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HomeMy WebLinkAboutRISK MANAGEMENT 12/20/1991 ARCO PRODUCTS COMPANY RISK ANALYSIS REPORT ARCO SERVICE STATION NO. 1960 1701 BRUNDAGE LANE ' ~ '.' BAKERSFIELD, CALIFORNIA " DECEMBER 20 1991 S. KATERI A. LUKA ~CO PRODUCTS COMPANY O. BOX 6411 1TESIA~ CAMFORNIA 90702~411 ~ 3) 402-1281 ANALYSIS REPORT VICE STATION NO. 1960 BRUNDAGE LANE ;FIELD, CALIFORNIA CEMBER 20, 1991 JNDWATER TECHNOLOGY, INC. kLKEN STREET, SUITE B-1 :ISFIELD, CALIFORNIA 93308 ;89-8601 REVIEWED BY: · .<~, .~ _.:/¥' ~ ,.-'/L '- ~ ~-- :-- -/ ;>STEPHAN A. BORK, PROJECT GEOLOGIST TABLE OF CONTENTS PAGE 1.0 EXECUTIVE SUMMARY ....................................................... 1 2.0 INTRODUCTION ............................................................ 2 3.0 SITE BACKGROUND ......................................................... 2 4.0 REGIONAL SETTING ......................................................... 2 5.0 RISK ANALYSIS ............................................................. 3 5.1 SESOIL Modeling ..................................................... 4 5.1.1 Model Input Parameters .............................................. 5 5.1.1.1 Sediment Characteristics ......................................... 6 5.1.1.2 Contaminant Application ......................................... 7 5.1.1.3 Conservatism ................................................. 8 5.1.2 SESOIL Output .................................................... 8 5.2 Inhalation Risk ........................................................ 8 6.0 SUMMARY AND RECOMMENDATIONS .......................................... 11 7.0 REFERENCES ............................................................. 12 Risk Analysis Report ARCO Products Company GROUNDWATER December 20, 1991 ii ~,L_2~ r:TECHNOLOGY - LIST OF lU. USTRATIONS TABLES Table 1. Analytical Results, Soil Samples Beneath Tanks .................................. 3 Table 2. Analytical Results, Soil Samples From Borings ................................... 4 Table 3. Leaching Potential Analysis .............................. ,. .................. 5 Table 4. General Risk Appraisal Applicability Checklist .................................... 6 Table 5. Maximum Pollutant Depth and Transportation Rates ............................... 9 Table 6. Comparison of Calculated Exposure Levels and Noncancer Acceptable.Exposure Levels... 10 FIGURES Figure 1. Location Index Figure 2. Site Map/Boring Locations Figure 3. Cross Section A Figure 4. Site Geology Figure 5. Depth to Groundwater Figure 6. Groundwater Gradient Figure 7. Soil Compartments Figure 8. Application Area APPENDICES Appendix A. SESOIL Climate and Chemical Data Input Appendix B. 95% Upper Confidence Level and Pollutant Load Calculations Appendix C. Abbreviated SESOIL Output Files Appendix D. SESOIL Output File Diskettes Appendix E. Abbreviated SESOIL Output Files -- Inhalation Risk Appendix F. SCREEN Output Files Risk Analysis Report ~---~.~, ARCO Products Company ,,'~._j,~ ~'~iGROUNDWATER December 20, 1991 iii ;~,;TECHNOLOGY 1.0 EXECUTIVE SUMMARY Seven borings have been drilled and sampled to assess subsurface conditions at ARCO facility no. 1960. Laboratory analysis of soil samples collected during assessment activities indicates gasoline hydrocarbons are present below the former location of underground storage tanks. Total petroleum hydrocarbons as gasoline ('rPHG) and benzene concentrations range from < 10 to 2,400 mg/kg and < 0.005 to I mg/kg, respectively. These maximum concentrations of were detected at a depth of approximately 15 feet. Site conditions do not allow the use of leaching potential analysis or general risk appraisal methods to determine acceptable concentrations of hydrocarbons which can be left In place without threatening groundwater (LUFT, 1988). A detailed site-specific analysis using the SESOIL model indicates that the concentrations of benzene, toluene, ethylbenzene, and total xylenes (BTEX) present at the site will not impact groundwater within a 99 year simulation. An evaluation of inhalation health risk using emission rates determined by SESOIL, resulting ambient air concentrations determined by the SCREEN model, and CAPCOA (1991) guidelines, indicates cancer risk from benzene is approximately one in ten million, the compounds evaluated do not exceed acceptable exposure levels, and the cumulative affects of benzene and toluene on the central nervous system are not considered adverse to health. Possible remedial action alternatives considered for the site include no action, soil venting, and excavation. No action is the preferred alternative because contaminant transport modeling indicates groundwater will not be impacted and health risks from inhalation are below acceptable levels. Soil venting is considered feasible but cost prohibitive. The excavation alternative is not considered feasible because of high cost and the required destruction of surface facilities. Risk Analysis Report ~--~-~.~ ARCO Products Company ',~L__]?___~,~ GROUNDWATER December 20, 1991 1 ':~' ~. " [' ,'L_ji~!TECHNOLOGY APPENDIX A SESOIL Climate and Chemical Data Input ~GROUNDWATER [~_~[-~_~!TECHNOLOGY 2.0 INTRODUCTION Groundwater Technology, Inc. has been contracted by ARCO Products Company to perform a dsk analysis for hydrocarbon contamination at their facility no. 1960 in Bakersfield, California (Figure 1). The purpose of the analysis is to determine if hydrocarbon contamination which is present at the site will impact groundwater or pose an inhalation risk. This report documents the findings of the analysis. 3.0 SITE BACKGROUND A preliminary assessment of soil conditions was completed at the site in October, 1990. The assessment consisted of drilling three borings (B1 - B3) at the locations shown in Figure 2. Laboratory analysis of soil samples indicated concentrations of benzene, toluene, ethylbenzene, and xylenes (BTEX) and total petroleum hydrocarbons as gasoline (TPH) were below detection limits in most samples analyzed. One sample exhibited a xylenes concentration of 1.0 mg/kg. Existing gasoline storage tanks were removed in October, 1990 (GTI, 1990). Samples collected at that time indicated the presence of gasoline hydrocarbons beneath former tanks 1, 2, and 3, and beneath two of three dispenser islands (Table 1). Subsequently, Groundwater Technology completed a site characterization study which included the completion of four additional borings (GTI, 1991). Gasoline hydrocarbons were encountered at levels exceeding 1000 mg/kg in one of these borings (Table 2). A cross section showing the distribution of hydrocarbons is presented in Figure 3. 4.0 REGIONAL SETTING The site is located on the alluvial plain of the Kern River. Topography in the region is fiat, and no natural bodies of water adjoin the site. The station is located in a commercial area and is approximately 2,500 feet southeast of the nearest school. The site ovedies alluvial-fan deposits of the Kern River (Figure 4). Sediments underlying the region consist of fluvial deposits including silt, sand and gravel. Sediments encountered during drilling and excavation activities at the site consist primarily of fine- to coarse-grained sand. Risk Analysis Report ~~ ARCO Products Company GROUNDWATER Oecember 20, 1991 2 L~__J[_._JL._.JI!I~--~-~--~iq~ECHNOLOGY Table 1. Anal~ ~(ical results (in mg/kg) of soil sam :)les collected from beneath tanks on 10/23/90. Sample # Benzene Toluene Ethyl- Total TPH as benzene Xylenee Gasoline T1 S-2' <0.05 4.6 1.7 90 1800 T1S-6' <0.05 0.95 0.93 65 1500 T1N-2' I 24 29 400 2400 T1N-6' 0.3 36 8.6 96 1600 T2S-2' < 0.05 2.6 2.2 47 730 T2S-6' < 0.05 0.09 0.17 3.6 300 T2N-2' < 0.05 2.1 1.7 21 170 T2N-6' 0.56 42 17 200 1500 T3S-2' < 0.05 2.4 2.5 33 280 T3S-6' < 0.05 < 0.05 < 0.05 0.14 < 10 T3N-2' < 0.05 < 0.05 < 0.05 < 0.05 < 10 T3N-6' <0.05 <0.05 <0.05 <0.05 < 10 T4S-2' <0.05 <0.05 <0.05 0.05 < 10 T4S-6' < 0.05 < 0.05 < 0.05 < 0.05 < 10 T4N-2' <0.05 <0.05 <0.05 <0.05 < 10 T4N-6' < 0.05 < 0.05 < 0.05 < 0.05 < 10 An unconfined aquifer is present below the site at a depth of approximately 175 feet (Figure 5). The gradient of this aquifer is generally toward the southeast (Figure 6). Shallow, perched water has not been identified in the vicinity of the site (KCWA, 1990). 5.0 RISK ANALYSIS The state Leaking Underground Fuel Tank Field Manual (LUFT 1988) establishes three methods to determine if soil contamination can be left in place without threatening groundwater. These methods vary greatly in their specificity and complexity. The most generic and least complex is a leaching potential analysis which considers four site characteristics: depth to groundwater, subsurface fractures, precipitation, and the presence of man-made conduits. Based on conditions present at the site, contamination levels exceed those determined as acceptable by the leaching potential analysis (Table 3). Risk Analysis Report ir ARCO Products Company i~ GROIJNDWATER December 20, 1991 3 Table 2. Analytical results (in mg/kg) of soil samples collected from borings on March 4 and 13, 1991. Sample No. Benzene Toluene Ethyl- Xylenes TPHG benzene B4-15' < 0.005 0.12 0.083 2.2 27 B4-35' < 0.005 < 0.005 0.005 0.10 < 10 B5-15' 0.050 7.3 7.1 150 1900 B5-35' <0.005 0.006 0.006 0.11 < 10 B6-10' 0.018 0.037 0.099 6.2 170 B6-25' <0.005 <0.005 <0.005 <0.015 < 10 B7-19' 0.017 0.046 0.33 5.5 200 B7-34' <0.005 <0.005 <0.005 <0.015 < 10 As stated in the LUFT Manual, the leaching potential analysis provides 'a simplified way to assess the possible threat to ground water from contaminated soils. Alternative cleanup levels, based on additional site specific analysis, would supersede the initial allowable levels" (LUFT, 1988, p 21). The second method, general risk appraisal, uses a "simulated environmental system that adapts two computer models to estimate the concentration of BTX&E that can be left in place ... without risking ground water pollution" (LUFT, 1988, p 23). These models are SESOIL (Bonazountas and Wagner, 1984) which addresses contaminant transport in the unsaturated zone, and AT123D (Yeh, 1981) which addresses contaminant transport in the saturated zone. These models have been used to create a method to determine the concentrations of BTEX which can be left in place without threatening groundwater. Work sheets and tables are presented in the LUFT Manual which can be utilized without actually modeling conditions at each specific site. However, this method was developed for sites which meet specific applicability criteria. Conditions present at the ARCO site do not meet those criteria (Table 4). At sites where the general risk appraisal is not appropriate, the LUFT manual suggests substituting "a more detailed site-specific analysis, employing the two models (SESOIL and AT123D) used in the general risk appraisal" (LUFT, 1988, p 24). A more detailed analysis of site conditions using the SESOIL model is presented below. Risk Analysis Report ARCO Products Company ~--~[]CROUNDW./¥~ER December 20, 1991 4 I~[],?_~iTECHNOLOGY Table 3. Leaching potential analysis for gasoline using TPH and BTEX. Modified from the LUFT Manual (1988, p 27), Score 10 Score 9 Score 5 Site Feature Score Pts. if Score Pts. if Score Pts. if Condition Condition Condition is Met is Met is Met Minimum depth to water 10 > 100 51 - 100 25 - 50* from the soil sample. Fractures in subsurface (applies to foothills or 10 None Unknown Present mountain areas). Average annual precipitation 10 <10 10 -25 26 - 40** (inches). Man-made conduits which increase vertical migration of 10 None Unknown Present leachate. Unique site features: recharge area, coarse soil, None 9 At Least More Than nearby wells, etc. One One Column Totals - Total Points 40 + 9 + 0 = 49 Range of Total Points 49 Pts. or More 41 - 48 Pts. 40 Pts. or Less Maximum Allowable BTX&E Levels (ppm) 1/50/50/50 .3/.3/1/1 N/A*** Maximum Allowable TPH Levels (ppm) 1,000 100 10 * If depth is greater than 5 feet but less than 25 feet, score 0 points. If depth is 5 feet or less, this table should not be used. ** If depth is over 40 inches, score 0 points. *** Levels of BTX&E are not applicable to TPH concentration of 10 ppm. 5.1 SESOIL Modeling SESOIL is a mathematical model that simulates long-term environmental fate of pollutants in the unsaturated zone. The model describes water transport, sediment transport, pollutant fate, pollutant migration to groundwater, and soil quality within as many as four user-specified compartments representing different soil types. Risk Analysis Report ~--~ ARCO Products Company ~it I! IL~'~I!(;ROUND.W~A~ER December 20, 1991 5 TECHNOLO~;¥ Table 4. General risk appraisal applicability checklist (LUFf, 1988, p 29). GENERAL RISK APPRAISAL FOR PROTECTION OF WATER GUAM'I'Y: YES NO APPMCABIUTY CHECKMS'I'* 1. Is the site in a mountainous area (shaded moist areas and/or areas X with rocky subsurface conditions)? 2. Is the site in an area which could collect surface runoff or collect or X intercept water from a source other than natural precipitation? 3. Does the areal extent of soil contamination exceed 100 m27 X 4. Do the concentrations of fuel constituents in any soil samples exceed the following amounts: benzene - 100 ppm, toluene - 80 ppm, X xylene - 40 ppm, ethylbenzene - 40 ppm? 5. Are their any records or evidence of man-made or natural objects which could provide a conduit for vertical migration of leachate? X 6. Do any boring or excavation logs show the presence of fractures, joints or faults that could act as a conduit for vertical migration of X leachate? 7. Do any boring logs show that contaminated soil could be within 5 feet of highest groundwater?. X 8. Do any boring logs show the presence of a layer of material, 5 feet thick or more, which is more than 75% sand and/or gravel? X * "If any of the questions on the checklist cannot be answered no, then the results of the general risk appraisal may be less than valid." (LUF-I', 1988, p 38). 5.1.1 Model Input Parameters A site-specific risk analysis of the potential for BTEX to impact groundwater at the ARCO site requires the determination of several input parameters. Climatologic and most chemical parameters are compiled from well-established databases (Appendix A). The rate of natural biodegradation of the compounds simulated is conservatively estimated at 0.002% per day. This is the same rate used by the LUFT Task Force in the development of the general risk appraisal (LUFT, 1988, p 87). Several physical parameters require some interpretation. These parameters, and the basis of their determination, are described below. 5.1.1.1 Sediment Characteristics Sediment characteristics required as input for SESOIL modeling include bulk density, effective porosity, disconnectedness, organic-carbon content, and intrinsic permeability. Bulk density and effective porosity are estimated to be 1.35 g/cm3 and 30% respectively for this simulation. These values are typical of the sediments encountered during this assessment. Risk Analysis Report ARCO Products Company The disconnectedness index relates intrinsic permeability to soil moisture. Disconnectedness is defined as: c = A[In(k)]/AIn(SO)] where c = soil disconnectedness Index, k = intrinsic permeability, and So = the long-term average soil moisture concentration. Disconnectedness in sediment typically ranges from 3 to 12, and can .,be varied to calibrate the model to reflect expected moisture concentrations. A disconnectedness index of 7.5 is used in this simulation. Hydrocarbons adsorb to organic carbon which occurs naturally in sediments. Once adsorbed, the hydrocarbons are essentially immobile. The percent organic carbon present in sediment at the ARCO site has been conservatively estimated to be 0.02%. This is the same value used by the LUFT Task Force in the general risk appraisal (LUFT, 1988, p 87). Intrinsic permeability is determined by comparison of the lithologies encountered at the site with permeability data compiled in Freeze and Cherry (1979). Their data represents ranges of permeability expected for given sediments based on observed grain-size distributions. The value representing the more-permeable, upper-75th percentile of their data is used. 5.1.1.2 Contaminant Application A partial list of the application parameters required for the SESOIL simulation includes the number of soil layers present in the system and their respective thicknesses, the area impacted by the contaminant, and the total mass of contaminant in each layer. Three soil layers are simulated for this site (Figure 7). These layers are segregated based on general sediment characteristics. The bottommost layer is assumed to be a well-sorted, permeable sand. Concentrations used in estimating total hydrocarbons in place are determined using the 95% upper confidence level (95% UCL) as described by Witte (1989) at each 5-foot depth horizon where more than one data point is available. The level is derived using the following equation: 95%UCL=x+ (1.96*s/n°'5) where x = mean, s = standard deviation, and n = the number of samples analyzed (Appendix B). Total hydrocarbons in place are calculated by multiplying the 95% UCL times the mass of soil in each 5-foot subcompartment of soil. At horizons with only one data point, that value is assumed to represent hydrocarbon concentration at that depth. Note that the concentration used for each layer is the most Risk Analysis Report ~GROUNDWATER ARCO Products Company December 20, 1991 7 I~--~[~--][TECHNOLOGY conservative value reported or calculated. For example, in cases where samples at depth yield a higher concentration than data from shallower subc, ompartments, the higher concentration is substituted (Appendix B). For this simulation, the application area for contaminants is approximated as shown on Figure 8. Pollutant load (.ag/cm2) is calculated by dividing the total mass of hydrocarbons per soil compartment by the application area (Appendix B). 5.1.1.3 Conservatism Input parameters are chosen to represent conservative site condition& In determining risk to groundwater, the simulation is calibrated such that all rainfall infiltrates the soil column and evapotranspiration is minimized. This simulation is also calibrated such that no pollutant is lost to the atmosphere through volatilization. In effect, the site is considered uncapped with respect to precipitation and completely sealed with respect to pollutant loss to the atmosphere. Using the 95% UCL helps ensure that contaminant concentrations are estimated at their highest level. Additionally, this concentration is used to characterize the entire lateral extent of each compartment simulated, disregarding lateral decreases in pollutant concentrations.. 5.1.2 SESOIL Output SESOIL generates data for each month of each year simulated. Output includes information about the hydrologic cycle (e.g. precipitation, evapotranspiration, etc.) and the distribution of pollutant in the soil column (e.g. concentration and depth). The period simulated for this analysis is the maximum SESOIL allows -- 99 years. The transport rate and maximum depth that each pollutant reaches at the end of the 99 year period is listed in Table 5. None of the chemicals modeled impact groundwater within the simulation period. Condensed SESOIL output files are presented in Appendix C. Complete output files stored on diskettes are also attached (Appendix D). 5.2 Inhalation Risk Inhalation risk is determined using emission rates calculated by the SESOIL model, resultant ambient air concentrations calculated using the model SCREEN (Brode, 1988), and risk assessment screening guidelines described by CAPCOA (1991). Cancer risk is evaluated for benzene and noncancer health effects are evaluated for benzene, toluene and xylene isomers. A separate SESOIL simulation is used to determine emission rates at the surface of the site. Input parameters are identical to those used in determining groundwater risk with the exception of Risk Analysis Report ~ ARCO Prociucts Company GROUNDW^TER December 20, 1991 8 ITECHNOLOGY Table 5. Maximum pollutant depth and transport rates for SESOIL simulation. Year Maximum Pollutant Depth in Soil (ft) Simulated I Benzene Toluene Ethylbenzene I Xylenes I 23 23 22. 23 10 27 25 23 24 20 31 28 24 26 30 35 31 24 28 40 51 34 25 30 50 67 43 25 31 60 83 54 26 33 70 99 66 26 36 80 115 77 27 43 90 131 88 28 50 99 ~146 't 98 28 56 Transport Rate (ft/yr) ? 1.49 ? 0.77 0.06 0.34 volatilization index. In determining groundwater risk, no volatilization was allowed, thereby maximizing pollutant concentrations in soil. In determining compound emission rates, 100% of the calculated volatilization is allowed. A 5 year simulation indicates compound emissions are highest at the beginning of the simulation and decrease steadily with time (Appendix E). The maximum emission rate calculated is used as input to the EPA model SCREEN (Brode, 1988) to determine resulting ambient air concentrations. For the purposes of the SCREEN simulation, an area source measuring 20 feet by 20 feet located in an urban setting is considered. The maximum 1-hour ambient air concentration of benzene calculated by the SCREEN model is 0.02 /~g/m3 (Appendix F). Following CAPCOA (1991) guidelines, this concentration is converted to an annual average by multiplying by 0.1. The annual average concentration can be used to determine individual excess cancer risk using the following: R = x*UR*L/70yr where R = individual excess cancer risk, x = pollutant concentration (/~g/m3), UR = unit risk factor [~g/m3)-~], and L = lifetime of the project (CAPCOA, 1991). Given a maximum unit risk factor of 5.3e-5 ARCO Products Company i~ ~[a~.!~ GROIJNDWATFR December 20, 1991 9 for benzene, the individual excess cancer risk for the maximally exposed Individual is 1.06e-7 (approximately one in ten million) in a 70 year lifetime. An evaluation of noncancer health effects can be made by comparing ambient air concentrations with established noncancer acceptable exposure levels 0'able 6; CAPCOA, 1991'). Because benzene and toluene affect the same target organ, the central nervous system (CNS), a I~,~rd index is developed following CAPCOA guidelines to evaluate cumulative adverse health effects. This method assumes the adverse effects for the individual compounds are additive. Estimated exposures to the two compounds are divided by their respective acceptable exposure levels and the resultant ratios summed; If the hazard index is greater than or equal to one, a potential health hazard may exist. The inhalation risk evaluation incorporates several conservative assumptions. Two specific assumptions are: e The site is considered uncapped. Volatilization is maximized in the SESOIL simulation used to calculate inhalation risk; and e The maximum emission rate calculated from the SESOIL modeling is considered constant for the analysis. In fact, the emission rate decays steadily with time (Appendix E). In spite of these conservative assumptions, the inhalation risk evaluation, following CAPCOA (1991) guidelines, indicates that: the cancer risk from benzene is less than 1 x 10~; none of the compounds evaluated exceed acceptable exposure levels; and the cumulative affects of benzene and toluene on the central nervous system are not considered adverse to health. Table 6. Comparison of calculated exposure levels and noncancer acceptable exposure levels. Acceptable exposure levels from CAPCOA (1991). Substance Calculated Acceptable Health Hazard Ratio for CNS Exposure Level Exposure Level (Calculated + Acceptable) 0,g/m Benzene 0.02 71 2.82 x 10.4 Toluene 15.11 2000 0.01 Ethylbenzene 7.806 ND N/A Xylenes 22.69 300 N/A II Hazard Index = 0.01 ND = None developed. N/A = Not applicable. Compound does not affect central nervous system (CAPCOA, 1991, Table 111-10) Risk Analysis Report ARCO Products Company December 20, 1991 10 6.0 SUMMARY AND RECOMMENDATIONS The preferred remedial action plan at this site is no action. Specific reasons for this recommendation are: the buffer zone between impacted soil and groundwater is approximately 125 feet, and. the SESOIL modeling indicates that BTEX will not reach groundwater during the 99 year simulation period; e an evaluation of health risk through inhalation pathways indicates noncancer acceptable exposure level are not exceeded, additive cumulative affects to the central nervous system from benzene and toluene are acceptable, and cancer risk from benzene is less than I x 10'6; ~ New double-walled storage tanks have been installed at the facility, thus eliminating the source of contamination in the area of the former tanks. As discussed in the site assessment report (GTI, 1991), soil venting is a proven technology which will remediate the plume in a shorter time frame than natural degradation. However, implementation costs are high. Excavation as an alternate means of remediation is not considered feasible due to high costs, worker safety concerns, and damage to surface structures. Risk Analysis Report ^R0O.roduc,scompa.y [ [][]C.OUNDW^TE. OecemO,r =0. ~S~ 11 ~ TECHNOLOCV 7.0 REFERENCES BonazOuntas, M., and J. Wagner, 1984, SESOIL: a seasonal soil compartment model: A.D. Uttle Inc., for U.S. EPA contract #68-01-6271, Cambridge, MA. Brode, R.W., 1988, Screening procedures for estimating the air quality Impact of stationary sources (draft): U.S. Environmental Protection Agency Publication EPA-450/4-88-010. California Division of Mines and Geology, 1975, Geologic Map of California, Bakersfield sheet. CAPCOA (California Air Pollution Control Officers Association), 1991, Air toxics "hot spots" program, risk assessment guidelines. Freeze, R.A., and J.A. Cherry, 1979, Groundwater: Prentice-Hall, Inc., Englewood Cliffs, NJ. GSC (General Sciences Corporation), 1990, Riskpro - environmental pollution modeling system: Laurel, MD. GTI (Groundwater Technology, Inc.), 1991, Site characterization report, ARCO service station #1960. GTI (Groundwater Technology, Inc.), 1990, Tank removal report, ARCO service station #1960. Howard, P.H., 1990, Handbook of environmental fate and exposure data for organic chemicals, v. 1 & 2: Lewis Publishers, Chelsea, MI. KCWA (Kern County Water Agency), 1990, 1989 Report on water conditions - improvement district no. 4. NOAA (National Oceanic and Atmospheric Administration), 1989, Local climatological data, annual summary with comparative data for Bakersfield, California: ISSN #0198-696, Ashville, NC. Witte, R., 1989, Statistics, third edition: Holt, Reinhart and Winston, Inc., the Dryden Press, NY. Yeh, G.T., 1981, AT123D: analytical transient one-, two-, and three-dimensional simulation of waste transport in the aquifer system: Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN. Risk Analysis Report ARCO Products Company L~,~,!GROUNDWATER December 20, 1991 12 ~j[__~_2~! TECHNOLOGY FIGURES GROUNDWATER TECHNOLOGY -~Sife N JOI) ~ 215 S~TE~ ARCO SS #1960 .350 0603 SITE LOC: 170~ Brundoge Lone Bakersfield, CA NAP TYPE, Location Index SCALE: DRAWN BY: DATE: IAPPROVED BY: MH 10/90 I REVI$IDN 1/2 0 1/4 1/2 mites Source: Hoven & Co. Inc. I FIi3URE 1~_~II4H-~I~"~"~*,,~,~, Bru"n, dage Lane LEGEND L.... Planter II ~ Boring Locotion II SI2 (o [] a) xx I - - SCALE: ~ 20' 0 I0' 20' ~ SI3 SITE, # 022 ARco ss SIT£ LOC, 1701 Brundage Lane .~, Bakersfield, CA, J~~~qr-B2 FormerTanks ~AP ~PE, Site Map q ~' ~ DRA~N ~Y, I DATE, [APPROVED ~Y, BATE, A A' West East; B5 B5 B4 B2 Former Tank 5'_ Excavation _ 5' <0.05 _10' 10'_ '~ 5' <0.05 0.05 ~o <0.005 '%'f6- _15' < 10 ? 1900 27 0.3 .0.56 / 20'_ <0.05 X1600 5:~ _20' <10 ? ? , / Scale: _25' ~ --_ ? ._T P H < IO_Q_~ -? 5' o' 5' _.50' SITr,ARCO SS #1960 ~ "022 B4 proiected north, 1127 B5 proiected south. SIT[ uno 1701 Brundoge Lone Bokersfield~ CA. Vertical scale -- Horizontal scale. <0.005 <0.005 _35' DESCRIPTION:Cross-Section A <0.005 - Benzene in mg/kg. <10 <10 < 1 0 TPH DRAVN BY,[ DATE, APPRflV£D BY, DATE, SABI 12/91 JOP 12/91 x-Tonk pit somple, proiecfed south. <0.05 ~40' I I I~ <10 ,FIGURE 3 ,II lql~l~Rou,,~^,£, , IL I .m ' ~L.--II T£CHNDLDGY, INC. :'~.~.:~.-~ ~? ... .~..% · . ~ u~ ........... .. .... ~ . ,......, ..... . 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',... :. · ..'. f..~ ;.:: V-~.: ,-.'-,k~., -,.:.. :~'~. ~:....,.~ .'.'" .'...:~ :?" '" "'"'s ~,.... .~ ~, .: . ~...,: ~-~. ~'~ . [.~,~...~' ~,~...:.:l.~:;~ fi,~:.';..:..:..:..:i.::~ :. -55S~te Legend] , ~ Stream channel } ~ Osc deposi~ "c~ ' Fan deposi~ .',:.~9.'.'. Basin deposi~ ~ "215 SZTS=ARCO ~ ~960 ~5o SITE Bokersfield, CA SCALE: MAP TYPE, Site Geology' Source: CDMG Bakersfield Sheet j FIGURE 4 ! · ' ~.~ = '- , . I~ ~ ' ] ~,' x. ,~.I ~' ' ". ~ ~=' ~l- ' .!}. , !' , ~ ~ ' / S te Legend , ,10'~ Depth to Croundwater ua~ . 215 s~E, ARCO SS~1960 35o o603 SITE LBC: SCALE: Bakersfield, CA ~ ~A~ T~PE:Depth to Croundwater 4000 0 aO00 4000 DRAUN BY' I DATE' Feet JOP 11/90 Source: K.C.W.A. Report, 1990 [FIGURE 5 Sire Legend .. Groundwater Elevation JaB # 215 SITE, ARCO SS#1960 .350 0603 SITE LBO SCALE, Bokersfield, CA NAP TYPE, Groundwater Gradient 4000 0 eO00 4000 DRA~,/N ~Y, I DATE, IAPPRaVED BY, Fee't: JDP I 11/90 I Source: K.C.W.A. Report, 1990 I FIGURE 6 I ]~--~,~,%,,¢. A A' West East B3 B5 B4 132 5'_ Soil Layer 1 _5, 10'_ _10' 15'_ ~ _15' 20'_~ _20' Soil Layer 2 Scale: _25' ~ 5' O' 5' _$0' SZTE,ARCO SS #1960 ~ "022 B4 projected north, il 27 B5 projected south. SZTELnO 1701 Brundage Lane Vertical scale = Horizontal scale. Bakersfield, CA. I __35' D£SCRIPTInN, Soil Compartments DRAWN BY,I DATE, APPRBVED BY, J DATE, SAB 12/91 JDP 12/91 Soil Layer 3 Soil Layer 3 extends fo 300'. --I[ ,~_ ~40' Ir~GuRr 7 J ~,~=:r¢~",,c. Brundage Lane LEGEND ~ Planter j I SI1 I B7¢ ~ ~ C ~ DO ~ B1 II ~ Boring Location II II II $12 ~.~ (O [] 0 \\ I \\ I - scat;: ~ 20' o 1 o' 2o' lm ~ 022 StT~, ARCO SS ~1960 50 ???? SITE LOC, 1701 Brundage Lane Bakersfield, CA. ~ B2 Former HAP TYPe, Application Area , Tanks Application = ~qr~n ---n~'~ ~RAVN ~Y,mDATE' IAPPROV[D BY, ~ATE, '~ Area I I1 B41 II I SAB 12/gl ] JDP 12/gl ~5 $ I II I~ I Table. A1. Chemical input data for the SESOIL simulation. Parameter Benzene Toluene Ethyl- Xylenes Reference benzene Solubility 1790 534.8 161.0 156.0 Howard, (mg/I) 1990 Diffusion Coeff. in Air 0.087 0.083 0.076 0.076 Lyman, et al, (cm2/s) 1990 Henry's Law Constant 0.00543 0.00594 0.00844 0.00768 Howard, (atm-m3/mol) 1990 Adsorption Coeff. on 98.0 331.13 870.98 870.96 GSC, 1990 Carbon, (I/kg) Biodegradation Rate 0.002 0.002 0.002 0.002 LUFT, 1988 (%/day) Molecular Weight 78.1 92.14 106.17 106.17 Howard, (g/mol) 1990 Table A2. Climate input data for the SESOIL simulation. Precipitation data is from NOAA (1989). Evapotranspiration is at the most minimal level SESOIL will allow. Storm-pulse data is from Riskpro (GSC, 1990) databases. Precipitation (cm) 2.62 2.54 2.54 1.55 0.74 0.20 0.03 0.08 0.33 0.84 1.42 1.98 Evapotranspiration 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 (cm/day) Mean Time Rainfall 0.40 0.40 0.37 0.33 0.16 0.04 0.01 0.04 0.10 0,14 0.33 0.37 (days) Mean No. Storms 2.94 2.74 2.42 1.82 0.51 0.14 0.09 0.11 0.41 0.80 1.77 1.85 (-) Mean Season 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 .30.4 (days) L--~ L-J~l[ GROUNDWATER ~,~ ~ITECHNOLOGY APPENDIX B 95% Upper Confidence Level and Pollutant Load Calculations i,' ,~ ~ I~: GROUN DWATE R Table B1. Calculation of 95% UCL for benzene. 5-10' 0.018 0.018 N/A N/A 10-15' <0.035 0.05 1 <0.05 <0.05 <0.05 0.19 0.40 0.51 1 5-20' 0.3 < 0.05 0.56 < 0.05 0.23 0.26 0.48 20-25' <0.005 0.0025 N/A N/A 25.30' 30-35' < 0.005 < 0.005 0.0025 0.03 0.0025 * Blanks indicate no data available. N/A = Not applicable to one data point. < Indicates sample did not exceed listed detection limit. A concentration of 1/2 the MDL is then used for calculations. Table B2. Calculation of 95% UCL for toluene. Sample - Sample ~ With/lnalyte 5-10' 0.037 0.037 N/A N/A 10-15' 0.12 7.3 24 4.6 2.1 2.6 6.79 8.78 13.8 15.20' 36 0.95 42 0.09 19.8 22.4 41.7 20-25' <0.005 0.0325 N/A N/A 25-30' 30-35' <0.005 0.006 0.0043 0.0325 0.01 * Blanks indicate no data available. N/A = Not applicable to one data point. < Indicates sample did not exceed listed detection limit. A concentration of 1/2 the MDL is then used for calculations. Table B3. Calculation of 95% UCL for ethylbenzene. 0-5' 5-10' O.Og9 0.099 N/A N/A 10-15' 0.083 7.1 29 1.7 1.7 2.2 6.96 11.1 15.8 15-20' 8.6 0.93 17 0.17 6.68 7.87 14.4 20-25' <0.005 0.0025 N[A N[A 25-30' 30-35' 0.005 0.006 0.006 0.001. 0.006 * Blanks indicate no data available. N/A = Not applicable to one data point. < Indicates sample did not exceed listed detection limit. A concentration of 1/2 the MDL is then used for calculations. Table B4. Calculation of 95% UCL for xylene isomers. 0-5' 10-15' 2.2 150 400 90 21 47 118 148 237 15-20' 96 65 200 3.6 91.2 82.1 172 20-25' <0.015 0.0075 N/A N/A 25-30' 30-35' 0.10 0.11 0.11 0.01 0.11 * Blanks indicate no data available. N/A = Not applicable to one data point. < Indicates sample did not exceed listed detection limit. A concentration of 1/2 the MDL is then used for calculations. ~! GROUNDWATER ?~J~--~TECHNOLOCY Table B5. Upper confidence levels and mass of hydrocarbons In place per 5-foot depth Increment. Total pollutant per compartment is divided by the application area (446,000 cm2) to derive )ollutant loads. Concentrations in/~g/g, masses in/~g, and pollutant load in/~g/cm2. Depth Benzene I Toluene IEth benzene I Xylene. Interval 0-5' 0.51 4.68e7 41.7 3.83e9 15.8 1.45e9 237 2.17el 0 5-10' 0.51 4.68e7 41.7 3.83e9 15.8 1.45e9 237 2.17e10 Mass in Layer I 9.36e7 7.66e9 2.90e9 4.34e10 Pollutant Load 210 17,180 6500 97,300 10-15' 0.51 4.68e7 41.7 3.83e9 15.8 1.45e9 237 2.17e10 15-20' 0.48 4.40e7 41.7 3.83e9 14.4 1.32e9 172 1.58e10 20-25' 0.0025 ' 2.29e5 0.0025 2.29e5 0.0025 2.29e5 O. 11 1.01 e7 25-30' 0.0025 2.29e5 0.0025 2.29e5 0.0025 2.29e5 0.11 1.01e7 30-35' 0.0025 2.29e5 0.0025 2.29e5 0.0025 2.29e5 0.11 1.01e7 Mass in Layer 2 9.15e7 7.66e9 2.77e9 3.75e10 Pollutant Load 205 17,180 6,210 84,150 i[ [ ]iTECttNOLOGY POi- INP-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+ O0 TRNSFORM~L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+OO O.OOE+O0 SINKS-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE + O00.OOE+O0 LIG.INPUT-L (UG/CM**2) O.OOE +00 O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT.-L 1.00E + O0 1.00E + O0 1.00E+O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E+O0 1.00E + O0 1.00E+O0 1.00E+O0 YEAR - 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POI- INP-1 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE +00 O.OOE+O0 TRNSFORMI~I (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS-1 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 LIG.INPUT-1 (UG/CM**2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE +00 O.OOE +00 O.OOE + O00.OOE + O00.OOE+ O0 O.OOE+ O00.OOE+O0 VOLATILIZATION MULT.-1 ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ O.OOE+O00.OOE+O0 SURFACE RUNOFFMULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ O.OOE +00 O.OOE+O0 POL. IN RAIN (FRAC~SL) O.OOE +00 O.OOE+O00.OOE +00 O.OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+ O00.OOE+O0 POL. INP-2 (UG/CM**2) O.OOE+O00.OOE+ O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+ O00.OOE+O0 0.00E + 00 0.00E+ 00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+O00.OOE+O00.OOE+O0 SINKS-2 (UG/CM**2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE+ O00.OOE + O00.OOE + O0 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 O.OOE + O00.OOE+O0 VOLATILIZATION MULT.-2 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 POL. INP-L (UG/CM**2) O,OOE+ O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O0 O,OOE +00 O.OOE+O0 TRNSFORMD-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS-L (UG/CM**2) O.OOE +00 O.OOE+ O00.OOE+ O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O0 0.00E+ 00 0.00E+ 00 LIG.INPUT-L (UG/CM**2) 0,00E + 00 0.00E +00 0,00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0,00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 O.OOE+O00.OOE + O0 VOLATILIZATION MULT.-L 1.00E+O0 1.00E+O0 1.00E +00 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 YEAR- 1 MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. IN L1 (%) 7.710 7.770 7.920 8.160 8.310 8.460 8.370 8.160 7.920 7.680 7.470 7.350 MOIS. BELOWL1 (%) 7.710 7.770 7.920 8.160 8.310 8.460 8.370 8.160 7.920 7.680 7.470 7,350 PRECIPATION (CM) 0.941 1.521 2.063 2.733 2.541 2.767 1.576 0.761 0.353 0.126 0.094 0.407 NET INFILT. (CM) 0.941 1.521 2.063 2.733 2.541 2.767 1.576 0.761 0.353 0.126 0.094 0.407 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) -0.263 0,263 0.657 1.052 0.657 0.657 -0.394 -0.9213 -1.052 -1.052 -0.920 -0.526 SUR. RUNOFF (CM) 0.000 0.000 0.000 0,000 0.000 0.(XX) 0.000 0.000 0,000 0.000 0.000 0.000 GRW. RUNOFF (CM) 0.900 0.954 1.101 1.377 1.579 1.806 1.667 1.377 1.101 0.874 0.710 0.629 YIELD (CM) 0.900 0.954 1.101 1.377 1.579 1.806 1.667 1.377 1.101 0.874 0.710 0.629 PAU/MPA (GZU) 1.120 1.071 1.042 1.043 1.000 1.048 1.017 1.028 1.765 4.205 1.169 1.233 PA/MPA (GZ) 1.120 1.071 1.042 1.043 1.000 1,048 1.017 1.028 1.765 4.205 1.169 1.233 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PREClP. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E + 00 0.000E + 00 LOAD UPPER 2.899E +09 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 O.O00E +00 O.O00E + O0 LOAD ZONE 2 2.770E +09 O.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O0 0.O00E + 00 O.000E + 00 LOAD ZONE 3 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.0(X)E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 O.000E + 00 LOAD LOWER ~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~ 0.000E + 00 0.000E + 00 TOTAL INPUT 5.669E + 09 0.0(X)E + 00 0.000E +00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0,000E + 00 0.000E + 00 O.O00E + O00.O00E +00 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 DEGRAD MOIS 1.165E+ 071.171E+07 1.193E+07 1.234E + 071.255E + 07 1.276E + 071.249E + 07 1.206E + 07 1.158E + 071.128E + 07 1.087E + 07 1.062E+ 07 IN SOIL MOl 1.938E+08 1.948E+08 1.983E+08 2.051E+08 2.086E+08 2.121E+08 2.077E+08 2,005E+08 1.927E+08 1.876E+08 1.808E + 08 1.767E + 08 ADS ON SOIL 5.912E + 08 5.895E + 08 5.890E + 08 5.912E+ 08 5.904E + 08 5.896E + 08 5.835E + 08 5.779E +08 5.720E + 08 5.745E + 08 5.693E+08 5.654E+ 08 IN SOIL AIR 2.102E+09 2.090E+09 2.074E+09 2.051E+09 2.034E+09 2.017E+09 2.014E+09 2.015E+09 2.016E+09 2.007E+09 2.008E+ 09 2.005E+09 SOIL ZONE 2: SUBLAYER 1 DEGRAD MOIS 5.758E + 08 1.122E + 07 1.143E+ 071.184E +07 1.205E + 07 1.226E + 071.201 E+07 1.160E+071.115E+ 07 1.086E+ 07 1.047E+07 1.023E+07 I IN SOIL MOl 1.856E+08 1.866E+08 1 .~02E+08 1.969E+08 2.004E+08 2.040E+08 1.998E+08 1.930E +08 1.855E+08 1.806E+08 1.741E+08 1.702E+ 08 ADS ON SOIL 5.662E + 08 5.648E + 08 5.647E + 08 5.674E +08 5.672E+08 5.670E +08 5.614E+ 08 5.562E + 08 5.507E + 08 5.531E+08 5.482E+ 08 5.446E+08 IN SOIL AIR 2.013E+09 2.002E+09 1.988E+09 1.968E+09 1.954E+09 1.940E+09 1.938E+09 1.939E+09 1.941E+09 1.933E+09 1.934E+ 09 1.931E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER I - POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 1.860E+01 1.855E+01 1.853E+01 1.860E+01 1.858E+01 1.855E+01 1.835E+01 1.818E+01 1.800E+01 1.808E+01 1.792E+01 1.779E +01 %SOLUBILITY 1.156E+01 1.152E+01 1.161E+01 1.156E+01 1.154E+01 1.152E+01 1.140E+01 1.129E+01 1.118E+01 1.123E+01 1.113E+01 1.105E+01 ADSORBED 3,241E + O0 3,231E + O0 3.228E + O0 3.241E + O0 3.236E+ O0 3.232E + O0 3.198E+ O0 3.167E+ O0 3.136E + O0 3.149E + O0 3.121E+00 3.099E + O0 SOIL AIR 6.977E+01 6.956E+01 6.950E+01 6.949E+01 6.939E+01 6.930E+01 6.891E+01 6.825E+01 6.757E+01 6.655E+01 6.595E+01 6.550E+ 01 SOIL ZONE 2: SUBLAYER 1 MOISTURE 7.131E+O0 7.114E+ O0 7.113E+00 7.147E+00 7.145E+00 7.142E+00 7.071E+O0 7.006E + O0 6.937E+ O0 6.967E +00 6.905E + O0 6.859E + O0 %SOLUBILITY 4.429E + O0 4.419E + O0 4.418E + O0 4.439E + O0 4.438E + O0 4.435E + O0 4.392E + O0 4.351E + O0 4.309E + O0 4.327E + O0 4.289E + O0 4.260E +00 ADSORBED 1.242E+00 1.239E+00 1.239E+00 1.245E+00 1.245E+00 1.244E+00 1.232E+00 1.220E+00 1.208E+00 1.214E+00 1.203E + O0 1.195E+00 SOIL AIR 2.674E+01 2.668E+01 2.667E+01 2.669E+01 2.668E+01 2.667E+01 2.654E+01 2.630E+01 2.604E+01 2.565E+01 2.542E+01 2.525E+01 SOIL ZONE 3: LOWER SOIL ZONE: POL DEP CM 6.816E+02 6,818E + 02 6.820E + 02 6.823E+ 02 6,826E +02 6.829E + 02 6.831E+02 6.832E + 02 6.832E + 02 6.832E+ 02 6.833E + 02 6.833E+ 02 YEAR - 1 ANNUAL SUMMARY REPORT =========================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE 2.899E+O9 SOIL ZONE 2 2.770E+09 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.940 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.940 TOTAL PRECIPITATION (CM) 15.882 TOTAL INFILTRATION (CM) 15.882 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 14.075 TOTAL MOISTURE RETENTION (CM) -1.841 TOTAL YIELD (CM) 14.075 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.418E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.309E+08 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1,831E+01 ADSORBED SOIL (UG/G) 3.190E+00 SOIL AIR (UG/ML) 6.831E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 7.045E+00 ADSORBED SOIL (UG/G) 1,227E+00 SOIL AIR (UG/ML) 2.628E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 6.8,.'.'.'.'.'.'.'.'.~3E+00 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.(XX)E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0,000E+00 LOWER SOIL ZONE 0,000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7,797 TOTAL PRECIPITATION (CM) 15,865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.1300 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) q3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 8.606E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 8.751E+07 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1,132E+01 ADSORBED SOIL (UG/G) 1.971E+00 SOIL AIR (UG/ML) 4.221E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4,607E+00 ADSORBED SOIL (UG/G) 8,025E-01 SOIL AIR (UG/ML) 1.718E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLl- DEPTH (M) 6.992E+00 YEAR - 20 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.0(X)E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15,865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) q3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTHi IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.098E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.465E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.703E+00 ADSORBED SOIL (UG/G) 1.168E+00 SOIL AIR (UG/ML) 2.500E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.877E+00 ADSORBED SOIL (UG/G) 5.011E-01 SOIL AIR (UG/ML) 1.073E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLl_ DEPTH (M) 7.170E+00 YEAR - 30 ANNUAL SUMMARY REPORT ================================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12,348 TOTAL MOISTURE RETENTION (CU) q3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CRC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.022E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.396E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 3.974E+00 ADSORBED SOIL (UG/G) 6.922E~1 SOIL AIR (UG/ML) 1.482E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.788E+00 ADSORBED SOIL (UG/G) 3.114E~1 SOIL AIR (UG/ML) 6.669E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 7.347E+00 YEAR - 40 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O(X)E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.788E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.100E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.351E+00 ADSORBED SOIL (UG/G) 4.096E-01 SOIL AIR (UG/ML) 8.771E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.105E+00 ADSORBED SOIL (UG/G) 1.925E-01 SOIL AIR (UG/ML) 4.123E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 7.524E+00 YEAR - 50 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION tN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.054E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.306E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.386E+00 ADSORBED SOIL (UG/G) 2.414E~31 SOIL AIR (UG/ML) 5.168E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.875Eq31 ADSORBED SOIL (UG/G) 1.198Eq31 SOIL AIR (UG/ML) 2.565E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 7.701E+00 YEAR - 60 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.204E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 8.127E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.158Eq31 ADSORBED SOIL (UG/G) 1.421E~31 SOIL AIR (UG/ML) 3.043E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4.278E-01 ADSORBED SOIL (UG/G) 7.452E-02 SOIL AIR (UG/ML) 1.596E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 7.878E+00 YEAR - 70 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 O.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.0(X) TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.680E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.043E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4.839E-01 ADSORBED SOIL (UG/G) 8.430E-02 SOIL AIR (UG/ML) 1.805E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.655E-01 ADSORBED SOIL (UG/G) 4.625E-02 SOIL AIR (UG/ML) 9.904E-01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLl- DEPTH (M) 8.055E+00 YEAR - 80 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+ 00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~).131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.179E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.117E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.865E-01 ADSORBED SOIL (UG/G) 4.991E-02 SOIL AIR (UG/ML) 1.069E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.641E-01 ADSORBED SOIL (UG/G) 2.858E-02 SOIL AIR (UG/ML) 6.121E-01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 8,232E+00 YEAR - 90 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.0(X)E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.0(X)E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.286E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.915E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.691E-01 ADSORBED SOIL (UG/G) 2.945E-02 SOIL AIR (UG/ML) 6.307E~1 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.008E~)1 ADSORBED SOIL (UG/G) 1.756E~32 SOIL AIR (UG/ML) 3.761E~31 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLl- DEPTH (M) 8.409E+00 YEAR - 99 ANNUAL SUMMARY REPORT - TOTAL iNPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.(XX)E+O0 SOIL ZONE 3 O.O(X)E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) q3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT I$ NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 7.948E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.247E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.045E-01 ADSORBED SOIL (UG/G) 1.821E~)2 SOIL AIR (UG/ML) 3.899Eq31 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.564Eq32 ADSORBED SOIL (UG/G) 1.143E~32 SOIL AIR (UG/ML) 2.449E~1 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 8.568E+00 *********************************************** COMPLETED**************************************** ***** SESOIL'84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** ..... DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. lITTLE INC. ,(617)864-5770~5871 ***** ***** J. WAGNER ,DIS/ADLPIPE, INC. ,(617)492-1991~5820 ***** ***** MODIFIED EXTENSIVELY BY: ***** D.M. HETRICK ***** OAK RIDGE NATIONAL LABORATORY ***** ***** (615) 576-7556 ***** VERSION : SEPTEMBER 1986 ***** ****** MONTHLY SESOIL MODEL OPERATION MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : 1,2-XYLENE WASHLOAD DATA : APPLICATION AREA: ARCO 1960, BAKERSFIELD, CA - XYLENE ISOMERS WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS -- SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200Eq31 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): .0(X) FREUNDLICH EXPONENT (-): 1,00 -- CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 175. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .760E~)1 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .510Eq32 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 871. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 106. VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .2OOE~32 DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND-POLLUTANT STABILITY CONSTANT (-): .O00 NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPLICATION INPUT PARAMETERS - - - NUMBER OF SOIL LAYERS: 3 YEARS TO BE SIMULATED: 99 AREA (CM**2): 0.446E+06 APPLICATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPUCATION (0): 1 DEPTHS (CM): 0.30E+03 0.76E+03 0.42E+04 NUMBER OF SUBLAYERS/LAYER 1 I 1 PH (CM): 7.0 7.0 7.0 INTRINSIC PERMEABILITIES (CM**2): 0.10E~37 0.10E~5 0.10E~4 KDEL RATIOS (-): 1.0 1.0 KDES RATIOS (-): 1.0 1.0 OC RATIOS (-): 1.0 1.0 CEC RATIOS (-): 1.0 1.0 FRN RATIOS(-): 1.0 1.0 ADS RATIOS(-): 1.0 1.0 YEAR - I MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0.000 0.000 O.(XX) 0.000 0.000 0.000 0.000 0.000 0.000 CLOUD CVR (FRAC.) O.O(X) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 REL. HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ALBEDO (-) 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PREClP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 20.400 30.400 30.400 30.400 30.400 30.400 30.400 20.400 30.400 - POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 9.73E+04 O.OOE+O00. OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00. OOE+O00.OOE+O0 O,OOE+O00.OOE+ O0 TRNSFORMD-1 (UG/CM**2) O.OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINK~I (UG/CM"2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE+ O00.OOE +00 O.OOE + O0 O.OOE+O00.OOE+O0 LIG.INPUT-1 (UG/CM**2) O.OOE +00 O.OOE + O00.OOE+ O00.OOE + O00.OOE+O00.OOE+O00,OOE+ O00.OOE + O00.OOE + O00.OOE+O0 O.OOE +00 O.OOE + O0 VOLATILIZATION MULT.-10.OOE + O00,OOE + O00.OOE +00 O.OOE + O00.OOE + O00.OOE+ O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE + O00.OOE+O0 SURFACE RUNOFF MULT. ~~~~E+~~~~~~E+~~~.~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ O.OOE+O00.OOE + O0 POL. IN RAIN (FRAC-SL) O.OOE + O00.OOE+O00.OOE +00 O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE +00 O.OOE+O0 POL. INP-2 (UG/CM**2) 8.41E+04 O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 TRNSFORMI~2 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS-2 (UG/CM**2) O.OOE+ O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE +00 O.OOE+O00.OOE+O0 O.OOE+O00.OOE +00 LIG.INPUT-2 (UG/CM**2) O.OOE +00 O.OOE + O00.OOE + O00.OOE+O00.OOE + O00.OOE + O00.OOE+ O00.OOE + O00.OOE + O00.OOE+ O0 O.OOE+O00.OOE + O0 VOLATILIZATION MULT.-2 1.00E + O0 1.00E + O0 1.00E + O0 1.00E+ O0 1.00E+O0 1.00E + O0 1.00E + O0 1.00E+ O0 1.00E+ O0 1.00E+O0 1.00E +00 1.00E+O0 POI_ INP-L (UG/CM**2) 0,00E+00 0,00E+00 0,00E+00 0,1XiE+00 0,00E+00 0,00E+00 0,00E+ 00 0,00E+O0 0,00E+00 0,00E+00 ...... 0.00E+00 0.00E+00 TRNSFORM~L (UG/CM**2) 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 SINKS-L (UG/CM'*2) 0,00E+00 0,00E+00 0,00E+00 0,O0E+00 0,O0E+00 0,00E+00 0,00E+00 0,00E +00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 LIG,INPUT-L (UG/CM**2) 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E +.00 0,00E + 00 0,00E + 00 O,00E + 00 O,00E + 00 0,00E + 00 0,00E +00 0,00E+00 VOLATILIZATION MULT,-L 1,00E +00 1,00E+00 1,00E+00 1,00E + 00 1,00E+00 1,00E +00 1,00E + 00 1,00E + 00 1,00E + 00 1,00E +00 1,00E+00 1,00E+00 YEAR - 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POL, INP-1 (UG/CM**2) 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E + 00 TRNSFORMD-1 (UG/CM**2) 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 SINKS-1 (UG/CM'*2) 0,00E + 00 0,00E + 00 0,00E+ 00 0.00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E+ 00 0,00E+00 0,00E + 00 0,00E+00 0,00E+00 LIG,INPUT-1 (UG/CM**2) 0,00E+00 0,00E+ 00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0,00E+ 00 0,00E + 00 0,00E+00 0,00E+00 0,00E+00 0,00E+ 00 VOLATILIZATION MULT,,1 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E+ 00 0,00E + 00 0,00E+00 0,00E+00 SURFACE RUNOFFMULT, ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0,00E+00 0,00E +00 POE IN RAIN (FRAC-SL) 0,00E+ 00 0,00E +00 0,00E+00 0,00E+00 0,00E +00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E +00 0,00E+00 POL, INP-2 (UG/CM**2) 0,00E+00 0,00E+00 0,00E+ 00 0,00E+00 0,00E+00 0,00E+00 0,00E+ 00 0,00E+00 0,00E+00 0,00E+00 0,00E+ 00 0,00E + 00 TRNSFORMD-2 (UG/CM**2) 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+O0 SINKS-2 (UG/CM*'2) 0,00E+00 O,OOE+O0 0,00E+00 O,OOE+O00,00E+ 00 O,OOE+00 0,00E+00 O,00E+00 O,00E+00 O,OOE+O0 0,00E + 00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0,00E + 00 0,00E + 00 0,00E + 00 0.00E + 00 0,00E + 00 0,0OE+ 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E+00 0,00E +00 VOLATILIZATION MULT,-2 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 POL, INP-L (UG/CM**2) 0,00E +00 0,00E+00 0,00E+00 0,00E +00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E +00 TRNSFORMD-L (UG/CM**2) 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 SINKS-L (UG/CM**2) 0,OOE+ 00 0,00E+00 0,00E+ 00 0,00E+00 0,00E+ 00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 O,00E+00 0,00E +00 0,00E+00 LIG,INPUT-L (UG/CM**2) 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E + 00 0,00E+ 00 0,00E + 00 0,00E + 00 0,00E +00 0,00E+ 00 0,00E+00 0,00E + 00 VOLATILIZATION MULT,-L 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E +00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 YEAR- I MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. IN L1 (%) 7.710 7.770 7.920 8.160 8.310 8.460 8.370 8.160 7.920 7.680 7.470 7.350 MOIS. BELOW L1 (%) 7.710 7.770 7.920 8.160 8.310 8.460 8.370 8.160 7.920 7.680 7.470 7.350 PRECIPATION (CM) 0.941 1.521 2.063 2.733 2.541 2.767 1.576 0.761 0.353 0.126 0.094 0.407 NET INFILT. (CM) 0.941 1.521 2.063 2.733 2.541 2.767 1.576 0.761 0.353 0.126 0.094 0.407 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) -0.263 0.263 0.657 1.052 0.657 0.657 ~3.394 -0.920 -1.052 -1.052 -0.920 -0.526 SUR. RUNOFF (CM) 0.000 0.000 0.000 0.000 O.(XX3 0.000 0.0(30 0.000 O.(XX) 0.000 O.O(X) 0.000 Gl:NV. RUNOFF (CM) 0.900 0.954 1.101 1.377 1.579 1.806 1.667 1.377 1.101 0.874 0.710 0.629 YIELD (CM) 0.9(30 0.954 1.101 1.377 1.579 1.806 1.667 1.377 1.101 0.874 0.710 0.629 PAU/MPA (GZU) 1.120 1.071 1.042 1.043 1.000 1.048 1.017 1.028 1.765 4.205 1.169 1.233 PA/MPA (GZ) 1.120 1.071 1.042 1.043 1.000 1.048 1.017 1.028 1.765 4.205 1.169 1.233 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O(X)E+O00.O00E+O00.O00E+O00.O00E+O0 O.O00E +00 O.O00E + O0 LOAD UPPER 4.340E + 10 O.O00E+ O00.O00E + O00.O00E + O00.O00E + O00.O00E+O00.O00E + O00.O00E + O00.O00E+ O00.O00E+ O0 O.O00E + O00.O00E + O0 LOAD ZONE 2 3.751 E+ 10 O.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O(X)E + O00.O00E + O0 0.0(X)E + 00 0.000E + 00 LOAD ZONE 3 0.(XX)E + 00 0.000E + 00 0,000E + 00 0,000E + 00 0.000E + 00 0,000E + 00 0,000E + 00 0,000E + 00 0.000E + 00 0,000E + 00 O.O00E +00 O.O00E + O0 LOAD LOWER O.O00E + O00.O00E + O00.O(X)E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O0 O.O00E + O00.O00E + O0 TOTAL INPUT 8.090E + 10 O.O00E + O00.O00E + O00.O00E + O00.O00E +00 O.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O0 O.O00E + O00.O00E +00 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 DEGRAD MOIS 1.094E + 081.102E + 08 1.124E~+ 081.158E + 081.179E + 08 1.200E + 081.188E + 08 1.158E + 08 1,124E + 081.090E + 08 1.060E+08 1,043E+08 IN SOIL MOl 1.823E+09 1.837E+09 1.873E+09 1.930E+09 1.965E+09 2.001E+09 1,979E+09 1,930E+09 1,873E+09 1.816E+09 1.766E +09 1,738E+ 09 ADS ON SOIL 5.561E+09 5.561E+ 09 5,561E+09 5,561 E+ 09 5.561E+09 5.561E+09 5,561E+09 5.561E+09 5.561E+09 5.561E+09 5.561E+ 09 5,561E+09 IN SOIL AIR 1.195E+09 1.191E+09 1.183E+09 1,166E+09 1,158E+09 1,150E+09 1.160E+09 1,172E+09 1,184E+09 1,174E+09 1.185E+09 1.192E+09 PURE PHASE 3.470E + 10 3.457E + 10 3.443E + 10 3.426E + 10 3.410E+ 10 3,394E + 10 3.383E + 10 3,374E+ 10 3.367E + 10 3.363E+ 10 3.356E+ 10 3.348E+ 10 SOIL ZONE 2: SUBLAYER 1 DEGRAD MOIS 1.995E + 08 2.754E + 08 2.808E + 08 2.893E + 08 2.946E + 08 2.999E + 08 2.967E + 08 2.893E + 08 2.808E + 08 2.722E + 08 2.648E+ 08 2.605E + 08 IN SOIL MOl 4.555E + 09 4.591E+09 4.679E+09 4.821E+09 4.910E+09 4.998E+ 09 4.945E+09 4.821E+09 4.679E+ 09 4.537E+09 4.413E+09 4.342E+09 ADS ON SOIL 1.389E+ 10 1.389E + 10 1.389E + 10 1.389E+ 10 1.389E + 10 1.389E + 10 1.389E + 10 1.389E + 10 1.389E + 10 1.389E + 10 ....... 1.389E+ 10 1.389E+ 10 IN SOIL AiR 2.984E+09 2.976E+09 2.956E+09 2.912E+09 2.892E+09 2.872E+09 2.899E+09 2.927E +09 2.959E+09 2.934E+09 2.961E+09 2.977E + 09 PURE PHASE 1.588E + 10 1.558E+ 10 1.524E+ 10 1.487E+ 10 1.452E + 10 1.416E + 10 1.390E + 10 1.371E+ 10 1.354E + 10 1.344E + 10 1.327E+ 10 1.306E+ 10 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 - POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 1.750E+02 1.750E+02 1.75OE+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.75OE+02 1.750E+02 %SOLUBILITY 1.000E + 021.0OOE + 02 1.000E + 02 1.000E + 021.000E + 02 1.000E + 02 1.000E + 02 1.000E + 021.0(X)E + 02 1.000E + 02 1.000E +02 1.000E+02 ADSORBED 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 SOIL AIR 3.965E+01 3.965E+01 3.965E+01 3.949E+01 3.949E+01 3.949E+01 3.969E+01 3.969E+01 3.969E+01 3.893E+01 3.893E+ 01 3.893E+01 PURE PHASE 2.568E +02 2.558E + 02 2.547E + 02 2.535E + 02 2.523E + 02 2.512E + 02 2.503E+02 2.497E+ 02 2.492E + 02 2.489E + 02 2.484E +02 2.477E +02 SOIL ZONE 2: SUBLAYER 1 MOISTURE 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E + 02 %SOLU BILITY 1.000E + 021.000E + 02 1.000E + 02 1.000E + 021.000E + 02 1.000E + 02 1.000E + 02 1.000E + 021.000E + 021.000E + 02 1.000E +02 1.000E+02 ADSORBED 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.G48E+01 3.048E+01 3.048E+ 01 3.048E+01 SOIL AIR 3.965E+01 3.965E+01 3.965E+01 3.949E+01 3.949E+01 3.949E+01 3.969E+01 3.969E+01 3.969E+01 3.893E+01 3.893E+01 3.893E +01 PURE PHASE 4.703E+01 4.616E+01 4.515E+01 4.404E+01 4.300E+01 4.194E+01 4.117E+01 4.061E+01 4.010E+01 3.979E+01 3.930E+01 3.870E+ 01 SOIL ZONE 3: LOWER SOIL ZONE: POL DEP CM 6,818E + 02 6.824E + 02 6.830E+02 6.839E +02 6.848E+02 6.857E +02 6.863E+02 6,866E + 02 6,868E+ 02 6.869E+02 6.870E + 02 6.871E+02 YEAR - 1 ANNUAL SUMMARY REPORT ================================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE 4.340E+ 10 SOIL ZONE 2 3.751E+ 10 SOIL ZONE 3 O.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.940 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.940 TOTAL PRECIPITATION (CM) 15.882 TOTAL INFILTRATION (CM) 15.882 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GFNV RUNOFF (CM) 14.075 TOTAL MOISTURE RETENTION (CM) -1.841 TOTAL YIELD (CM) 14.075 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYEP~ SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.352E+09 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.304E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1,750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.g44E+01 PURE PHASE (UG/ML) 3.019E+03 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 5.070E+02 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 6,871E+00 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.(XX)E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.(XX)E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GFNV RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) q3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.328E+09 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.672E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 1,901E+03 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.773E+01 ADSORBED SOIL (UG/G) 1.528E+01 SOIL AIR (UG/ML) 1,978E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL DEPTH (M) 7.369E+00 YEAR - 20 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 ~ LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.328E+09 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 4.126E+08 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 6.568E+02 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.166E+01 ADSORBED SOIL (UG/G) 3.773E+00 SOIL AIR (UG/ML) 4.883E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL DEPTH (M) 7.922E+00 YEAR - 30 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIl. SOILAIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.166E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.319E+08 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.076E+01 ADSORBED SOIL (UG/G) 1.407E+01 SOIL AIR (UG/ML) 1.821E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.928E+00 ADSORBED SOIL (UG/G) 1.207E+00 SOIL AIR (UG/ML) 1.562E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 8.475E+00 YEAR - 40 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O(X)E+O0 SOiL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.201E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.863E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.574E+01 ADSORBED SOIL (UG/G) 2.741E+00 SOIL AIR (UG/ML) 3.548E+00 SOIL ZONE 2: SUBLAYER I SOIL MOISTURE (UG/ML) 2.028E+00 ADSORBED SOIL (UG/G) 3.533E-01 SOIL AIR (UG/ML) 4.572E-01 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL. DEPTH (M) 9.02<JE+O0 YEAR - 50 ANNUAL SUMMARY REPORT ================================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E + 00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) 43.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOL, ADS. ON SOIL, SOIL AiR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.339E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.024E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.064E+00 ADSORBED SOIL (UG/G) 5.338E-01 SOIL AIR (UG/ML) 6.908E431 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.377E4:)1 ADSORBED SOIL (UG/G) 9.366E4:)2 SOIL AIR (UG/ML) 1.212E431 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) g.582E+00 YEAR - 60 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7,797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (GM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 4.546E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2,572E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.955E-01 ADSORBED SOIL (UG/G) 1,037E~1 SOIL AIR {UG/ML) 1.342E~31 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.349E-01 ADSORBED SOIL (UG/G) 2.351E-02 SOIL AIR (UG/ML) 3.042E-02 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL. DEPTH (M) 1.013E+01 YEAR - 70 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE O.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 8.841E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.158E+05 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 8.255E+03 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.158E-01 ADSORBED SOIL (UG/G) 2.017E-02 SOIL AIR (UG/ML) 2.611E-02 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.230E-02 ADSORBED SOIL (UG/G) 5.626E-03 SOIL AIR (UG/ML) 7.281E-O3 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.050E-05 ADSORBED SOIL (UG/G) 1.402E-05 SOIL AIR (UG/ML) 1.813E-05 MAX. POLL DEPTH (M) 1.0Cj6E+01 YEAR - 80 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~).131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.723E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.308E+05 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.638E+04 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.258E~32 ADSORBED SOIL (UG/G) 3.932Eq33 SOIL AIR (UG/ML) 5.089Eq~3 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.860E~)3 ADSORBED SOIL (UG/G) 1.195E-03 SOIL AIR (UG/ML) 1.546E~33 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.554E~4 ADSORBED SOIL (UG/G) 2.706E~5 SOIL AIR (UG/ML) 3.502E~)5 MAX. POLL DEPTH (M) 1.308E+01 YEAR - 90 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.353E+04 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.759E+04 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.573E+03 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4.392E-03 ADSORBED SOIL (UG/G) 7.650E-04 SOIL AIR (UG/ML) 9.900Eq34 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.447E-03 ADSORBED SOIL (UG/G) 2.520E~4 SOIL AIR (UG/ML) 3.262E-04 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 6.225E-05 ADSORBED SOIL (UG/G) 1.084E-05 SOIL AIR (UG/ML) 1.403E-05 MArC POLL. DEPTH (M) 1.520E+01 YEAR - 99 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.(XX)E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 7.671E+03 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.753E+03 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.316E+03 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.005E-03 ADSORBED SOiL (UG/G) 1.750E~4 SOIL AIR (UG/ML) 2.265Eq:)4 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.541E-04 ADSORBED SOIL (UG/G) 6.169E~5 SOIL AIR (UG/ML) 7.983E~5 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.192E-05 ADSORBED SOIL (UG/G) 3.818E-06 SOIL AIR (UG/ML) 4.941Eq:)6 MAX~ POLL DEPTH (M) 1.711E+01 ************************************************ COMPLETED**************************************** APPENDIX C Abbreviated SESOIL Output Files ~~iTECHNOLOGY ***** SESOIL~4: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. LITTLE INC. ,(617)864-5770,X5871 ***** ***** J. WAGNER ,DIS/ADLPIPE, INC. ,(617)492-1991,X5820 ***** ***** MODIFIED EXTENSIVELY BY: ****' D.M. HETRICK ***** ***** OAK RIDGE NATIONAL LABORATORY ***** ***** (615) 576-7556 ***** VERSION : SEPTEMBER 1986 ***** ****** MONTHLY SESOIL MODEL OPERATION MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : BENZENE WASHLOAD DATA : APPLICATION AREA: ARCO 1960, BAKERSFIELD, CA - BENZENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS -- SOiL iNPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E~31 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): .000 FREUNDLICH EXPONENT (-): 1.00 -- CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): .179E+04 DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .870E~)1 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .543Eq32 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 98.0 ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 78.1 VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .0(X) ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .0(30 DEGRADATION RATE IN MOISTURE (/DAY): .200Eq32 DEGRADATION RATE ON SOIL (/DAY): .000 LIGANI~POLLUTANT STABILITY CONSTANT (-): .000 NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPLICATION INPUT PARAMETERS - NUMBER OF BOIL LAYERS: 3 YEARS TO BE SIMULATED: 99 AREA (CM**2): 0.446E+06 APPLICATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPLICATION (0): 1 DEPTHS (CM): 0.30E+03 0.76E+03 0.42E+04 NUMBER OF SUBLAYERS/LAYER 1 1 1 PH (CM): 7.0 7.0 7.0 INTRINSIC PERMEABILITIES (CM**2): 0.10E~37 0.10E-05 0.10Eq34 KDEL RATIOS (-): 1.0 1.0 KDES RATIOS (-): 1.0 1.0 OC RATIOS (-): 1.0 1.0 CEC RATIOS (o): 1.0 1.0 FRN RATIOS(-): 1.0 1.0 ADS RATIOS(-): 1.0 1.0 YEAR o 1 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0,000 0.000 0.000 0.000 0.000 0,000 0.000 0,000 0,000 0.000 0,000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 0,000 0.000 REL. HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0,000 0.000 0.000 0.000 ALBEDO (-) 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1,770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 - POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 2.10E+02 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E +00 TRNSFORMI~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E +00 0.00E + 00 0.00E +00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 0.00E + 00 0.00E + iX) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E+ 00 0.00E +00 0,00E+ 00 0.00E+00 SURFACE RUNOFF MULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~-~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E+00 POL. IN RAIN (FRAC-SL) 0.00E +00 0.0OE+00 0.00E+ 00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 POL. INP-2 (UG/CM**2) 2.05E+02 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CM**2) O.0OE + 00 O.OOE+O00,00E + 00 0.00E+ 00 0.00E + 00 O.00E + 00 0.00E+ 00 0,00E +00 0.00E +00 0.00E+ O0 O.OOE +O0 0.OOE +O0 VOLATILIZATION MULT.