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Home My WebLink AboutBUSINESS PLAN HazardOus MaterialS/Hazhra°us.WaSte: Unified Permit Permit ID ~:: 015~00~00460 *: ~ Risk~n~e~P~mm LOCATION: 4000 BUCK OWENS BLVD . OFFICE OF EN~R ONM~NTAL SER ~CES' 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 ~meofEv~S~i~ Voice (661) 326-3979 F~ (661) 326-0576 ExpimtionDate: 'June 30. 2003 Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE ............. ~=~,,~,~?~,~,, .............. This permit is issued for the following: .,~ ~,~!'~}'=i: j; !:,,?:?:;i }~i!ii*~;~. ~:.ii il i!i~; iiii?'i~:~:~i:~=~i~e[ground Storage of Hazardous Materials PERMIT ID# 015-021000460 ,~i~i ~i il ili? '[!,.!~!!!~:!!';!!!}!!i:?!~.::!!!i!i~!! ,.:~ii}} !~!!~kii~nagement Program LOCATION 4000 PIERCE *?~?~/%%~?..?'~:= ~-~ ="-~ ~:'~"~'=':~'~'" ~'~'B~S~[~D CA B~er,field Fke D~ment Approv~ by: O~CE OF E~R ONe.AL 5~ ~CES ~ ~ph Hu~~ 1715 Chewer Ave., 3rd Floor Office of~~l B~e~el~ CA 93~01 Voice (80S)~2~070 Expiration~t~: dun~ ~O~ ~OO0 F~ (805) 32~576 CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3rd Floor, Bakersfield, CA 93301 FACILITY NAME ~)&tt'~tt~ ~)OtDc. t _]~r'C... INSPECTION DATE [0.[30 lOC) ADDRESS t40~t3 Ge. lc Ota)c~_~ O, Iod' PHONE NO. _~7- '7,3_'/~ ' FACILITY CONTACT BUSINESS ID NO. 15-210- INSPECTION TIME NUMBER OF EMPLOYEES t~ Section 1: Business Plan and Inventory Program 'J~ Routine [~] Combined [~ Joint Agency [~ Multi-Agency ~ Complaint [~ Re-inspection OPERATION C V COMMENTS Appropriate permit on hand Business plan contact information accurate Visible address ~ ,, / Correct occupancy / Verification of inventory materials Verification of quantities Verification of location Proper segregation of material Verification of MSDS availability ~, / Verification of Haz Mat training L/ Verification of abatement supplies and procedures / Emergency procedures adequate L,, / Containers properly labeled Housekeeping Fire Protection Site Diagram Adequate & On Hand C=Compliance V=Violation Any hazardous waste on site?: [~] Yes [~] No ~~ Explain: Questions regarding this inspection? Please call us at (661)326-3979 u~fi'~'isin~ss.~i~/espo~~ White - Env. Svcs. Yellow - Station Copy Pink - Business Copy Inspect°r: h~/~ J ~/~~_ _ _ PACIFIC POWER INC ;> Manager : '~ ~ BusPhone: (661) 327-7377 Location: 4000 BUCK OWENS BLVD '~,.,0~ ~ Map : 102 CommHaz : Moderate City : BAKERSFIELD ~/~ Grid: 23B FacUnits: 1 AOV: CommCode: COUNTY STATION 66 SIC Code: EPA Numb: DunnBrad: / Emergency Contact / Title ~Emergency Contact / Title JOHN R HAHN /~qt HAROLD L HAHN / Business Phone: (661) 327-7377x Business Phone: (661) 327-7377x 24-Hour Phone : (661) 5~ 5!93~[~73-7 24-Hour Phone : (661) 589-7645x Pager Phone : ( ) - x Pager Phone : ( ) - x Hazmat Hazards: Fire Press ImmHlth DelHlth Contact : Phone: (661) 327-7377x MailAddr: 4000 BUCK OWENS BLVD State: CA City : BAKERSFIELD Zip : 93308 Owner HAROLD L HAHN Phone: (661) 327-7377x Address : 11925 APRIL ANN State: CA City : BAKERSFIELD Zip : 93312 Period : to TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: No Emergency Directives: ~ Hazmat Inventory One Unified List ~ -- As Designated Order Ail Materials at Site ~ Hazmat Common Name... ISpeoHazlEPA HazardsI Frm DailyMax lunit MCP MOTOR OIL F DH L 300 00 GAL Min WASTE OIL F DH L 55 00 GAL Low SOLVENT F DH L 55 00 GAL Mod OXYGEN F IH DH G 154 00 FT3 Low ACETYLENE F IH DH G 640 00 FT3 Hi ARGON ~,~--_~o~ ;~ DO ~eFyP~ IH G 381 00 FT3 Min DIESEL #2 ce~i~fl~bB~/ha~ 300 oo GAL Low CY~ or ~nt name) 55 00 GAL Low ANTIFREEZE (COOLANT) DH L reviewed the a~ached haza~ous mmedals manage- ',, mere plan for~Ar~:. ,~,o(:~ .7~ and ~hm i~ along ~i~h (Na~ of Busine~) any corre~ions constitute a complete and correc~ man- agement plan for my ~cili~. -1- J~-/~-'/.,D 09/28/2000 ~gna~re Date PACIFIC POWER INC SiteID: 015-021-000460 ~ Inventory Item 0001 Facility Unit: Fixed Containers on Site -- CO~ON NAME / CHEMICAL NAME MOTOR OIL Days On Site 365 Location within this Facility Unit Map: Grid: SO~HEAST CO~ER CAS# 8020835 F STATE ~ TYPE PRESS~E TEMPERATURE CONTAINER TYPE JLi~id ~Pure I A~ient I A~ient DR~/BARREL-METALLIC MOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average G~ 300.00 G~ 55.00 GAL RAZ~DOUS COMPONENTS 100.00 Motor Oil, Petroleum Based N 8020835 ~Z~D ASSESSMENTS 'TSecretl RS BioHaz' Radioactive~Amount EPA Hazards NFPA USDOT# MCP IIINo No No No/ Curies F DH / / / Min ---- Inventory Item 0002 Facility Unit: Fixed Containers on Site -- COMMON NAME / CHEMICAL NAME WASTE OIL Days On Site 365 Location "within this Facility Unit Map: Grid: E MIDDLE OF YARD CAS# 221 FSTATE ~ TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid i Waste I Ambient I Ambient [ DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average GAL 55.00 GALI 55.00 GAL HAZARDOUS COMPONENTS 100.00 Waste Oil, Petroleum Based N HAZARD ASSESSMENTS ITSecretl RS BioHazI Radioactive/Amount I EPA Hazards I NFPA USDOT# MUP No No No No/ Curies F D}t / / / Low 2 09/28/2000 PACIFIC POWER INC SiteID: 015-021-000460 Inventory Item 0003 Facility Unit: Fixed Containers on Site -- COMMON NAME / CHEMICAL NAME SOLVENT Days On Site 365 Location within this Facility Unit Map: Grid: EAST SECTION OF BUILDING CAS# 8030306 F STATE I TYPE PRESSURE --[ TEMPERATURE CONTAINER TYPE Liquid Pure Ambient Ambient OTHER - SPECIFY AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average GALI 55.00 GAL 55.00 GAL HAZARDOUS COMPONENTS %Wt. Naphtha ~S CAS# 100.00 N 8030306 HAZARD ASSESSMENTS TSocrotlRsIBioHazRadioaotivo/AmountEPAHazardsNFPAIUSDOT#MCP No No No No/ Curies F DH / / / Mod = Inventory Item 0004 Facility Unit: Fixed Containers on Site q -- COMMON NAME / CHEMICAL NAME OXYGEN Days On Site 365 Location within this Facility. Unit Map: Grid: SOUTHEAST END OF BUILDING - PORTABLE CAS# 7782-44-7 Gas /Pure Above Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION' Largest Container Daily Maximum Daily Average FT3 154.00 FT3 154.00 FT3 HAZARDOUS COMPONENTS %Wt. ~SI CAS# 100.00 Oxygen, Compressed N 7782447 RS BioHaz Radioactive/Amount EPA Hazards. NFPA USDOT# MCP No No No/ Curies F IH DH / / / Low 3 09/28/2000 PACIFIC POWER INC SiteID: 015-021-000460 ~ Inventory Item 0005 Facility Unit: Fixed Containers on Site -- COMMON NAME / CHEMICAL NAME ACETYLENE Days On Site 365 Location within this Facility Unit Map: Grid: SOUTHEAST COWER CAS# 74-86-2 FSTATE i TYPE PRESS~E ~ TEMPE~TURE CONTAINER TYPE Gas Pure Above Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average FT3I 640.00 FT3 640.00 FT3 HAZARDOUS COMPONENTS 100.00 Acetylene Yes 74862 HAZARD ASSESSMENTS TSecretlRsIBioHazRadioactive/AmountEPAHazardsNFPAIUSDOT#MCPNo No No No/ Curies F IH DH / / / Hi ~ Inventory Item 0006 Facility Unit: Fixed Containers on Site 9 -- COMMON NAME / CHEMICAL NAME ARGON Days On Site 365 Location within this Facility Unit Map: Grid: SOUTHEAST END OF BUILDING - PORTABLE CAS# 7440-37-1 r STATE ~ TYPE PRESSURE ITEMPERATURE I CONTAINER TYPE Gas /Pure Above Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average FT3 381.00 FT3 381.00 FT3 HAZARDOUS COMPONENTS 100.00 Argon N 7440371 HAZARD ASSESSMENTS -- ~ ''TSecret' RS BioHaz' Radioactive/Amount EPA Hazards NFPA USDOT# MCP line No NoI No/ Curies F P IH / / /, Min -4- 09/28/2000 PACIFIC POWER INC SiteID: 015-021-000460 ~ ~ Inventory Item 0007 Facility Unit: Fixed Containers on Site -- COMMON NAME / CHEMICAL NAME DIESEL.~2 Days On Site 365 Location within this Facility Unit Map: Grid: SOUTHEAST CORNER CAS# 68476-34-6 ~ STATE TYPE PRESSURE TEMPERATURE I CONTAINER TYPE Pure I Ambient DRUM/BARREL-METALLIC lLiquid I Ambient AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average GAL 300.00 GALI 55.00 GAL HAZARDOUS COMPONENTS 100.00 Diesel Fuel No. 2 N 68476302 HAZARD ASSESSMENTS TSoorotI RSIBi°HazI Radioactive/Am°unt I EPA Hazards I NFPA USDOT# I MCP No No No No/ Curies F IH DH / / / Low -~ Inventory Item 0008 Facility Unit: Fixed Containers on Site ~ -- COMMON NAME / CHEMICAL NAME ANTIFREEZE (COOLANT) Days On Site 365 Location within this Facility Unit Map: Grid: 55 GALLON DRUM LOCATED SOUTHEAST CORNER OF BUILDING. CAS# 107-21-1 r STATE ~ TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid ~Pure I Ambient I Ambient I PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average GAL 55.00 GAL [ 55.00 GAL HAZARDOUS COMPONENTS 100.00 Ethylene Glycol N 107211 HAZARD ASSESSMENTS -- ITSoorotI RSIBioHazI Radioactive/Amount I EPA Hazard.~ I NFPA USDOT# [ MCP No No No No/ Curies DH / / / Low 5 09/28/2000 ~ PACIFIC POWER INC SiteID: 015-021-000460 Fast Format ~ Notif./Evacuation/Medical Overall Site --Agency Notification 02/13/1991 OFFICE OF EMERGENCY SERVICES SACRAMENTO, CA. 1-800-852-7550 HAZARDOUS MATERIAL COORDINATOR 1-~5-326-3979 FIRE DEPARTMENT 911 -- Employee Notif./Evacuation 02/13/1991 FIRST EMPLOYEE NOTICING FIRE, OR HAZARDOUS SPILL WILL CALL OUT OR DIRECT REST OF STAFF TO EVACUATE OUT OF BLDG BY THE NEAREST EXIT (NOT CLOSE TO DANGER). GO TO NEIGHBOR BUSINESS AND CALL 911 FOR HELP. -- Public Notif./Evacuation 02/13/1991 EVACUATION MEETING PLACE: AT HWY PATROL OFFICE ADJACENT TO THE NORTH SIDE OF BUSINESS. Emergency Medical Plan 02/13/1991 MANOR MEDICAL GROUP 6 09/28/2000 F PACIFIC POWER INC SiteID: 015-021-000460 Fast Format = Mitigation/Prevent/Abatemt Overall Site --Release Prevention 02/13/1991 FUEL AND OIL SPILLS ARE CLEANED UP BY ABSORBENT AND STORED IN CLOSED CONTAINER. CARB CLEANER SPILLS ARE CLEANED UP BY A~SORBENT AND STORED IN CLOSED CONTAINER. PAINT SPILLS ARE CLEANED UP BY DISPOSABLE RAGS AND DEPOSITED IN CLOSED CONTAINER SAFELY. MEETINGS ARE HELD FOR SPILLS OF FUEL AND OIL AND GENERAL SHOP RULES AND SAFETY. -- Release Containment 02/13/1991 RUPTURE BASINS AND OIL ABSORBANT MATERIALS -- Clean Up 02/13/1991 SQUEE-GEE, SHOVELS, PUSH BROOMS, AND RAGS ~ Other Resource Activation -7- 09/28/2000 PACIFIC POWER INC SiteID: 015-021-000460 Fast Format ~ Site Emergency Factors Overall Site Special Hazards --Utility Shut-Offs 10/23/1990 A) GAS - LEFT HAND SIDE OF BUILDING 4FT FROM FRONT B) ELECTRICAL - LEFT HAND SIDE OF BUILDING 25FT FROM FRONT C) WATER - LEFT FRONT OF BUILDING 2FT FROM LEFT SIDE D) SPECIAL - NONE E) LOCK BOX - NO -- Fire Protec./Avail. Water 10/23/1990 PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND W~ER HOSES FIRE HYDRANT - SOUTHWEST CORNER OF PROPERTY. Building Occupancy Level 8 09/28/2000 PACIFIC POWER INC SiteID: 015-021-000460 Fast Format = Training Overall Site -- Employee Training 05/07/1996 WE HAVE 6 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: PERIODIC MEETINGS DISCUSSING CONTENTS OF MATERIAL IN VARIOUS PRODUCTS WE USE. -- Page 2 --Held for Future Use Held for Future Use -9- 09/28/2000 MISCELLANEOUS RECEIVABLES ADJUSTMENT DATE ~'"/~- __~' NEVVACCOUNT AOO~SS CHANG~ CLOSE ACCT · FINANCE CHARGE · OTHER ADJ CUSTOMER NAME ~)~ o/i ~', C~ ~') ~ C~ ~ C, MAILING ADDRESS u~O(~(~ ~i ~ C~___. ~_~ CITY ~~_6.