Loading...
The URL can be used to link to this page
Your browser does not support the video tag.
Home
My WebLink
About
BUSINESS PLAN
TE/FACILITY DI iRAM FORM $ BUS I NESS NAME: FLOOR: OF NORTH SCALE: "~.O. Ipgt k0F? (~O~L'CixO-?Ci of~ DATE:~ .% /~ FACILITY N~ME: ~ /~ UNIT ,: OF (CHECK ONE) SITE DIAGRkM FACILITY DIAGR.~ ~ · ,~- 8i%' oooooo Inspector's Comments): -OFFICIAL USE ONLY- - SA - TE/FACILITY DI FORM $ NORTH SCALE: BUS INESS NAME: FL00R: OF (CHECK ONE) SITE DIAGRAM ~ FACILITY DIAGRAM / ~. / ~..~_,,',,.. / '~ /\ / ~ ~ l~ . / 'h~ · Inspector's Comments): -OFFICIAL USE ONLYh STATEMENT OF ACCOUNT CITY OF BAKERSFIELD 1501 TRUXTUN AVE BAKERSFIELD, CA 93301-0000 (805) 3~&-3~7~ DATE: 7/01/96 TO: KALPAKOFF CONSTRUCTI°N 3223 BRITTAN ROAD · BA½ERS~IELD, CA ~3308 CUSTOMER NO: 3001 CUSTOMI~ TYPE: ES/ 3001 FINANCE DEPARTMENT CITY OF BAKERSFIELD '' P.O. BOX 2057 BAKERSFIELD, CALIFORNIA 93303 ADDRESS CORRECTION REQUESTED KALP2~3 9330~2020 RETURN TO SENDER :KALPAKOFF CONSTRUCTION - PATTERSON CA RETURN TO SENDER II1,,,11,,,,,11,,11,,1~,,,!~,,,!!,,,!1,,,,,,1111,,,11,,,1t,,,t HM409601 "' Account Number ACCOUNTS RECEIVABLE ADJUSTMENT March 11, 1994 Date New Account New Address Esther Duren Close Account From Service Chan.qe Other Adjustments X Fire Department- Hazardous Materials Division Department/Division KALPAKOFF CONSTRUCTION Billing Name 3223 BRITTAN RD Billing Address Site Address Parcel # (if Applicable) Landlord Name & Address (If Applicable) ADJUSTMENT Last Billed Correct Billing Adjustment to Effective Date of Billing Change 377.00 0 1-1-94 App~ved' By,; Remarks: THIS BUSINESS SHOULD NOT HAVE BEEN BILLED ON THIS 01 ACCOUNT. THEY HAVE FILED BANKRUPTCY. THIS ACCOUNT IS NOW CLOSED. '-' '" ~'~ HM409602 ~ '- -~~~umber ACCOUNTS RECEIVABLE ADJUSTMENT March 11~ 1994 Date New Ac=ount New Address Esther Duran Close Account From Sewice Cham3e Other Adjustments X Fire Department- Hazardous Materials Division Department/Division KALPAKOFF CONSTRUCTION Billing Name 3223 BRI'i'I'AN RD Billing Address Site Address Parcel 8' (If Applicable) Landlord Name & Address (If Applicable) ADJUSTMENT Last Billed Correct Billing Adjustment to Effective Date of Billing Change 0 377.00 1-1-94 App~-c~ved~By.: - Remarks: THIS BUSINESS SHOULD HAVE BEEN BILLED ON THIS 02 ACCOUNT. THEIR 01 ACCOUNT IS NOW CLOSED. PLEASE GENERATE A MANUAL BILL FOR THE 02 ACCOUNT FOR THE ABOVE AMOUNT. Utilities General Account Maintenance 03/11/94 PUTLS801 Acct Nbr: 409601 Bill Stat: FB Transfer-f~om: Page 1 of 6 Cyc Stat: CL Acct Cyc Stat: CL Transfer-to: Due: 377.00 1. Customer Name: KALPAKOFF CONSTRUCTION 2. Social Sec Nbr: 3. Telephone: 4. Service Address: 3223 BRITTAN RD 5. Service City: BAKERSFIELD 6. State: CA 7. Zip: 93308 8. Parcel ID: 9. Bill Cycle: 5 20. Water Svc Class: 10. Route Nbr: 11. Comments : FILED BANKRUPTCY 12. Prev Acct: HM00584 23. Misc Services: 23.1 Fl4 HAZ MAT HANDLING 13. Service Date: 05/21/93 23.2 14. Fund no: 23.3 15. Billto Ad1:3223 BRITTAN RD 23.4 16. Billto Ad2: 24. Closing Date: 06/18/90 17. Bill-to City: BAKERSFIELD 18. State: CA 19. Zip: 93308 Enter Save(S), Cancel(XX), Next Page(/), or Field # to Change Utilities General Account Maintenance 03/11/94 PUTLS801 Acct Nbr: 409602 Bill Stat: NO Transfer-from: Page 1 of 6 Cyc Stat: CL Acct Cyc Stat: CL Transfer-to: Due: 0.00 1. Customer Name: KALPAKOFF CONSTRUCTION 2. Social Sec Nbr: 3. Telephone: 805-325-4096 4. Service Address: 3223 BRITTAN RD 5. Service City: BAKERSFIELD 6. State: CA 7. Zip: 93308 8. Parcel ID: 9. Bill Cycle: 5 20. Water Svc Class: 10. Route Nbr: 11. Comments : BILLED UNDER 409601 $377 12. Prey Acct: HM00584 23. Misc Services: 23.1 Fl4 HAZ MAT HANDLING 13. Service Date: 01/12/94 23.2 14. Fund no: 23.3 15. Billto Ad1:3223 BRITTAN RD 23.4 16. Billto Ad2: 24. closing Date: 17. Bill-to City: BAKERSFIELD 18. State: CA 19. Zip: 93308 Enter Save(S), Cancel(XX), Next Page(/), or Field # to Change 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 1 Overall Site with 1 Fac. Unit General Information Location: 3223 BRITTAN RD Map: 102 Hazard: Moderate Community: COUNTY STATION 64 Grid: 23B F/U: 1 AOV: 0.0 Contact NameI Title i Business Phone 24-Hour Phone~ ABE KALPAKOFF (805) 325-4096 x (805) 871-0475! CHERI BUTLER (805) 325-4096 x (805) 399-7771/ Administrative Data Mail Addrs: 3223 BRITTAN RD D&B Number: City: BAKERSFIELD State: CA Zip: 93308- Comm Code: 215-064 COUNTY STATION 64 SIC Code: Owner: ABE KALPAKOFF ~-- Phone: ( ) - Address: 14500 LAS PALMAS #41 State: CA City: BAKERSFIELD Zip: 93306- Summary RECEIVED APR 3 0 993 HAZ. MAT. D!V. f ~.~ I, ~"~cU ~'J, ~"[D~Do hereby ce.i~ that I have reviewed the a~ached h~a~ous materials manage- ment plan fo[~[ b~,~ ~nS~nd that it alo~ with (~me of any corre~ions constitute a ~mpl6te and ~ffe~ man- agement plan for my facili~. 4oq 60[ 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-008 AMMONIA Gas 300 Extreme · Pressure, Immed Hlth FT3 02-002 ACETYLENE Gas 2500 High · Fire, Pressure, Immed Hlth FT3 02-005 PROPANE GAS Gas 250 High · Fire, Pressure, Immed Hlth GAL 02-001 OXYGEN Gas 25000 Low · Fire, Pressure, Immed Hlth FT3 02-004 A1025 HELIUM ? 3870 Minimal · FT3 02-003 ARGON/CARBON DIOXIDE Gas 4000 Minimal · Fire, Pressure, Immed Hlth FT3 02-006 CARBON DIOXIDE Gas 20000 Minimal · Fire, Pressure, Immed Hlth FT3 02-007 NITROGEN Gas 12500 Minimal · Fire, Pressure, Immed Hlth FT3 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-008 AMMONIA Gas 300 Extreme · Pressure, Immed Hlth FT3 CAS #: Trade Secret: No Form: Gas Type: Pure Days: 365 Use: OTHER Daily Max FT3300I~ Daily Average 500.00FT3 I Annual Amount 1,500.00FT3 -- Storage Press T Temp~ Location .PORT. PRESS. CYLINDER Above ~Below ISOUTH END OF BLDG 3 - Conc~ Components MCP ---7Guide 100.0% I Unrated I 0 02-002 ACETYLENE Gas 2500 High · Fire, Pressure, Immed Hlth FT3 CAS #: 74-86-2 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: FABRICATION Daily Max FT3I Daily Average FT3 I Annual Amount FT3 2,500 ~ 2,000.00 25,000.00 StorageI Press T Temp~ Location PORT. PRESS. CYLINDER Iabove ~Below INORTH END OF BLDG 3 -- conc~ Components MCP ---TGuide 100.0% I Unrated I 0 02-005 PROPANE GAS Gas 250 High · Fire, Pressure, Immed Hlth GAL CAS #: 74-98-6 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: HEATING Daily Max GAL250I~ Daily Average150.00GAL I Annual Amount500.00GAL Storage Press T TempI Location ABOVE GROUND TANK . Above ~Below ISOUTH END OF BLDG 1 - Conc Components ~ MCP -~Guide 100.0% I Iunrated I 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 4 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-001 OXYGEN Gas 25000 Low · Fire, Pressure, Immed Hlth FT3 CAS #: 7782-44-7 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: FABRICATION Daily Max FT3 Daily Average FT3 Annual Amount FT3 -- 25,000 I 20,000.00 [ 250,000.00 Storage I Press T Temp I Location - PORT. PRESS. CYLINDER Above ~Below SOUTH END OF BLDG 3 -- Conc Components MCP ---~uide 100.0% I IUnrated I 0 02-004 A1025 HELIUM ? '3870 Minimal · FT3 CAS #:. Trade Secret: No Form: Unknown Type: Mixture Days: Use: FABRICATION Daily Max FT3 Daily Average FT3 Annual Amount FT3 3,870 I 0.00 I 27,864.00 Storage Press Temp Location PORT. PRESS. CYLINDER I T IS SIDE BLDG 3 -- Conc Components MCP ---TGuide 90.0% Unrated I 0 7.5% Unrated I · 0 2.5% Unrated I 0 02-003 ARGON/CARBON DIOXIDE Gas 4000 Minimal · Fire, Pressure, Immed Hlth FT3 CAS #: 7440-37-1 Trade secret: No Form: Gas Type: Pure Days: 365 Use: FABRICATION Daily Max FT3I Daily Average FT3 I Annual Amount FT3 4,000 ~ 2,000.00 10,000.00 Storage Press T TempI Location PORT. PRESS. CYLINDER Above ~Below ISOUTH END OF BLDG 3 -- Conc Components MCP -~Guide 100.0% I IUnrated ] 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 5 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02'006 CARBON DIOXIDE Gas 20000 Minimal · Fire, Pressure, Immed Hlth FT3 CAS #: 128-38-9 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELDING SOLDERING Daily Max FT3I Daily Average FT3 I Annual Amount FT3 20,000 ~ 16,000.00 32,000.00 StorageI Press T Temp~ Location ABOVE GROUND TANK IAbove ~Below ISOUTH END OF BLDG 3 -- Conc~ Components MCP ---/Guide 100.0% I Unrated I 0 02-007 NITROGEN Gas 12500 Minimal · Fire, Pressure, Immed Hlth FT3 CAS #: Trade Secret: No Form: Gas Type: Pure Days: 365 Use: OTHER Daily Max FT3I Daily Average FT3 I Annual Amount FT3 12,500 ~ 10,000.00 50,000.00 StorageI Press T Temp~ Location PORT. PRESS. CYLINDER IAbove ~Selow ISOUTH END OF BLDG 3 -- Conc~ Components MCP ---TGuide 100.0% I Unrated I 0 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 6 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency NOtification CALL 911 <2> Employee Notif./Evacuation FIRST WE SOUND BUZZER OUTSIDE 5 TIMES. THEN WE VERBALLY NOTIFY ALL EMPLOYEES. CaLL 911. WE EVACUATE FROM GATE ON . (FEWER HAZARDS) ~,-i~ I%o~c~ <3> Public Notif./Evacuation NONE LISTED <4> Emergency Medical Plan NEAREST HOSPITAL 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 7 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention TO PREVENT ANY ACCIDENTS WE ARE MAKING SURE GASES ARE STORED IN THE RIGHT CONTAINERS. THEY ARE STORED PROPERLY WITH THE CORRECT FITTINGS AND VALVES. 