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Home My WebLink AboutBUSINESS PLAN "" Hazardous MaterialS/HazardOus:Waste 'Unified Permit CONDITIONS' OF .PERMIT ON REVERSE SIDE .- .': ~.. ,: ~ . This ~it is issu~ ~r'the follo~n~: ; '. ~ H~ous Martials Plan ' D Unde~round Storage of H~ffiOus Mateflals Permit ID ~:: 015~00~01842 D RiskManage~tPr~mm LONGS DRUG STORE ~17 LOCATION: 4400 COFFEE RD IELD Issued by: Bakersfield Fire Department ,~ >. ' ~ ..- ~~--;~D 1715 Chester Ave., 3rd Floor ' Approved by: Bakersfield, CA 93301 . O~¢¢ofE. v,[ro~~ices...,d Issue Date ~i~r~r Voice (661) 326-3979 '~~ FAX (661) 326-0576 Exp~tion Date: Hazardous Materials/Hazardous Waste-Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE ~ ~,~,,~,,¢¢,~ ii~,i? i;~7~.i?,~ i~i!~,~,~,,, .... This permit is issued for the following: ' ..... ,,~,,~ ~'~:i~'' ~" ~': ~i ~ii~.::i~¢:;~:::;,~:::;,~,~:;~;ii~::~i :~E:;;;E~!~Hazardous Materials Plan ~*:~"~i~'~iii~:i:~.:~!i~,!!~ ::'~'*~:~'~:::;i!i iiiii!iiii,~ ~:i !ii, ii ?i;::: ?ii~ili~e[ground Storage of Hazardous Materials PERMIT ID# 015-0214)01842 ¢~ii:'i ~,,i:~i!;;il;~iJiiii:i!ii!i ? ?!!!!!i?iiii~!!ii!i ! !!:!!! ::~!!!iiiiiiiiii~!i~'~ki~nagement Program ~-',,.:-,,., ~ "'~'~,~¢.,~.,f ?~,~,r '~;'.,;,: .... ~ ,r ',' ,~ .~i~: ~, ,~, -.,.....::~ LOCATION 4400' COFFEE :~¢~:,:::,,..::??~,~;,, ',,,~,, ...... I. D CA9330~'""'"~'":';;,,,~¢~,'" ' '~:''''::'''~i~'....:::~. '~.~. i ". '"..~i ~¢[~' iF'i' "" ~ '.....~ ~' i= .." i...~ ~'-* "... ~ I'"'~ ~::::-'::::::( ~::~: 'i~.:~, '~: ............. :~':'"" ~ ...... "i ~1 ~ :!. %-...-.:~ ~-..,, ....... ¢.~ ....... i~".. "... ' ' ~._" --...:: .~' '~ :', ~?~.._.: -..;~, ~, ~;;_.,_4~. '.~.,,.~ · ~ ..... .~,. ,,-, ..... ~ ..... ~ .... ~¢' f,.".,,"¢ 'i~"-,,-.:~i~ , ...... ¢i ..','. ,,.,.-~" =¢.,,.~ .~4~.,,,...,..,,~, ~;T' ..... "i~ '%;: ....... :~,,~",~* =~i. ,¢¢~' ':~,~¢ ............ L.,.~,.,.%,,%i,!~,.7,~i ~ ' ~., ,.¢~,, ,, ~ ~' Issu~ by: O~ICE OF E~R O~AL S~ ~CE5 1715 Chewer Ay,., ~rd Floor B~emfiel~ CA 93301 ~ Office of ~enml S~i~ Voice (805) 326-3979 F~ (805) 326~576 Expiration Date: June 30, 2000 ~ LoT I ~MPI~./EE' ° I ..... J SHOP,S I LONGS DRUG STORES ~ Site 01842 Manager : BRUCE HUNTER BusPhone: Location: 4400 COFFEE RD ~%'~ %%~% (661) 588-0290 Map : 102 CommHaz : Moderate City : BAKERSFIELD Grid: 16C FacUnits: 1 AOV: CommCode: COUNTY STATION 65 SIC Code: EPA Numb: CAL000176616 DunnBrad: Emergency Contact / Title Emergency Contact / Title ...... ~u~ / MANAGER JOHN MENDIOLA / ASST MANAGER Business Phone: (661 588-0290x Business Phone: (661) 588-0290x 24-Hour Phone : (661 ~7-1~B~zt~8~x~~ 24-Hour Phone : (661) 664-9769x Pager Phone : ( - x Pager Phone : ( ) - x Hazmat Hazards: RSs Fire Press React ImmHlth DelHlth Contact : ~JCE ~IL~TER~4z.~~ Phone: (661) 588-0290x MailAddr: 4400 COFFEE RD State: CA City : BAKERSFIELD Zip : 93308 Owner LONGS DRUG STORES CALIF INC Phone: (925) 937-1170x Address : 141 N CIVIC DR State: CA City : WALNUT CREEK Zip : 94596 Period : to TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: Yes ParcelNo: Emergency Directives: WASTE TREATMENT SITE: CONTACT 326-3979 FOR JOINT HAZ-MAT INSPECTION I, "~__~...~ Do hereby certify that I have ffype o~ p~nt heine) reviewed the attached hazardous materials manage- merit plan for_~, (N~,~ of L')'i'Te,.~,,,,-) --and that it along with any corrections constitute a complete and correct man- agement plan for my facility. -1- 09/09/2003 LONGS DRUG STORES #417 - SiteID: 015-021-001842 + Manager ': BRUCE HUNTER BusPhone: (661) 588-0290 Location: 4400 COFFEE RD Map : 102 CommHaz : Moderate City : BAKERSFIELD Grid: 16C FacUnits: 1 AOV: CommCode: COUNTY STATION 65 SIC Code: EPA Numb: CAL000176616 DunnBrad: Emergency Contact / Title Emergency Contact / Title BRUCE HUNTER / MANAGER JOHN MENDIOLA / ASST MANAGER Business Phone: (661) 588-0290x Business Phone: (661) 588-0290x 24-Hour Phone : (661) 871-3201x 24-Hour Phone : (661) 664-9769x Pager Phone : ( ) - x Pager Phone : ( ) - x Hazmat Hazards: RSs Fire Press React ImmHlth DelHlth I Contact : BRUCE HUNTER Phone: (661) 588-0290x MailAddr: 4400 COFFEE RD State: CA City : BAKERSFIELD Zip : 93308 Owner LONGS DRUG STORES CALIF INC Phone: (925) 937-1170x Address : 141 N CIVIC DR State: CA City : WALNUT CREEK Zip : 94596 Period : to TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: Yes Emergency Directives: WASTE TREATMENT SITE: CONTACT 326-3979 FOR JOINT HAZ-MAT INSPECTION + += Hazmat Inventory == One Unified List + +== Alphabetical Order - All Materials at Site + ................................ + ....... + ........... + ..... + + .... +- - -+ Hazmat Common Name... ISpecHazlEPA HazardsI Frm I DailyMax IUnitlMCPI ................................ + ....... + ........... +_ + + .... +___+ CHLORINE F P IH G 128 00 GAL Ext CLEANER DH L 55 00 GAL Mod DEVELOPER L 3 00 GAL Low DEVELOPER PART A R IH L 2 00 GAL Hi DEVELOPER PART A R IH L 5 00 GAL Hi DEVELOPER PART B F R IH L 2 00 GAL Low DEVELOPER PART B F R IH L 5 00 GAL Low DEVELOPER PART C R IH L 2 00 GAL Mod DEVELOPER PART C R IH L 5 00 GAL Mod FIXER PART A R IH L 2 00 GAL Hi FIXER PART B R IH L 10 00 GAL Low HELIUM F P IH G 732 00 FT3 Min PHOTOGRAPHIC CHEMICALS F DH L 1 00 GAL Low PHOTOGRAPHIC DEVELOPERS R IH L / GAL Mod -1- 01/25/2002 + LONGS DRUG STORES #417 SiteID: 015-021-001842 + += Hazmat Inventory One Unified List + +== Alphabetical Order All Materials at Site + + ................................ + ....... + ........... + ..... + .......... + .... +- - -+ I Hazmat Common Name... ISpooHazlEPA HazardsI Frm I DailyMax IUnitIMCPI + ................................ + ....... + ........... + ..... + .......... + .... +- - -+ PHOTOGRAPHIC DEVELOPERS R IH L 10.00 GAL Mod PHOTOGRAPHIC FIXERS R IH L 20.00 GAL Mod PROPANE E F P IH G 360.00 FT3 Hi WASTE DEVELOPER R L 30.00 GAL Min I, .o~r'u~ /-~,-./¢.~'" Do hereby certify that ~ have {Type or r~,,;-,~,~,'~ the att~cned h~ardous materials manage- me~t r>tan for ~ei~ ~,{~¢* and that it alo~ with any corre~ions constituto a comploto and corro~ man- a~omonl plan for my ~acili~. =+ -2- 01/25/2002 + LONGS DRUG STORES ~417 SiteID: 015-021-001842 += Inventory Item 0018 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME ~ CHLORINE I Days On Site I CHLORINATING LIQUID 365 Location within this Facility Unit Map: Grid: + ................ BACK STORAGE RM RACK-WHS 21 I CAS# 7882-50-5 =4 += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Gas I Pure I Above Ambient { Ambient I PLASTIC CONTAINER ~ + ~ =4 +-- + + AMOUNTS AT THIS LOCATION ~=+ Largest Container Daily Maximum I Daily Average 1000 GAL 128.00 GAL 64.00 GAL + ~ HAZARDOUS COMPONENTS ---+===+ .......... 10.00 Sodium Hypochlorite No 7681529 + 7 ---+===+===== ~ 7===+ + HAZARD ASSESSMENTS ===+ 7 .... + ..... ITSecretINo NoRSIBi°Haz[No Radioactive/Amount { EPA No/ Curies F P Hazards IH NFPA/// USDOT# I MCP + 7===4 ~ ~ %=========~ +=====+ += Inventory Item 0002 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME + CLEANER I Days On Site SURTEC FLOOR CLEANER I 365 Location within this Facility Unit Map: Grid: + ................ INSIDE JANITOR'S CLOSET IN BACK STOREROOM I CAS# i + + += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER + + ~ ~===============+== + + AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum I Daily Average 5.00 GAL I 55.00 GAL I 5.00 GAL + 7 -- HAZARDOUS COMPONENTS %===+= 6.00 Diethylene Glycol Monoethyl Ether No 111900 + 7 ~ 7===+ + HAZARD ASSESSMENTS ===+ ~ + ..... I TSoorot INo NoRS I Bi°HasINo Radioactive/AmountNo/ Curies EPA HazardsIDH NFPA/// USDOT# MCP + 7===4 7= ~===========--+ 7 + -3- 01/25/2002 + LONGS DRUG STORES #417 SiteID: 015-021-001842 += Inventory Item 0008 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME += --+ DEVELOPER I Days On Site I DEVELOPER STARTER 365 Location within this Facility Unit Map: Grid: +- -+ PHOTO LAB I CAS# +---- + ------+ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER + AMOUNTS AT THIS LOCATION I Largest Container Daily Maximum I Daily Average 0.16 GAL 3.00 GAL I 3.00 GAL 4--- ~--- 4 4 HAZARDOUS COMPONENTS +===4 %Wt. RSI CAS# 10.00 Potassium Carbonate No 584087 7.00 Sodium Bicarbonate No 144558 5.00 Potassium Chloride No 7447407 4 ~===~ 4 .... 4 ~ HAZARD ASSESSMENTS ===+ ......... 4 + ...... ]TSecret RSIBioHazI Radioactive/Amount I EPA Hazards NFPA I USDOT# MCP No No No No/ Curies / / / Low 4 +===4 4 ~= 4 =4 ~=====- += Inventory Item 0003 Facility Unit: Fixed Containers at Site + +== COMMON NAME / CHEMICAL NAME --. DEVELOPER PART A Days On Site PART A DEVELOPER REPLENISHER 365 Location within this Facility Unit Map: Grid: + ................. PHOTO LAB CAS# 7757-83-7 += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER 4 + AMOUNTS AT THIS LOCATION I Largest Container Daily Maximum Daily Average 0.16 GAL 2.00 GAL 2.00 GAL 4 4 ~- :=========' 4 +-- HAZARDOUS COMPONENTS +===4 %Wt. Triethanolamine RS CAS# 10.00 No 102716 7.00 Hydroxylamine No 7803498 5.00 Acetic Acid, Pure No 64197 4 ~ .... ~-===-~ 4 +===4 4 HAZARD ASSESSMENTS ===4 =4 + ...... ITSecretlNo NoRSIBi°HazINo Radi°active/Am°unt I EPANo/ Curies HazardsR IH NFPA/// I USDOT# IMCPHi + =+===4 4 4-= .... +=====.====4 ==+=====+ -4- 01/25/2002 + LONGS DRUG STORES ~417 SiteID: 015-021-001842 += Inventory Item 0009 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME ~ ---+ DEVELOPER PART A Days On Site 365 Location within this Facility Unit Map: Grid: + ................ PHOTO LAB CAS# 7757-83-7 += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER += ~ ~ ~ 4 += -+ AMOUNTS AT THIS LOCATION I Largest Container I Daily Maximum Daily Average 0.25 GAL 5.00 GAL 5.00 GAL += + 4 + += HAZARDOUS COMPONENTS +===4 =+ 33.00 Potassium Carbonate No 584087 3.00 Sodium Sulfite No 7757837 += ,==========: ==+===+ + +===+= =4 HAZARD ASSESSMENTS ===4 += ~ ..... ITSecret N~S Bi°HazlRadi°active/Am°untNo No No/ Curies EPA HazardsIR IH NFPA/// IUSDOT# MCP + +===+ 4 ~=============4 ~========+=====+ += Inventory Item 0004 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME +~ DEVELOPER PART B Days On Site PART B DEVELOPER REPLENISHER 365 Location within this Facility Unit Map: Grid: + ................ PHOTO LAB CAS# 74-19-7 +========= 4 += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER +=========4 ~ ~ 4 += + AMOUNTS AT THIS LOCATION - ==+ I Largest Container0.16 GAL I Daily Maximum2.00 GAL I Daily Average2.00 GAL + =4 4 + += = HAZARDOUS COMPONENTS +===+ .... %Wt. I RS CAS# 70.00 Acetic Acid Solution IN° 64196 18.00 p-Phenylenediamine No 106503 1.00 Sodium Sulfite No 7757837 += + + + .... += 4 HAZARD ASSESSMENTS ===4 + ~ ..... ITsecretNO ,NORS I Bi°HasINo Radi°act ive/Am°unt I EPANo/ Curies F RHazardsIIH NFPA/// IuSDOT# MCP q ~===q + ~ =4 + ~=====+ -5- 01/25/2002 + LONGS DRUG STORES #417 SiteID: 015-021-001842 += Inventory Item 0010 -- Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME ~ DEVELOPER PART B Days On Site 365 Location within this Facility Unit Map: Grid: + ....... PHOTO LAB CAS# 74-19-7 += ~ .... += STATE =+= TYPE ===+== PRESSURE ===+ TEMPER3kTURE ==+ .... CONTAINER TYPE ..... I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER + 4 ~ ~--- ~==== + =+ AMOUNTS AT THIS LOCATION -~ I Largest Container I Daily Maximum Daily Average 0.12 GAL 5.00 GAL 5.00 GAL + ~ ~ .... =+ + += HAZARDOUS COMPONENTS -+===4 %Wt. I RS CAS# 70.00 Acetic Acid Solution IN° 64196 5.00 Hydroxylamine Sulfate No 10039540 5.00 Phosphoric Acid No 7664382 + + 4 + +===+ + HAZARD ASSESSMENTS ===4 + ~ ..... I TSecret INo NoRS BioHazINO Radioactive/AmountNo/ Curies EPAF RHa zardsIIH NFPA/// IUSDOT# MCP 4 +===4 ~ ==q ~ + ~=====+ += Inventory Item 0005 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME , DEVELOPER PART C Days On Site PART C DEVELOPER 365 Location within this Facility Unit Map: Grid: + ................ PHOTO LAB CAS# 111-30-8 += 4 +: STATE --+: TYPE :::+:= PRESSURE :=:+ TEMPERATURE :=+ .... CONTAINER TYPE ..... I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER + 4 ~ ~ 4 + ~ AMOUNTS AT THIS LOCATION I Largest Container I Daily Maximum Daily Average 0.16 GAL 2.00 GAL 2.00 GAL + ---- ~ ~ =====+ 4 HAZARDOUS COMPONENTS =+ .... %Wt. RS CAS# 41.00 Potassium Carbonate No 584087 7.00 Potassium Hydroxide No 1310583 + =+===.~ + +===+ ~ HAZARD ASSESSMENTS ===4 + ~ ...... ITSecret NoRSIBioHazI Radioactive/Amount I EPA HazardsI NFPA I USDOT# MCP No No No/ Curies R IH / / / Mod += +===+= .... =4 ~ ~ + ~=====+ 6 01/25/2002 + LONGS DRUG STORES #417 SiteID: 015-021-001842 += Inventory Item 0011 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME + --+ DEVELOPER PART C I Days On Site 1365 Location within this Facility Unit Map: Grid: + ................ PHOTOLAB I CAS# 111-30-8 +== + ~-+ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER + AMOUNTS AT THIS LOCATION I Largest Container Daily Maximum Daily Average 0.25 GAL 5.00 GAL 5.00 GAL 4 ~ ~ .... 4 HAZARDOUS COMPONENTS .... a %Wt. RS CAS# 16.00 p-Phenylenediamine No 106503 1.00 Sodium Sulfite No 7757837 +===4 4 ~===4 ~ HAZARD ASSESSMENTS ===4 ~ + ..... ITSecret[ RS[BioHaz[ Radioactive/Amount I EPA Hazards NFPA I USDOT# I MCP No ~No No No/ Curies R IH / / / Mod 4 k===~ ~ =4 ~ ~ ~=====+ += Inventory Item 0006 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME =~-a FIXER PART A Days On Site PARTZ BLEACH FIXER 365 Location within this Facility Unit Map: Grid: + ................ PHOTO LAB CAS# 7783-18-8 +-~- ~ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE ..... I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER ~ ~ + +- ~= +--- ~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 0.16 GAL 2.00 GAL 2.00 GAL +--- ~ ~= 4 HAZARDOUS COMPONENTS .... ~ %Wt. RS CAS# 33.00 Ammonium Thiosulfate No 7783188 20.00 Ammonium Sulfite No 10196202 7.00 Ammonium Nitrate No 6484522 7.00 Acetic Acid, Pure No 64197 7===+ 4 +===~ ~ HAZARD ASSESSMENTS ===q ~ + ..... TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Hi 4 k===4 ~ + ~ ~ +=====+ -7- 01/25/2002 + LONGS DRUG STORES #417 - SiteID: 015-021-001842 += Inventory Item 0007 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME ~ FIXER PART B Days On Site PART B BLEACH FIXER 365 Location within this FaCility Unit Map: Grid: + PHOTO LAB CAS# 10043-01-3 .... + += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Mixture I Ambient I Ambient I PLASTIC CONTAINER + =+ AMOUNTS AT THIS LOCATION I Largest Container I Daily Maximum Daily Average 0.25 GAL 10.00 GAL 10.00 GAL + ==4 ~ + HAZARDOUS COMPONENTS +===4 =+ %Wt. I RS CAS# 27.00 Ferric Ammonium Ethylene Diamine Tetraacetic AcidIN° 0 17.00 Ammonium Bromide No 12124979 3.00 Nitric Acid (EPA) No 7697372 + +===4 + +===+ ~ HAZARD ASSESSMENTS ===4 + +===== { TSoorot [No YeaRS BioHazINo Radioactive/AmountNo/ Curies EPA HazardsIR IH NFPA/// I USDOT# MCP {Low + + + =4 ~ =4 + ~ += Inventory Item 0017 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME ~ HELIUM Days On Site 365 Location within this Facility Unit Map: Grid: + ................ 1 IN PHOTO DEPT AND 2 IN RECEIVING CAS# 7440-59-7 +---- ~ += STATE=+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Gas [ Pure I Above Ambient I Ambient + ~ ~ ------4 + =+ AMOUNTS AT THIS LOCATION I Largest Container I Daily Maximum Daily Average 244.00 FT3 732.00 FT3 732.00 FT3 +---- ~ ~ + + HAZARDOUS COMPONENTS +===4 I 100.00 7440597 + + =+===4 =========+ + +===+= .... =4 HAZARD ASSESSMENTS ===4 + ~ ..... ITSecret N~S Bi°Haul Radi°active/Am°untNo No No/ Curies EPA HazardsIF P IH NFPA/// IUSDOT# MiBMCP += +===+======4 ~ ======4 + ~ -8- 01/25/2002 + LONGS DRUG STORES #417 SiteID: 015-021-001842 += Inventory Item 0015 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME + --+ PHOTOG~PHIC CHEMICALS I Days On Site I SAFER STABILIZER 365 Location within this Facility Unit Map: Grid: + ................ PHOTOLAB I CAS# + 7= ------+ += STATE= =+ TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Mixture I A~ient I a~ient I PLASTIC CONTAINER ~-- ~ AMOUNTS AT THIS LOCATION I Largest Container Daily Maximum I Daily Average 0.05 GAL 1.00 GAL 1.00 GAL 4 ~ ~ZARDOUS COMPONENTS ~===4 15.00 1,2,4-Triazole No 288880 ~===4 ~ ~ZARD ASSESSMENTS ===4 ~ + ..... ITSecretl RSIBioHazl Radioactive/Amount I EPA Hazards NFPA I USDOT# MCP No No No No/ Curies F DH / / / Low 4 ~===4 4 7= 4 =4 ~=====+ += Inventory Item 0012 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME ---4 .... PHOTOGRAPHIC DEVELOPERS Days On Site PART A BLEACH DEVELOPER 365 Location within this Facility Unit Map: Grid: + ................ PHOTO LAB CAS# 123-31-9 4 ------q += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid IMixture IAmbient IAmbient I PLASTIC CONTAINER 4 ~ AMOUNTS AT THIS LOCATION I Largest Container Daily Maximum I Daily Average GAL GALI GAL 4 HAZARDOUS COMPONENTS .... 4 %Wt. RS CAS# 30.00 Ammonium Bromide No 12124979 10.00 Disodium EDTA No 139333 4 .==='~ 4 ~===4 ~ HAZARD ASSESSMENTS ===+ ~ + ..... ITSecret{ RSIBioHazI Radioactive/Amount { EPA Hazards NFPA USDOT# I MCP No No No No/ Curies R IH / / / Mod 4 ~===4 ~ =+ ~ ~ +=====+ -9- 01/25/2002 + LONGS DRUG STORES #417 SiteID: 015-021-001842 += Inventory Item 0013 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME =4 -~ PHOTOGRAPHIC DEVELOPERS I Days On Site PART B BLEACH DEVELOPER 365 Location within this Facility Unit Map: Grid: + ................ PHOTOLAB I CAS# 123-31-9 4 ======4 += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE Liquid I Mixture ] Ambient I Ambient ] PLASTIC CONTAINER 4 ~ + + + +--- ~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 0.40 GAL 10.00 GAL 10.00 GAL ___+ __+ -_~+ HAZARDOUS COMPONENTS +===q 29.00 Ferric Ammonium EDTA No 0 19.00 Ammonium Bromide No 12124979 + + ~===4 ~ HAZARD ASSESSMENTS ===4 ~ =+ ..... TSecretINo NoRSIBi°HazINo Radi°active/Am°unt I EPANo/ Curies HazardsR IH NFPA/// USDOT# I MCP -=======+===4 ~ ============4 ~ 4 +=====+ += Inventory Item 0014 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME ..... + PHOTOGRAPHIC FIXERS I Days On Site I BLEACH FIXER 365 Location within this Facility Unit Map: Grid: +- PHOTO LAB I CAS# 64-19-7 += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE Liquid I Mixture I 'Ambient I Ambient I PLASTIC CONTAINER += =4 =====+ + ..... + AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 0.50 GAL 20.00 GAL 20.00 GAL HAZARDOUS COMPONENTS ~ = = = q %Wt. I RS CAS# 49.00 Ammonium Thiosulfate IN° 7783188 3o00 Sodium Sulfite No 7757837 3000 Sodium Bisulfite No 7631905 4-=== q +===4 4 FIAZARD ASSESSMENTS ===~ + ........ + ..... TSecretI RSIBioHazI Radioactive/Amount I EPA Hazards NFPA USDOT# I MCP No No No No/ Curies R IH / / / Mod ~-===4 ~ 4 ~ ~ +=====+ -10- 01/25/2002' + LONGS DRUG STORES #417 == SiteID: 015-021-001842 += Inventory Item 0016 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME PROPANE Days On Site 365 Location within this Facility Unit Map: Grid: + JANITORS CLOSET CAS# 74-98-6 + += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Gas I Pure I Above Ambient += ~ ~ ~ ~ =+ += + AMOI/NTS AT THIS LOCATION I Largest Container I Daily Maximum I Daily Average 188.00 FT3 360.00 FT3 360.00 FT3 += =========+ ~___ + ....... + HAZARDOUS COMPONENTS --+===+ --+ 100.00 Propane Yes 74986 + + +===+== --~+ + +===+ + HAZARD ASSESSMENTS ===+ ~ ~ ..... I TSecret INo NoRS BioHazINo . Radi°active/Am°unt I EPANo/ Curies F P HazardsIIH NFPA/// USDOT# MCP + 7===~ + ~ + ~ ~=====+ += Inventory Item 0001 Facility Unit: Fixed Containers at Site +== COMMON NAME / CHEMICAL NAME ~ ..... WASTE DEVELOPER I Days On Site I PHOTOGRAPHIC DEVELOPER WASTE 365 Location within this Facility Unit Map: Grid: + ................ INSIDE SE END OF BACK STOREROOM { CAS# +---- ~ ==+ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+ .... CONTAINER TYPE I Liquid I Waste I Ambient I Ambient I DRUM/BARREL-NONMETAL += ~ ~ ~ ~----~ , ----7 + =+ AMOUNTS AT THIS LOCATION ==+ I' Largest Container I Daily Maximum Daily Average 15.00 GAL 30.00 GAL 15.00 GAL + =+---- ~ += + HAZARDOUS COMPONENTS ==+===+ ==+ 1%Wt. I Silver INoRSI CAS#7440224 I + ~ ==+===+ ==+ += +===~ + HAZARD ASSESSMENTS ===7 += ~===== I TSecretINo NoRS I Bi°HasINo Radioactive/AmountNo/ Curies EPA RHazards I NFPA/// IUSDOT# MinMCP ( ~ ~===~ + ½ =% + ~=====+ -11- 01/25/2002 + LONGS DRUG STORES #417 - SiteID: 015-021-001842 + ~ == Fast Format + += Notif./Evacuation/Medical Overall Site + +== Agency Notification 02/17/1998 + DIAL 911 FOR EMERGENCY RESPONSE AND LET THEM KNOW OF HAZARDOUS MATERIALS ON SITE. + +=== Employee Notif./Evacuation 07/11/2000 + VERBAL NOTIFICATION/SHOUTING/PA SYSTEM. EVACUATE STORE THROUGH NEAREST EXIT (2 FRONT DOORS & EMERGENCY EXIT ON S SIDE) THEN MEET AT DESIGNATED MEETING AREA IN FRONT OF STORE. ~ + + .... Public Notif./Evacuation 07/11/2000 + VERBAL NOTIFICATION/SHOUTING/PA SYSTEM. EVACUATE STORE THROUGHT NEAREST EXIT (2 FRONT DOORS & EMERGENCY EXIT ON S SIDE) THEN MEET AT DESIGNATED MEETING AREA IN FRONT OF STORE. +___ ~ Emergency Medical Plan = 02/17/1998 + DIAL 911. -12- 01/25/2002 + LONGS DRUG STORES #417' SiteID: 015-021-001842 + Fast Format += Mitigation/Prevent/Abatemt Overall Site +== Release Prevention - 07/11/2000 PRODUCT MATERIALS ARE TRANSFERRED IN SMALL QUANTITIES. RESIDUAL PRODUCT MATERIALS STORED IN SECONDARY CONTAINMENT. WASTE TREATMENT UNIT IS SECONDARILY CONTAINED. +=== Release Containment 07/11/2000 MAINTAIN RIGID HOUSEKEEPING PROGRAM. USE SMALL QUANTITY CONTAINERS AND SECONDARY CONTAINMENT. WASTE TREATMENT UNIT OPERATED AS BATCH PROCESS ONCE DAILY. + + .... Clean Up -- 02/17/1998 ALL MINOR SPILLS CLEANED UP USING SPILL ABSORBENT MATERIALS AND SPILL KITS. SPILL CLEAN UP MATERIALS CONTAINERIZED AND PROPERLY LABELED. Other Resource Activation ---+ -13- 01/25/2002 + LONGS DRUG STORES #417 SiteID: 015-021-001842 + + Fast Format + += Site Emergency Factors ...... Overall Site + +== Special Hazards =+ +=== Utility Shut-Offs 02/17/1998 + A) GAS - OUTSIDE E FACING BLDG WALL NEAR NE CORNER B) ELECTRICAL - OUTSIDE E FACING BLDG WALL NEAR NE CORNER C) WATER - OUTSIDE E FACING BLDG WALL NEAR NE CORNER D) SPECIAL - SPRINKLER, INSIDE AT NE CORNER OF STORE E) LOCK BOX - NO ..... Fire Protec./Avail. Water == 02/17/1998 + PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS LOCATED NEAR 2 FRONT ENTRANCES AND NEAR EMERGENCY ENTRANCE (S SIDE OF STORE) SPRINKLERED BLDG. NEAREST FIRE HYDRANT - OUTSIDE S OF SW CORNER OF STORE. + ..... Building Occupancy Level + ~ -14- 01/25/2002 + LONGS DRUG STORES #417 SiteID: 015-021-001842 + Fast Format += Training Overall Site +== Employee Training 02/17/1998 WE HAVE 40 EMPLOYEES AT THIS FACILITY. WE DO HAVE MSDS SHEETS ON FILE NEAR THE PHOTO LAB AREA. BRIEF SUMMARY OF TRAINING PROGRAM: 30 MINJ3TE VIDEO AND WORKSHEETS WITH ANNUAL REFRESHER. +=== Page 2 + .... Held for Future Use Held for Future Use + + -15- 01/25/2002 Dear Business Owner: FIRE CHIEF RUN FRAZE This notice is meant to act as a reminder that the California Health ADMINISTRATIVE SERVICES and Safety Code, Chapter 6.95, requires any handler of hazardous materials 2101 'H' Street ~,~f~el,~, c~ 93301 to revise their hazardous materials business plan within 30 days of any one VOICE (805) 326-3941 FAX (805) 395-1349 of the following events: SUPPRESSION SERVICES 2101 'H' Street (1) A 100 per cent or more increase in the quantity of a Bakersfield, CA 93301 previously-disclosed material. VOICE (805) 325-3941 FAX (805)395-1340 (2) Any handling of a previously-undisclosed hazardous PREVENTION SERVICES 1715 Chester Ave. material, subject to the inventory requirements of Chapter Bakersfield, CA 93301 VOICE (805) 326-3951 6.95. FAX (805) 326-0576 ENVIRONMENTAL SERVICES (3) Change in business ownership. 1715 Chester Ave. Bakersfield, CA 93301 VOICE (805) 326-3979 (4) Change in business address. FAX (005) 326-0576 TRAINING DIVISION (5) Change of business name. 5642 Victor Ave. Bakersfield, CA 93308 VOICE (805)399-4697 Any questions regarding these required revisions, please call the FAX (805) 399-5763 Hazardous Materials Division at (805) 326-3979. Sincerely yours, Director, Office of Environmental Services General Offices: 141 North Civic Drive, P.O. Box 5222, Walnut Creek, California 94596, (925) 937~1170 September 24, 2001 Esther Duran Bakersfield Fire Department Office of Environmental Services 1715 Chester Avenue Bakersfield, CA 93301 RE: Site and Facility Maps for Longs Drug Store//417 Please find the enclosed site and facility maps for Longs Drug Store #417 located at 4400 Coffee Road in Bakersfield. This completes our submission of updated maps for our stores located in Bakersfield. If you require any further information, please call me at (707) 745-1654. S~cerely, Raqu~ Kames Environmental Coordinator ~ Grocery , -r- , PARKING ' I I GOFFF:I:: ROAD t.~a,n~ Emergency Exits Only Entrances/Exits (Normal) Evacuation Routes Evacuation Meeting Area Storm Drains Fire Protection Conn. Electric Utility Shutoff Gas Utility Shutoff ~. Water Utility Shutoff ~ ~~ #417 ~400 Coffee Rd. Bakersfield, CA 93308 oooo Emergency Exits Only Evacuation Routes Fire Extinguishers ~ Fire Hoses -- Fire Alarm/Bell ----. ~ Fire Sprinkler Riser ~/ t [--][~ MSDS Location f Hazmat Storage Spill Clean-up Kit ~ Silver Recovery Unit > ~ ~ D Helium Propane ;~-" " First Aid Kit ~ ~ggl, g~ #417 ]'~4400 coffee Rd. Bakersfield, CA 93308 LONGS DRUG STORE #417 SiteID: 215-000-001842 Manager : BRUCE HUNTER ~ BusP~one: (~) 588-0290 Location: 4400 COFFEE RD Map : 102 CommI-Iaz : Moderate City : BAKERSFIELD Grid: 16C FacUnits: 1 AOV: CommCode: COUNTY STATION 65 SIC Code: EPA Numb: CAL000176616 DunnBrad: Emergency Contact / Title Emergency Contact / Title BRUCE HUNTER ~ MANAGER JOHN MENDIOLA ~ ASST MANAGER Business Phone: (~5) 588-0290x '.. Business Phone:(~5) 588-0290x 24-Hour Phone : (~.) 871-3201x 24-Hour Phone : (~5') 664-9769x Pager Phone : (~!) - x Pager Phone : (~4) - x Hazmat Hazards: RSs Fire Press React ImmHlth DelHlth Contact : BRUCE HUNTER Phone: (~) 588-0290x MailAddr: 4400 COFFEE RD State: CA City : BAKERSFIELD Zip : 93308 Owner LONGS DRUG STORES CALIF INC Phone: (925) 937-1170x Address : 141 N CIVIC DR State: CA City : WALNUT CREEK Zip : 94596 Period : to TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: Yes Emergency Directives: WASTE TREATMENT SITE: CONTACT 326-3979 FOR JOINT HAZ-MAT INSPECTION ~ Hazmat Inventory One Unified List -- As Designated Order Ail Materials at Site Hazmat Common Na~e... ~ ec~z PA zards Frm DailyMax Unit MCP WASTE DEVELOPER . , '~ o ~ ~ ~ L 30 00 GAL Min CLEANER ~ = '~ ~' .~ ~ DH L -S ~ 0 0 G~ Mod FIXER P~T B ~ ~ IH L 10 00 G~ Low DEVELOPER ~ ~ ~' L 3 00 G~ Low DEVELOPER P~T A ~ ~ ~ IH L 5 00 G~ Hi DEVELOPER P~T C ~ ~ IH L 5 00 G~ Mod PHOTOG~PHIC DEVELOPERS %~ ~ 9 ~ IH L G~ Mod PHOTOG~PHI C DEVELOPerS ~ ~ ~ IH L G~ Mod FIXERS ~ ~ IH L G~ Mod PHOTOG~PHI C ~ .. ~ / ... ~~ ~ ~_ 0~/0~/~000 F LONGS DRUG STORE #417 SiteID: 215-000-001842 ~ Hazmat Inventory One Unified List --As Designated Order All Materials at Site Hazmat Common Name... ISpocHazlEPA Hazardsl Frm DailyMax IunitlMCP PHOTOG~PHIC CHEMICMS F DH L GM Low PROP~E F P IH G 360.00 FT3 Hi HELI~ F P IH G ~ ~44.00 FT3 Min CHLORINE F P IH G 128.00 GM Ext 2 05/08/2000 LONGS DRUG STORE #417 SiteID: 215-000-001842 ~- Inventory Item 0001 Facility Unit: Fixed Containers at Site ~UiV~Vl~ ~Vl~ / . ~£ ~X'-~I_~ ~Vl~ WASTE DEVELOPER Days On Site PHOTOGRAPHIC DEVELOPER WASTE 365 Location within this Facility Unit Map: Grid: INSIDE SE END OF BACK STOREROOM CAS# Liquid Waste Ambient Ambient DRUM/BARREL-NONMETAL --, AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average 15.00 GAL I 30.00 GAL 15.00 GAL HAZARDOUS COMPONENTS %Wt. RN~oRS CAS# Silver 7440224 HAZARD ASSESSMENTS TSecret RS BioHaz Radioactive/Amount EPA ~azards NFPA USDOT# MCP No N° No No/ Curies R / / / Min = Inventory Item 0002 Facility Unit: Fixed Containers at Site CUIVHVlUN N~vl~ / C~I UZ.