HomeMy WebLinkAboutBUSINESS PLAN BAKERSFIELD CITY FIRE DEPARTI~ENT
· 2130 "G" STREET
BAKERSFIELD, CA 93301
.... (805) 326-3979
OFFICIAL USE ONLY
HAZ ARDO1JS MATERI ALS
BUSINESS P'LAN AS a WHOLE
F()RM 2A
INSTRUCTIONS: 0 00 "~]/"" 9
1. TO avoid further action, ~etu~n this fo~m by
2. TYPE/PRINT ANSWERS IN ENGLISH. :
3. Answe~ the questions below fo~ the business as a whole.
4. Be as b~lef and concise as possible.
SECTION 1: BUSI~SS IDE~IFICATION DATA
A. BUSINESS N~E: Banks Pest Control, Inc.
B. LOCATION / STREET ADDRESS: 215 Go~den State Ave.
CI~: Bakersfield ZIP: 93301 'BUS=.P~ONE: (805) 323-7858
SECTION 2: EMERGENCY NOTIFICATIONS
In case of an emergency involving the release or threatened release'of a
hazardous material, call 911 and 1-800-8§2-75§0 or 1-916-427-4341. This will notify
your local fire department and the State Office of Emergency Services as required by
law.
EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY:
NAME AND TITLE DURING BUS. HRS. AFTER BUS. HRS.
A. O~tand Banks Ph# (805) 323-7858 Ph# (805) 399-t591
B. William H. Rogers Ph# (805) 323-7858 Ph# (805) 399-1421
SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOL~
A.. NAT. GAS/PROPANE: West outside wall a~jacent to "V" St.
B. ELECTRICAL: West outside wall adjacent to "V" St.
C. WATER: West outside wall adjacent to "V" St.
D. SPECIAL:
E. LOCK BOX: YES / N~_~ IF YES, LOCATION:
IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO
FLOO'R'PLANSg. YES / NO KEYS? YES / NO
- 2A
SECTION 4:-PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE
Does not apply
SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE
~ '~ ~Mipor ~injuries first aid tre. atment or persons own private physician
or t~n~~' to Bakersfield Memorial Hospital which is the closest
hospital from our place of busine.c;s.
SECTION 6: ~MPLOYEE TRAINING
EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND
REFRESHER TRAINING IN THE FOLLOWING AREAS.
B, PROCEDURES FOR COORDINATING ACTIVITIES:
WITH RESPONSE AGENCIES: .......................... ~-~ NO YES NO
C. PROPER USE OF SAFETY EQUIPMENT: .................. ~ NO (~ NO
D EMERGENCY EVACUATION PROCEDURES: .................~) NO ~ NO
E DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... NO .~ NO
SECTION 7: HAZ~H~DOUS I~[ATERI~d,
CIRCLE YES OR NO
DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A
SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES NO
I, WilliamH. Rogers , certify that the above information is accurate.
I understand that this tnformatlon will be used to fulfill my firm's obligations under
the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95
Sec. 25500 Et Al.) and that inaccurate information constitutes perjury.
SIGNATURE ~[.~[~.~_~ TITLE Owner DATE 3o 77
BAKERSFIELD CITY FIRE DEPARTMENT
2130 "G" STREET
BAKERSFIELD, CA 93301
OFFICIAL USE ONLY
ID#
BUSINESS NAME:
BUS I :NESS PLAN
SINGLE FACILITY UNIT
FORM 3A
INSTRUCTIONS 1. To avoid further action, this form must be r'eturned by:
2. TYPE/PRINT YOUR ANSWERS IN ENGLISH.
3. Answer the questions below for THE FACILITY UNIT LISTED BELOW
4. Be as BRIEF and CONCISE as possible.
FACILITY UNIT# FACILITY UNIT N~.ME:
SECTION 1: MITIGATION, PREVENTION, ABATEMEN~r PROCEDURES
Training procedure for prope~ mixing and handling of hazardous materials.
Training procedure for chemical spill emergency plan-. '
SECTION 2: NOTIFICATION AND EVACUATION PROCEDURES AT THIS b~IT' ONLY·
Intercom system
SECTION;S: HAZARDOUS MATERIALS FOR THIS [INIT ONLY
A, ~oos this Facility Unit contain Hazardous Materl~ls? ...... NO
If YES, see B.
