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WESTEJiN P.O. BOX 11881, SANTA ANA, CALIFORNIA 92711 EXTERMINATOR COMPANY 1732 KAISER AVENUE, IRVINE, CALIFORNIA 92614 (714) 261-2440 (800) 698-2440 FAX (714) 474-7767 Since 1921 April 20, 1998 Ralph Huey 2130 G St. Bakersfield CA 93301 Dear Ralph Huey Re: Our annual update I have reviewed the inventory for: 810 Brundage Ln in Bakersfield and this office is still under the 55 gallons for a liquid, 500 pounds ora solid, 200 cubic feet for gas, or TPQ. for any hazardoUs material. If you have any questions, please call me at (800) 698-2440. Thank you, · THE WEST'S LARGEST FAMILY-OWNED TERMITE & PEST CONTROL COMPANY ' WESTERN ' P.O. BOX 11881, SANTA ANA, CALIFORNIA 92711 J~-:X~Jm~--RJVJIJlI~',~J'~OR COJVI~J,~,JlI~'~/ 1732 ~iSER AVENUE, IRVINE, CALIFORNIA 92614 ~ ..... ~ ~ (714) 261-2440 {800) 698-2440 F~ (714} 474-7767 ~ ~ (~ ?~'J~/Z '~' ~ Since 1921 May 2, 1997 Ralph Huey 2130 G St. Bakersfield CA 93301 Dear Ralph Huey Re: Our annual update I have reviewed the inventory for: 810 Brundage Ln in Bakersfield andthis office is still under the 55 gallons for a liquid, 500 pounds of a solid, 200 cubic feet for gas, or TPQ. for any hazardous material. Except for the Name change I sent in on 4/8/96 the Hazardous Materials Management Plan I sent ~1'- ....... I ~ ~ 99~ ~.. ~'1-;11 .... I;,4 If you have any questions, please call me at (800) 698-2440. Thank you, Keith Willingham Safety. Manager Our 75tho THE WEST'S LARGEST FAMILY-OWNED TERMITE & PEST CONTROL COMPANY ' ' ~ 1732 KAISER AVENUE, IRVINE, CALIFORNIA, 92~14 EXTERMINATOR COMPANY (714) 261-2440 (800) 698-2440 FAX (714) 474-7767 Since 1921 April 8, 1996 Ralph Huey 2130 G St. Bakersfield CA 93301 Dear Ralph Huey Re: Our annual update I have reviewed the inventory for: 810 Brundage Ln in Bakersfield and this office is still under the 55 gallons for a liquid, 500 pounds of a solid, 200 cubic feet for gas, or TPQ. for any hazardous material. Except for the following, the Hazardous Materials Management Plan I sent on February 15, 1993 is still valid. Emergency Notification: please change "1" from Mike Lawton t° Mike Cahpman. Phones numbers are the same. If you have any questions, please call me at (800) 698-2440. Thank you, Keith Willingham Safety Manager THE WEST'S LARGEST FAMILY-OWNED TERMITE & PEST CONTROL COMPANY WESTERN RO. BOX '11881, SANTA ANA, CALIFORNIA 92711 :XTERMINATOR COMPANY t732 KAISER AVENUE, IRVINE, CALIFORNIA, 92714 (714)26t-2440 Since 1921 Bakersfield CA 93301 H4~. M4~ DIE Dear Ralph Huey I have reviewed the office's inventories for - 810 Brundage Ln in Bakersfield, and 510 W Ridgecrest B1 in Ridgecrest and both offices are still under the 55 gallons, 500 pounds for solids, 200 cubic feet for gases, or a material at or above TPQ. The Hazardous Materials Management Plan I sent in last year (February 15, 1993) are still valid. If you have any questions, please call me at (800) 698-2440 Thank you Keith Willingham THE WEST'S LARGEST FAMILY-OWNED TERMITE & PEST CONTROL COMPANY - SINCE 1921 WESTERN ~ P.O. BOX 11881, SANTA ANA, CALIFORNIA 92711 EXTERMINATOR COMPANY t732 KAISER AVENUE, IRVINE, CALIFORNIA, 92714 (714)261-2440 Since 1921 Ralph Huey 2130 G St tE8 1 8 993 Bakersfield CA 93301 Dear Ralph Huey I have enclosed the Hazardous Materials Management Plan for our building' s at: 810 Brundage Ln in Bakersfield and 510 W Ridgecrest B1 in Ridgecrest I have reviewed the office's inventories and neither office has quantities of a hazardous material at or above 55 gallons, 500 pounds for solids, 200 cubic feet for gases, or at or above TPQ. Although it was not required, I completed the entire management plan. If you have any questions, please call me at (800) 698-2440. Thank you Keith Willingham THE WEST'S LARGEST TERMITE & PEST CONTROL COMPANY - SINCE '192'1 " Bakersfield Fire Dept. Hazardous Materials Division 'L~ 2130 "G" Street B~kersfield, CA. 93301 HAZARDOUS MATERIALS MANAGEMENT PLAN INSTRUCTIONS: 1. To avoid further action, return this form within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA LOCATION: ~/0 ffrzb,,v,,)"'_2..~. /-~ '' : '-.~ ..... MAILING ADDRESS: CITY: /~/~'~' ~f~./~ STATE' ~7'--} ZIP: 9~.~o~ PHONE:~'~.~..) DUN & BRADSTREET NUMBER: SIC CODE: PRIMARY ACTIVITY: ~'~ $-~ ~ ~,~/,~) OWNER: fl-~,, 4~2'~ ~" '" MAILING ADDRESS: /7~ ~ f:~r~ ~o ~, ~ SECTION 2: EMERGENCY NOTIFICATION: CONTACT TITLEBUS. PHONE 24 HR. PHONE Bakersfield Fire Dept. Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 3: TRAINING: NUMBER OF EMPLOYEES: /? MATERIAL SAFETY DATA SHEETS ON FILE: /V'c~' BRIEF SUMMARY OF TRAINING PROGRAM: SECTION 4: EXEMPTION REQUEST: I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE · REPORTING REQUIREMENTS OF CHAPTER 6.95 OF THE "CALIFORNIA HEALTH & SAFETY CODE" FOR THE FOLLOWING REASONS: WE DO NOT HANDLE HAZARDOUS MATERIALS. /X WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT'NO TIMEEXCEED THE MINIMUM REPORTING QUANTITIES. OTHER (SPECIFY REASON) SECTION 5:' CERTIFICATION: I, - ~e,~ ('~'///)~ ~'~- CERTIFY THAT THE ABOVE INFOR- MATION IS ACCURATE. I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIV. 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT INACCURATE INFORMATION CONSTITUTES PERJURY. SIGNATURE ~ TITLE DATE FD1590 Bakersfield Fire Dept. Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN Facility Unit Name: SECTION 6: NOTIFICATION AND EVACUATION PROCEDURES: A. AGENCY NOTIFICATION PROCEDURES: B. EMPLOYEE NOTIFICATION AND EVACUATION: O. PUBLIC EVACUATION: D, EMERGENCY MEDICAL PLAN' B~ersfield Fire Dept.~ H~z~rdous M~teri~ls Division HAZARDOUS MATERIALS MANAGEMENT PI.AN SECTION 7: MITIGATION, PREVENTION AND ABATEMENT PLAN: A. RELEASE PREVENTION STEPS: pi/ ITFu,~2 ,~;;.))f)'~L~s ~,,~ B. RELEASE CONTAINMENT AND/OR MINIMIZATION' C CLEAN-UP PROCEDURES: , SECTION 8: UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FACILITY): NATURAL GAS/PROPANE: -'C°u~l' ~e~) ~'~'~ ~£ ~rt~'°'~ ~:/d~? WATER: ~'~ ~/ ~¢ ~:/~ic~ / SPECIAL: LOCK BOX: YES/NO IF YES, LOCATION: SECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABILITY: A. PRIVATE FIRE PROTECTION: B. WATER AVAILABILITY (FIRE HYDRANT)' 4. FI Branch 10 810 Brundage Lane Bakersfield, CA 93304 4th Street N Warehouse Chemical S Storage · o Spill K'~ ~ - Fire Extinguisher [] - Main Gas Shut off ~ [] - Main Water Shut off Rest © r°°m1 ~ - Fire Hidrant Office © - Electric Meter ~ [] Brundage Lane EXTERMINATOR COMPANY 4732 KAiSEr^VENUE, ~W~~,~.7~4~:.7~ Since 1921 [ By Ralph Huey 2130 G St. Bakersfield, CA 93301 Dear Ralph Huey, We have an office in Bakersfield & Ridgecrest at 810 Brundage Ln., Bakersfield, CA 93304 and 510 W. Ridgecrest Blvd., Ridgecrest, CA 93555. Please send me, at the address below, forms and any other information on Division 20, Chapter 6.95 Hazardous Materials Release Response Plans and Inventory. Because of the Iow amounts of hazardous materials we store at our facility, we may not need to submit a complete inventory or business plan. To help me in submitting any information you need, please let me know the following: 1) We want an inventory of any hazardous material 2) We want an inventory of any hazardous material stored at a.~y one time thatjs in exc.ess t of 50 gallons, 500 pounds or 200 cubic feet Y'"' r,~r,~(,.~ ~~fc&,'~,~.)-- 3) We want an inventory of any hazardous material that is stored in total for a year in excess of 50 gallons, 500 pounds or 200 cubic feet __ (800) t398-2440 1732 Kaiser Avenue Irvine, CA 92714 THE WEST'S LARGEST TERMITE & PEST CONTROL COMPANY - SINCE t921 04/14/92 WESTERN EXTERMINATOR CO 215-000-00059 P 1 Overall Site with 1 Fac. Unit General Information I Location: 810 BRUNDAGE LN Map: 103 Hazard: High I Community: BAKERSFIELD STATION 06 Grid: 31D F/U: 1AOV: 0.0 Contact Name Title Business Phone ~ 24-Hour Phoneq GUY F REEVES (805) 327-0949 xI (805) 871-3483! JAMES D WINFREY (805) 327-0949 x (805) 366-9723 / Administrative Data Mail Addrs: 810 BRUNDAGE LN D&B Number: City: BAKERSFIELD State: CA Zip: 93304- Comm Code: 215-006 BAKERSFIELD STATION 06 SIC Code: Owner: WESTERN EXTERMINATOR Phone: (805) 327 - 0949 Address: 810 BRUNDAGE LN State: CA City: BAKERSFIELD Zip: 93304- Summary 04/14/92 WESTERN EXTERMINATOR CO 215-000-000598 Page 2 0.2 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-~l~_VIKANE Gas 475 Extreme ~ ~F~e, Pressure, Immed Hlth, Delay Hlth FT3 CAS #: 26~9~8 Trade Secret: No / Form: Gas Type~:~J?