-2 1,00E+00 1.00E+00 1.00E+00 1.00E+00 1,00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E +00 1.00E + 00 1.00E+ 00 -' POL INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 TRNSFORMI~L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+.00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SlNKS-L (UG/CM**2) 0.00E +00 0.00E+00 O.00E+00 0.00E+00 O.00E + 00 0.00E+00 0.00E + 00 0.00E+00 O.00E+00 O.0OE+00 0.00E+00 0.00E+00 LIG.INPUT-L (UG/CM**2) 0.00E +00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E +00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 VOLATlUZATION MULT.oL 1.00E+00 1.0OE+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 YEAR - 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POL. INPol (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 LIG.INPUT-1 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0,00E +00 0.00E + 00 0.00E + 00 O.00E + 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 VOLATILIZATION MULT.-1 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 SURFACE RUNOFFMULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+ 00 0.00E+ 00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 POL. INP-2 (UG/CM**2) 0.00E +00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+O00.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~.~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+ 00 1.00E+ 00 1.00E+00 1.00E +00 1.00E+00 1.00E+00 1.00E+00 1.00E +00 1.00E + 00 1.00E+00 1.00E+00 1.00E+ 00 POL. INP-L (UG/CM**2) 0.00E +00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E + 00 TRNSFORMD-L (UG/CM**2) O.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+ 00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 VOLATILIZATION MULT.-L 1.00E +00 1.0OE +00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 YEAR -99 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - I MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. IN L1 (%) 7.710 7.770 7.920 8.160 8.310 8.460 8.370 8.160 7.920 7.680 7.470 7.350 MOIS. BELOW L1 (%) 7.710 7.770 7.920 8.160 8.310 8.460 8.370 8.160 7.920 7.680 7.470 7.350 PRECIPATION (CM) 0.941 1.521 2.063 2.733 2.541 2.767 1.576 0.761 0.353 0.126 0.094 0.407 NET INFILT. (CM) 0.941 1.521 2.063 2.733 2.541 2.767 1.576 0.761 0.353 0.126 0.094 0.407 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) ~.263 0.263 0.657 1.052 0.657 0.657 q3.394 ~3.920 -1.052 -1.052 q3.920 q3.526 SUR. RUNOFF (CM) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 0.000 GRW. RUNOFF (CM) 0.900 0.954 1.101 1.377 1.579 1.806 1.667 1.377 1.101 0.874 0.710 0.629 YIELD (CM) 0.900 0.954 1.101 1.377 1.579 1.806 1.667 1.377 1.101 0.874 0.710 0.629 PAU/MPA (GZU) 1.120 1.071 1,042 1.043 1.000 1.048 1.017 1.028 1.765 4.205 1.169 1.233 PA/MPA (GZ) 1.120 1.071 1.042 1.043 1.000 1.048 1.017 1.028 1.765 4.205 1.169 1.233 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E + 00 0.000E+00 LOAD UPPER 9.366E +07 0.000E + 00 0.0(X)E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0,000E+00 0,000E+ 00 LOAD ZONE 2 9.143E + 07 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E +00 0,O00E + 00 LOAD ZONE 3 0.O00E +00 0.000E + 00 O.000E + O00.00OE + 00 0.000E + 00 O.000E + 00 O.O00E+O0 0.00OE + O0 0.000E +00 0.000E + 00 0.000E +00 0.000E + 00 LOAD LOWER ~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~ 0.000E + 00 O.000E + 00 TOTAL INPUT 1.851E + 08 0.000E + 00 0.0(X)E + 00 0.000E + 00 0.000E +00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E+00 0.000E + 00 -- POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 DEGRAD MOIS 2.711E + 06 2.641E + 06 2.588E + 06 2.554E + 06 2.497E + 06 2.439E + 06 2.339E + 06 2.230E + 06 2.123E + 06 2.034E+06 1.941 E+06 1.866E + 06 IN SOIL MOl 4.451E+07 4.334E+ 07 4.247E+07 4.188E+07 4.093E+07 3.998E+07 3.837E+07 3.661E+07 3.487E+07 3.342E+07 3.190E+07 3.065E +07 ADS ON SOIL 1.528E+07 1.476E+07 1.419E+07 1.358E + 07 1.303E + 07 1.250E + 07 1.213E+07 1.187E+07 1.165E+07 1,151E+07 1.130E+07 1.104E+07 IN SOIL AIR 3.105E+07 2.992E+07 2.857E+07 2,693E+07 2.567E+07 2.446E+07 2.395E+07 2.367E+07 2.347E+07 2.300E+07 2.279E + 07 2.238E+07 SOIL ZONE 2: SUBLAYER 1 DEGRAD MOIS 1~376E + ~ 2~62~E + ~6 2~585E + ~6 2~565E + ~ 2~523E + ~6 2~ 481E + ~6 2~391E + ~6 2~286E + ~6 2~179E + ~6 2~89E + ~6 1,994E+06 1.918E+06 IN SOIL MOl 4.418E+07 4,318E+07 4.251E+07 4.219E+07 4,149E+07 4.079E+07 3.930E + 07 3.756E+07 3.580E+07 3.433E+07 3.277E+07 3.153E+07 ADS ON SOIL 1.516E+07 1.471E+07 1.420E+07 1.368E+07 1.321E+07 1.276E+07 1.242E+07 1.218E+07 1.196E+07 1.183E+07 1.161E+07 1.135E+07 IN SOIL AIR 3.082E+07 2.981E+07 2.860E+ 07 2.714E+07 2.602E+07 2.495E +07 2.452E+07 2.428E+07 2.411E+07 2.363E+07 2.341E+07 2.302E+07 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 4.272E+00 4.128E+00 3.968E+00 3.798E+00 3.645E+00 3.497E+00 3.393E+00 3.320E+00 3.258E+00 3.220E+00 3.160E+00 3.087E+ 00 %SOLUBILI']'Y 2.385E-01 2.305E-O1 2.215E-O1 2.120E-01 2.035E-01 1.953E-01 1.8.94E-01 1.854E-O1 1.819E-01 1.798E-01 1.764E-01 1.724E-01 ADSORBED 8.374E-02 8.091E-02 7.777E-02 7.443E-02 7.145E.-02 6.854E-02 6.650E-02 6.508E-02 6.385E-02 6.311E..02 6.193E-02 6.050E-02 SOIL AIR 1.031E+00 9.960E-O1 9.573E-01 9.125E-01 8.759E-01 8.403E-01 8.193E-01 8.018E-01 7.867E-01 7.627E-01 7.484E-O1 7,312E-01 SOIL ZONE 2: SUBLAYER 1 MOISTURE 1.697E+00 1.646E+00 1.590E+00 1.532E+00 1.479E+00 1.428E+00 1.391E+00 1.363E+00 1.339E+00 1.324E+00 1,300E+00 1.271E+00 %SOLUBILITY 9.477E-02 9.191E-02 8.878E-02 8.552E-02 8.258E-02 7.973E-02 7.764E-02 7.613E-02 7.476E-02 7.392E-02 7.256E-02 7.096E-02 ADSORBED 3.327E-O2 3.226E-02 3,116E-02 3.002E-02 2,899E-02 2.799E-02 2.726E-02 2.672E-02 2.624E-02 2.595E-02 2.547E-O2 2.491E-02 SOIL AIR 4.095E-01 3.971E-01 3.836E-01 3.680E-01 3.554E-01 3.431E-01 3.358E-01 3.293E-01 3.233E-01 3.136E-01 3.078E-01 3.010E-01 SOIL ZONE 3: LOWER SOIL ZONE: POL DEP CM 6.823E + 02 6.835E + 02 6.851 E+ 02 6.871E+02 6.891E+02 6,912E + 02 6.925E + 02 6.932E + 02 6.936E + 02 6.938E+ 02 6,940E+ 02 6.943E+02 YEAR - 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 9.366E+07 SOIL ZONE 2 9.143E+07 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.940 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.940 TOTAL PRECIPITATION (CM) 15.882 TOTAL INFILTRATION (CM) 15.882 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 14.075 TOTAL MOISTURE RETENTION (CM) -1.841 TOTAL YIELD (CM) 14.075 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.796E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.701E + 07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.562E+00 ADSORBED SOIL (UG/G) 6.982Eq32 SOIL AIR (UG/ML) 8.552E~1 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.447E+00 ADSORBED SOIL (UG/G) 2.835E-02 SOIL AIR (UG/ML) 3.473E-01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 6.943E+00 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0,(XX)E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL Gl:NV RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL. SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 9.370E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.310E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 -- AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.217E-01 ADSORBED SOIL (UG/G) 2.386E-03 SOIL AIR (UG/ML) 2.923E-02 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.824E-02 ADSORBED SOIL (UG/G) 1.337E-03 SOIL AIR (UG/ML) 1.638E-02 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL DEPTH (M) 8.085E+00 YEAR - 20 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) q3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.188E+04 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 4.187E+04 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 2.843Eq:)3 ADSORBED SOIL (UG/G) 5.573E~5 SOIL AIR (UG/ML) 6.826E~:)4 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.180Eq:)3 ADSORBED SOIL (UG/G) 4.273E~5 SOIL AIR (UG/ML) 5.234Eq34 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 9.354E+00 YEAR - 30 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0,000E+00 SOIL ZONE 3 0,000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRVV RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.134E+02 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.520E+01 TOTAL DEGRADED (MOISTURE) 1.293E+03 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.561E+00 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.674E~5 ADSORBED SOIL (UG/G) 1.308Eq36 SOIL AIR (UG/ML) 1.602E~35 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.730Eq:)5 ADSORBED SOIL (UG/G) 1,319E~36 SOIL AIR (UG/ML) 1.616E-05' LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.749E-08 ADSORBED SOIL (UG/G) 3.429E. 10 SOIL AIR (UG/ML) 4.172E-09 MAX, POLL. DEPTH (M) 1.078E+01 YEAR - 40 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 -- POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.202E+01 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 3.454Eq31 TOTAL DEGRADED (MOISTURE) 3.026E+01 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 7.937E+00 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.561Eq36 ADSORBED SOIL (UG/G) 3.059Eq38 SOIL AIR (UG/ML) 3.747E-07 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.573E~36 ADSORBED SOIL (UG/G) 3.084E-08 SOIL AIR (UG/ML) 3.778E~7 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 7.465E~8 ADSORBED SOIL (UG/G) 1.463E~39 SOIL AIR (UG/ML) 1.792E~38 MAX. POLL. DEPTH (M) 1.564E+01 YEAR - 50 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE :3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.252E+00 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.279E+00 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.364E+00 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.652E-07 ADSORBED SOIL (UG/G) 3,237E-09 SOIL AIR (UG/ML) 3.963E-08 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.750E-08 ADSORBED SOIL (UG/G) 1.323E-09 SOIL AIR (UG/ML) 1.620Eq38 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.298E~8 ADSORBED SOIL (UG/G) 2.545E-10 SOIL AIR (UG/ML) 3.116E~9 MA)C POLL. DEPTH (M) 2.051E+01 YEAR - 60 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E + 00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.0(30 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOII~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 8.748E~)1 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.099E~31 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 8.672Eq31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.154E~37 ADSORBED SOIL (UG/G) 2.262Eq39 SOIL AIR (UG/ML) 2.770E-08 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.634Eq38 ADSORBED SOIL (UG/G) 3.203E-10 SOIL AIR (UG/ML) 3.922Eq39 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.250E~39 ADSORBED SOIL (UG/G) 1.617E-10 SOIL AIR (UG/ML) 1.980Eq39 MAX. POLl_ DEPTH (M) 2.538E+01 YEAR - 80 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.(XX)E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0,000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl,, ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1,756E-01 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1,373E~31 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.262Eq31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.317E-08 ADSORBED SOIL (UG/G) 4.541E-10 SOIL AIR (UG/ML) 5,561E-09 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 7,250Eq39 ADSORBED SOIL (UG/G) 1,421E-10 SOIL AIR (UG/ML) 1,740E-09 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1,200Eq:)9 ADSORBED SOIL (UG/G) 2.352E-11 SOIL AIR (UG/ML) 2.880E-10 MAY~ POLL. DEPTH (M) 3.511E+01 YEAR - 90 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E + 00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.00OE+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~).131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS, ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.214E~1 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.142E-01 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.262E~31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.6(X)Eq38 ADSORBED SOIL (UG/G) 3.136E-10 SOIL AIR (UG/ML) 3.840Eq:)9 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.025E-09 ADSORBED SOIL (UG/G) 1.181E-10 SOIL AIR (UG/ML) 1.446Eq~9 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.200E-09 ADSORBED SOIL (UG/G) 2.352E-11 SOIL AIR (UG/ML) 2.880E-10 MAX. POLL DEPTH (M) 3.998E+01 YEAR - 99 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.214E~31 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.142E-01 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.262Eq31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.600Eq38 ADSORBED SOIL (UG/G) 3.136E-10 SOIL AIR (UG/ML) 3.840E~9 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.025E-09 ADSORBED SOIL (UG/G) 1.181E-10 SOIL AIR (UG/ML) 1.446Eq39 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.200E~39 ADSORBED SOIL (UG/G) 2.352E. 11 SOIL AIR (UG/ML) 2.880E-10 MAX. POLL DEPTH (M) 4.436E+01 ****** .... *** ....******************************* COMPLETED**************************************** ***** SESOIL~4: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ' ***** ***** DEVELOPERS: M. BONAZOUNTASj~I~rHUR D. M3'rLE INC. ,(617)864-5770,X5871 ***** ***** J. WAGNER ,DIS/ADLPIPE, INC. , (617)492-1991~5820 ***** MODIFIED EXTENSIVELY BY: ***** ***** D.M. HETRICK ***** OAK RIDGE NATIONAL LABORATORY ***** ***** (615) 57~7556 ***** VERSION : SEPTEMBER 1986 ***** ****** MONTHLY SESOIL MODEL OPERATION ****** MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : TOLUENE WASHLOAD DATA : APPLICATION AREA: ARCO 1960, BAKERSFIELD, CA - TOLUENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN WARNING- SOIL PERMEABILITY.VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E-01 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): .000 FREUNDLICH EXPONENT (-): 1.00 1 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 535. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .830E~1 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .594E~)2 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 331. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 92.1 VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200E~2 DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND-POLLUTANT STABIUT? CONSTANT (-): .(XX) NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPUCATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 3 YEARS TO BE SIMULATED: 99 AREA (CM**2): 0.446E+06 APPLICATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPMCATION (0): 1 DEPTHS (CM): 0.30E+03 0.76E+03 0.42E+04 NUMBER OF SUBLAYERS/LAYER I 1 1 PH (CM): 7.0 7.0 7.0 INTRINSIC PERMEABILITIES (CM**2): 0.10E~37 0.10E~35 0.10E~34 KDEL RATIOS (-): 1.0 1.0 KDES RATIOS (-): 1,0 1.0 OC RATIOS (-): 1.0 1.0 CEC RATIOS (-): 1.0 1.0 FRN RATIOS(-): 1.0 1.0 ADS RATIOS(-): 1.0 1.0 1 YEAR- 1 MONTHLY INPUT PARAMETERS -- CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.0(X) 0,0(30 0.000 0.000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 0.0(X) 0.000 0.000 0.000 REL. HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.0(30 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0,010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0,400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 - POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 1.72E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+ 00 LIG.INPUT-1 (UG/CM**2) 0.00E+00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E+00 0.00E+00 0.00E +00 O,00E+ O0 0.OOE+00 VOLATILIZATION MULT.-1 0.00E +00 0,OOE + 00 O.00E + 00 0.00E + 00 O,00E + 00 0.00E + 00 0.00E + 00 0,00E + 00 0,00E + 00 O.OOE+O0 0.00E+O0 0.00E+00 SURFACE RUNOFF MULT. O.00E +00 O,00E+ 00 0.00E + 00 0.00E + O0 0.OOE + 00 0.OOE+ 00 0,00E + 00 O,00E + O0 0.00E + 000.00E+00 0.00E+00 0.00E+00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 O,00E +00 POL. INP-2 (UG/CM**2) 1.72E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 TRNSFORM~2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+O0 0.00E+00 O.00E+00 0,00E+00 0.0OE+00 O.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 - -- 0.00E +00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 0.00E + (X) 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E +00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+ 00 1.00E+00 1.00E+00 1.0OE+00 1.00E+00 1.00E+00 1.00E ~00 1.0OE+00 1.00E+ 00 1.00E+00 POE INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+ 00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+00 O.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG,INPUT-L (UG/CM**2) 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+ 00 0,00E + 00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 VOLATILIZATION MULT.-L 1,00E+00 1.00E+00 1,00E+00 1.00E+00 1,00E+00 1.00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1.00E+00 1,00E+00 1 YEAR - 2 MONTHLY INPUT PARAMETERS -- CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 O.00E + 00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) ~~~~E+~~~~~~E+~~~~~~E+~~~-~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0,00E +00 0.00E+00 LIG,INPUT-1 (UG/CM**2) 0.00E + 00 0,00E + 00 0,00E + 00 0.00E+00 0,00E+00 0,00E +00 0.00E + 00 0.00E + 00 0.00E + 00 0,00E+ 00 0.00E + 00 0.00E+00 VOLATILIZATION MULT.-1 0,00E+00 0.00E+00 0.00E+00 0.00E+000.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 SURFACE RUNOFF MULT. 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E+00 0.00E+00 P~L, IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 O.OOE+O00.OOE+O0 POL, INP-2 (UG/CM**2) 0.00E +00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E + 00 0.00E+ 00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0,00E + 00 0,00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E+00 LIG,INPUT-2 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0,00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 0,00E ~-00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-2 1,00E+00 1.00E+00 1.00E+ 00 1,00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E +00 1.00E+OO POE INP-L (UG/CM*"2) 0.00E+00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 SINKS-L (UG/CM**2) 0.00E+ 00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 O.OOE+O00.OOE+O0 LIG.INPUT-L (UG/CM**2) 0,00E + 00 0.00E+ 00 0,00E + 00 0,00E + 00 0,00E+ 00 0.00E+ 00 0,00E + 00 0.00E + 00 0.00E +00 0.00E +CX3 O.00E+00 0.00E+00 VOLATILIZATION MULT.-L 1.0OE+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 YEAR - 1 MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. IN L1 (%) 7.710 7.770 7.920 8.160 8.310 8.460 8.370 8.160 7.920 7.680 7.470 7.350 MOIS. BELOW L1 (%) 7.710 7.770 7.920 8.160 8.310 8.460 8.370 8.160 7.920 7.680 7.470 7.350 PREClPATION (CM) 0.941 1.521 2.063 2.733 2.541 2.767 1.576 0.761 0.353 0.126 0.094 0.407 NET INFILT. (CM) 0.941 1.521 2.063 2.733 2.541 2.767 1.576 0.761 0.353 0.126 0.094 0.407 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) -0.263 0.263 0.657 1.052 0.657 0.657 -0.394 -0.920 -1.052 -1.052 -0.920 -0.526 SUR. RUNOFF (CM) 0.000 0.000 0.000 0.0(30 0.000 0.000 0.000 0.0(X:) 0.000 0.000 0.000 0.000 GRW. RUNOFF (CM) 0.900 0.954 1.101 1.377 1.579 1.806 1.667 1.377 1.101 0.874 0.710 0.629 YIELD (CM) 0.900 0.954 1.101 1.377 1.579 1.806 1.667 1.377 1.101 0.874 0.710 0.629 PAU/MPA (GZU) 1.120 1.071 1.042 1.043 1.000 1.048 1.017 1.028 1.765 4.205 1.169 1.233 PA/MPA (GZ) 1.120 1.071 1.042 1.043 1.0(X) 1.048 1.017 1.028 1.765 4.205 1.169 1.233 1 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. O.0(X)E+00 0.000E+00 O.000E+O0 0.000E+ 00 O.0(X)E+00 0.0(X)E+00 0.0(X)E+O00.000E+00 0.000E+00 O.000E+00 0.000E + 00 0.000E+ 00 LOAD UPPER 7.662E + 09 0.000E + 00 0.(XX)E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E + 00 0.000E+ 00 O.O00E + O00,O00E + O0 LOAD ZONE 2 7,662E + 09 O.O00E +00 O.O00E + O00.O00E + O00.O00E + O00.O(X)E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O0 0.000E + 00 0.0(X)E + 00 LOAD ZONE 3 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 O.O00E +00 O.O00E+O0 LOAD LOWER O.O00E + O00.O00E + O00.O00E + O00.O00E+ O00.O00E + O00.O00E + O00.(X30E + O00.O00E+ O00.O00E + O00,O00E + O0 O.O00E+ O00.O00E + O0 TOTAL INPUT 1.532E + 10 O.O00E + O00,O(X)E + O00.O00E + O00.O00E + O00.O00E + O00.O00E+ O00.O00E + O00.O00E + O00,O00E+ O0 0.000E + 00 0.000E + 00 0 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 DEGRAD MOIS 1,556E + 08 1.631 E+08 1,519E+ 08 1.518E+ 08 1,503E + 08 1,486E + 08 1,438E + 08 1.380E + 08 1.321 E+08 1,270E + 08 1.219E+08 1,180E+08 IN SOIL MOl 2,566E+09 2.525E+09 2.503E+09 2.502E+09 2,476E+09 2,448E+09 2.370E+09 2,275E+09 2,178E+09 2,096E+09 2.011E+09 1,947E+09 ADS ON SOIL 2.976E + 09 2.905E + 09 2.826E+09 2.741E+09 2.664E + 09 2.587E +09 2.532E + 09 2.493E+09 2,459E+ 09 2.440E + 09 2.407E+09 2,368E+09 IN SOIL AIR 1.958E+09 1.907E+09 1.842E+09 1.760E+09 1.699E+09 1.638E+09 1.618E+09 1.609E+09 1.604E+09 1.578E+09 1.572E+09 1.555E+09 SOIL ZONE 2: SUBLAYER 1 DEGRAD MOIS 8.075E + 07 1.551E+081.543E + 081.549E + 081.540E + 081.530E + 081.486E + 081.429E + 081.369E + 08 1.317E + 08 1.264E+08 1.224E + 08 IN SOIL MOl 2.596E+09 2.561E+09 2.548E+09 2.558E+09 2.542E+09 2.525E+09 2.452E+09 2.357E+09 2.259E+09 2.174E+09 2.087E+09 2.021E+09 ADS ON SOIL 3.011 E+ 09 2.947E + 09 2.877E + 09 2.803E + 09 2.735E+ 09 2.669E + 09 2.619E + 09 2.583E + 09 2.550E + 09 2.530E + 09 2.498E+ 09 2.459E+09 IN SOIL AIR 1.981E+09 1.934E+09 1.875E+09 1.800E+09 1.744E+09 1.690E+09 1.674E+09 1.667E+09 1.663E+09 1.637E+09 1.631E+09 1.614E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 2.463E+02 2.405E+02 2.339E+02 2.269E+02 2.205E+02 2.141E+02 2.095E+02 2.063E+02 2.035E+02 2.019E+02 1,993E+ 02 1.960E+02 %SOLUBILITY 4.605E+01 4.496E+01 4.374E+01 4.242E+01 4.122E+01 4.004E+01 3.918E+01 3.858E+01 3.806E+01 3.776E+01 3.726E+01 3.666E+01 ADSORBED 1.631E+01 1.593E+01 1.549E+01 1.503E+01 1.460E+01 1.418E+01 1.388E+01 1.366E+01 1.348E+01 1.337E+01 1.320E+01 1.298E+01 SOIL AIR 6.500E+01 6.346E+01 6.174E+01 5.964E+01 5.795E+01 5.628E+01 5.535E+01 5.451E+01 5.377E+01 5.232E+01 5.163E+01 5.079E+01 SOIL ZONE 2: SUBLAYER 1 MOISTURE 9.974E+01 9.763E+01 9.531E+01 9.287E+01 9.062E+01 8.842E+01 8.677E+01 8.556E+01 8.447E+01 8.383E+01 8.274E+01 8.147E+01 %SOLUBILITY 1.865E+01 1.826E+01 1.782E+01 1.736E+01 1.695E+01 1.653E+01 1.622E+01 1.600E+01 1.579E+01 1.568E+01 1.547E+01 1.523E+01 ADSORBED 6.605E+00 6.466E+00 6,312E+00 6.150E+00 6,002E+00 5,856E+00 5.746E+00 5.666E+00 5,594E+00 5.552E+00 5.480E +00 5.395E+00 SOIL AIR 2.632E+01 2.577E+01 2.515E+01 2.441E+01 2.382E+01 2.324E+01 2.292E+01 2.260E+01 2.231E+01 2.172E+01 2.144E+01 2.111E+01 SOIL ZONE 3: LOWER SOIL ZONE: POL DEP CM 6.820E + 02 6.829E+ 02 6.840E + 02 6.854E +02 6.868E + 02 6.883E + 02 6.892E + 02 6.897E + 02 6.900E + 02 6.901E+02 ...... 6.903E+02 6.905E+02 YEAR - 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 7.662E+09 SOIL ZONE 2 7.662E+09 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.940 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.940 TOTAL PRECIPITATION (CM) 15.882 TOTAL INFILTRATION (CM) 15.882 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 14.075 TOTAL MOISTURE RETENTION (CM) -1.841 TOTAL YIELD (CM) 14.075 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOILAIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.692E+09 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.661E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.166E+02 ADSORBED SOIL (UG/G) 1.434E+01 SOIL AIR (UG/ML) 5.687E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.912E+01 ADSORBED SOIL (UG/G) 5.902E+00 SOIL AIR (UG/ML) 2.340E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLl- DEPTH (M) 6.gO5E+00 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.(XX)E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.00OR+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOL, ADS. ON SOIL, SOIL AIR, IMMOBIL CRC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.564E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.019E+08 SOIL ZONE 3' SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2,04OE+01 ADSORBED SOIL (UG/G) 1.351E+00 SOIL AIR (UG/ML) 5.358E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.056E+01 ADSORBED SOIL (UG/G) 6.991E-01 SOIL AIR (UG/ML) 2.772E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 7,705E+00 · YEAR - 20 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.(XX)E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.128E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.833E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.471E+00 ADSORBED SOIL (UG/G) 9.743E~32 SOIL AIR (UG/ML) 3.864E-01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 9.584E-01 ADSORBED SOIL (UG/G) 6.347Eq32 SOIL AIR (UG/ML) 2.517E~31 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 8.594E+00 YEAR - 30 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~).131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 8.126E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.634E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.060E~1 ADSORBED SOIL (UG/G) 7.022E-03 SOIL AIR (UG/ML) 2.784E~2 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.543E~2 ADSORBED SOIL (UG/G) 5.658E~3 SOIL AIR-(UG/ML) 2.243E~2 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 9.482E+00 YEAR - 40 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.0(X) TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.863E+04 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.437E+05 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 7.651E-03 ADSORBED SOIL (UG/G) 5.067E-04 SOIL AIR (UG/ML) 2.009E-03 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 7.512E-03 ADSORBED SO~L (UG/G) 4.975E~34 SOIL AIR (UG/ML) 1.973Eq:)3 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 1.037E+01 YEAR - 50 ANNUAL SUMMARY REPORT ----.~ ========================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 4.370E+03 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.280E+01 TOTAL DEGRADED (MOISTURE) 1.093E+04 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.445E+03 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.702E~34 ADSORBED SOIL (UG/G) 3.776Eq:)5 SOIL AIR (UG/ML) 1.497Eq::)4 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.707E~34 ADSORBED SOIL (UG/G) 3.779E~5 SOIL AIR (UG/ML) 1.499E-04 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.368E~35 ADSORBED SOIL (UG/G) 9.061E~37 SOIL AIR (UG/ML) 3.592E-06 MAX~ POLL DEPTH (M) 1.318E+01 YEAR - 60 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.181E+02 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.300E+00 TOTAL DEGRADED (MOISTURE) 7.956E+02 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.727E+02 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4.151Eq35 ADSORBED SOIL (UG/G) 2.749Eq36 SOIL AIR (UG/ML) 1.090E~5 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4.156E-05 ADSORBED SOIL (UG/G) 2.752Eq36 SOIL AIR (UG/ML) 1.091 Eq:)5 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 2.573E-06 ADSORBED SOIL (UG/G) 1.704E~37 SOIL AIR (UG/ML) 6.757E-07 MAY~ POLL DEPTH (M) 1.659E+01 YEAR - 70 ANNUAL SUMMARY REPORT ================================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.(XX)E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.308E+01 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 4.018E-01 TOTAL DEGRADED (MOISTURE) 5.793E+01 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.337E+01 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.011E-06 ADSORBED SOIL (UG/G) 1.994E-07 SOIL AIR (UG/ML) 7.908E-07 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3,025E-06 ADSORBED SOIL (UG/G) 2.004E-07 SOIL AIR (UG/ML) 7.945E-07 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3,147E-07 ADSORBED SOIL (UG/G) 2.084E-08 SOIL AIR (UG/ML) 8.263E-08 MAX. POLL DEPTH (M) 2.000E+01 YEAR - 80 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.(XX)E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIl~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.581 E + 00 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 8.536E-02 TOTAL DEGRADED (MOISTURE) 3.953E+00 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.020E+00 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.071E-07 ADSORBED SOIL (UG/G) 1.371E-08 SOIL AIR (UG/ML) 5.437E~8 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.063E-07 ADSORBED SOIL (UG/G) 1.367E~8 SOIL AIR (UG/ML) 5.419E-08 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.843E-08 ADSORBED SOIL (UG/G) 1.883E-09 SOIL AIR (UG/ML) 7.466E-09 MAX. POLL DEPTH (M) 2.341E+01 YEAR - 90 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWI~R SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7,797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) q3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.024E+00 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.072E+00 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.225E+00 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.351E~)7 ADSORBED SOIL (UG/G) 8.946E~39 SOIL AIR (UG/ML) 3.546Eq38 SOIL ZONE 2: SUBLAYER I SOIL MOISTURE (UG/ML) 5.662Eq38 ADSORBED SOIL (UG/G) 3.749Eq39 SOIL AIR (UG/ML) 1.486E~38 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.165E-08 ADSORBED SOIL (UG/G) 7.715E.10 SOIL AIR (UG/ML) 3.058E~9 MAY~ POLL DEPTH (M) 2.681E+01 YEAR - 99 ANNUAL SUMMARY REPORT ================================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.0(X)E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 7.091E-01 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 9.893E-01 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 7.493Eq31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 9.350E-08 ADSORBED SOIL (UG/G) 6.192E-09 SOIL AIR (UG/ML) 2.455Eq38 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5,222E~8 ADSORBED SOIL (UG/G) 3.459Eq:)9 SOIL AIR (UG/ML) 1,371Eq38 SOIL ZONE 3: LOWER SOIL ZONE: SUBLAYER, 1 SOIL MOISTURE (UG/ML) 7.125E-09 ADSORBED SOIL (UG/G) 4.719E-10 SOIL AIR (UG/ML) 1.871Eq39 MAY~ POLL DEPTH (M) 2.988E+01 *********************************************** COMPLETED**************************************** SESOIL~4: SEASONAL CYCLES OF WATEFL SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. MTrLE INC. ,(617)864-5770~5871 *-~-~-~ J. WAGNER ,DIS/ADLPIPE, INC. ,(617)492-1991~5820 MODIFIED EXTENSIVELY BY: D.M. HETRICK OAK RIDGE NATIONAL LABORATORY (615) 576-7556 ..... VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION ~-~ MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : ETHYLBENZENE WASHLOAD DATA : APPLICATION ARF-N ARCO 1960, BAKERSFIELD, CA - ETHYLBENZENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200Eq31 CATION EXCHANGE CAPACITY (MILLI EQ,/IOOG DRY SOIL): ,000 FREUNDLICH EXPONENT (-): 1.(30 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 161. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .760Eq31 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .844E-01 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 871. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 106. VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200Eq32 DEGRADATION RATE ON SOIL (/DAY): .000 LIGANI~POLLUTANT STABILITY CONSTANT (-): .000 NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPUCATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 3 YEARS TO BE SIMULATED: 99 AREA (CM**2): 0.446E+06 APPUCATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPUCATION (0): 1 DEPTHS (CM): 0.30E+03 0.76E+03 0.42E+04 NUMBER OF SUBLAYERS/LAYER 1 I 1 PH (CM): 7.0 7.0 7.0 INTRINSIC PERMEABIMTIES (CM**2): 0.10E~7 0.10E~35 0.10E~4 KDEL RATIOS (-): 1.0 1.0 KDES RATIOS (-): 1.0 1.0 OC RATIOS (-): 1.0 1.0 CEC RATIOS (-): 1.0 1.0 FRN RATIOS(-): 1.0 1.0 ADS RATIOS(-): 1.0 1.0 YEAR - I MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.030 0.030 0.030 0.000 0.000 0.000 0.030 0.030 0.030 0.000 0.003 0.000 CLOUD CVR (FRAC.) 0.000 0.030 0.030 0.000 0.030 0.0(X) 0.000 0.030 0.000 0.0(X) 0.0(X) 0.000 REL. HUM.(FRAC.) 0.000 0.000 0,030 0,0(X) 0.000 0,000 0.0(X) 0.000 0.030 0.0(X) 0.000 0.0(X) ALBEDO (-) 0.030 0.030 0.030 0.000 0.000 0.030 0.030 0.000 0.030 0.000 0.000 0.030 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PREClP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 - POLLUTANT INPUT PARAMETERS - POL, INP-1 (UG/CM**2) 6.50E+03 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+03 0,00E+00 0.00E+00 0.00E+00 TRNSFORMD~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+03 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0,00E+00 0.00E+00 0,00E+03 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+03 0.00E+00 0,00E+00 0.00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E+ 03 0.00E +00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E+00 O.OOE+00 0.00E +00 VOLATILIZATION MULT.-1 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+00 0.OOE+00 0.00E+ 00 SURFACE RUNOFF MULT. 0.03E + 00 0.00E + 00 0.00E + 00 0.00E + 000.00E +00 0.00E+00 0.00E + 000.00E + 00 0.00E+00 0.00E +00 O.00E + O0 0.00E+00 POL. IN RAIN (FRAC-SL) 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E + 00 POL. INP-2 (UG/CM**2) 6.21E +03 0.00E+00 0.00E+00 0.03E+00 0.00E+03 0.00E+00 0.00E+00 O.00E+00 0.00E +00 0.00E+00 0,00E +00 0.00E + 00 TRNSFORMI~2 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CMt*2) 0.00E + 00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E +00 0.00E +00 0.00E + 00 0.00E+00 0.00E+00 O.OOE+O00.00E +00 VOLATILIZATION MULT.-2 1.00E+00 1.00E + 00 1.00E + 00 1.00E+00 1.00E +00 1.03E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 APPENDIX D SESOIL Output File Diskettes _ . ) ~GROUNDWATER i~! I~!TECHNOLOGY APPENDIX E Abbreviated SESOIL Output Files - Inhalation Risk :~[~ITECHNOLOGY SESOIL~4: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS DEVELOPERS: M. BONAZOUNTAS,~J~:ITHUR D. MTTLE INC. ,(617)864~'770~(5871 ***** J. WAGNER ,DIS/ADLPIPE, INC. ,(617)492-1991~5820 MODIFIED EXTENSIVELY BY: D.M. HETRICK OAK RIDGE NATIONAL LABORATORY (615) 576-7556 VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION **-~ MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : BENZENE WASHLOAD DATA : APPLICATION AREA: ARCO 1960, BAKERSFIELD, CA - BENZENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .0(X) DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E-01 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): ,000 FREUNDLICH EXPONENT (-): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): .179E+04 DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .870E-01 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .543Eq32 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 98.0 ADSORPTION COEFFICIENT ON SOIL (10: .000 MOLECULAR WEIGHT (G/MOL): 78.1 VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200E~32 DEGRADATION RATE ON SOIL (/DaY): .000 LIGAND-POLLUTANT STABILITY CONSTANT (-): .000 NO, MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPLICATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 3 YEARS TO BE SIMULATED: 5 AREA (CM**2): 0,446E+06 APPMCATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPLICATION (0): 1 DEPTHS (CM): 0.30E+03 0.76E+03 0.42E+04 NUMBER OF SUBLAYERS/LAYER 1 1 1 PH (CM): 7.0 7.0 7.0 INTRINSIC PERMEABIMTIES (CM**2): 0.10E~)7 0.10E~5 0.10E~4 KDEL RATIOS (-): 1.0 1.0 KDES RATIOS (-): 1.0 1.0 OC RATIOS (-): 1.0 1,0 CEC RATIOS (-): 1,0 1.0 FRN RATIOS(-): 1.0 1.0 ADS RATIOS(-): 1.0 1.0 YEAR - 1 MONTHLY INPUT PARAMETERS -- CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0.0(X) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0(30 0.000 0.000 0.000 0.000 REL. HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0(X) ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0,140 0.330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 20.400 30.400 30.400 30.400 30.400 20.400 20.400 20.400 20.400 - POLLUTANT INPUT PARAMETERS- POE INP-1 (UG/CM**2) 2.10E+02 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E + 00 0,00E + 00 0.00E + 00 0,00E+ 00 0.00E + 00 0.00E+00 0,00E + 00 0.00E+ 00 0.00E + 00 0.00E+00 0.00E+ 00 0,00E+00 VOLATILIZATION MULT.