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HomeMy WebLinkAboutBUSINESS PLAN Hazardous Materials/Hazardous Waste Unified Permit ~-.~<~ O.NDITIONS ~O.F ,PERMIT ON REVERSE SIDE :- .. .' · '~ This oermit is issued for the followin~_: [] Hazardous Materials Plan [] Underground Storageof HazardOus Materials Permit ID #:: 015-000-000645 [3 Risk Management Program [] Hazardous Waste On-Site Treatment BEDROSIANS '. LOCATION: 2701.BRUNDAGE LN ; . i. '., , . .,. - ~:? , · ~ . .. : ... ?; · · OFFICE OF ENVIRONMENTAL SER VICES' ' 1715 Chester Ave., 3rd Floor APProved by: Bakersfield, CA 93301 · VoiCe':(661) 326-3979 ~ FAX (661) 326-0576 .' , ,: ':,'.' EXi~tion.Date: :.-'' , '. ';~ ':~ ~':-]~ h ~I~ \~)MPORTANT MESSAGE ~OR A.M. DATE //~,~,~- --,,~,~TI M E* P.M. M OF PHONE NO. TELEPHONED PLEASE CALL CALLED TO SEE YOU WILL CALL AGAIN MESSAGE SIGNED. ASSOCIATED L1.A2334 ,..,,,Too ,,, u...,~. DATE ADDRESS ' ZIP CODE FEE "I.'BLOCKNO,':' x.-~- ~ ,z 7o/ ~/:/~~ 7~a¢' ..~' io2-~-b , .... . PERMIT ~EQUIRED: pERMiT BUSINESS LICENSE NO. ~,  BUILDING CLASS/TYPE OF OCCUPANCY BUSINESS NAME BU~SS OWNER ~USIN~S ~RJ/R'ES¢ON~IBLE . BUSI~'¢~ PHONE ' . . :.. ~0ME ~NE - ,- NO. OF FLOORS SQUARE FOQTAGE . , .._ : VIOLATION NOTICE ISSUED? U'/O OCCUPANT LbAD /~ . INSPECTOR STATION/SHIFT/STATION PHONE ¢ ~-, ,,~ ~~. -_. ~/UNIFIED PROGRAm. INSPECTION CHECKLIST FACILITY NAME INSPECTION DATE ADDRESS PHONE NO. FACILITY CONT{~CT BUSINESS ID NO..1-5-,E-H~- INSPECTION TIM~Ex,~ NUMBER OF EMPLOYEES Section 1: Business Plan and Inventory Program [] Routine [] Combined [] Joint Agency [] Multi-Agency [] Complaint [] Re-inspection OPERATION C V COMMENTS Appropriate permit on hand Business plan contact information accurate Visible address Correct occupancy Verification of inventory materials Verification of quantities Verification of location Proper segregation of material Verification of MSDS availability Verification of Haz Mat training Verification of abatement supplies and procedures Emergency procedures adequate Containers properly labeled Housekeeping Fire Protection Site Diagram Adequate & On Hand C=Compliance V=Violation Any hazardous waste on site?: [] Yes [] No Explain: Questions regarding this inspection? Please call us at (661) 326-3979 Business Site Responsible Party White - Env. Svcs. Yellow - Station Copy Pink - Business Copy Inspector: CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3rd Floor, Bakersfield, CA 93301 FACILITY NAME r..~o,:~' ~ro$'~, 5 INSPECTION DATE ADDRESS ,~, 7o ~ ~',-~,- ~.~ ~,.e PHONE NO. FACILITY CONTACT 5~,,,[-,~ ~,~,,-o., BUSINESS ID NO. 15-210- ~(-.J INSPECTION TIME {~' w;~ NUMBER OF EMPLOYEES Section 1: Business Plan and Inventory Program I~Routine [] Combined [] Agency Multi-Agency Complaint Re-inspection Joint OPERATION C V COMMENTS Appropriate permit: on hand Business plan contact infbrmation accurate Visible address e'7 -- Correct occupancy t., "~/:::, Verification of inventory materials Verification of quantities Verification of location Proper segregation of material Verification of MSDS availability Verification of Haz Mat training Verification of abatement supplies and procedures t/ Emergency procedures adequate Containers properly labeled Housekeeping Fire Protection Site Diagram Adequate & On Hand C=Compliance V=Violation AnYExplain:hazardous waste on site?: [~l Yes ]~No Questions regarding this inspection? Please call us at (805) 326-3979 Buginess Site Responsible Party While-[IIV. SVCS. Ydlow - Station Copy Pink - Business Copy Inspector:'~~ BEDROSIANS SiteID: 215-000-000645 666L~ ~.N~F~ BusPhone: (805) 322-5074 Manager : Location: 2701 BRUNDAGE LN'd!k~cDl~-; J I~~~'~_~_/Map :W 102 CommHaz : Low City : BAKERSFIELD __- .~ Grid: 36C FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 03 SIC Code:5211 EPA Numb: DunnBrad: Emergency Contact / Title Emergency Contact / Title MELANIE ROBERTS / MANAGER RANDY PORCHO / WAREHOUSE Business Phone: (805) 324-5000x Business Phone: (805) 324-5000x 24-Hour Phone : (805) 873-8941x 24-Hour Phone : (805) 323-5818x Pager Phone : (805) 634-7947x Pager Phone : ( ) - x Hazmat Hazards: Fire Press ImmHlth DelHlth Contact : Phone: ( ) - x MailAddr: 2701 BRUNDAGE LN State: CA City : BAKERSFIELD Zip : 93304 Owner BEDROSIANS Phone: (209) 275-5000x Address : 4285 N MOTEL DR State: CA City : FRESNO Zip : 937226316 Period : to TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: No Emergency Directives: ---- Hazmat Inventory One Unified List ~ -- Alphabetical Order Ail Materials at Site ~ Hazmat Common Name... ISpocHazlEPA HazardsI Frm DailyMax IUnitlMcP CEMENT BASED SANDED GROUT DH S 2500 LBS Min CERAMIC - MASTIC F DH L 168 GAL Mod HYDRATED LIME F IH S 2500 LBS Low, MORTAR IH S 25000 LBS Min PORTLAND CEMENT DH S 11000 LBS Min (Type or p~lnt ~'mmo) reviewe~ the a~ached hazardous materials manage- mere p~an ~o~~)% and tha~ i~ along with any corr~-~io~s constitute a complete and correc~ man- BEDROSIANS ~~~~&~&~&~&~&~&&&&~&&&~ SiteID: 215-000-000645 Inventory Item 0003 ~~~&~ Facility Unit: Fixed Containers on Site i~ COMMON NAME / CHEMICAL NAME ~~~~~~~~~~i CEMENT BASED SANDED GROUT o Days On Site o 365 Location within this Facility Unit Map: Grid: EAST RACK o CAS# O STATE ~ TYPE ~~ PRESSURE ~ TEMPERATURE ~~ CONTAINER TYPE Solid o Mixture o Ambient o Ambient o BAG i~~~~~~i AMOUNTS AT THIS LOCATION ~~~~~i Largest Container o Daily Maximum o Daily Average LBS o 2500.00 LBS o 1250.00 LBS i~~~~~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS# 35.00oPortland Cement ONo o 65997151 4.00OTitanium Dioxide ONo o 13463677 oTSecreto RSOBioHazo Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP No ONo o No o No/ Curies o DH o / / / o o Min Inventory Item 0001 &~&~&~ Facility Unit: Fixed Containers on Site i&~ COMMON NAME / CHEMICAL NAME CERAMIC - MASTIC o Days On Site o 365 Location within this Facility Unit Map: Grid: SOUTH EAST CORNER o CAS# o 8030-30-6 STATE &~& TYPE &&&~&& PRESSURE &&&~ TEMPERATURE &&~&&&& CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER Largest Container o Daily Maximum o Daily Average GAL o 168.00 GAL o 84.00 GAL %Wt. o o RSo CAS# 5.00°Petroleum Naphtha ONo o 8030306 2.00°Ethylene Glycol ONo o 107211 °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP No ONo o No o No/ Curies o F DH o / / / o o Mod 2 06/14/1999 i BEDROSIANS ~~~~~~~~~ SiteID: 215-000-000645 i~ Inventory Item 0002 ~~~ Facility Unit: Fixed Containers on Site i~ COMMON NAME / CHEMICAL NAME o HYDRATED LIME o Days On Site o o o 365 o o Location within this Facility Unit Map: Grid: o SOUTH EAST CORNER o CAS# o o o 1305-62-0 o i~ STATE ~ TYPE ~2~ PRESSURE ~2 TEMPERATURE ~~ CONTAINER TYPE ~i o Solid o Mixture o Ambient o Ambient o BAG o i~~~~~~ AMOUNTS AT THIS LOCATION o Largest Container o Daily Maximum o Daily Average o o LBS o 2500.00 LBS o 1250.00 LBS o zeeeeeee~eeeeeeeeeeeeee HAZARDOUS COMPONENTS eeeeeeeeeeeeeezeeezeeeeeeeeeeeeeeei o %Wt. o o RSo CAS# o o 50.00°Calcium Oxide ONo o 1305788° o 5.00OCalcium Carbonate ONo o 471341° o 3.00oSilicon Dioxide ONo o 7631869° oTSecreto RSOBioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o o No ONo o No o No/ Curies o F IH o / / / o o Low o i~ Inventory Item 0005 &&&&~&&&&&&&&&& Facility Unit: Fixed Containers on Site i~ COMMON NAME / CHEMICAL NAME o MORTAR o Days On Site o o o 365 o o Location within this Facility Unit Map: Grid: o WAREHOUSE - SOUTH WALL NEAR EAST WALL o CAS# o o o 65997-15-1 i& STATE &~& TYPE &&&i&& PRESSURE &&&~ TEMPERATURE &&~&&&& CONTAINER TYPE o Solid o Mixture o Ambient o Ambient o BAG o i~~e~6~eeeeeeeeueeeeeeeeeeeeeeeueeeeeeeeeeeeeeeueeeeeeeeeeeeeeeeeeeeeeeee~ i&&&&&&&&&~&&&~~&&~i AMOUNTS AT THIS LOCATION o Largest Container o Daily Maximum o Daily Average o o LBS o 25000.00 LBS o 20000.00 LBS o ~~&~e~&~eeeeeeeeeeeeeeeueeeeeeeeeeeeeeeeeeeeeeeeeueeeeeeeeeeeeeeeeeeeeeeeee~ i~~i~&~~&~&~ HAZARDOUS COMPONENTS o %Wt. o o RSo CAS# o o 30.00oSilica, Crystalline ONo o 7631869° o 30.00oportland Cement ONo o 65997151° oTSecreto RSOBioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o No ONo o No o No/ Curies o IH o / / / o o Min o -3- 06/14/1999 BEDROSIANS ~~~~~~~~~ SiteID: 215-000-000645 ~ Inventory Item 0004 ~~~ Facility Unit: Fixed Containers on Site [ i~ COMMON NAME / CHEMICAL NAME ~~~~~~~~~~i PORTLAND CEMENT o Days On Site o o 365 o Location within this Facility Unit Map: Grid: ~~~~ WAREHOUSE - SOUTH WALL NEAR THE EAST WALL. o CAS# o. o 65997151 o i& STATE &~& TYPE &&&~&& PRESSURE &&&~ TEMPERATURE &&~&&&& CONTAINER TYPE &~&&&i Solid o Pure o Ambient o Ambient o BAG o Largest Container o Daily Maximum o Daily Average o LBS o 11000.00 LBS o 5600.00 LBS o i&&&&&A&~&&&&&&A&&&&&&& HAZARDOUS COMPONENTS eeeeeeeeeeeeeezeeezeeeeeeeeeeeeee i %Wt. o o RSo CAS# o 100.00oCement ONo o 65997151° oTSecreto RSOBioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o No ONo o No o No/ Curies o DH o / / / o o Min o ~~6~6~eeeeeueeeeeeeeeeeeeeeeeeeeueeeeeeeeeeeeeueeeeeeeeeueeeeeeeeueeeeef Inventory Item 0006 ~&~~&~ Facility Unit: Fixed Containers on Site i~ COMMON NAME / CHEMICAL NAME PROPANE o Days On Site LPG CYLINDERS 6 (5 GAL) o 365 Location within this Facility Unit Map: Grid: ??? o CAS# o 74_98_6 STATE &~& TYPE ~&&~& PRESSURE &&&i TEMPERATURE &&~$~&& CONTAINER TYPE Gas o Pure o Above Ambient o Ambient o PORT. PRESS. CYLINDER Largest Container o Daily Maximum o Daily Average 181.95 FT3 o 1091.70 FT3 o 500.00 FT3 ~&&&&&&~e&&eeeeeeeeeeeeeeeeueeeeeeeeeeeeeeeeeeeeeeeeeueeeeeeeeeeeeeeeeeeeeeeeeef %Wt. o o RSo CAS# 100.00opropane ONo o 74986 oTSecretO RSOBioHaz° Radioactive/Amount ° ,EPA Hazards o NFPA o USDOT# o MCP No ONo o No o No/ Curies o F P IH o / / / o o Hi -4- 06/14/1999 BEDROSIANS ~~&~&~&~&&~&~&&&&&&&&&&&&&&&&&&&&&&&& SiteID: 215-000-000645 Notif./Evacuation/Medical ~&~&~&~~&~&&&~~&~ Overall Site CALL 911 NOTIFICATION BY WORD OF MOUTH OR BY PA SYSTEM (4 EMPLOYEES) FOR THE EVACUATION OF THIS BUILDING - MANY' EXITS. THE BUILDING HAS SEVERAL EXITS AND NOTIFICATION CAN OCCUR EITHER BY WORD OF MOUTH OR OVER THE PA SYSTEM. PA SYSTEM ONE EMPLOYEE IS EMT-1. ~&~~eeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeef -5- 06/14/1999 BEDROSIANS ~~~~~&&&~~~~ SiteID: 215-000-000645 Mitigation/Prevent/Abatemt ~~~~~~~ Overall Site i~ Release Prevention ~~~~~~~~~ 01/23/1990 M~TERIJ~S J~E ENCLOSED IN PAPER BAGS (TILE GROUT - CEMENT - LIME) STACKED IN THE SOUTH EAST CORNER OF THE WAREHOUSE. OUT OF THE WAY. IF A BAG IS TORN OPEN WE CLOSE IT WITH TAPE, gAID SWEEP UP THE S3J.~VAGE. 6 06/14/1999 BEDROSIANS ~&~&~&&~&&&&~&&&&&&&&&&&&&&&~&&& SiteID: 215-000-000645 Site Emergency Factors &~&&&~&&&&~&~&~&~&~~&~~ Overall Site A) GAS - NORTHEAST CORNER OF BUILDING GROUNDS B) ELECTRICAL - SOUTHEAST CORNER SIDE OF BUILDING C) WATER - EAST SIDE OF BUILDING D) SPECIAL - NONE E) LOCK BOX - NO i&&&& Fire Protec./Avail. Water &&&&&&&&~&&~&~&&&&&&&&~&~&&&&~&~& 01/23/1990 FIRE HYDRANT - NORTHWEST CORNER OF BRUNDAGE LAlqE AND N STREET -7- 06/14/1999 BEDROSIANS ~&~~&~&&&~&&&&&~&&~&&~&A&&&~&~&& SiteID: 215-000-000645 Training ~&&&&~&&&~&~&&~&&~&~&&&&&&&&&&~&~&~&&&~&~&~&~&~ Overall Site i~ Employee Training ~~~&~&&~~~&~~~ 04/10/1996 WE HAVE 4 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: LOCATING MATERIAL DATA SHEETS, CAUTINING EMPLOYEES OF HANDLING HAZARDOUS MATERIALS. PROPER RESPONSES TO ACCIDENTS INVOLVING HAZARDOUS MATERIAL. HAZ-MAT BRIEFING AT THE TIME OF HIRE (FOUND IN THE NEW EMPLOYEE PACKET). aeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeee eel -8- 06/14/1999 Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE ........... ,,~=~,,.~,?~i:~.¥.?,?~?.~,~, ........ This permit is issued for the following: ..~?i?~!~::'i:.~ ~,,ii:!!:?:4:[i iiii!iil;~ ~iii!!! iiill i;":'::::i~;[il}i;e'~i~[ground Storage of ea~rdous Materials LOCATION 2701 ~-~, Is~ by:  B~e.field F~e D~ment Approv~ by: 1715 Chewer Ave., 3rd Floor e of~~ B~e~fiel~ CA 93301 Voice (805) 3~979 F~ (80S)~26-0S7~ Exp~tionDate: ~Un~ ~O~ ~O00 01/12/96 BEDROSIANS 215-000-000645 Page 1 Overall Site with 1 Fac. Unit General Information Location: 2701 BRUNDAGE LN Map:102 Haz:2 Type: 3 City : BAKERSFIELD Grid: 36C F/U: 1 AOV: 0.0 Contact Nam9 ~ Title Contact Name Title iC~.~CA'I,S.Ivg=-..