~e Days: 365 Use: OTHER/ -- Daily Max FT3 D~!~ Average FT3 ~ An~a~ ~ount FT3 I oo o.oo ~ stOrage I Pres. s~/-~e'~~~ Location - PORT. PRESS. CYLINDER~A-b~9~~ ~Ambient SE CORNE~ OF WAREHOUSE ' " ......... ~' .~ , MCP ~List - Conc ..-1 ...... ' Components 99'~% ~Sulfuryl Fluoride ' - Notes .... 02-002 DURSBAN TC Liquid 200 High · Fire, Reactive, Immed Hlth GAL CAS #: 2921-88-21 Trade Secret: No Form: Liquid TYpe: Mixture Days: 365 Use: PESTICIDE Daily Max GALI Daily Average GAL ----~ Annual Amount GAL 200 ~ 20.00 200.00 StorageIIPress T Temp Location PLASTIC CONTAINER IAmbient/AmbientlSE CORNER OF WAREHOUSE -- Conc Components I MCP iList 42.0% IChlorpYrifos High. I 9.2% [Xylene, Mixed ModerateI 02-003 BAYBON 2% BAIT Solid 10 Unrated · Immed Hlth LBS CAS #: 11-42-6 Trade Secret: No Form: Solid TyPe: Mixture Days: 365 Use: INSECTICIDE Daily Max LBSI Daily Average LBS I Annual Amount LBS 10 i 5.00 20.00 StorageI~Press T Temp Location PLASTIC CONTAINER Iambient]AmbientlSE CORNER OF WAREHOUSE -- Conc ~ Components ~ MCP ~List 04/14/92 WESTERN EXTERMINATOR CO 215-000-000598 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in.Reference Number Order .02-004 AVITROL Solid 10 Moderate · Immed Hlth LBS CAS #: 504-24-5 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: PESTICIDE Daily Max LBSI Daily Average LBS [ Annual Amount LBS 10 ~ 5.00 10.00 Storage Press T Temp~ Location BOX Ambient~AmbientlSE CORNER OF WAREHOUSE -- Conc~ Components . MCP List 0.5% 14-Aminopyridine Moderate EPA 02-005 S~VIN SL Liquid 10 Moderate · F~r~ Immed Hlth GAL CAS #: 63~--2~~Trade Secret: No Form: Liquid Type: Mi~'JUse: I~ -- Daily Max GAL ~ Da~j_~l,y~ ~A~__~---q-- Annual Amount GAL 10 ~ / ' 5.00 ~ 40.00 ~ S t~r~ e~/~ P re's~/T T emp ' ~~~ . y~C~ONTAINER IAmbientlAmbient SE CORNER OF WAREHOUS'~ -- Conc Components MCP List 41.2% ICarbaryl ModerateI 02-006 DURSBAN LO Liquid 3 High · Fire, Reactive, Immed Hlth, Delay Hlth GAL CAS #: 2921-88-2 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: INSECTICIDE Daily Max GALI Daily Average GAL I Annual Amount GAL 3 I 1.00 3.00 Storage~~Press T Temp Location PLASTIC CONTAINER IAmbient~AmbientlSE CORNER OF WAREHOUSE -- Conc Components MCP List 41.5% IChlorpyrifos IHigh I 04/14/92 WESTERN EXTERMINATOR CO 215-000-000598 Page 4 02 = Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-007 DURSBAN 50W Solid 50 High · Reactive, Delay Hlth LBS CAS #: 2921-88-2 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: INSECTICIDE Daily Max LBSI Daily Average LBS I Annual Amount LBS 50 ~ 20.00 50.00 Storage Press T TempI Location BAG Ambient]AmbientlSE CORNER OF WAREHOUSE -- Conc Components MCP List 50.0% {Chlorpyrifos ' High I 02-008 DURSBAN ME Liquid 2 High · ReactiVe GAL CAS #: 2921-88-2 Trade Secret:, No Form: Liquid Type: Mixture Days: 365 ~ Use: INSECTICIDE Daily Max GALI Daily Average GAL [ Annual Amount GAL 2 ~ 1.00 3.00 Storage Press T TempI Location ~ PLASTIC CONTAINER Ambient~AmbientlSE CORNER OF WAREHOUSE -- Conc Components MCP List 11.7% Ichlorpyrifos IHigh I 02-009 DEMON WP Solid 20 Low · Reactive LBS CAS #: 52315-07-8 Trade Secret: No Form: Solid Type: Mixture DayS: 365 Use: INSECTICIDE Daily Max LBSI Daily Average LBS ] Annual Amount LBS 20 ~ 10.00_ .40.00 StorageIIPress T Temp ' Location BAG IAmbient~AmbientlSE CORNER OF WAREHOUSE -- Conc Components I MCP List 40.0% ICypermethrin 04/14/92 WESTERN EXTERMINATOR CO 215-000-000598 Page 5 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Nu~er Order 02-010 DRIONE Solid 10 Moderate ~ Reactive LBS CAS #: 8003-34-7 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: PESTICIDE Daily Max LBS ~ Daily Average LBS ? Annual Amount LBS 10I 10.00! 10.00 StorageI~Press T Temp Location PLASTIC CONTAINER I Ambient~AmbientlSE CORNER OF WARHOUSE -- Conc Components MCP .... List 1'0% IPyrethr~n IMinimal I 10.0% Piperonyl Butoxide Moderate 40.0% Amorphous Silicon Minimal 02-011 PT 270 DURSBAN Liquid 8 High ~ Pressure, Reactive, Immed Hlth, Delay Hlth GAL CAS #: 71-55-6 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: AEROSOL/INFLATION Daily Max GAL Daily Average GAL Annual Amount GAL Storage Press T TempI Location PORT. PRESS~ CYLINDER Above ~AmbientlSE CORNER OF WAREHOUSE -- Conc · Components MCP List 0.5% IChlorpyrifos High I 04/14/92 WESTERN EXTERMINATOR CO 215-000-000598 Page 6 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-012 PT 585 ROTENONE Liquid 3 Moderate · Pressure, Delay Hlth GAL CAS #: 8003-34-7 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: AEROSOL/INFLATION Daily Max GALI Daily Average GAL I Annual Amount GAL 3 ~ 2.00 5.00 Storage~ Press T Temp~ Location PORT. PRESS. CYLINDER Iabove IAmbientlSE CORNER OF WAREHOUSE --ConsI Components MCP iLls 0.5% Carbaryl Moderate t 0.1% Rotenone Moderate 0.5% Pyrethrin Minimal 0.2% Piperonyl Butoxide Moderate 02-013 PT 565 PYRETHRUM Liquid 3 Moderate · Reactive GAL CAS #: 71-55-6 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: AEROSOL/INFLATION Daily Max GALI Daily Average GAL I Annual Amount~ GAL -- 3 I 2.00 5.00 StorageI Press I TempI Location PORT. PRESS. CYLINDER IAbove ~AmbientlSE CORNER OF WAREHOUSE -- Conc Components ~ MCP ---~List 0.5% IPyrethrin Minimal I 1.0% IPiperonyl Butoxide ModerateI 04/14/92 WESTERN EXTE~INATOR CO 215-000-000598 Page 7 02 - Fixed Containers on Site Hazmat Inventory Detail in,Reference Number Order 02-014 PURGE III Liquid 50 Moderate · Pressure, Delay Hlth GAL CAS #: 64742-48-9 Trade Secret: No Form: Liquid TYpe: Mixture Days: 365 Use: AEROSOL/INFLATION Daily Max GAL I Daily Average GAL --~-- Annual Amount GAL 50 ~ 15.00 100.00 Storage I Press I Temp I Location PORT. PRESS. CYLINDER Above /~bient SE CORNER OF WAREHOUSE -- Conc' Components MCP List 0'9% IPyrethrin IMinimal I 1.9% IPiperonyl Butoxide Moderate 13.1% IPetroleum Distillate Moderate 02-015 FICAM W Solid 5 Low ' · Delay Hlth LBS CAS #: 22781-23-3 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: INSECTICIDE Daily Max LBS i Daily Average LBS T Annual Amount LBS 5I 3.00! 5.00 StorageiIPress T Temp Location BAG IAmbient~AmbientlSE CORNER OF WAREHOUSE -- Conc Components MCP List 76.0% IBendiocarb .CllH13NO4. ILow I 02-016 FICAM D Solid 20 Low · Delay-Hlth LBS CAS #: 22781-23-3 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: PESTICIDE Daily Max LBSI Daily Average LBS I Annual Amount LBS -- 20 I 10.00 50.00 Storage Press T TempI Location PLASTIC CONTAINER AmbientlAmbientlSE CORNER OF WAREHOUSE - Conc Components MCP List 1.0% IBendiocarb .CllH13NO4. ILow I 04/14/92 WESTERN EXTERMINATOR CO 215-000-000598 Page 8 02 -.Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-017 PT 3.6.10 PYRETHRUM Liquid 3 Moderate ~ Pressure GAL CAS #: 71-55-6 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: AEROSOL/INFLATION Daily Max GALI Daily Average GAL I Annual Amount GAL -- 3 ~ 2.00 5.00 Storage Press T Temp~ Location PORT. PRESS. CYLINDER Above ~AmbientlSE CORNER OF WAREHOUSE -- Conc Components MCP iLiSt 1.0% IPyrethrin Minimal I 2.0% Piperonyl Butoxide Moderate 02-018 METH-O-GAS Gas 320 Extreme ~ Fire, Pressure, Reactive, .Immed Hlth FT3 CAS #: 74-83-9 Trade Secret: No Form: Gas Type: Mixture Days: 365 Use: OTHER Daily Max FT3I Daily Average FT3 I · Annual Amount FT3 320 ~ 100.00 320.00 Storage Press T Temp~ Location PORT. PRESS. CYLINDER Above ~AmbientlSE CORNER OF WAREHOUSE -- Conc I Components MCPIIList 0.2% Methyl Chloride Extreme 99.5%Methyl Bromide (EPA) Extreme IEPA 0.2% Dimethyl Ether Moderate 04/14/92 .WESTERN EXTERMINATOR CO 215-000-000598 Page 9 O0 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation EMPLOYEES WITHIN IMMEDIATE OR DETACHED WAREHOUSE STRUCTURE, WILL BE NOTIFIED OF FIRE BY VERBALLY SAYING "FIRE, FIRE, FIRE"! AND ARE INSTRUCTED TO MEET AT FRONT SIDEWALK UNDER COMPANY SIGN. O <3> Public Notif./Evacuation OWNER OF STRUCTURE ON WEST AND EAST SIDE OF BUILDING WILL BE PERSONALLy NOTIFIED OF OCCURANCES DURING REGULAR WORKING HOURS. <4> Emergency Medical Plan VALLEY INDUSTRIAL 2501 G STREET BAKERSFIELD, CA. (805) 327-2225 04/14/92 WESTERN EXTERMINATOR CO 215-000-000598 Page 10 00 - Overall Site <E> Mitigation/Prevent/Abatemt <l>~Release Prevention BULK OF OUR MATERIALS ARE WETTABLE POWDERS AND AERSOLS. THERE ARE