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Home My WebLink AboutBUSINESS PLAN 10/28/1991 Hazardous Materials/Hazardous 'Waste Unified Permit . CONDITIONS OF PERMIT ON REVERSE SIDE Thi~ _=ermit is issued for the followin_=: , [] H.7-rdous Materials Plan L. ~~_._~ []D UndergroundRisk Management ProgramSt°rage of HazardOus Materials Permit ID #:: 015-000-000890 l~)~ ARCO GY [] Hazardous Waste On-Site Treatment LOCATION: 4550 CALIFORNIA AVE IELD ~. ., ~, ~ '~'~ OFFICE OF EN~RONMENTAL SER VICES ' 1715 Chester Ave., 3rd Floor Approved by: ~ Bakersfield, CA 93301 r Voice (661) 326-3979 F~ (661) 326-0576 Expiation Date: "-"~">'~ S ITE/FACILITY D lAG RAM '~' ...... FORM 5 ..... NORTH SCALE: NONE BUSINESS NAME: ARCO Oil & Gas Company 'iFLO01~ 6 OF"7 ~ DATE: 3/81/89 FACILITY NA.,M~: ARCO BUILDING, SIXTH FLOOR ~ #: 2 OF 2 ((X-IECKONE) SITE DIAGRAM FACILITY DIAGRAM X EVACUATION ROUTE EVACUATION ROUTE CMLQ ~ COMBUSTIBLE i'~ FIRE LIQUID STAIRS EXTINGUISHER r~ALARMCITY FIREBoxEs ~ KITsFIRST AID NFLG Q ELECTRICAL ,~ FIRE DEPT. ~ FIRE HYDRANT NON-FLAMMABLE SHUTOFF ACCESS ELEVATORS =5::,& SPRINKLER GAS VALVE I(Inspector's Comments): -OFFICIAL USE ONLY- LEC ~-'---"~ SITE/FACILITY DIAGRAM '~ FORM 5 NORTH SCALE: NONE BUSINESS NAME: ARCO 0il & Gas Company FLO01~ OF ~ DATE: 3/31/89 FACILITY NAME: ARCO OFFICE BUILDING UNIT #: OF ((2IF. L~KONE) SITE DIAGRAM X FACILITY DIAGRAM ASSEMBLY AREA DRIVE ,~,FIRE DEPT. ACCESS Q ELECTRICAL SHUTOFF ~ Q GAS SHUTOFF SUITE L '-.,.J' · ,! Q WATER SHUTOFF tr ~ f /~, PUBLIC FIRE HYDRANT I (Inspector's Comments):' -OFFICIAL USE ONLY- LEC -§A- ---~ .... ' SITE/FACILITY DIAGRAM FORM 5 lqORTH SCALE: NONE BUSINESS NAME: ARCO Oil & Gas Company FLOOR: 3 OF 7 //~ DATE: 3/31/89 FACILITY NAME: ARCO BUILDING, THIRD FLOOR UN1T #:. i OF 2 (CBECKONE) SITE DIAGRAM FACILITY DIAGRAM X EVACUATION EVACUATION ROUTE ROUTE TERRACE 0 ~341 NFL~ ;t NFLG ~ STAIRS FIRE r~ CITY FIRE [] FIRST AID EXTINGUISHER ALARM BOXES .~ KITS' NON-FLAMMABLE GAS Q ELECTRICAL ,~/ FIRE DEPT. ~ELEVATORS FIRE HYDRANT SHUTOFF ACCESS =5= & SPRINKLER VALVE (Inspector's Comments): -OFFICIAL USE ONLY- LEC ' SITE/FACILITY DIAGRAM FORM 5 NORTH SCALE: NONE BUSINESS NAME: ARCO Oil & Gas Company FLOOR: 6 OF 7 /~' DATE: FACILITY NAME: ARCO BUILDING, SIXTH FLOOR UNIT Ct: 2 OF 2 (CHECK ONE) SITE DIAGRAM FACILITY DIAGRAM X EVACUATION EVACUATION ROUTE ROUTE ROOM #69O ~'~ NFLG LEGEND STAIRS ~'~ EXTINGUISHER FIRE Ir~l ~ ~ CITY FIRE FIRST AID ALARM BOXES KITS . G ELECTRICAL .~ .FIRE DEPT. ~ FIRE HYDRANT SHUTOFF ACCESS ELEVATORS c:~ & SPRINKLER VALVE CommentS): -OFFICIAL USE ONLY- (Inspector's ARCO/4-92 ~ . ~ SITE/FACILITY DIAGR-ZklVI FORM / . '~o ~i,.~ / ' .NORT~ $CALE~:.~ BUSINESS N~E: .- FLOOR: 0F ,~31~_Z;~,-~ gRCO.O~l and ~as Company Basement 7 DATE: 7/15/87 FAClCITY N~E:ARC0 Buildi.ng UNIT ~:1 OF. 2 · (CHECK ONE) SITE DIAGRAM' FACILI~ DIAGR.%M X Floor Drain Fire Hydrant and Riser 80-,gal diesel tank" SITE/FACILITY D G R ~a~v~ ~1 FORM 5 I NORTH SCALE: BUSINESS NkME: FLOOR: OF 1" ~ 31' ARCO Oil and Gas Company 6 7 DATE: 7,~5 /87 FACILITY NAME: UNIT e: OF ARCO Building i 2 (CHECK ONE), SITE DiAGR.~M FACILITY DIAGR.~M X .. i spersant and Toner Storage Inspector s Comments): -OFFICIAL USE ONLY- ~. SI TE/FACI LI.TY D I AG R~kiv[ .; FORM $ NORTH SCALE: BUS INESS NAME: FLOOR: OF 1" : 31' ARCO Oil and Gas Company 5 7 DATE: 7 .4'5 /87 FACILITY NAME: UNIT ~: OF ARCO Bui'lding 1 2 (CHECK ONE) SITE DIAGRAM FACILITy DIAGRA3{ X . ~ ~ · l(Inspector's Comments): -OFFICIAL USE ONLY- - 5A - S I TE/FAC I L I TY AG R;k~f ..... NORTH SCAL~i:;~'-'":~ BUSINESS NAME: FLOOR: OF I"' = 3i~':>:~!~:':.:}- ' ARCO Oil and Gas Company '4 7 DATE:-~ /15/87 FACILI~ N~ME: UNIT ~: OF ARCO Bui]d~n~ 1 2 (C~ECK ONE) SITE DIAG~ FACILI~ DIAGraM X ~ ,a i r-s I (rnsp~ector's Comments): -OFFICIAL USE ONLY- · 7. 'SITE/FACILITY AG R~klvI' NORTH SCALE':,,i. BUSINESS N~%ME: FLOOR: OF 1" ~ 3'%''~'' ARCO OJ] and Gas Company 3 7 DATE:7'~15~87 FACILITY N~ME: UNIT ~: OF ' ARCO Building 1 2 (CHECK ONE) SITE DIAGRk~ FACILI~ DIAG~%~ X · . : ~ · I+ · ~ TERRACE . _ ' · t~; ~':.1 i.~.~ ' ' ' , [i'l I j('~"ol I r:"~ ,.) ,drous Ammonia Stonage I(rnspector's Comments): -OFFICIAL USE ONLY- - SA - o SiT]E/FAciLiTY AGR~ FORM 8 NORTH SCALE: BUSINESS N~%ME: FLOOR: OF I 1" = 68' ARCO Oil and Gas Company - - DATE: 7/15/87 FACILITY N~ME: UNIT ~: OF ARCO Buildinq (CHECK ONE) SITE DIAGRAM X FACILITM DIAGRAM % -. 0 Fi re ~ ~ Hydrant % · ,, -- . oWater -'. Shutoff · OGas · ,drant Shutoff ~ ~ (Roof Access) ~ G~ ARCO BLD'G / ....... Heater (on roof) (Inspector's 'Comments): -OFFICIAL USE 0NLY- - SA - SITE/FACILITY GRAM FORM 5 / NORTH SCALE:~ BUSINESS N~[E: FLOOR: OF 1" = 31" ARCO Oil and Gas Company 7 7 DATE:7 ,/15/87 FACILITY N~E: UNIT ~: OF' ARCO Building ] (CHECK ONE) SITE DIAGRam! FACILITY DIAGR.~ .X I(Inspector's Comments): -OFFICIAL USE ONLY- - SA - SITE/FACILITY AGRAM FORM ~ NORTH SCALE:' BUSINESS· N&~E: FLOOR: OF I 1" : t.20' ARCO Oil and Gas COmpany DATE~'.7/15/87. FACILITY N~E: UNIT ~: OF ARCO Building and ARCO kab {¢~ECK ONE) SITEDIAGR~ X FACILITY Mervyns .... / Zellerbach I ~aper CO. Co; J'Inspector~s Comments): -OFFICIAl USE ONLY- - SA - SITE/FACILITY DIAGRAM ', 'FORM 5 NORTH scALE: NoNE BUSINESS NAME: ARCO Oil. & Gas Company FLOOR: 6 OF 7 ~'~ DATE: 3/31/89 FACILITY NAME: ARCO BUTT,DING, SIXTH FLOOR UNIT #: 2 OF 2 (CBECKONE) SITE DIAGRAM FACILITY DIAGRAM X EVACUATION ROUTE EVACUATION ,~ ROUTE ROOM ~690 .. ~ NFLG CMLQ COMBUSTIBLE ~ ~ FIRE LIQUID STAIRS EXTINGUISHER r~ ALARMCITY FIREBoxEs [] FIRSTKiTS AID NON-FLAMMABLE SHUTOFF ' ACCESS ELEVATORS ~ & SPRINKLER GAS ~ VALVE ,(Inspector's 'Comments): -OFFICIAL USE ONLY- 'SITE/FACILITY D lAG RAM FORM 5 NORTH SCALE: NONE BUSINESS NAME:. ARCO Oil & Gas Company FLO01~ 3 OF 7 DATE: 3/31/89 FACTi.ITY NAME:. ARCO BUTT,DING, TI-TTRD FLOOR UNIT #: 1 OF 2 (CHF. L~ONE) SITE DIAGRAM FACILITY DIAGRAM X EVACUATION EVACUATION ROUTE ROUTE TERRACE LEGEND NFLG ~ STAIRS FIRE r~. CITY FIRE I~1 FIRST ,AID EXTINGUISHER ALARM BOXES ~m~ KITS- NON-FLAMMABLE (Inspect0'r's comments): . -OFFICIAL USE ONLY- LEC · ' -SITE/FACILITY DIAGRAM FORM 5 NORTH scALE: NoNE BUSINESS NAME: ARCO Oil & Gas ·Company· ' FLOOI~ OF A '" ~ DATE: 3/31/89 . FACTI,ITY NA_M_~P,:. ARCO OFFICE BUTr,]3ING ulXrlT #: OF ' (CHECKoNE) SITE DIAGRAM X FACILITY DIAGRAM · · ASSEMBLY AREA " . A-~,. -, ,-Z.,,~?~,'-~'. ~" DRIVE ',~, FIRE DEPT. AccEss Q WATER SHUTOFF l / ~'7 A pUBLIC FIRE. HYDRANT , (Inspector's Comments):· -OFYlCIAL USE ONLY- [ I ~ ,,i SITE/FACILITY DIAGRAM FORM 5 NORTH SCALE: NONE BUSINESS NAME: ARCO Oil & Gas Company FLOOI~ OF DATE: 3/31/89 FACILITY NAME: ARCO LABORATORY UNIT #: OF (CHECKONE) SITE DIAGRAM X FACILITY DIAGRAM DRIVE MASONRY WALL FIRE DEPT. ACCESS FD GAS SHUTOFF SUITE -~A- ~,;,~ ?'t SITE/FACILITY DIAGRAM ~) FORM 5 NORTH SCALE: NONE BUSINESS NAME: ARCO.Oil & Gas Company FLOOR: OF N/A DATE: 3/31/89 FACILITY NAME: ARCO LABORATORY UNIT #: .1 OF 1 '(CHECK ONE) SITE DIAGRAM FACILITY DIAGRAM X LABORATORY ! HALLWAY MEN'S ROOM STORAGE , FRONT DESK ~=~ FLGS ROOM ~ r'--'-~ O ~- ~ I // LADIES ROOM NFLG 0000~ ~ k.j . '_./.. I~ OFFICE OFFICE OFFICE ID EVACUATION ROUTE THROUGH PARKING LOT FLGS NFLG FLAMMABLE NON.FLAMMABLE ~ .FIRE Q ELECTRICAL WATER sHUToFF GAS GAS EXTINGUISHER SHUTOFF ~ ~,.,s.,,,.., ,3,,,,..,-'r. ®o,,s', WINDOW KITS ' ACCESS SHUTOFF ELECTRICAL SHED (Inspector's Comments): -OFFIC~ USE ON'L¥- LEC Bakersfield Fire Dept. HAZARDOUS MATERIALS DIVISION " ' Date Completed [D ;~ ' cf I Business Name:,, 'F')~'~O ~:~'( ~ ~ ~ Business Identification No. 215-000 ~0. ~U,~ ff~ ~usi.~" ~' Station No. ~ ~ ~,~h~ ~nspoc~ ~~¢h .. ... Adequate Inadequate ~Verification of Invent°~ Materials ~ , Verification of Quantities ~ Propor 8o~m~ation of Material ~ Comments: Vodfication of ~SDS ~vailabli~~ Gomments: Gomments: '~ Emergency'Procedures.Posted ~ . ~ Contai,ers Properi~ Labeled ~ Comments: Special Hmards Associated with this FaCility: ~k~ ~~~~ All'Items O.K. gusine~s~O~ner/aan~er ' Correction Needed FD 16~ (~v. 1-90) .,~i~-H~ ~t D~. Yellow-Staten ~py Pink-Busine~ ~y ARCO Oil and Gas Company Western District Post Office Box 147 Bakersfield, California 93302 Telephone 805 321 4000 April 2, 1992 Mr. Ralph E. Huey Hazardous Materials Coordinator Bakersfield Fire DeparUnent Hazardous Materials Division 2101 H Street Bakersfield, CA 93301 Dear Mr. Huey: Attached, please find the 1992 Hazardous Materials Business Plans for ARCO'S California Avenue Office Building. Please be aware that an Acutely Hazardous Matrerials registration form was previously submitted for the anhydrous ammonia on the third floor. If you have any questions, please do not hesitate to call me at 321~4033. Sincerely, Ron Stanfield Technician Attachment ~ ~ ..... cc:MAS w/o attachme File: 4-920.4 ARCO Oil and Gas Company is a Division of Atlantic Richfield Company HAZARDOUS MATERIALS BUSINESS PLAN 1992 ARCO OIL AND GAS COMPANY ARCO BUILDING BAKERSFIELD CITY FIRE DEPARTMENT 2101 "H" STREET BAKERSFIELD, CA 93301 (805) 326-3979 OFFICIAL USE ONLY ID# BUSINESS NAME HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE RECEIVED FORM 2A APR 0 6 INSTRUCTIONS: HA~. ~.T. DIV. 1. To avoid further action, return this form within 30 days of receipt. 2. TYPE/PRINTANSWER8 IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: AR(;;(:;) OIL AND GAS COMPANY. OFFICE BUILDING B. LOCATION/STREET ADDRESS: 4,550 CALIFORNIA AVENUE CITY: BAKERSFIELD ZIP: 93309 BUS. PHONE: !805) 321-4000 SECTION 2; EMERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS. A. Tom Stevens - Building Mechanic Ph# (805) 321-4300 Ph# (805} 329-6282 !_pager) B. Cecilia Zache _ry - Services Manager Ph# (805) 321-4177 Ph# (805) 832-1848 SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: OUTSIDE THE BUILDING ON THE NORTHEAST END B. ELECTRICAL: IN A ROOM ON THE NORTHEAST END OF THE BUILDING IN THE BASEMENT AREA C. WATER: OUTSIDE THE BUILDING ON THE NORTH END D. SPECI~ NONE E. LOCK BOX: YES / NO IF YES, LOCATION: FIRE CONTROL ROOM ON THE GROUND FLOOR IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDS'S? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO April 1992 page 1 SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE This facility has an Emergency Response Plan in effect. The plan covers emergency responses for medical, fire and chemical release emergency events. A team approach is incorporated in the Emergency Response Plan for evacuation procedures. SECTION 5: LO(;;AL, EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE For minor injuries, victims are taken tO Bakersfield Family Medical Center, 4580 California Avenue, Phone # 327-4411. The nearest hospital is Mercy Hospital located at 2215 Truxtun Avenue; patient information phone # 327-3371. For emergencies, personnel are instructed to call 911. SECTION 6; EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE SAFE HANDLING OF HAZARDOUS MATERIALS. A. NUMBER OF EMPLOYEES AT THIS FACILITY 220 B. DO YOU HAVE MSDS (MATERIAL SAFETY DATA SHEETS) FOR EACH HAZARDOUS MATERIAL YOU HANDLE? YES C. GIVE A BRIEF SU'MMARY OF YOUR HAZARDOUS MATERIALS TRAINING PROGRAM: This facility has a Hazard Communication Standard Program in effect. Employees that handle hazardous materials are briefed on the MSDS's for each chemical on the premises during periodic safety meetings. The briefings include handling, storage, release response information and personnel protective equipment usage. SECTION 7: HAZARDOUS MATERIAL I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAPTER 6.95 OF THE CALIFORNIA HEALTH AND SAFETY CODE FOR THE FOLLOWING REASONS: WE DO NOT HANDLE HAZARDOUS MATERIALS. WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIME EXCEED THE MINIMUM REPORTING QUANTITIES. OTHER (SPECIFY REASON) SECTION 8: CERTIFICATION I, Micha¢! A. Stah] , certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety Code on Hazardous Materials (Div. 20 Ch. 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. SIGNATURE~'~.~ ~.~TITLE.Environmcntal.(~oordinator DATE April 1992 page 2 SITE/FACILITY DIAGRAM FORM 5 NORTH SCALE: NONE BUSINESS NAME: ARCO Oil & Gas Company FLOOR: OF ~ DATE: FACILITM NAME: ARCO OFFICE BUILDING UNIT #: OF (CHECK ONE) SITE DIAGRAM X FACILITY DIAGRAM ASSEMBLY AREA ~/ / ~ / , ~ /' 7- / 4550 CALIFORNIA AVE / EASTON [ L~ ~AMT~D ~ RO~ wTEAL L / ' DRIVE LEGEND N~FIRE DEPT. ACCESS G ELECTRICAL SHUTOFF G GAS SHUTOFF SUITEL PUBLIC FIRE HYDRANT'/~ (Inspector's Comments): -OFFICIAL USE ONLY- ARCO/4-92 - 5 A BAKERSFIELD CITY FIRE DEPARTMENT 2101 "H" STREET . BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID# BUSINESS NAME BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by:. 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW. Be as BRIEF and CONCISE as possible, but explain fully. FACILITY UNIT# 1 FACILITY UNIT NAME: ARCO Office Building, Third Floor SECTION 1: MITIGATION. PREVENTION. ABATEMENT PROCEDURE~ Inventories are kept to a minimum. The ammonia cylinder is contained in a metal cabinet with forced draft ventilation to the outside. Employees regularly inspect the valves on the pressurized cylinders. For a large ammonia release, the emergency response plan will be initiated and the Fire Department notified. SECTION 2; NOTIFICATION AND EVACUATION PROCEDURES ^T THIS UNIT ONLY This facility has an Emergency Response Plan that includes notification and evacuation procedures. In the event of an emergency, the Command Center (Room 101 - Services Manager) will notify "Floor Wardens" of the emergency. The wardens will coordinate the evacuation of his/her respective floor by directing personnel to the safest exit. The wardens verify that their floor has been completely evacuated before leaving the premises. ARCO BLDG/Apri11992 page 1 SECTION 3: HAZARDOUS MATERIALS FOR THIS UNIT ONLY A. Does this Facility Unit contain Hazardous Materials? ....... YES I',E) If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret as defined by Section 6254.7 of the Government Code? ....... YES NO If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form #4A-1). If Yes, complete a hazardous materials inventory form marked: TRADE.SECRETS ONLY (yellow form #4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION SYSTEM In conjunction with the Emergency Response Plan, evacuation procedures and floor plans are located on the inside of all the office doors. A designated central fire control room is located on the ground floor. Fire extinguishers and City fire alarm boxes are located on all floors. Water sprinklers throughout the building are set,off by smoke detectors wired to a notification system that automatically calls the Fire Department. SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS Outside hydrants are located northeast and southwest of the building. Connections for fire hoses are located on the landings of each floor in the stairwells. SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT TH~S UNIT ONLY A. NAT. GAS/PROPANE: Main shut-off for the entire building is located outside the building on the northeast end. B. ELECTRICAL: Main electrical panel is located in a room on the northeast end of the building in the basement area. Electrical shut-off for the third floor is located in room 394. C. WATER: Main shut-offs for the entire building are located outside the building on the northeast end. D. SPECIAL: E, LOCK BOX: yES / NO IF YES, LOCATION: Fire Control Room on the Ground Floor IF YES, SITE PLANS? YES / NO MSDS's? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO ARCO BLDG 3rd Floor/April 1992 page 2 Farm and Agriculture r'-'-I standard Business ~ CITY OF BAKERSFIELD Page I of 1 HAZARDOUS MATERIALS INVENTORY NON-TRADE SECRET BUSINESS NAME: ARCO OIL AND GAS COMPANY OVVNERNAME: ARC.~OILAND~~PANY NAMEOFTH~SFAClUTY: UNIT#l, THIRD FLOOR LOCATION: 4550 CALIFORNIA AVE. LOCATION: 4550 CALIFORNIA AVE. STANDARD IND. CLASS CODE: 1 31 1 CITY, ZIP: BAKERSFIELD~ CALIFORNIA 93309 CITY, ZiP: BAKERSFIELD~ CALIFORNIA 93309 DUN AND BRADSTREETNUMBER PHONE#: (805) 321-4000 PHONE#: (805) .321-4000 02 768 8587 REFER TO INSTRUCTIONS FOR PROPER CODES 1 2 3 4 5 6 7 8 9 10 11 12 13 14 TRANS TYPE MAX AVERAGE ANNUAL MEASURE #DAYS CONT CONT' CCNT USE LOCATION WHERE % BY NAMES OFMIXTURE/COMPONENTS CCI~E CCI~E AMT AMT EST UNITS ON SITE TYPE PRESS TEMP CCDE STORED IN FACILITY WT SEE INSTRUCTIONS ~,.I P I 6700 I ~3~0 I 8100 I~r31 3651 4 I 214 1'991 ROOM341 100 ANHYDROUS AMMONIA Physical and Health Hazard C.A.S. Number: 7664-41-7 Component #1 & C.A.S. Number (Check all that apply) Component #2 & C.A.S. Number *99 Use Code = Printing Delayed Sudden Release Immediate ~ Fire Hazard [~ Reactivity ~ Health ~-~ of Pressure ~'~ Health Component ~L3 & C.A.S. Number Physical and Health Hazard C.A.S. Number: Component #1 & C.A.S. Number (Check all that apply) Component #2 & C.A.S. Number Delayed Sudden Release Immediate [-~ Fire Hazard [~] Reactivity [~ Health [~ of Pressure [~ Health component ~3 & C.A.S. Number Physical and Health Hazard C.A.S. Number: Component #1 & C.A.S. Number (Check all that apply) Component #2 & C.A.S. Number Delayed Sudden Release Immediate r-~ Fire Hazard r-'-] Reactivity [-~ Health r-"] of Pressure ~ Health Component #3 & C.A.S. Number Physical and Health Hazard C.A.S. Number: component #1& C.A.S. Number (Check all that apply) Component #2 & C.A.S. Number Delayed Sudden Release Immediate ~ Fire Hazard [~ Reactivity ~ Health ~ of Pressure [~ Health Component #3 & C.A.S. Number EMERGENCY CONTACTS ~1 CECILIAZACHERY SERVICES MANAGER 329-6144 (PAGER) ~2 TOM STEVENS MECHANIC 329-6282 (PAGER) Name Title 24 Hr Phone Name Title 24 Hr Phone Certification (Read and sign after completing all sections) I certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached documents, and that based on my inquiry of those individuals responsible for obtaining the information, I believe that the submitted information is true,accurate~ and complete, MICHAEL A. STAHL, ENVIRONMENTAL COODINATOR Name and official title of owner/operator OR owner/operator's authorized representative Signature-- ' --Dbte Signed ARCO/4-92 SITE/FACILITY DIAGRAM FORM 5 NORTH SCALE: NONE BUSINESS NAME: ARCO Oil & Gas Company FLOOR: 3 OF 7 ~' DATE: FACILITY NAME: ARCO BUILDING, THIRD FLOOR UNIT #: 1 OF 2 (CHECK ONE) SITE DIAGRAM FACILITY DIAGRAM X ~ EVACUATION ROUTE EVACUATION ROUTE TERRACE LEGEND ~ CITY FIRE FIRST AID ALARM BOXES KITS NON-FLAMMABLE GAS G ELECTRICAL '%~FIRE DEPT' ~ ELEVATORS c:~ FIRE HYDRANT SHUTOFF ACCESS -- & SPRINKLER VALVE (Inspector's Comments): -OFFICIAL USE ONLY- ARC0/4-92 BAKERSFIELD CITY FIRE DEPARTMENT 2101 "H" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID# BUSINESS NAME BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW. 4. Be as BRIEF and CONCISE as possible, but explain fully. FACILITY UNIT # 2 FACILITY UNIT NAME: ARCO Office Building. Sixth Floor SECTION 1: MITIGATION. PREVENTION. ABATEMENT PROCEDURES Inventories are kept to a minimum. Employees use absorbent material to wipe up liquid spills within the building. SECTION 2: NOTIFICATION AND EVACUATION PROCEDURES AT THIS UNIT ONLY This facility has an Emergency Response Plan that includes notification and evacuation procedures. In the event of an emergency, the Command Center (Room 101 - Services Manager) will notify "Floor Wardens" of the emergency. The wardens will coordinate the evacuation of his/her respective floor by directing personnel to the safest exit. The wardens verify that their floor has been completely evacuated before leaving the premises. ARCO BLDG/April 1992 page 1 SECTION 3; HAT_~RDOUS MATERIALS FOR THIS UNIT ONLY A. Does this Facility Unit contain Hazardous Materials? ....... yES ND If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret as defined by Section 6254.7 of the Government Code? ....... YES NO If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form #4A-1). If Ye.s, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form #4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION SYSTEM In conjunction with the Emergency Response Plan, evacuation procedures and floor plans are located on the inside of all the office doors. A designated central fire control room is located on the ground floor. Fire extinguishers and City fire alarm boxes are located on all floors. Water sprinklers throughout the building are set-off by smoke detectors wired to a notification system that automatically calls the Fire Department. Room 690 has a Halon fire system. SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS Outside hydrants are located northeast and southwest of the building. Connections for fire hoses are located on the landings of each floor in the stairwells. SECTION 6: LOCATION OF UTILITY SHUT-OFF8 ^T THIS UNIT ONLY A. NAT. GAS/PROPANE: Main shut-off for the entire building is located outside the building on the northeast end. B. ELECTRICAL: Main electrical panel is located in a room on the northeast end of the building in the basement area. Electrical shut-off for the sixth floor is located in room 694. C. WATER: Main shut-offs for the entire building are located outside the building on the northeast end. D. SPECIAL: F LOCK BOX: yES / NO IF YES, LOCATION: Fire Control Room on the Ground Floor IF YES, SITE PLANS? YES / NO MSDS's? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO ARCO BLDG 6th Floor/April 1992 page 2 Farm and Agriculture F--] Standard Business ~-] CITY OF BAKERSFIELD Page 1 of 1 HAZARDOUS MATERIALS INVENTORY NON-TRADE SECRET BUSINESS NAME: ARCO OIL AND GAS COMPANY OVVNERNAME: ARCO OIL AND GAS COMPNqY NAME OF THIS FACILITY: UNIT#2, SIXTH FLOOR LOCATION: 4550 CALIFORNIA AVE. LOCATION: 4550 CALIFORNIA AVE. STANDARD IND. CLASS CODE: 1 31 1 CITY, ZIP: BAKERSFIELD~ CALIFORNIA 93309 C~TY, Z~P: BAKERSFIELD~ CALIFORNIA 93309 DUN AND BRADSTREET NUMBER PHONE#: (805) 321-4000 PHONE#: (805) 321-4000 02 - 768 - 8587 REFER TO INSTRUCTIONS FOR PROPER CODES 1 2 3 4 5 6 7 8 9 10 11 12 13 14 TRANS TYPE MAX AVERAGE ANNUAL MEASURE #DAYS CON'I' CeNT CeNT USE LOCATION WHERE %BY NAMES OF MIXTURE/COMPONENTS O:JDE O2DE' AMT AMT EST UNITS ON SITE TYPE PRESS TEMP CC[2E STORED IN FACILITY WI' SEE INSTRUCTIONS u I PI 1538 I 1538 I 1538 lc'r3 I 3651 4 I 214 ['99 Physical and Health Hazard C.A.S. Number: 75-63-8 Component #1 & C.A.S. Number (Check all that apply) Component #2 & C.A.S. Number *99 Use Code = Fire Protection Delayed Sudden Release Immediate r~l Fire Hazard [~l Reactivity [~ Health ~ of Pressure ~ Health Component #3 & C.A.S. Number Physical and Health Hazard C.A.S. Number: Component #1 & C.A.S. Number (Check all that apply) Component #2 & C.A.S. Number ~ Fire Hazard r'~ Reactivity F-'l Delayed [~l Suddenof PressureRelease ~ ImmediateHealth Health Component ~k3 & C.A.S. Number Physical and Health Hazard C.A.S. Number: Component #1 & C.A.S. Number (Check all that apply) Component #2 & C.A.S. Number Delayed Sudden Release immediate ~ Fire Hazard r'-'-I Reactivity ~l Heallh F--I of Pressure F'-I Health component #3 & C.A.S. Number Physical and Health Hazard C.A.S. Number: Component #1 & C.A.S. Number (Check all that apply) Component #2 & C.A.S. Number Delayed Sudden Release Immediate r-"'] Fire Hazard I~ Reactivity F~ Health [~ of Pressure I~] Health Component #3 & C.A.S. Number EM ERGENCY CONTACTS #1 CECILIA ZACHERY SERVICES MANAGER 329-6144 (PAGER) ~2 TOM STEVENS MECHANIC 329-6282 (PAGER) Name Title 24 Hr Phone Name Title 24 Hr Phone Certification (Read and sign after completing all sections) i certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached documents, and that based on my inquiry of those individuals responsible for obtaining the information, I believe that the submitted information is tru,e,accurate_~and complete. ^. k. Name and official title of owner/operator OR owner/operator's authorized representative Signature Date Signed ARCO/4-92 .. ~Bakersfie!dFire Dept. ,. · ~-HAZARDOUS MATERIALS DIVISION " " ' Date Completed {0 "ag'-.- ~1' I .. Business. Name;.' '/~('~'0 '~"( ';~' ~--_f14~ Location: 'Z'/~_~%_'~O ~.4'bi,-corN ;'~-. ~,, · 'BusinesS. Identification No. 215-000 *~d/'O '(Top of Business Plan) Station No.,'/'/.~ ~' D'~T. Shift Inspector ~ Adequate Inadequate · .Verification of Inventory Materials Verification of Quantities Verification of Location' ~ ~] .. Proper s'egreg~tion of Material Comments: Verification of MSDS Availablity · Number of Employees . Verification of Haz Mat Training Comments: Verification of Abatement Supplies & Procedures Comments: '" Emergency Procedures P~sted · Containers ProperlY Labeled /~.~- Comments: · ' Verification of Facility Diagram Special Hazards Associated with this Facility:~ ', ,4nR~d.¢oo5//~n · '.. correction Needed Business owner/Manager { ' ~, ~'. . " ' ' FO 1652 (Rev. 1-90). ~ . .' '. White-Haz Mat Div. Yellow-Station Copy - Pink-Business Copy ARCO Oil and Gas Company '~e' Western District Post Office Box 147 Bakersfield, California 93302 RECBVED Telephone 805 321 4000 February 5, 1991 F{~6'O 8 1991 Mx. Ralph E. Hury HAZr, MAT. DIV. Hazardous Materials Coordinator Bakersfield Fire Department Hazardous Materials Division 2130 "G" Street Bakersfield, CA. 93301 Dear Mx. Huey, Please find attached the inventory update for ARCO's office building in the City of Bakersfield. The lab formerly located on Easton Drive is shown as being deleted from this plan. It has been relocated to the Carbon Lease which is outside the city limits. A Kern County Business Plan package is being prepared. Please be aware that the diesel located in the building basement is not owned by ARCO and was therefore not reported in the business plan. Also, an Acutely Hazardous Materials registration form was previously submitted for the anhydrous ammonia located on the third floor. If you have any questions, please do not hesitate to call me at 321-4298. Very- y yours, KathyE. earker ~~ h ~ Environmental Coordinator . Attachment ' ~ 13 MAS, File: 4-920.4 AR~O Oil and Gas Companyx~'au Post Office Box 147 (93302) ' 4550 California Avenue ? Bakersfield, California 93309 Telephone 805 321 4001 Gary L. Scullin .