~0~~,.:~ / MANAGER ~/~_1~ ~9~(~ ~ / WAREHOUSE Business Phone: (805) 324-5000x Business Phone: (805) 324-5000x 24-Hour Phone : (805)-~7%~1 24-Hour Phone : (805) Pager Phone : (~g)~-7~?x Pager Phone : ( ) - x Administrative Data Mail Addrs: 2701 BRUNDAGE LN D&B Number: City: BAKERSFIELD State: CA Zip: 93304- Comm Code: 215-003 BAKERSFIELD STATION 03 SIC Code: 5211 Owner: BEDRO~IANS Phone: (0o~) ~7~- Address: 4285 N State: CA City: FRESNO Zip: 93722- Summary RECEIVED ~PR 0 5 1996 HAZ. IvIAT. DIV. merit plan for ~~~% a~d that it along with (~e of Bm~) any ~rm~ions ~nstitute a ~mplete and mr~ man- agemg~ plan ~or my fadl~, 01/12/96 BEDROSIANS 215-000-000645 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-001 CERAMIC - MASTIC Liquid 168 Moderate ~ Fire, Delay Hlth GAL 02-002 HYDRATED LIME Solid 2500 Low · Fire, Immed/Hlth LBS 02-003 ~~~~;5~D~/~Q~D~ ~2~3~-- Solid 2500 Minimal · Delay Hlth LBS 01/12/96 BEDROSIANS 215-000-000645 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-001 CERAMIC - MASTIC Liquid 168 Moderate ~ Fire, Delay Hlth GAL ~CAS #: 8030-30-6 Trade Secret: No Form: L~uid Type: Mixture Days: 365 Use: ADHESIVE Daily Max GAL I Daily Average GAL I Annual Amount GAL 168 ~ 84.00 1,000.00 Storage ~~Press T Temp Location PLASTIC CONTAINER IAmbientlAmbientlSOUTH EAST CORNER -- Conc Components MCP ---7Guide 5.0% IPetroleum Naphtha IModeratel 27 2.0% Ethylene Glycol Low ! 27 -- Notes 02-002 HYDRATED LIME Solid 2500 Low ~ Fire, Inuned Hlth LBS CAS #: 1305-62-0 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: OTHER Daily Max LBSI Daily Average LBS I Annual Amount LBS 2,500 ~ 1,250.00 15,000.00 Storage~~Press T Temp Location BAG IAmbient~AmbientlSOUTH EAST CORNER -- Conc ! Components ! MCP ---~Guide 50.0%~lCalcium OxideIL°w ! 60 5.0% ICalcium Carbonate Minimal I 7 3.0% ISilicon Dioxide Minimal I 7 -- Notes 01/12/96 BEDROSIANS 215-000-000645 Page 4 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-003 F~_~{~A-~39fND ~iF.~T~,.%~-O ~,~O~D ~R~3~ Solid 2500 Minimal ~ Delay Hlth LBS CAS #: Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: OTHER Daily Max LBS Daily Average LBS I Annual Amount LBS 2,500 I 1,250.00 15,000.00 Storage Press T Temp Location BAG IAmbientlAmbientlEAsT RACK -Conc Components ~ MCP ---TGuide 35.0% Portland Cement ILow ~ 26 4.0% Titanium Dioxide IMinimal I 7 01/12/96 BEDROSIANS 215-000-000645 Page 5 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation NOTIFICATION BY WORD OF MOUTH OR BY PA SYSTEM (4 EMPLOYEES) FOR THE EVACUATION OF THIS BUILDING - MANY EXITS. THE BUILDING HAS SEVERAL EXITS AND NOTIFICATION CAN OCCUR EITHER BY WORD OF MOUTH OR OVER THE PA SYSTEM. <3> Public Notif./Evacuation PA SYSTEM <4> Emergency Medical Plan 01/12/96 BEDROSIANS 215-000-000645 Page 6 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention MATERIALS ARE ENCLOSED IN PAPER BAGS (TILE GROUT - CEMENT - LIME) STACKED IN THE SOUTH EAST CORNER OF THE WAREHOUSE. OUT OF THE WAY. IF A BAG IS TORN OPEN WE CLOSE IT WITH TAPE, AND SWEEP UP THE SALVAGE. <2> Release Containment <3> Cleap. Up <4> Other Resource Activation 01/12/96 BEDROSIANS 215-000-000645 Page 7 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS,-- NORTHEAST CORNER OF BUILDING GROUNDS B) ELECTRICAL - SOUTHEAST CORNER SIDE OF BUILDING C) WATER - EASy,SIDE OF BUILDING D) SPECIAL - NO~E E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION .... FIRE HYDRANT - NORTHWEST CORNER OF BRUNDAGE LANE AND N STREET <4> Building Occupancy Level 01/1R/96 BEDROSIANS 215-000-000645 Page 8 00 - Overall Site <G> Training <1> Employee Training WE HAVE 4 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY ~ TRAINING: LOCATING MATERIAL DATA SHEETS, CAUTINING ~PLOYEES OF HANDLING HAZARDOUS MATERIALS. PROPER RESPONSES TO ACCIDENTS INVOLVING HAZARDOU~ MATERIAL. ~ <2> Page 2 <3> Held for Future Use <4> Held for Future Use BAKERSfiELD CITY FIRE DEP. TMENT ~ HAZARDOUS MATERIALS INVENTORY page t__of~ Business Name ~:~t~',OS('~s Address "~7C~l ES~PA~'E L~+,YC CHEMICAL DESCRI~ION 1) IN~NTORY STA~S: New [ ] Add~on [~Re~sion [ ] ~letion [ ] Check, chemi~ ~ a NON ~DE S~R~ [~E SECR~ [ Ch,~ N~,: ~gTg~ 0~ F ~.M [ i CAS 4) PHYSICAL & H~L~ PHYSIC~ H~ H~D CA~RIES Fire [ ] Rea~e [ ] Sudden Rele~e of Pr~sure [. ] Immedl~e He~h ~e) [ ] ~y~ He~h (Chronic) s) WAS~ C~SS~F~C*~ON (~i.. ~ ~om OHS ~o~ ~0.~ USe CODe ~ff - ~ 6) PHYSICALSTAm Solid [~qu~ [ ] G~ [ ] Pure [~M~re [-] W~te [ ] m~b~ [ ] 7) AMOUNT ~D ~ME AT FAClU~ UNITS~SURE 8) STOOGE CODES M~mumOmNA~unt: [J~LbS I~ IH g~ Il ~a Il alco~nen Average D~N A~unt: ~~5 cu~s [ ] b) Pressure: AnnuN Amoum: ~~S ~T. c) Tem~r~um: ~gest Size'Cont~ner: ~ Da~ On SAe ~ Cimle~ich Momhs: ~J, F, M, A, M. J. J, A. S, O, N, D 9) MITRE: ~st COMPONENT CAS ~ % ~ AHM the three most h~dous I) [ ] chemi~ com~nen~ or ~y AHM com~nents 2) [ ] 3) [ ] CHEMICAL DESCRI~ION 1) IN~NTORY STA~S: New [ ] Add,ion [~sion [ ] Deletion [ ] Check ~ chemi~ is a NON ~DE SECR~ [~DE ~ECR~ [ ] Chemi~ Name: AHM [ ] CAS 4) PHYSICAL & H~L~ PHYSICAL H~ H~RD CA~GORIES Fire [ ] Ream~e [ ] Sudden Rele~e of Pressure [ ] Immedi~e He~h (Acme) [ ] ~layed He~h (Chron.) [ 5) WAS~ C~SSIFICA~ON (~igA code from DHS Fo~ 8022) USE CODE ~ - ~~i 6) PHYSICALSTA~ Solid [~Liquid [] G~ [ ] Pure [ ] Minute [~te I ] R.ioamNe [] 7) AMOUNT AND TIME AT FAClU~ UNITS~M~SURE 8) STOOGE CODES M~imum Daily Amount: ~ C~5 t~ [~ ga [ ] ~3 [ ] a) Cont=ner: Average Daly Amount: ~Oj ~ C~% curies [ ] b) Pressure: Annu~ Amount: ~ ~} ~ ~5 c) Tem~r~ure: ~gest Size Contmner: ~0 [b~ · DaysOnSAe .~ Circle ~ich Months: ~~ F, M, A. M. J, J, A. S, O. N. D the three most h~dous 1) ~~~ COMPONENT CAS · % ~ ~M chemi~ com~nenm or 3) l l ce~ under pen~ of law, ~at I have pe~on~ly examm~ ~d ~ f~ili~ w~ ~e mfoma~on suOmi~ on ~s ~d ~1 a~ch~ document. I believe submi~ in~a~on is ~e, accumm, ~d complem. I PRINTName&TitleofAuthorizedCompanyF~epresente~ve Signature Date Bedrosians New Employee Hazard Information & Briefing As a newly-hired Bedrosians employee, we would like to take this opportunity to brief you on the potential hazards of the materials you may be handling in the course of your work at Bedrosians. Materials are listed and described by category. The following is a listing of the material categories currently handled. Other categories may be added from time to time. All listed categories will be discussed further on the following pages: 1) Portland Cement 2) Cement-Based Thinsets & Mortars 3) Cement-Based Grouts 4) Hydrated Lime 5) Acrylic Latex Mastics 6) Acrylic Additives & Primers 7) Epoxy Mortar & Joint Filler 8) Solvent-Based Sealers 9) Cleaners & Strippers 10) Water-Based Sealers 11) Acid-Based Cleaning Agents 12) Polyurethane Coatings For each of the above-listed material categories, a representative product has been chosen. Its characteristics are described in detail in order to familiarize you with its potential hazards, if any. Definitions: The following information is included for each represemative product: I. Hazardous Ingredients: A listing of hazardous ingredients, and in some examples, the percentages of each ingredient II. Appearance & Odor: Identification information III. Fire & Explosion: Information on flammability, combustability, etc. IV. Health hazard information Health Hazard - Acute: An immediate health hazard - causing immediate physical problems or reactions as a result of overexposure to a hazardous material. 49 of 64 New Employee Policy Packet EMP 95-CA-2 Definitions: (Continued) IV. Health hazard information (Continued) Health Hazard- Chronic: A long-term health hazard - causing continuing physical problems as a result of extreme overexposure or repeated exposure to a hazardous material. V. First Aid: Steps to take in treating overexposure. Reference is usually made to MSDS sheets. VI. Reactivity: Characteristics of the products in the category as related to chemical stability, compatibility with other chemicals, etc. VII. Spill, Leak & Disposal Procedures: Information on what to do when a spill occurs as well as methods of disposal. VIII. Special Handling Information: Information on protective measures to be taken when handling spilled or leaked materials. Please be aware that products from different manufacturers in any one category may differ in composition and characteristics, eventhough the differences may not be significant. For detailed information on products from specific manufacturers, refer to the corresponding MSDS sheets found in your branch MSDS Binder. Products in the listed material categories usually come packaged in the following containers: Material Category Packaging Portland Cement Bags Cement-Based Thinsets & Mortars Bags Cement-Based Grouts Bags Hydrated Lime Bags Acrylic Latex Mastics Plastic Cans & Tubs Acrylic Additives & Primers Plastic, Bottles, Jugs & Tubs Epoxy Mortar & Joint Filler Units, Half Units (Boxed or in Tubs) Solvent-Based Sealers Plastic Bottles & Jugs Cleaners & Strippers Plastic Bottles & Jugs Water-Based Sealers Plastic Bottles & Jugs Acid-Based Cleaning Agents Plastic Bottles & Jugs Polyurethane Coatings Steel Cans Attention! As you can see, most products are sealed in containers, thus you will never inhale or come in contact with the actual materials contained therein. Only if a leak or spill occurs will inhalation or contact be possible. Of course, some products in categories like cements and grouts are packaged in bags. These containers can easily become compromised. Because of the possibility that you will inhale vapors/dusts or come into contact with one or more of these products in the course of your employment at Bedrosians, we are providing you with the following information so that you can take proper precautions whenever the need arises. New Employee Policy Packet EMP 95-CA-2 50 of 64 Portland Cement Portland cement is used to make a setting bed onto which are placed ceramic and stone tiles. (Product Described: - Mitsubishi Portland Cement) Hazardous Ingredients include: 1) Portland Cement (99.95%) & 2) Trace Metals (0.05%) Appearance & Odor: A grey powder with no odor Fire & Explosion: Not Combustible or Explosive Health Hazard Information: Effects of Overexposure Acute: Dry Cement - Eye Irritation & Upper Respiratory Tract Irritation FirstAid: See MSDS Sheets Reactivity: Stability: Stable Incompatibility: None; Hazardous polymerization will not occur Hazardous Decomposition: No hazardous products Spill, Leak & Disposal Procedures: Spill Response: Use dry cleanup method to minimize airborne dispersion. Waste Disposal: Material can be returned to container for later use, or disposed of as common waste. Special Handling Information: Respiratory Protection: When loading or unloading shipments of Portland cement by hand, a NIOSH approved dust mask (respirator) is recommended, especially if the immediate environment becomes dusty. Eye Protection: When loading or unloading Portland cement shipments by hand, tight-fitting goggles are recommended when the immediate environment becomes dusty. Skin protection: Use clothing (long sleeved shirts, gloves, etc.) to protect the skin from prolonged contact with Portland cement. Hygienic Practice: After working with Portland cement, employees should shower with water. 