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HomeMy WebLinkAboutBUSINESS PLAN I II MAP ' ,' SITE DIAGRAM ? . FACILITY DIAGRAM / For Office Use Only First In Station: ' Area Map # of Inspection Station: NORTH usiness NQme: ' '~:..~ ~o For Office Use OnLy First In Station: Area Map # 'of InsPection Station: NORTH I U I' AL DUb: '~'.J~. UU ~ STATEMENT OF ACCOUNT · k -CITY OF BAKERSFIELD ~ _-21 lsol .T,~UXTUN Av~. ' " BAKERSFIELD, CA 93301-0000 ' ~ ~:"'~ <':"~- DATE' 1/01/97 TO: POWER' SYSTEMS ,TESglN~ COMPANY.. ~"~' :3300 ANTONINO AVENUE ~ ......... , .... ~*- BA½ERSFIELI~, CA ~3308 ' ~.,,:~.. -~ /,~',-?~:~ CUSTOMER TYPE' EC/ 3606 A N '~;<'~:~ " FIN CE DEPARTMENT -~" .. ~.,,-~x.~;~ ;~m~- _ : · ~ P.O. BOX 2057 BAKERSFIELD~ CALIFORNIA 93303 ~ t ~ ~ ,oo~ss co~c~,oN ~Ou~s~o ~ ~ PONE3OORETURN TO ~330~O~SENDER .- :PONER SYSTEM5 TESTZN~ . . ~ ~a~7 OLAREHONT. CT , RETURN TO SENDER ~ ~ [ 0 IIh,,Ih,,,,Ih,lh,lh,,Ih,,Ih,,ll,,,,,,lllh,,Ih,,Ih,,I 04/05f96 POWER SYSTEMS TESTING COMPANY 215-000-000019 Page Overall Site with 1 Fac. Unit General Information Location: 3300 ANTONINO AV Map:102 Haz:3 Type: 3 City : BAKERSFIELD Grid: 23D F/U: 1 AOV: 0.0 Contact Name Title r Contact Name Title N / D~E I,J.R. BLAKE / FIELD ~NGii~A~R Business Phone: (805) 631-8343x 1Business Phone: (805) 631-8343x Pager Phone :ii- x IPager Phone : ( ) - x Administrative Data Mail Addrs: 3300 ANTONINO AV D&B Number: 6044-141570 City: BAKERSFIELD State: CA Zip: 93308- Comm Code: 215-065 COUNTY STATION 65 SIC Code: 3825 Owner: POWER SYSTEMS TESTING COMPANY Phone: (805) 631-8343 Address: P O BOX 6005 State: CA City: HAYWARD Zip: 94545- / Summary ~ /~ RECEIVED I, ~u,z~ so~ Do he.reSy eert. if! ~..'~t ~ have ~y~ or ~m ~) .... ~¢~ 2 3 ;996 review~ the arched haz~us m ' HAZ. MAL DIV. ment pla~ for ~4, ~o and tha'~ any ~rr~ions ~nsti~ e ~mp~e~e ~d~ agement plan for my 04/05~96 POWER SYSTEMS TESTING COMPANY 215-000-000019 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02 - O G 6 ACETYLENE Bo ~o7~ $~ ~< ~ ~ ,~6~ ~_ 20 O 200 · ~ ~re, l~ed Mltn, Delay Hith 02-001 MOTOR OIL Liquid 600 Minimal ~ Fire, Delay Hlth GAL 02-002 BREATHABLE AIR Gas 500 Minimal ~ Pressure FT3 02-003 NITROGEN Gas 200 Minimal ~ Fire, Pressure, I~ed Hlth FT3 02-004 SULFUR HEXAFLUORIDE Gas 200 Minimal ~ Pressure, Reactive, I~ed Hlth FT3 04/05/96 POWER SYSTEMS TESTING COMPANY 215-000-000019 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02~ETYLENE Gas 200 ~ ,~Pressure, Immed Hlth ~ CAS'#: 74~rade Secret: No~ Form: Gas Type: ~D?Us?: WELDING SOLDERING --'Daily M xa FT3 ~ D~verage FT3 ~ Annual Amount FT3 20~/~/ ~.00 , 200.00 ~ Storag~.-~Press T T~p ~ '~_~ __ Location ~ - PORT .~CYLINDER Ambient, INDOOR~ --~fc I Components ~-L MCP -~Guide /..-~00.0% IAcetylene I~ I 17 02~5~Q~YGEN Gas 200 L~D~/ ,~rmued Hlth, Delay Hlth ~ -- Daily Max~3 ~ D~Avera-~~ ----T---~nnual Amount ~3 ~ Sto 200~ _ 200.0~ . 200.00 PORT. P~LI~DER I~Bovo [~mB~ongII~DOOR B~Y ~ ~ _ 02-001 MOTOR OIL Liquid 600 Minimal ~ Fire, Delay Hlth GAL CAS ~: 64742-46-7 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: OTHER Daily Max GAL600 ~ Daily Averagel00.00GAL [ Annual ~ount1,200.00GAL -- Storage Press T Temp Location DRUM/BARREL-METALLIC Ambient~Ambient~OUTDOOR BAY -- Conc Components MCP ~uide 100.0% ~Motor Oil, Petroleum Based {Minimal ~ 27 04/05/96 POWER SYSTEMS TESTING COMPANY 215-000-000019 Page 4 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-002 BREATHABLE AIR Gas 500 Minimal · Pressure FT3 CAS #: 0 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: OTHER Daily Max FT3I Daily Average FT3 I Annual Amount FT3 500 I 200.00 600.00 Storage Press T Temp Location PORT. PRESS. CYLINDER IAbove [AmbientllNDOOR BAY -- Conc Components MCP --~Guide 100.0% lAir IMinimal I 12 02-003 NITROGEN Gas 200 Minimal · Fire, Pressure, Immed Hlth FT3 CAS #: 7727-37-9 Trade Secret: No Form: Gas Type: Pure Days: 365 'Use: OTHER Daily Max FT3 Daily Average FT3 Annual Amount FT3 200 [ 200.00 [ 400.00 Storage [ Press T Temp I Location PORT. PRESS. CYLINDER Above [Ambient INDOOR BAY -- Conc Components MCP ---~uide 100.0% INitrogen [Low ~ 12 02-004 SULFUR HEXAFLUORIDE Gas 200 Minimal · Pressure, Reactive, Immed Hlth FT3 CAS #: 2551-62-4 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: OTHER Daily Max FT3[ Daily Average FT3 I Annual Amount FT3 -- 200 I 200.00 200.00 Storage [ Press T Temp I Location PORT. PRESS. CYLINDER Above [Ambient INDOOR BAY - ConcI Components I MCP ---TGuide 100.0% ISulfur Hexafluoride IMinimal I 12 04/05/96 POWER SYSTEMS TESTING COMPANY 215-000-000019 Page 5 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification CALL 9-1-1 IN CASE OF EMERGENCY. .<2> Employee Notif./Evacuation VISUAL/VERBAL <3> Public Notif./Evacuation NONE ~,~ <4> Emergency Medical Plan NEAREST FACILITY. 04/05/96 POWER SYSTEMS TESTING COMPANY 215-000-000019 Page 6 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention OIL IS STORED IN SEALED METAL DRUMS. GASES ARE ANCHORED TO WALL. FLAMMABLES ARE STORED OUTSIDE IN MATAL LOCKER. <2> Release Containment DIKE AND ABSORB <3> Clean Up USE ABSORBANT MATERIAL 'AND DISPOSE OF PROPERLY. <4> Other Resource Activation 04/05/96 POWER SYSTEMS TESTING COMPANY 215-000-000019 Page 7 O0 - Overall Site <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - SE OF BLDG B) ELECTRICAL - SE OF BLDG/2 SHUT OFFS C) WATER - E SIDE OF BLDG D) SPECIAL - N/A E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - NONE LISTED. NEAREST FIRE HYDRANT - ARROW/ANTONINO AND PIERCE/ANTONINO <4> Building Occupancy Level 04/05/96 POWER SYSTEMS TESTING COMPANY 215-000-000019 Page 8 00 - Overall Site <G> Training <1> Employee Training WE HAVE 4 EMPLOYEES AT THIS FACILITY. WE DO HAVE MSDS SHEETS ON FILE. BRIEF SUMMARY OF TRAINING PROGRAM: ACCOMPANIES REGULAR SAFETY MEETING CONDUCTED ON SITE. <2> Page 2 <3> Held for Future Use <4> Held for Future Use Hazardous Materials Division ~L AUG 3 1992 2130 "G" Street- Bakersfield, CA. 93301 By_ ' ,.. HAZARDOUS MATERIALS MANAGEMENT,PLAN 1. To avoid further action, return this form within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be brief and concise as possible. SECTION 1' BUSINESS IDENTIFICATION DATA BUSINESS NAME' POWER SYSTEMS TESTING .COMPANY LOCATION: 3300 ANTONINO AVENUE MAILING ADDRESS: 3300 ANTONINO AVDkE~ CITY: BA_F~RSFIELD STATE: CA. ZIp:93308 PHONE: (805) 631-8343' DUN & BRADSTREET NUMBER: 6044-141570 SIC CODE' PRIMARY ACTIVITY: ELECTRICAL MAINTENANCE AND TESTING POWER SYSTEMS TESTING COMPANY / ATTENTION: RALPH MEEK '. OWNER'. MAILING ADDRESS: P.o. BOX 6005, HAYWARD, CAL]'FOR~TA 94545 SECTION 2: EMERGENCY NOTIFICATION: CONTACT TITLE BUS, PHONE 24 HR. PHONE HOME (805) 397-3824 ]. ROBERT NELSON DISTRICT MANAGER (805) 631-8343 (805) 631-8343 2. J.R. BLAKE FIELD ENGINEER (805) 631-8343 HOME (805) 834-3191 (805) 631-8343 .? 1. Bakersfield Fire Dept. Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 3: TRAINING: NUMBER OF EMPLOYEES: 4 MATERIAL SAFETY DATA SHEETS ON FILE: BRIEF SUMMARY OF TRAINING PROGRAM: ACCOMPANIES REGULAR SAFETY MEETING CONDUCTED ON SITE SECTION 4: EXEMPTION REQUEST: I CERTIFY UNDER pENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAPTER 6,95 OF THE "CALIFORNIA HEALTH & SAFETY CODE" FOR THE FOLLOWING REASONS: WE DO NOT HANDLE HAZARDOUS MATERIALS, WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIMEEXCEED THE MINIMUM REPORTING QUANTITIES. OTHER (SPECIFY REASON) SECTION 5: CERTIFICATION: I, ROBERT .C. NELSON CERTIFY THAT THE ABOVE INFOR- MATION IS ACCURATE, I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO FULFILL MY'FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIV, 20 CHAPTER 6,95 SEC, 25500 ET AL.) AND THAT INACCURATE INFORMATION CONSTITUTES PERJURY, /' / · DATE 2, t~DI Bakersfield Fire DePt. Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN FaCilitY. Unit Name: PO1~ER SYST~[_S TESTING CONPAN~ "' SECTION 6: NOTIFICATION AND EVACUATION PROCEDURES: A. AGENCY NOTIFICATION PROCEDURES: ~~',5~// ~// //"/ B.. EMPLOYEE NOTIFICATION AND EVACUATION: VISUAL / VERBAL C. PUBLIC EVACUATION' D. EMERGENCY MEDICAL PLAN' NEAREST FACILITY. Deg. Bakersfield Fire Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 7: MITIGATION, PREVENTION AND ABATEMENT PLAN: A. RELEASE PREVENTION STEPS: OIL IS STORED IN SEALED METAL DRUMS GASES ARE ANCHORED TO WALL ~LES ARE STORED oUTSIDE IN~TALLOCKER B. RELEASE CONTAINMENT AND/OR MINIMIZATION:' DIKE ANDABSORB C. CLEAN-UP PROCEDURES: USE ABSORBANT MATERIAL AND DISPOSE OF PROPERLY SECTION 8: UTILITY SHUT-OFFS (LOCATION OF sHuT-OFFS AT YOUR FACILITY); NATURAL GAS/PROPANE: SOUTH EAST OF BUILDING- ELECTRICAL: 'SOUTH EAST OF BUILDTNG / 2 SHUT OFFS EAST SIDE OF BUILDING WATER: SPECIAL: N/A LOCK BOX: YESES) IF YES, LOCATION: SECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABILITY: A. PRIVATE FIRE PROTECTION: B WATER AVAILABILITY (FIRE HYDRANT): ARROW'/ ANTONINO · PIERCE / ANTONINO , HAZARDOUS NAT~IALS INVENTORY ~ ~Farm and 'Agriculture ~ Standard Business Page 1: of 2~ NON - TRADE SECRET BUSINESS NAME: POWER sYSTEMS TESTING COMPANY OWNER NAME:CORP. HEADQUARTERS/HAYWARD, C. AUAME OF THIS'FACILITY: OFFICE/SHOP LOCATION: 3300 ANTONINO AVENUE ADDRESS: 2267 CLAREMONT COURT ~ STANDARD IND. CLASS CODE: CITY, ZIP.~AKERSFIEI.D, CALIFORNIA 93308 CITY, ZIP: HAYWARD~ CALIFORNIA 94545 DUN AND BRADSTREET NUMBER/FEDERAL ID PHONE #:(BnR~ 631-8343 PHONE .#: (510) 783-5096 --9 --4 - 2 2 8::- 9-- 2 5 2-- · D&B ~6044-141570 ~ ~u ~.nUCTIONS FOR PROPER CODES I 2~ '3 4 5 6 7 8 g 10 11 12 13 14 Trane Type Max Average Annual Measure # Days Cont Cont Cont Use Location Where i~Y Names of M~xture/Comp0nents Code Code Ami ;Ami Ami Units on Site Type Press Tem~ Code Stored in Facilit~ ~ S~ Instruct#one N '1 M 1600GALI100GAL 11200 IGA~ZON~ 360 106 I i i 4 , 1991 ou~o. ~Y v/ - E_~3t, -- ' C.A.S. Su~er MIXTURE component # I s~ '~ C.A.a. m,~er 100 64742-46--7 Ph.~ical and Health Hazard ,  eck all that apply) Component # 2 Name & C.A.a. Number 0,-- .~-' Fire Hazard ~.. Sudden Release ~ Reactivity ~ I.~ediate ,~ Delayed 40 64742--53--6 of Pressure Health.. Health Component # 3 Name & C.A.S. Number ~ 128--37--0 N ] p I 500 ] 200 ] 600 ] FT3 I 180 I 04 .I 2 ] '4 ] ] INDOOR BAY '~ BRF. AT~A~T,F. AIR Physical 'and Health Hazard' C.A.S; .~er N/A c0~onent # 1 Name & C.A.a. Number COMPRESSED AIR · (Check all that apply) Component # 2' Name & C.A.B. Number :E3. Fir, ,a,~d ga Sudden Melease ~ Reactivity ~-- ~=odiato of Pressure Health Heal'th Co.orient 9 3 Name & C'..A..S. N~mber 'N I P I 200 I g00 I 400 I FT3 I 180 104'1 2 I 4 I I ~O. BAYV NITR(~3EN 'PhystcaA .a'nd Health Hazard C.A.S. S,,-~er 7727-37-9 ' component # 1 Nam~ & C.A.a. Nu~er .(Check a~l that apply)... Component # 2 Name & C.A.a. 'Number Fire [lazard [] Sudden Release ~ Reactivity g~ i.~diate ~ DelaY~ · · of Pressure Health Health,' Component # 3 Name & C.A.S. Nu~er Physical,and Sealth'Hazard C.A.a. ~u~er 2551-62-4 .. component # 1 Name & 'C.AiSo Number (Check all that apply) Component ~ 2 Name $ C.A.a. l~umbar ~ Fire Bazard. [~ Sudden Release ~ Reactivity ~ I-~.edtate [~De'layed ' · " . Of Pressure . Health Health Component # 3 N~ & C.A.a. Number MERGENCY coNTACTS #1ROBERT C. NELSON MANAS~ (805[ ~31-8343 #2 J.R. RT,AKE FIELD ENGI~:~:~ (805) 631-8341 Name . Title 24 Hr. Phone· Na~e Title 24 Hr Phone ificatic. . - (READ AND SIGN AFTER COMPLETING ~T,T? SECTIONS) : I ct~rtifel~Under:peanlty of law that I hayer personally examined and am iamilia~ with the information submitted tn this and all attached documents and that based on my Inquiry of those . 1.~d~vi~a r~P°naib~ g~r o~taining the info ~r~na~tion. I believe that the submitted .tnfolma!:ion ia true, accu~ate,' and camplete~ · NAMe.AND ~PIC!AL. TITLE OF OWNER/OPEIqA-~OR OR OWNER/~PERATOR'S A .' $I~NkTURE DATE SIGNED "'%--1 Farm ahd Agriculture ~--] Standard Business ':~ Page 2 -of. 2-- NON - TRADE SECRET · BUSINESS'NAME:POWER sySTEMS. TESTING COMPANY OWNER NAME:CORP. HEADQUARTERS/HAYWARD LOCATION: 3300 ANTONINO AVENUE ADDRESS:2267 CI,AREMONT CO~T .' ~. STANDARD .IND..CLASS CODE: · BRADSTREET NUMBER/FEDERAL ID CITY, ZIP:BAKRR~qFYRT,D. CAT,T~ORNTA Q~30R CITY,. ZIP: ~AYWARD~ O. AT,T~RNTA Q4545! DUN AND ~'~??~- 2 2 8- 9_ 2_ 5_ 2_ · 'PHONE #: (805) 631-8343 PHONE ,.#.: i(510) 782-50q~.. ' REFER TO INSTRUCTIONS FOR PROPER ~ODES ' D&B ~6044-141570 .. ~ .... 1 2 , 3 4 5 6 7 8 9 10 11 12 13 ' . 14 I Trane Type :.. Max Average Annual Measure # Days Cont Cont Cont Use Location Where . I% by . Names of MiXture/Components , Code Code ." Amt'" ~Amt Amt Units on Site Type Press Temp Code Stored in Facility wt /''~-- See Instructions I P I 2~ I ~ I ~ I~ I 360 I~ I ~ '1 ~ I~1 ~ ~¥ ;/ n~.~ tcal a'nd Health aaZard C.A.8. ~er 7782--44--7 · Component # 1 ~a~ heck all that apply) · -- -- " , . Health . Health ! Component # 3 Name & C.A.S. Number / ' I N I P I 200I200 I 200 I FT3I360 I 0~ I2I 4 1~2 I ~OR BAY - Physical end ltealth lt~-ard C.A.8. ~a,er 74-86-2 . Component. # i lq'~n~ ;& C.A.8o ~tmher . (Check all that apply) ~ '" : of Pressure Health Health[ Component # 3 Name & C.A.S. NUmber } I I I I I I I · I ! Physical and Health Hazard C.A.S. Number ""J" Component # i Name & c.A.s. Su~er I' (Cb.ok an that apply) ' ' . ~-- . -, · : I' El pit, Ha,er~ [] su~en ~lea,. ~ ~eact.ivity [] ~=~ate ~ ~el~ ' " 'component # ~ ,~, C.A.S. ~er of Pressure ~ealth . Health .. ' Component # 3 Name'& C.A.S. Numbe~ I I I I I I I I ! Physical and Health Hazard ' C.A.S. Number . ': "' ;;,' ~.'. Component # 1 Namei& 'C.'A.S. Number .. (Check all that apply) ' ~ ' ' : , I_ ' , oE Pres~ure Health Health ,.' Component #. 3 Name. & C.A.S. Number ~,~'~aG~.~¢Y conTAcTs .#1 ~OBV?-T..C..~ELSON . MANAS~ '(805) 631~8343 #2J.~. BLAES. FT~LD ~NSI~a (805) 63Z-8343 ' . Name ' Title ' :24 Hr. Phone Na~e ( Title ' 24 Hr Phone ~._.~. fREAD AND SIGN AF'£E~ COMPLETING ALL SECTIONS~ '~ certify under peanlty of law that I hayer personally examined and am familiar with the information submitted ~n this and all atta¢~ed documents and that based oh my inquiry of those 't~dlv~dua~s responsiblg, for obtainin, g the information, i believe that the submitted ~nformation is true, accurate, and Complete. ' ~-~ ~~ LJQUlD AIR Material Safety Data Sheet Acetylene ~, ~ (41s) g77.4soo uaum ~ ~~ ~ ~ ~ ~ CAS Number' o~~~~ Acetylene. Ethyne 74-~-~ ~~~~ Acetvl erie. Ethvne H~L~ H~RD n~~~~~ Acetylene is defin~ as a simple asphyxiant. Oxygen levels should be ~intain~ at greater than [8 ~lar percent at noel a~spheric pressure which is ~utvalent to a pa~ial pressure Inhalation: Low concentrations {[O-20%-in air) cause s~ptom similar to that of being intoxicate. Higher concentrations so as ~ exclude an ad~uate supply of oxygen to the lungs cause unconsciousness. As a narcotic gas or intoxicant causes hypercapnia (an excessive amount of carbon dioxide in the blood). 