~Draftin~l Supervisor ARCO Oil and Gas Company is a Division of Atlantic Richfield Company Drafting Department Western District SPECIALTY TONER COI ORATION ~EBRU2t~RY EMERGENCY CONTACT CHEMTREC (800) 424-9300 FOR SPILL, LEAK, FIRE, EXPOSURE OR ACCIDENT SECTION 1 - PRODUCT IDENTIFICATION .Trade Name & Synonyms~ CE3000 CLEAR DISPERSANT (PG3000-DIS) Chemical Name & Synonyms: Electrostatic Toner Dispersant 'Chemical FamilY= Petroleum Solvent Molecular Weiqht= N/A Formula~ Isoparaffinic Petroleum Solvent SECTION ~ - PHYSICAL DATA Appearance/Odor: Clear/Slight Softening Range= Boling Points 150-180C Melting Point= N/A Solubility in Water= ~mmisclble pH= N/A Evaporation Rate: .25 - .45 Vapor Density (air =1): 5 Volatile N/A (wgt.) 80-100% Vapor Pressure (mm Hg;) 1nun @ 68F Specific Gravity (Water = 1)= 0.76 SECTION'3 - HAZARDOUS INGREDIENTS DEBCRIPTION CAS~ ~ TLV (Units} Isoparaffinic petroleum 64742-48-9 100 300 PPM Established Solvent by E~_~on SECTION 4 - FIRE AND EXPLOSION HAZARD DATA Flash Point (Test Method):. 10.3-106F (TCC) Autoignition.Temperature: Approx. 560F Flammable Limits LEL= 0.8 UEL= ' 7.0 Extinguishing Media= Foam, dry chemical, CO2, water fog Speo~al Fire Fighting. Procedures: Avoid water, it tends to spread hydrocarbon fires. Fire and Explosion Hazards: (NFPA) HEALTH 1; FLAMMABILITY 2, REACTIVITY 0, RECOMMENDED BY EXXON SECTION S - TOXICOLOGY INFORMATION [This mater~al has been extensively tested. When used as intended., it does not represent any knoWn'health or safety hazard.]' Oral LDS0~ 5g/kg (rat)* TLV= Dermal LDS0= 3.1$g/kg (rabbit)* PELF N/A Inhalation LDS0= N/A Aquatic LD$0= N/A *Information supplied by Exxon *Recommended exposure limit 300ppm for solvent manufactured by Exxon. e2o~2 .Haterial Safety Data Sheet SBCTZOM 6 .-w'mu, LTH~BARDD&TA A) ,qOUttl Or.81~tL'~, liglll ~J~d I~llptOll Or ovozoxposure, acute and chemical effect... Byet Xrzitant to. eye -.lay cauls o°n~un°tivitil Skin: ~rolongod contact causes defatting, drying, cracking, dormititie. Znhalationz Mot normally an inhalation hazard, overexposure, may cause headache, nausea and roepiratoz~ irritation. xngostion: Nausea and possiblo gHetto-intestinal irritation. Target Organs: Byes,-skin, respiratory B) Caroinogenioity: HTP:No lXRCaonoqraphe:No OSHA Rogulatod:N/X C) Medical conditions generally aggravated by normal exposure: Dernititie. Ropanted inhalation exposure to rate of a similar- hydrocarbon 'at concentrations greater than or equal to 300ppm in air caused lev grads (mild) anamia and kidney effects. D)' Emergency and First Aid Eye: Flush vith largo amounts of rater, including under eyelids. Skin: Wash vith soap and rater. Ramove any contaminated Clothing. Inhalation: Move to fresh air; if breathing difficulty, administer oxygen and get medical help. -Ingestion: Do ~OT induce vomiting due to aspiration hazard. Call a physician. SECTION 7 - SPECIAL PROTECTION INFOR]4ATION Respiration Protection: Not requirea. Ventilation - Local Exhaust: To maintain belov TLV. Other: Protective Gloves: Latex gloves for overexposure. Protection; Goggles for possible splashing. Other Protection: As eyevash station is desirable if splashing is a possibility. SECTION 8 - SPECIAL PRECAUTIONS Handling and Storage: Store in closed, cool, well ventilated area, away from heat and flame. Other: Read and follow label precautions. Do not reuse container. SECTION 9 - REACTIVITY DATA Stability: Stable Conditions to Avoid: None Incompatibility, Materials to Avoid: Very strong oxidants like chromic acid or liquid chlorine. Hazardous Decomposition Products: None Hazardous Pol~merization: Will not occur. SECTION l0 - SPILL OR L~AK PROCEDURE/WAsTE DISPOSAL Remove ignition sources. Collect. on inert a~sorbent, material- Place in vaste container approved for combustible vaste. Disposal: treat as hazardous waste and dispose in accordance with local environmental regulations. DO NOT pour down co~on drain. SECTION l~ - T~ANSPORTATION INFORMATION. IHDG (i.e. ocean) Proper Shipper Name: Petroleun.Distillate,'N*O.'S- (Contains Aliphatic Hydrocarbon Liquid, Resin, Pigment) F1Am~ablo Liquid, Hazard Classification: 3.3 ID Number:- UN1268, Packing Group III, IHD~ Page #3375 IAT& Proper Shipping Name:. petroleum Distillate, N.O.S* (Contains .. Aliphatic HYdrocarbon Liquid, Resin, Pigment)' Flammable' Liquid, Hazard Classification: 3 ID N .u~er: UN1268 Packing G~oup III DOT ProperShipping Nane:'Naphtha, Petroleum, Combustibl® liquid Hazard Classification: 3 ID Number: UNL2SS JUN-14-199B 11:48 SONE SYSTEMS ?1463938B2 TO 180563266B5 P.04 CORPORATION FEBRUARY 1991 - B~R~BN~ ~ACT ~~ (800) 424°9300 . ~R BPZLL~ ~, sR~xo~ x - ~RODO~ XD~XZX~XTXO~ (3000-B~ XD3000-B) ~oal M~e.~. & s~on~o t. BXeo~roo~a~io ~one~ xozoou~ woLgh~z yo~uxaz Xoop~atfln~a ~et~oxe~ solvent, ~ol~ers, Appo~oe/Odort BXao~/SXXg~ Softening iugez. SoX~AXi~ An wa~e~: '~ooAbXe pK~ . ~apora~Xon Ra~e: .25 - .4s Va~E DemeAn2 (aXE =~)= S 8peoXfl= eEavA~2 (Wa~o~ = ~): 0.76 u_TXON 3 - ~A~U8 XNG~DXE~8 ~S~RXPTZON ~ ~ TLr ~nitsl Ao~lio Copol~or/lestn 28430-sa-2 <2.0 '.Hone Est9lished Caren BXaol (~t~ent) 1333-86-4 <1.0 zoopara:rin~o ?etzoXe~ 64742-48-9 96'+ 300 ?PH Bo~lished 8oXven~ by E~on S.E~H 4 - F~RE ~ EX?~SXOM Au~oX~X~Xon Tompo~a~uEo: Approx. S60F FX~Xe LXmX~o LBL:~,8 ~Lz 7,0 ~n~iohing HedXa= Fo~, ~ oh~ioaX' C02, wa~e~ ~oq SpeoXaX Fire Fighting ~zoaeduEesz Avoid va~er, i~' tends to spread (~A) HB~H ~; F~XLXTX 2~ ~~Z~ Of ~O~ED BY' EXXON *'8EC~_ZQN '5 - TOX~QO~GY Z~O~TXON " [This material 'has been extensiVely .tested. ~en used-as intended,. does not represent ~ ~ovn health or-a~ety haZa~d.] O~al LD50: Sq/kg (rat) * TLV: N/A* .. De.aX LD50 z 3 · 16q/k~ (r~bit) * PEL: XnhaXation LDS0z' N/A. A~atio ~S0: ,xnro~atXon supplied b~ E~on JUN-14'1993 11:'48 SONE SYSTEMS 9146393832 TO ~a 18056326635 P.05 " ge BECTZON 6 -wR~LTKnR-B~DATA Materiai Sa£ety Data sheet 'ah~X o~feats. B) ~inoge~oit~t~Ho~KonogzaPho~Ho Xed~aaZ oondLt~ona gonor~y C) Oo~titio. Reps&ted inh~ation caused Xov g~ade (miX~) an~a B~et Flush v~tb ~o ~ounts a~in~ Uamh vith eo~ and varec. ~ove ~y oont~inatO4 o~othing. X~aXation: Move to fresh aicr it bzeathing'ditti~Xt~, .a~inieter o~gen ~d ge~ medieaX hemp. xngeO~ions Do~ induce vomiting due ~o-aspiEa~ion haaa~d. 'Calx a ph2olOl~. RespAra~Aon FEo~eo~ionz Ventilation - ~al Ezhauo~z ~o nain~aAn hexer TLV. O~he~ H/A ~ro~eo~ive OXovesz La~gloveo ~o~ ove~e~oou~e- · ~ro~eo~Aon; ~oggXea for poasAble oplao~ng. o~her ~o~eo~ion~ Ao~e2evaa~ o~a~ion a posgibiXi~2. HandXAng ~d O~orage, s~orejAn o?o~d, ~ ~oXX ven~iXa~ed area, O~herz Read ~d roXXov X~eX preoau~Aons. ~o no~ ~euse oon~ainez. SE~XON 9~ ~_A~XVX~ DATA 8t~ility: '8t~Xe con~x~xono to Avoid: Hone ' xncompati~llit2, Material, to ohzomio aoid o~ li~id ohX0cine. HaBa~dOUB Deoo~osition ~Foduo~sz Hone Ha=ardouo pol~ezisa~ionz aB~XON XO - BPXT.~ OR ~u~K ~RO~~/WASTE DXa~_8~ .... ' ,..~v~-i~iti~ source°. CoXXea~ on inert ~so.~en~ ,s~cTxoa xx - ~$~~xo- x~~xoH .... . ......... - l~ (i.e. Ocean) ~oper shippez ~ ~cr?lo~?x~i~iace' s.u.u- (Contains xliphatio H~droca~bon Li~Xa, Kesxn, FX~Xo Li~id, Hazard ClasoiEication: 3.3 lO N~ozt. UHX268~ X... ~.~.. ~h4uuina H~e: petroXe~ DAstiXXate, H.O.S. (~ont~ino' · Hazard cias~ifioation: 3 XD~eF: ~laeu rmuA~=y v-~-r - ~TFropez Shipping H~o: Haphtha, ~et:ole~, Oo~uotible li~id Hazard CXassitioation, 3 XD H~er: ~xass T~TaL ~.a5 I JUN-14-1993. 11:46 - SONE SYSTEMS ?146393832 TO - 18056326635 P.02 '¥ ",', I CORPORATION FBBRU~RY ~'99~ RMERGRNCY CONTACT CHRMTRRC (800) 42409300 BXI~)BURR OR AOGXDBIq~ $~¢TZO~ I o ~ODUb"T ~DBNTZ~TOATZO~ · Trade ,ams & Synonsms: CE3000 HA(;~I~TA CONCENTRATE (3000-CRM~ XD3000CR-16M) .Chemical Hame, a SFaonyaoz Risc=rest&tic Toner Concentrate Chemical Family: Petroleum Solvent Molecular Weight: For~uXa~ Xso~axa££Ania ~etroXeumsolvent, ~olsme~s, ~iqmen~ S~_CSXO~ 2 - Appearance/Odors Red/Blight Softening Ranges BolAng ~oint: Xe0-xe0c Helting Point: H/A . SoXuMAXAt2 An Water: XnnisoAblo pHz Evaporation l t ate: ,z5.- .4s vapor Densit~'(ai~ =l): S volatile M/A (vgt.) 80-X00~ ~Vapor ~ressuFe (mn Hg;! lmm'9 68F specific er&vAts, (Water.= l): 0.76 U~TZOH 3 -' IXA~ARDoua~T~GREDZEHTS DFj~J~O~ ~_~ _~_' TLV (Units) Ao~lic Copol~me~/Resin 28430-$8-2 (~.0 None Established Red (Piqment) c3,0 xsopa=affinio Petroleum 64742-48-9 91.+ 300 PPH EstabliShed Solvent by Exxon SECT..TO~ 4 - FX~B_M~_RXPLOSXON Flash ~oint (Test Ho=hod): .103-106F (TCC) Autoiqnition Temperature: approx. S60F Flammable Limits LEL: 0.8 UEL~ 7.0 EztAng~iehing Medias·Foam, dFy chemical, 002, water £og Special Fire FightAng~A~ocedures: Avoid water, it tends to spread hydrocarbon fires. Fire and ExploelonKazards: '(IqFPA) HEALTH X, FLMOS~BILXT¥ 2, REACTXVXTY 0, RECOI4XENDED BY EXXON ~EC~.$ON S - TOXXCOLOGY XNFORHATXON [~his'material has been extenslvel¥ tested. When used' as.intended,. it ... does not represent an~ ~uovn health or safe=2 hazard.] .. oral LDS0: Sg/kg (=at)* TLV: H/Z* · ~ernal LDS0s ~' 2.Xeg/~g (rabbit)* PEL:~ .... XnhaXatAon LD$0~' N/A Aquatic LDSO: · xn~ornation supplied by EXXon · Recommended exposure limit 200ppm for solvent manufactured by Exxon. ge 2 o~ 2 NAt~riaX Sa£ety Da~a Sheet · A~) aou~es o~ en~, si~ and s~p~s o~ over~os~e, a~e E~e: X~i~ant ~o e2e - maM cause con~Unctivi~is 'skin: P~olonged contac~ causes defa~ing, d~i~g, c~ac~ing, Inhalation: Non'no,ally an i~ala~ion hazard, ~e~e~osV~e maM . cause.headache, ~ausea and respi~a~o~ i~i~a~ion.. xnges~ion: Nausea and poss~Ie gas~o-in~es~inal i~ri~a~xOn. ' B) Ca~cin~enici~=~No ~H°n~aPhs:~° C) Hedical conditions generally aggravated by no~al hyd~ocarbon:a~ concen~ations.~ea~e~an o~ e~al caused low.~ade (mild) an~ia ~d Ei~ey effects. EYe:. Flush wi~h la~e ~oun~s o~ wa~e~ xncAuaxn~ S~in. ~as~ wi~ s°aP an~ wa~er. Remove an2 Contaminated clothing. o~gen and ge~ medical help. Xnges~ion:Do,induce.vomiting due ~o aspiration hazard.. CaXl. a physicxan. Respi~a~ion p~o~ec~ion= No~ ~e~i~e~. Ventilation - ~1E~aus~: To maintain below T~V. ~o~ec~ive Gloves: ~tex gloves fo~ p~otec~ion~ Goggles fo~ possible splashing. O~er Pro~ec~ion= As a2ewash s~a~ion is desi~le i a possibility. HandXimg and Sto~age: S~o~e in closed, cool, well Ven~ila~ed a~ea, awayfrom hea~ and flame. . o~e~= Read and follow label precautions. Do ~o~ ~euse container. SZ~TION 9 - ~A~IV~ S~ability= Stable Co~di~ion~ to Avoid= None In=ompa~ili~Y,' Materials ~0 Avoid= Ve~ ~trong oxidants l~ke chromic aci~ or 1~i~ c~lorine. Hazar~ou~ Decompo~i~ion Pr~uct~= None Hazardous Pol~eriza~i~= Will not occur. SE_~ION 10 - S~IT~- OR ~.~p~OCED~EZWAS.TE~S~AL Remove ~it~on sources. Collect on. ~ne~ absorbit ma~er~al. Place in Waste container approved for co~us~ible waste. Disposal= ~reat as hazardous waste and dispose in accordance wi~h enviro~ental re~la~ions.- ~ .pour do~ co, on drain. $~CTION .11 - T~S~RTATION INFO~T~O~ I~ (i.e. O~ean) Proper. Shipper ~ame= Pe~role~· Distills=e, (Con~ains Al~pha=~c ~rooarbon Li~id, ReSin,'P~e~~) 'Fishable ~i~, Hazard Classification=. 3.3 ID' N~er= ~12~S, Paoking GrOUp III, IM~ Page IATA ProOf Shipping N~e'=- Pe~role~ Distilla~e, N.O.S. (Con=sins 'Aliphatic Hydrocarbon Li~i~, Resin, pi~ent) . Fla~able Li~i~, Hazar~ Classification= 3 ID.Nu~er='~126S paoking Group III ~T proper Shipping Name= Naphtha, petroleum, Co~us~ible'li~id- Hazar~ Clas~ifi=at~=n= 3 IDN~er= ~1255 SPECIALTY . · ' TONER CORPORATION FEBRUARY 1991 EMERGENCY CONTACT CHEMTREC '(800) 424-9300 FOR SPILL, LEAK, FIRE, - EXPOSURE OR ACCIDENT SECTION ~ - pRODUCT IDENTIFICATION Trade Name & Synonyms: ECP 42 BLACK REPLENISHER (9230-6B, ID9230-6B) · Chemical Name & Synonyms: Electrostatic Toner Replenisher Chemical Family:' Petroleum SolVent Molecular Weight: N/A Formula: Isoparaffinic Petroleum Solvent, Polymers, Pigment SECTION 2 - PHYSICAL DATA Appearance/Odor:. Black/Slight Softening Range: Boling Point= 160-180C Melting Point:. N/A Solubility in Water: Immiscible pH: N/A Evaporation Rate: .25 - .45 Vapor Density (air =1): 5 .Volatile N/A (wg~.) 80-100% Vapor Pressure (mm Hg~) lmm @ 68F Specific Gravity (Water.= 1): 0.76 SECTION 3 - HAZARDOUS INGREDIENTS DESCRIPTION' CAS~ ~ TLV (units) Acrylic Copolymer/Resin 28430-58-2 <1.0 None Established Carbon Black (Pigment) 1333-86-4 <1.0 N/A Isoparaffinic Petroleum 64742-48-9 >97.0 300 PPM Established Solvent by Exxon Dye N/A <1.0 N/A SECTION 4 - FIRE AND EXPLOSION HAZARD DATA Flash Point (Test Method): 103-106F (TCC) Autoignition Temperature: Approx. 560F Flammable Limits LEL: 0.8 UEL: 7.0 Extinguishing Media: Foam, dry chemical, CO2, water fog Special Fire Fighting Procedures: Avoid water, it tends to spread hydrocarbon fires. Fire and Expl'°sion Hazards= (NFPA).HEALTH iv FLAMMABILITY 2, REACTIVITY 0v RECOMMENDED BY EXXON` 'SECTION 5 - TOXICOLOGY INFORMATION .[This material has been extensively tested. When used as intended,, it does not represent any known health or safety hazard.] oral LDS0: 5g/kg (rat)* TLV:. N/A* .. Dermal LDS0= 3.16g/kg (rabbit)* .PEL: N/A Inhalation LD50: N/A Aquatic LD50: N/A · Information. supplied by Exxon. ge 2 of 2 0BC~TZON 6 - B~LTHH~SXI~D DATA Materia! Safety Data Sheet · A) Routes o£ entzT, signs &ud symptoms o£ overexposure,' acute and Eyo~ Irritant toeye - may cause oon3unctivitie 8~inz ~rolongod oontact causes deferring, drying, cracking, dermititis. Inhalationz Not normally an inhalation hazard', overexposure may caueeheadaoho, nausea and respiratory irritation. Ingestion= Nausea and possible gastro-intsstinal irritation. Target Organs= Byes, skin, respiratory system. B) Carcinogenicity=_HTP.'No IARC Honographs=No QSHA Regulated=N/& C) Hedical conditions generally aqqravated by normal exposure: Darmititie. Repeated inhalation exposure to rate of a similar hydrocarbon at concentrations greater than or equal to 300ppm in air caused low grade (mild) anemia and kidney effects. D) Emergency and First Aid Bye~ Flush with largo amounts of Yeter, including under eyelids. Skin= Wash with soap and water. Remove any Contaminated clothing. Inhalation= Move to fresh air; if breathing difficulty, administer ox2qen and qet medical help. Ingestion: Do ~OT induce vomiting due to.aspiration hazard. Call a physician. SECTION 7 ' SPECIAL PROTECTION INFORMATION Respiration Protection= Not required. Ventilation - Local Exhaust= To maintain Below TLV. Other: Protective Gloves: Latex gloves for'overexposure. Protection;' Goggles for possible splashing. Other Protection: As eyewash station is desirable if splashing is a possibility. SECTION 8 - SPECIAL PRECAUTIONS .Handling and Storage:. Store in closed, cool, well ventilated area, away from heat and flame. Other: Read and follow label precautions. Do not reuse container. SECTION 9 - REACTIVITY DATA Stability: Stable Conditions to Avoid: None Xncompatihility, Materials to Avoid: Very strong oxidants like chromic acid or liquid chlorine. Hazardous Decomposition Products= None Hazardous Polymerization: Will not occur. SECTION X0 - SPILL OR LEAK PROCEDURE/WASTE DISPOSAL Remove ignition sources. Collect on inert absorbent material. Place in waste container approved for combustible waste. DiSposal= treat as hazardous waste and dispose in accordance with local environmental regulations. DO NOT pour down common drain. SECTION 11 - TRANSPORTATION INFORI~ATION. .. IHDG (i.e. Ocean) Proper Shipper Name= Petroleum DiStillate, N.O.S. (.Contains AliphaticH2drocarbon Liquid, Resin,. Pigment) Flammable. Liquid, Hazard Classification: 3.3 ID Number: UN1268, Packing Group III, XMDG Page #3375 XATA Proper Shipping Name: Petroleum Distillate, N.O.S. (contains Aliphatic Hydrocarbon Liquid, Resin, Pigment) F1ammaDle Liquid, Hazard Classification= 3 XD Number: UNX268 Packing Group III DOT Proper shipping Name=. Naphtha, Petroleum, Combustible liquid -Hazard Classification= 3 XD Number= UNX255 Farm and Agriculture r'--'~ Standard Business ~ CITY OF BAKERSFIELI) Page I of 1 H~ARDOUS MATERIALS INVENTORY NON-TRADE SECRETS BUSINESS NAME: ARCO OIL AND GAS COMPANY OWNER NAME: ARCO OIL AND GAS COMPANY NAME OF THIS FACILITY: UNIT #1, THIRD FLOOR LOCATION: 4550 CALIFORNIA AVE. LOCATION: 4550 CALIFORNIA AVE. STANDARD IND. CLASS CODE: 1 31 1 CITY, ZIP: BAKERSFIELDr CALIFORNIA 93309 CITY, ZIP: BAKERSFIELD~ CALIFORNIA 93309 DUN AND BRADSTREET NUMBER PHONE #: (805) 321-4000 PHONE #: (805) 321-4000 0 2 ,- 7 6 8,,,- 8 5 8 7 R~.leER TO I~STRUCTIONS FOR PEOP~R CODES 1 2 3 4 5 6 7 8 9 10 11 12 13 14 TRANS TYPE MAX AVERAGE ANNUAL MEASURE #DAYS CONT CONT CONT USE LOCATION WHERE % BY NAMES OF MIXTURE/COMPONENTS CODE CODE AMT AMT EST UNITS ON SITE TYPE PRESSTEMPCODE STORED IN FACILITY WT SEE INSTRUCTIONS Physical and Health Hazard C.A.S. Number: 7664-41-7 Component#1 & C~.S. Number (Check all that apply) Component#2 & C~.S. Number '99 USE CODE = PRTNTTN(7, Delayed ~ Sudden Release ~ Immediate ~ Fire Hazard r'~ Reactivity ~ Health of Pressure Health Component #3 & C.A.S. Number I I I I I I I I I I I Physical and Health Hazard C.A.S. Number: Component #1 & C.A.S. Number (Check all that apply) Component ~Y2 & C.A.S. Number Delayed Sudden Release Immediate ~ F,'e Hazard ~ Reactivity r'~ Health [--'-] of Pressure r'~ Health Component ~L3 & C.A.S. Number I I I I I I I I I I I Physical and Health Hazard C.A.S. Number: Component #1 & C~,.S. Number (Check all that apply) Component #2 & C,~.S. Number Delayed Sudden Release Immediate r--] Rte Hazard. r'~ Reactivity ~ Health r'~ of Pressure r'~ Health Component ~3 & C.A.S. Number ~ I J I I__LJ_L__~ _ Physical and Health Hazard C.A.S. Number: Component #1 & C.A.S. Number (Check all that apply) Component #2 & CJLS. Number Delayed Sudden Release Immediate ~ Fire Hazard ~ Reactivity r'~ Health [--'] of Pressure r'~ Health Component #3 & C.A.S. Number EMERGENCY CONi'ACTS ~ CECILIA ZACHERY SERVICES MANAGER 329-6144 (PAGER) ~ TOM STEVENS MECHANIC 329-6282 (PAGER) Name Tilde 24 Hr Phone Name Title 24 Hr Phone Cerlification (P~ead and sign after completing all sections) I certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached documents, and th~ based on my inquiry of those individuals responsible for obtaining the information, I believe that the submitted information is true,accurate, and complete. I Name and official title of owner/operator OR owner/operator's authorized representative Signature Date Signed LEC/1-91 Farm and Agriculture~'~ Standard BusinessCITY OF BAKERSFIELDPage 1 of 1 I-IAZ~OUS MATERIALS INVENTORY NON-TRADE SECRETS BUSINESS NAME: ARCO OIL AND GAS COMPANY OWNER NAME: ARCO OIL AND GAS COMPANY NAME OF THIS FACILITY: UNIT #2, SIXTH FLOOR LOCATION: 4550 CALIFORNIA AVE. LOCATION: 4550 CALIFORNIA AVE. STANDARD IND.' CLASS CODE: 1 3 11 CITY, ZIP: BAKERSFIELDr CALIFORNIA 93309 CITY, ZIP: BAKERSFIE,LDr CALIFORNIA 93309 DUN AND BRADSTREET NUMBER PHONE #: (805) 321-4000 PHONE #: (805) 321-4000 0 2 7 6 8 - 8 5 8.____Z_7 REFER TO INSTRUCTIONS FOR PROPER CODES 1 2 3 4 5 6 7 8 9 1~' 11 12 13 14 TRANS TYPE MAX AVERAGE ANNUAL MEASURE #DAYS CONT CONT CONT USE LOCATION WHERE . % BY NAMES OF MIXTURE/COMPONENTS CODE CODE AMT AMT EST UNITS ON SITE TYPE PRESSTEMPCODE STORED IN FACILITY WT SEE INSTRUCTIONS Physical and Health Hazard C.A.S. Number: 64742-48-9 Component #1 & CJ~.S. Number (Check all lhatapply) ComponentS2 & C.A.S. Number *99 USE CODE = PRINTING Delayed Sudden Release Immediate ~ F~reHazard ~ Reactivity r~ Health ~ ~1~ : ~ of Pressure Health Component #3 & C~.S. Number Physical and HeaJth Hazard C.A.S. Number: Component #1 & C~.S. Number 99 ISOP~INIC SOLV]~ 64742.-48-9 (Check all that apply) * Component ~2 & C.A.S. Number 1 [:~OL~'[vJ~-~ ~ FireHazard ~ Reactivity ~ Delayed r'~ Sudden Release ~ Immediate of Pressure Health Health Component#3&C~S. Number 1 CARBON B~C~ 1333-86-4 Physical and HeaJth Hazard C.A.S. Number: Component #1 & CA.S. Number 99 ISOP~INIC SOLV~I-~ 6474~-48-9 (Check all that apply) Component #2 & C~,.S. Number 1 [:~)L~S 64283-60-9 Delayed Sudden Release Immediate ~ I~reHazard ~ Reactivity ~ Health r~ of Pressure [-~ Heallh Component#3&C.A.S. Number 1 CAREN BLACK 1333-86-4 Physicaland Health Hazard C.A.S. Number: 75-63-8 Component#1 &c-A.S. Number (Check all thatapply) component#2 & C.A.S. Number ~99 USE C'ODE = FTRE r-~ Fire Hazard [----] Reactivity r-~ Delayed ~'1 Sudden Release ~-~ Immediate of Pressure Health Health Component #3 & C~.S. Number EMERGENCY CONTACTS ~ CECILIA ZACHERY SERVICES MANAGER 329-6144 (PAGER) , ~ TOM STEVENS MECHANIC 329-6282 (PAGER) Name Title 24 Hr Phone Name Title 24 Hr Phone Certification (H~ad and sign after completing all sections) I certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached documents, and that based on my inquiry of those individuals responsible for obtaining the information, I believe that the submitted information is true,accur,atle, and ~mplete. · Name and official title of owner/operator OR owner/operator's authorized representative Signature Date Signed LEC/1-91 Agriculture F'-"~ Standard Business CITY OF B $F_r LD Farm and HAZARDOUS MATERIALS INVENTORY NON-TRADE SECRETS BUSINESS NAME: ARCO OIL AND GAS COMPANY OWNER NAME: ARCO OIL AND GAS COMPANY NAME OF THIS FACILITY: BOO LOCATION: 4800 EASTON~ SUITE L. LOCATION: 4550 CALIFORNIA AVE. STANDARD IND. CLASS CODE: t 3 1 1 CITY, Z~P: BAKERSFIELD~ CALIFORNIA 93309 CITY, ZIP: BAKERSF,[ELD~ CALIFORNIA 93309 DUN AND BRADSTREET NUMBER PHONE #: 1805} 321-4000 PHONE #: (805) ,321-4000 O 2, - 7 6 8 - 8 5 8 7 REFER TO INSTR[ICTIONS FOR PROPER CODES 1 2 3 4 5 6 7 8 9 10 11 12 13 14 TRANS TYPE MAX AVERAGE ANNUAL MEASURE #DAYS CONT CONT CONm USE LOCATION WHERE % BY NAMES OF MIXTURE/COMPONENTS CODE CODE AMT AMT EST UNITS ON SITE TYPE PRESSTEMPCODE STORED IN FACILITY WT SEE INSTRUCTIONS Physical and Health Hazard C.A.S. Number: 7440-59-7 Component #1 & C~.S. Number (Check all that apply) Component #2 & C.A.S. Number Delayed ~ Sudden Release Immediate r-"] Fire Hazard [-"'] Reactivity [~ Heallh of Pressure [~ Health Component ~3 & C~,.S. Number Physical and Health Hazard C.A.S. Number: 1333-74-0 Component #1 & C.A.S. Number (Check all that apply) Component ~ & C.A.S. Number Delayed ~ Sudden Release Ir.mediate I---3 [--i Roac vity I--'1 Hea, I'--I Heelth Component ~3 & C.A.S. Number Physical and Health Hazard C.A.S. Number: 7727-37-9 component #1 & C.A.S. Number (Check all that apply) Component#2&CJ~,.S. Number *99 U$~. CODE = ?Brz"ROt,ElS~ :[AB Delayed ~ Sudden Release Immediate I--I R.c vity I---I Heal of.r ur I---I Heel component ~3 & C~.S. Number Physical and Heelth Hazard C.A.S. Number: component #1 & C~,.S. Number (Check all that apply) Component #2 & C~,.S. Number Delayed Sudden Release Immediate Component #3 & C~.S. Number #1 JAMES NABORS CORROSION SPECIALIST 765-6238 ~ KELLY LEE CORROSION ENGINEER 832-8613 Name Title 24 Hr Phone Name Title 24 Hr Phone Cerlification (Read and sign after completing all sections) I certify under penalty of law that I have personally examined and am familiar with the information submitted in this and all attached documents, and that based on my inquiry of those individuals responsible for obtaining the information, ! believe that the submitted information is true,accurate, and complete. Name and official title of owner/operator OR owner/operator's authorized representative Signature Date Signed LEC/1-91 , ' BAKERSFIELD CITY FIRE DEPARTMENT ~. 2~o "~" s'i~'r ' BAKERSFIELD, CA 93301 (805) 326-3979 OFFICIAL USE ONLY ID# BUSINESS NAME HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE FORM 2A INSTRUCTIONS: 1. To avoid further action, return this'form Within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible~ SECTION 1: BUSINESS IDENTIFICATION DATA A.BUSINESS N~. ARCO OIL^ND GAS COMPANY. OFFICE BUILDING s. t.OCATIO~ / smm'r ADDe.~SS: ' n~0 C^L~FoHni^ ClTY: ~ D ~ 93309 BUS. PHONE: : (805) 321-4000 sECno~ 2: E~OENC¥ NOn'CATIONS In case of an emergency involving the release or threatened release 'of a hazardous material, \ call 91-1 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and. the State Office of Emergency Services as required by law. 'EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE ,. DURING BuS. HRS. AFTER BUS. HRS. A. ,leto/_ Tfickey - Dist. Prod. SuDefintendent Ph# (805) 3~ -4053 Ph# (805) 831-4486 B. Cecilia Zache~ - Services Manager Ph# (805) 3~1-4~ 77 Ph# (805) 83~-1848 ~ECTION 3; LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: '. OI. JTSIDE THE BIJlLDING ON THE NO~ITHEAST END B. ELECTRICAL: IN A HOOM ON THE nOglTHEA~T END OF THE BUILDING IN THE BASEMENT Al:lEA C. WA'IER: OLJTSIDE THE BLJILDING ON THE NOlqTH END . E. ~OC~ sOX: '~s / NO IF ~S, ~OCATIO~: F~aE con~aoL aOOM On X.E aaouno F~ooa IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDS'S? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO LEC/APR 1989 page 1 ' SECTION 4; PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE This facility has an Emergency Response Plan in effect. The plan covers emergency responses for medical, fire and chemical release emergency events; A team approach ·is incorporated in the Emergency Response Plan for evacuation procedures. ~ECTION 5: LOCAL EMERGENCY'MF~DICAL ASSISTANCE FOR YOUR BusINEss AS A WHOLE' For minor injuries, victims are taken to Bakersfield FamilY Medical Center, 4580 California Avenue, Phone #·327-4411. The nearest hospital is Mercy Hospital lOcated at'2215 Truxtun Avenue; patient information 'phone # 327-3371. For emergencies, personnel are instructed to call 911 ~. SEQTIoN 6: .EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE'A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE SAFE HANDLING OF HAZARDOUS MATERIALS: A. NUMBER OF EMPLOYEES AT THIS FACILITY 290 B. DO YOU HAVE MSDS (MATERIAL SAFETY DATA SHEETS) FOR EACH HAZARDOUS MATERIAL YOUHANDLE? YES C, . GIVE A BRIEF SUMMARY OF YOUR HAZARDOUS MATERIALS TRAINING PROGRAM: This facility has a Hazard Communication Standard Program in effect. Employees that handle hazardous· materials are briefed on the MSDS's for each chemical on the premises during periodic safety meetings. The briefings include handling, storage, release response information and personnel protective equipment usage. .SECTION 7: HAZARDOUS MATERIAL I CERTIFY UNDER PENALTY OF pERJURy THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTs OF cHAPTER 6.95 OF THE CALIFORNIA HEALTH AND SAFETY CODE FOR THE FOLLOWING REASONS: · - WE DO NOT HANDLE HAZARDOUS MATERIALS. WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIME EXCEED THE MINt~ KEPORTIN6 QUANTrrms. OTHER (SPECIFY ,REASON) SECTION 8: CERTIFICATION I, BILL ROSICA , certify that the above information is accurate. I understand that this information will· be used 'to fulfill my firm's obligations under the'.new California Health and safety Code on Hazardous Materials (Div. 20 Ch. 6.95 Sec. 25500 Et Al.) and that inaccUrate information constitutes perjury. LEC/ARCO BLDG/APR 1989 page 2 BAKERSFIELD CITY FIRE DEPARTMENT 2130 "0" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID# BUSINESS NAME · BUSINESS PLAN ·SINGLE 'FACILITY UNIT " FORM 3A 1. To avoid· further action, this form must· be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. ~ 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW. 4. Be as BRIEF and 'CONCISE as possible, but explain fully. FACIL1TYUN1T'#. 1 FACIL1TY UNIT NAME: ARCO OFFICE BUILDING1 THIRD FLOOR SECTION i: MITIGATION. PREVENTION. ABATEMENT PROCEDURES Inventories are kept to a minimum. The ammonia cylinder is contained in a metal cabinet with forced draft ventilation to the outside.. Employees regularly inspect the valves on 'the pressurized cylinders~ For a large ammonia release,' the emergency response plan will be initiated and the Fire Department notified. '., SECTION 2: NOTIFICATION AND EVACUATION PROCEDURES AT THIS UNIT ONLY This facility has an Emergency Response Plan that includes notification and evacuation Procedures.. In the event of an emergency, the Command Center (Room 768 - Operations Manager) will notify "FloOr Wardens" of the emergency.. The wardens will coordinate the evacuation of his/her respective floor by directing personnel to the safest exit. The wardens verify that their floor has been completely evacuated befOre leaVing the premises. LEC/ARCO BLDG/APR 1989 page 1 SECTION 3: HAZARDOUS MATERIALS FOR'THIS UNIT ONLY · A. Does this Facility Unit contain Hazardous Materials? ..... YES NO · If'YES, see B. If NO,' continue with. SECTION.4~ Bi Are any of the hazardous materials a bona fide· Trade Secret as defined by Section 6254.7 of the Oovernment Code? ...... YES NO If No, complete· a Separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form ~A=I). If Yes, complete 'a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form ~A-2) in addition to the non-trade secret form. .List oniy the trade secrets on form 4A=2. SECTION 4: PRIVATE FIRE PROTECTION SYSTEM In conjunction with the Emergency Response Plan, evaCuation procedures and floor plans are located on the inside of all the office doors~ A designated central fire control room is located on the ground floor. Fire extinguishers and City fire alarm boxes are located on all floors. Water sprinklers throughout.the building are set-off by smoke detectors wired to a notification system that automatically calls the Fire ~Department. SECTION 5: LOCATION OF WATER sUPpLY FOR USE BY EMEROENCY RESPONDERS Outside hydrants are located northeast and southweSt of the building. Connections · for. fire hoses are located on the.landings of each floor in the stairwells. SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY A. NAT. GAS/PROPANE: ' Main shut-off for the entire building is located outside the building on the northeast end. ' B. F_,LECTRICAL: Main electrical panel is located in a room on the northeast end of the building in the basement area. Electrical shut-off for the third floor is located in room 394. C. WATER: Main shut-Offs for the entire building are located outside the building on the northeast 'end. D. SPECIAL: E. LOCKBOX: YES/NO IFYES, LOCATION: Fire Control Room onthe Ground Floor IF YES, SITE PLANS? - YES / N O. MSDS's? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO LEC/ARCO BLDG 3rd FLOOR/APR 1989 page 2 FARMANDAGRICULTURE ~ STANDARDBUSINESS ~ CITY OF BAKERSFIRLD Page 1' of 1 H.4ZARDOUS MATERIALS INVENTORY -- NON-TRADE SECRETS BUSINESS NAME: ARCO OIL ANDGA$ (~OMPANY OWNER NAME: ARCO OIL AND GAS COMPANY NAME OF THIS FAClUTY: UNIT t~1, THIRD FLOOR LOCATION: 45~50 CALIFORNIA AVENUE LOCATION: 4500 CALIFORNIA AVENUE STANDARD IND. CLASS CODE: 1311 .CITY, ZIP: BAKERSFIELD. CALIFORNIA 93309 CITY, ZIP: ' BAKERS.FIELD, (~ALIFORNIA 93309 DUN AND BRADSTREET NUMBER PHONE: {805) 321-4000 ' PHONE: (805~ 321-4000 02 - 768 -. 8587 I~_~FER TO EVSTRUC~ONS FOR PROPER CODES 1 2 3 4 5 6 7 8 9 10 11 12 13 . 14 . . TRANS TYPE, MAX AVERAGE ANNUAL MEASURE # DAYS CONT CONT CONT USE LOCATION WHERE % BY NAMES OF MIXTURE/COMPONENTS · CODE CODE AMT . AMT EST · . UNITS ON SITE T'YPE PRESSTEMPCODE STORED IN FACILITY WT SEE INSTRUCTIONS· Physical .and Health Hazard C.A.S: Number 7664-41-7 Component #i Name & CA.S. Number '99 USE CODE = pRINTING (Check all that apply) I---"] . ~ r-'-I ~ ~ Component ~ Name & C.A.s. Number Fire Hazard . Reactivity Delayed Sudden Release Immediate Health of Pressure Health Component #3 Name & C.A.S. Number Physical and Health Hazard C.A~S. Number ' Component #1 Name & CA.S. Number (Check all that apply) r'-'-] [-~ -~ . ~ ~ - ~ . Component ~2 Name & C.A.S. Number Fire Hazard Reactivity -Delayed Sudden Release Immediate . Health of Pressure Health Component #3 Name & C.A.S. Number !' Physical and Health Hazard C.A.S. Number Component #1 Name & CA.S.'Number (Check all that apply) ~ .r..~-i i----i ~ 1~1 ~ 'Component ~ Name & C;A~S. Numbei' . · Fire Hazard Reactivity Delayed Sudden Release . Immediate · Health of Pressure Health .. Component g3 Name & C.A.S. Number EMERGENCY CONTACTS #1 '.CECILIA ZACHERY .. ' SERVICES MANAGER .. 329-6144(PAGER) Name Title 24 Hr Phone //2 TOM STEVENS ~' ' - BUILDING MECHANIC 329-6282 (PAGER) . Name Title 24 Hr Phone Certificatbn '(Read and ~ after COmpleting ali sections) . . · ' .. ' I certify under penalty of law that I have perSOnally examined, and am familiar.with the information submitted in this and all attached documents, and that based on my inquiry of those individuals responsible for obtaining the information; I believe that the submitted information is true,accurate, and complete. ..~ ' BiLL ROSlCA ENVIRONMENTAL COORDINATOR ' ~. ' · "" Name and official title of owner/operator OR owner/operator's authorized representative ~/' Signature Date Signed LEC/APR 1989 . BAKERSFIELD CITY FIRE DEPARTMENT 2130· "O" sTREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY ID# BUSINESS NAME BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid. further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERs IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW. 4. Be as BRIEF and 'CONCISE as possible, but explain fully. FACILITYUN1Tg. 2 FACILITY UNIT NAlVIE: ARCO OFFICE BUILDING, SIXTH FLO0R ~]ECTION 1: MITIGATION. PREVENTION. ABATEMENT PROCEDURES , Inventories are kept to a minimum. EmplOyees uSe absorbent .material to Wipe up liquid spills Within the building. SECTION 2: NOTIFICATION AND EVACUATION PROCEDURES AT THIS UNIT ONLY This facility has an Emergency Response Plan that includes notification and evacuation procedures. In the event of an emergency, the Command Center (Room 768 - Operations Manager)'will notify "Floor Wardens" of the emergency. The wardens will coordinate the evacuation of his/her respective floor by directing personnel to the safest exit. The wardens verify that their floor has been completely evacuated before leaving the premises. LEC/ARCO BLDG/APR 1989 page 1 SECTION 3: HAZARDOUS MATERIALS FOR THIS UNIT ONLY A. Does this Facility' Unit contain Hazardous Materials? YES NO ff YES, See B. If NO, continue with SECTION 4. B. Are 'any of the hazardous materials a bona fide Trade Secret as -defined by Section 6254.7 of the Government Code? . . .-.... YES NO If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form .~4A-1). If Yes, complete a hazardous materials inventory form' marked: TRADE SECRETS ONLY (yellow form #4A-2) in addition to the non-trade secret form.. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION SYSTEM .' In conjunction With the Emergency Response Plan, evacuation procedures and floor plans 'are located On the inside of all the office doors. A designated central fire control room is located on the ground floor. Fire extinguishers and City fire alarm boxes are located on all floors. Water sprinklers throughout the building are set-off by smoke detectors wired to'a notification system that automatically calls the Fire Department. Room 690 has a Halon fire system. SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS Outside hydrants are ~ocated northeast and southwest of the building. Connections for fire hoses are located on the landings.of each floor in the stairwells. SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY : A.. NAT. GAS/PROPANE: Main shut-off for the entire building is located Outside the building on the northeast end. B. ELECTRICAL: ., Main electrical panel is located in a room on the northeast end of the building in the basement area. Electrical shut-off for the sixth floor is loCated in room 694.. C. WATER: Main shut-offs fOr the entire building are located outside the building on the northeast end. D. SPECIAL: E. LOCKBOX: YES/NO IFYEs, LocATION: .Fire Control Room on the Ground Floor IF YES, SITE PLANS?. YES / N O MSDS's? YES/N O FLOOR PLANS? YES / NO KEYS? YES / NO LEC/ARCO BLDG 6th FLOOR/APR 1989, page 2 FARM AND AGRICULTURE ~ STANDARD BUSINESS ~ CITY OF BAKERSFII~LD H~7,ARDOUS MATERIALS INVENTORY Pagelof 2 , . NON-TRADE SECRETS .. BUSINESS NAME: .AR(~O OIL AND GAS COMPANY OWNER NAME:_ ARCO O!L AND GAS COMPANY NAME OF THIS FACILITY: UNIT #2, SIXTH FLOOR LOCATION: 4550 CALIFORNIA AVENUE LOCATION: '4500 QA.LIFORNIA AVENUE ' STANDARD IND. CLASS CODE: 1311 CITY, ZIP: BAKERSFIELD, CALIFORNIA ~3,309 ' CITY,'ZIP: BAKERSFIELD. cALIFORNIA 93309 DUN'AND BRADSTREET NUMBER PHONE: 1805) 321-4000 PHONE: (805) 321-4000 02 - 768 - 8587 RRFER TO INSTRUCTIONS FOR PROPER CODES 1 2 3 4 5 6 7 ' 8 9 10 11 12 13 14 TRANS TYPE MAX AVERAGE ANNUAL MEASURE # DAYS CONT CONT CONT USE LOCATION WHERE % BY NAMES OF MIXTURE/COMPONENTS CODE CODE . AMT AMT EST UNITS ON SITE TYPE PRESSTEMP CODE STORED IN FACILITY · WT SEE INSTRUCTIONS'" Physical and Health Hazard · C.A.S. Number 64742-48-9 Component #1 Name & C.A.S. Number (Check all that apply) xI I---1~ I~. ~ . Component b*2 Name & C~,.S. Number Fire Hazard Reactivity Delayed Sudden Release Immediate . Health of Pressure ' Health Component ~G Name & C.A~S. Number *99 USE CODE = PRINTING Physical and Health Hazard (Check all that apply) C.A.S. Number Component. #1 Name & CA.S. Number 99 ISOPARAFFINIC SOLVENT 64742-48-9 I X'[ ''[~] 'r~-] [-'~'~ ~ -. Component~2Name&C.A.S. Number ':1 POLYMERS '64283-60-9- Fire Hazard Reactivity Delayed Sudden Release Immediate Health of Pressure. Health . Component #3 Name & CA.S. Number 1 CARBON BLACK 1333-86-4 Physical and Health Hazard C~A.S. Number Component #1 Name & CA.S. Number' 9 9 · IsOpARAFFINIC SOLVENT 64742~48-9 (Check all that apply) I x I I---] ~ r~l ~Component ~ Name & CA.S. Number l 1 POLYMERS 64283-60-9 Fire Hazard Reactivity Delayed Sudden Release. Immediate . Health of Pressure Health Component ~ Name & C~.Sl Number 1 cARBoN BLACK 1333-86-4' EMERGENCY CONTACTS #1 CECILIA ZACHERy SERVICES MANAGER 329-6144 (PAGER) Name Title 24 Hr Phone #2 TOM STEVENS BUILDING MECHANIC 329-6282 (PAGER) ' Name ~ Title 24 Hr Phone Cerlification (Read.and sign after.comPletinE all sections) I certifY under penalty of law that I have Personally examined' and am familiar withthe information submitted in this and all attached documents, and' that based on my inquiry. of those individuals responsible for obtaining the information, I belieVe that the SUbmitted information is true,accurate, and complete. 'B,.' ROS,CA - E.V, RONMENTAL COORD,.ATOR' ' .. . Name and official title of owner/operator~OR oWner/operator's authorized representati~.,/ ' Signature Date Signed EEC/APR 1989 FARMANDAGRIcULTURE ~-~]' STANDARDBUSINESS ~ CITY OF IlAICRRSFIE~LI) " Page 2 of 2 .. H ZARDOUS MATERIALS INVENTORY , NON-TRADE SECRETS BUSINESS NAME: ARCO OIL AND GAS COMPANY . OWNER NAME: ARCO OIL AND GAS COMPANY NAME OF THIS FACILITY: ' UNIT #2, SIXTH FLOOR LOCATION: 4550 CALIFORNIA AVENUE ·LOCATION: 4500 CALIFORNIA AVENUE - '. STANDARD IND. CLASS CODE: 1311 CITY, ZIP: BAKERSFIELD, (~ALIFORNIA 93309 CITY, ZIP: BAKERSFIELDi CALIFORNIA 93309 .DUN AND BRADSTREET NUMBER PHONE: (805) 321-4000 PHONE: (805)321-4000 ' 02 - 768 - 8587 ,, , o'TRUC ONS FOR PROPER CODES 1 2 3 4 5 6 '7 8 9 10 11 12 13 14 ' TRANS TYPE MAX AVERAGE ANNUAL MEASURE# DAYS CONT CONTCONT USE · LOCATION WHERE ' % BY NAMES OF MIXTURE/COMPONENTS CODE CODE AMT AMT EST UNITS ON SITE TYPE PRESSTEMPCODE STORED IN FACILITY' WT SEE INSTRUCTIONS U'-~'~-~ 1538 r1538 [ 1538 ~ RM. 690 100 HALON1301 PhysiCal. and Health Hazard C.A.s. Number 75-63-8 Component #1 Name &CA.S. Number *99 USE CODE= (Check all that apply) II· ~--~. ~ ~ ~-~ ~ Component #2 Name & CA.S. Number FIRE PROTECTION Fire Hazard ReactiVity Delayed Sudden Release Immediate Health of Pressure Health Component #3 Name & c-A.S.'Number PhysiCal and Health Hazard C~A.S. Number Component #1 Name & C.A.S. Number (Check all that apply). . · ~ ~ F~I' ~ ~--~ · Component #2 Name & C.A.S. Number Fire Hazard Reactivity Delayed Sudden Releasel Immediate Health of Pressure Health Component fl3 Name & C~.S~ NUmber PhysiCal'and Health Hazard ' C.A.S. Number' Component #1 Name & C~'.S. Number (Check all that apply) . ~ ['---'] . ~ ~"~' . [---'-~ . Component #2 Name & C~.S. Numbar Fire Hazard Reactivity Delayed Sudden Release Immediate · ' Health of Pressure Health ' Component ~ Name & c'A.S. Number EMERGENCY CONTACTS #1 . CECILIA ZACHERY SERVICES MANAGER 329-6144(PAGER)': Name Title '. 24 Hr Phone · '~Y2 TOM STEVENS ' BUILDING MECHANIC.. 329-6282 (PAGER)_ Name Title ~. 24 Hr Phone Certification (Read and sign after completing all sectiOns) : I certify.under penalty of law that I have personally examined and am familiar with the information submitted in this and all attaohed documents, and that based.On my inquiry of those -individuals responsible for obtaining the information, I believe that the submitted information is true,accurate, and complete. ' BILL ROSlCA - ENVIRONMENTAL COORDINATOR ~(~ ~;~,,~ (~/z e/®-~ _ Name and official title of owner/operator OR owner/operator's authorized representative Signature ' - E~ate Signed· LEC/APR 1989 ACUTELY HAZARDOUS MATERIALS REGISTRATION FORM THIS FORM MUsT BE COMPLETED BY THE OWNER OR OPERATOR OF EACH BUSINESS IN CALIFORNIA WHICH AT ANY TIME HANDLES ACUTELY' HAZARDOUS MATERIAL IN QUANTITIES 'GREATER THAN 500 POUNDS, 55 GALLONS OR 200 CUBIC FEET OF GAS AT STP. SUBMIT THIS FORM TO YOUR LOCAL ADMINISTERING AGENCY. ( ~ 25533 & 25536 Health & Safety Code) ' Note Instructions on reverse ausmsss Name ARCO Oil and Gas Company -- Buslnsss Site Address 4500 California Avenue. BakerSfield. CA 93309 Business Mailing Address (if different) P.O. BOx 147, BakerSfield. CA 93302 Business Phone (805} 321~4000 Business Plan Submission DateI July 1987 Process Designation2 ' Use Code 99. Printing Process ACUTELY HAZARDOUS'MATERIALS HANDLED3 -USE ADDITIONAL PAGES IF NECESSARY- CHEMICAL NAME ' QUANTITY Anhydr0u$ Amm0nig C.A.$. # 7664-41-7 6700 cubic feet GENERAL DESCRIPTION OF PROCESSES AND PRINCIPAL EQUIPMENT4: Anhydrous ammonia is used as a developer in an Ozalid Blue Line Machine bv the draftina department of ArCo Oil. and Gas ComPany. 'The ammonia is stored in a pressurized cylinder, as shown in the Business Plan for this f~cility. sIGNATURE ~-)~~~ TITLE Environmental Coordinator PRINTED NAME Bill ROsice, DATE (o/&.R/~9 CalifOrnia Office of EmergencY Services FORM HM 3777 (8-25-87) INSTRUCTIONS: Superscripts: 1. Please contact your Administering Agency if you have reportable quantities of Acutely Hazardous Materials and have not submitted a business plan. 2. "Process Designation" is provided for facilities that would most easily be reported by process. This will allow subdivision of a facility in agreement with the business plans. This will also provide information to simplify facility inspections and future emergency response. 3. Use EPA list of Acutely Hazardous Chemicals from the Federal Register, Volume 52, No. 77, p. 13397 et. see.. April 22, 1987. If appropriate, attach a copy of the inventory submitted to your Administering Agency with all Acutely Hazardous Materials highlighted. 4. Do not include Trade Secret information in these descriptions. General: For emergency response purposes, it would be desirable to describe the following to the Administering Agency: 1. Batch Process: a. What raw materials? b. What operating pressure range? c. What operating temperature range? d. Batch capacity rating? e. Product chacteristics? (e.g., state, flammability, toxicity, etc.) f. Critical process points and characteristics? 2. Continuous process: (similar information as above.) NOTE: 'Within 90 days after receiving an acutely hazardous material registration form filed pursuant to §25533, the Administering Agency may require the submission of a Risk Management Prevention Program (RMPP), if the Administering Agency determines that the handler's operation may present an acutely hazardous materials accident risk. The handler shall prepare the RMPP in accordance with subdivision (c). The RMPP shall be prepared within 12 months following the request made by the Administering Agency pursuant to this section.' (§25534 (a) Health and Safety Code) An amendment to the RMPP must be submitted to the Administering Agency within 30 days of: 1. Any additional handling of acutely hazardous materials. 2. Any material or substantial alterations to business activities. 3. Change of address, business ownership, or business name. (§25533'(c)~" 'l~ealth & Safety Code) · EVERY BUSINESS REQUIREDTOSUBMIT AN RMPP SHALL IMPLEMENT THE APPROVED RMPP. California Office of Emergency Services FORM HM 3777 (8-25-87)~ 2130 "G" STREET BAKERSFIELD. CA 93301 (005} 326-0979 ' OFFICIAL USE ONLY USINESS NAME HAZARDOUS I~TE R I ALS BUSINESS PLAN AS A WHOLE FORM 2A 1. To avoid fuvthee action, return this foem by ~. TYPE/PRINT ANSWERS IN ENGLISH. 8. answer the questions below foe the business as a whole. 4. Be as beief and concise as possible. SECTION 1: BUSI~SS IDE~IFICATION DATA A. BUSINESS NAME: ARCO 0~]' and Gas Compan3 B. LOCATION / STREET ADDRESS: 4550 California Avenue CITY: Bakersfield ziP: 93309 · BUS.PHONE: (805) 321-4000 SECTION 2: E~RGENCY NOTIFICATIONS In case of an emergency involving the ~elease o~ threatened ~elease of a hazardous material, call 911 and 1-800-852-7550 o~ 1-916-427-4341. This will notify you~ local fire department and the State Office of EmeF~ency SeFvices as ~equi~ed law. ' EMPLOYEES TO NOTIFY IN CASE OF E~ERGENCY: N~E AND TITLE DURING BUS. HRS. AFTER 8US. HRS. A. Cecilia Zachery - Services Manaqer Ph~ 321-4177 Ph~ 832-]848 B. John Hand]in : Business Manaqer Ph~ 321-4200 Ph~ a36-216a SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A ~IOLE A. NAT. GAS/PROPANE: _/~No main shutoffs ,for business as'a whole. Ser- B. ELECTRICAL: ~l each facility for location of shutoffs. c. D. SPECIAL: E. LOCK BOX: YES ~ IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? · YES / NO KEYS? YES / NO - 2A - ~ ~'~'~.~ SECTION 4: PRIVATE RESPONSE TE~ FOR BUSINESS AS A mOLE No private response team is used by ARCO at this location. SECTION 5: LOCAL ENERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS ASA ~HOLE For ~r~i~diu.ries, victims are taken to Bakersfield Family Medical Center. For emergencies, personnel are instructed to call 911. SECTION 6: EI~LOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF HAZARDOUS ;MATERIALS * Z~ ~ :.... .................................... NO NO B. PROCEDURES FOR COORDINATING ACTIVITIES· WITH RESPONSE AGENCIES:~ ......................... ~ NO /~.NO C. PROPER USE OF SAFETY EQUIPMENT:~ ................. ~ NO ~ NO D. EMERGENCY EVACUATION PROCEDURES: ................. /-~ NO ~ NO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... ~ NO /~ NO · 0n]y those employees who are required to handle SECTION ?: HAZ~ugDOUS NATERIAL hazardous materials. CIRCLE YES OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES NO I, ~ancy B. J0hannesmeyer , certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 Et Al.) and that inaccurate information constitutes perjury. SIGNATURE ~~.~~ TITLEEnvironmental Enc~¥~LDATE Jul,y 15, 1987 BAKERSFIELD CITY FIRE DEPARTMENT 2130 "O" STREET BAKERSFIELD,, CA 93301 - OFFICIAL USE ONLY BUSINESS BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A- INSTRUCTIONS 1. To avoid further action, this form must be returned by:' 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. FACILITY b~IT#. ' ' i - FACILITY.UNIT N~ME: ' Easement SECTION 1: MITIGATION, pREvE~ION, ABATEMEN~ PROCEDb~ES PREVENTION: .Inventor.les are kePt to a minimum, ·Regular'inspection. of diesel Storage area. For emergency firefighti.ng purposes only. ABATEMENT & Use of rags and absorbent material in case of ·spill, MITIGATION: SecondarY containment of diesel ,storage tanks; SECTION 2: NOTIFICATION ANq) EVACUATION PROCEDL'RES AT THIS UN'IT ONLY Notification. in the event of a fire will be through fire alarms, This part of the building is not normally occupied, however, other floors have. "Floor ~lardens" assigned.. In. the event of an emergency, the Command Center (Room 768, Operations Manager) ~ill not~fy, each warden of the emergency. Wardens coordinate evacuation of his/her floor.- .. Evacuation of the basement will be thro. ugh the driVeway ent'rance-_]onthe southwest si de of~ the building. SECTION 3: HAZARDOUS 'WATERIALS FOR THIS UNIT ONLY A. Does..this.FaCtlity Unit contain Hazardous ~ateria!s? ...... /YE~ NO If YES, see B. [f NO, continue with SECTION 4. '. B. Are any of the hazardous materials a bona fide Trade Sedret YES ~0 / · If No, complete a separate hazardous'materials Inventory form marked: NON-TRADE SECRETS ONLY (white form ~4A-1) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form-~4A-2) in addition to the nonLtrade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION Fire hydrant located in stairwell. Automatic sprinkler system tied into' Fire De- partment., Fire alarms notify City Fire Department; Central fire room located on ground 'fl oor. SECTION $: LOCATION OF' WATER' sUPPLY'FoR USE BY EMEROENCY RESPONDERS Outside hydrant located on east side of building. Connection for firehose in stairwell. SECTION 6: LOCATIO~ OF UTILITY SHUT-OFFS AT THIs L~IT ONLY. A. NAT. GAS/PROPAN.~ Shutoff located in lawn area next to basement"s driveway entrance. ~. ELECTRICAL: Main electrica] )ane] is located on east.end of basement. c. WATER: Shutoff located'on east side of basement b~'water sto~.age tank.. Outside shut- off located east of building. D.' SPECIAL: E. LOCK BOX YES / NO /IF YES, LOCATION: IF YES, SITE PLANS? YES ./ NO MSDSs? YES / XO FLOOR PLANS? YES / NO KEYS? YES / NO ~ 3B - BAKERSFIELD. CITY FIRE DEPARTMENT 2130 "G" STREET BAKF~RSFIELD, CA 93301 · . ...- OFFICIAL USE ONLY BUSINESS N~ME: .' '-. ~ BUSINESS' PLAN' · SINGLE FACILITY UNIT· .FORM 3A INSTRUCTIONS 1. To avoid further'action, this form must· be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH.' 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible.- FACILITY b~IT~ .2' FACILITY UNIT N~ME: .Third (3rd) Floor SECTION 1: .MITIGATION~ PRk-v'E~ION, ABATEMENT PROCEDb~ES PREVENTIONi Invent°rjes are kept to a minimum. '> Ammonia is stored in a.leak-proof air-tight..cabinet. Regular inspection of ammonia storagel· ABATEMENT & ~ShutOff va~'ve for ammonia tanks located in$ide, stdnage cabinet, MITICATION: Ammonia vapors vented to outside. For large ammonia releases, operator is instructed to contact Fire Department for help. SECTION 2: NOTIFICATION Ai%~ EVACUATION PROCEDL~ES AT THIS L%'IT ONLY Notification in the event of a fire will be. through fire alarms, - "Fqoor wardens are assigned to each floor, tn the event of an emergencY,.the Command Center .