The URL can be used to link to this page

Home My WebLink AboutMITIGATION 12/18/1981 KERN COUNTY HEALTH DEPARTMENT 1700 Flower Street AIR POLLUTION CONTROL DISTRICT LEON M HEBERTSON, M.D. Bakersfield, California 93305 Director of Public Health Air Pollution Control Officer Telephone (805) 861-2231 ~ December 18, 1981 Don Blurton, Manager Champion Chemical Company P. O. Box 10376 Bakersfield, CA 93389 Dear Sir: On Monday, December 14, 1981, our on-call sanitarian received a complaint alleging that an acid mist was escaping from your facility located at Brimhall and Coffee Roads. On Wednesday, December 16, 1981, I paid a visit to your yard to ascertain if there were any material.handling problems at your facility. During this visit, I noticed that there were numerous spills of materials in your unlined yard. Such spills may be in violation of Section 25181, California Health and Safety Code. The basic intent of this law is to prevent hazardous materials from being disposed in an uncontrolled manner. The usual way we ascertain compliance with these laws in a case such as yours is through labora- tory testing of the soils. However, due to the large area covered by spills and the many compounds that could have been spilled, I feel that laboratory testing would be prohibitive. Therefore, to assess any possible soil contamination hazards, we are asking you to send material safety data sheets (USDOL Form OSHA-20) for the following proprietary compounds: 1. Surfatron DO-44, DO-49, and DN-71 2. Gyptron T-50 and WTC 30 3. Formatron ¥-12 4. Drilltron B-143 5. Cleartron ZB-81 6. Emulsotron X-241 7. Cotrun R-2211, RN-106 8. DTRON SC-14, B-1588 9. Scortron GR-47 10. T-55 11. YR-0033 12. B-469 13. Code 495 14. T-42 15. LST-6 and LST-7 16. WR-3017 and WR-8039 Don Blurton, Manager ~ Champion Chemical Company Page Two December 18, 1981 We also recommend that to prevent any violent chemical reactions in your yard, you remove the sodium hydroxide drum from the pallet.containing three drums of formic acid. Thank you for your.~0operation in ~his matter. Very-truly yours, ~i~ ..... · Leon M Hebertson, M.D.. Health Officer Vernon S. Reichard, Director Environmental Health Division Robert D. Cook, Sanitarian Solid Waste Section RDC:jp Division of Environmental Health Location City Tenant Address RESULTS OF ' ' IN V ESTIG A T lO N ...._..~.....~..~...._~....i~(~_.~. '.~%~ c....------.~---- .-(~--. ...... ~'_.~.....~--.--.~...-~..~L .~...~)... ........ .~..~.._.~... ~ ~ ......._..~...."~"~'" ~.......-:~... ............... ...~.~.~_~.r..~ ..................................... .~ ...... ~ ..... .~__.~.....~'.~..~.~.~..~.~ ....... ..~i.,...~..~ ..... .~:~.~ ........ ~..~.~,~.~ .~ ....... -~:~ ....... ~.~..~..~;~.~.. ..~...~._~....~.~~-~ -~ ..................................... ~.~..~...~ ........... ~.~....~.~...~ ..... .~ .................. ..~..;...~ ..... ?~--~ ........................ ComDlalnant notified Information of results SuDervisor Sanitarian taken by KCHD ~/372-EH (5-70) .namp,o,_ Chemicals ,Inc. MATERIAL SAFETY DATA SHEET MANUFACTURER'~ NAME . EMERGENCY TELEPHONE NO. CHAMPION Cfl]~CA.LS, INC. 713-431-2561~ ADDRESS · : 3130 :F~ 521, ~'resno, Texas 77545 (P. O. Box 45509, Houston, Texas 77045) PRODUCT SURFATRON'DQ-44 CHEMICAL FAMILY FORMULA detergent proprietary ":'. ~:~::.i~;:::.:':::~:-~'~:~':~'::. '.~-:.',' ::-~:??;~:~:?:~i::!!~i~i~ili~iii!'~:~?i~ SECTION II - HAZARDOUS INGREDIENTS t '." TLv TLV MATEfllALS % (Units) MATERIALS % (Units) methanol 15 BOILING POINT ( F.) aqueous SPECIFIC GRAVITY (H20 - 1) 1; 00 PERCENT, VOLATILE VAPOR PRESSURE {mm Hg.) ND BY VOLUME (%) 15' VAPOR DENSITY (AIR = 1) ~TD EVAPORATION RATE ~ SOLUBILITY IN WATER soluble Viscosity (cps) @ 75°F 4.3 APPEARANCE AND ODOR ' "~.:.: ~ ::.?:;;+~:-:i.;."..:!::,::-~-:;~:;?:~:-..?.;:i:~:.:4:::fl, SECTION IV - FIRE AND EXPLOSION HAZARD DATA it " FLAS. ,'O,.T 105°~ (TCC) I FLAMMA"LE L,M,TS LEL I EXTINGUISHING MEDIA D ALCOHOL FOAM "E'] CARBON DIOXIDE ~ DRY CHEMICAL 'IE"I FOAM ~WATER SPRAY (FOG) [] OTHER SPECIAL FIRE FIGHTING PROCEDURES Water spray ~a¥ be used to cool fire-exposed metal containers to prevent re-ignition from hot surfaces. Do not breathe smoke or hot fumes. FIRE AND EXPLOSION HAZARDS None kno~m. - TRANSPORTATION DATA US DEPARTMENT OF TRANSPORTATION HAZARD CLASS COMBUSTIBLE LIQUID I-]UNREGULATED BY D.O.T. L~BEL REQUIRED f NONE, when container capacity is 110 ~allons or less. US D.O.T. PROPER SHIPPING NAME IUN NUMBER t COMBUSTIBLE LIQUID, N.O.S. NA1993 ' ': ..... '" ' : ! SECT'~3N V -- HEALTH HAZARD DATA '.' :::~. ":' THRESHOL[3 LIMIT VALUE ; None ~=~ablished for producl:. EFFECTS OF OVEREX"OSURE EVE5 Irri[a=ion, iCchins, excessive tearing. SK,"CO~ACT Irri[a=iou, redness. Sensitized skin ~y show de~a=i=is. ,N~A~T,ON Nausea, dizziness; pne~onia if aspira~e~. ,FSWAUUOWSO Naus~, voicing, and o~her s~pcoms of methanol poisoning. EMERGENCY AND FIRST AID PR~EDURB -' ' EY~ Flush ~Ch cleaa water ~ediaCely ~or 15 m~muCes and see ~ eye doctor. SKIN CONTACT ~aB~ ~ soap amd water. Remove and launder cloches be~ore ~e-w~ring. I~ skin izrtcaCton persists, see a physician. INHA~TION R~ve Co ~zesh air. Give artificial respiracton i~ needed.. IF SWALLOWED G~VE ~[k O~ water Co dilute. Induce vomic~g. GcC emergency medical crea~enc Eot meC~ol Ingestion. - .::::~?