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Home My WebLink AboutBUSINESS PLAN ' SITE/FACILITY DI AGRPu~¢ NORTH SCALE: BUSINESS N~E:d~{ ~ t~~~' FLO0~: OF UNIT ~: OF (CHECK ONE) SITE DIAGR~ FACILITY DIAGR~ ~ Inspector's Comments): -OFFICIAL USg ONLY- HMCU-13 ~ DIS I~IC~ 102-1 *~-*~'- *'~'~, COUNTY JURISTICTION SEC. 17, T. 29S.,R.29E. NORTH SCALE IN FEET ~9~- _ ....... -81- 02/20/92 CENTRAL LEASE INC 215-000-001183' Page 1 Overall Site with 1 Fac. Unit General Information I Locationf CALLOWAY LEASE Map: 102 Hazard: Minimal I Community: COUNTY STATION 65 Grid: 17A F/U: 1AOV: 0.0 Contact Name Title Business Phone 24-Hour Phoneq JAMES BITALL (805) 322-9402 x (209) 535-5135! MIKE UNSEL (805) 322-9402 x (805) 366-5197/ Administrative Data Mail Addrs: P O BOX 366 D&B Number: City: OAKVIEW state: CA Zip: 93022- Comm Code: 215-065 COUNTY STATION 65 SIC Code: Owner: CENTRAL LEASE Phone: (800) 640-0645 Address: P O BOX 366 State: CA City: OAKVIEW Zip: 93022- Summary RECEIVED MaR 1 1 992, HAZ. ~,~T. DIV. ~.'~a~,~--~c~T'~ Do. hereby certify that I h~e Uy~ ~ ~e) ' reviewed ~he a~ached h~zardous minerals manage- ment plan ~or~~ ,,,~~nd ~ha~ i~ aiong wi~h any ~rmcJions constitute a complete and ~rrect man- agement plan for my facility. 02/20/92 CENTRAL LEASE INC 215-000-001183 Page 2 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-001 CRUDE OIL Liquid 45000 Low · Fire, Delay Hlth GAL i~o;~ ~ CAS #: 8002059 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: OTHER Daily Max GAL I Daily Average GAL I Annual Amount GAL 45,000 ~ 22,500.00 531,000.00 St6rage IIPress T Temp Location ABOVE GROUND TANK IAmbient~AmbientlSE PRODUCTION TANK -- Conc Components MCP List 100.0% Icrude Oil ILow I 02-002 CRUDE OIL Liquid 90000 Low · Fire, Delay Hlth GAL CAS #: 800205.9 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: OTHER Daily Max GAL I Daily Average GAL ] Annual Amount GAL 90,000 ~ 45,000.00 '531,000..00 ~Storage ~~Press l Temp Location ABOVE GROUND TANK IAmbientlAmbientlE SIDE MIDDLE TANK -- Conc Components MCP List 100.0% ICrude Oil ILow 02-003 MOTOR OIL Liquid 75 Minimal · Fire, Delay Hlth GAL CAS #: 8020835 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: LUBRICANT Daily Max GAL75I~ Daily Average35.00GAL [ Annual Amount200.00GAL -- Storage ~ Press T Temp~ Location DRUM/BARREL-METALLIC IAmbient~AmbientlBY GAS ENGINE -- Conc Components ~ MCP · List 100.0% IMotor Oil, Petroleum Based IMinimal I 02/20/92 CENTRAL LEASE INC 215-000-001183 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-004 MAROK Ice 68 UNOCAL Liquid 75 Minimal · Fire, Delay Hlth GAL CAS #: 8020835 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: LUBRICANT Daily Max GALI Daily Average GAL I Annual Amount200.00GAL 75 ~ 35.00 StorageIIPreSs T Temp Location DRUM/BARREL-METALLIC IAmbient~AmbientlBY GAS ENGINE -- Conc Components MCP List 100.0% IMotor Oil, PetroleUm Based Minimal I CA~ #: Trade Secret: No ! F~m: Liquid Type: Mixture Days: 365 Use: WATER TREATMENT ~--~-- Daily Max GAL , Daily Average GAL ! Annual Amount GAL -- 'V~' ~ 55I 25.00~ 200.00 Location Storage IIPress I Temp DRUM/BARREL-METALLIC IAmbient~AmbientlBY WATER TANK -- Conc Components MCP List 5.0% IAmmonium Chloride ILow I 02/20/92 CENTRAL LEASE INC 215~000-001183 Page 4 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification <2> Employee Notif./Evacuation THIS FACILITY IS A CRUDE OIL TANK FARM WERE PEOPLE ONLY WORK FOR A FEW MINUTES ~TO A FEW HOURS EACH DAY. THERE ARE SIGNS POSTED WITH EMERGENCY PHONE NUMBERS IN CASE OF A SPILL WHEN AN EMPLOYEE ~IS NOT PRESENT. <3> Public Notif./Evacuation <4> Emergency Medical Plan WE WORK FROM EDISON GROVES TO ROSEDALE TO MARICOPA. THEREFORE EMERGENCY MEDICAL WOULD BE REFERRED TO THE CLOSED HOSPITAL. BAKERSFIELD'MEMORIAL HOSPITAL 420 34TH ST 327-1792 ~ 02/20/92 CENTRAL LEASE INC 215-000-001183 Page 5 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention <2> Release Containment / <3> Clean Up <4> Other Resource Activation 'l 02/20/92 CENTRAL LEASE INC 215-000-001183 page 6 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards CONTINUOUSLY RUNNING WATER INJECTION PIJMP OPERATED OFF PRODUCED NATURAL GAS. <2> Utility Shut-Offs A) GAS - AT WELL HEADS B) ELECTRICAL - NORTHWEST CORNER OF TANK FARM C) WATER - NONE D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - ????????????? FIRE HYDRANT - ????????????? <4> Building Occupancy Level 02/20/92 CENTRAL LEASE INC 215-000-001183 Page 7 00 - Overall Site <G> Training <1> Page 1 WE HAVE~?? EMPLOYEES AT THIS FACILITY ~t ). DO YOU HAVE MATERIAL SAFETY DATA SHEET$~ON FILE? <2> Page 2 as needed <3> Held for Future Use ? <4> Held for Future Use BAKERSFIELD CI/W FIRE DEPARTMENT 2130 "G" S~EET (sos) 32s-ss 9 OFFICIAL USE ONLY 00118$ HAZARDOUS gTERI ALS BUSINESS PL~ AS A WHOLE FORM 2A 1. To avoid further action, return this form by 2. ~E/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a ~hole. 4. Be as brief and concise as possible. SE~ION 1: BUSI~SS ID~IFICATION DATA LOCATION / STREET ADDRESS: CI~: A~ ~r; ~,, e%~ ZIP: SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency ,involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local f, ire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: N~ME AND TITLE Db"RING BUS. HRS. AFTER BUS. HRS. B. ~:~ (A,~ Ph~ ~%~to~ Ph~ a~tq7 SECTION 8: LOCATION OF UTILI/~f SHUT-OFFS FOR BUSINESS AS A WTIOLE ~ - ~ ,~ ~,~ A. NAT. GAS/PROPANE: B. ELECTRICAL: C. WATER: D. SPECIAL: E. LOCK BOX: YES / NO IF YES, LOCATION: IF YES, DOES [T'CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / ~0 KEYS? YES / NO - 2A - SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE SECTION 5: LOCAL EMERGEN~ MEDICAL ASSIST~%;CE FOR YOUR BUSINESS AS A WHOLE SECTION 6: EMPL0%~E TF~%INING EMPL0~ERS ARE REQUIRED TO F~4VE A PROGRb~M WHICH PR0VIDES ]LMPL0~1~ES WITH INITI.JJ~ .