(Room 768 - Operations Manager) will notify each warden of/the emerge'ncy. The wardens will coordinate the evDcuation.of his/her respective filoor by. directing personnel to the'safest exit. Exits are Shown on the attached floor plans. Wardens veri.fy that their 'floor has been completely evacuated before leaving 'the premises. [ SECTIO 3: AZARUOus TERIALs FOR THIS nit ONlY A. Does this. Facility Unit contain HazardoUs Materials? ....... ~ES/ NO · If YES,.see B. If NO, continue with SECTION 4. ' ..... B. Are any. of the hazardous matertals'a bona fide Trade Sedret YES · If N0,.comPlete a separate hazardous materials 'Inventory form marked: NON-TRADE SECRETS ONLY (white form ~4A-1) ~ .If Yes, completea hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form ~4A-2) in addition to the' nonLtrade secret form. List only the trade secrets on form 4A-2. ~SECTION 4:'PRIVATE FIRE PROTECTION Fire extjngu'ishers']o~ated as noted throughout building. · Automatic Sprinkler'system'throughout building triggered by smoke detectors tied into Fire ~Department. Fi re alarms notify City. Fi re Department.. Central 'fi re.control .room loCated on · , ~. g.round floor.. . ' SECTIO~ $: LOCATION OF WATER SUPPLY'FOR USE BY E,~RGENCY RESPONDERS Outside hydrant located'on east side of building. . ConnectiOns for.fire hoses located on landings.of eaCh.floor i,n stairwell, - SECTION 6: LOCATION OF L"rILiTY SHUT-OFFS AT THIS L~IT O~Y. A. NAT. GAS/':PROPAN~ Natural'gas shutoff located,'on east side of building next to water shutoff, ~. ELECTRICAL.: Ma~.neleCtrical panel is. located in room on the east end of the building in the basement C.-'WATER: : ~iShutoff l'oc~ted on east'~ide of bui~]ding. ,A~diti~nal'shutoff located in basement on east end of. building bywater storage · tank. D. spECIAL: E. LOCK BOXi YES .//~0 / IF YES, LOCATION: IF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS? YES / NO KEYS? YES ..' ; .., BAKERSFIELD CITY FIRE DEPARTMENT /. 2130'"G' STREET BAKERSFIELD, CA. 93301 I OFFICIAL USE ONLY · BUSINESS N~E: " BUSINESS PLAN· sINGLE FACILITY UNIT · FORM'3A INSTRUCTIONS 1. To avoid further action, .this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH.~ '3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be'as BRIEF and CONCISE as possible. FACILITY L~IT*. '3' FACILITY b~IT N~'4'E: Si:Xth (6th)'.Floor' SECTION 1: MITIGATION, PREVEntION, ABATEMENT PROCEbb~ES ~pREVENTI. ON: Inventories are kept to a minimum. ABATEMENT & Use of rags and absorbent material to wipe uP liquid spills with- IqITIGATION: in building. -SECTION 2: NOTIFICATION ~\~ EVACUATION PROCEDL~ES AT THIS L~'IT ONLY Notification iu the'event of a fire will be through fire alarms, "Flbor wardens" are assigned to each floor. In the'event o~ an emergency, the Command Center (Room 768 -'Operations Manager) will notify each warden of the emergency. The wardens will coordinate the evacuation of his/her respective floor by directing personnel to the safest exit."Exits· are shown on the attached floor plans. 'Wardens verify that their floor has been completely evacuated before leaving the )remises~ SECTION 3: HAZARDOUS MATERIALS FOR THIS UNiT ONLY A. DoeS[this Facility Unit contain Hazar'dous Materials? ...... /YES/ NO If YES, see B. If NO, continue with SECTION 4. B. Are.any of the hazardous materials a. bona'fide Trade Sedret-YES /.NO / · If No, complete a separate haZardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form ~4A-1} If Yes, complete a hazardous materials inventory form marked: TRADE'SECRETS ONLY (yellow form ~4A-2) in addition to the nonLtrade secret form. List only the trade secrets on form 4A-2. SECTION 4: 'PRIVATE FIRE PROTECTION Fire ex-tinguishers, located.as 'noted throughout building. Automatic sprink!'er system throughout building triggered by smoke detectors tied in~o Fire Department. Halon fire system located in computer room on six.th floor.. Fire alarmS.notify CitY Fire DePartment. ~Central fire control room located on ~-ground floor. SECTION 5: LOCATION OF WATER SUPPLY'FOR USE BY EMEROENCY RESPONDERS Outside hydrant located on east side of bUilding. Connections for fire hoses located on landings of each.floor in stairwell. SECTION 6: LOCATION OF L~ILIT~ SHUT-OFFS AT THIS L~IT ONLY.· A. NAT. GAS/'PROPAN~ Natural gas shutoff located on east side of bUilding next to water shUtoff, ~.~ ELECTRICAL: Main electrical'panel is located in room on the east end of the building i·n the . .basement.'· C.. WATER: · Sh·Utoff located on east s'ide of building. ' Additional shutoff locatedin basement on eaSt end·o~ building by, water sto~age ';. U. SPECIALi E. LOCK BOX YES / ~ IF YES, LOCATION: IF YES, sITE PLANS? YES ./ NO .' MSDSs? YES / NO {. FLOOR PLANS?' YES / NO KEYS? YES / NO BAKERSFIELD CITY FIRE DEPARTMENT FORM 4A-1 page 1 of 1' I.D. # N O N - T R A D E S E C R E T S HAZARDOUS MATERIALS INVENTORY BUSINESS NAME: ARCO Oil and Gas Company OWNER NAME: ARCO Oil and Gas Company FACILITY UNIT #: 1 ADDRESS: 4550 California Avenue ADDRESS: Same FACILITY UNIT NAME: ARCO Building.. CITY, ZIP: Bakersfield, CA 93309 CITY, ZIP Same PHONE #: (805) 321-4~00 PHONE #: Same OFFICIAL USE CFIRS CODE ONLY 1 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD D.O.T. CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE /~ 250 O !Gal 02 19 In basement by 100 Diesel Fuel CMLQ emergency generator ~ 80 0 Gal 02 19 In basement by emer- gency fireWater pump P 6700 81000 ft3 04 99 i3rd floor, Rm. 341 99.5 Anhydrous Ammonia . I CRMT printing P 20 300 Gal 10 08. 6th floor, Rm. 691 100 Dispersant-IsoparaYfi~c Splvent CMLQ M 5 50 Gal 10 99 6th floor, Rm. 691 99 ECP Toner Concentrates / ' CMLQ printing ~i ~ 80-90 Isoparaffinic Solvent CMLQ 10-20 iDye (Methacrylate Polymer) ORMS W213 55 300 Gal 10 40 6th floor, Rm. 691 Spent Dispersant and Toner CMLQ 99-100 Isoparaffinic Solvent CMLQ 0-1 Dye (Methacrylate Polymer) ORMS NAME Nancy B. Johannesme~er TITLE: Environmental Engr. SIGNATURE: ~a~7~~~tm~ Date: 7/2/87 EMERGENCY CONTACT: Cecilia Zachery TITLE: Services Manage¥ ~ ~HONE # B~/~.' HOURS: 321-4177 AFTER BUS. HOURS: 832-1848 EMERGENCY CONTACT: John Handlin TITLE: Business Manager PHONE # BUS. HOURS: 321-4200 PRINCIPAL BUSINESS ACTIVITY: Oil and Gas District Headquarters AFTER BUS. HOURS: 836-2164 '- - ARCO Petroleum Products Company EEC 391-87 Watson Refinery File 030-01 1801 East Sepulveda Boulevard Mailing Address: Box 6210 Carson, California 90749 Telephone 213 548 8000 September 16, 1987 R E C E I V E 0 ~--~ SEP 2 I 1987 ............ Attention: Members of the 2185/2187 ............ Administering Agency Gentlemen: Subject: AB 2185 Business Plans This letter is necessary to inform you of our compliance concerns for the business plan described in the Community Right to Know legislation AB2185/2187. California'is spotted with ARCO's gas stations,.terminals, chemical facilities and a refinery. In order to keep each one of facilities in compliance, we are trying to contact and attain the proper business plan forms and inventory directions from the respective administering agency. If you could, I would appreciate a copy of your plan so I can assure that the facilities in your jurisdiction are in compliance according to your requirements. Sincerely, Emergency Preparedness Coordinator APPC-700,~-.A ' - ARCO Petroleum Products Company Is a Division of AtlantlcRIchfieldComl:)any (7-81) Wesiern Disirict Posi Office Box 147 Bakersfield, California 93302 '~~' Telephone 805 321 4000 October 20, 1087 ~0V 3 1 87 lns'd ............ Mr. Ralph Huey . _. Bakersfield ~ D~partment 2130 "G" Street Bakersfield, California 93301 Dear Mr. Huey: ARCO Oil and Gas Company is in receipt of a request from your office requesting chemical breakdowns of gas- oline and motor oils that ARCO sells. ARCO Oil and Gas Company is the oil and gas exploration and production arm of Atlantic Richfield Company and as such does not manufactur, e or sell motor oil or gasoline. ARCO Petro- leum Products Company is the marketing arm of the cor- poration. Copies of your letter have been sent to ARCO Petroleum Products Company in Anaheim, California. If you have any questions, please contact me at (805) 321-4052 Sincerely, Nia~c ~B 'i~j~~e r ........ E-nvironmental- Engineer NBJ/sb cc: Mr. Corey L. Unfried, ARCO Petroleum Products ARCO Oil and Gas Company is a Division.of AtlanticRichfieidCompany Msos ~k~: 2050 XEROX. Material Safety Data Sheet - . om: M,y 22, 1985 ~ Sept. 30, 1986 Manufacturer:. Venatec (A Xerox Company) (Xerox Corp. Emergency Tel. No.: (716) 422-2177 - 2805 Bowers Ave. Rochester, N.Y. Information Tel. No.: (800) 828-6571 Santa Clara° CA' 95051 146M) Section I - Product Identification TradeNemes/Synonym$: Ve~latec Clear Disperlant Pert No.: aa03-1, ~K)3-1GR, ~103.2, a~03-3, ~103-3-2, 4403.1G R.2,4aO3-16-6 Chemical Name: Petroleum solvent · Inoredient~ ' CAS No.. Isoparaffinic petroleum solvent M742-~B-9 Section II - Emergency and First Aid Eyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash skin thoroughly With soap and warm water. Inhalation: Remove from exl3osure. Ob,aewe for any difficulty in breathing. Ingestion: Dilute stomach contents with several glasses of water. Do not induce vomiting Primary Route of Entry: Inhalation Symptoms of Overexposure: ingestion poses maximum risk of severe respiratory distress by aspiration, as well as cen.el nervous depression. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest, central nervous system toxicity. Additional Information: Consult a phylJcian.' Further information on file in Poisindex. Section III- Toxicology and Health Information This material has been extensively tested and evaluated by Xerox Corporation. When used as intended, it does not represent any known health or safety hazan~. Oral LDso: >.10 g/kg (Rat) Practically non-toxic. TLr: *None established Dermal LDse: >3.1 g/kg (Rabbit) Practically non-toxic. Inhalation LC,aa: 2240ppm/4 hrs. (Rat) Practically non-toxic. PEL: None established Eye Irritation: Not an irritant Skin Sensitization: Not a sensitizer · ~XEL: 200 ppm (Isoparaffinic ' - 'Petroleum Solvent) Skin Irritation: Not an irritant Human Patch: Non-sensitizing. May cause irritation and dermatitis with Prolonged or repeated cont. act. Mutagenicity: None available Carcinogens: None present Aquatic LCM: 'None available Additional Information: *The manufacturer recommends an exposure · limit of .:100ppm. ~XEL- Xerox GxPmure Form 58739 (10/~4) STAR N.A. - Not ADI)hcable · E00P~208 Tracle Name: I MSDS NO.: Versatec Clear gispersant I 2050 7. Section IV- Physical Data Alabearence~Odor: Water white liquid/mild odor" Softening Range: N.A. Boiling Point: .' 31 S-3480F (157-I 760C) Melting Point: ' None available Solubility in Water: Negligible Slaeciflc Grevity (NzO · 1): 0.75 Evalx)retion Rate: 0.3 (~butylacetate.m 1) Vapor Pressure (mm Hg): (~ 250C < 10 vapor Density (Air · 1): 5.0 pH · None available Volatile N.A. % (INgt.) 100% (Vol.) SectionV. Fire and Explosion Data Flash Point (Method Used): 10SOF (T.CC) Flammable LEL: 0.8% · Limit3 UEL: 7.0% Extinguishing Media: Foam, dry chemical, CO2, water fog or spray. Special Fire Fighting Pro(edures: Use air-supplied, breathing equipment for en¢lo~4~l areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Fire and Explosion Hazards: Do not mix or store with strong oxidants like liquid chlorine or concentrated oxygen. . Section VI - Reactivity Data Stable X Polymerization: Will Not Occu1 X HazardOus Decomposition Products: Fumes, smoke and carbon monoxide in the case of incomplete combustion. Incoml~tabliity (Materials to Avoid): Strong oxidants like liquid chlorine, concentrated oxygen, sodium or calcium hypochlorita. Section VII - Special Protection Information Respiratory PrOtection: None when~used as intended in Versatec (Xerox) products. Eye Protection: Splash goggles or face shield when a splash hazard exists (i.e. pouring). Protective Gloves: None when used as intended in Versatec (Xerox) products. Other: Chemical resistant apron or other clothing if needed to avoid repeated or prolonged skin contact. Section VIII- Special Precautions Handling and Storage: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame or strong oxidams. Conditions to Avoid: Adequate ventilation required (equivalent to outdoors). Section IX - Spill, Leak, and Disposal Procedures For Spills or Leakage: Remove ignition SOurces; ReCover free liquid, using an absorbant material (vermiculite, fire retardant, sawdust, etc.). Waste Disl~sal Method: Disl:~se of liquid and absorbant at an al)proved disposal site or facility. Ensure' conformity to local, state and federal regulations. Section X - Transportation Information DOTProper Shipping Name: Petroleum Naphtha Hazard Classification: Combustible Liquid ID Number: UNd11255 iOOH201 MSDS No.: 2001' =XEROX Material Safety Data Sheet o..,. ^ug:.19; 1985 II,vision: Sept. 30, 1986 Manufacturer: Versatec (A Xerox Company) (Xerox Corp. EmergencyTeI. No.: (716)422-2177 · 2805 Bowers Ave Rochester, N.Y. Information Tel. No.: (800) 828-6571 Santa Clara, CA 95051 14644) Section I - Product IdentificatiOn Trade Names/Synonyms: ' ECP - Process Black Concentrate ' Part No.: 4811-16, 4811-16-6 Chemical Name: None. Inqredients CAS No. Isoparaffinic petroleum.solvent (80-90%) 64742-48-9 Methacrylate co-polymer } (i0-20%) 9011-15-8 Carbon black 1333-86-4 Section II- Emergency and First Aid Eyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing. Ingestion: Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as Well as central nervous depression. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest, central nervous system toxicity. Additional Information: Call physician. See SectionVlll.' Further information on file in Poisindex. Section III- ToxicOlogy and Health Information This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or safety hazard. Oral LDso: None available TLV: *None established Oermal LOs0: >2 g/kg (Rabbits) practically non-toxic. Inhalation LCso: None available PELt None established Eye Irritation: Not an irritant Skin Sensitization: (Not a sensitizer ~XEL:' 200 ppm (Isoparaffinic Skin Irritation: (Not an irritant Petroleum Solvent) Human Patch: (1/100 dilution) potentially irritating**, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A *A-,'ar~d WP2 Assays. Carcinogens: None present Aquatic LC. so: None available· Additional Information: * The solvent manufacturer recommends an exposure limit of 300ppm for thepetroleum solvent. ** This is due to the solvent. tXEL - Xerox Form S8739 (10~4) STAR N.A. - NOt Al:)plicabie 600P9131 Trade Name: ECP- Process Black ntrat SDS No.: %* /'_.~ ~ 2001 .!: · Section IV- Physical Data Appearance/Odor: Black liquid / slight odor Softening Range: N.A. Boiling Point: 160°-. 180°C Melting Point: N.A. Solubility in Water:Immiscible Specific Gravity (H20 · 1): .75 - .82 Evaporation Rate: .25-.45 n-butylacetate Vapor Pressure (mm Hg): @20°C 1 Vapor Density (Air · 1):5.0' pH · N.A. Volatile: 85% (Vol.) .. Section V - Fire and Explosion Data " Flash Point (Method Used): 102° - 107° F (39-42°C) T. CC Flammable LEL: 0.8% Limits UEL: 7.0% Extinguishing Media: Foam, d~/chemical, CO2, water fog ' Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Fire and ExploSion Hazards: Do not mix or store with strong oxidants like liquid chlorine or concentrated oxygen. Section VI- Reactivity Data. Stability: Unstabl; I I Hazardous Ma¥Occur I I '* Stable X Polymerization: Will N~occurI x _ Hazardous Decomposition Products: Fumes, smoke and carbon monoxide in the case of incomplete combustion; Incomparability (Materials to Avoid): Strong oxidants such as liquid chlorine, concentrated oxygen, sodium · . or calcium hypochlorite. Section VII - Special prOtection InformatiOn Respiratory Protection: None when used as intended with.Versatec (Xerox) equipment; Eye Protection: · None when used as intended with Versatec (Xerox) equipment .... Protective gloves: Neoprene or nitrile gloves for prolonged or repeated skin contaCt. Other: None when used as intended with Versatec (Xerox) equipment. Section VIII- Special PrecaUtions Handling and Storage: Keep container closed. AVOid handling near heat, strong light, sparks, open flames, strong oxidants. Conditions to Avoid: Avoid breathing vapors. Avoid prolonged or repeated skin contact. Section IX - Spill, Leak, and Disposal Procedures 'For Spills or Leakage: Remove ignition sources. Recover free liquid.using an absorbant material (vermiculite, fire retardant, sawdust, etc.) Waste Disposal Method: Dispose of liquid and absorbant at an approved disposal site or facility. Ensure conformity with federal, state or local regulations. Section X - Transportation Information DOTProper Shipping Name: Combustible liquid, N.O.S. ID Number: N.A.* 1993 Hazard Classification: Combustible liquid '? 600P9131 - IdSOS No.: 2002 '.XEROX' Material Safety Data Sheet ...... Revision: Sept. 30, 1986 Manufacturer:. Ver~.tec (A Xerox Company) ' . (Xerox Corp. ' Emergency Tel. No.: (716) 422-2177- · 2805 Bowers Ave Rochester, N.Y. Information Tel. No.:. (800) 828-6571 . Santa Clara, CA 95051 14644). SeCtion I - Product Identification Trade Names/Synonyms: ECP- Magenta Concentrate Part No.: 4813-16, 4813-16-6 Chemical Name: None Inqredients CAS No. Isoparaffinic petroleum solvent (80-90%) C04742-48-9 Methacrylate co-polymer 9011-15-8 Magentadye * } (10-20%)- ' ....... Section II- Emergency and First Aid Eyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap'and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing. Ingestion: Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as well as central nervous depression. Intentional inhalation may result in abnormal · heart rhythms, respiratory arrest, central .nervous system, toxicity, Additional Information: Call physician. See Section VIII. Further information on file in Poisindex. Section III- Toxicology and Health Information This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or safety hazard. Oral LDSO: None available TLV: *None established Dermal LDs0:. >2 g/kg (Rabbits) practically non-toxic· Inhalation LCso: None available PEL: None established Eye Irritation: Not an irritant . Skin Sensitization: Not a sensitizer ~XEL: 200 ppm (Isoparaffinic Skin Irritation: Not an irritant Petroleum Solvent) Human Patch: (1/100 dilution) potentially irritating**, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A* A-, and WP2 Assays. ~arcinogens: None present AquaticLCso: None available AdditiOnal Information: *The solvent manufacturer recommends an exposure limit of 300ppm for the petroleum solvent. · * This is due to the solvent. ~xE[- Xerox Exposure Limit ~orm S873~ (~0~4) ST~ N.A. - NOt ADplicable 600P9132 ~ I Trade Name: ECP - Magenta Conc~,ote : 2002 ~ ~ ~.-~ Section IV- Physical Data Appearance/odor: Magenta liquid / slight odor- softening Range: N.A. Boiling Point: 160% 180°C Melting Point: N.A. Solubility in Water:Immiscible Specific Gravity (H20 - 1): .75 - .82 Evaporation Rate:' .25-.45 n-butylaCetate Vapor Pressure (mm Hg): @20°C 1 Vapor Density (Air · 1):5.0 pH · N.A. " Volatile: 85% (Vol.) Section V- Fire and Explosion Data Flash Point (Method Used): 102° 107' F (39-42°C) T. CC Flammable . . LEL: 0.8% · Limits UEL: 7.0% ExtinguiShing Media: Foam, dry chemical, CO2, water fog Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. AVoid breathing vapor or fumes. Fire'and Explosion Hazards: Do not mix or store With strong oxidants like liquid Chlorine or concentrated oxygen. section vi - Reactivity Data Stability: Unstable- I Hazardous May Occur,I Stable X Polymerization: Will Not OccurI X Hazardous Decomposition Products: Fumes, smoke and carbon monoxide in the case of incomplete combustion. Incomparability (Materials to Avoid): Strong oxidants such as liquid chlorine, concentrated oxygen, sodium or calcium hypochlorite. Section VII - Special Protection Information Respiratory Protection: None when used as intended with (Versatec) Xerox equipment; Eye Protection: None when used as intended with (Versatec) Xerox equipment. Protective gloves: Neoprene or nitrile gloves for prolonged or repeated skin contact. · Other: None when used as intended with (Versatec) Xerox equipment. Section VIII - Special Precautions Handling and Storage: Keep container closed. Avoid handling near heat, strong light, sparks, open flames, strong oxidants. Conditions to Avoid: Avoid breathing vapors. Avoid prolonged or repeated skin contact. Section IX - Spill, Leak, and Disposal Procedures For Spills or Leakage: Remove ignition sources. Recover free liquid using an absorbant material .. (vermiculite, fire retardant,'sawdust, etc.) .Waste Disposal Method: Dispose of liquid and absorbant at an approved disposal site. or facility. Ensure conformity with federal, state or local regulations. Section X- Transportation Information DOTProper Shipping'Name: Combustible liquid, N.O.S. ID Number: ' N.A. 1993 Hazard Classification: Combustible liquid " 600P9132 I~OS No.:' 2003 XEROX Material Safety' Data Sheet. '.. Revision: Sept. 30, 1986 Manufacturer: Versatec (A Xerox Company) (Xerox Corp. Emergency Tel. No.: (716) 422-2177 2805 Bowers Ave Rochester, N.Y. Information Tel. No.: (800) 828-6571 Santa Clara; CA 95051 14644) : Section I - Product Identification trade Names/Synonyms: ECP- Yellow Concentrate Part No.: 481'2-16, 4812-16-6 Chemical Name: None Inqredients CAS No. Isoparaffinic petroleum solvent (80-90%) 64742-48-9 Methacrylate co-polymer 9011-15-8 Yellow dye ' } (10-20%) · - Section II - Emergency and First Aid : Eyes: Flush thoroughly with Water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing. Ingestion: Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as well as central nervous depression. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest; central nervous system toxicity. Additional Information: Call physician. See Section VIII. Further information on file in Poisindex. Section III- Toxicology and Health Information This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or safety hazard. Ora! LDso: None available TLV: *None established Dermal LDso: >2 g/kg (Rabbits) practically non-toxic. Inhalation LCso: None available PEL: None established Eye Irritation: Not an irritant Skin SenSitization: Not a sensitizer sXEL: 200 ppm (Isoparaffinic Skin Irritation: Not an irritant Petroleum Solvent) Human Patch: (1/100 dilution) potentially irritating**, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A.A-, and WP2 Assays. Carcinogens: None present AquaticLCso: None available · Additional Information: *The solvent manufacturer recommends an exposure limit of 300ppm for the petroleum solvent. ** This is due rathe solvent. ~XEL- Xerox Exl)osure Limit Form 5a?]<~ (10~4) &TAR N.A. - NOt Al)placable 600P9133 "!k Trade Name:' EC.~ - Yellow Concen~ ~:.~. ~,, ~ 2003 , ~ - ~-~'~ :~ -Section IV- Physical Data Appearance/Odor: Yellow liquid / slight odor Softening Range: N.A.. Boiling Point: 160°- 180"C Melting Point: N.A.. Solubility in Water:Immiscible Specific Gravity (H20 · 1): .75 - .82 Evaporation Rate: .25-.45 n-butylacetate. Vapor Pressure (mm Hg): @20°C 1 Vapor Density (Air -1):5.0.. pH · N.A. Volatile: 85% (Vol.) SectiOn V - Fire and Explosion Data -. Flash Point (Method Used): 102° - i 07° F (39-420C) T.C.C. Flammable LEL: 0.8% Limits UEL: 7.0% Extinguishing Media: Foam, dry chemical, CO2, water fog Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Fire and Explosion Hazards: Do not mix or store with strong oxidants like liquid chlorine or concentrated oxygen. Section VI'- Reactivity Data Stable X - PolYmerization: Will Not OccurI X HazardOus Decomposition Products: Fumes, Smoke and carbon monoxide in the case of incomplete · combustion. Incompetability (Materials to Avoid): Strong oxidants such as liquid chlorine, concentrated oxygen, sodium or calcium hypochlorite. Section VII - Special Protection InformatiOn Respiratory Protection: None when used as intended with Versatec (Xerox) equipment. Eye Protection: None when used as intended with Versatec (Xerox) equipment. Protective gloves: Neoprene or nitrile gloves for prolonged or repeated skin contact. . Other: None when used as intended with Versatec (Xerox) equipment. Section VIII - Special Precautions Handling and Storage: Keep container closed. Avoid handling near heat, strong light, sparks, open flames, strong oxidents. Conditions to Avoid: '' Avoid breathing vapors. Avoid prolonged or repeated skin contact. Section IX - Spill, Leak, and Disposal Procedures · For Spills or Leakage: Remove ignition sources. Recover free liquid using an absorbant material (vermiculite, fire retardant, sawdust,-etc.) Waste Disposal Method: Dispose of liquid and absorbant at an approved disposal site or facility. Ensure conformity with federal, state or local regulations. Section X- TransportatiOn Information DOTProper Shipping Name: Combustibleliquid, N.O.S. ID Number: N.A. 1993 Hazard Classification: Combustible liqUid 600P9133 MSDS No.: 2004 XEROX Material Safety Data-Sheet o..: Aug. ,9,,98s' Revision: Sept. 30, 1986 · , Manufa~urer: Ve~t~ (A Xerox Company) (Xerox Corp. Emergency Tel. No.: (716) 422-2177 2~S Bowe~ Ave R~h~ter, N.Y. Information Tel. No.: (800) 82~6571 ; ~ara,~95051 1~) Se~ion I - Produ~ Identification. Trade Name~Synonyms: ECP- Cyan Concemrate Pa~ No.: ~1~1G, ~1~1~G Chemi~l Name: None Inqredients ~S No. Isoparaffinic petroleum solvent (80-90%) 64742-48-9 Methacrylate co-polymer } (10'20%) 9011-15-8 Cyan dye ...... Section II - Emergency and First Aid Eyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing. Ingestion: Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as well as central nervous depression. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest, central nervous system toxicity. Additional Information: Call physician. See Section VIII. Further information on file in Poisindex. SeCtion III- Toxicology and Health Information~ This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or safety hazard. Oral LDs0: None available TLV: *None established Dermal LD5o: >2 g/kg (Rabbits) practically non-toxic. Inhalation LC5o: ~ None available PEL: None established Eye Irritation: Not an' irritant Skin Sensitization: Not a sensitizer ~XEL: 200 ppm (Isoparaffinic Skin Irritation: Not an irritant Petroleum Solvent Human Patch: (1/100 dilution) potentially irritating**, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A* A-, and WP2 Assays. Carcinogens: None present AquaticLCs0: None available Additional Information: *The solvent manufacturer recommends an exposure limit of 300ppm for the petroleum solvent. ** This is due to the solvent. ~XEL- Xerox'Exposure Limit Form 58739 (10/84iSTAR ' N.A. - NOt Applicable 600P9134 '" Trade Name: ECP- an Concentra DS No.: 2004 Section IV- Physical Data Appearance/Odor: Cyan liquid / slight odor Softening Range: N.A.;'. Boiling Point: 160°~ 1800C' Melting Point: N~,. Solubility in Water:Immiscible Specific Gravity (Hz0 ml): .75 ' .82 Evaporation Rate:: .25-.45 n-butylacetate · Vapor Pressure (mm Hg):, @20°C 1 Vapor Density (Air · 1):5.0 pH · N.A. Volatile: 85% (Vol.) Section V- Fire and Explosion Data Flash Point (Method Used): 102° - 107° F (39-42°C) T.C.C. Flammable LEL: 0.8% Limits UEL: 7.0% Extinguishing Media: Foam, dry chemical, COz, water fog SpeciaI Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. · , Fire and Explosion Hazards: Do not mix Or store With strong oxidants like liquid chlorine or concentrated oxygen. SeCtion VI - Reactivity Data Stable X Polymerization: Will Not OccurI X Hazardous Decomposition Products: Fumes, smoke and carbon monoxide in the case of incomplete 'combustion. Incomparability (Materials to Avoid): Strong oxidants such as liquid chlorine, concentrated oxygen, sodium or calcium hypochlorite. Section VII - Special ProteCtion Information Respiratory Protection: None when used as intended with (Versatec) Xerox equipment. Eye Protection: None when used as intended with (Versatec) Xerox equipment. , Protective gloves: Neoprene or nitrile gloves for prolonged or repeated ski n contact. Other: None when used as intended with (Versatec) Xerox equipment. . Section VIII - Special Precautions Handling and StOrage: Keep container closed. Avoid handling near heat, strong light, sparks, open flames, strong oxidents. Conditions to Avoid: Avoid breathing vapors. Avoid prolonged or repeated skin contact. Section IX - Spill, Leak, and Disposal Procedures For Spills or Leakage: Remove ignition Sources. Recover free liquid using an absorbant material (vermiculite, fire retarant, sawdust, etc.) - Waste Disposal Method: Dispose of liquid and absorbant at an approved disposal site or facility. Ensure 'conformity with federal, state or local regulations. Section X -Transportation Information DOTProper Shipping Name: Combustibleliquid, N.O.S. ID Number: N.A. 1993 I:lazard ClassificatiOn: Combustible liquid 600P913& Heat, sparks and open flame INCOMPATASILITY (materials to avoid) Chloroform; Chromic Anhydride; Hydrogen Peroxide; Nitric Acid and Acetic Acid; Nitric Acid and Sulfuric Acid; Sulfuric Acid and Potassium Dichromate. HAZARDOUS DECOMPOSITION PRODUC'[S HAZARDOUS ~ CONDITIONS TO AVOID SPILLS Eliminate all sources of ignition. Absorb on paper. Evaporate on an iron pan in a hood. Burn the paper compound. DISPOSAL Atomize into an approved incinerator, if' local environmental regulations perm/t. RESPIRATORY PROTECTION (specify type) Have all-purpose cannister mask available VENTILAT;ON LOCAL SPECIAL ~X MECHANICAL (general) OTHER PROTECTIVE GLOVES EYE PROTECTION Rubber gloves 'Face shield OTHER PROTECTIVE EQUIPMENT Approved working clothes STORAGE & HANDLING Keep. away from heat, sparks, flkme. Keep in tightly closed container. Avoid contact with eyes. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Date~ssued:. 2/84 Revision: Approved by R. M. Mitchell Manager, Quality Assurance The information provided in this Material Safety Data Sheet has been combilecl from our experience and (]ara Dresentecl in various technical publications. It is the users responsibility to ctetermine trle suitability of this information for the acloption of safety precautions as may be necessary. We reserve the right lo rewse Material Safety Data Sheets from time to time as new technical information Oecomea available. The user nas the responsibility lo contact the company to make sure that the sheet ~s the latest one issued. * VIATE"IAL SAFETY SHEET MSOS No. -~ ~' .~, APPC 341 ~_~.. ~ ~RCOe D~E~EL ~ev. o.te. / -- - .-,.-, - 0~/22/a3 ~, ~~" ' AR~ PETRO~E~ PRO~S ~ IMPORTANT: ' h~d~g ~d DZVZS]ON OF ATLANTIC RZCHFZELD COMPANY ~d ~ th~ ~m~n on to " 5t~ SOUTH FLOWER STREET LOS ANGEL[S, CALZFORNZA 9~71 thM ~':"~:"* ' 'r'l'* '""T'l'*"r"" ' '* '" * '" "*'* ' "'" "'" '" ' * * ' ' ' ...... ....... TelG~gone NUmbers Trlde EMERGENCY Nlme ARCO DZESE~ e~/424-93~ C~EMTREC ~ N~es DZESE~ FUE~ 0Z~ N0. 2: ND. 2 D~ESE~: 0~ESE~ 0Z~ (MEDZUM)~ 312/333-3~ COMP&NY ASTM N0. 2-D GRADE DZESE~ FUE~ 0Z~ DOT HIz~dous FUE~ 0Z~. DOT Hiz~rd COMBUSTZB~E ~Z~ZD DANGER LZQUZD ZS HARMFUL OR FATAL ZP SYALLOVED OR ASPZRATEO. AVOZO BREATHZNG NZST OR VAPORS. AVOZD PROLONGED OR REPEATED SKZN CONTACT. MODERATELY CONBUSTZBLE! OSHA/NFPA CLASS ZZ OR ZZZA ~IBUSTZBLE I. ZQUZO. KEEP At, AY FROM HEAT, SPARKS, OPEN FLAME, &NO REACH QF CHZI.DREN! FOR SPECZAL PRECAUTZONS ON "SYZTCH LOADZNG", SEE SEGTZON XZ. '. FlammaOII L*m~ts I% VOl. ,n A,r) Fl~sh Point (Methodt Autoignition Temperature (Method)' I At Normal Atmospher,c ?empe,itura eno Preesu, AP 140'F (D'93) J AP 495'F (E-659) Ibower AP 0.6 Upper. AP 7.~ I I Unulull ~DERATELY COMBUSTZBLE~ ~HEN HEATED ABOVE THE FLASH POZNT. THZS MATERZAL Fire'and VZLL RELEASE FLAMMABLE VAPORS ~NZCH ZF EXPOSED TO A SOURCE OF ZGNZTZON CAN Explosi~ 8URN OR BE EXPLOSZVE ZN CONFZNED SPACES. MZSTS OR SPRAYS MAY BE F~AMMAS~E H~wdS AT TEMPERATURES BELOV THE NORMAL FLASH POZNT. FOR 'SVZTCH LOADZNG' PROCEDURES. SEE SECTZON Extin~ishing FOAM ~02' Mtdil ~OAM, DRY CHEMZCAL, HALON, CO2, AND VA~ER FOG. FOR FZRES ZNVOLVZNG THZS MATERZAL. DO NOT ENTER ANY ENCLOSED OR CONFZNED F~RE SPACE WZTHOUT PROPER PROTECTZVE EQUZPMENT. THZS MAY ZNCLUDE. SEI.~- SpINel CONTAZNED BREATHZNG APPARATUS TO PROTECT AGAZNST THE HAZARDOUS EFFECTS OF Flreft~httng C0HBUSTZDN PRODUCTS AND OXYGEN DEFZCZENCES. COOL TANKS AND C0NTAINERS Procedures EXPOSED TO FZRE WZTH WATER. SEQ: 183 :::~'Og 'DISCLAIMER OF LIABILITY.' SEE THE STATEMENT ON PAGE 4m P~ge 1 of Primary INGEST~ON OF L]QUT~;) LEADING TO ASP[RAT~0N iNTO THE LUNGS AND POSSIBLE Hazard CHEMZCAL PNEUNDNi A. ROUTE OF EXPOSURE.. SIGNS AND SYMPTOMS PROLONGED EXPOSURE T0 V~PORS 0F TH~S M&TER;~C M~Y CAUSE SYMPTOMS OF Inhalation NERVOUS SYSTEM DEP;ESS~0N. (SEE "EFFECTS 0F OVEREXPOSURE' BOX BELOW. ) Eye EYE ;RR~T~T~ON M~Y RESULT FROM CONTACT WiTH LZOU[D AND/OR V~PORS. Contaot Skin NO S~GN~F~C&NT SYSTEMZC EFFECTS ~qE EXPECTEO UNDER CONO;T;0NS OF· Absorption NORMAL USE. Ski~ SKiN ~RR;T&T;ON LEAD,NO TO DERM&T;T~5 MAY RESULT FROM PROLONGED OR ~rritlttOn SKiN CONTACT .., ~NGEST~ON: N~USE&. VOM;T[NG. D~AR~HE&. RESTLESSNESS. Ingestio~ ~SP;R~T~ON: CHEM~C~ PNEU~NZ&. ;~&~&T~ON .... M~CD DEPRESS;ON. ~E~O&CHE. N~USE&. CO~S;ONS. OR ~OSS OF CONSCIOUSNESS. Elfe~s Of SK;N CONTACT--DERMATiTiS. ~iftxpO~l ~SP;R&T~ON .... CHEM;C~L PNEU~N;A. TH[S MATER;Ak ZS NOT EXPECTED TO PRESENT &RESPZR&TORY HAZARD BECAUSE OF ~.~ Respiratory ZTS LOW VAPOR PRESSURE. wHERE EXCESSIVE VAPORS O~ MiST RESULT F~OM CONDZ- TZONS OF USEAGE, NIDSH/MSHA APPROVED RESPIRATORY 'EQUIPMENT MUST gE WORN. USE ADEQUATE VENTILATION TO KEEP VAPOR C0~CENTRAT]ONS OF TH[S Ventilation BELO~ APPLICABLE STANDARD(S). (SEE SECTZON VZ.-OCCUPATZONAL EXPOSURE LiMiTS.) .. EYE PROTECTION (CHEMiCAL-TYPE GOGGLES. ANO/OR FACE SHIE~D) SHOULD BE WORN ' Eye WHENEVER THE POSSIB~LITY EXISTS FOR EYE CONTACT DUE TO SPLASHING OR SPRAYING LIOU~D. CONTACT LENS SHOULD NOT BE ~ORN. AVOID PROLONGED OR REPEATEO SKiN CONTACT. iF CONDiTiONS OR FREOUENCY OF Skin USE PRESENT OANGER OF EXPOSURE. CLEAN AND iMPERViOUS PROTECTIVE CLOTHING ~1 SUCH AS G~OVES, APRON, BOOTS, AND FACIAL PROTECTION SHOULD BE WORN. USE GOOD PERSONAL HY~IENE PRACTICES. ~ASH HANDS BEFORE EATING, DRiNKiNG, Other SMOKING, OR USE'OF TO[LET FA¢~IT~ES. PROMPTLY'REMOVE SOILED CLOTHING AND ~ASH THOROUGHLY BEFORE REUSE. DISCARD FUEl-SOAKED ~EATHER SHOES AND GLOVES. Substanoe . Sourer Date KEROSENE (DHEW PUBLICAT~ON 77-192) NIOSH. 1977 Exposure Limit Value/Time IShort Term Limit/Time Limit 100 MO/M3 ./ ~0 HOURS I ~BO0 MG/M3 / 15 M~NUTES NOT :ance Souroo Date SEE SECTION x~. - GENERAL COMMENTs ~xPosure Limit Value/Time Sho~ Term Limit/Time Peak Limit P~ge 2 of 4 _ -~,. ~ " MSD$ No. Y APPC 34t ~~ ARC0eD[£$EL Rev. O.t. 07/22/B3. :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: '"'""::'"'":::r:::':::':::::::':i:i:::'::::".'":""' ':' '""':':'"'""'""" '"''~"'' '""'"'" -, · XMMEDZATELY REMOVE FROM CONTAMINATED AREA TO FRESH AIR. FOR RESPXRATORY Ilnhmlstion DZSTRESS. GZVE OXYGEN OR AD#]NXSTER CPR (CARD~OPULMONARY RESUSCXTATZON). XF I* I I NECESSARY. MUST OBTAXN PROMPT MEDXCAL ATTENTZON. ' ' FLUSH VXTH CLEAN LOW-PRESSURE WATER FOR AT LEAST IS MXNUTES: XF XRRXTATXON Eye PERSXSTS. OBTAZN MEOXCAL ATTENTZON. Contld. THOROUGHLY WASH AFFECTED AREA WXTH SOAP AND WATER. REMOVE CONTAMXNATEO Skin CLOTHXNG AND THOROUGHLY CLEAN BEFORE REUSE. BUT DXSCARO CONTAMXNATED Contld. LEATHER GOODS. DO' NOT ZNOUCE VDM]TZNG, SZNCE ASP]RATZON ZNTO THE LUNGS WZLL CAUSE CHEMZCAL Ingestion PNEUMONZA. MUST OBTAZN MEDZCAL ATTENTZON PROMPTLY. Note to *' Phys~iaa . · :::... :::S: """ CONTAXN SPZLL. REMOVE ALLXGNXTXDN SOURCES AND SAFELY STOP' FLO¥ OF SPXLL. SPZLL'MAY CREATE SLXPPXNG HAZMIDS. EVACUATE ALL NDN-ESSENTXAL PERSONNEL. XN URBAN ARE&, CLEANUP kS SOON AS POSSXBLE; XN NATURAL ENVXRONMENTS. CLEAN- PreeNti°nl UP ON AOVXCE FROM ECOLOGXSTS.. E~JZP CLEANUP CREWS WXTH PROPER PROTECTXVE .iifMetMiel EQUZPMENT. THXS M&TERZAL WZLL FLOAT ON WATER. ABSORBANT M&TERXAL AND PADS -~,. is' Spilled CAN BE USED. NDTxFY THE NATXONAL RESPONSE CENTER (800/424-8802) AND COMPLY Or ReigNed 'WXTH ALL APPLXCABLE LAWS. THE SPXLLED MATERX&L AND ANY WATER OR SOXL i ZT HAS CONTACTED MAY BE HAZARDOUS TO ANXMAL/AQUATXC LXFE. MAXXMZZE PRODUCT RECOVERY FOR REUSE PRXOR TO DXSPOSAL'. USED PRODUCT COULD BE AN EPA "XGNXTABLE HAZARDOUS WASTE"(O001). USE APPqOVE~ TREATMENT, TRANSPORTERS. AND OZSPOSAL SZTES XN COMPLXANCE WXTH ALL APPLZCABLE LAWS. Wsste XF SPXLL XS XNTRODUCED XNTO A WASTEWATER SYSTEM. THE CHEMXCAL AND BXOLOGZCAL OXYGEN DEMAND WXLL LXKELY XNCREASE. PROPERLY ACCLXMATE THE Disposal ' Methods BXOMASS TO THE MATERXAL. POTENTXAL O~SPOSAL METHODS XNCLUDE XNCXNERATXON. LAND FARMXNG. AND LAND DXSPOSAL, XF PERMZTTED. Component Nam~ CAS No. Composition smount - ISee Note on Page 4) POUR POZNT DEPRESSANT ' LT 0.1 PERCENT ZGNZTZON ZMPROVER LT 0.3 PERCENT· MZXTURE OF ADOZTZVES (METAL DEACTIVATOR. LT 0.01 PERCENT ANTZOXZDANTS, ETC.) KEROSXNE (PETROLEUM) 800B-20-6" AP 0 TO 10 PERCENT STRAXGHT-RUN 'MXDDLE OXSTXLLATE 64741-44-2' AP 0 TO . I~ PERCENT (PETROLEUM) SWEETENED MZDDLE DZSTZLL~TE (PETROLEUM) G474t'86'2" AP 0 TO 75 PERCENT CLAY-TREATED DZSTZLLATE (PETROLEUM)· 64742-3B,?' AP 0 TO GO PERCENT HYDRODESULFURZZED GAS OZL.(PETROLEUM) 64?42-79-6' AP 0 TO 15 PERCENT HYDROOESULFURZZED MZDOLE DZSTZLLATE 64742-80-9' AP 0 TO 100 PERCENT (PETROLEUm) MEDZUM &LZPHATZC SOLVENT NAPHTHA 64742-8g-?' AP 0 TO S PERCENT (PETROLEUM) " Compositions given ~e typical velues, not specificetion~ 183 Page3 of ARCO DIESEL MSDS NO. APPC 341 ~ Boiling Point EvN)or&tion Rate (Ratio of Time) Dry Point 325' TO 6BO'F SLO~ER THAN ETHYL ETHER N/AV Free:.;ng Point . ~apor Presswe Volatile Charscter~cs 4~ -5'F · (~EZO.pszA AT I~'F) LT 0.1 $LZGHT~~- Spe=ifi¢ Gravi~ (H~O = 1 M 3~'~ Vapor Sp. Gr. ~ir = 1.0 at 60'-SO'RI Solubili~ in Water Stlbili~ &P 0.85 AP ? I NEGLIGIBLE · STABLE H~zardou, Polymerization Viscosity Unltl, Temp., Method pH NOT EXPECTED TO OCCUr. AP 3 CST AT I~'F 0-445 N/AP O~er P~sical SULFUR CONTENT · CT 0.5 ~T..% and Chemical Prope~ie~ Appearance L~GHT YELLO~ TO AMBER COLORED L~QU~O; and O~r KEROSENE HEAT AND ~GN'~TZON Cendltionl .. te Avoid STaONG AC~OS, ALKALZES, AND OXIDiZErS SUCH AS I MltleiMI LZOUZO CHLOR]NE A~ OXYGEN. to Avoid Hizwdo~ BURNZ~ OR EXCESSZVE HEATZ~ MAY PRODUCE CARBON Dt=ompolition ~NOXZQE AND OTHER HARMFU~ GASES/VAPORS Z~UOZ~ ~oduots 0XZDES A~/Ok OTHER COMPOU~S OF SULFUR.. SPECIAL Sk0~ L01D PROCEDURES F0q "S~ITCH L0&O]NG" ~ST at ;0LLOVED T0 IV0ID THE STATIC ]GN~TZON HAZARD THAT CAN EXIST ~HEN THZS MATERZAL ]S LOADED :NTO Handling TANKS PREVIOUSLY CONTAiNiNG GASOLINE OR. OTHER ~0~ FLASH POZNT HYDROCARBON and PRODUCTS. (SEE A.P.[. PURL;CAT;ON 2~3.) KEEP CoNTAZNER$ CLOSEO ANO Storage F~OU HEAT J~ iGNiTiON SOURCES; ALL ELECTriCAL EQUIPMENT iN AREAS ~HERE ' PRODUCT ~$ STORED/HANDLED SHOULD BE iNSTALLED ZN ACCORDANCE ~[TH REQUIREMENTS OF THE NATIONAL ELECT~ZC CODE, N.F.P.A. O0 NOT USE THiS FUEL AS A CLEANING AGENT. EMPTY CONTAINERS RETAIN SOME LIQUID AND VAPOR ~ES;OUE$. AND HAZARD PRECAUTZONS MUST BE OBSERVED WHEN HANDLING EMPTIES. ~A~N~NG: USE OF ANY HYOaOCARBON FUEL ;N SPACES ~ZTHOUT ADEOUATE VENT~LAT:ON MAY ~ESULT ;N GENERAT;ON OF HAZARDOUS LEVELS OF COMBUST:ON PRODUCTS AND .iNADEQUATE OXYGEN LEVELS'FO~ B~EATHiNG. 5~NCE $PEC[FZC EXPOSURE STANDARDS/ General Comments 5~NC; $PECZFZC EXPOSUaE STANDARDS/CONTROL LiMiTS HAVE NOT BEEN FOR THIS MATER[AL. THE EXPOSURE LZHZTS iN SECTION Vi. ARE SUGGESTED AS MZNZMUM CONTROL GUZDELZNE$ FOR [NTERZM USE. MATERZALS SZH[LAR ~0 SOME COMPONENTS [N THZS PRODUCT ~ERE FOUNO TO BE MUTAGENZC [N 'ZN VZTRO' AND "[N V[VO" TESTS. THE EXACT RELATZONSHZP BETWEEN THESE RESULTS AND POSSZBLE HUMAN EFFECTS ZS NOT KNOWN. SOME OF THE [NFORMATZON PRESENTEO A~ CONCLUSZ0N$ ORA~N HEREZN ARE FRO~ SOURCES OTHER THAN DZRECT TEST 0ATA ON THE MZXTURE. ITSELF. EQ a Eq~ AP ~ Aggroxi~tely NIAV - Not Avail~ll - - - Note - - - Q~ifications: LT = Less ~ UK - ~o~ N/AP - Not A~lic~le GT = Greater Thru TR ~ TrKI N/DA - ~ D~ Avad~le Disclaimer of Liabili~ The mf=rmiti=n in th~l MSDS wll =btline~ from Iourcel w~ch we ~elieve $~e reliable. HOOVER, THE INFORM&~ON I~ FROVlDED WITHOUT &NY R~IS[NT&~ON OW W&RR~N~, [~[S$ O~ I~I[D, RI~iADIN~ ITS &CCUR&CY O~ The cofld~tiOfll ~ mlthodl of h~dling, StOflgl, ual Ifld d~lpolll of the ~oauct ~l 0lyond O~ con~roI ina may be beyond ow FOR THIS AND OTHER REASONS, ~ DO NOT ASSUM! RESPONSIBIUTY ANO E~RIS~Y DIS~AIM LIAIIU~ FOR LOBS, OAMAM OR EXPENSE ARISING O; OF OR IN ANY WAY CONNEC~D MTH THE NANDLINO, STORAOl, USE OR DISPOS~ OF ~! PROOUCT, P~ 4 of 4 Rev ~ 01 Issue N= 27 Print Ditto 09/14/83 MATERIAL SAFETY DATA SHEET "°' mm~ CORPORATE RESEARCH & DEVELOPMENT &NidYDROUS SCHENECTADY, N.Y. 12305 . . Phone: (5~8) ]8S-~08S~ D~L CO~ ~]S-~08S DG~e November ~979 DESCRiPTiON: L~~~epend~n8 on ~e~erac~re ~nd presaure cond~c~ona. Sup- p~ed pressurized ~n cylinders or tanks. ~R DESZ~T~ONS: ~3, ,~n~a Gas, GE ~acer~a~ D27A~, ~S ~007 666 ~7 ~FAC~: Available ~rom ~ny suppliers. SECTION II. INGREDIENTS AND HAZARDS x ~Z~O OAT~ Anhydrous ~nLa >99.5 8-h~ ~A 50 o~ 3~ mS/mi *Current OS~ ~V; N[OS~ has p~oposed a' 50 ppm CeL[Ln8 ~ 20 p~m, L~ttat LLmtc (&mtnuce s~Ltn~ ct~). ~e cu~enc ACG[H ~V Ls 25 ppm. ~C, inhalation LC~ 2000 ppn/~ hr ~ECTiON I[[, PHYSICAL DATA ~ng point, ~ ~cm, den ~ (C) ..... 28 (-33.-) Specific gravity 60/60 F -- 0.62 Vapor pressure ~c 60 F, ~ E~ ~800 VoCatiVes, Z ca ~00 Vapor density (A~r~Z) 0.6 ~H o~ ~ ~aze~ so~uzXon -~ ~.7 AC 0 C 89.9 (=77.7 AC ~00 C 7.~ ~o~ecu~r ~e~ghc ~7.03 Appearance & Odor: ~qu~ ~c ~o~ cemperncure, ~oder~e pressure. CoZor~esa gan moderate ~emper=~ure, ~ow pressure. S~rong, pungent odor, de~e~K~b~e ~c 5 ppm, ~rr~c~c~n~ ~c 25=~0 ~m; odor ~rov~des ~ w~rn~n~ of ~zsr~. Ftash Po[nc and Hechod i Auco~&nLCLo~_Temp. ~ FLa~bLLLcy LLm~cs [n ~aseous ac room cond~ L20& ~(~on pr~sen~* ~m VO[. : · 16 2S ~[~t-~~n~a.~.~:..(~g~;~y~. fog)' ~s be~c~j ~cop r/ow gas. Use vacer co keep ~[re-exposed conca~ne~%..coo'[~' a~.~ect ~en affec~n~ sbu= Diff.. [c Ls a Etre. and e~LOston~ h'az~?'~h~.~e~; co hea.~For ff[a~.'~ :f ~ is [eaktn~ or are.heavt[y e~osed co ~, evacuate the area ~nd =he area downwind. Eeac e~osed cenks should vent ac 250 ps~. ViD[eno rupcur~ can occur L~ reined, valves fat[. F~re~hcers need se[~-conca~ned breachtn~ apparatus wtch ~u[[-facep~ece and Eu[[ pro- cecc~ve c[och~nK, S~CTION V, ~EACTIVITY DATA Contained anhydrous ~3 ac room cemperature is stable. If heated above ~50 C, deco~Os- Icion co H2 and N0 begins. [~ is an alkaline ~as which reaccs vich acids wlch much heat evolution; i~ reacts ~th CO~ from the air.' Co~cacc of ~3 wiCh chemicals such as mercury, chlorine, Lodine, bromine, silver oxide, or hypochlorites can fo~ explosive compounds. Do not use copper, brass, bronze or ~aivanized steel Ln concact wich a~nia. Welded joincs are preferred to chreaded ]oiats in a~onia service. Do not use brazed m G N E .: . . ; No. ' SECTION Vl, :~~ZAR~NFOR~&T['O~ J TLV 25-50 ppm (See Sect. $ aaage can occur ~rou repeated, prolonged, or high concentration contact. Above 700 ppa tn air causes severe eye injur? and possible Loss o~ vision t~ not trea~ed mediately.- Burnin$ and bl~scering of the skin, as well as serious lun$ edema, occur quickly above 1700 ppm in air. Con:acc~h~]~quid ammonia will produce Erostbtte ie a~kt~o~o~e~orrosive damase. ~.~~~_Flush wtch lots of runnin$-water £mmediacel~ and continue at least 15 mi , '~~~under. the eyelids. Then contact ~hysician tnanediately, pre[erably an opththalmolo$ist. Speed and thoroughness in rinsin~ eyes £s importan~ to avoid per- .manan~inju~y. $~!a~ConSact~ Immediately flush with water and remove contaminated clothin8. Thae : froz~'fi' clothin$ before removal. Get ·medical help if irritation persists or larie Iahala~ion:~{ Remove promptly co [rash air. Restore and/or support breatin$ i~ requ~re[; ' ~eep-waz~:'and ac rest. Call ?hys£cian.. Have tra£ne~ per~@n ~dainSs~er o.xYsen. · [ Kescuer reculres, ,°r°~er, respirators ~ eqUl. ~me~ co prevent tls oecomzn~ a victim ale~ SECTION VII, .¢ .......... ROCED.URE~ . ~stabl£sh written plans [or emersency. Evacuate area o[ leak (and possibly dovn~rind als&) Exclude all except properly equipped (see Sect. sl~[ V~[I) and craine~ personnel v ich e~r- fancy assiqnmencs. Eliminate isn~cion sources aha provide vent2£ation. Use a cold va: r spray to absorb .~t3. An open boccie of Cont. HCL can be used to detect sources o[ leaks. ~hen possible, leakage should be adjusted co discharse Sa~, not liquid Nil3. not try to neutralize liquid .~t3 spills with acid! Caseous h~t3 ~ay be discharsed inco-T co--'~d water [or collection; do nocdirectly discharse this solution to amnicip&[ con[ined drains, or sur[ace waters. DISPOSAL:. Solutions o[ Nlt3 in pure water ~ay be 6sad or sold. For discharse, roi!or Federal, Scare and local resulacions. Li~Lted ~mount~ o~ NIt3 ~a! may be released to ch~ ac~opgher~.under ~ppropriat~ condi~iona) ~imice~ amounts o£ a~aonia solution can ~e h[2n~y d~uted ~r~th ~acer [neutralized.) discharse. The rece£vin$ stream must not exceea estaD~[shed limits Eot N'H~ or s~l~s,m SECTION V iI..SPiC[AL p.OT ¢ ION INFORmATiON Provide general ventilation and exhaust ventilation co meet TLV requirements. (la build inSs use explosion-proo[ electrical services £or NI~i.) For emergency and nonroutine . conditions a chemical cartridge resp£racor with full-~acepiece can be used [or periods belo~ ]00 ppm~ above ]00 ppm or for unknown exposures, approved, [ull-facep~ec~ sell-contained hreachtn~ ~tpparacus should be available. ~o prevent skin ~nEacc use rubber suit. boots, ~loves, apron, etc. as appropriate [or workplace ,:ondic~ons. Use safety gogglers and faceshield ~o prelect eyes [rom sas and direct splashin~ of solutions. &n eyewash station and saietv shower must be immediately accessible .o workers where .am{tonic is used or handled~ ~ash£n$ [acilities and /~rge amounts oi 'Lean watcr be.available Lot emergency use. (See also AN$I/CCA C2.i-197~, [ormerly ANSI on storage and handl~n~ of anhydrous a~on£a.) SECT ION IX, _$PE.~:I:~izPRff~u~..E TS ~Core cylinders or ranks in a Cool, well-ventilated, fire-resistant location, away ~rom oxidizin$ agents, combustible materials, and sources oi heac or ignition. Special external storage, out o~ direct sunlight, is pre~erred. $ee also C~R 29,Chapter XWlI, Parc 1910.111 £or regulations on containment and handling of anhydrous a~aonla. Folio, good practices for compressed gas in cylinders. ~onitor workplace to be sure of ammonia ekgosures of workers. 4ork practices and equipment must be designed to prevent any contact of liquid or a~nonia'solutions with a worker's body. .)replacement and periodic' medical examination is recommended for ammonia workers, and aminacions, should be provided when excessive cposure conditions occur. ~eep records. Provide training co workers ,)n safe handling. MIS, ~ ?NrA SOURCE(S) CODE: ,-8,1~,17,,9,.,0,, ' i'/ ~'~~ ..... 4, ~6,31 APPROVALS: ~RD · o. ~ ,~. ~,.~, .... .~.. ~ ,.. ,., .... ~. ,. o~o .... ~,~.o,, MEDICAL REV IEW: 12/79 GENERAL q~) ELECTRIC MATERIAL SAFETY DATA SHEET J.T. Baker Chemical Co., 222 Red School Lane, Phillipsburg, N.J. 08865 CHEMICAL NAME -FORMULA Acetone (CH3)2C0 SYNONYM OR CROSS REFERENCE CAS NO: 67-64-1 Dimethyl Ketone' MATERIAL BOILING POINT MELTING POINT 56.5°C. -94.6Oc. VAPOR PRESSURE SPECIFIC GRAVITY @ 20°C. 180mm 0.79 VAPOR DENSITY (AIR=l) PERCENT VOLATILE BY VOLUME (%) 2.0 WATER SOLUBILITY EVAPORATION RATE Soluble ( = 1) APPEARANCE Colorless liquid; fragrant mintlike odor 17°c. 0°F. (closed cup) 12.8% FIRE EXTINGUISHING MEDIA Water spray, alcohol foam, dry chemical or carbon dioxide. SPECIAL FIRE-FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARD Acetone is highly flammable and its vapors form explosive mixtures with air. THRESHOLD LIMIT VALUE ipr-mus LD50:1297 mg/kg orl-rbt LD50:5300 mg/kg 1,000ppm; 2,400mg/M3 HEALTH HAZARDS Harmful if inhaled. May cause irritation FIRST AIO PROCEDURES If inhaled, remove tO fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. If swallowed, if conscious, induce vomiting and call a physician. In case of contact, immediately flush eves or skin with plenty of water for STABLE X Heat, sparks, open flame INCOMPATABILITY (materials to avoid) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS MAY OCCUR CONDITIONS TO AVOID POLYMERIZATION WILL NOT OC¢ SPILLS Eliminate all sources of'ignition. Absorb on sand, earth or vermiculite. Care- fully sweep up and remove. Flush spill area with water. Alternatively use J. T. Baker's Flammable Spill Clean-Up Kit (Product No. 4437). DISPOSAL Atomize into an approved incinerator if local environmental regulations permit. RESPIRATORY PROTECTION (specify type) Have ail-purpose canister mask available. .VENTILATION LOCAL SPECIAL '" MECHANICAL (general) OTHER PROTECTIVE GLOVES EYE PROTECTION Rubber gloves Face shield OTHER PROTECTIVE EOUIPMENT Approved working clothes ~TORAGE & HANDLING Keep away from heat, sparks, flame. Keep in tightly closed container. Wash -thoroughly after handling. Avoid contact with eyes. Avoid prolonged or repeated breathing vapor. Avoid prolonged or repeated contact with skin. Do not take internally. Oatelssued: 5/84 Revision:. AI3provedby R.M. Mftch'ell Manager, Quality Assurance The information I~rovided in this Material Safety Data Sheet has been comotled from our exoerience anti data 13resentecl in various technical publications. It is the users resl;)oneJbtlity ,o determine the suitability of this information for the ado0tion of safety 13recautions as may De necessa~. We reserve tl3e right to revise Material Sa/ety Data Sheets from time to time as new tecllnical information Oecomes available. The user has t~e resOonsibility ,o contact the coml3~ny to make sure that the street is the latest one issue~. MA RIAL SAFETY DATA EET J. T. Baker Chemical Co., 222 Red SChool Lane, Phillipsburg, N.J. 08865 CHEMICAL NAME FORMULA 2-Propanol CH3CHOHCH3 SYNONYM OR CROSS REFERENCE CAS NO: 67-63-0 Isopropanol Tsopropyl Alcohol Dimethylcarbinol MATERIAL NATURE OF HAZARD BOLLING POINT MELTING POINT 181°C. VAPOR PRESSURE SPECIFIC GRAVITY @ 20°C. 33 mm 0.79 VAPOR DENSITY (AiR=l) PERCENT (%) VOLATILE BY VOLUME WATER SOLUBILITY EVAPORATION RATE Soluble ( = 1) APPEARANCE Colorless, transparent liquid FLASH POINT (method used) FLAMMABLE LIMITS Lower Upper 53°F. (closed cup) 21°C. (open cup) 2.5% 12.0% FIRE EXTINGUISHING MEDIA Water spray, alcohol foam, dry chemical, carbon dioxide SPECIAL FIRE-FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARD Flammable liquid THRESHOLD LIMIT VALUE 400 ppm orl-dog LDo0:6000 m~/k~ HEALTH HAZARDS Harmful if inhaled. FIRS/AID PROCEDURES If inhaled, remove to fresh air. If not breaching, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. If swallowed, if conscious, induce vomiting. Repeat until vomit fluid is clear. Call a physician. STABILITY UNSTABLE CONDITIONS TO AVOID STABLE X Heat, sparks, and flame INCOMPATABILITY (materials to avoid) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS MAY OCCUR CONDITIONS TO AVOID POLYMERIZATION WILL NOT OCCUR X SPILLS Eliminate all sources, of ignition and flammables. Absorb spill on sand, earth or vermiculite. Carefully sweep up and remove. Allow to evaporate. Flush spill area with water. Alternatively use J. T. Baker Flammable Liquid Spill Kit. DISPOSAL Atomize into an incinerator providing environmental regulations permit. Combustion may be improved by mixing with a more flammable solvent. RESPIRATORY PROTECTION (specify type) All-purpos~e canister mask available. VENTILATION LOCAL SPECIAL Preferable MECHANICAL (general), OTHER PROTECTIVE GLOVES I EYE PROTECTION Rubber gloves I Safety glasses; face shield OTHER PROTECTIVE EQUIPMENT Approved working clothes; eyebath STORAGE & HANDLING Protect containers against physical damage. Keep away from heat, sparks, and flame. Keep in tightly closed container. Wash thoroughly after handling. -- ' - - ' t ' v Ilr. ' I I ~ I' ~ . · ' ........ Avoid contact with eyes, skin, or clothing. Avoid breathing vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with Skin. Date issued:. 3/84 Revision: Approved by R. M. Mitchell (',. Manager, Quality Assurance The ~nformatlon provided in this Material Safety Data Sheet has been compiled from our experience and (3ata presente~3 in various technical puPlicatlons. It IS the users responsibility to determine the suitability of this information Ior the adoption of safety Precautions as may be necessary. We reserve the right to revise Material Safety Data Sheets from lime to time as new tecllnical Information becomes availaOle. The user nas the responslbilily to contact the company to make sure that the sheet ~s the latest one issued. MATERIAL SAFETY DATA SHEET J. T. Baker Chemical Co., 222 Red School Lane. Phillipsburg, N.J. 08865 CHEMICAL NAME FORMULA Toluene C6HbCH3 SYNONYM OR CROSS REFERENCE CAS NO: Toluol Methacide I08-88-3 Me thy lb enz ene Phenylmethane MATERIAL NATURE OF HAZARD BOILING POINT MELTING POINT lll°C. -95°C. VAPOR PRESSURE SPECIFIC GRAVITY 36.7 mmHg at 30°C. 0.87 VAPOR DENSITY (AIR=l) PERCENT VOLATILE BY VOLUME (%) 3.14 WATER SOLUBILITY EVAPORATION RATE Insoluble ( = 1) APPEARANCE Colorless, refractive liquid with benzene-like' odor. FLASH POINT (method used) FLAMMABLE LIMITS Lower Upper 40OF. (G[o~¢d cup) FIRE EXTINGUISHING MEDIA Water spray, carbon dioxide, dry chemical, foam. SPECIAL FIRE-FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARD Flammable liquid THRESHOLD LIMIT VALUE 200 ppm ipr-rat LD$0:1640 mg/kg orl-rat LDo0:7.53 ml/kg HEALTH HAZAROS Harmful if inhaled or swallowed. Causes eye irritation. FIRST AIO PROCEDURES If inhaled, remove to fresh air. Administer artificial respiration or as Call a physician. If swallowed, do not induce oxygen necessary. vomiting; if conscious, cautiously give warm water, then mineral oil followed by hot coffee or tea. CAll a physician. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. Flush skin with water. STABILITY UNSTABLE CONDITIONS TO AVOID STABLE X INCOMPATABILITY (materials to avoid) HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS I MAY OCCUR CONDITIONS TO AVOID POLYMERIZATION I WILL NOT OCCUR SPILLS Absorb spill on vermiculite or paper. Allow to evaporate in hood. Burn paper or vermiculite. Wash s~ill site with soap solution. Alternatively use 3. T. Baker's Solusorb~. DISPOSAL Contact a professional disposal service. RESPIRATORY PROTECTION (specify type) Self.-concained breaching apparatus. VENTILATION LOCAL SPECIAL ?referable MECHANICAL (general) OTHER PROTECTIVE GLOVES I EYE PROTECTION Rubber gloves I Safety glasses OTHER PROTECTIVE EOUIPMENT Approved working clothes; face shield; eyebath; safety shower. STORAGE & HANDLING Keep in tightly closed container. Wash thoroughly after handling. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor of contact with skin. - R. M. Mitchell Date issued: Approved by Manager, Quality Assurance Revision No. & Date issued: The Tnformatlon provTded in this Material Safety Data Sheet has Peen compiled from our experience and Data presented in various technical DuPhcatTons. It is the users resDonsiDihly tO ($etermlne the suitability of this information for the aOoption ol safety precautions as may ~ necessary. We reserve the right tO rewse Material Salety Data Sheets from time to time as new technical information Pecomes availaOle. The user has The resl3onslblliTv TO contact the company Io make sure that the sheet is the latest one issued. ~CHF-.~IC-.ALSI J.T. Baker Chemical Co., 222 Red School Lane, Phillipsburg, N.J. 08865 m~. CHEMICAL NAME FORMULA r'- Z 1,1,1-Trichloroechane CH3CCl3 m SYNONYM OR CROSS REFERENCE CAS NO: 71-55-6 Mechylchloroform Chloro chene MATERIAL NATURE OF HAZARD BOILING POINT MELTING POINT 74°C -38°C VAPOR PRESSURE SPECIFIC GRAVITY @ 30°C 144 mmHg 1.3376 20°/4°C VAPOR DENSITY (AIR=l) PERCENT VOLATILE BY VOLUME (o/~) 4.55 WATER SOLUBILITY EVAPORATION RATE Insoluble ( = 1) APPEARANCE Clear, water-white liquid. FLASH POINT (method used) FLAMMABLE LIMITS Lower Upper FIRE EXTINGUISHING MEDIA SPECIAL FIRE-FIGHTING PROCEDURES Non- f lammab 1 e UNUSUAL FIRE AND EXPLOSION HAZARO THRESHOLD LIMIT VALUE Maintain below 350 ppm HEALTH HAZARDS Irritating to eyes, mucous membranes, and in high concentrations nnrcotic. ~IRSTAIDpROChDURES If inhaled, remove to fresh air. Administer oxygen or artificial respiration as necessary. Call a physician. In case of contact, PRODUCT: Helium L-4602-B September 1985 RESPIRATORY PROTECTION (specify type): Select in accordance with OSHA 29 CFR 1910.134. Respirators shall be acceptable to MSHA and NIOSH. LOCAL EXHAUST -- Preferred MECHANICAL (general) m Acceptable VENTILATION SPECIAL -- Not applicable OTHER t Not applicable PROTECTIVE GLOVES: Preferred for cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133 OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29CFR 1910.132 and 1910.133. CAUTION: High pressure gas. Use piping and equipment adequately designed to withstand pressures to be encountered. Can cause (~' rapid suffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. Do not strike arc on cylinder. Do not ground cylinder. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an . Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all labels and other instructions supplied with all containers of this product. o When used in welding and cutting: Read and understand the manufacturer's instructions and the precautionary label on the product. See American Standard Z49.1, "Safety in Welding and Cutting" published by the American Welding Society, P.O. Box 351040, Miami, Florida 33135 and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail. For further SAFETY AND HEALTH information, refer to Linde's free publication 52-529. NOTE: Suitability for use as a component in underwater breathing gas mixtures is to be determined by or Under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the effects, methods, frequency and duration of use, hazards, s/de effects, and precautions to be taken. For safety information on general handling of compressed gas cylinders, obtain a copy of pamphlet P-1, "Safe Handling of Compressed Gases in Containers'~ from the Compressed Gas A~oci- at/on,/nc., 1235 Jefferson Davis Highway, Ar//ngton, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. ....~..-.. IN THE USA: IN CANADA: o UNION CARBIDE Union Carbide Corporation Union Carbide Canada Limited / Linde Division Linde Division ~.. 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P 1J3 Other offices in principal cities all over the world. ~ Acn,~_~ a~_n(~o~ (~/;~ 1nM Litho~raphed in U.S.A. PRODUCT: Helium L-4602-B September 1985 ~'~ FLASH POINT · AUTOIGNITION Not applicable (test method) Not applicable TEMPERATURE FLAMMABLE LIMITS LOWER Not applicable UPPER Not applicable IN AIR, '% by volume · ' EXTINGUISHING MEDIA: Helium cannot catch fire. Use media appropriate for surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately deluge containers with water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Helium (high pressure gas) cannot catch fire. Container may rupture due to heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125 °F). Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. STABILITY CONDITIONS TO AVOID: (See Section IX). I UNSTABLE STABLE X INCOMPATIBILITY (materials to avoid): None currently known. Helium is chemically inert. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: None currently known. May Occur Will not Occur X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Evacuate all personnel from danger area. Use Self-contained breathing apparatus where needed. Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area. Test area, especially confined areas, for sufficient oxygen content prior to permitting re-entry of personnel. WASTE DISPOSAL METHOD: Slowly release into atmosphere outdoors. Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with federal, state and local regulations. L-4602-B PRODUCT: Helium September 1985 THRESHOLD LIMIT VALUE: Simple asphyxiant--ACGIH (1984-85). EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING -- Unlikely route of exposure. This product is a gas at normal temperature and pressure. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- Asphyxiant. Moderate concentrations may cause headache, drowsiness, dizziness, excitation, excess salivation, vomiting and unconsciousness. SKIN CONTACT -- No evidence of adverse effects from available information. EYE CONTACT -- No evidence of adverse effects from available information. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: None currently known. This product is an asphyxiant. Lack of oxygen can cause death. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: A knowledge of the available toxicology information and of the physical and chemical properties of the material suggest that overexposure is unlikely to aggravate existing medical conditions. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY AND FIRST AID PROCEDURES: · SWALLOWING -- This product is a gas at normal temperature and pressure. SKIN --Wash with soap and water. INHALATION -- Remove to fresh air. Give artificial respiration if not breathing. Give oxygen if breathing is difficult. Call a physician. EYES -- Flush with water~ ' NOTE TO PHYSICIAN: There is no specific antidote· This product is inert. Treatment of overexposure should be directed at the control of symptoms and the clinical condition. L-4602-B MATERIAL SAFETY DATA SHEET J September 1985 An explanation of the terms used herein may be found in OSHA 29 CFR 1910.1200, available from OSHA regional or area offices. (Essentially similar to U.S. Department of Labor Form OSHA-20 and generally accepted In Canada for Information purposes) Do Not Duplicate This Form. Request an Original. PRODUCT Helium CHEMICAL Helium SYNONYMS Helium-4 NAME CHEMICAL Rare Gas FORMULA He FAMILY MOLECULAR 4.003 WEIGHT TRADE NAME Helium For mixtures of this product request the respective component Material Safety Data Sheets. See Section IX. MATERIAL (CAS NO.) Wt (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Helium (7440-59-7) 100 Simple asphyxiant (None currently established) BOLLING POINT, 760 mm. Hg _268.9oc (-452oF) FREEZING POINT -272°C (-457.6°F @ 25 Atto) SPECIFIC GRAVITY (H20 -- 1) Gas VAPOR PRESSURE AT 20°C. Gas SOLUBILITY IN Negligible VAPOR DENSITY (air -- 1) 0.138 @ 21 °C (70°F) WATER, % by wt. PERCENT VOLATILES 100 EVAPORATION RATE Not applicable BY VOLUME (Butyl Acetate -- 1) APPEARANCE AND ODOR Colorless gas at normal temperature and pressure; odorless. IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 304 -- 744-3487 In Canada 514 -- 645-5311 For routine information contact your local supplier ' Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) end become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION [] LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION PRODUCT: Hydrogen L-4604-A April 1986 RESPIRATORY PROTECTION (specify type): Select in accordance with OSHA 29 CFR 1910.134. Respirators shall be ~ acceptable to MSHA and NIOSH. LOCAL EXHAUST -- Explosion-proof system is acceptable. MECHANICAL (general) -- Inadequate. VENTILATION SPECIAL -- Not applicable. OTHER -- Not applicable. PROTECTIVE GLOVES: Preferred for cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. DANGER: Flammable gas under high pressure. Use piping and equipment adequately designed to withstand pressures to be encountered. May form explosive mixtures with air. Ground all equipment. Only use spark-proof tools and explosion-proof equipment. Keep away from heat, sparks and open flame. Store and use with adequate ventilation at all times. Use only in a closed system. Close valve when not in use and when empty. Keep away from oxidizing agents: In event of fire, cool cylinders with water spray from safe distance. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist or other trained person.when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all labels and other instructions supplied with all containers' of this product. For safety information on general handling of compressed gas cylinders, obtain a copy of pamphlet P-l, "Safe Handling of Compressed Gases in Containers" from the Compressed Gas Association, Inc., 1235 Jefferson Davis Highway, Arlington, VA ~;02. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. PREVENT FIRE: Protect cylinders from direct sunlight and store in well-ventilated area. Protect containers from physical damage. Preferably, isolate from cylinders of oxygen andchlorine; Do not load together with explosives, poisons, radioactive materials and organic peroxides. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained, herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of uSe of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. LINI: E IN THE USA: IN CANADA: o UN~ CARBIDE Union Carbide Corporation Union Carbide Canada Limited ' Linde Division Linde Division 39 Old Ridgebury Road 123 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P 1J3 Other offices in principal cities all over the world. L-4604.A 86-0928 4/86 25M Lithographed in U.S.A. Page 4 of 4 PRODUCT: Hydro§en L-4604-A April 1986 FLASH POINT I AUTOIGNITION 520oc (968OF) (test method) Flammable Gas ~ TEMPERATURE FLAMMABLE LIMITS I LOWER 4% UPPER 75% IN AIR, ~ by volume I EXTINGUISHING MEDIA: CO2, Dry Chemicals, water spray or fog. SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately cool container with water spray from maximum distance, taking care not to extinguish flames. Remove ignition sources if without risk. If flames are accidentally extinguished, eXplosive re-ignition may occur. Use self-contained breathing apparatu[ Stop flow of gas if without risk while continuing cooling water spray. Remove all containers from area of fire if without risk. Allow fire to bum out. On site fire bdgades must comply with OSHA 29 CFR 1910.156. UNUSUAL FIRE AND EXPLOSION HAZARDS: Flammable gas. Flame is neady invisible. Escaping gas may ignite "spontaneously". Hydrogen has a Iow ignition energy. Fireball is formed if gas cloud is ignited immediately after release. Forms eXplosive mixtures with air and oxidizing agents. Container may rupture due to heat of fire. Do not extinguish flames due to possibility of explosive re-ignition. Flammable gas may spread from spill. Explosive atmospheres may linger. Before entering area, especially confined areas, check atmosphere with approved device~ No part of a container should be sutYjacted to a temperature higher then 52°C (approximately 125°F). Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. STABIUTY · I CONDITIONS TO AVOID: See Section IX. INCOMPATIBILITY (materlaL~ to avoid): Oxidizing agents, lithium, halogens. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION CONDITION~ TO AVOID: None currently known. May Occur I Will not Occur ! X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR sPILLED: DANGER: Forms explosive mixtures with air (see Section V}. Immediately evacuate all personnel from danger area. Use self-contained breathing apparatus where needed. Remove all sources of ignition if without risk. Reduce gas with fog or fine water spray. Shut off leak ff without risk. Ventilate area of leak or move leaking. container to well-ventilated area. CAUTION: Flammable gas may spread from spill. Before entering area, especially confined areas, check atmosphere with appropriate device. residue, disposable container or liner in en environmentally acceptable manner, full compliance in with Federal, State regulations. P~e 3 of 4 PRODUCT: Hydrogen L-4604-A April 1986 THRESHOLD LIMIT VALUE: See Section II. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING m Unlikely route of exposure, this product is a gas. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- Asphyxiant. Moderate concentrations'may cause headache, drowsiness, dizziness, excitation, excess salivation, vomiting, and unconsciousness. SKIN CONTACT -- No evidence of adverse effects from available information. EYE CONTACT -- No evidence of adverse effects from available information. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: Hydrogen is an asphyxiant. Lack of oxygen can Cause death. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: A knowledge of the available toxicology information and of the physical and chemical properties of the material suggest that overexposure is unlikely to aggravate existing medical conditions. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING -- This product is a gas at normal temperature and pressure. SKIN CONTACT -- Wash with soap and water. INHALATION -- Remove to fresh air. Give oxygen if breathing is difficult. Give artificial respiration if not breathing. Call a physician 'immediately. EYE CONTACT --. Flush with water. NOTES TO PHYSICIAN: T~ere is no specific antidote. This product is relatively inert. Treatment o! overexposure should be directed at the control of symptoms and the clinicaJ condition. Page 2 of 4 L-4604-A · '".. !IIATERIAL SAFETY SHEET Apr,, An ex~enatlon of the terms used herein may be found in OSHA 29 CFR 1910.1200, available from OSHA regional or area offices. C (Emlmntlally ~imllar to U.S. Department of Labor Form OSHA-20 ~ gM~lh/accepted In Calflldl for Informltlon purpoMI) De Not Duplicate Thil Form. Request an Original. PRODUCT Hydrogen CHEMICAL Hydrogen SYNONYMS Not Applicable NAME FORMULA H2 CHEMICAL Not Applicable FAMILY MOLECULAR 2.016 WEIGHT TRADE' NAME Hydrogen For mixtures of this product request the respective component Material Safety Data Sheets. (See Section IX.) MATERIAL (CAS NO.) Wt. (%) 1984-1985 ACGIH TLV.TWA (OSHA-PEL) Hydrogen (1333-74-0) 100 Simple asphyxiant (None currently established) BOILING POINT, 760 mm. Hg -252.77°C (-422.99°F) FREEZING POINT -259.2°C (-434.6°F) SPECIFIC GRAVITY (H=O = 1) Gas VAPOR PRESSURE AT 20°C. Gas SOLUBILITY IN VAPOR DENSITY (air = 1) 0.0696 @ 21 °C (70°F') WATER, % by wt. Negligible PERCENT VOLATILES EVAPORATION RATE 100 Not Applicable BY VOLUME (Butyl Acetate = 1) APPEARANCE AND ODOR Colorless gas at normal temperature and pressure; odorless. IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 1-800-UCC-HELP (1-800-822-4357) In Canada 514-645-5311 For routine information contact your local Supplier Union Carbide requests the users of this product to. study this Material Safety Data Sheet (MSDS) and become aware of product .J. hazards and safety information. To promote safe'use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION [] LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION Copyright © 1986 Union Carbide Corporation Page I of 4 PRODUCT: Nitrogen L-4631-B August 19.85 RESPIRATORY PROTECTION (specify type): Select in accordance with OSHA 29 CFR 1910.134. Respirators shall be acceptable to MSHA and NIOSH. LOCAL EXHAUST--Preferred. MECHANICAL (general)--Acceptable. VENTILATION SPECIAL--Not applicable~ OTHER--Not applicable. PROTECTIVE GLOVES: Preferred for. cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. CAUTION: High pressure gas. Use piping and equipment adequately designed to withstand pressures to be encountered. Can cause rapid suffocation due to oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. ( MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unex- pected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause sedous injury or death. Be sure to read and understand all labels and other instructions supplied with all containers of this product. For safety information on general han,d, ling of compressed gas cylinders, it is recommen.d~ed that a copy of pamphlet P-l, "Safe H. andling of Compressed Gases in Containers,' be obtained from the Compressed Gas Association, Inc., 1235 Jefferson Davis Highway, Arlington, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. GENERAL OFFICES IN THE USA: IN CANADA: ~,~LINDJ~ LindeUni°n DivisionCarbide Corporation UnionLinde DivisionCarbide Canada Limited L · """ ~:~ UNION CARBIDE 39 Old Ridgebury Road 123 Egtinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P I J3 Other offices in principal cities.all over the world. .. L-4631-B 85-0928 8/85 35M Lithographedin U.S.A. Pa(Ia 4 of 4 PRODUCT:Nitrogen O e' L-4631-B August 1985 FLASH POINT AUTOIGNITION Not applicable (test method) Not applicable TEMPERATURE INFLAMMABLE LIMITS I LOWERAIR, % by volume . Not applicable IUPPER Not applicable EXTINGUISHING MEDIA: Nitrogen cannot catch fire. Use media appropriate for surrounding fire. ' ' SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately deluge containers with water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Gas cannot catch fire. Container may rupture due to heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125°F). Most containers are designed to vent contents when they are exposed to elevated temperature. -' STABILITY I CONDITIONS TO AVOID: See Section IX. I I UNSTABLE I STABLE X INCOMPATIBILITY (materials to avoid): Under certain conditions, nitrogen can react violently with lithium, neodymium, titanium, ozone. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: None currently known. May Occur I Will not Occur I X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Evacuate all personnel from danger area. Use self-contained breathing apparatus where needed. Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area. Test area, especially confined areas, for sufficient oxygen content prior to permitting re-entry of personnel. WASTE DISPOSAL METHOD: Slowly release into atmosphere. Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance with Federal, state and local regulations. Page 3 of 4 L-4631-B PRODUCT: Nitrogen August 1985 THRESHOLD LIMIT VALUE: See section II. ~ EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING--This product is a gas at normal, temperature and pressure. SKIN ABSORPTION--No evidence of adverse effects from available information. iNHALATION--Asphyxiant- Moderate concentrations may cause headache, drowsiness, dizziness, excitation, excess salivation, vomit- ing, and unconsciousness. Lack of oxygen can cause death. , SKIN CONTACT--No harmful effect expected from vapor. Liquid may cause frostbite. EYE CONTACT--No harmful effect expected from vapor. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: Contact with liquid may cause frostbite. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: The toxicology and the physical and chemical properties of the matedal do not suggest that overexposure is likely to aggravate existing medical conditions. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None cur- rently known. EMERGENCY AND FIRST-AID PROCEDURES: SWALLOWING--This product is a gas at normal temperature and pressure. SKIN CONTACT--For exposure to liquid, immediately warm frostbite area with warm water (not to exceed 105"F). In case of massive exposure, remove clothing while showering with warm water. Call a physician. INHALATION--Remove to fresh air. Give artificial respiration if not breathing. Give oxygen if breathing is difficult. Call a physician. EYE CONTACT--In case of splash contamination, immediately flush eyes thoroughly with water for at least 15 minutes. See a physician, preferably an ophthalmologist, immediately. NOTES 70 PHYSICIAN: There is no specific antidote: Treatment should be directed at the control of symptoms and the clinical condition. NOTE: Suitability for use as a component in underwater breathing gas mixtures is to be determined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the effects, methods, frequency and duration of use, hazards, side effects and precautions to be taken. · Au uLii ~ An explanation of the terms used herein may be found in OSHA 29 CFR 1910.1200, available from OSHA regional or area offices. (Essentially similar to U.S. Department of Labor Form OSHA-20 and generally accepted in Canada for information purposes) Do Not Duplicate This Form. Request an Original. PRODUCT Nitrogen __._...____ CHEMICAL Nitrogen SYNONYMS Not applicable NAME -.--------- CHEMICAL Not applicable FORMULA N2 FAMILY MOLECULAR 28.01 WEIGHT TRADE NAME Nitrogen For mixtures of this product request the respective component Matedal Safety Data Sheets. See Section IX. MATERIAL (CAS NO.). Wt (°Al) 1984-1985 ACGIH TLV-'rWA (OSHA-PEL) Nitrogen (7727-37-9) 100 Simple asphyxiant (None currently established) C BOLLING POINT, 760 mm. Hg - 195.8°C ( - 320-46°F) FREEZING POINT - 210°C ( - 345'8°F) SPECIFIC GRAVITY (H=O = 1) Gas -------.---- VAPOR PRESSURE AT 20°C Gas SOLUBILITY IN Negligible VAPOR DENSITY (air = 1) 0.967 WATER, °/o by wt. EVAPORATION RATE Not applicable PERCENT VOLATILES 100 (Butyl Acetate = 1) BY VOLUME APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and-pressure. IN CASE OF EMERGENCIES involving this material, further information is available at all times: In Canada 514--645-5311 In the USA 304--744-3487 For routine information contact your local supplier Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user-'should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information_.