NO MORE THAN 25- 1 GALLON CONTAINERS OF LIQUID MATERIALS IN OUR WAREHOUSE AT ANY GIVEN TIME. ANY SPILL ON OUR FLOOR PRESENTS ABSOLUTELY NO HAZARD TO CLEAN UP. ABSORBENT liS KEPT AVAILABLE IN THE WAREHOUSE TO CLEAN UP ANY SPILLAGE THAT MAY OCCUR. ICLEAN RAGS ARE KEPT IN METAL CONTAINERS. WAREHOUSE IS CLEANED ON A WEEKLY IBASIS TO PREVENT ANY ACCUMULATION OF FILTH THAT COULD PRESENT A FIRE HAZARD. HERE IS NO SMOKING IN THE WAREHOUSE OR OFFICE FACILITY AND IS POSTED.. elease Containment <4> Other Resource Activation 04/14/92 WESTERN EXTERMINATOR CO 215-000-000598 Page 11 00 - Overall Site <F> Site Emergency Factors. <1> Special Hazards <2> Utility Shut-Offs A) GAS - WEST SIDE OF STUCCO BUILDING BELOW WINDOW B) ELECTRICAL - WEST SIDE OF STUCCO BUILDING AT DOOR ENTRANCE C) WATER - FRONT CURB WEST OF BUSINESS SIGN D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS ARE READILY AT HAND FOR OUR OFFICE AND WAREHOUSE FACILITY. OFFICE HAS EXTINGUISHER ON SOUTH WALL BY WOMENS RESTROOM, ESTINGUISHER LOCATION FOR WAREHOUSE IS ON SUPPORT BEAM AT REGULAR ENTRANCE DOOR. A GARDEN HOSE IS AVAILABLE AT WAREHOUSE FAUCET BY SOUTHWEST CORNER. FIRE HYDRANT - BRUNDAGE AT SOUTHEAST CORNER OF OUR FRONT LOT <4> Building Occupancy Level 04/14/92' WESTERN EXTERMINATOR CO 215-000-000598 Page 12 00 - Overall Site <G> Training <1> Page 1 WE HAVE 17 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE ALL EMPLOYEES DEALING WITH PESTISIDE MATERIALS ARE EDUCATED IN PROPER PROCEDURE 'AND CLEAN UP. MOREOVER THEY CARRY A SPILL KIT IN THEIR VEHICLE. ALSO, A LARGE SPILL KIT IS ON HAND IN OUR WAREHOUSE FOR ANY ON SITE SPILLAGE. CONSTANTLY TRAINED AND REVIEW PROCEDURES BY VIDEO.REGARDING THIS. <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use ~ Bslrersfield Fire Dept. ~ S~- 3??? HAZARDOUS MATERIALS DIVISION Business Identification No. 21~000 ~o~ ~ Cop of Business Plan) HAT. ~ =T. DIV. Station No. ~ Shift ~ Inspector /~~o~ Adequate Inadequate Verificaion of Invento~ Materials ~ Verification of Quantities ~ Verification of Locaion ~ Proper Segregation of Materi~ ~ mments: Verificaion of MSDS Availabli~ ~ N~ber of Employees / ~ Verification d H~ Mat Training ~ Verification of Ab~eme~ Supplies & Procedures ~ Comments: Emergency Procedures Posted ~ Containers Properly Labeled ~ Comments: Verification of Facility Diagram ~ Sp~ial H=ards Associated with this Facility: ~ ~~ ~~/~¢~ Violations: ~ ,~'.~/..,~.,~ ,..,..,,~.s' .~-,.¢~..¢~ -f~ ~,,~.,~,¢~-'7". ,,'j'.,~7.,~. /-~ ,,',4'.a7'"~,~';~-7~.- All Items O.K. B usin,~-s/O"wfier/M anager Correction Needed FD 1652 (Rev. 1-90) White-Haz Mat Div. Yellow-Station Copy Pink-Business Copy ~/ ~ CITY of BAKERSFIELD 'RECEIVED NON--~'RADE SECRETS ~lth of h~ ~ltk ............. ~lth d ~m ~ltk .......... CITY of BAKERSFIELD ~ ~. HAZARDOUS MATERI ALS I NVENT-ORY' NON--mRAOE S~C~mS ' ,..~ o, Z0 ~lth of ~ ~ltk ...... ({~k ~11 t~t ~ly) I c~ttfy ~ wl~ oi lw tMt ! ~.~lly ~NJM.~ m fmtlt~ with tM tnf~tlm.~ittM~(thls ~ ell ~tmMMtl. ~ tMt ~ m ~ ~tq M t~ ~)vi~ls mwible CITY of BAKERSFIELD '~ ~/HAZARDOUS MATERI ALS I NVENT.ORY' F~ru and ~f~cultvre Stofldocd ~si~qss NON .--TRADE SECRETS ' LOCATION:~t~ ~F,I~~ ~' ADDRESS: /~L ~'~ ~/~l STANDARD ~ ~ X~U~XO~ ~ ~OP~ ~OD~ ~ ~ 3 4 S i T J J Il I I J2 13 14 (~ ~ ~ ~ Est ~tts & Site I~ ~ lm ~ ~ St~ b f~illty~- b I~t~tt~ ,~ ~ ~t~ ~,~ c.A.s. ~~qZ -~' ~ ,t ~ t c.i.s. ~ I ~ith ' of ~ bith ' ' ; t ' :_:-~ ._..-.._,.-.._,.-. -- ~ -- , ,-'-,- ~ r~ /~ -+~,~to~'--~ ~:.:.,.... U_l ~ 12o tbo,I ,o ,~, Ive./~,l~.l~ II% J I J q J z~ j~-~~ ~ ~. : ~mo~ ,c~, .,, ,., .,,) qb~:C~4~X~ (~)a~, Cy~O -(~', - - ~,. ~,c.,.s. ~ t~i~l ~ ~ll~ ~I~ ~.1.]. ~ ~ II i I I.Ll. i ~lth ~ ~m hlth ....... ~~ b & C.LS. ~ f "' ..... . ~ii Certlficotim (Re~d fnd si~ after co~pletlnE ail 'seclions] fo~ obtamt~ t~ iflf~tl~. I ~J~ tMt t~ ~itt~ interim is t~. ~ote. ~ ~l~e. ~/ . ~ , /I CITY of BAKERSFIELD NON--TRADE SECRETS o ~,~ .{ ~ L..~' ~ ~ Z~v~zo~ ~m ~o~ COD~ (~ C~e bt ~ Est ~ttS ~ Site U.I~I..~,~i~ ,~ t ~/~ 11~51~1 /pi./ I ql~ol~/~~o~ ~. .~IHe~ ~~c~~.~ . ,~..L~IJ~~IJ.~ 1,~13~1 ;0_.1 k ~li tbt amly) ...... _ ,-. .-. .-, ,-. ~(~/~ -~) . · ~ ~ ~1~ - , ..~.~~.Jqo-~lJ~lJ3~ J/oJ I J q ,.,.,~.,,,~, ,.,.,.~ )s_~-U/-.Y ~,,, I~k III t~t ~Jy) · . ~lth Of P~ ~ltk . - ' 'D_~L~ '~ ' llZ-~_[_~.l13~l o~ I ~C~k ,,, ,~, ~,,)I z q- 3 ~- q '- -~ .... 'a~°bt~i~'~inf--t"'l""'t~t t'"''tt"'n'--tim'st~'~'"'"--"t"x'' '~ CITY of BAKERSFIELD T~ { HAZARDOUS MATERI ALS I ~F~ENT.ORY' NON--TRADE SECRETS . ,. ~,,&-- .~. ..... L_I ....... I .... ~ .... I,.. I I I I I ! I .. ~ o~ ~v~+~,~ ~ CITY. of BAKERSFIELD NON--TRADE ' SECRETS · m~_of/~. CITY, ZIP: ~~5~ Y~E~ cz~. ZZ~-. ~ g DUN AND B~DSTREET ~lth of ~ CITY of BAKERSFIELD ~ ~ HAZARDOUS MATERI ALS I ~F~ENT.OR~r' NON--TRADE SECRETS ' I~ml~ 7of /t~ 7 LOCATION: Y~ ~0~-- ~. ~DRESS:/2~ ~'~ ~/ STANDARD I~. CLASS' CODE Mlth of ~ MIth ..... Wt 13 b&C.A.S. CITY of BAKERSFIELD ~ / HAZARDOUS MATERI ALS I ~ENT.ORY' ~m 4nd ~r~culbf~ Stondord gusmess NON--TRADE SECRETS ' BUSINESS .__ME: O~ER NA~E: NAME OF CITY· ZIP: ~~~ ~~ CI~. ZIP: ~ . DUN AND BRADSTRKET ~UMBER ' ' t CITY of BAKERSFIELD NON--TRADE SECRETS Cvtificati~ (Read and si~ after colpletJnE all sections} ' CITY of BAKERSFIELD ~ ~, HAZARDOUS MATERI ALS I NVENT.ORY NON--TRADE SECRETS CITY· ZXP: ~5~Cm ~ ~0~ CX~. ZXP% I~,W~ DUN AND a~DSTREET NUMBER r--5 ~ ~t~ ~ & C.A.S. ~ ~lth of ~ bltb ......... ~ ~ ~ & C.A.S. ~ P~icol ~ ~Jth hz~ C.i.S. ~ at II ~ l C.I.S. ~ ({~k o1~ t~t omJy) ...... - r--~ r--~ r--~ r--~ ~t ~ ~ S C.i.5. ~ d ~ ~1~ ..... .... I._ ~ "~ '~._~ _~ ~ ~.._ [ . ~.' 1,. i" ",~ "Y: . , ' P~icol ~ blth ~ C.l.S. ~ ~t Il b l C.l.S. ~ - r-~ r--~ - r-~ C~t 12 hiC.A.S.~ ~lth of ~fl~ ~lth · Certlltcatim (ke~d and si~ after completinf all sections) / / WESTERN EXTERMINATOR C~PANY O PROFESSIONAL SERVICE SINCE 192'. [] 1. LOS ANGELES ~ 1 AKERSFIELD [] 20. SOUTHERN CANIGHT DIVISION [] 2. VALLEY [] 11. SAN DIEGO [] 31. PHOENIX (~,,~ [] 3. LONG BEACH [] 12. FRESNO [] 60. LANCASTER PLEASE REFER REPLY TO [] 4. EL MONTE [] 14. OAKLAND [] 61. CARLSBAD SPEED A, O.ESSC."C,(E,, 5. ORANGE COUNTY ~ 15. SAN JOSE ~ 64. CORTE MADERA MEMO 6: SAN BERNARDINO ~ 16. SACRAMENTO ~ CORPORATE ~ 7. PALM SPRINGS ~ 17. OXNARD ~ OTHER T~/~ ' ~ 8. SAN FRANCISCO ~ 18. SALINAS ~ - 3SINESS NAME WESTERN EXTERMINATOR CO ID NUMBER 215-000-000598 · ~ 0CATION 810 BRUNDAGE LN HIGH HAZARD RATING 4 . OVERVIEW LAST CHANGE 01/06/88 BY EVAMC iRIS CODE 215-006 JURIS BAKERSFIELD STATION 06 %P PAGE 103 GRID 31D FACILITY UNITS 1 HAZARD RATING 4 SSPONSE SUMMARY 2A SEC 4) IN CASE OF AN EMERGENCY, EMPLOYEES WOULD EVACUATE BUILDING AND GO TO THE SOUTH SIDE OF THE STREET EMERGENCY CONTACTS 2A SEC 2) ~UY F REEVES 327-0949 871-3483 JAMES D WINFREY 327-0949 UTILITY SHUTOFFS 2A SEC 3) A) GAS - WEST SIDE OF STUCCO BUILDING BELOW WINDOW B) ELECTRICAL - WEST SIDE OF STUCCO BUILDING AT DOOR ENTRANCE C) WATER - FRONT CURB WEST OF BUSINESS SIGN D) SPECIAL - NONE E) LOCK BOX - NO NOT I F I CAT I ON / PUBL I C EVACUAT I ON 03 ~ ' LAST CHANGE / / BY ~Y < N(YJINFORMATION RECORDED FOR THIS SECTION ~AGE 1 12/27/88 15:52 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 JSINESS NAME WESTERN EXTERMINATOR CO ID NUMBER 215-000-000598 )CATION 810 BRUNDAGE LN HIGH HAZARD RATING 4 : . HAZ MAT TRAINING SUMMARY ,~.~, /~ ~ ~ .... LAST CHANGE / / BY ~ ~L~ ~,~O IN~R~ATI~N RELORDED FOR THIS SECTION > LOCAL EMERGENCY MEDICAL ASSISTANCE LAST CHANGE 01/06/88 BY EVAMC 2A SEC 5) DR. WILLARD CHRISTIANSEN 2021 22ND ST 327-9617 ~GE 2 12/'27/88 15:52 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 JSINESS NAME WESTERN EXTERMINATOR CO ID NUMBER 215-000-000598 )CATION 810 BRUNDAGE LN HIGH HAZARD RATING 4 ~CILITY UNIT 01 · . OVE~RAL L HAZARDOUS MATERIALS INVENTORY LAST CHANGE 01/07/88 BY EVAMC ID TYPE NAME MAX AMT UNIT HAZARD LOCATION CONTAINMENT USE 1 PURE VIKANE 500 FT3 HIGH REAR METAL BUILDING METAL CONTAINERS ANESTHETIC ID PERCENT COMPONENTS HAZARD LISTS 2573.00 100.0 SULFURYL FLUORIDE HIGH ~ . FIRE PROTECTION / WATER SUPPLIES LAST CHANGE 01/06/88 BY EVAMC 'AGE 3 12/27/88 15:52 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 ~JSINE~SS ~AME WESTERN EXTER~ATOR CO ID NUM] 215-000-000598 ~CATION 810 BRUNDAGE LN HIGH HAZARD RATING 4 EMPLOYEE NOTIFICATION / EVACUATION LAST CHANGE 01/06/88 BY EVAMC < NO INFORMATION RECORDED FOR THItg SECTION' MITIGATION / PREVENTION / ABATEMENT LAST CHANGE 01/06/88 BY EVAMC 3A SEC 1) BULK OF OUR MATERIALS ARE WETTABLE POWDERS AND AERSOLS. THERE ARE NO MORE THAN 25- I GALLON CONTAINERS OF LIQUID MATERIALS IN OUR WAREHOUSE AT ANY GIVEN TIME. ANY SPILL ON OUR FLOOR PRESENTS ABSOLUTELY NO HAZARD TO CLEAN UP. ABSORBENT IS KEPT AVAILABLE IN THE WAREHOUSE TO CLEAN UP ANY SPILL- AGE THAT MAY OCCUR. CLEAN RAGS ARE KEPT IN METAL CONTAINERS. WAREHOUSE IS CLEANED ON A WEEKLY BASIS TO PREVENT ANY ACCUMULATION OF FILTH THAT COULD PRESENT A FIRE HAZARD. THERE IS NO SMOKING IN THE WAREHOUSE OR OFFICE FACILITY AND IS POSTED. AGE 4 12/27/88 15:52 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 CITY of BAKERSFIELD NON--TRADE SECRETS · LOCATION: ~1~ ~t~~- L~- ADDRESS: 17 ~ ~'~ ~, STANDARD IND. CLASS CODE / of ~ ~lth ................. ~lth of ~ ~lth ~lth of Pr.