51 of 64 New Employee Policy Packet EMP 95-CA-2 Cement-Based Thinsets & Mortars Cement-Based Thinsets & Mortars are used to adhere tiles onto various types of substrates such as wood, concrete, etc. (Product Described: - Bostik/Hydroment Tile-Mate Premium Thinset) Hazardous Ingredients include: 1) Portland Cement (48.8%) & 2) Silicon Dioxide (Sand) (50.4%) - See specific MSDS sheets for others Appearance & Odor: A grey or white powder with no odor Fire & Explosion: Not Combustible or Explosive (Flash Point >200 degrees F - Closed Cup) Health Hazard Information: Effects of Overexposure Acute: Dry Thinset/Mortar - Eye Irritation & Upper Respiratory Tract Irritation Chronic: Dermatitis, Cumulative Lung Damage FirstAid: See MSDS Sheets Reactivity: Stability: Stable Materials to Avoid: Strong oxidizers Incompatibility: None; Hazardous polymerization will not occur Hazardous Decomposition Products: Fumes from complete or incomplete combustion may include carbon dioxide, carbon monoxide, water vapor, oxides of nitrogen and a wide variety of innocuous or toxic fumes. Spill, Leak & Disposal Procedures: Spill Response: Use dry cleanup method to minimize airborne dispersion. Sweeping compound may be used. Waste Disposal: Material can be returned to a container for later use if it has not been mixed with sweeping compound, or disposed of as common waste if it has. Cement-Based Thinset/Mortar has not been designated as a Hazardous Waste under U.S. Federal regulations. Special Handling Information: Respiratory Protection: When loading or unloading shipments of Cement-Based Thinset/Mortar by hand, a NIOSH approved dust mask (respirator) is recommended, especially if the immediate environment becomes dusty. Eye Protection: When loading or unloading Cement-Based Thinset/Mortar shipments by hand, goggles are recommended when the immediate environment becomes dusty. Skin protection: Use clothing (long sleeved shirts, gloves, etc.) to protect the skin from prolonged contact with the Portland cement in the Thinset/Mortar. Hygienic Practice: After working with Cement-Based Thinset/Mortar, employees should shower with water. New Employee Policy Packet EMP 95-CA-2 52 of 64 Cement-Based Grouts Cement-Based Grouts are used to fill in the spaces between applied tiles. (Product Described: - Bostik/Hydroment Ceramic Tile Sanded Grout) Hazardous Ingredients include: 1) Portland Cement (30-40%), 2) Silicon Dioxide (Sand) (60-70%), & 3) Titanium Dioxide (0.5-5%) - See specific MSDS sheets for others Appearance & Odor: A white or colored powder with no odor Fire & Explosion: Not Combustible or Explosive Health Hazard Information: Effects of Overexposure Acute: Dry Grouts - Eye Irritation & Upper Respiratory Tract Irritation Chronic: Dermatitis, Cumulative Lung Damage FirstAid: SeeMSDS Sheets Reactivity: Stability: Stable Materials to Avoid: Strong oxidizers Incompatibility: None; Hazardous polymerization will not occur Hazardous Decomposition Products: Fumes from complete or incomplete combustion may include carbon dioxide, carbon monoxide, water vapor, oxides of nitrogen and a wide variety of innocuous or toxic fumes. Spill, Leak & Disposal Procedures: Spill Response: Use dry cleanup method to minimize airborne dispersion. Sweeping compound may be used. Waste Disposal: Material can be returned to a container for later use if it has not been mixed with sweeping compound or other contaminant, or disposed of as common waste if it has. Cement-Based Grouts have not been designated as a Hazardous Waste under U.S. Federal regulations as of 2-4-91. Special Handling Information: Respiratory Protection: When loading or unloading shipments of Cement-Based Grouts by hand, a NIOSH approved dust mask (respirator) is recommended, especially if the immediate environment becomes dusty. Eye Protection: When loading or unloading Cement-Based Grout shipments by hand, goggles are recommended when the immediate environment becomes dusty. Skin protection: Use clothing (long sleeved shirts, gloves, etc.) to protect the ' skin from prolonged contact with the Portland cement in the Grout. Hygienic Practice: After working with, Cement-Based Grouts, employees should shower with water. 53 of 64 New Employee Policy Packet EMP 95-CA-2 Hydrated Lime Hydrated Lime is used as a component of mortar which is used as a substrate for the application of tiles. (Product Described: - Chemstar, Inc. Dolornitic Hydrated Lime) Hazardous Ingredients include: 1) Calcium Hydroxide (50%), 2) Magnesium Hydroxide (35%), & 3) Calcium Carbonate (<8%) - See specific MSDS sheets for others Appearance & Odor: A soft, white, crystalline powder with a mild, distinct odor Fire & Explosion: Not Flammable or Explosive Health Hazard Information: Effects of Overexposure Acute: Dry Lime - Eye Irritation & Inflammation of Respiratory Passages Wet Lime (reacting with perspiration) - Skin Irritation Chronic: Dermatitis, Chemical Bums, Cumulative Lung Damage FirstAid: See MSDS Sheets Reactivity: Stability: Stable - Hazardous polymerization will not occur Materials to Avoid: Acids, Ammonium Salts, Phosphorus, & Some Organic Compounds Decomposition Products: When exposed to air, this strongly alkaline compound will absorb and react with carbon dioxide, producing calcium carbonate. Calcium and magnesium salts are normal reaction products with other materials. Conditions to be Avoide& Contact with nitroparaffins, maleic anhydride or phosphorus. Spill, Leak & Disposal Procedures: Spill Response: Use dry cleanup method to minimize airborne dispersion. Sweeping compound may be used. Waste Disposal: Material can be returned to a container for later use if it has not been mixed with sweeping compound or other contaminant, or disposed in metal containers if it has. Lime can also be disposed of in alternate ways. Refer to the MSDS sheets. Special Handling Information: Respiratory Protection: When loading or unloading shipments of Hydrated Lime by hand, a NIOSH approved dust mask (respirator) is recommended, especially if the immediate environment becomes dusty. Eye Protection: When loading or unloading Hydrated Lime shipments by hand, goggles are recommended when the immediate environment becomes dusty. Skin protection: Use clothing (long sleeved shirts, gloves, etc.) to protect the skin from prolonged contact with the Lime. Hygienic Practice: After working with Hydrated Lime, employees should shower with water. New Employee Policy Packet EMP 95-CA-2 54 of 64 Acrylic Latex Mastics Acrylic Latex Mastics are used to adhere tiles to a substrate such as wood, gypsum board, concrete, etc. (Product Described: - Bedrosians 9000 Ceramic Tile Adhesive) Hazardous Ingredients include: Mineral Spirits (3%) - See specific MSDS sheets for others Appearance & Odor: A white paste with a mild acrylic odor Fire & Explosion: Not Flammable or Explosive Health Hazard Information: Effects of Overexposure Acute: Nose & Throat Irritation, Dizziness, Nausea and Headache Mild Eye or Skin Irritation FirstAid: See MSDS Sheets Reactivity: Stability: Stable - Hazardous polymerization will not occur Materials to Avoid: None Known Decomposition Products: None Known Conditions to be Avoided: None Known Spill, Leak & Disposal Procedures: Spill Response: Use absorbant material to collect or contain for salvage or disposal. Waste Disposal: Material can be returned to a container for later use if it has not contaminated, or disposed in metal containers if it has. Special Handling Information: Respiratory Protection: None should be needed. Eye Protection: None required if containers are intact. Use goggles if material has been spilled. Skin protection: None required. 55 of 64 New Employee Policy Packet EMP 95-CA-2 Acrylic Additives & Primers Acrylic Latex Additives are mixed with cement-based thinsets to create thinsets with greater strength, etc. Acrylic Latex Primers are used to coat concrete to aid in bonding tiles to concrete using thinset. (Product Described: - Bost#c/Hydroment Acrylic Latex Additive) Hazardous Ingredients include: None - See specific MSDS sheets for others Appearance & Odor: A white fluid with an acrylic odor Fire & Explosion: Not Flammable or Explosive Health Hazard Information: Effects of Overexposure Acute: None Known Chronic: None Known FirstAid: See MSDS Sheets Reactivity: Stability: Stable - Hazardous polymerization will not occur Materials to Avoi& Strong Oxidizers Hazardous Decomposition Products: Fumes from complete or incomplete combustion may include carbon dioxide, carbon monoxide, water vapor, oxides of nitrogen and a wide variety of innocuous or toxic fumes. Spill, Leal~ & Disposal Procedures: Spill Response: Soak up liquid with absorbant material such as sand or sweeping compound. Package absorbant material in steel drums which are in good condition. Thoroughly clean area where spill occurred. Be aware that this mixture contains some ammonia which may require ventilation prior to clean-up or the use of a self-contained breathing apparatus. Waste Disposal: See MSDS sheets. Special Handling Information: Resp#'atory Protection: Not necessary unless a spill has occurred. Eye Protection: None required if containers arc intact. Use goggles if material has been spilled. Skin protection: Gloves should be worn during spill or leak response. New Employee Policy Packet EMP 95-CA-2 56 of 64 Epoxy Mortar & Joint Filler Epoxy Mortar & Joint Filler is used to adhere files to a substrate such as wood, concrete, etc. or to fill in the spaces between applied tiles. (Product Described: - BostilVHydroment Colorpoxy #3) Hazardous Ingredients include: 1) Quartz (54.3%), 2) Bisphenol A Epoxy Resin (15%), 3) Titanium Dioxide (9.5%), 4) Tall Oil, Tetraethylenepentamine Reaction Products (8.2%), 5) Amorphous Silicon Dioxide Hydrate (3.4%) - See specific MSDS sheets for others Appearance & Odor: A colored paste with a solvent odor Fire & Explosion: Flash Point: >200 degrees F. (Closed Cup) Upper Explosive Limit: 6.7% (Calculated) Autoignition Point (Vapors): 751 degrees F. (Calculated) Health Hazard Information: Effects of Overexposure Acute: Eye & Skin Irritation & Upper Respiratory Tract Irritation Chronic: Dermatitis, Cumulative Lung Damage FirstAid: See MSDS Sheets Reactivity: Stability: Stable Materials to Avoid: Strong alkalis, Strong Acids Hazardous Polymerization: Will not occur Hazardous Decomposition Products': Fumes from complete or incomplete combustion may include carbon dioxide, carbon monoxide, water vapor, oxides of nitrogen and a wide variety of innocuous or toxic fumes. Aldehydes may also be produced. Spill, Leal; & Disposal Procedures: Spill Response: Soak up liquid with absorbant material such as sand or sweeping compound. Package absorbant material in steel drums which are in good condition. Thoroughly clean area where spill occurred. Waste .Disposal: See MSDS sheets. Special Handling Information: Respiratory Protection: Not Necessary. Eye Protection: None required if containers are intact. Use safety glasses if material has been spilled. Skin protection: Neoprene Rubber or Impervious Plastic gloves should be worn during spill or leak response. 57 of 64 New Employee Policy Packet EMP 95-CA-2 Solvent-Based Sealers & Polishes Solvent-Based Sealers & Polishes are used to coat the top of unglazed ceramic, concrete or clay tiles, etc. They provide a clear, glossy or semi-glossy surface treatment. (Product Described: Aqua-Mix Sealer's Choice) Hazardous Ingredients include: 1,1,1, Trichloroethane - See specific MSDS sheets for others Appearance & Odor: A clear liquid with a mildly sweet odor Fire & Explosion: Not Flammable or Explosive Health Hazard Information: Effects of Overexposure Acute: Liquid or mist may irritate the eyes, nose and throat, or dry the skin. Chronic: Central Nervous System Damage, Blindness, damage to Liver, death. FirstAid: See MSDS Sheets Reactivity: Stability: Stable - Hazardous polymerization will not occur Materials to Avoid: Strong Alkalis and Oxydizing materials. Hazardous Decomposition Products: Fumes from complete or incomplete combustion may include carbon dioxide, carbon monoxide, hydrogen chloride and chlorine gas. Spill, Leak & Disposal Procedures: Spill Response: Contain by diking and soak up liquid with sand or other non-combustible material. If spill is large, pump into DOT approved waste containers. If small, mop or wipe up and dispose of in DOT approved waste containers. Keep out of sewers, storm drains, surface waters and soils. Thoroughly clean area where spill occurred. Waste Disposal: See MSDS sheets. Special Handling Information: Respiratory Protection: Use a self-contained breathing apparatus in the pressure demand mode for large spills or, if necessary, a full face piece, air purifying cartridge respirator equipped for organic vapors for small spills. Eye Protection: Use goggles if material has been spilled. Skin protection: Neoprene gloves, boots and apron should be worn if there is significant spillage. New Employee Policy Packet EMP 95-CA-2 58 of 64 ~ Cleaners & Strippers Cleaners and Strippers are used to remove old sealers, waxes and polishes from tiles. (Product Described: - Glaze 'N Seal Stripper) Hazardous Ingredients include: 1) Methylene Chloride, 2) Methanol, 3) Toulene, 4) Ethylene Glycol & 5) Butyl-Ether - See specific MSDS sheets for others Appearance & Odor: A clear liquid with a mild chararcteristic odor at 70 degrees F. Fire & Explosion: Flash Point: No flash to boiling point Boiling Point: 104 degrees Health Hazard Information: Effects of Overexposure Acute: Excessive inhalation or ingestion may produce symptoms of central nervous system distress - depression, light-headedness to unconsciousness and death. Chronic: Can cause headaches, mental confusion, depression, nausea, vomiting, cough, & dermatitis. First~lid: SeeMSDS Sheets Reactivity: Stability: Stable Conditions to Avoid: Excessive high temperature, open flames, excessive hydraulysis. Materials to Avoid: Aluminum, Sodium, Potassium, & Magnesium Hazardous Polymerization: Will not occur Hazardous Decomposition Products: Exposure to open flames will generate Hydrogen Chloride and small amounts of Phosgene and Chlorine. Spill, Leak & Disposal Procedures: Spill Response: ' Large Spills: Contain by diking and soak up liquid with sand or other non-combustible material. Pump into DOT approved waste containers. Small Spills: Mop or wipe up and dispose of in DOT approved waste containers. Keep out of sewers, storm drains, surface waters and soils. Thoroughly clean area where spill occurred. V~aste Disposal: See MSDS sheets. Special Handling Information: Respiratory Protection: Use a NIOSH approved respirator for solvent vapors. Eye Protection: Use goggles if significant amount of material has been spilled. Skin protection: Impervious gloves should be worn. Neoprene boots and apron are recommended if there is significant spillage. 