¢% ~'i CI C[ STATE ~~ ZIP CODE~ %:~ O~ SITE ADDRESS PARCEL NUMBER OFAPPUCA~L~ ADJUSTMENT I CHG DATE CHARGE CODE ADJUSTMENT AMOUNT I. t REMARKS: '~'-'~ ~C %or'mC_ ,~O.d.~'¢~____ 04/05/96 PACIFIC POWER INC 215-000-000460 Page 1 Overall Site with 1 Fac. Unit General Information Location: 4000 PIERCE RD Map:102 Haz:3 Type: 3 City : BAKERSFIELD Grid: 23B F/U: 1 AOV: 0.0 Contact Name Title Contact Name Title JOHN R. HAHN / HAROLD L. HAHN / Business Phone: (805) 327-7377x Business Phone: (805) 327-7377x 24-Hour Phone : (805) 589-5183x 24-Hour Phone : (805) 589-7645x Pager Phone : ( ) - x Pager Phone : ( ) - x Administrative Data Mail Addrs: 4000 PIERCE RD D&B Number: City: BAKERSFIELD State: CA Zip: 93308- Comm Code: 215-066 COUNTY STATION 66 SIC Code: Owner: HAROLD L. HAHN RECeiVeD Phone: (805) 327-7377 Address: 11925 APRIL ANN State: CA city: BAKERSFIELD 0 ? zip: 93312- Summary HA~ ~A~ DI~ I, .~ /~A/-i~J Do hereby certify that I have ' O'¥Pe or p6nt na~ne) reviewed the attached hazardous materials manage- ment plan for ~c,1~ c./~~nd tha'~, it along with (Name of i~usine~) any corrections constitute a complete and correct man- agement plan for my facility. 04/05/96 PACIFIC POWER INC 215-000-000460 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-005 ACETYLENE Gas 640 High · Fire, Immed Hlth, Delay Hlth FT3 02-003 SOLVENT Liquid 55 Moderate · Fire, Delay Hlth GAL 02-004 OXYGEN Gas 154 Low · Fire, Immed Hlth, Delay Hlth FT3 02-002 WASTE OIL Liquid 55 Low · Fire, Delay Hlth GAL 02-007 DIESEL #2 Liquid 300 Low · Fire, Immed Hlth, Delay Hlth GAL 02-006 ARGON Gas 381 Minimal · Fire, Pressure, Immed Hlth FT3 02-001 MOTOR OIL Liquid 300 Minimal · Fire, Delay Hlth GAL 04/05/96 PACIFIC POWER INC 215-000-000460 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-005 ACETYLENE Gas 640 High · Fire, Immed Hlth, Delay Hlth FT3 CAS #: 74-86-2 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: FABRICATION Daily Max FT3 I Daily Average FT3 I Annual Amount FT3 640 ~ 640.00 3,200.00 Storage Press T Temp Location PORT. PRESS. CYLINDER IAbove 1AmbiontlsouTHEAST CORNER -- Conc Components MCP ---TGuide · High ! 17 100 0% IAcetylene 02-003 SOLVENT Liquid 55 Moderate · Fire, Delay Hlth GAL CAS #: 8030306 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: CLEANING Daily Max GALI Daily Average GAL I Annual Amount GAL 55 ~ 55.00 55.00 StorageIIPress T Temp Location OTHER - SPECIFY IAmbient~AmbientlEAST SECTION OF BUILDING -- Conc Components MCP ---TGuide 100.0% INaphtha IModeratel 27 02-004 OXYGEN Gas 154 Low · Fire, Immed Hlth, Delay Hlth FT3 CAS #: 7782-44-7 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELDING SOLDERING Daily Max FT3I Daily Average FT3 ] Annual Amount FT3 154 i 154.00 300.00 Storage I Press T Temp I Location PORT. PRESS. CYLINDER Above ~Ambient SOUTHEAST END OF BUILDING - PORT -- ConcI Components I MCP ---~uide 100.0% IOxygen, Compressed ILow ~ 14 04/05/96 PACIFIC POWER INC 215-000-000460 Page 4 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-002 WASTE OIL Liquid 55 Low · Fire, Delay Hlth GAL CAS #: 221 Trade Secret: No Form: Liquid Type: Waste Days: 365 Use: WASTE Daily Max GAL I Daily Average GAL I Annual Amount 55.00 GAL -- 55 I 55.00 Location Storage ~lPress T Temp DRUM/BARREL-METALLIC [ambient[ambient[E MIDDLE OF YaRD Guide - ConsI Components ILo~CP I 27 100.0% iWaste Oil, Petroleum Based 02-007 DIESEL #2 Liquid 300 Low · Fire, Immed Hlth, Delay Hlth GAL CAS #: 68476-34-6 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: FUEL Daily Max GALI Daily Average GAL I Annual Amount 600.00 GAL -- 300 I 55.00 Storage Press T Temp Location DRUM/BARREL-METALLIC IAmbient~ambientlsouTHEaST CORNER -- Cons Components MCP iGuide 100.0% IDiesel Fuel No. 2 IModeratel 27 02-006 ARGON Gas 381 Minimal · Fire, Pressure, Immed Hlth FT3 CAS #: 7440-37-1 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELDING SOLDERING Daily Max FT3 Daily Average FT3 Annual Amount FT3 -- 381 I 381.00 700.00 Storage Press T Temp Location PORT. PRESS. CYLINDER Above ~AmbientlSOUTHEAST END OF BUILDING - PORT -- Cons Components . MCP iGuide 100.0% Iargon IMinimal ~ 12 04/05/96 PACIFIC POWER INC 215-000-000460 Page 5 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-001 MOTOR OIL Liquid 300 Minimal ~ Fire, Delay Hlth GAL CAS #: 8020835 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: LUBRICANT Daily Max GAL I Daily Average GAL I Annual Amount GAL 300 ~ 55.00 600.00 Storage Press T Temp Location DRUM/BARREL-METALLIC IAmbient~AmbientlsouTHEAST CORNER -- Conc Components MCP Guide 100.0% IMotor Oil, Petroleum Based Minimal 27 04/05/96 PACIFIC POWER INC 215-000-000460 Page 6 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification OFFICE OF EMERGENCY SERVICES SACRAMENTO, CA. 1-800-852-7550 HAZARDOUS MATERIAL COORDINATOR 1-805-326-3979 FIRE DEPARTMENT 911 <2> Employee Notif./Evacuation FIRST EMPLOYEE NOTICING FIRE, OR HAZARDOUS SPILL WILL CALL OUT OR DIRECT REST OF STAFF TO EVACUATE OUT OF BLDG BY THE NEAREST EXIT (NOT CLOSE TO DANGER). GO TO NEIGHBOR BUSINESS AND CALL 911 FOR HELP. <3> Public Notif./Evacuation EVACUATION MEETING PLACE: AT HWY PATROL OFFICE ADJACENT TO THE NORTH SIDE OF BUSINESS. <4> Emergency Medical Plan MANOR MEDICAL GROUP 04/05/96 PACIFIC POWER INC 215-000-000460 Page 7 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention FUEL AND OIL SPILLS ARE CLEANED UP BY ABSORBENT AND STORED IN CLOSED CONTAINER. CARB CLEANER SPILLS ARE CLEANED UP BY ABSORBENT AND STORED IN CLOSED CONTAINER. PAINT SPILLS ARE CLEANED UP BY DISPOSABLE RAGS AND DEPOSITED IN CLOSED CONTAINER SAFELY. MEETINGS ARE HELD FOR SPILLS OF FUEL AND OIL AND GENERAL SHOP RULES AND SAFETY. <2> Release Containment RUPTURE BASINS AND OIL ABSORBANT MATERIALS <3> Clean Up SQUEE-GEE, SHOVELS, PUSH BROOMS, AND RAGS <4> Other Resource Activation 04/05/96 PACIFIC POWER INC 215-000-000460 Page 8 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - LEFT HAND SIDE OF BUILDING 4FT FROM FRONT B) ELECTRICAL - LEFT HAND SIDE OF BUILDING 25FT FROM FRONT C) WATER - LEFT FRONT OF BUILDING 2FT FROM LEFT SIDE D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND WATER HOSES FIRE HYDRANT - SOUTHWEST CORNER OF PROPERTY. <4> Building Occupancy Level 04/05/96 PACIFIC POWER INC 215-000-000460 Page 9 00 - Overall Site <G> Training <1> Employee Training WE HAVE ~MPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: PERIODIC MEETINGS DISCUSSING CONTENTS OF MATERIAL IN VARIOUS PRODUCTS WE USE. <2> Page 2 <3> Held for Future Use <4> Held for Future Use BAKERSFi ELD CITY FIRE DEP/ ITMENT HAZARDOUS MATERIALS INVEN'IR:)RY Page.._of_._ CHEMICAL DE$CRII~rlON .~,=~:? '. ~. , · ~ ) INVF. NTORY STATUS: Ne~ Addition [ ] Revmon [ ] Delefioa { ] Che¢~ if chemical ia · NON TRAD~ SEC.-eT i,,ri TRAi3~ 4) PH~IC~ & H~ PH~IC~ H~ H~D CA~GORIES Fire [ ] Rede { ] Sudden Relate of Pressure [ ] Immeeiae He~ (~e) ~ ~) w, sm c~ss~cA~o. ~-I~C (3~i~ ~ae ~= OHS Fo~ ~o~) USE CODE 7) AMOUNT AND ~ME AT FAClU~ U~TS OF M~SUR~ 8)'STOOGE C0~S - M~mumOa~Amount: '~ ~lJO~ ~ [ ] ga ~ ~3 [ ] a) Con~ Annua Amount: ~ ~11 o~ c) Tem~r~m: ~. ~est Size'Contane~ ~jJ o~ ~O~OnSite ~ Gi~cle~ic~om~s: ~ll~d, ~, ~, A. M, & ~, A. S, O, N, D' 9) ~i~RE: Ust COMPON~ CAS · % ~ ~M c~eml~ com~.e~ or CHEMICAL DESCRI~ION ~)IN~NTORYSTA~S: New( ] ,*ddRion[ ] ~e~sion( ] Deletion{ ] Che~cnem~aNON~OES~ [ ] ~DESECR~ [ ] ~) Common N~e: 3) ~T · (o~ Chem~ca N~e: AHM [ ] CAS ~) PHYSICAL & H~L~ PHYSICAL H~ H~D CA~GORIES F~re ] ~ea~ve ( ] Su~en Rete~e of Pressure [ ] Jmme0i~eHe~ (Accel ( ] ~) WAS~ C~SSIFICA~CN ~ig[t co~e from OHS Fo~ 8022) USE CODE 5} PHYSICAL STA~ Solid [ Ueu~d [ G~ [ ] Pure { j M~ure [ ] W~te [ ] R~m~ [ ] 7) AMOUNT AND ~ME AT FAC~ ;NITS CF M~SURE 8) STOOGE CCDES M~mumOaiyAmount: .. '~ { ] ;~ [ ] ~3 [ ] a) Contane~ Average GaN Amount: curies [ ~ b) Pressure: Annu~ Amount: c) Tem~m: ~est Size Cont~ne~ ~ Oa~OnSite C~r~e~ic~Montns: ~lYe~. J, F, M. A. M. J, J. A, S. O, N, O 9) MITRE: ~st CCMP~N~ CAS · the three most h~ous ; ~ [ ] cnem~ com~nen~ or lO) ~. ' .~ unaer pen~ ot law, ~at I nave ge~ e~n~ ~ ~ t~lll~ wl~ ~e ~ntom~n SUDmI~ on ~a ~ ~1 ~ I~ N~e & ~ge of ~nz~ Com~ ~e~s~e Sig~m' BAKERS Pt ELD CITY FIRE DEPARi'MENT ! OFFICE OF ENVIRONMENTAL SERVICES 1715 CHESTER AVENUE, 3RD FLOOR '-~ BAKERSFIELD, CA 93301 (805) 326-3979 HAZARDOUS MATERIALS INVENTORY FACILITY DESCRIPTION CHECK tF BUSINESS IS A FARM [] aiC CCDE ~UN & B~DSTREET NUMBER EMERGENCY CONTACTS BUSINESS ,--'HONE ~--.Z,'~-?~,'7'~ 24-HOUR PHONE BUSINESS PHONE '~.,~"-)'-'"'~""2 ") 24-HOUR PHONE 07/271~ PACIFIC POWER INC 215-000-000460 Page 1 Overall Site with 1 Fac. Unit General Information Location: 4000 PIERCE RD Map: 102 Hazard: Moderate Community: COUNTY STATION 66 Grid: 23B F/U: 1 AOV: 0.0 Contact Name Title Business Phone 24-Hour Phone- JOHN R. HAHN (805) 327-7377 x (805) 589-5183 HAROLD L. HAHN (805) 327-7377 x (805) 589-7645 Administrative Data Mail Addrs: 4000 PIERCE RD D&B Number: City: BAKERSFIELD State: CA Zip: 93308- Comm Code: 215-066 COUNTY STATION 66 SIC Code: Owner: HAROLD L. HAHN Phone: (805) 327-7377 Address: 11925 APRIL ANN State: CA City: BAKERSFIELD Zip: 93312- Summary RECEIVED i$ P 0 2 1992 HAZ. MAT. DIV. ' (¥~p~ or Print name) reviewed the attached hazardous materials manage- ment plan for and that it alon~ ~{~h (~e of Business) any corrosions constituie a comple~s and corre~ man- ~eme~ p~an for my facility. ~m · D~e 07/27/~2 PACIFIC POWER INC 215-000-000460 Page 2 02 ' Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-001 MOTOR OIL Liquid 300 Minimal · Fire, Delay Hlth GAL CAS #: 8020835 Trade Secret: No Form: Liquid Type:. Pure Days: 365 Use: LUBRICANT Daily Max GAL I Daily Average GAL I Annual Amount GAL 300 ~ 55.00 600.00 Storage Press T Temp Location DRUM/BARREL,METALLIC IAmbient/AmbientlsouTHEAST cORNER· -Conc Components ' MCP List 100.0% IMotor Oil, Petroleum Based IMinimal I 02-002 WASTE MOTOR OIL ? 55 Low · GAL CAS #: Trade Secret: No Form: Unknown Type: Waste Days:~ Use: CLEA~ING ~ Daily Max GAL55 . Daily Average0~~~ Annual Amount55.00GAL Storage Press T Temp Location ABOVE GROUND TANK I IE MIDDLE OF YARD -- Conc Components MCP --~List 100.0% IWaste Oil, Petroleum Based ILow ' 02-003 SOLVENT ? 55 Moderate GAL CAS #: Trade Secret: No / Form: Unknown Type: Pure . Days: Use:CLEWING Daily Max GAL55 -~ I Daily Average0?~nnual Amount55.00GAL Storage Press Temp Location -- Cone Components ~ MCP List 100.0% INaphtha IModeratel 07/27/9~2 PACIFIC POWER INC 215-000-000460 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-004 OXYGEN ? 154 Low · ~~.'~L FT3 CAS #: Trade Secret: No ,. Form: Unknown Type: Pure Days: DING SOLDERING --~ Daily Max FT3 I Daily Average FT3 I Annual Amount FT3 154 ~ . 