-1 1.00E +00 1.00E+00 1,00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E +00 1,00E+00 SURFACE RUNOFF MULT. 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E + 00 0.00E+ 000.00E + 00 0.00E+00 0.00E+ 00 0.00E +00 0.00E +00 POE IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 POL, INP-2 (UG/CM**2) 2,05E+02 0.00E+00 0,00E+00 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+ 00 0.0OE + 00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E+ 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 0.00E+00 0.00E+00 O.OOE + O0 0. OOE + O0 VOLATILIZATION MULT.-2 1.00E + O0 1.00E + 00 1.00E + 00 1.00E+O0 1.00E+ 00 1.00E+00 1.00E+00 1.00E + 00 1.00E+ 00 1.00E+00 1.00E + 00 1.00E+00 POL. INP-L (UG/CM**2) 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E + 00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E +00 0.00E+(X) 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 VOLATILIZATION MULT.-L 1.00E+00 1.00E + 00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 YEAR - 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0,00E +00 0.00E+ 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+00 0.00E + 00 0.00E+00 0.00E+ 00 0.0OE+00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+O0 SURFACE RUNOFFMULT. ~~~~E+~~~-~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E +00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E + 00 POL. INP-2 (UG/CM**2) 0.00E+ 00 0,00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.0OE+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+ 00 TRNSFORMD~2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0,00E+ 00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0,00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0,00E+ 00 0,00E+00 0.00E+ 00 0,00E +00 0,00E + 00 0.00E+ 00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+00 1.00E +00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POL. INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 SINK~L (UG/CM**2) 0,00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0,00E + 00 0.00E +00 0,00E +00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 VOLATILIZATION MULT,-L 1,00E+00 1.00E+00 1.00E+00 1.00E+00 1,00E+00 1.00E+00 1,00E+00 1,00E+00 1.00E+00 1,00E+00 1.00E+00 1.00E+00 YEAR. 5 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 9.366E+07 SOIL ZONE 2 9.143E+07 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.940 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.940 TOTAL PRECIPITATION (CM) 15.882 TOTAL INFILTRATION (CM) 15.882 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 14.075 TOTAL MOISTURE RETENTION (CM) -1.841 TOTAL YIELD (CM) i4.075 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 8.766E + 07 TOTAL DEGRADED (MOISTURE) 9.747E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.184E+07 TOTAL DEGRADED (MOISTURE) 2.567E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.111E+00 ADSORBED SOIL (UG/G) 2.178E~32 SOIL AIR (UG/ML) 2.675Eq31 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.366E+00 ADSORBED SOIL (UG/G) 2.678Eq32 SOIL AIR (UG/ML) 3.281Eq31 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 6.943E+00 YEAR - 2 ANNUAL SUMMARY REPORT ================================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 1.635E + 07 TOTAL DEGRADED (MOISTURE) 1.753E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.409E+07 TOTAL DEGRADED (MOISTURE) 1.383E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.238E-01 ADSORBED SOIL (UG/G) 4.387E~3 SOIL AIR (UG/ML) 5.377E-02 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 7.095E-01 ADSORBED SOIL (UG/G) 1.391E-02 SOIL AIR (UG/ML) 1.704E-01 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL DEPTH (M) 7.070E+00 YEAR - 3 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E + 00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOl[. SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 7.776E + 06 TOTAL DEGRADED (MOISTURE) 8.344E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 6.950E + 06 TOTAL DEGRADED (MOISTURE) 6.741E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.069E~31 ADSORBED SOIL (UG/G) 2.096E~33 SOIL AIR (UG/ML) 2.569Eq32 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.458Eq31 ADSORBED SOIL (UG/G) 6.778E~3 SOIL AIR (UG/ML) 8.307E-02 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL DEPTH (M) 7.197E+00 YEAR - 4 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOiL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 3.786E + 06 TOTAL DEGRADED (MOISTURE) 4.063E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 3.384E+06 TOTAL DEGRADED (MOISTURE) 3.283E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.207Eq32 ADSORBED SOIL (UG/G) 1.021E-03 SOIL AIR (UG/ML) 1.251 E-02 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.684Eq31 ADSORBED SOIL (UG/G) 3.300E-03 SOIL AIR (UG/ML) 4.045E~2 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 7.324E+00 YEAR - 5 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~).131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOII~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 1.843E + 06 TOTAL DEGRADED (MOISTURE) 1.978E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.647E+06 TOTAL DEGRADED (MOISTURE) 1.598E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2,535E~32 ADSORBED SOIL (UG/G) 4,g68E434 SOIL AIR (UG/ML) 6.088E~33 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8,197E~32 ADSORBED SOIL (UG/G) 1.607Eq33 SOIL AIR (UG/ML) 1.969E-02 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 7.451E+00 ************************************************ COMPLETED**************************************** -" ***** SESOIL-84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. LITTLE INC. ,(617)864-5770,X5871 ***** J. WAGNER ,DIS/AD[PIPE, INC. ,(617)492-1991,X5820 **"~ ***** MODIFIED EXTENSIVELY BY: ***** D.M. HETRICK ***** OAK RIDGE NATIONAL LABORATORY ***** ***** (615) 576-7556 ***** VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : TOLUENE WASHLOAD DATA : APPLICATION AREA: ARCO 1960, BAKERSFIELD, CA - TOLUENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E-O1 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): .000 FREUNDLICH EXPONENT (-): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 535. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): ,830E-01 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .594E..02 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 331. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 92,1 VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL. DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200E-02 DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND-POLLUTANT STABILITY CONSTANT (-): .0(30 NO. MOLES LIGAND/MOLE POLLUTANT (-): .(X)O LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPUCATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 3 YEARS TO BE SIMULATED: 5 AREA (CM**2): 0.446E + 06 APPLICATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPECATION (0): 1 DEPTHS (CM): 0.30E+03 0.76E+03 0.42E+04 NUMBER OF SUBLAYERS/LAYER 1 I 1 PH (CM): 7.0 7.0 7.0 INTRINSIC PERMEABIMTIES (CM**2): 0.10E~37 0.10E-05 0.10E-04 KDEL RATIOS (-): 1.0 1.0 KDES RATIOS (-): 1.0 1.0 OC RATIOS (o): 1.0 1.0 CEC RATIOS (-): 1.0 1,0 FRN RATIOS(-): 1,0 1,0 ADS RATIOS(-): 1,0 1.0 YEAR. I MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0,000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 REL. HUM.(FRAC.) 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PREClP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.4~3 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2,420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 -- POLLUTANT INPUT PARAMETERS - POL, INP-1 (UG/CM**2) 1.72E+04 O,OOE+O00.OOE + O00.OOE+O00.OOE+O00,OOE+O00,OOE+O00.OOE+O00.OOE+O00,OOE+O0 O.OOE+O00,OOE+O0 TRNSFORMD~I (UG/CM**2) O.OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 LIG.INPUT-1 (UG/CM**2) 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E +00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 O.0OE+ 00 VOLATILIZATION MULT.-1 1.00E+ 00 1.00E +00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 SURFACE RUNOFF MULT. 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E +00 0.00E+00 0.00E + 00 O.OOE+ O00.OOE+O0 POL, IN RAIN (FRAC-SL) O.OOE+O00.OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE~O0 0.00E+00 0.00E+00 POL. INP-2 (UG/CM**2) 1.72E+04 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+O00,OOE+ O0 TRNSFORMD-2 (UG/CM**2) O.OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O0 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E +00 O.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 0.00E+00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 O. OOE + O0 0. OOE + O0 VOLATILIZATION MULT.-2 1.00E+00 1.00E+ OO 1.00E + 00 1.00E+ 00 1.00E +00 1.00E + OO 1.00E+00 1.00E+ 00 1.00E+00 1.00E + 00 1.00E+00 1.00E+00 POI- INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+OO O.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E + 00 0.0OE+00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E +00 VOLATILIZATION MULT.-L 1.00E+00 1.00E+00 1.00E+ 00 1.00E+00 1.00E+00 1.00E + 00 1.00E+00 1.00E+00 1.00E+00 1.00E+ 00 1.00E+00 1.00E+00 YEAR. 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 TRNSFORMD~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E + 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 SURFACE RUNOFFMULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E + 00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE + 00 0.00E+00 POL. INP-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+ 00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINK~2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E + 00 LIG.INPUT-2 (UG/CM**2) 0.00E +00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E+00 0.00E +00 0.00E + 00 0.00E+00 0.0OE + 00 0.00E+ 00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E +00 POL. INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-L 1.00E+ 00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+ 00 YEAR - 5 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR * 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 7.662E+09 SOIL ZONE 2 7.662E+09 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.940 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.940 TOTAL PRECIPITATION (CM) 15.882 TOTAL INFILTRATION (CM) 15.882 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 14.075 TOTAL MOISTURE RETENTION (CM) -1.841 TOTAL YIELD (CM) 14.075 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 6.686E + 09 TOTAL DEGRADED (MOISTURE) 7,064E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 5.681E + 08 TOTAL DEGRADED (MOISTURE) 1,623E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.284E+01 ADSORBED SOIL (UG/G) 5.486E+00 SOIL AIR (UG/ML) 2.180E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.675E+01 ADSORBED SOIL (UG/G) 5.745E+00 SOIL AIR (UG/ML) 2.279E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 6,905E+00 YEAR - 2 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL. SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 1.424E + 09 TOTAL DEGRADED (MOISTURE) 1.462E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.109E+09 TOTAL DEGRADED (MOISTURE) 1.079E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - 'UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.870E+01 ADSORBED SOIL (UG/G) 1.238E+00 SOIL AIR (UG/ML) 4.914E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.583E+01 ADSORBED SOIL (UG/G) 3.698E+00 SOIL AIR (UG/ML) 1.467E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAX~ POLl_ DEPTH (M) 6.994E+00 YEAR - 3 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.7~7 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.0(X) TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 7.812E+08 TOTAL DEGRADED (MOISTURE) 8.043E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 6.950E+08 TOTAL DEGRADED (MOISTURE) 6.477E+08 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.039E+01 ADSORBED SOIL (UG/G) 6.878E~)1 SOIL AIR (UG/ML) 2.728E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.349E+01 ADSORBED SOIL (UG/G) 2.218E+00 SOIL AIR (UG/ML) 8.798E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLl_ DEPTH (M) 7.083E+00 YEAR - 4 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~).131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 4.656E + 08 TOTAL DEGRADED (MOISTURE) 4.794E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 4.162E+08 TOTAL DEGRADED (MOISTURE) 3.873E+08 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.193E+00 ADSORBED SOIL (UG/G) 4.101E~31 SOIL AIR (UG/ML) 1.627E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE'(UG/ML) 2.003E+01 ADSORBED SOIL (UG/G) 1.326E+00 SOIL AIR (UG/ML) 5.261E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL DEPTH (M) 7.172E+00 YEAR o 5 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.0O0E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INRLTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL. SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 2.782E + 08 TOTAL DEGRADED (MOISTURE) 2.865E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 2.487E + 08 TOTAL DEGRADED (MOISTURE) 2.315E+08 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.701E+00 ADSORBED SOIL (UG/G) 2.451E~)1 SOIL AIR (UG/ML) 9.722E-01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.197E+01 ADSORBED SOIL (UG/G) 7.926E-01 SOIL AIR (UG/ML) 3.144E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLl- DEPTH (M) 7.261E+00 *********************************************** COMPLETED**************************************** ***** SESOIL~4: SEASONAL CYCLES OF WATEFL SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,~RTHUR D. I.ITrLE INC. ,(617)864-5770~5871 ***** J. WAGNER ,DIS/ADLPIPE, INC. ,(617)492-1991~0 ***** MODIFIED EXTENSIVELY BY: ~--~-~-~ ***** D.M. HETRICK -'-~-~--~ ***** OAK RIDGE NATIONAL LABORATORY ***** (615) 576-7556 ~-~-~ ***** VERSION : SEPTEMBER 1986 -~-~-~- *~ MONTHLY SESOIL MODEL OPERATION *~-~-~ MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : ETHYLBENZENE WASHLOAD DATA : APPLICATION AREA: ARCO 1960, BAKERSFIELD, CA - ETHYLBENZENE WARNING- SOIL PERMEABlUTY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (.): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E~1 CATION EXCHANGE CAPACITY (MILLI EQ./IOOG DRY SOIL): .O(X) FREUNDLICH EXPONENT (-): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 161. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .760E~1 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .844E~)1 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 871. ADSORPTION COEFFICIENT ON SOIL (10: .O(X) MOLECULAR WEIGHT (G/MOL): 106. VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200Eq32 DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND-POLLUTANT STABILITY CONSTANT (-): .O(X) NO. MOLES LIGAND/MOLE POLLUTANT (-): LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPUCATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 3 YEARS TO BE SIMULATED: 5 AREA (CM**2): 0,446E+ 06 APPMCATION AREA LATITUDE (DEG.): 36,0 SPILL (1) OR STEADY APPUCATION (0): 1 DEPTHS (CM): 0,30E+03 0.76E+03 0.42E+04 NUMBER OF SUBLAYERS/LAYER I 1 1 PH (CM): 7,0 7,0 7,0 INTRINSIC PERMEABIUTIES (CM**2): 0,10E~7 0,10E~5 0,10E~:)4 KDEL RATIOS (-): 1,0 1,0 KDES RATIOS (-): 1,0 1,0 OC RATIOS (-): 1.0 1,0 CEC RATIOS (-): 1,0 1,0 FRN RATIOS(-): 1.0 1,0 ADS RATIOS(-): 1,0 1,0 YEAR - I MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP, (DEG C) 0.000 0.000 0.000 0,000 0.000 0,000 0.000 0.000 0.000 0,0(X) 0,000 0,000 CLOUD CVR (FRAC.) 0.000 0,000 0,000 0.000 0.000 0,000 0,000 0,000 0,000 0.000 0.000 0,000 REL. HUM,(FRAC.) 0,000 0.000 0,000 0.000 0.0(X) 0.000 0,0(X) 0.000 0.0(X) 0,000 0,0(X) 0.000 ALBEDO (-) 0,000 0.000 0.000 0,000 0.0(X) 0,0(X) 0.000 0.000 0,(XX) 0,000 0,0(X) 0,000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0,010 0.010 0,010 0.010 0.010 0.010 0,010 0,010 0,010 PRECIP, (CM) 0.840 1.420 1.980 2,620 2.540 2,640 1.550 0,740 0.200 0,030 0,080 0,330 M.TIME RAIN(DAYS) 0.140 0,330 0,370 0,400 0.400 0,370 0,330 0,160 0,040 0,010 0,040 0,100 M. STORM NO. (-) 0.800 1.770 1.850 2,940 2.740 2,420 1.820 0.510 0.140 0.090 0,110 0.410 M. SEASON (DAYS) 30,400 30.400 30,400 30.400 30,400 30,400 30,400 30,400 30,400 30,400 30,400 30,400 o- POLLUTANT INPUT PARAMETERS - POL, INP-1 (UG/CM**2) 6,50E+03 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 SINK~I (UG/CM**2) 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00.0,00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E+ 00 0,00E+ 00 0,00E + 00 0.00E + 00 0,00E+ 00 0,00E+00 0,00E+ 00 0,00E +00 0,00E+00 0,00E+00 0.00E+00 0.OOE + 00 VOLATILIZATION MULT.-1 1.00E+00 1,00E+00 1.00E+00 1.00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1.00E +00 1,00E+00 SURFACE RUNOFF MULT, 0.00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0,00E+00 0.00E + 00 0.00E + 00 0,00E+ 00 0,00E+00 0.00E +00 0.00E + 00 POL. IN RAIN (FRAC-SL) 0.00E +00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 POL. INP-2 (UG/CM**2) 6,21E+03 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 TRNSFORMD~2 (UG/CM**2) 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM""2) 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.0OE +00 LIG,INPUT-2 (UG/CM**2) 0.00E + 00 0,00E + 00 0,00E +00 0.00E + 00 0,00E+00 0,00E+00 0,00E+ 00 0,00E + 00 0.00E+00 0,00E+00 O.0OE + 00 O.0OE + 00 VOLATILIZATION MULT.-2 1.00E+00 1,00E + 00 1.00E + 00 1.00E +00 1.00E+ O0 1,00E+00 1.00E + 00 1,0OE+ 00 1,00E+00 1,00E+O0 1.00E+00 1,00E+00 POE INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LI G.IN PUT-L (UG/CM **2) O.00E + 00 0.00E + 00 0.0OE + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 O.00E + 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-L 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+ 00 1.00E +00 1.00E+ 00 1.00E+ 00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 YEAR - 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS- P~L~ INP-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 1.00E+00 1.00E +00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+O0 1.00E+O0 1.00E+00 1.00E+ 00 1,00E+00 SURFACE RUNOFF MULT. 0.00E + 00 0.00E+00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E + 00 0.00E+ 000.00E+ 00 0.00E+00 0.00E+00 0.00E +00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 POL. INP-2 (UG/CM**2) 0.00E+00 0.00E+00 O.00E + 00 0.OOE+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+O00.OOE+O0 TRNSFORMD-2 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 O.00E+00 0.00E+ 00 0.00E+00 0.00E +00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-2 1.00E + 00 1.00E+00 1.00E + 00 1.00E+ 00 1.00E + 00 1.00E+00 1.00E+ 00 1.00E + 00 1.00E + 00 1.00E+ 00 1.00E+00 1.00E+ 00 POL. INP-L (UG/CM*'2) 0.00E+00 0.00E+00 O.00E+00 0.00E + O00.00E+00 0.00E+00 0.00E+00 O.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+ 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E +00 0.00E +00 0.00E+00 VOLATILIZATION MULT.-L 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 I:00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+ 00 YEAR - 5 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - I ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 2.899E+09 SOIL ZONE 2 2.770E+09 SOIL ZONE 3 0.(XX)E+00 LOWER SOIL ZONE 0.0(X)E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 7.940 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.940 TOTAL PRECIPITATION (CM) 15.882 TOTAL INFILTRATION (CM) 15.882 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 14.075 TOTAL MOISTURE RETENTION (CM) -1.841 TOTAL YIELD (CM) 14.075 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL/MR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 3.699E + 09 TOTAL DEGRADED (MOISTURE) 2.999E+07 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.038E+09 TOTAL DEGRADED (MOISTURE) 1.104E+08 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 3.272E+00 ADSORBED SOIL (UG/G) 5.699E~31 SOIL AIR (UG/ML) 1.224E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.857E+00 ADSORBED SOIL (UG/G) 1.020E+00 SOIL AIR (UG/ML) 2.187E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 6.833E+00 YEAR - 2 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 8.861E + 08 TOTAL DEGRADED (MOISTURE) 7.020E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 7.867E+08 TOTAL DEGRADED (MOISTURE) 5.644E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.982E~)1 ADSORBED SOIL (UG/G) 1.565E~31 SOIL AIR (UG/ML) 3.354E+00 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.891E+00 ADSORBED SOIL (UG/G) 5.035E~1 SOIL AIR (UG/ML) 1.079E+01 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 6.851E+00 YEAR - 3 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 4.253E + 08 TOTAL DEGRADED (MOISTURE) 3.370E+06 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 3.777E+08 TOTAL DEGRADED (MOISTURE) 2.710E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4.312E-01 ADSORBED SOIL (UG/G) 7.510E-02 SOIL AIR (UG/ML) 1.610E+00 SOIL ZONE 2: SUBLAYER 1 SOiL MOISTURE (UG/ML) 1.388E+00 ADSORBED SOIL (UG/G) 2.417E-01 SOIL AIR (UG/ML) 5.182E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 6.869E+00 YEAR - 4 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.(}00E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 2.042E + 08 TOTAL DEGRADED (MOISTURE) 1.618E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.814E+08 TOTAL DEGRADED (MOISTURE) 1.301E+07 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.070E~)1 ADSORBED SOIL (UG/G) 3.605E~)2 SOIL AIR (UG/ML) 7.728E~1 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.663E~1 ADSORBED SOIL (UG/G) 1.161E~)1 SOIL AIR (UG/ML) 2.488E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 6.886E+00 YEAR - 5 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15,865 TOTAL INFILTRATION (CM) 15,865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.0(X) TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) q3.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 9.806E + 07 TOTAL DEGRADED (MOISTURE) 7.770E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 8.711E+07 TOTAL DEGRADED (MOISTURE) 6.249E+06 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 9.941E~32 ADSORBED SOIL (UG/G) 1.732E~2 SOIL AIR (UG/ML) 3.712E-01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.200Eq31 ADSORBED SOIL (UG/G) 5.575E~32 SOIL AIR (UG/ML) 1.195E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 6.904E+00 *********************************************** COMPLETED**************************************** ***** SESOIL-84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,~ITHUR D. UTrLE INC. ,(617)864-5770~5871 ***** .... * J. WAGNER ,DIS/ADLPIPE, INC. ,(617)492-1991~5820 ***** ***** MODIFIED EXTENSIVELY BY: *~ ***** D.M. HETRICK ~--~-~ ***** OAK RIDGE NATIONAL LABORATORY ***** ***** (615) 576-7556 ***** VERSION : SEPTEMBER 1986 ***** ****** MONTHLY SESOIL MODEL OPERATION MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : 1,2-XYLENE WASHLOAD DATA : APPLICATION AREN ARCO 1960, BAKERSFIELD, CA - XYLENE ISOMERS WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .0(X) DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E~31 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): .000 FREUNDLICH EXPONENT (-): 1.00 -- CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 175. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .760Eq31 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .510Eq32 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 871. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 106. VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT ~DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200E~)2 DEGRADATION RATE ON SOIL (/DAY): .000 LIGANI~POLLUTANT STABILITY CONSTANT (-): .000 NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPLICATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 3 YEARS TO BE SIMULATED: 5 AREA (CM**2): 0.446E+06 APPLICATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPLICATION (0): 1 DEPTHS (CM): 0.30E+03 0.76E+03 0.42E+04 NUMBER OF SUBLAYERS/LAYER 1 1 1 PH (CM): 7.0 7.0 7.0 INTRINSIC PERMEABILITIES (CM**2): 0.10E~7 0.10E~35 0.10E-04 KDEL RATIOS (-): 1.0 1.0 KDES RATIOS (-): 1.0 1.0 OC RATIOS (-): 1.0 1.0 CEC RATIOS (-): 1.0 1.0 FRN RATIOS(-): 1.0 1.0 ADS RATIOS(-): 1.0 1.0 YEAR - I MONTHLY INPUT PARAMETERS -- CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP, (DEG C) 0.0(X) 0.000 0.0(X) 0.000 0.000 0.0(X) 0.000 0.0(X) 0.000 0.000 0.000 0.000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 REL. HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 0.000 0.000 0,000 0.000 0.000 ALBEDO (-) 0.(X:)0 0.000 0.0(X) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0,010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.4~30 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30,400 20.400 30.400 30.400 30.400 30.400 20.400 30.400 30.400 30,400 20.400 20.400 -- POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 9.73E+04 0.00E + 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORM[~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~.~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E + 00 0,00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+ 00 O.00E + 00 0.00E+00 VOLATILIZATION MULT.-1 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 SURFACE RUNOFF MULT. 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E+00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E +00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 POL. INP-2 (UG/CM**2) 8.41E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E +00 0.00E +00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E + 00 0.00E+00 0.00E+ 00 O.OOE + O0 0.OOE + O0 VOLATILIZATION MULT.-2 1.00E + 00 1.0OE + O0 1.00E+00 1.00E +00 1.00E + 00 1.00E+00 1.00E+00 1.00E + 00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 P~L. INP-L (UG/CM**2) 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM~2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SlNKS-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 VOLATILIZATION MULT.-L 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 YEAR - 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT pARAMETERS - POE INP-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT.1 (UG/CM**2) 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 1.00E + 00 1.00E+O0 1.00E + 00 1.00E+00 1.00E+00 1.00E+00 1.00E+ 00 1.00E + 00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 SURFACE RUNOFFMULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ O.00E +00 0.00E+00 POE IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE +00 O.OOE+O0 P~L. INP-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM*"2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 O.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E +00 0.00E + 00 0.00E +00 VOLATILIZATION MULT.-2 1.00E+00 1.00E + 00 1.00E+00 1.00E+00 1.00E+ 00 1.00E +00 1.00E+00 1.00E +00 1.00E+00 1.00E+00 1.00E + 00 1.00E+ 00 POE INP-L (UG/CM**2) 0.00E+00 0.00E +00 0,OOE+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD~L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 SINKS-L (UG/CM**2) 0.00E + 00 0.00E +00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 LIG.INPUT-L (UG/CM**2) 0,00E + O0 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+ 00 0,00E+00 0.00E+00 VOLATILIZATION MULT.-L 1.00E+00 1.0OE+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+ 00 YEAR - 5 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 4.340E+ 10 SOIL ZONE 2 3.753E+ 10 SOIL ZONE 3 0.000E + 00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.940 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.940 TOTAL PRECIPITATION (CM) 15.882 TOTAL INFILTRATION (CM) 15.882 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 14.075 TOTAL MOISTURE RETENTION (CM) -1.841 TOTAL YIELD (CM) 14.075 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 9.899E + 09 TOTAL DEGRADED (MOISTURE) 1.352E+09 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.304E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3,944E+01 PURE PHASE (UG/ML) 2.546E+03 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1,750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 5.078E+02 SOIL ZONE 3: LOWER SOIL ZONE: MAY~ POLL, DEPTH (M) 6.871E+00 YEAR - 2 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.(XX)E +00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 1.011E + 10 TOTAL DEGRADED (MOISTURE) 1.328E+09 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.317E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 1.530E+03 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 3.943E+02 SOIL ZONE 3: LOWER SOIL ZONE: MArC POLL DEPTH (M) 6.927E+00 YEAR - 3 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E + O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 7,797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0.131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 1.011 E+ 10 TOTAL DEGRADED (MOISTURE) 1.328E+09 SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.317E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 5.071E + 02 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 2.789E+02 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL. DEPTH (M) 6.982E+00 YEAR - 4 ANNUAL SUMMARY REPORT ========================= - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) -0,131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL. SOILAIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 6.322E + 09 TOTAL DEGRADED (MOISTURE) 8.246E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.518E+09 TOTAL DEGRADED (MOISTURE) 3.317E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.046E+02 ADSORBED SOIL (UG/G) 1.822E+01 SOIL AIR (UG/ML) 2.361E+01 SOIL ZONE 2: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 1.415E+02 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 7.037E+00 YEAR - 5 ANNUAL SUMMARY REPORT ================================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.0(X)E+I30 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 7.797 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 7.797 TOTAL PRECIPITATION (CM) 15.865 TOTAL INFILTRATION (CM) 15.865 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.348 TOTAL MOISTURE RETENTION (CM) ~).131 TOTAL YIELD (CM) 12.348 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL VOLATILIZED 3.171E + 09 TOTAL DEGRADED (MOISTURE) 4.154E+08 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 2.489E+09 TOTAL DEGRADED (MOISTURE) 3.080E+09 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.389E+01 ADSORBED SOIL (UG/G) 9.387E+00 SOIL AIR (UG/ML) 1.215E+01 SOIL ZONE 2: SUBLAYER I SOIL MOISTURE (UG/ML) 1.611E+02 ADSORBED SOIL (UG/G) 2.806E+01 SOIL AIR (UG/ML) 3.632E+01 PURE PHASE (UG/ML) 6.369E+00 SOIL ZONE 3: LOWER SOIL ZONE: MAX. POLL DEPTH (M) 7.092E+00 *********************************************** APPENDIX F SCREEN Output Files i~__J[~,?~iTECUNOLO(;Y 1 12-19-91 13:38:46 *** SCREEN-i.1 MODEL RUN *** *** VERSION DATED 88300 *** ~ .lzene emissions from an area source (20' X 20') at ARCO No. 1960. SIMPLE TERRAIN INPUTS: SOURCE TYPE = AREA EMISSION RATE (G/S) = .2780E-06 SOURCE HEIGHT (M) = 1.00 LENGTH OF SIDE (M) = 6.10 RECEPTOR HEIGHT (M) = .00 IOPT (I=URB,2=RUR) = 1 *** FULL METEOROLOGY *** *** SCREEN AUTOMATED DISTANCES *** *** TERRAIN HEIGHT OF .00 M ABOVE STACK BASE USED FOR FOLLOWING DISTANCES *** DIST CONC U10M USTK MIX HT PLUME SIGMA SIGMA (M) (UG/M**3) STAB (M/S) (M/S) (M) HT (M) Y (M) Z (M) DWASH 1. .3637E-04 i 1.0 1.0 320.0 1.0 1.7 .2 NO 100. .9676E-03 5 1.0 1.0 5000.0 1.0 12.1 7.5 NO 200. .2798E-03 5 1.0 1.0 5000.0 1.0 22.5 14.0 NO 300. .1366E-03 5 1.0 1.0 5000.0 1.0 32.5 19.9 NO 400. .8306E-04 5 1.0 1.0 5000.0 1.0 42.1 25.3 NO 500. .5691E-04 5 1.0 1.0 5000.0 1.0 51.4 30.2 NO 600. .4204E-04 5 1.0 1.0 5000.0 1.0 60.4 34.8 NO 700. .3270E-04 5 1.0 1.0 5000.0 1.0 69.2 39.1 NO 800. .2639E-04 5 1.0 1.0 5000.0 1.0 77.7 43.1 NO 900. .2192E-04 5 1.0 1.0 5000.0 1.0 85.9 47.0 NO 1000. .1860E-04 5 1.0 1.0 5000.0 1.0 94.0 50.6 NO 1100. .1607E-04 5 1.0 1.0 5000.0 1.0 101.8 54.1 NO 1200. .1409E-04 5 1.0 1.0 5000.0 1.0 109.5 57.4 NO 1300. .1250E-04 5 1.0 1.0 5000.0 1.0 116.9 60.6 NO 1400. .1120E-04 5 1.0 1.0 5000.0 1.0 124.2 63.6 NO 1500. .1012E-04 5 1.0 1.0 5000.0 1.0 131.4 66.6 NO 1600. .9215E-05 5 1.0 1.0 5000.0 1.0 138.3 69.4 NO 1700. .8445E-05 5 1.0 1.0 5000.0 1.0 145.1 72.2 NO 1800. .7785E-05 5 1.0 1.0 5000.0 1.0 151.8 74.9 NO 1900. .7212E-05 5 1.0 1.0 5000.0 1.0 158.4 77.5 NO 2000. .6711E-05 5 1.0 1.0 5000.0 1.0 164.8 80.0 NO 2100. .6271E-05 5 1.0 1.0 5000.0 1.0 171.1 82.5 NO 2200. .5880E-05 5 1.0 1.0 5000.0 1.0 177.3 84.9 NO 2300. .5532E-05 5 1.0 1.0 5000.0 1.0 183.4 87.2 NO 2400. .5220E-05 5 1.0 1.0 5000.0 1.0 189.3 89.5 NO 2500. .4940E-05 5 1.0 1.0 5000.0 1.0 195.2 91.8 NO 2600. .4685E-05 5 1.0 1.0 5000.0 1.0 201.0 94.0 NO 2700. .4455E-05 5 1.0 1.0 5000.0 1.0 206.7 96.1 NO 2800. .4244E-05 5 1.0 1.0 5000.0 1.0 212.3 98.2 NO 2900. .4051E-05 5 1.0 1.0 5000.0 217.8 100.3 NO 3000. .3874E-05 5 1.0 1.0 5000.0 1.0 223.2 102.3 NO 3500. .3171E-05 5 1.0 1.0 5000.0 1.0 249.2 112.0 NO 4000. .2675E-05 5 1.0 1.0 5000.0 1.0 273.5 120.9 NO -- .500. .2309E-05 5 1.0 1.0 5000.0 1.0 296.4 129.3 NO 5000. .2028E-05 5 1.0 1.0 5000.0 1.0 318.1 137.2 NO 5500. .1806E-05 5 1.0 1.0 5000.0 1.0 338.7 144.7 NO 6000. .1626E-05 5 1.0 1.0 5000.0 1.0 358.4 151.8 NO 6500. .1479E-05 5 1.0 1.0 5000.0 1.0 377.3 158.6 NO 7000. .1355E-05 5 i.0 1.0 5000.0 1.0 395.5 165.1 NO 7500. .1250E-05 5 1.0 1.0 5000.0 1.0 412.9 171.4 NO 8000. .1160E-05 5 1.0 1.0 5000.0 1.0 429.8 177.5 NO 8500. .1082E-05 5 1.0 1.0 5000.0 1.0 446.2 183.4 NO 9000. .1013E-05 5 1.0 1.0 5000.0 1.0 462.0 189.1 NO 9500. .9525E-06 5 1.0 1.0 5000.0 1.0 477.4 194.6 NO 10000. .8987E-06 5 1.0 1.0 5000.0 1.0 492.3 200.0 NO 15000. .5729E-06 5 1.0 1.0 5000.0 1.0 623.9 247.5 NO 20000. .4198E-06 5 1.0 1.0 5000.0 1.0 733.6 287.4 NO 25000. .3310E-06 5 1.0 1.0 5000.0 1.0 829.4 322.3 NO 30000. .2732E-06 5 1.0 1.0 5000.0 1.0 915.5 353.9 NO 40000. .2233E-06 4 1.0 1.0 320.0 1.0 1552.4 1553.2 NO 50000. .1985E-06 4 1.0 1.0 320.0 1.0 1745.9 1750.0 NO MAXIMUM 1-HR CONCENTRATION AT OR BEYOND 1. M: 10. .2009E-01 5 1.0 1.0 5000.0 1.0 2.6 .9 NO DWASH= MEANS NO CALC MADE (CONC = 0.0) DWASH=NO MEANS NO BUILDING DOWNWASH USED DWASH=HS MEANS HUBER-SNYDER DOWNWASH USED 'WASH=SS MEANS SCHULMAN-SCIRE DOWNWASH USED ~SH=NA MEANS DOWNWASH NOT APPLICABLE, X<3*LB *** SUMMARY OF SCREEN MODEL RESULTS *** CALCULATION MAX CONC DIST TO TERRAIN PROCEDURE (UG/M**3) MAX (M) MT (M) SIMPLE TERRAIN .2009E-01 10. 