-~.b N~Vl~ CLEANER Days On Site SURTEC FLOOR CLEANER 365· Location within this Facility Unit Map: Grid: INSIDE JANITOR'S CLOSET IN BACK STOREROOM CAS# Liquid Mixture Ambient · Ambient PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average 5.00 GALI 55.00 GAL 5.00 GAL HAZARDOUS COMPONENTS 6.00 Diethylene Glycol Monoethyi Ether N 111900 HAZARD ASSESSMENTS ITsecret RS BioHaz ' Radioactive/Amount EPA Hazards NFPA I USDOT# MCP No No No No/ Curies DH / / / Mod 3 05/08/2000 LONGS DRUG STORE #417 SiteID: 215-000-001842 ~ Inventory Item 0003 Facility Unit: Fixed Containers at Site ~Ulv~vJu~ ~vl~ / ~l~ ~v]~ DEVELOPER P~RT A Days On Site P~RT A DEVELOPER REPLENISHER 365 Location within this Facility Unit Map: Grid: PHOTO LAB CAS# 7757-83-7 Liquid Mixture Ambient Ambient PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container } Daily Maximum I Daily Average 0.16 GALI 2.00 GALI 2.00 GAL %Wt. RS CAS# 10.00 Triethanolamine No 102716 7.00 Hydroxylamine No 7803498 5.00 Acetic Acid, Pure No 64197 HAZARD ASSESSMENTS [TSecretNo NoRS Bi°Hazl Radioactive/Amount J EPA HazardsNo No/ Curies R IH NFPA/// USDOT# HiMCP ---- Inventory Item 0004 Facility Unit: Fixed Containers at Site DEVELOPER PART B Days On Site PART B DEVELOPER REPLENISHER 365 Location within this Facility Unit Map: Grid: PHOTO LAB CAS# 74-19-7 r STATE -q-- TYPE PRESSURE i TEMPERATURE CONTAINER TYPE Liquid /Mixture Ambient Ambient PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container ! Daily Maximum Daily Average 0.16 GALL 2.00 GAL 2.00 GAL %Wt. RS CAS# 70.00 Acetic Acid Solution No 64196 18.00 p-Phenylenediamine No 106503 1.00 Sodium Sulfite No 7757837 HAZARD ASSESSMENTS TSecretl oRS BiOHaz Radioactive/Amount I EPA HazardsI NFPA USDOT# I MCP No N No No/ Curies F R IH / / / Low -4- 05/08/2000 LONGS DRUG STORE//417 ~~~~~ SiteID: 215-000-001842 ~ Inventory Item 0005 ~~~ Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME ~~~~~i~~~ DEVELOPER PART C o Days On Site o PART C DEVELOPER o 365 o Location within this.Facility Unit Map: Grid: PHOTO LAB o CAS# o o 111-30-8 o i~ STATE ~i~ TYPE ~i~ PRESSURE ~i TEMPERATURE ~i~ CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~~~~i AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average ° 0.16 GAL o 2.00 GAL o 2.00 GAL o i~i~66666~6~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS# o 41.00opotassium Carbonate °No ° 584087° 7.00°Potassium Hydroxide, ONo o 1310583° i~i~i~i~8~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP ° No ONoONo o No/ Curies° RIH o /// o OModO Inventory Item 0006 EEE~EEE~EEE Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME FIXER PART A o Days On Site o PARTZ BLEACH FIXER o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS// o o 7783_18_8° STATE ~i~ TYPE ~i~ PRESSURE ~i TEMPERATURE ~i~ CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~~5~~5i AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o 0.16GAL o 2.00 GAL o 2.00 GAL o i~i~~ HAZARDOUS COMPONENTS ~~i~i~~~i %Wt. o o RSo CAS// o 33.00OAmmonium Thiosulfate ONo o 7783188° 20.00OAmmonium Sulfite ONo o 10196202° 7.00°Ammonium Nitrate ONo o 6484522° 7.00°Acetic Acid, Pure ONo o 64197° i~i~i~i~~O HAZARD ASSESSMENTS ~i~~i~~i~i °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o No ONoONo o No/ Curies° RIH o /// o OHio -5- 05/08/2000 LONGS DRUG STORE//417 ~fi~~~6~~ SitelD: 215-000-001842 iff Inventory Item 0007 ~~6~ Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME ~~~~~i~~~ FIXER PART B o Days On Site o PART B BLEACH FIXER o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS// o o 10043-01-3 o i6 STATE ~i6 TYPE ~i~ PRESSURE ~6~i TEMPERATURE ~i~ CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER ° f~a~5~5~5~ AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o 0.25 GAL o 10.00 GAL o 10.00 GAL o f~5~~~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS// o 27.00OFerric Ammonium Ethylene Diamine Tetraacetic Acid °No o 0o 17.00OAmmonium Bromide ONo o 12124979° 3.00ONitric Acid (EPA) ONo o 7697372° i~55~ai~Si~55fii555~5555~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT//o MCP o No °Yes°No o No/ Curies o RIH o /// o OLowO iE Inventory Item 0008 E~EEEEEEEEEEEEE Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME DEVELOPER o Days On Site o DEVELOPER STARTER o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS// o o o STATE ~5 TYPE 5~i5~ PRESSURE ~5i TEMPERATURE 55i~555 CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o ~eeeeeeeeeeeeeeeeeeeeeaee~e] AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o 0.16 GAL o 3.00 GAL o 3.00 GAL ° ~555~5~555~555~555 HAZARDOUS COMPONENTS %Wt. o o RSo CAS// o 10.00opotassium Carbonate ONo o 584087° 7.00°Sodium Bicarbonate ONo o 144558o 5.00°Potassium Chloride °No ° 7447407° i~i~5i~i~58~5~8~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT//o MCP o No ONoONo o No/ Curies° o /// o OLowO -6- 05/08/2000 LONGS DRUG STORE//417 ise~eeei~isiieeeeisi~i~eeisisise~i~i~i~eeiii5 SiteID: 215-000.001842 f~ Inventory Item 0009 ~~ee Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME ~~~~~i~~~ DEVELOPER PART A o Days On Site o o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS// o o 7757-83-7 o i~ STATE ~i~ TYPE eeei~ PRESSURE ~ee~ TEMPERATURE ~e~e~ CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o ~~~~ AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o 0.25GAL o 5.00 GAL o 5.00 GAL o i~i~~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS// o 33.00opotassium Carbonate ONo o 584087° 3.00°Sodium Sulfite ONo o 7757837° i~i~i~i~~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT//o MCP o No ONoONo o No/ Curies° RIH o /// o OHi Inventory Item 0010 ~~~ Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME DEVELOPER PART B o Days On Site o o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS// o o 74_19_7° STATE ~ie TYPE ~i~ PRESSURE e~ei TEMPERATURE ~i~ CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~~~~i AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o 0.12 GAL o 5.00 GAL o 5.00 GAL o %Wt. o o RSo CAS// o 70.00OAcetic Acid Solution ONo o 64196° 5.00°Hydroxylamine Sulfate ONo o 10039540° 5.00°Phosphoric Acid ONo o 7664382° iEEEEEEEiEEEiEEEEEEiEEEEEEEEEEE HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT//o MCP o No ONoONo o No/ Curies°F RIH o /// o OLowO -7- 05/08/2000 LONGS DRUG S TORE #417 EEEEEEEEEEEEEEEEEEEEEEEEEEEEEEE SitelD: 215-000-001842 iE Inventory Item 0011 ~EE~E~EEEEE~E Facility Unit: Fixed Containers at Site iEE COMMON NAME / CHEMICAL NAME DEVELOPER PART C o Days On Site o o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS# o 111_30_8° iE STATE EiE TYPE EEEiEE PRESSURE EEEi TEMPERATURE EEiEEEE CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~5~55~5~5~i AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o 0.25 GAL o 5.00 GAL ° 5.00 GAL o i~i~~5¢~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS# o 16.00 op_Phenylenediamine ONo o 106503° 1.00°Sodium Sulfite ONo o 7757837° iEE~EE6i~E6iEE~EEEiEEEEEEE6EEE HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o. NFPA o USDOT# o MCP o No ONoONo o No/ Curies° RIH o /// o OModO iE Inventory Item 0012 EEEEEEEEEEEEEEE Facility Unit: FiXed Containers at Site iE~ COMMON NAME / CHEMICAL NAME o PHOTOGRAPHIC DEVELOPERS o Days On Site o o PART A BLEACH DEVELOPER o 365 o o Location within this Facility Unit Map: Grid: · 0 PHOTO LAB o CAS# o o o 123_31_9° i~ STATE ~i~ TYPE ~i~ PRESSURE ~i TEMPERATURE ~i~ CONTAINER TYPE o Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~~~~i AMOUNTS AT THIS LOCATION o Largest Container o Daily Maximum o Daily Average o o GAL o GAL o GAL i~i~~ HAZARDOUS COMPONENTS o %Wt. o oRSo CAS# o o 30.00OAmmonium Bromide ONo o 12124979° o 10.00ODisodium EDTA ONo o 139333° i~i~i~i~~ HAZARD ASSESSMENTS ~i~~i~55i~ °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o o No ONoONo o No/ Curies° RIH o /// o OModO -8- 05/08/2000 LONGS DRUG STORE #417 ~b~~g~8~~ SiteID: 215-000-001842 ~ Inventory Item 0013 ~~~ Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME PHOTOGRAPHIC DEVELOPERS o Days On Site o PART B BLEACH DEVELOPER o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS# o . o 123_31_9° i~ STATE ~i'~ TYPE ~ PRESSURE ~ TEMPERATURE ~i~5 CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~~~~e~] AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o O.l~ GAL o lO GAL o I C} GAL o i~i'~~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS# o 29.00OFerric Ammonium EDTA °No o 0o 19.00OAmmonium Bromide ONo o 12124979° i~i~i~i~~ HAZARD ASSESSMENTS ~i~~i~~i~ °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o No ONoONo o No/ Curies° RIH o /// o OModO Inventory Item 0014 '~~~ Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME PHOTOG~PHIC FIXERS o Days On Site o BLEACH FIXER. o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS~ o o 64_19_7° STATE 5~ TYPE 55~i55 PRESSURE 555] TEMPE~TU~ 5~ CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~~~~i AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average · 0 OAL o OAL o OAL o %Wt. o o RSo CAS~ o 49.00OA~onium Thiosulfate ONo o 7783188° 3.00°Sodium Sulfite ONo o 7757837° 3.00°Sodium Bisulfite ONo o 7631905o °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT~ No ONoONo o No/ Curies° RIH o /// o OModO -9- 05/08/2000 LONGS DRUG STORE #417 ~~~~~ SitelD: 215-000-001842 i~ Inventory Item 0015 ~~~ Facility Unit: Fixed Containers at Site i~ COMMON NAME/.CHEMICAL NAME PHOTOGRAPHIC CHEMICALS o Days On Site o SAFER STABILIZER o 365 o Location within this Facility Unit Map: Grid: PHOTO LAB o CAS// o o o i~ STATE ~i~ TYPE ~i~ PRESSURE ~i TEMPERATURE ~i~5 CONTAINER TYPE Liquid o. Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~~~~i AMOUNTS AT THIS' LOCATION Largest Container o Daily Maximum o Daily Average o O.O~' GAL° I GAL° I GAL° i~i~~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS// o 15.00o 1,2;4_Triazole ONo o 288880° i~i~i~i~~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT//o MCP o No ONoONo o No/ Curies°F DH° /// o OLow InVentory Item 0016 ~~~ Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME PROPANE o Days On Site o o 365 o Location within this Facility Unit Map: Grid: 999999999 o CAS// o "~-ahi'._~J~5 ~0~ o 74_98_6° STATE ~ TYPE 5~5~55 PRESSURE ~ TEMPERATURE ~]88~ CONTAINER TYPE Gas o Pure o Above Ambient o Ambient o PORT. PRESS. CYLINDER o i~~~~i AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o 188.00FT3 o 360.00 FT3 o 360.00 FT3 o i~i~~ HAZARDOUS COMPONENTS ~~i~i~~~i %Wt. o o RSo CAS// o 100.00Opropane OyesO 74986° i8~8~i~i~i~8~8~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o No ONoONo o No/ Curies°FP IH o /// o ~ -10- 05/08/2000 i LONGS DRUG STORE #417 ~~~~~ SiteID: 215-000-001842 f~ Inventory Item 0017 ~~~ Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME o HELIUM ° Days On Site o o 365 o ° Location .within this Facility Unit Map:' Grid: o I-' ~O11.3 ~ o CAS# o o [4 _ .Otctt o 7440_59_7o ~ STATE ~]~ TYPE ~5 PRESSURE ~ TEMPERATURE o Gas o Pure o Above Ambient o Ambient o PORT. PRESS. CYLINDER o i~~5~~i AMOUNTS AT THIS LOCATION o Largest Container o Daily Maximum o Daily Average o o 244.00FT3 o 7.~_i~2qtg?00 FT3 o -1~244.GG FT3 o i55~8~i~56558888 HAZARDOUS COMPONENTS o %Wt. ° o RSo CAS# o o 100.00OHelium ONo o 7440597° i~i~i~i~~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o o No ONoONo o No/ Curies°FP IH o /// o OMinO Inventory Item 0018 888~6~8~88 Facility Unit: Fixed Containers at Site i~ COMMON NAME / CHEMICAL NAME CHLORINE o Days On Site o CHLORINATING LIQUID o 365 o Location within this Facility Unit Map: Grid: BACK STORAGE RM RACK-WHS 21 o ' CAS# o o 7882-50-5 o STATE ~i~ TYPE a88i88 PRESSURE aS~i TEMPERATURE Gas ° Pure o Above Ambient o Ambient o PLASTIC CONTAINER o i~~~~Si AMOUNTS AT THIS LOCATION ~~~~i Largest Container o Daily Maximum o Daily Average o 1.00 GAL ° 128.00 GAL o 64.00 GAL o i~i~~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS# o 10.00OSodium Hypochlorite °No o 7681529° iEE~Ei~EEi~EE~i~EEE~SEE~E HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o No ONoONo o No/ Curies°FP IH o /// - 11- 05/08/2000 i LONGS DRUG STORE #417 EEEEEEEEEEEEEEEEEEEEEEEEEEEEEEE SitelD: 215-000-001842 i i~ Notif./Evacuatio~Medical ~~EE~E~~E~E~ Overall Site i i~ Agency Notification ~~~E~~~~ 02/17/1998 i o o o DIAL 911 FOR EMERGENCY RESPONSE AND LET THEM ~OW OF HAZARDOUS MATE~ALS ON o o SITE. o o O iEEE Employee Notif./Evacuation E~EE~EE~EEE~EEE~EEE~EEE~E 02/17/1998 i O o o VENAL NOTIFICATION/SHoUTING/PA SYSTEM. o EVACUATE STORE THROUGH NEAREST EXIT (2 FRON DOORS & EMERGENCY EXIT ON S o SIDE) THEN MEET AT DESIGNATED MEETING AREA IN FRONT OF STORE. o o o O o DIAL 911. o o - 12- 05/08/2000 i LONGS DRUG STORE #417 ~~~~~ SiteID: 215-000-001842 i~ Mitigation/Prevent/Abatemt ~~~~~ Overall Site i i~ Release Prevention ~~~~~~~ 02/17/1998 i o o o PRODUCT MATERIALS ARE TRANSFERRED IN SMALL QUANTITIES. o o RESIDUAL PRODUCT MATERIALS STORED IN SECONDARY CONTAINMENT. o o WASTE TREATMENT UNIT IS SECONDARILY CONTAINED. o o O i~i~ Release Containment ~~/~6~fi/~/~/~/~6/~ 02/17/1998 i o o o MAINTAIN RIGID HOUSEKEEPING PROGRAM. o ° USE SMALL QUANTITY CONTAINERS AND SECONDARY CONTAINMENT. o ° WASTE TREATMENT UNIT OPERATED AS BATCH PROCESS ONCE DAILY. o o o i~ Clean Up ~~~~~~~.~ 02/17/1998 o o o ALL MINOR SPILLS CLEANED UP USING SPILL ABSORBENT MATERIALS AND SPILL KITS. ° ° SPILL CLEAN UP MATERIALS CONTAINERIZED AND PROPERLY LABELED. ° O O ieeaee Other Resource Activation o o o o -13- 05/08/2000 i LONGS DRUG STORE #417 ~fifi~fififi~fififi~fifi~ SitelD: 215-000-001842 i~ Site Emergency Factors ~~~~~~ Overall Site i~ Special Hazards o o o O i~ Utility Shut-Offs ~~~~~~~ 02/17/1998 o o ° A) GAS - OUTSIDE E FACING BLDG WALL NEAR NE CORNER o ° B) ELECTRICAL - OUTSIDE E FACING BLDG WALL NEAR NE CORNER o °C) WATER - OUTSIDE E FACING BLDG WALL NEAR NE CORNER ° °D) SPECIAL - SPRINKLER, INSIDE AT NE CORNER OF STORE o ° E) LOCK BOX - NO o o o ~ Fire Protec./Avail. Water ~~~~~ 02/17/1998 o o o PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS LOCATED NEAR 2 FRONT ENTRANCES o o AND NEAR EMERGENCY ENTRANCE (S SIDE OF STORE) SPRINKLERED,BLDG. ° o o O O o o o NEAREST FIRE HYDRANT - OUTSIDE S OF SW CORNER OF STORE. o o o i~ Building Occupancy Level o o o o -14- 05/08/2000 LONGS DRUG STORE #417 i~ Training ~~~~~~~~ Overall Site i~ Employee Training ~~~~~~~ 02/17/1998 o WE HAVE 40 EMPLOYEES AT THIS FACILITY. o o WE DO HAVE MSDS SHEETS ON FILE NEAR THE'PHOTO LAB AREA. o o BRIEF SUMMARY OF TRAINING PROGRAM: 30 MINUTE VIDEO AND WORKSHEETS WITH o ANNUAL REFRESHER. o O o o i~ Held for Fumre Use O O i~¢~ Held for Fumre Use O o CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3ra Floor, Bakersfield, CA 93301 FACILITY NAME d._,O,x~ ''~ ~--4'"7 INSPECTION DATE ~/[}/°0 Section 4: Hazardous Waste Generator Program EPA ID # ~',4--r._ OOO / "7 ~ d I~ [] Routine [~(C_..ombined [] Joint Agency [] Multi-Agency [] Complaint [] Re-inspection OPERATION C V COMMENTS Hazardous xvaste determination has been made EPA ID Number (Phone:916-o_4-1781 to ohtain EPA ID #) waste treatment and/or storage Authorized fbr Reported release, tire, or explosion within 15 days ofoccurance ( Established or maintaius a contingency plan and training Hazardous waste accumulation time frames Containers in good condition and not leaking Containers are compatible xvith the hazardous waste / Containers are kept closed xvhen not in use Weekly inspection of storage area Ignitable/reactive waste located at least 50 feet from property line Secondary containment provided Conducts daily inspection of tanks Used oil not contaminated with other hazardous waste Proper management of lead acid batteries including labels Proper management of' used oil filters Transports hazardous waste with completed manifest Sends manifest copies to DTSC Retains manifests tbr 3 years Retains hazardous waste analysis fi)r 3 years ~., Retains copies of uscd oil receipts for 3 years Determines if waste is restricted fi'om land disposal C=Colnpliance V=Violation Office of Environmental Services (805)326-3979 Business Site Responsible Party \Vhite - Env. Svcs. Pink - Business Copy CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3ra Floor, Bakersfield, CA 93301 FACILITY NAME ~C3,,3~ :~t-~t? INSPECTION DATE Section 5: Hazardous Waste Tier Permit Treatment Program [] Routine .~.~mbined [] Joint Agency [] Multi-Agency [] Complaint [~ Re-inspection Onsite Treatment Unit Tier: Unit number & name: [] PBR [] CA [] CESW [] CESQT [] CEL [] CECL OPERATION C V COMMENTS All h~ardous wastes treated are generated onsite Onsite treatment notification forms available and complete Onsite treatment unit tier and/or count is correct on form Unit number is correct on notification tbrm ( Number of tanks or containers is correct on form Treatment monthly volume is correct on tbrm Waste identification & treatment is correct on form Complies with residual management requirements ./ Properly closed a treatment unit Complies with tank and containment certification Developed and maintains a written inspection log Meets pretreatment standards for waste discharge Developed and maintains a Closure Plan on site IPBRI Developed and maintains a Waste Analysis Plan and Waste Analysis Records [PBR] Maintains Training Records on site IPBRI Obtained local permits for treatment operations [PBR[ Identifies and labels Treatment Units IPBRI C=Compliance V=Violation ~.~..~..~ Inspector: /.~t r~c> ~ Office of Environmental Services (805) 326-3979 Business Site Responsible Party CA=Conditionally authorized CESW=Conditionally exempt specified wastestream CECL=Conditionally exempt commercial laundry CESQT=Conditionally exempt small quantity treatment CEL=Conditionally exempt limited PBR=Permit by rule White - Env. Svcs. Pink ~ Business Copy CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3rd Floor, Bakersfield, CA 93301 FACILITY NAME ~/£ ~ ..t~ t~ INSPECTION DATE d/It/OO FACILITY CONTACT ~/X,.3 C.-/'~ro.,,J BUSINESS ID NO. 15,210- INSPECTION TIME NUMBER OF EMPLOYEES Section 1: Business Plan and Inventory Program [] Routine ~ombined [] Joint Agency [] Multi-Agency [] Complaint [] Re-inspection OPERATION C V COMMENTS Appropriate permit on hand Business plan contact information accurate Visible address Correct occupancy Verification of inventory materials .~C3~-'~C--O ~'t4t. c.~.~dC-- Verification of quantities Verification of location Proper segregation of material Verification of MSDS availability Verification of Haz Mat training Verification of abatement supplies and procedures Emergency procedures adequate Containers properly labeled Housekeeping Fire Protection Site Diagram Adequate & On Hand C=Compliance V=Violation Any hazardous waste on site?: ./~l..Yes [] No Questions regarding this inspection? Please call us at (661) 326-3979 Business Site Responsible Party White - Env. Svcs. Yellow - Station Copy Pink - Business Copy Inspector: ~ CITY OF BAKERSFIELI~ OFFICE OF ENVIRONMENTAL SERVICES 1715 Chester Ave., CA 93301 (661) 326-3979 "~'"~~~'" ~' H~RDOUS MATERIALS INVENTORY CHEMICAL DESCRIPTION (one ~ per mate~al ~er bu~d~ or a~) ~ NEW ~ ~ DE~ ~ R~ISE ~ Page 8USINES~ ~E (~e ~ FACIL~ ~E ~ D~ - ~n9 8~ ~) 3 ~ ~ ~1 CHEMI~LLO~TION ~ Y~ ~ ~ ~2 CHEMI~L ~E t ff Subj~ to EPC~ COM~N ~ EHS* ~0 . ~PE ~ p ~ ~ m ~ ~ w WA~ 211 ~D~A~ ~ Y~ ~ ~ 212 ~ CURIES ~3 P~SI~L STA~ ~ s ~LID ~1 L~UID ~ g ~S 214 ~RGEST ~NNER ~ ~5 FED ~ ~ES ~ 1 FI~ ' ~ 2 ~ ~ 3 ~ ~E ~ 4 A~ H~L~ D 5 ~RONIC H~ ~6 DAYS ON STOOGE ~AINER ~ a ~VEG~UND T~K ~ · ~N~IC ~UM ~ i FIBER DRUM ~ m ~S BO~E ~ q ~IL ~R (Check ag ~at ap~) ~ b UN~RG~UND TANK ~ f ~ ~ j ~G ~~C BO~LE D r O~ER ~ c T~K INSI~ BUILDtNG ~ g ~Y ~ k BOX ~ o TO~ ~ d ~ ~UM ~ h SILO D I ~LINDER ~ p T~K WA~N STOOGE P~SSU~ IE~ D ~ A~VE A~I~ ~ ba BELOW A~I~ ~4 5 242 243 ~ Y~ ~ ~ 2~ PR~ ~ME & ~E OF A~OR~D ~MPA~ ~SE~A~E SI~TU~ OA~ UPCF (7/99) S:~CUPAFORMS~OES2731.TV4.wlXl LONGS DRUG STORE #417 ~4JD~..i~i V i~i3 SiteID: 215-000-001842 Manager : BRUCE HUNTERI FEB>!7 1998 BusPhone: (805) 588-0290 Location: 4400 COFFEE RD| ~/~ ~ Map : 102 CommHaz : City : BAKERSFIELD .IBy· ~ Grid: 16C FacUnits: 1 AOV: CommCode: COUNTY STATION 65 SIC Code: EPA Numb: CAL000176616 DunnBrad: Emergency Contact / Title Emergency Contact / Title BRUCE HUNTER / MANAGER JOHN MENDIOLA / ASST MANAGER Business Phone: (805) 588-0290x Business Phone: (805) 588-0290x 24-Hour Phone : (805) 871-3201x 2A-Hour Phone : (805) 664-9769x Pager Phone : ( ) - x Pager Phone : ( ) - x Hazmat Hazards: React DelHlth Emergency Directives: WASTE TREATMENT SITE: CONTACT 326-3979 FOR JOINT HAZ-MAT INSPECTION ~ Hazmat Inventory One Unified List -- MCP+DailyMax Order Ail Materials at Site Hazmat Common Name... ISpeoHazlEPA HazardsI Frm DailyMax Unit MCP CLEANER DH L 55 GAL Mod WASTE DEVELOPER R L 30 GAL Min r~vl~ed ~he a~ach~ h~e~ous ma~e~a~s ma~ge- p~an an~ corra~io~ constitute a ~mpls~s and corre~ man- agem~ p~an for m~ ~cili~. -1- 01/16/1998 LONGS DRUG STORE #417 SiteID: 215-000-001842 ~ Inventory Item 0002 Facility Unit: Fixed Containers at Site CLEANER Days On Site SURTEC FLOOR CLEANER 365 Location within this Facility Unit Map: Grid: INSIDE JANITOR'S CLOSET IN BACK STOREROOM CAS# F STATE ~ TYPE PRESSURE i TEMPERATURE CONTAINER TYPE Liquid Mixture Ambient Ambient PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container I Daily Maximum Daily Average 5.00 GALI 55.00 GAL 5.00 GAL HAZARDOUS COMPONENTS %Wt. EHS CAS# 6.00 Diethylene Glycol Monoethyl Ether No 111900 HAZARD ASSESSMENTS TSecret EHS BioHaz Radioactive/Amount EPA HazardsI NFPA I USDOT# I MCP No No No No/ Curies DH / / / Mod = Inventory Item 0001 Facility Unit: Fixed Containers at Site ~lV~Vl~£~ ~Vl~ / ~l ~ZA_b ~Vl~ WASTE DEVELOPER Days On Site PHOTOGRAPHIC DEVELOPER WASTE 365 Location within this Facility Unit Map: Grid: INSIDE SE END OF BACK STOREROOM CAS# FSTATE ~ TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid /Waste I Ambient I Ambient DRUM/BARREL-NONMETAL AMOUNTS AT THIS LOCATION Largest Container ~ Daily Maximum Daily Average 15.00 GALL 30.00 GAL 15.00 GAL HAZARDOUS COMPONENTS %Wt. I EHS CAS# I Silver No 7440224 HAZARD ASSESSMENTS TSecret EHS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R / / / Min 2 01/16/1998 F LONGS DRUG STORE #417 SiteID: 215-000-001842 Fast Format = Notif./Evacuation/Medical Overall Site --Agency Notification 01/16/1998 POSTED IN MDSD BINDER IN PHOTO DEPT. Employee Notif./Evacuation Public Notif./Evacuation Emergency Medical Plan -3- 0 /16/1998 LONGS DRUG STORE ~417 SiteID: 215-000-001842 Fast Format F Mitigation/Prevent/Abatemt Overall Site Release Prevention -- Release Containment 01/16/1998 SPILL KIT -- Clean Up 01/16/1998 SAFETY-KLEEN Other Resource Activation -4- 01/16/1998 F LONGS DRUG STORE #417 SiteID: 215-000-001842 I Fast Format ~ Site Emergency Factors Overall Site ~ Special Hazards --Utility Shut-Offs 01/16/1998 A) GAS - OUTSIDE NE CORNER OF STORE BLDG B) ELECTRICAL - OUTSIDE NE CORNER OF STORE BLDG C) WATER - OUTSIDE E SIDE OF PROPERTY D) SPECIAL - NONE E) LOCK BOX - NO -- Fire Protec./Avail. Water 01/16/1998 PRIVATE FIRE PROTECTION - SPRINKLERED BLDG & PORTABLE EXTINGUISHERS. NEAREST FIRE HYDRANT - OUTSIDE SW CORNER OF BLDG IN PARKING LOT. Building Occupancy Level -5- 01/16/1998 LONGS DRUG STORE #417 SiteID: 215-000-001842 Fast Format = Training Overall Site -- Employee Training 01/16/1998 WE HAVE 33 EMPLOYEES AT THIS FACILITY. WE DO HAVE MSDS SHEETS ON FILE IN THE PHOTO DEPT. BRIEF SUMMARY OF TRAINING PROGRAM: VIDEO, SAFETY MEETINGS AND TRAINING RECORD AVAILABLE IN PHOTO DEPT. Page 2 Held for Future Use Held for Future Use -6- 01/16/1998 CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3r~ Floor, Bakersfield, CA 93301 FACILITY NAME /_~>.MC '.q g:~ 'dr'('~ INSPECTION DATE ('T/3<5/~7 Section 5: Hazardous Waste Tier Permit Treatment Program [2] Routine ~l Combined [21 Joint Agency [21 Multi-Agency [21 Complaint [21 Re-inspection Onsite Treatment Unit Tier: Unit number & name: ~1-7 [~l PBR [2ICA ~CESW [~ CESQT [21CEL [2[ CECL OPERATION C V COMMENTS All h~ardous wastes treated are generated onsite Onsite treatment notification forms available and complete Onsite treatment unit tier and/or count is correct on form Unit number is correct on notification form b Number of tanks or containers is correct on form Treatment monthly volume is correct on form Waste identification & treatment is correct on form Complies with residual management requirements Properly closed a treatment unit Complies with tank and containment certification Developed and maintains a written inspection log Meets pretreatment standards for waste discharge and maintains a Closure Plan on site [PBRI Developed Developed and maintains a Waste Analysis Plan and Waste Analysis Records [PBRI Training Records on site [PBRI Maintains Obtained local permits for treatment operations IPBRI Identifies and labels Treatment Units IPBRI C=Compliance V=Violation Inspector: ~) t tr~f~.~q' Office of Environmental Services (805) 326-3979 Business Site Responsible Party CA=Conditionally authorized CESW=Conditionally exempt specified wastestream CECL=Conditionally exempt commercial laundry CESQT=Conditionally exempt small quantity treatment CEL=Conditionally exempt limited PBR=Permit by role White - Env. Svcs. Pink - Business Copy CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3ra Floor, Bakerstield, CA 93301 FACILITY NAME ~O"'JO 5 'qL ~ t'~ INSPECTION DATE /'~/~r--) Section 4: Hazardous Waste Generator Program EPA ID # ~,C OOO I "2 ~ro IF::, [] Routine ~ Combined [] Joint Agency [~ Multi-Agency [] Complaint [] Re-inspection OPERATION C V COMMENTS Hazardous xvaste determination has been made EPA ID Number (Phone:916-324-1781 to ohtain EPA ID #) .~' Authorized for waste treatment and/or storage Reported release, fire, or explosion within 15 days ofoccurance or maintains a contingency plan and training Established Hazardous waste accumulation time fl'ames Containers in good condition and not leaking Containers are compatible with the hazardous waste Containers are kept closed ~vhen not in use Weekly inspection of storage area Ignitable/reactive waste located at least 50 feet from property line Secondary containment provided Conducts daily inspection of tanks Used oil not contaminated with other hazardous waste Proper management of lead acid batteries including labels Proper management of used oil filters Transports hazardous waste with completed manifest Sends manifest copies to DTSC Retains manifests fbr 3 years Retains hazardous waste analysis for 3 years Retains copies of used ()il receipts tbr 3 years Determines if waste is restricted fi-om land disposal ~ /.~ C=Compliance V=Violation Inspector: ~.~t ¢'/~S Office of Environmental Services (805) 326-3979 Business Site Responsible Party White - Env. Svcs. Pink - Business Copy CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3ra Floor, Bakersfield, CA 93301 Lodr_,-'s ~ 4~"/ INSPECTION DATE ~'"~/'~/~"~ FACILITY NAME ADDRESS 4-Z4'OO PHONE NO. FACILITY CONTACT ~fLtZ.~ t4-O,,aa'-t:-rC BUSINESS ID NO. 15-210- t,dC--o0 INSPECTION TIME t'S'-oe-.) NUMBER OF EMPLOYEES '~O a-- Section 1: Business Plan and Inventory Program [21 Routine .~ Combined 1~ Joint Agency I~ Multi-Agency l~ Complaint ~j Re-inspection OPERATION C V COMMENTS Appropriate permit on hand Business plan contact infbrmation accurate Visible address i/ Correct occupancy Verification of inventor),' materials ../ Verification of quantities Verification of location Proper segregation of material Verification of MSDS availability Verification of Haz Mat training v/ Verification of abatement supplies and procedures ./" Emergency procedures adequate Containers properly labeled :V" Housekeeping Fire Protection Site Diagram Adequate & On Hand C=Compliance V=Violation~'~ Any hazardous waste on site?: 't~;Yes I~1 No Explain: ~tA~$ ~'C- ~'t-tO T~t. lt~_ ~-~2~.uq~a,X] ~t,/ . _ . . Questions regarding this inspection.'? Please call us at (805) 326-3979 Business Site Responsible Party While- Env. Svcs. Yellow- Station Copy Pink- Business Copy Inspector: I HAZARDOUS MATERIALS MANAGEMENT PLAN Longs Drug Store No. 417 4400 Coffee Road Bakersfield, CA I February 5, 1998 I ! .! I CITY OF BAKERSFIELD OFFICE OF ENVIRONMENTAL SERVI :C. ES I 1715 Chester Ave., Bakersfield, CA-(805) 326 3979 I I 1. To avoid further action, return this form within 30 days of'receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. I 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. I SECTION 1: BUSINESS IDENTIFICATION DATA I SECTION 2: EMERGENCY NOTIFICATION CONTACT TITLE BUS. PHONE 24 HR. PHONE I I 1 ELAZARDOUS MATER/ALS MANAGEMENT PLAN SECTION 3: TRAININ~ NUMBER OF EMPLOYEES: MATERIAL SAFETY DATA SHEETS ON FILE: BRIEF SUMMARY OF TRAINING PROGRAM: SECTION 4: EXEMPTION REQUEST I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAPTER 6.95 OF THE "CALIFORNIA HEALTH & SAFETY CODE" FOR THE FOLLOWING REASONS: ~ WE DO NOT HANDLE HAZARDOUS MATERIALS. ~ WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIME EXCEED THE MINIMUM REPORTING QUANTITIES. ~ OTI-IER (SPECIFY REASON) SECTION 5: CERTIFICATION I, .~/,~/~ Z~-v-~ CEP. TIF¥ T~T T~ A~OVE ~,~ s,~r¥ cor, s" o~ ~z~ovs ~t~,u.s 0~,v. ~o c~a,~. ~.~,~ s~c. 2~oo INACCURATE INFORMATION CONSTITUTES PERJURY. ~NA~ ' ' TiT~E " ' eDATE I 2 ItAZARDOUS MATERIALS MANAGE~NT PLAN SECTION 6: NOTIFICATION AND EVACUATION PROCEDURES A. AGENCY NOTIFICATION PROCEDURES: B. EMPLOYEE NOTIFICATION AND EVACUATION: C. pUBLIC EVACUATION: D. EMERGENCY MEDICAL PLAN: FLOOR MAP (Inside) LONGS DRUG STORE #417 COUNTY: KERN 4400 COFFEE ROAD BAKERSFIELD, CA 95508 DATE: Januo~ 1998 , N II I cos G S FE lEI -- FI LONOS DRUGS ~J ¢ PARKING LOT ~ ~ J ~ o ~ EMPLOYEE EMERGENCY ~ ME~ING AREA ~ PL RECIEVlNG LEGEND MSDS ~ FE CS Checkstonds J-E-I RX Pharmacy -= COS Cosmetics PL Photo Lab lEI Entrances I-E-I Emergency exits ----- Evacuation routes FE Fire extinguishers NOT TO SCALE PL Location of Photo Lob PLW Location of Photo Lob waste MSDS Location of Photo Lab Material Safety Data Sheets E Electrical utility shutoff G Gas utility shutoff W Water utility shutoff AS Automatic fire sprinkler EE Emergency equipment (spill cleon-up kit, dikes) SITE MAP (Outside) LONGS 'DRUG STORE #417 COUNTY: .. KERN 4400 COFFEE ROAD BAKERSFIELD, CA 95508 DATE: January 1998 HAGEMAN N BUSTER SHOPS S I SHOPS CARL'S JR I SHOPS BofA , PARKING LOT VONS o SHOPS r~ I..0 m o //,,O LONGS SHOPS (SD) DRUGS Employee Emergency Meeting _ Area m I (STD) (H) LEGEND lEI Entrances NOT TO SCALE [-E-I Emergency exits (EM) Employee emergency meeting area. (S'rD) Storm drain outlets (SD) Sewer drains (H) Fire hydrants (SS) Outside sprinkler system connection E Electrical utilif:y shutoff G Gas utility shutoff W Water utility shutoff Parking lot EMERGENCY EVACUATION PLAN I If a store evacuation is necessary, it is important that you are prepared and know how to respond i quickly and efficiently. Following is a list of what to do in the event of an emergency evacuation. You may be notified of the evacuation in several ways: * An announcement over the store intercom system I * A verbal from member of co-worker message a management or a IF YOU HEAR AN EMERGENCY EVACUATION ANNOUNCEMENT I ~ STOP. what you are doing. · LISTEN to any specific instructions I · FOLLOW the instructions · VACATE the building in a calm and orderly manner i Remember that while you know where the exits are, customers may not. Therefore, you must direct , them to the exits. I DOORS The front doors marked "IN" open to the outside when pushed. This is a safety feature. A manager I: · will demonstrate how the doors open outward. I ASSIGNMENTS I First Cashier · Go to the main "OUT" door at the front of the store. · Push the door out. Stand outside the door and hold it open standing to the side. I Cosmetic Clerk · Go to the "IN. door by the trial size bins. · Push the automatic rocker switch to "Hold Open." · Stand outside thedoor. I · If the "Hold Open" does not function, push the door and hold it open open, standing to the side. I Second Cashier * Go to the "OUT" door by the Photo Department and follow the same procedure as the First Cashier. I Photo Clerk * Go to the Emergency Exit in the north warehouse. · Open the Exit door. · Hold the door open, standing to the side. I Receiving * Open the receiving door. · Hold it open. I Emergency Evacuat' Employee Handout Pharmacy · Exit to the front or back of store. · Pharmacy personnel should take different aisles when exiting and direct customers to accompany them as they exit. Office and · Exit through the Receiving door if possible. Mez~_~nine · If it is closed, exit through the Emergency Exit in the north warehouse. · Office personnel should direct customers to accompany them as they exit. All Other Personnel · Exit using the closest exit door, directing customers to accompany them as they exit. ! MEETING PLACE I Meet in the front parking lot ' ;. A manager will verify attendance by using the daily schedule sheet. 1 I i I I I wpc:evac4Oe.mem Attachment i EMERGENCY PROCEDURES , EVACUATION Should an evacuation of part or all of the building be required, it will be announced by a manager via the store intercom. · AVOID PANIC, BE CALM, EVACUATE AS DIRECTED. · Advise customers to follow clearly marked exits. · Stay clear until directed otherwise. MEDICAL · Notify a manager immediately. EMERGENCY · Avoid moving victim. · Dial 911 if situation in any way appears life-threatening. · Ask loudly for assistance; ask nearest person to please notify a pharmacist. POWER OUTAGE · Remain at your workstation until told otherwise. · Ask customers to remain calm and not to move. Remember, you are familiar with the store floor plan; however, customers are not and may injure themselves. · Wait until you receive further instructions from a manager. EARTHQUAKE · Be calm. · · Stay inside. · Move away from windows and cabinets. · Assist customers in taking cover and staying away from windows. · Extinguish open flames. · Do not run through building. I FIRE · NOTIFY FIRE DEPARTMENT. Dial 911. Give exact location of fire and your name. · Notify manager for assistance. I · Move clear of the fire area and in a loud, clear voice, ask everyone to immediately leave the store. I BOMB THREAT · Be calm. · Listen, be alert and businesslike. · Keep caller on the line, signal someone for help to notify ama, nager. I · Repeat instructions, take detailed notes. · Ask for bomb location and when it is to go off. · Inform caller that building is occupied. I · Note caller's voice, background noise, etc. · DO NOT TOUCH ANYTHING SUSPICIOUS. I wpc:evacemp.mem (04/19/93) After reading the following statement, please sign and return to the store manager. UNDERSTANDING SAFETY I have read and understand the Emergency Evacuation Plan and the Emergency Procedures information. I understand how to safely evacuate this building in the event of an emergency. I will follow all instructions to the best of my ability without jeopardizing my safety and the safety of others in the event of an emergency evacuation. Signature Date wpczevacAOe.mem Attachment (02/17/94) ,i I HAZARDOUS MATERIALS MANAGEMENT PLAN I SECTION 7: M/TIGATION, PREVENTION AND ABATEMENT PLAN i A. RELEASE PREVENTION STEPS: B. RELEAS£ CONTAINMENT AND/OR MINIMIZATION: I C. CLEAN-UP PI~OCEDURES: I SECTION 8: UTILITY SHUT-OFFS _(LOCATION OF SHUT-OFFS AT YOUR FACILITY) LOCK BOX: YES/NO IF YES, LOCATION: ISECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABILITY I A. PRIVATE FIRE PROTECTION: P'IVW_.~ ~'~Vt~Ut~ 'l~ ~ I B. WATER AVAILABILITY (FIRE HYDRANT): ~ovCn o~ ~ ~ 1 I 4 I CITY OF BAKERSFIELD OFFICE OF ENVIRONMENTAL SERVICES I 1715 Chester Ave., Bakersfield, CA (805) 326-3979 I i HAZARDOUS MATERIALS INVENTORY FACILITY DESCRIPTION I CHECK IY BUSINESS IS A FARM [ ] I I SIC CODE 0.~L~OPERATOR "g,v't/~ ~ rf~'r~ PHONE ~c..~ Cg~- -. O"hq 0 CITY $/~ ~t,~t~ ~b~ STATE 6,k ZIP E~,~,~ CONTACTS BUSINESS PHONE (ao~.') c--o~-- EYl.~ 24 HOUR PHONE ~gO~') BUSINESS ?I-IONE ~li0;) ~l~y_ - C-9~.~ ~ 24 HOUR PHONE ~gOg'~. L,O.A-' q.~-~. 1 Page --4- of Business Name [~m~.~.~ ']5~nlzt ~,J't. Lt~, ~' 4 ~ ~ Ad~ ~ ~ ~~ ~ / ~~ ~ - - C~C~ DESk. ON I) ~ORY SlA~S: ~ [ ] A~fion [ ] Rehsion [ ] ~lefi~ [~] Ch~k ffch~ is a NON Tm~ S~et [ ] T~ S~t [ ] I 4) Physi~ & H~ P~SIC~ Hazard Categofi~ Fke [ ] R~five [ ] Sudd~ Rel~ of~ ~] ImmUre H~ (Acura) [ ~ ~lay~ H~ (C~) [ l 5) WAS~ C~S~CA~ON ~ g (3~t ~ ~ D~ Fora 8022) USE CODE q~ 6) P~SIC~STA~ SoUd[ ] Liqdd[ [ I ~[ ] ~e[ [ ] ~ve[ ] 7) ~O~ ~ ~ AT FAC~ ~ OF ~~ 8) STOOGE CODES ~m D~y ~o~t ~ Lbs [ ] ~ [X ] ~ [ ] a) Cm~ I O Av~e D~y ~o~t ~ C~ [ ] b) ~: ~ ~omt ~ c) T~m g Days on Si~ ~ C~le ~ch MmV: ~ J, F, ~ & ~ L J, & S, O, N, D 9) ~: Li~ CO~~ ~ C~g ch~m~nm~or 2) ~ogola~2~ ~~1~ ~-~-;].