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TE/FAC T L I T¥ D ]R-ZklVI _:-::,- !~ ORlVf ~ NORTH SCALE: BUSINESS NAME: FLOOR: OF B.C. LABORATORIES, INC. I 1 DATE: 7 /15/87 FACILITY N~ME: UNIT m: OF · I 1 (CHECK ONE) SITE DIAGRAM FACILITY DIAGraM . Y l(Inspector's Comments): -OFFICIAL USE ONLY- - SA - ORTH SCALE: BUSINESS NAME: FLOOR: OF B.C. LABORATORIES, INC. ! l DATE:7 /15/87 FACILITY N~ME: UNIT -~: OF · I I (CHECK ONE} SITE DIAGR~M /~'" FACILITY DIAGI~M (Inspector's Comments): -OFFICIAL USE ONLY- - 5A - ,...,"/~ // ® .... .....'"~ ..,~\:~ ~ . J~-__ E._ __ - S / A~IC ACCESS / OFFXff~ E" OFFICE OFFI~ ~ 0 '~ q lO0 PIERCE ROAD ITE/FACI LI TY D G RTtlv~ FORM 5 NORTH SCALE: BUSINESS NAME: FLOOR: OF B.C. LABORATORIES, INC. I I DATE: 7 /15/87 FACILITY NAME: UNIT ~: OF (CHECK ONE) SITE DIAGR~ f/ FACILITY DIAGraM i (Inspector's Comments): -OFFICIAL USE ONLY- - 5A - 5/5A Business Name: B.C. Laboratories, Inc. If Form 5A Box is Checked: Area Map # 1 of 2 ~ North Name of Area: Pierce Road SITE MAP - 5 ~-~ AREA - Form 5A Business Name: B.C. naboratories~ Inc. If Form 5A Box is Checked: Area Map # of ~ North Name of Area: -~ SITE MAP - 5 ~-] AREA - Form 5A ~? :' Business Name: B.C. Laboratorie, s~ Inc. If Form 5A Box ts Checked: A~ea Map · 2 of 2 ~ ~orth ~a~ of ~a: ~nion Ave. .ousE 8 QUINCY STREET }lOUSE 9 FLOWER STREET GARAGE ~// ALl.By ................ -~ ,'z, ~--[;7' ~ 1 <) I IlTM TM ' cLARK ELECTRIC . I [HHS STORAGE YARD ~o' B.C. ABS IIELT ENGINEERING VALLEY DECAL, INC. 3020 3000 2930 UNION AVENUE _ ~ CANAL., .__ .~_ - 5/5A ~ SITE MAP - Form 5 ~-~ AREA - Form ..-SA i.? Business Name: ..B.C, Loborato'ries: Inc. If Form 5A Box is Checked: Area Map # of ~ North Name of Area: [[ninn A~. %~ ~'~e "' I I _~ ' ~--~,;. -'--'-I ,' _J I r~ OFFICg 30[& UNION AVENUE .LAB()RA'I~ORIES, IFIC. Fred J. Beesley Account Representative 4100 Pierce Road (805) 327-4911 Bakersfield, CA 93308 Account Number ACCOUNTS RECEIVABLE~DJUSTMENT Februar~ 18~ 1993 Date New Account New Address Esther Duran Close Account From Service Chan.qe Other Adjustments X Fire Department- Hazardous Materials Division Department/Division B C LABORATORIES INC Billing Name 4100 ATLAS CT Billing Address 4100 ATLAS CT Site Address Parcel # (if ·Applicable) Landlord Name & Address (If Applicable) ADJUSTMENT Last Billed Correct Billing Adjustment to Effective Date of ., Billing. Change 01-01.93 $198.31 01-01-93 Approved By: Remarks: INCORRECT AMOUNT BILLED. BUSINESS NO LONGER HANDLES H~7. MAT. FIRE DEPARTMENT 210~ H STREET S. D. JOHNSON July 28, 1993 BAKERSFIELD, 93301 FIRE CHIEF 326-3911 I, Steve Ball Jr., have reviewed the site map for B.C. Laboratories located at 4100 Pierce Road and 3014 Union Avenue, from the City of Bakersfield Hazardous Materials Division. This information is to be used for internal purposes and will not be released to the public. REH/dlm EMPLOYEE TRAINING PROGRAM Information is provided and training is done with a 40-minutes video which includes the fOllowing: - Key Elements of a Chemical Hazard Communication Program - Hazardous Chemical Labeling - Types of Chemical Hazards - Hazardous Chemical Dosage - How to Use MSDS's ~aKey Elements in Responding to Chemical Spills - Control of Chemical Exposures - The Concept of Dose - Allowable Chemical Exposure Standards - OSHA Permissible Exposure Limits - ACGIH Threshold Limit Values - Routes of Entry Unto the Body - Inhalation - Absorption - Injestion - Effects of Hazardous Chemicals on Health - Acute Effects - Chronic Effects - Carcinogens/Mutagens/Teratogens Safety meetings covering emergency procedures, i.e.; phone 911, use of in-house emergency response equipment, showers, eye wash stations, blankets, sand containers, spill kits., etc.; evacuation procedures as well as in-house handling and safety problems and procedures; reviewing use of MSDS sheet's. BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID# BUSINESS NAME: BUS I NESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further, action, this form must be retui-ned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. ,3. Answe,~- the questions belo~v for THE FACILITY UNIT LISTED ~ELOW 4. Be as BRIEF and CONCISE as .possible. ~FACILITY UNIT# FACILITY UNIT NAME: B. C..LABORATORIES, INC. SECTION 1: MITIGATION, PREVENTION, ABATEMENT PROCEDURES MITIGATION: Use of Hazardous Material Emergency Spill Kits installed at the facility. Evacuation procedures taught to employees. PREVENTION: All gas bottles are chained. Acids and solvents stored in proper containers with proper labels. Employee training in proper handling of materials. ABATEMENT : Take action and precaution so that further complications do not arise as a result of the initial spill or emergency situation. SECTION 2: NOTIFICATION AND EVACUATION PROCEDb~ES AT THIS b~IT ONLY Ail exits are properly marked with visible signs. Ail employees have been informed to use the nearest of three (3) exits. Phone 911 to desribe nature of problem and request ehelp. Depending on the nature of the problem and its severity, neighboring businesses, (Cal- ifornia Highway Patrol) and those across Pierce Road would be notified to evacuate their premises. SECTION 3: HAZARDOUS MATERIALS FOR THIS UNIT ONLY A. Does this Facility Unit contain Hazardous Materials? ..... ~. (~ES)).NO k If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES (~0)) If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form #4A-l) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form #4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION Hand operated fire extinguishers handy to all locations. SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY E~MERGENCY 'RESPONDERS Fire. hydrant on north side of front driveway. SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY. A. NAT. GAS/PROPAN~ North side front of building. B. ELECTRICAL: North side front of building. C..WATER: North side front of building. D. SPECIAL: E. LOCK BOX: YES / NO IF YES, LOCATION: NONE iF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO - 3B - BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 (805) 326-3979 OFFICIAL USE ONLY ID# ~9~~ BUSINESS NAME 001}655 HAZARDOUS MATERI ALS BUSINESS PLAN AS A WHOLE FORM 2A INSTRUCTIONS: 1. To avoid further action, return this form by 2.. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: B. C. LABORATORIES~ INC. B. LOCATION / STREET ADDRESS: 4100 PIERCE ROAD CITY: BAKERSFIELD, CA ZIP: 93308 BUS.PHONE: (805)327-4911 SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE DURING BUS, HRS. AFTER BUS. HRS. A. S~J, EGLIN - OWNER Ph# q?7-aqll Ph# 87!-0747 B. DAN SC~UL%Z - LAB, MANAGER Ph# q77-4911 Ph# 5gq-q6?5 SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: NORTH SIDE!"~RONT B. ELECTRICAL: NORTH SIDE FRONT ~. C. WATER: NORTH SIDE FRONT · D. SPECIAL: BOTTLED GAS MANIFORLD SHUT OFFS - NORTH SIDE FRONT E. LOCK BOX: YES / NO IF YES, LOCATION: NO IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE Lab Manager, Dan Schultz and Owner, Joe Eglin. Both have lengthy experience in the handling of hazardous materials. Spill kits available as as are..~. ~ ~.~ well overhead emergency showers and eye wash stations. SECTION $:. LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE Eye wash stations - emergency showers - fire blankets - stretchers - first aid kits. Closest hospital for hazaldous treatment - Bakersfield Memorial. SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAzARDous ,MATERIALS:...- .................................... ((yES~ NO ((YES~ NO B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGENCIES: .......................... ((YES D NO ((YES~ NO C. PROPER USE OF SAFETY EQUIPMENT: .................. ((YESD NO ((YESD NO D. EMERGENCY EVACUATION PROCEDURES: ................. ((YES D NO ((YESD NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... ((YESD NO ((YESD NO SECTION ?: HAZARDOUS MATERIAL CIRCLE YES OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES[~NO)) I, J.J. EGLIN , certify that the above information is accurate. I understand that this information will be used to fulfill my firm's oblizations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. BUSINESS NAME B C LABORA IES, INC ID ER 215-000-000665 LOCATION 4100 PIERCE RD HIGH HAZARD RATING 4 E . MITTGATION / t~REVENT I ON / ABATEMENT LAST CHANGE 11/16/87 BY ESTER 3A SEC 1) MITIGATION: USE OF HAZARDOUS MATERIAL EMERGENCY SPILL KITS INSTALLED AT THE FACILITY. EVACUATION PROCEDURES TAUGHT TO EMPLOYEES'. PREVENTION: ALL GAS BOTTLES ARE CHAINED. ACIDS AND SOLVENTS STORED IN PROPER CONTAINERS WITH PROPER LABELS. EMPLOYEE TRAINING IN PROPER HANDLING OF MATERIALS. ABATEMENT: TAKE ACTION AND PRECAUTION SO THAT FURTHER COMPLICATIONS DO NOT ARISE AS A RESULT OF THE INITIAL SPILL OR EMERGENCY SITUATION. PAGE 5 12/28/88 11:13 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 0089-8~9 (§08) 'ONI '$~&SXS V&V~ X&~&VS ~VIH~£V~ 'S~SI~H8 ~IgH& ~&V~DVA~ O& ~RI~I&ON ~ ~qDOM ~H ~DH~I8 SSOHDV ~SOH& ~NV XVMHDIH VINHO~IqVD) S~SS~NISD~ DNI~O~HDIgN 'XIIH~A~S g£I ~NV ~Rq~o~8 ~H~ ~O ~H~iVN ~H~ NO DNI~N~8~ '8~H AS~D~H QNV ~q~oHd ~0 ~H~iVN O~ II6 ~NOHd 'S~IX~ (g)~HH£ ~0 ~SaHVaN ~H~ ~SD O~ ~HO~NI N~ ~AVH S~xOq~N~ ~qv 'SNDIS ~HISIA H£IM ~VN A~80~ ~V S~IX~ ~V (g O~S Vg H~IiS,W X8 ;,8/9I/II ,~DNVHO £SV~I NO I ~LVflOVA~{ / NO I iVO I ~I I iON ~I ~tiOClcIN~I ' fi 'fdf:~ J, NOH& ,40 ,w~IS H,I, HON NO iNV%I(IAH ,WHI& (~ D,~S VZ 'NOIAOMiOHd MHI~ ~iVAIHd HO~ SNOIiVOOq qqv &V X~NVH SHMHSIDDNI~XM MHIM ~MiVHMdO ~NVH (P OMS V~ M.~.Y.S.W AH £8/9I/II MONVHO ,I, SVq S ~I I ~-IcIcIflS H ~I JLVM / NO I JLO~IiOHcI 2tHI~I ' ~{ ~ DNIiVM ~MVZVH HDIH ~M HOHHId 00I~ NOIiVOOq ~99000-000-~Ig M~HNRN ~I ONI 'SMIMOIVMO~Vq O ~ ~VN SSMNIS~H BUSINESS NAME B C LABORA IES, INC ID N ER 215-000-000665 LOCATION 4100 PIERCE RD HIGH HAZARD RATING 4 FACILITY UNIT 01 A . OVERALL HAZARDOUS MATERIALS INVENTORY LAST CHANGE 03/08/88 BY EVAMC ID TYPE NAME MAX AMT UNIT HAZARD LOCATION CONTAINMENT USE PURE SULFURIC ACID 54 GAL HIGH OUTSIDE STORAGE SHED GLASS CONTAINER[S] OTHER ID PERCENT COMPONENTS HAZARD LISTS 1080.00 100.0 SULFURIC ACID, SPENT HIGH PURE NITRIC ACID 55 GAL EXTREME OUTSIDE STORAGE SHED GLASS CONTAINER[S] OTHER ID PERCENT COMPONENTS HAZARD LISTS 1793.00 100.0 NITRIC ACID (EPA) EXTREME EPA PURE ARGON 8304 FT3 NONE OUTSIDE GAS MANIFOLD PORTABLE PRESS. CYL. OTHER ID PERCENT COMPONENTS HAZARD LISTS 1365.00 100.0 ARGON NONE PURE ACETYLENE 801 FT3 EXTREME OUTSIDE GAS MANIFOLD PORTABLE PRESS. CYL. OTHER ID PERCENT COMPONENTS HAZARD LISTS 1241.00 100.0 ACETYLENE EXTREME WASTE WASTE OIL 280 GAL UNKNOWN OUTSIDE BACK DRUMS OR BARRELS MET.. WASTE ID PERCENT COMPONENTS HAZARD LISTS 1598.00 100.0 WASTE OIL UNKNOWN PAGE 3 12/28/88 11:13 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 BUSINESS NAME B C LABORATORIES, INC ID NUMBER 215-000-000665 LOCATION 4100 PIERCE RD HIGH HAZARD RATING 4 3 . HAZ MAT TRAINING SUMMARY LAST CHANGE / / BY < NO INFORMATION RECORDED FOR THIS SECTION 4 . LOCAL EMERGENCY MEDICAL ASSISTANCE LAST CHANGE 11/16/87 BY ESTER 2A SEC 5) EYE WASH STATIONS, EMERGENCY SHOWERS, FIRE BLANKETS, STRETCHERS, AND FIRST AID KITS. CLOSEST HOSPITAL FOR HAZARDOUS TREATMENT - GREATER BAKERSFIELD MEMORIAL HOSPITAL - 420 34TH ST - 327-1792. PAGE 2 12/28/88 11:13 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 BUSINESS NAME B C LABORA IES, INC ID N ER 215-000-000665 LOCATION 4100 PIERCE RD HIGH HAZARD RATING 4 1 . OVERVIEW LAST CHANGE 11/16/87 BY ESTER JURIS CODE 215-001 JURIS BAKERSFIELD STATION 01 MAP PAGE 102 GRID 23B FACILITY UNITS 1 HAZARD RATING 4 RESPONSE SUMMARY 2A SEC 4) LAB MANAGER, DAN SCHULTZ AND OWNER, JOE EGLIN. BOTH HAVE LENGTHY EXPERIENCE IN THE HANDLING OF HAZARDOUS MATERIALS. SPILL KITS ARE AVAILABLE AS WELL AS OVERHEAD EMERGENCY SHOWERS AND EYE WASH STATIONS. EMERGENCY CONTACTS 2A SEC 2) JOE J EGLIN - OWNER - 327-4911 OR 871-0747 DAN SCHULTZ - LAB MGR - 327-4911 OR 589-9625 UTILITY SHUTOFFS 2A SEC'3) A) GAS - NORTH SIDE FRONT B) ELECTRICAL - NORTH SIDE FRONT C) WATER - NORTH SIDE FRONT D) SPECIAL - NONE E) LOCK BOX - NO 2 . NOT IFICATION / PUBLIC EVACUATION LAST CHANGE / / BY < NO INFORMATION RECORDED FOR THIS SECTION > PAGE 1 12/28/88 11:13 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 CITY of BAKERSFIELD NON--TRADE SECRETS , pM 1 of 2 BUSINESS NAME: B C Laboratories, Inc. 0WN~R NAM~: ..... J.J. Eqlin~ .... NAM~ OF T~ =~.~FACILI~:__ Main LOCATION: . 4100 Pierce Rd. ADDRESS: ~100 P~ Rd, STANDARD I~. CLASS CODE c~rY, ZIP: Bakersfield~ CA 93308 CI~, ZIP: · Bakersfield. CA ~3308 DUN AND BR~STREET NU~R PHONE ~: 805-327-4911 PHONE ~: 80S-327-4911 - - C~t CW ~ ~ Est ~ts m Site I~ ~ l~ ~ St~ tn FKJItty ~ ~ I~t~tt~ :.~l~__J. ~ i ..... ~_~ ~8 __ Is~l 3esl oa I ~ I ~ I~ IOutside S~p~g.e :Shed ' .......... "~ca~ ~ ,~lth ~z,~ C.A.S. ~ 7664-93-9 ~t tt ~ & C.A.S. ~ ~r~ ,11 t~t e~ly) 96 Sulfuric Acid ~ith of P~ ~lth ............ ~ J ~ I ~ I99 J O~tsid~ Storage Shed ..... ......... 1 ............ L.L ..... P~icel ~ ~ith HizI~ C.A.S. ~ ~t II ~ i C.A.S. ~ ~-~ r--~ r--~ r--~ ~t ~ ~&C.~.S. ~ ~ : ~. ~z,~ ~-: ~t~v~y ~-: h~th~-: ~ ml~ [[] i~l,t, . 0f ~ ~lch ...... ~t I] ~IC.A.S. ~ .-~-k--[ 45 [ 35 L__~0 ~kAL_~ 365 ~09 J A ~ A ~99 {O~tside Storage Shed ............ P~*col ~ ~lrh b,o~ C.l.S. ~ 7697-37-2 ~t II b i C.I.5. i (C~ oil t~t o~ly) 70 ~ - .... ~t. ~ ~ c.A.a. ~ ~Jth of P~s~ ~Jth ; .......... ...... iL ( i51 ................. (~k all t~t ~ly) ,_ _ - -- -- ~--~ C~t 12 b iC.A.S. ~ ~lth of Prflsure ~lth L~ Manager 327-4911 '~:~,C~T~TS I~ J.J. Egl~ O~er 327-4911 ~-~ .............................. ~, ;[-~p~ ................~ ~ ......... ~: ~W ..... :,et~fica~l~ (Re~d f~d s~ 4fte~ coJpJ~t~n~ a]f sect Jena) ~ obtaini~ t~ Jnf~tlm. I ~liwe t~t t~ sumitt~ interim is t~. ac~rKe. ~ C~lete. t CITY of BAKERSFIELD '~____~ IIC HAZARDOUS MATERI ALS INVENTORY NON_TRADE SECRETS , p...~ of .~.. rOtATIOn: 4100 Pierce Rd. ADDRESS: 4100 Pierce Rd, STANDARD I~ S~ ~O~E CrTY, ZIP: R~k~w~im~a mn ~ao CI~, ZIP: - B~ersfi~l~, CA 93308 DUN AND BR~STREET NUMBER_ PHONE ~: 805-327-491I ........ PHONE ~: 327-4911 _- - --- -- .iz_l. a304i 6400 1_!6000 1~3.1~s lo. hsool a I 99[ ...... Ph~ic~l ~ N~lth ~z~ C.l.S. ~ ~t I1 ~ & C.A.S. ~ 100 ARGON ~lth of P~ ~lth P~ic, l ~ ~ith HiZi~ C.l.S. ~ ~t II ~ b C.k.S. ~ ACETYLENE ~lth of P~s~ ~lth ~lth of Pr~sure ~lth nEQGENCY ~I~TS I1 ........... ii nr'~ .... C,r~,(icati~ (Read and sJ~ after co~pJetJnff ail sections) I ~lty (~ - ~ ~rin% name) Do herebF certify that I have reviewed the attached Hazardous Materials business plan for ,, (name of business) and that it along with the attached additions or corrections constitute a complete and correct Business Plan for m,v facility. ~2-~n~ure - - date - r-, 4 Farm and Agriculture ~--' KERN COUNTY FII~E DEPARTMENT HAZARDOUS MATERI ALS INVENTORY DUN AND 8RADSTRE~T Nl!MiIE~ Standard Business BUSINESS NAME: B.C. Laboratories, Irc OWNER NAME: J J LOCATION: 4100 Pierce Road ADDRESS: . 5617 Red]ailcls__D_r_,___ CITY, ZIP: Bakersfield, CA 95508 CITY, ZIP: Bakersfield, CA 95506 PHONE #: (805) ~_li PHONE ~:_ ~805)87~0~1 Pa~e __!.._ of _~.__ STANDARD IND. CLASS CODE: 87~4 NAME OF THIS FACILITY:_..~W~b~ ~2~ - R~ER TO INSTRUOTIONS FOR PROPER OODES 1 2 3 ~ 5 6 ? 8 9 10 ]1 T~ans Ty~e Max Average Annual Measuee Cunt Cunt Cunt Use % by Namss of N~x~u~e/Components Code Code ~mt Amt Est UMts lyre P~ess ]'emp Code ~t See Instructions u-- ~ Immediate ....................................... Health u~ F~ne u--~ Delayed Health C.A.S. Numbe~ ~ -.~- ........................... ~'--~ Reactivity L--~ Sudden Release o¢ PnessuPe on Site Health ~J Fire L--J Delayed Health C.A.S. Number___ 7..~.: ........ c--~ Reactivity ~-~ Sudden Release of Pressure on Site Hea)th ~ Fire ~---' Delayed Health C.A.S. Number___Z/.~.=~S_.%.% .... r -- q r -- ~ 13 ) ~ Days i~-- I L__~ Reactivity s._¢ Sudden Release of Pressure on Site c .... ¢ ~,cY o0N~c~s ~'~-~- ........................................ ~' ~:_~A~e= ............................... ~ ~ Dan Schultz L~b ManaE~ ..................... 5.89&g&25_ .......... '15~ ..................................................... Tiii~ ............... z~ Certification (A'ead and sJ~n al'~r co~p]etJnE ~ sections) I certif under penalty of law that I have personally examined and am familiar with ~he informa(ion submi~ ~his and all a(~ached documen(s, and ~ha( based on my inquiry ~f ~hose individuals resoonsible for obtaining ~he information, ] believe ~hat t~~d ~paCtio~ tr~, acc~, and compmte. ~ ~ _ Farm and Agricuhune '-- ~ KE~N COUNTY FI~ DEPARTMENT HAZARDOUS MATERIALS INVENTORY r--'~ DUN AND 8RADST~FEI Standard Business ~- [ J 06-667-6222 BUSINESS NAME: B.C. Laboratories. I~c. OWNER NAMe: ,T_.T: ~]i~ LOCATION: 4100 Pierc~ Road ADDRESS: ~fi]7 9ed]~ D~. CITY, ZIP: Bakersfield, CA 9SS08 CITY, ZIP: Bakersfield, CA 93S06 STANDARD IND. CLASS ~ODE: 87~4. NAME OF THIS FACILITY:__Pie~ce Rd. - ~ER TO INSTBUOTIONS FOR PROPER OODES lrans Type ~ax Average Annua] Me~sure C~t C~t Coot Use ~ by Names of Mixture/Comoonents C~e Code Amt Ami Est Units lyDe Press iemp Code Nt See Instructions Heahh ............................................................... u--J Fire ~-- ~ Delayed Health C.A.S. Number ~ ~ - Reactivity ~-- ~ Sudden Release of Pressure on Site Hea~[h .................................................................. Fire ~]eyed Health C.A.S. ~uaber ~ ~_~-/ u_~ Reactivity ~--~ Sudden Release of Pressure on Site J Health u--J Fire ~-- ~ Delayed Health C,A.S. Number ............................ =-- J Reactivity ='- J Sudden Release of PPessure ~ Site = =~ Dan Schultz ' · Lab M~na~er 589-9625 Certification (Read and sY~n al(er comple(JnE all sec~Yons) I certify under penahy of ta~, t~t I ~ve ~rs~ally examin~ and am familiar with the information subm~d in this and ell at~ached documents, and t~t ba~ed on my inquiry ~f~se individuals responsible for obtaining the infor~a~ion, ) believe tha= t~m~ted ~orfa~)tru~ accuse, and complete. r-, 4 Farm and Agriculture c_J ~R.N COUN~ FIR.B DEP~TMEi~ HAZARDOUS MATERI ALS INVENT O RY Standard Business c~J 06-667-6222 " BUSINESS NAME:' B.C. Laboratories. Inc. OWNER NAME: LOCATION: 4100 Pierce Road ADDRESS: ~617 ~ed!~,Dr. CITY, ZIP: Bakersfield, CA 93305 C~TY, ZIP: Bakersfield, CA 93306 PHONE ~:. _ /805] 327-4911 PHONE ~:. [805~ 871-07~7 ~age_~.. o~ /.~. STANDARD IND. OLASS. CODE: 873~ NAME OF THIS FACILITY: . Pierce Rd. ~FER TO INSTRUCTIONS FOR PROPER CODES Trans Type Max Average Annual Measure Cont Cont Cont Use % by Names of Mixture/Comoonent$ -Code Code Amt Ami Est Units Type Press lemp Code Wt See Instructions ~' 1 .... .'f_~ .... [ .... _~:_~ ..... l?__-~sJ_~_?_]. / / ~- ,--~-~/~ .... ~ ~mmediate __U~.,:_~ _®~-/-. ~~_...,f.~_~.__~k_~_//__. Health .... ['~ Fire ~- ~ Delayed Health C.A,S. Number ...... ~.~..~_~_~.,__~._-___,~-__. r--~ r--n c_J Reactivity u--J Sudden Re]ease of Pressure on Site u---J Health ................................................................... u _.~ 'Fire u_~ Delayed Health ¢.A.S. Number ...... _-_ ......-'_ ........ r -- '~ r -- ~ 13 ) I~ Oays i ~-~ Reactivity L--.~ Sudden Release of Pressure on Site ~-==-'~ / .~ / j__./_ ./.~ .... [--'~ Immediate Health ................................................................. ~-' ~-" /3/o ~... -__5_. ~__a Fire u_ ~ Delayed Health C.A.S. Number ........... _-_ ~J~-~ Reactivity ~---J Sudden Release of Pressure on Site ' IP Ban Schultz Lab ~anager 589-9625 Certification ,(Read and sign after completing all sections) I certif under enalty of la~ t~t I have ~rs~ally examin~ and am familiar with the information subm~d in this and all attached d~uments, and inquiry ~f~sePindividuals responsible for obtaining the information, I believe that ~m~ted ~or~~tru~cu~, and complete. Dan S~h~g~_ :._~.~k~r~.~ ~ ........ , ................. ~ ..... ~- ~.te ~¢~8~8 'f" Far., ~n~ ~gr~cuhure ~--~ KE~N COUNTY FI~E DEPARTM~FT HAZARDOUS MATERI ALS INVENTORY 06-667-6222 BOSINESS NAME: B.C. Laboratories. Inc. OWNER NAME: .T_.T ~]~n " LOCATION:_ 4100 pierce Ro~d ADDRESS: ~617 ~e~!~ Dr. CITY, ZIP:. Bakersfield, CA 95508 CITY, ZIP: Bakersfield, CA 95306 PHONE ~:~ (805~ 32%-~9~.! . PHONE ~: ~.05) 871-~7 STANDARD IND. CLASS CODE:_ 875~ NAME OF THIS FACILITY: _Pierce Rd. ___ ~FER TO INSTRUCTIONS FOR PROPER CODES lrans Type ~ax Avepaoe Annual ~e~sure Cont Cont Cont Use ~ by Name~ of Mxture/Components C~e Code Am: Ami' Est Units lyoe Press iemp Cooe Wt See Instructions Heakh ............................ ~ -- J Fire ~-- ~ ~eleyed Health C.A.S. Number ......... ~ .... ~. r--n r--~ 13) ~ Days i~,~ t u--J Reactivity u--J Sudden Release of Pressure on Site ~----J ..... 