0.00 300.00 Storage Press Temp Location ABOVE GROUND TANK I T ISE END OF"BLDG -PORTABLE -- Conc Components MCP List 100.0% IOxygen, Compressed Low I 02-005 ACETYLENE Gas 640 High · Fire, Immed Hlth, Delay Hlth FT3 CAS #: 74-86-2 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: FABRICATION Daily Max FT3I Daily Average FT3 I Annual Amount FT3 640 ! 640.00 3,200.00 Storage ~ Press T Temp ~ Location PORT. PRESS. CYLINDER IAbove ~AmbientISOUTHEAST CORNER' -- Conc Components MCP ~List 100.0% IAcetylene IHigh! 02-006 ARGON ? 381 Minimal · FT3 CAS.#: Trade Secret: No Form: Unknown Type: Pure Days: Use: WELDING SOLDERING Daily Max FT3 Daily Average FT3 ~ Annual Amount FT3 I . ' I 7oo.oo Storage Press' Temp Location ABOVE GROUND TANK I T ISE END OF BLDG -PORTABLE -- Conc Components ! MCP List 100.0% ~lArgon IMinimal I 07/27/~2 PACIFIC POWER INC 215-000-000460 Page 4 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-007 DIESEL #2 Liquid 300 Low · Fire, Immed Hlth, Delay Hlth GAL CAS #: 68476-34-6 Trade Secret: No Form: Liquid TYpe: Pure Days: 365 Use: FUEL Daily Max GAL I Daily Average GAL I Annual Amount GAL 300 I 55.00 600.00. Storage Press T Temp ' Location DRUM/BARREL-METALLIC [Ambient~AmbientlsouTHEAST CORNER -- conc Components MCP List 100.0% IDiesel Fuel No.2 IModeratel 07/27/92 PACIFIC POWER INC 215-000-000460 Page 5 00 - Overall Site ' <D> Notif./Evacuation/Medical <1> Agency Notification OFFICE OF EMERGENCY SERVICES SACRAMENTO, CA. 1-800-852-7550 HAZARDOUS MATERIAL COORDINATOR 1-805-326-3979 FIRE DEPARTMENT - ' - 911 <2> Employee Notif./Evacuation FIRST EMPLOYEE NOTICING FIRE, OR HAZARDOUS SPILL WILL CALL OUT OR-DIRECT REST OF STAFF TO EVACUATE OUT OF BLDG BY THE.NEAREST EXIT (NOT CLOSE TO DANGER). GO TO NEIGHBOR BUSINESS AND CALL 911 FOR HELP. , <3> Public Notif./Evacuation EVACUATION MEETING PLACE: AT HWY PATROL OFFICE ADJACENT TO THE NORTH SIDE 'OF BUSINESS. <4> Emergency Medical Plan MANOR MEDICAL GROUP 07/27/9..2 pACIFIC POWER INC 215-000-000460 Page 6 O0 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention FUEL AND OIL SPILLS ARE CLEANED UP BY ABSORBENT AND STORED IN CLOSED CONTAINER. CARB CLEANER SPILLS ARE CLEANED UP BY ABSORBENT AND STORED IN CLOSED CONTAINER. PAINT SPILLS ARE CLEANED UP BY DISPOSABLE RAGS AND DEPOSITED IN CLOSED CONTAINER SAFELY. MEETINGS ARE HELD FOR SPILLS OF FUEL AND OIL AND GENERAL SHOP RULES AND SAFETY. <2> Release Containment RUPTURE BASINS AND OIL ABSORBANT MATERIALS <3> Clean Up SQUEE-GEE, SHOVELS, PUSH BROOMS, AND RAGS <4> Other Resource~C'tivation 07/27/92 PACIFIC POWER INC 215-000-000460 Page 7 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - LEFT HAND SIDE OF BUILDING 4FT FROM FRONT B) ELECTRICAL - LEFT HAND SIDE OF BUILDING 25FT FROM FRONTJ C) WATER - LEFT FRONT OF BUILDING 2FT FROM LEFT SIDE D) SPECIAL - NONE E) LOCK BOX - NO . <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND WATER HOSES FIRE HYDRANT - SOUTHWEST CORNER OF PROPERTY. <4> Building OccuPa,~¢~ Level 07/27/92 PACIFIC POWER INC 215-000-000460 Page 8 00 - Overall Site <G> Training <1> Page 1 WE HAVE 10 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: PERIODIC MEETINGS DISCUSSING CONTENTS OF MATERIAL IN VARIOUS PRODUCTS WE USE. <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use lOin-d/BI PA lC POWER INC 215-000-00[ ) Page 1 Overall Site with 1 Fac. Unit .~0 0~ 1990 General Ir, for~nat ion HA7 ~AAT. ~IV. Location: 4000 PIERCE RD Map: 102 Hazard: Moderate ~ Ident Nurnber: 215-000-(')00460 Grid: 23B Area of Vul: 0.0, I Contact Name ~ ~, I Title I .......... Busir, ess Phone ~ 24 Hour Ph,:,ne= ] JOHN R. HAHN ~ ~ (805) 327-7377 x ~ (805) 589-51831 Administrative Data Mail Addrs: 4000 PIERCE RD D&B Number: 0~78G5~01 City: BAKERSFIELD State: CA Zip: 93308- Cornrn Code: 215-001 BAKERSFIELD STATION 0i SIC Code: Owner: HAROLD L. HAHN Phone: (805) 327-~37'7 Address: 4~E~~~~ 11~5 ~pdl ~n' ,' State: CA City: ~~ ~i~ld,~: Zip: ~331~ - Summary Ii/,/#~-~_/-~/--' ~"~"Y'- Do hereby certlty that I have (TYpe or print na~le) reviewed the ~,qmched hazardous matorlal~ manage- ment pf~n ,or~_~_/,~/~"~/~)- and that it along with any corrections constitute a complete and correct man- agement plsn for my facility, 10/23/90 PACIFIC POWER INC 215-000-000460 Page 2 Hazmat Inventory List in MCP Order ~ 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Quantity MCP 02-005 ACETYLENE ~ 105 High FT3 02-003 SOLVENT 0 55 Moderate GAL 02-002 WASTE MOTOR OIL ~ 55 Low GAL 02-004 OXYGEN ~ 154 Low FT3 02-001 MOTOR OIL o 55 Minimal GAL 02-006 ARGON ~ 381 Minimal F'l'3 10/:='3/90 PAC'm~FIC POWER INC 215-000-00( Page 3 O0 - OYerall Site <D> Notif. /EYacuation/Medical <1> Agency Notification Office of Emergency Services Sacramento, Ca. 1-800'852-7550 Hazardous Material Coordinator Bakersfield, Ca. !-805-326-3979 911 Fire Department <2> Employee Notif./Evacuation FIRST EMPLOYEE NOTICING FIRE, OR HAZARDOUS SPILL WILL CALL OUT OR DIRECT REST OF STAFF TO EVACUATE OUT OF BLDG BY THE NEAREST EXIT (NOT CLOSE '¥0 DANGER). GO TO NEIGHBOR BUSINESS AND CALL 911 FOR HELP. <3> Public Nc, tif. /Evacuatior, EVACUATION 'MEETING PLACE: AT HWY PATROL OFFICE ADJACENT TO '['HE NORTH SIDE OF BUSINESS. <4> Emergency Medical Plan MANOR MEDICAL GROUP PACIFIC POWER INC 215-000-000460 Page 4 ex} - Overall Site <E> Mit igat iorWPrevent/Abatemt <1> Release Prevention FUEL AND OIL SPILLS ARE CLEANED UP BY ABSORBENT AND STORED IN CLOSED CONTAINER. CARB CLEANER SPILLS ARE CLEANED UP BY ABSORBENT AND STORED IN CLOSED CONTAINER. PAIN'[ SPILLS ARE CLEANED UP BY DISPOSABLE RAGS AND DEPOSITED IN CLOSED CONTAINER SAFELY. MEETINGS ARE HELD FOR SPILLS OF FUEL AND OIL AND GENERAL SHOP RULES AND SAFETY. <2> Release C,,,r, tainmer, t Rupture basins and oil absorbant materials. <3> Clear, Up Squee-Gee, .shovels, push brooms, and rags. <4> Other Resource Activation 10/23/90 PA~ POWER INC 215-O00-O00WO P~age 5 O0 - Overall Site <F> Site Er~ergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - LEFT HAND SIDE OF BUILDING 4FT FROM FRONT B) ELECTRICAL - LEFT HAND SIDE OF BUILDING 25FT FROM FRONT C) WATER - LEFT FRONT OF BUILDING 2FT FROM LEFT SIDE D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec. /Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND WATER HOSES FIRE HYDRANT - SOUTHWEST CORNER OF PROPERTY~ ~ <4> Held fo~* Futu~e use 10/23/90 PACIFIC POWER INC 215-000-000460 Page 6 O0 - Overall Site <G> Training <1> Page 1 10 WE HAVE ?? EMPLOYEES AT THIS FACILITY DO YOU HAVE MATERIAL SAFETY DATA SHEETS ON FILE? ¥~$ BRIEF SUMMARY OF TRAINING: Periodic meetings discussing contents of material in various products we use. <2> Page 2 as needed <3> Held for Future Use <4> Held for Future use CITY of BAKERSFIELDRECEIVED Farm and qticuiture [] Standard Business ~HAZARDOUS MAT.ERIAL8 TNVENTORY ' NON--TRADE SECRETS ij;~.~,, 031991Page ~_ of . USINESS NAME: P._a_c[fic Power Inc. . OWNER NAME: Harnld I Hnhn' Pr~im~nt 'NAME OF THIS FAC~II~klJ~'_.I~)taT, {![~.cific Power Inc, 0CATION; --.~u.uu ~.]erce Need _A~)_D.R. ES~;_ l l.q~5 A~ril Anh ~ .... STANDARD IND. CLASS' CODE~ CITY. ZIP~ J~EcrsHOld. (CA 9330B-4984CZ/Y. ZIP: ~akerst~eld CA 03312 DUN AND BRADSTREET NUMBER ...... Code cooe A.~ Amc Est Units on e ,ype Press Temp Co3e See ]nsLructtons ~ix~ure/Co~Donents _ SLorea In Al, ~ I aoo Is, 1'6oo I~,,I365 [061] 14'1-,~ I Southeast Corner 101 Physical and ffeal~h ~azard C.A.L Nuaber CoaP0nent II ~aae I C,I,S, ~er NA 1993 Texaco Diesel F~el {Check all ~hat a~01~l ~ . . Component Name I re Hazard ~ ReacLiviL~ ~ Delayed ~ Sudden Release ~[mmediace. I~ C.LS. Number 75?0-4 Shell Solvent Heal&h ' Health of Pressure Component 13 NAme I C.A,S. Number NA Exxon Gasoline PhySical ~od ~ealLh ~azard C,A,S. ~u~er :o~p0nen~ 11 ~a~e I C,~,S, ~uaber NA Valvoline Motor Oil / [Check ali that applH Component If Name I C,A.S, Number ~ire Hazard ~ Reactivity ~ Delayed ~ Sudden Release ~NmmediA~e Waste MotOr Oil Hea lLh of Pressure Componefl~ 13 Name I C.A.S. Number- A I P:, I 30 "l 50 -I ]m--IGaI. I 365 I 06 ! l [ 4. !.08;161 _~outheast Corner Physical and ~eal&h ~azard ' C.A,S. Number Componen~ I1 Name I C,A.S, Number NA Steam ~nn Soap ''~ '~-' (Check all ~ha& appl~) ,.. C'o=po~e~t 12 Name I C,A,S, Number13-163-67-7 ~ire Hazard ~ Reactivity ~ 0elayed ~ Sudden Release ~ .... jmmeo~ace - Ellis Paint Health of Pressure - Health . X~:~:~~. ,~, Componen& t3 Name I C.A.S. Numbe .~ 8032-32-4 ,~!,,~ ! ~o I~o I ~oo'-Iraqi ~ I~ I~ I~' I ~ I so.~.~ co~.~ ~o~ / {Check ali that app/yl ~.~- . Compoflen~ 12 Na.e'l C.A.S. Number 7782-44-7 Oxygen ~~ire ~azacd ~ ~activity ~ Oel~yed ~udd~Relea~ Health OT Pressure Health i- ;EMERGENCY CONTACTS fll John Hahn V.P; & ~neral Mgr; 589-5183 fl2 Harold Hahn President ' 589-7645 N~me , ' ~&l~ ' ~ Hr Phone Name TIHe ' z~ Hr ~one sUOmlt~e~ i~orm8CIofl lS true, accurate, and comHe~e. -' - ]2-26-90 Harold L. Hahn, President · ' · ~e e~d'0ficiai ti[ie of o~etlop~rator u~ ovner/ope~tor'~ authorized r~0resenta[tve ~9~re-~ Dear Business Owner: Enclosed please find a copy of your response to the Hazardous Material Management Plan (HMMP) request. We have found it necessary to reject your plan for the fdllowing reason(s) as checked below. ~-~ Illegible Management Plan (please print or type information). Section(s) z of HMMP incomplete. ' Inventory Missing or ~ Incomplete. Diagram Missing or ~--~ Incomplete. This is to be corrected and resubmitted within 30 days to: City of Bakersfield, Fire Department Hazardous Materials'Division 2130 G Street Bakersfield, CA 93301 If additional copies of any forms are needed they can be picked up from the Hazardous Materials° Division at 2130 G Street in person. Sincerely yours, ~rdous ,aterials Coordinator REH/ed i~--// - ~-''- BAKERSFIELD CITY FIRE DEPARTMENT 2130 "O" STREET BAKERSFIELD, CA 93301 RECE[VE~ (805) 326-3979 JUN 2 6 1987 A,td ............ OFFICIAL USE ONLY BUSINESS NAME HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE FORM 2A INSTRUCTIONS: .... . 1. To avoid further action, return this form by &qor"- 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA B. LOCATION / STREET ADDRESS: ~O~O /g~/f'/~C~ /~mD SECTION Z: E~RGENCY NOTIFICATIONS In case of an edergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-918-427-4841. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME ~ND %ITLE~ DURING BUS. HRS. AFTER BUS. HRS. SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE D. SPECIAL: E. LOCK BOX: YES / NO IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 2A - SECTION 4': PRIVATE RESPONSE TEAM FOR BUSINESS AS A hnrIOLE SECTION 5: LOCAL E~ERGENCY MEDICAL ASSIST~CE FOR YOUR BUSINESS AS A WHOLE SECTION 6: EMPLOYEE TRAINING /. EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER'TRAINING IN THE FOLLOWING AREAS. ~ CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAZARDOUS G¢ MATERIALS: NO YES NO B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGENCIES: .......................... ~ NO YES NO C. PROPER USE OF SAFETY EQUIPMENT: ..................