~ ~ ~-~ [ ] 10)L~A~O~ . 1) INVENTORY STATUS: New [ ]Addition[ ]Revision[ ]Deletion[y:] Check ifchemical is a NON Trade Secret [ ]Trad~Secret[ ] 2) Common Name: ~?-~ ~'AT[. 'p~ -R~'tZ~Vt~o~/L/ ~ 1'9[-~,~ 3)DOT# (optional) Ch Same: Oo- Ampi ] 4) Physical & Health PHYSICAL HEALTH Hazard Categories Fire [ ] Reactive [ ] Sudd_lm Release of Pressure ['.. ] Immediate Health (Acute) [.~,1 Uelayed Health (chronic) [ ] 5) WASTE CLASSIFICATION P/A (3-d/git code flora DHS Form 8022) USE CODE qq 6) PHYsicAL STATE Sotid [ ] Liquid [x,,]'"~C-as [ ] lha-e [ ] Mixture [wT'~Waste [ I Radioactive [ ] 7) AMOUNT AND TIME AT FACILITY UNITS OF IVIEASURE 8) STORAGE CODES Maximum Daily Amount q- Lbs [ )q Gal [ ] fl3 [ . ] a) Container:. Average Daily Amount 2. Curies [ ] b) Pressure: ! Annual Amount ~ o c) Temperature Largest Size Container ..... Ib~ ~ ' ' Days on Site 3/.v o Circle Which Months: ~(,~, J, F, M, A, M, J, J, A, S, O, N, D 9) MIXTURE: List COlVII~NEKr I// CAS// % WI' AHM the three most hazardous 1) v- 'PLtna~l,~n,_~f/J~ ;- J-, '9~ o4~,-:~1-'~ I~ -"l~ [ ] chcmicalcomponentsor 2) '4,,~zl,'u,n., "~,tl~. ~. t~ 7r"i'6 ~- ~a.,-~ 0, ~.. 1~' [ ] any AHM components 3) [ ] I certify under penalty of law, that I have personally examined and am familiar with the information on this and all attached documents. I believe thc submitted information is true, accurate and complete. PRINT Name & Title of Authorized Company Representative Signature Date P. age 7- of I Business Name ~"~l 1~P~1~ z~0't,~ :~ 4t':P'_ Address ~:~Cag./~~, ~./~~~ -- C~C~ DESC~ON I ) [ ] { ] { ~<] a { ]TradeSecret[ ] I fNVENTORY STATUS: New Addition Revision ] Deletion Check if chemical is NON Trade Secret ~AIZ'F ~ 2) Con, non N~me: /.r~- 40 F'A ~ V t - I? ~,~/~L~'~,~ ~ ~ 3) DOT # (op~on~) 4) Physical & Health PHYSICAL HEALTH I Hazard Categories Fire [ ] Reactive [ ] Sudden Release of Pressm'e [' ~ Immediate Health (Acute) [,~Delayed Health (Chronic) [ ] 5) WASTE CLASSIFICATION N~t (3-digit code fi'om DHS Form 8022) USE CODE ~c[ I6) PHYSICAL STATE Solid[ ] Liquid [ ] Pure[ ] Mixture[ [ ] Radiative[ ] 7) AMOUNT AND TIME AT FACILrrY UN'fI'S OF MEASURE 8) STORAGE CODES I Maximum Daily Amount 7. Lbs [ ] Gal [X ] fL3 [ ] a) Container:. I o Average Daily Amount '7- Curies [ ] b) Pressure: ~on~ Amount 5_'O_ e) Tmperatu~ I # Days on Site ~f~.< Circle Which Months: , F, M, A, M, $, $, A, S, O, N, D 9) MIXTURE: List COMPONENT '~' CAS# % WT AHM the three most hazardous 1) TO'~ge-zilJ~l /~2.~z,'rv~z~.~_~-- ' C-~A- Or~-q--- "~1-4! [ ] a~yAI-IM components 3) i~;,~,;dd ~af,~- ~a d 'V,.n~tVL. ~ %a - ~'f - ~ C. _ ~ [ ] IlO)LOCATION 1) INVENrORY STATUS: New [ ]Addition[ ]Revision[ ]Deletion[ff.] Check ffchemical is a NON Trade Secret [ ]Trade,Secret[ ] 4) Physical & Health PHYSICAL HEALTH ~y~ Hazard Categories Fire [ ] Reactive [ ] Sudden Release ofPressttre [ ] Immediate Health (Acute) [ Health (Chronic) [ ] I 5) WASTE ClASS~CATION 6) PHYSICAL STATE Solid [ ] Liquid [ ~ [ ] Pure [ ] Mixture [ X/~-a~ [ ] Radioactive [ ] 7) AMOUNT AND TI2ME AT FACILITY UNITS OF MEASURE 8) STORAGE CODES Maximum Daily Amount ! O Lbs [ ] Gal I Average Daily Amount I o Curies [ ] b) Pressure: I Annual Amount Largest Size Container . # Days on Site .3 0~ (J Cimle Which Months: ~,.~, J, F, M, A, M, $, $, A, $, O, N, D 9) MIXTURE: List COMPO~ :~ CAS# % WT AHM the threemost hazardous 1) ~cl~4FH~rliOr~q T-14~,~-.~iJ~J~F~ ~rq,ir~ - ~-R' . "1,"~,-"~ [ ] i chemicalcomponentsor 2) ~,~oni'Orn 2~o'J[~,fzJ ' ~t~lqt~"e~4.-O I~ -"t~ [ ] anyAHM components 3) '.~._'~a~i urn glfr~z.~ [~4.e4o c~-~. ' ~-~' [ ] 10)LOCATION ~ II certify under penalty of law, that I have personally examined and am familiar with the information on this and all attached documents. I believe the submitted information is true, accurate and complete. I PRINT Name & Title of Authorized Company Representative Signature Date II) INVENTORY STATUS: New [ ] Addition [ ] Revision [ ] Deletion [~] Check il'chemical is a NON Trade Secret [ ] Trade Secret [ ] rA~T $ 2) Common Name: F~I;'o,~/P P'~[_'~ 'F~ol~t, '~S[_~r~a_.. i~'I*.~,o 3) DOT # (optional) 4) Physical & Health PHYSICAL HEALTH~/a I , Hazard Categories Fire [ ] Reactive [ ] Sudd~ Release ofPressure [ ] Immediate Health (Acute) [ yeti Health (Chnmic) [ ] s) WASTE CLAssn~cA'nON ~/~ (3-digit ~ ~ Dm Fo~ g022) US~- COD~. q q - 6) PHYSICAL STATE Solid [ ] Liquid [,,~C-as [ ] Pure [ ] Mixture [ ~'~ [ ] Radioactive [ ] 7) AMOUNT AND TIME AT FACILIIT UNITS OF MEASURE g) STORAGE CODES I, Maximum Daily Amount I0 Lbs[ lGal[)<lra[ I a)Conmine= I c> Average Daily Amount I ~ Curies [ ] b) Pressure: Annual Amount 2. bO ¢) Teanperatm'e I # Days on Site 3 6g'~ Circle Which Months: F, M, A, M, 1, J, A, S, O, N, D 9) MIXTURE: List COMPONENT ? CAS# % WT AItM the three most hazardous 1).104/v'~-~ l~nrnOr~i0rv~ ~-t~i~A "/.D..Or-~ ~9~q Ir4. o~.-~ [ ] I chemicalcomponontsor 2) Manrnno.iOna ~o~n;A~, h.t't..,4o q'&-q '"4.-I:1.- [ ] · ~y ama compo~ts 3) O~ti,,'C. -.~:,! - ' :~t,q,- .5.-e'-',--- 'l-~ [ I I10)LOCATION 1) INVENTORY STATUS: New [ ] Addition [ ] Revision [ ] Deletion [-/] Check if chemical is a NON Trade Secret [ ] Trade Secret ChemicalName: ~ .'~_].o-ct~' C t~'?°l~ljl/'t'f') AI-nVI[ I CAS#'5 ,I 4) Physical & Health PHYSICAL HEALTH I4a~ard Categories Fire [ ] Reactive [ ] Sudden Releas~ of Pressure [' ,: Immediate Health (Acute) [ ] Dehyed Health (Chronic) I 5 ) WASTE CLASSIFICATION ~'q.~ (3-digit code from DHS Form 8022) USE CODE 6) ?HYS~CAL STATE Solid [ I Liquid [,,~ [ I eur~ [ I Mixture [x.-~~ [ I a~,_'omive [ ] -I 7) AMOUNT AND TIME AT FACILrrY UNITS OF MEASURE 8) STORAGE CODES Maximum Daily Amount , ~ Lbs [ ] Gal ~ ] fl3 [ ] a) Containe~. I I Average Daily Amount _:~ Curies [ ] b) Pressure: Annual Amount $ o c) Temlm-ature Largest Size Container , # Days on Site 3 b~~ Circle Which Months: ~"'Y~r, J, F, M, A, Iv[, J, J, A, S, O, N, D 9) MIX'rURE: List COMPONENT CAS# % WT AHM the three most hazardous 1 ) 'P',4t'a.,~h }v'va /,arbo~at,_ r_ga. og. ~- chemical components or 2) 2.,,~A ~h~' - ?:,¢r..at, b,or~a fo [ 4,d .. r..~... ~1 ~- '~ [ anyAHM components 3) .lrotJ4"~li/rrl' ~llOlrtS:t.c-, dO. ~ q~-C [ 'O 4~m,..~ r.4~.¢/.ql&., ,'~42.., 0~-4-t-6, o;e--- I lO)LOCATION ~a ',~4f.,~'¢ ~-,~e |~.c.~. ~ II certify under penalty o£1aw, that I have personally examined and am familiar with the information on this and all attached documents. I believe the submiRed information is true, accurate and complete. I PRINT Name & Tide of Authorized Company Representative Signature Date / ~ Pa~e Business Name ~ J)~4_ 1~._ 9t'tTl-d~ ~ X[I'~ - A~ ~ ~~ ~ C~C~ DESk. ON 1) ~ORY STA~S: N~ [ ] A~on [ ] Re~sion [ ] ~lefi~ [ ] Ch~k ~ch~ is a NON T~ S~t [~ T~ S~ [ ~A~Y A Ch~N~e: ~ ~~ ~ ~U~ ~{ ] C~~ 4) Physi~ & H~ P~SIC~ ~ / H~d Categories F~e [ ] R~five [ ] S~dd~ Rel~ of ~ [ ] lmm~ H~ (Acu~) [~ ~lay~ H~ (C~c) [ 5) WAS~ C~S~CA~ON ~ A (3~t ~ flu. D~ Fo~ 8022) USE CODE ~4 ' ~ 6) P~SIC~STA~ SoUd[ ] Liq~d[/~[- ] ~[ ] ~[~~[ ] ~ve[ ] V) ~O~ ~ ~ ~ ~C~ ~ O~ ~~' ~) S~O~OE CODnS ~m D~y ~omt q Lbs [ ] ~ [~ ~ [ ] a) C~ Av~e D~y ~o~t ~ C~ [ ] b) ~: t Days on Sim %bg C~Ic ~ch M~: F, ~ ~ ~ ~, ~, ~ S, O, N, D ~ 9) ~: Li~ CO~~~ C~t '' ' I ' ' t I'- " ' 10)L~A~O~ I .! 4)Physi~ & H~ P~SIC~ ~ [/y~~ ~d Categ~~ F~ [ ] R~ve [ ] Su~ Rel~ of~ [ ] Tmm~ H~ (A~) H~ (C~O [ 5) W~ C~S~CA~ON ~A (3~ ~ ~ D~ F~ ~0~) USE CODE 7) ~O~ ~ ~ AT FAC~ ~ OF ~~ 8) STOOGE CODES ~~D~y~o~t ~ n~[ ]~[~[ ] a)C~ ~ Days on Site ~ C~le ~eh M~: ~ ~, F, ~ & ~ $, ~, & 8, O, N, D 9) ~: Li~ ~O~~~ - ~ ~lieve ~e ~ ~~ is ~, ~ ~d ~mple~. IPRINT Name & Title of Authorized Company Representative Signature Date ~ :-, , HA,~O US MATER/ALS iNVENTOi Page ~ of~_ CIIEMICAL DESCRIPTION 1 ) INVENTORY STATUS: New [ ] Addition [ ] Revision [ ] Deletion [ ] Check il'chemical is a NON Trade Secret [x~:rade Secret [ ] 2) Common Name: d t~ - 112 t~ ~_F~. ! -l~ .~./~ .~t'~/A~.. 3) DOT # (optional) Ch~.me: ~ *~ '. 45 _u.,?_,~:~- ut '] cAs# Hazard Categories Fire [ ] Reactive [ ] Sudden Release of Pressure [ ] Immediate Health (Acute) eyed Health (Chronic) [ ] 5) WASTE CLASSIYICATION ~[ A (3-digit code ~om DHS Form 8022) USE CODE 4it - 6) PHYSICAL STATE Solid [ ] Liquid [~l'/C-as [ .] Pure [ ] Mixture [~W~ [ ] Radioactive [ ] 7) ~OUN-r ~ rnvm ^Z F^cn_rn' tn, ars oF ~mAs~ 8) SZO~OE CODES Maximum Daily Amount ¢ Lbs[ ]Gal [,/'Iit3 [ ] a) Containax. Average Daily Amount ~ Curies [ ] b) Pressure: Annual Amount r~O . c) Temperature Largest Size Container t.~:omt, r.O?~q/ F~--y~' · # Days on Site a~/~ d Cimle Which Months: J, F, M, A, M, J, J, A, S, O, N, D 9) MIXTURE: List COMPONEKr CAS# % WT AHM any AHM components 3) [ ] I10)LOCATION 1) INVEZqTORY STATUS: New [ ] Addition [ ] Revision [ ] Deletion [ ] Check if chemical is a NON Trade Secret [ ~md~ Secret [ ] F~ lz.r' A 4) Physical & Health PHYSICAL I-IF..a~TH Hazard Categories Fire[ ]Reactive[ ]SuddenReleaseofPressurc[ ] lmmediate Health (Acute) [~/ITlelayed Health (Chronic) [ ] 5) WASTE CLASSIFICATION N h (3-digit code fi'om DHS Form S0n) USE CODE 6) PHYSICAL STATE Solid [ ] Liquid [~/'Gas [ ] Pure [ ] Mixtu~ [v~Waste [ ] Radioactive 7) AMOUNT AND Tavm AT FACmrnc T.n, nTS OF NmAscr~ 8) STOOGE CODES Maximum Daily Amount Lbs[ ]Gall 1t13[ ] a) Container: Average Daily Amount Curies[ ] b) Pressure: tan~l~of' ~.~a Amount ~) Tempcr. t~ ~bd~t/ Largest Size Container # Days on Site Circle Which Months: ~J, F, M, A, M, J, $, A, S, O, N, D ' 9) M~-rm~: List comPo~lm'r~'. CAS# thethreemost.hazardous 1) .~v~lm olrlilJrrl ]~,'tywll/1J.~ I"}.!?~ -q."':J. ..~ ~_ 0- ~5> [ ] chemical components or 2) ~.lm'l., '9~q,r~,Jr}n z~,alf !_n~, .~n~ -O.. ~'it2 [ ] any AHM components 3) ']~{~1 'l~t~xt~l'.~!¥-.~~'- I~n~%_ q---t~t_9-C, i-"/~ [ ] O)LOCATION certify under penalty of law, that I have personally cxamiaed and am familiar with the iaformafion on this aad all attached documcats. I believe the submitted iaformation is true, accurate and complete. ~ame & Title of Authorized Company Representative Signature Date I ' " HAZ~OUS MATERIALS INVENTOR~ Page _{L of Business Name ~t)~l/&,o ~[2v'lJa. ~,~ ~ ~Cl'I~ Address ~'.Z~ ~?_z..~ ~t,./_'~~.~.~ CREM/CAL DESCRIPTION I l) INVENTORY STATUS: New [ ] Addition [ l Revision [.. l Deletion [ ] Check if chemical is a NON Trade Secret [~]] Trade Secret 2) Common Name: ~.d'-It_,,/~. !~/~Z--']~ bi _r.~.~t_..--- 3) DOT # (option~) I Ch~.i< N~me: ~ t,.,~: ~1') lli,¢t'O <L--" AaM [ I CAS # <-~.. 4) Physical & Health PHYSICAL HF_.ALTH v~la ' Hmard Categories Fire [ ] Reactive [ ] Suddon Rel(mse of Pressure [ ] Immediate Health (Acute) [ yed Health (Chronic) I 5) WASTE CLASSIFICATION ~/)i (3-digit code firom DI4.8 Form 8022) USE CODE I 6) PHYSICAL STATE Solid [ ] Liquid [~'"Cra.s[ ] Pure [ ] Mixture [~"~Waste [ ] Radioactive [ ] 7) AMOUNI AND TIME AT FAcmrrY trnTrs OF MEASURE 8) STORAGE CODES Maximum Daily Amora Lb~ [ I C~ [ ItU [ ] a) Cuntm< I Average Daily Amount Curies [ ] b) Pressure: Annual Amount c) Temperatu~ Largest Size Container y~,,, I # Days on Site Cimle Wh/ch Months: F, M, A, lyf, J, .r, A, S, O, N, D 9) MIXTURE: List COlVlPO~ ~ CAS# % WT AHM I chemical components or 2) ~v~v~o~iOrT'l ~v,'O_~'],i,d_L.-. 1'91'14-~7--~ q-lq [ any AHM components 3) ............. [ 10)LOCATION I I)INVENTORYSTATUS:New[ ]Addition[ ]Revision[ ]Deletion[ ] Check if chemical is a NON Trade Seo'et [ ]Trade~[ 2) Common Name: ~-/d- It,.(~ l/z~.'~ -~ ~la.r~,,/ru, i~'L~ 3)DOT # (option,q) ,4) Physical & Health FHYSICAL HEALTH ~ Hazard Categories Fire [ ] Reactive [ ] Sudd~ Releas~ of Pressure [ ] Immediate Health (Acute) [,~] Delayed He. alth (Chronic) [ 5) WASTE CLASSIHCATION ~ ~ (3=digit code fi'om DH8 Form 8022) USE CODE. H~l 6) PHYSICAL STATE Solid [ ] Liquid [,~Gaa [ ] Pure [ ] Mixture [~Waste [ ] Radioactive 7) AMotr~r ~ TrM~ AT FAca.rrY tnm~ OF MEASURE a) STORAOE CODES Maximum Dai~y Amount Lb~ [ ] C~ [ ] fU [ ] a) Contains. I,,l~,~.,/~C~, ~ 0 Average Daily Amount Curies [ ] b) Pressure: I Annual Amount c) Temlx-rature ~b~-e' ¢4) Largest Size Container # Days on Site Cimle Which Months: ~, F, M, A, M, J, J, A, S, O, N, D 9) MIXTURE: List COMPONENT ~ CAS# % WT AHM chemical components or 2) c-.~.,./,',]~,tn' ~t7. ~.- '" "b"~'l..d~-~ i-B [ 10)LOCATION l I certify under penalty of law, that I have personally examined and am familiar with the information on this and all attached docum(mta. I believe the submitted information is true, accurate and complete. IPRINT Name & Title of Authorized Company Representative Signature Data I .... H~RDOUS MATERIALS INVENT ~(~. of' CHP. MICAL DESCRIPTION 1 1) INVENTORY STATUS: New [ ] Addition [ ] Revision [ ] Deletion [ ] Cheek if chemical is a NON Irade Secret [. ] Trade Secret "2) CommonName: t"~.~.ot{~ OD.,4, -.~ /~,'d~0~p~ ~,TZ~zI!rT~r/~__.- 3) DOT # (optional) I - [ ] 4) Physical & Health PHYSICAL HEALTH~ ~y 'l HazardCategofies Fire[ ]Reactive[ ] Sudden Release of Pressure [ ] Immediate Health (Acute) [ edHealth(Chroui¢)[ 5) WASTE CLASSIFICATION lq A (3-digit code from DHS Form 8022) USE CODE 6~6[.- 6) PHYSICAL STATE Solid[ ] Liquid[~Q//Oas[ ] Pure[ ] Mixture[~aste[ ] Radioactive[ ] 7) AMOUNT AND TIME AT FACILrrY UNITS OF MEASflJRE 8) STORAGE CODES Maximum Daily Amount Lbs [ ] Gal [~/1 fi3 [ ] a) Containex:. b,L~/l~t/a~t~ I Average Daily Amount Curies [ ] b) Pressure: ~lt~uJ[' Annual Amount c) Temperature lerv0at~ Largest Size Container I # Days on Site '~;4~a f~ Circle Which Months: O J, F, lVl, A, M, J, J, A. S, O, N, D 9) M/XTURE: List COMPONENT~I: CAS# . % WT AI-IM the three most ba~ardous 1) I-.Q~..$° Tv'{~_~o~~' "l_X~l-~gg- C> la-I$ [ Ichemicalcomponentsor 2) t.;~b;.'r;'tu'r't~l 'r¥1',a.r~lz~. l?,a/l.~.~_zettol~l 'r~oio [ 10 )LOCATION I)INVENTORYSTATUS:New[ ]Addition[ ]Revision[ ]Deletion[ ] CheekifchemicalisaNONTradeSecret[,,,~TradeSeeret[ 'l 2) Common Name: '~le~grlTglB.~.~~ 3) DOT # (optional) ! Chemical Name: '~1~'O~~ AHM [ ] CAS # ri 'll~ 4) Physical & Health PHYSICAL ~ HEALTH Hazard Categories Fire [ ] Reactive [ ] Sudden Release ofPressure [~]' Immediate Health (Acute) [~/IDelayed Health (Chronic) I ' 5) WASTE CLASSWiCATION ~ A (3-digit code ~om DHS Form 8022) USE CODE 6) PHYSICAL STATE Solid[ ] Liquid[ I Gas[~'~ Puret~,d~'~Mixture[ I Waste[ I Radioactive[ l I 7) AMOUNT ~ TnVm AT FACiLiTY tn, aTS OF MEASURE / 8) STORAGE CODES maximtun Daily Amount %CeO Lbs[ lCral[ lft3[w~ a) Container:. _/~[iHd2yzY Average Daily Amount $_~:Q.~ Curies[ ] b) Pressure: )teim b~I I Annual Amount ~ 0 ¢) Iemperam .' I~at~ Largest Size Container [ g~g' ' # Days on Site %{tf. Circle Which Months: AIIYear, J,F,M,A,M,J,J,A.S,O,N,D 9) MIXTURE: List COMPONENT CAS# % WT HM the three most ha~&rdous 1) [ chemical components or 2) [ 'l any AHM components 3) [ 10)LOCATION I I certify under penalty of law, that I have personally examined and am familiar with the infonnafion on this and all attached documents. I believe the submitted information is true, accurate and complete. iI PRINT Name & Title of Authorized Company Representative Signature Date CHE~C~ DESC~ON 1 ) ~ORY STA~S: N~ [ ] A~fion [ ] Re,sion [ ] ~lefion [ ] Ch~k ffch~ is a NON Tm~ S~et [~T~ ~t [ ] 2) Co~on N~e: ~t~ 3) ~T ~ (opfi~) 4) Physi~ & H~ P~SIC~ Hazard Categories Fke [ ] R~five [ l S~ Rel~ of~ [~m~ H~ (Acu~) ~lay~ H~ (C~) [ ] ~5) WAS~ C~S~CA~ON ~ ~ (3~$t ~ ~ D~ Fora 8022) USE CODE qq 6) P~SIC~STA~ ~hd[ ] Liq~d[ I ~[~ ~e[~~e[ ] W~[ ] ~ve[ ] - 7) ~O~ ~ ~ AT FAC~ ~ OF ~~ / 8) STOOGE CODES' ~mD~y~o=t ~ Lbs[ ]~[ ]~[~ a)gm~ I Av~e D~y ~o~t ~ Cm~[ ] b)~: ch~ ~n~ or 2) [ ~y ~ ~n~ 3) [ ] 10)L~A~ON 1)~ORYSTA~S:New[ lA~fim[ ]Re,sion[ ]~Iefi~[ ] Ch~kffch~aNONT~~[ ]T~~[ ] 2) Co~on Nme: 3) ~T ~ (~fi~) Ch~Nme: ~[ ] C~' ~d Categofi~ F~ [ ] R~ve [ ] S~ Rel~ of~ [ ] lmm~a~ H~ (Am~) [ ] ~hy~ H~ (C~c) [ ] 1 5) W~ C~S~CA~ON (3~t ~ ~ D~ F~ 80~) USE CODE 6) P~SIC~SIA~ ~Hd[ ] Liq~d[ I ~[ I ~[ I ~[ I W~[ I ~ve[ ] 7) ~O~ ~ ~ AT FAC~ ~ OF ~~ 8) STOOGE CODES ~mD~y~omt L~[ ]~[ ]~[ ] a) Con~ Av~e D~ly ~omt C~ [ ] b) ~: ~ ~omt c) T~m , ~e~ S~ Con~ t Days on Site C~Ic ~ch MmV: ~ Y~. J. F. ~ & ~ J. J. & S. O. N. D ch~ ~m~n~ or 2) [ I O)L~A~ON P of Au~o~ Comfy R~mfive Si~ Nme & Title Dam STORE NUMBER/ADDRESS: Longs Drug Store ~N17 4400 Coffee Road Bakersfield, CA 93308 EPA NUMBER: CAL 000176616 PHONE NUMBER: (805) 588-0290 STORE POSITION NAME HOME PHONE NO, Store Manager ............ Bruce Hunter ......... (805) 871-3201 Assistant Store Manager .... John Mendiola ....... (805) 664-9769 Department Manager ....... Eric Tiara ............ (805) 837-1350 Lab Supervisor ........... Kris Rogers .......... (805) 396-1009 Chemtrec Chemical Hotline .. 1 (800) 424-9300 Chemical Manufacturer ..... FUJI 1 (800) 326-0800 Police Department ......... 911 or (805) 327-7111 Fire Department ........... 911 or (805) 324-4542 Paramedics .... ........... 911 or (805) 327-4111 Poison Control Center ...... (800) 346-5922 Utilities: Gas ........... (800) 427-2200 Electric ......... (800) 743-5000 Water .......... (800) 396-2400 Sewer District .... (800) 326-3111 Lab Supervisor ........... Kris Rogers .......... (805) 396-1009 Fuji Technical Hotline ...... FUJI I (800) 326-0800 .. Regional CoQrdinator ...... Debi Taniguchi ....... (800) 973-6164 Neighboring Stores ........ #239 Coffee Road ..... (805) 832-0964 #267 Stockdale ....... (805) 322-5024 wpc:cmtn'g I. rrm 112'04/96) 12/16/97 SHORT FORM (Contingency Plan -- Part 1) BUSINESS NAME: LONGS DRUG STORE #417 4400 Coffee Road Bakersfield, CA 93308 EPA NUMBER: CAL 000176616 BUSINESS PHONE: (805) 588-0290 PERSONS Application: Kathleen Gillis RESPONSIBLE (510) 210-6999 FOR: Business: Bruce Hunter (805) 588-0290 Property: ADS Properties LLC c/o Donahue/Schriver 3501 Jamboree Road S. Tower 300 Newport Beach, CA 92660 (714) 854-2100 PERSONS Name Home Phone RESPONSIBLE FOR AFTER-HOURS 1. Bruce Hunter ................ (805) 871-3201 EMERGENCY: 2. John Mendiola ............... (805) 664-9769 3. Kris Rogers ................. (805) 396-1009 4. Edc Tiara ................... (805) 837-1350 5. Chemtrec Chemical Hotline ...... (800) 424-9300 PRIMARY BUSINESS: Retail chain drug store which operates a 1-hour photo lab. Store Employees: Total Full-Time: 18 Total Part-Time: 20 Total Employees: 38 Number of Shifts: 3 Store HourS: Monday--Friday: 7-10 Saturday: 7-9 Sunday: 8-8 HAZARDOUS MATERIALS MANAGEMENT PLAN / SHORT FORM Page 1 of 3 NEAREST HOSPITAL: Mercy Southwest Hospital 400 Old River Road Bakersfield, CA 93311 (805) 663-6000 SiC: 59-12 COMPLETED BY: Bruce Hunter Print name Store Manager Print title Signature Date: 11124197 wpc:hmmp-sf.frm (04104/95) HAZARDOUS MATERIALS MANAGEMENT PLAN / SHORT FORM Page 2 of 3 General This facility contains chemistry used for the processing of film for the general Information public. All materials are monitored visually on a daily basis. Only compatible materials are kept together. All unopened chemistry is stored separately from consumer and store cleaning products. ,All opened case items are stored on shelves in secondary containment which is secured to the shelves. We do not use or store any chemistry that is a carcinogen or reproductive toxin. ,All spent wastes are pre-treated and then discharged to the sewer. We recycle the silver, which is hauled away off site. Our hazardous waste hauler is Safety-Kleen, Regional Office, 8795 Folsom 'Boulevard, Suite 108, Sacramento, California 95826, Phone: (916) 387-6335; Fax: (916) 387-6156. Emergency · Fire extinguishers Equipment · Absorbents · Collection containers on Site · Gloves · Posted emergency procedures · Emergency spill kit · First aid kits Emergency Chemistry spills are up using Paper are towels cleaned absorbent materials. Control Spill used for small spills; large spills are contained by dikes from a spill kit and then cleaned up using absorbent pads and materials. ,All contaminated Clean-up materials are disposed of in a non-corrodible container and labeled. This Procedures container is picked up by our hazardous waste hauler. If any spill would create a hazard, the Emergency Coordinator would call 911 and summon emergency response personnel. Each Photo Lab has emergency response numbers posted in their lab. The Material Safety Data Sheets for all chemistry used in the lab are located in the lab. Employee All photo lab employees are trained in the safe handling of chemistry and for Training emergency response. Employees are required to view a video which covers handling hazardous materials/waste, Material Safety Data Sheets, etc. They are instructed in a classroom setting and must complete a multiple choice questionnaire upon completion of the training program. Refresher training is conducted annually. All employees undertaking the training program must sign off when they have completed the class. Wdtten procedures are provided to all participants, including management. Employees are instructed in the use of safety equipment in the event of an emergency and shown where the equipment is located. Lab Supervisors and Technicians undergo additional training at Longs' Photo Lab Training Center in Concord, California. Records are kept in the employee's store personnel file. I wpc:hmml>-sf.frm (10/08/97) HAZARDOUS MATERIALS MANAGEMENT pLAN / SHORT FORM Page 3 of 3 WASTE A (NON SILVER-BEARING) (SlLVER-BEARINC;) SAMPLE POINT NO. 1 / (5 GAL CONTAINER) t SINK PUMP UFT 1 ! STATION OMNI 16 or 32. SILVER RECOVERY CANNISTERS! TO SAN[TAm' SEWER pH STAllON (OP'nON~,L) Process Flow Diagram Silver Rocovory Systom Long-., Drag Stores Callfomla0 Inc. SOURCE: SAFTEY-KLEEN CORPORATION J compi.d b~. R.O~<. io::o: 10/97 J ~eJ~z J 1. ALL UNITS WITH SECONDARY CONTAINI~IENT. mi ~ i,~o~, ~. ,o~. i,.~.,on-.. 1 SITE MAP (Outside) LONGS DRUG STORE #417 COUNTY: .. KERN 4400 COFFEE ROAD BAKERSFIELD, CA 95508 DATE: January 1998 HAGEMAN N BLOCK I BUSTER SHOPS S I SHOPS CARL'S JR I SHOPS BofA PARKING LOT VONS 0 SHOPS O~ ,,, LI.I ° ~ ~ LONGS SHOPS (SD) DRUGS Employee Emergency Meeting Area __m I (STD) . (H) LEGEND lEI Entrances NOT TO SCALE FE-I Emergency exits (EM) Employee emergency meeting area. (STD) Storm drain outlets (SD) Sewer drains (H) Fire hydrants (SS) Outside sprinkler system connection E Electrical utility shutoff G Gas utility shutoff W Water utility shutoff Parking lot FLOOR MAP (Inside) LONGS DRUG STORE #40 COUNTY: . MARIN 442 LAS GALLINAS AVE. SAN RAFAEL, CA DATE: February 1998 N = W+E W ~0 OTHER WAREHOUSE I co STORES S FE I FE AS __~ __~ ~ I STAGING AREA L~B ~KINO LOT I ...._co > :~ ~< ~t~ ·FE LEGEND CS Checkstonds OTHER RX Pharrnocy STORES COS Cosmetics PL Photo Lob lEI Entrances I-E-I Emergency exits NOT TO SCALE --,-- Evacuation routes FE Fire extinguishers PL Location of Photo Lab PLW Location of Photo Lob waste MSDS Location of Photo Lob Materiel Safety Dote Sheets E Electrical utility shutoff G (:;os utility shutoff (MALL CONTROL) W Water utility shutoff AS Automatic fire sprinkler (MALL CONTROL) EE Emergency equipment (spill cleon-up kit, dikes) LONGS DRUG STORES COMPLIANCE FORMS Store: ' ' " ' " ' - ' (~tl I 2 3 4 5 6 ? 8 9 fO 50. Chart D D 94. M$OS Manager: Fokb/Bend. O D B D D D O ri O D 51. punels ri D 05. HMMPPlan II 0 "' O~dAccu~.'h O [} O O O O O 130 52. MixingW~$ O O ~.HMISLabefs II Supervisor: Fo~ D 0 0 O O O O_O 13_ O 53. Magazine~ O U 97 Eme~g. Phone Lisl Date Open/Type: Pat~ Fall 54. Paper Oeck [3 D 98 Filler Buckel II O Date: tl Workftow I'.l [! 55. Racks [3 [3 99. Personnel 12 $~a [I LI 56. Squeegees 13 O 100 SRU Lo<j ri O m~m{): 13. Packag'.mg [I rJ 57. Dr/Rollers 'L1 13 10l. SRU Flow Rale rl Lab Operational? ["J Yes 1.1 No 14. Lab Ho~3 [I rJ 58. Culler II 13 102 SRU Silver Tesl II O 15. Lab Coals Iii [] 59 Pfin! S~er [J U 103 SRU Conlainmenl I I Lab Open? O Yes LJ No 16. While'Gloves LI ri 60 Temperalures [J D 304 SRUAppearance [J O Serviced By: fi. I~ma Tag~ rJ 13 61 Rep Ralos 13 D t05 Wesle Hauler Service Time: 18. Fkx~s L1 L1 62. Pump Outpuls 13 O , f06 EPA Number $1ore Conl3cl: 19 Equlpmenl I.I 1.1 63 CircFiil~ ri D f07 Cbecklisl II I'1 rypeolSen~e 20. Cluller [I U 64 RepFillers . IJ D ~08 Manifesls ~1' r.J '/Emen~ency I.ISchedu~d Procfu~ Quil~ty '..D'! :ii~..O . . . ! ~ . 65. Dr/er Fille~s I'l D 10g Mift~run Manii'esls I I D ,/Ouwledy Mainta,ance . T~is s~cl~~ ~..~!~~'J.~f~iii. 66. Wasle Tan~ !',1 O 110 Eye Wash Slalion ;, .~ ~ ~, , , ....... 6?. Pump Seab n 13 111 Eye Wash Ballles UAxtit (./Fraining .Upkeel).Frlm Pl'oce~ler 68 Lamp D 13 112 Sp~n Conlrol ~ I O ,,O,he,.. '~...1~..[ ~.0.., I 21 Chaff Il O Og. LampHo~sing O 13 113 Fir, lAid ,.I O ~. =.. :...;.,..ii;il. 22 Pa~,~s u 13 70. LampF,~, 13 o 11~ ve~, v~ O'Re~o~:i.!~iii'i!D~C~ !! :!!!i~ i ;J 23. Mixing Wafts [I O 71 Scanner O O 115 2nd Conlain II O ..... fl ........ ;; ............. 24 FeedSeclion ['1 ['1 72 ConlrolNegs O. 13 116. EadhquakeL!nes I:,1 O Prod~-'t Qualtl7 25 Culler Blades [l f3 ~. Lenses O 13 ,~t'ety.f : :'. R,ndomOn~erlnspect~on Pasa Fall 28. Bells [I [') 74. Lens Balance 13 D ?~S~f~2~l~!:~~....: ~. I O D 27. Crossovers [I [~ 75. Masler Balance 13 O ' ' ' 2 O O 28. Racks [J O 76. P~er Balance O O Proflt~hllll7 3 [3 O 29. Squeegees [! O 77 Sy~lem Badmp O D fl? Invenloo' I'J O 4 O O 30 Rinse Tanks I'l 13 78. Rifle Tanks O O 118 Spare Pads ['1 O $ O D 3t Moll Clolh H [] ^¢cesaorl~ 119 Lab Binder 6 O O 32 Exil Roller ! I (1 79 Forms f3 O 120 Monlhly Repods I I CJ 1 13 r~ 33 Exil Baskel I'1 [1 80 Sleeve~ I'I D 121 Marketing Cai I.I rJ ~ II ~1 34 Tempmalure$ I I I I 81 Paper Culler [] D 122 Wasle % I J O g .. U [I 35. Rep Ral~ I,I I`1 82 Ref~geralor {1 [3 123 Puffing Orders Il O 10 U D 36 Pump Oulpuls ri L1 83. Film Exlmctor 13 O 124 Minimum Volume O~(~'.~ I 2 3 4 5 0 7 8 ~ )g 3?.CitcF~llers (! I.I 84. Auloloader U D 126Sla~fin9 lJ O ~n,l~als 13 II L'I O O .O O D 13 13 38 Rep Fille~ II [1 85 FRSSUnil (.1 D 126 Training I.'1 O Due hme O II [.3 [) O O L3 LI [J O 39 Dry. Fillem Il [] 8~ Compuler U 13 .J~'~f/tab/El~ O O ;.~. · :: i/2 :ii;'i. :.~ ~:: Atoblof~14o~.ofthe128 s~,~,i~ n ~ 13 c~ o o o 13 o o ,~! Pumps.I, !~ 13 u~..p :~:i;~i~ ~ .il F~nger Prls O II 13 rJ E] O 13 U 13 O 43 ConltoJPIolsI] [.1 o.~ u u o o o a o (~ a o. 44 O~,Tr,~ L~ O Saree/ Lab Audit Result M, sculs[.I rJ D O O O O O O O 45. Cooling Fins [I (1 68 Gloves (J O £]Pass OFa// Water Mks. rJ il 13 13 000 O [J O 46 Drive Chain LI O Bg.Goggles D 13 C,eases ['1 II I"J O I'.1 D O [.I 13 D 4?.l~eader. Ca,tds' ..~!~: I~ m.~on ~ n The Safety Section requlres lO0% Colo~ Bel rill R [1 {I rJ [3 Fl 13 O Upkeel>Prtnter gl. Signage I] [I to Pass the Audit 0en$~l~es II fl t.I I) [J ['1 0 II U L1 48. ConlrolPIols 'II El 92 Conlaine~s I.J C,,o, echonsLI II Il I'J 00 I.'1 U 13 ~J 49 D~pTrays i'J II 93. Accum. Slad IJ ri While- General Office Yellow- Photolabs Deparlmenl Pink- Slot;' Gold- Regional Coordinator I Hazardous Waste Compliance Checklist - I Action Needed ] Date Completed: . · = .... ._.......... . ,:........., ...., .... .. · , .,. ... -, . ::.¢..~.::.%¢.%:.~ .~:.. :.. ..... :%',.'- : ~., ;~, , "' .:. .. . .... .~,.. <.~.,,.:¢..,.~&{;;..~..~.¢,%,~.... I Check Manifests lot completeness-look for both yellow copies, blue form sent to I ~ state, land ban notification, receipt of arrival at ECS I Silver Recovery Unit-clean, has IO number, in secondary containment, is : operational, No leaks I ; Contingency Plan-updated yeady or when personnel changes occur. ! Waste Hauler File-complete .- I Forms-updated yearly, all new hires have received and Employee safety tl-aining viewed video i I Permits posted-Health, EPA number ...- .' i Waste picl~ed up within 90 days of accumulation start date-swipes bucket, silver i recovery columns, filter bucket I ~ Emergency phone list-posted by phona, updated with any changes i Evacuation map- updated for stem remodels, changes I [ Warehouse-clean neat, eadhquake lines, secondary containment,free of spills ! i first aid kit-complete, replenish supplies, in photolab I Goggles, gloves apron-clean, in good repair, easily accessible Sliver bearing waste rep(M-complete, sent to G.O. monthly, flow rate and sihter I lest completed weekly, gallonage noted for month MSDS binder-updated for change~ or new products; binder on counter in photolab I Safety Inspection Form completed weekly, problem areas addressed Spill Control Kit-has drain bloc_~, absorbant material-no cat litter I Safety Signage-complete in lab & over lab sink-'Employees Only", 'Hazard Index", 'Dangerous Fumes', "Safety Equipment Warning", 'Lab Sink Useage" I Equipment exteriors and waste tank areas-clean and free of spills, no leaidng I:mmps, hoses or drains, all panels attached to machine Eye wash Station-continous flow unit InStalled & operating-checklist completed I weekly, eme[l;lency eye wash bottles in lab if cordinous flow is over 100 feet from lab Photolab Binder-complete, organized, on counter in photolab · .,~ ....:.,~.~. . . '- .-.:'. . . ....... :...~,~...~ S:-'~FUiTIS:,~:,~ ........... '.~.~,.: .... ~:~.,.... ,.. · · :.~.'1 ;. · .... :-.. -.:: :..... ......... . ....... , ,:, ,,: . ....., :~.:.~, .,.:,.~?~:~:... ~,.-:, ....... ...,,. ........ .~-,....,- .~ : ...... .. .. · .. . · , . .. .... ,. ,:..~: .: ..;..:-.,,-,,~,~.:-~.:.....~~.., . ~.;, .- .:. fi ;:' ,~ .'.-" · ~.P. hoto':Lab',H_~_ardoU~',Wa~'te'St0~gb':.A~aqfisp~ctio '.'Form. . .. .... Answer all questions Y=Yes or N=No. If no, explain problem and corrective action in Co~nm~nts section. o -- oD ~ ~ ~ o ~ m o .,~ -- ,.. -- o~ = < ~ ~omments " I Longs Drugs HATARD COMMUNICATION TRAINING ATTENDANCE RECORD Store fflName: Address: City/State/Zip Course Name: .. Training Period From: To: Employee Name (Print) Social Security No. Date of Training Employee Signature ,- Ir~.r~.x~s 12./7/96 ~ cq ~oH ~ m~ - 0 . o ] , : _ c o :'' . ,. i : . 0 .~ o ill Eyewash Inspection Form Longs Drugs Answer all questions Y=Yes or N=No. If no, ex~lain problem and corrective action in Comments Section. Inspected Check Are eye Is station Date by water caps on? accessible and Comments flow clear of objects I~a~.x~s 1Z/7/96 I I APPENDIX I Material Safety Data Sheets Fuji CP-Series Product Material Safety Data Sheets Waste effluent analysis according to ~aste tanks ~ s~ver re~ treatmer~ C, oncer~ral~ expressed in ppm (rog/I) ur;ess othep~e specmed. CP-40 FA Il (FOR PP4OOB, 540B MACHINES) EFFLUENTVOLUME PER PRINT Chemistry mi per m2 I mI per 8.5'x5' mi per 4'x6' mi per B'xlO' tank paper1. print print print P1 161, 1.8 2.5 8.3 P2 218 2.5 .. 3,4 11.,3 PS 364 .4.1 5.6 18.8 total v~. (ray,rim)" e.4 11.5 . ~8.3. total vol, (VSO d w/24 exp.) __ 10.1 13.8 46.0 total vol. (98V50 ri w/24 exp.) .. 2.7 3.6 12.1 . total vol. (I/100 p~ts) 0.8 ._1,2 .. total vol, (gaVlO0 prhts) 0.2 0.3 1.0 m ~ FUJI PHOTO FILM U.S.A., INC. 555 Taxter Road · E]m.,fo~d, NY 10523 I 09:~2am From-Pro~ertie: ~rtment 5102106887 T-972 P.04/~8 Jan-Z0-98 j~ MATERIAL SAFETY DATA SHEET cP.40 FAil P1-Rs Developer Replenisher Part A IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 JSECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name CP-40 FAll P1-Rs Developer Replenisher Part A Product Code 03021100 MSDS Code 03021100A Product Size 4 x 250 mi Distributor Manufacturer Fuji Photo Film, U.8.A., Inc, Fuji Hunt Photographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Box 988 Elmsford, NY '10523 Paramus, N.J. 07653 USA (9'14)789-8100 Prepared by Fuji Photo Film U. SJL, Inc. Revision Date 11/10/94 Issue date 11114/94 i SECTION 2. COMPOSITION'AND INFORMATION ON INGREDIENTS Inelredient .C. AS Number Weight Water ' 7732-18-5 73-84 Trlethanolamlne ..... 