~ ~lth ......... ., CITY of BAKERSFIELD NON--TRADE SECRETS , LOCATION: ~ ~D;;JD~ ~- ADDRESS: [TE~ ~'~ ~. STANDARD IND.'CLASS CODE: CITY. ZIP: ~~;~L~ ~,~D~ Cl~. ZIP: ~/~ ~ZT/~ DUN AND BRADSTREET NUMBER ~~ ~ i C.A.S. ~ ~lth of Pr~ ~lth CertifiCatl~ (Read and si~ after colpJ~t]n~ 411 sections) · ., CITY of BAKERSFIELD ~--, { HAZARDOUS MATERI ALS I I'4"TFENT.O R'M'" lr~m ~N! ~rtc~lture Stand~rd Business h of Prn~ blth ~t~ ~ & C.A.S. ~ ...... D~,~ _.~~ ..n..J~~~ ..... ~/~ ~. ~~ ' CITY of BAKERSFIELD NON--TRADE SECRETS o ,.~ Z./.,/fi..s- ,.:. CITY· ZIP: k oil t~t e~ly) - - [~rttftcott~ (Re~d and si~ after co~plet~n~ al] sectlofl~) CITY of BAKERSFIELD . NON--TRADE SECRETS ' o~ '~" of/,.~). ~lth of ~ ~lth .... L_i_ I._ I I I I I I ! I o~ ~11~ ~ ~ ~l~ ' ' I .._1 I I - .1 I I I I ! I I icaa~r/a( ~lth of ~ ~lth .......... : CITY of BAKERSFIELD ~ { HAZARDOUS MATERI ALS I ~FENT.OR~r' F~rm a~l ~}rt~ultm.~ Standard ~i~S ~ ~ X~U~XO~ ~R ~OP~ COD~ .... L_I [ 1 ..... I I I I I I I ~ ~ Di~e~xi.~ ~ ~lth of Pm~ ~lth - · ~Jth of Prfl~ ~Jth ' Certlftcati~ (Re~d and si~ after co~pIeting all sections) " CITY of BAKERSFIELD Z ~ HAZARDOUS MATERI ALS I NVENT.OR~' ~,. ~n~ m;f~c, lt.re Sta~cl~rd Business NON--TRADE SECRETS LOCATION: ~ ~'~"h'~-- ~; ........ ', ADDRESS:/7~ ~i~' ~'*/ STANDARD IND. CLASS CODE CITY. ZIP: ~~/~Cm ~~ CZ~. ZIP: rEOl06 ~ 7/~ DU, AND BRADSTREET NUMBER ~lth of ~fl~ ~ltb ........ ~ CITY of BAKERSFIELD NON--TRADE SECRETS · ~lth of Pr~ ' ~lth ..... CertlficltJ~ (Read and si~ a~ter co.plet~n; all sections) CITY of BAKERSFIELD NON--TRADE SECRETS · ,,~,qet/~.~...~_ CITY, ZIP: ~~t~T~~ ~ ~ CI~, ZIP:-~/~ ~1 ~ DUN AND BRADSTRKET NUMBER ~HO~E ~: ~-~ PHONE ~: ~/~- ~/- ~ -- -- - -- -- -- - ~ ~ ~U~o~ ~ ~0~ COD~ t 2 3 4 S i T I t II 11 1~ 13 (~ C~e bt ~ Est ~tts ~ Site 1~ ~ IW ~ .. St~ In FKIII~~' ~ I~t~tt~ / ~lth of ~ ~lth - ' - ' ' P~icll ~ ~lth ~z~ C.l.S. ~ ~t II ~ i C.l.S. ~ ,c~ .,, ,~, ..,y) ~1 ~d~ .. ~lth of P~ ~lth ' · .... ..~l~t~l~leT%l.~lO~ I.Z t.q 1 99 ]~1e ~'e o~ ~. '- vi P~ic.! ~ HHIth ~z~ C.A.S. ~~ ~t I! ~ & C.A.S. ~ ~lth of Prfl~M ~lth c~tlftcatim (Read and si~ after colpJetlng all sections) i . CITY of BAKERSFIELD ~ ~. HAZ'ARDOUS MATERI ALS I NVENT.OR~' ~rm ~nd 14r~cult~e Standard ~i~s NON--TRADE SECRETS ~ ~ X~U~XO~ ~R ~OP~ COD~ r--~ ~ ~t~ ~&C.A.S.~ ~lth of ~ ~lth - r--~ r--~ r--~ r--~ ~t ~ ~&C.A.S.~ ~lth of ~ ~lth fC~k 811 t~t ~ly) (C~k ~11 t~t rely) h of Pr~ ~lth '_-il' BiK .RSFIELD FIR RECEIVED BAKERSFIELD, CA 93301 (805) 326-3979 AilS'd ............ OFFICIAL USE ONLY BUSINESS NAME HAZARDOUS MATERI ALS BUSINESS PLAN AS A WHOLE FORM 2A 000598 INS~UCTIONS: " 1. To avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA SECTION 2: E~ERGENCY NOTIFICATIONS In case of an emergency Involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This' will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES T0 NOTIFY IN CASE 0F EMERGENCY: NAME_AND TITLE DURING BUS. HRS. AFTER BUS. HRS. SECTION 3: LOCATION'OF UTILITY SHUT-OFFS FOR BUSINESS 'AS A WHOLE A. NAT. GAS/PRO, PANE: ~SeS'~' 5lc~e., .. cc_o vo. '~,laa )'¥"¥t.\co~ k,o'~.f'x pt,o, D. SPECIAL: E. LOCK BOX: YES / N(.~ IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 2A - 'SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS-A WHOLE SECTION 6: EHPLO~E TRAINING E~P~OYERS ARE ~Eq~Z~ED'TO ~AVE A PRO6~ ~HZC~ PROVIDES E~PLOYEES ~IT~ ~NZTIAL AND REF~ESHE~ TRA~ING ~N T~E FO~LO~NB OZRCLE YES OR NO I~ZTZAL ~EFRESHER A. ~ETHOD$ FO~ SAFE ~ANDLIN6 OF HAZARDOUS D E~ERGENCY EVACUATION PROCEDURES: ................. ~NO NO E DO YOU ~INTAIN E~PLOYEE TRAINING RECORDS: ....... NO NO SECTION 9: ~Z~DOUS ~TERI~ I~ G~'~,~V(.G. , certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous ~atertals (Div.. 20 Chapter 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. WESTERN EXTERMINATOR COvIPANYt Address of Property Inspected ~ 1 (~ ]~LT"lln(21~l~ T,~l~ ]~]~l-~: ~ ~l Kt Bldg. No. St,eel Ci~ ¢¢' BAKERSFIELD CITY FIRE DEPARTMENT I.D. # FOR[{ 4A-1 Page ~of NON--TRADE .SECRETS HAZ AR. DOUS MATERI ALS I NVENTORY BUSINESS NAME: L~ ~k) ~r~'~,t~ ~_ .~. OWNER NAME: FACILITY UNIT ~:~ ADDRESS: ~/O ~~ ~ ' ADDRESS: FACILITY UNIT NA~E: _ CITY, ZIP: ~er~ f~e/~ ~5~Oq CITY,ZIP: PHONE ~: 3~7-0~{~ PHONE ~: [OFFICIALoNLY USE' CFIRS ~O'DE -'1 2 3 4 5 6 7 8 9 TYPE HAX ANNUAL CONT USg ~' LOCATION IN THiS · BY BAZARD D.0.T .~ODE AMQ,.UNTAMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE P do~ xoff !b~ 1~ 30 " '~~',~ 3 P 50~ /00~ J~s ~'~'~ " P .~o ~. ~o ~ lbs, /a 3o " D~¢sh~._ ~o ~ NAME: ,~Y ~eCy~fi.~ TITLE: ~l?,;,,,c~, ~ SIGNATURE: DATE:, E,~o~N~v CONTACT: ~,,~ ~ee~ .T~TL~ '.ONE m ~US ,OU~S:.3~-..,.Ogd~' ~EROENCY CONTACT: ~a~5 ~n ev TITLE: ~ ~n>~/~' , . .PHONE ~ BUS PRINCIPAL BUSINESS ACTIVITy:, ' ~fi~ ~1~ ~e~-m~'~ ~c9~ AFTER BUS HRS: O.D. FORM 4A-! Page ~.,.of~ NON--TRADE SECRETS HAZARDOUS MATERT ALS INVENTORY ADDRESS: ~/D ~UAi~J;7~B_ '~1~' ADDRESS: FACILITY UNIT NAME: PHONE Z: ~7-O~ PHONE Z: OFFICIAL USE CFIRS C00E ~ ONLY 1 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUAL CONT USE 'LOCATION IN TRiS % BY NAZARD D.O. C00E AMOUNT AMOUNT UNIT CODE CODE. FACILITY UNIT WT. CHEMIQAL OR COMMON NAME CODE GUID NAME: TITLE: SIGNATURE: ~ ~0~ DATE: EMERGENCY CONTACT:' me5 ~ TITLE: ~ ~NSP~O~ V AFTER BUS HRS: , . PHONE ~ BUS HOURS:~7-D~'9 BAKERSFIELD CITY FIRE DEPARTMENT 3 '3 ~.D. ;l FORM 4A-1 Page . NON--TRADE SE'CRETS HAZARDOUS MATERI ALS INVENTORY BUSINESS NAME: ~ N ~ m'~ · OWNER NAME: ' FACILITY UNIT #:~ ADDRESS: ~[0 ~-~(~C~, L~ . ADDRESS: FACILITY UNIT NA,E: CITY, ZIP: ~~ ~{ ~ ~0~ CITY,ZiP: PHONE ~: ~7' 0~ PHONE ~: OFFICIAL USE CFIRS CODE ~ 2 3 4 5 6 7 8 9 10 TYPE ~AX ANNUAL CONT USE LOCATION IN THis · BY HAZARD :D.O. ~,pDE A~OUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE GUID NAME: ~V&5 TITLE: ~. ~ SIONATURE: PRINCIPA~ BUSINESS ACTIVITY: ' ~es¢' ~nJ ~mf~e C,~Di ' AFTER BUS HRS.: / BAKERSFIELD CITY FIRE DEPARTMENT / 2130 "G" STREET / BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID# .... BUSINESS NA?4E: ~ - _. ~'~.::'" ~:L~ ...... :~[_. - BUS I NESS PLAN SINGLE FACILITY UNIT FORM 8A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questiens below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. FACILI~ L~IT~ 810 Br~daqe FACILI~ UNIT N.~E: ~S?E~ E~NA~R CO~ ~ 93304 SECTION 1: MITIGATION, PREVENTION, ABATEMENT PROCEDURES ~ 5~. SECTION 2: NOTIFICATION A~ EVACUATION PROCEDURES AT THIS b~iT ONLY SECTION 3: HAZARDOUS.MATERIALS FOR THIS b~IT ONLY · A. Does this Facility Unit contain Hazardous Materials? ...... YES NO If YES, ~ee B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES NO If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form #4A-l) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form #4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS SECTION B: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY. A. NAT. GAS/PROPAN~ B. ELECTRICAL: C. WATER: D. SPECIAL: E. LOCK BOX: YES / NO IF YES, LOCATION: IF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS? YES / N0~ KEYS? YES / NO - 3B - EXTERMINATOR COMPANY ~^~<~s~l~. c^~,^ 9~o4 Since 1921 RECEIVED OCT 5 1987 Ans'd ............ September 30, 1987 Dear Mr. Huey, Enclosed are the last remaining papers for the information packet detailing the requirments for compliance with the new California Law concerning hazard- ous materials. We appreciate your patience in this matter of gathering the pertinent infor- mation requested. Should you have any questions please do not hesitate to contact me at your convenience. Our office hours are 8 a.m to 5 p.m. Monday thru Friday. Bra~ch Manager Enclosures Ge/br (805) 327-0949 BAKERSFIELD (805) 945-1855 LANCASTER (619) 375-4352 RIDGECREST · THE WEST'S LARGEST TERMITE & PEST CONTROL COMPANY MATE.RIAL SAFETY D.ATA SHEET mmmmm mwmmmmmmmmmmmmmmmm~. Dow Chemical .U.S.A. Midland, MI 48674 EmergenCy Phone: 517-636-4400 HSD: 001h~9 Page: & PRODUCT'NAME:DURSBAN (R) TC TERMITICIDE cONCENTRATE Effective Date: 07/28/81 Date Printed: 10/16/85 Product Code: 26056 · 7.FIRST AID: (CONTINUED) Oral: Roderately toxic. Ray cause reaction similar to petroleum or petroleum-like solvent. Danger of chemical pneumonia must be weighed against toxicity when emptying the . stomach. If lavage is performed, suggest endotracheal and/or esophagoscopic control. Systemics Ray produce 'organo-phorphorus type cholinesterase inhibition· Atropine by injection is.antidote of choice. Oximes may or may not be therapeutic, butmust never be used in place of atropine. Consult standard literature. Treatment based on sound judgment of physician and the individual reactions of the patient· Suggest, serum and/or rbc cholinesterase · determination· · 8. HANOLING PRECAUTIONS: VENTILATION: Recommend control of xylene and chlorpyrifos to suggested guides. RESPIRATORY PROTECTION: Approved organic vapor-type respirator required in absence of proper environmental control. SKIN PROTECTION: Rubber gloves, boots, apron, gauntlets, and a face shield in addition to recommended eye protection depending upon the extent and severity of exposure likely. EYE PROTECTION: ~Chemical worker's goggles· g. ADDITIONAL INFORMATION:' ' SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORAGE: NSOS STATUS: New NSDS. (R) Indicates a trademark of The Dow Chemical Company The Information Herein Is Given In Good Faith, But No Warranty, Expressed Or. Implied, Is Rade. Consult The Dow Chemical Company For Further Information. :MATER*I.AL SAFET*Y DATA S,HEET Dow Cheeic~l U.S.A. #~d]~nd, #! 48674 Eeergency Phone: 517'636-4400 MSD: 001~9 Page.: ,PRODUCT NAIIE: DURSBAN (R) TC TE~!TICIDE CONCENTRATE Effective Date: 07/28/81 Date Printed:'10/16/85 Product Code: 26056 6. HEALTH HAZARD DATA: *(CONT!NUED) superficial burn; repeated contact: Moderate burn. SKIN ABSORPTION: LD~O rabbit i$7~ mg/kg, mode~ate!x toxic. INGESTION: Moderate'single dose toxicity; LD$O male rats ~72 . mg/kg, female rats ~87 mg/kg. INHALATION: ACGIH TLV 0.2 mg/m3 chlorpyrifos, 1OO ppm xylene range solvent. · SYSTEMIC & OTHER EFFECTS: Drowsiness (solvent), cholinesterase inhibition (chlorpyrifos). 7. FIRST A!D: EYES: Irrigate ~ith flowing ~ater immediate1y and continuously for fifteen minutes. Consult medical, personnel. SKIN: In case of contact, immediately flush skin with plenty of soap and ~ater while removing contaminated clothing and shoes. Call a physician if irritation persists. ~ash clothing before reuse. Destroy contaminated shoes. INGESTION: Do not induce vomiting. Call a physician and/or ....... transport*to e~nergency-facility. INHALATION: Remove to fresh air if effects occur. Consult medical. If respiration stops, give mouth-to-mouth resUscitation. NOTE'TO PHYSICIAN: Eyes: May cause severe irritation. May cause corneal injury or burn. Stain for evidence of corneal injury. If cornea is burned~ instill antibiotic steroid preparation frequently. Consdlt ophthalmologist. Skin: May cause mild irritation· ~ay cause.burn with prolonged contact. May be absorbed in acutely toxic'amounts. Respiratory: May cause drunkenness. Anesthetic or narcotic effect may occur. Aspiration may cause chemical pneumonia. (Continued on Page ~) (R) Indicates a trademark of The Dow Chemical Company #ATER 1AL SAFETY DATA SHEET DM Chemical U.S.A. Nidland, HZ 48674 Eamrgenc,,y Phone: 517-636-4400 fISD: 001.~) Page: 2 PRODUCT NANE: DURSBAN (R) TC TERHITICIDE CONCENTRATE Effective Date: 07/28/81 Date Printed: 10/16/85 Product Code: 26056 3.~ FIRE AND EXPLOSION HAZARD DATA: (CONTINUED) FIRE-FIGHTING EQUIPMENT: Use positive-pressure breathing apparatus. 4. REACTIVITY DATA: STABILITY: (CONDITIONS· TO AVOID) Avoid heating above $~C, 130F temperature for more than two hours. Chlorpyrifos undergoes exothermic decomposi.tion which can. lead to higher temperatures and violent decomposition if heat developed is not removed. Contains petroleum derivative solvent - will burn. INCOHPATIBILITY: (SPECIFIC HATERIALS TO AVOID) Unstable at pH above 10. Consult manufacturer for specific Cases. HAZARDOUS DECO~POSITION PRODUCTS: Hydrogen chloride, ethyl sulfide, diethyI sulfides and nitrogen oxides. HAZARDOUS POLYMERIZATION: Nill not occur. 5. ENVIRONMENTAL AND DZSPOSAL INFORkLATION: ACTION TO TAKE FOR SPILLS/LEAKS: Absorb spills with material such as sand. Wash exposed body areas thoroughly after handling. Contain spill by diking to keep out of sewers. For large spills, barricade area, eliminate*ignFtion sources, and consult manufacturer. DISPOSAL /~ETHOD: Bury clean-Up waste in location away from domestic water supplies, according to local, state, and federal regulations. Incinerate at 1800F with 2 second residence time. 6. HEALTH HAZARO DATA: EYE: Pain, severe irritation, moderate corneal injury; effects should heal with time. SKIN CONTACT: Prolonged contact: P, oderate irritation and a (Continued on Page 3) (R) Indicates a trademark of The Dow Chemical COmpany MATERZAL SAFETY DATA SHEET Dow Che=~cal-U.S.A. H~dland, HZ 48674 E~ergency Phone: 517-636-4400 RSD: 001~9 . Page: I PRODUCT N~E: DURSBAN (R) TC TE~¥[CZ~E C~ICENTRATE Effect~v~..Date: 07/28/81 Date Printed: 10/16/85 Product Code: 26056 1. Z#ERED]E#TS: O,O,-Dieth¥1 . " O-(~,~,6-trichloro-2-pyrid¥1) phosphorothiate, (chiorp¥rifos) .. X¥1ene range aromatic solvent Inerts ~8.8~; 2. PHYSICAL DATA: BOILING POINT: 2~OF, 1~3C VAP PRESS: 2~ mmHg @ ~OC VAP DENSITY: SOL. IN HATER: Emulsifies SP. GRAVITY: 1.15 APPEARANCE: Yello~ liquid. ODOR: ~ercaptan type odor. 3. FZRE ANO EXPLOSZON HAZARO OATA: FLASH POINT: 122F, $0C ~ETHO0 USED: TCC FLARRABLE LIMITS LFL: Not deter. UFL: Not deter. EXTINGUISHING ~EOIA: Hater spray, carbon dioxide, and dry chemical. FIRE & EXPLOSION HAZARDS: Foam system is preferred. Toxic irritating gases may be formed. Rapid'decomposition above 160-200C. Violent rupture of containers due to overpressurization may occur. (Continued on Page 2) (R) Indicates a trademark of The Oow Chemical Company ATA 1-NAPHTHALENE ACETIC ACID f O. Structural Formula: Hoiecular Formula~, C12HiO02 . Holecular Weight: 186.21 ~ Color~ Off White FOrm: Crgstalline Powder ~! Puritg: 98~ Average '~ ~lelting Point: ]~°C. l~inimum The data herein I$ believed to be Iccurltl. Howtver, It Is Intended for uw by qualified technical personnel at their own risk. No gu&rlnteeor warranty of any kind is expressed or implied, nor does Chemlspher® assume any resOonslblllty resulting from the use of the product or PrOCeSS deKrlDed hlreln. No patent warranty Is made of intended nor Is'any IxrmlSSlon to Use g~&nted whl wOuld De In conflict wltl~ e=lstlng patent rlgnts covMIng any product Of process. Chemisphere corporation . P.O. BOX 96, 8OONTON, NEW JERSEY 0700,5 TELEPHONE (201) 33,5-6972 212 898-2300 TWX: 710-582-4900 ~'~6'09' ~'' CABLES: ACETOCHEM NEW YORK ANTHONY BALDI,, PRESIDENT ...... NAPHTHALENE. ACET IC-AC ID ~ -- Chemical Name, 1-Naphthaleneacetic Acid Chemical Structure, LD$O (Oral) 1000 mg./ g. Caution: Keep Out Of Reach Of Children. May cause irritation of nose, throat and may be harmful if in- haled or swallowed. Do not breathe dust. Use with adequate ventilation. Avoid contact with eyes, skin or clothing. Wash thoroughly after handling. ('of compliance with the Occupational Safety' and Health Act of 197,0 and.: ~o~her purpose. U~-or :*~n of ~tl ~r"any part~ofr.~l/-inf~ma~=n for~=any other purpose, s ignft~e b'y'a high ene=~ .spazk at '~e fl=~ilfty 'li=lt~. liste4 ~ove.: ' )?,¢lO0',mff~kg. '.::. Inhalation hCra', (ra~) 'iS".3120' ppm for 15"minutes.. "':?'(h:~':~:,~:~ .'60000 'ppm',f°r 'ThoUrs. -,. M~:thYl "bromide is .a-poi~n..'., ~..cause-'..~ardiac:'arreSt, :and:central nervous system irritation in h~ans.. ?'bee~L . '.carcinogenic in a 90-day' Oral study, in rats. , : . ; medical,' a[$ention. ~dia[ely. ~ake peg~on :to a doctor or e~rgen~ Re~ve,,*ex~sedr'person ',from cont~inated area., Keep ~arm. ~ake' sure .' '; ': :': g had' s~opped, give artificial respire[ion.' Give'o~gen cOnt~inated c[othing;;~ahoea~:. ~evelry, and any o~er tiaa On skin; Hash con[~tnated":-- ,' ' ' ip'and '~ata~:~'~'IF IN ~gSt:i" ~old eyelids' open,' and 'ilush vith a steady~' gentle' S O. II ~:SPILL OR LEAK PflOC~DURES .'