If NO, continue with SECTION 4.
Are any of the hazardous materials a bona fide Trade Secret YES Q
B.
If No, complete a separate hazardous materials Inventory
form marked: NON-TRADE SECRETS ONLY (white form #4A-l)
If Yes, complete a hazardous materials inventory form marked:
TRADE SECRETS ONLY (yellow form #4A-2) in addition to the non-trade
secret form. List only the trade secrets on form 4A-2.
SECTION 4: PRIVATE FIRE PROTECTION
Fire Extinguishers
-sEcTION .5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS
North west corner of "V" St. and Golden State Ave.
SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT OXLY.
A. NAT. GAS/PROPANE~
West outside wall adjacent to "V" St.
B. ELECTRICAL:
West outside wall adjacent to "V" St.
C. WATER:
West outside wall adjacent to "V" St.
D. SPEC!AL:
E. LOCK BOX: ?ES /G IF YES, LOCATIOX:
tF YES, SITE PLANS? YES / NO MSDSs? YES ,." NO
FLOOR PLANS? YES / NO KEYS? YES / '.<0
BAKERSFIELD CITY FIRE DEPARTMENT -~
I.D. # FORM 4Avl Page 1 of 7
NON--TRADE ~ECRET9
HAZARDOUS I~IATE R I ALS I N'VENTORY
BUSINESS NAME: Banks Pest Control, Inc. O#NER NAME: Orland Banks &.William H. Rogers FACILITY UNIT #:
AODRESS: 215 Golden State Ave. ADDRESS: 4406 Knoll Dr. & 2320 Otto FACILITY UNIT NAME:
CITY, ZIP: Bakersfield~ CA 93301 CITY,ZIP: Bakersfield, CA .93308
PHONE ~: (805) 323-7858 PHONE #: (805) 399-1591 & (805) 399-1421 OFFICIAL USE IRS CODE
· 0N Y
~ 2 3 4 5 6 7 8 9 10.
tYPE MAX ANNUAL CONT USE LOCATION IN THIS ~:BY HAZARD
30DE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE
M 30 360 gal 10' 30 Storeroom South wall ' :; DURSBAN 4E PSNB
44.'4 Chlorpyrifos
55.6 'Inert Ingredients
M 96 1152 lbs 12 24 Storeroom South wall DURSBAN 50W PSNB
50 Chlorpyrifos
5~. Inert Ingredients
M 120 1440 lbs 10 30 Storeroom South wall DEMON WP PSNB
35~g Cypermethrin
64.4 Inert Ingredients
M 30 360 lbs 7 30 Storeroom South wall TALON G PSNB
0.005 Brodifacoum
~ 99~55 Inert Ingredients ·
M 25 300 gal 10 24 Storeroom South wall ~: KNOX OUT 2FM PSNB
23~0 Phosphorothioate
77.0 Inert~ Ingrediep~s
William H. Rogers TITLE: Owner S ONATURE: ~!
NAME':
DATE:
EMERGENCY CONTACT: Orland Banks TITLE: Owner - PHONE .~ BUS HOURS: 323-7858
.. ~ ..... AFTER BUS HRS: 399-1591
EMERGENCY CONTACT: William H. Rogers TITLE: Owner :' !~ PHONE/# BUS HOURS: 323-7858
'PR~N'CIPAL BUSINESS ACTIVITY: Pest Control Service & Termite Fumigation AFTER BUS' HRS: 399-1421
BAKERSFIELD CITY FIRE DEPARTMENT -'~
I.D. # FORM 4A~l Page 2 ,of '7..