'Repeated exposures to tolerable levels has not shown deleterious effects. The major property is the exclusion of an adequate supply of oxygen to the 1 ungs. Listed as Carcinogen National Toxicology Yes l"'i I.A.R.C. Yes I"i OSHA Yes [] or Potential Ca,-cinogenProgram No [] Monographs No [] No [] PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO ACETYLENE. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED'BREATHII4G APPARATUS AND BE COGNIZANT OF EXTREME FIRE AND EXPLOSION HAZARD. Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given mouth-to-mouth resuscitation and supplemental oxygen. Medical assistance should be sought in~nediately. Fla~able over an extrm~ely wide :range in air. Explosive ~acttons my occur on ignition. Reacts ~plosively with halogens and halogenated cmapounds. PHYSICAL DATA IOILII~ ~ ~ DE]4EITY AT ~ POINT Sublimation point · -118.8°F (-83.8°C) See last page' w~~ ~m~a~w,?~-.~-- ~ 60OF (15.6~C) = 645 psia (~50 kPa) e 70°F (21.1~C) .06~ lb/ft3 (1.107 kq/m3) ~,,-~ e 68"F {20"C) Bunsen , ~oefficien~ = 1.047 Trtole ~int = -l13"F (-80,~C) . ~~ Pure acetylene is a colorless gas wi~ an ethereal odor. Co~ericam (carbide) acetylene has a distinctive qarltc-ltke odor.Soec.Grav.fAir=l_0)= ~RE AND ~PLOSlON H~RD DATA Gas 565'F (296'C) UEL=80.85* *S~ note on last page, Carbon d~ox~de; d~ chorea1IClass l, Group A If possible, stop ~ of escaping gas. Use water spray ~ cool surrounding containem. K~p personnel a~y since heated or bumtng cylindem can mpture violently. ~SEOUS AC~L~E IS SPONT~E~sLY 'C0~U~IBLE IN AIR AT PR~SUR~ ABOVE 30 PSIA (207 kPa). (Cont~nu~ on last .page.). R~~I~ DATA ~ ~TO~ not all~ the f?ee g{~ (g~tsiqe o~.cy~inde?} ~ X ~ exCeed 30 ps~a. ~on~nu~ on ~as~ page.) ~.~m~(a~m~ Oxygen and othe? oxgd~ze?s ~nclud~ng al~ of the halogens and ha]o- qen compounds. Fo~s explosive acet~l~de compounds vHth (Continued on 3asr Ca~on and hvd~en mm mm ~~ X Evacuate all personnel from affected area. Use app~priate protective ~uipment. leak is in user's equi~ent, be ce~ain to purge piping with an inert gas prior to att~pting repairs. I~ leak is in container or containe~ valve, contact the closest Liquid Air Corporation location. Do not att~pt to dispose of waste or unus~ .quantities.. Return in the shipping container properly labeled, with any valve outlet plu~s or c~ps secured and valve protection ca~ in place to Liquid Air Co~oration for p~per disposal. For ~ergency disposal, contact t~e closest Liquid Air Co~oration location. EMERG~CY RESPONSE INFORMA~ON ,' IN ~SE OF ~ERGENCY INVOLVING THIS MATERIAL, ~LL DAY OR NIGHT (800) 231-1366 OR ~ CHEMTREC AT (800) 42~9300 · : ~ ~ SP. ECIAL PROTECTION INFOR TION ~e brea,l~hlnq aDoaratus should be available for emeroencv usa. v,~m~=. I~mm~"~ To prevent accumulation I ~ Hood with forced I ~beve th~ l;t_ I 'vent'1 latton I"mc~'~ m'"~ I PVC~or rubber in laboratory; as required for cutting & welding. I Safet.¥ qoqqles or ql '.SPECIAL PRECAUTIONS* DOT Shipping Name: Acetylene DOT Hazard Class: Flan~nable gas DOT'Shipping Label: Flan~nable :gas ID No.: UN lO0! .... '. Use only in well-ventilated areas. Valve protection caps must remain in place unless cont~ainer is secured with valve outlet piped to use point. Do not drag, slide or roll, cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing regulator when removing gas from the cylinder. DO NOT ALLOW THE FREE GAS TO EXCEED 30 PSIA {207 kPa} ~ 70°F {21.~°C). Do not heat cylinder by any means to incr~easa the discharge rate of product from the cylinder. Usa a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. . i Protect cylinders from physicall damage. Store in cool, dry, well-ventilated area of non-.mc~bustible construction away fr~ heavily trafficked areas and emergency exits. Do ri. mot allow the temperature wiiere cylinders are stored to exceed 130F {54C}. Cylinders must be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in-first our's' inventory system to prevent full cylinders being stored for excessive periods of time. Post "No Smoking or Open Flames" signs in the storage or use area. There shou,'ld be no sources of ignition.in the storage or use area. Since acetylene will explode or'combust if its pressure exceeds 20 psia (207 kPa) it*'* is ,~hipped dissolved in acetone or dimethYlformamide which is dispersed in a porous mass within the cylinder. Follow Liquid Air Corporation's instructions for the maximum withdrawal rate for each size cylinder so that solvent is not withdrawn with the acetyl erie. Most metals, except silver, copper, mercury or brasses with more than 66% copper, are compatible (non corrosive} with acetylene. Ear~h-grOund and bond all lines and equipment associated with the acetylene system. Electrical equipment should be.non-sparking or explosion proof. Compressed gas cylinders should not be refilled except by qualified producers of compressed gases. Shi~nent of a compressed gas cylinder which has not been filled by the owner or with his', (written) consent is a violation of Federal Law {49CFR}. Transport cylinders in well-ventilated vehicles,upright and sui.tably restrained to . ~ prevent movement (Con--ecl on ~ page) UQUID AIR CORPORATION ~ ~?A LIQUID DENSITY AT 8OILING POINT: (Continued) Solid density e sublin~tion point - 45.51 lb/ft3 (729 kg/m3) FI. AI~BLE LIMITS % BY VOLUME: (Continued} Note: Pure acetylene can ignite by decomposition above 30 psia (207 kPa); therefore, the UEL is 100% if the ignition source is of sufficient intensity. UNUSUAL FIRE AND EXPLOSION ~S: (Continued) It requires a very low ignition energy so that fires which have bee~i extinguished without stopping the flow of gas can 'easily reignite with possible'explosive force. Acetylene has a density very similar to that of air so when leaking~jt does not readily dissipate. ~,,~ CONDITIONS TO AVOID: (Continued} Cylinders should not be exposed to sudden shock or sources of heat. INCOMPATIBILITY (MATERIALS TO AVOID): (Continued) copper, mercury, silver, brasses containing ~re than 66% copper and brazing materials containing silver or copper. stacked t.ha: bu~ gas escaping fzq:zn a melted ~use plug (pressur~ relief cl.=vice) '~ ' CORI~RATIC '-'~"~ -~[~'1 UQUID AIR tN Material Safety Data Sheet .Nitrocjen- n-~ (415) 977.~5oo U~JIO ),M COI~OI~I'tON T~&DE WE M4O ~YNONYM~ ~ NUYaF. R One Calfomm mama, SuRe 35o _N i troqen 7T27-37.9 2121 N. CAJifernla BIYd. ~xewc~. IMM~ ~ ~YNONYklS we~. c~N~ c~mim mm~ ~(i 1;l~gerl · ,o,t,~ao.~ com,c~s~,,,~oe,~. 