.. :,"~L'; ~. :-.~ i. IN;}cAsE MAtERIAl"is RELEASED, OR SPILLED,'~ r', ~ ..... * ' ~'~,~ei'~',~? ;,~U*s~ng~} ........ ~r'iate respiratOry,protection ope'n-'ali',win~°wi .'? ~tector ;indicates4'safe~conditio~s.~ 'If~outd°ors, '? [ ''? oN"vill :: SPECIAL PflOTECTION INFOBMATION ~.as measured by .de~ec~or t~e exceeds 5 ppm~a¥ and d~tec~o~ .tu~s;'fo~ dete~ning 'methyl b~omide"concen~ations. above is presented, in'~o~ faith and has ~en derived from sources ~elieved to ~ reliable. However, no warranw, e~tended r~gard n~ ts"~cc~ra~ Di, the.,~esults tO'be'obtained from its use. Since conditions of u~ are beyond our :: MATERIAL iAFE.,T¥! .D. ATA SHEET:: Q ]~AC~URER~ NAME.: ' .~: :',: ": ',::.-?~/:~::- ~:" ~': ',:: ~.'~ E~ERGENCYTELEPHONE NO;./: TRADE.NAME AND SYNONYMS ?;',~,',: ';'-".:~f';:;~'3~'~*;~:f-': ','? "' '"~':;: ~;{<;.,.'" ;;~',: ',:-,:.:,;:. ' ' ": ? t':',ch:i6ro~ '" ,'.'.~hlor'O~PiC:~':X:,.....:.,,::~,: .... ,,.-:':.' ::.......:.:'. ".;.:; -: .'.~:? :. : :.' .:'...,'...: .:... ;., :~,' ''. ..... ' "" ' .:.?."' ." ' ' ' ~' . : ' ' .. ' " .'. ?.Chlor. opicr~n,~ .Tr~'chloron~tromethane, N~trochloroform ....... - ", ?,.,,,,:~w:. ,,,- :,,:<:"*-:::'::.' ::?.: ;' :,. ' "~~~~RD0~INGREDiENTS ' .. - ........ -.~¢,:*S"::":: ":::;:: ?" .?;' COMPONENT' '.' :- :'.:" ,: :' '- ,~ :, HAZARD DATA ,,," · .'j','?":::::.J':".'r:C'-,'?~'.~:"' %. '"2:%~2 ':t: '-.'.:-::,'-,c':,~:?&.~,: .: .'.:..':' :..:::' ~, :': : : ..::" ':%'t''.' ~::..''. . :-:' ?',: "~' ...' ',.. -'' ;.O~e~?:ha:onitroa~lkaneS:::~?:~: :." ~::)~,. :~ ~3; 5 Chloropicrin .:is, highly .toxic' by 'inhalation .' ..... ~..: ...... : .... ,,-:... ~...,..-..~.~.-~;.:.-,,::. ....... and toxlc,,by lngestlo~. It. lsa severe . ,- :,-~:",8.://;".:<:;' :~:/'}.~ :.::~::;<-,-- 7~. ~ :"- .:....:/..::; .:, ~;~::::'.. v ..:.. skln and eye lrrlt~nt ad lacrlmator..' ,, :.?. :.,: } .;~/~ .,/ ;~; ... . .. . , , , . , · . ....... ....... ' ........ '~ ': "~<' :: ::':': ;:3 '.' :':' :' '':¥ ':'" ..... .::, :' '-'; ........ '"":; ..... .." :', .:..~. ?' '.,, .-:':: '~.:t .'2 : :' _ .,.': ':r. '/:' ,.., .; : .: ~.~::.:..:~.. ,::.. ~VAPORpENSI~,,{A!R=J) .... -'":' -,~;:/::/.,-:,~'.<'%'.. :'~: ,~5.7~ ", : · ,.',.'. ,, . ' :. ~ ..... ' ' "'. ~ /io::/:" :' '<:' '~'~ ~ "' """ "' -' ~OLUBiLI~Y ~ ~ATE~' : : :: -.~.::.':.c ' : 0.'2 .... : ': ".' _.,,:.:.:..: ..... ..:, ,.,. : :, 09.,... .... -,. . . .' .:-.. :...:,. · . . : .. - . . . i""EX'":"C~ :"D ODe". Co:6~:eSS::?:l'q~id "~ith 'in~enseiy' irritating 'tear gas "Odor., .,,:?....,.~ . <,. . .:, ,.. . p :.'.': . ... :: .-.: . ':'c.'"-,'~:::~? ,-:.SECTION~:IV"~FIRE;AND EX LOSION ,HAZARD DATA .:.: --~ .. :':..-.. ~:.,. ::,.:.'~':x,':;:~,'--" · : .... y i!. b,!e .... : : r, ~,- Not aVailable. : <,:':.:?: :.~:'.:::,~':.'-::,,~ <.:~:?:~<$ 'f"? :. ,?:.:',.?, ~ ~ ITING_ __ _ .._..PROCEDURES ':-,:~?":::':'~': .?/:" ?,::.: :" '' ' '::. ," ::'::';"' ":" r.., '. ', .'::.../::..., :- ./:,...,.. :: .:.... }.:. ~ ~ Lned?.:reSp~ratOr~:equiPment -, :., ,,,. . , . .. ,. ,:wa~er: ::f0g::.fr°m''r~'ote location., mandatory,. ,',~,,Evacuate area..,,., coo.i:-,::., .~ION:HAZAR~,..X',.: :,::'.' ',' :(~:..C "' :" : ........ :":.":, ?' ' .... '.', ~, ' ' . . ':-;heate;d::material'' aecomposes'::'vi01ently':' at. 112"c,'~::';. gases 'eSpecially i.n contact'with' metals. ~- ' ~ . -. / · . : , ~ ~ , '~; · , . , ;a':::, ':'::" ':':;' ' "<',' ,:::'::;~ "'.' SECTION :-V: HEALTH HAZARD DATA {"':: ,,: ~: ': ': "." '... ".';" :., -.: .. L:'..ppm,., .or.,: 0,....'7.: mg./cU'.m.'.:.: '.,:.' ::;. ' "- '. ; - .... ' [:na:usea~: Coughing,;~ suffOcatiOn', andZo: AND.F[R~AIDpRO~DURE~ s~d, pro~tly induce ~.ting 'unless victim la ,con- ;~:'u~o~oiom ! .... [].assistance i~diate~y~. :', ~'~ eyes are contacted, obt~in;'~d!cal:.assistanoe i~edia2ely. If akin is contacted," ar~lficial respira~on if brea~ing atopa~, obt~a-{}~:,:~]~,-~.~¢?., ~-~ ~RDOUS:OE~M~OSmON .... . .;ASE:MATER AL':. S RELEASED OR,SPILLED ~vacuaLe .a~ea, ' ~apor8 are extremely~ . ace--'sas mask or se~dOn~a~ed' brea~hiP~ apparacus;'~.AVO~d run- )/inc0'a'bucke[, o~'~acer and 'let' stand ~or c~o hours. ~eU~ral: ;:.hydrochlor~c acid in,:~aCer.:: ~;P~ace ~n' a suitable container over~.soda ' : wi~h: .the. soda':..~sh,./drain Slowly. in~b'..'a:"l~rg~ ~ ,.U~r~ii'~ ':With: 'a so'lucion of 'iai ')hydrochlOric acid. in water and' remove MECHANICAL Se~' :'," '.. ' . . ' ~. OTHER ': .-' :~'?.';-.:..'-'.:'-' '--above.," .. ' None.' · -~ .., ,: ., . . ,' ,. ..-. STOmNG': Keep ~.conta~e~s uP~g~"a~ ~la~e .' away" f~om :' dwe 1 llngs .'. 'DO: not -remove , . ,, : -: . : ~ . . ~,..:,.' = -. ,~, '::?.,~, ' . :,,,~., ,, ~lied :above'ii I~resented in'good ..faith and'has been derived from $o.urces believed'to be reliable. Howeve?;t:no warranty is'extended regarding, ts' accuracy or the resu ts to be obtained from ts use. $ nce cond t one of use are beyond our '~" I "'' ;'": ',:"contro,al ~sksare'esSum~ by the u~r . -,;'*.. *-, :*' - -~ ' ~ :; ' ~:- ' ' ,' ", ..... " ' ' -' :' .". '.' ' ". ', ~' J ';' ~: ~3~:''~i~'7~'~:':':':~/''~:'~::-'''/'~:'.'' ~:':~/',"'~/:.' '""' :' ' .:'"~:?:','~' : ~'::'" "" ' ': '. : .;/' page:26f2" . -'-. ': ~'.' :~:~i'~,~ :-: -,.";~- "?' ;!.[r ': 'i~-~ "',':.. . :,.-~-.:c', .~-,~:.:./>~.'f,, : f, ,.. .. ... ' '. ~' ,.. ,,' ...... : . ' . ', .. Dow Che..,~ic:a!. U,.Y,.A,. Midi. and, HI: 48674 Emergency F'hone: ];"i7-6:36-,.')4(!:-.'.') F"r'odu. c'i' Code: ';"'i]~:',")~ Page: F'RODLiE:T NAME: VIKANr..~. (R) F'LiMI[:;-ANT Effec:i' i',.u=, )}a'('e: t.2/'1'::' '""'" . ..... ...., ,:'., _: D a !' e F:' r i n '!' e d :. ¢ 'i / 1 2 / 8 7 M,'~' D: 0 ¢ (:'.,'.i~: O 6 ~ .. I N Ii- R Ii': I) I E N T ~:..': ,.> tt i. f t.t f' y I i': i. L~ 0 I" i d e r'.,,,, ~',.~. A ;:'~") ...'- c, c:,... '",, o... o ,"',,"', .... Sttb_~i:'l.'anc:e:~ I. i '-!:'t'ed in the in::.~'r'ed i en'i.':-~: ~"t. ec'("i ,::n"~ are 'i:hoi:~:e .i,::le~:'~:(' i fi ecl a .s' I:) ,--, ..... i i'1g p ~" e :F.: e i] '[' a .!.. a c: o f~ c: e n 't' r a ~' i o ~') o f t ~',, o t" g '~" e a -I: e i", o r ,':.;',. ,, 'l ,.,, '/ i f ·l:.he :..'.t~b_'-~:'t'a~]ce i .~..". o~'~ '~;he L i :!:.!: .r.)'f po'~m'~'l: i a ]. carc i ~'~og,.:.:,'r~,.'-~: c i 't'ed 0,.:. ~"1A H a z a r d C o m m ~ n i ,::: a .1. i o n ,.~ 't' a n d a r d, W h e r e I::, '~" o )::, r i e 'i' a r y . i )"~ .,:.j r e d ~ e n .I: .'.~h,::)w.,~., the ider~'('i'i.'y of 'i:hir-..' .'-i:u.l:).~!:i'an.,'.':e may I:)e made ava i i. ab.l.e a~.;' "-' -':.~ C F"' F;: 1 9 t ¢., 'i 9,,,..),~} ( ]: ) ,. provided in ,~.; ,... ,.:., F'HY,?ICAt.I..-'r..~' ...... I r-.~: · F,,r.iiL. i~,) .. ... - ..... ..... i,:!.,. F:'~"I]'i'..!T: -,.'::, 7).. ""'" ':;.~ i '":;~':', mmt..!,:.:j ¢I ,_~(:,,.F' ~. t ,,-,,t., '.', V ¢-, [':::, t:4, ~::' ',] ~,": ..... D::' ~'' ~""' TY ','~, '.~ VAI::' . L.i,.,.:..~. : ... ."'..'. O l ..... ! N W A T E,r';.'. - ~::' ~" .!~') ,::: 't' i c a i. I. y i ~'}.,:,',::1 I. u.b i. e ,?i::', F ~.;' '" ...... :~ ~" ' ' ':I., cl ) :,r,~..) v .~. T )': I ; 2(')C:- t. i er~:.:..: ~.~ 1.. 1.. [:. A 1.,.: ~..~ N E: ii!:: C c.', I. o r I. ,.,..,., ,. .. o'rio F:: 0,.:! o ~" I. e s :.:< c: o m p ~" e :=..: :=.: e ,'.:1 q a z-.' !::'];'RE AND EXF'I.i"]~.;'TON HAZARD DATA' ~.. ..... 'L.,.',".t'l ,l::'O][i?T: N~!'I: app i. i c:.al.':., N[:'.'i'~.lO;(.., j,?;t.E[) ' Nc,'i: aF'P I. i c:ai:.', FI..Ai';~NAB1...E L. ! N :i: T,5..' L. FL ' ,,~ ' N c: 't: f I. a m m a b 1. e UFI..: '[, N o '[' 1"' I. a m m a b I. e --. ',~ '" i".~ G N,:)'n f t. a m m a b !. ;:,: [....,] ].'- r:l "*' N ..,..J.]. ,.., I-., ~. H E .l)i A: ... F' Z R E & i::.}X F'I_.O,~i: ]; 0 N H A Z Ai:':.'.:..r.:,,~.i: · C y i. i 'a d e r :.:..: e x I::' o.? e d '[' o f i ~," e m a y v e a I'Id T n t!,~,'[' u. I" .¢..:e a ~"~ d I" e l.'e a ~!: e .i.. o .'...'. i c g a ~i: ,. 1::' i R I-;:': '"' F' :i: C- H 'i'"]' i"..I r:. E [;.:! U I F' H E N T: W e a 'r' 1.':' o z.~' i .i: i v e -i::' ~" e .s' :~' u. '~" e :.~' e t. f .-.. ,.:: o n .I: .....~ i ~"~ ....:..., d b ~" e a 't' h i ~'},'.:. -."."~ i::' t::' a r a 't' t.~ .~!:., "; R E A C".'f' I V 'r '~""," :0 A T A ' ....... " .... ]: T Y ( C 0 N D ]: 'i" 'i; f.:') N 2;' '."[,' 0 A V 0 ]: :(::, ) ;"" ' bll-.~[~','.l.b : .... ;.-~.i'nder:~? may t. eak ,.':)~- rt.tr..,'['t.