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Home My WebLink AboutBUSINESS PLAN 6/14/19991 DATE: ~./oz/~ FACILITY N~E:. 8~$ ~[~]~ ~aa~+ p[~+ O~IT :: loft CHECK ONE) SITE DIAGR.~[ v/ FACILITY DIAGP~ MAINT. SUP, ~OOM MAIN~ .1 CATWALK ~ (Inspector s Comments : -OFFICIAL USE ONLY- Gist-brocades Food Ingredients, Inc. Business Plan L-J' BIOTECHNOLOGY CONTRIBUTING TO FOOD, HEALTH AND THE ENVIRONMENT June 14, 1991 Mr. Ralph Huey Bakersfield City Fire Department Hazardous Material Division 2130 G Street Bakersfield, Ca. 93301 Dear Mr. Huey: Enclosed is our updated Business Plan for Gist-brocades Food Ingredients, Inc. If you have any questions or need further information please contact me. Sincerely, Maintenance Engineer /cs Enclosures Gist-brocades Food Ingredients Inc. 5455 District Blvd. Bakersfield, CA 93313 (805) 834-1050 Fax (805) 834-6212 ~' ~" "'" CiTY of ~,,,.,-- .. , · -..~ ..,.,,. -"~-'i .. _.~:.~....~. .,,..~ ..~/ ~""~.'-. JUU 1 ? 1991 Do .:~.:_:b, c=r:_~, that I ha',-~ ~vie~,'ed the attached Hazardous Ha~erials business ~lan Gist-brocades Food Ingredients, Inc. for theme of business l and that it alone with the attached additions c,r correc~ions~ constitute _o com~le~:u~ and co~ect__ Business Plan for my facility S~snanur aa~e HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE FORM 2A ':[NSTRUCT I,ONS: l.. To avoid further action, return this from within ~0 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINE$~ ~DENTIFICATION QATA .. A. BUSINESS N~E: GIST-BROCADES FOOD INGREDIENTS, INC. 5455 DISTRICT BOULEVARD B. LOCATION / STREET ADDRESS: CITY: BAKERSFIELD CA. z~P: 9331~ Bus. PHONE: (805) 834-~050 SECTION 2: E~ERGENCY NOTIFICATIONS In case of an emergency involving (he release or (hr. ea~ened.rele~se of a hazardous me.~eriat, ca!.1 91! and 1-8~-85Z-?~5~ or ~-~16-427-434l. This will no(.ify youm !oc~! fire dep~m(men~ and (he S~a~e Offic~ o¢ Emergency 5_r/tc._ as required by EMPLOYEE~ TO NOTIFY IN C~SE OF EMERGENCY: NAME ~NO TITLE OURIN6 9US HRS. AFTER BUS. HRS. (805) 834-1050 (805) 664-0248 ~. Robert Deedy, Plant Manager PH~ PHC 8. Lloyd Fry, Plant Engineer PH~ (805') 834-1050 PH~ (805) 833-8764 PAGER: 32g-2617 SECTION ~: LOCATION OF ~T~LITY SHuT-OFFS FOR BUSINESS AS ~ ~HOLE "N~" corner of pla. nt between driveway and block wall B. ELECTRIC&L: Main power room, above process; "~'~" wall c. bitTER: Cit7 ~,~ater valve "W" end of bui~dinq, between buildino and water tank O. SPEC!~L: ,,N ' ~'5%/ NO 'iF YES LOC~TION~ On fence - ~E." corner at main entrance E. LOCK 8OX: L:--~' , FLOOR PL:qhlS? ~_ .' NO KE'/~? '(E~ 8AKERSFtErD CITY FiRE OEPART. I~.,T 2.l~0 ~G' STREET BAKERSFIELD, CA 93301 ID~ BUSINESS ' '~ BUSINESS PLAN SINGLE FACILITY UNIT INS~UCTIONS ....... I... 7o avoid further action,, this form must be rgturned 2. ~"~=~:.~..~,,..'°~rXT YOUR ANS~ERS IN ENGLISH. 3 anz~.~er Eke questions beio~,' f-or r=E FACILITY UXrT LISTED 4. Be as SRZEF and ~. r-- as ible Co~C~oa ~oss . FACILI~ ~IT: FACILI~ ~IT N~: G~st-brocades Food Ingredients, Inc. SECTION' I: ~ITIGAT!ON', PR~IO~'. ABA~}~E>~ PROCEDB~ES We have an Environmental Incident Plan available upon request. SEC*ION '7: NOT!FTCATiON .*;~D -~' ' ~' ' .._. ..... . '" a,ACUA, zON PEOCEDL.'RES AT THIS L~iT nrr.v NOTIFICATION: Please note attached Internal ~nd External Reporting Charts. m~s[t~[ss ,nMg: Gist-brocades Food lng. om, Ea HAME: G:i. st-brocades Food Ingredients ,~Ma or r~ FACILITY: COC~T~O,: 5455-District gird. AOm~ESS: 5~5' District ~vd. Sr~*,O~nO ~,O. CC~SS COO~ ~r~ ro ~s~ucr~oxs ro~ 'wov~ co~s ' ~1 fl~a}th O~ Pr~ssur, H~lth ............................................ ,, aobert Fo ~ee~x, ............ plant ~?X 664-0248 ,; 'LloTd Fr~ ~ainrenance Engineer a33-8767 ~ CIT'} of' I3/11(£I $t-1f2LD ~usi.~ss .~.t:gist-b'rocades Food Ing. o.~zn ua~g: Gist-brocades Food Ingredients tornados: ,5~5~ District Blvd. ~oo~zss: 5~5-District Blvd. crrY. zre:~i~ld ~A g~lq~P]gR cr~v. zrP:~a~~~~?12~ , DU" ~.O na~osrn~r uu~n . n~n ro x~s~ucrxo~s ro~ enoe~ coo~ (~e ~ C~z ~t , ~t Est Units ~ Sit* ly~ Pr~ 1~ C~e .. St~ ~n Eacllity Nt ~ In~t~tl~J .. v Health o~ Pr~s~ur~ ~lth .... H~alth el Pres~vr~ N,* Ith " ...... , ~,~,~t,c, c~,,c,s ,, Robert F. Deedff, Plant ~anager 664-0248 ,,~?.Y_O_2zZ._.~in<~nce ~e= ................ ~3y&tG& ..... ~ · ...... ~ .... Pager ~ 329-261T _ CI7-)' of B/II( FJ St:Jt2'£D t,,,~,, ........ _,~.Gist-brocades Food Ing. ~ ............ -,~; Gist-brocades Food Ingredients zocaT~os: 5~5~' District Blvd ' ADDRESS: 5~55 Pistffict Blvd. STANDARD IND.]~SS CO~E Health o~ Pr,s~ur ~ ~,~c~c~c~s ~ ~obe~t F. Deed~ Plant Hanage~ 664-0248 ' 833-876 C~r(l[ic~tt~ (~e~d and sJ~u after co~pJ~(J~{ ali ~, ,y ~ Y . : CITY oJ' B/iKHt $trlHLD sus~,~ss ,A~:Gist-brocades Food Ing. ou~ n~. ~ist-brocades Food Ingredients ~oc~o~: 545~District Slvd. a~s~:"~55"Distriht'Blvd s~onn~ ~,~.~is~o~ . r,oN~ ,: (UUDJ-SD~ilgDU r,o~ ,:(gO%) RqA-l~O J ...... - - ~ ro z~s~crro~ ro~ ~oP~ co~s Physical ~n~ H~lth Halzr~ C.A.~. ~ C~ It N~ ~ C.X.S. ~r r--~ ~ ' · r--~ r--~ ~t 1~ ~ ~ C.~.S. ~ .I .... ....... {C~ck ~11 t~t apply) *'~ ..... ~ ~l~- ~/ ...... : ' (C~k all t~t apply)/ -- ~ " ~'~'~ FIr~ ~z~rd ~ Re,ct . ' Hea}th of Pr ~ssvre Health ]' ..... ~ic~l N ~.lth ~rd C.X.S. ~r ........................ C~mt Il ~ ~ C.A.S. ~ / ' ~ Fir, ~.z.rd ~_. ~t.ctivlty ~_. ~1,~ [--~ ~dd~ R,I,,,, ~_. I~1,~, .__ ........................................... Heslth of Prrssurt H~ahh .............. C~ I~ ~ I C.~.S. ,~,o~c, c~,,c~s ,,' ROber~ F. Oeedy.' plant ~anager '664-0248 ,~ ._¢.}~j__FX~.~_~ten~ce. Ene~z . .833-876~ ........ ~ ~i~': ............................... ;~ .................. nm~ ....... ~,~ C~rtllicatl~ (Rend and sJ~n mftcr comi~Jtt(Jl;E ali -,o. obtiRobert, i.~ t~F.inl~-,~.Deedy,I ~,i..,Plant,~, Managert~ ,u~St,,d i.~...,,m is ~r~,. ,cc,,,,..~d c~/~~_.2 / ~ ./ . ~;~fi~1~a~i~6~a~;;[6;~ii~ii;~[~;~ S~''~' ................. --~-" ....................... Oili'S1 ................... / CITY of BAKERSFI£LJ) ~.s~'~ss u~:Cisc-brocades Food ~ng. ouN~a u~a~: Gist-brocades Food ~ngredien~s .~ ov z~ r~czuzzY~': noc~o.: 5455'"'District BI'vd. Aooaass:~ 5455' DiStrici' 'Blvd. STANDARO IND. GLASS CODE CITY. ZIP:~f~m]fl CA Q~q]q-9]gq CITY, ZIP: RmP~refS~]d, ~A O~q]%-912% DUN AND BRADSTREgT ~ ~ ro x~s~vcrxo~ ~0~ v~ov~ co~s ~e t C~e ~t . ~t [st Units ~ Slta ly~ Pr~ [~ C~e St~ In Facility ~t . ~e~ }~h ~1 Pr~su~ ~i~ [~?~ ],,,*% [~ ~1~-~[,~, I~ i.,_~' ~"~:"~'~"'~"+~'~'+' ' H~l }th ut Pr~ure H~ P~ic.I ~ He~T~h Hatavd C./.5. ~r C~t II X~ L C.A.S. ~ '~i- ~'y,'~¢~ C~t I1 X~ ~ C.I.S. ~r ': .,.o,.c, cm,,c,S ;; RObert F. Deedz, Plant Manager 664-024S ".~ ........................ :--m,, .................... ~ .................................... nn{ ..................... u-R~-P~{ ........ Certlflcati~ (Rend and sJKn after col'pieCing al] secilons] Robert Fo Deeds. Plant Manager ~~~_~.~ ];~'~]'61{iEl~l-llil2-M'~e2)55~F~[aF'O~'~2/ou~2[a~'~-;O[~][~-F~6~{{[i;[ Sl~2 .................... . O{~-- ...................... susr~ss ~:Gist-brocades Food Ing. o~a s~ss: Gist-brocades Food Ingredients .n.~ or T~5 F~crc~rY~ : ,. coc~r~o~: 545~'~istrict glSd ..... ~DDa[SS: 5455 District B19d' ~ TO IMS~UCTIO~ FOR ................................ ~ ..... ~ .... ~ .... ~__."--..~_ , ~ ~_~.._~ .... ~.~_.~. · . ~ --J Fire Ha~ard ~--d R~ac:lvlty Nee Ith o~ Pr.sur~ H~ Ith HealTh ol Pr~ssurt H~alth t . e y, Plant Manager ~E'. ' ,,u.,iE4~Z~ ........... : ......... ' m~s~.~ss .~:Gist-brocades Food Ing. ou~ ;~: Gist-brocades Food Ingredients tOC~T~O~: 545~District gl~d. a~a~ss: 5455-District Blvd. CitY. ZIP:~i~lH ~A Q~]~-217~ CITY, zlP:~ker~' ~A QRR1R-212% DUN AHD BRADSTREET ~r~ To I~sr~ucrIo~ FOR PROP~ COPg~ L~e t C~e ~t ~t [St Unit~ ~ Site [y~ Pr~ I~ C~e St~ In f*cllity WT ~ Inst~tt~l · .. ~ ' He~hh ol Health al Pceslvre Health ' . Ne~lth ol ~?~ssurl H,~l(h ......... ' ....................... ,~,o~,c, c,,,c,s ,,,;a~Qb_er_t..F..._~ee_dy_,..R]_o~,[4~oger ........ 664-0248 ,, LZozd Fr~. ~in~a2ce .RnoSneez 833-8765. ...... C,rtlflc*tl~ (Rend and si~t~ nftcr co~pl~f/n~ nil scc(lon.~/ / : CIT~~ of/2/1KHi~Si:ltELD ,a~.Gist-brocades Food lng. u.,,,,, ,,~:~.Gist-brocades Food Ingredients NAME OF T~ F~C.~LI~' ' $45~ District Blvd. ADO~tESS: 5~55 District Blvd. STANDARD IND. ~SS CODE ~ ro r~s~cr~o~s ro~ ~o~ co~s ~ ~ ~ ~_ ~,"~,~ .. . r--~ ' ' : r--~ r--~ ' --~ r r--~ C~t Il ~ ~ C.A.S. ~ ~ " Health of 'Robert F. Dee~ Plant Manager 664-0248 ,~ Llozd Fr~ Ma%n~e~nne ~i~ar 833-8~64 ........ : :Gist-brocades Food Ing. Gist-brocades Food Ingredients ~a.~ or T~g r~c~zrT~' ; ' zOC~T~O.: 5455 D~strict Blvd' ~ooasss: 5~ District Blvd. STA~D&nO I,O.~SS CODE ~.l~.l...~J ...... L_.~ .... :I.~_~__~ .... '~ '~ ~ '""~y) I~- 37-~ ---~ .............................. r-- ~ ' ; r--~ r--~ / ~r~,,.,~a ~ ]~.,ct~ty ~ .~,~ ~_, ~a~,~ .... ~-~ ~,~, ~ ............ '. Health o~ Pr, ~ur ~ a ~lre Ha~4rd ~ a Re~ccSv~ty ~ -- - .... - ..... I ' -- ~ Fire Ri/4rd ~ a Reactlvlt~ ~ a ~1,~ [ ~..,,~ o, .., .... :~4~L~ ~, ,, ~, c.,.s. ~~%4'~ T~', ,,~oq d~q.L,~~,, ~,~ ' ..... l ...... t .... : .... ,j_:.__'__[ ...... ~ ............ J ...... , ......... t ..... l ...... l ..... l ...... t. __ P~ical ~ H~elth ~,llrd C.A.S. ~r ........................ , ~ ~,. ,,,,~ [ ] ~,,,ti,~,r [ ] ~.~ [ ] ~a~ ~,~ .... '--" I~l,t, . .............. ~ ............................................ B¢~llh of Przssur~ B,Ith ~,~c~c~,~c~s ,. Robert E. Deed~ plant ~nagep .664-0248 .Llozd Fr~, Maintenance Engineer 833-87~J ...... .............................. ,.,,- .................. ..~,-.~, ........ ,,. ............................... ,,., -:--~-;~--;~-~_ ~-~, C~rtllic~ti~ (R~d and sj~n a(~CF CO.pJ~TfJ.E Ct7-')' ~)./' IJ/ll(tSi~Si:'It2'LD ~us~:~ss ,~.~:6isZ-brocades Food IH8. o,,z~ ,~: CisL-brocad~s Food ~.OC~T~O.: 545~-i~trict 1~. ~.On~SS: 5~istr:i. ct ~vd. t~e ~ C~ ~t ~t [SI Uni~l ~ SII~ ly~ Pr,,~ I~ C~, .. St~ In f,cillt~ fit ~ Instr~tlm~ · ,,,~, ,~, ,~, ,,,,, ~ ~ - 5 ?-~ '-=~-~-'-~'~ .... '"~'"~"-~'~- .............. C.l.5.~ ........................ C~t II ~ L C,I.S, (C~k ~ll t~t ,pply) ..... ... [-] ~,'-~ ~-~ _ ~.~.c~ c~-c[s ,~Ohert [. De~, ~]ant Mano~er 664'0248 ,; Lloyd Frx, Maintenance ~ngi~er 833-8764 ...... CITY o./' 13?iK£1 $'I:71ZLD ~us~,~ss ,~:Gist-brocades Food lng. ou,~ ua~: Gist-brocades Food Ingredients ,a~ o~ ~ FRCILITY~ : LOCaZ~ON: 545~District Blvd. ' '" ~oO,~ss: ~istrJ. ct Blvd. C~TY. Z[P:~~F~id .CA qRR1R-?193 crTY. zrm:~a~~' CA q3313-?]2~ OU~ AHD BRADSTREET ~xr~ ro z~sr~vcr~o~s ro~ ~oP~ coo~ .~.~,~c, c~,,c,s ,, Robert F. ~e~dy, ~lant Manager ' 664-0248 "Lloxd ~z, ~ain:enanne .Enoin~r 833-8764 ...... ~ ............... ' ~a~er ~3.2~-2617 CIY-'}' of 1~/1 l{£'-R57~ILL'£L) ~r~ ro ~srnucr~o~s ro~ rRo~ CO~ '-T ~,,,, ,~, ,,,.,,~ ~ .... , ~.,.,. ~ ~, ,, ~_, ~.~.,. ~ E~t~ ,/ ~'~'~ '~ ¢~' ""'~'~ ......................... *~76 -% - ~ ~l .... ~)o~ ........... H~, Ith of Pr,,,u¢, ~-~ Jc~ ,~l ~ ,~) ....................... ~95 - z~ -D t ~d~nq .......... Hf~Jth O[ Pr,~lur~ H,~ {th ' - ' ,~.~c~c~,~c,s ,, Robert.~, Deedy, ~]_~0t Manager 66¢7~02~8 ....... ';~ay~_~ny_,_.~ia~ance R~oine~ 83%8764 ' , ......... . - t~, r " ; ~' ya~er ~329-2617 ~;~ ....... {~ ............ r ri, ~tP . - .... ~ .......... ~l-~r-?~{ ........ R;;;'iA2~T;l~llli'~T~F/nn~41~ ') ~,tOoD ~ t' ~ ,,;a';;G~HJdHl~; S;6A ....................... OH ...................... i.' ~FE/FACI LI TY D G RTlb~ .: NORTH SCALE: BUSINESS NAME: Gist-brocades Food FLOOR: 1 .OF 2 Ingredients, Inc. DAIE: 6/7 /91 FACILITY NAME: Bakersfield Yeast Plant UNIT #:1 OF 1 (CHECK'ONE) SITE DIAGRAM FACILITY DIAGRAM X Inspector's Comments): -OFFICIAL USE ONLY- ........, .--. ,XORTg.:. SCALE: I":40' B~$~h'ESS ~'~XE: Gist-brocades Food Ingredients Inc. OATE: 6/ ~'/ 88f'A~r~[~ 'Y~E':~Sakersfield Yeast Plant' · ..-:"' (CEECK ONE) SITE DrAG~ X ~AC~L~ DrAG~ ~ . · i'~) ~! %, lerm~nter Pro~"~oric ~c{~ ~'ll~ Tank C0ntel ~ h ~ ........ ~,~,, ........... , ........ , ADV~CB BBVE~QB~ N BUS~-BU~H) ~. so~d 631-2355 ~7~ ~ ,. .......... ~.. =,...,~'~,~.~ ...... , ........ D~T ~. ., .. ~ 83&1050 ~nCl{ BLanC 5BRVIC~ 2. or, s .... PB~O~ ~TOLm ~~) ~t. >,__, 831'-6500 ~ ~ ) } ' 5 i ' ; ~-- ~ N L BARO~ c. Oue~ 2 Vacant Bldg ~[~ ~ ~B~ PACIFIC ~ANS~RTA~ON ~MP~y 321-4603 ~ ~T [~ 5~55 District B1 i~%~brOcades. 8AKERSFI~LD,j__._~CA I ~ x / .~ 5455 District Blvd. ' ' ' -~ ~'1'=15' J ...... o D ~ '-_-' '~-~ .... ~, ,-- MOLASSES PIT TANK ~S PIT TANK 5455 District Blvd. k/1OL~S PIT BdxEI~SFIELD YEAST PL~T ACUTELY HAZ OUS MATERIALS REGI ATION FORM THIS FORM MUST BE COMPLETED BY THE OWNER OR OPERATOR OF EACH BUSINESS IN CALIFORNIA WHICH AT ANY TIME HANDLES ANY ACUTELY HAZARDOUS MATERIAL IN QUANTITIES GREATER THAN 500 POUNDS, 55 GALLONS OR 200 CUBIC FEET OF GAS AT · 'STP. 1 THIS FORM SHALL BE COMPLETED AND SUBMIITED TO YOUR LOCAL ADMINISTERING AGENCY. (§25533 & 25536 Health & Safety Code) Note instructions on r~v~r~ Business Name GIST-BROCADES FOOD INGREDIENTS INC. (BAKERSFIELD YEAST PLANT) 5455 DISTRICT BLVD., BAKERSFIELD, CALIFORNIA 93313 Business Site Address N/A Business Mailing Address (if different) Business Phone (80~) 834-1050 Business Plan Submission Date2 July 3, 1987 Process Designation3 .. N/A ACUTELY HAZARDOUS MATERIALS HANDLED4 -USE ADDITIONAL PAGES IF NECESSARY- CHEMICAL NAME Q UANTFi'Y CHLORINE (GAS IN 2,000 LBS. PRESSURIZED CYLINDER'S) 4,000 LBS. SULFURIC ACID (77-99 WT% WITH HATER) 700 GALLONS GENERAL DESCRIPTION OF PROCESSES AND PRINCIPAL EQUIPMENTS: CHLORINE: USED FOR DESTRUCTION OFALL NEGATIVE- STATE ORGANISMS IN. COOLING TOWER AND WELL WATER. SULFURIC ACID: USED FOR PH CONTROL IN FERMENTERS. sIGNATURE --~ ~ TITLE MAINTENANCE ENGINEER ! California Offic~ o~ Emergency S~vic~s FORM H~ ~7177 I "sPzLL" ¥ Superviser 1, C. Walker 398-7220 2, C. Winger 397-0833 V D. Ensey '<- L. Fry Home 664-1124 Home 833-8764 II/I Home 398-7220 Pager 329-4946 Pager 329-2617 t / Pag~9-1023JI Office 835-8385 ¥ Plant Manager Corporate Management R. Deedy ' >11 J.KEVIN KRAUS Home 884-0248 ~[ Office (215) 272-4040 ~ / Hom~ (201) 568-4473 ¥ Corporate Kemper Insurance H'~o Office (201) 251-6650 Augustin Vega Home (201) 526-6472 (714) 598-3000 ¥ Corporate Lawyer Morgan, Lewis & Bockius 2001 Logan Square Philadelphia, PA. 19103 Ken Heyers (215) 963-5000 /' 4-3-91 EXTER L REPORTING HART Worker "Spill" V h Dan Ensey Office 835-8385 t' Safety Pager 834-2337 " >11 C.Walker Home 329-4946 Pager 329-1023 LLoyd Fr~ Office 834-1050 Home 398-7220 Pager 329-2617 Home 833-8764 Robert. Deedy Office 834-1050 Home 664-0248 I V Hazard Material Division < or Fire/Rescue (805) 326-3979 >11 911 California Office of' EMERGENCY RESPONSE t[ =rom CA. (800) 852-7550 '< as needed Bakersfield Police out of state > (805) 327-7111 (916) 427-4341 Calif, Hwy Patrol (805) 325-5822 Vacuum Truck Service ias needed as needed M.P. Vacuum K.C.A.P.C.D. < >- (805) 393-1151 (805) 861-3682 depending on Kern Vacuum Service type of spill (805) 589-5220 National Response t Center < ' as needed Hazardous Material (800) 852-7550 >- Disposal Company K.E.S. (805) 589-5220 Chemical Waste M.qt. (800) 222-2964 , Waste Control Svc. (805) 399-4620 6-28-90 REPORTING CHART " SPTLL AT R H " I V DAN ENSEY , HONE 664-1124 WORK 835-8385 · PAGER 329-4946 REPAIR CREW AS LLOYD FRY SOUTH VALLEY PUNP NEEDED ") · ) HONE 833-8764 ..... < .... < PAGER 329-2617 WORK 831-3703 " HONE 393-7828 AS ll ....... VACUUM TRUCK NEEDED > >' IIK'C'A'P'C'D' t I861-3682. .., t I BACK HOE WH I'TTEN EXCAVATI'ON AS GARY WHZTTEN NEEDED WORK 834-8002 < < ' NOBTLE 327-3505 ¢8400 PAGE i } 7- 10-90 GIST-BROCADES FOOD INGREDIENTS, INC. PLANT CHEMICAL MATERIAL INVENTORY QUANTITIES CHEMICAL NAME COMMON NAME MAXIMUM TOTAL AMOUNT AT AMOUNT ONE TIME IN YEAR LABORATORY ACETALDEHYDE ETHANOL, ACETIC ALDEHYDE 1 GAL 1 GAL ETHYL ALDEHYDE ACETIC ACID, GLACIAL METHANE CARBOXYLIC ACID EyHANOIC ACID 20 LBS 240 LBS 4-AMINO-S-HYDROXYL 4-AMINIO-$-HYDROXY- 500 GMS 500 GMS AND NAPHTHALENE 1-NAPHTHALENE SULFONIC ACID SULFONIC ACID ACETONE DIMETHYL KETONE; METHYL 1 GAL 1 GAL KETONE; 2-PROPANONE ALCOHOL, REAGENT RCC CAT. NO. 6590 4 GAL 15 GAL AMMONIUM CHLORIDE SAL AMMONIAC 1 K 1 K AMMONIUM MOLYBDATE AMMONIUM PARAMOLYBDATE 500 GMS 100 GMS AMMONIUM SULFATE AMMONIUM HYDROGEN SULFATE SO0 GMS 500 GMS AMMONIUM MONOBASIC- AMMONIUM DIHYDROGEN PHOSPHATE ~ONOBASIC 2 K 2 K PAGE '2 AMMONIUM PHOSPHATE PRIMARY AMMONIUM PHOSPHATE 1500 GMS 3000 GMS MONOBASIC AMMONIUM DIHYDROGEN PHOSPHATE;AMMONIUM BI- PHOSPHATE; PHOSPHORIC ACID, MONOAMMONIUM SALT ANTHRONE ANTHRACENONE 100 GMS- 25 GMS ARABINOSE MCB AX1705 25 GMS iO0 GMS D-(-)-ARABINOSE BENZOIC ACID PHENYL FORMIC ACID 500 GMS 10 LBS BIOTIN PYRROLE THIOPHENE 15 GMS 15 GMS IMIDAZOLE-4-PENTANDIC ACID HEXAHYARO-2-OXO,BIOEPIDERM BORIC ACID BORACIC ACID; ORTHOBORIC ACID; BOROFAX 1000 GMS 3000 GMS BROMOCRESEOL GREEN- RICCA 1220 16 OZ 52 OZ METHYL RED CALCIUM CARBONATE J T BAKER 1-1288 2 LB 5 LB CALCIUM CHLORIDE MCB CX129 50 GMS 50 GMS CALCIUM -D-PANTOTHENATE USP CAL-PAN 500 KG 2400 KG CALCIUM SULFATE LIMESTONE, MARBLE, 1 LB 1 LB CALCITE, CHALK, CARBONIC ACID, CALCIUM SALT CARTRIDGE, CATION 2 2 COBALT CHLORIDE J T BAKER 1670 125 GMS 250 GMS CUPRIC SULFATE BLUE VITRIOL; BLUESTONE lO00 GMS i500 GMS COPPER PAGE ITRIC ACID, MONOHYDRATE TWO HYDROXY-ONE,TWO,THREE 8 LBS 10 LBS PROPANETRICARBOXYLIC ACID COLI-MUG TUBES 1 GAL i GAL' CRYSTAL VIOLET BASIC VIOLET THREE; 25 GMS 10 GMS GENTIAL VIOLET DEXTROSE GLOSOCE, GRAPE,SUGAR,CORN 1000 GMS ~000 GMS SUGAR DODECYL SODIUM SULFATE SODIUM LAURYL SULFATE i LB 1/2 LB 2-ETHANE SULFONIC ACID RESEARCH ORG Ol13M 1 K i0 K (ETHYLENEDINITRILO) ETHYLENEDIAMINETETRACCETIC 500 GMS 500 GMS TETRAACETIC ACID, ACID, OISOOIUM SALT DISOOIUM SALT ETHYL ALCOHOL ALCOHOL 2 QT i GAL ANHYDROUS, DENATURED FERROUS AMMONIUM SULFATE AMMONIUM IRON SULFATE 2 LB 1/2 LB AMMONIUM FERROUS SULFATE, HEXAHYORATE FERRIC AMMONIUM CITRATE CITRIC ACID AMMONIUM I LB 1 LB IRON (5+) SALT AMMONIUM FERRIC CITRATE FERRIC CHLORIDE 100 GMS 100 GMS FERROUS SULFATE IRON VITRIOL 500 GMS 500 GMS HEPTHYARATE D-(-)-FRUCTOSE D-FRUCTOPYRANOSE 500 GMS 2000 GMS GLYCEROL GLYCERINE: ONE, TWO.THREE-PROPANETRIOL HYDROCHLORIC ACID HYDROGEN CHLORIDE 4 GAL 20 GAL HYDROCHLORIDE INOSITOL INOSITOL 100 GMS 100 GMS PAGE IODINE , ~00 GMS 500 GMS ISOPROPYL ALCOHOL 2-PROPANOL,SECPROPYL 2 GAL 6 GAL ALCOHOL LACTIC ACID 2-HYDROX PROPANOIC 52 OZ 52 OZ ACID EHTYLiDEN ELACTIC ACID LACTOSE MILK SUGAR 1 LB 1 LB LEAD ACETATE LEAD DIACETATE 1000 GMS 1000 GMS SUGAR OF LEAD MAGENSIUM CHLORIDE i LB i LB MANGANOUS SULFATE MANGANESE SULFATE 500 GMS 500 GMS MANNITOL,POWDER MAL 2554-1 500 GMS 500 GMS MALTOSE ALDRICH CHEM 100 GMS 100 GMS MERCURIC SULFATE MERCURY BISULFATE 1 LB 1/2 LB MERCURY EMERGENCY ZINC METAL 1 PK 1 PK CLEAN UP SYSTEM SULFURIC ACID O.IN MESO-INOSITOL 5 GMS 100 GMS METHYL ALCOHOL 1 LIT QT 2 LIT QT METHYL RED, NEUTRAL ACID RED 2;TWO- 25 GMS 25 GMS (4-(DIMETHYLAMINO) DIMETHLAMINO) PHENYLAZO) BENZOIC ACID METHYLENE BLUE BASIC BLUE 9 25 GMS 10 GAL MINERAL OIL PARAFFIN OIL; 8 LTR 16 LTR LIQUID PETROLATUM PAGE NALCO SOLUTION S0222 P-INDICATOR, PHENO- 16 OZ 64 OZ LPHTHALEIN SOLUTION IN DENATURED ETHANOL NALCO SOLUTION S0226 SULFURIC ACID i GAL i GAL NALCO SOLUTION S0254 1 GAL 2 GAL NALCO SOLUTION S0245 1 GAL 1 GAL NALCO SOLUTION S0250 ..... 1 _GAL 1 GAL NALCO SOLUTION S0274 1 GAL 1 GAL NALCO SOLUTION S0275 1 GAL 1 GAL H-2 TOTAL HARDN NALCO SOLUTION S0277 1 GAL 1 GAL NALCO SOLUTION S0279 I GAL i GAL NALCO SOLUTION S0280 1 GAL 1 GAL NALCO SOLUTION SH555 P-1 P-1,AMMOMIUM MOLYBDATE IN 2 LIT 2 LIT AN AQUEOUS SULFURIC ACID SOLUTION NALCO SOLUTION S0515 1 GAL 1 GAL NALCO SOLUTION S0614 1 GAL 1 GAL NALCO SOLUTION S0901-SC1 TEST KIT 2 OZ 16 OZ NALCO SOLUTION S0902-SC2 TEST KIT 2 OZ 15 OZ NALCO SOLUTION S509i t GAL 1 GAL .... ORTHOTOLIDINE/ RICCA 8540 i50Z 52 OZ o-TOLIDINE REAGENT- PAGE PARAFFIN OIL, WHITE 1 L i5 L PENICILLIN-G-SOOIUM PENICILLIAN 1 BTLE 2 BTLE PENICILLIN-STREPTOMYCIN 10 BTLES 24 BTLES PERCHLORIC ACID 500 MLS 1000 MLS 60%, 70~ PHENOL HYDROXYBENXENE 1 PT 1 PT PHENANTHRENE AROMATIC HRDROCARBON 25 GMS 25 GMS PHENOLPHTHALEIN 125 GMS 50 GMS PHOSPHORIC ACID o-PHOSPHORIC ACID 8 GAL 16 GAL PHTHALIC ACID 1,2-BENZENEDICARBOXYLIC 1 ~T 1/2 ~T MONOPOTASSIUM SALT ACID MONOPOTASSIUM SALT POTASSIUM BROMIDE 5 LBS 3 LBS POTASSIUM CHLORIDE POTASSIUM MURIATE 50 GMS 100 GMS POTASSIUM CHROMATE CA~ 7789-00-6 1 LB 1 LB POTASSIUM HYDROXIDE CAUSTIC POTASH 500 GMS 500 GMS POTASSIU~ SULFATE SAL POLYCHRESTUM 2 LB 10 LB POTASSIUM PHOSPHATE POTASSIUM PHOSPHATE 1SO0 GMS 2000 GMS MONOBASIC MONOBASIC POTASSIUM PO4 DIBASIC 500 GMS 500 GMS POTASSIUM IODATE IODIC ACID, 1000 GMS 500 GMS POTASSIUM SLT POTASSIUM OXALATE OXALIC ACID, 1 LB i LB DEPOTASSlUM SALT, PAGE 7 ETHANEDZOIC SALT POTASSIUM PHOSPHATE DIBASIC MAL 7092 1 LB 1 LB DIBASIC POTASSIUM SODIUM TARTRATE ROCHELLE SALT 2.5 K 2.5 K POTASSIUM IODIDE 2 LB 2 LB PROPYLENE GLYCOL DIHYDROXYPROPANE, 1 PT 1/2 GAL PROPANEDIOL PURGE III INSECT KILLER 12 CANS 12 CANS RAFFINOSE GOSSYPSE;MELITOSE; 200 GMS 500 GMS MELITROSE L-RHAMHOSE MC8 RXO070 25 GMS 25 GMS SILVER NITRATE 50 GMS 100 GMS SILVER CHLORIDE 50 GMS 50 GMS SILVER SULFATE 1 LB 1 LB SODIUM ACETATE, ACETIC ACID, 1 LB 1/2 LB ANHYDROUS SODIUM SALT SODIUM BICARBONATE BAKING SODA; SODIUM ACID CARBONATE 2 LB 15 LB SODIUM BISULFITE SODIUM ACID SULFITE 500 GMS 100 GMS SULFUROUS ACID SODIUM CITRATE TRISODIUM CITRATE 500 GMS 500 GMS SODIUM CHLORIDE 5 K 10 K SODIUM GLUCONATE SODIUM 2,5,4,5,6 1000 1000 PENTAHYDROXY-1- HEXANOATE SODIUM HYDROXIDE CAUSTIC SODA 5 GAL 50 GAL 504 SOLUTION SODIUM HYDRATE;LYE PAGE 8 HYDROXIDE, CAUSTIC SODA;LYE 12 K 24 K SOLID SODIUM HYDRATE SODIUM SULFITE 500 GMS 1000 GMS SODIUM SULFATE TRISODIUM SULFATE 1 LB 1 LB ANHYDROUS SULFURIC ACID SODIUM THIOSULFATE S-HYDRATE 1 LB 5 LB SORBITOL GLUCITOL 1 LB 1 LB STREPTOMYCIN ...... 12 BTLES 12 BTLES SULFATE SUCROSE BEET SUGAR, CANE SUGAR 2 K 10 K SODIUM HYDRATE SULFURIC ACID NORMAL,EPA,APHA,ASTM, 8 GAL 16 GAL 96~ AOA, FOR ALKALINITY SULFURIC ACID MINERAL ACID SOLUTIONS 6 GAL 24 GAL DILUTE SOLUTIONS TREHALOSE SPECTRUM T1097 25 GMS 200 GMS TRICHLOROAECTIC ACID TRICHLOROACETIC ACID 10 LB 5 LB 2,3,5-TRIPHENY - HETEROCYCLIC NITROGEN 50 GMS 50 GMS TETRAZOLIUM CHLORIDE THIAMINE HYDROCHLORIDE VITAMIN B, HYDROCHLORIDE 500 GMS 100 GMS ZINC CHLORIDE 500 GMS 500 GMS ZINC SULFATE, 7-HYDRATE WHITE VIRTRIOL ZINC VITRIOL 600 GMS 1000 GMS XYLOSE WOOD SUGAR 25 GMS 25 GMS PAGE 9 PROCESS AIR 255 CU FT 2820 CU FT ACCORD II 150 GA~ 1800 GAL ALCATEL lO0 MECHANICAL PUMP FLUID i2 QTS 5 QTS AMINOSULFURIC ACID; SULFAMIC ACID ......... 5000 LBS 14000 LBS AMINOSULFONIC ACID MONOBROMOTRIFLUOROMETHANE S-[(4-AMINO-2-METHYL-5- HALON 1SO1, FREON FE 1SO1 1141 LBS 1141 LBS PYRIMIDINYL) HYDROXYETHYL)-4-METHYL- THIAZOLIUM CHLORIDE AMMONIUM HYDROXIDE AQUA AMMONIA 576000 LB 4512000 LB NEUTRALIZATION GRADE BIOPAL NR-20 150 GAL i800 GAL IODOPHORS CALCIUM -D-PANTOTHENATE USP CAL-PAN 500 KG 2400 KG CALCIUM HYPOCHLORITE HTH 600 LBS 5000 LBS D-ASPARAGINE MONOHYDRATE 25 GMS 25 GMS CRYSTALLINE ORGANIC DEFOAMER , MAZU DF204 220 GAL 2640 GALS DIAMMONIUM PHOSPHATE, DIAMMONIUM PHOSPHATE DIBASIC DIBASIC;PHOSPHORIC ACID, i25 LBS 1500 LBS ANHYDROUS DIAMMONIUM SALT MAGNESIUM SULFATE, HEPTAHYDRATE EPSOM SALT MAGNESIUM SULFATE, U.S.P. i500 LBS i8000 LBS PAGE lO ~Y MERCURY 5 LBS 5 LBS NIACINAMIDE 100 GMS 100 ~MS ORTHYOPHOSPHORIC ACID, PHOSPHORIC'ACID 4000 GAL' 48000'GAL MONOPHOSPHORIC ACID ORTHO-PHOSPHORIC ACID; WHITE PHOSPHORIC ACID PYRIDOXINE HYDROCHLORIDE 5 GMS 5 GMS SODA ASH SODIUM CARBONATE, 1250 LBS 5000 LBS ANHYDROUS SODIUM HYDROXIDE, CAUSTIC SODA 50~ LIQUID CHELATED LIQUID LYE 4000 GAL 48000 GAL SODIUM 2,3,4,5,6 SODIUM GLUCONATE 1000 LBS lO00 LBS PENTAHYDROXY 1-HEXAMQTE SULFATE OF AMMONIA AMMONIUM SULFATE 150 LBS 18000 LBS SULFURIC SULFURIC ACID 8400 LBS 35250 LBS THIAMINE HCl THIAMINE 186 KG 900 KG MONOHYDROCHLORIDE VITAMIN 81 ZINC SULPHATE METEOR BRAND ZINC MONOHYDRATE SULPHATE 56~ 1666 LBS 20000 LBS PACKAGING AND SHIPPING ALKI-FOAM RHOZYME-H59 5 GAL 20 GAL ENZYME BACTERIAL DIASTASE 150 LBS 150 LBS BLAIR ADHESIVES MODIFIED LATEX EMULSION 125 LBS 1500 LBS PAGE 1 1 BONCHEM MIKRO-FOME CLEANING SOLUTION 12 GAL 144 GAL CALCIUM HYPOCHLORITE HYPOCHLOROUS 1000 LBS 5000 LBS CHLOR-TERGENT 500 LBS 2150 LBS CRYSTALS TRISODIUM PHOSPHATE 2000 LB9 7000 LBS DPDECAHYDRATE, TSP CRYSTALS, TSP CRYSTALLINE FULLER'S EARTH ALL PURPOSE ABSORBENT 150 LBS 1800 LBS (SERICITIC CLAY) H B FU-LLER/HM-5509 THERMOPLASTIC ADHESIVE 250 LBS 5000 LBS HARBORLITE 8190 LBS 174720 LBS HYDRO CLEAN 500 50 GAL 120 GAL MAZER CUTTING OIL 551 PROPRIETARY SURFACTANT 8000 LBS 95000 LBS BLEND, CUTTING OIL MAZER MAZU DF 552 PROPRIETARY SURFACTANT 880 LBS 10550 LBS BLEND MAZU DF 5~0 MOD 2 ORGANIC BASED ANTIFOAM 7200 LBS 85400 LBS PLASTICIZER MAZU CUTTING OIL 550 200 LBS 2400 LBS POTATO STARCH 55000 LBS 700000 LBS QUATERNARY AMMONIUM SANITIZER 400 (BOS 400) 48 GALS 575 GALS SANITIZER THERMOCLEEN ALL PURPOSE CLEANER 1 GAL 4 GAL MAINTENANCE PAGE 12 IVE GRINDING WHEEL PHENOLIC BONDED GRINDING 4 EA 8 EA WHEEL ABRASIVE WHEELS 4 EA 12 EA ACETYLENE ACETYLENE (GAS) 258 CU FT 595 CU FT ACTI-KLEAN 5 GAL 20 GAL , AEROSOL CLEANERS 2X726-A 12 CANS 50 CANS DEGREASING SOLVENT AEROSOL CLEANERS 2W756A PAINT & DECAL 5 CANS 25 CANS REMOVER AEROSOL CLEANERS 4X598-A 12 CANS 40 CANS CONTACT CLEANER AEROSOL CLEANERS 5WO47-PREMIUM 6 CANS 20 CANS AEROSOL COATINGS 4XO42-A HIGH HEAT ALUM 4 CANS 12 CANS AEROSOL COATINGS 2 X 710-A MACHINE GRAY 6 CANS 20 CANS AEROSOL COATINGS 2 X 987B BELT DRESSING 2 CANS 5 CANS AEROSOL LUBRICANTS 2W757 TEFLON DRYLUBE 2 CANS I0 CANS AEROSOL STAINLESS PAINT 2 CANS 2 CANS STEEL COATING ALLOY STEEL-HR&CR ALLOY STEEL i.e. 4150 .75 TONS 5 TONS ALLOY LEADED STEEL 4140,4540,8620 ALLOY LEADED I.E. 86L20 ALUMINUM OXIDE KASCO 4 EA i6 EA GRINDING WHEELS, CUT-OFF WHEELS, AND CUPS ALUMINA ZIRCONIA GRINDING KASCO ABRASIVES 8 EA 52 EA WHEELS, CUT-OFF WHEELS AND CUPS 2-4 INCH ALUMINUM'OXIDE CUT-OFF WHEELS, PAGE LPHUR FREE ALUMINUM OXIDE GRINDING KASCO ABRASIVES 4 EA 16 EA ARGON ARGON (GAS) 672 CU FT i680 CU FT BIODISPERSANT ilO GAL- 550 GAL BRASS HALF HARD,SOFT,SHIM 2 LBS 10 LBS BRONZE 50 LBS 50 LBS pH BUF'FER SOLUTION BUFFER W/ETHYLENE GLYCOL 40Z 40Z CARBON STEEL-HR & cR LEADED CARBON STEEL i.e. AS6, CARBON 1018,1010,1040 PRESSURE VESSEL QUALITY LEADED CARBON I.E. 10L42 50 LBS 100 LBS CEMENTED CARBIDE PROOUCT REFRACTORY METAL CARBIDE 50Z 10 LBS W/COBALT BINDER CEMENTED TUNGSTEN CARBIDE & HIGH SPEED CUTTING TOOLS CHEMGRIP TREATING AGENT LIQUID DISP OF 5 OZ 12 OZ METALLIC SODIUM IN A HIGH-BOILING SOLVENT (DIETHYLENE GLYCOL DIMETHYL ETHER D-14) CHLORINE 2 TON 6 TON COPPER 10 LBS 50 LBS DEPEND NO MIX ADHESIVE 10 OZ 10 OZ DOWFROST (R) HEAT 55 GAL 220 GAL TRANSFER FLUID COVERED ELECTRODE CARBON STEEL CORE WIRE 2 LBS 6 LBS PAGE 14 ERED ELECTRODE E6010 50 LBS 200 LBS COVERED ELECTRODE E6011 50 LBS 200. LBS COVERED ELECTRODE E6015 5 LBS 10 LBS DURABLA COMPRESSED COMPRESSED GASKET MATERIAL 1 LB 5 LB -' GASKET MATERIAL FILLER METAL AND WELDING RODS 20 GAL 20 GAL FLEXITALLIC GASKET ASBESTOS FILLED SPIRAL 2 LB 10 LB WOUND GASKET FORAY DRY CHEMICAL 90 LB 90 LB ESTINGUISHING AGENT K45 FOOD EQUIPMENT FOOD EQUIPMENT LUBE 1 CAN 6 CAN LUBE 00755 FUEL OIL DOMESTIC HEATING OIL 15000 GAL 15000 GAL GASKET REMOVER GASKET REMOVER ~50020 2 CANS 5 CANS TM-1206B HALON i25 CU FT 125 CU FT LINDE TUNGSTEN 1/4 L8 1/4 LG ELECTRODES LUBRICANT (AEROSOL) ALUMINUM TAPPING 4 CANS 15 CANS COMPOUND LUBRIPLATE "HO" SERIES LUBRIPLATE HYDRAULIC'OIL LUBRICATING OIL 100 GALS 500 GALS HO-i, HO-2, HO-5 LUBRIPLATE CHAIN LUBRICATING OIL 5 GALS 15 GALS AND CABLE FLUID LUBRIPLATE "APG" LUBRICATING OIL 5 GALS 5 GALS PAGE 15 LERIES UBRIPLATE APG-90 LUBRIPLATE "FMO" SERIES LUBRICATING OIL 55 GALS 500 GALS LUBRIPLATE FMO-$50 LUBRIPLATE "650" SERIES LUBRICATING GREASE 15 LBS 100 LGS LUBRIPLATE NO,. 650-2 LUBRIPLATE "NUMBERED" SERIES LUBRICATING OIL 55 GALS 110 GALS LUBRIPLATE NO. 4 LUBRIPLATE "SUPER FML" LUBRICATING GREASE 5 LBS 20 LBS SERIES LUBRIPLATE SUPER FML-2 4M POTASSIUM CHLORIDE REF ELECTRODE SOLUTION 2 OZ 2 OZ SOLUTION PLUS GYLCOL MERCURY MERCURY 5 LBS 5 LBS METHYL CYANOACRYLATE/ PERMABOND 910 4 OZ 12 OZ SUPER GLUE MURIATIC ACID 20 DEGREE INORGANIC ACID 55 GALS 275 GALS NT. 595 TAPPING TAPPING COMPOUND 4 CANS 12 CANS Nr. 278 PUMP VALVE AND MACHINERY CLEANER (AEROSOL) iO CANS 25 CANS Nr. 590 CUTTING OIL (AEROSOL) 4 CANS 12 CANS Nr. 651 DETERGENT LUBRICATING OIL (AEROSOL) 6 CANS 15 CANS Nr. 275 ELECTRIC MOTOR CLEANER (AEROSOL) 12 CANS 56 CANS Nr. 208 MULTI-PURPOSE INDUSTRIAL SOLVENT 5 GALS 15 GALS PAGE 16 Nr. 710 ANTI-SEIZE COMPOUND (AEROSOL) 4 CANS 6 CANS Nr. 360 PHOSPHATE FREE CLEANER lO GAL 55 GAL Nr. 262 INDUSTRIAL SOLVENT DEGREASER/CLEANER 5 GAL 70 GAL NALCO 2896 LIQUID 1882 LBS 4000 LBS NALCO 7330 MICROBIOCIDE 15 GAL 15 GAL NALCO i9 PULV BLEND/SODIUM METABISULFITE, 2 DRUMS 8 DRUMS OXYGEN SCAVENGER SODIUM SULFITE AND COBALT SULFATE NALCO 75 PULV 1/2 DRUM 1/2 DRUM BOILER TREATMENT NALCO 359 AQUEOUS SOLUTION OF CORROSION INHIBITOR DIETHYLAMINOETHANOL 1 DRUM 4 DRUMS NALCO 2543 PULV P,OLYPHOSPHATE SULFITE 1 DRUM 4 DRUMS HUMATE & POLYGLYCOL ETHER BLEND NITROGEN NITROGEN (GAS) 614 CU FT 1535 CU F7 OXYGEN OXYGEN (GAS) 498 CU FT 1494 CU F7 EPOXY PAINT 801 PAINT 24 GAL 24 GAL PAINT THINNER 1 GAL 5 GALS 900 GOLD END PASTE 1 LB 5 LBS PERMABOND SOLVENT NITROETHANE 3 OZ 6 OZ NITROPARAFFIN .... _ PLASTIC DIP 14.5 OZ 43.50Z PAGE 17 =ROPYLENE GLYCOL 1, 2-DZHYDROXYPROPANE 55 GAL 220 GAL 1, 2-PROPANEDIAL QUICK SET CYANOCRYLAIE 4 OZ 10 OZ SAFETY-KLEEN 105 SOLVENTS-MS~6617 35 GAL 315 GAL 105 SOLVENT-MS SEALANT, 758 ELECTRICAL 5 LBS 20 LBS SILICONE-732 RTU CLEAR 10 LBS' 20 LBS 723 SPRASOLVO 240 OZ 600 OZ (20-1201 CANS) (50 12 OZ CANS) SOLDER, ~44 RESIN CORE 5 LBS 2 LBS SOLVENT CEMENT, CRAFTICS 8 OZ 8 OZ SOLVENT CEMENT PVC CEMENT 1 LB 2 LB SOLVENT, STODDARD 5 LBS 10 LBS TM 2166 SOLVENT i GAL 1 GAL REFERENCE ELECTRODE i OZ 1 OZ SOLUTION STAINLESS STEEL 5XX SERIES, 1 TON 4 TONS 4XX SERIES STATE PEN PENTRATING OIL 2 CANS 2 CANS STEEL IT POLYURETHANE PAINT 2 CAN 2 CAN SULFURIC ACID BATTERY ACID, 58 38 ELECTRDYTE SUPERBONDER 416 CYANDACRYLATE ESTER 2 OZ 8 OZ INSTANT ADHESIVE 800 GOLD END TAPE 1/2 LB 5 LB PCAGE 18 THZCKEND CENENT NELD ON 15 5 OZ 5 OZ CLEAR TOUGHENED 5 OZ 5 OZ ZNST~NT CEHENT ORGANZC BONDED 4 E~ 8 EA GRZNDZNG NHEELS VZTRZFZED BONDED GIST-BROCADES FOOD INGREDIENTS, INC. BAKERSFIELD YEAST PLANT ENVIRONMENTAL INCIDENT PLAN 1992 BIOTECHNOLOGY CONTRIBUTING TO FOOD, HEALTH AND THE ENVIRONMENT June 25, 1990 Evacuation Plan: 1. A) Any full time Gist-brocades employee may determine if evacuation is required, getting management approval only if time permits and does not severely endanger life or property. Exceptions: 1. Earthquake 2o Flood B) If an exception: all personnel evacuate immediately. Follow the procedures described in the Earthquake or Flood Action Plans° C) In case of fire, notify the fire department immediately. Call: 326-3911. Follow the Fire Action Plan, included. D) If there is a Chlorine Spill, follow the procedure described in the attached "Chlorine Safety Procedure". E) If there is an Aqua/Ammonia Spill, follow the procedure described in the attached "Ammonium Hydroxide (Aqua/Ammonia) Spill Action Plan". F) In case of fire, notify all neighboring businesses on the attached letter, "Businesses in Close Proximity to Gist-brocades Yeast Plant"° 2. Personnel will shut down what equipment they can reach without endangering themselves, or others, within a few minutes; evacuation must be completed within 2 minutes. A) Process Operators: Follow the attached checklist. B) Maintenance: Ensure that the following systems are off if it can be accomplished safely° 1o Boilers 2. Aqua/Ammonia Pumps 3° Caustic Pumps 4. PhOSo Acid Pumps C) Packaging Operators: Ensure that the following is done: 1o Truck drivers evacuated 2° Fluid transfers stopped, valves closed. 3o All personnel will gather at the northeast corner of the property° Gist-brocades Food Ingredients Inc. 5455 District Blvd. Bakersfield, CA 93313 (805) 834-1050 Fax (805) 834-6212 Evacuation Plan Page 2 of 2 4. Managers will complete a checklist, turning it in to the plant secretary who will compile it before furnishing the list to the Plant Manager. 5. If phones are available, missing persons shall be called to confirm whether or not they are at home. 6. If phones are available, notify the fire department of evacuation. Call 326-3911o In some circumstances, such as an earthquake, or flood,*the emergency response contractor hired to manage chemical spills may not be available, or contactable. Under these emergencies only, an attached list of plant personnel qualified with emergency equipment will be required to contain chemical spills. The attached list is entitled, "Emergency Equipment Qualification List". A checklist has been prepared for each area supervisor. The checklists are attached° * KES Kern Environmental Service - (805) 589-5220. oy~ Fry ~- ~ Maintenance Engineer October 8, 1992 BUSINESSES IN'CLOSE PROXIMITY'TO'GIST,BROCADES YEAST'PLANT, BUSINESS'PLAN The following businesses own or lease property along the property line of the Gist-brocades Yeast Plant: Northwest: Northeast: Contel Advance Beverage (Anheuser-Busch) (805)631-2355 (805) 833-3783 5306 District Blvd. 5200 District Blvdo Bakersfield, Cao Bakersfield, Cao East: South: Superintendent (Vacant) Southern Pacific Transportation Co. 5201 District BlVdo (805) 321-4603 Bakersfield, Cao Bakersfield, Ca. Southeast: Southeast: (Vacant) The Pump House, Inc. 4730 Armstrong Road (805) 832-6975 Bakersfield, Ca. 4730-A Armstrong Road Bakersfield, Ca° West: Petrolite Oil Field Group Tretolite Chemicals (805) 834-5516 5501 District Blvd. Bakersfield, Cao JUNE 25, 1990 PROCESS OPERATOR'S'CHECKLIST;'BAKERSFIELD YEAST PLANT,'BUSINESS PLAN In an orderly shut-down, the following systems shall be disabled, in priority: 1) Chlorine 2) Sulfuric Acid 3) Phosphoric Acid 4) Aqua/Ammonia (Ammonium Hydroxide) 5) Caustic Soda 6) CIP Acid To reduce time, the computer shall be used when possible to disable these systems. However, in some instances, HOA controls and hand valves will do. The following shall also be turned off, if time permits: 1) Close the main sulfuric acid valve (from pot) 2) Shut off the ammonia tanks from tanks 3) Turn off the phosphoric acid pumps (HOA controls) 4) Turn off the CIP pumps (HOA controls) 5) Turn off the iodine solution pump (HOA controls) 6) Turn off caustic supply pump (HOA controls) 7) Turn off CIP Phos Acid pump (HOA controls) 8) Shut down blowers ("4", "Lower Group", "8") 9) Deactivate Mash Sequence 10) Turn off yeast separators (HOA controls) 11) Deactivate tower sequence 12) Open steam bleed valves to fermenters: *SOV-233 *SOV-234 *SOV-240 *SOV-241 *SOV-247 *SOV-248 13) Close fire doors, exit process area Lloyd Fr~ Maintenance Engineer PERSONNEL CHECKLIST NAME PRESENT AT HOME MISSING OFFICE Robert'Deedy, 'Plant'Manager' ' co'nni, e'~.S'~aulding, OffiE~ Manager " Sandy Campbel 1, Secre.ta.~Y PRODUCT I ON- PROCESS Steven Schnurrer, Fermentation Sc!pervisnr Charli'e Coar,'Operator Gilb'ert Cazares, .Operat.or " . . . . · Ronald Corona'd6 Operator George Hicks, 'Operator Sandra Merrill, Operator ' ' PRODUCTION - PACKAGING Carl Walker, Packaging Supervisor Gerald LUca~"~ Filter Operator .... D6nn~ s Ver'tr'ee"~, ' Fil t~r' O'oera'to'~ Bill Fur. ga.son, Filter Operator ' .... Patterson, Bi ll, Fil'ter' OPe'rai~'o-r '.'. ~'.. · .._.t '"' L6uie Garc~a L'ee' Mel vi 11 e · . D'ou'9 "Perkins Jose Si 1 va ' ' ...... Melvin Hicks Darrell CQoper . i MAINTENANCE Lloyd Fry, Mainten.a.n.ce. Engineer ... ... Hipo1 i t6 .~Camoto _ " ' ' Tom Bai 1 ey Darrel Beller .......... Gene Davi's .... QC LABORATORY MalColm Moore .... , Theresa Efada Mark Williams ...... ~randen P a',~_k e r CASUAL DATE: June 21, 1990 TO: All Plant Employees SUBJECT: Earthquake Action Plan Attached is a drawing showing the assembly area if an earthquake should strike Bakersfield. Also attached is a drawing showing the second level of the plant. In an earthquake, all personnel are to exit the building quickly and calmly and assemble on Armstrong Road at the northeast corner of the plant property° Considering nominal wind direction, and the location of the railroad spur, this location is the safest nearby area. The following areas will be avoided: 1) the unloading area, especially, the cooling tower (because of the Chlorine tanks), and the Aqua/Ammonia and Phosphoric acid tank pad, the CIP pad, and the fermenter pad. Any areas downwind, i.e., directly southeast of the cooling tower, Ammonia tank, and Phosphoric acid tank must also be avoided. In a severe quake, serious enough to cause structural damage to the building, there will be no time for management to make a rational decision regarding evacuation: This responsibil, ity rests with the individual employee. After regrouping in the assembly area, the Plant Manager will meet with his staff and determine if the building is safe to reoccupy° If his decision is negative, a structural engineer must be hired to certify that the building is safe, and recommend any repairs necessary to make it safe once more° It is advisable that the Plant Manager call the Bakersfield City Planners to be certain that his decision meets with city and county codes. The City Planners can be reached at 326-3727. If the telephones are operating, the security contractor should be notified when the building has been evacuated and declared unsafe. Guards are needed to prevent personnel from reentering the building to recover personal property. If the telephones are out, the Plant Manager will appoint two people to guard the plant until service is restored° Area supervisors will be responsible for assuring that their personnel evacuate the building safely. After egressing the building, supervisors will check the roster to be certain that all personnel are accounted for. A roster is attached for this purpose. GB-030-DP Earthquake Action Plan Page 2 The personnel below are responsible for the particulars after an earthquake. The Maintenance Engineer will be responsible for coordinating the plant shut- down operation in this situation. Bill Furgason will be responsible for shuting off the gas and city water to the building. Doug Perkins will be responsible for assuring that no one reenters the building without approval. The Plant Manager and Maintenance Engineer will estimate damage and prepare a preliminary report for the insurance company, and company management° Under no circumstances is the building to be reentered for this assessment without the expressed permission of management° The electrical power will probably be lost for a couple of days as a result of a severe earthquake. This is what occurred during the 1972 earthquake. If the power fails, the main break6rs on the second level will turn off build- ing electricity, and everything that is not on the UPS will go dowh, including the boiler. For this reason, the electrical power can probably be ignored after an earthquake. In a severe earthquake, an orderly process shut-down is not practical. Although the control room is constructed of 6 inch concrete block and has a high degree of survivability, it must be evacuated immediately after tremors have passed; the control room is at the center of what may be a structurally unsafe building° Personnel trapped there during the earthquake should avoid the areas previously mentioned and proceed to the assemb}y area by the fastest route available° Persons trapped on the roof should avoid crossing directly and should instead crawl along the load supporting concrete walls to the fermenter catwalk. Lloyd-'F~y// F~~. Maintenance Engineer cc: Bob-Deedy Connie Spaulding Lloyd Fry Steve Schnurrer Ronald Coronado Bill Furgason Doug Perkins Carl Walker Attachments: 1. Plant Roster 2. Plant Drawing (Level 1) 3. Plant Drawing (Level 2) PERSONNEL CHECKLIST NAME PRESENT AT HOME MISSING OFFICE Robert Deedy,'Pla~t Manager' ' -' I .... Conni. e~.Spauldin§,~ Off'iCh Manager i' .' · . Sandy Campbell, Secre.ta.rY' . PRODUCTION-PROCESS Steven Schnurrer, Fermentation Supervisor Charlie. Coar, Operator G'ilbert Caza~e's,.Operator · Ronald COronado, Operator George Hicks, Operator ~"~n~r~ M~r'~ill~ OPerato'r PRODUCTION -PACKAGING Carl Walker, Packaging Superv..