NON--TRADE ~ECRETS
HAZ'ARDOUS MATERI ALS IiN~VENTORY
BUSINESS NAME: Banks Pest Control, Inc OWNER NAME: Orland Banks & William H. Rogers FACILITY UNIT #: '
ADDRESS: 215 Golden State Ave. ADDRESS: 4406 Knoll Dr & 2320 Otto FACILITY UNIT NAME:
CITY, ZIP: Bakersfield~ CA 93301 CITY,ZIP: Bakersfield, CA ~93308
PHONE ~: 323-7858 PHONE #: 399-1'591 & 399-1421 {OFFICIAL USE CFIRS CODE
tYPE MAX ANNUAL CONT USE LOCATION IN THIS ~,.BY HAZARD D.O.T
CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE OUlUE
M 2 24 gal 10' 30 Storeroom South wall ~" DIAZINON 4S PSNB
48.,7 Phosphorothioate
42-.5 Aromatic petroleum derivative solven
8.8 Inert Ingredients
M 5 60 lbs 10 30 Storeroom South wall ZP TRACKING POWDER PSNB
10 Zinc
90~ Inert Ingredients
M 10 120 lbs 10' 30 Storeroom South wall ~' ZP RODENT BAIT PSNB
'2"' Zinc Phosphide
98" Inert Ingredients
M 125 1500 lbs 04- 24 Storeroom South wall PURGE CB S-1000 PSNB
~ ~ 1.000 Resmethrin Cyclopropanecarbox~late ..
. , 0.136 Related Compdunds
1.328 Aromatic Petroleum Hydrocarbons '
97.536 Inert ..... Ingredient~ ,,,
NAME William H. Rosers TITLE: Owner S GNATURE: ~O~l~.~ ~ ~ DATE:
EMEROENCY CONTACT: 0rland Banks TITLE: Owner PHONE { HOURS: 323-785M
,. '" AFTER BUS HRS: 399-1591
~MERGENCY CONTACT: William H. Ro~ers TITLE: Owner' PHONE # BUS HOURS: 323-7858
PRINEIPAL BUSINESS ACTIVITY: Pest Control Service & Termite Fumigation AFTER BUS HR$: 399-1421
BAKERSFIELD CITY FIRE DEPARTMENT
I.D. # FORM 4A-1 Page .3 of 7.
NON--TRADE ~ECRETS
HAZARDOUS MATERI ALS I N-VENTORY
BUSINESS NAME: Banks Pest Control, Inc. OWNER NAME: Orlasd Banks &-William H. Rogers FACILITY UNIT #:
ADDRESS: 215 Golden State Ave. ADDRESS: 4406 Knoll Dr. & 2320 Otto FACILITY UNIT NAME:
CITY, ZIP: Bakersfield, CA 93301 CITY,ZIP: Bakersfield, UA 93308
PHONE ,: 323-7858. PHONE #: 399-1591 & 399-1421 OFFICIAL USE CFI~S CODE
1 2 3 4 5 6 7 8 9 10.
tYPE MAX ANNUAL CONT USE LOCATION IN THIS ,.~.BY HAZARD D.O.T
~ODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE GUIDE
M 15 180 lbs 10 30 Storeroom South wall ROZOL PSNB
...... 2-p-Chlorophenyl phenylacetyl
0.005 1,3-indandione
99 995 Inert Ingredients
M 15 180 gal 10 30 Storeroom South wall SEVIN SL PSNB
43 CarbarT1 '
57 Inert Ingredients
P 90 1080 lbs 7 30 Storeroom South wall BORID PSNB
99 Ortho Boric Acid
t Inert Ingredients
M 4 48 gal 13 30 Storeroom South wall DELTIC PSNB
· ~ 20.-7 Dioxathion
8.7! Related C~mpOunds
0.'6 Cyclohexane
65.0 {Heavy aromatic naphtha
5.~0 Inert Ingredients _
NAME William H. Rogers TITLE: Owner SIGNATURE: ~[~A~ ~~ DATE: ~-.~-~"
EMER{,ENCY CONTACT: Orland Banks TITLE: Ovzner PHONE ~ ~US HOURS: 323-7858
" AFTER BUS HRS: 399-1591
EMERGENCY CONTACT: William H. Rogers TITLE: owner .. PHONE # BUS HOURS: 323-7858
PRINCIPAL BUSINESS ACTIVITY: Pest Control Service & Termite Fumigation AFTER BUS' HRS: 399-1421
- 4A-! -
BAKERSFIELD CITY FIRE DEPARTMENT
I.D. # FORM 4A-1 Page 4 of 7
NON--TRADE ~ECRE-TS
· HAZARDOUS MATERI A. LS I N-VENTORY
BUSINESS NAME: Banks Pest Control, Inc. OWNER NAME: orland Banks &.:William H. Rogers FACILITY UNIT #:
ADDRESS: 215 Golden State Ave. ADDRESS: 4406 Knoll Dr. & 2320 Otto FACILITY UNIT NAME:
CITY, ZIP: Bakersfield~ CA 93301 CITY,ZIP: Bakersfield, CA 93308
PHONE ~: 323-7858 PHONE #: 399-1591 & 399-1421 [OFFICIAL USE CFIRS CODE
m
1 2 3 4 5 6 ? 8 9 10.
tYPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD D.O.T
~OOE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE
M 4 48 gal 13 30 Storeroom South wall PYRENONE CONCENTRATE PSNB
1 Pyrethrins
1~ Technical Piperonyl Butoxide
74' Petroleum Hydrocarbons
15 Inert Ingredients
M 45 540 lbs 04 24 Storeroom South wall PURGE III PSNB
019175 Pyrethrins
1.g50 Piperonyl Butoxide Technical
3.2-10 N-Octyl Bicycloheptene Dicarboximide
13.t20 Petroleum Distillate
B0.745 Inert Ingredients
M 30 360 gal 13' 30 Storeroom South wall HI-LIN PSNB
12.9 Lindane
78.4 Xylene
8.7 Inert Ingredients~..~
N~ME William H. Rogers TITLE: Owner SIGNATURE: "~A~'~I.9.~ ~~.li.- DATE:
EMERGENCY CONTACT: Orland Banks TITLE: Owner PHONE ~ B~ MOORS: 323-7858
., ,~ AFTER~US MRS: 399-1591
EMERGENCY CONTACT: William H. Rogers TITLE: Owner .. PHONE # BUS HOURS:., 323-7858
PRINCIPAL BUSINESS ACTIVITY: Pest Control Service & Termite'Fumigation- AFTER BUS~ HRS: 399-1591
- 4A-I - .
BAKERSFIELD CITY FIRE DEPARTMENT,
I.D. # FORM 4.A-1 Page 5 of 7
NON--TRADE ~ECRE'T'S
HAZARDOUS MATERI ALS I'N'VENTORY
BUSINESS NAME: Banks Pest Control, Inc. OWNER NAME: Orlan'd Banks &'William H. Rogers FACILITY UNIT #: .....
ADDRESS: 215 Golden State Ave. ADDRESS:4406 Knoll Dr. & 2320 Otto FACILITY UNIT NANE:
CITY, ZIP: Bakersfield, 93301 CITY,ZIP: Bakersfield, 93308
PHONE ~: 323-7858 PHONE #: 399-1591 & 399-1421 ~OFFICIAL USE CFIRS CODE
I 9N y
3 4 6 ? 8 9
FYPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD~D.0.T
~ODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE
M 5 60 lbs 12 24 Storeroom South wall FICAM PLUS PSNB
29.45 Bendiocarb
3.06 Pyrethrins
7.66 Piperonyl Butoxide, Technical
12.'25 Petroleum Distillate
47.58 Inert Ingredients
M 126 1512 lbs 04 24 Storeroom South wall PURGE CB-40 PSNB
= 0.50 Pyrethrins
1.00 Technical Piperonyl Butoxide
1.00 N-Octyl Bicycloheptene Dicarboximide
8.00 Petroleum Distillate
~ 89.50 Inert Ingredients
M 90 1080 lbs 12' 30 Storeroom South wall DIAZINON 3 DUST PSNB
3.00 Phosph0rothioate
97.00 Ine]t I~gredi~n.~
NAME' William H. Rogers TITLE: Owner SIGNATURE: DATE:
EMER~;ENCY CONTACT: Orland Banks TITLE: Owner PHONE · HOURS: 323-7858
AFTER BUS HRS: 399-1591
~MEROENCY CONTACT: William H. Rogers TITLE: Owner .. PHONE # BUS HOURS: 323-7858,
PRINCIPAL BUSINESS ACTIVITY: Pest Control Service & Termite Fumgiation AFTER BUS HRS: 399-1421
BAKERSFIELD CITY FIRE DEPARTMENT · ~' "'
I.D. # FORM 4A-t Page 7 of .7
NON--TRADE ~ECRETS "~ ~
HAZARDOUS NATERI ALS T NVENTORY
BUSINESS NAME: Banks. Pest Control, Inc. OWNER NAME: orland Banks & William H. Rogers FACILITY UNIT #:
ADDRESS: 215 Golden State Ave. ADDRESS: 4406'Khbll Dr. & 2320 OttOFACiLiTY UNIT NAME:
CITY, ZIP: Bakersfield, CA 93301 CITY,ZIP: Bakersfield, CA 93308 ,'
PHONE #: 323-7858 PHONE #: 399-1591 & 399-1421 OFFICIAL USE CFIR'S CODE
1 2 3 4 5 6 7 8. 9 10.