%\~ REFRESh"ER TI~INING IN THE FOLLOWING AREAS. CIRCLE YES 0R NO INITIAL REFRESHER A. METHODS FOR SAFE F~ANDLING OF HAZARDOUS MATERIALS:.. ' I .................................... B. PROCEDURES FOR COORDINATING ACTIVITIES wi/q{ RESPONSE AGENCIES: ......... ~ ................ ~t~_S: NO (~S~J N0 C. PROPER USE OF SAFE~ EQUIPMEL-r: .................. ~- NO~._ NO D. EMERGENC~L EVACUATION PROCEDURES: ................. E. DO YOU ~5%INTAIN EMPLOYEE TRAINING RECORDS: ....... YES ~ YES NO SECTION 7: HAZARDOUS CIRCLE YES OR NO DOES YOL~ BUSINESS HA~LE HAZARDOUS ~TERIAL I~ QUANTITIES LESS THAN 500 POL~DS OF A SOLID, SS GALLONS OF A LIQUID, OR Z00 CUBIC FEET OF A COMPRESSED GAS: ..... YE~__~S NO I, ~,.~ ~,¥1~\\ . , certify that th~ above information is accurate.' I understand that this information will be used to fulfill my firm's obliMations under the new California Health and Safety code on Hazardous Materials (Div. Z0 Chapter 6.95 Sec. ZB~00 E~ Al.) and that inaccurate information constitutes perjury. - 2B - BAKERSFIELD CiTY FIRE 21S0 "G" STREET BAKERSFIELD, CA 9S301 OFFiCiAL US£ Oh'LY BUSINESS NAME: BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must' be returned 2. TYPE,/PRI~T YOUR ANSWERS IN ENGLISH, 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. FACILITY UNITe S FACILITY b~'IT NAME: detL(o~o~_~ L¢~ SECTION 1: MITIGATION~ PRE~%k~iON~ ABATEMEh% PROCEDb~ES SECTION 3: HAZARDOUS MATERIALS FOR THIS b~'iT ONLY A. Does this Facility Unit contain Hazardous Mater~a!s? ...... ~NO If YES, see B. If NO, continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES NO If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form ~4A-1) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form ~4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-~. SECTION 4: PRIVATE FIRE PROTECTION SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS SECTION 6: LOCATION OF UTILI~ SHUT-OFFS AT THIS UNIT ONLY. A. NAT. G.4S./PROP.:tNE~ B. ELECTRICAL: C. WATER: D. SPECIAL: E. LOCK BOX: YES ' NO IF YES, LOCATION IF VES, SITE PLANS? YES / NO ;x'~SD,C.,~9 YES ¥0 FLOOR PLANS? YES ./ NO !<E¥So YES - 3B - N0'N--TRADE sECRETS HAZARDOUS MATERI ALS · INVENTORY ONLY i'YPl~ HAX ANNIIAI, CONT USE LOCATION IN Tills ~ BY ilAZARD D.O.T ~;()I)E AMOUNT AMOUNT UNIT CODE CODE FACIL,,~TY UNIT WT. UIIEMI~AL OR COMMON NAME CODE GUIDE BAKERSFIELD CITY FIRE DEPARTMENT -,~ I.D. ~ FORM 4A-2 page 0'f TRADE SECRETS ,~. HAZARDOUS MATERI ALS INVENTORY ~ BUSINESS NA~IE: ~-~-~r~.~' L~c,~(.-~,, OWNER NA~IE: ~_~,~,~-~,_~ ~ ~, FACILITY UNIT ~: ~ ADDRESS:~:~',~c. ~,,,~ ¢~. ~:~ ~,~~ ~,,~.~ ADDRESS: ~p:~ ~ '~..~'~,~,k ~ ~,,~ FACILITY UNIT NAME:~e~ ~. CITY ~IP:~.~.~,. ~ ~ -' ~ PHONE ~: ,,~ ~¢. PHONE ~: ~-~ ff~ ~:. O~FICIAL USg CFIRS CODS 1 2 3 4 5 6 7 8 9 ~0 TYPB ~AX ANNUAL COXT USS LOCATIOX IR T~IS % BY ~A~ARD D.O,T c,,ODB ANOUNT ANOU~T UNIT CODE CODE FACILITY UNIT WT. C~B'~ICAL OR CO~ON NA~B .COD~ GUIDE NA~E: TITLE: SIGNATURE: DATE: BNERGENCY CONTACT: TITLE: PHONE ¢ BUS HOURS: ', AFTER BUS HRS: EMERGENCY CONTACT: TITLE: PHONE ~ BUS HOURS: PRINCIPAL BUSINESS ACTIVITY: ", ~ AFTER BUS HRS: - 4A-2 - PRODUCT FORMULATION DISCLOSURE PRIVATE AND CONFIDENTIAL PRODUCT INGREDIENT PERCENTAGE OR RANGE AQUA SURF 702 Non-Ionic Quaternary 25 - 35 % ~Jo ~d c~ ~ Ammonium Chloride ~13~1 i IRA 5 % ~ HAZARD CLASS : COMBUSTIBLE LIQUID N. .S. /...,AQUA FLOC 428 CATIONIC COPOLYMER 25 - 35 % ~c_~.~ U N NO N/AP HAZARD CLASS : NOT REGULATED AQUA HIB 324 High Molecular Weight Amines 35 - 45 % ~ o ~.~-~ · IRA 10 % U N No. : UN-1993 HAZARD CLASS : FLAMMABLE LIQUID NI.O.S. AQUC FLOC EXP-I ANIONIC POLYMER 25 - 35 % .... ~:~/? U N NO. : N/AP ,~ HAZARD CLASS : NOT REGULATED MATERIAL SAFETY DATA SHEET PACE CHEMICALS 10/20/87 PRODUCT NAME: BREAX/T 1513 7-1513 NO. 71513000 SECTION VII TYPICAL PHYSICAL & CHEMICAL PROPERTIES BP. GRAVITY REF. TEMP., P VAPOR PRESSURE mmHeat 1.08 @ 60.0 75 ~ 190 ~alculated DENSITY, lbs/gal: 8.65@ 60 SOLUBILITY IN WATER, WT. % at F VISCOSITY OF LIQUID, cST at F Soluble 7 @ 100 Cannon-Fenske SP. GRAVITY OF VAPOR, at 1 ATM AIR=I :REEZING MELTING POINT/RANGE, F 1.OO 32 Pour Point EVAPORATION RATE, n-BU ACETATE=I BOILING POINT/RANGE, F 2.000 Calculated 206 Calculated IBP SECTION VII! REACTIVITY DATA ;TABILITY7 HAZARDOUS POLYMERIZATION OCCUR? Stable Will not occur CONDITIONS TO AVOID INSTABILITY CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION None Not applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY Strong Oxidizing Agents HAZARDOUS DECOMPOSITION PRODUCTS None SECTION IX TRANSPORT AND STORAGE ELECTROSTATIC ACCUMULATION HAZARD Unknown, use proper grounding procedure STORAGE TEMPERATURE, F ILOADING/UNLOADING TEMPERATURE, F Ambient I Ambient STORAGE/TRANSPORT PRESSURE mmHg IVISCOSITY AT LOADING/UNLOADING TEMPERATURE,cST I Atmospheric ~ Not available SECTION X HAZARD CLASSIFICATION U.S. DOT CLASSIFICATION IEPA HAZARDOUS SUBSTANCE AMOUNT LBS. Combustible Liquid . Methyl Alcohol 99999 I ADDITIONAL INFORMATION Under the provisions of Title III, Sections 311/312 of the Superfund Amendments and Reauthortzatton Act, this .product is classified into the following hazard categories: Immediate Health, Delayed Health. REFERENCE NUMBER [DATE PREPARED ISUPERCEDES ISSUE DATE HDHA-A-10394 OCTOBER 20, 1987 SEPTEMBER 18,1987 FOR ADDITIONAL PRODUCT.INFORMATION CONTACT YOUR TECHNICAL SALES REPRESENTATIVE FOR ADDITIONAL HEALTH/SAFETY INFORMATION CALL 713-870-6885 ATERIAL D TA E, ON SAFETY. 