1 .... ..$ I / .............. u~J Immediate C_ ,_._ Health ...... u--J Fire ~J Oela~ed ~ealth C,A.S. Number ........... ~- . T .... =--~ Reactivity u_u Sudden Release of Pressure on Site =----~ Health ' - ........... u_j Fine ~--'~<J Delayed Health C.A.S. Number._~.~.$~.~. r ----~ .~ ~--~ Reactivity ~--~ Sudden Release of Peessu~e on S~e .... J~ j'J~ ~:REENCY CONIACIS ~ _T 3 ~' :- O . .... .................................... ............................ ....... ~2 Dan Schultz ' Lab Manager 589-9625 j~ I certify under penalty of law that ] have personally examined and am familiar with the information submjJ:.t~d in this and all attached documents, and that based on my inquiry 6f,,e~hose indiv{duats responsible for obtaining the information, ] believe that th~e-,sq,bmitted ~4(,onma~Ct~r~-i?-)true~ accury~t), and complete. __ /O-- Dan S c h U l: ~. :. _ .L. SkQ r,~ I.O.r.v. _ ~ILa ~.aL ....... , ................................................. ~-~-6{f{~TaT t{t/e ot owner/operator O~ owner/operator s authorized representative ~.mqa~,ore J uate 5~gneo"' Farm and Agricukure L_= ~P~ COUNTY FIP~ DEPARTMENT HAZARDOUS MATERI ALS INVENTORY r -- ~ ~UN Standard Business BUSINESS NAME: B.C. Labor.atories. Inc. OWNER NAME: ,T-.T- LOCATION: 4100 ~ierce Road ADDRESS: ~ .~617 ~e~!~ Dr. CITY, ZIP: Bakersfield, CA 93308 CITY, ZIP: Bakersfield, CA 93506 PHONE ~: [805) 327-49~1 ' PHONE ~: [805] 871-~7 Pa~e.~_. of _~ STANDARD IND. CLASS CODE:_ 8734 _ NAME OF THIS FACILITY: ' Pierce Rd. ~FER TO INSTRUCTIONS FOR PROPER CODES 1 2 3 ~ 5 ~ ? 8 9 10 ~ T~ans Typo Max Average Annual Measure C~t C~t Cont Use % by Names of ~ix~u~e/Compomemts C~e C~e Amt Amt Est Units lype Press iemp Cooe Nc' See Instructions Fire [~] Deiayed Health C.A.S. ,u~ber_..~.7~_z_~/_Z~ ...... ~ Reactivity ~--~ Sudden Release of Pressure on Site ..J ....... j. .... / c ~ ~ ................................................... r--n r--n 13) ) Days ~:i~ - J ~--J Reactivit~ ~--~ ~dden Release of Pressure ~ Site. ' Health .......................................................' u--J Fire u--J Delayed Health C.A.S. Number 7~ ~3 Reactivity ~--J Sudden Release of Pressure on Site .... EMERGENCY CONIACTS ,l_ J .J. ~] i~ .................................... a~r_ ............................... ~3_[:_03_4]. ....... ' ' N~ '. ..... ,,~,e ~, .~ .~e ~ Dan Schultz ~ab M~na~es 589-9625 Certification (Read and ~Y~) a[(ez' eom~Je(Yn~ a]] I eeetif~ under penalty of law t~t I ~ve ~r~ally examin~ and am ~amiliar with ~he infoemat{on sub~d in this and all attached d~uments, and inquiry or--se individuals responsible for obtaining ~he information. I believe that ~m~ted ~or~a~tru~c~. and complete. ~" ~-~-~FFl~TaT't{tTe o~ ow~er~operat~r~ owner~6~rator s aut~rlzeo representa~lv~ ~~ Oate 51gne~ Far~. and Agriculture a__~ Yd~P,~T COUNTY FIR]~ DEPAS~Ii'MEI4'T ~ HAZARDOUS MATERI ALS INVENTORY '~ Standard Business ~ ~ ~ " 06-667-6~ ~USI~SS ~AH~:' ~.C..~bo~to~ies. Inc. O~BR ~AH~: 3_3 ~]in CitY, ZIP: ~ke~ield, CA g~O~ ~I~Y, ZIP: ~e~s~ield, C~ g~OO Tnans Type ~x Averaoe Annual ~asure Cont C~t Cont Use % bv Names of ~ixtune/Comoonents · ~e Code Am: Am:' Es~ Units 9yoe Press ]emp Code ~:' See Instructions ~_.J. ~. ]__. 2 ___1_ _L.__~I ..... ~:g. ...... l~.l. LG_J. L ._LES ..... ~[¢2v.~...~e .................................. ~ ~o, kh .......................................... ~ .......................... ~ ~--~ Fire ~_2 belayed Health ~.X.S. Number ........................... ~ ~ Reactivity ~--~ Sudden Release o{ Pressure on Site ~---- ~ Health ........................ ~ ~ire '--~ ~]ayed ,aa]th c.~.s. ,umber_._E.O._...-._~.~_-..7_. ..... Reactivity ~--~ Sudden Release of Pressure on Site Health ' '- ~ Fire L_ J Delayed Hea]th C.A.S. Number ...... ~ Reactivity ~--~ Sudden Re]ease of Pressure on Site ..... tMt~ENCY' '" CON]ACTS -- ~ .................................... ............................. ~'~?-P~e ......... ...................................... ! certify under penalty of ]aA. that ] have personally examined and am familiar with the information subm~.in this and all attached documents, and that based on my inquiry of,-mhose individuals responsible for obtainino the information. ] believe that th,,e-~Lbmitted jJ:~orma,~,,ory-~sgtrue~ accu~%tg, and co, plate. R~6[-~'6FF~E~T'[{[~e oF o,ner/opera[or u~ o,nen/opera[oF s a6t~F[ze~ Fepnese~[a[{G~ ................ ~ ....................... 0~[~'~ .... ~ar~ and Agriculture =--~ KERN COUNTY FIFLE DEPARTMENT ~1~ HAZARDOUS MATERI ALS INVENTORY r--~ DUN ~NO 8R~DST~E~ Standard Business ~ ~ ~ 06-667-6222 BUSZNESS NAMe: B.C. ~bo~ato~ies. Inc. . OWneR NAME:...T_.T ~g]~ CITY, ZIP:... B~ke~sEield, CA 9~508 CITY, ZZ~: B~ke~sEield, CA 95~06 STANDARD IND. C~ASS COD~:_ 87S4 NAM~ O~ ~HZS ~ACZ~ZTY: * Pierce RS. Trans Type ~ax Average Annual ~e~sure ConC C~C C~ Use ~ by Names of ~ix:ure/Comoonen~s C~e Code AmC Am~ ~s~ Units lyre Press iemp Co0e ~t See instructions Health ~--~ Reactivity L--~ Sudden Release of Pressure on Site u---- = Health ~ Fi~e ~-- ~ ~layed Heakh C.k.S. Numbe~ ..... Z_ ~ Reactivity ~--~ Sudden Release of P~essu~e on Site ~-- ~ ~u Reactivity u--o Sudden Release of P~essure ~ S~e .... ~2 Dan Schultz Lab Hanag~_~ .................... 589-9625 Centifica~ion ,(Read and sJ~n af~el' completJnK all sections) cehtffy under penahy of law t~t I ~ve ~rs~ally examin~ and am familiar wi:h ~he information sub~d ~n this and all at:ached documents, and ~ ~f-~-6ff~i~; d~e o[ owner/opera,or u~ o.ner/oper~:or s au~r~zeo eepresen~a:we ~re ~ ua:e ~gneo Farm and Agricultune '--J ICER.N CO~TY HAZARDOUS MATERI ALS I NVENTO RY r--~ DUN ~ND 8RADSTR~ Standard Business u [ J 06-667-6222 LOCATION: .4100 Rierc~ Road ADDRESS: CITY, ZIP: Bakersfield, CA 93308 CITY, ZIP: Bakersfield, . CA 95506 PHONE ~: (80S1 527~_4911 . PHONE STANDARD IND. CLASS , CODE :_ 873~ NAME OF THIS FACILITY: P~rce Rd. ~F~R. TO INSTRUCTIONS FOR PROPER CODES- 1 2 3 ~ 5 6 1 Trans. Type Max Average Annual ~e~sure C~t C~t Cont Use ~ by Naees of ~ixture/Comoonen~s Code Code Aat A~t Est Units Type Press ]emp Code ~t See Ins~ruc:ions Health .......... ~--'~ F~re ~--~ Delayed Health C.A.S. Number .... r--q r-~ 13): Days ~--~ Reactivity ~--~ Sudden Release of Pressure on Si:e u~J Immediate / Heakh ..................................... r ............... [~ Fire a--~ ~layed H~alth C.A.S. Number ~--~ Reactivity a--~ Sudden Release of Pressure on Site ~- Health ............. ~--~ Fire ~-- ~ Delayed Health C.A.S. Number ............................ ~--~ Reactivity ~--~ Sudden Release of Pressure on Site EM:RGENCY CONTACTS ~ .T .T ~1 ;n ' ~2 Dan Schultz Lab Manager 589-9625 'Certifica~i~ (Read and sJEn al[em comp3e~JnE a]3 secrions/ certify under penalty of ]a~ t~t ] ~ve ~rs~a]]y examin~ and am familiar with the information inquiry or--se ~ndfv~due~s aes~s~61, for ob,aining the informetfon, ] be~eve ~-~B-6[[~aT-[{[T~'6['ow~er~perator~ner~6perator s aut~ zed epese tatlv~'~~ ........................ ~'5~'~ Farm an~ ~ricuhure ~-~ KERN COUNTY FI~E DEPARTMENT HAZARDOUS MATERIALS INVENTORY Standard Business u ~ ~ " ,,, 06-66?-6222 . B~SINESS NAME: B.C. Laboratories, Inc. OWNER NAME:. .T..T~ LOCATION: 4100 Pierce Road ADDRESS: ~617 ~ed]~ Dr. CITY, ZIP: Bakersfield, CA 95308 CITY, ZIP: Bakersfield, CA 95506 STANDARD IND. CLASS CODE:_ 8754. . NAME OF THIS FACILITY: Pierce Rd. ~FER TO INSTRUCTIONS FOR PROPER CODES T~ans Type Max Aveeage Annual Measure Cont Cont Cont Use % by Names of M~x~uee/Components Code Code Am~ Am~ [st Un4ts ]FOe P~ess ]emp Code Nt See Health ~ -- ~ Fire ~-- ~ Delayed Hea]th C.A.S. Number r :--J Reactivity c--J Sudden Release of Pressure on Site ~----~ . FiPe u--~ Oelayed Health C.A.S. Numbe~ ..... ~_ ...... ~_a Reactivity u_J Sudden Release of Pressure on Site ----~ ~J Immediate ~ ....... Health L~J Fire u-- j Delayed Health C.A.S. Number__ff.~_~L~ ........ L--~ Reactivity u--J'Sudden Release of Pressure on Site c .... I~ Dan Schultz Lab Manager 589-9625 Certification {Read and ~Ygn a~te~ compJetY~g aJ1 I centify under penalty o~ law t~t I have ~rs~ally examin~ and am familiar with the information sub~d in this and ell attach~ d~uments, and tMt bas~ ~ my inquiry o{~se individuals res~nsible for obtaining the information, I believe that t~bmitted ~orma~true~ accuse, and complete. _ rN..l Farm and Agriculture '-- ~ KERN COUNTY F~i~ DEPARTHENT HAZARDOUS MATERI ALS INVENT O RY Standard Business u ~ ~ 06-667-6222 ~USZN~SS ~AN~: .B.C. Labor. arouSes. ~nc. ONN~R ~AN~: ,T~.T~ ~OOATZO~: 4100 ~e~ce Road ADDRESS: R~? ~d[~ D~, . OZTY, ZZ~: Bakersfield, CA 93308 CITY, g~2: Bakersfield, CA 9~06 PHONE ~:_ _ [805] 32Y,49.11 PHONE ~ :_.. (805) 871-~7 ~ Page _~.. of .~ STANDARD IND. CLASS CODE:_ 873~ _ NAME 0F THIS FACILITY: P~¢rce Rd. ~F~R TO ~NSTRUCTIONS FOR PROPER CODES .................................. 1 2 3 ~ 5 $ 7 8 g 10 ~1 Trans Type Hax Average Annual Me~sure Cont Cont Cont Use % by Names of ~ix~ure/Components C~e Code Amt Amt Est Units ]yOe Press ]emp Code ~t See Instructions Hea~th u_J Fire ~--J Delayed Health C.A.S. Number ........................... r--n r--n 13) ~ Oay~ i ~--~ Reactivit~ ~--~ Sudden Re]ease of Pressure on Site / ~-- J Immediate Health c~J Fire ~--~ Oe~a~ed Health C.A.S. Number ....... ~--~ Reactivity u--~ Sudden Re]ease of PressuPe on S~te Hem)th '- . ....... u_~ Fi,e u_ ~ Delayed Health C.A.S. Number ...... .~__ 5_ ............ r----~ r--q r--n 13) ~ Days )~1 ~--~ Reactivity ~--J Sudden Release of Pressure on Site ~ ..~r. ............................ ~t'~r-~ E~ERGENCY C~IACIS 1 ~t ~e )2 Dan Schuitz . ~.Q~_.~9~ ~ .................... 589-9625 R~ ....................... 7-~ ....................... i~: ~e . . )I-R~'P~ ............ Certification (Read and sYRn after cospJe~YnE aJ3 sect3ons) J~..~((. ,,.~.r oenaltv of law t~t ] ~ve m~s~ally examin~ and am familiar with the infoPmation subm~d in this and al~ attach~ documents, and t~t bas~ n~j~;~-~se~indiv~duals responsible for obtainin'9 the informadon, ] believe t~t t~bmi~ted ~o~a~true~ ecrus'4, and c~plete. ~ ~ / N~E~o-6FF~EEa~'t~EI~-6F ow6er/operat6' oE ~ner~FSE6F ~'$OE~FE{~'F~FE~E~EE;~ ............... ~ ....................... D~E('S~ .... Farm and Agricuhune ~----~ KERN COUNTY FIRE DEPARTMENT HAZARDOUS MATERI ALS INVENTORY r--'~ DUI~ ~N[~ 8RAOSTR[EI Standard Business u ~ J 06-667-6222 BUSINESS NAME:' B.C. Labo~atories~ Inc. OWNER NAME: 3_3_ ~g]in LOCATION:. 4100 Pierc¢ 9cad ADDRESS: , ~17 Red!~ CITY, ZIP: Bakersfield, CA 9530~ CITY, ZIP: Bakersfield, CA 93306 PHONE ~ :_ -' (805] 5.23-4911. . . PHONE · :. (805~ 87~-~A7 ..... Page .~_. of _(~. STANDARD IND. CLASS. CODE:_. 8734 _ NAME OF THIS FACILITY: Pierce ~FER TO INSTRUCTIONS FOR PROPER CODES .......................... 1 2 3 4 5 6 ? 8 9 10 il 12 Trans Type Nax Average Annual fleasure Cent Cent Cent Use % by Names of Nixcure/Componenrs Code Code Amt Amt Est Units lype Press lamp Code Wt See instructions. Heahh u_u Fire u_u OelaFed Health C.A.S. Number ............... 5 .......... u--~ Reactivity u_u Sudden Re]ease of P~essu~e on SSte ---- .._,~ / J' / u_~ Immediate --~6'/' d3cV43~ [~] ~eact~v~y =_u Sudden Ee]ease o{ P~essu~e on 5~te =---- ~ ......................... Health c--J Fire =- j Delayed Health C.A.S. Number · r--n r--~ 13) ~ Days i~-I ~_u Reactivity ~--J Sudden Release of Pressure on Site ~----~ EMERGENCY ~NIACTS ~lRamej.j. ~1~: .................................. Ti~r. ............................ ......... IVRr-P~e ......... ,2 Dan Schultz Lab Manager 589-9625 ....................... . ................. ........ ................................ ............ _ C~t~ficati~ (Read and s3gn after cospletJng ~3~ sections) I ceetifv ~der ~enaltv of 1.~ tMt I My, ~e,~ally exam~n~ ~nd a~ fam~li~e w~th the infoe.ation ,ub~ ~n thi~ an~ ~11 ~tt~ch~ inquiry ~ee indiv{dual~ res~nsible for obtaining the informeri~, I believe that th~bmitte6 ~on~~true, eccu~t~, and c~plete. ~g~[-~6~'6U~E~,VH[~['6~ o.6ertoperat6F 0~ ~ner76~F[[6F i'~6[~F{i6~'F[[F[[66[~{~~ ................ ~ ....................... 6~'5~66~ .... 7" SECTION 3: EXPLAIN WHAT PRIVATE FIRE PROTECTION SYSTEMS A~E IN PLACE IN THIS AREA OR BUILDING THAT MAY ASSIST EMERGENCY RESPONDERS. Hand operated.fire extinguishers handy to all locations. SECTION 4: LIST THE LOCATION OF ANY WATER SUPPLIES IN THIS A~HA OR BUILDING THAT MAY BE USED BY EMERGENCY RESPONDERS. Fire hydrants at north and south ends of alley. SECTION 5: LIST THE UTILITY SHUTOFF LOCATIONS THAT CONTROL THIS PARTICULAR AREA OR BUILDING. A. NATURAL GAS/PROPANE: South Side ba~k yard next ot fence. B. ELECTRICAL: South side back of building,. C: WATER: SOU~h ~ide ba~k ¥~rd next to fence. D. SPECIAL/OTHER: E. LOCK BOX IN AREA? YES ~NOD (CIRCLE ONE) LOCATION: CONTENTS: , , (805) 861-276! I DO NOT WRITE IN THIS BOX I BUSINESS PLAN ADDI TI ONAL AREA DETAILS FORM This form is used as a supplement to Form 2 and is required when directed by the administering agency and/or the business consists of several buildings or a large geographic area. Name of this area or subdivision .Union Ave. This is Area # 1 of a total of 2 areas or buildings SECTION 1: EXPLAIN WHAT PREVENTION, MINIMIZATION, AND CLE~iNUP PROCEDURES YOUR EMERGENCY PLAN INCLUDES FOR THIS AREA OR BUILDING. INCLUDE A DESCRIPTION OF MONITORING EQUIPMENT AND PROCEDURES. 'Prevention: Ail high pressure gas tanks are chained. Acids and. solvents are stored in proper containers wfth proper labels. Oxidizers are isolated, employees are trained in proper handling of materials. Minimization: Take action and precaution so that further complications do not arise as a result of the initial spill or emergency situration. Clean-Up: Use of Hazardous Material Emergency Spill Kits installed at the facility. Evacuation procedures taught to employees. SECTION 2: EXPLAIN THE NOTIFICATION METHOD AND EVACUATION PROCEDURES YOU HAVE DEVELOPED FOR THE EMPLOYEES THAT , WORK IN THIS AREA OR BUILDING. All exits are properly marked with visible signs. All emplyees have been informed to use the nearest of three (3) exits. Phone 911 to describe nature of problem and request help. Depending on the nature of the problem and its severity, neigh- boring businesses, Valley Decal and Dean Clark Electric, and the houses across the alley would be informed to evacuate their premises. - CONTINUED ON REVERSE - (l) sEcTION 9: EXPLAIN ~ PRIVATE FIRE PROTECTION ;TEMS ARE IN PLACE THAT MAY ASSIST EMERGENCY RESPONDERS. SECTION 10: LIST THE LOCATION OF ANY WATER SUPPLIES THAT MAY BE USED BY EMERGENCY RESPONDERS. I, ~ .-~.-~O/~F. , certify that the information' submitted on all the business plan forms is accurate and complete. I understand that this information will be used to fulfill my obligations under Galifornia Health and Safety Code Division 20 Chapter 6.95 et seq. and Title 42 U.S.G.C. Section 1100 et seq. and false information may be punishable by fine, imprisonment, or both. (5) · / .--.-J (805) 861-2761 , OCT 1 I 1989 I DO NOT WRITE IN THIS BOX I ~-/AZ ARD O U S MATERI ALS BUS I NESS PLAN For~ Due S~: OCT 1 0 1989 SECTION 1: BUSINESS IDENTIFICATION DATA A. FULL LEGAL BUSINESS NAME: B.C. 4~boratorie.s, Inc.. B. PHYSICAL LOCATION/STREET ADDRESS: 4100 Pierce Rd. CITY: Bakersfield ZIP: 95308 BUS. PHONE: ( 805 ) 327-4911 C. MAILING ADDRESS: 4100 Pierce Road CITY: Bakersfield ZIP: 93308 D. HAVE YOU FILED A BUSINESS PLAN WITH THE DEPARTMENT UNDER A DIFFER~.NT NAME WITHIN THE LAST TWO YEARS? YES NO X IF YES, UNDER ~HAT NAME DID YOU' FILE? E. THIS SUBMISSION IS A NEW OR REVISED X BUSINESS PLAN SECTION 2: EMERGENC~ NOTIFICATIONS In the event of an emergency involving the release or threatened release of a hazardous material, telephone 9-1-1 and then (800) 852-7550 or (916) 427-4341. This will notify your local fire department and the State Office of Emergency Services as required by State law. Additional Federal reports may be required. PERSONS WHO SHOULD BE NOTIFIED IN GASE OF EMERGENCY AT YOUR BUSINESS THAT HAVE FULL ACCESS AND CAN PROVIDE TECHNIGAL ASSISTANCE: NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS. A. J.J. E~lin - Owner Ph# 327-4911 , Ph# ~7]-~7~7 B. Dan Shultz- I,ah Mana~e~ Ph# ~77-4qll Ph# - CONTINUED ON REVERSE - '(1) SECTION~3: L0c~TION OF THE MAIN UTILITY SHUTOFFS FOR THE ENTIRE BUSINESS A. NATYGAS/PROPANE: North Front Side on Outside of Building. B. ELECTRICAL: North Front Side on Outside of Building C. WATER: Nn~th Frout Side on Outside o~ Building. D. SPECIAL/OTHER: ~ntt~ed Ga~ Man4fold Shut Off - North Front Side' on Outside E. LOCK BOX: ~ES~O)) IF YES, LOCATION: IF YES, DOES I~ CONTAIN SIT~ PLANS7 YES / NO MSDS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO SECTION 4: PRIVATE RESPONSE TEAM DESCRIPTION Do you have a group of employees trained to handle minor accidents involving hazardous materials at your business? Yes X No__ If so, you must exPlain the level of training and equipment they possess and how they are notified to respond. Lab Manager, Dan Shultz and owner, Joe £glin. Both have lengthy experience in the handlin§ of hazardous materials. Spill kits are available as well as overhead emergency showers and eye wash stations. SECTION 5: IDENTIFICATION OF THE CLOSEST APPROPRIATE EMERGENCY MEDICAL ASSISTANCE AVAILABLE TO YOUR BUSINESS #! B~ker~fi eld Memorial #2 Mercy ,Ho.spital ADDRESS: 420 - 34th Str~t 2215 Truxtun Ave. CITY: _ B~ker~ F4 eld ..... Bakersfield PHONE: (RO5 ) 327-1792 PHONE: ( 805 ) 328-5275 COMMENTS/ADDITIONAL INFO: Eye wash stations, emergency showers, fire blanket and first aid kits are located on the premises. - CONTINUED ON NEXT PAGE - (~) "~.~.~~~~ UN,T£O STATES ENVIRONMENTAL PROTECT,ON AGENCY 75 Hawthorne Street '~ San Francisco, Ca. 94105 LETTER OF INTRODUCTION .July 9, 1993 Mr. Joe Eglin Mr. Dan Shultz BC Laboratories 4100 Arias Court Bakersfield, CA 93308 W.O. No. 04900-003-025-0002-01 Document'Control No. 04900-003-025-0002-AAAA Dear Mr. Eglin and Mr. Shultz: This letter is to certify that Steve D. Ball, Jr.', of Roy F. Weston, Inc. (WESTO~, whose signature, photograph and physical description appear below, is a duly designated representative of the U.S. Environmental Protection Agency (EPA). Pursuant to applicable provisionS of Section. 104 of the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) of 1980, 42 U.S.C. Section 9604, as amended; Section 9 of the Federal Insecticide, Fungicide, and Rodenticide Act; the Clean Water Act, EPA requests that, upon presentation of this letter, this duly designated representativ~ be allowed to: A. Enter any facility maintained by a person where any hazardous substance, pollutant Or contaminant may have been or may be generated, stored, treated, disposed of or transported from; B. Collect samples from your facility of any hazardous substance, pollutant or contaminant and any container or place where any hazardous substance, pollutant or contaminant may have been or may be generated, stored, treated, disposed of, or transported from; C. Have access to and copy all records relating to (1) any materials which have been or are generated, treated, stored, disposed of, or transported from the property; and (2) your ability to pay for or to perform a cleanup; D. Determine compliance with any effluent limitation or 6ther limitation, prohibition or ..r. effluent standard, pretreatment standard, standard of performance, levels of p.erfOrmance, sanitary landfill criteria, standards applicable to waste generators, transporters and owners and operators of hazardous waste treatment, storage and disposal facilities, or other standards, or any permit, compliance order or court order issued pursuant to the Resource Conversation and .Recovery Act (RCRA); Printed on Recycled Paptt% 5'I'}~SINTRO LTR~.WI~ Mr. Joe Eglin and Mr. Dan Shultz July 9, 1993 BC Laboratories 'Page 2 E. Talk to employees concerning waste management practices. please see Attachment A for important information regarding confidential business information. Thank you for your anticipated cooperation in this matter. Weight: 180 lbs. Color of Eyes: Brown Color of Hair: Brown Date of Birth: 12/7/67 Expiration Date: De~ember 31, Designating Authority: --' Donald C. White Chief, Field Operations Branch Hazardous Waste Management Division cc: Sherry Nikzat - EPA Project Officer Wenona Garside - EPA Contracting Officer Frank Monahan - WESTON Paul Sundberg - WESTON Joe Demmler - WESTON CERCLA FILE ~'TIGINTRO LTRk?.