~sgr · Gerald Lucas, Filter Operator Denn~ s Ve'f~ees ~ F'i l'~r'O~era'tor Bill 'Furgaso~, Filter Operator .... ... Patterson, Bill, Filter' Operator Loule ~arcia ' ' ' · Lee MelVille D'ou'~ 'Perkins Jose Silva. ' ' M'~lvin HickS Darrell CoOpeF . ...... MAINTENANCE Lloyd Fry, .Maintenance E.n~..ineer ~ipol it~ ~Eamoto .... TOm' B~ile~ ' ' -- · - Darrei Belier · Gene Davis QC LABORATORY Malcolm MOore Theresa Efada .' . Ma~k Williams ''- ~anden P~rker CASUAL _AF'cFA ~(]~T~{.' SCANS: i"=40' 8~s~a'Ess ~W~E: Gist-brocades Food Ingredients Inc. O~ZZ: ~/ ~') SS~Acrcr~r '>f~':~akersfield Yeast ~lant' :- ': / Interoffice i/ 'q BIOTECHNOLOGY CONTRIBUTING TO FOOD HEALTH AND THE ENVIRONMENTCorrespondence DATE: June 21, 1990 TO: All Plant Employees SUBJECT: Flood Action Plan In the event of a severe thunderstorm, or flood, there are thirteen items that employees should be concerned about: (1) the sump pumps; (2) the catch basin screens; (3) covers for equipment; (4) a power failure due to lightning, or windstorm; (5) roof leaks; (6) sump overflow; (7) personal safety; (8) the roof drains; (9) the fuel oil pit; (10) water collection behind the molasses tanks; (11) the windstorm preceeding the thunderstorm; (12) the blower screens; (13) and the molasses unloading pit covers. The sump pumps have a limited capacity which means that they can be overwhelmed in a severe thunderstorm. When this occurs, the process area and unloading area catch basins will overflow and there is a real danger that the cooling tower water will be contaminated° Additionally, the overflowing water may short out the junction boxes around the north tower sump; they are only a few inches off the ground. Unless the molasses unloading pit covers are bolted down tight, backed up water can pour into the pit° Also, sewage can back up in the indoor drains causing flooding and a contamination problem inside. To avoid, or, at least, to ameliorate overflowing the following steps should be taken during a rain storm: (1) the process operator should monitor the sump pumps at least every hour; (2) the use of water should be reduced to cut back the pump load; (3) equipment near indoor drains should be moved; (4) major loads, such as dumping a fermenter, which can be delayed, should be until a time when the sump level has returned to normal, below 60%. Even with the process Shut down, "SUMLEV" will read about 20-30%. A process operator, or, a packaging worker should clean the screens every hour during a thunderstorm provided that the lightning is at least five miles away. Anyone can determine the distance of lightning by counting the seconds between sighting the bolt, and hearing the thunder. The number of seconds represents the approximate distance in miles° When the storm has subsided, the next shift operator should spray down the concrete around the catch basins, and clean the screens. If the sump pumps were overwhelmed, he should sanitize the process area and any areas indoors where backflowing has occurred. He should also inspect the boiler room, instrumentation room, and packaging room for drain backflowing. GB-030-DP Flood Action Plan Page 2 Tile process engineer, or, the safety coordinator, if the former is absent, should monitor the daily weather and notify the Plant Manager, his staff, and general plant personnel if thunderstorms become imminent° The engineer must also notify other members of the natural disaster emergency response team at least twelve hours in advance. He should decide specifically who is available on the team to fulfill the tasks of the checklist. To warn plant personnel, a bulletin will be posted on the board. Bill Ferguson, or Doug Perkins shall be responsible for assuring that the catch basin screens are cleaned prior to a thunderstorm. This can consist of notifying the process operator, and the packaging supervisor that the screens must be cleaned° Whomever of the team notifies the operator, or, foreman shall do so in writing, by memorandum° After notification by the process engineer, it is the responsibility of each area supervisor to assure that any equipment in use outdoors either be moved indoors, or, covered properly. A proper cover should be tied down to prevent blowing away during a windstorm. It should also be waterproof, in good condition, and cover the equipment completely° Typically, a lightning storm means a power failure in Bakersfield. The duration of a failure can be anywhere from less than I minute to two or more hours. When a lightning storm warning has been issued operators and packaging. room workers should check their flashlights~ During an electrical storm it is tempting to go outside and watch the lightning° This is an unsafe practice which must be avoided. Also, since the roof, the tops of the fermenters, the top of the blower building, the top of the molasses tanks, and the cooling tower are high points in the flat horizon of the valley these areas are to be avoided during a thunderstorm. A number of spectacular roof collapses have occurred during Bakersfield thunderstorms. In August, 1983, the roof over Mervyn's collapsed because of poor drainage. To avoid this problem, and reduce leakage, the roof drains must be inspected before each storm° Ronald Coronado, and Bill Ferguson will share this responsibility° The fuel oil pit will fill in any sizeable shower° Oil contaminated water poses an environmental hazard. For this reasons tie-ins have been provided for tidy removal from the pit via an air-driven pump° Unless the pit is about to overflow, this installation can be done during the next day by the shift maintenance man. If overflow is approaching, call the plant engineer. Flood ~ction Plan Page 3 Typically, a valley thunderstorm will be preceeded by a windstorm° To prevent a serious dust problem all doors should be closed including the dock doors, the boiler room doors, and the storage room doors° Doug Perkins, and Ron Coronado are responsible for this task° Wind-driven rain can soak the outside blower screens causing them to collapse° The blowers could shut down in this situation. During a storm, the process operators should monitor the air flow and watch for any sudden drops in air flow which would indicate an intake problem. If the filters collapse the plant engineer should be contacted immediately. After a thunderstorm, the blower filters should be inspected for damage. If soaked,'they should be replaced immediately since they will shrink away from their frames thereby allowing unimpeded air flow to the blowers. Lloyd Fry Maintenance Engineer Attachments: 1. Checklist PERSONNEL CHECKLIST NAME PRESENT AT HOME MISSING OFFICE ~ Deedy, ~lant Manager ,, Connie-Spaulding,,,Office ~I'~n,ag6'r ' ,,, Sandy CamPbell, Secretary PRODUCTION-PROCESS Steven Schnurrer, Fermentation Supervisnr tharlie COar, Operator Gilbert 'Cazares, Operator 'ROnal~ Corona'do, 'Operator 'George Hicks, OpeWatOr ' S~ndr'a Merr'ill, Operator PRODUCTION - PACKAGING Carl Walker, Packaging Supervisor Gerald Lucasl 'FiT'ter Operator ' · Dennis VertreeS~ Filter'Omerator Bill Furgason, Filter Ooerator Patterson, Bill, Fil~er'Operator " ' Louie Garcia Lee M~lv'ille ,, Dou~ PerkinS "' ' ...... JoSe SilVa · MelVin Hicks Darrell CooPer , MAINTENANCE Lloyd, Fry, Maintenance. En~i,neer , , HipolitO.s~Ca~oto. Tom Bailey' Darrel Be~ler Gene Davis QC LABORATORY Ma'lcolm Moore Theresa.Ef,~da Ma'rk Williams .... Branden Parker CASUAL BIOTECHNOLOGY CONTRIBUTING TO FOOD, HEALTH AND THE ENVIRONMENT June 14, 1991 FIRE ACTION PLAN When the fire alarm system is activated by either smoke or heat a signal is sent to ADT. ADT will then dispatch the Fire Department. Once the alarm sounds it becomes the responsibility of all supervisors to check their respective departments for fire locations. Then, announce the fire locations over the Public Address System (Telephone Address System) and determine if evacuation of the Plant is necessary. If necessary, activate the evacuation horn. Gist-brocades Food Ingredients's personnel will attempt to fight fires of a small nature only, i.e., trash cans, rags, etc. A map showing the evacuation areas is in the business plan and are posted throughout the plant with arrows showing the primary escape routes. Should evacuation be necessary, all personnel should exit through the respective exit assigned to each section of the plant. All personnel will assemble on the grass, next to the main entrance on Armstrong Street, and report to their immediate supervisor. Each supervisor will be responsible for assuring that their personnel evacuate the building and are accounted for. After a head count, each supervisor will report missing persons to the plant manager. In an evacuation follow the.'!Evacuation Plan" included in the business plan. When evacuating the building follow the rules below: 1. Leave all personal belongings 2. Walk, do not run, to exits 3. If an area is covered with dense smoke, crawl to the exit 4. Stay in the assembly area until told to leave by the acting plant management 5. Do not re-enter the building unless authorized Lloy~d Fry Maintenance Engineer cc: File Gist-brocades Food Ingredients Inc. 5455 District Blvd, Bakersfield, CA 93313 (805) 834-1050 Fax (805) 834-6212 Interoffice .... ~ ;IOTECHNOLOGY CONTRIBUTING TO FOOD, HEALTH AND THE ENVIRONMENT Correspondence INQUIRY (MEDICAL EMERGENCY) Should an injury occur at Gist-brocades Food Ingredients Inc. the following steps should be observed by all personnel: 1. Prevent loss of blood 2. Maintain breathing 3. Prevent individual from further injury 4. Prevent shock 5. Notify your immediate supervisor Supervisor will be responsible for the transport of injured in- dividuals to a medical facility. ! if -' I eroffice B,OTECHNOLO~Y CONTF~IBUT NG T© F©OD HEALTm AND THE ENVIROF,/MENT Correspondence AUGUST .6, 1992 PERSONNEL qUALIFIED TO USE EHERGENCY EQUIPHENT, BAKERSFIELD YEAST PLANT BUSINESS PLAN The personnel be]ow have been qualified and trained to use emergency equipment: Air Purifying SCBA CPR Equi pmt. (Mask) Certified Certified Bailey, Thomas X X Beller, Darrel X X Cazares, Gilbert × Coronado, Ronald X Coar, Charles X Davis, Gene , X .. Deedy, Bob ' X Fry, Lloyd X Furgason, Bill X t~j~ Garcia, Louie X X X Hicks, Ernest X Hicks, Melvin X Lucas, Gerald X Patterson, Bill X X Perkins, Doug X Sacamoto, Hipolito X Silva, Jose X Spaulding, Connie X Vertrees, Dennis X X X Walker, Carl X Additional qualified personnel will be trained. New personnel will be evaluated for qualification and trained as qualified. The training performed shall be annual. Carl Walker Safety Coordinator CW/sc cc: Connie Spaulding Lloyd Fry All Business Plan Books GB-O30-DP /l/ GIST-BROCADES FOOD INGREDIENTS INCORPORATED BAKERSFIELD YEAST PLANT HAZARDOUS SUBSTANCE COMMUNICATION PROGRAM INVENTORY An inventory has been taken and a complete list of all hazardous substance has been compiled. Material Safety Data Sheets (MSDS) have been received from the manufacture or from vendors distributing these substances. Ail shipments of hazardous substances must include the Material Safety Data Sheet with the delivery. If the Material Safety Data Sheet is not included the shipment should not be accepted. The master inventory should contain the following information for each substance listed: 1) Identification of the product 2) Location of the Material Safety Data Sheet 3/ Maximum amount handled/stored at any one time. The master inventory of hazardous substances will be kept current and maintained by: Connie Spaulding, Office Supervisor Sandra Campbell, Secretary -Each workplace where substances are stored, handled or utilized must be posted with a list of those substances. Workplace postings will be located at the plant office and each supervisor has these as part of their Business Plan and Environmental Incident Plan. Any product received without the appropriate Material Safety Data Sheet requires follow up with the distributor. If the distribu- tor has working days from the date of~ request the local Occupational Safety and Health Administration Office must be notified. These follow up procedures will be the responsibility of the supervisor responsible for the product. MATERIAL SAFETY DATA SHEETS Material Safety Data Sheets will be obtained and kept on file for all hazardous substances purchased, stored, used or handled by the Gist-brocades Food Ingredients Inc., Bakersfield Yeast Plant. Material Safety Data Sheets will be kept on file with each indi- vidual supervisor. Copies of Material Safety Data Sheets of products use in our facilities can also be obtained by: CALL: Carl Walker at (805) 834-1050 WRITE: Carl Walker, Safety Coordinator Gist-brocades Food Ingredients Incorporated 5455 District Blvd. Bakersfield, CA. 93313 EMPLOYEE TRAINING Employee training will be provided to each employee on all hazar- dous substance he or she may come in contact with or be exposed to while working for Gist-brocades Food Ingredients Incorporated. · Current employees have received appropriate training as a group. Each group will consist of employees utilizing or having possible exposure to the same or similar hazardous substances. This group training will enable the training to be as specific as possible. The training program will be on-going with additional training presented as new substances are introduced into our operations or if information on current Material Safety Data Sheets significa- tly changes. A significant change entails new information indi- cating an increased risk in the use of the substance and/or changes in the measures necessary to protect the employees from exposure. In addition to employees being updated on significant changes and new products, training will be conducted as follows; 1) Initial training 2) Annual re-training 3) Newly hired employees will receive training immediately upon starting work. 4) Specific training for all non-routine tasks. 5) Vendors/contractors will receive training on hazardous substances they could be exposed to while on company Premise. All training and re-training will be thoroughly documented as to the trainers, course outline, and those in attendance. Training, re-training programs and all documentation of training programs will be conducted under the direction of each individual supervi- sor with plant wide coordination from Carl Walker. Employee hazardous substance training shall include the follo- wing: A. An explanation of what a Material Safety Data Sheet is, its intended purpose and how to read and interpret the informa- tion provided on the Material Safety Data Sheet. B. An explanation of the information provided on the Material Safety Data Sheet: --the health hazards associated with the use and/or exposure to exposure to the substance --proper handling for safety to reduce the exposure --personal protective equipment which is necessary or recom- mended during handling or use of the substance. --Emergency procedures for spills, fires, first aid and dis- posal --other safety precautions necessary to prevent or minimize exposure to the substance. C. An explanation of the information on the container labels. D. An explanation of the right of the employee to obtain a copy of any Material Safety Data Sheet by following the procedures explained in the "Material Safety Data Sheet" section of this policy. E. An explanation of the right for a collective bargaining agent or a treating physician to obtain a copy of any Material Safety Data Sheet upon following the proper procedures explained in the "Material Safety Data Sheet" section of this policy. F. An explanation of the employee's protection from termination, discrimination for retaliation by the company for exercising rights under the General Industry Safety Orders. LABELS Ail containers, to include secondary containers, holding hazar- dous substance will be labeled with at least the following information. --A complete identity of the product. --Ail appropriate hazard warnings and safety precautions. It is the responsibility of each employee to be certain that all containers have proper label with the appropriate information and that all labels are securely attached to the containers. Sub- stances which do not have the proper label and/or cannot be identified are not to be used, handled or stored. If containers are found without proper labels notify Carl Walker, Safety Coor- dinator and/or supervisor. Shipping and receiving will not ac- cept shipments of materials that are not properly labeled. EMERGENCY RESPONSE PLANS AND PROCEDURES Gist-brocades Food Ingredients Incorporated has developed the following emergency response plans to be followed in the event of a release or threatened released of hazardous materials. 1) Lloyd Fry, Plant Engineer,and/or Robert Deedy, Plant Manager will be in charge of the coordination of all emergency procedures to include notification and communication with all emergency response agencies. 2) Ail other employees will follow preplanned evacuation proce- dures during an emergency. 3) Dial 911 for all emergencies. DISCIPLINARY PROCEDURES Employees will comply with all safety rules and regulations implemented by Gist-brocades Food Ingredients Incorporated for the purchasing, storing, handling and/or using hazardous substan- ce. Disciplinary action taken will be within the guidelines as defined in the company employee handbook. Internal Reporting Responsibilities Personel R~spon~ibility Worker Report incidents immediately; "no doubts, always report" Area Supervisor Decide if incident involves priority substance and report; report to main- tenance engineer if in doubt; initiate prescribed contingency plans Utilities Foreman Inspect, assess, take action,"repo~t; (Maintenance Engineer) seek confirmation on action if in doubt; initiate safety and health procedures or other contingency plan Resident Engineer Decide if incident reportable to agencies; (Environmental Coordinator) if in doubt, consult corporate staff; inform Plant Manager and corporate staff of decision; confirm action taken Safety Manager Confirms action taken: decides if local outside emergency units should be invol~ed; assists Resident Engineer if incident is reportable and demands immediate outside agency assistance Plant Manager Coordinate all activities involving incident; inform appropriate managers; prepares PR agent and controls information flow and actions taken Environmental Staff Confirms decision to report to agencies; advises on corrective action; prepares PR ~ ~ '~' ~ agent; liason with Legal Staff Corporate Legal Considers liability issues and interprets laws and rules Kemper Insurance Incidents may involve claims, will notify various insurance companies Note: The Environmental Reporting Policy attached requires reporting to outside agenices if for some reason the internal reporting scheme breaks down. Consult this policy for this exception. BIOTECHNOLOGY CONTRIBUTING TO FOOD, HEALTH AND THE ENVIRONMENT WASTE WATER SPILL DUE TO FORCE MAIN BREAK BETWEEN PLANT AND RANCH A. GENERAL The force main lines (8" and 3") are inspected daily by the Ranch Coordinator and his assistant. Further frequent inspections are made by the Water Canal Personnel and Railroad personnel. A log of these inspections is maintained by the Ranch Coordinator. A possible source of leaks was the nine air release valves in the line. To date eight of the nine have been eliminated, with one more to go. B. ACTION Should a break (leak) occur the following guidelines shoQld be fol- lowed for containment, reporting repairs and clean-up. 1. Notify LLoyd Fry, Robert Deedy, or Steve Schnurrer at the Plant, during normal work days, or Process operator at night or on weekends. -Telephone(805) 834-1050. Have contact person shut-down L ~ N ~pump. Note: Since the 3'J and 8" tines are fed. by separate pumps, it is important to determine which of the two lines are leaking. When defective line 'is located, restart the pump on the good line. Without pumping, the L E N pump will soon over flow and could shut-down plant operation. We must also take steps to reduce the volume of waste water while pump is down. Notify a company who is e'quipped to repair leak. All work and time schedules must be coordinated,between work site, plant and ranch. Gist-brocades Food Ingredients Inc. 5455 District Blvd Bakersfield, CA 93313 (805) 834-1050 Waste WaterO~i-ll Page 2 The person in charge of plant operation will arrange for vacuum trucks for the L & N sump as needed to main=~',- tain plant operations. Ranch Coordinator or Plant Manager will take steps to notify involved property owners and/or regulatory people. When equipment arrives at leak site, berms are to be formed to contain leak. Once leak is contained, steps to repair break can begin. Keep plant informed of situation at all times. WASTE WATER SPILL IN TANK AREA OF RANCH 1. Any spill occurring in the tank areas of the ranch should be stopped)~ in a timely manner. 2. Any major spill at the ranch tank site would run into an adjacent} check so any damage would be minimal if any. 3. Any resulting potential for odor should be minimized. ~ ...........--'Z 4. Plan~ Manager, local residents and repair crews should be notified ] as required. Gist-brocades Food Ingredients Inc. 5455 District Blvd Bakersfield, CA 93313 18051 834-1050 BIOTECHNOLOGY CONTRIBUTING TO FOOD HEALTH AND THE ENVIRONMENT April 23, 1989 AMMONIUM HYDROXIDE ~AOUA AMMONIA) SPILL, ACTION PLAN aeneral Characteristics Aqua Ammonia is a 25~; by weight solution of water and ammonia. The chemical and physical characteristics are detailed in the attached M .S .D .S. Potential Hazards As an aqueous solution ammonia, known as ammonium hydroxide, is not an acutely hazardous material. However, anhydrous ammonia, often used for refrigeration is an acutely hazardous material. In a weak air mixture, ammonia causes burning of the eyes and throat. In concentrated mixtures immediate, temporary blindness will occur. A liquid solution will cause skin burns on contact. Protective Clothing A full-face (with eye protection) gas mask with the proper chemical cartridges should be sufficient provided direct skin contact is avoided. The correct cartridge is: "R-54A: 'For Ammonia and Methy Amine.'' An alternative cartridge is: "R-5~HE: 'Combination Cartridge.'" These should not be worn unless the R-S4A cartidges are unavailable. Extremely high concentrations of ammonia should be avoided because the cartridges will be penetrated at vapor concentrations above 5 ppm. Compromised cartidges usually provide sufficient warning. Gas masks are not to be worn by any but qualified individuals who are acquainted with proper mask testing. Masks are not be worn by anyone with a beard. Annual training is required for all qualified individuals in the wearing of gas masks. First Aid a. Move the victim immediately from the contaminated area to air. b. Check the victim's breathing. If breathing has stopped, use CPR. c. If breathing has stopped, call the paramedics at 911. d. If breathing is O.K. and skin or eyes have been exposed to ammonia vapor or liquid use a safety shower or eye wash to flush the affected area. e. Refer to the attached M.S.0.S. for further information. Gist-brocades Food Ingredients Inc. 5455 District BIvd Bakersfield, CA 93313 (805) 834-1050 Ammonium Hydroxide Spill Action Plan Page 2 of 2 Spill Response Major Spill: A major spill is one of 1000 pounds or more, i.e., more than 130 U.S. gallons of aqua ammonia, assuming an ammonia concentration of 25% (a density of 7.59 lbs./gallon). A major spill must be reported to the National Response Center° Reporting is done through the Local Administration Agency, or L.A.A.; the Bakersfield Fire Department is the L.A.A. The L.A.A. should be contacted if, in the judgement of the on-site management, a spill constitutes a reportable quantity, i.e., 1000 pounds, or a spill poses a hazard to either health or environment° Failure to report such a hazard to the L.A.A. is punishable by fines up to $25,000/day, and criminal prosecution resulting in up to 5 years, incarceration. In a major spill, the following procedure is to be used: 1. Shut down the boiler. Wear protective gear. 2. Evacuate downwind areas° 3o Treat any injuries. 4. Keep all personnel out of affected area. 5. Notify the immediate supervisor who will decide whether the emergency response contractor is required° The immediate supervisor shall also decide whether the L.A~A. should be contacted. 6. If the supervisor is unavailable, contact (in succession): ao Carl Walker @ 398-7220 Pager @ 329-1023 b. Lloyd Fry @ 833-8764 Pager @ 329-2617 c. Bob Deedy @ 664-0248 7o The emergency response contractor is: KES ~ /~c~// Kern Environmental Service (805) 589-5220 Maintenance Engineer "' MMONIUM HYD ROXIii E - Corrosive or ORM-A '-? RQ 1000 Lb/454 Kg* GENERAL INFORMATION Ammonium hydroxide (NHdOH) is a colorless to milkly colored liquid that is ~ormulated by dissolving.ammonia water. Various grades generally (but nor always) contain 15-29.4% ammonia by weight and are used as household cleaners, for fertilizer, and in making plastics, dyes, explosives, detergents, pesticides, nitric acid, and other products. All are futly soluble in water and are not considered flammable. Nevertheless, ammonia vapors may evolve and burn if these solutions are heated in fires. Accumulations of ammonia vapor in confined spaces within a narrow range of concentrations may occasionally result in explosions if exposed to a strong source of ignition. There is some limited potential for containers of ammonium hydroxide to rupture due to overpressurization if exposed to fire or excessive heat for sua2lcien[ time duration. Concentrated solutions may boil at higher ambient temperatures and many solutions are capable of evolv/ng signixqcan[ amounts of toxic ammonia vapors. A solution containing 20% ammonia weighs about 7.7 pounds per gallon. Ammonium hydroxide mixes in water 'adth mild liberation of heat. It is corrosive to some metals and reacts with various chemicals. ,.'v[ixrures with halogens, calcium, mercury, silver oxide, or hypochlorites of calcium or sodium may be explosive. The liquid and its concentrated vapgrs may be irrita[ing and corrosive to bodily tissues, l:h'oducts of combustion may include nitrogen oxides and unburned ammonia. Downwind evacuation should be considered on a case by case basis if a concentrated solution of ammonium hydroxide is leaking from its container. CHEMICAL~PHYSICAL DATA Solubility in Wa~r: Soluble in all proportions Burni_r~g Rare: Not pertinent Solubility in Other Chemicmfs: Dare unavailable Stability: Stable Specific Gram'ty (Liq~d): 0.9592 (10% NHa); 0.9245 Corrosiveness: Corrosive to aluminum, tin. copper, lead. (20% NH,); both at BS°F (20°C). silver, zinc, galvanized su~aces, and various alloys of Boiling Point: 81°F (27.2°C) at 1 arm for 29.4% solution these metals. ~felting ?oi_n~ -98.3°F (-72.4°C) Reacrivi~ ~'th Wa~r:. Mild liberation of heat upon Freez~g PoLn~z - 98.3°F ( - 72.4°C) dissolution. :~oIecufar Weight: 35.05 for NH~OH; 17.03 for N. Ha Reactiwity ~Hth Other Chemicals: Reacts with strong Heat o£ ~ombusriou: - 4440 calYg for NI-{~ vapor rmneral acids, silver n/tram, silver oxide, silver o.'dde Vapor'Pr.essure: 556.7 mm Hg (10.76 psia) at 70°F and e~yl alcohol, calcium, mercury, hypochlorites of (21.i°C) for 28.8%; 221.4 mxn Hg (4.28 psia) for 19.1% calcium or sodium, acrolefn, acrylic acid, dimethyt Nlra " sulfate, halogens, gold, hydrochloric acid, nitric acid, Flash Point: Not flammable under conditions likely to be hydrofluoric acid; B-propiolactone, propylene oxide, or encountered, silver permanganate. Autoig'aition Temperature: 1204°F (651°C) for Nlra vapor IDENTIFICATION Shipping Names: Ammonium hydroxide (USDOT); Physical Stage as Shipped: Liquid ammonia solution,(USDOT and ~iO) Physicat State as Released: Liquid Synonyms and Tradenames: .~mmonia monohydrate; Color of the Skipped Material: Colorless or milky aqueous ~mmonia; ammonia solution; ammonia water; white household nmrnonia; aqua nmmonia; water of Odor Cfum'acteristics: Like ammonia, pungent ammonia; ammonium hydrate. Common Uses: Mfg. plastics, dyes, e.xplosives, Chemical. Formula: NI-I~OH detergents, pesticides, nitric acid, rayon, rubber, Consritne:at. Components(% each): 15-29.4% ammonia, pharmaceuticals, inks, ceramics, lubricants, household in water (generally, no~' always) · cleaners, fertilizers, and other chemicals; used in ~9 STCC; 49 352 80; 49 403'47; ~9 403 16; 49 352 8~. refrigeration, photography, and fireproofing wood. UN/NA Desiguaation: NA2672; UN20?3; UN2672 IMO Designation: 8 (corrosive) depending on NH~ concentration "l~por~able quamity {i~q) ~ubje~ ~ e. han~--raf~r m ~.rr~nt. EPA ':'" FOR. ~DDITIONAL,~SSISTANCE OR INFORMATION CALL: " CHEMTREC (800)424-9300 OR (202)483-7616 OR. '"'" ... THE. AAR BUREAU OF EXPLOSIVES (202)835-9500 ' -. A ONIUM HYDROXIDE Corrosive or ORM-A POTENTIAL HAZARDS .. .... ..,. GENERAL I-Li_ZARDS. ' ' Threshold Odor Concentration: 0.03%20 ppm reported for NH, : ' UnusuaJ PIazards: May evolve considerable amounts of ammonia vapors from concentrated solutions or if heated. Concentrated solutions may boil au higher ambient temperatures. Short Term Exposure r,lmits(STEL): 35 ppm NH3 for 15 minutes. (ACGIH) Time Weighted Average(TLIZ~TWA): 25 ppm NH~ over each 8 hours of a 40 hour work week.(ACOlH) Cond_l'~ons to Avoid: Heat, 5re, and strong ignition sources; contact with incompatible materials; runolT to s'~wers or water bodies; inhalation, inges[ion, or direct physical contact. HEALTH HAZARDS Public Heafth f-fazards: Major hazard is from inhalation of high ammonia concentrations that may result in air from larger spills or spills of concentrated ammonium hydroxide. Direct contact and ingestion are also to be str/cdy 'avoided. Hazards of Skim or Eye Contact: Contact of liquid ammonium hydroxide with the skin or eyes may cause intense imtation and possibly severe burns. The hazard is proportional to the amount of Nit3 in solutions, but even those wieh only 10% ammonia by weight should be considered highly hazardous. Ammonia vapors in air at high concentrations may also cause bm-ns and blisters of the skin or eyes. Hazards o£Iahalation: Ammonia vapors may cause burning and tearsng of the eyes, runny nose, coughing, chest pain, and irritation of the nose and throat. Severe exposures may result in difficult breathing, bronchospasm, bronchitis, pulmonam/edema, and possibly death. Some effects may be delayed in onset and may be accompanied by pink frothy sputum. Note that a level of 5000 ppm in air may be almost immediately fatal due to serious edema, strangulation, and asphyxia. Hazards off.m, gestion: Ingestion may cause burning pain in mouth, throat, stomach, and thorax, constriction of i I throat and~:0ughing, may vomiting or passage bloody Breathing.difficulties, TbJs be followed by blood 0[ stools. convulsions, and shock may result. Ingestion of only 3-4 ml may be fatal. FIRE HAZARDS Lower FI~mmable Liml'~: 15.5% (for NH3) · Upper Flam222able Limit: 27% (for NHi) Behavior in Fire: May generate large quantities of vapor upon release. Vapors will bm but are difficult to ignite. Conta/ners may rupture in lire due to overpressurization. Hazardous Combustion Products: Ma7 include oxides of nitrogen and unburned armmonia. EXPLOSION HAZARDS Lower Expiosiv~'Limit: 16% (for NH~) Upper Explosive f,imit: 25% (for Explosiveness: Containers may rupture in fire due to overpressurization. Vapors are difficult to ignite but may occasionally explode if ignited by a s[rong source within a cor~2ned area. Contact with certain other chemicals may result in formation of explosive mixtures. PROTECTIVE CLOTHING AND EQUIPMENT Protectiye CJothing Required: Equ/pment should prevent any possibility of skin or eye contact with the Spilled product. This may include rubber boots, gloves, face shields, splash-proof safety goggles, and other' impervious and resistant cloth_ina. Fully encapsulating suits w/th self-contained breathing apparatus (SCBA) may be-advisable in some cases .to prevent contact w/th high vapor or fume concentratiorm in air. Compatible materials may:include butyl 'rubber; natural rubber, neoprene, neoprene/sytrene-butadiene rubber, nitrile rubber, nitrite rubber/polyvinyl chloride, polyethylene, chlorinated polyethylene, polyurethane, polyvinyl chloride, styrene-butadiene rubber, Viton, and ni~ril~-butaddene rubber. - Respiratory Protection: For unknown concentrations, fire fighting, or l-flab concentrations (above 500 ppm NHa), a self-contained breathing apparatus (SCBA) with full facepiece (or the equivalent). For lesser concentrations, a gas mask with chin.-style or front or back mounted ammonia canister(500 ppm NH~ or less) oran azmmonia Cartridge [ respirator with 'a full facepiece 300 ppm NHa or less) within the,use,,, limitations of these devices. · 63 AMMONIUM HYDROXIDe. ' -- Corrosive or ORM-A FIRST' AID f~onspecit~c s2xnp~om$: Irritation or burns of any bodily tissues; other symptoms of exposure. F/rs: Afc/for £nhsJat:ion: Kemove victim to fresh air and keep warm and at rest. If breathing becomes difficult or if breathing has stopped, administer artil~cial respiration. Get medical attention immediately. (Caution: Administration of mouth-to-mouth resuscitation may expose the first aid provider to chemical wichin the vic¢im's lungs or vomit.) First AJd for Skin and Eye Contact: Flush eyes immediately with water for at least 15 minutes, occasionally lifting.. the eyelids. Remove all contaminated clothing. Wash affected body areas with'large araounts of water. Get medical attention imraediateIy if eye contact has occua'red or if skin irritation is present aI%er washing. First As'd for Ingestion: If victim is conscious, administer large quantities of water immediately. Do not attempt to make the victim vomit. Cret medical a¢tention immediately. FIRE RESPONSE Extinguishing ,~YfaterJat$: As necessary for surrounding fire. Ext/ng-uJsh/ng Techniques: Unusual vapor or fume hazard. Stay upwind. Avoid all bodily contact. Wear breathing apparatus and appropriate protective clothing. Wear full chemicai protective suit if contact with materiai or dense fanes/smoke anticipated. ~iove container from fire area if no risk. Be alert to the possibility that the container may tear or rupture and suddenly release massive amounts of product whea exT. osed to high heat (over 800°F), suck as from a direct flame. Use water [rom side and from sale distance to keep ~re exposed containers coo[. SPILL RESPONSES '. GeneraJ. Informatffon: Proceed with caution. Restrict access to area. Keep unprotected personnel upwind of spill area. Avoid~contact with spilled product. Eliminate ignition sources. Prevent liquid from entering sewers and confined spaces. Protect sewers and waterways from contaminated rtmoff. Notify proper authorities, downstream sewer and water treatment operations, and other downstream users of potentially contaminated water. ~ote that intake of highly contaminated water may result in damage to boilers or industrial process equipment. Use explosion-proof equipment where necessary. Choose equipment, where possible, that is not corroded or otherwise damaged by the spilled product. Take into account that concentrated ammonium hydroxide is volatile, to.x/c, corrosive, and potentially flammable under conditions described in the General In. formation section. Ail{ SPILL TE C I-~¥I Q UE EVACUATION ,.. Evacuate local and downwind areas as conditions warrant to prevent e.'cposure and to allow vapors or fumes to dissipate. Aznmonium hydroxide spills may expose downwind areas to toxic concentrations over considerable distances in some ca~es, particularly if large amounts have spilled in warm weather and/or the product is £air[y concentrated. C ONSE Q UENCE ~eed to notify, organize, transport and house displaced persons. MITIGATION Stop !eak if without risk and if proper equipment available. Allow vapors s_nd fusses to dissipate completely before reentering spill area without special protective gear. Consult qualified experts for assistance: MONITOR THE SITUATION... Arrunonium hydroxide may not evolve large amounts of hazardous airborne contaminants in mealy outdoor spill situations. It may be advisable in some cases to simply monitor the situation' until the spilled product is removed, particularly if small amounts have spilled, the product is not very concentrat.ed, and/or the weather is cold. ", CONSEQUENCE' Hazardous levels of ammorfia in air may be found in the local spill area and immediately downwind. M~TZGATZON' Remove the spilled product as soon as possible. Restrict access to the localcsP&ll area and. areas immediately downwind by unprotected personnel. ...