FYPE MAX ANNUAL CONT!USE LOCATION IN THIS .~-BY 'HAZARD D;.O.T
~ODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME 'CODE GUIDE ;
cubi -_ feet
P 1,.425 25,175 FT3 04 30 Storeroom East wall ::~ VIKANE NFLG
99 Sulfury Plouride
1 .~ Inert ..Ingredients
cubi : feet
p 4 4 FT3 04 30 Storeroom East wall .. METHYL BROMIDE NFLG
100 Methyl Bromide
P 1 1 FT3 04 30 Storeroom East wall. '~: CHLOROPICRIN NFLG
'- 99, Chloropicrin
~ i' Inert Ingredients
M 6 72 lbs 13 30 Storeroom South wall -.. .: FUMITOXIN FLSL
55 Aluminium phosphide
45 ~ Inert Ingredients
NAME William H. Ro~ers TITLE: Owner SIGNATURE: ~l~ '~~
, DATE:
EMERGENCY CONTACT: Orland Banks TITLE: Owner pHOt~E '~BUS HOURS: 323-7851
., :, -~ 7 AFTER BUS HRS: 399-1591
EMEROENCY CONTACT: Willaim H. Rogers TITLE: Own.er .. PHONE , BUS HOURS: ~"23-7858
PRINCIPAL BUSINESS ACTIVITY: Pest Control Service & Termite Fumigation AFTER BUS' HRS: 399-1421'
- 4A-1 -
BAKERSFIELD CITY FIRE DEPARTMENT ~"
[,D. # FORM 4A='! Page· 6 of '7
NON--TRADE ~ECRE:T's
HAZARDOUS I~[ATERI ALS I NV'ENTORY
BUSINESS NAME: Banks Pest Control, Inc. OMNER.NAME: Orland Banks & Willlam H. Rogers FACILITY UNIT #:
ADDRESS: 215 Golden State Ave; ADDRESS: 4406.Knp~!l Dr. & 2320 Otto FACILITY UNIT NAME: ''
cITY, ZIP: Bakersfield, CA 93301 CITY,ZIP: Bakersfield, CA 93308
PHONE #: 323-7858 PHONE #: 399-1591 & 399-1421 {OFFICIAL USE CFIRS CODE' -
I
2 4 5 6 ? 8', 9
TYPE MAX ANNUAL CONT USE LOCATION IN THIS ~ BY HAZARD D.O.T
CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE
M 12 144 gal i0- 24 Storeroom South wall .:. SAFROTIN PSNB
50' Propetamphos
- 50 Inert Ingredients
M 10 120 lbs 10' 30 Storeroom South wall ~' QUINTOX BAIT PSNB
~.0'75 Cholecalciferal
99..925 Inert Ingredients
M 55 55 gal 06 35 Storeroom West wall ~ BASE OIL C' ~(~ PSNB
100~ Petroleum Oil
M 1 6 lbs 04 ·24 Storeroom South wall --. DURSBAN PT 270 PSNB
.500 Chlorpyrif?s ..