42 28.013 Inert gas HF. JI~LI~fl H~..a~RD DATA n~wmG~mo,ve~o~u,eu~,T Nitrogen is defined as a simple asphyxiant. Oxygen levels should be maintained at greater than 18 molar percent at normal atmospheric (Continued on last paqe.) ~11~lrrOM~ OF EYJ~3~URE E:ffects of exposure to high concentrations so as to displace the oxygen in air necessary tot']ire may include an.v, all or none of the following: o Loss of balance or dizziness; o Tightness in the frontal area of the forehead; (Continued on last page.) TO~]COI. OGICAI. IMqO II~RT1E:~ Nitrogen i.s nontoxic but the liberation of a large amount in a confined area could displace the amount of oxygen in air necessary to support life. Listed as Carcinogen National Toxicology Yes 1--] I.A.R.C. Yes [] OSHA Yes ~__ or Potehtial Carcinogen' Program No [] Monographs No [] No RECOMMENO~ ~IIST A~ ~TMENT P~O~PT MEDICAL ~TTE~TIO~ I$ M.~DATORY I~ ~LL C~$~$ OF OYER£~POSU~£ TO ~IT~OG£~. RESCUE P~$O~EL SHOULD B~ E~UZPP£D ~TH $~LF-CO~T~I~ED BREaTHinG ~PP~I~TU$. Inhalation: Conscious persons should be assiste~ to an uncontaminated a~ea and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given mouth-to-mouth resuscitation and supplemental oxygen. Medical assistance should be sought in~nediately. Juaqeme~ts as to me su.aab~ of in~n ner~n ~r ~'s ~ are ~ ~Ra~'s r~n~a~, ~ere~fe. a~ug~ re~nao~ cate nu O~n tarn in ~e oreoaratton ot suc; in~. L~ N~ ~ ~t~ ~ w~. ~ ~ reor~n~s, ~ ~s ~ r~ U tO ~e K~r~ or sumqbi~ of ~ in~rmatmn for mOplica~on to ourcnaser'~ iflt~ ~ or c~ue~ of i~ u~. ~e Li~ Nt ~n h~ ~ control ~ ~l u~ of ~ ~uct. it ~ ~ ~ ~r da~ge of ~u of prMuct resultmg trom grooer <o ,~l uM a ~ of mi ~t. Data ~ ~ ~ ~g~ lmm n~ m e~. ~ ~m m ~n~ ~ ~t~ ~n. 14AZ. Mq~QUI blIXTtJRI~ OII OTi, tllq uQUIO~, ~O Iq ~ ' I None m PHYSICAL DATA .oiu~ ,OI.T UOUm oe..rrY AT -320.445°F (-195.803°C) 50.48 lb/ft3 (808.607 kq/m3), v.~.~usulq~ ~ 70°F (21.1°C) above the (~.~oewn,.TT.-,_~..,, .07245 lb/ft~ critical temp. of -232.51°F (-146.95°C) (1.)605 kq/m3) Sol.u..J'n,,.W*T~ @ 68°F (20°C) Bunsen coefficient = ,0~557 -346.0~F (-210.002~C) A~~ A~ O0~ FIRE AND ~PLOSION HA~RD DATA ~ ~INT (M~ U~) ]A~O I~ON ~P~A~RE I ~~ UM~ h ~ VOLUME H/A IH/A I N~nfl a~abl ~. inert ~as I Nonhazardous · N/A REACTIVI'T~ DATA STAIIUTY CONDITIONS TO AVOID None I.U~,AROOU~ DIe¢OMPO~4TION I~ODUCT~ None HAZ.&RDOUS PQLYMEII~ZATION CONDITIONS TO AVOID Ib7 Occur SPILL Off LEAK PROCEDURES $TEP~ TO BE TAKEN IN ~ MATERIAl. IS REl.E.A~ED OR SPILLED Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in container or container valve; contact the closest Liquid Air Corporation location. WASTE DiSPOSAl. ME'r'HoO Do not attempt to dispose of waste or unused quantities. Return in the shipping container properly labeled, with any valve outlet plugs or caps secured and valve protection cap in place to Liquid Air Corporation for proper disposal. For emergency disposal, contact the closest Liquid Air Corporation location. EMERGENCY RESPONSE INFORMATION IN CASE OF EMERGENCY INVOLVING THIS MATERIAL, CALL DAY OR NIGHT (800) 231-1366 OR CALL CHEMTREC AT (800) 424-9300 ,.~r'~.l.,&~l.. i.,I'Iu I I:~ i IU'N' iNI'UHMA ~--~o~,~no~,-_~__:, Postttve p~essure air ltne h mask or self;con~aine~ h~e~th4n~ appaeatus ~uld be availab~ f9~ ~q~qen~,7 use, See Local ~haus~ See las~ page. on las~ page. "~~(~ Any ma~a~i al Safe~ ~o~les o~ ~lasses Safe~ shoes SPECIAL PRECA~ION5· DOT Shipping Name: Nitrogen o~ Nitrogen, C~p~essed ~.D. No.: UN ~0~ DOT Shipping Label: NonViable gas DOT Hazard Class: Nonfla~able gas Use only in well-ventilated a~eas. Valve pro~ec~ion caps mus~ r~ain in place unless con~ainer is secur~ wi~h valve ou~le~ piped ~o use point. DO no~ drag, slide o~ ~11 cylinders. Use a suitable hand ~uck fo~ cyllnde~ mordent. Use a p~essu~e ~educing ~egula~or when connecting c~11nder ~o lower pressure (~3,000 psig) piping o~ sys~s. DO no~ hea~ cylinder by any means of p~duc~ from ~he cylinder. Use a check valve o~ ~ap in ~he discharge line p~even~ hazardous back flow i n~o the cylinder. For ~clitional I~nclling recommen~aaiona consult L'Air LJcluiCe'a EJ'~cyctol~lia cie Gaz or C. omgressad Gas As~3c~lion Paml=niet P-~. · I~IC~AI. ~I'OI~M~ RECOMMENOATK}N8 Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 130F (54C}. Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in-first out" inventory system to ~revent full cylinders being stored for excessive periods of time. For aclcl~orml storage recornrnenc~at~ons consult L'Air Liquide'$ Enc'yclol)e~ia cie Gaz or Compres,~' Gas Association Pamprtlet ~)ECtAL PACXAGING I~ECOMMENDATtONS Nitrogen is noncorrosive and may be used with any common structural material. OTHER RECOMMENOA~ON$ OR PRECAUTIONS Compressed gas cylinders should not be refilled except by qualified producers of compressed gases. Shipment of a compressed gas cylinder which has not been filled by the owner or with his (written) consent is a violation of Federal Law (49CFR). .Page LJQUID AIR CORPORATION ~" '~ "~""~ TIME WEIGHTED' AVERAGE EJ(POSURE LIMIT: (Continued) pressure which is equivalent to a partial pressure of 135 ~ Hg (ACGIH, 1984-85} SYMPTOMS OF EXPOSURE: (Continued} o Tingling of the tongue, fingertips or toes; o Weakened speech leading to the inability to utter sounds; o Rapid reduction in the ability to perform movements; o Reduced consciousness of the surroundings. o Loss of tactile sensations. o Heightened mental activity· It should be recognized that it is possible that. none of the above symptoms may occur in nitrogen asph~x!a so that. there are no definite warning symptoms. Nit. re, eric an cause * For additional information, refer to L'Air Liquide's Encyclopedia des Gaz. LOCAL EXHAUST: (Continued} To prevent accumulation of high concentrations so'as to reduce the oxygen level in the air to less than 18 molar percent· Material Safety Data Sheet O~yaen · rm~t~ (41S) 977-6500 E]M.RqENGY P,E~K~N~E ;NFOfl~TION ON PAGE 2 ~qUlO Alii CORPOR,~IQN TlqAOI WI ANO SYNONYM~ ~ NUMBER One CaJif~mi~ Plaza. Suite 350 ' 0xya. en 7782-44-7 2121 N. CaJifOrTdl Blvd. CHE:MIC.~L IL&ME .&NO SYNONYMS IS,~JI 0ATE QCTC)BER 1, lW FQRMUL,A ~ WEIGHT CHEMIC&L FAMILY ~,o ,mw~Q,m ~om,o,urra u,.=., o~'r. 02 31.999 HEALTH HAZARD DATA ~mw~T~EAM[X~OSu,~umT None established (ACG[H, [984-85). Oxygen is the "vital element" in [he at~'nosphere in which we live and breathe (approximately 2]. mo]ar ~ of the atmns~here). Breathing high concentrations (greater than 75 molar percent) causes symptoms of hyperoxia which include cramps, nausea, dizziness, hypothermia, ambylopia, respiratory difficulties, bradycardia, fainting spells and convuls.ions capable of leading to death. For additional data on hyperoxia as it relates to oxygen pressure and exposure duration, refer, to L'Air Liquide's £ncyclopedie des Gaz. TQXIGOI.C~ Pt~OI~J~llF.