59 of 64 New Employee Policy Packet EMP 95-CA-2 Water-Based Sealers Water-Based Sealers are used to coat the tops of unglazed concrete or clay tiles, etc. They provide a clear, glossy or semi-glossy surface treatment. (Product Described: Glaze 'N Seal Waterbase Conc. & Masonry Sealer) Hazardous Ingredients include: 1) Diethylene Glycol, 2) N-Butyl Ether, 3) N-Butoxypropanol, 4) Diethylene Glycol Methyl Ether - See specific MSDS sheets for others Appearance & Odor: A clear liquid with a mildly sweet odor Fire & Explosion: Non-Combustible Health Hazard Information: Effects of Overexposure Acute: Liquid or mist may irritate the eyes, nose and throat, lungs, or dry the skin. Can cause slurred speech, headache, nausea, vomiting, marcosis, diziness, stupor and unconsciousness. Chronic: Liver or Kidney damage FirstAid: See MSDS Sheets Reactivity: Stability: Stable - Avoid temperatures above 350 degrees F. Hazardous Polymerization: Will not occur Materials to Avoid: Not Applicable. Hazardous Decomposition Products: Not Applicable. Spill, Leak & Disposal Procedures: Spill Response: Contain by diking and soak up liquid with sand or other non-combustible material. If spill is large, pump into DOT approved waste containers. If small, mop or wipe up and dispose of in DOT approved waste containers. Keep out of sewers, storm drains, surface waters and soils. Thoroughly clean area where spill occurred. Waste Disposal: See MSDS sheets. Special Handling Information: Respiratory Protection: Use a NIOSH approved respirator. Eye Protection: Use goggles if significant amount of material has been spilled. Skin protection: Protective gloves should be worn. Long-sleeved shirt, Neoprene boots and apron are recommended if there is significant spillage. New Employee Policy Packet EMP 95-CA-2 60 of 64 Acid-Based Cleaning Agents Acid-Based Cleaning Agents are used to clean tiles of grout residue, and other discoloration from foreign matter, etc. (Product Described: Glaze 'N Seal Phosphoric Acid Cleaner) Hazardous Ingredients include: Phosphoric Acid (20%) - See specific MSDS sheets for others Appearance & Odor: A green/clear liquid with a slightly acidic/citrus odor Fire & Explosion: Non-Combustible Boiling Point: 210 degrees Health Hazard Information: Effects of Overexposure Acute: Slight skin and eye irritation FirstAid: See MSDS Sheets Reactivity: Stability: Stable Hazardous Polymerization: Will not occur Materials to Avoid: Highly Alkaline Chemicals Hazardous Decomposition Products: Not Applicable Conditions to Avoid: Sulfides and sulfites which could release toxic gases. Spill, Leak & Disposal Procedures: Spill Response: Contain by diking and soak up liquid with sand or other inert material. Sweep up and dispose of in DOT approved waste containers. Thoroughly rinse area where spill occurred. Waste Disposal: See MSDS sheets. Special Handling Information: Respiratory Protection: No special requirements under normal use conditions. Eye Protection: Use chemical safety goggles if significant amount of material has been spilled. Skin Protection: Protective gloves should be worn. Long-sleeved shirt, Neoprene boots and apron are recommended if there is significant spillage. 61 of 64 New Employee Policy Packet EMP 95-CA-2 Polyurethane Coa s Polyurethane Coatings are used to adhere tiles to a substrate such as wood, gypsum board, concrete, etc., or used as apply-on vapor barriers. (Product Described: - Bostik/Hydroment Ultra-Set) Hazardous Ingredients include: 1) Calcium Carbonate (32.9%), 2) Xylene Xylol (2.9%), 3) Calcium Oxide (1.1%), 4) 2,4-Toluene Diisocyanate (0.6%), & 5) 2,6-Toluene Diisocyanate* (0.2%) - See specific MSDS sheets for others * A suspected cancer hazard Appearance & Odor: A thick paste with a significant odor Fire & Explosion: Combustion Liquid Flash Point: 145 degrees F. (Closed Cup) Lower Explosive Limit: 1.0% (Calculated) Upper Explosive Limit: 6.86% (Calculated) Autoignition Point (Vapors): 947 degrees F. (Calculated) Autoignition Point (Solids): Not Available Health Hazard Information: Effects of Overexposure Acute: Sinusitis, Dry Throat, Breathing Difficulties, Bronchitis, Coughing, Nausea, Possible Eye Injury. Chronic: Lung Impairment, Respiratory Sensitization Medical Conditions Aggrevated By Exposure: Asthma, Respiratory Disease, Conjunctivitis First~lid: See MSDS Sheets Reactivity: Stability: Stable Materials to Avoid: Strong Oxidizers, Alkalis, Acids, Alcohols, Amines, Water Temperatures > 200 degrees F. Decomposition Products: Fumes from complete or incomplete combustion may include carbon dioxide, carbon monoxide, water vapor, oxides of nitrogen or a wide variety of innocuous or toxic fumes. Aldehydes, Hydrogen Chloride, Hydrogen Cyanide, Sulfur Dioxide, & Toluene Diiosocyanate may also be produced. Hazardous polymerization: Can occur with water, amines, alkalis, etc.. Spill, Leak & Disposal Procedures: Spill Response: Soak up liquid with absorbant material such as sand. Package absorbant material in steel drums which are in good condition. Thoroughly clean area where spill occurred. Waste Disposal: See MSDS sheets. This product contains Vinyl Chloride (lppm) and is considered a Hazardous Waste - EPA # D043. Special Handling Information: Respiratory Protection: Use a NIOSH approved respirator during spill clean-up. Eye Protection: Use safety glasses if significant amount of material has been spilled. Skin protection: Protective gloves should be worn. New Employee Policy Packet EMP 95-CA-2 62 of 64 Spill and Leak Clea - p (Emergency Response Refer to appropriate MSDS Sheets in MSDS Binder for guidance in cleaning up spills & leaks. If the spill is large, refer to your Emergency Response Plan found in the red binder (if your branch is required to have one). Leak and Spill Reporting All spills and leaks must be reported to your branch manager. Branch managers must log each incident in the ERP Use record found in the Emergency Response Plan Binder (if your branch is required to have one). For Additional Information! If you have any other questions concerning any of the above-mentioned material categories, feel free to ask your branch manager or contact Ara J. Movsesian in Fresno. 63 of 64 New Employee Policy Packet EMP 95-CA-2 !30 'G~ STREET ~_.~Z__.. (805) 32e-~n79~ ~ ~' ~ i' I HAZARDOUS MATERIALS RECEIVED BUSINESS PLAN AS A WHOLE fiPR 1 8 1989 '"' FORM INSTRUCTIONS: ..... I .. To avoid further action, return this from within 2. TYPE/PRINT ANSWERS 'IN ENGLISH. 3. Answer the questions below for the busines~ a~ a ~hole. · "-4. Be as brief and concise a~ possible.. :- SECTION ): BUSINESS IDENTIFICATION DATA ..... g. LOCATION / STREET ADDRESS: ~Q~ ( ,SECTION 2: EMERGENCY NOTIFICATIONS In case of an e~ergency involving a hazardous ma.teriat, call 911 and I-See-SSZ-?SS~ on l-~16-427-43~I. This ~ill notify your local fine depar!~eni and ih~ State Off~ce o~ E~ergency Services as required by la~. EMPLOYEES TO NOTIFY IN CASE DF EMERGENCY: NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS. - 0 SECTION 3~ LOCATION OF UT~E)TY SHUT-OFFS FOR BUSINESS AS A aHQLE O. S'PEC!fiL: E. LOCK BOX: YES /~ iF YES, LOCATION; iF YES~ DOES IT CONTAIN SITE PLANS? YES / NO MS,SS? YES / NO FLOOR PLaiNS? YES / NO KEYS? YES / NO SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS 8S ~ WHOLE SECTION S: LOCAL EMERGENCY MEDICAL 8SS!STANCE FOR YOUR BUSINESS 8S A WHOLE SEOTION G: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE h TRAINING PROGRAM WH!CH PROUIDES EMPLOYEES WITH INITIAL ANO REFRESHER TRAINING IN .THE SAFE HANOL!NG OF HAZARDOUS M6TER I ALS, ~ H A. NUMBER OF EMPLOYEES AT THIS FhOIL!TY DO YOU ~au[ MSDS (MaTSR~aL SaF~T~ O~Ta SHEETS) FOR EaC..aza~oous M6TERI6L YOU C. GIVE A 8RIEF SECTION 7: .[X~UPTION REquEST /~2~J~ ' I CERTIFY UNOER PENALTY OF PERJURY THET MY BU,!NESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF OHAPTER G.gS OF THE CALIFORNIA HEALTH 8N0 SAFETY C00E FOR THE FOLLOW!NG EEASONS: WE 00 NOT HANOLE HEZ~ROOUS MATERIALS. WE 00 HANOLE HAZAROOUS METER!ALS~ BUT THE qUANTITIES ~T NO TIME EXCEEO THE MINIMUM REPORTING qUANTITIES. OTHER (SPECIFY REASON) SECTION 8: OERTIFICATION I,_~E ~~~. ...... , ~ti?y that th~ ~bov~ information accuratm. I undmr~tand that thi~ in?orMation will bm used to ?u!?ill ~irM~s obligations u~dmr thm n~w Ca!i~oroi~ H~lth ~od Sa~ty ood~ Haz~rdou~ Mat~rial~ (Oiv ~ Chapter G gS S8~. 2SS~ Et 8! ) and that in~ocurat~ information constitut~ ~m~jur~. ' SZGNRTURE~~' T~TLE .~¢~- DATE BAKERSFIELD CiTY FiRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 08301 0FFTCiAL USE ONLY · BUSINESS NAME: BUSINESS PLAN siN r. . .... · . .- ..... :'.-::::-'. ~--',-' >-. ¥~!:~ ...... :+ '..-: .:¥:': '..'.'.--:,[:~,'-:":.:'~i' ' ' ' :FACi '~_~ I'Ty' T' '" '""" "": '"" ..... ' FORM 3A INSTRUCTIONS :" ' ....... ':'~. "~nswev the 'questions below for THE FACILITY UNIT LISTED BELOW ' "' · -~. Be'as BRIEF and CONCISE '~S possible.' .... ' " SECTION 1: MITIGATION~ PRE~ION~ ABATEME~ PROCED~ES SECTION 2: NOTIFICATION AND EVACUATION PROCEDURES AT THIS UNIT ONLY SECTION 3: HAZARDOUS MATERIALS FOR THIS bqNiT ONLY A. Does this Facility [_init contain Haz~:'dous MaterSa!s? .... If YES, see B. ~.~ . If NO, continue with SECTION ~. ':"::" '" B. A~ie ;my of the hazardous mate?iais ~ bona fide T:ade ] ...... "-' If No, compl'ete a SeParate hazardbus materials inventory' ·" ~ "" ..... ."": ' ' form marked: NON-TRADE SECRETS ONLY (white form =4A-l) If Yes, complete a hazardous materials inventory form marl<ed: T~DE.SECRETS. ONLY (~ello~ form ~4A-2.) in addition to the non-trade ..... .~ ' C. WATER D, SPECIAL: BOX: YES /~IF YES, LOCATION: E. LOCK IF VES, SITE PLANS? YES .i NO, MSDSs? YES NO, FLOOR PLANS? YES / NO KEYS? YES / .YO 3B CITY of BAKER SFIELD ~r, ,nd Aqricuhu.e ~-- Standard ~s~ness '---= ~A~R~O~ ~A~~ A~ ~ ~~~.O~ NON--TRADE SECRETS ' ~,ge.._of. _ BUSINESS N~M~:~C~/~ , xOWNER NAME: *O~ CJ ~'d t NAME OF T~ FACILITY: LOCATXO~: ~.~t ~~~_ ~e ~ ADDreSS: ~T ~¢. ~-~/ ~F~ STA,DAR~ r~D. CLASS COD~ CITY, ZIP: ~C~~g ~ ~3o~ CITY, ZIP: · FF~ c~' ¢37~ DUN AND BRADSTREET NUMBER ~ ~0 I~s~UC~zo~ FOR PROP~ COD~ t ~ { 4 5 S 7 8 g I0 11 12 13 li Trnns Type ~x iwra~l ~nual ~asu~ I ~ Cml ~t ~t hi L~ttm M~re t ~ Nam of N~xtuq/~ts C~e C~e ~t ~t Est Units m Stte TyN Prig Trap C~ .. Stor~ ~n Fac~llty' Nt ~ Instwct~ms .~_ml.._t~_g___l .... ~q__l ~ ~~~~~F c~>z~h~. .... f~O~fk ~_ c_~ Fire Hazard [--J Reactivity [ ] ~]a~Heaith[2] ~of P~relel~se u_J [~tltlH~lth I O~ ~[- ~ - ~t 13 ~AC.A.S. H~}th of P~ ~Jth Had } th of P~su~ Had }th .... L_t ....... , L, .... ......... ~ ...... -_j ~__t__L~_~ ..... t P~ical ~ HHlth Hazaed C.A.S. N~r Cm~t Il Nm & C.l.S. N~ (C~k all t~t apply) ...................... ~--~ -- r--~ -- r--~ C~t 12 Nm i C.A.S. N~P Fire Hazard [ ~ R~ctivity ~_a ~lay~ ~ ~ ~dd~ Release ~_a I~tate Health of Presume Health ...... ' ....... b~t l{ Nm & C.l.S. Numar Certificati~ (Read and sign after compJetJng al] sections) [ certify unde, ~alty of 1~. t~t I ~ve ~,s~elly exa~in~ and ~, fe,ili;, .tth t~ infor~tim su~itt~ in ~is a~ ~~ gm~;s, and t~t ~s~ m W in~ui.y of t~e J~ivi/ll; for obtainin9 t~ infor.ti., I ,lieve t~t t~ su.itt, infor, tim is true, accurate, and c.~ ~/ ~// ~~~-~/-/~ ~ March ~5, t989 TO: Nina Meyer, Accounts Receivable FROM: Ralph E. Huey, Haz Mat Coordinator SUBJECT: Haz Ma~ Billing Please cancel the billing for Monarch Tile MPg, %his business has changed names and ownership. The new business name is 8edrosians~ and we will bm bill ~he~ in our second billing. But, ~or thm %ime being ~e will void this account. 