0. ** REMEMBER TO INCLUDE BACKGROUND CONCENTRATIONS ** *************************************************** 1 12-19-91 13:52:07 *** SCREEN-i.1 MODEL RUN *** *** VERSION DATED 88300 *** ~_xuene emissions from an area source (20' X 20') at ARCO No. 1960. SIMPLE TERRAIN INPUTS: SOURCE TYPE = AREA EMISSION RATE (G/S) = .2090E-03 SOURCE HEIGHT (M) = 1.00 LENGTH OF SIDE (M) = 6.10 RECEPTOR HEIGHT (M) = .00 IOPT (i=URB,2=RUR) = 1 *** FULL METEOROLOGY *** ********************************** *** SCREEN AUTOMATED DISTANCES *** *** TERRAIN HEIGHT OF .00 M ABOVE STACK BASE USED FOR FOLLOWING DISTANCES *** DIST CONC Ul0M USTK MIX HT PLUME SIGMA SIGMA (M) (UG/M**3) STAB (M/S) (M/S) (M) HT (M) Y (M) Z (M) DWASH 1. .2734E-01 1 1.0 1.0 320.0 1.0 1.7 .2 NO 100. .7274 5 1.0 1.0 5000.0 1.0 12.1 7.5 NO 200. .2103 5 1.0 1.0 5000.0 1.0 22.5 14.0 NO 300. .1027 5 1.0 1.0 5000.0 1.0 32.5 19.9 NO 400. .6245E-01 5 1.0 1.0 5000.0 1.0 42.1 25.3 NO 500. .4279E-01 5 1.0 1.0 5000.0 1.0 51.4 30.2 NO 600. .3161E-01 5 1.0 1.0 5000.0 1.0 60.4 34.8 NO 700. .2458E-01 5 1.0 1.0 5000.0 1.0 69.2 39.1 NO 800. .1984E-01 5 1.0 1.0 5000.0 1.0 77.7 43.1 NO 900. .1648E-01 5 1.0 1.0 5000.0 1.0 85.9 47.0 NO 1000. .1399E-01 5 1.0 1.0 5000.0 1.0 94.0 50.6 NO 1100. .1208E-01 5 1.0 1.0 5000.0 1.0 101.8 54.1 NO 1200. .1059E-01 5 1.0 1.0 5000.0 1.0 109.5 57.4 NO 1300. .9394E-02 5 1.0 1.0 5000.0 1.0 116.9 60.6 NO 1400. .8417E-02 5 1.0 1.0 5000.0 1.0 124.2 63.6 NO 1500. .7608E-02 5 1.0 1.0 5000.0 1.0 131.4 66.6 NO 1600. .6928E-02 5 1.0 1.0 5000.0 1.0 138..3 69.4 NO 1700. .6349E-02 5 1.0 1.0 5000.0 1.0 145.1 72.2 NO 1800. .5852E-02 5 1.0 1.0 5000.0 1.0 151.8 74.9 NO 1900. .5422E-02 5 1.0 1.0 5000.0 1.0 158.4 77.5 NO 2000. .5046E-02 5 1.0 1.0 5000.0 1.0 164.8 80.0 NO 2100. .4714E-02 5 1.0 1.0 5000.0 1.0 171.1 82.5 NO 2200. .4421E-02 5 1.0 1.0 5000.0 1.0 177.3 84.9 NO 2300. .4159E-02 5 1.0 1.0 5000.0 1.0 183.4 87.2 NO 2400. .3925E-02 5 1.0 1.0 5000.0 1.0 189.3 89.5 NO 2500. .3714E-02 5 1.0 1.0 5000.0 1.0 195.2 91.8 NO 2600. .3523E-02 5 1.0 1.0 5000.0 1.0 201.0 94.0 NO 2700. .3349E-02 5 1.0 1.0 5000.0 1.0 206.7 96.1 NO 2800. .3191E-02 5 1.0 1.0 5000.0 1.0 212.3 98.2 NO 2900. .3046E-02 5 1.0 1.0 5000.0 ~ 217.8 100.3 NO 3000. .2913E-02 5 1.0 1.0 5000.0 1.0 223.2 102.3 NO 3500. .2384E-02 5 1.0 1.0 5000.0 1.0 249.2 112.0 NO 4000. .2011E-02 5 1.0 1.0 5000.0 1.0 273.5 120.9 NO ....... 500. .1736E-02 5 1.0 1.0 5000.0 1.0 296.4 129.3 NO 3000. .1524E-02 5 1.0 1.0 5000.0 1.0 318.1 137.2 NO 5500. .1358E-02 5 1.0 1.0 5000.0 1.0 338.7 144.7 NO 6000. .1223E-02 5 1.0 1.0 5000.0 1.0 358.4 151.8 NO 6500. .1112E-02 5 1.0 1.0 5000.0 1.0 377.3 158.6 NO 7000. .1019E-02 5 1.0 1.0 5000.0 1.0 395.5 165.1 NO 7500. .9398E-03 5 1.0 1.0 5000.0 1.0 412.9 171.4 NO 8000. .8719E-03 5 1.0 1.0 5000.0 1.0 429.8 177.5 NO 8500. .8131E-03 5 1.0 1.0 5000.0 1.0 446.2 183.4 NO 9000. .7616E-03 5 1.0 1.0 5000.0 1.0 462.0 189.1 NO 9500. .7161E-03 5 1.0 1.0 5000.0 1.0 477.4 194.6 NO 10000. .6756E-03 5 1.0 1.0 5000.0 1.0 492.3 200.0 NO 15000. .4307E-03 5 1.0 1.0 5000.0 1.0 623.9 247.5 NO 20000. .3156E-03 5 1.0 1.0 5000.0 1.0 733.6 287.4 NO 25000. .2488E-03 5 1.0 1.0 5000.0 1.0 829.4 322.3 NO 30000. .2054E-03 5 1.0 1.0 5000.0 1.0 915.5 353.9 NO 40000. .1678E-03 4 1.0 1.0 320.0 1.0 1552.4 1553.2 NO 50000. .1492E-03 4 1.0 1.0 320.0 1.0 1745.9 1750.0 NO MAXIMUM 1-HR CONCENTRATION AT OR BEYOND 1. M: 10. 15.11 5 1.0 1.0 5000.0 1.0 2.6 .9 NO DWASH= MEANS NO CALC MADE (CONC = 0.0) DWASH=NO MEANS NO BUILDING DOWNWASH USED DWASH=HS MEANS HUBER-SNYDER DOWNWASH USED -WASH=SS MEANS SCHULMAN-SCIRE DOWNWASH USED IASH=NA MEANS DOWNWASH NOT APPLICABLE, X<3*LB *** SUMMARY OF SCREEN MODEL RESULTS *** CALCULATION MAX CONC DIST TO TERRAIN PROCEDURE (UG/M**3) MAX (M) HT (M) SIMPLE TERRAIN 15.11 10. 0. ** REMEMBER TO INCLUDE BACKGROUND CONCENTRATIONS ** 1 12-20-91 14:01:59 *** SCREEN-i.1 MODEL RUN *** *** VERSION DATED 88300 *** ~_nylbenzene emissions from an area source (20' X 20') at ARCO No. 1960. SIMPLE TERRAIN INPUTS: SOURCE TYPE = AREA EMISSION RATE (G/S) = .1170E-03 SOURCE HEIGHT (M) = 1.00 LENGTH OF SIDE (M) = 6.10 RECEPTOR HEIGHT (M) = .00 IOPT (i=URB,2=RUR) = *** FULL METEOROLOGY *** ********************************** *** SCREEN AUTOMATED DISTANCES *** ********************************** *** TERRAIN HEIGHT OF .00 M ABOVE STACK BASE USED FOR FOLLOWING DISTANCES *** DIST CONC U10M USTK MIX HT PLUME SIGMA SIGMA (M) (UG/M**3) STAB (M/S) (M/S) (M) HT (M) Y (M) Z (M) DWASH 1. .1531E-01 1 1.0 1.0 320.0 1.0 1.7 .2 NO 100. .4072 5 1.0 1.0 5000.0 1.0 12.1 7.5 NO 200. .1177 5 1.0 1.0 5000.0 1.0 22.5 14.0 NO 300. .5751E-01 5 1.0 1.0 5000.0 1.0 32.5 19.9 NO 400. .3496E-01 5 1.0 1.0 5000.0 1.0 42.1 25.3 NO 500. .2395E-01 5 1.0 1.0 5000.0 1.0 51.4 30.2 NO 600. .1769E-01 5 1.0 1.0 5000.0 1.0 60.4 34.8 NO 700. .1376E-01 5 1.0 1.0 5000.0 1.0 69.2 39.1 NO 800. .lillE-01 5 1.0 1.0 5000.0 1.0 77.7 43.1 NO 900. .9224E-02 5 1.0 1.0 5000.0 1.0 85.9 47.0 NO 1000. .7829E-02 5 1.0 1.0 5000.0 1.0 94.0 50.6 NO 1100. .6764E-02 5 1.0 1.0 5000.0 1.0 101.8 54.1 NO 1200. .5928E-02 5 1.0 1.0 5000.0 1.0 109.5 57.4 NO 1300. .5259E-02 5 1.0 1.0 5000.0 1.0 116.9 60.6 NO 1400. .4712E-02 5 1.0 1.0 5000.0 1.0 124.2 63.6 NO 1500. .4259E-02 5 1.0 1.0 5000.0 1.0 131.4 66.6 NO 1600. .3878E-02 5 1.0 1.0 5000.0 1.0 138..3 69.4 NO 1700. .3554E-02 5 1.0 1.0 5000.0 1.0 145.1 72.2 NO 1800. .3276E-02 5 1.0 1.0 5000.0 1.0 151.8 74.9 NO 1900. .3035E-02 5 1.0 1.0 5000.0 1.0 158.4 77.5 NO 2000. .2825E-02 5 1.0 1.0 5000.0 1.0 164.8 80.0 NO 2100. .2639E-02 5 1.0 1.0 5000.0 1.0 171.1 82.5 NO 2200. .2475E-02 5 1.0 1.0 5000.0 1.0 177.3 84.9 NO 2300. .2328E-02 5 1.0 1.0 5000.0 1.0 183.4 87.2 NO 2400. .2197E-02 5 1.0 1.0 5000.0 1.0 189.3 89.5 NO 2500. .2079E-02 5 1.0 1.0 5000.0 1.0 195.2 91.8 NO 2600. .1972E-02 5 1.0 1.0 5000.0 1.0 201.0 94.0 NO 2700. .1875E-02 5 1.0 1.0 5000.0 1.0 206.7 96.1 NO 2800. .1786E-02 5 1.0 1.0 5000.0 1.0 212.3 98.2 NO 2900. .1705E-02 5 1.0 1.0 5000.0 217.8 100.3 NO 3000. .1631E-02 5 1.0 1.0 5000.0 1.0 223.2 102.3 NO - 3500. .1334E-02 5 1.0 1.0 5000.0 1.0 249.2 112.0 NO 4000. .1126E-02 5 1.0 1.0 5000.0 1.0 273.5 120.9 NO --- .500. .9716E-03 5 1.0 1.0 5000.0 1.0 296.4 129.3 NO 5000. .8533E-03 5 1.0 1.0 5000.0 1.0 318.1 137.2 NO 5500. .7600E-03 5 1.0 1.0 5000.0 1.0 338.7 144.7 NO 6000. .6845E-03 5 1.0 1.0 5000.0 1.0 358.4 151.8 NO 6500. .6223E-03 5 1.0 1.0 5000.0 1.0 377.3 158.6 NO 7000. .5703E-03 5 1.0 1.0 5000.0 1.0 395.5 165.1 NO 7500. .5261E-03 5 1.0 1.0 5000.0 1.0 412.9 171.4 NO 8000. .4881E-03 5 1.0 1.0 5000.0 1.0 429.8 177.5 NO 8500. .4552E-03 5 1.0 1.0 5000.0 1.0 446.2 183.4 NO 9000. .4263E-03 5 1.0 1.0 5000.0 1.0 462.0 189.1 NO 9500. .4009E-03 5 1.0 1.0 5000.0 1.0 477.4 194.6 NO 10000. .3782E-03 5 1.0 1.0 5000.0 1.0 492.3 200.0 NO 15000. .2411E-03 5 1.0 1.0 5000.0 1.0 623.9 247.5 NO 20000. .1767E-03 5 1.0 1.0 5000.0 1.0 733.6 287.4 NO 25000. .1393E-03 5 1.0 1.0 5000.0 1.0 829.4 322.3 NO 30000. .1150E-03 5 1.0 1.0 5000.0 1.0 915.5 353.9 NO 40000. .9396E-04 4 1.0 1.0 320.0 1.0 1552.4 1553.2 NO 50000. .8355E-04 4 1.0 1.0 320.0 1.0 1745.9 1750.0 NO MAXIMUM i-HR CONCENTRATION AT OR BEYOND 1. M: 10. 8.456 5 1.0 1.0 5000.0 1.0 2.6 .9 NO DWASH= MEANS NO CALC MADE (CONC = 0.0) DWASH=NO MEANS NO BUILDING DOWNWASH USED DWASH=HS MEANS HUBER-SNYDER DOWNWASH USED ~WASH=SS MEANS SCHULMAN-SCIRE DOWNWASH USED ;ASH=NA MEANS DOWNWASH NOT APPLICABLE, X<3*LB *** SUMMARY OF SCREEN MODEL RESULTS *** CALCULATION MAX CONC DIST TO TERRAIN PROCEDURE (UG/M**3) MAX (M) HT (M) SIMPLE TERRAIN 8.456 10. 0. ** REMEMBER TO INCLUDE BACKGROUND CONCENTRATIONS ** 1 12-20-91 14:06:24 *** SCREEN-i.1 MODEL RUN *** *** VERSION DATED 88300 *** ,.~ene emissions from an area source (20' X 20') at ARCO No. 1960. SIMPLE TERRAIN INPUTS: SOURCE TYPE = AREA EMISSION RATE (G/S) = .3140E-03 SOURCE HEIGHT (M) = 1.00 LENGTH OF SIDE (M) = 6.10 RECEPTOR HEIGHT (M) = .00 IOPT (i=URB,2=RUR) = 1 *** FULL METEOROLOGY *** *** SCREEN AUTOMATED DISTANCES *** ********************************** *** TERRAIN HEIGHT OF .00 M ABOVE STACK BASE USED FOR FOLLOWING DISTANCES *** DIST CONC U10M USTK MIX HT PLUME SIGMA SIGMA (M) (UG/M**3) STAB (M/S) (M/S) (M) MT (M) Y (M) Z (M) DWASH 1. .4108E-01 1 1.0 1.0 320.0 1.0 1.7 .2 NO 100. 1.093 5 1.0 1.0 5000.0 1.0 12.1 7.5 NO 200. .3160 5 1.0 1.0 5000.0 1.0 22.5 14.0 NO 300. .1543 5 1.0 1.0 5000.0 1.0 32.5 19.9 NO 400. .9382E-01 5 1.0 1.0 5000.0 1.0 42.1 25.3 NO 500. .6428E-01 5 1.0 1.0 5000.0 1.0 51.4 30.2 NO 600. .4748E-01 5 1.0 1.0 5000.0 1.0 60.4 34.8 NO 700. .3693E-01 5 1.0 1.0 5000.0 1.0 69.2 39.1 NO 800. .2981E-01 5 1.0 1.0 5000.0 1.0 77.7 43.1 NO 900. .2475E-01 5 1.0 1.0 5000.0 1.0 85.9 47.0 NO 1000. .2101E-01 5 1.0 1.0 5000.0 1.0 94.0 50.6 NO 1100. .1815E-01 5 1.0 1.0 5000.0 1.0 101.8 54.1 NO 1200. .1591E-01 5 1.0 1.0 5000.0 1.0 109.5 57.4 NO 1300. .14lIE-01 5 1.0 1.0 5000.0 1.0 116.9 60.6 NO 1400. .1265E-01 5 1.0 1.0 5000.0 1.0 124.2 63.6 NO 1500. .1143E-01 5 1.0 1.0 5000.0 1.0 131.4 66.6 NO 1600. .1041E-01 5 1.0 1.0 5000.0 1.0 138.~3 69.4 NO 1700. .9539E-02 5 1.0 1.0 5000.0 1.0 145.1 72.2 NO 1800. .8793E-02 5 1.0 1.0 5000.0 1.0 151.8 74.9 NO 1900. .8146E-02 5 1.0 1.0 5000.0 1.0 158.4 77.5 NO 2000. .7580E-02 5 1.0 1.0 5000.0 1.0 164.8 80.0 NO 2100. .7083E-02 5 1.0 1.0 5000.0 1.0 171.1 82.5 NO 2200. .6642E-02 5 1.0 1.0 5000.0 1.0 177.3 84.9 NO 2300. .6249E-02 5 1.0 1.0 5000.0 1.0 183.4 87.2 NO 2400. .5897E-02 5 1.0 1.0 5000.0 1.0 189.3 89.5 NO 2500. .5579E-02 5 1.0 1.0 5000.0 1.0 195.2 91.8 NO 2600. .5292E-02 5 1.0 1.0 5000.0 1.0 201.0 94.0 NO 2700. .5031E-02 5 1.0 1.0 5000.0 1.0 206.7 96.1 NO 2800. .4794E-02 5 1.0 1.0 5000.0 1.0 212.3 98.2 NO 2900. .4576E-02 5 1.0 1.0 5000.0 ~ 217.8 100.3 NO 3000. .4376E-02 5 1.0 1.0 5000.0~0 223.2 102.3 NO ,- 3500. .3581E-02 5 1.0 1.0 5000.0 1.0 249.2 112.0 NO 4000. .3022E-02 5 1.0 1.0 5000.0 1.0 273.5 120.9 NO .... ~500. .2608E-02 5 1.0 1.0 5000.0 1.0 296.4 129.3 NO ~000. .2290E-02 5 1.0 1.0 5000.0 1.0 318.1 137.2 NO 5500. .2040E-02 5 1.0 1.0 5000.0 1.0 338.7 144.7 NO 6000. .1837E-02 5 1.0 1.0 5000.0 1.0 358.4. 151.8 NO 6500. .1670E-02 5 1.0 1.0 5000.0 1.0 377.3 158.6' NO 7000. .1530E-02 5 1.0 1.0 5000.0 1.0 395.5 165.1 NO 7500. .1412E-02 5 1.0 1.0 5000.0 1.0 412.9 171.4 NO 8000. .1310E-02 5 1.0 1.0 5000.0 1.0 429.8 177.5 NO 8500. .1222E-02 5 1.0 1.0 5000.0 1.0 446.2 183.4 NO 9000. .1144E-02 5 1.0 1.0 5000.0 1.0 462.0 189.1 NO 9500. .1076E-02 5 1.0 1.0 5000.0 1.0 477.4 194.6 NO 10000. .1015E-02 5 1.0 1.0 5000.0 1.0 492.3 200.0 NO 15000. .6471E-03 5 1.0 1.0 5000.0 1.0 623.9 247.5 NO 20000. .4741E-03 5 1.0 1.0 5000.0 1.0 733.6 287.4 NO 25000. .3739E-03 5 1.0 1.0 5000.0 1.0 829.4 322.3 NO 30000. .3085E-03 5 1.0 1.0 5000.0 1.0 915.5 353.9 NO 40000. .2522E-03 4 1.0 1.0 320.0 1.0 1552.4 1553.2 NO 50000. .2242E-03 4 1.0 1.0 320.0 1.0 1745.9 1750.0 NO MAXIMUM I-HR CONCENTRATION AT OR BEYOND 1. M: 10. 22.69 5 1.0 1.0 5000.0 1.0 2.6 .9 NO DWASH= MEANS NO CALC MADE (CONC = 0.0) DWASH=NO MEANS NO BUILDING DOWNWASH USED DWASH=HS MEANS HUBER-SNYDER DOWNWASH USED ~WASH=SS MEANS SCHULMAN-SCIRE DOWNWASH USED ;ASH=NA MEANS DOWNWASH NOT APPLICABLE, X<3*LB *************************************** *** SUMMARY OF SCREEN MODEL RESULTS *** CALCULATION MAX CONC DIST TO TERRAIN PROCEDURE (UG/M**3) MAX (M) HT (M) SIMPLE TERRAIN 22.69 10. 0. ** REMEMBER TO INCLUDE BACKGROUND CONCENTRATIONS ** PREPARED FOR: MS. KATERI LUKA ARCO PRODUCIS COMPANY P.O. BOX 6411 ARTESIA, CAIJFORNIA 90702-64 (213) 404-5360 REMEDIAL ACTION PLAN ARCO SERVICE STATION #1960 1701 BRUNDAGE LANE BAKERSFIELD, CALIFORNIA MAY16, 1991 PREPARED BY: GROUNDWATER TECHNOLOGY, INC. 4101 ALKEN STREET, SUITE B-1 BAKERSFIELD, CALIFORNIA 93308- (805) 589-8601 ~~N BY: [ ( PARKER ' ] R~E~D BY:( PARKER REGIS~RED GEOLOGIST REGIS~RED~GE~OGIST ~4728 ~4018 ~ ~ ~: GROUNDWATER , " '" ~TECHNOLOGY, INC. CONTENTS PAGE INTRODUCTION .................................................. 1 SITE BACKGROUND ............................................... SITE CHARACTERISTICS ........................................... ! GEOGRAPHY ............................................... ! HYDROGEOLOGY ........................................... 2 RISK ANALYSIS ................................................... 2 PROPOSED REMEDIATION SYSTEM ................................. 2 IN-SITU VAPOR EXTRACTION ' 2 VAPOR-ABATEMENT DEVICES ................................. 4 CARBON ADSORPTION ..................................... 4 CATALYTIC OXIDATION ................................... 5 THERMAL OXIDATION ..................................... 5 INTERNAL COMBUSTION ENGINE ........................... 5 RECOVERY WELL INSTALLATION ............................. 6 SAMPLING ............................................... 6 LABORATORY ANALYSIS .................................. 6 WASTE MANAGEMENT .................................... 7 WORK SCHEDULE ................................................ 7 REFERENCES ..................................................... 8 TABLE TABLE 1. LEACHING POTENTIAL .................................... 3 FIGURES FIGURE 1 - LOCATION INDEX FIGURE 2 - SITE MAP FIGURE 3 - CROSS-SECTION A FIGURE 4 - SITE GEOLOGY FIGURE 5 - DEPTH TO GROUNDWATER FIGURE 6 - GROUNDWATER ELEVATION FIGURE 7 - RECOVERY WELL LOCATION FIGURE 8 - CROSS-SECTION A W/RECOVERY WELL LOCATION FIGURE 9 - RECOVERY WELL CONSTRUCTION APPENDIX APPENDIX A - SITE SAFETY PLAN Remediat Action Ptan ,~ .... ~I,~ L=,' '~i GROUNDWATER ARCO Products Company ,:-~r~,,i--~; t4a¥ 16, 1991 L~' TECHNOLOGY, INC. INTRODUCTION Groundwater Technology, Inc. has been contracted by ARCO Products Company to remediate hydrocarbon-bearing soil at facility # 1960 in Bakersfield, California. Laboratory analysis from previous investigations indicate that hydrocarbon-bearing soil is present at the site. This workplan outlines site background, a proposed remediation system, equipment installation procedures, and worker safety considerations. SITE BACKGROUND The facility is located at 1701 Brundage Lane in Bakersfield (Figure 1). Three borings were completed as part of a tank replacement assessment in October, 1990 (B1-B3, Figure 2). Laboratory analysis indicated concentrations of benzene, toluene, ethylbenzene, and xylenes (BTEX), and total petroleum hydrocarbons as gasoline (TPH) were below detection limits in mo&t__s_a.~m_p?s analyzed. One sample exhibited a xylenes concentration of 1.0 mg/kg. Existing gasoline storage tanks were removed in October, 1990. Samples collected beneath tanks, dispensers, and piping indicated the presence of gasoline hydrocarbons in soil beneath former tanks 1, 2, and 3, and beneath two of three dispenser islands (see Report, November 12, 1990). Subsequently, Groundwater Technology completed a site characterization study which included the completion of four additional soil borings (B4-B7, Figure 2). Hydrocarbons were encountered at levels exceed_! ~ngl_0_0_0_~g/_~kg_i~n__one of these borings (see Report, March 26, 1991). A cross section showing the distribution of hydrocarbons is presented in Figure 3. SITE CHARACTERISTICS GEOGRAPHY The site is located on the alluvial plain of the Kern River. Topography in the region is flat, and no natural bodies of water adjoin the site. The station is located in a commercial area and is approximately 2500 feet southeast of the nearest school. Re~.odiat Action Ptan ~--;~---.~-.~ GROUNDWATER ARCO Products Company May 16, 1991 1 : ' TECHNO~GY, INC. HYDROGEOLOGY The site overlies alluvial fan deposits of the Kern River (Figure 4). Sediments underlying the region consist of fluvial deposits including silt, sand, and gravel. Native sediments encountered at the site consist of fine- to coarse-grained sand. An unconfined aquifer is present below the site at a depth of approximately 175 feet (Figure 5, Kern County Water Agency, 1990a). The gradient of the unconfined aquifer is generally toward the southeast (Figure 6). Shallow, perched groundwater has not been identified in the vicinity of the site (Kern County Water Agency, 1990b). RISK ANALYSIS Mitigation procedures have been requested by Kern County Environmental Health Services (see Letter, April 18, 1991). A very conservative risk analysis as referenced in the State LUFT manual indicates the maximum allowable concentrations of gasoline hydrocarbons which can remain in place at the site and not pose a threat to groundwater is 1000 mg/kg (Table 1.) PROPOSED REMEDIATION METHOD Three remedial action options were considered for the site in the Characterization Report. They included no action, excavation, and soil venting. The County has indicated that the no-action alternative is not acceptable, and requested that mitigation procedures be implemented. Excavation of the contaminated soil is feasible, but is considered cost- prohibitive and may cause structural damage to buildings at the site. Groundwater Technology therefore proposes util~izing inr. sjt_U, v~a_p0r-extraction to remediate the site, IN-SITU VAPOR EXTRACTION Conditions favorable to vapor extraction include a contaminant with a high vapor pressure and a relatively permeable substrate. The vapor pressure of most of the components of gasoline are ideal for vapor extraction. Theoretically, assuming 100% vapor saturation, 1,965 lbs/day of BTEX can be transported in a process stream with a flow rate of 100 SCFM. In practice several factors reduce this extraction efficiency. Some of these factors GROUNDWATER ARCO Products Company ........ May ~6, ~ 2 ! ..... ',I i TECHNOLOGY, INC. TABLE 1. LEACHING POTENTIAL ANALYSES FOR GASOLINE* USING TOTAL PETROLEUM HYDROCARBONS (TPH) AND BENZENE, TOLUENE, XYLENES, AND ETHYLBENZENE (BTX&E) S SCORE S SCORE S SCORE SITE C 10 PTS C 9 PTS C 5 PTS FEATURE O IF CON- O IF CON- O IF CON- R DITION R DITION R DITION E IS MET E IS MET E IS MET Minimum Depth to 10 >100 51-100 25-50\1 Groundwater from the Soil Sample (feet) Fractures in'subsurface 10 None Unknown Present (applies to foothills or mountain areas) Average Annual 10 <10 10-25 26-40~2 Precipitation (inches) Man-made Conduits which 10 None Unknown Present ~ncrease vertical !migration of leachate Unique site features: None 9 At least More recharge area, coarse one than one soil, nearby wells, etc. COLUMN TOTALS - TOTAL PTS 40 + 9 + 0 RANGE OF TOTAL POINTS 49 Pts or more 41-48 pts 40 pts or less B/T/X/E/LEVELS (PPM) MAXIMUM ALLOWABLE ~i~:.ii 100 10 TPH LEVELS (PPM) \1 - If depth is greater than 5 ft. but less than 25 ft., score 0 points. If depth is 5 ft. or less, this table should not be used. \2 - If depth is over 40 inches, score 0 points, \3 - Levels for BTX&E are not applicable to TPH concentration of 100 ppm. * - Table from page 28, Table 2-1, LUFT Manual, 1988 Remedial. Action Pi.an '---~=--~; GROUNDWATER ARCO Products Company Nay 16, 1991 3 ~ ~ i..TECHNOLOGY, INC. include condensation, the presence of soil moisture, evaporative cooling, and air-stream dilution. However, gasoline is still considered to be 100% removable with a vapor- extraction system. Sediments at the sight are well suited to vapor-extraction processes. Hydraulic conductivity of the sediments is estimated to range from 10.4 to 10'1 cm/s based on comparison with data published by the USGS. Based on this estimate, a minimum radius of influence of 30 feet is expected for each vapor-recovery well (Figure 7 and 8). More likely, a radius of influence of 50 feet is expected. The in-sim vapor-extraction process requires an air-collection system, a method to move air, and a vapor-abatement device. These three elements ultimately remediate the site by inducing air flow through hydrocarbon-bearing soil, volatilizing and transporting hydrocarbons to the surface in the air steam, and destroying or adsorbing the hydrocarbons in a vapor-abatement system to meet emission requirements set forth by air pollution regulations. The air-collection system consists of recovery wells and associated plumbing and manifolding. This collection system is typically attached to an explosion-proof regenerative blower to move the hydrocarbon-laden vapors to an abatement device. Four of these devices are described in detail below. VAPOR-ABATEMENT DEVICES Four vapor-abatement methods are typically utilized to control emissions in vapor-extraction systems. They include: granular activated carbon (GAC), catalytic oxidation (Cat-Ox), thermal oxidation (Therm-Ox), and an internal combustion engine (ICE) Carbon Adsorption Removal of hydrocarbons from a vapor stream can be accomplished by passing the vapor through a canister of granular activated carbon. The granular form of activated carbon provides a large surface area onto which the hydrocarbons are readily adsorbed, yielding an effluent stream that meets regulatory discharge requirements. Remediat Action Ptan ~--~L---~J~ GROUNDWATER ARCO Products Company . --.~. ........ , May 16, 1991 4 ii~) _/--.~ TECHNOLOGY, INC. Catalytic Oxidation Catalytic oxidation is an effective method to destroy hydrocarbons entrained in an air stream. The catalytic oxidizer utilizes an electric heating element to preheat the influent vapor stream to approximately 600°F. After passing the unit's heating element, vapors are oxidized as they pass through a platinum-coated catalyst. Use of a catalyst allows oxidation of hydrocarbon components at substantially lower temperatures than normal oxidation (approximately 1400°F). Effluent streams typically exhibit destruction efficiendes of 95%, meeting regulatory discharge requirements. Thermal Oxidation Thermal oxidation is also an effective method for destroying hydrocarbons entrained in an air stream. The thermal oxidizer uses a fuel (e.g., propane or natural gas) to heat the influent stream to temperatures of approximately 1400°F resulting in the oxidation of hydrocarbons. Effluent streams typically exhibit destruction efficiencies of 95%, meeting regulatory discharge requirements. Internal Combustion Engine An internal combustion engine destroys hydrocarbon-laden air streams by mixing them with propane or natural gas and using the final mixture as fuel. The internal combustion engine also uses a catalytic converter to increase the destruction efficiency of the unit. With this system, destruction efficiencies of 95% are possible. Selection of the most effective and economical abatement device will be made following a detailed analysis of site-specific conditions. Health-risk modeling,' piping and instrumentation diagrams, and system-monitoring protocol will also be developed for APCD permitting procedures. RECOVERY WELL INSTALLATION Based on the limited extent of the hydrocarbon plume and the extensive radius of influence expected by recovery wells, Groundwater Technology proposes to install a single recovery Re~ediat Action Ptan :::---;~--.-~--~: GROUNDWATER ARCO Products Company Flay 16, 1991 5 !. ' ! i: ~,__~,._~__: TECHNOLOGY, INC. well at the location shown in Figures 7 and 8. The well will be screened from 10 to 25 feet and constructed as shown in Figure 9. All necessary County well permits will be acquired prior to well installation. Sampling The well boring will be drilled to a depth of approximately 25 feet and sampled every 5 feet with a split-spoon sampler. The sampler will be filled with brass sample rings. The material from one sample ring will be described and field screened with a photoionizafion detector (PID) for volatile organic content. A second ring will be sealed at each end with a teflon sheet and plastic cap. The cap will be secured with tape and the sample will be preserved on ice. As requested by the County, selected samples collected from the boring will be analyzed by a state-certified laboratory as described in the next section. Between sampling attempts, the sampler and rings will be washed with detergent and rinsed successively in tap and distilled water. Laboratory_ Analysis The soil samples selected for analysis will be shipped via overnight courier to GTEL Environmental Laboratories in Torrance, California (Cert. #723). The samples will be analyzed for TPH and BTEX (EPA 8015/8020). The sample exhibiting the highest hydrocarbon concentration will also be analyzed for total lead (EPA 7421). Standard chain- of-custody procedures will be followed. Waste Management The drill cuttings from the boring will be stored on site in appropriately labelled drums pending the results of the analysis of a composite cuttings sample. Dependant upon hydrocarbon concentrations, and following County approval, the cuttings will either be aerated on site until clean or disposed of at an appropriate landfill. ARCO Products Company May 16, 1991 6 '--~:--:~-]~ !_.&__:~._~i TECHNOLOGY, INC. WORK SCHEDULE Upon approval of the proposed plan, a licensed drilling company will be scheduled to perform necessary drilling. The drilling and in.qtallation of wells is anticipated to require one day. Kern County Environmental Health Services and Underground Service Alert will be notified at least 48 hours prior to commencement of work. Laboratory _analyses will require approximately 15 days following submission of the samples to the laboratory. An APCD permit application will be submitted following the determination of the best abatement device for use at the site. Following the receipt of an Authority to Construct, equipment installation will commence. Remediat Action Ptan ~ GROUNDWATER ARCO Products Company .ay 16, 1~1 7 i~-~-!,~-~ TECHNOLOGY. INC. REFERENCES California Division of Mines and Geology, 1975, Geologic Map of California, Bakersfield sheet. Kern County Water Agency, 1990a, 1989 Report on Water Conditions - improvement district no. 4. · Kern County Water Agency, 1990b, Water Supply Report - 1989. Remecliat Act/on Ptan :~[.~ GROUNDWATER ARCO Products Company Hay 16, 1991 8 i~ '.~ ~', !! TECHNOLOGY, INC. FIGURES GROUNDWATER TECHNOLOGY, [NC. VALLEY PLAZA g MALL - Si e N IJrl]~ # 215 SITE, ARCO SS #1960 350 0603 SITE LOC~ 1701 Brundoge Lone Bokersfield, CA HAP TYPE, Locotion Index SCALE: DRAWN BY: I DATE, APPROVED ]~Y, MH I 10/90 REVISION 112 0 114 ~/2 mr[es Source: Hoven &: Co. Inc. [FIGURE 1 F~=~'~" Brundage Lane LEGEND L~ Planter [ I I I B I SI1 I H + B1 Service I II -~ Boring Location Islands I II I IConopy \\ I I  ~ SCA~: S]T~, I~8 ~ 215 ~ ARCO SS ~]960 D50 060~ I SZTE CDC, 1701 BFundeDe Lene I% FoF~eF I PFO~ucf BQReFsfield, CA. ~ B2 I Line West East B5 B5 B4 , 'B2 Former Tank __5' 5' _ Excavation <0.05 _10' 10'_ <----T-O- <'~o ? ~9--~ ~o <o.oo5 27 ~-~ _15' O.3 .0.56 / 20'_ <0.05 5 600 _20' <10 ? ? _25' -._ ? ~PH < 10_¢.__._ -? 5' O' 5' ARCO SS #1960 I;~3 ~ 0~ SITE, 0603 Size LaC, 1701 Brundoge Lone Bokersfield, CA. <0.005 <0.005 55' DESCRIPnnN, <0.005 = Benzene · -- ~ <10" - Cross-Section A-A' <10 ~ mn rog/Kg. DR^v. BY, DATE, APPROVED ]BY, I DATE, x-Tonk pit somple, proiecfed south. JDP 5/91 P JRI 5/91 B4 proiecfed north and B5 proiected south. <0.05 _40' [ I r"T'l~ Verficol scole equols horizontol scole. <10[FIGURE .~ '1F~r'~ Legend Site  Stream channel ~ ' deposits ~ F~n deposits ~ B~in deposits ~ ~ # 2~5 ~ZTE~ASCO SS #~960 ~50 0605 SITE LDO B~ker$field, CA SCALE: MAP TYPE, Site Geology DRA~/N BY, DATE, APPRDVED BY, 2 0 1 2 JDP Source: CDMG Bokersfield Sheet ~FIGURE ~ ~.~v,~,~:~.~.oGy ........ ~.._...~ .~ -~ - , . ~ .... '~ .... ~' ~ ~'~- ,-' ~ ~ ~"~' I '"' ' '~'"~&:~'~~' "~ ~ ..... ' s ~ '~ ~ ' --" ~ r -X~ , , ..... ~5.~,,,-,,...~IU,,.-~,~, , ~ ...... ~~. I, '~- ~.~' ' ' = ~"~ ~ ~ ~ :~ ~. I~ ~t~l N ' ~:,' ~ ,%1 ~. ' ~ 'E~' ~ ' ~: ' ~ · "~ ~ ::" L~ ~'~ ~ ' It'li/~ I Legend x~O'~ Depth to Groundwater JB~ ~ 21 s~[,ARCO SS~1960 35O 0603 S~TE LBO gCALE: Bakersfield, CA ~ MAP TYPE, Depth to Groundwater 40o0 o ~ooo 4000 ~. ~, ~T~, I~P~V~ .Y, ~T[, Feet JDP 11/90 I I Source: K.C.W.A. Report, 1990 ]FIGURE Legend ~Site Groundwater Elevation I JaB # 215 S~TE, ARCO SS#1960 350 0603 SZTE LOC, Bokersfield, CA SCALE~ MAP TYPE~ Groundwater Grodient ,oooo ~ooo 4000 II '~'"'" ~'~' I ~,,,ov~,,,, ~'~' I Fee, JDP ,,,,o I I Source: K.C.W.A. Report, 1990 J FIGURE 6 I ~~,.,v,,~, Brunclc~ge Lane LEGEND L~ Planter I I II J t -(J)- Boring Location Service II 1 II o Proposed Recover~ ~ Well Location I Canopy J~B ~ 2~5 s~, ARCO SS ~IB~O 1350 0~03 I s~T~ Lao 1701 Brundage Lane ~ Former Bakersfield, CA, Product VW1 ~ B2 Line ~ ~P~' Recove~ Well Location ROI Il II I Former JDP 5/91 J P JR 5/91 L_JL~JL_Ji Planter Proposed West Recovery Well East B5 B5 ] B4 , 'B2 I'1 Former Tonk 5'_ Exc(]vofion _5' 10'_ <0.05 _10' .KO.05 ~ 15' <0.05 0.0.5 <0 5 ~ _15' <10 ? 1900 0.3 .0.56 / <o.o _2o' <10  Scale: _25' ~ 0~ SITD 060~ <0.005 <0.005 ~5' ~[SCRZPTmN, Bakersfield~ CA. <0.005 = Benzene · ;- ~ <10 - Cross-Section A-A' <~ 0 ~ mn rog/Kg. ~RAVN ~Y, DATE, APPROVED ~Y, I DATE, x-Tonk pit somple, proiected soufh. JDP 5//91 P JRI 5/91 B4 proiected north ,nd B5 protected south. <0.0~ _40,m Verfm~l scele equels horizontal scele. <10IF[GURE 8i ~ ~ ~ Grade Street Box () ~- To Manifold Concrete Grout Bentonite ob) >- cq Filter Pack ~ I JO]~ # 215 SITE, ARCO SS# 1960 350 0603 SITE LDC, Bokersfield, C~lifornio DESCRIPTION~ DRA~N 3Y, DATE, ~APPRDVED BY, DATE~ JOP I 5?® J PJR 15/91 APPENDIX A SITE SAFETY PLAN ~L__~_~ ~ GROUNDWATER i~-~ TECHNOLOGY, INC. SITE SAFETY'PLAN ARCO PETROLEUM PRODUCTS COMPANY STATION %1960 BRUNDAGE LANE AND "H'w STREET SEPTEMBER 18, 1990 GROUNDWATER TECHNOLOGYt INC. 20000/200 MARINER AVENUE TORRANCE, CALIFORNIA 90503 PROJECT NUMBER: 215-350-0603 Completed by:- ~/ ,~6ject Manager: Health & Safety Manager:~Y~ [][][]l ' ' ' ' ' ~{TE~HNOLO6Y,~C. ARCO Service Station #1960 Site Safety Plan September 18, 1990 TABLE OF CONTENTS 1.0 SITE EMERGENCY PLAN 1.1 Emergency Telephone Numbers ............ 1 1.2 First Aid_ .................. 1 1.3 Emergency EnVironmental Contacts . . . ] ...... 2 1.4 Encountering Hazardous Situations ........... 2 2.0 INFORMATION SUMMARY 2.1 Health and Safety Summary .............. 3 3°0 INTRODUCTION 3.1 Background ..................... 5 3.2 Purpose ...................... 5 3.3 Objective ..................... 5 3.4 Amendments ..................... 5 4.0 HAZARD EVALUATION 4.1 Site Conditions .................. 6 4.2 Site Tasks ..................... 6 4.3 Job Task Hazards ................. 7 4.3.1 All Field Tasks ............... 7 4.3.2 Well Installation, Development ........ 10 4.3.3 Sample Preservation ............. 10 4.3.4 Cleaning Equipment .............. 11 4.3~5 Confined Space ................ 11 5.0 PERSONAL PROTECTIVE EQUIPMENT .............. 13 6.0 DECONTAMINATION PROCEDURES ............... 14 7.0 CHEMICALS OF CONCERN 7.1 Health Effects ................... 15 8.0 GAS/VAPOR MONITORING PROCEDURES 8.1 Tasks Performed within a Confined Space ...... 17 9.0 HEALTH AND SAFETY REQUIREMENTS 9.1 Medical Monitoring ................. 19 9.2 Training ...................... 19 9.3 Work Zone Access .................. 19 9.4 Emergency Equipment ................ 20 I--11---3I~3 ARCO Service Station #1960 Site Safety Plan September 18, 1990 TABLE OF CONTENTS (Continued) 9.5 Carbon Treatment ................. 20 9.6 Drilling Procedures ................ 20 9.7 Electrical Equipment ................ 21 9.8 Fire Prevention .................. 21 -- 9.9 General Health ................... 22 9.10 MSDS Information .................. 22 10.0 PROJECT PERSONNEL 10.1 Project Manager .................. 23 10.2 Regional Safety officer .............. 24 10.3 Site Safety Officer ................ 24 10.4 Field Team Leader ................. 25 10.5 Other Field Personnel 25 10.6 Medical/Technical Advisors ............. 26 APPENDICES APPENDIX A: Agreement and Acknowledgement Statement APPENDIX B: Site Safety Plan Amendment Sheet APPENDIX C: Definition of Hazard Evaluation Guidelines APPENDIX D: Site Maps APPENDIX E: MSDS APPENDIX F: Accident/Injury Form APPENDIX G: Vapor Monitoring Worksheet APPENDIX H: Excavation/Trenching APPENDIX I: OSHA Inspection Steps APPENDIX J: UST Removal ARCO Service Station #1960 Site Safety Plan September 18, 1990 1.0 .SITE EMERGENCY PLAN Survey the situation. Do not endanger your own life. Your site address: Corner of Brundage Lane & "H" Street 1.1 Emergency Telephone Numbers: Telephone located at: Ambulance: (911) Fire: (911) Police:- (911) Poison Control: 1-800-346-5922 Nearest Hospital: Mercy Hospital Street Address: Telephone: 1-805-328-5275 Directions to: "H" Street north to Truxton; west on Truxton to 2200 block & hospital. 