESENT AN ZNHALATZON HAZARD AT ANBZENT CONDZTZONS. CAUTZON SHOULD BE TAKEN TO PREVENT AEROSOLZZATZON OR HZSTZNG OF THZS PRODUCT. THE PERMZSSABLE EXPOSURE LZMZT (PEL) AND THRESHOLD LZMZT VALUE (TLV) FOR THXS PRODUCT AS OZL MZST ZS 5 MC/M3. EXPOSURES BELObI' $ MC/M3 APPEAR TO BE NZTHOUT SZGNZFZCANT HEALTH RZSK. 'THE SHORT-TERM EXPOSURE LZMZT FOR THZ$ PRODUCT AS AN OZL MZST ZS 10 MG/M3. INGESTION DO NOT ZNGEST. THZS PRODUCT' ZS RELATZVELY NON-TOXZC BY ZNGESTZON. THZS PRODUCT HAS LAXATZVE PROPERTZES AND MAY RESULT ZN ABDONZNAL CRAHPS AND DZARRMEA. SEE HEALTH DATA SECTZON BELON. HEALTH DATA ON RARE OCCASZONS, PROLONGED AND REPEATED EXPOSURE TO OZL MZST POSES A RZSK OF PULHONARY DZSEASE SUCH AS CMRONZC LUNG ZNFLAHHATZON, THZS CONDZTZON 1S USUALLY ASYMPTOMATZC AS A RESULT OF REPEATED SMALL ASPZRATIONS. SHORTNESS OF BREATH AND COUGH ARE THE HOST CONNON SYHPTOHS. ~ ~FOR GASOLZNE-ENGZNE MOTOR OZLS ONLY, AVOZD CONTACT NZTH USED MOTOR OZLS. THE INTERNATZONAL AGENCY FOR RESEARCH ON CANCER HAS DETERMINED THERE ZS SUFFZCIENT EVZDENCE THAT USED GASOLZNE-ENGZNE OZLS PRODUCE SKZN TUHORS ZN EXPERZMENTAL ANZMALS. EYE CONTACT ZMMED'rATELY FLUSH EYES W1'TH LARGE AMOUNTS OF WATER AND CONT'rNUE FLUSHI'NG UNTZL I'RRI'TATI'ON SUBSI'DES. TF NATERZAI. ZS HOT, TREAT FOR THERMAL. BURNS AND TAKE VTCT'rM TO HOSpI'TAI. 1'MM ED1'ATEI. Y. REHOVE CONTANZHATED CLO'THZNG. WASH CONTAHZNATED AREA THOROUGHLY WZTH SOAP AND WATER. ZF SKIN CONTACT MATERZAL ZS HOT, SUBNERGE ZNJURED AREA ZN COLD WATER. ZF VZCTZH ZS SEVERELY BURNED, REHOVE TO A HOSPZTAL ZMHEDZATELY. THZS HATERZAL HAS A LOW VAPOR PRESSURE AND ZS HOT EXPECTED TO PRESENT AH ZHHALATZOft INHALATION EXPOSURE AT ANBZENT CONDZTZONS. DO NOT ZNDUCE VOHZTZHG. SEEK HEDZCAL AT'rENTZON. INGESTION L~t'E EYE PROTECTZON ZS NOT REQUZRED UNDER CONOZTZONS OF NORMAL USE. ZF MATERZAL ZS HANDLED SUCH PROTECTION THAT ZT COULO BE SPLASMEO ZMTO EYES, ~/EAR PLASTZC FACE SHTELO OR SPLASH-PROOF SAFETY GOGGLES. · ~KJN NO SKZN PROTECTZON ZS RE(~JZRED FOR SZNGLE, SHORT DURATZC)fl EXPOSURES. FOR PROLONGED OR PROTECTION REPEATED EXPOSURES, USE TMPERVZOUS SYNTHE'TZC RUBBER CLOTHZNG (BOOTS, GLOVES~. APRONS, ETC. OVER PARTS OF THE BODY SUS,JECT TO EXPOSURE. ZF HANDLZNG HOT HATERZAL, USE ZNSULATED PROTECTZVE CLOTHZNG (BOOTS, GLOVES, APRONS~ ETC. ). LAUNDER SOZLED CLOTHES. PROPERLY D'rsPOSE OF CONTAHZNATED LEATHER ART'rCLES 'rHCLUDZNG SHOES, t./HZCH CANNOT BE DECONTANZNATED. RESPIRATORY RESPZRATORY PROTECTZON ZS NOT RE(~UTREO UNDER CO~IDZTZON$ OF NORMAL USE. ZF VAPOR OR MZI~I' PROTECTION GENERATED NHEN THE MATERTAL ZS HEATED OR HANDLED, USE AH ORGANZC VAPOR RESP:ZRATOR tezTH DUST AND MZST FZLTER. ALL RESPZRATOR$ MUST BE NZOSM CERTTFTED. DO NOT USE COMPRESSED OXYGEN ZN HYDROCARBON ATMOSPHERES. VENTILATION ZF VAPOR OR MZST ZS GENERATED I~HEN THE MATERZAL Z$ HEATED OR HANDLED, AOEi~LIATE VENTZLATZON ZN ACCORDANCE ~Z'I'H GOOD ENGZflEERZNG PRACTZCE MUST BE PROVZOED TO MAZHTAZH CONCENTRATZONS BELOW/ THE SPECZFZED EXPOSURE OR FI-ANMABLE LZMZTS. OTHER CONSUMPTZON OF FOOD AND BEVERAGE SHOULD BE AVOZDED ZM NORK AREAS 14HERE HYDROCARBONS ARE PRESENT. ALNAYS MASH HANDS AND FACE NZTH SOAP AND MATER BEFORE EATZNG, DRZNKZNG~ OR SNOKZNG. FLASH POINT 390P TEST METHOD c.o.c. AUTOIGNITION TEMPERATURE · aooF .~ .' TEST METHOD HO EAT~ FLAMMABLE LIMITS IN AIR % BY VOL LOWER ~o DATA UPPER ~o DATA EXTINGUISHING USE DRY CHEN]:CAL, FOAN, OR CARBON DZOXZDE. MEDIA SPECIAL FIRE NATER NAY BE ZNEFFECT]:VE BUT ~ BE USED TO COOL CONTA:I:NER$ EXPOSED TO HEAT OR PLANE. CAUTZON SHOULD BE EXERCZSED NHEN U$]:NO NATER OR FOAH AS FROTH]:NG NAY OCCUR~ ESPECZALLY IF FIGHTING SPRAYED TNTO COHTAZNERS OF HOT, BURN:I:NG LZGU:I:D. PROCEDURES UNUSUAL FIRE DENSE SHOKE NAY BE GENERATED NHZLE BURNZNG. CARBON NONOXZDE, CARBON DZOXZDE, AND OTHER AND EXPLOSIVE OXZDES HAY BE GENERATED A~ PRODUCTS OF CONBUSTTON. CON DITIONS STABILITY CONDITIONS TO (THERMAL, sT~a~ NONE LIGHT, ETC.) AVOID HAZARDOUS WZLL HOT OCCUR CONDITIONS TO NONE POLYMERIZATION AVOID INCOMPATIBILITY NAY EEACT NI'TH STRONG OXI'DTZl'NG AGENTS. MATERIALS TO AVOID HAZARDOUS DECOMPOSITION NONE PRODUCTS STEPS TO BE CONSULT HEALTH EFFECT :[NFORMAT~:ON ZN SECT:ION 'r'r:[, PERSONAL HEALTH PROTECTION INFORMATION TAKEN IF TN SECTION V, FIRE PROTECTION ZNFORMATTON ZN SECTION VI, AND REACTZVTTY DATA ZN SECTTON VIZ. NOTIFY APPROPRI'ATE AUTHORTTTES OF SPILL. CONTAZN SPILL IMMEDIATELY. DO NOT ALLON MATERIAL IS sPz-L TO ENTER SENERS OR NATERCOURSES. RENOVE ALL SOURCES OF TGNTTZON. ABSORB 18ITH ; RELEASED OR APPROPRZATE ZNERT MATERZAL SUCH AS SAND, CLAY, ETC.. LARGE SPZLLS MAY BE PZCKED UP USZNQ VACUUM PUMPS, SHOVEL~, BUCKETS, OR OTHER MEANS AND PLACED TN DRUMS OR OTHER SUZ. TABLE S PI LLED CONTATNERS · WASTE DISPOSAL ALL DISPOSALS MUtrr COMPLY N[TH FEDERAL, STATE, AND LOCAL REGULATIONS. THE MATERIAL, :CF METHOD SPZL. LED OR DZSCARDED, MAY BE A REGULATED NASTE, REFER TO STATE AND LOCAL REGUI.ATZONS. CAUTZON! ZF REGULATED SOLVENTS ARE USED TO CLEAN UP SPZLLED NATERZAL, THE RESULTZNG NASTE MIXTURE MAY BE REGULATED. DEPARTMENT OF TRANSPORTATZON(DOT) REGULATZONS HAY APPLY FOR TRANSPORTING THZS MATERZAL NHEN SPZLLED. NASTE NATERZAL HAY BE LANDFZLLED OR ZNCZNERATED AT AN APPROVED FAC1'LI'Ty. MATERZALS SHOULD SE RECYCLED ZF POSSZBLE. HANDLING AND DO NOT TRANSFER TO UNMARKED CONTAINERS. STORE 'IN CLOSED CONTAINERS AMAY FROM HEAT, SPARKS, STORAGE OPEN FI. AME, OR OXZDZZZNG MATERIALS. THZS PRODUCT ZS NOT CLASSZFZED AS HAZARDOUS UNDER DOT REGULATIONS. F~RE EXTZNGUZSHERS SHOULD BE KEPT READILY AVAILABLE. SEE NFPA ;S0 AND OSHA REQUIREMENTS ~.910.106--FLANHAELE ANO coNeusTzsie LZQUZOS. ADDITIONAL THIS MIXTURE MAY BE FORMULATED IN PART ~ZTH COMPONENTS PURCHASED FROM OTHER CONPANIES. ~N INFORMATION · MAHY INSTANCES, ESPECIALLY NHEN PROPRIETARY OR TRADE SECRET MATERIALS ARE USED, PENNZOIL COMPANY MUST RELY UPON THE HAZARO EVALUATION OF SUCH CONPONENT SUBNZTTEO TO PENNZOIL BY THAT PRODUCT'S MANUFACTURER OR IMPORTER. BOLLING POINT . SOOF PERCENT VOLATILE NO DATA MELTING POINT - 1OF VAPOR DENSITY (AIR=l) NO DATA APPEARANCE clEA~ -z~uzo. EVAPORATION RATE (EE = 1) NO DATA ODOR NEARLY OOORIESS. SPECIFIC GRAVITY o.887 VAPOR PRESSURE NO DATA MOLECULAR WEIGHT VARZES SOLUBILITY INSOLUBLE ZN NATER. SOLUBLE ZN HYDROCARBONS. r MATERIAL SAFETY PENNZOIL PRODUCTS DATA SHEET Manufacturer's Name PEYOTL C~P~ CAS Number: ~RE MSDS C~e: 000~00 Address P.O. ~x 808 NFPA Hazard Identification OIL CZ~, PE~YLV~ZA ~6~0~0808 Degr~ of Hazard Hazard Ratings 0 - Least Health: ~ 1 - Slight Fire: Z 2 - Moderate 3 - High Emergen~ Telephone No. ( 7~ } 2~6-6070 ReactiviW: 0 4 - Extreme Trade Name PE~ZL C-~ FLUZD Synonyms PETROLE~ L~RZC~. COM~NE~T NAME HAZARDOUS PERCENTAGE COMPOnEnT CAS NUMBER IN BLEND MIN M~ ~POSURE MMITS UNITS B~E LUBRICATING OZ~ OSHA PEL NO NZXTURE ~ ~S. ~0 ~ ~. ~0 ACG[H TLV NO L~[T P~R ~Z~ DEPRESSA~ O~HA PEL NO ~ZNZT PROPRZET~Y ~ · Z.O0 ACGZH TLV ~ LZHZT D~SCLA~ER OF THE INFORMATION CONTAINED HEREIN IS BASED UPON DATA AVAILABLE TO US, AND REFLECTS OUR BEST PROFESSIONAL JUDGEMENT. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY OTHER WARRANTY IS EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF SUCH DATAs THE RESULTS TO BE'OBTAINED FROM THE USE THEREOF, OR THAT ANY SUCH USE DOES NOT INFRINGE ANY PATENT. SINCE THEINFORMATION CONTAINED HEREIN MAY BE APPLIED UNDER CONDITIONS OF USE BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR, ~E DO NOT ASSUME ANY RESPONSIBILITY FOR THE RESULTS OF SUCH APPLICATION. THIS INFORMATION IS FURNISHED UPON THE CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR HIS PARTICULAR PURPOSE. REQUIRED UNDER USDL SAFETY AND HEALTH REGULATIONS FOR SHIP REPAIRING, SHIPBUILDING, AND SHIPBREAKING (29 CFR ~9~5, 19~6, MSD. S ~ODE: ooo$oo PROC ,ENNZOZL C-Z FLUXD PAGE 2 OF 6 EYE CONTACT ~ZS PRODUCT IS PRACTZCALLY HON-ZRRITATING TO THE EYES UPON DIRECT CONTACT. SKIN CONTACT AVOZD SKIN CONTACT. THZS PRODUCT HAS NOT BEEN TESTED FOR ACUTE DERMAL EFFECTS. THZS PRODUCT IS EXPECTED TO BE PRACTICALLY NON-ZRRITATING UPON DZRECT CONTACT. PROLONGED OR REPEATED COHTACT MAY RESULT IN CONTACT DERHA1CZTZS NHZCH ZS CHARACTERIZED BY DRYNESS, CHAPPING, AND REDDENING, THIS CONDITION MAY MAKE THE SKIN HORE SUSCEPTZBLE TO OTHER IRRITANTS, SENSITIZERS, AND DISEASE. PROLONGED OR REPEATED CON'TACT MAY RESULT ZN OIL ACNE NHZCH IS CHARACTERIZED BY BLACKHEADS NZTH POSSIBLE SECONDARY INFECTION. ALLERGIC DERMAT[TZS, USUALLY PRECEDED BY CONTACT DERMATITIS, MAY OCCUR AND SPREAD BEYOND AREAS OF DIRECT CONTACT. CONSTZTUENTS OF THIS PRODUCT HAVE BEEN ASSOCIATED NITH PHOTOSENSITIVITY, AN ABNORMAL SENSITIVITY OF SKIN TO SUNLIGHT. INHALATION THIS PRODUCT HAS A LON VAPOR PRESSURE AND IS NOT EXPECTED TO PRESENT AN INHALATION HAZARD AT AHBIEHT CONDITIONS. CAUTION SHOULD SE TAKEN TO PREVENT AEROSOLZZAT/ON OR MISTING OF THIS PRODUCT. THE PER]4ZSSABLE EXPOSURE LIHZT (PEL) AND THRESHOLD LIMIT VALUE (TLV) FOR THIS PRODUCT AS OZL MIST ZS $ MG/H$. EXPOSURES BELON $ HG/N~ APPEAR TO BE WITHOUT S[GNIFICANT HEALTHRIBK. iNGESTION ~o NOT INGEST. INGESTION IS RELATIVELY NON-TOXIC UNLESS ASPIRATION OCCURS. THIS PRODUCT HAS LAXATIVE PROPERTIES AND NAY RESULT ZN A~DONIHAL CRAMPS AND DIARRHEA. SEE HEALTH DATA BECTION BELON. HEALTH DATA ON RARE OCCASIONS, PROLONGED AND REPEATED EXPOSURE TO OIL HIST POSES A RISK OF PULMONARY DZSEASE SUCH AS CHRONIC LUNG ZNFLAHNATZON. THIS CONDITION ZS USUALLY ~YMPTONATZC AS A RESULT OF REPEATED SHALL. ASPIRATIONS. SHORTNESS OF BREATH AND COUGH ARE THE HOST COMMON SYNPTOHS, ASPIRATION MAY LEAD TO CHEMICAL PNEUHONITIS NHZCH IS CHARACTERIZED BY PULHONARY EDEHA AND HEMORRHAGE, AND HAY BE FATAL. SIGNS OF LUNG INVOLVEHENT INCLUDE INCREASED RESPIRATION RATE, INCREASED HEART RATE, AND A BLUISH D~SCOLORATION OF THE SKIN. COUGHING, CHOKZNG~ AND GAGGING ARE OFTEN NOTED AT THE TIME OF ASPIRATZONo GASTROZNTESTZNAL DISCOHFORT NAY DEVELOP, FOLLONED BY VOHZT'TING, NITH A FURTHER RISK OF ASPIRATZON. THIS PRODUCT CONTAINS ZINC DIALKYLDITHZOPHOSPHATE (ZDDP). REPEATED AND PROLONGED DERHAL APPLICATION OF ZDDP TO THE SKIN OF LABORATORY RABBITS RESULTED ZN SEVERE SKIN ZRRZTATION, REDUCED FOOD INTAKE, AND SUBSTANTIAL HEIGHT LOSS. TESTZCULAR ATROPHY NAS OBSERVED ZN THESE ANZNALS. THESE REACTIONS ARE SIMILAR TO THO~E EXPECTED BY REPEATED APPLICATION OF ANY CORROSIVE CHEMICAL. ZDDP HAS ALSO SEEN FOUND TO BE NUTAGENZC ZNA FEN SUBHAHHALZAN TESTS. THE ACTZVZTY HAS BEEN ASCRIBED TO THE ZINC COMPONENT, AN ESSENTZAL NUTRZENT FOR HUMANS. IT ZS NOT SUSPECTED AS POSSESSING NUTAGENZC OR CARCINOGENIC ACTIVITY IN HUMANS AT LON LEVELS. ZDDP~ AT THE CONCENTRATIONS PRESENT IN THIS HZXTURE, IS NZTHOUT BZGNIFZCANT RISK. MSDS, CODE: ooozoo PRODUC ,~PENNZOTL C-$ FLUZD PAGE 3 OF 6 EYe CONTACT ZNMEDTATELY FLUSH EYES ~IZ'TH LARGE AMOUNTS OF WATER AND CONT'rNUE FLUSNZNG FOR Z$ M"rNUTES. ~'F NATERTAL TS HOT~, TREAT FOR THERMAL BURNS AND TAKE v'rc'rl'M TO HOSpTTAL TNMEDI'ATELY. REMOVE CONTAM'rNATED CLOTH'rNG. WASH CONTAN'rNATED AREA THOROUGHLY WZTH SOAP AND WATER. ZF SKIN CONTACT NATERZAL ZS HOT, SUBMERGE ZNJURED AREA. ZN COLD WATER. ZF v'rCTZN ZS SEVERELY BURNED, REMOVE TO A HOSPZTAL ZNMEDZATELY. THZS NATERZAL HAS A ~ VAPOR PRESSURE AND ZB NOT EXPECTED TO PRESENT AN ZNNALATZON INHALATION EXPOSURE AT ANBZENTCONDZTZONS. ZF VAPOR OR MZST ZS GENERATED NHEN THE HATERZAL ZS HEATED OR HANDLED, REMOVE VZCTZN FROM EXPOSURE. ZF BREATHZNG HAS STOPPED OR ZS ZRREGUI-AR, ADMZNZSTER ARTZFZCZAL RESPZRATZON AND SUPPLY OXYGEN ZF ZT ZS AVAZLABLE. ZF VZCTZN ZB UNCONSCZOUS, REMOVE TO FRESH AZR AND SEEK NEDZCAL ATTENTZON. DO NOT ZNDUCE VONZTZNG. SEEK NEDZCAL ATTENTZON. INGESTION EYE EYE PROTECTION ZS NOT REQUIRED UNDER CONDITIONS OF NORMAL USE. ZF MATERIAL IS HANDLED SgCM PROTECTION THAT IT COULD BE SPLASHED INTO EYES, NEAR PLASTIC FACE SHIELD OR SPLASH-PROOF SAFETY GOGGLES. SKIN No SKIN PROTECTZON ZS REQUIRED FOR SINGLE, SHORT DURATION EXPOSURES. FOR PROLONGED OR PROTECTION REPEATED EXPOSURES, USE /:NPERV'rOUS SYNTHET~ZC RUBBER CL.OTHZNG (BOOTS~ GLOVES, APRONS, ETC. ) OVER PARTS OF THE BODY SUBJECT TO EXPOSURE. 'rF HANDI-ZNG I'fl~T HATER'rAL, USE 'rNSULATED PROTECTIVE CLOTHING (BOOTS, GLOVES, APRONS, ETC. ). RESPIRATOR. RESPIRATORY PROT'ECTZOfl ZS NOT REQUZRED UNDER CONDITIONS OF NORMAL USE. IF VAPOR OR MZ~T ZS PROTECTION GENERATED NNEN THE MATERIAL IS HEATED OR HANDLED, USE AN ORGANIC VAPOR RESPIRATOR NZTHA DUST AND HIST FILTER. ALL RESPIRATORS MUST BE NIOSH CERTIFIED. DO NOT USE COMPRESSED OXYGEN ZN HYDROCARBON ATHOSPHERES. VENTILATION ZF VAPOR OR MIST ZS GENERATED NHENTHE MATERIAL ZS HEATED OR HANDLED, ADEQUATE VENTILATION ZN ACCORDANCE NZTH GOOD ENGINEERING PRACTICE MUST BE PROVIDED TO MAINTAIN CONCENTRATIONS BELON THE SPECIFIED EXPOSURE OR FI-AHHABLE LZNZTSo OTHER CONSUMPTION OF FOOD AND BEVERAGE SHOULD BE AVOIDED ZN NORK AREAS t/HERE HYDROCARBONS ARE PRESENT. ALNAYS MASH HANDS AND FACE NZTH SOAP AND MATER BEFORE EATING, DRINKING, OR SMOKING. FLASH POINT 3EOF TEST METHOD c.o.c. AUTOIGNITION TEMPERATURE · aooF /, TEST METHOD ~o DATA FLAMMABLE LIMITS IN AIR % BY VOL LOWER Ho DATA UPPER No DATA EXTINGUISHING USE DRY CHEMZCAL, FOAN, OR CARSON OZOXZOE. MEDIA SPECIAL FIRE ~tATER MAY BE TNEFFECTTVE BUT CAN BE USED TO COOl. CONTATNERS EXPOSED TO HEAT OR FLAHE. CAUTZON SHOULD BE EXERCZSED NHEN USZNG 1dATER OR FOAH AS FROTHZNG HAY OCCUR, ESPECZALLY ZF FIGHTING SPRAYE~ ZNTO CONTATNERS OF HOT, BURN1'N~ LZeUTO. PROCEDURES UNUSUAL FIRE DENSE SMOKE MAY BE GENERATED t~HZLE BURNZNG. CARBON MONOXTDE, CARBON DTOXZDE, AND OTHER AND EXPLOSIVE OXZOES MAY BE GENERATED AS PRODUCTS OF COflBUSTTON. CONDITIONS STABILITY (THERMAL, S'rA~LE CONDITIONS TO NONE LIGHT, ETC.) AVOID HAZARDOUS wZl.L NOT OCCUR CONDITIONS TO NORE POLYMERIZATION AVOID INCOMPATIBILITY MAY REACT WZTH STRONG OXqrDZZZNG AGENTS. MATERIALS TO AVOID HAZARDOUS DECOMPOSITION NONE PRODUCTS STEPS TO BE CONSULT HEALTH EFFECT TNFORHAT[ON ZN SECT[ON Z[I~ PERSONAL HEALTH PROTECT[ON [NFORHATZON TAKEN IF ZN SECT[OH V, FZRE PROTECT[ON :~NFORMATZON IN SECT[ON VZ, AND REACTZVZT~ DATA ZN SECT[ON VZZ. NOTZFY APPROPRZATE AUTHORZTZES OF SPZLL. CONTAZN SPZLL ZNHEDZATELY. OD NOT ALLOW MATERIAL IS SP]:LL TO EI~I'ER SENERS OR WATERCOURSES. REMOVE ALL SOURCES OF I'GNTTZON. ABSORS N[TH RELEASED OR APPROPRIATE INERT HATER[AL SUCH AS SAND, CLAY, ETC.. lARGE SPZLLS HAY BE PZCKED UP US[NEi VACUUH PUMPS, SHOVEL;S, BUCKETS, OR OTHER MEANS AND PLACED IN DRUHS OR OTHER SU'tTABLE SPILLED co~rrAzNERs. WASTE DISPOSAL ALL DZSPO~AI.~ MUST COMPLY NZTH FEDERAL, STATE, AND LOCAL REGULATZONS. THE HATER[ALt ZF METHOD SPZLLED O~ DZSCARDED, MAY SE A REGULATED HASTE. REFER TO S'rATE AND LOCAL REGULATZONS. CAUTZON! IF REGULATED SOLVENTS ARE USED TO CLEAN UP SPILLED MATER[AL, THE RESULTING WASTE MZXTURE MAY BE REGULATED, DEPARTMENT OF TRANSPORTATZON (DOT) REGULATZONS MAY APPLY FOR TRANSPORTZNG THZS HATERZAL WHEN SPZLLED, ~/ASTE MATER[AL HAY BE LANDFZLLEO OR [NCZNERATED AT AN APPROVED FACZLZTY. NATERZAL~ SHOULD BE RECYCLED IF POSSZBI. E. HANDLING AND DO NOT TRANSFER TO UNNARKED CONTAZNERS. STORE TH CLOSED CONTAZNERS ANAY FROM HEAT, SPARKS, STORAGE OPEN FLAME, OR OXZDZZZNG HATER[ALS. THZS PRODUCT TS NOT CLA~SZFZED AS HAZARDOUS UNDER DOT REGULATZOMS. FZRE EXYZNGUZSHERS SHOULD SE KE~' R~ZLY AVAZLAaLE. SEE HFPA ~0 AND OS.~ REQUIREMENTS Z;Z0.t06--FLA~M~L£ AND COMBUSTZBLE LIeU[OS. ADDITIONAL THZS NZXTURE HAY BE FORMULATED [N PART WZTH COHPOMENTS PURCHASED FROM OTHER COMPANZESo ZN INFORMATION MANY ZNSTANCES, ESPECZALLYNHEN PROPRZETARY OR TRADE SECRET NATERZALS ARE USED, PENNZOZL COMPANY MUST RELY UPON THE HAZARD EVALUATZON OF SUCH COMPONENT SUBMZTTED TO PENNZOZL BY THAT PRODUCT'S MANUFACTURER OR ZMPORTER. BOLLING POINT · SO0F PERCENT VOLATILE N/A MELTING POINT - 3oF VAPOR DENSITY (AIR=l) N/A APPEARANCE CLEAR - O~d~E RED. EVAPORATION RATE (EL ODOR #[Lo LUBE OZL ODOM. SPECIFIC GRAVITY o VAPOR PRESSURE H/A MOLECULAR WEIGHT VARTES SOLUBILITY SOLUBLE ZN HYDROCARBONS. CITY of BAKERSFIELD NON--'ITRADE S ECRE2'S ' ~e 2 o~ 2 nus/.~ss 8~N~: Baker Sand Control O~R~ ~: Baker Sand Control N~N[ O~ CITY. ZIP: BAKERSFIELD. CA 93313 CITY. zzP: HOU$TON. TX 77208 DUN AND BRADSTREET P.ong ~: 805-834-2844 Pmo~ ~: 713-443-1590 0~_ - ~5 h of Prom ~lth .... ....... ~lth Of ~ ~lth .............. (C~k ell t~t rely) C~t 12 ~ & C.A.S. ~lth of Pr~re ~lth . ;.F~E~Y ~TACTS BI DON COBB DISTRICT ~AGER 8834-2844 12 C~IG PA~ER FIELD SUPERVISOR 834-2844 L-4559-C MATERIAL SAFETY DATA SHEET Uay 108S An explanation of the terms used here~n may be found in OSHA ~¢J CFR 1910.1200, available lrom OSHA recJ~ona~ or area offices (Eseentielly similar to U.S. Department of Labor Form OSHA-20 and generally accepted in Canada for information purposes) Do Not Duplicate This Form. Request an Original, PRODUCT Acetylene CHEMICAL NAME Acetylene SYNONYMS Acetylen, Ethine, Ethyne, Narcylene FORMULA C~H~ CHEMICAL FAMILY Alkyne MOLECULAR WEIGHT 26.038 TRADE NAME Acetylene (This product is intended for welding and cutting use.) · '~ '~ .... II. HAZARDOUS INGREDIENT~ .... ~ '~ .... ~ -' This sechon covers the materials from which this product is manufactured. The fumes and gases produced during welding and cutting with lhe normal use of th~5 proOuct are covered by Section VI. The term "hazardous" should be interpreted as a term required and dehned in OSHA 29 CFR 1910 1200 and does not necessarily imply the existence of any hazard. MATERIAL (CAS NO.) Vol (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Acetylene (74-86-2) 100 Simple asphyxiant (None currently established) BOLLING POINT, 760 mm. Hg Not Applicable SUBLIMATION POINT -84 'C (-119.2 F~ ~ 760mm Hg SPECIFIC GRAVITY (HaO = 1) Not Applicable VAPOR PRESSURE AT 21 ~C. 635 psig VAPOR DENSITY (air = 1) 0.91 SOLUBILITY IN Slight WATER, % by wt. EVAPORATION RATE PERCENT VOLATILES 100 Not Applicable BY VOLUME (Butyl Acetate = 1) APPEARANCE AND ODOR Colorless gas at normal temperature and pressure; garlic-like odor. EMERGENCY PHONE NUMBEI=i'''' ;7'~,~'~. T '.~'::;.':;. IN CASE OF EMERGENCIES involving this material, further information is available at all times: ~ In the USA 304 -- 744-3487 In Canada 514 -- 645-5311 o~ For routine information contact your local supplier ~ Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product · -J hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the mformahon on this MSDS and any product hazards and safety information, (2) furnish this same information to each of ~ts customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information UNION CARBIDE CORPORATION ; LINDE DIVISION UNION CARBIDE CANADA LIMITED LINDE DIVISION CoDvriOh! ~ , 1985 Union Carbide CorDorahon Pao~ 1 of ~1 ~'PRODUCT: Acetylene L-4559-C May 1985 :.'~'*-*'~ ?-*~-*' :-'-- W. HEALTH HAZARD DATA '-,~*:~*;~,,~'..*~, '../~,' ~~'_'.~ THRESHOLD LIMIT VALUE The ACGIH 1984-85 recommended limit for welding fume, not otherwise classified (NOC), is 5rog/m;. TLV-TWA's should be used as a guide in the control Of health hazards and not as fine lines between safe and dangerous concentrahons, See Section VI for specific fume constituents which may modify this TLV-TWA. EFFECTS OF OVEREXPOSURE AND EMERGENCY AND FIRST AID PROCEDURES working with welding and cutting may create one or more of the following health hazards: FUMES AND GASES can be dangerous to your health and may cause serious lung d~sease,' HEAT RAYS (INFRARED RADIATION from the flame or hot metal) can injure eyes. NOISE can damage hearing, Acetylene is an asphyxiant. Moderate concentrations may cause headache, drowsiness, d~zziness and unconsciousne'~s Lack of oxygen can cause death. Keep your head out of the fumes. Do not breathe fumes and gases caused by the process, Use enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone and the general area. The type and amount of fumes and gases depend on the equipment and supplies used. Possibly dangerous materials may be found in fluxes, coatings, gases, and metals. Get a Material Safety Data Sheet (MSDS) for every material used. Air samples can be used to find out what respiratory protection is needed. Wear correct ear. eye. and body protection, Short term overexposure to fumes may result in discomfort such as dizziness, nausea, or dryness or irritation of nose, throat, or eyes MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create adcht~onah unexpected hazards Obtain and evaluate the safety reformation for each component before you produce the mixture. Consult an Industrial Hygienist. or other trained person when you make your safetyevaluation of the end product. Remember, gases and hqu~ds have properties which can cause serious injury or death, A detailed descr;ption of the Health Hazards and their consequences may be found in Linde's free safety booklet L-2035 You may obtain cop;es from your local supplier, or by writing tO Union Carbide Corporation, Linde Division, Communications Department 39 Old R~dgebury Road. Danbury, Connecticut, 06817-0001. FIRST AID IN CASE OF EMERGENCY -- Call for medical aid Employ First A~d techniques recommended by t~e Amer~ca'~ Re~ Cross. IF BREATHING IS DIFFICULT give oxygen. Call a physician. IF NOT BREATHING, begin artificial respirahon, preferably mouth. to-mouth. If no detectable pulse, begin external heart massage, Immediately call a physician. IN CASE OF EYE BURN call a physician. 'NOTES TO PHYSICIAN: Acute -- Gases. fumes, and dusts may cause irritation to the eyes, lungs, nose. and throat. Some toxic gases associated with welding and related processes may cause pulmonary edema, asphyxiation, and death. Acute overexposure may include signs and symptoms such as watery eyes, nose and throat ;rritation, headache, d~zzmess, difhculty breathing, frequent coughing, or chest pains. Chronic -- Protracted inhalation of air contaminants may lead to their accumulation in the lungs, a condition which may be seer~ as dense areas on chest x-rays, The severity of change is proportional to the length of exposure. The changes seen are not necessarily associated with symptoms or signs of reduced lung function or disease. In addition, the changes on x-rays may be caused by non-work related factors such as smoking, etc PRODUCT: Acetylene L-4559-C May 1985 ~.,., . ' ..' .. ,,~~. ',*.