6ccoun% 00645. Th~nk you ~or all your help in ~his /~. ~ BAKERSFIELD CI~ FIRE DEPARR~NT 2130 "O" S~EET JUL ~ ' B~RSFIELD, CA 93301 l~s'd ..... (805) 326-3979 ....... OFFICIAL USE ONLY v BUSINESS HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE FORM 2A INSTRUCTIONS: 1, To avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. ~nswec the questions below for the business as a ~hole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDE~IFICATION DATA A. BUSINESS NAME: ~~Q~C~ -' %-,0 ~e ~ CITY~~k~~; ~[~ ZIP: q~C)~ BUS.PHONE: (~ SECTION 2: EBiERGENCY NOTIFICATIONS In ~ase of an emergency involving the release GU threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAr'It~ AND TITLE DURING BUS..HRS. ( SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: ~4~T ~ '{~l.,~/'.~o~a~... ~ ~0~' 1~ ~ B. ELECTRICAL: C. WATER: ~ ~ D. SPECIAL: E. LOCK BOX: YES /~IF YES, ~OCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 2A - SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE t SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAZARDOUS MATERIALS:.... .................................... ~Y~ NO YES NO B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGENCIES: ................. ~ ......... ~NO YES NO C. PROPER uSE OF SAFETY EQUIPMENT: .................. {~NO 'YES NO D. EMERGENCY EVACUATION PROCEDURES: ................. ~/J/,~ YES NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... YESN~ YES NO SECTION ?: HAZARDOUS MATERIAL CIRCL~OR NO DOES YOITI~BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN ...... 500 POUND. S_OF SOLID, $5 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: I,,~~5 g)_ ~-~W ~e(-' , certify that the above information is accurate. I understand that th~s information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. Z0 Chapter 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. .BAKERSFIELD CITY FIRE DEP~TMENT 2130 "G" STREET BAKERSFIELD, CA 93301 0FFICiAL USE ONLY ID# BUSINESS NAME: BUSI NESS PLAN SINGLE FACILITY UNIT FORM SA INSTRUCTIONS 1. To avoid further action, this form must be refurned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be'as BRIEF and CONCISE as possible. FACILITY UNIT# / FACILITY UNIT SECTION 1: MITIGATION, PRE~ION, ABATEMENT PROCED~ES SECTION 2: NOTIFICATION AND EVACUATION PROCEDURES. AT_ THIS UNIT ONLY - 3A - SECTION.3: HAZARDOUS MATERIALS FOR THIS UNIT ONLY ' A. Does this' Facility~ Unit contain Hazardous Materials? ...... Y~ NO If YES., see B. If NO, continue with SECTION 4, B. Are any of the hazardous materials a bona fide Trade Secret YES ~ If No, complete a separate hazardous' materlals inventory . form marked: NON-TRADE SECRETS ONLY (white form #4A-1) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form ~4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION SECTION ~: LOCATION OF WATER SUPPLY FOR USE BY E~RGENCY RESPO~ERS SECTION 6: LOCATION OF UTILI~ S~T-OFFS AT THIS UNIT ONLY. A. NAT. GAS/PROPAN~ o. SPECIAL: E. LOCK BOX: YES IF YES, LOCATION: IF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 3B - BAKERSFIELD CITY FIRE DEPARTMENT ~x .,~ I.D. # FORM 4A-1 Page NON--TRADE SECRETS "~ HAZARDOUS MATERX ALS INVENTORY BUSINESS NAME: ~om~N C~,c ~ OWNER NAME: ~o~M ~ FACILITY UNIT ~: .... ONLY . . . 1 2 3 4 5 6 7 8 9 "16 TYPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD ~D;0.T CODE AMOUNT AMOUNT UNIT CODE [CODE FACILITY UNIT WT. CHEMICAL O~ COMMON N~ME CODE ~OUIDE TITLE S~GNATURE: : EMERGENCY ~ __T~TLE ~ PNONE ¢ BUS  AFTER ~US SITE/FACILITY DIAGR-Zkl~ (CHECK ONE) SITE DXAGR~M FACrnITV DrAGR.~M / (Inspector's Comments): -OFFICIAL USE ONLY- - SA - SITE DIAGRAM (Requl~teas) 1. Address: Identify the 9. Lock (key) Box principle buildings by the Street numbers. 10. MSDS Storage Box 2, Street(m), Alleys, ~11, Railroad Track. Drlveway., and Parking Areas adjacent to the 12. Fence or Barrier property, Include the a. Wire street names, b. Masonry 3. Storm Drains, Culverts. Yard Drains c. Wood 4, Drainage Canals. Ditches. d. Gates Creeks. 13, Powerllnes 5. Buildings a. Frame construction 14. Guard Station b. Masonry construction IS. Storage Tanks: Identify the c. Metal construction capacity in gal.. a. Above ground d. Access Door b. Underground 6. Utility Cnntrols a. Gas 16. Diking or Berm b. Electricity 17. Evacuation Route c. Water 18. Evacuation Area: Identify the ?, Fire Suppression Systems: location where a. Fire Hydrants employees will meet. b. Fire Sprinkler 19. Outside Hazardous Connections Mast. Storage ,c. Fire standpipe 20. Outlide Hazardous Connections Material Storage d. Water Control Valves 21. Outside Hazardous for protection systems Material Use/Handling e. Fire Pump RM. Type of Hazardous Material/Waste Stored 8. Fire Department Access or Used (See Below) Type oF ~AZ~UOus NATERIA~ F - Flammable E - Explosive L - L/qu/d R - Radiological C - Corrosive 0 · Oxidizer O - Gas P - Poison W - Water Reactive T - Toxic g - Solid H - Cryogenic D - Waste B - Etiological Example: Flammable Liquid · FL FACILITY DIAGRAM (Required items in addition to the above) 1. Rimers for Sprinklers H. Fire glcapea 2. Partitions 0, ALt Conditioning Units 3. Stairways: Indicate the 10. Windows levels served free highest to lowest. 11. Inside Hazardous Waste Storage 4. Escalator: Indicate the levels served from '12. Inside Hazardous higheet to low, et. Materials Storage S. Elevator 13.* Inside Hazardous Mmterieis Uae/Handling 6. Attic Access 14. Sewer Drain Inlets T. Skylights Bedrosians Ms. Sarah Kobzeff ~825 N. Motel Drive Fresno, Ca. 9J722 Dear Ms. Kobzeff Per our discussion yesterday, March 14, 1989, in a recent £nspection of your facility located at 2701 BrundaGe Lane, Bakersfield, Oa. 9J~04, it was determined that your company does in fact handle Hazardous materials. You also handle these materials in reportable quantities aa defined by Chapter 6.95 of the California Health and Safety Code, Your business is therefore required to complete a Hazardous Materials Business Plan. This plan was due within ~0 days of Bedrosians taking over the previous business, Monarch Tile Company previously located at that address. We have previously sent new business plan forms under separate cover to the business address on Brundage Lane. I am enclosing an additional set with this letter. 8tthouGh you are late in filing we will extend the due date until 8pril l~, 1989. If we can be of any assistance please don't hesitate to call. The previous bill for Monarch Tile's Hazardous Materials Handling Fee has been voided, You are not liable for the Monarch fee. This bill was for the fiscal year 1988, 1989, a b~itin9 for your Hazardous Materials Handling fee will be made late this year. Sincerely, Ralph E. Huey Hazardous Materials Coordinator REH:vp ENCLOSURES Bedrosians 4285 N. Motel Drive Fresno, CA 93722 City of Bakersfield P. O. Box 205~7 Bakersfield, Ca. 93303-2057 BEDROSIANS HA; o AT. D V. March 08, 1989 City of Bakersfield P.' O. Box 2057 Bakersfield, Ca 93303-2057 Re: Hazardous Materials Handling Fee I am returning the enclosed Invoice #121579 in the amount of $150.00. This bill is made out to Monarch Tile Mfg, but they are no longer pat this address. Bedrosians are now leasing this building and do not handle Hazardous Materials. If you have any further questions please contact me at (209) 275-5000. SincerelY, Sarah Kobzeff MONARCH TILE' MANUFACTURING, INC. I BAKERSFIELD BRANCH RECEIVED F E B n I 1988 Ans'd ............ January 22, 1988 City of Bakersfield Hazardous Material Division 2130 G. Str Baekrsfield, CA 93301 Re:'Selling Inventory located at 2701Brundage .Lane. Dear Eva: This is to inform you that Monarch Tile Mfg. Inc. is selling it's operation located at 2701Brundage Lane to Bedrosian Tile & Marble, which will remain at same location. This transaction will take effect on Febru- Please change the name on this account accordingly. Send any final billings to the following address: Monarch Tile Mfg. Inc. / P 0 Box 2041 ~ Attn: Ronnie Sanford ? Cordially, 2701 BRUNDAGE ~NE BAKERSFIELD, CALIFORNIA 93304 ~5~22~074 MATERIAL SAFETY DATA SHEET PRODUCT NAME~ OUARRY.BROUT HMIS CODES: H F R P ' ' PRODUCT-"CODE'H-~GR~'O-T ......... ~-", ........... ~ ........... .......................... T .................. 0 ....0 ..... 0 ............................. ~ I~ANUFACTURER' S 'NAHE:'. CUSTOM' BUILDING PRODUCTS , " . ADDRESS~ 651i ·SALT LAKE AVE.'~. BELL~ 'CA. ", 90201 · -:' ' ' ' DATE PREP/iRED ~ 12;>-11-86 NAIqE OF PREPARER ~ HAROLD HEBSTER REASON REVISED ~ NEW ==== ==== ".sEcTIoN '!I- HRZR'RDOUS INGREDIENTS/IDENTITy INFORHRTzoN Ol~UffiTIffil:lL EXPOSURE LI#ITS VflPOR PRESSURE ~IEHT I,~,Zt~RI)OUS COIIP(IENT~' ' ·~ ' .' (~llS NUIqliER 0GHI~ PEL IICI}IH TLV OTHER m .NO I~I/.P, RII~ IIGREI)IENTS PRESENT ,.. . VAPOR DENSITYi HEAViER'THAN AIR .. EVAPORATION RATEI SLOWER THAN ETHER SOLUBILITY IN WATER~ SLIGHT'  _~LAPltqRBLE LIN/TS IN AIR BY ¥OLUI~E.' LO~/ERa N/A UPPERa N/¢~ .' SPECIAL FIREF/GHTING . PROCEDURES QGROUT MATERIAL SAFETY DATA SHEET PAGE 2 OF 3 SECTION V - REACT I VI TY DATA STABILITY: STABLE CONDITIONS TO AVOID INCOMPATIBILITY (MATERIALS TO AVOID) ' HAZARDOUS DECOMPOSITION OR BYPPRODUCTS' HAZARDOUS POLYMERIZATION: WILL· NOT OCCUR . ~ ~: : HAZP. RDDUS PDLY~'RIZATIQN CAIt~T OCCUR ' " '.'. '. SECTION VI -- HEALTH HAZARD DATA. ' INHALATION HEALTH 'RISKS AND SYHPTOMS .OF EXPOSURE. .~ " PDRTLAN]) ~ I$ CLASSIFIE]) AS g I(JISANCE OUST BY I)sEq, 14SHA~ANI) ACGIH. AS ~H, TFE TLV ----N~-i'OM~/I'LI FOR TOT~ I]~IST. T~ USE I]F NIOSH APPROVEO RESPIRATOR IS SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE INGESTION HEALTH r RISKS AND SYMPTOMS .OF EXPOSURE .,. HEALTH HAZARDS (ACUTE AND CHRONIC) ACUTE:WET EEMENT, E~PEC~ALLY IN PLASTIC.,(UI~RI)F_~) I:ONCRETE, MDRTAR, OR SLURRIES,~ DRY TI~ SKIN ~)NI) CARCINOGENICITY: NTP? NO IARC MONOGRAPHS? NO OSHA REGULATED?' NO MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE HYPEES~SITIVE INOIVIOI_~LS M~¥ ])EW. LOPE SKIN I~qSH. EMERGENCY AND' FIRST AID'PROCEDURES~?. "': ..... , ,":. .... · EYE CQkTRCT: IRRI~TE EYES 'wITH· ~TERiCDNSULT,,, PHYSCI~ ImII~TELY. ' SKIN CONT~CT.:WASH EXposs), ,, , AREAS WITH.. SOR: :.::': ,::;:: :.i::,. ':::,"ii!i; P ~0 ~qTER IMMEI)IATELY.~' *' .- ;~:' ', '.., ~'IHALED:WEAR APPROVED* ~SPI~TOR IN ])USTY ENVIROI~B~T. STA]~ILITY = STABLE CONDITIONS TO -AVOID · INCOHPATIBILITY, (NRTERIALS TO AVOID) '.' :. HAZRRDOuS DECONPO~I'TION OR, BYPPRODUCTS' "HAZARDOU~ POLYMERiZATIONs WILL' NOT OCCUR ON . INHALRT'I' HEALTH RI'SKS "AND SYHPTOHS OF EXPOSURE. .':,' "P0Frbq~ [2]~rr ]s Q.~S[F]EI) RS R ~]SR~CE lXJST ~Y 0StR~I) i~6]H, RS ~UCH~E TLV IS · SKIN AND EYE CONTACT HEALTH RISKS AND SYNPTONS OF EXPOSURE INS£STION HEALTH.'RISI<S t=IND SYIflPTOHS OF EXPOSURE , -';.:.. '. HEALTH HAZARDS ,(ACUTE AND CHRONIC) CARCINOI~ENICITYs NTP? NO II:IRC NONOI~RAPHS? NO OSHA RESULATED? NO --T-~JI~)"'iIgl~TS iRE. NOT LISTE]) BY NTP, ]RRC~0R (]SHR RS C0NTRININ6 CRRCINREN~, - E~IERBENCY AND FIRST AID PROCEDURES ER[ QIkTRSTIIRRIBIlE EYES I~ITlt I~TERIQ)ISUt.T PflYSCI~ IR~I)IIITELY; ~IN IIIITIICT=BI~It EXP01~ gRERS #ITH SIR ',..: .... .~' P ~ ~TER IleE~IMELY. IltPLB)-"i~ IlPPRIIVD) I~'~PlRMOR IN ]XJSTY ENV]RI]~E]~T. .. MATERIAL SAFETY DATA SHEET PRODUCT NAME:'THINSET GRAY W/TIII.; HMIS CODES= H F· R P ..... PRODUCT"CODEi--TS-~T*L-'~ ........................................................... ; ...... 0'- 0 · = = SECTION. I MANUFACTURER IDENTIFICATION NANIJFACTURER~S NAME=.iCUSTOM BUILDING PRODUCTS 'ADDRESS1 6511.'.SALT LAKE'AVE,~' BELL~ CA. 90201 '"-"*EMERBENC~"PHONE~ (213) 582-0846 INFORMATION'*PHONE~-""('2*i3)"582~0846~ DATE, PREPARED I .12'11-86 NAME OF PREPARER m HAROLD WEBSTER REASON REVISED = NEW ========== SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION .... ~-~--.~ ~[~ p~ ,~ , : i ~.: · ... ;.?.cF.?:'.-:..:. tim '"'"'"'==""==="" SECTION ! I I - -- pHYSICAL/CHEMICAL CHflRt:ICTERISTICS SO I L I NO RANGE: N / A B'pE'{:'t'~-i-~-"-e'R~)iY~--FH-2'O*&'i'}"'i .... :'-""i~-:6- .......... VAPOR DENSITYm HEAVIER THAN AIR EVAPORATION RATE,m E~LOWER THAN ETHER SOLUBILITY IN WRTERa SLIGHT · 7'-~t p pEA RA~--RN-i~-~ R ~:, C 0 L O~ E-D---p-o-~-E~R --I~0- - (3 DD R ..... 7'-~ ...................... ' ==~.,.,m~=~=-,=,,-~,~.~-.' SECTION IV ~ FIR£ ~ND EXPLOSION HAZARD 'FLRSH POINTm i~/A FLAHIqABLE LIMITS IN AIR BY VOLUIqlE- LOWERI N/A UPPER. I N/A t ONE EXTINBUlSHIN8 ' ' · ~N~WN ' SPECIAL FIREFIGHTINO PROCEDURE~ ?lJNt,P3~ FXR :lin EXpLos ..