99.500 Inert Ingredients
M 12 160 gal 10! 24 Storeroom South wall DURSBAN TC PSNB
42.0 Chlorpyrifos
~' 9.2 Xylene .Range Aromatic Solvent
"'.:. 48.8 Inert Ingredient~-~
EMEROENCY CONTACT: Orland Banks TITLE: ~er PHONE {~US ~OURS: 323-7858
., '~ '.. AFTERBUS MRS: 399-1591:
EMERGENCY CONTACT: William H. Rogers TITLE: O~er ...... PHONE { BUS HOURS:_
PRINCIPAL BUSINESS ACTIVITY: Pest Cdntrol Service & Termite Fumigation AFTER BUS HRS: 399-1421
BAKERSFIELD CITY FIRE DEPARTMENT
I~D~ # FORM 4A-3 page i of_ 3
FARM & A(~RI CULTURE
HAZARDOUS MATERI ALS INVENTORY
BUSINESS NAME: Banks Pest Control, Inc. OWNER NAME: Orland Banks & William H. Rogers FACILITY UNIT #:
ADDRESS: 215 Golden State Ave. ADDRESS: 4406 Knoll Dr. & 2320 OttOFACiLITY UNIT NAME:
CITY, ZIP: Bakersfield, CA 93301 CITY,ZIP: Bakersfield, CA 93308
PHONE #: 4805) 323-7858 PHONE #: (805) 399-1591 & (805) 399-1421 ~FF'~CIAL'USE CFiRS CODE
I
ONLY ,
1 2 3 4 5 6 7 8 [ 9 10
TYPE MAX ANNUAL CONT USE LOCATION IN TttIS -% BY HAZARD !D,O.T
CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE
M 400 4800 lbs 12 23 Storeroom South wall RONSTAR G PSNB
2.0 Oxadiazon
98.0 Inert Ingredients
M 20 240 lbs 12 23 Storeroom South wall KARMEX PSNB
80 i Diuron
I 10 TLV
10 Inert Ingredients
M 0 100 lbs 12 23 Storeroom South wall AATREX 80W PSNB
76.0 Atrazine
4.0 Related comPounds
20.0 Inert Ingredients
M 25 100 lbs 12 23 Storeroom South wall UROABOR PSNB
30 Sodium Chlorate
66.5 Sodium Methaborate ~etrahydrate _
1.5 Bromaci~ .... ~, .....
NAME: Willia---------~. Rogers .... TITLE: -- Owner SIGNATURE: L~_~¢~,,,' t~'~,]:,,~£v~ DATE: ~f.,,7~ ~--
EMER~C~,CY CONTACT: Scott Holloway -- TITi, E:~_ualified applicator ~fio'NE # '~f~S HoURs: 323-7858 ~ --
· ,, AFTER "BUS
EME~GE.N:~ CONTA"3T: Orland Banks TITLE: Owner PHONE ~ BUS ?~OURS: 323-7858
PRINCIPAL BUSINESS ACTIVITY: Pest Control service & Termite Fumigatiom AFTER BUS HRS: 399'1591
- 4A-3 -
BAKERSFIELD CITY FIRE DEPARTMENT
I.D, # FORM 4A-3 page 2 of 3_
FARM & AGRI CULTURE
HAZARDOUS MATERIALS INVENTORY
BUSINESS NAME: Banks Pest Control, Inc. OWNER NAME: Orland Banks & William H. Rogers FACILITY UNIT #:__
ADDRESS: 215 Golden State Ave. ADDRESS:4406 Knoll Dr. & 2320 Otto FACILITY UNIT NAME:
CITY~ ZIP: Bakersfield, CA 93301 CITY,ZIP: Bakersfield, CA 93308
PHONE #: (805) 323-7858 PHONE #: (805) 399-1591 & (805) 399-1421 FFICIAL USE CFIRS CODE
ONLY
1 2 3 4 5 6 ? B 9 10
TYPE MAX ANNUAL CONT USE LOCATION IN THiS ~ BY HAZARD D.O.T
q,,ODE, AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE
M 1 72 _.ga!,. 1n 23 ~toreroom South wall [ .... ROUNDUP pSNB
41.0 Isopropylamine Salt of G1yphosalt
59.0 Inert Ingredients
M 2 24 gal 10 23 Storeroom South wall SURFLAZW A.S. PSNB
59.6 Inert Ingredients
__M_ 2 24 gal 13__, 23 Storeroom South wall TRIMEC ?SNB
Dimethylamine Salt