~ The property is that of hyperoxia which leads to pneumonia. Concentrations between 25 and 75 mol-ar percent present a risk of inflan~nation of organic matter in the body. Listed as Carcinogen National Toxicology Yes I'"I I.A.R.C. Yes [~ OSHA Yes C or Potential Carcinogen Program No [] Monographs No [] No [] PROMPT MEDICAL ATTENTION IS HANOATORY [N ALL CASES OF OVEREXPOSURE TO OXYGEN. RESCUF PERSONNEL SHOULD BE COGNIZANT OF EXTREME FIRE HAZARD ASSOCIATED ~[TH OXYGEN-RICH ATMOSPHERES. Conscious persons should be assisted to an uncontaminated area and breathe fresh air. They should be kept warm and quiet. The physician should be informed that the victim is experiencing (has experienced) hyperoxia. Unconscious persons should be moved to an uncontaminated area and given assis, ted respiration. When breathing has been restored, treatment should be as above. Continued treatment should be symptomatic and supportive. Juai~ts u (Q 01i SUml3~kly Of ifl~rman(~ r~mmn fM ~mfl~'s ~J~ ~e n~nly purcflmf'$ mWlsd)iiily l'hm~, ait~gfl re3soflabll c31'l fl~1 i~een ~aXen tn me preoa~aaon Of ~n~'rn~uan. L,qmd Air Cof~orilmn extends no wanantte~, maim~ no (eOreslntauons. and assumes no resOafls~l~iily ~ ~ ~e Ktu~cy ar suitaOlilty Of SUN~I IfltofmitlOfl for apOlK:atK)n fo ,mOmW) usa al' aoolmcatimt o! ~al pmdKt. Oata Sheets may Isa caamaed from ama to hml. 8i sure tO consult the latest edibon. Oxygen vigorously accelerates combustion. ContaCt with all flan~able materials should be avoided. Some materials which are not flammable in air will burn in pure oxy.jan or oxygen-enriched atmospheres. I PHYSICAL DATA ' ~31UIM~ imOINT U~UID OENMTY &T BOIUN(~ Jm~INT v~oN~u.m 0 70°F (21.1°C) above the (3&~OINIITYATm'.IMm criti, .0828 lb 1.326 · ~.um~rrv tN WAT~ Bunserl ~ ~ coefficient = .0310 -361.838°F {-1~8.574°C) Colorless. odorl .ecific ~ 70F Air=l.0) is 1.11. FIRE AND EXPLOSION HAZARD DATA N/A N/A N/A m~n,~um,~,m~m Copious quantities of water for fires with I Oxyqen as the oxidizer.I Nonhazardou~ If possible, stop the flow of oxygen which is supporting the fire. Vigorously accelerates combustion. . I REACTIVITY DATA STAMI.JTY CONOITION8 TO AVOID UnIWMI A11 fl an~nabl e material s I'IAZ, A~OOIJ~ DICOMI)(~ITION I)NOOUCl'~ None HJ~.&~OOU~ ~II~LYMEI~Z~TION CONOnloN~ TO AVOID wm NM (~m~ SPILL OR LEAK PROCEDURES ~ TO U TAKEN IN ~ M&TEIMAI,, IS I~EI,,EA~O OR ~I~U,,EO [vacuate all personnel' from affected area. Use appropriate protective equipment. If leak is in user's equipment, be certain to .purge piping with an inert gas prior to attempting repairs. If leak is in container or container valve, contact the closest Liquid Air Corporation location. W&Sl"I OiS~OS~L Do not attempt to dispose of residual or unused quantities. Return in the shippingI container p .roperly labeled, with any valve outlet plugs or caps securld and valve protection cap in place to Liquid Air Corporation for proper disposal. For emergency I disposal, contact the closest Liquid Air Corporation location. EMERGENCY RESPONSE INFORMATION' IN CASE OF EMERGENCY INVOLVING THIS MATERIAL, CALL DAY OR NIGHT (800) 231-1366 OR CALL CHEMTREC AT (800t 424-9300 :~PECLA. L PROTECTION IN~OP"~.TION vm~n~ (~,~o~um~ To prevent accumulation To prevent accumula- ~hov~ ~ m~l~ Pe. rcent. As required; any material Safety goggles or glasses OTHER PRQ'T'EG'TW~ EQUIPMENT Safety shoes, safety shower SPECIAL PRECAUTIONS* DOT Shipping Name: Oxygen or Oxygen, compressed DOT Hazard Class: Nonflan~able gas DOT Shipping Label: Oxidizer I.D. No.: UN 1072 ~II~:~AL. HANOLJN~ RECQMMF. NQATIQNI Use only in well-ventilated areas. Valve protection caps and valve outlet threaded plugs must remain in place unless container is secured with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing regulator when connecting cylinder to lower pressure (<3000 psig) piping or systems. Do not heat cylinder by any means to increase the discharge rate of product from the cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. For additional handling recomnlen(~tlortm c~n~ult I.'AJr I. jquicle's EncyctOl)~dla cie Gmz or Com13ressid Gas Aasocia~lon Pwt~Dhlet p-1. SP~C~AL ST'QRAGI R~CC)MIdINOATION~ Protect cylinders from physical damage. Store in cool, dry, well-ventilated area, away from heavily trafficked areas and emergency exits and away from full or empty stored cylinders which contain flan~nable products. 0o not allow the temperature where cylinders are stored to exceed 130F (54C). Cylinders should be stored upright and firmly Secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in-first out" inventory system to prevent full cylinders being stored for excessive periods of time. For acldWonai stooge recommencla~ons con~ff CAir ~qu~ds EncyciopiclM ~e Gaz or Compresasd Gas Aszoc~bon Pamphlet P-1. SP~GIA~ PAGXA~NG REGOMMENOA~ON,,~ Carbon steels and low alloy steels are acceptable for use at lower pressures. For high pressure applications use stainless steels,~opper andjts alloys, nickel and its alloys, brass, bronze, silicon alloys, ~nel~, Inconel~or bAryllium. (~ad and silver or lead and tin alloys are good gasketing materials. Teflon~and Kel-F~are the preferred nonmetal gaskets. Special Note: It should be recognized that the ignition temperature of metals and nonmetals in pure oxygen service decreases with increasing oxygen pressure. For additional information refer to L'Air Liquide's Encyclopedie des Gaz. Oxygen should not be'used as a substitute for compressed air in pneumatic equipment since this type generally contains flan~nable lubricants. Equipment to contain oxygen must be "cleaned for oxygen service." See Compressed Gas Association Pamphlet G-4.1. Compressed gas cylinders should not be refilled except by qualified producers of compressed gases. Shipment of a compressed gas cylinder which has not been filled by the owner or with his (written) consent is a violation of Federal Law (49CFR}. L ALPHAGAZ LIQUID AIR CORPORATION ALPHAGAZ DIVISION Specialty Gas Material Safety Data Sheet PRODUCT NAME Sulfur Hexafluoride TELEPHONE (415) 977-6500 EMERGENCY RESPONSE INFORMATION ON PAGE 2 LIQUID AIR CORPORATION TRADE NAME AND SYNONYMS CAS NUMBER ALPHAGAZ DIVfSION One California Plaza, Suite 350 SU1 fur Hexafl uo ri de 2551-62-4 2121 N. California Blvd. CHEMICAL NAME AND SYNONYMS Walnut Creek, California 94596 Sul fur Hexafl uori de ISSUE DATE OCTOBER 1, 1985 FORMULA MOLECULAR WEIGHT CHEMICAL FAMILY AND REVISIONS CORPORATE SAFETY DEPT.SF6 146.05 Inorganic Fluoride HEALTH HAZARD DATA TIME WEIGHTED AVERAGE EXPOSURE LIMIT 1000 Molar PPM; STEL = 1250 Molar PPM (ACGIH, 1984-85). PLEASE SEE NOTE ON LAST PAGE. SYMPTOMS OF EXPOSURE Effects of exposure to high concentrations so as to displace the oxygen in the air necessary for life are headache, dizziness, labored breath, lng and eventual unconsciousness. TOXICOLOGICAL PROPERTIES Sulfur Hexafluoride is nontoxic, but the liberation of a large amount in a confined area could displace the amount of oxygen in air necessary to support life. Listed as Carcinogen National Toxicology Yes ' [] I.A.R.C. Yes [] OSHA Yes. [] or Potential Carcinogen Program No [] Monographs No [] No [] RECOMMENDED FIRST AID TREATMENT PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO SULFUR HEXAFLUORIDE. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED BREATHING APPARATUS...~ Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the. contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given mOuth-to-mouth resuscitation and supplemental oxygen. Medical assistance should be sought immediately. JuOgements as to the suitability of information herein for purchaser's purposes are necessarity purchaser's responsibility. Therefore, although reasonable care has been taken in the preparation of suc,q information, Liquid Air Corporation extends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's intended purposes or consequences of its use. Since Liquid Air Corporation has no control over the use of this product, it assumes no liability for damage or loss of product resulting from proper (or improper) use or application of the product. Data Sheets may be changed from time to time. Be sure to consult the latest edition. AG 05273 ~ '"Page 2 ~HAZARDOU$ MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES Disilane explodes violently on contact with sulfur hexafluoride. Electrical arCing in the presence of oxygen will break down sulfur ~ hexafluoride yielding toxic thionyl fluoride compounds. PHYSICAL DATA BOLLING POINT Subl i mation poi nt : LIQUID DENSITY AT BOLLING POINT -82.8°F (-63.8°C) See last page. VAPOR PRESSURE@ 70°F (21.1oc): GASDENSlTYAT70°Flatm@ 68OF 3(20oc) : 319.1 psia (2200 kPa) ,3847 lb/ft3 (6.162 kg/m ) SOLUBILITY IN WATER @68°F (20°C) Bunsen FREEZING POINT coefficient : .0056 ~-Sg.4°F (-50.R°£) APPEARANCE AND ODOR Colorless, odorless gas. Specific gravity @70°F (Air = 1.0) is 5.13. FIRE AND EXPLOSION HAZARD DATA EXTINGUISHING MEDIA I ELECTRICAL CLASSIFICATION Nonflammable, inert gas I Nonhazardous SPECIAL FIRE FIGHTING PROCEDURES N/A UNUSUAL FIRE AND EXPLOSION HAZARDS REACTIVITY DATA STABILITY CONDITIONS TO AVOID Unstable Slable X INCOMPATIBILITY (Materials to avoid) See Hazardous Decomposition' Products HAZARDOUS DECOMPOSITION PRODUCTS See last page. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur Will Not Occur X SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Evacuate all personnel from affected area. Use appropriate protective equipment.. If leak is in user's equipment, be certain to purge piping with an inert gas prior to attempting repairs. If leak is in container .or container valve, contact the closest Liquid Air CorpOrat.ion location. WASTE DISPOSAL METHOD Do not attempt to disPose of waste or unused quantities. Return in the shipping container properly labeled, with any valve outlet plugs or caps secured and valve protection cap in place to' Liquid Air Corporation for proper disposal. For emergency disposal', contact the closest Liqu.id Air Corporation location. . EMERGENCY RESPONSE INFORMATION IN CASE OF EMERGEN(~Y INVOLVING THIS MATERIAL, CALL'DAY OR NIGHT (800) 231-1366 'OR CALL CHEMTREC AT (800) 424-9300 · SPECIAL PROTECTION INFORM~)N Page 3 RESPIRATORY PROTECTION (Sl~Cl~/type) POS i ti ve pressure air 1 i ne wi th mas k or sel f-contai ned breathin.q apparatus should be available for emeraencv use. VENTILATION LOCAL EXHAUST I'0 prevent ac~umul ation SPEmAL HOOd with forced above the TWA venti l ati on MECHANICAL (Gen.) OTHER PROTECTIVE GLOVES Any material EYE PROTECTION Safety goggles or gl asses OTHER PROTECTIVE EQUIPMENT I Safety shoes SPECIAL PRECAUTIONS* SPECIAL LABELING INFORMATION DOT Shipping Name: Compressed gas, n.o.s. DOT Hazard Class: Nonflammable gas DOT Shipping Label: Nonflammable gas I.D. No.: UN 1956 SPECIAL HANDLING RECOMMENDATIONS Use only in well-ventilated areas. Valve protection caps must remain in place unless container is secured with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand tru'ck for cylinder movement. Use a pressure reducing regulator when connecting cylinder to lower pressure (<700 psig), piping or systems. Do not heat cylinder by any means to increase the discharge rate of product from the cylinder. Use a check valve or trap 'in the discharge line to prevent hazardous back fl ow into the cylinder. For additional handling recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet p-1. SPECIAL STORAGE RECOMMENDATIONS Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 130F (54C). Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in-first out" inventory system to prevent full cylinders being stored for excessive periods of time. For additional storage recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet P-1. SPECIALPACKAGINGRECOMMENDAT|ONS At normal temperatures, sulfur hexafluoride is noncorrosive and may be used with any common structural material. (See hazardous decomposition products.) OTHER RECOMMENDATIONS OR PRECAUTIONS Compressed gas cylinders should not be refilled except by qualified producers of compressed gases. Shipment of a compressed gas cylinder which has not been filled by the owner or with his (written) consent is a violation of Federal-Law (49CFR). *Various Government agencies (i.e., Deoartment of Transporta~fion, Occupational Safeb/and Health Administration, Food and Drug Administration and o~ers) may have specific regulations concerning ~e transportation, handling, storege or use of this product whicl3 may not be contained herein, The customer or user of this product should be familiar with ~ese regulations. Page 4 ~'~--~ LIQUID AIR CORPORATION ALPHAGAZ DIVISION ADDITIONAL DATA TIME WEIGHTED AVERAGE EXPOSURE LIMIT: (Continued) NOTE: The American Conference of Government and Industrial Hygienists has indicated in the 1984-85 "Threshold Limit Values for Chemical Substances and Physical Agents in the Work Environment and Bilogical Exposure Indices with Intended Changes" that they are deleting the STEL value for sulfur hexafluoride. LIQUID DENSITY AT BOILING POINT: ~(Continued) Liquid at vapor liquid equilibrium @ 59°F (15°C) : 89.83 lb/ft3 (1439 kg/m3). HAZARDOUS DECOMPOSITION PRODUCTS: (Continued) Sulfur hexafluoride is only stable at elevated temperatures (~400°F) if contained in aluminum, stainless steel, copper and brasses or silver. Other metals can cause slow decomposition to SF2, S2F2, SF4 and S2F10. If oxygen is present, thionyl fluoride compounds such as SOF2, S02F2 will De formed as well as other' toxic fluoride compounds. 0 '=~ LIQUID AIR CORPORATION INDUSTRIAL GASES DIVISION Material Safety Data Sheet PRODUCT NAME Compressed Air TELEPHONE (415) 977-6500 EMERGENCY RESPONSE INFORMATION ON PAGE 2 LIQUID AIR CORPORATION TRADE NAME AND SYNONYMS CAS NUMBER iNDUSTRIAL GASES DIVISION One California Plaza, Suite 350 See 1 est page .. N/A 2121 N. California Btvd. CHEMICAL NAME AND SYNONYMS Walnut Creek, California 94596 Air ISSUE DATE OCTOBER 1, 1985 FORMULA MOLECULAR WEIGHT CHEMICAL FAMILY AND REVISIONSCORPORATE SAFETY DEPT. See note on last page, 28,966 I N/A HEALTH HAZARD DATA TIME WEIGHTED AVERAGE EXPOSURE [JMIT None listed (ACGIH, 1984-85). SYMPTOMS OF EXPOSURE Air is nontoxic and necessary to support life. Inhalation of air in a high pressure environment such as underwater diving, caissons or hyperbaric chambers can result in symptoms similar to overexposure to pure oxygen. These include tingling of finger, s and toes, abnormal sensations, impaired coordination and confusion. Decompression sickness pains or "bends" are possible following rapid decompression. TOXICOLOGICAL PROPERTIES High pressure effects (greater than two atmospheres of oxygen) are on the central nervous system. Improper decompression results in the accumulation of nitrogen in the blood. Listed as Carcinogen National Toxicology Yes [] I.A.R.C. Yes [] OSHA Yes [] or Potential Carcinogen Program No [] Monographs No [] No' [] RECOMMENDED FIRST AID TREATMENT Facilities or practices at which air is breathed-in a high pressure environment should be prepared to deal with ~lnesses associated with decompression (Bends or Caisson Disease). Decompression