102-71-6 7-10 Hydroxylamine Derivative P-90-I 986 5-7 Acetic Acid 64-19-7 3-5 Sulfonlc Acicl DedvatNe 41098-56-0 1-3 SECTION 3, HAZARDS IDENTIFICATION q IN CASE OF EMERGEN L CHEMTREC (8130 ;9300 Matedal Is a clear, light yellow liquid. May emit toxi~ gases in fire conditions. Hydmxylamine may explode above 265'~'C. Wear equipment to protect eyes, skin and respirator' tract. Dike or absorb spais to keep material and mn-off from entedng sewer orwaten~ys. Use water spray to cool containers and disperse vapom. Box contains multiple components. Consult all MSD$'s. .HM~SRatin.q Health 2 Rm 0 Reaclivity 0 Protection C NFPARat. inq Health 2 Fire 0 Reactivity 0 SpecifioHazards None Hazard rating 0 = minimal 1= slight 2 = moderate 3 = serious 4 = severe C = gloves, goggles and apron UN None ERG Guide 60 p~tential Health. Effects Skin: Contact causes irritation. May cause allergic skin reactions. Eves.' Contact causes irritation. Inhalation.' May cause irritation to tile respiratory tract. Inoestlon: May casue irritation to tile stomach and gastrointestinal tracL May cause nausea and diarrhea. Conditions aooravated bY exoosur~ Skin sensitivity. .Carcinoaenic~tv Are any ingredielttS list~ as carcinogens? IARC? N NTP? N OSHA? N P~gel o! 4 Jan-21)-g8 09:33em From-Propertie,, 510210688? T-972 P.05/~8 F-333 artment E~es: Flush eyes ~th la~e amounts of ~ter for at lea~ 15 min~. See a m~i~l do~or immediately. Skin[ Fl~h s~n with I~e amoun~ of water. Remove ~ntami~ do~ing. See a do.or il ~, redne~ or i~ion develo~ [nhal~ion: Move to fresh air. If vi~im is having d~lty ~ea~ing, give o~en if available. vi~tm Is not breathing, ~ CPR. Get immediate m~i~l ~e~on. ~.nqemion:. Do not Indu~ vom~l~ or gi~ an~lng by mo~ ~o~ eme~ medl~ introns. Immediately seek medi~ aEention. Call ~bon ~n~l ~nter (202)625-~33. if vi~ b un~ns~ous, trained pemonnel sh~d ~a~ CPR. Never give an unconsdous pemon an~lng by mo~h. ~SECTION 5. FIRERGH~NG M~ASURES Elash Point None Uooer Rammable~lmit Not a¢~i~01e Lo~r Flammable Limit N~ a~li~ble A~oinnffion T~pem~ None ~in~uishin~ ~ia Choose m~ia ~i~ble for su~unding mate~als. No ~ions on media b~ on ~go of material. EImfia~n~ in~mmlons Evac~e ~a ~d fight tim ~om a sa~a ~n~. W~r p~e ~um dema~ bm~i~ ap~mt~ and p~e~ ey~ anO ~n. ~ ~to ~1 ~ ~inem, ~ ~em pe~nnel ~ ~ d~ ~m an~ spl~. W~er runoff ~n d~a~ ~he envlmnm~ D~e and mile~ ~er ~ 10 light tim. May emit teac ~s~ In tim ~n~o~. Hydm~mine ~y ~e a~ve 26~. ~ECTION 6. ACCIDENTAL ~EL~SE ..... _ ; ' Keep unne~ a~ unp~e~ pm~nnei ~m e~e~ng ~e sp~l ama. W~r ap~p~ate ~mhing. S~ ~m ~ se~ ~om s~ll ~ ine~ mineral, ~p up a~ hold in label[~ ~T ~ainer for~spo~l. C)ike la~e spll~ to minima ~e s~ll ama. M~edal ~n en~men~l damage. Pmve~ m~edal ~m ~min~ soil or e~edng ~r ~ ~i~ of ~er. !SEC~ON,7. HA~SUNG AND ~;TO~GE .., .~ndline Wa~ thomughN aRer I~andling. A~ ~a~ ~h s~n. A~id ~ ~h e~s. Avoid b~ffiing mi~, du~ ~m or ~ Ha~l if ~i1~. ~omne 8lore in ~ol, d~, wel~ve~l~ ama a~ ~m in~m~tible ~edab ~ed in 8e~ian 10. IsEc oN a; e0su, q CON O S .ERSO C PROTEC ON ~a~ to ~U~e ~uimmen~ ~A8~ ~-1989. E~um good m~ng ~ ~sh air suppll~ ~ a minimum of o.5 ~ Pemonal Pm~ve Eaui~en~: Use chemi~l s~a~ g~gles. Be ~,in ~ is in ~o ~ ama. Wear neopr~e, n~e robber or olher c~emi~l ~i~t ~ov~ and apron or ~b ~aL R~l~o~ p~e~'on is generally nol ~ui~, Ruler to 29CFR 1910.1~ for OS~ r~u~me~s. P~ ~lOOA Jan-20-98 09:35a~n Froth-Properties ' rtment 5102106887 T-gT;? P,06/d8 F-333 Exposure Guidelines: inqredient ' .OSHA pEL ACGIH TLV Water Not established Not established Triethanolamine Not established Not established Hyclroxytamine Derivative Not established Nol established Acetic Acid 10 ppm 10 ppm Sull'oni~ Acid Derivative Not establishecl . Not established ISECTiON 9: PHYSICAL AND ~HEMi-CAL'i=ROPERTIES A, pp. earance: Clear, light yellow liquid Odor Slight vinegar ~.oilino Point; approx. 100°C C~,pr Threshold; No data Specific.Gravity:. 1.0~4 Reactivity with Water:. None Vat, or Pressure., approx. 15 mm Hg .Mq.!tfn~ Point;. No data Evaporation Rate.' I (water-l) Freezir~ Point: No data percent Volatile..- approx. 70 Percem voc: No data .S,olt!bllity in Water. Completely ~/aeor Density: No data ~H: 6.02 Wa_tm-Oil Partition Coeff'a:i_en_t: Ne data Hazardous polymerization wll not occur if product is used and stored as directed. Product is stable if used and stored as directed. Hazardous Decomoosltlon Pmducts_[ Nitmsarnines. Suffurdioxide. Ammonia. Hydrox~amine. Materials to avoid: Strong acicl~, b-'tong bases, Oxidizers. N~d~tes, Conditions to ay. oi.d.;. Excessive heat: ISEC ON. 1.1. TOXICO~OGICAL~INFORMATION_ -~. _ , - , 1 LI~: >2000 rog/kg oral, rat Acute Overexposure: Irritating by ~ontact with eyes and skin. Irritating to respiratory tract if lnl~aled. Irritating to gastrointestinal tract fi ingested. May cause gastrointestinal distress, nausea and ~iarrtlea. ,Chropic Oveml<posum: Chronic dermat~s. May cause liver and kidney damage, digestive clisordem and blaclcening or hyperKemtosis of the skin. Carcinogenic activity of trletha~olamine is being Investigated. I Pages of 4 dan~-O-98 O9:3Gam F rem-P rope r t i esi~i~ar tmen t 510210681~? T-§72 P.07/48 F-~33 SEC~pN E~to~ciW Data None available. -' Chemi~l Fare Data None avai~bie. ISECtiON' 13' DIsPOSA~ CONSIDE~TI6NS .... Dbcha~ing this material to the s~eT may require a ~E, Da n~ d~a~e te se~e ~ems. O~e~ all ~. ~te and federal ~ulations ~en ~is~.ing of ~is material. . Matedal do~ not e~ibH haza~o~ ~ chamme~. [SEc~ON'i~T~NsPORT~)ION INFOR~oN ' - - · ' ' "_,, '., ~poqent DOT Shippi'n~ Name, N~ DOT ~a~d. Pa~ B&C am ~la~. Ha~ cl~ None U~ Nu~ N~ pac~lnfl G~up= None Box qOT ShloDInu Na~ N~ ~T ~ulM~. Ha=~ ~laes:. No~e UN Numbec None Pac~neGroup~ · None In~ieptWa,r ~ y -' N Li~ 31t~12 N~ N~ N Pmo6S N Td~anolamino Y Y Y N N N H~m~lamine Defiv~ve : Y Y Y N N N A~cA~d -~ Y Y Y Y N N Sul~nle A~ ~d~tive Y N Y N N N ! All ingredients amply with EPA TSCA requirements. ISECT!. ON 18,. O?HER I.NFOR-MATiON ............. I This Information is provided without wartarlty, The inl'ormation is believed to be correct. Thls Inforalatio~ should be usecl to make an inclepefl(~ent deten'nination of the methods to safeguard workers and the environment. I J an-~0:98 O~:37am From-Properties ?tment 5102106887 T-972 P.08/48 F-333 · ' .~mlll~l~...,. MATERIAL SAFETY DATA SHEET CP~0 FAll P1-R Developer Replenisher Part B IN CASE OF EMERGENCY, CALL CHEMTREC (800)424,9300 I ISECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name CP-40 FAll P1-R Developer Replenisher Part B Product Code 03021100 MSDS Code 03021100B Product Size 4 x 250 mi I Distributor Man ufacturer Fuji Photo Film, U.S.A., Inc. Fuji Hunt Photographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Box 988 Elmsford, NY 1052;I Paramus, N.J. 07653 USA I {914)789-8100 Prepared by Fuji Photo Film U.S.A., Inc. Revision Date 11/10/94 Issue date 11114194 I I SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS InQredient CA.S Number WeiQht % Water 7732-18-5 81-92 I Derivative ...... 25646.71-3 8-18 p-Phenylen~lamine Sodium Sulfite 7757-83-7 0.5-1 ! SECTION 3. HAZARDS IDEN'i'IFIcA~IoN ..... ..... cAs ' MERGENCY C" MT. sC '0i IN OF , CALL E (8 0 424-g301) Material is a dear. light yellow iiqu~J. May produce toxic gases under fire conditions. Wear equipment to prelect eyes, skin and respiratory tract. D~l~e or absorb spills to keep material and mn-off from entering sewer or watelways. Use water spray to cool corltainem and disperse vapors. Asthmatics are said to be aaflgemu'~ly' sensitive to even minute amounts of sulfites. Box contains multiple components. Consult all MSDS's. HMISRatinq Health 2 Fire 0 Reactivity 0 Protection C NFPA Ratipq Health 2 Fire 0 Reactivity 0 Specific Hazards None Hazard 0 = minimal 1= 2 = m~erate 3 = serious 4 = severe C = gloves, goggles Pe~ential Health Effects .Skin: contact causes irritation. Eves: Contact causes irritation. ~ May cause irritation to mucous membranes and respiratmy tract. Asthmatics are said to be dangerously sen~-itive to even minute amounts of sulfites. May cause ,~=nsitization. .In.qesfion: May cause irritation to stomach and gastronintestinal tract. May cause diarrhea and colic. Conditions aqqravated by exposure~ Asthma. Skin sensitivity. .Carcinogenicity Are any ingredienls listed as carcinogens? I,~.C~ N NTP? N OSHA? N p~m~l of 4 O302110O1) From-Propertle., artment 510210688'/ T-972 P.og/48 F-333 Jan~-20-98 ~yes; Flush ey~ ~th la~e amounm of water for at lea~ 15 min~. See a medi~l do~or immediately. Flush s~n with la~e amoun~ of ~ter. Remove ~ntaminat~ clothing. See a do,or if ~h, mdne~ or ~on develop. Inhalatiog= Move to fresh air. If ~ b having diffi~l~ ~a~ing. give o~gen I[ available. If ' vi~im ~ not bma~ing, ~a~ CPR. Get imm~ia~ medl~l ~ention. ]nqe~ion= Do not in~u~ wmi~g or g~e an~lng by momh ~ eme~en~ in~ons. Immealalely sae~ madl~l ~tion. Call poison ~ntml ~er at (202)625-3333. If vi~m is un~ns~o~. ~ned pemonnel should ~ CPR. Never give an un~nse~ous pemon an~hing ~ ~h. }:lash Point None "''''-' U~er Flam~ble Limit N~ a~i~e ~o~r Flammable L~E N~ applique A~oiqn~io~ Tempe~um E~inQuishin~ m~ia Cho~ me,ia sul~e for su~undirg ~edab. No ~H~ on m~ia based on ~edge ofth~ material. Eva~me a~ and fight tim from a =~fe ~i=a~. Wear ~e p~m d~nd a~ p~e= ey~ an~ s~n. Use ~terto ~ol fi~~ ~ine~ to ~t~ ~nnel and to dis~e K~p unne~ and un~t~ pe~nnel from emed~ ~c spi~ ~a. W~r a~e ~o~e labell~ DOT ~n~iner for dis~sal. D~ la~e ~ ~ minim~e ~e spi~ ama. Mat~ envimnme~al damage. Pmv~t m~e~al from m~n~ng ~1 or e~efi~ ~er or b~i~ ISEC O, ,. HAu U.o ' ! Handlinq Wash thom~y aRer hailing. AvoM ~na~ ~th s~n. Avoid ~m ~ eye. Avoid' ' ISECTION S. ~OSURE COhlTRO~ AND PE EON6L PROTEC~ON - '1 Venation Reoulm~en~; ~a~ ~ s~the ~uimm~m of AS~ 62-1989. ~m g~d m~ng ~ ~sh air ~1~ ~ a minimum of 0.5 Pemonal p~~ U~ ~eml~l spl~ goggles. Be ~in ey~sh b in the ~ ama. We= neoprene, n~le robber er ~her ~emi~l rmi~anl glov~ a~ a~n or lab ~L R~pimto~ pmte~on is generally not r~u~. Rear to ~C~ 1910.1~ for OS~ ~uireme~. I3an~0-98 ~9:~9a~ Frea-Propertles ~rtment 5102106887 T-972 P.10/48 F--333 I F. xnosure Gui, deline,s; Inqredient OSHA PEL ~CGIH TLV Water Not established Not established I p-Phenylenecliamlne Derivative Not established Not established Sodium Sulflte Not established Not estal~lished ! I SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES I Aooearance: Clear, light yellow liquid Odou STight sulfur ~ applier. 100=C .Odor Threshold; No data S~ecific Grayltv; 1.054 Reactivity ~ Water; None I Vapor Pressure: approx. 15 mm Hg Meltlrm Point: No ~lata EvarmrafionRate: I (wateml) Fl~.zinq Polqt: No data percerLt. ~ Vela~le.'approx. 85 p,,ement Voc: No data . I soluhilitvfn Water:. Completely ~ No ~lata PH:, 1.25 w.,.a~er. Oil partition coeffielent~ No data .. · I ISECTION 10. STABILITYAND'REACTIVIT~ Hazardous polymmtzaUon will not eccl,-If prc~dct is used and stor~ as dlmctecL I Pmcluct is stable if used and stored as Hazardous,Decomposrfi0~' p. ro~luct~l: Ammonia. Amines. Carbon dioxide. Materiqls tn avold: Slrong Aclcts. Oxidizers. I'-- ,Conditions Io avoid= Excessive heat. I lSECTI°N I,'T°XIC0LoGicAL INFORMATION ,. __. ! LD..A_e: >2000 ing/~ oral, rat Aeu~e Overexposure.. Irrlta1~n{i by contact with sun. Res and mucous membranes. Irritating to I respiratmy tract if inhaled. Irritating tO gas~4~lntestJnal tract if ingested. May cause =[isrrllea, circulatory cITsturbances and central nervous syslem depression. I sensitization reaclfons of the skin and tract. May cause Chronic Overexl~osu ,m: May res~mtory derrnatrls and bronchial asthma. IJa~-~0-98 0~:40a~ From-Properties 'tment 510210588~ T-972 P.11/48 F-333 I I I SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Data None available. I ,Chemical., F_ate Data None available, ISECTION 13. DISPOSAL CON._~ICIERATIONS .... I D ischarging ~hls material to the sewer may require a permit. Do not discharge to septic systems. Observe all local, state and federal mgulation.s when disposing of this material. M~terlal exhibits "corrosive" hazardous waste characteristics. I iSECTIO... N 14. TRA .NS. PORTAT!0N iHFoR~ATI0, '"i .... ,Component,DOT Shfpr~in_qName.- corrosive liquid, N,O,S. (para'Phenylenecliamine derivative) .F]a~,.a '.rd Class.- 8 UN Number=. UNI?6O ..EackinaGrouo: III Box DOT Shiol=irl= Name Corrosive liquid, N.O.S (p-Phe~ylenediamine derivative, Potassium I H~roxk~) Hazard, Class: 8 UN Number=, UN1700 P.,aekin~ Group; III I Other Instructi,ons'. Pro~luc~ is la~elled in accom w~h U.8.49CFR. IS, ECTION !5. .R'EG'u'LAT~RY !NFORMATION ........ . ..... c~r~adian SAR~~ "Clean '~ CAL Water Y N N N N FI p-Phenylenediamine Derivative 'Y N Y N N N I Sodium Sulfile Y N Y N N N I All Ingredients comply with EPA T~A requirements. ISECTION 16. 0'~ER INFORMA~ON ........... IThis Inlrormatlon is provided without vrarmnty. The information is believed to be eon'ecL This Information sl~ould be use~ lo make an independent determination of the methods to safeguard workers and the environment. I I I From-Properties r tment 51021068B~ T-972 P.12/48 F-333 Jan~-20-98 ~9:41am ~ MATERIAL SAFETY DATA SHEET CP-4O FAll P1-R Developer Part C · IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-930! ISECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name CP-40 FAll P1-R Developer Part C Procluct Code 03021100 MSDS Code 03021100C Procluct Size Distributor Manufacturer Fuji Photo Film, U.S.A., Inc. Fuji Hunt Ptlotographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Box S88 Elms-ford, NY 10623 Paramus, N.J. 07653 USA (914)789-8100 Prepared by Fuji Photo F~m U.S.A., Inc. Revision Date 11110/g4 Issue date 11/14/94 I SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS_ ...... lnaredient ' C .As.,r, lumber wei,qht % Water 7732-18-5 45-59 Potassium Carbonate .......... 584-08-7 31-~1 Potassi u m Hydroxide 13113-5~3 5-7 Aminopolycarboxylic Acid Derivative 7379-27-3 5.7 SEC'IION 3, ~AZARDS IDENTIFICATION CASE OF CHEMTREC (800 Material is a deer, colorless liquid. No unusual fire hazarcls Imown. I Wear ec~pment to protec~ eyes, skis ancl respiratory tract. Dike or absorb spills to keep matedal and mn-off from entering sewer or watenvays, Use water spray to cool containers and disperse vapom. I Box contains Consult all multiple components. MSDS's. H_M!SRatinq Health 2 Fire 0 Reactivity 0 Protection C I.NFPARatinq Health 2 FiT 0 Reactivity 0 Speciflc Hazaffts None Hazard rating 0 = minimal 1-- slight 2 = moderate 3 = serious 4 = severn C = gloves, goggle,,; and apron UN UN1760 ERG Guide 81) .P0~e~tlal Hea~tfl E s ~ contact causes InltatlOlt. May cause burns. Eves: Contact causes irritation. May cause bm'ns. I Inhalation: Causes irritation to resi:iratory tract and mucous membranes. May cause bums. May caUSe difficulty in breathing and coughing. Incmstiop: Causes irritation to stomach ancl gastrointestinal tract. May cause bums. May cause I vomitting, diarrhea anti bleeding in ~e,.5'tomactL Corlditiol~s aqRravated by_ exl3osu~ff[ Skirl sensitivity. Carcinoaenicitv Are any inored~err~ I~stecl as carcinogens? IARC? N NI'P? N OSHA? N I ~rtment 5]0210688'/ T-972 P.]3/48 F-333 Fr~-Properties I SECTION 4. FIRST AID M~URES Flus~ ey~ with la~e amounts o~ w~er for at lea~ 15 min~es. See a medi~l do.or immedl~e~. Skin: Flush la~e amounts ~ot~l~. a ~th of water. RemDve ~ntaminatea ~ -~ d~or ~ ~, r~n~ or i~aon develop. Inhalation: Move to ~h air. If vi~im ~ having diffi~lly breathing, one o~en if available. If ~im is n~ bma~ing, ~ CPR. G~ immobile meaJ~l ~ent~n. inae~ion= Do not indu~ vom~ng or give an~hi~ by mo~ ~o~ eme~en~ medi~ in~m~ons. Immediately seek medi~l a~ention. Call ~i~n ~n~l ~nt~ at (202)625-3333. I~ vi~ is un~nscious, tmin~ ~monnel should ~a~ CPR. Never give an un~nsc~ous pe~n an~ing by mo~. JSEC ON 5, FIREFIGH~ING ~SURES .__ Flash Point None U~r Flammable Lime Not appll~le ~o~r Flammable L~E Not appli~ble A~aian~on Tem~e~m Hon~ E~inauishin~ madla Ch~se media su~able for su~unding mate~al~ No ~om on media ~sed on ~ge of~b m~e~al. E~e a~ and ~gM tim from a ~fe d~n~. Wear ~ive p~m ae~ ~lng ap~ a~ ~ e~s and s~n. U~ w~er to ~1 fi~~d ~[nem,-to pmte~ pe~nnel a~d to di~ va~m and sp~ls, W~r runoff ~n damage the e~me~ ~ke a~ ~11~ ~ ~ to fight tim. Keep unne~ and unpmte~ pemonnel ~m e~ ~ ~ill a~. Wear a~mp~e ~othi~. S~ ~ Co~ls se(~n. A~ spill ~h Ine~ m~, ~p up a~ hold in la~ll~ DOT ~iner far algal. Dike la~e ~i~ to minimi~ ~e s~l a~. M~e~al ~n en~mnmemal damco. Pmve~ material ~m ~minati~ ~il or e~eHng ~r ~ ~es of ~. I~ECTION 7; ~'ANDLING ANEW'STOOGE .... . Handline W~ ~ughly a~r handling. A~ ~a~ ~h s~n. A~d ~ma~ ~b ~. AvoM breathing mi~, du~, va~m ~ fum~ Ha~! ir ~1~. Sto~qe ~om In ~ol, d~, ~l~ve~lal~ ama ~ from ig~m~ble m~e~a~ ~ in Se~on 10. ISEC~ONvenfllafion R~uimman~: ~ ~POSURE CON~O~ AND'PE~SO~ PROT~ON ~au~ to sa~ ~e ~uimmen~ of ASH~E 62-1989. ~m go~ m~ng w~ f~ air suppli~ at a minimum ~ 0.5 pemoqal Pr~Ive Equlp~ent; Use ~emi~l splash g~gl~. Be oe~in ey~s~ is In the ~ e~. Wear neoprene, n~le m~r or ~.er ~emi~l ~ glw~ a~ apron ~ lab ~. Respi~o~ ~ion is generally ~ required. Refer to 29C~ tg10.1~ for OS~ ~uire~e~. ~2 ~11~ I Ja~-20-98 eg:44am From-Properties rtment 5102106887 T-gT2 P.14/48 F-333 I. I ,Exposure Guidelines_'. lnqredient OSHA PEL ~ACGIH. TLV Water Nol established .. No! established I Potassium Carbonate Not established Not established Potassium Hydroxide 2 mg/m~ (c) 2 rog/m,= (c) Aminopolycarboxylic Acid Derivative Not es~ablishecl Not establishe(l ! I SECTION 9. PHY.S!C.AL A~D {_.~EMICAL P.R, 0PERTh. ES ' Ar)Pea_rance; Clear, colorless liquid .Odor:. No~e Boilirlq Point; api3mx. 100"C ,Odor. Threshold; No data S~ecific Gravity:.. 1.4.54 Rea~ with Water~. Nene Vaoor Pressure: approx. 15 mm HI] ~ No data EvaRoratf_ on Rate_.-I (water=l) Flree~inu_ Point; No i:lata -Percent Volatile: N/A Parcent_VOC: No data Selubilltv In Water:. Completely _Vm3or Dens~ No data ~H: 14. Watqr...Ofl Partifloq Coeft]clent~ No data IsEcT o. i c raw.. ' ' '..__ ' .i '." Hazardous polymerization wai not occur if product is asea and stored as directed. Product is staDle if used and slored as, directed. .Hazardous Deco,~poslffon ProductS: Carbon dioxide. Materials to avoid: ~long acid.';. OxicEzers. C~onditions to avold: Excessive heat. ISECT~ON 1~. ToxIC~)LOGI'~AL INFORMATiON ". .... '' ': .' ..... . : ~---~o: >2000 rog/kg omi rat Acute Overexposure: Irritating by contact with sldn and eyes. May cause bums to skin, respiring/tract and gastminlestinal tracL May cause bloody vomitous diarrh~;a. May cause esophegeal perforation. Chrol~ic Overexposure.' May cause pneumonia. May cause delayed esopllageal Cllronlc dermat/tis. strlctu.m. May cause glotti~ edema leading to ashy=da. IJa~20-98 99:45am From-Properties ~rtment 51021068~7 T-gT2 P.I§/48 F-333 SECTION 12. ECOLOGICAL INFORMATION Ecotoxicltv Data None available. .Chemical F...ate .Datq None avialable. ISECTION 13. DISPOSAL CON.SlDERATIC~NS -' ' Discharging ~is materlal to the sewer may require a permit. Do not clisc~arge [o septic syb-tems. Obsewe all local, state ancl federal regulations when disposing of this material. Material exhibits "corro:~ivc" hazardous waste characteristics. Comoonent DOT_Shio~inq Name: corrosive Ilquide, N.O.S. (Potassium hydroxide, Potassium camormte) Haza~ Class= 8 UN Number:. UN1760 Packlna Group; III : ~BoxDOT Shi~inqName Corrosive liquid, N.O.S (,o-Phenylenediamlne derivathre, Potassium HydmxJde) Hazard Clas.s: 8 _UN Number:. UN176D Packin.q.Group= I!I Other Instructions: Product Is labelled in accordance with U.8. 49CFFL I All Ingredients comply with EPA TSCA requirements. I ISl~CTION 16, OTHER_INFORMATI_- 0N ..... This information is pmvicled without ,nrarranty. The Information is believed to be correct. This information should be usecl to make an inclepenclent delennination of the methods to safeguan~ worker~ end the i envlronmeflt. I I'lge4 c~4 I 0~021104~ .lan'-20-98 ~9:4~a~ From-Properties r tment 510210688T T-972 P.1G/48 F--q33 J~ MATERIAL SAFETY DATA SHEET cP-40 FAll P2-R Bleach-Fix Part A IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 lSECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name CP-40 FAll P2-R Bleach-Fix Part A -' Product Code 03021106 MSDS Code 03021106A Product Size 4 x 1 liter Dlstrib Lrtor Manufacturer Fujl Pl~oto Film, U.S.A,, Inc. Fuji Hum Photographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Bc~x 988 Elmsford, NY 10523 Paramus, N.J. 07653 USA (914)789.8100 Prepared by Fuji Photo Film U.S.A., Inc. Revision Date 11110/04 Issue date 11/14/94 l SECTION.,2.. C .0MpOS. I ,T!.ON~,.~ND INFORMATION ON INGREDIENTS InQrediept CAS Number WelQht Water 7732-18-5 33-57 Ammonium ThioSulfate .......... 7783-18-~ 23-33 Ammonium Sul~te 1'0196-04-0 10-20 Ammonium Nitrate 6484-52-2 5-7 Acet~ AclcI 6~-19-7 5-7 SECTION :3. HAZARDS IDENTIFICATION .... · IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 Mater/al is a clear, colorles~ liquid. ~ I May pmduca toxic gases under fire c~clitlon~. Wear equipment to protect eyes, skin al~cl respiratory tract. Dike or absorb splits to keep mate~al and run-off from entering sewer or wate~eays. Use water spray to cool containers and disperse vapors. I May produce toxic gases in fire conditions or if mixed with bleach. Box contains multiple components. Consult all MSDS's. ~i~IIS Ratinq Health 1 Fire 0 Reactivity 0 Protection C IHealth I Fire 0 Reactivity 0 Specific H.:~ ~.m'ds None NFPA Ratine Hazard rating 0 = minimal 1= sligl~t 2 = ~e 3 = serious 4 = severe C = gloves, goggles and apron UN None ERG Guide 60 ~otential He.a!th E~ects ' Skln.__~ Contact may c~use irrit;~lon. I Eves: Contact may cause irritation. InhaJatip. n; causes irritation to respiratory tract, Asthmatics am said to be dangerously sensitive to even minute amounts of sulfides. May cause eyes to water and dlfflcult breathing. I !n;estion: Causes irritation to stomach and gastrointestinal tract. May cause abdominal pain. May cause vomitting and diarrhea. May have effects on the blood, kidneys and liver. Conditions aQQra~dby exp.os, ul_~ Skin se~. Asthma. I ..Camino.qenicity Are any ingredients listed as carcinogens? IARC"? N NTP? N OSHA? t,l I~gel at4 Jan-'20-g8 F rem-Pr°perti es Ir tment 5102106887 T-g72 P. 17/48 F-3~3 Eyes: Flush ey~ ~th la~e amounts of ~ter for at lea~ 15 min~es. See a m~l~l do.or Immed~tely. Skin.' ~ush s~n ~h I;~e amours of water. Remove ~ntaminat~ ~othing. See a do. or ii rash, mdne~ or i~alion Inhalation: Move to fresh ai:r. If ~im ~ having diffi~l~ brushing, gi~ o~gcn if availaMe. If vi~im is not bm;~thing, ~a~ CP~ Get imme~iate medi~l a~e~ion. !n~e~ion; Do not ~du~ romping or g~e an~ Dy mou~ ~ho~ eme~en~ m~i~l in~io~. Imm~iately seek medl~l aEenlion. Call po~ ~n~l ~nter at (202)~3333. i¢ ~m ~ un~ns~ous, ~in~ pe~nnel should ~a~ ~R. Never give an un~cie~ pem~ an~ing by moulh. ~SEC~ON 5. FIREFIGHTING M~SU~S Flash Point No~e ...... Up~r Elam~ble Limit N~ appll~ble goer Fla~ble ~mff N~ appli~ble A~oiqnition None ~nquisht~ media Cho~ m~ ~able for su~und~ ~eda~. No m~ on media ba~ on ~edge ~t~ material. ~mfiahtino Introns Eva~e ama a~ F~ tim from a =lie diMan~. W~r ~ive pm~ dema~ bm=hing ap~t~ and pmt~ e~ ~ sun. U=e ~ter ~ ~ol fl~~ ~malnem, to p~ ~nnel and to va~m a~ spare. W~er runoff ~n e~age ~e e~ent. Dike and ~11~ ~er used to fi~flm. May ~d~ to~c gases under tim [SECTION 6. AmlpmT~L REL~SE ..... ~ep unne~ and unpmte~ [~onnel ~m e~ed~ the sp~l ama. Wear app~ ~e c~h~g. See ~~ Co~ ~tion, ~ s~ll ~h ine~ m~e~l, ~ep up and ~ld In la~l~ D~ ~ner ~or di~saf, ~ la~e s~lls to mlnim~e ~e spill a~ ~edal mn m~ environmental da~e. Pmve~ material ~m ~in~ng soil or e~ed~ ~r or ~es ISkCfioN 7. HANDLING'~NEI STOOGE .... ! ~ W~ ~omughly a~¢r ha~li~. A~ ~ ~h ~n. Avid ~ma~ ~h ey~. AVoid b~thing m~, d~ ~m ~~ Ha~ul ~1~. Stomee ~om in ~aJ, ~, w~l~ve~l~ a~ ~y ~m in~mp~ble m~eda~ fl~ in ~on 10. ISE ON 8. ~POSURE CONTROL~ ~ND, P~RS0~L PROTEC~qN' , ' ' Ventil~io~ ~au= to ~ the r~uiremen= ~=f ASHEN 62-1~. ~sure go~ m~ng ~h ~ air S~li~ minimum ~ 0.5 Pemonal Pm~e. Equlp~e~ spl~h goggles, oa~ ey~ is in the ~ ama. Use Be W~r neoprene, n~le robber or ~,er ~emi~l ~ant glov~ and ~mn or lab ~. R~pi~o~ ~e~ion ~ generally nat ~ui~. Eef~ to 29C~ 1910.1~ f~ OS~ mquimme~. P~2 of 4 IJan~20-§8 0~:48a~ From-Properties 'tment 510210688T T-§72 P.i8/48 l:-~33 I I _Exposure Guidelines: !nQredient OSHA PEL ACGIFI T!r~V Water Not established Not established I Not eb-tablished Not established Ammonium Thio~ulfate Ammonium Sulfite Not established Not established Ammonium Nitrate Not established NOt estaD[iShed I Acetic Acid 10 pPm 10 ppm ]SEC~ON s: pHYSICAL AND'CHEMICAL PROPERTIES Appeam. rlce~ Clear, colorless liquid Odor. Slight vinegar .B_oilina Point: approx. 100~ Odor Thresh,old: No data ~Specific Grayity: 1.261 ,Reactiv~y With Wee ~ None Vaoor Pres,.sur~; approx. 15 mm Hg Mehina Point: No data Evaporal~ion Rate,: 1 (water=l) Free~:inQ Polnt: ~ No data Percent Velalile: approx. 45 Percent_ VOC., No data So!ubllltv in Waten Completely Yaoor Defi.sit~., No data PH.'_ s.sa Water-Oil Partition Coefficient= i~ data I.SECTi0N lO. Sl'ABILITY'N~P REACTIVITY ........ , .... ' ,, ', ' Haza~ou~ polymerization will not occur if product is used and stored as directed. Produc~ Is ~taMe I~ used and st~red as directed. Ha?~rdous Decompqsfflon Produ~s.' Ammonia. Carbon dioxide. Sulfur dioxide. Nitrous ex, es. MaterialS to a~,gid: ~ng ac[ds, Reducing materials. Bleach. Hypochlorites. .Con,difions to avoid.- Excessi~t he~ ~..~a: >200~ ml~ oral, rat · ! vomilJous and dianllea, uremia or circulatory collapse if ingested. May cause respiratory irritation, lachrym~on, edema or pneumonia if inhaled. Chronic Ovem, xppsure: Chronic dermatiti& May cause central nervous system depression. May cause systemic ackiosis. May cause esophageal er gastric stricture. May cause leslons on the heat and liver. PIg~a of 4 I Jan-20-98 69:49am From-Properties rtment 5102106887 T-972 P.19/48 F-333 I ISECTIoN 12. ECOLOGICAL INFORMATION E(:otoxicity Data None availabl{~. I Chemical.Fate para None availabl~ ISECTION 13. DISPOSAL CON.~iIDERATIONS L , , ·., - , I Dis~argino this material to the ~ewer may require a permit. Do not discharg~ to septic systems. Observe all local, state and federal regulations v~hen disposing of this material. Material does not exhibit hazardous ws~e characteristics. I ISECT ON 14: TRAt, NSPORTAT~'ON INFORMATION ; Component DOT Shi~Pin~ Name: N,~t DOT regulated. I .... - Contains ammonium salts. Hazard Class_; None UN Number:. None pac.k.inq Group; Nol~ i Box DOT Shipp. in.q Narne Not DOT regulated. ._J~?-_rd Clam.. No.e U~ Number:. None Pacldn~ Gmat: Noae I Other !ns~ructiOps.' Product is labelled In acco~lanc~ with U.S. 49CFR. IS~CTION 15. REG'" LATORY INFORMATION ..... ....... canadian SARA' Clear CleaR CAL.- i lrmredie, pt ~rSCA Ust 351/312 ~ Wat.~ Pro~.65 Water Y N N N N N Ammonium Thiosuffate Y N Y Y · Y Y I Ammonium Sulfite Y N Y N Y N Ammonium Nitrate Y N Y N N N Acetic Acid Y . Y Y Y N N I All ingredients comply with EPA TSCA requirements. JSEC:TION 16. OTHER INFORMArjOE . " ' , -,_ - This information is pmvkled w~hout warmnb'. The information is believed to be cormcL This information should be used to make an independent determinatio~ of l~e methods to safeguard workers and the en¥ironment. I I i ~211Q6A Fr~-Properties rtment 510210688T T-97Z P.20/48 F-333 Jan'--20-98 CP-40 FAll P2-R Bleach-Fix Part B IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 I'SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name CP-40 FAll P2-R Bleach-Fix Pad B Product Code 03021106 MSDS Code 03021106B Product Size 4 x 1.05 liters Digtributor Manufa~urer Fuji Photo Film, U.S.A,, Inc. Fuji Hunt Photographic Chemicals, Inc. 555 Tax'mr Road West 115 Century Roacl P.O. Box 988. Eimsford, NY 10523 Paramus, N.J. 07653 USA (9t4)789-8100 Prepared by Fuji Photo Film U.S.A., Inc. Revision Date 11/10/94 Issue date 11114/94 }SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS J Inqredient .CAS Nurrlber yVeloht % Water 7732-18-5 53-75 Ferric Ammonium EDTA · ~.-: ....... 21265-50-g 17-27 Ammonium Bromide 12124-97-g 7-17 Nitric Acid 7697-37-2 1-3 [SECTIO ,N, 3._HAZARDS !PENTIFiCATION . I- IN OF EMERGENCY, CALL CHEMTREC 00)424-9:300 Matedal is a clear, recl-larown liquid. May proc~u~ taxic gases in fire ccoditior~ or if mixed with blea~. Wear equipment to protect eyes, --kln and respiratory tract. Dike or absorb spills to keep matedal and mn-of/from entedng sewer or watenvays. Use vcater spray to cool containem and disperse vapors. Box contains multiple componerr~, Consult all MSDS's. HI~IIS Ratlno Health 1 Fire 0 Reactivity 0 Protection NI=PA Ratfnc~ Health 1 Fire 0 Reactivity 0 Specific Hazards None Haza~ Fating O = minimal 1= slight 2 = moderate 3 = serious 4 = severe C = gloves, goggles and apron UN None · ERG Guide 60 PotentialHealth Effects Skin: Contact may cause irrilation. May cause rashes. ~ Contact may cause irrf~mion. May cause permanent eye damage, j ~ Causes irritation to respiratory tract. May cause drowsiness, vertigo and breathing difficulties. Incmstion'. Causes irritation to stomach and gastrointestinal tract. May cause nausea, diarrhea and - vomlttlng. May cause bums to the mouth, throat and stomach. Conditions actelravatedb_v expasu..~.m Skin sensitivity ' .C.p, rc!no, qenlcity Am any ingredit;rrts listed as camlnogens? IARC? N qTP? N OSHA? N Pe~l I From-Properties ~r tment 510210688T T-972 P.21/48 F-333 Ja~-20-98 Eves: Flush eyes w~th large amounts of water for at least 15 minutes. See a medical doctor immediately. I Skin: Flush skin witl~ I~rge amounts of water. Remove contaminated clothing. See a doctor if rash, redrtess or irritation develops. I Inhalation: Move to fresh air. if victim is having difficulty breathing, give oxygen ir available, if victim Is not breathing, start CPR. Get immediate medical attention. Ingestion.- Do not Induce vomitting or give anything by mouth without emergency medical in.ructions. Immediately seek medical attention. Call pbison control center at I (202)625-:~33. If victim is unconscious, trained personnel sl~ould start CPR. Never give an uncon.~ious person anything by mouth. I ISECTION 5, FIREFIGHTING MEASURES .. ....... :~ - J Flash Point None Upper_Flammable Llm~ Not applicable Lower Fie .tamable Limit Not applicable I AutoiRnifiqn Temperatq.re None J Extinnuishingmedia Choose media suitable for surrounding materials. No restrictions on media based on knowledge of this I material. FirefiQhtinojnstmctions - Evacuate area and fkjht fire from a sal'e distance. Wear Pes~tive pressure demeJ d breathing apparatus I and protect eyes and skin. Use water to cool fire-exposed containers, to protect p :monnel and to disperse vapors and splits. W~ter runoff' can damage the environment. Dike and coliectw ~ter used to figl~t fire. May produce toxic gases in fire conditk~s or if mixed with bleach. ! , ISECTI.°N 6'.ACC. IDE,NT'~L RE~EASE ,. -. ,. i i Keep unnecessary and unprotected personnel from entedng the spill area. Wear appropriate protective clothing. See Exposure Contro(s section. Absorb spill with inert material, sweep lp and hold in properly labelle~ DOT corrlainer for dispesal. Dike large spills to minimize the spill area. Material can cause environmental damage. Prevent material from contamln.atlng soil or entering se~ er or bodies of water. I ]SECTION 7.--:---HANDLING ANDSTORAGE _- ,- ' ' ! Washth°roughly a~te, I~andling. Avoid contact v~h skin. Avoid ~ntact with eyes. Avoid Handlin~ breathing mist, dust, vapors orfumes. Harmful ifswallowecl. 1. I 8to .['aqe Store in cool, dry, well-venffiated area away from IncompaUble m~terials rmod in Section 10. I ISECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTEC~I'iON , , I VenUlation Requirements: Exhaust to satisfy the requirements o'[ ASHRAE 62-1989. Ensure good mixing w th fresh air supplied at a I minimum of 0.5 cfm/Itz i Personal Protectfve_Eq uiprrmnt: Use chemical splash goggles. Be certain eyewash is in the work area. Wear neoprene, nitrlle rubber or othe~ chemical resistant gloves and apron or Iai coal I Respiratory protection is generally no( required. Refer to 29CFR 1910.t 34 for O~HA requirements. P~- of 4 From-Properties ~rtment 510Zl OI;81~T 1'-972 P.22/48 F-~33 Jan-20-98 O~:53am Exl3osure Guidelines: hl{3redient OSHA PEL ACGIH TLV Water Not established Not established Ferric Ammonium EDTA Not established Not established Ammonium Bromide Not established Not established 2 ppm (TWA) Nitric Acid 2 ppm (TWA) 4 ppm (GTE]_) I SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES ......... I A~vearance: Clear, red-brown liquid Odo~ None Boilinq.f~01.nt: approx. 100~C Odor Threshold: ~1o data i $pecific Gmv~/:. 