~Y'z. AAAA.WP 83 WEST MARCH LANE SUITE 12 STOCKTON, CA 95207 PHONE: (209) 476-1635 SITE VISIT CONFIRMATION LETTER July 9, 1993 Mr. Joe Eglin Mr. Dan Shultz BC Laboratories 4100 Atlas Court Bakersfield, CA 93308 W.O. No. 04900-003'-025-0002-01 Document Control No. 04900-003-025-0002-AAAB Dear Mr. Eglin and Mr. Shult. z: ROY F. WESTON, INC. (WESTON) is currently a contractor to the U.S. Environmental Protection Agency (EPA) under EPA Contact No. 68-W9-0046. Pursuant to Section ~104 of the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA or Superfund), as amended by the Superfund Amendments and Re. authorization Act.of 1986 (SARA), and Section 3007 of the Resource Conservation and Recovery Act of 1986 (RCRA), as amended by the Hazardous and Solid Waste Amendments of 1984 (HSWA), EPA is conducting a nationwide inventory and sc. reening of sites and facilities where hazardous substances may be located. Under the contractual relationship with EPA', WESTON is responsible for assisting EPA in identifying and investigating such potential sites. Enclosed is a Letter of Introduction duly designating WESTON to perform such work on behalf of EPA. BC Laboratories (BCL) has been listed on EPA's inventory of Potential hazardous substance sites. EPA has requested that WESTON conduct a Preliminary Assessment (PA) of the BCL site located at 4100 Pierce Road, Bakersfield, Kern' County, California, 93308. A .significant aspect of the investigation involves a meeting with BCL representatives followed by a tour of the facility. As part of the PA, an on-site inspection will be conducted to obtain information about current and historical practices at the' site. The on-site inspection will include a meeting with BCL representatives or,your consultants folloWed by a walk-through tour of the site. Pursuant to applicable provisions of Section 104 of CERCLA; Section 3007 of the Resource -Conservation and Recovery Act (RCRA); Section 9 of the Federal Insecticide, Fungicide, and Rodenticide Act; Section 3 of the Toxic Substances Control Act; and Section 308 of the Clean- Water Act, EPA hereby requests that you make the following documents available to WESTON at the time of the facility tour: 5TKL~A LTR$ OF IN'~RO~.WP Mr. Joe Eglin' and Mr. Dan Shultz July 9,. 1993 BC Laboratories Page 2 * Information regarding the ownership and operational history of the site. * Site plans, facility maps, and historical aerial photographs, if available, showing the locations of any hazardous substances, pollutant or contaminant, management activities, wells, buildings, drainage, and any. other relevant features. * List of all hazardous substances, p°llutants or contaminants generated, stored, treated, disposed of at or transported from the facility; include dates and amounts, if known. Description Of past and present waste management practices, including on-site generation,' storage, treatment, disposal, or removal of hazardoUS substances, pollutants, or contaminants. * Description of all on-site hazardous substance, pollutant or contaminant storage, treatment or disposal areas, including size, containment features, dates used, and amounts of materials stored, treated or disposed of. ' * Description of any releases of hazardous substances to the environment. Include dates and regulatory agency .response to the releases, if any. * Description of any enVironmental or public health regulatory or enforcement agency involvement at your facility. Description of all federal, state, and local permits held by the facility. Include permit number,, issuance and expiration dates. Also 'describe any occurrence of noncompliance with these permits. Please also See Attachment A to the accompanying letter for important information on confidential business information. If you wish to comment on the confidentiality of the information requested or EPA's release of such confidential information to WESTON, youI must do so in writing' within 5 days from your receipt of this letter. Submit any such comments to: Thomas A. Mix Chief, Site Evaluation Section (H-8-1) EnvirOnmental Protection Agency 75 Hawthorne Street San Francisco, CA 94105 In the near future, I will be contacting you to set up the time and date for our site.visit. ~I'K~PA LTR$ OF INTRO~..502.&,a,.AB.W'P Mr. Joe'Eglin and Mr. Dan Shultz July 9, 1993 BC Laboratories Page 2 Information regarding the ownership and operational history of the site. Site plans, facility maps, and historical aerial photographs, if'available, showing the locations of any hazardous substances, pollutant or contaminant, management activities,. wells, buildings, drainage, 'and any. other relevant features. List of all hazardous substances, pollutants or contaminants generated, stored, treated, disposed of at or transported from the facility; include dates and amounts, if known. 'Description Of past and present waste management practices, including on-site generation, storage, treatment, disposal, or removal of hazardous substances, pollutants, or contaminants. * Description of all on-site hazardous substance, pollutant or contaminant Storage, treatment or disposal areas, including size, containment features, dates used, and amounts of materials stored, treated or disposed of. * Description of any releases of hazardous Substances to the environment. Include dates and regulatory agency response to the releases, if any. * Description of any environmental or public health regulatory or enforcement agency involvement at your facility. * Description of all' federal, state, and local permits held by the facility. Include permit number, issuance and expiration dates. Also describe any occurrence of noncompliance with these permits. Please also see Attachment A to the accompanying letter for important information on confidential business information. If you wish to comment on the confidentiality of the information requested or EPA's release of such confidential information to W'ESTON, you must do so in writing within 5 days from your receipt of this letter. Submit any such comments to: Thomas A. Mix Chief, Site Evaluation Section (H-8-1) EnvirOnmental Protection Agency 75 Hawthorne Street San Francisco, CA 94105 In the near future, I will be contacting you to set up the time and date for our site visit. ~T~PA LTR~ OF [NTRO~%AB.WI~ Mr. Joe Eglin and Mr. Dan Shultz July 9,' 1993 BC .Laboratories Page 3 For the meeting and tour, I will be accompanied by one other WESTON emplOyee. Our corporate health and safety requirements may' necessitate our carrying certain air monitoring equipment with us during the facility tour. This equipment would be used to monitor our own exposure to hazardous mater/als, and will not be used to document air quality at the facility. We will also be taking pictures during the .facility tour. If you haVe any questions about the meeting and facility tour or the PA in general, you can contact me at our office in Stockton, California at (209) 476-1635, or you may contact Carolyn J. Douglas, EPA Region IX Work Assignment Manager at (415) 744-2343. Sincerely, ROY F. WESTON, INC. Steve D. Ball, Jr. PA Primary Investigator SDB/cmc ' ' cc: sherry Nikzat - EPA Project Officer Wenona Garside - EPA Contracting Officer Frank Monahan - WESTON Paul Sundberg - WESTON Joe'Demmler - WESTON CERCLA File S'I'K~A LTR$ OF [N'rRO ~L!.qO?-kA..MI.W1~ Attachment A Access to the information requested by EPA in the accompanying letter must be provided notwithstanding its possible characterization as confidential information or trade secrets. You may, if you desire, assert a confidentiality claim covering part or all of the information requested,, pursuant to CERCLA Section 104 (e) and 40.C.F.R. Section 2.203 .(b), by attaching to such information at the time EPA's duly designated representative is provided access to such information, a cover sheet, stamped or typed legend, or some other suitable form of notice employing language such as "trade secret," "proprietary," or "confidential business information." Information co,~ered by such a claim will be released by EPA or its representatives only to the extent authorized by CERCLA Section 104 (e). If no such claim accompanies the information when it is available' to the public by EPA and its representatives without further notice to you. You should read the above-cited regulations carefully before asserting a business confidentiality claim, since certain categories of information are not properly the subject of such a claim. The regulations of 40 CFR Section 2.211 preclude EPA employees from wrongfully using or disclosing any business information, that was obtained during the performance of the employee's official duties. In addition," EPA employees must take all appropriate action to safeguard business information from improper disclosure. EPA employees who violate these requirements are subject to dismissal, suspension, or fines. Criminal action may be taken against EPA employees who 'willfully disclose confidential business 'information. A contractor with EPA who obtains business information during execution of an EPA contract can disclose information only as allowed in the contract. EPA' regulations on confidentiality in 40 CFR Part 2 Subpart B require that the contractor agree to the clause entitled, "Treatment' of Confidential Business Information" before any confidential business information may be furnished to the Contractor. This letter serves as notice to you, pursuant to 40 C.F.R. Section 2.31.0 (h), of the contemplated disclosure by EPA 'of the information at your facility relating to (1) any materials which have been or are generated, treated, stored, disposed of, or transported form the facility, and (2) your ability to pay for or to perform a cleanup. EPA plans to disclose'this information to WESTON/68-W9-0046; this disclosure is necessary in order for WESTON tO carry out the inspection of your facility, including document review and copying. Pursuant to 40 C.F.R. Section 2.310 (h), you may .submit comments.to EPA on EPA's disclosure of confidential business information to its authorized representatives. Any comments 'on this contemplated disclosure must be submitted to EPA within 5 days of your receipt of'this letter. Submit any such comments to: Thomas A. Mix Chief, Site Evaluation Section (H-8-1) Environmental Protection Agency 75 Hawthorne Street .... San Francisco, CA 94105 Failure to submit your comments in a timely manner shall, not be cause for refusal to allow WESTON access to the requested records. ~I'KXlN'rRO LT Rk2.~IT.A.~.WI~ 0VKlgt~ BAKERSFIELD CITY FIRE DEPARTMENT .D. # FORM 4A-1 Page 2 .o[ 2. NON--TRADE SECRETS HAZARDOUS MATERT AY..S T NVENTORY BUSINESS NAME: B. C. LABORATORIES; INC. OWNER NAME: J. J. EC.I.TN FACILITY UNIT ADDRESS: 4100 PIERCE ROAD ADDRESS: 3617 REDI,AND.R DRIVE FACILITY UNIT NAME: MAIN LAB. CITY, ZIP: B~AKERSFIELD, CA 93308 CITY,ZIP: I~AWER.~T~.I.n_ CA q~n~ · , PHONE #: 327-4911 PHONE #: 871-O747 ' , [OFFICIALONLY USE CFIRS .... CODE 1 2 3 4 5 6 ? 8 9 10 'YPE MAX ANNUAL CONT USE LOCATION IN THIS ~ BY HAZARD D.O.T ' :ODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMI(~AL OR COMMON NAME CODE GUIDE. P 1/4 1/2 GAL 09 99 WET LAB. CABINET 98 PHOSPHORIC ACID CRMT ~ 2 2 GAL 09 99 BACK CENTER NORTH 98 PHOSPHORIC ACID CRMT P 1/2 I GAL 09 99 " " " 96 SULFURIC ACID CRMT P 1- 1/2 2 GAL 09 99 " " " I00 AMMONIUM HYDROXIDE ORMA P 1/2 I GAL 09 99 " " " 40 HYDROCHLORIC ACID CRMT P 1 I GAL 09 99 " " " 100 GLUCONIC ACID ORMA P 1/2 1 GAL 09 99 " " " I00 'ACETIC ACID ORMA P I I I I LBS 09 99 " " " 100 MAGNESIUM CHLORIDE ORMA P 25 25 LBS 11 99 " " " 100 SODIUM SULFATE ~. OXID .~ 25 25 LBS ' I I 99 " "' " 100 BORIC ACID ORMA P 25 25 LBS 11 99 " " " 100 CATION EXCHANGE RESIN ~ CMSL P 25 25 LBS 1t 99 " " " I00 SODIUM ACETATE ORMA P 3 3 LBS 11 99 " " " I00 SODIUM HYDROXIDE PELLETS OXID P 25 25 LBS I I 99 " ,, ,, I00 CITRIC ACID P 25 25 LBS 11 99 ' " " " I00 POTASSIUM CAILBONATE ORMA NA~ME: F.J. BEESLEY TITLE:SAFETY (~O-ORDINA~'OR.S-ONATURE: ' DATE:Jnly q-lq~7 EMERGENCY CONTACT: J. J. EGLIN TITLE: OWNIng PHONE · BUS HOURS: 327-491 ! AFTER BUS HRS: 87 !-0747 EM~ERGENCY CONTACT: DAN SCHULTZ TITLE: LAR 'NANAC. F.R PHONE # BUS HOURS: 327-~911 PRINCIPAL BUSINESS ACTIVITY: ~NALYTICAL LABORATO]~Y AFTER BUS ltRS: 589-9625 BAKERSFIELD CITY FIRE DEPARTMENT .D. # FORM 4A-1 Page I :of ~ .. NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY BUSINESS NAME: B. C. LABORATORIES; INC. OWNER NAME: J. J.F.C.I.TN FACILITY UNIT ADDRESS: 4100 PIERCE ROAD ADDRESS: 3617 REDLANDg DRTVF. FACILITY UNIT NAME: MAIN LAB. CITY, ZIP: BAKERSFIELD, GA 93308 CITY,ZIP: BAWERgFTF. LD. CA q'~mR , 327-49 1 P.ONE #: ' ,.,[OFFICIAL USE CFIRS ] 2 8 4 5 ~ ? 8 9 10 YPE MAX ANNUAL CONT USE LOCATION IN THIS ~ BY HAZARD D.O.T ' ODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE GUIDE. P 29 58 GAL 09 99 :OUTSIDE STORAGE SHED 96 SULFURIC. ACID CRMT P~O' 32 64 GAL 09 99 " " " 40 ~IYDROCHLORIC ACID CRMT P 45 90 GAL 09 99 " " " 70 NITRIC ACID OXID P 2 5 GAL 09 99 " " " 100 ~CETIC ACID PSNB P 4 8' GAL 09 99 " " " 100 kMMONIUM HYDROXIDE ORMA P 13 20 GAll, 09 99 " " " 100 METHANOL FLLQ P 3 5 GAL 09 · 99 " " " 100 PERCHLORIC ACID CRMT P 200 300 LBS 09 99 " " " 100 SODA ASH . CRMT P ]5 35 GAL 07 99 OUTSIDE BACK YARD 93 SULFURIC ACID REAGENT / CRMT ~ 6 6 GAL 07 99 BACK ATTACHED S_~R~ 93 SULFURIC ACID REAGENT - CRMT P 25 25 LBS 06 99 " " " IO0 SODIUM HYDROXIDE ~ OXID P 2 2 GAL 09 '99 WET LAB CABINET 96 SULFURIC ACID CRMT P 3 3 GAL 09 99 " " " 70 NITRIC ACID OXID P I I GAL 09 99 " " " 100 ACETIC ACID ,~ PSNB P l/2 I GAL 09 99 ' "' " " 100 HYDROFLUORIC ACID CRMT ~A~E: F.J. BEESLEY TITLE:SAFETY ~O-ORDINA~OR.S ONATURE: ~ DATE:July 9~1987 ~MERGENCY CONTACT: J. J. EGLIN TITLE: OWN~ PHONE ~ BUS HOURS: 327-49ll AFTER BUS HRS: 87]-0747 ~MERGENCY CONTACT: DAN SCHULTZ TITLE: 1.AR 'MANAO. F.R PHONE # BUS HOURS: 327-491! ?RINCIPAL BUSINESS ACTIVITY: ANALYTICAL LABORATOI%Y AFTER BUS HRS: 589-9625 ~ - 4A-I - ACUTELY HAZARDOUS MATERIALS REG J TRATION FORM THIS FORM MUST BE COMPLETED BY THE OWNER OR OPERATOR OF EACH BUSINESS IN CALIFORNIA WHICH AT ANY TIME HANDLES ANY ACUTELY HAZARDOUS MATERIAL IN QU ,ANTITIES GREATER THAN 500 POUNDS, 55 GALLONS OR 200 CUBIC FEET OF GAS AT STP. I THIS FORM SHALL BE COMPLETED AND SUBMITFED TO YOUR LOCAL ADMINISTERING AGENCY. (§25533 & 25536 Health & Safemf Code) NOte instructions on reverse J~AR 2 8 1988 Business Name B C Laboratories, ;Inc. All$'d ........ Business Site Address® Pierce Road, Bakers£ield, CA 93308 4100 Pierce Road, Bakers£ield, CA 93308 Business Mailing Address (if different) Business Phone (805) 327-4911 Business Plan Submission Date2 July 15, 1987 Process Designation3 A(;I,ITE~,Y HAZARDOUS MATERIALS HANDLED4 -USE ADDITIONAL PAGES IF NECESSARY- CHEMICAL NAME QUANTITY See attached (~ENERAL DESCRIPTION OF PROCESSES AND PRIN(;IPA~ EQUIPMENTS: Analytical Laboratory SIGNATURE ~. ~..~"~.,~,_5 TITLE PreSident PRINTED NAME ~ J'~J' Eglin DATE March 23, 1988 California Office of Emergency Services FORM HM 3777 (1-15-88) · INSTRUCTIONS: Superscripts: 1. ~Quantities for RMPP compliance are "equal to or greater than" thc minimum criteria and apply to chemicals handled ,"at any one time". 2. Businesses handling reportable quantifies of Acutely Hazardous Materials that have not submitted a business plan MUST contact local Administering Agencies. The business plan submission date will assure the Administering Agency that a business plan has been submitted and is on t-de. This will also immediately identify businesses that have not submitted business plans. 3. "Process Designation" is provided as a reporting option(with the approval of the Administering Agency) for facilities that can most easily report by process. Thus, facility RMPP registration data could be submitted in a similar format to a business plan that is divided by process. "By process".data can initiate an emergency response to a process incident rather than a general emergency response to a major facility. Process designation can s~p-~-~fy ~-si~ec~[ions-f6r~j~ti~-~zFim~rove future emergency response. ~ -~_ .... - 4. Refer to the EPA list'of Exuemely Hazardous Substances from the Federal Register (Volume 52, No. 77, p. 13397 et. sea_., April 22, 1987). Each chemical has a threshold planning quantity. This list may be changed by EPA on an annual basis. Updates of this list may be available early in 1988. To comply with this element, you may attach a copy of the inventory submitted to your Administering Agency from your business plan and highlight all Acutely Hazardous Materials. It is recommended that facilities list all exlremely hs?ardous chemicals handled in quantities equal to or in excess of 1) 500 pounds, and 2) any EPA threshold planning quantity less than 500 pounds. 5. Do not include Trade Secret information in these clescriptions. General: For emergency response purpose, s, it would be desirable to describe the following to the Administering Agency: 1. Batch Process: a. What raw materials? b. What operating pressure range? c. What operating tem~ range? d. Batch capacity rating? e. Product characteristics? (e.g., chemical state, flammability, toxicity, etc.) f. Critical process points and characteristics? .... 2: Continuous process:-(similar information as-above;) .... ~ _. ~ ............ .. NOTE: "Pursuant to §25534, the Administering Agency may require the submission of a Risk/Vmnagement Prevention Program (R]V~P), if the Administering Agency deteannines that the handler's opca-ation may present an acutely hazardous materials accident risk. The handler shall prepare the RMPP in accordance with subdivision (c) [of §25534]. The RMPP shall be prepared within 12 months following the request made by the Administering Agency pursuant to this section." (§ 25534 (a) Health and Safety Code) An amendment to the RMPP must be submiued to the Administering Agency within 30 days of: 1; Any additional handling of acutely hazarcious materials. 2. Any material or substantial alterations t~ business activities. 3. Change of address, business ownership, or business name. (§ 25533 (c) Health & Safety Code) · EVERY BUSINESS REQUIRED TO SUBMIT AN RMPP SHALL IMPLEMENT THE APPROVED RMPP · California Office of Emergency Services FORM HM 3777 (1-15-88) BAKERSFIELD CITY FIRE DEPARTMENT I.D. # FORM 4A-1 Page I .of NON--TRADE SECRETS HAZARDOUS I~IATER I ALS '~' NVENTORY BUSINESS NAME:.B.C. LABORATORIES. INQ, OWNER NAME: J. J. EC.I,TN FACILITY UNIT #: ADDRESS: 4100 PIERCE gO~ ADDRESS: 3617 ~DI.ANDS DRIVE FACILITY UNIT NAME: ~IN LAB. CITY, ZIP :..~ERSFIELD, ~A 93308 CITY, ZIP: ~A~ERRFTELD: CA PHONE ~: -327-4911 PHONE ~: R71-~747 [OFFICIAL USE CFIRS CODE ONLY 1 2 3 4 5 6 7 8 9 10 TYPE ~AX, ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.0.T CODE ANOUNT ,ANOUNT UNIT CODE CODE FACILITY UNIT ~T. CHENIqAL 0R CONNON NANE CODE GUID~ P 29 5S G~ 09 99 OUTSIDE STOOGE SHED 96 S'~F~.C-> ACID % [ ~ C~T -- 90 G~ 09 99 " " " 70 NITRIC ACID P . /2~ 5 G~ 09 99 " " " 100 ACETIC ACID ~sNB '. P 8 GAL 09 99 " ,, ,, 100 ~ONI~ HYDROXIDE :0~~ ~ "~ 20 G~ 09 99 P P ~ 5 GAL 09 99 " " " 100 PERCHLORIC ACID C~T P 200 300 LBS 09 99 " " " 100 SODA ASH C~T P 15~' 35 GAL 07 99 OUTSIDE BACK YA~ 93 'SU~E~'R~C'~'~'ACID ~AGENT C~T p 6' 6 G~ 'Q~.~ 99 BACK ATTACHED SHED 93 SULF~URIC'% ACID REAGENT C~T~ ~ 25 LBS 06 99 " " " 100 SODI~ HYDROXIDE OXID P 2 2 G~ 09 99 ~T LAB CABINET 96 ' ~C,~¢ ACID /' . P 3 3 G~ 09 99 " " " 70 NITRIC ACID OXID P 1 1 G~ 09 99 " ,, ,, 100 ~ ~CETIC ACID PSNB~ ~/~2/ 1 G~ 09 99 "' " " 100 {YDROFLUORIC ACID C~T P NAME: F.J. BEESLEY TITLE:SAFETY CO-O~INATOR SIGNATURE: .~ ~ DATE:July q-~qR7 EMERGENCY CONTACT: J. J. EGLIN TITLE: O~ER PHONE ~ BUS HOURS: 327-4911 AFTER BUS HRS: 871-0747 EMERGENCY CONTACT: DAN SCH~TZ TITLE: LAR.'MANAGmR PHONE ~ BUS ROURS: 327-4911 PRINCIPAL BUSINESS ACTIVITY: AN~YTIC~ LABO~TORY "~ '' AFTER BUS HRS: 589-9625 - 4A-I - BAKERSFIELD CITY FIRE DEPARTMENT I' D ' ~ ' rF 0 ~ ~ 4A--1 Page 2 ..of NON--TRADE SECRETS HAZARDOUS MA-TERI ALS INVENTORY BUSINESS NAME: B. C. LABORATORIES; INC. OWNER NAME: J. j. ECl,IN FACILITY UNIT #: ADDRESS: 4100 PIERCE ROAD ADDRESS: 3617 REDI,ANDS DRTVE FACILITY UNIT NAME: MAIN LAB. CITY, ZIP: BAKERSFIELD. CA 93308 CITY,ZIP: BAWF. RSFIELI): CA PHONE #: 327-4911 PHONE #: 871-O747 [OFFICIAL USE CFIRS CODE ,[ ONLY , 1 2 3 4 5 6 7 8 9 10 TYPE MAX,~ ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE GUIDE P //~4 / 1/2 GAL 09 99 WET LAB CABINET 98 PHOSPHORIC ACID CP&IT P~ 2 GAL 09 99 BACK CENTER NORTH 98 PHOSPHORIC ACID CRMT P 1/2 ./-- 1 GAL 09 99 " " " 96 " S_I~LFU2iilC~'~)ACID CRMT , 1 A2 2 GALo999 " " "1oo A ONiuM YDROXIDE P 1/2 I GAL 09 99 " " " 40 t ROCHLORIC ACID CRMT P /1'~' I GAL 09 99 " " " 100 OLUCONIC ACID ORMA P 1/2 I GAL 09 99 " " " 100 .,&CETIC ACID ORMA P ~ I I LBS 09 99 " " " I00.. MAGNESIUM CHLORIDE ORMA P 25 25 LBS ' i I 99 " . ,, 100 BORIC ACID ORMA :'"', y 25 . 