equipment may be required. Judgements as to the suitability of information herein for purchaser's purposes are necessarily purchaser's responsibility. Therefore, although reas~3nable care has been taken in the preparation pt such information. L qu d Air Corporation extends no warranties, makes no representations, and assumes no responsibility as to the accuracy or suitability of such information for application to purchaser's intended purposes or consequences of its use. Since Liquid Air Corporation has no control over the use pt this product, it assumes no liability for damage or loss of product resulting from proper (or improper) use or application of the product. Data Sheets may be changed from time to time. Be sure to consult the latest edition. ~ Page 2 ¢ HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES PHYSICAL DATA BOILING POINT LIQUID DENSITY AT BOILING POINT -317.9°F (-194.4°C) 54.70 lb/ft3 (876.21 kg/m3) VAPOR PRESSURE@ 70°F (21.1°C) above the GASDENSITYAT70°Flatm critical temperature of -220.4°F (-140.2°C .0749 lb/ft3 (1.200 k§/m3) SOLUBILITY IN WATER @ 68°F (20°C) Bunsen FREEZlNGPOINT N/A; Bubble Point @ 1 Atm. : coefficient = .0183 -317.8°F (-194.35°C) APPEARANCE AND ODOR Colorless, odorless gas. Specific gravity @70.°F (Air : 1.0) is 1.0. FIRE AND EXPLOSION HAZARD DATA N/A I N/A I N/A EXTINGUISHING MEDIA I ELECTRICAL CLASSIFICATION Nonfl ammabl e gas I Nonhazardous SPECIAL FIRE FIGHTING PROCEDURES N/A UNUSUAL FIRE AND ~PLOSION HAZARDS Compressed air at high pressures will accelerate the burning of materials to a greater rate than they burn at atmospheric pressure. REACTIVITY DATA STABILITY CONDITIONS TO AVOID Unstable Stable X INCOMPATIBILITY (Materials to avoid) None HAZARDOUS DECOMPOSITION PRODUCTS None HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur Will Not Occur X SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR.SPILLED ~ N/A WASTE DISPOSAL METHOO N/A EMERGENCY RESPONSE INFORMATION IN CASE OF EMERGENCY INVOLVING THIS MATERIAL, CALL DAY OR NIGHT (800) 231-1366 ,~ ~ I SPECIAL PROTECTION INFORM~DN Page 3 RESPIRATORY PROTECTION (Specify type) N/^ VENTILATION LOCAL EXHAUST SPECIAL N/A N/A MEC.A.,CA' (G...I OT.ER ¼..,:~.- N/^ PROTECTIVE GLOVES Any material EYE PROTECTION Safety goggles or glasses OTHER PROTECTIVE EQUIPMENT Safety shoes SPECIAL PRECAUTIONS* SPECIAL LABELING iNFORMATION DOT Shipping Name: Air, compressed DOT Hazard Class: Nonflammable gas DOT Shipping Label' Nonflammable gas I.D. No.: UN 1002 SPECIAL HANDLING RECOMMENDATIONS Valve protection caps must remain in place bnless container is secured with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing regulator when connecting cylinder to lower pressure (,3,000 psig) piping or systems. Do not heat cylinder by any means to increase the discharge rate of product from the cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. For additional handling recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet p.1. SPECIAL STORAGE RECOMMENDATIONS Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 130F (54C). Cylinders should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should be segregated. Use a "first in-first out" inventory system to prevent full cylinders being stored for excessive periods of time. For additional storage recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet P-1. SP;CIALPACKAGINGRECOMMENDATIONS Dry air is noncorrosive and may be used with all materials of construction. Moisture causes metal oxides which are formed with air to be hydrated so that they increase in volume and lose their protective role (rust formation). Concentrations of S02, Cl2, salt, etc. in the moisture enhances the rusting of metals in air. OTHER RECOMMENDATIONS OR PRECAUTIONS '. '.. Compressed gas cylinders should not be refilled except by qualified ~rodu'cers of .;~.' compressed gases. Shipment of a compressed gas cylinder which has not been filled by the owner or with his (written) consent is a violation of Federal Law (49CFR). *Various Government agencies (i.e., Department of Transportation. Occupational Safety and Health Administration, Food and Orug Administration and o~ers) may have specific regulations concernit~g the transportation, handling, storage or use of this product which may not be contained herein, The customer or user of this product should be familiar with these regulations. Page 4 ' I~iOUID AIR CORPORATION INDUSTRIAL GASES DIVISION ? ADDITIONAL DATA TRADE NAME AND SYNONYMS: (Continued) Air; Compressed Air; Compressed Air, Breathing Quality NOTE: Atmospheric air which is compressed is composed of the following concentrations of gases: Gas Molar % Nitrogen 78.09 Oxygen 20.94 Argon 0.93 Carbon Dioxide 0.033* Neon 18.18 x 10-4 Helium 5.239 x 10-4 Krypton 1.139 x 10-4 Hydrogen 0.5 x 10-4 Xenon 0.086 x 10-~ Radon 6 x 10-18 Water vapor Varying concentrations * Concentrations may have slight variations. Compressed air is also produced by reconstitution using only oxygen and nitrogen. This product contains 79 molar percent nitrogen and 21 molar percent oxygen plus trace amounts of other atmospheric gases which are present.in the oxygen and nitrogen. MATERIAL SAFETY DATA SHEET Shell ' MSDS NUMBER ~ 60,030-6 PAGE 1 97367 SHELL: 713-473-9461 CHEMTREC: 800-424-9300 SHELL: 713-241-4819 E SA REA~ OUR PRODUCT ACUTE HI:Al'TH '~.~' Fl'l: ~R~ACTIVITY RAT,NG ~  t'' ~ t HAZARD LEAST · 0 SLIGHT - I MODERATE - 2 ...AND PASS IT ON HIGH'' EXTREME'' ~ / #For acute and chronic health effects refer to the discussion in Section I11 S.ELL OIA'A R) .OIL AX PRODUCT ~ MIXTURE (SEE SEC II-A) CHEMICAL NAME CHEMICAL ~ PETROLEUM HYDROCARBON; INDUSTRIAL OIL FAMILY SHELL ~, 68702 69702 63702 63722 ,CODE SECTZON XX-A PRODUCT/ZNGREDZENT NO. COMPOSITION CAS NUMBER PERCENT P SHELL DIALA OIL AX MIXTURE 100 1 SOLVENT REFINED HYDROTREATED MIODLE DISTILLATE 64742-46-7 60-100 2 SEVERELY HYDROTREATED LIGHT NAPHTHENIC DISTILLATE 64742-53-6 0-40 3 BUTYLATED HYDROXY TOLUENE t28-37-0 <0.2 SECTION XI-B ACUTE TOXXCXTY DATA NO. ACUTE ORAL LD$O ACUTE DERMAL LD50 ACUTE INI'IALATXON LC50 P >10 ML/KG. RAT >2 ML/KG, RAT NOT AVAILABLE BASED UPON DATA AVAILABLE TO SHELL, COMPONENT 3 IN THIS PRODUCT XS NOT HAZARDOUS UNDER OSHA HAZARD COMMUNXCTION (29 CFR 1910.1200). SECTION XII HEALTH INFORMATION THE HEALTH EFFECTS NOTED BELOW/ ARE CONSISTENT ~/ITH REQUIREMENTS UNDER THE OSHA. HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200). EYE CONTACT BASED ON ESSENTIALLY SIMILAR PRODUCT TESTING PRODUCT IS PRESUMED TO BE NONIRRITATING TO THE EYES. SKIN CONTACT BASED ON ESSENTIALLY SIMILAR PRODUCT TESTING PRODUCT IS PRESUMED TO BE SLIGHTLY IRRITATING: TO THE SKIN. PROLONGED AND REPEATED CONTACT MAY RESULT IN VARIOUS SKIN DISORDERS SUCH AS DERMATITIS, FOLLICULITIS OR OIL ACNE. INHALATION INHALATION OF VAPORS (GENERATED AT HIGH TEMPERATURES ONLY) OR OIL MIST MAY CAUSE A MILD IRRITATION OF THE MJCOUS MEMBRANES. OF THE UPPER RESPIRATORY TRACT. INGESTICN OF PRODUCT MAY RESULT IN VOMITING: ASPIRATION (BREATHING OF VOMITUS INTO THE LUNGS) MUST _BE AVOIDED AS EVEN SMALL QUANTITIES MAY RESULT IN ASPIRATION PNEUMONITIS. PRODUCT NAHE: SHELL DZALA(R) OIL AX MSDS 60,O30-~:e,: PAGE 2 SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE. ASPIRATION PNEUMONITIS MAY BE EVIDENCED BY COUGHING, LABORED BREATHING AND CYANOSIS (BLUISH SKIN); IN SEVERE CASES DEATH MAY OCCUR. AGGRAVATED MEDICAL CONDITIONS PREEXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. / SECTION IV OCCUPATIONAL EXPOSURE LIMITS OSHA ACGIH OTHER NO. 