__ 25.93 Dichlorophenoxyacetic Acid
Dimethylamine Salt
13.85 Propionic Acid
..... Dimethylamine salt of Dicamba
2.76 Dichloro-o-Anisic Acid
57.46 Inert Ingredients
M 30 360 lbs 12 23 Storeroom South wall AMIZOL PSNB
90.0 Amitrole
i0 Inert Ingredients
NAME: William H. Rogers TITLE: Owner SIGNATURE: ~\ ~,.2 ~ ~6~ DATE: ~-~
EMER~g~,CY CONTACT: Scott Holloway TITLE: qualified applicator- PHONE # B~S HOURS: 323-785B ~
~ AFTER BUS HRS: "399-47'50
EMErgENt? CONTACT: Orland Banks T!TLE: Owner ~HONE # BUS HOURS: 323-7858
PRINCIPAL BUSINESS ACTIVITY: Pest Control service & Termite Fumigation AFTER BUS HRS: 399-1591
- 4A-3 -
BAKERSFIELD CITY FIRE DEPARTMENT
I.D. # FORM 4h-3 page 3 of 3
FARM & AGRI CULTURE
HAZARDOUS MATERI ALS INVENTORY
BUSINESS NAME: Banks Pest Control, Inc. OWNER NAME: Orland Banks & William H. Rogers FACILITY UNIT #:
ADDRESS: 215 Golden State Ave. ADDRESS: 4406 Knoll Dr. & 2320 Otto FACILITY UNIT NAME:
CITY, ZIP: Bakersfield, CA 93301 CITY,ZIP: Bakersfield, CA 93308
PHONE ~:~_~805) 323-7858 PHONE #: (805) 399-1591 & (805) 399-1421 ~OFFICIAL USE CFIRS CODE
I
ONLY
1 2 3 4 5 U6E,'S 7 8 9 1 0
TYPE MAX ANNUAL ]CONT LOCATION IN THIS · BY HAZARD D,O~T
CODE AMOUNT AMOUNT UNIT[CODE [CODE FACILITY UNIT WT., CHEMICAL OR COMMON NAME CODE GUIDE
M 1 12 _~al__~13~__~_~__ Storeroom South wall DIQUAT
PSNB
35.3 Diquat dibromide
64.7 Inert Ingredients
'NAME: Will-am H. Rogers TITLE: Owner SI ;NATURE: ~.tD '~ ' ' ' ~ / ~-'0 ~
E.MER~CY COqTACT: Scott Holloway TITLE: qualified applicato~ PHONE # ~IS HOURS: 323-7858'
~ AFTER 'BUS HRS: 399-4750
EME~GENCV cONTACT: Orland Banks TITLE: Owner PHONE # BUS HOURS: 323-7858
PRINCIPAL BUSINESS ACTIVITY: Pest,Control service & Termite Fumigation, AFTER BUS HRS: 399-1591
- 4~-3 -
~ORTH SCALE:l/8,,=20' BusINEss NAME'.- Banks Pest Control, Inc. FLOOR: 1' OF 1
~ bATE:(~/.~d/~TFACILITY NAME: n/a .... UNIT *: lor 1
(CHECK ONE) SITE DIAGRAm{ X FACILIT~ DIAORA~
"
,'
I. It~O)', Al'ie~o, 11. leilromd Tr~e
Arfle ~Jl~lt ~e the 12. Fence or ~rrler
p~rt~. IM~ .~ a. Mire
~. ICofl OriL~. Culotte.
Yird Drains c. ~od
4. ~elaeee ~lt. Oi~chee, d.
Cr~a.
i3. ~rllaee
S. hi ldtMe
b. ~e~rW ~crKtl~ ia. It~r~ Ta~I:
"~ Z~nttty
c. M~ ~tmC/~ cl~f~y
b.
a. ~s 16. D~k~nl or
b. ~lectricfty , 17. ivleuitLoo Route
c. Mater 18. fvac~tJon Area:
lden~ry the
a. fi~ ey~u~l ~ployeeo
~ctl~ Weo~ S~orqe
.c. Plre S~o~t~ 30. ~oide ~ze~ouo
~mc~lm ~terlai Itorqe
d. ~i~er ~t~l Valves
for prot~ttu systems ~torlal
gee/~l
-' e. Fire ~ aa. ~ or ~zer~
biff)
~ple~ flmle Liquid -
F~ILI~ DI~ (~lr~ lt~o In addition to the s~u)
3, PirtltJNl I. Air ~ltlnlq Units
. : .... .,~:,:,~,. ~, .,,. ,, ..... .~ ......... ~ .....
kl~at M Int. ktittall
S~E: 1"-20' B~SI~SS N~: Banks Pest Control, Inc. F~R: 1. OF 1
(C~CK ONE) SI~ DIAG~ · FACILI~ DIAO~ X
¢RIgCK ONE) $ITg DIAGRAN FACILITY DIAORAN
Date APPLICATION Application No.
