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HomeMy WebLinkAboutBUSINESS PLAN STATEMENT OF ACCOUNT CITY OF BAKERSFIELD 1501TRUXTUN AVE BAKERSFIELD, CA 93301-0000 (805~ 32&-397~ DATE: 2/01/97 TO: BRUNDA~E CAR WASH CLARK K KiM 6273 JAQUAR DR RIVERSIDE, CA 92506 CUSTOMER NO: 3880 CUSTOMER TYPE: ES/ 3880 CHARQE DATE DESCRIPTION REF-NUMBER DUE DATE TOTAL AMOUNT 1/01/97 BEQINNING BALANCE 6&.O0 UTOOi 2/0i/97 ADMiN SERVICE FEE 6.66 PNOii THiS UNIFIED BiLL REPLACES SEPERATE BILLS RECEIVED IN THE PAST FOR THESE PROGRAMS. UTOOi 2/0i/97 FINANCE CHARGE FCOll THIS UNIFIED BILL REPLACES SEPERATE BILLS RECEIVED IN THE PAST FOR THESE PROQRAMS. FOR QUESTIONS OR CHANGES TO YOUR ACCOUNT PLEASE CALL THE NUMBER AT THE TOP OF THIS STATEMENT. CURRENT OVER 30 OVER 60 OVER 90 7~3~ ....... &&.~-~O DUE DATE: 2/03/97 PAYMENT DUE: 73.32 TOTAL DUE: $73.32 PLEASE DETACH AND SEND THIS COPY WITH REMITTANCE .~.~~.~ DATE: 2/01/97 DUE DATE: 2/03/97 REMIT AND MAKE CHECK PAYABLE TO: CITY OF BAKERSFIELD P.O. BOX 2057 BAKERSFIELD CA 93303-2057 CUSTOMER NO: 3880 CUSTOMER TYPE: ES/ 3880 TOTAL DUE: $73.32 ITE DIAGRAM [ZZZZ3. FACILITY DIAGRAM Business Nome: Business Address: c:~----~,',~ FOr Office Use Only ~/'~ First In Station: Area Map # of Inspection Station: ~ ~-"/'%~ SI TE/~:'ACI LI T¥ D I AGR-~ ~~ NORTH SCALE: BUSINESS NAME: ~~¢& ~r W~,k FLOOR: I OF ~ (CHECK ONE) SITE DIAGR~ ¢ FACILI~ DIAGR.~ l(Inspector's Comments): -OFFICIAL USE ONLY- - SA - SITE DIAGRAM (Required items) 1. Address: Identify the 9. Lock (key) Box principle buildings by the Street numbers. 10. MSDS Storage 2. Street(s), Alleys, 11. Railroed Tracks Driveways, and Parking Areas adjacent to the 12. Fence or Barrier property. Include the a. Wire street names. b. Masonry 3. Storm Drains. Culverts, Yard Drains c. Wood 4. Drainage canals, Ditches, d. Gates Creeks, 13. Powerllnes S. Buildings a. Frame construction 14. Guard Station b. Masonry construction 15. Storage Tanks: Identify the c. Metal construction capacity in gal. a. Above ground d. Access Door .... b. Underground 6. Utility Controls a. Gas 16. Diking or Berm b. Electricity 17. Evacuation Route c. Water 18. Evacuation Area: Identify the Fire Suppression Systems: location where a. Fire Hydrants employees will meet. b. Fire Sprinkler 19. Outside Hazardous Connections Waste Storage c. Fire Standpipe 20. Outside Hazardous Connections Material Storage d. Water Control Valves 21. Outside Hazardous for protection systems Material Use/Handling e. Fire Pump 22. Type of Hazardous Material/Waste Stored 8. Fire Department Access or Used (See Below) TYPE OF EAZAROOUS MATERIAL F = Flammable E .= Explosive L = Liquid R = Radlologlcal ¢ - Corrosive 0 = OXidiZer O ~ Gag-- - Water Reactive T - Toxic S = Solid H = Cryogenic O = Waste B - Etiological Example: Flammable Liquid = FL FACILITY DIAOiLaaq (Required Items In addition to the. abo~®) 1. Risers for Sprinklers 8, Fire Escapes Partitions 9. Air Conditioning Units 3. Stairways: Indicate the 10, Windows levels served from highest to lowest. 12. Inside Hazardous Waste Storage 4. Escalator: Indicate the levels served from 12, Inside Hazardous highest to lowest. Materials Storage 5. Elevator 13. Inside Hazardous Materials Use/Handling B. Attic Access 14,'Sewer Drain Inlets 7, Skylights Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE This hermit is issued for the followina: ;n Hazardous Materials Plan [3 Underground Storage of Hazardous Materials Permit ID #:: 015-000-001034 [3 Risk Management Program BRUNDAGE CAR WASH [3 Hazardous Waste On-Site Treatment LOCATION: 2523 BRUNDAGE LN ~,~ ~' ~-?' IELD OFFICE OF EN~R ONMENTAL SER VICES 1715 Chester Ave., 3rd Floor Approved by: Bakersfield, CA 93301 off~~~~i~, Issue r Voice (661) 326-3979 F~ (661) 326-0576 Expi~tionDate: ., -: CUST TYPE & NO. ~___'"--,_~ ~IISCELI.~NEOUS RECEIVABLES ADJUSTMENT DATE I -'z:~(~-~'/ 'NEWACCOUNT ADDRESS CHANGE CLOSE ACCT 'FINANCE CHARGE I/k/ OTHER ADJ CUSTOMER NAME ~-'~J~-©F~O~C~'~ L~r'- (J~-~,~-~___~/Qr'/::: /~' ~r~ MAILING ADDRESS / ~ ~ ~/~ ~f~ CI~ ~ z~rs,'d~ STATE P~ ZIP CODE ~%-~¢¥~' SITE ADDRESS ~ ~ ~c ~~C ~ P~CEL NUMBER (IF APPLICAB~ '. ADJUSTMENT I CHG DATE CHARGE CODE ADJUSTMENT AMOUNT ~IMpORTANT MES AGE~ DATE , . : AR~ OOOE~ NUMBER ~ENSION CAME TO S[E YOU WILL CALL AGAIN WANTS TO SEE YOU RUSH R~URNED YOUR CALL SPECIAL A~ENTION A=count Number ACCOUNTS RECEIVABLE ADJUSTMENT · May 10, 1994 Date New Ac=aunt New Addre~ F.~ther Duren Close Account From Service Chan.qe Other Adjustments X Fire Department- Hazardous Materials Division Department/Division BRUNDAGE CAR WASH Billing Name 2523 BRUNDAGE LN Billing Address Site Address Pamel # (If Applicable) Landlord Name & Address (If Appiicable) ADJUSTMENT Last Billed Correct Billing Adjustment to Effective Date of Billing Change <8.76> 5-1-94 Ap rov ey: '-' Remarks: THEY PAID AFTER THE ABOVE FINANCE CHARGES ACCRUED. SINCE THE BUSINESS IS CURRENTLY CLOSED WE WILL WRITE OFF THESE CHARGES. Page: 1 Account Billing/Collection Activity Inquiry SUTL108 Acct : 770401 Cyc St CL Bill St: NO Cyc: 6 Rt: i Seq: SSN : .Parcel: .... Svc Cls :e Name : BRUNDAGE CAR WASH Svc Add: 2523 BRUNDAGE LN Amt due: 8.76 Current Period Postings Lst Pmt: -66.00 Type Desc Date Amount Receipt # Pmt Dte: 04/04/94 B91 PENALTY 03/01/94 6.60 -- Prior Bills -- B92 FINANCE CHARGE 03/01/94 1.33 Date Balance B92 FINANCE CHARGE 04/01/94 0.74 01/01/94 0.00 99 PAYMENT 04/04/94 -66.00 86802 01/01/93 0.00 B92 FINANCE CHARGE 05/01/94 0.09 'D' For Detail Page, or 'P' To Print Report, Enter '/' For Billing History, '/C' For Credit and Deposit History or 'XX' To Exit O Bake~x~sfield Fire Dept. HAZARDOUS MATERIALS DIVISION Date Completed Business Name: ~.,~u^lZ)A.d~F_. . . ~& /,4.)~/~ Location: ~ ~5'Z ,~ J-~/2~"v'~"t-G'/=-'--/c""/' Business Identification No. 215-000 OO/o ~ ~ (Top of Business Plan) Station No. ~ Shift ~ Inspector Ade~ Inadequate Verification of InYentorg Materials ._~? Verification of Ouantities ~ Proper Segregation of Material Comments:, f'~"7'~ ~'~Verificati°n °f MSDS Availabli~~"'-' ;Number~_.' of' Employees-/'''~ J~~/...,______._~~~/ Verification of Has Mat Training Comments: Verification of Abatement Supplies & Procedures ~/ Comments: / Emergency Procedures Posted I~"/ Containers Properly Labeled ~/ Comments: Verification of Facility Diagram Special Hazards Associated with this Facility: Violations: Correction Needed BuSine~ne~i~er- - FD 1652 (Rev. 1-90) White-Has Mat Div. Yellow.Station Copy Pink-Business Copy / ~, k ~ Hazardous MaterialsDivision HAZARDOUS MATERIALS MANAGEMENT PLAN 2. ~P~/P~IXT ANSWERS IN 3. Answer the questions below for the business as a whole. 