~.re i'n ..'.'., fire,. ];i"-.]COi"'iPA]':~.i'.:.~iL.]:T?,: ( ;!it ,::' ,ii; C ::: F' ]; C HA'i"E;F:IAL,'!;' TO AVOID) 2.;: '!",." o'r,,,:;! ba_'-i:e., ::]:'[' ,?u.) 'i'"~ ~." ,':i ~ (:; ;-:: I ,::I ¢.!:: .a'r'~,::i hyd o,:~e'n -"*"::'"'~:; '"',;"' ':." :[:,E:COi'ii- ]'rii,.J ....... ;",' ,; ...... '.' ...... ...... i I"-. L .,, t.~ t... i ,;:. : ,. i" ] i"i .-:.. I t ...~ t...k. ,4- f !. u. o'r' i d e u.'n d e i-~?' i 'r' e ,::: o'n,.':t i '(' i o'r',, :ii: w i .i: l'i h y,::l 'r' c.: (:: .a r b ,.'::, I"~ :~: ,. \ ( C o'n '(' i i"~ u. ecl o n !::' a g e .:-. ) ,,-..; :::, ...-., -r~. i'i c} ,; ,-'.. a .1..._....,.':., .::' ...':~ '(' i" ..-':} c! e f~l a i" I¢, ........ ¢'.,. f ]' }'1 ,'-'.', '~) o w C }"~ (.:.:, ~'~i i r' a }. C c; r:i ,,':.:, ...'.-'~ ;"~ ¥ \ F:'roduci' C:ode: 9~5(.)~ Page: F'I~OgUCT NAME' VI .... ~ .... 4. R !:. ~..~b l ]. v 1 l' Y D a i a: ( C D N'¥' i N U F(I) ~, Hm. aRI,.]U,:~ POLYMER ]'nh~ I.I. . '",. .[ .. ¢'.~ ~ .... : ~.J i ENViF<ONHIEN'rAi.. ¢,NI) 9i,SF'O};'¢d_ iNF'ORidAT]:Oiq: _ T l '~ '" ' '~ . · ' P,=~nnyp Cy t. i 1]d(E'¥' '['0 eon'rained b¥'eai:hin9 appar<,,i'tui: oni. y,. .,~ ............ i. eaking 01::' (~') TI i 2' o [ a 'I: e d a t" e a ~ ~.,.:.r -.,~:.~..,,.. HE. ~HUI,: A [ I.,::)N i'D eVapO¥'a'te in open area away 'from p E' O p I. O., HEALTH HAZARI) i)ATA: E. fb: bs'.s'an~'i.al.i.y nonir'ritating to eye:s', ];T [iq. aid con'?act:~' eye, ev.~!l:)Of'a'[' iofi aay c:a II!i'e fro~"['l:) i i:e--.'i'yi::,e (: c) o I. i n g ,. · ,¢I(:[N CONT¢~CT: I::.:~:=.a~i~ial. l.y m:)¥~r¥'i~:ai'ing i'o s'kii'~ If I. iq. uid ccm'l'ac'!:~? ~:ki¥i, evapo¥'ai:ion may cause f¥'o~:'~bi"(e--'i'ype inju. r'y dtie t'o faF, id c:oo!.ing~ ~'" ~; I< p 't' i o n . ~!: ii n (:! u. e i: o .... i c a i. ,.~ ~'~ I N fi I!~ ~; 0 R F' l" I [IN: i n a b x: n r' i I. i k e I. y proper t i e:~:, ZNGE~;T]:ON: Inges'f i on i~ do.s;e rural, toxici'l:y i.:~ I. ivei" effect:~:., ~ N H A L A T I 0 N: E x c: e s :,; i v e v a p o r c o n c e n t r a .i: i o n s' a r e a i' t a i n a b !. ~.:.~ a n,::i may i:~(¢ i. ethal, on .?in,;.~l.c.) eXl:,C).s'af'e~ 5'eVeTe iT'T i ~'a'~ i(:)l] '!;0 ti };YiSi'EH~'¢''* OTHER E.F['[:.t ....'~: ' '" kidnc, y, l. ive¥' ancl CN.?; effec4:.'~:, Nay c:au2:e fl. tloro.si:~: c:,f te6:,i'h o~" t) (:) n a ~;., }:': i ¥' .l: h d e f,,:~ (: 'ir :~' aclver':~:?ac, effe(::'(' on the · F fi.} '~- ll:~:., I) i d 1'1 o 't' (:: a Ill~;e (,ie)l"e .Seen i n the fei' tis' -i; c) i: h o al(.)'[ h e ~" ,. ( E:,::,'n -.'.: i n u e d o'n F' a 9 e '..'"i ) (i:;.'.) ]:nd ica'i:e.,.~: a 'l:rademarl< oi: 'i'h(..'.., 9,.':.',.~;.¢ Chemical. C, ofrd::,ar~y ?,. I:' !: i.~:~.']" ,S'KZN: t~a.~:h off i~'~ fl.o~i¥~g ~,,~a'~'e~" or :s'ho~e¥',. I f-~ C; E ~ T I 0 N: N o a d v e ¥' ~: e e 'f 'f e c: '~' ~s' a ¥~ ~' i c i 1:~ a .1: tNHf~L.~TI(:)N: Remove '?o 'Fi"e~:l'i a ir i f e'f'fec'l:~ c),:::(:: u.r ,. Z'[ ¥!o'(' brea'~h .... NOTE: TO F'I-IY/~'!Ci~i',I: The i)¥'eclic~'ic:,i'l of po.?~'ibi, e hu. ma¥1 a n i m a 1..~: ,. i i' i :~.' !:~ ¥' e d i c ~: e dt' h a '[' I:, e ¥' s o n :is' e x ? o :s'e d 't c) :~: u. 1. f u. ¥' y I. · ff.l~o¥'ide ~,,~i 1.1. ~hc)~ 1. i~"['i.e evidenc:e c)'f i ur~l. es:~: ~'l'le c:o¥ic:el't~'ra~:io'n i.s: very high The ini'('ial, el'fee'(' ~,~ii.t. prc)babl, y be on '~he ~ i g n ~s' ~'l o .1: e d ,. ]: '~' i ~' e ~: ~' e ~'t 't' i a t. .!: (:~ k e e I::' .~!: u.(:: h a n i ~'~ d i v icl ([ a I. a .f: b e d res'~' 'for a'~' l. ea~s"[' 2,~. hr.s', Cl. il'ii(::ai. (:)bser'~xa't'ic,'ns shc:,u.i.d I:)e d i i" e (:: .I: e (:! a .1.. "h e p u. i. m o ¥i a i" y, h e p a '~' i r:. a i'l d r ConvL~ !.s'i (:)ms.' may en.s'u.e ~ i ~'h ¥'~9:~'I::, [ ¥'a 'l:oT¥ a¥'¥'e:~?~' be ~u.i)l:~i:)r't i ye care., ]"rea ~'me¥~'~ ba:i~:ed o¥~ .j nd,~:~ien'!: o'f ~:he phy~ i c: i al'~ I...,,I L.,.~d,~.,... ~:~LJ~.J;l..1...].~d..( ~ ~Cg]'l"~ ""~ ~'" ,:. . , ~...,~ a¥~d O,..H VE:i'.~T.I.L.~..~ t ION:Co~'~'ro I. a i rbo¥'~'~e c:once~'~'l'ra '? ~ c)~'~3' be I.o~;..~ ~:he exit')sure ,::~t.~ictel. i~'~e U~:e ~nl~, ~.~i~'h a~',:~,:~Lta'('e ven'l'i [a'('io~'~ [~'~c'al. ve¥~'['~l.a~'io¥~ may be ~'tec:es:~:a~"y 'for 3'omc Ol::,era~' (::c)'nce~'~'l:ra'[ i c)¥~ may ex ~:'[' i ¥1 a¥'ea~: ~ i '['h Fd~:5:i::']:i:;~iYTOI:~Y i::'!:~OTi~:CT]:C)i~]: [~'i:~o:~.'pher j c: [eve I.s ;3:hou i. ci be ma in~:a ined .?/.- m... q.. Lte I'i ~' I. ¥' ~" E) p e a 4.~ ~-:"' r'~., c: c) i'1 ~' a ......... i...(- c: c) ~ I. cJ r~ r' c: t.( i" ( R ) ! ~'~ c! i (:: a ~' e.'~: a -i: ~.. a cl e m a r k o 'F T h e ):) o ~..~ C h e ~'~ i c: a I. C o m F, a ~'~ y 8 ~ H ~ i",! ~J) t... I N C, i: ,.,, :F. !., ~ U i ]: 0 N ~':,': ( C; ~.) N T ]: N Li E ,~) ~ EYE F'F'.r.)'¥ECTiON: U!~'e cl~.r...:,r~i ca L gogg I.e~.'~ 9.-. ¢'~ I) .[:..' I 'f' ]1 C) N ~ L~ ~'F'ECi¢fi.. F:'t"d:;C¢~LJT]:ON,.*? T£] t','l:: 'f'¢fi','lEN IN Hr.~.~N.~:'L.];Ni] Al'.!:[) ,S'TOF;,',":'iGE: ,~;ee Label -.. keep ot.~'l: oi'" 'reach c.','l" chi I.d¥'e'r'~... ~)c:, 'nc,'l: I:)~-ea'l:l"Je ga!~',. Keep a L L um'~ec:es.~:ar'¥ peop Le and r.:,e'[':.~' (:)u.'(' o1" al'ca c:o¥~'!:a v i I,.. a 'n e g a .'.-~. ,. L;.' '? o'r e a ~;.~ a ¥ 'r'~" o ~'~'~ h e a 'f a n d d ~.,.~e L I. i n 9 -'.~' ... N,?g,~; ,?'f'¢~'f'U,.?: l:;.:ev i :.--..'ecl 6, '7, a¥'.,d ' " reat cakes MATERIALSAFETY DATA SHEET !! · ~ Chemical Corporation Ii: .-:..., .... : EMERGENCY TELEPHONE (501) 862-5141 .,, . IDENTITY : BROM-O-GAS, TERR-O-GAS 98, 98-2, BROM-O-GAS 15, 0.5% and ';~ ~,:~ ~:.,~:.,~;~?.~:, :~.~. '~0.255 are substantially similar in properties to ~ T,. ' ' · " .' ". ~ '-':~'.'.. ;?: ,' -. ?' ,~:?,:.' 7 ...................... '- ~- - ' ... SECTION I .... PRODUCT '~NFORHAT~ON '":": ?~:'HANUFACTURER'* ~"NAHff '~" GREAT LAKES CHEMICAL 'CORPORATION TELEPHONE NUMBER FOR INFORMATION - (317) 463.-2511 ~:..CAS REGISTRY NO. -174;-83-9; 76-06-2 DATE PREPARED - 10/86 FORMULA - CH3Br;CCL3NO2 SUPERCEDES - 7/86 CHEMICAL FAMILY- Alkyl b~omtde; Halon~troalkane ......... i],PREPARED BY .... Research Services Department ..... ' ........ ..... Great' Lakes Chemical Corporation · West Lafayette, Indiana 47906 SECTION II HAZARDOUS COMPONENTS (Specify Chemical Identity: Common Name(s)) Methyl bromide . C20 ppm (skin); 5 ppm (skin) 5 ppm EPA 98 Chloropicrin 0.1 ppm 0.1 ppm; 0.1 ppm EPA 2 , .. - .- i :~' . STEL'0.3. ppm GLCC Product Code: 200; 275 for T-O-G.98 GREAT ·LAKES CHEMICAL CORPORATION P.O. Box 2200 · Highway 52 NW · West Lafayette, Indiana 47906 ii~'>':,, ',,<,~ Great,Lakes C_~.~ ical Corporation '. f ~. :. !.! ~f page '2!, 't,. ~ - ' ' ,' - ~', ' _ · ' SECTIO ."II - P SICAL/CHEM CAL CHARACTERISTICS · : '-'.:' ........................ (chloropicrin is 23 .'. [ "' Specific.Gravity (water=l) N/A (methyl bromide ~s 1 732) ,: _.,: ...... ' .... , ............ (chloropicrin is 1.66) : .... ~'"' ...... Vapor.'~essure (mm'~g.) N/A-(~ethyl bromide is 1~00 at ' . ' ' ' (chloropicrin is 1~.] at 68~F) i~ ' Melting Poin~ ~/A (ehloropicrin is -83uF ) ': ~ Vapor Density (AIR=l) N/A (methyl bromide is approx. 3.27) Rate Not Available ............ · (Butyl Acetate = 1.) ' Solubility in Water N/A.(methyl bromide is 1.75g/100g) ,i~!i', ,. ..... (chloropicrin is O.2g/lOOg) ..~, Appearance and' Odor:' Colorless liquid with tear gas odor' .'.:~;.,., ~;:... ., below boiling point of methyl bromide ' ' ~" Colorless gas with'tear gas odor at .. .: ~ .normal temperatures and pressures. ~',,< ..',..,.~:.. .-, -.-, --'.-. --.--- .......... . ........ . ..... ~ ~,, SECTION IV '- FIRE AND EXPLOSION HAZARD DATA · . '~"?:~"~;:~.~'Flash Point (Method Used) unknown for Mixture " "'" ' '"' (see below). · fi~i ..'.:'~::.':.:Flammable'Ltmits Methyl bromide in air · :f ~, t . · · . ':: '" ,..,~, UEL '. · 15% i ..~?e.,~;,~ Extinguishing Media :;,. ': ,,~-, ...: :::' ". ~, ',~:- .'- ,::::,,~ ,':.'~ :.~:. ?~':,.'.'.,.. ...: Ail conventional media are suitable . · Special:Fire Fighting Procedures :~ '..:.. Wear sel~-oontained brea~hing apparatus "' Unusual Fire and Explosion Hazarda: Non-flammable in concentrated ~orm. See "Flammable Limits"; 'Chloropicrin decomposes at 112 C to severelY toxic gases especially in contact with metals. Combustion in the presence of other fuels may result in the release of hydrogen bromide and/or bromine or other toxic gases.. Methyl bromide is ignitible by a high energy spark at the flammability limits. '~ r ''i ," ~'~ta't Lakes CJical Corporation · '" '~." ~SDS . BROM-O~JiS ; ' ,, . .:' SECTION V - REACTIVITY DATA .