- ~'.. ZARDS ', "- TSMGTLSN I~TERIRL sRFET¥ DRT;t SHEET PRGE 2 OF 3 ======================= SECTION V - REACTIVITY DRT~ = = . CONDXTX~S TO RVOXD INCOMPflTI~ILITY (MflTERI~L8 TO .. HRZRRD~ DECoMP$ITION' OR BYPPROD~TS " HAzaRDous ~LyMERIZ~TION~ WILL NOT OCCUR ====~=""==="====~'~= SECTION ~Z - HEALTH HAZARD DRTR INHRLRTI~. HERLTH RISKS.' RND 9YMPTOMS OF EXPOSURE , 'SKIN R~ EYE CO~R~ HERLTH RISKS RND SYMPTOMS OF EXPOSURE , :;~ ~ ~'~-'~'-~i~-~-~'~~2'~**~"~ IRRIT~.~ :' INeEBTZON HERLm RZSKB ~:'BY~PTOHS OF' EXPOSURE · HERLTH HflZfiRD8 (~TE fiND '~N~C) ~IC~ ~. ~ l~Tlffi ~ ~ Ll~Iffi Tl~ ~ ~ I~ERIOR ~ ~ '" CAKZN~ENICITY, NTP? NO" lnRc ~R~PHS? NO '?~Hn RE~MTED? NO F ' . - , . .:x ...., '~; ' .'~}'.:' .. : ~' ..'? ~ .. " ~ ' ~ ::':."" ': .L.. "'. .: . :. ') :.:.: ~ ;:. .:: ~:.~?:,...~:'.. ~. ': ~:" :.'C . :":~. · . . . "' ' : .. .. TSMnTLSH I~ClTERIAL SAFETY DnTn SHEET . p_~_GE_ 3 ~ 3 J::,/m=========~ SECTION VII -. PRECISIONS FOR S~FE HflNDLZNG fiND USE :" 5TEpG' T0 BE' TR~EN IN C~E ~T~i'~IG--REEE~ .:~.;: HASTE'. DzsPOsnL" ": "' :~ P~CnUTXONS TO~ BE...T~EN. XN ~nN~X~ nND--'~TORIN~ .. : . .. OTHER P~C~UTION8 ,~ ............ ~ · : ~ ...~..... . .. ....... = sEcTIoN VIII CONTROL .MEASURES ==== RESPI RflTORY P~3TECTION ~PI~M~) NIOSH VENTILRTION ' . IMP~INIOU9 II.OVEB SHOULD ~ I, lOffi TO ~ ~l# C0NTPCT., EYE PROTECTION · ~' TI~ USE 0F TI~HT ~ ~ IE(3)II~I'~)ED TO PREt~rr EYE II~ITI:ITION FI~I CEHOIT {X{gT. ,. " =.='='---".~_=..=,.~.=.=~_='.='-~y~..=_=~y~_==:_. :.~ECT:ION I'X' - . DISCLAIMER ===================== DISCLnlMER" ' DE I~0~I~TION P~HrE]) ~ERE I9 ~ELIE~rD TO IE PCOJffiTE ~UT I9 NOT I~IRRI~D TO ~E, ~4ET}ER URIOI,~TIN6 ~I~ THE c0~P~Y"0R-NOT;"R~CIPlENTS'~' P~/i~ED'-T0"C0M:IRN'IN PJ)VPt~E oF'NEED, ]'HI:IT DE INFORt~TION I9 CURRENT, ¢IPPLICI:IBLE, [}NO gJITP. BLE TO THEIR ClltCUIqST~. ' NATERIRL SAFETY DRTR SHEET ........................................................... PRODUCT NI:~IE; NONSANDED POLYBLEND . · H~IS CODES; H F R P PRODUCT coDE"~'-N~PB "- o o o ======'==""========"== SECT I ON I - HANUFACTURER I DENT I F I CAT I ON NANUFACTUREReS NAHE; CUSTOM BUILDING PR(~DUCTS ADDRESS; 6511 SALT LAKE AVE., BELL~ CA. 90201 ' '¢ · ENEReENCY-' p-~i~i'E '~ -~- ~- i- ~3--' ~ '8-~ -'*b-8-4-6~- ........... iN'~O'Rl'l;i~r-~ ON DATE PREPARED ; 04-:=,9-B7 NAME OF PREPARER = TERZ ~E~ON REVISED =NEN =======~= SECTION ~Z "- H~Z~RDO~ ~NBRED~ENT6/ZDENTITY ~NFO~TION .................. ~_~TI~ EX~ 'LIWI~ ~ P~ ~I~ ======'========= ,SECTION III' - PHYSICAL/CHENXCAL'i"Ci~RACTERISTIC8 BOiLING'RANGE; N/A-- SPECI'FiC'-GRA~'i'TY'-'~H~O=I)=" 2.9 VAPOR DENSITY~ HEAVIER THAN AIR EVAPORATION RATE; SLOWER THAN ETHER SOLUBILITY IN HATER; SLIGHT AppEARANCE'i'~ND-ODOR~--CO'~ORE~'--PO~DE R~-NO-'ODO R .. ='==============" SECTION IV - FIRE AND EXPLOSION. HAZARD FLASH POINT= N/A 'FLA~q~JgLE LIHITS IN AIR BY VOLUI~- LONER; N/R UPPER; EXTINBUISHIN8 HEDIR;*NONE KNOWN ,'. SPECIAL FIREFISHTINB PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS .. NSPB MATERIAL SAFETY DATA SHEET PABE ~ OF 3 = SECTION ¥ - REACTI¥ITY DATA ======================== ========== STABILITYi-"STABLE CONDITIONS TO AVOID INCOMPATIBILITY {MATERIflLS TOAVOID) HAZARDOUS DECOMPOSITION OR SYPPRODUCTS I'~ZARDOUS POLYMERIZATZONI WILL NOT OCCUR .. ===================== SECTION VI - HEALTH HAZARD DATA ===================== INHALJ:ITION HEALTH RISKS AHD SYMPTOMS DF EXPOSUR~ POR]I.I~) CBENT 1S CLASSIFI~ ~ ~ ~IB~ICE ]XJST ~ OSHa, HSH~, ~N~ ;CSI~ ~ SUC~ 5E ~¥ 1S ~IE/~ F~ RF. SPIR~B.E SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE SKIN'-ABSORPTZON--HEA£T~-R'i~'-~ND-~¥MPTOMS-'OF-EXPOS~RE INGESTION HEALTH RISKS'AND SYMPTOMS OF EXPOSURE ' ,NONE HEALTH HAZARDS (ACUTE AND CHRONIC) HEBi'C'n~"C~IT ]ONS 6ENER~LY ~; N/~ . ,~NSPB Iq~TER]AL ~II:ETY DATA SHEET PRGE 3 --=--=,==:=== SECTION VII PRECRUTIONEI FOR SAFE.' I-~NDLINE) ~ND USE' STEPS TO BE TAKEN IN CASE Iq~TERIAL IS RELERSED--GR--sPI-L~ED · HASTE D ISPOSRL P~-TTiOD ' ' . : · ,¢ OTHER PRECRUTIONS ===================== SECTION ¥1 11 - CONTROL HE/:tSIJRES REBP! RI:iTORY PROTECTION IIPPlI)VED NIOSH IIESPIllIITOR. VENTXLATION I1VOID 6ENERflTIN6 i1.15'1. IEIJ~ICI1L EX~RU~T. ...... PROTECT l VE ~LOYES IMPERVIOUS HLOVES 9{XILD lie IdOl~l TO PREVENI' SKIN 'CONT~CT, ' *EYE'PROTECTION TME USE (F TI6HT 6066LES liRE REC(]I~EI~ TO PREVENT EYE IRRITIITI~N FD CE)ENT "oTHER' pROfEC~X-~E--~I~OTi~iNG*-OR "EQUX'PNENT ~ USE OF taRRIER CREAIlS OR ELOVES, IMPERVIIXI$ ~O19 M llJ.OTHIm TO PROTECT ~ ~IN FR(M Q31ITflCT WITH kET CIDIE)tT. HORK/HYSIENIC PRPlCT ICES 1t30D .HOl____te~d~2qEEPlN6 PROC[DIJRES ~ E R31.Lfll4EI) lit AU. TI~S. ..... DISCLAIMER ' ~ I~ORRqTII3N PR[SENIle) ~RE IS BI~.IE~IED ]1) I)E ACCUItflTE 9UT IS NOT W~RltflHTED TO liE, ~tE'TI{[R ORIGIIqMIN6 WI1TI THE "C{31qPANY 131t NOT.' RECIPlE)ilS liRE III)VIS[I) TO COM:iRPl IN III)V~NCE OF NEED, THflT TH[ INFOItMMION 'I$ CURItENT~~ IIPPI-IciiiI.E~-'-1114~ ....... SUITAItU[ TO THEIR CII{CUqSIAtlC[S. PRODUCT ~M~ ~NDE~ ~RoUT· HM~ PROD~T CODE:-**SGROUT .................................... =~=========m====== SECTION I - MANUFACTURER IDENTIFICATION M~CTURER~S N~ 'CUSTOM BUILDING PRO~CTS ,.. ~" ' ADDRESS~ 6511 SALT LAKE AVE., BELL~ D~TE PREPARED ~ 1~-11-B6 NAME OF PREPARER' ~ HAROLD WEBSTER. REASON REVISED : NEW ==~====== 'SECTION II -, H~ZARDOUS INGREDIENTSZIDENTITY INFOR~TION ========= ===-=-=-====== SECTI°N III "- PHYSICRL/CHEHICRL BO~'L'ING"R~NGE= N/A SPECI'~C-~'R~'~'Y~'-~~ ~APOR DENSITYI HEAVIER THAN AIR EVAPORATION RATEI SLOWER THAN ETHER SOLUBILITY IN WATERI SLIGHT ~ppEARANCE--~NI~'-DDOR~--C~ORED--PDWDER-NO'**ODOR ' ' .... ' .. ================' SECTION'IV -- FIRE AND EXPLOSION HAZARD~,.DRTA FLASH POINTI N/A FLA~LE LI~IT5 IN AIR BY VOLUlqE- LOWERa N/A UPPER~ N/A EXTINGUISHING ~EDIAI NONE KNOWN ..':: .. JNLISURL FIRE RND EXPLOSION HAZARDS' .... ' SSROUT MATERIAL SAFETY DATA SHEET PAGE ~ OF 3 ==== ==== =========== ===== SECTION V - REACTIVI'TY DATA =====. ============== ==== 'STRBILITY:"-'STABLE .... CONDITIONS TO AVOID · INCOMPATIBILITY (MATERIALS TO AVOID) t ,¢ HAZARDOUS DECOMPOSITION OR BYPPRODUCTS HAZARDOUS POLYMERIZATIONs WILL NOT OCCUR · ~7.qR~ POL~IZ~TI~ ~T 0CCU~ ' INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE ' "~ 'i~/m Fm'"t~--~;-T~--~-~-~z~~-~sPI~-l'~'~. SKIN R~ EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE "S~'IN'-'RBSORPTION HEALTH RISKS R~ SYMPTOM~-'E-XPOSU~ INSESTZON HE~TH RISKS AND SYMPTOMS DF EXPOSURE ' " ~---- , : .. ..::. · .... .. : . . . :..... ..: . .. "}~TE:WET CZMENT~ESPECI/)LLY IN PM)STIC (~) Cl)I(~I~t"TE~PlDRTRR~CN! ~l. URRIE,ehr.~ti DRY T~ Iii(IN ~ r,,AUCdE I)LJ(.qLI [IUIU~. CHRDNIC:CE)EWT ~ CAUSE IM:LI~I&qTIDN BF'.THE LII~IIN6 TIS'~_~ I]F ]HE INTERIOR I]F. ]l~ M31{E ~ lbtq.l~l~qTll]l( (]F ])E CDStE~' .~: '. CARCINDSENICITY= NTP? NO IARC MONOE}RAPHS? NO OSHA RESULATED? NO P~TUI~ CE)ENTS ~RE N~T LISTED BY NTP, IAR~OR ~ lis CI~fAININ~ ~RCINSE]~. ." :. 'MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE ~YPERSNSITIVE IN~IVI~J~S ~qY ~'V[M3PE S~IN ~ 'i~'i~RSENCY AND FIRST RID PROCEDURES ". ', EYE CONT~T:IRRIGME EYES tIlTlt mTERiCONgJLT I~t~Im IMMEI)IIITELY. BKIN CONTACTmWflSH EXPOSED IIRFJqG #ITtl I~ '" . P ~X~ ~qTER ]~E])]~TEL¥. · ]H~LED;IE~R ~PP~ED RESPIRATOR IN DUSTf fNV]ROMI98. ' '~SS UT I~ATERIRL SAFETY DATA SHEET PAGE '3 OF 3 =========== SECTION V[! . PRECIIUTIflNS FOR SAFE HliNDLIN8 lIND USE --'STEPS- T O-"BI~-TRKEN--i N--C ASE~HRTE R IA~-IS--RE~EflSED-OR-'SPILL£D a. EAN-IJP USINg DRY ~ 11.~T m NOT DISPERSE DUST INI~ 11E JtlILiM)II) BRFATHINB II.E DUST.~ PR(X/~RES P~E NOT HASTE DISPOSAL Iq~rHOD / a:lN E TRF. flTED ~ A CI:)II(]N ~ OR ILr'I1JI~IED TO THE CONTAINER FOR LATTER U~E IF' IT IS NOT COiMTAIdI~TE]). -~':' ,. '%7' :~,.- ...... PREC~HTI 0N~-'- T~--BE--'i'~£N---i i~-HfiI~B~INS-~ND--STOR~iN~'' OTHER PRECAUTIONS ===================== SECTION VIII -- CONTROL MEASURES ==================mmmm ..... RESPIRATORY-PROTECTION .............. : ..... ~ ~PROV~)NZE~N~SPI~TORo VENTiLATiON. ' '-PROTECTIVE"BEOVES ............................. ~ ................................ .................................. i'-': ................ ~:i ................. : .......................... l~lO~ ~OVES~(I.qJ)~ ~ ~,PREVENT~INCONT~T. ''EYE"PROTECTION TI'ti USE ~ TI6HT 6066LE5 J&q~: ~~ ~ PRLrVI~iT EYE IRRITATZ~ FROM a~ENT IXJb"T. .. '"OTHER PROTECTIVE-'C~OTHINS'OR"EQUIPMENT ......................................................................................... THE USE ~ ~IER CREq~ gR ~ [M~I0US BOOTS ~ ~0TIII~ ~ PRO~ I~E ~[N F~l~ C0NT~CT #[~ kET CF. JI~ff, HORK/H¥SIENIC PRACTICES = ====== = = === SECTION IX - DISCLAIMER = ==== ======= DISCLAIMER TIE I~ORJ~TI~ PRESENT~ ~ IS BIELIGED I ~ ACOJ~E ~T IS ~T ~RRANTED ~ ~, ~t,ETI. ER ORIBI~TI~ WI~ THE i 'COMPI~NY OR ~T. RECIPI~ fl~ RI)VISED ~"CONFI~ IN P. DVI~ICE ~ NEEI), THAT'TIE I~OI~TI~ IS ~RRI~iT, flP~I~' ~ ~ITABLIE ~ THEIR CIRCUMSTANCES. PRODUCT NAME: DRY TILE GROUT'- WHITE HMIS CODES: H F R P PRODUCT-CODE:-**DTG 0 0 0 MANUFACTURER'S NAI~: CUSTOM BUILDING PRODUCTS' ADDRE6S: 6511 SALT LAKE AVE,, BELL~ CA. 90201 'EMERGENCY**PHONi~':*:'~(~'l*3)---S8~=08~6 ................. INFORIqATIONPHONE: DATE PREPARED : 1~-11-8& NAME OF PREPARER m HAROLD WEBSTER REASON REVISED : NEW == = SECTION II - HAZMRDOUS XNSREDIENTS/IDENTITY INFORMATION OCCU~TX~I. EXPOSU~ U#XTS VP3DR PRESSU~ ~I6HT ~R~ COMPONENTS C~S NUIGER ~ PEL ~C6XH T~ OTHER t-t.J ~ ~ZP, IU~]S INI~qEI)I~ PRESENT ~ ' ~m~=~=~ SECTION III - PHYSICAL/CHENICAL CHARACTERISTICS SOILING RANGE: N/A .............. SPECIFIC GRAVITY (H~G~I)*: 3.0 VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE~ SLOWER THAN ETHER SOLUBILITY IN WATER: SLIGHT APPEARANCE AND ODOR:' COLORED'POWDER NO ODOR ==========~=~ SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH pOINT: N/A FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: N/A UPPER: N/A EXTINGUISHING ~EDIA: NONE KNOWN SPECIAL FIREFIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS NO,E REqUIRED DTG I~ATERIAL SAFETY DATA SHEET PAGE ~ OF'3 STABILITY;':'STASLE CONDITIONS TO AVOID INCOMPATXBILXTY (MATERIALS TO A¥OXD) ~' HAZARDOUS'DECOMPOSITION OR BYPPRODUCTS HAZARDOUS POLYMERXZATXONI WILL NOT OCCUR ~ZI~P~LYIERI~TI~Q~NDT(~ ' ===================== SECTION VI - HEALTH HAZARD DATA =====================- INHALATION HEALTH RISKS AND SYMPTOHS OF EXPOSURE ~RTL.qND CEIE. NT IS CU~IFI~ ~ R ~ISI~NC[ lXJST ~ OSt~l~ ACSIH. ~ SLJCH~TI't; ~V I8 ~d~16/~ ~R IE~PIRRIILE IN.JST R ~ lONG/~ F~ TOT~'DUST~'T~~'U~"~-NIOSH-R~ROV~)"~I~T~ 16 IECONIENI~,' ........ SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE. ~* WET CEtENTCI~IDRY THE SKIN'I~)C~J~'I~LKILI'~,(ZIE~DU~T~IRRI~EYES~NDUPPERIE~I~TORY,S~TE& SKI N ABSORPT I ON -*HEAl:TH *R I SKS" AND *'SYMPTOMS' OF EX POSURE INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE HEALTH HAZARDS (ACUTE AND CHRONIC) ;~ITE:tET (/HENT, ESPECI~LI.Y IN RASTIC (LIIH;IRIEM~) CI~C~'TE~IERTP. R,D~ ~.URRIES~ DRY THE SKIN ~ ~USE ~LKRLI 9URNS. CH~]I~IC:CBF. Kr (3~N CoAJSE I~TI~ OF THE LII~tIN~ TISBJE OF THE INTERIOR OF THE ~ ~ I~TION OF THE ~RtEA, HYPERSNSITIVE INI)IVI~ M~Y DEVELOP fin ALLER6IC DERM~TITUS(SKIN R~H), CARCINOGENICITY! NTP? NO II:IRC MONOGRAPHS? NO OSi'U:I REGULATED? NO P0RTLRN0 CE)ENT6 ;IRE NOT'LISTEO'BY'NTP;"IP~;'0R'~Sk~"~; CONTRININ6 CP. RCIFES~ ..' MEDICAL' CONDITIONS-GENERI~£m-Y"~AGGRAVATED*BY EXPOSURE HYPE. RSNSITIVE INDIVIDURLS ~Y I)EA;I.OPE: 6KIN ~ EMERGENCY" AND' F'l RST'-'Ail-'PROCE:DURES EYE CONTRCTslRRIffilE EYBi MITH ~TERICONB,LT PHYSCII~I II'IIE:DIIITECY. SKIN CONTRCTddRg. I F.,XPOED P ~ ~TER Iiq, E])IflTELY. IHRI.ED:~ ~PlIOVED IIE:IiPlRI:ITOR IN DUSTY DTG MATERIAL SAFETY DATA SHEET PAGE =========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE STEPS TOBE-'TAKEN-'-'IN*-CASE--MATERIAL--IS-~RELEASED"OR SPILLED D..F~P ~I~ DRY I~ 11~T ~ NOT DISPERSE ~ INN THE RI&I~/0ID BRE~i~I~ THE I)U~T.~ERSENCY PROC~S ~ ~T WASTE DISPDSAL METHOD ~ C~ [ TREATED t A CI~ ~ ~ ~RNED TD T]~ CONTAIIR ~R ~£R I~E IF IT I~ ~T CI3NNT~I~TED, - PRECA~TIONS~TD*BE'-TAKEN'iN I-LCtNDLIN6 AND STDRII~ OTHER PRECAUTIONS RESPIRATORY'--PROTECT*ION ~PRI)~NI[]~I~SPI~TI)R, VENTILATION ~/DIDSENER~TI~DUEr. PROTECTIVE GLOVES I~IOUS ~r.S S~Ui.D [ I~ T~ P~VENT ~IN C0~TRCT, EYE PRGTECTION OTHER PROTECTIVE'CCDTHINS"OR EQUIPMENT WORK/HYGIENIC PR~TICES MATEI~IAL SAI:-ETY~ DATA SHEET SECTION I Manufacturer's Name and Address Emergency Telephone Rive. r~i~e Cemer, t Company 714-686-0181 ~P. 0. Box ~3~ ~Riverside, CA 92502 Chemical Name and Synonyms Teade Na~e a~d Synonyms Pc, rtlar~d Cerements (CAS ~65977-15-1> Plastic Cements "Riverside Balanced Block Ce~]ent" "Riverside Plastic Cement" Chemical Family Formula C~lcium Sa~lts 3 Ca0 · Si02 (CAS # 12168-.