~. * 'V. ?.IRE AND EXPLOSION HAZARD DATA .... :: .- "*'* '~" ' . .......INT *'~"~*"~"~'. .......... ---r-".--- .......... AUTOIGNITION ....... ~'"~'*'"~'~~'""'~ ' PO'*'"'* ..... ' 'o ...... FLASH - 17.8"C (0 F) T.C.C. / TEMPERATURE 299 C (571 F) (test method) INFLAMMABLE LIMITS 1 LOWERAIR. % by volume 2'3% IUPPER 100% EXTINGUISHING MEDIA See paragraphs below. SPECIAL FIRE FIGHTING PROCEDURES Refer to CGA pamphlet SB-4, "Handling Acetylene Cylinders in Fire Situations." Evacuate all personnel from danger area. immediately cool containers with water spray from maximum distance taking care not to extinguish flames. Remove ignition sources if without risk. If flames are accidentally extinguished, explosive re-ignition may occur. Use self-contained breathing apparatus. Stop flow of gas if without risk while continuing cooling water spray. Remove all containers from area of fire if without risk. Allow fire tO burn out. On-site fire brigades must comply with OSHA 29 CFR 1910.156. UNUSUAL FIRE AND EXPLOSION HAZARDS Extremely flammable gas. Forms explosive mixtures with air and oxidizing agents. Container may rupture due to heat of fire. Do not extinguish flames Oue to possibility ol explosive re-ignition. Flammable vapors may spread from leak. Explosive atmospheres may linger. Before entering area, especially confined areas, check atmosphere with approved explosion meter. No par[ of a container should be subjected to a temperature higher than 52 C (approximately 125 F). All containers are provided with a pressure relief device designed to vent contents when they are exposec~ to elevated temperature. Contact with copper, silver, or mercury or their alloys or halogens can cause explosion. STABILITY CONDITIONS TO AVOID UNSTABLE STABLE Stable as shipped. Avoid use at pressures above 15 psig. X INCOMPATIBILITY (materials to avoid) Copper, silver, mercury or their alloys, oxidizing agents, acids, halogens, moisture. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition or burning may produce CO/CO,IH2, The welding and cutting process may form reaction products such as carbon monoxide and carbon dioxde Other decomposihon products of normal operation originate from the volatihzation, reaction or oxidation of the material being worked. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur I Will not Occur Elevated temperature and pressure and/or the presence of a catalyst. X VII. ~ILL OR LEAK PROCEDURES '~ '"'*' ~'~"~ '* *'" ' STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Forms explosive mixtures with air (See Section V). Immediately evacuate all personnel from danger area. Use self-contained breathing apparatus where needed. Remove all sources of ignihon if without risk. Reduce vapors with fog or fine water spray. Shut off leak if without risk, Ventilate area of leak or move leaking container to well-ventilated area. Flammable gas may spread from leak Before entering area, expecially conhned areas, check atmosphere with appropriate device. WASTE DISPOSAL METHOD Prevent waste from contaminating surrounding environment. Keep personnel away. Discard any product, residue, disposable container or liner m an environmentally acceptable manner, in full compliance with Federat, Stale and local regulations. Pa~j,~ ? o~ 4 PRODUCT: Acetylene L-4559-C May 1985 INFORMATI, ON,,~. .... ~;,; RESPIRATORY PROTECTION (specify type) -- Use respirable fume respirator or air supplied respiralor when working in confined space or where local exhaust or ventilation does not keep exposure below TLV, Select as per OSHA2g CFR lgl 0.134. LOCAL EXHAUST -- Use enough ventilation, local exhaust or both, to keep the fumes and gases below TLV's in the worker's breathing zone and the general area. Train the worker to keep his head out of the fumes. MECHANICAL (general) ALWAYS WORK WITH ENOUGH VENTILATION VENTILATION SPECIAL Nol applicable OTHER Depends on specific use conditions, and location. Use adequate ventilation or personal respiratory protection. See Section IX and OSHA29 CFR1910.252. PROTECTIVE GLOVES Welding gloves recommended EYE PROTECTION -- Wear goggles with filter lens selected as per ANSI Z49.1. Provide protective screens and goggles, if necessary, to protect others Select as per OSHA29 CFR1910.133. OTHER PROTECTIVE EQUIPMENT -- As needed, wear hand, head, and body protection which help to prevent injury from radiation, and sparks. See ANSI Z49.1. At a minimum this includes welder's gloves and protective goggles, and may include arm protectors, aprons, hats, shoulder protection, as well as substantial clothing. Train the worker not to touch live electrical parts. IX. SPECIAL PRECAUTIONS=,~,'~.~, .-*'* ~.~.. . Fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being worked, the process, procedure and electrodes used, Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being worked (such as paint, plating, or galvanizing), the number of workers and the volume of the work area, the quality and amount of ventilation, the position of the worker's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample from inside the worker's helmet if worn or in the worker's breathing zone. See ANSI/AWS F1.1, available from the American Welding Society, 550 N.W. Le Jeune Rd., Miami, FL 33126 Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard Z49.1, "Safety In Welding And Cutting" published by the American Welding Society and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more details. For further safety and health information refer to Linde*s free safety booklet L-2035. OTHER HANDLING AND STORAGE CONDITIONS Heat and sparks during use could be the source of ignition of combustible materials. Prevent fires. Refer to NFPA 51B "Cutting and Welding Processes" and NFPA 50 *'Oxygen*Fuel Gas Systems." Use piping and equipment adequately designed to withstand pressures 1o be encountered. Gas can cause rapid suffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. Never work on a pressurized system. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. GENERAL OFFICES ,. ,. Union Carbide Corporation Union Carbide Canada Limited e UNION CA~BIDE Linde Division Linde Division 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontar,o M4P I J3 Other offices in principal cities all over the world. IL-4559-C 85,0928 4/85 25M LithographecJ in USA Page 4 of 4 SAFETY L-,,638-A ' MATERIAL DATA SHEET September 1985 An explanation of the terms used herein may be foun~l in OSHA 29 CFR 1910.1200, available from OSHA regional or area offices, (Easentlal!y Mmllar to U.S. Depertment of Labor Fom~ OSH&-20 and generally accepted in Canada for Information purpo~el) Do Not Duplicate Thai Form. Requeat an Original. [~ .... ,':'.~_'-:'", ........... '. PRODUCT 'DENTIFICAT~'~~~?j PRODUCT Oxygen CHEMICAL Oxygen SYNONYMS Not applicable NAME FORMULA O2 CHEMICAL FAMILY Not applicable MOLECULAR WEIGHT 32.00 TRADE NAME Oxygen · .~- .: . ~7~..~-.t,4.-.~.., '~':. .',-'~.,- . ...... . ...... ...=.,,.~.-,~r~..._~_~.,~_,~.'= -. ~'..~,~.,~. ,~_~' ~ -.- - ... · For mixtures of this product request the respective component Material Safety Data Sheets. See Section IX. MATERIAL (CAS NO.) Wt (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Oxygen (7782-44-7) 100 None'Currently established (Non~ currently established) BOILING POINT, 760 mm. Hg -183°0 (-297.4°F) FREEZING POINT -218.4°0 (-361.1 °F) SPECIFIC GRAVITY (H20 = 1) Gas VAPOR PRESSURE AT 20~C. Gas SOLUBILITY IN VAPOR DENSITY (air = 1) 1.105 (~ 25~C WATER, % by wt. Negligible PERCENT VOLATILES 100 EVAPORATION RATE BY VOLUME (Butyl Acetate = 1) Not applicable APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure. IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 304 -- 744-3487 In Canada 514 -- 645-5311 For routine information contact your local supplier Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazarc!s and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors .of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each o! its ~:ustomers (or the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information, UNION CARBIDE CORPORATION ~- LINDE DIVISION UNION CARBIDE CANADA LIMITED ~ LINDE DIVISION Copyright ' 1985 Umon Carbide Corporahon P~¢' ~ nr 4 PRODUCT: Oxygen L-4638-A ~ September 1985 THRESHOLD LIMIT VALUE: None currently established. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING -- No evidence of adverse effects from available information. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- Breathing 80o/0 or more oxygen at atmospheric pressure for more than a few hours may cause nasal stuffiness, cough, sore throat, chest pain and breathing difficulty. Breathing oxygen at higher pressure increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause lung damage and also central nervous system effects resulting in dizziness, poor coordination, tingling sensation, visual and hearing disturbances, muscular twitching, unconsciousness and convulsions. Breathing oxygen under press~;re may cause prolongation of adaptation to darkness and reduced peripheral vision. SKIN CONTACT -- No evidence of adverse effects from available information. EYE CONTACT -- No evidence of adverse effects from available information. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: See "Notes to Physician." MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: See "Notes to Physician." SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING -- This product is a gas at normal temperature and pressure. SKIN -- No emergency care anticipated. INHALATION -- Remove to fresh air. Give artificial respiration if not breathing. Keep victim warm and at rest. Call a physician. EYES -- No emergency care anticipated. NOTES TO PHYSICIAN: Supportive treatment should include immediate sedation, anti-convulsive therapy if needed, and rest. Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, increases the susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate that vitamin E deficiency may increase susceptibility to oxygen toxicity. Airway obstruction during high oxygen tension may cause alveolar collapse following absorption of the oxygen. Similarly. occlusion of the eustachian tubes may cause retraction of the eardrum and obstruction of the paranasal sinuses may produce "vacuum-type" headache. Newborn premature infants exposed to high oxygen concentrations may suffer delayed retina/damage which can progress to retinal detachment and blindness (retrolental fibroplasia). Retinal damage can also occur in adults exposed to lO0O~fl oxygen under greater than atmospheric pressure, particularly in individuals whose retinal circulation has been previously compromised. All individuals exposed for long periods to oxygen at high pressure and all who exhibit overt oxygen toxicity should have ophthalmologic examinations. WHEN USED IN WELDING AND CUTTING: Read and understand the manufacturer's instructions and the precautionary label on the product. See American Standard Z49.1 "Safety In Welding and Cutting" published by the American Welding Society, PO. Box 351040, Miami, Florida 33135 and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail. For further SAFETY AND HEALTH information, refer to Linde's free publication, L-52-529, "Precautions and Safe Practices for Electric Welding and Cutting", as well as L.2035, "Precautions and Safe Practices for Gas Welding, Cutting, and Heating**' You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Linde Division, Communications Department, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. NOTE: Suitability for use as a component in underwater breathing gas mixtures is to be determined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the effects, methods, frequency and duration of use, hazards, side effects and precautions to be taken. Fage 2 of 4 PRODUCT: Oxygen L-4638-A ~ September 1985 ' ' . ' . ·1/. FIRE AND EXPLOSION HAZARD DATA FLASH POINT I AUTOIGNITION Not applicable (test method) Not applicable TEMPERATURE FLAMMABLE LIMITS LOWER UPPER Not applicable Not applicable IN AIR, % by volume EXTINGUISHING MEDIA: Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (i.e. safety shower) is the preferred extinguishing media for clothing fires. SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. immediately cool containers with water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxidizing agent, vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion. Container may rupture due to heat of fire. No part of a container should be subjected to a temperature higher than 52 :C (approximately 125 ~F). Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. Smoking, flames and electric sparks in the presence of enriched oxygen atmospheres are potential explosion hazards. STABILITY CONDITIONS TO AVOID: See Section IX. I 'UNSTABLE STABLE X INCOMPATIBILITY (materials to avoid): Combustible materials, asphalt, flammable materials, especially oi;s and greases. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: None currently known. May Occur Will not Occur X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilatect area. Remove all flammable materials from vicinity. Oxygen must never be permitted to strike an oily surface. greasy clothes, or other combustible material. WASTE DISPOSAL METHOD: Slowly release into atmosphere, in an open, outdoors area. Remove all flammable materials from vicinity. Page 3 of J PRODEICT: Oxygen L-4638-A September 1985 ~ VIII. SPECIAL PROTEC ION INFORMATION .i~ .. 'i~, RESPIRATORY PROTECTION (specify type): Not required. LOCAL EXHAUST -- Not applicable. MECHANICAL (general) -- Acceptable. VENTILATION SPECIAL -- Not applicable. OTHER -- Not applicable. PROTECTIVE GLOVES: Preferred for cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. [ ........... sPECiAL PRECAUTIONS :~,.... · IX. - ........ ~":'~?'"?'~*:~' '~:~'~' "~' ~ '"' ~:" '" WARNING: High pressure gas. Vigorously accelerates combustion. Avoid contact with oils, greases and other flammable materials· Never use manifolds for oxygen cylinders unless specifically designed for such use. Use only with equipment conditioned for oxygen service. Use piping and equipment adequately designed to withstand pressures to be encountered. Protect container against physical damage. Isolate from combustible gas installations and combustible materials by adequate distance or by gas,tight, fire-resistive barriers. Protect against over-heating. Never use an oxygen jet for cleaning purposes of any sort, especially clothing, as it increases the likelihood of an engulfing fire. Note: Reverse flow into cylinder may cause rupture. Use a check valve or other protective apparatus in any line or piping from the cylinder to prevent reverse flow. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture, Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all labels and other instructions supplied with all containers of this product. NOTE: Compatibility with plastics should be confirmed prior to use. For safety information on general handling of compressed gas cylinders, obtain a copy of pamphlet P- 1~ "Safe Handling of Compressed Gases in Containers" from the Compressed Gas Association, Inc., 1235 Jefferson Davis Highway, Arlington, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. Never lubricate oxygen valves, regulators, etc., with any combustible substance. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use o! the product are not within the control of Union Carbide, it is the user's obligation tO determine the conditions of safe use of the product. ~.,.~ OFFICES IN THE USA: IN CANADA: ~ UN/OW c,4~a/DE Union Carbide Corporation Union Carbide Canada Limitecl Linde Division Linde Division 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P 1J3 Other offices in principal cities all over the world. L-4638-A 85-D928 9/85 45M Lithographed m US A Page 4 of 4 CITY of BAKERSFIELD NON--TRADE SECRETS BusI~£ss #AHa-: BAKER S~D CONTROL Owg~ NA~g: BAKER SAND CONTROL ~A~ O~ T~S pA~IglTY:OUTSIDE S.E,., CORNO~ c~rY, ZIP: BAKERSFIELD. CA 9~1~' C~T~. ZIP: HOUSTON, TX 72208 DU~ ~D BR~D~TRg~T ~R Ul P J. ~ i 30 LIOUEFIED P$~ROLE~ G~ (PROPANE]~ of ~m blth ...... (C~k ell t~t a~ly) r- 'r--~ r-~ r-~ r--~ ~t ~ ~IC.A.S. ~ k itl t~t ~ly) ~lth of ~re ~lth ........ ~'~, ~,,C,S I, DON COBB DISTRICT ~NAGER 834-2844 . c~IC PA~ER FIELD S'~P~R~6R : 83~:2844 i~t~ i~iwi~l~ COAST GAS Dear Customer: The Federal Occupational Safety and Health Administration (OSHA) recently published "The Hazard Communication Standard" (29 CFR Pan 1910.1200), establishing a number o{ requirements for developing, obtaining and providing health and safety in- formation of potentially hazardous chemicals used in the work place. Of particular note is the requirement that "Employers shall have a Material Safety Data Sheet for each hazardous chemical for which they use." Included in the definition of "hazardous chemical" are substances that are flammable. As a purchaser of Coast Gas propane, we are providing you with the following MSDS to assist you in meeting this OSHA Standard. We request that you forward this Information to the appropriate person responsible for safety and health in you organization. Coast Gas appredates your business and will be happy to discuss with you the availability of safety or training programs relative to the use of its LP-gas. MATERIAL SAFETY DATA SHEET Section ! Emergency Suppllers Name Phone Number Address Chemical Name Liquefied petroleum gas or Propane CAS Registry No. 74-98-6 Chemical Family Hydrocarbon Formula C,~H~ HAZARDOUS INGREDIENTS Section il Hazardous Mixtures Air with 2.15 to 9.60 percent propane PHYSICAL DATA Section Ill Bolling point -44 F Specific Gravity (H2 O--1) 0.51 .Vapor Pressure (mm HG) at 100 F 9825 Percent, Volatile by Volume (%) 100 Vapor Density (Air= 1) 1.52 Evaporative Rate None Solubility in Water$1iq~htlv Appearance and Odor Clear--unpleasant odor (caused by odorant) FIRE AND EXPLOSION HAZARD DATA Section IV Flammable limits Flash Point N/A .Classification Flammable Gas UN 1075 Extinguishing Media Water Spray: Class A-B-C or BC Fire Extinguishers Special Fire Fighting Procedures Stop flow o[ gas. Use Water to keep fire-exposed containers cool. Use water spray to disperse unignited gas or vapor. If ignition has occurred and no water available, tank metal may weaken [rom overheating. Evacuate area. I[ gas has not i_qnited, LP-gas liquid or vapor ma~; be dispersed by water spray or flooding. HEALTH HAZARD Section V Threshold Limit Value 1,000 PPM Effects of Overexposure Inhalation-concentration can lead to symptoms ranging [rom dizziness to anesthesia and respirato~ arrest. Eyes--moderate irritation. Emergency & First Aid Procedures Inhalation--Remove to fresh air. Guard against seli-inju~. Apply artificial respiration ii breathin_q has stopped. ~ REACTIVITY DATA Section VI Stable X Unstable Hazardous Decomposition Products None Incomparability (materials to avoid) Mixing with oxygen or air, except at burner. Hazardous Polymerization: May occur .Will not occur X SPILL OR LEAK PROCEDURES Section VII Steps may be taken in case material is released: Keep public away. Shut off supply of gas. Eliminate sources of ignition. Ventilate the area. Disperse with water spray. Contact between skin and these gases in liquid form can cause freezing of tissue causing injury similar to thermal burn. Disposal Method Controlled burninq. Contact supplier. SPECIAL PROTECTION INFORMATION Section ViII Respiratory Protection . Stay out of gas or vapor (because of fire hazardl Ventilation Explosion-proof motors and keep sources Of ignition at safe distances. Personal Protective Equipment and Apparel Leather or equivalent gloves, goggles for protection against accidental release of pressurized products. MATERIAL SAFETY DATA SHEET SPECIAL PRECAUTIONS Section IX Precautions to be taken when handling and storing Keep containers awav from heat sources and store in upright position. Containers should not be dropped. Keep container valve closed when not in use. Other. Precaution Install protective caps when not connected for use. TOXICOLOGICAL INFORMATION Section X OSHA Carcinogen Classification (29 CFR 1910 Not listed/applicable X Category I Carcinogen Category Il Carcinogen Listed as Possible Category I Listed as possible Category II .' DOT LABELING INFORMATION (49 CFR 100-199) Section Xl Proper Shipping Name Liquefied Petroleum Gas Hazardous Classification Flammable Gas Identification No. UN 1075 Label(s) Required Flammable, Class 2 Date of Preparation or Last Change: April 24, 1987 CITY of BAKERSFIELD NON--'tRADE SECRETS BUSZff£SS #AHE: BAKER SAND CONTROL OILIER ................ #AHE: B~ER 'S~D CONTROL HAM~ OF T~ FACILITY: WEST S~D ~SE. ~0N: ....... 55~1 ALDRIN CT. ADDRESS: 1010 ~KIN ~./P.0. BOX 61486 STANDARD crrv. zI~: B~ERSFIELD, CA 93313 CZTY, Z~P: HOUSTON TX 77208 DUN AND B~D~TR~T NUHB~R LBS 365 12 1 4 1 lJ ~ST S~D ~SE. ~ 7~ SILICON D%OXIDE/DIATO~CEQUS EART~ ~-~ r--~ ~~ ~ & C.A.S. ~ t t IWEST SAND ~SE. : 1~9. ~s~L~coN D~OX!DE/SILICA' S~D ic,I ~ ~lth ~z~ C.A.S. ~ 14808-69-7 ~t II ~ & C.A.S. ~ (C~k oil t~t ~iy) - -- r--~ r--~ r--~ ~t ~ ~&C.A.S. ~ Mlth of Pm~ ~lth ~lth of Pr~ ~lth ....... ~E~Y ~TS e~l~~ ~.O~ ................ ~ ........ DISTRICT ~AGER 834-2844 ~ C~IG PARKER FIELD SUPERVISOR 834-2844 t~tttic~t~ (Re~d and s~ after coBpJet~ng all ~ect~ons) ?BAKEI~%AND CONTROL MATERIAL SAFETY DATA SHEET esc-223 JJ AI'RIL 6, 1988 I. PRODUCT IDENTIFICATION MANUFACTUreR ~ NAME ADDRESS BAKER SAND CONTROL ~).0. BOX 61486, HOUSTON, TX 77208 r~M£RGENCY P~ONE NO. PI~OOUCT NAME: 713-443-7590 DIATOM]{CEOUS ;ARTH CHEMICAL Ti'. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER DIATOMACEOUS EARTX 68855-54-9 100 0.1 mg/m3 0.1 mg/m3 50 mg/m3 (NIOSI) (~S~IRABLIi) (~SPIRABLB) (RSS~'IRABLB) MAY CONTAIN ~ARTX 14808-60-7 5 MAX 0.3 Ig/m3 CRI b'I'0BALITE 14464-46-1 70 MAX TrY. pHYSICAl DATA BOLLING POINT VAPOR I:)~RESSURE VAPOR DENSITY (AIR - 1 ) E'VAI:N2)~TION RAT[ (BUTYL AC[TATE = 1 ) ~OLUB}LITY IN WATER 5Im'E:CIF'IC GRAVITY (WATER = ! ) VOLATILITY AI:q=F. ARANC[ AND OOOR 1-~. FIRE AND EXPLOSION INFORMATION '-ASH FK){NT I;' UISHING MEDIA FL.AJ~MABLE2 SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARD5 CONTAC! WITX FLURIIIH. Cm. ORI~, TRIFLUO~IDE WANGANES~ TRIOXIDE AND OXYGEN DIFLUOEID! MAY CAUSi SI~3NTAN~OUS FIP, H$. V. HEALTH EFFECTS INFORMATION PRIMARY RO~ OF EX~URE: [] SKIN [] EYES [] INHALATION [] INGESTION ACUTE (SHORT) E.XPOSU~ SKIN: ~ EYES: tN H A LATtON: ~/~J~JSI ~3JJl Z INGESTION: SKIN: ~ EYES: I~YA~ ENHALATION:P~~IS. SILI~IS ?ffi~l FIB~IS, ~$IB~ C~l~ INGESTION: N ~M~6NCY ~I~T AI~ ~IN: ~. ~S: ~USH ~H L~ ~ OF WA~ ~ ~ DU~. ~Y ?HSICI~ IF I~TA~ffi PERSI~S. POT[NlrdL CA.C,NO~EN XIi:~. ZA NU J AGGRAVIII~JI3I{{~I~I{~[~IIII~]UI~5 Ut ~}[~k~J{~ I I NPT: IARC: OSHA: ~, , "~, ~ VI. REACTIVITY INFORMATION ~TARILITY CONDITIONS TO AVOID INCOMPATIBILITy (MATERIAL. S TO AVOID) b'TJJ/.l ~ ~ROFbUORIC ACI%) HAZARDOUS POL.YMERIZAT1ON I CONOIT~TO AVOICI THERMAL. C)ECOMPO$1TION PRODUCTS Si~4 E'RODUC~ U[:~0g CONTAC? #I~ ~ ~lrz. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF' MATERIAL. IS R£L.F..ASED OR YAC[JUN 0E $11~ ~. A¥0ID CREA'I'IN0 DU~. II,AR 01Jb'l' NAS ~ SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION 01J~ NASK ~,E.T,~'no. FROVID! ~ VENTILATION 'l'0 ~ COtfC~fl~,TI~ B~,O~ ~ LI~IT~. PROTECTIVE GLOVES EYE PROTECTION OTHER faROTECTIVE EQUIPME-NT lJ0'J' R~R~ 1'~, HANDUNG AND STORAGE INFORMATION AVOID C~ATI~ DU~. RI?AIR ~ltOKBi/l'Oill lAOS llOi~I)IAI'BI, Y. #NAR DU~ ~ ~ I1~I)~. ~'. ADDITIONAL INFOEMATI~ CHEMICALS REGULATED UNDER TITLE II! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCL.A EXTREMEL.Y HAZARDOUS SUBb-TANCF.,S C£RCL.A HAZARDOUS SUB~TANCE.~ SARA EXTREMEL.Y HAZARDOUS SARA TOX/C CHEMI. CAL.~. O~HA HAZARDOUS CHEMICALS ~r'"J IMMEDIATE (ACUTE) HEALTH HAZARD I ZDELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): ~10 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL MAT~RIAL;~-(FETY DATA SHEET EFFEC'r~VE DATE i~C--223 ~ 17, :].988 T. PRODUCT IDENTIFICATION MANUFACTURER'S NAME ADDer. SS P.O. BOX 614~6. HOUS~O#, ~ 77208 B~R SA~I) CONll~0L PRoOUCr NAME .MERGENCY PHONE NO. 713-443-7590 BAI~E LOW PI~ CHEMICAL DESCRIPTION CRY~fALLI~ SILICA TI'. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEt. ACG~H Tt.V OTHER SILICA 14808-60-7 100 0.1 Ng/N3 0.1 I(g/N3 50 Ug/N3 (NI0$E) C.S'rALLINS ~ARTZ (RSS~Ii~LS) (US~mLS) (.SeX~LS) 0.3 (TOTAL) TI1. PHYSICAL DATA * . BOLLING POINT VAPOR PRF. SSURE VAPOR DIC'NSfTY (AIR = 1 ) EVAFK3RATtON RATE (BUTYL Ace-rATE NOT APPLICABLE NOT APPLICABLE ~LUSILITY IN WATER ~ClFIC GF~AVrrY (WATER ~ NSOLUBLll 2.65 VOLATILITY APPEARANCE AND .~'~ £OWER: ~ SPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS CONTACT IIIT~ ~UORIIlll, C]ILORIN~, TRI~UORIDE, RA0~ TRIOIIDR AND O]ffglfll DI~LUORIDll NAY CAUS8 SPONTANSOUS I*IRES. V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE [] SKIN Ii:::] EYES ]j:] INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE SKIN: JJOJ~ EYES: IRRITA?IOIi iNHALATION~OJ~"J~SS O~ B~A'I'~, ~.~U~[~ PUIu#0#I~RY [II~C"J~0~. '[~J~SI'~O~Y J~?~JJ ~"PlJJA'J.~OJJY IItRITATIOll z O INGESTION: JJJ~ CHRONIC (PROLONGED) EXPOSURE SKIN: ~ EYES: I[~i~ITA~[~011 INGESTION: ~ EMERGENCY FIRST AID PROCEDURES 3: KIN: !I(~. SYBS: FLUS~ WII~ LAi~ ANOUNTS 0f #ATBR TO RSNOVB DUST. CONSULT P~YSICIAII It* IRRITATION P~RSIST$. NHALATI~: RSMOV~ TO I~.SSH AIR, DRINK #ATilt TO CLSAit T~ROAT. BLOIf NOSll. II~STION: i POTEI#~]ALCAR(:INOG£N ~$' ZANPT: IARC: OSHA: #0 JAC'GRA~[a~I~q)[S~Ab'~$ jTAaG~'[I~I~IANs TV'Z!. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL I~ RELEASED OR SPILL£D SC~P OR SfillP ~. A¥OID CRI!ATING DUST. ~ DUST MA~ ~ ~S, WASTE DISPOSAL METHOD LANDFILL VZTI. SPECIAL PROTECTION INFORMATION RES.,RA'roR¥ ..OTECT~OH DUST ~ v~.r,~,o. PROYIDS CS~R~ ~ILA~ ~ ~ C~~ BS~ ~IS)~S L~L. L~ ~ILATIOM ~Y BS ~CSSS~Y ~ ~BP C~ATI~ B~ S~ LI~TS. P~TE~VE GLOV~ ~. HANDM~ AND $T~A~ IN~EMATION AYOID C~ATIOH O) DU~. ~AIR )R~/~ BAOS I~IA~Y. ~R D~ Eq~ AS ~. X. ADOITIONAt INFORMATION CHEMICALS REGULATED UNDER TITLE [Z! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA), C£RCLA EXTREMIrLy HAZARDOUS SUB~TANCE~ CERCLA HA~.ARDOUS SUB~TA~CF..5 N0 5ARA EXTREMELY HAiR.US GU~TANC~ ~0 SARA TOXIC CHEMICA~ OSHA HA~US CH[M~CALS ~ I~EDIATE (ACUTE) HEALTH HA~ED ~DELAYED (CHRONIC) HEALTH HAZARD ~ FIRE HAZARD ~ SUDDEN RELEASE OF PRE~UEE HAZARD ~ REACTIVE'HAZARD HAZARDOUS WASTE (~CEA, ~ CFR 25t): ~ N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED ( THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. iT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. CITY of BAKERSFIELD NON--TRADE SECRETS ' P~ge 1 of 1 BUSINESS NAME: B~ER .................................... SMD CONTROL O~ER NAME: B~ER SMD CONTROL NAME OF TM§ rAczr, z?Y:0UTSIDE N.E. ~SE ~OCA?ION: 5551 ALDRIN CT. ADDRZSS: 1010 ~NKINRD~P.O--Box~-~'~ ~ 61486 STAND~RD I~. C~ASS ceDI C~Y. ZZP: .... B~ERSFIELD~ CA 93313 ~Z~, ZIP: HOUSTON. TX 77208 DU~ A~D BRADSTR~T ~UHB~R ~HO.~ ~: ~ms-~qa-~844 ~.o,E ~: 713-443-1590 0~_ - 357 - 7377 C~ C~ ~t ~ Est ~*ts m Site I~ ~ Tm ~ St~ tn F~tltty~ ~ I~t~tt~ h__l.L_l._.5)o _i ~oo I ~oo ~ 36s ~3 ~ 4 oaJours~ ~.~. ~s~. ~ s-6o/~s~ ........... ,~c,I ~ ~th ~ C.~.S. ~ 68476-34-6 ~t ~; ~ & C.A.S. ~ I ~'" ~-~-',, . · ......... ~x.. . ~-~ ~--,,h[-~~of ~ [~ '~"t'~th ~t' ~SC.A.S. ~ , ~t~ ~ & C.A.S. ~ ..... [.-,1 J I ' 1 .... 1 ...... 1 ..... I I I l___ . ..... " icil M Mlth ~Z~ C.l.S. i Wt II M & C.l.S. i k ell tMt 4wly) ~--~ r--5 r--~ ~--~ r--~ ~t~ M&C.A.S.~ Mlth of ~ Mlth _i~L,l [ .... I_~_ i~I' ~'1 I .I J. I .......... :-'_ ..... '. k ~11 t~t mil) - r--~ . r--~ r--~ r--~ ~t ~ ~&C.A.S. ~ ~lth of ~ - ~lth .... l__t ...... ~ I I I .t__J :: ! : i___! .: ........... : ..... _ ..... . - r--~ -- r--~ C~t 12 ~EC.A.S. ~ h of Pr~sure ~lth ~K~KY ~TS f~ DON CO.~ .............. ~ ........ DISTRICT ~AGER 834-2844 ~2 C~IG P~KER FIELD SUPERVISOR ~3~'2844 i~'~ ....... fiTli ....................... 2I'gF'P~ ..... ~ Utli ~'~ ...... '! ~ B~ER SAND CONTROL MATERIAL SAFETY DATA SHEET EFFECTIVE DATE Bsc-~3 I~RBRUAR~ 19. 1988 L PRODUCT IDENTIFICATION . MANUFACTURER'S NAME ADDRESS 8AKHR SAND COIFlliOL P.O. BOX 61t86. ]{OUS~ON. TX 77208 EMERGENCY PHONE NO PRODUCT NAME 713-443-7590 S-60 DIESEL OIL CHEMICAL DESCRIPTION PETROLEUM DISTILLATE FUEL FRRPARRD Iii; g['B~ ~{OSCHBWSKI H. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER DIIISI{I. 2 68476-3t-6 100 N/l{ N/E 100 PPM * · RRCOMMHNDED BY ~ANU~ACTURRR IlL PHYSICAL )ATA BOILING POINT VAPOR PRE~SURE 320-650'F (160-3S0'C) ~1 mm Ilo ~ 68'[ (20'C) VAPOR DENSITY (AIR = 1 ) EVAPORATION RATE (BUTYL ACETATE = 1 ) >5 0,02 SOLUBILITY IN WATER SPECIFIC GRAVITY (WATER = 1 ) MBGLIGIBLH 0,86 ~ 60'F (16'C) VOLATILITY APPEARANCE AND ODOR lO0~ (¥ly) CLI{~ Y]{LLOW LIOUID WITH i~kI~ EYDROCAI[BON ODOR IV. FIRE AND EXPLOSION INFORMATION LASH POINT EXTINGUISHING MEDIA FLAMMABLE LIMITS (% BY VOLUME} I~O'F (60'C), fllCC kS~ll D93 WAYRR b~[t~YI~0(]IP0~,C02 LOWER: 0.9 UPPER: ')'.0 SPECIAL FIRE FIGHTING PROCEDURES USE S~F CONTAINED BRRAHINO APPAIJA~S WITH I~ULL FACE PI]ICE. COOL I~IRR-~XFOSBD CONYAINRRS USING WATRR ~RAY UNUSUAL FIRE AND EXPLOSION HAZARDS VAPORS CAN PORN IGNITABLE MIk"ItIRR WIH AIR. VAPORS CAN PLOW AI, ONG SUR~ACIIS TO DISYAN~ IGNITION SOURCES AND ]~LASH BACK. COMBUSTIBLB LIDUID V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE ~ SKIN ]~ EYES ~ INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE SKIN: IRRITATION EYES: IRRItAtION iNHALATION:RRABACRR, DI/.~.I~SS. RR~IRA~RY TRACT IRILIYAtlOli, CNS D~RRSSIOli ~ INGESTION: NAUSEA, VOMI?I~ CHRON(C (PROLONGED) EXPOSURE ~ SKIN: DERMATITIS EYES: N/R -- INHALATION:p0$$IBLJ[ KIDJ~Y ~ INGESTION: NIH [M[RG£NCY FIRST AID P"OC[OURES i ~KIN: WA~ Y]IOROUG~Y WIt]{ SOAP &WATRE. ~YHS: FLUSH WITH WIT]H{ AY LHA~Y 15 MIN. (' ~ [N~tLED: I~IOVE 'M FRRSI{ AIR, AUMINISTRH OH~N OR ARTII.~ICI~ RESPIRATION AS li~IJDED. ~ NGES~IED: DO iO~ INDUCH VOMITING, GI~ PLHN~Y O[ WA~. N~VER GIVE ANIq'I{ING BY {OUT~ TO UNCONSCIOUS PERSON. IN ASL CASES OF CONTACT SERK N~DICAL M~'HNTION [IOI~DI AY]D~Y. POTENTIAL CARCINOGEN AGGRAVATION OF EXISTING CONDITIONS TARGET ORGANS NPTNo {ARCNO OSHA: NO NON~ IDR~IFIED EYHS, SKIN. CNS RESPIRATORY , -m~ VL REACTIVITY INFORMATION S~ABLE g~AT, S~ARI(S, OR OP]~ FLA]4]~S STRONG OXlDI~IN~ A~S ~I~ ~ ~C~ ~0~ CO, ~D~, ~MO~ VII. SPILL OR LEAK PROCEDURES ~TEPS TO BE TA~E~ ,~ MAT£R'^~ ~S RELEAS~ oR S~,LLE~ SMALL SPILL: COVIIR #Illl SAND OR CO~RCI~ ~SORBE~ ~ PLACE IN SUIT~LE CO~AI~R. LARGE SPILL: DI~, P~ ~RING SE~R/NA~R~AY. ~S~ER ~ ~OLDING T~. CO~ ~SID~ MI~ S~ OR CO~RCI~ OSO~ ~ PLACE IN ~ITOLE CO~AI~R. USE PBRSON~ PR~CTI~ E~UIP~ AS ~C~SS~Y. CO~USTIBL~ LIQUID. S~ 0~ I~TI~ SO~C~S. WASTE DISPOSAL METHOD USE RCM ~PROYED ~ZklU)0US XASTE DISPOS~ SITE. ¢0NSULT U)C~, STATE, ~ ~DEI~ REGULATIONS VIII. SPECIAL PROTECTION INFORMATION ,~ES.,R^TO.Y PROTECT'O" I~i~g CONCENTRATIONS EXCE~ EXPOb~P~ LIMITS, USE PROPER NIOSR ~PRO~D C~IDDE ~SPI~R. ~N LIMITS OF C~I~E ~SPI~R EXCEEDS, US~ NIO~ ~P~D SELF C~AI~ B~A~ING ~P~S NI~ F~L FACEPIEC~. V~,T,~T,O, PROVID~ GR~ ~ILATION ~ OEP C~C~TION BE~M ~IS~CE LEAL. L~ ~ILATION ~Y BR ~CESS~Y ~ ~BP CONCE~ATION BELON E~ LI~TE. PROTECTIVE GLOVES ~. HANDLING AND STORAGE IN~RMATION AVOID )~k~I~ Y~ORS/MI~ ~ CO~AC~ )I~ ~IN. ~S. 0R CL~I~. ~ CO~AI~R llO~I C~O ~) N~ IN USE. ~Z~OUS ~SID~ ~Y ~IN IN ~ D~. DO ~ ~U~ CO~AI~RS. ~C~C~ N~ ~D F~SON~ ~OI~. CO~US~IB&~ &I~UID. AVOID X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE IH OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLAEXTREMELY HAZARDOUS SUBSTANCES CERCLA HA~AROOUS SUBSTANCES TES. U~ISTED ~k~./J~I)0U$ D001. R~) - 100 SARA EXTREMELY HAZARDOUS SUBSTANCES SARA TOXIC CHEMICALS #0 OSHA HAZARDOUS CHEM*CALS [] IMMEDIATE (ACUTE) HEALTH HAZARD E]~)ELAYI:D (CHRONIC) HEALTH HAZARD ~J~ FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): ~S, HA ~ZklU)0US llA~ IlO. l)O01 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. CITY of BAKERSFIELD NON--qTRADE SECRETS ~u.~.c~ .-.m: BAKER SAND CONTROL u~.g~ .a.g: BAKER S~D CONTROL ~ocaTIO~: 5551 ALDRIN COURT ~DDmZSS: 1010 ~NKIN ~./P.O. BOX 61486 ST~DhRD I~. C~SS cedi ~ , ciTY, ZiP: B~ERSFIELD~ ~A 93313 Cl~, Zzp:HOUSTON~ TX 77208" DON AND BRADSTRE~T NUMBER PffONg ~: 805-834-2844 PHON~ ~: 713-443-7590' ~9_ - 357 - 7377 L ic.I ~ ~lth ~ C.A.S. ~ N/A ~ II ~ & C.A.S. k ell t~t INly) ....... ~ With of ~ ~lth 1 ~ ~lth ~t~ C.A.S. ~ ~t II ~ & C.l.S. k all t~t ~ly) -- ~--~ r--~ ~--~ ~--~ ~t~ ~iC.A.S. ~ic~l ~ ~lth ~ C.l.S. ~ ~t II h I C.A.S. (C~k rely) ~- r-~ r-, [-] - ~t l~ ~&C.A.S. ~lth of Prfl~fe ~lth ~,~, ~,~,$ ,,D.Qa..CQ~ ............... ~ ....... DISTRICT ~AOER 834-2844 . C~IO P~ER FIELD :su3~Rvi~OR ; ~42284~ BAKER SAND CONTROL ~;~ATERIAL SAFETY DATA SHEET JJEFFEC'nVE . L PRODUCT IDENTIFICATION MANUFACTURER'~ NAME ADDERS ~R S~ C~0L P.0. BOX 614~, HOUS~, ~ 77208 EMERGENCY PHONE NO. P~DU~ NAME INORG~IC ACID. HCL. ~IltlC ICID P~P~D BY: OLE~ ROSC~SKI ~. HAZAR~gS INGRJDIJNTS INGREDiEnT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER ~R~ORIC IClD 76i7-01-0 35 5 ~R~ * 5 PPI * 7 Jq/a3 * ~[. PHYSICAL DATA BOILING ~INT VA~R PR~URE VA~R DENSI~ (AIR = 1 ) EVA~RATION RATE (6U~L AC~AT[ SOLUBILITY IN WATER SPECIFIC GRAV~ (WATER SOL~LH ~IH SLIG~ EVOL~I~ OF ~lt 1.1778 (21.8 'Be) VOLATILITY APP~RANCE AND ~ CO~USTIBL~ I~ I~OL~D IN ~I~. NA~R SP~Y LOWER: ~ UPPER: NO~ ~PECIAL FIRE FIGHTING PR~EDURE~ UNUSUAL FIRE AND EXPLOSION HAZARDS CORROSIVE I`I~ID ~ V~0R. TOXIC ¥~0RS/FUI~S (IICI,) E¥0I,RID LIPON C0~ACT NItii IIATEE ~ StE~l. linEmEN I~A$ (~2) ll¥0I,VED ~0N COEI'AC? MIl'E l!057 V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE J~ SKIN j~] EYES [[~ INHALATION [] INGESTION ACUTE (SHORTI EXPOSURE SKIN: R.~D[~J~S$, PAIN. SEVE~ BURIIS. CONCORD SOL,IONS CAUS~ DRRP ~RRS ~ DISCOLOR SKIN EYES: V~0R~ ~ I~ITAIING ~ ~l CAUSR D~. SPLAS~S CAUSR CHRONIC (PROLONGED) EX.SURE SKIN: INGE$TION: [~DIA~LY PLU~] ~I~ WlH PL~ 0F gA~R Fffi It LEAST 15 ~I~. ~0~ C~INI~D C~ ~ WAS~ ~0ROU~Y ~0~ ~TE~L CARCIN~ENNPT: ,AEC:~O OSHA: REACTIVITY INFORMATION HA~R~U~ ~LYMERI~TION CONDITIONS TO AVOID gILL ~ ~C~ THERMAL OECOM~SITION ~R~Eg ~[[. SPILL OR LEAl( PR~EDURES ~ILL: DI~ ~I~K ~ ~I~D SOL'ION ~I~ WASTE DIS~AL M~HOD DIS~E IN ~ ~D ~Z~S NA~ FACILI~. ~N~T L~. ~A~. ~ FSDE~ ~ATI~S VIII. SPECIAL PROTECTION INFORMATION RES.R^TORV ~ROTECT,o. NIOSH J~PROVSD I~TLL I*ACI~ [*IECl~ CB~IICAL CARTRID~ llESPINATOR. SSLI! CORTAINSD BESATHINO ~PARATUS glTH I~ULL [~ACl[ [~IBCB. AIRLI~D HOOD. VE.T,~T,O. LOCAL SXEqUST TO t*RSVI~' SXCI~SDING ~][~OStlRS LINITS AND TO PRI~rBIT DISTSRSION TO OT~R I83RKARSAS. PROTEc-r,vE GLOVES EYE PROTECTION CH]DIICAL OOOOLI~S OR [*tiLL I~ACS SHISLD. DO NOT NHAR CONTACT LNNSSS ~ HANDLING THIS NATSRIAL. OT. ER PROTECTIVE E~U~PME.T II~RNVIOUS BOOTS. ~RON0 OR SUIT NAY BB h3CSSS~Y TO [~ SKIN CONTACT. BYB BAn AND SAIq~rY SHO~DRIlNCIIING FACILITY SHOULD lis AVAILAB~. IX. HANDLING AND STORAGE INFORMATION CORROSIVS LI[[IID. STO~ IN COOL. DRY. VlfliTILATIB ARHA. I~1[* CONTAINSR TIGIITLY CLOSSD glBN NOT IN IN lfl~l'Y DRUN. DO NOT RI~ISS CONTAII~BRS. t*RACTICS NORNAL GOOD ?BRSONAL X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). C£RCLA EXTREMELY HAZARDOUS SUBSTANCES. nS, GAS ONLY (~q)R13G'~ CHLORIDS) R~ - 1 ~ CERC~ HAiR.US 6U~TANC~ ~S. ~~IC ACID ~ - ~ LBS SARA EXTREMELY HAiR.US SU~TANC~ ~S. GAS ~Y (~R~ C~IDS) ~ - ~ ~S ~RA TOXI~ CHE~ICA~ ~S. ~~C ACID os~ H~US CH~*CA~ ~ I~EDIATE (A~UTE) HEALTH HAZARD ~ DRAYED (CHRONIC) HEALTH HAZARD ~ FIRE HAZARD ~ SUDDEN RELEASE OF PRESSURE HAZARD ~REA~TIVE HAZARD HAZARDOUS WASTE (ETNA. 40 CFR 26]): ~S. ~A ~S ~ ~. ~2 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR / CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. CITY of BAKERSFIELD NON--TRADE SECRETS , p,9, .1... of ~,~ ausINr-SS #&Hr: BAKER SAND CONTROL ONNP_R ............. #AHE: BAKER SAND CONTROL NAHZ OF T~S ~CILXTY.:SOUTH CH-EMICALL~St CITY. ZXP:. BAKERSFIELD. CA 93313 CXTY. ZXP: HOUSTON. TX 77ZO~ DUN AND BRADSTR~gT NUNB~R PUO,g ~: 80~-834-284~ P~O,g ~: 713-443-1590 0~_ - 357 -7377 P~icll ~ ~lth ~ C~A.S. ~ 12125-02-9 ~ It ~ & C.A.S. ~ ~ ~ ~&C.A.S. ~ of P~ blth ~~ ~ & C.I.S. ~ icll W ~lth ~z~ C.A.S. ~ 5329-14-6 ~t II M & C.A.S. i k ell tMt ~ly) .... ~ ~ ~ & C.A.S. ~ I tcll ~ ~lth ~l~ C.A.S. ~ 7447-40,7 ~t It ~ & C.A.S. ~ - '" --~ - ~t ~ ~&C.A.S. ~ ~lth of Pm~ ~lth · . . ~ .... 1 4 SOU~ CHg~CA~ ~Sg. 9~ SO~ CBLOA~g ~1 ~ ~lth ~ C.A.S. ~ 7647-15-6 ~t Il ~ & C.A.S. ~ (C~k all t~t ~lth of P~ ~lth ~NEK~K~ ~r~S fl DON COBB DISTRICT ~AG~R 834-2844 12 C~IG ?A~ER ~IELD SUPERVISOR · 83412844 BAKER SAND CONTROL · e~c~3 ~RBRUIR~ 16, 1988 I. PRODUCT IDENTIFICATION MANIJFACTUt~.t~ ~, NAME '~llllR $11~ID C0gTR0t P.O. B0X 61t86. IIOUSI'0M. TX ??~-08 ~ERGS:'NCY Pt.tONE NO. I~ODuCT NAME 713-4t3-7590 B-610 A~MON]~ C~0RDR ~NGREDENT CAS NO. APPROX % EXPOSURE UM~TS OSHA PEL ACG~H TLV OTHER AI~ONIU~ CHLORIDE 12125-02-9 >99 20 ~gla3 10 ag/a3 2) ~j/.3 (AC$IH ST~L) ZIL PHYSICAL )ATA BOILING POgNT VAlU<~ 968'F ($20°C) !1~ ~PLICA~LR VAPOR DENSITY (AIR · 1) EVAPOI~ATION RAT~ (BUTYL ACETATE = I ) ~ II'PLICIBLR ~)T ~PLICIILR SOLUBILITY INWATER SP[~ GRAVITY (WATER - 1 ) $0tl~tl 1.567 9 68'F (20'C) VOLATILITY AI=~=~I, RANCE AND !~ ii~Pl, IC~l.! I~t~ CRY~II~ S0I, ID #IH il0 ODOR J'V. Rill= AND EXPLOSION INFORI~kTION &$H POINT EXTINGUISHING MEDIA F~B[.[ UMIT~ (% BY VOLUME) IJ0J~ JJ0JJ-C0J~U~J'IB~J LOWER: Jj~ UPPER: SPECIAL FIRE FIGHTING PROCEDURE5 NOt UNUSUAL FIRE AND EXPL~ON HAZARDS ~TI~IILI, Y~)0RI~S AT 653"F (335'C) ~ ~YOL~S ~0XIC ~l~S. ~ V. HEALTH EFF~TS INFORMATION PRIMARY 1~3UTES Gl~' J~ SKIN [] EYES ~ INHA~TION ~ INGESTION ACU~ (SHO~) ~U~ INHALATION:C~, ~ I~TI~$ ~ ~ INGESTION: ~, ~S, G~C I~ CH~NIC (~LON~D) ~U~ SKIN: ~/~' EYES: INHALATION: INGESTION: N EME~ENCY ~T AiD ~EDUR~ ~IN: Wk~~YWI~&WA~. ~S: ~U~WA~AY~ISHIN. I~: ~I~V~I~. GI~P~OFWA~. ~GI~KBY mTEN~NPT: CA~IN~ENiARC:~ OSHA: VI~. SPILL OR LEAK PROCEDURES STEPS TO RE TAKEN IF MATERIAL IS RELEASED OR SPILLED WASTE DISPOSAL ML;'I'HOD ~L~. SPECIAL PROTECTION INFORMATION .ESP*RATORY V£NT,LAT,O. PROVIDB ~ C~~ B~ ~ LI~. .~,V~ ~OV~ R~B~. ~, ~, EYE ,~. HANDLING AND STORAGE iN~RMATION AVOID B~AHI~ V~/~ X. ADDITIONAL INF,,ORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARI:)OU~* SU~iTANCr~.s CERCLA HA~R~U~ SU~TANC~ ~S. ~ C~IDS. ~ - ~ LBS SARA EXTREMELY H~R~US SU~TA~ ~ARA TOXIC CHEM~A~ os-~ .*~.~us c.;~c~ ~ I~EDIATE (ACUTE) HEALTH H~ARD ~ DE~YED (CHRON.) HEALTH HAZARD ~ FIRE HAZARD ~ SUDDEN RELEASE OF PRESSURE HAZARD ~ REA~IVE HAZARD HAZARDOUS WASTE (RCRA, ~ CFR 261): ~ N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. iT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. B-~K~' SAND CONTROL MATERIAL SAFETY DATA SHEET EFFE~,VE DATE ~,c-223 NEBRUARY 19, 1988 I. PRODUCT IDENTIFICATION MANUFACTURER'S NAME ADDRESS ,~R S~ C0~0[ ~.0. ~0X 61~. EOUS~N. ~ 77208 EMERGENCY PHONE NO, P~DU~ NAME 713-~A3-7590 g-322 EZG~ ~~ S~R CHEMICAL DESCRI~ION ~. HAZAR~US INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER ~IC ~CID 5329-14-6 100 N/~ ~/~ ~/~ I!'1'. PHYSICAL )ATA BOLLING POINT VAPOR PRESSURE DECOI~OSHS ~ APPLICUtLH VAPOR DENSITY (AIR = 1 ) EVAPORATION RATE (BUTYL ACE~KATE = 1 ) NOT ~PLIC~LH ~ ~PLIC~LH SOLUBILITY IN WATER SPECIFIC GRAVITY (WATER = 1 ) SOLU~LH 2.126 VOLATILITY APPEARANCE AND ODOR NOT APPLICABLE WSITH CRYSTALS WITH NO ODOR [V. FIRE AND EXPLOSION INr-ORMATION ,ASH POINT EXTINGUISHING MEDIA I FLAMMABLE LIMI'I'.~ (% BY VOLUME) NON~ WATHR SPRAY OR FOC, FOUlo DRY C][]~I(X~h~R:I ~ UPPER: SPECIAL FIRE FIGHTING PROCEDURE.~ USI{ SIILF CO~AIMND BRHATHING APPARAIIIS WITH F~L ~ACI{ PIRCI{. COOL FIRR-~0~D CONtAINeRS USING #AIKK 5~'KA¥ UNUSUAL FIRE AND EXPLOSION HAZARDS ~0~ V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE · SKIN [] EYES [] INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE SKIN: IRRITATION EYES: IRRIYAliON {NHALAT{ON:NOSI{ AND THROAT IRRITATION O INGESTION: 0EU, LD-50 (RAT): 1.6 ~J/kg I-- CHRONIC (PROLONGED) EXPOSURE SKIN: aw, ~ EYES: NIH :z INHALATION:H/R m: INGESTION: W/R EMERGENCY FIRST AID PROCEDURES ~KIN: WASH THOROUGIil. Y WITH SOAP & WATHR. RTHS: FLUSH WITH WATHR AT LI{A~Y 15 MIN. · dINGI{STHD: DO NOT INDUCE VOMITING, GI~ FLRNTY OF WATHR. ~YRR GI~ ANY'IIIIMO BY '" }4Ob~ TO b'dCOiiSCi~S [MMRDIATHLY. NPTNO IARcNO OSHA: NO NO~ IDB~rIIFIRD SKIN. EYES VT. REACTIVITY INFORMATION HAZAR~US ~LYMERIZATION CONDITIONS TO AVOID THERMAL DECO~POSITION P~ODUCTS S0~. S03. ~F~ ACID. ~0~IA VII. SPILL OR LEAK PROCEDURES STEPS TO SE TAKEN IF' MATERIAL IS RELEASED OR SPILLED S~I~P UP OR SIIOVEL II, TO SUIT~Lll CO~AINERS. [A~ ~SIO~ ~I~ BXCESS WA~R. AVOID [LUS~IN8 ~ SE~R OR WA~RWAY. US~ P~SONAL F~CTI~ ~glP~ AS WASTE DISPOSAL METHOD USII RCM APPROVED ~AZAP, DOUS IIASTII DISPOSAL SlTII. CONSULT LOCAL. STAI'~. AND [~EP, AI, I~(~ULATION$ VIII. SPECIAL PROTECTION INFORMATION RES.,RATORY PROTECT,O. NiSiM COMC[MTi~TIOMS liXCI~RD I[~0SU[~ LIMITS. U~ [R~R NI0Sg ~P~D C~IDGE ~SPI~R. ~N LIMITS 0[ C~I~E ~SPI~ [XC[~D[0. USE NIOS~ ..OT~C~V~ ~OVES OTHER PROTE~tVE EQUIPMENT IX. HANDlING AND STORAGE IN~E~ATION AVOID B~A~ING V~0B/NIST ~ C0~ACT ~I~ ~IN. ~S. 0~ C~I~. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLAEXTREMELY HAZARDOUS SIJB~TANCI~S CERCLA HAZARDOUS SUJ~STANCES ~liS, [INLISTI[D ~Z/3J)0US NAS'II~ D002. Rg - 100 L~S SARA EXTREMELY HAZARDOUS SUBSTANCES SARATOXICCHEMICALS Il0 , OSHA HAZARDOUS CHEMICALS ~ IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHI~ONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): '~S. ]J~A ~iJ0U$ IJAS~ Il0. J)002 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED 'L THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BA~ SAND CONTROL -/'M~TERIAL SAFETY DATA SHEET ? ~SC--223 j ~RU~ 17~ 19~ L PRODUCT IDENTIRCATION ~ S~ CO~b ~.0. BOX 614~. E~, ~ 77208 MERGENCY PHONE NO PROOU~ NAM[ 713-443-75~ ~-620 P~ASSl~ C~ORIDS II. HAZAR~US INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER P~ASSI~ C~ID~ 7447-~-7 >g5 ~t k~ ~IS ~ DU~ S~I~ C~ID[ 7~7-14-5 (4 10 q/a~~ ~k~ DU~ (ACGID lJ.i. PHYSICAL DATA BOI~_tNG POINT VAPOR ~F-SSURE VA~R ~N~tTY lAIR = 1 ) EVA~RA~ON RAT~ {BU~L AC~A~ = 1 ) ~ ~PLIC~L! ~ ~PLIC~ ~OLgBILiTY IN WATER $~CI~C GRAVI~ (WATER = 1 ) ~ 1.98 VO~TIEITY A~RANC[ ANO O~R ~. ~1~[ AND ~XPtOSI~ IN~MATION FLASH ~INT EX~NGUISHING MEDIA JJ F~MMA~[ LIMITS (~ BY VOLUME) } ,~ ~'~U~]~ LOWER: ~ UPPER: SPECIAL FIRE FIGHTING PR~EDUR[S U~ ~ C~kI~ B~A~ ~P~S ~I~ ~L ~kCl PI~i. C~ [I~-~ C~kI~ USI~ UNUSUAL FiRE AND EXPLOSION HA~RO~ V. HEALTH EFFECTS INFORMATION PRIMARY ROUT£S OF EXPOSURE" ~] SKIN ]j~ EYES I'-I INHALATION [] INGESTION ACUTE (SHORTI EXPOSURE SKIN: IRILITATXOll, BURNS I! SKIN IS I~f EYES: JJ0D~J[~ ~0 ~ IRRITA~. ~ lfllALI~ CORliLtL I~ INHALATION:IRJLJTA~S JJ0~ ~ 'rJJJOAt. COUI~iXNO. CI~'~' DISC0W01~ CHRONIC {PROLONGEDI EXPOSURE SKIN: #Il INHALATION~/~ INGESTION: ~l~ POTENTIAL CARCIN~EN A~GRAVATION OF EXISTIN~ CONOI~ON~ TA~G~ ORGANS VI. REACTIVITY INFORMATION S~.BLI{ N0k~ S~0NG ACIDS ' · HAZARDOUS POLYMERIZATION ~ CONDITIONS TO AVOID #I~L N0Y OCCUR NON~ OXIDS$ O~ CONTANINATED METALS AMD Cm. ORIl~ YZZ. SPILL OR LEAK PROGEDURES STEPS TO BE TAKEN IF' MATERIAL IS RELEASED OR SPILLED SW]{~P UP OR S]{0V]{~ INT0 SUI?ABLI{ CONTAINRRS. U$I{ ?ERSON~tL IPR011{CYIV]{ I{~UI?~ AS N]{CESSARY. WASTE D~SPOSAL METHOD USE AP['ROVI{D WAST~ SII'E. C0NSUI~? LOC~, ~A~, AND l~lb~J, ~GULAIIffi$ VIII. SPECIAL PROTECTION INFORMATION RE~.,RATO.Y.ROTECT, ON ~ CONC~IiTRAYIOMS ~Clgfl) ~ LI~. U~ ~ NI~R ~PR0~ C~I~ ~I~. ~N LIMI~ 0~ C~I~ B~I~ EC~, U~ ~ ~P~ ~ C~ B~A~IK ~P~S WI~ ~L FAC~IEC~. P~OT[CTIV[ R~B~. ~. NIXIe. YI~ EYE PROTE~ION C~IC~ ~A~ ~ ~ ~ {AC~ ~ S~ ~/D~ ~ACILI~ ~ B~ AY~.