'SHEET PAGE 3 CHEMICA~ 10/20/87 PRODUCT NAME: BREAXIT 1513 7-1513 N0.71513000 Eliminate sources of ignition, Prevent additional discharge of material, if possible to do so without hazard. For small spills implement cleanup procedures; for large spills implement cleanup procedures and, if in public area, keep public away and advise authorities. Also, if this product is an EPA hazardous substance (See Section X, Page 4) notify the U.S. EPA if appropriate. Vapors/dUst can be harmful/fatal. Warn occupants of downwind areas. Prevent liquid from entering sewers, watercourses, or low areas. Contain spilled liquid with sand or earth. Recover by pumping or with a suitable absorbent. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. WATER SPILL Prevent additional discharge of material, if possible to do so without hazard. Advise authorities. Eliminate sources of ignition. Vapors/dust can be harmful/fatal. Warn occupants and shipping in downwind areas. Consult Health Information and Protection (Section III) regarding possible hazards Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SECTION VI NOTES No notes applicable. IVIATER L SAFETY DATA S ET .^GE 2 CHEMICALS 10/20/87 PRODUCT NAME: BREAXIT 1513 7-1513 N0.71513000 INGESTION: If swallowed, and INDIVIDUAL IS CONSCIOUS, induce vomiting. Get prompt medical attention. DO NOT attempt to give anything by mouth to an unconscious person. The principle hazard of methyl alcohol arises from its ingestion as a substitute for ethyl alcohol. As little as 15 ml (1/2 oz.) of 40% methyl alcohol has caused death. The most significant systemic effect caused by sublethal doses of methyl alcohol is the damage to the optic nerve which can result in permanent visual changes, loss of vision or total blindness. PERMISSIBLE EXPOSURE LIMIT; OSHA REQUIRES (29CFR1910.1000): a TWA of 200 ppm (260 mg/m3) for Methyl Alcohol (skin). THRESHOLD EXPOSURE .LIMIT; ACGIH RECObIHENDS: a TWA of 200 ppm (260 mg/m3), and a STEL of 250 ppm (310 mg/m3) for Methyl Alcohol (skin). PERSONAL PROTECTION For open systems where contact is likely, wear chemical resistant gloves, rubber boots, a chemical jacket, chemical goggles, and a face shield. Where contact may occur, wear.long sleeves, chemical resistant gloves, and a face shield. All contact should be avoided by persons with known hypersensitivity to AMINES Where concentrations in air may exceed the limits given in this Section and engineering, work practice or other means of exposure reduction are not adequate. NIOSH/MSHA approved respirators may be necessary to prevent overexposure by inhalation. VENTILATION The use of mechanical dilution ventilation is recommended whenever this product is used in a confined space, is heated above ambient temperatures. or is agitated. SECTION IV FIRE & EXPLOSION HAZARD FLASHPOINT DEG. F : 210 METHOD: Sera CC NOTE: Greater than FLAMMABLE LIMITS-LEL: UEL: NOTE: Not applicable AUTOIGNITION TEMPERATURE DEG. F : NOTE: Not available GENERAL HAZARD Low Hazard, liquid can burn upon heating to temperatures at or above the flashpoint. Toxic gases will form upon combustion. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld or expose containers to flame or other sources of ignition. FIRE FIGHTING Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel" supply from fire. Use alcohol type foam, dry chemical or water spray to extinguish fire. Respiratory and eye protection required for fire fighting personnel. HAZARDOUS COMBUSTION PRODUCTS Smoke, Fumes, Carbon Monoxide, Carbon Dioxide ~;FCTION V SPILL CONTROL PROCEDURE LAND :SPILL MA ERIAL DATA'SHEET -' E ON ' SAFETY ../ ~. PAGE 1- EXXON CHEMICAL AMERICAS · P.O. BOX 3272, HOUSTON, TEXAS 770{~"t ' / · ~'*~ ~ "~' - CHEMICA~ 10/2078~ division of EXXON CHeMiCAL COMPANY, = division o, EXXON :O,PO,A~ION " : ....... ='~0. 7'1 SECTION I PRODUCT IDENTIFICATION & EMERGENCY INFORMATION PRODUCT NAME BREAXIT i5i3 ?-1513 CHEMICAL NAME Not applicable: Blend CHEMICAL FAMILY Amine PRODUCT APPEARANCE Dark Amber Liquid Mild Odor EMERGENCY TELEPHONE NUMBERS: EXXON CHEMICAL AMERICAS 713-870-6000 CHEMTREC 800-424-9300 SECTION II.__ HAZARDOUS COMPO.NENTS OF MIXTURES THE PRECISE COMPOSITION OF THIS MIXTURE IS PROPRIETARY INFORMATION. A MORE COMPLETE DISCLOSURE WILL BE PROVIDED TO A PHYSICIAN OR NURSE IN THE EVENT OF A MEDICAL EMERGENCY. THE FOLLOW[NC COMPONENTS ARE DEFINED HAZARDOUS IN ACCORDANCE' WITH 29CFR1910. 1200: OSHA HAZARD COMPONENT Eye Irritant Alkyl Quaternary Salt Toxic Methyl Alcohol: via Ingestion, Inhalation PEL/TLV .l~et hy l Alcohol For additional information see Section III. SECTION III HEALTH INFORMATION AND PROTECTION FIRST AID & NATURE OF HAZARD EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get prompt medical attention. Irritating, and will injure eye tissue if not removed promptly. SKIN CONTACT: Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. If irritation persists, seek medical attention, Methyl alcohol may be absorbed through the skin which can contribute to damage of the optic nerve resulting in permanent visual changes, loss of vision or total blindness. May cause skin sensitization, an allergic reaction which becomes evident on reexposure to this material. INHALATION: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration if breathing is stopped. Keep at rest. Call for prompt medical attention. High vapor concentrations are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anesthetic and may have other central nervous system effects. This product contains methyl alcohol. Vapor inhalation and/or skin absorption can cause central nervous system effects and blindness. THIS INFORMATION RELATES TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF OUR KNOWLEDGE AND BELIEF, ACCURATE AND RELIABLE AS OF THE DATE COMPILED. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARANTEE IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBILITY TO SATISFY HIMSELF AS TO THE SUITABILITY AND COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE. WE DO NOT ACCEPT LIABILITY FOR ANY LOSS OR DAMAGE THAT MAY OCCUR FROM THE USE OF THIS INFORMATION NOR DO WE OFFER WARRANTY AGAINST.PATENT ~NFRINGEMENT. ~ ~, MATERIAI~BAFETy DATA SHEET PRODUCT I VI-SEP 716 ~31SION BREAKER NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION I PRODUCT IDENTIFICATION TRA~E NAME: VI-SEP 716 ~3LSIC~ ~FAKER ~o~~ [~ 2~~ o~~ o~ ~iCfi~t l~liCt 2~~ 3~¢ 4=~ ~ECTION 2 ~AR~U~ INGREDIENTS .~ ~tic ~~ 64742-94-5 4~ SECTION 3 PRECAUTION~Y ~BEL INFO~TION SECTION 4 FIRST AID I~O~TION PAGE 1OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER · NAPERVILLE, ILLINOIS 60566-1024 AREA 312-961-9500 MATERIAL SAi~[TY DATA SHEET~ IPRODUCTVI-SEP 716 'E~JLSION BREAKER NALCO' Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 5 HEALTH EFFECTS INFORMATION mmmU~ ~nm(s) OF ~: .Eye, Skin, Umalati~ INHAIATIC~: Prolonged inhalation of vapor may be harmful. ~ OF EXPOSURE: ACUTE: Inhalation of high concentrations of heavy aromatic naphtha can cause nausea, dizziness, v~miting, stupor or unconsci~. (31~ONIC: Prolonged skin contact can cause dry skin and defatting resulting in irritation end dermatitis. AGGRAVATION OF EXISTING OOND~: A Z-eview of available data does not identify any ~rsenin~ of existing conditions. SECTION' 6 TOXICOLOGY INFORMATION AOJTE TOXICITY STUD~: No toxicity studies have been ~ on this product. SECTION ? PHYSICAL AND CHEMICAL PROPERTIES COLOR: Yellow ~ORM: Liquid ODOR: H2~zocafoc~ SOI//BILITY IN ~ER: Dispersible sP~L~c ~AVn~: 0.92 @ 60 De~mes F ~a CroaT) =. 5.7 k~m E-70 'vIscos~: 16 'cps/17 cts/87 sus @ 60 De~rees F AS~ D-445 ~ ~OINT: Less than -25 De~rees F AS~4 D-97 FLASH POINT: 131. Decjrees F (PF~CC) AS~4 D-93 VAPOR PRESSURE: 18 ~m H~ @ 100' Degrees F AS~/4 D-323 BY WEIGHT: 1 @ 75. Degrees F NOTE: ~ese ~]si~ properties are typical values for. this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 131 Degrees F (PMOC) AS~M D-93 alcohol foam, carbon dioxide or other extin~H~ agent suit~_ble for Class B fires. Use water to cool containers exposed to fire. For pA~E 2 OF 8 NA/CO CHEMICA1 COMPANY ONE NALCO CENTER · NAPERVILLE, ILLINOIS 60566-1024 AREA 312-961-9500 ~ ~ MATERIAI~iSAFETY DATA SHEET PRODUCT VI-SEP 716 ~JLSION ~REAKER NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED large fires, use water spray or fog, thoroucjhly dr~ the burning' SECTION 9 REACTIVITY INFORMATION IN~ATIBILITY: Avoid contact with strong oxidizers (eg. chlorine, peroxi~, chromates, nitric acid, perchlorates, concentrated oxygen, ~ermanga~ates) which c~_n generate heat, fires, explosions and the release of toxic fumes. THE~4AL ~ITI~N PRODUCl~: In 'the event of ccmgamtion CO, 002 may be formed. Do not breathe smoke or fumes. Wear suitable SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally ~ed, If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a p . , self~nta/ned breathing apparatus is recurS. VENTIIATION: General ventilation is recommended. Nktitionally, local e~aust veatilati~ is ~nde~ ~here vaDors, mists or aerosols P~3i~3~'IVE ~I~T: Use ~ble gloves and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc. ) when attaching feeding equipment or doing maintenance. If clothing is contaminated, remove cl~ and thoroucjhly wash'the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPOREATION A~, C~TL ~E FOLLOWING 24-}K~3R' T~R~E ~ (312-920-1510) SPTT~. OC~TROL AND RECOVERY: Small liquid spills: Contain with absoft material, such as clay, PAGE 3OF 8 HALCO CHEMICAl. COMI~ANY ONE NALCO CENTER · NAPERVILLE, ILLINOIS 60566-1024 AI~EA 312-961-~500 MATERIAL SAI IITy.. DATA SHEET, I PRODUCT v[-s~ 716 ~ION :EilRF_A,~ NALCO Emergency TelePhone Number Medical (312) 920-1510 (24 hours) SECTION 11 8PILL AND DISPOSAL INFORMATION ( CONTINUED soil or any ccm~rcially available absorbent. Shovel recla/med liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA i~ Sectic~ 14. Iarge liquid spills: 'Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA i~ Secticml 14. For large indoor spills, evacuate employees and ventilate area. ~ose responsible for control and recovery should wear the protective equi~_nt specified in Section 10. DIsPOSAL: If this product becomes a waste, it meets the criteria of a Recovery Act (RCRA) 40 CFR 261. Hazardous Waste D001. As a hazardous liquid waste, it must be solidified before disposal in a landfill (Hazardous Waste Treatment,. Storage and. Disposal facility). SECTION 1~ EI~IRONI~I~AI'. INFORI~ATION SECTION J.~ REOUI.~TOR¥ INFOR.