'THE GASES ARE CHAINED OUTSIDE BUILDING 3. ~THE OXYGEN AND ACETYLENE ARE SEPERATED. NO ONE 'SMOKES NEAR THE GASES. <2> Release Containment ALL SPILLS WILL BE HANDLED ACCORDING TO THE MATERIAL SAFETY DATA SHEETS <3> Clean Up <4> Other Resource Activation 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 8 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards NEED A 10 BC TYPE FIRE EXTINGUISHER SECURE COMPRESSED GAS CYLINDERS <2> Utility Shut-Offs A) GAS - NORTHWEST END OF BUILDING 1 B) ELECTRICAL - NORTHEAST CORNER BUILDING 2 C) WATER NORTHEAST CORNER OF. BUILDING 2 D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - NONE LISTED FIRE HYDRANT - ????? <4> Building Occupancy Level 04/14/93 KALPAKOFF CONSTRUCTION 215-000-000584 Page 9 00 - Overall Site <G> Training <1> Page 1 WE HAVE 9 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE OUR EMPLOYEES KNOW WHERE MSDS ARE AND HOW TO USE THEM. <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use CITY of BAKER SFIELD "WE CARE" FIRE DEPARTMENT 2101 H STREET S. D. JOHNSON April 15, 1993 BAKERSFIELD,93301 FIRE CHIEF 326-3911 Kalpakoff Construction c/o Abe Kalpakoff 3223 Brittan Road Bakersfield, CA 93308 Dear Mr. Kalpakoff, When you filed bankruptcy in 1990, we inadvertently removed your business plan and inventory, and placed your file as "no longer in business". In discussion with Dave Kalpakoff at your facility on April 13, 1993, it was decided that we would reactivate the old plan and send it to you for review and update, instead of filing a new business plan. The computer generated business plan is attached. Please review this plan and make any corrections, additions or deletions and return it to this office by May 10, 1993. We have also enclosed blank inventory forms in case changes to your inventory are necessary. If you have any questions, please do not hesitate to call. Sincerely yours, "~'alpl~ ~--'~~""J REH/dlm CASH MANAGEMENT ADJU~S TO ACCOUNTS UI~L~iiES' ~' BILKING HISlDRY FOR AN ACCOUNI _ ~ .'~,~k'q RUILIO? ' SERVICE NAME: KALPAKDFF CONSTRUCTION ~ ACCT CYCLE STATUS: CL SERVICE ADDRESS: ~228 BRITTAN RD 8ILL STATUS: FB ,CITY STATE ZIP: BAKERSFIELD, CA 9&&08 WATER SEWER BILL BALANCE CHARGE/ CHARGE/ ..................... PERIOD POSTINGS ....................... BILL DATE FORWARD CONS CONS DAlE AMOUNT TYPE DESCRIPTION IDENTIFIER A~OUNi CURRENT ~47.05 647.05 01/01/91 628.02 ~ 08/01/90 6.28 892 - FINANCE CHARGE NM,8250,4,26 647.05 ~ 09/01/90 6,34 892 - FINANCE CHARGE NN'8283'6'26 ~,/ 10/01/90 6,41 892 -FINANCE CHARGE NN*8~ll*l*2$ 06/18/90 600.00 / 05/01/90 8.02 892 - FINANCE CHARGE NM*8164*2*88 628.02 ~k,,.05/01/90 20.00 891 - PENALTY NH'81~4'2'89 02/15/90' 400.00 02/15/90 200.00 FFJ - NM~8088~2~272 600,00 02/10/89 . Bill History record for bill date 02/10189 not found.' (BILLHISTS>409601~7712) City of B,jzkersfield ~~,~^~ ~,~ ~o~, ...... ~...~....l.....-_...,_~. ......... [] Signature [] Action [] Information [] File Please:-- [] Return [] See Me [] Follow Up [] Prepare Answer Copy to: ................................................................................................... I. This p~oof is made for the claimanl named below by the undersigned individual who stales thai: {¢he~k appropriate box) E EThe claimanl is a COrpOra'iO~ and the Under E The claima~' is a partnership and ~He Or she is age~` Or attorney He or she is the signed is an aulhorized officer of such Corpora- Ihe undersigned is a member for the claimant Claimant {ion ~hereo~ (INOICA rE THE S TA rE OF INCORPORATION, NAME OF PAR TNERS. O~ SUCH OTHER DESCRIPTION OF THE CLAIMANT AS MA Y BE APP~OPRIA TE] (Please ~upply {or verify) your accent numar for thb ~bl~) 2. The undersigned represents that he or she is duly authorized to make this proof of claim (if appropriate, and to accept the plan) on behalf of the claim~nl. 3. The correct post office add~ess of the claimant to which all notices and dislribution checks ~C ~ ~ ~{~ '~ ~ ~ ~ J ~ ~ ~ ~ should be maifed is stated ~low. ~..i[¥' OF LiA~Eb:Si iLLU If name or address, as printed, is not correct please indicate c?~rect 4. This claim is based upon: (check appropriate box) `name and address to which checks and notices should be del,rated. A note, contract, or olher writing, The original or compfele duplicate copies el all documents are atlached, (or are nol attached ~or the reason sel forth in Ihe statement altached hereto). An open account. An ilemized statement showing the date due is atlached, '~' ( ~ CALCULATION~OF BALANCE DU~E Oth~rconside. r.~tion {or g_ropnd of liability,). Explain. ~.~))r~.~:~FF__.' ~b~:~ ] ?~)~1 ~ PRINCmAL / 5. NO judgment has been rendered upon lhe claim except ~ ~ ' ~5 · m ADDITIONAL CH~F~GES 6. The debtor was at the time of the filing of the pelilion initialing the case, and still is, indebted (or liable) tO this claimant (crier giving full credit for all paymenls, seboffs, and counlerclaims) as follows: ~ TOTAL . ~ tESS rA~ MENTS~ and set forth any olher consideration relevant to Ihe legality of any charge,) Exclude any interest N ACCOUNT ~ accrued after the date the csse was commenced. / PRESENT [ 7. ~la claim I~ free from any charge forbidden by applicable law and e~clude~ all unmalured Inleresl. (PAYOFF 8.This claim is a general unsecured claim, except ~o the extent that the security interest, i~ any, described below is s~fflcient to satisfy the claim. (If priority is claimed, state the amounts and the basis thereof:) 9. NO SECURITY INTEREST IS HELD FOR THIS CLAIM EXCEPT: {1~ security interest in prope~y of the debtor is claimed). The security interest is clahned under the writing relerred to m Paragraph 4 hereof for un,er separate writing which (ora duplicate of which) is aHached hereto, or Under a separate writing which cannot be attached hereto for the reason set fo~h statement attached hereto.) Evidence of perfection of such security interest is also attached hetelo. I L J .L LJ 5 ~ i( ~ ~." Penally For Prate ~(ma Fraud~ent Claim Fine of not more than $5000 or imprisonment for not more than 13 (2-83) F~LE IN DUPLICATE 5 years or both ---- Title 18, U.S.C..{152 ACCOUHT HISTORY: RALPRROFF COHSTRUCTIOH (H~00584) PRIH1£D: 05/07/90 DATE BILLING PRY~EHT AD3UST~EHT BALANCE ]2/o9187 200.00 o2/~o/89 200.00 400.00 400.00 ~CCOU~I HISIOR¥ - :CUSiO~ER: 409601 K~IPAKOfF £OMS]RUCTIOH 10:51:$2 05-07-90 ~ALA~CE DUE: $600.00 0~/i0/87 400.00 02[15[90 200.00 600.00 0.00 0.00 0.00 0.00 records listed, May 4~ 1990 Nine Mayer~ Accounts Receivable FRQM~ Ralph £, Huey~ Hazardous Materials Division SUBJECT: Kalpakoff Construction Nina~ account # HM 409601 has filed bankruptcy effective April 1990. Please make this business no longer in business and close the account. Thanks - _~ that I laave reviewed the MAZ. ~AT. D~V. ett~ched Hez~rdous M~teri~ls business ~l~n name of business and that it alon~ with the attached additions or corrections constitute a complete and correct Business Plan for my facility. sl~na%ur.e date ~ LOO6TtON 3223 BRI,[~N RD HIo,--~, H~Z~RD R~TING ~ 1. OVERVIEW LAST CHANGE OZ/OB/SB BY VAL JUR!S CODE Z15-.OB4 JURIS COUNTY STATION 84 MAP PAGE 1OZ GRID Z3B FACILITY UNITS t HAZARD RATING 3 RESPONSE SUMMBRY 2A SEC NO PRIVATE RESPONSE TEAM EMERGENCY CONTACTS ZA SEC ~~~AKOFF - ~ZS.-4a6 OR 871-B.