4. Be brief and concise as po~ible. / SECTION 1: BUSINESS IDENTIFICATION DATA BUSINESS NAME: ~ R t) ~} DA ~ ~ R  CITY: ~Zf~,~¢~[.LO STATE: ~ ZIP: DUN & BRADSTREET NUMBER' SIC CODE: PRIMARY ACTIVITY: ~F ~)~,SJ ~ Z,~¢ OWNER' .~.~O~ MAILING ADDRESS: ~~ 3¢D~5¢¢ SECTIO~ 2: E~ER~CY ~OIIFICATIO~: CONTACT TITLE BUS, PHONE 24 HR, PHONE 2. Bakersfield Fire Dept. Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 3: TRAINING: NUMBER OF EMPLOYEES: MATERIAL SAFETY DATA SHEETS ON FILE: .~. · BRIEF SUMMARY OF TRAINING PROGRAM' SECTION 4: EXEMPTION REQUEST:' REPORTrN.G.~EQUIREMENTS OF CHAPTER 6,95 OF THE "CA~.~A HEALTH & .SAFETY CODE~O~~OLLOWING REA~ ' __ WE DO HA~I.DEE HAZAT'd~O,~S MATERIALs, BUT THE .QUANTITIES AT NO I, . q'~'?/)~' CERTIFY THAT THE ABOVE INFOR- MATION IS ACC~RATEi~ ' I UNDERSTAND THAT THIS INI~ORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIV. 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT INACCURATE INFORMATION CONSTITUTES PERJURY. ...... _SJG _.{'~._ REd TITLE DATE FD1590 Bakersfield Fire De . Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN Facility Unit Name: ~7.~-~~,_ ~~x_~.~ SECTION 6: NOTIFICATION AND EVACUATION PROCEDURES: A. AGENCY NOTIFICATION PROCEDURES' B.. EMPLOYEE NOTIFICATION AND EVACUATION: C. PUBLIC EVACUATION: D. EMERGENCY MEDICAL PLAN: Bakersfield Fire De Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 7: MITIGATION, PREVENTION AND ABATEMENT 'PLAN: A. RELEASE PR~EVENTION STEPS: B. ~ELEASE OONTAINMENT AND/O~ MINIMIZATION: C. CLEAN-UP PROCEDURES: - SECTION 8: UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FACILITY)' NATURAL GAS/PROPANE: ELECTRICAL: & (J~Ci' I / LOCK BOX: YES,~--~ IF YES, LOCATION: SECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABILITY: A, PRIVATE FIRE PROTECTION: B. WATER AVAILABILITY (FIRE HYDRANT): CITY OF B/~KERSF I ELD HAZARDOUS MATERIALS II~'ENT~RY ~ Fa~ and Agriculture ~ Standard Business Page of~ ~ NON - ~E SEC~T LOCATION: ~%~-~mn~~ . - ~D~SS: ['~Jb' ~9~ ~-~$~ · ST~ IND. C~SS CODE: CITY, ZIP: [~ ~ ~O~ ' CITY, ZIP: ~ ~;'I3~ - O-g~ DUN ~D B~ST~ET N~BER/FEDE~ ID ..ON 7 3/' - - - ~ 2 3 4 5 6 7 8 9 10 ~1 ~2 13 14 ~ ~e ~ Average ~nual Heasure ~ Days Cont Cont Cont Use Location Where ~ by N~s of ~ture~Com~nents  Co~onent ~ 2 N~ & C.A.S. N~er of Pressure H~lth H~lth Component $ , , ,bye,ua, and ,.,,h Sazard C.A.a. ,u~er Co~onen,, , N~ , C.A.a. N~er (Check all that apply) Fire Saz~4 Sudden Release R~ctivity I~tate ~ Delay~ ~ Fire Hazed ~ Sudden ~lease ~ R~cttvtty ~ im~iate ~ Delay~ Component, 2 Na~ & C.A.S. N~er Ph~ical and ~l~h Hazard C.A.a. N~er ~. [ . Componen~ 8 i N~e & C.A.a. N~er (Check all t~ apply) ¢ ~ Component , 2 N~ & C.A.S. N~er F~re ~az~d ~ Sudden Release ~ R~ctivity ~ I~iate Delay~ of Pressure H~lth H~lth Co~onent ~ 3 N~ & C.A.S. Nu~er E~RGENCY CONTACTS ~1 ~; ~0m ~f~ ~,]Ae~ .%~%, ~ ~2 N~ ' ~ ' T~le 24 ~. Phone N~e Title 24 ~ Phone c~tification (~ ~D SIGN AFTER COMPLETING ~L SECTIONS) I ~srtify ~der p~nlty of law t~t I ~ver ~rsonally ~in~ ~d ~ f~lt~ with the info~ation su~itted in this ~d all attached d~ents ~d ~at ~sed on ~ in~i~ of those N~ ~ ' 6F ~OP~R OR ~OP~R'S A~O~D ~P~S~TI~ SI DA~ Date Issued: 01/22/91 Supercedes: 01/17/91 TEXACO MATERTAL SAFETY DATA SHEET NOTE: Read and understand Material Safety Data Sheet before handling or disposing of product 1. CHEMZCAL PRODUCT AND C'OMPANY IDENTZFZCAT[ON MATER[AL [DENTZTY Product Code and Name: 02196 HAVOLZNE FORMULA 3 MOTOR OZL SAE 20W-50 Chemical Name and/or Family or Description: Havoline Motor Oils Manufacturer's Name and Address: Texaco Lubricants Co. Div of TRMI P.O. Box 52332 Houston, TX 77052 Telephone Numbers: TRANSPORTATION EMERGENCY Company: (914) 831-3400 CHEMTREC: (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 GENERAL MSDS ASSISTANCE (914) 838-7204 TECHNICAL INFORMATION Fuels: (914) 838-7336; Lubricants/Antifreezes: (9t4) 838-7509 Chemicals: (512) 459-6543 2. C0MPOSZTZON/[NFORMAT[ON ON ~tlGREDZENTS OSHA IARC NTP OTHER NONE Product and/or Component(s) Carcil~ogenic According to: .... ~ Composition: Chemical/Common Name CAS No. Exposure Limit Range in % * Proprietary aromatic amine TSCA OBI None Established 0.01 0.09 Solvent-dewaxed heavy parafftnic petroleum 64742G50 5mg/m3 OSHA (MIST) 80.00 - 94.99 distillates 5mg/m3 ACGIH (MIST) lOmg/m3 STEL (MIST) Alkenylsucctnimide dispersant TSCA CBI None Established 1.00 - 3.99 Product is non-hazardous according to OSHA (t9i0.1200). * Component(s) is hazardous acco~'ding to OSHA or one or more state Right-to-Know laws. 3. HAZARD ]DENTZFZCATZON EMERGENCY OVERVIEW Appearance and Odor: Bright 'and clear liquid, mild additive odor. W/.RNZNG STATEMEMT WARNING! USED GASOLINE ~IOTOR OIL IS A POSSIBLE SKIN CANCER HAZARD BASED ON ANIMAL HMZS NFPA Health: 0 Reactivity: 0 Health: 0 Reactivity: 0 Flammability: t Special: - Flammability: 1 Special: POTENT[AL HEALTH EFFECTS EYE. SK!~ INHALATION INGESTION Primary Route of Exposure: ~ ~ ~ _ Effects of Overexposure Acute Eyes: May cause minimal irritation, experienced as temporary discomfort. Page: 1 N.D. - Not Determined N.A. - Not Applicabl~ N.T. - Not Tested < - Less Than > - Greater Than ; PRODUCT CODE: 02196 .,~ Date Issued: O1/22/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OIL SAE 2018-50 Supercedes: O1/17/91 3. HAZARD IDENTZFICATZON (CONT) Skin:' No adverse effects expected from absorption of material through the skin. Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause defatttng of skin or irritation, seen as local redness with possible mild discomfort. Inhalation: Vapors or mist, tn excess of permissible concentrations, or in unusually high concentrations generated from spraying, heating the material or as from exposure tn poorly ventilated areas or conftned spaces, may cause irritation of the nose and throat, headache, nausea, and drowsiness. Ingestion: No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea may occur. Sensitization Properties: Unknown. Chronic: No adverse effects anticipated. Medical Conditions Aggravated by Exposure: '. Because of 1ts deferring properties, prolonged and repeated sktn contact may aggravate an existing dermatitis (skin condition). Other Remarks: None 4. FIRST AID MEASURES Eyes: Flush eyes wtth plenty of water for several minutes. GeV me~lcal attention if eye irritation persists. Skin: Wash skin with plenty of soap and water for several min~Jtes. Get medical attention if skin irritation develops or persists. Ingestion: If more than several mouthfuls have been swallowed, give two glasses of water (16 oz.). Get medical attention. Inhalation: If irritation, headache, nausea, or drowsiness oc~;urs, remove to fresh air. Get medical attention if breathing becomes diffi, Jlt or symptoms persist. Other Instructions: Remove and dry-clean or launder clothing soake, or sotled with this material before reuse. Dry cleaning.of contam rated clothing may be more effective than normal laundering. Infor"~ individuals responsible for cleaning of potential hazards associated witr ~andltng contaminated clothing. ' -. S. FIRE-FIGHTING MEASURES .. Ignition Temp. Degrees F.: N.O. Flash Point Degrees F. (Method): 465'F (COC) Flammable Limits (%) Lower: N.D. Upper: N.b. Page: 2 N.D. - Not Determined N.A. - Not Applicable N.T. - Not Tested < - Less Than > Greater T,~an [~RODUCT CODE: 02196 Date Tssued: 01/22/91 PRODUCT NAME: HAVOLTNE FORMULA 3 MOTOR OIL SAE 20~/-50 Supercedes: 01/17/91 S. FZRE-FZGHTZNG MEASURES fCONT) Recommended Fire Exti~gutshlng Agents And Special Procedures: According to NFPA (;~ide, use water spray, dry chemical, foam, or carbon dioxide. Water ~-~am may cause frothing. Use water to cool fire-exposed containers. If a lcak or spill has not ignited, use water spray to disperse the vapor~ and to provide protection for persons attempting to stop the leak. UnUsual or Explosive R~ards: None 6. ACCZDENTAL RELEASE MEASURES .(Transportation Spills Call: CHEMTREC (800) 424-g300) Procedures tn Case of Ac~:~c:ental Release, Breakage or Leakage: Ventilate area. Avoid breathing vapor. Use self-contained breathing apparatus or supplied air for large spills or confined areas. Contain spill if possible. I ipa up or absorb on suitable matertal and shovel up. Prevent entry into s~er$ and waterways. Avoid contact wtth skin, eyes or clothing. ?. HANDLZNG AND STORAGE precautions to be Taken. in Handltng and Storage: Mtnimum feastble hanHltng temperatures should be maintained. Periods of exposur~ to htgh temI~e~atures should be minimized. Water contamination should be avotded. 8. EXPOSURE CONTROLS/PERSONAL Ii~OTECT~ON Protective Equipment (Type~ Eye/Face Protection: Chemical-type goggles 3r face shteld recommended to prevent eye contact. Skin Protection: Workers should wash ex~o'~ed skin several times daily with soap and water. Soiled work clothing sho~.~ld be laundered or dry-cleaned at least once a week. Respiratory Protection: ,-~ Airborne concentrations should be kept to lowest levels possible. If vapor, mtst or dust is gener~'~ed, use respirator approved by MSHA or NZOSH as appropriate. Supplied air respiratory protection should be used for cleaning large spills or upon .~ntry Into tanks, vessels, or other confined spaces. See below for appllc~'~le permissible concentrations. Ventilation: Adequate to meet component occup~tional exposure 11mits (see Sectton 2). .Exposure Limit for Total Product: None established for this product; refer to Section 2 for component permissible concentration. ~ 9. PHYSZCAL AND CHEMZCAL PROPERTZES Appearance and Odor: Bright and clear ~iquid, mild additive odor. Botltng Point (Degrees F.): N.D. Percent VOC: 100 Specific Gravity: 0.8934 (H20=1) Vapor Density: N.D. Air=t Page: 3 N.D. - Not Determined N.A. - Not Applicable N.T. - Not Tested < - Less Than > - Greater.Than ~ PRODUCT CODE: 02196 Date Issued: 01/22/91 PRODUCT.NAME: HAVOLINE FORMULA 3 MOTOR OIL SAE 20W-50 Supercedes: 01/17/91 9. PHYSICAL AND CHEMICAL PROPERTIES (CONT) pH of undiluted product: N.A. Solubility in Water: N.b. Vapor Pressure: N.D. mmhg Viscosity: 169.2 cst @40'C Other: N.D. 10. STABILITY AND REACTIVITY This Material Reacts Violently With: (If others is checked below, see comments for details) Air Water Heat Strong Oxidizers Others None of These Y Comments: None Products Evolved When Subjected to Heat or Coml~stion: Toxtc levels of carbon monoxide, carbon dioxide, irrttatJng aldehydes and ketones; combustion products of nitrogen, sulfur, calcium, zinc, or phosphorous may also be released. OCCUR O0 NOT OCCUR Hazardous Polymerizations: _ ~ 11. TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose (LDSO LCSO) (Species) Oral: believed to be >5 g/kg (rat); practically non-toxic Inha]atton: N.D. Dermal: belteve~ to be > 3 g/kg (rabbit); practi~;~lly non-toxic Irritation Index, Estimation of Irritation (Species) Skin: believed to be < 0.5/8.0 (rabbit); no appreciable effect Eyes: haltered to be < 15/1t0 (rabbit); no app:'ectable effect Sensitization: N.D. Other: Used gasoline motor oils have been shown to cause skin c~ncer when repeatedly applied to mouse skin without any effort to r'~move the material between applications. There is no evidence of a-causal relationship between skin cancer in humans and exposure to used motor otl. 12. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS This product has been evaluated for RCRA character ts~tcs and does not meet the criteria of a hazardous waste if discarded in its purchased form. Under RCRA, it is the responsibility of the user (~f the product to deter- mine at the time of disposal, whether the produ~ ~c ~eets RCRA criteria for hazardous ~aste, This is because product uses,,[~nsformations, mixtures, processes, etc. may render the resulting materi~)~ hazardous. REMARKS None t3. TRANSPORT INFORMATION TRANSPORTATION ~ DOT: PROPER SHIPPING NAME: N.D. ZMDG: PROPER SHIPPING NAME: N.D. IATA: PROPER SHIPPING NAME: N.D. Page: 4 N.D. - Not Determined N.A. - Not Applicable ' N.T. - Not Tested < - Less Than > - Greater Than ~PRoDUCT CODE: 02196 Date Issued: 01/22/91 PRODUCT NAME: HAVOLINE. FORMULA 3 MOTOR OIL SAE 20W-§O Supercedes: 01/17/91 13. TRANSPORT INFORNATZON (CONT) TDG: PROPER SHIPPING N/~IE: N.D. 14. REGULATORY INFORHATION A. SARA TITLE II! Title II! Section 302/304 Extremely Hazardous Substance: ...Componen~ CAS No. Percent RQ (lbs) TPQ (lbs) NONE CERCLA Section 102(a) Hazardous Substance Component CAS No. Percent RQ ~lbs) NONE Tttle ZZZ Section 311 Hazard Categorization Acute Chronic Fire Pressure Reactive Not Applicable X Title II! Section 313 Toxic Chemicals Component CAS No. Percent Ztnc dtthi~,),osphate 25103542 0.10-0.99 Zinc dtthic~)~osphate 84605298 0.10-0.99 B. WHMIS CLASSIFI~:ATION Not RegulateO C. MICHIGAN CRITICAL MATERIALS 0.12% zinc 15. OTHER INFORMATION None THE INFORMATION CONTAINED HE~;EIN IS BELIEVED TO BE ACCURATE. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM. IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT, NO EXPRESS WARRANTY. OR IMPLIED WARRANTY OF MERCHANTABILTIY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PR[IOUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS, YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY. PROCESS. USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH Si~CH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS. Date: 01-22-9t _ New ~ Revtsed, Supersedes: 01-17-91 Date Printed: 02-27-91 Inquiries regarding MSDS should be directed to: Texaco Inc. Manager. Product Safety P.O. Box 509 Beacon, N.Y. 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL Page: S N.D. - Not Determined N.A. - Not Applicable N.T. - Not Tested < - Less Than > - Greater Than PRODUCT CODE: 02196 Date Issued: 01/22/91 PRODUCT NAME: HAVOLlrNE FORMULA 3 MOTOR OIL SAE 20W-50 Supercedes: 01/17/91 16. PRODUCT LABEL READ AND UNDERSTAND MATERZAL SAFETY DATA SHEET BEFORE HANDLZNG OR DZSPOSZNG OF PRODUCT 02196 HAVOLINE FORMULA 3 MOTOR OIL SAR 20W-50 NARNZNG STATEMENT WARNING! USED GASOLINE MOTOR OIL IS A POSSIBLE SKIN CANCER HAZARD BASED ON ANIMAL DATA PRECAUTZONARY HEASURES CONTINUOUS CONTACT WITH USED GASOLINE MOTDR OIL HAS CAUSED SKIN CANCER IN LABORATORY ANIMALS. AVOID CONTACT WITH USED MOTOR OIL. AVOID PROLONGED BREATHING OF MIST OR VAPOR. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING. CLEAN OIL-SOAKED CLOTHING BEFORE REUSE. FIRST AZD INGESTION: If more than several mobthfuls have been swallowed, give two glasses of water (16 oz.). Get medical attention. INHALATXON: If irritation, headache, nausea, or d~owsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or symptoms perstst. EYE CONTACT: Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists. SKIN CONTACT: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists. FIRE In case of fire, use foam, dry chemical, or C02. Use water spray to keep containers cool. Chemical/Common Name CAS No. Range t~ % * Proprietary aromatic amine TSCA CBI 0.01 - 0.09 Soivent-dewaxed heavy paraffinic petroleum 64742650 80.00 - 94.99 distillates Alkenylsuccinimide dispersant ,., TSCA OBI 1.00 - 3.99 Product is non-hazardous according to OSHA (1910.1200). * Component(s) is hazardous according to OSHA or one oP more state Right-to-Know laws. Not classified as a hazardous material by DOT Qeflnttion. HMIS National Fi,'e Protection Association Health : 0 Reactivity : 0 Health : 0 Reactivity : 0 F)ammaDility: 1 Specia) : - Flammability: I Special : CAUTION: Misuse of empty containers can be hazardous. Empty con~ainers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat. Keep container closed and drum bungs in place. Manufacturer's Name: Texaco Lubricants Co. Div of T~I. P.O. Box 52332 Houston, TX 77652 TRANSPORTATION EMERGENCY Company: (914) 831-3400 CHEMTREC: (800) 424-930¢~ HEALTH EMERGENCY Company: (914) 831-3400 Date Issued: 04/11/9t Supercedes: 01/22/91 TEXACO MATERIAL SAFETY DATA SHEET NOTE: Read and understand Material Safety Data Sheet before handling or disposing of product 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name: 02190 HAVOLINE FORMULA 3 MOTOR OIL SAE 10W-30 Chemical Name and/or Family or Description: Havoline Motor Oils Manufacturer's Name and Address: Texaco Lubricants Company a Division of Texaco Refining and Marketing Inc. P.O. Box 4427, Houston, TX 77210-4427 Telephone Numbers: TRANSPORTATION EMERGENCY Company: (914) 831-3400 CHEMTREC: (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 GENERAL MSDS ASSISTANCE (914) 838-7204 TECHNICAL INFORMATION Fuels: (914) 838-7336; Lubricants/Antifreezes: (914) 838-7509 Chemicals: (512) 459-G543 2. COMPOSITION/INFORMATION ON INGREDIENTS OSHA IARC NTP OTHER NONE Product and/or Component(s) Carcinogenic According to: .... Composition: Chemical/Common Name CAS No. Exposure Limit Range in % * Proprietary aromatic amine TSCA CBI None Established 0.01 - 0.09 Soivent-dewaxed heavy paraffinic petroleum 64742650 5mg/m3 OSHA (MIST) 80.00 - 94.99 distillates 5mg/m3 ACGIH (MIST) lOmg/m3 STEL (MIST) Alkenylsuccinimide dispersant TSCA CBI None Established 1.00 - 3.99 Product is non-hazardous according to OSHA (1910.1200). * Component(s) is hazardot~s according to OSHA or one or more state Right-to-Know laws. 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance and Odor: Bright and clear ltquid, mild additive odor NARNING STATEMENT WARNING! USED GASOLINE MOTOR OIL IS A POSSIBLE SKIN CANCER HAZARD BASED ON ANIMAL DATA HMIS NFPA' Health: 0 Reactivity: 0 Health: 0 Rea=t~vity: Flamma~ilit'>: 1 SpeciE, l: - Flammability: 1 Special: POTENTIAL HEALTH EFFECTS EYE SKIN INHALATION INGESTION Primary Route o~ Exposure: ~ ~ ~ _ E~fects of Overexposure Acute Eyes: May cause minimal irritation, experienced as temporary discomfort. Page: 1 N.D. Not Determined N.A. - Not Applicable N.T. - Not Tested < Less Than > - Greater Than PRODUCT CODE: 02190 Date Issued: 04/11/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OIL 5AE 10W-30 Supercedes: 01/22/91 3. HAZARD IDENTIFICATION (CONT) Skin: No adverse effects expected from absorption of material through the skin. Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause defatting of skin or irritation, seen as local redness with possible mild discomfort. Inhalation: Vapors or mist, in excess of permissible concentrations, or in unusually high concentrations generated from spraying, heating the material or as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea, and drowsiness. Ingestion: No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea may occur. Sensitization Properties: Unknown. Chronic: No adverse effects anticipated. Medical Conditions Aggravated by Exposure: Because of its defatting properties, prolonged and repeated skin contact may aggravate an existing dermatitis (skin condition). Other Remarks: None 4. FIRST AID MEASURES Eyes: Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists. Skin: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists. Ingestion: If more than several mouthfuls have been swallowed, give two glasses of water (16 oz.). Get medical attention. Inhalation: If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or symptoms persist. Other Instructions: Remove and dry-clean or launder clothing soaked or soiled with this material before