~ NO 'YES NO D. EMERGENCY EVACUATION PROCEDURES: ................. NO YES NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... YES (~ YES NO SECTION 7: HAZARDOUS I~TERIAL CIRCLE YES OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN. 500 POUNDS OF_A, $$ GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES(N~ SOLID, I, //~L~ ~ //~/~ , certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6~5 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. .BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93501 ID# BUSINESS glJs SINGLE FACILITY UNI FORM 3A INSTRUCTIONS 1. To avoid further action, this form Inust be re'turned by: 2. TYPE/PRINT YOUR A~.;S'WERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. SECTION 1: MITIGATION, PRE~NTION, ABATEMENT PROCEDb~ES SECTION 2: NOTIFICATION ~%~ EVACUATION PROCEDb~ES AT THIS 5%'IT ONLY ~j~j ~ ~// 911 ~ ~/~ SECTION 8: HAZARDOUS ¥~ATERIALS FOR THIS UNIT ONLY ~A. Does this Facility Unit contain Hazardous ~ater~als? ...... NO If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form #4A-l) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form #4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRI~ATE FIRE PROTECTION SECTION 5: LOCATION OF WATER SuppLy F0R USE BY E,~fERGENCY RESPONDERS SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS 5~IT ONLY. A. NAT. GAS/PROPAN~'~ E. LOCK BOX: YES /~ IF YES, LOCATION: IF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS? YES /' NO KEYS? .YES / NO - 3B - I .D. ~ FORM 4A=l ~,,., Page _ NON--TRADE SECRETS HAZARDOUS MATERI ALS · I NVENTORY BUSINESS NA~E: ~ ~ O~NER NAME: ~,/ FACILITY"UNIT CITY, ZIP: ~~~ ~0~ CITY,ZIP: 0~;, ~ ~ 2 3 4 9 o v s 9 i o TYPE MAX ANNUAL CONT ;USE LOCATION IN Tills · BY llAZARl) lt.O.T., NAME: T I TLE: S I g : ~e, nsnncv contact: de/~ ~ ~~ t~tl, g: ~~ ~.o~ ~ BUs .ours: ~ '" avtgr ~us .rs: ~$/~$ ~,~.,;~.~ ~o~ta~t: ~~ C ~~ t,t~: ~ .,,o.~ . ..~ ,,ours: - .4A-I - ~' SITE/FACILITY DIAGR -" /' FORM 8 NOI~TH SCALE: .~ BUS I NESS .aXl~tE: FLOOR: DATE:,L/~/~/FACILITY N~ME: UNIT ~: 0F (Inspectov's Co~ents): -OFFICIAL USE ONLY- SITE DIAGRA/~ {Required items) 1. Address: Identify the 9, Lock (key) Box principle buildings by the Street numbers. 10. MSDS Storage Box 2. Street(s), Alleys, Il. Railroad Tracks Driveways, and Parking Areas adjacent to the 12. Fence or Barrier property. Include the a. Wire street names. b. Masonry 3. Storm Drains, Culverts~' Yard Drains c, Wood 4. Drainage Canals, Ditches, d. Gates Creeks, 13. Powerllnes 5. Buildings a. Frame construction 14. Guard Station b. Masonry construction IS. Storage Tanks: Identify the c. Metal construction capacity In gal, a. Above ground d. Access Door : b. Underground 6. Utility Controls a. Gas 16. Diking or Berm b. Electricity 17. Evacuation Routs c. #star 18. Evacuation Area: ~ Identify the ?. Fire Suppression Systems: location where a. Fire Hydrants employees will meet. b. Fire Sprinkler 19. outside Hazardous Connections Masts Storage c. Fire Standpipe 20. Outside Hazardous Connections Material Storage d. Water Control Valves 21, Outside Hazardous for protectloneyateee Material Use/Handling e. Fire Pu~p 22. Type of Hazardous Material/Masts Stored e. FAre Department Access or Used (See ~elou) TYP~ oF .R~RooUS ~T~iAL F - Flammable g '- Kxplosive L - Liquid R - Radlologlcal C - Corrosive 0 - Oxidizer G - Gms P - Poison # - Water Reactive T - Toxic S - Solid '~ - Cryogenic D.":- Waste 8 - Etiological Example: ~laamable Liquid - FL F~CILITY DIAGRA~ (Required Items la addition to the. abo~e) i. Risers toe Sprinklers O. Fire Escapee 2. Partitions g. Air Conditioning Units 3. Stairways: Indicate the 10. Windows levels served ~rom highest to lo=est. 11. Inside Hazardous Waste Storage 4. Escalator: Indicate the levels Served from 12. Inside Hazardous highest to lowest. Mater/als Stora~s 5. Elevator 13, Inside aazardous Materials Use/Handling 6. Attic Access '14. Sewer Drain Inlets ?. Skylights - HAT£RIAL. SAFETY DATA SHEET APPR0VEO BY U S LAB0~ DEPT, ESS.ENTIALLY SIMILA~ T0 ~0aM 0SHA174 BERRY~qAN PRODUCTS 3800 E RANDALL ~ILL ARLINGTON,TX 76011 E~RGENCY PHONE: CHEI4ICAL NA~E & ~YNOI, IY~S: Solvent TRADE ~A~: Che~-Dtp (0901,0902,0903,0905~0955) CHEMICAL FAMILY: Not Applicable FORMULA: Not Applloable I. PHYSICAL DATA BOILI~IG' RANGE :. 3~ 93 207'"C '/ 102 200 ~05'~ (*~End Point) APl GRAVITY :' Not Applicable SPECIFIC GRAVITY (~ter~l) : 1.313 POUND~/GALLON : 10.9.~1 ' . VAPOR PRESSURE (mm of Hg)~20~C : 124.9 VAPOR DENSITY (~ir~l) : ~.0 SOLUBILITY IN ,~ATER : Negligible SOLUBILITY IN ACID (85% H~SO~) : ~oderate DRY TI~E .;Ether~l) : Long ~/. VOLATILE BY VOL : APPEARANCE : Cla~r,~t er-~hita ODOR : Chlorinated II. HAZARDOUS I~GREDIENT~ NATERIAL .~ CAS ~ VOL(%) TLV(ppm) Dichlorometh~,ne ~ 75-09-~ Tetre, chlo~thyle~e' 12~-18-4 ~edtum Aliph~tic'Solvent N~phth~ *~4742-88-7 ) Honoohlo~o~oluene 25168-05-2 ) 5 50 Cre~ylio Acid ~ 1319-77-3 Potaszium Hydro~ide 1310-58-3 ) I Not Applicable DOT SHIPPING NA~E: C6mbustible Liquid,NOS HAZARD RA'rlNO '" HEALTH: 3 FLM~ABILITY: ~' REACTIVITY: (THIS PRODUCT flEETS R~OUIREMEI.IT~ OF L A RULE ~ ~ SIMILAR REGULATIONS) III. FIRE' $ EXPLOSioN HAZARD DATA LO~ER FLA~}IASLE LI~I~T IN AIR (% by.vol)' 0.9 (Lowest Component) FLASH POINT (TE~T ME~HOD): 45'C I II~'F (TCC) (Lowest Component) FLAH~ABILITY CLASSIFICATIOtI: Class 11 EXTINGUISHING : [.IFPA~ Clas~ B es[inguishers (COl or foam) MEDIA : for o1~9~ II liquid fires. ~PECIAL FIRE : ~ater spray may be ineffective on fire but can protect FIGHTING : fire fighters & cool closed cont~in~r~. Use fog nozzles PROCEDURES :. water i~ used. Use alr-~upplied breathing masks. UNUSUAL :',COI~BUSTIBLE! Keep container tightly closed. EXFLOSION : . Isolate from o~idizerS, heat, S open flame. AND FiRE : ~ Closed containers may esplode if esposed to eatreme heat. PROCEDURES : Applying to hot surfaces requires special precautions. Legal responsibility is assumed only for the fact that all studies reported here ~ all opinions are those of qualified esperts. ~uyer assumes all risk S liability. He ac~pts $ uses this material on these conditions. He must have a copy of this HSDS where mate[iai is handled. IV. HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: 35 ppm (Freshly Prepared) EFFECTS OF : INHALING: Anesthetic. Irritates respiratory tract. ACUTE : May cause slrious nervous system depression. OVER- : damage to kidneys,blood,nerves,liver.& lungs. EXPOSURE : Absorption thru skin increases e~posure. : SKI~I CONTACT: Primary irritation, deferring, dermatitis. : EYE EONTACT: Primary Irritation, redness, tearing, blurred vision. EFFECTS' OF : ~ POISON!! · ~ S%.;ALLO%;- : ~ CALL A PHYSICIAN ~ I I.I'G AND : CORROSIVE CHRONIC :.. ~dpor harmful. H~ating forms hazardou~ vapor. OVER- : Liquid causes severe skin &-eye burns . EXPOSURE : ~ash thoroughly after handling. : Absorption thru ~kin may be harmful. : Harmful or fatal if swallowed. : Per$on~ with heart or lung trouble should avoid use. : E~posure increases carbon monoxide l~vel of blood. : E~ce~sive e~posure to vapor may be fatal. EHERCENCY ~ : In ca~e of contact with skin, ~ash thoroughly with soap S water; FIRST AID : For eye~, immediately flush with plenty of water fo~ · FROCEDURES : 15 minute~ ~ CALL A PHYSICIAN. Remove $ wash ~ontaminated : ' clothing before reuse. (Discard contaminated shoes.) : After high vapor eaposure, r~move to fresh air. If breathing ts difficult : 9ire o~yg~n. If breathing has stopped give artificial respiration. : CALL A PHYSICIAN immediately} : If swallowed, CALL A PHYSICIAN IMHEDIATELYI ANTIDOTE - Induce vomittn~ promptly according to physician's instructions or by having patient stick finger down throat. ., Encourage patient to rinse out mouth with plenty of water. Give Ep~on ~alt ~olution in water. Giv~ milk or white of 2 or 3 ~9gs beaten in water. Never giv~ anythin~ by mouth to an unoonsotous p~rson. Have patient lie down $ ~ep warm. PHYSICIAn: Give o~ygen un~il recovery. Do no~ give p~tient ~ympathomimettc amines such as epinephrine, which may cause arrythmta~. V. REACTIVIT~ DATA STABILITY: Stable CONDITIONS TO AVOID: IsoJate from heat,'& open flame. llATERIALS TO AVOID ' Isolate from strong o~idizers such as permanganate. HAZARDOUS : Carbon Mono~itde, Carbon Dioxide, Hydrogen Chloride, Phosgene, DECO~[POSITION : Potassium O~ide ~ Hydro,ida from burning. ' PRODUCTS : VI. ~NVIRONMZNTA~ P~OTE[TION SPILL OR LEAK ' Small: Mop up with absorbent matezial ~ transf.~ to hood.. PROCEDURES : Large: l~olate from osidizers, heat, ~ open flame. : Unp~oteot,d persons ~hould be kept from area until el~an,d up. · Stop spill at souroe. Dike area to pr.wnt ~pr.a4. Pump liquid to ~alvag. tank. : Remainder may be tak,n up on absorbent material ~ shoveled into containers. WASTE DISPOSAL : Sm~ll: E~aporate until all vapors ars gone. ~ETHOD : Dispose of r~mainder by legally applicable methods. · Larg,: Reoyole or dispose of observing local,state ~ Federal health, : safety $ pollution laws. VII. E~PLOYEE PROTECTION RESPIRATORY PROTECTION - Ventilate to keep air below 20 ppm. If over TLV, use ~elf-contain~d air (~PECIFY TYPE) : pack approved by NIOSH/OSHA. Consult Safety Equipment Supplier. : Use e~plosion proof electric equipment. VENTILATION : LOCAL EXHAUST: Preferable MECHANICAL(GENERAL'} : Acceptable ' SPECIAL : None OTHER : None PROTECTIVE : ~ear OSHA Standard chemical goggles. Consult Safety Equipment Supplier. CLOTHING: Wear gloves & footwear impervious to this material. ~ash clothing befor~ reuse. 'VIII. SPECIAL PROTECTIONS When using, loosen bung slowly to relieve pressure. Do not store above 38'C/100"F. Store large amounts in structures made for OSHA Class II liquids. Avoid free fall of liquid. Grbund containers when pouring. Do not flame cut, braze or w~ld. Empty container hazardous! Continue all label precautions! Do 'not drink alcohol shortly before, during or after use. DATE : 11 / .°.5 CONTAINS: CHLORINATED SOLVENT, PETROLEUM DISTILLATE, POTASSIUM HYDROXIDE, CRESOL POISON~ CO~OSIV~ CO~BUBTIBLE VAPOR HARMFUL LIQUID CAUSES ~EVERE SKIN S EYE BURNS ~ASH THOROUGHLY AFTER HANDLINg, ASSORPTIO~ THRU SKIN MAY BE HARMFUL HARMFUL OR FATAL IF S~ALLO~ED PERSONS ~ITH HEART OR LUNG T~OUBLE SHOULD AVOID U~E EXPOSURE INCREASES CARBON MONOXIDE LEVEL OF BLOOD EXCESSIVE EXPOSURE TO VAPOR MAY BE FATAL I~alate from oxidi~er~, he~t, ~ open flame. U~e only with adequate ventilation. Avoid breathing of w. por or spray mist. Do not ge~ in eyes, on ~kin.or clothing. Do not take internall~. ~a~r OSHA St~nd~rd chemical goggles. Consult S~fe~y Equipment Supplia~. ~ear gloves ~ footwear impervious to thi~ materl~l. ~a$h clothing before Drinking ~Icohol ~hortly before, during o~ ~[ter use m~y c~u~e unwanted effects. Contact with hot ~urface$ may produce toxic Keep closure tigh~ ~ upright when not in use to prevent leakage. ~hen u~ing, loosen bung $1owly to relieve pressure. G~ound containers when pouring. Do not flame cut, braze or weld. DISPOSAL: R~cycle or dispose of observing local,state S Federal $~faty ~ pollution l~w$. If.spilled, ~op up ~ dispose of FIRST AID : In ca~e of contact with ~ktn~ ~a~h thoroughly with soap ~ For eyes, immedi~.