~- ~. HANDLING AND STORAGE IN~RMATION MI~ ~IN C~ACY X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE [1! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATiON ACT OF 1986 (SARA). CERCLA EXTREMELY HAZAR{2)OUS SU~TANCES NO CERCLA HAZARDOUS SUBSTANCES SARA EXTREMELY HAZARDOUS SUBSTANCF'-~; SARA TOXIC CHEMICAL~ OS.A .AZA.DOUS C,£M~CALS {1 IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): ~0 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THiS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, iNVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. "~KER SAND CONTROL MATERIAL SAFETY DATA SHEET B5C--~23 J~ L PRODUCT ID~NTIMCATION 8~ S~ C~ ~.0. 80X 614~, ~OU~N, ~ '77208 EMERGENCY PHONE NO P~DU~ NAME 713-4~3-75~ S~l~ C~RIDE (SOCID OR SOL. ON) CHEMICAL DE~RI~ION I~RG~C H. HAZAR~US INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER P~ASSI~ C~ID~ 74i7-~-7 <S N/R N/~ * N/R At A~ ~IS~,~ DUST ~I. PHYSICAL DATA ~ ~IC~L~ ~ ~IC~L~ SO~L~ 2.165 ~. FIRE AND EXPLOSION IN~RMATION V. HEALTH EFFECTS INr-ORIVlATION PRIMARY RouTF.~ OF ~:XIJlOSUI~E j~] SKIN ~ EYES ~ INHA~TION ~ INGESTION SKIN: l~itI~ EYES: ~ ~ ~ I~tt~. ~ ~I~ C~ I~ INHALATIONI~I~I~S INGESTION: ~[ E YES: -- INHALATION[Ii INGESTION: ~/~ [M~RG[NCY ~I~T ~T[NTIAL CARCIN~[N AGGRAVkTION OF EXISTING CONOl~Ofl5 TARG~ ORGAN5 NP~ ~.~-t~ VI. REACTIVITY INFORMATION STABILITY CONDITIONS TO AVOID INCOMPATISILITY (MATERIALS TO AVOID} ST~JLE NOI~ ~ONG ACIDS HAiR.US ~LYMERI~TION CONDITIONS TO AVOID 0X[~S 0~ C~0E[~ V~. SPILL OR LEAK PROCEDURES STEP~ TO SE TAKEN IF MATERIAL iS RELEASED OR SPILLED SI~E' OR Sil0V1['L IHT0 SUITABLE C0~AI~RS. USE ~PRO~D llASTE Sin. COtiSULT I~Ckb. S~l~, ~ ~I~UiI, ~C~ITJ~S VIII. SPECIAL PROTECTION INFORMATION VeNTI~TIO" tlOVlD~ ~ ~LATI~ ~ ~ C~TI~ ~ ~S~ L~. ~ ~LATI~ ~Y BE ~C~SS~Y ~ ~ C~~ B~ E~ LIMITS. EYE P~TE~ON ~. HANDLING ANO STORAGE IN~EMATION X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE ]'1'I OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUB~TANCE,~ SARA EXTREMELY HAZARDOUS SUB~TANCE~ SARA TOXIC CHEMICALS OSHA HAZARDOUS CHEMICALS [] IMMEDIATE (ACUTE) HEALTH HAZARD r"J DELAYED (CHRONIC) HEALTH HAZARD J-~ FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD n REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ iTS LABEL. CITY of BAKERSFIELD 3'RADE sEcRETS ' p,~, J__ of .!.. BUSINESS NAME: BAKER SAND CONTROL OWNER NAME: BAKER SAND CONTROL NAME OF T~'~ FACILITY: SOUTH CHEMICAL WHSE. LOCATION: ~-5-5-~--A~RIN-C~[ ADDRESS: 1010 RANKIN RD/P.O. BOX 61486 STANDARD IND. CLASS CODE crrY, ZIP:. BAKERSF. IELD~ CA 93313 CITY, ZIP: HOUSTON, TX 7-7208 DUN AND BRADSTREET NUMBER P,ONE ~: 805_834_?R/.A PBONE #: 713-443-1590 Q9_ - _~5_7 _ - _7~_77_ _ Trans Ty~ ~x A~iqe ' ~l ~e~ I ~ ~t ~t ~t hi L~tt~ ~ % ~ ~ of Ntxt~/~tl ~e C~e 'Mt ~t Est Un,ts ~ Site T~ ~1 TM ~ .. St~ in FKtlity ~ b Inst~t~ u 1 MI 5,000 i 5,000 I 0 ILBSl 36S I ~21 ~ I 4 I ~1 SOUTU CHEMICAL ~SE. BRIDGESAL~ ......................................... ...... Fire Hazard ~--u Reactivity u--~ hla~ u--a ~ htme ~J c.A~s. ............................................................... ___ P~ical and Health HaZi~ C.A.S. ~ ~t II ~ & C.A.S. ~ ~¢~ al~ t~t apply) ~309-48-~ - ~--~ -- r--~ r--~ ~t I~ ~&C.A.S. ~ [ ] Fire Hazard u--u Mctivtty [ ] hii~ ~--u b him ~--J I/tltl 9004-32-4 _q_~_L_~ap. b=m9_ ] 0 ]~sl 365 [~D ~1 11 1 S°UTH CHEMICAL =SE. PLUGSAL (C~k all tMt epply) ' /~ __ Health of P~sure H~lth * ~t 13 ~&C.A.S. .~ ..... t_i ....... ,1 ............. L-, .... ~ ~ L--__~ .... ~_~ .... t ........... ~ical ~ HHlth ~Za~ C.A.S. ~ ~t II Nm A C.A.S. ~ (C~k ail r~t a~ly) . ' ~ -- r--~ r-- ~--~ CWt B~ NM& C.A.S. ~ Health of Pr~suPe Health ............... ?MEaGENCY C~TACTS It DON ~O~ DISTRICT ~NAGER 834-2844 82 CRIAG PA~ER FIELD SUPERVISOR "' 83422844 R;~-[ ............................... ~[1i ....................... ;l'~'P~i ........ ai~ .............. 7 ............. T1~1~ ...................... ~-~-~a ........ Cert~f~cat~ [~ead and s~n after coepJet~n~ a]] c~r%~fv ~de~ ~lty e~ 1~, t~t I ~ve.~s~ally e,a,m~ and aa fae~l~ar ,~th t~ t,for~t~ su~ttt~ t, th~ ~11 ett~ ~t~. a~ t~t ~ ~ ~ ~,~ o~ t~e t~1v~ei~ DON ~,, QOBBfDI$~IQ% ~AGER . ~.~..~ n~-e~'6T .,Eial'EiE1,-6T-~er75~r~iSF-OR'~76~F;E6~ ~-~6[6~i~;i~F~[~[i~ Si~[~;e .............. , ............................ ~)~ ~ '~'~ ................ i ,Material Sai'e!y Data Sheet November 5, 1985 ' ' ' A DIVISION OF TEXAS UNITED CHEMICAL CORPORATION 2000 WEST LOOP SOUTH, SUITE 990 HOUSTON, TEXAS 77027 I Chemical Name E~y Telephone Numbe, ~Sv.-~,-~, PROPRIETARY- BLEND 713 664-4911 ~ ~,~ PLUGSAL r~ N/A PROPRIETARY BLEND AS T.U.C.C. INTERPRETS THE U.S.OCCUPATIONAL SAFETY AND HEALTH ACT OF 1970, THIS PRODUCT IS NOT CONSIDERED A HAZARDOUS MATERIAL NOT APPLI,,CABLE ~ TLV (Un.s) Boiling Poh'd ('F) Specific Grev,ify (H~O-1) N/A 2.18 Vepof Prmute (mm Hg.) Pe~c~t Volatile by Volume (%) N/A N/A, VelXX Denelty (AIR-t) Evaporallon R~te N/A, "') N/A ~)lubil~ in Wete~ GREATER TF~N 99% LIGHT TAN POWDER WITH A FAINT, MILD ODOR ~xtJflgutshtflOModi8 _ , NON FLAMMABLE N/A N/A Unueu81 Fire and ExplosK)n Hazards NONE PLUGSAL ~ v. H#~ ~ D~ .......... , SEE ATTACHMENT THIS I~TERIAL IS NOT EXPECTED TO CAUSE PHYSIOLOGIC II~AIRMEI~ AT LOW CONCENTI~TION. UNTIL A SPECIFIC TLV IS ADOPTED BY THE A.C.G.I.H., THIS MATERIAL MAY BE TREATED AS A I~IS,~CE DUST OR PARTICULATE MECHANICAL CLEAN-UP FOR USE OR DISPOSAL DISPOSE OF IN LANDFILL IN ACCORDANCE WITH LOCAL, STATE ~ FEDERAL REGULATION. Relpketo~/Pr~n (~ T~) ~IS~CE DUST ~SPI~TOR ~PROVKD BY NT~R~/~R~A TM ~qTV~ ~T~ CONC~NT~ATTONS Ve~t~ L~l Exhaust ! ~ial SAT I SFACTORY MAY RE TREATEn AR ~TTRAM~F ~AP~T~IW ATF GOGGLES Ol~er Preceulions (Rev .~ , · PRODUCT NAME : ATTACHMENT HEALTH HAZARD II~ORMATION NON HAZARDOUS MATERIAL OSHA Permissible Exposure Limit: NO~E .'ESTABLISHED ACGIH Treshold Limit Value: NONE ESTABLISHED Primar~ Route(s) of Exposure/Entry: IN'HALATION, SKIN, EYE. Acute Effects of Overexposure: Ingestion: Not intended for human or animal consumption - may cause nausea I~hilation: May cause nose and throat irritation Skin Contact: May cause dryness to skin Eye Contact:May cause irritation and redness Chronic Effects of Overexposure: None known Listed as Carcinogen or Potential Carcinosen by: NTP no IARC no OSRA no ~RCL~CY AND FIRST AID PROCEDURES: Ingestion: Consult physician. D~ink large amounts of water Inhalation: Remove to fresh air Skin: Wash with water Eye: Flush with water. If irritation persists, get medical attention. We cannot anticipate all conditions under which this information and our products may he used. Users may %fish to make their o~n tests to determine the safety and suitability of e;ich product or product combination. DIVISION OF' TEXAS UN~TED CHEMICAL CORPORATIOf~ 2000 WEST LOOP SOU'I'H,~UITE 990 HOUSTON, TEXAS 77027 ~,ectm~l I Chemtcll Name Emergency Telepr)0r~e Number and SynOm/m$ PROPRIETARY BLEND 713-664-4911 I~d Synonyms BRIDGESAL C~emical Fam~y N/A PROPRIETARY BLEND As T.U.C.C. interprets the U. S. Occupational Safety and Health Act of 1970, This product is not considered a hazardous material. Not applicable ~. III - ~ D~ta BOiling P~nt ('F) ~cifiC N/A~ 2.18 vapor P~sure (mm Hg.) .... P'~enl v0~al,le by Vo~u~ (~) ...... ... ~/A .............. N/A va~r D~s~ (AIR-t) ~Evapora,o, Rate ... . ..... N/A ~) N/A ~lub~i~ ~ Waler Cr~r tbsn 99% . L.~ght tan powder witb'a faint, mild odo~ FlashP~nt(~l~U~d)NON FL~LE ,IFl~mmab~Limds'N/m ~Le, ~Oel E~mguishing M~ia ~A~[[~ C0~ 0[ ~0~ S~ial F~e Fitting Pr~ur~ Non~ (Continued on Reverse l~lde) re.,. '.'.*~A.2~'; k~t4n ~- ~lm ~lrd DiM SEE ATTACHMENT NOTE: This material is not expected to cause physiologic impairment at low concentration. Until a specific TLV is adopted by the A.C.G.I.~.~this material may be treated as a nuisance dust or particulate. kotlofl VI - Ammttvlty Data ~tabltlty Unmtable Condition8 to AvoiO Stable Incompatibility (Me.rials to AvoiO) NON~ ~HO~ 1 H~arO~ Decom~aition Prnducln NO~[ ~0~ ~'~aous ;May Occur Co~ltton~ lo AvolO ........... Poly~rlzntion Will Not Occur 51epa lo De Taken In Case Material is flelealeO o~ Spltle~ Mechanical clean-up for use or dis~osa]. Max, contribute to slier. ~urf~c~ if incompletely removed. Waste Diapoaal Me<hOd Dispose of in landfill in accordance with local, State and Federal regulations. lectle~ VIII - ~ Proleotlon Intormatten Respiratory Protection (Specify TyDe) Nuisance dust resoirator aooroved bv NIOSHA/MSHA in excessive air concentrat~.ons,.. Ventilation I Local Exhaust ISpec~a~ I Satisfactory' r Mechanical (General) I Other JMay be treated as nuisance particulate Protective Gloves I Eye Protection · { Goggles ' . , Other Protective Equipment Pt'ecaulions lo De Taken in Handling end Storing Surfaces subject to spills or dustin~ with the product can benome s]~pper.x., when wPt Keep floors clean. Other Precautions Pmge 2 r~,... OS~' IRev ,, ~P~O~UCT NAME : ATTACHMENT BRIDGESAL HEALTH HAZARD INFORMATION NON HAZARDOUS ,MATERIAL OSHA Permissible Exposure Limit: N~E ESTABLISHED ACGIH Treshold Limit Value: NONE ESTABLISHED Primary Route(s) of Exposure/Entry: INGESTION, SKIN, EYE. Acute Effects of Overexposure: Ingestion: Not intended for human or animal consumption - may cause nausea I~hilation: May cause nose and throat irritation Skin Contact: May cause dryness to skin Eye Contact: May cause irritation and redness Chronic Effects of Overexposure: None known Listed as Carcinogen or Potential Carcinogen by: NTP no IARC no OSHA no EMERGENCY AND FIRST AID PROCEDURES: Ingestion: Consult physician. Drink large amounts of water Inhalation: Remove to fresh air Skin: Wash with water Eye: Flush with water. If irritation persists, get medical attention. We cannot anticipate all conditions under which this information and our products may bo used. Users may wish to make their own tests to determine the safety and suitability of each product or product combination. M,lterial Safety Data Sheet i O "-'-November 7, ;1985 A DIVIS~N ~ TEX&S ~ITED CHEMIC~ C~A~I~ CAS ~OS= ~309-48-4 9004-32-4 2~ WEST LOOP SOUTH. SUITE ~0 HOUSTON. TEXAS 71027 ~tt~ I C~m~al Name Emergency Teleph~e Number ~dSy~ms CELLULOSE DERIVATIVES ~ AL~LINE EARTH OXIDES 713 664-49~ 1 a~ Sy~,,,~ POLYTEX HT C~cel F~m~m Fem~y N/A PROPRIETARY BLEND CONTAINS NUISANCE DUST H~t,~ou~ NOT A~PLTRABT,~ N/A 2.6 V~or Pr~ure ~ Hg.) ~P~ce~l vcalile ~y vcu~ (%) ~PRECI~LE ~ITE G~~ PO~ER, ODO~ESS ~/~g~shmg S~ial F~e F~ti~ Pr~ur~ Unusual Fira and Explosion Hazards TREAT AS FLAMMABLE DUST IN FINELY DIVIDED AND SUSPENDED STATE Page I (Continued POLYTEX HT ;~*,etie~ V - H~I~ H~erd SEE ATTACHMENT k~llen VI - Re~lhrlty Data ~abllity Unsleble Conditions to Avoid Stable Incomparability (Materials to Avo~cl) ACIDS Hazarc~oul Decomposition Proclucts -lazardoul May Occur ConOItions to Avoid ~o~ymedzetton Will Not Occur le~lut ¥1l · Iplll or L#k Proo~l~r~ M'F,C,~A'I~T(q, AT, CT.~'AN-TTP ~P T~T~'P~qAT Wa~eDm~ulMmhod DISPOSE OF IN LANDFILL IN ACCORDANCE WITH LOCAL STATE A~ FEDERAL REGULATIONS leeilen VID - I1~ Respiratory Protection (Specify Type) NUTSANCE DU~T RES]STRAT~R APPROVE]3 BY NT~R'R/'HR'RA , Ventilalg)n .. I Local Exhaust · I TREAT AS NUISg2,ICE BUST Protectn~e Gloves ' 1 Eye Protect,on STAND~ I GOGGLES Other Pro~ective Equipment le~llml IX - Ipe4:~ial Pre~eutiona Precaullons IO be Taken in Handling an~ SlorJng KEEP DRY MAY CONTRIBUTE TO SLICKNESS OF SURFACE IF ALLOWED TO BECOME WET Other Precautions Page 2 r, .*,, OS~' · {Rev .'t ,,. ~RODUCT NAME : ATTACHMENT POLYTEX HT HEALTH HAZARD INFORMATION NUISANCE DUST OSHA Permissible Exposure Limit: NOT ESTABLISHED ACGIH Treshold Limit Value: 10 mg/M3 Primary Route(s) of Exposure/Entry: INHALATION, SKIN, EYES. Acute Effects of Overexposure: Ingestion: MAY CAUSE NAUSEA I~hilation: MAY CAUSE DRYNESS OF NOSE AND THROAT. Skin Contact: MAY CAUSE DRYNESS Eye Contact: MAY CAUSE IRRITATION & REDNESS Chronic Effects of Overexposure: NONE KNOWN Listed as Carcinogen or Potential Carcinogen by: NTP no IARC no OSHA no EMERGENCY AND FIRST AID PROCEDURES: Ingestion: INDUCE VOMITING. CONSULT PHYSICIAN Inhalation: REMOVE TO FRESH AIR Skin: WASH WITH WATER Eye: FLUSH WITH WATER. GET MEDICAL ATTENTION We cannot anticipate all conditions under which this information and our products may be used. Users may wish to make their own tests to determine the safety and suitability of e~ch product or product combination. CITY of BAKERSFIELD N O IXl-- T R/~ D l]C ~c3 I~ C R !~3 T S ' .~ ~._. of .~.. BUSINESS NAME: B~ER SNAD CONTROL 5551 ALDRIN CT. ADDRESS: lOlo-~KI~ ~.~] ~ox 61486 STANDARD IND. C~SS CODE C~TY. ZIP: B~ERSFIELD, CA 93313 CITY, ZIP: HOUSTON, TX 77208 DUN AND BRADSTREKT NUMBKR V.O,~ ~: gns-gq4-2g44 Pao. E ~: 713-443-7590 ~_ - ~52 _ - ~3~7_ _ A P . . .... 1 .... ] 3,000 1 3,000 J ~,000 IL~sl P~,c~! ~ ~lth ~ C.A.S. ¢c~k ~11 t~t truly) -- r--~ -- r--~ ~~ ~ & C.A.S. ~ of ic.I ~ ~lth ~ C.A.S. ~lth of ~ ~lth ............. k iii t~t ~ly) - - AMINE/GLYCOL MIXTURE ~lth of Pm~ ~lth ~t (C~k ail t~t 15 ZTgRCO~ OXYCHLORIDE 7699-43-6 of Pr~ ~lth ......... .................................. [~r ~18 ~ DON COBB DISTRICT ~AGER 83~-28~ ~ C~IG ~A~ER FIELD SUPERVISOR 83~- C~t+ficati~ (Read and ~ after coepJe(Xn~ pON B. COBB/DISTRICT ~AGER . ....at rial Safetv Data Sheet ~P~r:~re detailed Information on the h~ards of this product, contact Regulations Compliance Depa~ment or ~edical:~ - ~.Ge~ices Depa~ment at the address above. Technical Information Bulletin is a so avai able. For emergency Ioformation,'~'~ ~RODU~T IDENTIFICATION PHYSICAL AND.~HE~I~AL PROPERTIE~; ~rand' Name. ;...' .........TRONA soda ash State Grand Boiling Point C ................... DecOm'po'ses ~': ...... DOT. proper .' . .. Odor ........................... ... No~e ~ · ~R~ ....... " ' ' Flash Point And Method ........... Not ap~licable'""~ =p~able.Quantity (RQ).. Not applicable :Chemical Name,':-' - comm~n Name(s) . . ,.~..,:~.~ive: No Upper Explosive Limit: Not applicable Lower Explosive Limit: No~ applicable ?::Flammable: No Flammability Class: Not applicable . ,,'{ .' :~.~:::.,U.?:'.COmbustible: No organic Peroxide: No ~' ~:~':Oxidizer: No Compressed Gas: No "~ ,~'~,:',,,:: ..Reactivity: 'Normally stable. May react violently with strong acids. Carbon dioxide gas and large, :~ '"'"~:" '~¥"~' quantities of heat can be evolved. Reacts with hydrated lime in the presence of 'moisture .'~,~?'::::-:" to form caustic soda, a corrosive. ammoniacal silver nitrate and molten lithium. ~ H~at~ous'~"::":"' Soda ash 'decompOses at temperatures above 1000C, releasing carbon diox'id ,"g~' (CO~,:~: Carbon dioxide is an asphyxiant and may affect,r~spiration rate or Interfere with breathing. The sodium oxide residue sublimes at 1275C, forming vapom and m~sts of cau{~c soda on '-" contact with moisture or water. ' ':~ - ' Conditions D0 not expose to intense heat. ~ " . To Avoid: -~ --,. -.:-,, -j~,~.:.PreCaUtl;n'ry !nfo?mation: CAUTION! Causes irritation. This product isa severe irritant ,o the eyes.and I~i;;':'SY,mPtoms Of Exposure: Eye, nose or skin irritation. ::.,:}.?.,.;'??~¢~;..:.¢.~. ,. .... Burning sensation to nose, throat and eyes. ~":?" . Sneezing and coughing. ---r,Medical Eye'or'Skin disease and breathing or respiratory disorders will be aggravated.,..~_ ~Restrictive ~ioqn,.cl. .................. by exposure to this chemical. :e'J~nd skin contact, Inhalation (breathing), and Ingestion (swallowing). TOXICITY INFORMATION · Orai-;'rat LD. 2463 mglkg; I ntraperitoneal - mouse LD,0 117 mglkg; ' Skin Irritation - rabbit 50 mg124 hour, moderate; Eye irritation - rabbit 100 mg124 hour, severe. . ~OSH~.i'):·!': Not established. ~ACGIH:' · Not established. ~:?Other: ACGIH - TLV-TWA for nuisance dust is 10 mg/ma total dust or 5 mglm~ respirable dust. ~ As A Potential Carcin(~gen IX,1. Not Applicable [] ~ational Toxicology Program I-I OSHA r-i International Agency For Research ~n °an'0er .-, ...... PRECAUTIONS FOR SAFE HANDLING AND USE id.contact.with'eYes, skin, and clothing. lng dust.' · uate -Ventilation~ .- ~poontainer closed when not in use. ~Wash thoroughly after handling. SPILL AND LEAK PROCEDURES ''" ...... i~'"'":~%Shovel and sweep ui~ Dispose of in a chemical waste facility as permitted by' f~deral ' ,:. :!i!):'~.'(RCRA), state and local regulations, ~?~::~-: Dilute and disperse with water ]ets~ propellers or similar agitation techniques. ~' '?.' ~.- ..??'. Keel~ upWind. T~'e~i i~i~(~t site as appropriate for soil or water spill. ' Spill:~' .Shovel and sWeep'up. 'A~ permitted, small spills may be washed to an industrial s~wer. ~ i;},?. Large amounts can be disposed of in a chemical waste facility as permitted by fed~ral~ "? ' ' :'state and local regulations. . ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT /entilation: ~: .~ Use general dilution and local exhaust ventilation techniques to meet nuisanc~dust ~.-. : exposure limit. ' ! ' · ?~.~ '.R?..Pirator: Use NIOSH/MSHA approved dust type respirator, · Eye Protection: Use safety glasses or safety goggles. Ensure eyewash fountain is located ih imm~dlat ".. work area. - Use gloves that will not allow alkaline solutions to penetrate. thing': -..'...,.-:..--..-.;. Wear easil~ washable clothing. Change dally or' ~ore often if contaminated. Wash · -:.':- ' :clothing before reuse. ~'.-.~'~,_~:;t~:~;~: ~ ..' ..................... . :;~t"-~?.;:,..... ':?:~'~C'~' ' EMERGENCY PROCEDLARES '.,. ' ~'~ Fire:'~;:~',~' i" TM - This product Is not flammable and does not support combustion. ~ , -~,: ~., ~;..~~ :, ~' .- - ~ .: .,L :,. !." . ..~'~'~... '.:' . . ~ : -~," :. ~, i-:~~ . [~i.'Spill or Leak: Sweep up and shovel into Containers for later disposal. :~ " ' -'?~--'¢'i';" -'' :, ~' ' .i..'....:~}i~: :' · ,,' . '. "?..' ' . ' " "'~:'":' · . . '-~:':": . . ~.' .: . ,': .... ., _,.. . ..:.;. 'i. ' ..... ~, : ....::,~.T;. - :. .-..." '. ,.... ":: · PROCEDURES . -. · redl uce'vomiting.'Give'large quantities of water. Ne~er gi an ;~ by'. ...... '~'" ' ~o"an unconS.c~!o~s.:Pe'.rsOr~. Call a phYsiciah. :. ~ii',F.,?::..'i.'., :~ . ..... ,'.': ",:, .~/i.,,:",-.,, ,,~.~:~'~?- ,~:,:~,.: ,,:: · ~.. . , , ... ,~,' ~ .- ;. . . · ': · ~ ' , ~ -. ' ,/ '~.,~-"'a "V"~?' '""~" If inhaled, remove to fresh air..If not breathing give artificial respiration, preferably mot =' ........ -": "~ '"'.. :" mouth. If breathing is difficultl give oxygen. Call ~ physician. : . ..: . -..'..~-~.-~i '..'. · Contact: Flush with plenty of water. Wash clothing before rei~'~:Oroughly clean shoes before. reUSe.;` Eye COntact: 7~' Immediately flush eyes with plenty of water for at least 15 minutes. Gall a physician. '" .:; .. Note To The chemical of exposure is sodium carbonate which is alkaline in solution. ':Physician:'" .? .:....,. , ~ ~?, ,... oF"ISSUE: Jun~e, i985 DATE REVISED: Original REPLACES: TP 8010110-80 \KER SAND CONTROL .~.'JT£RIAL_.~.~. SAFETY DATA SHEET £FFECT,¥E L PRODUCT IDENTIFICATION MANUFA~URER'$ NAME ADDR~S ~ S~ CO~O~ g.0. ~0X 6]{~, EOUS~N, ~ 77208 EMERGENCY PHONE NO. J P~OOU~ NAME ~. HAZAR~US INGREDIENTS INGREDIENT CAS NO. APPROX % OSHA PEL ACGIH TLV OTHER ~RO~ C~OS~ g00~-62-0 >~ ~/~ ~ ~/~ ~ H/~ * ~AZ AS ~]S~Cg DUST OS~ . ACg]~ 3 ~ OUST 1~ ~/~} 10 ~S~I~L~ DUST 5 .g/.- ~I. PHYSICAL DATA N~ NO~ N~ NO~ SOL~ 1.38-1.40 ~ 60"~ (15.6'C) ~0~ ~I~ POKgR ~IH KILO C~C~RISTIC ODOR ~. FIRE AND EXPLOSION IN~RMATION '~ ~CO~Oh ~ ~0~. C02 LOWER: NO~ uPPeR: UNUSUAL FIRE AND EXPLOSION HAZARDS AVOID DISPIiRSION 01~ DUST IN AIR TO P~D~I! POTS~IAI, I~OR DUn IONITION/IIXPLOSION. DUSt IS llASILY ISNI~D. V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE ~[] SKIN ~] EYES ~[~ INHALATION [] INGESTION ACUTE (SHORT~ EXPOSURE SKIN: mO IlVIDENCII 0l~ AOV~Sll ~I.qlCTS EYES: DUn lily BR NINIIIALLY I~ITATI~, CAUSINO DISCO~Oi~ ~ WILD LICESS ~DDIININO O~ ~ CONJUI~IVA INHALATION:mO II~ORI~TION AYAIIABLE INGESTION: N0 ~'IDIINCII 0~' AOVZ['RSI1 ~CT$ CHRONIC (PROLONGED) EXPOSURE SKIN: EYES: ~IS PR~T M~ C~IB~ ~ ~IS~R DU~ ~ ~SIBLR ~ ~SPI~LR DU~. INHALATION: ~ ~ ~CTS C~ ~. INGESTION: IASR SKIm HOROUG~Y ~IH SO~ a ~A~R. IE I~ g~S. I~Igl~ ~I~ ~ ~A~R EOR AT LEAST 15 NI~S. ~CASIOH~L~ ~HTI~G POTENTIAL CARCINOGEN AGGRAVATION OF EXISTING CONDITIONS J TARGLrT ORGANS N Pml~0 IARCN0 OSHA: ~0 ~01{~ I N0[~rJ~ VL REACTIVITY INFORMATION ~ CONDITIONS TO AVOID j iNCOMPATIBILITY {MATERIALS TO AVOID) HAiR. US POLYMERI~TION THERMAL DECOM~SITfON PRODU~S STEPS TO BE TAKEN IF MATERIAL IS REL~SED OR SPILLED WASTE DISPOSAL METHOD USE RC~ ~PROV~D HAZAPJ)OUS #AS~ Dlfl'OSAL SI~. CONSULT LOCAL. STA~. ~ FEDERAL i~GUI,ATIONS VIII. SPECIAL PROTECTION INFORMATION RESP,RATORY PROTECt,ON DUST R~S2IR~OR II DUSTING CONDITIONS SXI~. v~.z.~z,o. FEOVIDE G~ ~ILATI~ ~P CO~TI~ B~L~ ~0~ ~I~ITS. ..o~e~,v~ ~ovEs ~VC EYE PROTE~ION OTHER P~TE~IVE EQUIPMENT ~ [~. HANDLING AND STOEAGE IN~RMATION X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE [[! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUBSTANCES NO CERCLA HAZARDOUS SUBSTANCES N0 SARA EXTREMELY HAZARDOUS SUBSTANCES NO SARA TOXIC CHEMICAlc;, OSHA HAZARDOUS CHEMICALS [] IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (C~tRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA. 40 CFR 261): ~0 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. CO,','r.oL .~:-223MATERIAL SAFETY DATA SHEET I. PRODUCT IDJNTIF:ICATION MANUFACTURER'S NAME A~DRF.~S BAIOKR SAMD CON'I'R0b ['.0. BOX 61486. "iX 77Z05 £MERGENCY PHONE NO. PRODU~ NAME 713-4~3-7590 W-3SO RIG]{ ~E{A~IIR~ CHEMICAL AMIN~/GLYCOC MI X'IllR~ PREPARED BY: GL;NN ~$CREWSKI H. HAZARDOUS INGREDI{NTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER AMIN~/~YCOL MIKI1JR]{ HI]{ 100 #1]{ N/I{ ]]]. PHYSICAL DATA BOLLING POINT VAPOR PRESSURE 225')' (107.2'C) 11.7 U ]{g ~1 68'[ (20'C) VAPOR DENSITY (AIR = 1 ) EVAI~2)R~TION RAT[ (BUTYL AC['TATE = I ) 2.41 1.11 SOLUBILITY IN WATER SPECIFIC GRAVrTY (WATER - 1 ) SOLUM~ 1.123~ ~1 6~'[ (20'C) VO~..ATILJT'Y AP~c. ARANCE AND ODOR 15~[ (v/v) ]{l~O~lil ].IgUID WX~ J%}~I{Di~iA lDO(X{ IV. FIRE AND [XPI.