1~11 Reactivity_with Wate~ ~lone ~3.~g.r..l~.~3~ approx. 15 mm Hg Melfl_n~. P. oint:. 40 data Eva~oration Rate;, I (wader=l) F~. ~io data i Percerl~Volatile: approx. 60 " ~ ~o data Solubilitv'JnWatec Completely Vapor Densit~ ;o data I Water_-OJl Partition_Co~_fficlent; No data. ISECTION 10. STABILITY AN~3' REACTIVITY IHazan~ous polymerization will not occur if product is used anti stored as directed. Product is s~able if ~sed and stored as ¢lirected. Hazardous pec.omr)osition Producl~ Ammonia. Carbon dioxide. I Materials to,.avold~ Stror~j acids. Strong bases. Bleact]. Hypochlorite. C_onditions to avoid.- .Exce___~sive lleat. I_O;o: >2ooo mg4q I ~cute Overexposure: Irritatir~l by contact ~ sldn and eyes, May' cause c,g! naal corneal · opacificaiton. May cause skin rashes. Inhalation ma; cause ataxia, nausea an~l ~splmtory effects. Ingestion may cause bums t~ ~outh and gastrointestinal tract. I Chronic Oy/emxposu_ .m; ~ cause neurological effects. Ingestion of large d{: '~ may causa gaslrlc hemorrhage. May cause renal failure and ischemlca !, Siorm on the liver and I head. Jan-20-98 09:54am From-Properties r tment $10210688? - T-972 P.23/48 F-333 E~toxic~ Data Nene available, Chemi~l Fate O~a None ay.ailable. ISECTION 13. DISPOSAL CONSIDE~TIO'Ns " , _ ' ~., Dls~a~i~ this matedai to the se~r may require a pe~. Do not disch~e to se~ic s~e~. O~e Matedal do~ n~ ~ibit h~a~ous wa~e ~am~e~. ISECTION 14. T Nspo TA O iNFORMA ON , ' Component DOT Shlp~in~ Name: N~T~ulaI~. '" : .- .' Ha~ Class; None UN.N~be~ None packln~ Grou~: None Box_DOT Shi~olna Name Not DOT ~ulat~. H~a~ Cla~: None UN Npmbe~ None pa~n~ Grou~ None .lnamd~e~ ~CA ~er Y N N N N N Fe~c ~onium ~TA Y N Y N N . N ~onium Bm~e Y , N Y N N N N~dc ~d Y Y Y N Y N should ~ us~ to make ~ indepe~,e~ dete~[a~on ~e m~ en~mnm~. I ~ c~4 I Oa~llOl~, . MATERIAL SAFETY DATA SHEET CP--4o FAll P1-Ss Developer Starter IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 ISECTION 1. CHEMICAL PRI3DUCT AND COMPANY IDENTIFICATION Product Name CP-40 FAll P1-Ss Developer Starter Product Code 03021110 MSDS Code 03021110 Product Size 10 x 425 mis Distributor Manufacturer Fuji Photo Film, U.S.A., Inc. Fuji Hunt PhOtographic Chemicals, Inc. 555 Taxter Roacl West 115 Century Roacl P.O. Box 988 Elmsford, NY 10623 Paramus, N.J. I)7653 USA (914)789-8100 Prepared by Fuji Photo Film U.S.A., Inc. Revision Date 11110/cJ4 Issue clate 11114/94 {SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS ~ CAS Number Weiqht % Water 7732-18-5 77-85 Potassium Carbonate "- ...... ~ 584-08-7 7-10 Soaium Bicarbonate ,. 144-55-8' 5-7 Potassium Chloride 7447-40-7 3-5 Aminopolycarl3mcylic Acid 67-43-6 0.5-1 I !SECTION 3. HAZARDS IDENTIFICATION I '--NCASE RGEN' .... ""' "'" ' '"~300 ...... '; , OF EME cY, CALL CHEMTREC (800)424- Material is a clear, colorless l/quid. I No unusual tim conditions known. Wear equipment to protect eyes, ~n and respiratory tract. Dike or absorb spills to keep material and mn-off from entering sewer or waterways. Use water spray to cool containers and disperse vapom. I ~MISRa,tinq Health 1 Fire 0 Reactivity 0 Protection C I NFPA Retina Healttl I Fire 0 Reactivity 0 Specific Hazards None Hazard rating 0 = minimal 1= s~igl31 2 = moderate 3 = serious 4 = severe C = g loves, . goggles and apron UN None ERG Guide 60 P~otentlal Health _ Skin: Coronet may cause irritation. I Eves: Contact may cause irritation. ~ May cause Irritation to mucous membranes and respiratory tract. i InQestion: May cause nausea, vomitting, diarrhea and abdominal cramping. Conditions ao~3rayated bvexloosure None known. I _Carcinoq.eni.c;ny Are any ingrodieots listod as carclnogens? IARC? N NTP? N ost-U~,? lq Fagel of 4 Jan'-20-gB 0'9 :SSam Fro~-Properties r tment 5102106887 l'-gFZ P. 25/~I8 F-~133 I SECTION 4. FIRST AID MEA.~;URES Ev_es: Flush eyes with large amounts of water for at least 15 minutes. See a medical doctor immediately. Skin: Flush skin with Iago amounts of water. Remove contamlnated clotfllng.' See a doctor if rash, r(~tness or irritation develops. lnhalatiolrl: Move to fresh air. If victim is having difficulty brea~ing, give oxygen il' available. If - ' victim is not breathing, start CPR. Get immediate medical attention. Jn.qestion: Do not Induce vomitting or give anything by mouth without emergency meeical instructions. Imalediately seek medical attention. Call poison control comer at (202)625-3333. If vlctlm is unconscious, trained personnel should start C.~R. Never give an unconscious person anything by mouth. Flash Point None Upner Flammable Limit Not applicable ~.ower Flammable Limit ~Not applicable Amolanlflon Temoerature None Extin~ulshine media Choose media suitable for surrounclic~3 materials. No restrictions on media based on knowledge of this material. FlrefiQhtinQ instructions Evacuate ama and fight fire from a safe distance. Wear 'positive Pressure demand breaUllng apparatus and protect eyes and skin. Use water to cool fire-exposed containem, to protect per sonnel and to disperse vapors and spills. Water runoff can ¢lamage the environment. D~e and collect wet ;r used to fight tim. No unusual fire conditions known. ISEC 'iON S. A,C, CiDENTAL RE.[LEASE . '" , ' . ........ Keep unnece_s~y and unpmtecte~ personnel from entering the spill area. Wear qppropriate protective clothing. See Exposure Controls secllon. Absorb spill with inert material, sweep up and hold in properly labelled DOT container for disposal. Dike large ~-pills to minimize the spill ama. Material can cause environmental damage. Prevent ma~ial from. c~ntaminating soil or entering sewe!' or bodies of water. ISE .c'n,o. 7. HANDLING AND'sTORAGE .......... Handlina Wash thOrOughly aft{~'handling, Av°i~l contact with skin. Avoid co~tact with eye. Avoid brealhing mist, dust, vapors or fumes. Harmful if swallowed. . / StoraQa Store in cool, (IFF, w~lPvenfilaled area away from incompatible materials listed in Section 10. ISECT[ON 8. ,EX,POS[J~E Co~iTROLS AND PERSONA,,L. PROTECTION, _Va~tilatlo,n Requirements..'_ Exhaust to satisfy the requirements ef ASHRAE ~2-1989. Ensure good mixing with fresh air supplied at minimum of 0.5 cfnVffz Personal Protective E~uipm, en~ chemical splash goggles. Be c~;naln eyewash is in the work area. Use Wear neoprene, nitrile rubber or other chemical resistant gloves and apron or lab coat. Respiratory protection is generally not required. Refer 1o 29P-.FR 1910.1~14 for OSHA requirements. PIlO~I of 0~021110 I dan~20-98 t~9:57~ From-Properties ~rtment 5102106887 T-972 P.26/48 F-333 ii Ext~osum. Guidelines: I .InRredient OSHA PEL ACGIH TL~/ Water Hot established - Not established ':: ~ Potassium Carbonate - NOt established Not establl'shed. I Sodium Bicarbonate Not e~tablished Not established Potassium Chloride Not established Not I Aminopolycarboxylic Acid Not established Not established I8'E,C, .TION 9. PHYSICAL AND CHEMICAL PRoPER~I~.s".'' II ' Appearance: Clear. colorless iiqui~l Odor=.pdor Tht'eshpld:' * ~one~n ~I ,Bqilinq Point: approx. 100°C data Specific Gravity: 1.16 Reactivity_with Water,otto I, _Val~or Pressure: approx. 15 mm Hg Meltin~ Point: ..~.~1o data E'vaporation.Rate: 1 (wateml) Frpe. ~nq Polnt: "; No data Percent Volatile: approx. 60 . Percent VOC: No data Solub.~iW in Water=. Completely Val~or Density. No data oH: 9.$ Water. Oil Parfltlqn j~oell~clent: No data ISECTION 10. STABILI'i'Y AND REACTIVITY' .. Hazardous polymerization will not occur If product Is used and stored as directed. '-'~'- Product Is stable If used arid storb~l as ~li~ected. · Hazardous pecompos..ition Product~:_ Carbon dioxide. Materials to avo~f; ~rong aci~. Ox~dizem. _C._ondiflons to avoid: Excessive heat. ISECTibN 11. ToxI~OI~SGiCAIL. INFORMATION I ~.Dso: ~,5000 rl~g oral. rat Acute Overexposure: Irritatir~l I~ ~ontact with skin and eyes. Irritating to respiratory tract if Inhaled. Irrilatir~ if ingested. May also cause alkalosis, nausea, vomitting, diarrhea and abclominal cramp[rig. Chronic Overexposure: No specific effect~ of chrorllc overexposure are knowrl. Plgl~ of 4 ~1021110 · .IEcoloxicity Data. None availal:te. ,. .,. ChemicaJ.Fale Data .None available. .,- ,'_-"~, JSECTioN 13.-DiSPOSAL'Col~i$iDERATIONS ~ . _: _ j Discl~arging this material to the sewer may require a permit. Do not discharge to septic systems, Obsente all local, state and federal regulation.'j when disposing of this material. Material does nat exhibit hazardous ~vaste characteristics. SECTION 14: TRA .NSPO RTA,'I~ ~ "--'-"-'-, _~ '] Component DOT shim3lnClName: Not DOT regulated Haza~Clasm None · UN N~qmb_er: Npne tl] a~ None Box DOT Shio~3lna Name Not DOT regulated ' iiII · J-lazard ,Class= None UN, Humber: None ~ l~ckina Gmu!3., None Other ~nstKu, qiorlS~,- Product is labelled in accordance with U.S. 49CFP.. Inomd!em'_ :TSCA Potassium Carbonate Y N Y ! N N N Soclium Bicarbonate Y "N N J N N N Potasslure Chloride 'Y N ¥ J N N N Aminopolycarl=oxylJo Acid ..Y : N N N N All ingredients coreply with EPA TEJCA requirements. This inl'ormation is provided wilhaut warranty. The information is believed to be ce rrect. This infon'nation should be used to reake an indeper~dent determination of ttte methods to safeguar I workers and tire i environment. P~4 of 4 Fuji CN-Series Product Material Safety Data Sheets I' J~ MATERI/~SAFE~ DATA SHEET CN~I~Q NQ1-S Developer Starter c,s. o. ( 0014 4- 00 I lSECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name CN~16Q NQI-S Developer Starter I Product Code 03015112 MSDSCode 0301511 x235mls 2 Product Size '1 0 Distributor Manufacturer i Fuji Photo Film, U.S.A., Inc. Fuji Hunt Photographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Box 988 Elmsford, NY 10523 USA Paramus, N.J. 07653 USA (914)789-8100 I Prepared by Fuji Photo Film U.S.A., Inc. Revision Date 11/14/94 Issue date 11/14/94 I I SECTION 2. COMPOSITION AND INFORMATION ON.INGREDIENTS. Inqredient CAS Number Weiaht % Water 7732-18-5 69-85 I Potassium Carbonate 584-08-7 8-18 Sodium Bicarbonate 144-55-8 5-7 Potassium Bromide 7758-02-3 1-3 I Sodium m-Bisulfite 7681-57-4 1-3 {~E¢~TION 3. HAZARDS IDENTIFICATION IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 Mat(~riai is a clear, coloHess liquid. No unusual fire hazards known. Wear to skin and tract. Dike absorb spills to matedal and equipment protect eyes, respiratory or keep run-off from entedng sewer or waterways. Use water spray to cool containers and disperse vapors. Asthmatics are said to be dangerously sensitive to even minute amounts of sulf'ftes. HMIS Ratinq Health I Fire 0 Reactivity 0 Protection C NFPA Ratinq Health I Fire 0 Reactivity 0 Specific Hazards None Hazard rating 0 = minimal 1= slight 2 = moderate 3 = serious 4 = severe C = gloves, goggles and apron UN None ERG Guide 60 Potential Health Effects Skin: Contact may cause irritation. Eyes: Contact may cause irritation. Inhalation: May cause irritation to the respiratory tract. Asthmatics are said to be dangerously sensitive to even minute amounts of sulfites. Inqestion: May cause irritation to the stomach and gastrointestinal tract. May cause abdominal pain, vomitting and diarrhea. Conditions aqqravated byexposure Asthma. Skin sensitivity. Carcinoqenicity Are any ingredients listed as carcinogens? IARC? N N'I-P? N OSHA? N Page1 of 4 0:3016112 I /SECTION 4. FIRST AID MEASURES Eyes: Flush eyes with large amounts of water for at least 15 minutes. See a medical doctor I immediately. Skin: Flush skin with large amounts of water. Remove contaminated clothing. See a doctor if rash, redness or irritation develops. I Inhalation: Move to fresh air. If victim is having difficulty breathing, give Oxygen if available. If victim is not breathing, start CPR. Get immediate medical attention. Inqestion: Do not induce vomitting o{' give anything by mouth without emergency medical I instructions. Immediately seek medical attention. Call poison control center at (202)625-3333. If victim is unconscious, trained personnel should start CPR. Never give an unconscious person anything by mouth. I ISECTION 5. FIREFIGHTING MEASURES Flash Point None I Upper Flammable Limit Not applicable Lower Flammable Limit Not applicable Autoiqnition Temperature None I Extinquishinq media Choose media suitable for surrounding materials. No restrictions on media based on knowledge of this material. IFirefiqhtinq instructions Evacuate area and fight fire from a safe distance. Wear positive pressure demand breathing apparatus and protect eyes and skin. Use water to cool fire-exposed containers, to protect personnel and todisperse vapors and spills. Water runoff can damage the environment. Dike and collect water used to fight fire. I No unusual fire hazards known. m ISECTION 6. ACCIDENTAL RELEASE Keep unnecessary and unprotected personnel from entering the spill area. Wear appropriate protective clothing. See Exposure Controls section. Absorb spill with inert material, sweep up and hold in properly I labelled DOT container for disposal. Dike large spills to minimize the spill area. Material can cause environmental damage. Prevent material from contaminating soil or entering sewer or bodies of water. I Is c,,oN 7. HANDLING AND STORAGE I Handlinq Wash thoroughly after handling. Avoid contact with skin. Avoid contact with eyes. Avoid breathing mist, dust, vapors or fumes. Harmful if swallowed. I Storaqe Store in cool, dry, well-ventilated area away from incompatible materials listed in Section 10. [SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION l I Ventilation Requirements: Exhaust to satisfy the requirements of ASHRAE 62~1989. Ensure good mixing with fresh air supplied at a I minimum of 0.5 cfm/ftz i Personal Protective Equipment: Use chemical splash goggles. Be certain eyewash is in the work area. Wear neoprene, nitrile rubber or other chemical resistant gloves and apron or lab coat. I Respiratory protection is generally not required. Refer to 29CFR 1910.134 for OSHA requirements. i Page2 of 4 0~016112 Exposure Guidelines: Inqredient OSHA PEL ACGIH TLV Water Not established Not established Potassium Carbonate Not established Not' established Sodium Bicarbonate Not established Not established Potassium Bromide Not established Not established Sodium m-Bisulfite 5 mg/m3 5 mg/m3 TWA = time weighted average STEL = short term limit (c) = ceiling [SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, colorless liquid Odor:. None Boilinq Point: approx. 100°C Odor Threshold: No data Specific Gravity: 1.231 Reactivity with Water:. None Pressure: 15 Point: No data Vapor approx. mm Hg Meltinq Evaporation Rate: 1 water = 1 Freezinq Point: No data Percent Volatile: appro~ 70 Percent VOC: No data Solubility in Water:. Completely Vapor Density: No data pH: 9.7 Water-Oil Partition Coefficient: No data ISECTION 10. STABILITY AND REACTIVITY Hazardous polymerization will not occur if product is used and stored as directed. Product is stable if used and stored as directed. Hazardous Decomposition Products.' Carbon dioxide. Sulfur dioxide. Materials to avoid: Strong acids. Oxidizers. Chlorine. Conditions to avoid: Excessive heal ISECTION 11. TOXICOLOGICAL INFORMATION L.~D o: > 5000 mg/kg oral, rat Acute Overexposure: Irritating by contact with skin, eyes and mucous membranes. Skin contact may also cause eruption-type rashes. Eye contact may cause corneal effects. Irritating if inhaled. Ingestion may cause abdominal pain, vomitting and diarrhea. Chronic Overexposure: May cause dermatitis. Bromides can cause central nervous system depression, fatty degeneration of the liver and kidneys and edema in the brain and kidneys. I Page3 of 4 I 03015112 Ecotoxicity Data None available. Chemical Fate Data None available. Discharging this matedal to the sewer may require 'a permit. Do not discharge to septic systems. Observe all local, state and federal regulations when disposing of this material. Material does not exhibit hazardous waste characteristics. ISECTION 14. TRANSPORTATION INFORMATION Component DOT Shippinq Name: Not DOT regulated Hazard Class: None UN Number:. None Packinq Group: None Box DOT Shippinq Name. Not DOT regulated Hazard Class: None UN Number:. None Packincl Groul3: None Other Instructions: product is labelled in accordance with u.S. 49CFR. Canadian SARA Clean Clean CAI_ In,qredient TSCA List 3111312 Ai__[r Water Prop 65 Water Y N N N N N Potassium Carbonate Y N Y N N N Sodium Bicarbonate Y N N N N N Potassium Bromide Y N Y N N N Sodium m-Bisulfite Y Y Y N N N Ail ingredients comply with EPA TSCA requirements. ISECTION 16. OTHER INFORMATION This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. ! Page4 of 4 133015112 J~ MATER'IAL,~AFETY DATA SHEET C'N-~E) NQ1-IR Developer Part A IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 ISECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I Product Name CN-16Q NQ1-R Developer Part A Product Code 03015100 MSDS Code 03015100A Product Size 2 x 1 liter Distributor Man ufacturer .Fuji Photo Film, U.S.A., Inc. Fuji Hunt Photographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Box 988 Elmsford, NY 10523 USA Paramus, N.J. 07653 USA (914)789-8100 Prepared by Fuji Photo Film U.S.A., Inc. Revision Date 11/14/94 Issue date 11/14/94 I SECTION 2. COMPOSITION AND INFORMATION ON.INGREDIENTS I Inqredient CAS Number .Weiqht % Water 7732-18-5 63-76 Potassium Carbonate 584K)8-7 23-33 Sodium Sulfite 7757-83-7 1-3 Aminopolycarboxylic Acid Potassium Salt 10143-41-6 0.5-1 ISECTION 3. HAZARDS IDENTIFICATION IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 Material is a clear, colorless liquid· Material may produce sulfur dioxide under fire conditions. Wear equipment to protect eyes, skin and respiratory tract. Dike or absorb spills to keep material and run-off from entedng sewer or waterways. Use water spray to cool containers and disperse vapors. Asthmatics are said to be dangerously sensitive to even minute amounts of sulf'rtes. Box contains multiple components. Consult all MSDS's. HMlS Ratinq Health I Fire 0 Reactivity 0 Protection C NFPA Ratinq Health 1 Fire 0 Reactivity 0 Specific Hazards None Hazard rating 0 = minimal 1= slight 2 = moderate 3 = serious 4 = severe C = gloves, goggles and apron UN None ERG Guide 60 Potential Health Effects Skin: Contact may cause irritation. Eyes: Contact may cause irritation. Inhalation: May cause irritation to the nose, throat and respiratory tract. Asthmatics are said to be dangerously sensitive to even minute amounts of sulfites. Inqestion: May cause irritation to the stomach and gastrointestinal tract. May cause buming pain. Conditions aqqravated byexposure Asthma. Skin sensitivity. Carcinoqenicity Are any ingredients listed as carcinogens? IARC? N NTP? N OSHA? N Page1 of 4 0301~100A Eyes: Flush eyes with large amounts of water for at least 15 minutes. See a medical doctor I immediately. Skin: Flush skin with large amounts of water. Remove contaminated clothing. See a doctor if rash, redness or irritation develops. I Inhalation: Move to fresh air. If victim is having difficulty breathing, give oxygen if available. If victim is not breathing, start CPR. Get immediate medical attention. Inqestion: Do not induce vomitting or give anything by mouth without emergency medical I instructions. Immediately seek medical attention. Call poison control center at (202)625-3333. If victim is unconscious, trained personnel should start CPR. Never give an unconscious person anything by mouth. I ISECTION 5. FIREFIGHTING MEASURES Flash Point None I Upper Flammable Limit Not applicable Lower Flammable Limit Not applicable Autoiqnition Temperature None I Extin.quishinq media Choose media suitable for surrounding materials. No restrictions on media based on knowledge of this mstedal. I Firefiqhtin(~ instructions Evacuate area and fight fire from a safe distance. Wear positive pressure demand breathing appa~tus and protect eyes and skin. Use water to cool fire-exposed containers, to protect personnel and to disperse vapors and spills. Water runoff can damage the environment. Dike and collect water used to fight fire. I Material may produce sulfur dioxide under fire conditions. ISECTION 6. ACCIDENTAL RELEASE I Keep unnecessary and unprotected personnel from entering the spill area. Wear appropriate protective clothing. See Exposure Controls section. Absorb spill with inert material, sweep up and hold in properly labelled DOT container for disposal. Dike large spills to minimize the spill area. Material can cause environmental damage. Prevent material from contaminating soil or entering sewer or bodies of water. Handlinq Wash thoroughly after handling. Avoid contact with skin. Avoid contact with eyes. Avoid breathing mist, dust, vapors or fumes. Harmful if swallowed. Storacle Store in cool, dry, well-ventilated area away from incompatible materials listed in Section 10. ISECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION I Ventilation Requirements: Exhaust to satisfy the requirements of ASHRAE 62-1989. Ensure good mixing with fresh air supplied at a minimum of 0.5 cfm/ftz Personal Protective Equipment: Use chemical splash goggles. Be certain eyewash is in the work area. Wear neoprene, nitrile rubber or other chemical resistant gloves and apron or lab cost. Respiratory protection is generally not required. Refer to 29CFR 1910.134 for OSHA requirements. P~ge2 of 4 03015100A Exposure Guidelines: Inqredient OSHA PEL ACGIH TLV Water Not established Not established Potassium Carbonate Not established Not established Sodium Sulfite Not established Not established ArninopOlycarboxylic Acid Potassium Salt Not established Not established TWA = time weighted average STEL = short term limit (c) = ceiling I SECTION 9. PHYSiCAl AND CHEMICAL PROPERTIES Appearance: Clear, colorless liquid Odor: None Boilinq Point: approx. 100°C Odor Threshold: No data Specific Gravity: 1.327 Reactivity with Water:. None Vapor Pressure: appro)c 15 mm Hg Meltinq Point: No data Evaporation Rate: 1 water = 1 FreezJnq Point: No data Percent Volatile: approx. 65 Percent VOC: No data Solubility in Water:. Completely Vapor Density: No data pH: 11.7 Water-Oil Partition Coefficient: No data JSECTION 10. STABILITY AND REACTIVITY Hazardous polymerization will not occur if product is used and stored as directed. Product is stable if used and stored as directed. Hazardous Decomposition Products: Carbon dioxide. Sulfur dioxide. Materials to avoid: Strong acids. Oxidizers. Conditions to avoid: Excessive heat. ISECTION 11. TOXICOLOGICAL iNFORMATION I-D~0: 2408 mg/kg od, rat Acute Overexposure: Irritating by contact with skin, eyes and mucous membranes. Ingestion may cause gastdc irritation and burning pain. May also cause decreased motor activity. Chronic Overexposure: Chronic dermatitis. Pages of 4 03015100A I SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Data None known. Chemical Fate Data None known. Discha~ing this material to the sewer may require a permit. Do not dischan3e to septic systems. Observe all local, state and federal regulations when disposing of this material. Material exhibits 'corrosive" haza~ous waste characteristics. ISECTION 14. TRANSPORTATION INFORMATION component DOT Shippinq Name: Not DOT regulated. Parts B & C are regulated. Hazard Class: None UN Number:. None Packinq.Group: None Box DOT Shippinq Name Corrosive liquid. N.O.S. (p-Phenyldiamine derivative, Hydrexylamine Sulfate) Hazard Class: 8 UN Number:. UN1760 Packinq Group: III Other Instructions: Product is labelled in accordance with U.S. 49CFR. 'ISECTION 15. REGULATORY INFORMATION I Canadian SARA Clean Clean CAL Inqredient 'i'SCA List 31tl312 Air · Water Prod 65 Water Y N N N N N Potassium Carbonate Y N Y N N N Sodium SulF~e Y N Y N N N Aminopolycarboxylic Acid Potassium Salt Y N Y N N N All ingredients com'ply with EPA TSCA requirements. ISECTION 16. OTHER INFORMATION This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. ! Page4 of 4 0301~100A 'J~ MATERi~) SAFETY DATA SHEET CIq-16Q NQI-R Developer Part B IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 ISECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION I Product Name CN-16Q NQI-R Developer Part B 03015100 MSDSCode 03015100B Product Size 2 Product Code 5OO mis Distributor Manufacturer Fuji Photo Film, U.S.A., Inc. Fuji Hunt Photographic Chemicals, Inc. 555 TaXter Road West 115 Century Road P.O. Box 988 Etmsford, NY 10525 USA Paramus, N.J. 07653 USA (914)78 S-8100 Prepared by Fuji Photo Film U.S.A., Inc. Revision Date 11/14/94 Issue date 11/14/94 I SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS Inqredient CAS Number Weiqht % Water 7732-18-5 87-93 Hydroxylamine Sulfate 10039-54-0 3-5 Phosphonic Add Derivative 2809-21-4 3-5 Aminopolycarboxylic Acid 67-43-6 1-3 I SECTION 3. HAZARDS IDENTIFICATION IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 Material is a dear, colorless liquid. May emit toxic gases in fire conditions. Hydroxylamine may explode above 265°C. Wear equipment to protect eyes, skin and respiratory tract. Dike or absorb spills to keep material and run-off from entering sewer or waterways. Use water spray to cool containem and disperse vapors. Box contains multiple components. Consult all MSDS's. HMIS Ratinq Health 2 Fire 0 Reactivity 0' Protection C NFPA Ratinq Health 2 Fire 0 Reactivity 0 Specific Hazards None Hazard rating 0 = minimal 1= slight 2 = moderate 3 = serious 4 = severe C = gloves, goggles and apron UN UN1760 ERG Guide 60 ~otential Health Effects Skin: Contact causes irritation. Eyes: Contact causes irritation. Inhalation: May cause irritation to the respiratory tract. May cause changes in the blood, cyanosis, convulsions and coma. Inqestion:May cause irritation to the stomach and gastrointestinal tract. May cause changes in the blood, cyanosis, convulsions and coma. Conditions aqqravated by exposure Skin sensitivity. Carcinoqenicity Are any ingredients listed as carcinogens? IARC? N NTP? N OSHA? N Pa<jel · of 4 03016100B I tSECTION 4. FIRST AID MEASURES Ey.es: Flush eyes with large amounts of water for at least 15 minutes. See a medical doctor I immediately. Skin: Flush skin with large amounts of water. Remove contaminated clothing. See a doctor if rash. redness or irritation develops. ! Inhalation: Move to fresh air. If victim is having difficulty breathing, give oxygen if available. If victim is not breathing, start CPR. Get immediate medical attention. i Inqestion: Do not induce vomitting or give anything by mouth without emergency medical instructions. Immediately seek medical attention. Call poison contro~ center at (202)625-3333. If victim is unconscious, trained personnel should start CPR. Never give an unconscious person anything by mouth. I ISECT1ON 5. FIREFIGHTING MEASURES I i Flash Point None Upper Flammable Limit Not applicable Lower Flammable Limit Not applicable Autoiqnition Temperature None I Extinquishinq media Choose media suitable for surrounding materials. No restrictions on media based on knowledge of this material. I Firefiqhtinq instructions Evacuate area and fight fire from a safe distance. Wear positive pressure demand breathing apparatus and protect eyes and skin. Use water to cool fire-exposed containers, to protect personnel and'to disperse i vapors and spills. Water runoff can damage the environment. Dike and collect water used to fight fire. May emit toxic gases in fire conditions. Hydroxylamine may explode above 265~C. i ISEC 0. s. CC,=EUT^L RELE S[ I Keep unnecessary and unprotected personnel from entering the spill area. Wear appropriate protective I clothing. See Exposure Controls section. Absorb spill with inert material, sweep up and hold in propedy labelled DOT container for disposal. Dike large spills to minimize the spill area. Material can cause environmental damage. Prevent matedal from contaminating soil or entedng sewer or bodies of water. I ISECTION 7. HANDLING.AND STORAGE i Handlinq Wash thoroughly after handling. Avoid contact with skin. Avoid contact with eyes. Avoid breathing mist, dust, vapors or fumes. Harmful if swallowed. I Storaqe Store in cool, dry, well-ventilated area away from incompatible materials listed in Section 10. I ISECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Ventilation Requirements: Exhaust to satisfy the requirements of ASHRAE 62-1989. Ensure good mixing with fresh air supplied at a I minimum of 0.5 cfrrdf~z i Personal Protective Equipment: Use chemical splash goggles. Be certain eyewash is in the work area. Wear neoprene, nitdle rubber or other chemical resistant gloves and apron or lab coat. I Respiratory protection is not required. Refer to 29CFR 1910.134 for OSHA requirements. generally Page2 of 4 I &3015100B Exposure Guidelines: Inqredient OSHA PEL ACGIH TLV Water Not established Not established Hydrox"ylamine Sulfate Not established Not established Phosphonic Acid Derivative Not established Not established Aminopolycarboxylic Acid Not established Not established TWA = time weighted average STEL = short term limit (c) = ceiling [SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, colorless liquid Odor:. None Boilinq Point: approx. 100°C Odor Threshold: No data Sp'ecific Gravity: 1.076 Reactivity with Water:. None Vapor Pressure: appm~ 15 mm Hg Meitinq Point: No data Evaporation Rate: I (water=l) Freezinq P. oint: No data Percent Volatile: N/A Percent VOC: No data Solubility in Water:. Completely Vapor Density: No data Pr:. 