~ely flush with plenty of w~er for 1~ minutes ~ CALL A PHYSICIAn. Remove ~ wash oont~min~ted clothing befor~ reuse. (Discard contaminated shoes.) After high v~por exposure, remove to fresh ~ir. If breathing i$ difftoult gn~e o~ygen. If bre~hing h~$ stopped give ~rtifici~l CALL A PHYSICIA~ immedl~[ely~ If ~allowed, CALL A PHYSICIAN I~MEDIATELY~ ANTIDOTE - Induce vomiting promp~l~ according [o in~truction$ or by h~ving p~ien~ stick finger down throat. Encourage patient ~o rinse ou~. mouth with plenty of water. Give Epson Salt solution in water. Give milk o~ white of 2 or 3 eggs beaten in water. ~ever give anythin'g by mouth to ~n uncon$ciou~ pe~son. H~ve patient lie down S keep w~rm. PHYSICIAN: C~ve o~ygen until recovery. Do not give ~ympathomtmetic ~mtne$ ~uch a~ ~pinephrine, which maF cause arry~hmias. Consuit ~S~S ic, r further information. FOR II.IDUSTRY USE ONLY KEEP OUT OF THE REACH OF CHILDRE~ BERRY~AN PRODUC'T~ 3809 E RANDALL I~ILL ARLII4CTON,TX 75011 DOT SHIPPING HANg: Combustible Liquid,NOS Legal responsibility i~ ~ss~ed only for the [~t that all studies reporte~ here $ all opinions ~re those of q,~lJfied e~perts. ~uyer assumes all risk 8 liability. He aocepts 8 uses this material on these conditions. · ATTENTI ON! ! THIS CONTAINER HAZARDOUS ~HEN EMPTIED. E,~PTY CO]~ITAINERS RETAIN RESIDUES OF PRODUCT (VAPOR, LIQUID OR SOLID), ALL HAZARD PRECAUTIONS MUST BE OBSERVED. HAZARD RATING HEALTH; 3 FLAI'IMABILITY: 2 REACTIVITY: MSDS NUMBER: 52 PRODUCT NAME: SODIUM BICHROMATE Attachment for 4A and 2A CHEM-DIPS I.. PRODUCT IDENTIFICATION 3 HEALTH HAZARD, 8 FIRE HAZARD, & I REACTIVITY rating based on NIOSH "identification System for Occupationally Hazardous Materta]s" (1974) MANUFACTURER'S NAME AND ADDRESS: Diamond Shamrock Chemicals Company, Soda Products, 35! Phelps Court, Irving, Texas 75815-2388 CHEMICAL NAME: Sodium Blchromate Dihydrate CAS NUMBER: 18588-81-9 SYNONYMS/COMMON NAMES: Sodium Dichromate CHEM!CAL FORMULA: NaECr207 2H20 DOT PROPER SHIPPING NAME: Sodium Dichromate DOT HAZARD CLASS: ORM-A DOT. ! .D. NUMBER: NA14?9 HAZARDOUS SUBSTANCE: RE)- 106)6) II. HAZARDOUS INGREDIENTS MATERIAL Or COMPONENT HAZARD DATA _ CAS NUMBER % Sodium Dichromate PEL=8. 1 mg/mj as CrC3 18588-81-9 1-5 Dlhydrate B hr. TWA_ TEV=8.85 mg/mj as Cr Water (SEE SECTION V) 95-100 NIOSH Exposure Limit = 0.825 mg/~3 as Cr VI 8 hr. TWA NIOSH Exposure Limit = 8 858mg/m~ as Cr VI Ceiling This material is listed on the TSCA inventory. III. PHYSICAL DATA BOILING POINT ~ 768 mm.Hg: 212°F VAPOR DENSITY {Air=l): N~A MELTING POINT: N/A %'VOLATILES BY VOL.:Same as water VAPOr PRESSUrE:Same as water EVAPORATION RATE (BuAc=!): BULK DENSITY: Loose packed-7.7.8 lb/cu ft Tapped -98.8 lb/cu ft SPECIFIC GRAVITY (H20=1) : 1 @ 25°C SOLUBILITY IN H20 % BY WT: 100 @ 28°C APPEARANCE AND ODOR: Orange red s01Qti0n no distinctive odor pH: 3.8 - 4.6 (Depending on concentration o¢ solution) TLV · TLV~, ACGIH fhrmlhotd L,m,I ViI~. Current PROI~UCT NAME: SODIUM~iCHROMATE (SOLUTION) Page 2 o¢ 5 ., 10/01/85 IV. FIRE' AND EXPLOSION 'DATA FLASH POINT: Not combustible ~UTOIGNITION TEMPERATURE: Not combustible FLAMMABLE LIMITS [N AIR. % BY VOLUME- UPPER: NA LOWER: NA ........ · . EXTINGUISHING MEDIA: Use water fog, dry chemical, or carbon dioxide in areas where this product is stored. This product is not combustlb]e. SPECIAL FIRE FIGHTING PROCEDURES: Pressure demand se]f-contained breathing apparatus should be provided for fire fighters in buildings or confined spaces where this product ts stored. UNUSUAL FIRE AND EXPLOSION HAZARD: Oxidizer. Avoid contact with organic materials (see Section VI) . V. 'HEALTH HAZARD INFORMATION HEALTH HAZARD DATA: Ora] LDs0 (rat) = 51. 10 · 5,93 mg/kg (both sexes) Derma] LD58 (rabbtt) = l.~O ± ~. 11 g/kg~ (both sexes) Acute Inhalation LChO (rat) = 124.42 ± 34 44 mg/m~ (both sexes) Corrosion to skin: Dry So]id Moistened Dry Moistened 4 hours .4 hours 24 hourB 24 hourB Erythema 2/6 6/6 Edema g/6 5/6 Necrosis 8/6 l/O Corrosion 1/1 1/1 NTP- Known to be.carcinogenic, 1981 IARC- Sufficient evtdence for carcinogentctty, 1982 There is laboratory evtdence that Aqueous 'Sodium Btchromate administered dtrect]y tnto the lung, at the ht~hest tolerated dose, over the ]lfettme oF rats, causes a significant Increased Incidence oF lung cancer. ROUTES OF EXPOSURE INHALATION: Inhalation oF dust or mists may cause Irritation of the nasa] septum and respiratory tract, Prolonged or repeated exposure may cause 'ulceration and perforation of the nasa] septum. SKIN CONTACT: Contact with broken skin may lead to formation of firmly mar'gtnated "chrome sores" SKIN ABSORPTION: Massive overexposure cou]d lead to kidney Fei lure and death. EYE CONTACT: Overexposure wi]] cause severe irritation and potential permanent damage to the eyes. Exposure to ]ow ]eve] concentrations may cause moderate Irritation or conjunctivitis. INGESTION: Can cause severe tissue destruction. Kidney failure may Fo]Iow and result in death. ' M~ Page 3 of 5 PROL~UCT NAME: SODXU XCHROMATE (SOLUTI0~]) l®/® 1/85 V. HEALTH .HAZARD INFO. RMATION ...continued EFFECTS OF OVEREXPOSURE ACUTE: Causes severe ~rritatton to eyes, and may cause blindness. May cause deep, penetrating ulcers on skin. May cause severe irritation of the respiratory tract and nasal septum and possible perforation. CHRONIC: · Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact, espectal]y with broken skin, may cause "chrome sores". Prolonged or repeated inhalation of Sodium Btchromate dust and mists may cause ulceration and perforation of the nasal septum. Eptdemiologtcal studies indicate that long term exposure to high levels of dust and mists in the Chromate producing industry is associated with increases in respiratory tract cancer in man, the causative agent is not known. Thus far eptdemiologlcal studies have not demonstrated any ~ncreased r~sk of lung cancer at levels below current TLV. EMERGENCY AND FIRST AID PROCEDURES EYES: Immediately flush eyes with plenty of water for at least 15 minutes holding eyeltds apart to ensure flushing of entire eye surface. Washing eyes within 1 minute is essential to achieve maximum effectiveness. Seek medical attention immediately. SKIN: Wash contaminated areas with plenty of soap and water for at least ~5 minutes. Remove contaminated clothing and footwear and wash clothing before reuse. Discard ~ootwear which cannot be decontaminated. Seek medical attention immediately. INHALATION: Get person out of contaminated area to fresh air. If breathing has stopped, artificial respiration should be started. Oxygen may be administered, if r~adtly available. If conscious irrigate nasal passages and mouth with water. Seek medical attention immediately. INGESTION: Never give anything by mouth to an unconscious person. Have conscious patient drink several glasses of water and then induce vom ttlng by having patient tickle back of throat with finger. Keep airway clear. Seek medical attention t m mediately. NOTES TO PHYSICIAN: Masstve overexposure to solutions of thls product could lead to kidney failure and death. Death has been av'otded . in several such cases through the use of early renal dialysis. It has been reported that ascorbtc actd administered intravenously ts an effective antidote In preventing renal failure, Skin ulcers may be treated by removal from exposures, daily cleansing and debrtdement, and application of antibiotic cream and dressing. VI. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY: Under normal use conditions, this product is stable. INCOMPATIBILITY: This.produCt is mildly oxidizing in solution, but becomes strongly oxidizing In strong acid solution. Avoid contact with organic materials, ot'ls, greases, and amy oxidizing materials. .... HAZARDOUS DECOMPOSITION PRODUCTS: None. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMER[ZATION: Material is not known to polymertze. S0O I UM ~m~ CHROMATE~! t SOLUT IOI]) Pagel (9 / E)4 ofl/855 PR0qUCT NAME: VIL ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Stop leaks. Remove as much as possible (e,g. vacuum truck). Then treat the spill area with a reducing agent .to convert the hexavalent chromium to the trtvalent form and neutralize with a weak base. Following neutralization, soak up with inert absorbent material (e.g. sand), place in a closed, labelled container and st'Ore in a safe place to await dlsposal . NEVER FLUSH TO SEWER. St'gnlftc'ant spllls should be reported to appropriate agencies. NEUTRALIZING CHEMICALS: Reduce hexavalent chromium with sodium btsu]fite, sodium sulfite, ferrqus sulfate or ferrous chloride. Neutralize . with sodium bicarbonate, soda ash, or lime. WASTE DISPOSAL METHOD: Hexa~alent chromium in solution, may be reduced to trtvalent chromium by reducing agents, such as sodtum blsulflte, sodium sulfite, sulfur dioxide, ferrous sulfate or ferrous chloride. The reduced chromium may then be precipitated as the chromic oxtde by .neutralizing to a pH 7.5 with soda ash, caustic soda, or lime. The solid material may be disposed of via an approved chemical waste landftl 1. Shipments should be manifested. Dispose of in accordance with all federal , state and local health pollution requirements. VIII. INDUSTRIAL HYGIENE CONTROL MEASURES VENTILATION REQUIREMENTS: Good industrial hygiene practice dtctates that the work area be isolated and contained and be provided with adequate local exhaust ventlla.tton where dust or fumes may be generated (see Sectton II for applicable control levels) . The number of persons exposed should be minimized. Certain processes like chrome pigment production, high temperature welding or cutting, etc., 'may form materials more hazardous to humans. These materials may be the formation of slightly soluble salts (barium, zinc, calcium or other chromates) or fumes of chromium/chrom!um., oxide, respectively which are known to be human carcinogens, Engineering controls and local exhaust ventilation is required to ensure that worker exposure is below current TLV, SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY: A NIOSH/MSHA approved respirator should be used following manufacturer's recommendation, where dust, mists, fumes or vapors are generated. EYE: Face shield and