reuse. Dry cleaning of contaminated clothing may be more effective than normal laundering. Inform individuals responsible for cleaning of potential hazards associated with handling contaminated clothing. FIRE-FIGHTING MEASURES Ignition Temp. Degrees F.: N.D. Flash Point Degrees F. (Method): 400'F (COC) Flammable Limits (%) Lower: N.D. Upper: N.D. Page: 2 N.D. - Not Determined N.A. - Not Applicable N.T. - Not Tested < - Less Than > - Greater Than PRODUCT CODE: 02190 Date Issued: 04/11/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OTL CAE 10W-30 Supercedes: 01/22/91 5. FIRE-FIGHTING MEASURES (CONT) Recommended Fire Extinguishing Agents And Special Procedures: According to NFPA Guide, use water spray, dry chemical, foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons attempting to stop the leak. Unusual or Explosive Hazards: None B. ACCIDENTAL RELEASE MEASURES (Transportation Spills Call: CHEMTREC (800) 424-9300) Procedures in Case of Accidental Release, Breakage or Leakage: Ventilate area. Avoid breathing vapor. Use self-contained breathing apparatus or supplied air for large spills or confined areas. Contain spi]l if possible. Wipe up or absorb on suitable material and shovel up. Prevent entry into sewers and waterways, Avoid contact with skin, eyes or clothing. 7. HANDLING AND STORAGE Precautions to be Taken in Handling and Storage: Minimum feasible t~andling temperatures should be maintained. Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Equipment Eye/Face Protection~ Chemical-type goggles or face shield recommended to prevent eye contact. Skin Protection: Workers should wast} 9xposed skin several times daily with soap and water. Soiled work clothit%F }hould be laundered or dry-cleaned at least once a week. Respiratory Protection: Airborne concentraticns should be kept to lowest levels possible. vapor, mist or dust is generated, use respirator approved by MSHA or NIOSH as appropriate. Supplied air respiratory protection should be used for cleaning large spills or upon entry into tanks, vessels, or other confined spaces. See below for applicable permissible concentrations. Ventilation: Adequate to meet component occupational exposure limits (see Section 2). Exposure Limit for Total Product: None established for this product: refer to Section 2 for component permissible concentration. 9. PHYSICAL AND CHEMICAL PROPERTIES I Appearance and Odor: Bright and clear liquid, mild additive odor Botling Point (Degrees F.): N.D. Percent VOC: 100 Specific Gravity: 0.8762 (H20=1) Vapor Density: N.D. Air=l Page: 3 N.'D. Not Determined N.A. - Not Applicable N.T. - Not Tested < Less Than > - Greater Than PRODUCT CODE: 02190 Date Issued: 04/11/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OIL SAE lOW-30 Supercedes: 01/22/91 9. PHYSICAL AND CHEMICAL PROPERTIES (CONT) pH of undiluted product: N.A. Solubility in Water: N.D. Vapor Pressure: N.b. 'mmhg Viscosity: 6.8 cst @100 C Other: N.b. 10. STABILITY AND REACTIVITY This Material Reacts Violently With: (If others is checked below, see comments fop details) Air Water Heat Strong Oxidizers Others None of These Y Comments: None Products Evolved When SubJected to Heat or Combustion: Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones; combustion products of nitrogen, sulfur, calcium, zinc. or phosphorous may also be released. OCCUR DO NOT OCCUR Hazardous Polymerizations: _ ~ 11. TOXICOLOGICAL INFORMATION TOXICOLOGICAL [NFORHAT[ON(ANIMAL TOXICITY DATA) Median Lethal Dose (LDSO LCSO) (Species) Oral: believed to be > 5 g/kg (rat); practically non-toxic Inhalation: N.D. Dermal: believed to be'> 3 g/kg (rabbit); practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin: believed to be < 0.5/8.0 (rabbit); no appreciable effect Eyes: believed to be < 15/110 (rabbit); no appreciable effect Sensitization: N.D. Other: Used gasoline motor oils have been shown to cause skin cancer when repeatedly applied to mouse skin without any effort to remove the materia] between applications. There is no evidence of a causal relationship between skin cancer in humans and exposure to used motor oil. 12. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its purchased form. Under RCRA, it is the responsibility of the user of the product to deter- mine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may render the resulting materials hazardo~.~s.- REMARKS None 13. TRANSPORT INFORMATION TRANSPORTATION DOT: PROPER SHIPPING NAME: N.D. [MDG: PROPER SHIPPING NAME: N.b. [ATA: PROPER SHIPPING NAME: M.D. Page: 4 N.b. - Not Determined N.A. - Not Applicable N.T. - Not Tested < - Less Than > - Greater Than PRODUCT CODE: 02190 Date Issued: 04/11/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OIL SAE IOW-30 Supercedes: 01/22/9i 13. TRANSPORT INFORMATION (CONT) TDG: PROPER SHIPPING NAHE: N.D. 14. REGULATORY INFORHATION A. SARA TITLE Title III Section 302/304 Extremely Hazardous Substance: Component CAS No. Percent RO (ihs) TPO (lbs) NONE CERCLA Section 102(a) Hazardous Substance Component CAS No. Percent RQ NONE Title III Section 311 Hazard Categorization Acute Chronic Fire Pressure Reactive Not Applicable X Title II1 Sac*ion 313 Toxic Chemicals Component CAS No. Percent Zinc dithiop~:~sphate ACC# 81697 0.10-0.99 Zinc dithiophr~sphate 25103542 0.10-0.99 B. 'WHHIS CLASSIFICATION NA C. NICHIGAN CRITIC, ~ NATERIALS 0.12% zinc, 116 FPm copper 15. OTHER INFORHATION None " THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUET .FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM. IT IS I"' INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR 'r'LIED WARRANTY OF MERCHANTABILTIY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE ',RODUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS. "YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT ~ITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE APPLICABILITY O~ EFFECT OF ANY LA~ OR REGULATION ~[TH RESPECT TO THE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. TEXACO DOES NOT UNDERTAKE TO FURNIS~ ADVICE ON SUCH MATTERS. Date: 04-11-91 _ Hew [ Revised, Supersedes: 01-22-91 Date Prtnted: 01-21-92 Inquiries regarding ~SDS should ~e directed to: Texaco Inc. Eanager, Product Safety P.O. Bo>: 509 Beacon, N.Y. 