~ CHERI BUTLER - 3ZS--409G OR 399-7771 UTILITY SHUTOFFS ZA SEC A) GAS - NY END OF BLDG I B) ELECTRICAL - NE CORNER BLDG Z C) WATER - NE CORNER BLOG 2 O) SPECIAL - NONE E) LOCK BOX - NO Z. NOTIFICATION / PUBLIC EVACUATION LAST CHANGE / / BY < NO INFORMATION RECORDED FOR THIS SECTION > PAGE 1 0Z/09/89 15:19 MATERIAL. SAFETY DATA SYSTEMS, INC. (805) 648-6800 BUSINESS NAME KALPRKOFF CONSTRUC'TION ID NUMBER Z15-00~-0~0584 LOCATION 32Z3 BRtTTRN RD HIGH HAZARD RATING 3. HAZ MAT TRAINING SUMMARY LaST CHANGE / / BY < NO INFO~I'ION RECORDED FOR THIS SECTION > 4. LOCAL EMERGENCY MEDICAL ASSISTANCE LAST CHANGE OZ/OB/89 BY VAL 2A SEC S) NEAREST HOSPITAL PaGE Z 0Z/09/89 15:19 MATERIAL SAFETY DaTA SYSTEMS, INC. (805) G48-a800 LOCnTION 3ZZ3 BRlq"TRN RD HIGI~HAZRRD RATING 3 FACILITY UNIT 0! OVERALL HAZARDOUS MATERIALS INVENTORY LAST CHANGE OZ/Og/B9 BY VRL ID LOCRTIoNTYPE NAME C~ usEMRX RMT UNIT HRZBRD I PURE OXYGEN ~ 6600 FT3 HIGH S SIDE BLOG 3 .... 'PORTRBLE PRESS. CYL. F~BRICRTION ID PERCENT COMPONeNtS HAZARD LIST Z359.00 100.0 OXYGEn' COMPRESSED HIGH PURE ACETYLENE 1248 FT3 EXTREME S SIDE BLDG 3 'PORTABLE PRESS. CYL. FABRICATION ID PERCENT COMPONENTS HAZARD LIST 1Z41.OO 1OO.O ACETYLENE EXTREME PURE ~RGON 1344 FT3 NONE S SIDE BLDG 3 PORTABLE PRESS. CYL. FABRICATION ID PERCENT COMPONENTS HRZRRD LIST 1365.00 t00.0 RRGON NONE 4 MIXTURE RIOZS HELIUM 3870 FT3 LOg S SIDE BLDG 3 PORTABLE PRESS. CYL. FABRICATION ID PERCENT coMPONENTS HAZARD LIST ZOZ?.00 90.0 HELItJM UNKNOgN 1365.00 7.5 ARGON NONE 1Z51.00 Z.5 CRRBON DIOXIDE LOg PURE PROPANE GAS 500 GAL EXTREME NW BLDG 1 FIXED PRESS.T~NKS HEATING ID PERCENT COMPONENTS HAZARD LIST llSS.OZ 100.0 PROPANE EXTREME PAGE 3 0Z/09/89 I5:19 MATERIAL SRFETY ORTR SYSTEMS, INC. (80S) G48-G800 BUSINESS NAME KALPRKOFF CONSI'RUCTION ID NUMBER Z15-0¢~0-000584 LOCATION 3ZZ3 BRITTAN RO HIGH HAZARD RATING 3 8. FIRE PROTECTION / WATER SUPPLIES LAST CHANGE 02/09/89 BY VAL SEC 4) NO PRIVATE FIRE PROTECTION 3A SEC S) FIRE HYDRANT 0. EMPLOYEE NOTIFICATION / EVACUATION LAST CHANGE 02/09/89 BY VAL SEC Z) FIRST WE SOUND BUZZER OUTSIDE S TIMES. THEN WE VERBALLY NOI'IFY ALL EMPLOYEES.. CALL.,9I;.~. , WE,,t, EVRCUA'¥E ~FROM,,,GATE ON,, GULF~ STREET. ( FEWER HAZARDS ~ ,-, <~. ~,.,_.., c),/"/ ~",.:~'.~?-,',2¥,~'~ .~', .... ', PAGE 4 0Z/09/89 1S:19 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 848-'8800 BUSINESS NRME KRLPRKJCONSTRUCTION ID NU~ 21.5-000-000584 LOCRTION 3223 BR.'~RN RD HIG~ HRZRRD RRTING 3 E. MITIGRTION / PREVENTION / RBRTEMENT LRST CHRNGE 02109189 BY VRL SEC ]) TO PREVENT RNY RCCIDENTS WE RRE MRKING SURE GRSES BRE STOREO IN THE RIGHT CONTRINERS. THEY ~RE STORED PROPERLY WITH THE CORRECT FITTINGS RND VRLVES. THE GBSES ~RE CHBINED OUTSIDE BLDG 3. 'THE OXYGEN RND RCETYLN RRE SEPER~TED. NO ONE SMOKES NEAR THE GASES. RS FAR RS RBRTEMENT, RLL OF OUR SPILLS WILL BE HRNOLED RCCORDING TO THE~MSDS SHEETS. PRGE 5 02/09/89 15:19 M~TERIRL SBFETY DRTR SYSTEMS, INC. <805) 648-6800 CITY of BAKERSFIELD · - NON--'FRADE SECRETS t ~ I ~ I .!, I ~ I, I ! I I CITY of BAKERSFIELD " NO N-- 17 RAD E S E C R ET S ~,~l,..jof .... CITY, ZIP: ~al~5'~'tJA ~ ~23~ CZ~, ZIP: (~n ~%~{~ ~A~O(~ DUN AND BRADSTREET NUMBER ' O ' d k all t~t a~ly) a. ~tq i & C.A.S. i B~ERS~IELD cI~ FIRE DEPAm3m~ RECEIVED~~/ B~RSF[ELD,CA 93301 JUL 13 1987 (805) 326-3979 OFFICIAL USE ONLY ID# BUSINESS NAME HAZARDOUS lvI3%TERI ALS BUSINESS PLAN AS A WHOLE 000584 FORM 2A INSTRUCTIONS: 1. To avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: CITY: ~ I~*'~' ~ SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency involving the releas6 or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS. ! SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE ~+~o-~ I~- J D. SPECIAL: ~,o.n~_ O ~ ' E. LOCK BOX: YES /~ IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 2A - SECTION 4: PRIVATE RESPONSE TEA~{ FOR BUSINESS AS A WHOLE SECTION. 5:', LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES .EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAZARDOUS MATERIALS:...- .................................... No YES NO B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGENCIES: .......................... ~ NO YES NO C. PROPER USE OF SAFETY EQUIPMENT: .................. ~ NO YES NO D. EMERGENCY EVACUATION PROCEDURES: ................. NO YES NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... NO YES NO SECTION 7: HAZ~u~DOUS NATERIAL CIRCLE YES OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES ~ I, /~_ I<~1 ~D~ kO'~2~ , certify that the above information is accurate. I understand that %his information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. "M ' / F// / BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID# BUSINESS NAME: BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRIk;T YOUR ANSWERS IN ENGLISH. 3. An~.~'er the questions below for THE YACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. FACILITY b~IT# ~ /~ FACILI~ ~IT N~: ~ /~ SECTION 1: MITIGATION~ PRE~NTION, ABATEMENT PROCEDURES SECTION ~: NOTIFICATION ~ND EVACUATION PROCEDb~ES AT THIS UNIT O~LY SECTlgN 3___~: HAZARDOUS MATE____RIAL____S FOR THIS UNIT ONLY, A. Does this Facility Unit contain Hazardous Materials? YES N If YES, see B. If NO, continue with SECTION 4. / B. Are any of the hazardous materials a bona fide Trade Secre>//YES NO If No, complete a separate hazardous materials invent0~Y form marked: NON-TRADE SECRETS ONLY (white form #4A-~f If Yes, complete a hazardous materials inventory foffn marked: TRADE SECRETS ONLY (yellow form #4A-2) in additio~l/to the non-trade secret form. List only tile trade secrets on f~ 4A-2. / SECTION 4: PRIVATE FIRE PROTECTION / .. SECTION 5: LOCATION OF WATER SUPPLY FOR ~SE BY EMERGENCY RESPONDERS / SECTION 6: LOCATION OF UTILITY ~T-OFFS AT THIS UNIT ONLY. A. NAT. GAS/PROPAN~'~ / B. ELECiRICAL: 'C. WATER: D. SPECIAL.'/ OX: YES / NO IF YES', LOCATIOS: IF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 3B - FORM 4A-! Pa~e / of ~ NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY PHONE ~: ~0~-_~2~-~O~& PHONE ~: ~q/-qS{~' {OFFICIAL USE CFIRS CODE - - / ' ONLY 1 2 3 4 9 6 7 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIQAL OR COMMON NAME CODE GUIDE // .... ~/ _,~ ~ NAME: __TITLE: O~m~ SIGNATURE DATE: ~-~- ~ EMERGENCY C ?~ TITLE: ~)~ US HOURS: ~-~0~,~ AFTER BUS HRS: F~I-~ I~ - 4A-1 - SAFETY DATA June 1985 An explanation of the terms used herein may be found in OSHA 29 CFR t910.1200, · available from OSHA regional or area offices. (Essentially similar to U.S. Department of Labor Form OSHA-20 _ ~.. and generally accepted In Canada for Information purposes) Do Not Duplicate This Form. Request an Original. PRODUCT Argon CHEMICAL Argon SYNONYMS Shielding Gas, Argon-40 NAME FORMULA Ar CHEMICAL FAMILY (Rare Gas) Noble Gas MOLECULAR 39.948 WEIGHT TRADE NAME Argon (This product is usually intended for electric welding use.) This section covers the materials from which this product is manufactured. The fumes and gases produced during cutting with the normal use of this product are covered by Section VI. The term "hazardous" in "Hazardous Materials" should be interpreted as a term required and defined in OSHA 29 CFR 1910.1200 and does not necessarily imply the existance of any hazard. MATERIAL (CAS NO.) Vol (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Argon (7440-37-1) 100 Simple asphyxiant (None currently established) BOLLING POINT, 760 mm. Hg - 185.9°C (-302.6°F) FREEZING POINT - 189.2°C (-308.6°F) SPECIFIC GRAVITY (H~O = 1) Gas VAPOR PRESSURE AT 20°C. Gas VAPOR DENSITY (air = 1) 1..378 ~ 21.2°C (70°F) SOLUBILITY IN Neglible WATER, % by wt. PERCENT VOLATILES EVAPORATION R~E BY VOLUME 100 ' (Butyl Acetate = 1) Not Applica~e APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure. [, ...... ' ....... ~=*-.'*,~:: ~ *' - : " ' .'*~ ' , · ; ,~*~:'~ * ,'..;'~ · '~' .,-.~,. ;.'~.. : * :*..T~* '::;~ t '~:~a: '**' .*"*',? *,.2':':L~F-:' ,' *. '=~:Z~'~LZ'~.:~.2~ *~ · IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 304 -- 744-3487 In Canada 514 -- 645-5311 For routine information contact your local supplier Union Carbide requests the users o~ this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION ~ LINDE DIVISION UNION CARBIDE CANADA LIMITED O LINDE DIVISION Copyright ~ 1985 Union Carbide Corporation Page 1 of 4 PRODUCT: · Argon L-4563-B ,__~ ~,~ June 1985 THRESHOLD LIMIT VALUE .._/ The ACGIH 1984-85 recommended limit for welding fume, not otherwise classified (NOC), is 5mg/m3. TLV-TWA's should be used as a guide in the control of health hazards and not as fine lines between safe and dangerous concentrations. See Section VI for specific fume constituents which may modify this TLV-TWA. EFFECTS OF OVEREXPOSURE AND EMERGENCY AND FIRST AID PROCEDURES working with welding and cutting may create one or more of the following health hazards: ' FUMES AND GASES can be dangerous to your health and may cause serious lung disease.