}~TTON ~ foll~Sr~ r~:juht'ions apply to ~ Based on cx~.r ha~.ard ~4.uat±en, th~ foll~,incj ~m in ~ Heavy a~-o~atic naphtha - Skin irritant, cc~le Naphthalene- Irritant PAGE 4OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER · NAPERVILLE. ILLINOIS 60566-1024 AREA 312-961-9500 ,~ ~ MATERIAIL~iAFETY' DATA SHEET IPRODUCT VI-SEP 716 ~3LSI(IN ~2~Q%KER NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION .14 REGULATORY INFORMATION ( CONTINUED ') Naphthalene = TWA 10 pFa, STEL 15 p~a ACGI~VTLV 50 m~ 75 m~ AO~V Naphthalene = PEL 10 p~a, 50 rog/m3 0SHA/TLV Heavy arca~tic naphtha = TWA 100 p~a TLV Manufa~' s CERCIA/SUPERFUND, 40 CFR 117, 302: ~-~ product con~_~ns naphthalene, a Reportable Quantity (RQ) substance and if 10,000 pounds of product are released, it requires notification to the NATIC~AL RESPONSE CENTER, ~FINGIC~, D. C. (1-800-424-8802). SARA/~ ~ AND ~ZATI(~ ACT OF 1986 (TITiE III) - SECTI(X~S 302, 311, 312 AND 313: Urzler Section 311, su~aittal of MSE~'s or a list of product emergency ~ commission ar~ local fire department is required after October 17, 1987 if you have: - 10,000 pounds or more of a hazardous substance, or - 500 pounds or the threshold planning ~,~_ntity, whichever is less, of an extremely hazardous substance. After October 17, 1989, MSDS(s), or a list of product names for all .ham~d~m ~ ~~ zero (0) and 10,000 p~nds, SECTION 302 - ~.v HAZARDOUS SUBSTANCES. (40 CFR 355): ~ product does not c~ntain ingredients listed in Appendix A and B as an Extreme___~ly Hazardous Substance. (40' CFR 370): ~he product should be reported under the following EPA hazard categories: ' XX Immediate (acute) health hazard --Delayed (chronic) health hazard xx Fire hazard PAGE 5 OF 8 NALCO CHEMICAL COMI~ANY ONE NALCO CENTER · NAPERVILLE. ILLINOIS 60560-1024 AREA 312-961-9500 MATERIAL SAi~TY DATA SHEET, ~RODUCT VI-SEP 716 ]~4D~-SI~ NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION L4 REGULATORY INFORMATION ( CONTINUED ) -- ~en release of p~ hazard S]DC'ITON 313 - f,I~/~ OF TOXIC (]{]~4ICALS (40 CFR 372): ~ds product contains naphthalene, which appear(s) on the List of Tc~ic Chemicals. TOXIC SuBSTANC~ ~L ACT (TSCA): ~he chemical ingredients in this product are on the 8 (b) Inventory List. (40 CFa 710). RESOURCE OC~S~~ AND RE(/)VERY ACT (RCRA), 40 CFR 261 SUBPAR~ C & D: If this product becomes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). FEDERAL HATER poLIU~ON ~L ACT, CLEAN HATER ACT, 40 CFR 401.15 (fozmerly Sec. 307), 40 CFR 116 (formerly Sec. 311): ~ ~ contains the foZZ~4_ng ing~dient(s) covered by "the Naphthalene - Section 307, 3ZZ cr~AN AIR ACT, 40 CFR 60, SECTIC~ 111, 40 CFR 61, S~FCTZCI~ 112: CALI~C~gIA PR0t~GITIC~ 65: . ~ts p~ ~zi~ w~th ~he mm ~ zm~zin~ re~Lre~n~ of the Drinking Water And Toxic Enforcement Act of 1986 (Proposi~on 65). Regulated in those states using the TLV for nat~hthalene as a criteria for listing. SECTION ~5 ADDITIONAL INFORMATION None PAGE 6OF 8 NALCO CHEMICAL CONII~ANY ONE NALCO CENTER · NAPERVILLE, ILLINOIS 60566-1024 AREA 312-961-9500 , ,, MATERIA~ISAFETY DATA SHEET PRODUCT VI-SEP 716 ~ULSION NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) 8ECTION 16 USER~8 RESPONSIBILITY ~ product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product Should be informed of the ~_ed safety precautions and should have access so that appropriate ~ir~ practices and training programs can be est_~blished to ensure safe w~rkplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPOR~ C~ CARCIA~X~S, U.S. Department of Health and Human Services, B/blic Health Service, PB 33-135855, 1983. CASARETT AND DOULL'S TOXIOOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., . Klaassen, C. D., and Admur, M. O., eds., Macmillian Publ~ing Company, Inc., N. Y. ,. 2nd edition, 1980. O~ICAL HAZARDS OF ~E WORKPIACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipincott COmpany, N.Y., 1981. D~ PRO~ OF ~ MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC ~ ON ~E EVAI//ATIC~ OF ~E CA~IR~0G~C RISK OF ~ICAIS TO MAN, Geneva: World Health Organization, International Agency for ~esea~ on Car~er, 1972-1977. PAT~,S n~u~aUaL mGnmE ~D TOXI~U~, ~ay~m, G. D., ~a~, F. E., eds., Jc~l~ Wiley and Sc~s, N. Y., 3rd edition, Vol. 2 A-C, 1981, R~GISTR~ OF TOXIC ~'~'~ ON (:~4I~ SUBSTANCES, U.S. De~ of Health and Human Services, Public Health Service, Center for Disease Oontrol, National Institute for Oco/pational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, C~, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic ar~ Hazardous Substances, OccupatiOnal Safety and Health ~tion (OSHA). WORKRO(~ ~ ~ INTENI~D C~N~ES, American Conference of PAGE 7 OF 8 NALCO CHEMICAl. COMPANY ONE NALCO CENTER · NAPERVILLE. ILLINOIS S0566-1024 AREA 312-~161-9500 MATERIAL SAIF~'Y DATA SHEET, . PRODUCT I VI-SEP 716 ~JLSI~ ~REAKER NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 17 BIBLIOGRAPHY ( CONTINUED ) DATE C:-]ANGED: 0'1/~2/88 ~ PRINTED: 02/26/88 , · PAGE 8 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER · NAPERVILLE. ILLINOIS 605'66-1024 AREA 312-91~ 1-~)500 MATERIA SAFETY DATA SHEET PRODUCT VI-SEP 716 ~ULSION ~EAKER NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION i PRODUCT IDENTIFICATION TRABE NAME: VI-SEP 716 ~4D'iSIC~ ~REAKER E~RIPI~/O~: A bl~ of ~la~ ~e~ ~ ~la~ ~ h~' ~A70~~ 1~ 2 ~ 0~~ 0~ ~i~fi~t l~li~t 2~~ 3~ 4=~ SECTION 2 ~ZAR~UB INGREDIENTS ~ ~ ~ti~ ba~ i~ifi~ ~e foll~ ~~ ~~t(s) ~ ~z~ ~ ~'s ~z~ ~~ti~ ~e, 29 ~ 1910.~00. ~t S~ion 14 for ~e ~ of ~e ~z~(s). % ~ ~tic ~~ 64742-94-5 4~ N~~~ 91-20-3 1-10 SECTION '3 P~CAUTION~Y ~BEL INFO~TION ~: ~ ~i~ ~ ~ ~ eye. ~t~le. ~1~ ~a~ of ~rmy~~. ~ ~ get ~ ~, ~ ~, or ~ clX. ~ ~1~ or fa~ ~d~~~. A~id p~l~ or ~~ b~~ of ~r. U~ ~ ad~ v~ati~. ~ ~ ~ ~ly. ~p a~y f~~t ~ ~ ~ ~ly ~~. SECTION 4 FIRST AID I~O~TION ~ ~~ for ~ ~. ~1 a~ici~. ~ ~ ~ for ~ ~. ~~:~ ~ ~~t~. Gi~~. ~la ~ic~. ~~:~e ~ ~ ~. '~t ~. ~1 a ~ici~. ~ ~ ~SI~: No ~ific ~tid~ ~ ~. ~ ~ ~ ~vi~ ~i~ of ~e ~ti~, ~e ~ici~'s j~ ~d ~ ~ ~ ~n~l ~ ~ cl~ ~tion. ~~: If ~i~, ~v~ ~le b~~ or ~ ~sio~, ~ ~ ~ v~t~ or give ~. PAGE 1 OF '8 NALCO CHEMICAL COMFIANY ONE NALCO CENTER · NAPERVILLE, ILLINOIS 60566-1024 AREA 312-961-9500 MATERIAL SAIF TY DATA SHEET IPRODUCT VI-SEP 716 ~V[JLSION ~EAKER NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION I PRODUCT IDENTIFICATION