'PEL/TWA PEL/CEILING TLV/TWA TLV/STEL P 5 MG/M3* NONE 5 MG/M3~ tO MG/M3* *0IL MIST, MINERAL SECTION V EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT. FLUSH EYES WITH WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. SKIN CONTACT REMOVE CONTAMINATED CLOTHING/SHOES AND WIPE EXCESS FROM SKIN. FLUSH SKIN WITH WATER. FOLLOW BY WASHING WITH SOAP AN0 WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION. INGESTION O0 NOT INDUCE VOMITING. IF VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. GET MEDICAL ATTENTION. NOTE TO PHYSICIAN IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED AND VOMITING HAS NOT OCCURRED, EMESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSIONS OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS, GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. SECTION V! SUPPLEMENTAL HEALTH INFORMATZON NONE IDENTIFIED. SECTION VII PHYSICAL DATA BOILING POINT:.>3OO SPECIFIC GRAVITY: 0.883 VAPOR PRESSURE: NOT AVAILABLE (DEG F) (H20-I) (MM HG) MELTING POINT: -60 (POUR POINT) SOLUBILITY: NEGLIGIBLE VAPOR DENSITY: NOT AVAILABLE ~DEG*'~) (IN W~ER) (AIR-~) pRoDuCT NAME: SHELL DZALA(R) OIL AX MSDS B0,030-6 PAGE 3 / EVAPORATION RATE (N-BUTYL ACETATE " 1): NOT AVAILABLE VIS CS (40 DEG C) ' 9.07-9.3 APPEARANCE AND ODOR: WHXTE LIQUID. SLIGHT HYDROCARBON ODOR. SECTION ~ZZI FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: FLAMMABLE LIMITS /% VOLUME IN AIR 295-3t0 DEG F (COC) LOWER: N/AVA UPPER: N/AVA EXTINGUISHING MEDIA USE WATER FOG, FOAM, DRY CHEMICAL OR C02. DO NOT USE A SIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER. SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER CONFINED FIRE-SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE-PRESSURE NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. SECTION ZX REACTIVITY STABILITY: STABLE HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS AND MATERIALS TO AVOID: AVOID HEAT, OPEN FLAMES, AND OXIDIZING MATERIALS. HAZARDOUS DECOMPOSITION PRODUCTS THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION CONDITIONS. A COMPLEX MIXTURE OF AIRBORNE SOLID, LIQUID, PARTICULATES AND GASES WILL EVOLVE WHEN THIS MATERIAL UNDERGOES PYROLYSIS OR COMBUSTION. CARBON MONOXIDE AND OTHER UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED UPON COMBUSTION. SECTION X EMPLOYEE PROTECTION RESPIRATORY PROTECTION IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SECTION IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS AND PARTICULATES. PROTECTIVE CLOTHING WEAR CHEMICAL-RESISTANT GLOVES AND OTHER PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE SKIN CONTACT. NO SPECIAL EYE PROTECTION IS ROUTINELY NECESSARY. TEST DATA FROM PUBLISHED LITERATURE AND/OR GLOVE AND CLOTHING MANUFACTURERS INDICATE THE BEST PROTECTION IS PROVIDED BY NITRILE GLOVES. SECTION XI ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS ~JUDGMENT WHEN CLEANING UP LARGE SPILLS. *** LARGE SPILLS *** WEAR RESPIRATOR AND PROTECTIVE CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ADSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIALS; DISPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE. *** SMALL SPILLS *** TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY. PRODUCT NAME: SHELL DZALA(R) OIL AX MSDS BO.O30-B, ' · PAGE ·4 ' SECTION llI SPECIAL PRECAUTIONS MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET. FACILITIES. LAUNOER CONTAMINATEO CLOTHING BEFORE REUSE. PROPERLY DISPOSE OF CONTAMINATED LEATHER ARTICLES, INCLUDING SHOES, THAT CANNOT BE DECONTAMINATED. SECTION XZI! TRANSPORTATION REQUZREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION= NOT HAZARDOUS BY D.O.T. REGULATIONS SECT[ON X[V OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. IN ACCORDANCE WITH SARA TITLE III, SECTION 313, THE EDS SHOULD ALWAYS BE COPIED AND SENT WITH THE MSOS. · SECTION XV SPECIAL NOTES SECTION XI - ENVIRONMENTAL PROTECTION HAS BEEN REVISED. THE INFORMATION IN THE "WASTE DISPOSAL" AND "ENVIRONMENT PROTECTION" HAS BEEN REMOVED AND INCLUDED IN THE ATTACHED ENVIRONMENTAL DATA SHEET. IN ACCORDANCE WITH SARA TITLE III, SECTION 3t3, THE EDS SHOULD ALWAYS BE COPIED AND SENT WITH THE MSDS. THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE T~ US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF· SHELL ASSUMES NO RESPONSIBILITY FOR INdURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:NOVEMBER O3, 1988 d. C. WILLETT BE SAFE REAO OUR PROOUCT SHELL OIL COMPANY SAFETY INFORMATION ...AND PASS IT ON PRODUCT SAFETY AND COMPLIANCE (PRODUCT LIABILITY. LAW P. O. BOX 4320 REQUIRES IT) HOUSTON. TX 77210 ENVIRONMENTAL DATA SHEET Shell' EDS NUMBER ~ 60,030 PAGE 1 97449 19- g7) PRODUCT ~ SHELL DIALA(R) OIL AX PRODUCT CODE · 68702 69702 63702 63722 SECTION ! PRODUCT/COMPOSITION NO. COMPONENT CAS NUMBER PERCENT P SHELL DIALA OIL AX MIXTURE t00 I SOLVENT REFINED HYDROTREATED MIDDLE DISTILLATE 64742-46-7 60-t00 2 SEVERELY HYDROTREATED LIGHT NAPHTHENIC DISTILLATE 64742-53-6 0-40 3 BUTYLATED HYDROXY TOLUENE t28-37-0 <0.2 SECTZON Z! " SARA TZTLE ZZZ ZNFORHATZON NO. EHS RQ (LBS) EHS TPQ (LBS) SEC 313 313 CATEGORY 311/312 CATEGORIES (.1) (,2) (-3) (-4) (*B) BASED ON THE DATA AVAILABLE TO SHELL THIS PRODUCT IS NOT REGULATED BY SARA, TITLE IIX - ............................................ FOOTNOTES .................................... ~ ......... · 1 = REPORTABLE QUANTITY OF EXTREMELY HAZARDOUS SUBSTANCE, SEC.302 · 2 · THRESHOLD PLANNING QUANTITY. EXTREMELY HAZARDOUS SUBSTANCE. SEC 302 · 3 = TOXIC CHEHICAL, SEC 3t3 · 4 ' CATEGORY AS REOUIRED BY SEC 313 (40 CFR 372.65 C), MUST BE USED ON TOXIC RELEASE INVENTORY FORM · 5 ' HAZARD CATEGORY FOR SARA SEC, 311/312 REPORTING HEALTH H-I - IMMEDIATE (ACUTE) HEALTH HAZARD H-2 · DELAYED (CHRONIC) HEALTH HAZARD PHYSICAL P-3 · FIRE HAZARD P-4 = SUDDEN RELEASE OF PRESSURE HAZARD . P-5 · REACTIVE HAZARD SECTION ZZZ ENVIRONMENTAL RELEASE INFORMATION THIS PRODUCT IS CLASSIFIED AS AN OIL UNDER SECTION 31t OF THE CLEAN WATER ACT. SPILLS ENTERING (A)- WATERS OR (B) ANY WATER COURSES OR SEWERS ENTERING/LEADING TO SURFACE WATERS THAT CAUSE A .SHEEN MUST REPORTED TO THE NATIONAL RESPONSE CENTER. 800-424-8602. SECTION ZV RCRA ZNFORMATZON PLACE ZN AN APPROPRIATE DISPOSAL FACILITY ZN COMPLIANCE WITH LOCAL REGULATIONS. PRODUCT NAME: SHELL DZALA(R) OZL AX EDS 60,O~. PAGE 2 THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER. SHELL MAKES NO WARRANTY, EXPRESSED DR IMPLIED REGARDING THE ACCURACY OF THESE DATA DR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES'ND RESPONSIBILITY FOR INdURY FROM THE USE OF THE PRODUCT DESCRIBED HEREZN. DATE PREPARED:DECEMBER 08, 1987 .................. SHELL OIL COMPANY ENVZRONHENTAL AFFAIRS P. O. BOX 4320 HOUSTON, TX 79210 FOR ADDZTZONAL ZNFORMATZON ON THZS ENVZRONHENTAL DATA PLEASE CALL (713) 241-2252 FOR EMERGENCY ASSISTANCE PLEASE CALL SHELL: (713) 473-9461 · CHEMTREC: (800) 424-9300