~ION {Nr. ORMAT{ON ASHPOINT EXTINGUISHING MEDIA J FLAMMASLE LIMITS (% BY VOLUME) * ~ #~I~!~ Sfl~3/t;1~/~0g. C02 J LOWER: il/! I UPPER: SPECIALFIRE FIGHTING PROCEDURES SFFJ%! UNUSUAL. FIRE AND EXPLOSION HAZARDS V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE [~ SKIN ~ EYES [] INHALATION [-3 INGESTION ACUTE (SHORT) EXP~URE SKIN: il0~ II)~NYIH~ EYES: MINOR YEII'0RAR! C01{~ INJUI~Y INMALATION:IlgJJ~ IDIKWYI~I{n z O_ INGESTION: ilAl l-- CHRONIC (PROLONGED) EXPOSURE ~ SKIN: ffi IDBITI~I~ ~ EYES: !~ N EME~ENCY FI~T AID P~EDUR~ POTENTIAL CAR<~INOGEN J ~,~RAVATK)N OF EX. ISI'~NG CONDITIONS TARGET OJ~GANS NPT..#0 IARC:#0 OSHA: il0 J ~ ll)~T[;I~ !~$ ~I. SPILL OR LEAK PROCEDURES SNALL SPILL: CO~R WITS S~ SE~R/~A~RNAY. ~S~R ~ H~DI~ T~. ~ ~SID~ WI~ S~ OR C~CI~ ~S~E~ ~ ~LACB IN SUIT~LE C~kI~. USS ~SRS~ PR~C~ S~P~ AS ~CSSS~Y. WASTE DISPOSAL METHOD USS RCHA APPllOt~D HAZARDOUS IIASTS DISPOSAL SITS. CONSUL! LOCAL, STATS, AND ~IIHAL RSC, ULATIONS SPECIAL PROTECTION INFORMATION EESPIRATORY PROTECTION m ~R~D Itl ~ USS. VENT'LATION PROVIDE b~INSRAL VllNTILATION TO i~ CONCSNTRATION BSLOtl NLrfsANCll l~"/llI,. LOCAL ¥1~I?II~TI011 NAY BE h*~CIlSSARY TO ~ CONCIINTHATIOR BSLOlt ~ LXMXTS. PI~OTECTIVE GLOVES NSO~RSI~ OR NITSILS EYE OTHER P~OTECT, VE E~U,PMENT C~KICAL RSSIST~IT ~TS. Al~--lt~. OR SUIT NA! BB I~CSS$~Y IN ~iD S~V~ SSOlf~R/DRIINC~ING ~ACILI~f SSOULD SS AV~ILA~LS. IX. HANOtlNG AND STORAGm~ AVOID S~AT~IN~ VAPORS/MIST AND CONTACT illTH SKIN. il!SS. OR CLOTSIK. ~ OORTAINSR TIGHTLY CLOSSD ~ NOT IN USS. HAZARDOUS RSSIDUB MAY RSNAIN IN ~ DRY. DO NOT RSUSS CONTAIBIRS. PI~t£TICS NORI~ GOOD ~8RSONAL X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CER'CLA EXTREMELY HAZARDOUS SU~TANC~ CERCI.A HAZARCX)US SuI~STANCES SARA TOXIC CHEMICALS OSHA HAZ~eDOUS CH£MICALS ~] IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 26]): ~0 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. B~AKE'R SAND CONTROL B5C--223 Il EFF'ECTIVE DATE MATERIAl. SAFETY DATA SHEET Il FI[]tRUlY 23. 1988 I. PRODUCT IDENTIFICATION ' ~NUFA~URER'5 NAME .~ S~ C0~0~ E.0. BOX 614~, ~0US~N, ~ 77208 713-443-7590 W-315 BC GEL II CROSSLI~ING C~EMICA~ DE~RI~ION ~. HAZAR~US INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACG~H TLV OTHE~ ~]~COB[~ 0~C~0R[D~ ?6gE-&3-6 ]5 * 5 ~/m3 ~/~ B/k · AS Zr ** C~ILING l/l. PHYSICAL DATA BOLLING POINT VAPOR PRESSURE 221'F (lOS'C) N/ii VAPOR DENSITY (AIR = 1 ) VAP~ATION RATE (BUTYL ACIETATE =1 ) Ii/ii N/ii SOLUBILITY INWATER ~:~:~ClFtC GRAVITY (WATER = 1 ) SOLU~LII 1.36 VOLATILITY AP~a~ARANCE AND ODOR N/Ii ~I,IG~fLY Y~LLO# LIQUID #In IICL ODOR IV. FIRE AND EXPLOSION INFORMATION _ASH POINT EXTINGUISHING MEDIA FLAMMABLE LIMITS (% BY VOLUME) I NO~ C0NEUS~IBLII IF I~0LVE0 IH FIEf. J(An[[ SE[~Ji. lJ LOWER: ~ JUPPER: SPECIAL F.IRE FIGHTING PROCEDURES U~ SIILF CO~AINED B~AnlNG ~PAPJtTU$ #In [qJLL FACII PIIiCii. COOL lq~-~D CONTAINERS USING WATER Sg~ UNUSUAL F'IRE AND EXPLOSION HAZARDS 0 TOXIC ~ ~.~,~.~t~I~.~I~U..~ VA~S/FUX~S (IICL) EVOLVED ~ON CONTAC? Win #ATRR OR' bi'Ea. RTORODII, GAS (ii2) II¥OLVED V. HEALTH EFFECTS INFORMATION ,MARY ROUTES OF EXPO~.~RE l_J EYES [] INHALATION [] INGESTION CUTE (SHORT) EXPOSURE SKIN: CORROSIVE, TI$$~ D~IA~, BURNING, b'TRONG I~ITATI~ EYES: STRONG II~PRR R~$PIRATOR! 11~ACT IRRITANT, NUCOUS ~ DANAb"E Z INHALATION:coRRosIVE ~0 TISSU~ CONTACTS O INGESTION: I.- CHRONIC (PROLONGED) EXPOSURE SKIN: i EYES: z_ ~N~ALAT~ON.N/II INGESTION: / : rml'll, Rn: RRI,fOW '1'0 PRR~R AIR, AflNTNTgTRR OXTfiRN DR ARTTF'TCTAI, ~R~PTRA'I'T('~N k~ N1L'TZhR'h m dOflTff TO flNf~ON.~f~TOl]~ PRR~ON TN ALL ~A~R~ OF fiONTA~T .~RRK Nlti~T~kL ATTRHTTi~N [14]~Dl knl,T. POTEN~ CARC.N~£N N0 NO AGGRAVj~y~. o, £X,ST, NG ¢O.D,T,ONS 2J~: '~S,TM^ RRSPIRATOR~ NPT: IARC: OSHA: -~l~ $'~ rY. REACTIVITY INFORMATION COND,T,ONS ~0 ~O,O ) ,HCClIi,bEIE~Iyll~i~,L~UI~M~9?~I~IDES' MIL& ~ THERMAL DECOMPOSITION PRODUCTS ~ ~ID) (~), ~)N (~) ~, ~I~ (~) VII. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED WE~ ~E'R0~RIA~ C[,0~IN(~/EESE'I~TORY E~UI~'I~lff I~ ~XlCl~0SI~ ~S/V~0RS. ~[ S~Ib~: IbUSH MI~ ~[C~SSIB NA~. b~) B~I~L: DI~ ~ 2~ ~RI~ SE~/MA~MA)S. ~I~ MI~ S~k A~. LI~. ~VID~ FORCED ~ILATION ~ DISSI~A~ I~ ~ ~IM~CES ~LOW. VIII. SPECIAL PROTECTION INFORMATION RE~P'RATORY PROTECT{O" NIOSH APPR0~D I~ULL )kCl{ ?I~C~ C]{~MlCl~ CARIIIIDG~ ~I~. SHL~ C~AI~D B~A~ING ~P~S WI~ I~L )ACE PIEC). AI~I~ EYE PROTE~/ON OTHER PROtE~IVE E~UIPMENT ~. HANDUNG AND 5~OEAGE IN~E~ATION C0~1~ bI~. ~ IN C~L ~E). ~I~ ~. ~ C~ ~ C~ ~ N~ IN U~. ~)~0US ~SI~ ~l ~IN X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUBSTANCES Y~$. SAS 0M&Y (I{YI)R0{]~ CBII)RIDE) R~ - 1 LB CERCLA HAZARDOUS SUB~TANCE~ YBS. ~YDROC~II)RIC ACID R~ - ~00 lBS SARA EXTREMELY HAT-ARDOU$ SU~TANC~ Y~S. OAS OgLY (HYDRO~N C~)RID~) ~T~ - 500 LBS SARA TOXIC CHEMICAL~ NS. lffl)i~]l~IC ACID OSHA HAZARDOUS CHEMICALS X-} IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD E~REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): ~1~$. ~DA ~Jt.Z.lll~,~J$ #Ab1~ ~0. ~002 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKERSFIELD CITY FIRE DEPARTMENT I~ E C E [ 1/E r~ r/i 2130 ,,G- STREET BAKERSFIELD, CA 9:330:1 JUN 3 0 1987 (805) 326-3979 ~~O AIls'Ii ............ OFFICIAL USE ONLY BUSINESS NAME HAZARDOUS MATER I ALS BUSINESSFORM PLAN 2AAS A WHOLE INSTRUCTIONS: 1. To avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local'fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE B. ELECTRICAl: C. WATER: D. SPECIAL: E. LOCK BOX: YES /~ IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 2A - SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE SECTION 5: LOCAL EMERGENCY MEDICAL ASSIST~CE FOR YO~ BUSINESS AS A ~HOLE SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A P~0GRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAZARDOUS MATERIALS:...- .................................... ~ NO ~ NO B. PROCEDURES FOR COORDINATING ACTIVITIES C. PROPER USE OF SAFETY EQUIPMENT: .................. NO NO D. EMERGENCY EVACUATION PROCEDURES: ................. NO ~ NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... NO NO SECTION 7: HAZARDOUS MATERIAL CIRCLE YES OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN $00 POUNDS OF.~% SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES ~NO~ I, ~C~%.~O%~, certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.98 Sec. 25500 Et Al.) and that inaccurate information constitutes per3ury. BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID~ BUSINESS NAME: BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. SECTION 1: MITIGATION, PREVENTiON~ ABATEMENT PROCEDURES SECTION 2: NOTIFICATION AND EVACUATION PROCEDb~RES AT THIS UNIT ONLY - 3A - SECTION 3: It~ZARDOUS MATERIALS FOR THIS b~lIT ONLY A, Does this Facility Unit co~tain Hazardous Materials? ...... ~ NO If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES',~ If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form ~4A-1) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form ~4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY E~RGENCY RESPO~ERS A. NAT. GAS/PROPAN~'¥ D, SPECIAL: E. LOCK BOX: YES /~ IF YES, LOCATION: IF YES, SITE PLANS? YES / ~0 MSDSs? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 3B - . BAKERSFIELD CITY FIRE DEPARTMENT FORM 4A-1 Page , '-_of~' NON--TRADE SECRETS HAZ ARD-OUS IVlATERI ALS INVENTORY )USINESS NAME: Baker Sand Control OMNER NAME:Corp· (Baker Sand Control) FACILITY UNIT #: ~DDRESS: 5551 Aldrin Ct. ADDRESS: 1010 Rankin Rd. FACILITY UNIT NAME: ZIP: Bakers£±eld, Ua. 93313 CITY,ZIP: Houston~ Tx. 77073 ~: (805)834-2844 PHONE #: (713) 443-7590 OFFICIAL USE CFIRS CODF 2 3 4 5 6 7 8 9 l0 MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD O.D. AMOUNT ,AMOUNT UNIT CODE CODE FACILITY UNIT MT. CHEMICAL OR COMMON NAME COI~E GUI[ ~ ~ LB'---~' -T~ 1--~--- Sout Chemica areho ~ 286 286 LBS 11 11 South Chemical Warehouse Magnesium Chloride None None 220 220 LBS 11 11 South Chemical Warehouse ~ Magnesium Oxide ~ , ~ None None ~ ..... ~ ~/~_S ~ o._ , 10,000 35,000 LBS 12 1i South Chemical Warehouse ~ Hydro~thyl Cellulose None None .... , -~-~ -l~ ~ ~ South Chemical Warehouse ~ ' ~carbona e '~ -None / 75 75 LBS 12 11 South Chemical Warehouse ~ Borax -~=~ ~cl~, None None ~ 10 10 Ton 12 ii Northwest Sand ,,=-~house oianomaceous ~arth None None ~o0 509 To,, 12 ii Northwest Sand Warehous~ Cystalline Silica None Non~_ ~ 30 "30 ~ --i2-- 11 No~th~e~'ff--Sa~d warehous~ ---- · . · - None None q.00O . 9.000 LBS l~ It ~ou~h Chemical Warehous~ o ~' 'Bridgesal ; None None q.O00 3.000 LBS 12 11 South Chemical Warehous~ ~ ( None None TITLE: SIONATURE: , ~ DATE: {EROENCV CONTACT: Do~ Cobb TITLE: Manager PHONE # BUS HOURS: 834-284~" AFTER BUS HRS: 833-9784 {EROENCV CONTACT: S~eve Ty.l~r. TITLE:,,,,Region Sales ., PHONE # BUS HOURS: ~34-2844 tlNCIPAL BUSINESS ACTIVITY: Oilfield Service Company AFTER BUS HR8: - 4A-I - · BAKERSFIELD CITY FIRE DEPARTMENT .D. t ' FORM 4A-1 Page "of. NON--TRADE SECRETS HAZARD. OUS MATERI ALS INVENTORY ~USINESS NAME: Baker Sand Control O#NER NAME: Corp. (Baker Sand Control) FACILITY UNIT #: ~DDRESS: 5551 Aldrin Ct. ADDRESS: 1010 Rankin Rd. FACILITY UNIT NAME: ~ I TY. Z I P: Bakersfield, Ca. 93313 c I TY, Z I P: Houston, Tx. ??0?3 :,nONE ,: (805)834-2844 PHONE #: (?13) 443-7590 OFFICIAL USE CFIaS CODr ~ 2 3 4 § 6 7 8 9 10 ;PE MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O. IDE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT #T. CHEMIi~AL OR COMMON NAME CODE GUI[ ~ P 4000 4000 LBS 02 11 Storage Tank Outside Southwest 100 Ammonium Nitrate /~-- OXID 194. ~ P 115 115 GAL 07 11 South Chemical Warehous~ 15 Sodium Hypochlorite / / ~ ~ OXID 791 V P~ 5000 ~2~000 LBS 12 11 South Chemical Warehouse 100 Ammo,hint Chloride 1~5 I t :ORMA ~085 P 2000 ~000 LBS ]2 11 South Chemical War~hous~ 100 Sulfam%c Acid ~--7 CRMT ....... None ~? 350 350 LBS 12 11 South Chemical Warehous~ 100 Lime ~ ~ Ofi~,t~,~ ~]~"~, CRMT 1910 t--P 100 300 LBS 12 11 South Chemical Warehous~ 100 Sodium Hydroxide, Flake ~ CRMT 1823 South Chemical Warehous~ /~ P 130 165 GAL 06,08 11 o-~=~Ho ~-~hwmst 25 Sodium Hydroxide, liqui CRM% 1824 CRMT f~ 1779 /~ 55 55 C~AT, 06 11 Sou~h Chemical W~hous~ la Nalco ASP-200/Sodiu y · CRMT 176m~ ~ , ~ ] ~ G~. ~ ~ ~ Sou~h Chemical ~arehou~ 3 Defoamer/Potassium Hydroxide CP~T 1760 /~ M 150 150 GAL 07 11 South Chemical Warehous~ 12 W-315/Zirconium Oxy Chloride CRMT 1760 ~ P 300 300 GAL 07 11 Outside Southwest 35 Hydro Chloric Acid 10~ CRMT 1789 '~l~ M 55 55 GAL 07 11 South Chemical Warehous~ 25 Biocide/Glutaraldehyde ~q~% ORMA None O ~-------.:~-'. mono and didodecyl M 330 330 GAL 06 11 South Chemical Warehous~~- ~Dow-f-ax ,2A0/disulfonated diphenyloxi, .eORMA None ~M 55 55 Gal 06 11 South Chemical Warehous~ · Union/Carbide Ucar 310/Amine/Glycol ORMA None ~ME: TITLE: S IONAT DATE: tEROENCY CONTACT: Don Cobb TITLE: Manager PHONE # BUS HOURS: AFTER BUS HRS: 833-9784 IERGENCY CONTACT: Stev~ ~yler. TITLE: Region Sales ... PHONE # BUS HOUR8:,~34-2844 ~INCIPAL BUSINESS ACTIVITY: Oilfield Service Company AFTER BUS HRE: ~33-bOb~ - 4~-! - BAKERSFIELD CITY FIRE DEPARTMENT' · D. # FORM 4A-1 Page ', NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY ~USINESS NAME: ]~er Sand Control 0MNER NAME: Co~. (~ S~ C~o~) FACILITY UNIT ~DDRESS: ~ ~ C~. ADDRESS: ~0~0 ~ ~. FACILITY UNIT NAME: ~HONE *: (805)834-2~ PRONE ~: (713) ~3-7590 IOFFICIAL USE CFIRS COD~ I ONLY I 2 3 4 5 6 ? 8 9 10 fPE MAX ANNUAl, CONT USE LOCATION IN THIS · BY HAZARD D.O. )DE z/AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT MT. CHEMICAL OR COMMON NAME CODE GUIt 440 440 G~ 06 11 SouZA C~e~lcal ~a~ehous< ~alco AS~ 162/~osp~ate~ Alt ~ F~Q 199~ ~ 55 GAL 06 i~ SouLh Chemlcai Warehous~ Nalco ASP 166/Phosphated Alcohol FLLQ 1393-' ~q ~ 55 .... 110 G~ 06 11 8outh ChemScal,, ,,,, ,, ,.,~ar°h°us~ ~ Hagna All~/AromatSc,, Petro, ,S°lvent FLLQ.,, 1993 ~ M 55 55 GAL 06 11 South Chemical Warehous, 15 Magna All7/Isopropanol . ~[¢¢ FLLQ 1993 ~' M 55 55 GAL 06 11 South Chemical Warehous< A-100/Cronox 265/Isoproponol ~ FLLQ 1993 ........ ~ Chc~r~] Wa~eho-~ p~ o ....... I,~Q 1993 ~ Z~ 25 GAL uu ~ oo '~ P 55 100 GAL 06 19 South Chemical Warehous, 100 Kerosene. I ~pi 'D~ ~ , ~ ~66 j~ P 430 ~00 GAL 02 .... 19 Outside Southwest ,, 100 Liquefied Petroleum Gas ~propane) FLGS 107~ ~W,FL 300 1000 GAL 02 40 Outside Southwest 100 :Waste Oil (Nm 9189) ~ ~ ~ FLLQ 127~ ooo M c a. ic S op Motor ~ME: ~ B. Cobb TITLE: SIGNATURB: DATE: 6-2~ ' IERGENCY CONTACT: ~ ~bb T~TLg: ~a~er PHONg ~ BUS HOURS: 834-28~ AFTBR BUS MRS: 833-9784 IERGENCY CONTACT: S~e~ ~ler. TITLE: ~gi~ Sales P~ONg ~ BUS ~OURS: 8'34-28~ ~[NCIPAL BUS~NESS ACTiViTY: Oilfield Se~ce C~y AFTBR BU~ BAKER SAND CONTROL: 834-2844 MOBILE NL~MBER: 327-3501 ANSWERING SERVICE: 393- 2711 TOLL FREE NLU~ER: (800) 442-3222 HAZARDOUS MATERIALS RESPONSE OR M~5~ZNCY: 911 HAZARDOUS MATERIALS RELEASE; OFFICE OF MMERGENCY SERVICES: (800) 852-75~0 (916) 427-4341 HAZARDOUS MATERIALS MMERCENCY RESPONSE TEAM: (1) D~n Cobb 833-9784 (2) Steve Tyler 833-6064 (3) Rick Jeffrey 834-0878 (4) Brad Wellman 834-6058 .............. (5) Robert ·Usher 589-0647 WHITE LANE MEDICAL CENTER: 832-2000 MMMORIAL HOSPITAL: 327-1792 ~604 (Tools) Mobile' Local a~d Aong Distance Page No. COBB, DON --- 833-9784 ' 321~5378 TYLER,· ~ (sales) 833-6064 321-5379 GWARTNEY, TONY ..... 835-1887 1227 321-5380 PARKER, CRAIG 835-9056 1233 32~1-~5 3 81 PITI~4AN, ELLY 834-9578 6694·(Pumping) Mobile Local and Long Distance Page No. WELTJ4AN, BRAD 834-6058 1229 32-i JEFFREY, RICK ...... 834-0878 1228 321-5384 ORTON, JEFF ...... 834-4671 321-5385 ENGLE, RAY 831-9554 -~i2 ~38~6 m mu , 835-8793 321-5387 mviS, 832-1792 321-5388 o~Azr, D~ 831-3725 32ii5390~ B~BUS, nav~ ...... 832-1792 321-5391 SHOP F-250 PICKUP 1224 MATERIA GAFETY DATA SHEET PRODUCT NA,T.J:30 AS1:~162 OIL ~ ,T ~ HALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION I PRODUCT IDENTIFICATION TRADE NAME: NALO0 ASP-162 OIL ~ESCRIPITON: A blend of alkyl phosphates in a h~k~z~k~ solvent NFPA 704M RATING 1 ~ 2 ~ILITY 0 REACTIVITY 0 OILER 0=Insignificant l~light 2=Moderate 3=High 4=Extreme SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous urger OSHA's Hazard Co..~,Inication R~le, 29 CFR 1910.1200. (kxl~/lt Section 14 for the ~at~re of the hazard(s). n mEDn T (S) # AP OX. % Heavy aromatic naphtha 64742-94~5 1-10 SECTION 3 PRECAUTIONARY LABEL INFORMATION goggles or face shield when handling. Avoid prolonged or repeated breathin~ of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep o0~ta~ closed when not in use. unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: Flush with water for 15 m/nutes. SKIN:' Wash tho~y with soap ar~ rinse with water. Cai1 a physician. INC~TI(~: Do r~t ~ reuniting. Give water. Call a ~T~sician. INHAIATION: Remove to fresh air. Treat symptoms. Call a physician. NOTE TO P~YSICIAN: No specific antidote is known. Based on the ir~ividual reactions of the patient, the physician's judgment should be used to oontrol sy~ and clinical condition. CAUTI~: If unoor~cicus, having t_rouble breathir~ or in oorml~l$ions, do not induce womitir~ or give water. PAGE 1 OF 6 MATERIA~SAFETY DATA SHEET PRODUCT ],;~j~ AS1:~162 OLL mALCO · Emergency Telephone Number Medical (312) 920-1510 (24 hours) ~~(s) OF~: ~, ~, ~~ ~ ~: ~y ~ ~i~ti~ ~ ~1~ ~~. ~~: ~1~ ~a~ of ~ ~y ~ ~. ~ OF ~: ~: ~a~ of ~ ~~ of ~ ~~c ~~ ~ ~C: ~l~~~~~~~~fa~ BECTION 6 TOXICO~GY INFO~TION SECTION 7 PHYSICAL ~ CHEMICAL PROPERTIES ~~ ~ ~: ~l~le s~c ~~: o.~s ~ 6o ~ F ~ ~) - ~.o ~ E-7o ~~: 471 ~ ~ 60 ~ F ~ ~445 ~ ~: +26 ~ F ~ ~7 ~ ~: 14 ~ ~ ~ 100 ~ F ~ ~323 SECTION 8 PI~ ~ ~XP~SION I~O~T/ON ~1 f~, ~ ~~ or ~ ~ ~ ~eable for ~ B f~. U~~~i ~~~ f~. ~ ~f~, ~~~yor f~, ~y~~~ P~ 2 OF 6 MATERIA~AFETY DATA SHEET PRODUCT ~ ASP-162 OIT. ~ NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 9 RE;t, CTIVZT¥ INFORF~TION INOC~P~: A~id ~~ wi~ ~ ~z~ (~. ~or~, ~d~, ~~, ~ic acid, ~o~, ~~ ~, ~~) ~~ of ~c ~~~ ~~: ~ ~of ~i~ ~, ~2 ~y ~ fo~. ~ ~ b~ ~ ~ ~. ~ ~hle ~ve ~~. S~CT~ON ~0 ~E~SONAL ~OTECT~ON s~ ~ ~lat~i~ ~ or a~ls ~~r, (~I Z 88.2, 1980 for ~ ~ ~~). For l~e ~ills, ~ wi~ ~~~ v~tilati~, a p~~, ~f~~ b~~ a~~ ~ ~,,,~. ~1~ (~I Z 87.1 ~~ ~ ~:icn of gl~, ~l~, ~, ~. ) If ~~ aff~ ~. SECTION 11 SPILL ~ DIS~EAL I~O~TION ~ ~ OF ~~~ ~~, ~TI.~ ~~ 24~ ~~ ~ (3~-920-~10) S~;. ~L ~, clay, ~1~ li~d ~ ~~ ~ ~~ ~ ~ge '~ f~ ~. ~f~ ~ ~ ~ ~i~ 14. ~~ or ~ge ~ ~i~ 14. P~ 3 OF 6 MATERIAIISAFETY DATA SHEET PRODUCT ],mz.co Asz:,.-:].62 0IL I NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) BECTION 11 BP/LL AND DIBPOB~tL INFORMATION ( CONTINUED ) DISPOSAL: Ifthis~~awas~, tt does not meet the criteria of a hazarcham waste u defined urger the l~esouroe Oor~ervaticn and aecovery Act (R~A) 40 CF~ 261, since it does ~ot have the d~racteristtcs of .~ C, (i.e. D001 throu~ D017) ncr is it As a non-hazardous liquid waste, it should be solidified before a~%po~__ 1 to a sanita_--y landfill. Can be incinerated in aooordar~ with local, state and federal re~ulaticr~. SECTION 12 ENVIRONMENTAL INFORMATION SECTION 13 TRANSPORTATION INFORMATION ' DOT PROPER SHIPPING NAMe/HAZARD (I)~E - ~STIBLE LIQUID, N.O.S.- NA 1993 SECTION 14 REGULATORY INFORMATION The foll~_r~ re~tlations apply to this prc~t. C~H~'S HAZARD ~CATIC~.I~JLE, 29 CFR 1910.1200: Based c~ our hazard evaluation, the followir~ ingredient in this ~ a.rce~t~c haler, ha - ~ible, .fgrrit. an"c ~ arc~t.~c r~?.t..ha = lO0 ~ TLr CERCLA, 40 CFR ].'1'7, 302: (40 CFR 710). If this product ~ a waste, it does not meet the criteria of a PN~. 40F 6 NALCCI CHEMICAL COMI:IANY ONE NAI. CO CENTER · NAPERVII_.LE. ILLINOIS ; MATERIAl)SAFETY DATA SHEET NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) BECTION 14 REGULATORY 'rNFORMATION ( CONTZNUED ) FEI]ERAL I~ATER I:~T$~FI~O~ ~L ACT, CLF. AN ~ ACT, 40 CFR 401.15 (fornm. rly Sec. 307), 40 CFR 116 (formerly Sec. 311)= None of the ~ents are specifically ~FAN AIR ACT, 40 CFR 60, 'SECi~C~ 111, 40 CFR 61, SECTI~ 112: SECTION 15 ~%DDITION~%L INFORMATION Nc~e SECTION 16 USER'S RESPONSIBILITY our product literature. Indiv~a~ls handling this product should be informed of the reo~,~_~_ safety precautions and should have aooess so that a~zupriate handling practices and t~ programs can be establt-~h~ to ensure safe workplace c~exatic~s. Please consult your local sales z1~tive for any further ir~ormati~n. SECTION 17 BIBLIOGRAPHY ANNt~L REPO~ ~ C~CIN~NS, U.S. De~ of Health and Human Services, P~blic Health Service, PB 33-135855, 1983. ~ AND DOULL'S TOXICOLOGY, ~tE BASIC SCIENCE OF POISC~S, Doull, J., Klsassmn, C. D., and ~mr, M. O., .ds., Mmmillian Publis~ Cm~sny, Luc., N. ¥., 2~ edition, 1980. O~ICAL ~ OF ~E W~IACE, Proctor, N. H., and Hughes, J. P., eds., PASE 50F MATERI SAFETY DATA SHEET ~'~' ~' - ~. · PIRODUCT NAI,CO ASP-162 OIL HALl:::: D Emergency Telephone Number Medical (312) 920-1510 (24 hours) 8ECTZON 17 BZBLZOGI~PHY ( CONTZNUED ) J. P. Lipinoctt ~_(k3~'?. ny, N.Y., 1981. ~ PRO~ OF I~UJSTR/AL MATERIALS, Sax, N. Irvir~, ed., Van Noetrand Reinhold C~pany, N.Y., 6th edition, 1984. IARC ~ C~ I~E EVAIiRtTI~ OF ~ (~%~C~t0G~NIC RISK OF TO MAN, Gen~za: World _FPa_ !th Organization, I/fcezr~tional A~ency for Researc~ c~1 Canoer, 1972-1977. PATTY'S INUJSTRIAL HYGTWNE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and So~s, N. Y., 3rd ~_i_tion, Vol. 2 A-C, 1981. l~II~ OF TOXIC ~'~ui~ ~ Ofl~ICAL SUBSTANCES, U.S. D~ of H~lth and Human Sex~ioes, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement 'of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Recjulations Part 1910, Subpart Z, Toxic a~d ~ ~ wrIH INTENI~D (~GES, American Conf~ of PAGE 6OF 6 2 ,~,,~jk2 Page 1 'f~ MAGNA CORPOP, ATION MAG NA MATERIAL SAFETY DATA SHEET Manufacturer's Emergency .Name Magna Corporation Telephone No. (713) 599-7400 A~ldress 3920 Essex Lane, P.O. Box 27714 Date Prepared 12/5/85 Houston, TX 77227-7714 Supercedes SECTION I - IDENTITY Common Name: (used on label) CAS Number (T~de Name e Synonyms) ~.- 100 Proprietary Chemical Chemical Formula ' DOT Identification Name Proprietary Family Proprietary Proprietary UN 1993 ' Number sECTION il - HAZARDOUS INGREDIENTS PHncipal Hazardous Component(s) CAS -. (Chemical e common name(s)) Number % '~ Threshold Limit Value (units) .A. cetyl enic Alcohol* 107-19-7 1-10 lppm Aromatic Petroleum Solvents 67891-77-6 40-50 200ppm Isopropanol 67-63-0 1-10 400ppm *No known antidote. Treat symptomatically. SECTION Ill - PHYSICAL Et CHEMICAL CHARACTERISTICS Boiling I Specific Gravity I Vapor Point HA I(H=° = 1) ~ 60°F O. 968:0.974 I Pressure (mm. Hg) NA Percent Vol,tile NA I Density NA veport~0. Rate pH by Volume (%) I (Air = 1) ' ) = I 100~ Product NA Solubility ~ Reactivity in WaterDispersible lin Water NonReactive Appearance andOdor Clear reddish brown liquid - mild odor SECTION IV- FIRE Et EXPLOSION DATA NFPA Code 3- 3- 0 ' '' Flash (method) Flammable Limits Lower Upper Point 76°F (TCC)' In Air % by Volume NA Extinguisher Foam, dry chemical, C02, water fog or Auto-Ignition , Media S pray Temperature NA Special Fire.Fighting Procedures Do not enter fire area without proper protective equipment, includinq NIOSH approved self- ?-ntained breathinq apparatus. Cool exposed containers with water spray. Avoid breathinq ~pors or fumes. Page NIA3NA ~ORPORATION Unusual Fire end Explosion Hazards Material is flan~able. Do not store with strong oxidants. Vapors are heavier than air may travel alon9 9round to ignition source and flash back. Never use welding or cutting'' ~mOrCh on or near drum, even when empty. Explosion may result. SECTION V - PHYSICAL HAZARDS Stability Unstable__ Conditions lo avoid Use away from heat, sparks, or open flames. Stable X Incompatibility (Materials to Avoid) Avoid strong oxidizers. Hazardous Thermal Decomposition Products Carbon Monoxide, 0x~des of HC1 and Nitrogen. Hazardous May Occur,,,, Conditions polymerization Will Not Occur X to Avoid Not appl i cable .. & , SECTION VI- HEALTH HAZARDS Threshold umitVelue See Section II ~ectso~ Inhalation of concentrated vapors may cause dizziness, headaches, or unconsci.ousness. Overexposure .Prolonged or repeated skin contact, may result in irritation or dermatit.is. Eye contac' ~ay c.ause...sQver.