- I.164 AMMO ._I [UM HYDROXIDE: .. , Corrosive or ORM-A' WATER FOG OR SPRAY... Water fog or spray may absorb ammonia vapors and accelerate their dispersal in the atmosphere. CONSEQUENCE · Water runo~t' may contain ammonium hydroxide from contact with vapors or fumes. MIT£GATION Contain contaminated water and remove or neutralize as soon as possible to .prevent spread of contamination. Be alert to conditions such as fire hose runoff or rainwater that may add to spill volume and overfill impoundments. Consult qualified experts for safe neutralizing techniques. TE CHiVIQ UE DILUTION ... The addition of a relatively Iarge amount o£ water to Hquid ammonium hydroxide may slow the reiease of vapors into the atmosphere. C OiVSE ~ UENCE Addition of water will increase the volume of material requiring recovery. Contain spi!led product and remove or neutralize as soon as possible to prevent spread of con~aminauon. Be aler~ to conditions such as lire hose runo~i or rainwater that may add ~o spill vo[ume and overfill impoundments. TM CHN£ Q US NEUTRALIZATION ... Application of an appropriate neutralization agent to liquid ammonium hydroxide may eventually slow the release of vapors or fumes in~o the atmosphere· 'CONSEQUENCE Depending on the neutralization agent and application (echnique used, the resulting chemical reaction may produce varying amounts of heat, vapors, fumes and spattering. ~IITIGA TION Procee~t with caution. Consult quali~ed experts for safe neutralizing techrdques. TM CPL~VI Q UE FOA~'V~ . .. There is a possibility that special chemical hazard foam or certain high expansion foams applied to the surface of liquid pools may slow the relekse of ammonia vapors into the atmosphere. CONSEQUENCE The effects of foam may be short term. As the foam breaks down, release of vapors will increase. Products of foam breakdown will add to the volume of spilled material. MITIGATION Continue foam applications until spilled product is removed. Contain increased volume. Use ' alternativ~ technique if response is ineffective. LAND SPILL TIS C HIVI Q UE CONTAINMENT DIKES .. Ammonium hydroxide may be contained by building dikes using soil, sand or other materials. · CONSEQ, UENCE Contained arnznomum hydroxi~le may percolate into soil or seep through dike material. This may result in loss of contained product and spread of contamination. ~%IITIGA TION Remov~ or neutralize contained product as soon as possible to prevent spread of contamination Be alert to conditions such as fire hose runoff or rainwater that may overfill impoundments. Where possible, line collection area with compatible impervious materials. AMMONIUM HYDR _ADE Corrosive or OR TE CIt~VIQ UE EXCAVA. TION · .. A trench or ditch may be excavated to contain leaking product. CONSEQUENCE There may be increased potential for groundwater contamination in some cases. MffTIGA TION Remove contained products as soon as possible to prevent spread of contanmination. Use surface dikes or barriers where groundwater contamination is possible or Iine collection basin with compatible impervious material. TE C I-L¥I Q UE PUMPING/VACUUI%£ sUcTION ... Accumulated liquid pools may be recovered using appropriate hoses, pumps and storage containers or vacuum trucks. ' CONSEQUENCE Equipment that is incompatible with the spilled product may become damaged or develop leaks. M_rTIGA TION Use equipment compatible with spilled product. TE C HNI Q UE ABSORPTION .. · Spreading of spilled product may be controlled by absorbing liquid with sand, ear, h, olay, fly ash, cement powder, or other compatible substances. CONSEQUENCE Once used, sorbent materials pose the same hazards as the spilled product. Their use adds to the overall volume o£ contaminated material. ~VzITIGA TION Deplete accumulated liquid pools with pumps or vacuum trucks if possible before applying i;- sorbents. Remove conta~.inated sorbents to safe storage by mechanical means. Where necessary, neutralize sorbents under g'uidance of qualified exper:. TE C I-L¥I Q UE NEUTKA!,IZATION ... Application of an appropriate neutralization agent may modify the spilled product to a lesJ hazardous substance. CONSEQUENCE Application and removal of chemical agents involves additional environmen~l risks. ~VzITIGA TION Consult qualified experts for safe neutralization techniques[ TE C H~I Q [CE - MECIL~NICAL REMOVAL... Contaminated soil and spilled product may be removed by shovels, motorized graders and scrapers, loaders, bulldozers, and draglines. CONSEQUENCE Removal equipment may become contarainated and presen~ a hazard to later users. Incompatible equipment may be damaged or corroded. Improper storage of removed materials may result in future spread of cont. anlination. MITIGATION De'contaminate all equipment after use. Use equipment compatible with spilled product. StOre contaminated materials in safe and secure location. · WATER SPII,I, ., TE C I~INI Q UE STOP USE ... Notify downstream industrial, municipal, and public users ~o stop water intake or to monitor' water for contamination. t. CONSEQUENCE' ... ~ Alternative water.supplies may be-needed ~o accommodate users. ~]4ITI GA TI , Provide alternative water supplies as needed until water supply is declared safe. iii 66 AMiI tONIUM HYDROXIDE --' rrosive or ORM-A T~T CH1VI Q UE :ONTA/2qMENT DIKES .., Water with d/ssolved chemical may be conta/ned (or dive,ted to impoundment area) by diking upper and/or lower bounds to limit volume of water affected and spread of contamination. CONSEQ UE1VCE Eamhen dikes may' become saturated with water and seep through or collapse, Additional water may cause overflow o£ diked area or water body boundaries. iV~_~TIGA TION Reinforce or modify dikes as necessary. Be alert to conditions that may lead to over~low or dike collapse. Remove contaminated water to impoundment or storage area for later treatment or disposal. TECt-tWIQ UE NEUTI:bkLIZATION . . . Application of a suitable neutralization agent to the contaminated water may reduce environmental hazards. C ONSE ~ UENCE Some neutralizing agents are themselves hazardous and must be handled with care. Improper application may lead ~o increased damage or harm. MITIGA TIO N Proceed with caution. Consult qualified experts for safe neutralizing techniques. TECHNI~ O~I AEP~kTION ... ~Nater containing dissolved volatile chemicals may be decontaminated to some de=~ree by aeration, air stripping, or air sparing techniques. These involve the use o£ air compressors and pe~oraced piping to bubble large quantities of air through the contaminated water body. C ONSE Q UE~¥CE T~e air bubbles entering ~he atmosphere will be contaminated with some amount of chemical vapors if the technique is e~/ective. i!" frfITf GA TIO?[ Consult qualified expe~ts for ad¼ce and assistance in obtain~n¢ and deployin§ necessary equipment. Apply alternative techniques where air emissions may pose a do--wind hazara. O ', uM HYDROXIDE SATURATED lIQUID. DENSITY LIQUID HEAT CAPACITY LIQUID THERMAL CONDUCTIVITY LIQUID VISCOS}TY Temperature Pounds per cubic Temperature 8dtish ~errnal unit Temperature 8ddsh thermal {de<jrees F') tool (degrees P-') pe¢ pound-F (degrees F) unit-inch per hour- Tempera~re .......... squ~ue toot-F (degrees F) Centipeise 10 56.64O 34 1.000 · N N 15 56.530 38 1.0OO O O 29 56.430 38 I 1.0OO T T 25 58,330 40 I 1 30 56.220 42 i 1,000 p p 35 58.120 44 i t.0OO 40 55.010 46 ~ 1.000 R R 45 55.910 48 1.000 T 50 55.810 50 1.0oo 55 55.700 52 1.000 N N 60 55.800 54 1.000 E E 65 55.490 56 ~.00~ N N 70 55.390 58 1.000 T 75 55.290 60 1.0OO 80 55. t80 62 1.0OO 85 55.080 8.4 1.0OO 68 1.O00 70 ! 72 1.000 74 ! .000 76 1.0OO 1'2.21 12.22 12.23 12.24 SOLUBIUTY:3N WATER SATURATED VAPOR PRESSURE SATURATED VAPOR DENSITY IDEAL GAS HEAT CAPACITY Tempera[ute Pounds per 100 Temperature Pounds per Temperature Pounds per cubic Tempera~Jre · (degrees F) po~nd~ ol water (degrees ~ square inch (degrees F) loot M O 0 N I A A O S T T T C A A I p 8 N N E L O O R E T T T A A N V V E A A N I I T L L A A 8 8 L L J ~' 8IOTECNNOEOGY CONTRIBUTING TO FOOD, H~UTH AND THE ENVIRONMENT April 23,. 1989 CHLORINE SAFETY PROCEDURE General Characteristics Chlorine is a 9r. een gas with a pungent, irritating odor. It is heavier than air and clings to the ground. Potential Hazards Chlorine reacts rapidly with numerous chemicals. A fire may result from some of these reactions. An acid will form when chlorine is exposed to water. Containers may rupture and explode during a fire. Contact may cause severe skin and soft tissue (eyes, nose, etc.) irritation. Breathing chlorine could cause permanent respiratory damage, even death due to affixation. Water runoff from a chlorine leak coutd pollute a water supply. Reaction with water vapor in the air could cause pollution. .. Usage Points Chlorine is injected into the cooling tower sump at each sump pump. Chlorine is also injected into the water well line feeding into the house water tank. Two one (i) ton chlorine tanks supply four roto meters from the southeast corner of the cooling tower. First aid Do not attempt to rescue a fellow worker without an MSA air pac and chemical suit. Do not enter a leak area alone ---use the buddy system. Only fully trained personnel shall use the emergency equipment or enter the leak area. Personnel shall be trained annually in the use of the MSA air pacs and chemical suits. Use the following procedure in treating injuries: a. Move the victim immediately from the contaminated area to air. b. Check the victim's breathing. If breathing has stopped, use' CPR. c. If breathing has stopped, call the paramedics at 911. d. If breathing is O.K. and skin, eyes, or clothing have been exposed to chlorine use a safety shower or eye wash to flush the affected area. e. Refer to the attached M.S.D.S. for further information. Gist-brocades Food Ingredients Inc. 5455 District Blvd Bakersfield, CA 93313 (805) 834-1050 Chlorine Safety Procedure Page 2 of 3 Spill Response Major Spill: A major spill is one of 10 pounds or more, ioeo, more than 53 cubic feet (396 U..S. Gallons) of chlorine gas, assuming an ambient temperature of 65 F and a pressure of I atmosphere. A major spill must be reported to the National Response Center. Reporting\ is done through the Local Administration Agency, or L.A.A., the Bakersfield/ · Fire Department is the L~A~A.. The LoA.A. should be contacted if, in the judgement of the on-site managemer a spill constitutes a reportable~quantity, i.eo, 10 pounds, or a spill poses a hazard to either health or environment. Failure to report such a hazard to the L.A.A. is punishable by fines up to $25,000/day, and criminal prosecution resulting in up to 5 years incarceration° If a major spill occurs, complete the following Procedures as quickly as possible: 1. Evacuate downwind areas° 2o Treat any injury. 3. Contact the L.A~A.: or Call 326-3979 6. Immediately'.call att ~surroundi..ng. neig-hbors.-fowi-evac:uation of areas. . ............ a. Contel (N~) @ 631-2355- · - ........ b. Advance Beverage (NE) @ 833-3783 d. Southern Pacific (S) @ 321-4603 e. The Pump House, Inc. (SE) @832-6975 -' fo Vacant (SE) @ go Petrolite (W) @'83'4-5516 70 Call the emergency response contractor immediately° KES Kern Environmental Service ~-. (8Q5) 589-5220 Chlorine Safety Procedure Page 3 of 3 8. Contact all of the Gist-brocades response team: a. Carl Walker @ 398-7220 Pager: @ 329-1023 b. Lloyd Fry @ 833-8764 Pager: @ 329'2617 c. Bob Deedy @ 664-0248 Minor Spills: If a minor leak is detected, immediately don a gas mask; one of the two avai. lable in the area of the chlorine system.' If ~as'is ViSible, it'is not a minor leak;~ evacuate immediately. Determine'the cause of the minor leak, then call the immediate supervisor and safety coordinator for instructions. L1 oyd Fry Maintenance Engineer LF/s¢ September 26, 1990 CHLORINE UNLOADING PROCEDURE PRELIMINARY Inspect safety equipment. Review Chlorine sa. fe.~S ProcedUre in Business Plan. Prepare a solution of 5% (by weight) ammonia/water° Notify direct supervisor and maintenance engineer when truck arrives° Brief delivery'truck driver on the procedure and the location of the safety equipment° Locate truck chocks. Get qualified 2nd person to man self contained breathing equipment and capping kit. PROCEDURE 1) Chock delivery truck° 2) Lube overhead crane. 3) Relocate movable lines and equipment out of the way of 'the overhead crane° /Lower the full tank in place using the crane° Guide 'it slowly into place° Open container of 5% ammonia/water (commercial window cleaner.will do) and place it under the tank valve. 6) If a cloud forms then the tank is leaking and cannot be accepted° Mai-~i'tenance Engineer' September 26, 1990 EMPTY CHLORINE CYLINDER LOADING PROCEDURE PRELIMINARY Inspect safety equipment. Review Chlorine safety ProcedUre in Business Plan. Notify direct supervisor and maintenance engineer when truck arrives. Brief delivery truck driver on the procedure and the location of the safety equipment° Locate truck chocks° PROCEDURE 1) Chock delivery truck. 2) Lube overhead crane° 3) Replace caps and cover on tank if not already done. 4) Relocate movable lines and equipment out of the way of the overhead crane. 5) Use the crane to lift empty tank on to the delivery truck° Make sure latches are tight and move the tank slowly. The truck driver should guide it safely in place and secure it for the return trip° 6) Remove chocks from tires. L1 oyd Fry Maintenance Engineer September 26, 1990 CHLORINE ROTOMETER MOUNTING PROCEDURE PRELIMINARY Inspect safety equipment. RevieW Chlorine safety Procedure in Business Plan. Prepare a solution of 5% (by weight) ammonialwater. Notify direct supervisor and maintenance engineer° Make sure that pump I or pump 2 is operating° This will cause a steady draw from the chlorine tanks° Get qualified 2nd person to man self contained breathing equipment and capping kit. PROCEDURE 1) Close tank angle valve and remove rotometero 2) Reinsert the rotometer, assuming,it has been inspected by maintenance. 3) Open container of 5% ammonia/water (commercial window cleaner will do) and place it under the tank valve° If a cloud forms during valve adjustment, chlorine is leaking. 4) Open the tank valve a one-quarter turn then close back. 5) Open container of 5% ammonia/water (commercial window cleaner will do) and place it under the tank valve. If a cloud forms during valve adjustment, chlorine is leaking° 6) If no leak occurs, open the tank valve one-half turn. 7) Process all paperwork. Notify supervisor° Report any incidents. L1 oyd Fry Maintenance Engineer P~e .'. TOX~CAND/OR CORROSIVE:,. Produ~ 40 NON FLAMMABLE ' ' Ammonia ......................... 1 40' Boron Trichlorid~ .................... .40 STORAGE INSTRUCTIONS ' ' Boron Trifluoride .............. 41 Store ~ we~-ven~te~ pl~t ~ea or keep '~ covered Bromine pentzfluoride ......... 41 outdoor ~ez, prodded ~ders ~e k~pt off ~ound . Bromine Trifluoride ......... . ....... 41 ~d zwzy ~om r~t ':" BromotrifIu°r°e~hYlese .......... 42. cAUTiON:' Ay. aid brea~ing or skin: conta~ with ." Chlorine .... , .... ' .......... 42 these g~-- Use- ~on~l prote~ive equipment .... "' Chlorine Trifluoride .............. 42 emergenci~. Get medi~t a~endon if exposed. - ' . ,: Fluorine ................ . ...... 43 USAGE PROCEDURES '' Hydrogen ~romide .......... ~ ....... ~3 ' ;'.~: :"' Hydrogen Chloride .......... . ......... 43 Do ~o~ b~ez~ ~s. Hydrogen Fluoride .......... 43 cia~. Use ~ Hydrogen Iodide ...................... 44 e~u~me~t comp~[~b[¢ Iodine Penn,fluoride .......... ~ s~c~. K~p o~, ~s~, -. .pe~iuoro-2-Bu~ene .............. . . . . 44 ~wzy [~m o~c~. ~se o~y ~ cLose~ syst¢~ ~- Phosphorous Pentafluaride .......... 45 stmct~4 ~d de~cd to ~,4 pressures ~volwd. Silicon Tat~iuoride .............. . /45 Close v~vc when not'~ ~e or when emoty. Suifu~l Fiuoride .................... WAHNING: Suck-back ina cylinder ~n cause expire sion. Always use avacuumbreakara~herpro~e~ivea~ Far,us in any line ar piping from ~e ~iinder · , / prevent suck-back- '~ EMERGENCY PROCEDURES; --- · ~ ~' ~D: ~t mc~ ztt~ntion ~ztely for p~rso~s ~scd. to ~s~ ~s ~v~n ~ no ~p~o~ ":~ from expo~r~ to ~s~ g~ses ~ ~Md~nt. R~f~r to spe~%c g~ for more dct~ ~ ~e a~uisu~tion of f~st Md, k' app5~blc. ~ ~c of con[aa .~ eyes, · r_L ~ush cycs ~th cool 'wa~r for at Icas~ t5 ~u~cs. C ~ ~c of contact ~tk s~, flu~ s~ wi~ plcn~ :ff-,pL;:v~ cont~atcd cto~g ~d ckoes. Wash clo~g befor~ ...:..::., Mct~ to fresh ~. ~ not brest~g, ~ve ~%ci~ . - .... ~.-:..-; . :.~;-~.~:;T;.L:~j : respir~don. . . If. brea~g is. ~cuLt, eve .. o~gen'. .:;%'f?,.i'.%-L LE~. E,acuzte area ~d keep perso~e[ up~d. Use ' : ~~ ~~ . ~g'md ~ut'off leak ~ ~tkout. ~., . ' ' ':' '" .'.:" :' " ""' """ .,. . ':;;;..~:~;/;a~:¢~mo~d~:.~-~-t~.:~ ...,..... . ...... .:. :.;:.::' · j~-:' ;;~.~:}-:' ;i~'C;:.;; ~L.' ""~: "' ' . · ....... ~ EMERGENCY:-" C~. U~0~ ~biB~ Co~omdon's .. : .-... .........;:...,:~;.:.;.~. ::: ~=~o~,.~,a~-..~¢- ~;oo~y~ · . ':' :,'-:".~...:'.'.:'"... :"L ' " - ' · .' '::...:."?:'~:3~?:1'~ ;'.: ' "~ ........'-.:"':':~'.?.~'::~;%::/;:?.b~;,~¢~:omo,~.~ ..'..-. ;;;..:: ~'::."y:.::..C;':;::::~;;,??; .; ::,;;.. '.: ~;..' :;. :; ..; .. '....-.... .. .. ., .. ' .' .:. "...,.-. ,,.::.:.'_' ....::.......... - . :~' . ~..~ .... :~::'?::;~':'?'::: "L..' ..... :" '"' ' ~8 ':' '"' ·" ~'' :';'":'-'"'?';: ~'"': :" '-.-' ' '.'"' .'-' '," ''~'':' ''':~ "~:-: '~' ' '" ; -~ '' '" '"'" '' · :',-~-' -..h.. . . . .." · ' '....." :,' -'~..':La'?&;:L'":'/'~ .'.._~E. ;-',: ".;~ '.' ..'' : - "..,.... .' , · . ~ . .,.,...~.' -.... _ ' - ' -,< - ' -r'"'..:"~;;;';~,i', ..: ,~'...:.-::'-" .': ." .'-'..;..:; ". ', .,' '.' .' :., ~'...~..' . . ' .-::~]~ :. · ...... i ' .,..',.:~.,' :~.~.." .; .-'..:'.' ' :'" '; .... . .' · . ' ' :: ' ' · · · ' · · '. ·" ' ..' '- -' ..... . " '" ' ~ '~.~ ~.--r~:~¢.~.~Z,?:'~:'.~:T,'' "- .:' -' ".' / ' ' ' ' ',: ........ - .........~'"':~":~"i;~:'?: "':~%~7:"~' :~': "" ""' '-'"""" ..... "'" ..... ?' · : ~,.--=--~-,~:~.,.:~ .. ,.x~ . :. ,~ .... . .... ...~ ............ , ..... · ........ . ..... - ....... .~--..¢-.........: :--.~---,.-,~.: ........ . . . gas which is an oxidizer: {t is shJp~d at ~. ~por J:~.' of 320 psig at 70°F. it caul'severe-burns on con~c~ pressure of 8E ~ig at 7O°F. ~t causes bums on con~a~- J, ? with [he'eyes,.skin-,and mucousmembran~. '... ,... · ' with eyes, skin and mucous membrane.. ~.~.~r · · '. ...... .... MAJOR HAZARDS:. Inhalation sad 8odily Con~~ MAJOR H~AR DS: Inhalation and 8odily Con.c: ~ TOXICI~: Highly Toxic; T.L.V. of'3 ppm- ". TOXICITY: Highly Toxic, T.L.V. of 1 ppm. FIRE. POTENTIAL; Nonflammable-, .- ' FI REPOTENT[AL: Sup~Combu~Jon ~'~.. ODOR: Irri~adng . ODOR: Pungent, Irri~a~ing ~ DOT LA,ELS: Nonflammable Gas DOT LABELS: Undi O~31, ~978: SPEC~F1CVOLUME: 4.~cf/~b ..... Nonflammable Gas ~: H~ -- A colorless, irritating, corrosive, highly toxic, SPECIFIC VOLUME: 5.4 cf/lb liquefied ~cid ga~ which i~ ~hip~d a~ im va~or pre~sure ~'~'~', ,.7'.:~"' of 513 psig a~ 70°F. It ~use~ severe burns on contain ': with ~e eyes, ~kin, and mucous membrane. . MAJOR HAZARDS: Inhalation andBodil~Con~ac= ~~HLORINE TRIFLUORIu~:~ c~'~:.~: .-. TOXICITY: Highly Toxic, T.L.V. of 5 ppm . FIRE POTENTIAL: Nonflammable ~F3 -- A colorless, irritating, highly corrosive, highly ._. ODOR: Pungent, Suffocating ~oxic liquefied g~ which vigorously r~ac:~ with or~anic DOT LA,ELS: Nonflammable G~ com~und~ and also many inorganic commune. I~ SPECJFICVOLUME: lO, cf/lb causes severe burn3 on con~c~ '~th eyes, skin and MAJOR HAZARDS: ~nhaladon,~e~m~i~,Bodily HF A colorjet, highly ~oxic, highly corrosive, C~n~c~ J queried ~cJd ~ which is ship~d a~ i~ vapor pressu~ TOXICI~: Highly Toxi~, T.L.V. of 0.~ ppm FIRE POTENTIAL: Highly Oxidizing of 1 psig ~t 70°~, , Jt vigorously a~cks eye, skin ODOR: Swee~lrrit~ting and mucous membrane~. DOT LABELS; 'Corrosive SP~CIF1CVOLUME; 4.2cf fib MAJOR HA~R~: [nha{ation,~odilyCon~, FIRST AID: In ~ of cont~ wi~h-skin, in Re~ivi~ addition to pro,dura oudined a~ve, aher flush- ' TOXICITY: Highly Toxic, T.L.V. of 3 ppm ing contaminated area of con,am, pay ~icular "' FIREPOTENTtAL: NonJlammable . .-. . a~endon [o ~kin under:naii~. Follow by aOplying ODOR: iced alcoholic or aqueou= 0.2% Zephiran chloride OOTLABELS: ColD, ire or Hyamine 1622 solution, if no~ available, corn SPECIFIC VOLUME: 19.3¢/Ib tJnue ~shin9 in cool ~ter for 2 to 4 hou~ or FIRST' AID: In ~ o~ contact wi~h skin, until medi~la~entionlsobtained, addition to.pre~du~ oudined a~ve, 8~ter flush- , ing conmmmated area of contain, pay pa~icular a~entJon to skin under, nails. Follow. . by applying ..' · iced alcoholic or aqueEus 0.2% Zephiran chloride or HyamJne 1622 solution. If not available, corn F2 -- A. pa~e. yellow, highly toxic, h~ghly co~osive, ;",':~:." vigorousJy reac~ with almo~ ~1 organic'and [nerganic ~~_ HYDROGEN I ODIDE.~.~ sub~ances. It csuses severe burhs- on conm~ with' ' :.. eye~,skin or mucous memhrane~. HI --- A colorjet, highly, toxic',, highly corrosive, ,. ,. . . queried acid.-, which', d~ompo~ in ~he- pr~n~: of MAJOR HAZARDS~"lnhalation] Reamivi~, B~ily heat', or light;_. It: c8u~. severe., burns: an con.ct .. - ,:. with ey~;'skin and mucau~ memb~nes.:- ' quid. and gaa' - capable: o E..causing.. a.' burn.. "'. . .: '. quid and. gas' -- capable of causing' ~ burn. 3r likely a. problem because of burn and because, i~ ia a. gas.. ' .... _.ppm (197~) __.~.a~_on eyes, ~sal. & ~oa~: !icings. L~mg injury, I Eye & S~n' l .... ~d~ca/y re~ve canta~ted, clocking-' ;~ .~ ~ flushing the skin in a shower; f~r eyes, ~diata!y fl~h. :h~ ~ for' at !east 30 mfnutas and get. ~dical a~tannion, iriaalation: i~x~u~ On any and. all si~ af ill e~ecz~, pr~[!y re~ve ~erson to ~-,r~ fresh air, keep him warm and. quiet and get ~dizal attention ~j~o~,.~ i,~-;adia~e/y. Scarf arz/f/c~l rasp/ration, if breaching scous.. ,.r~ Ingestion; Noc !/l~!y a oroble=. 15 liquid ia swallowed, do ~ .r non /nd~e vomiting; give'~!k, wa[er, ~lk of ~gnezia and col1 ~ sr la ohysic~n .i~ed~na!y. Prevent ail. concoct -- s2in eve and T ~ ~r~ala~/~n. ~z expos~e occ~s, e~acts fr~ ir~alarion should~ ra~ be. !oo~d. for firsn and. treats& even. thcu~ skin. and. eye ccncacZ. ( I~y' have: occurred also. . Sufficient: to 'cent:o! ~V.. ~s 1. pp~ -- nsne; i pp~ ~ 25 fer' !0 ~nu~es- ~ !es~,. a~ ~!l face ~'sk. and acid. gas canister; ~ea~ar, ~ self-contained, brea~hing~ appara.r~ or- equ/va!en:'. K~bbe_.,, ~- gloves, auron, an& boo~s and ~!! fkce. shield, ova=- eve.. procecrion. ~-,o~,.,~, ~' Eve fountain· and:' safatw showers: am'work scation'. No:.~ aCuemp~ shoul*d:~ Be5 ~d~, to¥'handI~, o's'scota' ~klorin~w-ithou~ review. 0'~7' thru: ~' Ch'!o=inez Handboo~:and/o~ th~..: Ckiorin~-~n~X,. a.va-i!able-. from:, the-:: Chio.rine, Institute-... " ':.' . · .-. COY/ CHF~MICAL U. $. A. . ..... glDLAND'. [IICHIGAN 48840 : November' !3', 1974 Chlorine, Liquid : S.c~to~ 2 IHGR F. DI~NT~ %. ~'I~, Chlorine S.,ctla. 3 PH'I'SIC..LL gAT.L None '~ , t~ .... ~. None . . ~as ~s~a or se-_-c~nca2nad b~ea~hin ao~aratus far reso!rat~r7 protection and ~To:ectiye clothing. .An e!evana~ [~oerau,~es (>30O~F) ~y react. =o cause :ire. and/or' e~losnon u~n con=act with ~ny organic comgo~nda, a~nia, hydrogen, steel, or' finely divided S.c~o.- 5 REACTIVITY DAT~. ~OL.Y~ ~ ~1~. ~ OCCUr: · TtON- . ~ILL. NOT OCCU~ S.c~i.n. 6- .SPILL OR' LEAX' PROCEDURES. Nove'unproCeeEed.. personnei upwind.. Close:..nec'essary' valves with' trained pe-'nonnaI., using presc=ibed, procec~Lve~, equipment.. Ch'tOr~ne. w~y be-. absorbed.' ~n' Ca~ r.~:- NaOH)',..~.soda: ~'s~- ~.~a'2C02) REGISTRATION .-~ , .. ~ MATERIALS FORM This form MUST.be completed by the owner or operator of EACH business in California which, at · any time, handles' :Acutely Hazardous Material in quantifies, or in a mixture; equal to or greater than the Federal Threshold Planning ~Qt?an. titles for-Extremely Hazardous Substances~ Submit this completed form t° your local Administering Agency. '(§25533 & 25536 Health& SafetY Code) ............ ' Note instructions on rever~e .... _.~._,. ......... 5455 Di'strict .BlVd . Bakersfield, Ca. .93313' - ::3:, ACI.1TELY HAZARDOUS MATERIALS HANDLEEP .':y?--'z -USE ADDITIONAL PAGES IF NECESSARY-. CHEMICAL NAME '; ' - ' ' - ~ REGEiV,"o GENERAL DESCRIIvI'ION OF PROCF~gSES AND PRINCIPAL EO?IPIVIEN~: AnhydroUs Ammonia: Mixing Anhydrous Ammonia with ~oftwote'r in a reactor, cooljn9 down in'heat exchanger and making Amm6nio~'Hydroxide for fermentation process. ' .... TITLE Pro,iect En,qineer I I Ashok Pandya CaJlfornln. Office o4' Emergency Services FORM HM3777 (11 - 12 - 89)' 1-3 TO: All Supervisors MAY ? 1992 FROM: Ashok Pandya SUBJECT: Anhydrous Ammonia Training There will be Anhydrous Ammonia Training conducted by Unocal on Wednesday,~May ~3, 1992-a-t 1.0-:-O0-a-..m. and_2.:O0 p.mo_ i.n She]Unchrogmo This is mandatory for all affected department. Ashok Pandya Project Engineer AP/sc cc: Bob Deedy Local Fire Dept. Don Mordyke (Unocal)~ Barbara Brenner GB-O30-DP IOTECHNOLOGY CONTRIBUTING TO FOOD, HEALTH AND THE ENVIRONMENT May 1, 1992 Ms. Barbara Brenner City of Bakersfield Fire Dept. 2101 "H" Street Bakersfield, Ca. 93301 Dear Barbara: This is to inform ~ou-th~t Gist-6ro~a~6~ Food Ingredients, Inc. has discontinued the services of Luft Environmental Engineering. Gist- brocades will be handling the completion of the ammonia RMPP. We will submit a revision to the RMPP based on your most recent concerns as well as the comments you provided on the draft responses from Luft that you were kind enough to review for me. I have decided to begin utilization of the ammonia conversion system based on your conditional approval. I expect the first delivery of ammonia the week of May llth. We will contact the local fire depart- ment to set up training on the system. Because I need to become more familiar with the RMPP reporting require- ments as well as research the materials to satisfy your concerns.it may take a couple of weeks for me to prepare my responses. I will most likely give you a call to discuss my proposed response prior to a formal submittal. I appreciate the patience and cooperation you have given to me in this matter and please don't hesitate to contact me if you have any questions. Bob Deedy/ cc: Ralph Huey Ashok Pandya Gist-brocades Food Ingredients Inc. 5455 District Bivd, Bakersfield, CA 93313 (805) 834-1050 Fax (805) 834-6212 Busch Industrial Products Corporation ONE OF THE ANHEUSER-BUSCH COMPANIES July 3, 1987 Bakersfield Fire Department Hazardous Material Division 2130 G Street Bakersfield, Ca. 93301 Enclosed is the Business Plan for Busch Industcial Products Corp' concerning hazardous materials i~ '. If you have any questions or need further information, pi~ase contact 'ii~' me at 834-1050. " Richard Hughes :~;.' Plant Engineer :cs 5455 District Blvd. Bakersfield, CA 93313 (805) 834-1050 BAKERSFIELD CITY FIRE DEPARTMENT R E C ~0 2130 "G" STREET 'BAKERSFIELD, CA 93301 JUL ? r't (805) 326--3979 Ans'd ............ OFFICIAL USE ONLY ~USINESS N~E HAZARDOUS lVIAT E R I ALS BUSINESS PLAN AS A WHOLE FORI~I 2A 1, To avoid further action, return'this fopm by 2. TYPE/PRINT ANSWERS IN ENGLISH. IA ~ 8. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: BUSCH INDUSTRIAL PRODUCIS CORPORA/ION B. LOCATION / STREET ADDRESS:5455 DISTRICT BLVD. CITY: BAKERSFIELD, CALIFORNIA ZIP: 93313 BUS.PHONE: (805) 834-1050 SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material,, call-911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS. A. MICHAEL K. HILLBERR¥, Plant Manaqer Ph# (805) 834-1050 Ph# (805) 832-5766 <~B. RICHARD HUGHES~ Plant Enqineer Ph# (805) 834-1050 Ph# (805) 398-1404 SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: "N" of building between drive and block wa]] B. ELECTRICAL: Main power room, above process, C. WATER: City Water valve "W" end of building, between bU]lOlng ano wager ~ank D. SPECIAL: E. LOCK BOX: YES /~IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO SECTION'4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE We currently do not have individual response teams set-up. We are working on this now. We were handling this by cross training all employees in all areas.. Schedule for completing response team assignments is as follows: 1. Evacuation - - July 10, 1987 2. Fire and injury - July 15, 1987 3. Chemical spill - July 30, 1987 4. Natural disaster - August 15, 1987 SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE All i~jury,'.~r accident cases are referred to: White Lane Emergency. Located at 5401Wh~teL~L~he~ Avenue, Bakersfield, telephone (805) 832-2000. · ~ ~' ~.~. We have a company'-physician who works at Mercy Hospital, Dr. Stephen Helper. Plant employees are trained and certified in C.P.R. and First Aid,' Update of.C.P.R. and First Aid training is done every two years. For ambulance service we use Hall Ambulance, telephone (805) 327-4111. For General Emergency we use the 911 service. SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES. OR NO INITIAL REFRESHER A. METHODS FOR SAFE HANDLING OF'HAZARDOUS MATERIALS:...- .................................... /YES/ NO YES NO B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGENCIES: .......................... /YES/ NO /~ES/ NO C. PROPER USE OF SAFETY EQUIPMENT: .................. 7~'~-7'NO YES NO D. EMERGENCY EVACUATION PROCEDURES: ................. YES /NO/ YES NO (IN PROGRESS) E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... /YES/-~-~ ?YES/NO SECTION ?: HAZARDOUS MATERIAL CIRCLE/YES/OR NO DOES YOUR BUSINESS-HANDLE HAZARDOUSMATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS:..i... /YES /NO I, RICHARD HUGHES , certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 Et Al,) and that inaccurate information constitutes perjury. BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY BUSINESS NAME: BUS I NESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below, for THE FACII, ITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. - FACILITY UNIT# 3 FACILITY b~I~ NAME: BUSCH INDUSTRIAL PRODUCTS CORPORATION SECTION 1: MITIGATION, PREVENTION, ABATEMENT PROCEDURES Please refer to attached "Environmental Incident Plan." SECTION 2: NOTIFICATION AN~ EVACUATION PROCED5~ES AT THIS UNIT ONLY NOTIFICATION: Please note attached In~ernal and External Reporting Charts, contained in Environmental Incident Plan. SECTION 3: HAZARDOUS~+~IATERIALS FOR THIS UNIT ONLY A. Does this Facility Unit contain Hazardous Materials? ...... /YES/ NO If YES, see B, If NO, Continue with SECTION 4. B. Are any of the hazardous materials a bona fide Trade Secret YES /NO / If No, complete a separate hazardous materials inventory ~4A-.~) form marked: NON'TRADE SECRETS ONLY (white form ~ -~ , ' ed If Yes complete a hazardous materials inventory form mar,<..,: TRADE SECRETS .ONLY (yellow form #4A-2)'in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION 1. We have smoke detectors ~n office, laboratory and power room above laboratory. 2. Computer room has a ha]on system. 3. Coo]~ng tower has a sprinkler system. 4. Dry storage, maintenance shop and maintenance storage area have sprinklers. 5. Sma]] f~re ext~ngu~she~throughout plant. 6. Smoke detectors and spr~nk]er~systems tied ~nto switchboard of, "Crime Co,tro]." SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS [~re hydrant located ~n ]awn area, "W" of Coo]~ng Iower and "S" of mo]asses tanks. SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS ~N~T ONLY. 6as shut off and meter located "N.W." corner of building between drive-way and block wall. B. ELECTRICAL: Pacific ~as and Electric transformer located ~n"N.W.!' corner of parking lot. Ma~n 41 60 ¥.A.C. d~sconnect located ~n..ma~n power roam, uDDer ]eve], rear of bu~]'d~ng, above process floor, ',S,W." corner of main build,D§. C. WATER: C~ty Water ma~n cut-off located ~n pit on ]awn ~n front of bu~]d~ng, "S" of D~strJct Boulevard. We also have a ma~n shot off ~n header between "W" s~de of bu~]d~ng and water tank. We]] Water can be shot off by sw~tch off pumps located on outside, "W" s~de of obuil~i~q, behind water tank. #6 Fuel Oil pumps can be shut off by switches located on "E" wa]] of.o~] tank retainin9 wa]], behind o~] pumps. E. LOCK BOX: YES ~NO / IF YES, LOCATION: IF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS?' YES / NO KEYS? YES / NO - 3B - ' SITE/FACILITY ) I AG Rk'~l NORTHi_i SCALE: 1":40' BUSINESS N~%~E: BUsch Industrial Products FLOOR: 2 OF 2 Anheuser Busch Inc, DATE: 6./ 2/87 FACILITY N~E:]Bakersfie]d Yeast Plant' b~IT ~:1 OF 1. (CHECK ONE) .SITE DIAGIAa~ × FACILITY DIAGR.a3I UP, ~OOM t. CATWALK ~- '~ J(Insgector"s Comments): -OFFICrAL USE' O~YLY- BAKERSFIELD FIRE DEPARTMENT I.D. # 4A-1 Pa of .2, NON--TRADE SECRETS HAZARDOUS MATERI ALS INVENTORY BUSINESS NAME: BUSCH INDUSTRIAL PRODUCTS CORP. OWNER NAME: BUSCH INDUSTRIAL PRODUCTS CORP. FACILITY UNIT #: ADDRESS: 5455 DISTRICT BLVD. ADDRESS: 54bb UISIRIU{ BLVD. FACILITY UNIT NAME: CITY, ziP:BAKERSFIELD, CA. 93313 CITY,ZIP: BAKERSFIELD, CA. 93313 PHONE ~: '('805) 834-1050 PHONE #: (8Ob) 834-1Ub0 [OFFICIAL USE CFIRS CODE { ONLY 1 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS ~ BY HAZARD D.O.T CODE ANOUNT AMOUNT UNIT CODE !CODE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE GUIDE S.W. CORNER OF BUILDING M 23,000 615,000 GAL 03 18 BETWEEN DRIVE&BUILDING 25% ,AQUA AMMONIA CRMT HAZARDQ.U.S COMPONENT: -,, '---' ~,.AMMONIA HY--DROXIDE 25~ S.E. CORNER DF 4,000 23,000 LBS 04 05 COOLING TOWER 99.8% CHLORINE iC)S_Oy~ NFLG 'NENT:3~ S. END OF BUILDING ~ 700 2,400 GAL 02 18 OUTSIDE 99% SULFURI.C ACID }~)'~ ~O CRMT / HAZARDOUS COMPONENT: SULFURIC ACID 99% W. END OF BUILDING 5~000 45~800 GAL 02' 18 BETWEEN DRIVE&BUILDING 75% PHOSPHORIC AC'ID { ~;~ ~ CRMT HAZARDOUS COMPONENT: PHOSPHORIC ACID 75% ~.~ W. END OF BLOWER 5,000 48,000 GAL 02 08 BUILDING, E..END OF 50% CAUSTIC SODA (SODIUM HYDROXIDE) CRMT COOLING TOWER HAZARDOUS COMPONENT: SODIUM HYDROXIDE 50% -~3) M 1,800 1,800 GAL 07 36 W. END OF BLOWER BUILDING (OUTSIDE) 39% IODINE DETERGENT SANITIZER ~jo CRMT ..... HAZARDOUS COMPONENTS: .PHOSPHORIC 18.5% ACID ALKYLPOLYOXYETHYLENE POLYOXYPROPYLE~IE 13.1% ~ IODINE COMPLEX NAME: RICHARD HUGHES TITLE: PLANT ENGINEER SIONATURE: ../~,...~w¢...~ ~z/~'~i~.~ DATE:~ ~---~' EMEROENCY CONTACT: RICHARD HUGHES TITLE:PLANT ENGINEER pHONE/# BUS HOURS: /805) 834,1050 AFTER BUS HRS: (805) 398-1404 EMERGENCY CONTACT: MICHAEL K, HILLBERRY TITLE:PLANT MANAGER . PHONE # BUS HOURS: /805) 834-1050 PRINCIPAL BUSINESS ACTIVITY: BAKER'S YEAST MANUFACTURING AFTER BUS. HRS: /805) 832-5765 BAKERSFIELD CITY FIRE DEPARTMENT NON--TR SECRETS HAZARDOUS MATERI ALS INVENTORY -' BUSINESS NAME: BUSCH INDUSTRIAL PRODUCTS CORP, OWNER NAME: BUSCH INDUSTRIAL PRODUCTS CORP. FACILITY UNIT #: ADDRESS: 5455 DISTRICT BLVD, ADDRESS: 5455 DISTRICT BLVD. FACILITY UNIT NAME: CITY, ZIP:BAKERSFIELD, CALIFORNIA 93313 CITY, ZiP: BAKERSFIELD. CALIFORNIA 93313 PHONE ~: 805 834-1050 PHONE #': 805 834-]!050 ]OFFICIAL USE CFIRS CODE ONLY 1 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS .% BY HAZ'ARD. D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE 7M DRY STORAGE AREA "E" OF 65 256 GAL 10 39 LABORATORY, "S" OF pACK- 25% BONCHEM MIKR0-FOME 0RMA AGING AND SHIPPING -- HAZARDOUS COMPONENT: SODIUM-I DODECYLBENZENE SULFATE 1~5 ~ ,-~ CHEMICAL STORAGE ROOM · ~ M 1000# 3000# LBS 07 05 "S',' SIDE OF PROCESS 65% CALCIUM HYPOCHLORITF I~_z~ CRMT '1 HAZARDOUS COMPONENT CALCIUM .HYPOCHI ORITF ~M FUEL TANK ON "W" SIDE 23,000 190,000 GAL 02 19 O~ BUILDING AND "E" #6 LOW SULFUR FUEL OIL //~ CMLO SIDE OF WAREHOUSE NAME: TITLE: PLANT ENGINEER s GNATURE :/~z.~ ~_.z~.~ _~ DATE: ~--7~-~-~ EMERGENCY CONTACT: RICHARD HUGHES '~ TITLE: PLANT ENGINEER pHON~~ # BUS HOURS: ~805~ 834-1050 AFTER BUS HRS: C805i 398-1404 EMERGENCY CONTACT: MICHAEL K. HILLBERRY' TITLE: PI.ANT MANAGFR . PHONE # BUS HOURS: PRINCIPAL BUSINESS ACTIVITY: BAKER'S .YEAST MANUFACTURING AFTER BUS. HRS: (805) 832-5765 W Busch lndustllal Inter-Office - ' ~~~,?" Correspondence June i0, 1987 TO: ALL PLANT- EMPLOYEES FROM: CARL WALKER EMERGENCY RESPONSE TEAMS We are going to form three Emergency Response Teams and we need volunteers for this. Team 1 - FIRE .& INJURY (medical emergency) to be headed by Jerry Freeman Team 2 - CHEMICAL SPILL to be .headed by Mike McCoy Team 3 - NATIONAL DISASTERS (earthquakes, etc.) to be headed by Dirk Willard We need volunteers to sign up by Wednesday, June 17th for' these teams and these individuals will receive', training in Emergency Response. Safety Coordinator :cs TEAM 1 TEAM 2 TEAM 3 BAKERSFIELD YEAST PLANT " E~¥IRONMENTAL INCIDENT PLAN 1987 INTERNAL P£PORTI NG CHART FOREMAN/SuPERV! SOR , M.,.MCCOY 833-6645 d, FREEMAN 836-0885 .... Q,WALKER .......... 398-7220 ..... . ..... RA!idH. COORDINATOR ( pLANT'EN~i'NE~ "'i ..... > . AF ~,ENSEY HOME 834-233~ 'D,' HuGHEs 398-1404 I i ~ C,WALKER ~398-7220 PAGER 329 -4946 'OFFIC~ ' '835=8385 / ' \ ~.L./~[T_I~N~ . >CORP. ORATE MANAGEMENT M,HILLBERRY . JOHN RIESCH ..... HOME .892-5765 i OFFICE 1(3110 577-710] '-" i'HOME'"I(314) 645-92S9 ..CO~OI:~-[E ENVIRONMENTAL... CORPO[~IE RISK C,JOST OFFICE ~L:(314) 577-4162 MANAGEMENT. AND · . HOME :[(314) 962-733~ 'INSURANCE d, STE I NOFF I CE1 (314) 5 77-416C d, W, ROBSON HOME 1(314) 227-7467 .......... !(314)_577-2318 I :F;d; HRUB¥ 1(314) 577-32021(" I s,J, CORTORP^SST EXTERNAL REPORTING· WORKER "SPILL" DAN ENSEY OFFIHoMECE 835-8385834_2337 ' / '.' q C'WALVER 398-7~2. PAGER 329-4946 DICK HUGHES OFFICE 834-1050 HOME 398-1404 M. HILLBERRY OFFICE 834-1050 HOME 832-5765 BAKERSFIELD CITY FIRE ~ I HAZARD MATERIAL DIVISON 'FIRE/RESCUE- (805) 326-3979 . AS NEEDED . . 911 or (805) 324-4542 i California Offic~ Of I EMERGENCY RESPONSE from Calif.