1.2 First Aid Ingestion: Give water if patient is conscious. Call Poison Control - follow instructions. Administer CPR, if necessary. Seek medical attention. Inhalation: Remove person from contaminated evironment. Administer CPR, if necessary. Seek medical attention. Skin Contact: Brush off dry material, remove contaminated clothing. Wash skin with soap and water. Seek medical attention if irritation develops. Eye Contact: Flush eyes and surrounding tissue with water for 15 minutes. Seek medical attention. * Exposure Symptoms: Headache, dizziness, nausea, drowsiness, irritation of eyes, nose, throat, breathing difficulties. Report incident to Project Manager and Regional Health and Safety Manager after emergency procedures have been implemented. ARCO Service Station #1960 Site Safety Plan September 18, 1990 '1.3 Emergency Environmental Contacts TELEPHONE: Groundwater Technology, Inc.: Contact Person: Tina LePage 1-805-589-8601 Home: 1-805-589-8683 Alternates: Jon Parker 1-805-589-8601 Home: 1-805-833-8984 Maureen Grant 1-213-371-1394 Home: 1-213-374-3551 National Response Center: 1-800-424-8802 U.S. EPA (24-hour Hotline): 1-800-424-9346 State Regulatory Agency: Kern County Dept. of 1-805-861-3636 Env. Health Services Client: ARCO Products Company Contact Person: Joseph .Tully 1-213-404-5360 1.4 Encountering Hazardous Situations (requiring evacuation) In the event of an emergency, i.e. fires, explosions or any unplanned sudden or non-sudden release of hazardous waste or hazardous waste constituents to air, soil or surface water at the facility, the team member that observes this condition shall give an emergency alarm. The emergency alarm signal will be 3 horn blasts on the horn located in the site vehicle. Actions to be taken will be dictated by the emergency. Ail appropriate local emergency response agencies shall be notified immediately. The police, fire department, emergency response teams and ambulance may be reached via telephone by dialing 911. The nearest hospital and additional emergency contacts are listed on the previous page (Section 1.0). Personnel encountering a hazardous situation shall instruct others on site to evacuate the vicinity immediately and call the (1) Site Safety officer, (2) the Project Manager, and (3) the Health & Safety Manager for instructions. The site must not be re-entered until back-up help, monitoring equipment, and personal protective equipment is on hand. 2 [][][] ARCO Service Station #1960 Site Safety Plan September 18, 1990 2.0 INFORMATIONAL SUMMARY 2.1 Health and Safety Summary Chemicals of Concern: Gasoline, Benzene, Toluene, Ethylbenzene, & Xylene Hazard Determination: Serious Moderate Low X Minimum Level of Protection: Modified Level D is the minimum acceptable level for this site. Action Level for Upgrading Personal Protection: Upgrade from Level D to Level C at 100 ppm measured within the breathing zone. This should be determined by a photoionization detector (PID) with a 10.2 lamp or a flame ionization detector (FID). Air Monitoring Requirements: PID X OVA FID O2/LEL DETECTOR TUBES OTHER ARCO Service Station #1960 Site Safety Plan September 18, 1990 TABLE I ACTION LEVELS NOTE: The information in this chart applies to gasoline and its chemical constituents. GASOLINE PEL* = 300 PPM GTI ACTION LEVEL = 100 PPM ACT I O N LEVE LS FOR P PE Air Monitoring Instrument LEVEL D LEVEL C LEVEL B LEL < 1% 1% - 5% >5% PID/FID < 100 ppm 100 - 750 ppm > 750 ppm 02 19.5 - 23% 19.5 - 23% <19.5% Explanatory Information: LEL Gasoline = 1.4 % or 14,000 ppm 1% LEL = 140 ppm (Wear Level C) 5% LEL = 700 ppm (Wear Level C) >5% LEL = Level B (>700 ppm) NOTE: Withdraw from site and contact the project manaqer if: LEL > 20%, and/or O2 > 23% * PEL = Permissible Exposure Limit (OSHA 1989) ARCO Service Station #1960 Site Safety Plan September 18, 1990 3.0 INTRODUCTION 3.1 Background ARCO Products Company has retained Groundwater Technology, Inc. (GTI) to perform a site assessment/investigation at their facility located at the corner of Brundage Lane and "H" Street. 3.2 Purpose The purpose of the site safety plan is to provide Groundwater Technology field personnel and subcontractors with an understanding of the potential chemical and physical hazards that exist or may arise while the tasks of this project are being performed. This SSP describes the procedures to be followed in order to reduce employee exposure to potential health hazards which may be present at the project site. The emergency response procedures necessary to respond to such hazards are also described within this SSP. 3.3 Objective The primary objective is to ensure the well-being of all field personnel and the community surrounding this site. In order to accomplish this, project staff and approved subcontractors shall acknowledge and adhere to the policies and procedures established herein. Accordingly, all personnel assigned to this project shall read this site safety plan and sign the Agreement and Acknowledgement Statement (Appendix A) to certify that they have read, understood and agreed to abide by its provisions. GTI personnel have the authority to stop work performed by our sub- contractors at this site if any work is not performed in accordance with the requirements of this site Safety Plan. 3.4 Amendments Any changes in the scope of work of this project and/or site conditions must be amended in writing on the Site Safety Plan Amendment Sheet (Appendix B) and approved by Health & Safety Manager. ARCO Service Station #1960 Site Safety Plan September 18, 1990 4.0.HAZARD EVALUATION 4.1 Site Conditions General Site conditions at the ARCO Service Station 91960 site include the scheduling of pre-drill operations to check for contamination near old tank pit and new tank pit area. 4.2 Site Tasks The field tasks at this site may include: Soil boring samples Monitoring well installation Monitoring well survey Monitoring well gauging Monitoring well development Product bailing Groundwater and soil sampling Excavation/trenching Equipment installation Operation and maintenance Tank excavation ARCO Service Station #1960 Site Safety Plan September 18, 1990 4.3 Job Task Hazards 4.3.1 Ail Field Tasks: The following hazards may be encountered. Slippery Surfaces: Ail employees must wear ANSI approved work boots with steel toe protection. Skid proof soles are highly recommended.. · Organic Vapors: The inhalation of volatile organic vapors during all operations can pose a potential health hazard. Hazard reduction procedures include monitoring the ambient air with a PID and/or FID and use of Personal Protective Equipment indicated on Table II. Workers should stand upwind of the source of contamination whenever possible. If ambient air levels in the breathing zone exceed 100 ppm, full face _ respirators equipped with organic vapor cartridges must be worn. Flammable Vapors: Presence of flammable vapors can pose a potential fire hazard and health hazard. Hazard reduction procedures include monitoring the ambient air with an O~/LEL meter. If 4 the LEL reading exceeds 20%, leave the site immediately and contact the fire department. * Oxygen: Atmospheres that contain a level of oxygen greater than 23% pose an extreme fire hazard (the usual ambient oxygen level is approximately 20.5%). All personnel encountering atmospheres that contain a level of Oxygen greater than 23% must evacuate the site immediately and must notify the Fire Department. If Oxygen Level is less than 19.5%, do not enter the space. * Noise: GTI and ANSI approved hearing protection must be worn during noisy operations such as drilling. ARCO Service Station #1960 Site Safety Plan September 18, 1990 · Surface and Equipment Contamination: Contact with contaminated surfaces, or surfaces suspected of being contaminated should be avoided. This includes walking through, kneeling or placing equipment in puddles, mud, discolored surfaces, or on drums and other containers. Eating, smoking, drinking and/or the application of cosmetics is prohibited on this site in the immediate work area. This reduces the likelihood of contamination by ingestion. · Exposure - Heat Stress: Since climatic changes cannot be avoided work schedules will be'adjusted to provide time intervals for intake of juices, juice products and water in an area free from contamination and in quantity appropriate for fluid replacement. Heat stress may occur even in moderate temperature areas and may present any or all of the following: A. Heat Rash: result of continuous exposure to heat, humid air, and chafing clothes. Heat rash is uncomfortable and decreases the ability to tolerate heat. B. Heat Cramps: result of the inadequate replacement of body electrolytes lost through perspiration. Signs include severe spasms and pain in the extremities and abdomen. C. Heat Exhaustion: result of increase stress on the vital organs of the body in the effort to meet the body's cooling demands. Signs include shallow breathing; pale, cool, moist skin; profuse sweating; dizziness. D. Heat Stroke: result of overworked cooling system. Heat stroke is the most serious form of heat stress. Body surfaces must be cooled and medical help must be obtained immediately to prevent severe injury and/or death. Signs include red, hot, dry skin; absence of perspiration; nausea; dizziness and confusion; strong, rapid pulse. Can lead to coma and death. ARCO Service Station #1960 Site Safety Plan September 18, 1990 Heat Stress Prevention A. Replace body fluids (water and electrolytes) lost through perspiration. Solutions may include a 0.1% salt and water solution or commercial mixes such as Gatorade and Squench. B. Cooling devices to aid the natural body ventilation. Cooling occurs through evaporation of perspiration and limited body contact with heat-absorbing protective clothing. Utilize fans and air conditioners to assist in evaporation. Long, cotton underwear is suggested to absorb perspiration and limit any contact with heat- absorbing protective clothing (i.e., coated Tyvek suits). C. Provide hose-down mobile shower facilities to cool protective clothing and reduce body temperature. D. Conduct non-emergency response activities in the early morning or evening during very hot weather. E. Provide shelter against heat and direct sunlight to protect personnel. F. Rotate workers wearing protective clothing during hot weather. Exposure - Cold Stress: Work schedules will be adjusted to provide sufficient rest periods in a heated area for warming up during operations conducted in cold weather. Also thermal protective clothing such as wind and/or moisture resistant outerwear is recommended to be worn. If work is performed continuously in the cold at or below -7°C (20°F), including wind chill temperature, heated warming shelters (tents, cabins, company vehicles, rest rooms, etc.) shall be made available nearby and the worker should be encouraged to use these shelters at regular intervals the frequency depending on the severity of the environmental exposure. The onset of heavy shivering, frostnip, the feeling of excessive fatigue, drowsiness, irritability, or euphoria, are indications for immediate return to the shelter. When entering the heated shelter the outer layer of clothing shall be removed and the remainder of the clothing loosened to permit sweat evaporation. ' A change of dry work clothing shall be provided as necessary to prevent worker from returning to their work with wet clothing. Dehydration, or the loss of body fluids, occurs in the cold environment and may increase the ARCO Service Station #1960 Site Safety Plan September 18, 1990 susceptibility of the worker to cold injury due to a significant change in blood flow to the extremities. Warm sweet drinks and soups should be provided at the work site to provide caloric intake and fluid volume. The intake of coffee should be limited. (Adapted from TLV's and Biological Exposure Indices 1988-1989; ACGIH). % Falling Objects: Hard hats must be worn by all personnel whenever construction- type activity is taking place. (ie., drilling, excavation, trenching). % Vehicular traffic: All employees will be required to wear a fluorescent safety vest at all times while on site. In addition, the following safety equipment procedures must be adhered to. TASK TRAFFIC SAFETY EQUIPMENT Drilling A Subsurface Entry A Well Installation A Well Maintenance B Well Gauging B Sampling B Pump Test B SAFETY EQUIPMENT KEY: A = Cones and barricades required - tapes and flags are recommended but optional. B = Cones are required - flags are recommended but are optional. 4.3.2 Well Installation~ Well Development~ Well Gauging; Well Bailing; Soil & Groundwater Sampling: Skin and eye contact with contaminated groundwater and/or soil may occur during these tasks. Nitrile butyl rubber or neoprene gloves and approved safety goggles should be worn when contact with contaminated substance and/or splash is possible. 4.3.3 Sample Preservation: When hydrochloric acid is used, skin and eye contact can occur. This hazard can be reduced with the use of Nitrile butyl rubber or neoprene gloves and the use of safety goggles. 10 [][][] ARCO Service Station #1960 Site Safety Plan September 18, 1990 4.3.4 Cleaninq EquiDment: Skin and eye contact with methanol, Alconox, or other cleaning substances can occur while cleaning equipment. This hazard can be reduced with the use of Nitrile butyl rubber or neoprene gloves and the use of safety goggles. 4.3.5 Confined Space: Manholes, subsurface vaults and sheds are examples of confined spaces that may lack adequate ventilation. Organic and/or combustible vapors may be trapped resulting in a lack of oxygen (anoxia) and/or overexposure to vapors. When site work takes place in a confined space the air must be monitored for (a) oxygen level, (b) flammable vapors, and (c) toxic vapors. The following air monitoring procedures must be followed before entering a confined space. a. Oxyqen Level: Monitor for % Oxygen with an O2/LEL meter to ensure a minimum oxygen level of 19.5%. Oxygen level monitoring will be done at the top, middle and bottom of the enclosed space to determine if there is a minimum acceptable oxygen level of 19.5% PRIOR to entry. If oxygen is less than 19.5%, do not enter the space. b. Explosive Vapors: Monitor for % of Lower Explosive Limit (LEL) with a 02/LEL meter to determine whether vapor concentrations within the confined space are within the flammable range. If LEL readings exceed 20%, personnel MUST leave the site immediately, and contact the project manager. c. Toxic Vapors: Monitor for toxic vapors with a PID and/or an FID (e.g., HNU or OVA) to determine whether toxic vapors within the confined space exceed the action levels. If the PID and/or the FID readings exceed 100 ppm, a full face respirator must be worn. All monitoring equipment must be calibrated and maintained in accordance with manufacturer's recommendations. If an HNU is used, the 10.2 eV lamp is required for accurate readings. ARCO Service Station #1960 Site Safety Plan September 18, 1990 d. Summary: Do not.enter the confined space unless: · the oxygen concentration is between 19.5 and 23%; · the LEL is less than 20%; · PID and/or FID readings are less than 750 ppm (a full face respirator must be worn if the readings exceed 100 ppm) e. Buddy System: The buddy system must be used when the work in the confined space: (1) requires the person's head to be below ground level; or (2) the person must work in a manhole or other space in which an exit may not be easily accessible. TABLE II HAZARD SUMMARY AIR MONITORING - BREATHING ZONE PPE Job Task Level Instrument Frequency* Soil boring D PID or FID At start of work and samples 15 min to continuously Monitoring D PID or FID At start of work and Well Installation 15 min to continuously Monitoring D PID or FID Start-up of work at each Well Survey well location Monitoring D PID or FID Start-up of work at each Well Development well location Groundwater Start-up of work at each and soil sampling D PID or FID well location. Ail air monitoring data must be recorded on the Vapor Monitoring Sheet, Appendix G. ARCO Service Station #1960 Site Safety Plan September 18, 1990 5.0 PERSONAL PROTECTIVE EQUIPMENT Modified Level D is the minimum acceptable level for this site. Modified Level D includes: · coveralls/work uniform steel toe and shank boots Nitrile butyl rubber or neoprene gloves (optional) · splash goggles/safety glasses if potential for splash hard hat fluorescent vest · Tyvek suit (optional) hearing protection (as appropriate) Level C includes: full face respirator NIOSH approved with organic vapor cartridges Tyvek suits (if splash hazard is possible, a coated suit must be worn) · Nitrile butyl rubber or neoprene gloves steel toe and shank boots · outer boots - chemical resistant inner disposable gloves (2 pairs recommended) hard hat fluorescent vest hearing protection (as appropriate) Level B includes: air supplied respirator coated Tyvek suit, such as Saranex Nitrile butyl rubber or neoprene gloves inner latex or vinyl gloves steel toe and shank boots outer boots - chemical resistant hard hat fluorescent vest hearing protection (as appropriate) ARCO Service Station #1960 Site Safety Plan September 18, 1990 6.0 Decontamination Procedures Ail operations conducted at this site have the potential to contaminate monitoring equipment and personal protective equipment (PPE). To prevent the transfer of contamination to vehicles, administrative areas and personnel, the following procedures must be followed: Equipment Decontamination 1. Whenever possible, monitoring equipment should be decontaminated with a solution of Alconox and thoroughly rinsed with water prior to leaving the site. This must be done outside a 5-foot radius of any work area. Personal Decontamination LEVEL D * segregated equipment drop ~ wash/rinse outer boot (as appropriate) · wash/rinse chemical resistant outer glove, then remove (as appropriate) · remove hard hat, goggles/safety glasses/faceshield · remove and throw out inner disposable gloves in designated lined receptacles (as appropriate) LEVEL C · segregated equipment drop · wash/rinse outer boots · wash/rinse chemical resistant outer gloves, then remove · remove outer boots and place to dry (if reusable) · remove chemical resistant suit (remove by rolling down the suit) · remove first pair(s) of disposable gloves · remove respirator/hard hat/faceshield dispose of cartridges and wash respirator ~ remove last pair of disposable gloves LEVEL B · segregated equipment drop · wash/rinse outer boots · wash/rinse chemical resistant outer gloves, then remove · cross hotline (into clean area) and change air tanks, then redress or · cross hotline (into clean area) · remove boots and gloves · remove SCBA, if worn over chemical resistant suit · if SCBA is worn under the suit, remove the chemical resistant suit, then the SCBA · remove hard hat 14 ~ [---] ~--~I G ~NDWATEH ARCO Service Station #1960 Site Safety Plan September 18, 1990 7.0 CHEMICALS OF CONCERN 7.1 Health Effects Potential health effects from a chemical exposure are dependant on several exposure factors such as: toxicity of substances, duration of exposure, concentration during exposure and the overall health of the person exposed. The chemicals commonly at this site are: Gasoline, Benzene, Toluene, Ethylbenzene, and Xylene. The following is a health analysis of these chemicals. Additional information on these chemicals can be found in the Material Safety Data Sheet located in Appendix E. Gasoline constituents can be divided into five major groups: alkanes, alkenes, cycloalkanes, aromatics and additives. The aromatics are the constituents generally regarded to be of greatest toxic concern. The major aromatics in gasoline are benzene, toluene, ethyl benzene and xylene. Of these, benzene is considered to be the most toxic. One characteristic effect of gasoline and its aromatic constituents is their ability to irritate the skin when repeated or prolonged exposure occurs. Benzene Benzene can enter the body through inhalation, ingestion and skin contact. Studies have noted that chronic exposure to benzene vapor can produce neurotoxic and hematopoietic (blood system) effects. Other effects can include headache, dizziness, nausea, convulsions, coma and possible death if exposure is not reversed. One significant effect from chronic benzene exposure is bone marrow toxicity. There is also an association between chronic exposures to benzene and the development of certain types of leukemia. Toluene Inhalation exposure to toluene vapor can produce effects such as central nervous system depression. Depending on exposure factors signs and symptoms can include headache, dizziness, fatigue, muscular weakness, incoordination, drowsiness, collapse and possible coma. Toluene can be a skin and mucous membrane irritant and studies have shown that high levels of toluene exposure can cause liver and kidney damage. ARCO Service Station #1960 Site Safety Plan September 18, 1990 7.1 Health Effects (Continued) Eth¥1benzene Exposure to ethyl benzene at high vapor concentrations may.produce irritation to the skin, eyes. and upper respiratory tract. Overexposure to ethyl benzene vapors can produce central nervous system depression with symptoms of headache, nausea, dizziness, shortness of breath and unsteadiness. Prolonged skin exposure to ethyl benzene may result in drying and cracking of the skin (dermatitis). Solvent resistant gloves should be worn during sampling to prevent exposure to the skin. Xylenes Depending on exposure factors, inhalation exposure to xylene vapor may produce central nervous system excitation followed by depression. Exposure to xylene vapor can produce dizziness, staggering, drowsiness and unconsciousness. At very high concentrations, xylene vapor may produce lung irritation, nausea, vomiting and abdominal pain. Xylene is not known to possess the chronic bone marrow toxicity of benzene, but liver enlargement and nerve-cell damage have been noted from chronic overexposure. 16 ARCO Service Station #1960 Site Safety Plan September 18, 1990 8.0 GAS/VAPOR MONITORING PROCEDURES The greatest potential hazards to safety and health at this site are: 1. Exposure to chemical vapors - through inhalation 2. Exposure to chemical contamination - through skin contact and ingestion. Ongoing air monitoring during project tasks will provide data to ensure that vapor concentrations are within acceptable ranges and will provide adequate selection criteria for respiratory and dermal protection. 8.0.1 If PID readings exceed 100 ppm, a NIOSH approved air-purifying respirator with organic vapor cartridges must be worn by all site workers within any area where monitoring results exceed 100 ppm. 8.0.2 If PID readings exceed 750 ppm, level B protection will be required. Personnel must leave site immediately and contact site safety officer or Health & Safety Manager for further instructions. 8.0.3 Respirator cartridges will be changed once per day as a minimum. This can be accomplished at the end of the work day during respirator decontamination. If odor breakthrough is detected while wearing the respirator or breathing becomes difficult, change cartridges immediately. 8.1 Tasks Performed Within a Confined Space When site work takes place in a confined space the air must be monitored for (a) oxygen level; (b) explosive vapors; and (c) toxic vapors. The following air monitoring procedures must be followed before entering a confined space. a. Oxyqen Level: Monitor for % Oxygen with a O2/LEL Meter to ensure a minimum oxygen level of 19.5%. Oxygen level monitoring will be done at the top, middle and bottom of the enclosed space to determine if there is a minimum acceptable oxygen level of 19.5% prior to entry. If oxygen is less than 19.5%, do not enter the space. ARCO Service Station #1960 Site Safety Plan September 18, 1990 b. Explosive Vapors: Monitor for % of Lower Explosive Limit (LEL) with a 0~/LEL Meter to determine whether vapor concentrations within the confined space exceed 20% of the LEL. If readings exceed 20% LEL, personnel shall shut off accessible equipment, leave the site immediately, and contact the fire department. c. Toxic Vapors: Monitor the air within the confined space for organic vapors with a PID or FID following guidelines stated in 'Section 8.0 (above) to decide on the respiratory protection needed. Enter the space only if the oxygen level is at or above 19.5%, the %LEL is below 20%, the toxic vapor concentration is determined, and the proper respiratory protection is worn. PID or FID readings will be taken at the top, middle and bottom of a vault, shed, or other confined space to ensure that vapors do not exceed acceptable levels. All monitoring equipment must be calibrated and maintained in accordance with manufacturer's recommendations. ARCO Service Station #1960 Site Safety Plan September 18, 1990 9.0 HEALTH AND SAFETY REQUIREMENTS 9.1 Medical Monitorinq Program All Groundwater Technology, Inc. field personnel are required to have annual medical evaluations in accordance with the company's Health and Safety Program policy. Additional re-evaluation will be considered in the event of chemical over-exposure while working on this site. The petrochemicals typical of these facilities can affect specific organ systems producing characteristic health effects. The medical evaluation will, therefore, focus on the liver, kidney, nervous system, blood systems, and skin and lung function. Laboratory testing will include complete blood count, and applicable kidney and liver-function tests. Other tests include skin examination. 9.2 Traininq Ail personnel working at this site should have received a minimum of 40 hours of initial hazardous waste activity instruction, and a minimum of three days of field experience under the direct supervision of a trained, experienced person. Personnel assigned to the site will also receive eight hours refresher training per year. On-site managers and supervisors directly responsible for employees engaged in hazardous waste operations have received an additional eight hours of supervisory training. These training requirements comply with the OSHA Hazardous Waste Operations and Emergency Response regulation, 29 CFR 1910.120. The initial 40-hour training and the 8-hour annual refresher training includes specific details on the following: Regulatory Requirements First Aid/CPR Confined Space Entry Respiratory Protection Air Monitoring Decontamination Procedures Hazard Communication Toxicology These specifications are then complimented with actual hands-on experience with the use of personal protective equipment and air monitoring equipment. 9.3 Work Zones Access Access within a 5-foot radius of any on-site operation is prohibited to all but Groundwater Technology, Inc. field personnel and subcontractors. ARCO Service Station #1960 site Safety Plan September 18, 1990 9.4 Emergency Equipment Vehicles used for site work will be equipped with a first aid kit and safety equipment including: fluorescent vests, cones, flags (as needed) barricades (as needed) fire extinguisher-dry chemical ABC-type extinguisher, flashlight, water, suitable for drinking, portable eye wash, appropriate emergency bandage material. 9.5 Carbon Treatment If this site involves the use of a Carbon Treatment System, then the following information will apply. The Carbon Treatment System is equipped with an emergency shut-off. The system will shut off automatically when the non-methane TPH vapor concentrations in the intermediate line reach 5% of the Lower Explosive Limit (LEL) for gasoline as recorded by the system monitors. The suggested equipment for decontamination and spill response procedures includes: wash tubs (3) plastic sheets trash bags scrub brushes detergent sorbent booms (as applicable) The carbon system is a closed system where no chemicals are used. The potential for a spill is minimal and thus spill containment is not addressed in this Site Safety Plan. 9.6 Drilling Procedures A Dig-Alert authorization number must be obtained prior to drilling. During the drilling operation, two persons (one designated as "driller" and the other as "helper") must be present at all times. The helper (whether Groundwater Technology, Inc. personnel or subcontractors) must be instructed as to the location of the emergency shut-off switch. Every attempt must be made to keep unauthorized personnel from entering the work area. If this is not possible, the operation should be shut down until the area is cleared. The area where the operation is taking place shall be cordoned off with a barricade. The Site Safety Officer or the Field Team Leader has the authority and the responsibility to 20 ~--~--~ 'ITECH~LOG~ ARCO Service Station #1960 Site Safety Plan September 18, 1990 shut down the drilling operations whenever a hazardous situation is deemed present. The mast of the drilling rig must maintain a minimum clearance of 20 feet from any overhead electrical cables. All drilling operations will cease immediately during hazardous weather conditions such as high winds, heavy rain, lightening and snow. Hart hats shall be worn at all times. Hearing protection shall be worn during noisy operations. If product is encountered during the drilling operation, all work must stop in order for employees to upgrade personal protective equipment to Level C. A full-face respirator should be worn in order to prevent the inhalation of vapors and to provide face and eye protection from splashes. Coated tyvek suits, gloves, and overboots should be worn to prevent skin contact with the soil. Air monitoring must be performed in the work area to document breathing-zone concentrations. If air monitoring results indicate concentrations greater than 700 ppm, then Level B respiratory protection will be implemented. Respirator cartridges must be changed at the end of a work period or if "breakthrough" occurs. If employees experience continuous cartridge "breakthrough", then the employees' work procedures and the level of respiratory protection must be re-evaluated by the Site Safety officer and the Health and Safety Manager in order to determine the necessity of upgrading to Level B respiratory protection. 9.7 Electrical Equipment and Ground-Fault Circuit Interrupters All electrical equipment and power cables in and around wells or structures suspected of containing chemical contamination must be intrinsically safe and equipped with a three-wire ground lead, rated explosion-proof for hazardous atmospheres. In accordance with OSHA 29 CFR 1926.404, approved ground fault circuit interrupters (G~CI) must be used for all 120 volt, single phase, 15 and 20 ampere receptacle outlets on the site which are in use by employees. Receptacles on the ends of extension cords are not part of the permanent wiring and therefore, must be protected by GFCI's whether or not the extension cord is plugged into permanent wiring. The GFCI is a fast-acting circuit breaker which senses small imbalances in the circuit caused by current leakage to ground, and in a fraction of a second shuts off the electricity. However, the GFCI will not protect the employee from line-to-line contact hazards (such as a person holding two "hot" wires or a hot and neutral wire in each hand). The GFCI does provide protection against the most common form of electrical shock hazard - the ground fault. It also provides protection against fires, overheating, and destruction of insulation on wiring. 21 ---] [---] ~---]1 GROUNDWA~R ARCO Service Station #1960 Site Safety Plan September 18, 1990 GFCIs can be used successfully to reduce electrical hazards on construction sites. Tripping of GFCIs - interruption of current flow - is sometimes caused by wet connectors and tools. It is good practice to limit exposure of connectors and tools to excessive moisture by using watertight or sealable connectors. Providing more GFCIs or shorter circuits can prevent tripping caused by the cumulative leakage from several tools or by leakages from extremely long circuits. (Adapted from OSHA 3007; Ground-Fault Protection on Construction sites, 1987.) 9.8 Fire Prevention During equipment operation, periodic vapor concentration measurements should be taken with an explosimeter or combustimeter. If at any time the vapor concentrations exceed 20% of LEL, then the Site Safety Officer or designated field worker should immediately shut down all operations. Only Factory Mutual (FM) approved fire safety cans will be used to transport and store flammable liquids. Ail gasoline and diesel-driven engines requiring refueling must be shut down and allowed to cool before filling. Smoking is not allowed during any operations within the work area in which petroleum products or solvents in free-floating, dissolved or vapor forms, or other flammable liquids may be present. No open flame or spark is allowed in any area containing petroleum products, or other flammable liquids. 9.9 General Health Medicine and alcohol can increase the effects of exposure to toxic chemicals. Unless specifically approved by a qualified physician, prescription drugs should not be taken by personnel assigned to operations where the potential for absorption, inhalation, or ingestion of toxic substances exists. Drinking alcoholic beverages is prohibited. Drinking alcoholic beverages and driving is prohibited at any time. Driving at excessive speeds is always prohibited. Skin abrasions must be thoroughly protected to prevent chemicals from penetrating the abrasion. It is recommended that Contact Lenses not be worn by persons working on the site. 9.10 MSDS Information Material Safety Data Sheets (MSDS) on chemical substances encountered at the site shall be made available to all persons (including subcontractors) working at the site. These MSDSs shall be enclosed within this site safety plan in Appendix E. For emergency situations not specifically addressed by this site safety plan, refer to MSDS recommendations for action information. ARCO Service Station #1960 Site Safety Plan September 18, 1990 10.0 PROJECT PERSONNEL Groundwater Technology, Inc. will oversee and act accordingly during all phases of the project. The following management structure will be instituted for the purpose of successfully and safely completing this project. 