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Home My WebLink AboutUST 9/21/1991 MILIZARK" ~ ~ DRILLING FLUH~S MATERIAL SAFETY DATA SHEET A Baker Hughes company Mi[park DriLling FLuids Supplier: MILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency Tetepbone: 713/439-8000 Emergency Tetephone: 713/439-8000 [. - MANUFACTURER'S INFORMATION: Product Name: ALUM]NUM STEARATE CAS Ntat~er: 000637-12-7 Code: 1217010 Chemical Name: OEFOAMER FOR WATER BASED MUDS Chemical Description: ALUMINUM SOAP OF C~14MERCIAL STEAR[C ACID. DEFOAMER FOR WATER BASED MUDS. DOT Hazard CLass: gAP Shipping Id. No. - UN: NA: DOT Proper Shipping Name: II. -INGREO[ENTS: ............ ~::~:~:.~?:~.!?~.~.~!~.!~!?:!~??!: ............. ~!~: .... 1 .... ~: .... 1 .... ~: .... I--~LI-~L~: ......... .A. .AP .AP I.AP I.AP I.AP NAP NAP HAP INAP INAP INAP NAP NAP NAP INAP NAP INAP NAP NAP NAP INAP NAP INAP ............................................................... ......... ......... ......... ................. ............ ~:~-~?~-!~-~?-~-~?~!~ ..................... ~!~ .... 1 .... ~ .... I-~:~L~:I--~LI-~LL-~--: .......... NAP NAP NAP INAP INAP INAP NAP NAP NAP INAP INAP INAP NAP NAP NAP INAP INAP INAP NAP NAP NAP INAP INAP INAP HAP NAP INAP ]NAP [NAP INAP III. - PHYSICAL DATA: 8oiLing Point(F): NAP Vapor Pressure(mmHg): NAP Specific Gravity: 1.01 PHc NAP HeLting Point(F): 243 Vapor Density(Air=l): NAP Percent VoLatiLe By VoLtane(~): 1.0 Freezing Point(F): NAP SoLubiLity In Water: NAP Evaporation Rate: ( = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: FINE WHITE SLIGHTLY FATTY Gl)OR HateriaL Is: MIX-SOLID Coefficient of ~ater/Oit Distribution: INSOLUBLE ~N WATER iV. - FIRE & EXPLOSIOH HAZARD DATA: FLashpoint(F): 350 OPEN CUP Auto Ignition Temperature(F): NAP FLammabLe Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To i~pact: NAP Extinguish Media - Water: C02: X HaLon: Ory ChemicaL: X Foam: X Fog: Hazardous Combustion Products: NORMAL DEODMPOS[TioR PRODUCTS, i.e. C02, H20 AND AL203, CARBONACEOUS MATTER Fire Fighting Procedures: ,,. NO SPECIAL PRECAUTIONS OR PROCEDURES UnusaL Fire and ExpLosion Hazards: POSSIBILITY OF EXPLOSION EXISTS UNDER DUSTY CONDITIONS, AVOID DUSTY CONDITIONS AND ALL POSSIBLE SOURCES OF IGNITION IN DUSTY CONDITIONS. V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under Which Conditions? AVOID SOURCES OF [GN~T[ON [N OUSTY CONDITIONS. Incompatib[fty (MateriaLs to Avoid): DO NOT MIX W~TH STRONG OXIO[ZING AGENTS. Hazardous Decomposition or Byproducts: NORMAL DECOMPOSITION PRODUCTS C02, H20, AL203, CARBONACEOUS MATTER. Hazardous PoLymerization - May Occur: WiLL Not Occur: X Conditions to Avoid: NAP Mitpark Oritting FLuids SupPtier: MILPIRK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY OATA SHEETS Add~ess: 3900 Essex Lane Houston, Texas T702~ Houslon, Texas 77027 Emergency Tetephone: 713/G39-8000 Emergency TeLe hone: 713/439-8000 VI. - HEALTH HAZARD DATA: ALUMINUM STEARATE Carcinogen - NTP Program: NAP Carcinogen - IARC Program: NAP Symptoms of Exposure: ALUMINUM STERATE IS AN INNOCUOUS PROOUCT- FOA SANCTIONEO FOR INDIRECT FOOD PROCESSING. ACCIOENTIAL NGESTION OF LARGE AMOUNTS MAY PRODUCE GASTRO-INTEST]NAL DISTURBANCES AND REOUIRE MEDICAL TREATMENT. Medical Conditions Aggravated By Exposure: Emerge~y and First Aid Procedures: Eyes: FLUSH WITH CLEAN RUN#INGWATER FOR AT LEAST 15 NINUTES AND CONTACT A PHYSIC)A# ]F IRRZTATIONDVELOPS/PERSIST$. Skin: FLUSH SKIN WITH WATER. S~aL[ow: INGESTION OF LARGE AMOUNTS WILL PRODUCE GASTRO-INTESTINAL OISTURBANCES ANO RE(;IU~RE MEOICAL ATT NT~ON. Breath: REMOVE TO FRESH AIR AND CONTACT PHYSICIAN IF RESPIRATORY IRRITATION OEVELOPES. Vll. - ENVIRONMENTAL PROTECTION PROCEDURES: SpiLL Response: NORMAL CLEAN-UP PROCEOURES FOR ORY PROOUCTS- SUEEP~ VACtJUM, ETC. Waste OisposaL Method: OISPOSE IN ACCOROANCE WITH LOCAL~ STATE ANO FEDERAL REGULATIONS. HandLing and Storage: KEEP AWAY FROM HEAT ANO OPEN FLAMES. VII~. - SPECIAL PROTECTION INFORMATION: Respiratory Protection: PARTICULATE OUST RESPIRATO~ IN OUSTY CONOITIONS. VentiLation: LOCAL EXHAUST CLothing: PER dOB RE~UIRENENTS GLoves: SUITABLE FOR THE TASK Eye: GOGGLES FOR VERY DUSTY ATMOSPHERES. EYE WASH STATION AVAILABLE. Footwear: NORMAL Other: NORMAL WORK CLOTHING Known Hazards Under 29 CFR 1910.1200 .......................... :-"-1 ......................... Fta~nabte Material Eye Hazard Reactivity: 0 StabiL:ity: 0 Pyrophoric Material Toxic Agent ExpLosive MateriaL HighLy Toxic Agent ....................... UnstabLe Materia( Sensitizer Water Reactive Naterai Carcinogen Oxidizer Reproductive Toxin Organic Peroxide BLood Toxin Compressed GasCorrosive Materia~ I Nervous Systam T°xin ILung Toxin Irritant I Liver Toxin Nuisance Dust Kidney Toxin ........................ 1'--~ ......................... b--~ ......................................................................... Physical & HeaLth Hazard - SARA 40 CFR Part 370 (Check aLL that apply) (NOTE (*) indicates TLV for nuisance dust only) Fire: SL_~_en ReLease Of Pressure: Reactivity: I~tate(Acute): ,I OeLa, ed(Chronic): IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contaminated Equipment: NAV Other Precautions: POSSIBILITY OF EXPLOSION EXISTS UNDER OUSTY CONDITIONS, AVOIO OUSTY CONDITIONS ANO ALL POSSIBLE SOURI ES OF IGNITION. X. - APPROVAL: Prepared By: Safety Oeportment Code: 1217010 Oate Prepared: 05/01/91 S~ mrcedes Issue Oate: 04/26/90 MATERIAL SAFETY DATA SHEET PAGE: Q1 of 07 A Division of Hercules Incorporated Cellulose Polymer 1313 North Market Street P. O. Box 8740 Wilmington, Delaware 19899-8740 MSDS No.: 300 3583 0100-03 Phone #: (302) 594-5000 (24 hrs) Supersedes MSDS No: 300 3583 0100-02 Date: 09/21/91 I. PRODUCT IDENTIFICATION WARNING! STATIC CHARGES GENERATED BY EMPTYING PACKAGE IN OR NEAR FLAMMABLE VAPORS MAY CAUSE FLASH FIRE. MAY FORM FLAMMABLE DUST-AIR MIXTURES. DUST CAUSES MILD EYE IRRITATION. MAY CAUSE RESPIRATORY IRRITATION IF INHALED. SURFACES SUBJECT TO SPILLS OR DUSTING WITH THIS PRODUCT CAN'BECOME SLIPPERY WHEN WET. AQUALON* AQUAPAC HMIS RATINGS:(1) Cellulose polymer Health hazard: 1 Slight Flammability hazard: 1 Slight CASRN: 9004-32-4 Reactivity hazard: 0 Minimal CHEMICAL & COMMON NAMES: Cellulose polymer APPEARANCE AND ODOR: White to off white granular powder; odorless * Trademark of Aqualon (1)Explanation of acronyms: HMIS: Hazardous Materials Identification System rating for product as supplied. CASRN: Chemical Abstracts Service Registry Number AIHA WEEL: American Industrial Hygienists Association - Workplace Environmental Exposure Level. OSHA: Occupational Safety and Health Administration. TLV: Registered trademark of American Conference of Governmental Industrial Hygienists for Threshold Limit Values. TWA: Time Weighted Average STEL: Short term exposure limit (See 29 CFR 1910.1048, March 1, 1989, revision) C: Ceiling exposure concentration (See 29 CFR 1910.1000, March 1,_ 1989, rev.) SKIN: May be absorbed through skin (See 29 CFR 1910.1048, March 1, 1989, rev.) N/A: Not applicable MSDS No.: 300 3583 0100-03 Date: 09/21/91 PAGE: 02 of 07 II. HAZARDOUS INGREDIENTS & EXPOSURE LIMITS This material is not expected to cause physiologic impairment at low concentration. Until a specific TLV(1) is adopted by the ACGIH (American Conference of Governmental Industrial Hygienists), or an OSHA (Occupational Safety & Health Administration) standard is issued, Aqualon Company suggests that this material be treated as a NUISANCE DUST OR PARTICULATE in accordance with the recommendations of ACGIH. III. TYPICAL PHYSICAL & CHEMICAL CHARACTERISTICS CAUTION! SURFACES SUBJECT TO SPILLS OR DUSTING WITH THIS PRODUCT CAN BECOME SLIPPERY WHEN WET. BOILING POINT: N/A SOLUBILITY IN WATER: Limited by viscosity VAPOR PRESSURE @ 20 C: N/A SPECIFIC GRAVITY: 1.59 VAPOR DENSITY: N/A pH: N/A VOLATILE (WT.) %: Negligible @ 20 C EVAPORATION RATE: N/A FREEZING POINT: N/A MOISTURE CONTENT, %: 8 max. (as packed) IV. FIRE, EXPLOSION, & REACTIVITY HAZARD DATA WARNING! STATIC CHARGES GENERATED BY EMPTYING PACKAGE IN OR NEAR FLAMMABLE VAPORS MAY CAUSE FLASH FIRE. MAY FORM FLAMMABLE DUST-AIR MIXTURES. BROWNING TEMPERATURE: 227 C (440 F) FLAMMABLE LIMITS: Not determined AUTOIGNITION TEMPERATURE: Above 370 C (698 F) Dust EXTINGUISHING MEDIA: Water spray, dry chemical, foam, carbon dioxide, or halon SPECIAL FIREFIGHTING PROCEDURES: Not known UNUSUAL FIRE & EXPLOSION HAZARDS: May form flammable dust-air mixtures. STABILITY CONSIDERATIONS: Stable INCOMPATIBILITY WITH: Sunlight or ultraviolet light Continued... MSDS NO.: 300 3583 0100-03 Date: 09/21/91 PAGE: ,.0.3'_0f 07 .... IV. FIRE, EXPLOSION, & REACTIVITY HAZARD DATA ...Continued HAZARDOUS DECOMPOSITION PRODUCTS: None HAZARDOUS PRODUCTS OF COMBUSTION: Carbon monoxide, carbon dioxide, and smoke HAZARDOUS POLYMERIZATION: Will not occur. V. HEALTH HAZARD DATA WARNING! DUST CAUSES MILD EYE IRRITATION. MAY CAUSE RESPIRATORY IRRITATION IF INHALED. SIGNS & SYMPTOMS OF OVEREXPOSURE IN THE WORKPLACE: EYES: Contact with dust causes mild eye irritation. SKIN: None INHALATION: Inhaling dust may cause respiratory irritation. INGESTION: None EMERGENCY & FIRST AID PROCEDURES: EYES: In case of contact, immediately flush with plenty of low-pressure water for at least 15 minutes. Remove any contact lenses to assure thorough flushing. Call a physician. INHALATION: Remove to fresh air. Treat any irritation symptomatically. Call a physician. MEDICAL CONDITIONS GENERALLY RECOGNIZED AS BEING AGGRAVATED BY EXPOSURE None known. PRIMARY ROUTE OF ENTRY: Following standard industrial hygiene and recommended procedures, entry of the compound into the body is not expected. CANCER INFORMATION: Not listed as a carcinogen by NTP (National Toxicology Program); not regulated as a carcinogen by OSHA (Occupational Safety & Health Administration);. not evaluated by IARC (International Agency for Research on Cancer). REPORTED HUMAN EFFECTS: A single case of allergic contact dermatitis reported after repeated long-term (8 years) skin contact with purified sodium CMC. REPORTED ANIMAL EFFECTS: Eye irritation after exposure to dust of purified sodium CMC. MSDS No.: 3000 3583 0100-03 Date: 09/21/91 PAGE: 04 of 07 VI. SPILL PROCEDURES &WASTE DISPOSAL SPILL PROCEDURES: Sweep up spilled material for use or disposal. Surfaces subject to spills or dusting with this product can become slippery when wet. WASTE DISPOSAL METHOD: Incineration of waste material in a Permitted facility in accordance with local, state, and federal regulations is the recommended disposal method. Landfilling in a licensed facility equipped with leachate collection is a suitable alternative. This product is biodegradable. Wastewater containing this product can be considered for treatment in an acclimated biological treatment system of adequate capacity. Refer to Section VIII for specific Federal Environmental and Regulatory Data regarding use or disposal of this product. VII. APPLICABLE CONTROL MEASURES APPROPRIATE HYGIENIC PRACTICES: Avoid contact with eyes, skin, and clothing. Avoid breathing dust. Wash thoroughly after handling. PERSONAL PROTECTIVE EQUIPMENT: Safety glasses Impervious gloves Appropriate respiratory protection is required when exposure to an airborne contaminant is likely to exceed acceptable limits. Respirators should be selected and used in accordance with OSHA, Subpart I (29 CFR 1910.134) and manufacturer's recommendations. WORK PRACTICES: Eyewash fountains and safety showers should be easily accessible. Surfaces subject to spills or dusting with this product can become slippery when wet. Keep floors clean and dry. HANDLING AND STORAGE PRECAUTIONS: WARNING! STATIC CHARGES GENERATED BY EMPTYING PACKAGE IN OR NEAR FLAMMABLE VAPORS MAY CAUSE FLASH FIRE. MAY FORM FLAMMABLE DUST-AIR MIXTURES. Avoid ignition sources such as sparks and flame. Ground all equipment. In addition, when emptying bags where flammable vapors may be present, blanket vessel with inert gas, ground operator, and pour material slowly into conductive, grounded chute. TO protect product quality, store in sealed containers in a dry place away from heat and sunlight. Continued... MSDS NO.: 300 3583 0100-03 Date: 09/21/91 ~_~E: .:05 of 07 VII. APPLICABLE CONTROL MEASURES ...Continued ENGINEERING CONTROLS: Adequate ventilation should be provided to keep dust concentrations below acceptable exposure limits. Discharge from the ventilation system should comply with applicable air pollution control regulations. PROTECTIVE MEASURES DURING REPAIR AND MAINTENANCE: Eliminate ignition sources. Keep area clean. Product will burn. MSDS No.: 300 3583 0100-03 Date: 09/21/91 PAGE: 06 of 07 VIII. ENVIRONMENTAL & REGULATORY DATA The following environmental and regulatory data are provided to assist users of this product in defining their regulatory environmental compliance obligations. A. PRODUCT COMPOSITION PRODUCT (P) or TRADE NAME or COMPONENT NO. CHEMICAL COMPONENT CAS NUMBER WT. PERCENT P AQUALON* AQUAPAC 9004-32-4 100 Cellulose polymer B. SARA TITLE III (See footnotes) , SEC. 304 SEC. 302 COMPONENT EHS EHS SEC. 311/312 SEC. 313 TOXIC NO. RQ (lbs) TPQ (lbs) HAZARD CATEGORY CHEMICAL (YES, NO) P N/A N/A HC-1, HC-3 N/A C. CERCLA (40 CFR 302.4 HAZARDOUS SUBSTANCE & REPORTABLE QUANTITIES) This product does NOT contain any hazardous substances listed in 40 CFR 302.4. D. RCRA INFORMATION This product is not listed in federal hazardous waste regulation 40 CFR 261.33, paragraph (e) or (f) - i.e., chemical products that are considered hazardous if they become wastes. It does not exhibit any of the hazardous characteristics listed in 40 CFR 261, Subpart C. State or local hazardous waste regulations may apply if they are different from the federal regulation. E. OTHER None Continued... MSDS No.: 300~3583 0100-03 Date: 09/21/91 PAGE: 07 of 07 VIII. ENVIRONMENTAL REGULATORY DATA ...Continued FOOTNOTES: SEC. 302 - Threshold Planning Quantity, Extremely Hazardous Substance (EHS) (40 CFR 355 Emergency Planning and Notification regulations) N/A: Thi's chemical is not an EHS. Therefore, there is no Threshold Planning Quantity (TPQ). SEC. 304 - Reportable Quantity for Releases of an EHS (40 CFR 355, Appendix A) N/A: This chemical is not an E~S. Therefore, there is no Reportable Quantity (RQ). ~3~~40 CFR 370 Hazardous Chemical Reporting Requirements "Hazard Categor~T~ HC-1 Immediate (acut'~th hazard ) HC-2 Delayed (chroni healt'~~d HC-3 Fire hazard~'~ HC-4 Sudden release of pressure hazard HC-5 Reactive hazard NPIH Not a health hazard NPH Not a physical hazard SEC. 313 - 40 CFR 372 Toxic Chemical Release Reporting Requirements NO: This component is NOT subject to the reporting requirements of Section 313 of ~itle III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 Toxic Chemical Reporting requirements. YES: This component is subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372 Toxic Chemical Reporting requirements. Percent composition (or estimated range) is listed above. N/A: This product is a mixture. AS such, it is not listed as a Toxic Chemical under 40 CFR 372, Sect. 313 reporting requirements. Reportable constituents are listed individually where they exceed threshold concentration limits. AQUALON COMPANY HAS COMPILED THE INFORMATION AND RECOMMENDATIONS CONTAINED IN THIS MATERIAL SAFETY DATA SHEET FROM SOURCES BELIEVED TO BE RELIABLE AND TO REPRESENT THE MOST REASONABLE CURRENT OPINION ON THE SUBJECT W-HEN THE MSDS WAS PREPARED. NO WARRANTY, GUARANTY OR REPRESENTATION IS MADE AS TO THE CORRECTNESS OR SUFFICIENCY OF TH~'INFORMATION. THE USER OF THIS PRODUCT MUST DECIDE WHAT SAFETY MEASURES ARE NECESSARY TO SAFELY USE THIS PRODUCT, EITHER ALONE OR IN COMBINATION WITH OTHER PRODUCTS, AND DETERMINE ITS ENVIRONMENTAL REGULATORY COMPLIANCE OBLIGATIONS UNDER ANY APPLICABLE FEDERAL ORi STATE LAWS. Doc. no. 7696s MATERIAL SAFETY DATA SHEET 7000 Holli~er Rd., SuRe 300 Emergency Telephone: (713) 439-8900 _Ij~rj~ Houston, Texas 77040 BIO-LOSE CHElVlTREC: 1-800-424-9300 "HANUFACTURER'S INFORHATION: Manufacturer: BAKER HUGHES INTEQ HMIS Hazard Rating HeaLth 0 #inime[ - 0 Product Name: BIO-LOSE and Key: FLammabiLity Z SLight - 1 ChemicaL Name: FILTRATION CONTROL AGENT Reactivity 0 Moderate - Chemical Description: MOOIFIED POLYSACCHARiDE Persona[ Serious - Protection E SeYere - Proper Shipping Description: DRILLING FLUID COHPOUND, N.O.S. Hazard CLass: NOT REGULATED UN Nc~ber: NA Hazard LabeL: NA DOT Re~-~eGuJde: NA Transportation Note: NA il. - HAZARD IDENTIFICATION: Hazardous. Components! ............................. ....... / I'°° ........ Hazards Associated with Product Use Yes Yes iYes Ye CombustibLe Liquid FLan~nab[e Material PyropborJc MateriaL ExpLosive Material UnstabLe Material ~ater Reactive Material Oxidizer Organic Peroxide Corrosive Material Compressed Gas Irritant #uisance ParticuLate X Skin Hazard Eye Hazard Toxic Agent HighLy Toxic Agent Sensitizer Carcinogen Reproductive Toxin BIDed Toxin Nervous System Toxin Lung Toxin Liver Toxin Kidney Toxin · Commodity Right-to-Know (SARA TitLe Ill Section311-312) ...-J:e: Sudden ReLease Of Pressure: Reactivity: lmaediate (Acute): X DeLayed (131renic): Iii. - PHYSICAL DATA: BoiLing Point(F): NA Vapor Pressure(rm~lg): NA PH: 10-11 MeLting Point(F): NA Vapor Density(Air=l): NA Specific Sravity: ltd Freezing Point(F): NA SoLubiLity in ~ater: APPRECIABLE Percent VoLatile By VoL[me(I): RA Odor ThreshoLd: ND Appearance And Odor: OFF-WHITE, MILD ETHER O00R Evaporation Rate ( - 1): BA Material Is: PURE-SOLID Coefficient of ~ater/OiL Distribution: ND IV. - FIRE & EXPLOSION HAZARD DATA: F[ashpoint(F): HA Auto Ignition Temperature(F): F[an~abLe Limits - LFL: NA UFL: NA ExpLosion - LEL: NA UEL: BA Extinguish Media - Uater: X C02: X Dry ChemicaL: X Foam: X Fog: X Hazardous Combustion Products: UPON COHBUSTION, OXIDES OF CARBON MAY FORM PROOUCING TOXIC, FUMES. Fire Fighting Procedures: IN CASE OF FIRE, GENTLY FLOOD UITH UATER FOG, USING CARE NOT TO SUSPEND DUSTS. SELF-CONTAINED BREATHING APPARATUS NAY BE EEl=nED IH ENCLOSED AREAS DURING A FIRE. Unusual Fire and ExpLosion Hazards: AT VERY HIGH DUST CONCENTRATIONS, PROOUCT MAY FORM EXPLOSIVE OUST-AiR MIXTURES. V. - REACTIVITY DATA: ChemicaLLy StabLe: Yes: X No: If no, Under ~hich Conditions7 VERY DUSTY CONOITIONS. lncc~tibttty (Materials to Avoid): STRONG OXlOIZERS. " %qrdous Decomposition or Byproducts: PROOUCT ~iLL NOT REAOILY DECOMPOSE. ~azardous PoLymerization - May Occur: ~iL[ Not Occur: X Conditions to Avoid: NA ND - Not Determined NA - Not AppLicabLe T - Tote[ Dust R - RespJrabLe Fraction C -CeiLin~Lilit BIO-LOSE IS A TRADEMARK OF BAKER HUGHES INTEQ. Page 1 BIO-LOSE .. VI. ' HEALTH HAZARD INFORMATION: Primary Exposure Route - Skin Contact: Skin Absorption: Eye Contact: X lnha[atim: X Ingestion: Product Carcinogenicity - NTP: NO IARC: NO Acute Ef{ects of Overexposure: PRODUCT OUST MAY CAUSE MECHANICAL IRRITATION TO EYES~ SKIN ANO UPPER RESPIRATORY TRACT. Chronic Effects of Overexposure: SOI4E PARTICULATE DUSTS MAY CAUSE ALLERG[C SENS]T]ZAT]ON OF SC)ME INDIV[DUALSw CHARACTERIZED EITHER BY SREATHING DISTRESS O1[ TOPICAL SKIN IRRITATION SYMPTOMS. Vil. - EMERGENCY AND FIRST AID INSTRUCTIONS: Eyes: HOLD EYELIDS APART AND FLUSH EYES YITH YATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAI~ IF IRRITATIO# PERSISTS. Skin: YASH THOROUGHLY YITH MILD SOAP AND YATER. APPLY MEDICATED CREAMS TO RELIEVE IRRITATION AND REPLEN]S# SKIN OILS. ]ngestion: GIVE FLU]OS TO RINSE MOUTH AND~THROAT IRRITATION AND TO DILUTE. CONSULT A PHYSICIAN IF ADVERSE SYMPTOMS DEVELDP. InhaLation: MOVE TO FRESH AIR. GIVE ARTIFICIAL AESP]RATION [F NOT BREATHING. GIVE OXYGEN IF BREATHING IS DIFFICULT. VIII. - ENVIRONMENTAL PROTECTION PROCEOURES: SpiLl Response: YEAR PROPER PROTECTIVE EQUIPMENT (SECTION IX). RECOVER SPILLED MATERIAL TO THE ORIGINAL CONTAINER FOR SALE IF POSSIBLE OR TO A SU]TABLE YASTE CONTAINER. MINIMIZE DUSTING DURING CLEANUP. FLUSH RESIDUE YITH YATER. Yaste Disposal Method: PRODUCT IS NOT HAZARDOUS ACCOROING TO RCRA CRITERIA OR LISTING AS SUPPLIED. DISPOSE OF ACCOROING TO LOCAL~ STATE ~ #ATIONAL REGULATIONS DEALING YITH A YASTE PRODUCT. Handling: CAUTION! MAY CAUSE MECHANICAL EYE, SKIN AND RESPIRATORY IRRITATION. AVOID CONTACT ANO YEAR PROPER PROTECTIVE EGUIPflE#T. AVOID BREATHING DUST. Storage: KEEP DUSTS TO A MINII~. KEEP CONTAINER CLOSED YHEN NOT 1N USE. USE UITN ADEQUATE VENTILATION. IX. - OCCUPATIONAL CONTROL MEASURES: Respiratory Protection: YEAR AN APPROVED PARTICULATE RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR FOR 13:~IFORT. Ventilation: - VENTILATION AS NEEDED TO MAINTAIN SAFE EXPOSURES TO NUISANCE PARTICULATES (15 NG/N], TOTAL DUST). Clothing: LONG-SLEEVE CLOTHING OR APRON. Eyeuear: WEAR CHEMICAL SAFETY GOGGLES OR GLASSES WITH SIDEGUARDS. INSURE A PROPER FIT. Gloves: YEAR GLOVES TO PREVENT MECHANICAL IRRITATION. Footuear: NORMAL PRECAUTIO#S. Other Measures: OROINARY MEASURES OF PERSONAL HYGIENE SHOULD SAFEGUARD YORKER HEALTH. USE APPROPRIATE CLEANSERS TO YASH OFF PRODUCT AND INCORPORATE SKIN CONDITIONERS I#TO NYGIE#E. X. - ADDITIONAL INFORMATION: DISCLAIMER The statements, information, and data provided in this material safety data sheet are believed re[iabte and accurate by Baker Hughes INTEQ and its responsib[e perso~ne(; houever, no other guarantee, representation, uarranty or responsibi[ity is expresaed or imp[ted to any user, regard[ess of retiance on ail or any part thereof. This includes warranties of merchantability or of fltne~ for a part]cuter purpose, and Baker Hughes ]NTEQ assumes no responsibi[ity whatever for advice or recmeendati~ aede. #othing c~teined herein shoutd be interpreted as permission, inducement, or condonement to viotate any tau persuant to thia product~e or disposal. Prepared By: Jim Rushing Date Prepared: 01/17/9& Supercedea ]Hue Date: / / ND - Not Determined NA - Not Appticab[e · - Greater Than < - Less Than C - Ceitin~ Page __~__~r MILPAI~iK" MATERIAL SAFETY DATA SHEET ==: DMILLING FLUIDS A Baker Hughes company MiLpark DriLLing FLuids SuppLier: MILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 [. - MANUFACTURER'S INFORMATION: Product Name: . BLACK HAGIC SFT CAS Number: MULTIPLE Code: 1219~05 Chemical Name= SPOTTING FLUID Chemical Description: BLENDED LUBRICANT SPOTTING FLUID ASPHALT COMPOSITION BLEND. DOT Hazard CLass: NAP Shipping Id. No. - UN: DOT Proper Shipping Name: II. - INGREDIENTS: ............ ~rf~-~--~--~?~-!~f~-~-~!~-!~!?:!f?~!: ........ 1 .... ~: ......... ~: ......... ~: .... 1--~:-1-~LL-~--: .......... FLUX-CALCINED DIATONACEOUS EARTH NAP 1.1MG/M~ NAP 1<4 168855-54-9 ASPHALT FUMES NAP :SMG/N3 MAP 1>60 [8052-42-4 NAP NAP iNAP NAP NAP NAP NAP NAP INAP NAP NAP NAP .............................................................. .......... ...... ......... .................. ............ ~:f?~-~?~-!~-~?-~-~?~ ................ 1 .... ~I~ ........ ~ .... l_~:.°f.~.~l..~.l.~f~.~..':'~..: .......... SOOIUM DODECYL BENZENE SULFATE NAP !NAP 13,900 17.2 25155-50-0 NAP NAP NAP NAP I NAP NAP NAP INAP NAP INAP NAP NAP NAP INAP NAP INAP NAP NAP NAP )NAP NAP INAP INAP III. - PHYSICAL DATA: BoiLing Point(F): NAP Vapor Pressure(n~nHg): NAP Specific Gravity: 1.0~ PH: >10 H20 SUSP MeLting Point(F): NAP Vapor Oensity(Air=l): NAP Percent VoLatiLe By VoLume(~): NAP Freezing Point(F): NAP SoLubiLity In ~ater: SLIGHTLY Evaporation Rate: ( = 1): NAP Odor ThreshoLd: MAP Appearance And Odor: GRAY-BLACK POM)ER / HYDROCARBON ODOR Material Is: MIX-SOLID Coefficient of 9ater/OiL Distribution: NAP IV. - FIRE & EXPLOSION HAZARD DATA: Ftashpoint(F): >500 CLOSED CUP Auto Ignition Temperature(F): NAV FLammabLe Limits - LFL: NAP UFL: NAV ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAV Sensitivity To Impact: NAP Extinguish Media - ~ater: X C02: X Ha[on: Dry ChemicaL: X Foam: X Fog: Hazardous Combustion Products: CARBON MONOXIDE, CARBON DIOXIDE - ASPHALT PROOUCES HOT DENSE SMOKE IN THE PRESENCE OF FIRE. Fire Fighting Procedures: ~EAR SELF-CO~TAINED POSITIVE PRESSURE BREATHING APPARATUS AND FULL FlEE FIGHTING PROTECTIVE CLOTHING FOR'ENCLOSED AREAS. UnusaL Fire and ExpLosion Hazards: HIGH CONCENTRATIONS OF SUSPENDED DUST MAY RESULT IN EXPLOSION HAZARD. HOT ASPHALT MAY IGNITE FLAMMABLE MATERIALS. HIGH ASPHALT CONCENTRATIONS COULD PROOUCE HOT-SMOKY FIRE IF EXPOSED TO HOT FIRE. V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under ~hich Conditions? HIGH CONCENTRATIONS OF SUSPENDED DUST MAY RESULT IN EXPLOSION HAZARD. Incompatib[ity (MateriaLs to Avoid): ACIDS Hazardous Decomposition or Byproducts: HONE - OTHER OXIDES OF CARBON i.e. CO, C02 Haza;dous PoLymerization - May Occur: UiLL Not Occur: X Conditions to Avoid: NAP Mi[park DriLLing FLuids SuppLier: M[LPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 39C~ Essex Lane Houston, Texas 77027 Hocston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 VI. - HEALTH HAZARD DATA: SLACK HAGIC SFT Carcinogen - HTP Program: NAP Carcinogen - IARC Program: PROSASLE Symptoms of Exposure: PROLONGED OR REPEATED EXPOSURE HAY CAUSE IRRITATION TO EYES, SKIN OR ~JCOUS NEHBRANES. Hedica[ Conditions Aggravated 8y Exposure: HIGH DUST CONCENTRATIONS OF SILICA OVER AN EXTENDED NO. OF YEARS~AY PRODUCE P#EUIM)CONIOSI$ (INFLAHMA*ION OF THE LUHGS). CRYSTALLINE SILICA HAS BEEN CLASSIFIED AS PROBABLY CARCINOGENIC FOR HUHA#S BY THE I.A.R.C~ Emergency and First Aid Procedures: Eyes: FLUSH WITH CLEAN RUNNING WATER FOR AT LEAST FIFTEEN HINUTES AND CONTACT A PHYSICIAN. Skin: WASH WITH SOAP AgO WATER SwaLLow: DRINK SEVERAL GLASSES OF WATER AND CORSULT PHYSICIAN Breath: REMOVE FROH EXPOSURE TO FRESH AIR AND IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN.AND CONSUL* A PHYSICIAN. VII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spit[ Response: SVEEP INTO WASTE CONTAINER. Waste Disposal Method: DISPOSE IH ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. HandLing and Storage: STORE IN A COOL, DRY AREA. KEEP DUST TO A VIII. - SPECIAL PROTECTION INFORHATIOR: . Respiratory Protection: gEAR NIOSH/HSHA APPROVED RESPIRATOR FOR NUISANCE DUST IF TLV HAY SE EXCEEDED VentiLation: #ECHAMICAL CLothing: NORHAL gORE ATTIRE GLoves: GLOVES SUITABLE TO PREVENT SKIN CONTACT Eye: SAFETY GLASSES OR GOGGLES Foot,ear: NORHAL Other: AS NEEDED Known Hazards Under 29 CFR 1910.1200 I HMIS ] NFPA ....................................................... HeaLth: 1 HeaLth: 1 CombustibLe Liquid Skin Hazard I F[anmabJ[ity: 0 I F[anllmbiLitY: 0 ~ Ftanmmbte Mater~a[ Eye Hazard X I ReaCtivity: 0 I StabiLity: 0 ! ExpLosive Material H~gh[y Toxic Agent .................... UnstabLe gateriaL Sensitizer 1later Reactive Meters[ Carcinogen Oxi di zer Reproduct ive Toxi n Organic Peroxide BIDed Toxin I Corrosive Material Nervous System Toxin Compressed Gas Lung Toxin irritant Liver Toxin ; Nuisance Dust X Kidney Toxin ............................ t ......................... ~-"t ................................... ~ .................................... Physical & Health Hazard - SARA 40 CFR Part 370 (Check ail that apply) (NOTE (*) indicates TLV f ~r nuisance dust on[y) Fire: Sudden Re[ease Of Pressure: Reactivity: In~nediste(Acute): t DeLays iChronic): IX.*- SPECZAL PRECAUTIONS: Precautions For Repair & Maintenance Of ContamJrmtod EqUil:merit: NAV Other Precautions: AVOID HIGH DUST CONCENTRATION. H[NIHIZE CONTACT UITH EYES, SKIN, AND CLOTHING. KEEP AWAY FRoH HEAT, Si'ARKS AND OPEN FLAME. X. - APPROVAL: Prepared By: Safety Department Code: 1219905 Date Prepared: 05/~1/91 Supa~cedes Issue Date: 03/08/90 MILPARK' MATERIAL SAFETY DATA DRILLING FLUIDS A Baker Hughes company Milpark Drilling Fluids Supplier: MILPARK DRILLING FLUIDS :~900 Essex Lane, Suite 300 HATERIAL SAFETY DATA SHEETS Address: :~900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency Telephone: 713/439-8000 Emergency Telephone: 713/439-8000 I. - HANUFACTURER~S %NFORHATION: Product Name: CAUSTIC SOOA CAS Number: NAV Code: ~)00742 Chemical Name: SOOtUH HYDROXIOE Chemical Description: SOOIUH HYDROXIDE - DRY ALKALINITY CONTROL FOR WATER BASED MUDS DOT Hazard Class: CORROSIVE HATERIAL Shipping [d. No. - UN: 182~ NA: DOT Proper Shipping Name: CORROSIVE MATERIAL II. - INGREDIENTS: SOOIUM HYDROXIDE 182~ 2 NG/H5 2 MG/l~(8hr)llO0 11310-75-2 NAP NAP DUST NAP INAP /NAP ~AP NAP NAP HAP INAP INAP ............................................................... .......... .......... ......... .................. S~IUM HYDROXIDE NAP ~ MG/~ 1000 ~NAP 1310-~-~ NAP NAP NAP NAP INAP NAP NAP NAP NAP NAP NAP NAP NAP NAP NAP NAP NAP NAP NAP NAP INAP NAP INAP IgAP ]][. - PHYSICAL DATA: Boiling Point(F): 2~ Va~r Pressure(~gg): 1~ ~ ~9oC S~ific Gravity: 2,13 PH: STRONG BASIC Melting Point(F): 6~ Va~r Density(Air=l): NAP Perc~t Volatile By Vol~(~): NAP Freezi~ Point(F): NAP Solubility In gater: GREATLY Eva~rati~ Rate: ( = 1): NAP ~or Threshold: NAP A~arance A~ ~or: gglTE TO SLIGHTLY COL~ED SOL]D NO ~OR ~aterial is: PURE-SOLID Coefficient of ~ater/Oi[ Oistri~ti~: NAP IV. - FIRE & EXPLOSION HAZARD DATA: FLashpeint(F): NAP Auto Ignition Temperature(F): NAP FLammable Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Se.nsitivity To ]mpact: NAP Extinguish ~edia - ~ater: C02: HaLon: Dry Chemical: Foam: Fog: Hazardous Combustion Products: Fire Fighting Procedures: FIREFIGHTERS SHOULD ~EAR SELF-CONTAINED POSITIVE PRESSURE BREATHING APPARATUS, AND AVOID SKIN CONTACT. ,Unusa[ Fire and Explosion Hazards: CONTACT ~ITN SO~IE HETALS PARTICULARLY MAGNESIUM, ALUMINUH AND ZINC (GALVANIZED) CAN RAPIDLY GENERATE HYDROGEN, UHICH IS EXPLOSIVE. V. - REACTIVITY DATA: Chemical Stable: Yes: X No: If no, Under Uhich Conditior~;? UNDER PROPER CONDITIONS OF TEHP. PRESSURE, AND STATE OF SUBDIVISION IT CAN REACT WITH ACETIC AC]D, ACETALDEHYDE, ACETIC ANHYDRIDE , ACROLEIN, ACRGLONITRILE (SEE SAX 6th EDITION P. 2435) ]ncompatiblity (Haterials to Avoid): ORGANIC MATERIALS AND CONCENTRATED ACIDS MAY CAUSE VIOLENT REACTIONS. CAUSTIC SOOA REACTS WITH HAGNES]UM, ALUHINUH, ZINC (GALVANIZED), TIN, CHROH]LIH, BRASS AND BRONZE GENERATING HYDROGEN WHICH ]S EXPLOSIVE. Hazardous Decomposition or Byproducts: THERHAL DECONPOS]TION PROOUCTS ARE HAZARDOUS. HazaFdous Polymerization - Hay Occur: WiLL Not Occur: X Conditions to Avoid: NAP HiJpark Drilling FLuids Supplier: MILF IRK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 ' Hous:on, Texas 7702? Emergency Telephone: 713/439-8000 Emergency TeLe~one: 713/439-8000 VI. - HEALTH HAZARD DATA: CAUSTIC SODA Carcinogen - NTP Program: NAP Carcinogen - IARC Program: NAP Symptoms of Exposure: NAP Medical Conditions Aggravated By Exposure: Emergency and First Aid Procedures: Eyes: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF CLEAN WATER FOR AT LEAST 15 MINUTES AND CONTACT A PHYS[C%AN IMMEDIATELY. Skin: REHOVE CLOTHING THAT IS CONTAMINATED. FLUSH SKIN WITH HATER FOR AT LEAST 15 MINUTES. IF SKIN IS SLICK FEELING, CONTINUE TO FLUSH AS CAUSTIC MAY STILL BE PRESENT. Swallow: IF CONSCIOUS, DRINK LARGE QUANTITIES OF UATER OR ACIDIC BEVERAGES (TOMATO, ORANGE, OR CARBONATI[D JUICES). DO NOT INDUCE VOHITING. IF VOH[TING GIVE HORE WATER. IF UNCONSCIOUS OR IN CONVULSIONS, TAKE TO THE HOSPITAL. Breath: REHOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CONTACT A PHYSICIAN. VII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spill Response: flORMAL CLEAN-UP PROCEDURES FOR DRY PRODUCTS - SWEEP, VACUUH, ETC. IF MIXED gITH WATER, OR LIKELY TO BI! MIXED, DIKE AND CONTAIN. NEUTRALIZE LIQUIDS gITH DILUTE ACID. NEUTRALIZED LIglJID (PH 6 TO 9) MAY BE TREATED AS A NEUTR,~L SALT. ~aste Disposal Method: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling and Storage: AVOID CONTACT UITH ORGANIC MATERIALS. CONCENTRATED ACIDS MAY CAUSE VIOLENT REACTIONS. AVOID CONTACT ~iTH INCOMPATIBLE MATERIALS. REACTS WITH VARIOUS SUGARS TO GENERATE CARBON MONOXIDE. KEEP CONTAINER CLOSED ~HEN NOT IN'USE. VIII. - SPECIAL PROTECTION INFORMATION: Respirator~ Protection: USE NIOSH/MSHA DUST/HIST RESPIRATOR. FOR ROUTINE kJORK. Ventilation: LOCAL EXHAUST CLothing: LAUNDER BEFORE REUSE GLoves: NITRILE, NEOPRENE, NATURAL RUBBER. Eye: DO NOT ALLOU THIS MATERIAL TO GET IN EYES. ~EAR CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELII. Foot,ear: RUBBER BOOTS Other: APPROPRIATE GEAR TO PREVENT SKIN CONTACT. RUBBER BOOTS, APRI)N, HARD HAT Knoen Hazards Under 29 CFR 1910.1200 J HMIS NFPA J /Yes/ /Yes! .............................................. ........................ ~---J ......................... ~---J Health: 3 Health: 3 J Combustible Liquid Skin Hazard X J F[a~nabiLity: 0 F[anmabi[ity: 0 J FLammable Material Eye Hazard XJ Reactivity: 2 Stability: 0 I Pyrophoric Material Toxic Agent J ~.1~.~!~}] J Explosive Material Highly Toxic Agent .~.o~.~!.~.e~.~!.o~.~_~ ..... , ............... Unstable Material Sensitizer J ~ater Reactive MateraL Carcinogen I Oxidizer Reproductive Toxin J Organic Peroxide BLood Toxin I Corrosive Material X Nervous System Toxin J Compressed Gas Lung Toxin I Irritant ~ Liver Toxin J Nuisance Dust Kidney Toxin r ........................ t---t ............................ t ......................................................................... Physical & Health Hazard - SARA 40 CFR Part 370 (Check all that apply) (NOTE (*) indicates TLV for nuisance dust only) Fire: Sudden Release Of Pressure: Reactivity: Iflmediate(Acute): X ' Delayed(Chronic): IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contaminated Equipment: HAV Other Precautions: DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. CAN CAUSE SEVERE INJURY OR BLINDNESS. DO NOT IBREATNE MIsr. DO NOT S~ALLOU. ~ASH THOURGHLYAFTER HANDLING. DO NOT EAT, DRINK, OR SMOKE IN I~ORK AREAS.'cedeslssueoate: X. - APPROVAL: Prepared By: Safety Deportment Code: 9900742 Date Prepared: 06~1 /90 Supe OxvChem® MATERIAL SAFETY DATA SHEET MSDS NUMBER : M4820 MSDS DATE : 01-14-93 PRODUCT NAME,' CAUSTIC SODA-BEADS 24 HOUr EMERGENcy PHONE: 1-800-733-3665 OR 716-278-7~21 I. PRODUCT IDENTIFICATION HMIS HAZARD RATINGS HEALTH HAZARD 3 FIRE HAZARD 0 REACTIVITY 2 Based on the National Paint & Coatings Association HMIS rating system. SARA/TITLE III HAZARD CATEGORIES (See Section X) Immediate (ACUTE) Health: YES Reactive Hazard: YES Delayed (Chronic) Health: NO Sudden Re]ease of Pressure: NO Fire Hazard: NO MANUFACTURER'S: Occidental Chemical Corporation NAME AND : Customer Service, Occidental Tower, Telephone ADDRESS : P 0 Box 8~9~5~, Dallas, Texas 7538~ (1-8~-752-5151) CHEMICAL NAME: Sodium hydroxide CAS NUMBER: 131~-73-2 SYNONYMS/COMMON NAMES: Sodium Hydroxide-Dry CHEMICAL FORMULA: NaOH DOT PROPER SHIPPING NAME: Sodium Hydroxide, so]id DOT' HAZARD CLASS: Corrosive material DOT I.D'. NUMBER: UN1823 DOT HAZARDOUS SUBSTANCE: RQ 1~0 lbs. II. HEALTH HAZARD INFORMATION EMERGENCY AND FIRST AID PROCEDURES EYES: OBdECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION. IMMEDIATELY flush eyes with large amounts of water for at ]east 15 minutes, ho]ding lids apart to ensure flushing of the entire surface. Washing eyes within samara] seconds is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY. OCCIDENTAL CHEMICAL Page 2 of 9 MSDS NUMBER: M4820 01-14-93 PRODUCT NAME: CAUSTIC SODA-BEADS II. HEALTH HAZARD INFORMATION (Continued) SKIN:. IMMEDIATELY wash contaminated areas with plenty cf water for at least 15 minutes.' Remove contaminated clothing· anc footwear and wash clothing before reuse. Discard footwear which cannot b'e decontaminated. SEEK MEDICAL ATTENTION IMMEDIATELY. INHALATION: Remove to fresh air; if breathing is difficult, have tra'ined person administer oxygen. If respiration stops, give mouth-to-mouth resuscitation. GET MEDICAL ATTENTION. INGESTION:. NEVER GIVE ·ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. If available, give several glasses of milk If vomiting occurs spontaneously, keep airway clear. SEEK MED CAL ATTENTION IMMEDIATELY. ROUTES OF EXPOSURE INHALATION: Breathing of dust, mist, or spray may cause dame e to the upper respiratory tract and the lung tissue which Could produce chemical'pneumonia depending upon severity of exposure. SKIN: Contact produces severe burns and destroys tissues. Irritation may be delayed. EYE CONTACT: Causes severe burns that result in damage to the eyes and possibly blindness. INGESTION: Causes severe burns to mucous membranes Of the mouth, throat, esophagus, and stomach. EFFECTS OF OVEREXPOSURE ACUTE: Corrosive to all body tissues by all routes of exposure. The effect of local dermal exposure may consist Of mul iple areas of superficial destruction of the skin or of Primary rritant dermatitis. Similarly, inhalation of dust, spray, ar mist may result in varying degrees or irritation or damage ~ the respiratory tract tissues and an increased suscept ~ility to respiratory illness. CHRONIC: No known chronic effects. TOXICOLOGY DATA: Caustic soda is a corrosive material'. Acute Dermal ED50 (rabbit) 1350 mg/kg Human Dermal Exoosure Regardless of concentration, the severity of dam; De and extent of its lrreversibil ity increases with length of correct time. Prolonged contact with sodium hydroxide solutions cf ~1% can cause a high degree of tissue destruction. The latent period, following skin contact during which no sensation of irritation occurs, varies from several hours for 0.4 - 4% solutions.to 3 minutes with concentrations of 25% or greater OCCIDENTAL CHEMICAL Page 3 o¢ 9 MSDS NUMBER: M4820 01-14-93 PRODUCT NAME: CAUSTIC SODA-BEADS III. IMPORTANT COMPONENTS CAS NUMBER / NAME . 1310732 Sodium hydroxide (Na(O'H)) . EXPOSURE LIMITS 'PERCENTAGE PEL=2 mg/m3. Cei'ling VOL' ND TLV=2 mg/m3, Ceiling WT 97'98.20 COMMON NAMES: CAUSTIC SODA Listed On(List Legend Below): 13 18 21 7647145 Sodium chloride (NaCl) EXPOSURE LIMITS PERCENTAGE PEt=None established VOL ND TLV=None established WT 0:1.20 COMMON NAMES: SALT Listed On(List Legend Below): 497198 Carbonic acid disodium salt EXPOSURE LIMITS PERCENTAGE PEL=Not Established VOL ND TLV=Not Establ 1shed WT '0.40-1 COMMON NAMES: SODA ASH SODIUM CARBONATE Listed On(List Legend Below): 23 All components of this product that are required to be on the TSCA Inventory are listed on the inventory. Not listed as carcinogen - IARC, NTP, OSHA LIST LEGEND 13 PA ENVIROMENTAL HAZ SUBSTANCE 18 NY HAZARDOUS SUBSTANCES 21 Nd SPECIAL HEALTH HAZ SUB 23 NJ REQUIREMENT- 1% OR GREATER OCCIDENTAL CHEMICAL Page 4 of 9 MSDS NUMBER: M482e e1-14~93 PRODUCT NAME: CAUSTIC SODA-BEADS IV. FIRE AND EXPLOSION DATA FLASH POINT: NA . AuToIGNITION TEMPERATURE: qonflammable FLAMMABLE. LIMITS IN AIR, % BY VOLUME-'uppER: .NA LOWER: NA EXTINGUISHING MEDIA: This product is not combustible. Foam, carbon dt ~xide, or dry chemical may be used in areas where the product is stored. SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing. Avoid direct contact of this product with water as thls can cause violent exothe~-mic reaction. UNUSUAL FIRE'AND EXPLOSION HAZARD: Direct contact' with water can cause violent exoth,~rmic reaction. See Reacti.vity (Section VII). V. SPECIAL PROTECTION VENTILATION'REQUIREMENTS: Special ventilation is not required under normal ~se. Use local exhaust ventilation where dust, mist, or spra' may be generated. NOTE: Where carbon monoxide or other reaction pr, ducts may be generated, special ventilation may be required. SPECIFIC PERSONAL PROTECTIVE EQUIiPMENT RESPIRATORy: Respiratory protection is not required under norm;~l use. Use NIOSH/MSHA approved respirator where dust, mi'.st, or spray may be .generated. EYE: ' Wear chemical safety goggles plus full face shiel to protect against splashing. GLOVES: wear chemical resistant gloves such as natural an butyl rubber. Gloves may be decontaminated by washing wi h mild soap and water. OTHER CLOTHING AND EQUIPMENT: Impervious protective clothing and chemically res stent safety shoes should be worn to minimize contact. Wash con' amtnated clothing with soap and water and dry before r:euse. Emergency shower and eyewash facility should be in close proximity. OCCIDENTAL CHEMICAL Page 5 of 9 MSDS NUMBER: M482~' ®1-14-93 PRODUCT NAME: 'CAUSTIC SODA-BEADS VI. PHYSICAL DATA BOILING POINT @ ?es mm Hg: 1388°C FREEZING POINT: 3t8°C VAPOR PRESSURE: 42 mm Hg @ IGS~C SPECIFIC GRAVITY (H20:t) : ' 2. 13 @ 2~°C SOLUBILITY IN H20 .% BY WT: Completely Soluble VAPOR DENSITY (Air=t): NA APPEARANCE AND ODOR: Clear whlte solld with no. distinct' odor. pH: ~.~1 moles/liter has pH. 12.~ VII. REACTIVITY DATA CONDITIONS CONTRIBUTING.TO INSTABILITY: Under'normal conditions of use., this material is stable. INCOMPATIBILITY: See Section VIII.' Avoid contact with water. This product may be added slowly to water.or acids with dilution and constant stirring to avoid a violent exothermic reaction. When handling this product, avoid contact with aluminum, tin, zinc, and alloys. containing these metals. Do not mix with strong acids without dilution and agitation ±o prevent violent or explosive reaction. Avoid contact with leather, wool, acids, organic halogen compounds, and organic nitro compounds. HAZARDOUS DECOMPOSITION PRODUCTS: None known. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION: Not known to polymerize. VIII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: Do not get into eyes,' on skin, on clothing. Avoid breathing dust, mists, or spray... Do not take internally. Use with adequate ventilation and employ.respiratory protection when exposure to dust, mist or spray is possible. When handling, wear chemical splash goggles, face shield, rubber gloves and protective clothing. Wash thoroughly after handling or contact - exposure can cause burns which are not immediately painful.or visible. Keep container closed. Product can react violently with water, acids, and other substances - read Special Mixing and Handling Instructions below carefully before using. Product is corrosive to tin, aluminum, zinc and alloys containing these metalS, and will react violently with these metals in powder form. Hazardous carbon monoxide gas can form upon contact with food and beverage products in enclosed spaces and can cause death. Follow appropriate tank entry procedures (ANSI Zll?. 1). OCCIDENTAL CHEMICAL Page 6 of 9 MSDS NUMBER: M4820 ' 01-14-93 PRODUCT NAME: CAUSTIC SODA-BEADS VIII. HANDLING AND STORAGE (Continued) SPECIAL MIXING AND HANDLING iNSTRUCTIONS:' Product can react violently wit.h water. Considerable heat is · · generated when product is mixed with water. Therefore, when making solutions always carefully follow, theSe steps:. ALWAYS wear' ALL protective clothing described above. NEVER add water to product. ALWAYS add product - with constant stirring - slowly to surface of lukewarm (80-100°F) water, to assure product is being completely dissolved as It is added. If product is added too rapidly, or without stlrr lng, and becomes concentrated at. bottom of mixtng vessel, excessive heat may be generated, resulting in DANGEROUS boiling and spattering, and a possible IMMEDIATE AND VIOLENT ERUPT[ON of highly caustic solution. NOTE: 50 pounds of product dissolved in 20 gallfns of 90CF water will raise temperature of resulting solution to approximately 180~F. Never add more product than can be absorbed by solution while maintaining temperature below 20E~F (@' sea level) to prevent boiling and spattering. Product can react EXPLOSIVELY with acids, aldehyces., and many other organic chemicals - when mixing product with Solutions containing such chemicals, follow all of above mixing instructions, and add product very gradually, .while stirring constantly. ALWAYS empty and clean containers of all residuee before adding product, to avoid possible EXPLOSIVE reaction between product and unknOwn residue. Returnable containers should be shiPped in'accorcance with supplier's recommendations. Return shipments should comply with all federal, state, and DOT regulations. All resicual caustic soda should be removed from containers prior to dieaosal . IX. ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Leaks should be stopped. Spills should be conta ned and cleaned up immediately. Liquid spills should be rt moved by using a vacuum truck. Solid spills should be scooped up and placed in approved containers for disposal. Neutralize remaining traces of material with any dilute inorganic acid such as hycroch]oric, sulfuric, nitric, phosphoric or acetic acid. The spill area should then be flushed with water followed by liberal covering of sodium bicarbonate.. All clean-up material should ~e removed and placed in approved containers, labeled and stored n a safe place to await proper treatment or disposal. Spills. on reas other than pavement, e.g. , dirt or sand, may be handled y removing the affected soils and placing in approved containers. Persons · performing clean-up work should wear adequate pets nal.protective equipment and clothing. Spills or releases Should be reported, if required, to the appropriate local, state, and rE,dural regulatory agencies. CAUTION: Caustic Soda may react violentl with acid water. OCCIDENTAL CHEMICAL Page 7 of 9 MSDS NUMBER: M4828 8t-t4-93 PRODUCT NAME: CAUSTZC SODA-BEADS IX. ENVIRONMENTAL PROCEDURES (Continued) 'WASTE DISPOSAL METHOD= The materials resulting from clean-up operations may be .hazardous waste and; therefore, subject.to specific regular!ohS. Package, store, transport, and dispose of a]] clean-up materials and any contaminated equipment in accordance with all applicable federal, state, and local .health environmental regulation. Shipments of waste materials are subject ±o manifesting requirements per applicable regulations. Appropriate disposal will depend on the nature of each waste material and should be performed by competent and properly permitted contractors. Ensure that al] responsible federal, state, and local agencies receive proper notification of spill and disposal methods. X. ADDITIONAL INFORMATION OSHA Standard 29CFR 1918.1288 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, material safety data sheets, training and access to written records. We request that you, and it is your legal duty to, make al] information in this Material Safety Data Sheet available to your employees. To aid our customers in complying with regu]atory requirements, SARA Title II! hazard categories for this product are indicated in Section I. If the word "YES" appears next to any category, this product may be reportable by you under the requirements of 48 CFR Part 378. Please consu]t those regulations for details. Xl. PREPARATION INFORMATION For additional Non-Emergency health, safety, or environmental information telephone (716) 286-3881, or write to: Occidental Chemical Corporation Product Stewardship Department Suite 488 368 Rainbow Boulevard South Niagara Falls, NY 14382 For Emergencies: 24 HOUR EMERGENCY PHONE: 1-800-733-3665 This MSDS replaces MSDS No M4828 dated 83/38/92. OCCIDENTAL CHEMICAL Page 8 of 9 MSDS NUMBER: M482Q ®t-14-93. PRODUCT NAME: CAUSTIC SODA-BEADS WARNING LABEL INFORMATION SIGNAL WORD: DANGER' STATEMENT OF HAZARDs: CAUSES SEVERE BURNS TO SKIN, EYES AND'MUCOUS MEMBRANE ~. CONTACT WITH EYES CAN CAUSE PERMANENT EYE DAMAGE. INHALATION OF.DUST, MIST', OR SPRAY CAN CAUSE SEVERE LJNG DAMAGE. CAN. REACT VIOLENTLY'WITH'WATER, ACIDS; AND OTHER SUBSTANCES. PRECAUTIONARY STATEMENTS: Do not get into. eyes, on' skin, on clothing. Avoid breathing dust, mist, or spray. Do not take internally. Use with adequate ventilation and employ respiratory' ~rotectton when exposure to dust, mist or spray is possible. When handling', wear chemical splash goggles, face sh ~ld, rubber gloves, and protective clothing. Wash thoroughly after handling or contact - exposure can cause burns which are not immediately painful or visible Keep container closed. Product can react violently with water, acids, 'and o' her substances - read Handling and Storage instructions below carefully before using. Product is corrosive to'tin, aluminum, zinc and alloys containing these metals, and will react violently with these m ~tals.in powder form. Hazardous carbon monoxide gas can form upon co~tact w th food and beverage products in enclosed spaces and can cause teeth. Follow appropriate tank entry procedures {ANSI Zl14, 1). FIRST AID: FOR EYES: 'OBdECT IS TO FLUSH MATERIAL OUT IMMEDIATELY THEN SEEK MEDICAL ATTENTION, IMMEDIATELY flush eyes with large amounts of water · for at least 15 minutes, holding lids apart to ensure flushing of the entire surface. Washing eyes within several se:onds is essential to achieve maximum effectiveness. SEEK M~DICAL ATTENTION IMMEDIATELY. FOR SKIN: IMMEDIATELY wash contaminated areas with plenty of water for at least 15 minutes. Remove contaminated clothing and footwear and wash clothing before reuse. Discard footwear which cannot be decontaminated. SEEK MEDICAL ATTENTION IMMEDIATELY IF INHALED: Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops, give mouth-to-mouth resuscitation. GET MEDICAL ATTENTICN. IF SWALLOWED: NEVER GIVE ANYTHING BY.MOUTH TO AN UNCONSCIOUS PERSON. If swallowed, DO NOT INDUCE VOMITING. Give large quarJtities of water. If available, give several glasses o~ milk~ If vomiting occurs spontaneously, keep airway clear. SEEK MEn CAL ATTENTION IMMEDIATELY. IN CASE OF: SPILL OR LEAK: Leaks should be stopped. Spills, after c°ntalnm~ st, should be shoveled up or removed by vacuum truck (if liquid) to chemical waste area. Neutralize residue with dilute acid, lush spill area with water followed by liberal covering:of socium bicarbonate. Dispose of wash water and spill by-prodUcts according to federal, state, and local regulations. OCCIDENTAL CHEMICAL Page 9 of 9 MSDS NUMBER: M4820 01-14-93 PRODUCT NAME: CAUSTIC SODA-BEADS WARNING LABEL INFORMATION (Continued) HANDLING AND STORAGE: Considerable heat is generated when product is mixed with water. Therefore, when making solutions always'carefully follow these.steps: ALWAYS wear ALL protective clothing described above. NEVER add water to product. ALWAYS add Product - with constant stlrr!ng - slowly to surface of lukewarm (8®-1S9°F) water, to assure product is being completely dissolved as it is added. If product is added too rapidly, or without stirring, and becomes concentrated at bottom of mixi.ng vessel, excessive heat may be generated, resulting in DANGEROUS boiling and spattering, and a possible ZMMEDIATE AND VZOLENT ERUPTION of highly caustic solution. NOTE: 5~ pounds of product dissolved in 30 gallons of 99°F water will raise temperature of resulting solution to approximately 18e°F. Never add more product than can be absorbed by solution while maintaining temperature below 2990F (@ sea. level) to prevent boiling and spattering. Product can react EXPLOSIVELY with acids, aldehydes, and many other organic chemicals - when mixing product with solutions containing such chemicals, follow all of above mixing instructions, and add product very gradually, while stirring constantly. ALWAYS empty and clean containers of all residues before .adding product, to avoid possible EXPLOSIVE reaction between product and unknown residue. Returnable containers should be shipped in accordance with suppl ier's recommendations. Return shipments should compl'y with all federal , state, and DOT regulations. All residual caustic soda should be removed from containers prior to disposal. DISPOSAL The materials resulting from clean-up operations may be hazardous wastes and, therefore, subject to specific regulations. Package, store transport, and dispose of all clean-up materials and any contaminated equipment in accordance with all applicable federal, state, and local health environmental regulations. Shipments of waste materials may be subject to manifesting requirements per applicable regulations. Appropriate disposal will depend on the nature of each waste material and should be performed by competent and properly permitted contractors. Ensure that 811 responsible federal, state, and local agencies receive proper notification of disposal. INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS: This product contains: CAS# NAME 131e732 Sodium hydroxide (Ne(OH)) 7647145 Sodium chlOride (NEC1) 497198 Carbonic acid disodium salt HMIS RATING SYSTEM: HEALTH 3 FLAMMABILITY 0 REACTIVITY 2 FOR INDUSTRIAL USE ONLY LABEL 013M4820 ~ I)RIL~'~I'~ FLUlUS MATERIAL SAFETY DATA'SHEET A Baker Hughes company Nitpark DriLLing FLuids SuppLier: NILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 ttouston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 I. - MANUFACTURER'S INFORMATION: Product Name: COTTONSEED HULLS CAS Nunber: NAV Code: 1216290 Chemical Name: CELLULOSE Chemical Description: COTTONSEED HULLS DOT Hazard CLass: NAP Shipping Id. No. - UN: NA: DOT Proper Shipping Name: II. - INGREDIENTS: ............ ~:~?~.~..°~..~.!?~.~.~.!~!~:!~!~ ........ { .... ~!~: .... { .... ~ .... { .... ~f~ .... {..~LI.~f.L.~C..: .......... HAP INAP INAP INAP tNAP INAP NAP INAP {NAP INAP INAP INAP NAP {NAP {NAP {NAP NAP {UP NAP {NAP {NAP {NAP NAP{NAP .............................................................. ......... {cc ......... ......... {cc:..{cc: .................. ............ ~c~c:~?~:.~c?~:.!~.~?.~_~?~!: ................ { .... ~!~: .... { .... ~: .... {.~:~L~?:I._~:.I.~L~: .......... NAP HAP INAP IHAP INAP {NAP ~AP NAP I#AP {NAP {NAP INAP NAP NAP INAP INAP INAP INAP ~AP NAP INAP INAP INAP INAP NAP INAP INAP INAP INAP INAP III. - PHYSICAL DATA: BoiLing Point(F): NAP Vapor Pressure(n~nHg): NAP Specific Gravity: NAV PH: NAP Netting Point(F): NAP Vapor Density(Air=l): NAP Percent VoLatile By Voiume(~): NAP Freezing PointCF): NAP SoLubility In ~ater: NAP Evaporation Rate: ( .. = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: BROI~N FLAKES/ODORLESS Material Is: PURE-SOLID Coefficient of ~ater/Oi[ Distribution: PARTIALLY SOLUBLE IN ~ATER IV. - FiRE & EXPLOSION HAZARD DATA: Ftashpoint(F): NAP Auto Ignition Temperature(F): NAV FLammabLe Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To Impact: NAP Extinguish Media - ~ater: X C02: X Haton: Dry ChemicaL: X Foam: X Fog: Hazardous Combustion Products: CO, C02 Fire Fighting Procedures: VEAR SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS AND FULL FIRE FIGHTING PROTECTIVE CLOTHING FOR ENCLOSED AREA. UnusaL Fire and ExpLosion Hazards: TREAT AS FLAIqNABLE DUST ~HEN IN THE SUSPENDED STATE. V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under t4hich Conditions? NAP IncompatibLity (MateriaLs to Avoid): HEAT, OXIDIZING AGENTS. Hazardous Decomposition or ~yproducts: HEAVY SMOKE, CO COZ HazaFdous Polymerization - May Occur: Vil[ Not Occur: X Conditions to Avoid: NAP MATERIAL SAFETY DATA SHEET 7~00 Hollister Rd., Suite 300 Emergency Telephone: ~13) 439-890u IJ~ Houston, Texas 77040 CHR~E FREE II CHEMTREC: 1~00-42~9300 ~NUFACTURER'S INF~TI~: Nanuf~turer: BAKER HUGHES INTEG HMIS Hazard Rati~ HeaLth 0 MiniM[ - 0 Product Name: CHROME FREE II a~ Key: F[aamabi{t~ 1 SLight - 1 Choice[ Name: FLUID LOSS, VISC~ITY CONTROL AGENT Emotivity 0 #oderate - 2 Choice[ De$crJptJ~: CHRC~IEFREE LIGNO~LF~ATE Pera~[ Seriou~ - Proration E Severe - Pr~r Shi;iH Descriptim: DR%LLING FLU%D C~P~JND, N.O.S. Hazard CLass: NOT RE~LATED UN N~nber: NA Hazard La.L: ~ DOT Resrx~e Gui~: NA Trans~rtati~ Note: NA --- n~Ku,u~.zr,~,,~:l==~:~::=::::T~:~::~= ................................. = .......... ======~--~--'===========-~- == -- ' ....... =====: ...... ................................ Hazar~ Ass~iat~ wi~h Pr~t Use ~Yes Yes Yes es Combustible Liquid F[anmabte #ateria[ Pyrophoric Nater~a[ Exp[~ive Nateriat U~tab[e Material ~ater Reactive #ateria[ Oxidizer Organic Peroxi~ Corrosive Nateria[ Compress~ Gas Irrit~t Nuisance ParticuLate X Skin Hazard Eye Hazard Toxic Ag~t HighLy Toxic Ag~t Sensitizer Carci~g~ R~roductive Toxin Brood Toxin He~ous S~t~ Toxin L~a~g Toxin Liver Toxin Kidney Toxin Coam~Jty Right-to-K~u (SARA TitLe lZl SectJm 311-312) Sudd~ Re[ease Of Pr~sure: Reactivity: I~mdiate (Acute): X Oe[ay~ [IL.- PHYSI~L OATA: aD[Ling Point(F): NA Va~r Pr~sure(n~g): NA PHc ~.1-~.~ (1CreSOL) ~e[ting Point(F): NA Va~r Oe~sity(Air=l): NA Specific Gravity: O.S Fr~zing Point(F): NA So[~i[ity In ~ater: APPRECIABLE Perc~t VoLatiLe By Vo[,-~([): ]-6 ~or ThreshoLd: ND Appearance A~Odor: L%GHT TAN, SL%GHT ~ Eve~ratim Rate ( = 1): HA ~aterieL Is: NIX-POkiER Coeffici~t of Water/OiL Oistri~ti~: NA F[ash~int(F): NA Auto Igniti~ Te~rature(F): NA F[an~nab[e Limits - LFL: NA UFL: NA Exp[osi~ - LEL: NA ~L: NA Extinguish #~ia - ~ater: X C02: X Ory Ch~ica[: X Foam: X F~: X ~azardousCombusti~ Products: UPON C~aUSTI~, OXIDES OF ~RB~ AND SULFUR, ~OKE AND IRRITATING F~ES ~¥ F~N. Fire Fighting Procedures: USE POSITI~ PRES~RE SELF-C~TAINED BERTHING APPARATUS ANO PRIER PROTEETI~ CLOTHINg ~HILE FIGHTING FREES IN ENCLOSEO CONFINEO SPACES OURING A FIRE. Unus~[ Fire a~ Exp[osi~ Hazard: NOXJ~S ~LFUR OIOXIDE ~¥ F~N IH FIRE C~OITI~S. V. - REACTIVITY OATA: Chmica[[y Stab[e: Yes: x No: if ~, Under ~ich Conditi~s7 NONE EEPORTEO. [~c~tibtity (Nateria[a to Avoid): AVO[O STR~G OX[OIZING AGENTS Oecompoaiti~ or B~roducts: PE~UCT ~ILL NOT REalLY OEC~POSE. PoLymerization - ~ay~cur: ~it[ Not ~cur: X Conditi~ to Avoid: HA NO - Not Oete~ined NA - Not App[ic~[e T - Total O~t R - Reapirab[e Frecttm C - Ceiii~ Limit Pa~ 1 CHRONE FREE I! Primary Exposure Route - Skin Contact: X Skin Absorption: Eye Contact: X lnh. JLation: X Ingestion: Pr-~-~--~'-t CarcinogeflicJty- NTP: NO IARC: NO Acute Effects of Overexposure: PRODUCT DUST HAY HECHANICALLY IRRITATE EYES AND SKIN. PROLONGED INHALATION HAY CAUSE SHGRTHESS OF IREATH, C~UGHING AND CHEST TIGHTNESS. INGESTION OF S~ALL A#OUNTS SH~IJLD GIVE NO EFFECT BEYOND HILD $TONACH UPSET IF ANY. Chronic Effects of Overexposure: PRODUCT NAY AGGRAVATE AN EXISTING ALLERGIC SKIN ON RESPIRATORY CONDITION CHARACTERIZED BY TOPICAL ;ICIN IRRITATION OR BREATH', DIFFICULTY. VII. - E#ERGENCY AND FIRST AID INSTRUCTIONS: Eye~: FLUSH WITH LARGE A~OUNT$ OF MATER FOR AT LEAST 15 HINUTES AND CO~TACT A PHYSICIAN. Skin: MASH AFFECTED AREA MITH HILD SOAP AND MATER. IF IRRITATION PERSISTS CONTACT A PHYSICIAN Ingestion: GIVE FLUIDS TO DILUTE. CONTACT-A PHYSICIAN Inhalation-~ RENOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHIHG IS DIFF ~JLT, GIVE OXYGEN. VIII. - EHV[RON#ENTAL PROTECTION PROCEDURES: SpJ LL Response: gEAR PROPER PROTECTIVE EGUIPNE~IT. CONTAIN THE SPILL AND ~dEEP INTO A SUITABLE CO#TAINER. KEEP OUT )F gATERgAYS. Mesas Disposal #ethod: AS A MASTE, PRGOUCT 1S NOT HAZARDOUS ACCORDING TO RCRA CRITERIA OR LISTING AS SUPPLIED. DISPOSE at IN ACCORDANCE WITH LOCAL AND FEDERAL REGULATIONS. Handling: CAUTION! PRODUCT PlAY IRRITATE EYES, SKIN AND RESPIRATORY SYSTEH. AVOID CONTACT AJ~D INHALATION OF JSTS. ~t'EAR PROPER PROTECTIVE EQUIPHENT STATED IN THE HSDS. Storage: STORE IN A COOL, WELL-VENTILATED AREA. KEEP CONTAINER CLOSED WHILE NOT Il/ USE. DO NOT REUSE EHPTY CONTAIhlERS BEFORE DISPOSAL. IX. - OCCUPATIONAL CONTROL HEASURES: Respiratory Protection: gEAR AN APPROVED PARTICULATE RESPIRATOR WHERE RE--ENDED EXPOSURE LI#ITS llY BE EXCEEDED. Vefltitation: SUPPLY HECHANICAL OR LOCAL EXHAUST VENTILATION TO INSURE EXPOSURES ARE BEL RECI:I~EH1)ED LEVELS. CLothing: ~ LONG PROTECTIVE CLOTHING. LAUNDER CLOTHING BEFORE REUSE. Eyesear: gEAR CHE#ICAL SPLASH GOGGLES OR SAFETY GLASSES MITH SIDESHIELDS WHILE HANDL NG PRODUCT. GLoves: WEAR GLOVES TO PREVENT SKIN CONTACT. Footwear: JSE NORHAL SAFETY BOOTS. Other Heasures: GO~O PERSONAL HYGIENE IS ENCOURAGED TO H[NIHIZE EYE AND SKIN IRRITATION.NON: gASH AFTER HANDLING AND BEFORE HEALS OR BREAKS. CLEAN EQtJiPHENT BEFORE EACH'USE. X. - ADDITIONAL INFOIU~ATION: DISCLAIHER The statements, information, and data provided in this material safety data sheet are believed reLia ~Le and accurate by Baker Hughes [NTEQ and its res~',~ibLe pors~L; h~ver, no other g~rantc~, r~:}res~tation, warranty or resp~ibiLity is express~l or :o any user, regardless of reliance on all or My part thereof. This includes warrantiesi of merchar.tobitity or of fitness for s =articular FxJrpose, and Baker Hughes IHTEQ assunes no responsibility uhatever for advice or recoffrnerdatiofls made. Nothing contained herein should be interpreted aa permiaaiofl, inducement, or conclonemeflt to violate any Law! perauont o this pr_~k__~_tws USe, coflvey~-"-. or disposal. 04/0~/9 Prepared By: Jim Rushing Date Prepared: 05/12/94 : Supercecles Issue Date: ND - Not Detemined #A - Mot Applicable > - Greater Than < - L~sa Than C - Ceiling Lilit Po~ 2 MATERIAL SAFETY DATA SHEET 7000 Hoilister Rd., Suffe 300 Emergency Telephone: (713) 439-890~ I~ Houston, Texas 77040 CHEMTROL X · CHEIVITPJ;C: 1-800-424-9300 ) NANUFACTURER~S INFORMATION: Manufacturer: BALER HUGHES INTEQ HMIS Hazard Rating HeaLth 0 Minimal - 0 Product Name: CHEMTROL X and Key: FLammability 1 SLight - 1 Chemical Name: FILTRATION CONTROL AGENT Reactivity 0 Noclerate - Chemical Description: HIGH TEMPERATURE POLYMER/LiGNiTE BLEND Personal Serious - Protection E Severe Proper Shipping Description: ORILLING FLU[O COMPOUND, Hazard CLass: NOT REGULATED UN Nar: NA Hazard LabeL: NA DOT Response Guide: NA Transportation Note: NA Ii. - HAZARD IDENTIFICATION: ...... ................................ ........ sOOIU~ H¥OROXIOE ~Z.O MG/M3 C ]Z.O MG/K~ C I<1 ]1110-7'5-2 /100,000 LB. LEONARDITE, AS COAL DUST ~2.0 MG/M~ R /2.0 NG/I,~ R IPROP. 11415-93-6 INA Hazards Associatedwith Product Use Yes Yes Yes Yes CombustibLe Liquid FtatrnabLe Material Pyrophoric Material ExpLosive Material UnstabLe Material Water Reactive NateriaL Oxidizer Organic Peroxide Corrosive Material Compressed Gas irritant Nuisance ParticuLate Skin Hazard Eye Hazard Toxic Agent ' HighLy Toxic Agent Sensitizer Carcinogen Reproductive Toxin BLood Toxin Hervous System Toxin Lung Toxin X Liver Toxin Kidney Toxin Community Right-to-Know (SARA TitLeiIi Section 311-312) . ~: Sudden ReLease Of Pressure: Reactivity: In~iate (Acute): X DeLayed (Chronic): iii. - PHYSICAL OATA: BoiLing Point(F): NA Vapor Pressure(mmHg): NA PH: 9-10 MeLting Point(F): NA Vapor Density(Air=l): NA Specific Gravity: 1.3 'Freezing Point(F): NA SoLubiLity in Water: APPRECIABLE Percent VoLati[e By VoL~ae([): NA Odor ThreshoLd: ND Appearance And Odor: BLACK, EARTHY OOOR Evaporation Rate ( HateriaL is: MIX-POUOER Coefficient of Water/OiL Distribution: ND IV. - FIRE & EXPLOSION HAZARD DATA: Ftashpeint(F): NA Auto Ignition Temperature(F): gA FLan~mbLe Limits - LFL: NA UFL: NA ~: ExpLosion - LEL: NA UEL: NA Extinguish Media - Water: X C02: X Dry'ChemicaL: X Foam: X Fog: X Hazardous ContxJstion Products: UPON COMBUSTION, OX%DES OF CARBON MAT FORM PROOUC%NG TOXIC FUMES, Fire Fighting Procedures: IN CASE OF FIRE, GENTLY APPLY WATER FOG TO THE SURFACE OF THE BURNING MATERIAL USING CARE NOT TO SUSPEND DUSTS. PROTECTIVE CLOTHING AND SELF-CONTAINEO BREATHING APPARATUS MAY BE HEEDED FOR ENCLOSED AREAS OURING A FIRE. Unusua[ Fire and ExpLosion ~azards: HIGH CONFINED CONCENTRATIONS OF DUST MAY RESULT i# A POTENTIAL EXPLOSIVE ATMOSPHERE. V. - REACTIVITY DATA: ChemicaLLy StabLe: Yea: X No: if no, Under Which Conditions? AVOID VERY DUSTY CONDiTiONS. lncompatib[ity (MateriaLs to Avoid): AVOiO STRONG OXiDiZERS. ./*-*~dousOecampositionor Byproducts: PRODUCT WiLL NOT READILY DECC~POSE. ~dous PoLymerization - Nay Occur: Wit[ Not Occur: X Conditions to Avoid: HA ND - Not Determined NA - Not AppLicabLe T - Total Dust R - Respirabie Fraction C - CeiLing Limit CHENTROL X CHEHTROL X VI. - HEALTH HAZARD INFORNATION: Primar~ Exposure Route - Skin Contact: X Skin Absorption: Eye Contact: X Inh;Lation: X Ingestion: Product CarcinogenJcJty - NTP: NO IARC: NO Acute Effects of Overexposure: PRODUCT NAY CAUSE HECHANICAL IRRITATION TO EYES, SKIN AND UPPER RESPIRATORY SYSTEH. INHALATION OF UST NAY CAUSE COUGH, SHORTNESS OF BREATH OR CHEST TIGHTNESS. Chronic Effects of Overexposure: PROLONGED INHALATION OF DUST CONTAINING FREE CRYSTALLINE SILICA NAY RESULT IN DELAYED LUNG INJURY. IARC HAS CLASSIFIED FREE CRYSTALLINE SILICA AS PROBABLY CARCINOGENIC FOR HUNANS. VII. - EHERGENCY AND FIRST AID INSTRUCTIONS: Eyes: HOLD EYELIDS APART AND FLUSH WITH CLEAN RUNNING WATER FOR AT LEAST 15 NINUTES. CONSULT A PHYSICIAN. Skin: WASH AFFECTED AREA THOROUGHLY WITH #]LD SOAP AND UATER. Ingestion: GIVE FLUIDS TO RINSE NOUTH AND ~THROAT AND TO DILUTE. CONSULT A PHYSICIAN. InhaLation: REHOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIF]CZAL RESPIRATION. IF BREATHING IS DIF:ICULT, GIVE OXYGEN. VIII. - ENVIRONHENTAL PROTECT[ON PROCEDURES: Spi{[ Response: WEAR PROPER PROTECTIVE EQUIPNENT. CONTAIN THE SPILL. REBAG AND SELL IF POSSIBLE. SWEEP RESIDUE IHTll A SUITABLE WASTE CONTAINER. RENOVE ALL SOURCES OF IGNITION IF SPILL IS IN A CONFINED AREA. KEEP OUT OF WATERWAYS. SPILL RQ IS 00,000 LBS OF PROOUCT. Waste Disposal Hethed: FIATERIAL IS NOT HAZARDOUS ACCORDING TO RCRA CRITERIA OR LISTING. AS SUPPLIED. DISPOSE OF IN ACCORD ,NCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling: WARNING! CONTAINS CRYSTALLINE SILICA, INHALATION OF WHICH NAY CAUSE CANCER. INHALATION HAY CAUSE R SPIRATORY IRRITATION. NEAR PROPER RESPIRATORY PROTECTION. NININIZE CONTACT WITH EYES, SKIN, AND CLOTHING. Storage: STORE IN A t~ELL VENTILATED AREA. AVOID H%GN DUST CONCENTRATIONS. KEEP AWAY FRON HEAT, SPARES AND PEN FLANES. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT REUSE CONTAINERS BEFORE RECONDITIONING OR DISPOSAL. IX. - OCCUPATIONAL CONTROL HEASURES: ............ ~ .................... ~)~==~AA ......................... ~ ......................................... - ......... ~N:~DED EXPOSURE LIHITS HAY= === ==== Respiratory P otection: WEAR AN APPR D RTICULATE RESPIRATOR IF R C 3E EXCEEDED VentiLation: USE #ECHANICAL OR LOCAL EXHAUST VENTILATION TO INSURE CONPLIANCE WITH REC~ 4ENDED EXPOSURE LI#ITS. CLothing: WEAR LONG PROTECTIVE CLOTHING WITH AN'APRON OR COVERALLS FOR ADDED PROTECT Eyeuear: WEAR CHENICAL SPLASH GOGGLES DURING USE. Groves: USE NEOPRENE OR BUTYL-RUBBER GLOVES TO PREVENT SKIN CONTACT. Footuesr: UEAR NORNAL SAFETY BOOTS. Other #assures: GOQ) PERSONAL HYGIENE IS ENCOURAGED TO NINIHIZE EYE AND SKIN IRRITATION. LAUNDER CONTAHINATED CLOTHING BEFORE REUSE. X. - ADDITIONAL INFORNATION: DISCLAIMER The statemantao information, and data provided in this material safety data sheet are be[iieved re[J~b[e and accurate by Baker Hughe~ INTEQ and its responsible porsannel; houever, no other guarantee, represontatJon, uarranty or resporsibiiJty is expressed or implied to any user, regardless of reliance on ali or any part thereof. This includes ~arranties of merchm tabi[ity or of fitness for particular purpose, and Baker Hughes INTEQ assu~es no responsibility ~hatever for advice or recaeme datiorm mede. Nothing contained herein should be interpreted as penaission, inducement, or condonement to violate any ~a~ persuant io this product's use, convqv-~.e or disposaL. Prepared By: Jim Rushing Date Prepared: 03/05/9& Supercedes IsSUe Date: 05/01/91 ND - Not Determined NA - Not Appkicabke > - Greater Than < - Lest Than C - Ceiling Liait Page HUG-.-'O-'9~ FRI 16."18 fD:HILPRRK DF SLC UT TEL N0;88i 263 $UN~23-1993 18:10 PROM WB S~LLIURN-D.~LG.SPEC.DEN TO i8058340264 P,O1 ,,,. ~ Material Safety Data Sheet DRILL-THINTM THINNER PHONE NU~ERS B&r~l~=vtll~, O~Llahoma 74004 Gc~e~al MSD$ P~oduct Identification S~non~m~t Drilling mud Chemical Fa~ily~ P~oduct N9.~ Not P~oduC~ and/or C~mponent$ g.e~r~d on EPA'~ TSCA InVe~ory~ Components G~S ~ O~HA ~ngr~d&en%~ Nu~b~ B~ W%. PE~ TLV ma~ ~n~lude= Crys%a~l~nt ~&l~ca Variou~ · ! 0.1 mo/mS 0.1 Pa~t 1910.1200(i). In ~he ~ven~ o~ a medical emergency, At will bo prov~dod ~o a ~rea~ing phF~i~an or ~ur~e ~hrough u%iliza~ion of '~ove E~e~genoy Telophon~ Nu~er. __~O_~.~..~..~F,~.~_~6:l~ [D~I.~K .DF SLC UT TEU NO:~O1Z~5 Z~5 ~ ~U~ JUN-25-~3 18:11 FROH W~ SLILLIU~-DRL~.SPEC.DEN TO 18058~40264 P.O~ C. Personal Protection Information level~. E~e Pro~ction, U~e ch~ic~ ~og~les, D. Handling: arid Storage Precautions DO not get &~ eyes, On skin, oV On clothi~g. Bo not b~eathe dust. Nash condi%ion~ warrat. Use o~ly with adequate vln~ilation. E. Reactivity Data /n~ompattbili~ (Nat~rials to lvotXi)~ Oxidtlil~g agents, Hazardous Polymerization~ ~tI1 Not Occu~ Hazardous Dscomposition P~oduetst Sulfur and carbon oxid~ £~med ~he~ bu~n~d, Health Hazard Data Recommended Exposure Limit~. S~e S~tion B, Drill-3:d~TM Thinno' (US315030) P~e 2 of 5 Acute Effects of Overexposur~ ~ye, Hay ca~sc severe i~rita~ion o~ burns to ~he Ingestion, ~y cause ~stroin~s~$~l traot irritation, nausea, vomi~lng~ diarrhea, ~evere poisoning requl~e$ immediate ~edical at%enti~n,. Subchronie ~md Chronic Effects of O~erexposure: C~tallin~ ~i~ca, n common co~onen~ of ~and, has bee~ ~eporied to cause Crya*a~line ~ilmca'h&s been.~lamsifiod a~ a p~obable human ~arcinogen Feedin~ ~u~£es u~ing a component ~howed ~rowth re~arda2ion an~ o~ pH t~ body O~er Health Effect: Preexisting medical ~o~di%ions ~hi~h may be affff~ava~ed b~ e.v~posu~e include, de~itis, a~tHma, coaJu.no~iv~tis, stomach or dige~tiv.~ problems. Health Hazard Categories: Animal H,~aa~ An~aal Human iCno~n Carcinogen J(_ To~i~ Suspeo~ Oa~-c~o~an ~ _X ~ Cor~'os~ve ~]~ ~ Mut agen -- X~ i~ a~t T~ato~en Ta~e~ Organ To,in _~ ~ ~lerg~o ~ensitAze~ ~. '~ SD~clfy - Lung Toxin. Highly T~aA~ First Aid and Emergency Procedures: ~ye, Immediately flush ~yes wx~h running wate~ for at lea~ f~fteen mAn~es. Seek m~4ical &tten~on. ~kin: Immediately wash with soap and water. If f~i%a%lon develops, ~nhala~on~ R~m~v~ ~om ~xpg~V~. ~£ ~1~ o~ ad¥~ symptoms develop~ seek ~edical at~ntion. Ingestiont Give two glasses o~ Water and induce vomiting, only if ~ubJect i~ co~,~Ciovs. $~e~ immediate ~edical attention. Note ~o PhySfci~n~ This produet contair~ ivon ~alts. If ~ever~y of poison~u~ requires chelation therapy, th* ~ollowing is ~e¢ommen~ed, contain~ng ~odiu~ b~ca~bona~e~ 20 mg/1. heave 10 m~s o~ ' ....... .:_ Dele~oxa~ine in 50 mi of 51 ~odium bicarbonate in the ~tomach. RUG-20--'93 F~ &6:2& ~D~IL~RRK DF SLC UT TEL N0=80~ 265 2885 R058 P~b .......... JUN-2~r1993 18:12 FROM WB SOLLtVRN-DRLG.SPEC, DEN TO ~858340264 P.04 G. Physical Data Agpe~anOt: Fi.ne reddiah"bvown powder H. Fire and Explosion Data ~L - No~ dioxide (COa) F~o and ~plosf~n H~za~d~: I~ ~ a f~ely divided and ~us~end~d L Spill, Leak and DispOsal Procedures P~cau~lons Requi~ed i~ Na~erial il R~l~a~ed o~ Spilled, · EVaO~a~e a~ea o£ ~1! unnecessary pe~m~l, ~©ar p~%sc~ve ~q~pm~n~ ~as~e Dfspoaal (ln~e Conio~mi~y with ill Applicable Disposal le~lation~), P~.ace in ~ permitted ~s~e disposal ~actlity. DOT Trartsportt~tion Shippfn~ Name: No~ A~licable ID Number, NO~ ~plic~Xe Na~k~9: No~ Applic~le ~bel: Not Applicable Placard, Not H~dous ~u~st~ce/~t No~ AppXiC~le DrIII-Tl~inTM Thinner (U$315030) Page 4 of $ ~UN~23-1993 l@:l~ M~OM ~B ~U~LZ~N~DRLG.SPEC.D~N TO 1~58340264 K. RCR~I Classification - Unadulterated Product as a Waste Pr~O~ ~0 d~sposa~, con~u~t your Env~ronmen~&l contact to dote~mLne 1311) ~ ~qu~ed, Ro~e~nc~ &O CFR P~t 261. L. Protection Required for Work on Contaminated Equipment ~on~ac~ ~med~ato ~ugerv~o~ ~o~ '~peci£~c f~uc~ons b~£or~ ~o~k ~s M. Hazard Classification ~_ Th~ p~odu~t meets the £Ol~o~ng hazard def~u~on(s) a~ de£~n~d ~a ae~tion 1910.1~00): N. Additional Comments ~nv~roma~ntal ToxLci~y~ Envi~onme~t&~ effocts ~es~in~ h~ boen conducted usir~ this and g~neric mud. The t~sts we~ conducted ~ccord~9~ t~ the 1~$~ U. S, ~A draft ~hodo~ogy - Drilling Fluid Toxicity Tests. ~ene~tc mud i~ a~ a concentration o~ 4 ppb (pound~ pe~ bar~l)~ ~here m~sid ~u~p~nded paniculate pht~. for tho mysid ~h~imp was As of the p~pa~ation date, ~his Droduct did no~ contain chemical or ohemicals sub}~c~ to %he repo~in~ ~e~iOn ~13 ~f Title III o~ %he S~=fun~ ~endme~ts and R~authg~i~%%i~n Act of 1986 ~d ,%0 CFR Pa~% FW~ OR ~OT~g~ ~A~NTY. EX--SS OR IMPaleD, IS MADB ~ ~RN$ T~ ~FO~TION HEP.~ gROVID~. The tu~rmatl~ say a~d alt It~}ll~ ~ ~ any ~vlt~ Obtained Or Dr;iblhlnTM T}Ganer (U$$ ;. 5030) P~$c $ 9f S SAFETY DATA SHEET MATERIAL 7000 Hollister Rd., Sure 300 Emergency Telephone: (713) 439-890u ~JMrrJ~ll:~ Houston, Texas 77040 HEC CHEMTREC: 1-800-424-9300 Manufacturer: BAKER HUGHES INTEG HNIS Hazard Rating HeaLth 0 Minimal - 0 Product Name: HEC and Key: FtanmabiLity 2 SLight - 1 Chemical Name: DRILLING FLUID VISCOSIFIER Reactivity 0 Moderate - Chemical Description: CELLULOSE, 2-HYDROXYETHYL ETHER Persona[ Serious - Protection E Severe - Proper Shipping Description: DRILLING FLUID COMPOUND, N.O.S. ' ~ Hazard CLass: NOT REGULATEO UN Nunber: NA Hazard LabeL: NA DOT Response Guide: NA Transportation Note: NA .... ~"~ II. - HAzARD IDENTIFICATION: Hazards Associated with Product Use Yes Yes Yes Yes CombustibLe Liquid F[an~nabLe Material Pyrophoric Material ExpLosive Material U~tab[e Material Uater Reactive Material Oxidizer Organic Peroxide Corrosive Material Compressed Gas Irritant Nuisance ParticuLate X Skin Hazard Eye Hazard Toxic Agent HighLy Toxic Agent Sensitizer Carcinogen Reproductive Toxin BLood Toxin Nervous System Toxin Lung Toxin Liver Toxin Kidney Toxin Co~a~Jnity Right-to-Know (SARA TitLe Ill Section 311-312) Sudden Re[ease Of.Pressure: Reactivity: In~nediate (Acute): X DeLayed (Chronic): III. - PHYSICAL DATA: BoiLing Point(F): NA Vapor Pressure(n~Hg): NA PH: 6.5-8.5 Me[ting PointCF): NA Vapor Density(Air=l): NA Specific Gravity: NO Freezing Point(F): HA SoLubiLity In Water: APPRECIABLE Percent VoLatiLe By VoL~ne(%): 5 Odor ThreshoLd: NONE Appearance And Odor: WHITE, COORLESS Evaporatio~Rate (. .... = 1): NA Material Is: MIX-POWOER Coefficient of Water/OiL Distribution: PARTIALLY SOLUBLE IN WATER IV. - FIRE & EXPLOSION HAZARO OATA: F[ashpoint(F): NA Auto Ignition Temperature(F): NA F[anmab[e Limits - LFL: NA UFL: NA ExpLosion - LEL: NA UEL: NA Extinguish Media - Water: X C02: X Dry ChemicaL: X Foam: X Fog: X Hazardous Combustion Products: UPON COMBUSTION, OXIDES OF CARBONt SMOKE AND IRRITATING FUMES MAY FORM. Fire Fighting Procedures: WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS AND SlRUCTURAL FIRE FIGHTING GEAR IN ENCLOSED OR CONFINED AREAS DURING k FIRE. GENTLY APPLY WATER FOG TO AVOIO SUSPENSION OF DUSTS. Unusual Fire and ExpLosion Hazards: MAY FORM EXPLOSIVE DUST-AIR MIXTURES. V. - REACTIVITY DATA: ChemicaLLy Stab[e: Yes: X No: If no, Under t~hich Conditions7 AVOIO OUSTY CONDITIONS, HEAT, ANO SPARKS. Incompatib[ity (MateriaLs to Avoid): AVOIO STRONG OXIDIZERS. ~dousOecompositionor Byproducts: NONE REPORTEO. ~az~ ~ous PoLymerizatioA - May Occur: Wit[ Not Occur: X Conditions to Avoid: NONE REPORTEO. NO - Not Determined NA - Not AppLicabLe T - Total Oust R - RespirabLe Fracti~ C - CeiLing Limit Page 1 HEC ::::::::::::::::::::::::::: Primary Exposure Route - Skin Contact: Skin Absorption: Eye Co, tact: X InhaLation: X Ingestion: Pr_,~h__u~_t Carcinogenicit¥ - NTP: NO %ARC: NO Acute Effects of Overexposure= PRODUCT MAY CAUSE ~]LD EYE, SKIN AND RESP]RATORY IRRITATION ~ITH OVEREXPOSURE. ]NGESTIO~ NAY CAUSE MILD STOMACH UPSET. Chronic Effects of OvereXposure='` CELLULOSIC DUSTS NAY AGGRAVATE AN EXISTING SKiN OR RESPIRATORY ALLERGIC CONDITION OR SENSITIZE SOME INDIVIDUALS ~ITH TOP]CAL SKIN OR RESPIRATORY ]RRITATION. VII. - EMERGENCY AND FIRST A%D INSTRUCT]OHS: Eyes= FLUSH ~ITH LARGE AMOUNTS OF CLEAN UATER FOR AT LEAST FIFTEEN MINUTES. CONTACT A PHYSIC]AN ]F IRRIAT]ON PERSISTS. Skin: WASH THOROUGHLY ~ITH SOAP AND ~ATER. Ingestion: DR]NK ~ATER TO RINSE ~OUTH AND'THROAT AND TO DILUTE. CONTACT A PHYSiC%AN IF UPSET OCCURS OR PERSISTS. InhaLation: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFIC]AL RESPIRATION. IF BREATHING IS D]FFICULT, GIVE OXYGEN. Viii. - ENV%ROHMENTAL PROTECTION PROCEDURES: Spill Response: USE NORMAL CLEAN-UP PROCEDURES FOR DRY PRODUCTS - SUEEP, VACULIN, ETC. KEEP OUT OF ~ATER~AYS. ~ET MATERIAL IS SLIPPERY. Uaste Disposal Method: ~ASTE PRODUCT IS NOT HAZARDOUS ACCORDING TO RCRA CRITERIA OR LISTING AS SUPPLIED. INC%NERAT]ON OF COMBUSTIBLE ~ASTE MATERIAL ' ITTED FACILITY IS RECOMMENDED ~HERE APPLICABLE. CC3NPLY ~[TH LOCAL, STATE AND FEDERAL REGULATIONS. ing: ~AUTION! PRODUCT MAY CAUSE MILD IRRITATION TO EYES, S~IN AND UPPER RESPIRATORY SYSTEM. AVOID EYE AND SKIN CONTACT. AVOID BREATHING DUSTS. ~,/EAR PROPER PROTECTIVE EQUIPMENT STATED IN THE MSDS. Storage: STORE 1N DRY AREA. K~EP DUST TO A NININI. J~. KEEP A~AY FROM ~EAT, SPARKS AND FLA~E. IX. - OCCUPATIONAL CONTROL ~EASURES: Respiratory Protectio¢~: I~EAR All APPROVED PARTICULATE RESPIRATOR IF RECOMMENDED EXPOSURE LII4[TS MAY BE EXCEEDED. VentiLation: SUPPLY VENTILATION NEEDED TO MAINTAIN DUST LEVELS 8ELO~ RECOt4MENDED EXPOSURES. CLothing: igEAR LONG PROTECTIVE CLOTHING. LAUNOER BEFORE REUSE. Eyeuear: ,, ~/EAR SAFETY CLASSES ~/ITH SIDESHIELDS TO PREVENT DUST FRC~ ENTERING EYES. GLoves: ~dEAR COTTON GLOVES TO PREVENT MECHANICAL IRRITATION. Foot.ear: USE NORMAL SAFETY BOOTS. Other Measures: USE GO00 PERSONAL HYGIENE TO MINIMIZE EYE ANO SKIN IRRITATION. CLEAN EQUIPMENT OF DUST BEFORE REUSE. UATCH FOR SLIP HAZARD ~/ITH I,I~T PRC~OUCT. X. : ADDITIONAL iNFORMATION: DISCLAIMER The statements, information, and data provided in this materia~ safety data sheet are believed reLiabLe and accurate by Baker Hughes INTE~3 and its responsible personneL; however, no other guarantee, representation, ~arranty or responsibility is expressed or implied to any user, regardless of reliance on aLL or any part thereof. This inctude~ uarranties of merchantability or of fitness for a particular purpose, and Baker Hughes ]NTECi assumes no respc~qsibiLity uhatever for advice or reccmme~datio~s made. Nothing contained he~l~ should be interpreted as permission, inducement, or condonement to violate any Leu persuant to this product's use, convey- ofl~posat.-- 'prOd By Jim ": . : Rushing Date Prepared: 05/19/9& Supercecles Issue Date: 07/25/89 ND - Not Determined NA - Not AppLicable > - Greater Than < - Less Than C - Ceiling Limit Page 2 MILPARK" MATERIAL SAFETY DATA SHEET DRILLING FLUIDS A Baker Hughes company Nilpark Drilling Fluids SuppLier: N%LPARK DRILL%NG FLU%DS 3900 Essex Lane, Suite :)00 MATERIAL SAFETY DATA SHEETS Address: :)900 Essex Lane Houston, Texas 7'/027 Houston, Texas 77027 Emergency Telephone: 71:)/4:)9-8000 Emergency Telephone: 715/4:)9-8000 I. - MANUFACTURER'S INFORMATION: Product Name: LD-8 CAS N~mnber: NAV Code: 1218151 Chemical Name: Chemical Description: A NON-HYDROCARBON BASE DEFOAMER FOR USE IN BOTH FRESH AND SALT WATER FLUIDS. DISPERSION OF FATTY ACID SOAP IN AM ALKOXYLATED ALC: HOL. DOT Hazard Class: NAP Shipping Id. Ho. - UN: NA: DOT Proper Shil~oing Name: ]]. - INGREDIENTS: PRODUCT IS NOT HAZARDOUS BY 29 CFR, NAP NAP NAP INAP NAP 1910-1200 REGULATIONS NAP NAP NAP INAP NAP NAP NAP NAP NAP NAP NAP HAP NAP NAP NAP NAP NAP .............................................................. ......... .......... ......... ................. ............ ~f~:~-~?~-!~-~?-~-~?~!~ ................ 1 .... ~!~ .... 1 .... ~ ...... ~:~-~1--~-1-~-~: .......... PROPYLENE OXIDE NAP INAP 125~000 <0.0875-56-9 HAP NAP INAP NAP NAP NAP NAP NAP NAP IMAP NAP NAP NAP NAP NAP INAP NAP NAP NAP INAP INAP INAP INAP INAP ]]]. - PHYSICAL DATA: Boiling Point(F): >392 Vapor Pressure(mnHg): <.01 Specific Gravity: .98 PH: 5.5-6.5 5% MeLting Point(F): NAP Vapor Density(Air=l): >1 Percent VD]Stile By VoLume(%): NAP Freezing Point(F): NAP Solubility In Water: NAP Evaporation Rate: ( = 1): NAP Odor Threshold: NAP Appearance And Odor: WHITE DISPERSION WITH BLANO ODOR Material Is: MIX-LIgUID Coefficient of Water/Oil Distribution: PARTIALLY SOLUBLE IN OIL IV. - FIRE & EXPLOSION HAZARD DATA: FLashpoint(F): >200 CLOSED CUP Auto Ignition Temperature(F): NAP Flammable Limits - LFL: NAP UFL: NAP Explosion - LEL: NAP UEL: MAP Rate Of Burning: NAP Sensitivity To Impact: NAP Extinguish Media - Valet: X C02: X Halon: Ory Chemical: X' Foam: X Fog: Hazardous Combustion Products: NAP Fire Fighting Procedures: VEAR SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS AND FULL FIRE PROTECTIVE CLOTHING FOR ENCLOSEO AREAS. Unusa[ Fire and Explosion Hazards: NAP V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under Which Conditions? NONE KNOWN OTHER THAN TO AVOID HIGHLY REACTIVE CHEMICAL OXIDANTS Incompatiblity (Materials to Avoid): STRONG OXZDIZING AGENTS Hazardous Decomposition or Byproducts: OXIDES OF CARBON Hazardous Polymerization - May Occur: Ui[l Not Occur: X Conditions to Avoid: NAP Mitpark Drifting FLuids SuppLier: NILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 39C ) Essex Lane Houston, Texas 77027 Ho[~ton, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency To{ .~hone: 713/439-8000 VI. - HEALTH HAZARD DATA: LD-8 Carcinogen - NTP Program: NAP Carcinogen - IARC Program: NAP Symptoms of Exposure: NAP Medical Conditions Aggravated Sy Exposure: NAP Emergency and First Aid Procedures: Eyes: FLUSH WITH COP[US AHOUNTS OF WATER AND CONTACT A PHYS[CZAN, Skin: WASH AFFECTED AREA WITH SOAP AND WATER. SwaL[ou: CONSULT A PHYSIC[AN. O[RECT TREATMENT AT CONTROL OF SYMPTOMS. Breath: REMOVE TO FRESH AIR. V;[. - ENVIRONMENTAL PROTECTION PROCEDURES: SpiLL Response: ABSORB WITH INERT ABSORBENT HATERZAL AND STORE [N CONTAZNERS FOR DISPOSAL. PREVENT MATERIAL FROM ENTI;RING DRAINS, SEWERS OR STREAMS. Waste OisposaL Method: OISPOSE IN ACCOROANCE WITH LOCAL, STATE ANO FEOERAL REGULATIONS. HandLing and Storage: NAP VIII. - SPEC[AL PROTECT[ON IHFORMAT[ON: VentiLation: LOCAL EXHAUST CLothing: NORMAL GLoves: NEOPRENE, BUTYL-RUBBER TO PREVENT SKIN CONTACT Eye: GOGGLES Foot,ear: NORMAL Other: EMERGENCY EYE WASH Known Hazards Under 29 CFR 1910.1200 I HMIS I NFPA |Yesl /Yest .......................... t .................. ........................ t-"t ......................... t---I HeaLth: 1 I HeaLth: 1 / Co~bustibteLiquid Skin Hazard X I FLammabiLitY: 0 IFLammabiLity= 0 F[an~ab[e Material Eye Hazard X Reactivity: 0 StabiLity: 0 ExpLosive Material HighLy Toxic Agent ................................................. UnstabLe Material Sensitizer Water Reactive MateraL Carcinogen I Oxidizer Reproductive Toxin Organic Peroxide BLood Toxin I Corrosive Material Nervous System Toxin Compressed Gas Lung Toxin I irritant Liver Toxin Nuisance Dust Kidney Toxin j ' ............................ ~ ......................... ~---t .................................. ?-: ................................. Physical & HeaLth Hazard - SARA &O CFR Part ]?0 (CheCk aLL that al:~Ly) (NOTE (*) indicates TLV lot nuisance dust on[y) Fire: Sudden'Re[ease Of Pressure: Reactivity: Ina~diate(Acute): X ' Oe[ay~CChronic): IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contaminated Equipment: HAV Other Precautions: AVOID VREATHING VAPORS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. Hi[park DriLLing Fluids SuppLier: H%LPARK DR%LLING FLUIDS 3900 Essex Lane, Suite 300 HATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane -' ~ Houston, Texas 77027 Houston, Texas 77027 ~ Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 I~ VI. - HEALTH HAZARD DATA: LD-8 Carcinogen - NTP Program: NAP Carcinogen - [ARC Program: NAP Symptoms of Exposure: NAP HedicaL Conditions Aggravated By Exposure: HAP Emergency and First Aid Procedures: Eyes= FLUSH WITH COPIUS AI4(XJNTS OF WATER AND CONTACT A PHYSICIAN. Skin: WASH AFFECTED AREA WITH SOAP AND WATER. S~aLLow: CONSULT A PHYSZCIAN. DIRECT TREATHEHT AT CONTROL OF SYMPTOMS. Breath: REMOVE TO FRESH AIR. VI%. - ENVIRONMENTAL PROTECT]ON PROCEDURES: SpiLL Response: ABSORB W%TH INERT ABSORBENT MATERIAL AND STORE IN CONTAINERS FOR DISPOSAL. PREVENT MATERIAL FROM EHTER%NG DRA%NSt SEWERS OR STREAMS. Uaste Disposal Method: DISPOSE IN ACCORDANCE ~ITH LOCALt STATE AND FEDERAL REGULATIONS. HandLing and Storage: HAP VIII. - SPEC%AL PROTECT%OH INFORMAT%OH: RespiratoryProtection: HAP VentiLation: LOCAL EXHAUST C£othing= HORHAL GLoves: NEOPRENE, BUTYL-RUBBER TO PREVENT S[%N CONTACT Eye: GOGGLES ~ Foot,ear= HORMAL Other: EHERGEHCY EYE UASH Known Hazards Under 29 CFR 1910.1200 I HMIS NFPA IYesl |Yest .................................................... ........................ t'"t ......................... ~'"/ HeaLth: 1 HeaLth: 1 Combustib[eLiquid IlSkin,azard XlF[ammabiLity:O FtanmabiLity:O FLammabLe Material Eye Hazard X Reactivity: 0 StabiLity: 0 ExpLosive HateriaL HighLy Toxic Agent ................................................... UnstabLe HateriaL Jl [ Sensitizer Uater Reactive Hatera[ Carcinogen Oxidizer J Reproductive Toxin Organic Peroxide BLood Toxin Corrosive Material I I Nervous System Toxin Compressed Gas Lung Toxin Irritant I I Liver Toxin Huisance Oust Kidney Toxin ........................ ~---~ ......................... ~---~ ....................................... · .................................. Physical & HeaLth Hazard - SARA 40 CFR Part ]70 (Check aLL that apply) (NOTE (*) indicates TLV for nuisance dust on[y) Fire: Sudden ReLease Of Pressure: Reactivity: %n~edJate(Acute): X DeLayed(Chronic): IX. - SPEC[AL PRECAUTIONS: Precautions For Repair & Maintenance Of ContaminatedEquipment: NAV Other Precautiens: AVOID VREATHIHG VAPORS. AVOID CONTACT ~ITH EYES, SKIN, AND CLOTHING. MILPARK" DRILLING FLUIDS MATERI!AL SAF -'TY DATA SHEET A Baker Hughes company Hi[~nk Drilling Fluids Sup ier: HILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 HATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency Telephone: 713/439-8000 Emer!ency Tetephene: I. - MANUFACTURER'S iNFORMATION: Product Name: LD-8 CAS #uaber: NAV Code: 1218151 Chemical Name: Chemical Description: A NON-HYDROCARBON BASE OEFOAMER FOR USE IN BOTH FRESH AND SALT VATER FLUIDS. DISPERSiON OF ~TTY ACID SOAP IN AN ALKOXYLATED ALC:. HOL. DOT Hazard CLass: NAP Shipping Id. No. - UN: NA: DOT Proper Shipping Name: II. - INGREDIENTS: PRODUCT IS NOT HAZARDOUS BY 29 CFR, IHAP NAP INAP 1910-1200 REGULAT%ONS ~NAP NAP ~NAP~ ~NAP {NAP NAP INAP NAP INAP! INAP INAP HAP INAP NAP INAP| INAP INAP .............................................................. .......... ......... ......... .................. HazardousSubstance(EPA~OCFR302): I PIN: ,LV: IPr(~v~.~l..~.l.~.~..u~__r .......... PROPYLENE OXIDE INAP INAP 1125, 300 1<0.08175-56-9 NAP JHAP INAP IHAP )NAP IHAP HAP INAP INAP INAP INAP INAP NAP INAP INAP INAP INAP INAP NAP INAP INAP INAP INAP INAP ]]I.' PHYSiCAL DATA: Boiling Point(F): >392 Vapor Pressure(n~Hg): <.01 Specific Gravity: .~8 PHc 5.5-6.5 5~ He[ting Point(F): NAP Vapor Density(Air=l): >1 Percent Volatile By ¢o[ume(~): NAP Freezing Point(F): NAP Solubility In ~ater: NAP Evaporation Rate: (.. = 1): NAP Odor Threshold: NAP Appearance And Odor: ~HiTE DISPERSION WiTH BLAND ODOR Material Is: MIX-LIQUID Coefficient of Water/Oil Distribution: PARTIALLY SOLUBLE [N O%L IV. - FiRE & EXPLOSION HAZARD DATA: F[ashpoJntCF): >200 CLOSEO CUP Auto Ignition ~emperature(F): NAP F[anmable Limits - LFL: NAP UFL: NAP Explosion - LEI: NAP UEL: NAP Rate Of Burning: NAP SenSitivity To Impact: NAP Extinguish Hedia - Water: X COZ: X Ha[on: Dry Chemical: X' Foam: X Fog: Hazardous Conex~stionProducts: NAP Fire Fighting Procedures: WEAR SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS ANO FULL FIRE PROTECTIVE CLOTHING F~ ENCLOSED AREAS. Unusa[ Fire and Explosion Hazards: NAP V. - REACTIVITY DATA: Chemical Stab[e: Yes: X No: If no, Under Vhich Conditiorts? NONE KNOI, M OTHER THAN TO AVOID HIGHLY REACTIVE CHEH%CAL OX%DANTS ]nco~patib[ity (Materials to Avoid): STRONG OXIDIZING AGENTS Hazardous Decomposition or Byproducts: OXIOES OF CARBON Hazardous Polymerization - May Occur: Will Not Occur: X Conditions to Avoid: NAP MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., Sure 300 Emergency Telephone: (713) 439-890u · !j~rj~i~ Houston, Texas 77040 LIGCO CHEMTREC: 1-800-424-9300 0~- NUFACTURER'S INFOR ILO#: Manufacturer: BAKER HUGHES INTEG HMIS Hazard Rating HeaLth 0 Minimal - 0 ProduCt Name: LIGCO and Key: FLaamabiLity 2 SLight - 1 Chemical Na~e: FILTRATION CONTROL AGENT Reactivity 0 Moderate - Chemical Description: HIGHLY OXlDIZEO LEONAROITE Personal Serious Protection E Severe Proper Shipping Description: DRILLING FLUID COMPOUND, N.O.S. Hazard CLass: NOT REGULATED UN N~mt~er: NA Hazard LabeL: IdA DOT Response Guide: NA Transportation Note: NA !1. -HAZARO IDENTIFICATION: .... ................................ ~EO#A~DI~. AS COAL DUST 12.0 MG/M3 R 12.0 NG/M3 R 197 iiiii!~6~!; ..... 11415-93-6 INA SILICA, CRYSTALLINE QUARTZ /0.1 NG/N~ R 10.1 NG/N~ R 13 I "Jiil ................. Hazards Associated with Pr_~k__uct Use Yes Yes Yes Yes CombustibLe Liquid Ftanmab[e NateriaL Pyrophoric Nateria[ ExpLosive Nateria[ UnstabLe Material Water Reactive Material Oxidizer Organic Peroxide Corrosive Nateria[ Compressed Gas Irritant Nuisance ParticuLate X Skin Hazard Eye Hazard Toxic Agent HighLy Toxic Agent Sensitizer Carcinogen Reprt~_~tive Toxin BLood Toxin Nervous System Toxin L~qg Toxin Liver Toxin Kidney Toxin Conm~ity Right-to-Kno~ (SARA TitLe II! Section 311-312) Sudden ReLease Of Pressure: Reactivity: Inmediate (Acute): X DeLayed (Chronic): Ill. - PHYSICAL DATA: BoiLing Point(F): NA Vapor Pressure(n~g): NA PH: &-6 (I~LSOL) NeLting Point(F): NA Vapor Oermity(Air=l): NA Specific Gravity: 1.5-1.8 Freezing Point(F): NA SoLubiLity In Water: INSOLUBLE Percent VoLatiLe By Vo[~mae(Z): NA Odor ThreshoLd: ND Appearance And Odor: BRC~ TO BLACIC, EARTHY ODOR Evaporation Rate ( ~ 1): NA NateriaL is: PURE-POidOER Coefficient of Water/Oi[ Distribution: INSOLUBLE IN OIL IV. - FIEE & EXPLOSION HAZARD DATA: Fiashpoint(F): ]10 (PMCC) Auto Ignition Temperature(F): NA Ftafm~b[e Limits - LFL: NA UFL: NA ExpLosion - LEL: HA UEL: NA Extinguish Nedia - Water: X C02: X Dry ChemicaL: X Foam: X Fog: X Hazardous Combustion Products: UPON COMBUSTION, OXIDES OF CARBON NAY FORM PROOUCING TOXIC FUHES. Fire Fighting Procedures: IN CASE OF FIRE, GENTLY FLOGO gITN WATER USING CARE NOT TO SUSPEND DUSTS. SELF-CONTAINEO BREATHING APPARATUS NAY BE NEEOEO IN EHCLOSEO AREAS DURING A FIRE. Unusual Fire and Exptesion Hazards: PRODUCT NAY FORM EXPLOSIVE OUST-AIR MIXTURES AT VERY HIGH DUST CONCENTRATIONS. V. - REACTIVITY DATA: ChemicaLLy StabLe: Yes: X No: If no, Under ghich Conditions7 NONE REPORTEO. IncaqoatibLity (MateriaLs to Avoid): STRONG OXIOIZING AGENTS. ACTS AS AN O~GA#IC REDUCING AGENT. rdous Decomposition or Byproducts: PRODUCT gILL NOT REAOILY DECOMPOSE. PoLymerization - May Occur: gilt Hot Occur: X Conditio~ to Avoid: NA NO - Not Determined NA - Not AppLicabLe T - Total Dust R - Respiralote Fraction C - CeiLing Limit LIGCO IS REGISTERED TRAOENARK OF BAKER HUGHES INTEO. Page 1 LIGCO Primary Exposure Route - Skin Contact: Skin Absorption: Eye Contact: X Inhalation: X Ingestion: Product Carcinogonicity - NTP: NO IARC: NO Acute Effects of Overexposure: HAY CAUSE NECHANICAL IRRITATION TO THE EYES, SKIN ANO UPPER RESPIRATORY TRACT. INGESTION HAY CAUSE STOflACH UPSET, NAUSEA, VC~qlTING OR OIARRHEA. rJironic Effects of OverexposUre:"' UNPROTECTED PROLONGED INHALATION OF DUST CONTAINING CRYSTALLINE SILICA HAY CAUSE PERMANENT LUNG AND LIVER INJURY. LINITED EVIDENCE (IARC) SHC~S THAT THE INHALATION OF CRYSTALLINE SILICA CAUSES CANCER ]N HU~ANS. VII. - EMERGENCY AND FIRST AID I#STRUCTIONS: Eyes: HOLD EYELIDS APART AND FLUSH WITH HATER FOR AT LEAST 15 MINUTES. CONSULT k PHYSICIAN IF IRRITATION PERSISTS. Skin: WASH THOROUGHLY WITH SOAP ANO WATER. APPLY MEDICATED CREAMS TO RELIEVE IRRITATION AND REPLENISH *SKIN OILS. Ingestion: GIVE FLUIDS TO RINSE MOUTH AND'THROAT IRRITATION ANO TO OILUTE. CONSULT A PHYSICIAN IF ADVERSE SYMPTOMS OEVELOP. Inhalation: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. VIII. - ENVIRONMENTAL PROTECTION PROCEOURES: Spill Response: WEAR PROPER PROTECTIVE EGUIPNENT (SECTION IX). RECOVER SPILLEO MATERIAL TO THE C~IGINAL CONTAINER FOR SALE IF POSSIBLE. SHOVEL WASTE INTO A SUITABLE WASTE CONTAINER. NININIZE OUSTING DURING CLEANUP. FLUSH RESIOUE WITH UATER. Waste Disposal Method: )RCX)UCT IS NOT HAZAROOUS ACCOROING TO RCRA CRITERIA OR LISTING AS SUPPLIED. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE ANO Fl ~ULATIONS. inN: CAUTIONI MAY CAUSE MECHANICAL IRRITATIOH TO EYES, SKIH ANO UPPER RESPIRATORY TRACT. AVOIO UNNECESSARY CONTACT ANO HIGH OUST CONCENTRATIONS. Storage: STORE IN A DRY AREA. KEEP DUSTS TO A MINIMUH. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE WITH AOEGUATE VE#TILATIO#. IX. - OCCUPATIONAL CONTROL NEASLIRES: Respiratory Protection: WEAR AN APPROVEO PARTICULATE RESPIRATOR IF EXPOSURE LIMITS NAY BE EXCEEDEO OR FOR COMFORT. VentiLation: SUPPLY NECHANICAL EXHAUST TO INSURE SAFE EXPOSURES TO PARTICULATE DUSTS. Clothing: WEAR LONG PROTECTIVE CLOTHING WITN AN APRON FOR AOOEO PROTECTION. LAUNDER CLOTHING BEFORE REUSE. Eye,ear: ~EAR SAFETY GLASSES WITH S[OEGUAROS OR GOGGLES OUR[NG USE. INSURE A PROPER FIT FOR BEST PROTECTION. G~oves: ~EAR GLOVES TO PREVENT MECHANICAL IRRI~ATION. Footuear: I~R NC~14AL SAFETY BOOTS. Other Measures: INSURE USE OF GOC~ PERSONAL HYGIENE. CLEAN EOU[PMENT OF RESIOUES BEFORE REUSE. WASH AFTER HANOL]NG ANO BEFORE NEALS OR BREAKS. USE APPROPRIATE MILO CLEANSERS TO gASH OFF PRCOUCT. X;'~ ADOIT]ONAL INFORKATION: OISCLA]MER The statements, informtion, and data provided in this material safety data sheet are believed reLiabLe and accurate by Baker Hughes INTEG and it· responsible per·or, eL; however, nD.other guarantee, representation, warranty or respordibiLity is expressed or implied to any user, regardless of reLi~ce on aLL or any part thereof. This includes warranties of merchantability or of fitness for · particular purpose, and Baker Hughes INTEG assumes no respc~sibiLity ~t~atever for eclvice or recoa~tiofls Bade. #othir~ CQ~tair~,ct herein should be interpreted a· permission, inctuce~eflt, or condo~eme~t to violate ~ny law periuant to this product's use, conve sposaL. red My: Jim Rushing Date Prepared: 03/05/9& Supercecles Issue Date: 05/01/91 NO - Not Determined NA - Not AppLicabLe · - Greater Than < - Less Than C - CeiLing Limit Page 2 LOST CIRCULATION SPECIALISTS · o.@. [=~ox 53 Telephone ,; Ca_~per, Wyoming 82602 (307) 237-3315 MAGMA FIBER DATA SHEET ( ;CRIPTION: MAGMA FIBER is specially formulated, extursion spun mineral fiber. This coarse, long flexible fiber will give increased circulation by bridging and plugging off voids, fractures and all types of permeable formations. MAGMA FIBER is compatible with all oil and water based muds and emusions. The interlocking nature of these strong fibers provides a framework for forming a Iow permeable mud cake with a resultant reduction in drilling fluid loss and hole caving. Low alkaline, flexible, inorganic MAGMA FIBER is inert to drilling fluids. This fiber is non-corrosive to expensive equipment while maintaining high-solubility in diluted hydrochloric acid. It is particularly adaptable to rework operations. MAGMA FIBER is coated with a mono nuclear film of a specially formulated surfactant (that speeds seperation of the fibers), then formed into nodules. These nodules are formed into loosely connected groups so that when they are immersed in drilling fluids and subjected to agitation the nodules separated into the indlvidual fibers. ACID SOLUBLE, EASlLY-WE'FTED, NON-COMBUSTIBLE, NON-FERMENTING, INORGANIC, NON-POLLUTING, NON-CORROSIVE, NON-TOXIC, TEMPERATURE STABLE, CONTAINS NO ASBESTOS. TYPICAL ' COMPOSITION % WEIGHT CHEMICAL Sio~ 38-42 ANALSIS AL~o~ 8-12 Cao 19-28 (~ ' Mgo 5-9 Fe~o~ 10-16 Total alkalines as Nato 2-3 So3 1.0 Ph in water less than 8.0 Loss on ignition less than 0.5 % water soluble less than 0.2 Water soluble sulfate . lessthan 0.05 melting point 2400° F. ~PPLICATIONS MAGMA FIBER can be used in concentrations of up to 30 + Ib/bbl in slug treatments or as additive to entire system. MAGMA FIBER has been used in concentrations of 1/2 bag every 30 min. for ongoing seepage, to concentrations of 5-151b/bbl for seepage/partial or total losses. MAGMA FIBER is particulary~suitable for oil base mud, when more than 6-10 bags are mixed at once, a man should be at the shaker screen when the slug comes around (to clean or bypasss the shaker screen). MAGMA FIBER can be used in all oil and water base mud systems. MAGMA FIBER should be added directly into pits and gunned into the mud, it can be mixed through the mud hopper but it is much slower. Limitation When acid solubility is not important, a combination of materials can be added to ensure a good particle size distribution. tckaging MAGMA FIBER is available in 40 lb. (18kg) plastic sacks. ~ feets ~tated am::l ~ recommem:~afio~$ anti sugges~ herein are based upo~ expef'iments ~ informatio~ believa<l tO be reliable. NO gu~a~toe is made of their accuracy, however, ~ LOST CIRCULATION SPECIALISTS, INC. ASSUMES NO UASIUTY FOR PRODUCT FAILURE OTHER THAN TO SUPPLY REPLACEMENT MATERIAL FOR PRODUCTS SHOWN TO BE DEFECTIVE WHEN DELIVERED OR TO REFUND THE PURCHASE PRICE. Except as ~lated. THERE ARE NO WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OTHERWISE. LOST CIRCULATION SPECIAUST$, INC. SHALL NOT BE LIABLE FOR SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAJ~AGE$. NO stalemef~t c=~'~tainecl h~ein s,haJl be c~ as an inducement to ~ exis'~g patents o~' ~s a~ ~ o! pfoclucts of specific ma~u~actu~em. .-.; ~ Lost Circulation Specialists, Inc. Environmental Impact & Material Safety Data Sheet Lost Circulation Specialists MAGNA FIBER is inorganic, inert, and non-toxic. MAGMA FIBER a non-corrosive product. VlAGMA FIBER is under the classification of nuisance-type dusts. Lost Circulation Specialists re )mmends use of nuisanr~l dust, single use/disposable respirators or dust respirators certified by the National Institute for Oc,,'upational Safety or the Mine Safety and Health Administration (MSHA). Where dust concentrations cannot be eliminated or minimized by the use of ventilation controls, a respirator should be worn. Skin irritation, which may be ca[sed by handling MAGMA FIBER, is a mechanical irritation and not a allergic reation. It is transitory in nature (tempor~ry). The irritation can be eliminated or reduced significantly by following a few suggestions: compressed air should not )e used for removing fiber from clothing or skin areas. If fiber accumulates on skin areas, rinse with warm water, then w ~sh gently with soap, skin cream or lotion may be applied after washing. Use long-sleeved shirt and gloves. Physical Data MELTING POINT: 2400o F. SOLUBILITY IN WATER: Nil ACID SOLUBILITY: High solubility in diluted hydrochloric acid and/or mud acid. Fire and Explosion Hazard Data FLASH POINT (METHOD USED): None EXTINGUISHING MEDIA: Not combustible SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL FIRE AND EXPLOSION HAZARDS: None Health Hazard Data EFFECT OF OVEREXPOSURE: (~.~-.. ACUTE: · Magma Fiber may cause transitory mechanical irritation to eyes, skin or uppE respiratory tract. CHRONIC: None known. EMERGENCY AND FIRST AID PROCEDURES: EYES: Flush eyes with water and see physician if irritation continues. SKIN: Wash fiber from skin with soap and water. INHALATION: Remove to fresh air. INGESTION: Call a physician. Reactivity Data STABILITY: Stable ;~':. · CONDITIONS TO AVOID: None ..-i~,~ ..~..~:' INCOMPATABILITY: Acids .. ~;.. HAZARDOUS POLMERIZATION: Will not occur~ ~.:.- Spill or Leak Procedures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED::' Normal clean-up procedures. Avoid creating excessive dust. WASTE DISPOSAL METHOD: To landfill in accordance with local, state and federal regulatic Special Protection Information PROTECTIVE EQUIPMENT: Gloves if dust is irritating, tight fitting goggles in dusty environment. Wear loose fitting clothing and minimize skin exposure. Wash work clothes separately from other wash. NIOSH appro'/ed nuisance dust mask in dusty environment. LOST CIRCULATION SPECIALISTS P.O. Box 53 Telephone Casper, Wyoming 82602 (307) 237-3315 MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., Sure 300 Emergency Telephone: ~13) 439-8900 .... IJ~ Houston, Texas 77040 #ILNI~ (ALL GRAOES) CHEMTREC: 1-800-424-9300 '- ~NUFACTURER~S INF~NAT~: Manufacturer: BAKER HUGHES INTEG HNIS Hazard Rating HeaLth 0 #inimi - 0 Product Name: MILNI~ (ALL GRAOES) and Key: FLamaabiLity 0 SKirt - 1 Choice[ Name: LOST CZR~LATI~ ~TERIAL Reactivity 0 Noclerate - 2 ChmicaL Description: ~SCOVlTE NI~ Persona[ Serious - 3 Prot~tian E Severe - 4 Pro~r Shipping Oescription: ORILLING FLUIO C~POUNO, N.O.S. Hazard CLass: NOT RE~TED UN N~nber: NA Hazard La.L: ~ DOT Respor~e ~ide: NA Tra~rtation Note: NA II. - HA~RD IDENTIFI~TION: ...... ................................ .... ..... ........ MICA /3 MG/~ R II MG/~ R 100 12001-26-2 INA Hazar~ Associat~ with Product Use Yes Y~ Y~ CombustibLe Liquid F[amnab[e Material Pyro~oric Material ExpLosive Ne[erie[ U~tab[e #ateria[ Water Reactive Nateria[ Oxidizer Organic Peroxide Corrosive ~ateriaL Compressed Gas Irritant Nuisance ParticuLate Skin Hazard Eye Hazard Toxic Ag~t HighLy Toxic Agont S~itizer Carcinogon R~roductive Toxin BLood Toxin Nervous Systat Toxin L~g Toxin Liver Toxin Kidney Toxin Cemmnity Right-to-Know (SA~ TitLe 111S~tion ~11-312) r~re: SL__vS-Jen_ Re[ease Of Pressure: Reactivity: lemediate (Acute): X Oe[ayed (~ranic): X Ill. - PHYSI~L DATA: BoiLing Point(F): NA Vapor Pr~sure(nmHg): NA PH: ~ Me[ting Point(F): HA Vapor Oonsity(Air=l): NA Specific Gravity: 2.6 Freezing Point(F): NA SoLubiLity In ~ater: INSOLUBLE Percont VoLatiLe By ¥oL~ae(~): NA ~or Thr~ho[d: NmE Appearance AndOdor: SILVER TO G~¥, ~LESS EvaporationRate ( = 1): ~ Material is: ~RE-POgOER C~ffici~t of Water/OiL Dis[rib[ion: INSOLUBLE IN OIL IV. - FIRE & EXPLOSI~ HA~RD DATA: Fiashpoint(F): NA Auto Ignition Temperature(F): NA F[an~nab[e Limits - LFL: NA UFL: NA E~[oaion - LEL: NA UEL: ~ Extinguish Media - Water: C02: Dry ChemicaL: Foam: F~: Hazardous Combustion pr_nck_~ta: NOHC~BUSTIBLE. Fire Fighti~ Pr~edur~: C~PAT%BLE WITH AGENTS USED TO EXTIN~ISH ~RR~NDIHG FIRES. IH SUSPENDED DUST CONOITI~S, WEAR AN APPR~RIATE AIR-PURIFYING ~ AIR-SUPPLYING RESPI~T~ TO A~IO RESPI~T~Y IRRITATION ~ INJURY. Unusual Fire and Exp[~ion Hazards: NONE REPORTEO. V. - REACTIVITY DATA: Choice[Ky Stab[e: Y~: X No: If nc, Under ~ich Conditions? AVOIO OUST¥CONDITI~S. l~ompatib[ity (Materia[a to Avoid): NONE REPORT~. ~,rdom O~ompoaitim or Bypr_~_~ta: PR~UCT WILL NOT RE~%LY DEC~P~E. Hazardous Polymerization - Nay ~cur: Wit[ Not ~cur: X Conditions to Avoid: ~ ND - Not Dete~ined ~ -~ot AppLicabte T - Total O~t R - RespirabLe Fraction C - CeiLing Liait NILNI~ IS A REGISTERED TRADEMARK OF BAKER HUGHES INTEQ. Page 1 #IL#ICA (ALL GRADES) · VI. - HEALTH HAZARD INFORHATiON: Primary Exposure Route- Skin Contact: Skin Absorption: Eye Contact: X lr~mLatJon: X l~gestio~: Product Carcinogonicity - #TP: NO IARC: HO Acute Effects of Overexposure: HAY BE IRRITATING TO EYES, SKIN AND THE UPPER RESPIRATORY TRACT. HECHANICAL iRRiTATioN HAY BE C;IARACTERXZED BY SHORTNESS OF BREATH, COUGH, AND CHEST TIGHTNESS. EYES AND SKIN HAY DEVELOP REDNESS AND ITCHING. Chronic Effects of Overexposure: UNPROTECTED PROLONGED INHALATION OF DUST CONTAINING CRYSTALLINE SILICA HAY CAUSE PERHANENT LUNG AJID LIVER INJURY. LI#ITED EVIDENCE (IARC) SHO~S THAT THE INHALATION OF CRYSTALLINE SILICA CAUSES CANCER IN HUHANS. VII. - EHERGENCY AND FIRST AID INSTRUCTIONS: Eyes: FLUSH WITH CLEAN RUNNING 1dATER TO REHOVE DUST PARTICULATES AND CONTACT A PHYSICIAN IF IllRITATION PERSISTS. Skin: WASH AFFECTED AREA WITH #iLD SOAP AND WATER. RENOVE CONTAHINATED CLOTHING AND LAUNDER. Ingestion: GIVE FLUIDS TO RINSE HOUTH AND~THROAT AND TO DILUTE. IF UPSET OCCURS, CONTACT A PHYSICI;~N. Inhatstior~: REHOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING !$ DIFI~ICULT, GIVE OXYGEN. VI l I. - ENVIRON#ENTAL PROTECTION PROCEDURES: Spi I t Response: gEAR PROPER PROTECTIVE EGUIPHENT. CONTAIN THE SPILL AND SHOVEL TO A SUITABLE CONTAINER ;FOR RECYCLING OR SALE IF POSSIBLE. gET HATERIAL HAY BE SLIPPERY. KEEP OUT OF WATERWAYS. gaste Disposal #ethad: AS A WASTE, PROI)UCT IS NOT HAZARDOUS ACCORDING TO RCRA CRITERIA OR LISTING. DISPOSE OF IN ACCORDAI!CE WITH LOCAL, STATE AND F~ REGULATIONS DEALING WITH NONHAZARDCUS HINERAL WASTES. Handt inN: · MARNINGI CONTAINS CRYSTALLINE SILZCA, INHALATION OF WHICH HAY CAUSE CANCER. gEAR PROPER' RESPIRATOr Y PROTECTIVE EGUIPHENT. HAY CAUSE #ECHANICAL EYE, SKIN AND RESPIRATORY IRRITATION. AVOID CONTACT WITH EYES OR SKIN. AVOID BRE/.THING DUST. Storage; STORE IN A NELL VENTILATED AREA. KEEP CONTAINER CLOSED IJHEN NOT IN USE. KEEP DUSTS TO A #INIHUN. IX. - OCCUPATIONAL CONTROL #EASURES: Respiratory Protection: gEAR AR APPROVED PARTICULATE RESPIRATOR IF RECOHHENDED EXPOSURE LI#ITS HAY 3E EXCEEDED. VentiLation: SUPPLY ADEQUATE MECHANICAL VENTILATION TO INSURE SAFE EXPOSURES BELOU RECC~ 4ENDED LI#ITS. CLothing: gEAR LONG PROTECTIVE CLOTHING WITH AN APRON TO ICEEP OFF DUSTS. LAUNDER CLOTHES BEFORE REUSE. Eye.ear: gEAR SAFETY GLASSES WITH SIDESHIELDS. GLoves: klEAR GLOVES TO PREVENT NECHANICAL SKIN IRRITATION. Foot,ear: JSE NORNAL SAFETY BOOTS. Other Neaaures: YEARLY*CHEST EXA/41NATIONS ARE RECOI41qENDED AS A HEALTH HAINTENANCE #EASURE. WASH 'AFTER HANDLING AND BEFORE HEALS OR BREAKS. CLEAN EQUIP#ENT OF DUST BEForE USE. X. - ADDITIONAL ]NPOR)qATION: D I SCLA I HER The statements, information, and data provided in this material safety data sheet are believed reLie~Le and accurate by Baker Hughes [NTEQ a~d its resp~-~ibte persor~eL; however, rm other guarantee, representation, warranty or resrx~iibility is expressed or implied to any user, regar~ltess of reliance on att or any part thereof. This includes warranties of merchan~aJ~ility or of fitnes~ for a particular p~Jrpoee, a~d Baker Hughes INTEQ assuages no responsibility ~d~atever for mice or recae~enJatiorm made. Nothing contained herein should be interpreted ss perlisSion, inducement, or condor~ment to viotate any tsw.bersuant this prc~iuct~l use~ convr , 'e or dispos~l. . I 'i Prepared By: Jim Rushing Date Prepared: 05/17/9& ~upercede~ ieeue Date: 10/02/91 ND - Not Determined NA - Not AppLicabLe · - Greater The g - Le~ Thm~ C - Ceiling Limit Pag~ MILPARK" MATERIAL SAFETY DATA SHEET DRILLING FLUIDS A Baker Hughes company Milpark Drilling Fluids Supplier: MILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency Telephone= 713/439-8000 Entergency Telephone: 713/439-$000 I. - MANUFACTURERtS INFORMATION: Product Name: NIL-BAR REGULAR ~'C'~ ~ ~ CAS Number: 14808-60-7 Code: 1215010 Chemical Name: BARIUM SULFATE, BARITE Chemical Description: A HIGH PURITY BARITE USED TO INCREASE THE DENSITY OF ALL TYPES OF DRILLING FLUIDS. DOT Hazard Class: NAP Shipping Id. No. - UN: MA: DOT Proper Shipping Name: II. - INGREDIENTS: ............ ............. ;;:: .... i .... ;:;: .... i=:;:: .... i:=;:=i':::::=: .......... SILICA (QUARTZ) NAP ).1NG/N3 INAP )<5 )148o8-60-7 NAP NAP INAP J**TOTAL DUST)NAP INAP .AP N^.I"AP .API"AP I"AP NAP NAPINAP NAPINAP INAP ~:: ............................................................... ~: ......... 1~: ......... l~: ......... 1~:--1~: .................. ............ ~e~re~u~.~ue~em~.~r~.~.~r~.~ ..................... r~ .... 1 .... ~ .... l.rr~.~e~l..~.l.s~.e~r .......... SILICA (QUARTZ) NAP .lNG/N3 INAP 1>5 14808-60-7 **TOTAL DUST _ NAP NAP ~NAP INAP NAP NAP NAP NAP NAP INAP INAP NAP NAP NAP NAP INAP INAP NAP NAP )NAP INAP ~NAP (NAP III. ' PHYSICAL DATA: Boiling Point(F): NAP Vapor Pressure(mmHg): NAP Specific Gravity: 4.2 PH: INSOLUBLE Melting Point(F): 2876 Vapor Oensity(Air=l)= NAP Percent Volatile By VoL~zne(~): NAP Freezing Point(F)= NAP Solubility In Water: SLIGHTLY Evaporation Rate= ( = 1)= NAP Odor Threshold= NAP Appearance And Odor= GRAY TO PINK AND ODORLESS Material Is: PURE-POWOER Coefficient of Water/Oil Distribution= INSOLUBLE IN WATER IV. - FIRE & EXPLOSION HAZARD DATA= Flashpoint(F)= NAP Auto Ignition Temperature(F)= NAP F[ar~nab[e Limits - LFL: NAP UFL: NAP Explosion - LEL= NAP UEL= NAP Rate Of Burning: NAP Sensitivity To Impa. ct: NAP Extinguish Media - Water: X C02: X Halen= Dry Chemical: X Foam: X Fog: Nazardous Con~b~stion Products: WHEN IN PRESENCE OF EXTREME NEAT COULD PROOUCE CO, C02 FOR TNOSE ORES CONTAINING ANTS. OF CARBONATES Fire Fighting Procedures= NAP Unusat Fire and Explosion ~azards: NAP V. - REACTIVITY DATA= Chemical Stable= Yes: X No: If no, Under Which Conditions? HEATING WITH ALUMINUM CAN PRODUCE AN EXPLOSION. Incompatib[ity (Materials to Avoid)= HEATING UITH ALUMINUUM CAN PROOUCE AN EXPLOSION. Hazardous Decomposition or ByprOducts: THERMAL DECOMPOSITION PROOUCTS- CO, C02, OXIDES OF SULFUR Hazardous Polymerization - May Occur= Will Not Occur= X Conditions to Avoid: NAP NiLpark Drilling FLuids Supplier: MILP~RK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Hous:on, Texas 77027 Emergency Telephone: 713/6,39-8000 Emergency TeLe=hone: 713/6,39-8000 V[. - HEALTH HAZARD DATA: NIL-BAR REGULAR Carcinogen - NTP Program: NAP Carcinogen - IARC Program: HAP Symptoms of Exposure: PROLONGED iNHALATiON OF THE POM)ER CONTAINING FREE CRYSTALLINE SILICA MAY RESULT IN SiliCOSIS, A NONoC%NCEROUS LUNG DISEASE OR OTHER RESPIRATORY DISEASE. NedicaL Conditions Aggravated By Exposure: NAP Emergenc~ and First Aid Procedures: Eyes: FLUSH ~dZTH LARGE AHOUNTS OF CLEAN RUNNING tdATER FOR AT LEAST FIFTEEN NiHUTES AND CONTACT A PH~ SICIAN iF IRRZTATiOH DEV- ELOPS/PERS I STS. Skin: ~/ASH VITH SOAP AND VATER $~aLLo~-- COHSULT A PHYSLCIAN Breath: REHOVE FROR EXPOSURE TO FRESN AiR V[[..- ENVIRONMENTAL PROTECTION PROCEDURES: SpfL[ Response: NORMAL CLEAH-UP PROCEDURES FOR DRY PRCOUCTS - VACUUH, ETC. Uaste Disposal Method: DISPOSE IN ACCORDANCE V[TH LOCAL, STATE AHD FEDERAL REGULATIONS. HendtirKj and Storage: AVOID CREATING DUST I. ADEN ATNOSPHERES. VIIi. - SPECIAL PROTECT[OR INFORHATION: Respiratory Protection: k~cAR NLOSH/NSHA APPROVED RESPIRATOR IF TLV HAY BE EXCEEDED. Ventilation: LOCAL EXHAUST CLothing: LAUNDER BEFORE REUSE Gloves: AS PERSONAL NEEDS DICTATE. Eye: SAFETY GLASSES/GOGGLES Foot~,~ar: NORHAL Other: AS HEEDED FOR PERSONAL COHFORT Kno~ Hazards U~er ~ CFR 1910.1200 ~ HN[S ; NFPA . /Yes/ /Yesl .......................... t ........................ ........................ t---t ......................... t---/ Health: 1 I Health: 1 Combustible Liquid Skin Hazard I FLanmabiLity: 0 I FLmmmbiLity: 0 FLa~bLe Material Eye Hazard j Reactivity: 0 I Stability: 0 Pyrophoric Material Toxic Agent Explosive Material Hi, ghLy Toxic Agent ..................... Unstable Material Sensi tizer UaCer Reactive MateraL Carcinogen I Oxidizer Reproductive Toxin J OrgenfC Peroxide Blood Toxin I Corrosfve Material Nervous System Toxin Compressed Gas L~g Toxin I irritant Liver Toxin Nuisance Dust X Kidney Toxin Physical & Health Hazard - SARA 6,0 CFR Part 370 (Check al[ that apply) (NOTE (*) indicates TLV for nuisance dust only) Fire:* Sudden Release Of Pressure: Reactivity: %n~nediate(Acute): * OeLa/ed(Chronic): ? IX..- SPECIAL PRECAUTIONS: Precautions For Repair & Haintenonce Of Contaminated Equipment: O~er Precautions: AVOID CREATIHG DUST LADEN ATHOSPHERESo '"' ....... ........... := .................................. :_- SENT BY:BAKER HUGHES TNTEQ ;10-13-94 ; 1:$2PM ; BAKER HUGHES [NTE9.-+ 8058340264;¢ 1 VL, I J~ "~' I,~:F--'Ji PIAVl'l ll'~ I~..~ i r~our~l ~ m~'". , v ,-, ........ .,., ................ .- iil__zr'~ -- -T-ii-i..~'-':l-'---- rll'- , 2m .............. '~ ~v Iff~ of ~~s , (t~) S~ T~T THE IN~TI~ OF ~YITALLIME SI~X~ ~U~8 ~ IN ~S, ~~-- .... '~& ' ' r' _=~2. _&~_.~ -- ~=~ ~.~:~__ __ __~, . ~;~ ~ t! .... 2t~ _ ........... ,. __ r Y~LY ~ST ~i~TIRS ~E ~~ AS k K~LFN ~IMT~ ~. mw~i .... ~ - =e~=- . ~ ~ ,~ ~ ......... ~~ . _ _ . ~Z .... - ........ ~,~j or di~t, MILPARK" MATERIAL SAFETY DATA SHEET DRILLING FLUIDS A Baker Hughes company NJ[perk Dritting Ftuicls SuppLier: Nitperk Drifting FLuids 3900 Essex Lane, Suite 300 HATERIAL SAFETY DATA SHEETS Address: 3!)00 Essex Lane - Suite 300 Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8117 I. - HANUFACTURER~S INFORNATION: Product Name: ,,NIL-CEDAR PLUG CAS N~nber: NAV Code: 1216480 Chemica[ Name: ***** Chemica[ Description: HANUFACTURED FRO~! CEDAR BARK~ IS A FIBROUS LOSS OF CIRCULATION HATERIAL TO BE USED IN t~ATER SASE NIJDSo IX. - INGREDIENTS: ........................................................ 1;; ......... ..... ';; ......... 1;;;'1;; .................. NAPINAP NAP NAP INAP INAP NAPINAP NAP NAP INAP INAP NAPI NAP I NAP NAP INAP INAP NAPINAP NAP NAP INAP INAP ............ ~:;;;g~;;;~g;g'i;;;.;'~;;'~;g: ................ 1 .... ;i;,: ........ ;[;: .... I';;;-;:';;:I";,:'I'~X;;,~; .......... .............................................................. l x; .......... ......... 1;; ......... l;;"l;; .................. NAP INAP NAP INAPINAP INAP NAP INAP NAP IHAPIHAP ~NAP NAP NAP NAP I NAP I NAP I NAP NAP NAP NAP INAPIHAP INAP Ill. - PHYSICAL DATA: SoiLing Point(F): NAP Vapor Pressure(mmHg): NAP Specific Gravity: 0.6 PH: NEUTRAL Ne[ting Point(F): NAP Vapor Density(Air=l): NAP Percent VoLatiLe By Vo[un~([): NAP Freezing Point(F): NAP $o[ubitity In ~later: NAP Evaporation Rate: ( = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: BROI~# TO RED/IWOSD DUST Is: PURE-SOLID Coefficient of Water/OiL Distribution: INSOLUBLE IN t~ATER IV. - FIRE & EXPLOSION HA7J~RD DATA: F[ashpoint(F): NAP Auto Isnition TeniperatuneCF): NAP F[an~nab[e Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To Impact: NAP Extinguish Nedia - ~/ater: X C02: X Ha[oni Dry ChemicaL: X Foam: X Fog: X Hazardous Combustion Products: NAP Fire Fighting Procedures: NO UNUSUAL PROCEDURES - TREAT AS A ~ FIRE, SOAK ~/%TH I~ATER Unusa[ Fire and ExpLosion Hazards: HIGH CONCENTRATIONS OF FLAHHABLE SOLIDS IN CONFINED AREA HAY CREATE A POTENTIALLY EXPLOSIVE ATHOSPflERE. V, - REACTIVITY DATA= Chemical Stab[e: Yes: X No: If no, Under Which Conditions? NAP lncompatib[ity (Nateria[$ to Avoid): NAP Hazardous Decomposition or Byproducts: THERHAL - SNOKE~ CO, C02 Hazardous PoLymerization - Nay Occur: Ui[[ Not Occur: X Conditions to Avoid: NAP Niiperk DriLLing FLuids SUppLier: NiLpark DriLL.inN FLuids 3900 Essex Lane, Suite 300 NATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane - Suite 300 Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/&39-8000 Emergency TeLephone: 713/439-8117 Vi. - HEALTH HAZARD DATA: #iL-CEDAR PLUG Carcinogen - NTP Program: NAP Carcinegen - IARC Program: HAP Symptoms of Exposure: HAY PRODUCE IMI4EDiATE AND DELAYED SENSiTiViTY REACTION iN SUSCEPTIBLE iNDiViDUALS HAVING BREATHING DiF;ICULTiES. HAY CAUSE MiLD iRRiTATiON TO THE SKiN AND #ECHAMICAL ABRASiON iRRiTATiON TO THE EYES. MedicaL Conditions Aggravated By Exposure: HAP Emergency and First Aid Precec~ures: Eyes: FLUSH WiTH CLEAN RUNNING HATER TO REMOVE DUST/PARTiCULATES. Skin: WASH AFFECTED AREA WiTH SOAP AND HATER. SwaL Lo~: HAP Breath: REMOVE FRGI4 EXPOSURE TO FRESH AiR. DIRECT TREATMENT OF CONTROL OF SYMPTONS. Vii. - ENVIRONMENTAL PROTECTiON PROCEDURES: Spi L L Response: gORHAL CLEAN-UP PROCEDURES FOR DRY PRODUCTS - SHEEP, VACUUM, ETC. REMOVE ALL SOURCES OF iGNiTiON iF ~ILL iS ZN CONFINED OR UHVENTILATED AREA. Waste Disposal Method: SUITABLE FOR LANDFILLS. DISPOSE iN ACCORDANCE WiTH LOCAL, STATE AHD FEDERAL REGULATioNS. HandLing and Storage: KEEP AWAY FROI4 OPEN FLJU4ES. MiNI#IZE CONTACT WiTH SKIN, CLOTHING AND EYES. VentiLation: LOCAL EXHAUST CLothing: NORMAL GLoves: AS PERSONAL HEEDS DICTATE Eye: GOGGLES OR SAFETY GLASSES WiTH SiDESHIELDS Footwear: NORHAL Other: NONE Known Hazards Under 29 CFR 1910.1200 I HMIS I NFPA I Yes lyes! .......................... ~ ....... ; ................ ...................................................... J'"l HeaLth: 0 ! HeaLth~: 0 CombustibLe Liquid Skin Hazard I FtarmmbiLity: 0 I FLammabiLity: 0 FLan~abLe tlateriaL ! Eye Hazard J Reactivity: 0 I StabiLity: 0 Pyrophoric #ateriaL ! Toxic Agent ! Personal Protection: B ! SpeciaL: ExpLosive #ateria[ ! HighLy Toxic Agent ] .......................... ~ ....... * ................. UnstabLe HateriaL Sensitizer I Water Reactive Matera[ Carcinogen I DOT Hazard CLass: HAP Oxidizer Reproductive Toxin Organic Peroxide B[oocl Toxin DOT Proper Shipping Hame: SAUDUST-SHIPPED B~ WATER Corrosive Material Nervous System Toxin Compressed Gas Lung Toxin I Shipping Id. I~o. - UN: NAP NA:i gAP Irritant Liver Toxin ~ Huisance Dust X Kidney Toxin I ' Physical & HeaLth Hazard - SARA 40 CFR Part 370 (Check aLL that apply) (#OTE (*) indicates TLV for nuisance dust on[y) Fire: Sudden ReLease Of Pressure: Reactivity: i~,ediate(Acute): * DeLe, ed(Chronic): iX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contaminated Equipment: I #AV Other Precautions: , MiNiMIZE CONTACT i~,~ITH EYES, SKIN, AND CLOTHING. / ============--------===----------------=====----====--------===----========----===== ====----=========----==----==--------================---========= X.'- APPROVAL: Code: 1216480 Date Prepared: 03/08/90 Su ercedes issue Date: 08/11/89 MATERIAL SAFETY DATA SHEET 7000 Hollister· Rd., Sure 300 Eme~ency Telephone: (713) 439-890~ -~J~]rJ~C~ Houston, Texas 77040 MIL-FREE CHEMTREC: 1-800-424-9300 - NANUFACTURER'S INFORMATION: Manufacturer: BAKER HUGHES INTEG HMIS Hazard Rating Nee[th 2 Niniea[ - 0 pr_n~_~t Name: MIL-FREE and Key: FLammabiLity 2 SLight - 1 Chemical Name: FATTY ACID/OIESEL BLENO Reactivity 0 Moderate - ~eaicai Oescription: OIL-BASED SPOTTING FLUIO Persona[ Serious - Protection H Severe - Proper ShippingDescription: FLN~IABLE LIQUID, N.O.S. (CONTAINS DIESEL FUEL #2) Hazard CLass: 3, PG Iii UN Nunber: 1993 Haza~ LabeL: FLA~ABLE LIQUID DOT Response Guide: 27 Transportation Note: #A Il. - HAZARD IDENTIFICATION: ...... ................................ ..... ..... ........ * MANUFACTURER'S RECOMMENDED TLV: 100 PPM T. / Hazards Assaciateduith pr_n~_~t Use s Yes Yes Yes CombustibLe Liquid FLa~nab[e MateriaL' X Pyro~oric Material ExpLosive Material U~tab[e Material Water Reactive Material Oxidizer Organic Peroxide Corrosive Material Compressed Gas Irritant X Nuisance ParticuLate Skin Hazard Eye Hazard X Toxic Agent HighLy Toxic Agont Sensitizer Carcinogen Reproductive Toxin BLood Toxin Nervous System Toxin Lung Toxin Liver Toxin Kidney Toxin .: ', Con~u~ity Right-to-Know (SARA TitLe III Section 311-312) F'~re: X Sudden ReLease Of Pressure: Reactivity: l~nediate (Acute): X DeLayed (Chronic): X I%%. - PHYS%CAL DATA: BoiLing Point(F): 380-420 Vapor Pressure(m~lg): ND PH: ND Ne[ting Point(F): NO Vapor Donsity(Ai~l): NO Specific Gravity: 0.87 Fr~zing Point(F): ND SoLubiLity In ~ater: INSOLUBLE Percont VoLatiLe By Votu~e(X): NO Odor ThreshoLd: ND Appearance And Odor: AMBER, HYOROCARBON ~ON Evaporation Rate (ACETATE=l): >1 ~ateria[ Is: NIX-LIQUID Coefficient of gater/Oil Distribution: INSOLUBLE IN gATER IV. - FIRE & EXPLOSION HAZARD DATA: Ftashpoint(F): 128 (PMCC) Auto Ignition Temperature(F): ND FLare,abLe Limits - LFL: NO UFL: NO ExpLosion - LEL: ND UEL: NO Extingui~ Nedia - ~ater: C02: X O~ ChemicaL: X Foes: X Fog: X Hazardous Combustion Products: UP~ COMBUSTION, PROOUCT FORNS S140KE, IRRITATING FLIMES, CARB~ NONOX[DE AND CARSON DIaXIDE. Fire Fighting Pr~edures: ~AR SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS ANO FULL FIRE FIGHTING PROTECTIVE CLOTHING F~ ENCLOSED AREAS OURING A FLEE. Unus~L Fire and ExpLosionNazards: N~E REPORTED. V. - REACTIVITY DATA: ChemicaLLy Stab[e: Yes: X No: If no, Under ~lhich Conditions? AVO%D EXTRENE HEAT, SPARKS AND OPEN FLAI4ES. l~ompatib[ity (Nateria[a to Avoid): AVOID STRONG OXIDIZING AGENTS. i"~rdousOecompoaitionor Byproducts: PRODUCT ~ILL NOT READILY OECONPOSE. Hazardotm PoLyeerizetion - Nay Occur: UiLt Not Occur: X Conditions to Avoid: NA HO - Hot Determined NA - Not AppLicabLe T - Total Dust R - RespirabLe Fraction C - CeiLing Limit NIL-FREE IS A REGISTERED TRADENARK OF BA~R HUGHES ]NTEQ. Page 1 NIL-FREE VI. - HEALTH HAZARD INFORHAT]ON: Primary Exposure Route - Skin Contact: X Skin Absorption: Eye ContaCt: X lrha[JtJan: X ingestion: Pr_~-__~_t CarcJnogonJcJty - NTP: NO IARC: NO Acute Effects of Overexposure: CHENICAL PNEUHOHITIS, HUCOUS NE#BRAHE IRRITATION, DIZZINES, NAUSEA, Alii) POSSIBLY UNC~I,SCIOUSNESS. PROLONGED USE HAY CAU~ IRRITATION TO SKIN; REDNESS, TEARING AND CO#JUNCTIVITIS TO EYES. NAUSEA, VONITING, DIARRHEA, GASIORINTESTII4AL IF IHGESTED. Chronic Effects of Overexposure: LIQUID IS IRR/TATING TO EYES AND SKIN. VAP{~ IS IRRITATING TO EYES. HAY BE HAR#FUL OR FATAL IF SUALLOUEDo VII. - EHERGENCY AND FIRST AID INSTRUCTIONS: Eyes: FLUSH UITH CLEAN RUH#IHG IJATER FOR AT LEAST 15 #INUTES AND CALL A PHYSICIAN. Skin: IJASH klITH ~P A~D UATER. C~LT A PHYS~CZA~ IF RED~ESS DEAL,S. Z~gestJ~: DO gOT IHDU~ V~T~NG. DRIgK~R~ GUAgTIT~ES OF gATER AND C~TACT A PHYSICI~. l~atatJ~: REHO~ TO FRESH A~R ~ ~LT A PHYS~C;AH. VI ~ ~. - EHV~ROHHEHTAL PROTECTI~ PROCURES: SpJ [~ Res~e: ELIHIgATE S~RCE$ OF ;GNIT~. AB~B UITH ZgERT ABSORBENT ~TERIAL AND STYE ~ CL~ ~TAlgEI~S F~ DIS~L. FLUSH RESIDUE ~ITH ~RGE ~T$ OF ~TER, PRE~gT R~-OFF FR~ EgTERIHG DRA~S, SE~RS~ ~ gaste Dis~sa[ Heth~: AS A ~ASTE, TH~S PR~UCT ZS CHA~CTERISTI~LLY HAIRDOS ACCORDING TO RC~ $T~ARD$ (~GNITABILIT~'). ~STE SPILLS ~N EX~: ~LL~S SH~ BE RE~T~. ~LY g[TH L~L, STATE AND NATIONAL RE~T[~S F~ DIS~L. Ha~ti~: ' ~UT]~! PR~UCT ~Y iRRITATE EYES. SKIN ~D UPPER RESP]~TO~Y SYSTEH. 'O~R~RE TO V~S ~Y ~ NER~ SYST~ EFFECTS. DO HOT GET IN EYES, ~ SK~ ~ ~ CLOTHiHG. AVOID BREATH]HG VAPORS ~ H~STS. ~ PRIER FROTECTZ~ . Storage: STYE IN A DRY, ~LL ~NT[LATED AREA. KEEP A~? FR~ H~T, SPARKS AND F~S. ~EP ~TAINER$ CLO :~ ~EN NOT IN USE. ~ ~T REUSE EHPTY C~TAINERS PRI~ TO RE~D]T]~ING ~ DIS~SAL. IX. - ~PAT]ONAL ~TROL Respiratory Prot~tJ~: ~ ~ ~PR~D ~IC VAP~ RESPI~T~ IF RE~ EX~E LINIT$ ~ BE EX~. V~tJtatJ~: USE L~L EX~ST ~NT~LAT]~ IF REC~ENDED EX--RE LINIT$ ~Y BE EX~E Ct~thJ~: ~ L~G PROTECTI~ CLOTHING glTH APR~ AND/~ ~LLS F~ ~D~ PROTECTI~. Eyewe~r: ~ CH~I~L SP~SH ~GLES ~NILD HANDLING PR~UKT. GLoves: ~R NE~RENE ~ ~YL RUBBER GLO~S TO PROTECT SKIH. F~t~nr: JSE CH~I~L-RESIST~T Other Nensur.: EYE ~ASN ~D E~ERGEg~ SH~RS ARE ~EC~ENDED N~RBY ~ILE ~LIN~. ~ER ~T~IBAT~ CLOTHING BEF~E REUSE. ~SH AFTER ~K ~ BEF~E ~L ~ ~. X. - ~DITIONAL INF~TI~: D 1 SCLAIHER The star--ts, info~tJ~, ~ ~ta ~ovi~ in this mteriet safety ~ta ~t are ~tJev~ retie~te ~ ~ate ZNTEO a~ Jt~ res~-~ibte ~rs~t; h~ver, ~ other g~r~nt~, r~r.mtatJm, wnrr~ty or r~ iblil~ Jm e~.mN ~ J~tiN to nny ~er, r~a~t~s of retire m ntt or ~ ~rt ther~f. This i~t~ ~rr~tt.~of mr~ ~Ji[~ or of fJt~ for ~rticut~r ~e, ~ B~ker ~ IBTEG ~s~ ~ res~ibitity ~ntever for ~ice or r~ ItJ~ ~. Notht~ herein ~td ~ inte~et~ aa ~missim, i~t, or c~t to violate ~ ia, ~rs~t t~ thin ~t's or dis~s8~. Pr~r~ By: Jim R~t~ Date Pr~r~: 0~/17/~ $~r~ 1~ D=te: ~/OZ/~ ~D - Hot Oe~emi~ ~ - Not ~iJc~ie > - Greater Th~ < - Li Th~ C - ~iiI; Page MILPARK' MATERIAL SAFETY DATA'SHEET DRILLING FLUIDS A Baker Hughes company NiLpark DriLLing FLuids SuppLier: NILPARK DRILLING FLUIDS 3900 Essex Lane, Suite :500 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 HmJston, Texas 77027 Emergency TeLephone: 713/459-8000 Emergency TeLephone: 713/439-8000 [. - MANUFACTURER'S INFORMATION: Product Name: MIL LIME CAS Nt~ber: 1305-62-0 Code: 1218~00 Chemical Name: CALCIUM HYDROXIDE Chemical Description: LIME DOT Hazard CLass: NAP Shipping Id. No. - UN: NAP NA: NAP DOT Proper Shipping Name: NAP II. -INGREOIENTS: ............ ~f~:~LL..~....~L!~L~L~!L!~!?:!~?!~ ............. ~[~ ......... ~ .... 1 .... ~ .... !--~LI-~LL-~--: .......... CALCIUM HYDROXIDE NAP NAP i5 MG/.~ 1100 11]o~-62-o NAP NAP NAP INAP /NAP INAP NAP NAP NAP INAP NAP INAP NAP HAP NAP INAP NAP INAP ............ , .................................................. .......... ......... ......... .................. ............ ~:~.~_!~.~?.~.~?~!~ ..................... ~!~ ......... ~ .... I.~:~L~I..~LI.~LL.~..: .......... HAP NAP INAP NAP NAP INAP NAP NAP ~NAP NAP NAP ]NAP NAP NAP NAP INAP INAP 1NAP NAP NAP NAP INAP INAP INAP HAP NAP 1NAP 1#AP INAP 1HAP IZL. - PHYSICAL DATA: BoiLing Point(F): NAP Vapor Pressure(n~Hg): NAP Specific Gravity: 2.2-2.4 PH: 12.6 MeLting Point(F): OEHYORATESlO?6 Vapor Oensity(Air=l): NAP Percent Vo[atite By VoLtmae(X): NAP Freezing Point(F): NAP SoLubiLity In Hater: SLIGHTLY Evaporation Rate: ( = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: GREYISH ~HITE POM)ER, MUSTY Material Is: PURE-SOLID Coefficient of gater/Oi[ Distribution: NAP IV. - FIRE & EXPLOSION HAZARD DATA: FLashpoint(F): NAP Auto Ignition Temperature(F): HAP F[an~nab[e Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To Impact: NAP Extinguish Media - ~ater: C02: HaLon: Ory ChemicaL: Foam: Fog: Hazardous Combustion Products: NAP Fire Fighting Procedures: USE FIRE FIGHTING MEDIA ~HICH ZS APPROPRIATE FOR SURROUNDING FIRE. UnusaL Fire and ExpLosion Hazards: CALCIUM HYOROXIOE IS A STRONGLY ALKALINE MATERIAL gHICH IS INCOMPATIBLE ~ITH ACIDIC MATERIALS. IT FORMS SALTS ~ITH NITROPARIFFIN$ IN THE PRESENCE OF ~ATER gHICH ARE EXPLOSIVE UHEN ORIED. IT CAN CAUSE THE EXPLOSIVE OECOMPOSITION OF flALEIC ANHYDRIOE. V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under Which Conditions? NORMALLY STABLE EXCEPT IN THE PRESENCE OF MOISTURE AND ACIDS. Incompatibtity (MateriaLs to Avoid): MOISTURE AND ACIDS. HIGH ATMOSPHERIC HUMIDITY CAN AIR-SLACK LIME CAUSING IT TO CONVERT TO CARBONATE. Hazardous Oecomposition or Byproducts: NAP Hazardous PoLymerization - May Occur: ViL[ Not Occur: X Conditions to Avoid: IN PRESENCE OF ACIDS WILL PROOUCE HEAT AND GAS. Hi[park DriLLing FLuids SuppLier: MILPi~RK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Hous':on, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency Te[e hone: 713/439-8000 VI. o HEALTH HAZARO OATA: MIL LIME Carcinogen - NTP Program: NAP Carcinogen - IARC Program: NAP Symptoms of Exposure: NAP Medical Conditions Aggravated By Exposure: NAP Emergency and First Aid Procedures: Eyes: FLUSH WITH LARGE AHOUHTS OF CLEAN RUNNING WATER FOR AT LEAST FIFTEEN NINUTES Alii) CONTACT A PHY',:ICIAN IMMEOIATELY. Skin: FLUSH IMNEOIATELY WITH LARGE AMOUNTS OF WATER SwaLLow: IF PERSON IS CONSCIOUSw GIVE LARGE QUANTITIES OF WATER IMHEOIATELYw GET MEDICAL ATTENTION. Breath: IF BREATHING HAS STOPPEDw REMOVE TO FRESH AIR AND PERFORM ARTIFICIAL RESPIRATION. VII. - ENVIRONMENTAL PROTECTION PROCEDURES: SpiLL Response: KEEP SPILL AREA DRY AND* USE DRY TECHNIGUES TO COLLECT AND CONTAIN SPILLED MATERIAL. RETURN TO CONTAIN! Waste Disposal Method: DISPOSE IH ACCORDANCE WITH LOCAL~ STATE AND FEDERAL REGULATIONS. HandLing and Storage: STORE ;N DRY AREA AWAY FROM ACIDS. VIII. - SPECIAL PROTECTION INFORHATIOH: Respiratory Protection: NIOSH/MSHA APPROVEO CARTRIDGE RESPIILRTOR IF AIRBORNE CONCENTRATION EXCEEDS TLV. Venti[ation: LOCAL EXHAUST CLothing: PROTECTIVE CLOTHING GLoves: RUBBER GLOVES TO PREVENT SKIN CONTACT Eye: TIGHT FITTING SPLASH GOGGLES. Footwear: NORMAL Other: EYE PROTECTIOH, PROTECTIVE CLOTHIHG, AND RESPIRATORY PROTECTI )N I$ REQUIRED. Known Hazards Under 29 CFR 1910.1200 HMIS ........................ 1:-"-1 ......................... F[amabLe Material Eye Hazard X Reactivity: 0 StabiLity: 0 Pyrophoric Material I Toxic Agent Persona[ Protection: HI SpeciaL: I ExpLosive Material i HighLy Toxic Agent .......................... 1 ........................ 1 UnstabLe Material Ser~ftizer Water Reactive MateraL Carcinogen Oxidizer ~ Reproductive Toxin Organic Peroxide I B[o~ Toxin Corrosive Material I Nervous Systm Toxin Compressed Gas I L~mng Toxin Irritant x Liver Toxin Nuisance Dust X i(iclney Toxin ........................... ( ......................... (---t ......................................................................... Physical & HeaLth Hazard SARA 40 CFR Part 3?0 (Check ail that apply) (NOTE (*) indicates TLV f)r nuisance dust on[y) Fire: Sudden Re[ease Of Pressure: Reactivity: In~nediate(Acute): X De[aye][Chronic): IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contaminated Equipment: NAP Other Precautions: SHOWER WITH SOAP ANO WATER AFTER WORKING WITH THIS PROOUCT. X. - APPROVAL: Prepared liy: Safety Oepartment Code: 1218300 Oate Prepared: 05/01/91 Supercedes Issue Oate: 08/07/90 SAFETY DATA SHEET MATERIAL 7000 Hollister Rd., Suite 300 Emergency Telephone: (713) 439-890u .. IJ~ Houston, Texas 77040 m L-PAC CHEMTREC: '1-800-424-9300 ';- MA~JFACTURER~S INFORNATION: Manufacturer: BAKER HUGHES INTEG HMIS Hezard Rating HeaLth 0 Minimal - 0 Pr_n~__~_t Name: NIL-PAC ~nd Key: F[mmmbiLity Chemical Name: POLYANIONIC CELLULOSE Reactivity 0 Moderate - Chemical Description: FILTRATION CONTROL AGENT Personal Serious - Protection E Severe Proper Shipping Description: DRILLIHG FLUID CONPOUND, N.O.S. Hazard CLass: NOT REGULATED UN NLmber: NA Hazard LabeL: HA DOT Respo~e Guide: HA Tr~portstion Note: HA Il. - HAZARD IDENTIFICATIDN: ...... ............................... ........... / / ...... I ' .G/ T Hazards Associated uith Product Use Yes Yes !Yes Coe~uatibte Liquid FLea. abLe Material Pyrophoric Material ExpLosive Mate~iet UnstabLe Material Uster Reactive #ateria[ Oxidizer Organic Peroxide Corrosive Material C~pressed Gas Irritant Nuisance ParticuLate Skin Hazard Eye Hazard Toxic Agent HighLy Toxic Agent Sensitizer Carcinogen Reproductive Toxin BLood Toxin Nervous System Toxin Lung Toxin Liver Toxin Kidney Toxin Comm~ity Right-to-Knou (SARA TitLe ill Sectien 311-312) · .~'e: Sudclen ReLease Of Pressure: Reactivity: IIm~-clJete (Acute): X DeLayed (Chranic): III. - PHYSICAL DATA: Baiting Point(F): NA Vapor Pressure(nmHg): NA P#: MeLting Point(F): ND Vapor De,airy(Air=l): NA Specific Gravity: 1.6 Freezing Point(F): NA SoLubiLity in l~ater: MOOERATE Percent VoLatiLe By VaLise(L): 8-10 Odor ThreshoLd: NONE Appearance And Odor: OFF ~HITE, ODORLESS Eveporetien Rate ( = 1): HA Material Is: PURE-SOLID Coefficient of ldater/Oit Distribution: INSOLUBLE IN OIL IV. - FIRE & EXPLOSION HAZARD DATA: FLashpoint(F): HA Auto Ignition Temperature(F): NA FLmmmbLe Limits - LFL: NA UFL: RA ExpLosion - LEL: NA UEL: HA Extinguish Media - Water: X C02: X Dry ChemicaL: X Foam: X Fog: X Hazardous Combustion Products: UPOM COHBUSTION, OXIDES OF CARBON, ACRID S#OKE AND IRRITATING FUMES HAY FORM. Fire Fighting Procecluree: SELF CONTAINED POSITIVE PRESSURE BREATHING APPARATUS AND FULL FIRE FIGHTING PROTECTIVE CLOTHING HAY BE NEEDED FOR ENCLOSED AREAS DURING A FIRE. Unusual Fire and ExpLosion Hazards: ZF IH A FINELY DIVIDED AND SUSPENDED STATE, TREAT AS A FLAHI4ABLE DUST. V. - REACTIVITY DATA: ChemicaLLy StabLe: Yes: X No: if no, Under tdhich Conditions? NONE REPORTED. lnccm~atib[ity (MaterieLs to Avoid): AVOID STRONG OXYDIZERS AND ACIDS. i" ~'~?rdous Decomposition or Bypr_~c~__~_ts: PRODUCT gILL NOT READILY DECOMPOSE. Hazardous PoLymerization - Hay Occur: WiLL Not Occur: X Conditions to Avoid: NA lid - Not Detemined HA - Not AppLicabLe T - Total Dust R - Respirab[e Fraction C - CeiLing Limit MILoPAC IS A TRADEHARIC OF BAKER HUGHES INTEQ. Page NIL-PAC VI. - HEALTH HAZARD INFORMATION: Primary Exposure Route - Skin Contact.- Skin Absorption.' Eye Contact.' X In,station: X Ingestion: Product Carcinogenicity - NTP: NO IARC: NO Acute Effects of Overexposure-- PRODUCT FlAY MECHANICALLY IRRITATE EYES, SKIN AND UPPER RESPIRATORY SYSTEM. #UISANCE DUST EXPOSURE #AY ~JUJSE COUGH, SHORTNESS OF BREATH, AND CHEST TIGHTNESS. INGESTION NAY CAUSE STOMACH UPSET. Chronic Effects of Overexposure: OVEREXPOSURE NAY DRY SKIN AND AGGRAVATE AN EXISTING DERMATITIS OR RESPIRATORY CONDITION. VII. - EMERGENCY AND FIRST AID INSTRUCTIONS: Eyes: HOLD EYELIDS APART AND FLUSH WITH HATER FOR AT LEAST 15 MINUTES. ~J~NTACT A PHYSICIAN IF IRRITATION PERSISTS. Skin: WASH THOROUGHLY WITH SOAP AND WATER. USE CONDITIONING CREA~S TO RELIEVE IRRITATION AND EPLENISN SKIN OILS. Ingestion: GIVE FLUIDS TO RINSE MOUTH AND~THROAT AND TO DILUTE. IF UPSET OCCURS, CONTACT A PHYSIC! N. InhaLation: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. VIII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spill Response: REBAG AND SELL IF POSSIBLE. SUEEP RESIDUES INTO A SUITABLE WASTE CONTAINER. SCRUB RESIDUES FROM SPILL AREA AND FLUSH WITH WATER. k~ET PRODUCT IS VERY SLIPPERY. waste Dispose[ Method: AS A WASTE, PRODUCT IS NOT HAZARDOUS ACCORDING TO RCRA STANDARDS. DISPOSE OF IN ACCORDANCE WITH LC~AL, STATE AND FEDERAL REGULATIONS. Hm'~:lt lng: CAUTION! PRODUCT NAY IRRITATE EYES, SKIN AND RESPIRATORY TRACT. AVOID EXCESSIVE CONTACT AND gEAR ROPER PROTECTIVE EGUIPMENT STATED IN THE MSDS. Storage: STORE IN COOL DRY AREA IN SEALED BAGS OR CONTAINERS. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE ITH ADEGUATE VENTILATION. DISPOSE OF EMPTY CONTAINERS. tX. * OCCUPATIONAL CONTROL MEASURES: Respiratory Protection: gEAR AN APPROVED PARTICULATE RESPIRATOR TO MAINTAIN EXPOSURE LIMITS OR FOR ~O#FORT. Vonti{atJon: USE ADEGUATE MECHANICAL VENTILATION TO CONTROL EXPOSURES BELOW RECCINNENDED LIMITS. Clothing: gEAR LONG PROTECTIVE CLOTHING. LAUNDER CLOTHES BEFORE REUSE. Eymdear: gEAR SAFETY GLASSES OR GOGGLES WHILE HANDLING THIS PRODUCT. GLoves: gEAR GLOVES FOR CC~tFORT AND TO PREVENT IRRITATION. Foot~e&r: JSE NOdU4AL SAFETY BOOTS. Other Measures: GOCO PERSONAL HYGIENE IS ENCOURAGED TO MINIMIZE EYE AND SKIN IRRITATION. gASH AFTER HANDLING, BEFORE MEALS OR BREAKS. CLEAN EQUIPMENT OF DUST BEFORE REUSE. X. * ADDITIONAL INFORMATION: DISCLAIMER i#TEQ 8~1 its respoflsib[e personneL; houever, no other guarantee, representation, aarranty or respc~-~ibi[tty ia expressed or implied to ~ user, regar~lIess of reIiaflca on ail or arty pert thereof. This includes uarronties of merchanl:abi[ity ar of fitness for · particular purpose, arid Baker Hughes INTEO ssauneo no respoflsibi[ity ~hatever for advice Or reccxrme~btioflo moc~. Nothing contained herein should bE inteq~'etecl as pemission, indusemeflt, or c~t to viotate any [au perauant ti this i~oduct'a we, coflvr or disposaL. '.._~ Prepared By: Jim Rushing Date Prepared: 01/04/94 Super~edeo Issue Date: 08/24/92 t4o - #at Detemined NA -_Not AG~Licabte · - Greater There · - Less Than C - Ceiling Lieit Page 2 MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., Suite 300 EmergeNcy Telephone: (713) 439-8905 I~ Houston, Texas 77040 NIL-PLUG (ALL GRADES> CHEMTREC: 1-800-424-9300, - #ANUFACTURER~S INFORMATION: Manufacturer: BAKER IR/GHES INTEG HNIS Hazard Rating Health 0 Minimal - 0 pr_n~__~_t Name: MIL-PLUG CALL GRADES) a~d Key: FLammability 2 SLight - 1 Ches~icaL Name: GROUND CELLULOSIC HATERIAL Reactivity 0 Moderate - Chemical Description: GROUND PECA# SHELLS Personal Seriou~ - Protectio~ E Severe' - Proper Shipping Description: DRILLING FLU%D COMPOUND, N.O.S. Hazard CLass: NOT REGULATED UH Ncfrioer: IdA Hazard Label: RA DOT Response Guide: NA Transportation Note: gA II. -HAZARO IOENTtFICATION: Hazards Associated ~ith Product Use Yes Yes Y~ Yes Combustible Liquid FLammable #ateria[ Pyrophoric Material Explosive Material Unstable Material ga[er Reactive Material Oxidizer Organic Peroxide Corrosive Material Compressed Gas irritant Nuisance Particulate . X Skin Hazard Eye Hazard Toxic Agent Highly Toxic Agent Sensitizer Carcinogen Reproc~__~tive Toxin BLood Toxin Nervcx,m Syste~ Toxin Lung Toxin Liver Toxin Kiclney Toxin Conmdnity Right-to-Knou (SARA TitLe ill Section :~11-312) Sucldan Re[ease Of Pressure: Reactivity: lawnediate (Acute): X Delayed (Chronic): III. - PHYSICAL DATA: Boiling Point(F): NA Vapor Pressure(nm4g): NA PH: NEUTRAL Ne[ting Point(F): )IA Vapor Oensity(Air=l): HA Specific Gravity: 1.2 Freezing Point,F): )IA Solubility In tJater: I)ISOLUBLE Percent Volatile By Vol[me(%): IdA Odor Threshold: NONE Appearance And Odor: TAN TO LIGHT BRO~N, ODORLESS Evaporation Rate ( = 1): NA Material Is: PURE-PO~ER Coefficient of k/ater/Oi[ Distribution: INSOLUBLE IH ~ATER IV. - FIEE & EXPLOSION HAZARD DATA: Ftashpoint(F): NA Auto Ignition Temperature(F): F[araneb[e Limits - LFL: HA UFL: NA Explosion - LEL: MA UEL: HA Extinguish Media - Uater: X C02: X Dry Chemical: X Foam: X Fog: X Hazardous Combustion Products: UPON COMBUSTION, OXIOES OF CARBON MAY FORM PRODUCING TOXIC, ACRIO FUMES. Fire Fighting Procedures: IN CASE OF FIRE, GENTLY FLC~O IdITH I.'ATER FOG, USING CARE NOT TO SUSPEND DUSTS. Unusual Fire and Explosion Hazards: ' ' ' ,.,:,'."' . AT VERY HIGH DUST CONCENTRATIONS, PRODUCT MAY FORN EXPLOSIVE DUST-AIR #IXTURES. V. - REACTIVITY DATA: ChemicaLLy Stable: Ye~: X No: If no, Under k~ich Co~cJitions? VERY DUSTY CONDITIONS. lncog~oatibtity (#ateriets to Avoid): STRONG OXIDIZERS. Ha~ar~c~m Oecemposition or Byprc~__~_ts: PRODUCT UILL HOT READILY DECOMPOSE. rdous Polymerization - Ney Occur: gilt Not Occur: X Conditions to Avoid: HA NO - Not Determined HA - Not Applicable T - Tote[ Dust R - Respirmb[e Fraction C - Ceiling Limit NIL-PLUG IS A REGISTERED TRADEI4ARK OF BAKER HUGHES INTEQ. Page 1 MIL-PLUG (ALL GRADES) Primary Exposure Route - Skin Contact: Skin Absorption: Eye Contact: X InhaJation: X Ingestion: Product Carcinogenicity - NTP: HO IARC: NO Acute Effects of Overexposure: PRDOUCT DUST NAY CAUSE NECHA#JCAL IRRITATION TO EYES, SKIN AND UPPER RESPIRATORY TRACT~ INHALATION NAY CAUSE SHORTNESS OF BREATH, COUGH OR CHEST TIGHTNESS. Chronic Effects of OverexP°aure:' SONE PARTICULATE DUSTS NAY CAUSE ALLERGIC SENSITIZATION OF SONE ~NDIVIDUALS, CHARACTERIZED EITHER BY BREATHING DISTRESS OR TOPICAL SKIN IRRITATION SYNPTOMS. VII. - ENERGENCY AND FIRST AID INSTRUCTIONS: Eyes: HOLD EYELIDS APART A~D FLUSH EYES WITH WATER FOR AT LEAST 15 HI#UTES. CONSULT A PHYSICIA# IF IRRITATION PERSISTS. Skin: WASH THOROUGHLY WITH NILD SOAP AND WATER. APPLY MEOICATED CREANS TO RELIEVE IRRITATION AND REPLE#JSH SKIN OILS. Ingestion: GIVE FLUIDS TO RINSE NOUTN AND'THROAT IRRITATION ANO TO 0ILUTE. CONSULT A PHYSICIAN IF ADVERSE SYMPTOI4S DEVELOP. lflhatation: HOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS DIFFICULT. VIII. - ENVIRONMENTAL PROTECTION PRDCEOURES: Spi t t Response: WEAR PROPER PROTECTIVE EQUIPNENT (SECTION IX). ELIMINATE IGNITION SOURCES IN OUSTY COPlOITIONS. RECOVER SPILLEO NATERIAL TO THE ORiGiNAL CONTAINER FOR SALE [F POSSIBLE Oii TO A SUITABLE WASTE CONTAINER. NINIMIZE DUSTING DURING CLEANUP. FLUSH RESIDUE. Waste Disposal Method: tPRODUCT [S NOT HAZARDOUS ACCOROING TO RCRA CRITERIA OR LISTING AS SUPPLIED. OJSPOSE OF ACCOROJNG TO LOCAL, STATE ANO NATIONA' GLILATJONS DEALING WITH A NONHAZARDOUS WASTE PRODUCT. ting: CAUTJONI NAY CAUSE NECHANICAL EYE~ SKiN AMD RESPIRATORY iRRiTATION. AVOID CONTACT ANO WEAR PROPER PROTECTIVE EOUJPNENT. AVOID BREATHING DUST. Storage: KEEP DUSTS TO A #ININL~I. KEEP CONTAINER CLOSED WHEN NOT IH USE. USE WiTH ADEQUATE VENTILATION. DISCARD ENPTY CONTAINERS. IX. - OCCUPATIONAL CONTROL MEASURES: Respiratory Protection: WEAR AN APPROVED PARTICULATE RESPIRATOR IF EXPOSURE LINITS ARE EXCEEDED OR FOR CONFORT. vefltitation: SUPPLY NECHANICAL VENTILATION NEEDED TO MAINTAIN SAFE EXPOSURES TO NUISANCE PARTICULATES (1§ CLothing: ~ LONG PROTECTIVE CLOTHING WITH AN APRON FOR ADOEO PROTECT[ON. EyeMear: I~cAR CHENICAL SAFETY GOGGLES OR GLASSES ~[TH S[DEGUAROS. INSURE A PROPER FIT. GLoves: WEAR GLOVES TO PREVENT NECHANICAL IRRITATION. FootMear: I~EAR HORNAL SAFETY BOOTS. Other Measures: CLEAN CLOTHES, APRONS, GLOVES AND FACE PROTECTION OF DUST BEFORE REUSE. USE APPROPRIATE CLEANSERS TO WASH PRODUCT OFF SKIN AND INCORPORATE CONDITIONERS TO PROTECT SKIN. X .... 'ADOIT[ONAL INFORNATION: 01SCLAIMER The statements, information, and data provided in this material safety data sheet are believed reliable and accurate by Baker Hughes INTEQ and its respen~ibLe personnel; however, no other guarantee, representation, ~arranty or responsibility is expressed or implied to any user, regardless of reliance on ali or any part thereof. This includes ~arranties of merchantability or of fitness for a particular purpose, and Baker Hughes INTEQ assu~es no responsibility ~natever for advice or recc~tiona made. Nothing ce~tairecl n should be interpreted aa permission, inducement, or corot to violate any tau persu~nt to this procluct's use, corw, Prepared By: dim Rushing Oats Prepared: O/~/l~/g& Supercecle~ Issue Date: 05101/91 ND - Not Determined NAo Not Applicable · - Greater Then · - Less Than C - Ceiling Limit Page MATERIAL SAFETY DATA SHEET 7000 Hoilister Rd., Sure 300 Emergency Telephone: ~13) 439-890u IArr~ Hou~on, Texas 77040 NIL-SEAL (ALL GRADES) CHEMTREC: 1-800-424-9300 Nanufacturer: BAKER HUGHES INTEQ HNIS Hazard Rati~ HeaLth 0 Nini~L - 0 Pr_~k_~t Name: NiL-SEAL (ALL GRADES) end [ay: FLmmuabiLi~' 1 SLight - 1 ChmicaL Name: DRILLING FLUID LOST CIR~LATI~ HATERIAL Reactivity 0 Noderste - Chemical Description: NUT NULLS, IdOCO FIBER, ~LL~HANE BLEND Personal Serious - Proration E Severe - Proof Shippi~ Description: DRILLING FLUID C~P~ND, N.O.S. Hazard CLass: NOT RE~LATED UN N~nber: NA Hazard La.L: NA DOT R~lX~se Guide: NA Tra~rtation Note: NA Hazards Associat~ with Pr_~d-_~t Use Yes Yes Yes Yes C~mbustibLe Liquid FLammabLe Material Pyro~oric Material ExpLosive Material U~tab[e Material ~ater Reactive Nateria[ Oxidizer Organic Per~ide Corrosive Naterisi Compres$~ Gas Irritant Nuisance ParticuLate X Skin Hazard Eye Haza~ X Toxic Ag~t HighLy T~ic Agent Sensitizer Carci~gon Reproductive Toxin BLood T~in #ervous S~tem Toxin L~g Toxin Liver Toxin Kidney Toxin Cmummity Right-to-K~ (SA~ TitLe lli $~tion Sudden ReLease Of Pr~sure: Reactivity: Innediate (Acute): X OeLayed(~r~flic): Ill. - PHYSI~L DATA: 8oiLi~ Point(F): NA Vapor Pr~sure(n~Hg): NA PH: ?.0 MaLting Point(F): NA Vapor Dermity(Air=l): HA Specific Gravity: 0.~6 Fr~zi~ Point(F): NA SoLubiLity In Mater: INSOLUBLE Percent VoLatiLe By VoLume([): NA ~or ThreshoLd: ND AppearaflceAfldOdor: BRO~N, IdOi~OY ~ EvaporationRate ( -1): NA Material Is: NIX-~LID Coefficient of ~ater/Oit Distri~tion: ND as' FIRE & EXPLOSI~ ~ DATA: FlammabLe Limits - LFL: HA UFL= NA ExpLosion - LEL: NA ~L: Extinguish #~ia- ~ater: X C~: X Dry ChemicaL: X Foam: Fog: X Hazardous CembustionProducts: UPON C~BUSTIO#, PR~UCT HAY F~N ~IDES OF ~RBON, ~OKE AND ACRID, IRRITATING FUHES. Fire Fighting Procedures: ~AR NORHAL PROTECTI~ CLOTHING AND POSITI~ PRES~RE SELF-CONTAINED BREATHING APPA~TUS IN EN£LOS~ AREAS DIJIIING A FIRE. ~NTLY F LOCO FIRE ~ITH ~TER USING C~qE NOT TO ~SPE~ DUSTS. ~nus~L Fire and ExpLosion Hazards: DUSTS HAY F~N EXPLOSI~ DUST-AIR NIXT~E$ IN A FINELY DIVIDED AND ~SPE~ STATE. V. - REACTIVITY DATA: ChemicaLLy StabLe: Yes: X No: If no, Under ~Jch CotldjtJons? AVOID ~R¥ DUSTY CO~DITI~S. I~ampatJbiJty (Materia[a to Avoid): NME REPO~TED. trdousOeca~posJtionor Byproducts: PR~UCT UILL NOT REalLY DEC.POSE. PoLymerization - May Occur: ~iLI Not Occur: X Conditions to Avoid: HA HD - Not Detemined ~ - Not AppLicabLe T - Total D~t R - R~pirab[e Fraction C - CeiLJngLimJt NiL-SEAL IS A REGISTER~ TRADENARK OF BA~R HUGHES INTEG. Page 1 MIL-SEAL (ALL GRADES) Vi. - HEALTH HAZARD INFORMATION: Primary Exposure Route - Skin Contact: Skin A~orption: Eye Contact: X %~latatJon: X %ngestion: Prc~t Carcinogonicity - NTP: NO XARC: NO Acute Effects of {~erexposure: PROOUCT MAY CAUSE HECHANICAL IRRITATION TO EYES, SKIN AND UPPER RESPIRATORY SYSTEH. INHALATION MA~ CAUSE COUGH, SHORTNESS OF BREATH OR CHEST TIGHTNESS. PROOUCT DUSTS MAY CAUSE AN ALLERGIC SKiN OR RESPIRATORY REACTION IN SUI;E INDIVIDUALS. Chronic Effects of ~erexposure: PROOUCT MAY AGGRAVATE AN EX%STING DERMATITIS OR ALLERGIC RESPIRATORY CONDITION. VII. - EMERGENCY AND FIRST AID INSTRUCTIONS: Eyes: HOLD EYELIDS APART AND FLUSH WITH WATER FOR AT LEAST 15 HINUTES. CONSULT A PHYSICIAN IF IRRITATION DEVELOPS OR PERSISTS. Skin: WASH THOROUGHLY WITH SOAP AND WATER. APPLY HEDICATED CREARS TO RELIEVE IRRITATION AND REPLENISH SKIN OILS. In~estion: GIVE .FLUIDS TO RINSE NOUTH AND'THROAT AND TO DILUTE. CONSULT A PHYSICIAN IF IRRITATION ERSISTS. lnttatation: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING ZS DIF ICULT, GIVE OXYGEN. VIII. - ENVIRONHENTAL PROTECTION PROCEDURES: SpiLL Response: gEAR PROPER PROTECTIVE EQUIPMENT. CONTAIN THE SPILL. REBAG ANO SELL iF POSSIBLE. SgEEP RESIOUE IN! A SUITABLE CONTAINER FOR OISPO SAL. KEEP OUT OF SEgERS ANO gATERUAYS. Waste Disposal Method: f ~ PROOUCT IS NOT HAZAROOUS ACCORDING TO RCRA CRITERIA OR LISTING AS SUPPLIEO. OISPOSE OF IN ACCOROA# WITH LOCAL, STATE ANO REGULATIONS. HandLing: CAUTION! PROOUCT MAY IRRITATE EYES, SKIN AND UPPER RESPIRATORY SYSTEM. O0 NOT GET IN EYES, ON SKIN OR (gl CLOTHING. AVOID BREATHING DUSTS. WEAR PROPER PROTECTIVE EQUIPHENT STATED IN THE HSOS. Storage: STORE IN A gELL VENTILATED DRY AREA. KEEP AgAY FROM HEAT A#D OPEN FLAMES. KEEP DUSTS TO A MININUN. KEEP CONTAINER CLOSED WNEN NOT IN USE. IX. - OCCUPATIONAL CONTROL MEASURES: Respiratory Protection: gEAR AN APPROVED PARTICULATE RESPIRATOR IF RECOIq4ENDED EXPOSURE LIMITS HAY IE EXCEEDED. VontiLatio~: USE MECHANICAL OR LOCAL EXHAUST VENTILATION TO kEEP EXPOSURES BELO~ RECC~MEIDED LIMITS. CLothing: ~ LONG PROTECTIVE CLOTHING WiTH AN APRON TO CATCH DUST. Eye,ear: ~ CHEMICAL SAFETY GOGGLES OR GLASSES WITH SIDESUARO$. iNSURE A PROPER Fi FOR BEST PROTECTION. GLoves: WEAR GLOVES TO PREVENT SKIN IRRITATION. Foot,ear: ~AR NORMAL SAFETY BOOTS. Other Heesures: GOOO PERSONAL HYGIENE IS ENCOURAGED TO NINIHIZE EYE AND SKIN IRRITATION. LAUNDER CLOTHING BEFORE REUSE. WASH AFTER HANDLING AND BEFONE HEALS ON BREA~S. X. - ADDITIONAL INFOIU4ATION: DISCLAIHER The statements, informtJon, and data provided in this material safety data sheet are believed reLi&)~e end accurate by Baker Hughes INTEQ and its responsible personneL; however, no other guarantee, representation, ~arrsnty or res~a~iJbJ[Jty ia expressed or implied to any user, regardless of reliance on a~l or any part thereof. This includes ~arrantJee of merchan:abiLity or of fitnesa for · particular purpose, ~ Baker Hughes I#TEQ assunes no respansibiLity ~hatever for advice or recannonbtiem mede. Nothing ¢ontair~'~a herein should be interpreted aa pamissim, inducement, or cendenement to violate any La~ perauant t thia preduct,a use, conve~ or disposaL. Prepared By: dim Rushing Dat~ Prepared: 03/21/9~ Supercedes Issue Date: 05/01/91 ND - Not Determined NA - Not AppLicabLe > - Greater Then · - LeSa Then C - Ceiling Limit Page 2 ~?~AIILP~i/L'K" MATER IAL SAFETY DATA SHEET IJI?ILLING FLU/US A Baker Hughes company Mi[park DriLLing FLuids Supplier: MILPARX DRILLING FLUIDS 3900 Essex Lane, Suite 300 NATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/&39-8000 Emergency Te[ephone: 713/439-8000 I. - MANUFACTURER'S INFORMATION= Product Mane: MIL-TEHP CAS Nmber: 68037-40-1 Code: 1218500 Chemica[ Hame: SULFONATED STYRENE/MALEIC ANHYDRIDE Chemical Description: A LCN MOLECULAR WEIGHT CO-POLYMER DEFLOCCULANT. DOT Hazard Crass: NAP Shipping Id. No. - UN: NAt DOT Proper Shipping Name: II. - INGREOIENTS: ............ fff~:~?~.~L!?~L~.~L!~!?:!~!~ ........ 1 .... ~!~ ......... ~ ......... ~: .... 1--~:-1-~LL-~--: .......... NUISANCE DUST NAP 10 MG/M3 NAP I<1 NAP HAP NAP :NAP NAP I NAP NAP NAP NAP NAP NAP IMAP INAP NAP NAP NAP NAP INAP INAP .............................................................. .......... .......... ......... .................. ............ ~:~?~-~-!~-~?-~-~!: ................ 1 .... ~!~ ........ ~: ...... ~Lff:I--~:-I-~LL-'ff--: .......... NAP NAP !NAP NONE NAP NAP NAP NAP #AP NAP HAP NAP HAP NAP NAP NAP NAP NAP NAP NAP NAP NAP NAP NAP HAP INAP NAP NAP INAP INAP III. ' PHYSICAL DATA: BoiLing Point(F): NAP Vapor Pressure(mmHg): NAP Specific Gravity: .940 PH: 7 a 1~ SO He[ting Point(F): NAP Vapor Density(Air=l): NAP Percent VotatiLe By Vo[ume(~): 10 Freezing Point(F): NAP SoLubitity In ~ater: GREATLY Evaporation Rate: ( = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: TAN/DOORLESS I~ER Hateria[ Is: PURE-SOLID Coefficient of ~ater/Oi[ Distribution: PARTIALLY SOLUBLE IN ~ATER IV. - FIRE & EXPLOSION HAZARD DATA: F[ashpoint(F): HAP Auto Ignition Temperature(F): NAP FLar~nabLe Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To Impact: NAP Extinguish Media -gater: X C02: X Haton: Dry ChemicaL: X Foam: X Fog: Hazardous Combustion Products: THERMAL DECOMPOSITION COULD RESULT IN THE FORMATION OF OXIDES OF CARBON ANO SULFUR. Fire Fighting Procedures: WEAR SELF CONTAINEO POSITIVE PRESSURE BREATHI#G APPARATUS AHD FULL FIRE FIGHTING PROTECTIVE CLOTHING FOR ENCLOSED AREA. UnusaL Fire and ExpLosion Hazards: NAP V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under ~hich Conditions? NAP Incc~tibLity (MateriaLs to Avoid): STRONG OXIDIZING AGENTS ~azardous Oecomposition or Byproducts: SODIUM OXIDES~ SULFUR OXIDES MAY BE RELEASED. THERMAL DECOMPOSITION: CARBON MONOXIDE, CARBON OIOXIOE Hazardous PoLymerization - Nay Occur: Will Not Occur: X Conditions to Avoid: NAP MiLpark DriLLing FLuids SuppLier: MiL ARK DRiLLiNG FLUIDS 3900 Essex Lane, Suite 300 HATERZAL SAFETY DATA SHEETS Address: 390ll Essex Lane Houston, Texas 77027 Hou,~ton,~ Texas 77027 Emergency TeLephone: 71"4/439-8000 Emergency Tet~ ~hone: 713/439-8000 Vi. - HEALTH HAZARD DATA: MIL-TEHP Carcinogen - HTP Program: HO Carcinogen - IARC Program: NO Symptoms of Exposure: REPEATED AND PROLONGED CONTACT IdiTH DUST HAY BE iRRiTATiNG TO EYES, SKiN AND RESPIRATORY TRACT. Medical Conditions Aggravated By Exposure: Emergency and First Aid Procedures: Eyes: FLUSH JdiTH CLEAN RUNNING WATER FOR AT LEAST 15 HINUTES AND GET HEDICAL ATTENTION iF IRRITATIOI DEVELOPS/PERSISTS. Skin: UASH AFFECTED AREA ~dITH SOAP AND ~ATER. SwaLLow: INDUCE VONITIHG ONLY IF VICTIH IS ALERT. GET PRONPT HEDICAL ATTEHTION. DO HOT ATTEMPT TO GIVE ~NYTHiNG BY HOUTH TO A DROUS Y OR UNCONSCIOUS PERSON. Breath: REHOVE TO FRESH AIR. GET HEDICAL ATTENTION iF IRRITATION PERSISTS. Vii. - EHVIRON#ENTAL PROTECTION PROCEDURES: Spi L i Response: NORHAL CLEAN-UP PROCEDURES FOR DRY PRODUCTS - b~dEEP~ VACtJUH, ETC. REHOVE ALL SOURCES OF IGNiTiON IF ~ILL IS ZN A CONFINED OR U#VENTZ LATED AREA. $~l~te Disposal Method: DISPOSE IN ACCORDAHCE $dITH LOCAL, STATE AND FEDERAL REGULATIONS. HandLing and Storage: AVOID HiGH DUST CONCENTRATIONS. I(EEP A~IAY FR(~q SPARKS, HEAT, AND OPEN FLAJqES. · VTi[. - SPECIAL PROTECTION INFORI4ATioN: VentiLation: LOCAL EXHAUST CLothing: NORHAL GLoves: AS NEEDED FOR COHFORT - CHEHICAL RESISTANT RECON~ENDED Eye: SAFETY GLASSES Foct~ear: NORHAL Other: AS NEEDED Under 29 CFR 1910.1200 1 ........... ............ l ......... ............ ....................................................... HeaLth: 0 I HeaLth: 0 CombustibLe Liquid I Skin Hazard FLmrmabJLJty: 0 I FLammabiLity: 0 FLa~aabLe #ateriaL i Eye Hazard Reactivity: 0 I StabiLity: 0 Explosive NateriaL HighLy Toxic Agent ...................... UnstabLe Nateriai Sensi tizer ~ater Reactive Matera~ Carcinogen Oxidizer Reproductive Toxin Organic Peroxide BLood Toxin Corrosive Material Nervous System Toxin Campressed Gas Lung Toxin Irritant Liver Toxin Nuisance Dust X I(ideey Toxin ........................... ~ ......................... ~---~ ......................................................................... Physical & HeaLth Hazard - SARA 40 CFR Part 3?0 (Check aLL that apply) (NOTE (*) indicates TLV For nuisance dust only) Fire: Sudden ReLease Of Pressure: Reactivity: [n~iate(Acute): ~ DeLa' ~(Chrenic): iX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Centaminated Equipment: NORHAL CLEAN-UP, SOAP & ~ATER OR VACULLq Other Precautions: MI#I#~ZE CONTACT ~JITH EYES; SKIN, AND CLOTHING. UEAR #IOSH/HSNA APPROVED DUST RESPIRATOR FOR PROLONGE; PERiODS OF EXPOSURE WHERE X. - APPROVAL: Prepared By: Safety Department Code: 1218500 Date Prepared: 05/01/91 Sup MILPARK" MATERIAL SAFETY DATA'SHEET DRILLING FLUII)S A Baker Hughes company Hi[park DriLLing FLuids SuppLier: HILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 HATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 I. - MANUFACTURER'S INFORMATION: Product Name: MILPARKMO CAS #t~ber: NAV Code: 1218310 Chemical Name: DRILLING MUD SURFACTANT (OETERGENT) Chemical Description: AGUEOUS SOLUTION OF NON%ONIC ALCOHOL ETHOXYLATED DETERGENT DOT Hazard CLass: NAP Shipping Id. NO. - UN: NA: DOT Proper Shipping Name: II. - INGREDIENTS: ............ ~r~u~.~e~.!e~c.~.fr~.!~!~:!~!~ ........ 1 .... ~!~: ......... :~: .... 1 .... ~ .... l--~:-l-~C~-~ ......... NAP NAP NAP INAP INAP INAP NAP HAP NAP INAP INAP INAP NAP INAPNAPINAPINAP INAP NAP INAPNAPINAPINAP INAP ~: .............................................................. 1~:: .......... ~: ......... 1~: ......... 1~::--1~: ................. NAP NAP NAP NAP NAP INAP NAP NAP NAP NAP NAP INAP NAP INAP tNAP INAP INAP INAP III. - PHYSICAL DATA: BoiLing Point(F): 212 Vapor Pressure(mmHg): EOUAL TO gATER Specific Gravity: 1.04 PH: 10 - 11 MeLting Point(F): NAP Vapor Density(Air=l): EOUAL TO VATER Percent VoLatiLe By VoLume(~): NAP Freezing Point(F): 32 SoLubiLity In Vater: GREATLY Evaporation Rate: ( = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: LIGHT BLUE Material Is: MIX-LIOUID Coefficient of gater/Oi[ Distribution: NAP IV. - FIRE & EXPLOSION HAZARD DATA: F[ashpoint(F): >200 Auto Ignition Temperature(F): NAP FLammabLe Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NON-FLAMMABLE Sensitivity To Impact: NAP Extinguish Media - ~ater: X C02: X Haton: Dry ChemicaL: X Foam: Fog: Hazardous Combustion Products: NON-COMBUSTIBLE Fire Fighting Procedures: ~EAR SELF-CONTAINED POSITIVE PRESSURE BREATHING APPARATUS AND FULL FIRE FIGHTING PROTECTIVE CLOTHING FOR ENCLOSED SPACES. Unusa[ Fire and ExpLosion Hazards: NAP V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under ghich Conditions? NAP Incompatib[ity (MateriaLs to Avoid): STONG OXIDIZING AGENTS. Hazardous Decomposition or Byproducts: PROOUT IS NON-FLAMMABLE UNTIL ALL ~ATER BOILS AVAY. RES%DUE MAYBE COMBUSTIBLE. Hazardous PoLymerization - May Occur: ~i[i Not Occur: X Conditions to Avoid: NAP Hitpark '~ritting Fluids Supplier: MIL; IRK DRILLING FLUIDS 3900 Essex Lane, Suite 300 HATERIAL SAFETY DATA SHEETS Address: 390( Essex Lane Houston, Texas 77027 Hou.