3.15. Water-Oil Partition Coefficient: No data ISECTION 10. STABILITY AND REACTIVITY Hazardous polymerization will not occur if product is used and stored as directed. Product is stable if used and stored as directed. H~Tnrdous Decomposition Products: Hydroxylamine. Sulfur dioxide. Carbon dioxide. Materials to avoid: Strong adds. Strong bases. Oxidizers. Hypohalites. Conditions to avoid: Excessive heat_ Is c.,o, I LDs0: > 5000 rog/kg orl, rat Acute Overexposure: Irritating by contact with eyes and skin. Irritating to mucous membranes and respiratory tract. Inhalation or ingestion may cause systemic poisoning. Hydmxylamine is an experimental teratogen and can cause methhemoglobinemia. Chronic Overexposure: Possible allergic or hypersensitivity type reactions based on knowledge of ingredients. ! Page3 of 4 03016t00B .J SECTION 12. ECOLOGICAL INFORMATION Ecoto×icity Data None available. Chemical Fate Data None available. tSECTION 13. DISPOSAL CONSIDERATIONS Discharging this material to the sewer may require a permit. Do not discharge to septic systems. Observe all local, state and federal regulations when disposing of this material. Material does not exhibit hazardous waste characteristics. ISECTION 14. TRANSPORTATION INFORMATION I Component DOT Shippinq 'Name: Corrosive liquid, N.O.S. (Hydroxylamine sulfate, Phosphonic acid derivative) Hazard Class: 8 UN Number:. UN1760 Packinq Group: III 'Box DOT Shippinq Name Corrosive liquid, N.O.S. (p-Phenyldiamine derivative, Hydmxylamine Sulfate) Hazard Class: 8 UN Number:. UN1760 Packinq Group: III Other Instructions: Product is labelled in accordance with U.S. 49CFR. Canadian SARA Clean Clean CAL Inqredient TSCA Est 3t'113'i2 Air Water Prop 6S Water Y N N N N N Hydroxylamine Sulfate Y Y Y N N N Phosphonic Acid Derivative Y N Y N N N Aminopolycarboxylic Acid Y N Y N N N I All ingredients comply with EPA TSCA requirements. ISECTION 16. OTHER INFORMATION I I This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. I I Page4 of 4 I 03015100B I '!J~ MATERI~t SAFETY DATA SHEET C1~'-16Q NQ1-R Developer Part C · IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 'ISEcTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION i Product Name CN-16Q NQ1-R Developer I~art C Product Code 03015100 MSDS Code 03015100C Product Size 2 x 500 mis ' Distributor Manufacturer ; ! Fuji Photo Film, U.S.A., Inc. Fuji Hunt Photographic Chemicals, Inc. i't 555 Taxter Road West 115 Century Road P.O. Box 988 Elmsford, NY 10523 USA Paramus, N.J. 07653 USA (914)789-8100 I Prepared by Fuji Photo Film U.S.A., inc. Revision Date 11/14/94 Issue date 11/14/94 I I SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS Inqredient CAS Number Weiclht % Water 7732-18-5 83-94 I p-Phenylenediamine Derivative 28020-34-0 6-16 Sodium Sulrrte 7757-83-7 0.5-1 ! ISECTION 3. HAZARDS IDENTIFICATION " IN CASE OF E~ERGENCY, CALL CHEMTREC (800)424-9500 Matedal is a clear, amber liquid. May produce toxic gases under fire conditions. Wear equipment to protect eyes, skin and respiratory tract. Dike or absorb spills to keep material and run-off from entedng sewer or waterways. Use water spray to cool containers and disperse vapors. Asthmatics are said to be dangerously sensitive to even minute amounts of suifites. Box contains multiple components. Consult all MSDS's. HMIS Ratinq Health 2 Fire 0 Reactivity 0 Protection C NFPA Ratinq Health 2 Fire 0 0 H~:,~rds None Reactivity Specific Hazard rating 0 = minimal 1= slight 2 = moderate 3 = serious 4 = severe C = gloves, goggles and apron UN UN1760 ERG Guide 60 " Potential Health Effects .Skin: Contact causes irritation. May cause bums. Eyes: Contact causes irritation. May cause bums. Inhalation: May cause irritation to the respiratory tract. May cause breathing difficulties. Asthmatics are said to be dangerously sensitive to even minute amounts of suifites. Inqestion: May cause irritation to the stomach and gastrointestinal tract. May cause changes in the blood. Conditions aqqravated,by exposure Asthma. Skin sensitivity. Carcinoqenicity Are ingredients listed as carcinogens? IAPC? N N'i'P? N OSHA? N any I Page I of 4 0301610OC [SECTION 4. FIRST AID MEASURES Eyes: Flush eyes with large amounts of water for at least 15 minutes. See a medical doctor immediately. Skin: Flush skin with large amounts of water. Remove contaminated clothing. See a doctor if rash, redness or irritation develops. Inhalation: Move to fresh air. If victim is having difficulty breathing, give oxygen if available. If victim is not breathing, start CPR. Get immediate medical attention. Inqestion: Do not induce vomitting or give anything by mouth without emergency medical instructions. Immediately seek medical attention. Call poison control center at (202)625-3333. If victim is unconscious, trained personnel should start CPR. Never give an unconscious person anything by mouth. {SECTION 5, FIREFIGHTING MEASURES Flash Point None Upper Flammable Limit Not applicable Lower Flammable Limit Not applicable Autoiqnition Temperature Extinquishinq media Choose media suitable for surrounding materials. No restrictions on media based on knowledge of this material. Firefiqhtinq instructions · Evacuate area and fight fire from a safe distance. Wear positive pressure demand breathing apparatus and protect eyes and skin. Use water to cool fire-exposed containers, to protect personnel and to disperse vapors and spills. Water runoff can damage the environment. Dike and collect water used to fight fire. May produce toxic gases under fire conditions. ISECTION 6. ACCIDENTAL RELEASE Keep unnecessary and unprotected personnel from entering the spill area. Wear appropriate protective clothing. See Exposure Controls section. Absorb spill with inert material, sweep up and hold in propedy labelled DOT container for disposal. Dike large spills to minimize the spill area. Matedal can cause environmental damage. Prevent matedal from contaminating soil or entedng sewer or bodies of water. iSECTION 7. HANDLING AND STORAGE Handlinq Wash thoroughly after handling. Avoid contact with skin. Avoid contact with eyes. Avoid breathing mist, dust, vapors orfumes. Harmful if swallowed. Storaqe Store in cool, dry, well-ventilated area away from incompatible materials listed in Section 10. SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Ventilation Requirements: Exhaust to satisfy the requirements of ASHRAE 62-1989. Ensure good mixing with fresh air supplied at a minimum of 0.5 cfm/ftz Personal Protective Equipment: Use chemical splash goggles. Be certain eyewash is in the work area. Wear neoprene, nitrile rubber or other chemical resistant gloves and apron or lab coat. Respiratory protection is generally not required. Refer to 29CFR 1910.134 for OSHA requirements. Pag~2 of 4 03015100C Exposure Guidelines: !nqredient OSHA PEL ACGIH TLV Water Not established Not established p-Phenylenediamine Derivative Not established Not established Sodium Sulfite Not established Not established ! I TWA = time weighted average STEL = short term limit (c) = ceiling I SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES I Appearance: Clear, amber liquid Odor:. None Boilinq Point: approx. 100°C Odor Threshold: No data I Specific Gravity: 1.040 Reactivity with Water:. None Vapor Pressure: approx. 15 mm Hg Meltinq Poi .nt: No data Evaporation Rate: 1 (water=l) Freezinq Point:. No data I Percent Volatile: approx. 90 Percent VOC: No data Solubility in Water:. Completely Vapor Density: No data pH: 2~4 I Water-Oil Partition Coefficient: No data ISECTION 10. STABILITY AND REACTIVITY I Hazardous will not if is used and stored as directed. polyrnedzation occur product Product is stable if used and stored as directed. Hazardous Decomposition Products: Carbon dioxide. Sulfur dioxide. I . Materials to avoid: Stong bases. Oxidizers. Conditions to avoid: Excessive heat. [SECTION 11. TOXICOLOGICAL INFORMATION I LD60: 1018 rog/kg oral, rat · Acute Overexposure: Irritating by contact with skin and eyes. May cause bums to skin, eyes and mucous membranes. May cause ataxia, breathing irregularities, erythema i and decreased motor activities. Chronic Overexposure: Allergic skin reactions. May cause colic, diarrhea and central nervous system I depression. May cause respiratory tract hypersensitization. ! i Page3 of 4 03015100C I ISECTION 12. ECOLOGlCALINFORMATION Ecoto×icity Data None available. I Chemical Fate Data None available. I ISECTION 13. DISPOSAL CONSIDERATIONS Discharging this material to the sewer may require a permit. Do not discharge to septic systems. Observe all local, state and federal regulations when disposing of this material. I Matedal exhibits "corrosive" hazardous waste characteristics. [SECTION 14. TRANSPORTATION INFORMATION I Component DOT Shippinq Name: Corrosive liquid, N.O.S. (p-Phenylenediamine derviative) I Hazard Class: 8 UN Number:. UN1?60 Packinq Group: Iil Box DOT..Shippinq Name Corrosive liquid, N.O.S. (p-Phenyldiamine derivative, Hydroxylamine Sulfate) I Hazard Class: 8 UN Number:. UN1760 Packinq.Group: !11 Other Instructions: Product is labelled in accordance with U.S. 49CFR. ! I ISECTION 15. REGULATORY INFORMATION I Canadian SARA Clean Clean CAL Inqredient 'I'SCA List 31'11312 Air Water Prop 65 I water Y N N N N N p-Phenylenediamine Derivative Y N Y N N N I Sodium Sulfite Y N Y N N N I I IAll ingredients comply with EPA TSCA requirements. I ISECTION 16. OTHER INFORMATION This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the i environment. I Page4 of 4 I 03015100C I F&"0-06-98 '08:41am From-Properties 'tmcnt 5102106887 T-371 P.02/09 F-314 '- I~m I m ~. NIATERIAL"""~AFETY DATA SHEET CN-16Q NQ2-R Bleach Part A IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 [SECTION 1. CHEMICAL PRODUCT AND cOMpANY IDENTIFICATION I Product Name CN-16Q NQ2-R Bleach Part A Product Code 03015103 MSDS Code 03015103A Product Size 2 x 800 mis i Distributor Manufaclurer Fuji Photo Film, U.S.A., Inc. F.uji Hunt Photographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Box 988 Elmsford, NY 10523 USA Paramus. N.J. 07653 USA I (914)789-8100 Prepared by Fuji Photo Film U.S~., Inc. Revision Date 11/14/94 Issue date 11/14/94 ~ I SECTIC)N 2. COMPOSITION AND INFORMATION ON INGREDIENTS ~ln.qredient CAS Number Wei.qht ~ Water 7732-18-5 57-72 I Ammonium Bmmicle 12124-97-9 20-30 EDTA, Disodium salt 139-33-3 7-I 0 Thiol Derivative 17339-80-5 1-3 ! "' CASE'"~)'F -- ........... IN EMERGENCY, CAi. L CHEMTREC (800)424-9300 a ¢Jear, liqui(~. Matedal is ~lone~ May produ~ to~c gases in r~ ~ions or E m~ ~h blea~. Wear equipment to pmtc~ eyes, ~in an~ ~sp~m~tm~. D~e or a~ spills to ~ep mate~ and mn-off ~m entedng sewer or ~te~y~ Use ~ter ~y to ~1 ~ntainem and dis~ vasT. Box ~a~ mu~iple ~m~nen~. Consult all MSDS's. HMIS Ratinq Health 1 FiT 0 Rea~iv~y 0 Pmte~ C NFpA Ratinq HeaEh 2 FiT 0 Rea~ivEy 0 Spe~ficHaza~s None Haza~ rating 0 = minimal 1= s[igM 2 = m~erate 3 = ~dous 4 = ~vem C = gloves, goggles a~ apron UN No~ ERG Guide 60 Gtem . .............. Skin: Conta~ ~u~ i~ation. May ~e s~n rash. Eyes: Co~ ~es i~taQon. Inhalation: ~y ~e i~t~lon to ~e mucus membm~ and respi~to~ t~. May ~e d~n~, ata~a and ve~igo. . laaemion: ~a~ ~ iffitation ~o t~e momach and ~mmlate~i~l tm~. Genemll~ ~u~e~ imm~ime Cond~ions aqqra~ted bvex~0~Um None k~n. ~rcinoqeniciW ~e any ingmdien~ li~ as ~n~ens? ~RC? N ~? N gsa? N I Page1 of 4 ! I Fe~-0G-g8 ~8:43am Fro~-Properties 'tment 510210G887 T-3Z1 P.03/09 F-314 I I Eves: Flush eyes with large amounts of water for at a medical doctor least 1 5 minutes. See immediately. Skin: Flush skin with large amounls of water. Remove contaminated clothing. See a I doctor if rash, redness or irritation develops. Inhalation: Move to fresh air. If victim is having difficulty breathing, give oxygen i~ available. If victim is not breathing, start CPR. Get immediate medical attention. I Do not induce vomitting or give anything by mouth without emergen~ medical Inqestion: instructions. Immediately seek medical attention. Call poison control center at (202)625-3333. If victim is unc_~nscieus, trained personnel should start CPR. Never i give an unconscious person anything by mouth. [SECTION 5. FIREFIGHTING MEASURES I Flash Po!pt Hone Upper Flammable Limit Not applicable Lower Flammable L~,,~ Not applicable Autoiqpftlon Temperature None I ExtinauishlnC~ medlPl Choose media suitable for surrounding materials. No restrictions on mecFm ~ on knowledge of this mater~al. I Firefightlnq instructions Evacuate ama and fight fire from a safe distance. Wear positive pmssu~ demand breathing apparatus and protect eyes and skin. Use water to cool fire-exposed containem, to l~XX~ct pemo~nel and to disperse vapors and spills. Water runoff can damage the envimnmenL Dike and collect ~ used to fight tim. I May produce toxic gases in tim condition~ or if mixed with bleach. I ISECTION 6, ACCIDENTAL RELEASE Keep unnecessary and unprotected personnel from entedng the spill area. We~r ~te protective clothing.- See Exposure Controls section. Absor'o spill with inert material, sm~p ~ and hold in properly labelled DOT container forcllsposal. Dike large spills to mipimize ~e Sl~ a'ea. I/,a~erlal can cause I envimnmemal clamage. Prevent material from contaminating soil or entering semer or bodies o! water. [SECTION 7. HANDLING AND STORAGE I Handlina Wash thoroughly after handling. Avoid contact with skin. Avaid comact with eyes. Avoid bm..,athi~ mist, dust, vapors or fumes. Harmful ifswa~ I storaqe stem in COOl, d~, well-ventilated area away from inco ~rr~=sa~ ~ listed in Section 10. ISECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Ventilation Re,quiremertts: IExhaust to satisfy the requirements of ASHRAE 62-1989. Ensure good rni~ng with fresh air supplied at a minimum of 0.5 cfm/flz I Personal Protective Equipr~ent: Use chemical splash goggles. Be certain eyewash is in the work area. I Wear neoprene, nitrile rubber or other chemical resistant gloves and apron oe lab coat. Respiratory protect/on is generally not required. Refer to 29CFR 1910.134 for OSHA requirements. I of I Fe~-06-98 08:44am From-Properties rtment 5102106887 T-371 P.04/09 F-314 .Exposuro Guidelines: I InqTedient OSHA PEL ACGIH TLV Water Net established Not established Ammonium Bromide Not established Nat e_...~tablished I EDTA, Disodium salt Not established Not e~-tablished Thiol Derivative Not established Not established I SECTION ~.' PHYSICAL AND CHEMICAL PROPERTIES A~pearance: Clear. colorless liquid OdoF. None Boilinq p. oi~.- approx. 100"C ,Odor Threshold: No data Specific Gravity:., 1.213 Reactivity with Water.' None V. apor Pressure: approx. 15 mm Hg JVleltinR Point:. No data Evaporation Rate: I (water=l) Fmezin,q point~ No data Percent Volatile: approx. 65 percent VOC: No data Solubil',~y in.Water:. Completely y.a, par Density:. No data pH: 4.15 Water-Oil Partitfon Coefficient:. No data Haza~lous polymerization ~n'll nol occur if product is used and stored as dimctecl. Pmcluct is stable ff usecl and stoma as aimctecl. Hazardous Dacoml~osition ,P, roducts: Carbon dioxide. Materials to avoid: Strong bases. Hypochlorites. Bleach. Conditions to ayoid: Excessive heat. SECTION 11. TOXICOLOGICAL INFORMATION LDso: > 5000 rog/kg oM, rat Acute Overexposure: Irritating by contact wilh skin and eyes. Ingestion may cause gastroilltestirlal distress and immediate vomitting. Inhalation may cause respiratory irritation. May cause ataxia, drowsiness ar~ vertigo. I Chronic Overexposure: Allergic or hypemenstivity type reactions. May cause sensory cr'~tur'oances, mania, hallucinations or coma. I Page3 e! 4 ~0161MA 510210688'/ Fet.-06-98 Frea~-Proper ti es ~rtment Ecotoxic~y Da~a None available. Chemi~l Fate Data None available. ~SECTION 13. DISPOSAL CONSIDE~TIONS Discha~ing t~is material to the sewer may require a pe~it. Do not eischa~e to se~c ~ems. Obsewe all le~l, 5tare an~ fe~eml regulations when d~posing of t~is mate~al. Material does n~ e~ib~ h~ous ~e ~a~ed~. component DOT shi~in~ Name; Co~Ne ~q rd, N.O.6, ~e~c Ammonium ~T& ~monium ~mmide) ,a~ Class: 8 U~N Numbe~ 1760 ~cUnq Gro,: Ill ~ox DOT ShlDDln~ Name Co~osivc liquid, N.O.S. (Fe~c Am~nium ~ ~monium B~ide) Ha~ Class: 8 UN Num~ UN 1760 P~nq GroUp= II! Other In~m~ons: Pmdu~ ~ labelled in a~Man~ ~ffi U.S. 49CFR. c~0U 45. ~'E~U~ToRY iNFORMATION , , Canadian S~ ~ Clean CAL InQmdiem ~C~ ~ 311~2 Waer Y N N N N N Fe~c Ammonium EDTA Y N Y N N N Ammonium Bromide Y N Y N N N ! All ingredients comply with EPA TSCA requirements. This information is provided witho~ wamanty. The information is believed lo be correct. This information I should be used to make an independent determination of the methods to ,safeguar¢l workers and the environment. ! I Pa~e4 of 4 I m Feb-0G-98 ~}8:4Gam Fro~-Properties ~rtment 510210G887 ~ T-371 P.0G/0§ F--314 . ~a~,,, ~. MATERIAL-SAFETY DATA SHEET m CN-16Q NQ2-R Bleach Part B , IN CASE OF EMERGENCY, CALL CHEMTREC (800)424.9300 tSECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION m Product Name CN-16Q NQ2-R Bleach Part B Product Code 03015103 MS;DS Cooke 03015103D Product Size 2 x 3.2 liters I Distributor Manufacturer Fuji Photo Film, U.S.A., Ir]c. Fuji Hunt Photographic Chemicals, inc. 555 Taxter Road ' Wrist 115 Century Rca(3 P.O. Box 988 Elmsford, NY 1052;3 USA Paramus, N.J. 07653 USA m (914)789_8100 Prepared by Fuji Photo Film U.S.^., Inc. Revision Date 11/14/94 Issue date 11/14/04 m I SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS lr]oredlent CAS Number .Weiqht % Water 7732-18-5 52-72 m Ferric Ammonium EDTA i 21265-50-9 19-29 Ammonium Bromide 12124-97-9 9.19 m m m SECTION 3. HAZARDS IDENTIFICATION IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-~300 m a clear, liquid. Material red-brown May produce toxic gases in fire conditions or if mixed with bleacil. Wear equipment to pmmct eyes, skin an(I respiratony tract. Dike or absorb spills to keep material and m run-ct[ from entering sewer or walerway5. Use water spray to cool containers and disperse vapors, Box contains multiple components. Consult all MSD~'s. m HMIS Ratlna Health I Fire 0 Reactivity 0 Protection C NFPARatinq Health 2 Fire 0 Reactivity 0 Specific Hazards None m Hazard rating 0= minimal 1=slight 2= moderate 3 = sedous 4=severe C = gloves, goggles and apron UN 1760 ERG Guide 60 =otential Health .Effe ,c!:s m ,Skin: Contac~ causes irritation. May cause skin rash. JEYes: Contact causes irritation. Inhalation: May cause irritation to the mucous membrane{; and respiratory tract. May cause ataxla, m drowsiness and vertigo. Inqestion= May cause irritation to the stomach and gastrqintestinal tracL May cause Immediate vomitting. m conditions ao~oravated bY exposure None knov~l. ,Ca~i,noclenic!tv Are any ingredients listed as carcinogens? IARC? N NI'P? N OSHA? N m Pagal o! 4 SECTION 4, FIRST AID MEASURES Eye~-. Flush eyes with large amounts of water for at leaSt 15 minutes. See a medical doctor immediately. Skin: Flush skin with large amounts of waler. Remove contaminated cloihing. See a doctor, if rash, redness er irritation develops. Inhalation: Move to fresh air. If victim is I'laving difficulty breathing, give oxygen if available. If victim is not breathing, start CPI=,. Get immediate medical attention. In._~_qestion: Do not induce retaining or give anything by mouth emergency medical instructions. Immediately seek mecljcal ~ttention. Call poison control center at (2D2)625-3333. If victim is unconscious, trained personnel should start CPR. Never give an unconscious person anything by mouth. JSECTION 5. FIREFIGHT1NG MEASURES Flash Point None U~pper Flammable Limit Not applicable ~_ower Flammable Limit NO[ applicable Atrtoiqnilion Temperature None .Extinquishinq medic Choose media suital~le for 5urrounciing materials. No restrictions on media baseci on knowleclge of this material. Firefi~htincl instructions Evacuate area and fight fire from a safe distance. Wear pos.itive pressure demand breathing apparatus and protect eyes and skin. Use water to cool fire-exposecl containers, t.o protect personnel and to disperse vapors and spills. Water runoff can damage the environment. D~e and collect water used to fight fire. May produce toxic gases in fire conditions ar if mixed with bleach. ISECTION 6. ACCIDENTAL RELEASE .... Keep unnecessary anti unprotected personnel from entering the spill area. Wear appropllate protective clothing. ~ Exposure Controls section. Absorb spill with irlert material sam~ep up and hold in properly labelled DOT container for clisposal. Dike large spills to minimize the spill area. Material can cause environmental Carnage. Proven! material from contaminating so~ or entering sewer or boclies of water. ISECTION 7. ~'A~DLi~IG AND STORAGE , , Handlinq Wash thoroughly after handling. Avoid contact with skin. Av~cl contact with eyes. Avoid breathing mist, dust, vapom or fumes. Harmful if swallowed. Storacm b"lore in cool, dry, well-ventilated area away from incompal~e materials r~ed in Section t O. ISECT1ON 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Ventilation Requiremerrt~; E.xhaust to satisfy the requirements of ASHRAE 62-1989. Erasure good mixing with fresh air supplied at a minimum of 0.5 cfm/ftz Personal Protective Equipment:. Use chemical spla.~ goggles. Be certain eyewash is in the work area. Wear neoprene, nitrile rubber or other chemical resistant glRves and apron or lab coat. Respiratory protection is generally not required. Refer to 2gCFR 1910.134 for OSHA requirement, Page2 of Feb.-O6-g8 ~8:48a~ Fro~n-Properti es itrnent 510210(;88'/ T-~71 P.08/0g F-~14 E~posure Guidel~nes~ ~ OSHA PEL A~.GIH TLV Water No[ e~ablis~ Not e~ablished Fe~c Ammonium EDTA' N~ e~ablished Not e~ablisheO Ammonium Bromide Net e~ablished Hot e~ablishe~ ~A = time ~ighled avenge S~L = sho~ te~ lim~ (c) = ~iling I SEC~ON 9. PHYsI'CA~ AND CHEMICAL PROPERTIES Appeamnce~ Clear. r~-bm~ liquid Odoq 81~ ammonia Boilinq Poi~: appr~ 10~ Odor Threshold: No ~clflc Gmv~ 1,237 ~~ ~h Wate~ None Vapor Pressure. approx. 15 ~ Hg ~elfing Pof~: No data Solubll~ in ~ ~mpl~e~ ~por Dens~: No data ~ater~il Paff~ion C~ciem: N~ ~ata Haza~o~ polymed~ion ~11 not o~r ~ ~u~ is u~ an~ ~ored as dim~. P~u~ is ~able if u~ a~ ~or~ as di~ed. Hazardous Decom~os~io~Produ~: ~n di~de. ~onia. CondAions m a~id: ~e hem. ~o: . > 5000 mg~g od, ~ Acute Ovemxposu~, I~ting by ~ ~h s~n ang eyes. Ing~ion ~ ~u~ ga~i~e~inai di~ ~m Imm~iate voting. Inhal~ion may ~ m~mio~ i~tion Chronic Ove~xposure. or h~eme~ivlty ~Pe ~amions. May ~u~e ~ digu~an~, mania, hallucina~ons I Feb-0G-98 08:45am Fro~-Properties ~r tment 51021058B7 1'-371 P.05/0§ F-314 I SECTION 12. ECOLOGICAL INFORMATION IEcotoxiciW Data None available. Chemical Fale Data None available. I ISECTION 13. DISPOSAL CONSIDERATIONS ~ Discharging this material to the sewer may require a pen~it. De not discharge to septic systems. Observe I all local, state and federal regulations when disposing af this material. Material does not exhibit hazardous wasie characteristics. I ISECT,O.'14. TRANSPORTATION INFORMATION Component DOT Shippinq Name: Not DOT r~ulated, Part B is regulated~ J I Hazard ClaSs: None -- UN Number:. None Packin(l Group: None .,Box DOT -~hippinq Name COIT~Sive liquid, N.O.S. (Ferric ammonium ED'I'A, Ammonium Bromide) I Hazard Class: 8 UN Numb, er;. UN 17{~0 [Packinq Grpup: Ill Other Insiructions'. Product is labelled in accordance w~th U.S. 49CFR. ISE'CTION 15. REGULATORY INFORMATION ~ I ,Canadian .SARA Clean Claa_n .CAL .[~qredient 'rsc._._~A ~ 311/312 N._.Er W.i~ter Prop SS Water Y N N N N N I Ammonium Bromide Y FI Y N N N EDTA, Disodium sail Y N Y N N N i Trliol Derivative Y N ¥ N N N I I All ingredients comply with EPA TSCA requirements. This information is providod without warranty. The information is believecl to be correct. This Information should be used to make an independent determination of the methods to safegua~l workers and the I environment. I PI~4 ~! 4 03~16103A I J~ MATERIAi~AFETY DATA SHEET ', ~N-16Q NQ3-R Bleach Fix · IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 ISECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name CN-16Q NQ3-R Bleach Fix I Product Code 03015106 MSDS Code 03015106 Product Size 2 x 4 liters Distributor Manufacturer i Fuji Photo Film, U.S.A., Inc. Fuji Hunt Photographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Box 988 Elmsford, NY 10523 USA Paramus, N.J. 07653 USA (914)789-8100 I Prepared by Fuji Photo Film U.S~,., Inc. Revision Date 11/14/94 Issue date 11/14/94 I I SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS Inqredient CAS Number Wei,qht % Water 7732-.18-5 45-59 I Ammonium Thiosulfate 7783-18-8 $9-49 Sodium Sulfite 7757-83-7 1-3 Sodium m-Bisulf'~e 7681-57-4 1-3 ! I I IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 Material is a clear, colorless solution. May produce toxic gases in fire conditions or if mixed with bleach. I Wear equipment to protect skin and respiratory tract. Dike or absorb spills to keep matedal and eyes, run-off from entedng sewer or waterways. Use water spray to cool containers and disperse vapors. Asthmatics are said to be dangerously sensitive to even minute amounts of suit-rtes. ! HMIS Ratinq Health 1 Fire 0 Reactivity 0 Protection C I NFPA Ratinq Health 2 Fire 0 Reactivity 0 Specific Hazards None Hazard rating 0 = minimal 1= slight 2 = moderate 3 = sedous 4 = severe C = gloves, goggles and apron UN None ERG Guide 60 ! , Potential Health Effects Skin: Contact causes irritation. i Eyes: Contact causes irritation. Inhalation: May cause irritation to the respiratory tract. Asthmatics are said to' be dangerously sensitive to even minute amounts of sulfites. I Inqestion: May cause irritation to the stomach and gastrointestinal tract. Conditions aqqravated by exposure Asthma. I Carcinoqenicity Are any ingredients listed as carcinogens? IARC? N NTP? N OSHA? N i Page1 of 4 034315106 I SECTION 4. FIRST AID MEASURES Eyes: Flush eyes with large amounts of water for at least 15 minutes. See a medical doctor immediately. Skin: Flush skin with large amounts of water. Remove contaminated -clothing. See a' doctor if rash, redness or irritation develops. Inhalation: Move to fresh air. If victim is having difficulty breathing, give oxygen available. If if victim is not breathing, start CPR. Get immediate medical attention. Inqestion: Do not induce vomitting or give anything by mouth without emergency medical instructions.. Immediately seek medical attention. Call poison control center at (202)625-3333. If victim is unconscious, trained personnel should start CPR. Never give an unconscious person anything by mouth. ISECTION 5. FIREFIGHTING MEASURES Flash Point None Upper Flammable Limit Not applicable Lower Flammable Limit Not applicable Autoiqnition Temperature None Extinquishinq media Choose media suitable for surrounding materials. No restrictions on media based on knowledge of this material. Firefiqhtinq instructions Evacuate area and fight fire from a safe distance. Wear positive pressure demand breathing apparatus and protect eyes and skin. Use water to cool fire-exposed containers, to protect personnel and to disperse vapors and spills. Water runoff can damage the environment. Dike and collect water used to fight fire. May produce toxic gases in fire conditions or if mixed with bleach. ISECTION 6, ACCIDENTAL RELEASE Keep unnecessary and unprotected personnel from entering the spill area. Wear appropriate protective clothing. See Exposure Controls section. Absorb spill with inert material, sweep up and hold in propedy labelled DOT container for disposal. Dike large spills to minimize the spill area. Material can cause environmental damage. Prevent material from contaminating soil or entering sewer or bodies of water. ISECTION 7. HANDLING AND STORAGE Handlinq Wash thoroughly after handling. Avoid contact with skin. Avoid contact with eyes. Avoid breathing mist, dust, vapors or fumes. Harmful if swallowed. Storaqe Store in cool, dry, well-ventilated area away from incompatible materials listed in Section 10. ISECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Ventilation Requirements: Exhaust to satisfy the requirements of ASHRAE 62-1989. Ensure good mixing with fresh air supplied at a minimum of q.5 cfrrdftz Personal Protective Equipment: Use chemical splash goggles. Be certain eyewash is in the work area. Wear neoprene, nitdle rubber or other chemical resistant gloves and apron or lab coat. is not Refer to 29CFR 1910.134 for OSHA Respiratory protection generally required. requirements. Page2 of 0~0161o6 Exposure Guidelines: .Igqredient OSHA PEL ACGIH TLV Water - Not established Not established Ammonium Thiosulfate Not established Not established Sodium Suit-rte Not established Not established Sodium m-Bisulfite 5 mglm~ 5 mglm~ TWA = time weighted average STEL = short term limit (c) = ceiling I SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, colorless liquid Odor:. Slight ammonia Boilinq Point: approx. 100°O Odor Threshold: No data Specific Gravity: 1.275 Reactivity with Water:. None Vm3or Pressure: approx. 15 mm Hg Meltinq Point:. No data Eyaporation Rate: 1 (water=l) Freezinq Point: No data Percent Volatile: approx. 50 Percent VOC: No data Solubility in Water:. Completely Vapor Density: No data pH: 8.0 Water-Oil Partition Coefficient: No data ISECTION 10. STABILITY AND REACTIVITY Hazardous will not if product is used and stored as directed. polymerization occur Product is stable if used and stored as directed. Hazardous Decomposition Products: Ammonia. Sulfur dioxide. Carbon dioxide. Materials to avoid: Strong acids. Strong bases. Hypochlodtes. Bleach. Conditions to avoid: Excessive heat. I SECT, ON 11. TOXICOLOGICAL INFORMATION .l_Dso: 4676 mg/kg ora.~, rat Acute Overexposure: Irritating by contac~ with eyes and skin. irritating to respiratory tract if inhaled. Irritating to gastrointestinal tract if ingested. Asthmatics are said to be dangerously sensitive to even small amounts of suifites. Chronic Overexposure: May cause diarrhea, colic, circulatory disturbances and central nervous system depression. ! Pages of 4 I 0~016106 SECTION 12. 'ECOLOGICAL INFORMATION Ecotoxicity Data None available. Chemical Fate Data None available. ~ischa~in~ this matehal to the sewer may r~uire a ~it. ~o not discha~e to septic sy~ems. all Io~1. ~ate anO fe~eml re~ulalioas when disposin~ of this matehal. ~atefial does not exhibit haza~ous wa~e cham~e~i~. -ISECTION 14. T~NSPORTA~ON INFORMA~ON Component DOT Shippinq 'Name: Not DOT ~ulat~ Hazard Class: None UN Number:. None Packinq Group: None Box DOT Shippinq Name Not DOT regulated Hazard Class: None UN Number:. None Packinq Group: None Other InStructions: Product is labelled in accordance with U.S. 49CFR. Canadian SARA Clean Clean CAL Jnqredient 'I'SCA List 3111312 Air Water prop 65 water Y N N N N N Ammonium Thiosulfate Y N Y Y Y Y 'Sodium Sulffie Y N Y N N N Sodium m-Bisulfite Y Y Y N N N All ingredients comply with EPA TSCA requirements. [SECTION 16. OTHER INFORMATION This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workers and the environment. Page4 of 4 03015106 m j~ MATERIAI~AFETY DATA SHEET Chl~mr6Q NQ4-R Safer Stabilizer m IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300 ]SECTION 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ] I Product Name CN-16Q NQ4-R Safer Stabilizer Product Code 03025109 MSDS Code 03025109 Product Size 10 x 80 mis Distributor Manufacturer I Fuji Photo Film, U.S.A., Inc. Fuji Hunt Photographic Chemicals, Inc. 555 Taxter Road West 115 Century Road P.O. Box 988 Elmsford, NY 10523 USA Paramus, N.J. 07653 USA m (914)789-8100 Prepared by Fuji Photo Film U.S.A., Inc. Revision Date 11/14/94 Issue date 11/14/94 m )SECTION 2. COMPOSITION AND INFORMATION ON INGREDIENTS I Inqredient CAS Number .Weiqht % Water 7732-18-5 70-84 m 1,2,4-Tfiazole 288-88-0 10-15 Substituted Tdazole Trade Secret 36559300-5001 5-10 i NonionicSurfactant Trade Secret 36559300-5002 1-5 m m ISECTION 3. HAZARDS IDENTIFICATION m IN CASE OF EMERGENCY, CALL CHEMTREC (800)424-9300' Matedal is a clear, coiodess liquid. mMay produce small amounts of formaldehyde fumes under fire conditions or if mixed with acids.. Wear equipment to protect eyes, skin and respiratory tract. Dike or absorb spills to keep matedal and run-off from entedng sewer or waterways. Use water spray to cool containers and disperse vapors. ! m HMIS Ratinq Health 2 Fire 0 Reactivity 0 Protection C NFPA Ratinq Health 2 Fire 0 Reactivity 0 Specific HnTnrds None Hazard rating 0 = minimal 1= slight 2 = moderate 3 = serious 4 = severe C = gloves, goggles and apron UN None ERG Guide 60 ! . =otential Health Effects Skin: Contact causes irritation. m Eyes: Contact causes irritation. Inhalation: May cause irritation to the respiratory tract. May release small amounts of formaldehyde fumes that can cause bufining to the nose and throat, coughing and heaving tearing. m Inqestion: May cause irritation to the stomach and gastrointestinal tract. Conditions aqqravated by exposure Skin sensitivity. m Carcinoqenicity Are any ingredients listed as carcinogens? IARC? N NTP? N OSHA? N I Page 1 of 4 0302510~3 Eyes: Flush eyes with large amounts of water for at least 15 minutes. See a medical doctor immediately. Skin: 'Flush skin with large amounts of water. Remove contaminated clothing. See a doctor if rash, redness or irritation develops. Inhalation: Move to fresh air. If victim is having difficulty breathing, give oxygen if available. If victim is not breathing, start CPR. Get immediate medical attention. Inaestion: Do not induce vomitting or give anything by mouth without emergency medical instructions. Immediately seek medical attention. Call poison control center at (202)625-3333. If victim is unconscious, trained personnel should start CPR. Never give an unconscious person anything by mouth. ' ISEOTION S. F1REFIGHTING MEASURES Flash Point None Upper Flammable Limit Not applicable Lower Flammable Limit Not applicable Autoiqnition Temperature None Extinquishinq media Choose media suitable for surrounding materials. No restrictions on media based on knowledge of this material. Firefiqhtinq instructions Evacuate area and fight fire from'a safe distance. Wear p°sitive pressure demand breathing apparatus and protect eyes and skin. Use water to cool fire-exposed containers, to protect personnel and to disperse vapors and spills. Water runoff can damage the environment. Dike and collect water used to fight fire. May produce small amounts of formaldehyde fumes under fire conditions or if mixed with acids. ISECTION 6. ACCIDENTAL RELEASE Keep unnecessary and unprotected personnel from ~ntering the spill area. Wear appropriate protective clothing. See Exposure Controls section. Absorb spill with inert material, sweep up and hold in properly labelled DOT container for disposal. Dike large spills to minimize the spill area. Material can cause environmental damage. Prevent material from contaminating soil or entedng sewer or bodies of water. Handlinq Wash thoroughly after handling. Avoid contact with skin. Avoid contact with eyes. Avoid breathing mist, dust, vapors or fumes. Harmful if swallowed. .St'oraqe Store in cool, dry, well-ventilated area away from incompatible materials listed in Section 10. ISECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Ventilation Requirements: Exhaust to satisfy the requirements of ASHRAE 62-1989. Ensure good mixing with fresh air supplied at a minimum of 0.5 cfm/ftz Personal Protective Equipment~ Use chemical splash goggles. Be certain eyewash is in the work area. Wear neoprene, nitdle rubber or other chemical resistant gloves and apron or lab coat. Respiratory protection is generally not required. Refer to 29CFR 1910.134 for OSHA requirements. I Page2 of 4 03025109 Exposure Guidelines: ln,qmdient OSHA PEL ACGIH TLV Water Not established Not established 1.2,4-Tdazole Not established Not established Substitgrted Triazole Trade Secret Not established Not established Nonionic Surfactant Trade Secret Not established Not established mf m TWA = time weighted average STEL = short term limit (c) = ceiling [SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, colode_~$ liquid Odor:. None Boilinq Point: approx. 