~%~::~:?~?.~??~:???~??::~::~:~:~:~.::~:.~?:~:~] SECTION VI -- REACTIVITY DATA ~'~.:~:~:?'.:/::.:: STABILITY= I UNSTAB~I I~ABLEIx I Sources of ignition ~NCOMPATABILI~ (Materials to a~) ~neral acids,., caustic, oxidizers such as chro~Ces. :4AZARDOUS DECOM~SITION PRODUC~ Smoke. f~es. carbon monoxide, carbon dioxide, oxides of nitrogen. ! ~LYMERIZATION= MAY OCCUR WILL NOT OCCUR X SECTION VII --SPILL OR LEAK PROCEDURES RESPIRATOR~ PROTECTION ~ EVA~RATE SMALL ~EUTRAEI~E ANO WASH ~EV~CUATEAH~ ~ (~PER~[CTION VIH} ~ ~MO~NT~ IN HOOD ~AWA~ WITH WATER OBSERVE GOVERNMEN- SKIN PROTECTION INCINERATE UNDER ~TAL SPILL & WATER ~STOP FLOW ~ (AS PER SECTION VIII) ~ CONTROLLED CONDITION5 QUALITY REGU~TION5 ~ ELIMINATE ALL SOURCES __ INCINERATE USING A~ER ~ REMOVE SOILED OF IGNITION~ F~MMABLES ~ A~ORB OR SCRAPE UP ~ BURNER & SCRUBBER ~CLOTHING mKEEP U~IND AND ~ AVOID INHA~TION ~ VACUUM UP ~ ~NDFILL OR ~NOFARM ~ISO~TE EXPOSURE AREA ~ AVOID DERMAL CONTACT ~ OTHER ~ SECURE CHEMICAL ~NDFILL · -'' :":"~' :J SECTION VIII --SPECIAL PROTECTION INFORMATION .... .'.: ~PI RATORY PROTECTION (~pg~ None needed in routine use. VENTI~TION LOCAL EXHAUST SPECIAL Reco~ended Entering Can~ or cleaning MECHANICAL (~g~r~J~ [~e spills; air supp17 reco~ended. 3ROTECTIVE GLOV~ I EYE PROTECTION neoprene or latex gubbe~! chemical safety goggles ~THER PROTECTIVE EQUIPMENT eyebach stations or water supply; showegs ' ""' .... ' ":"'! SECTION IX - SPECIAL PRECAUTIONS ~: ~'::~?./?'~.'~¥:~:'~ :-'::-~ )RECAUTIONS TO BE TAKEN IN HANDLING AND STORING zep away ~rom spares ~d ~cessive heat. '~oid con,act. )THER PREC~UTI ONS :~OW and be able Co use firs~ aid and fire figh~g procedures. The information contained heroin is basKI on da~a COnsidered accurate. However, no warranty, expressad or implied, Champlo . Chemicals,Inc. MATERIAL SAFETY DATA SHEET t MANUFACTURER'~ NAME EMERGENCY TELEPHONE NO. CHAMPION CH]~ICALS, INC. · ........... 713-431-2561 '" ADDRESS 3130 FM 521., Fresno, Texas 77545 (P. O. Box 45~09, Houston, Texas 77045) PRODUCT SURFATRON DQ-49 CHEMICAL FAMILY de~ergent FORMUL~k proprie£ary TLV TLV MATERIALS *. % (Units) MATERIALS % (Units) methanol 19 200 (ppm) BOILING POINT (o F.) SPECIFIC GRAVITY (H20 = 1) 0. 976 aqueous PERCENT, VOLATILE VAPOR PRESSURE {mm Hg.) ND BY VOLUME (%) 19 VAPOR DENSITY (AIR = 1) ~ EVA~RATION RATE SOLUBILI~ IN WATER soluble ViSCOS~7 (cps) ~ 7~°~ APP~RANCEANDODOR ~e11OW tO oran;e !~quid wi~h a pungent odor. .... SECTION IV - FIRE AND EXPLOSION HAZARD DATA, EXTINGUISHING MEDIA ~ ALCOHOL FOAM ~ CARBON DIOXIDE ~ DRY CHEMICAL ~ FOAM ~WATER SPRAY (FOG) ~ OTHER SPECIAL FIRE FIGHTING PROCEDURES ~ater spray may be used to cool f~re-exposed me~al con~a~ers to prevent re-i;n~t~ou from hot surfaces. ~ not breathe smoke or hot fumes. Frae A.O EXPLOSION HAZARDS None ~o~. - TRANSPORTATION DATA FLAMMABLE LIQUID I I-]UNREGULATED BY D.O.T. LABEL REQUIRED FLAHHABLE LIQUID US D.O.T. PROPER SHIPPING NAME [ UN NUMBER FLAMM~BI~E LIOUID. N.O.S. I UN1993 THRESHO.[.O LIMIT VALUE · ' None established for product. EFFECTS OF OVEREXPOSURE EVES Irritation, itching, excessive tearing. SKIN CONTACT Irritation, redness. Sensitized sk~ ~y show INHA~TION Nausea, dtzz~ess; pne~on~ t~ aspirated. ~SWA~O~O Naus~, volt,g, and other s~pC~s of methanol poisoner. EMERGENCY AND FI RST Al D PR~ENR~ ev~ Flush ~th clean water t~edlat~y for 15 m~utes and see an eye doctor. stun CONrAC~ Wash ~th soap and ~Cer. Remove and la~der cloches before re-wearing. INHA~TION If S~ irritation persists, see a physician. R~ove Co fresh air. Give artificial respiration if needed. iF SWALLOWED Give milk or water Co dilute. Induce vomiting. Get ~ergency medical tr~t~c for merino1 ~gescton. ..... 'l ........ I I ""i' I ~ STABILI~= t UNSTAaLEI I~Aa~IX J Sources of ~INCOMPATABILI~ ~U~C ~ OXidiZE~ such aB ch~o~Es. (Materla~ to Ivo~J ~ HAZARDOUS DECOM~SITION PRODUC~ Smoke, ~umes, ca~bq~ mo~oxi~e~ cagbo~ ~ioxtde~ 0x~es o~ ,ntC~o~en, POLYMERIZATION: MAY OCCUR WILL NOT OCCUR RESPIRATOR~ PROTECTION ~ EVA~RATE 5MA~ NEUTRAUZE AND W~H ~ EVACUATE ABU ~ [U PER SECTION VIII) ~ AUOUNTS IN HOOD ~ AWAY WITH WATER O~ERVE GOVERNMEN- ~ SKIN PROTECTION INCINERATE UNDER ~TAL SPILL A WATER ~STOP FLOW ~ (AS PER SECTION VIII) ~ ~ CONTROLLED CONDITIONS ~UALITY REGU~TIONS ~ELIMINATE ALL 50URCB __ INCINERATE USING A~ER __REUOVE SOILED OF IGNITION. F~MMABL~ ~ A~ORB OR SCRAPE UP ~ BURNER & SCRUBBER ~CLOTHING ~KEEP U~IND AND ~AVOID INHA~710N ~ ~ VACUUM UP ~ ~NDFILL OR ~NDFARU UISO~TE EX.SURE AREA ~AVOID DERUAL CONTA~ ~ OTHER ~ SECURE CHEUICAL ~NOFILL ~ESPlaATO~Y PROTECTION [~ None needed in routine use. VSNW~V,ON LOlL ~HAU~ S.EC~AC Reco~ended ~nCer~g ~Es or clean~g UECHANICAL (~e~r~J Large spills; air supply ;eco~ended. .