(800)852-7550~ out of state ~ 1-(916)427-4341 [ t BAKERSFIELD POlICE . AS NEEDED . .. (805) 327-7111 REGION 9 EPA 1 (415) 974-8131 '' VACUUM.:TRDCK.'SERVICE M,P, VACUUM (805) 393-1.151 L KERN.VACUUM{'SERVICE K.C.A.P.C.D. ~S NEEDED AS NEEDED (805) 589-5220 861-3682 ~ DEPENDING ON TYPE (805) .~ OF SPILL ~ HAZARDOUS MATERIAL' NATIONA~E~ONSE L 'DISPOSAL.' COMPANY To CORP. i (800) 852-755o (805) 763-4171 AS NEEDED .... CHEMICAL WASTE MBT. (800) 222-2964 WASTE CONTROL SVC. (805) 399-4620 REPORTING'CHART'"SPILL'AT'RANCH" 'WORKER I IF TF~ N~ULU DAN ENSEY '1 ~ ~ JOE PAZ HOME 834-2337 ~_I_~ HOME 834-4012 WORK 835-8385 OR 397-8797 PAGER 329-4946 ! REPAIR CREW ~ DICK HUGHES 398-i404 MIKE MCCOY 833-6645 MASCO CONTRUCTION AS ~ MIKE HILLBERRY N. OLLIVIER NEEDED WORK 831-3703 832-5765 HOME 393-7828 i VACUUM TRUCK L AS AS K.C.A.P.C.O. M.P ,VACUUM~ NEEDED NEEDED 861-3682 393-1151 BACK HOE 'AS''" ....... WHITTEN EXCAVATION ~E'EDED GARY WHITTEN WORK - '834-8002 MOBILE- 327-3505 #8400 Internal Reporting Responsibi Personnel Responsibility' Worker Report incidents immediately; "no doubts, always report" Area Foreman or Supervisor Decide if incident .involves priority substance and report; report to Utilities Foreman if in doubt; initiate prescribed contingency plans Utilities Foreman Inspect, assess, take action, report; (Roving Engineer) seek confirmation on action if in doubt; initiate safety and health procedures or other contingency plan Resident Engineer Decide if incident reportable to agencies; (Environmental Coordinator) if in doubt, consult corporate staff; inform Plant Manager and corporate staff of decision; confirm action taken Safety Manager Confirms action taken; decides if local outside emergency units should be involved; assists Resident Engineer if inc.ident is reportable and demands immediate outside agency assistance Plant Manager Coordinate all activities involving incident; · inform appropriate managers; prepares PR agent and controls information flow. and actions taken Environmental Staff ~ Confirms decision to report to agencies; advises on corrective action; prepares PR agent; liason with Legal Staff Corporate Legal Considers liability issues and interprets laws and rules Risk Management Incidents may involve claims, will notify and Insurance various insurance companies. Note' The Environmental Reportin~ Policy attached requires reporting to outside agencies if for some reason the internal reporting scheme breaks down. Consult this policy for' this exception. Busch industrial Products Corporation TO WHOM IT MAY CONCERN: The purpose of this memo is to state that as of June 1, 1987, our Oil Spill Control Plan is under study and in the process of being rewritten. RI CHARD HUGH~S ma 5455 District Blvd. Bakersfield, CA 93313 (805) 834-1050 Busch Industrial Products Corporation OIL SPILL CONTINGENCY PLAN Any person finding an oil leak or spill should do the following: 1. Stop leak by turning off pumps or closing valves. 2. Contain the oil spill, by diking with quick sorb or sand. 3. Notify the appropriate people, using the Internal Reporting Chart located in this manual. The oil spill must be contained and the sooner the better. If at all possible, prevent oil from entering the drain system. This can be done by diki~ng or otherwise blocking the oil. By keeping oil out of the plant drain system, clean-up becomes a relative easy task. Should oil enter the plant drain system the next place we can stop and contain it, is in our L & N sump. This can be done by shutting off the three (3) L & N Pumps. We would then pump out and clean the sump and drain system as required. Should the spill go beyond the L & N sump it will contaminate the whole system from where it entered the drains to the tanks at the ranch. With quick enough notification to Dan Ensey, Michael Hillberry, or Richard Hughes, we can divert the lines at the ranch and bypass the contamination into the small tank. Once a spill has happened and we get it contained, we must clean up and dispose of the material. This will be done by an approved Hazardous waste disposal company. 5455 District Blvd, Bakersfield. CA 93313 {805) ,534-t050 SPILL ~NTION CONTROL& coUNTEPJ~EAS~PLAN P~RT I GENERAL INFOR~TION 1. Name of facility BUSCH INDUSTRIAL PRODUCTS CORPORATION., BAKERSFIELD.YEAST PLANT 2. Type of facility YEAST PLANT 3. Location of facility 5455 DISTRICT BLVD., BAKERSFIELD, CALIFORNIA 93313 4. Name and address of o~er or operator: Name BUSCH INDUS/RIAL PRODUCTS CORPORATION Address 5455 DISTRICT BLVD. BAKERSFIELD~ CALIFORNIA 93313 5. Designated person accountable for oil spill prevention at facility: Name and title RICHARD HUGHES~ PLANT ENGINEER i 6. Facility experienced a reportable oil spill event during the twelve months prior to Jan. 10, 1974 (effective date of 40 CFR, Part 112). ~L~NAGERAPPRO~AL This SPCC Plan will be J~plemented a.s herein described. Name MICHAEL K. HILLBERRY Title PLANT MANAGER CERT IF ICAT ION I hereby certify that I have examined the facility, and being familiar with the provisions of 40 CFR, Part 112, attest that this SPCC Plan has been pretm~red in accor~ance with good engineering practices. t>rinted Name of Registered Professional F~ngineer (Seal) Signature of Registered Professional Engineer Date Registration No. State PART I GENERAL INFORMATION 7. Potential SPills - Prediction & Control: Total Major Type Quantity Rate Direction Secondary Source of Failure (bbls) (bbls/hr) of Flow* Containment 1. No. 6 Fuel Oil a. Storage Tank Tank Rupture 525 Unknown Note #1 Yes b. Truck Truck or Line Unloading Rupture 83 Unknown Note #2 Yes (Ranch) c. Piping Rupture 5 Unknown Note #2 Yes (Ranch) 2. Lubricating Oils a. Drum Storage Rupture 1 1 Note #2 Yes (Ranch) Discussion: Note #1: Fuel Oil Tank is in~dik~ area. Note #2: No primary or secondary containment at unloading site. Spill would enter storm drain and be pumped to ranch where it could be held in 650,000 gallon holding tank. Attach map if appropriate. Plot Plan Attached. Name of facility Busch Industrial Products Operator Anheuser Busch Inc.~ St. Louis~ MO (Part 1) Page 2 of 3 GENERAL INFORMATION (Response to statements should be: YES, NO, or NA (Not Applicable). 8. Containment or diversionary structures or equipment to prevent oil from reaching navigable waters are practicable. (If NO, complete Attachment #2.) YES 9. Inspections and Records A. The required inspections follow written procedures. YES B. The written procedures and a record of inspections, signed by the appropriate supervisor or inspector, are attached. YES Discussion Proposed inspection forms and written procedures for inspection are attached. The #6 fuel tank will be inspected and level recorded daily. Oil pipeline will be inspected weekly when in use. 10.~ Personnel, Training, and Spill Prevention Procedures A. Personnel are properly instructed in the following: (1) operation and maintenance of equipment to prevent oil discharges, and YES (2) applicable pollution control laws, rules, and regulatic~. YES Describe procedures employed for instruction: The mainten~c~ supervisor will give appropriate on-the-job training to operating personnel recording the prevention of oil discharges. He will keep the operatin~ personnel updated as changes necessitate. Written procedures will be posted listing spill prevention Drocedures. B. Scheduled prevention briefings for the operating personnel are conducted fre- quently enough to assure adequate understanding of the SPCC Plan. Describe briefing program: The maintenance supervisor will conduct annual trainin~ sessions to review and update operating personnel on the SPCC Plan and current pollution control requirements. Name of facility Busch Industrial Product Operator Anheuser Busch Inc.~ St. Louis~ MO (Part 1) Page 3 of 3 (Prior to completing Far~li, alternate ~{, reler to regu±ao±ono ~L~d ~**c, OrUCoiO~s pages 6-7.) PART II, ALTERNATE A DESIGN AND OPERATING INFORMATION ONSHORE FACILITY (EXCLUDING PRODUCTION) A. Facility Drainage 1. Drainage from diked storage areas is controlled as follows (include operating description of valves, pumps, ejectors, etc. (No~e: Flapper-type valves, should not be used): A locked valve is provided to drain rain water from the concrete diked area to a dry well. tn case of an oil spill from tank~ a vacuum truck would be used tb suck oil out of pit and into a tank truck. 2. Drainage from undiked areas is controlled as follows (include description of ponds, lagoons, or catchment basins and methods of retaining and returning oil to facility): At times of unloading~ a operator or supervisor would be in constant observation. An oil spill from unloading station or truck would enter storm drains that are 25' from unloading station. It would then flow into a underground tank with a capacity of 14~000 gallons. All liquid in this .pi~ will be pumped out to 650~000 gallon storaCe tank at ranch and then held for deposition storage tank at ranch. 3. The procedure for supervising the drainage of rain water from secdondary con- tainment into a storm drain or an open watercourse is as follows (include description of (a) inspection for pollutants, and (b) method of valving security). (A record of inspection and drai.nage events is to be maintain~,d.~ on a form similar to Attachment #~)~ ~ ~' The maintenance suoervisor has only a~cess to key for valve in diked area. No water or oil can be drained from inside dike to outside. The dry well won't accept water from diked area. Any water or oil~must be removed by .pumping or vacuum truck. Name of facility Busch Industrial Products Operator Anheuser Busch Inc.~ St. Louis~ MO (Part II, Alternate A) Page 1 of 5 'l PART II, ALTERNATE A ~ DESIGN AND OPERATING INFORMA~'~ON ONSHORE FACILITY (EXCLUDING PRODUCTION) [(Response to statements should be: YES~ NO, or NA (Not Applicable).] B. Bulk Storage Tanks 1. Describe tank design, materials of construction, fail-safe engineering features, and if needed, corrosion protection: Tank is a horizontal welded tank fabricated to API specification 650~ material is ASTM-283~ grade C~ steel tank. The tank exterior is painted with one coat red oxide primer~ one coat 282E~ U Primer~ 2 mills~ and a finish coat 4310 E~ epoxy glaze~ 2 mills. 2. Describe secondary containment design, construction, materials, and volume: A reinforced concrete dike 41'x21'x5'6" high and constructed to hold 830 bbl.~ or 50~ more than contents of the tank. 3. Describe tank inspection methods, procedures, and record keeping~ The tank is completely exposed for inspection and is subject to daily visual inspections. Tank will be inspected weekly and results recorded on an inspection sheet. 4. Internal heating coil leakage is controlled by one or more of the following control factors~ (a) Monitoring the steam return or exhaust lines for oil. YES Describe monitoring procedure~ 1. Steam condensate flows from steam heating coil to a return tank located in molasses pitI then pumped to D.A. tank for reuse in boiler. Boiler water is checked by our lab daily. (b) Passing the steam return or exhaust lines through a settling tank, skimmer, or other separation system. N/A (c) Installing external heating systems. N/A 5. Disposal facililties for plant effluents discharged into navigable waters are observed frequently for indication of possible upsets which may cause an oil spill event. Describe method and frequency of observations: Human waste is the only matter we discharge into city sewer system. All other plant water and process matter goes to ranch~ and is checked before being land applied. Name of facility Busch Industrial Products Operator Anheuser Busch Inc.~ St. Louis~ MO (Part II, Alternate A) Page 2 of 5 DESIGN AND OPERATING INFORMA~N ONSHORE FACILITY (EXCLUDING PRODUCTION) [Response to statements should be: YES, NO, or NA (Not Applicable).] C. Facility Transfer Operations, Pumping, and In-plant Process 1. Corrosion protection for buried pipelines: (a) Pipelines are wrapped and coated to reduce corrosion. N/A (b) Cathodic protection is provided for pipelines if determined necessary by electrolytic testing. N/A (c) When a pipeline section is exposed, it is examined and corrective action taken as necessary. N/A 2. Pipeline terminal connections are capped or blank-flanged and marked if the pipeline is not in service or on standby service for extended periods. Describe criteria for determining when to cap or blank flange: Oil fill line is capped at all times~ except when tank is being filled. 3. Pipe supports are designed to minimize abrasion and corrosion and allow for expansion and contraction. Describe pi~e support design: All piping was designed and installed according to API standard~ 650. 4. Describe procedures for regularly examining all above-ground valves and pipe- lines (including flange joints, valve glands and bodies, catch pans, pipeline supports, locking of valves, and metal surfaces): When oil system is in use the maintenance supervisor and operating personnel will make daily inspection of all above ground piping~ checking for undue wear or impending problems. 5. Describe procedures for warning vehicles entering the facility to avoid damaging above-ground piping: All above-ground piping is ~uarded or protected. Name of facility Busch Industrial Products Operator Anheuser Busch Inc.~ St. Louis~ MO (Part II, Alternate A) Page 3 of 5 DESIGN AND OPERATING INFORMA~N HORE FACILITY (EXCLUDING PROD~ION) D. Facility Tank Car & Tank Truck Loading/Unloading Rack Tank car and tank truck loading/unloading occurs at the facility. (If YES, complete 1 through 5 below.) YES 1. Loading/unloading~procedures meet the minimum requirements and regulations of the Department of Transportation. NO 2. The unloading area has a quick drainage system. NO 3. The containment system will hold the maximum capacity of any single compart- ment of a tank truck loaded/unloaded in the plant. NO Describe containment system design, construction materials, and volume:~ We do not have a containment system at unloading station. . Any minor spill will be cleaned up using quick sorb mtl. A major spill would enter storm drain and be Dumped to a holding tank at ranch. A spill could be retained in this holding tank for disposition. 4. An interlocked warning light, a physical barrier system, or warning signs are provided in loading/unloading areas to prevent vehicular departure before disconnect of transfer lines. NO Describe methods, procedures, and/or equipment used to prevent premature vehicular departure: ~ None at this time 5. Drains and outlets on tank trucks and tank cars are checked for leakage before loading/unloading or departure. YES Name of facility Operator (Part 11, Alternate A) Page 4 of 5 .HOR~ FAC±LL'I'Y (~×CLUDING FHODU [Response to statements should be: YES, NO, or NA (Not Applicable).] E. Security i!, 1. Plants handling, processing, or storing oil are fenced. YES 2. Entrance gates are locked and/or guarded when the plant is unattended or not in production. YES 3. Any valves which permit direct outward flow of a tank's contents are locked closed when in non-operating or standby status. NO 4. Starter controls on all oil pumps in non-operating or standby status are: (a) locked in the off position: NO (b) located at site accessible only to authorized personnel. NO 5. Discussion of items 1 through 4 as appropriate: Valves not locked - wrong type Electrical starters are by oil pumps~ outside by tank. These items are listed on attached proposed corrective list. 6. Discussion of the lighting around the facility: The levels of illumination throughout the plant are in accordance with current edition of IES Lighting Handbook~ 2nd Edition. Name of facility Busch Industrial Products Operator Anheuser Busch~ Inc. St. Louis~ MO (Part II, Alternate A) Page 5 of 5 SPILL HISTORY (Complete this form for any reportable sPill(s) which has (have) occurred from'this facility during the twelve months prior to January 10, 1974 into navigable water.) 1. Date Volume Cause: Corrective action taken: Plans for preventing recurrence: 2. Date Volume Cause Plans for preventing recurrence~ 3. Date Volume Cause: Corrective action taken: Plans for preventing recurrence: Name of facility Operator (Attachment ~;1, SPCC Plan) OIL SPILL CONTINGENCY PLANS AND WRITTEN COMMITMENT OF MANPOWER Secondary containment or diversionary structures are impracticable for this facility for the following reasons (attach additional pages if necessary): Yes A strong oil spill contingency plan is attached. A written commitment of manpower is attached. Name of facility Operator (Attachment #2, SPCC Plan) ONSHORE FACILITY BULK STORAGE TANKS DRAINAGE SYSTEM Inspection Procedure: Record of drainage, bypassing, inspection, and oil removal from secondary containment: Date of Date of Bypassing Date of Supervisor's or Drainage Open Closed Inspection Oil Removal Inspector's Signature Name of facility Operator (Attachment #3, SPCC Plan) ATTACHMENT NO. 1 OIL FACILITIES INSPECTION AND DIKE DRAINAGE REPORT No. ~.Fuel Oil Piping Draining of Diked Storage Area ,, Oil Tank a~d..Valy~e.s. Oil On Surface InstI. Level Yes (Do Not No (Proceed Time Time ~' Valve Comments Sup. or In- Drain) ........ ~i.t..h D r_~_i.~ ) Drain Drain Locked spector' s Started Stopped Yes No Signature Attachment No. 2 INSTRUCTIONS FOR INSPECTION OF OIL TANKS AND PIPELINES The No. G fuel oil storage tank will be visually inspected daily and th~ tank oil level recorded. The tank will be inspected for any signs of deterioration and any unusual condition must be reported to the Production and .Maintenance Supervisor. If water is present within the diked area, determination has Go be made as to whether oil is present on the surface of the water. ? If no oil is present, the Production or MaLntenance Supervisor will unlock~' the drain valve and drain the contents to a dry well. All applicable portions of the Oil Facilities Inspection and Dike Drainage Report must be completed and signed each time the facility is inspected and/or drained. When the oil pipe lines are in use, all piping and valving will be inspected daily. The inspector will check all piping, valves., flanges, etc. for evidence of undue wear or possible impending problems. Any rupture or severe leak will require the immediate shutdown of that particular pipeline and blocking off of any floor drain into which the oil spill could flow. Any. spill or evidence of possible problem areas must initiate prompt repair as well as further containment and clean-up of the oil spill. The inspection of these pipe ~ines is to be logged on the Oil Facilities Lnspection and Dike Drainage Report, with any spill or unusual conditions found fully explained under comments. 14 L OE~ IN~ TION ILL ~ WlP.C-~ TO ~¢AK~ J~/~ ' PUMP ----17-11(~ EtffLO~EINATION E-QUIPME-NT (£ UENT~UA ' HL O~, IiXIATION .~PUA,4P-. ~A TAN?~ /7-102 . IIe~.IGATIOI',f PUA4P 'F) /4" ,~ ~STOleAG E' TANK · ' [~ Y O Tt4E-/e.S to'* 64e. TN~-t,l ~-E'lvf ~F:FL U~'V T ,CE-5 E-,E VOle, ~SCH-f~D~TRiAL P~0DLLCT£ C0~P. ~NH~USER-BUSCH, INC. ST. lOUIS, ~O. a~w~ ~Y AP~ROV~ =Y j ORAW~ ~O. ! .... Busch Indu ...... Products Corporation PROCEDURE 1. Draining of fuel oil tank diked area without fuel oil contamination. A'. Rain Water that collects in pit may be pumped into Plant storm drain if it is oil free. '-' Verification of water condition will be m~de By:R. Hughes or M. ~i'll~eF~y-. B. If verification of water dondition has been made, and is okay, then you may pump water from diked area into the Plant storm drain system, in the drive way area. C, Once water in diked area has been removed, then remove and store sump pump and hose in Butler Building. 2. Draining of fuel oil tank diked area with fu61'o-il contamination, A. No pit water is to be pumped,out of containment pit if it is in anyway contaminated with fuel oil. . .... B. If a oil spill should occur within the diked area. 1. Make every effort to stop the leak if possible. 2. Notify the following people at once' FOREMAN / SUPERVISOR PLANT ENGINEER' RICHARD HUGHES 398-1404 SAFETY COORDINATOR :.~ ,,,.. CARL WALKER 398-7220~ PLANT MANAGER MICHAEL H~ELBS~R¥ 832~.5765 C. Mt. Hughes and Mr, Nillberry will make any further notification required, and will provide for, "Clean Up", as required. 3. Draining fuel oil from molasses unloading pit. A. If a oil line should rupture in the molasses pit the following steps should be taken. 1. Turn fuel oil pump off and close valve on fuel line at fuel tank- ': outlet. 2. Turn off all electrical equipment in pit'such as lights/pumps. 5455 District ~lvd. i8<)~) B34- ~ 0,50 PAGE I I _ - CON'T ..... 3. Stop all molasses unloading. 4. Switch boiler to gas and refire. 5. Notify: Foreman/Supervisor Plant Engineer: Richard Hughes 398-i404 Safety Coordinator: Carl Walker 398-7220 Plant Manager: Michael ~]]be~r~ 832-,5765 6. Mr. Hughes and M~,Hi~lb~ry wi. ll make further notification as required and will"provlae Tor clean-up. 4. Fuji o~].Un)oad~ng prmc~dure. 1. Notify Richard Hughes when you arrive. 2. Together you will verify fuel oil level in storage tank. 3. Unlock unloading line valve, 4. Make transfer line connections. 5. Unload fuel oil. 6. Disconnect transfer lines. 7. Lock unloading line valves. 8. Clean any spills from unloading area. 9. Inspect tank diked area for anz.spillage. i ,10. Have Richard Hughes sign delivery slip when completed. Busch Industrial . Products Corporat n WASTE WATER SPILL DUE TO FORCE MAIN BREAK BETWEEN PLANT AND RANCH A. GENERAL The force main lines (8" and 3") are inspected daily by the Ranch Coordinator and his assistant° Further frequent inspections are made by the Water Canal Personnel and Railroad personnel° A log of these inspections is maintained by the Ranch Coordinator. A possible source of leaks was the nine air release valves in the line. To date eight of the nine have been eliminated, with one more to go. B. 'ACTION Should a break (leak) occur the following guidelines should be fol- lowed for containment, reporting repairs and clean-up. .1. Notify Richard Hughes, Michael Hillberry, or Mike McCoy at the Plant, during normal work'days, or Process operator at night or on weekends. Telephone (805) 834-1050. Have contact person shut-down L & N pump. -. Note: Since the 3" and 8" lines are fed by separate pumps, it is important to determine which of the two lines are leaking. When defective line is located, restart the pump on the good line. Without pumping, the L & N sump will soon over flow and could shut-down plant operation. We must also take steps to reduce the volume of waste water while pump is down. Notify. a company who is equipped to repair leak. ..... , All work and time schedules must be coordinated between work site, plant and ranch. 5455 District BIvd, Bakersfield, CA 93313 (805) 834-1050 Page 2 The person in charge of plant operation will arrange for vacuum trucks for the L & N sump as needed to maintain plant operations° Ranch Coordinator or Plant Manager will take steps to notify involved property owners and/or regulatory people. When equipment arrives at leak site, berms are to be formed to contain leak. Once leak is contained, steps to repair break can begin. Keep plant informed of situation at all times. Busch Industrial Products Corporation WASTE WATER SPILL IN TANK AREA OF RANCH 1. Any spill occurring in the tank areas of the ranch should be stopped in a timely manner. 2. Any major spill at the ranch tank site would run into an adja- cent check so any damage would be minimal if any. 3. Any resulting potential for odor should be minimized. · 4, Plant Manager, local residents~and repair crews should be notified as required. 5455 District Blvd. Bakersfield. CA 93313 (805) 834-1050 Busch Industrial Products Corporation AQUA AMMONIA SPILL ACTION PLAN See attached~M,S~D,S, Sheet for information on: a. General information b. Chemical and physical data c. Potential hazards d. Protective clothing and equipment e. First aid f. Fire response g. Spill response h. Air spill i. Land spill j. Water spill Should a major ammonia leak happen: · 1. Shut-down boiler-wear protective gear as required. 2. Evacuate any area down wind of leak. 3. Notify people as shown on attached reporting chart. "4. If anyone is injured;'call paramedics. 5. Keep all personnel out of affected area. Note: Any spill of one hundred pounds or greater, must be reported to the National Response Center. Due to the dilution of our ammonia, it would take a 345 pound spill to equal 100 pounds of ammonia. 5455 District -Divd Bakersfield. C,:, 93313 (805) 834-1050 October 1984 AMMONIUM HYDROXIDE Corrosive or ORM-A RQ 1000 Lb/454 Kg* GENERAL INFORMATION Ammonium hydroxide (NH4OH) is a colorless to milkly colored liquid that is ~ormulated by dissolving ammonia (NH3) in water. Various grades generally (but not always) contain 15-29.4% ammonia by weight and are used as household cleaners, for fertilizer, and in making plastics, dyes, explosives, detergents, pesticides, nitric acid, and other products. All are fully soluble in water and are not considered flammable. Nevertheless, ammonia vapors may evolve and burn if these solutions are heated in fires. Accumulations of ammonia vapor in confined spaces within a narrow range of concentrations may occasionally result in explosions if exposed to a strong source of ignition. There is some limited potential for containers of ammonium hydroxide to rupture due to overpressurization if exposed to fire or excessive heat for sufficient time duration. Concentrated solutions may boil at higher ambient temperatures and many solutions are capable of evolving significant amounts of toxic ammonia vapors. A solution containing 20% ammonia weighs about 7.7 pounds per gallon. Ammonium hydroxide mixes in water with mild liberation of heat. It is corrosive to some metals and reacts with various chemicals. Mixtures with halogens, calcium, mercury, silver oxide, or hypochlorites of calcium or sodium may be explosive. The liquid and its concentrated yap.ors may be irritating and corrosive to bodily tissues. Products of combustion may include nitrogen oxides and unburned ammbnia. Downwind evacuation should be considered on a case by case basis if a concentrated solution of ammonium hydroxide is leaking from its container. CHEMICAL/PHYSICAL DATA Solubility in Water: Soluble in all proportions' Burning Rate: Not pertinent Solubility in Other Chemicals: Data unavailable Stability: Stable Specific Gravity (Liquid): 0.9592 (10% NH3); 0.9245 Corrosiveness: Corrosive to aluminum, tin, copper, lead, (20% NH3); both at 68°F (20°C). silver, zinc, galvanized surfaces, and various alloys of Boiling Point: 81°F (27.2°C) at I atm for 29.4% solution these metals. Melting Point: - 98.3°F ( - 72.4°C) Reactivity with Water: Mild liberation of heat upon Freezing Point: -~ 98.3°F ( - 72.4°C) dissolution. Molecular Weight: 35.05 for NH4OH; 17.03 for NH3 Reactivity with Other Chemicals: Reacts with strong Heat of Combustion: - 4440 cal/g for NH3 vapor mineral acids, silver nitrate, silver oxide, silver oxide Vapor Pressure: 556.7 mm Hg (10.76 psia) at 70°F and ethyl alcohol, calcium, mercury, hypochlorites of (21.1°C) for 28.8%; 221.4 mm Hg (4.28 psia) for 19.1% calcium or sodium, acrolein, acrylic acid, dimethyl NH3 sulfate, halogens, gold, hydrochloric acid, nitric acid, Flash Point: Not flammable under conditions likely to be hydrofluoric acid; B-propiolactone, propylene oxide, or encountered, silver permanganate. Autoignition Temperature: 1204°F (651°C) for NH3 vapor IDENTIFICATION Shipping Names: Ammonium hydroxide (USDOT); Physical State as Shipped: Liquid ammonia solution, (USDOT and IMO) Physical State as Released: Liquid Synonyms and Tradenames: Ammonia monohydrate; Color of the Shipped Material: Colorless or milky aqueous ammonia; ammonia solution; ammonia water; white household ammonia; aqua ammonia; water of Odor Characteristics: Like ammonia, pungent ammonia; ammonium hydrate. Common Uses: Mfg. plastics, dyes, explosives, Chemical Formula: NH4OH detergents, pesticides, nitric acid, rayon, rubber, Constituent.Components(% each): 15-29.4% ammonia pharmaceuticals, inks, ceramics, lubricants, household in water (generally, not always) cleaners, fertilizers, and other chemicals; used in 49 STCC: 49 352 80; 49 403 47; 49 403 16; 49 352 34 refrigeration, photography, and fireproofing wood. UN/NA Designation: NA2672; UN2073; UN2672 IMO Designation: 8 (corrosive) depending on NH3 concentration *Reportable quantity (RQ) subject to change--refer to current EPA regulations. FOR ADDITIONAL .ASSISTANCE OR INFORMATION CALL: CHEMTREC (800)424-9300 OR (202)483-7616 OR THE AAR BUREAU OF EXPLOSIVES (202)835-9500 AMMONIUM HYDROXIDE Corrosive or ORM-A POTENTIAL HAZARDS GENERAL HAZARDS Threshold Odor Concentration: 0.037-20 ppm reported for NH3 Unusual Hazards: May evolve considerable amounts of ammonia vapors from concentrated solutions or if heated. Concentrated solutions may boil at higher ambient temperatures. Short Term Exposure Limits($TEL): 35 ppm NH3 for 15 minutes. (ACGIH) Time Weighted Average(TLV. TWA): 25 ppm NHs over each 8 hours of a 40 hour work week.(ACGIH) Conditions to A~,oid: Heat, fire, and strong ignition sources; contact with incompatible materials; runoff to sewers or water bodies; inhalation, ingestion, or direct physical contact. HEALTH HAZARDS Public Health Hazards: Major hazard is from inhalation of high ammonia concentrations that may result in air from larger spills or spills of concentrated ammonium hydroxide. Direct contact and ingestion are also to be strictly avoided. Hazards of Skin or Eye Contact: Contact of liquid ammonium hydroxide with the skin or eyes may cause intense irritation and possibly severe burns. The hazard is proportional to the amount of NHs in solutions, but even those with only 10% ammonia by weight should be considered highly hazardous. Ammonia vapors in air at high concentrations may also cause burns and blisters of the skin or eyes. Hazards oflmbalation: Ammonia vapors may cause burning and tearing of the eyes, runny nose, coughing, chest pain, and irritation of the nose and throat. Severe exposures may result in difficult breathing, bronchospasm, bronchitis, pulmonary edema, and possibly death. Some effects may be delayed in onset and may be accompanied by pink frothy sputum. Note that a level of 5000 ppm in air may be almost immediately fatal due to serious edema, strangulation, and asphyxia. Hazards of Ingestion: Ingestion may cause burning pain in mouth, throat, stomach, and thorax, constriction of throat and coughing. This may be followed by vomiting of blood or passage of bloody stools. Breathing.difficulties, convulsions, and shock may result. Ingestion of only 3-4 ml may be fatal. FIRE HAZARDS Lower Flammable Limit: 15.5% (for NHs) Upper Flammable Limit: 27% (for NHs) Behavior in Fire: May generate large quantities of vapor upon release. Vapors will burn but are difficult to ignite. Containers may rupture in fire due to overpressurization. Hazardous Combustion Products: May include oxides of nitrogen and unburned ammonia. EXPLOSION HAZARDS Lower Explosive Limit: 16% (for NHs) Upper Explosive Limit: 25% (for NH3) Explosiveness: Containers may rupture in fire due to overpressurization. Vapors are difficult to ignite but may occasionally explode if ignited by a strong source within a confined area. Contact with certain other chemicals may result in formation of explosive mixtures. PROTECTIVE CLOTHING AND EQUIPMENT Protective Clothing Required: Equipment should prevent any possibility of skin or eye contact with the spilled product. This may include rubber boots, gloves, face shields, splash-proof safety goggles, and other impervious and resistant clothing. Fully encapsulating suits with self-contained breathing apparatus (SCBA) may be advisable in some cases to prevent contact with high vapor or fume concentrations in air. Compatible materials may include butyl rubber, natural rubber, neoprene, neoprene/sytrene-butadiene rubber, nitrile rubber, nitrile rubber/polyvinyl chloride, polyethylene, chlorinated polyethylene, polyurethane, polyvinyl chloride, styrene-butadiene rubber, Viton, and nitrile-butadiene rubber. Respiratory Protection: For unknown concentrations, fire fighting, or high concentrations (above 500 ppm NH3), a self-contained breathing apparatus (SCBA) with full facepiece (or the equivalent). For lesser concentrations, a gas mask with chin-style or front or back mounted ammonia canister (500 ppm NHs or less) or an ammonia cartridge respirator with a full facepiece 300 ppm NH3 or less) within the use limitations of these devices. AMMONIUM HYDROXIDE Corrosive or ORM-A FIRST AID Nonspecific symptoms: Irritation or burns of any bodily tissues; other symptoms of exposure. First Aid for Inhalation: Remove victim to fresh air and keep warm and at rest. If breathing becomes difficult or if breathing has stopped, administer artificial respiration. Get medical attention immediately. (Caution: Administration of mouth-to-mouth resuscitation may expose the first aid provider to chemical within the victim's lungs or vomit.) First Aid for Skin and Eye Contact: Flush eyes immediately with water for at least 15 minutes, occasionally lifting the eyelids. Remove all contaminated clothing. Wash affected body areas with large amounts of water. Get medical attention immediately if eye contact has occm'red or if skin irritation is present after washing. First Aid for Ingestion: If victim is conscious, administer large quantities of water immediately. Do not attempt to make the victim vomit. Get medical attention immediately. FIRE RESPONSE Extinguishing Materials: As necessary for surrounding fire. Extinguishing Techniques: Unusual vapor or fume hazard. Stay upwind. Avoid all bodily contact. Wear breathing apparatus and appropriate protective clothing. Wear full chemical protective suit if contact with material or dense fumes/smoke anticipated. Move container from fire area if no risk. Be alert to the possibility that the container may tear or rupture and suddenly release massive amounts of product when exposed to high heat (over 800°F), such as from a direct flame. Use water from side and from safe distance to keep fire exposed containers cool. SPILL RESPONSES General Information: Proceed with caution. Restrict access to area. Keep unprotected personnel upwind of spill area. Avoid contact with spilled product. Eliminate ignition sources. Prevent liquid from entering sewers and confined spaces. Protect sewers and waterways from contaminated runoff. Notify proper authorities, downstream sewer and water treatment operations, and other downstream users of potentially contaminated water. Note that intake of highly contaminated water may result in damage to boilers or industrial process equipment. Use explosion-proof equipment where necessary. Choose equipment, where possible, that is not corroded or otherwise damaged by the spilled product. Take into account that concentrated ammonium hydroxide is volatile, toxic, corrosive, and potentially flammable under conditions described in the General Information section. AIR SPILL TECHNIQUE EVACUATION... Evacuate local and downwind areas as conditions warrant to prevent exposure and to allow vapors or fumes to dissipate. Ammonium hydroxide spills may expose downwind areas to toxic concentrations over considerable distances in some cases, particularly if large amounts have spilled in warm weather and/or the product is fairly concentrated. CONSEQUENCE Need to notify, organize, transport and house displaced persons. MITIGATION Stop leak if without risk and if proper equipment available. Allow vapors and fumes to dissipate completely before reentering spill area without special protective gear. Consult qualified experts for assistance: TECHNIQUE MONITOR THE SITUATION... Ammonium hydroxide may not evolve large amounts of hazardous airborne contaminants in many outdoor spill situations. It may be advisable in some cases to simply monitor the situation until the spilled product is removed, particularly if small amounts have spilled, the product is not very concentrated, and/or the weather is cold. CONSEQUENCE Hazardous levels of ammonia in air may be found in the local spill area and immediately downwind. MITIGATION Remove the spilled product as soon as possible. Restrict access to the local spill area and areas immediately downwind by unprotected personnel. AMMONIUM HYDROXIDE Corrosive or ORM-A' TECHNIQUE WATER FOG OR SPRAY... Water fog or spray may absorb ammonia vapors and accelerate their dispersal in the atmosphere. CONSEQUENCE Water runoff may contain ammonium hydroxide from contact with vapors or fumes. MITIGATION Contain contaminated water and remove or neutralize as soon as possible to.prevent spread of contamination. Be alert to conditions such as fire hose runoff or rainwater that may add to spill volume and overfill impoundments. Consult qualified experts for safe neutralizing techniques. TECHNIQUE DILUTION ... The addition of a relatively large amount of water to liquid ammonium hydroxide may slow the release of vapors into the atmosphere. CONSEQUENCE Addition of water will increase the volume of material requiring recovery. MITIGATION Contain spilled product and remove or neutralize as soon as possible to prevent spread of contamination. Be alert to conditions such as fire hose runoff or rainwater that may add to spill volume and overfill impoundments. TECHNIQUE NEUTRALIZATION... Application of an appropriate neutralization agent to liquid ammonium hydroxide may eventually slow the release of vapors or fumes into the atmosphere. CONSEQUENCE Depending on the neutralization agent and application technique used, the resulting chemical reaction may produce varying amounts of heat, vapors, fumes and spattering. MITIGATION Proceed with caution. Consult qualified experts for safe neutralizing techniques. TECHNIQUE FOAM... There is a possibility that special chemical hazard foam or certain high expansion foams applied to the surface of liquid pools may slow the release of ammonia vapors into the atmosphere. CONSEQUENCE The effects of foam may be short term. As the foam breaks down, release of vapors will increase. Products of foam breakdown will add to the volume of spilled material. MITIGATION Continue foam applications until spilled product is removed. Contain increased volume. Use alternative technique if response is ineffective. LAND SPILL TECHNIQUE CONTAINMENT DIKES... Ammonium hydroxide may be contained by building dikes using soil, sand or other materials. CONSEQUENCE Contained ammonium hydroxide may percolate into soil or seep through dike material. This may result in loss of contained product and spread of contamination. MITIGATION Remove or neutralize contained product as soon as possible to prevent spread of contamination. Be alert to conditions such as fire hose runoff or rainwater that may overfill impoundments. Where possible, line collection area with compatible impervious materials. AMMONIUM HYDROXIDE 6s Corrosive or ORM-A TECHNIQUE EXCAVATION... A trench or ditch may be excavated to contain leaking product. CONSEQUENCE There may be increased potential for groundwater contamination in some cases. MITIGATION Remove contained products as soon as possible to prevent spread of contamination. Use surface dikes or barriers where groundwater contamination is possible or line collection basin with compatible impervious material. TECHNIQUE PUMPING/VACUUM sUcTION... Accumulated liquid pools may be recovered using appropriate hoses, pumps and storage containers or vacuum trucks. CONSEQUENCE Equipment that is incompatible with the spilled product may become damaged or develop leaks. MITIGATION Use equipment compatible with spilled product. TECHNIQUE ABSORPTION... Spreading of spilled product may be controlled by absorbing liquid with sand, earth, clay, fly ash, cement powder, or other compatible substances. CONSEQUENCE Once used, sorbent materials pose the same hazards as the spilled product. Their use adds to the overall volume of contaminated material. MITIGATION Deplete accumulated liquid pools with pumps or vacuum trucks if possible before applying sorbents. Remove contaminated sorbents to safe storage by mechanical means. Where necessary, neutralize sorbents under guidance of qualified expert. TECHNIQUE NEUTRALIZATION... Application of an appropriate neutralization agent may modify the spilled product to a less hazardous substance. CONSEQUENCE Application and removal of chemical agents involves additional environmental risks. MITIGATION Consult qualified experts for safe neutralization techniques. TECHNIQUE MECHANICAL REMOVAL... Contaminated soil and spilled product may be removed by shovels, motorized graders and scrapers, loaders, bulldozers, and draglines. CONSEQUENCE Removal equipment may become contaminated and present a hazard to later users. Incompatible equipment may be damaged or corroded. Improper storage of removed materials may result in future spread of contamination. MITIGATION Decontaminate all equipment a/~er use. Use equipment compatible with spilled product. Store contaminated materials in safe and secure location. WATER SPILL TECHNIQUE STOP USE... Notify downstream industrial, municipal, and public users to stop water intake or to monitor water for contamination. CONSEQUENCE Alternative water supplies may be needed to accommodate users. MITIGATION Provide alternative water supplies as needed until water supply is declared safe. AMMONIUM HYDROXIDE Corrosive or ORM-A TECHNIQUE CONTAINMENT DIKES... Water with dissolved chemical may be contained (or diverted to impoundment area) by diking upper and/or lower bounds to limit volume of water affected and spread of contamination. CONSEQUENCE Earthen dikes may become saturated with water and seep through or collapse. Additional water may cause overflow of diked area or water body boundaries. MITIGATION Reinforce or modify dikes as necessary. Be alert to conditions that may lead to overflow or dike collapse. Remove contaminated water to impoundment or storage area for later treatment or disposal. TECHNIQUE NEUTRALIZATION... Application of a suitable neutralization agent to the contaminated water may reduce environmental hazards. CONSEQUENCE Some neutralizing agents are themselves hazardous and must be handled with care. Improper application may lead to increased damage or harm. MITIGATION Proceed with caution. Consult qualified experts for sa£e neutralizing techniques. TECHNIQUE AERATION... Water containing dissolved volatile chemicals may be decontaminated to some degree by aeration, air stripping, or air sparging techniques. These involve the use of air compressors and perforated piping to bubble large quantities of air through the contaminated water body. CONSEQUENCE The air bubbles entering the atmosphere will be contaminated with some amount of chemical vapors ii the technique is.effective. MITIGATION Consult qualified experts for advice and assistance in obtaining and deploying necessary equipment. Apply alternative techniques where air emissions may pose a downwind hazard. 