~ '. ;"~,*~ ..... .'~...Stabilit¥ Stable x Unstable .'?:,...:,, >.: .... .~' ~:,,.t..: . .-.'.:Conditions to Av, oid: None known [J[ ?~[ Incompatibility (Materials to Avoid) .:'~.";:... Aluminum, magnesium, zinc, alkali metals, strong alkalis : ' ~:Hazar. dous.;DecomP~siti'on ..tot.- Bypr. oduota'~.~,,~:,.~,~".~,:'~:'~:'? ., Methyl bromide may release hydrogen bromide or bromine' fumes. Chloropicrin will release nitric oxide, HCl, phosgene. ,, Hazardous Polymerization ':~May-Occur .Will Not Occur x · Conditions to.. Avoid: '.... None '-:, SECTION VI :- HEALTH HAZARD DATA ;'~' 'i.;-L~ ~. · .. ' '',' '. '::,~.f ~'Route(s) of Entry.' ,. '. :..[ .i' :' f.::: . Inhalation? .Yes ~ Skin? Yes Ingestion? Yes ..... .~, ............. Health Hazards '(Acute and Chronic).. ,. ,,.t,i!/.i;!:2.;-': :.:i?'"'Aoute.--°'r~i LD~n' (fa,ts)', ehltrop, ierin is 250 rog/kg. 'Acute oral [, Ch~ropicrin and methyl bromide are severe irritants. .: ~'~: ..... . Chloropicrin LC (rabbits) is 150 ppm (15 min.). Methyl ,~' bromide LC (r~bits) is 3120 ppm (15 min.). Inhalation LC. ~ ,~-,..,~,~'.,, ...... (human) isS~o,o00 ppm for 2 hours Methyl bromide is a pois~ ,, ~;.~ and.:..can cause,respiratory distress, cardiac arrest and central '.~ : t,,;~! ,nervous system effects, Overexposure may cause neurotoxic ~",,' ": .effects from/which recovery may be. slow. Methyl bromide ~,~,[..~:.~-., ~. demonstrates genotoxicity in several .test systems at levels .,.~.,~z:..?~'.:-:'; "~!'above the'.TLV, but has not been,found to be carcinogenic in a ..... .~',,,~,~.:~ :. ".,90-day .oral study · in rats.. ~: :-iY~' ~.;~:: :¥ Carcinosenicit¥ :. ' ' ' ~ NTP? No IARC Monographs? No OSHA Regulated? No ,.....~'i'.Great. Lakes'( cal COrporation -.~. MS,DS - BROM-O-GAS :,. page. 4 .. '~' ?i':~'"'F-'~,~!~',$igns and Symptoms of Exposure : :,.:.;~: .... Methyl Bromide: symptoms appear slowly and include: '''.':'~' ·Dizziness, blurring vision, lassitude, sensation of fatigue, ,'~:·<.: :~:.~!,., staggering gait, slurring sPeech, nausea, vomiting, anorexia, ~ ~lack of appetite; high concentrations can cause convulsions, ~...~.~.very high concentrations cause lung damage. Prolonged skin .. .. and eye contact~'can cause.burns. Chloropicrin:' Is a powerfu~ ..... '.. ;:, .-irritant with effects observed on all body surfaces. It' ' · causes tearing, pulmonary edema, vomiting. Severe exposure ~ may cause .weak and irregular heartbeat,, asthmatic attack. ? ' '. -. i:;' ~' · ~ ......... Medical ConditiOns Generally Aggravated by Exposure ,;~,~.~?~-~.·,~..: Existing dermatitis and respiratory problems may.be · ., .~:j .~ij...-.,.aggravated, ..:- .:' . ., ..Emergency and FirSt Aid Procedures ?. ...... · In all cases· Of overexposure, get medical attention ~ ~ immediately. Take person to a doctor or. emergency treatment { .' facility. IF INHALED: Remove exposed person from · . contaminated area. Keep warm. Make sure person can. breathe ~ ..~,::..;.~.~:-:',. freely. If breathing has stopped, give artificial ;. ' ........ ~'!h:~..'~::.~'::"~'.r~espiration.. Give oxygen if needed. If not unconscious, :. rinse mouth out with .water. Seek medical 'a~tention : .' :'?.-~ immediately. IF ON SKIN: Immediately remove contaminated . .clothing, shoes, jewelry, and any other item on skin. Wash i '.. ~ J" '~'' contaminated skin area thoroughly with.soap·and water. IF IN · .~ .; EYES: Hold eyelids open and flush with a steady, gentle-- ~. >.:. stream.of water for at least 15 minutes, ~ S~CTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE :' '--?'.:'-,..:'. .... Steps To'Be, Taken in Case Material iS Rel'eased or. Spilled 'i'{:.:!-::~.,?,: . Evacuate immediate area of spill or 'leak. Use of NIoSH/MSHA approved self-contained breathing.apparatus (SCBA) or " ~.~,:!..i..~. combination,air-supplied/SCBA respirator for entry into " ',"',.:.::. ,:.~!~, ,~.affected area to correct problem. Move leaking or damaged ,~:' ~.::., cylfnders or. containers outdoors or to an isolated location, ~ ; ..... observing Strict safety precautions. Work upwind if possible. Allow spill to evaporate. Do not permit entry into spill area · . by persons without appropriate respiratory protection, until concentration of methyl bromide is determined to be less than . '.5 ,ppm. .! '... ....... ~ .... "i'~.~;~; at~L.akes mical Corporation · '": ~f,,MSDS -~,-BROM-O-GAS ~ '-'?'~.':~'~iiii.:~ :-~-Pesticide wastes 'are toxic, Improper di.sposal of excess ~ "'"~'~;:'~:...? pesticide, spray mixture, or rinsate is a violation of Federal '" ',:.,:~:..,:~': law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or :'. .Environmental Control Agency, or the Hazardous Waste i~, '' .q. representative..at the n~arest EPA ·Regional Office for ~ " ., guidance. Return empty cylinders freight collect to the Great ~' ,ii'~'...."i.I-''. Lakes Chemical Corporation.location from which shipment was ~ ',..'i'i ·made. Close cylinder valve by turning clockwise until hand· .. ~ ..-...i.~ii~.~:~:~i..:,.:.'~'tight, Disconnect lines. Replace safety cap and bonnet. '~ -.":::'ii,;.~i '[i[~:i~.[ii:i'.i Return empty~ and~or p~rtial c~llndems.'.only-after .consulting ii! -" '" ~:~:~:'":~'-~ff~a~ '~ak~s ~hemic'al-:'Corpora~ion for prOper. ~ipping ~' : instructions. ',~.,",,t~.~,~,.,.:..,~PrecaUtions to be Taken in Handling and'Storing ~:.,n.~:z.;.:i......~: 'Store in a locked, dry, cool, well'ventilated area. Post as a · .:~'~:."-/:,.,,pesticide storage area. Do not contaminate water, food, or ~:,' :'~!:'~i'.i,..::i:i'.':..~feed. by storage. Store cylinders upright, secured to a rack ,,. -...,~.~. or wall to prevent tipping. Cylinders should not be subjected "':",: to rough handling or mechanical shock such as dropping, ? ......... .~ . .. ,,,,....,.,."'?'i'~".:~::'.'qbumping,,...,,~ ~,, ~... ..~ dragging, or sliding. Do not use rope slings, hooks, tongs or similar devices to unload cylinders Transport cylinders using hand truck, fork truck or .other device to . !~..,.:~.~:~ which the cylinder can be firmly secured. Do not remove valve ~.:, ,.~-;.i~..~.. protection bonnet and safety cap until immediately before'use. 'Replace safety cap and valve protection bonnet when cylinder ..' is not.in use. When cylinder is empty, close valve, screw. ~ ~'., .safety'cap on to valve outlet, and replace protection bonnet ! ~ ' beforereturning to shipper. Only the registrant is ..i.,.'i' authorized to refill cylinders. Do not use cylinders for any ~:, ., . other purpose. .~ ~' Methyl bromid~ has no odor at dangerOus levels and is ? .~ .~... :....:'extremely hazardous. This product is toxic to fish and : wildlife. Keep out of lakes, streams, and ponds. Do not · contaminate water.by cleaning of equipment or disposal of .... :..'~, wastes., ~" SECTION VIII - CONTROL MEASURES '.'' Respiratory Protection · ,' .. ;.:: . .,.. If the concentration as measured by detector tube exceeds 5 ~: : .ppm of methyl bromide at any time, a!l persons in fumigation ~, area must wear NIOSH/MSHA approved SCBA. . , : . :...':,.~,: :,~--:~...., :-.. . ;- -' :"...:':'...Great Laken cal Corporation ...... " .' ",. '. ':'~: 'MSDS - BROIl-O'GAS 4" .,: ' .~ . "· · i" '~ ':"?""~:" Ventilation ,:h:.,.'-. . . · ' ' ".~:~:~,~;~.,~: Local. Exhaust- Essential when rindo0~ Special , None r... ,..,~,~-:1~ .~.?~.., ~ ~Mechanical.,See~above . .. Other - None ~..,' ..... -~.~' P~o~e~ve. GLoves -,,Do... . no~ uae . .. · ,~: e Protection - y goggl,es below 5 ppm. .: -,.~.~.-..,: Pump and de~ea~o~' ~ubea to~.meaau~ me~ky~ b~om~de . . . concentrations .- .... .. "' ':'""'::"-'"~";':"'~0 en~ a '"'" .... : Practices' : .. :,,'., ......, . ~? '-~. ..:...:., . :' Wear all.necessary protective equipment, wash after handling ,,~ .'. equipment. Nak~ sure piping is empty before doing maintenance, .. {~ :~. ...~ ~,-::.work. Ail persons working wi~h Brom-O-Gas should be ~rained :-~-~ ~.~,mt,:~~ in the hazards, use of required respirator equipment and " .:,,' '~ ,o..~ ~ .detector equipment, emergency procedures and in the proper use . : .~.~.,.~ ..~ of Brom-O-Gas as a fumigant where applicable. .~ ~ :2. ~ ~.', ,: Information on this form is furnished solely for the purpose of, .~ ?.~._ compliance with OSHA's Hazard Communication Standard, 29CFR .:,p;.~ ~1~.,10..1200 and shall not be used for' any other purpose. - DLM.c.F/db: 18 -.