~owcv,vs ~covEs gv[ .aOTECWON neipgene or lacex rubbeg chemical safety goggles ~THER "~OTSCWVE [eU,"~ENT eyeba~h s~aCions o~ water supply; showers PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep away from sparks and excessive heat ......... ........... Avoid contact ..... OT~ER "RECAUT,ONS K~OW and be able t0. u.s.e fir.st aid and fire .fighting procedures The information ccmtained heroin is basKI on data considered aCCUrate. However, no warranty, expressad or implied, " > Champione Chemicals ,Inc. MATERIAL SAFETY DATA SHEET I SECTION I I MANUFACTURER'~ NAME EMERGENCY TELEPHONE riO. CHA~ION CHEMICALS, INC. 713-431-2561 ADDRESS 3130 FM 521, Fresno, Texas 77545 (P.O. Box 45509~ Houston, Texas 77045) PRODUCT SURFATRON DN-~I CHEMICAL FAMILY detergents FORMULA proprietary ' . , , -. I SECTION II - HAZARDOUS INGREDIENTS I .... TLV TLV MATERIALS % (Units) MATERIALS % (Units) petroleum naphtha .... ¸ im ~ BOILING POINT ( F.) ~'~° '~"~--' ' SPECIFIC GRAVITY (H20 = 1) , :' ~ '- .... ND 0.95 " PERCENT, VOLATILE VAPOR PRF-S~URE (mm Hg.) [~TD BY VOL(.JME (%) ND VAPOR DENSITY (AIR = 1) ND EVAPORATION RATE ND SOLUBILITY IN WATER Highly dispersible pH NA APPEARANCE AND ODOR Dark brown liquid with an aromatic odor. I SECTION IV- FIRE AND EXPLOSION HAZARD DATA I FLASH PO,ET , 130°F (TLC) { FLAMMASLE L,M,TS I LEL I UEL EXTINGUISHING MEDIA [] ALCOHOL FOAM ~] CARBON DIOXIDE ~ DRY CHEMICAL ~] FOAM [] WATER SPRAY (FOG) [] OTHER SPECIAL FIRE FIGHTING PROCEDURES Water spray may be used to cool fire-exposed metal containers to prevent re-ignition from hot surfaces. Do not breathe smoke or hot fumes. FIRE AND EXPLOSION HAZARDS None known. - TRANSPORTATION DATA US DEPARTMENT OF TRANSPORTATION HAZARD CLASS COPHtUSTIBLE LIQUID LABEL REQUIRED NONE~ if less than 110 ~allons/container us O.O.T. PmOP~ S~,P~,~S ~ J u~ ~o~.~R CO~USTIBLE LIQUID, N.O.S. ~ NA 1993 '; ~(t PRODUCT, SURFATR~_)N-71 Pa~ 2 ~,f 2 · ! SECTION V - HEALTH HAZARD DATA L THRESHOLD LIMIT VALUE Not established EFFECTS OF OVEREXPOSURE EYES Trrltation~ excessive tearing. SKINCONTACT Irritation, redness, itching, pain. ~NHALATION Nausea, dizziness, aspiration pneumonia. IFSWALLOWED Nausea, vomiting, and other symptoms of petroleum naphtha poisoning. EMERGENCY AND FIRST AID PROCEDURES EYES Flush with clean water immediately for 15 minutes and see an eye doctor. SKiN CONTACT Wash with soap and water. Remove and launder clothes before re-wearing. INHALATION If irritation persists, see a physician. Remove to fresh air. Give artificial respiration if needed. IF SWALLOWED Give milk or water to dilute. Do not induce vomiting. Get emergency medical attention for petroleum naphtha ingestion. STABILITY: UNSTABLEI I STABLE] XI Sources of ignition INCOMPATABILITY (Materials to Mineral Acids, caustic, oxidizers such as chromates. HAZARDOUS DECOMPOSITION PRODUCTS Smoke, fumes, carbon monoxide, carbon diD×idB, sUlfur oxides. .. SEcTION.~ RESPIRAToRyVII --SPILLpRoTECTiON m0R LEAKEvAPORATEPROCEDURESsMALL I'~ EVACUATE AI~EA L~ (AS PER SECTION VIII) t_l AMOUNTS IN HOOD [] AWAY WITH WATER OBSERVE GOVERNMEN- ,.~ SKIN PROTECTION INCINERATE UNDER [~TAL SPILL & WATER [~STOP FLOW L~ (~ PER SECTION VIII) E-Ii CONTROLLED CONDITIONS QUALITY REGULATIONS [~ELIMINATE ALL SOURCES INCINERATE USING AFTER ~REMOVE SOIL[I:) OF IGNITION, FLAMMABLES [~ ABSORB OR SCRAPE UP [~ BURNER & SCRUBBER mKEEP UPWi;~ID AND ~AVOID INHALATION E] VACUUM UP [] LANDFILL OR LANOFARM UISO[.ATE EXPOSURE AREA [~ AVOID DERMAL CONTACT [-I OTHER [~ SECURE CHEMICAL LANDFILL RESPIRATORY PRO~'ECTION (SpeC/fy /~g) "' None needed in routine use. VENTiLATiON LOCAL ~XHAUST SPECIAL Recomaended. MECHANICAL "ROTECTIVE GLOVES I EYE PROTECT,ON neoprene or latex rubberI chemical safety goggies OTHER PROTECTIVE EQuIP~NT eyebath stations or water supply; showers 1 SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO eE TAKEN ~N HANaLING ANO STORING Keep a~ay ~rom sparks and excess±ve heat. Avoid contact. OTHER PRECAUTIONS Know and be able to use first aid and fire fighting procedures. U.S. DEPARTMENT OF LABO, OMB No. 44-R1387 Occupational Safety and Health Administration · ...% . /IAT[ IAL S FETY DATA S E[T Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION I MANUFAC,TUR[R'$ NAME EMERGENCY TELEPHONE NO. ~ICN ~CALS, INC. 713/431-2561 ADDRESS/Number, Street. City, State. and ZIP Code) 3130 ~5;~ 288; Fresno: Tex~s 77545 (P. O. Box 45509, Houston, Texas 77045) CHEMICAL NAME AND SYNONYMS I TRADE NAME AND SYNONYMS I DRILTRON B-143 CHEMICAL FAMILY I FORMULA ~ L~_n~n z~nc complex SECTIONII - HAZARDOUS INGREDIENTS { i TLVt I TLV PAINTS, PRESERVATIVES, & SOLVENTS % {Units) ALLOYS AND METALLIC COATINGS % {Units) PIGMENTS BASE METAL SOUV[NTS methanol 19I 200 PLUS COATING OR CORE[ FLUX ADDITIVES OTHERS ~/' OTHERS I TLr . · HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GASES % . {Units1 SECliON ill - PHYSICAL DAIA BOLLING POINT (°F.) SPECIFIC GRAVITY aqueous 210° F ,, l. ll PERCENT, VOLATILE VAPOR PRESSURE (mm Hg.) BY VGLUME (%) 19% EvAPoRATiON RATE VAPOR DENSITY (AIR=E) ( $OLUE)ILITY IN WATER soluble APPZA.~C[ A.O OOOR dark brown l±~u±a - molasses odor SECTIONIV - FIRE AND EXPLOSION HAZARD DATA FI.ASH POINT (Metno~ useO) ICC 92"C I~UAM~ASUa ~,M,TS he, I. ue, EXTINGUISHING MEDIA water foam SPECIAL FI~RE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS PAGE {1) (Continued on reverse side) Form OSHA-20 ~ Rev. May 72 ' Champio ? Chemicals,Inc. MATERIAL SAFETY DATA SHEET MANUFACTURER~ NAME EMERGENCY TELEPHONE NO. CHAM~ION CHEMICALS, I~C. i713.--431-2561._ ADDRESS 3130 FM 521, Fresno, Texas 77545 (P.O. Box 45509, Houston, Texas 77045) PRODUCT CLEARTRON ZB-81 CHEMICAL FAMILY FORMULA polyelectrolyte proprietary TLV MATERIALS % TLV MATE RIALS % (Unim) (Units) methanol 27 200 (ppm} I BOILING POINT ( F.) aqueous SPECIFIC GRAVITY ~H20 = ].) 