12.17 12.18 12.19 12.20 SATURATED LIQUID DENSITY LIQUID HEAT CAPACITY LIQUID THERMAL CONDUCTIVITY LIQUID VISCOSITY Bdtish thermal Temperature Temperature Pounds per cubic Temperature British thermal unit Temperature unit-inch per hour- (degrees F) Cent/poise (degrees F) foot (degrees F) per pound-F (degrees F) square foot-F 10 56,640 34 1.000 N N 15 56.530 36 1.000 O O 20 56.430 38 1.000 T T 25 56,330 40 1.000 30 56,220 42 1.000 P P 35 56.120 44 1.000 E E 40 56.010 46 1.000 R FI 45 55.910 48 1.000 T T 50 55.810 50 1.000 I I 55 55.700 52 1.000 N N 60 55.600 54 1.000 E E 65 55,490 56 1.000 N N 70 55,390 58 1,000 T T 75 55.290 60 1.000 80 55.180 62 1.000 85 55,080 64 1.000 66 1.000 68 1.000 70 1.000 72 1.000 74 1.000 76 1.000 12.21 12.22 12.23 12.24 SOLUBILITY IN WATER SATURATED VAPOR PRESSURE SATURATED VAPOR DENSITY IDEAL GAS HEAT CAPACITY Temperature Pounds per 100 Temperature Pounds per Temperature Pounds per cubic Temperature Bdtish thermal uni~ (degrees F) pounds of water (degrees F) square inch (degrees F') foot (degrees F) per pound-F M D D N I A A O S T T T C A A I P B N N E L O O R E T T T I A A N V V E A A N I I T L L A A B B L L E E Cmmmo~ Synonym. Watery i.3u.~ Co~o,-~sa Ammonia ~ ~ FI~ H~O$ 10. H~RD ~ESSMENT CODE U~ Not ~nt Avo,~ contact w,~h ~,~u~ and va~r Keeo people away 6.5 ~ ~ of ~ IL H~RD C~SSIFI~TIONS Fire 6.12 F~ T~lt~ Not' ~nt CALL ;OR MEDICAL AiD 7. CHEMI~L R~CTIVI~ Exposure Will ~n ~in aN ~. ~ ~lute ~ wat~ 7.a Re~ O~ 6 ]~ PHYSI~L AND CHEMI~ P~IES Pollution ~o.~ I~1 health and ~ldhfe othc~a~s, t2.3 ~ P~t at 1 a~ NOt ~t L RES~NSE TO DI~HA~EZ ~BEL 8. WA~R ~LLUTION 3. CHEMI~L 0ESIGNATIONS 4. OBSE~ASLE CHA~CTERISTICS 12.12 ~t~ Heat of Va~ 5. H~LTH H~S g, SNI~NG INFORMATION JUNE 1986 DBusch lndusl:rial Inter-Office C or re s p onden c e 1. General Characteristics Chlorine is a heavier than air, yellowish green gas, with a pungent, highly detectable irritating odor° 2. Potential Hazards Chlorine can not catch fire, however it may ignite combustibles° Containers may rupture and explode, 'due to heat of a fire. Contact may cause severe ir~.itation to the skin, eys and the soft tissue of the mouth, nose and throat. · Runoff from a chlorine leak could pollute a water supply. 3o Usage Points We have one chlorine system that consists of two each, one ton chlorine tanks and four roto meters o Chlorine injection points are at each cooling tower sump pump (three each, and the house water tank fill line from the well) 4o Alarms There are no alarms in this system. 5o Chlorine Leaks A chlorine leak can be detected by smell' or visual observation° a. Call for assistance° 1o On days - call Richard Hughes 834-1050 extension 18 Mike McCoy 834-1050 extension 16 Michael Hillberry834-1050 extension 12 2o On off shift or holidays call Richard Hughes 398-1404 Mike McCoy 833-6645 Michael Hillberry832-5 765 .i bo Use extrenm~ caution-~.~ .... 1o Do not enter leak area alone. Use the buddy system° ' ?{! 2. Wear protective clothing and respiratory protection° a o) If leak is minor (noticeable odor, but not enough to cause coughing) rubber gloves, chlorine cannister type mask and "' face shields will give adequate protection. There are two masks mounted in area of chlorine system. bo) If leak is major, a MSA air pac and a chemical suit must be used° The area must be evacuated of all personnel° Page .2 c. Ventilate leak area° 1. If teak is anywhere down stream of the cylinder, shut off cylinder .valve. 2. If the cylinder itself is leaking, clear area of all per- sonnel until it can be safely removed by supplier, Argo Chemical, telephone number (805) 322-2222. 3. Do not use water to flush awaz chlorine gas° The mixture of water and chlorine gas will increase the rate of cor- rosion and make the leak larger. Water may also Warm the chlorine, increasing its pressure, thus forcing the chlo- rine to escape faster. 6. Emergency First Aid. a. Immediately remove victim from 'contaminated area, to the fresh air. Take necessary precautions of wearing a respirator so that you do not become a victim. b. Check victims breathing. If breathing has stopped, use CPRo ' c. Call paramedics at 911 or 800 324-4512. d. If victims eyes, skin or clothing have been exposed to liquid chlorine and victim can be moved, use a safety shower for thorough flushing of. skin and eyes. Remove contaminated cloth- ing. If victim cannot be moved, remove contaminated clothing° 7. Refer to attached M,S,D~S~ Sheet for further information. 8. Reporting of a spill will be as shown in the "INTERNAL REPORTING CHART," contained in section 1 of this E.I.Po plan. 9. Reportable quanity of chlorine is 10 pounds° Ammonia .......................... 4~' TOXIC AND/OR CORROSIVE; Boron Trichloride ...................... 40 · NON FLAMMABLE Boron Trifluoride'. ..................... 40 STORAGE INSTRUCTIONS Bromine Pentafluoride .................. 41 Sto~c ~ we~-ve~t~te~ ~t a~e~ o~ ~ee~ ~ co~e~ed Bromine Trifluoride 41 outdoo~ ~ea, p~o~ded cy~de~s ~e ~e2t o~ ~ou~d .'~- ." . Bromotrifluoroethylene .................. 41 ~d ~a7 f~om ~ad~t ~e~t so~ces. '~;..: .. Chlorine 42 CAUTION: Avoid breathing or skin conta~ with '::::":':' "" Chlorine Trifluoride 42 these 9as~.. Use ~rsonal prote~ive equipment in · .: -: Fluorine ............................ 42 emergencies. Get medi~l a~ention if exposed. ::...- Hydrogen Bromide .................... 43 USAGE PROCEDURES Hydrogen Chloride .................... 43 Hydrogen Fluoride .................... 43 Do ~ot b[ea~e ~as. Hydrogen Iodide ...................... 43 c~o~. Use ~ a~ea ~t~ adequate ~e~tQ~tJo~. Use Iodine Pentafluoride .................... 44 e~uJpment compatible ~t~ ~d co~tJo~ed for specJ~c . -Pe~luoro-2-Butene .................... ~ sc~ce. ~cep o~, ~ease, ~d combustJ~[e mate~ Phosphorous Pentafluoride .............. 44 awa~ [~m o~e~s. Use o~7 ~ cZosed s~ste~ co~- Silicon Tetr~Fiuoride .................... 45 st~cted Suifu~l Fluoride ...................... '45 CZose .v~Ye w~e~ ~ot'~ use o~ w~e~ e~pt7. WARNING: Suck-back into cylinder ~n cause expi~ sion. Always use a vacuum break or other prote~ive Faratus in any line or piping from the cylinder to prevent suck-back.· - EMERGENCY PROCEDURES .__ ~T ~D: ~t : pe[so~'s exposed to ~ese ~scs evc~ ~ ~o s7m2to~s ': [~om cxpo~e to t~esc ~ases ~e c~de~t. ~e[e~ to spec~c ~as ~o~ mo~e ' ~st ~d, Jf ~ppU~b]e. ~ ~se of co~tact .~ eyes, ~: Qus~ eyes ~t~ coo] wate~ for at ]east Z5 ~utes. ~: ' ~ case o[ co~t~ct ~t~ s~, L[~: ~cuate a~ea ~d ~eep pe~so~c~ up~d. Use sea-coat,ed b~e~t~ app~atus ~d p[otectJ~e c[ot~- . . sp~zY o~ [o~ no~e to keep cy~de~ cool: 38 ' · : 39 I ~J~ ~~ ~~ ~ ~'I I? HBf -- A colorless, irritating,, highly toxic, corrosive, CI2 -- A yellow-green, pungent, highly toxic liquefied l i~. liquefied acid gas which is shipped at its vapor pressure gas which is an oxidizer; It is shipped at its vapor :~i':' of 320 psig at 70°F.. It causes'severe burns on contact pressure of 85 psig at 70°F. It causes burns on contact ~' with the'eyes, skin, and mucous membranes," .... · with eyes, skin and mucous membranes. ~.. · ' MAJOR HAZA'RDS:. Inhalation and Bodily Contact MAJOR HAZARDS: Inhalation and Bodily Contact '~i:i. TOXICITY: Highly Toxic, T.L.V. of'3 ppm TOXICITY: Highly Toxic, T.L.V. of 1 ppm ~ FIRE POTENTIAL: Nonflammable FIRE POTENTIAL: Supports Combustion ::.~- ODOR: Irritating ODOR: Pungent, Irritating DOT LABELS: Nonflammable Gas DOT LABELS: Until Dec. 31, 1976: :: I:l I SPECIFIC VOLUME: 4,8 cf/lb Nonflammable Gas . ..?- After Dec. 3~, 1976: ~~2-'HyDRoGEN-Ct:i£'dRi'~~! Nonflammable Gas ~l~. HCl -- A colorless, irritating, corrosive, highly toxic, SPECIFIC VOLUME: 5.4 cf/lb liquefied acid gas which is shipped at its vapor pressure of 613 psig at 70°F. It causes severe burns on contact with the eyes, skin, and mucous membranes. · MAJOR HAZARDS: Inhalation and Bodily Contact ~~(~H LO R I N E TR I F LUO R I D E~,~.~; -- I TOXICITY: Highly Toxic, T.L.V. of 5 ,pm ' ~' ;~ ' ' ~ ......................................... ' .......... FIRE POTENTIAL: Nonflammable CIF3 -- A colorless, irritating, highly corrosive, highly ... ODOR: Pungent, Suffocating toxic liq~Jefied gas which vigorously reacts with organic DOT LABELS: Nonflammable Gas compounds and also many inorganic compounds. It SPECIFIC VOLUME: 10.gcf/[b causes severe burns on contact with eyes, skin and mucous membranes. ~. - HYDROGEN FLUORIDE'>~~' MAJOR HAZARDS: Inhalation, Reactivity, Bodily HF --A colorless, highly toxic, highly corrosive, Ii- Contact queried acid gas which is shipped at its vapor pressure TOXICITY: Highly Toxic, T.L.V. of 0.1 ppm FIRE POTENTIAL: Highly Oxidizing of 1 psig at 70°F, It vigorously attacks eyes, skin ODOR: Sweet, Irritating and mucous membranes. DOT LABELS: Corrosive SPECIFIC VOLUME: 4.2 cf Jib MAJOR HAZARDS: Inhalation, Bodily Contact; FIRST AID: In case of contact with skin, in Reactivity addition to procedure outlined above, after flush- TOXICITY: Highly Toxic, T.L.V. of3 ppm lng contaminated area of contact, pay particular FIRE POTENTIAL: Nonflammable attention to skin under:nails. Follow by applying ODOR: Sharp, Penetrating iced alcoholic or aqueous 0.2% Zephiran chloride DOT LABELS: Corrosive or Hyamine 1622 solution. If not available, con- SPECIFIC VOLUME: 19.3cf/lb tinue washing in cool water for 2 to 4 hours or FIRST AID: In case of contact with skin, in addition to procedure outlined above, after flush- until medical attention is obtained. ing contaminated area of contact, pay particular attention to skin under, nails. Follow by applying iced alcoholic or aquedus 0.2% Zephiran chloride or Hyamine 1622 solution. If not available, con- ..... ~¢~' .7'.~'..~.~!~ FLUORINE-,~ ..... ,~ ............. -. tinue washing in cool water for 2 to 4 hours or until medical attention is obtained. F2 -- A pale yellow, highly toxic, highly corrosive, irritating gas. The most reactive element known. It ~.~.2:~.:_~.~;~:~ ........ vigorously reacts with almost all orgamc and inorganic ~.~,~:.. HYDROGEN IODID 'substances. It causes severe burhs on contact" with HI -- A colorless, highly toxic, highly corrosive, Ii- eyes, skin or mucous membranes, queried acid which decomposes in the presence of MAJOR HAZARDS: Inhalation;Reactivity, Bodily heat or light. It causes, severe burns on contact · Contact . . with eyes, skin and mucous membranes. TOXICITY: Highly Toxic, T;L.V.0f0.1 ppm: ~ : · ' ' .... ' :'~ '-': ' ' "FIRE POTENTIAL: Highly Oxidizing . :.;.:. : MAJOR HAZARDS:- Inhalation, Bodily Contact,. _ Reactivity- .: ODOR:- Sharp, Penetrating, . DOT LABELS:. Until Dec. 31, 1976: TOXICITY': Highly Toxic. Flammable Gas FIRE'POTENTIAL: Nonflammable - ODOR:' Pungent, Irritating . After Dec. 31, 1976: DOT LABELS: Corrosive- .-. Poison Gas and Oxidizer SPECIFIC VOLUME: 3.0 cf Jlb . SPECIFIC VOLUME: 4.8cf Jlb~ ' - ....... '..- · 43 , '" .- " 42 ~ ' ' :~hlorime, Liquid ' ATE:RIAL SAFETY DATA SHEET' cco. -' ' u.s.^.- ~ctte~ 7 HEALTH HAZARD DATA y a problem became it is a. gas at: roo~ gempera~e. Liquid and gas - capable, of ca~ing a-burn. Not likely a problem because of burn and because it is a gas. TLV: I ppm (1974) ~"'~' °' °~"~"°"~' Marked irritation:eyes, nas~l~&, throat, linings. Lung injury. So irritating, it ~ ~ be difficul~ ~o breath. ~ ~r[ 'flushing the skin-in a shower; for eyes:, ~dta~ely fl~h th~ o~¢Lu~. On any and all si~ of ill effects, primly =e~ve person to ~,,, fresh air, keep-him warm and quie~ and~.gec ~dical attention ~,~o,~ i~.-diately. S~art artificial respiration tf brea~hing stops. ,.r~, Ingestion: Noc. lilly a problem. If' liquid ia swallowed, do -r no~ indue vomiting; give ~lk, wa~er', ~lk of mEnesia an~ cal~ :'_ ~ aphy~c~n .~dfareZy. Pre~en~' ail'con.cc - a~n, eye and =%~ i~alation. If expos=e oct=s, effects f=~ i~alatton ~hould be loo~d for- fimst: and treated, even., rhone akin. and eye_ contac~ ~y have 0co,red. also. Sufficient Co co~CroI %V'.. to 1 ppm - none; 1. ppm to 2% for 10 ~nute~. or: less, a ~11 face ~sk and acid. gas canister; ~eater, a self-con=ained:~ brea~hing appara=~ or equ!valen=. Rubber gloves, apron and boots and ~11 face::' Shield over eye protection. o ,- · ,, '::~'?? " ~g:',%%%[~,~¢~" ~ Ey~ fountain.: an8~::: safety' showers- ac work' sFation. Section- 9 SPECIAL PRECAUTION~'OR::O~HERqCD~MENTS No-a~Ee~pC should be¢-~de,~::uo handle, o=' s~tor~?htorine without' a,. complete... rev&ew, of. the ~w. Ch-lo=lne:, Handbook and/orff;t~e~:-Chlorine ~n~l, .a.va!Iable. from the Chlorine '"¢'-~ . ..-.: <.i -~ . . ,, ] - ;.,~ .._:?'~;",. - . .: . . _' :' . ..... '.. - .' .~ ',;,' .' .... ;" -' '-:...:"r' -:~;~,~.~5:<:.ir~:' --)."-.. ': '-.-' 'i":' -. '- . :'7:'~'.~[ MATERIAL SAFETY DATA SHEET -""--- .... ~ectl~. I N~E & PRODUC.T OOW CH~ICAL U.S.A. . MIDLAND. MICHIGAN 48640~[ 517- 636- 4400 Nove~er 13. 1974 Chlorine 9.8 lppm · ~,~,,,~c~. A~r 'C"blor - ' gene_Odor; lf~ified gas under pressure i apparatus for'~r~[~tory" pro~ec~'ion' and pro~ecglwe c'lo~hin~. , At elevatea temperat~es L>~uu ~) ~y teac=, to cause. 5ire and/or e~losIon ~n con=ac= with ~ny' organic, compound~, a~nia, hydrogen,~ ~ steel, .......... or' ftn~l~...~dtvided ~a 5,etlon, 5 REACTIVITY DATA. ~O~NAL CONOIT~ON~) ...... J Prox~i~y to fla~ble, raCer!als or' ch~icals'. l~r See above " MAY' HAZAROOU~ ~ X' occur. · .. :. Move unprotected personnel upwind. Close: necessary- valves with trained pe"'3onneI using, prescribed protec~ive~ equipment.... lor-i'ne~ ~y' be. absorbed in' ca~.ic-NaOH)',, soda ~'sh (Na-2CO3),, or' hYdra,ed 80TECHNOLOGY CONTRIBUTING TO FOOD, HEALTH AND THE ENVIRON ME~_~.,.~/ December 7, 1989 Mr. Ralph Huey Bakersfield City Fire.' Department Hazardous Material Division 2130 G Street Bakersfield, Ca. 93301 Dear Mr. Huey:: Enclosed is an updated MSDS inventory list for the Gist-brocades Food Ingredients Business Plan. Fry [ Maintenance Engineer cc; Sue Luft Mike Del Vecchio Bob Deedy Gist-brocades Food Ingredients Inc. 5455 District Blvd Bakersfield, CA 93313 (805) 834-1050 I N VIE i'.l l' 0 P, Y [.I U A N T I T I E S CHI.ZMICAI.. NAHI.:' COHHON NAHI!:i MAXIMUM '/(]'/AL AHOUNT AT AMOUNT ~. 0 NI!." T I H Ii.' I N Y E,A L.. A B 0 I::¢ A T 0 P, Y ~L IH:: I-'1 ~ I E: ]. GAl.. I GAl.. ACIE'TAI_I)F:]-IYI)Ii:' E'I'HSNOL. ~ ACIE'TI C ..... ' ..... E'THYI... Al. DFI-tY[ E Ii" T I C A C I ]} ~ Gl... A C I A I.. Mli:'l' I-'1A N E C AIR B 0 X Y L. I C A C I D E:. T H n N U t C A C ]'. I) 520 I... B S ~..° ~.,~,n I... B S 4-AMINO-S-q-~YDR[IXYL. 4--AMINIO'.'-3'-HYI]FCOXY- " 500 (.")MS 500 GMS I A N D N A F' I.-IT I'-I h I...1!.'". N I.E 1 .... N A F:' H T I..IA I... E N E S U I... I::' CI FI I C'. A C II] SUI...FON IC ACID ACITTONE I)IMIETHYL. I~:IETONIE~ MI'ZTHYI... ]. [-~hl... 1 GAl_ I'(ETONE ~ Z~"'F:'F'¢OF:'ANONE AMHONILIN [,IIL. C.I",IDE SAL. AMMONIAC AMM[]NIUH H[]I_YBBA'I"E AHHONZUM F'AI"'.'AHOI...YBFJATIE 500 GHS 100 GMS AMMONZUM SUL. FA'I'IE AMMC)NTUH I"IYDF~;OGF_:]'~ S !1 I::'A'l['li:: 500 (::1Ic., 500GMs)' c, A Fi H 0 N I U M M [] N 0 B A S I C A H H - N '[ J H 'D :[ I.'1Y D F: 0 G Ii!: N F:' Iq 0 S F:'I..! A I'E M 0 N C] B A S :[ C '"~.:. K ~.9 E F'AGE 2 AidMONIUid F'HOSF'HATE F:'I:;IMAI:~Y AMIdONIUM Fi'HOSF'HATF:i ].,=.00 GidS 3000 GM,C3 PI"I[]SPHATE]; AMMON I LJM B !- F'HOSF'HATE.~ PH[]SF'HOF; I C AC I ~) ~ HON O~Mi"ION ]i I..Jid SALT RI£AGENT AL. COH[]I., I'"¢CC CA'Y, N0,6590 4 GAl,. 't. 5 GAL. ANTHRONF_' ANTHF~:ACENONE 100 GMS 25 C..iidS ARABINOSE idCB AX1705 :;.!!5 GHS 100 GMS ~, I)'- ( -" ) - A Iq A B I N 0 S E BENZOl[] ACID F'HENYL. F'OF;;idI[] AC]i}] 500 GMS 10 I...BS B I 0 T I N F:'Y P, F: 0 I.. I:": 1' I"110 I:i' I"t Iii] N Ii!: 15 (]'.; M S 15 G id S '[ H I D A Z 0 L E "' 4 "- P li!] N l' A N D I C A C I I) I"l E X A I"! Y A F; O- 2"" 0 X 0 ,, B I 0 Iii] F:' I D E I::; M B O1:;~ I C A C I D B[] R A C I C A C I I) ~, O I:;', l"l"l 0 B 0 F:; I C A[]II)~, BEff:~OF:'AX 1OOO GidS SOOO GidS BI3OMOC,'I31F.'$E[]I_ [3 F;: E I:": N "- F:;ICCA 1220 16 OZ ~20Z id E T H Y L I:/ii'.' B CALCITL~]~ CHAI..I'<, CAF~BONIC , CAI_CIUId CI"II_ORII)L:: biCB "''"~ ...... " CX.I .... :,' ':J 0 bido 130 GMS C A R T R I'D G E ~ C A T :[ 0 N ;2 0 F'/N 0S956S COBALT CHI..OF:IBE J T BAI'~E:R 1670 :l. 2'd., Gi'lS 250 GidS CLJI:'F~IC SLJL. F:A'FE' 'BL. LJE VITF:~]]OL.~*, BI...I. JEST']ix!I!~. 1000 GMS 1500 GMS C'f't' ....... '" ~.~1 - CT.'I"I-~IC AC.tL, IdONOHYDF,:ATI.:. 'l"l.,O I.-IY[IF,:OXY-.-ONI?~,'I"WC~T'HF,:I~J!!: 8 L. BS' 10 I..BS I:' F, 0 f' P N I"] T I", I C A I::,; B 0 X Y L.. I C A C I I) F'~GI£ ~ COl_l-MUG TUBES i GAl.. i GAL. CRYSTAl_ VIOl_El" BASIC VIOL. lET TI--IIiEE} 25 GMS 10 GHS GENT3[AL VIC)L. IET [{EX'rF,:OSI.:: Gl_OoO..,l::, bl,.A}-I:., .=fl. JL~c".l-,, COF,:N1000 GMS 3~<>00 Gi'4S c.,tJGAI, I]O3DECYI_ oOI. IUM SUI...F:'AI'E: SOI]It. JM I...AUFV, YL. SUI...F:'ATIE 1 I...B 1/2 LB 2--I=:THANE SUI_FUN.rC ~[3I'[{ ........... '" 10 K <ETHYLENI=Y'{];N!]'I:klLO> IETHYL. IENIEI;{IAHINI:::TE]'I:kACClii;TI'C'. 500 GMS 500 GMS TE'rI~AACETIC ACID, ACID, )3I?...;C));:IIUM SALT' ~.~ I SO1] I {.JM S~I_-/' ETHYl_ AI_CC)I"IOL. AI_COHOL 2 QT 1 GAL. · ANHY£1F~[3US, DE;N~TUI:kED F'EIr,:I'",:OLJS. r'hMMONIUM SULFAI'E AMMONIUM IF;:E)N SULI::'~"i'E 2 I...B 1/2 LB, AI4NON ;[ LIN F.'r='I.',:F:;C)US :S/JI_F:'A'T'E, I--Ilii;X A I.-IY I] P,A T iii: FEF,;RIC AMMONIUM CI'FI::iA'f'Ii.' C:I;'¥F,:IC ACIY..I AHMONIUPI :l L.B i I_B II:;;ON <S4.) SALT A M Id C..) N ! U M I" Ii" I",; R I C C I T I:;: A T Iii - ,, F'EF,:'RI[.'. CI"{I_OI=,',II)IE 100 (;')MS; '1.00 GMS FEF;ROUS SL.ILI-P, TE :CRON UI'TF::.T. OL. 5<)0 (;'}HS 500 Gt'l.'.'-3 I'-IEF:' T H Y AI:";A ]' E F'OF;'.MAI...I)EHYI)I=Z SOI_UT:rON A F:'OI:~:MAI...DEHYI:IE .... A 1.:00 MI... 3000 ML I::'O I:~ 14,A I.. :I: tkI ¢- I"10 R E', :[ (] :[ [J ,x,,l'] :1: fi- (-)-I::'P, UCI'OSE .])'"I::'F:-:U[3'TOF:'YF:;~NCISE 500 GMS 2000 GMS GI..YCIEROI_ GI_YCI:~.F:;INE: C)NIi~.~ 1 r..2T i QT T W 00 T I..I F:.', E: E .--. P I:k 0 F:' A N lli: T I::.: I C.:t L HY3C. F,:OCHI_OR'[C ACID I..IYY. F, IC(3F=N CHI_OF;:IDE 4 (.'..'iAI.. 20 GAl_ ]:;hGE 4 ]:OI)INE i~O() L~L.) ~.00 GMS AL..COHOL.. LAC"F IC ACID 2-I.iY)]I:~OX F'F;:OF:'P~NO:I:C :32 OZ S2 OZ &C I '0 E H T Y L. I 1)E: N EI..ACTIC hCID ~LACTOSI-':] M]:LK SUGAI::¢ 1. LB 1 L..B LEAD ACETATE .[A..,t::.]nTE :LO00 GMS 1000 GMS S U G A I::~ 0 F:' L. E h I) MhGI'-NS:I:UM CHI...OF~IDlii: :l. I...B I I...B I~lhNG/~NOUS SUL. F'f"~TE PJhNGF~NI::.c.I:. SLII I::',~"l'li!; 500 GMS 500 , c, .... ' ..... . ....... G M o MhNN I TOL., F'OWDEF~ I'iFq_ ")'::":"'., .:.,Plo 500 GMS .....J ,~ '1. -. :L 5 0 0 r ...... MALTOSE AI..I:~I:~:I'CI-.I (:;I.-II..]:i'l 100 GNS 100 GMS MERCURIC SUI_FhTE Mli!:I::~CUF;:Y BI¢~.JI. I-'n I [::. i LB '1./2 LB M::.I',,CIJI'~f E]"IIEI"'~Glii]'ICY ZINC i'il~i:'l'¢H... 1 I::'K i F:'K CL..EP~N LIP. SYSTEi't S Jl_l:rtJl:~ I C hCI I) O o :[ N ? · ':'~ ' R ' '-.": G M S t'iE.,..,O - I NO,. 1TOI_ 1 O0 GMS ME'T'HYI_ ¢~L. COlaOL. :l I_]:'1" Q'f' ,':.2 LIT QT i'tE'rHYL. IRED~ NEL.ITRFd... ¢~CII) REI) 2;TWO .... 25 GMS 25 GMS ( 4-- ( D :1: H E 'f' I-.I Y I_ h H I N 0 .) D :[ Pi E T I..IL h N I N 0 )F:'I-.IE N Y L.. h Z 0 ) BIFNZOIC .':',CID METI~IYI...ENE BI_LIE: BhSIC. BL. UE 9 ':)5 GMS 1.0 G&I... 'F':AGF_ 5 N A L C 0 S O L. U T I O N 'q~... ~... ~=.~'> ''~ '~ F:'"" T N I) I C A"I' 0 R .~ I::' H E N O. .... :t. 6 0 Z 6 4 0 Z Lr"HTHALEIM .:~LI...UrlON IN .. ][ EMA"rL.IF:Er~ ETHAi'.IOI.. A..,ID 1 GAl.. .1. 6Al_ NALCO SOLU'FION S02'26 SI.I.F'I.F,:IC P" NAI..CO SOLU-rlON S02S4 I (:.;Al_. 2 GAl.. ~AI..CO SOLUTION S0243 :1. GAl.. 1. GAl.. NAI:.CO SOLUTION S0260 1 GAl... 1 GAL. NALCO S(]L. LYrlON S0274 :l GAl._ 1 GAl... NAI_CO SOLUTION S0275 i GAl_ 1 GAL :1'-1-2 TOTAL HAI:kON NAI_CO SOI..UTION. SC'2.77 :l GAL. 1 GAL.. ' NAI.,CO SOI_U'¥ION S0279 i (:'}Al.. 1 GAl.. NAI._CB SOI..UT![)N S0280 !. GAl... :1. GAl. NAI.,Co SOLLJ'FION~ SH355 F'---1 F'-i,AIdMOMIUM MOL. YBBA'['E IN ' 2 LI')" 2 l_I'l' AN A[-IUIEOUS SUL. I::'UI:k!C'. ACIB o ..I L U 'f' I 0 N NAI. CO SOI._U]'ION .S06:IS :l (3Al... 1 GAl.. NAI_UO SOI_UTION .'.-306:1.4 1 .:.,Al... :l GAl_ NAI_CO SOI_UTION S5091 I GAl... i GAl. ORTI'~OTOI_IDINE/ RI( .... A 8640 :1.60Z 3;20Z F'AI:~AFFIN Oll..~, t41"llTli~. :1. I... 1.51.. F'EN I C I I..L I N-'G-SC)D I LIM' F:'l::]q.I C'. I L.L. I AN 1. ]~C['I...E 2 BTLE F' E N I C I L L I N'- S T P,I!: F' T 0 Pi Y C :[ N 10 E I I...1:..~ ]E ]' I.., I:, o F'EI:~CHI_OP, IC AC]:I) t.'.'O,O MI...S 1000 ML.S ·60%, 70.,, "F'HI:":NOL I"IYBF~CIXYBE:NXE:NI=: :L I::']" 1. PT F'I"iENANTI'tRENIE AF:,:OMA'I- I C I"IF;:DF~:CK]ARBON ;2..'5 GMS .'..'~'::',., GMS PI"IENOLPHTFIAI_E:]:N :1.2'.::i GMS SO GMS F'HOSF'HOF,; l C AC :ID o -I- I I(). ~1- I I )1~ [ C Ar.: I )] 8 GAl... 16 (::)Al.. P I'-IT 14 h L I C A C I ii :L ~ 2-'" BI"!: N Z Ii.': N Ii!: l' I C A I:t:B 0 X Y I... I C. :1. Q ]' 1. / 2 Q T M 0 N 0 F' O'r A S S I I.J M S A I.. T A C I [I H C) N C) P 0 T A S S I U H S A L T F'OTASSIUM CI..ILOF:,:II)lii: "r · r,q '5C, CiNS ...... 77,::~ :2-00-,.:~ I ' L.B i L.B POTASSIUM CHROHA I'E. CA:II: .....,', z ,.:00 GMS ,.,00 (:;PIS F'O 1' A S S I tJ M H Y D F:O X i B E C ALI S"f I C: F:' 0 T A S I-.I .... ' ' F'C) AS<~' 2. I...B .T o.[.JM SUI...F'ATE SAL. F'OI..YC'HF,:ESTI. JM 1.0 L.B POTASSIUM PHOSF:'HATli:". F'OTASSILli~I PI'-IC~SF'HATF: :L'::;O"') GMS 2000 GMc., M 0 N 0 B A S I C M C} N 0 B A S I C F'OTASSIUH 1::'04 DIBASIC'. ,~"()0 GMS LSO0 GMS F'(]'¥F~SS:I:I. JM IODATIE :[C)DIC AC]:):)~ 1000 :~Mo 500 F:'OTASSI UN S,"h[..T POTASSIUM OXAL..ATIE OXAL.]:C AC:ED~ :L LB I I..B I)EF'OThSS]:L.JH SAI...T, E'TI-IANED I 0:1: C SALT F'OTASSItJM I-IIC.~:,I'IIAll I)IBASIC HAl.. 7092 I L..B 1 I...B D I B A S ]: C ~F':AGI-- 7 ~"" " ") '::; K ':~,5 1< POTASSIUM SODIUH T&F,;I'P, ATE: L::.',OC.'.HE]_I_Iii: ,:~r.fl...r ....... ( .... :) I_B .~ L'B FOFAS,~II. JM IODI'DE PROF'YLF£NIE C-)I_YCOL I)IHYI)F':OXYI::'I'~OI::'ANI!i:~, 1 I::'T 1/2 GAl_ F'FiO F'A NIE D I C) I_ C':Mo 500 GMS '~ C~C: "~'~" RAF"I"-INOSE bO~.,..,YI oI:..;MI:.":I...]:TOE':Iii:; 200 " c' M E I.. I T R 0 S E t_-RHAMI-IOSIE MCB RXO070 ')'::; GMS 25 SILVER NII'T:~ATIE 50 GMS 100 GMS S]:I_VER CHLOF~II)I.:.: 50 (.'Chh:., ~0 bM,.) SILVER ,SUL..F~TE i i I...B I L.B S 0 B I U M ~ C E T A 1' F-": ~ AC I.-] T I C'. ~ C I I) ~, :1. I... B 1 / 2 L. B ANHYrIROLJS , SODILJM SAI...'[ · I SOl'. IUM BICARBONA]'Iii: BAKING SO:OA; SOI)IUM AC.]:I; C~{.",,'BOiqAT{!i: '"' L.B 1 .... I...B SO][IILJM BISIJI_FITE SOI)IUM ACIi) SLJI...F'ITI!; 500 GMS 100 (']MS S U I.. F' I..I F,: C) U S A C I D SODIUM CITF~ATE TRISDDIUM Ci"I'F~hTE 500 GMS 500 GMS SO]OIUM CHLOI"':II)Ii':: 3 K 10 I< SOD I LJM GL. LJC()NrYTIF SOD I tim ,..., ,~, 4,5,6 '~ 000 1. 000 F:' I!:' N T 6 I'-I Y D I::; 0 X Y "-' 1 - I"1 I!" X A N 0 FA 'f' E SOI]I UM I"IYDF;;OX I I'vE. CALJE~'T I C SOI:l(~ ,.~:' GAl.... 50 C-.~AI... 50"/ SOl UTI ']N o(3[ .I !,iH HYDI~A'I"Ii::. ~ LYE SO B I U Pi H, 1:. I",[. X .I I)I'2: ~ C'.i~ U ST ]: C ~.:)t.)I. A; I... Y E: :L 2 IE' 24 K SOl_ I D SOD I L M I"IYDRA ]"E ' F;~GE 8 SODIUM SULF:'ITE 5()0 GMS 1000 GMS SODIUM oUl...I..~rl::. TR.[oOD.[U,-~ SUI...F:'r~TE .1. I...I!~ .1. L.B fl NI"I Y ][ IR I] IJ S ~,!!: U I... F U R I {.'. A C I D SODIUM '¥HIOSUI..F"'ATIF S.-..I'~YDF'O:~Tli[ :1. I...B 5 L.B SOI'~B I ]' OL ' (31.. LJ C I T OL. 1 I... B 1. '1.. B ~STRI=F'TOMYCIN .I .... [ TI...F.':..::~.1.2 BTI t.ES "'S L.II...F: f~-r E SU[,I'~O:'.,I:. BE:ET SL.I[')~I:i;~, C'.,"~Nli[ St..IGf:d:~ 2 K .1.0 K S 0 D I U I'f H Y D I:'~ ~ T Iii: SUI...hL I-,, .lC F/CID NORH~d... ~. EI::'F~ ~, F'ff:l-'h"~ ,- F'~,S'I'M ~, o Gt~l... 1 6 96% A¢.]~, FOR P,I..I'(P,I..INI'f'Y SUI_FrUIr4]:C F/CIB I'tINEFih~I... ¢'~C.:[I)SOI...UT!ON'S 6 C'.~61... 24 Gt~L D I I..[J TE SOL:.tJ T I [)NS " ................. (:., M :'. 200 GMS '1'REHAL[.ISIE o1" I:.C I'I",LIM 7' 10':?7 .25 "q TR l CHI.OROAEC T' :[. C; ~(:; ID 1-Fl I CHI.. OROAC E T I C' F'~[.', :r. D 10 I... B Ii:; L B Tl"lIt~MIi'-Ili"' I-IYI:tI:k[)CHL[)FZ'.IDli!: VI'fAM]:i'-I B~, I--IYI)F:;C~C:HL. OFk]:I)IE 500 (:-iHS 1.00 GMS ZINC [,I.-II.(]F¢.[][E ....,,Jo GMS 500 GMS ZINC' SLJI_F~TE~., 7-1-.IYZ..;RCFFE: WHI'f'E V]:F~'f'F~]:OI._ Z :[ N C: V I "1'1::~ ]: [)1... 600 (3 Pi S 1000 G M S XYLOSE: WO(]D ,SI. JGAI:k 2,,5 GHS 25 GMS 'F;AGE 9 A I F:'; 2 '~ 5 C U F:' T 2 6, 2 © C: U F:"I' a.CC, OFfD II :l. 50 GAl_ 1800 GAl.. aLCATEL 100 MECHANICAl... PUMP F:'I...UID :1.2 C-YI'S 3 (.:l lo ~MINOSUI_FUF~IC ACI]O~ SI. JI..F'AM!C ACt'D '5000 LBS 14000 I_'BS ~MINOSUL. FONIC ACII) MONO BRON OTF~ l F'L.L OF~(]ME TI-.I~ N E 3--1'(4-ANINO-2-MI-ZTHYL..-5- HAI...ON 13()1.~ F'F:..'IEC)N F'I-':: ].',301 114:L I...BS 1142. LBS F'YRIMIDINYL) HYBF~OXYET HYL. ) -.4- MIET H YI...- :: TH I AZOL I UM CHI.,(]F~ I DF- AMMONIUM HYIP. OXI:[Fi' AQLIA AMMONIh S76000 I...B 4512000 L.B NEU TF~AL IZA 'FION BIOI::'aL NI:~:-.20 :L50 Gal... :LBO0 GAl.. IODOF'HOF~$ CALCIUM I--IYI::'OCHI..OFi]:TE I-'l"l'l-'l 600 I_,BS S000 LBS ' 'l ....... DIAMMONIUM PI"I(]SF'HATI~:: DIAHHONIUH I' HC..q- HA [ I.'. ~ 4 1] l B A S I C D I B a S :1: C; I::' I"1 C) S F:' H CI 5: I C A C I l) ~, 125 I... B S ]. 500 I... B S ' ANHYDF:OIJS D IAMMON I UH SAI..T MAGNESIUM ~'3IJL. F'ATE: ~ HI":'PTAHYDP. ATF: El::'c30M SAI..."I' MAGNE:SILJM SUI.,F'A]'IT, U,.S,,F:'~ 1500 L..BS 18000 I BI:, MEI:(CURY MEI:',:CLIF,:Y 5 I...BS 5 I..BS '"ORGAN]:C ]]IEI::'OAHli.:.R FIAZLJ l)F'10F:' MC)I'~ '"' r704) 2.::.)0 GAL. ')~ .............. ~,4',)" GaL. S ORTHYOF'HOSF'I'~OF~:IC ACII]~ F'HOSF'HOI~:IC ACID 4000 GAL 48000 Gal._ PAGE 10 ,.C)l.~a ASI-I SOEILJM CAF:;B[)NATli!:~ 1250 L. BS 3000 I...~:,=~ A N H Y D R 0 U S S 0 D I [J I1 H Y D R r.] X ]:'D E, C A U S T I C S 0 D A 50."/. LIQUID CI-IE]_ATI!.'ED I...I[-IL.II]O LYE 4000 GAL. 48000 GAL SODIUM :Z,:3~4~,.:,6 oO[.[UH GL. LJCONA'[E 1000 I...t.:) 1000 I...B¢~ F'ENTAHYDROX'¥ 1.'-I.J EXAMO-I'Ii:J IJI_F6TE 01:: hHMONIA 6HMONIUH SLJI..FATE 150 I...BS 18000 L. BS SLJI..I=LJRIC SLJI..F'I.JF{IC ACID 8400 I._BS 'S'3':2'..".";0 I_BS 1' I-.I I A M I I'-IE H C 1 "1' I"11 A M I N Iii: .1. 8 cf:. I'(G 900 K (3 HONOHYDROCHLOF~ I D Ii:'. VIT~PiIN B1 ZIN., SUI..F'HA'FE HE'FECH:~ BRAN[I Z]:NC M(]NOHYI)F~;ATI:-': SUI...I::'H~Tlii: S6% 1666 I...BS 20000 L. BS BACTER]:AL. Ii.Ia,. FR,.l:.. 150 :~c: I... ]E .... 150 LBS BLAIR r~I:.HE,':~IVES HC)DIFIED I..AirE,~ EMI. II .qION .I.,.-....~ L.).'...:,.tSO0 · "1 '"~ ...... " " ' "':"=' ';i':~ L )~.~.::~ BONCHEM MII':;F, iO-F:'OHE · CI...EANING ";::.UI...U 11 ON 12 [;AL. :1.44 GAl... CALCIUM HYPOCH[,CIRITE I"IYF:'OCHI..OROU:~ !000 I...BS [~000 I...BS CRYSTAI...S "fF~:ISOI)IUi~I F'HOSF:'HATlii: 2000 LBS 7000 I...BS 'lEI F:' D E C A H Y D R R T Iii: ~ T S F' CF~YSTRI...S ~, -f,SF:' [.'.F;',YSTRL. I_ I iHl:.": ], I:;PK3E ]. :L E, AI'~ H Al_L, F'UF~F'OSE AP, SOI~BENT ,1,~0 ~"'~ · (SIL'F< ICI T 1,~ CI,,,~'~ Y ) H B FULLER/HM-'6509 "I']..iE:F~MCIF'L.R.:.,]'].C RI)I..II!i]SIUli:.' ..... ;0 lBS :~.000 L. BS HYDRO CI_E:P,N 3()0 50 GAl.. 120 GAl.. MAZEF,' CUTTING OIL. "¢'"' ... ,:ol I::'F~OF:'F~ilii:I'AF~Y StJF:F:'ACTANT 8000 I..BS 96000 L. BS BLEND ~'MAZER M~ZU I)F: '"~':;;~ I::'F(OF:'F~:II:::'I"AI\Y SURF:'ACTAN"I" 880 L. BS 1.0560 L. BS )': L..I:.K.[. MAZU DI::' SS() MO:[~ ~..'. LI",bAI,IIC BRSE'T ,~N'T]:I::'ORM 7200 I...B~:. 86400 LBS M~.~ZI.J CU'F'I"ING CIIL. 350 ' '2.00 I...)3S 2400 '.LBS F:'OT,RTO S'T'6I::~CH 35000 L. BS 700000 I..BS QLhYH=':RNt~F."~ 6MMON:[UM SP~NITIZEF': 400 (EU.::~"' .... 400) 4:!3 G(~L..S 576 S,fiN I T I ZER THEF~MOCLEE:N ~"]I..L. F:'UI:~F:'OSE CI...EF~NIER :1. GhI... 4 G~L. I'I ~ I N T E N I:'~ N C E .} AE I'~S ]. VI.". GR I ND :[ NG WHEE:L. PI"IF':NOI.. :[ C B(:)NI:IE:I:I GI:~ :[ NIl :l: NC')EF'~ 8 [='~ !,l I"1E E L. ABI:~ASIUE WHF:I-EL.S 4 E:R 1:2 6CIF'FYL. ENE 5CETYI FhIF (G~S) "r',V ,::' ,:; ......... ,'.....<] CU F'T ,.~9,.~ gl.J FT' P~CT]:-KLIE~N 5 G~I... 20 GJ~L. ~EI'~OSOL. CI...IE(~NEF~:3 2:,(726.-f~ DI'.:.GF,',FP~S]:NG 12 [.'.r'~NS ;50 CP/NS S (] L. V E: N T AEI"',:OSOL. C.'.I..EANEF~:S 4X,:'~',:,"A' :1.':'.,-.. CAhIS 40 CANS CONTACT CI...EANEF;: ' AF-'F:.:OS[IL CL. EANr:i:F;~S E'tu, 4 --I-I-;h. idJ. UH 6 CANS ,:.0 AEROSOL COATINGS 4XO42-A HIGH HEAT hL. UM. 4 CAN:!.~ ,,:. CANS AEROSOL COATINGS 2X7:[O-A MAC. HIi',tr'!: GRAY 6 CANS 20 CANS '~AE:I:~:OSOL L.t. JBI'i I CAN'I'S "> .....'"" "> CANS ]. 0 CANS ,:.. W / ...¢ / T E F: L 0 N D F'; Y L.U B E ,,.. A E'F:O S 0 L S T A '[ N I. F S S P A I hiT 2 f...Rl'~ ~:> 2 C A N,:~ S'f' F E I..: C 0 A T I N G · ""' ":"':' "f' 0 N S '",-; T 0 N S AI..LOY 'STEEI...-HF:~CF.', AL I L ~ STIEI!i:I... :i. 0 e · 4:[S0 0., ~ AL. LOY L.EAI)ED o.rl:.EL 4140-,, 4340 ~, .36,,.:0 r'd..LO r L.E:A:[ lED I + I"": ~ 861...20 AI_.UMINA ZIF-:COi',IIA'. GI:;:INDING KASCO ABt::~ASIVES '8 lEA 32 E:A WHEEL. S~ ;u'r-"/F'F: WHEIEI...S AND CLI ~ 2-4 ZNCH ALUHINUM OXIDE: CLJT.-~OFF DI-41:I:.[..;:~, S LJI.. F:"H UI:~ F I:~ E E A L.t.J H I N U M 0 X I lq E O 1:'41 N D l N G I'( A S 6.'. 0 A B F;: A S I V E S .4 Ii!: A 16 E: A ARGON ("W'di;) 672 CU F'T :1.680 CU f-"T I:4IODISPEI:~:SAN'f' 1:[0 GAL. Si~.O GAL pl'.l BUF'F-"IER".:.~OI...IJ'¥ION BUFF'E]::~ WiTH ETB~ GLYCOL (.'-)UALI"f'Y I...IEA[dET..~ 50 LBS '100 L.B$ C¢~R[.<ON I + E, :1.01_42 S 14'rGH SF'I::I'Z[~ CUTTZNG TOOLS SHLOF,;ZNI£ '2 'f'l::)N 6 TON I:IEF'I-"'ND t",lO ' M :[ X t-'~)' HF'S :[ VE:' :1. 00Z :1. 0 (:}Z I:.IL3t;JI=F:EJST ( R ) I"IE:¢'~'{ .... E.~¢:l.. 220 (:~1... T'F:i~NSF'EF; F:I._U I C[)VF:-I'~IE.'[~ E:I...IEC. TI::~f:)DE: (:;¢d-TB[:)N <>"':' ?. I I:,<', 6 L. BS ,.. 1 L. [..L.. C'.(:)i::.:lii; t,,I ]: I:k I'Z ... :":.' C 0 V I.'-_ R E: ]::~ E: L.. E' C 'f' R 0 D E E: 60 :L 0 ~'"; .... 0 L. [':{ S ""~'. 0 ¢.) L.. ]E:¢";~ C[)VIEF4E:I:J L:.:I...E:C"f'F,:(:)I:JE: IE60:I.:L '50 I...BS 200 LP, S GP~SKFT FOR~Y ']EII:;:Y []I"IIEHIC. P,I_ ':20 I...B 90 ELS T Z NGL~ ]] E.q-'l Z N!? 1<4.5 FOOD EiX.~U I F:'MENT F:'O0)_'I I!-" []1...I ]: I::'HI.T.H'i" I...LSBli!: 1 CP, N 6 CPJ'~ I...UBI'~ O07;),."'""'A I::L.IEL. OIL i)OMlii:i!Y1']:C I..!IE6T]:NC{~ OIL. 1. C:.000 (.'-;AL. .:1.~000 GAl... HALON 125. CI.J F.'T' .125 CU F"T LIN:OF' 'I'LJNGE~"fE:N 1/4 L..I-.'~ ]./4 L..]B EL. ECTRODES L. tJBI:";;[Ct~NT (,~EF:~C)SOI...) RI...UH]:NUi'I 'I" ,"'d::' F; ]: N G 4 C.'.f"d',lE: "15 CP~NS C 0 Pi F' 0 IJ N D LUBI~IF'I_~TE" "H(3" Sli"_'F~IE.S -- L:UBF~F'LRTE I..IYDF~RLJL...'[C. OZL. L. UDI-'~ZCR"I'];N.F...I C.1ZL. :1.00 C..iRL.,'-3 ~OO C~RL..S HO.--I~ 1.-10-2. HO.--3 ' I_LJBRIF'L~$TE: CHAIN I...LJBF~',]:C'.R'i"]:i'.IC~ C)]]I... 'J: (3AI_.S '1.5 GALE', AND CA'BI_IE F'I_U]]D L. Llli'U::.:IF'L. RTE: "APG" I...I. JP, F:;]:Ct'h'F]:NC{~ 0]:1... 5 (31~1_.'~:: .... ,.".; S E.' R :[ E S I_ UBIg :[ PLATI:_' F~ F:'G.-.-~ 0 ,..:. L. tJI:.q:~:IF'LATE: "F'HC)" !i.~FZI:;:]:E:S L..I..JBF;]:CR"F]:N(3 [3:[I... ',:.:;',":.} (3f;d...S~'5()O {3r"',L..S L. UIiU:,: Z F'L. 5 TE: I_.LIBF,::[F.'I._R'¥1:_:: NUMBI'~:I::Hii::O" ,c.:, ........ o ",.1~1~.1.1: .... I...LJBF~:]:ChT]:NC'.;. C)]:I... 5',_, (..RI"~' ...... ~" 110 GAI_.S L. UE~F;:[F'L.~'FE~ NO, .4 HIEI:~ C U F;Y H FZ F;;C LJF:;Y ',:: L. I'.'~!3 ~:..; I.. t~E; ..... ' .... " ~:. 7,~ HLJF<IAT]:C AC:ILl 20 IlsEGF:E:I~: :[NOIRL")F'~N:I:C AL::I:):) '5'~ L=,~'q...o ~>'"'= NT,. -,3c'-.~=.. TAF'F']: NG TAF'F:']: NG C. ONF:'CI..INI/ 4 [.'.fiNS 1. 2 [,'.fiNE.; Nr, 278 F'LJHF' L.JmSI_UE: AND Nr", 390 CU'r'r]:NO O:I:L. ('AIEF<OE.;(.1. L. ) 4 CAN!i; 1. 2 CAN!i; Nh, 651. DE:'¥1EF:GI!-:N') .... L. UBI:~ I CAI' ]: NG 0:1: L.. ( P,I!:.'F,:O,C~OI_ ) e'.-, (:.'.P'~NE~. ]. ~5 C::t~Nf"; Nr', 27.'3 E:I._IZC'I'F~:I:C' 208 I'~UI_'F]:..-.I.. JI.d..O.:l: N.~:iUSI'T/:[ ~31.. SOL..k,~E:NT , ':J.; (3F4..~i; 1 ~:; GAl_ 710' C£)HF:'O UN.~:I ( :360 CI_E:ANI!i:F~ :LO L'..i Fq... ,~.".; ~:; [.~1!!:(3 F?. F_: A,S Ii: I:< / (:.'. I... I!i: h N Ii!: [~ !~; G F~ I_ 70 (3 ~5 I... NAI_CO 7330 H :[ C F; 0 B :[ (3(7.1 I3 E: :L 5 (3,'~ I... 1 [:~ G A L. F~AGF 16 Nf~I...CO )'5 F'I...ILk,~ .1./2 ]]F~I..IM 1/2 B 0 :[ I_ E R 'r F: E ~'r M ti!:N'r NAI_C[] S[31_LJ'['ION' S0279 I..I..-6, AQLIE:OLIS SOI...]'LJ]:ON OF:' ,.""::'.,,.., (}.~AI.... '~ .... ''~0 GAl.. c.,(.)[..[ UH I.-IY).]F~OX I DE i, NAL. CO -,-~ ~3o, A(:~UI.:.:OUS SOL_I..JT:I:ON OF COI:~I:~OS I ON :[ NH Z B I TOI:~ Z I E'THYI. bpi T N[)E:TI"IhNOL. ,1. .~)I::~UM 4 N A L C 0 254..'.~ F' L. 1. V F'[:)L Y F'H 0 S I:'I"IA T Ii'.] S LJ I...1::' I 'l" E :1. ][ R . Pi 4 ][IF~I..IPIS I'-II..I ~'i A T Iii: & F' [.~ L. Y G I... Y C 0 L ~ Ii:. 'T H .F: ~ ')3 I... Ii!: N )} N]iTF~OGiEN NITI:~O[3EN (r'i~q .1 5Z5' F:'T ,:. ~,,:. ) 614 [:; L; F:'"[' . .... [.'.L.I OXYGEN OXYGEN (G~¥i3) ,."I?:!..} C':I.J F'T 14'-74 CLJ FT q'] 24 GAl... 24 GAl_" EF'OXY F'AINT c.~.1 F:'AINT .900 GOI...I) E:N.~)l::'f:~S]'liE i 'I...B 5 LBS QUICK SET CYRNOCI:4YL.~Tli~: 2 OZ :1.0 OZ QUICK SI'El" '¥M ~DI'-IESIk)F:Z 404 SAF:'IETY-.I'::I_E:Iii:N 105 SOl VI::'N'TS....N!::;:II:¢;).~.,]7 'S',": (3Al... ~3].'=J GAl_ 105 S [] I.. V E N 'F -' iq !.'i S]:I.~ICONIF'"7:32 I:~'TU Cl..EAR 10 LBS 20 LBS 72.'.3 SF:'F~'~SOLVO '.]!'.~0 OZ ,600 OZ (20'"'120Z CANS) (50-12 OZ'. F':~G F' .1.7 SC)L. DI--R~ ;~:4,-; .RE:SZN CORE 5 I...~i-;S 52 L. BS SOLVENT [.'.EMI!ENT '2, OZ 80Z SOL. VI='N'I', S'¥OD'DAI.',:D 5 I...):..:.~ .1.0 I~.BS 2156 SOI..VE:NT I. [..;AL. I GAl_ ' .... ..),... :1. OZ F:EI:I:F,:E:NL~IE IEI_EC'I-F',OEIE :1. r''x S Ol...U T T [)N ~ ' :l. TON 4 TONS , 'I R :[ N L.. E: S S S'l' I:: E: L 3 X X S E: F.: ]: Iii: S ~ . 4 X X :!315 i::; :£ I!.": S'[' r~'l' L:.' I::'E: N I::' I.Z N'I' I:~', R "l' ]: i'-( G (3 :[ L. 2 C. t'~ I .I =., 2 C'. R N S. l Ns'r~N'r ~DI-d.E.:S Z VE 6 C 0.. (3 01... D E:N:O T ~ F' E: :1. / 2 I... B L_ B · 11:33 TI'-I:[CKE:ND C'.!i'EHE:N'T WE:I...I) ON :1.,.5 50Z 5 t:.)~.. 41 :L CL. iTRF: "f'(3L.JGl.-!l.]:i'.II!i::(:~ 5 '"' '::; DZ INS'¥6NT Cli"'HENT . OI::.'