25 LBS 11 99 " " " 100 CATION EXCHANGE RESIN CMSL P 25 25 LBS 11 99 " " " 100 SODIUM ACETATE ORMA P 3 3 LBS 11 99 " " " 100 SODIUM HYDROXIDE PELLETS OXID P ' 25 25 LBS I I 99 " " " 100 CITRIC ACID ORMA P 25 25 LBS I ! 99 ' " " " 100 POTASSIUM CARBONATE ORMA NAME: F.J. BEESLEY TITLE:SAFETY CO-ORDINATOR S 6NATURE: ~ ~ DATE:J,,ly 0-1087 EMERGENCY CONTACT: J. J. EGLIN TITLE: OWN~I~ / --PHONE~'~ BUS HOURS: ~27-4~!1 · , AFTER BUS HRS: 871-0747 EMERGENCY CONTACT: DAN SCHULTZ TITLE: T.AR 'M~qAa~R PHONE # BUS HOURS: 327-4911 PRINCIPAL BUSINESS ACTIVITY: ANALYTICAL LABORATORY AFTER BUS HRS: 589-9625 BAKERSFIELD CITY FIRE DEPARTMENT ., I.D. # FORM 4A-1 Page 3 NON--TRADE SECRETS --i. HAZARDOUS MATERI ALS INVENTORY BUSINESS NAME: B. C. LABORATORIES.,_ ING, OWNER NAME: j. j. EC.L'[N FACILITY UNIT #: ADDRESS: 4100 PIERCE ROAD ADDRESS: 3617 REDLANDS DRTVE FACILITY UNIT NAME: MAIN LAB, CITY, ZIP: B~AKERSFIELD, CA 9~08 CITY,ZIP: BAWERSFIEI.D: CA PHONE #: 327-4911 PHONE #: 871-O747 [OFFICIAL USE CFIRS CODE I ONLY 1 2 3 4 5 6 ? 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O.T '.' C09E AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE GUIDE, P 20' 25 LBS 11 99 BACK CENTER NORTH 100 POTASSIUM CARBONATE ORMA ,.~ 40 'I 50 LBS I I 99 " " " 100 FERROUS SULFATE ORMA P 20 25 LBS I I 99 " " " 100 AMMONIUM SULFATE ORMA P 20 25 LBS I I 99 " " " 100 AMMONIUM CHLORIDE ORMA P 20 , 40 LBS I I 99 " " " 100 SODIUM BICARBONATE ORMA P 25 25 LBS I I 99 " " " 100 MAGNESIUM NITRATE OXID P 1/2 I LBS 09 99 SO. CENTER STORAGE 74 CALCIUM HYDROXIDE ORMA P 3 3 LBS I I 99 " " " 100 AMMONIUM ACETATE ORMA P 12 12 LBS I I 99 " ,, ,, 100 CITRIC 'ACID ORMA P 4 8 GAL 09 99 " " " 60 ISOPROPYL ALCOHOL FLLQ ~ I ' 'l GAL 09 99 " " " 70 ~!'NITRIC ACID OXID P 1 I GAL 09 99 " " " 96 ~ stJ~FURi~-~ ACID CRMT P 3 3 GAL 09 99 REAR STORAGE NORTH 100 METHANOL FLLQ P 5 8 GAL 13 99 " " " 100 PENTANE FLLQ P 10 18 GAL 13 99 '" " " 100 DENATURED ALCOHOL FLLQ NAME: F, J, BEESLEY TITLE:SAFETY CO-ORDINATOR SIGNATURE: .-z~--f',,/ DATE:July O-IOR7 EMERGENCY CONTACT: J. J. EGLIN TITLE: OWNER ' -PHONE'S# BUS HOURS: AFTER BUS HRS: 871-0747 EMERGENCY CONTACT: DAN SCHULTZ TITLE: 'LAB 'MA~AC,~.R .- PHONE # BUS HOURS: 327-49{{ PRINC,!PAL BUSINESS ACTIVITY: ~NALYTICAL LABORATORY AFTER BUS HRS: 589-9625 - 4A-1 - · BAKERSFIELD CITY FIRE DEPARTMENT I.D. # FORM 4A-1 Page 4 ..of '-7 ,, NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY ,, BUSINESS NAME: B. C. LABORATORIES, II~Q, OWNER NAME: J. J. EC, I,IN FACILITY UNIT #: ADDRESS: 4100 PIERCE ROAD ADDRESS: 3617 REDLAND,~ DRIVE FACILITY UNIT NAME: MAIN LAB. CITY, ZIP: B~AKERSFIELD, SA 93308 CITY,ZIP:. ~AIiER.q¥IEI.D: CA q~D6 , PHONE #: 327-4911 PHONE #: 871-0747 [OFFICIAL USE CFIRS CODE I ONLY 1 2 3 4 5 6 ? 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS ~ BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE P 10 18 GAL 13 99 REAR STORAGE NORTH 100 CHLORFORM ORMA P_.. 5 8 GAL 13 99 " " " 100 BUTYL ALCOHOL FLLQ i~'~ 2 4 GAL 13 99 " " " 100 1- 1- 1 TRICHLOALETHANE FLLQ P $ 5 GAL 13 99 " " " 100 HEXANE FLLQ P 4 6 GAL 09 99 LEAN TO STORAGE CABINET 72 ~ETHYL ETHYL KETONE FLLQ P 9 12 GAL 09 99 " " " 100 BUTYL ALCOHOL ORMA P 1 3 GAL 09 99 " " " 100 ?YRIDINE FLLQ P 3 3 GAL 09 99 " " " 100 BUTYL ACETATE FLLQ P 3 3 GAL 09 99 " " " 100 3HLOROFORM O ~..~ ~: ': P 1/2 ' I GAL '09 99 " " " 100 3ARBON DISULFIDE PSNB ~ I '2 GAL 09 99 " " " 100 .tEXANE FLLQ P 2 3 GAL 09 99 " " " 100 ERIETHLAMINE ORMA i P 1 2 GAL 09 ' 99 " " " 100 %CETONITRILE FLLQ P 2 3' GAL 09 99 " " " lO0 rRICHLORHEXANE FLLQ P 1 2 GAL 09 99 " " " 100 3ARBONTETRACHLORIDE ORMA NAME: F. J BEESLEY TITLE:SAFETY CO-ORDINATOR SIGNATURE: ~'- '~ '~ EMEROENCV CONTACT: J. J. EGLIN TITLE: OWNEI~ PHONB# BUS HOURS: 327-4911 ,, AFTER BUS HRS: 871-0747 EMERGENCY CONTACT: DAN SCHULTZ TITLE: LAB 'MA~AC.~.R .. · PHONE # BUS HOURS: 327-4911 PRINCIPAL BUSINESS ACTIVITY: ANALYTICAL LABORATORY AFTER BUS HRS: 589-9625 BAKERSFIELD CITY FIRE DEPARTMENT I.D. # FORM 4A-1 Page 5 ..of 7-- NON--TRADE SECRETS HAZARDOUS ' MATERI ALS INVENTORY BUSINESS NAME: B. C. LABORATORIES, 1NQ, OWNER NAME: J. J. EC.I.]'N FACILITY UNIT #: ADDRESS: 4100 PIERCE ROAD ADDRESS: 3617 P, EDLAND.q DRTVE FACILITY UNIT NAME: MAIN LAB. CITY, ZIP.: BAKERSFIELD, CA 93308 CITY,ZIP: BAI<ERgF]'F~I.F)_ CA q'{'{f]6 , PHONE #: "~27-4911 PHONE #: 871-O747 [OFFICIAL USE CFIRS CODE I ONLY 1 2 3 4 5 6 ? 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE P I 2 =:=GAL 09 99 LEAN::_TO STORAGE CABINET 100 HEPTANE FLLQ P..~ 2 4 GAL 09 99 " ,, ,, 100 PETROLEUM ETHER FLLQ P'~' I 2 GAL 09 99 " " " 100 CHLOROBENZINE FLLQ P I 3 GAL 09 99 " " " 100 DICHLORO 'METHANE ORMA P I 2 GAL 09 99 " " " 100 ETHYL ACETATE FLLQ P 1/2 " I GAL 09 99 " " " 96 ~ >SULFURIC ACID CRMT P 1/2 I GAL 09 99 " " " 70 ~ x.NITRIC ACED OXID P 2 24 ' FT3 04 99 FRONT INSTRUMENT ROOM 100 NITROGEN NFLG P I 2 FT3 04 99 " " " 100 OXYGEN OXID P 1 12 FT3 04 99 " ,, ,, 100 'NITROUS OXIDE NFLG '". .'.3 '; 30 FT3 04 99 " ,, ,, 100 ARGON NFLG P 1 2 FT3 04 99 CENTER SOUTH 100 COMPRESSED AIR OXID P I 10 FT3 04 99 " " 100 NITROGEN NFLG P I 8 FT3 04 99 " " 100' ACETYLENE FLGS P 3 12 FT3 04 99 CENTER INSTRUMENT ROOM 100 NITROUS OXIDE NFLG NAME: F.J. BEESLEY TITLE: SAFETY CO-ORDINATOR SIGNATURE: ~ ~z~~---~ DATE :.l,,]y 9-10R7 EMERGENCY CONTACT: J. J. EGLIN TITLE: OWNEI~ "~HONE # BUS HOURS: ~27-/~)11 ,, AFTER BUS HRS: 871-0747 EMERGENCY CONTACT: DAN SCHULTZ TITLE: I,AB 'MANAf'.~.R PHONE # BUS HOURS: 327-4911 PRINCIPAL BUSINESS ACTIVITY: ANALYTICAL LABORATORY AFTER BUS .HRS: 589-9625 " - 4A-I - BAKERSFIELD CITY FIRE DEPARTMENT I.D. # FORM 4A-1 Page 6 ..-of '?-- NON-TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY BUSINESS NAME: B. C. LABORATOR~S_. INC, OWNER NAME: J. J. EC. LIN FACILITY UNIT #: ADDRESS: 4100 PIERCE ROAD ADDRESS: 3617 REDLAND~q DRIVE FACILITY UNIT NAME: MAIN LAB, CITY, ZIP: BAKERSFIELD, CA 93308 CITY,ZIP: BAKER~qFIELD: CA PHONE ~: 327-491l PHONE #: 871-0747 {OFFICIAL USE CFIRS CODE ! ONLy 1 2 $ 4 5 6 ? 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O.T ' CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE P 2 4 ET-3-, 04% 99 BACK ROOM SOUTH 100 NITROGEN NFLG ~ .. 1' 2 FT3 '-~04f 99 " " " 100 OXYGEN OXID ~' ] ]0 FT3 '0~j 99 " " " 100 ARGON NFLG P ! .. 2 GAL 'p?' 99 LEAN TO STORAGE CABINET 100 PENTANONE ' FLLQ P ! : 2 GAL 09 99 " " "~ ]00 METHYL ACETATE AORMA P ] I GAL 09 99 WET LAB CABINET ]00 ACETONE '. ORMA P ! ] GAL 09 99 " " " ]00 TOLUENE FLLQ P I ] GAL 09 99 " " " ]00 HEXANE FLLQ P I I GAL 09 99 ,, ,, ,, 100 METHANOL FLLQ P 1 I GAL '09 99 " " " ]00 PENTANE FLLQ .~,.- 1' :. 1 GAL 09 99 " " " 100 METHYL ISOBUTYL KETONE FLLQ P ! ! GAL 09 99 " " " 100 CHLOROFORM ORMA 3~~ 830~" 36;040 FT3 04 99 OUTSIDE GAS MANIFOLD , 100 ARGON ~ NFLG sod .... . 2'40~_ ?T3 04 99 " " " ACETYLENE i~ ~ FLGS NAME F.J. BEESLEY TITLE: SAFETY CO-ORDINATOR SIGNATURE: ~~~.-~- DATE EMERGENCY CONTACT: J. J. EGLIN TITLE: OWNEg {fHON~ ~ BUS -HOURS: 327-4911 " AFTER BUS HRS: 871-0747 EMERGENCY CONTACT: DAN SCHULTZ TITLE: T.AR_'MANAC. ER .. PHONE # BUS HOURS: 327-491l PRINCIPAL BUSINESS ACTIVITY: ANALYTICAL LABORATORY AFTER BUS HRS: 589-9625 · BAKERSFIELD CITY FIRE DEPARTMENT I D # FORM 4A-1 Page 7 --of NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY ,' BUSINESS NAME: B. C. LABORATORIES~. INC. OWNER NAME: j. j. EC, LIN FACILITY UNIT #: ADDRESS: 4100 PIERCE ROAD ADDRESS: 36{7 REDLAND,q DRIVE FACILITY UNIT NAME: {Y{AIN LAB. : CITY, ZIP:_BAKERSFIELD, CA ~)3308 CITY,ZIP: BAKERSFIELD; CA PHONE #: 32'-4911 PHONE #: 871-0747 [OFFICIAL USE CFIRS CODE [ ONLY 1 2 3 4 5 6 ? 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.0.T ' CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIC~AL OR COMMON NAME CODE GUIDE. 22{ I_2801 : ..500 GAL 06 OUTSIDE BACK WASTE OIL --10{q ORME ~ 22 50 GAL 07. " " CAUSTIC WATER ORME 551 35 50 GAL 07 " " ACID WATER ORME P 25 42 GAL 06 " " ACETONE ORMA 611 75 100 LBS 06 " " CONTAMINATED SOIL ORMA NAME: F. 3. BEESLEY TITLE:SAFETY CO-ORDINATOR SIGNATURE: ~ DATE:July q-lqR7 EMEROENCY CONTACT: J. J. EGLIN TITLE: 0WNEI~ OURS: 327-491{ " AFTER BUS HRS: 871-0747 EMER~ENCY CONTACT: DAN SCHULTZ TITLE: LAR.'MANAC.~.R PHONE # BUS HOURS: 327-491{ PRINCIPAL BUSINESS ACTIVITY: ANALYTICAL LABORATORY AFTER BUS HRS: 589-9625 - 4A-I - MARCH 8, 1988 B C LABORATORIES, INC 4100 PIERCE RD BAKERSFIELD, CA 93308 DEAR SIR: THE ENCLOSED "ACUTELY HAZARDOUS MATERIALS REGISTRATION FORM" MUST BE COMPLETED BY ANY BUSINESS, HANDLING ABOVE THE MINIMUM REPORTING QUANTITY ANY MATERIAL ON THE EPA LIST OF EXTREMELY HAZARDOUS SUBSTANCES. (FED. REGISTER VOL. 52, NO. 77, P. 13397). YOUR COMPANY HAS REPORTED HANDLING THE FOLLOWING ACUTELY HAZARDOUS MATERIALS: NITRIC ACID PLEASE RETURN THE COMPLETED ACUTELY HAZARDOUS MATERIALS REGISTRATION FORM TO: HAZARDOUS MATERIALS DIVISION 2130 G STREET BAKERSFIELD, CA 93301 IF YOU HAVE ANY QUESTIONS REGARDING THIS FORM PLEASE CALL RALPH HUEY AT 326-3979. SINCERELY YOURS, RALPH E HUEY HAZARDOUS MATERIALS COORDINATOR REH:em ENCLOSURE , BORIC ACID ;'2- ~eCeria! Safety DaCe Sheet ~,.~e and Exn]osion S£CTTON 2 Emergency Telephone Number Information 3~&-982*~OU0 Fire: ~ Not' considered to be · fire hazard. ~ Nallinckrodc Inc. :j L.~..: ; Science Products Dlvlelon .... P.O. Box H · Paris. Kentucky 40361 '~' ~' · Effective Date:,,ll-27*85 Explosion: A mixture of~pOtalliUm end borio acid may explode on . . .. impact, P.~O~UCT IDENTIFIGATION~ Synonyms: ortho-~oric acid; boracic acid · - . . Fire Extinguishin[ Hedia: Uae any maann suitable for extinguishing surrounding fire, CAS No.: 100~3.3~-3 Nolecular ~elsh~: 61.82 Hazardous Ingredients: Chemical Formula: H3BO3 - · ' N0C applicable.' Special Information: In tho event of a fire. wear full p~otec~ivo . ,. clothinl and NIOSil-approved self-contained breathin~ apparatus ~ith full facepiece operated iff the pressure deu~ o~ other positive pressure mode. PRECAUTIONARY MEASURES UA~IHU{ I~L ~F SUAL~UED OR INHALED. ~Y CAUSE I~ITATION. Avoid b~ea~hin8 dus~. Ke~p conKaine~ c~osed. ~eaettvi~ DaKn SE~YON ~ Use wiCh adequate ven~ilaCion. ' ' ' Avoid con,acC wi~h eyes, skin and clothing. .. . Stability: {~able ~nde~ o=dl~=y ~ondl~lonn of use and s~orage. Uash thoroughly, a?er handling. .. .. If Misture is p~esenC, boric acid can be corrosive ,, .~ . ... to i~on. ENEEGENUY/F[RST AID Haaardous Docompool~ton If svalloved,.~nd0he vomicinB l~ediacely by given{ eve glasses o[ voter, or milk ~ ~od~s: Fo~ boron oxide when hea~ed ~o decomposition. if available and kcickin~ ginger do~ throat. Never give anychin{ by ~uch to an ~ ..... . · . unconscious person. If l~aled, remove Co f~esh air. l~ nec b~ea~hini, artificial respiration. If breachtn~ Is difficu}c, give oxygnn. In cass of concflcc, l~edia~ely flush skin or eyes with plenty og wa~er ~or ac ~easC ~5 Hazardous Pelletization: ~11~ ~ occur. minutes. In ~ cases call a physician. I · SEUTION 5J _.. Incompatibilities: ~oCassi~, acetic onhydride, a~kalies, carbonates, hydroxides. ~hysical Data " ~CTION 1 , ;, . "' Appearance; ' ~ico po~der o~ ~ranules. !~ak/Sulll Olsoosal ln~o~aCfon - ~IO~ i Odor: .No apparen~ odor. ~ .,, : VanCllaco area of lea~ or spill, flleafi-op personnel require procecciv~ ~lochio~ a~d : ': rospiraCor~ pro~eccion fr~ dust. -. ~ , : Spills: Pick up and place in a suitable container for reclamation or disposal in a ~olltn~ PoinC~ ~ecomposes. Vapor Density (Air-l):No lnfomaCion method tha~ does nec generate dus~. found. ', ' OIsposal: ~a~ever cmn~C be saved gar recl~lofl may be disposed Joo ~) RCRA Helcin~ Point: 185'C (365'F) Vapor Pressure (~ 11S):2.6 ~ 200C approved hazardous ~as~a facility. Specific Gravity: 1.~3 Evaporation Race:No ln[ormacion found. Ensure compliance with local, state a~ federal regulations. ~ Amer can Burdick & Jackson '":'... ' ":; M~terial Safety Data. . Sheet ' v. ,,..,,h ..,.,,,, ~ Ind~0e~yldeS~MWflO ~elJ-JGOO (Ame;'lca~'~clefltlfic ProdUCts)" ' MATERIAL SAFETY . :, .(~al f~posure Limits · Cbe~K~.O eOO/q~q-t300 DATA SHEET , .. toZLuUb ~o,mMm.~.s~o,uM St'--~6f"~Zs-3tT! (.Americaq e~dl'Ck S~ack~) OSHA i-~ PEb SOO ~m ~. : ~ Olchl~°~thoMt ~gthy~e~ 0I~l~l~ TLV-STEL - SOO ppm. ~le~ UNISt] , ~Sm, ~'~'] ' NIOSH TLV-TWA - 7S ~m NSC 200 ~, ~ItICM a~ C~mlcd D~ .... * . ,, TLV-C - SOO ppm %~M~M Ca ~09 ~p~l~0-t) ~ ~OoC 1.13 ~ Stable ~~~ Terat~fllc DAta ~' , ~J1~6t . Positive ~to~n (RTEC) . . MethyleM chl~i~ may exert itt effects I~ fnholotl~ skim ~.~ H~ (cIo~ c~J ~MI SSSOC ' ~odoc~ o~ dirtiness. ~c~sci~ets. o~ eve~ ~,th Iff oxtrem ~mM%~MM~ !~.0 ~m . II.O cotes. Ex~s~e to vl~l con elevlte ca~f~ln levels C~centroted vl~l con ~ I~!ted by M~ Intensfly ~ll ~cI ~ In I~ Clrdlovlscullr t~tem. ~dbe Ke~m~u~ ,, ' fbi.. To=lc I~ c~rotlve ~t ~e (K~d ~ c~lict with ~ ~t glowS~'S~faces. ... Eye C~tsct: Liquid ~ high vo~ c~centrltt~ ,con co~e pein ~ I,ItitJ~ .. woter t~aX as ~p~iale f~ s~r~l~ fire o~ moterlart. Skin CelloS: Prolo~ ~ re,ired skin c~tecl can ~rmitltls t~ ~(otti~ of skl~. K~lhyle~Chl~J~ %, , ~imlry toxic effect Is norco~i~, Olher toxic effects Itl ~l~lry ence~olopilhy, ~ ~molysit, ~elhyle~ chlori~ irrlloles '*~*~. retplril~y Irict, No systemic eflectl hove ~en re~rl~ iff. ~mant, ill~ excessive Concentrations have caused fiver and kidney dlmo~ :;~ ~iH ~ ~can au~ick & hckson ~Vd~ Other: Emergency eye wash fountains and safety :showers :.~should be -: --'..:. - ;- ?: .... '~:,[:-_~.:,~,~,,-. ..... available' . in the vicinity of .any potential expo_sure._'., Ground_ and · . _ : - _.' ~.:q.,:_..~i~,,.: :r~rd,~ ~.~,b0ndmetal~containers-tb.~inimi.ze '~[atic~spark~; VII. ,SPill .and Dis~i- Data -. :.;;..? .,~, :_C~ '., Spill Control: Protect from-ignition. Wear protective clothing and use approved ~ .. * - respirator equipment. Absorb..spilled material in an ~.absorbent recommended for sOlvent spills and. . remove to a safe location for disposal by approved methods.-If released to the environment. r;:,:~,~ ~t-.~/:'~':~ r;..:~,~ comply with all regulatory notificat[onfrequi[ements. . .:,~.:~,;~' , .... Waste. Disp°Sal::~,i-:*~Dispose:')of...ethyl' ether as-.an EPA:chazardous waste. Hazardous · ,... : :'. . :. L . ,. waste'n~mbers:U,11 ~(Ignitable); Dg0]~lgnitabl.e). m t If stabilized, contains eithert~w'mc a)'.:'=~ .... ' ca 2~ ethanol ~ ~ ..... : ....... ;~:~,~q~p~ b:m ..... * "~ V~e~.~ ..~'~ "' :~=:'",'-'~"? :': ;~T='~{~i-~ *~LV o~ 1000 ppm (ACGIH).. ' e~0C~f; mo~'{ te:~nc~:Ethanolfis~a suspected~carcin~entand;teratogen ,b)w . [~ ~.~e,*~p ~0 ~:aol ppm butylat~ :hydr°~to~uene (BHT,)~O~' ~fiT , , Revision,Da:ie:~:l'l.85 1420114 wo'LJoi~ ,;" * ::' ' - . ,.~ ' . ' : ,.,. , .... . .. ,.~. '":. . ~'%;~' ,.*.t .. :KEY ' ""' ";' '" · ca- '::::'f~-Approximately ;<::" >.:,L .... : STEL*''-. Short'Term Exposure Level na Not applicable?*. . ~: . .. TLV.." ?:'Threshold Limit Value C Ceiling TWA Time Weighted Average PEk Permissable Exposure Level BuAc Butyl Acetate' NSC National Safety Council ("Fundamentals of Industrial Hygiene", 1983) :*. OHS .Occupational Health Services.("Hazardline") ,:.-...'.::: :': · , , ~ ; ...... : ..... : ............ : , '.:, .' ',' ':::'L :: ': ...... , .. : .:~ r "' .Inhalation:. ~ ~lmmediately :-re'mOve:;:to ;fresh ~,aiF~'~sl~':nOt¥?breathing~-;administe~ -. --: -mouth~to-mouth rescUe breathing. _-If ~here~:is no pulse _~d~in-ister - '* -.~:_. - _L ,_,c~dj~pul mona~Y, ;,. ~ ~esusci.tation;.~,~(C~R)~.~,~..Co~tact:~,:.~physician . * immediately. ~EyeContact: .'~: ~::-Rinse wit~:copious'amounts of'Twater' for .at least 15 minutes.' ,~: '..;~. .~",'"~ ., Get'emergency medical assistanc~':~-" Skin Contact:~ '".' '.. Flush thorobghly for'at.~'least' 15' minutes. Wash affected skin '.'with soap and water. Remove contaminated clothing and shoes. Get:~eme~geEcy me~i cai a~Si~ance';.~.:~?;~:~ ~' '~" Ingestion: .................. ~ ~1i ~10caLPoison.: Con Cente~, .fot_ass~stance .~ , .immediately. ~ Never induce vomiti~g:,'0r'give anything,by-mouth i' '": to a victim unconscious or having'convulsioh{: VI. Safety Measures and E~ipment , - Vent i lat i on:(~-~*E 0 ?~i) ~equatd ~ent, ilat.ioh; is~ rdquired~to prdt~*ct~peFsonnel -from exposure ...... ' to chemical vapors-exceeding.th~ PEL and to minimize fire hazards. ,'v.. ' ' ...... The cholce~of}vent~latmn::.eqmpment;~.e~thejr+,local or-geneFal~ ,_depend on the conditions .of use, .quantity. of material;_ and other. .......... operating parameters. ~ ,. ............ . ..... ~, Respiratory: ~ O'se approved~re~piratoF equipment.': Follow NloSH',~n~'eqmpment~e;'~ manufacturer's,,? ,.recommendations ~ to "determine appropriate " .......... i~pu i~yi g,' ai~ Upplied 0 n{ g '-; ,Eyes:,-' Safety -gl~sses are .considered, minimum .protection.. 'Goggles or . /' face shield may be necessary'"depending"on ~quantity' Of 'material Skin: Protective gloves and,,.~lo~h~ng aqe. ~ecommended. The Choi~ . of material must be-ba~e~ -on .chemical resistance and other user . requirements. Generally, neoprene * 0r'*"Bun~-N" offers 'a~cePtable ,~ chemical resistance.;,IndividUals~ Who;;ar~.;acdtelY~nd specifically sensitive to, .ethyl' ~'ether ~ ,may,~, require. ,additional ."~ protective. Storage: Ethyl e{her' ~h~id be Pr0'tected '~O~"'t~'~pe/atbre .: · direct sunlight.. Proper storage,of ethyl ether, must be determined based on other materials stored and their~ hazards and..potential' chemical incompatibility. In general, ethyl ether sh~ld be stored in an acceptably protected and secure flammable liquid storage ~_ '~ ,u~::,~room... Periodically ;;check for peroxides ,in .stored,<material and -..;?:.;. Jprior to-use, ?pecially'before concentrating orheating~ _ V. Health Hazards · -' ~!" ~'~, - :~=~at~.nal Exposure Limits .... Concentration Immediately Danoerous ' ' OSHA 8-hour PEL -- ~00ppm - - '". .. ,. Ceiling '- .'not listed .... -OSHA/NIOSH . -,19,000ppm ' :':'~:'~' ~ Peak - -not listed ACGIH TLV-TWA - ~00 ppm ,,: Odor Threshold ,.. TLV-STEL - 500 ppm ............... - {1S-rain) NSC_g'. OHS '-.~ .,.~': r.:"l;O 'ppm O SH 'TLV-TWA~' ...... .- ' "not ":''~'. ~': ..... ' ; ' 0.33 Ni_._ ,., .. listed .. ~NIOSH ,.~ .......... ppm, ~, . . ~"" ................... ' ~ TLV=C'~';;' "~"= ~'-not listed ";,.;d~.~,, ....... ,- ;~ · ~' '?, ~?s ., . '~ .~. ' ~.;.:,~ ~.r o~en,c '.,.,u.a.~n.c.'-~ra.ouen.c :...n: :'.:, .... :.'. '."': .... ...~'. ' ~ "Pri~ar~ Entrv, · ' · ' .' · '~F-'~-'? ...... E{~l-$~$k'*-~$~'e~-:ifS-'$'f f~t~'X~iou~h"ifih~l~ti6h;"~kid' ~bsofption,- ~'n-~ ingestiod~'.~ "'"" · . ~.i~o~ ~q:q;lnddgt~i~l;E~Dd~u~,Rou't~'~:.EXOosb-re/Sions-and'Svmotoms ............................... -'~. ....... Inhalation: .........: .... Exposure can ;-,c~Use-7 ~e'aQache;-~- nausea, .... vomiting,--mss ~ = ~ ............ ~ ................. consciousness,- -and .m---ve~--h~gh - concentrat~onsc-deat-h - due- to .... ~'---~'~h~i~ Liquid and high vapor concentration can cause irritatioh. ~--~'~}'~-~h~CqfiCa~!'~-~ ,~ ~} '..prOlon~... or .~ .rop~atod-~ skin'~x~ontact can Cau~ ir~it'atiO ..... s .......... ' ...................... ~ermatiti~:throu~h defattin~ of ~kin'~ : ........................ · · - In~e~tion: ......... S~mptom information is inadequate/unknown. - .__6~ ~:.~-.~_:.. ~tBy[-$iBe~ 6i~.-~:~ild :~e .~nd: ~ucoUg- membr~n&~',irrit~nt, prima~ skin irritant, and _~:).". ~). ::L Centkal 'nervbfiS' :system ~depressant,.; Acute -exposure. can ~cause anesthetic effects such 'as~vomiting,. excitement; unconsciousness, coma, respiratory paralysis, and death. Chronic expo,ure~'ma~ pr~ce central nervou~ ~tem.di~turbance,. .......... Med~ ca I"C ond~ t ~on -A~rava ted by E xnosure ' . ....... Preclude from.exposure those individuals susceptible to dermatitis · ,,.,.:,.~.: ,r-;~ ,.'.'...: ~: · ,~ ..-'.. , ,_ , . . ,. , ,-, ...... · ,~,.. America Burdick tJackson ";'. Material Safet Data Sheet ............... ...,., · 312/973-3600 (American Scientific Products) MATERIAL 8AFETY emergency telephone no. - , ' . infOrmation telephone no. '616/.726~3171:- (American'Burdick & Jackso~ '. " ' -- I, Identification · . '~'- -, . . .. ..-, ; ': :: chemicalname Ethyl Ether molecular weight. .7,.12 ,., ETHYL ETHER chemical family Ether formula C ~ H 100 synonyms Diethvl Ether~ Ether, Ethoxyethane '" DOT proper shipping name Ethyl Ether ..... " ' DOT hazard class .... Flammable Liquid ". .~ , --";: DOTidentificati0nn0. UNl155 ~ CASh0. 60-29-7 ....... :... I1,' Physical and Chemical Da~ boiling point, 760mm Hg. 3~.55°C freezing point -1 ~'7.