-85-3) '=.' Ca0 . Si02 (CAS # 10A34-77-~) 3 CaO · A12(5 <CAS ~ 1~042-78-~) 4 CaO. Al203 · Fe203 (OAS ~ 1~068-~5-8) CaSO~ ' 2H20 (CAS ~ 13397-~4-5) C~C~, MgO, CaO plus small amour~ts of K2SO~' arid Na2SO~ may be present. SECTION II -- HAZARDOUS INGREDIENTS~ Pc0rtland cer,ler~t,.'~ are classified as nuisance dusts by OSHA (~9 CFR 1910. 1000, ]'able Z.-3)~ MSHA (30 CFR 56.5001~ ACGIH TLV~s for 197~, Appendix E), '~r,~ ACGIH (TLV's for 1985-86~ Appendix D). Portland cements/are NOT listed ~y NTP, IARC, or OSHA as containing carcir, ogens. / SECTION III -- PHYSICAL DATA Boiling Point Specific Gravity Not applicable, as port land 3. 15 cement is a powdered solid Vapor Pressure Pe~entage Volatile by Volume Not applicable, as port land 0% cement is a powdered solid Vapor Density Evaporation Rate Not applicable, as port land Not applicable, as port land cement is a powdered solid cement is a powdered solid Solubility in Water Appearance and Odor Slight (0. 1 -1.0%) Gray (or white) powder; no odor. SECTION IV -- FIRE AND EXPLOSION HAZARD DATA Flash Point Special Firefighting Procedures. Pc, Pt iar~d cements are noncombustible Not applicable and rlonexplosive Flammable op Explosive Limits ~ Unusual Fire & ExplosioD Hazards Wot applicable None Extinguishing Media Not applicable SECTION V,-- HEALTH HAZARD DATA Threshold Limit Value Effects of Overexposure Respipable Dust - 5 mg/m~ Acute: Wet cement, especially as Total Dust.- 10 mg/m~ an ingredient in Plastic (unhardened) ~¢) million Particles/ft3 concrete~ can dry the skin and cause alkali burns. Cement dust can irritate Emergency & First Rid the eyes and upper respiratory system. Procedures Irrigate eyes ~ith ~ater~ Chronic: Cement dust can cause consult physician. Wash inflammation of the lining tissue of the exposed skin areas ~ith interior of the nose and inflammation of soap arid ~ater. the eye. Hypersensitive individuals may develop an allergic dermatitis (skin rash). SECTION VI -- REACTIVITY DATA Stability Hazardous Decomposition Products Product is stable· None Keep dry until used. Ir~=ompat i bi I ity Hazardous Polymeri zat ion None Will not occur SECTION VII -- SPILL PROCEDURES Steps to be. Taken in Case Waste Disposal Method Material is Spilled Material can be.returned to Use dry cleanup methods that do not container for later use~ or it disperse the dust into the air. can be disposed of as an industrial ~ast e. SECTION VI II -- SPECIAL PROTECTION INFORMATION Respiratory Protection Skin Protection Ir, dusty environrnents~ the use of *Use barrier crearns~ gloves~ NIOSH approved pespirator is boots and clothing to protect recc, nlrnended. ~ the skin fporn ppolonge~ contact ~ith ~t cement~ especially in ~ent i [at ion plastic (unhardened) concheS. ' U,:,~al exhaust can be used~ if , Immediately after ~opking ~i.th necessary, to control airborne cement~ ~opkeps should sho~ep dust levels. ... ~ith soap and ~atep. Precautions must be observed because ce~ent Eye Protection , burns with little warning - little In dusty environments, the use of heat is sensed. tigh't fitting goggles is pecormnended. SECTION IX -- SPECIAL PRECAUTION~ P~ecautions to be Taken in Othe~ P~ecautions Handling and Stoeing None None SECTION X -- ABBREVIATIONS ACGIH American Conference o~ Governmental ~illigram Industrial Hygienists CAS Mine Safety and Health Chemical Abstract Service Administration CFR NIOSH Code of Federal Regulations National Institute fop Occupational Safety & Health ft3 Cubic Foot NTP National Toxicology Program IARC International Agency for OSHA Research on Cancer Occupational Safety and Health Administration Cubic Meter TLV'~ Threshold Limit Values SECTION ! I. lanufacturer~s Name and Address Emergency Telephone No. ,~ R~verside Cement Co~lpany .. ~P.O. Bc,~ 8327 Riverside, CA 9~50~ ~14-686-C)181 'P.O. Bo~ L~ Opo Grande, CA 9~S68 619-~45-5~1, e~t. ~60 Chemical Na~ and synonyms Trade Name a~ Sy~nyms Portland Cements (CAS 865977-15~1) Portland Cements Wh it e Port land Cerement s "Sivepside Portland Cement" ~Riverside Special ~hite~ "Riverside ~hite Oement" Chemical Family Formula , Oalciu~ Salts. ~ CaO. SiO2 (CAS ~ 1~168-85-~) ~ CaO. SiO2 (CAS ~ 100S4-~-~) .,. ~ CaO. A120~ (CAS ~ 1~04~-78-~) 4 CaO' A120~ · Fe2~ (CAS ~ 1~068-3~-8) CaSOq · ~H20 (CAS H 1~97-~4-5) plus s~all a~nounts of CaO, MBO, K2SO~, Na2SOq .~ay be present. SECTION II -- HAZARDOUS INGREDIENTS Portland cements are classified as nuisance dusts by OSHA (29 CFR 1910. 1000, Table Z-3), MSHA (30 CFR 56.5001, ACGIH TLV's fop 1973, Appendix E), and ACGIH CTLV~s for 1985-86, Appendi~ D). Portland cements are NO~ listed by NTP, IARC, or OSHA as containing ~arcinoBens. SECTION III -- PHYSICAL DATA Boiling Point Specific Gravity Not applicable, as portland 3.15 ' ~ement is a po~dered solid Vapor Pressure PerCentage Volatile by Volume Not applicable, as portland cement is a po~deped solid Vapor Density Evaporation Rate Not apglicab'le, as portland Not applicable, as portland cement is a powdered solid cement is a po~dered solid Solubility in Water Appearance and Odor Slight (0.1- 1.0~) Gray (or ~hite) po~der~ no odor. SECTION'IV'-- FIRE AND EXPLOSION HAZARD DATA Flash Point Special Fi~efighting Procedures Portland cements are noncombustible. Not applicable and nonexplosive Flammable or Explosive Limits ' unusual Fire & £xplosio~ Hazards N~t applicable None .~ EXtinguishing Nedia Not applicable SECTION V ~ HEALTH HAZARD DATA Threshold Limit Value Effects of Overexposure Respirable Dust - 5 mg/m3 Acute: Wet cement, especially as Total Dust - 10 mg/m3 an ingredient in plastic (unhardened).~. 30 million Particles/ft3 concrete, can dry the skin and cause alkali burns. Cement dust can irritate Emrgenc¥ & First Rid the eyes and upper respiratory system. Procedures Irrigate eyes with water; Chronic: Cement dust can cause cor~sult' physician. Wash inflammation of the lining tissue of the exposed skin areas with interior of the nose and inflammation of soap and water, the eye. Hypersensitive individuals may develop an allergic dermatitis (skin rash). SECTION VI -- REACTIVITY DATA Stabi 1. ity Hazardous Decc~aposit ion P~oducts Product is stable. None Keep d~y until used. I ~pat i b i I ity ~za~ous Po 1 ~e i zat ion None Will not occur ~ECTION VII -- ~PILL PROCEDURES Steps to be Taken in Case Waste Die,ual ~teeial is Spill~ Material can be returned to Use dry cleanup methods that do' not container fop later use, op it disperse the dust into the air. can be disposed of as an industrial SECTION VIII -- SPECIAL PROTEL-~I'ION INFORMATION Respiratory .Protection Skin P~otection In dusty environments, the use of Use barrier creams, gloves, NIOSH approved respirator is boots and clothing to protect recommended. ~ the.skin from prolonged contact with wet. cement, especially in ~entilation plastic Cunhardened) ~ocal exhaust can be used, if Immediately after wopking~With necessary~ to control airborne~ cement, ~opkeps should shower dust levels, with soap and water. Precautions must be observed because cement Eye Protect ion ~ burns with little warning - little In dusty environments, the use of heat is sensed. tight fitting goggles is recommended. · SECTION IX -- SPECIAL PRECAUTIONS Precautions to be Taken in Other P~ecautions Handling and Storing None None SECTION X '-- ABBREVIATIONS ACGIH American Conference of Governmental Milligram Industrial Hygienists CAS Mine Safety and Health Chemical Abstract Service Administration CFR NIOSH Code of Federal Regulations National Institute Occupational Safety & Health Cubic Foot NTP National Toxicology Program International Agency fop Research on Cancer Occupational Safety and '~Health Administration Cubic Meter TLV~s Threshold Limit Values MATERIAL SAFETY DATA SHEET SECTION I -- NAME AND PRODUCT Manufacturer: CHEMSTAR, Inc. Emergency Telephone: -~ (702) 565-8995 Contact: Dr. Starr Curtis '~.... Address: P.O. Box 127, Henderson, NV 89015 Trade Name,'Comm°n Name: * ' DOLOMITIC HYDRATED LIME.. ' ' ~ '. '* ~ 'DOLOMITIC HYDRATED'LIME, Ca(OH)2.Mg(OH)2, (No'CAS#) . . ,.. Genstar Type S Hydrated Lime, Genstar Pr~essure Hydrated Dolomltic Lime .. Specification: ASTM C51, C206, C207, C911, C977 ;!'Chemical Family: ' Alkaline Earth Hydroxide SECTION II--COMPOSITION · ... '~ '. Chemical Name . .% . Common Name REG* CAS OSHA Permissive ' ACGIH Carcinogen? (If/N) .. No. Exposure Limit TLV/TWA (Y/N) Calcium Hydroxide ~50 Hydrated Lime. N 1305-62-0 -- 5 mg/cu.m. Magnesium Hydroxide .... ~35 Brucite ~ _,N .... !309-42-8 .... N Calcium Carbonate ~.~.~ ~ ~*5-~.imestone. N t317~65-3 -- ~- 10 mg/cu.m. N Silicon Dioxide .. ~ 3. Quartz Y 14808'-60-7 0.1 mg/cu.m. 0.1 mg/cu.m. N Other (Fe203, A1203) ~ 3 -- N -- , -- -- N Purity depends on the dolomite starting material and the manufacturing, handling, and storage techniques:' GENSTAR LIME COMPANY strives to maintain high purity and production quality standards. SECTION III--PHYSICAL AND CHEMICAL DATA Appearance and Odor: Soft white crystalline powder mixture of calcium hydroxide and magneMum hydrotrld® with properties Intermediate between the two principal components. Odorless. Genstar Type S Hydrated Lime is avaiia, ble in bags or bulk as a fine powder, generally 95% passing 200 mesh. Melting Point: partially dehydrates at 350 C Bulk D.ensity: 30-40 Ibs/cu.ft. : Boiling Point: 5162 F/2850 C Water Solubility: Slight. Aqueous Solution Behavior: Vapor Pressure: N/A Temp. Solubility pH (sat'd sol'n) Vapor Density: N/A 0 C . '"1.85 g/I 13.0 Evaporation Rate: N/A 25 C. "'1.59 12.4 % Volatile by Vol: : N/A 50 C '"1.28 11.5 ' Solubility in Alcohol: NAIF** 90 C -'-0.71 10.5 Solubility in other Solvents: Dolomitic hydrated lime reacts with acids, forming calcium'and magnesium salts which may be soluble. SECTION IV--FIRE AND EXPLOSION-HAZARD DATA . Special Fire Fighting ProCedures: Dolomitic hydrated lime dehydrates to magnesium oxide (350 C/662F)~add calcium oxide (580. C/1079F) and steam. If these upper temperatures prevail, wear self-contained breathing apparatus app~bved by NIOSH.. Protect eyes from dust. The presence of Type S hydrated lime in a fire does not hinder the use of any standard extinguishing medium. Flashpoint: Not Flammable · Flammable Limits: N/A Extinguishing Media: Not Flammable Exp!~sion Potential: None SECTION V--HEALTH, FIRST AID AND MEDICAL DATA Threshold Limit Value (TLV): 5 mg/cu.m. Dolomitic hydrated lime is an alkaline material. In presence of moisture, contact with skin and eyes will cause irritation and possible severe corrosion damage. Inhalation of dust may cause coughing, sneezing, or inflammation of the respiratory passages. While short term exposure and irritation are generally without permanent effects, untreated contact and irritation can cause dermatitis and chemical burns. Prevention of contact and exposure under good working conditions is much preferred to first aid after injury. See Section VIII below. FIRST AID: Inhalation: Remove from exposure to dust and get prompt medical help. Eye Contact: Wash eyes immediately with running water for 15 minutes, including under eyelids. Get prompt medical attention! Skin Contact: Wash exposure area with large amounts of water. Remove and wash contaminated clothing. Ingestion: Immediately dilute the chemical by drinking large amounts of water or milk. Then neutralize by drinking dilute vinegar or fruit juice. *Regulated on lists: OSHA 29CFR 1910, subpart Z; ACGIH,HHS/NTP & IARC. **NAIF--No Applicable Information Found SECTION VI--CORROSIVITY AND REACTIVITY DATA * * Stability: STABLE Hazardous polymerization will NOT occur. Incompatibilities: Dolomitic hydrated lime is incompatible with acids, ammonium salts, phosphorous, and some organic compoUnds. It is stable in sealed containers at normal temperatures. Decomposition Products: When exposed to air, this strongly alkaline compound will absorb and react with carbon dioxide, producing caldium~ carbonate. This forms lumps, reduces thlt chemical activity and .:. results in a limited shelf lif~. Calcium arid magnesium salts are normal ~e,~ction products with ...... i other materials ..... · ,iConditionsto be avoided: Handling procedures which may generate dust. Contact with nitrQparafflns, maleic anhydride or phosphorous. SECTION VII--STORAGE, HANDLING AND USE PROCEDURES Normal Storage and Handling: ~ Dry area, out of weather and flood danger. Avoid dusting in handling. Normal Use: '.. ~ standard equipF~ent for hydrated lime use. Make adequate provision for dust-free operations. S,teps tO be taken in Those involved in cleanuP must protect against skin contact .and inhalation of dust or mist. Case of Leaks or Spills:_ See Section VIII. Carefully'pick upstate l~O_w.der w_!th a.minimumof-duatlngand celleCt-lrtmetal:-'.. containers with covers for disposal. The small amount8 of residue after Shoveling and sweeping can 'be flushed to the: drain, using .plenty of water. , Waste Disposal Method: . ... Several methods may be suitable: a) Spread in a protected area to permit reaction with carbon dioxide in air. (Prevent air current dusting.) b) Neutralize with acid or waste acid. c) Use as a soil amendment. .