TRADE NAME: VI-SEP 716 ]~4DISION ~EAKER DESCRIPI~C~: A blend of .c~lated esters ar~ oxyalkylates 'in heavy arc ati¢ tha NFPA 704M RATING 1 ~ 2 FIAMMABITETY 0 REACITVITY 00%/qER O=Insignificant l~light 2=Moderate 3=High 4=Extreme SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation bas identified the follc~in~ chemical ingredient(s) as hazardous under OSHA's Hazard O~r,,runication Rule, 29 CFR .1910.1200. Consult Section 14 for the nature of the hazard(s). n REDnmT (S) # APmOX. % Heavy a-~matic naphtha 64742-94-5 40+ ' Na~hthalene 91-20'3 1-10 SECTION 3 PRECAUTIONARY LABEL INFORMATION t~U~DlqG: 'Causes irritation to skin and eyes. Combustible. Prolonged inhalation of vapor may be harmful. Do not get in eyes, on skin, or on cloth/n~. Wear goggles or face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away frc~ heat and open unless properly recond/ti _one~__. SECTION 4 FIRST AID INFORMATION EYES: Flush with water for 15 minutes. Call a physician. SKIN: Flush with water for 15 m/nutes. ~C~: .Do not ~ Vc~i~. Give water. Call a physician. INHAIATION: .Remove to fresh air.. Treat symptc~s. Call a physician. NOTE TO PHYSICIAN: No specific antidote is known. Based on the indivi~a~ reactions of the patient, the.physician's judgment should be used to'control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, 'do not ~ vomiting or give water. PAGE .1 OF 8 NALCO CHEMICAL COMPANY ONE NALCO CENTER · NAPERVlLLE. ILLINOIS 60566-1024 AREA 312-961-9500 MATERIA~SAFETY DATA SHEET VI-SEP 716 ~3L~I~N ~EAKER NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 8 FIRE ]%ND EXPLOSION INFORMATION ( CONTINUED ) SECTION 9 REACTI~;ITY INFORMATION INCCNPATIBILITY: Avoid contact with strong oxidizers (eg, chlorine, peroxides, chroma~, nitric acid, perchlorstes, concentrated oxygon, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. ~ DECCNP0SITION PROUJCi~: In the event of combustion 00, ~02 may be formed. Do not breathe smoke or fumes. Wear suitable ;~ctive e~uip~nt. SECTION 10 PERSONAL PROTECTION EQUIPMENT P~cded. If significant, vapors, mists or aerosols are general, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressu~, self-~onta~ breathing apparatus is recommended. VENTIIATIC~: General ventilation is ~. Additic~mlly, local exhaust ventilation is ~cm~a~ded where vapors,, mists or aeroso~ PROTECTi~E ~i~r/PMENT: Use imperme___eble glOVes and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc. ) when attach~ feeding equipment or doing maintenance. If clothing is contaminated, remove clothi~ and thorny wash the affected ·area. Launder contaminated clot~ before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANS~Q~ A~, C~T,T, ~ FO~ 24-~ T~m~E NUMAR (3~2~510) sP~;. C~mOL AND ~: Small liquid spills: Contain with absorbent material, such as clay, PAGE 3 OF 8 NA~.CO CHEMICAl- COMI=ANY ON5 NALCO CSNTSF~ · NAPSRVIL~5. I~UNOIS 6056~-1024 MATERIAL SAIF~rY DATA SHEET~,, .. I PRODUCT ~ I VI-SEP 716 ~4ULSION ~EAKER NALCO Emergency Telephone Number .Medical (312) 920-1510 (24 hours) SECTION 8 FIRE AND EXPLOSION INFORMATION ( CONTINUED laxcle fires, 'use water spray or fog, tho~y ~ the burning SECTION 9 REACTIVITY INFORMATION INOC~4PATIBILITY: Avoid contact with stror~ oxidizers (e~. chlorine, ~roxides, chromates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. may be formed. Do not breathe smoke or fumes. Wear suiteble protective equipment. SECTION 10 pERSONAL 'PROTECTION EQUIPMENT .~cded. If significant vapors, mists or aerosols are generated, wear a NIOSh{ approved or'equiwalent.r~sp~tor, (ANSI Z 88.2, 1980 for rec~~ts and selection). For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilatien, a Fnmsur~z~m~d, ~lf~ntained V~HTLATIC~: General ventilation is recommit. ;~ditionally, local exhaust ventilation is recommmnded ~ere vapors, mists or aerosols P~U~CTIVE ~I~NT: Use ~le gloves an~ c~mical splash goggles (ANSI Z 87.1 re:/u/rements and selection of gloves, goggles, shoes, etc. ) when attaching feeding equipment or doing maintenance. If clothing is contain/hated, remove clothing and thorcu~y wash the affected area. Launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANS~ON A~, CALL ~E FOIIDWING 24-~0~3R T~~ ~ (312-920-1510) SPILL CONTROL AND RECOVERX: Small liquid spills: Contain with absorbent material, such as clay, PAGE 3OF 8 NALCO CHEMICAL COMI~ANY ONE NALCO CENTER · NAPERVILLE. ILLINOIS 60566-1024 AREA 312-961-9500 , ~, MATERIAI~SAFETY DATA SHEET IPRODUCT VI-SEp 716 ]i:~;.ESI(:~ ~ NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION ].4 REGULATORY TNFORMATZON ( CONTINUED ) Naphthalene =. T~ 10 p~n, STEL 15 p~u AO~IH/TLV · 50 m:~m3. 75 m:~/m3 AOG~V Naphthalene = ~ lO p~=, 50 ri=j/m3 , CSHA/TLV ~vy arcaat±c naphtha = ~A 100 ~t= TLr' '. Menu~actmrer' s recc~menc~t~cn ~~, 40 CFR 117, 302: ~ and if 10,000 ~ of prcx~-~ are relY, it requires (1-S00-4~-4-e80~.). S~A/~ ~ N~ ~Z/L~(2~ ~ OF 1986 (TTlw_E ITT) - SECT[oHs 302, 311, 312 N~D 313: Urcler Sectic~ 311, sul~ttal of MSDS's or a l~st of p~ ~ ~ ~ 17, 1987 if yc~t have: - 10,000 pounds or ~ore of a hazardous ~, or - 500 p=ur~.