__~__ UNION CARBIDE CORPORATION [] LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION Page 1 of 4 e MSOS No. APPC Boiling Point Evaporation Rate (Ratio of Time) Dry Point 325' TO 690'F SLOWER THAN ETHYl. ETHER N/AY ~ree:.':ng Point VeDas Pressure Volatile Characteristics Sgecific Gravi~ [H~O ~ 1 at 3~2'R~ Vapor S~.Gr; (Air = 1.0 at 60'-90'~lSolu~ili~ in Water Stabili~ Hazardous Polymerization Viscosi~ Units, Temp., Method pH NOT EXPECTED TO OCCU~ AP 3 CST AT l~'F 0-445 N/AP Other P~si;ai SULFUR C~NTENT = CT O. 5 ~T .% and Chemical A~pelrance KEROSENE ODOR. and Odor , HEAT AND [GN[T[0N S0U~CES. Conditions to Avoid STRONG &CEOS, ALKALIES, ANO 0XZOZZERS SUCH &S 'MetriCS L[QU[O GHLOR]NE A~ OXYGEN. Haz~do~ BURN[~ 0R EXCESSIVE ~EAT[~ MAY P~OOUCE CA~ON Oeeom~osition ~XZDE &NO OTHER HARMFUL GASES/VAPORS ~odu~s OXZOES A~/OR OTHER C0MPOU~S OF SULFUR. SPECIAL SL0t LOA0 PROCEOURES FOR 'SIITCH LOADING' ~ST 8l F~LL0~EO T0 lV0IO' Handling TANKS PREVZOUSLY CONTAINING GASOL[NE OR. OTHER LOW FLASH P0[NT HYDROCARBON mnd PRODUCTS. (SEE A.P.[. eUBL:CAT[0N 2~3. ) KEE~ coNTAZNERS CLosE0 A~ AWAY Storage FROM HEAT A~ [GNZTION SOURCES! ALL ELECTRZCAL EQUIPMENT IN AREAS WHERE ~EQUIREMENTS OF THE NAT[0N&L ELECTRIC CODE, N.F.P.&. O0 NOT USE THIS FUEL AS A CLEANING AGENT. EMPTY CONTAZNERS ~ETA~N SOME L[0U[O &NO VAPOR MAY ~[SULT IN GENERATION 0F HAZAR00US LEVELS 0F COMBUST[0N Pe00uCTS AN0 [NAOEQUATE OXYGEN LEVELS FOR 8REATHZNG. $[NCE $PEC[F[C EXPOSURE $TANOAROS/ Ge,oral ;Comments SINCE SPEC[FIC EXPOSURE 5TANOAROS/CONTaOL LIMITS HAVE NOT ~EEN MZN[MUM CONTROL GUIDELINES FOR INTERIM. USE. MATERIALS SZMZLAR ~0 SOME COMPONENTS IN TH[S PROOUCT WERE FOUND TO BE MUTAGENZC [N '[N vITRO' ANO ":N V[V0" TESTS. THE EXACT RELATIONSHIP BETWEEN THESE RESULTS AND POSSZBLE HUMAN EFFECTS [S NOT KNOWN. SOME OF THE INFORMATION PRE~ENTED A~ CONCLUS[ONS 0RA~N HEREZN ARE FROM SOURCES OTHER THAN O[RECT TEST 0ATA ON THE MIXTURE. [T~ELF. EQ - Eq~ AP a ADoroxi~tetY NIAV" Not AvIiI~tl - - - Note O~ifications: LT - Less ~ UK - ~o~ N/AP - NOt AoOlicele ~ ~ Greater Th~ TR ~ Tr~e N/DA "NO ' Disclaimer of Liabili~ The reformation m th*l MSDS wis OOtlinlO from Sources which we oil,eve are rlliall. HOOVER, THE INFORMA~ON IS PROVIDED WITHOUT ANY R~RESENTA~ON OR WARRANt, E~RESS O~ I~IED. REGARDING ITS AC~RACY OR The cond~t~o~l ~ melhodl of h~dling. StOrage. use ina ail~Olll of t~e ~OOUGt Ifa DeiGn4 ow conYrol lng rely ~e 0eyofl4 FOR THIS AND OTHER REASONS. ~ DO NOT ASSUME RESPQNSIBI~TY AND E~RES~Y DIS~AIM UAII~ FOR LOSS. OAMA~ EXPENSE ARISING O~ OF OR IN ANY WAY CONNEC~D ~TH THE HANDLING. STORAGE, USE OR OlSPOS~ OF ~E PRODUCT. Page 4 of 4 Rev ~ O1 Issui N~ 27 Print Oat~ 09/14/83 ARCO D~ESEL 'MSOS No. AP~C 341 Primary INGESTION OF L~QUT~3. LE.~O[NG TO ASP[RATION INTO THE ~UNGS AND .He~d CHEM[CAC PNEU~NZA. ROU~ OF EXPOSURE. SIGNS AND SYMPTOMS · P;O~ONGED EXPOSURE TO V~PO~S OF TH~S ~ATE~;A~ ~AY CAUSE SYMPTOMS 0F Inhalation NERVOUS SYSTEM DEP;ESS~0N. (SEE. 'EFFECTS 0F OVEREXPOSURE' BOX BE~O~.) Eye EYE ~RR~TATZON MAY ~ESULT FROM CONTACT ~[TH LZQU~D AND/OR VAPORS. Contaat Skin NO SIGNiFiCANT SYSTEM[C EFFECTS ~RE EXPECTED UNDER CONDiTiONS OF Absorption NORMAL USE. Skin SKIN [RR[TAT~ON LEAD,NO TO OERMAT]TZS MAY ~ESULT FROM PROLONGED OR ~EPEATED Irritltio~ SKiN CONTACT. ZNGEST~ON: NAUSEA, VOMZT]NG, DIARRHEA, RESTLESSNESS. Ingestion ASPZRATZON: CHEMICAL PNEU~N;A. ;~ALATZON .... M;LD DEPrESSiON, HEADACHE, NAUSEA, CO~LSZONS, OR LOSS OF CONSC]OuSNESS· Effects Of SKIN CONTACT--OERMATZTZS. ~lxpol~e ASP~RATZON .... CHEMICAL PNEU~N[A. THIS IiTERII[ IS ~T EXPECTED T0 PRESENT i IESPIRIT01Y HAZIIO 8ECIUSE 0F Respirato~ ~T$ LO~ VAPOq PqESSURE. ~ERE EXC~SSZVE VAPORS OR MZST ;ESUkT FRO~ CO~Z- T~ONS OF USEAGE. N]OSH/MSHA APPROVED. qESP[RATORY EQUZPMENT ~ST ~E USE ADEQUATE VENTZ~AT]ON TO KEEP VAPOR CONCENTRATZONS OF THIS Ventilation gELO~ APPLICABLE STANOAqD(S). (SEE SECTION V].-OCCUPAT]ONAL EXPOSURE EYE PROTECTZON (CHEMICAL-TYPE GOGGLES AND/OR FACE SHIELD) SHOULD gE Eye ~HE~EVER THE POSSiBIlITY EX[ST5 FOR EYE CONTACT DUE TO SPLASHING OR SPRAYING LIQU:O. CONTACT LENS SHOULD NOT ~E AV0[O PROLONGED 0R REPEATED SKIN C~NTACT. [F CONO[T[0NS 0R F~[~ENCY 0F Ski~ USE PRESENT 0ANGER 0F EXPOSURE. CLEAN AND :MPERV[0US PROTECTZVE CLOTHING SUCH AS GLOVES. AP~0N. 800TS. ANO FACIAL P~0TECT[0N SHOULD 8E ~OaN. USE GOOO PERSONAL HYG]ENE PRACTICES. ~ASH HANDS BEFORE EAT[NO. 0RINK[NO. Othe~ SMOK[NG. 0R USE~F TO:LET FACZL[T~ES. PROMPTLY ~EMOVE SOZLED CLOTH[NG ~ASH THOROU~LY BEFORE REUSE. OZSCARO FUEL-SOAKED LEATHER SHOES AND GLOVES. Substance So,ge Date 1. KEROSENE (DHE~ PUBL[CAT~0N 77-192) N]0SH 1977 Exposure Limit Value/Time Short Term Limit/Time Pea~ Limit 1~ MO/M3 / IO HOURS 18~ MO/M3 / 15 MINUTES NOT Substance Source Date 2. SEE SECT[ON X[. - GENERAL COMMENTS 1983 · Exposure Limit Value/Time Sho~ Term Limit/Time Peak Limit P~e 2 of 4 AP;)(:: 34 1 0?/22/83 Inblllti=.~~:-~l~ ~XYGEN O~ AD~INI~TE~ CP~ (CA~DIOPUL~ONA~Y RESUSCITATION), IF NECESSARY. MuST OBTAIN PROMPT MEDICAL ATTENTION. FLUSH ~[TH CLEAN LOW-PRESSURE ~ATER FOR AT LEAST 15 MINUTES. [~ IRRITATION Eye PERSISTS, OBTAIN MEOZCA~ ATTENTZ0N. conrad THOROUGHLY ~ASH AFFECTED A~EA ~ZTH SOAP AND ~ATER. ~EM0VE CONTAMINATED Skin CLOTH[NG AND THOROUGHLY CLEJN BEFORE ~EUSE, BUT DISCARD CONTAM;NATED Contact LEATHER GOODS. DO' NOT [NOUCE VOM[T~NG, SZNCE ASPiRATiON ZNTO THE LUNGS ~ZLL CAUSE CHEMZCAL Ingestion PNEUMONZA. MUST 0BTAZN MEDICAL ATTENTZ0N P~OM~TLY. Note to CONTAZN SPZLL. REMOVE ALL ZGNZTZ0N SOURCES &NO SAFELY STOP' FL0¥ OF SPZLL. SPZLL MAY CREATE SLZPPING HAZARDS. EVACUATE AL~ NON-ESSENTZAL PERSONNEL. ZN URBAN AREA. CLEANUP kS SOON AS POSSZBL[; iN NATURAL ENVIRONMENTS. CLEAN- Precautions UP ON AOVZCE FROM ECOLOGISTS.. EQUIP CLEANUP CRE¥S VZTH PROPER PROTECTIVE if MatetIM EOUZPMENT. THIS MATERIAL WILL FLOAT ON WATER. ABSORBANT MATERIAL ANO PAOS is Spilled CAN BE USED. NOT~FY THE NATIONAL RESPONSE CENTER (800/424-8802) AND COMPLY Or Relealed WITH ALL APPLICABLE LAWS. THE SPILLED MATERIAL AND ANY WATER DR SOZL ZT HAS CONTACTED MAY BE HAZARDOUS TO ANIMAL/AQUATIC LIFE MAXZMZZE PRODUCT RECOVERY FOR REUSE PRIOR TO DISPOSAL. USED PRODUCT COULD BE AN EPA "IGNITABLE HAZAROOUS WASTE' (0001). USE APPROVE~ TREATMENT, TRANSPORTERS. ANO DISPOSAL SITES ~N COMPLIANCE W~TH ALL APPLICABLE LAWS. Waste IF SPILL ZS INTRODUCED ZNTO A WASTEW&TER SYSTEM. THE CHEMICAL AND BIOLOGICAL OXYGEN DEMANO WILL LIKELY INCREASE. PROPERLY ACCL:MATE THE Disposal B[OMASS TO THE.MATERIAL. POTENT[AL DISPOSAL METHODS INCLUDE INCZNERATZON, Methods LAND FARMZNG, AND LAND DISPOSAL, IF PERMITTED. Component Name CAS No. Composition amount _ (See Note on Page 4) POUR POINT DEPRESSANT LT 0.I PERCENT [GN[T]0N IMPROVER LT 0.3 PERCENT MIXTURE OF ADDITIVES (METAL DEACTIVATOR, LT 0.01 PERCENT ANTZOXZDANTS, ETC.) KEROSZNE (PETROLEUM) B00~-20-6" AP 0 TO 10 PERCENT STRAIGHT-RUN M~DOLE DISTILLATE 64741-44-2' AP 0 TO . 15 PERCENT (PETROLEUM) SlaEETENED MZDDLE DISTILLATE (PETROLEUM) 6474t-8G-2" AP 0 T0 75 PERCENT CLAY-TREATED DISTILLATE (PETROLEUM) 64742-38-7' AP O TO GO PERCENT HYDRODESULFUR~ZED GAS O~L .(PETROLEUM) 64742'79'6" AP 0 TO 15 PERCENT HYDRODESULFUR[ZED M[DDLE O[ST[LLATE 64742-80'9' AP 0 TO 1~ PERCENT (PETrOLEUm) MEDZUM ALZPHATZC SOLVENT NAPHTHA G4742-~8-?" AP 0 T0 5 PERCE~ (PETROLEUM) Compositions given are typical values, not sgecifications. SEO: 183 P~ge 3 of ,, IIMATERIAL SAFETY I TA SHEET ~' I MSDS No. ARCOe DIESEL IAPP¢ 3,, '~ Rev. Date -- ' '""' 07/2:2/83 IMPORTANT: Re~l this IdBDS before ARC:~ PETROLE~ PRO~CTS D~V~SZON 0F ATLANTIC ~ZCNF~ELD COMPANY h~d~e ~d ~g of th~ ~o~ ~d 5~5 SOUTH FLOWER STREET em~,~stom.~dumef LOS ANGEL~S. CALIFORNIA I Telephone Numbers Trade I EMERGENCY Name ARCO DZESEL ~ 800/424-9300 CHEMTRE¢ Other N~mee DZESEL FUEL 0~L NO. 2: NO. 2 DIESEL; D~ESEL 0ZL (MEDIUM); I 312/333-3000 COMPANY &BTM NO. 2-0 GRADE DZESEL FUEL 0ZL (D-975). I DOT Hazardous Mltl~iall Proper Shipping Name Chemical Flmil~ PETROLEUM HYDROCARBONS I FUEL OZL. OZESEL. NO. 2" ~DO? Hazed Clue Generi~ Nlme I COMBUSTZBLE LZ~UZD' PETROLEUM DZST~LLATE FUEL I¢ompany IUN No. ISB3 CAS No. 6847G-34-G" IlO No. 1037106500 DANGER LZQUZD ZS HARI4FUL OR FATAL ZF SWALLGVED OR ASPIRATED. AVOID BREATNXNG #XST OR VAPORS. AVOZD PROLONGED OR REPEATED SKZN CQNTAGT. Id3DERATEI.Y COMeUSTZBLE! OSHA/NFPA CLASS XX OR KEEP AWAY FRON HEAT, SPARKS, OPEN FLAME, AND REACH OF C:NZI.D~EN! FOR SPEC::ZAL PRECAUTZGNS ON "SYZTC3'I U3ADZNG", SEE SECTZON XZ. '. ::::::::: :: ::..:. :' :::::::::::::::::::::::::::::: ·::::::::::::: - :.. ·: '.7: ..:.:.'... . . . ..: · ... Fl~sh Point <Method! I Autoignition Tempereture (Metl~od) I~.mm.o~. ~,m,js ~% vol ,~ l,,, AP 140'F (D-93) Il AP 495'F (E-659) ~ Lower AP 0.6 Upper AP 7. I Unusual ~DERATELY COMBUST]BLE~ WHEN HEATED ABOVE THE FLASH POINT. THZS MATER~AL Fire and ~{LL RELEASE FLAMMABLE VAPORS ~HZCH ~F EXPOSED T0 A SOURCE 0F ~GN~T~0N CAN Explosion BURN OR BE EXPLOSZVE ZN CONFZNEO SPACES. MISTS OR SPRAYS MAY BE FLAMMABLE H~dS AT TEMPERATURES BELDV THE NORMAL FLASH POZNT. FOR 'S~ZTCH ~0AD~NG' PROCEDURES. SEE SECT[0N Extinguishing FOAM C02' Media DRY CHEMT CAL FOAM, DRY CHEMZCAL, HALON, C02, AND WATER FOG.. FOR F~RES ]NVOLVZNG THZS MATER]AL. DO NOT ENTER ANY ENCLOSED OR CONFZNED F]RE SPACE W~THOUT PROPER PROTECTZVE EOUZPMENT. THIS MAY ]NCLUDE BELa=- SDeciei CONTAZNED BREATHING APPARATUS TO PROTECT AGAZNST THE HAZARDOUS EFFECTS OF Firefighting COMeUSTZON PRODUCTS AND OXYGEN DEFZCZENCES. COOL TANKS &NO CONTAZNERS Procedures EXPOSED TO FZRE W~TH ~ATER. SEQ: 183 :::70R 'DISCLAIMER OF LIABILITY.' SEE THE STATEMENT ON PAGE 4~ Page 1 of XEROX (laterial Safety Data Sleet o,,.. I~,visia~: Sept. 30, 1986 Manufacturer: Versatec (A Xerox Company) (Xerox Corp. Emergency Tel. No.: (716) 422-2177 2805 BowersAve Ro<hester, N.Y. Information Tel. No.: (800) 828-6571 ~anta Clara, CA 95051 14644) SeCtion I - Product. Identification Trade Names/Synonyms: ECP- Cyan Concentrate Part No.: 4814-16, 4814-16-6 Chemical 'Name: None Inqredients CAS No. Isoparaffinic petroleum solvent (80-90%) 64742-48-9 Methacrylate co-polymer } (10.20%) 9011-15-8 Cyan dye Section II - Emergency and First Aid Eyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing, i Ingestion: ' Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation :Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as well as central nervous depression. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest, central nervous system toxicity. Additional Information: Call physician. See Section VIII. Further information on file in Poisindex. Section III - Toxicology and Health Information' This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or safety hazard. Oral LD50: None available TLV: *None established Oermal LDs0: >2 g/kg (Rabbits) practically non-toxic. Inhalation LCso: None available PELt None established Eyelrritation: Not an irritant ~XEL: 200 ppm (Isoparaffinic Skin Sensitization: Not a sensitizer Petroleum Solvent Skin Irritation: Not an irritant Human Patch: (1/100 dilution) potentially irritating**, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A* A-, and WP2 Assays. Carcinogens: None present Aquatic LCs0: None available Additional Information: *The solvent manufacturer recommends an exposure limit of 300ppm for the petroleum solvent. ** This is due to the solvent. ~XEL - Xerox Exposure Limit Form 58739 (1O/&~) STAR N.A. - NOt AOpifcat3te 600P9134 T..,...m.: EC,- Cyan Concrete I Msos.o.: 2004 Section IV- Physical Data Appearance/Odor: Cyan liquid I slight odor Softening Range: N.A. Boiling Point: 160'- 180°C Melting Point: N.~. Solubility in Water:Immiscible Specific Gravity (H20 - 1): .75- .82 Evaporation Rate: .2S-.4S n-butylacetate Vapor Pressure (mm Hg): @20°C 1 Vapor Density (Air · 1):S.0 pH · N.A. Volatile: 8S% (Vol.) Section V- Fire and Explosion Data - Flash Point (Method Used): 102° - 107° F (39-42°C) T.C.C. Flammable LEL: 0.8% Limits UEL: 7.0% Extinguishing Media: Foam, dry chemical, COz, water fog Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. · , Fire and Explosion Hazards: Do not mix or store With strong oxidants like liquid chlorine or concentrated oxygen. Section VI - Reactivity Oata Stable X Polymerization: Will Not OccurI x Hazardous Decomposition Products: Fumes, smoke and carbon monoxide in the case of incomplete 'combustion. Incomparability (Materials to Avoid): Strong oxidants such as liquid chlorine, concentrated oxygen, sodium or calcium hypochlorite. Section VII - Special ProteCtion Information Respiratory Protection: None when used as intended with (Versatec) Xerox equipment. Eye Protection: None when used as intended with (Versatec) Xerox equipment. Protective gloves: Neoprene or nitrile gloves for prolonged or repeated skin contact. Other: None when used as intended with (Versatec) Xerox equipment. Section VIII - SpeCial Precautions Handling and Storage: Keep container closed. Avoid handling near heat, strong light, sparks, open flames, strong oxidents. Conditions to Avoid: Avoid breathing vapors. Avoid prolonged or repeated skin contact. Section IX - Spill, Leak, and Disposal Procedures For Spills or Leakage: Remove ignition Sources. Recover free liquid using an absorbant material (vermiculite, fire retarant, sawdust, etc.) Waste Disposal Method: Dispose of Ii'quid and absorbant at an approved disposal site or facility. Ensure conformity with federat, state or local regulations. Section X- Transportation Information DOT Proper Shipping Name: Combustible liquid, N.O.S. ID Number: N.A. 1993 ~azard Classification: Combustible liquid 600P<J Trade Name: EC~ - Yellow Concentrate I MSDS No.: a~a 2003 Section IV- Physical D ' Appearance/Odor: Yellow liquid/slight odor Softening Range: N.A. Boiling Point: 160'- 180°C Melting Point: N.A. Solubility in Water:Immiscible Specific Gravity (H20 · 1): .75 - .82 Evaporation Rate: .2S-.45 n-butylacetate Vapor Pressure (mm Hg): @20°C 1 Vapor Density (Air - 1):5.0 pH · N.A. Volatile: 85% (Vol.) Section. V- Fire and Explosion Data Flash Point (Method Used): 102° - 107° F (39-42°C) T.C.C. Flammable LEL: 0.8% Limits UEL: 7.0% Extinguishing Media: Foam, dry chemical, CO2, water fog Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Fire 'and Explosion Hazards: Do not mix or store with strong oxidants like liquid chlorine or concentrated oxygen. Section VI-Reactivity Data Stability: Unstab'e- I I HazardousMayOccur 'I " Stable I Ix Polymerization: Will NOt oc,urI x Hazardous Decomposition Products: FUmes, Smoke and carbon monoxide in the case of incomplete combustion. Incompetability (Materials to Avoid): Strong oxidants such as liquid chlorine, concentrated oxygen, sodium or calcium hypochlorite. Section VII - Special Protection Information Respiratory Protection: None when used as intended with Versatec (Xerox) equipment. Eye Protection: None when used as intended with Versatec (Xerox) equipment. Protective gloves: Neoprene or nitrile gloves for prolonged or repeated skin contact. Other: None When used as intended with Versatec (Xerox) equipment. Section VIII- Special Precautions Handling and Storage: Keep container closed. Avoid handling near heat, strong light, sparks, open flames, strong oxidents. Conditions to Avoid: Avoid breathing vapors. Avoid prolonged or repeated skin contact. Section IX - Spill, Leak, and Disposal Procedures For Spills or Leakage: Remove ignition sources. Recover free liquid using an absorbant material (vermiculite, fire retardant, sawdust, etc.) Waste Disposal Method: Dispose of liquid and absorbant at an approved disposal site or facility. Ensure conformity with federal, state or local regulations. Section X- Transportation Information DOT Proper Shipping Name: Combustible liquid, N.O.S. ID Number: N.A. 1993 Hazard Classification: Combustible liquid 600P9133 .: Trade Name: ECP - Magenta :entrate I MSDS No.: ~ I 2002 Section IV- Physical Data ' Appearance/Odor: Magenta liquid / slight odor SOftening Range: N.A. ' ' . Boiling Point: 160e- 180°C Melting Point: N.A. Solubility in Water:Immiscible Specific Gravity (H20 · 1): .75 - .82 Evaporation Rate: .25-.45 n-butylacetate Vapor Pressure(mm Hg): @20°C 1 Vapor Oensity (Air m 1):5.0 pH ,~ N.A. Volatile: 85% (Vol.) Section V- Fire and Explosion Data - Flash Point(Method Used): 102°- 107~ F (39-42°C) T.C.C Flammable · LEL: 0.8% Limits UEL: 7.0% Extinguishing Media: Foam, dry chemical, COz, water fog Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Fire and Explosion Hazards: Do not mix or store With strong oxidants like liquid Chlorine or concentrated oxygen. section vi - Reactivity Data Stability: Unstable- I Hazardous May Occur I :' Stable I X Polymerization: Will Not occurI x Hazardous Decomposition Products: Fumes, smoke and carbon monoxide in the case of incomplete combustion. Incomparability (Materials to Avoid): Strong oxidants such as liquid chlorine, concentrated oxygen, sodium or calcium hypochlorite. Section VII- Special Protection Information Respiratory Protection: None when used as intended with (Versatec) Xerox equipment; Eye Protection: None when used as intended with (Versatec) Xerox equipment. Protective gloves: Neoprene or nitrile gloves for prolonged or repeated skin contact; Other: None when used as intended with (Versatec) Xerox equipment. Section VIII - Special Precautions Handling and Storage: Keep container closed. Avoid handling near heat, strong light, sparks, open flames, strong oxidants. Conditions to Avoid: Avoid breathing vapors. Avoid prolonged or repeated skin contact. Section IX - Spill, Leak, and Disposal Procedures For Spills or Leakage: Remove ignition sources. Recover free liquid using an abSorbant material (vermiculite, fire retardant, sawdust, etc.) Waste Disposal Method: Dispose of liquid and absorbant at an approved disposal site or facility. Ensure conformity with federal, state or locat regulations. Section X -Transportation Information DOT Proper Shipping Name: Combustible liquid, N.O.S. ID Number: N.A. 1993 Hazard Classification: Combustible liquid 600P9132 MSDS No.: 2003 , XE'E OX Material Safety Data Sheet Aug. 1,, 19BS ~vi~on: Sept. 30, 1986 Manufacturer: Versatec (A Xerox Company) (Xerox Corp. Emergency Tel. No.: (716) 422-2177 2805 Bowers Ave Rochester, N.Y. Information Tel. No.: (800) 828-6571 Santa (:3ara, CA 95051 14644) Section I - Product Identification Trade Names/Synonyms: ECP- Yellow Concentrate Part No.: 4812,16, 4812-16-6 Chemical Name: None Inqredients CAS No. Isoparaffinic petroleum solvent (80-90%) 64742-48-9 Methacrylate co-polymer 9011-15-8 Yellow dye } (10-20%) Section II- Emergency and First Aid Eyes: Flush thoroughly with 'water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing. Ingestion: Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as well as central nervous depression. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest; central nervous system toxicity. Additional Information: Call physician. See Section VIII. Further information on file in Poisindex. Section III-Toxicology and Health Information This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or sa fety hazard. Oral LD50: None available TLV: *None established Dermal LDs0: >2 g/kg (Rabbits) practically non-toxic. Inhalation LC. SO: None available PEL: None established Eye Irritation: Not an irritant Skin Sensitization: Not a sensitizer ~XEL: 200 ppm (Isoparaffinic Skin Irritation: Not an irritant Petroleum Solvent) Human Patch: (1/100 dilution) potentially irritating**, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A +A-, and WP2 Assays. Carcinogens: None present Aquatic LCs0: None available Additional Information: *The solvent manufacturer recommends an exposure limit of 300ppm for the petroleum solvent. ** This is due to the solvent. 1XEL - Xerox ExOosure L~mit ~orm 58739 (10,~4) STAR h~,A. - NOt AOOt~cable 600P9133 M~U~, ~o.: 2001 -XEi; OX : vlateriai safety Data Sll et o..:. Aug. 985 - ~ I~evisiQn: Sept. 30, 1986. anufa~urer: Ve~t~ (A Xerox Company) (Xerox Corp. Emergency Tel. No.: (716) 422-2177 2~5 Bowe~Ave R~hester, N.Y. Information Tel. No.: (800) 82~6571 Sa~ ~ara, ~ 95051 1~) Section I - Produ~ Identification 'rade Name~Synonyms: ECP- Pr~ess 81ack Concentrate ' PaK No.: ~11-16, ~11-1&6 Chemical Name: None Inqredien~ ~S No; Isoparaffinic petroleumsolvent (80-90%) 64742-48-9 9011-15-8 Methacrylate co-polymer } (10-20%) 1333-86-4 Carbon black Section II - Emergency and First Aid :; Eyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing. Ingestion: Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as well as central nervous depression; Intentional inhalation may result in abnormal heart rhythms, respiratory arrest, central nervous system toxicity. Additional Information: Call physician. See Section VIII. Further information on file in Poisindex. Section III- Toxicology and Health Information This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or safety hazard. Oral LDs0: None available TLV: *None established Dermal LDs0: >2 g/kg (Rabbits) practically non-toxic. Inhalation LC. so: None available PEL: None established Eye Irritation: Not an irritant ~XEL: 200 ppm (Isoparaffinic Skin Sensitization: (Not a sensitizer Petroleum Solvent) Skin Irritation: (Not an irritant Human Patch: (1/100 dilution) potentially irritating**, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A* A-, and WP2 Assays. Carcinogens: None present AquaticLCso: None available- Additional Information: * The solvent manufacturer recommends an exposure limit of 300ppm for thepetroteum solvent..** This is due to the solvent. ~XEL - Xerox Exposure. Limit Form 5873g (10/~1) STAll N.A. - NOt AoghcaOle 600P91 31 us~s No.: 2002 · .XEROX Material Safety Data Sheet o,,...Aug. 1,, 1,.S ~vish)n: Sept. 30, 1986 Manufacturer: Versatec (A Xerox Company) (Xerox Corp. Emergency Tel. No.: (716) 422-2177 2805 8owers Ave Rochester, N.Y. Information Tel. No.: (800) 828-6571 Santa Clara, CA 95051 14644) Section I - Product Identification TradeNames/$ynonyms: ECP-Magenta¢oncentrate PartNo.: 4813-16,4813-16-6 Chemical Name: None Inqredients CAS No. lsoparaffinic petroleum solvent (80-90%) C04742-48-9 9011-15-8 Methacrylate co-polymer Magenta dye ' } (10-20%) - Section II - Emergency and First Aid Eyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap'and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing. _. Ingestion: Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as well as central nervous depression. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest, central nervous system toxicity, Additional Information: Call physician. See Section VIII. Further information on file in Poisindex. Section III - Toxicology and Health Information This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or safety hazard. Oral LDs0: None available TLV: *None established Dermal LDs0:. ~2 g/kg (Rabbits) practically non-toxic. Inhalation LCso: None available PEL: None established Eyelrritation: Not an irritant sXEL: 200 ppm (Isoparaffinic Skin Sensitization: Not a sensitizer Petroleum Solvent) Skin Irritation: Not an irritant Human Patch: (1/100 dilution) potentially irritating*e, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A * A-, and WP2 Assays. Carcinogens: None present Aquatic LCso: None available Additional Information: *The solvent manufacturer recommends an exposure limit of 300ppm for the petroleum solvent. · * This is due to the solvent· ~XEL- Xerox Exoosure Limit Form 58739 (10/~4) STAR N.A. - NOt ADplicable 600P9132 " Trade Name: ECP- Process B~ Concentrate MSDS No.: ' 2001 Section IV- Physical Data Appearance/Odor: Black liquid / slight odor Softening Range: N.A. Boiling Point: 160'- 180°C Melting Point: N.A. Solubility in Water:Immiscible Specific Gravity (H20 - 1): .75 - .82 Evaporation Rate: .25-.45 n-butylacetate Vapor Pressure (mm Hg): @20°C 1 Vapor Density (Air- 1):5.0 pH · N.A. Volatile: 85% (Vol.) .. Section V - Fire and Explosion Data Flash point (Method Used): 102° - 107° F (39-42°C) T.C.C Flammable LEL: 0.8% Limits UEL: 7.0% Extinguishing Media: Foam, dry chemical, CO2, water fog Special Fire Fighting Procedures: Use air-supplied breathing equipment for enclosed areas. Cool exposed containers with water spray. Avoid breathing, vapor or fumes. Fire and Explosion Hazards: Do not mix or store with strong oxidants like liquid chlorine or concentrated oxygen. Section VI- Reactivity Data Stable X Polymerization: Will Not OccurI X Hazardous Decomposition Products: Fumes, smoke and carbon monoxide in the case of incomplete combustion. Incomparability (Materials to Avoid): Strong oxidants such as liquid chlorine, concentrated oxygen, sodium' · or calcium hypochlorite. Section VII - Special Protection Information Respiratory Protection: None when used as intended with Versatec (Xerox) equipment. Eye Protection: None when used as intended with Versatec (Xerox) equipment. Protective gloves: Neoprene or nitrile gloves for prolonged or repeated skin contact. Other: None when used as intended with Versatec (Xerox) equipment. Section VIII - Special Precautions Handling and Storage: Keep container closed. AvOid handling near heat, strong light, sparks, open flames, strong oxidants. Conditions to Avoid: Avoid breathing vapors. Avoid prolonged or repeated skin contact. Section IX - Spill, Leak, and'Disposal Procedures For Spills or Leakage: Remove ignition sources. Recover free liquid using an absorbant material (vermiculite, fire retardant, sawclust, etc.) Waste Disposal Method: Dispose of liquid and absorbant at an approved disposal site or facility. Ensure conformity with federal, state or Iocat regulations. Section X - Transportation Information DOT Proper ShiPping Name: Combustible liquid, N.O.S. ID Number: N.A.' 1993 Hazard Classification: Combustible liquid SO01xJ131 Trade Nlm: I KOS No.: Versatec Clear Oispersant I 2050 Section IV- Physical Data Al~earanceJOdor: Waterwhite liquid/mild odor Softening Range: N.A. Boiling Point: 315.3480F (157-1760C) Melting INiint: None available Solubility in Water: Negligible Specific Gravity (H20 - 1): 0.75 Evaporation Rate: 0.3 (n-butyiacetate = 1) Viper Pressure (mm Hg): (~ 250C < 10 Va~or Density (Air · 1): 5.0 pH · None available Volatile N.A. % (Wgt.) 100% (VOL) Section V - Fire and Explosion Data Flash Point (Method Used): 10SOF(T. CC) Flammable LEL:. 