- · d)' Use to stabilize clay soils. Follow Federal, State and local regulations. ... SECTION VIII--PERSONAL PROTECTION INFORMATION Respiratory Protection: NIOSH approved dust filter respirator in dusty conditions. In absence of dust, mechanical exhaust is adequate. Eye Protection: Approved tight-fitting safety goggles. Protective Gloves: : Clean, dry rubber gloves. Clothing: Clean, body-covering protective clothing, such as Iong-sleeve shirt .with buttoned collar; long pants extending over tops of work shoes. ' Ventilation: Provide general ventilation and local exhaust ventilation with approPriate dust collection to .... meet TLr requirements for lime dust. Other Equipment: An eyewash station and safety shower should be readily available near the work area. SECTION IX--SPECIAL PRECAUTIONS Store materials in sealed containers in a dry place. Avoid contact with acids and other incompatible materials. Exposure to air lowers the available dolomitic hydrated lime reactivity'over time. SPECIAL REFERENCE: LIME HANDLING, APPLICATION, AND STORAGE, Nat. Lime Assoc. Bull. 213, 4th ed., .1982. . * Rev. 03/04/86 HSC. APPROVED:. DATE:. US~ INDUSTRIES, INC. 312/321-1555 101 S. Wacker Drive, Chica~o, IL SECTION I pRODUCT': MTM-5000 Thin Set Mortar, White DATE ISSUED: September 26, 1986 CHEMICAL FAMILY: Portland Cement SECTION II HAZARDOUS INGREDIENTS ! MATERIAL: % PEL or TLV: CAS # Silica Sand 45-55 · 0.1 mg/M3 respirable (OSHA) 14808-60-7 .Portland Cement 35-55 10 mg/M3 (ACGIH). 65997-15-1 SECTION III PHYSICAL DATA SOLUBILITY IN WATER: Forms an alkaline dispersion with water SPECIFIC GRAVITY (H20 = 1): 2.3 - 2.4 APPEARANCE AND ODOR: Sandy, white free-f~owing powder SE ION '~FIRE AND EXPLOSION HAZARD DATA FLASH POINT (METHOD USED): None EXTINGUISHING MEDIA: Not combustible SPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL FIRE AND EXPLOSION HAZARDS: None SECTION V EFFECTSOF OVEREXPOSURE: ACUTE: Portland cement is highly alkaline. Causes severe eye ,. irritation. Irritating to skin, especially in sensitive C]~ONIC: Inhalation of silica may cause permanent scarring of lungs ~ (fibrosis). ', EMERGENCY AND FIRST AID PROCEDURES: EYES: Immediately flush eyes with water for at least 15 minutes. Call physician immediately. SKIN: Wash skin withwater. INHALATION: Remove to fresh air .... INGESTION: Drink fluids~,call physician immediately.' PaGe: 2 PRODUCT: NTH 5000 Thin Set Nortar, White SECTION VI RE&CTIVITY DATA STABILITY: Stable HAZARDOUS'POLYHERIZATION: Will not occur. ' SECTION VII SPILL OR LEAK PROCEDUREs STEPS To BE TAKEN IN CASE NATERIAL IS RELEASED OR SPILLED: Sweep up; minimize airborne dust. Do not flush down drains[ Nay,pluG drains. WASTE DISPOSAL HETHOD: In accordance with local, state and federal regulations. SECTION VIII SPECIAL PROTECTION INFORHATION RESPIRATORY PROTECTION: NIOSH-aPproved dust respirator if,TLV is exceeded. VENTILATION:' Local exhaust to keep below TLV. PROTECTIVE EQUIPHENT: Safety glasses, impervious.gloves. SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Keep dry. HATERIAL SAFETY DATA SHEET USG INDUSTRIES, INC. Day 312/321-4383 101 S. Wacker Drive, Chicago, IL 60606 Night 312/321-4382 SECTION I PRODUCT NO: 15376 PRODUCT: HTM 2010 Multi-Purpose Ceramic Hastic DATE ISSUED: Hatch 20, 1986 CHEMICAL FAMILY: Acrylic Latex Emulsion SECTION II HAZARDOUS INGREDIENTS MATERIAL: % TLV: CAS ~ · Petroleum Distillates 5 500 ppm (OSHA) 00107-21-1 Ethylene Glycol 2 C 50 ppm (ACGIH) 64742-88-7 SECTION III - PHYSICAL DATA BOILING POINT: 212 F SOLUBILITY IN WATER: Emulsion SPECIFIC GRAVITY (H20 = 1): 1.32 APPEARANCE AND ODOR: Off-white heavy paste with sweet odor SECTION IV FIRE AND EXPLOSION HAZARD DATA FLASH POINT (METHOD USED): Not applicable EXTINGUISHING HEDIA: Will no~ support combusion. Will not propagate flame. sPECIAL FIRE FIGHTING PROCEDURES: None UNUSUAL FIRE AND EXPLOSION HAZARDS: None SECTION V HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE: Irritating to eyes. Possible irritation to ~kin on prolonged contact due to defattlng action. EMERGENCY AND FIRST AID PROCEDURES: ~ EYES: Flush eyes with water for 15 minutes; if'irritation persists, see physician. ~KIN: Wash with soap and water. INGESTION: DO NOT induce vomiting; see physician. '/ ,RODUCT NO: lS376 Page: 2 PRODUCT: NTH 2010 Hulti-Purpose Ceramic Hastic SgCTION VI ,,, REACTIVITY DATA STABILITY: Stable HAZARDOUS POLYMERIZATION: Will not occur SECTION VII SPILL OR LEAK.PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Scrape up and place contents in waste containers. Wash area withsoap and water before adhesive dries. WASTE DISPOSAL HETHOD: In accordance with local, state and federal regulations. SECTION VIII SPECIAL PROTECTION INFORHATION RESPIRATORY PROTECTION: None normally required. NIOSH approved for organic vapor if TLV .is exceeded. VENTILATION: Local exhaust if above TLV. PROTECTIVE EQUIPMENT: Sa~e~y g~asses recommended. . ateri Safety Data Sheet" M~nufacturer'. ~- ~mergency H,~o Bo~t;lk Construction P~oduc~6 91vtBton Te~6oneH~ -881-o033 Address / I . ~ ' O~h~ (, ] ' ~ . ' ' ' , - lnform.~n ]zu C a. 900 '" " 'ITY m~ · SECTIONI-IDE~ ~ '" ' ~ ' '~""'~" ' ' ~o~p?. H.~: (.,~ o~ i%et)tlydroment Ceramic' ~Tt le Grout leu Ho, '¢ ' ''''""""'"'~°"m') Jo~ n~ ~4 ]; ~.TU-pox~ ~/D A;~e~a~e' ~/A'. : · :'.i%'., Ch~n~c~ ' ,, · ~ ..... '.. ' ',: *' '": ' "' '~ :' Chemlcd ro, m,~. Portland cement, 8tltca ~and, Zron ox/dee, Titanium Dioxide,.... Ha~neslum Ferrlte,Ca~bon Black. SE~'ION 2 - IIAZARDOUS INGREDIE~8' '* ~'rinclpM II~d~ ~m~nent(s} (ch~cM & m~on n~d4ll % Thre=hold kilt VMue ~) 8111ca 8and: G~8tall/ne:' (lqBOB-G0-~) <6~ See 08IlA 1910.1001 : Table Z-3 Portland Cemenb (6~9~-15-1) '<~5 50 mppor Titanium Dioxide (iR~6~-67-7) <~ ]5 mg/m~ Iron OXide (1309'~37.=1) ': <~ 1~ mg/m~ Magnesium Ferrt%e (12068~86-~) ' '<~ ' 10 mK/~t Carbon Black (1333-86-~) ~q q.5 ~g/mq SECI'ION 3 - PIIYS~CAL & CIIEMICAL Ct~CTERISTICS (Fire & Explosion Data) Boiliog Sp~flc Poi.t Not known ~o b0il Ora~tym,o-n.2.0_2.2 ~-~1~.$ N/A Percent Volotlle VApor . by Volume l%l N/A D..sltr~=."'. N/A ' ": ~ '" ' N/~ "' -~ ' "' ' ':' ' ~,,i,ty ~Ne~ m.=u,~t~m Reacts slowly wi~h ,a sltgh~ ~W.~r ~igible w.~, exobherm and hardens. Appenrnnce sndOdor Powde~j Ro odo~ ' . ,, , ...~1~'~ , .... . ,,. Flnsh Fl~mnhleUmi~ N/A ~w~ · . up~ ~xtln~sh~ , . Au~l~Uon Point ~/A h~ ~ byVolumo' ' .' Sp~iol Fha mghu,g r~,r, H/A " Unus.sl Fbe and . ~ . Exploslonll~ds ~/~ ""~'~ · ~ "~ ~' ' ' ' .... .... ~nbllRy Unltnblo C] Conditioo~ . .' SLflbl0 X to Avoid bl o n e ..... ' , (M.ted.ls,toAvoldl ., Produc'~ may coa'~ula~e-or [loceu"~a~e tg mixed 'w~h highly tonic soluLton, or'organic .olven~.. I1.~..I... " ' ' - ' ' . iln~nrdmt, ,, Mny Occur U Conditiqne I ' , I'nlymedzntlon Will~oL~ccur ~ ~Avold ' ~one SECTION 5 - IIEALTII IIAZAILDS .. ,, Thre~hohl ' ~ f ' I,hnltVnl,e ~O~ kn'o~n. .. .' ' TM '" s,,,~..[i I.Acu~ Irritat~on of 8'~in'ma~resuX~ from frequent or --. 2. Chro,lc . :. ' ~verexposuro ~'0 ~ k~O~tl , Medicfll Condition90e~rnll~ ' ACRrnvntedb)'~xpo~ure. ~O~ 'kno~.~. ' ' ' 4 '. , ChemicM Listed es Cntclnogen ' ' NMlonniToxicolo~ YeS~ Yes ~' OSIIA Ye$ I.A.Jt.O. or l'otentlol CflrcJ,ogen ~ / A I'rogr~m ~o . Mono~oph$ Ho ~ ' No__ / OSIIA I'rrmisaiblo ACUII! Threshold Other Hxposuro Exl'nsuleLimlt ~Oe known LlmltValue ~O~ known U~tUoe~, ' Hoe kqown I~lller~elJev fllJ([ ) Viral Aid I'toeedme$ .. . I. Inhnlntlon Hot known 2. Eyes " Flush ae once with lent of old water I[ irritation persi'ses, physicianP'' y. . .c a. Skh, ~a~h affected area wiLii soap and C01d ~ater aC Consul~ a phvsicia.R.if irtit.atton ~.e.rsist8. If conscious induce vomi~.i~g and 'call a physician. 81~0'1'1 ON ~ - SPECIAb PIIO'I'~C'I'ION INFORMATION "",ri,:':"'YProtectl'"'None required if good ventilation is maintained...~ear respirator :,,~,y'ra~d (HSilA/HIOSll..aooroved) s~x~able for ai~ coutaminanes'._e.ncountered.' , .' ~'~,~i~tion L6cnl -- ~lechnnjCol $peclg Oth~ Recommended ~xl,,ust Recommend~ene,~ Recommended 'N/A ' I'lotective ~lyo . · . (;to,'es ' ImperviOus ¢ 'J "'z" ( .... '"'' I'rot~tlon ' Chemical splash goggles (}Liter I'roteCtlVe ,. ~ , . : Clothi,g or Equipment N [~ ' .'.' I ....... SECTION 7 - 81'EOlAb PRECAUTION8 AND 8PILLIL~AK PROCEDUILE8 '. J'r,ernutio,s to be 3'flken inllnt.lli,,gandStornge Keep from freezin~ product ma~ coagulate'. othf, r I'~ecfl,timts ~ O B e ~???'.~'Q'~tcc~,llle. Keep Spectators away. : Floor' may: be aZipperyl'use care to avoid rat tlnR_,uzKe and contain -hill ~tti~ ine.l~~al~~d or ~[~). Transfer liquid to container· for iecoVery or disposal and%~l-td diking.. materia[~parate container.Kee~ spillslruno[i~ out of ~evers.and open-waters w-~,'u~,Po'~Coagulate the emulsion by step~ise addition of ferric chloride MeLI,,,,I, l~me. Remove the..clear supernatant:liquld and flush to chemicai'seu~r. Land fill or inc{nerate :he aolidd and the contaminated dikin8 material ac'cordin~ to local,~tate.~nd Federal regulations. IMPOILTANT ~ ' ~o ,ot lcnve'n-~ bin,lc spaces. Ir required luformatlou is unavailable, unlmown~ or d~es not DPpI~' so Indlca~. l Iatcrml Safety Data Shee : ~ydromenL 965 :.:..' ', ;':..'.. ' , ~ ' . ~ ~'. ~ · .......... ; ................ . .;. . ........., .: .... ,'. ': ...... .. ~'~' Bosttk Cm truct'~oH P~ddue~s.Dtvtatnn ',.w,o.e,~ Plg-Ra1-OO~2 P.O. Box ~ ~ llun~ do Valle ,Pa.19006 215-67Q-~600 f~adeHame&S~°nym'l712- 765'. 760 ;l'lydromen~ Single S~ep., Hydtoment.'.~6~ '. C~ s ,o ~ N/A J'Hnclp~ I I~dous ~m~n~qs) (d~ & ~n n~ell ~ ' ~ .. T~e~hoid LJ~t' ~ue ' Portland ~ement ' . {659 2 2' ~' ' Silica sana,crTstalltn, (14808-~'0~7) ' <49 See OSHA'."lglff. 1001 , Table` Z-3 ,'. Bentonite (1302-78-9) <~ 15 ms/m3 ~ ' :.. SEUrlON 3 - PIIYSiCAL & CIIEMIC~ CIIAI~'EIIISTICS (Fire & Explosion Data} Percent Volatile ' V.~r · ' Evo~raHon I~ I '" ~lubillt~ Itenctlvit~ln lleacts slowly With a sltgh~ Apl~atnnce . :. · ,,~o~o. Po~de~a no Odor. Au~l~Uon . ~'.~ . . Stnbla X ~ Avoid NO~ , ' , ' ' )'olymerization WIUNotOceur ~ ~Avold .*'. '. ' i": : : ~i~.,,.d ~l.A~u~ .... Repeated inhalation of respl~able dust fo~ extended . zch.o.lc Hep~ated inhala$ign or resoir~ble dust for extended periods or o.~,,.~o,,,, time may cause ln.lu~V to the Medical Conditions Oen ~[~ Aggravnt~b~poouro fiepea~d exposure ~i~hou~' ~e~nt~at9~y pwa~a~inn may ChemicnlLIstedosCarcaosen NatlondTodcolo~ Yes ~ i.A.B.O. Yes ~ O811A Yes OSIIA I'etmisslblo · '". " lCOllli'lueehold . . OtherEsposure .. Em~;~m~cy and " , First Aid P;ocedutel i. Inhalation None 2. Eyes 3.5kin [ ' ~ Avoid ~rolonged' contact w1~h skin. rinse' w~th elean'~a~e~ rn~ 1~ mt nute8. 4. Ingestion N/, . -- 8EO'I'ION 6 - 81'gOIlL PItOTgOTION INFORMATION ' Be~ldrntoty I';otection ~s,,,~,~Ty,,~ NIOSIt approved for dusty, environment, L~'~rren~ EPAM~h~ic'l . sp~id Otb. c;]o,., For sensitive skin SECTION 7 - SPECIAL I)IIECAUTION8 AND 8PIL~LEAK PROCEDURES ' ' ' inllnndU.gnndSW,nS~ Avoid dust~ C_nditi___. " , . " Other Avoi~ pgol0nged contact between skin surfaces and wet' i~t' i'recputiono portland_ . c~men:'. . 'Skin'a~$as._.tha~ have.' been in contac. ....: por~land cement should be washed promptly and thorouEhly Hith fresh clean ~ater for 15 mtn.res: .. 5(cps In be Taken In Ca'se- '. Mnte,lallslteleas~or~plU~ Avoid excessive duSting. " .. Waste Disposal I · r .~,,tJ,od, Preferred procedure ts t/o 'v~cuum material. Ir not spray, with water ' andS.clean up with br. oom(and{shovel. ~i~po~e of 1n accordance with - Ua not leave'anY blank spnce~. Ir req~red ~onnagon I~ unav~abl~ ml~o~, or does not apply, so Indies,.