1.05 PERCENT, VOLATILE VAPOR PRE~URE (mm Hg.) ND BY VOLUME (%) 27 VAPOR DENSITY (AIR = 1) N~ EVAPORATION RATE ND SOLUBIUTY IN WATER soluble pH 6.5 APPEA~NCE AND ODOR Light ~ber liquid with a sweet odor. ,.: :' · ~ ........ '::~:::?:::r. SECTION IV -- FIRE AND EXPLOSION HAZARD DATA . J "'~": ." ~.~,.~ 90~ (~cc) I~"~ ~'~'~ I~ I~ EXTINGUISHING MEDIA D ALCOHOL FOAM ~ CARBON DIOXIDE ~ DRY ~.[MICAL ~ FOAM ~ WATER SPRAY (FOG) ~ OTHER SPECIAL FIRE FIGHTING PROCEDURES Water spray ~y be used to cool fire-exposed metal conta~ers to prevent re-ignitiom from hot surfaces. Do not breathe smoke or hot fumes. FIRE AND EXPLOSION HAZARDS None kno~.m. -TRANSPORTATION DATA US DEPARTMENT OF TRANSPORTATION HAZARD CLASS FLAMMABLE LIQUID I F~UNREGULATED BY D.O.T. LABEL REQUIRED FLAMMABLE LIQUID US D.O.T. PROPER SHIPPING NAME 1 UN NUMBER FIJuMMABLE LIQUID, N.O.S. I UN1993 +HRES~OL0 LIMIT VALU'~ ' ~ .... None estab_.shed for product. EFFECTS OF OVEREXPOSURE EYES Irritation, itchi~§, e~cessive tear/~g. Sm~CO~ACZ Irri~aCio~, red, ess. SeasiCi~ed sk~ ~y show de~cicis. ~N~A~Z~ON Nausea, di~i~ess; p~e~ if aspi=a~ed. ~SWACCOWEO Nausea, vo~g, a~d o~heg s~o~ o~ meC~ol poison~g. ~E~aENCV ~N~ m~ Am P~OCE~U~ ~v~s ~lush ~Cb clea~ ~a~er ~edia~ely fog 15 ~uces a~d see a~ eye doc~°~. SmN CO~AC~ ~ash ~h soap a~d wa~er. ~emove aad launder cloches before re-wear~g. ~N~A~V~O~ If Sk~ irriCaLio~ persists, see a physiciaa. R~ove ~o ~resh air. Give ar~l~icial respiracio~ if needed~ ~ SWACCOWE~ Give mil~ or ~a~er ~o dilute. I~duce v~ici~g. Gec ~erge~cy medical ~rea~ea~ ~or men,sol ~ges~io~. I I ~ I ICONDITIONS TO AVOID STABILI~: UN.ABLE ~ABLE X ~OU~CES O~ t~n~ INCOMPATABILI~ (Materials lo avoid) ~=e=a~ ac/ds, causClc, oxtdtze=s such as c~=o~es. HAZARDOUS DECOM~SITION PRODU~ Smo~e, ~est ca=bo~ mo~oxlde~ ca=bo~ dioxide, oxides o~ ~t~=o~e~. POLYMERIZATION: MAY · ...:. ~:?~:'~-.:::.?..':'?;.::'~-~-:~:~.::=:.'??~.:.~:~.??~J SECTION VII -- SPILL OR LEAK PROCEDURES ... ~ EVACUATE AE~ ~ R~PI RATORY PROTE~ION ~ EVA~RATE SMALC NEUTRALIZE A~D WASH'" (~ PER SECTION VIII) U AMOUNTS IN HOOD '~ AWAY WITH WATER O~ERVE GOVERNMEN- SKIN PROTECTION INCINERATE UNDER ~TAL SPILL & WATER ~STOP FCOW ~ (AS PER SECTION VIII) O CONTROLCED CONDITIONS ~QUALITY REGU~TIO~ ELIMINATE ALL SOURC~ INCINERATE USING A~ER ~ REMOVE SOICED OF IGNITION, F~MMABC~ ~ A~ORB OR SCRAPE UP ~ BURNER & SCRUBBER ~CLOTHING mKEEP U~INO AND ~ AVOID INHALATION ~ VACUUM UP ~ ~NDFILL OR ~NDFARM UISO~TE EXPOSURE AREA ~ AVOID DERMA~ CONTACT ~ OTHER ~ sECURE CHEMICAL LANDFILL · ~' ............ ~;.*~*,:-~.-?;~*~.:~.~.'::'~??.'~:~:~:~?~ SECTION VIII -- SPECIAL PROTECTION INFORMATION ~:~?;:.~?~?~.~?~.~?~?~?", '..~ R~PlRATORYPROTECTION (~p~pe} ~ODe needed ~ r0ut~e use. VENTI~TION LOUL EXHAU~ SPECIAL ~eco~ended ~eg~8 c~n~s og clearing MECHANICAL (~/ la~ge spllls; at~ supp17 ~eco~ended. PROTECTIVE GLOVES I EYE PROTECTION ~eop~ene o~ laCe~ ~ubbe~I ch~tcal saEe~7 goggles OTHER PROTECTIVE E~UIPMENT eTebaCh sCa~ions og ~a~eg supp17; sho~egs PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep away from sparks and excessive heat. Avoid contact. OTHER PRECAUTIONS Know and be able to use first aid and fire fighting procedures. The ~formatien ~taiae4 heroin b ~ ea 4~ta ~mk~4 a~rate. H~, ne wa~mm% expmm~ er impl~4. b given regarding the accuracy of thrum data or the results to be obtiin~d from ~. ,,em thmrmW Champio , Chemicals,Inc. "'~.'"' MATERIAL SAFETY DATA SHEET MANUFACTURER~ NAME EMERGENCY TELEPHONE NO. ~ION' CH]~G. CA~S, INC. .' 715-451-2562 -. ADDRESS 3130 FM 521 , Fresno, Texas 77545 .... · (P. O. Box 45509~ Houston~ Texas 77045) PRODUCT CORTRON R-2211 CHEMICAL FAMILY : FORMUL.~ proPrietaz~z , Amine/Fatt7 Acid Mixture TLV - TLV MATE RIALS % (Units) MATE RIALS % (Un its) petroleum naphtha '-- BOILING POINT (F.) 250-500 SPECIFIC GRAVITY (H20 = 13 0. 954 PERCENT, VOLATILE VAPOR PRESSURE (mm Hg.) [hid BY VOLUME (%) ND VAPOR DENSITY (AIR = 1) EVAPORATION RATE SOLUBILITY IN WATER nil Viscosity (cps) 65 APPEARANCE ANDODOR Dark black liquid with a pungent aromatic odor. F~SH PO,NT 180°F (Tcc> I F~MMABLE L,M,,S I LEL I UEL EXTINGUISHING MEDIA D ALCOHOL FOAM ~ CARBON DIOXIDE ~ DRY CHEMICAL ~ FOAM ~ WATER SPRAY (FOG} ~ OTHER : SPECIAL FIRE FIGHTING PROCEDURES ~a~er spra7 ~7 be used to coo[ ~re-exposed me~a[ containers to preven~ re-~gn~t~on from hoe surfaces. Do no~ br~the smoke or ho~ E~es. FIRE AND EXPLOSION HAZARDS None ~o~. - TRANSPORTATION DATA -- ~ US DEPARTMENT OF TRANSPORTATION HAZARD CLASS · COMBUSTIBLE LIQUID I'~IUNREGULATED BY D.O.T. LABEL REQUIRED .......... - NONE, if container capacity is 110 ~allons or less. US D.O.T. PROPER SHIPPING NAME ................... I UN NUMBER COMBUSTIBLE LIQUID, N.O.S. I NA1993 ....- ................ · . ::":'..:.-"" -'...~ ......... ~--., "i! SECT~ V - HEALTH HAZARD DATA 'HRESHOLO LIMIT VALUE Nolle establ~Ls~ned ~or product. :FFECTS OF OVEREX~SURE gv~ Irritation, itching, excessive tear~g. S~NCONTA~ Irritation, redness. Sensitized sk~ ~y show der~titis. *--'~'~ ~NHA~WON Nausea, dizziness; pne~omia'if aspirated. ~SWACCOWE~ Nausea, v~ting~,and other s~pt~s of petrole~ naphtha poison~g. :~Ea~ENCV AND ~,aSV A,O EV~ Flush ~th cl~ water ~ediately for 15 m~uces and see ~ eye doctor. S~,N CONTACT Wash ~th soap and water. ~move' ~d launder clothes before re-wearing. If skin ~ritation persists, see a physician. ~NHA~V, ON R~ove ~o fresh air. Give artificial respiration '~f needed. ~SWACCOWE~ Give ~lk or water to dilute. Do not induce vomit~g. Get ~ergency medical treatment ~o~ pecrole~ naphtha ingestion. STABILITY: l UNSTASLEI I STASLEI xl Sources of i~nition ~JCOMPATABILITY (Materials to AZARDOUS DECOMPOSITION PRODUCTS Smoke, fumes, carbon monoxide, carbon d/oxide, oxides of nitrogen. I OLYMERIZATION= MAY OCCUR WILL NOT OCCUR ~:~:~-:~?