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL Page: 5 N.D. Not Determined N.A. Not Applicable N.T. Not Tested < Less Than > - Greater Than PRODUCT CODE: 02190 Date Issued: 04/11/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OIL SAR 10W-30 5upercedes: 01/22/91 16. PRODUCT LABEL READ AND UNDERSTAND MATER[AL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT 02190 HAVOLINE FORMULA 3 MOTOR OIL SAR I.OW-30 WARNING STATEMENT WARNING! USED GASOLINE MOTOR OIL IS A POSSIBLE SKIN CANCER HAZARD BASED ON ANIMAL DATA PRECAUTIONARY MEASURES CONTINUOUS CONTACT WITH USED GASOLINE MOTOR OIL HAS CAUSED SKIN CANCER IN LABORATORY ANIMALS. AVOID CONTACT WITH USED MOTOR OIL. AVOID PROLONGED 6REATHING OF MIST OR VAPOR. ~ WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING. CLEAN OIL-SOAKED CLOTHING BEFORE REUSE. FIRST AID INGESTION: Ir'more.than several mouthfuls have been swallowed, give two glasses of w~ter.(16 oz.). Get medical attention. INHALATION: If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get,medical attention if breathing becomes difficult or symptoms persist. .EYE CONTACT: .F~ush eyes with plenty of water for several minutes. Get medical i~at~entlon if eye irritation persists. SKIN CONTACT: Wash skin with plenty of soap and water fop several minutes. /Get medical attention if skin irritation develops or persists. FZRE In case of fire, use foam, dry chemical, or C02. Use water Spray to keep containers cool. Chemical/Common Name CAS No. Range in % Proprietary aromatic amine TSCA CBI 0.01 0.09 Solvent-dewaxed heavy paraffinic petroleum 64742650 80,00 - 94.99 distillates Alkenylsuccinimide dispersant TSCA CBI 1,00 - 3.99 Product is non-hazardous according to OSHA (1910.1200). ~ Component(s) is hazardous according to OSHA or one or more ~ state Right-to-Know laws. ~- Not classified as a hazardous material by DOT definition. HMI5 National Fire Protection Association Health : 0 Reactivity : 0 Health : 0 Reactivity : 0 Flammability: t Special : Flammability: 1 Special : - CAUTION: Misuse of empty containers can be hazardous. Empty contair)ers can be hazardous tf used to store toxic, flammable, or reactive materials, Cuttir~g or:welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat. Keep container closer and drum bungs in place. Manufacturer's Name: Texaco Lubricants Company ,' a Division of Texaco Refining ancJ Marketing Inc. P.O. Box 4427, Houston, TX 77210-4427 TRANSPORTATION EMERGENCY Company: (914) 831-3400 CHEMTREC: (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 Date Issued: 01/22/91 Supercedes: 01/17/91 TEXACO MATERIAL SAFETY DATA SHEET NOTE: Read and understand Material Safety Data Sheet before hand] lng or dis~posing of product 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MATERIAL IDENTITY Product Code and Name: 02193 HAVOLINE FORMULA 3 MOTOR OIL SAE 30 Chemical Name and/or Famtly or Description: Havoline Motor Oils Manufacturer's Name and Address: Texaco Lubricants Company a Division of Texaco Refining and Marketing Inc. P.O. Box 4427, Houston, TX 77210-4427 Telephone Numbers: TRANSPORTATION EMERGENCY Company: (914) 831-3400 CHEMTREC: (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 GENERAL MSDS ASSISTANCE (914) 838-7204 TECHNICAL INFORMATION Fuels: (914) 838-7336; Lubricants/Antifreezes: (914) 838-7509 Chemicals: (512) 459-6543 2. COMPOSITION/INFORMATION ON INGREDIENTS OSHA IARC NTP OTHER NONE Product and/or Component(s) Carcinogenic According to: .... ~ Composition: Chemical/Common Name CAS No. Exposure Limit Range in % $olvent-dewaxed heavy paraffintc petroleum 64742650 Smg/m3 OSHA (MIST) 80.00 - 94.99 distillates 5mg/m3 ACGIH (MIST) lOmg/m3 STEL (MIST) Alkenylsuccinimtde dispersant TSCA CBI None Established 1.00 - 3.99 Product is non-hazardous according to OSHA (1910.1200). 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW Appearance and Odor: Bright ~nd clear liquid ~ARNING STATEMENT WARNING! USED GASOLINE MOTOR OIL IS A POSSIBLE SKIN CANCER HAZARD BASED ON ANIMAL DATA HMIS NFPA Health: 0 Reactivity: 0 Health: 0 Reactivity: 0 Flammability: 1 Special: - Flammability: I Special: POTENTIAL HEALTH EFFECTS EYE S~(IN INHALATION INGESTION Primary Route of Exposure: ~ ~ ~ _ Effects of Overexposure Acute Eyes: May cause minimal irritation, experier~¢:ed as temporary discomfort. Page: 1 N.D. - Not Determined N.A. - Not Applicable N.T. - Not Tested < - Less Than > - Greater Than PRODUCT CODE: 02193 Date Issued: 01/22/91 PRODUCT NAME: HAVOLINE FORMULA 3 I~OTOR OIL SAE 30 5upercedes: 01/17/91 3. HAZARD IDENTIFICATION (CONT) Skin: No adverse effects expected from absorption of material through the skin. Brief contact is' not irritating. Prolonged contact, as with clothing wetted with material, may cause defatting of skin or irritation, seen as locai redness with possible mild discomfort. Inhalation: Vapors or mist, in excess of permtssiDle concentrations, or in unusually high concentrations generated from spraying, heating the material or as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea, and drowsiness. Ingestion: No adverse effects expected. If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea may occur. Sensitization Properties: Unknown. Chronic: No adverse effects anticipated. Medical Conditions Aggravated by Exposure: Because of its defatting properties, prolonged and repeated skin contact may aggravate an existing dermatitis (skin condition). Other Remarks: None 4. FZRST AID MEASURES Eyes: Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists. Skin: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists., Ingestion: If more than several mouthfuls have been swallowed, give two glasses of water (16 oz.). Get medical attention. Inhalation: If irritation, headache, nausea, or drowsiness oc'curs, remove to fresh air. Get medical attention if breathing ,becomes difficult or symptoms persist. Other Instructions: Remove and dry-clean or launder clothing soake¢!or soiled with this material before reuse. Dry cleaning of conta~'~nated clothing may be more effective than normal laundering. Infcr,a-,individuals responsible for cleaning of potential hazards associated with handling contaminated clothing, 5. FIRE-FIGHTING MEASURES Ignition Temp. Degrees F,: N.D. Flash Point Degrees F. (Method): 465 F (COC) Flammable Limits (%) Lower: N.D. Upper:. N.D. Page: 2 N.D. Not Determined N.A. - Not Applicable N.T. Not Tested < - Less Than > - Greater Tllan PRODUCT CODE: 02.193 Date Issued: 01/22/91 PRODUCT. NAME: HAVOLINE FORMULA 3 MOTOR OIL SAE 30 Supercedes: 01/17/91 5. F[RE-FZGHT[NG MEASURES (CONT) Recommended Fire Extinguishing Agents And Special Procedures: According to NFPA Guide, use water spray, dry chemical, foam, or carbon dioxide. Water or foam may cause frothing. Use water to cool fire-exposed containers. If a leak or spill has not ignited, use water spray to disperse the vapors and to provide protection for persons attempting to stop the leak. Unusual or Explosive Hazards: None 6. ACC[DENTAL RELEASE MEASURES (Transportation Spills Call: CHEMTREC (800) 424-9300) Procedures in Case of Accidental Release, Breakage or Leakage: Ventilate area. Avoid breathing vapor. Use self-contained breathing apparatus or supplied air for large sptlls or confined areas. Contain sptl] if possible. Wipe up or absorb on suitable material and shovel up. Prevent entry into sewers and waterways. Avotd contact with skin, eyes or clothing. 