~e !r. ritation, redness, tearinq, or blurred vis,on. Ingestion can cause gasl~. Intestinal lrrltmtlon, nausea, vomiting or d~ath.. Toxicity Information NA OSHA Permissible ACGIH Threshold Other Exposure Exposure Limit See Section II Limit Value See Section II Limit Used None .% SECTION VII - EMERGENCY FIRST AID PROCEDURES Eve Contact Flush eyes in~nediately with larqe amounts, of water for at. least 15 minutes. Call a physician. '" m Ingestion DO not induce vomitinq. Drink large quantities of water and: call. a physician. Skm Contact Remove contaminated clothes. Wash skin thoroughly with soap. and water-- Launder clothes before reuse. Inhalation ]f overcome by vapors, .remove immediately from exposed a:re~ to fresh air. Call a physician. If breathinq is irreqular or stopped~ start resuscitation~ administer Oxygen, and call a physician. MA~'NA SECTION VIII - SPECIAL PROTECTION INFORMATION RespiratowProtection(Speci~Type) Use with adequate ventilation. If ventilation is not adequate, use approved N[0SH vapor canister. Ventilation Use with adequate ventilation. If ventilation is not adequate to prevent buildup of ..... vapors, use mechanical, ventilation. I Eye GIovesPr°tective Wear chemical resistant gloves, iProtection 'Wear chemical .goggles or face shield. Other Protective Clothing or Equipment Wear chemical resistant boots and aprons. SECTION Villi - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCED~JRES Precautions to be taken in Handling _U. se proper protective clothing and equipment. Do not handle near heat,, sparks, and open. flames. ,.R. eseal container when not in use. Do not add any foreiqn material to container. Do not reuse _empty container. If used in enclosed area~ be Sure that there is adequa'te ventilation and all .electrical equipment is explosion proof. Precautions to be taken in Storage i, not store near heat~ sparks~ or open flame. Do not store with strong oxidizers. Store in. .well ventilated area. If store in enclosed areal make sure all. electrical equipment is _explosion proof. Steps to be taken in case material is Released or Spilled _Eliminate ignition source~. ~h,t riff leak if it can hm dnnm ~afely_ t~,a, appropri~_te clothing and respiratory protection. Dike and pump large sDills into salvage container~. ,up residue and small spills with absorbent clay, sand, Or diri;, and place in ~alwge con~in~r~_ Waste Disposal Methods .Under RCRA~ it is the responsibility of the user of this oroduct to determihe.'~t the t~m~ nf disposal, whether product meets RCRA criteria for hazardous waste. This is becaUse product uses transformations, processes, mixture, etc. may render a nonhazardous material hazardous or a hazardous material nonhazardous. The information on this MSD$ is based on data which is considered to be accurate. Magna. however, makes no guarantees on warranty, either expressed or imf)Iisi] of the accuracy or completeness of this information. Megrim does expressively disclaim any loss incurred with the handling, storage, transpo~lmtion, use or disposal of the p~ol:luci ,., ;~' EFFECTIVE DATE: March 1, 1982 PRODUCT NAME: CHEMICAL NAME: Amine/Glycol Mixture CHEMICAL FAMILY: Amine/Glycol FORMULA: - - MOLECULAR WEIGHT: Mixture SYNONYMS: - - DEPARTMENT OF I 'HAZARD CLASSIFICATION None TRANSPORTATIONI SHIPPING NAME None CAS # CAS NAME Not available (mixture) Sets ~o glass BOILING POINT, 760101.325mm kHFJ;la 107.2 °C (225 °F) POUR POINT -44 SPECIFIC GRAVITY {H~O = 1) 1.1234 at 20/20 °C VAPOR PRESSURE at 20'C 11.7 mm Hg ' SOLUBILITY IN VAPOR DENSITY (air = 1) 2.41 WATER, % by wt, 100 :PER CENT VOLATILES 15 EVAPORATION RATE 1.11 BY VOLUME (Butyl Acetate = 1) · APPEARANCE AND ODOR Brown liquid; ammoniacal odor. . MATERIAL % TLV (Units) HAZARD · Amine/Glycol Mixture 100 Not established Eye irritant. "* . FLASH POINT [test method(s)] None, Pensky-Martens Closed Cup FLAMMABLE LIMITS IN AIR, % by volume I LOWER I .otdetermin,d I UPPER I .otdeterm,.ned EXTINGUISHING Use water spray, carbon dioxide, dry chemical, alcohol-type or MEDIA universal-type foams applied by manufacturer's recommende(f technique. Don't spray pool fires directly. A solid stream of water directed into hot, SPECIAL FIRE FIGHTING burning liquid can cause fro~ing. Use self-contained breathing apparatus-and PROCEDURES protective clothing. UNUSUAL FIRE AND None EXPLOSION HAZARDS 304/744-3487 This number is available days, nights, w~ekends, and holidays, While Union Carbide Corporation believes that the data contained herein are factual and the opinions expressed are those of qualified experts regarding the results of the tests conducted, the data are not to be taken as a warranty or representation for which Union Carbide Corporat ion assumes legal responsibitity. They are offered solely for your consideration, investigation, and verification. Any use of these data and information must be determined by the u~er to be in accordance with applicable Federal~ State, and local laws and regulations. STABILITY UNSTABLE ~ STABLE CONDITIONS TO AVOID None INCOMPATIBILITY (materials to avoid) Avoid contamination with strong acids. HAZARDOUS COMBUSTION OR Burning can produce carbon monoxide and/or DECOMPOSITION PRODUCTS carbon dioxide, and nitrogen oxides. HAZARDOUS POLYMERIZATION ~~__-- Will i°~t~cc~urTO CONDITIONS AVOID None STEPS TO BE TAKEN Wear suitable protective equipment, especially eye protection. IF MATERIAL IS RELEASED Small spills could be flushed toa sewer with large amounts of OR SPILLED water. Larger spills should be collected for disposal. Incinerate in a furnace where permitted under appropriate WASTE DISPOSAL METHOD Federal, State, and local regulations. RESPIRATORY PROTECTION None required in normal use, (specify type) VENTILATION General (mechanical) room ventilation is expected to be satisfactory. EYE PROTECTIVE GLOVES Neoprene or nitrile PROTECTION Safety glasses OTHER PROTECTIVE Eye beth and/or safety shower EQUIPMENT PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Avoid contact with eyes. Wash thoroughly after handling. FOR INDUSTRY USE ONLY OTHER PRECAUTIONS F-49560 3/82-3M Printed In U.S.A. TLV AND SOURCE: None established by ACGIH or OSHA. ACUTE EFFECTS OF OVEREXPOSURE ~ · ~ SWALLOWING None currently known, May cause some nausea, SKIN ABSORPTION None currently known. INHALATION None currently known. SKIN CONTACT None currently known. EYE CONTACT May cause minor temporary corneal injury. CHRONIC EFFECTS None currently known. I OF OVEREXPOSURE OTHER HEALTH HAZARDS None currently known. SWALLOWING No harmful effects expected. SKIN Wash with soap and water. INHALATION No emergency care anticipated. Immediately flush with water for at least fifteen (15) EYES minutes and seek medical attention. NOTES TO PHYSICIAN There is no specific antidote.Treatment of overexposure should be directed at the control of symptoms and the clinical condition. 5551 ALDRIN COURT BAKERSFIELD, CALIFORNIA 93313 TELEPHONE: (805) 834-2844 IRAKERSFIELD CITY FIRE DEPARTMENT RALPH E. HUEY HAZARDOUS MATERIAL COORDINATOR 2130 "G" STREET 326-3979 BAKERSFIELD. CA 93301 LABORATORIES, Inc. PETflOLEU¥ J' J' EGLIN, REG. CHEM. ENGR. 4100 PIERCE RD., BAKERSFIELD, CALIFORNIA 93308 PHONE 327-4911 Baker Sand Control Date Reported: 08/02/88 5551 Aldrin Court Date Received: 07/'20/88 Bakersfield, CA 95513 LaboratOry No.: 538'7-1 Attn: Don Cobb Sample Description: Project #2282, #1 Southeast, Surface Soil, 06/19/88 @ 5:25 PM Ammonia-Nitrogen 5419 mg/kg Nitrate-Nitrogen 5686 mg/kg B C LABORATORIES, INC. cc: Calpi, Inc. :Attn: Curtis Dalton LABORATORIES, Inc. p~cT~OLELI¥ J.J. EGLIN, REG. CHEM. [:NOR. 4100 PIERCE RD., BAKERSFIELD, CALIFORNIA 93308 PHONE 327-4911 Baker~Sand Control Date Reported: 08/02/88 5551Aldrin Court -' Date Received: 07/2'0/88 Bakersfield, CA 93515 Laboratory No.: 5587-2 Attn: Don Cobb Sample Description: Project #2282, #2 Southwest, Surface Soil, 06/19/88 @ 3:'35 PM Ammonia-Nitrogen 9882 mg/kg Nitrate-Nitrogen 10829 mg/kg B C LABORATORIES, INC. cc: Calpi, Inc. Attn: Curtis Dalton LABORATORIES, Inc. J. J. EGLIN, REG. CHEM. ENGR. PETIIOL£~II~ 4100 PIERCE RD., BAKERSFIELD, CALIFORNIA 93308 PHONE 327-4911 Baker Sand Control Date Reported: 08/02/88 5551Aldrin Court Date Received: 07/'20/88 Bakersfield, CA 95315 Laboratory No.: 5387-5 Attn: Don Cobb Sample Description: Project #2282, #3 Northeast, Surface Soil, 06/19/88 @ 3:40 PM Ammonia-Nitrogen 4'2'88 mg/kg Nitrate-Nitrogen 13894 mg/ki B C LABORATORIES, INC. ~ J~ Egli~Z cc: Calpi, Inc. Attn: Curtis Dalton LABORATORIES, Inc. J. J. EGLIN, REG. CHEM. ENGR. 4100 PIERCE RD., BAKERSFIELD, CALIFOR[llA 93308 PHONE 327-4911 Baker Sand Control Date Reported: 08/02/88 5551Aldrin Court Date Received: 07/20/88 Bakersfield, CA 95515 LaboratOry No.; 5587-4 Attn: Don Cobb Sampl~ Descri~gion: Project #2282, #4 Northwest, Surface Soil, 06/19/88 @ :'~ ~: 3:45 Ammonia-Nitrogen 5.6 mg/kg Nitrate-Nitrogen 10507 mg/kg/ B C LABORATORIES, INC. cc: Calpi, Inc. Attn: Curtis Dalton I, JNI'/' 5313 Index: 441.40 December 19, 1988 Replaces: -- Page I of 33 BAKER PERFORATING GUN EXPLOSIVES ~ 1986, by Baker Sand Conlrol Division Baker-Hughes, Inc. THIS DOCUMENT IS CONFIDENTIAL AND IS THE PROPERTY OF BAKER SAND CONTROL DIVISION BAKER-HUGHES, INC. ("BAKER"). IT MAY NOT BE COPIED OR REPRODUCED IN WHOLE OR IN PART IN ANY WAY WITHOUT THE EXPRESS WRITTEN CONSENT OF BAKER. THIS DOCUMENT ALSO IS AN UNPUBLISHED WORK OF BAKER. BAKER OWNS ALL RIGHTS TO THIS WORK AND INTENDS TO MAINTAIN THIS WORK CONFIDENTIAL AND AS A TRADE SECRET. BAKER MAY ALSO SEEK TO PROTECT THIS WORK AS AN UNPUBLISHED COPYRIGHT. IN THE EVENT OF EITHER INADVERTENT OR DELIBERATE PUBLICATION, BAKER INTENDS TO ENFORCE ITS RIGHTS TO THIS WORK UNDER THE COPYRIGHT LAWS AS A PUBLISHED WORK. THOSE HAVING ACCESS TO THIS WORK MAY NOT COPY, USE OR DISCLOSE THE INFORMATION IN THIS WORK UNLESS EXPRESSLY AUTHORIZED BY BAKER TO DO SO. WARNING: THIS EQUIPMENT SHOULD BE usED ONLY BY QUALIFIED PERSONNEL. USE CONTRARY TO MANUFACTURER'S SPECIFICATIONS MAY RESULT IN PROPERTY DAMAGE, INJURY OR FATALITY. The following explosives are used in various components The explosives data and usage chart identifies some utilized in Baker Perforating equipment: of the most popular facts concerning these explosives. RDX HMX HNS PYX LEAD AZIDE Specifications and Material Safety Data sheets are in- cluded for each explosive for reference purposes. EXPLOSIVES DATA AND USAGE CHART Color App. Temp. I App. Name Code Use Limit Compoaltion Detonation Use -~D~X.~ . Shaped Charge, -C~Ig'ni te Or Pink Up to 250°F C3HeNeOa 8,180 M/Sec. Prirnacord Hexogene for 48 Hours Boosters Sh,, Charg. ~ "Cycl~etramethylene . White Up to 325°F C4H,N4(NO2)4 9,100 M/Sec. Primacord Tetranitramine for 48 Hours Boosters HNS Pale Up to 400°F C~4HeNeO~2 6,900 M/Sec. Shaped Charge, Hexanitrostilbene Yellow for 50 Hours Primacord Boos~em --PYX Shaped Charge, 2,6 BIS (Picrylamino) Yellow 430°F C~7H7N~O~ 7.100 M/Sec. Primacord -3, 5 Dinitropyridine for 200 Hours Boosters Lead Azide, Clear 437°F RD 1333 or 6-12 K f/s Boosters Non-Dextrihated for 200 Hours Pb Ns Initiators TUBING CONVEYED PERFORATING GUN TEMPERATURE CURVES ~$o TEMPERATURE RATINGS 4e~ L~ ~O0 HCX~S ~ ~'~ HTP SYSTEM I ~ ~/ HNSII SYSTEM ~ ~1~) HMX SYSTEM ZZS ~1~ ROX SYSTEM INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 2 of 33 RDX (Cyclonite, Cyclotrimethylene Trinitramine) grades contain wax coatings that enable charges to be The RDX series of specialty explosives includes regular- made by pressing or pelleting; some are also coated with ly produced and custom-produced crystalline high ex- small amounts of graphite, which serves as a lubricant plosives used when high detonation rates and exceptional during pressing. stability are needed. A wide variety of granulations, wax contents, and graphite contents is standard. Requests for other RDX- Applications of RD×-based items include pressed based compositions or granulations are welcome. charges for oil-well perforation, detonating cord and flex- The following pages include bulk powder specifications ible linear shaped charges, shaped charges for underwater and material safety data sheets supplied by The Ensign- detonation work and aerospace components. Several Bickford Company. BULK POWDER KDX, WAXED AND G~PHITED CHEMICAL NAME: Cyclo-1,3,5 crimechylene-2,4,6 crinicramine DESCRIPTION : Grey powder SOLUBILITY : Soluble in acetone, insoluble in water and sparinEly solub~!e ~, in ether and ethanol. ~ TYPICAL SPECIFICATIONS Percent Wax : 1.0% Percent Graphite: 0.5% Gravimetric Moisture : 0.05% density g/cc: 0.90 Granulation : USS Sieve Percent Through 20 99.9% 40 72.0% 60 50.0% lO0 8.0% Loose Powder Weight Loss : 0.50% weight loss in 10 hours at 325 degrees F. PACKAGING INFORMATION Standard Package: 11 gallon Drum Dimensions' 14" diameter fiberboard' drum x 16 1/2" high Weight · Gross 56 pounds Net 50 pounds SHIPPPING INFORMATION U.S.D.O.T. Class: Class A U.N. Class : 1.1D 'High Explosive U.N. Number: Not available EX Number : EX-8207083 CA Number : Not available I ,, DEX: ,,,.,,o u,,-r ,o. 5313 December 19, 1988 Page 3 of 33 BULK POWDER RDX, PRIMER GRADE CHEMICAL NAME: Cyclo~l,3 ,§ urimechylene-2, a ,6 crinicramine DESCRIPTION : Virgin white crystals, water wec. SOLUBILITY · Soluble in acetone, insoluble in wacer and sparingly soluble in ether and ethanol. TYpiCAL SPECIFICATIONS Percent Wax : 0.0% Percent Graphite: 0.0% Gravimetric Moisture · 15.0% density g/cc: Not available Granulation (wet): USS Sieve Percent Through 20 98 +/- 2% 40 90 +/- 10% 60 60 +/- 30% 100 25 +/- 20% Loose Powder Weight Loss · 0.50% weight loss in lO hours at 325 degrees F. 0 27% wei§nt loss in lO hours at 300 degrees F. 0 20% weight loss in [ hour ac 325 degrees F. PACKAGING INFORMAT~O,N Standard Package' 11 gallon Drum Dimensions: 14" diameter fiberboard drum x 16 1/2" high Weight · Gross 64 pounds Net 50 pounds ~H~PPPING INFORMATION U.S.D.O.T. Class: Class A U.N. Class · 1.lb High Explosive U.N. Number: 0072 EX Number · EX-8207084 CA Number · Not available INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 4 of 33 Material Safety Data Sheets Section I Manufacturer's Name I Emergency Telephone No. The Ensign-Bickford CompanyI 1-203-658-4411 Address (Number,Street,City,State,Zip Code) 660 Hopmeadow Street, Simsbury, CT 06070 Chemical Name & Synonyms ITrade Name & Synonyms CYCLO-1,3,5 TRIMETHYLENE-2,4,6 I DESENSITIZED RDX TRINITRAMINE PHLEGMATI ZED RDX ORGANIC NITRO COMPOUND C ~ Hc N~ O~ Section II - Hazardous Ingredients Ingredient Percent CYCLO-1,3,5 TRIMETHYLENE-2,4,6 TRINITRAMINE T.L.V.: P.E.L. Section III - Physical Data ] Boiling Point: N/A [Specific Gravity: 1.82 Vapor Pressure:N/A IPercent Volatile: N/A Vapor Density: N/A [Evaporation Rate: N/A Solubility in Water: INSOLUBLE[Melting Point: 400c F Appearance and:ODORLESS CRYSTALLINE SOLID WITH COLOR RANGING Odor :FROM WHITE TO GREY DEPENDING ON WAX AND/OR GRAPHITE CONTENT SubS:diary o£' Ensign-Bickt'ord Industries, Inc. I 112 518 5 INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 5 of 33 Data Sheet for:DESENSITIZED RDX;PHLEGMATIZED RDX Manufactured By: THE ENSIGN-BICKFORD COMPANY Section IV - Fire and Explosion Hazard Data Flash Point: N/A (F) :Flamm.: Lel: : Uel: Extinquishing Media: NONE Special Firefighting: DO NOT FIGHT FIRES WHERE RDX IS PRESENT. Procedures : ISOLATE AREA. EVACUATE PERSONNEL TO A SAFE AREA. Unusual Fire and : WILL DETONATE IF SUITABLY PRIMED WITH Explosion Hazards : SEVERE IMPACT OR BY HEAT OR FLAME. HAZARDOUS GASES PRODUCED IN FIRE ARE NITROGEN OXIDES. Auto Ignition Temperature: N/A Section V - Health Hazard Data Threshold Limit Value: 1.5 MG/M3 Effects of Overexposure Eye : Contact ": NONE Skin : Contact : NONE Inhalation: RDX POISONING VIA THE RESPIRATORY SYSTEM CAN RESULT IN NERVOUS SYSTEM IRREGULARITY Ingestion : UNKNOWN Section V Continued on Page 3 I NDEX: 4.1..o UNiT NO. 5313 December 19, 1988 Page 6 of 33 Data Sheet for:DESENSITIZED RDX;PHLEGMATIZED RDX Manufactured By: THE ENSIGN-BICKFORD COMPANY Section V - Health Hazard Data (continued) Emergency and First Aid Procedures Eye : Contact : FLUSH EYES WITH WATER Skin : WASH WITH SOAP AND WATER Contact : Inhalation: IF DETONATION FUMES ARE INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL.RESPIRATION, PREFERABLY MOUTH TO MOUTH. IF BREATHING IS DIFFICULT GIVE OXYGEN, CALL A PHYSICIAN. Ingestion : INDUCE VOMITING IMMEDIATELY BY GIVING TWO GLASSES OF WATER AND STICKING FINGER DOWN THROAT Section VI - Reactivity Data Stability: STABLE Conditions to Avoid: BECOMES UNSTABLE WITH EXPOSURE TO EXTREME HEAT,IMPACT, OR ELECTROSTATIC DISCHARGE. Incomparability : NO KNOWN CHEMICAL INCOMPATIBILITIES. Hazardous Decomp. : HAZARDOUS FUMES PRODUCED ARE NITROGEN Products : OXIDES. Hazardous Polymerization: WILL NOT OCCUR Conditions to Avoid: AVOID BREATHING DUST. AVOID BREATHING FUMES FROM DETO IATION. Section VII - Spills or Leak Procedures Steps to be Taken : REVIEW FIRE & EXPLOSION HAZARDS AND SAFETY In Case Material is: PRECAUTIONS BEFORE PROCEEDING WITH CLEAN UP. Released or Spilled: USE APPROPRIATE PERSONAL PROTECFION DURING CLEAN UP. MOP UP WITH WATER. Waste Disposal : CONSULT AN EXPLOSIVES MANUFACTUIER FOR Method : RECOMMENDED METHODS FOR DESTROYING EXPLOSIVE MATERIALS. COMPLY wITH APPLICABLE FEDERAL REGULATIONS. I NoEx: ..1..o No. 5313 December 19, 1988 Page 7 of 33 Data Sheet for:DESENSITIZED RDX;PHLEGMATIZED RDX Manufactured By: THE ENSIGN-BICKFORD COMPANY Section VIII - Specical Protection Information Respiratory : FILTER RESPIRATOR: NIOSH CERTIFIED DUST Protection : RESPIRATOR. AVOID DUSTING BY KEEPING WET WHEN POSSIBLE. Ventilation Local Exhaust : N/A Special : N/A Mechanical : N/A Other : N/A Protective Gloves : BUTYL GLOVES Eye Protection : GOGGLES Other Protective : NONE Equipment : Section IX - Specical Precautions I Precautions To Be : TRANSPORTATION AND STORAGE MUST BE IN !Taken in Handling : COMPLIANCE WITH STATE AND FEDERAL and Storing, Etc. : REGULATIONS Other Precautions : REFER TO MANUFACTURER'S INSTRUCTIONS AND WARNINGS SUPPLIED WITH PRODUCT. Data Sheet Prepared By: E.L. STEARNS Last Data Sheet Revision: INDEX: 44i.40 UNIT NO. 5313 December 19, 1988 Page 8 of 33 HMX (Octegen, Cyclotetramethylene Tetranitramine) grade. Technical Grade HMX is i lreferred in many commer- HMX is a crystalline high explosive similar to RDX in cial applications where granuhltion is less critical. its sensitivity and output characteristics. Because HMX has a higher melting point than RDX. it is more useful in The following pages include ~: ulk powder specifications high-temperature situations, and material safety data sheets supplied by The Ensign: HMX is available in Class A, Class C, and technical Bickford Company. BULK POWDER HMX, UAXED AND GRAPHITED CHLMICAL NAME: Cyclocecramechyiene ceCranitramine DESCRIPTION ' Grey powder SOLUBILITY · Soluble in acetone, insoluble in wager. TYPICAL SPECIFICATIONS Percent Wax : 1.0% Percent Graphite: 0.5% Gravimecric Moisture : 0.03% density g/cc: 1.00 Granulation : USS $iev~ Percent :Through aO 99.0% 60 48.0% 100 2~.0% 200 4.0% Loose Powder Ueighc Loss ' 0.30% weight loss in 100 hours at 310 degrees F 0.35% weight loss in'lO hours at 360 degrees F. 0.40% weight loss in i hour at &lO degrees F. PACKAGING INFORMATION Standard Package' 8.6 gallon Drum Dimensions' 14 1 '2" diameter fiberboard drum x 13 1/2" high Weight ' Gross 56 pounds Nec 50 pounds SHIPPPING INFORMATION U.S. D.O.T. Class: Class A U.N, Class · 1 .D High Explosive U.N. NU~ber' No available EX Number · EX-8308759 CA Numbier · No( available INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 9 of 33 BULK POWI3ER RMX. PRIMER GRADE CHEMICAL NAME: Cyclocecramechylene ceeranigramfne DESCRIPTION ' VirEin whige powder, wager wet. SOLUBILITY · Soluble in acetone, insoluble in water. ,TYPICAL SPECIFICATIONS Percent Wax : 0.0% Percent Graphite: 0.0% Gravimetric Moisture : 15.0% density g/cc: Noc available Granulation (wet): USS Sieve Percent Through 5O 100% 100 97.0% 200 80.0% minimum 325 50.0% minimum Loose Powder Weight Loss ' 0~30% weight loss in 100 hours 'at 310 degrees F. 0 30% we%g~t loss in 10 hours ac 360 degrees F. 0 50% weight loss in 1-hour ac 410 degrees F. ~ACKAGING INFORMATION Standard Package' 8.6 gallon Drum Dimensions' 14 1/2" diameter fiberboard drum x 13 1/2" high Weight · Gross 33 pounds Net 25 pounds SHIPP?ING INFORMATION U.S.D.O.T. Class: Class A U.N. Class : 1.1D High Explosive U.N. Number: 0226 EX Number : EX-8207085 CA Number : Not available INDEX: 441.40' UNIT NO, 5313 December 19, 1988 Page 10 of 33 Material Safety Data Sheets Section I Manufacturer's Name IEmergency Telephone The Ensign-Bickford CompanyI 1-203-658-4411 Address (Number,Street,.City,State,Zip Code) 660 Hopmeadow Street, Simsbury, CT 06070 Chemical Name & Synonyms ITrade Name & S CYCLOTETRAMETHYLENE TETRANITRAMINE I DESENSITIZED HMX PHLEGMATIZED HMX Section II - Hazardous Ingredieltts Ingredient Percent CYCLOTETRAMETHYLENE TETRANITRAMI NE T.L.V.: P.:E. L. Ingredient Percent GRAPHITE T.L.V.: P.E.L. I Ingredient ,~ Percent T.L.V.: P,E.L. Section III - Physical Data Boiling Point: N/A ISpecific Gravi~ty: 1.96 Vapor Pressure:N/A I Percent Volatile: N/A Vapor Density: N/A I Evaporation Rate: N/A Section III continued on