goggles or chemical goggles should be worn. GLOVES: Industrial grade rubber or plastic gloves shou'ld be worn. OTHER CLOTHING AND EQUIPMENT: Protective clothing should b~ worn when handling this product. Protective clothing should be changed at least ~ai'ly. Wash contaminated clothing with soap and water and dry before reuse. Advise the laundry of the material contaminating the clothing. Shower and eyewash facilities should be accessible. MONITORING EXPOSURE PERSONAL/AREA: Air samples may be collected and analyzed by NIOSH P&CAM. (method) NOS. Sll?, S352. PRODqCT NAME: SOOJL~M :HROMATE (SOLUTION) Pagelq)/(])50fl/855 IX. SPECIAL PRECAUTIONS SIGNAL WORDS: ..DANGERI POISONI POSSIBLE CANCER HAZARDI STATEMENT OF HAZARDS: MAY BE FATAL IF SWALLOWED. INHALED. OR ABSORBED THROUGH SKIN CAUSES BURNS TO SKIN AND EYES - MAY CAUSE EXTERNAL ULCERS PROLONGED OR REPEATED BREATHING MAY CAUSE ULCERATION OR, PERFORATION OF.NASAL MEMBRANES OVEREXPOSURE MAY CREATE CANCER RISK STRONG OXIDIZER PRECAUTIONARY STATEMENTS: .Do not' breathe dust or mists. Do not get in eyes, on skin, on clothing. Wear respirator, chemical goggles, rubber gloves, and Protective clothing when handling. Keep container closed. Use only with adequate engineering controls and ventilation where dust, mists, sprays may be generated (see Section II of MSDS #1,052 for control levels). Wash thoroughly after handling (take shower after work using plenty of soap; use fresh clothing dai'ly) . Store in tightly closed containers away from combustible materials. Container, when EMPTY, remains hazardous; dispose.in accordance with applicable laws and regulations. FIRST AID: IN CASE OF CONTACT: For eyes: Immediately flush eyes with plenty of Water for at least 15 minutes. Hold lids apart to ensure flushing of entire surface. SEEK MEDICAL ATTENTION. For skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and wash before reuse. Discard contaminated shoes. SEEK MEDICAL ATTENTION. IF INHALED: Move to fresh air. If conscious, irrigate nasal passages and mouth with water. If breathing has stopped, apply artificial respiration; administer oxygen if readtly available. SEEK MEDICAL ATTENTION. IF SWALLOWED: If conscious, give several glasses of water to drtnk and induce vomiting by having patient tickle back of throat with finger. Never give anything by mouth to an unconscious person. SEEK MEDICAL ATTENTION. NOTE TO PHYSICIAN: See Material Safety Data Sheet (MSDS) , Ml052, for more detailed information for first aid and safe handling. IN CASE OF SPILL OR LEAK: Follow precautionary statements. Shovel or soak up spilled material into a plastic or steel container and reuse or remove to · agent (e.g. sodium bisulfite) . then neutralize with soda ash or lime; remove to approved chemical , waste disposal area. Flush area with water, directing runoff to appropriate treatment or disposal container. NEVER .FLUSH TO SEWER. Major spills should be reported according to regulations. STORAGE AND DISPOSAL STORAGE Do not store in areas of high humidity. Do not store in close proximity to combustible materials. Store in. tightly closed containers away from sources of heat. FOR INDUSTRIAL USE ONLY APPROVED BY U S LABOR DEPT, ESSENTIALLY SIMILAR TO FO~MS OSHA20 BERRYMAN PRODUCT~ 3~00 'E RANDALL MILL ARLINGTON,TX 7601~ EI']ERCENCY PHONE: CHEMICAL FAMILY: Acid FORHULA: Mot Applicable I. PHYSICAL DATA BCiLIhlG RAN6E . 37 ~08 209'~ ~ 10Z 227 ~08'~ (*~End Point) AP! CRAVIiY : Not Applicable SPLC!FiC GRAVITY {%.;ater=I) : 1.~29 PO Cr~IDS,'CALLOM : 11.070 VAPOR PRESSURE ~mm ct H~)~:20~ : 105.? VAPOR DEI.iS. ITY (ail=l) : 5.2 SOLUBILITY II,l ~ATER : Complete SOLUBILITY IN ACID (~5~/~ H~SO~) : Complete DRY TIME (Ether=l) : Long % VOLATILE BY VOL : APPEA~AI.ICE : Ciear,~ater-~hite ODOR : Acid II. HAZARDOU~ H'A?EEIAL . CAS ~ VOL(~) ' TLV(ppm) l'lonoohl orc:t oluan~ 25168-05-2 ) 9 50 Diohio~omethans 75-09-~ ) ~ 100 Cr~}.lio A~id 1~19-77-3 ) 9 . ZyioI 1330-20-7 ) 9 100 LOad;EaT Kl'lO~Jl/'LC60 (VAFOhS) 1~30-20-7 5000 ppm DOT ~h!FFING NAH~: Co~z0sive Liquid,N05 HAZARD RATING HSALTH: 3 FLAMMABILITY: 3 P,~ACTI~ITY: III. FIRE ~ EXPLOSION HAZARD DATA LOg~ER FLAMMABLE LIMIT 1N AiR (% by vol): 1.0 (Lowest Component) FLASH POINT (TEST METHOD>. > ~9'C / } 105'F (TCC)(10~I E~ap) FLAM~IA~!LITY CLASSIFICATIOI{: Class ii EXV'iHGUIS. HII.IC I.IFPA Cla~ ~ e~tin~ut~hers (COl or foam) MEDIA : for olas~ ii liquid fires. SPECIAL FIRE ~.~er ~pray may be ineffective on fire but can proteot FIGHTING : fire tighte~'s & oooi olosefl oontatners. Use fog noszles If PROCEDURES : ~,'ater,is u~ed. Use air-supplied breathing ma~ks. UI'IUaUAL : COMSUSTI~LE~Reaots with many metals to produce hydrogen EXPLOSION. : which i~ e:~tremely flammable $ may esplode. AND FIRE PROCEDURES L~al r~sponsibi]itF i~ a~sum~d o~lF for the fact that ali studi,s r~porte4 h~rm $ all opinions a~ those.of qualified exp~t~. ~uyer ~s~umes all risk $ liability. He accepts ~ u~m~ this material, on the~e ~on~tto~s. He mu~t hav~ a c:o~ of this MSDS where mattrial is handl~d. IV. I-{EALTH HAZARD DATA THRESHOLD LIMIT VALUE: 25 ppm (Freshly Prepared) EFFECT.~. OF INHALING: Severe respiratory tract irritation may occur. .. ACUTE r p damage to kidneys,blood,r~erves,]iver & lungS, OVER- Absorption thru skin increases e~po~ure. EXPOSURE SKIN CONTACT: ~ev~re burns, dafattlng, dermatitis. EYE CONTACT: Severe burns, rednos~ tearing, blurred vision. EFFECTS OF ~:~ POISONH SWALLOW- ~ CALL A FHYSICIAN IHS AND CORROSIVE CHRONIC Vapor harmful. Heating forms hazardous vapor. OVER- Liquid cause~ severe skin ~ e~e burns . EXPOSURE ~ash ~horoughly after handling. Absorption thru ~kin may be harmful. Harmful or fatal if ~wallowsd. Per~on~ with heart or lung ~roublm ~houId avoid E;:po~ure increase~ carbon mono~id~ level of blood. Enoes~ive e~posure to vapor may be fatal. EI'IERGENCY & In case of contact with skin, Wash thoroughly with soap & Water; FIRST AID For eyes, immediately flush with plenty of watsr for PROCEDURES 15 minutes & CALL A PHYSICIAN. Remove & wash contaminated ' olothing 5efo:'e ~eu~e. (Discard contaminated ~hoe~.) After high vapor e~posurs, remove to fresh air. If breathing is difficult give o~ygen. If breathing has stopped give artiliotal respiration. If swallowed, CALL A PHYSICIAN IHHEDIATELYt ANTIDOTE - Induce vomiting promptly according to physiolan's inztruc%ion~ or by having patient stick fin~er down throat. Encourag~ p~[ient to rinse out mouth wi~h plenty of water. Give Epson Salt solution in water. Give milk or white of 2 or 3 eggs beaten in water. H~ver giv~ anything by mouth ~o an onoonsoious per,on. Have patient lie down ~ keep warm. :, PHY~ICIAH. Give o~ygen until recovery. Do not ~ive patient ~ympathomimetic ~mmes such as epinephrine, which may cause arrythmias. V. REACTIVITY DATA STABILITY: Stable but Reacts with many metals to produce hydrogen : which ~$ extremely flammable & may explode.' CCI'iDITIC...I.II~ TO AVOID: Isolate frcm heat, ~ open flame. I-lATER!ALS TO AVOID : Isolate from Alkalis HAZARDOU'~ : Carbon Monoxide, Carbon Dioxide, Hydrogen Chloride, Phosgene DECOI.!POSIT1 git : from burning. PRODUCTS VI. ENVIRONMENTAL PROTECTION ~PILL OR LEAK ; N~ut;alize & dilut~ with water. PROCEDURES : If laws permit, dilut~ ~ flush to sewer : Stop spill at source. Dike area to prevent spread. Pump liquid to salvage tank. : Remainder mai be taken up on absorbent material & shoveled Into containers. ~A~TE DISPOSAL : Small: Dispose of b~ legallF applicable methods. PIETHOD : Large: ~ec~cle or Neutralize & dilute with water. ; If lawz permit, dilute $ flush to sewer observing local,state ~ Federal health, : se. fety & pollution laws. VII. E~PLOYEE· PROTECTION RESPIRATORY PROTEC~TIOI,I : Acid vapor, mis[ gas mask approved by NIOSH/OSHA. (SPECIFY TYPE) Consult Safety Equipment Supplier. : U~e e~ploston proof ~leotric ~quipment. VENTILATION : LOCAL E>~HAUST : Necessary MECHANICAL(GENERAL) : Necessary : SPECIAL : None OTHER : None PRQTECi'I¥'E : ~ea~ CSHA Standard chemical google~. Consult Safety Equipment Supplier. .,.'> CLOTHING: Wear gloves & footwea~ imperviou~ to thi~ material. Wash clothing before reuse. VIII. SPECIAL PROTECTIONS lJhen using, loo~en bung slowly to relieve p~essure. Do not sto~e above 39'C~100'T. Store large amounts in structures made for OSHA Class Ii ,liquids. Avoid free fall of liquid. Ground containers when pouring. Do not flame cut, braze or weld. Empt~ container ha~ardous~ Continue all label preoautions~ Do not drink alcohol shortly before, during or after DATE: 1~ / 85 CHEM--DIP COl.ITAI?.lS: CHLORINATED SOLVENT, CRESOL, XYLENE;ETHYLBENZENE DAI~IGER! . ~J, POISON!! ~ :,: CALL A PHYSICIAN X .... "CORROSIVE WASH THOROUGHLY AFTER HANDLING A~ORPTION THRU SKIN ~A~ BE HA~UL HARMFUL OR FATAL IF SWALLO~D PERSONS WITH HEART OR LUNG TROUBLE SHOULD AVOID USE EXPOSURE I~4CREASES CAHBO~ MONOXIDE LEVEL OF BLOOD EXCESSIVE EXPOSURE TO VAPOR HAY BE FATAL l~olate from o:,:ldizers, heat, & open flame. U~e only %~ith adequate ventilation. AvcJd breathing of v~por or ~pray mist. Do ~;:k get in eyes, on 5kin or clothing. Do not take internally. %]eaz OSHA Stand~rd chemic:al goggles Con~ult Safe~y Equipment Supplier. %'ear gloves S f0ot~.ve~ impervious to this material. Wash clothing before reuse. Drinking alcohol ~hortly before, during or after u~e may cause unwanted effeot_~. Contact with hot ~urfaces may produce to]{io ga~es. Y. eep olo~ure {ight & upright when not i~ u~e to prevent leakage. When u~ing, loosen bung ~lo%~!y to relteue pressure. Ground containers when pouring. Do not flame out, braze or weld. DISPOSAL. 5ecyole or dispose of observing looal,~tate & Federal health, safety & pollution la~..¢s. If ~pilled, wet down with water ~ remove immediately. ~ear goggle~ or face shield, gloves' S protective clothing when opening or handling. ~Jhen empty drain completely, replace bung~ securely. FIRST A~D : In ca~e of contact with skin, ~amh thoroughly with ~oap & water; For eye~, immediately flush ~.;ith plenty of water for 15 minute~ $ CALL A PMYSICIAH. Remove & wash contaminated clothing before reuse. (Discard contaminated shoes.) After high vapor e~posure, remove to fresh air, If breathing is difficult give o~ygen. If breathing has stopped give artificial respiration. If m~vallowed, CALL A P~SICIAN IMP~ED!ATELY~ AHTIDOTE - induce vomiting promptly according to phy~ioian'~ in~ruotion~ or by having patient stick finger down thromt. Encouraige patient to rinse out' mouth with plenty of water. Give Epson S~lt soJuzion in watmr. Give milk cr white c:f 2 or 3 e~9~ beaten in water. Nmvmr ~ive anythin~ by mouth to an uncon~oicm~ person. Have patiant lie down g ke~p w~rm. FHYS!CIAN; Give o~y~em ~ntil reoovery. Do not ~ive patient ~ympathom~metic .