7. HANDLZNG AND STORAGE Precautions to be Taken in Handllng and Storage: ~tnimum feasible handling temperatures should be maintained. Pertods of exposure to high temperatures should be minimized. Water contamination should be avoided. 8. EXPOSURE CONTROLS/PERSONAL PROTECT[ON Protective Equipment (Type) Eye/Face Protection: Chemical-type goggles or face shteld recommended to prevent eye contact. Skin Protection: Workers should wash exposed sktn several times daily with soap and water, Soiled work clothing should be laundered or dry-cleaned at least once a week. Respiratory Protection: Airborne concentratfons should be kept to lowest levels possible. vapor, mist or dust is generated, use respirator approved by MSHA or NIOSH as appropriate. Supplied air respiratory protection should be used for cleaning large sptlis or upon entry into tanks, vessels, or other confined spaces. See below for applicable permissible concentrattoos. Ventilation: Adequate to meet component occupational exposure limits (see Section 2). Exposure Limit for Total Product: None established for product. Refer to component permissible concentrations. 9. PHYS[CAL AND CHEMICAL PROPERTIES Appearance and Odor: Bright and clear liquid Boiling Point (Degrees F.): N.D. Percent VOC: N.D. Specific Gravity: 0.8916 (H20=1) Vapor Density: N.D. Air=l Page: 3 N.D, Not Determined N.A. - Not Applicable N.T. Not Tested < Less Than > - Greater Than PRODUCT CODE: 02193 Date Issued: 01/22/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OIL SAE 30 Supercedes: 01/17/91 9. PHYSICAL AND CHEMICAL PROPERTIES (CONT) pH of U'ndiluted product: N.A. Solubility in'Water: N.D. ' Vapor Pressure: N.D. mmhg Viscosity: 95.5 cst @ 40 C Other: N.D. 10. STABILITY AND REACTIVITY This Material Reacts Violently With: (If others is checked below, see comments for, details) Air Water Heat Strong Oxidizers Others None of These Y Comments: None '* Products Evolved When Subjected to Heat or Combustion: Toxic leve]s of carbon monoxide, carbon dioxide, irritating aldehydes and ketones. OCCUR DO NOT OCCUR Hazardous Polymerizations: _ ~ 11. TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Hedian Lethal Dose (LO50 LCSO) (Species) Oral: Believed to be > 5 g/kg (rat); practically non-toxic Inhalation: N.D. Dermal: Believed to be > 3 g/kg (rabbit); practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin: Believed to be <0.5/8.0 (rabbit); no appreciable effect Eyes: Believed to be <15/110 (rabbit); no appreciable effect Sensitization: N.D. Other: Used gasoline motor oils have been shown to cause skin cancer when repeatedly applied to mouse skin without any effort to remove the material between applications. There is no evidence of a causal relationship between skin cancer in humans and exposure to used motor oi1. 12. DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHODS This product has been evaluated for RCRA characteristics and does not meet the criteria of a hazardous waste if discarded in its purchased form. Under RCRA, it is the responsibility of the user of the product to deter- mine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes, etc. may render the resulting materials hazardous. REMARKS None 13. TRANSPORT INFORMATION TRANSPORTATION DOT: PROPER SHIPPING NAME: N.D. IMDG: PROPER SHIPPING NAME: N.D. IATA: PROPER SHIPPING NAHE: N.D. Page: 4 N.D. - Not Determined N.A. - Not Applicable N.T. Not Tested < - Less Than > - Greater Than PRODUCT CODE: 02193 Date Issued: 01/22/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OIL SAE 30 Supercedes: 01/17/91 13. TRANSPORT INFORMATION (CONT) TDG: PROPER SHIPPING NAME: N.D. 14. REGULATORY INFORMATION A. SARA TITLE ZZ! Title !II Section 302/304 Extremely Hazardous Substance: Component CAS No, Percent RQ (lbs) TPQ (lbs) None CERCLA Section 102(a) Hazardous Substance Component CA5 No. Percent RQ (lbs) None Title !!! Section 311 Hazard Categorization Acute Chronic Fire Pressure Reactive Not Applicable X Title III Section 313 Toxic Chemicals Component CAS No. Percent Zinc dialkyldithtophosphate 25103542 O. 10-0.99 Dialkyidithtophosphortc acid, 84605298 O. 10-0.99 zinc salt B. WHM!S CLASSTF!CATZON N.A. C. MICHIGAN CRIT!CAL MATER!ALS Michigan Critical Materials 0.12% ztnc 15. OTHER INFORMAT!ON None THE INFORMATTON CONTAINED HEREIN IS BELIEVED TO BE ACCURATE. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM. IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILTIY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. TEXACO DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS. ~ Date: 01-22-91 _ New X Revised, Supersedes: 01-17-91 Date Printed: 01-24-92 Inquiries regarding MSDS should be directed to: Texaco Inc. Manager, Product Safety P.O. Box 509 Beacon, N.Y. 