~ :on, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TaLE ~one: 713/439-8000 VI. - HEALTH HAZARD DATA: HILPARK HI) Carcinogen - NTP Program: NAP = = Carcinogen - IARC Program: NAP = Symptoms of Exposure: HAY CAUSE OAHAGE TO RESPIRATORY TRACT, ANO MAY CAUSE IRRITATION TO SKIN AND EYES. HedicaL Conditiens Aggravated By Exposure: NAP Emergency and First Aid Procedures: Eyes: FLUSH WITH CLEAN RUNNING WATER FOR AT LEAST 15 HINUTES AND CONTACT A PHYSICIAN. Skin: gASH WITH SOAP AND WATER. S~aLLou: CONTACT A PHYSICIAN. Breath: REHOVE TO FRESH AIR. VII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spi L l Response: ABSORB WITH INERT ABSORBENT HATERIAL AND STORE IN CLOSED CONTAINERS FOR DISPOSAL. PREVENT MATERIAL FR~)N ENTERING DRAINS, SEUERS, OR STREAHS. Waste Disposal Hethed: DISPOSE IN ACCORDANCE glTg LOCAL, STATE AND FEDERAL REGULATIONS. HandLing and Storage: KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT REUSE CONTAINER. VIII. - SPECIAL PROTECTION INFORHATION: Respiratory Protection= NIOSH/#SNA APPROVED TO PROTECT FROH HIST. Ventilation: LOCAL EXHAUST Clothing: NORHAL GLoves: RUBBER, NEOPRENE, OR BUTYL-RUBBER. Eye: CHEMICAL SPLASH GOGGLES OR FACESH]ELD. Foot#ear: NORMAL Other: BOOTS, CLOTHING, APRON AS REQUIRED. Known Hazards Under 29 CFR 1910.1200 I HMIS ] NFPA I |Yes/ /Yest .......................... t .................. ........................ t---t ......................... t---I HeaLth: 1 / HeaLth: 1 / Combustib,e Liquid I Skin Hazard X FLammabiLity: 0 I FLammabiLity: 0 F[mmmb[e Material Eye Hazard X Reactivity: 0 StabiLity: 0 Pyrophoric Material [ Toxic Agent Persona[ Protection: O [ Special: I UnstabLe Material Sensitizer Water Reactive HateraL Carcinogen Oxidizer I Reproductive Toxin Organic Peroxide I Blood Toxin Corrosive Hateria[ I Nervous System Toxin Compressed Gas I Lung Toxin Irritant I Liver Toxin #uisance Oust I Kidney Toxin ........................ t---~ ......................... t .............................................................................. Physical & HeaLth Hazard - SARA 40 CFR Part 370 (Check aL[ that apply) (NOTE (*) indicates TLV for nuisance dust only) Fire: Sudden ReLease Of Pressure: Reactivity: In~ediate(Acute): X OeLayed(Chronic): IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Haintenance Of Contaminated Equipment: gAV Other Precautions: AVOID CONTACT WITH EYES, SKIN ANO CLOTH%NG. AVOIO BREATHING VAPORS. MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., SuRe 300 Emergency Telephone: (713) 439-8900 - IJ~/~l~ Houston, Texas 77040 MILGEL NT CHEMTREC: 1-800-424-9300 .. - HANUFACTURER'S INFORMATION: Manufacturer: BAKER HUGHES INTEQ H#]S Hazard Rating Health 0 Mini~aL - 0 Product Name: NILGEL NT and Key: Flae~,ebi[ity 0 Slight - 1 Chemical Name: BENTONITE, UNTREATED Reactivity 0 Moderate - 2 Chemical Oescription: NATURALLY OCCURRING MINERAL Personal Serious - 3 Protection E Severe - ~ Proper Shipping Oescription: DRILLING FLUIO COMPOUNO, N.O.S. Hazard Class: HOT REGULATED UN NUTioer: NA Hazard Label: NA DOT Response Guide: NA Transportation Note: NA Il. - HAZARD IDENTIFICATION: SILICA, CRYSTALLINE QUARTZ /0.1MG/~ R lO.1MG/~ R /2-15 J1~08-60-? INA SILICA, CRYSTALLINE CRISTOBALITE /O.~ ~O/~ R 10.05 MG/~3 R 12-12 /14~6~-~6-1 INA SILICA, CRYSTALLINE TRIDYNITE /0.05 MG/~ e 10.05 MG/K] R /<2.0 /15468-32-3 INA Hazards Associatedwith Product Use Yes Yes Yes Yes Combustible Liquid FLea.able Nateria[ Pyrophoric Material Explosive Material Unstable Material ga[er Reactive Material Oxidizer Organic Peroxide Corrosive Material Cc~ressed Gas Irritant Nuisance Particulate Skin Hazard Eye Hazard Toxic Agent Nighly Toxic Agent Sensitizer Carcinogen Repr_~9-~tJve Toxin B[oedToxin Nervous Systex Toxin Lung Toxin X Liver Toxin KJc~ey Toxin ~ Comaunity Right-to-Know (SARA TitLe III Sactien311-312) *F'~e: Sudden Release Of Pressure: Reactivity: laa~<liate (Acute): X Delayed (Chrenic): X Ill. - PHYSICAL DATA: Boiling Point(F): NA Vapor Pressure(n~g): NA PH: NEUTRAL Mettipg Point(F): RA Vapor Density(Air=l): NA Specific Gravity: 2.6 Freezing Point(F): NA Solubility In ga[er: INSOLUBLE Percent Volatile By VoL~ae([): NA Odor ThreshoLd: NA Appearance And Odor: TAN, ODORLESS Evaporation Rate ( = 1): NA Material Is: PURE-PO~ER Coefficient of Water/Oil Distribution: INSOLUBLE IN OIL IV. - FIRE & EXPLOSION HAZARD OATA: FLashpoint(F): RA Auto Ignition Temperature(F): NA FLat, able Limits - LFL: NA UFL: NA Exp[o~ien - LEL: NA UEL: NA Extinguish Media - Water: C02: Dry Chemical: Foam: Fog: Hazardous Combustio~ Products: NONCOMBUSTIBLE. MATERIAL ~ PRODUCE SODILIN OXIDE AND CARBON DIOXIDE AT DECOMPOSITION TEMPERATURES. Fire Fighting Procedures: COMPATIBLE WITH AGENTS USED ,TO EXTINGUISH SURROUNDING FIRES. KAY BE USEO AS INERT MATERIAL FOR SOME CLEANUP APPLICATIONS. Unusual Fire and ExpLosionHazarcls: UATER-gET PROOUCTNAY BE SLIPPERY. V. - REACTIVITY DATA: Chemically Stable: Yes: X No: If no, Uncler ~hich Conditions? NONE REPORTEO. IncompatibLity (Ns[arista to Avoid): NONE REPORTEO. :{',rdousDeconlooeitSenor Byproducts: PRODUCT gill NOT READILY DECOMPOSE. Hazardotm Polymerization - Nay Occur: gill Not Occur: X Conditions to Avoid: PRODUCT gill NOT POLYlqERIZE. #O - Not Determined KA %Not Applicable T - Total Dust R - Reapirable Fraction C - Ceiling Lieit MILGEL NT IS A REGISTERED TRADENARK OF BAKER HUGHES INTEQ. Psge 1 N] LGEL NT *~- VI. - H~LTH HA~ I~F~TI~: PriM~ E~sure E~te - Skin C~toct: Skin A~orpti~: Eye C~t~t: I~aLoti~: X l~esti~: Pr~t Carci~icity - NTP: NO IARC: NO Acute Eff~ts of ~erex~sure: IHHALATIOH ~Y RE~LT IH DISTRESS IH BREATHIHG, C~GHIHG, AND ]RRiTATi~ OF THE UPPER RESPI~T~Y SYSTEH. ~]N AND EYE ~TACT ~USE HECHAHi~L Chr~ic Effects of ~erex~sure: UNPROTECTED PROL~GED ]HHA~T{~ OF DUST COHTA]H]HG CRYSTALLINE SILIU ~Y UUSE PER~NEHT LUHG AH LI~R INJURY. LiHITED EWDEHCE (]ARC) SH~ T~T THE ]HH~TI~ OF CRYSTALLINE SiL[~ CAUSES ~HCER IH H~HS. Vll. - EHERGEHCY AND FIRST AiD INSTRUCTIONS: Eye: HOLD EYEL]DS AP~T AND FLUSH ~]TH ~ATER F~ AT L~ST 15 H]HUTES. ~H~LT A PHYS]CiAH iF ]RRITAT]~ PERSISTS. Skin: UASH TH~GHLY ~]TH HILB ~ AND ~ATER. APPLY HEDI~T~ CRE~S TO REL]~ ]RRiTATI~ ~D REPLEHISH SgIH O]LS. [~esti~: G]~ FLUIDS TO RIH~ ~TH ARD, THR~T IRR]TAT]~ A~ TO DILUTE. ~LT A PHYSIC]AR IF }~R~ $YHPT~S DE~L~. ]~eLatim: ~ TO FRESH AiR. G]~ ARTiFICiAL RESPI~T]~ IF HOT 8E~THIHG. G]~ OXYGEH IF BREATH] ]S DIFF]~LT. Viii. - EHVIROHHEHTAL PROTECT]~ PROCEDURES: SpiLl Ees~e: ~ PE~ER PEOTECT]~ E~]~EHT (SECT]~ iX). RECUR SPILLED ~TER]AL TO THE ~IGIH~L ~TAIHEE r~ ~LE iF ~SlaLE ~ ~]TABLE VASTE C~TA]NEE. HINIH]~ DUSTING DURING CL~NUP. FLUSH RESIDUE MITH ~ATEE. ~aste Ois~sa[ ~ASTE PR~UCT IS HOT HA~EO~S AC~RD]HG TO EC~ CR]~EEI~ ~ L]ST]HG AS ~PPLIED. OIS~SE OF ACC~)IHG TO L~L, STATE ~ F~ EE~T]~S D~L]NG ~]TH A H~HA~EO~S ~ASTE Ha~Ling= "' -VARNING! ~NTAINS ~YSTALLINE SILI~, IN~TI~ OF ~HICH ~Y ~USE ~ER. ~ PR~ER RESPI~T~ PROTECTI~ E~I~ENT. ~USE NEC~N]~L EYE, SKiN ~D RESPI~TORY ]RRITAT]~. A~ID CONTACT g]TH EYES ~ SKIN. Storage: KEEP DUSTS TO A NIN]~. ~EP ~NTA]NER CLOS~ gHEN NOT IN USE. USE g]TH ~E~ATE ~NTILAT]~. IX. - OCCUPATIONAL CONTROL NEASURES: Respiratory Protection: klEAR AN APPROVED PARTICULATE RESPIRATOR IF EXPOSURE LI#ITS NAY BE EXCEEDED, Ventilation: - VENTILATION NEEDED TO NAINTAIN SAFE EXPOSURES TO CRYSTALLINE SILICA-CONTA]I ING DUSTS. Clothing: klEAR LONG PROTECTIVE CLOTHING gITH AN APRON TO KEEP OFF DUSTS. LAUNDER CLO1HING BEFORE REUSE. Eyewesr: t/EAR CHENICAL SAFETY GOGGLES OR GLASSES WITH $]DEGUARD$. INSURE A PROPER FIT. Groves: UEAR GLOVES TO PREVENT NECHANICAL S[]H ]RRITATIOR. Footuesr: USE NORNAL SAFETY BOOTS. Other #assures: YEARLY CHEST EXAHINAT]ONS ARE RECCIOIENDED AS A HEALTH NA]NTENANCE #EASURE. USE APPROPRIATE CLEANSERS TO WASH OFF PROOUCT. CLEAN E~JIPNEHT oF DUST BEFCRE REUSE. X. - ADDITIONAL iNFORK~T]OR: DISCLAI#ER The statements, information, and date provided in this materiaL safety data sheet are believed reLiaBLe m~l accurate by Baker Hughes INTEG and its responsible personnel; houever, no other guarantee, representation, MarrantY or respo~Bibi]Jty is expressed or implied to any user, regardless of reliance on aLL or any part thereof. This includes MsrrantJes of merchantability or of fitness for · particular purpose, and Baker Hughes INTEQ assumes no responsibility ~hatever for advice or rec~emeedation~ mede. Nothing contained herein should be interpreted as permission, inducement, or condonement to viol&ts any LaM. persuant this product's use, callvm* ~ or disposal. ~ PrePared By: Jim Rushing Date Prepared: 01/17/9~ Supercecle~ Issue Date: / / ND - Not Determined NA - Not AppLicable · - Greater Than < - Less Than C - Ceiling LJaJt PaRe 2 _~_~MILPARK' MATERIAL SAFETY DATA SHEET ==.- I~RILLING FLUli)S A Baker Hughes company NiLpark DriLLing FLuids SuppLier: HILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 · Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 I. - MANUFACTURER'S ZNFORMATION: Product Name: MILGEL CAS N~Tdoer: NAV Code: 1215151 Chemical Name: BENTONITE CLAY Chemical Description: BENTONITE CLAY DOT Hazard CLass: NAP Shipping Id. No. - UN: NA: DOT Proper Shipping Name: !!. - INGREDIENTS: ............ "'LzL~'~'°-~'L'L"~'"'nt--?'~"-'A-2"L-c-~"'-'-'~"°-:'-2'°'°'!:' ........ 1 .... .,i.,.:_ ......... _,L._v:_ ......... _,E__~ .... I_.;.'.I.~S...,..~...~ .......... QUARTZ-USE TLV FOR CRYSTALLINE SILICA INAP .1 PlG/M~ NAP <5.0 ~14808-60-7 ACCORDING TO ~. OUARTZ PRESENT OTHERWISE INAP RESPIRABLE NAP NAP INAP TREAT AS #UISANCE PARTICULATES WITH TLV- INAP DUST NAP NAP INAP IOMG/14~ TOTAL DUST <1% QUARTZ, OR 5NG/14~ INAP 0.3MG/M~ NAP NAP INAP ...~:..!...L..~L...~_s::.LL.!_..!_~...~::.~ .................................... ILL. .......... :.o:L~....u::......L. ......... I.".L"..ILL" .................. ............ L"--L~-~-°-~L-~t--L~-~-?-P-L~-°--c--~R--~-°-~- ! "- ................ l .... _~i.~.:. ......... T..~.~:. ...... .L~g.~.~.LR.~..'. l...~:. I..%L.~..: .......... NAP NAP NAP NAP INAP INAP NAP NAP NAP NAP INAP INAP NAP I NAP :NAP NAP I NAP NAP NAP I NAP NAP NAP I NAP NAP NAP INAP I NAP NAP IgAP INAP !!I. - PHYSICAL DATA: BoiLing Point(F): NAP Vapor Pressure(n~aH9): NAP Specific Gravity: Z.6 PH: NEUTRAL Ne[ting Point(F): NAP Vapor Density(Air=l): NAP Percent VoLatiLe By Vo[t~e(~): NAP Freezing Point(F): NAP SoLubiLity In Water: NAP Evaporation Rate: ( . = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: TAN/CLAYEY O00R Nateria[ Is: PURE-PCNOER Coefficient of t~ater/Oi[ Distribution: NAP IV. - FIRE & EXPLOSION HAZARD OATA: FLashpoint(F): NAP Auto Ignition Temperature(F): NAP FLammabLe Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NON COMBUSTIBLE Sensitivity To !mpact: NAP Extinguish Media - Water: C02: HaLon: Dry ChemicaL: Foam: Fog: Hazardous Combustion Products: NONE Fire Fighting Procedures: NAP UnusaL Fire and ExpLosion Hazards: NAP V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under Which Conditions? AVO!D CREATING DUST LAOEN ATONSPHERES. BECOMES SLIPPERY WHEN t~ET WITH WATER, !ncompatibLity (MateriaLs to Avoid): NAP Hazardous Decomposition or Byproducts: NAP Hazardous PoLymerization - Nay Occur: WiLL Not Occur: X Conditions to Avoid: NAP Milpark DriLLing FLuids SuppLier: MILP,RK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY OATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/439-8000 . Emergency TeLe~one: 713/439-8000 VI. - HEALTH HAZARD DATA: MZLGEL Carcinogen - HTP Program: NAP Carcinogen - IARC Program: NAP Symptoms of Exposure: NAP HedtcaL Conditions Aggravated By Exposure: NAP Emergency and First Aid Procedures: Eyes= FLUSH ~ITH LARGE AHOIJNTS OF CLEAN ~ATER TO REHOVE DUST AND CONSUT A PHYSICIAN IF IRRITATION PEISISTS. Skin= ~ASH AFFECTED AREAS ~ITH ~ATER. S~aLLow: CONSULT A PHYSICIAN. Breath: REHOVE FROH EXPOSURE TO FRESH AIR. VII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spi L L Response: HORHAL CLEAN-UP PROCEDURES FOR DRY PROOUCTS- VACUUM, ETC. ~aste O~sposat Method: DISPOSE IH ACCORDAHCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. HandLing and Storage: AVOID DUST LADEN ATOMSPHERES. BECOHES SLIPPERY ~HE# t~ET. VIII. - SPEC]AL PROTECT]ON INFORMATION: Respiratory Protect~'-~n: ~EAR #~=~/MSHA APPROVED RESPIRATOR IF TLV MAY BE=EXCEEDEd. = VentiLation: LOCAL EXHAUST CLothing: NORMAL GLoves: OPTIONAL Eye: SAFETY GLASSES ~ITH SIOESHIELDS OR GOGGLES. Foot~ear: NORMAL Other: AS NEEOEO IF DESIREO. Known Hazards Under 29 CFR 1910.1200 I HNIS I NFPA IYes: IYe, .......................... t ......................... ......................... [---! HeaLth: 1 I HeaLth: 1 CombustibLe Liquid Skin Hazard Fta~ability: 0 I FLarrmabitity: 0 FLammabLe Material Eye Hazard Reactivity: 0 J StabiLity: 0 Pyrophoric Material Toxic Agent Personal Protection: E I SpeciaL: ExpLosive Material HighLy Toxic Agent ................................................... UnstabLe Material Sensitizer ~ater Reactive MateraL Carcinogen Oxidizer Reproductive Toxin Organic Peroxide BLood Toxin Corrosive MateriaL Nervous System Toxin Confessed Gas Lung Toxin Irritant Liver Toxin Nu(sance Dust X Kidney Toxin ........................ ~---~ ......................... b--~ ......................................................................... Physical & HeaLth Hazard - SARA 40 CFR Part 370 (Check aLL that apply) (NOTE (*) indicates TL~ for nuisance dust only) Fire: Sudden ReLease Of Pressure: Reactivity: In~nediate(Acute): ~ OeL;~ed(Chronic): X IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of ContaminstedEquipment: NAV Other Precautions: MATERIAL BECOMES EXTREMELY SLIPPERY ~HEN ~ET. MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., Suite 300 ' EmergenCY Telephor~e: (713) 439-8900 IJ~r~l~ Houston, Texas 77040 u.o. DEF0~U4 CHEMTREC: 1-800-424-9300 - ~L~NUFACTURER~S INFOR~ATION: Manufacturer: IL~KER HUGHES INTEQ HNIS Hazard Rating Health I Ninimai - 0 Pr_~c~__~_t Name: Id.O. DEFOA/q and Key: FLanmabitity 2 SLight - 1 Chmicat Hare: C8-C12 DIOL/ALCDHOL BOTTOI4S BLEND Reactivity 0 Noc~erate - 2 ChmicaL Description: ALCOHOL-BASED DEFOANER ' Personal Seriou~ - 3 Protect io~ H Severe - Z~ Pro,er Shipping Oescription: DRILLING FLUID CCNPOLJND, #.D.a. Hazard CLass: NOT REGULATED UN Ntz~ber: NA Hazard Label: NA DOT Response Guide: NA Transportation Note: FOR.,.U.S. SHIPI4ENTS Iii. BULK CONTAINERS (>119 GALLONS), USE THE SHIPPING DESCRIPTION: CC~IBUSTIaLE LIOUID, #.O.S. (CONTAINS 2-ETHYLHEXANOL),,~ "' Il. - HAZARD IDENTIFICATION: ................... : ............ ........ Hazards Associated uith Product Use Yes Yes Yes Contx~tibLe Liquid X Flan~abte Nateria[ Pyrop~oric #~teriaL Explosive Material Unstable #ateriat I~ater Reactive NateriaL Oxidizer Organic Peroxide Corrosive Material Cc~qoressed Gas . Irritant Nuisance Particulate $1cin Hazard X Eye Hazard X Toxic Agent Highly Toxic Agent . ~ensitizer Carcinogen Reproductive Toxin BLood Toxin Nervous System Toxin Lung Toxin Liver Toxin Kidney Toxin Caanunity Right-to-Kno~ (SARA Title II[ Section 311-312) ~,re: X Sudden Release Of Pressure: Reactivity: l~mediate (Acute): X Delayed (Chronic): X III. - PHYSIGAL DATA: ,. BoiLing Point(F): 390 - 586 Vapor Pressure(n~g): <1 PH: 9.2-10.2 aSZ Netting Point(F): NA Vapor Oensity(Air--1): >1 Specific Gravity: 0.91 Freezing Point(F): NO Sotubi[ity In I~ater: I40OERATE Percent Volatile By VoLu~e(:l:): liD Odor Threshold: NO Appoarar~:e And Odor: CLEAR-GREYISH,ALCOHOL C~OOR Evaporation Rate ( = 1): ND Nateriat Is: NIX-LIqUID Coefficient of t~ater/OiL Distribution: PARTIALLY SOLUBLE IN OIL IV. -F[RE & EXPLOSIO# IL~7_ARO OATA: Flashpoint(F): 198 (PNCC) Auto Ignition Te~erature(F): ~ Fiaw~able Limits - LFL: NO UFL: NO Explosion - LEL: ND UEL: NO Extinguish Nedia - 1~8ter: X CO2: X Dry Chemical: X Foam: X Fog: X Hazardous Comtx~stion Products: UPON COMBLJSTION, PRC~)UCT FO~#S CARBO# NO#OXIDE, ACRID SI4C)ICE AND ]RRITATZl4G FUNES. Fire Fighting Procedure~: gEAR SELF CONTAINED POSZTIVE PRESSaJRE BREATHING APPARATUS AND FULL FIRE FZGHTIHG PROTECTIVE CLOTHING FOR ENCLOSED OR CO, FINE0 AREAS. ALCOHOL RESISTANT FOAN IS RECOI4NEla:)ED. USE IdATER TO COOL FIRE-EXPOSEO CONTAINERS AND 0]SPERSE VA.~ORS. Unusual Fire and Explosion Hazard~: VAIN3R$ ARE HEAVIER TNA# AIR AND NAY TRAVEL ALONG THE GRC~JNO TO AN IGNITION SOURCE AND FLASH IL~C3C. V. o REACTIVITY DATA: Chemically Stable: Ye~: X Mo: If no, Under ghich Conditions7 AVOIO HEAT, SPARKS AgO OPEN FLANES. ]noonq~atibLity (NateriaLa to Avoid): AVOIO STRONG OXYOIZ]NG AGENTS. 'zarckx~ Oecceq3o~ition or Byp~_-,:~_~ta: NATERZAL DOES NOT READILY DECOMPOSE. .zardo~ Pokyemrizatio~ - Nly Oecd: ~l~ll #or Occur: X Co~ciitio~ to Avoid: ~ ND - NOt Oeter~ir~.d I~A - Not Applicable T - Total Dust R - Reipir~Le Fraction C - Ceiling Limit ~1.O. DEFOAJq [SA TRAZ)EI~ARIC OF BJUCER HUGHES INTEO. Page 1 W.O. DEFOAM '~. - HEALTH liAT_~RO INFORI4ATIC~I: Primary Exposure Route o Skin Contact: X Skin Absorption: X Eye Contact: X Inhalation: X Ingestion: Product Carcinogenicity - NTP: NO IARC: NO Acute Effects of Overexposure: INHALATION OF VAPORS OR MISTS IN EHCLOSEO OR CONFINED AREAS MAY PROOUCE DIZZINESS, HEAOACHE, NAUSEA OR VOMITING. PRODUCT NAY SEVERELY IRRITATE EYES AND NOOERATELY IRRITATE SKIN. Chronic Effects of Ove~e~'~osure:.-, LIOUIO IS NOOERATELY TOXIC AND MAY 8E HARMFUL IF ABSORBED THROUGH THE SKIN OR INGESTED. 2 ETHYLHEXANOL IS AN EXPERIMENTAL TERATOGEN ANO HAS EXHIBITED OTHER REPRODUCTIVE EFFECTS. VII. - EMERGENCY AND FIRST AIO INSTRUCTIONS: Eyes: HOLD EYELIDS APART AND FLUSH idiTH MATER FOR AT LEAST 15 14%MUTES. CONTACT A PHYSICIAN IF IRRITATION PERSISTS. Skin: MASH THOROUGHLY Id%TH MILD SOAP AND MATER. REMOVE CONTAI4INATED CLOTH]NG. Ingestion: DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE AMOUNTS OF MATER AND CONTACT A PHYSICIAI4. Inhalation: REHOVE' TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIILRTION. IF BREATHING IS OIFFICULT, GIVE OXYGEN. VIII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spill Response: ~ PROTECTIVE E~UIPNENT. RENQVE IGNITION SOURCES AND CONTAIN THE SPILL IF POSSIBLE. TRANSFER ~PILL TO A SUITABLE CONTAINER FOR DISPOSAL. ADO INERT ABSORBENT AND REMOVE RESIDUE. FLUSH REMAINS MITH LARGE AMOUNTS OF IdATER. SPILL R(a lS 1],192 GAL. I~aste Disposal Nethod: REEt/ALUATION OF THE PRODUCT NAY BE REQUIREO BY THE USER AT THE TIME OF OISPOSAL SINCE PRODUCT USES, REACTIONS, MIXTURES, A~IO PROCESSES MAY AFFECT IdASTE CLASSIFICATION. CC~PLY ~/ITH LOCAL, STATE AI~O FEDERAL REGULATIONS IN DISPOSAL OF IdASTE MATERIAL. _..a/ARNINGI COMBUSTIBLE Ll~lJIO. PRODUCT NAY IRRITATE EYES, SKIN AND UPPER RESPIRATORY SYSTEM. DO NOT GET 11~ EYES, ON SKIN OR ON CLOTHING. AVOID BREATHING VAPORS OR MISTS. VEAR PROPER PROTECTIVE EOUIPNENT STATED IN THE MSDS. Storage: '" KEEP AIdAY FROM HEAT, SPARKS AND FLAHES. STORE IN A COOL, DRY AREA. USE I~lTfl ADEOUATE VENTILATION. KEEP CC~TAINER CLOSED. DO NOT PRESSURIZE, CUT, idELO OR DRILL EMPTY CONTAINERS. O0 NO REUSE EMPTY CONTAINERS BEFORE RECONDITIONING OR DISPOSAL. IX. - OCCUPATIONAL CONTROL ME.~SURES: Respiratory Protection: IdEAR AN APPROVED ORGANIC VAPOR RESPIRATOR IF RECC~ENDED EXPOSURE LIMITS NAY BE EXCEEDED. Ventilation: SUPPLY ADElaUATE MECHAI~ICAL OR LOCAL EXHAUST VENTILATION TO EXI~AUST VAPORS BELOW/ RECI~I~ENDED LIMITS. Clothing: IdEAR LONG PROTECTIVE CLOTHIHG AND AN APRON OR I~VERALLS FOR ADDED PROTECT]ON. Eye, ear: USE CHEMICAL SPLASH GOGGLES MITH OPTIONAL FACESHIELD IdHILE HANDLING THIS PRODUCT. Gloves: USE NEOPRENE OR BUTYL°RUBBER GLOVES TO PREVENT SKIN CONTACT. Footwear: UEAR RUBBER ~FETY BOOTS. Other Neaaure~: IdASH CLOTHES BEFORE REUSE. SUPPLY EMERGENCY SHOIdER ANO EYE UASH STATION NEARBY. IdASH ATTER HANOL[NG A#O BEFORE HEALS OR BREAKS. USE CORO[T[ONING CREAMS TO TREAT OR¥ SKIN. X. - ADDITIONAL INFORMATION: DISCLAIMER The statemes~ts, information, and data provic~-cl in this material safety data sheet are believed reliable and accurate b~ Baker Hughes INTEG and its responsible persor~ei; houever, no other guarantee, representation, warranty or responsibility is expressed or implied to any user, regardless of reliance on all or arty part thereof. This includes warranties of merchantability or of fitness for a particular purpose, ~ Baker Hughes INTEIa assuaes no responsibility ~hatever for service or recoa~aendations made. Nothing contained herein should be interpreted as permission, inciucement, or condonement to violate any law persuant to this product's use, conveym~ce or disposal. ;,, sred By: Jim Rushing Data Prepared: 0]/17/9/. Supercec~es Issue Oate: 05/01/91 NO - Hot Determined NA - Not Applicable > o Greater Than < - Less Than C - Ceiling Limit Page MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., Suite 300 Emergency Telephone: (713) 439-890u ~J~T~ Houston, Texas 77040 xc~ ~OL~ER CHEMTREC: 1-800-424-9300 - #AIJUFACTURERtS INFORI4ATIC~I: #anufacturer: BAKER HUGHES iNTEQ HI4iS Hazard Rating HeaLth O #inimL - 0 Prcx~uct Name: XCD I~YHER and ICey: Ftammbitity 2 SLight - 1 ChmicaL Idame: POLYSACCHARIDE POLYMER Reactivity O #oderate - 2 ChmicsL Description: DRILLZHG FLUID VISCOSIFIER Personal Serio~ - Protectio~ E Severe Proper Shipping Description: DRILLING FLUID C:C~ND, #.O.S. Hazard CLass: NOT REGULATED Uid Humer: IdA Hazard LabeL: JlA DOT Response Guide: IdA Transportation Hate: NA Ii. - HAZARD [OE#TZFZCATZON: ...... ............... ................ ..... ........ Hazards Associet. with Product Use Yes Yes - Yes Yes .......... . ........................................................... o ....................... . ... CombustibLe Liquid F[mmmbLe #aterieL *Pyrophoric #ateriai ExpLosive #ateriel UnstabLe #ateria[ k/star Reactive #aterial Oxidizer Organic Peroxide Corrosive Idateria[ Cc~preseed Gas l rri tent Nuisance ParticuLate X Skin Hazard Eye Hazard Toxic Agent HighLy Toxic Agent Sensitizer Carcinogen Reproductive Toxin Blood Toxin Her~ous Syst-- Toxin L[~g Toxin Liver Toxin Kidney Toxin Commmity Right-to-Enou (SARA TitLe Ill Section ]11-312) ,.ire: Suclde~ Re[ease Of Pressure: Reactivity: Immediate (Acute): X De[eyed (Chronic): ill. - PHYSICAL DATA: Boiling Point(F): NA Vapor Pressure(nm~g): HA PH: #eLting Point(F): HA Vapor Donsity(Air=l): IdA Specific Gravity: 1.5 Freezing Point(F): HA SoLubiLity in t~eter: APPRECIABLE Percef~t VoLatiLe By Odor ThreshoLd: LOk/ Appearance And Odor: LIGHT BEIGE, SL[GI~T ODOR Evaporation Rate ( = 1): Idateria[ IS: PUREoPOM)ER Coefficient of k/star/OiL Distribution: INSOLUBLE ]# OIL IV. - FIRE & EXPLOSION HAZARD DATA: F[ashpoint(F): RA Auto Ignition Temperature(F): NA FlammabLe Limitl - LFL: IdA UFL: HA ExpLosion - LEL: IdD UEL: ltd Extinguish #edia - k/star: X C02: X Dr~ ChemicaL: X Foam: X Fog: X Hazardous C~mbustion Products: k/ILL PROVIDE CARBO# DIOXIDE UPO# C~I~USTioR. Fire Fighting Procedures: t~F. AJI SELF CO#TAIIdED POSITIVE PRESSURE BREATHIIJG APPARATUS AND FULL FiRE FIGHTI#G PROTECTIVE CLOTHIIdG FOR EIdCLOSED AREAS. GEIdTLY FLOC30 FIRES k/ITH k/ATER FOG,'US]#G CARE HOT TO SUSPEND DUST. Unusual Fire and ExpLosion Hazards: PR(X)UCT k/ILL ~tJRid IH CO#TACT k/iT# A FLA/4E. TREAT AS A F~BLE DUST. I~A¥ FORI~ EXPLOSIVE DUST-AIR ll]XTURES. V. - REACTiVITT DATA: ChemicaLLy StabLe: Yes: X #o: If rm, Under I~hich Cor~litiorml #O#E REPOllTED. incompetib[ity (l~ateris[s to Avoid): STRO#G OXIDiZI#G AGEIJTS. "~zardou~ Decomposition or Byproducts: PRODUCT k/iLL HOT READILY DECOHPOS~. '"'-~azemlmm PoLymerization - #ay Occur: k/iLL Hot Occur: X Conditions to Avoid: IdA NO - Hot Deterlined IdA - Not AppLicabLe T - TOtaL Dust R - Respirab[e Fraction C - CalLing Limit XCD POLY#EE IS A REGISTERED TRADF. J~ARI( OF HERO( AND CO., i#C. Page XCD POLYMER VI. - HEALTH HAZARD INFOi~NATXON: Prim~ E~ure R~e - Skin C~tact: Skin A~ti~: E~ C~tKt: Pr~t CarcJ~JcJty - gTP: ~0 ;~C: Acute Eff~ts of ~ere~ure: EX~SSI~ ;N~TI~ OF DUST )NPEDES RESPZ~TZ~ DUE TO HYGROSC~;C PR~ERTIES. DUSTS ~Y ~ · :~I~L ~RR~TAT~ TO EYES, g~E, THR~T ~ LUg~. OE~TITlS AND AST~ ~Y RE~LT FR~ SH~T ~TACT PERZ~S. Chr~c Eff~ts of ~erex~sure: PROL~G~ C~TACT ~Y PROUd- ~ AGG~VATE AN EX~STING ALLERGIC Vii. - EHERGEI~CY A~D FIRST AiD I#STRUCTiO#S: Eyes: FLUSH gITH LARGE N~UNTS OF CL~ ~TER F~ AT LEAST FIFTEE~ NI~ES ~ ~TA~ A PHY$: CI~ iF iRRiTATI~ PERSISTS. Skin: ~SH TH~GHLY U~TH N]~ ~ A~ ~TER. ~PLY HEDI~TED ~ TO RELIE~ ~rRR~TATI~ ~ REPLENISH ~]g OILS. l~tJ~: ES~NTIALLY g~ TOXIC. DRINK ~TER TO DILUTE. CON~LT A PHYSICI~ IF ~STROINTESTINAL U 'SET ~RS. [~aLatJ~: RE~ TO FRESH AIR. IF NOT BR~THZgG, G~ ARTIFICIAL RESPI~TZ~. IF BR~THlgG IS D~IFI~LT, GZ~ OXY~L VI l ~. - E~VIR~NTAL PROTECTZ~ PR~EDURES: Spit t R~e: ~ PRIER PROTECTI~ E~[~E~T (SECT~ ]X). REaR SP[LL~ ~TER]AL TO THE ~]~I~L ~TAINER F~ ~LE IF ~SIBLE ~ TO A ~TABLE ~STE ~TAINER. N[~XMI~ OUSTING D~]~G CL~RUP. FLUSH RES]D~ g~Tg ~TER. gaste DJs~sat Neth~: VASTE PR~UCT 1S gOT HA~S AC~DI~G TO RC~ CRITERZA ~ LISTIHG AS ~LI~. DI~E OF AC~DING TO L~L, STATE ~ FF' 'L RE~T~S D~LING UITN A UASTE PR~UCT. *~1~1 ~Y ~C~]~LLY IRRITATE EYES, SKI#ANO RESPI~T~Y T~CT. ~ PRIER PROTECT]~ E~I~EMT. k~lO EYE ~ ~IM ~TACT. A~ID BR~TNI~G O~T. Storage: ~EP A~AY FR~ H~T ~ ~EN FL~ES D~ING OUSTY ~T]~S. STYE IN A DR~ ~ ~ ~EP ~TA~ER CL~ ~NEM MOT IM U~. N]NINI~ DUSTING. ~TERZAL ZS SLIPPERY ~HEM ~T. IX. - ~PAT]~L ~TR~ ~RES: R~irato~ ProtKti~: ~ ~ ~PR~ P~TI~TE RESP]~T~ IF EXP~E L]NITS ~Y ~ EX~ V~tikati~: ' ~MTI~T]~ NEEDED TO ~]NTA]~ ~FE EXPO~RES TO MU]~ P~TI~TES. CLothi~: ~ L~G PROTECT]~ CLOTHING ~]TH ~ ~R~ TO ~EP OFF DUSTS. ~DER ~F~ ~ R~. EyMar: ~FETY G~SSES F]TT~ ~ITH SIDE--DS ~ ~GLES. IM~E A PRIER FIT. Grove: ~ GL~S TO PR~MT NEC~I~L SKIM ]RR]TAT]~. 'F~t~r: U~ Other Neasur~: USE ~ PER,AL NYGIENE. ~SN AFTER HA~LING A~ BEF~E N~LS ~ BR~S. CL~M E~I~NT OF D~T BEF~E REUSE. USE ~PR~RIATE N]~ CLOSERS TO ~;N OFF PR~UCT. D~SC~IMER The statute, info~ti~, ~ ~ta ~i~ in this mteria{ safety ~te ~t ere ~LJ~ INTEG ~ its r~ibie ~rs~[; h~r, ~ other g~rant~, r~res~tetJ~ ~rr~ty or to ~ ~er, r~a~L~s of reiJ~e ~ ~{[ or ~ ~rt ther~f. Thie i~{~ ~rr~tt~.of ~rticuLar ~e~ ~ Baker g~h~ ~MTEQ el~ ~ r~JbJLJty ~&t~r for ~tce or herein sh~Ld ~ inte~ret~ as ~miaaJ~, i~t, or c~t to violate ~ ta~ ~ra~t :o thle ~t~l me, c~e Pr~r~ By: aim R~t~ Date Pr~r~: 03/21~ ~~ ~a~ Date: 07/~/~ NO - Not Dete~i~ ~ - Not ~tic~te ) - Greeter Th~ ( - L~I Th~ C - Cel[i~ Limit Page 2 MILPARK' MATERIAL SAFETY DATA SHEET DRILLING FLUIDS A Bake~ Hughes company HiLl=ark DriLLing FLuids SuppLier: HILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 HATER[AL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 I. - HANUFACTURERIS INFORHATION: Product Name: NEV DRILL CAS N~ber: NAV Code: 1219185 Che;ice[ Name: SHALE STABILIZER FOR VATER BASE Chemical Description: A ANIONIC POLYACRYLAHIDE IN VATER-IN-OIL EHULSION POLYHER. A SHALE STABILIZER FOR A ~ATER BASED HUOS. DOT Hazard CLass: ORH-A Shipping id. No. - UN: NA: 1693 DOT Proper Shipping Name: ORH-A, N.O.S.,¢CONTA]NS PETROLEUN DISTILLATE) II. - INGREDIENTS: ............ ~:.=..~.~..."~...~.!~f~.f~.~.!~!~:!f~?!: ........ 1 .... ~!~: .... 1 .... ~: .... 1 .... ~: .... 1--~:-1-~f-~--~--: ......... PETROLEUN DISTILLATE INAP INAP ]NAP ]26-271008002-05-9 T~A CEILING 500 #G/H3 INAP INAP INAP INAP INAP NAP INAP NAP INAP NAP INAP HAP INAP NAP INAP NAP INAP .............................................................. ......... ......... ......... ................. ............ ~:f~-~-!~-~-~!~-~?~!~ ................ 1 .... ~!~ .... 1 .... ~ .... l-~:-°f~-~:l--~:-I-~f~-~--~--: ......... CONTAINS HINERAL OIL NAP INAP INAP INAP INAP NAP NAP INAP INAP INAP INAP NAP NAP NAP INAP INAP NAP NAP NAP NAP I#AP INAP NAP NAP INAP INAP INAP iNAP INAP III. ' PHYSICAL DATA: BoiLing Point(F): >390 Vapor Pressure(n~g): SAgE AS VATER Specific Gravity: 1.0~ Pti: 6-8 IN VATER HeLting PointCF): -27 Vapor Density(Air=l): NAP Percent VoLatiLe By Freezing PointCF): NAP SoLubility In gater: GREATLY Evaporation RaCe: ¢ = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: VHITE, VISCOUS, OPAQUE LIQUID UITH SLIGHT HYDROCARBON O00R Hateria[ Is: HIX-LIQUZD Coefficient of gater/Oi[ Distribution: NAP [V. - FIRE & EXPLOSION HAZARD DATA= F[ashpoint(F): >200 CLOSED CUP Auto Ignition Temperature(F): NAV F[anr0abLe Limits - LFL: NAV UFL: NAV ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To. Impact: NAP Extinguish #edia - ~ater: X C02: X Ha[on: Dry ChemicaL: X Foam: Fog: Hazardous Combustion Products: SNOKE, CO, C02, OXIDES OF NITROGEN Fire Fighting Procedures: USE ~ATER SPRAY, CARBON DIOXIDE OR DRY CHEHICAL TO EXTINGUISH FIRES. USE ~ATER TO kEEP CONTAINERS COOL. k/EAR SELF-CONTAINED~ POSITIVE PRESSURE BREATHING APPARATUS AND FULL FIRE-FIGHTING PROTECTIVE CLOTHING. Unusa[ Fire and ExpLosion Hazards: NAP V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under ~hich Conditions? NONE Incompatib[ity (Hateria[s to Avoid): STRONG OXIDIZING AGENTS. PROOUCT REACTS SLOULY ~ITH IRON, COPPER, ALUHINUH. RESULTING IN CORROSIOfl AND PROOUCT DEGRADATION. Hazardous Decomposition or Byproducts: THERHAL DECOHPOSITION OR CONBUSTION HAY PROOUCE CARBON HONOXIDE, CARBON DIOXIDE, AHHONIA AND/OR OXIDES OF NITROGEN. Hazardous PoLymerization - Hay Occur: Ui[[ Not Occur: X Conditions to Avoid: NAP Mi[park DriLLing FLuids S~[ier: MILI~ARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address= 390~) Essex Lane Houston, Texas 77027 H~)ton, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeL. ~one: 713/439-8000 VI. - HEALTH HAZARD DATA: NEW DRILL Carcinogen - NTP Program: NAP Carcinogen - IARC Program: NAP Symptoms of Exposure: HAY CAUSE IRRITATION TO THE RESPIRATORY TRACT AND LUNGS. PROLONGED CONTACT MAY CAUSE IRRITATION TO T SKIN AND EYES. Medical Conditions Aggravated By Exposure: HAP Emergency and First Aid Pr~eciur~: Eyes: FLUSH WITH CLEAN RUNNING WATER FOR AT LEAST FIFTEEN MINUTES AND CONTACT A PHYSICIAN. Skin: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER. SwaLLow: DO NOT INDUCE VOMITING. GIVE WATER AND CALL A PHYSICIAN. NO SPECIFIC ANTIDOTE IS KNOWN. BA: D ON INDIVIDUAL REACTION OF THE PATIENT, THE DOCTORS JUDGEHENT SHOULD BE USED TO CONTROL SYMPTOMS AND CLINICAL CONDITION. Breath: REHOVE TO FRESH AIR. TREAT SYMPTOMS AND CALL A PHYSICIAN. VII. - ENVIRON#ENTAL PROTECTION PROCEDURES: SpiLL Response: WEAR NIOSH APPROVED RESPIRATOR. ABSORB WITH INERT ABSORBENT MATERIAL.' NORHAL CLEAN UP PROCEDURES FOR DRY PRODUCTS - SWEEP, VACUUM ETC. SPILLS ARE EXTREMELY SLIPPERY. THE AREA SHOULD BE THOROUGHLY FLUSHED WITH WATER ANO SCRUBBED TO ~EHOVE RES[OUR. Waste Disposal Method: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. HandLing and Storage: DO NOT REUSE CONTAINERS. AVOID PROLONGED BREATHING OF VAPORS. FOOD, BEVERAGES AND TOBACCO IPRODUCTS S~OULD NOT BE CARRIED, STORED OR CONSUMED WHERE THIS PRODUCT IS IN USE. WASH FACE AND HANDS WITH SOAP AND WATER BEFORE EATING, DRIN#ING OR SMOKING. VIII. - SPECIAL PROTECTION INFORMATION: VentiLation: LOCAL EXHAUST m clothing= LONG SLEEVED SHIRT GLove: NEOPRENE, BUTYL-RUBBER FOR PROLONGED AND/OR REPE~TED CONTACT Eye: CHEMICAL GOGGLES Footwear= NORMAL Other: RAINSUIT WHEN DEALING WITH SPILLS. AS REGUIRED FOR PERSONAL CO~IFORT. K~ Hazar~ Under 29 CFR 1910.1~00 I HMIS NFPA Yesl IY't ............................................. t ............................ t ......................... t---! HeaLth: 1 HeaLth: 1 C~tibte Li~id I Skin Hazard Ft~bi[ity: 0 Ft~bitity: 0 F[~bLe Material I Eye Hazard X Reactivity: 0 StabiLity= 0 I Pyrophoric #aLexia[ I Toxic Agont Parsul Prot~tien: G I Expkosive Material i HighLy Toxic Agent ................................................... UnstabLe Material S~itizer Water Reactive MateraL Carcinogen Oxidizer I Reprod~tive Toxin Organic Peroxide ) B[oe~l Toxin Corrosive Material I ) Nervous System Toxin Compressed Gas I ~ Lung Toxin Irritant I X I Liver Toxin . Nuis~e D~t ) I gic~y Toxin ........................ t---( ............................. ( ......................................................................... Physical & HeaLth Hazard - SARA 40 CFR Part 370 (Ch~k at[ that apply) (NOTE (*) indicates TLV 'or ~isance d~t only) Fire: Sudd~Re[esse Of Pressure= Reactivity: Inmediate(Acute): X DeLay, d(Chronic): IX. - SPECIAL PRECAUTIONS: Pr~autio~ For R~ir & Msint~e Of Contami~ted NAV Other Pr~autions= PREVENT PROOUCT FROM CONING IN CONTACT WITH COJMMON METALS. DO NOT USE IRON, COPPER OR ALUMINUM CONTAINERS OR EGUIPMENT. FOR OPERA- TIONS WHERE EYE OR FACE CONTACT CAN OCCUR, WEAR CHEMICAL SPLASH PROOF GOGGLES. m x.. APPROVAL: Pr~redBy: Safety D~rt~nt Code: 1219185 Date Prel~red: 05/01/91 SUl~rC~s Issue Date= MILPARK" MATERIAL SAFETY DATA SHEET DRILLING FLUIDS A Baker Hughes company Mitpark DriLling FLuids SuppLier: #ILPARK DRILLING FLUIDS 3900 Essex Lane, Suite :]00 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 I. - HAHUFACTURERtS INFORMATION: Product Name: NEV THIN CAS #mloer: HAV Code: 121990Z Chemica[ Name: SODiUI4 POLYACRYLATE COPOLYMER Chemical Description: AN AQUEOUS SOLUTION OF AN ACRYLIC COPOLYNER USED OEFLOCCULAHT. DOT Hazard CLass: NAP Shipping Id. No. - UN: NA: DOT Proper Shipping Name: ]]. - INGREDIENTS: ....... : .... ~:~.~~.!?~_~_~.!~!?:!~??!: ........ 1 .... ~!~: .... 1 .... ~: .... 1 .... ~ .... 1--~:-1-~L~: ......... NAP 1¼AP IMAP I#AP INAP INAP NAP INAP INAP IMAP /NAP INAP NAP NAP NAP NAP NAP NAP HAP HAP NAP NAP NAP #AP .............................................................. .......... ......... ......... .................. ............ ~:~.~.!~_~.~r~.~!~.' ............... 1 .... ~!~ ......... ~! .... I-~:~L~I--~-I-~L~: ......... NAP INAP NAP INAP INAP INAP NAP I#AP ~AP IMAP INAP I#AP NAP INAP NAP I"AP INAP INAP NAP I#AP 8AP I#AP INAP INAP NAP INAP NAP IMAP INAP IMAP III. ' PHYSICAL DATA: BoiLing Point(F): Z1Z Vapor Pressure(mmHg): SAME AS ~ATER Specific Gravity: 1.2-1.3 PH:7.5 ~etting Point(F): NAP Vapor Density(Air=l): 1 AS HATER Percent VoLatiLe By Votume(~): Freezing Point(F): NAV ' SoLubiLity In gater: GREATLY Evaporation Rate: ( = 1): Odor ThreshoLd: gAP Appearance And Odor: CLEAR, STRAU COLORED gITH VINEGAR ODOR Material Is: MIX-LIGUID Coefficient of Water/OiL Distribution: NAP IV, - FIRE & EXPLOSION HAZARD DATA: F[ashpoint(F): NAP Auto Ignition Temperature(F): NAP FLanmmbLe Limits - LFL: NAP UFL: HAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To Impact: NAP Extinguish Media - ~ater: X COZ: X HaLon: Dry ChemicaL: X Foam: X Fog: Hazardous Combustion Products: THERMAL OECOMPOSITION PRODUCTS: COt COZ, ANO OX[OES OF SULFUR. Fire Fighting Procedures: ~ILL NOT REAOILY BURN. Unusa[ Fire and ExpLosion Hazards: NAP V. - REACTIVZTY DATA: Chemical StabLe: Yes: X No: If no, Under Uhich Conditions? PRECIPITATION ~ILL OCCUR IF MIXED ~ITH LIQUID CATION]C MATERIALS. ]ncompetib[ity (MateriaLs to Avoid): AVOID CONTACT ~ITH STRONG OX[DAHTS Hazardous Decomposition or Byproducts: MAY EVOLVE OXIDES OF SULFUR UNDER EXTREME FIRE CONDITIONS. Hazardous PoLymerization - May Occur: Vitt Not Occur: X Conditions to Avoid: NAP Mitpark DriLLing FLuids SuppLier: MILFARK DRILLING FLU]OS 3900 Essex Lane, Suite 300 HATER]AL SAFETY DATA SHEETS Address: 390C Essex Lane Houston, Texas 77027' Houston, Texas 77027 Emergency TeLephone: 713/6,39-8000 Emergency TeL~ ~ene: 713//,39-8000 VI. - HEALTH HAZARD DATA= HEU THIN Carcinogen - HTP Program: NAP Carcinogen - ]ARC Program: NAP Symptoms of Exposure: HAY CAUSE IRRITATION TO EYES, SKIN. HedicaL Conditions Aggravated By Exposure: SEE ABOVE. Emergency and First Aid Procedures: Eyes: FLUSH IdITN CLEAN RUNNING IdATER ANO CONTACT A PHYSICIAN IF IRRITATION DEVELOPS/PERSISTS. Skin: idASN AFFECTEO AREA IdlTH SOAP ANO i4ATER. S~aLlo~: OR]HI( PLENTY OF IdATER ANO CONTACT A PHYSICIAN Breath: REI4OVE TO FRESH AIR. TREAT SYMPTC~ATICALLY. VII. - ENVIRONMENTAL PROTECTION PROCEOURES: Spi i [ Response: ABSORB IdITH INERT ABSORBENT MATERIAL ANO STORE IN CLOSED CONTAINERS FOR DISPOSAL. PREVENT MATER]AL FIIOM ENTERING DRAINS, SEIdERS, OR STREAMS. Idaste Oisposa[ Method: OISPOSE IN ACCOROANCE IdITH LOCAL, STATE ANO FEOERAL REGULATIONS. HandLing and Storage: MINI~IIZE CONTACT IdITN EYES, SKIN, AND CLOTN~#G. VIII. - SPECIAL PROTECTION INFORMATION: Respiratory Protectien: NOT REGUIRED / VentiLation: LOCAL EXHAUST · CLothing: NORHAL GLoves: CHEH[CAL RESISTANT Eye: CHEFIICAL SPLASH GOGGLES AND OPTIONAL FACESHIELDS TO PREVENT EYE CONTACT. Foot,ear: NORMAL Other: AS NEEDED FOR COMFORT. Known Hazards Under 29 CFR 1910.1200 I H#IS ............. : .......... 1 .......... : .............. Combustib[eLiquid Skin Hazard X I F[almmbiLity: 0 FLaarnabLe Material Eye Hazard X Reactivity: 0 StabiLity: 0 ExpLosive MateriaL HighLy Toxic Agent ...................... UnstabLe Material Sensitizer ~ater Reactive Matera[ Carcinogen I Oxidizer Reproductive Toxin Organic Peroxide BLood Toxin I Corrosive 14aterie[ Nervous System Toxin Canpressed Gas Lung Toxin I ] rritant Liver Toxin Huisance Oust Kidney Toxin I ......................... f---! ......................... ~---t ........................ : ................................................. Physical & Has]th Hazard - SARA /,0 CFR Part 3?0 (Check aLL that apply) (NOTE (*) indicates TL~ for nuisance dust only) Fire: Sudden ReLease Of Pressure: Reactivity: Inmediate(Acute): X Deb ,ed(Chronic): iX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contaminated Equipment: ether Precautions: ¼AV :!=:: ::::: :::: :;=e. MILPARK" DRILLING FLUIDS MATERIAL SAFETY DATA SHEET A Baker Hughes company MiLpark DriLLing FLuids Supplier: #ILPARK DRILLING FLU%DS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency Telephone: I. - NANUFACTURER'S INFORMATION: Product Name: NEg-TROL CAS Member: NAV Code: Chemicst Name: COPOLYHER, SODIUM ACRYLATE & ACRYLAMIDE ., Chemical Description: FILTRATION CONTROL AGENT DOT Hazard Class: NAP Shipping Id. No. - UN: MA: DOT Proper ShilAoing Name: II. - INGREDIENTS: NUISANCE DUST {NAP 10 NG/K3 NAP {NAP {NAP NAP I#AP NAP NAP INAP INAP NAP NAP NAP NAP NAP INAP NAP NAP NAP NAP NAP INAP .............................................................. .......... .......... ......... .................. ............ ~:~:~:-~?::-!~-t~-~-~!: ................ 1 .... ~!~: ......... ~: ...... ~:g~L~:I--~LI-~LL-~--: .......... NAP NAP INAP "AP HAP INAP HAP NAP INAP ~AP NAP INAP NAP INAP INAP RAP INAP INAP NAP {NAP {NAP NAP INAP INAP III. - PHYSICAL DATA: Boiling Point(F): NAP Vapor Pressure(mmHg): NAP Specific Gravity: NAV PN: 7 Me[ting Point(F): NAP Vapor Density(Air=l): NAP Percent Vo[atite By VoLume(Y): NAP Freezing Point(F): NAP SoLubility In Water: GREATLY Evaporation Rate: ( = 1): NAP Odor Threshold: NAP AiAoearance And Odor: WHITE FREE FLOWING MICRO-BEADS/NO ODOR Material Is: MIX-SOLID Coefficient of Water/Oil Distribution: PARTIALLY SOLUBLE IN WATER IV. - FIRE & EXPLOSION HAZARD DATA: Ftashpoint(F): MAP Auto Ignition Ten~erature(F): NAP FLammable Limits - LFL: NAP UFL: NAP Explosion o LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To ln~act: NAP Extinguish Media - Water: C02: X Haton: Dry ChemicaL: X Foam: X Fog: X Hazardous Cont~Jstion Products: NAP Fire Fighting Procedures: WEAR SELF-CONTAINED POSITIVE PRESSURE BREATHING APPARATUS ANO FULL FIRE FIGHTING PROTECTIVE CLOTHING FOR ENCLOSED AREAS. Unusa[ Fire and ExpLosion Hazards: NAP V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under ghich Conditions? NAP IncompatibLity (Materials to Avoid): STRONG OX%DAMTS Hazardous Oecon~osition or Byproducts: THERMAL DECOMPOSITION OR COMBUSTION MAY PRODUCE CARBON MONOX%OE, CARBON DIOX%DE,.AND OXIOES OF NITROGEN. Hazardous Polymerization - May Occur: Wi[[ Not Occur: X Conditions to Avoid: NAP MiLpark Drilling FLuids Supplier: MILl ARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 390~ Essex Lane Houston, Texas 7702? Hou: ton, Texas 77027 Emergency Telephone: 71~1/439-8000 Emergency Tel. ~one: 713//+39-8000 VI. - HEALTH HAZARO DATA: NEW-TROL Carcinogen - NTP Program: NAP Carcinogen - IARC Program: NAP Symptoms of Exposure: MAY CAUSE MILO IRRITATION TO MUCOUS MEMBRANES, SKIN AND EYES. Medical Cor~litions Aggravated By Exposure: NAP Emergency and First Aid Procedures: Eyes: FLUSH IJITH CLEAN RUNNING WATER FOR AT LEAST FIFTEEN MINUTES ANO CONTACT A PHYSICIAN IF IRRITA' ION PERSISTS/DEVELOPS. Skin: WAHS WITH SOAP ANO WATER S~aLLow: ORINK LARGE QUANTITIES OF WATER ANO CONTACT A PHYSICIAN. Breath: REMOVE TO'FRESH AIR ANO TREAT SYSTEMATICALLY. VIZ. o ENVIRONMENTAL PROTECT]OIl PROCEDURES: Spi IL Response: NORMAL CLEAN-UP PROCEOURE$ FOR ORY PRODUCTS - S~EEP, VACL~, ETC. Waste OisposaL Method: OISPOSE IN ACCONOANCE I~ITIt LOCAL, STATE ANO FEOERAL REGULATIONS. Handling and Storage: FOOD~ BEVERAGES ANO TOBACCO PROOUCTS SHOULO HOT BE CARRIEO~ STOREO OR CONSUMEO WHERE PRODUCT IS IN USE VI !!. - SPECIAL PROTECTION INFORMATION: CLothing: LAUNDER BEFORE REUSE Eye: SPLASH GOGGLES OR FACE SHIELD WHEN EYE CONTACT MAY OCCUR. Foot,ear: NORMAL Other: NAP Kno~ Hazards Under 29 CFR 1910.1200 I HMIS NFPA I ' /yes/ IYest ............................................. ........................ t'"t ......................... 1'"1 Health: I Health: 1 J Combustible Liquid ! Skin Hazard FLammability: 0 FLammability: 0 I Flammable Material J Eye Hazard X Reactivity: 0 Stability: 0 J Pyrophoric Material I Toxic Agent Personal Protection: B Special: I Explosive Material j Highly Toxic Agent ................................................... I Unstable Material Sensitizer ~ater Reactive MateraL Carcinogen Oxidizer J Reproductive Toxin Organic Peroxide j Btocd Toxin Corrosive Material Nervous System Toxin Compressed Gas Lur~ Toxin Irritant J Liver Toxin Nuisance Oust Xj Kidney Toxin ........................ ~--d ......................... ~---! ......................................................................... Physical & Health Hazard - SARA 40 CFR Part 370 (Check all that apply) (NOTE (*) indicates TLV for nuisance dust only) Fire: Sudden Release Of Pressure: Reactivity: I~nediate(Acute): X Dele, ed(Chronic): IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contaminated Equipment: NAY Other Precautions: AVOID BREATHING DUST. ~ / X. - APPROVAL: Prepared By: Safety Department Code: 1219906 Date Prepared: 05:/01/91 Su ercedes Issue Date: 05/02/90 MILPARK" MATERIAL SAFETY DATA SHEET DRILLING FLUIDS A Baker Hughes company Mikpark Dri fling FLuids SuppLier: MILPARK DRILLI#G FLUIDS :~900 Essex Lane, Suite :~00 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/z,39-8000 Emergency TeLephone: 713/439-8000 I. - MANUFACTURER'S INFORMATION: Product Name: PAPER CAS Nunber: NAV Code: 1216800 Chemical Name: GROUNO PAPER Chemical Description: A LOST CIRCULATION MATERIAL. DOT Hazard CLass: NAP Shipping Id. No. - UN: NA: DOT Proper Shipping Name: I%. - %#GREDIENTS: NONE NAP INAP I#AP IHAP INAP NAP NAP I#AP /NAP IHAP INAP NAP NAP I#AP INAP IHAP INAP NAP NAP I#AP INAP I#AP I#AP ............................................................... ......... ......... ......... ................. ............ ~:~?~.~.!~.~?.~!~.~?~!: ..................... ~!~: .... [ .... ~ .... I_~:..~_.L~:I..~LI.~LL.~..: ......... HAP NAP NAP INAP INAP NAP HAP NAP NAP INAP INAP NAP NAP NAP I#AP INAP I#AP I#AP NAP NAP ~NAP I#AP I#AP INAP NAP NAP I#AP INAP I#AP INAP III. - PHYSICAL DATA: Boiling Point(F): NAP Vapor Pressure(n~Hg): HAP Specific Gravity: 0.:]6 PH: NAP MeLting Point(F): NAP Vapor Oensity(Air=l): HAP Perce~t VoLatiLe By VoL~e(~): NAP Freezing Point(F): NAP SoLubiLity In Uater: HAP Evaporation Rate: ( = 1): NAP Odor ThreshoLd: NOT KNOWN Appearance And Odor: GROUND/PAPER gOOR Material Is:. PURE-SOLID Coefficient of ~ater/Oi[ Distribution: INSOLUBLE ]N kIATER ]V. - FIRE & EXPLOSION HAZARD DATA: FLashpoint(F): NAP Auto Ignition Temperature(F): NAV FLammabLe Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAV Sensitivity To Impact: NAP Extinguish Media - ~ater: X C02: X HaLon: Dry ChemicaL: X Foam: X Fog: Hazardous Combustion Pr_e~__~_ts: NAP Fire FightingProcedures: TREAT AS BURNING PAPER Unusa[ Fire and ExpLosion Hazards: NONE V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under ~hich Conditions? Incompatibtity (MateriaLs to Avoid): NONE Hazardous Decomposition or Byproducts: SMOKE~ CO2 HazaVdous PoLymerization - May Occur: ~iL[ Hot Occur: X Conditions to Avoid: NAP Mi[park DriLLing FLuids SuppLier: MILFARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATER[AL SAFETY DATA SHEETS Address: 390C Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency TeLephone: 713/439-8000 Emergency Te[E ~o.ne: 713/439-8000 Vl. - HEALTH HAZARD DATA: PAPER Carcinogen - NTP Progrma: NAP Carcinogen - IARC Progrm: NAP Symptoms of Exposure: SMOKE MAY BE IRRITATING TO EYES ANO RESPIRATORY TRACT. Medical Conditions Aggravated By Exposure: NAP Emergency and First Aid Procedures: Eyes: FLUSH WITH CLEAN RUNNING WATER TO REMOVE PARTICLES ANO CONTACT A PHYSICIAN IF IRRITATION OEVELOPS/PERSISTS, Skin: WASH AFFECTED AEAR WITH WATER. CONTACT A PHYSICIAN, S~at[o~: NAP Breath: REMOVE FRON EXPOSURE TO FRESH AlE AND TREAT ACCORDING TO SYMPTOMS. VII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spit[ Response: COLLECT AND CONTAIN AS ANY PAPER PROOUCT. Waste Disposal Method: MAY BE DEPOSITED IN A LAND FILL. HandLing and Storage: KEEP AWAY FRON OPEN FLAMES. VIII.'- SPECIAL PROTECTION INFORMATION: Respiratory Protection: NIOSH/MSHA APPROVED PARTICULATE RESPIRATOR IF DUSTY CONOITIONS EXIST. VentiLation: LOCAL EXHAUST CLothing: NORNAL GLoves: AS NEEDED FOR COMFORT Eye: SAFETY GLASSES Foot,ear: NORMAL Other: AS NEEDED Kno~a~Hazards Under 29 CFR 1910.1200 lyes| IYest ............................................. ........................ t---f ......................... t---I HeaLth: 0 HeaLth: 0 / Combustib,e Liquid I Skin Hazard I F[a~abi[ity: 0 Ftmmmbi[ity: 0 F[mmmb[e Material Eye Hazard Reactivity: 0 StabiLity: 0 ExpLosive Nateria[ HighLy Toxi~ Agent ............................... UnstabLe #ateriaL I Sensitizer k~ater Reactive MateraL Carcinogen Oxidizer I Repr_~9__~_tive Toxin I Organic Peroxide i BLood Toxin I Corrosive Material Nervous Systm Toxin I Co~pressed Gas Lung Toxin Irritant I Liver Toxin ........... l-f- ............ ......................................................................... Physical & ~ea[th Hazard o SARA 40 CFR Part 370 (Check ail that apply) (NOTE (*) indicates TLV '=or nuisance dust on[y) Fire: Sudden Re[ease Of Pressure: Reactivity: I~nedJate(Acute): * De[ay~(Chronic): IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contmainsted Equipment: NAV Other Precautions: __:::=Z::::::: .............................................................................. MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., Suite 300 Emergency Telephone: (713) 439-8900 IJ~ Houston, Texas 77040 SAPP CHEMTREC: 1-800-424-9300 - NANUFACTURER'S IgFORHATIO#: #anufacturer: BAKER HUGHES IMTEQ H#IS Hazard Rating ges[th 0 Ninimai - 0 Product Name: SAPP and Key: FLammability 0 SLight - 1 ChmicsL Name: SOOIUM ACID PYROeHOSPHATE Reactivity 0 Noderate - Chemical Description: DEFOCCULANT/CALC%UN PRECIPITANT *' Persona[ Seriom - 3 Protection E Severe - Proper Shipping Description: DR%LLI#G FLUID COMPOUgD, g.O.S. Hazard CLass: HOT REGtJLATED UN #uaber: HA Hazard LabeL: gA DOT Response Guide: HA Transportation Note: gA II. - HAZARD IDENTIF]CATIOH: Hazards Associated with Product Use Yes Ye~ Yes Yes CombustibLe Liquid FLammable #ateriat Pyrophoric #ateriaL Explosive #ateria[ - Unstable #ateria[ t~ater Reactive #ateria[ Oxidizer ' Organic Peroxide Corrosive #ateriaL Compressed Gas Irritant X Nuisar~e Particulate Skin Hazard X Eye Hazard X Toxic Agent Highly Toxic Agent Sensitizer Carcinogen Repr-~--~-tive Toxin B[ocd Toxin Nervous System Toxin Lung Toxin Liver Toxin Kidney Toxin Con~dnity Right-to-Kno~ (SARA Title I[I Section 311-312) . .re: Sudde~ Release Of Pressure: Reactivity: Immediate (Acute): X Delayed (Chronic): III. - PHYSICAL DATA: Boiling Point(F): gA Vapor Pressure(rm~lg): gA PH: gelling Point(F): /~28 Vapor Oer~ity(Air=l): HA Specific Gravity: 1.9 Freezing Point(F): 1202 Solubility In t/stet: APPRECIABLE Percent Volatile By VoLmm(X): gA Odor Threshold: HO Appearance And Odor: I~HITE, OOORLESS Evaporatien Rate ( · 1): gA Material is: PURE-POkiER Coefficient of I, later/Oil Distribution: INSOLUBLE IH OIL IV. - FIRE & E. XPLOSION HAZARD DATA: FLashpointCF): gA Auto Ignition Temperature(F): RA FLmmmb[e Limits - LFL: NA UFL: NA Explosion - LEL: HA UEL: NA Extinguish Nedia - Water: X C02: X Dry Chemical: X Foam: X Fog: X Hazardous Combustien Products: HONCOMBUSTIBLE. SOOIUN Ago PHOSPHORUS OXIOES 14A¥ FORM AT DECC~4POSITION TEMPERATURES. Fire Fighting Procedures: CCI4PATIBLE VITH AGENTS USED TO EXTI#GUISH SURROUNOING FIRES. USE WATER TO COOL FIRE EXPOSEO CONTAINERS. Unusual Fire and Explosion Hazards: NONE REPORTED. V. - REACTIVITY DATA: ChemicaLLy StabLe: Yes: X Ho: If no, Under ghich Conditions? NONE REPORTED. Incaapatib[ity (NaterJa[$ to Avoid): AVOID ACIDS. ~'~r~J~ Decempo~Jtio~ or Bypreducts: PRC~UCT WILL NOT READILY DECOMPOSE. ~'l~a~ardous PoLweerization - Nay Occur: gilt Hot Occur: X Conditio~ to Avoid: NA ND - Not Determined gA -_. Hot Applicable T - Total Dust R - Respirab[e Fraction C - Ceiling Limit Page 1 ~ SAPP . VI. - HEALTH HAZARD INFORMATION: Primary Exposure Route - Skin Contact: X Skin Absorption: Eye Contact: X lnl elation,: X Ingestion: pr_~k__~_t CarcJnogonicity- NTP: NO IARC: NO Acute Effects of Overexposure: PRODUCT CAN IRRITATE EYES, SKIN AND UPPER RESPIRATORY TRACT. DUST INHALATION CAN LEAD TO BRONCHIT] S, EMPHYSEMA, AND ASTHI4A. DERI4ATITIS CAN RESULT FRC~4 SHORT CONTACT PERIGOS. INGESTION MAY CAUSE NAUSEA, ¥ONITING AND OIARRHIA. Chronic Effects of Overexposure: SOME PARTICULATE OUSTS MAY CAUSE ALLERGIC SENSITIZATION OF SOME INDIVIDUALS, CHARACTERIZED EITHER BY BREATHING DISTRESS OR TOPICAL SKIN IRRITATION SYMPTOMS. VII. - EMERGENCY AND FIRST AID INSTRUCTIONS: Eyes: HOLD EYELIDS APART A#O FLUSH EYES WITH ~IATER FOR AT LEAST 15 NIHUTES. CONSULT A pHYSIcIJN IF IRRITATION PERSISTS. Skin: WASH THOROUGHLY WITH MILD SOAP AND WATER. APPLY MEDICATED CREAMS TO RELIEVE IRRITATION IND REPLENISH SKIN OILS. Ingestion: GIVE FLUIDS TO RINSE MOUTH AND'THROAT IRRITATION AND TO DILUTE. INDUCE VOMITING I~IT# A~VICE FROM A PHYSICIAN. InhaLation: NaVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GIVE OXYGEN IF BREATNIIG IS DIFFICULT. VI!I. - ENVIRONNENTAL PROTECTION PROCEDURES: spa I. [ Response: WEAR PROPER PROTECTIVE EQUlPNENT (SECTION IX). RECOVER SPILLED NATERIAL TO THE ORIGINAL CONTAINER FOR SALE IF POSSIBLE OR TO A SUITABLE T~ASTE CONTAINER. MININIZE DUSTING DURING CLEANUP. FLUSH RESIDUE WITH T~ATERo Waste Disposal Nethod: PRODUCT IS NOT HAZARDOUS ACCORDING TO RCRA CRITERIA OR LISTING AS SUPPLIED. DISPOSE OF ACCORDING LOCAL, STATE AND FEDERALi.' ATIONS DEALING ~/ITH A WASTE PRODUCT. HandLing: '~-'. CAUTION! MAY CAUSE NEC~UIICAL EYE, SKIN AND RESPIRATORY IRRITATION. AVOID CONTACT ANO ~IEAR PROPER ROTECTIVE EQUIPNENT. AVOID BREATHING DUST. Storage: KEEP OUSTS TO A NIHIMUM. KEEP CONTAINER CLOSED WHEN NOT IH USE. USE WITH ADEQUATE VEHTILATION. IX. - OCCUPATIORAL CONTROL MEASURES: Respirat Prot~ti~ P T RES %RAT~ % EX ITS F~ ~F~T. V~tJiati~: ' ~PPLY ~NTI~TX~ NEEDED TO ~[NTAIN SAFE EXPO~RES TO NUI~N~ PARTI~TES. C[othi~: ~ L~G PROTECTX~ CLOTHING ~ITH AN APR~ F~ ~DED PROTECTX~. ~NOER LATHES BEF~E R~SE. Ey~er: ~R CHENI~L SAFETY ~GLES ~ G~SSES ~[TH SIDE--DS. [N~RE A PRIER F Gtov~: ~ GL~S TO PRE~NT NEC~NI~L SKIN ]RRITAT]~. F~t~ar: Other Neasur~:' USE ~ PER,AL HYGIENE. ~ASH AFTER HANDLING AND BEF~E NEALS ~ BR~S. U~ ~PR~R[ATE CLOSERS TO ~SH OFF PR~UCT AND [NC~TE SKIN ~IT[( 4ERS INTO HYGIENE. O I SCLA l HER The stat~ts, info--tim, ~ ~te provi~ in thia ~teria[ safety ~te sh~t are ~ie~ reLii ZNTEQ ~ its res~-~ibte ~rs~L; h~ver, ~ other g~rentee, r~res~tati~, ~rrant'y or res~aibiLity to ~ ~er, r~ard[~s of reLi~e ~ aK[ or ~ ~rt ther~f. This i~[~a ~rr~ti~ of ~rchm~tabiLJty or of firms for ~rticuLar ~r~e, ~ Baker H~h~ INTE~ ess~ ~ res~ibitity ~etever for ~ice or r~tj~ ~. NothJ~ c~tai~ herein ~[d ~ inter~et~ es ~missi~, i~t, or c~t to violate ~ Leu ~rs~t o thJe No - Not DetemJ~ ~ - Not ~[ic~[e > - Greeter Th~ ( -Lm Th~ C - ~JLi~ LJaJt MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., Suite 300 Emergency Telephone: (713) 439-890u I~ Houston, Texas 77040 POTASSILIN CHLORIDE CHEMTREC: 1-800-424-9300 - MANUFACTURER'S INFORMATION: Manufacturer: BAKER HUGHES %HTEO HM%S Hazard Rating Health 0 Minimal - 0 pr_~ck__~_t Name: POTASS%UI4 CHLOR%DE and Key: F[a~r~bJLity 0 SLight - 1 ChmicaL Name: POTASSIUM CHLORIDE Reactivity 0 Moderate - 2 Chmicei Oeecription: AL[ALI METAL CHLORIOE Perso~i Serious - ] Protection F Severe - 4 Proper Shipping Description: DRILLIHG FLUID COl4POUHO, #.O.S. Hazard CLass: NOT REGULATEO UN #[a~ber: NA Hazard Label: NA DOT Reside Guide: NA Tr~portetian Note: NA Il. - HAZARD IDENTIFICATION: ...... ' ................................,:RO . . Hazards Associated with Product Use Yes Yes Yes - Yes Combustible Liquid FLammable Material Pyrophoric Material Explosive Material Unstable Nateria[ Water Reactive Material Oxidizer Organic Peroxiche Corrosive Material Cc~npressed Gas Irritant Nuis~e Particulate X Skin Hazard Eye Hazard Toxic Agent Highly Toxic Agent Sensitizer Carcinoge~ Reproductive Toxin BLood Toxin Nervous System Toxin Lung Toxin. Liver Toxin Kidney Toxin CoamJnity Right-to-Knou (SARA Title III Section 311-312) ,re: SL__~Jde~_ Release Of Pressure: Reactivity: In,mediate (Acute): X Delayed (Chronic): LTl. - PHYSICAL OATA: Boiling Point(F): 2732 Vapor Pressure(mmHg): NA PHc 9.2 (l~L~OL) Melting Point(F): I&Z~ Vapor O~ity(Air·l): HA Specific Gravity: 1.98 Freezing Point(F): KA Solubility In Water: APPRECIABLE Percent Volatile By Vol~mae(%): NA Odor Threshold: NONE Appearance And Odor: WHITE, O00RLESS Evaporation Rate ( · 1): NA Material Is: PURE-~OLID Coefficient of Water/Oil Distribution: INSOLUBLE IN OIL IV. - FIRE & EXPLOSIOR HAZARD DATA: FLashpoint(F): NA Auto Ignition Teatoerature(F): NA FtamnabLe Limits - LFL: NA UFL: NA Explosion - LEL: NA UEL: NA Extinguish Nedia - Water: C02: Dry Chemical: Foam: Fog: Hazardous Combustion Prodta:ts: THIS MATERIAL IS NONCOMBUSTIBLE. DECOMPOSITION MAY PROOUCE TOXIC SM(~CE ANO IRRITATING FUMES. Fire Fighting Procedures: WEAR POSITIVE PRESSURE SELF-CONTAIHEO BREATHING APPARATUS AND STRUCTURAL FIRE FIGHTING PROTECTIVE CLOTHING I# ENCLOSED OR CONFINED AREAS. Unusual Fire end Explosion Hazards: WHEN HEATED TO DECCMPOSITIOR, PRGOUCT EMITS TOXlC FUMES OF POTASSILJM OXIDE AND CHLORINE ~S. V. - REACTIVITY DATA: ChemicaLLy StabLe: Yos: X No: If no, Under ghich Coalitions? NONE REPORTED. lncompatibLJty (Nateria[s to Avoid): HOT NITRIC ACID MAY EVOLVE TOXIC NITROSYL CHLORIDE. AVOID OTHER STRONG ACIDS. ".