~mines ~uoh ~ epinephrine, which may oause arrythmia~ Con~u~, M~DS ~or fu~thez reformation. FOR IHDUSTRY USE O~'[LY KE~P OUT OF THE REACH OF CHILDREN BEFiRYMAb~ PRODUCTS 3~[]9 E RANDALL MILL ARLII.IG?OI.I,TX ~011 DOT SHIPPING NAME: Corrosive Liquid,NOS. (UN17~0) ,~ Legal responsibility i~ a~sumed only for the f~ct that all ~tudies reported here ~ all opinions are tho~e of qualified e>:peris. Buyer a~$umes ~11 risk $ liability. ~ He acc~ep~s & uses this material on the~e conditions. I/ ..v:, .:.:::: AI''FEI'q7~ ION .~ ! THiS CONTA[i.IER HAZARDOUS %;HEN EHPTIED. EI.~FTY COI',ITAII,IERS RETAIN RESIDUES OF PRODUCT (VAFO,q, L!OUID OR SOLID), ALL HAZARD PRECAUTIOHS blUS, T BE OBSERVED. HAZARD RATII,IG HEALTH. 3 FLAI.!i-i ABILITY: 3 REACTIVITY: IVIATERIAL SAFETY DATA ~;~ ~ ~ ' .... r MSDS NUMBER b . 60, ]J0-B "~.~GE,"~. ~' .. '. ' ~7.O~ ~c'-85~ = r : ' ' '~l ~/'~r~'~~'~'' 24 HOUR :EMERGENCY .ASSISTANCE ,' ' ~[~== G~NERAL~[~s~ MSDS. :ASSISTANCE. ~oa[.~,~ : ~' "~" ,,;.. SHELL: 713-473-9461 CHEMTREC: 800-424-9300 SHELL: 713-241-4819 ~ 1 ~ 1 0 HAZARD RATING -- PASS IT ~ .; ' ~'~ ¢' *Fo~ acute and chromc health effects refer to the d~scuss~on m Sechon IH xN ~' ~ SECTION I : -: :NAME · · * ::' :': '¢:. " SHELL ROTELLA(.R) ~ OIL 30 F CHEMICAL M~XTURE (SEE SECTION I]-A~ ~; CHEMICAL ~ PETROLEU~ HYDROCARBON; HEAVY DUTY MOTOR OIL ~ ' FAMILY ~' SHELL'~ 54103 CODE ................................................................................................. ¢'~ SECTION [ I-A PRODUCT/INGREDIENT ............................ - . ................................................ ;~?. '...;? N0. CO~POS[TION. ' CAS NU~EE PERCENT ....................... ~ ..... . ..... ..................................................... , .......... P SHELL EDTELLA T D~L 3G ' MIXTURE 1OO ' 1. SOLVENT REFINED, ~YDROTREATED HEAVY PARAFFINIC DISTILLATE 64742-54-7 20-85 ' '' 2 S0~VENT REFINED, HYDROTREA~ED RESIDUAL 0IL 64742-57-0 20-85 %-~.:.,~7~'~;.~,~ ~ 3 ADDITIVE PKG. CONTAINING CALCIU~ PHENATE AND ZDDP MIXTURE* <15 ~' 4 ~INOR ADDITIVES ~]XTURE · <1 ' :' "' ':~ , ,. . · T~E SPECI:FI6 CHEMICAL IDENTITY OR PERCENT IN COMPOS~TION OF COMPONENT 3 IS CONSIDERED TRADE SEOR~T,:v ,:*~ INFORMATION. ' ',' , ................................................................................................. =_~ .,: ':~'r~ S[CT~N ~--B ACUTE TOXICITY DATA :,' .... 'r. T-- T -- -- '~ r '~ -- --'F -- ~ --'r -- r r.-- -- ~ -- -- = .................................................................. = ' ~' NO. ' ACDTE" oRAL~''rLDso' '"'"' ' ' "''''': ACUTE DERHAL LDSO ACUTE INMALATION LC50 ' "'~':L' ' ' -- ......... % ...................................................................... ~ NOT AVAILABLE BASED UPON DATA AVAILABLE TO SHELL, COMPONENT 4 IN TH~S pRODUCT 'IS NOT HAZARDOUS UNDER OSH~ COMMUNICATION (29 CFR 1910 1200) '' ~'~ · . ., . .. . ....................................... ~. ~'~: '~.~ SE~ZON ~~ HEALTH INFORMATION ......................................................... .................... , ........... THE HEALTH .-" STANDARD (29 CFR 1910.1200). EYE CONTACT LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN U[N[MALLY IRRITATING TO THE EYES, ',~ . ..': ~ SKIN CONTACT- '~f' LUBRICATING O[LS ARE GENERALLY CONSIDERED NO MORE THAN MILDLY IRRITATING TO THE SKIN, PROLONGED'* AND REPEATED CONTACT MAY RESULT IN VARIOUS SK[N D[SORDERS SUCH AS DERMATiTiS, FOLL[CUL[T~S OR O[C " · * ACNE, INHALATZON ' '~ :' ,~'~' ]NHALAT[ON OF VAPOR (GENERATED AT HIGH TEMPERATURES ONLY) OR OIL MIST FROM TH[:S PRODUCT M~Y R~SU~T"'".-', ~ ~N M[LD ZRR~TAT[ON O¢ THE UPPER RESPIRATORY TRACT. ' PRODUCT NAME SHELL .ROTELLA(R);,T 0Z=L- 30. · .... :% .... "..,~ ' Jl , :*'~'~ =':. · ..:~ MSDS 130-3 INGESTION LUBRICATING OILS ARE GENERALLY CONSIDERED NO MORE THAN SLIGHTLy TOX~.C IF SWALLOWED. 'SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE.' AgGRAVATEO MEOIrCAL CONDITIONS PRE. EXISTING SKIN AND RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT i! .OTHER HEALTH EFFECTS i'- THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCE~ HAS DETERMINED THERE IS SUFFICIENT EVIDENCE FOR THE i', CARCINOGENICITY IN EXPERIMENTAL ANIMALS OF USED MOTOR OILS. HANDLING PROCEDURES AND-SAFETY. ~. PRECAUtiONS IN THE ~SDS SHOULD BE FOLLOWED TO MINIMIZE EMPLOYEE'S EXPOSURE TO THE USED,PRODUCT. i~. sEE SECT]ON V} FOR ADDiTiONAL HEALTH ~NFORMAT[ON. ... * ,' ,,: ................................ ' ..................................................... ~.'. SECTION ZV OCCUPATIONAL EXPOSURE _ ......... ....... ....... ,::-_ .................................................................. ~ . OSH~ '~ ACGZH OTHER ?, ~. PEL/T~A ~, PEL/CEZLZNG TLV/TNA TLV/STEL ;,.. ; ......... . ......... -~ ............................................................................... ~:~. P 5 MG/M3 NONE z. 5 MG/M3, 10 MG/M3" NONE *O[L MIST, ~MZNERAL FLUSH ~ITH ~ATED FOR 15 MZNUTE~ ~H[LE HOLD[NG EYELIDS OPEN. GET MEDICAL ATTENd[ON. ' SKZNREMovECONTA~coNTAMiNATED OFF. CLOTHING AND WIPE EXCESS WASH WITH SOAP AND WATER CLEANER FOLLOWED BY SOAP AND WATER. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT GET MEDICAL ATTENTION. DO NOT INDUCE VOMITING. IN GENERAL NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES OF PRODUCT ARE INGESTED, HOWEVER, GET MEDICAL ATTENTION. ....~TE TO P~SZCZ~ ZN G~NE~L, E~ESZS ZNDUCTZON ZS UNNECESS~'~V ZN HZGH WSCOSZTV, LO~ VOL~T[LZ~V P~ODUC~S, Z.E., " OILS AND GREASES. SECTION VI SUPPLEMENTAL HEALTH INFORMATION .................................................................................................... SUPPLIER O~ COMPONENT ~ REPORTS THAT CERTAIN CALCIUM PHENATES AND ZINC DITHIOPHOSPHATES (ZDDP), ".. .~HEN APPLIED TO THE SKiN OF MALE RABBITS OVER A PERIOD OF TIME, ADVERSELY AFFECTED SPERMATOGENZC ACT[V[TY~" SECTION VII PHYSICAL DATA BOILING POINT: NOT AVAILABLE SPECIFIC GRAVITY: 0.8956 VAPOR PRESSURE: NOT AVAILABLE ' (DEG F) (H20=1) (MM HG) ~[~,'~ i ]i'' MELTING POINT: -5 (POUR POINT) SOLUBILITY IN: NEGLIGIBLE VAPOR DENSITY: NOT AV uC;}~ EVAPORATION RATE (N-BUTYL ACETATE = 1) NOT AVAILABLE VIS. CS (40 PEG C) " APPEARANCE AND ODOR: DARK RED LIQUID, SLIGHT HYDROCARBON ODOR. FLASH POINT AND NETHOD: FLAMNABLE LINIT5 /% VOLU~E 'IN AIR 990 DEG F (P~CC) LOWER: N/AV H~GHER: N/AV EXTINGUISHIN~ NEDIA USE WATER FOG, FOA~, DRY CHEMICAL OR COZ. D~ NOT USE A 5IRECT STREAM DF WATER. PRODUCT WILL AND C~N GE REIGNITED ON SURFACE OF WATER SPECIAL FIRE FIGHTING PROCEDURE~ AND PRECAUTIONS MATERIAL WILL NOT BURN UNLESS PREHEATED, DO NOT ENTER CONFINED FIRE-SPACE WITHOUT FULL BUNKER (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE-PRESSURE · ~' NIOSH=APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. STAEtLIIY: STA~LE HAZARDOUS POLYMERIZATION: W]LL NOT OCCUR ": CONDITIONS AND NATERIAL~ TO AVOID: AVOID HEAT, OPEN FLA~ES AND OXIDIZING ~ATERIALS. ' ' ' H~ARDOUS DECO~POSITION PRODUCTS , x, THERMAL DECOMPOSITION PRODUCTS ARE HIGHLY DEPENDENT ON THE COMBUSTION CONDITIONS A COMPLEX · ,~':' " MIXTURE, OF AIRBORNE SOLID, LIQUID, PARTICULATES AND GASES WILL EVOLVE WHEN THIS MATERIAL UNDE - PYROLYSIS OR COMBUSTION. CARBON MONOXIDE AND OTHER UNIDENTIFIED ORGANIC COMPouNDs MAY BE UPON COMBUSTION .... SECTZON X E~PLO~EE PROTECTION RESPIRATORY PROTECTION IF EXPOSURE ~AY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SECTION IV) USE A NIOSH-APPROVED ' RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910. 134 USE EITHER AN_ . ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS AND PARTICULA " PROTECTIVE CLO~HIN6 WEAR CHEMICAL RESISTANT GLOVES AND OTHER PROTECTIVE CLOTHING AS REQUIRED TO NINI~IZE SKIN CONTACT. :. WEAR SAFETY GOGGLES TO AVOID EYE CONTACT. TEST DATA FROM PUBLISHED LITERATURE AND/OR GLOVE ~ND CLOTHING ~ANUFACTURERS INDICATE THE BEST PROTECTION IS PROVIDED BY NITRILE GLOVES. ..:;]:.. SE~ZON XI ENVZRONHE~AL PROTECTION SPILL OR LEAK PROCEDURES ~AY BURN ALTHOUGH NOT READILY [GN[TABLE. USE CAUTIOUS dUDG~ENT ~HEN CLEANING UP LARGE SPILLS. LARGE SPILLS IF S~FE TO DO SO. DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE SALVAGE VESSELS SOAK UP RES[DUE ~[TH AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATER[ALS; D[SPOSE OF PROPERLY. FLUSH AREA WITH WATER TO REMOVE T~ACE RES[DUE. *** ~MALL SP['LL5 *** TAKE UP WI'TH AN ABSORBENT MATERIAL AND D[SPOS'E OF PROPERLY. PLACE [N AN APPROPRIATE DISPOSAL FACILITy [N COMPLIANCE WITH LOCAL REGULATIONS. '~:/P DU NA#E 'SHELL ROT£LLA(R)T OIL 30 #SDS ~.60,130-3 ~ £NV] RONI~ENTAL HAZARDS L' ' ::.. THIS PRODUCT IS CLASSIFIED AS AN OI UNDER SECTION 311 OF THE CLEAN WATER ACT SPILL:S~ENTERING (~A) SURFACE ~ATERS O~ (B) ANY ~ATE~ COURSES OR SE~ERS ENTERING/LEADING TO SURFACE ~ATERS. THA~ CAUSE A ?~.~:..SHEEN MUS~ BE. REPORTED TO THE NATIONAL RESPONSE CENTEP, 800-424-8602. '. :'. ~* MI'NI~IZE SKIN'CON~ACT. ~ASH ~ITH SDAP AND ~ATER BEFORE EATING. DRINKING,/SMOKING~O~ USING ~OILE~ ~ACILIT'IES'. LAUNDER CONTAMINATED CLOTHING, BEFORE, REUSE, ' PROPERLY~DISPOSE OF CONTAMINATED"L[ATHE~' A~Y]CLE5 INCLUDING SHOES., THAT CANNO~ BE D[CONTAM~N&TED. ~':' STORE IN A COOL DRY PLACE WITH ADEQUATE,-vENTILAT]ON. KEEP AWAY 'FROM OPEN FLAMES AND HIGH . J':, DEPARTMENT OF T~ANSPDRTATI~N CLABS~F]CATION: N~T HAZARDOUS BY D.O T. REGULATION~ :":'SE~ON XIV ' OTHER RE~LATDRY'CO~ROLS ¥:'.~HE. COMPONENT5 OF TH~5 PRODUCT A~, L~STED ON THE EPA/TSCA ;NVENTORY OF CHEmiCAL ~UBS~ANCES... ~- ..... ":: ;THE '~NFDR~ATZON CONTAZNED.:'HEREZN 3S BASED ON THE DATA AVAILABLE TO US AND ZS'BEL~;'EVED' ~0 BE CORRECT .'? .HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPL~ED',REGARDZNG THE ACCURACY .OF THESE"DATA OR THE '.' RESULTS. TO B.E OBTAINED FROM THE USE THEREOF.r SHELL' ASSUMES'NO RESPONSIBILITY FOR"INdORY"FROM THE ;" "~' USE OF THE PRODUCT DESCRIBED HERE[N, ' " RE~ OUR PRODUCT : sHELL OIL ~MP~Y . 'SAFETY ZNFORHATZON ...AND PASS ZT 0N PR0~CT SAFETY ~D COmPLInE (PR0~CT LIABILITY LA~ P~ 0. BOX 4320 ..... · .... ,:...:~:~,, MATERIAL SAFETY DATA SHEET Shell ' ' ;~.~J .... ':~-MSDS NUMBER ~ ~7367 ,.~5)7,~7 3____0-_ PAGE = RE~ OUR PRODUCT ACUTE HEARTH . ' FIR~ r ~ . REACTIVITY , ~ '.~ ~ · t SAFETY INFORMATION ~ ..'' ~'' ~ =,H ~LEAST- 0. SLIGHT ; 1 MODERATE ; 2 ...AND :: 2 ";' ~' "' 0 '~'~/: HAZARD RATING ' . '' PASS~tOa . . : t. HIGH - ~ EXTREME .. 4 ~For acute~and chronic health effects refer to the discussion in Section III ~ MINERAL ~PIRITS t45-EC . PRODUCT . , . ., ,. , ;, ,~. CHEMICAL k NOT APPL [CABLE NAME ....~ ' ~ ..... CHEMICAL FAMILY ~ HYDROCARB'ON SOLVENT SHELL ~ ~; , , CODE~ 83063 ~ ;~ ~''' ¥ ,r :'~' '~ t' '~' ' -. '=l ( .~. . ~ . [ :. SECTION I]-A PRODUCT/INGREDIENT ~t~ ' :' "' .................... [~ ...... ~ ............................... ; ......................................... NO. ' COMPOSITION ~ CAS ~MBER PERCENT . . p M]NERAL SPIRITS 145~EC '; ~' ~ ......... ";~':""": ...... MIXTURE* t00 t SOLVENT N~PHTHA (PETROLEUM), MEDIUM AL~PHATZC 64742-88-7 >90 ' 2 SOLVENT NAP~HA (PETROLEUM)~ L~GHT .AROMATIC ~ ~ 64742-95-6 <t0' : = '.":''r r ........... TYPICAL D[STR]BUT[ON ..................................... : PARAFFINS ' ' '. NOT APPL. S2.g '~ ., NAPHTHENES~":: '~']". ":~-,.