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL Page: 5 N.D. Not Determined N.A. - Not ~pplicable N.T. Not Tested < Less Than > - Greater Than PRODUCT CODE: 02193 Date .Issued: 01/22/91 PRODUCT NAME: HAVOLINE FORMULA 3 MOTOR OIL SAE 30 Supercedes: 01/17/91 16. PRODUCT LABEL READ AND UNDERSTAND HATER[AL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT 02193 HAVOLINE FORMULA 3 MOTOR OIL SAE 30 WARNING STATEHENT WARNING! USED GASOLINE MOTOR OIL IS A POSSIBLE SKIN CANCER HAZARD BASED ON ANIMAL DATA PRECAUTIONARY HEASURES' CONTINUOUS CONTACT WITH USED GASOLINE MOTOR OIL HAS CAUSED SKIN CANCER IN LABORATORY ANIMALS. AVOID CONTACT WITH USED MOTOR OIL. AVOID PROLONGED BREATHING OF MIST OR VAPOR. -WASH THOROOGHLY WITH SOAP AND WATER AFTER HANDLING. CLEAN OIL-SOAKED CLOTHING BEFORE REUSE. FIRST AID INGESTION: If more than several mouthfuls have been swallowed, give two glasses of water (16 oz.). Get medical attention. INHALATION: If irritation, headache, .nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or symptoms persist. EYE CONTACT: Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists. SKIN CONTACT: Wash skin with plenty of soap and water for severa) minutes. Get medical attention if skin irritation develops or persists. FIRE In case of fire, use foam, dry chemical, or C02. Use water spray to keep containers cool. Chemical/Common Name CAS No. Range in % Solvent-dewaxed heavy paraffinic petroleum 64742650 80.00 - 94.99 distillates Alkenylsuccinimide dispersant TSCA CBI 1.00 - 3.99 Product is non-hazardous according to OSHA (1910.1200). Not classified as a hazardous material by DOT definition. HMIS National Fire Protection Association Health : 0 Reactivity : 0 Health : 0 Reactivity : 0 Flammability: 1 Special : - Flammability: 1 Special : CAUTION:Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or toxic fumes from residues. Do not pressurize or expose to open flame or heat. Keep container closed and drum bungs in place. Manufacturer/s Name: Texaco Lubricants C~mpany a Division of Texaco Refining and Marketing Inc. P.O. Box 4427, Houston, 'FX 77210-4427 TRANSPORTATION EMERGENCY Company: (914) 831-3400 CHEMTREC: (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 ,k Bakersfield Fire Dept. V'" /~ .~ _ ~ .~az ard~lu~0 'M' Gat''e SritralesetDivisi°n ~.~ ?~~7~/~~]~rsfield, (3A' 93301 INSTRUCTIONS: 1, To avoid further action, return this form within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. ~A~ 3 1 1~(~ .3, Answer the questions below for the business as a whole. - 4. Be brief and concise as possible. HA.7_~ MAT, DIV. SECTION 1: BUSINESS IDENTIFICATION DATA BUSINESS NAME: ._~/~_///~/~)/4-c~ ~/~/~_ ~/~4 LOCATION: c.~g ~./~.-dO4~_~_ /~.-/1,/ ~~/~ P~ ~3o~ MAILING ADDRESS'. ~¢ 1¢ Ikbm~ 'CITY', ~~~/~ ~ STATE', ~4 ZIP' ~33~¢ PHONE: ~g~~/~ DUN & BRADSTREET NUMBER' SIC CODE: PRIMARY ACTIVITY: /-~5;/'//A/~'- ~--~/fl~ ~ OWNER: ~"~,P/~'/(' :~ ~ 70~ ~ " MAILIN~ADDRESS:'~3 ~~~ ~, ~~~/~ ~ ~3~ SECTION 2: EMERGENCY NOTIFICATION: CONTACT TITLE BUS. PHONE 24 HR, PHONE 2. FD15~ 03/18/92 BAKERSFIELD CAR WASH 215-000-001034 Page 1 Overall Site with 1 Fac. Unit General Information Location: 2523 BRUNDAGE LN Map: 102 Hazard: Low Community: BAKERSFIELD STATION 03 Grid: 36C F/U: 1 AOV: 0.0 Contact Name Title~ Business Phone ---~ 24-Hour Phone- KIL-OAN KIM 1'(805) 325-8515 x/(805) 324-1146 JOHN DE LA CRUZ1(805) 325-8515 x (805) 589-4711 Administrative Data Mail'Addrs: 2523 BRUNDAGE LN D&B Number: City: BAKERSFIELD State: CA Zip: 93304.- Comm Code: 215-003 BAKERSFIELD STATION 03 SIC Code: Owner: KIL-OAN KIM Phone: (805) 325-8515 Address: 2523 BRUNDAGE LN State: CA City: BAKERSFIELD Zip: 93304- Summary I,_ rry~,~,~..,,~4), Do hereby cert~ that I have reviewed the mtached hazardous materials manage- roent plan for ~< .~, ~; ~us~.i _,and that it along with any correu~ions cons'~itute a complete and correct man- agement plan for my facility. 03/18/92 BAKERSFIELD CAR WASH 215-000-001034 Page 2 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-001 UNLEADED GASOLINE Liquid 10000 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: 8006-61-9 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: FUEL Daily Max GAL Daily Average GAL I Annual Amount GAL 10,000 I 5,000.00 100,000.00 Storage Press T TempI Location UNDER GROUND TANK Ambient~AmbientlSOUTH OF CAR WASH AREA -- Conc Components I MCP List 100.0% IGasoline IModeratel 02-002 SUPER UNLEADED GASOLINE Liquid 10000 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: 8006-61-'9 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: FUEL Daily Max GAL Daily Average GAL I Annual Amount GAL -- 10,000 I 5,000.00 100,000.00 Storage Press T Temp Location UNDER GROUND TANK IAmbient~AmbientlSOUTH OF CAR WASH AREA -- Conc Components ~ MCP ----~List 100.0% IGasoline IModeratel 02-003 NEW MOTOR OIL Liquid 110 Minimal · Fire, Delay Hlth GAL CAS #: Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: LUBRICANT --.Daily Max GAL~ Daily Average GAL ~ Annual Amount GAL 110 I 55.00! 1,200.00 Storage Press T Temp I Location DRUM/BARREL-METALLIC I Ambient/AmbientlSW CORNER -- Conc Components I MCP List 100.0% [Motor Oil, Petroleum Based IMinimal I 03/18/92 BAKERSFIELD CAR WASH 215-000-001034 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-004 WASTE OIL Liquid 500 Low · Fire, Delay Hlth GAL CAS #: 221 Trade Secret: No Form: Liquid Type: Waste Days: 365 Use: WASTE Daily. ~, Max GALI Daily Average GAL I Annual Amount GAL f 500 I 250.00 2,000.00 Storage~~Press T Temp Location UNDER GROUND TANK IAmbientlAmbientlEAST OF LUBE PIT -- Conc Components MCP ... List 100.0% Iwaste Oil, Petroleum Based ILow I 02-005 SOLVENT Liquid 55 Moderate · Fire, Delay Hlth GAL CAS #: Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: CLEANING Daily Max GAL Daily Average GAL Annual Amount GAL 55 I 25.00 I 55'.00 Storage Press T Temp Location DRUM/BARREL-METALLIC IAmbientlAmbientlsE CORNER -- Conc Components MCP ---TList 100.0% INaphtha Solvent IModeratel 03/18/92 BAKERSFIELD CAR WASH 215-000-001034 Page 4 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation THE NOTIFICATION OF ALL EMPLOYEES IS BY WORD OF MOUTH <3> Public Notif./Evacuation BY WORD OF MOUTH <4> Emergency Medical Plan KERN MEDICAL CENTER 1830 FLOWER ST 323-7651 03/18/92 BAKERSFIELD CAR WASH 215-000-001034 Page 5 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention SHUT OFF SWITCH ON EAST SIDE OF FACILITY #1, FOR GASOLINE SPILL, IF MAJOR SPILL, CALL 911 <2> Release Containment ABSORBS IT 50LB SAND <3> Clean Up PICK UP SAND AND REUSE <4> Other Resource Activation 03/18/92 BAKERSFIELD CAR WASH 215-000-001034 Page 6 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - WEST SIDE OF DETAIL SHOP BUILDING #2 B) ELECTRICAL - SOUTH SIDE OF DETAIL SHOP BUILDING #2, CENTER OF MAIN BUILDING #1 C) WATER - ON SOUTH SIDE OF STREET ON SIDEWALK ON BRUNDAGE LN D) SPECIAL - NONE E) - LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS IN BUILDINGS 1,2,3,4 FIRE HYDRANT - ON THE CORNER OF PINE AND BRUNDAGE LN <4> Building Occupancy L~vel 03/18/92 BAKERSFIELD CAR WASH 215-000-001034 Page 7 O0 - Overall Site <G> Training <l>.Page 1 WE HAVE 6 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: LOCATION OF FIRE EXTINGUISHER AND HOW TO USE IT. HOW TO CLEAN UP A SPILL AND CONTACT TO HAZARDOUS MATERIALS CO, <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use