~ or ~he threshold planni~ qu~n~tT, ~chever ~cer ~ :17, 1989, l~[:S(s), or a lis~ of l~Cduct names for all ]~7~ sut~carces ~ zero (0) and 10,000 t~=~s, SECTION 302 '- ~.v HAZARDOUS SUBSTANCES (40 CFR 355): This product does not cc~tain ingredi~ listed in Appendix A and B as an Extremely Hazardous Substance o SEC'TI0~ 311 and 312 - MATERIAL SAFETY D~' S~E~ ~ (40 CFR 370): ~ product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard --Delayed (chronic) health hazard XX Fire hazard PAGE 5OF 8 · NALCO CHEMICAl. COMPANY ONE NALCO CENTER i NAPERVILLE, ILLINOIS 60566-1024 AREA 312-961-9500 MATERIAL SAIF~TY DATA SHEET~; ~ IPRODUCT I VI-SEP 716 ~LSI~ ~EAKER NALCO Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Naphthalene = T~A 10 ~, STEL 15 l:%a~' ACG]2{/TLV 50 ~ 75 ~/~ A~nVTLV Naphthalene = PEL 10 p~a, 50 m~/m3 ~V Heawy aromatic naphtha = T~A 100 ppm TLV Manufacturer ' s CERCIA/~, 40 CFR 117, 302: ~ product contains naphthalene, a Reportable Quantity (RQ) substance and if 10,000 pounds of product are released, it requires notification to the NATI(~J~ RESPONSE CENTER, ~, D. C. (1-800-424-8802). ~ma/~ mm~s~s ~D ~mn~uu~ ~ oF 1986 (TITLE III) - SECTIC~S 302, 311, 312 AND 313: Ur~ler Section 311, suhaitt~ of MSDG's or a 1L~t of product names to the local emezg~ plannin~ c~{-~sion, state ~_m~__rgency resp~ commission and local fire department is required after Oct~ 17, 1987 if yo~ have: - 10,000 pounds or more of a hazazdous substance, 'or - 500 ~s or the thre~ld pl~ing quantity, whi~r is less, of an extre~y hazardous substance. After ~ 17, 1989, MSES(s), or a list of product ~ for all ~.ard~ substances bet~ zero (0) ar~. 10,000 ~unds, SECTION 302 - EXTR~.v HAZARD~ SU~TANCES (40 CFR 355): and B as an Extremely Hazardous ~o S~TIONS 311 ar~ 312 - MATERIAL SAFETY [I~TA (40 CFR 370): ~e product shc~d be reported ur~__~r the following EPA hazard categories: XX Immediate (acute) health hazard --Delayed (chronic) health hazard XX Fire hazard i'i P~. 5 oF NAI. CO CHEMICAC COMI~ANY ONE NALCO CENTE~ · NAPERVlLLE. ILLINOIS 60568-1024 ~ ] AREA ~ _ ., MATERIAI~SAFETY DATA SHEET I PRODUCT · VI-SEP 716 ~JiSION ~kKER NALCO Emergency Telephone Number Medical (312) 920-1510 {24 hours) SECTION 16 USER'S RESPONSIBILITY ~ product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handl/n~ this product should be informed of the ~ safety precautions and should have access so that appropriate ~ing practices and training programs can be established to ~ safe workplace operations. Please consult your local sales ·r~presentative for any further information. SECTION 17 BIBLIOGRAPHY ANNSkL REPOK~ C~ CARCINOGenS, U.S. Depart of Health and Human Services, Public Health Service, PB 33-135855, 1983. CASAREIT AND DOULL'S. TOXIOOLOGY, ~E BASIC SCIENCE OF POISONS, 'Doull, J., Kl~a-~n, C. D., and Admur, M. O., eds., Macmillian Publishing Company, Inc., N. Y., 2r~ edition, 1980. (3~4I~ ~ OF ~{E ~ORKPIACE, Pructor, N. H., and Hughes, J. P., eds., J. P. Lipincott Cc~, N.Y., 1981. DANGERC[~ PR~~ OF INUJS~9/AL MATERIALS, Sax, N. Irving, ed. ,. Van Nostrar~ Reinhold Company, N.Y., 6th edition, 1984. IARC ~ (~ ~E EVAILSkTIC~ OF ~{E CA~/R~DG~IC RISK OF (~I~ Research on ~, 1972-1977. PATTY'S ~ HYGIENE AND TOxiCOLoGY, Claytcn, G. D. ,. Clayton, F. E., eds., Jc~J~ Wiley and Sc~s, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC ~'~i~ ON'C~4ICAL SUBSTAN~, U.S. De~ of Health and Human Services, Public Health Service, Center for Disease COntrol, National Institute for Occupational Safety ar~ Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, C~, 1984. Title 29 Code of Federal Recjulations Part 1910, Subpart Z, Toxic ar~ WORKR0CM ~ ~ INTENDED C}~ES, American Conferenoe of PAGE 7OF 8 NALCO CHEMICAL COMI~ANY ONE NALCO CENTER · NAPERVILLE. ILLINOIS 6056S-1024 AREA 312-~81-9500 MATERIAL SAIF~'Y DATA SHEET~ .._ ~ I N ALC O . ]PRODUCT vi-s1!2 '/16 :]!~jT_ST(:~ ~ Emergency Telephone Number Medical (312) 920-1510 (24 hours) SECTION 16 USER'S RESPONSIBILITY ~ pruduct material safety data sheet provides health and safety our product literature. .Individuals handling this product should be informed of the .~uue.?',z:].ed safety precautions and should, have'access so that appropriate handling practices and trainir~ programs can be. est~_blished to ~ safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPOR~ ~ CA~CINfX~{S, U.S. Department of Health and Human Services, Public Health Service; PB 33-135855, 1983. CASAREIT AND DU~_L'S TOXIOOLOGY, ~HE BASIC SCIENCE OF POLgDNS,' Doull, J., Klaa.~en, C. D., and Admur, M. O., eds., Macmillian Publishing Company, Inc., N. Y., 2~d edition, 1980. C~E~ICAL HAZARDS OF ~{E WORKPIACE, Proctor, 'N. H., and Hughes, J. P., eds., J. P. Lipir~Dtt Co~, N.Y., 1981. DANGEROUS PROPE~ OF ~ MATERIALS, Sax, N. Irving, ed., Van Nostrand Reirhold Cc~, N.Y., 6th edition, 1984. IARC ~ ~ ~E EVAU~ OF ~E CARC~O~C RLSK OF ~CALS l%esea~ on Car~er, 1972~1977. PAT~'S n~U~a~AL ~GnmZ AND ~OXI~U~Y, ~ay~n, G. D., ~ay~n, F. Z., eds., John Wiley a~d Sc~s, N. Y., 3rd edition, Vol. 2 A-C, 1981. R~GISTRY OF TOXIC k~'~'~3i~ C~ O~4I~ SUBSTANCES, U.S. Department of Health ar~ Human Services, Public Health Service, Center for Disease Control, National Institute for Occ~ti~ Safety and Health, 1983 s~pplemerfc of 1981-1982 edition, Vol. 1-3, ~H, 1984. Title 29 Code of Federal Regulati°ns Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). WORKROC~ ~ WITH INTENDED C~ANGES, American Conf~ of · PAGE 7OF 8 :- NALCO CHEMICAL COMPANY ONE NALCO CENTER · NApERVILLE. ILLINOIS 00566-1024 · AREA 312-961-9500 M ERIAL SAFETY DATA HEET PETROLITE CORPORATION REVISION DATE: 05/21/86 369 MARSHALL AVE. EMERGENCY PHONE: 1-314-961-3500 ST.LOUIS MO 63119 U.S.A CHEMTREC EMER NO: 1-800-424-9300 SECTION 1 PRODUCT IDENTIFICATION PRODUCT: SP 0252 TRADE NAME: SP LABEL: 014 097 SHIPPING NAME: NOT HAZARDOUS PER D.O.T. CFR TITLE 49 CHEMICAL DESCRIPTION AN ORGANIC PHOSPHONATE IN WATER. SECTION 2 HAZARDOUS INGREDIENTS CAS NUMBER MATERIAL % EXPOSURE LIMITS 00050-00-0 Formaldehyde <1 ACGIH TLV: 1.0 ppm OSHA PEL: 3.0 ppm ACGIH STEL: 2.0 ppm Specific chemical identity of unlisted ingredients