~:~::?~??~:~::~:~:??::~::?:~::~:~:~:~:.:~ SECTION VII - SPILL OR LEAK PROCEDURES I' '.:.?:~":':':~:.~:~??:::'"~': RESPIRATORY PROTECTION m EVAPORATE SMALL m NEUTRALIZE AND WASH ~ EVACUATE AB~ ~ (~ PER SECTION VIII) U AMOUNTS IN HOOD ~ AWAY WITH WATER O~ERVE GOVERNMEN- SKIN PROTECTION INCINERATE UNDER RTAL SPILL & WATER ~TOP FCOW ~ (AS PER SECTION VIII) ~ CONTROLCED CONDITIONS ~QUALITY REGU~TIONS ~ELIMINATE ALL SOURC~ INCINERATE USING A~ER ~ REMOVE SOICED OF IGNITION, F~MMABL~ ~ A~ORB OR SCRAPE UP ~ BURNER & SCRUBBER ~CLOTHING ~KEEP UPWIND AND ~AVOID INHA~TION ~ VACUUM UP ~ ~NDFILL OR LANDFARM ~ISO~TE EXPOSURE AREA ~ AVOID DERMAL CONTACT ~ OTHER ~ SECURE CHEMICAL ~NDFILL · :'?:.':'?'~: ~. ?';~':.??:?:?"~??~-::"?:~.:.-?::?:':~ SECTION VIII - SPECIAL PROTECTION INFORMATION ~;~?~???:~::;~:~?:?? ESPl RATORY PROTECTION f~p~ ~o~e ~eeded ~ :ou:tae use. 'ENTI~TION LOCAL EXHAUST SPECIAL ~eco~e~ded ~:e:t~g :a~s o: clea~t~g MECHANICALfGenemI/ la:ge spills; at: supply :eco~e~ded. ROTECTIVEGLOVES ~ EYE PROTECTION ~eop:e~e o: la:ex :ubbe~ chemical safety goggles ,THER PROTECTIVE EQUIPMENT eyebach stations o: ~ace: supply; sho~e:s aECAUTIONS TO SE TAKEN IN HANDLING AND STORING Keep away from sparks and excessive heat. Avoid contact. ]-HER PRECAUTIONS.. Know and be able to 'use' first'-~id and fire fighting' 'pr'0~edures. .... f. · : ~'*'.,; The information contained heroin is basKI on data considered __~__,rate. However, no warranty, expr~KI or implied, Champio Chomicals,lnc. 'MATERIAL SAFETY DATA SHEET MANUFACTURER'S NAME .EMERGENCY TELEPHONE NO. CHAMPION CRF3[ICALS, INC. 1-800-424-9300 :'* ADDRESS ' - ' 3130 Highway 288. Fresno, Texas 77545 (P. O. Box 45509~ Houston~ Texas 77045) PRODUCT CORTRON RN~106 CHEMICAL FAMILY FORMULA proprietary Am/neB ...... : .......... , ~-~i:..~¥~! SECTION"il -- HAZARDOUS INGREDIENTS t ~ ...... ":. '"'-' ":'" TLV TLV ,* MATE RIALS % (Units) MATE RIALS % (Units).* Keroseae ": ~ ........... ·'1 SECTION III -pHySICAL DATA ! SOILING POINT (F.) I~P 130 SPECIFIC GRAVITY (H20 ~' 1) 0.,77 PERCENT. VOLATILE VAPOR PRESSURE (mm Hg.) ~ BY VOLUME (%) vAPOR DENSITY (AIR = Z) 'ND VtSCOStC7 (CPS) 20 SOLUBILITY,,,, IN WATER highly dispersible pH (1Z in 75/25 TFA/H20) 10.65 APPEARANCE AND ODOR Clear yellow liquid ~rlth an ammoniacal odor. ' :" '" I SECTION IV -- FIRE AND EXPLOSION HAZARD DATA I FLAs. PO,.T <-60F' (TCC) i FLAMMASLE L,M,TS I' LEL I U~L EXTINGUISHING MEDIA rl ALCOHOL FOAM [] CARBON DIOXIDE [] DRY CHEMICAL [] FOAM [] WATER SPRAY (FOG) I--] OTHER SPECIAL FIRE FIGHTING PROCEDURES Water spray may be used to co01 fi~e-exposed metaZ co~ta/~e~s to preveat from hot su~aces. Do___~ br~the smoke o~ hot ~es. ~RE ~.D EXPLOSm. HAZARDS ~o:e ~o~. - TRANSPORTATION DATA US DEPARTMENT OF TRANSPORTATION HAZARD Cl..A~S .......... I ........ ~[~. LIOUID I I--)UNREGULATED BY D.O.T. ' LABEL REQUIRED . , :.., ..:: .-,.,: . . , . · . FLAMMABLE LIQUID US D.O,T. PROPER SHIPPING NAME ....................... UN NUMBER * . . FLAMMABLE LIqUID~ N;O.S. UN1993 PRODUCT L, UKLL~U~ ~L~--.LUO Page 2 of 2 THRESHOLD LIMIT VALUE None established for product. EFFECTS OF OVEREXPOSURE EVES Irritation, itching, excessive tearing. SKIN CONTACT. Irritation, redness. Sensitized skin may show dermatitis. INHALATION Nausea, dizziness; pneumonia if aspirated. IF SWALLOWED Nausea, vomiting, and -other symptoms of kerosene poisoning. EMERGENCY AND FIRST AID PROCEDURF.~ EYES Flush with clean water ~mmediately for 15 minutes and see an eye doctor. SK,N CONTACT Wash with soap and water. Remove and launder clothes before re-wearing. INHALATION If skin irritation persists, see a physician. Remove to fresh air. Give artificial respiration if needed. IF SWALLOWEO Give milk or water to dilute. Do not induce vomiting. Get emergency medical ·treatment for kerosene ingestion. J CONDITIONS TO AVOID STABILITY: I UNSTASLEI I STABLEIx I Sources of iKnition INCOMPATABILITY (Materials to HAZARDOUS DECOMPOSITION PRODUCTS Smoke. fumes; carbon monoxide, carbon dioxide, oxides of nitrogen. POLYMERIZATION: MAY OCCUR WILL ~OT OCCUR X RESPIRATORY PROTECTION ~ EVAPORATE SMALL ~ NEUTRALIZE AND WASH [] EVACUATE AEF-~ ~] (AS PER SECTION VIII) i i AMOUNTS IN HOOD i iAWAYWiTH WATER OBSERVE GOVERNMEN- SKIN PROTECTION INCINERATE UNDER ~]TAL SPILL & WATER ~STOPFLOW ~] (AS PER SECTION VIII) [] CONTROLLED CONDITIONS QUALITY REGULATIONS ~ ELIMINATE ALL SOURCES INCINERATE USING AFTER ~ REMOVE SOILED OF IGNITION, FLAMMABLES ~ ABSORB OR SCRAPE UP ~ BURNER & SCRUBBER ]~ CLOTHING mKEEP UPWIND AND "k--I AVOID INHALATION [] VACUUM UP [--ILANDFILL OR LANOFARM LJISOLATE EXPOSURE AREA ~'~ AVOID DERMAL CONTACT [] OTHER ~] SECURE CHEMICAL LANDFILL RESPIRATORY PROTECTION ($peci. l~O,pe) None needed in routine use. VENTILATION LOCAL EXHAUST I SPECIAL Recommended ~ntering tanks or cleaning MECHANICAL (General/ ~arge