~arck~a~ Decoe~oo~itJon or Bypr_-~-__~:ts: NONE REPORTED. ::~.*d~mrdou~ Poty~erization - Nay Occur: Will Hot Occur: X Condition~ to Avoid: NONE REPO~TED. ND - Not Determined NA - Not Applicable T - Total Dust R - Respirabte Fraction C - Ceiling Limit Page 1 : POTASSZUN CHLORIDE VI. o HEALTH HAZARD IHFORHATIOR: Primary Exposure Route - Skin Contact: X Skin Absorption: Eye CorttKt: X Ir~l[ition: X Ingestion: Pr_~k_xc CarcinogeniciCy - NTP: NO IARC: NO Acute Effects of Overexposure: IRRiTATiON OF THE EYES, SKIN, NASAL PASSAGES, AND TRACHEA. SHALLOWING A LARGE AJ~OUNT OF POTASSIUI CHLOEZDE NAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT, CRAHPS, DIARRHEA, TINGLING OF HANDS O~ FEET, AND UEAE PULSE. Chronic Effects of Overexposure: VERY HIGH CONCENTRATIONS OF DUST NAY CAUSE PERFORATION OF THE NASAL SEPT,. LORG-TER# EXPOSURE T HIGH CONCENTRATIONS C~ULD CAUSE CHRONIC COUGH AND HILD BRONCHITIS. THERE IS NO EVIDENCE OF PERI4ANENT LUNG DAHAGE DUE TO LO ~:-TER# EXPOSURE TO KCL. VII. - EHERGEHCY AND FIRST AID INSTRUCTIONS: Eyes: FLUSH WITH CLEAN RUNNING WATER FOR AT LEAST 15 MINUTES AND CONTACT A PHYSICIAN IF IRRIT~TIOR DEVELOPS OR PERSISTS. Skin: WASH THOROUGHLY WITH 'SOAP AND WATER. REHOVE CONTAHINATED CLOTHING AND LAUNDER. Ingestion: DRINK LARGE AHOUNTS OF WATER TO DILUTE. IF A LARGE AHOUNT IS SVALLCX/ED, INDUCE VOHITING AND CONSULT A PHYSICIAN. In, eLation: REHOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS DIFFICULT. CONSULT A PHYSICIAN IF PATS :HT DOES NOT RECOVER OUIC[LY. VII[. - E#VIRONHENTAL PROTECTION PROCEDURES: Spi i I Response: CONTAIN THE SPILL. SV~EP, SHOVEL OR VACUUH THE HATERIAL INTO A SUITABLE VASTE CONTAINER. REBAG OR RECYCLE IF POSSIBLE. RINSE RESIDUES WITH HUCH WATER FOR DILUTION. gaste Disposal Hethod: THiS PROOUCT IS NOT HAZARDOUS ACCORDING TO RCRA CRITERIA OR LISTING AS SUPPLIED. DISPOSE OF FEDERAL REGULATIONS. : Handl inN: 'CAUTION! HAY CAUSE HECHANICAL EYE, SKIN AND RESPIRATORY SYSTER IRRITATION. AVOID UNNECESSARY CON1 kCT. Ur. AR PROPER PROTECTIVE EGUIPHENT STATED IN THE HSDS. Storage: STORE IH A DRY LOCATION TO AVOID CAKING AND DISSOLUTION. KEEP CONTAINER CLOSED. NO TENPERATURE L! UTS. USE ~/ITH ADEGUATE VENTILATION. IX. - OCCUPATIONAL CONTROL HEASURES: Respiratory Protection: WEAR AH APPROVED PARTICULATE RESPIRATOR IF RECC~#ENDED EXPOSURE LIHITS HA~ BE EXCEEDED. Ventilation: * USE ADEGUATE LOCAL ON #ECHANICAL EXHAUST IF RECOleqENDED EXPOSURE LIlelT$ NA BE EXCEEDED. Clothing: gEAR LONG PROTECTIVE CLOTHING WITH AN APRON OR COVERALLS FOR ADDED PROTECl Eye-ear: gEM SAFETY GOGGLES IF DUST CONCENTRATIONS ARE HIGH. Groves: gEAR GLOVES TO PREVENT SKIN IRRITATION. Foot~eear: gEAR NORNAL SAFETY BOOTS. Other Heasures: USE GO(X) PERSONAL HYGIENE. WASH AFTER HANDLING AND BEFORE HEALS OR BREAKS. LAUNDER CLOTHES BEFORE REUSE. USE APPROPRIATE HILD CLEANSERS TO gASH OFF I~ODUCT. X. - ADDITIONAL INFORNATION: DISCLAIHER The statements, information, and data provided in this material safety data s~eet are believed tel: ~b[e end Kcurate by Baker Hughes INTEG and its respormible personnel; however, no other guarantee, representation, ~arranty or reSl~ibJtity Jm expressed or implied to any user, regardless of reliance on ail or any part thereof. This includes ~erranties of particular purpose, mqd Baker Hughes INTEG essc~m~ no respe~sibility k~natever for ~dvice or recemm~clatiorm mmda. #Gibing contained herein shou[d be interpreted es permission, inducement, or concJoneme~t to violate ~rpy La~ peraumnt to thJm produgt~ u~e, cMw~*-~ce or dj sposa[. Prepared By: Jim Ruling Date Prepared: 0]11719~ Supercedes Issue Date: 05/02/90 ND - #o~ Determined NA - Not App[JcmbLe · - Greater Thm~ < - iLm Thm~ C - Ceiling Limit P~ge / S551211 ~--'-.~ E~&E] 23 · HEALTH 0 FL~,~4ABILITY 1 REACTIVITY 0 PERSONAL PROTECTION B ' SAWDUST ' SECTION I - PRODUCT IDENTIFICATION Synonyms : Sawdust CASS : ~,.]ultip!e Formula : Variable Unit of Issue: ~qultiple Application : Lost circulation Chemical Family: Cellulose material Warning WARNING! ~UISANCE DUST! Avoid high dust concentration. Minimize con~ac~ with eyes, skin, and clothing. Keep away from heat, sparks, and open f 1 ame. SECTION II - HAZARDOUS INGREDIENTS COMPONENT PERCENT (%) TLV Reference Cellulose 100 10 mg/m3 ACGIH (Nuisance dust) TRANSPORTATION INFORM3%TION Classified as a hazardous material according to DOT(49 CFR 172): X'YES NO Proper shipping name: Sawdust Hazard Class : ORM-C Identification No. : None Labels required : None IMCO class : None IATA class : None SECTION III - PHYSICAL PROPERTIES Appearance & color : Brown hulls Odor : Odorless Solubility in water: Insoluble Melting point : N/A Boiling point : N/A Vapor pressure(~-~m I!g): H/A Evaporation rate : N/A % Volatile (by vol.) : ~4/'A Vapor density : N/A Specific gravity : 0.24 pH : N/A ~SECTION IV - FIRE & EXPLOSION HAZ~qD INFORI~TION Flash point : ~.D. Autoignition temp : N.D. Flammable limits (% by vol.): H.D. Decomposition temp: ~;.D. Extinguishing media : Water, carbon dioxide, dry or chc;nical foam Fire & explosion hazards : Treat as flammab!~ du~t'.~han in the suspended state. SA~DUST page 2 SECTION'~V .- HEALTH HAZARD INFORbLATION Routes of Entry: Inhalation X Ingestion Skin & E re Contact Acute effects of overexposure: ~o data available. .First aid: Eyes : Skin : None required. Inhalation: Ingestion : · Additional comments: Follow suggested precautions for nuis .nce dust. SECTION VI - REACTIVITY DATA Stability YES(X) NO( ) Undergoes Polymerization: YES( ) NO(X) Incompatible materials: Heat, oxidizing agents. Hazardous decomposition product's: None reported. · SECTION VII - SPILL OR LE~K PROCEDURES Xeep dust to a minimum. S%~eep into a waste container. Waste Disposal Disposal should be in accordance with federal, state and t~cal regulation~ This material is not listed as a hazardous material, as defined in Section~ 101 (14) of the Comprehensive, Environmental Response, Co~oensation, Liability Act (CERCLA) of 1980. SECTION VIII - PERSONAL PROTECTIVE EQUIP~.~NT Wear cotton gloves and particle dust mask for comfort. P~rsonai Protection Index "B". SECTIOi'~ XI - SPECIAL PRECAUTIOn.IS ~ Handling & storage: Store in a cool, dry area. Keep dust to a minimum. Other regulatory agency controls: DOT: Hazardous ~qaterials Table 49 CFR 712.101. Data Sheet Issued: 01/17/86 MILPARK' DJEILLING FLUIUS MATERIAL SAFETY DATA SHEET A Baker Hughes company MiLpark Drilling FLuids Supplier: MILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027' Houston, Texas 77027' Emergency Telephone: 713/439-8000 Emergency Telephone: 713/439-8000 I. - MANUFACTMRERVS I#FORMATIOfl: Product Name: SOOA ASH CAS Nt~ber: 497-19-8 Code: 1218~90 Chemical Name: CONTROLS ALKALINITY OF DRILLING ~ Che~i cal Oescr i pt i on: SOOIUM CARBONATE, NA2C03 ALKALINITY CONTROL AGENT. CALCIUM AND MAGNESIUM REMOVER FROM WATER SASE I~10. DOT Hazard CLass: NAP Shipping Id. No. - UN: MA: DOT Proper Shipping Name: ]I. - INGREDIENTS: ............ ........ 1 .... ......... ......... .... ........... SODIUM CARBONATE /NAP NAP NAP I>1OO 1497-19-8 NUISANCE PARTICLES PEL TWA 8 HR. 15 MG/M3 JNAP NAP NAP INAP JNAP TOTAL DUST PEL TWA 8 HR. 5 #G/I,~ INAP NAP NAP NAP JNAP TOTAL DUST TLV TWA 8 HR. 10 MG/M3 ]NAP NAP NAP NAP INAP .............................. l": ........ . 11": .... NAP INAP NAP INAP NAP INAP NAP INAP NAP INAP NAP INAP HAP INAP I#AP IRAP IMAP INAP NAP ~NAP INAP INAP INAP INAP NAP INAP INAP INAP INAP INAP III. - PHYSICAL DATA: Soiling Point(F): NAP Vapor Pressure(llmlHg): NAP Specific Gravity: 2.5 PH: 11.3 Melting PointCF): 1564 Vapor Density(Air=l): NAP Percent Volatile By VoLune(%): NAP Freezing Point(F): 1569 Solubility In Water: SLIGHTLY Evaporation Rate: ( ... = 1): NAP Odor Threshold: NAP Appearance And Odor: O00RLESS WHITE CRYSTALS Material IS: MIX-P(YdDER Coefficient of Water/Oil Distribution: NAP IV. - FIRE & EXPLOSION HAZARD DATA: FLashpoint(F): NAP Auto Ignition TemperstureCF): NAP FLammable Limits - [FL: NAP UFL: NAP Explosion - LEL: NAP UEL: NAP Rate Of Burning: NON FLN~MABLE Sensitivity To Impact: NAP. Extinguish Media - Water: X C02: X He[on: Ory ChemicaL: X Foam: Fog: X Hazardous Canbustion Proclucts: HEATING LIBERATES C02 Fire Fighting Procedures: USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE, AND WEAR SELF CONTAINED BREATHING APPARATUS. UnusaL Fire and Explosion Hazards: NAP V. - REACTIVITY DATA: Chemical Stab[e: Yes: X No: If nc, Under Which Conditions? HAY REACT VIOLENTLY WHEN NEUTRALIZED WITH ACIDS; CARSON DIOXIDE AND HEAT MAY BE EVOLVED. CAN REACT VIOLENTLY WITH RED HOT ALUMINUM METAL AND PHOSPHORUS PENTOXIDE. lnc~tib[ity (MateriaLs to Avoid): HEAT, HOT ALUMINUM METAL, FLLI&qlNE GAS, LITHIUM AND PHOSPHORUS PENTOXIDE. Hazardous Oeconq=osition or Byproducts: HEAT LIBERATES C02 Hazardous Polymerization - May Occur: Will Not Occur: X Conditions to Avoid: REACTS WITH HYDRATED LIME IN THE PRESENCE OF MOISTURE TO FORM CAUSTIC SOOA. IN THE PRESENCE OF MOISTURE AND C02 WILL FORM SOOIUM BICARBONATE. Mi[park DriLLing FLuids SuppLier: MIL) ARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 MATERIAL SAFETY DATA SHEETS Address: 3901 Essex Lane Houston, Texas 77027 Hou: ton, Texas 77027 Emergency TeLephone: 713/Z~39-8000 Emergency Teb ~one: 713/z~39-8000 VI. - HEALTH HAZARD DATA: SOOA ASH Carcinogen - NTP Program: NAP Carcinogen - IARC Program: HAP Symptoms of Exposure: IRRITATES SKIN, EYES, NOSE, THROAT AND LUNGS. INGESTION NAY CAUSE NAUSEA, VOMITING, STOMACH ACHE, O[~RRHEA. SOOA ASH IS LOW IN T OXICITY, BUT CAN BE HARMFUL. Medical Conditions Aggravated By Exposure: EXCESSIVE CONTACT NAY PROOUCE SODA ULCERS ON HANDS AND PERFORATION OF NASAL SEPTUN. SENSITIVITY REAC 'IONS NAY OCCUR FROM PROLONGED AND REPEATED EXPOSURE. Emergency and First Aid Procedures: Eyes: FLUSH WITH LARGE AMOUNTS OF CLEAN WATER FOR AT LEAST FIFTEEN MINUTES AND CONTACT A PHYSICIAN. Skin: REHOVE CONTAININATED CLOTHING. WASH AFFECTED AREA WITH SOAP AND WATER. SwaLLow: GIVE 2-3 GLASSES OF WATER. DO NOT INDUCE VOMITING. CONTACT A PHYSICIAN. Sreath: REHOVE TO FRESH AIR. RESTORE AND/OR SUPPORT BREATHING CONSULT A PHYSICIAN. VII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spi [ [ Response: NORMAL CLEAN-UP PROCEDURES FOR DRY PROOUCTS- SUEEP, VACUUH, ETC. WEAR PROTECTIVE EGUIPflENT. Waste Disposal Methed: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIOMS. HandLing and Storage: KEEP CONTAINER COVERED AND KEEP PRODUCT DRY. IF ADDING TO WATER DO SO SLOULY. VIII. - SPECIAL PROTECTION INFORMATION: ,~ Respiratory Protectien: NIOSH/NSHA APPROVED PARTICULATE OR MIST RESPIRATOR. Ventf [aLien: LOCAL EXHAUST CLothir~: TO PREVENT EXTENDED CONTACT GLoves: COTTON GLOVES FOR DRY CONDITIONS. RUBBER FOR ILUTIONS. Eye: SAFETY GLASSES GOGGLES * NO CONTACT LENSES Foot,ear: FOR COMFORT Other: LONG SLEEVE SHIRT AND TROUSERS. Knoun Hazards Under 29 CFR 1910.1200 ........................ .Y.e~.! ............................. HeaLth: 2 HeaLth: 2 CombustibLe Liquid Skin Hazard X FLanmabLe MateriaL Eye Hazard X J Reactivity: 0 / StabiLity: 0 ExpLosive Material HighLy Toxic Agent ...................... UnstabLe MateriaL Sensitizer Water Reactive )lateraL Carcinogen I Oxidizer Reproductive Toxin Organic Peroxide BLood Toxin I Corrosive Material X Nervous System Toxin Compressed Gas Lung Toxin I Irritant Liver Toxin .... . ................. - .................... (.--( ......................................................................... Physical & HeaLth Hazard SARA 40 CFR Part 370 (Check aLL that apply) (NOTE (*) indicates TLV for nuisance dust only) Fire: Sudden ReLease Of Pressure: Reactivity: I~mediate(Acute): X DeLe 'ed(Chronic): IX. - SPECIAL PRECAUTIONS: Precautiog~ For Repair & Maintenance Of Contaminated Equipment: MATERIAL HAS A HIGH PH AND IS CORROSIVE. Other Precaut fo~s: X. - APPROVAL: Prepared By: Safety Department Code: 1218990 Date Pi'epared: 05101/91 Su~ercedes Issue Date: 07125189 MILPARK" DRILLING FLUIDS MATERIAL SAFETY DATA SHEET A Baker Hughes company HiLpark DriLLing FLuids SuppLier: H[LPARIC DRZLL[NG FLU[DS 3900 Essex Lane, Suite 300 14ATER[AL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houstonw Texas 77027 Emergency TeLephone: 713/439-8000 Emergency TeLephone: 713/439-8000 [. - MANUFACTURERWS INFORMATION: Product Name: SOOIUM BICARBONATE CAS Nu~ber: NAV Code: 1219010 Chemical Name: DR[LL%NG FLUID AOD[T%VE Chemical Oescription: SOD %UH B% CARBONATE. DOT Hazard CLass: NAP Shipping Id. No. - UN: HA: DOT Proper Shipping Name: [[. - INGREDIENTS: ,,z,~ ~~ ~o~,~ ~ ~, ~0.~00~= SOO[U~ BICARBONATE NAP /lo mw/m3 NAP HAP INAPI#APINAP INAP NAP NAP INAPINAPNAP NAP NAP NAP INAPINAPNAP NAP ~ .............................................................. ~ ......... l~: ......... I~ ....... 1"~ 1"~: ............... ............ ~e~r~.~e~.!~re.~.~!~.~!: .................... r!~: .... 1 .... NAP NAP NAP NAP INAP NAP NAP NAP NAP NAP INAP NAP NAP NAP INAP NAP HAPINAP NAP NAP INAP NAP NAPINAP NAP NAP INAP NAP INAP INAP ILl. - PHYSICAL DATA: BoiLing Point(F): NAP Vapor Pressure(n~Hg): NAP Specific Gravity: 2.16 PH: 8.6 in I~,SOL MeLting PointCF): NAP Vapor Density(Air:l): NAP Percent VoLatiLe By VoLtage(Z): NAP Freezing PointCF}: NAP SoLubiLity [n Water: SLIGHTLY Evaporation Rate: ( = 1): NAP Odor ThreshoLd: NAP Appearance And Odor: WH[TE/OOORLESS Material Is: PURE-POI~ER Coefficient of Water/OiL Distribution: NAP IV. - FIRE & EXPLOSZON HAZARD DATA: F[ashpoint(F): NAP Auto Ignition Temperature(F): NAP F[aranabLe Limits - LFL: NAP UFL: NAP ExpLosion - LEL: NAP UEL: NAP Rate Of Burning: NAP Sensitivity To impact: NAP Extinguish #edia - Water: C02: Ha[on: Dry ChemicaL: Foam: Fog: Hazardous Conloustion Products: NONE Fire Fighting Procedures: NAP Unusa[ Fire and ExpLosion Hazards: NAP V. - REACTIVITY DATA: Chemical StabLe: Yes: X No: If no, Under Which Conditions? NAP Incompatib[ity (#ateria[s to Avoid): AC[DS - WILL REACT TO PROOUCE C02, SALT AND WATER Hazardous Decomposition or Byproducts= PROOUCT DECOMPOSES WITH HEAT TO PROOUCE CARBON DIOXIDE Hazardous PoLymerization - #ay Occur: Vi[[ Not Occur: X Conditions to Avoid: NAP Hi[park DriLLing Fluids SuppLier: HILl ~RK DRILL%NG FLUIDS ~[900 Essex Lane, Suite ]00 HATER%AL SAFETY DATA SHEETS Address: ]901 Essex Lane Houston, Texas 77027 Hou: ton, Texas 77027 Emergency TeLephone: 713/419-8000 Emergency Te[e ~lone: 71]/419-8000 VI. - HEALTH HAZARD DATA: SOOIUH BICARBONATE Carcinogen - NTP Program: HAP Carcinogen - IARC Program: NAP Symptoms of Exposure: NAP HedJca[ Conditions Aggravated By Exposure: HAP Emergency and First Aid Procedures: Eyes: FLUSH EYES WITH CLEAN RUNNING HATER FOR AT LEAST FIFTEEN HIHUTES HOLD EYELIDS OPEN DURING FLUS~II#G. IF %RRITATIOR PRESISTS CONTACT A PHYSICIAN. Skin: RENOVE CONTANINATED CLOTHING. WASH AFFECTED AREAS V/SOAP & UATER. IF IRRITATION PERSISTS, CONTACT A PHYSIC%A# II4NEDIATELY. S,a[Low: GIVE 1/2 TO 1 GLASS OF WATER TO D%LUTE HATER[AL. DO HOT INDUCE VON%TING. %F VON%TING OCCURS, LEAN FORWARD & RINSE HOUTH, AVO%D%NG BREATH%NG IN VONXTUS,' GIVE NORE WATER. OBTA%N HEDZCAL ATTENT%OR INNEDIATELY. Breath: NOVE TO FRESH A%R. G%VE CPR ONLY %F BREATH%NG AND PULSE HAS STOPPED. G%VE ARTIF%CIAL RESP%RArION ONLY IF BREATH%NG HAS STOPPED. OBTAIN HED%CAL ADVICE %NNED%ATELY. VII. - ENVIRONHENTAL PROTECTION PROCEDURES: Spi [ [ Response: PREVENT FROg ENTER%NG tWATER COURSES OR SEWERS. t/aste Disposal #ethod: D%SPOSE %# ACCORDANCE W%TH LOCAL, STATE AND FEDERAL REGULAT%ONS. Hand]lng and Storage: AS HEEDED. V%I I. - SPECIAL PROTECT%0~ %NFORHATIOR-' ~;~;~;~ ~'~ro-~ i~;~$~H=~=:;P=~O='~ R=~-~I~J~"~ =~ F~-~=~ ..................................................... =' =0 VentiLation: LOCAL EXHAUST CLothing: NORHAL GLoves: AS NEEDED FOR COgFORT. Eye: SAFETY GLASSES W%.TH SIDE SHIELDS. Footuear: NORHAL Other: AS NEEDED. I(nmm Hazards Under ~9 CFR 1910.1200 I H#IS I NFPA I ........................ 1;-"-1 ........................... ................ .............. I Ftanmab[e Ha[aria[ Eye Hazard X Reactivity: 0 Stabftity: 0 Pyrophoric Ha[aria] I Toxic Agent Personal Protection: E~ SpeciaL: I Exptosive #ateria[ j HighLy Toxic Agent .......................... 1 ........................ 1 UnstabLe Ha[erie[ Sensitizer i4ater Reactive Ha[era] Carcinogen Oxidizer ~ Reproductive Toxin Organic Peroxide I BIDed Toxin Corrosive Ha[aria[ Nerv~ System Toxin Compressed Gas Lung Toxin Irritant X I Liver Toxin Nuisance Dust XI Kidney Toxin .... .................... t---t ......................... t---t ......................................................................... Physical & HeaLth Hazard - SARA &O CFR Part ]70 (Check alt that apply) (NOTE (*) indicates TLV for nuisance dust only) Fire: Sudden Re[ease Of Pressure: Reactivity: I~mnediate(Acute): X Deja' ~(Chrenic): IX. - SPEC%AL PRECAUT%ONS: Precautions For Repair & )laintenance Of Contaminated Equipment: HAV Other Precautiom~: USE WITH ADEGUATE VENT%LAT%ON. X. - APPROVAL: Prepared By: Safety Department Code: 1219010 Date Prepared: 05/01/91 Sup.,rcedes Issue Date: 05/02/90 ~MILPARK" MATERIAL SAFETY DATA SHEET DRILLING FLUIDS A Baker Hughes company Mill=ark Drilling Fluids Supplier: NILPARK DRILLING FLUIDS 3900 Essex Lane, Suite 300 HATERIAL SAFETY DATA SHEETS Address: 3900 Essex Lane Houston, Texas 77027 Houston, Texas 77027 Emergency Telephone: 713/439-8000 Emergency Telephone: 713/439-8000 [. - HA#UFACTURERfS INFORHATION: Product Name: SUPER-COL CAS N~nber: NAV Code: 1215190 Chemical Name: BENTONITE CLAY Chemical Description: BENTONITE CLAY DOT Hazard CLass: NAP Shipping Id. No. - UN: NA: DOT Proper Shipping Name: [[. - INGREDIENTS: ............ ~:::L~----L--~----~L!~f~LfL~L!~!?:!f?~!: ............. ~[~: .... 1 .... ~Y: ......... ~: .... I-2LI-~LL-~--: ......... OUARTZ-USE TLV FOR CRYSTALLZNE SILICA NAP 1.1NG/K:3 NAP {<5.0 11&808-60-? ACCORDING TO %. QUARTZ PRESENT OT~ERg~SE NAP JRESPIRABLE .NAP JNAP JNAP TREAT AS NUISANCE PARTICULATES ~ITH TLV- NAP IDUST NAP INAP ]NAP IOHG/H3 TOTAL DUST <1~ QUARTZ, OR 5HG/H.~ NAP JO.~G/I,~ NAP ~NAP ]NAP ~!~.~:~!~.!~:t? ..................................... ~t .........lI~I~L~fI...~ ......... I~L.I~ ................. ............ ~:f~.~?~.!~.~.~.~!~ ..................... ~!~ .... l .... EY~ ...... tL°f~L~I.2LI.~LL.'Z~..: ......... NAP #A" INAP 'NAP INAP INAP NAP NAP INAP NAP INAP INAP NAP NAP INAP ,NAP INAP INAP NAP NAP INAP NAP INAP INAP NAP NAP I#AP NAP INAP INAP III. - PHYSICAL DATA: Boiling Point(F): NAP Vapor Pressure(nmHg): NAP Specific Gravity: 2.6 PH: NEUTRAL Ne[ting Point(F): NAP Vapor Density(Air=l): NAP Percent Volatile By Vo[~ne(~): NAP Freezing Point(F): NAP Solubility In gater: NAP Evaporation Rate: ( = 1): NAP Odor Threshold: NAP Appearance And Odor: TAN/CLAYEY ODOR Materia[ Is: PURE-POUOER Coefficient of Water/Oil Distribution: NAP IV. - FIRE & EXPLOSION HAZARD DATA: F[ashpoint(F): NAP Auto Ignition Temperature(F): NAP Fish.able Limits - LFL: NAP UFL: NAP Explosion - LEL: NAP UEL: NAP Rate Of Burning: NON CONBUSTIBLE Sensitivity To Impact: NAP Extinguish #edia - ~ater: C02: HaLon: Dry Chemical: Foam: Fog: Hazardous Combustion Products: NOllE Fire Fighting Procedures: NAP Unusa[ Fire and Explosion Hazards: NAP V. - REACTIVITY DATA: Chemical Stable: Yes: X No: If no, Under ~hich Conditions? NONE - BECOHES SLIPPERY ~HEN I~ET ~ITH ~ATER. Incempatib[ity (Hateria[s to Avoid): Hazardous Oecomposition DP Byproducts: NAP Hazardous Polymerization - Hay Occur: ~i[L Not Occur: X Conditions to Avoid: HAP Mi[park Drilling FLuids Supplier: MILl aRK ORILLING FLUIDS 3900 Essex Lane, Suite 300 MATER[AL SAFETY DATA SHEETS Address: 39011 Essex Lane Houston, Texas 77D27 Hou=~ton, Texas 77027 Emergency Telephone: 713/439-8000 Emergency Te[~ ~one= 713/439-8000 VI. - HEALTH HAZARD DATA: SUPER-COL Carcinogen - NTP Program: NAP Carcinogen - IARC Program: NAP Symptoms of Exposure: PROLONGED INHALATION OF DUST CONTAINING FREE CRYSTALLINE SILIC MAY RESULT SILICOSIS, A NON CANCEROUS .UHG DISEASE OR OTHER RESPIR- ATORY DISEASE. CONTACT HAY CAUSE IRRITATION TO SKIN AND EYES. Hedica[ Conditions Aggravated By Exposure: SEE ABOVE. Emergency and First Aid Procedures: Eyes: FLUSH gITH CLEAN RUNNING gATER FOR AT LEAST 15 MINUTES TO REMOVE DUST. Skin: gASH AFFECTED AREAS gITH HATER. $~a[[og: CONSULT A PHYSICIAN. Breath: REMOVE FROg EXPOSURE TO FRESH AIR. VII. - ENVIRONMENTAL PROTECTION PROCEDURES: Spilt Response: FOLLOg NORHAL CLEAN-UP PROCEDURES FOR DRY PRODUCTS - SgEEP, VACUUH, ETC. Waste Disposal Method: DISPOSE IN ACCORDANCE gITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling and Storage: AVOID HIGH DUST CONCENTRATION. BECOMES SLIPPERY gHEN WET. VIII. - SPECIAL PROTECTION INFORMATION: Respiratory Protection: WEAR NIOSH/MSRA APPROVED RESPIRATOR IF TLV MAY BE EXCEEDED. Ventilation: LOCAL EXHAUST Ctothing: NORMAL GLoves: OPTIONAL Eye: SAFETY GLASSES WITH SIOESHIELOS OR GOGGLES. Footuear: NORMAL Other: AS NEEDEO %F DESIRED. Knogn Hazards Under 29 CFR 1910.1200 I HMIS I NFPA IYesl /Yest .......................... t ................. ! ........................ ~"'~ ......................... ~'"/ Health: 1 / Health: 1 Combustible Liquid Skin Hazard IFta"eabitity: ° IFtanmabitity: ° FLanmab[e Material Eye Hazard X Reactivity: 0 Stability: 0 Pyrophoric Material Toxic Agent Ipers°na[ pr°tertian: E ISpecial: Explosive Material Highly Toxic Agent .................................................. Unstable Material Sensitizer Water Reactive Materal Carcinogen I Oxidizer Reproductive Toxin Organic Peroxide Brood Toxin I Corrosive Material I Nervous System Toxin I Compressed Gas Lung Toxin Irritant I Liver Toxin I Nuisance Oust X Kidney Toxin .... ~ ................... t"'t ......................... t-'d ......................................................................... Physical & Health Hazard - SARA 40 CFR Part 370 (Check ail that apply) (NOTE (*) indicates TLV for nuisance dust on[y) Fire: Sudden Release Of Pressure: Reactivity: In. fate(Acute): * OeLa ,ed(Chronic): IX. - SPECIAL PRECAUTIONS: Precautions For Repair & Maintenance Of Contaminated Equipment: #AV Other Precautions: MATERIAL BECOMES EXTREMELY SLIPPERY gHEN ~ET. X. - APPROVAL: Prepared By: Safety Department Code: 1215190 Date Prepared: 05/01191 Su3ercedes Issue Date: 03/08190 MATER;AL SAFETY DATA SHEET 7000 Hollister Rd., Suite 300 Emergency Telephone: (713) 439-8900 IJMeJl;~ Houston, Texas 77040 PYROoTROL CHEMTREC: 1-800-424-9300 - I'IANUFACTURER'S INFORMATION: #anufacturer: BAKER IIUGiiES [#TEG H#I$ #azard Rating #es[th 0 #ini~aL - 0 Pr_-~_~t Na~e: PYRO-TROL and Key: FLantmbi[ity 0 SLight - 1 ChmicsL Name: FILTRATION CONTROL AGENT Reactivity 0 #oderate - 2 Cheaicat Description: A/4PS/ACRYLANIDE COPOLYMER PersotmL Serious - ] Protection E Severe - 4 Proper Shipping Description: DRILLING FLUID C~POUND, N.O.S. Hazard CLass: NOT REGULATED UN Ntmber: NA Hazard Label: NA DOT Response Guide: NA Transportation Note: gA . II. - HAZARD IDENTIFICATION: ...... :. ................................ .... ........ Hazards Associated with Product Use Yes Yes Yes Yes Coeloustib[e Liquid FLare. bls Nateria[ Pyrophorio Nateria[ Explosive #ateriaL Unstable NateriaL Water Reactive Nateria[ Oxidizer Organic Peroxide Corrosive NateriaL Compressed Gas Irritant Nuisance Particulate X Skin Hazard Eye Hazard Toxic Agent Highly. Toxic Agent Sensitizer Carcinogen Repr_~_~tive Toxin BLood Toxin Nervous System Toxin Lung Toxin Liver Toxin Kidney Toxin ,~, Conm~ity Right-to-Know (SARA Title III Section 311-312) .re: Sudden ReLease Of Pressure: Reactivity: Xnmediate (Acute): X Delayed (Chronic): Ill. - PHYSICAL DATA: Boiling Point(F): gA Vapor Pressure(mmHg): HA PH: 7.0 NeLting Point(F): lid Vapor Density(Air=l): NA Specific Gravity: 1.4 Freezing Point(F): gA Solubility In Uater: APPRECIABLE Percent Volatile By VoLuae(Z): 10-15 O~or Threshold: NO Appearance And Odor: gHITE POM)ER, ODONLESS Evaporation Rate ( z 1): #A Nateriat Is: PU~E-PO~ER Coefficient of Uater/Oit Distribution: INSOLUBLE IN OIL IV. - FIRE & EXPLOSION HAZARD DATA: F[ashpoint(F): NA Auto Ignition Temperature(F): ND FLenmabLe Limits - LFL: ND UFL: ND Explosion - LEL: ND UEL: ND Extinguish Nedia - gater: X C02: X Dry Chemical: X Foam: X Fog: X Hazardous Combustion Products: UPON COMBUSTION, OXIDES OF CARBONi NITROGEN AND SULFUR NAY FORN, TOXIC SNOKE AND IRRITATING VAPORS. Fire Fighting Procedures: I~AR SELF-CONTAINED POSITIVE PRESSURE BREATHING APPARATUS ANO STRUCTURAL FIRE FIGHTING PROTECTIVE CLOTHING IN ENCLOSED OR CONFINEO AREAS DURING A FIRE. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL ANO TO DISPERSE VAPORS. Unusual Fire and Explosion Hazards: HONE REPOItTED. VD - REACTIVITY DATA: Chemically Stable: Yes: X No: If no, Under ~hich Conditior~? NONE REPORTED. lncompatibLity (#ateriaL8 to Avoid): AVOID STRONG OXIDIZING AGENTS. 'erckxa Oecanpo~ition or Bypr_r~_~ts: PRODUCT WILL NOT READILY OECC~tPOSE. · .azardou~ PoLyaerization - Hey Occur: Vitt Not Occur: X Conditions to Avoid: HA NO - Not Determined NA - Not Applicable T - Total Dust R - Respirabte Fraction C - Ceiling Lilait PYRO-TROL IS A REGISTERED TRADENARX OF BAKER HUGHES INTEQ. Page 1 PYRO-TROL VI. - HEALTH HAZARD I#FO~MATION: PrJlABry Exposure Route - Skin Contact: X Skin Absorption: Eye Contact: X InhaLation: X Ingestion: Product CarcJnogeflJcJty - I~TP: NO IARC: NO Acute Effects of Overexposure: ~L4Y ~AUSE EYE AND SKIN IRRITATION WITH OVEREXPOSURE. INHALATION MAY IRRITATE RESPIIL~TORY SYSTEN AND CAUSE SHORTNESS OF BREATH, C~IJGHING, NAUSEA 04~ VOMITING. iNGESTION HAY CAUSE NILD STC~4ACH UPSET, MAUSEA OR VOMITING. Chronic Effecta of Overexposure: NONE REPORTEO. VII. o EMERGENCY AND FIRST AiD INSTRUCTIONS: Eyes: HOLD EYELIOS APART AND FLUSH WiTH CLEAN RUNNING WATER FOR AT LEAST FIFTEEN MINUTES. CONTAI:T A PHYSICIAN IF iRRITATiON PERSISTS. Skin: WASH THORCXJGHLY WITH MILD SOAP AND WATER. REMOVE CONTAMINATED CLOTHES ANO LAUNDER. lngestJm: GIVE FLUIDS TO RINSE NOUTH AgO ~THROAT AND TO OILUTE. CONTACT A PHYSICIAN IF UPSET OCCURS ~R PERSISTS. InhaLation: REMOVE TO FRESH AIR. IF NOT BREATHING, GiVE ARTIFICIAL RESPIIL~TION. IF BREATHING IS DIFF! ~JLT, GIVE OXYGEN. VI I I. o ENVIRONMENTAL PROTECTION PROCEDURES: Spi t i Response: gEAR PROPER PROTECTIVE EQUIPNENT. CONTAIN THE SPILL ANO b~/EEP INTO AN APPROVEO CONTAINER FOR OISPOS/L. KEEP OUT OF WATERWAYS ANO SEI/ERS. NATERIAL %S A SLIP HAZARO WHEN gET. Waste Disposal Nethod: WASTE PROOUCT IS NOT HAZAROOUS ACCOROING TO RCRA CRITERIA OR LISTING AS SUPPLIEO. DISPOSE OF IN ACC~OANCE WITH LOCAL, STATE ! FEOERAL REGULAT %OHS. Handijng: CAUTIONI PROOUCT NAY IRRITATE EYES, SKIN AND RESPIRATORY SYSTEN. NININIZE CONTACT WITH EYES, SKIN, ND CLOTHING. AVOID BREATHING DUSTS. PRODUCT BECC]4ES EXTREMELY SLIPPERY WHEN gET. WEAR PROTECTIVE EQUIPMENT STATEO IN THE NSOS. Storage: KEEP AWAY FROM HEAT, SPARKS ANO FLN4ES. USE WITH AOEQUATE VENTILATiON. KEEP CONTAINER CLOSED WHEN N ~T IN USE. NININIZE DUSTING. MATERIAL IS A SLIP MAZARO WHEN gET. PROPERLY DISPOSE OF EMPTY CONTAINERS. IX. o OCCUPATIONAL CONTROL NEASURES: Respiratory Protection: gEAR AN APPROVEO PARTICULATE RESPIRATOR IF RECOI44ENOEO EXPOSURE LIMITS NAY B EXCEEOEO. Ventilation: SUPPLY NECMANICAL VENTILATION TO INSURE SAFE EXPOSURES TO PARTICULATE DUSTS. CLothing: ~ LONG PROTECTIVE CLOTHING WiTH AN APRON OR COVERALLS FOI~ ADOED PROTECTIO . LAUNOER BEFORE REUSE. Eye,ear: gEAR SAFETY GLASSES WiTH SIDESHIELDS WHEN HANOLIHG PRODUCT. GLoves: gEAR GLOVES'TO PREVENT SKIN IRRITATION. FOotuear: U;E NORMAL SAFETY BOOTS. Other Measures: INSURE GOOD-PERSONAL HYGIENE. CLEAN EQUIPMENT OF DUST BEFORE REUSE. WASH AFTER MANDLING AND BEFORE MEALS OR BREAKS. SENSITIVE INDIVIDUALS AVOID :URTHER CONTACT. X. - AODITZONAL INFOIU, IATION: DISCLAIMER The statements, information, ~ data provided in th{s material safety data sheet are believed re[ia~ ,e ~nd accurate by Baker Hughes IHTEG and its res~-~ib[e personneL; however, no other guarantee, representation, uarranty or respord ibi[ity ia expressed or implied to any user, regard[ess of reliance on ail or any part thereof. This includes uarranties of merchant d~iLity or of fitrms8 for a particular purpose, and Baker Hughes INTEG essunes no respc~sibiLity ~atever for advice or reoeemeflc ~tions ~wde. 'Nothing contained herein should be interpreted as permission, inducement, or condoc~m~qt to violate any Lea persua~t tc this product's use, convey--'e or disposaL. / Prepared By: dim Rushing Date Prepared: 05/31/9/, Supercedes laaue Date: 09/15/92 140 - Not Oetermir~cl NA - Not AppLicabLe · - Greater Thm~ < - Lesa Than C - CeiLing Lieit Page Z · MATERIAL SAFETY DATA SHEET 7000 Hollister Rd., SuRe 300 Emergency Telephone: (713) 439-890u JJ~ Hou=on, Texas 77040 KEN-SEAL CHEMTREC: 1-800-424-9300 ~- MANUFACTURER'S INFORHATIO~: Manufacturer: BAKER HUGHES INTEQ HNIS Hazard Rating Health 0 Minimal - 0 product Hame: KEN-SEAL and Key: Fiml~ability 2 Slight - 1 Chemical Name: AMPS-Na/AL[YLACRYLANIDE POLYMER Reactivity 0 Moderate - 2 Chemical Description: AMPS POLYMER Persorm[ Serious - Protection E Severe - Proper Shipping Description: DRILLING FLUID COI4POUNOw g.o.s. Hazard Class: NOT REGULATED UN N~rnber: NA Hazard Label: NA OOT Response Guide: NA Transportation #ore: NA II. - HAZARD IDENTIFICATION: Hazardous Components: ACGiH TLV: J OSHA PEL: Hazards Associateduith Product Use Yes Yes Yes 'Yes Combustible Liquid F[an~ab[e Material Pyrophoric Material Explosive Material Unstable #ateria[ Uater Reactive Material Oxidizer Organic Peroxide Corrosive Material Compressed Gas Irritant Nuisance Particulate X Skin Hazard Eye Hazard Toxic Agent Highly Toxic Agent Sensitizer Carcinogen Reproductive Toxin Blood Toxin Nervous System Toxin Lung Toxin Liver Toxin Kidney Toxin .,, '--- Co~mdnity Right-to-Knou (SARA Title Ill Section 311-312) .... :e: Sudden Re[ease Of Pressure: Reactivity: In~ediate (Acute): X Delayed (Chronic): III. - PHYSICAL DATA: Boiling Point(F): NA Vapor Pressure(nl~qg): NA PH: ND Me[ting Point(F): ND Vapor Density(Air=l): NA Specific Gravity: 1.3 Freezing Point(F): NA Solubility In ~ater: APPRECIABLE Percent Volatile By Volume(l): NA Odor Threshold: NO Appearance And Odor: ~HITE CRYSTALINEw MILD ODOR Evaporation Rate ( = 1): NA Material Is: NIX-POgOER Coefficient of ga[er/Oil Distribution: INSOLUBLE IN OIL IV. - FIRE & EXPLOSION HAZARO OATA: Flashpoint(F): NA Auto Ignition Temperature(F): NA Flammable Limits o LFL: NA UFL: NA Explosion - LEL: NA UEL: NA Extinguish Media - ga[er: X C02: X Dry Chemical: X Foam: X Fog: X Hazardous Conbustion Products: UPON CONBUSTION~ OXIDES OF CARBON MAY FORM PR~UCING TOXIC, ACRID FUMES. Fire Fighting Procedures: IN CASE OF FIRE, GENTLY FLOG0 UITH.UATER FOG, USING CARE NOT TO SUSPEND DUSTS. t/EAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING IN ENCLOSEO OR CONFINED AREAS OURING A FIRE. Unusus[ Fire and Explosion Hazards: AT VERY HIGH DUST CONCENTRATIONS IN THE PRESENCE OF AN IGNITION SOURCE, PRODUCT MAY FORM EXPLOSIVE OUST-AIR MIXTURES. V. - REACTIVITY OATA: Chemically Stable: Yes: X No: ~f no, Under I~hic~ Conditions? AVOIO VERY DUSTY CONDITIONS. I.ncompatibLity (Materials to Avoid): AVOID STRONG OXIDIZERS. 'rdous Decomposition or Byproducts: PRODUCT UILL NOT READILY OECI:~IPOSE. Hazardo~m Polymerization o May Occur: UiLL Not Occur: X Conditimq~ to Avoid: NA 140 - Not Oetermir~d NA - Not Applicable T - Total Dust R - Respirabte Fractien C - Ceiling Limit KEN-SEAL IS A REGISTERED TRADEMARK OF BAKER HUGHES INTEQ. Page 1 KEN-SEAL VI. - HEALTH HAZARD IHFORHATION: Primary Exposure Route - Skin Contact: Skin Absorption: Eye Contact: X Ird~alation: X Ingestion: Pr_~k__~_t CarcJnogenicity - #TP: NO ]ARC: NO Acute Effects of Overexposure: PROOUCT DUST HAY CAUSE NECHAHICAL IRRITATIOH TO EYES, SKIN AND UPPER RESPIRATO~IY TRACT. RESPIRATORY IRRITATION HAY IHCLUI)E SHONTNESS OF BREATH, COUGH OR CHEST TIGHTNESS. EYE AND SKi# IRRITATION HAY INCLUDE REDNESS, ITCHING OR RASH. Chronic Effects of Overexposure:. SOHE PARTICULATE DUSTS HAY CAUSE ALLERGIC SEHSITIZATION OF SO~E IHDIVIDUALS, CHARACTERIZED EITHER BREATHING DISTRESS OR TOPICAL SKIN ]RRITATION SYNPTOHS. VII. - ENERGENCY AND FIRST AiD INSTRUCTIONS: Eyes: HOLD EYELIDS APART AND FLUSH EYES WiTH WATER FOR AT LEAST 15 NINUTES. CONSULT A PHYSICIAN IF IRRITATION PERSISTS. Skin: WASH THOROUGHLY WITH NILD SOAP AND WATER. APPLY NEDICATED CRE~S TO RELIEV~ IRRITATION AN REPLENISH SKI~ OILS. ingestion: GIVE FLUIDS TO RINSE NOUTH AND'THROAT IRRITATION AND TO DILUTE. CONSULT A PHYSICIAN IF ~ VERSE SYNPTONS DEVELOP. lnhsLstion: NOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION iF NOT BREATHING. GIVE OXYGEN IF BREATHINI IS DIFFICULT. VIII. - ENVIRONNENTAL PROTECTION PROCEDURES: SpiLL Response: ~EAR PROPER PROTECTIVE EQUIPNENT (SECTION IX). RECOVER SPILLED NATERIAL TO THE ORIGINAL CONTAINER F~ SALE IF POSSIBLE OR TO A SUITABLE WASTE CONTAINER. NININIZE DUSTING DURING CLEANUP. FLUSH RESIDUE WITH WATER. Waste Disposal Method: WASTE PROOUCT IS NOT HAZARDOUS ACCORDING TO RCRA AS*SUPPLIED. REEVALUATION HAY BE REGUIRED AT DISP~;AL SINCE USES, REACTIONS,/: N]XTURES OR WORK PROCESSES NAY ALTER THE PRCOUCT'S STATUS. CONPLY WITH LOCAL, STATE AND NATIONAL REI~ILAT]ONS FOR DISPOSAL. HandLing: CAUTION! HAY CAUSE #ECHANICAL EYE, SKIN AND RESPIRATORY IRRITATION. AVOID CONTACT AND UEAR PROPER PIIOTECTIVE EQUIPHENT. AVOID BREATHING DUST. Storage: KEEP OUSTS TO A NiH]HUH. KEEP CONTAINER CLOSED WHEN HOT IH USE. USE UITH ADEGUATE VENTILATION. DISI~SE OF EHPTY CONTAINERS. IX. - OCCUPATIONAL CONTROL NEASURES: Respiratory Protection: UEAR AN APPROVED PARTICULATE RESPIRATOR IF REC~IEIIOEO EXPOSURE LINITS HAY BI EXCEEDEO. VentiLation: SUPPLY NECHANICAL VENTILATIOH TO EXHAUST DUST BELOU RECO~ENOEO EXPOSURES TO HUISANCE PARTICULATES. CLothing: UEAR LONG PROTECTIVE CLOTHING. LAUNDER CLOTHES BEFORE REUSE. Eye~esr: WEAR CHENICAL SAFETY GOGGLES OR GLASSES WITH SIOEGUARDS. INSURE A PROPER FIT GJoves: UEAR GLOVES 'TO PREVENT MECHAHICAL IRRITATION. Footuear: U~ NOIU~L SAFETY BOOTS. Other Measures: USE GO00 PERSONAL HYGIENE ANO CLEAN PERSONAL EGUIPNENT OF RESIOUE BEFORE REU~;E. USE APPROPRIATE CLEANSERS TO WASH OFF PROOUCT AND INCORPORATE SKIN CONDITIONIR$ INTO NYGIENE. X. - AODITIOHAL INFORNATION: DISCLAIMER The stateaants, information, and data provided in this material safety date ~heet ere believed reliable end ~ccurste by Baker Nughe~ INTEQ and its responsible personneL; however, no other guarantee, representation, ~arranty or resl:~* bitity is expressed or implied to any user, regardless of retiance on eLL or any pert thereof. This inciucle~ ~arrantte~ of mrchant;~i~ity or of fitnesl for · particular purpose, ~ Baker Hughes INTEQ assumes no responsibitity ~hetever for advice or recom~er~tiorm made. Nothing conteinod herein should be interpreted as permission, inducement, or conda~enent to violate any La~ persuant to this proc~_~_t'· use, conve~. or disposaL. Prepared By: dim Rushing Date Prepared: 01/17/9~ ;up~ecede~ Issue Date: / / ND o Not Determined RA o Not Appticab[e · - Greater Than < o Lasts Than C -Cei[ing Li~it Page 2 :" ~ '' MATERIAL SAFETY DATA SHEET '2001 Rankin Road EMERGENCY TELEPHONE: (713) 439-g900 J~']~g~ '-Hou~ten, Texas 77073 ....... CHEMTREC: 1-800-424-9300 I. ~NUFAC~R~S ~O~ATION: M~acmrer: , B~R HUG. S ~Q ~IS H~ard He~ 0 M~m~ 0 Product N~e: HP~07 ~YRO-VIS) Rang and Key Hmmabili~ 2 Slight ; 1 Chemic~ Name: POLYSACCHA~E ;' ReactiviF 0 Mode~te 2 " Pe~o~ Serious 3 Chemic~ Description: POLYSACCHA~E Pw~r S~ppi~ Descfip~on: DR~L~G ~U~ CO~OU~, N.O.S. H~ Cl~s: NOT ~GULA~D UN Number: H~d Label: NA DOT Res~e Guide: NA T~po~fion No~: NA /' .. '" ~[~,' ,, H. ~ZARD ~ENTWICATION: ~srdous Components: · ACGIH TLV: OS~ PEL: % CAS Numbe~ P~duct SODOM H~RO~E 2 MGm3 T 2 MGm3 T 2.0 1310-73-2 NA H~ards Assodated with Product Use . Yes Yes Yes Yes Combus~ble Liquid Flammable Matcfi~ . ~mphogc Matcfi~ .Explosive U~table Matefi~ · Water Re.five Matefi~ O~dizer Org~c Pemxid~ Co~sive Ma~fi~ Compressed Gm I~nt N~sance P~culate X Skin H~ X Eye H~d X Toxic Agent HigMy To~c Agent Scmiti~r Ca~inogen Repmduq~ve Tox~ Blood Toxiff Newou~,~ystem To~ Lung To~n Liver To~ Kidney Toxin Community ~ght-to-~ow (SA~ Title ~ S~tion 311-~1~) Fire: Sudden Release Of Pms~re: Rcactivi~: Immediate (Acute): X Delayed (CMo~c): IIL PHYSICAL DATA: Boil~Po~t ~): ~ VaporPmssure (m~g): ~ pH: 9.0 (2%SOL) Melting Point~): ~ Vapor Densi~ (Ai~l): ~ Spec~c GraviS: 0.65 Freez~g Point~: ~ . Solubilig' In Water: ~SOLUBLE Pement Volagle By Volme: ND Odor T~shold: .~ -- Appe~ce And Odor: BKOWN, M~D Evapo~fion Rac ( =1): Matc~ -Is: - M~-PO~ER Coefficient of Water/Oil Dis~bufion: ~SOLUBLE ~ OIL ~. F~ ~ E~LOSION HA~ BATA: Fl~h~int ~): -:?. '212 ~MCC) . Auto Ig~on Temperature (F): ~ Fl~able Limi~ - L~: ND ~L: ND ...' Explosion- LEL: ~ UEL: ~ Ex~n~is~ Media: Wa~r: X CO2: X D~ Chemic~: X Fo~: X Fog: H~dous Combusgon pmduCiS: UPON CO~US~ON. PRODUCT FO~S OX~ES OF CA~ON A~ ~CRID SMOg. ' ' GE~Y FLOOD WI~ WA~R US~G C~ NOT TO SUSPE~ DUSTS. ~ SELF-CO~ED B~A~ING ~P~A~S A~ PROTEC~ CLO~ING. ' ' ' Un~l Fire ~d Explosion H~ds: " ........ , PRODUCT MAY FO~ E~LOSI~ DUST-A~ M~S. V, ~ACT~Y DATA: C~mioagy S~blo: Yes: X No: .. ~ no, Under W~ch Con,flora? AVOID DUS~ CONDI~ONS WI~ HEAT, SPA~S A~ OPEN FL~ES'. I~o atibili ~d~s to Avoid): . NO~ ~OR~D. ' "-.: ::}~{. -. H~ous Decomposition on Bypr~uc~: NO~ ~POR~D. H~ous Polymefi~fion M~ Occu~ Will Not Occ~: X C0ndi~om to Avoid:NA ~ - Not Dete~ned NA - Not Applicable. T - To~ Dust R - Kespi~le Fraction C - Ce~g L~t HP-007(PYRO-VIS) VI. HEALTH HAZARD INFORMATION: ,, Primaq~ Exposure Route: Skin Contact: X Skin Absorption: Eye Contact: X Inhalation: X Ingestion: Product Carcinogenicity,,- NTP: NONE IARC: NONE Acute Effects of Overexposure: MAY CAUSE SEVERE EYES IRRITATION. INGESTION MAY CAUSE IRRITATION OF THE GASTROINTESTINAL TRACT. INHALATION MAY IRRITATE UPPER RESPIRATORY SYSTEM AND CAUSE COUGH. Chronic Effects of Overexposure: PROLONGED EXPOSURE MAY DRY SKIN LEADING TO DERMATITIS OR MAY AGGRAVATE AN EXISTING ALLERGIC CONDITION. VIL EMERGENCY AND l~IRST AID INSTRUCTIONS: Eyes: FLUSH'WITH CLEAN RUNNING WATER FOR 15 MINUTES. COI~ITACT A PHYSICIAN. Skin: WASH AREA WITH SOAP AND WATER. Ingestion: WASH MOUTH' OUT WITH WATER. GIVE LARGE AMOUNTS OF WATER TO DRINK. DO NOT INDUCE VOMITING. CONTACT A PHYSICIAN. Inhalation: REMOVE TO FRESH AIR IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, IF BREATHING IS DIFFICULT, GIVE OXYGEN. VIIL ENVIRONMENTAL PROTECTION PROCEDURES: Spill Response: WEAR SUITABLE PROTECTIVE EQUIPMENT. SWEEP UP THE SPILL INTO CONTAINER FOR RESALE OR LATER DISPOSAL. FLUSH RESIDUE TO DRAIN. Waste Disposal Method: DISPOSE OF ACCORDING TO LOCAL, STATE AND NATIONAL REGULATIONS. Handling: WARNINGt PRODUCT MAY IRRITATES EYES, SKIN, AND UPPER RESPIRATORY SYSTEM. AVOID CONTACT WITH PRODUCT AND WEAR PROPER PROTECTIVE EQUIPMENT. Storage: · - KEEP CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. AVOID EXCESSIVE DUST CONCENTRATIONS IN USE. WEAR PROPER PROTECTION FOR HANDLING. IX. OCCUPATIONAL CONTROL MEASURES: Respiratoq~ Pw'i~on: USE AN APPROVED PARTICULATE RESPIRATOR F'oR'HIGH CONCENTRATION~ OF AIRBORNE DUSTS. Ventilation: USE ADEQUATE VENTILATION TO EXHAUST MISTS AND VAPORS. Clothing: .'/' WEAR LONG PROTECTIVE CLOTHING WITH AN APRON OR COVERALLS FOR ADDED · Eyewear: WEAR SAFETY GLASSES OR GOGGLES TO PREVENT EYE CONTACT WITH DUST. REMOVE CONTACT LENSES IF PRESENT. Gloves: AS NEEDED TO ROTECr iAims FOR pROLONGED osu . Footwear: WEAR NORMAL SAFETY BOOTS. X, ADDITIONAL INFORMATION: DISCLAIMER ~ ..' The ststem~nts, inform~ion, and d~ provided in this malerlal safety data sheet are bellewtt reliable and aceuraIe vy Baker Hughes INTEQ a~d its responsible personnel; however, no other gmu~n~e, represen~tion, wan-anly or r~sponslbility is ~xpressed or implied to any user, regardless ofreli~n¢= on al! or any part thereof. This includes w~ies or merchantability or offi~ness for a particular purpose, and Baker Hugh~s INTEQ a~sumes no responsibilily wh&lever for advioe or reoommendaliom m~de. Nothing oontaineg herein shouM be in/erpr~g as p~rmlssion, induoem~nt, or ¢ondonement to viola~ any law persuant ~o g~is product's use, ¢onveyanc~ or disposal.. Prepared By: Jim Rushing Date Prepared: 05/01/94 Supercedes Issue Date ND - Not Determined NA - Not Applicable > - Greater Than < - Less Than C- Ceiling Limit Facsimile Health, Safety and Environment 2001 Rankin Road, Houston, Texas 7707:3 To: Stan Goodman From: . Jim Rushing Location: Bakersfield, CA Location: Houston Fax No.: 805-834-0264 Phone No.: 625-4492 Fax No.: 625.5492 Number of Pages (inch. this page): 3 Date: Sanuary 17, 1996 Subject: MSDS ,f.,.or HP-007 (PYROVIS) Stan, As you can see, there must not be a problem going with either name according to the MSDS. Good talking to you. Regards, Jim · ' Wm 'JJm M'ATER]:AL SAFETY DATA SHEET mmmmmm SECTION ONE PRODUCT IDENTIFICATIO'N~ ' ~ PRODUCT NAME(S): SYNTHETIC DRILLING MUD POLYMER PREPARED 1-95 CHEMICAL FAMILY: SULFONATEO ORGANIC POLYMER TRAOENAME~ POLYDRILL ADDITIVE SUPPLIER I DISTRIBUTOR: BAKER CHEMICALS, INC. ADDRESS: 50 BRIAR HOLLOW LANE, SUITE 310 WEST, HOUSTON, TX 77027 FOR FURTHER INFORMATION CALL: (713)-965-0898 SECTION TWO HAZARDOUS INGREDIENTS OF MIXTURES PRINCIPAL HAZARDOUS INGREDIENTS: NONE (AS DEFINED BY OSHA 29 CFR 1910.1200) SECTION THREE PHYSICAL DATA BOILING POINT: NOT AVAILABLE SPECIFIC GRAVITY: .7§ VAPOR PRESSURE: NOT AVAILABLE pH: 7.0 TO 9.0 VAPOR DENSITY: NOT AVAILABLE EVAPORATION RATE: NOT AVAILABLE SOLUBILITY IN WATER: SOLUBLE APPEARANCE: FINE BLACK, BROWN-RED POWDER SECTION FOUR FIRE AND EXPLOSION HAZARD DATA FLASH POINT: NOT AVAILABLE EXTiNGUISHiNG MEDIA: FOAM, CO2 , DRY CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES: NONE KNOWN UNUSUAL FIRE I EXPLOSION HAZARDS: NONE KNOWN SECTION FIVE HEALTH HAZARD DATA ROUTES OF ENTRY: ENTRY INTO BODY IS NOT EXPECTED WHEN OBSERVING INDUSTRIAL HYGIENE PROCEDURES CARCINOGENICITY: NOT LISTED AS A CARCINOGEN BY NTP, OSHA. OR IARC THRESHOLD LIMIT VALUE: 15.0 MG/M~ TOTAL DUST EFFECTS OF OVER EXPOSURE: NOT AVAILABLE EMERGENCY FIRST AID PROCEDURES: iN CASE OF CONTACT W~TH'EYES, FLUSH WiTH PLENTY OF FRESH WATER SECTION SIX REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID: SOURCES OF HIGH HEAT INCOMPATIBILITY {MATERiALs TO AVOID): STRONG OXIDIZERS HAZARDOUS DECOMPOSITION PRODUCTS: NOT AVAILABLE HAZARDOUS POYMERIZATION: WILL NOT OCCUR SECTION SEVEN SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN iN CASE MATERIAL .IS RELEASED OR SPILLED: SWEEP UP INTO CONTAINER, RECYCLE, IF POSSIBLE WASTE DISPOSAL METHOD: DISPOSAL IN INDUSTRIAL LANDFILL, ACCORDING TO APPLICABLE LAWS SECTION EIGHT SPECIAL PROTECTION-DATA APPROPRIATE HYGIENIC PRACTICES: AVOID DIRECT COHTACT WITH EYES, SKIN, AND MOUTH PERSONAL PROTECTION EQUIPMENT: CHEMICAL SAFETY GLASSES, AND OSHA APPROVED RESPIRATOR PERSONAL PROTECTION-EQUIPMENT: CHEMICAL RUBBER GLOVES, FACE SHIELD MAY BE NEEDED VENTILATION: LOCAL OR MECHANICAL EXHAUST OTHER PROTECTIVE MEASURES: AVOID SPILLAGE AS FLOORS MAY BECOME SLIPPERY. STORE IN SEALED CONTAINER. SECTION NINE ADDITIONAL INFORMATION NFPA HAZARD RATING: FIRE: t REACTIVITY: 0 0=MINIMAL 1=SLIGHT 2=MODERATE 3=SEVERE 4=EXTREME TOXICITY: 0 OTHER: 0 WISH/HMIS RATING: HEALTH: 0 REACTIVITY: 0 FLAMMABILITY: 1 PROTECTIVE EQUIPMENT: B SECTION TEN TRANSPORTATION DATA SHIPPING NAME: OILWELL DRILLING MUD TREATING COMPOUND, SOLID O.O.T. REGULATED? NO SPECIAL SHIPPING LABELS REQUIRED? NO "' 3AN 19 '96 16:30 FROM QUALITY ASSURANCE ~0 918058340264 PAGE.004/005 MAT~ SAFETY DATA 8I:nKET 2001 Rankin Road EMERGENCY TELEPHONE: (713) 439-8900 f~l[l~ Houston, Texas 77073 CHEMTREC: 1-g00-424-9300 L MANUi~ACTURER'$ INFORMATION: Chemic~d N~e: D~TL,OCCULAI~¥ l~eactivity 0 Modem~ 2 Chemical De~cripfioo: ACRYLIC COPOLYM][~ l~onM ~a~s Com~neots: --- - ~==~cG~ T~V~ OSilA P~L: % C~ ~m~ber: P~uct RQ: PAETICULA'~.S NOT 10 M~/M3 T i~ MG,~ T b~ NA NA ~RW[SE CLAS~D ~s ¥e$ Ye~ Yes S~ Ha?o.~t~ Eye H~i'd ~ic &~nl Highly Toxic A~nt ~.z.'r C~uogen ~ep~,~cfive Toxh: Bi~ Tamn Ne~,~ S~'slem Toxin Ltm8 Toxin Liver 'Co,in ~ov Toxin ~ PHYSICAL DATA: Material Is. ~:~ L,IQUID C~c~tciet,t of Wal'.~riOi; Distribution: N~ , ~ing~shi~,g M,:~.., Warv~: X C02: X D~, C~1~caJ: X Fo~: X Fog: ~do~ ~mbusJon PrOud: PRODUCT IS NO~-FL~4MABLE AS S~ ;' LLED. Ub}f A~PRODRIA~ ~.X'I'[NGUISJ~NG ,~:D]A FOR Fi~ Figh~ng P~ur~: ~ SE[~'.CO~TA~F D I t,.zEATHJ NO APPARATUS FOR EN'CLOSED O~ CObfFi~ED A~AS DU]O~G A S~O~DING Un~ Fire a.d Explosion ~ODU~' IS NON-~tM~LE AS SUPPLED. IT bbkY' SPLAT~'R W ~.~t~Bg~.ATI.FKES 'EXCEED. ~4E ~[~G PO~'. D~ ~LYM~ FILMS ~ C~LE OF B~'NIHG. C~ty Suable: Yes: x N0~' If ~, U~d~ ~ich C:onditi0n~:? H~mes D~.r, a~sifion on Bt~t~u~Rs: PRODUCT %~,L NO~ READK '~ DFE-518 L VI. FIEALTR ~ INFORMATION: Primary Exposure Route: Skin Contact: X Skin Absorption: Eye Contact: Inhalation: X Ingestion: Product Carcinogenicity- NTP: NO IARC: NO Acute Effects of Overexposure: [NGESTION MAY CAUSE NAUSEA AND VOMITING. PRODUCT HAS A LOW ORDER OF TOXICITY. SKIN OR EYE CONTACT OF FREQUENT OR PROLONGED NATURE MAY IRRITATE SKIN SOMEWHAT AND MODERATELY IRRITATE EYES. INHALATION PRESENTS NO HAZARD IN NORMAL INDUSTRIAL USE. Chronic Effects of Overexposure: NO CHRONIC EFFECTS OF OVEREXPOSURE ARE REPORTED FOR THIS PRODUCT. VIL EMERGENCY AND FIRST AID INSTRUCTIONS: ' , Eyes: HOLD EYELIDS APART AND FLUSH EYES WITH CLEAN WATER FOR AT LEASE 15 MINUTES. CONSULT A PHYSICIAN, Skin: WASH AFFECTED SKIN W1TH MILD SOAP AND WATER. OBTAIN MEDICAL ATTENTION. Ingestion: GIVE FLUIDS TO RINSE MOUTH AND THROAT AND TO DILUTE. CONSULT A PHYSICIAN. Inhalation: REMOVE TO FRESH AIR. FIRST AID NOT NORMALLY REQUIRED. VllL ENVIRONMENTAL PROTECTION PROCEDURES: Spill Response: WEAR PROPER PROTECTIVE EQUIPMENT (SECTION IX). SOAK UP SPILLS WITH ABSORENT MATERIAL AND SCOOP INTO DRUMS. FOLLOW ALL LOCAL, STATE, AND FEDERAL REGULATIONS FOR DISPOSAL. DO NOT DISCHARGE INTO LAKES AND STREAMS. SPILL AREA MAY BE SLIPPERY. USE CAUTION TO AVOID FALLS. Waste Disposal Method: PRODUCT IS NOT HAZARDOUS ACCORDING TO RCRA CRITERIA OR LISTING AS SUPPLIED. FOLLOW ALL LOCAL, STATE, AND FEDERAL REGULATIONS FOR WASTE DISPOSAL. Handling: CAUTION! MAY CAUSE EYE, SKIN OR RESPIRATORY IRRITATION. AVOID CONTACT AND AVOID BREATHING VAPORS. WEAR PROPER PROTECTIVE EQUIPMENT INCLUDING RUBBER GLOVES AND SAFETY GOGGLES. Storage: KEEP CONTAINER CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. SPILLED MATERIAL IS SLIPPERY. IX. OCCUPATIONAL CONTROL MEASURES: Respirato~ Protection: WEAR A NIOSH/MSHA APPROVED PARTICULATE RESPIRATOR IF EXPOSURE LIMIT MAY BE EXCEEDED. Ventilation: VENTILATION AS NEEDED TO MAINTAIN SAFE EXPOSURES TO NUISANCE PARTICULATES. Clothing: WEAR LONG SLEEVE CLOTHING OR APRON. Eyewear: WEAR CHEMICAL SAFETY GOGGLES OR GLASSES WITH S1DEGUARDS. Gloves: WEAR RUBBER GLOVES TO PREVENT MECHANICAL IRRITATION. Footwear WEAR NORMAL SAFETY BOOTS. X. ADDITIONAL INFORMATION: DISCLAIMER The statements, information, and data provided in this material safety data sheet are believed reliable and accurate by Baker Hughes INTEQ and its responsible personnel; however, no o~her guarantee, representation, warranty or responsibility is expressed or implied to any us~r, regardless ofrdiance on all or any part thereof. This includes warranties or cnerchantabil/ty or of fitness for a particular purpose, and Baker Hughes INTEQ assumes no responsibility whatever for advice or recommendations made. Nothing contained herein should be interpreted as permission, inducement, or condonement to violate any law persuant to this product's use, conveyance or disposal. Prepared By: Jim Rushing Date Prepared: 01/17/94 Supercedes Issue Date / / ~VD - Not Determined NA - Not Applicable > - Greater Than < - Less Than C- Ceiling Limit ** TOTAL PAGE.O05 ** LIQUID AIR CORPORATION INDUSTRIAL GASES DIVISION Material Safety Data Sheet PRODUCT NAME Acetylene TELEPHONE (415) 977-6500 EMERGENCY RESPONSE INFORMATION ON PAGE 2 LIQUID AIR CORPORATION TRADE NAME AND SYNONYMS CAS Number: INDUSTRIAL GASES DIVISION One California Plaza, Suite 350 Acetylene, Ethyne 74- 86- 2 2121 N. California Blvd. CHEMICAL NAME AND SYNONYMS Walnut Creek, California 94596 Acetylene, Ethyne ISSUE DATE OCTOaER 1, 1985 FORMULA MOLECULAR WEIGHT CHEMICAL FAMILY AND REVISIONS CORPORATE SAFETY DEPT. C2H2 26.0 A1 kyne HEALTH HAZARD DATA TIME WEIGHTED AVERAGE EXPOSURE LIMIT Acetylene is defined as a simple asphyxiant. Oxygen levels should be maintained at greater than 18 molar percent at normal atmospheric pressure which is equivalent to a partial pressure of 135 mm Hg. (ACGIH, 1984-85) SYMPTOMS OF EXPOSURE Inhalation: Low concentrations (10-20% in air) cause symptoms similar to that of being intoxicated. Higher concentrations so as to exclude an adequate supply of oxygen to the lungs cause unconsciousness. TOXICOLOGICAL PROPERTIES As a narcotic gas or intoxicant causes hypercapnia (an excessive amount of carbon dioxide in the blood). Repeated exposures to tolerable levels has not shown deleterious effects. The major property is the exclusion of an adequate supply of oxygen to the 1 ungs. Listed as Carcinogen National Toxicology Yes [] I.A.R.C. Yes [] OSHA Yes [~ or Potential Carcinogen Program No [] Monographs No [] No ~ RECOMMENDED FIRST AtD TREATMENT PROMPT HEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO ACETYLENE. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED'BREATHING APPARATUS AND BE COGNIZANT OF EXTREME FIRE AND EXPLOSION HAZARD. Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given mouth-to-mouth resuscitation and supplemental oxygen. Medical assistance should be sought immediately. Judgements as to the suitability of inforr~ation herein for purchaser's purposes are necessarily purchaser's responsibility. Therefore, although reasonable care has been taken in the preparation of such information, Liquid Air Corporation extends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's !ntended purposes or consequences of its use. Since Liquid Air 6orporati0n has no control over the use of this product, it assumes no liability for damage or loss of product resulting from proper (or ~mproper) use or application of the product. Data Sheets may be changed from time to time. Be sure to consult the latest edition. LAC 05101 Page 2 [. t-IAZAI:IDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES Flammable over an extremely wide range in air. Explosive reactions ma~v occur on i§nition.. Reacts explosively with halo§ens and halogenated compounds. PHYSICAL DATA BOILING POINT LIQUID DENSITY AT BOILING POINT Sublimation point = -118.8°F (-83.8°C) See last page VAPOR PRESSURE GASDENSlTYAT70°Flatm La 60OF ~15.6oc) = 645 psia (4450 kPa) ~ 70°F (21.1°C) .0691 lb/ft3 (1.107 kg/m~) SOLUBILITY IN WATER ~68°F (20°C) Bunsen FREEZING POINT coefficient = 1.047 Triple point = -113°F (-80.55%) APPEARANCE ^NO OOOR Pure acetylene is a colorless gas with an ethereal oSor. Commerical (carbide) acetylene has a distinctive qarlic-like odor.Spec.Grav.(Air=l.'.0)= 0.91 @ 70°F. F~R£ AND EXPLOSION HAZARD DATA FLASH POINT (METHOD USED) } AUTO IGNITION TEMPERATURE [ FLAMMABLE LIMITS % BY VOLUME LEL=2.2; Gas 565°F (296°C) UEL=80-85* *See note on last page.. EXTINGUISHING MEDIA . I ELECTRICAL CLASSIFICATION Carbon dioxide; dry chemical IClass 1, Group A SPECIAL FIRE FIGHTING PROCEDURES If possible, stop flow of escaping gas. Use water spray to cool surrounding containers. Keep personnel away since heated or burning cylinders can rupture violently. UNUSUAL FIRE AND EXPLOSION HAZARDS GASEOUS ACETYLENE IS SPONTANEOUSLY COMBUSTIBLE IN AIR AT PRESSURES ABOVE 30 PSIA (207 kPa). (Continued on last page.) REACTIVITY DATA STABILITY CONDIT{ONS TO Avoto DO not al 1 ow the free g~s (gutside of. cyl i nder) u,stab~e I X to exceed 30 psia. (Continued on ~ast page. 1 Stable INCOMPATIBILITY (Materials to avoid) 0x,y! en and other oxidizers including all of the halogens and halo- ~qen compounds. Forms exl)losive acet~lide compounds with (Continued on last page.) HAZARDOUS DECOMPOSITION PRODUCTS Carbon and hyJ_dr, ogen HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur 1 Will Not Occur X SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN iN CASE MATERIAL IS RELEASED OR SPILLED Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in user's equipment, be certain to purge piping with an inert gas prior to attempting repairs. If leak is in container or container valve, contact the closest Liquid Air Corporation location. WASTE DISPOSAL METHOD Do not attempt to dispose of waste or unused quantities. Return in the shipping ~tainer ro~labeled, with an~ valve outlet l~_~s or caI3s secured and valve ~tection ca2___~_~__place to Liquid Air Corporation for proper disposal. For emergency 5posal, contact the closest Liquid Air Corporation location. EMERGENCY RESPONSE INFORMATION IN CASE OF EMERGENCY INVOLVING THIS MATERIAL, CALL DAY OR NIGHT (800) 231-1366 OR CALL CHEMTREC AT (800) 424-9300 SPECIAL PROTECTION INFORMATION Page 3 ~REsP~ATORYPROTECTION(Speclfytype) Positive pressure air line with mask or self-contai~ed L_breathinq apparatus should be available for emerqency use. VENTILATION LOCAL EXHAUST TO prevent accumulation SPECIAL .Hood with forced above the LEL. .~ venti 1 ati on MECHANICAL (Gen.) OTHER Tn aCCnrd_anc~ with ~l~ctrical cmd~ -PROTECTIVE GLOVES PVC or rubber in laboratory; as required for cutting & weldin9. -EYE PROTECTION Safety qoqqles or §lasses ~THER PROTECTIVE EQUIPMENT Safety shoes, .safety shower SPECIAL PRECAUTIONS* SPECIAL LABELING INFORMATION DOT.Shipping Name: Acetylene DOT Hazard Class: Flammable gas DOT Shipping Label: Flammable gas ID No.: UN 1001 SPECIAL HANDLING RECOMMENDATIONS Use only in well-ventilated areas. Valve protection caps must remain in place unless container is secured with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing regulator when removing gas from the cylinder. DO NOT ALLOW THE FREE GAS TO EXCEED 30 PSIA (207 kPa) @ 70°F (21.1°C). Do not heat cylinder by any means to increase the discharge rate of product from the cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. For additional handling recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet ;PECIAL STORAGE RECOMMENDATIONS Protect cylinders from physical damage. Store in cool, dry, well-ventilated area of non-combustible construction away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 130F (54C). Cylinders must be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in-first out" inventory system to prevent full cylinders being stored for excessive periods of time. Post "No Smoking or Open Flames" signs in the storage or use area. There should be no sources of ignition in the storage or use area. For additional stooge recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet P-1. SPECIAL PACKAGING RECOMMENDATIONS Since acetylene will explode or combust if its pressure exceeds 30 psia (207 kPa) it is shipped dissolved in acetone or dimethylformamide which is dispersed in a porous mass within the cylinder. Follow Liquid Air Corporation's instructions for the maximum withdrawal rate for each size cylinder so that solvent is not withdrawn with the acetylene. Most metals, except silver, copper, mercury or brasses with more than 66% copper, are compatible (non corrosive)-with acetylene. OTHER RECOMMENDATIONS OR PRECAUTIONS Earth-ground and bond all lines and equipment associated with the acetylene system. Electrical equipment should be non-sparking or explosion proof. Compressed gas icylinders should not be refilled except by qualified producers of compressed gases. Shipment of a compressed gas cylinder which has not been filled by the owner or with his (written) consent is a violation of Federal Law (49CFR). Transport cylinders in well-ventilated vehicles,up~ight and suitably restrained to prevent movement. (ContJ_nmect on last page). *Various Government agencies (i.e., Depamment of Transpo~ation, Occupational Safe~ and Health Administration, Food and Drug Administration a~ o~ers) may ~ve specific regulations concerning the transpo~tion, handling, storage or use of this product which may not be contained herein. The customer or user ~ this pr~uct sh~M be familiar with ~ese reoulations. · Page 4 Li~"UID AIR CORPORATION INDUSTRIAL GASES DIVISION ADDITIONAL DATA LIQUID DENSITY AT BOILING POINT: (Continued) Solid density @ sublimation point = 45.51 lb/ft3 (729 kg/m3) FLAMMABLE LIMITS % BY VOLUME: (Continued) Note- Pure acetylene can ignite by decomposition above 30 psia (207 kPa); therefore, the UEL is 100% if the ignition source is of sufficient intensity. UNUSUAL FIRE AND EXPLOSION HAZARDS: (Continued) requires a very low ignition energy so that fires which have been extinguished ~out stopping the flow of gas can easily reignite with possible explosive force. .ylene has a density very similar to that of air so when leaking it does not readily sipate. CONDITIONS TO AVOID- (Continued) Cylinders should not be exposed to sudden shock or sources of heat. INCOMPATIBILITY (MATERIALS TO AVOID)' (Continued) copper, mercury, silver, brasses containing more than 66% copper and brazing materials containing silver or copper. ~ RECOMMENDATIONS OR PRECAUTIONS (Continued) increasing fire intensity ~]d explosion hazard if cylinders are so piled or that burning gas escaping frc~n a melted fuse plug (pressure relief device) ~ ~s on other cylinders. ............... 'fO 1818'36124~ h'. l.~£ · ,. ¢~t lt.i-OG-'i?D1 10:56 FROI4 ],2 !-TOF:P¢iI'.ICE H A T' E R I A .L S A F E T Y D A T A S H E E T O " Jones Chemicals, ~nc. 80 Munson Street LeRoy, New York 14482 (and Principal Cities) Tot information' Pl. ease Contact the Jones Chemicals facility in your area at ( 213)' 32~- 8383 or the Jones Chemicals · ..,~ Laboratory in Caledonia, New York'at (716) 538-2311, In the event of a .transportation.~mergency, Call CHEMTREC: (800) 424-9300 · : SECTION I - IDENTIFICATION TRADE NAME: . Sunny.'Sol® Aqua Ammonia; Aqua Ammonia 26° Baume' CHEMICAL NAME= ..Ammonium Hydroxide. FOR/~ULA: NHaOH DOT SBIPPIN~NA~E=' .AmmOnium Hydro~ide, 2914% DOT HAZARD CLASS~ .'.Corrosive Material UN/NA.NU~BER= NA 2672 DOT LA~EL~ Corrosive DOT PLACARD~ CorrOsive " REPORTABLE 'QUANTITY~I Ammonium Nydroxide: 1000 lbs/454 kg~ CAS NUMBER~ 1336-21-6 NFPA DESIGNATION~ *.The NFPA has not rated ammonium hydroxide. SECTION II - HAZARDOUS INGREDIENTS MATERIAL %'8Y. CAS NO. OSHA ACGIH W~IG~T. PEL TLV '. ~ "' ..... ' .... Ammonia 29.'4%' 7664-41-7 35 ppm STEL(NH ) .. 3 35 ppm STEL (NH Inert Ingredients Balance Not applicable Not applicable Not applicable · * Thi~ ~ubstance i~a chemical subject to the reporting requir, ement~ of'Section 313 of Title III of the Superfund Amendments and-Reauthorization Act of 1986 and 40 CFR Part 372. CARCINOG£NICITY STATUS: NTP - No, IARC - No, OSHA -No; )(Jones Chemical~, Inc. SUnny $ol® Aqua Ammonia) PAGE 2 of 5 SECTION III - PHYSICAL DATA APPKARANCE: Colorless liquid ' BOILING POINT: 84~9"F (29.4°C) FREEZING pOINTS -ll0"F (78.9"C) ODOR: Pungent; 'irritating PS: 13.5 s.u. @ VISCOSITY '(Cs): Not available PERCENT VOLATILE SY"VoLU~tE: 100% at 212"F (100~C) SOLUBILITY IN WATER2 Complete SPECIFIC GRAVITY (wATER-l)= 0.897¢'at 60"F (15.6°C) VAPOR DENSITY VAPOR PRESSURE: '420"- 475 mm Hg at 60°F (15.5~C) SECTION IV - FIRE AND EXPLOSION DATA FLASH POINT ('Test .method)~ Not applicable AUTO IGNITION TE~PE~%~TURE: 1204"F (651"C) (99% NH ) F~BLE LIMITS IN AI~ (VOLUME %)~ Upper: 25% Low'r:. i6% (99% NH3) EXTINGUISHING MEDIA~ Water spray or fog. SPECIAL FIRE FIG~ING PROCEDURES~ Protection from generated ammonia gas with appropriate respiratory equipment .is necessary. (See Section VIII). (The mixture will not burn but escaping ammonia gas can burn in the range of 16-25% in air.) Ammonia (16-25% in air) can explode in a confined space on Contact with sourc,s of ignition. Wear full protective clothing, and self-contained brea~hing apparatus. s~TION V - SEALTH HAZARD INFORF~%TION MEDICAL CONDITIONS'AGGRAVATED BY EXPOSURE INHALATION'~ MaY cause irritation, bronchitis, pneumonia. SKIN: May cause dermatitis. EYES: May Cause irritation, cataracts and retinal atrophy INGESTION: May cause excessive salivation, nausea, Vomiting, gastric irritation and possibly perforation of the. digestive and respiratory t~acts.. ROUTES OF EXPOSURZ' INHALATION: May cause irritation to mucous membranes of the respiratory tract. SKIN CONTACT: May severely injure skin upon contact.. SKIN ABSORPTION: May cause severe burns and irritation. £YE CONTACT: May be severely irritating upon liquid exposure, with mild irritation from fumes. INGESTION: Corrosive to the digestive tract. (Jones Chemicals, Inc. Sunny Sol® Aqua Ammonia) PAGE 3 of 5 EFFECTS OF OVEREXPOSURE ACUTE OVEREXPOSURE SWALLOWING~. CorrosiVe to the digestive tract; swallowing as little as a teaspoonful has caused death. SKIN CONTACT: High concentrations can cause Severe irritation and'burns. · - .INHALATION~ Can result in headac~e~,- 'coughing, severe lung congestion. LCso (HUMAN) - 5000 ppm. EYE CONTACT: May De severely irritating and cause burns upon liquid exposure. ORAL LDo0 - 350 mg NH]/kg (RATS) INHAL LD50 - 4230 ppm NH3 C~EONIC OVEREXPOSURE EYE: May cause irritation, cataracts and retinal atrophy. sKIN: May cause dermatitis. EMERGENCY AND FIRST'AID PROCEDURES INHALATION: If inhaled, remove to fresh air. If not breathing give artificial' respiration and call a physician. SKIN: In case of contact, immediately remove contaminated clothing and shoes, Wash skin thoroughly with soap and water. If irritation persists, call a physician.. EY£S: In case of eye contact, flush eyes with large amounts of water for at 'least fifteen (15)minutes. If irritation per~ist$, call a physician. iNGESTION: If'.swallowed, DO NOT induce vomiting. Drink large quantitie~ of water, followed by milk. Never give anything by mouth roan unconscious person. $~CTION VI - REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY This material remain~ stable when stored in a cool area and closed .container~. Avoid heating~ ~NCOMPATIBILITY Avoid contact with sulfuric acid or other strong mineral acids; avoid mixing with.hypochlorites, chlorine (and other halogens), and sodium hydroxide. Avoid contact with iron, galvanized ~urfaces, copper, bra~s, bronze, aluminum, alloys, mercury, gold, ~ilve~, and ~trong oxidizers. Avoid heating. (Jonee Chemical~,. Inc. Sunny Sol ®Aqua Ammonia) PAGE 4 of DECOMPOSITION pRODuCTs Decomposes'to ammonia.gas, and above 842°F (450eC) to hydrogen and nitrogen gas. CONDITIONS CONTRiBuTING TO HAZARDOUS POLYMERIZATION Will not occur. SECTION VII -'SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF'~ATERIAL IS RELEASED OR SPILLED Cleanup personnel'must wear proper protective equipment. (See Section VIII). Completely contain spilled material with dikes, sand bags, etc'. and prevent run-off into ground or surtace waters or sewers. Recover as much material as possible into containers for disposal. Remaining material may be diluted with water and neutralized with dilute acetic acid. Neutralized products, both liquid and solid, must be recovered for disposal. A dry sorbent can be 'used to collect neutralized ammonium hydroxide. Comply with all Federal, State and Local reporting requirements. DISPOSAL NETHOD Contact Federal,' State, county, and Local environmental regulators ~or guidance regarding proper disposal. SECTI°N· VIII - SPECIAL PROTECTION INFOI~HATION VENTILATION REQUIREMENTS ~rovide general~'ventilation to m~et OSHA permissible exposure limits (OSHA PEL) (~ee Section II). SPECIFIC 'PERSONA~ PROTECTIVE EQUIPMENT RESPIRATORY: Use'National Institute of Occupational Safety and Health (NIOSH) or.Mine. Safety aItd Health Administration (MSHA) approved re~pirator appropriate for this product when ~ermissible exposure limit~ are exceeded. .EYES: Use chemical' goggles and face ~hield. GLOVES: Use neoprene gloves or rubber gloves. OT~ER: Use ~eoprene splash apron. Safety shower and eyewash fountain should'be located nearby. ones Chemicals, inc. Sunny sol® Agua Ammonia) ~AGE 5 of 5 szc~xoN zx - SP~C~AL ~RECAUT~ONS PR.~CAUTIONS TO BE TAKEN IN HANDLING' Keep container closed when not in use. Do not breathe vapors. Do not take.internally. Avoid contact with eyes, skin and clothing. Wash thoroughly after handling. Use of goggleS, neoprene gloves, and neoprene shoes is recommended..· Loosen · closure cautiously, before opening. Keep lights, ~ire--aad sparks away from drum~. PROPER HANDLING AND STORAGE ~EQU/REMENTS Before moving container, be sure closure is securely fastened. Avoid rough handling or dropping. Keep lights, fire, add sparks away from container. Avoid contact with acids and combustibles. Keep container out of sun and away from heat. Replace closure after each withdrawl. Rinse empty container thoroughly with water and discard. Do not re-use container for any other purposes. In case of spillage, flush with plenty of water. STORE IN AN UPRXGHT.POSITION. 'HER PRECAUTIONS not handle or use until you are familiar with all safety 9recautions pertaining to the handling of corrosive liquid material. AlwayS·use protective clothing and eye protection when handling this material. NOTE: Fumes of this product are very pungent and irritating. NOTE~ 'Use caution when removing closures from this container. LooSen closure cautiously before opening'. AvOid brea~hing fumes, mists, gases or vapors. Use adequate ven~ilation or personal protection. Avoid Spilling and contacting, on skin, eyes and clothing. ADDITIONAL REGULATORy CONCERNS TSCA: Included in ~he Toxic Substances Control ACt (TSCA) Inventory of Chemical Substances. MSDS PREPARED BY: Jones Chemicals, Inc. :1'00 Sunny Sol Blvd. Caledonia, New·York i4423 Corporate Laboratory (716), 538-2311 ISSUE DATE: 12/12/89 :RCEDES ISSUE DATE:: 7/28/89 information herein is given in good faith but no warranty, expressed'or implied is made. MATERIAL SAFETY PENNZOIL DATA SHEET Manufacturer's Name PENNZOZL COHPANY CAS Number: HX~RE MSDS Code: ooo~q6 Address P.O. ~X 808 NFPA Hazard Identification OZL CZ~ PE~YLVANXA 16~01080B Degree of Hazard Hazard Ratings 0 - Least Health: ~ 1 - Slight Fire: ~ 2- Moderate 3 - High Emergency Telephone No. ( 7~ ) 2~6-6070 Reactivity: 0 4 - Extreme Trade Name PE~ZOZL AH HYD~UL~C OZL 68 Synonyms PETROLE~ L~RZCA~S. COMPONENT NAME HAZARDOUS PERCENTAGE COMPONENT CAS NUMBER IN BLEND MIN MAX ~POSURE LIMITS UNITS BASE LUBR~CATZNG OILS OSHA PEL NO LZH~T MZXTURE NO 9S.00 TO [00.00 ACG[H TLV NO L[MZT S[LZCONE ANT[FOAN ADDITIVE OSHA PE~ NO LZH[T PROPRIETARY NO ~ ~ .00 ACG~H TLV NO L~M~T iiiiii iiiii iiiii i: i i i i ii iii iiiiiiiiiiiii ii i: ii}i }iiiiiiii ii iiiiiiiiiiiiiiiiiii iiiiiiiii[ iii} iii iiiiii1iiiii}iiii iiiiiii ¢ iii iiii ii ii iiiii iiiil;iii {iiiiiiiiii DISCLAIMER OF ~ARRANTY: THE INFORMATION CONTAINED HEREIN IS BASED UPON DATA AVAILABLE TO US, AND REFLECTS OUR BEST PROFESSIONAL JUDGEMENT. HOWEVER, NO WARRANTY OF MERCHANTABILITY, FITNESS FOR ANY USE, OR ANY OTHER WARRANTY I$ EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF SUCH DATA, THE RESULTS TO BE OBTAINED FROM THE USE THEROF, OR THAT ANY SUCH USE DOES NOT INFRINGE ANY PATENT. SINCE THEINFORMATION CONTAINED HERIN MAY BE APPLIED UNDER CONDITIONS OF USE BEYOND OUR CONTROL AND WITH WHICH WE MAY BE UNFAMILIAR, WE DO NOT ASSUME ANY RESPONSIBILITY FOR THE RESULTS OF SUCH APPLICATION. THIS INFORMATION IS FURNISHED UPON THE CONDITION THAT THE PERSON RECEIVING IT SHALL MAKE HIS OWN DETERMINATION OF THE SUITABILITY OF THE MATERIAL FOR ~1S PARTICULAR PURPOSE. REQUIRED UNDER USDL SAFETY AND HEALTH REGULATIONS FOR SHIP REPAIRING, SHIPBUILDING, AND SHIPBREAKING {2~ CFR I~$, 1916, 1917J. MSDS CODE: ooo~4e PRODUCT: PENNZOIL AW HYDRAULIC OIL 68 PAGE 2 OF 6 EYE CONTACT THIS PRODUCT IS PRACTICALLY NON-IRRITATING TO THE EYES UPON DIRECT CONTACT. SKIN CONTACT AVOID SKIN CONTACT. THIS PRODUCT HAS NOT BEEN TESTED FOR ACUTE DERMAL EFFECTS. THIS PRODUCT IS EXPECTED TO BE PRACTICALLY NON-IRRITATING UPON DIRECT CONTACT. PROLONGED OR REPEATED CONTACT MAY RESULT IN CONTACT DERMATITIS WHICH IS CHARACTERIZED BY DRYNESS~ CHAPPING~ AND REDDENING. THIS CONDITION MAY MAKE THE SKIN MORE SUSCEPTIBLE TO OTHER IRRITANTS, SENSITIZERS~ AND DISEASE. PROLONGED OR REPEATED CONTACT NAY RESULT IN OIL ACNE WHICH IS CHARACTER[ZED BY BLACKHEADS WITH POSSIBLE SECONDARY INFECTION. ALLERGIC DERMATITIS~ USUALLY PRECEDED SM CONTACT DERMATITIS~ MAY OCCUR AND SPREAD BEYOND AREAS OF DIRECT CONTACT. CONSTITUENTS OF THIS PRODUCT HAVE BEEN ASSOCIATED WITH PHOTOSENSITIVII'~ AN ABNORMAL SENSITIVITY OF SKIN TO SUNLIGHT. INHALATION THIS PRODUCT HAS A LOW VAPOR PRESSURE AND IS NOT EXPECTED TO PRESENT AN ~NHALATION HAZARD AT AMBIENT CONDITIONS. CAUTION SHOULD BE TAKEN TO PREVENT AEROSOLIZATION OR MISTING OF THIS PRODUCT. THE THRESHOLD L~MIT VALUE (TLV) FOR THIS PRODUCT AS OIL MIST IS $ EXPOSURES BELOW $ MG/M$ APPEAR TO BE WITHOUT SIGNIFICANT HEALTH RISK. INGESTION DO NOT INGEST. INGESTION IS RELATIVELY NoN-TOXIC UNLESS ASPIRATION OCCURS. THIS PRODUCT HAS LAXATIVE PROPERTIES AND MAY RESULT IN ABDOMINAL CRAMPS AND DIARRHEA. SEE HEALTH DATA SECTION BELOW. HEALTH DATA ON RARE OCCASIONS~ PROLONGED AND REPEATED EXPOSURE TO OIL M~ST POSES A RISK OF PULMONARY DISEASE SUCH AS CHRONIC LUNG INFLAMMATION. THIS CONDITION IS USUALLY ASYMPTOMATIC AS A RESULT OF REPEATED SHALL ASPIRATIONS. SHORTNESS OF BREATH AND COUGH ARE THE HOST COMMON SYMPTOMS. ASPIRATION MAY LEAD TO CHEMICAL PNEUMONITIS WHICH IS CHARACTERIZED BY PULMONARY EDEMA AND HEMORRHAGE~ AND MAY BE FATAL. SIGNS OF LUNG INVOLVEMENT INCLUDE INCREASED RESPIRATION RATE, INCREASED HEART RATE, AND A BLUISH DISCOLORATION OF THE SKIN. COUGHING~ CHOKING, AND GAGGING ARE OFTEN NOTED AT THE TINE OF ASPIRATION. GASTROINTESTINAL DISCOMFORT MAY DEVELOP, FOLLOWED BY VOMITTING, WITH A FURTHER RISK OF ASPIRATION. MSDS CODE: oooz4e PRODUCT: PENNZOIL AW HYDRAULIC OIL 68 PAGE 3 OF 6 EYE CONTACT TMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER AND CONTINUE FLUSHING FOR 15 MINUTES. iF MATER[AL TS HOT, TREAT FOR THERMAL BURNS AND TAKE V[CTTM TO HOBPTTAL TMMEDZATELY. A REMOVE CONTAMINATED CLOTHING. WASH CONTAMINATED AREA THOROUGHLY WITH SOAP AND WATER. IF SKIN CONT CT HATERIAL ~S HOT, SUBMERGE INJURED AREA IN COLD WATER. IF V[CT[M IS SEVERELY BURNED, REMOVE TO A HOSPITAL IMMEDIATELY. THIS MATERIAL HAS A LOW VAPOR PRESSURE AND ZS NOT EXPECTED TO PRESENT AN INHALATION INHALATION EXPOSURE AT AMBIENT CONDITIONS. IF VAPOR OR MIST IS GENERATED WHEN THE MATER[AL IS HEATED OR HANDLED, REMOVE VICTIM FROM EXPOSURE. IF BREATHING HAS STOPPED OR IS IRREGULAR, ADMINISTER ARTIFICIAL RESPIRATION AND SUPPLY OXYGEN ZF ZT IS AVAILABLE. IF VICTIM IS UNCONSCIOUS, REMOVE TO FRESH AIR AND SEEK MEDICAL AT'rENTION. DO NOT INDUCE VOMITING. SEEK MEDICAL ATTENTION. INGESTION MSDS CODE: 000346 PRODUCT: PENNZOTL At4 HYDRAUL~'C OTL 68 PAGE 4 OF 6 EYE EYE PROTECTTON TS NOT REQUI'RED UNDER CONDTTTONS OF NORMAL USE. TF MATERTAL TS HANDLED SUCH PROTECTION THAT ?T COULD BE SPLASHED TNTO EYES~ WEAR PLASTTC FACE SHTELD OR SPLASH-PROOF SAFETY GOGGLES. SKIN NO SKTN PROTECT[ON TS REQUTRED FOR STNGLE, SHORT DURATTON EXPOSURES. FOR PROLONGED OR PROTECTION REPEATED EXPOSURES, USE TNPERVTOUS SYNTHETTC RUBBER CLOTHTNG (BOOTS, GLOVE$~ APRONS, ETC.) OVER PARTS OF THE BODY SUBJECT TO EXPOSURE. TF HANDLTNG HOT HATERZAL, USE TNSULATED PROTECTTVE CLOTHTNG (BOOTS, GLOVES, APRONS, ETC.). RESPIRATORY RESPTRATORY PROTECTTON IS NOT REQUTRED UNDER CONDTTTONS OF NORMAL USE. TF VAPOR OR MTST PROTECTION GENERATED WHEN THE MATERTAL IS HEATED OR HANDLED, USE AN ORGANTC VAPOR RESPTRATOR WITH DUST AND MTST FTLTER. ALL RESPZRATORS MUST BE NIOSH CERTTFTED. DO NOT USE COHPRESBED OXYGEN TN HYDROCARBON ATMOSPHERES. VENTILATION TF VAPOR OR MTST TS GENERATED WHEN THE MATERTAL IS HEATED OR HANDLED~ ADEQUATE VENTILATTON TN ACCORDANCE WTTH GOOD ENGINEERTNG PRACTICE MUST BE PROVTDED TO MAINTATN CONCENTRATIONS BELOW THE SPECTFTED EXPOSURE OR FLANHABLE LTMTTS. OTHER CONSUHPTTON OF FOOD AND BEVERAGE SHOULD BE AVOTDEO IN WORK AREAS WHERE HYDROCARBONS ARE PRESENT. ALWAYS WASH HANDS AND FACE WTTH SOAP AND WATER BEFORE EATTNG, DRTNKING, OR BMOKTNG. MSDS CODE: ooo~4e PRODUCT: PSNNZO'rL AW HYDRAUL"rC OI'L 68 PAGE 5 OF 6 FLASH POINT ,~ooF TEST METHOD c.o.c. AUTOIGNITION TEMPERATURE · ,~OOF TEST METHOD No DATA FLAMMABLE LIMITS IN AIR % BY' VOL LOWER NO DATA UPPER NO DATA EXTINGUISHING USE DRY CHEMZCAL, FOAM, OR CARBON D:~OX:~OE. MEDIA SPECIAL FIRE WATER MAY BE [NEFFECTZVE BUT CAN BE USED TO COOL CONTAZNERS EXPOSED TO HEAT OR FLAME. CAUTZON SHOULD BE EXERCZSED WHEN USING WATER OR FOAM AS FROTHING MAY OCCUR~ ESPECZALLY FIGHTING SPRAYED ZNTO CONTAZNERS OF HOT, BURNZNG LZQU~D. PROCEDURES UNUSUAL FIRE DENSE SMOKE MAY BE GENERATED ~H:[LE BURN:I:NG. CARBON NONOX:I:DE, CARBON D~:OXZDE, AND OTHER AND EXPLOSIVE OXTDES MAY BE GENERATED AS PRODUCTS OF COMBUST:[ON. CONDITIONS STABILITY (THERMAL, STABLE CONDITIONS TO NONE LIGHT, ETC.) AVOID HAZARDOUS WZLL NOT OCCUR CONDITIONS TO NONE POLYMERIZATION AVOID INCOMPATIBILITY MAY REACT W~:TH STRONG OX?D:~ZTNG AGENTS. MATERIALS TO AVOID HAZARDOUS DECOMPOSITION NONE PRODUCTS MSDS CODE: 0003~.6 PRODUCT: PENNZOIL AW HYDRAULIC OIL 68 PAGE 6 OF 6 STEPS TO BE CONSULT HEALTH EFFECT INFORMATION IN SECTION III, PERSONAL HEALTH PROTECTION INFORMATION TAKEN IF ZN SECTIOH V, FIRE PROTECTION INFORHATION IN SECTION V3~, AND REACTIVITY DATA IN SECTION VII. NOTIFY APPROPRIATE AUTHORITIES OF SPILL. CONTAIN SPILL IMMEDIATELY. DO NOT ALLOW MATERIAL IS SP~LL TO ENTER SEWERS OR WATERCOURSES. REHOVE ALL SOURCES OF IGNITION. ABSORB WITH RELEASED OR APPROPRIATE INERT HATERIAL SUCH AS SAND, CLAY, ETC.. LARGE SPILLS NAY BE PICKED UP USING VACUUM PUHPS, SHOVELS, BUCKETS, OR OTHER HEANS AND PLACED IN DRUHS OR OTHER SUITABLE SPILLED CONTAINERS. WASTE DISPOSAL ALL DISPOSALS MUST COMPLY WITH FEDERAL, STATE, AND LOCAL REGULATIONS. THE MATERIAL, IF METHOD SPILLED OR DISCARDED, MAY BE A REGULATED WASTE. REFER TO STATE AND LOCAL REGULATIONS. CAUTION! IF REGULATED SOLVENTS ARE USED TO CLEAN UP SPILLED HATERIAL, THE RESULTING WASTE MIXTURE MAY BE REGULATED. DEPARTHENT OF TRANSPORTATION (DOT) REGULATIONS MAY APPLY FOR TRANSPORTING THIS HATERIAL WHEN SPILLED. WASTE HATERIAL HAY BE LANDFILLED OR INCINERATED AT AN APPROVED FACILITY. MATERIALS SHOULD BE RECYCLED IF POSSIBLE. HANDLING AND DO NOT TRANSFER TO UNHARKED CONTAINERS. STORE IN CLOSED CONTA:~NERS AWAY FROM HEAT, SPARKS, STORAGE OPEN FLAME, OR OXIDIZING MATERIALS. THIS PRODUCT IS NOT CLASSIFIED AS HAZARDOUS UNDER DOT REGULATIONS. FIRE EXTINGUISHERS SHOULD BE KEPT READILY AVAILABLE. SEE NFPA 30 AND OSHA REOUIREMENTS zgzo. 106--FLAHMABLE AND COHBUSTIBLE LIQUIDS. ADDITIONAL THIS MIXTURE MAY BE FORHULATED IN PART WITH COMPONENTS PURCHASED FROH OTHER COHPANIES. IN INFORMATION MANY INSTANCES, ESPECIALLY WHEN PROPRIETARY OR TRADE SECRET MATERIALS ARE USED, PENNZOIL COMPANY MUST RELY UPON THE HAZARD EVALUATION OF SUCH COHPONENT SUBMITTED TO PENNZOIL BY THAT PRODUCT'S MANUFACTURER OR IMPORTER. BOLLING POINT (MID POINT) · aOOF PERCENT VOLATILE NO DATA MELTING POINT (POUR POINT) - 20F VAPOR DENSITY (AIR=l) NO DATA APPEARANCE CLEAR, YELLON COLOR. EVAPORATION RATE (EE=I) NO DATA ODOR MZLD LUSE OIL O00R. SPECIFIC GRAVITY o.sTs VAPOR PRESSURE NO DATA MOLECULAR WEIGHT VARIES SOLUBILITY INSOLUBLE ZN WATER, SOLUBLE IN HYDROCARBONS. BAKER 5AND CONTIOL L I~tODUCT IDENTIFICATION ~3-~ " EX.SURE ~S INGRE~E~ ~S ~. APeX % OSHA ~L AC~H TLV OmER SILICA C~I~ ~Z 14~-~7 ~.5 ~l. 0.1 ~/~3 0.1 ~/~3 ~ ~/~ (~) (~I~LI) (~I~) 1~I~) 0.3 ~1.- (~) ~. ~YSI~L DATA ~ ~FLIC~LE ~ ~LIC~LE ~ ~LIC~LS ~ ~LIC~LE IN~LB 2.7 ~ ~LIC~LE ~-~ ~INS ~ ~ ~ ~. fiRE AND EX~ION IN~TI~ .~.N~ : ~.U,~,~G M.. I~ uMns'% ay v~u~ ~ ~ LOWER: ~ UPPER: COl(TACT FI~ FLOOZie. CHLORI~. TItI~%t~IDR, MA~A]~ l~I0XlO! A~ ~ DII%UOEIDE MAY CAU~ V. HEALTH EFFECTS INFOitMATION PIllORY J~OU"JT-.5 ~ ~X~U~ SKIN ~ EYES ~ INHA~T~N ~ INGESTION SKIN: ~ EYES: -- INGESTION: c~~x~u~ SKIN: ~ EYES: INGESTION: ~ ' POTE~J0'L CAeC'NOG£~YJJS' ~-ANPT: IARC: OSHA: LANDFILL ~ SPECIAL PROTECTION INFORMATION ~ t~ROVXDE ~IERAL VEh*TILATIC~ TO KEEP CONCEh~TICN BEL(~ lilfiSAgC]i LEVEL. L~CAL VENTILATION ~! BE N~R$$,~Y ~0 ~. HAN~NG AND STORAGE IN~MATION AYOID CR~ATI~ 0F DU~. ~IlR B~/~ ~kOS I~II~T. ~ DU~ ~ kS ~D. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AJ~ENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). os.^ H~Z~.DOUS CH£M~C^, ~ ][:] IMMEDIATE (ACUTE) HEALTH HAZARD [:](DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA0 40 CFR 261): #0 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL J EFFF'C'TIVE DATE ~c-~23MATERIAL SAFETY DATA SHEET Jl NO',,'~,,m~ 30; 199o 1. PRODUCT IDENTIFICATION I BILKER SAND CONTROL J P.O. BOX 61486, HOUSTON, TX 77208 713-443-7590 / BAKER LOW FINE GRAVEL CRYSTALLINE SILICA PREPARED BY: BRIAN EVANS II. HAZARDOUS INGREDIENTS EXPOSURE LIMITS INGREDIENT CAS NO. APPROX % OSHA PEL ACGIH TLV J OTHER SILICA 14808-60-7 100 0.1 Mg/Ma 0.1 Mg/M~ 50 Ug/M~ (NIOSH CRYSTALLINE QUARTZ (RESPI J~LBLE } ( RESPIRABLE ] ( RESPIRABLE ) 0.3 Mg/M~ '* I7/. PHYSICAL DATA [~:)JLJ~G POJ~T VAPOJ~ P~ESSURE 4046°F (2230°C) NOT APPLICABLE VAPOR DENSITY lAIR = 1 ~ EVAPORATION RATE {BUTYL Afl--rATE NOT APPLICABLE NOT APPLICABLE SOLUBILITY IN WATER SPECIFIC GRAVITY {WATER INSOLUBLE 2.65 VOLATILITY APPEARANCE ANO ODOR NOT APPLICABLE SAND COLORED GRAINS WITH NO ODOR IV. FIRE AND EXPLOSION INFORMATION ,SH POINT] ] EXTINGUISHING MEDIA NONE NONE J LOWER: NONE UPPER: ~ FIGHTING PfiOCEDURES NONE UNUSUAL FIRE AND EXPLOSION HAZARI~S CONTACT WITH FLUORINE, CHLORINE, TRIFLUORIDE, MAGANESE TRIOXIDE AND OXYGEN DIFLUORIDE MAY CAUSE SPONTANEOUS FIRES. V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE [] SKIN [] EYES [] INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE SKIN: NONE EYES: IRRITATION INHALATION: SHORTNESS OF BREATH, REDUCED PULMONARY FUNCTION, TRANSITORY UPPER RESPIRATORY IRRITATION Z O INGESTION: NONE 1-- CHRONIC (PROLONGED) EXPOSURE ~ SKIN: NONE ~C) EYES: IRRITATION Z INHALATION: SILICORIS, PNEUMOCONIO~IS, PULMONARY FIBROSIS, POSSIBLE CARCINOGEN ,~ INGESTION: NONE SKIN: NONE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER TO REMOVE DUST. CONSULT PHYSICIAN IF IRRITATION PERSISTS. -~NJJALATION~--~.E~OVE TO FRSSH AIR, DRINK WATER TO CLEAR THROAT, BLOW NOSE. INGESTION: NONE. riAL C~RCINOGI' N J A(',Gr~AVAI'ION OF' EXISTING CONDITIONS J TAPGE r ORGAN5 NPT: NO IARC: YES, 2A OSHA: NO . UPPER RESPIRATORY/LUNG DISEASES I LUNGS VI. REACTIVITY INFORMATION :~TA~ILITY l CONOITIONS TO AvoID I INCOMPATIBILITY (MATERIALS TO AVOID) S~M~LE Il ~ONE J Hi~ , OXIDIZING AGEKTR HAZAROOuS FK)LYMERIZAT1ON CONDITIONS TO AVOIO WLLL NOT OCCUR NONE THE]~4AL DECOMF~)SITION P~OUCTS VZ]. SPILL OR LEAK PROCEDURES S'I'EP~ TO BE TAKEN IF' MATERIAL IS RELEASED OR SPILLED SCOOP OR S'W'~EP UP. AVOID CRE.a~ING DUST. WEJ~ DUST t'U~K AND GOGGLES. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. WASI~ D~SPOSAL. METHOO LANDFILL VIII. SPECIAL PROTECTION INFORMATION RE,~g~ATONY PROTECTION DUST t'~SK VElVet. AT,ON PROVIDE GENERAL VENTILATION TO KEEP C~DNCENTRATION BELOW NUISANCE LEVEL. LOCAL VENTILATION MAY BE NECESSARY TO KEEP CONCENTRATION BELOW EXPOSURE LIMITS. PROTECTIVE GLOVES N(X~E REQUIaED EYE I:~:~OTECTION SAFETY GLASSES OT~ER PROTECTIVE EOUIPMENT NONE REQUIRED IX. HANDLING AND STORAGE INFORMATION AVOID CREATION OF DUST. REPAIR BROhq:N/TORN BAGS IMMEDIATELY. WEAR DUST MASK AS NEEDED. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE [H OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 SARA). No NO Ilo O~I.4A HAZARDOUS CHEMICALS ['~ iMMEDiATE (ACUTE) HEALTH HAZARD [-~ DELAYED (CHRONIC) HEALTH HAZARD [~ FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD NO HAZARDOUS WASTE (RCRA, 40 CFR 261): I~I/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED ~' THIS iNFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL EFFECTIVE DATE M~.~A?~?~IAL SAFm DATA SHEET [ ~IL 6, 1988 ]'. PRODUCT ID(NTIFICATION MANUFACTURER'S NAME I ADDRESS BAKER SAND CONTROL I P.O. BOX 61486,, HOUSTON, TX 77208 PHONE NO. TPRODUCT NAME 713-443-7590 / DIATOMECEOUS EARTH (DE) CHEMICAL DESCRIPTION SILICA PREPARED BY: GLENN ROSCF. EWSKI IT. HAZARDOUS INGREDIENTS EXPOSURE LIMITS INGREDIENT CAS NO. APPROX % OSHA PRE I ACGIH TkV OTHER I DIATOMACEOUS EARTH 68855-54-9 100 0.1 mg/m' 0.1 mg/m3 50 mg/m~ (NIOS] ( RESPIRkBLE ) ( RESP IPJ%B LE ) ( RESPIRABLE ) MAY CONTAIN QUARTZ 14808-60-7 5 MAX 0.3 mg/m' CRISTOBALITE 14464-46-1 70 MAX (TOTAL) III. PHYSICAL DATA NONE NONE NONE NONE SLIGHT 2.35 NONE WHITE POWDER WITH NO ODOR IV. FIRE AND EXPLOSION INFORMATION POINT [EXTINGUISHING MEDIA ] FLAMMABLE LIMITS (% BY VOLUME) NONEi ~ NONE/ LOWER: NONE UPPER: NONE SPECIAL FIRE F')GHTING PROCEDURES NONE UNUSUAL FIRE AND EXPLOSION HAZARDS CONTACT WITH FLURINE, CHLORINE, TRIFLUORIDE MANGANESE TRIOXIDE ;~D OXYGEN DIFLUORIDE MAY CAUSE SPONTANEOUS FIRES. V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE [] SKIN [] EYES [] INHALATION [] INGESTION ACUTE {SHORT) EXPOSURE SKIN: NONE EYES: IRRITATION INHALATION: TRANSITORY UPPER RESPIRATORY IRRITATION, SHORTNESS OF BREATH, REDUCED PULMONARY FUNCTION Z NONE O INGESTION: I~ CHRONIC (PROLONGED) EXPOSURE ~ SKIN: NONE ..O EYES: IRRITATION _Z INHALATION: PNEUMOCONIOSIS, SILICOSIS PULMONARY FIBROSIS, POSSIBLE CARCINOGEN ~:~ NONE ',,' INGESTION: N EMERGENCY FIRST AID PROCEDURES SKIN: NONE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER TO REMOVE DUST. CONSULT PHYSICIAN IF IRRITATION PERSISTS. --{NFd%f~I~fOff.-~REMOVE--TO--FRESM-AiR, D~NK WA'I'E~-L'~R-T~T;--15T;C~ ~u~E. /~u~'rluB: NUN]:;. NPT: NO IARC: YES, 2A OSHA' NO UPPER RESPIRATORY/LUNG DISEASES I~ LUNGS VI. REACTIVITY INFORMATION ~AZARE)OUS POLYMERIZATION [ CONDITIONS TO AVOID WILL NOT OCCUR ! NONE THERMAL DECOMPOSITION PRODUCTS S~. PRODUCED U~C)N COh~ACT W:[~] HF VII. SPILL OR LEAK PROCEDURES ~TEf:~ TO BE TAKEN IF' MATERIAL. IS RELEASED OR SPILLED VACUUM OR SWEEP UP. AVOID CREATING DUST. W~AR DUST MASK AND GOGGLES. 'WASTE DISPOSAL METHOD LANDFILL VIII. SPECIAL PROTECTION INFORMATION "RESPIRATORY PROTECTION DUST MASK VENTILATION PROVIDE GENERAL VENTILATION TO KEEP CONCENTRATION BELOW NUISANCE LEVEL. LOCAL VENTILATION MAY BE NECESSARY TO KEEP CONCENTRATION BELOW EXPOSURE LIMITS. ~ROTECTIVE GLOVES NOT REQUIRED EYE PROTECTION NOT REQUIRED OTHER PROTECTIVE EQUIPMENT NOT REQUIRED IX. HANDLING AND STORAGE INFORMATION AVOID CREATING DUST. REPAIR BROKeN/TORN BAGS IMMEDIATELY. WEAR DUST MA~K AS NEEDED. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUBSTANCES NO CERCLA HAZARDOUS SUBSTANCES ['iQ SARA EXTREMELY HAZARDOUS SUBSTANCES NO SARA TOXIC CHEMICALS - ' -: ......... : ........ . ...... :';- ....... ' ' ~': ..... ~+:: ' . NO OSHA HAZARDOUS CHEMICALS ['~ IMMEDIATE (ACUTE) HEALTH HAZARD {~ DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): No N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUJ~ CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. G "AEROSOL MATERIAL SAFETY DATA SHEET CHEMICAL PACKAGING CORPORATION I EMERGENCY PHONE I305)974-5440 I P.O. BOX ~47, FT. LAUOERDALE. FL 333t0 HMIS SYMBOL HUIS NFPA COMMUNICATION STANDARD (HCS) 29 CFR 1910. 12(X). HEALTH 2 SERIOUS 3 HIGH STANDARD MUST BE CONSISTED FOR SPECIFIC REQUIREMENTS. FLA~MN~UW MOOERATE 2 MODERATE THIS PROOUCT CONTAINS SUBSTANCES SUBJECT TO REACTIVI'~Y SUGHT 1 ~ TOXlC~ SECTK)N 313OF SARATITLE III AND 40 CFR 372. MINIMAL 0 INSIGNFICANT .. SPEC~L I-IDENTIFICATION PROOUCTNAMEI DRY MOLY LU_B~ 955 / PACKAGE TYPE AEROSOL CONTAINER S GNATURE OF PERSON//' J DATE RESPONSIBLE FOR PREPARATION /~_~_.~.~I~,~'/F'~II~-'~ PREPARED APPJL 4, 1991 ~' / U-HAZARDOUS INGREDIENTS mNC P E ZARDOUS COMPONENT(S×C.EMICAL.AMES) - CAS PEL APPROX. % WT. METHYLENE CHLORIDE 75-09-2 100 100 <80% WT. TOLUENE 108-88-3 100 100 <10% .:: METHYL ALCOHOL 67-56-1 200 200 <1%WT. PROPELLANT HYDROCARBON PROPELLANT 68476-86-8 1000 1000 Ill-PHYSICAL DATA BOILING POINT (0 F) 92'F VIGOROUS BOIUNG SPECIFIC GRAVITY (H20 = 1) @ 750F 1.28 OF CONCENTRATE OF CONCENTRATE · % VOLATILE BY VOLUME IAPOR PRESSURE (psig) 50 >92 IN CAN @ 750F IN CAN VAPOR DENSITY FLASH POINT N.D. OF CONCENTRATE 80OF SOLUBILITY IN WATER APPEARANCE AND ODOR OF CONCENTRATE OF SPRAY NEGLIGI.BLE BLACK LUSTROUS MQUlD CHARACTERISTIC ODOR. IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABIUTY as per CPSC FLAME EXTENTION TEST FLAMMABLE EMITS Lower Upper NON- FLAMMABLE SPRAY N.A. NJL EXTINGUISHING MEDIA NFPA COOE 30B FOAM, DRY CHEMICAL, CARBON DIOXIDE LEVEL 1 AEROSOL SPECIAL FIRE FIGHTING PROCEDURES K~EP CONTAJNER~ COOL. US~ EQUIPMENT OR SHIi~,.OI~K~ REQUm TO PROTECT PERSONEL AGAINST BURS'TId~ RUPTURING OR V~ CONTAINERS LJNUSUAL FIRE AND EXPLOSION HAZARDS AT ELEVATED TEMPERATURES (ABOVE 1200 F) CONTAINERS MAY VENT RUPTURE OR BURST. V - REACTIVITY DATA CHEMICAL UNSTABLE CoNomONS TO AVOID !STABIUTY STABLE XX DO NOT EXPOSE TO TEMPERATURES ABOVE 1200. F. INCOMPATABIUTY (MateriaLs to avoid) STRONG ALKAUES, OXIDIZERS, ALUMINUM AND OTHER REACTIVE METALS. HYDROGEN CHLORIDE PHOSGENE (SMALL AMOUNTS). MAY OCCUR C, ONDFrK:)NS TO AVOID HAZARDOUS WILL NOT OCCUR XX NONE AEROSOL PRODUCTS PRESENT A UMITED'HAZARD DURING STORAGE OR USE IF LABEL PRECAUTIONs ARE FOLLOWED. INTENTIONAL MIS-USE BY DEEBERATELY CONCENTRATING AND INHAUNG THE CONTENTS CAN BE HARMFUL, OR FATAL PRESSURIZED CONTAINERS MUST NOT BE EXPOSED TO TEMPERATURES ABOVE 120° F AND SPRAY SHOULD NOT BE DIRECTED TOWARD FACE OR EYES, OPEN FLAME OR OTHER SOURCE OF IGNITION. VI - HEALTH HAZARD DATA ROUTE(S) OF ENTRY: INHALATION? I SKIN? PRIMARY I INGESTION? EFFECTS OF OVER EXPOSURE : ACUTE AND CHRONIC INHALATION: EXCESSIVE INHALATION OF VAPORS CAN CAUSE RESPIRATORY IRRITATION, DIZZINESS, NAUSEA, HEADACHES, -- UNCONCIOUSNESS AND POSSIBLE DEATH. CHRONIC OVER EXPOSURE MAY CAUSE EVER, KIDNEY OR LUNG DISEASE, ANEMIA, CORONARY DISEASE OR RHYTHM DISORDERS OF THE HEART. SKIN CONTACT/ABSORPTION: PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE IRRITATION, DEFATriNG AND DERMITITIS. INGESTION: CAN CAUSE SEVERE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA, ASPIRATION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL PNEUMONrrls. EYES: CAN CAUSE SEVERE IRRITATION, REDNESS TEARING AND BLURRED VISION. CARClNOGINIOITY: I NTP? I IARC MONOGRAPHS? I OSHA REGULATED? NO NO NO YES EMERGENCY AND FIRST AID PROCEDURES: EYES AND SKIN: FLUSH EYES WITH WATER, UFTING UPPER AND LOWER E DS. GET MEDICAL ATTENTION. ' WASH EXPOSED SKIN AREAS WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING STOPS GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION. ASPIRATION OF ~ MATERIAL INTO LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS. VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TO BE TAKEN IN CASE CONTAINER IS PUNCTURED AND MATERIAL IS RELEASED: CLEAN UP AREA BY MOPPING OR WITH ABSORBENT MATERIALS AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL CONTACT FEDERAL, STATE OR LOCALAUTHORITIES FOR APPROVED DISPOSAL PROCEDURES. WASTE DISPOSAL METHOD: WHEN USED PROPERLY AEROSOL PRODUCTS DO NOT GENERATE HAZARDOUS wASTF_ EMPTY DE-PRESSURIZED CONTAINERS CAN NOT BE REUSED AND SHOULD RE WRAPPED AND PUT IN A PERMITI'ED WASTE MANAGEMENT FACILITY. CONSULT FEDERAL, STATE AND ~OCAL O~OSAL AUT~ORrr~s FOR ~PROVa3 P~OC~JRES. VIII - SPECIAL PROTECTION INFORMATION SPECIFIc PERSONAL PROTECTIVE EQUIPMENT: RESPIRATORY: WHERE VAPOR CONCETRATION IS 100-10D0 PPM, ORGANIC VAPOR RESPIRATOR. · "" :. IF CONCENTRATION EXCEEDS 1000 PPM SELF CONTAINED BREATHING APPARATUS.' ':". '** EYE: . WEAR SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES WHERE SPLASHING. · ' SKIN: ~ PROTECTIVE GLOVES: ~'.'~ ' "O SPECIFIC PROTECTIVE EQUIPMENT NEEDED I CHEMICAL RESISTANT: VITO" OR POLWlNYLCHLORIDF- VENTILATION REQUIREMENTS: PROVIDE SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST VENTILATION TO MAINTAIN EXPosuRE BELOW TLV (S). . IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDUNG AND STORING: --- DONOTSTOREATTEMPERATURESABOVE 1200F, SPECIAL PRECAUTIONARY STATEMENTS: PLEASE REN~ AND FOLLOW 11..IE DIRECTIONS ON 'II.IE PROOUCT LABE/.: ~ ARE YOUR BEST GUIOE TO U~ING THI~ PRODUCT IN 3HE MO~T EFFECTNE WAY, AND THEY ~ ~ THE NECESSARY SAFETY PRECALJTIONS TO PROTECT YOUR HEALTH. NOTICE: WE BELIEVE 314AT THE INFORMATION CONTAINED ON 11~ts MATERIAL SAFETY DATA SHEET IS ACCURATE. THE SUGGESTED PROCEDURES ARE BASED ON EXPERIENCE AS (36 THE DATE OF PUGLICATIOI~ THEY ARE[ NOT NECESSARILY ALL INCLUSIVE NOR FULLY ADEQUATE IN EVERY CIRCUMSTANCE. ALSO, THE SUGGESTS SHOULD NOT BE CONED V~qTH NOR FOLLOWED ~/VIOLATION OF APPUCABLE LAWS. REGULATIONS. PAJLES OR INSURANCE REQUIREMENTS. NO WARRANTY, ID~PRESS OR IMPUED, OF MERCHANTABII~W, FITNE~ OR Olt4ER1MSE tS MADF_ ~J~ERVICES ~IS ~Z~ INDEX M~T~: 3 F~ILITY: 2 ~CTIVITY: 0 P~SON~ PROTECTION: j PRODUCT N~E .................... INF~ 40 CH~IC~ DESCRIPTION ............ Ethylene glycol monobutyl ether PRODUCT USE ..................... Surface tengion reducer S~PLI~R ........................ BJ S~RVICES ~DRESS ......................... 5500 NORT~EST C~T~ DR HOUSTON TX 77092 ~R~CY TELEPHONE ~~ ...... (800)424-9300 for CH~REC (202) 483-7616 in Alaska P~P~D BY ..................... B~ S~VICES ~IRO~T~ GROUP (713)351-0773 DATE PREP~D ................... December 19~3 Supersedes: December 1992 ~Z~DOUS CO~ON~TS CAS f PERCE~ ~Z~ Ethylene glycol mo~obutyl e=her 111-76-2 >99 Toxic, Co~ustible S~~ III - F~ ~ ~SION ~ F~SHPOINT ~D METHOD OF DETE~INATION .................. 150 ~P~ ~XP~SION LIMIT(% BY VOL). 10.6 · LOWER EXPLOSION LIMIT(% BY VOL}. 1.1 A~O-IGNITION T~E~T~E ....... N.E. E~INGUISHING MEDIA ............. Dry chemical, C02, foam or water spray. SPECI~ FI~ FIGHTING PROCED~ES Use a self-contained breathing apparatus with full facepiece opera=ed in pressure-demand or other positiue pressure mode. E~SION DATA .................. Vapors can flow along surface~ to distant ignition sources and flash back.~ 03/23/1994 N.E.= Not Established N.A.= Not Applicable Page -1- ]igFr.~40 HMI$ HAZARD INDEX ~EALTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: j HAZARDOUS COMBUSTION PRODUCTS... carbon monoxide, carbon dioxide, and unidentified organic compounds in black smoke PRIMARY ROUTES OF ENTRY ......... SKIN CONTACT EYE CONTACT SKIN ABSORPTION INHALATION ACUTE OVEREXPOSURE EFFECTS: SKIN CONTACT ................. Prolonged or repeated exposure may cause skin irritation. SKIN ABSORPTION .............. A single prolonged exposure may result i! the material being absorbed in harmful amounts. Excessive exposure may impair the blood's ability to transport oxygen. Repeated minor exposure may result in absorption of harmful amounts. EYE CONTACT .................. May cause moderate eye irritation. May cause moderate corneal injury. Effects may be ~low to heal. Vapors may irritate eyes. INHALATION ................... A single p~olonged (hours) excessive inhalation exposure may cause adverse effects. Excessive exposure may cause irritation to upper respiratory tract. Observations in animals include blood and kidney effects. INGESTION .................... Small amounts swallowed incidental to normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause injury. 03/23/1994 N.E.= Not Established N.A.= Not Applicable Page -2- BJ H~4IS HAZARD INDEX HEALTH: FI2%MMABILITY: 2 ~CTIVITY: 0 P~SON~ PROTECTION: J C~ONIC OV~RXPOS~ EFFECTS .... Repeated overe~os~e may cause damage to ~he liver, kidney~, lungs and red blood cells causing blood in the ~ine. Repeated skin contact may absorb bagful ~ount~. E~OS~E LIMITS: ~Z~OUS CO~ONENT ACGIH TLr OS~ PEL Ethylene glycol monobutyl ether 25 ppm 25 ppm ~CINOG~ICITY, ~PRODU~IVE In animal studies, fertility or EFFECTS ........................ reproduction were affec:ed only following potentially lethal oral doses. T~TOG~ICITY, ~AGENICITY .... Birth defects are unlikely. E~osures having no effect on ~e mother ~hould have no effect on ~e fetus. Did not cause birth defects in animals. Results of nutagentcity tests in animals have been negative. TOXICITY STUDIES LD(50) ....................... 4?0 mg/kg (oral rat) LC(50) ....................... 700 ppm/Thr (inhal mouse) FOR EYES ........................ Immediately flush with plenty of water for at least 15 minutes. SEEK MEDICAL ATTENTION IMMEDIATELY! FOR SKIN ........................ Flush skin with water or wash with mild soap and water if available. If irritation persists, contact a physician. Wash clothing before reuse. Destroy contaminated shoes. 03/23/1994 N.E.~ Not Established N.A.= Not Applicable Page -3- ~J SERVICES ~a~TER/ALSAFET~ ma?a ~ INF~O 40 HMIS HAZARD INDEX HEALTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: j FOR I~TION .................. Remove to fresh air. If breathing is labored, give oxygen. If breathing has stopped, give artificial respiration. Keep person warm, quiet and get medical attention. FOR INGESTION ................... Give plenty of water. INDUCE VOMITING! Never give any=hing by mouth to an unconscious or convulsing person. SEEK MEDICALATTENTION IMMEDIATELY! APPEARANC~ AND ODOR ............. Clear colorless liquid, mild odor SPECIFIC GRAVITY ................ 0.902 VAPOUR PRESSURE ................. 0.6 VAPOUR DENSITY (air=l) .......... 4.1 EVAPORATION RATE ................ BOILING POINT ................... 340 oF FREEZING POINT .................. N.A. SOLUBILITY IN H20 ............... Soluble pM .............................. N.A. SECTION ~II - ~EACTIFITY DATA CHEMICAL STABILITY .............. Stable INCOMPATIBLE MATERIALS .......... Strong oxidizing agents HAZARDOUS POLYMERIZATION ........ DOES NOT POLYMERIZE HAZARDOUS DECOMPOSITION PRODUCTS Carbon dioxide, carbon monoxide, varioum hydrocarbons SECTION VIII -SPECIAL/PERSONAT. PROTECTION 03/23/1994 N.E.- Not Established N.A.~ Not Applicable Page -4- ~J SERVICES ~ATERL~LSAFET~DATASHEET INPTuO40 HMI$ HAZARD INDEX~ HF2LLTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: j VENTILATION ..................... The use of mechanical ventilation is recommended whenever this product is used in a confined space. Where enqineerinq controls are not feasible, assure use is in an area where there is natural air movement. RESPIRATORY PROTECTION .......... Cartridge or Cannister Respirato~ Organic Vapor PROTECTIVE GLOVES ............... Neoprene EYE PROTECTION .................. Goggles OTHER PROTECTIVE' EQUIPMENT ...... Eyewash bottle~ or other rinsing equipment should be ~asily accessible. Apron SECTION IX -HANDLINGPRECA~ONS LEAK AND SPILL PROCEDURES ....... Dike or contain spill to prevent material from entering waterways. Pump large spills into ~alvage containers. Soak up residue or ~mall spills with absorbent pads, clay, or dirt and place in salvage containers. WASTE DISPOSAL .................. DiSpose of according to all local/state/and federal regulations HANDLING PROCEDURES & SPECIAL EQUIPMENT ...................... Keep away from heat, sparks and flames. Avoid contact with eyes,skin and clothing. Av6id breathing fumes. STORAGE REQUIREMENTS ............ Store in a cool, dry, well-ventilated place away from incompatible materials. Do not store in aluminum containers. SECTION X - R]~;UIATORY INFORMATION INFORMATION 03/23/1994 N.E.- Not Established. N.A.- Not Applicable Page -5- MATERIAL SAFETY ~a SHEET HIS HAZA/~D INDEX MF2tLTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: j PROPER SHIPPING NAME ......... Ethylene Glycol Monobutyl Ether HAZARD CLASS ................. 6.1 (Keep away from food) UN/NA NUMBER ................. UN 2369 PACKING GROUP W/ "PG" ........ PG III SUBSIDIARY RISK .............. N. A, REPORTABL£ QUANTITY (RQ) ..... N.A. ~ERGENG¥ GUIDE RESPONSE #... 26 SARA T/TI~ III SECTION 302/304 ............ This product does not contain ingredients li~ted am an Extremely Hazardous · Sub~tance. SECTION 311/312 ............ IMMEDIATE, DELAYED AND FIRE SECTION 313 ................ This product contains the following ingredients (at a level of 1% or greater which appear on the List of Toxic Chemicals: Ethylene glycol TSCA I~ENTOR¥ ................ All ol the co~ponen~s in this produc~ appear on the T$CA inventory. CALIFORNIA PROP 65 ........... None of the chemicals on the current Proposition 65 list are known to be present in this product. SECTION # REVISION IV Health hazard information updated 03123/1994 N.E.~ Not Established N.A,~ Not Applicable Pa~e -6- ~MIS HAZARD INDEX HEALTH: 3 FLAMMABILITY: 2 RJCACTIVITY: 0 PI2~SONAL PROTECTION: j The information contained herein is based on data considered'accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, vendor assumes no r.sponslbillty for injury to vend.e or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes.the risk in his use of the material, 03/23/1994 N.E.= Not Established N.A.~ Not Applicable Page -?- ~G~ P~ON~ NO. PflODU~ NAME -'; : .. ( "" : ~. PHYSI~L ~ATA mOILING ~OINT VA~R PR~SURE NIX I~ NIA vo~Tlkl~ ~PP~RANC[ AND N/k ~I~ ~ ~0~/~SS ~ H~ 0~0~ ~. HRE AND EXPLOSION IN~ATtON ~0~ [ ~0~ LOWE~: ~/~ UPPE~: ~/~ UNUSUAL F~RE AN~ ~PLOSION H~Q~ ~0~ HEALTH EFFECTS INFORMATION SKIN ~ EYES ~ INHALATION ~ INGESTION ACUT~ (~HORTI ~X~U~E ~YES: I~ITA~0X INHA~T1ON:D~ ~0US ~S o ~NGESTiON:, N/~ EYES: N/A ~NGESTION: NJ~ N ~NCY FI~T AiD PR~mUR~ E [~: ~V~T0 F~ AI~NiS~ OX~O~N OR ~iitiC~ ~m~rloN As N~D~D. [~IA~Y. DEC-07-1994 09:4? BHI-TECH SERUS - HRR 713 ~30 3,965 ~U5 ~LYMER]~ON COND~TION~ TO AVOIO ~. SPILL OR LEAK PROCEDURES SC~ OR S~ ~. PL~E IN ~ CO~lI~S, ~ ~ROPRIA~ F~ONAL FR~CTION EQUIP~, U~ RCHA APPROYZO HAZARDOUS WASTE DISPOSAL SITE. CONb'Lr~T LOCAL, SIA~, AND ~EDRPJJ, ~O~ATIOMS 'KZI[[. SPECIAL PROTECI'ION INFORMATION .~.^'ro.¥ ..o~~ M~EN CONC~TIO~S ~CEED ~O~ LIMITS. U~ PROPHR NIO~ ~FRO~ CAR~D~ ~SPI~YOR. ~N LIMITS K~ CONC~O~ B~OW ~O~ LIMIYS. ~E P~ION IX. HANDLING AND STORAGE INFORMATION b"l~3~ FRODUC~ IN CLOSED COIq'fAIMlP~S IN COOl~, DRY FLACR. AVOID BRHA~ING DUS'f. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENT5 AND REAUTHORIZATiON ACT OF 1986 (SARA). ~0 ~0 ~0 ~RA TOXIC ~0 OSHA HA~E~U~ CHEMICALS ~ IMMEDIATE (ACUTE) HEALTH HAZARD ~ DELAYED (CHRONIC) HEALTH HAZARD ~ FIRE HAZARD ~ SUDDEN RELEASE OF PRESSURE HAZARD ~ REA~V~ HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): N/A - 0ATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NO? ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DC GIVE PERMISSION, iNDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT iS GIVEN SOLELY FOR ~ CONSIDERATION, INVESTIGATION, AND VERIFICATION. ~EFORE USING ANY P'RODUCT, READ ITS LABEL. TOTAL P. [~ Ii} Pi k' E t-'-! :i!.", r::'~ N t~! t';i: 0 N '1" I?. (;} i... 5 5 5 ;I. F':il... [} 1;;; ~11 ix! E:(J U F.;"I" E~A l'(lii; RSI::' ;[ El.. I] , CA ~;)(ii3:l. 3 , V ~'~ N (.,~ ~'.":~"F Iii; IR-E; & R 0 ~':'} E; IR S ;1: N r.;;, , .'.'ii; U Iii S :!: !::~ ;l; r::~ IR Y (;;~ F:' U N ;1: kC F.', IR ( 2 0 ~'."., ) ,?, (?, ?'"' 3 4 0 0 & :1. 0 0 C ¢'~ I;:". ;[ L. I....O ~"..! F:' (:;~ :£ ~"..! T ., !*'.' ;1; !R 14 L ~::i i"--.! 1;) ., ~.,j ;'r:i':i,:' i!i: 0 ~i.~ 3 .......................................................................................................... Iii: i".ttii; IR ~:;-) IZ N C Y ¢: S S ;1: S 'fh':':~ h..'.r..'.': E ............................................................................................................... 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(::C'.CURA'I"EJ, gl;.J&l:~ i"'~ A I< E: !3 NC) t~'.EF~it!EJSE:N'i"A't"]JL]NS (:;,(3 TO SUF:'F:']:C:IiiEi'--K;Y, C.C:iND:E"i"]:(:INS Ol:: [.JSFJ r::'~l:~l!i: li.lliiJYCJN[) g!,,i&lk'.S (:;CiN"f'F.:.','.:)t... AND · ' L, (.. ', 1.., .,. T ]: (:.iN!~; 'f'O .... '"" :~r't/',':::' 11"~. !il DATA L! i".! L, l::. k 'f'!"tl;i::l: ('~ JN t? F: IE Ii (-'.', 'I" :I; N !": * '~i: ""' ~. ~ r: t:.. F?. Ii:: :iii; ..... :1: Iii I... li'] "l' C.t b' Ii!: R .!: F:' Y '" '" '; .... ' I.? ... D i!i:'t"li!: R H :1; N E t.,.l Hi!i:"l" H E R T' I"!I!E F: F;..'O I:) U C T' :[ !ii; !il t..! ]: T'.":.~ li!: L. E: F:' (:.11;:: T HiE :i: R F:'(::~ R"I" ]. C L.II... A R F" U I"--": P -C.i.S;i!i: S A N i:) T H iii: Y · ('IS.SUHE AI...L. R]::iiil'::.S OF: 'i" H IE :I; t( U,S;I!i:, I"h':.',N[)t...]:NC'.i, r.":~N!:) [)'I:Si:'"C}."i!;.,':'.'.,L. C.'.F:' 'l"l"ilii: F:'RO[!UCT., CiR F"F;:OH 'l"l"llii: F:'UE:L..]:C.'.'A'i":[5'N CiR i.lSiii: gl::., gl:':: i:-."..r.'i'l...:l:¢:'."~N(.'::l].'!: UF:'C1;'-~ , ]:NF:'OFi'NAT]:C. IN CCiNTA]:NI!i:D 'Y'I-I:!'S ]:NF:'C)F/NAT:I:ON RE:LATiii:.'3 ONt...Y 'f'C,' 'f'l.-llii: I:'~I:-.-'.::;}I:ILH.:iT DE:S.I:C.)N(..','f'E:D I..I E: FI Ii!: ]: N , r::~Nl:.~ [.':C)lii:S NCi'f' RIEL.,/'.'F¥'Ii:_' 'f'O ;l;'l"!i:: U!ii;E: :IN C'::if'tli;~]:NAT:[CIN t..j:[TH ..'::'~NYO'i"HE:Fi NA"FE:R]:AL. OR ;I;N ANY OT'HE;F;: F" R 0 C'. l!i: S Ii!; , · ;,.. .:'-,. ..,'.. lie N I:) 0 F:' N !ii; D !ii; ./,. 4 . LIQUID AIR CORPORATION INDUSTRIAL GASES DIVISION ,Material Safety Data Sheet PRODUCT NAME Oxygen TELEPHONE (415) 977-6500 EMERGENCY RESPONSE INFORMATION ON PAGE 2 LIQUID AIR CORPORATION TRADE NAME AND SYNONYMS CAS NUMBER 'NOUSTRIAL GASES D'VISION One California Plaza, Suite 350 (~xyg en 7782-44-7 2121 N. California Blvd. CHEMICAL NAME AND SYNONYMS Walnut Creek, California 94596 0xygeR ISSUE DATE OCTOBER 1, 1985 FORMULA MOLECULAR WEIGHT CHEMICAL FAMILY AND REVISIONS CORPORATE SAFETY DEPT. 02 31. 999 0xi di zer HEALTH HAZARD DATA TIME WEIGHTED AVERAGE EXPOSURE LIMIT None established (ACGIH, 1984-85). Oxygen is the "vital element'' in the atmosphere in which we live and breathe (apProximately 21 molar % of the atmosphere). SYMPTOMS OF EXPOSURE Breathing high concentrations (greater than 75 molar percent) causes symptoms of hyperoxia which include cramps, nausea, dizziness, hypothermia, ambylopia, respiratory difficulties, bradycardia, fainting spells and convulsions capable of leading to death. For additional data on hyperoxia as it relates to oxygen pressure and exposure duration, ~refer to L'Air Liquide's Encyclopedie des Gaz. TOXICOLOGICAL PROPERTIES The property is that of hyperoxia which leads to pneumonia. Concentrations between 25 and 75 mol'ar percent present a risk of inflammation of organic matter in the body. Listed as Carcinogen National Toxicology Yes [] I.A.R.C. Yes [] OSHA Yes ~ or Potential Carcinogen Program No [] Monographs No [] No ~ RECOMMENDED FIRST AID TREATMENT PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO OXYGEN. RESCUE PERSONNEL SHOULD BE COGNIZANT OF EXTREME FIRE HAZARD ASSOCIATED WITH OXYGEN-RICH ATMOSPHERES. Conscious persons should be assisted to an uncontaminated area and breathe fresh air. They should be kept warm and quiet. The physician should be informed that the victim is experiencing (has experienced) hyperoxia. Jnconscious persons should be moved to an uncontaminated area and given assisted piration. When breathing has been restored, treatment should be as above. ]ontinued treatment should be symptomatic and supportive. Judgements as to the suitability of information herein for purchaser's purposes are necessarily purchaser's responsibility. Therefore, although reasonable care has been taken in the preparation of such information, Liquid Air Corporation exfends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's intended purposes or consequences of its use. Since Liquid Air Corporation has no control over the use of this product, it assumes no liability Ior damage or loss of product resui[ing from proper or improper) use or application of the product. Data Sheets may be changed from time to time. Be sure to consult the latest edition. LAC 05r27 H. AZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES Oxygemvigorously accelerates combustion. Contact with all flammable materials should be avoided. Some materials which are not flammable in air will burn in pure oxygen or oxygen-enriched atmospheres. PHYSICAL DATA BOILING POINT LIQUID DENSITY AT BOILING POINT -297.35°F (-182.97°C) 71.23 lb/ft3 (1141 kg/m3) VAPOR PRESSURE ~ 70OF (21.1°C) above the GASDENSITYAT70°Flatm critical temp.@o~f~ 181.433°F (-118.574°C~ .0828 lb/ft3 (1.326 kg/m3) SOLUBILITY IN WATER 8;F (20°C) BL~nsen ' FREEZING POINT coefficient = .0310 -361.838°F (-118.574°C) APPEARANCE AND ODOR Colorless, odorless and tasteless gas. Specific gravity @ 70F (Air=l.0) is 1.11. FIRE AND EXPLOSION HAZARD DATA FLASH POINT (METHOD USED) I AUTO IGNITION TEMPERATURE r FLAMMABLE LiMiTS % By VOLUME N/A N/A N/A EXTINGUISHING MEDIA Copious quantities of water for fires with IELECTRICALCLAsslFICATION oxygen as the oxidizer, I Nonhazardous SPECIAL FIRE FIGHTING PROCEDURES If possible, stop the flow of oxygen which is supporting the fire. UNUSUAL FIRE AND EXPLOSION HAZARDS Vigorously accelerates combustion. REACTIVITY DATA STABILITY CONDITIONS TO AVOID Unstable Stable X INCOMPATIBILITY (Materials to avoid) All flammable materials HAZARDOUS DECOMPOSITION PRODUCTS None HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur Will Not Occur X SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in user's equipment, be certain to purge piping with an inert gas prior to attempting repairs. If leak is-in container or container valve, contact the closest Liquid Air Corporation location. WASTE . . DISPOSAL METHOD not attempt to dispose of residual or unused quantities. Return in the shlpplng tainer ~abeled, with any valve outlet ~or c__~_~_p_~secured and valve tection~~~ Air--for proper disp--~-~: ~ em-~ency [s contact th~ ~-losest Liquid Air Corporation location. EMERGENCY RESPONSE INFORMATION IN CASE OF EMERGENCY INVOLVING THIS MATERIAL, CALL DAY OR NIGHT (800) 231-1366 OR CALL CHENITREC AT (800) 424-9300 _~ SPECIAL PROTECTION INFORMATION Page 3 tRESP~IATORY PROTECTION (Specify type) N/A VENTILATION ~C umu l a t i o ~q SPECIAL To prevent accumula- tion above 25 molar / MECHANICAL(Gen.) OTHER ~rcent. PROTECTIVE GLOVES As required; any material EYE PROTECTION Safety goggles or glasses OTHER PROTECTIVE EQUIPMENT Safety shoes, safety shower SPECIAL PRECAUTIONS* SPECIAL LABELING INFORMATION DOT Shipping Name: Oxygen or Oxygen, compressed DOT Hazard Class: Nonflammable gas DOT Shipping Label: Oxidizer I.D. No.: UN 1072 SPECIAL HANDLING RECOMMENDATIONS Use only in well-ventilated areas. Valve protection caps and valve outlet threaded plugs must remain in place unless container is secured with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing regulator when connecting cylinder to lower pressure (<3000 psig) piping or systems. Do not heat cylinder by any means to increase the discharge rate of product from the cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. For additional handling recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet P-1. SPECIAL STORAGE RECOMMENDATIONS Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away .from heavily trafficked areas and emergency exits and away from full or empty stored cylinders which contain flammable products. Do not allow the temperature where cylinders are stored to exceed 130F (54C). Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in-first out" inventory system to prevent full cylinders being stored for excessive periods of time. For additional storage recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet P-1. SPECIAL PACKAGING RECOMMENDATIONS Carbon steels and low alloy steels are acceptable for use at lower pressures. For high pressure applications use stainless steels, copper and_its alloys, nickel and its alloys, brass, bronze, silicon alloys, Monel~, Inconel®or b~ryllium. Lead and silver or lead and tin alloys are good gasketing materials. Teflon~and Kel-F~are the preferred nonmetal gaskets. Special Note: It should be recognized that the ignition temperature of metals and nonmetals in pure oxygen service decreases with increasing oxygen pressure. For additional information refer to_L'_Air. Liquide's Encyclopedie des Gaz._ _ OTHER RECOMMENDATIONS OR PRECAUTIONS Oxygen should not be used as a substitute for compressed air in pneumatic equipment since this type generally contains flammable lubricants. Equipment to contain oxygen must be "cleaned for oxygen service." See Compressed Gas Association Pamphlet G-4.1. Compressed gas cylinders should not be refilled except by qualified producers of :ompressed gases. Shipment of a compressed gas cylinder which has not been filled the owner or with his (written) consent is a violation of Federal Law (49CFR). 'Various Government agencies (i.e., Department of Transportation, Occupational Safety and Health Administration, Food and Drug Administration and ot~ers) may have specific regulations concerning the transportation, handling, storage or use of this product which may not be contained herein. The customer or user of this product should be familiar with these regulations. i ¢OAST GAS Dear Customer: The Federal Occupational Safety and Health Administration (OSHA) recently published "The Hazard Communication Standard" · (29 CFR Part 1910.1200), establishing a number of requirements for developing, obtaining and providing health and safety in- formation of potentially hazardous chemicals used in the work place. Of particular note is the requirement that "Employers shall have a Material Safety Data Sheet for each hazardous chemical for which they use." Included in the definition of "hazardous chemical" are substances that are flammable. As a purchaser of Coast Gas propane, we are providing you with the following MSDS to assist you In meeting this OSHA Standard. We request that you forward this information to the appropriate person responsible for safety and health In you organization. Coast Gas appreciates your business and will be happy to discuss with you the availability of safety or training programs relative to the use of its LP-gas. MATERIAL SAFETY DATA SHEET Section ! Emergency Suppliers Name Phone Number Name Liquefied petroleum gas or Propane CAS Reglstr~ No. 74-98-6 Family Hydrocarbon Formula C,~H8 HAZARDOUS INGREDIENTS Section Il Hazardous Mixtures Air with 2.15 to 9.60 percent propane PHYSICAL DATA Section Boiling point -44 F Specific Gravity {H20=1) 0.51 .Vapor Pressure {mm HG) at 100 F 9825 Percent, Volatile by Volume (%) 100 .Vapor Density _(Air--1) 1.52 Evaporative Hate None Solubility in Water Slightly Appearance and Odor Clear--unpleasant odor (caused by odorant) FIRE AND EXPLOSION HAZARD DATA Section IV Flammable limits Flash Point N/A Classification Flammable Gas UN 1075 Extinguishing Media Water Spray: Class A-B-C or BC Fire Extinguishers Special Fire Fighting Procedures Stop flow of Sas. Use Water to keep fire-exposed containers cool. Use water spray to disperse unignited Sas or vapor. If ignition has occurred and no water available, tank metal may weaken from overheating. Evacuate area. If sas has not ignited, LP-~qas liquid or vapor may be dispersed by water spray or flooding. HEALTH HAZARD V IAmlt Value 1,000 PPM Effects of Overexposure Inhalation--concentration can lead to s_~mptoms ran~qing from dizziness to anesthesia and respiratory arrest. E_~es--moderate irritation. Emergency & First Aid Procedures Inhalation--Remove to fresh air. Guard against self-injury. Apply art(ficial respiration if breathin!l has stopped. REACTIVITY DATA Section V! Stable X Unstable · Hazardous Decomposition Products None Incomparability (materials to avoid) Mixing with oxygen or air~ at burner. Hazardous Polymerization: May occur Will not occur X SPILL OR LEAK PROCEDURES Section VI! Steps may be taken in case material is released: Keep public awa_v. Shut off supply of gas. Eliminate sources of ignition. Ventilate the area. Disperse with water spra_~. Contact between skin and these gases in liquid form can cause freezing of tissue causing in]ur~ similar to thermal burn. Disposal Method Controlled buminq. Contact supplier. SPECIAL PROTECTION INFORMATION Section ..... Respiratory-Protection- :- $ta:~ out Of~.gas-or-vapor-(because-of fire-hazard) Ventilation Explosion-proof motors and keep sources of ignition at safe distances. Personal Protective Equipment and Apparel Leather or equivalent gloves, goggles for protection against accidental release of pressurized products. MATERIAL SAFETY DATA SHEET SPECIAL PRECAUTIONS Section IX Precautions to be taken when handling and storing Keep containers away from heat sources and store in urori~ht roosition. Containers should not be dropped. Keep container valve closed when not in use. Other Precaution Install protective caps when not connected for use. TOXICOLOGICAL INFORMATION Section X OSHA Carcinogen Classification (29 CFR 1910 Not listed/applicable X Category I Carcinogen Category II Carcinogen Listed as Possible Category I Listed as possible Category II DOT LABELING INFORMATION (49 CFR 100-199) Section X! Proper Shipping Name Liquefied Petroleum Gas Hazardous Classification Flammable Gas Identification_No..._ UN 1075 Label(s)_Required Date of Preparation or Last Change: April 24, 1987 m~,ar- . J'..~U:" ,' SAFETY-KLEEN 105 PARTS WASHING SOLVENT MATERIAL SAFETY DATA SHEET |' SECTION I -- PRODUCT INFORMATION J Safety-Kleen Corporation - 77'/Big Timber Road. - Elgin, IL 60123 For Product/Sales Information Call 708/697-8460 EMERGENCY TELEPtlONE MEDICAL: TRANSPORTATION: Ta~s~ ~m~-~ sr. r~- ~e~m, ~ ~/~2-~9 ~ 31~2-~9 ~/~9~ ~. ~y~ d~ ~~ RU~ ~N COBOL C~ ~f~ ~ ~ F~ CHI~, ~LINO~ ~ HO~ ~YNO~M$: " 'P~OLE~ DI~~, ~OLE~ N~HA, 'SK P~ ~UMBERi ~17 F~IL~/CH~I~ N~E: H~R~ON PRODU~' USAGE:' .. SOL~ FOR ~~G ! ' ........... SE~IO~ ~ HAZ~OUS ~ ~13 ~) · Xyl~ 1.o ~~~ < 03 I~-1 ~P~CE ~D O~R: ~~lc ~q~ - BO~NG POI~: 3~° - 4~° F PAGE . .EVAPORATION RATE: (Bulyl Acetate = 1) 0. l PERCENT VOLATILE: 99.9% VAPOR DENSITY: 4.9 (Air= I) VAPOR PRESSURE: 2 mm of Hg at 68° F SOLUBIL.ITY IN WATER: Negligible ,oH: Not Applicable SPECIFIC GRAVITY: 0.77 to 0.80 MOLECULAR WEIGHT: Approxima,.ely 142 VOLA TILE ORGANIC COMPOUNDS: 795 g/L SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: 105° F ($ETA) AUTOIGNITION TEMPERATURE: 473° F CONDITIONS OF FLAMMABILITY: Mmeria~ must be moderately heated before ignition can occur. FLAMMABLE LIMITS IN AIR. LOWER: 0.7% UPPER: 6.0% EXTINGUISHING MEDIA: Cadxm dioxide, foam, dry chemical, watex (mist only). FIRE FIGHTING PROCEDURES- SPECIAL: NFPA 704 Rating 2-2-0 Keep s~:n'ag¢ tanks cool with water Hray. Use serf-contained breathing appm (SCBA), 'UNUSUAL F. IRE AND EXPLOSION HAZAJ~S: Decomposition and combustion prcxtucts amy be toxic. Heated tanks may rapture, ~plode Or be thrown into thc air. Va~rs are heavier than air and may travel gxeat dismcea to ignition ~ HAZARDOUS COMBUSTION PRODUCTS: Thermal ~com~ition and burning may produce carbon monoxide~ STABILITY: Normally stable even under fire expoaz~ conditions and is not reactive with water. Normal f'm:fighting procedures may be INCOMPATIBILITY (CONDITIONS TO A VOID): Strong oxidiz_ing agents (e.g. chlorine, peroxides, strong acids). HAZARDOUS POLYMERIZATION: Not known to occur under normal condition& HAZARDOUS DECOMPOSITION PRODUCTS: Normally none; however, incomplete burning may yield cartxm monoxide. SECTION VI - HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE: Skin and ¢y¢ contact; inImlalioa, ttEALTtt HAZARD DATA/SIGNS A. ND SYMFTOM$ OF EXPOSURE: ACUTE: S/da: Protongefi c~ repeated contact tr. nds to remove ~ ~ posgib/y lcading to irrirnti,-~ and dermatttiz. No sign/tic:mt skin abzorpdon _t~p,_ m~:L 105 Ptru W~d~:a~ Sotvem - p~: 2 of 4 Ey~r. Contac[ may cau.~ ~ight to moderat, irmat/on. Itigh va~r concentrat/ons (> 500 ppm) are laA~a: I-Dgh conce~w~ion~ of vapor o~ mi~t may bc irrimfi,~g ~o ~ re..~i~tory u'~ct, ca~e Inges~n: ~w order of ~ o~ ~x~ity. ~y ~ ~fion of ~e ~, ~ vo~fing ~d ~ptoms of c~ ~. ~S~ d~i~. ~on ine, ~c lun~ d~g lagoon or vo~ng CHRONIC: ~l~ged ~Oor ~t~ ~nmct ~y ~ ~Mg ~d c~mg of ~c ~ ~ d~fi~. ~HER P~E~ H~TH HA~S: MEDICA~ COND~IOffS A~ VATED BY EXPOSU~: SE~ION ~ - E~RGEN~ ~ ~ ~ PRO~D~ 5PI~ ~E DISPOS~ ~y~g. H~D~NG ;HIPP1NG ~ . PERSONAL H!".'.;:IENE: U~e ~ood personal hygiene. Wa..~h thoroughly wi~ soap and ~ aftra' ha.adl~g and before eating, drinking or using tobacco products. Laundcx contaminated clothing and clean protective " equipment before reuse. SECTION IX - CONTROL MEASURES VENTILATION: Provide local exhaust or general dilution ventilation as dcxermincd ncc. easat'y to maiatam concentrations of vapors or mists below applicable cxposuw limits. Where explosive mixtures may be pre~ent, systems sa/'¢ for .~.uch locations should be usecL PROTECTIVE GLOVES: Usc mtrile or neoprene glovc~ ~o prevent contact with akin. EYE PROTECTION: Where there is likeLihood of spill or ~plash, wear chemical gogglea or race. shield. Contact should not be worn. RESPIRATORY PROTECTION: Use NiOSH-approved reapiratocy protective equipment when concentration of vapors or mists exceeda appticabic expasu~ limit. De4)endiag oa thc aittxna~ concentration, u~ a rca'pixator or gas mask wire appropm~ cartridges and ~c~_ i_~:~ (for organic vapor ~ith Mt preCtlta'). A sca'- comained breathing apparatus ($CBA) is required for large spills and ~ Selection and u.~ of respiratory protective cquipmemt should be in ~ with OSHA C.,eaenal Indu$~ Standard 29 CFR I910.134 - Respirato~ Protection. OTHER PROTECTIVE EQUIPMENT: Wear solvcnt-rc.~tant boots, apron ar otl~r protective clothing wbez: sTAlls and sgbtshe~ are gnysaible. A source of clean water should be available in work ar~s for flO_-.hing thc cyca aad ak~n " SECTION X -- OTHER REGULATORY INFORMATION DOT PROPE~ SHIPPING NAME: P~troleum Naphtha DOT CLASS: Combustible Liquid DOT NUMBEI~: UN 1255 SARA 17TLE II1: Product contains a toxic chemic, al or chomP, als subject to the reporting requixtments of Section 313 of Tide 11I of'tbe Suge:fu:xt Ameadmeats and RcaU~ Act of 1986 and'40 CFR Part 372. Toxic conztimcma ate listed with an asterisk ia Section II of this ~uexial Safety Data Sheet. l~duc: poses tt~ foilowiag physical a.nd/ot health hazard(5) as defiaed in 40 CFR 3703 (Sectic~ 311, 31:2 of SARA Title liD: Lmmedia~ (Acu~) Hr. aha Hazard ~a~y~d (C:~nt~c) Hea~ Hazard F'~ Haza~ l SECTION XI- pREPARATION INFORMATION PREPARED BY: SK Product Review Committee FORM NO. ORIGINAL ISSUE DATE: July 20, 1989 REVISED: March 12, 1990 SUPEJtSEDES: July 20, 1989 ,=, .~ ::,,:. ,. t}" "' '"'"' ..,!..!..!i~:l/UP, iR ( 206 ) ix.! 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'. i::' i... ~'::~ ?'"i i':i :ti iil :[: i... :i: ']" Y ........ ~ O t'-.':ti:: ~'.':': C)"[' .'[ :...--: :,:: T Y .......... : :I. :i3 F:'l!i: (:} :I: F': i... H :":': Z :':'.: IR !:) ...... : {:) X ~' t3 !ii: (."; tR iii: I!:: O F' 1' :......'.... 1~ O .... i'.! (:) H :'.':': Z :':':': I:-;: ........ t::. ,'~. ::. H :::'., Z :'::'.,,~ :.., ..'" ;-~:.-,:, --...,. .... ,r,,.-. ':"~" "'"'""' t'~', i " '"" .... ri',,~:'"" q.".' ]:'.' , ,.~ ~,...1 . .;:., 1 ~..,,, ,::. t"."'. ~.":',i",~l"~ ."'~'! :? ..':'~:'"'r,,".'~;'--~""."'" 'I '¥Ii!;CHN];C¢-,I ....:;,:..,t.,k,...E.:::, " .... ~ ~-'l,..,.. , t.. Ri".t¢'~"i"];.....,,; .:.. ~", '"; "~::' tm'- r'.- '" " ....... ":' .......U I,, ,-'.;. i~ :"-- ""t '~ ......... >' ''~' :' c .......... ::,!..h ~" """' 'r ~" ?..~ ¢" v t; f'~ :'~ ........ U E;I~i: "' '"' "' V L & '~' '" r.~i' ~ /'" "; '~' ....... ~" ~''' ~'''''''''' "'" ........... '"" I.,,:. , t:.. l:,'.i'~ :!: N l:: ...... ~ ,. R ..... I" ,~,..; ~ .. ~., ~ ~1: '.':'; ..... '" "; ~ "' i:'" ~: ~. :,, ~-!.::.~.:::. :.,,' i::. ~.. ~... L R" ¢'' """ .f...:: }'-...::.'. -~] F' "t" H iii; ]: R ', ~ ::.'.I::' '::'.'i N "l ....... "":"" '" ... ,....t.,~'~. , ,..,.~.~ :~: ...... !'~!:..,, ...... t.:-.':~::. (] F': C R ', '", 'r .',.'. ~' ....... ",;" '~, i MAY 4 ' 20 11:12 FROM QUALITY ASSURANCE TO 918058340264 PAGE.002/003 ~ MATERIAL SAFETY DATA SHEET 7000~olllster Rd., Sure 300 ' ' Emerge~ Telephone:' ~13)-43~ ~ --.~~ Houston, Texas 77040 ~a-mx CHE~REC: 1~0~2~300 X. - ~NUFACT~ER~ H~f~turer; ~[ER ~HE8 ZHTEQ HMIS Hazard Rati~ HeaLth 1 NlnlmL - Pr~t N~: TEe-NIX ~ Key: FtmblLlty 0 I[ltt - 1 Chmlcl[ N~: ~KD GRANULATED BLAST-FURNACE SLAG ReKtl.vity 0 N~rate - · Chmlci[ O~crlpti~t HYDR~LIC CALCZ~ SILICATE IN AN ;NSEP~ABLE GLOSSY ~SS. Pers~[ Seri~ - 3 Prot~tt~ ~ ~evere - Pr~r Shl~l~ Descrfpt]~: DRZLL1NG FLUID C~D, N.O.S. Hazard CLass: NOT RE~LATED UN H~r: NA H~zard La~[: ~ DOT Res~e Guf~: Tr~rtetl~ Note: ~ ...... ................................ Hazmr~ A~lat~ ~tth Prat Uae t Y~ Yes Yes Y~ C~at~bLe L~d FLmbLe NateHaL Pyr~oric HateHaL ExpLosf~ H~te~l~L ~tabLe HatertmL I ~ater Relcttve H~ter~a[ Oxtdlzer Organic Peroxt~ Skin Hazard I X Eye Hazard X Toxic Ag~t Highly Toxic S~itlzer I Carct~g~ Eepr~ttve Toxin BL~ T~in Ner~ S~t~ Toxin I' L~ Toxin Ltver Toxin ~;~y Toxin C~ity Rtght-to-K~. (SARA TitLe Si; Sectf~ 311-312) Fire= 6~ ReLeail Of Preslure= Reactivity= ]~ilte (Acute)= X DeLmy~ (Chr~ic)= X .... IZZ. - PHYS;~L OATA= BolLt~ Point(F): NA Veer preSsureC~g): ~ PH= HA NeLti~ Point(F): ND Veer DenmltyCAlr-l.): ~ ~iffc Gravity: 2.~ Fr~zt~ PolntCF)l HA So[~lLlty In Water= INSOLUBLE Perc~t Vo[lttLl By Vo[~(~)x NA ~r Thr~hotd: ~LESS ~lraKe A~ ~r: G~Y ~ ~HITE ~ER Eva~retf~ Mite (... m 1): NA NeterteL Ii= NIX-~LZD Coefflct~t of ~ater/Ot[ Ol=trl~tt~: IN~LUBLE IN iV, - FIRE & EXPL~I~ HA~RD DATA: Ftaah~tnt(F)= NA Auto lgntti~ T~tatureCF).= NA FtwbLe Llmtt8 - LFLt ~ UFL= HA ExpLoel~ - LEL= HA UEL= NA '. Extl~utsh H~tl - ~ater= C02: Dry Ch~lcaL: Fo~: HIza~ C~ti~ Pr~ctB: H~E. PR~T ~ N~STIBLE. Fire Flghtt~ Pr~reB= USE EXTZN~I$HZHG HEDZA APPR~E[ATE F~ ~URR~NDING FIRE. ~ SELF C~TAiNED BREATHING APPARATUS F~ ENCLOSED ~ ~FINED AEEA~ D ~]H~ A FIRE. C~L FIRE EXPOSED CONTAINERS ~ZTH ~ATER ~RAY. ~[ Fire ~ ExpL~f~ NazifY= N~E RE~T~. V, - REACTIVITY DATA= Ch~lciL[y ~tlb[e: Y~: X No: If ~, ~r ~htch Co~ltt~l N~; REPORTEO. i~tibiity (Hltlrla[8 to Ava{d): AVOID 8TR~; OXYDZZERS ANO ACIDS. Hazar~ Dec~elt{~ or B~r~t8: ~0~; ~EP~TED. ~azar~ PoL~rtzatf~ - ~y ~cur: ~i[[ Not Occur: X Co~ftl~s to Avoid: N~E REPUTED. ~ - Not Detemt~ NA - Not A~Llceb[e T - Total Dust R - Resplrabte Fracti~ C'- CelLl~ Limit TEG-NIX I~A T~EWK OF BAKER K~HEI INTEG. Plea 1 NAY 4 20 11:15 FROM QUALITY ASSURANCE .TO 918058340264 PAGE 003/003 TEQ-~IX Prt~ry E~ure R~te - Skin C~tact; X ~kin ~orptl~; Eye C~tlCt: X l~aiit(~= X Prat Carct~tclty' - NTP= HO IARC: KO A~tt Eff~tl o~ ~T PR~UCT ~ DRY THE KIN ~D ~SE AL~LI ~RN~. THE PR~UGTFS DUST ~ IRRITATE THE EYES ANO UPPER RESPI~T~Y 1~ ~Y BE NARHFUL ~ FATAL. Chr~ic Eff~tl of ~er~ure: TNE PR~UCT/8 DUST ~g ~U~E .[NFL~TZ~ OF THE LINING TI~E OF THE INTERI~ ~ THE NOSE A~ THE C~N~. ~Y DEVEL~ A~ ALLERGIC DER~TITI~, PR~UCT ~Y ~TAI~ ¢0.05~ CHR~I~, INGL~ING ~VALENT VII. - ENER~NCY AND FIRST AID IN,TRiTIUm: Eyes: HOLD EYELIDS APART ~D FLUSH ~ITH ~ATER F~ AT L~ST 15 HI,UTES. ~TACT A PHYSICIAN PR~PTLY. Skin: ~SH TH~GHLY ~IT~ ~P AND ~ATER. RE~VE ~NT~ZNATED CLOTHING. GET HEDI~L ATTENTZ~ F~ C~R~I~ EXPIRES. [~flttm: DRINK ~ATER TO DILUTE. NEaR OZVE ~YTHiNG BY ~TH TO AN UNC~SCI~S PERSON. ~NTACT A PHYSICI~ IHRE~IATELY. T~a~atf~: REdE TO FRESH AIR. GIVE OXYGEN IF BREATHING [S DiFFI~LT ~ ARTIFICIAL RESPIRAT[~ iF NOT BREATHING. VIII. - ENVZR~KENTAL PROTECT]~ PR~EOURES: Spt LL ~AR PRIER PROTECT]~ E~I~ENT. S~EEP UP INTO ~[TABLE ~TAZNERS F~ DI~OSAL ~ RECYCLING. KEEP ~T OF ~TER~YS. KEEP DUSTS T O A HINZ~. PR~UCT AS ~PPLIED IS NOT HA~6 AC~]HO TO RCRA. O]S~E OF tN ACCORDANCE V[TH LO~L, STATE A~ FEDE~L Xa~ L I nO: ~ARNTNGI PR~UCT IS AN EYE, SKIN AND RESPIRATORY IRRITANT ~D ~Y ~USE BURNS, DO NOT GET IN EYES, ~ SKiN PRIER PROTECTZVE EGU[P~NT STATED IN THE KEEP ~TA~HEE CLOSED UHTIL USE. STYE ~NTAIHEE IH A ORY PLACE AND USE ~]TH ~E~ATE EYE$~ SKIN AXD RESPIRAT~Y PROTECTI~. IX. - OCCUPATIONAL CONTROL NEASURE$: Respiratory Prot~ctfon~ I~EAR AN APPROVED PARTICULATE RESPIRATOR FOR DUST LEVELS ABOVE EXPOSURE LINITS OR CO#FORT. VentiLation: SUPPLY 71~EQIJATE LOCAL EXHAUST OR NECHANICAL VENTILATION TO KEEP EXPOSURES BELO~ SET EXPO~JRE LINITS. Clothing: ~AR LONG PROTECTIVE 'CLOTHING VITH A IHPERVIOUS APRON FOR N)DED PROTECTION. LAUNDER BEFORE REUSE. Eye,ear: ~EAR ~AFETY GOGGLES OR FULL FACE SHIELD ~HEN USING PROOUCT. GLoves: ~IEAR RUBBER OR NEOPRENE GLOVES ~HEN HANDLING THE PROOUCT. Footuear: t~Elll NORHAL SAFETY.B(X)TS. Other #l&8uree:. USE GO00 PERSONAL HYGIENE. SUPPLY ENERGENCY SHO~ER AND EYE ~ASH STATION NEARBY. Ii~IEDIATELY AFTER k~)RKING ~[TH THE PR~D~CT, SHOI~ER ~ITH SOAP AND ~ATER. PROOUCT NAY BURN S[IN. X, - ~ODITIONAL INFOR#ATioN: D]$CLAI#ER The etlt~tl, Information, and dst& provided in this materiel ee~ety date sheet ere believed roLtabLe end sccurete by Baker Hughe~ to any user, regerdLei8 of reliance on et[ or any Part thereof. This includes ,arrantiea of marchantabltity or of fltnsss for a particular purpe~e, end Gaker Hughee INTEG esaurMe no responsibility aha:ever far advice or recoat~endattor4 made. Nothing contelr~d herein should be interpreted Il permission, tnduceMnt, or c~t to vi.olate ~y [e~ pereuant to thil i~oduct'; use, conveyance or dlepeae[. Pr~rld By: Jim Rushing Date Prepare~l: 03/17/9~ Supercecles Ise~ Dete$ I / ND - Not Detemtned IdA - Not AppLicabLe · - Greeter Than < - Lems Than C - Cefi~ng Limit Pege2 31qM 25 *06 &~241zIl"l CHEP1EX ];MC po1 3300 Bin§lc Road ~o,~o~, Texas 77055 MATERIAL SAFETY DATA SHEET Page 1 Tel.: (71.3) 895-7575 F ax: {713) 895.7586 Emergency Telephone: (7 [3) 895-7575 SECTION [ - PRODUCT IDENTIFICATION Product Name: Kelza. XC, Kelzan XCD, XANVIS HMIS ~TING: Kelznn XC Hi-Vis & Kelznn XCD Hi-Vis Healtl~ 0 ?rodtlc~ Use: Rheology cram'el h~ w. tcr based systems. Flammabili~ .I Chemical Family or ~ol'llltlll[: Xillllhsi1 giHll. Reactivi~ 0 Description: Whim to ~an poxvdcr SECTION ~1. INGREDIENTS Toxic & Hxzarthms Ingredients: Thc i,~gceclicms ol'thi~ product are on die TSCA Cl~emical Stlbstance Inventou. the Catmdian Domcslic Siib$lallCC5 List and m'c iocludcc[ in thc European im'emoG.' ct'Existing Commercial Chemical Substances (EI~CS). As of dm date otthis MSDS. Ke(zan XC. Ke[~an XC~ and XANVIS are not specifically re~flated under CERCLA. CWA. DOT m' TSCA. Il is not "~oxic" under SARA ~ille Ill, All hazardous ingredients are below de minimis SECT[ON I1[ - CHEMICAL AND PHYSICAL PROPERTIES Form: White Io mn powder Odor: sliglu Specific Gravity (wmm'=l): NA Boiling Point: NA Melting Poinl; NA Solubility in Water: Complete % Vol:nile by %WT: NA Evap. Rate (n-BuAc~l): NA Vapor Pressure (rani Hg): NA Vapor Densi~ (ai~l); NA [~: (~ l,O %: 7 Stable: Yes Viscosity sgs aC' lOo F: NA SECTION IV - FiRE AND [~XPIOSION DATA ]~Ot ~l'e'.t. iil%'oJ¥'ill[J Ibis llltlJCl'illl {,Jo I101 1211Jef v,'ilJtOllt I}l'{)pgr projective cqBiI}LIII2BI illcJBdillg S(}JJ'-COllttqJlll~cJ bi'eathing apparalu$ In common with mo.~l OfgalllC ,Batcri;IJ.s. this })foducl $llould bc fronted its a conlbustible dust in the finely divided ~lIId st~spended Stale. Flash Point: NA I=xlingtti$1'dllg Agenls: DB,chenfictll. CO:.. Fo;mt, S~¢TION V - HEALTH HAZARD DATA NAT~E OF PRINCIPLE HAZARD: Not a hcahh hazard as defined by OSHA. Permissible ConccntraliOnS (Air): NA. Excessive inlmlitliml Hlily ClI[ISC minor respirato~ disconlfo~ Effects of Overexpo~m'e: Prolonged conlacl ~vilh Ihe dr3' po~(Icr may cause ch3'ing of lite skill. Non-loxic thrm~gh JllgOSliOn mid dcm)hi EMERGENCY FIRST All) PROCEIItlRES: Eves: FhJsh ~x itlt plcnt> o1' %valor. It irritiKion developS, call a physician. Skin Contact: No tmrmlh[ c{'l~cls expected. I,halation: If If 5wallowed: Symptomat.c II'CDIIllelII. No INII'IIII~I[ :ll~cts acc expected, NA = NOT APPLICABLE NDA = NO DATA AVAILABLE SAM ~5 '96 ii:~4AH CHEME~ IHC P.~ MATERIAL SAFETY DATA SHEET P,~ge PRODUCT: Kclza, XC, Kclzan XCD, XANVI$, Kuiz;m XC Hi-Vi.~ ~ Kcl'z:m XCD Hi-Vis SECTION VI - PERSONAL PROTECTION INFORMATION V~ntih~io~ T)~c Rcquh'cd: Local Respiralo]3' Prolection; ht hca? prodt~ct dust cxposm'c :t NIOSH ;lpprovcd Protective Glove~: No~ t~orHlally required. Eye Proration: Nol ~lormally ~quircd. Od~r ~rot~ctJw Equipmnt: None. SECT1ON VII - HANDLING OF SPILLS OR LEAKS Procedures For Clemt-Up: Swce~ l~l~ ~Hled tnaiecial ',md rep:~ck:~ge. Hose spill area tl~orougNy with water. Use caution as th~ product is extremely slippco' whc~ Was[e Disposal: Dispose or in :~ccorda,c~ with local, s~aic, iu~l Cooler:il rcgul:~lio~s. S~CTION Vlll - REACTI~TY DATA Stabilil2: Product is slabl~. hicompntibilily: S~rong oxidanls. ~qrdous decomposido~ PJ-odttcls: Thcmml dccomposiiio~ products may include c[lrbot~ ~ioxide and carbon monoxide. ffa=~rdous polymerization: Wifl 'n61 oc&m ' ' " ~onditiot~s Io avoid; Non~ SECTION IX - TOXICOLOGICAL INFORMATION ,. Aquatic Toxicib' (96 hr LC~ APl Tes~ Procedure): Mysi(i s[u'imp > l.t]00.00[) ppm ~cmtox Toxicity: Pholobaclcrium ~hosphm'cum - Nol] Toxic SECTION X - SPECIAL PRECAUTIONS Precautions to be Inkel] iu Hm~dling flll(~ Storage: Nooual prccl~utions common {o gcod manufitcturing practice sl~ould ~ECTION XI - REGULATORY iNfORMATION US DOT. Proper Shippins Name: OrilllnB Mud Compouud US DOT. Haz:~rd Clas~: None ~D Number: NA Lab~l[~) Required None Freigh~ Classific;uion: [Icm ~1~864(1 NMF 10ft G Class ~(I Spcci;,l Tra,tSporl:lliou Noms None OSHA Hazt~rd CoulululHcalio~l SLlluS: NA Revision Date: 10/")5 .~,, B,~KER SAND CONTROL MATERIAL SAFETY DATA SHEET ~v'Ez, m~ 30, 1990 BSC--223 I. PRODUCT IDENTIFICATION SAND CONTROL [ P.O. BOX 61486, HOUSTON, TX 77208 [ P~ODUCT NA~v~E L3-443-7590 I A-100 1NOHG~qIC CO~RCXSION INHIBITOR ORGANIC BLEND PREPARED BY: BRIAN A. EVANS TI. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER ETHYL OCTYNOL 104-76-7 5-15 N/E N/E N/E ISOPROPYL ALCOHOL 67-63-0 1-10 400 PPM 400 PPM 500 PPM (ACGIH STEL) PROPARGYL ALCOHOL 107-19-7 i- I0 N/E 1 PPM (SKIN) N/E PETROLEUM DISTILLATE 64741-67-9 ~ 1-10 500 PPM N/E N/E III. PHYSICAL )ATA N/A N/A N/A J N/A DISPERSIBLE 0;971 @ 60°F (16°C) - N/A AMBER LIQUID WITH MILD IRRITATING ODOR ; .... IV. FIRE AND EXPLOSION INFORMATION ' i, ij UPPER: °F (27°C), TCC j WATER SPRAY/FOG/FOAM,CO2 LOWER: N/A N/A USE SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE. COOL FIRE-~.<lPOSED CONTAINE~ USING WATER SPRAY VAPORS CAN FORM IGNITABLE MIXTURE WITH AIR. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. FLA~LE LIQUID. V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF" EXPOSUR~ ~X SKIN J~ EYES J:~ INHALATION [] INGESTION ACUTE ISHORT) SKIN: IRRITATION EYES: IRRITATION, REDNESS, TEARING, BLURRED VISION INHALATION: DIZZINESS, HEADACHE, UNCONSCIOUSNESS Z O INGESTION: GI IRRITATION, NAUSEA, VOMITING, DEATH I~ CHRONIC IPROLONGEO) EXPOSURE :~ SKIN: ~ EYES: THIS PRODUCT CONTAINS A CANCER SUSPECT AGENT (MANUFACTURER) _Z INHALATION: (CAS NO. 64741-67-9) ~: INGESTION: SKIN: WASH THOROUGHLY WiTH SOAP & WATER. EYES: FLUSH WITH WATER AT LEAST 15-MIN. ~J~RALE-~: RE~;IO-'~ TO ]FRESII"ATR~- A~-:~M[NISTER-~(~E-N-'~'~"~-"~-~6IA.L RESPIRATION AS NEEDED. - ............................ INGESTED: DO NO'/' INDUCE VOMITING, GIVE PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH ~"UNCdN$C[OU~ [:,Eh.SON: "iN"A~,~L--c;~..~k-~ ~'-c~0-1~6'~ ~E~'-~E~i6~L--AITEI~T-[O-N ........................................... IMMED LATELY. NPT: NO iARC: NO OSMA: NO i NONE IDENTIFIED ~ SKIN, EYES, CNS, GI SYSTEM VI. REACTIVITY INFORMATION STABILITY I CONDITIONS TO AVOID INCOMPATIBILITY (MATERIALS TO AVOID) STABLE I HEAT, SPARKS, OR OPEN FLAMES STRONG OXIDIZING AGENTS m:Z kARDOUS POLYMERIZATION CONDITIONS TO AVOID '-,': ~L NOT OCCUR NONE "[RMAL DECOMPOSITION PRODUCTS CO, NO~, SOx VII. SPILL OR LEAK PROCEDURES STEP~ TO RE TAKEN IF MATERIAL IS R£LFr.,ASED OR SPILLED SMALL SPILL: COVER WITH SAND OR COMMERCIAL ABSORBENT AND PLACE IN SUITABLE CONTAINER. LARGE SPILL: DIKE, PREVENT ENTERING b~w~u~/~L£~wAi. ~r~u~o~ki~ iD ~{OLDiNG ~-A~K. CO'v~R ~iD~-~ ~'-;; ~A~;"D ~,,"~ ................... A~,"D ~"L:C-"- I:: ~UIT.~L-" .~,~n USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. FLAMMABLE LIQUID. SHUT OFF IGNITION SOURCES. WASTE DISPOSAL METHOD USE RCRA APPROVED HAZARDOUS WASTE DISPOSAL SITE. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS VIII. SPECIAL PROTEC_TJp_N_I_N__FgR.._MA.T. Iq_N_ ...................... OF CARTRIDGE RESPIRATOR EXCEEDED, USE .NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS WITH FULL FACEPIE~E. ................ u~ ~ ~ .~ .... ~ATIC:: .~'~.Y ~.~. :;~CESSAP. Y '"~ KEEP CONCENTRATION BELOW EXPOSURE LIMITS. PROTECTIVE GLOVES RUBBER, NEOPRENE, NITRILE, VI~ON CHEMICAL SP[J%SH GOGGLES OR FULL FACE SHIELD AND S~'~¥ SHC~mR/DRENCHING PAC[;.ITY S~OULD SE AVAIZJU~LE. IX. HANDLING AND STOEAGE INFORMATION AVOID BRF. ATHING VAPORS/MIST AND CONTACT WITH sKIN, EYES, OR CLOTHING. KESP CONTAIN~B TIGWrLY CLO$ED W~EN NOT IN USE. HAT~A~DOU$ RESIDUE MAY REMAIN IN EMPTY DRUM. DO N(g£' WdSu~h C~JN'I'~INhJ4~. t'M~[Jl'l~.~ NOtU'U%,. taJuO ~'~t~:~JN~%L HkGiEm[. FLi~4Ph~b,.,- LiQUiD. A-vuiD HEAi, SPARKS, OR OPEN FLAMES. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARD(~US SUBSTANCES NO YES, PROPARGYL ALCOHOL, RQ = lO00 LBS, UNLISTED HAZARDOUS WASTE DOO1, RQ = 100 LBS NO YES, ISOPROPYL ALCOHOL OSHA HAZaRdOus CHEMICALS [] IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD ¥£s, £~A ~AZA~DOUS WAST£ ~O. ~[0~, DO0[ HAZARDOUS WASTE (RCRA. 40 CFR 261): N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL J EF'FECTIVE DATE B_~:-:,2',,MATERIAL SAFETY DATA SHEET j ~vE~:a 30, .,990 L PRODUCT IDENTIFICATION MANUFACTURER'S NAME / ADDRESS -~-'"~BAKER SAND CONTROL J P.O. BOX 61486, HOUSTON, TX 77208 PHONE NO. TPROOUCT NAME I 43-7590 { A-101 HIGH TEMPERATURE INTENSIFIER , CHEMICAL DESCRIPTION ORGANIC ACID PREPARED BY: BRIAN A. EVANS II. HAZARDOUS INGREDIENTS J EXPOSURE LIMITS INGREDIENT CAS NO. APPROX OSHA PEL ACGIH TLV OTHER FOJ~MIC ACID 64-18-6 90 5 PPM 5 PPM N/E III. PHYSICAL DATA BOtLIhG POINT VAPOR PRESSURE 214oF (10loC) 23 mm Hg @ 68°F (20°C) ,'AP~:~ ~ENSITy (AIR ' I , EVAPORATION RATE (BUTYL ACETATE 1.6 1.6 ~J'E~..!TY IN 'WATER SPECIFIC GRAVITY (WATER : SOLUBLE 1.208 @ 68°F (20°C) 100% (v/v) WATER-WHITE LIQUID WITH SHARP ODOR IV. FIRE AND EXPLOSION INFORMATION ;lOF (60.6oc) TCC J ALCOHOL, FOAM, CO2 18.0 J 'I LOWER: IIUPPER: 57.0 USE SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE. COOL FIRE-EXPOSED CONTAINERS USING WATER SPRAY. ALCOHOL-TYPE OR ALL PURPOSE--TYPE FOAMS FOR LARGE FIRES. CO2 OR DRY CHEMICAL FOR SMALL FIRES. WEAl{ FULL u~o'£~L~£~v~ CLU£~IN~ 'l~J ¥~v~N'~' ~x~ ~O~iAC/ VAPORS CAN FORM IGNITABLE MIXTURE WITH AIR. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CORROSIVE LfQUID. V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE ~_X SKIN [] EYES J~ INHALATION [] INGESTION ACUTE {SHORTI F-J~°OSURE SKIN: CHEMICAL BURNS EYES: VAPGJ~S PRODUCES MARKED IRRITATION AND CONJUCI'IVITIES. LIQUID CAUSES SEVERE IRRITATION AND CORNEAL BURNS INHALATION: NOSE, THROAT, RESPIRATORY TRACT IRRITATION, CHEST DISCOMFORT, COUGHING, NAUSEA, ITCHING O INGESTION: MOUTH, THROAT, ESOPHAGUS, STOMACH BURNS, SEVERE CHEST/ABDOMINAL PAINS, NAUSEA, DIARRHEA, VOMITING OF BLOOD ~" CHRONIC IPROL(~C. ED~ EXPOSURE :~ SKIN: PROLI~iGED AND WIDESPREAD CONTACT MAY RESULT IN ABSORPTION OF POTENTIALLY HARMFUL AMOUNTS OF MATERIAL ..0 EYES: N/E Z INHALATION: N/E -~ INGESTION: N/E N EMERGENCY FIST AID PROCEDURE5 '~ SKIN: WASH THOROUGIILY WITli SOAP & WATER. EYES: FLUSH WITH WATER AT LEAST 15 MIN. '-'jNI~gD:-' -'~,tOv~ TO ~RESH ]%(R~-~D-I{[N[~' (JXY~' ~3~ -ARTIFICIA~-R~SPIRATION AS- INGESTED: IX3 NOT INDUCE VOMITING, GIVE PLENTY OF WATER. NEVER, GIVE ANYS~{ING BY MOUTH' T°- U'NE~SCXOUS ~RR~JN.--XN--)~L--dASES 0~'-~ONTACT'-~EK MEDICAL'-A~'~NTION IMMED[ATEL1L DILUTE AND NEUTRALIZE ACID BY GIVING LARGE VOLUMES OF MILK TO DRINK. NPT: NO IARC: NO OSHA: NO :. A SMALL PROPORTION OF INDIVIDUALS MAY DEVELOP SKIN, EYES, KIDNEY, CROSS SKIN SENSITIZATION TO FORMALDEHYDE RESPIRATORY SYSTEM VI. REACTIVITY INFORMATION STABILITY CONDITIONS TO AVOID I N C O M P ~TaI~I~TlV~ ~M AsT*/~i]tt~ ~$[r~O ~1~4~ ~+J;:- S, OXIDIZING STABLE NONE A~E~S, ~NC~D SULFURIC AC'ID HAZAR~U$ ~CYMERIZATION CONDITIONS TO AVOID WILL N~ ~CUR ~ONE THERMAL OECOM~SITION PROOU~S CO, CO~ VII. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED SMALL SPILL: COVER WITH SAND OR COMMERCIAL ABSORBENT AND PLACE IN SUITABLE CONTAINER. LARGE SPILL: DIKE, PREVENT ENTERING SEWER/WATERWAY. TRANSFER TO HOLDING TANK. COVER RESIDUE WITH SAND OR COI~4ERCIAL ABSORBENT AND PLACE IN SUITABLE CONTAINER. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. WASTEDISPOSAL ME-FHOD USE RCRA APPROVED HAZARDOUS WASTE DISPOSAL SITE. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION W~I~N CONCENTRATIONS EXCEED EXPOSURE LIMITS, USE SELF CONTAINED BREATHING APPARATUS. VENTILATION PROVIDE GENERAL VENTILATION TO KEEP CONCENTRATION BELOW NUISANCE LEVEL. LOCAL VENTILATION MAY BE NECESSARY TO KEEP CONCENTRATION BELOW EXPOSURE LIMITS. PROTECTIVE GLOVES BUTYL OF PVC EYE PROTECTION CHEMICAL SPLASH GOGGLES OR FULL FACE SHIELD OTHER PROTECTIVE EQUIPMENT CHEMICAL RESISTANT BOOTS, APRON, OR SUIT MAY BE NECESSARY IN HIG74 EXPOSURE SITUATIONS. EYE BATH AND SAFETY SHOWER/DRENCHING FACILITY SHOULD BE AVAILABLE. IX. HANDlING AND STORAGI: INFORMATION AVOID BREATHING VAPORS/MIST AND CONTACT WITH SKIN, EYES, OR CLOTHING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. HAZARDOUS RESIDUE MAY REMAIN IN EMPTY DRUM. DO NOT REUSE CONTAINERS. PRACTICE NORMAL GOOD PERSONAL HYGIENE. CORROSIVE LIQUID. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). NO YES, FORMIC ACID, RQ 5000 LBS NO NO OSHA HAZARr)()US CHEMICALS ~ IMMEDIATE (ACUTE) HEALTH HAZARD ~ DELAYED (CHRONIC) HEALTH HAZARD [~ FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): YES, FORMIC ACID, EPA HAZARDOUS WASTE NO. U123 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL EFFECTIVE DATE MATERIAL SAFETY DATA SHEET [ ,ov~m .30, ].99o ~SC--223 L PRODUCT IDENTIFICATION MANUFACTURER'S NAME I ADDRESS I -"~-'"' ~R S~ CC~qTROL [ P.O. 9OX 61486, ROUS"I~N, 1~ 77208 - PRODUCT NAME A-Il4 NONIONIC NON-EMULSIFIER CHENIICAL DESC RII:~FION ORGANIC BLEND PREPARED BY: BRIAN A. EVANS II. HAZARDOUS INGREDIENTS EXPOSURE LIMITS INGREDIENT CAS NO. APPROX % OSHA PEL ACGIH TLV OTHER AROMATIC PETROLEUM SOLVENT 67891-77-6 40-44 200 PPM N/E N/E III. PHYSICAL DATA N/A N/A N/A N/A DISPERSIBLE I 0.904 @ 60°F (16°C) N/A DARK AMBER LIQUID WITH AROMATIC ODOR I"V. FIRE AND EXPLOSION INFORMATION EXTINGUISHING MEDIA IF'LAMMASLE L'M'T$ (% BY vOLUME) 22°F (50°C), TCC WATER SPRAY/FOG/FOAM,CO2 LOWER: N/A UPPER: N/A USE SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE. COOL FIRE-EXPOSED CONTAINERS USING - WATER' '$P~AY UNUSUAL F'IRE AND EXPLOSION HAZARDS VAPO~tS CAN FORM IGNITABLE MIXTURE WITH AIR. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION V. HEALTH EFFECTS INFORMATION J~K KIN J~ EYES J~INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE SKIN: MODERATE IRRITATION EYES~ MODERATE IRRITATION INHA[ATION~ NAUSEA, VOMITING, DIZZINESS; UNCONSCIOUSNESS O INGESTION: NAUSEA, VOMITING, DIZZINESS, DIARRHEA ~ SKIN: IRRITATION, DERMATITIS ~O EYES: N/A Z INHALATION: N/A ~-' INGESTION: N/A : I SKIN: WASH THOROUGHLY WITH SOAP & WATER. EYES: FLUSH WITH WATER AT LEA~T 15 MIN. ~N~L~L-EU~--REF~v~ TG' FRk'~R ~?/R~-ADMIN/STER' OXYGEN O~']%RTIFICIAL--R]~S~IRATI~N '~S--NEED~-D. INGESTED: DO NOT INDUCE VOMITING, GIVE PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUT~{-TD-UWCONSCIOUS"PERSON. '~N-ALL-CA~E~-bF CONTACT SEEK MEDICAL A~ENTiON IMMEDIATELY. NPT: NO [AR~: NO OSHA: NO NONE IDENTIFIED ! SKIN, EYES VI. REACTIVITY INFORMATION STABILITY CONDITIONS TO AVOID I INCOMPATIBILITY IMATERIALS TO AVOID) STABLE HEAT, SPARKS, OPEN FLAMES I STRONG OXIDIZING AGENTS HAZAROOUS POLYMERIZATION CONDITIONS TO AVOID WILL NOT OCCUR N/A THERMAL DECOMPOSITION PRODUCTS CO, CO= VII. SPILL OR LEAK PROCEDURES s'r'E]=~ TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED SMALL SPILL: COVER WITH SAND OR COMMERCIAL ABSORBENT AND PLACE IN SUITABLE CONTAINER. LARGE SPILL: DIKE, PREVENT ENTERING USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. COMBUSTIBLE LIQUID. SHUT OFF IGNITION SOURCES. WASTEDISPOSAL METHOD USE RCRA APPROVED HAZARDOUS WASTE DISPOSAL SITE. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS VIIL SPECIAL PROTECTION INFORMATION OF ~IDGE ~SPI~R EXCEEDED, USE NIOSH ~PRO~D SE~ CO~AINED B~HING ~P~S WI~ FU~ FACEPIECE. ~EP ~NC~TION BE~W ~SU~ LIMITS. ~OTECT~VE GROVES R~BER, NEOP~NE, NITRILE, VI~N CM~I~L SP~SH G~GLES OR FU~ FACE SHIELD ~ S~Y SH~ER/D~NCHING FACILITY SHOULD BE AVAI~LE. IX. MANOUNG AND 5~ORAG~ INfOrmAl[ON AVOID B~ATHING V~'ORS/MIST AND CONTA~ WITH SKIN, EYES, OR C~ING. ~EP CONTAIN~ TIG~LY C~SED ~EN N~ IN USE. ~OUS SPas, OR OPEN F~S. · - X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUBSTANCES NO - CE~CLA HAZARDOUS SUBSTANCES YES, UNLISTED HAZARDOUS WASTE D001, RQ = 100 LBS SARA EXTREMELY HAZARDOUS SUBSTANCES NO NO OSHA HAZARDOUS CHEM)CALS [] IMMEDIATE (ACUTE) HEA[IH HAZARD [] DELAYED {CHRONIC) HEALTH HAZARD J~J FiRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD YEs, HAZARDOUS WASTE NO. DO0~ HAZARDOUS WASTE (RCRA, 40 CFR 261): N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, iNVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL II ~:??~CTIV~' OAT£ MATERIAL~_2,,, SAFETY DATA SHEET j[ ,0~ 3o, ~.990 L PRODUCT IDENTIFICATION MANUFACTUR£R*$ NAM[ I ADOR[SS BAKER SAND CONTROL J P.O. BOX 61486, HOUSTON, TX 77208 ~ NO. J PRODUC'r NAM[ J A-120 SEQUESTERING AGENT ORGANIC ACID PREPARED BY: BRIAN A. EVANS TI. HAZARDOUS INGREDIENTS II~IGREDtENT J CAS NO. J APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV J OTHER CITRIC ACID 77-92-9 100 N/E N/E N/E J TREAT AS NUISANC] DUST J OSHA PEL: 5 mu/Il~ RESPIRABLE, 15 mgtm* TOTAL J ACGIH TLV: 5 mu/ RESPIRABLE, 10 mg tm~ TOTAL III. PHYSICAL DATA NOblE NONE NONE ~ NOI~ SOLUBLE 1.54 @ 60°F (15.6°C) NONE WHITE, FREE FLOWING CRYSTALLINE MATERIAL, ODORLESS IV. FIRE AND EXPLOSION INFORMATION J EXTINGUISHING MEOIA J fLaMMABLE LIMITS {~ BY VOLUME) I NONE J LOWER: NONE !UPPER: NONE NONE NONE KNOWN V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF' EXPOSURE [~',;KIN J~ EYES J~ INHALATION [] INGESTION ACUTE ISHOF2T) EXPOSURIF SKIN: SLIGHT IRRITATION EYES: SLIGHT IRRITATION INHALATION: Z O INGESTION: ~ SKIN: ~) EYES: Z INHALATION: NONE DETERMINED. GRAS, 21CFR 182-1033 (MULTIPLE PURPOSE FOOD SUBSTANCE} ~ INGESTION: I FLUSH EXPOSED AREA WITH WATER. IF IRRITATION PERSISTS, CONTACT PHYSICIAN. NPI: NO IARC.. NO OSHA NO NONE IDENTIFIED t NONE DETERMINED VI. REACTIVITY INFORMATION STA~U~ coNomoNs TO AVO, O ,NCOMP~U~','~,~'tO"'~V~UC'::C'-----'------------"-------' ~.~ZA~US ~LYMERI~ON CONOI~ONS TO AVOID ' WILL N~ ~R NO~ DE~IN~ rHE~L ~COM~5~ON ~DU~5 VIZ. SPILL OR LEAK PROCEDURES cT.~2~/ H¥ VACUUH OR BROOM SWEEDING AND RE~OV~ TO DISPOSJLL COt~AtN~R. WASTE DISPOSAL METHOD ADD WATER AND NEUTRALIZE WITH SODA ASH OR SODIUM BICARBONATE. FLUSH TO SEWER WITH EXCESS WATER. PRODUCT IS HIGHLY DEGRADEABLE. VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION ~.~ -VENTILATION GE[~-'~.~ VEh'TiLATiO;~ SHOULD DE PROVIDED TO PROTECfIVE GLOVES R~]]ER OR VINYL IF G~O$S CON~AC~ EYE P~OTECTION SPLASH GOGGLES OTHER PROTECTIVE EQUIPMENT AND SAFETY SHOWER/DRENCHING FACILITY SHOULD BE AVAILABLE. IX. HANDLING AND STORAGE INFORMATION AVOID BREATHING DUST OR CONTACT WITH EYES AND SKIN. KEEP CONTAINERS CLOSED WHEN NOT IS USE. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE H! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT_OF 1986 (SARA). NO CERCLA HAZARDOUS SUBSTANCES NO SARA EXTREMELY HAZARDOUS SUBSTANCES NO SARA TOXIC CHE/VlICALS :" : r '. NO OSHA HAZARDOUS CHEMICALS J~ IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD NO HAZARDOUS WASTE (RCRA, 40 CFR 261): N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY' FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATIOI~ AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL ·J EFFECTIVE DATE M,~:AT?~IAL SAFETY DATA SHEET I .o',,,'~.mER 3o, ].99o L PRODUCT IDENTIFICATION MANUFACTURER'S NAME I ADORE.~S ~,O[R SAND CON'i~OL L P.O. BOX 61486, HOUSTON, TX 77208 PHONE NO. [PROOUC"r NAME 713-443-7590 J A-170 HYDROCHLORIC ACID INORGANIC ACID, MURIATIC ACID, HYDROUS HYDROGEN CHLORIDE, HCL PREPARED BY: BRIAN A. EVANS II. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS· OSHA PEL I ACGIH TLV I OTHER HYDROCHLORIC ACID 7647-01-0 5-28 5 PPM * 5 PPM * 7 mg/m~ · CEILING VALUE D(POSURE AT NO TIME ~0 EXCEED THESE LIMI] III. PHYSICAL DATA BOLLING POINT VAPOR PRESSURE N/E 190 m Hg 77°F (16°C) 1.639 N/E SOLUBLE WITH SLIGHT EVOLUTION OF HEAT 1.0249 (5%)-1.1421 (28%) @ 60°F (16~C) N/E CLEAR COLORLESS FUMING LIQUID WITH PUNGENT ODOR OF HYDROGEN CHL IV. FIRE AND EXPLOSION INFORMATION ' %SH POINT [EXTINGUISHING MEDIA ]FLAMMABLE LIMITS (% BY VOLUME) COMBUSTIBLEIi. IF INVOLVED' IN FIRE, " WATER sP~OWER:/ NONE JUPPER: NONE WEAR FULL PROTECTIVE CLOTHING AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN PRESSURE DEMAND/POSITIVE PRESSURE MODE. UNUSUAL FIRE AND EXPLOSION HAZARDS CORROSIVE LIQUID AND VAPOR. TOXIC VAPORS/FUMES (HCL) EVOLVED UPON CONTACT WITH WATER OR STEAM. HYDROGEN GAS (H2) EVOLVED UPON CONTACT WITH MOST METALS. V. HEALTH EFFECTS INFORMATION [] SKIN J~J EYES [] INHALATION [] INGESTION I ACUTE (SHORT) E,~POSURE SKIN: REDNESS, PAIN, SEVERE BURNS. CONCENTRATED SOLUTIONS CAUSE DEEP ULCERS AND DISCOLOR SKIN EYES: VAPORS ARE IRRITATING AND MAY CAUSE DAMAGE. SPLASHES CAUSE SEVERE BURNS AND PERMANENT DAMAGE iNHALATION: COUGHING, CHOKING, INFLAMMATION OF NOSE, THROAT AND UPPER RESPIRATORY TRACT Z O INGESTION: I~4EDIATE PAIN AND BURNS TO TISSUES CONTACTED, NAUSEA, VOMITING, DIARRHEA ~ SKIN: ~ EYES: LONG TERM EXPOSURE TO CONCENTRATED YAPORS MAY CAUSE EROSION OF TEETH, BUT LONG TERM _Z INHALATION: EXPOSURE SELDOM OCCURS DUE TO CORROSIVE/IRRITATING PROPERTIES ,v INGESI'ION: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND WASH THOROUGHLY BEFORE REUSE. WASH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. IF INHALED, REMOVE TO FRESH AIR AND ADMINISTER OXYGEN/ARTIFICIAL RESPIRATI6N AS NEEDED. IF ~"WALLOWED, DO NOT INDUCE VOMITING, GI~4E LARGE 1- QUANTITIES OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. IN ALL CASES SEEK MEDICAL kL'r~NTION IMMEDIATELY. IMMEDIATELY. NPT: NO JARL: NO OSHA: NO NONE SPECIFICALLY IDENTIFIED '= SKIN, EYES, RESPIRATORY V'[. REACTIVITY INFORMATION STA~LrrY I CONDiTiONS TO AVOID tNCOMP~, ~,~ ,-~,-~MAt~i~i~irOP~Ie~, ?~LE ~ CO~IN~S ~Y BU~T ~ H~D ~ONAT~, FOrE.DES k,~: ~US ~LYMERI~ON CON~TION5 TO AVOID ~g~ ~ ~R NO~ T-,~MAL DECOM~SITION PRODOSS H~N CHaR/DE (HCL), ~DR~EN G~ (H~), C~ORINE (CL=) VI/. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED WEA~ APPROPRIATE CLOTHING/RESPIRATORY EQUIPMENT FOR TOXIC/CORROSIVE FUMES/VAPORS. SMALL SI>ILL: FLUSB WIT~{ EXCESSTVE WATER. I~ARGE SPILL: DIKE TO P~VENT I~IiING SEWER/WATER WAY-~. NEU'£M~iZlf WITH :WODA 'A~B, h£ME. Pl~Dv£Dh ~ffOKCl~l; V~-N'L'~.I~'IUN 'LU Ui~-~.F~%'r~ ~u~%~-~. PICK UP NEUTRALIZED SOLUTION WITH ABSORBENT AND PLACE IN APPROPRIATE CONTAINERS. NEL~IZED SLURRY MAY BE FLUSHED TO SEWER IF LOCAL OBDINANCES ALLOW. WASTE DISPOSAL METHOD DISPOSE IN RCRA APPROVED HAZARDOUS WASTE FACILITY. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS. VIII. SPECIAL PROTECTION INFORMATION ~£S~RATOR¥ PROTECrIO~ NIOSH APPROVED FULL FACE PIECE CHEMICAL CARTRIDGE RESPIRATOR, SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE, AIRLINED HOOD. · VENTILATION LOCAL EXHAUST TO PREVENT EXCEEDING EXPOSURE LIMITS AND TO PREVENT DISPERSION TO OTHER WORKAREAS. PROTECTIVE GLOVES RUBBER OR NEOPRENE EYE PROTECTION CHEMICAL SPLASH GOGGLES OR FULL FACE SHIELD OTHER PROTECTIVE EQUIPMENT IMPERVIOUS BOOTS, APRON, OR SUIT MAY BE NECESSARY TO PREVENT SKIN CONTACT. EYE BATH A/qD SAFETY SHOWER/DRENCHING FACILITY SHOULD BE AVAILABLE. IX. HANDLING AND STORAGE INFORMATION CORROSIVE LIQUID. STORE IN COOL, DRY, VENTILATED AREA. KEEP CONTAINER TIGHTLY CLOSED W~EN NOT IN USE. HAZARDOUS RESIDUE MAY REMAIN IN EMPTY CONTAINER. DO NOT REUSE CONTAINERS. PRACTICE NORMAL GOOD PERSONAL HYGIENE. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUBSTANCES YES, GAS ONLY (HYDROGEN CHLORIDE) RQ = I LB CERCLA HAZARDOUS SUBSTANCES YES, HYDROCHLORIC ACID RQ = 5000 LBS SARA EXTREMELY HAZARDOUS SUBSTANCES YES, GAS ONLY (HYDROGEN CHLORIDE) TPQ = 500 LBS SARATOXIC CHEMICALS YF~, HYDROCHLORIC ACID OSHA HAZARDOUS CHEMICALS [] IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): YES, EPA HAZARDOUS WASTE NO. 0002 N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL MATERIAL SAFETY DATA SHEET 8$C--223 J NOVEI'~BI~q 30, 1990 I. PRODUCt IDENTIFICATION MANUFACTURE:R'S NA~E J AODRI:'S$ I '~' ~R ~ C~OL [ P.O. ~X 61486, HOU~N, ~ 77208 PHONE NO. TPeooucr NAME J B-610 ~NI~ C~ORIDE CHEMICAL OESC RIPTIO~i INORGANIC SALT P~ BY: BRI~ A. [[. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA .PEL ACGIH TLV OTHER ~NI~ C~ORIDE 12125-02-9 >99 ~0 mg/m~ 10 ~/m III. PHYSICAL DATA I~OILING POINT VAPOR PRESSURE 968°F (520°C) NOT N~ ~PLICABT.