* ELECTRIC SHOCK can kill you. ARC RAYS can injure eyes and burn skin. NOISE can damage hearing. This gas is an asphyxiant. Moderate concentrations can cause headache, drowsiness, dizziness and unconsciousness. Lack of oxygen can cause death. Keep your head out of the fumes. Do not breathe fumes and gases caused by the process. Use enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone and the general area. The type and amount of fumes and gases depend on the equipment and supplies used. Possibly dangerous materials may be found in fluxes, coatings, gases, metals etc. Get a Material Safety Data Sheet (MSDS) for every material used. Air samples can be used to find out what respir.atory protection is needed. Do not touch live electrical parts. Wear correct ear, eye, and body protection. Short term overexposure to fumes may result in discomfort such as dizziness, nausea, or dryness or irritation of nose, throat, or eyes. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an ~--" Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. A detailed description of the Health Hazards and their consequences may be. found in Linde's free publication "Precautions and Safe Practices for Electric Welding and Cutting," L52-529. You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Linde Division, Communications Department, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. FIRST AID IN CASE OF EMERGENCY -- Call for medical aid. Employ First Aid techniques recommended by the American Red Cross. IF BREATHING IS DIFFICULT give oxygen. Call a physician. IN CASE OF ELECTRICAL SHOCK disconnect and turn off power. IF NOT BREATHING, begin artificial respiration, preferably mouth-to-mouth. If no detectable pulse, begin external heart massage. Immediately call a physician. IN CASE OF ,ARC BURN call a physician. *NOTES TO PHYSICIAN: Acute -- Gases, fumes, and dusts may cause irritation to the eyes, lungs, nose, and throat. Some toxic gases associated with welding and related processes may cause pulmonary edema, asphyxiation, and death. Acute overexposure may include signs and symptoms such as watery eyes, nose and throat irritation, headache, dizziness, difficulty breathing, frequent coughing, or chest pains. Chronic ~ Protracted inhalation of air contaminants may lead to their accumulation in the lungs, a condition which may be seen as dense areas on chest x-rays. The severity of change is proportional to the length of exposure. The changes seen are not necessarily associated with symptoms or signs of reduced lung function or disease. In addition, the changes on x-rays may be caused by non-work related factors such as smoking, etc. Page 2 of 4 °PRODUCT: Argon L-4563-B - ~ June 1985 ~,'.~ ?: i'~ ~- ~,~,~ ... ~: ?,~' ~--?.~.~ ,_~ ,~-~.? :~? ~;~:~:~*~,~'~ ? ................................... , .................. ~ .~.¥~ .~ .~ ?..?. ~% ~ ~ ..~ .~?~. ~ ~,~ ~,.:. -..' .., .... '.,~ :~'*~ ~- . ~, .~'.. V FIRE AND EXPLOSION HAZARD DATA '~ '. .... ' ............ ~ ,-~--~.-..-~ ~.?,.,,'. ~., ~ [~:~:~:~ ' . Not Applicable I ¢~T[~E Not Applicable INFLAMMABLE LIMITS I LOWERAIR, % by volume Not Applicable IUPPER Not Applicable EXTINGUISHING MEDIA Argon cannot catch fire. Use media appropriate for surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES Evacuate all personnel from danger area. Immediately cool cylinders with water spray from maximum distance until cool then move containers away from fire area if without risk. Shut off leak Jf without risk. Arcs and sparks can ignite combustibles. Refer to American National Standard Z49.1 "Safety in Welding and Cutting" for fire prevention information during the use of welding and allied procedures. UNUSUAL FIRE AND EXPLOSION HAZARDS' Argon cannot catch fire. Container may rupture due to heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125°F). Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. STABILITY I CONDITIONS TO AVOID IUNSTABLE STABLE High pressure gas. Close valve when not in use and when empty. Use with equipment rated to adequately withstand pressures to be encountered. Do not strike arc on cylinder. Do not ground cylinder. See Section IX. X INCOMPATIBILITY (materials to avoid) None currently known. Argon is chemically inert. HAZARDOUS DECOMPOSITION PRODUCTS Ozone and Nitrogen Oxides may be formed by the radiation from the arc. See Section IV. Other decomposition products of normal operation originate from the volatilization, reaction or oxidation of the material being worked. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur Will not Occur None currently known. X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Argon is an asphyxiant. Evacuate all personnel from danger area. Use self contained breathing apparatus where needed. Shut off cylinder if without risk. Ventilate area of leak or move cylinder to well ventilated area. Test area, especially confined areas, for sufficient oxygen content prior to permitting re-entry of personnel. WASTE DISPOSAL METHOD: Slowly release into atmosphere. Discard any product, residue, disposable container or liner in an environmentally acceptable manner in full compliance with Federal, State and local regulations. Page 3 of 4 'PRODUCT: Argon L-4563-B June 1985 RESPIRATORY PROTECTION (specify type) -- Use respirable fume respirator or air supplied respirator when working in confined space or where local exhaust or ventilation does not keep exposure below TLV. Select as per OSHA29 CFR1910.134. LOCAL EXHAUST -- Use enough ventilation, local exhaust or both, to keep the fumes and gases below TLV's in the worker's breathing zone and the general area. Train the worker to keep his head out of the fumes. MECHANICAL (general) ALWAYS WORK WITH ENOUGH VENTILATION VENTILATION SPECIAL - Avoid using electric arcs in the presence of chlorinated hydrocarbon vapors - highly toxic phosgene may be produced. Avoid arc operations on parts with phosphate residues (anti-rust, cleaning preparations) - highly toxic phosphine may be produced. OTHER Depends on specific use conditions, and location. Use adequate ventilation or personal respiratory protection. See Section IX and OSHA29 CFR1910.252. PROTECTIVE GLOVES Welding gloves recommended EYE PROTECTION -- Wear a helmet or use a face shield with a filter lens selected as per ANSI Z49.1. Provide protective screens and flash goggles, if necessary, to protect others. Select as per OSHA29 CFR1910.133. OTHER PROTECTIVE EQUIPMENT -- As needed, wear hand, head, and body protection which help to prevent injury from radiation, sparks and electrical shock. See ANSI Z49.1. At a minimum this includes welder's gloves and a protective face shield, and may include arm protectors, aprons, hats, shoulder protection, as well as dark substantial clothing. Train the worker not to touch li~ electrical pa~s. Fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being worked, the process, procedure and electrodes used. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being worked (such as paint, plating, or galvanizing), the number of workers and the volume of the work area, the quality and amount of ventilation, the position of the worker's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample from inside the worker's helmet if worn or in the worker's breathing zone. See ANSl/AWS F1.1, available from the American Welding Society, 550 N.W. Le Jeune Rd., Miami, FL 33126. Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard Z49.1, "Safety In Welding And Cutting" published by the American Welding Society and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more details. For fu~her safety and health information refer to Linde's free publication "Precautions and Safe Practices for Electric Welding and Cutting" L52-529. OTHER HANDLING AND STORAGE CONDITIONS Arcs and sparks during use could be the source of ignition of combustible materials. Prevent fires. Refer to NFPA 51B "Cutting and Welding Processes." High pressure gas mixture. Use piping and equipment adequatelY designed to withstand pressures to be encountered. Gas can cause rapid suffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. Do not strike arc on cylinder. The defect produced by an arc burn could lead to cylinder rupture. Do not ground cylinder, Never work on a pressurized system. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product.. GENERAL OFFICES ~~LINDE IN THE USA: IN CANADA: .. Union Carbide Corporation Union Carbide Canada Limited ~ u~o~a~o~ Linde DN~sion Linde Division 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronlo, Ontario M4P I J3 O~her offices in principal cilies all over ~he world. ~-4563-B 85-0928 6/85 30M Lithographed in U.S.A. Page 4 of 4 M I'ERIAL DATAI H L-4559-c SAFETY EET May 1985 An explanation of the terms used herein may be found in OSHA 29 CFR 1910.1200, ~ available from OSHA regional or area offices. · (Essentially similar to U.S. Department of Labor Form OSHA-20 .~ and generally accepted In Canada for Information purposes) Do Not Duplicate This Form. Request an Original. PRODUCT Acetylene CHEMICAL NAME Acetylene SYNONYMS Acetylen, Ethine, Ethyne, Narcylene FORMULA C;H2 CHEMICAL FAMILY Alkyne MOLECULAR 26.038 WEIGHT TRADE NAME Acetylene (This product is intended for welding and cutting use.) This section covers the materials from which this product is manufactured. The fumes and gases produced during welding and cutting with the normal use of this product are covered by Section VI. The term "hazardous" should be interpreted as a term required and defined in OSHA 29 CFR 1910.1200 and does not necessarily imply the existance of any hazard. MATERIAL (CAS NO.) Vol (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Acetylene (74-86-2) 100 Simple asphyxiant ·(None currently established) BOILING POINT, 760 mm. Hg Not Applicable SUBLIMATION POINT -84°C (-119.2°F) @ 760mm Hg SPECIFIC GRAVITY (H;O = 1) Not Applicable VAPOR PRESSURE AT 21~C 635 psig VAPOR DENSITY (air= 1) 0.91 SOLUBILITY IN Slight WATER, % by wt. PERCENT VOLATILES EVAPORATION RATE BY VOLUME 100 (Butyl Acetate = 1) Not Applicable APPEARANCE AND ODOR Colorless gas at normal temperature and pressure; garlic-like odor.. IN CASE OF EMERGENCIES involving this material, further information is,available at all times: O In the USA 304 -- 744-3487 In Canada 514 -- 645-5311 (~ For routine information contact your local supplier ~ Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product --J hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors · of the information on this MSDS and any product ha~;ards and safety information, (2) furnish this same information to each of its · - customers for the product, and (3) ~equest such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION [] LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION Copyright (D, 1985, Union Carbide Corporation Page I of 4 PR, ODUCT; Acetylene L-4559-C ~ ~ May 1985 .*.:'.~-~'*',:,.:~'~*~'~:~-'~-~*:~* ~ ,~IV~'HEAETH~ AZ DD TA~:~ THRESHOLD LIMIT VALUE The ACGIH 1984-85 recommended limit for welding fume, not otherwise classified (NOC), is 5mg/m3. TLV-~A's should be used as a guide in the control of health hazards and not as fine lines between safe and dangerous concentrations. See Section VI for specific fume constituents which may modify this TLV-TWA. EFFECTS OF OVEREXPOSURE AND EMERGENCY AND FIRST AID PROCEDURES working with welding and cutting may create one or more of the following health hazards: FUMES AND GASES can be dangerous t0 your health and may cause serious lung disease.* HEAT RAYS (INFRARED RADIATION from the flame or hot metal) can injure eyes. NOISE can damage hearing. Acetylene is an asphyxiant. Moderate concentrations may cause headache, dr~siness, dizziness and unconsciousness. Lack of oxygen can cause death. Keep your head out of the fumes. Do not breathe fumes and gases caused by the ~rocess. Use enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone and the general area. The type and amount of fumes and gases depend on the equipment and supplies used. Possibly dangerous materials may be found in fluxes, coatings, gases, and metals. Get a Material Safety Data Sheet (MSDS) for every material used. Air samples can be used to find out what respiratory protection is needed. Wear correct ear, eye, and body protection.. Short term overexposure to fumes may result in discomfort such as dizziness, nausea, or dryness or irritation of nose, t~roat, or eyes. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evalbation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. A detailed description of the Health Hazards and their consequences may be found in Linde's free safety booklet L-2035. You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Linde Division, Communications Depadment, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. FIRST AID IN CASE OF EMERGENCY -- Call for medical aid. Employ First Aid techniques recommended by the American Red Cross. IF BREATHING IS DIFFICULT give oxygen. Call a physician. IF NOT BREATHING, begin adificial respiration, preferably mouth- to-mouth. If no detectable pulse, begin external heart massage. Immediately call a physician. IN CASE OF EYE BURN call a physician. *NOTES TO PHYSICIAN: Acute -- Gases, fumes, and dusts may cause irritation to the eyes, lungs, nose, and throat. Some toxic gases associated with welding and related processes may cause pulmonary edema, asphyxiation, and death. Acute overexposure may include signs and symptoms such as watery eyes, nose and throat irritation, headache, dizziness, difficulty breathing, frequent coughing, or chest pains. Chronic -- Protracted inhalation of air contaminants may lead to their'accumulation in the lungs, a condition which may be seen as dense areas on chest x-rays. The severity of change is proportional to the length of exposure. The changes seen are not necessarily associated with symptoms or signs of reduced lung function or disease. In addition, the changes on x-rays may be caused by non-work related factors such as smoking, etc. Page 2 of 4 ~ PRODUCT: Acetylene L-4559-C ~- '-'~ May 1985 FLASH POINT ' J ' AUTOIGNITION ' .. .... (test method) -17.8°C (0°F) T.C.C. ~ TEMPERATURE FLAMMABLE LIMITS I LOWER 2.3% IUPPER 100% IN AIR, % by volume EXTINGUISHING MEDIA See paragraphs below. SPECIAL FIRE FIGHTING PROCEDURES Refer to CGA pamphlet SB-4, "Handling Acetylene Cylinders in Fire Situations." Evacuate all personnel from danger area. Immediately cool containers with water spray from maximum distance taking care not to extinguish flames. Remeve ignition sources if without risk. If flames are accidentally extinguished, explosive re-ignition may occur. Use self-contained breathing apparatus. Stop flow of gas if without risk while continuing cooling water spray. Remove all containers from area of fire if without risk. Allow fire to burn out. On-site fire brigades must comply with OSHA 29 CFR 1910.156. UNUSUAL FIRE AND EXPLOSION HAZARDS Extremely flammable gas. Forms explosive mixtures with air and oxidizing agents. Container may rupture due to heat of fire. Do not extinguish flames due to possibility of explosive re-ignition. Flammable vapors may spread from leak. Explosive atmospheres may linger. Before entering area, especially confined areas, check atmosphere with approved explosion meter. No pall of a container should be subjected to a temperature higher than 52 °C (approximately 125 o~. All containem are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. Contact with copper, silver, or mercury or their alloys or halogens can cause explosion. STABILITY CONDITIONS TO AVOID UNSTABLE STABLE Stable as shipped. Avoid use at pressures above 15 psig. X INCOMPATIBILITY (materials to avoid) Copper, silver, mercury or their alloys, oxidizing agents, acids, halogens, moisture. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition or burning may produce CO/CO2/H2. The welding and cutting process may form reaction products such as carbon monoxide and carbon dioxide. Other decomposition products of normal operation originate from the volatilization, reaction or oxidation of the material being worked. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID May Occur ] Will not Occur Elevated temperature and pressure and/or the presence of a catalyst. X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Forms explosive mixtures with air (See Section V). Immediately evacuate all pemonnel from danger area. Use self-contained bmathing apparatus where needed. Remove all sources of ignition if without risk. Reduce vapors with fog or fine water spray. Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area. Flammable gas may spread from leak. Before · entering area, expecially confined areas, check atmosphere with appropriate device. WASTE DIsPOsAL METHOD Prevent waste from contaminating surrounding environment. Keep pemonnel away. Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with Federal, State and local regulations. Page 3 o! 4 ~PRODU~CT: Acetylene L-4559-C May 1985 [~' ..*,i i'~ ?~' ~' ~;~;=,'~:~;:,~;~ :.:.,i ;~: .VIII..~SPECIAL~PROTECTION;INFORMATION ~?~,'.'.~.:~* RESPIRATORY PROTECTION (specify type) -- Use respirable fume respirator or air supplied respirator when working in confined space or where local exhaust or ventilation does not keep exposure below TLV. Select as per OSHA29 CFR1910.134. LOCAL EXHAUST -- Use enough ventilation, local exhaust or both, to keep the fumes and gases below TLV's in the worker's breathing zone and the general area. Train the worker to keep his head out of the fumes· MECHANICAL (general) ALWAYS WORK WITH ENOUGH VENTILATION VENTILATION SPECIAL Not applicable OTHER Depends on specific use conditions, and location. Use adequate ventilation or personal respiratory protection. See Section IX and OSHA29 CFR1910.252. . PROTECTIVE GLOVES ' " " Welding gloves recommended EYE PROTECTION -- Wear goggles with filter lens selected as per ANSI Z49.1. Provide protective screens and goggles, if necessary, to protect others. Select as per OSHA29 CFR1910.133. OTHER PROTECTIVE EQUIPMENT -- As needed, wear hand, head, and body protection which help to prevent injury from radiation, and sparks. See ANSI Z49.1. At a minimum this includes welder's gloves and protective goggles, and may include arm protectors, aprons, hats, shoulder protection, as well as substantial clothing. Train the worker not to touch live electrical~, arts. Fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being worked, the process, procedure and electrodes used. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being worked (such as paint, plating, or galvanizing), the __~. number of workers and the volume of the work area, the quality and amount of ventilation, the position of the worker's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample from inside the worker's helmet if worn or in the worker's breathing zone. See ANSI/AWS F1.1, available from the American Welding Society, 550 N.W. Le Jeune Rd., Miami, FL 33126. Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard Z49.1, "Safety In Welding And Cutting" published by the American Welding Society and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more details. For further safety and health information refer to Linde's free safety booklet L-2035. OTHER HANDLING AND STORAGE CONDITIONS Heat and sparks during use could be the source of ignition of combustible materials. Prevent fires. Refer to NFPA 51B "Cutting and Welding Processes" and NFPA 50 "Oxygen-Fuel Gas Systems." Use piping and equipment adequately designed to withstand pressures to be en~:ountered. Gas can cause rapid suffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. Never work on a pressurized system. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the. user's obligation to determine the conditions of safe use of the product. · GENERAL OFFICES :-... Union Carbide Corporation Union Carbide Canada Limited ~ UNION CARBIDE Linde Division Linde Division 39 Old Ridgebury Road 123 Eglinton Avenue East ~ ' Danbury, CT 06817-0001 Toronto, Ontario M4P I J3 Other offices in principal cities all over the world. · L-4559.C 85-0928 4/85 25M Lithographed in U.S.A. Page 4 of 4 MAI bHIAL tSAl-lr. I Y UAIA I -- Ju,y _ .. (Essentially limHlf IO U.S. Devilment of b~r Fo~ OSHA-20 . and ge~erally accepted iff Canada for inTonation pur~ses) Oo Not O~phcate Thi~ Form. Request an Original. I. PRODUCT IDENTIFICATION PRODUCT A-1C25 He'.,jm CHEMICAL Argon. Hehum-Carbon D~oxide mixture SYNONYMS Not ADDlicabte NAME ' FORMULA Ar. COz & He CHEMICAL Not Applicable FAMILY MOLECULAR Not Applicable WEIGHT TRADE NAME A-1025 Hehum M.,ture (This product is intended for electric welding use.) .......... ~AZARDOUS INGREDIENTS %h,s 5ec~'~ covers I~e ma~,~a~s fro~ ~,ch th~s pr~uct iS manufactured The fumes and gases ~r~uc~ during cutting w~th the nor~a~ u~e cf th,s ~rod~ct are-covere~ ~y Sect,ch VI The lerm "h~ardous" should be inter,rated as a term r~u~red a~d defln~ in OSHA 29 CFR 19~0.1Z~ and toes nol necessarily ~mpty ihe ex,stance of any h~ard. M~ERIAL (CAS NO.) Vol (~) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) ",' Helium (744~5g-~ · ' '... · ~ ...... . . " ~ Simple asphyxiant ~ · (None currently establish~) Argon (7~37-1) .~ (None ~ently establish~ .. .... -- .. . : '~.¢ '.~ ',.' ,'..,: .. ,-. :... . ,; · ".. ", Caren Dioxide (12~9) , ' ;' ""'-' '"'.'"'.'.- --' .'.. 2.5 ' 5~ ppm .- -.' (5~ ppm) ....... ,....,:'..'.. ~.,..~... '.:_ ,..:.... · ~- ,".'.;' *'.' '..'~"~:,.::;....-.'. L:'." ¥. .'.:.,'-: .:'. - :'~ '"""" : '" . '..:--'-'." .' .' ; .;;~"7,,: '. BOILING POINT, ~60 mm. Hg Not Applicabl~ FREEZING POINT Nol Applicable SPECIfiC GRAVITY (H~O, 1) Gas VAPOR PRESSURE AT 20=C. Gas SOLUBILITY I~ VAPO~ BENSITY (air = 1) 0.266 W~ER, ~ by wt. Neglibl~ PERCENT VOL~ILES E~POR~ION R~E Bf VOLUME 1~ (Butyl Ac'eraSe = 1) Not Applicable APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure. ~ IN CASE OF EMERGENCIES involving this material, fun~e~ information is available at all times: ~ In the USA 3~ -- 7~-~87 In Canada 514 -- ~5-5311 ~ . For routine information contact your l~al supplier Ur;,~n CarD'de requests the users cf th~s product to s~udy this Material Safety Data Sheet (MSDS) and become a~'are of prcc~ct h~arOs and salety'infcrmat~on. To ~romote sale use of Ibis product a user should (1) noti~ its employees, agents and contractors of the ~nforma~iOn on t~iS MSDS a2d any proddct h~ards and safety information. (2) furmsh this same information tO each of its = , _ 2:c.~uc'. =-~ {3~ 'e:~l s~ch c~s~cmers to ncLfv ',heir emp~cyees and c~s~cmer$ for the ~o.~:I cf UNION CARBIDE CORPORATION ~ LINDE DIVISION UNION ~RBIDE CANADA LIMITED ~ LINDE DIVISION Co~x":~b~ ~' 1~85 Umon Ca,=:de Cor~ration Page 1 ~,~ ~ .~::.... -,.. .... .....:~-~ IV. HF-..~LTH H'*,qT. ARD DATA ~ - ..- . . T~P, ESHOLD LIMII VALUE The A~GtH 1S5~-E5 re=ommer, ced limit for welding fume. nol orbed'isa classihed {NOC). is TL~ -Tvv~ s shoulc De us~ as a gu)d~ m th~ Co~'o) Ol heahh h~a'~S and not as fine lines belween safe a~d q~ = S,~- ...... Vi '~' ~= -'"~ ~"-~ '~"~,"~,'~"~ which mzv mc~'+) '~,~ TL','-~'/c. ~FEC~c OF OVE~:E~POSLI~E ~.ND E~~ c ,~ : ~ ~...~.:..~ '~;tr~ we;~'~ D ~ Cu~;~,C ma~' create one or mo'e ci the ioh,:~..-,, hea::~ FUI,~[S Lt;D 8A~E~ can be daqgero.us ~o y=ur health and may cause serious lung disease.' ELECTRIC SHOCK can kd1 you ARC RAYS can iruure eyes aqd burr: skin. NOISE can damage hearing. Th:s .cas mixtu,e is an asphyxia-,t. Moderale concentrations may cause headache, drowsiness, dizziness a~.d unconsciousness. O! oxy~C.r: can cause d~th. Ke~p your head ou~ of the fume-' Do not breathe fumes and gases cause3 by the pr~ess. Use enough veqldation, local exhaust. or both to keep fumes and gases from your breathing zone and the general area. The type and amount of fumes and gases depend on t~e ~uipmenl and supplies u~. Po~ibly dangerous materials may ~ found in fluxes, coatings, g~es. and metals. Get a Material Satety D~ta Sheet (MSDS) for eve~ material used. Air samples can ~ used to find out what respirato~ protection is needed. Do not touch live electrical pa~s. Wear correct ear. eye. and ~y proration. · ' ' ': ':' : ' Sho~ ~erm overexposure to lure~ may resutt in dis~mto~ such as di~iness, nausea, or d~ness or i~at~n of nose:throat, or eyes." MIXTURES: When ~o or more gases, or liquefi~ gases are mixed, their h~ardous progenies may ~mbine to create additional, unex~cted h~ards. Obtain and evaluate the safety information for each com~nent before you pr~uce the m~ture. Consult an Industrial Hygiemst, or other train~ person when you make your safety evaluation of the end pr~uct. Remember. gases and liquids . have pro~mes ~ich ~n ~u~ serious inju~ or death. : . . A detailed description of the HeAth H~rds and their consequents may ~ tound in Linde's Ir~ sale~ ~klet.'