Page 2 Sub~,diarw of: Enslgn-Bickford lndus~r,cs, Inc. 11125185 NDEX: ..1..0 UN ¥ NO. 5313 December 19, 1988 Page 11 of 33 _'ta Sheet for: DESENSITIZED HMX;PHLEGMATIZED HMX Manufactured By: THE ENSIGN-BICKFORD COMPANY Section III - Physical Data continued Solubility in water: INSOLUBLEIMelting Point: 527° F Appearance and:ODORLESS CRYSTALLINE SOLID WITH COLOR RANGING Odor :FROM WHITE TO GREY DEPENDING ON WAX AND/OR GRAPHITE CONTENT Section IV - Fire and Explosion Hazard Data Flash Point: N/A (F):Flamm.: Lel: : Uel: Extinquishing Media: NONE Special Firefighting: DO NOT FIGHT FIRES WHERE HMX IS PRESENT. Procedures : ISOLATE AREA. EVACUATE PERSONNEL TO A SAFE AREA. Unusual Fire and : WILL DETONATE IF SUITABLY PRIMED WITH Explosion Hazards : SEVERE IMPACT OR BY HEAT OR FLAME. HAZARDOUS GASES PRODUCED IN FIRE ARE NITROGEN OXIDES. Auto Ignition Temperature: N/A Section V - Health Hazard Data Threshold Limit Value: NONE ESTABLISHED Effects of Overexposure Eye : Contact : NONE Skin : Contact : NONE Inhalation: SLIGHTLY TOXIC BY INHALATION Ingestion : SLIGHTLY TOXIC BY INGESTION Section V Continued 6n Page 3 ND X: 44 .40 UNiT NO. 5313 December 19, 1988 Page 12 of 33 Data Sheet for:DESENSITIZED HMX;PHLEGMATIZED HMX Manufactured By: THE ENSIGN-BICKFORD COMPANY Section V - Health Hazard Data (c'ontinu~d) Emergency and First Aid Procedur,~s Eye : Contact : FLUSH EYES WITH WATER Skin : WASH WITH SOAP AND WATER Contact : Inhalation: IF DETONATION FUMES ARE INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPI}~TION, PREFERABLY MOUTH TO MOUTH. IF BREATHING IS DIFFICULT GIVE OXYGEN, CALL A PHYSICIAN. Ingestion : INDUCE VOMITING IMMEDIATELY BY GIVING T%IO GLASSES OF WATER AND STICKING FINGER DOWN THROAt. I Section VI - Reactivity Data Stability: STABLE Conditions to Avoid: BECOMES UNSTABLE WITH EXPOSURE TO EXTREME HEAT,IMPACT, OR ELECTROSTATIC DISCHARGE. Incompatability : HMX AND RD 1333 LEAD AZIDE MIXTURES OR INTERFACES BECOME SUPERSENSITIVE WHEN HEATED TO 400a F FOR + HOUR. A SIMILAR SUPERSEN- SITIVIT, Y RESULTS WHEN HEATED HMX IS MIXED WITH UNHEATED RD-1333 LEAD AZIDE. Hazardous Decomp. : HAZARDOUS FUMES PRODUCED ARE NITROGEN Products : OXIDES. Hazardous Polymerization: WILL NOT OCCUR Conditions to Avoid: AVOID BREATHING DUST. AVOID BREATHING FUMES FROM DETO]~ATION. SectiOn VII - Spills or Leak Procedur,~s Steps to be Taken : REVIEW FIRE & EXPLOSION HAZARDS AND SAFETY In Case Material is: PRECAUTIONS BEFORE PROCEEiDING WiTH CLEAN UP. Released or Spilled: USE APPROPRIATE PERSONAL ~PROTEC'ION DURING CLEAN UP. MOP UP WITH WAT~ER. Waste Disposal : CONSULT AN EXPLOSIVES MANUFACTU]~ER FOR Method : RECOMMENDED METHODS FOR D'ESTROYi[NG EXPLOSIVE MATERIALS. COMPLY WIT! APPLICABLE FEDERAL REGULATIONS. I INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 13 of 33 Data Sheet for:DESENSITIZED HMX;PHLEGMATIZED HMX Manu£actured By: THE ENSIGN-BICKFORD COMPANY Section VIII - Specical Protection Information Respiratory : FILTER RESPIRATOR: NIOSH CERTIFIED DUST Protection : RESPIRATOR. AVOID DUSTING BY KEEPING WET WHEN POSSIBLE. Ventilation Local Exhaust : N/A Specia 1 : N/A Mechanica 1 : N/A Other : N/A Protective Gloves : BUTYL GLOVES Eye Protection : GOGGLES Other Protective : NONE Equipment : Section IX - Specical Precautions I Precautions To Be : TRANSPORTATION AND STORAGE MUST BE IN Taken in Handling : COMPLIANCE WITH STATE AND FEDERAL and Storing, Etc. : REGUlaTIONS Other Precautions : REFER TO MANUFACTURER'S INSTRUCTIONS AND WARNINGS SUPPLIED WITH PRODUCT. Data Sheet Prepared By: E.L. STEARNS Last D~ta Sheet Revision: INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 14 of 33 HNS 2.2'.4,4'.6,6' -- Hexanitrostilbene Specification: WS 5003 Type I and II, Grade A and B HNS was first prepared at the Naval Ordnance Laboratory, White Oak, Silver Spring, Maryl~ nd, to meet a require- ment for a heat-resistant explosive. Demonstrated acceptable performance over the tem. p ~rature range -320° F to +525°F attests to the success of this effort. Subsequent studies have proven HNS to possess other superior prol~erties which have resulted in its use in additional designs not requiring heat resistance HNS has a uniquely small critical diameter (on the order of 0.020 inches), is practically insensitive to elect'ostatic spark, is less sensitive to impact than tetryl, and is radiation resistant. Chemtronics, Inc., in response o increased demands for HNS. in 1976 designed and'constructed an HNS manufacturing facility. This on-stre~ m plant is capable of producing quantities up to 100 pounds per day of HNS-I and commensurate quantities of I~NS-II nitric recrystal- lized or organically recrystallized. Strict quality control is employed during all operatio~ns. This has contri- buted to exceptionally high lot-to-lot uniformity, with analytical test data well= within all Icurrent physical and chemical specification requirements. J / TYPICAL PROPERTIES TYPE I TYPE II Melting Point ................................................... 316°C (60i°F) dec. 319°C (607°F) dec. Particle Size .......... .......................................... 1-5 microns 100-300 microns Bulk Density .................................................... 0.15-0.35 gm/cc 0.45-1.0 gm/cc 50% Impact Height: NOL-ERL Machine. Type 12 Tools. 5/0 Sandpaper, 2.5 Kg Wt ..................................... 44 cm 61 cm Vacuum Stability @ 260°C (500°F): First 20 minutes .............................................. 1.8cc/gm/hr O3cc/gm/hr Additional 2 hours ........................................... 0.6cc/gm/hr 0,2cc/gm/hr Electrostatic Spark Sensitivity: Fires Above ...................... 0.001 ufd @ 8 kv 0.0001 ufd @ 17 kv Differential Thermal Analysis: Onset of Exotherm ................ 315° C (599° F) 325° C (617° F) TYPICAL PROPERTIES, TYPE I AND TYPE II Molecular Weight: C~4H~N60~2 ....................................................................... 450,25 Autoignit on Point ............................................................................ 325° C (618° F) Vapor Pressure .......................................................... 2.9 x 10-6 mm' I-Ig (~ 160°C (320°F) Weight Loss @ 210°C (410°F) ......................................................... Negligible after 48 hrs Decomposition Rate @ 260°C (500° F) ................................................................ 0.1%/hr Vacuum Stability @ 280° C (536° F) .............................................................. 2.7 cc/gm/hr Heat of Combustion ............................................................................ 3451 Cai/gm Oxidant Balance ................. -2.22 (Equivalents of oxidant per 100 gm explosive for C-- CO and H-- H20) Detonation Velocity ............................................... 7,000 meters/second 1,70 gm/cc density Theoretical Density ............................................................................ 1.74 gm/cc Friction Sensitivity .............................................................. 10/10 N, Fires @440 kg-cra Mean Firing Voltage for EBW ........ 1 ufd capacitor, gold wire 4 mil dia. x 150 mil. = 12,95 v @ 0.gg/cm3 dens The information set forfh with respect Io the performenC~ or uae of tudal)ility of Iuch products for their patti( jlar I:)urpOte$. Likewise. our products is based on published data and ~s believed, b~! not statements concerning the possible uses o our products are not in- warranted, tO be accurate The products d~scussed are ~old without fended as recommendations to use our pr( ducts ~n Ihe infringement warranty, as to fitness of performance, expressed or ~molied. and uponof any I~atanf. condit,on that purchasers shall make their own tests to determine the CHEMTRONICS, INC. · OLD BEE TREE ROAD · SWANNANOA. N.C. 28778 TELEPHONE (704) 298-7941 INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 15 of 33 BULK POWDER PYX CHEMICAL NAME: 2,6-bis(picrylamino)-3,§-dini~ropyridine DESCRIPTION : Yellow co oranEe crTs~all£ne powder. SOLUBILITY : Soluble in 90% nitric acid, slightly soluble in acetone or ceconi¢rile. ]lYrICAL SPECIFICATIONS Percent Wax ' 0.0% Percent Graphite: 0.0% Granulation · Made to order, average Loose Powder: 1.0% weight loss particle sizes range Weight Loss ' in 24 hours at [rom 20 - 120 microns. 572 degrees F. PACKAGING INFORMATION Standard Package: 11 gallon Drum Dimensions: 13"7'diameterl ' fiberboard drum x high Weight · Gross 31 pounds Net 25 pounds SHIPPPING INFORMATION U.S.D.O.T. Class: Class A U.N. Class : 1.1D High Explosive U.N. Number: Not available EX Number : EX-8307858 CA Number : Not' available IINDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 16 of 33 Material Safety Data Sheets Section I Manufacturer's Name IEmergency TelePhone 5o. The Ensign-Bickford CompanyI 1-203-658-441 Address (Number,Street,City,State,Zip Code) 660 Hopmeadow Street, Simsbury, CT 06070 Chemical Name & Synonyms ITrade Name & Synonyms 2,6-BIS(PICRYLAMINO)-3,5-DINITROPYRIDINEI PYX Chemical Family IFormula IC.A.S. Number AROMATIC NITRO COMPOUND C~H~ N~, O,~ 38082-89-2 Section II - Hazardous Ingredi(!nts Ingredient Percent 2,6-BIS(PICRYL3d~IINO)-3,5-DINITROPYRIDINE T.L.V.: P.E.L. Section III - Physical Data Boiling Point: N/A (F) ISpecific Gravity: 1.77 Vapor Pressure: N/A IPercent Volatile: N/A Vapor Density: N/A IEvaporation Rate: N/A Solubility in Water: INSOLUBLEIMolting Point: > 370° C Appearance and: ODORLESS YELLOW CRYSTALLINE SO]JID. Odor : Su~idiarx of. '~ Ensign-B;~ kford industries, Inc. I 1/2 5/8 5 December 19, 1988 Page 17 of 33 Data Sheet For: 2,6BIS(PICRYLAMINO) 3,5DINITROPYRIDINE Manufactured By: THE ENSIGN-BICKFORD COMPANY Section IV - Fire and Explosion Hazard Data Flash Point: N/A (F) :Flamm.: Lel: : Uel: Extinquishing Media: NONE Special Firefighting: DO NOT FIGHT FIRE WHERE PYX IS PRESENT. Procedures : ISOLATE AREA. EVACUATE PERSONNEL TO A SAFE PLACE. Unusual Fire and : EMITS TOXIC FUMES UPON EXPLOSION. WILL Explosion Hazards : DETONATE IF SUITABLY PRIMED WITH SEVERE IMPACT, EXTREME HEAT OR FLAME. Auto Ignition Temperature: N/A Section V - Health Hazard Data Threshold Limit Value: LD 5 GMS/KG - RATS Effects of Overexposure Eye : Contact : MILD AND TRANSITORY EYE IRRITANT Skin : SKIN CONTACT'SHOULD NOT CAUSE IRRITATION. Contact : Inhalation: NONE AVAILABLE - AVOID Ingestion : NONE AVAILABLE - AVOID Section V Continued on Page 3 INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 18 of 33 Data Sheet For: 2,6BIS(PICRYLAMINO) 3,5DINITROPYRIDINE Manufactured By: THE ENSIGN-BICKFORD COMPANY Section V - Health Hazard Data (continue~) Emergency and First Aid Procedures Eye : FLUSH EXPOSED AREAS THOROUGHLY WITH WATE . Contact : Skin : WASH WITH SOAP AND WATER. Contact : Inhalation: IF DETONATION FUMES ARE INHALED REMOVE T FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL IRATION, PREFERABLY MOUTH TO MOUTH. IF BREATHING ~LT, GIVE OXYGEN. CALL A.PHYSICIAN. Ingestion : INDUCE VOMITING IMMEDIATELY BY GIVING 9 GLASSES OF WATER AND STICKING FINGER DOWN . Section VI - Reactivity Data Stability: STABLE Conditions to Avoid: PYX BECOMES UNSTABLE WITH URE TO EXTREME HEAT, IMPACT, OR ELE~ OSTATIC DISCHARGES. Incompatability : NO KNOWN HAZARDOUS CONDITIONS N COMBINAT- ION WITH OTHER CHEMICALS. Hazardous Decomp. : OXIDES OF NITROGEN PRODUCED ,N Products : DECOMPOSITION. Hazardous Polymerization: WILL NOT OCCUR Conditions to Avoid: AVOID INHALATION OF DETONATION PRODUCTS. Section VII - Spills or Leak Pirocedu]:es Steps to be Taken : REVIEW FIRE & EXPLOSION !HAZARD~ AND SAFETY ;ITH CLEAN UP. In Case Material is: PRECAUTIONS BEFORE PROCEEDING! Released or Spilled: USE APPROPRIATE PERSONAL' PROTECTIVE EQUIP- MENT DURING CLEAN UP.MOP UP SPILL WITH WATER Waste Disposal : CONSULT AN EXPLOSIVES MANUFACT13RER FOR Method : RECOMMENDED METHODS FOR DESTROfING EXPLOSIVE MATERIALS. COMPLY WI'~H APPLICABLE December 19, 1988 Page 19 of 33 Data Sheet For: 2,6BIS(PICRYLAMINO) 3,5DINITROPYRIDINE Manufactured By: THE ENSIGN-BICKFORD COMPANY Section VIII - Specical Protection Information Respiratory : FILTER RESPIRATOR: NIOSH - CERTIFIED DUST Protection : RESPIRATOR. Ventilation Local Exhaust : NONE Special : N/A Mechanical : N/A Other : N/A Protective Gloves : BUTYL GLOVES Eye Protection : GOGGLES Other Protective : NONE Equipment : Section IX - Specical Precautions I Precautions To Be : TRANSPORTATION AND STORAGE MUST BE IN Taken in Handling : ACCORDANCE WITH FEDERAL AND STATE and Storing, Etc. : REGULATIONS Other Precautions : REFER TO MANUFACTURER'S INSTRUCTIONS AND WJ~RNINGS SUPPLIED WITH PRODUCT. Data Sheet Prepared By: E.L. STEARNS Last Data Sheet Revision:· INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 20 of 33 tad Azide Ihe preparation, lhe formation of larce crystals must be avo~dee eiazid; azoture de plomb since the breakup of the crystellin; ~ needles may produce an explosion. Accordingly, technical grade producl ~s mostly Pb(N3)2 manufactured; it contains 92--96 % 'b(N3)~. and ~s precipitated ~n colorless crystals; mlcrocrystalline the presence of dextrin. 'polyv~nyl ~cohol. or other'substances granules, if dextr~nated which mtedere with crystal growth. L(~ad azide is employed as an molecular weight: 291.3 iniliating explosive in blasting caps. When used as a primary energy of formation: + 346 kcal/kg = + 1450 k J/kg charge, it iS effective in smaller quanlities than mercury tulminate. entbalpy of formation: +340 kcal/kg = + 1420 k J/kg has a higher triggering rate, and. unlil;e mercury fulminate, cannot oxygen balance:--5.5 % be dead-pressed by even relatively Iow pressures. In order to nitrogen percentage: 28.85 % improve its flammability, an easily flarr mable additive, such as lead volume of detonation gases: 308 l/kg trinitroresorcinate, is added. Lead azide is decomposed by explosion heat: 367 kcal/kg = 1540 k J/kg atmospheric CO2, with evolution of hy:lrazoic acid. density: 4.8 g/cma Lead azide detonators for use in coal mining have copper lead block test: 110 cm3/10 g capsules; for all other blastings, aluminum caps are used. detonat,on velocity, confined: 4,500 m/s ~ 14 800 ft/s at ~: 3.8 g/cm3 Specifications 5300 m/s ~ 17 400 ft/s at 12 4.6 g/cm3 net content (by determination deflagration point: 320--360 °C 600--680 'F as PbCrO4): not less than 91.5 % impact sensitivity: moisture: not more than 0.3 % pure product: 0.25--0'.4 kp m 2 5--4 N m mechanical imPurities: nil dextrinated: 0.3--0.65 kp m 3--6.5 N m water solubles: not more :hen 1% friction sensitivity: lead content: at least 68 % at 0.01--0.1 kp = 0.1--1 N pistil load explosion copper: free reaction: neutral, ad azide is insoluble in water, is resistant to heat and moisture, not acid d is not too hygroscopic. It is prepared by reacting aqueous bulk density: at least 1.1 g/cra3 lutions of sodium azide and lead nitrate with each other. During deflagration point: not bel~)w 300 °C 572 'F INDEX: 441.40 UNIT NO. 5313 December 19, -1988 Page 21 of 33 Material Safety Data Sheets Section I Manufacturer's Name IEmergency Telephcne ~c. The Ensig~,-Bickfo£d Company I 1-2t~3-65~-4411 Address (Number,Street,City,State,Zip Code) 660 Hopmeadow Street, Simsbury, CT 06070 Chemical Name & Synonyms Trade ~ame & Synon.y~,s NOT A CHEMICAL [PRIMADETA Nonelectric detonator-~ ChemicalN/A Family I FormulaN/A [C.A.S. Number Section Ii - Hazardous Ingredients Ingredient [Percent PENTAERYTHRITOL TETRANiTRATE T.L.V.: I P.E.B.: I Ingredient I Percent LEAD AZIDE T.L.V.: i P.E.L.: Ingredient Percent SILICON T.L.V.: P.E.L.: Ingredient Percent RED LEAD T.L.V.: P.E.L.: IIngredient Percent I BARIUM CHROMATE T.L.V.: P.E.L.: Section II Continued on Page 2 Subsidmr7 of: Ens~gn-Bicld'ot,~ Industries, Inc. I 1/25185 INDEX: 441.40 UNIT NO.5313 IData Sheet ,for: [N ELECTRIC D]~TONATORS December19,1988 Page22of33I Manufactured By: THE ENSIGN.-BICKFORD CO Section II - Hazardous Ingredients (contin~ ~d) Ingredient Percent POTASSIUM PERCHLORATE Ingredient Percent OTTAWA SILICA T.L.V.: P.E.L.: Ingredient Percent LEAD CHROMATE T.L.V.: 0.050 mg/m3 P.E.L.: Ingredient Percent SELENIUM T.L.V.: 0.200 mg/m3 P.E.L.: Ingredient Percent MOLYBDENUM T.L.V.: P.E.L.: Ingredient Percent TUNGSTEN T.L.V.: P.E.L.: Ingredient Percent ALUMINUM T.L.V.: P.E.L.: Ingredient Percent LEAD T.L.V.: .05 rog/m3 P.E.L!.: .0! mg/m3 I Section III - Physical Data I Boiling Point: N/A. ISpecific Gravity: N/A Vapor Pressure:N/A IPercent Volatile: N/A Vapor Density: N/A IEvaporation Rate: N/A Solubility in Water: N/A IMelting Point: N/A ~ Appearance and:ALUMINUM SHELL CONTAINING APPROXIMATELY 100 MG Odor :LEAD AZIDE & 400-800 mg PENTAERYTHRiTOL TETi ANITRATE (PETN) WITH PLASTIC TUBE ATTACHED I INDEX: 441.40 UNIT December19,1988 Page23of33 Data Sheet for: PRIMADET~ON ELECTRIC DETONATORS Manufactured By: THE ENSIGN-BICKFORD COMPANY · Section IV - Fire and Explosion Hazard Data Flash Point: N/A (F) :Flamm.: Lel~ : Uel: Extinquishing Media: NONE Special Firefighting: DO NOT FIGHT FIRE. ISOLATE AREA. Procedures : EVACUATE PERSONNEL TO A SAFE PLACE. Unusual Fire and : HAZARDOUS FUMES PRODUCED IN FIRE ARE LEAD Explosion Hazards : LEAD FUMES AND NITROGEN OXIDES. WILL DETONATE IN A FIRE. Auto Ignition Temperature: N/A Section V - Health Hazard Data IThreshold Limit Value: NOT ESTABLISHED Effects of Overexposure Eye : Contact : NOT A LIKELY ROUTE OF EXPOSURE Skin : NOT A LIKELY ROUTE OF EXPOSURE Contact : Inhalation: NOT A LIKELY ROUTE OF EXPOSURE Ingestion ~ NOT A LIKELY ROUTE OF EXPOSURE Emergency and First Aid Procedures --------------------------.--------------------------_ Eye : Contact : N/A Skin : N/A Contact : Inhalation: IF DETONATION FUMES ARE INHALED REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH TO MOUTH. IF BREATHING DIFFICULT GIVE OXYGEN. CALL A PHYSICIAN. Ingestion : N/A IINDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 24 of 33 Data Sheet for: P~RIMADET~NO~ ELECTRI.~ Manufactured By: THE ENSIGN-BICKFORD COMPANY Section VI - Reactivity Data Stability: STABLE Conditions to Avoid: BECOMES UNSTABLE WITH HEAT FRICTION, OR IMPACT. IncomPatability : INCOMPATIBLE WITH ACIDSf ALKAL . Hazardous Decomp. : HAZARDOUS GASES PRODUCED ARE NITROGEN Products : OXIDES. Hazardous Polymerization: WILL NOT OCCUR Conditions to Avoid: HEAT, SHOCK, FRICTION, OR IMPA:T. AVOID BREATHING FUMES FROM DET()NATION. Section VII - Spills or Leak Procedu]'es I Steps to be Taken : REVIEW FIRE & EXPLOSION HAZARD~ & In Case Material is: SAFETY PRECAUTIONS BEFORE EDING Released or Spilled: WITH CLEAN UP. USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT URING CLEAN UP Waste Disposal : CONSULT AN EXPLOSIVES ~R FOR Method : RECOMMENDED METHODS FOR DEST ING EXPLOSIVE MATERIALS. INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 25 of 33 Data Sheet for: PRIMADET~NON ELECTRIC DETONATORS Manufactured By: THE ENSIGN-BICKFORD COMPANY Section VIII - Specical Protection Information Respiratory : NONE Protection : Ventilation Local Exhaust : N/A Special : N/A Mechanical : N/A Other : N/A Protective Gloves : NONE Eye Protection : SAFETY GLASSES Other Protective : NONE Equipment : Section IX - Specical Precautions I Precautions To Be : TI~NSPORTATION AND STORAGE MUST BE IN Taken in Handling : ACCORDANCE WITH FEDERAL AND STATE and Storing, Etc. : REGULATIONS Other Precautions : REFER TO MANUFACTURER'S INSTRUCTIONS AND WARNINGS SUPPLIED WITH PRODUCT. Data Sheet Prepared By: E.L. Stearns Last Data Sheet Revision: INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 26 of 33 Material Safety Data Sheet SECTION I MANUFACTURER'S NAME: EMERGENCY TELEPHONE NO. The Ensign-Bickford Company 1-203-658-4411 ADDRESS: 660 Hopmeadow Street, Simsbury, CT 06070 CHEMICAL NAME & SYNONYMS: ~AME&SYND/IYJ S: Not A Chemical /O~l_~ellf ' ~- ~ --Cartridge, er~ ~i-directional Boos~ N/ACHEMICAL FAMILY I N/AFORMULA I N/AC'A'S' NUMBER SECTION II - HAZARDOUS INGREDIENTS Inqredient: Percent: 100~ Cyclotetramethylene tetranitramine (HMX). Threshold Limit Value: Permissible Exposure Limit: N/A N/A SECTION III - PHYSICAL DATA Boiling Point: N/A Specific Gravity: N/A Vapor Pressure: N/A Percent Volatile: N/A Vapor Density: N/A Evaporation Rate: N/A Solubility in Water: N/A Melting Point: N/A Appearance and Odor: Aluminum shell (cup) containing cyclotetra- methylene tetranitramine (HMX) and polyethylene end plug. subsidiary of E nsign-Bickford Industri~, Inc. NDEX: 441.40 NO. 5313 December 19, 1988 Page 27 of 33 Material Safety Data Sheet for: Oil Well Cartridge, HMX Page 2 Manufactured by: The Ensign-Bickford Company SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Flamm. Limits: N/A Lel: Uel: Extinguishing Media: None. Special Fire Fighting Do not fight fire. Isolate area. Evacuate Procedures: personnel to a safe place. Unusual Fire and May detonate in fire. Hazardous Gases Explosion Procedures: produced are nitrogen oxides. Auto IGnition Temperature: N/A SECTION V - HEALTH HAZARD DATA Threshold Limit Value: N/A Effects of Overexposure Eye Contact : Not a likely route of exposure. Skin Contact: Not a likely route of exposure. Inhalation : Not a likely route of exposure. Ingestion : Not a likely route of exposure. Emergency and First Aid Procedures Eye Contact : N/A Skin Contact: N/A Inhalafion : If detonation fumes are inhaled, remove to fresh air. If not breathing, Give artificial respiration. If breathing is difficult, contact a physician. Ingestion : N/A INDEX: 441140 UNIT NO. 5313 December 19, 1988 Page 28 of 33 Material Safety Data Sheet for: Oil Cartridge, HMX Page 3 Manufactured by: The Ensign-Bickford Company SECTION VI - REACTIVITY DATA Stability: Stable. Conditions To Avoid: Becomes unstable with shock, fl~iction, impact or exposure to heat abo,~e manufacturer's recommended ran('e. Incompatibility: None known. Hazardous Decomp. Hazardous gases produced, are n~ trogen Products: gases. Hazardous Polymerization: Will not occur. SECTION VII - SPILL OR LEAK PROCEDURES Steps to be Taken Review fire and explosion hazards an,~ safety In Case Material Is precautions before proceeding with clean up. Released or Spilled Use appropriate personal protective .