~ NOT ~LUBLE 1.567 @ 68°F (20°C) N~ ~PLICABLE ~I~ ~YST~INE ~LID ~ NO ODOR · IV. FIRE AND EXPLOSION INFORMATION i NON-COMBUSTIBLE [LOWER: NONE UPPER: NONE NOT APPLICABLE UNUSUAL FIRE AND EXPLOSION HAZARDS MAT~ERIAL V~ORIZES AT 653°F (335°C) AND ~OL~S ~XlC FUNES. V. HEALTH EFFECTS INFORMATION [~ ;KIN [] EYES [] INHALATION [] INGESTION SKIN: I~ITATION, DE~TITI S EYES: I~ITATION INHALATION: COUGHING, MILD IRRITATION ~ NOSE ~ T~OAT Z O INGESTION: MOU~, ~OP~GUS, G~IC I~ITATION :~ SKIN: N/E ...O EYES: N/E Z_ INHALATION: N/E -,' INGESTION: N/E SKIN: W~H ~OROUGHLY WITH ~ & WAT~. E~S: FLUSH WI~ WATER AT LE~T 15 MIN. · INGESTS: DO N~ INDUCE V~ITING, GI~ PL~ OF WA~R. ~ GI~ ~ING BY -'~ ~ON~CIOUS~ER~~nL C~ OF ~A~ SE~ ~IC~ A~TION I~DIATELY. NPT: NO JARC: NO OSHA: NO NONE IDENTIFIED { SKIN, ~ES, ~SPI~RY VI. REACTIVITY INFORMATION STABILITY CONDITIONS TO AVOID J INCOMPATIBILITY (MATERIALS TO AVOID) STRONG OXIDIZING OR REDUCING AGENTS STABLE NONE HAZARDOUS POLYMERIZATION I CONDITIONS TO AVOID WILL NOT OCCUR I NONE THERMAL DECOMPOSITION PRODUCTS At~4ONIA, CHLORINE GAS VT~. SPILL OR LEAK PROCEDURES STEPS TO SE TAKEN IF MATERIAL IS R£L~.ASED OR SPILLED SWEEP OR SHOVEL UP WASTE DISPOSAL METHOD USE APPROVED WASTE SITE. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS VIZ"[. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION L)U~,1. VENTILATION ~P CONCEPTION BE~W ~SU~ LIMITS. ~OTE~IVE R~BER, NEOP~NE, NI~, VI~N S~Y ~SES IX. HANDLING AND STORAGE INFORMATION AVOID BREATHING VAPORS/MIST AND CONTACT WITH SKIN, EYES, OR CLOTHING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. HAZ~RDOUS tu~luu~ Pu~ tu:mu~ifl ~m ~r~.wA'z ut(om. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUSSTANCE~ NO CERCLA HAZARDOUS SUB~TANCIFS YES, AMMONIUM CHLORIDE, RQ = 5000 LBS SARA EXTREMELY HAZARDOUS SUBSTANCES NO SARA TOXIC CHEMICALS NO OS~A HAZARDOUS CHEMICALS ~ IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): N/A - DATA NOT AVAILABLE FROM MANUFACTURER ' N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL MATERIAL SAFETY DATA SHEET ILEFFECTIVE DATE ~C--223 NO'v'F.,~v~F.,P, 30, 1990 ][. PRODUCT IDENTIFICATION MANUFACTURER'S NAME I ADDRESS BAKER SAND CONTROL i P.O. BOX 61486, HOUSTON, TX 77208 PHONE NO, IPRODUCT NAME 713-443-7590 ~ 5-40 PRE~YDRATING FLUID FOR HEC CHEMICAL DF-.~CR~PTION TRIHYDRIC ALCOHOL PREPARED BY: BRIAN A. v. VANS :[]:. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER GLYCERINE 56-81-5 99.5 N/E 10 r~/m~ * N/E · TREAT AS NUL' ,ANCE MIST ]//. PHYSICAL DATA BOILING POINT VAPOR PRESSURE 554oF (290°C) <1.0 mm Hg @ 68°F (2ooc) 3.1 N/A MISCIBLE 1.261 @ 77oF (25oC) N/A WATER-W~ITE LIQUID WITH NO ODOR IV. FIRE AND EXPLOSION INFORMATION IEXTINGUISHING MEDIA ] FLAMMABLE LIMITS (% aY VOLUME) 390°F (199°C) WATER SPRAY/FoG/FOAM,CO2J LOWER: N/E UPPER: N/E SPECIAL FIRE FIGHTING PROCEDURES NONE UNUSUAL FIRE AND EXPLOSION HAZARDS NOt,E; V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOBURE [] SKIN [] EYES [] INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE SKIN: NONE EYES: 5LIGHT TRANSIENT IRRITATION INHALATION: NUISANCE MIST Z LOW TOXICITY O INGESTION: I~ CHRONIC {PROLONGED) EXPOSURE ~ SKIN: NONE ~) EYES: IRRITATION Z_ INHALATION: N/E ~'~ LOW TOXICITY m INGESTION: N EMERGENCY FIRST AID PROCEDURES SKIN: WASH THOROUGHLY WITH SOAP & WATER. EYES: FLUSH WITH WATER AT LFJ~T 15 MIN. INGESTED: INDUCE VOMITING IN LARGE QUANTITIES INGESTED. NEVER GIVE ANYTHING BY IMMEDIATELY. NPT: NO IARC: NO OSHA: NO NONE ! EYES VZ. REACTIVITY INFORMATION STABILITY CONDITIONS TO AVOID IN. COMPATIBILITY (MATERIALS TO AVOID) STABLE NONE STRONG OXIDIZING AGENTS HAZARDOUS POLYMERIZATION J CONDITIONS TO AVOID I WILL NOT OCCUR ~ NONE THERMAL. DECOMPOSITION PRODUCTS ACROLEIN (CH=CHCHO) VJ.L SPILL OR LEAK PROCEDURES STEPS TO BE TAKENIF MATERIAL IS RELEASED OR SPILLED SMALL SPILL: COVER WITH SA-ND OR COHMERCIAL ABSOBBENT AND PLACE IN SUITABLE CONTAINER. LARGE SPILL: DIKE, PREVENT ENTERING SEWER/WATERWAY. TRANSFER TO HOLDING TANK. COVER RESIDUE WITH SAND OR COMMERCIAL ABSORBENT AND PLACE IN SUITABLE CONTAINER. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. WASTE DISPOSAL METHOD USE RCRA APPROVED HAZARDOUS WASTE DISPOSAL SITE. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS VI_EL SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION W~N CONCENTRATIONS EXCEED EXPOSURE LIMITS, USE PROPER NIOSH APPROVED CARTRIDGE RESPIRATOR. WHEN LIMITS OF CARTRIDGE RESPIRATOR EXCEEDED, USE NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE. VENTILATION PROVIDE GENERAL VENTILATION TO KEEP CONCENTRATION BELOW NUISANCE LEVEL. LOCAL VENTILATION MAY BE NECESSARY TO KEEP CONCENTRATION BELOW EXPOSURE LIMITS. PROTECTIVE: GLOVES RUBBER, NEOPRENE, NITRILE, VITON EYE PROTECTION CHEMICAL SPLASH GOGGLES OR FULL FACE SHIELD OTHER PROTECTIVE EGUIMMENT C~C~ RESISTANT BOOTS, APRON, OR SUIT MAY BE NECESSARY IN HIGH EXPOSURE SITUATIONS. EYE BATH AND SAFETY SHOWER/DRENCHING FACILITY SHOULD BE AVAILABLE. IX. HANDLING AND STORAGE INFORMATION AVOID BREATHING VAPORS OR EYE CONTACT. DO NOT REUSE CONTAINERS. PRTACTICE NORMAL GOOD PERSONAL HYGIENE. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCI-A EXTREMELY HAZARDOUS SUID~TAN(~F..--~ NO CERCLA HAZARDOUS SUBSTANCES NO NO NO OS.A H^Z^RDOUS CHEMICALS F1~ IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD ~J-] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD .J-] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): HO I N/A - DATA NOT AVAILABLE FROM MANUFACTURER ' N/E - NOT ESTABLISHED CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL EF'FECTIyF' DATE MATERIAL SAFETY DATA SHEET [ Nov'~ER 30, 199o BSC--223 1:. PRODUCT IDENTIFICATION NAME l ADDR~..~.~ ~ CO--On I F.O. ~)X 61486, BOUSTON, ~ 77208 & PHONE NO. ] PRODUCT NAME 713-443-7590 I S-90 MU'~JAL SO~.V~'~ CHEMICAL DESCRIPTION ORCd~IC ,sor.v~I~, GL¥COT. PREPARED BY: BRIAN A. EVANS II. HAZARDOUS INGREDIENTS EXPOSURE LIMITS INGREDIENT CAS NO. APPROX OSHA PEL ACGIH TLV OTHER ETHYLENE GLYCOL MONOBUTYL 111-76-2 100 50 PPM (SKIN) 25 PPM (SKIN) N/E ETHER ( EGMBE, BU'I'YL CELLOSOLVE ) 1:]:I. PHYSICAL DATA BOILING POINT VAPOR PRESSURE 340°F (171°C) 0.6 ~ma Hg @ 68°F (20°C) VAPOR DENSITY (AIR = I ) :VAPORATION RATE (BUTYL ACETATE s $ ) 4.1 0.08 SOLUBILITY IN WATER SPECIFIC GRAVITY (WATER = I ) ..SOLUBLE 0. 9022 VOLATILITY APPEARANCE AND ODOR 100% (v/v) COLORLESS LIQUID WITH MILD ODOR ~ · 1:V. FIRE AND EXPLOSION INFORMATION 150°F ~ WATER SPRAY/FOG/FOAM, CO2 LOWER: 1.1 UPPER: 10.6 BPECIAL FIRE FIGHTING PROCEDURE~ USE SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE. COOL FIRE-EXPOSED CONTAINERS USING w~'.L'~ ~ ~,~' l'~. ! UNUSUAL FIRE AND EXPLOSION HAZARDS VAi~ORS CAN FORM IGNITABLE MIXTURE WITH AIR. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION V. HEALTH EFFECTS INFORMATION J~ SKIN J~JKEYES C]XINHALATION [] INGESTION SKIN: READILY ABSORBED IN POTENTIALLY HARMFUL AMOUNTS. SEE INGESTION. EYES: MODERATE IRRITATION, CORNEAL INJURY ~NHA[AT~ON: RESPIRATORY TRACT IRRITATION, HEADACHE NAUSEA, VOMITING, DIZZINESS Z O INGESTION: RBC, KIDNEY, LIVER DAMAGE. HEADACHE, NAUSEA, VOMITING, GENERAL WF_2%KNESS :~ SKIN: ~O EYES: Eyes: Z INHALATION: Inhalation: REPEATED OVEREXPOSURE MAY CAUSE RBC, KIDNEY, LIVER DAMAGE ,v INGESTION: Ingestion: SKIN: WASH THOROUGHLY WITH SOAP & WATER. EYES: FLUSH WITH WATER AT LEA~T 15 MIN. ............ ~;--%-- TO FF~$H AiR, AD;-;iN£o~ Ok~ OR AnflffC~AL R~l~Afium ~ m~u~u. ~ INGESTED: GIVE TWO GLASSES OF WATER AND INDUCE VOMITING IP~LEDIATELY. IN ALL CASES OF POT£NTIAL CARCINOGEN J AC. GRAVATION OF EXISTING CONDITIONS TARGET ORGANS NPT: NO IAI~C: NO OSHA: NO J NONE SPECIFICALLY IDENTIFIED P~C, KIDNEY, LIVER VI. REACTIVITY INFORMATION STABILITY CONOIT]ONS TO AVOID INCOMPATIBIL/TY (MATI=RIAL~. TO AVOIO) ~ERMAL DECOM~ON ~OU~S CO, ~= ' V]:]. SPILL OR LEAK PROCEDURES ~TC~5 TO ~E~ TAKEN IF MATERIAL IS R[~SED OR S~ SPI~: ~R ~ ~ OR C~RC~ ~ ~ P~CE IN SUI~LE ~R. ~GE SPILL: DI~, P~ E~&~ING S~~Y. ~SF~ ~ HO~ING ~. C~ ~ID~ WITH ~ OR ~CI~ ~O~E~ ~ P~ IN SUIT~ CO~. USE P~ PR~I~ EQUIP~ ~ ~Y. ~USTIBLE LIQUID. S~ OFF IGNITION SOURCES. WAST[ DISPOSAL METHOD INCINERATE. CONSULT FEDERAL, STATE, AND LOCAL REGULATIONS. ~I:ZI. SPECIAL PROTECTION INFORMATION RESF~RATOR¥ PROTECTION WHEN CONCENTRATIONS EXCEED EXPOSURE LIMITS, USE PROPER NIOSH APPROVED CARTRIDGE RESPIRATOR. WHEN LIMITS OF CARTRIDGE RESPIRATOR EXCEEDED, USE NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS WITH FULL FACE~IECE. VEN'TII..AT1ON PROVIDE GENERAL VENTILATION TO KEEP CONCENTRATION BELOW NUISANGE LEVEL. LOCA~ VENTILATION MAY BE NECESSARY TO KEEP CONCENTRATION BELOW EXPOSURE LIMITS. P~DTECTIV E GLOV~ EYE P~TECT]ON CHF_~I~ SPLASH GOGGLES OR FULL FAC£ SHIELD OTHER F~OTECTIVE EQUIPMENT CH~M]:CAL ~SISTA~T ~:K~T-~, A~RON, OR SUIT I~I~Y BE N~CF~Sul~Y TN -HTGH F~O~UI~I~ SITUATIONS. E~ ~ATH A~) SAFETY SHOWER/DRENCHING FACILITY SHOULD BF. AVAILA~L£. ' L~. HANDLING AND STORAGE INFORMATION AVOTD BREATHING VAPOR~/t~I:ST AND CONTACT WITH SKTN, EYES, OR CLOTHING. KEEP CONTAINER T]:GHTL¥ CLOSF.D WHEN NOT IN USF.. EU%Z2~i~)OUS RESIDUE MAY REMAIN IN F~PTY DRUM. DO NOT REU$£ CONTA[NENS. PRACTICE NOIr[AL GOOD PE~DNAL ITfGIENE. COMBUSTIBLF. ~-IQUID. A~1:D EEAT, SPARKS, O~ OPF~I ELAI~S. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE Il! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SU~TANCE5 NO CERC~A HAZARDOUS SUBSTANCES SARA E~TREMELY HAZARDOUS SUBSTANCE:S NO SARA TOXIC CHEhtlCAI_~ NO OSHA HAZARDOUS CHEMICAI_C~ ['~ IMMEDIATE (ACUTE) HEALTH HAZARD [xl DELAYED (CHRONIC) HEALTH HAZARD I [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD' HAZARDOUS WASTE (RCRA, 40 CFR 261): NO N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOU~ A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL MATERIAL SAFETY DATA SHEET ] EFF~'C'",VE DATE Ssc--zZ3 NOVEMBER 30, 1990 [. PRODUCT IDENTIFICATION MANUFACTURER'S NAME ADDR~C-S BAKER SAND CONTROL ~ P.O. BOX 61486, HOUSTON, TX 77208 NO. ] PRODUCT NAME 713-443-7590 J B-643 BIOCIDE CHEMICAL DESCRIPTION ORGANIC BLEND PREPARED BY: BRIAN A. EVANS [I. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER IsoPRoPYL ALCOHOL 67-63-0 >40 400 PPM 400 PPM 500 PPM (ACGIH ALKYL HYDRoXYETHYL-BEN ZYL 61789-68-2 20-40 N/E N/E N/E AMMONIUM CHLORIDE ISOBUTYL ALCOHOL 78-83-1 1-10 100 PPM 50 PPM 75 PPM (ACGIH STE] ) METRYL kLCO~iOL .' 67-56-1 1-10 200 PPM 200 PPM 251 PPM SKIN (ACGIH STE] ) LIT. PHYSICAL DATA BOllING POINT VAPOR PRESSURE N/A 91 mm Hg @ 100°F (37.8°C) VAPOR DENSITY (AIR = 11 EVAPORATION RATE (BUTYL ACETATE: I ) N/A N/A SOLUBILITY IN WATER SPECIFIC GRAVITY (WATER = ! ) SOLUBLE 0.93 @ 60°F (15.6°C) VOlATIlITY APPEARANCE AND ODOR 17% (w/w) @ ?5°¥ (23.g°c) CLF. A~ Y~LLC~/~V~£H LIQU'rD WI~.~ HYDROCARBON TV. FIRE AND EXPLOSION INFORMATION EXTINGUISH(NG MEDIA [FLAMMABLE LIMITS (% BY VOLUME1 76°F ( 24.4°C ) WATER SPRAY/FOG/FOAM, CO2tLOWER: N/E UPPER: N/E SPECIAL FIRE FIGHTING PROCEDURES USE SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE. COOL FIRE-EXPOSED CONTAINERS USING WATER SPRAY UNUSUAL FIRE AND EXPLOSION HAZARDS VAPORS CAN FORM IGNITABLE MIXTURE WITH AIR. VAPORS CAN FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. FLAMMABLE LIQUID. %;'. HEALTH EFFECTS INFORMATION PRIMARY ROUT~-~ Of EXPOSURE [] SKIN [] EYES [] INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE SKIN: CORROSIVE TO SKIN, POSSIBLY LEADING TO THIRD DEGREE BURNS DEPENDING ON LENGTH OF FD(POSURE EYES: EXTREMELY IRRITATING, PERMANENT EYE DAMAGE POSSIBLE INHALATION: NOSE AND RESPIRATORY IRRITATION Z O INGESTION: NAUSEA, VOMITING, CIRCULATORY SHOCK, CONVULSIONS I~ CHRONIC (PROLONGED} EXPOSURE :~ SKIN: N/A ~O EYES: N/A Z INHALATION: N/A ,',,INGESTION: N/A N EMERGENCY FIRST AID PROCEDURES Z SKIN: WASH THOROUGHLY WITH SOAP & WATER. EYES: FLUSH WITH WATER AT LEAST 15 MIN. INHALED: REMOVE TO FRESH AIR, ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION AS NEEDED. INGESTED: DO NOT INDUCE VOMITING, GIVE PLENTY OF WATER. NEVE~ GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. IN ALL CASES OF CONTACT SEEK MEDICAL ATTENTION IMMEDIATELY. POTENTIAL CARCINOGEN AGGRAVATION OF EXISTING CONDITIONS TARGET ORGANS NPT: NO IARC: NO OSHA: NO J NONE IDENTIFIED J EYES, SKIN, RESPIRATORY VI:. REACTIVITY INFORMATION STABILITYsT.a~LE CONDITIONS TO[./~i~T ,AVOID SPA];~'~'~ ~, OR OPE~ F~I~S INCOMPATIBILITY~C)NG (MATERIALSox~DT 'Z~-~,~TO AVOID). HAZARDOUS POLYMERIZATION 8 CONDITIONS TO AVOID WILL NOT OCCUR THERMAL DECOMPOSITION PRODUCTS VZZ. SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF' MATERIAL IS RELEASED OR SPILLED SMALL SPILL: COVER WITH SAND OR COMMERCIAL ABSORBENT AND PLACE IN SUITABLE CONTAINER. LARGE SPILL: DIKE, PREVENT ENTERING SEWER/WATERWAY. TRANSFER TO HOLDING TANK. COVER RESIDUE WITH SAND OR COt~WE~CIAL ABSORBENT AND PLACE IN SUITABLE CONTAINF.~R. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. FLAMMABLE LIQUID. SHUT OFF IGNITION SOURCES. WASTE DISPOSAL METHOD USE RCRA APPROVED ~IAZARDOUS WASTE DISPOSAL SITE. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS VII:'[. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION WHEN CONCENTRATIONS EXCEED EXPOSURE LIMITS, USE PROPER NIOSH APPROVED CARTRIDG~ Rw-SPIRATOR. W~N LIMITS OF CARTRIDGE RESPIRATOR EXCEEDED, USE NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE. VENTILATION PROVIDE GENERAL VENTILATION TO KEEP CONCENTRATION BELOW NUISANCE LEVEL. LOCAL VENTILATION MAY BE NECESSARY TO KEEP CONCENTRATION BELOW EXPOSURE LIMITS. PROTECTIVE GLOVES RUBBER, NEOPRENE, NITRILE, VITON EYE;PROTECTION CHF_/~ICAL SPLASH GOGGLES OR FULL FACE SHIELD OTHER PROTECTIVE EQUIPMENT CHEMICAL RESISTANT BOOTS, APRON, OR SUIT MAY BE NECESSARY IN HIGH EXPOSURE SITUATIONS. EYE AND SAFETY SHOWER/DRENCI-]ING FACILITY SHOULD BE AVAILABLE. A FULL SLICKER SUIT IS RECOMMENDED IF GROSS EXPOSURE IS POSSIBLE. IX. HANDLING AND STORAGE INFORMATION AVOID BREATHING VAPORS/MIST AND CONTACT WITH SKIN, EYES, OR CLOTHING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. HAZARDOUS RESIDUE MAY REMAIN IN EMPTY DRUM. DO NOT REUSE CONTAINERS. PRACTICE NORMAL GOOD PERSONAL HYGIENE. FLAMMABLE LIQUID. AVOID HEAT, SPARKS, OR OPEN FLAMES. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE H! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). NO CERCLA HAZARDOUS SU~3STANCES YES, ISOBUTYL ALCOHOL, RQ 5000 LBS, METHYL ALCOHOL, RQ 5000 LBS SARA ~rXTR£NIELY HAZARDOUS SUSSTANCES NO YES, ISOPROPYL ALCOHOL, METHYL ALCOHOL OSHA HAZARDOUS CHE'MICALS ['~ IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): YEs, ISOBUTYL ALCOHOL, EPA HAZARDOUS WASTE NO. U140, METHYL ALCOHOL, EPA WASTE NO. U154 THIS PRODUCT IS REGISTERED (EPA REG. NO.' 10349-3) FOR USE AS A MICRO-ORGANISM CONTROL C~EMICAL USED IN OILFIELD APPLICATIONS. N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND COIJ~OL ~ EFFEC'T~VE DATE -- E;ATERIAL SAFETY DATA SHEET NOVgMBEA 3O, 1990 · !~ [. PRODUCT IDENTIFICATION MANUFAL-'~ruRER'S ~ J A~)ORESS BAKER SAND C~L P.O. BOX 61486', HOUSTON, TX 77208 ~J~ERGENC¥ PHONE ~ PRO~':UCT NAME 713-443-7590 W-300 5AKER CLEAN GEL I AND II CHEN!:CAL DERIFrll~ CEJ~LULOSE PREPARED BY: BRIAN A. EVANS [1. HAZARDOUS Ifl~REDIEIt4TS ING~DIENT CAS NO. APPRC;X % -- EXPOSURE LIMITS OSHA PEL J AC,.,QIH TLV OTHER HYDROXYETHYL ~ULOSE 9004-62-0 >90 N/.E * N/E * N/E · TREAT A~ NUIS CE DUST OC~HA ACGIH ~' TOTAL DUST ~ 15 mg/zt-~ 10 mg/m'. RESPIRABLE DUE 5 mE/r:a 5 mE/m:' I~I. PHYSICAL DATA NONE NONE NONE NONE SOLUBLE 1.38-1.40 @ 600F (15.&DC) ~.~.....3.~,_ NONE. WHITE POWDER WITH MILD CHARACTERISTIC ODOR IV. FIRE AND EXPLOSION INFORMATION P~AS. PO,NT . ~xTi.~u.$.,N~ .~E~,A I ~.AM.~AeL~ L,M,TS ,% ~Y VO.~,~, J NONE ALCOHOL TYPE ~'OAM, CO2 LOWER: NONE UPPER: NC SPECIAL FIRE FIGHTI~EOURES USE SELF ':ON3~U~D BREATHING APPARATUS WITH FULL FACE PIECE. COOL FI~-EXPOSED CONTAINERS USING AVOID DISP~ OF bUST IN AIT( TO REDUCE POTEN£IAL FOR DUST IGNITION/EXPLOSIC. N. DUST IS EASILY IGNITED. V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF~IPOSU2~- [] SKIN J~ EYES [] .~NHALATION n' INGESTION ACUTE ( ~HO~ ;~OSUt~ - SKIN: NO~IDENC~., OF ADVEI~E EFFECTS EYES: - D~Y BE MINI~LY I~ITATINq, cAUsING DIS~ORT ~D ~LD EXCESS ~DD~ING OF T~ CON~IVA. INHALATI~ ~'o INFO~TION AVAII~%BLE · Z ~ CH~N~C (~ EX'SURE O EYES: ~IS PRODU~ ~Y ~BIBI~ ~IS~ DUST ~D ~SSIB~ ~ ~SPI~ DUSTS. W~H SKI~LY'WITH SO~ & ~A~. IF IN E~S, I~IGA~ WI~, F~WING WA~ FOR AT ~T 15 MIN~, ~ION~LY LI~ING ,· ' ~i':;. VI. REACTIVITY INFORMATION ~' · $TAI~::J'TY' '~ < !' '; CONDITIONS TO AVOID J INCOMPATIBILITY (MATERIALS TO AVOID} STABLE , ~,,~ ~:3~i ,'~ -' NONE ~ NONE HAZ.ARDOUS POLYMERIZA1NON ~ ;~ ' J i~ONDITIO~ TO 'AVOID [ - wI~ NOT Occm~ ~ON~ .F' CO, CO~ ,, ..11 / l/II. SPILL 0~ LEAK PROCEDURE[; SWEEP. UP DRY POWDER SPILLS-I!-:MEDIATE.LY. MATERIA~L WILL ABSORB ¥;ATb'R AND BECOF~E SLIPPERY. COVER W~TER SOLUTIONS WITH ABSORBENT, SWEEP UP, PLACE IN SUITABLE CONTJ%INERS. ~'4 ~TI~ DISPOSAL' METHOD USE RCRA APPROVED FJV:ARDOUS WAS~ DISPOSAL SITE. C,ONSUT~T LgCAL, STATE, AND FEDERAL REGULA~TIONS ~r'[[[. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION DUST RESPIRATOR IF DUSTING CO..~rDITIONS EXIST. VEN]qL~&TION PROVIDE GENEP~L ;,'?,NTILAgfION TO K]~EP CONCENTRATION ~iELOW ,NUISANCE L~:VEL. LOCAL VENTILATION MAY BE FECE, SSARY TO KEEP CONCENTRATION ~ELC)W EXPOSURE LIMITS. PROTECqTVE GLOVES ~VC COATED .~ EYE PROTECTION MONOGOGGLES '; ~ OTHER PROTECTIVE EQUIPMENT NONE · . IX. HANDLING AND STORAGE INFORMATION '~VOID CONTACT WITH EYES AVOID DISPERSION OF DUST IN AIR TO REDUCE PCnJENTIAL FOR DU~ IGNITION/F,D(PLOSION. AVOID BREATHING DUST. PR~C%Z'ICE NO~z%L GOOD PL:P,~ONA.T. HYGIENE. · . ~. ADDITICtNAL INFORM!~,T~ON REGUL.'.'~iE~ ~NDER TITLE III .OF..THE .SUPERFUND AMEND/vt.SNTS AND REAUTHORIZ271ON ACT OF 1986 (SARA). C~'~¥~ICALS CERCI.~ EXTR,E:~£LY HAZARDOUS SUB,.~TANCES " . t'~i.; ii '- ' NO , ~ .' , :~ '., SARA rr_XTREMELY HAZARDOUS SUBSTANCES ...... "" ' ' ' ' ." ,'.z ' . .... NO - · ¢ ........ .' ' SAR~ TOXIC CHEMIC~,LS ~ · · ' ' ~ ' . ' NO ~) os~^ .~z~ousc,[~c^. ¢ I-1 IMMEDIATE (ACUTE) H~ALTH HAZARD '1-1 DELAYED (CHRONIC),HEALTH HAZARD J-J FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD ~J 'REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): NO . . . .' N/A - DATA NOT AVAILABLE FROM MANUFACTURER ' ' N,?E - NOT ESTABLISHED tH'IS iNFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBIUTY FOR SAME. NOR DO WE GIVE PERMISSION, INQUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PAT. ENTED INVENTION WITHOU? A LICENSE. iT IS GIVEN SOLELY FOR YOUR CONSIDERATION, !NVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL J EFFECTIVE DATE MATERIAL SAFELY DATA SHEET ,( ~ov~m 30, ~99o 1~--223 --**-"--, 1~. PRODUCT IDENTIFICATION SAND CONTROL ! P.O. BOX 61486, HOUSTON, TX 77208 PHONE NO. [ PRODUCT NAME / 713-443-7590 ~ W-322 ~{ZGH TEMi~ERATURE BREAKER SULFAMIC ACID PREPARED BY: BRIAN A. EVANS rL HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER SULFAMIC ACID 5329-14-6 100 N/~. N/E N/E I'/'L PHYSICAL DATA DECOMPOSES NOT APPLICABLE NOT APPLICABLE NOT APPLICABLE SOLUIglLITY IN WATER SPECIFIC GRAVITY (WATER = ! } SOLUBLE 2.126 VOLATILITY APPEARANCE AND OOOR NOT APPLICABLE W~ITE CRYSTALS WITH NO ODOR 1'~. FIRE AND EXPLOSION INFORMATION NONE/ [ WATER SPRAY OR FOG, FOAH, DRY~J~ NONE UPPER: NONE USE SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE. COOL FIRE-EXPOSED CONTAINERS USING · WATER SPRAY NONE V. HEALTH EFFECTS INFORMATION I~RIMARY ROUTES OF EXPOSURE [] SKIN [] EYES [] INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE J SKIN: IRRITATION J EYES: IRRITATION J INHALATION: NOSE AND THROAT IRRITATION ~ J INGESTION: ORAL LD-50 (RAT): 1.6 rog/kg J EYES: N/E -- J INHALATION: N/E [INGESTION: N/E EMERGENCY FIRST AID PROCEDURES SKIN: WAS~{ THOROUGHLY WITH SOAP & WATER. EYES: FLUSH WITH WATER AT LEAST 15 MIN. REMOVE TO FRESH AIR, ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION AS NEEDED. INGE-~T~',,: DO NOT INDUCE VOI~ITING, GIVE PLE~ OF WATER. NEVER GIVE ANYTHING BY .~: MOUTH TO UNCONSCIOUS PERSON. IN ALL CASES OF CONTACT SEEK MEDICAL AI'L'~NTION IMMEDIATELY. NPT: NO IARC: No OSHA: NO NONE IDENTIFIED SKIN, EYES VL REACTIVITY INFORMATION ~TA~UTY CONDITIONS TO AVOID IINCOMPA~I~.~.~e.'IM~I~,X.~J.,Ze;B¥O~HLOi~,TES, CHLORINE, S~LE NO~ ~ ~~S ACID, ~1~ ~~ H~S ~LYMEm~ /C~ONS TO AVOID ~ERM~ OECOM~SITION ~DU~5 ~O=, ~, S~U~ AC[D~ ~N[A ~[[. SPILL OR LEAK PROCEDURES STEF3'~ TO BE TAKEN IF MATERIAL. IS RELEASED OR SI:fiLLED $~EEP UP OR SHOVEL INTO SUITABLE CONTAIN~. WASH ~ESIDUE WITH EXCESS WATER. AVOID FLUSHING TO SEWER OR W~WA¥. USE PERSONAL Pt%OTECTIVE EQUIPH. ENT A~ NECESSARY. '~tASTE DISPOSAl. METHOD USE RCRA APPROVED RAZARDOUS WASTE DISPOSAL SITE. CONSLILT LOCAL, STATE, AND FEDERAL REGULATIONS VJTI. SPECIAl. PROTECTION INFORMATION I~SPIRATORY PROTECTION W~N CONCENTRATIONS EXCEED EXPOSURE LIMITS, USE PROPER NIOSH APPROVED CA~TEIDG~ RESPIRATOR. WHeN LIMITS OF CARTRIDGE RESPIRATOR EXCEEDED, USE NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE. VENT~LA~ON PROVIDE GENE~iJ~ VENTILATION TO KEEP CONCENTRATION BELOW NUISANCE LEVEL. LOCAL VENTILATION MAY BE NECESSARY TO KE~P CONCENTRATION BELOW EXPOSURE LIMITS. PROTEC~¥ E GLOVES RUBBER, NEOPRENE, NITRILE, VITON EYE PROTEC~ON CHE~IICAL SPLASH GOGGLES OR FULL FACE SHIELD OTHERP~OTECTWE£OU~PMENT CHEMICAL RESISTANT BOOTS, APRON, OR SUIT MAY BE NECESSARY IN HIGH EXPOSURE SITUATIONS. EYE BATH AND SAFETY SHOWER/DRENCHING FACILITY SHOULD BE AVAILABLE. IX. HANDLING AND STORAGE INFORMATION AVOID BREATHING VAPORS/MIST AND CONTACT WIT~ SKIN, EYES, OR CLOTHING. KEEP CONTAINER TIGHTLY CLOSED t~HEN NOT IN USE. HAZARDOUS RESIDUE MAY R~IN IN EMPTY DRUM. DO NOT R~USE CONTAINF~. P~U&CTIC£ NO~ GOOD PERSONAL ~YGIENE. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE [['[ OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). NO YES, UNLISTED HAZARDOUS WASTE D002, RQ = 100 LBS ~ARA EXTREMELY HAZARDOUS SU~STANCF.5 NO NO :)~HA HAZARDOUS CHEMICAI-~ ~ IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED {CHRONIC) HEALTH HAZARD ::] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD (RCRA, 40 CFR 261): YEs, EPA HAZAROUS WASTE NO. D002 {AZARDOUS WASTE ,I/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED HIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE ~IVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR :ONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL II £~*F£cnv£ o^'rg MATERIAL SAFETY DATA SHEET Jl ~ 30, 1990 I. PRODUCT IDENTIFICATION ADORE. SS BAKER SAND CONTROL / P.O. BOX 61486, HOUS/~N, ~X 97208 ~ERGE~Y PHONIr NO. PRODUCT NAME 713-443-7590 W-324 SPECIAL BRFJLKER CHEMICA/ orr.,.~CRIPTION PEROXYGEN PREPARED BY: BRIAN A. EVANS II. HAZARDOUS INGREDIENTS INGREDIENT CAS NO. APPROX % EXPOSURE LIMITS OSHA PEL ACGIH TLV OTHER AMMONIUM ~Ui~-AI~ 7727-54-0 100 13 rog/m:* 5 mg/mTM N/E ~I. PHYSICAL DATA BOIUNG POINT VAPOR PRESSURE DECOMPOSES @ 347°F (175°C) N/A N/A N/A SOLUBILITY IN WATER SPECIFIC GRAVITY (WATER = 1 ) SOLUBLE 1.9 APPEARANCE AND ODOR LIGET STRAW COLORED POWDER/CRYSTALS WIT~ NO ODOR IV. FIRE AND EXPLOSION INFORMATION FLASH POINT EXTINGUISHING MEDIA FLAMMABLE LIMITS (% BY VOLUME) NON~ WA~ER, WATER Fo<; LOWER: N/A UPPER: N/A SPEC,AL F.RE F~GHT,NG .ROC£DURES FOR ADVANCED OR HASSTVE FI~S, CONTROL SHOLY~D BE CONFIRED ~0 DRO~C~ING E3CPOSED STRUC'~JR~S BY ~ EQUTpM~N~. CON~JU~tZNATION wll'tt u~., ~;t~z<uuaJ~, UK U,£tt~K ~:N~J. TiT-IN~ -~UH~TA~C~;S COULD CAUSE EXELC~ION OF E['~/:I~]g MA~S. AVOID SCA~'I"ERING MASS WITH WA~ER SPPJ~Y. UNUSUAL FIRE AND EXPLOSION HAZARDS OXIDIZER VAPORS/MISTS ARE EXTREMELY TOXIC. WEAR SELF CONTAINED BREATHING APPARATUS. CONFINEMENT WILL NOT LIMIT OXYGEN AVAILABILII% V. HEALTH EFFECTS INFORMATION [] SKIN [] EYES [] INHALATION [-J INGESTION SKIN: IRRITATION EYES: IRRITATION iNHAlATiON: IRRITATION, SHORTNESS OF BREATH Z O__ INGESTION: NAUSEA :~ SKIN: N/E ~ EYES: N/E Z INHALATION: N/E INGESTION: N/E EMERGENCY FIRST AID PROCEDURES SKIN: WASH T~OROUGHLY WITH SOAP & WATER. EYES: FLUSH WIT~ W~TER AT LEA~T 15 MIN. INGESTED: DO NOT INDUCE VOMITING, GIVE PLENTY OF WATER. NEVER GIVE ANYTHING BY IMMEDIATELY. POTENTIAL CARCINOGEN . ] AC*GRAVATION OF EXISTING CONDITIONS J TAPGE~' ORGANS V[. REACTIVITY INFORMATION ~TA ~IUTY CONO~TIONS TO AVOID I NCOM pA/[I~ ( I~i~El;/l~,~vT¢~ S, CC~UST~ ~qT-l~ UNSTABLE, DEC~SS ~ 347°F (175°C) ~ ~T, SP~, OPEN ~ ~S, ~ ~S WI~ ~ ~ J NO~ T~MA~ O[COM~SI~ON ~OU~S ~N~, ~G~, S~IC ACID, SOx ~JI. SPILL OR LEAK PROCEDURES ~r'EPS TO BE TAKEN IF MA'rl[RIAL IS RELEASED OR SPILLED SCOOP OR SW~P UP. PLACE IN SUITABLE CONTAINE~. DILUTE WITH LARGE QUANTITIES OF WATER (3:1 OR MORE). WASTE DISPOSAL METHOD USE RCRA APPROVED ~.~x~US WASTE DISPOSAL SITE. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS V]~I'. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION WHEN CONCENTRATIONS EXCR'FD EXlK)SURE LIMITS, USE PBOPER NIOSH APPROVED CARTRIDGE RESPII{ATOR. WHF~N LIMITS OF CARTRIDGE RESPIRATOR EXCEEDED, USE NIOSH APPROVED SELF CONTAINED B~EATHING APPARATUS WITH FULL FACEPIECE. VENTILATION PROVIDE GENERAL VENTILATION TO KEEP CONCENTRATION BELOW NUISANCE LEVEL. LOCAL VENTILATION MAY BE NECESSARY TO KEEP CONCENTRATION BELOW EXPOSURE LIMITS. ~OTECT~VE GLOVES RUBBER, NEOPRENE, NIT, tILE, VITON ~E PROTECrION CHEMICAL SPLASH GOGGLES OR FULL FACE SHIELD OYHERPROT£C~¥££OU~PMENT CHEMICAL RESISTANT BOOTS, A~RON, OR SUIT MAY BE NECESSARY IN ~ AND SAPET"f SHOWF-I~/DRENCHING FACILITY SHOULD BE AVAILABLE. IX. HANDLING AND STORAGE INFORMATION OXIDIZERS. STORE IN CLO~ED CONTAINERS IN A COOL, DRY PLACE. KEEP AWAY FROM ORGANIC COMBUSTIBLE MATERIALS, HEAT, SPARK~, OR OPEN FLAMES. AVOID CONTACT WITH EYES AND SKIN. AVOID BREATHING DUST. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE H! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUBSTANCES NO CERCLA HAZARDOUS SUBSTANCE~ YES, UNLISTED HJ~US WASTE D001, RQ = 100 LBS SARA EXTREMELY HAZARDOus SUBSTANCES NO SARA TOXIC CHEMICALc~ NO OSHA HAZARDOUS CHEMICAL.~ [2~ IMMEDIATE (ACUTE) HEALIH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [~ FIRE HAZARD [~ SUDDEN RELEASE OF PRESSURE HAZARD ['~ REACTIVE HAZARD U<u<,,~'"~"-, 40 CFR ZO,l"'": YES, EPa HAZARDOUS WASTE NO. D001 HAZARDOUS WASTE N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND cO~rROL EFFECTIVE DATE MATERIAL SAFETY DATA SHEET Nov'~.m~ 30, 1990 ~SC--223 I. PRODUCT IDENTIFICATION ,NUFAC'rURER'S ~ I ADDRF..~5 ~ C~I'I~OL J P.O. ~OX 61486, BOUSI~N, ~ 77:208 ~,'~ONE ,m TP.ODUCr NAME / 713-443-7590 / W-321 MEDIUM TEMPERATURE BREAKER CHEMICAL INORGANIC ACM, HCL, MURIATIC ACID PREPARED BY: BRIAN A. EVANS ~. HAZARDOUS INGREDIENTS EXPOSURE LIMITS INGIEDIENT CAS NO. APPROX % OSHA PEL ACGIH TLV OTHER HYDROCHLORIC J~'ID 7647-01-0 35 5 PPM * 5 PPM * 7 mg/m · CEILING VALUE .2XPOSURE AT NO TIME TO EXCEED TH~E LIMI' 1~. PHYSICAL DATA SOILING POINT VAPOR PR~SURE 127°F (53°C) 190 n~a Hg @ 77°F (16°C) VAPOR DENSITY (AIR = I,) E:VAPORATION RATE: (BUTYL ACETATE = 1 ) 1.639 N/E 5OLUBILITY IN WATER SPECIFIC GRAVITY (WATER = 1 SOLUBLE WITH SLIG~IT EVOLUTION OF HEAT 1.1778 (21.8 °Be) @ 60°F (16°C) VOLATILITY APPEARANCE AND ODOR N/E CLEAR COLORLESS FUMING LIQUID WITH PUNGENT ODOR OF HYDROGEN CHL IV. FIRE AND EXPLOSION INFORMATION COMBUSTI]~ IF INVOLVED IN FIRE, WATER SPR~OWER: NONE UPPER: NONE WEAR FULL PRO~ECTIVE CLOTHING AND NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE OPERATED IN PRESSURE DEMAN1 POSITIVE PRESSERE MODE. UNUSUAL FIRE AND EI;J~OSION HAZARDS CORROSIVE LI~D AND VAPOR. TOXIC VAPORS/FUMES (HCL) EVOLVED UPON CONTACT WITH WATER OR STEAM. HYDROGEN GAS (H2) EVOLVED UPON V. HEALTH EFFECTS INFORMATION PRIMARY ROUTES OF EXPOSURE J~J iKIN ~ EYES [] iNHALATiON [] iNGESTION ACUTE (SHOR7~ EXPOSURE SKIN: R~SF. SS, PAIN, SEVERE B~S. CON~D ~L~IONS ~USE DEEP ~CE~ ~D DISCOLOR S~N EYES: v~ ~ I~ITATING ~ ~Y CAUSE D~GE. SP~H~ CAUSE S~ B~S ~ P~ D~GE INHALATI~ COUGHING, CHOKING, IN~TION OF NOSE, ~AT Z ~ JNO~SIJO~ I~IA~ PAIN ~D BU~S ~ TISSU~ CO~A~, NAUS~, ~MITING, DI~ CH~NIC (PR~GED) ~ SKIN: ~ EYES: ~ INHALATJ~ ~ SE~ ~C~ DUE ~ CO~SI~/I~ITATING PROP~TI~ ~ INOESTIO~ EMERGENCY F~ AID PR~EDURES [~DIAT~ ~USH SKIN WI~ PLE~ OF WA~R FOR AT L~ 15 MI~S. ~ CO~NA~D ~ING ~ W~H ~OR~Y B~O~ ~USE. ~ E~S WI~ PLE~ OF W~ FOR AT ~T 15 MIN~, LI~ING ~PER ~D ~R ~IDS ~ION~LY. IF IN--D, ~ ~ ~ ~H AIR ~D ~NI~ O~N/~IFICI~ ~PI~TION ~ ~. IF ~D, DO ~ INDU~ ~[TING, G~ ~GE QU~ITI~ Of WA~R. ~R GI~ ~ING BY ~ ~ ~NSCI~S PE~ON. S~K ~DI~ A~ION. ~TENTIAL CAREN AGGRAVATION OF EXISTING CONDITIONS TARG~ ORGANS NPT: NO IAPC: NO OSHA: NO J NONE SPECIFI~LY [DE~IFIED SKIN, ~, ~SPI~RY VL REACTIVITY INFORMATION STABILITY CONDITIONS TO AVOID I N C O M P A~;~L~: ~M~A T~;14~T~O ~ ~;~ S ~. SULFIDES, S~ COCAINES BY B~ ~N ~ ~ON~, ~D~ES H~R~S ~YM[RI~ON ~ C~ONS TO AV~D WILL ~ ~R ] NONE H~N ~RIDE (HCL), ~R~ G~ (H~), C~ORINE (CL=) %"-~. SPILL OR LEAK PROCEDURES ~I"EF~ TO BE TAKE. N IF MATERIAL IS RELEASED OR SPILLED WEAR APPROPP~A.TE CLOTHING/R~SPIRATORY EQUIPMENT FOR TOXIC/CORROSIVE FUMES/VAPORS. SMALL SPILL: FLUSH WITH EXCESSIVE WATER. LARGE SPI~L: DIKE TO PREVENT ENTERING SEWER/WATER WAYS. KEUT~ALIZE WITH SODA ASE, LIME. PBOVIDE FORCED VENTILATION TO DISSIPATE FUMES. PICK UP ~IZED SOLUTION WITH ABSORBENT AND PLACE IN APPROPRIATE CONTAINERS. NEUTRALIZED SLUBRY MAY BE FLUSHED TO SEWER IF LOCAL ORDINANCES ALLOW. .. WASTE DISPOSAL ML~THOO DISPOSE IN RC~A APPROVED HAZARDOUS WASTE FACILITY. CONSULT LOCAL, STATE, AND FEDERAL REGULATIONS %q/I. SPECIAL PRO?EC~ION INFORMA?ION RF_~PIRATORY PROTEClqON NIOSH APPROVED FULL FACE PIECE CHEMICAL CARTRIDGE RESPIRATOR, SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE, AIRLINED HOOD. VE:NTILATION .T~CAL EXHAUST TO PREVENT EXCEEDING EXPOSURE LIMITS AND TO PREVENT DISPERSION TO OTHER WORKAREAS.' ~OTECT~VE GLOVES RUBBER OR NEOPRENE EYE PROTECTION C[.~24ZCAL GOGGLES OR FULL FACE sH'rELD. DO NOT WEAR CONTACT L~NSES WHEN HANDLING THIS MATERTAL. OTHER PROTECTIVE £OUIPMENT IMP~R%;IOUS BOOTS, APRON, OR SUIT MAY BE NECESSARY TO PREVENT SKIN CONTACT. EYE BATH AND SAFETY SHOWER/DRENCHING FACILITY SHOULD BE AVAILABLE. 1Qr. HANDLING AND STORAGE INFORMATION CORROSIVE LIQUID. STORE IN COOL, DRY, VENTILATED AREA. K~EP CONTAINER TIGHTLY CLOSED W~EN NOT IN USE. HAZARDOUS RESIDUE MAY REMAIN IN EMPTY DRUM. DO NOT REUSE CONTAINERS. PRACTICE NORMAL GOOD PERSONAL HYGIENE. X. ADDITIONAL INFORMATION CHEMICALS REGULATED UNDER TITLE HI OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). YES, GAS ONLY (~YDROGEN CHLORIDE) RQ = 1 LB CE~CLA HAZARDOUS SUEISTANCE~ YES, HYDROC~ILORIC ACID RQ = 5000 LBS ~ARA EXTREMELY HAZARDOUS SUB~/'ANCES YES, GAS ONLY (~YDROGEN CNLORIDE) TPQ = 500 LBS SARA TOXtC CHEMICALS YES, HYDROCHLORIC ACID O~HA HAZARDOUS CHEMICALS [] IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD ["'-J FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCRA, 40 CFR 261): YES, EPA HAZARDOUS WASTE NO. DO02 NJA - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED . THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. BAKER SAND CONTROL MATERIAL SAFETY DATA SHEET EFFE~,VE':'ATE ssc--zz3 NOV~ER 30, lggo I. PRODUCT IDENTIFICATION ~NUFA~TURER'S NAME [ADDRESS BAKER SAND CONTROL / P.O. BOX 61486, HOUSTON, TX 77208 EMERGENCY PHONE NO. PRODUCT NAME 713-443-7590 W-350 HIGH TEMPERATURE GEL STABILIZER CHEMICAL DESC RIPTIO/4 AHTNE/G~YCOL t~J JG: PREPARED BY: BRIAN A. EVANS II. HAZARDOUS INGREDIENTS EXPOSURE LIMITS INGREDIENT CAS NO. APPROX % OSHA PEL ACGIH TLV OTHER AMINE/GLYCOL M~XTURE N/E 100 N/E N/E N/E i III. PHYSICAL DATA BOILING POINT VAPOR PRESSURE 225°F (107.2°C) 11.7 mm Hg @ 68°F (20°C) VAPOR DENS[TY (AIR = I) EVAPORATION RATE (BUTYL ACE-rate = 1) 2.41 1.11 SOLUBLE 1.1234 @ 68°F (20°C) VOLATILITY APPEARANCE AND ODOR 15% (v/v) BROWN LIQUID WITH AMMONIA ODOR IV. FIRE AND EXPLOSION iNFORMATION NOb,.'~ WATER $?I.:U%.Y/FOG/FOAH, CO2 LOWER: N/E UPPER: N/E USE SELF CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE. COOL FIRE-EXPOSED CONTAINERS USING WATER SPRAY NONE / V. HEALTH EFFECTS INFORMATION " PRIMARY ROUTES O~: EXPOSURE [] SKIN ' [] EYES [] INHALATION [] INGESTION ACUTE (SHORT) EXPOSURE SKIN: NONE IDENTIFIED EYES: MINOR TEMPORARY CORNEAL INJURY INHALATION: NONE IDENTIFIED O INGESTION: MAY CAUSE NAUSEA '-- ChRON,C mROLO.(;Em EXPOSURE ~ SKIN: NONE ZDENTIFIED " O EYES: NONE IDENTIFIED Z INHALATION: NONE IDENTIFIED -- INGESTION: NONE IDENTIFIED EMERGENCY FIRST AID PROCEDURES WASH SKIN THOROUGHLY WITH SOAP & WATER, IF RASH OR IRRITATION DEVELOPS, CONSULT PHYSICIAN. IF IN EYES, IRRIGATE WITH FLOWING ~. WA'~'~:~ YUR aT h~T lb MiNUT~-~, OCCASIONALLY LIFTING UPPER AND LOWER EYELIDS. IF INHALED OR INGESTED, NO HARMFUL EFFECTS ~ [XPEc~'~u. POTENTIAL CARCINOGEN AGGRAVATION OF EXISTING CONDITIONS TARG~T ORGANS NPT: NO IARC: NO OSHA: NO NONE IDENTIFIED EYES Vl~. REACTIVITY INFORMATION STABLE NONE STRONG ACIDS WILL NOT OCCUR / NONE CO, C02, OXIDES OF NITROGEN SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED SMALL SPILL: COVER WITH SAND OR COMMERCIAL ABSORBENT AND PLACE IN SUITABLE CONTAINER. LARGE SPILL: DIKE, PREVENT ENTERING SEWER/WATERWAY. TRANSFER TO HOLDING TANK. COVER RESIDUE WITH SAND OR CO~94ERCIAL ABSORBENT AND PLACE IN SUITABLE CONTAINER. USE PERSONAL PROTECTIVE EQUIPMENT AS NECESSARY. WASTE DISPOSAL METHOD USE RCRA APPROVED HAZARDOUS WASTE DISPOSAL SITE. CONSULT LOCAL, STATE, AND PEDF/~AL REGULATIONS VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION ~ NONE REQUIRED IN NORMAL USE. VENTILATION PROVIDE GENE~AL VENTILATION TO KEEP CONCE~NTRATION BELOW NUISANCE LEVEL. LOCAL VENTILATION MAY"~E NECESSARY TO KEEP CONCENTRATION BELOW EXPOSURE LIMITS. PROTECTIVE GLOVES NEOPRENE OR NITRILE EYE PROTE~TION SAFETY GLASSES OTHER PROTECTIVE EQUIPMENT CHEMICAL BESISTANT BOOTS, APRON, OR SUIT MAY BE NECESSARY IN HIG~ EXPOSURE SITUATIgNS. EYE BATH AND SAFETY SHOWER/DRENCHING FACILITY SHOULD BE AVAILABLE. IX. HANDLING AND STORAGE INFORMATION AVOID BREATHING VAPORS/MIST AND CONTACT WITH SKIN, EYES, OR CLOTHING. KEEP CONTAINER TIGHTLY CLOSED W~EN NOT IN USE. HAZARDOUS RESIDUE MAY REMAIN IN EMPTY DRUM. DO NOT REUSE CONTAINERS. PRACTICE NORMAL C4DOD PERSONAL HYGIENE. X. ADDITIONAL INFORMATION CHEMICALS REGULA'[ED UNDER TITLE II! OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA). CERCLA EXTREMELY HAZARDOUS SUBSTANCES NO CERCLA HAZARDOUS BUBSTANCES NO SARA EXTREMELY HAZARDOUS SUBSTANCES NO NO OSHA HAZARDOUS CHEMICALS ~] IMMEDIATE (ACUTE) HEALTH HAZARD [] DELAYED (CHRONIC) HEALTH HAZARD [] FIRE HAZARD [] SUDDEN RELEASE OF PRESSURE HAZARD [] REACTIVE HAZARD HAZARDOUS WASTE (RCR~ NO .. N/A - DATA NOT AVAILABLE FROM MANUFACTURER N/E - NOT ESTABLISHED THIS INFORMATION IS GIVEN WITHOUT A WARRANTY OF REPRESENTATION. WE DO NOT ASSUME ANY LEGAL RESPONSIBILITY FOR SAME. NOR DO WE GIVE PERMISSION, INDUCEMENT, OR RECOMMENDATION TO PRACTICE ANY PATENTED INVENTION WITHOUT A LICENSE. IT IS GIVEN SOLELY FOR YOUR CONSIDERATION, INVESTIGATION, AND VERIFICATION. BEFORE USING ANY PRODUCT, READ ITS LABEL. ~~~~ 5400 ^LDRIN CT. groundWater resources inc. BAKEI~SFIELD, CALIFORNIA 93313 General Engineering Contractor Class A/HBz License No. 520768 GROUNDWATER RE SOURCES INC. (GRI) 5400 Aldrin Court Bakersfield, California (805) 835-7700 HEALTH AND SAFETY PLAN A RESNA Company MAILING ADDRESS: P.O. BOX 9383, BAKERSFIELD, CA 93389 (805) 835-7700 LOS ANGELES (213) 724-3147 HEALTH AND SAFETY PLAN LO PURPOSE The purpose of this Plan is to assign responsibilities, establish personnel .protection standards and mandatory safety procedures, and provide for contingencies that may arise while operations are being conducted at the site. 2.0 APPLICABILITY The provisions of the Plan are mandatory for all on-site Groundwater Resources Inc. (GRI) employees and subcontractors engaged in hazardous material management activities including, but not limited to, initial site reconnaissance, preliminary field investigation, mobilization, project operations, and demobilization. Subcontractors shall provide a Health and Safety Plan for their employees covering any exposure to hazardous materials and shall complete all work in accordance with that plan. The sub- contractor may choose to use the GRI Health and Safety Plan as a guide in developing its own plan or may chose to adopt GRI's plan. In either case, the subcontractor shall hold GRI harmless from, and indemnify it against, all liabilities in the case of any injury. GRI reserves the right to review and approve the subcontractor's plan at any time. Grossly inadequate Health and Safety practices on the part of the subcontractor or the belief that the subcontractor's personnel are or may be exposed to an immediate health hazard, shall be cause for GRI to suspend the subcontractors site work and ask the subcontractor's personnel to evacuate the hazard area. The subcontractor shall provide its own safety equipment in accordance with Health and Safety Plan requirements. The sub- contractor shall comply with all regulations including OSHA 29 CFR 1910.134 (Respiratory Protection). 3.0 RESPONSIBILITIES 3.1 Safety Coordinator The Safety Coordinator (SC) generally shall not be involved directly in onsite activities. However, the SC shall provide the following functions in support of the field activities: 1. Maintain an adequate inventory of equipment in good working order. 2. Maintain all necessary files and records. 3. Ensure that all monitoring equipment is calibrated on a regular basis and that the results are properly recorded and filed. 4. Ensure monitoring equipment is operating correctly and provide for maintenance if it is not. 5. Be available for consultation by the Project Manager or Safety Officer. PAGE 1 GROUNDWATER RESOURCES, INC. HEALTH AND SAFETY PLAN 3.2 Project Manager The Project Manager (PM) shall direct on-site investigation operational efforts. At the site the PM, assisted by the Safety Officer (SO), shall have the primary responsibility for:. 1. Ensuring that appropriate personal protective equipment is available and properly utilized by all on-site personnel. 2. Ensuring that personnel are aware of the provisions of this plan, are instructed in the work practices necessary to insure safety, and in planned procedures for dealing with emergencies. 3. Ensuring that Personnel are aware of the potential hazards associated with on-site operations. 4. Monitoring the safety performance of all personnel to ensure that the required work practices are employed. 5. Correcting any work practices or conditions that may result in injury or exposure to hazardous substances. 3.3 Safety Officer The Safety Officer (SO) shall: 1. Implement project Health and Safety Plans, and report any deviations from the anticipated conditions described in the plan. 2. Ensure that all on-site personnel have a minimum of 24 hours safety training, 3. Ensure Sat all monitoring equipment is recently calibrated. 4. Ensure monitoring equipment is operating correctly (report to Safety Coordinator if it is not.) 5. Be responsible for identifying all site personnel with special medical problems. 6. Preparing any accident/incident report. 7. Assume any other duties as directed by the PM. 3.4 Project Personnel Project personnel involved in on-site operations shall be responsible for: 1. Taking all reasonable precautions to prevent injury to themselves and to their fellow employees. 2. Performing only those tasks that they believe can be done safely, PAGE 2 GROUNDWATER RESOURCES, INC. HEALTH AND SAFETY PLAN and immediately reporting any accidents and~or unsafe conditions to the SO or PM. 3. Implementing the procedures set forth in the Health and Safety Plan, and reporting any deviations from the procedures described in the Plan to the SO or PM for action. 4.0 BACKGROUND All personnel shall be knowledgeable concerning the following topics on a site specific basis including, but not limited to: Site History Prior Activity Suspected Hazards $.0 EMERGENCY CONTACTS AND PROCEDURES 5.1 Contacts Should any situation or unplanned occurrence require outside or support services, the appropriate contact from the following list should be made: Agency Contact Person ' Telephone Police 9`11 Fire 911 Ambulance 91'1 Hospital Mercy HQSpital 805/327-3371 Project Manager Gary Cawthon 805/835-7700 Safety Coordinator Gary Cawthon 805/'U3b- / / uu Safety Officer Gary Cawthon 80b/t33b- //U0 Client Contact Brian Frohmuth 805/589-5970 5.2 Procedures In the event that an emergency develops on site, the procedures described below are to be immediately followed. Emergency conditions are considered to exist if: -- Any of the project personnel are involved in an accident or experiences any adverse effects or symptoms of exposure while on site; or -- A condition is discovered that suggests the existence of a situation more hazardous than anticipated. PAGE 3 GROUNDWATER RESOURCES, INC. HEALTH AND SAFETY PLAN The following emergency procedures shall be followed: 1. Personnel onsite shall use the "buddy" system (pairs). Personnel shall pm-arrange hand signals or other means of emergency signals for communication in case of lack of radios or radio breakdown. The following hand signals are suggested: Hand gripping throat: out of air, can't breathe Grip partner's wrist or place both hands around own waist: leave area immediately Hands on top of head: need assistance Thumbs up: OK, I'm all right, I understand Thumbs down: No, negative 2. The Safety Officer shall establish emergency evacuation routes and shall make all project personnel aware of these routes prior to the first onsite activities. In the event of an emergency, selection of the escape route shall be based on the nature of the emergency and wind direction. 3. Visual contact shall be maintained between on-site personnel. Support personnel shall remain in close proximity in order to assist in case of emergencies. 4. In the event that any of the personnel experiences any adverse effects or symptoms of exposure while on site all personnel shall immediately halt work and act according to the instructions provided by the Safety Officer. 5. Wind indicators, visible to all on-site personnel, shall be provided by the Safety Officer to indicate possible routes for upwind escape. 6. The discovery of any condition that would suggest the existence of a situation more hazardous than anticipated shall result in the evacuation of the on-site personnel and re-evaluation of the hazard and the level of protection required. 7. In the event that an accident occurs, the SO shall complete an Accident Report Form for submittal to the Safety Coordinator (SC). The SC shall initiate action to correct the situation that caused the accident. PAGE 4 GROUNDWATER RESOURCES, INC. HEALTH AND SAFETY PLAN 6.0 HAZARD CHARACTERISTICS, MONITORING METHODS AND PROTEC- TION REQUIRED All personnel shall be knowledgeable concerning the following topics on a site specific basis including, but not limited to: Exposure Limits Recognizable Characteristics Symptoms of Overexposure Potential Chronic Effects First Aid Treatment Monitoring Methods Action Levels Protection Measures 7.0 STANDARD SAFE WORK PRACTICES 7.1 General 1. Eating, drinking, chewing gum or tobacco, and smoking shall be prohibited in the contaminated or potentially contaminated area or where the possibility for the transfer of contamination exists. 2. Avoid contact with potentially Contaminated substances. Do not walk through puddles, pools, mud, etc. Avoid, whenever possible, kneeling on the ground, leaning or sitting on equipment or ground. Do not place monitoring equipment on potentially contaminated surface (i.e., ground, etc.). 3. All field personnel shall make use of all their senses to alert them to potentially dangerous situations which they should avoid (i.e. presence of strong, irritating or nauseating odors). 4. Prevent spillages to the extent possible. In the event that a spillage occurs, contain liquid immediately. 5. Prevent splashing of the contaminated materials. 6. Field personnel shall be familiar with the physical characteristics of the investigation site, including: Wind direction Accessibility to associates, equipment, vehicles Communications Hot zone (areas of known or suspected contamination) Site access Nearest clean water sources PAGE 5 GROUNDWATER RESOURCES, INC. HEALTH AND SAFETY PLAN 7. The number of personnel and equipment in the contaminated area shall be minimized, but only to the extent consistent with worlfforce requirements of safe site operations. 8. All wastes generated during on-site activities shall be disposed of in accordance with all applicable laws and regulations. 7.2 Excavation and Well Installation Practices For all excavation and well installation activities, the following standard safety procedures shall be employed: 1. All equipment shall be cleaned before proceeding to site, and after the excavation and/or well installation has been completed. 2. Only the minimum number of personnel necessary to achieve the objectives shall be within 25 feet of the excavation and/or drilling activity. 3. If the emergency and backup subcontracted personnel are at the site, they shall remain 25 feet from the excavation and/or drilling activity, where practical. 4. Exclusion zones shah be established with designated hot lines. Delineation of a hot line shall reflect the interface between areas at and below a predetermined threshold contaminant concentration based on available data. This determination shall be made by the Safety Officer. 5. All unauthorized personnel shall remain outside exclusion zones at all times. 8.0 SITE SAFETY PLAN The personnel on site will be equipped with a draeger PA-80 air pack, gastech D-11 vapor testor or an equivalent, a photoionizafion meter, fn'e extinguishers and any additionally requi~ed equipment for health and safety considerations. PAGE 6 GROUNDWATER RESOURCES, INC. groundwater resources inc. SAMPLING PROTOCOL groundwater resources inc. 'rEST BORING PROCEDURES I. Soil Samp'iing Protocol The following procedures are following during soil sampling operations utilizing the ho'l'low stem auger arl'lling technique. A. Hollow Stem Auger 1. Soil borings drilled by the hollow stem auger utilize continuous flight hollow stem augers. 2. Augers, samplers and all downhole equipment are steam c'leaned prior ~o use. In the fiela s~eam cleaning is done between borings to minimize the potential for .cross-conCamina[ion. 3. A G.R.I. geologist observes the work, visually logs the soils, and collects samples at appropriate intervals. 4. The Unified Soils Classifica[ion System is utilized to classify soi'ls encountered. Additional geological observations are noted as appropriate. 5. Soil samples destined for laboratory analysis are collected by a modified California Split Spoon. This sampler uses ~hree, six ~nch long, Dy Cwo and one- half inch diameter (o.d.) Cubes. Various ~u~bes can be utilized Co accommodate the type of analysis n~cessary: Brass - All organacs and general analyses (not to De used ~or copper or z~nc analysis) Stainless - All organics and meta'ls analyses for Steel copper and zinc (hOC Co be used for chrome or nickel analyses) Plastic '- All metals analyses (not to be used for organics) groundwater resources inc. TEST BORING PROCEDURES (Con~'d) 6. The tubes are cleaned and prepareO in the G.R.I. laboratory. Tubes are scrubbed, inside aha outsiOe, with a brush and TSP, rinsed, dryea, and packed clean con=diners with seals. Tubes are delivered the dri'lling site in these closed containers preserve %he state of cleanliness. 7. After the sample(s) have been removed from the sampler, the sampler is completely disassembled and scrubbed in TSP and Cap water. IC is then rinsed in clean and reassembled with three clean Cubes. 8. Dirty' Cubes are field washed in TSP so'lu%ion, rinsed with water, anO reused. 9. The sampler is Oriven by a 140 pound ~ammer wicn ~ 30 inch free fall. Blow counts are recordeO as number of blows per inch of drive. 10. The sampler 'is driven 18 inches aC each sampling interval. The first (or lowest) tube is generally retained as the sample for an~'lysis. The ocher Cwo Cubes are retaineO for back-up or sp'liC samples. 11. A sand catcher is used in the sampler where loose soils are anCicipateO. This wlll preven~ one soi'l from f~llin9 ouC of the samp'ler. 12. After reSrieval, the sample is visually logged anO immediately sealeO with aluminum foil 'lineO caps, laDe'lea, and chi'lleO. Clean ice chests and c~emical ~ce ("blue ice") are used to keep the samples cold until Oelivered to the chemical laboratory. Teflon seals are also available for fielO samples. 13. Samples are delivered to the 'laboratory the same day they. are taken, if physically possible. If C~e samples mus~ be held until the next day, they are kept frozen in a'secure freezer aC 14. Sample control is maintained by a Chain o~ CustoOy ~orm which accompanies the sample. The form documents rime, date, and responsible person Outing each s~ep the ~ransportation process. groundwater resources inc. MONITORING WELL SAMPLING PROTOCOL II. Groundwater Sampling A. All equipment that is used in a monitoring well for purging, sampling, or depth measurement is decontaminated by steam cleaning or a TSP wash and rinse procedure prior to use and before re-using when more than one samp'le ~s collected. B. Purge Volume Determination The following procedure is followed to determine the appropriate purging volume prior to we'll sampl3ng. 1. The depth-to-water is measured by a clean, electric level indicator. Measurement datum is the top of well protector. 2. Depth to the bottom of the well is measured by a c'lean tape and plumb Dob. If possible, this is compared to the well construction log to determine inconsistencies, i.e. damaged casing, sediment in casing, etc. 3. Water volume is calculated Dy using the total water depth and the inside diameter of the casing. C. Well Purging and Sampling 1. P?ior to sampling, a minimum of three to ?'~ve well volumes are purged from each well to ensure that water sampled is representative or' the groundwater with'in the formation. 2. Measurements of H, conductivity and temperature are taken at frequent interva'ls during the purge. Stabilization of these values indicates that representative formation t"luids are being removed from the wel 1. groundwater resources inc. MONITORING WELL SAMPLING PROTOCOL (Cont'd) 3, In the event that the well is pumped dry, And ~lternate procedure will De fo'l'lowed. Once a we'l'l is pumped dry, the water tha~ enters the well during recovery is, by definition, representative formation water. The well will, therefore, be pumped dry and ~11owed to recover to 80~ or more of the origina'l water level. 4. Purge water is pumped directly into barrels on site until the proper method of disposal is determined. 5. Samples are pumped or poured, from a bailer into sampling bottles prepared by a state certified ~a~oratory contracted for t~e perticular ~ob and placed ~n refrigerated coo'lets for transport ~o the laboratory. 6. Samples are delivered by courier, d~rectly to the lab on the same day of sampl~ng~ ~henever practical. If next d~y del~¥ery is necessary, t~e samples are kep~ refrigerated ~t ~ degrees C overnight and delivered to the l~boratory Lhe ~o'llowing morning. 7, Samples are accompanied by a Chsin of Custody form which documents Lhe time, date and responsible person during each step of the transportation process. 8. The G.R,I. coded sample numbering system allows i~en~fica~on of samp'le and c'lien~ to G.R.I., while I · not revealing the client to anyone else.