~, .:,' ~?t . ~:~'~[ ~*~t:'" '~:"*~" = ' :' NOT APPL~ 38.g TOTAL AROUAT~CS~''~ ,~t?~ :.;t~=~r: ~'. '~;~]'~ ~-~ ~Li ..... ~ r~ ~"~ ~'~ ~ NOT APPL. 8.2 (TR~ETHYLBENZENE ' 2.3-2.7) ....... : 25~51-13-7 · . . 255~0- t4-5 -- (ETHYLTOLUENE~ 0.9-1.1) ; ~[~ .~ ~ , : OLEFZNS~ '': '''~ '''~'~ t ' ~ ~,;~'.~ .'~ ~ ': :' ' NOT APPL. <0.1 · A COMPLEX COMBINAT]ON OF PREDOMINATELY C8-Ct2 HYDROCARBONS; EXACT COMPOSITION WILL VARY. ......................... ; .......... *----;~_;__~ .... ; ...... ~ .......... ~ .............................. SECTION ]Z-B ACUTE TOXICITY DATA NO. ACUTE ORAL LDB( A~TE DERMAL LD50 ACUTE I~ALATION LCSO P ' NOT AVAILABLE ~" :'. ~¢~)~th ~;d~:j~ ..... ~?,'?'," ........ ~.,.'.'~ : , ,~ , 1~ >25 ML/KG (RA~') ' >4 ML/KG (RABBIT)' "~"'' '' >?00 PPM/4H (RAT) ... ...... ',,,' '/~. >4 ML/KG (RAT} ~ >3670 PPM/SH (RAT) 2' 4.7 G/KG (RAT~: · BASED UPON'.TEST[NG OR EZTHER PRODUCT,OR~ES'SENTZALLY S~MZLAR PRODUCTS. ". "' ~ .......... ~-";~-:' .~ ;,.'~.:,~?~:~'~"~ ,,~; ~ ~,-? ~,'~,' '~:;~*~'~.'~'~:i.'~:: ':" ~¥~'~;~'~ ~: '" '~",~' ¥~ ~ ~'::: "~, ' · ~:', '. '. "" ' */' ,' : SECTION ']]~ ?[~'?~?'~:':~:[ "~:'~:~'/,f~["~*?::~:'":~':;~ HEALTH '*]NFORMAT~oN~:~:~.~;~'''? ?,* '~ ,.r~;~.?~: ', ~[~ ,~* .. .~. :- ,.' ~*- .. ....... . · . · '~:, ~, ' . ~ ".'.:.~: THE HEALTH..'EFFECYS 7, NOTED .BEEOW: A~E-CONS] STENT/~ W]TH .:REQUIREMENTs.UNDER .~ THE OSHA 'HAZARD CO~MUN[CATZON . . ' ":'. , EYE CONTACT ' '.,'- H ' .' - .' ' . :" " " . ~.~ .,.'~ LIQUID ZS MINIMALLY ~EEZTAT]NG TO THE EYES.'"'HZGH'VAPO~ CONCENTRATIONS ~AY CAUSE IRRiTATiON' ..... ;,-':,," LZQUZD"]S' SLZG~TE~U.~RZTATZNG'TO',THE SKZN:,:?'PROEONGED":OE''REPEATED 'LZQUZD CONTACT'S'CAN RESULT. [N ' ' "..' ." .'.'; ':? DEFATTZNG;~AND' DRYING OF:~THE:SKJN WHICH MAY. RESULT?::JN SKJN..JRR[.TATJON' AND' DERMATiTiS,:.. '" '- ,. ,.~ ....... ., .. ,.. : ,.. ... ,...~:..::..,~.,.: ,. .. '. ' ?;,?.- ,. , ~.....: :. -;... · . . , . .:, .:.....~.., ~., . , · . .., ...-..., , · .... . .. ... ~ .. .. .~ .;~.{.~%~...~.. .. ,, ,; . . , . .f;. ~ -, .... . . .,, .. ..... .~ . ., -.: ...... .., ...: =.,~,..: ~..:.~;..~/~..~,~.~.%;~.:)~,,..¢~;~',~.~l;.::,:':~':,,?~u:,', :.. · ~:,,.., ,.. ~-.;, ~, :-;:..~,~.~.~'..:'.'~,'.~.;,;,.,, ,..,.:.: =. :..... '::...'..., . . .-:. -..:.: .... . .'.. '._., .,."..,-.,.,.~ ....... . ...... , .... ,.. ..... =,, .................................... ..... PRODUCT NAME: MINERAL SPIRITS 145-EC MSDS 7,570--~ PAGE 2 INHALATION VAPORS MAY BE IRRITATING TO NOSE, THROAT AND RESPIRATORY TRACT. HIGH VAPOR CONCENTRATIONS MAY CAUSE CNS DEPRESSION. ,i INGESTION INGESTION OF PRODUCT MAY RESULT IN VOMITING; ASPIRATION (BREATHING) OF VOMITUS INTO THE LUNGS MUST BE AVOIDED AS EVEN SMALL QUANTITIES MAY RESULT IN ASPIRATION PNEUMONITIS. SIGNS AND SYMPTOMS IRRITATION AS NOTED ABOVE~ EARLY TO MODERATE CNS (CENTRAL NERVOUS SYSTEM) DEPRESSION MAY BE EVIDENCED BY GIDDINESS, HEADACHE, DIZZINESS AND NAUSEA; IN EXTREME CASES, UNCONCIOUSNESS AND DEATH MAY OCCUR. ASPIRATION PNEUMONITIS MAY BE EVIDENCED BY COUGHING, LABORED BREATHING AND CYANOSIS (BLUISH SKIN); IN SEVERE CASES DEATH MAY OCCUR. AGGRAVATED MEDICAL CONDITIONS PREEXISTING EYE, SKIN AND'RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SEE SECTION VI FOR SUPPLEMENTAL INFORMATION. SECTION IV OCCUPATIONAL EXPOSURE LIMITS OSHA 'I ACGIH OTHER NO. PEL/TWA :PEL/CEILING TLV/TWA TLV/STEL P* 500 PPM i! 100 PPM 200 *RECOMMEND THAT LIMITS FOR: STODDARD SOLVENT BE USED AS A GUIDE. SECTION V :I EMERGENCY AND FIRST AID PROCEDURES EYE CONTACT FLUSH EYES WITH PLENTY OF iWATER_ FOR t5 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN CONTACT REMOVE CONTAMINATED CLOTHiNG/SHOES. FLUSH SKIN WITH WATER. FOLLOW BY WASHING.WITH SOAP AND WATER. IF IRRITATION OCCURS, GETi MEDICAL ATTENTION. DO NOT REUSE CLOTHING UNTIL CLEANED. INHALATION REMOVE VICTIM TO FRESH AIR AND PROVIDE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION DO NOT INDUCE VOMITING. i:F VOMITING OCCURS SPONTANEOUSLY, KEEP HEAD BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO iTHE LUNGS. GET MEDICAL ATTENTION.* NOTE TO PHYSICIAN *IF MORE THAN 2.0 ML PER KG HAS BEEN INGESTED AND VOMITING HAS NOT OCCURRED, EMESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP VICTIM'S HEAD BELOW HIPS TO PREVENT ASP[RAT[ON. IF SYMPTOMS SUCH AS LOSS OF GAG REFLEX, CONVULSIONS OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS, GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE CONSIDERED. SECTION VI ! SUPPLEMENTAL HEALTH INFORMATION MALE RATS EXPOSED FOR 90 DAYS BY INHALATION TO VAPORS OF SOLVENTS SIMILAR TO COMPONENT 1 SHOWED EVIDENCE OF KIDNEY DAMAGE.iI THE RELEVANCE OF THIS EFFECT TO MAN IS UNKNOWN. IN ONE OF THE STUDIES A LOW GRADE ANEMIA WAS ALSO OBSERVED. RATS EXPOSED FOR 4 MONTHS TO 1700 PPM OF A SOLVENT SIMILAR TO COMPONENT 2. SHOWED EVIDENCE O~ MILD DAMAGE TO THE L~'VER~ [UNGSiAND KIDNEYS.' THESE EFFECTS WERE NOT SEEN IN RATS EXPOSED FOR 1 YEAR TO 350 PPM OF ANOTHER'SIMILAR,[SOLVENT. -., PRODUCT NAME: MINERAL SPIRITS 145-EC MSDS 7,570-3 ~ PAGE 3 SECTION VII :' PHYSICAL DATA BOILING POINT: 317-388 SPECIFIC GRAVITY: 0.78 VAPOR PRESSURE: <5* @ (DEG F) ! (H20=~) (MM HG) 100 DEG. F MELTING POINT: NOT A~AILABLE SOLUBILITY: NEGLIGIBLE VAPOR DENSITY: 4.8* (DEG F) ,I (IN WATER) (AIR=I) EVAPORATION RATE (N-~UTYL ACETATE = 1): <0.1' * ESTIMATED APPEARANCE AND ODOR: ILIGHT COLORED LIQUID. HYDROCARBON ODOR. SECTION VIII :i FIRE AND EXPLOSION HAZARDS FLASH POINT AND METHOD: FLAMMABLE LIMITS /% VOLUME IN AIR i12 DEG. F (TCC) .i, LOWER: 1 UPPER: EXTINGUISHING MEDIA USE WATER FOG, FOAM, bRY CHEMICAL OR C02. DO NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE REIGNITED.ON SUFACE OF WATER. :l SPECIAL FIRE FIGHTING PROCEDURES AND PRECAUTIONS CAUTION. COMBUSTIBLEi. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET WITH FACE SHIELD, BUNKER COATS, GLOVES AND RUBBER BOOTS), INCLUDING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS, COOL FIRE EXPOSED CONTAINERS WITH WATER, UNUSUAL FIRE AND EXPLOSION HAZARDS ' CONTAINERS EXPOSED TO INTENSE HEAT FROM FIRES SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE BUILDUP WHICH COULD RESULT IN CONTAINER RUPTURE. CONTAINER AREAS EXPOSED TO DIRECT FLAME CONTACT SHOULD BE COOLED WITH LARGE QUANTITIES OF WATER AS NEEDED TO PREVENT WEAKENING OF CONTAINER STRUCTURE. SECTION IX 'i REACTIVITY STABILITY: STABLE '/. HAZARDOUS POLYMERIZATION: WILL NOT OCCUE CONDITIONS AND MATERIALS TO AVOID: AVOID HEAT, FLAME ANDi, CONTACT WITH STRONG OXIDIZING AGENTS, HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE AND UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION. SECTION X ii EMPLOYEE PROTECTION RESPIRATORY PROTECTION AVOID PROLONGED OR REPEATED BREATHING OF VAPORS. IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMITS (SEC.' IV) USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910. 134 USE E,!THER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS. PROTECTIVE CLOTHING AVOID CONTACT WITH EYES. WEAR SAFETY GLASSES OR GOGGLES AS APPROPRIATE. AVOID PROLONGED OR REPEATED CONTACT WITH} SKIN. WEAR CHEMICAL-RESISTANT. ~LOVES*AND OTHER CLOTHING AS REQUIRED TO MIN..TMI ZE CONTACT. ,. ADDITIONAL PROTECTIVE MEASURES USE EXPLOSION-PROOF VENTILATION AS REQUIRED TO CONTROL VAPOR coNcENTRATIONS. AIR-DRY CONTAMINATED CLOTHING IN A W~LL VENTILATED AREA, THEN LAUNDER BEFORE REUSING. PRODUCT NAME: MINERAL SP!R]TS 145-EC MSDS 7,570. PAGE 4 SECT]ON X] ? ENVIRONMENTAL PROTECTION SPILL OR LEAK PROCEDURES ' CAUTION. COMBUSTIBLE. *** LARGE SPILLS *** ELIMINATE POTENTIAL SOURCES OF IGNITION. WEAR APPROPRIATE RESPIRATOR AND OTHER PROTECTIVE CLOTHING. SHUT OFF SOURCE OF LEAK ONLY IF SAFE TO DO SO. DIKE AND CONTAIN. REMOVE WITH VACUUM TRUCKS OR PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE WITH AN ABSORBENT SUCH AS CLAY, SAND, OR OTHER SUITABLE MATERIAL; PLACE IN NON-LEAKING CONTAINERS AND SEAL TIGHTLY FOR PROPER DISPOSAL. FLUSH AREA WITH WATER TO REMOVE TRACE RESIDUE; DISPOSE OF FLUSH SOLUTION AS ABOVE. *** SMALL SPILLS. *** TAKE UP WITH AN ABSORBENT MATERIAL AND PLACE IN NON-LEAKING CONTAINERS FOR PROPER DISPOSAL. NASTE DISPOSAL i UNDER EPA - RCRA (40 CFR '261.21), IF THIS PRODUCT BECOMES A WASTE MATERIAL, IT WOULD BE IGNITABLE HAZARDOUS WASTE, HAZARDOUS WASTE NUMBER DO01. REFER TO LATEST EPA OR STATE REGULATIONS REGARDING PROPER DISPOSAL. .'I ENVIRONMENTAL HAZARDS *~ UNDER EPA-CWA, THIS PRODUCT IS CLASSIFIED AS AN OIL UNDER SECTION 311. SPILLS INTO OR LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE REPORTED TD THE NATIONAL RESPONSE CENTER, 800-424-8802. EPA - COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION AND LIABILITY ACT. UNDER EPA-CERCLA ("SUPERFUND") RELEASES TO AIR, LAND OR WATER MAY BE REPORTABLE TO THE NATIONAL RESPONSE CENTER, 800-424-8802 (CIRCUMSTANCES SURROUNDING THE RELEASE AND CLEANUP DETERMINE REPORTABILITY). SECT]ON XII ~ SPEC]AL PRECAUTIONS i KEEP LIOUID AND VAPOR AWAY FROM HEAT, SPARKS AND FLAME. SURFACES THAT ARE SUFFICIENTLY HOT MAY IGNITE EVEN LIQUID PRODUCT IN THE ABSENCE OF SPARKS OR FLAME. EXTINGUISH PILOT LIGHTS, CIGARETTES AND TURN OFF OTHER SOURCES OF IGNITION PRIOR TO USE AND UNTIL ALL VAPORS ARE GONE. VAPORS MAY ACCUMULATE AND TRAVEL TO IGNITION SOURCES DISTANT FROM THE HANDLING SITE; FLASH-FIRE CAN RESULT. KEEP CONTAINERS CLOSED WHEN NOT IN USE. USE WITH ADEQUATE VENTILATION. :: CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, CAN CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, DRILL, GRIND, WELD OR PERFORM SIMILAR OPERATIONS ON OR NEAR CONTAINERS. STATIC ELECTRICITY MAY ACCUMULATE AND CREATE A FIRE HAZARD. GROUND FIXED EOUIPMENT. BOND AND GROUND TRANSFER CONTAINERS AND EOUIPMENT. SECTION X!!! ' TRANSPORTATION REQUIREMENTS DEPARTMENT OF TRANSPORTATION CLASSIFICATION: COMBUSTIBLE LIQUID D.O.T. PROPER SHIPPING NAME: PETROLEUM NAPHTHA ,.; OTHER 'REQUIREMENTS: UN 1255. GUIDE SHEET 27.i SECTION X]V OTHER REGULATORY CONTROLS THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES PRODUCT NAME: MZNERAL SPZRXTS 145-EC MSD$ 7,570-3 PAGE 5 ! THE INFORMATION CONTAINED HEREIN IS BASED ON THE DATA AVAILABLE TO US AND IS BELIEVED TO BE CORRECT. HOWEVER, SHELL MAKES NO WARRANTY, EXPRESSED OR IMPLIED REGARDING THE ACCURACY OF THESE DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. SHELL ASSUMES NO RESPONSIBILITY FOR INdURY FROM THE USE OF THE PRODUCT DESCRIBED HEREIN. DATE PREPARED:OCTOBER 04, i985 dOHN P. SEPES! BE SAFE .............. ' ......................... READ OUR PRODUCT SHELL OIL COMPANY SAFETY INFORMATION ...AND PASS ZT ON PRODUCT SAFETY AND COMPLIANCE (PRODUCT LIABILITY LAN P. O. BOX 4320 REQUIRES ~T) HOUSTON, TX 77210