=quipment during clean up. Waste Disposal Consult an explosives manufacturer f,)r recom- Method: mended methods for destroying explosive materials. SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: None. Local Exhaust: N/A Special: N/A Mechanical: N/A Other: N/A Protective Gloves: None. Eye Protection: Safety glasses. Other Protective Equipment: None. I ~NDEX: 44~.40 UNIT NO. 5313 I December 19, 1988 Page 29 of 33 Material Safety Data Sheet: Oil Well Cartridge, HMX Page 4 Manufactured by: The Ensign-Bickford Company SECTION IX - SPECIAL PRECAUTION Precautions To Be Taken Transportation and storage must be in In Handling and Storing accordance with Federal and State Etc.: regulations. Other Precautions: Refer to manufacturer's instructions and warnings supplied with product. Data Sheet Prepared By: R.J. Peebles Last Data Sheet Revision: December 19, 1988 Page 30 of 33 Material Safety Data Sheet SECTION I MANUFACTURER'S NAME: EMERGENCY TE]JEPHONE NO. The Ensign-Bickford Company 1-203-658-44 1 ADDRESS: 660 Hopmeadow Street, Simsbury, CT 06070 CHEMICAL NAME & SYNONYMS: Not A Chemical Well Cartr: Bi-directional CHEMICAL FAMILY I FORMULA I C.A.S. NUMBIR N/A N/A N/A SECTION II - HAZARDOUS INGREDIENTS Ingredient: Percent: 100% 2, 6-bis-(pikrylaminQ)-3.5-dinitropyridine (PYX) Threshold Limit Value: Permissible Exp)sure Limit: N/A N/A SECTION III - PHYSICAL DATA Boiling Point: N/A Specific Gravity: /A Vapor Pressure: N/A . Percent Volatile: I/A Vapor Density: N/A Evaporation Rate: I/A · Solubility in Water: N/A Melting Point: Appearance and Odor: Aluminum shell (cup) containing PY explosive and polyethylene end plug. a subsidiary of Emign-Bickford Industries, Inc. INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 31 of 33 Material Safety Data Sheet for: Oil Well Cartridge, PYX Page 2 Manufactured by: The Ensign-Bickford Company SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A Flamm. Limits: N/A Lel: Uel: Extinguishing Media: None. Special Fire Fighting Do not fight fire. Isolate area. Procedures: Evacuate personnel to a safe place. Unusual Fire and May detonate in fire. Hazardous gases Explosion Procedures: produced are nitrogen oxides. Auto Ignition Temperature: N/A SECTION V - HEALTH HAZARD DATA Threshold'Limit Value: N/A Effects of Overexposure Eye Contact : Not a likely route of exposure. Skin Contact: Not a likely route of exposure. Inhalation : Not a likely route of exposure. Ingestion : Not a likely route of exposure. Emerqency and First Aid Procedures Eye Contact : N/A Skin Contact: N/A Inhalation : If detonation fumes are inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, contact a physician. Ingestion : N/A INDEX: 441.40 UNIT NO. 5313I December 19, 1988 Page 32 of 33I " Material Safety Data Sheet for: Oil Cartridge, PYX Page 3 Manufactured by: The Ensign-Bickford Company SECTION VI - REACTIVITY DATA Stability: Stable. Conditions To Avoid: Becomes unstable with shock, ~riction, impact or exposure to heat ab(~ve manufacturer's recommended rarge. Incompatibility: None known. Hazardous Decomp. Hazardous gases produced are itrogen Products: gases. Hazardous Polymerization: Will not ocCur. SECTION VII - SPILL OR LEAK PROCEDURES Steps to be Taken Review fire and explosion hazards aI~d safety In Case Material. Is precautions before proceeding with ;lean up. Released or Spilled Use apprOpriate personal protective equipment during clean up. Waste Disposal Consult an explosives manufacturer for recom- Method: mended methods for destroying explo.~ive materials. SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: None. Local Exhaust': N/A Special: N/A Mechanical: N/A Other: N/A Protective Gloves: None. Eye Protection: Safety glasseS. Other Protective Equipment: None. INDEX: 441.40 UNIT NO. 5313 December 19, 1988 Page 33 of 33 Material Safety Data Sheet: Oil Well Cartridge, PYX Page 4 Manufactured by: The Ensign-Bickford Company SECTION IX - SPECIAL PRECAUTION Precautions To Be Taken Transportation and storage must be in In Handling and Storing accordance with Federal and State Etc.: regulations. Other Precautions: Refer to manufacturer's instructions and warnings supplied with product. Data Sheet Prepared By: R.J. Peebles Last Data Sheet Revision: BAKER %Ji%II'T' 5313-1 SAND CONTROL Index: 441.40 September 5, 1988 A Baker Hughes company Replaces: -- Page 1 of 9 PRIMACORD FOR USE WITH BAKER PERFORATING GUNS © 1986, by Baker Sand Control Division Baker-Hughes, Inc. THIS DOCUMENT IS CONFIDENTIAL AND IS THE PROPERTY OF BAKER SAND CONTROL DIVISION BAKER-HUGHES, INC. ("BAKER"). IT MAY NOT BE COPIED OR REPRODUCED IN WHOLE OR IN PART IN ANY WAY WITHOUT THE EXPRESS WRI~FrEN CONSENT OF BAKER. THIS DOCUMENT ALSO IS AN UNPUBLISHED WORK OF BAKER. BAKER OWNS ALL RIGHTS TO THIS WORK AND INTENDS TO MAINTAIN THIS WORK CONFIDENTIAL AND AS A TRADE SECRET. BAKER MAY ALSO SEEK TO PROTECT THIS WORK AS AN UNPUBLISHED COPYRIGHT. IN THE EVENT OF EITHER INADVERTENT OR DELIBERATE PUBLICATION, BAKER INTENDS TO ENFORCE ITS RIGHTS TO THIS WORK UNDER THE COPYRIGHT LAWS AS A PUBLISHED WORK. THOSE HAVING ACCESS TO THIS WORK MAY NOT COPY, USE OR DISCLOSE THE INFORMATION IN THIS WORK UNLESS EXPRESSLY AUTHORIZED BY BAKER TO DO SO. The following Primacords are used in Baker Perforating 5. Always keep hands and gage blocks free of grease Guns: since grease can desensitize explosives. Type Comm. No. 6. Never make sharp bends or buckles in cord because 40 Grain RDX Nylon Ribbon* 06-75790-00 this can damage the explosive core and cause Iow 40 Grain HMX Nylon Ribbon, LS 06-75790-01 order detonation. 40 Grain HNS Lead Ribbon .06-75790-02 7. Store cords below 150°F or degradation can occur. ~8d:'Grain ~X'Nylon,".LS~' ~06,.75~4400,f 8. Always visually inspect cords for damage such as pin .,~'6 Gr.a,i~' FIMX~Nylon~L:St ~.~ holes or cracks in jacket. Look for explosive voids in 'K0 ~Gra~-n'~J~-~as:]~3'~nd 06-75014-02 cord by detecting recesses or pits in cord. Reject ques- 100 Grain PYX Aluminum Round 06-76269-00 tionable cord because scrapping cord is much All cords are received in Houston prior to shipment for cheaper than a misrun. 9. Do not hit or drop heavy objects on cord. inspection per QC/QA 1006-180-11 and 1006-180-12. 10. Never dispose of small pieces of cord by placing in The term "grain" is a measure of weight where 7,000 a loaded perforating gun. This could cause transfer grains equals 1 pound. Eighty grain primacord means 80 or charge interference problems within the gun. If RDX grains of explosives per linear foot of cord. The cords used cord scrap was placed in a high temperature explosive in Baker guns have been selected based on reliability, package, the RDX could predetonate at high tempera- price, and ease of assembly in perforating guns. ture. Primacord is shipped on spools. On the end of the spool 11. Use continuous uncut cord through gun. Do not use is a series of numbers. For example; for a 500 foot spool lap connections or union boosters since these reduce there may be a "300-50-150" which means the spool has reliability. two splices (i.e., 3 pieces of 300 feet, 50 feet, and 150 feet). 12. When cutting textile cord in the "Primacord Gage The spools, when ordered, should specify a maximum of Block" use a slicing action rather than a pushing three splices because the more splices the greater the loss action. Pushing the razor through the cord can smash of drop-off cord. *_..Not available in L.S. and damage the explosive core. NOTE: LS means "Low Shrink." 13. A 7/32" drill gage hole has been added to the gage blocks to allow the field to O.'D. gage cord. SPECIAL NOTES 1. Always be sure cords are kept dry. Wet boxes should TEXTILE BRAIDED DETONATING CORD be returned to vendor. The explosives, coreloads, diameter, braid materials and 2. WARNING: Always cut primacord with a sharp, clean sheath materials of this product line have been tailored razor blade. DuPont No. 4 Crimping Tools should not to meet the varied needs of the oil and gas well comple- be used to cut cord. tion industry. Coreloads range from 40 grains per foot to 3. Always remove a minimum of 6 inches of cord before 100 grains per foot. Explosive materials include RDX, attaching booster. Cut cord and attach booster HMX, HNS, and PYX. Braid materials include polyester, immediately, rayon and fiberglass. Sheath materials include plastic or 4. Do not allow powder to drop out of end of jacket. Cut nylon. Low shrink cords use Kevlas which is a thermally should be straight with no powder loss. Use cutting stable plastic. gage blocks when cutting textile cords. Metal jacketed RDX - Cyclotrimethylene, is naturally white in color but cords must be cut by marking length of cord and then is frequently dyed pink for use in linear exPlosive products. rocking razor blade around entire outside diameter of The melting point of RDX is 339°F (204°C); the detona- cord. There is no need to cut all the way through cord. tion velocity is 8,180 meters per second at a density of 1.65 Once a mark or groove is on O.D. of cord, it can be g/cc. The temperature resistance of RDX detonating cord snapped without losing powder, is dependent on sheath material and RDX purity. Most IINDEX: 441.40 UNIT NO. 5313-1 September 5, 1988 Page 2 of 9 RDX cords will withstand 325°F (163°C) or slightly higher HNS - Hexanitrostilbene, has a Iow .~r initiation sensitivity for short periods of time. than RDX and meets the initiation ser~sitivity criteria of MIL- HMX - Cyclotetramethylene Tetranitramine, a homolog STD-1316. HNS is pale yellow in cole r, has a melting point of RDX, is white to colorless and often used when rem- of 601°F (316'~C) and a detonation rae of 6,900 meters per perature requirements are slightly higher than recom- second at a density of 1.6 g/cc. HNS used by The Ensign- mended for RDX. HMX is very similar to RDX in output Bickford Company is type II conform ng to WS-5003F. Two and susceptibility to initiation. The melting point of HMX grades of HNSJI are covered by WE-5003F. Grade A has is 523°F (273°C), 1.84 g/cc. Most HMX cords can withstand been subjected t© and passed sensi :ivity and output'tests 350°F (177°C) for short periods of time. of WS-5003F; grade B has not be( '~ subjected to those tests but meets all other requireme~ :ts of WS-5003F. The METAL JACKETED PRIMACORD Ensign-Bickford Company produ( ~s HSN-II with the Higher coreload cord is also available to meet specific organic process using the acetonibile-toluene extraction demands. Forty (40) to 100 (80) grains/foot are the common process originally developed by Ta3'lor and Oesterling at sizes used in oilfield applications, the Naval Surface Weapons Center Yhite Oak Laboratory. PYX - 2, 6-Bis (picrylamino) - 3, i - Dinitro pyridine, is Typical Oilfield Specifications a secondary high explosive with a yellow crystalline ap- Coreload Diameter Sheath pearance. The melting point of PY)< 860°F (460°C). PYX (gr/ft) Explosives {Inches) Material Configuration is 'stable to 662°F (350°C). 40 HNS-II ' Lead Ribbon 80 HNS-II ,200 ± .007 Lead Round 100 PYX .210 Aluminum Round * Not applicable - flat (ribbon) cord dimensions are - height: .082 inch maximum, width: .210 inch maximum IINDEX: 441.40 UNIT NO. 5313-1 I September 5, 1988 Page 5 of 9 BAKER COMM. NUMBER 06-75790-02 SPECIAL APPLICATION PRIMACORD® DETONATING CORD 40 HNS LEAD RIBBON DESCRIPTION: Flat lead sheath wl¢h an HNS explosive core. APPLICATION: The hi~her ou¢pu¢ of Chis cord's fla¢ construction makes ideal for ini¢ia¢lng shaped charges in ¢he smaller perforating guns. The HNS explosive core will function a¢ ~empera¢ures which exceed ~he limits of R DX. -. SPEGIFICATIQN$ Explosive : HNS Dimensions : Height 0.082 in. max. : Width 0.210 in. max. Nominal : Explosive : 40 grains/foot Temperature: , Core Load : 8.50 grams/meter · Resistance : Not tested Minimum : Lap Joint : Detonation: 19.300 ft./sec. Sensitivity: Not tested Velocity. : 6,000 m./sec. Jacket : Material : Lead PACKAGING 'INFORMATION' Weight : Order specific Explosive : 0.57 lbs. (0.25 kg.) Weight : per 100 ft. (30.4 m.) Feet : 1 - 100 foot spool Box : 9 1/2" x 9 1/2" Per Box: (30.4 meters) Dimensions: x 6 1/2" SHIPPING IFFORMATION U.S.D.O.T. Class: Class A U.N. Class : 1.1D Explosive (type 8) U.N. Number: 0065 EX Number : EX-8504371 CA Number : CA-850512- IINDEX: 441.40 UNIT NO. 5313-1 September 5, 1988 Page 6 of 9 BAKER. COMM. NUMBER 06-75014-00 SPECIAL APPLICATION PRIMACORD® DETONATING coRD 80 RDX NYLON "Lq" DF£~CRIPTION: Black n_vlon sheath covering a kevlar low shrink bra. id. Explosive core is RDX. APPLICATION: _.This is the most widely used Primacord detonating ;ord for all types of perforating ?kns. Nvlon has excell mt resistance to well fluids. SPECIFICATIONS Explosive : RDX Outside : 0.210 inches Diameter : +/- 0.008 inches Nominal : Explosive : 80 grains/foot *Temperature: 340 F. (171 C. 1 hour Core Load : 17.01 grams/meter Resistance : 325 F.(163 C. 24 hours Minimum . Lap Joint : Tensile 150 pounds Sensitivity: Yes Strength Jacket : Minimum Material : Black nylon Detonation: 20,800 ft./sec. Velocity 6,370 m./sec. Jacket : Thickness : .010 inches mil .mum PACKAGING INFORMATION -,). Net 11.5 lbs. 5. kg. Weight : per 500 ft. 1 .~ m.) Feet : 1 - 500 foot spool Box : 10 1/4" x 10 1/4" Per Box: (152.4 meters) Dimensions: x 5 1/2" SHIPPING INFORMATION U.S.D.O.T. Class: Class C U.N. Class : 1.1D Explos ive U.N. Number: 0065 EX Number : EX-8210034 CA Number : CA-841018 *Temperature resistance Is .based upon the manufacturer's laborat ~ry tests in air, aC ambientpressure only. NO CLAIM, REPRESENTATION OR W LERANTY OF ANY KIND IS MADE, EXPRESS OR IMPLIED, AS TO THE TEMPEP, ATURE RES [STANCE OF THIS PRODUCT UNDER ACTUAL CONDITIONS. USERS must satisfy, chemse yes as to the product's sul£ablll£y for £he particular use co be made of ic September 5, 1988 Page 9 of 9 BAKER COMM. NUMBER 06-76269-00 JRC TECHNICAL BULLETIN 100 GR/FT ALUHINUH-SHEATHED PYX DETONATING CORD PART NUMBER: P74100 DESCRIPTION: Annealed aluminum sheath with a PYX explosive core. Initiating. ability superior to lead-or plastic-sheathed cords. A~PLICATION: Suited for high temperature, long term exposure associated with tubing conveyed perforating guns using PYX shaped charges. Will shoot other hi-temp explosive charges ordinarily hard to initiate. Replaces lead-or plastic-sheathed cord. SPECIFICATIONS Explosive : PYX Outside : .205 Diameter : ± .008 inches Nominal : Explosive : 100 grains/foot *Temperature : 600"F (315"C), I hour Core Load : 21.26 grams/meter Resistance : 450°F (232°C), 200 hours Nominal : Jacket : Aluminum Alloy Detonation : 21,500 ft./sec. Material : Annealed Velocity : 6,500 m./sec. Jacket : Thickness : .016 inches PACKAGING INFOR~iATION Weight : Gross 3.4 lbs, (1,5 kg.) Explosive : 1.43 lbs. (0.65 kg.) Net 2.3 lbs. (1.0 kg.) Weight : per 100 ft. (30.5 m.) Fee: : 3 pcs. 30 ft. (9.1 m.} long Box : I0 7/16" X I0 7/16" · ~r Box: 90 ft. (27.4 m.) total Dimensions : X 4 7/8" SHIPPING INFORMATION U.S.D.O.T. Class: Class A* Explosive U.N. Class : 1.ID · Wp to 109 lbs. gross wt. of this product can be shipped as Class C under HM 191. U.N. Number : UN 0290 ~X Number: EX 8501088 CA Number : CA 850302 ~Iemperature resistance is based upon the manufacturer's laboratory tests in air, at ambient pressure only. NO, CLAIM, REPRESENTATION OR WARRANTY OF ANY KIND IS MADE, EXPRESS OR I}~LIED, AS TO THE TEMPERATURE RESISTANCE OF THIS PRODUCT UNDER ACTUAL CO~'.7)!TIONS. USERS must satisfy themselves as to the product's suitability for the particular use to be made of it. SAND CONTROL ~ndex: 441.40 December 19, 1988 A Baker Hughes company Replaces: 5288 Page I of 2 INITIATOR (PRIMER) ~ 1987, by Baker Sand Control Division Baker-Hughes. Inc. THIS DOCUMENT IS CONFIDENTIAL AND IS THE PROPERTY OF BAKER SAND CONTROL DIVISION BAKER-HUGHES, INC. ("BAKER"). IT MAY NOT BE COPIED OR REPRODUCED IN WHOLE OR IN PART IN ANY WAY WITHOUT THE EXPRESS WRITTEN CONSENT OF BAKER. THIS DOCUMENT ALSO IS AN UNPUBLISHED WORK OF BAKER. BAKER OWNS ALL RIGHTS TO THIS WORK AND INTENDS TO MAINTAIN THIS WORK CONFIDENTIAL AND AS A TRADE SECRET. BAKER MAY ALSO SEEK TO PROTECT THIS WORK AS AN UNPUBLISHED COPYRIGHT. IN THE EVENT OF EITHER INADVERTENT OR DELIBERATE PUBLICATION, BAKER INTENDS TO ENFORCE ITS RIGHTS TO THIS WORK UNDER THE COPYRIGHT LAWS AS A PUBLISHED WORK. THOSE HAVING ACCESS TO THIS WORK MAY NOT COPY, USE OR DISCLOSE THE INFORMATION IN TH~S WORK UNLESS EXPRESSLY AUTHORIZED BY BAKER TO DO SO. ' WARNING: THIS EQUIPMENT SHOULD BE USED ONLY BY QUALIFIED PERSONNEL. USE CONTRARY TO MANUFACTURER'S SPECIFICATIONS MAY RESULT IN PROPERTY DAMAGE, INJURY OR FATALITY. The terms Initiator, Primer or Blasting Cap are synonymous terms when used in the text of this unit. The Initiator is used in Baker mechanical and hydraulic type firing heads to initiate the Perforating Guns. The following specification sheets identify two Initiators currently in use: TELEDYNE INITIATOR: PERFORMANCE DATA TMS No. 821437-1A or 821437-2 Baker No. 06-75020-00 Operating Temperature -65°F to +400°F Maximum Assembly Torque is 50 fi-lbs. (see Firing Head Auto Ignition Tested to 450°F Units) Sealing Characteristics Tested to I x 10-6 cc/sec of Pressure Rating - 25,000 psi Helium DO NOT USE FIRING PIN 06-76517-00 WITH THIS External Dimensions See Sketch INITIATOR Weight 85 grams PRIMER BOOSTER ASSEMBLY Input (all fire) Energy Recommended Ali-Fire TMc/S 821437-1A or 821437-2 (from tests conducted with a BAKER COMM. NO. 06-75020-00 3 lb. weight) is 18 fi-pounds. DESCRIPTION Output 850 mg of lead azide in 0.250" diameter pressed The primer/booster assembly is a percussion initiated charge device for detonation of secondary explosive charges Environment Exposure Rated for proper operation under adverse environmental conditions. The assembly after exposure to 400°F for is an all welded, hermetically sealed unit that will func- 100 hours. tion properly after exposure to moisture and temperatures Control Identification Units are electroetched with up to 400°F (204°C). The explosive load of approx. 850 TMc/S Part Number, Menu- milligrams of lead azide is contained within the type 304 facturing Lot Number, Date CRES body and burst diaphragm. Initiation is accom- of Manufacture and a safety plished by a firin~pin with a 0.050" radius tip that pro- warning "DANGER-EX- vides 18 fi-pounds of impact energy. PLOSIVE" Output is a detonation from the 0.250" diameter charge DOT Shipping Pemussion Fuze, Class "C" of lead azide. Units are supplied with an 'O'ring to pro- vide a face seal at the output end. Classification Explosive Recommended Uses Detonation of Secondary F .. ,,- WW-B115-C40 Explosives where high tem- peratures and moisture ~- environments exist, e.g., ' /f.~ ~.~34 deep wells/shafts. (:.,o¢) I t,,ezV Packaging Units are packaged per (i~°~~) (I.ooo ~J DOT regulations i Special Safety Feature The 0.008" thick CRES burst diaphragm is de- signed to fail at 4800 psi · , ~. external pressure thus (z:)eo)---- L-- ~.__Teledyne preventing the unit from · (8.s') = Initiator firing in the event of a water/pressure leak in the (All dimensions in inches) firing head. INDEX: 441.40 UNIT NO. 5313-4 High Explosive Name: L6ad Azide - Non Dex- tri~ated December 19, 1988 Page 2 of 2 · ~ Total Explosive Weight: .0(~22160 lb. / 1.0050 gm./ea.' (Teledyne cont'd.) Function: Cc,mponent part for Firing Hz.ad EXPLOSIVE PRODUCTS: Final Assembly By: Te edyne McCormick Selph Physical Description: Percussion Primer 1.000" P/~ - 821437-1A or 821437-2 ~25.4000 mm (Fuze - Cap Designation Code: U1~S-0044 / 'U.S. DOT - Type) R1L-EX-8201014 Dimension: 1.156"/29.3624 mm Dia. x .906"/23.0124 mm long IMPORTANT NOTE: All TMS ~21437-1 Primers should Gross Weight: .1780156 lb. / 80.7327 have been reworked to 821437-' A. Any 821437-1 Primer gm./ea, should be scrapped. UNIDYNAMICS INITIATOR (HIGH TEMP.): Material: 304 Stainless Steel U.D. No. 51-4316-1 Seal: Co~nplete hermetic, leak Baker No. 06-76514-00 rate of less than 1 x 10-6 std Maximum Assembly Torque is 50 fi-lbs, cch;ec at one atmosphere MUST BE USED WITH FIRING PIN 06-76517-00. THIS pre ;sure differential using PIN WILL NOT WORK WITH 06-75020-1 INITIATOR. helium as a trace gas. CAUTION: HANDLE INITIATORS WITH CARE. DO NOT Pressure Cap~.bilities: Will withstand hydrostatic HIT OR IMPACT WITH HEAVY OR SHARP OBJECTS OR pre;sure of 25,000 psi ap- DETONATION COULD OCCUR. pile to primer cap. These initiators are stainless steel and are completely O-Ring Gland: Opt )nal Location sealed from the environment; therefore, shelf life is estimated to be five (5) years. This percussion actuated Detonal )r was designed for use Always use new Firing Pins with these Initiators since in oil drilling operations. Its functic is to initiate primacord the pin profile is critical to reliable performance, which in turn detonates shaped cl arges used to perforat.e the well casing. This Detonator w II withstand a tempera- HI-TEMP PERCUSSION DETONATOR - 51-4316-1 ture in excess of 430 degrees F;[hrenheit at a pressure BAKER COMM. NO. 06-76514-00 of 25,000 psi for 200 hours. This device can be tailored to meet specific envelope requir ;ments. Technical Specifications: Initiation Energy: 5 fi-lbs minimum @ 8 ft/sec Temperature: Withstand 425°F for 96 hrs. 430°F for 200 hrs. (tested @ 437°F for 200 hrs) Output: 690 mg of PYX Physical Characteristics ~ Length: 0.850 inch Diameter: Barrel 1.000 inch Rim 1.100 inch Unidynamics Ir ~itiator ,Use O-Ring WW-B113-£ 40