~°C ' evaporation'rate ' (BuAc=l) > 10 vapor pressure at 20~C ~2 mm Hqvaporden~i{y(air='l)' ' ,2.6 ' ~solub~lityinw~te~ ' ~ 20°C 6.89~ % volatil~ by volume ca' 100 "' :~ific gravity (H~O =1~'. ~ 20~C- 0.71 3 .stability ~'' ' ' Unstable hazardous polymerization " · Not expected to'OccUr. -" ' appearance and odor C lear, colorless liquid with a sweet, Pungent'Odor." conditions to avoid ' Heat, sparks, open flame, open containers, and, poor ~veqtilation. ~, ' ''OxidiZing agents an~ strong'acids, ...,, . materials to i"ncom" ~':~! '" '" ~ :~b ~]~ a'- ~ ~ .....' '" ''~carUOn~mOnOxlde'and'Oth'' er hazardous decomposition products, ete"c°m-ust f°~--~n[-enerate toxic ,:.' ~ ;;:::~.. .... - ,. , .. ~ -,. , '~..;: ,_ ~:. vapors,"..Explosive .... peroxides,can form after-standing or..up°n, exposure III. Fire and ~plosion Hm .D *' ..... 160°C flash point. (test method) , ' ' -~5°C (Tag closed cup) auto ignition temperature flammable limits in a,r Yo ~y volume: lower hmlt :, ,:~.: :;-r%.,'~ '~o%~v ' ,;¢ ~ c~. ~; ..-.: ~ unusual fireand explosion hazards .... Extremely volatile and extremely .flammable., Can form heat sensi- tive peroxides ~ , ,........ ,?;~:::.:. ~* . ~hi~h"mav*exoiode. off~oncentra~in~.'Or bvaporating. '" .... a,oxtde, 'd~ chemical Er. foam. " extinguishing media 'C'arbofi" '" ' ~+ ............. ' ' .....' .... ~' · Wear full protective ~lothing and'self~dbdta'in~d bff~athing"apparatus. special fire fighting procedures ¢,.-~. ~,..,.-~, ,.~, ,',;~ ,,-,,,;~.,~,,.' ,Heat-,will.build pressure:,and may rupture closed.storaqe.containers. ~:,~.:.~ ;~ :~; ~ :~i ~,~,.~ t;,~-;~¢ ~-.~.:Keep fire=exposed ~ntainers,cool' with~water,spray, reTie.at, as flam- . ,. ' ?-:~.~/mable ~as.,,Surroundinqs:must be kept co,led below 160°C-to ex- IV. Ha~ous Components ' "":?~'?'"tinbuish an ether fire.and prevent' reignitiOn,(~;-;~:.:... Ethyl Ether plus stabilizer % · ca 100 .TLV . ~00 ppm . ~S.no... 60-29-7 (see supplement) ........ ~':'~ .... '~'~ "~"'z~':" '~ ~':':' ~:':~ ~' :; k~' '-";'~ "'' Ameri~n Burdick & Jackson's Disclaimer: "The information a~d recommendations Presen{ed herei~ are based on sources believed to be reliable as of the date hereof. American Burdick & Jackson makes no representation as to the completeness or accuraw thereof. It is the user's responsibility to determine the product's suitability for its intended use. the product's safe use. and the product's proper disposal. No representations or warranties not expressly set forth herein are made hereunder, whether express or implied by operation of law or otherwise, including, but not limited to any implied warranties of MERCHANTABILITY OR FITNESS. American Burdick & Jackson neither assumes nor authorizes any other person to assume for it, any other or ADDITIONAL LIABILITY OR RESPONSIBILITY resulting from the use ol. or reliance upon. this information." · -' .... American Burdick& cksonSubsidiary of Ameri~n 1953 South Ha~ey Street ::: Hospital Supply ~rpo~tion Muskegon MI 49442 'Inhalation: ' -,Imrnediately'-i-~move to 'fresl~-'air.~:--'l¢?"nbt breathing, administ% -mouth-to-mouth rescue breathing.' If.there is no pulse administer cardi.opulmonary resuscitation (C PR). Contact physician immediately. Eye'Contact: Rinse with copious amounts of water for at least 15 minutes. Get emergency medical assistance. Skin Contact: Flush thoroughly for~ at-least 15 minutes.- Wash affected skin with soap and water. Remove contaminated clothing and shoes. '"'"' Wash ' clothing before- re-use,' "and " discard contaminated 'shoes. ' :' "'~' · ": Get.,emergency medical assistance, '~': " " 'Ingestion:.: Call I~)~:al Poison':C0nt~01 Cent~r'fOr' a~sis~ance.-' Contact physician immediately. Aspiration Hazard- Do' n~)t"'induce Vomiting. quip VI. Safety MeaSures and'E ment Ventilation: Adequate ventilation is required to protect personnel from exposure to chemical vapors'exceeding the PEL and to minimize fire hazards. The choice of ventilation equipment, either local or general, will depend on the conditions of use, quantity of material;'~and other · operating .parameters,.., ReSpiratory:' Use aPProved respirator equipment. FOllow NIOSH and equipment ' ~ manufacturer's 'recommendations '" to: -'determine · appropriate equipment (air-purifying, air-supplied, or self-contained breathing apparatus). Eyes: Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending'on quantity of material and conditions of use. Skin: Protective gloves and clothing are recommended. The choice of material must be based on chemical resistance and other user requirements. Generally, neoprene or Buna-N offers acceptable chemical resistance. Individuals who are acutely and specifically sensitive to petroleum ether may require additional protective equipment. _ _ _ - .:~ - F:~ .. · . ..'~ · :: - Inhala~'ion: _.:;-.Immediately":i~emove .~to-fresh air. 'If :not 15reathing,'- administer.I mouth-to-mouth rescue breathing. If .there is no pulse administer cardiopulmonary -resuscitation (C PR). Contact physician immediately. Eye'Contact: Rinse with copious amounts of water for at least 15 minutes. Get emergency medical assistance. · Skin Contact: Flush.--thoroughly for at least 15 ,minutes. Wash affected skin with soap and water. Remove contaminated clothing and shoes. ."~ ,':~- ', Wash ~' clothing before re-use,-end';disCard contaminated 'shoes.~ '" ........ " Ge~emergency med!cal assistanCe. 'Ingestion:'" Call Io'cal"Poison C0nt~ol Center'for a~si~i~ance:. ;Contact physician immediately." ASpiration' Ha'Zard - Do n0t'indu(~e' vomiting. · Ventilation: Adequate 'ventilation is required 'to protect personnel' from exposure to chemical Vapors exceeding the PEL and to minimize fire hazards. The choice of ventilation equipment, either local or general, w~ill depend on the conditions of use, :quantity of material~'"'~nd! ~'ther .. operating, parameters~ . ,, ., .... ,. Respiratory: Use .approved respirator ' equipment.' Follow NIOSH 'and equipment ·, v .- ,,. .,. manufacturer's~ recommendations :::'to ~-"determine appropriate equipment (air-purifying, air-supplied, or self-contained breathing apparatus). . .. Eyes: Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending on quantity of material and conditions of use. Skin: Protective gloves and clothing are recommended. The choice of material must be based on chemical resistance and other user requirements. Generally, neoprene or Buna-N offers acceptable chemical, resistance. Individuals who are acutely and specifically sensitive to' petroleum ether may require additional protective equipment. Vo Health Hazards ' Occuoational Exposure Limits Concentration Immediately Dangerous to Health OSHA 8-hour PEL - 500 ppm Ceiling - not listed OSHA/NIOSH 10,000 ppm Peak - not listed . . Odor Threshold ~ * ACGIH' TLV-TWA not listed TLV-STEL ~' not listed OHS 5 ppm (15-min) NIOSH & NSC "not listed NIOSH TLV-TWA - 115 ppm ..... ~ ...... ~ ~. - ........ :.,TLV.-C..., ~ .... ~ ~..,590 ppm ,: , . ...... ,..~., .... ~..~ .......... ~t. ........ ; , .: ?:'...' ~' ,. ,.,,,~-~;?,:;'~ ,~* ' ~ Routes.o_[ Entry' ':'-,.: ' ~ ' Pe{roleurn ether may' exert it's effects through inhalation, skin absorption, and ingestion. ,Industrial Exposure: Route of Exposure/Signs and SymPtoms. . ..... Inhalation: ............ Exposure.~can .cause~headache, .{Jizziness, nausea,, intoxication,. central .:nervOus .system. depression, and irritation of. respirator7 ,,,.. , : ',:~,.~,., .... ....... ....... E.y~. Contact :'~" ............. L'i q~i'd an(:J' h i ~' ,~,~ p0r ;::*~e n tra ti~)~-~:a n' i:~' *i~.r'i {~t i ~ g: .............. ..... : ...... '" -. skin.Contact: ....... May'be;absorbed through intact'skin and prOdUce toxic effects' """ ' . ' .... ':::?:?--":.-: ....... :- RePe'at~d.'or' 'prolonged skin '.: Contact: can cause irritation "and ~,~ : . ~ . . .~.,~ · ..... ~.~-~.::: ~,.- dermatitis through defatting of the skin.~=. .... ..:. ~ ',' ...... Ingestion: ......... Can cause gastrointestinal tract discomfort 'Effects.of Overexposure .......................... * PetrOleum 'ether "is a mild.eye 'and muc. ous membrane'irritant, Pri'~ar¥ skin irritant .... 'and-lcentr~i nervous system depressant.. Acute exposure irritates the eyes, nose, and skin. Narcosis may occur at 'elevated concentrations. Medical condition Aggravated by Exposure Preclude from exposure those individuals susceptible to dermatitis. · 0004 JaCkson '"'"' American Burdick & ...'-- Material Safety.Data. Sheet · : · .. - MATERIAL SAFETY · . emergency telePhone no. ' '312/973-3600 '('American Scientific ProductS)· .- ' - DATA SHEET -- ..- chemtrec telephone no. 800/zl2q-~ 9.300 information telephone no. 616/726-3171 (American Burdick & Jackson) I. Identification chemical name Petroleum Ether molecular weight na chemical family Aliphatic Hydrocarbon formula na PETROLEUI~ ETHER synonyms Liqroin, Petroleum Spirits DOT proper shipping name Petroleum Ether DOT hazard class Flammable Liquid DOT identification no. U N 1271 CAS no. 8032-32-4 II, Physical and Chemical Data boiling point, 760mm Hg. 30-60°C freezing point <-q0°C evaporation rate (BuAc= 1 ) >. 10 vapor pressure at 20oC ca/400 mm Hq vapor density iair=l) ca 3 solubility in water ~ 20°(; 0.0/4~ ' %volatilesbyvolume ca 100 specific gravity (H20 = l) @ 20oc 0.6Z~ stability Stable hazardous polymerization Not expected to occur. appearance andodor. . Clearr colorless liquid with'a mild hydrocarbon odor. - ~ conditionstoavo!d. ,¢... ..~,~; Heat,. sparks, open flame,, open containers,.. ; and poor ventilation. materials to avoid Stronc~x[di zincj ~c, lents. ' ...... Incomplete combustion can generate carbon monoxide and other hazardous decomposition p~oducts, toxic vapors. III, Fire and Explosion.Hazard Data flash point, (test method) -qg°c (oPen cup) auto ignition ,temperature 288°C' flammable limits in air % by volume: lower limit 1.1 upper limit 5.9 unusual fire and explosion hazards Very volatile and extremely flammable, extinguishing media Carbon dioxider dry chemical or foam· special fire fighting pr0cedure{; "' '- : Water will not be effective in'fiqhtinq'a fire and may spread it, but a water spray can be :used t0 CoOl exposed containers~ Wear full protective clothing and self-contained breathing apparatus. Heat will build up pressure and may rupture closed containers. IV. Hazardous Components , -.. ' ,,_ '"' Pentane and Hexane isomers .... %-- ' . "ca 100 TLV 500 ppm(PEL) CASno. 8032-32-/4 American Burdick & Jackson's Disclaimer:. "The information and recommendations presented herein are based on sources believed to be reliable as of the date hereof. American Burdick & Jackson makes no representation as to the completeness or accuracy thereof. It is the user's responsibility to determine the product's suitability for its intended use, the product's safe use, and the product's proper disposal. No representations or warranties not ..xpressly set forth herein are made hereunder, whether express or implied by operation of law or otherwise, including· but not limited to any implied warranties of MERCHANTABILITY OR FITNESS. American Burdick & Jackson neither assumes nor authorizes any other person to assume for it, any other or AOOITIONAL LIABILITY OR RESPONSIBILITY resulting from the use of, or reliance upon, this information·" · '- .... American Burdick & Jackson Subsidiary of Amedcafl1953 South Harvey Street · · · Hospital Supply Corporation Muskegon MI 49442 ": :''" ' ' "" ' *" "*' '. '"'~: :,i:' ":!:' ::: .... ' ............ .*.*'"" .'. ...... .: .:. . . :. · ,. . . :. :.. .. ~ Storage- Methyl isobutyl 'ketone 'should be protected from .temperature' C -.-*.-~ : : - - - :-'- - -extremes and-direct-sunlight. -Proper .stora~ge .'of.. methyl_ ,sobuty ' :*.:',,-~: ,': *--~.i;:."~ ;' :, Cketon~-:taUs{ :. be:;determinedF:based: .on othe~,.materialS S~ored~ :and_:*. " .- '.. - *,.~.' ,_~ --~,'¥~ ,, s::-.;. _their;hazards' ;and;. potential :=chemical,~dncompatibility· ;' In genera J, -:~ .:: ;: '- .~,'.~-~-: . methyl isobutyl-ketone should be stored in a~Ccept*abiy prOteCted. and secure flammable liquid storage room. ~ Other: ..... , Emergency eye':wash _fountains .and safe~y* showers-should be available in the vicinity .of any potential ~xposure. Ground and - *bond metal containers to minimize static sparks. , '~ ' G 6, * : . VII.. Spill a~ Di~l Data :~. ~ ~'~ ..... ~:'~'-" .... ?~ .......* ....... ~:' ~ ~= ?- * ' · ~ Spill Control:.--~-"~ Protect. from ignition~>:~Wear~protective ~lot~ing'~and use approved respirator equipment. Absorb spilled material in an absorbent "*' '~.~:~ ~':?a;~.,<f~;.;~:~.~?:'r;:recommended fo~ ;*solvent'cspills' and~,r~mo~e. ~to;;a safe location ' "' ' ~'.; .:,~:?~ ~ ~c..:;L. for disposal by~aPproved.*meth~s;,' If releas~d.;to~the environment, · :, -~ *' :comPly'with all~regulato~ notification requir~ments. * "'= WasteDisposah ..... *..Dispose ~.of .~methyl.~isobutyL.ketone as xan: ?A ~hazardous-~,waste.-,~ ~: , ,:;* * .~.~.',~;/ . ;;~;-.~ :HaZardous Waste num~rs:.,U 163 (Ignitable); E 001 (Ignitable). ' '" ' .. '.,. x...-,,~ ~.;r~ ~,-~.~,.?'~.~ ,,'..' t~'~',.,~¢ .*,-~,~:~d~,~· , ,.~'~.-,,"~..~':,~ ~5"~;"-; 'z"'"'., ' :, '"".. Revision' Date: bl018.5~l'~.r.f,~ .~., .......... ~,,a.p ,.~,~ Ic .......... ' ~,~,~t. '~ :b~c:~ ~;:~:~' ~",-*:- ~p~.~.,.., . :.. . ... .. · . ... .~. ,i . .... . ,. . ; ..' ... '-.;'S:~:: ~t~3~q~' ~'~',; ~ *~ :' ~".;~,.'~ ~t?~':'-~".::'-c: ~, ~ -'*~*:~ '*~ ,: ' ,. :, .:, ,,~ - . ca" Approximately; STEL Short Term~ Exposure Level na Not applicable TLV Threshold Limit Value C Ceiling . TWA Time Weighted .Average PEL Permissable EXposure Level BuAc Butyl Acetate NSC 'National Safety Council ("Fundamentals of Industrial I~ygiene", 1983} OHS Occupational Health Services ("Hazardline") l' .................. · ...... 7: ......... ?: "~' ...........: .......... ' ': ' ........ :;.:' i,;" ?~:.", :~ ;~ :~;~ ~cardibpulmona~'~resuscitat~on (O PR);",,Oonta~t ~phyS~c~an '~mmed~ate- Eye ContaCt: ~ ;~:. ,, Rinse' :~it'h copious 'amounts of:water for at~least L-15 minutes. ~Get. ' 5kin;Contact:.~;~?:FluSh~horoughly for at least. 15 minutes. Wash 'affected skin ' :: Wash clothing .before re-use, and discard co ~taminated shoes., Get' ' Ingest~onu "'et.~a, ~-.s C,all ~local,,:P0is~n -O~htrol~'~eenter"f0r asSistar ,~e~g,g..ontact' physician. ...... - : ;, ' . ";,tO~a~vietim-unconsci0us?or~having3con~ulsions. 'r~.~o: .... '~' .. ~ Ventilation/ . AdeqUate ventil~tion is required to protect p~'monnel from exposure'. . "' '~ .........." ~minimize fire hazards.. ~:. , The "Choice of~:ventilation equipment,, either~l~&~ Or ~eneral~ will .~ . depend on t~e conditions., of .use, quantity.. . _ ResPirato~')','~ t ~se=', a~Proved~respirator Tequipment~F~ Io~'NI OS H ~and · . ', :- =' .:'manUfacture'~~('~ecbmmehdations -to:-' determ~ne-~appropriate equi~ ..... Safety' glasses are considered m~nimum p~tection. Goggles or ..... Eye~:. ~, ,.~ , '~.'. andfa~e:: fiondition~~ ~hield"~aY,~. of u~o. ~ n°c°~arY., dependin~ Skin: ~' Protective ~love~ and Clothin~ aro reco~mondod. 'lhe choice ...... of" material mu~t: ~.,ba~od on chemical:~re~[stance' and other u~er .... requirSment~ ~ Generally, ne0pr~ne-' or'n~tur~':rub~r offer~ accept-. ablo ?~hemical ro~i~tance. -Individual~ ~ho- ~re acutel~ and ~: ....... specificallY: sen{i{i~e~ to. 'methyl isobutyl d~t~onal )rotect~ve eqmpment. ' .. , ,. . . ·.. +,~ '~ V. Health Hazards. OS'HA '8-hour-PEL ' '~ . 100 ppm ......... ' :" Ceiling - not listed. OSHA/NIOSH 3,000 ppm .. Peak:.---. ..... not listed :-' " Odor Threshold ACGIH TLV-TWA - _50ppm . TLV-STEL T~ 75 ppm OHS ': I .: 0.10 ppm (15-min) NIOSH .. ,- ..... -:~..,:.~notlisted.~. ..... ~ ..... '~50 pP~ ..... Methyl:SisobUtyI ketone.:~may exe~t~.it~' and ingestion ............... ............ Eyo 'COhtaCtF ......... Eiqui~'*and high"vap°r'concentrationcan'be in;itating; ............ Skin~Contact'f-.~-:---' PrOlonged~ O~re~o~ted-,~km 'Contact :ean:cau~ ~.--irritation :~' ~,:,~ ,.~..~ · Mothyl i~obutyl ketono-~is a mild'oye:~nd mucou~ membran~ irritant~ primary skin irritant, and central nervou~ ~y~tem depressant. Acute exp }~ure causes irritation and narcosis. ' '~ '-: Medical Condition. Aggravated ~~" PreclU~ from exp~u~o'.tho~e *Oep ... . .. . _.. . ~: ~ ~.,, .- · "'' . ', ; '' ' · American Burdick & JackSon **'*'" .Material Safety Dam'.Sheet ......... .!.' ." emergencYtelel~h'~;~.~--~312/973-3600(Am'~r/can: s~ientific Pre)ducts) ' '~':': ~' "- "MATERIAL SAFETY chemtrectelephone.o. 800/424-930'0 '? "' . · ' · ' ~" ~ DATA SHEET information telephone no. 616/726-317~ (American Burdick & Jackson) I. Identification:' ! ' I· '~ *~ "' chemicalname Methyl Isobu, tyl Ketone molecular weight ~00.~6, F1ETHYL ISOBUTYL KETONE chemical family Ketone formula C 6 H 12° ! "' synonyms MIBK; U,-Methyl-2-pentanone: :I. - .' ', · DOT proper shipping name Flammable Eiquid, mo.s.- ~....' ,_. . .... :;;,'.". :...~ DOT hazard class Flammable Eiquid: --' ~. '- ~' -''.,~ -,. DOT identification no. U N 1993 ' ' ' CAS no. - 108-10;I i::.,. '~' '. ;. ' . i :,: ' ' II. Physical and Chemical Data';,, .... "'"' "'~' ~''' ;~' '~' ~ ::'~''' ' ' '"'""' ''~ '~ boiling point, 760mm Hg 1 16.5 °C freezing point . -8z~°C . ev rat!on rate - (BuAc.ff ! 1.6 vapor pressure at 20oC 16 mm Hg ~i vapo~density(~ir;1) 3,5 sol~u.~ilitYinwate~"'@ 20~(~;' % volatiles byvolume -".'~-ca !00 , ,,? ;~..specific;gravity(H;0=J),." @ 20°C 0.801 stability,'-' '--:~ :','Stable' ,~ ..,- ,. Not expected to occur. hazardous polymerization I ' ' ' appearance and odor .,~,~- -, ~ .,:~.~ Clear, colorless liquid with a sharp might-like odor. ' ' .' Heat;: spai'ks;.bpen:flame,,.open containers, and poor...._~ ........ ...~.,...... conditions to avoid,:. ': .; ., .' ' '~" .~,:~ ,--:! ven. tilation..':. -..'- -' .... ., ~ , : :'. L~:i~: .¥ ~.:., : .-. ,. ~ - s.'and bases. , materials to avo,d . . Strdna"o' · . ; :.'..~ ~idiz~na aaents and strona aci~ ..... .. ~,'..~:,~,~ ,,.; , T' .*,.- . ; ~.. -. ~ .,~. ,,: ,... :,, ,~ -, . ,', .._i~_-: ..hazardous decomposition:products,' .... . ;, Incomplete co,m_bustion can generate ~'arbon monoxide . and other tox,c vapors, · .~ ;. . . flash point, (test method) t 23°C (Tag closed cup) auto ignition ter~perature u,60°__C. flammable limits in air % by volume: lower'limit l.Zl -: upper hmtt ~ ............... 7.5 unusual fire and explosion hazards '~". ~ None;"'other than flammability. ; ~" --,' · ' · ~ ~';~'~.; ' ' .t~ ~ . · ." . :- ': · · ." ,.* . ~ .;?'~'_ ,'';,.': ' ,. . extinguishing media Carbon dioXide,' dry chemical, or ~oam, special fire fighting procedures , ~.~ ,, Wear,.full protective clothing and. selftcontained breathing ...... apparatus. Heat will build p';'essu're and may rupture closed , , ':', storage containers. Keep fire-expose~l containers cool with 'I water spray, IV. Hazardous Components ' Methyl Isobut,vl Ketone % ca 100 TLV 50 ,opm CASno. ~08-10-1 American Burdick & Jackson's Disclaimer: "The information and recommendations pre~ented herein are based on sources believed to be reliable as of the date hereof. American Burdick & Jackson makes no representation as to the completenes~ or accuracy thereof. It is the user's responsibility (~?' ' to determine the product's suitability for its intended use, the product's safe use, snd the product's proper disposal. No representations or warranties not · expressly set forth herein are made hereunder, whether express or implied by operation of law or otherwise, including, but not limited to any implied warranties of MERCHANTABILITY OR FITNESS. American Burdick & Jackson neither assumes nor authorizes any othe~ person to assume for it, any other or ADDITIONAL LIABILITY OR RESPONSIBILITY resulting from the use of, or reliance upon, this information." .! ;:::::: American aurdick & JacksonSubsidiary of American 1953 South Harvey Street · .. Hospital Supply Corporation Muskegon MI 49442 '~ 7~ k.J'T'Ba MATERIAL SAFETY DATA SHEET ~ CHF. N~CAL5 J.T. Baker Chemical Co., 222 Red School Lane, Phillipsburg, N.J. 08865 CHEMICAL NAME FORMULA Toluene C~ H; CH ~ Z SYNONYM OR CROSS REFERENCE CAS NO: 108-88-3 Toluol Methacide E PA NO: B719-5023 Methylhenzene Phenylmethane MATERIAL ] I NATURE OF HAZARD BOILING POINT MELTING POINT 111"C - 95"C VAPOR *PRESSURE . spECIFIC GRAVITY 36.7 mmHg at 30"C 0.87 'VAPOR DENSITY (AIR=l) PERCENT VOLATILE BY VOLUME (%) 3.14 WATER SOLUBILITY EVAPORATION RATE Insoluble (. = 1 ) APPEARANCE Colorless, refractive liquid with benzene-like odor. FIRE EX3~.INGUISHING MEDIA Water spray, carbon dioxide, dr/chemical, foam. SPECIAL FIRE-FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARD Flammable liquid THRESHOLD LIMIT VALUE ipr-rat LD50:1640 mg/kg 200 ppm orl-rat LD50:7.53 mi/kg HEALTH HAZARDS Harmful if inhaled or swallowed. Causes eye irritation. FIRST AID PROCEDURES If inhaled, remove to fresh air. Administer artificial respiration or oxygen as necessary. Call a physician. If sallowed, do not induce vomiting; if conscious, cautiously give warm water, then mineral oil followed by hot coffee or tea. Cai! a phys. ician. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Flush skin with water. STABILITY UNSTABLE CONDITIONS TO AVOID STABLE Heat, sparks, and flame. INCOMPATABILITY (materials to avoid) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS I MAY OCCUR CONDITIONS TO AVOID POLYMERIZATION I WILL NOT OCCUR SPILLS Eliminate all sources of ignition and flammables. Absorb spill on sand, earth or vermiculite. Carefully sweep up and remove. Allow to evaporate. Flush spill area with water. Alternatively use J. T. Baker Flammable L/quid Spill Kit. DISPOSAL Atomize into an incinerator providing environmental regulations permit. Combustion may be improved by mixing with a more flammable solvent. RESPIRATORY PROTECTION (specify type) All PUrpose canismr mask available. VENTILATION LOCAL SPECIAL Preferable MECHANICAL (general) OTHER PROTECTIVE GLOVES I EYE PROTECTION Rubber gieves I Safety giasses; face shield OTHER PROTECTIVE EQUIPMENT Appzoved working clothes; eyebeth. STORAGE & HANDLING Protect conteinezs against physical damage. Keep away from heat, sparks, and flame. Keep in tightly closed container. Wash thoroughly after handling. Avoid breathing vapor. Avoid contact with ayesAkin, or clothing. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. Manager, Quality AssUrance Revision No. & Date Issued: The information provided in this Material Safety Data Sheet has been compiled from our experience and data 0resente¢l In various technical Dubllcatlons. it is the users reel3onsibillty to determine the suitability of this information for the adoption of safety precautions as may be nece~ry. We reserve the right to revise Material Safety Data Sheets from time to time as new technical information Oecomea available. The user has the resgonsibllity to contact the comDany to make sure that the sheet is the latest one issued. JTB FORM M399, R~v. 7/77 :;. American Burdick & Jackson *****"...... Material .Safety Data Sheet emergency telephone no. · 312/973-3600 (American Scientific Products) MATERIAL SAFETY chemtrec telephone no. 800/424-9300 DATA SHEET information telephone no. 616/726-3171 (American Burdick ¢_, Jackson) I. Identification C HL OROF ORFI chemical na~e Chloroform molecular weight 119,38 chemical family Chlorinated Hydrocarbon formula C H C 13 synonyms Tri ch I oromet ha ne DOT proper shipping name Chloroform DOT hazard class O RM-A DOT identification no. g N 1888 CAS no. 6.7-66-3 II, Physical and Chemical Data boiling point, 760mm Hg 61,2°C freezing point -63,5°C evaporation rate (ether--1) ca 0.6 vapor pressure at 20oC 159 mm Hgvapordensity(air=l) /4,1 solubility in water @ 20°C 0.8% %volatilesbyvolume ca 100 specific gravity (H20 = l) @ 20°C 1.q9 stability Stable hazardous polymerization Not expected to occur. appearance and odor Clear, colorless liquid with a mildly sweet odor, conditi0nsto avoid Heat, sparks, open flame, open containers, poor ventilation, and moisture, materials to avoid Active metals and stronq alkaline solutions, hazardous decomposition products~. . . . .. . . Phos<~ene._ . hvdrooen.. _ _ chloride, and chlorine.: III. Fire and Explosion Hazard Data flash point, (test method) None (closed cup) auto ignitiOn temperature__ Not known flammable limits in air % by volume: lower limit na upper limit na unusual fire and explosion hazards Concentrated vapors can be ignited b.v high intensity heat source or flame, Toxic and corrosive gases are formed on contact with flames or hot glowing surfaces, extinguishing media Non-flammable material, Use dry chemical, carbon dioxide, foam or water spray"as appropriate for surroundin9 fire and materials. special fire fighting procedures Non-flammable material. Wear full protective clothing, and self- contained breathing apparatus, Heat will build pressure and may' rupture closed storage containers,. Keep fire-exposed containers cool with water spray, IV, Hazardous Components Chloroform plus stabilizer . % ca 100 TLV 10 ppm CASno. 67-66-3 (see supplement) American Burdick & Jackson's Disclaimer: "The information and recommendations presented' herein are based on sources believed to be reliable as of the date hereof. American Burdick & Jackson makes no representation as to the completeness or accuracy thereof. It is the user's responsibility to determine the product's suitability for its intended use, the product's safe use, and the product's proper disposal. No representations or warranties not expressly set forth herein are made hereunder, whether express or implied by operation of law or otherwise, including, but not limited to any implied warranties of MERCHANTABILITY OR FITNESS. American Burdick & Jackson neither assumes nor authorizes any other person to assume for it, any other or ADDITIONAL LiABILiTY OR RESPONSIBILITY resulting from the use of, or reliance upon, this information." .,oo,.. American Burdick & Jackson Subsidiary of American 1953South Harvey Street · ,, Hospital Supply Corporation Muskegon MI 49442 ©1985 American Hospilal Supply Corporation · Vo Health Hazards Occupational Exposure Limits Concentration Immediately Dangerous to Health OSHA 8-hour PEL - not listed Ceiling - 50ppm OSHA/NIOSH 1000ppm Peak - not listed ACGIH TLV-TWA '- ]Oppm Odor Threshold TLV-STEL - · 50 ppm (15-min) OH5 100 ppm NIOSH TLV-TWA - not listed NSC 200ppm TLV-C - 2 ppm (1-hour) Carcinogenic. Mutagenic. and Teratogenic Data Suspected carcinogen in humans (IARC, ACGIH, NTP) Animal carcinogen (IARC); Animal teratogen (RTEC) Positive carcinogen in mice (NCI); Positive mutagen (RTEC) Primary Routes of Entry Chloroform may exert its, ffects through inhalation, skin absorption~ and ingestion. Industrial Exposure: Route of Ex.oosure/Signs and Symptoms. Inhalation: Exposure can cause nausea, vomiting, drowsiness, headache and dizziness, unconsciousness, and even death in extreme cases, Subsequent liver .and kidney damage may result from both acute and chronic exposure. Chloroform can cause olfactory fatigue and has poor warning properties. Eye Contact: Liquid or high vapor concentration can' cause pain and irritation with slight corneal injury possible, Skin Contact: Prolonged or repeated skin contact can cause, irritation and dermatitis through defatting of skin. Ingestion: Swallowing is followed by burning of throat and mouth. Liver and kidney damage can result, Effects of Overexposure Acute exposure causes excitation followed by dizziness, nausea, headache, unconsciousness, and respiratory failure. Death may occur from cardiac arrest or hepatic damage. Chronic inhalation may result in liver or kidney damage. High cOncentrations of vapor cause conjunctivitis and spasmodic winking. Liquid contact with eye results in burning Pain and irritation, with possible corneal injury. Storage: Chloroform should be protected from moisture,' temperature extremes, and direct sunlight. Proper storage of chloroform must be determined based on other materials stored and their hazards and potential chemical incompatibility. In general, chloroform should be stored in a cool, well ventilated and secure toxic storage room. Other:' Emergency eye wash fountains and safety showers should be available in the vicinity of any potential' exposure. VII. Spill and Disposal Data ~ Spill Control: Wear protective clothing and use app,roved respirator equipment. Absorb spilled material in an absorbent recomm~nded~for solvent spills and remove to a safe location ~for disposal by approved ~' methods. If released to the environment, comply with all , ~ ~ regulatory notification requirements. .,.. Waste Disposal: Dispose of chloroform as an EPA hazardous waste." Hazardous '~ waste number - U O44(Toxic). VIII. Supplement Hazardous Components Stabilizer will consist of either: · -.: · a)~ .... ca 50 ppm amylene · .. b) ca 1% ethanol + 50 ppm amylene ; Ethanol has a TLV of 1000 ppm (ACGIH). Ethanol is a suspected carcinogen and teratogen (NIOSH) . Revision Date: 1/85 KEY ca Approximately STEL Short Term. Exposure~evel na Not applicable TLV Threshold Limit Value C Ceiling TWA Time Weighted Average PEL Permissable Exposure Level BuAc :~ Butyl Acetate NSC National Safety Council ("Fundamentals of Industrial Hygiene"; 1983) OHS Occupational Health Services ("Hazardline") · Medical C ndi ion Aggravated by Exposure Preclude from exposure individuals, with diseases of liver, kidneys and central nervous system. Simultaneous exposure to chloroform and alcohol can increase the toxic hazards of chloroform. - Emergency First Ai____d. Inhalation: Immediately remove to fresh air. If not breathing, administer mouth-to-mouth resuscitation. If there is no pulse, administer cardiopulmonary resuscitation (C PR). Contact physician immediately. Eye Contact: Rinse,'with copious amounts of water for at least 15 minutes. Get emergency medical assistance. Skin Contact: Flush thoroughly for at least 1~5 minutes. Wash affected skin with soap and water. Remove contaminated clothing and shoes; .. Wash clothing before-re-use and discard shoes.. Get emergency medical assistance. Ingestion:' Call .local Poison Control Center for assistance. Contact physician immediately. Never induce vomiting or give anything by mouth to a victim unconscious or having convulsions. Note to Physician ~A~nual physical exams of-exlSose-d-Pefsons should'make special reference to li~Ter and kidney function. VI. Safety Measures and Equipment Ventilation: Adequate ventilation is required to protect per,sonnel from exposure to chemical vapors exceeding the PEL. The choice of ventilation equipment, either local or general, will depend on conditions of use, quantity of material, and other operating parameters. Respiratory: Use approved respirator equipment. Follow NIOSH and equipment manufacturer's recommendations to determine appropriate equipment (air-purifying, air-supplied, or self-contained breathing ~, apparatus). Eyes: Safety glasses are considered minimum protection. Goggles or face shield may be necessary depending on quantity of material and conditions of use. 5kin:- Protective gloves and clothing are recommended. The choice ~ of material must be based on chemical resistance and other user ~*, requirements. Generally, neoprene or Buna-N 'offers acceptable "--'~ chemical resistance.. Individuals who are' acUtelY and specifically " Sensitive~ to chloroform may require additional protective equipment. LABORATORIES, InC. J. J. EGLIN, REG. CHEM. ENGR. 4100 PIERCE RD., BAKERSFIELD, CALIFORNIA 93308 PHONE 327-4911 June 27, 1988 Management Safety and Health Policy People are our most importan~ asset-their safety is our greatest responsibility. It is the policy of our company that every employee is entitled to a safe and healthful place to work. When a person enters the 'employ of our company, he or she has a right to expect to be provided with a proper place in which to work, as well as proper machines and tools with which to do the job, and that the employee will be able to devote his or her energies to the work' without undue danger. Only under such circumstances can the association between employee and employer be mutually profitable and harmonious. It is our desire and intention to provide a safe workplace, safe equipment, proper materials, and to establish and insist on safe methods and practices at all times. It is a basic responsibility for all to make the SAFETY of human beings a part of their daily, hourly concern. This responsibility must be accepted by each one who conducts the affairs of the com- pany, regardless of the capacity in which he or she function. Employees are expected to use the SAFETY equipment provided. Rules of conduct and rules of SAFETY shall be observed. SAFETY equipment must not be destroyed or abused. The joint cooperation of employees and management in the observance of this policy will provide safe working conditions and accident-free performance to our mutual advantage. We consider the SAFETY of our personnel to be of first importance, and we ask your full cooperation in making this policy effective. Chief Operating Officer LABORATORIES J. I. EGIIN, REG. CHEM. ENGII. PETROLEUM MAIN OFFICE: 4100 PIERCE ROAD, BAKERSFIELD, CA. 93308 PHONE 327.491 ltazardous Materials Information What is a "hazardous material"? "ltazardous material" means any material that, because of its quantity, concentration, or physical or chemical characteristics, poses a signi- ficant present or potential h~zard to human health and safety or to the environment if released into the workplace or the environment. "Hazardous materials" include, but are not limited to, hazardous sub- stances, hazardous waste, and any material which a handler or the admin- istering agency has a reasonable basis for believing that it would, be injurious to the health and safety of persons or harmful to the environ- ment if released into the workplace or the environment. .What is "release"? "Release means any spilling, leaking, pumping, pouring, emitting, emptying, discharging, injecting, escaping, leaching, dumping, or dis- posing into the environment, unless permitted or authorized by a regu- latory agency. What is "threatened release"? "Threatened release" means a condition creating a substantial proba- bility of harm, when the probability and potential extent of harm make it reasonably necessary to take'inunediate action, to prevent, reduce, or mitigate damages to persons, property, or the environment. In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify our local fire department and the State Office of Emergency Services as required by law. LABORATORIES, Inc. J. J. EGLIN, REG. CHEM. ENGR. PETflOL~U¥ 4100 PIERCE RD., BAKERSFIELD, CALIFORNIA 93308 PHONE 327~4911 City of Bakersfield Date RepOrted: 7/18/88 Fire Department Date Received: 7/11/88 2130 "G" Street Laboratory No.: 5079-1 Bakersfield, CA 93301 Attention: Ralph E. Huey Sample Description: Possible diesel fuel ~ngle~ Distillation °F Initial Boiling Point 397~ 5% 449 10% 467 20% 488 30% 502 40% 514 50% 524 60% 535 70% 5~6 80% 559 90% 578 95% 595 End Point 617 Recovery 98.5% Distillation indicates that this :i:s a diesel fuel. B C LABORATORIES, INC. ~x~. ~./ Eg 1 i~PY -- ~ NITRIC ACID.'70% -2- Material Safety Data Shee~ Fire and Exulosion SECTION 2 Information Emergency Telephone Number Hallinckrodt Inc. 31&-982-5000 Fire: Not combustible, but substance is a strong oxidizer Science Products Division and its heat of reaction with reducing agents or P.O. Box H combustibles may cause ignition. Can react with Paris, Kentucky hO]61 metals to release flammable hydrogen gas. Effective Date: 08-21-85 PRODUCT IDENTIFICATION: Explosion: Reacts explosively with combustible organic or readily oxidizable materials such as: alcohols, Synonyms: Aqua Fortis; Azotic Acid; Nitric Acid 70% turpentine, charcoal, organic refuse, metal powder, hydrogen sulfide, etc. Formula CAS No.: 7697-37-2 Nolecular Ueight: 63.00 Fire Extinguishing Nedia: If involved in a fire, use water spray. liazardous Ingredients: Chemical Formula: HNO3 Hoc Applicable Special Information: Increases the flammability of combustibl~, organic and readily oxidizable materials. In the event pRECAUTIONARY HEASURES of a fire, wear full protective clothing and NiOSH-approved self-contained breathing apparatus DANGERI STRONG OIIDIZER. CONTACT UITH OTHER HATERIAL HAY CAUSE FIRE. with full facepiece operated in the pressure demand CAUSES SEVERE BURNS. HAY BE FATAL IF SgALLOgED. HAI~FUL IF INI~LED. or other positive pressure mode. Do not get in eyes, on skin, or on clothing. Reactivity Data SECTION 3 Avoid breathing mist. Use only with adequate ventilation. Stability: Stable under ordinary conditions of use and storage. Cash thoroughly after handling. Containers may burst when heated. Keep from contact with clothing and other combustible materials. Do not store near combustible materials. Hazardous Decomposition Store in a tightly closed container. Products: U~-move end wash contaminated clothing promptly. Ighen heated to decomposition, emits toxic nitrogen This substance is classified as a POISON under the Federal Caustic Poison Act. oxides fumes and hydrogen nitrate, gill react with water or steam to produce heat and toxic and EHEROENCY/FIRST AID corrosive fumes. In case of contact, immediately flush skin or eyes with plenty of water for at Hazardous Polymerization: ~ill no~ occur. least 15 minutes. If swallowed, DO NOT INDUCE VONIT1NG! Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. Incompatibilities: If i~mled, remove to fresh air. If not b~eathing, give artificial respiration. If A dangerously powerful oxidizing agent, concentrated breathing is difficult, give oxygen. In all cases call a physician, nitric acid is incompatible with most substances, SEE SECTION 5. especially strong bases, metallic powders, carbides, hydrogen sulfide, turpentine, and combustible DOT ltazard Class: Oxidizer organics. Physical Data SECTION ~ Leok/Spt~ DiSposal Information SECTION h Appearance: Clear, colorless to slightly yellow liquid. Isolate or enclose the area of the leak or spill. Clean-up personnel should wear Odor: protective clothing and respiratory equipment suitable for toxic or corrosive Suffocating acrid, fluids or vapors. Solubility; lnfinice in water. Small Spills: Flush with water and neutralize with alkaline material (soda ash, lime, etc.). Sewer with excess water. Boiling Point: 122'C (252'F) Vapor Density (Air-I):2-] approximately Larger spills and lot sizes: Helting Point: -34'C (-29'F) Vapor Pressure (mm Hg):62 @ 20'C (68'F) Neutralize with slkaline material, pick up with absorbent material (sand, earth, vermiculite) and dispose in a RCRA-approved waste facility or sewer the neutralized Spaclftc Gravity: 1.il Evaporation Rate:No information found, slurry with excess water if local ordinances allow. Provide forced ventilation to dissipate fumes. Reportable Quantity (RQ)(CgA/CERCLA) : 1000 lb~. Ensure compliance with local, state and federal regulations. -3- -4- Ih_z'.!tltl.