spills; air supply I :ecommended. PROTECTIVE GLOVES I EYE PROTECTION neoprene or latex rubberI chemical safety goggles 'bTHER PROTECTIVE EQUIPMENT eyebath stations or water supply; showers. PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep away from sparks and excessive heat, Avoid contact ..... OTHER PRECAUTION~ Know and be able to use first aid and fire fighting procedures. The information contained herein is based on data considered aecurata. However, no warranty, expressed or implied, Champio Chemicals,Inc. MATERIAL SAFETY DATA SHEET M~N~FACTURER~ NAME EMERGENCY TELEPHONE NO, CRAMPION CREMICALS, INC. 1-800-424-9300 ADDRESS 3130 Highway 288, Fresno, Texas 77545 . (P. O. Box 45509~ Houston~ Texas 77045) PRODUCT D-TRON' SC-14 CHEMICAL FAMILY FORMUL~ deter~ents proprietar7 TLV TLV MATERIALS % (Uni~) MATERIALS % (Units) methanol 12 200(ppm) .... ', ,, '" ':'::::::~"":~:' ..... : ':~1 SECTION III - PHY~;ICAL DATA i BOLLING POINT ( F.) aqueous SPECIFIC GRAVITY (H20 = 1) 1. 000 PERCENT, VOLATILE VAPOR PRESSURE (mm Hg.) ~D BY VOLUME (%) 12 VAPOR DENSITY {AIR = Z) ~ .~ Viscosity (cPS) @ 75° F 36 SOLUBILITY IN WATER soluble pH of 1% solution 8.5 APPEARANCE ANOO[:)OR Light yellow liquid with a sweet odor. '.'"~':~'?-'-:;::"~:'::"::" :. ::'.i'SECTION IV-- FIRE AND EXPLOSION HAZARD DATA I :::~::~ : '' .... FLASH POINT' 85 o~ ~TCC') I FLAMMABLE LIMITS I'LEu I .EL I m EXTINGUISHING MEDIA r~ ALCOHOL FOAM ~--~ CARBON DIOXIDE r~ DRY CHEMICAL ~3~ FOAM [] WATER SPRAY (FOG) ~'~ OTHER ~ SPECIAL FlEE FIGHTING PROCEDURES Water spray ma7 be used to cool £ire-exposed metal containers to prevent re-ignition from hot surfaces. " : Do not breathe smoke or hot fumes. FIRE AND EXPLOSION HAZARDS Hone k~o~m. - TRANSPORTATION DATA ' ' US DEPARTMENT OF TRANSPORTATION HAZARD CLASS I FLAMMABLE LIQUID! ~UNREGULATED BY D.O.T. lABEL REQUIRED FLAMMABLE LIQUID US O.O.T. PROPER SHIPPING NAME I UN NUMBER FLAMMABLE LIQUID, N.O.S .... '! UN1993 'HRESHOLD LIMIT VALUE None eska~£ished for product. ~FFECTS OF OVEREXPOSURE gv~s Irritation, itching, excessive tearing. SKiN CONTACT Irritation, redness. Sensitized skin may show dermatitis. INHALATION Nausea, dizziness; pneumonia if aspirated. 'FSWA~OWED ' .M. outh amd es. ophagus .may _be chemically burned, pH of 1% solution is 8.5. mausea, vomltlmg, Bna other symptoms of methanol poisoning. -'MERGENCY AND FIRST AID PROCEDURE~ EYES Flush with cleam water immediately for 15.minutes and see an eye doctor. SKIN CONTACT Wash with soap and water. Remove and launder clothes before re-wearing. INHAL~TION If skin irritation persists, Bee a physician. Remove to fresh air. Give artificial respiration if needed. IF SWALLOWED Give milk or water to dilute. Do not induce vomiting. Get emergency medical treatment for methanol ingestion. ,. "i,,: "*.-,':'~/!~i~:i:~.~.i. ~? ='.~.-??~=,,?.~=~??=:~i~!i~!~,?~.??~?!i~ii,~ SECTION VI -- REACTIVITY DATA STAB,--,TV: l UNSTABL£1 I STABLEI xl Sources of ignition NCOMPATABILITY (Materials to avoid) Mineral acids, caustic, oxidizers such as chromates. ~AZARDOUS DECOMPOSITION PRODUCTS Smoke, fumes, carbon monoxide, carbon dioxide~ oxides of nitrogen. 'IAZARDOUS I I I I XlCONDITIONS TO AVOID ~OLYMERIZATION: MAY OCCUR WILL NOT OCCUR ~.'::? .: :'."~'::::?-'~ SECTION VII -- SPILL OR LEAK PROCEDURES I ..... "-~?i::'"'?~'~'~:'i:':":': ~ RESPIRATORY PROTECTION,-~ EVAPORATE SMALL NEUTRALIZE AND WASH r'J EvACUATE AREA ~] (AS PER SECTION VIII) i i AMOUNTS IN HOOD E]AWAY WITH WATER OBSERVE GOVERNMENo SKIN PROTECTION iNCiNERATE UNDER r2] TAL SPILL & WATER ~STOPFLOW ~ (AS PER SECTION VIII) [] CONTROLLEDCONOITIONS ~(~UALITY REGULATIONS ~ELIMINATE ALL SOURCES INCINERATE USING AFTER ~ REMOVE SOILED OF IGNITION, FLAMMABLES ~ ABSORB OR SCRAPE UP ~ BURNER & SCRUBBER ~CLOTHING r~KEEP UPWIND AND ~AVOID INHALATION F~ VACUUM UP [] LANDFILL OR LANDFARM LJISOLATE EXPOSURE AREA r~ AVOID DERMAL CONTACT [] OTHER ~ SECURE CHEMICAL LANDFILL ....... ~.~: RESPIRATORY PROTECTION [$pt~C~ ~7£} None needed in routine .use. VENT,LATION LOCAL EXHAUST SPEC'AL Recommended Entering tanks or cleanin§ MECHANICAL [~} large spills; air supply recommended. PROTECTIVE GLOVES I EYE PROTECTION neoprene or latex rubber I chemical safety goggles OTHER PROTECTIVE EQUIPMENT eyebath stations or water supply; showers PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Eeep away from sparks and excessive heat. Avoid contact. OTHER PRECAUTIONS The information ¢°~tained hernia i~ ba~d on data considered m~uram. Howe~er, no warranty, expressed or implied, U.S. DEPARTMENT OF LABOR ~o,m A..,ov,. OMB NO. 44-R].387 Occupational Safety and Health Administration h i TEfii L SAFF. T¥ DATA SflEET / Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917) SECTION I MANUFACTURER'S NAME ~ EMERGENCY TELEPHONE NO, Cha.mp/c~ Chemicals, :Loc. I 713/431-2561 ADDRESS bVttmbcr, Street, tit)', State, a/rd ZIP Code] Box 45509, Houston, Texas (3130 Hwy 288, Fre.s~, Texas 77545) CHEMICALQ~at~r~izedNAME AND~SY, NONYMS IJ TRADE NAME AND SYNONYMS~O~ GR-47 CHEMICAL FAMILY I FORMULA I SECTION II - HAZARDOUS INGREDIENTS TLV TLV PAINTS, PRESERVATIVES, & SOLVENTS % ~Units) ALLOYS AND METALLIC COATINGS % (Units) PIGMENTS BASE METAL CATALYST ALLOYS VEHICLE METALLIC COATINGS -FILLER METAL SOLVENTS 15 400 F~[I, Lus COAT,NS oR cORE FLUX ADDITIVES t OTHERS OTHERS Wa~?