is being withheld for confidential business purposes. SECTION 3 PHYSICAL DATA SPECIFIC GRAVITY(H20 = 1.0@60 F): 1.214 VOLATILITY: N/A VAPOR PRESSURE: Not Established SOL. IN WATER: Soluble MISC. DATA: pH <0.1 APPEARANCE AND ODOR: Amber liquid. Slight odor. SECTION 4 FIRE AND EXPLOSION HAZARD DATA FLASH POINT: >200 F FLAMMABLE LIMITS: Not Established FLASH METHOD: SFCC ASTM D-3828 EXTINGUISHING MEDIA: Material is non-flammable. Use water spray, foam, CO2 or any other media suitable for extinguishing materials supporting combustion. FIRE FIGHTING PROCEDURES: Use a self-contained breathing apparatus with full facepiece operated in pressure-demand or other positive pressure mode. ***CONTINUED ON PAGE: 2*** IV ERIAL SAFETY DAT/ HEET PAGE 2 ***CONTINUATION OF SP 0252 *** Non-flammable. Keep fire-exposed containers cool using water spray. UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. ************************************************************************************* SECTION 5 HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE: INHALATION: Inhalation of mists, aerosols or very high vapor concentrations will produce intense eye, nose and respiratory irritation and may result in lung damage. Prolonged exposure may result in chemical pneumonitis and, in extreme cases, pulmonary edema. SKIN AND EYE CONTACT: Contact with skin will cause moderate to severe irritation or burns. Contact with eyes will result in severe eye irritation or burns, and if not immediately removed, may lead to permanent eye injury. INGESTION: Causes severe irritation or burns to the mouth and gastrointestinal tract. In extreme cases may cause kidney and liver damage. EMERGENCY AND FIRST AID PROCEDURES: If contacted, wash skin immediately with soap and water. Remove contaminated clothing and wash before reuse. If irritation or burns develop, consult a physician. If in eyes, irrigate with flowing water immediately and continuously for fifteen minutes. Consult a physician. If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if symptoms persist or exposure was severe. If ingested, DO NOT induce vomiting. If conscious, drink promptly large quantities of water. Call a physician immediately. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock and convulsion may be necessary. ************************************************************************************* SECTION 6 REACTIVITY DATA STABILITY: Stable under normal conditions of storage and use. ***CONTINUED ON PAGE: 3*** I ERIAL SAFETY DAT/ HEET PAGE 3 ***CONTINUATION OF SP 0252 *** INCOMPATIBILITY: Keep away from strong oxidizing agents. HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of phosphorus and nitrogen. HAZARDOUS POLYMERIZATION: Will not occur. SECTION 7 SPILL AND LEAK PROCEDURES IF MATERIAL IS SPILLED OR RELEASED: Small spill - Absorb on paper, cloth or other material. Large spill - Dike to prevent entering any sewer or water- way. Transfer liquid to a holding container. Cover residue with dirt, or suitable chemical adsorbent. Use personal protective equipment as necessary. DISPOSAL METHOD: Place chemical residues and contaminated adsorbent materials into a suitable waste container and take to an approved waste disposal site. Dispose of all residues in accordance with applicable waste management regulations. DECONTAMINATION PROCEDURES: Not appropriate. ************************************************************************************* SECTION 8 SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION: When concentrations exceed the exposure limits specified. use of a NIOSH-approved supplied air respirator is recommended. Where the protection factor of the respirator may be exceeded, use of a self-contained breathing unit may be necessary. VENTILATION: General ventilation should be provided to maintain ambient concentrations below nuisance levels. Local ventilation of emmission sources may be necessary to maintain ambient concentrations below recommended exposure limits. PROTECTIVE CLOTHING: Synthetic gloves (such as rubber, neoprene, nitrile or viton), chemical goggles, ~ace shield and synthetic apron or coveralls should be used to prevent contact with eyes, skin or clothing. ***CONTINUED ON PAGE: 4*** IV ERIAL SAFETY DAT/ HEET PAGE 4 ***CONTINUATION OF SP 0252 *** ************************************************************************************* SECTION 9 SPECIAL PRECAUTIONS Avoid breathing of vapors and contact with eyes, skin or clothing. Hazardous product residue may remain in emptied container. Do not reuse container without commercial cleaning or reconditioning. NOTE: Formaldehyde has been identified as a suspect cancer agent by the National Toxicology Program and/or by the International Agency for Research on Cancer (IARC). Although the information and recommendations set forth herein are believed to be correct as of the date hereof, Petrolite makes no representations to the accuracy of such information and recommendations. It is the user's responsibility to determine the suitability and completeness of such information and recommendation for its own particular use.Petrolite shall not be responsible for any direct,indirect,incidental or consequential damages of whatsoever nature resulting from the publication,use of or reliance upon such information and recommendations. PETROLITE EXPRESSLY DISCLAIMS ANY AND ALL WARRANTIES OF EVERY KIND AND NATURE INCLUDING THOSE OF MERCHANTABILITY AND OF FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE PRODUCT, THE INFORMATION AND RECOMMENDATIONS cONTAINED HEREIN, OR ANY USE OR RELIANCE THEREON.