__A~d Informattoq ~CTION 5 Occnpqtional Coo{tel Measures SECTIO~ 6 Expos~t~-/llealth Fffects Airborne Exposure Limits: -OSIIA Permissible Exposure Limit (PEL): lnbalation: Corrosive{ Inhalation of vapors can cause breatbln§ 2 ppm (TUA) difficulties and lead to pneu~uonia and pulmonary edema, -ACGIH Threshold Limit Value (TL¥): uhich ~ay be fatal. Other s~upco,ns may include 2 ppm (T~A); ~ppm (STEL) coughing, choking, a~d irt{caY{on o~ ~he nose, Chroa~, and respiratory tract. Vencilavion System: A system of local exhaus~ ts reco~ended re keep employee exposures belou ~he Airborne Exposure Limits. In~est[o~: Corrosive~ S~allowinE nivric acid can cause [~edia~;e ~cal exbaust ven~ilacion Is generally preferred pain and burns of the mouth, [hroa~, esophagus and because lC can control ~he emissions of ~he dust or Kastroin~esLlnal tract, vapo~ a~ l~s source, preventing dispersion o~ tU into the ~eneral ~ork area. Please refer ~o Lhe ACCIH dec.eno, "Induscria! Ventilation, A Hanual o~ Skin Contact: Corrosive{ Can cause redness, pain, and severe skin Reco~ended Practices", mos~ recen~ edition, for burns. Concentrated solutions cause deep ulcers a~d de~ails. stain skin a yellow or yello~-bro~ color. Pesonal Respirators: If ~he TLV Is exceeded, ~ear a supplied air, Eye Contact: Corrosive{ Vapors are irritating and may cause damage (NIOSH Approved) full-facepiece respirator, airlined bood, or to ~he eyes. Splashes may cause severe burns and self-con~ained brea~hinE apparatus. permanent eye damage. Hi{tic acid Is an oxidizer and should nor come tn con~ac~ ~tch cartridges and cannisters cha~ contain oxidizable materials, such as ac[lva~ed charcoal. Chronic Exposure: ~ng-Cer= exposure to concenLra~ed vapors may cause erosion of teeth. ~n~ term exposures seldom occur due Skin ProuecCion: ~ear i~pe~ious protective clothing, including boots, to the corrosive properties of the acid. gloves, lab coat, apron or coveralls ~o prevun~ skin Pre-exis~tn~ Conditions: Eye Protection: Use chemical sa~e~y ~o~[es and/or a full lace shie}d Persons ~iuh pre-exts~in~ skin disorders or eye disease uhere splash{ns is possible. Con~ac~ lenses should may be mo~e susceptible ~o ~he e~[ec~s oE ~his be uorn ~hen ~orkin~ ~[~h chis material. subsLance. Hain~ain eye rash fountain and quick-drench ~acili~ies F{RS~~ in york area. Inhalation: Remove Co fresh air. If nec breaUhin~, sire arCiflclal respiration. [~ brea~hin~ is difficult, live oxygen. Call a physic{an. S[ora~e and Specfal {~formacfoq SECTION ~ Keep in a ~i~h~ly closed concainer, s~ored in a coo[, dry, ventilated area. Pro~ec~ Ingestion: DO NOT INDUCE VO~]TING{ Give large quan~icies o~ ua~er from physical dama[e and dtrec~ sunlishc. o~ milk i~ available, Never sire anyUhin~ by mouth co [solaCe ~rom incompatible substances. Procecu from moisture. a[~ unconsc{ous p~rson. Ce~ medica[ a~encion i~edia~ely. The information contained herein is provided in ~ood f~iuh and ts believed ~o Skin Exposure: In case o~ conLac~, immediauel~ [lush skin uich plenty be correc~ as of ~be da~e hereo~. Ho~ever, Hal[lnckrodc, inc. makes no repre- o~ v~er ~or a~ least 15 minutes ~htle removin~ senca~ion as ~o ~he comprehensiveness or accuracy o~ [he inEorma[ion, l~ is con~amina~ed c[o~hin~ and shoes. Uash c]o~bin~ be[ore expected cha~ indivi, dua]s receivin~ ~he information ~il[ exercise ~heir in- reuse. Thoroughly clean shoes be[ore reuse. Ce[ dependenE Judgment in de~erminin~ its appropriateness for a paruicular medical a~en~lon i~ediauely, purpose. Accordin[ly, Hallinckrodc, inc. will no~ be responsible ~or damages of any kind re~u]cin~ from ~he use of or reliance upon such information. NO REPRESEHTAT[OHS, OR UAR~NTIES, EITHER EXPRESS OR [HPLIED, OF Eye Exposure: ~ash eyes ~{Lh p[ency of ~a~er for a~ leas~ [5 minu[es, HERCtlAHTABIL]TY, FITNESS FOR A PART[CU~ PURPOSE OR OF ~ OTHER lifcin~ [over and upper eyelids occasionally. Ge~ NATURE ARE ~DE ilEREUNDER UITH RESPECT TO TIt~ INFECTION SET FORTtl medical a~en~ion imi~ediaL~ly. HEREIN OR TO THE PRODUCT TO UIIICH THE It{FO~TION REFERS. TOX]~ PAT~ (RTECS, 1982) Inhalation (Rat) I.C50: 24~ ppm SECTION I PRODUCT IDENTIFICATION & E~IERGENCY INFOR~,IATION PRODUCT NAME Acetone CHEMICAL NAME 2-PPopanone CAS # 67-64-1 CHEMICAL FAMILY Ketone PRODUCT APPEARANCE Clear colorless liquid with a characteristic pungent odor. EMERGENCY TELEPHONE NUMBERS: EXXON CHEMICAL AMERICAS 713-870-6000 CHEMTREC 800-424- 9300 SECTION II HAZARDOUS COMPONENTS OF ~IXTURES THE PRECISE C~OSITION OF THIS ~IXTURE IS PROPRIETARY INFORMATION. A MORE COMPLETE DISCLOSURE WILL BE PROVIDED TO A ~H¥SI¢IAN OR N~RSE IN THE EVENT OF A ~EDIC&L EMERCENCY, Not applicable for this product. For additional information see Section III. ;. SECTION III HEALTH INFORMATION AND PROTECTION FIRST AID'& NATURE OF HAZARD ~ EYE CONTACT: Immediately flush eyes with large amounts of water for at l~ast 15 minutes. Get prompt medical attention. Irritating, and may injure ey~ tissue if not removed promptly. INHALATION: Using proper respiratory protection, immediately remove the ~ffected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. High.vapor concentrations are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, a~e anesthetic and may have other central nervous system effects. SKIN CONTACT: Flush with large amounts of water: use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. Frequent or prolonged contact may irritate and cause dermatitis. Low order of toxicity. INGESTION: First aid is normally not required. Minimal toxicity. ACUTE TOXICITY DATA IS AVAILABLE UPDN REQUEST PERhtISSIBLE EXPOSURE LIMIT; OSHA REQUIRES (29CFR1910.1000): A TWA of 1000 ppm (2400 mg/m3) for Acetone. THRESHOLD EXPOSURE LIHI~;~ ACGIH RECO[~4ENDS: A TWA of 750 ppm (1780 mg/m3), and a STEL of 1000 ppm (2375 mg/m3) for Acetone. ,,[ DA~E COMPILE3, ~¥EVE~, NO RE~SENTAT!ON, ~RR~NT,' OR GUARANTEE IS ~&DE AS TO ITS ACCUraCY, ~ELI~BiLITY O~ C~=LETE~ERS, IT IS T~E USER'S RES;ON$1BiLiTY TO SAI1SFV HIMSELF AS TO THE SU1TASILITY AW~ COMPLETENESS OF SUCH INaORU&TiON FO~ HIS O~N PARTICULAR USE. WE DO ~GT ~CCEPT LiAEILIT¥ FOR A~Y LOSS OR ~&CE TNAT MAY OCCUR FR~ THE USE OF ~HIS IN;O~MATIO~ ~3~ DD ~% OFFER ~&RRANTY AC.~!NST pATENT tNFRi~OEHENT. SUI~RIC ACID 93% Fi.we and Exnlosion SECTION 2 ® ~aterla~ Ssfet~ Data Sheet Information Emergency T~lephone Number Nallinckrodc Inc. 314-982-50OO Fire: Hot combustible, but substance is a strong oxidizer Science Products Division end its heat of reaction with reducinB agents or P.O, Box H combustibles may cause ignition. Reacts with most Paris. Kentucky 40361 metals releasing flammable, potentially explosive ~ffective bate: 08-27-85 hydrogen gas. ~ODIJCT ID~HTIPICATION: Explosion: Not considered to be an explosion hazard under Synonyms: Oil of vitriol; Babcock acid normal conditions. Pormula.CAS No.:. 7664-93-9 Nolecular Weight: 98.07 Hazardous Inggedients: 'Chemical Formula: H2SO4 Fire Extinguishing Hedia: Dry chemical, foam or carbon dioxide. Water spray Not applicable, may be used to keep fire exposed containers cool. PRECAUTIONARY NEASURES Special Information: In the event of a fire, ~ear full protective clothing and NiOSH-approved self-contained breathinl ~ARHING! CAUSES S~VERE BURNS. NAY BE FATAL IF SUALLOUED. HARHFUL IF INI~LED. apparatus ~lth full facepiece operated in the pressure demand or other positive pressure mode. Do not Eec in'eyes, on skin, et on clothinE. Do not breathe mist. ~eep container closed. ~epctivitv Data SECTION 3 Use only with adequate ventilation. "- Uash thoroughly aftet handlinE, Stability: Stable under ordinary conditions of use and storage. This substance is classified as a POISON under the Federal Caustic Poison Act. EHERCENCY/FIRST AID Hazardous Decomposition In all cases call a physician. Products: In case of contact, immediately flush skin or oyes ~ith plenty of water for at Toxic fumes of oxides of sulfur. Ulll react ~lth least 15 minutes. If svallowed, DO NOT INDUCE VOHITING! Give large quantities of ~ater or steam to produce toxic and corrosive fumes. ~ater. Never five anytt~ing by mouth to an unconsciotis person. If inhaled, remove Reacts ~lth carbonates to generate carbon dioxide to fresh air I£ not breathing, siva artificial respiration. If breathing is Ess, and ~lth cyanides and sulfides co form · poisonous hydrogen cyanide and hydrogen sulfide difficult, five oxy&on, respectively. SEE SECTION 5. DOT Hazard Class: Corrosive Haterial Ilazardous Polymerization: Will not occur. Pltysical Data SECTION 1 Incompatibilities: Water, bases, organic material, halogens, metal acetylides, oxides and hydrides, strong oxtdizinE Appearance: and reducinE agents and many other reactive Colorless, oily liquid, substances. Odor: Odorless. Solubill£y: Hlscible ~lth rater - libecatin8much heat. C~k/Seill. Disposal Information SECTION & Boiling Point: 279°C ($34'F). Vapor Density (Air-I):3.4 Dike and cover leakin8 or spilled liquid ~ith dirt, vermiculite, kitty-litter or Nell/hr Point: .35°C (.31°F). Vapor Pressure (mm ltg):l @ 1~5.8 C ocher inert absorbent. Cover spill with sodium bicarbonate or soda ash and mix. (249.4 P). Clean-up personnel require protective clothing and respiratory protection from vapors and mists. Neutralized ~aste may be containerized and disposed in a RCRA Specific Gravity: 1.835 Evaporation Rate:No Information found, andappr°veddiscard~asteto sever.disp°sal facility. Plush area of spill uith dilute soda ash solution Reportable Quantity (RQ)(C~A/CERCLA~ : IO00 lbs. Ensure compliance ~lth local, state and federal regulations. tlealrh Ha~a~L~_~fprmatlon SECTION ~ Occunational Con~Fo~ Neasures SECTION_~ A. Exvosu~Health E~fe~ts Airborne Exposure Limits: -OSHA ~ermissible Expiosure Limit (PEL): Inhalation: Inhalation produces damaging effects on the mucous I mg/m~ (T~A), membranes and upper respiratory tract. Nay cause lu,~g -ACCIH Threshold Limit Value (TLV): edema. Symptoms may include irritation of the nose and I mS/m~ (~A). throat, and labored breathins. Ventilation System: A'sys~em of local exhaust is reco~ended to keep employee exposd~es belo~ the Airborne Exposure Limits. Ingestion: Corrosive. S~allo~in~ can cause severe burns of the ~cal exhaust ventilation Is Eenerally preferred mouth, throat, and s~omach, leadinE ~o death. Can cause because it can control the emissions of the dust sore ~hroa~, vomiCinE, diarrhea, vapor a~ its source, preventIn~ dispersion of lc into the Eene~al ~ork area. Please refer ~o the ACGIll doc~en~, '!ndus~rial Ventilation, A Hanna1 of Skin Con,acC: Corrosive. S~pcoma of redness, pain, and severe Lum Reco~ended Practices', most recent edition, can occur, details. Eye Con.act: Corrosive. Splashes can cause blurred vision, redness, Pesonal Respira~ora: If the TLV is exceeded a full faceptece chemical pain and severe ~lssue burns. (NIOSH Approved) carCrid~e respira~or may be ~orn, in ~eneral, up co 100 ~imes the TLV or th~ maxim~ uae concentration specified by the respirator supplier, ~hichever Chronic ~xposure: ~nS~erm exposure to mist or vapors may cause damaie less. Alternatively, a supplied air full ~aceptece to teeth, r~spira~or or ai~lined hood may be ~orn. A~sravation of Skin Pro~ection: Year impe~lous pro,active clothins, includin~ Pra-existin~ Conditions: Persons ~i~h pre-exis~ins skin disorders or eye sloves, lab coat, apron or coveralls co preven~ skin problems or impaired respiratory function may be more contact. susceptible Co the effects of ~he substance. Eye Protection: Use chemical safety SosEles and/or a full face shield ~here splashinE Is posslble.Con~ect lenses should be yom ~hen vorklns ~ith chis ma~erial. Inhalation: Remove to f~esb air. If not brea~hinS, sire artiliclal Haincain eye ~ash fountain and quick-drench facilities respiration. If breaChinE Is difficult, ~/ve oxysen, in ~ork area. Call a physician. Inses~lon: If s~allo~ed, ~ ~OT induce vomi~lnE. Give larse ~ra~e and Svecial ]~(o[matioq SE~!ON ] quan~lties of ~ater o~ milk if available. Call a physician l~edtacely. Never sire anythin~ by mouth ~o S~ore in a cool, dry, ventilated sCoraEe area ~lth acid resistant floors and Eood an unconscious person, draiaaEe. Protect from physical debase. Keep out of direct sunlisht and a~ay from heat, ~ater, and incompatible ma~erials. Do not ~ash ou~ con~ainer and use It for o~her purposes. ~en dllutin~, al~ays add the acid co ~a~erl never add ~ater to ~he Skin Exposure: In case of contact, l~ediately flush skin ~ich plenty acid. of ~ater for aC least 15 minu~es ~hile removins contaminated clo~hinE and shoes. Call a physician. E~e Exposure: ~ash eyes ~l~h plenty of ~ater [or a~ least 15 minutes, The information contained herein Is provided In ~ood faith and Is believed to lifcins lover and upper eyelids occasionally. Get be correct as o~ the date hereof. Ho~ever, Hallinckrod~, Inc. makes no repre- medical attention l~edtataly, se~atlon as ~o ~he comprehensiveness or accuracy oi the information. Ic Is expected ~ha~ individuals receivin~ the information vi11 exercise their in- dependen~ judEmentin de~ermlnin~ its appropriateness for a particular purpose. Accordingly, Hallinckrodt, Inc. ~ill no~ be responsible for damaEes ~ ~ DATA (RTECS, 1982) o[ any kind resulCin~ from ~he use of or relianceupon such in[ormacion. ~O REPRESENTATIONS, OR ~TIES, EITHER ~XPRESS OR IHPLIED, OF O~al rat 1~50:~140 ms/kS. HERCI~TABILI~, FITNESS FOR A P~TICU~ PORPOSE OR OF A~l OTHER I~halaCion Guinea PiE LCSO: 18 mS/m~. NATURE ARE ~DE H~REUND~R ~ITll RESPECT TO THE I~TIOH S~T FORT~ II~REIN OR TO THE PRODU~ TO ~tlCii THE INFO~TION REFERS. BAKERSFIELD CITY FIRE DEPARTMENT · D. # FORI~ 4A-1 Page 5 :of 7.- NON-TRADE SECRETS HAZARDOUS MATERI ALS I NVENTORY BUSINESS NAME: B, C, LABORAT0~{I~$; INC, OWNER NAME: J; J. E~,I.IN FACILITY UNIT #: ADDRESS: 4100 PIERCE R0~ ADDRESS: 36t7 REDLANDg DRIVE FACILITY UNIT NAME: ~IN LAB, . PRONE t: 327-~911 PHONE ~: 871-07~7 .. [OFFICIAL USE CFIR$ CODE I a 3 4 5 6 ~ 8 . YPE MAX ANNUAL CUNT USE LOCATION IN THIS · BY HAZARD D.O.T ' :ODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. C.EMI~AL OR COMMON NAME CODE GUIDE. F I 2 ..G~ 09 99 LE~. TO STO~GE C~INET 100 HEPT~E FLLQ P ~ 2 4 G~ 09 99 " " " ~00 PETROLE~ ET~R FLLQ P I 2 G~ 09 99 " " " lO0 CHLOROBENZI~ FLLQ P I 3 G~ 09 99 " " " lO0 DIC~ORO ~T~ O~ F I 2 G~ 09 99 " " " 100 ETH~ ACETATE FLLQ P 1/2 I G~ 09 99 " " " 96 S~FURIC ACID ~ C~T P 1/2 I G~ 09 99 " " " 70 NITRIC ACID OXID P 2 24 FT3 04 99 FRONT INSTK~NT ROOM lO0 NITROGEN NFLG F I 2 FT3 04 99 " " " lO0 O~GEN OXID * ' F~ 1 12 FT3 04 99 " " " 100 NITROUS OXIDE NFLG. ~ 3 30 FT3 04 99 " " " lO0 ~N ~ NFLG P 1 2 FT3 04 99 ~ENTEK SOUTH 100 CO~SSED AIR. OXID P 1 l0 FT3 04 99 " " 100 NITROGEN NFLG P I 8 FT3 04 99 " " lO0 ACET~ENE FLGS P 3 12 FT3 04 99 C~NTER INSTR~NT ROOM 100 NITROUS OXIDE NFLG NA~4E F.J. BEESLEY TITLE:S~ETY ~O-ORDINATOR S-ONATURE: , DATE:Jr,Wv EMERGENCY CONTACT: J. J. EGLIN TITLE :. O~ER PHON~ ~ BUS HOURS: 327-~911 AFTER BUS HR$: 871-0747 E~'ERGENCY CONTACT: DAN SCH~TZ TITLE: LAB.'MANAgeR PHON~ ~ BUS HOURS: 327-4911 PRINCIPAL BUSINESS ACTIVITY: AN~YTIC~ LABO~TOgY AFTER BUS HRS: 589-9625 : BAKERSFIELD CITY FIRE DEPARTMENT · D. # FORM 4A-1 Page 3 ,.ui' ?-- NON-TRADE SECRETS HAZARDOUS MATERI ALS I NVENTORY BUSINESS NAME: B.,.C. LABORA%ORIES; INC. OWNER NAME:_J. 3. EC. IJN FACILITY UNIT #: ADDRESS; 4100 PIERCE RO~ ADDRESS:~617 REDI.ANDR D~VE FACILITY UNIT NA~E: ~IN LAB. CITY, ZIP: ~ERSFIELD, CA ~3308 CITY,ZIP: BA~ERRFTEI,D: CA q~fif PHONE ~: 327-4911 PHONE ~: ~71-0747 , _ [OFFICIAL USE CFIRS CODE 1 2 3 4 5 6 V 8 9 '10 ODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT, WT..,., CHEMI~A[ OR COMM, ON NAME CODE GUID P 20 25 LBS 1] 99 BACK CENTER NORTH 100 POTASSI~ C~O~TE O~ 40 50 LBS I ] 99 " " " 100 FE~OUS S~FATE O~ P 20 25 LBS I I 99 " " " 100 ~ONI~ S~FATE O~ P 20 25 LBs 11 99 " " " 100 ~ONI~ C~ORIDE P 20 40 LBS I I 99 " " " 100 SODI~ BIC~ONATE O~ P 25 25 LBS I I 99 " " " 100 ~GNESI~ NIT~TE OXID P 1/2 1 LBS 09 99 SO. CENTER STOOGE 74 C~CI~ HYDROXIDE O~ P 3 3 LBS 11 99 " " " 100 ~ONI~ ACETATE O~ P 12 ]2 LBS ] ! 99 " " " " 100 CITRIC ACID 'O~ ~ 4 8 G~ '09 99 " " " 60 ISOPROP~ ~COHOL FLLQ P 1' ] G~ 09 99 " " " 70 NITRIC ACID ~ OXID P ] ] G~ 09 99 " " " 96 S~FURIC ACID C~ P 3 3 G~ 09 99 ~AR STOOGE NORTH 100 ~T~OL FLLQ P 5 8 G~ 13 99 " " " 100 PENT~E FLLQ P 10 18 G~ 13 99 '" " " 100 DENATU~D ~COHOL FLLQ NAME: F. 3. BEESLEY TITLE:SAFETY QO-ORDINA~OR, SIGNATURg: ~ DATE:July q-lqR7 EMERGENCY CONTACT: J. J. EGLIN TITLE: 0~g~ PHONE 9 BUS HOURS: 327-49ll AFTER 8US HRS: 87]-0747 EM~RGENCY CONTACT: DAN SCH~TZ TITLE: LAR.'WANA~RR PHONE ~ BUS HOURS:· 327-491] PRINCIPAL BUSINESS ACTIVITY: ~YTIC~ LABO~TORY AFTER BUS HRS: 589-9625 MATERIAL SAFETY DATA SHEET · C..1-1F. JV~C_.AI_5 J.T. Baker Chemical Co., 222 Red School Lane, Phillipsburg, N.J. 08865 CHEMICAL NAME FORMULA Methanol CH30H SYNONYM OR CROSS REFERENCE CAS NO: 6-7561 Methyl Alcohol Wood Alcohol MATERIAL NATURE OF HAZARD BOILING POINT MELTING 'POINT 64,. 5°C. VAPOR PRESSURE SPECIFIC GRAVITY 0.792 VAPOR DENSITY (AIR=l) PERCENT VOLATILE By VOLUME (%) 1.11 WATER SOLUBILITY -... EVAPORATION RATE Complete ( = 1) APPEARANCE Clear, colorless fla~ble, poisonous Mobile liquid. , _.__-- ~ ..... --' ~' .... --~ --~--i -" " - - - ..... ~ -Trl ....... FLAS.~ POINT (method used) · I FLAMMABLE LIMITS I Lower '1 Upper l~. ~ c. (open c~p)I FIRE EXTINGUISHING MEDIA ""]:)t'~ c~em$cal, ca=boa d$o~lcte, alcohol ~o~. SPECIAL FIRE-FIGHTING PROCEDURES ~e= sg=~ a~e~c b~t ~ate= s~o~d be ~se~ to keep ~$=e-e~ose~ co~t~$ae=s coo~. UNUSUAL FIRE AND EXPLOSION HA~RD THRESHOLD LIMIT VA~UE 200 ~; 260 m~/m~ sc~-m~s ~50:9800 H~LTH HA~RDS FIRST AID PROCEDURES -~ sw~l~d, '$~ co~c$ous, ~ve o~en or apply arC~f~cial respiration. Call a physician. STABILITY CONDITIONS TO AVOID STABLE Keep away from hea~:, sparks, fla~e. INCOMPATABILITY (materials to avoid) Chromic Anhydride; Iodine; Ethyl Alcohol, Mercuric Oxide; Lead Perchloric; Potassium Hydroxide & Chloroform; Sodium Hydroxide and Chloroform. HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS MAY OCCUR CONDITIONS TO AVOID POLYMERIZATION WILL 'NOT OCCUR Z SPILLS Eliminate all cources of t~=/tion. Absorb on sand, earth, or vermiculi:e. 'Carefully sweep up and remove. Alternatively use J.T.Baker's Fl-~,-ble Solvents Spill Clean-Up Kit (Product No. 4437). DISPOSAL Atomize into a furnace if local en%-ironmental regulations pe~t. RESPIRATORY PROTECTION (sl3ecify tyl3e) Have all-~)ur~)ose canister amsk erecT, labia. VENTILATION LOCAL I SPECIAL X MECHANICAL (general) OTHER PROTECTIVE GLOVES I EYE PROTECTION Rubber ~loves ! Face Shield OTHER PROTECTIVE EQUIPMENT Approved workins clothes. STORAGE & HANDLING Keep away from heat, sparks, flame. Keep in tightly closed container. Avoid breathing vapor. Wash thoroughly after handling. Oats issued: ~ Approvecl 0y ~__ Manager, Quality Asaurar~e Revision No. & Date issued:. Tl~e Informatlpn provided In this Material Safety Data Sheet has I~en complied from out experience and data presented In various technical i~uhllcatlona. It is the users responsibility to determine the saltahlllty of this information for the adoption of safety precautions as may I:)e nece~ty. We reserve the right to revise Material Safety Data Sheets from time to time as new technical information I~ecomas availal=le. The ............. ~ h??_ t_n.e_rssponsl~lllty to Co_n.t._a.ct the compare/to make sure that the sheet is the latee., t__o.ne.l_sau.. .~L .... MATERIAL. SAFETY DATA SHEET CHEA41CAL_% J.T. Baker Chemical Co., 222 Red School Lane, Phillipsburg, N.J. 08865 CHEMICAL NAME FORMULA >O Pent:ane CH3 (CH2) 3CH3 ~z SYNONYM OR CROSS REFERENCE CAS NO: 109-66-0 n-Pent:ane ;Amyl hydride MATERIAL NATURE OF HAZARD BOILING POINT MELTING POINT 36°C o -130oc. VAPOR PRESSURE SPECIFIC GRAVITY' '@ 25°C. 500 ~q$ 0.63 VAPOR DENSITY (AIR=l) PERCENT VOLATILE BY VOLUME (%) _. 2.5 100% WATER SOLUBILITY EVAPORATION RATE Very Soluble i ( = 1) APPEARANCE Liquid, colorless, with faint gasoline odor. FLASH POINT (method used) Upper -50°C. (cc) 1.4% 8.3% FIRE EX3qNGUISHING Wa~er spray, alcohol foam, dry chemical, carbon dioxide. Nat:er MEDIA may be ineffective. SPECIAL FIRE-FIGHTING PROCEDURES Flashback along vapor trail may occur. Containers may explode when heat:ed. UNUSUAL FIRE AND EXPLOSION HAZARD ~evere 'explosion hazard when exposed to heat: or flame, shock can shat:er metal containers and release con~en=s. S~a=ic dischar~e from =he human can cause THRESHOLD LIMIT VALUE 500 ppm HEALTH HAZARDS ~ Harmful if inhaled. May'be ~rritating to eyes. ~IRST AID PROCEDURES in case ot contact, flush eyes or skin wi:h plenty of water ~or at least 15'm~nutes. If inhaled, remove ~o fresh air. If no: breathing, give ~art:ificial respiration. If breathing is difficult, give oxygen. STABILITY INCOMPATASILITY (materials to avoid) Strong oxtdtztn8 asent. HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide; carbon dioxide and other hydrocarbons. -' HAZARDOUS CONDITIONS TO AVOID POLYMERIZATION SPILLS Eliminate all sources of i~nition. Absorb on sand, earth or vermiculite. Carefully sweep up and remove. Flush spill.area w~th water~Alternat, ively use J.T.Baker's Fl~m-mble Solvent Spill Clean-Up Kit or Solusor~WSolvent Absorbent. DISPOSAL Burn absorbent ~-~th other flammable material. Atomize liquid into an incinerator, providing local environmental reg, ulations pertain. RESPIRATORY PROTECTION ($1~ecify tyl~e) Self-cont:ained breathing apparatus. VENTILATION I LOCAL ~ain=ain work room ~ Exhaust levels below 600 ppmI MECHANICAL (general) I General ventilation PROTECTIVE GLOVES J EYE PROTECTION lubber gloves I Full face shield or goggles OTHER PROTECTIVE EQUIPMENT Full protective clothing; eye wash; safety shower. STORAGE & HANDLING Keep away from heat, sparks, hot metal surfaces and open flame.' Keep in tishtly closed container. Protect against physical d~m~$e. Static ground. Harmful narcotic in high concentrations. May be.rapidly fatal. Will cause dizziness or difficult breathing. Use with adequate ventilation. Avoid prolonged or repeated contact ~lth skin. ~. ~. Mitchell Date issue: Ag~r~ Dy __ M~ag~, Ouall~ Assurance R~iaion NO. & Date Issue: ~e info.scion 0r~id~ in t~is Material Safe~ Data Sh~t h~ a~n comoil~ from our e~ehce an~ Oats greaent~ in various t~nntcal ~u~li~tion~ It is t~e usam res~nsi~ili~ to dateline t~e suita~ill~ of t~is information for t~e ado~tlofl of safe~ 0r~autions ~ ma~ Oe n~essa~. We reae~ the dg~t to revise Material Sate~ Data Sh~ts t~m time to time ~ n~ t~nic~ info.scion O~omes a~ailaDle. ~e us~ ~as t~e ~onsi~lli~ to contact the comoany to m~e sure that t~e an~t Is the latest one issu~ PHOSPHORIC ACID -2- Material Safety Data Sheet Fir~ and Explosion SECTION 2 InfdrmatioD Emergency Telephone Number Mallinckrodt Inc. 314-982-5000 Fire: Not considered to be a fire hazard. Science Products Division I Contact with most metals c~uses formation of P.O. Box M t flammable and explosive hydrogen gas. Paris, Kentucky 40361 Effective Date: 09-05-85 Explosion: Not considered to be an explosion hazard. ~ODUCT IDENTIFIC6TION; llnOnyms: Ortho-phosporic acid; white phosphoric acid Fire Extinguishing Media: ~$e any means suttsble for extinguishing surrounding ' { fire. Water sprey may be used to keep fire exposed '~mula CAS No.: 7664-38-2 Molecular Weight: 98.00 ~ containers cool. If water is used, use in abundance ' to control heat and acid build-up. Hazardous Ingredients: Chemical Formula: H3PO4 Not applicable. Speiiai Information: In the event of a,£ire, wear full protective clothing and NIOSB:approved self-contained breathing · apparatus with full facepiece operated in the PRECAUTiONAry ~EASURES pressure demand or other positive pressure mbde. ' DANGERI CAUSES SEVERE BURNS. HARMFUL IF SWALLDWED OR INHALED. ) .... Avoid contact with eyes, skin and clothing. Rea~tivitv Data ~ECTION 3 . Keep container closed. ~ Use with adequate ventilation. Stability: Stable under ordinary conditions of use and storage. Avoid breathing mist. ! lo -U Substance can supercool without· crystallizing. Wash thoroughly after handling. ...... Haz -' · rd s Decomposition EMERGENCY/FIRST AID Products: Toxic fumes of phosphorous oxides. - In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. If swallowed, DO NOT INDUCE VOMITING[ Give large quantities of Hazardous Polymerization: Will not occur. water or milk if available. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If / , . breathing is difficult, ~ive oxygen. Incbmpatibilities: Strong caustics, metals, sulfides, and sulfites. A In all cases call a physician. } strong mineral acid,' contact with water can cause SECTION 5. 'f liberation of much heat and violent· spattering. DOT Hazard Class: Corrosive Material ~e~k/Soil1 Dlspo~a~ InformatioB SECTION 4 Physical Data SECTION % Dik~ and cover leaking or spilled liquid with dirt, vermiculite, kitty-litter or Appearance: Clear, colrless syrupy liquid, other inert absorbent. Cover spill with sodium bicarbonate or soda ash and mix. Clean-up personnel require protective clothing and respiratory protection from Odor: Odorless. vapors and mists. Neutralized waste may be containerized and disposed in a RCRA approved waste disposal facility. Flush area of spill with dilute soda ash solution Solubility: Miscible in all proportions in water, and' discard to sewer. · Boiling Point: 85%:75%: 135°C158°C (275°F)(316'F) Vapor Density (Air-I):3.4 Rept rtable Quantity (RQ)(CWA/CERGIA) :dSO00 lbs. Ensure compliance with local, state an federal regulations. Melting Point: 85%: 21'C (70'F) Vapor Pressure (mm Hg):@20°C (68°F) 75%: -17.5'C (-0.5'F) 85%: 2.16 75%: 5.65 Specific Gravity 85%: 1.69 75%: 1.58 Evaporation Rate:No information found. Density 85%:14.08 75%: 13.16 -3- -4- Health Hazard Information ~ECTION 5 Occupational Control Measures SECTION 6 A, Exposure/Health Effects Airborne Exposure Limits: -OSHA [ermlssible Exposure Limit (PEL): 1 mg/m~ (TWA) Inhalation: Inhalation is not an expected hazard unless misted or -ACGIH Threshold Limit Value (TLV): heated to high temperatures. Mist or vapor inhalation 1 mg/m3 (TWA) 3 mg/m3 (STEL) can cause irritation to the nose, throat, and upper respiratory tract. Severe exposures can lead to a chemical pneumonitis. Ventilation System: A system of local exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred Ingestion: Corrosive. May cause sore throat, abdominal pain, because it can control the emissions of the dust or nausea, and severe burns of the mouth, throat, and · vapor at its source, preventing dispersion of it into stomach. the general workarea. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for Skin Contact: Corrosive. May cause redness, pain, and severe skin details. burns. Pesonal Respirators: If the TLV is exceeded a full facepiece chemical Eye Contact: Corrosive. May cause redness, pain, blurred vision, eye (NIOSH Approved) cartridge respirator may be worn, in general, up to burns, and permanent eye damage, times the TLV or the maximum use concentration specified by the respirator supplier, whichever is Chronic Exposure: No information found, less. Alternatively, a supplied air full facepiece respirator or airlined hood may be worn. Aggravation of : Pre-existiNg Conditions: Persons with pre-existing skin disorders or eye Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls to prevent skin problems, or impaired liver, kidney or respiratory contact. function may be more susceptible to the effects of the substance. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Contact lenses should not be worn when working with this material. B. FIRST AID Maintain eye wash fountain and quick-drench facilities Inhalation: Remove to fresh air. If not breathing, give artificial in work area. respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion: If swallowed, DO NOT induce vomiting. Give large quantities of water or milk if available. Gall a Storaie and Special Ipformation SECTION ? physician immediately. Never give anything By mouth to an unconscious person. Keep in a tightly closed container. Protect from physical damage. Store in a cool,dry, ventilated area away from sources of heat, moisture, incompatabilities, and direct sunlight. Corrosive to mild steel. Store in rubber lined or 316 Skin Exposure: In case of contact, immediately flush skin with plenty stainless steel designed for phosphoric acid. of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Call a physician immediately. ****************************************************************************** The information contained herein is provided in good faith and is believed to . be correct as of the date hereof. However, Mallinckrodt, Inc. makes no repre- Eye Exposure: Wash eyes with plenty of water for at least 15 minutes, sentation as to the comprehensiveness or accuracy of the information. It is lifting lower and upper eyelids occasionally. Get expected that individuals receiving the information will exercise their medical attention immediately, dependent judgment in determining its appropriateness for a particular purpose. Accordingly, Mallinckrodt, Inc. will not be responsible for damages of any kind resulting from the use of or reliance upon such information. C. TOXICITY DATA (RTECS, 1982) NO REPRESENTATIONS, OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO THE INFORMATION SET FORTH Oral rat LDSO: 1530 mE/kg HEREIN OR TO THE PRODUCT TO WHICH THE INFORMATION REFERS Skin rabbit LD50:2740 mE/kg - ****************************************************************************** Aquatic toxicity rating TLm96:1000-10 ppm -3- -&- 'Health Hazardo~liLiO~il~,j[on SECTION ~ Occuvational Control Heasures ~ECTION 6 A. Exoosure/~ Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL): 50 ppm (T~A) (A~monia) Inhalation: Hay cause irritation to the respiratory tract, symptoms -ACGIM Threshold Limit Value (TLV): may include coughing, sore throat, and labored 25 ppm (T~A); 35 ppm (STEL) Ammonia breathing. High concentrations may cause laryngitis, tracheitis, pulmonary edema, chest pains, or pneumonitis. Ventilation System: A system of local exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. IngesCl0n: Toxicl May cause corrosion to the esophagus and stomach Local exhaust ventilation is generally preferred with perforation and peri~onitis. Symptoms may include because it can control the emissions of the dust or pain in tho mouth, chest, and abdomen, with coughing, vapor at its source, preventing dispersion of it into vomitint and collapse, the general work area. Please refer to the ACGIH document, 'Industrial Ventilation, A Hanual of Recommended Practices', moat recent edition, for Skin Contact: Nay cause skin burns with vesication, details. Eye Contact: Vapors may cause irritation. Splashes may cause severe Pesonal Respirators: If the TLV is exceeded, a dust/mist respirator with pain and eye injuries such as glaucoma, corneal scars, (NIOSH Approved) chemical go~gles may be worn, in general, up to ten iris atrophy, and ca~aracte, times the TLV. Consult respirator supplier for limitations. Alternatively, a supplied air full facepiece respirator or airlined hood may be worn. Chronic Exposure: No information found. Skin Protection: Wear i~pervious protective clothing, including boots, Aggravation of gloves, lab coat, apron or coveralls to prevent skin Pre-existing Conditions: Persons with pre-existing eye disorders or impaired contact. respiratory function may be more susceptible to the effects of this material. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Contact lenses should not be worn when working with this material. g. FIRST AID. Maintain eye wash fountain and quick-drench facilities Inhalation: Remove to fresh air. If not breathing, give artificial in work area. respiration. If breathing is difficult, give oxygen. Call a physician. Storage and Soecial Information SECTION 7 Ingestion: Give several glasses of water to drink to dilute. Vomiting may occur spontaneously, but do not induce, Keep in a tightly closed container, stored in a coo], dry, ventilated area. Get medical attention immediately. Protect against physical damage. Separate from incompatabilities. Protect from direct sunlight. Skin Exposure: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated.clothing and shoes. Call a physician, The information contained herein is provided in good faith and is believed to Eye Exposure: Wash eyes with plenty of water for at least 15 minutes, be correct as of the date hereof. However, Mallinckrodt, Inc. makes no ~epre- lifting lower and upper eyelids occasionally. Get sentation as to the comprehensiveness or accuracy of the information. It is medical attention immediately, expected that individuals receiving the information will exercise their dependent Judgment in determining its appropriateness for a particular purpose. Accordingly, Mallinckrodt, Inc. will not be responsible for damages of any kind resulting from the use of or reliance upon such information. ~ (RTECS, 1982) NO REPRESENTATIONS, OR WARRANTIES. EITHER EXPRESSED OR ,I~PLIED, OR RERCHANTABILITY. FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER Oral rat Iii50:350 mE/kg NATURE ARE MADE HF&EUNDER VITH RESPECT TO THE INFORMATION SET FORTH Mutation Effects cited HEREIN THE PRODUCT TO WHICH THE INFORMATION REFERS. Aquatic Toxicity Rating: TLm 96:100 - 10 ppm - · AHItONIUHHYDROXIDE -2- ~ Haterial Safety Da~ Sheet Fire and Exnlosion SECTION 2 Information Emergency Telephone Number Hallinckrodt Inc. 314-982-5000 Fire: Autoisnition temperature 651°C (120~°F) as NH*3. Science Products Division Flammable limits in air volume % (as NH*3): P.O. Box N uel: 27. Paris, Kentucky 40361 Effective Date: 07-22-85 Explosion: Not considered to be an explosion hazard. PRODUCT IDENTIFICATION: Fire Extinguishing Hedia: Use any means suitable for extinguishing surrounding Synonyms: Aqua a~monia; ammonia water; ammoniu~ hydrate fire. Use water spray to blanket fire, cool fire exposed containers, and to flush non-iEnited spills Formula CAS No.: 1336-21-6 Holecular Weight: 35.05 or. vapors away from fire. Hazardous Ingredients: Chemical Formula: NH4OH Not appliqable. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiecs operated in the PRECAUTIONARY HF~URES pressure demand or other positive pressure mode. WARNING! HARNFUL IF SWALLOWED OR INHALED. CAUSES BURNS. Do not get in eyes, on skin, or on clothing. Avoid breathing vapor. Reacti'~it~ Data SECTION ~ Keep container closed. Use with adequate ventilation. Stability: Stable under ordinary conditions of use and storage. Wash thorou§hly after handling. This substance is classified as a POISON under the Federal Caustic Poison Act. Hazardous Decomposition Products: hits toxic fumes of a~onia and nitric oxides ~hen EMERGENCY/FIRST AID heated to decomposition. If swallowed, give several glasses of water to drink to dilute. Vomiting may occur spontaneously, but DO NOT INDUCE[ If inhaled, remove to fresh air. If not Hazardous Polymerization: Will not occur. breathing, give artificial respiration. If breathing Is difficult, give oxygen. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. Incompatibilities: Acids, acrolein, dimethyl sulfate, halogens, silver In all cases call a physician, nitrate, propylene oxide, nitromethane, silver oxides, sliver permanganate, oleu~, SEE SECTION 5. beta-propiolactone. DOT Hazard Class: Corrosive Haterlal Physical'Da~a SECTION 1 Leak/Swill Disoosal Information ~ECTION 4 Appearance: Clear, colorless solution. Ventilate and evacuate area. Clean-up personnel require protective clothing and Odor: Ammonia respiratory protection from vapors. Allow only qualified personnel to handle the spill. Solublllty: Infinite in water. Contain and recover liquid when possible. Spills may be neutralized with dilute hydrochloric acid or dilute sulfuric acid and discharged to sewer with large Boiling Point: ca 36'C (97°F) Vapor Density (Air-1):l.2 amounts of water. Regulations for pH, ammonia content and salts for effluents must be considered. Do not flush directly to sewers. Alternatively, spills may be Melting Point: -72'~ (-98'F) Vapor Pressure (mm Hg):ll§ @ 20°C (68°F) absorbed with dry inert material and collected for disposal in a RCRA approved facility. Specific Gravity : 0.9 Evaporation Rate:No information found. Reportable ~uantity (Rq) (CWA/CERCLA) : 1000 l~s. Ensure compliance with local, state and federal re~ulations. ,/ Medical Cnndlllnn.~gl~HHJyatedJzY E~I2US'e ' ' SI~: Methyle~ chl~lde s~ld ~ protected from melitta. extremes, and direct ~llght. Prier stora~ of ~thyl~ ~l~l~ ' PreciSe from ex~tt~e tndlvl~lt with ~telNt of liver, kl~, cardlovlscul*r .... - m~l ~ ~ferml~d based ~ ol~r m~terlal~ sl~ed ~ I~lr ~,r~ '" ~ centr~! ~rv~ tystem~, I~ ~l~ I~ert, Sl~lll~ *~l~t to ~lhyllne , ' ' i~ ~tenll~l chemical Incompatibility. In ~rml, ~thyle~ . :~. chl~lde ~ ~lcohol can Incre~ I~ In:lc ~rdl ~ ~l~le~ chl~l~, : chl~lde Ih~ld ~ st~ed In = cool, well ventilated I~ ~c~l toxic stora~ r~. .:~ Ot~r: ' Emer~ncy eye wish (~talnl and safety I~werl I~ld '. Inhalali~: Im~dlatety remove tp (rash air. If ~t ~elthln~ ldmlnlster I ~ In t~ vicinity of 4ny~tenHll ax~s~e. cardi~fm~iry ret~cltatl~ ICPR), C~tict physician YlI. ~111 ~ DI~I DatA,, , ' ' , , , Immedlalely. · ,- ., . ,~ . · '. .. Spill C~trol: Wear ~otectlve clothing i~ u~ i~oved resplrlt~ e~l~nl. Eye C~tact: Rinse with c~l~ im~ll of Wlt~ f~ at Illlt IS minuteK Get ..~ -. Abs~ splll~ material In an a~nt rec~ 'f~. ~lvKt emer~ncy medical assistance. , . -: ~:;. ,.. spills a~ remove to a safe I~111~ f~ dls~al by a~ov~ · .-. .... .:-. . If relel~ Io t~ envlr~nt, comply with ~11 " Skin C~IecI: Fl~sh Ih~ly for II least IS mln~lL Wi~h affect~ skin with ' ~ ..... ... notlflcat!~ re~ke~nts... soap i~ water. Re.vt c~tamlnited clothl~ i~ s~k Wilh' '. ' :'~ .' :'.' : '*, -~ clothing ~f~e re-use a~ dltcBrd I~1. Get e~rp~y ~cll Waste - ,.. ..... , assistance. .. / DIs~sah-'- ~: : Dit~ of ~thyle~' ~1~1~ as an EPA hlz.~ wiltl. '. ~' ,~ ~'~ ..... HIZB~ Wills numar ' U010(Toxlc). In~stl~: Celt local PolI~ C~lroI Cenlff f~ Iillltl~i, C~tlCt I ~yllclen ~' -- . immediately, Never t~e ~ltl~ ~ girl Bnythl~ by m~th to a victim ~c~ecl~ ~ ~vl~ cm~lll~. . , ~ .... · ' Revltl~ Date: IIIS . ' .- ~. ~fety ~as~s ~ E~lp~t Ventllitl~: A~ate ventUall~ Is re~lr~ lO ~Ot~t ~1 fr~ lo chemical v~l IxCl~l~ t~ PEL. h c~lce of ~ntllltl~ ~. ~antlty of material, e~ ot~ witl~ paremtem. "' Retplrat~ U~ ap~ov~ rel~rat~ e~. Fallow NIOSH a~ e~l~nt E~s: Safety glasses ~ c~si~ mlai~ ~olectl~ G~le~ ~ ....... ., face shield may h M. sti~ ~ M ~ntlly o~ mterlal ,: ' Skin: ~olecllve gloves a~ clothl~ ~t ~C~' ~ c~lce' of .... ~ .... '. mBlerlal mint h ba~ m ~1 rellslince IK olhr mr '. .. retirements. Ge~rally, ~ ~ B~N Off~ accepllble ' chemical resltti~e. I~vl~ll w~ ~ ic~ely ~ t~clflcilly ~nsitlve to ~lhyllM chl~l~ ~y re~i~e a~ltl~ll ~otectlve ' e~ipment. ~ - · -- ~ ' KEY ca Approximately STEL S~l Term Ex~e Level - ne Not applicable . TLV Threl~ld Limit Val~. '~ . :.' .C Ceiling TWA Ti~ WaiSted Avere~ : :".':: PEL Permis~able Ex~e Level BuAc Butyl Acetate . . NSC Natl~al Safety C~cll ("F~da~ntal~ of Industrial Hygle~", OHS Occuplll~al Health ~rvlcel ("Hagardllne~) ." Health Ilazard [nforpatlon editing 5 "-- Occuoatlonal Control Keasuree S~CTXON 6 A. £x~osure/~eelth £ffects Airborne Exposure Limits: .None os~bliehed. Inhalation: ' Hay cause Irritation to mucous' membranes o£'tbe~- '~.. '.' . ,. " , respiratory tract. Ha7 be absorbed ~rom tbs mucous .. , , ~ .. membranes, and dapendinS on the amoun~ of exposure : could result in the development of nausea, vomitin~, Ventilation System: A local e~he~t system ~htch captures the contaminant diarrhea, drovsiness, coma, and death. ~, :. .. aC ice source is recommended to prevent dispersion of. · tho contaminant into ~he vorkro~ ~lr. ' Ingestion; S~p~oms parallel absorption via inhalation. Adult ~a~al dose repo~ed a~ 5 ~o >30 grams. Parnell Respirators For condi~io~ of us~ ~hero exposure ~o ~he dust lo ~.. , (HIOSII Approved) '~pparonC, · dua~/mis~ raspl~cor may be yarn. For Skin Contact: ~oc significantly absorbed through cbs In,acC bkin. eme~se~ios, · self-contained brea~hing apparatus R~adil7 absorbed through da~ased or burned skin. S~mpcoms o[ skin absorption parallel Inhalation and ~ ', , "' ,, in&est/on. Skin Pro~ec~ion: gloves a~ lab coat, apron or coveralls. Eye Con~ac~: ;' ' Hay cause i~ri~acion o[ the eyes. .'+.' -~ ";.' ' . ' · ' , ,~ [:. Chronic Exposure::' Prolonged absorption causes veishc loss, vomiting, Eye Pro,action: Uae chemical safety Sos~les. Contact lenses should nec . ~ ,,' ' diarrhea, skin rash, con. Islets and anemia. Kld~e~s .. be ~o~ rhea vorklnj ~i~h this na~e~lal. . . .. and liver may be parCicularl~ susceptible, Hain~min eye rash fouflCain and quick*drench facilities la ~ork ~rea. Assrava~ion of Pre-extscin~ Conditions: Persons with p~a-exisClfl~ skin disorders or eye '.:... ' ' problems, o~ impaired [lve~, kidney o~ respiratory ' "' · function may be more susceptible Co the effects of ~he ;~, Uso ~d housekeepin~ p~acCices co prevent . subsCanco, acc~ulation o[ dust and foiler sound claanin~ ,, , · techniques ~hac viii keep airborne particulates eating, drtnklnS or s~kls)S. Yeah hands after Inhalation:~.. Remove to fresh att.' I~ not braathin~, &tva artificial handling this material. Avoid contact especially ~hen skin ia cut or abratded. respiration. If b~eachtns la difficult, Siva oxygen. Call a physician.' Y In~esclon:'' ~ If svalloved, induce vomittn& t~edtataly by &tying ~o ; Storaea and Soecial Info~acion SE~ION 7 . glasses of ~ater, or silk ti available a~ stickin~ ' '' ' ..... - ~. '" fln~e~ do~ throat. Call a physician i~edtately. Store tn closed .containers In a toni, d~ area. Carbon steel or ai~ln~ containers ~ever give anytbieS by south to an unconscious person, ara suitable for scora&e. Stainless steel is needed fo~ anise conditions. ~:'::..., I'.' Skin Exposure: Remove any contaminated cloc~n~. ~aah skin vl:b aesp ~:: ' or mild date~enC and vaCe~ for aC least ~5 minutes. The info~ation co~tained herein i= provided In 8end leith a.d la believed GcC medical attention ~ ~rricatton develops or be co:tact as o~ the date hereoi. IIo~avet, Nallinckcodc, Inc. makes ~o aantatlon aa to the comprehensiveness et mccutacy of the ln[orea:to~. It ~, persists, e~pacted tl~t individuals recelvia8 ~e inforaation viii esercise their ln- ~ ,'. .depe~dant Jud&ment tn detarmlntn& its eppropriate~ss for a particular Eye ExposuIe: ~ash eyes rich plency of ~atar lee a: least 15 m~nutas, purpose. Accordln&ly, ~allinckrodt, ]~. viii not be ~u~ponalble [ur damages ' ' lifting lo.er and upper eyelids occasionally. Ge~ of any kind raaultin~ ires tbs use u~ or reliance upon 5ucb medical aC:enC~on l~edtaculy. NO REPRESE~ATIONS, OR gAR~NTIES. EI~I~ ~PRESS OR IMPLIEO, nE ~ClI~AB]LITY, FI~ES5 FOR A ~TI~l~ PURPOSE OR O~ ~Y NATURE AgE ~OE II~EUNO~ g]~l R~P~ TO TIlE ]a~'rl~ s~r [~gTII C, TOXICI~ 'DATA (RTECS. 1982) . II.fIN OR TO TIlE PRODU~ TO UIIICII ~IE INACTION REF~S. Oral fac ~50:, 26~0 mg~K& ; .... ~T gu:a:lon re~erances cited. ,~.... ~. .;., .. Reproduc.:lve =e'f~ects.cl~ed.