[:),"'tNI[.': BON.~E'I' 4 lii:r~ Ii) G R :[ N D ]: N1:3 W I-t IE E: L S V ]: TI::: :[ F :[ lii::O P~ B IR R S :[ VIE F:' F: 0 D U C 'l- S SULFURIC ACID SPILL ACTION PLAN SEE ATTACHED M.S.D.S. FOR INFORMATION ON: A) General Information B) Chemical and Physical Data C) Potential Hazards D)~ Protective Clothing and Equipment E) First Aid F) Fire Response G) Spill Response Sulfuric acid can cause rapid and severe corrosion or burn action. Treat with extreme caution. Sulfuric acid reacts vigorously with water. Pour acid into water, NEVER add water to acid. Should a major sulfuric acid leak happen: 1. Treat with caution and wear'protective gear as required. 2. Keep all personnal out of affected area. 3. Notify people as shown on attached reporting chart. 4. Dike area and neutralize with soda ash, then flush with water. If water is not available, cover with sand ashes or gravel and neutralize with soda ash. 5. Do not use combustibles such as cloth or sawdust for mopping up. 6. If anyone is injured; call paramedics. NOTE: Any spill of 1000 pounds or greater must be reported to the National Response Center. BIOTECHNOLOGY CONTRIBUTING TO FOOD, HEALTH AND THE ENVI RONMENT June 9, 1989 RECEIVED Mr. Duane Meadows Bakersfield City Fire Department ~0 9 ~989 Hazardous Material Division 2130 G Street ~A~. J~A~ O~V. Bakersfield, Ca. 93301 Dear Mr. Meadows: Enclosed is the Business Plan for Gist-brocades Food Ingredients, Inc. If you have any questions or need further information please contact me. Enclosed is a copy of the Hazardous Materials Inventory sheet we have done on our computer. Would it be possible for us to use this form in the future in place of the one put out by your department? Maintenance Engineer /cs Enclosures Gist-brocades Food Ingredients Inc. 5455 District BIvd Bakersfield, CA 93313 (805) 834-1050 ZNTE NAL REPORTZN CHART Il "SP LL" V Superviser 1. C. Walker 398-7220 I1 2. d. garter ...... 834-1050 V Ranch Coordinator Maintenance Engineer D. Ensey '<- L. Fry ~-->1) C.Walker Home 664-1124 Home 833-8764 [1~1 Home 398-7220 Pager 329-4946 Pager 329-2617 II~ Pager 329-1023 O¢¢i¢e 835-8385 ,, , "· , , · V R. Deedy > Peter Doodeman Home 664-0248 Office (215) 272-4040 '. Home (215) 520-0256 Corporate Environmental Michael Del Vecchio Office (201) 251-6650, Corporate Kemper Insurance Home (201) 526-6472 Augustin Vega John Hogan Of¢ice (201) 251-6650 (714) 598-3000 Home (201) 521-5317 " ¥ Corporate ka~¥er Morgan, Le~is & BocRius 2001 Logan Square Philadelphia, PA. 19103 Ken Meyers (215) 963-5000 Dan Ensey Office 835-8385 Safety Pager 834-2337 ' >' C.Walker Home 329-4946 Pager 329-1023 LLoyd Fry Office 834-1050 Home 398-7220 Pager 329-2617 Home 833-8764 Robert Deedy Office 834-1050 Home 664-0248 v Bakersfield City Fire t either /I .... Hazard Material Division < or Fire/Rescue (805) 326-3979 >11 911 t~ (805) 324-4542 , California Office of EMERGENCY RESPONSE /1 from CA. (800) 852-7550 '< as needed Bakersfield Police out of state >11 ~ (916) 427-4341 ~1 Calif. Hwy Patrol ' ~1 (805) 325-5822 Vacuum Truck Service II "' ~ as needed as needed M.P. Vacuum K.C.A.P.C.D. < ...... >' (805) 393-1151 II (~2 II depending on Kern Vacuum Service type of spill (805) 589-5220 National Response ~ Center ~< as needed Hazardous Material ~ H >' Disposal Company I.T. Corp (805) 763-4171 Chemical Waste Mgr. (800) 222-2964 Waste Control Svc. (805) 399-4620 REPORTING CHART "SPILL AT RANCH" WORKER IF DAN ENSEY JOE PAZ HOME 664-1124 ~ HOME 834-4012 WORK 835-8385 OR 397-8797_ PAGER 329-4946 ~ ' I REPAIR CREW ' I MASCO CONTRUCTION AS I " : N. OLLIVIER ~' NEEDE~ ~ LLOYD FRY 833~8764 WORK 831-3703 PAGER 329-2~.? HOME 393-7828 VACUUM TRUCK AS AS K.C.A.P.C.D. M.P. VACUUM ~ NEEDED NEEDED 861-3682 393-1151 BACK HOE WHII'FEN EXCAVATION hAS GARY WHITTEN ~EEDED WORK - 834-8002 MOBILE- 327-3505 #8400 I=E[::dlIC C~-L.:~::.[I.E :[.,::'.'-.';> ¢':ii".i:::~ l::' l!!: ~:!-: l::.', C) U S E; l.J i... F' ~'-"t T liil F'C)Rid¢.~L. DI!EHY');:d-'f ~:;r:'ll UT t (37.,! ~'.~'~ F'El?-'-;i-i?~i.::.'(;tEW'fl"¢¢= ::',"-"-"'-.'-" ~ :[ ':~('~,'"', ~',!f... ".'-;r.,r'~ .-) I" J::' O I:."-: id ~":'~ L. ~'~ ..-. ¢ -- ) --. ? F,: U ~"; T ~'~ '- ..... i- -... i::' i:k t 1('; T O i::' ¥' I::.: ¢~'~ f.,! i::;I S E '::: ;' '"'> E~ ?i :E; ":~ ,'"; ,"', (', (;~ i"l :ii; ~ ...... .::, i::. . - .-' *.' '.. ,. , G L Y (;.'. [:.: F; (:) [.. ~":i ! '"¢' f": E: F.; '~' i'..l ~::' ~. ~ i' "I ¢',, t::. ::: '-" r' ',, ~:::~ !::' ~:~ i"'.! !!;: T i:;: i '.,.'::i i... I--tYId::~(3E:HL.E!i:"-::I;C .'":¢;;.': ]: ~f' I..u,' '~::, ","'-~::",. ("~..II '"q::.-' ,'~ ¢".;,~:,~ .... _ ,, ¢ :(.I,-,Lh.:,...¢.! ........... I ~:?!i: .,- , ....... :i:.'"'; (:!;¢':~1 .... .i f'-!(3 !;~ 11' (3 L. 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L:. ~--., "i' F:.', I!!i A"F ?i li!i i",i i ,.,~-,L..C:I21) 'iii;lii~lL..L.!T iil Ci~'..! ~ii~O'?'7'::;'i..I...,,z, ~':~i17!I/i::'i'"i~:::; ':::" ,"L l? r"~?...l '-'"ii::' ::: '"1 ¥' i[ 1...I i'"i ..... "" "'""'" '; : ........ .-: ~ :.,....,,.......:. Ei !!-.'. .: ,?'.? f..IAl f'f"~ 3!.57' ;"'di~' ' ""' "' ,::.,.-.~ ~ ;.¥-., ........ · Ji- , '-' · ...... Ci?'.i ~.~'" . ('". I" ~:::, ......... ]::; r'~ '::.', T C~, bl '1' ?-.1. ...... !-'1 i[ I'i-; i]i "i' ("l F:~ i) T E!i T !..! Y L. ~" ...... 1' . .... ?'.i iTi !iil "i' ~..! ~'::~ i"...: il) L. ii..~.""~ :., ...... ,...ti 1' .4 'i'li::.,,, ~... ,I 1~,4. u"~ ·, .'7, '~'~ ::. :::, ..., ~...!" .~. ~ -. I-'.~,..! '! f~'~'TiE ?;'; .:::' C'iI ...... (': 1 ;'31 : N iI~ T 1::~ 0 (ii F:'. i'-.I _. - _. ' N J!i "f' I::~ (i)(iii !!i~ ~'.! C-) A !i!: ........ ~ii:! U ]7 (.~ ~4 "~:.~ ........ !::. ~" "i' i~'~ C Y A N i12) C: i::?. "i' I..'. ~ "f' !iil ?.,..~".~ ":'..t. A)ii~I'-IE!.':; i[ L;I.'-Z ..:'1.04 : ' .... F:' i!il Fi~ i',1 f:,~ ?..'411~ i,.i i(71 ': :' i'",.., ...~,... ¥ ;,::- .,.~ .-r- ,... ~, , i'47. T ":' "':" '" ";" ; '" "i',. ,...~ I::. i !..! ~'%,~ ;:: ..... .... ".¥. : ' N iiJ" :~' "' ::',"", ::'"~:" ::'l:? ".' Do hereb3~ certify that I ha'ce reviewed the attached Hazardous ~laterials business Dian Cist-brocades Food ~ngredients, ~nc. - gO~&~O7 for . {name of business; and that it along with the attached additions or corrections constitute a complete and correct Business Plan for mM facility. - .aat - ACUTELY H. ARDOUS MATERIALS REgiSTRATION FORM TI--Z!S FORM MUST BE COMPLETED BY THE OWNER OR OPERATOR OF EACH'BUSD, fESS IN CALZFORNIA WI-tlCH AT ANY TIME I-IANDLES ANY ACUTELY I-tAZA~OUS MATERIAL IN QUOS GREATER THAN 500 POUNDS, 55 GALLONS OR 200 CUBIC FEET OF GAS AT STP.z TI-IIS FORM SI{ALL BE COMPLETED AND SUBMITTED TO YOUR LOCAL ADNflZqlSTERING AGENCY. (§25533 & 25536 Health & Safety Code) NO~ instructions on reverse ·. BusinesS Name ·GIST-BROCADES FOOD' INGREDIENTS INC~'-'(BAKERSFIELD YEAST· PLANT) Business Site Address 5455 DISTRICT BLVD., BAKERSFIELD, CALIFORNIA 93313 Business Mailing Address (if different) N/A Business Phone (805),834-1050 Business Plan Submission Date2 JULY.3, 1987 ~:oce. s ~ Designation3 N/A A0~RqELY HAZARDOUS MATERIALS HANDLED4 -USE ADDITIONAL PAGES IF NECESSARY- .C_]::L~~ Q U A N T Ff"Y CHLORINE (GAS IN 2,000 LBS. PRESSURIZED CYLZNDER'S) 4,000 LBS. SULFURIC ACID (77-99 WT% WITH WATER) 700 GALLONS GENERAL DESCRIPTION'OF PROCESSES AND PRINCIPAL EQUIPMENT5: ' CHLORINE: USED FOR DESTRUCTION OF. ALL NEGATIVE - STATE ORGANISM~ IN COOLING TOWER AND WELL WATER. SULFURIC ACID: USED FoR'PH CONTROL IN FERMENTERS. · ~._:?~· ....:: ~ : . · sIGNATuRE.'%/~~"~ TITLE' P.ROCES'S ENGINEER PRINTED NAME ' DIRK JEFFREY WILLARD DATE OCTOBER'is" 1988 -'- California Office of Emergency Services FORM HM 3777 (1-15-88) - ' ;-: A[IACHMENT 11 ACUTELY Hj C, RDOUS MATERIALS REI STRATION FORM HIS FORM MUST BE COMPLETED BYTHE OWNER OR OPERATOR OF EACH BUSINESS IN CALIFORNIA WHICH AT ANY TIME HANDLES ACUTELY HAZARDOUS MATERIAL IN QUANTITIES GREATER THAN 500 POUNDS, 55 GALLONS OR 200 CUBIC FEET OF GAS AT STP. SUBMIT THIS FORI~~~:~_0CAL ADMINISTERING AGENCY. (§25533 & 25536 Health & Safety Code) JAN 0 8 1988 Note instructions on reverse Ans'd ............ ' Business Name BUSCH INDUSTRIAL PRODUCTS Business SiteAddress 5455 DISTRICT BLVD, BAKERSFIELD, CALIFORNIA~ 93313 Business Mailing Address (if different) " Business Phone 805 834-:].050 Business Plan Submission DateI ,JULY 3, 1987 Process Designation2-. N/A ACUTELY HAZARDOUS MATERIALS HANDLED3 -USE ADDITIONAL PAGES IF NECESSARY- CHEMICAL NAME QUANTITY AMMONIA 22,000 gal Ions CHLORINE 2 each, I ton cyl i nders SULFURIC ACID , 600 gallons (~ENERAL DE$¢RIPTIQN OF PROCE$~E~'AND PRIN(~IPAL EQUIPMENT4: AMHONIA: · USED IN FERMENTATION PROCESS AS A NUTRIENT FOR YEAST GROWTH. CHLORINE: USED FOR DESTRUCTION OF ALL NEGATIVE - STATE ORGANISM IN COOLING TOWER AND I.~ELL t~ATER. SULFURIC ACID: USED FOR PH CONTROL IN FERMENTERS. SIGNATURE ~ ~.,c~...~,,-~ TITLE' PLANT ENGINEER PRINTED NAME RICHARD HUGHES DATE DECEMBER 29, 1987 California Office of Emergency Services FORM HM 3777 (8-25-87) · Captai'n Ralph Hue Hazardous Material Division Bakersfield Fire Department · 2130 "G" Street Bakersfield, California 93301 Re: Business Plan". for Busch Industrial Products Corporation Please remove Richard Hughes' name from the business plan that was submitted to your office for: Busch Industrial Products Corporation 5455 District Blvd. Bakersfield, California 93313 and replace with Connie Spaulding. We have a name change as Busch Industrial Products Corporation was sold' to Gist-brocades Food Ingredients, Incorporated as of June 3, 1988. Please change your records accordingly. Thank you, Connie Spaulding Office Supervisor Gist-brocades Food Ingredients, Inc. ma cc: Michael K. Hillberry Plant Manager Marlene Accardo Anheuser-Busch Incorporated Corporation Environmental Affairs 5455 District Blvd. Bakersfleld~ CA '95515 (805) 854-1050 Busch Industrial R E C E I V E 13 ~~ucts Corporation ^N.IUS~.~BUS~.GO~P~N,ES 0 E r' 0 I 1987 tuber ~3, 1987 Bakersfield Fire Department 2130 %" Street Bakersfield, California 93301 RE: Update Material for Busch Industrial Products Business Plan Please add the attached information to Busch Industrial Products Corporations Business Plan. 1. Flood Action Plan 2. Earth Quake Plan 3. Spill Response 4. Asbestos Plan 5. Fire Plan 6. Medical Plan Thank you, Plant Engineer ma cc: Marlene Accardo Don Dehart Michael Hil 1 berry Michael McCoy Debra Tesch Carl Walker Dan Ensey 5455 District Blvd, Bakersfield, CA 93313 (805} 834-1050 .. ~ Busch IndUstrial Products Corporation ONE OF THE ANHEUSER-BUSCH COMPANIES October 15, 1987 A,~'~ ............ Captain Ralph Hue Hazardous Material Division Bakersfield Fire Department City of Bakersfield 2130 "G~ Street Bakersfield, California 93301 Captain. Ralph Hue I have revised the "External RepOrti.ng Chart!! contained in our business plan p_er our telephnn~ c~nVersatinn ___~ ~close the corrected chart. 'PleaSe remove the "External Reporting Chart",cont~ined in'our plan and replace it with the new chart.' lhank You, Richard Hughe~ Plant Engineer Busch Industrial Products ma cc: Don DeHart Marlene Accardo Michael Hillberry Michael McCoy Debra Tesch Carl Walker Dan Ensey 5455 District Blvd. Bakersfield, CA 93313 ,/805) 834-1050 Busch Industrial RE C ~ ! V ~ 13 Products Corporation 0 CT I 6 1987 ONE OF THE ANHEUSeR-bUSCH COMPANIES ~n~'~ ............ October 15, 1987 TO: Bakersfield Fire Department Hazardous Material Division City of Bakersfield 2130 "G" Street Bakersfield, CA. 93301 FROM: Richard Hughes Plant Engineer Busch Industrial Products 5455 District Blvd. Bakersfield, CA. 93313 Subject: Corection of SARA, Title iii, Report Question #2 Please note the attached corrected list of chemicals requested in question #2 (Extremely Hazardous Chemicals). The chemical Phosphorus Pentoxide has been eliminated from our inventory. Thank you, Richard Hughe.~/ Plant Engineer' Ilia 5455 District Blvd. Bakersfield, CA 93313 (805) 834-1050 QUESTION 2. LIST EXTREMELY HAZARDOUS THRESHOLD REPORT'~BLE CHEMICAL NAME PLANNING QUANIITV QUANTITV AMMONIA 500~ 100~ CHLORINE 100~ 10~ SULFURIC ACID 1000~ 1000~ PHOSPHORIC ACID 500~ 1~ COBALT IOOO0~ 5000~ FORMALDEHYDE 500~ 1000~ WARFARIN 500~ 100~ Busch Industrial Products Corporation ONE Of THE ANHEUSER'BUSCH COMPANJE$ October 15, 1987 TO: Bakersfield Fire Department Hazardous Materials DiviSion 2130 "G" Street Bakersfield, California 93301 FROM: Richard Hughes Plant Engineer Busch Industrial Products 5455 District Blvd. Bakersfield, CA. 93312 SUBJECT: SARA, title III, Section 311 REPORT As required under section 311, t enclose the MoS.D.S. sheets for the following materials: 1.. Sulfuric Acid ~-r'2. Chlorine 3o Ammonia 4o Iodine Sanitizer Accord II 5. Sodium Hydroxide 6. Fuel Oil (#6) 7. Phosphoric Acid Ri chard Hughes Plant Engineer ma 5455 District Blvd. Bakersfield, CA 93313 (805) 834-1050 NOCAL UNOCAL. CHEMICALS DIVISION/NITROGEN GROUP UCO No.: ] 752 ~u~ c~, No~ ~l! UN No. 1830 MANUFACTURER'S NAME Union Chemicals Division, Union Oil Company of California 461 South Boylston CITY, STATE, AN[3 ZIP CODE Los Angeles, CA 90017 P.O. Box 60455, 90060 EMERGENCY TELEPHONE NO, Transoor~ation Emergencies call CH EMTREC (800) 424-9300 Health Emergencies Call Los Angeles Poison Control Center (24 hour~) (2131 664~2121 PRODUCT: WARNING STATEMENT: COMMON NAME: Sulfuric Acid Poison--cannot be made nonpoisonous. GENERIC NAME: Sulfuric Acid Can cause burns. CHEMICAL NAME: Sulfuric Induce vomiting if swallowed. DOTCHEMICAL PROPER FAMILY: SHIPPING NAME: Inorganic Acids For industrial use only. TLV° Sulfuric Acid 'Threshold Limit value A, OSHA [] a, ACGIH E~' c. see Section III [~. O, Other [] Unocal Chemicals Divbion, Chemical Sales Services Department, Post Office Box'r 60455, Los Angeles, California 90060/(213) 977-7199 EMERGENCY: Have a physician call LOS ANGELES POISON CONTROL CENTER (24'hrs.) 213/664-2121 Conlact., Flush with large- quantities of water for at least 15 minutes and seek ~mediate medical attention. Skin co.,~-~ Wash with large quantities of water and seek medical attention if irritation from contact persists. Inhalation If 5reathing difficulties, dizziness, or ltght-headedness occur when working in areas with high vapor concentration, victim should'he removed- to fresh air free of vapors. I nges~ion . DO NOT induce vom/t.tng. Seek {-.-ediate medical advice and/or attention. Eye This product may be an eye irritant. Effects: Corneal damage. Skin E ffec~s Ski= burns. Systemic Various studies have shown a possible association with exposure to this produc~ and the following: Effects Respirator7 tract irritation. Lung fnf lamma~ion. Dental errosion. R espirato~y Protection The use of respiratory protection, depends on vapor concentration above :_ (Specify · :,- ',Type) t~Le time-weighted TLV; use, a:.N~OSH approved cartridge respirator or gas mask. " Ventilation General mechanical ventilation may be,sufficient to keep product vapor concentrations within specified time-weighted TLV ranges; If.general ventilation proves inadequate to maintain safe vapor concentrations, {upplemental local exhaust may be required. Other special precautions such as respiratory masks or environmental, containment devices may be required in extreme cases. . · Protective Eye G~oves The use of impez~eable gloves,. Protection Sa£et¥ glasses, chemical is advised to prevent skin : goggles and/or'face sh±elds irritation in sensitive' .......... . are recommended to safeguard' individuals. .' against potential eye contact, irritation or injury. Other Impermeable aprons are advised, when working with this product. The Protective Equipment availability of eye washes and safety showers in work areas is recommended. The use of long sleeved clothing closed at the neck is advised. Change daily if Go, Cam±nateS, Stability Conditions to Avoid: Unstable (':'it'.h: Stable X Temperatures above 150°F I ncompatibility (Materials to Avoid) ~ Base (alkali) Hazardous Decomposition Products SO3 at high temperatures Hazardous Conditions to Avoid: Polymerization May Occur Will Not Occur X HIGHWAY OR RAILWAY SPILLS- CALL CHEMTREC 800/424-g300 Precautions ' In Case of Release or Flush spilled matemfal imco': suitable retaining areas or containers w±th s~iH large quantities of Reportable ....... ;'*(f~* .... Quantity Notify Coast Guard National Res~onf~ Center; Phone No. 800-4244~802, If Spill Is Greater Than lbs (Kilograms) Method Dispose Of product in acc0rd~ce with applicable local, county,, state and federal regulations. Form AM-CA02 (10-80) Printed in U.S.A. ':' *?'¥'~*(; 3 Handling amd Storing Precautions Keep product containers closed when not in use. Prevent contact of this produc: with moisture (i.e., atmospheric air). Other Precautions Personnel should avoid 'inhalation of vapors. (See Sections I, II,~III~V,vi.) Personal contact with the product should be avoided. Should contact be made, remove saturated clothing and flush affected areas with water. (See Sections II', Iy,V.!'.) DOT Flash Point Range: [] Below 20° F, [] 20° F- 100° F Flammability [] 100OF -200OF [] Over 200° F Classification Not Applicable. ~ None to boiling Extinguishing Media · - Unusual Fire and Explosion Hazards Avoid water. Fire Fightfng Procede res Approximate Vapor Oensity: ~ Heavier Than Air Boiling Range, o F [] Lighte~ Evaporation Rate: [] Faster Percent Solubility in (~ Slower Than Ether Volatile: Water: 100 Complete Specific Gravity: [] Lighter ThanWater ~)gZ 1.8342 Weight 99% 15.30 [~ Heavier 95~ l. 8355 per Gallon: 93% 1.8279 Appearance and Odor: ~ Colorless liquid. Product CodeNo. 311 I~ue'Oa..te ,, J~ly 198] PreparedS¥ P. S. Backlund Replaces: UCD No. 296 ~odu~, Code No. '~11 Issued .Tmn~,mry lqRC) Reviewed By:,, Manager, Loss Prevention Reviewed By: / ~.~~ u~-~-~ Director of Occupational Health & Toxicology Reviewed By~ ?'/~// Science and Technology Division · The above information is believe~'o be correct as of the date hereof. However, no warranty of merchantability, fitness for any use, '- ~''' or any Other warranty is expressed or is to be implied regarding the accurancy of these data, the results to be obtained from the use of the material, or.the hazards connected with such use. Since the information contained herein may be applied under condi- tions beyond our control and with which We may be unfamiliar, and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume responsibiliW for the results of its use. This information is furnished on the condition that the person receiving it shall make his own determination as to the suitability of the material for his particular purpose and on the condition that he assume the risk of his use thereof. Form AM-6A02 (10-~,0) Printed in U.S.A.. 4 UNION CHEMICALS DIVISION / NITROGEN GROUP uc~ No,: 1776. Product Code NO;. 121 UN NO. 2672 MANUFACTURER'S NAME Union Chemicals Division, Union Oil Company of California STREET ADDRESS 461 South Boylston CITY, STATE, AND ZIP CODE Los AngeZes, CA 90017 I P. 0. Box (;0455, 90060 EMERGENCY TEll=PHONE NO. Transoort"ation Emergencies call CHEMTREC (800) 424-9300 Health Emergencies Call Los Angeles Poison Control Center {24 hours) (:213) 664-2121 PRODUCT: WARNING STATEMENT: COMMON NAME: Aqua Ammonla Warning Vapor Harmful. Can catch fire. GENERIC NAME: Ammon±a Hydroxide Do not induce vomiting if ~.._a. llowed. For industrial use only. CHEMICAL NAME: Ammonia Hydroxide Can cause burns. CHEMICJ~L FAMILY: Inorganic bases DOT PROPER'SHIPPING NAME: :::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :~:~:! :~:~: i:~:::i:i:::::: :::~.~:~: ~:i:~:~: ::: ::: :::i:: :: ::. :~: :: :: ::: :::~: i:::: .~:: .:::::::.::i ::: ::: .: :: ::?:~:::::. ::: ::::.:-: :: :. :: :.: ~::: ::::. :' ::;' .-,%-: ==================================== ............ ?/??,: i:?:?:::::: ::i::;: ::: :;: ~:':/:/:;: ::: TLV° Ammonia 2Aopm Water NE Threshold Limit Value A. OSHA [] B. ACGIH [] C. See Section III [] O. Other NE, none established Union Chemicals Division Union Oil Company of California Chemical Sales Services Department, Post Office Box 60455, Los,Angeles, California 90060/(213) 977-7199 EMERGENCY: Have.a physician call LOS ANGELES POISON CONTROL CENTER (24 hrs.) 213/664-2!21 Eve. Co.~C~ Flush with large, quantities of water for ac least' 15 minutes and ,, seek immediate medical attention. Skin Contact wash with large quantities of water and seek medical attention if irritatiou from contact persists. Inhalation If breathing difficulties, dizziness' or light-headedness occur when working in areas with high vapor concentration, victim should be removed to fresh air free of vapors° If breathing stops, begin artificial respiration and seek 4~mediate medical attention. Ingestion DO NOT induce vomiting. Seek ~mediace:' medical advice: and/or attention. Eye ~ This product may be an eye irritant. Effects Corneal damage. Skin Effects Prolonged or repeated skin couCac~ may result in dermatitis. SVS~emic VarioUs s'cudies have shown a possible association with exposure to this product and the following: Effects · Respiratory tract irritation. Lung. infl ....... ~tion. Lung d~--~ge. ; Respiratory .................. . ......... · ,~:" Protection f , (Specify Use self-contained breathing apparatus when vapor concentrations are ' .. Type) above the TLV.., Ventilation General mechanical ventilation may be sufficient to keep product vapor concentrations within ' specified time-weighted TLV ranges. If general ventilation proves inadequate to maintain safe vapor concentrations, supplemental local exhaust may be required. Other special precautions : such as respiratory masks or environmental containment devices may be required in extreme "' Protective Eye. Protection Gloves ... ~'te use of impermeable gloves ......... Safer7 glasses, cheaP'cai .... fs advised to prevent sk±n :-.: :. ::-.. ';' .: goggles and/or face sl~:elds irrtt~t~on in sens.±t~'ve " .'.'.:.: ...... :'- are;recommended to safeguard indiv~duals, against Potential eye contact, · : ..... ~rritat~'on er injury. Other Protective Impermeable aprons are advised when working w~th this product ' Equipment Stability Conditions to Avoid: ,., Unstable ::i stable- X Incompatibility ........ '. Decomposition ~: '::.. :~ ..... :~" · ,' ' '~ -'~ ' ~ . ,. . ,.: Hazardous Conditions to Avoid: . _ ,. Polymerization May Occur : ':' .' .:... . , ~. . Will Not Occur X ...................... : .............. : ................... -: ................ ': .......... HIGHWAY OR RAILWAY SPILLS - CALL CHEMTREC 800/424-9300 Precautions ............................................................................. In Case of - Release or '--',..:.-: Flush w*-th large .quant~':~es of ~rater. Quantity Notify Coast Guard National Response Canter; phone N0.'800-4244~802, If Spill Is Greater Than 'lbs (Kilograms) i. Waste ,- Method ~:., . -' : .... " .Dispose of product in accordance w~'th applY'cable local,, countTs state and federal regulations. ':' ' :' , ..... :",' . .' Form AM-6A02 (10-80 Printed In U.S.A. '-' 3 ' ' ;?.': .* *' T- HandlinO and Precautions Keep product containers cool, dry and away from sources of ignition. '" Other Precautions PersOnnel should avoid i~halation of.vapors. -(See Sections !, 2, 3, 5, 6.) Personal contact with the produc~ should be avoided. Should contact be made, remove 'saturated clothing and flush affected areas with water. (See Sections 2, 4, 6'.) DOT Flash Point Range: [] Below 20e F, [] 2C~ F- 10C~ F Flammability . '= :* - J-} 10(PF -200~F ~ Over 200° F Classification ............. '* - .. .... ~ToG ~':1.~111~.~le. [] None to bo~ling Extinguishing '~ ' Media : '~:.:.:~ .- 7. :,:i:.' :, ,,' ,:.,,~ ~.,~. :.. :'..:, :-,- ,.' ,..,, .: .., -,. , . Unusual Fire ..... - and Explosion ...... ' F ire .............................................................. :7 ............................................ Fighting -. ' ...~ ,..~ .... Procedure~ Approximate Vapor DemiW: [~] Heavier Than Air Boiling Range, e F [] Lighte~ 212 Evaporation Rate: [] Fa~e~ Percent ......... ' ..... Solubiliw in ................. : ~Z SIowa' Than Ether Volatile: Water: 100 Complete .... .~:-:. Specific Gravity: [~ Lighter- ' 29% .8974 [] Heavier ThanWater :~-' Weightpe~ Gallon~ ..... ;.~' ........... ~? ...................... Appearance and.O, dor: , :. ; .:~ .~f. :.__. ..~ ........ ': ........ ':.:'-C°10~les's, 'liquid.~": Pungent odor. -,'~ .......... .--.--~: ....................... - Product Code No. 12I ~l~ue Date'-c'..,.Tul7 '%981: .'--'.'.-':,~: :Prepared By "P · S · BacK. Lurid' Replaces: UCD No. .' 3/41 Product CodeNo. 121 Is~uecl July 1979 Reviewed By: . Manaqer, Loss Prevention Reviewed By: Science and Technology Division '" The above information is believed to be correct as of the date hereof. However, no warranty of merchantability, fitness for any use, or any other warranty is expressed or is to be implied regarding the accurancy of these data, the results to be obtained from the use of the material, or the hazards connected with such use. Since the information contained herein may be applied under condi- tions beyond our control and with which we may be unfamili'ar, and ~ince' data m~de.availal~le :s_ubsequent to the date hereof may suggest modification of the information, we do not assume responsibility for the'results of its use. This information is furnished ....... on the condition that the person receiving it shall make his owndeterm!nat!on_.as ~o the suitability of the material for his particular purpose and on the condition that he assume the risk of his use thereof. , .............. :::~.-~:;:.- Form RM-6AO2 (10-eel Printed In U.S.A. ' 4' ' MATE'RIAL SAFETY i, ATA SHEET ! 5ecfiofl I NAUE &PROOUCT DOW CH~ICAL U.S.A. . MIDLAND. MICHIGAN 48640 Chlorine, ~iquid ..... Chlot ina 9.8 'lppm Se~tten 3 PHY~ICAt DATA 'eo([,-o,.~q~.~ ?~.J, ~ ib.b,,~ .-29 :'3'F' [OLUSlUTY tN -~. 20'C O. 729 ~/100 ~ ~O ~PP~A.~.c~, . '~en: 'Odor; liq ~tfi~ ~as und~ ~ressure Sectl~ 4 FIRE AHO EXPLO~IOfl HAZARD DATA ~.,c,.~ .,.~,.,..,,..-.o,.~,,~. ,~.,~-..- ..o..,.... Gas ~s~ or self-contained brea~inK apparatus for_respiratory protec~ion and pro~ecti~e clochinz. At elevatea temperances (>30~ F) ~y reac~ to cause [t:e and/or e~los[on ~n contact with ~ny orEantc compo~ds, a~nia, hyd~oEe~, steel, or finely divided . I Prox~iCy to fla~ble ~Cerials or ch~icala'. ~~ See above " ATION SILL NOT , :X occu~ .. .. ~ectiee 6 SPILL OR L[AK PROCEDURES Move unprotected personnel up. ind. Close necessary valves with trained pe"3onnel usinE prescribed protective equipment. Ch[orine.~y be absorbed tn Ca~tc NaOH), soda ash (Na2C03), or hydra=ed ' "Chlordne, L£quld · " TERIAL'SAFETY DATA SHEET (co, - - '- Do. C.E..C.L u.s.A.-. Sectlen 7 HEALTH HAZARD DATA Nor likely a problem because ig is a gas ar room =empera==e. Liquid and gas - capable of causing a burn. Liquid and gas - capable of causing a burn. Not likely a problem because of burn and because it is a gas. TLV: 1 ppm .(1974) · .~,c,, o, o.[.,..o.~., Marked irrita~ton:eyes, nasal & throa~ linings. Lung injury. So irritating, it ~/ be difficult to breath. Eye & S~n: I~d~tely re, ye conta~ted clothing while ~- flushing the skin in a shower; for eyes, ~dtately fl~h them leas~ 30 ~nu=es and ~dical for a:ten~ion. I~ala=ion: ~ ~uul- On any and all si~ of ill effects, pr~:ly re--ye person to u -,r, fresh air, keep him warm and quiet and get ~dical attention ~ ,~o-,,G t~-diately. S~art artificial respi~ation if breathing stops. ~ ~gestto~: ~oc ~:~y a p:ob~e~. ~ ~tqutd ta a~o~ed, do : ~ a phys~c~n ~d~a:e~y. ~:eve~: a~ con:ac: - a~:n, eye ~ ",,urfs inhalation. If expos~e occ~s, effects fr~ i~alation should ca"'u~"°m ( be loo~d for first and treated even thou~ skin and eye con=scl ~y have occ~red also. S.ctio. $ SPECIAL. PROTECTION INFORMATION Sufficient to control ~V., to 1 ppm - none; 1 ppm to 27. for 10 ~nutes or less, a ~11 face ~sk and acid Ess canister; ~eater, a self-contained brea=hin~ appara~ or equivalent. Rubber gloves, apron and boots and ~11 face shield over eye protection. lYE ' I ~o':',L~,~l~f~',~'' ~] Ey..e fountain and safety showers at work s.tatton.~ Section 9 SPECIAL PRECAUTIONS OR OTHER COMMENTS ~o atCemp~ should be made co handle or score Chlorine without a complete revte~ of the Dow Chlorine Handbook and/or the Chlorine Manual, available fro~ the Chlorine Institute. .FMC MATERIAL SAFETY DATA '?~A~4 ~ 2 FLAMMABILrTY fRED) NFPA Designation 704 '" PHOSPHORIC ACID (70-85~) DEGREE OF HAZARD 4 = EXTREME HEALTH REACTIVITY 3: .,GH <eLUE) (YELLOW) EMERGENCY TELEPHONES: 2=MODERATE 1 = SLIGHT PLANTS= (41 5) 793-1 ·231 NEWARK~ CA 0=,NSIGNF,CANT (913) 749--8100 LAWRENCE. KS (201) 541-4171 CARTSRET. NJ CHEMTREC: (800) 424-9300 TRANSPORTATION SPECIAL MEDICAL: (303) 595-90~8 ROCKY MTN HAZA.D REVZSION: EFFECTIVE: 10/17/85 PRINTED: 02/06/86 PREPARED FOR USE BY ....... BUSCH INDUSTRIAL PRODUCTS 5455 DISTRICT BLVD ATTN: MIKE HILLBERRY BAKERSFIELD CA 93313 INFORMATION PROVIDED BY..: FMC CORPORATION 2000 MARKET STREET PHILADELPHIA PA 19103 ==== ==~================ PRODUCT INFORMATION ==== == ==== = == SYNONYMS ................. : ORTHOPHOSPHORIC ACID. MONOPHOSPHORZC ACIO SHIPPING NAME - OOT ...... : PHOSPHORIC ACID IATA ..... : PHOSPHORIC ACID IMC0 ..... : PHOSPHORIC ACID FORMULA .................. = H3POfi CHEMICAL FAMILY .......... : PHOSPHATE ==== PRECAUTIONARY INFORMATION: === ====== PRECAUTIONARY STATERENT..: HEALTH= (PLEASE USE TH~S STATEHENT LIQU[D IS CORROSIVE TO E~ES AND SKIN. TO SATISFY THE IN-PLANT PROOUCE5 IRRiTATiON TO EYESx NOSE~ THROAT ANO LA~EL[NG REqUIrEmENTS LUNGS. OF THE OSHA HAZA~O CON~UN[CAT~ONS STANDARO PHYSICAL; NO SIGNIFICANT HAZARD. 29CFR 1910.1200) F[RST AID= IN CASE OF CONTACT/ IHNEOIATELY FLUSH EYES N[TH PLENTY OF ~ATER FOR AT LEAST 15 ~[NUTES. CALL A PHYSICIAN. FLUSH' SK[N ~[TH HATER. I~GREBIENT$ ============ CAS~ AND COHPONENT ....... = NATERZAL OR CONPONENT= PHOSPHORIC ACID PERCENT = 70-85 CA58 = 7664-38-2 HAZARD CLASS = CORROSIVE ~ATERIAL OR COMPONENT: PERCENT : ~ALANCE PAGE 01 -FMC MATERIAL SAFETY DATA 7 6 ~)~¢ 3 ~ ~ FLAMMABILITY '-' (RED) NFPA Designation 704 " P~tOSPHORiC ~.CID (70-35%) DEGREE OF HAZARD HEALTH REACTIVITY 4 = EXTREME (BLUE) (YELLOW) 3 = HIGH EMERGENCY TELEPHONES: 2=MODERATE 1 = SLIGHT PLANTS: (415) 793-1231 NEWARK. CA 0=,NSIGNF~CANT (913) 749--8100 LAWRENCE. KS (201) 5'41-4171 CARTERET. NJ CHEMTREC: (800) 424-9300 TRANSPORTATION S~EC~L HAZARD MEDICAL: (303) 595-9048 ROCKY MTN REVISION: EFFECTIVE: 10/17/85 PRINTED: 02/06/86 PHYSICAL! DATA' ================================= MELTING POINT ............ : -17.5C FOR 75%, ~21C FOR 85% BOILING POINT ............ : 130-158C VAPOR PRESSURE ........... : .03 MM HG@20C VAPOR DENSITY (AIR- 1)..: NON-VOLATILE ROOM TEMPERATURE APPEARANCE AND STATE: CLEAR, COLORLESS LIQUID ODOR ..................... : NONE SPECIFIC GRAVITY (H20 =1): 1.5-1.7 SOLUBILITY IN H20 % BY WT: INFINITE % VOLATILES BY VOLUME .... : NON-VOLATILE EVAPORATION RATE (BUTYL ACETATE = 1).: NON-VOLATILE PN (AS,IS) ............... : ABOUT 1.5 PH (1% SOLUTION) ......... : 1.7 FIRE." EXPLOSION'AND REACTIVIT~F DATA =========== FLASH POINT .............. : NON COMBUSTIBLE AUTOIGNITION TEMPERATURE.: NON COMBUSTIBLE FLAMMABLE LIMITS UPPER..: NOT APPLICABLE (AIR) LOWER..: NOT APPLICABLE EXTINGUISHING MEDIA ...... : NOT APPLICABLE SPECIAL FIREFIGHTING ..... : USE ,FULL PROTECTIVE CLOTHING AND SELF-CONTAINED PROCEDURES BREATHING APPARATUS. THERMAL DECOMPOSITION EMITS TOXIC FUMES OF OXIDES OF PHOSPHORUS. DEGREE OF FIRE AND ...... : NONE EXPLOSION HAZARD STABILITY ................ : STABLE HAZARDOUS POLYMERIZATION.: WILL NOT OCCUR CONDITIONS TO AVOID ...... : CONTACT WITH ALKALINE MATERIALS, REACTIVE METAL: MAJOR CONTAMINANTS THAT..: NONE CONTRIBUTE TO INSTABILITY INCOMPATIBILITY .......... : CONTACT WITH REACTIVE METALS (E.G. MILD STEEL AND ALUMINUM) MAY PRODUCE FLAMMABLE/EXPLOSIVE HYDROGEN - AIR MIXTURES. REACTS VIOLENTLY WITH STRONG BASES. .... HAZARDOUS DECOMPOSITION..: AT FLAME TEMPERATURES, WILL EMIT TOXIC PRODUCTS PHOSPHORUS OXIDE FUMES. -FMC MATERI.~L SAFETY DATA 7 ~<~4 38 2 FLAMMABILITY (RED) NFPA Designation 704 ~HOSPHORIC ACID (70-~5%) DEGREE OF HAZARD HEALTH REACTIVITY 4 =EXTREME (BLUE) (YELLOW) 3 = HIGH EMERGENCY TELEPHONES' 2: MODERATE ~ 1 = SLIGHT PLANTS: (415) 793-1231 NEWARK, CA O:INSIGNFICANT (913) 749--8100 LAWRENCE, KS (201) 541-4171 CARTERET, NJ CHEMTREC: (800) 424-9300 TRANSPORTATION SPEC,AL MEDICAL: (303) 595-9048 ROCKY MTN HAZARD REVISION': EFFECTIVE: 10/17/85 PRINTED: 02/06/86 ========================== ROUTES OF EXPOSURE ============================ EYE CONTACT .............. : SEVERE IRRITANT; CHEMICAL BURN LIKELY. SOURCE: RTECS DATE: I 980 SKIN CONTACT ............. : SEVERE IRRITANT, CORROSIVE TO TISSUE SOURCE: FMC SKIN ABSORPTION .......... : SLIGHTLY HAZARDOUS L050 (R~BBIT) = 2740 MG/KG SOURCE: RTECS DATE: I 980 INHALATION ............... : SEVERE IRRITANT - TCLO (HUMAN): 100 MILLIGRAMS PER CUBIC METER. SOURCE: RTECS DATE: 1980 TLV = I MG/CU. M SOURCE: ACGIH DATE: 1984-85 PEL = I MG/CU. M SOURCE: OSHA DATE: 1974 INGESTION ................ : SLIGHTLY HAZARDOUS. LO50 (RAT) = 1530 MG/KG SOURCE: RTECS DATE: 1980 ==== EFFECTS OF OVEREXPOSURE =='--=====:=============== ACUTE EXPOSURE ........... : IRRITANT, SLIGHTLY TOXIC WHEN INHALED OR INGESTED. CHRONIC EXPOSURE ......... : SLIGHTLY TOXIC WITH REPEATED INHALATION OR INGESTION. CAUSES BURNS TO EXPOSED TISSUE. ======================== EMERGENCY AND: FIRST AID PROCEDURES ====--=====~= EYES ..................... : FLUSH WITH COPIOUS WATER. FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, 06TAIN MEDICAL ATTENTION. SKIN ..................... : WASH OFF WITH WATER. IF IRRITATION PERSISTS, OBTAIN MEDICAL ATTENTION. INHALATION ............... : REMOVE FROM EXPOSURE. IF BREATHING IS DIFFICUL1 OR DISCOMFORT PERSISTS, OBTAIN MEDICAL ATTENTION. INGESTION ................ : RINSE MOUTH WITH WATER; GIVE COPIOUS WATER TO CAUSE DILUTION IN STOMACH. DO NOT CAUSE VOMITING. DECONTAMINATION P,ROCEDURE: WASH WITH COPIOUS WATER. PAGE 03 -FMC FLAMMABILITY MATERIAL SAFETY DATA 766/+ 38 2. ~ED) NFPA Designation 704 PHOSPHORIC ACID (70-$5%) OEGREE OF HAZARD 4=EXTREME HEALTH REACTIVITY 3 = HIGH (BLUE) (YELLOW) 2 = MODERATE EMERGENCY TELEPHONES: 1=SLIGHT PLANTS: (415) 793-1231;NEWARK. CA O:,NS,GNF,CANT (913) 7~9-8100:LAWRENCE. KS (201) 541-4171~ CARTERET. NJ CHEMTREC: (~00) 424-9300 TRANSPORTATION SREClAL HAZARD MEDICAL: (303) 595-9048 ROCKY MTN REVISION: EFFECTIVE: 10/17/85 PRINTED: 02/06/86 NOTES TO PHYSICIAN ....... : MODERATELY CORROSIVE AGENT WHICH MAY BURN ANY-EXPOSED TISSUES UPON OTHER THAN VERY BRIEF CONTACT. EYES. SKIN AND MUCOUS MEMBRANES SHOULD BE FLUSHED THOROUGHLY WITH WATER. AND DPHTHALMOLOGIC CONSULTATION SHOULD BE OBTAINED FOR ANY CORNEAL BURNS. IN CASES OF INGESTION. IMMEDIATE DILUTION WITH WATER. MILK OR DEMULCENTS IS WORTHWHILE. BUT ATTEMPTS TO NEUTRALIZE WITH A BASE SHOULD BE AVOIDED BECAUSE OF EXCESSIVE GAS AND HEAT FORMATION. WHICH MAY INCREASE THE THREAT OF ESOPHAGOGASTRIC PERFORATION. VOMITING AND , DIARRHEA (LAXATIVE EFFECT OF PHOSPHATES) ARE EXPECTED WITH LARGE DOSES. PARENTERAL FLUID ADMINISTRATION MAY BE NEEDED IF LOSSES THEREFROM ARE SEVERE. OR IF SHOCK ENSUES. SUPPORTIVE CARE MAY BE NEEDED FOR SUCH OTHER COMPLICATIONS AS GLOTTAL EDEMA. HEMATEMESIS AND PERFORATION (UNLIKELY). INDUCE£ VOMITING SHOULD BE AVOIDED BECAUSE LOCAL TISSUE INJURY MAY BE AGGRAVATED. BUT THE PATIENT SHOULD BE WATCHED FOR HYPERPHOSPHATEMIA AND HYPOCALCEMIA. MILK OR OTHER DEMULCENTS MAY BE WORTHWHILE FOR GASTRIC IRRITATION. =--=:==~--:~- ====-- SPECIAL~ PROTEC3'ION:' ====================== VENTILATION REQUIREMENTS.:' ADEQUATE TO MEET MAXIMUM EXPOSURE LIMIT FOR ACID MIST OF 1 MG/CU. M IN $ HOURS. RECOMMENDED PERSONAL ...... : PROTECT EYES AND SKIN FROM CONTACT. PROTECTIVE EQUIPMENT, RESPIRATORY ...... ~:: FOR SEVERE MIST USE NIOSH/MSHA ACID GAS RESPIRATOR WITH FULL FACE PIECE OR IN SEVERE ' EXPOSURE USE SELF-CONTAINEO BREATHING APPARATUS. PAGE 04 -FMC MATERIAL SAFETY DATA 7664 38 2 FLAMMABILITY · fRED) NFPA Designation 704 P'HOSPHORIC ACID ('70-85%) DEGREE OF HAZARD 4 = EXTREME HEALT REACTIVITY 3 = HIGH (BLUE) ~r~,. ~ (YELLOW) EMERGENCY TELEPHONES: 2=MOOERATE 1 = SLIGHT PLANTS: (415) 793-1231 NEWARK, CA O=INSIGNFICANT (913) 749--8100 LAWRENCE, KS (201) 541-4171 CARTERET, NJ' CHEMTREC: (800) 424-9300 TRANSPORTATION S,EC,AL MEDICAL: (303) 595-9048 ROCKY MTN HAZARD REVISION: EFFECTIVE: 10117/85 PRINTED: 02/06/86 SPECIAL PROTECTION ============= ==== ===== === EYES .............. : WEAR CHEMICAL GOGGLES, IF SPLASHING, SPRAY OR MIST CONDITIONS ARE POSSIBLE. GLOVES ............ : RUBBER, NEOPRENE OR OTHER RESISTANT ELASTOMER SPECIAL CLOTHING..: WHERE CONTACT IS LIKELY, RUBBER APRON AND BOOTS. AND EQUIPMENT STORAGE AND HANDLING ======== ======== ====== (PLEASE USE THIS STATEMENT USE GOGGLES AND/DR FACE SHIELDS, RUBBER APRONS, TO SATISTY THE IN-PLANT GLOVES AND BOOTS WHERE SPLASHING OR LIQUID LABELING REQUIREMENTS CONTACT IS EXPECTED. FOR EXPOSURE TO AIRBORNE OF THE OSHA HAZARD MIST USE NIOSH/MSHA ACID GAS RESPIRATOR WITH COMMUNICATIONS STANDARD FULL FACEPIECE. STORE IN SUITABLE CONTAINERS 29CFR 1910.1200) (E.G. GLASS,' FIBERGLASS REINFORCED PLASTIC, POLYETHYLENE LINED DRUMS, TYPE 316 STAINLESS STEEL). == == ==*=== DISPOSALW SPILL'OR LEAK PROCEDURES ==== - = PROCEDURE FOR RELEASE .... : DIKE AND SALVAGE OR NEUTRALIZE. SODA ASH OR SPILL AND LIME ARE NEUTRALIZING AGENTS. WASTE OISPOSAL METHOD .... : IF MATERIAL CAN NOT BE SALVAGEO, A METHOD IS NEUTRALIZATION FOLLOWED BY DISCHARGE INTO A TREATMENT SYSTEM IN ACCORDANCE WITH ALL LOCAL. STATE.'AND FEDERAL REGULATIONS. TRANSPORTATION~DATA DOT PROPER SHIPPING NAME,: PHOSPHORIC ACID DOT CLASSIFICATION ....... : CORROSIVE MATERIAL DOT LABELS ............... :CDRROSIVE DDT MARKING .............. : PHOSPHORIC: ACID UN 1805 DOT PLACARD .............. : CORROSIVE UN NUMB ER ............... : UN 1805 ' HAZARDOUS SUSSTANCE/RQ,,,: 5000 LBS,. (2270 KG) 49 STCC NUMBER ........... = 4930248 ,.. EMERGENCY ACCIDENT PRECAUTIONS AND PROCEDURE: FLUSH WITH LARGE AMOUNTS OF WATER PAGE 05 -FMC MATERIAL SAFETY DATA 7654 3~ 2 FLAMMABILITY (RED) NFPA Designation 704 P'HOSPHOR'IC ACED (70-85%) DEGREE OF HAZARD ,~ HEALTH~ REACTIVITY 4 = EXTREME (BLUE) (YELLOW) 3 = HIGH EMERGENCY TELEPHONES ~ 2=MODERATE 1 = SLIGHT PLANTS: (415) 793-1231 NEWARK, CA O=INSIGNFICANT (913) 749--8100 LAWRENCE, KS (201) 541-4171 CARTERET, NJ CHEMTREC: (800) 424-9300 TRANSPORTATION SPECIAL HAZARD MEDICAL: (303) 595-9048 ROCKY MTN REVISION: EFFECTIVE: 10/17/S5 PRINTED: 02/06/86 TRANSPORTATTO#' DATA PRECAUTIONS TO BE TAKEN..: PROTECT AGAINST PHYSICAL DAMAGE IN TRANSPORTATION CMA CHEMC~RO NUMBER ...... : NONE TYPE PACKAGES ............ : ~ULK ACID TRUCKS OR RAILCARS; DRUMS OTHER SHIPPING IDS ....... : AODZTZONAL REGULATORY' INFORNATZON ==========='--- MATERIAL IS REPORTEO IN EPA TSCA INVENTORY LIST? YES MATERIAL IS LISTED ~S A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING NTP ANNUAL REPORT... ? NO I,ARC MONOGRAPHS ..... ? NO OSHA 29CFR PART 1910 SU~PART Z ? NO FDA GRAS lIST; PERMITTED IN FO00. USOA PERMITTED IN MEATS. PAGE 06 · '-~- ,:-. 45~. INDUS HYGIENE, TOXICOLOGY, AND M~ [RIAL NO~: NO REPRESE~ATION IS MADE AS TO THE ACCURACY OF THE INFORMATION ........ HEREIN, SEE PAGE 7 FOR CONDITIONS UNDER WHICH DATA ARE FURNISH~. Trade Name and Synonyms 00753 ~L OIL Manufacturer's Name _: . . .. Emergency Telephone No. . .. Texaco [~c. ~9~4) 83~-3~00 ext. 204 Address . .- P,O, ~ox' 509 Beaco~ NY Chemical Name and/or Family or Description .~...; . :,,. .... .. ... THIS PRODUCT IS CLASSIFIED AS: NOT HAZARDOUS: ~ HAZARDOUS 9Y DEFINITION NO.(S) [ ' [0 ON A~ACHED EXPLANATION SHE~S WARNING STATEMENT: ...... "~ ~i..~::: .~:~;.. H2S GAS ~Y CAUSE IRRITATION TO EYES Protective EQuipment (Type) ~i Eyes: .. Chemical type goggles or face shield optional. Skim . Exposed employes should exercise reasonable personal cle~liness;... this includes cleansing exposed skin areas several times daily " with so~p and water, and laundering or dry cleaning soiled work ~ .. ¥:.~- ~'-'-'"clothing at' least weekly;=' Gloves'resistant to chemicals' and ~--pet=oleum distillates reco~ended .......................... . ' Inhalation:' ' MS~ approved pos. pressure air supplied respirators'-if H2S:"Level': '' ............... is ~kno~ o~ exceeds 20ppm limit (See "Addtional Cements" pg.6) Ventilation.' - :'J2;:'Adequste to meet 'permissible-concentrations;~';:-:-:i;-?!; ............. Permissible Concentrations: .' .... '.. · .... ' Aim. ~;:: None established, fo~ coal ta= pitch volaLiies'~ 0.2 mg/m3 TLV/TWA ~ 7. H2S TLV/TWA- 10ppm (ACGIH 1984-85). OS~ H2S-ceiling i'imit- 20ppm ~ Eyem ' As with most ~oreign materials, should eye contact occur, flush :. eyes with plenty of water. '-.' ' ;'~':-:~'::' Wash exposed ~reas with J'oap~nd water. Ingestion: Do NOT induce vomiting.' Aspiration may cause chemical pneumonia. inhalation: · : ShOuld symptoms .noted under physiological effects occur, remove -;: ..: .: to fresh air. If not. breathing, apply artificial respiration. Other Instructions: None. N.D. - Not Determined N.A. -Not Applicable < - Less Than > - Greater Than 1 :::' ' :' ..: .. · '~:! '.' '.....i" :: .~:!:!:!: ........ ::::::::::::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::: :!:!:!:i:!:i:!:~F.~:!:::!:::i::i:i:!:!:~::!~!::~hi::!:!:!:!:i:!:~:!:!:i:!:i:!:!:!:i:!:i!ii:iE ii:: ..:"'":" -- Effects of Exposure · Acute: ................................................. ' ................ '~i Eyes: Believed to be'minimally irritating· ' 'F. -- :~ ~- __'~L-_ £ ............ · ............ j_:. .~_Skin: Believed to be slightly irritating with possible redness, ._ ~ edema or drying of the skin. May cause derma[iris on prolonged ':"~. '" · '- ' or. repeated contact ....................................... '. -:' Respiratory'System:-H2S gas-can cause irritation to the throat and lungs, nausea and dizziness. Death by suffocation may also occur. See other below. Chron,c: Based on compositional analysis, this product may cause skin cancer in laboratory animals when repeatedly applied for most of ........... the lifetime of the animal with no effort made to remove the oil '..: between applications (See additional comments, p. 6.) · . ..~ . !,.. ... . .. :. . .... .~. Other: CAUTION! H2S has poor warning properties, fatigues s'ense of smell ..... . ~-.. i .--- ¢ ' ". ~ . -. - ; . ' ' - ~ "' ' ." - ~ -~ '. : ,. Sensitization Properties:. . -: · ..... .. : .-.' _ .: ;:. Skin: Yes No -- Unknown X " ...... Respiratory:. Yes No Unknown X , Median Lethal Dose (LDs0 LC 50 )(Species)-. . . · Oral Believed to be > 5 g/kg (rat); practically non-toxic Inhalation N. D. Dermal Believed to be > 3 g/kg (rabbit); practically non-toxic Other N.D. irritation Index. Estimation of Irritation (Species-}" " Skin Believed to be 0.5-3.0/8.0 (rabbit); slightly irritating Eyes Believed to be < ·15/110 (rabbit); no appreciable effect ,. Symptoms of Exposure See above Ignition Temp.°F. N.D. Flash Point OF. (Method) 150°F (PM) Flammable Limits (%) Lower N.D. Upper N.D. Products Evolved When Subjected to Heat or Combustion: Carbon monoxide and carbon dioxide may be formed on burning in limited air supply. RecommendedFire Extinguishing Agents And Special Procedures: According to the National Fire Protection Guide 49, combustible liquid fires may be extinguished by water spray, dry chemical, foam or carbon dioxide. Use water to keep fire-exposed containers cool. If a leak or spill has not ignited, use water spray to · disperse the vapors and to provide protection for persons at- tempting to stop the leak. Unusual or Explosive Hazard~ None. N.D. - Not Determined N.A. - Not Applicable < - Less Than > - Greater Than 2 Waste Disposal Method: Under RCRA, it is the responsibility of the user..of products to determine, at the time of disposal, whether product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixture, processes, etc. may render'the resUlt- ing material hazardous. (See Remarks for Waste Classification.) Procedures in Case of Breakage or Leakage: [Transportation Spills Call CHEMTREC (800) 424-9300) · Ventilate area. Avozd breathing vapor. Use self-contained ,. breathing apparatus or supplied-air mask for large spills in con- fined area, Contain spill if possible. Wipe up or a, bsor. b.on suitable material and shovel up. Remarks: Waste Classification: Product has been evaluated for RCRA charac- teristics and does not meet criteria of a hazardous waste if discarded in its purchased form. DANGER! MAY RELEASE HYDROGEN SULFIDE {H2S) GAS MAY BE FATAL IF INHALED. COMBUSTIBLE H2S GAS MAY CAUSE IRRITATION TO EYES. MAY BE HARMFUL TO SKIN May cause skin cancer in laboratory animals. H2S gas ~nay accumulate in confined spaces that have contained this product Avoid breathing gas, vapor or mist. Avoid contact with eyes; skin or clothing. Avoid heat, sparks and flames. Wash thoroughly after handling. If contact is unavoidable, wear appropriate oil-impervious clothing. Requirements for Transportation, Handling and Storage: Store away from heat and open flame. Placard required only when material is contained in packaging or container that exceeds 110 gallons, or in tank car or tank truck. Transport, handle and store in accordance with Regulation 1910.106, and applicable D.0.T. regulations. DOT Proper Shipping Name: Fuel 0il No. 6 DOT Hazard Class (if applicable).' Combustible liquid NA1993 Boiling Point (oF) N.D., Vapor Pressure N.D. (mmHg) SPecific Gravity .946 (H20= 1) Vapor Density ,N.,.D. (Air= 1) Appearance and Odor - pH of undiluted product N.A. Solubility N.D. Percent Volatile by Volume N.D. Evaporation N.D. ( )=1 Viscosity 315 SFS @ 122°F Other - 'Hazardous Polymerizations Occur X Do not occur The Material Reacts Violently With: (If others is checked below, see additional comments on page 6 for luther details 'Air Water - Heat Strong Oxidizers Others None of These N.D. - Not Determined N.A: - Not Applicable .... "' ' .' < - Less Than > - Greater Than 3 Chemical/Common Name CAS No. Exposure Limit' Range in / Atmospheric tower petroleum residues (CAS No. · 100.00 64~41453) or lil~ht: yacuum petroleum residue- :. s (CAS No. 64741566) blended with heavv cat- ~.'. alytic crac~ked petroleum distillates (~AS N- "o. 64741613), l~gh.t catalytic cracked petro- : leum di~tillate~ (CAS No. 64741599), or cat- :~ alytic Cracked clarified petroleum oils (CA- S No..64741624) to pre,or,bed viscosity ran- - ges. '~" · · . . ~{] C~ ~.~.~ :~ -: . . · . Evaluation o~"this product indicates that it is hazardous according to 0S~ Appendix A criteria mhd/or Texaco'~ hazard criteria. . . {y.. ] _~'. ... . ]....- :~ ,-. 4 1532 B~ddle Avenue ~ .( 'Wyandotte, MIchigan 4S192 Emergency Telephone (313) 281-0930 -... SECTIONI-- PRODUCT IDENTIFICATION Product ACCORD II PC Description Iodine Detergent Sanitizer and EPA 8/82 Chemical Mixture -- Germicide EPA Registration Number: 875-97 SECTION II -- HAZARDOUS INGREDIENTS CAS Number Chemical Component % TLV (Units) Hazard Data 58439-47-4 !Alkylpolyoxyethylene poly- Corrosive to skin, eyes oxypropylene iodine complex 13.1 - and mucous membranes. 11096-42-7 Oc ty lphenoxypo lyoxye thylene iodine complex 6.9 - Rat - Oral LDs0 2.8 gm/kg 7664-38-2 Phosphoric acid 18.5 ~ mg/m3 SECTION 111 -- PHYSICAL DATA I Appearance Solid Liquid XX and Odor Dark brown liquid with iodine odor cificGravity 1.140 pH at 25°C ........ As shipped Solubility in Water Complete Freezing Point 28OF (_3oc) Percent Volatiles f.l~y weight) Phosphorus ~one 5.9% P Halogen 1.75% titratable iodine SECTION IV -- FIRE AND EXPLOSIVE HAZARD DATA Flammable I LFL t UFL Flash Point (method) NA. Limits NA - - Extinguishing Media Water, water fog. Special Fire Hazards and Equipment,Required Corrosive liquid. Good firefighting practice requires use of full turn-out gear and self-contained breathing apparatus for fires in area of stored product. ATTENTION: Spilled product will cause slippery surfaces. SECTION V -- REACTIVE HAZARDS Product ~ H a z a r d o u s Will Not Occur Stable Below 130°F Unstable at __.]._4.D_ "F F;~ °C 1 Polymerization None 3~[~:,0x Conditions High temperatures will release iodine vapor. Keep from freezing. · '.void Incompatibility Do not mix with ammonia, bleaches or other chlorinated (Materials to Avoid) compounds. Hazardous High temperatures such as in combustion will release Decomposition Products iodine vapors. - Product ACCORD II sEcTION V1 -- HEALTH HAZARDS es Corrosi.ve - Severe bUrns ~r irritation resulting in ~n2~eversible damage to 'cornea and conjunctival tissues. :in Corrosive - Causes burns or severe irritation. Wash thoroughly with soap and water after use. ~estion May be fatal if swallowed. Causes burns or possible mucosal perforation Of stomach or esophagus. Causes diarrhea and possibly vomiting. ,elation Mists or vapors may cause irritation of nose, IThresholdLimitVatue throat and pulmonary tissues. ': I Not established inCipal Routes Of Absorption Direct contact, ingestion, inhalation. ~ute Ef f~ct~ Overexposure Corrosive action on skin, eyes and mucous membrane tissues. nronic Effects of Overexposure None known. F RsT P 0cEUURE-- SW e¢ S ¢LUmS OR NDUCE VO mNG PATIENT UNCONSCIOUS OR HAVING CONVULSIONS. CALL A PHYSICIAN. Flush immediately with water for about 15 minutes. Get prompt medical .'es attention. ;in Wash thoroughly with soap and water. ~estion If swallowed, drink promptly a <large quantity of milk, egg whites or gelatin solution or if not available, large quantities of water. Avoid · alcohol. NOTE TO PHYSICIAN: Probable mucosal damage contraindicates the na a~ort use of gastric lavage. If breathing difficulty de~elops, remove to fresh air. Ge~t medical " attention. SECTION VII -- NORMAL HANDLING PROCEDURES ... ecautions to be taken Store in a cool area between 40° to 100°F. Avoid freezing. , Handling and Storage. KEEP OUT OF REACH OF CHILDREN. Use only in accordance with label use directions. Do not mix with other cleaners or chemicals or hazardous qases or heat maV be qenerated. -otective Equipment 'Ventilation Requirements fee Goggles or side-shield safety glasses. Generally not required unless large loves Rubber or chemical resistant, amount of mists are generated. Clothing to prevent skin contact. ther -~rr°siveActi6n°n Paint and ~ost metals. Product will stain plastics. aterials SECTION VIII -- SPILL OR LEAK CONTROL PROCEDURES :eps to betaken in Contain spill. Absorb with sand or clay. Neu~ra±~ze w~t~ a ~se of Spills. dilute alkali. Neutralize iodine with thiosulfate solution. Discharge liquid to a sanitary sewer. Wash affected area with water. ,asie Disposal D%i~te s~Zutions should be neutralized to a~3ust pH.w~(n soda ash iethods or dilute~ alkali./~ Neutralized solutions usually acceptable by sa~far~ew~/1 See l~el d~rections for ¢o~ta_iner disposal statement. he above information is believed to be accurate and discloses the known hazards for this product as o! this date. No additional warranties are made. Signed~ /~, ..... Date -. DIVERSEY WYAi~ OCcidental Chemical COrporation-- MSDS 433 A industrial & Specialty Chemicals Division ~~ M AT F R. I A L S~A F F TY' DATA S H F F T'i~;~_~ PrOduct Information Product Name CAS Registry Number SODIUM HYDROXIDE, 50% LIQUID 1310-73-2 Common Name or SYnonym Chemical Family Caustic soda Alkali Lye Chemical Name Chemical Formula Sodium hydroxide NaOH Health Data DANGER~ SODIUM HYDROXIDE CAN CAUSE SEVERE BURNS OR BLINDNESS. · PROMPT TREATMENT IS IMPORTANT TO MINIMIZE EFFECTS OF OVEREXPOSURE, First Aid Measures Eye Contact: IMMEDIATELY, flush eyes with a Effects of Overexposure: Sodium hydroxide directed stream of water for at least 15 minutes. "" as a solid or in dusts, mists or solutions may Forcibly hold eyelids apart to ensure complete cause irritation of the eyes and, with greater irrigation of all eye and lid tissue. GET IMMEDI- exposure, severe burns with possible blindness. ATE MEDICAL ATTENTION.. Contact lenses Contact of the skin may cause skin irritation should not be worn when working with this and, with greater exposure, severe burns with chemical, scarring. Ingestion of sodium hydroxide may cause intense pain, nausea, vomiting and col- Skin Contact: IMMEDIATELY flush contamin- lapse. Swallowing sodium hydroxide may cause ated skin with water and wash with soap and severe burns of the mouth, throat, esophagus water, if large areas of the body are contamin- and stomach. Death may result. ated or if clothing is penetrated to the skin, Inhalation of dust or mist can cause injury to the immediately use safety shower preferably entire respiratory track. Repeated local contact removing clothing while under the shower. Flush of dusts, mists or solutions may cause burns exposed areas with large amounts of water for and permanent scarring. Cases' of squamous at least 15 minutes. GET PROMPT MEDICAL cell carcinoma of the esophagus have occurred ATTENTION. Wash clothing before reuse. years after ingestion. Inhalation: If a person breathes in a large Sodium hydroxide solutions cause burns on con- amount of mist, move the exposed person to fresh tact with all body tissues. Prolonged contact air at once. If breathing has stopped, perform with even dilute sodium hydroxide solutions may cause tissue destruction. A latent period may artifical respiration. Keep affected person warm and at rest. GET IMMEDIATE MEDICAL exist between exposure to skin and sense of ir- ATTENTION. ritation. In human studies skin irritation has been observed at concentrations as Iow as 0.12% for Ingestion: If person is conscious, immediately one hour. administer large quantities of water. Do not induce Toxicity: Acute. Oral Toxicity vomiting. Avoid having an unconscious person vomit. GET IMMEDIATE MEDICAL ATTENTION. LDLo (rabbit, 10% solution): 500 mg/kg Corrosive to animal tissues. '~..? '~ ~'.-_,.~ ?: c~i ~ c. ;"~ ~ ~ .:~ ?'!',.: ~ ;-_.. ~-;' _.~w ~!~ :~ ::,!.~ ~ ,'.. '.-i ::'-'-_. I ).-t_.. ,...-,,~.., -~ ?'. ".~ ./':~ :'... T"-. '~ ' ,Sodium Hydroxide, 50% Liquid ....... MSD~%,", · ;~MATERIAL SAFFTY DATA SHFET~ Fire and EXplosion Hazard Data Flash Point: Not Flammable Unusual Fire and Explosion Hazards: Water when added to sodium hydroxide solutions Special Fire Fighting Procedure & Personal may cause localized overheating and possible Protection: Not combustible. Use clothing and splattering. Sodium hydroxide reacts with safety equipment as may be suitable for sodium aluminum, zinc and their alloys generating hydroxide and materials in the surrounding fire. hydrogen gas which is flammable and/or explo- sive when ignited. Extinguishing Media: Not combustible. Use extinguishing agents, as may be suitable for materials in surrounding fire. Special Protection Ventilation: Ventilation is not usually required Eye Protection: Use chemical goggles and for caustic solutions. Avoid creation of mist or face shield where appropriate. spray. If present wear appropriate safety cloth- ing and provide local exhaust systems. Other Protective Equipment: Maintain eye Respiratory: Provide mist protection where wash and safety showers in immediate handling applicable. Use NIOSH or MSHA approved areas. Provide impervious rubber or neoprene respirators, suits, rubber shoes or boots and plastic hard hat with brim. Gloves: Use impervious rubber, neoprene or vinyl gloves. Physical Data Boiling Point Appearance and Color 293°F Water white to slightly gray, odorless solution. Vapor Pressure Specific Gravity 1.5 mm Hg @ 20°C 1.541 @ 60°F/60°F (12.8 lbs/gal) Solubility In Water Melting Point Infinite 55 ° F 2 ~n.... ," .... ", .... ... ~.... '"?: ~ '.'"";","~,:::'i::',~. ~ .,....., ........... }"!....!::'!:,;1 !.,'.'3"i'';''''~. .... 'v!:',~,i'.,~ ,, ,_. .......... I'".'::::;!::' '::; ,"", r'~ F';i'"~:!i:' ?()(.',() ,...,~ ~....."'.:""~:::' .~. ~...~, . ............ · .......... !'::'! 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C': :[. :"~ 0 ,"':, ,... ...... v 'f "" ':*' ::' '"':"; "' "' C" 'l :;~; :::';: "'" :::' i":' }',"":::; "::' :s Ei H :iii: ~qM]:N(3SUL. F' L.i t::; :]; C: A i::: :l; !;i ; !i;UL.F'¢'~M:I:C ¢"~C'-:!::0 7'O"-:) LBS° ?,400 !...B'.E;~ Ak'i '!' N ': S L.::'E i'-..! '[: :"~ ~"'~.'.'~ .;: ~.~ i~i (3 N (3 :(~': F", O i*! (3 "¢' i::-: 2: i::' !... l.J (:) I:;,' C) hi !E T H r":~ N IE :~""f' ( 4""¢"~NZNC)"-2'"NiET?'tYi._""5 .... I"l~'/L.E~i".l :I.:2;O:!. ~: F'F.',iEON F:'E: :1.?"':O~. :!. ~4:!. !...8!ii; -.'. F' Y F: :I: M Z D :,r. i',! Y !._ ) ~'-t ...... Y :(' I::.; t'~ X Y F:' "[' !'! Y !... ~. -... ,:).-, .-.. N,,...,,,, ,...t::' "," .4 v ~ .... 'f'I'! ;[: ~ Z O L. ;[ LJ N C ).-I L.(3 !:"; :t: DE N O N (:) C l-f I... (:) I;; Z D Iii: T !"i Z :'"~ Pi :i: N E !--! C !. ? 5 F: g ':!-:' 0 ,:.'.', !':; ?'~P~[.'-.'ih!ES 2 Ui"! ::ii;tJl_F'.,"~T!.'T. ~., H iii: F'"f' A H Y:(3 F.: ¢'.. T !ii: !ii;!::'.S !3 H S ¢"~. L. T f'i ¢~ (3 ?'4 I::; !i.": :1: "-..; Pi 'ii~ L.! [... F' f::~ T ~' 1 (!i; ~. i::, . 1 '~: ,""~ ,"~ I....'(.i'~ :!ii; · :i. (~ ? P, ¢"~/~ '... ;.; i". ? ,. -:- , ¥ ......-. ,~ ..., ..., ,.. i r-...., ....... · :>U;._I .~ ~:: :~.50 I ¥:.,,,.'::; :l.'"r,"'. ~ ¥:.,,:::- ':21j~ t:: ~'¢',, 'f'I::' f3F' .":i ?i ?'4 (;) i',! Z ,'"'~ ~:~f"i!"i(3~,lZUi"! " .... ACCORD II (IODINE DETERGENT SANITIZER) SPILL ACTION PLAN SEE ATTACHED M.S.D.S. FOR INFORMATION ON: A) General Information B) Chemical and Physical Data C) Potential Hazards D) Protective Clothing and Equipment E) First Aid F) Fire Response G) Spill Response Accord II is a corrosive liquid which can cause burns or severe irritation. Spilled product will cause slippery surfaces. Should a major leak occur: 1. Notify people as shown on attached reporting chart. 2. Keep all personnal out of affected area. 3. Contain spill, absorb with clay or sand. Neutralize with a dilute alkali or soda ash. 4. If anyone is injured; call paramedics. PHOSPHORIC ACID SPILL ACTION PLAN SEE ATTACHED M.S.D.S. FOR INFORMATION ON: A) General Information B) Chemical and Physical Data C) Potential Hazards D) Protective Clothing and Equipment E) First Aid F) Fire Response G) Spill Response Should a major phosphoric acid leak happen: 1. Wear protective gear as required. Phosphoric acid is a moderately corrosive agent which may burn any exposed tissue. 2. Keep all personnal out of affected area. 3. Notify people as shown on attached reporting chart. 4. Dike area and neutralize with soda ash. 5. If anyone is injured; call paramedics. Note: Any spill of five thousand (5000) pounds or greater must be reported to the National Response Center. CAUSTIC SODA (SODIUM HYDROXIDE) SPILL ACTION PLAN 1. General Characteristics Sodium Hydroxide is a clear, odorless liquid. 2. Potential Hazards Sodium Hydroxide is a strong alkali and is destructive of all human tissues it contacts, giving severe burns. Eye contact will produce severe or permanent injury. Inhalation of mist or spray can injure the entire respiratory tract. Sodium Hydroxide will react with metals such as aluminum, tin and zinc to generate flammable and explosive hydrogen gas. 3. See attached M.S.D.S. for information on: A) General Information B) Chemical and Physical Data C) Potential Hazards D) Protective Clothing and Equipment E) First Aid F) Fire Response G) Spill Response 4. Dike area and neutralize with dilute acid and rinse with water. 5. Keep all personnal out of affected area. 6. Notify people as shown on attached reporting chart. 7. If anyone is injured; call paramedics. NOTE: Any spill of 1000 pounds or greater must be reported to the National Response Center. WORKER "SPILL" DAN ENSEY OFFICE 835-8385 J 'SAFETY HOME 834-2337 1 C.WALKER 398-7220 PAGER 329-4946 DICK HUGHES OFFrCE 834-I050 HOME 398-t404 M. HILLBERRY OFFICE 834-1050 HOME 832-5765 BAKERSFIELD CITY FIRE ~ 1., HAZARD MATERIAL DIVISON (805) 326-3979 AS NEEDED FIRE/RESCUE' 911 or (805) 324-4542 California Office Of ] EMERGENCY RESPONSE L from Calif,(800)852-7550~ out of state 1-(916)427-4341 , i~A~ERSFIELD POEIC~ i , ,AS N~?~D .... (805) 327-7111 REGION 9 EPA I (415) 974-8131 . :~ VACUUM,:TRDCK'SERVICE 'M~P VACUUM (805) 393-1151 1' K.C.A.P.C.O. ~AS NEEDED AS NEEDED KERN' VACUUM 'SERVICE (805) 861-3682 [DEPENDING ON TYPE - (805) 589-5220 OF SPILL - 'h'AZARDCu~ MATE~L NATIONA~E~ONSE ~ DISPOSAL:COMPANY 1 (800)'852-7550 (805) 763-4171 AS NEEDED CHEMICAL WASTE MGT. ~ (800) 222-2964 WASTE CONTROL SVC. (805) 399-4620 II ITERNAL PJ PORTING FOREMAN/SUPERVJ SOR M.,.MCCOY 833-6645 J, FREEMAN 836-0885 ' C,WALKER ....... 398-7220 ': .......... PLANT 'EN(~'I'NE~R COOP ATOR D,ENSEY HOME 834-233? D,' HUGHES 398-1404 C,WALKER 398-7220 PAGER 329 -4946 , .................. OFFICE ·835'8385 pLANT MANAGER > CORPORATE MANAG~ME~NLT_ M,HII l BERRY : JOHN RIESCH · .... HOME ....... 832-5765 OFFICE 1(314) 577-710] -'HOME'"I(314) 645-923~ CORPORATE ENVIRONMENTAL_ CORPORATE RISK C,JOST OFFICE 1'(314) 577-4162 MANAGEMENT AND · HOME 1'(314) 962-7336 _INSURANCE J'STEINoFFICE 1(314) 577-4160 J,W,ROBSON HOME 1(314) 227-7467 ,. ......... 1(314)...577-2318 F;.J; HRUBY 1(314) 577-3202 <' '' · , S,J, CORTORPASS · '. ........ 1(314) 577-40621 COMMON MSD$ TF_RM$ negligible Less than 0. I percent slight 0.1 to 1.0 percent moderate I to 10 percent appreciable more than 10 percent : complete soluble in all proportions SOx Oxides of sulfur; undesirable air pollutants. SOx emissions are regulated by EPA under the Clean Air Act. Species A biological type; on MSDSs, species refers to the test animals - usually rats, mice, or rabbits -which were used to obtain the toxicity test-data reported. Specific gravity The weight of a material compared to the weight of an equal volume of water; an expression of the density (or heaviness) of the material. Example: if a volume of a material weighs $ pounds, and an equal volume of water weighs 10 pounds, the material is said to have a speci- fic gravity of ~ lbs = 0.~ lO lbs Insoluble materials with specific gravity of less than 1.0 will float in (or on) water. Insoluble materials with specific gravity greater than 1.0 will sink (or go to the bottom) in water. Most (but not all) flammable liquids have specific gravity less than 1.0 and, ii not soluble, will float on water - an important consideration for fire suppression and spill clean-up. Stability An expression of the ability of a material to remain unchanged. For MSDS purposes, a material is stable if it remains in the same form under expected and reasonable conditions of storage or use. Conditions which may cause instability (dangerous change) are stated - examples, temperatures above 150°F, shock from dropping. STEL Short term exposure limit~ ACGIH terminology. See I'TLV-STEL,,. Synonym Another name or names by which a material is known. Methyl alcohol, for example, is also known as metha- nol, or wood alcohol. Page -17- COMMON MSDS TERMS T TCC Tag (Tagliabue) Closed Cup; a flash point test method. Teratogen A substance or agent to which exposure of a pregnant female can result in malformations in the fetus. TLV Threshold Limit Value; a term used by ACGIH to .express the air-borne concentration of a material to which nearly all persons can be exposed day after day, without adverse effects. ACGIH expresses TLVs three svays: TLV-TWA: the allowable T__i m e __Weighted A__verage concentration for a normaJ g-hour work- day or ~0-hour work week. TLV-STEL: the Short-Term _Exposure --Limit, or max- imum concentration for a continuous 15-minute exposure period (maximum of four such periods per day, with at least 60 minutes .between ex posure periods, and provided that the daily TLV-T~'A is not exceeded). TLV-C: the Ceiling exposure limit - the concen- tration that should not be exceeded even instan- taneously. Also see "Skin" in the Glossary relative to TLVso TOC TAG Open Cup; a flash point test method. Toxicity The sum of adverse effects resulting from exposure to a material, generally by the mouth, skin, or respiratory tract. For RCRA purposes, solid or liquid wastes which exhibit certain specified "characteristics of -t. oxicity" may be regulated by EPA as hazardous wastes. Trade Name The trademark name or commercial trade name for a material. TSCA Toxic Substances Control Act; Federal environmental le§islation, administered by EPA, for regulating the manufacture, handling, and use of materials classified as "toxic substances". T~/A Time Weighted Average exposure; the airborne con- centration of a material to which a person is exposed, Page -18- COMMON MSDS TERMS averaged over the total exposure time-generalLy the total workday (g to 12 hours). Also see "TLV". U UEL, or uFL Upper explosive limit or upper flammable limit of a vapor or gas; the highest concentration (highest percen- tage of the substance in air) that will produce a flash of fire when an ignition source (heat, arc, or flame) is present. At higher concentrations, the mixture is too "rich" to burn. Also see "LEL". Unstable Tending toward decomposition ar other unwanted chemi- Cal change during normal handling or storage. USDA U.S. Department of Agriculture; prior to 1971, USDA performed tests and issued approvals on respirators for use with pesticides. In 1971, the Bureau of Mines took over the pesticide respirator testing/approval functions - procedures later delegated to the Testing and Certification Branch (TCB) of NIOSH. Also see "BOM". V Vapor density The weight of a vapor or gas compared to the weight of an equal volume of air; an expression of the density, of the .vapor or gas. Materials lighter than air have vapor densities less than 1.0 (examples: acetylene, methane, hydrogen). Materials heavier than air (examples: pro- pane, hydrogen sulfide, ethane, butane, chlorine, sulfur dioxide) have vapor densities greater than 1.0. All vapors and gases will mix with air, but the lighter materials wiiI tend to rise and dissipate (unless confined). Heavier Vapors and gases are likely to con- centrate in iow places - along or under floors, in sumps, sewers and manholes, in trenches and ditches - where they may create fire or health hazards. Vapor pressure The pressure exerted by a saturated vapor above its own liquid in a closed container. When quality control tests are performed on products the. test' temperature is 'usually iO0°F and the vapor pressure is expressed as pounds per square inch (psig or psia) - but vapor Page.-19- COMMON MSDS TERMS pressures reported on MSDSs are in millimeters of mer- cury (mmHg) at 65°F (20°C), unless stated otherwise. Three facts are important to remember:· I. Vapor pressure of a substance at 100°F will always be higher than the vapor pressure of the substance at 65°F (20°C). 2. Vapor pressures reported on MSDSs in mmHg are usually very low pressures; 760 mmHg is equivalent to 1¢.7 pounds per square inch. 3. The lower the boiling point of a substance, the higher its vapor pressure, Ventilation , See "general exhaust", "local exhaust", and "mechanical ventilation". Page -20- COMMON MSD$ TERMS NIOSH National Institute for Occupational Safety and Health of the Public Health Service, U.S. Department of Health and Human Services (DHHS); Federal agency which - among other activities -tests and certifies respiratory protective devices and air sampling detector tubes, recommends occupational exposure limits for various substances and assists OSHA and MSHA Jn occu- pational safety and health investigations and research. NOx Oxides of nitrogen; undesirable air pollutants. NOx emissions are regulated by EPA under the Clean Air Act. Olfactory Relating to the sense of smell. The olfactory organ in the nasal cavity is the sensing element that detects odors and transmits information to the brain through the olfactory nerves. Oral Used in or taken into the body through the mouth. Oral Toxicity Adverse effects resulting from taking a substance into the body via the mouth. Ordinarily used to denote effects in experimental animals. OSHA Occupational Safezy and Health Administration of the U. $. Department of Labor; Federal agency with safety and health regulatory and enforcement authori- ties for most U. S, industry and business. Also see "MSHA". Oxidation In a literal sense, oxidation is a reaction in which a substance combines with oxygen provided by an oxidizer or oxidizing agent (see definitions below). [na broader sense, based on modern atomic theory, science today defines oxidation as a reaction - brought about by an oxidizing agent - in which atoms, molecules or ions lose electrons. [n this broader sense, an oxidation reaction may occur even when oxygen is not present. However it may be defined, an oxidation reaction is always accompanied by an offsetting (balancing) reduction reaction in which (I) oxygen is removed from a com- pound, or (2) atoms, molecules, or ions gain electrons. Oxidizer DOT defines an oxidizer or oxidizing material as a sub- stance which yields oxygen readily to stimulate the Page -13- COMMON MSDS TERMS combustion (oxidation) of organic matter. Chlorate (C103), permanganate (MnOo), and nitrate (NO3) com- pounds are examples of oxidizers; note that all contain oxygen (O). Oxidizing Agent A chemical or substance which brings about an oxi- dation reaction. The agent may (1) provide the oxygen to the substance being oxidized (in which case the agent has to be oxygen, or contain oxygen), or (2) it may receive electrons being transferred from the substance undergoing oxidation (chlorine is a good oxi- dizing agent for electron-transfer purposes, even though it contains no oxygen). P PEL Permissible exposure limit; an exposure limit established by OSHA regulatory authority. May be a time- weighted average (TWA) limit or a maximum concentration exposure limit. Also see "Skin". % Volatile Percent volatile by volume; the percentage of a liquid or solid (by volume) that will evaporate at an ambient temperature of 70°F (unless some other temperature is stated). Examples: butane, gasoline, and paint thinner (mineral spirits) are 100% volatile; their individual eva- poration rates vary, but over a period of time each will evaporate completely. PMCC Pensky-Martens Closed Cup; a flash point test method. Poison, Class A A DOT term for extremely dangerous poisons, that is, 15oisonous gases or liquids of such nature that a very small amount of the gas, or vapor of the liquid, mixed with air is dangerous to life. Some examples: phosgene, cyanogen, hydrocyanic acid, nitrogen peroxide. Poison, Class B A DOT term for liquid, solid, paste, or semi-solid substances - other than Class A poisons or irritating materials which are known (or presumed on the basis of animal tests) to be so toxic to man as to afford a hazard to health during transportation. Polymerization A chemical reaction in ~vhich one or more small molecu- les combine to form larger molecules. A hazardous Page -1~- COMMON MS DeTER MS polymerization is such a reaction which takes place at a rate which releases large amounts of energy, if hazardous po[ymeri'zation can occur with a given material, the MSD5 usually will list conditions which could start the reaction;and since the material usually contains a polymerization inhibitor, the expected time period before the inhibitor is used up. ppm Parts per million; a unit for measuring the con- centration of a gas or vapor in air - parts (by volume) of the gas or vapor in a million par.ts of air. · Also used to indicate the concentration of a particular substance in a liquid or solid. ppb Parts per billion; a unit for measuring the concentration of a gas or vapor in air parts (by volume) of th,.; gas or vapor in a billion parts of air. Usually used to express measurements o[ extremely low concentrations of unusually toxic gases or vapors. Also used to ind;- cate the concentration of a particular substance in a liquid or solid. psi Pounds per square inch; for MSDS purposes, a unit for. measuring the pressure' a material exerts on the walls- of a confining vessel or enclosure. For technical accuracy, pressure must be expressed as psig (pounds per square inch gauge) or psia (pounds per square inch absolute; that is, gauge pressure plus sea level atmospheric pressure, of psig plus about 1~,.7 pounds per square inch). Also see "mmHg". Reaction A chemical transformation or change; the interaction of two or more substances to [orm new substances. Reactivity A description o~ the tendency o~ a substance to undergo chemical reaction with the release of energy. Undesirable e:[:[ects - such as pressure buildup, tem- perature increase, formation of noxious, toxic, or corrosive by-products - may occur because o~ the reac- tivity of a substance to heating, burning, direct contact ~,ith other materials or other conditions in use or in storage. A solid waste which exhibits a "characteristic -of reactivity", as defined by RCRA, may be reguiated (by EPA) as a hazardous waste. Page -15- COMMON MSDS TERMS Reducing agent In a reduction reaction (which always occurs simul- taneously with an oxidation reaction) the reducing a§ent is the chemical or substance which (l} combines with oxy§eh or (2) loses electrons to the reaction. See "oxidation". Respiratory system The breathing system; includes the lungs and air p~ssages (trachea or "windpipe", larynx, mouth, and nose) to the air outside the body~ plus the associated nervous and circulatory supply. RCRA Resource Conservation and Recovery Act; Federal environmental legislation, administered by EPA, aimed at controlling the generation, treating, storage, transportation, and disposal of hazardous wastes. S Sensitizer A substance which on first exposure causes little or no reaction in man or test animals, but which on repeated exposure may cause a marked response not necessarily limited to the contact site. Skin sensitization is the most common form of sensitization in the industrial setting, although respiratory sensitization to a few che- micals is also known to occur. SETA Setaflash Closed Tester; a flash point test method. "Skin" A notation, sometimes used with ?EL of TLV exposure data; indicates that the stated substance may be absorbed by the skin, mucous membranes, and eyes -either airborne or by direct contact - and that this additional exposure must be considered part of the total exposure to avoid exceeding the PEL or TLV for that · substance. Skin Sensitizer See "Sensitizer". 5kin Toxicity See "Dermal Toxicity". Solubility in water A term expressing the percentage of a material (by weight) that will dissolve in water at ambient tem- perature. .Solubility information can be useful in determining spill cleanup methods and fire-extinguishing agents and methods for a material. Terms used to express solubility are: Page -16- COMMON MSDS toll-free telephone number (1-g00-~2~-~302) which must be called when significant oil or chemical spills or other' environmentally related accidents occur. NBUAC, or n-BuAc Normal butyl acetate. See "evaporation rate". NFPA National Fire Protection Association; an international voluntary membership organization to promote/improve fire protection and prevention and establish safeguards against loss of life and property by fire. 5est known on the industrial scene for the National Fire Codes - 16 volumes of codes, standards, recommended practices, and manuals developed (and periodically updated) by NFPA technical committees. Among these is NFPA 70~,M, the code for showing hazards of materials using the familiar diamond-shaped label or placard ~vith appropriate numbers or symbols. The brief explanation below illustrates the NFPA principle of using scales of 0 to ~ (logy to high) to classify material hazards: Page ~11- COMMON MSDS TERMS Fire Hazard (Red) 0- Will not burn I - Will ignite if preheated 2 - Will ignite if moderately heated 3 - Will ignite at most ambient conditions '4 - Burns readily at ambient conditions Health Hazard (Blue) Reactivity (Yellow) 0 - Ordinary combustible 0 - Stable and not hazards in a [ire reactive with water [ - Slightly hazardous I -Unstab[e ii heated 2 - Hazardous 2 - Violent chemical change ,' 3 - Extreme danger } - Shock and heat may ) detonate ¢ - Deadly ~ - May detonate Specific Hazard OXY Oxidizer 'ACID Acid ALKALI Alkali COR Corrosive -W- Use No Water Radiation Hazard Page -12- [ COMMON MSDS Formula The conventional scientific designation for a material (~vater is H20, sulfuric acid is H2504, sulfur dioxide is 502, etc.). G General exhaust A system for exhausting air containing contamin ants from a general ~vork area. Also see "local exhaust". g Graml a metric unit of weight. One ounce U.S. (avoirdupois) is about 25./~ grams. g/kg Grams per kiIogram~ an expression of dose used in oral and dermal toxicology testing to indicate the grams o~ substance dosed per kilogram of animal body weight. Also see "kg" (kilogram). ,~... Hazardous Material In a broad sense, a hazardous material is any substance or mixture of substances having properties capable of producing adverse effects on the health or sa£ety of a human being. In 197! the Occupational Safety and Health Administration (OSHA) adopted the following definition in regulations affecting employers in opera- tions subject to the Federal Longshoremen's and Harbor Workers' Compensation Act.' "The term hazardous material means a materiaJ ~vhich has one of more of the following characteristics: has a flashpoint be!ow !