10.1 Project Manaqer: Jonathan Parker The Project Manager will be responsible for implementing the project and obtaining any necessary personnel or resources for the completion of the project. Specific duties will include: coordinating the activities of all subcontractors, to include informing them of the required personal protective equipment and insuring their signature acknowledging this Site Safety Plan (see Appendix A), selecting a Site Safety officer and field personnel for the work to be undertaken on site, ensuring that the tasks assigned are being completed as planned and on schedule, providing authority and resources to ensure that the Site Safety Officer is able to implement and manage safety procedures, preparing reports and recommendations about the project to clients and affected Groundwater Technology, Inc. personnel, ensuring that persons allowed to enter the site (i.e., EPA, contractors, state officials, visitors) are made aware of the potential hazards associated with the substances known or suspected to be on site, and are knowledgeable as to the on-site copy of the specific site safety plan. · ensuring that the Site Safety officer is aware of all of the provisions of this site safety plan and is instructing all personnel on site about the safety practices and emergency procedures defined in the plan, and ensuring that the Site Safety officer is making an effort to monitor site safety, and has designated a Field Team Leader to assist with the responsibility when necessary. ARCO Service Station #1960 Site Safety Plan September 18, 1990 10.2 Health & Safety Manaqer Maureen Grant The Health & Safety Manager shall be responsible for the overall coordination and oversight of the site safety plan. Specific duties will include: approving the selection of the types of personal protective equipment (PPE) to be used on site for specific tasks, monitoring the compliance activities and the documentation processes undertaken by the Site Safety Officer, · evaluating weather and chemical hazard information and making recommendations to the Project Manager about any modifications to work plans or personal protection levels in order to maintain personnel safety, · coordinate upgrading or downgrading PPE with Site Safety Officer, as necessary, due to changes in exposure levels, monitoring results, weather, other site conditions, approving all field personnel working on site, taking into consideration their level of safety training, their physical capacity, and their eligibility to wear the protective equipment necessary for their assigned tasks (i.e.: Respirator Fit Testing Results), and, overseeing the air monitoring procedures as they are carried out by site personnel for compliance with all company health and safety policies. 10.3 Site Safety Officer Jonathan Parker The Site Safety Officer shall be responsible for the implementation of the site safety plan on site. Specific duties will include: · monitoring the compliance of field personnel for the routine and proper use of the PPE that has been designated for each task, ·routinely inspecting PPE and clothing to ensure that it is in good condition and is being stored and maintained properly, · stopping work on the site or changing work assignments or procedures if any operation threatens the health and safety of workers or the public, ARCO Service Station #1960 site Safety Plan September 18, 1990 · monitoring personnel who enter and exit the site and all controlled access points, reporting any signs of fatigue, work-related stress, or chemical exposures to the Project Manager and/or Health & Safety Manager, · dismissing field personnel from the site if their actions or negligence endangers themselves, co-workers, or the public, and reporting the same to the Project Manager and/or Health & Safety Manager, reporting any accidents or violations of the site safety plan to the Project Manager and/or Health & Safety Manager, and documenting the same for the project in the project records, knowing emergency procedures, evacuation routes and the telephone numbers of the ambulance, local hospital, poison control center, fire and police departments, ensuring that all project-related personnel have signed the personnel agreement and acknowledgments form contained in this site safety plan, · coordinate upgrading and downgrading PPE with the Health & Safety Manager, as necessary, due to changes in exposure levels, monitoring results, weather, and other site conditions, and perform air monitoring with approved instruments in accordance with requirements stated in this Site Safety Plan (see monitoring procedures on page 20 for specific information). 10.4 Field Team Leader Tina LePaqe In the event that the Project Manager and the Site Safety officer are not on site, the Field Team Leader will assume all responsibility of the Site Safety officer. 10.$ Other Field Personnel Technician staff is responsible for system maintenance, calibration and system operation. Records of site visits documenting system conditions are maintained by the technicians. All field personnel shall be responsible for acting in compliance with all safety procedures outlined in the site safety plan. Any hazardous work situations or procedures should be reported to the Site Safety Officer so that corrective steps can be taken. TF~Ol,O6~ INC. ARCO Service Station #1960 site Safety Plan September 18, 1990 10.6 Medical/Technical Advisors Frank H. Lawrence, M.D. ENVIROLOGIC DATA, Portland, Maine ................ (207) 773-3020 Marilyn E. Grant, R.N., B.S., C.O.H.N ENVIROLOGIC DATA, Portland, Maine ................ (207) 773-3020 Lori St. Pierre, I.H.I.T. ENVIROLOGIC DATA, Portland, Maine ................ (207) 773-3020 The specific duties of the Medical/Technical Advisors include: providing technical input into the design of the site safety plan, ~ advising worker exposure potential along with appropriate hazard reduction methods, and recommending a suitable medical monitoring program for the site workers. ARCO Service Station #1960 Site Safety Plan September 18, 1990 APPENDIX (Agreement and Acknowledgment Statement) TECI-INOLOGY, INC.SIGN - OFF SHEETS This is to cerli[y that I have read, fully undersland and agree to comply fully with the attached Health and Safety Plan furnished Io me blt Groundwater Technology, Inc. for the above project. NAME SIGNATURE COMPANY DATE ~PPENDIX B (Site Safety Plan Amendment Sheet) ~PPENDIX B Site Safety Plan Amendment Sheet Project Name: Project Number: Location: Changes in field activities or hazards: Proposed Amendment: Proposed by: Date: Approved by: Date: Project Manager Date: Health & Safety Manager Declined by: Date: Amendment Number: Amendment Effective Date: ~PPENDIX C (Definition of Hazard Evaluation Guidelines) ~ ~F-'-][ GROUNDWATER APPENDIX C Definition of Hazard Evaluation Guidelines Hazard: Airborne Contaminants Guideline Explanation Threshold Limit Value The time-weighted average concen- Time-Weighted Average tration for a normal 8-hour work (TLV-TWA) day and a 40-hour work week, to which nearly all workers may be repeatedly exposed without adverse effect. Permissible Exposure Limit Time-weighted average concentra- (PEL) tions similar to (and in many cases derived from) the Threshold Limit Values. Immediately Dangerous to "IDLH" or "Immediately dangerous Life and Health to life or health" means any (IDLH) atmospheric condition that poses an immediate threat to life, or which is likely to result in acute or immediate severe health effects. This includes oxygen deficiency conditions. ~azard: Explosion Guideline Explanation Lower Explosive Limit The minimum concentration of (LEL) vapor in air below which propagation of a flame will not occur in the presence of an ignition source. Upper Explosive Limit The maximum concentration of fUEL) vapor in air above whic~ propagation of a flame will not occur in the presence of an ignition source. Hazard: Fire uideline Explanation ~lash Point The lowest temperature at which ~lash p) the vapor of a combustible liquid can be made to ignite momentarily in air. APPENDIX D (site maps) APPENDIX E (MSDS) ~~OUNDWA'rER LOGY, From Genium s Reference I BENZENE Genium Publishing Corporation [ (Revision D) 1145 Catalyn Street [ Issued: November 1978 Schenectady, NY 12303-1836 USA SECTION 1. MATERIAL' IDENTIFi'cAT'ION 25 Material Name: BENZENE Description (Origin/Uses):' Used in the manufacture of medicinal chemicals, dyes, linoleum, airplane dopes, varnishes, and lacquer~; and as a solvent for waxes, resins, and oils. .: HMIS Other Designations: Benzol; Phene; Phenylhydride; C,H,; NIOSH RTECS No. CY140(~00; H 2 CAS No. 007143-2 F 3 R 1 Manufacturer: Contactyour supplier or distributor. Consult the latest edition ct'the C~micalweett R 0 I 4 Buyerx' Guide (Oenium tel 73)/'or a list of supplier. PPG**See sect g SK ,t2 ]SECTION 2.' INGREDIENTS AND HAZARDS % EXPOSURE LIMITS I Benzene, CAS No. 0071-434 Ca IIX) OSHA PEL 8-Hr TWA: 1 ppm 15-Mia Ceiling: :5 ppm  Action Level: 0.5 ppm ACGIH TLV,' 1957-88 TLV-TWA: 10 ppra, 30 mg/m~ Toxicity Data" Human, Inhalation, LC,.: 20CO ppm/$ *See NIOSH, RT£CS, for additional data with references to irfi.'.afivc, mutagcnic, Human, Oral, TDt~: 130 rog/kg tumorigenic, and reproductive effcc~s. Human, Inhalation, TCu,: 2 l0 ppm SECTION 3. PHYSICAL DATA Bolling Point: 176'F(80'C) Water Solubility'(%): Slight Melting Point: 42'I::(5.5'C) % Volatile by Volume: Vapor Pressure: 75 Tom at 68'F (20'C) Molecular Weight: 78 Gram..~Mole Vapor Density (Alt = 1): >I Specific Gravity (H,O = I): 0.87865 at68'F(20'C) Appearance and Odor: A colorless liquid; characteristic aromatic odor. SECTION 4. FIRE AND EXPLOSION DaTA LOWER .UPPER Flash Point and Method [ Autoignition Temperature , Flammability Limits in Air 12'[: (-I lA'C) CC [ 928'I: (498'C) ~ % by Volume 1.3.% 7.1 Extinguishing Media: Use dry chemical, foam, or carbon dioxide to put out benzene fires. Water may be ineffective as an extinguishing agent because it can scatter and spread the fire, Usc water to cool fi.,'c-cxposcd containers, flush spills away from exposures, dis~rse benzene vapor, and protect personnel attempting to stop an unignited be~er.e leak. Unusual Fire or Explosion Hazards: Benzene vapor is heavier than air and can collect in low-lying areas such as sumps or welLs. Eliminate all sources of ignition there to prevent a dangerous flashback to the original l/quid be.':~ne. Danger: Explosive and flammable benzene vapor-air mixtures can easily form at room temperature; always use thL~ material in a way that minimizes dispersion of iu vapor into general work areas. Special Fire-fighting Procedures: Wear a self-contained breathing apparatus (SCBA) wi':.'~ a full facepiece operated in the demand or positive-pressure mode. SECTION 5. REACTIVITY DATA Benzene is stable in closed containers during routine operations. It does not undergo hazardous ~lymerization. Chemical Incompatibilities: Hazardous chemical re~:tions involving benzene and the following materials are reported in Ge~ium reference 84: bromine pentafluoride, chlorine, chlorine t~h"luoride, chromic anhydride, nitryl pe,':hlorate, oxygen, ozone, perchlorates, perchloryl fluoride and aluminum chloride, permanganates and sulfuric acid, potassium peroxide, silver perchlorate, a~d sodium peroxide. I Condltlons to Avoid: Avoid all exposure to sources of ignition and to incompatible chemicals. Hazardous Products of Decomposition: Toxic gases like carbon monoxide (CO) may be ~'roduced during ~nzene rims. No. 316 BENZENE 4/88 SECTION 6. HEALTH HAZARD INFORMATION ....... :~?:-~:' :i~: '~::?~,'.~"~::".~'~."~':~.:.:.-'!::~!:~:'".:---' .' ..'.". Benzene is listed a~ a susp~wxl human c~ogen by ~ ACGIH .... ~.. Sum mary or Risks: ~l~g~ ~i~ con,ct wi~ ~ or cxce~ive ~hala~on of i~ vapor ~y cau~ he~he, w~es~ loss of ~pc/im, a~ l~it~e. C~gnu~ ex~s~c c~ ca~ collap~, bm~hi~, ~d p~u~ni~ ~c ~st i~o~t (leu~e~a), ~nc ~w cff~, md inju~cs ~ ~c bl~d-fo~g g~uc ~om c~c low-level exposure. '" Medical Conditions A~grsvsted by Lonl-Term Exposure: Ai~n~ of~c h~ lungs, ~v~r, kidneys, bl~, m~ous sys~m (CNS) may ~ wo~n~ by exhale. AdwJnis~r pr~laccment ~d ~g~ic ~ical cxa~ cmpha~g ~e~ o~ans' ~nctions ~d re~ign worsen w~ ~t ~si/ive. Target Organs: BI~, CNS, ~ne m~w, eyes, and up~r ~R~. Primary Entry: ~i~ ~nac~ ~hda~on. Acute Effects: Di~e~, ment~ dull~ss, nau~ he~ac~, faggue, giddi~ss. Chronic E[l~cts: Possible c~c~(lcu~c~a). FIRST AID Eyes: l~dia~ly flu~ cyc~ ~clad~g v~cr ~c e~Ed~ gently but ~omughly wi~ plenty ofm~ing wa~ for at lc~t 1~ ~u~s. 5kin: I~ia~ly w~h ~ aff~ g~ wi~ soap ~d wa~r. lnhnlatioa: Re~vc ~c ex~ p~n ~ ~csh ~; ms~ a~ s~n his or hm bma~g ~ Ingestion: Never ~ve ~g by ~u~ ~ ~one w~ ~ u~on~ious g convuls~g. ~ not indu~ young becau~ of~e ~sgbi~ of ~pkaion. GET MEDICAL HELP (IN PLANT, PARAMEDIC, COMMUNITY) FOR ALL EXPOSURES. Seek prompt medical assistance for further treatment, ob~rvstlon, sad support after first aid. SECTION 7. SPILL~ LEAK, AND DISPOSAL PROCEDURES Spill/Leak: No~y s~cty ~nncl, provide rendition, ~d eE~nam all sour~s of ig~on i~cdiaaly. Clc~up pc~onneI p~t~on ~a~st coast wi~ ~ inhalation of va~r (~c ~L 8). Contain l~gc spills ~d ~E~t was~ or ab~rb it wi~ ~ ~cn ma~ ' such ~ s~d, e~% or ve~cu~. Use nonsp~ng ~ ~ pl~c w~ liquid or absent ~ closable ~n~incm for d~Fosal. Keep w~ out of ~we~, w~h~s, ~ waylays. Waste DIsposal: Con,ct yo~ supplier or a licc~ ~n~r tcr derailed r~o~cnda~om tot disposal. Follow Fcde~k sram, ~d l~al rcgula~oas. OSHA Designations Ak ConSOnant (29 CFR 1910.1~ Subp~ Z) EPA Designations (40 CFR 302.4) RCRA H~ous W~, No. U019 CERC~ H~ous Subs~cc, Rc~blc ~[ity: I~ lbs (4~4 SECTIONS. SPECIAL PROTECTION INFORMATION ..... ' : .. .:. God,les: Always w~ ~fivc eyeglass or chc~c~ s~c~ gc~l~. ~cm spl~hing is ~ssible, we~ a eye-~df~e-pm~cfiontuiflc~ncs~ 2gc~1910.133. Respirator: We~aNlOSH-app~v~mspka~r~r~eN/OSHP~tG~i~ ~o C~ H~ for ~c ~ximum-use ~n~n~ons ~or uhc ex~s~ ~ ci~d ~ ~c~cn 2. PoDow ~e msp~r guidel~es in ~ C~ 19!0.l]4. ~r c~g~cy or ~nmu~ u~ (c.g., clc~i:g m~ar v~sels or sadie ~), wc~ ~ SCBA with a ~ f~cpi~e ~mtcd in ~ p~um4c~d or ~sifive-~rcs~re ~, Wir~ing: Ak-pu~ing re~ka~m will ~ pm~ct wor~ers ~ oxygen- deficient a~osp~ms. Other: Wc~ im~ious gloves, ~ a?mn~ gaunflc~ ~., ~ prevent a~y ~ssibfli~ suspend hum~ c~ogca. Ventilltlon: I~11 ~d o~r~ t~n~fl ad loc~ vcn~ion sys~ ~wc~l c~u~h ~me levels of ~n~ac ~low ~e ~HA FEL s~d~ ci~ in ~oa 2. Safety Stations: M~c cyew~h s~s, w~h~i f~fl~, ~d sff¢~ showc~ av~lable in ~c a~d h~d~g ~as. Contaminated Equymen/: C~l~l I~5 ~ ! special h~-d; ~ft ~s ~y ~rb ~ ~d ~1 lc~cs ~n~nUa~ ~c~ ~ ~r wc~ con~t c~cs ~ ~y wo~ ~a. Rc~vc ~n~na~ clouhi~ ~d laun~r it ~fom wc~ng it ~a~; cl~ ~s ~m~ ~m shes ~uip~n~ Corn meats: ~ficc t~ ~ hygi~; ~ways w~h aomughly afmr us~g ~is ~al. Keep it off of ~ur clot~g ~d equip~t. Avoid ~sfc~g it from yo~ h~s ~ yo~ ~u~h w~le c~g, ~n~ing, or s~ng. ~ ~t ca~ dfi~ or s~kc ay ~rk ~. ~ not ~hde ~n~c v~r! ~ECTION 9. SPECIAL PREQAUTIONS AND ~OMMENT~ ..' , S torage/Segregatloa: S~ ~c ~ ~ ~1, ~, wc~-venfl~d g~ sway ~m ~s of ~on ~d incompafible che~cas. ~ecial Handling/Storage: ~o~ct ~ntdn~ ~m ph~ic~ gamagc. E!~ca~y ~u~d ~d ~M ~I mc~ ipping or ~asfc~ng o~mfio~. ~lbw aH ~ of 29 C~ 1910.1~8. Engineering Controls: A~ eng~e~g sys~ ~o~ ~n~r~on, c~.) must ~ of ~mum cxplosion-p~f dcsi~ (non- .~-~ng. clec~cally gmun~d ~ ~nd~, c~.) i .mine nts: If ~iblc, subs~ l~s ~xic solv~ for ~n~c; use ~ ~fi~ wi~ ex,cmo ~u~on ~d o~y ~ R is ~solu~ly T :nsportatlon Data (49 CFR 171.10I-l) E T Shipping Name: ~cn~c DOT Label: ~mm~lc ~quid IMO Label: ~ammabte ~quid O~T Cla~: H~m~l~ Liquid DOT ID No. UNlll~ IMO Class: 1 ~rences: 1, 2, 1~ 73, 84-94, 1~, 103. ~ ...... ~ ,-~ ia ~ ~oa ~ ,~ ~fo~. ~ ~t~as co~. IM~ Hygiene Renew: DJ Wilson, ~ ~e ~y or mi~lRy ~ ~ ~f~im f~ ~pl~ ~ M~c~ Review: ~ H~,~ 1145 Catalyn Strcc ,(Revision Schenectady, NY 12303-1&,~o-uSA [Issued: August 1979 (518)37%8855 c~p~u~co~. ~Re~ed: A~H1 I986 SECTION 1. MATER~L ~ENTIFiCATiO~ .. H: 2 CTH~, CAS ~10I-gS-3 R: 0 PPE* MANUFA~E~SUPP~ER: Av~able ~m ~y r~FpEe~, ~clud~g: *~ S~ 8 ~ed Co~., ~ Box 2~R, Mo~, NJ 07~; Columbus, OH; Telephone: (614) 889-3~ , ::~SECTION 2.-~GREDIENTS ~D HAZA~S~ "-~ :'.::,.:' ....... ~ -' .:' HAZED DATA ~I~ [ 8-~ ~V: 1~ ~ or Tolueu: I ] I~ ~= Psycho~pic" · · , Cu~nt (19t54~ ACGiH ~V. T~e OSHA P~L ~um ~ of 5~ pp~10 ~u=. s~ ~d can~bu~ ~ ov~fll ex~u~ ..................... :;~.SECTION 3.'PHYSICAL DATA ~'. · ..'...'"- .:. Va~r ~:si~ (~ = 1) ... 3.14 Mo ..... Wd~h[ ~.I~ · c raage of 10 ~ 15 ppm. B~au~.ch'=~ fatigue ~ ~?~d!y u~ ex~s~ U ~=~=, ~r ~ ~t a g~ ~'~g pmpe~. ~SE~ION 4.:FIRE AND EXPLOSION DATA ..- .' '.". :;..-;~ 4 LO~ER t UYPER 40'F (~'C) CC 8%'F (aS0'O % by Vel:~ 127 7.1 EX~NGUL~ING MEDIa' C~o dio~de, d~ che~dcfl, L~USUAL ~RE'E~LOSIQN E~i.~,~: ~h ~HA SPECIAL ~RE-FIG~NG PR~y~E5: F~ ;~fSECTION 5.:'REA~ITY DATA '- V':: ':'.:" ' · ' .'-.- .'"" · ..... "-" ',. ". ::- ?~%¥.:?."? ~:.." CHEMICAL IN~MP.A~BIL~IES: Tolue~ is sublc my cause f~ or explosion. Ni~c ~id ~d mlue~, cam~unds ~hat ~ d~ge~uxly explosive. ~4~ a~ck ~ fo~ of plas~cs, mb~, md ~a~gs. c~-~n ~nodde. Groundwater Technology, Inc. Standard Operating Safety Procedures March, 1990 Tank Disposal It is critical for the tank to be safely and properly disposed of. Check state and local disposal requirements. Whether sold to a scrap dealer or disposed of at an acceptable tank yard, some areas require an unprotected steel tank to be cut, or punctured sufficiently to render it unfit for future use as an underground storage tank. If reuse of tanks is permitted, make sure there are plans to certify that the tank is tight, structurally sound, and will meet all the requirements for a new installation. u~'.t op- 8 Groundwater Technology, Inc. Standard Operating Safety Procedures March, 1990 The tank must be blocked to prevent any movement. The tank's atmosphere should be constantly rechecked. The sludge contents and rinse water from the inside of the tank should be disposed of properly and in accordance with local, state and federal regulations. Transporting the Tank Certain steps must be taken before the tar,_k can be safely transported to the disposal site. These are the steps to be followed. Before the tank is removed from the site, the tank atmosphere should be rechecked to ensure that the flammable vapor concentration does not exceed safe levels for transport. The tank should not be moved from the site unti/readings taken with an O:/LEL are all below 20%. Readings should be taken by placing the probe into the fill opening with the drop tube removed. Readings should be taken at the top, rrfiddle and bottom portions of the tank. The O:/I_.EL meter must be cleared after each reading. If the tank has a non-removable fill tube, readings must be taken through another opening. Recheck to make sure any corrosion holes in the tank a_re plugged with screwed (boiler) plugs for transport, and that the 1/8 inch vent plug is on top of the tank for transport and storage. Tanks should be labeled with inform, at/on about the former contents, present vapor state, vapor-freeing treatment and date, and warning against certain types of reuse. Tanks should be secured and removed from the site as soon as possible, preferably on the day the tank is removed from the excavation. If a tank remains at a site overnight or longer, vapor may be regenerated from residues in the uncleaned tank, so the ta. nk must be rechecked for OJI.I::.L conditions before transporting. Groundwater Technology, Inc. Standard Operating Safety Procedures Man:h, 1990 Exhaust vapors from inerting should be vented at a minimum height of twelve feet above grade and three feet above any adjacent roof lines. The atmosphere at ground __ level should be tested periodically to be sure that vapors am being vented effectively into the upper atmosphere, and are not collecting at ground level. In order to test the effectiveness of the inerting procedures, the oxygen levels within the tank must be measured by use of a combustible gas/oxygen meter. To eliminate the chance of combustion, readings should be between 1-10% oxygen. Readings must be taken at the top, middle, and bottom of the tank. The tank should not be entered unless very specific safety procedures are followed. If the tasuk is to be entered for any mason, such as cleaning, supplied air breathing apparatus must be used. The tank v,511 be oxygen deficient following inching and may still contain high concentrations of vapors following p~ging. Entry into a tank without supplied air can result in immediate collapse followed by death in a few minutes. Sometimes, the tank is inened, excavated, and pulled from the ground, then forcefully ventilated mechanically with air before entry. Again, the O-.jUEL meter must be used to measure O= concentrations and LEL before enn"y is considered. The tank should not be entered at all if the LEL is over 20%. Extreme cautions must be used if the LEL is over 10% If the oxygen concentration is below 19.5%, a supplied air breathing apparatus must be worn. A supplied air or purifying respirator may have to be worn if toxic gas concen~ations exceed the action level stated in the main body of the site safety plan. If the tank was filled with gasoline, toxic gas readings should be taken with a PD and an 10.2er lamp or an FD. Air purifying respirators need to be worn if PD or FID readings exceed 100 units but are less than 750 units. If PID or I::D readings are over 750 units, the use of a supplied air respirator is mandatory. Cleaning out Sludge If sludge needs to be removed from the underground storage tank, the following safety procedures must be complied with. The tank must f'~rst be purged or ~erted to make it safe for handling. Then the tank can be tipped and jet rinsed with water to wash the sludge to one end of the tank. The sludge can then be pumped out while the tank is still in the excavation. Groundwater Technology, Inc. Standard Operating Safety Procedures March, 1990 Inerting Safety Precautions Inerting is a method of reducing the concentration of oxygen inside the storage tank to a level - insufficient to support combustion by replacing the oxygen with an inert gas. Inerting may be done by adding either carbon dioxide (dry ice) or nitrogen gas to the tank. Use of dry ice may is one method that may be used to generate carbon dioxide. This is done by crushing and distributing the dry ice evenly over the greatest possible area in the bottom of the tank, before the openings are plugged. Where practical, plug all openings except the vent after distributing the dry ice in the tank. Recommended amounts vary from 15-20 pounds per 1,000 gallons of tank capacity. The dry ice will release carbon dioxide gas as it warms. With this method, there is no momentum for vapors in the tank to move toward the vent, so inerting takes longer and may be less effective than inerting with nitrogen. Avoid skin contact with dry ice because it may produce burns. When dry ice is handled, heavy leather gloves must be worn. Nitrogen gas can be pumped into the tank from a hose that passes through the fill hole to the bottom of the tan.k. Nitrogen is lighter than air, so its introduction low in the tank is essential to effective inerdng. Caution needs to be taken when handling the bottles of compressed nitrogen. The nozzle or hose must be bonded or grounded to prevent static build-up. DO NOT INERT WITH COMPRESSED CARBON DIOXIDE GAS. Inerting with compressed carbon dioxide gas may be extremely dangerous. The contents are under pressure and static electricity can build up during discharge of the gas. More importantly, the compressed CO: has a much larger temperature difference with the outside atmosphere than bottled nitrogen. This difference leads to condensation which increases the generation of static electricity. In order to prevent reintroduction of oxygen into the tank, all holes should be effectively plugged, except for ti-,e vent line. Since the inert gas displaces some of the flammable vapors along with the oxygen in the tank, the same venting precautions for the exhaust must be followed as for a purging operation. Groundwater Technology, Inc. Standard Operating Safety Procedures March, 1990 To avoid rupturing the tank, air pressure in the tank must not exceed 5 psi. The subcontractor or responsible party must take into account the size of the vent opening as well as the rate at which air is pumped into the tank. An eductor-type air mover, typically driven by compressed air, draws vapors out of the tank and fresh air into the tank. The fill pipe (drop tube) should remain in place to ensure ventilation of the tank bottom tube. For this reason, the eductor-type method is a good method to use for tanks with non-removable fill pipes (drop tubes). The air mover should be bonded properly to prevent the generation and discharge of static electricity. NOT RECOMMENDED: The use of steam (as opposed to hot water sprays) to purge and clean the tank is not recommended. Steam, under greater pressure than hot water, is more likely to build up on the steam nozzle, and on insulated objects on which the steam impinges or condenses. Also, it is not an effective method in cold weather. If steam is used for either purg/ng or cleaning a tank or other equipment, all isolated conductors and objects subject to impingement or condensation, as well as the discharging hose or nozzle, should be properly bonded (to the tank or equipment) or grounded. Exhaust vapors from purging should be vented at a minimum height of twelve feet above grade and three feet above any adjacent roof lines. The atmosphere at ground level and by the excavation should be tested periodically while purging is in progress to be sure the vapors are being vented effectively into the upper atmosphere, and are not collecting at ground level. CAUTION! Pur~ng is a tempora.D' procedure, Product happed in the bottom sludge and wall scale regenerates flammable vapors inside the tank. TEST the %LEL FREQUENTLY inside the tank, in the excavation and any other below grade areas, and at ground level, especially near the vent! The concentration should not exceed 20% LEL of the product inside the tank. CAUTION! In air purging, with plenty, of oxygen present, the concentration of vapors in the tank may start out in the flammable range, or may go from too rich, down through the flammable range and then into the range of a safe atmosphere. It is especially important to ensure that all ignition sources have been removed from the area before this process beg/ns! - Groundwater Technology, Inc. Standard Operating Safety Procedures March, 1990 If it is necessary to use a hand pump to remove the bottom few inches of liquid, the subcontractor or responsible party must observe grounding and bonding procedures. If a vacuum truck is used for removal of liquid or residues, the area of operation for the vacuum truck must be vapor-free, and the truck should be located upwind from the tank and outside the probable path of vapor dispersion. The vacuum pump exhaust gases should be discharged through a hose of adequate size and length, downwind of the u-uck and tank area. Residual product and solids must be disposed of properly. Once the tank is emptied and exposed to the air, the atmosphere inside the tank is a mixture of product vapor and air. As long as no source of ignition is introduced, combustion cannot occur with this potentially dangerous mix of flammable vapors and oxygen. However, it is difficult at an excavation site to eliminate all potential sources of ignition (striking the tank with the backhoe could produce a spark). Before the tank is handled with large equipment, flammable vapors in the tank must be m-checked. Purging Safe~. Precautions Once the underground storage tank has been emptied of its contents, the concentration of any flammable vapors within the tank may be reduced or eliminated by utilizing purging procedures. This controls the concentration of the fuel, one of the factors necessary to start a rue. The following precautions should be adhered to when conducting pur~ng procedures. After the tank is emptied of product, the concenu'ation of flammable vapors in the tank can be reduced by pur~ng. This may be done by using either a diffused-air blower or an eductor- .type air mover. A diffused-air blower pumps air into the tank through the extended fill pipe (drop tube). Since the petroleum vapors are heavier than air, air must be introduced as low into the tank as possible so that product vapors are stirred up sufficiently to be moved out of the If the drop tube is removed, air can be pumped through an air diffusing pipe. This new pipe must be properly bonded (to the tank, for example) to prevent static build-up. Groundwater Technology, Inc. Standard Operating Safety Procedures March, 1990 Locate all utility, gas, and water lines which exist on-site prior to excavation. These need to be avoided at all times during excavation procedures. Call the local utility locator for information on utility lines. The water and sewer companies must also be called to locate those pipelines. It is the responsibility of the employer to ensure that the subconu:actor or responsible party demonstrates a knowledge, capability, and understanding of the product stored in the tank.. If not, the job should be stopped. Tanks containing products other than petroleum should be given special consideration. Such substances could have a dangerously low flash point or be toxic. If advice is needed on-site, call the Health and Safety Manager. If the Health and Safety Manager cannot be reached, the Fire Department or state envkonmental office may be able to provide assistance. Prior to the start of work all meteorological conditions should be checked. If there is little or no breeze blowing, vapors may accumulate at ground level. Under such conditions, consider delaying the removal or take additional precautions (such as ventiIating the work area with "explosion-proof' high capacity fans). For personnel protection, a hard hat, steel toed boots, safety goggles, a combustible gas/oxygen meter, and a PIX) or FID are essential items that must be utilized during on-site activities. The main body of the SSP will specify under what conditions a respirator must be worn. Check uhe action levels in the SSP prior to starting work. Preparation of the Tank Vapors and leakage of residual product may present a hazard. The following precautions must be taken before any liquid is removed fi.om the underground tank. When the piping is disconnected and the product in the piping is drained, a bucket should be placed at the end of the exposed pipe to avoid spillage. The emptied product piping must be capped and removed. When product and residues fi-om the tank are removed, explosion-proof or air- driven pumps should be used. Pump motors and suction hoses must be bonded to the tank (or otherwise grounded) to prevent electrostatic ignition hazards. CAUTION! Avoid using plastic (PVC) pick-up tubes on the stripping lines of vacuum trucks. The plastic' tubes are especially prone to accumulating static charges. UST REMOVAL Preparation of the Site -- Tank removal activities should not begin until the site has been adequately prepared for this potentially hazardous operation. All potential sources of ignition must be eliminated. Also, the site must be cordoned off so that bystanders and outsiders are not able to enter the work area. These precautions must be taken before tank removal activities begin. Ban smoking in the area. Shut down all flame and spark producing equipment within the vapor hazard area. Check with the local fke marshall to determine what the distance requirement is for the vapor hazard area. Remove all electrical and internal combustion equipment unless it is desired to be "explosion-proof". Use only non-sparking tools to expose tank fittings and to prepare for vapor freeing procedures. CAUTION! Even these tools are not risk free; pieces of metal embedded during previous use may cause a spark. Non-sparking tools are usually made of brass rather than other mater/als. Minimize ag/ration or static-producing movement generated by moving 1/quids, a/r, or solids. For example, static electricity results from: liquid flowing through a hose when product is pumped from the tank; ~om compressed gas or air being released into the tank atmosphere; or from the high speed rolling of pneumatic rubber tires on pavement under dry conditions. If static producing movement cannot be eliminated, a conductive path for the safe discharge of static electricity must be provided. Tiffs must be done by bonding or grounding equipment and vehicles. Equipment is "bonded" by connecting it with wire to something that is grounded (such as the tank, if the tank is still in contact with the earth). Equipment is "~ounded" by connecting it to earth or some conducting body which serves in place of the earth. Control access to the tank removal area by cordoning it off with barricades, hazard tape, or other suitable means. It may be necessary to post, "DO NOT ENTER" signs. APPENDIX J (UST Removal) APPENDIX I Immediate OSHA Inspection Steps 1. Identify the Inspector. (a) Ask to see credentials. (b) Write down the relevant information, including the inspector's name, agency affiliation, address, telephone number and the ._ statutory authority under which the inspection is being conducted.. (c) If any doubts, call OSHA office to verify the visit. (d) If inspection occurs at a project site, ask for written certification of medical monitoring (including respiratory evaluation) and for 40 hour hazardous waste training certification. NO ONE may venture out of the clean zone without it. DOUBLE CHECK it with his/her office if in doubt. 2. Notify the Health & Safety Manager and Project Manager immediately. (a) The Project Manager should notify the District Manager. (b) The Health & Safety Manager should notify Corporate Health and Safety (ELD). 3. Take notes on: (a) What is said (b) What is seen (c) Who spoke to whom (d) Any sample or copies taken (e) Any corrective actions done in the inspector's presence (f) Any activity, including where, when, who, and what (g) Any other occurrence, even if seemingly minor When in doubt on any question, DO NOT BLUFF AN ANSWER. Ask the inspector to put the question in writing, addressed to company counsel. Never lie, even by omission; jail can be the penalty. If inspection occurs on site, carefully review the Site Safety Plans with the Inspector if asked to do so. If inspection occurs at an office, have accident reports, OSHA 200 logs ready at all times for inspection. Always make sure OSHA poster is visible. Determine the scope of the inspection: Ask the OSHA inspector what areas of the company activity are of interest and the reason for the inspection. Discover what has triggered the inspection. If complaints initiated the inspection, find out specifically what they were. ~---][~--'q[~ GROUNDWATER L_] I I I IJ T~ZH~LOGY, I~C. APPENDIX I (OSHA Inspection Steps) TECHNOLOGY, INC. OA~ND, CA ound 9at~r Technolosy; !ac. ~O80 Pine Lane ~D R~lon~- San Fran~co . Concord, CA ga520 1-2387  15) 07 - TeL (&15) 5~-8002 ANNUAL - Tren:h ~nd/or Ex~a~ion Pursuant to Lobar Code Sections 6500 and 6502, this Permit rs i~uc6 to tha c:bove-named employer for the proio~ de.ri'bed below. ' ~'.