_l- I TLV HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % (Units) SECTION Iii - PHYSICAL DATA eO,L,nG PO,NT (°F.) 170--212'~ SPECIFIC GRAVITY (H20=1) 0.99 PERCENT, VOLATILE VAPOR PRESSURE (mm HcJ.) BY VOLUME (%) 67% EVAPORATION RATE Slowly VAPOR DENSITY (AIR=l) ( SOLUBILITY IN WATER Cc~ple~ APPEARANCE AND ODOR SECTION IV- FIRE AND EXPLOSION HAZARD DATA FLASH POINT (MetnoO userS) ~ 80°F IFLAMMABLE LIMITS I Lei I Uel EXTInGUiSHING BEOIA W~I ~t B~ SPECIAL FI"E FlaHT~NG PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS PAGE (1) (Continued on rever~a ,ide) Form OSHA-20 ~age Z - 5oortron C~.-47 SECTION V - HEALTH HAZARD DATA THRESHOLD LINIIT VALUE EFFECTS OF OVEREXPOSURE Dizziness and skin rash possible from contact EMERG£NCYANOF'RSTA'OPRO¢~T~ to fresh ~r - wash from skin with soap and water. Flush from eyes wi~h water for 5-10 minu~es and consult ~ysic~. SECTION VI - REACTIVITY DATA' S~ABILIT¥ CC~DITIONS TO ~VOIO UNSTABLE STABLE HAZARDOUS DECOM~SlTION PRODUCTS CONDITIONS TO AVOID HAZARDOUS MAY OCCUR ~LYME RIZATION WILL NOT OCCUR SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Fl~h wi~ WASTE DISPOSAL METHOD SECTION ViII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION [$pe¢~/~ ~ypej None necessary above non, al precaution VENTILATION I LOCAL EXHAUST SPECIAL I MECHANICAL [G~ttcraJ} OTHER ~ spec~ PROTECTIVE GLOVES I EYE PROTECTION Goggles I OTHER PROTECTIVE £mUIPMENT SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING No Special Precautions Necessary OTHE~ PRECAUTIONS PAGE (2} eeo ,34.~m '" Form OSHA-20 ........ ' Reef. May 72 THRESHOIc, D LIMIT VA~UE ....... ~ .... " None est~*_~J~ed for product. EFFECTS OF OVEREXPOSURE EYES Trrttation, itching, excessive tearing. SKIN CONT^CT TrrtCatlon, redness. Sensitized sktn ~ay show dermatitis. INHALATION Nausea, dt~-zl~ess; pneumonia if asp/rated. IFSWAI. LOWED Nausea,.vomtt/~g, .and other symptoas 'of btsuZflte poison/ag. EMERGENCY AND FIRST AID PROCEDURES EYES Flush with cle~n water t~,edtately for 15 minutes and see an eye doctor. SKIN CONTACT Wash ~t/th soap and ~aceg. ~ove ~d launde~ cloches beffo~e ~e-,ea~t~g. INHA~TION [~ove co ~esh at~. Give a~Clfftctel ~espt~aCto~ tff ~eeded. IF SWALLOWED Give ~1~ o~ ~aCe~ to dilute. Z~duce vomtt~g. Get ~e~genc7 medical C~Cne~C ffo~ btsulfftCe ~gesCto~. ~ :,.::.: ===================================================================== ::.:~:~:--::::.~: INCOMPATABIUTY (Materla~ to Htne~aZ acids, caustic, oxtdtze~s such es ch~o~ces. H~Z~,OOUS o~co~smo~ ca~bon dtozt~e~ ox/des of ntC~o~en~ sulfu~ oxides. Smo~e. ff~es t ca~5on monoxide ~ .. m R~PI RATORY PROTECTION EVAPORATE SMALL : ~ ~'EuTRALIZE AND WASH ~ EVACUATE ABEA ~ lAS PER SECTION VIII) ~ AMOUNTS IN HOOD ~ AWAY WITH WATER OBSERVE GOVERNMEN- ~STOP FLOW ~ SKIN PROTECTION INCINERATE UNDER ~TAL SPILL & WATER ~ ~ PER SECTION VIII) ~ CONTROLLED CONDITIONS ~UALITY REGU~TIONS ELIMINATE ALL SOURC~ INCINERATE USING A~ER m REMOVE SOILED OF IGNITION, F~MMABL~ ~ A~ORB OR SCRAPE UP ~ BURNER & SCRUBBER ~LOTHING mKEEP U~IND AND ~AVOID INHA~TION ~ VACUUM UP ~ ~NDFILL OR ~NDFARM UISQ~TE EXPOSURE ARiA ~AVOID DERMAL CONTACT ~ OTHER ~SECURE CHEMICAL ~NDFILL R~PI RATORY PROTECTION ~ ~one needed ~ ~outi~e use. VENTI~TION LOlL ~HAUST SPECIAL Reco~ended Entering tan~ or clearing ~ECHmN~CA~ fG~r~l~ large spills; air supply ~eco~ended. neoprene .or latex rubber~ chemical safety goggles OTH[R .moV[CT~V[ aeUm~ENT eyebath stations or water supply; showers PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep away from sparks and excessive heat ................... Avoid contact. OTHER PRECAUTIONS Know and be able to use first aid and_. fire..ftghtin*~' procedures. The information emtt~ined heroin is based on data considered agcurat~. Howevm, no wjrr41tt¥, l](plll~l~d o1' i~l~, Champk. Chemicals,Inc. MATEFIIAL SAFETY DATA SHEET MANUFACTURER~ NAME EMERGENCY TELEPHONE NO. CHA~[PION CHEMICALS, INC. 713-431-2561 ADDRES~ 3130 FM 521, Fresno, Texas 77545 (P. O. Box.45509, Houston. Texas 77045) PRODUCT CORTRON ~TR-3017 CHEMICAL FAMILY FORMULA amine salts proprietary TLV TLV MATERIALS % (Uni~) MATERIALS % (Uni~) methanol 4 200 (~ ~etroleum naphtha BOILING POINT ( F.} SPECIFIC GRAVITY EH20= 1) 250-500 PERCENT, VOL~TI LE VAPOR PRESSURE (mm Hg.) ]%TD BY VOLUME (%) ~(~ VAPOR DENSITY {AIR = 1) EVAPORATION RATE SOLUBILITY INWATER dispersible ¥iscosity @ 75° F 15.5 cps APPEARANCE ANDODOR Dark brown liquid with a pungent odor. · ....~i.:: · :~?.::;i:~...~*.* '~*~*~1 SECTION IV -- FIRE AND EXPLOSION HAZARD DATA t F~SH PO,NT ~° ~ (TCC)' !~"~ ~'~'~ I~' I°~ EXTINGUISHING MEDIA O ALCOHOL FOAM ~ CARBON DIOXIDE ~ DRY CHEMICAL ~ FOAM ~ WATER SPRAY (FOG) O OTHER SPECIAL FIRE FIGHTING PROCEDURES ~aCe~ sp~a7 ma7 be used co co°l Eige-~posed ~ecal containers ~o p~eve~c ~e-ignicion ~gom hoc sug[aces. Do ncc b~eache smoke og ho~ ~es. FIRE AND EXPLOSION HAZARDS None ~o~. - TRANSPORTATION DATA US DEPARTMENT OF TRANSPORTATION HAZARD CLASS FLAMMABLE LIQUID ) IT]UNREGULATED BY O.O.T. LABEL REQUIRED FIr,AMOrA 1~'1', F. T.TC)IrTTh. us D.O.T. PROPER SHIPPING N'AME I UN NUMBER ,,, ~LAP~ABL~. LIQUID,. N.o.s. [ UNlqq'~ ,. * : '- 1 S~=~.v~-~ON V - HEALTH HAZARD DATA;. THRESHOLD LIMIT VALUE r None est~.'