~0°F., closed cup, or is subject to spontaneous heating~ 2. has a threshold limit value belosv 500 ppm for gases and vapors, below 500 MG/m3 for fumes, and belosv 25 mppcf for dusts~ a single dose oral LDO0 belo~v 500 mg/kg~ 4. is subject to polymerization ~ith the release of lar§e amounts of energy~ is a strong oxiding or reducing agent~ Page -7- COMMON MSDS TFRI~S 6. causes first degree burns to skin in short time exposure, or is systemically toxic by skin Contact, or 7. in the course of normal operations, may produce dusts, gases, fumes, vapors, mists, or smokes which have one or more of the above characteristics". Ignitable Capable of being set afire. Incompatible .Materials which could cause dangerous reactions from direct contact with one another are described as incompatible. Ingestion The taking in of a substance through the mouth. InhaJation The breathing in of a substance in the form of a gas, vapor, fume, mist, or dust. Inhibitor A chemical which is added to another substance to pre- vent an unwanted chemical change :from occurring. Irritant A substance which, by contact in sufficient concentration for a sufficient period of time, wil! cause an infIam- matory response or reaction of the eye, skin, or respiratory system. The contact may be a single expo- sure or multiple exposures. Some primary irritants: chromic acid, nitric acid, sodium hydroxide, calcium chloride, amines, meta!lic salts, chlorinated hydrocar- bons, ketones, alcohols. Irritating An irritating material, as defined by DOT, is a liquid or solid substance which, upon contact with fire or when exposed to air, gives off dangerous or intensely irri- tating fumes (not including poisonous materials; see Poison, Class A and Poison, Class B). kg Kilogram; a paetric unit of weight, about 2.2 U. S. pounds. Also see "g/kg", "g", and "rog". Page -g- COMMON MSD~ERM$ L Liter; a metric unit of capacity. A U. S. quart is about 9/10 of a liter. LC Lethal concentration; a concentration of a substance being tested which will kill a test animal. LC.~0 Lethal concentration 50; the concentration of a material in air which, on the basis of laboratory tests, is expected to kill .50% of a group of test animals when administered as a single exposure (usually I or 4 hours). The LCs0 is expressed as parts of material per million parts of air, by volume (ppm) for gases and vapors, or as micrograms of material per liter of air (ug/L) or milligrams of material per cubic meter of air (mg/m3) for dusts and mists, as well as for gases and vapors. LD Lethal dose; a concentration of a substance being tested which will kill a test animal. LDs0 Lethal dose 50; a single dose of a material which on the basis of laboratory tests is expected to kill 50% of a group of test animals. The LD~0 dose is usually expressed as milligrams or grams of material per kilogram of animal body weight (rog/kg or g/kg). LEL, or LI=L Lower explosive limit or lower flammable limit ol a vapor or gas~ the lowest concentration (lowest percen- tage of the substance in air) that will produce a flash of :~ire when an ignition source (heat, arc, or flame) is present. At concentrations lower than the LEL, the mixture is too "lean" to burn. Also see "UEL". Local exhaust A system for capturing and exhausting contaminants from the air at the point where the contaminants are produced (welding, grinding, sanding, other processes or operations). Also see "general exhaust". M m3 Cubic meter, or stere; a metric measure of volume, about 35.3 cubic feet or 1.3 cubic yards. Melting point '~'he temperature at which a solid substance changes to a liquid state. For mixtures, the melting range may be given. Page -9- COMMON MSDS TERMS Mechanical exhaust A powered device, such as a motor-driven fan or air/stream venturi tube, for exhausting contaminants from a workplace, vessel, or enclosure. mg Milligram; a metric unit of weight. There are l,O00 milligrams in one gram (g) of a substance. mg/kg Milligrams per kilogram; an expression of toxicological dose. See "g/kg". mg/m3 Milligrams per cubic meter; a unit for measuring con- centrations of dusts, gases, or mists in air. mL Milliliter; a metric unit of capacity, equal in voiume to one cubic centimeter (cc), or about i/16 of a cubic inch. There are 1,000 milliliters in one liter (L). mmHg Millimeters (mm) of mercury (Hg); a unit of measure- ment for low pressures or partial vacuums. mppcf Million particles per cubic foot; a unit for measuring particles of a substance suspended in air. Exposure limits for mineral dusts (silica, graphite, Portland cement, nuisance dusts, and others), formerly expressed as mppcf, are now more commonly quoted in mg/m3. MSHA The ,Mining Safety and Health Administration of the U. S. Department of the Interior; Federal agency with safety and health regulatory and enforcement authori- ties for the mining industry. Also see "OSHA". Mutagen A substance or agent capable of altering the genetic material in a Living cell. NaOH Sodium hydroxide, or caustic soda. N2 Nitrogen; a colorless, odorless, and tasteless gas that will not burn and will not support combustion. The earth's atmosphere (air) is about 7g% nitrogen; at higher concentrations, nitrogen can displace oxygen and become a lethal asphyxiant. See "Asphyxiant". NRC National Res~)onse Center; a notification center in the Coast Guard Building in Washington, DC, U.S., with a COMMON MSD~TERMS - Dermal Used on or applied to the skin. Dermal Toxicity Adverse effects resulting from skin exposure to a substance. Ordinarily used to denote effects in experimental animals. DHHS U. S. Department of Health and Human Services; created in 19g0 to replace the Department of Health, Education, and Welfare (DHEW) a.s "parent" for NIOSH, Public Health Service, and other agencies related to health and safety. DOL U.S. Department of Labor; includes the Occupational Safety and Health Administration (OSHA). DOT U. S. Department of Transportation; regulates transportation of chemicals and other substances, to aid in the protection of the public as well as fire, law enforcement, and other emergency response personnel, particularly when transportation incidents occur involving hazardous materials. Detailed DOT classifi- cation lists specify appropriate warnings - such as Oxidizing Agent or Flammable Liquid - which must be - used'for various substances. E EPA U. $. Environmental Protection Agency; Federal agency with environmental protection regulatory and enfor- cement authority. Administers Clean Air Act, Clean Water Act, FIFRA, RCRA, TSCA, other Federal environmental laws. Epidemiology The science which deals with the study of disease in a general population. Determination of the incidence (rate of occurrence) and distribution of a particular disease (as by age, sex, or occupation) may provide information about the causes of the disease. Evaporation Rate The rate at which a particular material will vaporize (evaporate) when compared to the rate of vaporization of a known material. The evaporation rate can be useful in evaluating the health and fire hazards of a material. The known material is usually normal butyl 'acetate (NBUAC or n-BuAc), with a vaporization rate designated as 1.0. Vaporization rates of other solvents - or materials are then classified as: Page -5- COMMON MSDS TERMS FAST evaporating if greater then 3.0. Examples: Methyl Ethyl Ketone (MEK) = 3.8, Acetone : .5.6, Hexane : 8.3. MEDIUM evaporating if 0.8 to 3.0. Examples: 190 proof (95%) Ethyl Alcohol = l.~, VM&P Naphtha : I.#, MIBK : 1.6. SLOW evaporating ii less than 0.g. Examples: Xy-lene : 0.6, Isobutyl Alcohol = 0.6, Normal Butyl Alcohol = 0.4, Water = 0.3, Mineral Spirits = 0.1. FDA The U. 5. Food and Drug Administration; under the provisions o£ the Federal Food, Drug and Cosmetic Act, the FDA establishes requirements for the labeling of foods and drugs to protect consumers from misbranded, unwholesome, ineffective, and hazardous products. FDA also regulates materials for fo~d contact service and the conditions under which such materials are approved. FIFRA Federal Insecticide, Fungicide, and Rodenticide Act; regulations administered by EPA under this Act require that certain useful poisons, such as chemical pesticides, sold to the public contain labels that carry health hazard warnings to protect users. Flash Point The temperature at which a liquid will give off enough flammable vapor to ignite. There are several flash point test methods, and flash points may vary for the same material depending on the method used, so the test method is indicated when the flash point is given (.{50° PMCC, 200° TCC, etc.). Flammable A "flammable liquid" is defined by NFPA and DOT ~ a liquid with a flash point below 100°F (37.8°C). Solids which will ignite readily or are liable to cause fires under ordinary conditions oi transportation through friction or retained heat from manufacturing or pro- cessing, and which burn so vigorously and persistently as to create a serious transportation hazard, are classified by .DOT as "flammable solids". Also see "combustible". Page COMMON MS D~I'ERM$ "C", or Ceiling The maximum allowable human exposure limit for an airborne substance; not to be exceeded even momen- tarily. Also see "PEL" and "TLV". CAA Clean Air Actl Federal law enacted to regulate/reduce air pollution. Administered by EPA. Carcinogen A substance or agent capable of causing or producing cancer in mammals. C.A.$. 'Chemical Abstracts Service; A Columbus, Ohio. organi- zation which indexes information published in "Chemical Abstracts" by the American Chemical Society and pro- vides index guides by which information about particular substances may be located in the "Abstracts" when needed. "C.A.S. Numbers" identify specific chemicals. cc Cubic centimeter; a volume measurement in the metric system, equal in capacity to one milliliter (mi). One quart is about 946 cubic centimeters. Chemical Family A group of single elements or compounds with a com- mon general name. Example: acetone~ methyl ethyl ketone (MEK), and methyl isobutyl ketone ('MISK) are of the "ketone" familyl acrolein, fur~[ural, and acetaldehyde are of the "aldehyde" ;~amily. CHEMTREC Chemical Transportation Emergency Center; a national center established by the Chemical Manufacturers Association (CMA) in Washington, DC in 1970, to relay pertinent emergency information con- cerning specific chemicals on request. CHEMTREC has a 2g-hour toll free telephone number (800-;2~-9300), intended primarily for use by those who respond to chemical transportation emergencies. Chronic Efle<:t An adverse effect on a human or animal body, with symptoms which develop slowly over a long period of time or which recur frequently. Also see "acute". Chronic Toxicity Adverse (chronic) effects resulting :~rom repeated doses of or exposures to a substance over a relatively pro- longed period of time. Ordinarily used to denote effects in experimental animals. C WA Clean Water Act; Federal law enacted to regulate/reduce water pollution. Administered by EPA. CO ~arbon monoxide, a 'colorless, odorless, flammable and very toxic gas produced by the incomplete combustion Page -3- CO~I~MMON MSDS TERMS of carbon; also a by-product of many chemical pro- cesses. CO2 Carbon dioxide - a heavy, colorless gas, produced by the combustion and decomposition of organic substan- ces and as a by-product of many chemical processes. CO2 will not burn and is relatively non-toxic (although high concentrations, especially in confined spaces, can create hazardous oxygen-deficient environments). COC Cleveland Open Cup; a flash point test method. Combustible A term used by NFPA, DOT, and others to classify cer- tain liquids that will burn, on the basis o£ flash points. Both NFPA and DOT generally define "combustible liquids" as having a flash point of 100°F (37.~°C) or higher. Also, see "flammable". Non-liquid substances such as wood and paper are classified as "ordinary combustibles by NFPA. Concentration The relative amount of a substance when combined or mixed with other substances. Examples: 2 [}pm hydro- gen sulfide in air, or a 50 per cent caustic solution. Corrosive As defined by DOT, a corrosive material is a liquid or solid that causes visible destruction or irreversible alterations in human skin tissue at the site of contact or - in the case of leakage from its packaging a liquid that has a severe corrosion rate on steel. solid or liquid waste which exhibits a "characteristic corrosivity", a_s defined by RCRA, may be regulated (by EPA) as a hazardous waste. CPSC Consumer Products Safety Commission; Federal agency with responsibility for regulating hazardous mater]als when they appear in consumer goods. For CPSC put- poses, hazards are defined in the Hazardous Substances Act and the Poison Prevention Packaging Act of ]970. Cutaneous Toxicity See "Derma] Toxicity". Decomposition Breakdown of a material or substance (by heat, chemical reaction, electrolysis, deqay, or other processes) into parts or elements or simpler compounds. Page -~' .. GLOSSARY OF COMMON MSDS TERMS · A Absolute A chemical substance that is not mixed; pure. An example is. Absolute Alcohol - which is ethyl alcohol containing not more than one percent by weight of water, Acute Effect An adverse effect on a human or animal body, with severe symptoms developing rapidly and coming quickly to a crisis. Also see "chronic". Acute Toxicity The adverse (acute) effects resulting from asingle dose of or exposure to a substance. Ordinarily used to denote effects in experimental animals. ACGIH American Conference of Governmental Industrial Hygienists; an organization of professional personnel in governmental agencies or educational institutions engaged in occupational safety and health programs. ACGIH develops and publishes recommended occupational exposure limits (see TLV) for hundreds of chemical substances and physical agents. ANSI American National Standards Institute; a privately funded, voluntary membership organization that iden- tifies industrial and public needs for national concensus standards and coordinates development of such stan- dards. Many ANSI standards relate to safe design/ performance of equipment - such as safety shoes, eyeglasses, smoke detectors, fire pumps, household appliances - and safe practices or procedures - such as noise measurement, testing of fire extinguishers and flame arrestors, industrial lighting practices, use of abrasive wheels. API American Petroleum Institute; voluntary membership organization of the petroleum industry. Among its ser- vices, API assists member committees in developing - by the concensus process - and publishing recommended practices for drilling .and well servicing, storage tank installation, tank cleaning, piping and fittings, other industry-related design, installation and operating practices; also funds and publishes basic reference books and manuals (example: "Industrial Hygiene Monitoring Manual for Petroleum Refineries and Selected Petrochemical Operations"). Asphyxiant A vapor or gas which can cause unconsciousness or d~ath by suffocation (lack of oxygen). Most simple asphyxiants are harmful to the body only when they Page -1- COMMON MSD$ TERM$ become so concentrated that they reduce oxygen in the air (normally about 21%) to dangerous levels (18% or lower). Asphyxiation is one o~ the principal potential hazards o;[ ~vorking in conjoined spaces. ASTM American Society ~or Testing and Materials; voluntary membership organization with members from broad spectrum of individuals, agencies, and industries con- cerned with materials. The world's largest source of voluntary concensus standards for materials, products, systems and services, ASTM is a resource J~or sampling and testing methods, health and safety aspects materials, safe performance guidelines, effects of phy- sical and biological agents and chemicals. Boiling Point The temperature at which a liquid changes to a vapor state, at a given pressure; usually expressed in degrees . Fahrenheit at sea level pressure (760mmHg, or one atmosphere). For mixtures, the initial boiling point or " the boiling range may be given. Flammable materials with low boiling points generally present special fire hazards. Some approximate boiling points: Propane -~°F Anhydrous Ammonia -2g°F Butane 31°F Gasoline 100°F AIIyI Chloride lI3°F Ethylene Glycol 357°F BOM~ or BuMines Bureau of Mines of the U. S. Department of Interior. BuMines began approving air breathing apparatus in "1918~ later added ali types of respirators. BOM's respirator testing/approval activities have been discontinued; NIOSH now has this responsibility. BOM-approved Type I~F gas masks are still acceptable; alt other BOM approvals have expired or been replaced by NIOSH approvals. Page -2- SPILL RE~ Prevention Know the substance youwork with, what their risks are, and how to handle them in a way that minimizes those risks. Use and maintain complete and accurate labels, Material Safety Data Sheets and all other required paperwork because these documents tell you and everyone else who comes in contact with a hazardous substance what is is, how to handle it and how to avoid trouble. Know in advance what protective equipment to use for each type of chemical in your area. Know how to use it before you have an emergency. Prepardness Follow the attached internal and external reporting charts and get the experts there fast. Keep things from getting worse before the experts arrive. Protect workers and others in the area. Spill Containment Stop the source of the leak by closing valves, pumps, etc. Cover drains or other possible escape routes. Patch the holes with patch kits, valve pluggers or whatever is appropiate. Contain spill. This method will depend on the chemical spilled. Use absorbent material to soak up the spill or neutralize the material at the exit point. If you have to use protective equipment in an emergency make sure you decontaminate it thoroughly when you remove it. You do not want to care- lessly contaminate yourself or any other uncontaminated person or area. ~cF~REANY~NE;HAN~LE~AN¥~CHEHICAL;~NE;SH~LD~C~NS~LT~:THE:MATERIA~;$AFET¥;DATA~$HEET~FIRST The Material Safety Data Sheet contains information relative to any hazardous ingredients that may be present, the name of the product, what it looks like, how to handle it safely and several other sections. SECTION I 'product'Identification This section gives the product name and brief description° SECTION II '.HaZardous.'Inqredients This section provides hazard data on any potentially harmful components of the product° SECTION III 'PhySiCal'Data This section provides specific properties of the compound. SECTION IVFire~and,'Explosive'Data. This section provides information related to fire-fighting in chemical areas. SECTION V Reactive.'Hazards. This section describes specific conditions to avoid regarding storage and mixing of chemicals due to potential hazards. SECTION VI - Health Hazards This section gives potential health hazards related to the use of the chemical and first-aid procedures. SECTION VII' 'Normal'Handling ProcedUres. This section describes the proper procedure for the safe handling and storage of the chemical. SECTION'VIII ' Spill.'or'Leak,'controt'procedures This section gives the proper steps to be followed in the event of spills as well as for normal waste disposal° Busch Industr Products Corp'6ration AQUA AMMONIA SPILL ACTION PLAN See attached-M:S~D;S~ sheet for information on: a. General information b. Chemical and physica.1 data c. Potential hazards d. Protective clothing and equipment e. First aid f. Fire response g. Spill response h. Air spill i. Land spill j. Water spill Sh~Suld a major ammonia leak happen: 1. Shut-down boiler-wear protective gear as required. 2. Evacuate any area down wind of leak. 3. Notify people as shown on attached reporting chart. '4. If anyone is injured;' call paramedics. 5. Keep all personnel out of affected area. Note: Any spill of one hundred pounds or greater, must be reported to the National Response Center. Due to the dilution of our ammonia, it would take a ~45 pound spill to equal 100 pounds of ammonia. 5455 District Si,,d. Sakersfield. CA, an~-~'~ (805) 834-1050 ~~!. Busch Indl~-~riai Inter-Office , Correspondence "FIRE'ACTION'PLAN When the fire alarm system is activated by either smoke or heat signal is sent to Crime Control this will activate a local alarm. Crime Control will then dispatch the Fire Department. Once the alarm sounds it becomes the responsibility of all super- visors to check their respective departments for fire location. Then announce the fire location over the Public Address System (Telephone Address System) and determine if evacuation of the Plant is necessary, they'Will~'sound the evacuation horn° Busch Industrial Products personnel will attempt to fight fires of a small nature only (trash cans, rags, etc,)° Attached is a drawing showing the Plant divided into four (4) sections, with arrows showing the primary escape routes for that section. 1o Section i - Main Front Door 2o Section 2 - Rear Entrance to Plant 3o Section 3 - South Side Door under stairwell · .,'~ 4° Section 4 - South Side Door Should evacuation be necessary all personnel should exit through the respective exit assigned to eaCh section of the plant° All personnel will assemble on the grass, next to the main entrance on Armstrong Street and report to their immediate supervisor. Each supervisor will be responsible for assuring that their personnel evacuate the building and account for their personnel after the evacuation and report to the plant manager° Should an evacuation be necessary the following are some basic rules to be observed: 1. Leave your work station immediately 20 Leave all personal belongings (time is of the essence) 3.. Walk do not run to exits 4o If the area is covered with dense smoke get'down on your hands and knees and crawl to the exit 5°. Stay in the assembly area until you are told to leave by authorized personnel (Management, Fire Department, Police, etc.) 6o Do not re-enter the building until authorized personnel tell you it is safe to enter (Management, Fire Department and Police, etCo) "Inter-Office Busch Industrial Correspondence I,..NQUIRY" (MEDICAL EMERGENCY) Should an injury occur at Busch Industrial Product Corporation the following steps should be observed by all personnel: 1. Prevent loss of blood 2o Maintain breathing 3o Prevent individual from further injury 4° Prevent shock 5o Notify your immediate supervisor Supervisor will be responsible for the transport of injured individuals to a medical facility° ma Busch Industrial Products Corporation ONE OF THE ANHEUSER-BUSCH COMPANIES ASBESTOSACTION PLAN We have two (2) know sources of asbestos in the plant. 1. Asbestos cement panels on the cooling tower. 2. Some older pipe insulation. The asbestos content in the tower panels is a known problem. The pipe insulation is a unknown. We cannot tell if the pipe insulation contains asbestos fibers without sending it to a laboratory for anal- ysis. 'PROCEDURES Tower Panels: These asbestos panels will not cause a problem as long as panels are in tact. The asbestos fiber are contained within the panel. The problem comes about when you drill, saw, file or grind these panels. This action releases the asbestos fibers into the air. To eliminiate any potential problem there will be no drilling, s~wing, filing, grinding or any other action to the'~e panels that might cause the release of fibers. If a situation arises where a.hole must be out into a existing panel we will remove the complete panel and replace it with a P.V.C. panel. We can then drill or saw panel as required. P.V.C. panels are available fromMorley Cooling Tower Company. PIPE INSULATION Since'we~can not detect asbestos in the insulation we must assume it does have asbestos until proven otherwise. This asbestos is not a problem until it is exposed or disturbed. As long as it is covered it is okay. If a situation develops where you must disturb the insulation to re- pair a pipe or make a tie in the following procedure is to be followed: 5455 District Blvd. Bakersfield, CA 93313 (805) 834-1050 Page 2 1. Put on goggles and a respirator. 2. Remove a small amount of the insulation and seal in a sample bottle, or a baggie will do. 3. Send sample to a laboratory for analysis. You can use: Microanalytical Service Incorporated 25 North Lake Avenue Pasadena, California 91101 Telephone Number 818 405-2929 4. If report comes back negative you can proceed with removing that section of insulation to perform the job. 5. If report comes back positive you can not proceed until insula- tion has been removed by a authorized, licensed and state certified contractor. Do not attempt insulation removal with in-house personnel. You can use: A.P,C. Contractors Incorporated P.O. Box 12501 Fresno, California 93778 Telephone Number 209 441-7971 or Waste Control Service P.O.. Box 80101 Bakersfield, California 93308 Telephone Number 805 399-4620 6. Arrangements for proper disposal of asbestos will be required also. The authorized contractor can make the proper arrange- ments for disposal. A hazardous waste manifiest is required. Disposal of cement tiles from tower is regulated also and must be dis- posed of as a hazardous waste. Set defective panels on a pallet and set in some out-of-the-way spot. Wrap panels in plastic and mark "ASBESTOS". Call a hazardous waste disposal company and they will provide a drum and packaging material. They will also label drum. Fill-out the hazardous waste manifest for disposal. Plant Engineer ma FLOOD CHECKLIST Item Action Needed Responsible Date Storm Warning Post Process~Eng. Prestorm Catch Basin Inspection, Clean Ferguson, Perkins Flashlight Batteries Check Process Eng. Outdoor Eqmt Covers Check, Inform Supervisors Process Eng. Roof Drains Inspect, Clean Coronado, Perkins Power Panels, other Inspect, Close Coronado, Electrical Dangers Inform Supervisors Perkins Doors Check, Close Perkins, Coronado Molasses Pit Covers Check, Bolt Down Ferguson, Inform Drivers Coronado Catch Basin Screens Clean Process Op. Workers Fuel Pit Inspect Process Eng. Backflowed Drains Inspect, note Process Op. Roof Leaks Inspect, note Proces Op. Blower Filters Inspect, Poss. Replc. Plant Engineer Wind-driven rain can soak the outside blower screens causing them to collapse. The blowers coul~ shut down in this situation. During a storm, the process operators s~ould monitor the air flow and watch for any sudden drops in air flow which would indicate an intake.problem. If the filters collapse the plant engineer should be contacted immediately. After a thunderstorm, the blower filters should be inspected for damage. If soaked, they should be replaced immediately since they will shrink away from their frames thereby allowing unimpeded air flow to the Blowers. Dirk J. Willard Process Engineer Attachments: 1. Checklist 2. Drainage (Plant) 3. Drainage (SE Area) CC: Michael Hillberry Connie Spaulding Richard Hughes Michael McCoy Jerry Freeman Debra Tesch Dirk Willard Ronald Coronado Bill Ferguson Doug Perkins Carl Walker File Busch Industrial.- Ce Products Corporation Correspondence ONE OF THE ANHEUSER'~USCH COMPANIES October 12, 1987 TO: All Plant Employees FROM: Dirk Willard RE: Flood Action Plan Attached are drawings showing storm drainage at the Bakersfield yeast plant. Also attached is a checklist for the emergency response team. In the event of a severe thunderstorm, or flood, there are thirteen items that employees should be concerned about: (1) the sump pumps; (2) the catch basin screens; (3) covers for equipment; (4) a power failure due to lightning, or windstorm; (5) roof leaks; (6) sump overflow; (7) personal safety; (8) the roof drains; (9) the fuel oil pit; (10) water collection behind the molasses tanks; (11) the windstorm preceeding the thunderstorm; (12) the blower screens; (13) and the molasses unloading pit covers. The sump pumps have a limited capacity which means that they can be overwhelmed in a severe thunderstorm. When this occurs, the process area and unloading area catch basins will overflow and there is a real danger that the cooling tower water will be contaminated. Additionally, the overflowing water may short out the junction boxes around the north tower sump; they are only a few inches off the ground. Unless the molasses unloading pit covers are bolted down tight, backed up water can pour into the pit. Also, sewage can back up in the indoor drains causing flooding and a contamination problem inside. To avoid, or, at least, to ameliorate overflowing the following steps should be taken during a rain storm: (1) the process operator should monitor the sump pumps at least every hour; (2) the use of water should be reduced to cut back the pump load; (3) equipment near indoor drains should be moved; (4) major loads, such as dumping a fermenter, which can be delayed, should be until a time when the sump level has returned to normal, below 60%. Even with the process shut down, "SUMLEV" will read about 20-30%. A.process operator, or, a packaging worker should clean the screens every hour during a thunderstorm provided that the lightning is at least five miles away. Any boyscout can determine the distance of lightning by counting the seconds between sighting the bolt, and hearing the thunder. The number of seconds represents the approximate distance in miles. When the storm has subsided, the next shift operator should spray down the concrete around the catch basins, and clean the screens. If the sump pumps were overwhelmed, he should sanitize the process area and any areas indoors where backflowing has occurred. He should also inspect the boiler room, instrumentation room, and packaging room for drain backflowing. The process engineer, or, the safety coordinator, if the former is absent, should monitor the daily weather and notify the plant manager, his staff, and general plant personnel if thunderstorms become imminent. The engineer must also notify other members of the natural disaster emergency response team at least twelve hours in advance. He should decide specifically who is available on the team to fulfill the tasks of the checklist. To warn plant personnel a bulletin will be posted on the board. Bill Ferguson, or Doug Perkins shall be responsible for assuring that the catch basin screens are cleaned prior to a thunderstorm. This can consist of notifying the process operator, and the packaging supervisor that the screens must be cleaned. Whomever of the team notifies the operator, or, foreman shall do so in writing, by memorandum. After notification by the process engineer, it is the responsibility of each area supervisor to assure that any equipment in use outdoors either be moved indoors, or, covered properly. A proper cover should be tied down to prevent blowing away during a windstorm. It should also be waterproof, in good condition, and cover the equipment completely. Typically, a lightning storm means a power failure in Bakersfield. The duration of a failure can be anywhere from less than 1 minute to two or more hours. When a lightning storm warning has been issued operators and packaging room workers should check their flashlights. Roof leaks are a present problem which will eventually be eliminated. However, until then, power panels, and othe electrical equipment must be protected against dripping. Electrical equipment with an enclosure specification above 2 (NEMA-2 Class) is probably safe from some dripping. Ron Coronado, or, Doug Perkins is responsible for assuring that all power panels are closed, and that all electrical dangers are avoided prior to a thunderstorm. One danger could be extension cords plugged together lieing on the ground near a drain where flooding could cause a short. During an electrical storm it is tempting to go outside and watch the lightning. This is an unsafe practice which must be avoided. Also, since the roof, the tops of the fermenters, the top of the blower building, the top of the molasses tanks, and the cooling tower are high points in the flat horizon of the valley these areas are to be avoided during a thunderstorm. A number of spectacular roof collapses have occurred during Bakersfield thunderstorms. In August 1983, the roof over Mervyns collapsed because of poor drainage. To avoid this problem, and reduce leakage, the roof drains must be inspected before each storm. Ronald Coronado, and Bill Ferguson will share this responsibility. The fuel oil pit will fill in any sizeable shower. Oil contaminated water poses an environmental hazard. For this reason, tie-ins have been provided for tidy removal from the pit via an air-driven pump. Unless the pit is about to overflow this installation can be done during the next day by the shift maintenance man. If overflow is approaching, call the plant engineer. Typically, a valley thunderstorm will be preceeded by a windstorm. To prevent a serious dust problem all doors should be closed including the dock doors, the boiler room doors, and the storage room doors. Doug Perkins, and Ron Coronado are responsible for this task. ISI TE/FAC ILI T¥ AGR~ .~ ::4? WORTH SCALE: ~ffrlooiBUSINESS NAME: ~o~[ ~u,+~;~l ~,&-~s FE00R: 1 0F'L (CHECK ONE) SITE DIAGR.~[ -~ FACILIT~ DIAGR.~M DISTPlCT BLVD, · --'~TfEt~' PlT,,,/~q~F'IRE VALVE PIT ' ELECT. ~t~--k ~° = ~ ~ SUBSTATION ~ ~ ~"~'~'~ I ~ METAL 'J- ~ ~-- /'%--~- I ~ FENCE x -- ~:~ ~t~, ~ ~ --' ~ ~,~ ACCESS ~0 .... ~ PAVEMENT -" ~ ~~~~1 . F~.I Oil ; z~,~ s~li.~-~ ~,;J · (Inspector's Comments): -OFFICIA~ USS ONLY- ~i te: Roster P_~ge 1 Report: St.~.tus 10.,".5/'87 Name Ape,,,. Pno.=.ent At Home M ssing Adame, Mona Clerical Bai 1 ey., Thomas t"l.a i ntenance Bratcher, Ri chard Pro,-e.=.s 8 r o~,..~ n ~ M.C. M.~. i n t e n a n c e Cazar-es., Gilbert Process Co.ar., Charles Process Cc, ntreras, David Process Cc, r. onado~ Ron.~.ld F'acKaging Oa,Jis.~ Gene Maintenance Ense:?~ D.sr, iel ~Ranch Fr>.'~ Llc, yd Mainten.~.nce Fupge. sor~ b. Jil 1 lam F'acb(.~gi ng H i c k: s., G e o r. g e F' r. c, c e s. s. Hugh ~ s s - ~ R i ,-har. d **Ma i n tenance McCoy, t"lich~el *~Pr'c, cess Perb::ins., Ger. a. ld Pack:aging Robbins, Her. man GA L.!bc, r. ator.?' Si 1va, Jo, se F'ack:aging Smi th, Lar. py r~.uk¢.,ging Spa. ulding, C:onnie Clepica.! .... Tesch, Debr. a **QA Labor. a.(c,r.>-' Veptr. ees, Dennis F'acKaging b..lalk:ep, Ca.r. 1 *Pack.~ging L., J Js.r-d~ DJr. k; *EngJne~pJng BuSChlndustTiai . I er-OffiCe Correspondence RE: Earthquake Action Plan :'~{~t~:Att~cA~'di~s a' ~a~l~g s~o~l~g ~he assembZy a~ea 1~ a~ ea~tAquake should ~a~e~s~leld. Also a~tached lsa d~a~l~g sho~l~g the second level Z~ a~ earthquake all ?e~so~el a~e to e~l~ ~he bulZdl~g qulc~ly a~d calmly loca~lo~ ls ~he sa[es~ ~ea~by a~ea. (r:Or~:..i.~o:ot$~g~o~e~ (becauSe o~ ~he. C~lo~lne ~a~s), the A~ua/A~o~la a~d ?hospho~ic directly sou~heas~ o~ ~e coo11~g to~e~, A~mo~la ~a~, a~d ?hos~ho~lc acld ~:','-~.~i ~ a se~e~e quaAe,~· se~lous e~ough ~o cause s~uc~u~al damage ~o the building, ~eg~oupl~g 1~ ~he assembly a~ea, ~he pla~ ma~age~ ~111 mee~ ~l~h bls s~a~ } .:~?:}:~.he ,oe.~a~n:.~hat Ais declsio~ mee~s ~1~ city a~d county codes. ~he City ~la~e~s b~:: ~::.::'.~eh~ ~he. bU~Zdl~g-,'h~s .been.:evacua~ed a~d dec~a~ed u~sa~e. Guards a~e ~eeded A~ea su~e~vlso~s ~111 be ~espo~slble ~o~ assu~l~g ~ha~ ~hel~ ~e~so~el e~acua~e ~:he ~:.'~:~e~::P~ov$~e~ by ~he ?~ocess e~gi~ee~ to be ce~ta~ tha~ all pe~so~eZ a~e accou~ed ~o~? A ~oste~ is a~ached ~o~ thls ~' ~c- b~e ~p.e~o~Z belo~ a~e. ~espo~sib~e fo~ the ?a~lcula~s a~e~ a~ earthquake. a~d ~l~y ~ate~ to t~e building, ~oug ~e~l~s ~111 be ~espo~slble ~o~ assu~l~g reentered for this assessment without the expressed permission of management. The electrical power will probably be lost for a couple of days as a result of a .severe earthquake. This is~what occurred during the 1972 earthquake. If power fails, the main breakers on the second level will turn off building electricity, and everything that is not on the UPS will go down, including the boiler. For this reason, the electrical power can probably be ignored after an earthquake° If the power is still on after' evacuation, and the plant manager deems the building unsafe, the process engineer is responsible for shutting off the main b~eaker. In a'severe earthquake, an orderly process shut-down is not practical. Although the control room is constructed of 6 inch~concrete block and has a high degree of survivability, it must be evacuated immediately after the tremors have " passed; the control room is at the center of what may be a structurally unsafe building. Personnel trapped there during the earthquake should avoid the areas previously mentioned and proceed to the assembly area by the fastest route available. Personnel trapped on the roof or the east receivers should avoid the catwalk with the fiberglass grating. They should egress via the fermenter catwalk which has steel grating which is less likely to crumble during a quake. Persons trapped on the roof Should avoid' crossing directly and should instead crawl along the load supporting concrete walls to the fermenter catwalk. Dirk /.Willa Process Engineer Attachments: 1. Plant Roster 2. Plant Drawing (Level 1) 3. Plant Drawing (Level 2) CC: Michael Hillberry Connie Spaulding Richard Hughes Michael McCoy Jerry Freeman Debra Tesch Dirk Willard Ronald Coronado Bill Fergason Doug Perkins Carl Walker File