*'pre~ut~ns and ,. Safe Practices lot Electric Welding and Cuuing." L52-5~. You may obtain copies from your I~1 s~plier, or by writing to Union Ca,ida Co,ration. Linde Division. ~mmunications Depa~ment. 39.O!d Ridgebu~ Road. Danbu~. C~n~ficut, 0~17~1. :{ · ' R.ST AIO IN CASE OF EME. GENCY ~'Call'to~ ~icai aid. Employ nrst :Aid t~hnlqueS re~ed by the Amain Red *~" Cr~s. IF BREATHING IS DIFFICULT give Dx~en..Call a ph~ician. IN CASE OF ELECTRICAL SH~K di~nne~ and turn off ~er. IF NOT BREATHING. begin aqificial respiration, preferably mouth-t~mo~h. Il no detectable pulse, ~in e~ernal haan massage. Immedialely,~ll a physician. IN CASE OF ARC BURN call a ph~ician.. .. , ,., , 'NOTES TO PHYSICIAN: Acute -- Gases. fumes, and dusts may cause irritation Io the eyes. lungs, nose. and throat. ~me toxic gases ass~iat~ with ~etd[ng ~d ~etat~ pr~e~es may cause pulmona~ edema, asph~iation, and death. ~e overex~ure may include · , ' signs and symptoms such as wate~ eyes. nose and throat initation, headache, di~iness, difficulty breathing, frequent .Chronic -- Protracted inhalati~ of air contaminants may lead to lheir accumulation in"the lungs, a ~nd~ion ~ich may ~ seen · as ~ense areas on chest x-rays. The severity of c~nge ~ pro~nional to the length of ex~ure. T~ changes seen are not necessarily associated with symptoms or signs of reduced lung function or ~i~. In addition, ~e changes on x-ra~ may be ~used by non-work related factors such as smoking, etc, i Pa~e 2 o! z '~ ....:' -- ................... W .... AUTOIGNITIOt~ -~' ' -' ............................ ' FL~.SH POINT Not Applicable Not Apphcabte (test method) TEMPERATURE FLA~M'A, ELE LIMITS ~ LOWER Nm ~-' .... ~ UPPER E~:IlNGUISH~NG SF~CIAL FIRE FIGHTING PROCEDURES Evs;uate a~f personnel from danger 8re~. Immediately c~3~ cyhbdefs with ws[er spray from m~ximum d~stance until co;~amers away from hre area if w=thcut risk. Shut o~ tezk ~f ~:t~out risk. Arcs aqd spa'ks can ipmte combustibles Reler to America~ f4a:~cna~ Standard ZZg.1 "Safe~y in mfcrmat~gn durraB the use of welo~ng and athed proceCu'e5 UNUSUAL FIRE AND EXPLOSION HAZARDS G.~.~ rr,,~xtu~e cant, o: ca,ch fire. Container may ruplure due to heat o! fire· No part, of a con~aine, shou!d be subjected to e tempe-a~d,e hL:.her thar, 52'~0 lapprox~mately 125'-F). Most containers are provioed w~th a pressure relie! devIce designed to vent co~t=.nt.~ v,,her, they are exposed to elevaled temperature. .. "'"'.;:.~.;_;~,::/,.:;~.'"";; ': :'-".: ;:' .".:.,:'., · VI. REACTIVITY DATA -;:~:2:.'/,~_~;...'.' :" '. :~..! ~.~..:_~., '.-:~ · . o ..,- ,....~:;.=..:.' ..~.,~ : ....... . ............. . ............. -.~ ~ ~ ~.,.;.- , , . - .~. .... STABILITY : CONDITIONS TO AVOID "" ' "' ' ' ' ' '" ' ' '' ' ' "' ': .X withstand pressures to be encountered. Do not strike arc on cylinder. Do not ground cylinder. See Section IX. · INCOMPATIBILITY (materials t0~void) ., -' .' ': '.'..'.-': '~'-'~. "::~:' '.:'~ :~ .-'.-',.-":,.' ':i:: :.' ~. '. :' ': '~,_: :' :-' ' "'"-.:~' ."" None currently known. '~ .' · '. ....... · .. , .~ .:'.. -- . . . .. ;- .: : -~,. - ......' = · ...... .: ." . - .. · , -.,. ,.: . , ': ::. ., . ' - HAZARDOUS DECOMPOSITION PRODUCTS , "rhe arc process may fo. rm gaseous reaction products Such as Carbon Monoxide and Carbon Dioxide. Ozone and Nitrogen Oxides · . ~'~:. ':'? may be formed by the radiation from the arc. See Section IV. Other decomposition.products of normal operation originate from the . . - · volatilization,' reaction or oxidation of the material being worked. .. ~' -, . '"'. ', - .,. '. · *' HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID iVl~y Occur Will not Occur None currently known. -- x STEPS TO BE ~AKEN IF MATERIAL IS RELEASED OR SPI~ED ' This gas mixture ~ an ~ph~lant. Evacuate all ~rson~l from da~ger area. Use self<ontained breathing ~paratus ~ere needed. Shut off cylinder il w~hout risk. Ventilate ~ea of leak or move cylinder to well-ventilated area. Test area. es~cially ~nfined areas. for suff~cienl oxygen ~tent prior ~ ~rmi~ing re~nt~ of ~rsonnel. WASTE DISPOSAL METHOD: Slowly release into atm~here. Discard any pr~uct, residue, disposable container or liner in an environmentally acceptable manner in full compliance with F~eraL State and I~al regulations. ) P=,ge 3 of 4 Jul). 19F..5 · - - ' -.: --., VIII.~ECIALFROTECTIONINFORMATI - RESPIRaTORy PROTECTION (specify' lyp,) ~ Use respff~b~e fume respirator or air suppi~ed r~x,~a'~r w~en werkmc in . "[ L'v' 5 ;n the ~,,'o;~,:e"s D:es:hin~ rome and the genera., area '}rat,'-, the v,.?.,.e: tc ~.ee.'- t-,s h_cam C.u; r,f I',*.ECHANICAL (general) ALWAYS WORK WITH ENOUGH VEi'C{'ILATION YENTILATION SPECIAL -- A','o~O us;r,~ elect;lc arcs in the presence ol chl~tmale0 hyc,'~-tr-rb:n va?ors -- H~.ch;y ph~s.3e-,e may be pro,iced. Avoid arc operalions on pans v,.mth phosphate res,0ue., (em,-~,,st. cleanm, g pre,sa:at!OhS) -- H~ghl) toxic phosphine m~), be procLJced.. OTHERDe;:,eqds on s,..,e_~,:c use conCmr.,ns. ~nd location. Usc aoe,,?,uat£ ,,.ent~;r--bon or pe:sonai resp'ra;ory p,~terl,~.n. See Sectior~ IX anO OSHA29 C:R1910.252. PROTECTIVE GLOVES Welding gloves recommended EYE PROTECi'ION -- Wee; a helmet o: use a face shielo v, qh a filter lens selected as per ANSI Z4~ 1. Prov,oe protectiYe screens and flash .co.:gles. if necessary, to protect others. Select as per OSHA2.9 CFR191D.133. I, OTHER PROTECTIVE EOUIPM, ENT-- As needed, wear hand. head. anr~ body protection which heip to prevent injury from radiation, sparks, and electrical shock. See ANSI Z49.1. At a minimum this includes welder's gloves and a protective face shield, and may include .arm protectors, aprons, hats. shoulder protection, as well as dark substantial clothing. Train the worker not to touch live electrical parts. .. ',.. Fumes and oases cannot be'classified simp{Y.'{'he composition and quantity ol both are dependen! upon the metal being worked. ' the process, procedure and electrodes used. Other conditions which also influence the composition and quant,fy o! the fumes and gases to which workers may be exposed include: coatings on the metal being worked (such as paint, plating, or galvanizing), the · number of workers and the volume of the work area, the ciuahty and amount of ventilation, the position of the worker's head with . respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon, vapors · :. One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an v Read and understand the manufacturer's instrUctiohs and "" '" "' " ":' . · the precautionary label on the product. See American National Standard · -:.'Z49.1, "Safety In Welding And Cutting" published by the American Welding Society and OSHA Publication 2206 (29CFR1910), U.S. · :' Government Printing Off,ce. Washington. D.C. 20402 for more details. For turther satety and health information refer to Linde's tree safety booklet. "Precautions and Safe Practices for Electric Welding and Cutting." L52-529. ' OTHER HANDLING AND STORAGE CONDITIONS Arcs end sparks during use could be the source o! ignition of combustible materials. Prevent fires· Refer to NFPA 51B "Cutting and Welding Processes," High pressure gas mixture· Use piping and equipment adequately designed .to withstand pressures to be encountered. Gas can cause rapid suffocation clue to oxygen cleficiency. Store and use with adequate "ventilation. Close valve v,+~en not in use and when empty: Do not strike arc on cylinder· The defe~ produced by an arc burn could lead to cylinder ruplure. Do not ground cylinder. Never work on a pressurized system. The opinions expressed herein are those of qualified experts within Union Carbide· ..We believe that the information contained herein ~ is current as of the clare of this Material Salary Data Sheet. Since the use of this information and these opinions and the conditions · 'of use of the product are not within the control of Union Carbide. it is the user's*obligation to determine the conditions of safe use of the product.. GENERAL OFFICES ~ u~to,~ ~a~p~ Linde D~vis,on Linde Dwision 39 OIc R~ope.'c'u,y Road 123 Eohr. ton Ave'~ue East Other offices in principal cilies all over Ihe world. L--4713-A ES-O92E 7/E5 2M L,!hoGra;~hed in U.S.A. Page 4 of 4 M/ ERIAL J IEET L-46.8-A SAFETY DATA September 1985 An explanation of the terms used herein may be found in OSHA 29 CFR 1910.1£00, available from OSHA regional or area offices. (Essentially similar to U.S. Department of Labor Form OSHA-20 ' . ... end generally accepted In Canada for Information purposes) Do Not Duplicate This Form. Request an Original. PRODUCT Oxygen CHEMICAL Oxygen SYNONYMS Not applicable NAME FORMULA O~ CHEMICAL .FAUILY Nol applicable MOLECULAR 32.00 WEIGHT TRADE NAME Oxygen For mixtures of this product request the respective component Material Safety Data Sheets. See Section IX. MATERIAL (CAS NO.) Wt (°/0) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Oxygen (7782-44-7) 100 No~e currently established (None currently established) BOLLING POINT, 760 mm. Hg - 183°C (-297.4°F} FREEZING POINT -218.4°C (-361.1°F) SPECIFIC GRAVITY (H;© = 1) Gas VAPOR PRESSURE AT 20°C. Gas VAPOR DENSITY (air'= 1) 1.105 ~ 25°C SOLUBILITY IN WATER, % by wt. Negligible PERCENT VOLATILES EVAPORATION RATE BY VOLUME 100 (Butyl Acetate = 1) Not applicable APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure. ............ . ........ , ~, :;,, ....EMERGENCY PHONE NUMBER ~,~: ~', ~ .... ..,' L~ ". ~' " :': ' ' ' ~ ' '.. '. '. ; -' ,: . ' : ..: ..... : ~I"L'*:; IN CASE OF EMERGENCIES involving this material, fuHher information is available at all times: In the USA 304 ~ 744-3487 In Canada 514 ~ 645-5311 . For routine information contact your local supplier Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish, this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION U LINDE DIVISION UNION CARBIDE CANADA LIMITED ~ LINDE DIVISION Copyright ~ 1985 Union Carbide Corporation Page I of 4 PRODUCT: Oxygen L-4638-A ~ September 1985 THRESHOLD LIMIT VALUE: None currently established. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING -- No evidence of adverse effects from available information. SKIN ABSORPTION -- No evidence of adverse effects from available information. ~NHALATION -- Breathing 80% or more oxygen at atmospheric pressure for more than a few hours may cause nasal stuffiness, cough, sore throat, chest pain and breathing difficulty. Breathing oxygen at higher pressure increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause lung damage and also central nervous system effects resulting in dizziness~ poor coordination, tingling sensation, visual and hearing disturbances, muscular twitching, unconsciousness and convulsions. Breathing oxygen under pressure may cause prolongation of adaptation to darkness and reduced peripheral vision. SKIN CONTACT -- No evidence of adverse effects from available information. EYE CONTACT -- No evidence of adverse effects from available information. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: See "Notes to Physician." MEDICAL CONDITIONS AGGRAVATED, BY OVEREXPOSURE: See "Notes to Physician." SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING -- This product is a gas at normal temperature and pressure. SKIN -- No emergency care anticipated. INHALATION -- RemOVe to fresh air. Give artificial respiration if not breathing. Keep victim warm and at rest. Call a phYSician. EYES -- No emergency care anticipated. NOTES 70 PHYSICIAN: Supportive treatment should include immediate sedation, anti-convulsive therapy if needed, and rest. Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, increases the susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate that vitamin E deficiency may increase susceptibility to oxygen toxicity. Airway obstruction during high oxygen tension may cause alveolar collapse following absorption of the oxygen. Similarly, occlusion of the eustachian tubes may cause retraction of the eardrum and obstruction of the Paranasal sinuses may produce "vacuum-type" headache. Newborn premature infants exposed to high oxygen concentrations may suffer delayed retinal damage which can progress to retinal detachment and blindness (retrolental fibroplasia). Retinal damage can also occur in adults exposed to 100O/o oxygen under greater than atmospheric pressure, particularly in individuals whose retinal circulation has been previously compromised. All individuals exposed for long periods to oxygen at high pressure and all who exhibit overt oxygen toxicitY should have ophthalmologic examinations. WHEN USED IN WELDING AND CUTTING: Read and understand the manufacturer's instructions and the precautionary label on the product. See American Standard Z49.1 "Safety In Welding and Cutting" published by the American Welding Society, P.O. Box 351040, Miami, Florida 33135 and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail. For further SAFETY AND HEALTH information, refer to Linde's free publication, L-52-529, "Precautions and Safe Practices for ElectriC Welding and Cutting", as well as L-2035, "Precautions and Safe Practices for Gas Welding, Cutting, and Heating." You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Linde Division, Communications Department, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. NOTE: Suitability for use as a component in underwater breathing gas mixtures is to be determined by or under the suPervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the effects, methods, frequency and duration of use, hazards, side effects and precautions to be taken. Page 2 of 4 PRODUCT: Oxygen L-4638-A September 1985 FLASH POINT AUTOIGNITiON Not applicable Not applicable (test method) ' TEMPERATURE FLAMMABLE LIMITS I LOWER Not applicable I UPPER Not applicable IN AIR, % by volume I I EXTINGUISHING MEDIA: Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (i.e. safety shower) is the preferred extinguishing media for clothing fires. SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately cool containers with water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxidizing agent, vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion. Container may rupture due tO heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125°F). Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. Smoking, flames and electric sparks in the presence of enriched oxygen atmospheres are potential explosion .hazards. STABILITY CONDITIONS TO AVOID: See Section IX. I UNSTABLE I STABLEx INCOMPATIBILITY (materials to avoid): Combustible materials, asphalt, flammable materials, especially oils and greases. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: None currently known. May Occur Will not Occur X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area. Remove all flammable materials from vicinity. Oxygen must never be permitted to strike an oily surface, greasy clothes or other combustible material. WASTE DISPOSAL METHOD: Slowly release into atmosphere, in an open, outdoors area. Remove all flammable materials from vicinity. Page 3 of 4 PRODUCT: Oxygen L-4638-A September 1985 ,~ i *. ~'..* .,-~ '~;..~', ~ ~4 ,[" =~'.2& ,.: '~ VIII. SPECIAL' PRQTECTION INFORMATION ~;~ ,.'~ ~ ;~,.~'~,;.~:=~ ~ ~'~j ~.~*~. A~; ~* ,~ RESPIRATORY PROTECTION (specify type): Not required. LOCAL EXHAUST -- Not applicable. MECHANICAL (general) -- Acceptable. VENTILATION SPECIAL -- Not applicable. OTHER -- Not applicable. PROTECTIVE GLOVES: Preferred for cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. WARNING: High' pressure gas. Vigorously accelerates combustion. Avoid contact with oils, greases and other flammable materials. Never use manifolds for oxygen cylinders unless specifically designed for such use. Use only with equipment conditioned for oxygen service. Use piping and equipment adequately designed to withstand pressures to be encountered. Protect container against physical damage. Isolate from combustible gas installations and combustible materials by adequate distance or by gas-tight, fire-resistive barriers. Protect against over-heating. Never use an oxygen jet for cleaning purposes of any sort, especially clothing, as it increases the likelihood --.~ of an engulfing fire. Note: Reverse flow into cylinder may cause rupture. Use a check valve or other protective apparatus in any line or piping from the cylinder to prevent reverse flow. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death, Re sure to read and understand all labels and other instructions supplied with all containers of this product. NOTE: Compatibility with plastics should be confirmed prior to use. For safety information on general handling of compressed gas cylinders, obtain a copy of pamphlet P. 1, "Safe Handling of Compressed Gases in Containers" from the Compressed Gas Association, Inc., 1235 Jefferson Davis Highway, Arlington, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then rePair the leak. Never lubricate oxygen valves, regulators, etc., with any combustible substance. The oPinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. o .c s :.:... IN THE USA: IN CANADA: ~ UN~ONCAR~DE Union Carbide Corporation Union Carbide Canada Limited ' Linde Division Linde Division 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P 1J3 Other offices in principal cities all' over the world. L-4638-A 85-0928 9/85 45M Lithographed in U.S.A. Page 4 of 4