100°C Odor Threshold: No data Specific Gravity: 1.050 Reactivity with Water:. None Vapor Pressure: approx. 15 mm Hg Meltinq Point: No data Evaporation Rate: 1 (water=l) Freezinq Point: No data ... Percent Volatile: approx. 80 Percent VOC: No data Solubility in Water:. Completely Vapor Density: No data pH:, 7.35 Water-Oil Partition Coefficient: No data ISECTION 10. STABILITY AND REACTIVITY Hazardous polymerization will not occur if product is used and stored as directed. Product is stable if used and stored as directed. Ha:~rdous Decomposition Products: Carbon dioxide. Materials to avoid: Stong acids. Strong bases. Oxidizers. Conditions to avoid: Excessive heal I SECTION 11. TOXICOLOGICAL INFORMATION LDso: > 2000 nlg/kg od, rat Acute Overexposure: Irritating by contact with skin and eyes. Irritating to respiratory tract and mucous membranes if inhaled. Irritating to gastrointestinal tract if ingested. May release small amounts of formaldehyde which is a carcinogen. Chronic Overexposure: Chronic dermatitis. May cause coughing, burning to the nose and throat, difficult breathing and other effects associated with formaldehyde overexposure. Page:) of 4 03O251O9 I [SECTION 12. ECOLOGICAL INFORMATION Ecoto×icity Data None available. I Chemical Fate Data None available. I ISECTION 13. DISPOSAL CONSIDERATIONS Discharging this material to the sewer may require a pen-nit. Do not discharge to septic systems. Observe all local, state and federal regulations when disposing of this material. IMaterial does not exhibit hazardous waste characteristics. I -ISECTION 14. TRANSPORTATION INFORMATION Component DOT Shippinq Name: Not DOT regulated I Hazard Class: None UN Number:. None Packinq Group: None Box DOT Shippin.q Name Not DOT regulated I Hazard Class: None UN Number:. None Packinq Group: None i Other Instructions: Product is labelled in accordance with U.S. 49CFR. I ISECTION 15. REGULATORY INFORMATION I Canadian SARA Clean Clean CAL Inqredient. .'I'SCA List 311/312 Air, .Water ,P. rop 65 I Water Y N N N N N 1,2,4-Tdazole Y N Y N N N i Substituted Triazole Trade Secret Y N N N N N Nonionic Surfactant Trade Secret Y N N N N N I ingredients comply with EPA TSCA requirements. Ali I ISECTION 16. OTHER INFORMATION This information is provided without warranty. The information is believed to be correct. This information should be used to make an independent determination of the methods to safeguard workem and the i environment. ! i Page4 of 4 03025109 Propane Material Safety Data Sheets <head><title>SUBURBAN PROPANE -- COMMERCIAL PROPANE </title></head><body bgcolor=ffffff><pre>SUBURBAN PROPANE -- COMMERCIAL PROPANE MATERIAL SAFETY DATA SHEET NSN: 683000N032803 Manufacturer's CAGE: 52413 Part No. Indicator: A Part Number/Trade Name: COMMERCIAL PROPANE General Information Company's Name: SUBURBAN PROPANE Company's ?. O. Box: 208 Company's City: WHIPPANY Company's State: NJ Company's Country: US Company's Zip Code: 07981 Company's Emerg Ph #: 800-424-9300(CHEMTREC) Company's Info Ph #: 201-887-6300 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 002 Status: SMJ Date MSDS Prepared: 01AUG91 Safety Data Review Date: 23AUG95 MSDS Preparer's Name: REGULATORY DEPT Preparer's Company: SAME MSDS Serial Number: BPBCZ Hazard Characteristic Code: G2 Ingredients/Identity Information Proprietary: NO Ingredient: ETHANE Ingredient Sequence Number: 01 Percent: 0-5 NIOSH (RTECS) Number: KH3800000 CAS Number: 74-84-0 OSHA PEL: NOT APPLICABLE ACGIH TLV: ASPHYXIANT Proprietary: NO Ingredient: PROPANE. %(WT): 87.5-100. Ingredient Sequence Number: 02 Percent: SEE ING NIOSH (RTECS) Number: TX2275000 CAS Number: 74-98-6 OSHA PEL: 1000 PPM ACGIH TLV: ASPHYXIANT Proprietary: NO Ingredient: PROPENE; (PROPYLENE) (SARA III) Ingredient Sequence Number: 03 Percent: 0-5 NIOSH (RTECS) Number: UC6740000 CAS Number: 115-07-1 OSHA PEL: NOT APPLICABLE ACGIH TLV: ASPHIXIANT Proprietary: NO Ingredient: BUTANE; (BUTANES) Ingredient Sequence Number: 04 Percent: 0-2.5 NIOSH (RTECS) Number: EJ4200000 CAS Number: 106-97-8 OSHA PEL: 800 PPM ACGIH TLV: 800 PPM Proprietary: NO Ingredient: ETHANETHIOL; (ETHYL MERCAPTAN) .- Ingredient Sequence Number: 05 Percent: 0-50PPM NIOSH (RTECS) Number: KI9625000 CAS Number: 75-08-1 OSHA PEL: (C) 10 PPM ACGIH TLV: 0.5 PPM; 9293 Proprietary: NO Ingredient: SUPP DATA: USE EXTREME CAUTION WHEN APPLYING H*20 TO CNTNR WHICH HAS BEEN EXPOS TO HEAT/FLAME FOR MORE THAN A (ING 7) Ingredient Sequence Number: 06 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 6:SHORT TIME. FOR UNCONTROLLABLE FIRES & WHEN FLAME IS IMPINGING ON CNTNR, WITHDRAW ALL PERS & EVAC VICINITY IMMED. Ingredient Sequence Number: 07 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO PROPANE & SOME OF MINOR COMPONENTS HAVE BEEN REPORTED (ING 9) Ingredient Sequence Number: 08 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 8: TO BE CARDIAC SENSITIZERS IN EXPERIMENTS. Ingredient Sequence Number: 09 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: SPILL PROC:EVAC AREA. IF POSS,REMOVE LEAKING CNTNR TO SA]FE AREA. STOP FLOW OF GAS/ALLOW TO DISPERSE IN SAFE AREA.(ING 11) Ingredient Sequence Number: 10 NIOSH (RTECS) Number: '9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 10: WATER SPRAY CAN BE USED TO HELP DILUTE VAPOR CONCENTRATION IN AIR. Ingredient Sequence Number: 11 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: OTHER PREC: DO NOT DROP/ABUSE CYLINDERS. KEEP CNTNR'VALVE CLSD & PLUGGED WHEN NOT IN USE.INSTALL PROT CAPS WHEN (ING 13) Ingredient sequence Number: 12 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 12: CYLINDERS ARE NOT CONNECTED FOR USE. E~4PTY CNTNRS RETAIN SOME RESIDUE, SO THEY SHOULD BE TREATED AS IF (ING 14) Ingredient Sequence Number: 13 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT A~PLICABLE Proprietary: NO Ingredient: ING 13: THEY WERE FULL.AVOID UNCONTROLLED RELS OF MATL. LIQ RELS WILL HAVE POSS EFT ON PLANT & ANIMAL LIFE. LRG (ING 15) Ingredient Sequence Number: 14 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 14: LIQ RELS WILL QUICKLY VAP TO PRDCE LRG, VAP CLOUD. VAP CLOUD IS BOTH FIRE & ASPHYXIATION HAZ. ODORANT (ING 16) Ingredient Sequence Number: 15 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 15: WARNING: ODORANT IS ADDED TO AID IN DETECTION OF LEAKS. ONE COMMON ODORANT IS ETHYL MERCAPTAN, CAS NO. (ING 17) Ingredient Sequence Number: 16 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 16:75-08-1. ODORANT HAS FOUL, SKUNK LIKE ODOR. oDORANT IS EFT IN MOST INSTANCES, BUT NOT EVERYONE CAN SMELL (ING 18) Ingredient Sequence Number: 17 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 17:ODOR. ABILITY OF PEOPLE TO DETECT ODORS VARIES WIDELY. ALSO, CERTAIN CHEM RXNS W/MATL IN PROPANE SYS CAN (ING 19) Ingredient Sequence Number: 18 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 18:REDUCE PROPANE ODOR LEV.NO ODORANT WILL BE 100% EFT IN ~LL CIRCUMSTANCES. IF ODOR LEV APPEARS TO BE WEAK, (ING 20) Ingredient Sequence Number: 19 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 19: NOTIFY PROPANE SUPPLIER IMMEDIATELY. Ingredient Sequence Number: 20 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: RESP PROT:SUFF TO ACHIEVE FULL CONFORMANCE W/ACCEPTABLE CRITERIA, USE NIOSH/MSHAAPPRVD RESP PROT (SUPPLIED-AIR/ (ING 22) Ingredient Sequence Number: 21 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: ING 21:SCBA AS APPROP).RESP SHOULD BE SELECTED BASED ON FORM & CONC OF CONTAMINANT IN AIR & I/A/W OSHA(29 CFR 1910.134). Ingredient Sequence Number: 22 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Proprietary: NO Ingredient: VP: 196 PSIG @ 100F. Ingredient Sequence Number: 23 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE Physical/Chemical Characteristics Appearance And Odor: COLORLESS, ODORLESS IN NATURAL FORM. Boiling Point: -44F,-42C Melting Point: N/A Vapor Pressure (MM Hg/70 F): ING 23 Vapor Density (Air=l): 1.5 Specific Gravity: 0.504 (H20=l) Solubility In Water: SLIGHT (0.1 TO 1%) Fire and Explosion Hazard Data Flash Point: -156F,-104C Lower Explosive Limit: 2.2% Upper Explosive Limit: 9.6% Extinguishing Media: USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS (FP N). Special Fire Fighting Proc: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP N).ELIM SOURCES OF IGNIT.EVAC AREA.NOTIFY FIRE DEPT.ALLOW ONLY TRAINED, PROPERLY PROT PERS IN AREA. SHUT (SUPDAT) Unusual Fire And Expl Hazrds: UNCONTROLLED VAPORS SPREAD RAPIDLY, ARE HEAVIER THAN AIR AND ARE EXTREMELY FLAMMABLE. Reactivity Data Stability: YES Cond To Avoid (Stability): HIGH HEAT, SPARKS, OPEN FLAME. Materials To Avoid: STRONG OXIDIZING AGENTS. Hazardous Decomp Products: INCOMPLETE COMBUSTION MAY YIELD CARBON MONOXIDE, A TOXIC GAS. Hazardous Poly Occur: NO Conditions To Avoid (?oly): NOT RELEVANT. Health Hazard Data LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: NO Route Of - Ingestion: YES Entry Health Haz Acute And Chronic: INHAL: ASPHYXIANT IN HIGH CONC DUE TO DILUTION OF AVAIL 02. AT EXCESSIVE %rAP CONC, PROD HAS.ANESTHETIC, ASPHYXIATING PROPERTIES & MAY CAUSE SLEEPINESS. AT LEVS >100,000PPM (I.E. 10%), PROPANE IS MILDLY IRRIT TO RESP TRACT & MAY RSLT IN DIZZ, HDCH, DROW, NAUS, SHORTNESS OF BRTH, MUSCULAR INCOORD, (EFTS OF OVEREXP) Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT. Signs/Symptoms Of Overexp: HLTH HAZ: EXCESSIVE SALIVATION, DISORIENTATION, VOMIT, & EXCITATION. IN EXTREME CASES, CONVL, UNCON & DEATH MAY OCCUR AS RSLT OF ASPHYXIATION. INGEST:LIQ MAY CAUSE FREEZE BURN SIMILAR TO FROSTBITE. INGEST NOT EXPECTED TO OCCUR IN NORM USE. EYE: LIQ MAY CAUSE FREEZE BURN SIMILAR TO FROSTBITE. SKIN: LIQ MAY CAUSE (ING 8) Med Cond Aggravated By Exp: PERSONS WITH CHRONIC RESPIRATORY DISEASE SHOULD AVOID EXPOSURE. Emergency/First Aid Proc: INHAL: REMOVE VICTIM FROM FURTHER EXPOS & INTO FRESH AIR. PROVIDE 02 IF BRTHG IS DFCLT. IF VICTIM IS UNCONSCIOUS, GET PROMPT MEDICJtL ATTENTION. EYE: FLUSH IMMEDIATELY W/H20 FOR AT LEAST 15 MIN. OBTAIN IMMED MED ATTN. INGEST: GET IMMEDIATE MEDICAL ATTN. SKIN: REMOVE CONTAMINATED CLOTHES, SHOES AND JEWELERY. IMMERSE BURNED AREA IN WARM (NOT HOT) WATER. KEEP IMMERSED. GET PROMPT ATTENTION. Precautions for Safe Handling and Use Steps If Matl Released/Spill: PROD IS EXTREMELY FLAM.VAP IS HVR/AIR & MAY COLLECT AT LOWER LEVS.FLAM CONC MAY BE PRESENT BELOW NOSE LEV. IF THERE IS LEAK BUT NO FIRE, DO NOT IGNITE ESCAPED GAS.ELIM ALL IGNIT SOURCES.DO NOT SMOKE,USE NEARBY PHONE/TURN ELEC SWITCHES ON & OFF. (ING 10) Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSE OF GAS I/A/W APPLICABLE LAWS AND REGS. VENT VAPOR IN SAFE LOCATION AND INSURE THAT GAS DISSIPATES BELOW LOWER FLAM LIMIT. CONTROLLED BURNING IS PREFERRED. DISP OF IN ACCORDANCE WITH FED, STATE AND LOCAL REGS (FP N). RCRA HAZ WASTE NO: D001. Precautions-Handling/Storing: STORE IN AUTH LOCATION OUTSIDE, DETACHED STOR IS PREF W/ADEQ VENT. ISOLATE FROM HEAT & IGNIT SOURCES. ISOLATE FROM COMBUSTIBLE MATERIALS. Other Precautions: PROVIDE SEPARATE STOR LOCATIONS FOR OTHER COMPRESSED/ FLAM GASES. INSPECT CYLINDERS FREQUENTLY FOR LEAKS,DENTS, GOUGES & CORR W/ EMPHASIS ON BOTTOM OF CYLINDER. STORE CYLINDERS IN UPRIGHT POSITION OR W/ PRESS RELIEF VALVES IN VAP SPACE. (ING Control Measures Respiratory Protection: IF CONCARE HIGH ENOUGH TO WARRANT NIOSH/MSHA APPRVD SUPPLIED-AIR/SCBA, ATMOSPHERE MAY BE FLAM. APPROP PREC MUST BE TAKEN REGARDING FLAM. FOR SITUATIONS WHERE FLAM HAS BEEN SAFELY ADDRESSED & WHERE CNTRL MEASURES ARE NOT FEASIBLE/ (ING 21) Ventilation: USE LOCAL AND DILUTION VENTILATION TO MAINTAIN EXPOSURES BELOW ACCEPTABLE CRITERIA. Protective Gloves: IMPERVIOUS GLOVES (FP N). Protection: CHEMICAL WORKERS GOGGLES .(FP N). Eye Other Protective Equipment: WEAR PROTECTIVE CLOTHING WHICH ARE IMPERVIOUS TO PRODUCT FOR DURATION OF ANTICIPATED EXPOSURE. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Suppl. Safety & Health Data: FIRE FIGHT PROC:OFF SOURCE OF GAS,IF POSS. ALLOW FIRE TO BURN ITSELF OUT AFTER GAS FLOW IS SHUT OFF.IF GAS FLOW CANNOT BE SHUT OFF, DO NOT EXTING FIRE.ALLOW FIRE TO BURN ITSELF OUT USING HIGH VOL H20 SUPPLY TO COOL HEAT-EXPOS PRESS CNTNRS & NEARBY EQUIP. APPROACH FLAME ENVELOPED CNTNR FROM SIDE, NEVER HEAD ENDS. (ING 6 Transportation Data Trans Data Review Date: 92289 DOT PSN Code: LLG DOT Proper Shipping Name: PETROLEUM GASES, LIQUEFIED OR LIQUEFIED PETROLEUM GAS DOT Class: 2.1 J DoT ID Number: UN1075 DOT Label: FLAMMABLE GAS IMO PSN Code: LMX IMO Proper Shipping Name: PETROLEUM GASES, LIQUEFIED o * IMO Regulations Page Number: 2147 IMO UN Number: 1075 IMO UN Class: 2(2.1) IMO Subsidiary Risk Label: - IATA PSN Code: TJL IATA UN ID Number: 1075 IATA Proper Shipping Name: PETROLEUM GASES, LIQUEFIED IATA UN Class: 2.1 IATA Label: FLAMMABLE GAS AFI PSN Code: TJL AFI Symbols: 0 AFI Prop. Shipping Name: PETROLEUM GASES, LIQUEFIED AFI Class: 2.1 AFI ID Number: UN1075 AFI Label: FLAMMABLE GAS AFI Basic Pac Ref: 6-6,6-8 Disposal Data Label Data Label Required: YES Technical Review Date: 20JUL92 Label Date: 14JUL92 Label Status: G Common Name: COMMERCIAL PROPANE Chronic Hazard: NO Signal Word: DANGER! Acute Health Hazard-Moderate: X Contact Hazard-Slight: X Fire Hazard-Severe: X _ Reactivity Hazard-None: X Special Hazard Precautions: FLAMMABLE. ISOLATE FROM HEAT AND IGNITION SOURCES AND COMBUSTIBLE MATERIALS. ACUTE: INHAL: AT EXCESSIVE VAPOR CONCENTRATIONS, THIS PRODUCT HAS ANESTHETIC, ASPHYXIATING PROPERTIES AND MAY CAUSE SLEEPINESS. AT LEVELS >100,000 PPM PROPANE IS MILDLY IRRITATING TO RESPIRATORY TRACT AND MAY RESULT IN DIZZINESS, HEADACHE, DROWSINESS, NAUSEA, SHORTNESS OF BREATH, MUSCULAR INCOORDINATION, EXCESSIVE SALIVATION, DISORIENTATION, VOMITING AND EXCITATION. CONVULSIONS, UNCONSCIOUSNESS AND DEATH MAY OCCUR. SKIN/EYE CONTACT/INGEST: LIQUID MAY CAUSE FREEZE BURN SIMILAR TO FROSTBITE. CHRONIC: NONE LISTED BY MFR. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y Label Name: SUBURBAN PROPANE Label P.O. Box: 208 Label City: WHI?PANY Label State: NJ Label Zip Code: 07981 Label Country: US Label Emergency Number: 800-424-9300(CHEMTREC) URL for this msds http://siri.org. If you wish to change, add to, or delete information in this archive please sent updates to dan@siri.org.. I I I I I Helium I Material Safety Data Sheets I I I I I I I I I,0¢~;.01 87 11:53a RU ~IZED USER 2097230179 p,1 HEUUM GAS LIQUID HELIUM .... NFPA RATING NFPA RATING ___ MATERIAL SAFETY DATA SHEET Pr~,p~ to U.S. OSH,~ CMA, ANSI and Canadian WHMIS Standards PART ! VVhat is the maferial and what do I need to know in an emerge.~, y? 1. PRODUCT IDENTIFICATION CHEMICAL NAME; CLASS: HELIUM - He LIQUEFIED HELIUM - He, (Cryogenic) Document Number:. P-O025 PRODUCT USE: For general analytical/synthetic chemical uses. SUPPLIER/MANUFACTURER'S NAME: AIRGAS INC. ADDRESS: Suite 100 259 RADNOR-CHESTER ROAD RADNOR, PA 19087-5240 EMERGENCY PHONE: CHEMTREC: 1-800-424-9300 International: 202-4I~3-7616 BUSINESS_PHONE: t-610-687-5253 DATE OF PREPARATION: May 12, 1996 FIRST REVISION: October 31, 1996 2. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME. CA8 # mole % EXPOSURE UMIT$ IN AIR ACGIH OSIitA I LV STEL PEL STEL IDLH OTHER ppm ppm ppm ppm ppm Helium I 7~7 ~.~5~5 There are no specifiO exposure limits for Helium. Helium i~ a simple asphyxiant (SA). I Oxygen le~Is should be maintained above 19,b-'%. Maximum Impurities < 1 ' None d tho trace impurities in this mixture conf,~bu[e sign~ica~l, iy 1o the h~z~rds associated with the ~'0cluct. ,~dl h,~zard ioform~b~n r,e~ir~n~ to th~- 13ro~u~ ~ boon {~,~Oppm) provided in this Material Safaty D~ta Sheet. per the re~uiromer~s of the OSHA HazarO ,, Communication S~andard (29 CFR 1910.1200) and ,State eciuivala'~ts standar ~ds. NE = Not E~tabtished. C -= C.,eil[ng Limit. See Seddon 16 for Definitions of Terms Used. NOTE: all VV~MIS required information is included. It is Io~ated in apprnprbt~, section~ b~ed on tf~o ANSI Z4QO. 1 I I I . I I II I . I III EMERGENCY OVERVIEW': Helium is a cc)Idem, odorless gas, or a colorless, odod~ss cryogenic liq~cl The i ,.prim. ary..,heal~, .ha.z~..d associated with releases of bhis gas is asphyxiation, by c~splaccment of oxygen. The cryogenic i .qud vwii ral~(~y Doll tO (~3¢ ~s at standard temperatures aFrd pr~sstxes. Tho cryogertc liquid can cause trostbite to any corf~minated tissue. I I I I III I IIII HELIUM GAS _LIQUID HELIUM oI ... SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPO~SUEF; The most significant route ot over-exposure for this gas is by inhalation. INHALATION_: High concenb'a'dons of this gas can cause an oxygen-deficient env~onmont Ir~viduaIs breatfling such ~.n atmosphere my expederr, e symptoms which include headache~, ringing in ears, clzziness, drowsiness, Lmonscim, nausea, vomiting, and depression of all the senses. Under some circu~ of over-exposure, death may occtr. The following effects associated wilh vadous levels of oxygen are aa follows: 12-10% Oxygen: Breathing and pulse rate increased, muscular coordination ~ightly crm~hJrbecl 10-14% OxTgen: EroSional upset, ab~0rrnal fatigue, distul13ed respire, ion. 6-10% Oxyg~: Nausea and ~omiting, co[lapse or loss 13ciow (~K,: C.,~l'~l~ ~, po'~:~bl~ r t~pirato~J oolla.DSe, OTHER POTENTIAL HEALTH EFFECTS: Contact with cryogedc liquid or mpidy expencfng gases (which arc released under high pre"..suro) may' m frc~t~t~. Gympt~nm ur I'[os~bite include change irt sldl'l color to wt~te or grayish-yeflow. The pain after c~ntact with liquid can quickly subside. loot. ~1 S?.. 11:53a AUTiRI'ZED USER Z087i0179 3. HAZARD IDENTIFICATION (Continued) I HEALTH EFFI--C;T$ OR RISKS FROM EXPO~,URE: An Explanation in Lay 'ren~s. Over'exposure to HeJium may calve tlne following he~Jth cff~'cs: ' I ACUTE: The most significant hazard associated wilh this gas is inhalalJon of oxygen-deficient atmospheres. Symptoms of oxygen deficiency include respiratory difficulty, ringing in ears, headaches, shortness of breaih, wheezing, headache, diz~ness, indigestion, nausea, and, ~ high c, oncer~ations, tmcor~ci~ or death may occur. The skin of a victim of over-e...Xl~OSU'e may have a blue color. Contact with cryogenic liquid or rapidly expanctng gases (which are released I under h~gh press~e) may cause frostbite. Symptoms of frostbite include change in skin color to white or grayish-yellow. The pain after contact with liquid can quickly subside. CHRONIC: There are currently no known adverse heelt~ effects associated with chronic exposure to this gas. I 4. I=IR,ST-AID MEASURES RI::SCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS OF EXPOSURE TO THIS PRODUCT VVITHOUT ADEQUATE PERSONAL PROTFCTIVE EQUIPMENT. At a minimum, Self- I Breathing Apparatus Personal Protective equipment should be w:)rn. Confined Remove ~m(s) to fresh ~ir. a~ q~acld¥ as po~ible. Trained per~mr~i ehoulcl admJr'J~er".¢,upplemer~l oxygen I carcIo-pulmonary resuscitation, if Only Irained personnel should administer supplemental rlece~o oxy§erL In case of frostbite, place the frostbitten part in warm w~ter. DO NOT USE HOT WATER; If warm water is not ;; ~ilable, ac is if~pr~,'[ic~ to use, wrap l~e affected parts gently in ~enKets. Alternatively, if t~le fire, rs or hand~ ere I os'~tten, place the effected area in the armpit, l:ncourage vict~m to ge~¥ exercise the affected pert while being w~rmed. Seek immec~te medical ~ttention. Vi~m(s) must be taken for medic~l affention. Rescuer~ ~nould be l~ken for met[cai attenlJon, if necea~ary. Tal~e copy ! of label and MSDS to physician or other heel~ prof~sional with viclJm(s). 5. FIRE-FIGHTING MEASURES I I HI::LIUM ~/~S LIQLIID HI::LIUM i NFPA RATIN~ NFPA RATING FLASH POINT, (method): Not applicable. I _AUTOIGN "I'I-ON TEMPERATURE: Not applicable. FLAMMABLE UMITS (in air by volume, %): -' Lo_g._w_.e.r__~,E~: Not applical~l~. Upper (UEL): Not applfr_~31e. I EXTINGUISHING MATERIALS: No, q-flammable, inert gas. Lime e~ng~shing~le~, a appropriate for ~xrot~tding~ FIRE fire. · I ! · Oo~, O1 97 11:53a RUTHORIZED USER 2097230178 5. FIRE-FIGHTING MEASURES (Continued) I UNUSUAL FIRE AND EXPLOSION HAZARDS: Helium does not bLs"n; however, containers, when involved in fire, may rupture in lhe heat of the fire. Note that he danger to cryogenic vessels is greater from the water used to control the fire than the heat from the fire. See the next paragraph. I RESPONSE TO FIRE INVOLVING CRYOGEN: Cryogenic liquids can be particularly dangerous during fires because of their pot~Y~ial to rapicly freeze water. Careles~ us~ of water may cause h~avy idng which could cause blockages in the vcnt~ nec~ to relea~ lfle gas that Is always ven'ong ~TOm a cryogenic vessel. Those blockages could cause i enough pressgtre to bLJld up to rupture or blast the container. For this reason firefighters must be made aware of the fact that they must avoid spraying water on any pressure relief device or gas vent in a cryogenic system. Liquid Hdium, when exposed to the a~x.~3her¢, will produc~ u cloud of Ice//og in the air ~ it~ release. If largo concentrations o~f cold Helium gas are vented, any water vapor in the surrounding air will condense, creating a dense fog I that may make ft cr~fficutt to find fire exits or eq~pment Ex331osion Sensi~vity to Mechanical Impact:. Not Sensif~vo, _Explosion Sensi{?ity to Sta~c Di,'schar.qe: Not SensilJve. ~FIGHTIN PROCEDURES; S~I fire-fightc're must wear Oclf-Corrtah~ B~.athing Apparatus and full protective er.~pment. 6./~CCIDENTAL RELEASE MEASURES ' SPILL AND LEJ,~K RESPONSE: Uncontrdled releases should be re~;~ded to by kained personnel using pre-planned procedures. Prc~.~er protective equipment should be used. In case of a spill, dear the affected area, protc~., people, .and respond w{~fl tr~;~ined pemonncl. Minimum Personal P~ut~,.~ve Eq~pment si3o~ld be Level B: protective clothing, I gloves ar~l Self-Contained Breathing Apparatus. Locate and seal the so,ce of ~he I~aldng mecha nically~ri.'sista nt gas, Allow thet gas, which is lighter tha~ air, to dissipate. Monitor the surrounding e~ea for oxygen levels..The atmosphere mu~ have at least la.5 percent oxygen befare pemonn~ can be allowed in ~hc area without Self'-Cor~aJned Breathing Apparatus, A~tempt to close the main source valve prior to entedng the area. If this does not stop tho release I (or if it is not po~;~ible to reach vane), gas in-place or remove a the the it to safe and eJIow the to be released l~iere. - RESPONSE TO CRYOGENIC RELEASE: Clear the affected a~ea and allow the liclu~d to evaporate and the gas to I dissipate. After the gas is formed, follow the ins~t.~ons provided in the previous para~aph, if the area must be entered by emergency I~, SCBA, Kevlar gloves, and api:~opriate foot and leg prot~'ti~n rnu~t be PART Iff} i ' 7. HANDLING and STORAGE WORK PRACTIiCES AND HYGIENE PRACTICES: As wi~h all chemicals, avoid gating this product IN YOU. Do not ~ or drink while': handing chemiceJs. Be aware of any ~igns of dizziness or fa~gu¢; exposures to fatal cor~centra~ons of i 1his product coul~ occur without any significant warring ~ymptom~ STORAGE AND' HANDLING PRACTI.C. ES: Cylinders should be sf~red in dry, well-ventilated areas aWay from sources of heat. Compre;s.s?.. d ga~s can pre~ent significant safety hazard& Store conta{nem away from heavily f~a/fiCked areas and emergc~3cy {.~xits. Post "No Smoking or Open Flames" signs in storage or Lisa areas. I SPECIAL PREC':AUTION. S FOR HANDLING GAS CYLi.N. DERS: Protect cyfindem against physical damage. Store in cool, dry, well-v(,.rfa'lated fireproof a~ea, away from flammable materiais ~ corro~ve atmospheres. Store away from heat and ignifionts~3urces and out of direct sgnlight Do not store near elevators, corridors or Ioac~ng docks. Do not allow arco where cylir~lcc5 are sto~,d to exceed 125'F. U~e or~ly storage core,ers and equipment (pipes, valves, fiffings to I relieve pressu"e, etc.) designed for the storage of Liquid Helium. Do not '~tore containers where they can come into contact wilh moi.<'rture. Cylinders should be stored upright and be firrn~y sect~el:l to prevent falling or being knocked over. C~nder~ can b~ s~red in the open, but in such cases, r~hoMd be l~otected ~gaJns! extremes of weather and from the dampr~ss of th~ ground to prev~t ruing. Keep DeWar fiasks covered, with loose tiffing cap. Th~s prevents air or I moisture from ~tering the cor~ainer, y~ allow~ pressure to c~cape. Ll~e or~y the stopper or plug supplied with the. [ container. Ens~ie that ice does not form in the neck o~ flasEr., if the n,~< ¢~f Dew-ar flaek is blooked by ice or air, [ollow manufacturer's irtsl~.~lion for removing it. A.131ugged Dewar or storage flask may develop sufficient press~e to c,~use catastri>ph~c fa~Lre. Ice can also cause pressure release ~tlves to fail, Never tamper Wi~h press~e relief I d.ed,.es i~n. and of Li?d. cold to c~rld~se freeze all c~irlder~. He~.um is. ~ the except~.~n o1' hydrogen an~ nature..' .,u(~. erin.y, mere ts a <3~pger et ~pes or vents ~;~ry~ng p{ug~ed, and air ~iquefac~on hazard. Liquid Helium must theremre I~ stored and handled t~der pos~[ive pre. sure or in a dosed system to preyer the irffiitralJon and solidification of a~r or o~e~ gases. The following rules are applicable to situations I eylindem are b~ng I.Oct O1 8'7 11:53a RUTHORIZED USER 2087230178 7. HANDLING and STORAGE (Continued) I Before Use: Move cylinders with a s~table hand-truck. Do not dra, g, slide or roll cylinders, Do not drop cylinders or permit '~em to strike each other. Secure cylinders firmly. Leave the valve protection cap in-place (where provided) until cylinder is ready for usc, I During Use: Use designated CGA fittings and other support equipment. Do not use adapters. Do not heat cylinder by any means to increase the discharge rate of the product from the cylinder. Use check va(ve or trap in discharge line to prevent hn~"'dou$ back-flow into the cylinder. It i~ alway-~ a good practicc not to uae oils or grease on 9a,$-handlir~ i fiffings or equipment After Use: Close main cylinder valve. Replace valve protection cap. Mark empty cylinders "EMPTY". NOTE: Use only DOT or ASME ~od~ cu~ ~t~iners. Earth-ground and bond all Ilr~es atld ecrdipment associated with tyis product, Close valve after each USe and when empty. Cylinders must not be recharged except by or with the consent of I owner. For additional information refer to ~he Compressed Gas Assodation Pamphlet P-I, Safe Handling of Compre,*~ed Gases in CordMnerg. For (~ryogenJc llquida, refer to CGA P-'I2, Safe Handling of Cryog~'nio Liquids. Additionally, refer to CGA BuJletin SB-2 ~Oxygen Deficient Atmospheres". I PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in section 6 (Accidental Release Meo~arcs), Make certain appl~catir~3 ¢q~pmont is Io(;kud and tagged-out s~tfoly. Purge gas handling equipment with inert gas (i.e. Helium) b~ore attempting repairs. Always use product in areas where adequate ver~lation is provided. I 8. EXPOSURE CONTROLS - PERSONAL PROTECTION I VENTILATION AND ENGINEERING CONTROLS: Use with adequate verdJlalJon. Local ex~ust ver~Jlation is preferred, because it prevents Helium dispersion into the work place by eliminating it at its source. If appropriate, install automatic 'monitoring equipment to detect thc level of oxygen. m RESPIRATORY PROTECTION: Maintain oxygen levels above 19.5% in the workplace. Use supplied air respiratory protedJon if oxygen levels are below 19.5% or d~ng emergency response to a release of this product If respiratory protection is required, follow the reqLireme~s of the Federal OSHA Respiratory ProteclJon standard (29 CFR 1910.134), or equivalent State standards. " I EYE PROTECTION: Splash goggles, face-shields or safety g~asses. Face-~hields must be vwm when using cryoger~c Helium. HAND PROTECTION: Wear mechani~ly-res~stant gJove~ when handing cylinders of ~s product. Use Iow- tempecature protective gloves (i,e. Kevlar) whe~ working wi~ containers of Uq~d Helium, BODY PROTECTION: USe body protec~on eppr0p0ate for task. Transfer of large quan~tJes under pressure may require protective equipment appropriate to protect eml~oyees from splashes of liquefied product, as well provide suffident insular/on from extreme cold. 9. PHYSICAL and CHEMICAL PROPERTIES VAPOR DEN SITY: O. 178 kg/ma DH: Not applicable. SPECIFIC GRAV]TY( air --~: 0.1381 FREEZING POINT: Not applicable,, SOLUBIMTY IN WATER: Insoluble. BOILING POtNT(°F (~j 1 atmos.): -452.1 °F; -268.9 °C EVAPORATION RATE (nl3uAc = 1): Not applicable. EXPANSION RATIO: 754 (cryog~ic liquid) ODOR THRESHOLD: Not applicable. VAPOR PRESSURE (psla): Nc~pplicable. COEFFICIENT WATER/OIL DISTRIBUTION; Not applicable. SPECIFIC VOLUME (ft~/Ib): 96,7 APPEARANCE AND COLOR: This product is a cola4ess, ododess gas or a co/orless and odorless cryogenic liquid. HOW TO DETECT THIS SUBSTANCE {'warnin~ properties): There are no ~3u~__~J warning properties associate(fwith" a release of this product, In terms of leak detection, fiffin~ and joints can be painted with a soap sc~t~ic, n leaks, which will be indicated by a bubble formalJon. 10. STABIETY and REACTIVITY I ~TABIUTY:,.Normally stable, inert gas. ~.ECOMP~..,ITION PRODUCT.~; Nun~. MATERI/~LS VVITH WHICH SUBSTANCE IS INCOMPATIBLF: None. Helium is an ir~rt gqs. H~. R~U~, POLYMERI~,'[]QN: Will not occur. CONDITIONS T~).~,VgtD; qy~.~s -Oct O1 S? 11:54a RUTHORIZED USER 2087230179 p. PART iV /s there any other useful information about this mageda/? i 1. TOXICOLOGICAL INFORMATION TOXIC4TY DATA: There is no specific toxicology data for Helium. Helium is a simple asphyxiant, which acts to displace oxy.g~'~ ir~ Ihe environment. SUSPECTED CANCER AGENT: Helium is not found on the following lists: FEDERAL OSHA Z UST, NTP, CAL/OSHAi IARC, and therefore is not considered to be, ~ suspected to be a cancer-causing agent by these agencies IRRITANCY OF PRODUCT: Contact with rapidy expanding gases can cause frostbite and damage to exposed skin and eye~. .~NSITIZATION OF PRODUCT; Helium ia not a ~_,ensitizcr, REPRODUCTIVE TOXICITY INFORMATION: Usted below is information concerning the effects of this product and its components on He human reproductNe system. ~Muta_~citv: This product is not expected to cause mutagenic effect~ in human. Embryotoxldty: No embryotoxic effects have been described for Helium. T~c/t~_: This product Is not expected to cause teratogenic effects in humar~. Reproductive ToxicS: This product is not expected to cause adwrse reproductive effects in humans. A rnufagen is a chemical which causes I~rmanent changes to genetic mate~fal (DNA) such that the change~ will propagate through generation fines. An eml~ryc~oxin ~s a chemical which eause~ dorn~je fo e <feveloping ornbryo (i.e. within the §~t eight weeks of pregnancy in humans), but the damage does no~ propagate acro~ generational lines. A teratoge.n_ is a chemical which causes damage to a developing fetus, but the damage does nc~ propaga~ across generational lineg. A reproductive toxin is any substance which interferes in any way wilfl the reproS{Jcfive procegg. MEDICAL CONDITIONS AGGP, AVATED BY EXPOSUEE; Pre-existing respiratory conc~ona may be aggravated by over-exposure to 1his product. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms end reduce over-~xposure. .. BIOLOGICAL EXPOSURE INDICES (BEIs): CL~rently, Biological Exposu'e Indices (BEIs) are not applicable for this 12. ECOLOGICAL INFORMATION ENVIRONMENTAL STABILITY; Helium occ~s naturally in the atmosphere. The gas will be dissipated rapicly in well- verf~lated areas. EFFE_C~T_ OF MATERIAL ON PLANTS or ANIMALS: Any advcr~ ¢ffe~-t animals would ~ated to deffaent environments. No adverse effect is arfictpated to occur to pla3Hife, except for frost produced in ~he presenCe of rapidly expanding gases. EFFECT OF CHEMICAl. ON AQUATIC MFE: NO evidence i$ c~'rent~y ava~able on t~/$ product's effects 13. DISPOSAL CONSIDERATION5 PREPARING WASTES FOR DiSPOSAl '. Waste ~ must be in acca'dance wilh appropriate Federal, State, and local regulations. Rettzn Airgas supplied cylind~m w~th any residual product to AJrga.-3. Do not c~spose of' Icc. ally. 14. TRANSPORTATION INFORMATION THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OI- TR~NSPORTAIION. PROPER SHIPPING NAMe: Helium, compressed HAZARD CLASS NUMBER and DE~SCRIPTION: 2.2 (Non-Rammabl¢ Gas) .UN IDENTIFICATION NUMBEF~: UN 1046 PACKING GROUP: Not applicable. D.__OT LABEL(S) REQUIRED: Non-Flammable Gas _NORTH AMERICAN EMERGENCY REE3PONGE GUIDEBOOK NUMBEI~ {19c.~): 121 Oc~ O1 9'7 11:55a RUTHORIZED USER 209?230175 p.'7 14. T~NSPORTATION INFOR~TION {Con~nued} F~ Helium L~uid: PROPER SHIPPING NAME: Helium, refd~ated li~d H~RD C~SS NUMBER and DESCRIP~ON: 2.2 (N~Ram~c Gas) UN IDEN~CATION NUMBER: UN ~9~ PACKING GROUP: Not ap~i~e. ~T ~BEL(S) REQUIRED: N~Ramma~e Gas NORTH AMERICAN EMERGENCY RESPONSE GUIDEB~K NUMBER (1~); 120 MARINE POLLUTANT; Hdium is ~t d~ by ~e ~T ~ a M~ne Poll~ (~ d~n~ by ~ CFR 172.101, ~x B). T~NSPORT CANADA T~NSPORTATION OF D~GEROUS GOODS REGU~TIONS: THIS MATERI~ IS CONSIDERED AS D~GEROUS G~DS. U~ ~e foiling i~orma~ f~ ~e ~ep~ of ~d~ SNpm~. F~ Heli~ PROPER SHIPPING N~E: H~ium, ~m~d H~RD C~SS NUMBER ~d DESCRIPTION: 2.2 (N~Ram~ffe G~) UN IDENTIFICATION NUMBER: UN PACKING GROUP: Not ap~i~e. ~BE~S) REQUIRED: N~Ram~e CANUTEC EMERGENCY RES~NSE GUIDE NUMBER: 08 F~ Liq~fi~ Helium: PROPER SHIPPING ~E: Helium, re~g~ted H~D C~ NUMBER ~d DESCRI~ON: ~ (N~Ramma~o G~) UN IDENTIFICATION NUMBER: UN PACKING GROUP: Not ~e. ~BEL(O) REQUIRED: N~>Ramma~¢ Gas .' CANUTEC EMERGENCY RESPONSE GUIDE NUMBER: 15. REGU~TORY INFOR~TION SA~ REaRiNG REQUIREMENTS: ~s ~o~ is ~bj~ ~ ~er~ng r~rcm~ ~ ~ ~. ~ ~d 313 of T~e ill of ~e S~ ~m~ ~ R~~ A~., ~ fdic: Haium .... "] ..... NO' _.. NO - 'NO .......... S~ ~d ~ ~: Not ~e. TSCA INVENTORY STA~S: Hdium is li~ ~ ~e TSCA I~. CERC~ REPORTABLE OUt,TIES OTHER FEDE~L R~U~NS: N~ ap~i~e. G~FO~NIA PR~SI~ON ~; H~ium is ~I ~ ~e ~ff~a ~~ ~ li~. STA~E ~GU~TORY INFOR~ON: H~ium is ~v~ed ~~ Toxic Ha~$ S~a~ Helix. ~a~ ~li~. Li~: ~i=. Calera - P~e ~e Mi~-~ IM~l~Toxic Te~s - ~a~s Su~a~ LI~: ~w d~y - ~g~ to ~ - S~~:~li~. ~r~ ~a~ LI~: Hell~. L~: No. Ma~s S~a~ ~: N~ ~i~. P~lvania - ~d~s S~a~e Li~; ~li~. i'0o% O1 87 11:55a RUTHORIZED USER EO97E3017S p.8 1 $. REGULATORY INFORMATION (Continued) ~BELING (For ~m~e~d G~: CAUTION: HIGH PRESSURE GAS CAN CAUSE ~PID SUFF~ATION, Stye ~d ~ ~ ade~e v~lafi~, Use ~pm~ ~t~ f~ c~ind~ ~e. Cl~e v~ve aft~ ~ ~ a~ ~ erupt. U~ in ~~e ~ ~e M~ ~e~ ~ Sheet. RR~T-~D: IF IN.LED, remove to fre~ ~r. If ~t ~ng, ~ve ~fici~ r~imfi~. If ~ is ~fl~, ~ve o~g~. ~1 a phy~d~. DO NOT REMOVE THIS PRODUCT ~BEL. ~BELING (f~ ~WAYS KEEP CONT~NER IN UPRIGHT ~SITION. WARNING: ~TREMELY CO~ UQUlD AND GAS UNDER PRESSURE. CAN CAUSE ~RD SUFFOCA~ON. CAN CAUSE SEVERE FROST~TE. UQUID OR ~LD GA~ C~ FRE~ ~R IN VENT UNE8. ~=e a~ ~ ~ ad~te v~3a~. ~ ~t get li~d in eye, ~ ~n, ~ do~. F~ li~d ~~, w~ face ~d ~d ~ov~. ~ ~t ~, U~ ~d ~k f~ ~n~ ~em~. S~ ~n~ ~~'s ~flng i~fi~ ~ avdd ff~ng ~r in v~ ~, ~ ~w a~ ~ ~ ~ ~ erupt. U~ in ~~e ~ ~e Mat~ ~f~ Da~ Sh~t. RRST-~D: ? IF IN.LED. re~ve to fr~ ~r. If ~t ~, ~ve a~d~ r~mfi~. If ~ng is ~ ~w o~gm. ~1 a IN ~SE OF FROSTBITE, ~n imme~ate m~ DO NOT REMO~ THIS PRODUCT ~SEL T~GET OR~S: R~ s~m, WHMIS SYMBOLS: PREPARED BY: CH~C~ ~ A~OC~TE~, I~. 9163 Ch~ke DrN~ ~n Dido, CA 9212~1~2 61~302 ~ ~ in ~n ~ ~ n~ i~. '~' """ ~' ~ - ~;~"/- -~-' ,Oc~ O1 S7 11:56a RUTHORIZED USER 20S7230179 p.~ I · DEFINITIONS OF TERMS I A large number of abbreviations and acronyms appeer o~ a MSDS, TOXICOLOGICAL INFORMATION: Some of these which are commonly used inck~le the follnwing' P,'~-~ble health hazards as derived from human data, animal studies, or fTom the results of studies w~h similar compounds are I CAS #: This is the Chemical Abstract Set, ce Number which presem'ed. Definitions of someterms used in this section are; LDo0 uniquely identifies each constituent. It is u~:l fo~ computer-related - Le~hal Dose (solids & liquids) which kills 50% of the e:~x>sacl 5ear¢l~ing. animals; LC~ · Lc{hal Conc4x~rafion (g3¢e~) which kills 50~ O[ th~3 e~posed animals: ppm concentration expressed in parts o[ material I EXPOSURE LIMITS IN AIR: per million parts of air or waler; mg/m* concen'cration expressed in ACGIH - American Conference of Governmental Industrial weight of substance p~ ~lume of air, rog/kg quantity of material, by I-lyglenls~5, a pr01'e~Sional a~oclaUon Wi3lCrt esl:abll~e5 exposure wreighl., i~dmit[i::;I.~c~l tv u tt;~st 5ubJ~-~;, bar=ed on their body weight in limits, kg. Data from several sources are used to evaluate the cancer- I TLV - 'l~reshold Limit Value - an airborne concentration o1: a caur~ng pclential of the material. The sources are: IARC - the substance which represents co~ditions under which it is generally !ntematioral Agency fo~ Research on Cancer; NTP - the National believed that nearly all w~xkers rn~y be repeatedly exposed without T_oxicology p..rogram, RTEC,5 - the ~egr3~'y ol~ ~J~oXi¢ EITec~s ol' ao'veree effect. The duration must be ¢onsidei'ed, including the 8- _Chemical _Substances, OSHA and CAI/OSHA IARC and NTP rate hour Time Weighted Average (TWA), the 15-minute Shin1 Term chemicals on a scale of dec~easing potential to cause human cancer I Exposure Limit. and the instan~3neous Ceilin~i Level. Sldn with rankings from I to 4. Subranklngs (2A, 2B, mc.) are also used. adsofpl~n effects must also be considered. (Xher measures of toxk:ity include 'rDLo, the lowest dose to cause a OSHA - U.S. Occupational Safel:y arid Health Administration. symptom and TCLo the lowest conr_,er~a'don to cause a symptom; PEL - Permissible F_xpostze Emit - this exposure value means TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCO, the i ex3c{ly th~ ~=~me a~ a TLV, except that ~ i~ enforceable by O..eJAA ~ (hr r. oncentration) to cause death. BE1 - Biological E.~3osure The IDLH - Immediately Dangerous to Life and Health level Indices, represent the le',~ls of determinants which am most lilly tO represents a concentration from which one can escape within 30- be observed in Sl:~cimens collected from a healthy worker who has minutes without suffering escape-pre~'~ing or permanent injury. ~ exposed to chemicals to the same extent as a worker with Thc DFG - MAI( Is the Republic of Oerrnany'a Maximum Expo--,.-urc Jnh~l,sf~n expoeure to the TLV. I Level, similar to rne U,S. PEL. NIOSH is the N~onal Institute oi~ Occupational Safd. y and Health, which is the research arm of the REGULATORY INFORMATION: U.S. Occupational ,Safety and Health Administration (OSHA). This section explains the impact of various Isws and regulstions on NIOSH ~ exposul'e gulaeline~ c,~lled R. ecomm~td~J F_x[,x,~ l,l~ ~'~'~'J~l. EPA i~ the U.~. En~ironmcatal F'rc~eC~iOn Agency. i Levels (RELs). Whe~ no exposu~ guidelines are e~blished, an WHMI,S /s the Canadian Workplace Hazardous M~tedals entry of NE is made for re{erence. Information System, DOT and TC are the U.S. Departmen~ Of Transportation and the Transport Canada, respecti~y. The FLAMMABIETY LIMITS IN AIR: Much of the information related to tOllOWmg taws are alSO pe~tirle~ [o the In1'orm~on presemea In mis rice and explo, sion is derived from the National Fire Prmecti0n MSDS: Superfund _Amendments and _Reauthorizalion _Act I Association (NFPA). LEL - the lower percent of vapo~ in air, by (SARA); the Toxic Substance _Control Act (TSCA); Marine volume, that will explode or ignite in the presence of an ignition Pollutant status according to the OOT: California's Safe Drinking source, .UEL - the highest percenf, of vapor in air, by ~lume, tha~ will Water Act (Proposifio~ 65); the Comprehensive _Environmental explode or ignite in the pcesenca of an ignition source. Resl~llse, ~Compensation, and _Liability _Act (CERCLA or I ,Superfulld). This section also includes information on the precautionary warnings which appear on the materials Package label. CITY OF BAKERSFIELD OFFICE OF ENVIRONMENTAL SERVICES 1715 Chester Ave., Bakersfield, CA (805) 326-3979 INSTRUCTIONS: 1. To avoid further action, remm this form within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA BUSINESS NAME: LOCATION: ~/~-) MAIl.lNG ADDRESS: CITY: STATE: ZIP: (-~' PHONE: DUN & BRADSTREET NUMBER: SIC CODE: PRIMARY ACTIVITY: OWNER: MAILING ADDRESS: SECTION 2: EMERGENCY NOTIFICATION CONTACT TITLE BUS. PHONE 24 HR. PHONE HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 3: TRAINING NUMBER OF EMPLOYEES: ~ MATERIAL SAFETY DATA SHEETS ON FILE: BRIEF SUMMARY OF TRAINING PROGRAM: · ~-r',-A,'u~t~dr.;- ~,o.:~ ,&,,/A, ca-f~e~ ,,~ ?~"o ~--~-r SECTION 4: EXEMPTION REQUEST I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAPTER 6.95 OF THE "CALIFORNIA HEALTH & SAFETY CODE" FOR THE FOLLOWING REASONS: WE DO NOT HANDLE HAZARDOUS MATERIALS. WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIME EXCEED THE MINIMUM REPORTING QUANTITIES. OTHER (SPECIFY REASON) SECTION 5: CERTIFICATION I, CERTIFY THAT THE ABOVE INFORMATION IS ACCURATE. I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIV. 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT INACCURATE INFORMATION CONSTITUTES PEKJURY. SIGNATURE TITLE DATE 2 ItAZA~OUS MATI~RIALS MANAGEMENT PLAN SECTION 6: NOTIFICATION AND EVACUATION PROCEDURES A. AGENCY NOTIFICATION PROCEDURES: ~O~-~C~ ,~ ~$~ ~,,~O~ ,,~ P~6 ~r B. EMPLOYEE NOTIFICATION AND EVACUATION: C. PUBLIC EVACUATION: D. EMERGENCY MEDICAL PLAN: HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 7: MITIOATION, PREVENTION AND ABATEMENT PLAN A. RELEASE PREVENTION STEPS: B. RELEASE CONTAINMENT AND/OR MINIMIZATION: C. CLEAN-UP PROCEDURES: SECTION 8: UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FACILITY) NATURAL GAS/PROPANE: (~a.J~ .9,~_ A/~ C.R,~ o4::. ~"c~: f3c. o6- ELECTRICAL: O~'r-¢~0co zo'C~ WATER: (D.a"r'~ ~ O~ ~- ~ SPECIAL: LOCK BOX: YES/NO IF YES, LOCATION: SECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABILITY A. PRIVATE FIRE PROTECTION: B. WATER AVAILABILITY (FIRE HYDRANT): 4 Business Name ~ov.~ ~ r -'7-4-/~ Address ~ ~ ~"c.~'~ Page of CHE~C~ DESC~ON I) ~ORY STA~S: Ne~ Ad&tion [ ] Re, sion [ ] ~lefion [ ] Ch~k ifch~ is a NON T~ S~et [ ] T~ ~ [ ] ChrONic: ~[ ] C~ ~ 4) Physi~ & H~ P~SIC~ H~d Catego~ Fife [ ] R~cfive ~S~ Rel~ of~ [ ] ~at~ H~ (Acu~) [ ] ~lay~ H~ (C~c) [ ] 5) WAS~ C~SS~CA~ON (3~t c~ ~m D~ Fo~ 8022) USE CODE 7) ~O~ ~ ~ AT FAC~ ~ OF ~~ 8) STOOGE CODES ~ ~ly ~o~t ~ L~ [ ] ~ ~ ~3 [ ] a) Con~ Av~e ~ly ~o~t ]~ C~ [ ] b) ~: ~ ~o~t ~) T~~ ~ Days on Si~ C~le ~ch Mon~: ~ Y~, I, F, ~ ~ ~ I, I, ~ S, O, N, D 9) ~: Li~ ~ CO~~ C~ % · e ~ mom bo-~o~ 1) % ~ ~ V~ [ ] ch~ ~~ or 2) [ ] ~y ~ ~n~m 3) [ ] 1)~ORYSTA~S:New~A~[ ]ReMsion[ ]~lefion[ ] Ch~k~~aNONT~~[ ]T~~[ ] Ch~N~e: ~[ ] C~ 4) Physi~ & H~ P~SIC~ ~dCa~gofi~ F~[ ]R~cfive~S~Rel~of~e[ ] ~a~H~(A~)[ ]~lay~H~(C~c)[ ] 5) W~ C~SS~CA~ON (3~t ~ ~m D~ Fo~ 8022) USE CODE 7) ~O~ ~ ~ AT FAC~ ~OF~~ ~) STOOGE COD~ ~ D~ly ~o~t ~ L~ [ ] O~ [~] ~ [ ] a) C~: Av~ge ~ly ~o~t C~es [ ] b) ~e~e: ~ ~o~t c) T~a~ ~est S~ Con~ ~ Days on Si~ C~le ~ch M~: ~ Y~, I, F, ~ A, M, ~, ~, ~ S, O, N, D 9) ~: Li~ CO~~ C~ % · e~mom~ 1) D)C~aW~ ~cgcoc ~o~ ~ ~ [ ] ~y ~ ~m~n~ 3) [ ] 10 )L~A~ON ~licve ~e sub~.~[~ is ~, a~te ~d ~pl~. . ~ / P~ Nme & Tifl~ of~u~ Comfy R~fiv~ Si~ ff~RDOUS MATERIALS INVENT~y . Page _ of Business Name Address CHEMICAL DESCRIPTION I ) INVENTORY STATUS: New [ ] Addition [ ] Revision [ ] Deletion [ ] Check if chemical is a NON Trade Secret [ ] Trade Secret 2) Common Name: 3) DOT # (optional) Chexnical Name: ~ [ ] C~S # 4) Physical & Health PHYSICAL HEALTH Hazard Categories Fire[ ]Reactive[ ]Sud,~,'~aReleaseofPressure[ ] lmmediateHealth(Acute)[ ]DelayedHealth(Chroni¢)[ 5) W^STE Ct.~SSU~C^T~ON (3-aigit co~ a,,... DHS Form 8022) USE CODE 6) ?HYSICAL STATE SoUd [ I Liquid [ ] Cas [ I Pure [ ] Mixture [ ] Waste [ ] Raaio~tive [ ] 7) AMOUNT AND TI2vlE AT FACILITY UNITS OF MEASUR~ 8) STORAGE CODES Maximum Daily Amount Lbs [ ] Gal [ ] R3 [ ] a) Container:. Average Daily Amount Curies [ ] b) Pressure: Annual Amount ¢) T .empetatum Largest Size Container # Days on Site Circle Which Months: Ail Year, fi, F, M, A, M, ~, ~, A, S, O, N, D 9) MIXTURE: List COMPONENT CAS# % WT AHM the three most hAT~rdons 1) [ chemical components or 2) [ any AH~ components 3) [ 10)LOCATION 1) INVENTORY STATUS: New [ ]Addition[ ]Revision[ ]Deletion[ ] Check if che~cal is a NON Trade Secret [ ]Trad~Seo~[ 2) Common Name: 3) DOT # (optional) Chemical Name: AHM [ ] CAS # 4) Physical & Health PHYSICAL HEALTH Hazard Categories Fire[ ]Reactive[ ]SuddenRelesseofPressure[ ] lmme, rli~teHealth(Acute)[ ]DelayedHealth(Chroni¢)[ 5) WASTE CLASS~C^T~ON (3-aigit coa~ from Dm Form S022) USE CODE 6) ?HYSICAL STATE Sotia[ ] Li~uia [ I C-as [ ] Pure [ 1 IViixture [ I Waste [ ] Radioactive [ l 7) AMOUNT AND TIME AT FACILITY UNITS OF MEASURE 8) STORAGE CODES Maximum Daily Amount Lbs [ ] Cad [ ] ft3 [ ] a) Container:. Average Daily Amount Curies [ ] b) Pressure: Annual Amount ¢) Te~nperature Largest Size Container # Days on Site tin:lc Which Months: All Year, J, F, M, A, M, ~', J, A, $, O, N, D 9) MIXTURE: List COMPONENT CAS# % WT AH1Vi the three most hazardous 1) [ ] chemical components or 2) [ any AHM components 3) [ 10)LOCATION ! certi~ under penally oFlaw, tha~ I have personally examined and am familiar with the information on this and all attached docuuumts. I believe the submitted information is true, accurate and complete. PRINT Name & Title o£Authorized Company R~tstive Sismmre Date BAZARDOUS MATERIALS INVENTORY Page of, Business Name Adrift. ss CHEMICAL DESCRIPTION I)INVENTORYSTATUS:New[ ]Addition[ ]Revision[ ]Deletion[ ] Check if chemical is a NON Trade socret [ ]Tradesocr~t[ 2) Common Name: 3) DOT # (optional) Chemical Name: AHM [ ] CAS # 4) Physical & Health PHYSICAL HEALTH Hazard Categories Fire [ ] Reactive [ ] S~d_den__ Release of Pressure [ ] Immediate Health (Acute) [ ] Delayed Health (Chronic) 5) WASTE CLASSIFICATION (3-digit code fi'om DHS Form 8022) USE CODE 6) PHYSICAL STATE Solid[ ] Liquid[ ] C_ras[ ] Pure[ ] Mixture[ ] Waste[ ] Radioactive[ ] 7) AMOUNT AND TIME AT FACILITY UNITS OF MEASURE 8) STORAGE CODES Maximum Daily Amount. LI~ [ ] Gal [ ] fl3 [ ] a) Container:. Average Daily Amount Curies [ ] b) Pressure: Annual Amount ¢) Temperature Largest Size Container # Days on Site Circle Which Months: Ail Year, $, F, M, A, M, $, $, A, S, O, N, D 9) MIXTURE: List COMPONENT CAS# % WT AHM the three most h---,dom 1) [ chemical components or 2) [ any AHM components 3) [ 10)LOCATION I)INVENTORYSTATUS:New[ ]Addition[ ]Revision[ ]Deletion[ ] Check if chemical is a NON Trade Secret [ ]TradeSecret[ 2) Common Name: 3) DOT # (optional) Chemical Name: AHM [ ] CAS # 4) Physical & Health PHYSICAL HEALTH I-l,~,zrdCategories Fire[ ]Reactive[ ]S~d,L,~ReleaseofPressure[ ] lmmediateHealth(Acute)[ ]DelayedHealth(Clmmic)[ 5) wASTE CLASSn~C^T~ON (3-aiSit co~ from OHS Form S022) USE CODE 6) PHYSICAL STATE Solid[ ] Liquid[ ] Gas[ ] Pure[ ] Mixtu~[ ] Waste[ ] Radioa~ve[ ] 7) AMOUNT AND TIME AT FACILITY LrN1TS OF MEASURE 8) STORAGE CODES Maximum Daily Amount Lb~ [ ] Cad [ ] fi3 [ ] a) Containec. Average Daily Amount Curie~ [ ] b) Pressure: Annual Amount ¢) Temperature Largest Size Container # Days on Site Circle Which Months: All Year, $, F, M, A, M, $, I, A, S, O, N, D 9) MIXTURE: List COMPONENT CAS# % WT AHlVl the three most hazardous 1) [ chemical components or 2) [ any AHM components 3) [ 10 )LOCATION I ceftin, under penalty of law, that I have personally examined and am familiar with the information on this and all aRached doomlents. I believe the submitted information is true, accurate and complete. PRINT Name & Title of Authorized Company Represantative Signature Date H~RDOUS MATERIALS INVENT(~. Page of __ Business Name Addr~s CHEMICAL DESCRIPTION 1 ) ~VENTORY STATUS: New [ ] Addition [ ] Revision [ ] Deletion [ ] Check ifchemicai is a NON Trade Secret [ ] Trad~ Secret 2) Common Name: 3) DOT # (optional) Chemical Name: AHM [ ] CAS # 4) Physical & Health PHYSICAL HEALTH Hazard Categories Fire [ ] Reactive [ ] $,_,a_d~ Release of Pressure [ ] Immediate Health (Acute) [ ] Delayed Health (Chronic) 5) WASTE CLASSIHCATION (3=digit code from DHS Form 8022) USE CODE 6) PHYSICAL STATE Solidi ] Liquid[ ] Gas[ ] Pure[ ] Mixture[ ] Waste[ ] Radioactive[ ] 7) AMOUNT AND TIME AT FACILITY UNITS OF MEASURE 8) STORAGE CODES Maximum Daily Amount Lbs[ ]Gall ]R3[ ] a) Container ^verage Daily Amount Curies [ ] b) Pressure: Annual Amount ¢) Temperature Largest Size Container # Days on Site Circle Which Months: AH Year, $, F, M, A, 1~ $, $, A, S, O, N, D 9) MIXTURE: List COMPONENT CAS# % WT AHM the three most hazardous 1 ) [ chemical components or 2) [ any AHM components 3) [ 10)LOCATION I)INVENTORYSTATUS:New[ ]Addition[ ]Revision[ ]Deletion[ ] CheckifchemicalisaNONTradeSeeret[ ]Tradesocret[ ] 2) Common Name: 3) DOT # (optional) Chemical Name: AHM [ ] CAS # 4) Physical & Henlth PHYSICAL HEALTH Hazard Categories Fire[ ]Reactive[ ]S~dd~ReleaseofPressure[ ] lmmediateHeaith(Acute)[ ]DelayedHealth(Chroni¢)[ ] 5) wASTE CL~SI~C^T~ON (3.digit code finn Dm Form S022) USE CODE 6) PHYSICAL STATE Solidi ] Liquid[ ] Gas[ ] Pure[ ] Mixture[ ] Waste[ ] Radioactive[ ] 7) AMOUNT AND TIME AT FACILITY UNIT~ OF MEA~ 8) STORAGE CODES Maximum Daily Amount Lbs [ ] Gal [ ] ~ [ ] a) Container. Average Daily Amount Curies [ ] b) Pressure: Annual Amount ¢) Temperature Largest Size Container # Days on Site Circle Which Months: All Year, J, F, M, A, M, $, $, A, S, O, N, D 9) MIXTURE: List COMPONENT CAS# % WT AHM the three most ),.,,A_,~tous l) [ ] chc-micai components or 2) [ ] any AHM components 3) [ ] 10 )LOCATION f certify under penalty of law, that I have personally exantined and am familiar with the information on this and all attached documents. I believe the submitted information is true, accurate and complete. PRINT Name & Title of Authorized Company Representative Signature Date H~ZARDOUS MATERIALS INVENTORY. · Page of Busine~ Name Addr~s CHEMIC^L I~E$CI/II:TION ~) {NVENTORY STATUS: New [ ] Ad~lition [ ] Revision [ ] Deletion [ ] Check ifch(mfical is a NON Trad~ 8(~a~t [ ] Trad~ ,S~cr~t 2) Common Name: 3) DOT # (optional) Chea~ical Name: AHM [ ] CAS 4) Physical & Health PHYSICAL HEALTH Hazard Cat~$orie..s Fir~ [ ] Reactiv~ [ ] Sudd(m Rel~a~ ofPr~ssu~ [ ] Imm(Miat~ Health (Acura) [ ] l~lay~d Health (Chronic) s) WASTE CLASsn~c^TION O-digit c(z~ fi-om DHS Form a022) USE CODE 6) Ph'YSICAL STATE Sold { ] Liquid [ I C-~ [ ] Pu~ [ ] Mixtu~ [ ] Wa.~ [ ] Radioa~ive [ ] 7) AMOUNT AND TIME AT FAClLrrY UN1TS OF MEASURE g) STORAGE CODES Maximum Daily Amount .. Lbs [ ] C-al [ ] 1t3 [ ] a) Contains. Average Daily Amomt Annual Amoum c) T(m~a~atur~ Larg(m Sm Contaitm' # Days on Site ... Circle Which Montl~ All Year, $, F, M, A, M, $, $, A, $, O, N, D 9) MIX'Il.IRE: List COMPONENT CAS# % WT AHM the ~ mo~t hazardous 1) [ chemical componmta or 2) .... [ any AHM compon(~ts 3) [ 10)LOCATION I)INVENTORYSTATU$:Ncw[ ]Addition[ ]Revision[ ]Deletion[ ] Ch~ckifchemic~iaaNONTra~[ ]Trad~[ 2) Common Nm: 3) DOT # (optiom~l) Chemical Name: AHM [ ] CAS # 4) Physical & H(mlth PHYSICAL HEALTH HazardCat~ori~ F~[ ]Reactive[ ]Sudd~R~lea.~or~[ ] ~mn~Uat~H~th(^cut~){ ]De~ay~H(~th(C~uic)[ s) wASTE ct.~ss~c^Tio~ (3-,li$it r. ea~ fi,~ Dm Fora a022) USE CODE 6) PHYSXCAL STATE So,id[ I Liquid [ I C-~ [ ] Pu~ [ ] Mixtm [ I W~r,: [ ] P.~lioaCd~,e [ ] 7) AMOUNT AND TIME AT FACILITY UNITS OF IVIEASURE g) STORAGE CODES Maximum Daily Amount Lbs [ ] C~ [ ] ~ [ ] a) Contaium Ay(wage Daily Amotmt Curi~$ [ ] b) Annual Amotmt c) T(:mporatun: Larger Sm Contaixtor # Days on Site Circle Which Months: All Year, J, F, M, A, M, .r, $, A, $, O, N, D 9) MIXTURE: List COMPONENT CA,S# % WT AHM the thr~ moat hazardous i) [ ] chemical compon~nta or 2) [ any AHM compon~U 3) [ ] 10 )LOCATION t c,:rtiCy u~d~r p(malty orlaw, that ! have [mraona]ly c, xamin(xi and am familiar with tha information on this and ~11 ~ttae, h~ documents. I believe the $ubmitt~ inform-,tion is true., ~e, curat~ and complete. PRINT Name & Title of ^uthoriz~(i Compony Repre$(mtative Signatu~ Date H~ZA~DOUS MATERIALS U~I'VENTORY Page of__, Business Name Addruss CI~MICAL DESCRIPTION I ) I~fVE~OR¥ STATUS~ New [ ] Addition [ ] Revision [ ] Deletion [ ] Check ifchemicai is a NON Trade Secret [ ] Trade Soer~ [ 2) Common Name: 3) DOT # (optional) Chenucai Name: AH~ [ ] CAS # 4) Physical & Health PHYSICAL HF. ALTH HazardCategorie~ Fire[ ]Reactive[ ]S,~Relea.~of~[ ] lmm,~liateHealth(Acute)[ ]DelayedHeaith(Chronic)[ ] 5) WASTE CLASSIFICATION (3-diait code fi-om DHS Form 8022) USE CODE 6) PHYSICAL STATE Solld[ ] Liquid[ ] Gas[ ] Puli ] Mixture[ ] Waste[ ] Radioactive[ ] 7) AlVIOUNT AND TIME AT FACILITY UNITS OF MEASURE 8) STORAGE CODES Maximum Daily Amouat LI~ [ ] Gal [ ] f~ [ ] a) Contamec. Average Daily Amount Curies [ ] b) Pressure: Anaual Amount ¢) T~ Largest Size Contaiaer # Days on Sit~ Civic Which Months: All Year, $, F, M~ A, ~ $, $, A, S, O, N, D 9) ~XTURE: List COMPO~ CAS# % WT AHM the three most hazardo~ 1) [ chemical components or 2) [ ] any AHM components 3) 10)LOCATION 1)IiqVE2qTORYSTATU$:New[ ]Addition[ ]R,~vision[ ]Deletion[ ] Check ifchemical is a NON Trade Secret [ ]Tradesoo'et[ 2) Common Name: 3) DOT # (optional) Cheafical Name: AHM [ ] CAS # 4) Physical & Health PHYSICAL HFALTH Ha,srdCategories Fire[ ]R~,'tive[ ]S~_a,Se~_ Relea~of~[ ] lmm,.diateHealth(Acute)[ ]DelayedHealth(Chroni¢)[ ] 5) WASTE CLASSIFICATION (3-digit cod~ from Dm Form 8022) USE CODE 6) PHYSICAL STATE Solidi { Liquid[ ] Gas[ ] Put~[ { I~[ ] Waste[ ] Radioactive[ ] 7) AMOUNT AND TIME AT FACILITY UNITS OF MEASURE 8) STORAGE CODES Iviaximum Daily Amount Lb~ [ ] C-al [ ] fi3 [ ] a) Coutainer: Average Daily Amount Curies [ ] b) Pressu~: Annual Amount ¢) Temperatu~ Largest Size Container # Days on Sit~ Circle V~Ch Months: All Year, ~, F, M, A, IV{, $, $, A, S, O, N, D 9) lVi~: List COMI~NENT CAS# % Wf AI-IM the three most t,,,~'-',_,xious 1) [ . chemical components or 2), [ ] any AHM components 3) [ 10)LOCATION [ certify under penalty of law, that I have personally examined and am familiar with the information on this and all attached documents. I believe the submitted information is true, accurate and complete. PRINT Name & Title of Authorized Company Representative Signature Date SITE DIAGRAM ! ! FACIIATY DIAGRAM Business Name: Business Address: Hazardous Materials Management Plan (Contingency Plan -- Part 1) SHORT FORM Please fill in the following information and return to June Obrochta at the General Office BUSINESS NAME: LONGS DRUG STORE Street Address Z~O0, City/State/Zip ~R~~e{d EPA NUMBER: ~O~ I~Ol~ Bus~.~ss P.o.~: Mai..,o.~ ( 80~ ) PERSONS Application: June Obrochta RESPONSIBLE (510) 210-6932 FOR: Business: Manager ~I~L~C~(~ Property: Longs Drug Stores California, Inc. (510) 937-1170 List property owner if not Longs Drugs: Company Name: Phone: PERSONS RESPONSIBLE FOR AFTER-HouRS Store Manager 2. John mend(ola ~smtant Manager Photo Lab Supe~sor O~er 5. Chemtrec Chemical Hotline ............ (800) 424-9300 PRIMARY BUSINESS: Retail chain drug store which operates a 1-hour photo lab. Store Employees: Total Full-Time ~ Total Part-Time 2.,O Total Employees '~6 Number of Shifts: 6 Store Hours: Monday-Friday ~ ;(~0 RIr~ - lO: (~) prY~ Saturday -~ :(~ ~ITI- q:O0 prY~ Sunday R :i~t~FFI- ~::~ :(~ pm NEAREST HOSPITAL: Name ~X/~'-CL/ ~_.~(~JchI, OC,..~ ~ -~ Street Address 4~ Old P-,i vcr- P-,d City/State/Zip r'~3..~-~-~l~ , C.~{Tr Phone ((~0~) (.O(D~- (PO0~) SIC: 59-12 COMPLETED BY: KI~ ~i~____.J~ Pdnt name Photo L~Lb Su~SYvisOE~, Pdnt title Signature U ~ -- Date: ~J'OV. I z:¥'t I g~q~ w~x::hmmp-stx.ffl'n (12/04/96) Store Number/Address: Longs Drug Store EPA Number: ~..Jq C 0001-/~ Phone Number: ( ~00 STORE POSITION NAME HOME PHONE NO. Store Manager ............ ~~ HA~Tg~ Assistant Store Manager ..... John Chemtrec Chemical Hotline.,. 1 (800) 424-9300 \ Chemical Manufacturer ...... FUJI '1 (800) 326-0800 Police Department ......... 911 or ('~'0~'~._~)~_~-Till Fire Department ........... 911 or(~(]~} ~)2--L~ Paramedics ' 911 o,("~b~5 .~ 32.-I - q-tll Poison Control Center ...... .~L,~') ,..~-~ .~ Utilities: Gas ........... (~-'~'~ ~.'7~ o~(2~ Electdc ......... ('~'00) -"/q~ - 5(~0 Water .......... ("~'©,-~) ~f~ - Sewer Distdct .... ('~,05) c.~2~ - 311 I Lab Supe~sor ............ K'~i~5 I~.~t%~ Fuji Technical Hotline ....... FUJI 1 (800) 328-0800 .. Regional Coordinator ....... ,l~)i.'T~qOiq,Chi Neighboring Stores ......... Store # ;3q Phone("(:~O,~) Store # r~ Phone("~:::)~2---?---~?-~ LONGS DRUG STORE # General This facility contains chemistry used for the processing of film for the Information general public. All materials are monitored visually on a drily basis. Only compatible materials are kept together. All unopened chemistry is stored separately from consumer and store cleaning products. All opened case items are stored on shelves in secondary containment which is secured to the shelves. We do not use or store any chemistry that is a carcinogen or reproductive toxin. All spent wastes are pre-treated and then discharged to the sewer. We recycle the silver, which is hauled away off site. Our hazardous waste hauler is ECS Refining, 705 Reed Street, Santa Clara, California 95050, Phone: (408) 988-4386; Fax: (408) 988-5154. Emergency · Fire extinguishers Equipment · Absorbents · Collection containers on Site · Gloves · Posted emergency procedures · Emergency spill kit · First aid kits Emergency Chemistry spills are cleaned up using absorbent r~aterials. Paper towels Control Spill are used for small spills; large spills are contained by dikes from a spill kit Clean-up and then cleaned up using absorbent pads and materials. All contaminated materials are disposed of in a non-corrodible container and Procedures labeled. This container is picked up by our hazardous waste hauler. If any spill would create a hazard, the Emergency Coordinator would call 911 and summon emergency response personnel. Each Photo Lab has emergency response numbers posted in their lab. The Material Safety Data Sheets for all chemistry used in the lab are located in the lab. Employee All photo lab employees are trained in the safe handling of chemistry and Training for emergency response. Employees are required to view a video which covers handling hazardous materials/waste, Material Safety Data Sheets, etc. They are instructed in a classroom setting and must complete a multiple choice questionnaire upon completion of the training program. Refresher training is conducted annually. All employees undertaking the training program must sign off when they have completed the class. Written procedures are provided to all participants, including management. Employees are instructed in the use of safety equipment in the event of an emergency and shown where the equipment is located. Lab Supervisors and Technicians undergo additional training at Longs' Photo Lab Training Center in Concord, California. Records are kept in the employee's store personnel file. ~lx::hmml~af.rnem (12~)5,'96) If a store evacuation is necessary, it is important that you are prepared and know how to respond quickly and efficiently. NOTIFICATION OF AN EVACUATION You may be notified of an evacuation by: · An announcement over the store intercom · A verbal message from a member of management or a co-worker WHEN YOU HEAR AN ANNOUNCEMENT · STOP what you are doing · LISTEN to any-specific instructions · FOLLOW the instructions · VACATE the building in a calm and orderly manner Remember that while you know where the exits are, customers may not. Therefore, direct customers to the exits. DOORS The front doors marked "IN" to the outside when This is feature. Push pushed. open a safety all doors open. ASSIGNMENTS First Cashier · Go to the "IN" door by the Photo Department · Push the door out · Stand outside the door and hold it open, standing to the side Second Cashier · Go to the "OUT" door by the R~ · Push the automatic rocker switch to "Hold Open" · Stand outside the door · If the "Hold Open" does not function, push the door open and hold it open, standing to the side First COsmetics · Go to the "OUT" door by the Cosmetics Department and Cashier follow the same procedure as the Second Cashier {OVER) EMERGENCY EVACUATION PLAN SITE SPECIFIC FOR STORE # L/I-/ 1. Complete the floor map and site diagram. 2. Make sure that all employees know: a. Where emergency exits are located b. How to operate the exit safety features on store entrance doors c. Where the fire extinguishers are located It is important that all newly hired employees are made aware of this information. 3. Identify the designated meeting place where employees are to meet in the event of a building evacuation and communicate that information to them, 4. Show employees where the emergency evacuation map is posted. A copy should be posted in the lunchroom. 5. Review the evacuation plan annually. WHAT TO DO IF AN EVACUATION IS NECESSARY 1. A manager should make the following announcement on the store intercom: ",4 TTENTION! PLEASE EVACUATE THIS STORE IMMEDIA TEL Y. PLEASE PROCEED TO THE (front of the store or back of the store-the direction A WA Y from the disaster) .... . PLEASE LEA VE ALL PURCHASES, STAY CALM, AND IMMEDIA TEL Y EVA CUA TE THIS STORE." Repeat the evacuation announcement as many times as safety will permit. Post this announcement near the intercom at checkstand #1. (See attached copy.) 2. A manager should go to checkstand #1 and take the daily schedule. At the designated meeting place, roll call should be taken to ensure that all employees have safely left the store. Second Cosmetics · Go to the En'.~,~er~rE'xlt by s~ Cashier · Open the '~'~" door . · Hold the dolSi' open, standing to the side Receiving · Open the receiving door · Hold it open Pharmacy · Exit to the front of the store · Pharmacy personnel should take different aisles when exiting and direct customers to accompany them as they exit Office and · Exit through the receiving door if possibleu~ Mezzanine · If it is closed, exit through the sll~mf~e-w'~Texit · Office personnel should direct customers to accompany them as they exit All Other · Exit using the closest door, directing customers to Personnel accompany them as they exit MEETING PLACE DO NOT LEAVE WITHOUT TELLING A MANAGER · A fire, earthquake, or collapse of the structure may disable the store intercom system. Announcements need to be made in a LOUD voice throughout the store so all employees and customers may exit safely. · First aid may be necessary. Remember, SURVEY THE SCENE to ensure it is safe to enter before determining if first aid is needed. · You and your employees know where the exits are located; however, customers need to be escorted safely from the store. In a power outage, have customers remain where they are until they can be safely escorted out. · Attached is your site specific evacuation plan for your store. Make sure you review it with all employees.