~aed for product. EFFECTS OF OVEREXPOSURE EMERGENCY AND FI ~T AID PROCEOUR~ SKIN CONTACT ~ash ~t~h soap ~ ~aCe~. ~ove a~d lau~d~ clo[hes INHA~TION [~ Skt~ tg~t~a~to~ pe~ets~s, see a IF SWALLOWED Give milk og ~aCeg [o ~t[u[e. Do ~o~ t~uce medical c~ee~e~c ~o~ pec~ole~ aaphcha 1~gesClo~. STABILI~: ! UNSTABLEI J STABLE~X J Sources of ignition INCOMPATABIUTY (M~lals ~ avoid) ~neral acids, caustic, oxid~ers such. as c~0maCes4 HAZARDOUS OECOU~SITI~N PROOUC~ Smo~e, f~e~, carbon monoxide, carbon dioxide, oxides of nfcro~en~ RESPIRATORY PEOTECTION m EVAPORATE 5MALL NEUTRALIZE AND WASH ~ EVACUATE A~ ~ (~ PER ~ECTION VlII) U AMOUNTS IN HOOD ~ AWAY WITH WATER O~ERVE GOVERNMEN- 5KIN ~ROTECTION INCINERATE UNDER ~TAL 5PILL & WATER ~STOP FLOW ~ (~ PER SECTION VIII) ~ CONTROLLED CONDITION5 ~ GUALITY REGU~TIONS ELIMINATE ALL SOURCE5 INCINERATE USING A~ER REMOVE SOILED ~OF I~NITION, F~MMABL~ ~ A~ORB OR SCRAPE UP ~ BURNER & SCRUBBER ~ CLOTHING mKEEP U~IND AND ~ AVOID INHA~TION ~ VACUUM UP ~ ~NDFILL OR ~NDFARM ~ISO~TE EX.SURE AREA ~ AVOID DERMA~ CONTACT ~ OTHER ~ 5ECUEE CHEMICAL ~NDFILL RESPIRATOnY PROTECTION ~p~ ~o~e ~eede~ ~ ~ou~e use. VENTI~TION LOCAL EXHAUST ~ SPECIAL ~eop~e~e o~ [a~ ~bbe~ ~ chemical sa~e~7 ~o~s[es 3~ER PROTECTIVE EQUIPMENT ~RECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep away from sparks and excessive heat. Avoid contact. )THER PRECAUTIONS Know and be able to use first aid and fire'fi~;htin§ procedures. The information contained heroin is based on data considered ~curm. However, no warranty, expressed or implied, is given regarding the accuracy of these data or the results to be obtained from the use thereof. - Champic,,e. Chemicals,Inc. MATERIAL SAFETY DATA SHEET MANUFACTURER~ NAME EMERGENCY TELEPHONE NO. C%L~PION CETEMICALS, INC. 713-431-2561 ADDRESS 3130 FM 521, Fresno, Texas 77545 (P.O. Box 45509, Houston, Texas 77045) PRODUCT, C0RTRON WR-8039 CHEMICAL FAMILY FORMUI.~ aqueous amine blend ' proprletar7 TLV TLV MATERIALS % (Units) MATERIALS % (Units) methanol 4 ° BOILING FNDINT { F.) 85_212OF SPECIFIC GRAVITY (H20 = l) 1.114 PERCENT, VOLATILE VAPOR PRESSURE {mm HE.) ND BY VOLUME (%) VAPOR DENSITY (AIR = Z) ~ EVAPORATION RATE SOLUBILITY IN WATER soluble D~ 5.7 8 APPEARANCE AND ODOR Dark .1. iquid with 'a pungent odor of sulfur dioxide. F~SHPO,NT ll0°F (TCC) I F~MM^BLE L,M,TS I LEL lULL EXTINGUISHING MEDIA [] ALCOHOL FOAM ~ CARBON DIOXIDE ~ DRY CHEMICAL ~ FOAM ~ WATER 5PRAY (FOG) ~ OTHER SPEClA~ FIRE FIGHTING PROCEDUR~ NaCe= Bp=ay ~y be used· Co CODE ~=e-exposed me~a[ conca~ne=s co p=eve~C =e-~s~C~o~ ~o~ hoc su=~aces. Do hoc b=ea~he smoke o= hot ~umes. F~RE nNO EX.LOmON H~ZnRDS ~o~e ~o~. - TRANSPORTATION DATA US DEPARTMENT OF TRANSPORTATION HAZARD CLASS COMBUSTIBLE LIQUID I r"]UNREGULATED BY D.O.T. LABEL REQUIRED NONE, if 110 gallons or less per container US D.O.T. PROPER SHIPPING NAME I UN NUMBER COMBUSTIBLE LIQUID, N.O. S ' I NA1993 THRESHOt~D LIMIT VALUE.~_. None est.- ..... bed for product. EFFECTS OF OVEREXPOSURE EYES.Irritation, itching, excessive tearing. SK'NCONTACT Irritation, redness. Sensitized skin may show dermatitis. SNHA~A~ON Nausea, dizziness; pneumonia if aspirated. SFSWA''OWED Nausea, vomiting, .and other symptoms of bisulfite poisoning. EMERGENCY AND FIRST AID PROCEDURES EYES Flush with clean water immediately for 15 minutes and see an eye doctor. SKIN CONTACT Wash with soap and water. Remove and launder clothes before re-wearing. If skin irritation persists, see a physician. INHA~TION Remove to fresh air. Give artificial respiratiom if needed. IF SWALLOWED Give milk or water to dilute. Induce vomiting. Get emergency medical treatment for bisulfite ingestion. "" I .... i I .......... I' I STABILITY= [UNSTABLE[ [,STABLEIX I Sources of ignition INCOMPATABILITY (Material- to avo~) Mineral acids, caustic, oxidizers such as chromates. HAZARDOUS DECOMPOSITION PROOuGT~ Smoke~ fumes~ carbon monoxide~ carbon dioxide, oxides of HAZARDOUS I '' ' [ .... ' ' ] X. CONDITIONS TO A~OID ' nitrogen, , sulfur oxides. POLVME"''AT'ON: I MA' OCCU"I IW'LLNOT OCCV" RESPIRATORY PROTECTIONr~ EVAPORATE SMALL m NEUTRALIZE AND WAS'H E~ EVACUATE AEEA [~ (AS PER SECTION VIII) I-J AMOUNTS IN HOOD [-J AWAY WITH WATER OBSERVE GOVERNMEN- {~$TOP FLOW ~ SKIN PROTECTION INCINERATE UNDER I-4-TAL SPILL & WATER I.~ (AS PER SECTION VIII) r~ CONTROLLED CONDITIONS ~'*G~UALITY REGULATIONS [~ELIMINATE ALL SOURCES INCINERATE USING AFTER m REMOVE SOILED OF IGNITION, FL*~XMMABLES [~ ABSORB OR SCRAPE UP C~ BURNER & SCRUBBER L~CLOTHING mKEEP UPWIND AND [~AVOID INHALATION r-J VACUUM UP [] L~NDFILL OR LANDFARM LJISOL~TE EXPOSURE AREA [~AVOID DERMAL CONTACT [] OTHER [~SECURE CHEMICAL LANDFILL RESPIRATORY PROTECTION ($peCJ~ None needed in routine use. VENTILATION LOCAL EXHAUST SPECIAL Recommended ~ntering tanks or cleaning MECHANICAL f~¢/'Ie/,'IZI} Large spills; air supply ~ecommended. PROTECTIVE GLOVES I EVE PROTECT,ON neoprene .or latex rubberI chemical safety goggles OTHER PROTECTIVE EQUIPMENT eyebath stations or water supply; showers PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Keep away from sparks and excessive heat Avoid contact. · .... -. · :.L. .-.'~'- .% OTHER PRECAMTIONS tr~ow and be able to use first aid and fire f~gh:~g P:ocedu:es. . ~e info~at~ ~ ~min ~ b~ on dm ~n~e~ ~. How~, ~ warm~, exp~ or i~l~, b g~ ~ina ~ ~ of ~m d~a or the m~l~