- ........... ~,~ ........ ~-~v~~ecember 31, !990 arious projects Statnuide S tatewlde 3/20/90 !2/31/90 Permit is tssu.d upon the ~ol/ow/ng canditA~ns: ]. ~ ~e work is poHo~o4 by ~e ~me employer. I~ ~ i~ en annual ~t ~e appropriu~, D;~tr[~ ~ice ~all ~ notified, in wr~ng, of d~es and l~on ~ jo~ s~e prior to commencement. 2. ~ employer will comply w;~ all occup~onal ~fe~ ~nd h~ ~andards or orders pi/cable to the ~b~vo pro[~, and any o~er la~ul orde~ of ~ DMsion. 3.~ if any ~nfore~, cond~on ~u~s devi~on from ~a plans or ~men~ contained ~e Pe~ Appllc~on Fa~ ~e ~ployar will nofi~ ~e OMsioa im~diul~ly. 4. Any vari~on from ~e ~ific~on and as~Hlons of ~e Pe~H Applic~on Faint or 5. This p~rm~t sh.ll ~ posted ~ or 0~r ~c~ plat. o n d ~n 8 CAC 4~'LL~? lC. Jackson ~ ~.~ 3/4 ~"..X I 1 I // FLATTER THAN _ 3/4 TO 1 DRAFT EXCEPTIONS: In hard, compact soil where the depth of the excavation or trench is 8 feet or less, a vertical cut 5f 3-1/8 feet with sloping Of 3/4 horizontal to I vertical is permitted. CONSTRUCTION SAFETY ORDERS j 3/4 TO 1 8' .MAX. In hard, .compact soil where the depth of the excavation or trench is 12 feet or less, a vertical cut of 3-I- feet witin sloping of Borixontal to 1 vertical is permitted. (2} Benchin~ in hard, c~mpact soil, is per- mitted provided that a slope ratio of horizontal to I vertical, er flatter, is used. ', ...... (TYP)CA~)~ - !~l / " 3 MIN. ~.,~i I[~] GROL',~DV,'ATER .. : TECH~'OLOGY. ]SC. ! DE~i ' " ,, ,, ' DRAFT I ' ' TECHN(~I.()GY. I.\'L' ' . TECHN()i.()L;Y. ISL'. § ~].541 CONS'rfiUCTION ~_,,I--r.'~ O~'-'ms TITLE 8 ~,'C,,OD ~I. OPJ~,'C FOR l-lARD COMFACT' SOIL :5 I,, 7 4 2 · 10 4 a 4 INC. DRAFT ~h~ :, ~ ~ -. (~, 170.151) E~ING V~ OF bl~ r~:ulre f~t blc~ er ~ls to d~t~h,~ta the lo~d. In ~he lbzeact ct :c:: da:: that ~b~sh~a :ustai~g ~wer Ot the ~o~ tn qu~tion, the tetlc'.~ag ir~or- quate sup~ ~cm me ~fl. wo~ =lzy .................................................................... ~ad lnd day, ~d:rd in layer: .................................................. 2 · / D~IGN CONSiD E~ATiONS - EX~(VAT[ONS. ~LOP~ AND BENCH~ Taa dc ~ -~.,, c. the .,o e c. ~...n c .... ~ ..... ~nc,- c.~'-':-- .... .-:"~ ..... ~neru.~' ' avztem sn:ll be ~¢ u~cn re:.] c,~]2-2:., G, ~Jc,, Fcrhn:n: :::::rs us tr.e (2) P~':o~e variation M wz:rr ...... - .... v,,,,cn (2) A .......:.~. chang: :a Fr:= ex~z:r: to ::r ...... ~tored male:i~. . (5) V~or.t]on ,r .... eoutp,,.c ..... [ ......~, t,.l~c, h.,r~ c ..... c ...... cu.,. (67 ~ti~g underground (7) New or cid adiacent ev:lu:~i:n i:d{c:tcs othc~'i~. NOT~ Auth~rity ci~:d: ~:ic~ }~2.2, ~r ~!~..Rc{rrunc=: .Scot;an 1-i2.2. ~bo, Cede. III~ORY: - DRAFT 15. If protective shields, (i.e., trench shields) are to be utilized for the protection of employees within an excavation, a civil engineer registered in California must prepare the necessary calculations and designs prior to the use of such eq/uipment. 16. h~nen sloping or benching are 'utilized in lieu of a shoring system, the slope shall be at least three-qua~er horizontal to one ve~ical for excavations up to 8 feet, unless the instability of the soil req/uires a slope flatter than 3/4:1. For excavations greater than 8 feet but less than 12 feet, a slope of 1:1 shall be utilized (Appendix C). On the following pages are suecific rec~irements as .et by California Cod~ of Regulation, Title 8, Chapter 4, Subchaptar 4- Construction Safety Outline. The pages are facsimiles of pages from this document. 4068A Con-3/90 . ,~,i,. GROU~DI,¥ATI~R , TECH.%'OLOG): l~'C. DRAFT 5. The conditions in #4 above, will also re.cuire Groundwater Technology to obtain the necessary excavation permit and/or notification procedures with Cai-OSHA. 6. Excavated materials shall be prevented' from falling back into the excavation, spoils should be placed no closer than 2 feet from the edge of the-excavation. 7. Work which is conducted within the excavation should be -. under the direct supe~¢ision of a qualified person ~ho is capable of modifying the shoring or sloping system. 8. A convenient and safe means of egress shall be provided for employees working within an excavation 4-feet deep or greater. This may consist cf a stairway, ladder, or ramp located within 25 feet cf lateral travel. 9. Any employee working in the vicinity of an excavator shall not be in a position where that employee might fall into contact with. the moving pa~s of that excavator. Employees shall also be wearing a reflective west. !0. An adequate means of water drainage shall be implemented tc reduce the like!ihcod of Tan-off entering the excavation. This shall hold true durin? the rainy season. If the accumulation of wa~er ccu!d ~ose a hazard to employees, the situation should be con~r,-i~e~ prior to resumption cf operations. 11. All shoring systems shall incorporate the soil specifi- cations and conditions for that particular site. The installation of shoring systems shall be conducted in such a way that the employee is properly protected from the potential of cave-ins. Additionally, the removal of the system shall follow the same requirement. 12. If the excavation exceeds 20 feet, or if an alternative shoring, sloping, or benching system is utilized, a civil engineer currently registered in California shall prepare detailed plans showing the materials and methods to be utilized (Appendix A). 13. The detailed plans in #12 above, shall be available for inspection at the site. i4. Shoring shall be installed in accordance with Table !-6 located within Appendix B, cr as detailed in plans and specifications prepared by a State of California Registered Civil Engiheer in accordance with engineering criteria within Appendix A. Con-3/90 '~ GROUNDWATER , TECH~OLOGZ l~c. , , " DRAFT S!oDinc - a method of excavation whereby the faces of an excavation of trench are laid back to provide protection from moving ground. sDoi! - the earth material that is removed in the formation of an excavation. Strincers - the horizontal mer~ers of the shoring system whose sides bear against the uprights. Stringers are sometimes called whalers. Strut - a structural member designed to resist forces, either tensional or compressiona!. Trench - an excavation made below the surface of the ground. In general, the depth is greater than the width at the bottom, but the width of a trench at the bottom is not greater than 15 feet. Trench Shield - a protective device which shields workers from the effect of ground movement and which can be moved along as work progresses. .? UDrichts - the vertical me,ers cf the sh~ring'system. Whaler - a structural member in a horizontal or nearly horizontal position used for stiffening or securin~ other components of concrete forms, excavation-..=-~-..~~h-=e~a, cr similar temporary_ _ structures. EXCAVATION PROCEDLTR~S (also trenches, shafts and other ea~hwork) 1. Prior to beginning an excavation, the location of all underground utilities and other underground hazards shall be determined. 2. A hazard assessment shall be conducted by a .~ualified person to evaluate the potential exposure to employees who 'may work in or around the excavation. 3. The excavation shall also be inspected by a qualified person after each rain or other hazard-increasing event to evaluate the potential hazards from slides or cave-ins. 4. Anytime an employee enters an excavation 5 feet or greater in depth, that employee must be protected by a system of shoring, sloping, benching or alternative means addressed in #15 below. con-3/90 ..... ~'~ ~'~i CROU~'DWATER , . TECH~NOLOG'~: INC. Earthwork - the process of excavating, moving, storing, p!acinq, and working any type of earth materials. Excavation - a man-made cavity or depression in the earth's surface, including its' sides, walls, or faces formed by the removal of materials, and producing unsuppo~ed earth conditions by reason of such removal. If installed forms or similar structures reduce the depth-to-width relationship, the excavation may become a trench. Exploration Shaft - a shaft created and used for the purpose of obtaining subsurface data. Geotechnical SDecia!i=t (GTS~ - a person registered by the State as a Certified Engineering Geo!cgist, or a Registered Civil Engineer trained in soil mechanics, or an engineering qec!cqist or civil engineer with a minimum of 3 years applicable experience working under the direct supervision of either a Certified Engineering Geologist cr Registered civil Engineer. Hard Compact - a!L~earth material not classified as running sci!. Hvdrau!ic Shorinc - a shorin~ system using hydraulic cylinders, planks, rails, p!~-ood or steel beams to support the excavated wall of trenches. Laa~inc - boards which are joined, side-by-side, !ininq an excavation. Runninc Soil - earth material where the angle cf repose is approximately zero, as in the case of soil in a nearly !i~did state, or dry, unbacked sand ~hich flows frae!y under s!icht pressure. Running material also includes loose cr disturbed earth that can be only contained with solid sheeting. Shaft - an excavation under the earth's surface in which the depth, is much greater than its cross-sectional dimensions (such as those formed to serve as wells, cesspools, certain foundation footings, and under streets, railroads, bui!din~s, etc.). Shore - a supporting member that resists a compressive force imposed by a load. Shorin~ System - a temporary structure for the support of earth surfaces formed as a result of excavation work. Sides, Walls, and Faces - the vertical or inclined earth surfaces formed as a result of excavation work. con-3/90 '[~ GROUNDWAT£R , T£CH.h'OLOG~: l.~c. GROUNDWATER TECHNOLOGY, INC. EXCAVATION AND TRF, NCEING POLICY - C~r.TFORNIA SAFE CODE OF PRACTICES Although many of the rules and regulations pertaining to excavation and trenching operations in the State of California -- closely parallel Federal Standards, this policy specifically pertains to California operations. It shall be the policy cf Groundwater Technology, Inc. to ensure that all Groundwater Technology employees and sub- contractors comply with the provisions within the California Code of Regulations, Title 8, Chapter a,. Subchapter = ~ - Construction Safety Orders. It is inevitable that~=_-m-liation.=~ .procedures. for which Groundwater Technology is retained will invc!ve some aspecu within the jurisdiction of the Construction Safety Orders. Such operations may include: ~-- ~- . . t_=~c~_~g, vault construction, tank removal, and excavation of contaminated soils. DEFINITIONS - EXCAVATION, TRENC5.~S, EARTHWORK Bank - a mass of soil rising above a digging level. Bell Hole - an additional excavation made into the sides cr bottom of a trench to provide additional work space. Belled Excavation - a part of a shaft or footing excavation, usually near the bottom and bell-shaped, that makes the cross- sectional area at that point larger than that above. Benchinc - a method of excavation whereby the faces of an excavation or trench are widened progressively outward with respect to the bottom of a specific series ef horizontal and vertical cuts to provide protection against the hazard of moving ground. Braces for Excavations - the horizontal members of the shoring system, the ends of which bear against the uprights or stringers. Con-3/90 '~ GROUNDWATER , TECH~OLOG~ l~c. APPENDIX H (Excavation/Trenching) ~t---~t--~l'l¥~mOL~V, L~ TECI,-INOLOGY, INC. DA'Il! O17 SAMPLING CONTAMINANTS RESULTS OF VAPOR MONITORING ' · IONIZATION DE'fECTOIt EXPLOSIMEq'EFI FIADIATION READING READING MONI'[Oi'I TIME RE^DING LOCATION PURPOSE INIIIAL FID 10.2oV PID 11.7oV PID °/°LEk %O~ mR/hr APPENDIX G (Vapor Monitoring Sheet Form) ~ t.._..l~ ~J TECliNOLOGY, INC. Acoident/In¢ident/Near Miss Report ~' Employee's Name: D.O.B. Address: D.O.H. SS# Job Title: Supervisors's Name: office Location: Location at Time of Incident: -.Date/Time of Incident: Description: Describe clearly how the accident occurred: Was Incident: Physical Chemical Part(s) of body affected: Exposure: Dermal right left Inhalation Ingestion Witnesses: 1) 2) Conditions/acts contributing to this incident: Explain specifically the corrective action you have taken to prevent a recurrence: Did the injured go to a doctor? Where? When? Did injured go to a hospital? Where? When? Signatures: Employee Reporting Manager Regional H&S Manager Date Date Date This form must be completed and returned within 5_ working days to Regional Health & Safety Manager, who wi[[ forward a copy to Corporate Health & Safety Manager at ELD. APPENDIX F (Accident Investigation Form) NO · 667 SECTION VI, HEALTH HAZARD INFORMATIONJ TLV 300 ppm (See Sect. hnhaiation causes intense burning of the mucous membranes, throat and resoirato'rv 'tract; / overexposure to vapors can lead.to bron?hopn~umppia, ltlhalation of hiRh co~c.. / fatal pulmonary edema. Repeate~ or proionge~ skin exposure_causes ~ermat~t~s. ! cause blistering of skin due to its dele=ting propertles. ~xposure ~o eyes can cause ! hype~mia of the conjunctive. . ....... ~nEestion or excessive vapors can cause inebriation, arowslneSs, oiurrea v~s~on, vertigo J confusion, vomiting and cyanosis (2000 ppm produces mild anesthesia in 30 mia, higher / cont. are intoxicating in less time.) Aspiration after ingestion causes bronchitis, J pneumonia, or edema ~hich can be fecal. · .. IFIRST AID: Eye Contact: Flush thoroughly with running water for 15 min. inclu~ing under eyelids. Skin Contact: Remove contaminated clothing.' Wash affected area with soap and water. Inhalation: Remove to fresh air. Restore breathing and administer oxygen if needed. ~n~estion: Do not induce vomiting. Aspiration hazard. Contact physician. Seek prompt medical assistance for further treatment, observation and support.' SECTION VII, SPILL, LEAK, AND DISPOSAL PROCEDURES Notify safety personnel of leaks or spills. Remove sources of heat or ignition. Pro- vide adequate ventilation. Clean-up personnel require protection a§ainst liquid con- tac~ and vapor inhalation. If a leak or spill has not ignited, use water spray to disperse vapors and to protect men attempting to stop the leakage. C¢%ntain spill. Do nog allow to enter sewer or surface water. Add absorbent solid to small spills or residues and pick up for disposal. DISPOSAL: Burn scrap material in an approved incinerator. Burn contaminated liquid by spraying into an incinerator. Follow Fed'eral, State, and Local regulations. SECTION VIII, SPECIAL PROTECTION INFORMATION Use general and local exhaust ventilation (~x?!psion-proof) to keep vapors betew requirements in the workplace. Respirators should be available for nonroutine or emergency use above the TLV. Avoid eye contact by use of chemical safety goggles and/or full faceshield where splash- ing is possible. Wear pro~ective clothing appropriate for the work situation to minimize skin co,tact such as rubber gloves and boots. Clo:hing to be changed daily and laundered. Eyewash fountains, showers and washing facilities should be readily accessible Provide suitable training ~o ckose handling and working with this material. SECTION IX, SPECIAL PRECAUTIONS AND COMMENTS Store in closed containers in a cool, dry, well-ventilated area away from sources of heat, ignition and strong oxidizing agents. Protect containers from physical damage. Avoid direct sunlight. Storage must meet requirements of OS,U_~ Class IA liquid. Outdoor or detached storage preferred. No smoking in areas of use. Prevent static electric sparks and use explosion-proof electrical scrvices. (Must meet code.) Avoid skin a,d eye contact. Avoid inhalacion of vapors. Wear clean work clothing dail) Indoor use of this material requJrcs exhaust ventilation to remove vapors. ICC Flammable Liquid, Red Label. ]ABEL: Flammable Liquid ~T I.D. No. UN 1203. DOT Classification: ~L~L[ LZOU[D ~f MISc~D ~,'~- ~.~ .... , ..... ',,~ .................. Industrial Hygiene "'"'" · ~ ~ '~-- ............. ~.,., ~ .... -~,~ ~ .... · ........ and Safety : :~' I MEDICAL REVIEW: ~a November 1981 GENIUM PUBLISHING No, ~67 '.; :~ : ~ AUTOMOTIVE ~ . GENIUM PUBLISHING CORPORATION GASOLINE, LEAD-FREE 1145 CATALYN STREET ~'[] SCHENECTADY. NY12303.1836USA (518) 377-8855 'GENIUM~SNINGCOeP. Date October 1981 SECTION I, HATERIAL IDENTIFICATION MATERIAL N~ME: AUTOMOTIVE GASOLINE, LEAD-FREE DESCRIPTION: A volatile blend of hydrocarbons for automotive fuel OTHER DESIGNATIONS: Petrol, CAS #008 006 619, ASTM D439 MANUFACTURER: Available from several suppliers. SECTION II, INGREDIENTS AND HAZARDS x HAZARD DATA Gasoline 100 8-hr TWA 3~0 ppm or A hydrocarbon blend that can include normal and branched 900 mg/m~* chain alkanes, cycloalkanes, alkenes, aromatics and other additives.** '(Lead max 0.013 g/L, phosphorus Man max 0.0013 g/L, sulfur max 0.10 w;,.. May contain Eye: 500 ppm/1H benzene, <5%; see ASTM D3606). Moderate irritation *ACGIH 1981TLV (Intended Changes List). See also Am. Ind. H¥~. A. 39 110-117 (1978) Inhalation: **The composition of fuel is varied with altitude and TCLo 900 ppm/1H seasonal requirements for a locality. The blend must TFX:CNS meet antiknock requirements. (Antiknock Index min 85, ASTM D439.) '.,~ .... SECTION llI, PHYSICAL DATA : Distillation at [ arm, Initial, deB C >39 Specific gravity, 60/60 F - 0.72-0.76 :' 50% distilled - 77-121 Melting point, deg C ....... 90.5-95.4 End point ..... <240 Evaporation rate ......... N/A Vapor density (Air=l) 3.0-4.0 Solubility in water Insoluble Appearance and Odor: A clear, mobile liquid with a characteristic odor which can be recognized at about 10 ppm in air. (Gasoline may be colored with dye.) SECTION IV, FIRE AND EXPLOSION DATA LOWER UPPER '~lash Point and Method [ Autot~nttton Temo. Flammability Limits In Air -45 F 536-853 F ' % by volume 1.4 7.6 I Extinguishing Media: Dry chemical, carbon dioxide, alcohol foam. Use of water may be ineffective to extinguish fire, but use water spray for cooling fire-exposed, drums and tanks to prevent pressure rupture. It is a dangerous fire and explosion hazard when exposed to heat and flames. Vapors can flow along surfaces, reach distant igni- tion sources and flash back. Can react violently with oxidizing agents. Firefighters should wear self-contained breathing apparatus and full protective clothing SECTION V. REACTIVITY DATA This is a stable material in closed containers at room temperature under normal storage and handling conditions. It does not undergo hazardous pol)~erization. This is an OS~ Class IA flammable liquid. A mixture of gasoline vapors and air can be explosive. It is incompatible with oxidizing agents. Thermal-oxidative degradation can yield carbon monoxide and partially oxidized hydrocarbons. ' I c~,,-~, ~ ,~ ~--~ c,-s,,~ GENIUM PUBLISHING No. 385 SECTION VI, HEALTH HAZARD INFORMATION I ?Lv lO0 Excessive exposure Co vapors will irritate the eyes and nn~cous mer, hranes of the upper respiratory tract. Sustained high levels can produce headache, depression of the central nervous system, narcosis and coma. Liquid contact is irritatiSg to the eyes and irritation and defa~ting to the skin, leading to dermatitis on prolonged or repeated exposures. Ingestion may lead to aspiration of liquid into the lungs small amounts of aspirated ethyl benzene cause extensive edema and hemorrhage of lung tissue. FIRST AID~ Eye contact: Wash eyes well with plenty of running water, Get medical help if irritation persists. Skin contact: Wash exposed areas of skin. Pro:..-ptly remove con.'a~.-~inated clothing. Inhalation: Remove victim to fresh air. Zes:ore breathing if necessary. Get medical help for serious exposure. Infest. ion: Ge." prompt medical help'. (The danger of aspirating ethyl benzene into the lungs indicates medical direction before inducing vomiting.) SECTION vii. SPILL, LEAK, AND DISPOSAL PROCEDURES Personnel involved in leak or spill control and clean-up must use protective equip- ment to avoid inhalation of vapors and concact with liquid. Eliminate ignition sources, Provide maximum explosion-pr¢of venrilatlon. Pick-up spilled material for recovery or disposal. Absorb wich sand, etc. for dis- posal in a sanitary landfill or with paper towels or cloths for burning. Water can be used to flush liquid away from sensitive areas to special cacch basins or ground, but not to sewer or surface water, DISPOSAL: Scrap ~'aterial can be burned in approved incinerators in accordance with Federal, State and local regula:icns. SECTION VIII. SPEC[AL P~OTECTION INFO.-'i.HATION Provide expolosion-proof general and local exhaust ventilation to meet TLV require- ments. Approved respirators must be avaiiab!e for non-routine or emergency use. A full face respirator with organic vapor cartridge can be used up to 1000 ppm; a gas mask with organic vapor canister can be used up to 5000 p?.. a self-contained respirator is needed for high and unknc'-~, concentrations of vapor. Use impervious gloves and clothing and a face shield to prevent repeated or prolor, g~. contact with the liquid, Vaere splashing is possible chemical goggles should be used. Clothing contaminated with ethyl benzene should be pronpr!y removed and not reused until free of the cont~v, inanc. Exposures above the action level, liquid contact, or Jorking ~.e.-e fire and explosic hazards exist may require instituting employee training, medical surveillance, vapor concentration monitoring, record keeping, etc. ~i~en the proposed standarJ issues, SECTION IX. SPECIAL PRECAUTIONS AND COMMENTS Store this material in rightly closed containers in cool, weli-ventilace~ areas, away from oxidizing agents, heat and sources of ignition, Use non-sparking tools around this material. Containers must be electrically bonded and grounded for transfers of liquid. Use safety cans for s=zl! amounts. No Szx~king: where this material is stored or used. .. J Screen workers for history of kidney, liver, skin and lung pro~,_e.--s which could £iv ] increased sensitivity and risk in ethyl benzene exposure. Avoid breathing of vapors and contact with licuid.~ Do not inRes:. Chronic proper-! ties ara not fully kno~,~; use with care. GE,¥1UM PUBLI.~HING 385 No. ETHYl. BE~Z ENE GFNIUM PLIt~LISItiNG 1145 CA[ALYN SI~IEET SCHENECTADY. NY 12303-183~ USA (518) 377-8855 G~N~U~PUIUSm~CO~ Date August 1978 SECTION ~, HATERIAL IDENTIFICATION ~TERIAL N~: ET~L BENZ~E OTHER DESIGNATIONS: Phenylethane, E~hylbenzol, C2HBC6HB, CAS~ 000 100 ~!4 ~NUFACTURER: Available from several suppliers. SECTION II. INGREDIENTS AND HAZARDS ~ I'~AZA~..D DATA Ethyl Benzene ca 100 8-hr · Current OSHA pe~issable exposure level. A Standard Human, inhalauion was proposed by 0S~t in October 1975 which includes TCLo 100 ppm for an action level of 50 ppm, and detailed requirements 8 hr (irritation) of monitoring, medical surveillance, employee train- Rat, Oral LDB0 lng, etc.; when e~osure exceeds 50 ppm. It has not 35~ mg/kg vet issued as a legal reeuiremen:. SECTION III, PHYSICAL DATA "... Boiling point at I arm, deg C -- 136 Specific gravity 20/4C 0.~67 Vapor pressure at 25.9 C, mm Hg - 10 Volatiles. % ca 100 Vapor density (Air=l) 3.66 Evaporation rate (BuAc=l) <1 Water solubility at 20 C Wt. % - 0.0!5 Melting point, deg C -95 Molecular weigh: 106.16 Appearance & Odor: Clear, colorless liquid with an aroratic hydrocarbon odor. SECTION IV. FIRE AND EXPLOSION DATA ILO~i~ 59 F (15 C) (closed cup] 810 F (432 C) Volume % I.Cl 6.7 Extinguishing media: Carbon dioxide, dry chemical or "alcohol" foam. A w~.teP spray may be ineffective to put out fire, but may be used to cool fire-e~sa8 container A stream' of water can spread fire of burning liquid. This is a'flammable liquid (OSHA Class lB) which can readily fo~m e~losive mixtures with air, especially when heated. Heavier-than-air va=ors can flow along surfaces to reach distant ignition sources, a=d then flash back'. Firefighters should use self-contained breathing equipmen~ amd eye protection to fight [ires in enclosed. places. SECTION V, REACTIVITY DATA This material is stable in storage in closed containers at room temperature. It does not polymerize. This flan~able material should be kept separated from oxidizing agents, s:r:ng acid: and bases and ammonia. Thermal-oxidative degradation cam produce toxic products, including carbon monoxide. Xylene is not listed as a carcinogen by the IARC, NTP, or OSHA. Summary of Risks: Liquid xylene is a skin irritant and causes erythema, dryness, and defatting; prolonged contact may cause blistering. Inhaling xylene can depress the central nervous system (CNS), and ingesting it ca,n,.result in gastrointestinal disturbance; and .;'.-.. possibly hematemesis (vomiting blood), Effects on the eyes, kidneys, liver, lungs, and the CNS am also reported. Medical Conditions ':-' '"-';-' A oravated by Lon -Term Ex osure' Problems with eves, skin, central nervous system, kidneys, and liver may be worsened b ?."-.'-i..-' g,, g P · . -. .. . . Y exposure to xyle~e. Target Organs: CNS, eyes, gastrointestinal tract, blood, liver, kidneys, skin. Primary Entry: Inhalation, ....... skin contact/absorption. Acute Effects: Dizziness; excitement; drowsiness; incoordination; staggering gait; irt/tan'on of eyes, nose, and throat; corneal vacuolization; anorexia; nausea; vomiting; abdominal pain; and dermatitis. Chronic Effects: Reversible eye damage, headache, loss of appetite, nervousness, pale skin, and skin rash. FIRST AID: Eyes. Immediately flush eyes, including under the eyelids, gently but thoroughly with plenty of running water for at least 1:5 minutes. Skin. Immediately wash the affected area ~ith soap and water. Inhalation. Remove the exposed person to fresh air; restore and/or support his or her breathing as needed. Have a trained person administer oxygen. Ingestion. Never give anything by mouth to someone who is unconscious or convulsing. Vomiting may occur spontaneously, but do not induce it. If vomiting should occur, keep exposed person's head below his or her hips to prevent aspiration (breathing the liquid xylene into the lungs). Severe hemorrhagic pneumonitis with grave, possibly fatal, pulmonary, injury can occur aspiring very quantities of xylene. from small GET MEDICAL HELP (IN PLANT, PARAMEDIC, COMMUNITY) FOR ALL EXPOSURES. Seek prompt medical assistance for further treatment, observation, and support after first aid. If exposure is severe, hospitilization for at least 72 hours with careful monitoring for delayed onset of pulmonary edema is recommended. Spill/Leak: Notify safety personnel, provide ventilation, and eliminate all sources of ignition immediately. Cleanup personnel need protection against contact with and inhalation of xylene vapor (s~ sect. 8). Contain large spLUs and collect waste or absorb it with an ine:~ material such as sand, earth, or vermiculite. Use nousparking tools to place waste liquid or absorbent into closable coumLue,-~ for disposal. Keep waste out of sewers, watersheds, and waterways. Waste D isposah Contact your supplier or a licensed contr~tor for detailed recommendations. Follow Federal, state, and local regulations. OSHA Designations Ah' Contaminant (29 CFR 1910.1030 Subpart Z) EPA Designations (40 CFR 302.4) RCRA Hazardous Waste, No. U239 CERCLA Hazardous Substance, Reportable Quantity: 10OO lbs G$4 kg), per the Clean Water Act (CWA), section 311 (b) (9) Goggles: Always wear protective eyeglasses or chemical safeD' goggles. Where splashing is possible, wear a full face shield as a iupplementary protective measure. Follow OSHA eye- and face-protection regulations (29 CFR 1910.133). Respirator: Usc a NIOSH- _.. approved respirator per the NIOSH Pock. et Guide to Ch~rnica! Hc.z~ds for the maximum-usc concentrations and/or the exposure limits ;ired in sectiou 2. Follow OSHA respirator regulations (29 CFR 19 t0.13.1). For emergency or nonroutine use (leaks or cie.ming reactor vessels and storage tanks), wear an SCBA with a full facepiece cpera'.ed in the pressure-demaed or positive-pressure mode. Warning: Air- ourffying respkators will not protect workers in oxygen-deficient atmospheres. Other: Wear im?ervlous gloves, boots, a?rons, gauntlet, :lc., as required by the specifics of the work operation to prevent vrolon~ed or repeated skin contact with xylene. Ventilation: Install ..nd operate general and local maximum, explosion-proof retailer!on sys~terns powerful enough to maintain airborne levels of xylene Ixlow thc OSHA PEL standard cited in section 2. Local exhaust ven~afion is preferred because it prevents dispersion of xvlene into general work areas by eliminating it at its source. Consult the least edition of Genium reference 103 for detailed recorn~e'ndations. ~afety Stations: Make eyewash stations, safeqt/quick-dre:ch showers, and washing facilities available in areas of use and handling. .~ontaminated Equipment: Contact lenses pose a special haz,_rd; soft lenses may absorb fir/tents and all lenses concertware them. Do ,.or wear contact lenses in any work area. Remove contaminatexl cloth/ng and launder it before wearing it again; clean xylene from shoes and equipment. Comments: Practice good personal hygiene; always wash thoroughly after using this material. Keep it off of your olothing and equipment. Avoid transferring it from your hands to your mouth while eating, drinking, or smoking. Do not eat, drink, or .'noke in any work area. Do not inhale xylene vapor. :torage/Segregation: Store xylene in a cool, dry, well-ventilated area away from sources of ignition and strong oxidizers. Protect ontainers from physical damage. epeciai Handling/Storage: Make sure all engineering systems (production, ~ansportation) are of maximum explosion-proof design. ;round and bond all containers, pipelines, e~c., used in shipping, transferring, reacting, producing, and sampling operations. Transportation Data (49 CFR 17:2.101-2) OT Shipping Name: Xylene DOT Label: Flammable Liquid IMO Label: Flammable Liquid OT ID No. UN1307 DOT Hazard Class: Flammable Liquki IMO Class: 3.2or33 _.:ferences: 1, 2, 12, 73, g4-94, IIX), 103. Judgments as to the sui/ability of i~formaUon herei,~ forputchaser's purposes a,.~ ! Prepared by PJ Io. oe, BS necessarily purc.~aser's real:runs/b/lily. The..~fo,.~, all.hough reasonable care has ~ bccntakcninth~p."e.~'aarationofsuchinformation, C, cniumPublishingCo~. I Industrial Hygiene Review: DJ Wilson, CIH extends no warranties, n-..ak~s no repruscn[atio~ and assumes no responsibility a.s to 0lo accuracy or mi[ability of such infom-,alion for application to [ Medical Review: Hard/es, MD purchasers intended purposes or for conseque~Ices of its use. J~i ~,',~g~ ~ 19~ Geni~m l~Mi.~ C~por~fioa. safety D .ta Sheet No. 18 From Genium's Reference O~ction XYLENE (Mixed Isomers) Genium Publishing Corporation (Revision D) 1145 Catalyn Street Schenectady, NY 12303-1836 USA Issued:' November 1980 (518) 377-8855 GENIUM PUBLISHING CORP. Revised: August 1988 · S E C .T I O N '1 ;~:::;M A T E R I A L'*~' I D E N T I F I C A T I O N '~;:?:::'~'~'???:%11~5.......:-.. ::~ ~:::!;;ili~.i:.ii:~!?~!i!~.ii~ii:i!!ii!!ii: ;?...;:~ ~:-;'?~.~- --;.'-:: .~?::. · .. · · ;!2 6 Material Name: XYLENE (Mixed Isomers) Description (Origin/Uses): Used as a raw material for the production of benzoic acid, phthalic anhydride, isophthalic and terephthalic acids and their dimethyl esters in the manufacture of polyester fibers; in sterilizing catgut; with · Canadian balsam as oil-immersion in microscopy; and as a cleaning agent in microscopic techniques. Other Designations: Dimethylbenzene; Xylol; C,H,o; CAS No. 1330-20-7 NFPA Manufacturer: Contact your supplier or distributor. Consult the latest edition of the Cl~micalweek HMIS Buyers' Guide (Genium ref. 73) for a list of suppliers. H 2 R 1 Comments: Although there are three different isomers of xylene (ortho, mete, and para), the health and physical F 3 hazards of all three isomers are very similar. This MSDS is ~tten for a xylene mixture of all three isomers, R 0 I 3 which is usually commercial xylene. PPG* $ 2 · Sec sect. 8 K 3 · SECTION 2YlNGREDIENTS AND HAZARDS -:'::'&: [ . % ! .':i::":.i;ii!'EXPOSURE LhMITS ' Xylen¢ (Mixed Isomers), CAS No. 1330-20-7' ** IDLH"' Level: 1000 ppm · o-Xylene, CAS No. 0095-47-6 OSHA PEL m-Xylene, CAS No. 0108-38-3 8-Hr TWA: 100 ppm, 435 mg/m~ p-Xylene, CAS No. 0106-42-3 ACGIH TLVs, 1987-88 "Check with your supplier to determine if there are additions, contaminants, or TLV-TWA: 100 ppm, 435 mg/m~ ' impurities (such as benzene) that are present in reportable quantities per TLV-STEL: 150 ppm, 655 mgtm~ 29 CFR 1910. · "Immediately dangerous to life and health. Toxicity Data .... Human, Inhalation, TC,$ 2(30 gpm · *** See NIOSH, RTECS (No. ZE2100~0), for additional data with references Man, Inhalation, LCt.,: 10000 ppm,'6 I-~ to reproductive, k, Titative, and mutagenic effects. Rat, Oral, LDm: 4300 rog/kg 'SECTION 3.:PHYSICAL DATA ' Boiling Point: 275'F to 29YF (135'C to 145'C)* Water Solubility (%): Insoluble Melting Point: -lYF (-25'C} Molecular Weight: 1135 Grams/Mole Evaporation Rate: 0.6 Relative to BuAc = 1 % Volatile by Volume: Ca 100 Specific Gravity (HaO = 1): 0.86 Vapor Pressure: 7 to 9 Torts at 68'F (20'C) Vapor Density (Air = 1): 3.7 Appearance and Odor: A clear liquid; aromatic hydrccarbon odor. · Materials with wider and narrower baiting ranges are commercially available. 'SECTION 4.:FIRE AND XPLOSION D TA : :.' :'. LOWER -UPPER Flash Point and Method Autoi...nition Temperature / Flammability Limits 8 I'F to 90'F (27'C to 32'C) $67'F (464'C) [ % by Volume I% 7% Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Use water sprays to reduce the rate of burning and to cool con~ners. Unusual Fire or Explosion Hazards: Xylene vapor is heavier than air and may tzavd a considerable distance to a low-lying source of ignition and flash back. Special Fire-fighting Procedures: Wear a self-contai~ed breathing apparatus (SCBA) with a full facepiece operated in the pressu:'e- demand or positive-pressure mode. SECTION 5. REACTIVITY DATA '. :'::"'":"' '~" Xylene is stable in closed containers during routine operations. It does not undergo hazar~o=s polymerization. Chemical Incompatibilities: This material may react dangerously with strong oxidiz¢,~. I Conditions to Avoid: Avoid any exposure to sources of ignition and to strong oxidizers. Hazardous Products of Decomposition: Carbon monoxide (CO) may be evolved du,5ng xylene fires. tract, m3d ~Id. Expcs'um ~ 200 gpm f~r 8 hours caams mlkl faxigu=, ..,