0.8% LJmit~ UEL: 7.0% Extinguishing Media: Foam, dry chemical, CO2, water fog or spray. Special Fire Fighting Procedures: Use air-supplied, breathing equipmerrt for enclosed areas. Cool exposed containers with water spray. Avoid breathing vapor or fumes. Fire and Explosion Hazards: Do not mix or ;tore with st,-prig oxidants like liquid chlorine or concentrated oxygen. . Section VI -Reactivity Data Stable X Polymerization: Will Net O~r. ur~ X HazardOus Decomposition Products: Fumes, smoke and carbon monoxide in the case of incomplete Incompatability (Materials to Avoid): Strong oxidants like liquid chlorine, concerrtrated' oxygen, sodium or calcium hypochlorite. Section VII * Special Protection Information Respiratory Protection: None when used as intended in Versatec (Xerox).product~ Eye Protection: Splash goggles or face shield when a splash hazard exists (i.e. pouring). Protective Gloves: None when used as intended in Versatec (Xerox) products. Other: Chemical resistant apron or other clothing if needed to avoid repeated or prolonged skin contact. Section VIII- Special Precautions Handling and Storage: Keep containers closed when not in use. Do not handle or store near heat, sparks, flame or strong oxidants. Conditions to Avoid: Adecluate ventilation recluired (equivalent to outdoors). Section IX - Spill, Leak, and Disposal Procedures For Spills or'Leakage: Remove ignition sources. Recover free liquid, using an al~sorioant material (vermiculite, fire retardant, sawdust, etc.). Waste Oislx~sal Method: Dispose of liquid and absorbant at an approved disposal site or facility. Ensure conformity to local, state and federal regulations. Section X -Transportation Information DOT Proper Shipping Name: Petroleum Naphtha Hazard Classification: Combustible Liquid ID Number: UN~1255 ':XEi OX /laterial Safety Data Si' let o,,:. Aug. 19, ,985 _ ~evisiofl: Sept. 30, 1986 Manufacturer: Versatec (A Xerox Company) (Xerox Corp. Emergency Tel. No.: (716) 422o2177 ' 2805 Bowers Ave Rochester, N.Y. Information Tel. No.: (800) 828-6571 Santa Clara, CA 95051 14644) Section I - Product Identification Trade Names/Synonyms: ECP- Process Black Concentrate ' Part No.: 4811-16, 4811-16-6 Chemical Name: None !nqredients CAS No. Isoparaffinic petroleum.solvent (80-90%) 64742-48-9 9011-15-8 Methacrylate co-polymer } (10.20%) 1333-86-4 CarbOn black Section II - Emergency and First Aid Eyes: Flush thoroughly with water. Skin: Remove contaminated clothing. Wash skin thoroughly with soap and water. Inhalation: Remove from exposure. Observe for any difficulty in breathing. Ingestion: Dilute stomach contents with several glasses of water. Primary Route of Entry: Inhalation Symptoms of Overexposure: Ingestion poses maximum risk of severe respiratory distress by aspiration, as well as central nervous depression. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest, central nervous system toxicity. Additional Information: 'Call physician. SeeSection VIII. Further information on file in Poisindex. Section Iil- Toxicology and Health Information This material has been tested and evaluated by Xerox Corporation. When used as intended, it does not represent a health or safety hazard. Oral LDso: None available TLV: ' 'None established Dermal LDs0: :>2 g/kg (Rabbits) practically non-toxic. Inhalation LC. so: None available PEL: None established Eye Irritation: Not an irritant Skin Sensitization: (Not a sensitizer lXEL: 200 ppm (Isoparaffinic Petroleum Solvent) Skin Irritation: (Not an irritant Human Patch: (1/100 dilution) potentially irritating'*, non-sensitizing Mutagenicity: No mutagenicity detected in Ames, Poly A-A-, arid WP2 Assays. Carcinogens: None present AquaticLCs0: .None available Additional Information: * The solvent manufacturer recommends an exposure limit of 300ppm for thepetroleum solvent. '* This is due to the solvent. ~XEL - Xerox Exposure Lirmt ~orm ss739 ( ~o~! s?=* N.A. · NOt AoPhcaDle 600P9131 MSOS Ne,: 2050 XEROX Material Safety Data Sheet M.y 22. ,sas. ~ SeOt. 30, 1986 Manufacturer: Versatec (A Xerox Company) (Xerox Corp. . Emergency Tel. No.: (716) 6,22-2177 2805 BowersAve. Rocl~ester, N.Y. Informabon TeL NO.: (800) 828-6571' Santa Clara, CA' 95051 1464a) Section I - Product Identification Trade Names~Synonyms: Versatec Gear Dispersant Part No.: 4403-1, 4403.1GR, 4403.2, 4403~3, 4403-1-1, 4403.1-4, 4403:2.1, 4403-3-2, 4403.1G R-2,4403-16-6 Chemical Name: Petroleum solvent Iflqrediem~ C~AS No. Isoparaffinic petroleum solvent 64742-48-9 SectiOn II - Emergency and First Aid Eye: Flush thoroughly with water. Skin: Remove contaminated clothing. Wish skin thoroughly with soil:) and warm water. Inhalation: Remove from exposure. Observe for any clifficuity in breathing. Ingestion: Dilute s~omach contents with several glasses of water. I:~ nat induce vomiting Primary Route of Entry: Inhalation Symptoms of Overextsosure: Ingestion W maximum risk of severe respiratory distress by asl)iration, as well is central nervous del0ressJon. Intentional inhalation may result in abnormal heart rhythms, respiratory arrest, central nervous system toxicity. Additional Information: Consult a physician. Further information on file in Poisindex. Section III- Toxicology and Health Information This material has been extensively tested and evaluated by Xerox Corporation. When used as intended, it does not represent any known health or safety hazan~. Oral LDso: > 10 g/kg (Rat) Practically non-toxic. TLV: 'None es~aiolished Dermal LDs0: >3.1 g/kg (Ral010it) Practically non-toxic. Inhalation LCso: 2240ppm/4 hrs. (Rat) Practically non-toxic. PEL: None established Eye Irritation: Not an irritant Skin Sensitization: Not a sensitizer ~XEL: 200 porn (Isoparaffinic Skin Irritation: Not an irritant 'Petroleum Solvent) Human Patch: Non-sensitizing. May cause irritation and dermatitis with prolonged or repeated contact. MutagenicJty: None availa~)le CarcJno~jens: None present Aquatic LCse; None availalole Additional Information: 'The manufacturer recommends an exposure limit of 300Dom. ~XEL- Xerox ExOosure L~en~t LCorm 58739 (10/~) STAR N.A. - NOt Appl~caele &OOP9208 No. SECTION VI. I'~EALTH HAZARO INFORMATION i~ I Tcv Z5-50 ppm (See Sect. II) ISE[n da~8e can occu~ ~roe repeated, pro[on~ed, or high concentration contact. ~ove 700 ppn ia at~ ca~es severe eye t~]u~7 and poss~5[e Loss o~ vtston ti hoc c~eaced aed~ace[y. Su~utnS 3~d b[tscertn~ of the skin, ~s ~e[[ as se~to~ Junk ed~, occu~ qu~c~y above [700 ppm ~n 3~r. Concave ~ch ~qu~d ~n~a v~[[ p~o~uce ~oscb~ce ETe-~ncacc:'~ Flush ~ith ~ots o~ ~unnin~ water ~ediatel~ and continue ac least 15 inclUd~nE Under the.eyelids. Then contact physician ~ediacely, preferably an opchchal~losisc. Speed and chorou~hness in rinsin~ ayes [s t~orcanc co a~id per-~ ~nenc Enjoy. . Skin ~ncacc:-:' [~ediacely flush with water and remov~ contaminated clochins. =rozen clochin~ before removal. Gec medical help ~= irrlcacion persists or large area affecced. . Inhalation: '~ ~e~ve ?rompciy ~o ~resh air. ~escore anq/or supporc breacin8 if req~re~; ~eep wa~ and ~c =est. Call ~hys~cian.. Have craineo per~qn ~d~n%scer o~8~n. Kescuer requires proper respirator e~u~pme~ ~o prevent n[s oecom[n~ a v[cc~m Establish written plans ~or emergency. Evacuate area of leak (and possibly d~nd als~). Exciude all except properly equipped (see Sect. V~I) and trained perso~el ~ch. e~r-J ~ency assi~n~ncs. El'~minace ~n~cion sources an~ provide ventilation. Use a cold spray co absorb ~3- An open bottle of Conu. HCi can be used co detect sources of ~}1 lea~. ~en possible, leakage should be adjusted co discharse ~, nec liquid ~3' hOC c~ co neutralize liquid ~ spills with acid~ Caseous ~3 ~Y be dischacKed ~d water for collection; do hOC directly discharge this solution Co ~cip~i s~rs~ confined drains, or sub,ace waters. DISPOSe: Solutions of ~3 in pure wace= used or sold. For dischar]e, roi!ow ~ederal, Scare and local regulations. ~uncs of ~1 ~as ~y be .el~ased co the acmosohere under appropriate condiCio~. Limited ~un[s of a~nia so[uclon can be highly diluted ~ch racer (neutralized?) dischar~e. ~e receivin8 scre~ must hoc excee~ escaol[sned Li~cs ~or ~] or s~cs./ SECTION VIII, SPECIAL PROTECTION INFORMATION ~rovide ~eneral ventilation an~ exhaust ventilation ~o meec ~V requir~ncs. ~n~s use explosion-pcoo~ electrical se~ice~ ~or ~3.) For emergency and nonroutine conditions a chemical cor~rid~e respirator w'Lch fu[l-~acepiece can be used periods be[ow 300 ppm; above 300 ?pm or f'oc unknoun exposures, aporoved, full-Eacepiec self-contained %re~chin~ app~rncus should be available. ' ~o prevent skin ~nc~c~ use rubber ~utc. boo~s. ~loves, apron, etc. as appropriate workplace ,:ondi=[ons. Use safety ~og~L~:s and ~aceshieid co pr=Lc~ eyes [rom 8as and direct sp[ashin~ o[ so[ucions. [n eyewash station and surety sho~er must be ~udiace[v accessible .o workers where a~onia is used or handle~l WashinK facilicies and Lic~e amounts o~ 'Lean be available for emergency use. (See also ANSI/CGA G2.[-[97~, formerly ~I ~61.1, on s~orase and handlin~ of anhydrous a~onia.) SECTION IX. SPECIAL PRE'C.a~I~ION$::AND C. DMMENTS tore cylinders or tanks in a cool, well-ventilated, fire-resistant Location, away from oxidizing agents, combustible materials, and sources of heat or ignition. Special external storage, out of direct sunlight, is preferred. See also CFR 29,Chapter X'VII, Parc 1910.111 for regulations on containment and handling of annydrous a~onia. Folloq good practices for compressed gas in cylinders. [on~tor workplace to be sure of ammonia ekposures of workers. . ~or~ practices and equipment must be designed to ~revent any contact of liquid a~on~a k or a~nonia solutions ~i~h a worker's bo~v.- ~replacement and periodic medical examination is recommended for ammonia workers, and aminacions should be provided ~hen excessive ex)osure condi~ions occur. ~ee~ records. Provide training ~o ~orkers on safe handling. MIS, DATA SOURCE(S) CODE: 2-~ , L9 '4 16~3L APPROVALS: ~RD, , ~L2~l~, ,£0,_ , . .... ~ .... , .... o,,.~ ~ ..... , ..... '-o,~ ....... ~,~,, · MEDICAL REVIEW: 12/79 GENERAL ~ ELECTRIC MATERIAL SAFETY DATA SHEET CORPOIIATE 'RESEARCH & DEVELOP--ENT ~1 ~t~ RE~T.$ON B SCHENECTADY, N. Y. ~MAT~ Phone: (5L8) 385-~08~ ~L CO~ ~'215-;O85 D~e ~ovember L979 SECTION [. MA~ERL,~ [DE~TT~ICATION pZ~ed pressure.zed. ~n cyk~nders or cank~. ~ER DESZ~T:ONS: ~3, ,~nLa Gas, GE ~acer~aL 027A~, ~S ~O07 ~AC~: AvaLLab~e ~tom ~ny suppLLets. SECTION II. INGREDIENTS AND ~AZARDS = Anhydrous ~nLa ~99.5 8-bt ~A 50 p~me H~, L~a~acton *Current OS~ ~V; ~:OSH has proposed a' 50 ppm CeLLLn~ L~m~c (~ m~nuce s~p~:n8 clx). ~e current ACG:H ~V Ls 25 ppm. LC~ 2000 ppm/a SECT[ON II~, PHYSICAL DATA BoLa:ns poLnc, L acm, ~e~ ? (C) ~8 (-33.-) SpecLftc ~ravtc7 60/60 F -- 0.62 Vapor pressure ac 60 ~, ~ ~g ~800 VoLacLLes, ~ ca :00 Vapor density (A~r-L) . 0.6 =H o~ L% water solution --- 1~.7 :Solub~Zi:7 ~ ~acer, g/100 cc: >leZcin~ point, deb ~ (C) -- -108 AC 0 C 89.9 (-77.7 AC ZOO C 7.~ ~oZecuLar ~etBhc Appearance a Odor: L~quid at ~o~ temperature, moderate pressure. ColorZess moderate :empera:ure, ~ou pressure. 5crong, pungent odor, dececcabZe at 5 ppm, irrtcactn~ at 25-~0 ~m; odor ~rovtdes a ~arnin~ of hazard. SECTION IV, FIRE AND EXPLOSION DAT4 ,Gaseous ac room condiment~ 120~ F(~,~on presen~* Vol. 'J 16 25 Ez[~u~&n~ ~ia:..s.~ (s~a~;~r fo~) is best. Stop ftow ~as. Use wager co keep fire-exposed containers cool and':'~rOCeC~ men affec:in~ shu[ off. fire and e~fosion haz~ whe~ e~se4 ~o heaE or fiat. ~f ~as are heavily e~osed ~o h~aE, evacuate the area and =he area downwind. Heac e~ose4 tanks should vent ac 250 ~si. Violent rupture can occur tf relief valves fail. Firefi~h~ers need self-contained breachinE apparatus ~ich fu[l-facepiece and full pro- teccive clochinK. SECTION V, REACTIVITY DATA Co~cai~ed tnh~d~ous ~] ac ~oom temperature is stable. LE ~eaced ~bove ~0 C, decompom- ' icion'Co H2 and N~ begins, it is an alkaline gas which reacts rich acids with much hea~ evolution; i~ reacts wi~h CO~ from the air. Con~acc of ~3 w~ch chemicals such as mercury, chlorine, toG[ne, bromine, silver oxide, or hypochlorices can fo~ explosive compounds. Do not use copper, brass, bronze or galvanized s~ee[ ~[n concac: w~ch a~qnia. Welded joints are preferred ~o ~hreaded joints in a~on~a ~ervice. Do not use brazed joints. GENERAL 0 ELECTRIC BUSINESS NAME ARCO OIL KND GAS COMPANY ID NUMBER 215-000-000890 LOCATION 4550 CALIFORNIA AV HIGH HAZARD RATING 2 1 . OV]Ei=~V I EW LAST CHANGE 11/09/87 BY ESTER JURIS CODE 215-003 JURIS BAKERSFIELD STATION 03 MAP PAGE 102 GRID 35A FACILITY UNITS 1 HAZARD RATING 2 RESPONSE SUMMARY 2A SEC 4) NO PRIVATE RESPONSE TEAM EMERGENCY CONTACTS 2A SEC 2) CECILIA ZACHERY - SVC MGR - 321-4177 OR 832-1848 JOHN HANDLIN - BUS MGR - 321-4200 OR 836-2164 UTILITY SHUTOFFS 2A SEC 3) A) GAS - NE END OF BLDG B) ELECTRICAL - NE END OF BLDG C) WATER - NE END OF BLDG D) SPECIAL - NONE E) LOCK BOX - NO 4 . LOCAL EMERGENCY MEDICAL ASSISTANCE LAST CHANGE 11/09/87 BY ESTER 2A SEC 5} FOR MINOR INJURIES - VICTIMS ARE TAKEN TO BAKERSFIELD FAMILY MEDICAL CENTER. FOR MORE SERIOUS EMERGENCIES - PERSONNEL ARE INSTRUCTED TO CALL 911. PAGE 1 06/02/88 08:11 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 BUSINESS NAME ARCO OIL AND GAS COMPANY ID NUMBER 215-000-000890 LOCATION 4550 CALIFORNIA AV HIGH HAZARD RATING 2 FACILITY UNIT 01 A . OVERALL HAZARDOUS MATERIALS INVENTORY LAST CHANGE 06/02/88 BY ESTER ID TYPE NAME MAX AMT UNIT HAZARD LOCATION CONTAINMENT USE 1 PURE DIESEL FUEL 330 GAL MODERATE BASEMENT BY GENERATOR, ABOVE GROUND TANKS FUEL ID PERCENT COMPONENTS HAZARD LISTS 1178.00 100.0 FUEL OIL NO. 1 MODERATE 2 PURE ANHYDROUS AMMONIA 6700 FT3 MODERATE 3RD FLOOR, RM 691 PORTABLE PRESS. CYL. OTHER ID PERCENT COMPONENTS HAZARD LISTS 1024.00 100.0 AMMONIA MODERATE EPA 3 MIXTURE ISOPARAFFINIC SOLVENT 80 GAL UNKNOWN 6TH FLOOR, ROOM 691 PLASTIC CONTAINER[S] OTHER ID PERCENT COMPONENTS HAZARD LISTS 2291.00 100.0 WASTE ACIDS UNKNOWN B . FIRE PROTECTION / WATER SUPPLIES LAST CHANGE 11/09/87 BY ESTER 3A SEC 4) FIRE HYDRANT LOCATED IN STAIRWELL. AUTOMATIC SPRINKLER SYSTEM TIED INTO FIRE DEPARTMENT. FIRE ALARMS NOTIFY CITY FIRE DEPARTMENT. CENTRAL FIRE ROOM LOCATED ON GROUND FLOOR. 3A SEC 5) OUTSIDE FIRE HYDRANT LOCATED ON EAST SIDE OF BUILDING. CONNECTION FOR FIREHOSE IN STAIRWELL. PAGE 2 06/02/88 08:11 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 BUSINESS NAME ARCO OIL AND GAS COMPANY ID NUMBER 215-000-000890 LOCATION 4550 CALIFORNIA' AV HIGH HAZARD RATING 2 FACILITY UNIT 01 D . EMPLOYEE NOTI F'i CATION / EV~tCUAT I ON LAST CHANGE 11/09/87 BY ESTER '3A SEC 2) NOTIFICATION IN THE EVENT OF A FIRE WILL BE THROUGH FIRE ALARMS. THIS PART OF THE BUILDING IS NOT NORMALLY OCCUPIED, HOWEVER, OTHER FLOORS HAVE "FLOOR WARDENS" ASSIGNED. IN THE EVENT OF AN EMERGENCY, THE COMMAND CENTER (ROOM 768, OPERATIONS~MANAGER) WILL NOTIFY EACH WARDEN OF THE EMERGENCY. WARDENS COORDINATE EVACUATION OF HIS/HER FLOOR. EVACUATION OF THE BASEMENT WILL BE THROUGH THE DRIVEWAY ENTRANCE ON THE SOUTHWEST SIDE OF THE BUILDING. E . MITIGATION / PREVENTION / ABATEMENT LAST CHANGE 06/02/88 BY ESTER 3A SEC 1) PREVENTION: INVENTORIES ARE KEPT TO A MINUMUM. REGULAR INSPECTION OF DIESEL STORAGE AREA. FOR EMERGENCY FIREFIGHTING PURPOSES ONLY. ABATEMENT & MITIGATION: USE OF RAGS AND ABSORBENT MATERIAL IN CASE OF SPILL. SECONDARY CONTAINMENT OF DIESEL STORAGE TANKS. PAGE 3 06/02/88 08:11 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 ARCO Oil and Gas Company Western District Post Office Box 147 Bakersfield, California 93302 · Telephone 805 321 4000 May 17, 1088 ~~ .......... Captain Ralph E_. Huey Bakersfield Fire Department 2101 "H" Street Bakersfield, California 93301 " Dear Captain Huey: Enclosed for your files is a completed Acutely Hazard- ous Materials Registration Form for ARCO Oil and GaAs Company's office. ARCO Oil and Gas Company's Labora- tory located at 4800 Easton Drive, Suite L, does not handle any of the acutely hazardous materials listed in SARA Title III, Section 302. If you have any questions regarding ARCO's facilities, please contact me at 321-4052. Sincerely, Nancy B. Johannesmeyer -Environmental Engineer ._ NBJ/sb Enclosure ARCO OII and Gas Company is a Division of AtlanlicRichfieldCompany ACtJT =LY HAZARDOUS MATERIALS RE 'iSTRATION FORM THIS FORM MUST BE COMPLETED BY THE OWNER OR OPERATOR OF EACH BUSINESS IN CALIFORNIA WHICH AT ANY TIME HANDLES ANY ACUTELY HAZARDOUS MATERIAL IN QU ,ANTiTIES GREATER THAN 500 POUNDS, 55 GALLONS OR 200 CUBIC FEET OF GAS AT STP. ~ THIS FORM SHALL BE COMPLETED AND SUBMITFED TO YOUR LOCAL ADMINISTERING AGENCY. (§25533 & 25536 Health & Safety Code) Not~ instructions on r{~v~r~ Business Name ARCO 0il and Gas Company Business Site Address 4550 California Avenue, Bakersfield, California Business MailingAddress(ifdifferent) Post Office Box 147, Bakersfield, California 93302 Business Phone (80'5) 321-4000 Business Plan Submission Date2 7/20//87 Process Designation3 0ffi ce ACUTELY HAZARDOUS MATERIALS HANDLED4 -USE ADDITIONAL PAGES IF NECESSARY- CHEMICAL NAME QUANTITY ~ Anhydrous Ammonia 6700 Ft3 GENERAL DESCRIPTION OF PROCESSES AND PRINCIPAL EQI,IIPMENTS: Graphics Reproduction Equipment SIGNATURE ~ ~ ~~~ TITLE Environmental Enaineer PRINTED NAME Nancy B. Johannesmeyer DATE Ma.'/ 17, 1988 California office of Emergency Services FORM HM 3777 (1-15-88) INSTRUCTIQN$: Superscripts: 1. Quantities for RMPP compliance are "equal to or greater than" the minimum criteria and apply to chemicals handled "at any one time". 2. Businesses handling reportable quantifies of Acutely l-laTardous Materials that have not submitted a business plan MUST contact local Administering Agencies. The business plan submission date will assure the Administering Agency that a business plan has been submitted and is on f'fle. This will also immediately identify businesses that have not submit~d business plans.' - 3. "Pmce.~ Designation" is provided as a reporting option (with the approval of the Administering Agency) for facilities that can most easily report by process. Thus, facility RMPP registration data could be submitted in a similar format to a business plan that is divided by process. "By process" data can initiate an emergency · -~ msporL~ to-a.proee~s.incidentrather~flmh, a:genexal em~gency_respq.__nse_to~amajo~r f_a~cih'ty,~Prg~c~ _e_ss__des_i.~m~_ .a~dqn can simplify inspections for major facilities afld improve future emergency response. 4. Refer to the EPA list of Extremely Hazardous Substances from the Federal Register (Volume 52, No. 77, p. 13397 et. seq., April 22, 1987). Each chemical has a threshold planning quantity. 'This list may be changed by EPA on an annual basis. Updates of this list may be available early in 1988. To comply with this element, you may attach a copy of the inventory submitted to your Administering Agency from your business plan and highlight all Acutely Hazardous MateriaLs. It is recommended that facilities list all extremely haTardous chemicals handled in quantities equal to or in excess of 1) 500 pounds, and 2) any EPA threshold planning quantity less than 500 pounds. 5. Do not include Trade Secret information in these descriptions. General: For emergency response purposes, it would be desirable to describe the following to the Administering Agency: 1. Batch Process: ·., a. What raw matedals? b. What operating l:ressure range? c. What opetming teanpea-'auwe range? cl. Batch capacity rating? e. Product ctuu'acteristics? (e.g., chemical rate, flammability, toxicity, etc.) f. Critical points and characmristics? ,NOTE: "Pursuant to §25534, the Administering Agency may require the submission of a Risk Management Prevention Program (RMPP), if the Administering Agency determines that the handler's operation may present an'acutely hazardous materials accident risk. The handler shall prepare the RMPP in accordance with suixtivision (c) [of §25534]. The RMPP shall be prepared within 12 months following the request made by the Administering Agency pursuant to this section." (§ 25534 (a) Health and Safety Code) An amendment to ~ RMPP must be submiued to the Administering Agency within 30 days of: 1. Any additional handling of acutely hazardous materials. 2. Any material or substantial alterations to business nctivities. 3. Change of address, business ownership, or business name. (§ 25533 (c) Health & Safety Code) · EVERY BusINESs REQUIRED TO SUBMIT AN RMPP SHALL IMPLEMENT THE APPROVED RMPP · California Office of Emergency Services FORM HM 3777 (1-15-88) ACUTELY HAZARDOUS MATERIALS REGISTRATION FORM THIS FORM MUST BE COMPLETED BY THE OWNER OR OPERATOR OF EACH BUSINESS IN CALIFORNIA WH]CH AT ANY TIME HANDLES ANY ACUTELY HAZARDOUS MATERIAL IN QUOS GREATER THAN 500 POUNDS, 55 GALLONS OR 200 CUBIC FEET OF GAS AT STP. THIS FORM SHALL BE COMPLETED AND SUBMITTED TO YOUR LOCAL ADMINISTERING AGENCY. (§25533 & 25536 Health & Safety Code) ~['~~~~/~""~s Note Instructions on r~v~r~ Name ARCO 0il and Gas Company /.: Business Site Address 4550 California Avenue, Bakersfield, CA 93309 [ Business Mailing Address (if different) Post 0ffice Box 145, Bakersfield, CA 93302 Business Phone (805) 321-4000 Business Plan Submission Date2 9/15/87 Process Designation3 Of fi ce ACUTELY HAZARDOUS MATERIAL~; HANDLED4 -USE ADDITIONAL PAGES IF NECESSARY- CHEMICAL NAME QUANTITY .~--~ Anhydrous Ammonia 6700 SCF GENERAL DESCRIPTION OF PROCESSES AND PRINCIPAL EQI, IIPMENTS: ...... Di-s'tri-¢l;- 0ffice ' --- ~ P-r-i-n¢-i'p'a~l-~Eq~i'~ Drawin(~ Reproduction Equipment PRINTED NAME Nancy B. Johahnesmeyer DATE Ma?ch 18, 1988 California Office of Emergency Services FORM HM 3777 (1-15-88) INSTRUCTION : Superscripts: 1. Quantities for RMPP compliance are "equal to Or greater than" the minimum criteria and apply to chemicals handled "at any one time". 2. Businesses handling reportable quantities of Acutely Hazardous Materials that have not submitted a business plan MUST contact local Administering Agencies. The business plan submission date will assure the Administering Agency that a business plan has been submitted and is on f'de. This will also immediately !dentify businesses that have not submitted bosiness plans. 3. "Process Designafion~ is provided as a reporting option (with the approval of the Administering Agency) for facilities that can most easily report by process. Thus, facility RMPP registration data could be submitted in a similar format to a business plan that is divided by process. "By process" data can initiate an emergency response to a process incident rather than a general emergency response to a major facility. Process designation can simplify inspections for major facilities and improve future emergency _response. 4. Refer to the EPA list of Extremely Hazardous Substances fxom the Federal Register (Volume 52, No. 77, p. 13397 et. seq_., April 22, 1987). Each chemical has a threshold planning quantity. This list may be changed by EPA on an annual basis. Updates of this list may be available early in 1988. To comply with this element, you may attach a copy of thc inventory submitted to your Administering Agency fxom your business plan and highlight all Acutely Hazardous Materials. It is recommended that facilities list all extremely haTardous chemicals handled in quantities equal to or in excess of 1) 500 pounds, and 2) any EPA threshold planning quantity less than 500 pounds. .. -~ 5. Do not include Trade Secret information in these descriptions General: For emergency response purposes, it would be desirable to describe the following to the Administering Agency: 1. Batch Process: a. Whatraw materials? b. What operating tnessure range? c. What ofx~g tem~ range? d. Batch capacity rating? e. Product characteristics? (e.g., chemical state, flammability, toxicity, etc.) f. Critical ~ points and characteristics? 2. Continuous process: (similar information as above.) NOTE: ._ "Pursuant to §25534, the Administering Agency may require the submission of a Risk Management Prevention Program (RMPP), if the Administering Agency determines that the handler's operation may present an acutely hazardous materials accident risk. The handler shall prepare the RMPP in accordance with subdivision (c) [of §25534]. The RMPP shall be prepared within 12 months following the request made by the Administering Agency pursuant to this section." (§ 25534 (a) Health and Safety Code) An amendment to the RMPP must be submitted to the Administering Agency within 30 days of: 1. Any additional handling of acutely hazardous materials. · 2. Any material or substantial alterations to business activities. 3. Change of address, business ownership, or business name. (§ 25533 (c) Health & Safety Code) · EVERY BUSINESS REQUIRED TO SUBMIT AN RMPP SHALL IMPLEMENT THE APPROVED RMPP · Califomia Office of Emergency Services FORM HM 3777 (1-15-88) . MEMOR,ANDUM ' "~WE CARE'"' ARCO Oil and Gas Company Environmental, Safety and Training ~O ,- Post Office Box 147 Bakersfield, California 93302 4550 California Avenue Bakersfield, California 93309 Telephone 805 321 4298 William J. Rosica Environmental Coordinator "q