In conformity with provisions of pertinent ordinances, codes and/or regulations, application is rnade
by:
Name of Compan7 / ' [ Address
to display, store, install, use, operate, sell or handle materials or processes involving or creating con-
ditions deemed, hazardous to life or prol:ertv as follows:
..........
/Authorized Representative
~ ~/~/4~. ~ ............ .~~ ......................................................
Permit demed ................................................
Date Fire Marshal
RECEIVED
MAZ. MAT. D~V.
R~ ABBOTT 2700 M Street, Suite 300
Agency Director Bakersfield, CA 93301
(805) 861-3502 ,.,:; ~'c-!.,?': :_ Telephone (805) 861-3636
~VE McCA~Y '~ ' ~ .... ~ .~.
~,.~,~ R E S 0 U R C E M'~A)N'~AG .E;M~E N T A G E N C Y
DEPARTMENT J~F ENVIRONMENTAL
HeA~TH* SERViCeS
PERMIT FOR PERMANENT CLOSURE PERMIT NUMBER A 1291-15
OF UNDERGROUND HAZARDOUS
SUBSTANCES STORAGE FACILITY
FACILITY NAME/ADDRESS: OWNER(S) NAME/ADDRESS: CONTRACTOR:
Banks Pest Control Banks Pest Control McNabb Construction Co.
215 Golden State Ave. 215 Golden State Ave. 7808 Olcott Ave.
Bakersfield, CA 93301 Bakersfield, CA 93301 Bakersfield, CA 93308
, License #47433 !
Phone: 805-323-7858 Phone: 805-397-8118
PERMIT FOR CLOSURE OF PERMIT EXPIRES November 8, 1990
3 TANK(S) AT ABOVE APPROVAL DATE Auqust 8, 1990
.LOCATION APPROVED BY ~°l.,J~t~ ~ 0 (-~~,
Hazardous Mat erials ~..kcialist
............................................................................... POST ON PREMISES ................................................................................
CONDITIONS AS FOLLOWS:
1. It is the responsibility of the Permittee to obtain permi!s which may be required by other regulatory agencies prior to beginning work (i.e., City
Fire and Building Departments).
2. Permittee must nolify the tlazardous IVlaterials Management Program at (805) 861-3636 two working days rip_.cLgX to tank removal or'abandonment
in place to arrange rot required inspections(s).
3. Tank clo~ure activities must be per Kern County Environmental Ilealth and Fire Department approved methods as described in Itandbook UT-30.
4. It is the contractor's responsibility to know and adhere to all applicable laws regarding the handling, transportation or treatment of hazardous
materials.
5. The tank removal coutractor must have a qualified company em ployee on site supervising the tank removal. The employee must have tank removal
experience prior to working unsupervised.
6. ff any contractors other thaff those listed on permit and permit application are to be utilized, prior approval must be granted by the specialist
listed on the permit. Deviatiou from the 'mbmilted application is not allowed.
7. Soil Sampling:
a. Tank size less than or equal to 1,000 gallons - a minimum of two samples must be relrieved from beneath the center of the tank at depths
of approximalely Iwo feet and six feet.
b. Tank size greater than 1,000 to I0,000 gallons - a minimam of four samples must be retrieved one-third of the way in from lhe ends of
each tank at depths of approximately two t'eel and six feel.
c. Tank size greater titan 10,000 gallons - a minimum, of six samples must be rclricvcd one-fourth of thc way in front thc ends of each tank
and benealh Iht center of each tank al depths of approximately Iwo fact and six fact.
8. Soil Sampling (piping area):
A minimum of two samples must be retrieved at depths of approximat,:ly lwo feet and six feet for every 15 linear feet of pipe run and under the
dispenser area.
FOR PERMANENT CLOSURE PERMIT NUMBER A 1291-15 ' ".' ' ·
UNDERGROUND HAZARDOUS ADDENDUM ', '-: -
STORAGE FACILITY ' '~'~'" '
9.' ..Soi| Sample ana,ysis: ..'
.. ' "a. All soil samples retrieved from beneath gasoline (leaded/unleaded) tanks and appurtenances must be analyzed for benzene, toluene, xylene,
...' ... and total petroleum hydrocarbons (for gasoline). '..
b. Ali soil samples retrieved from beneath diesel tanks and appurtenances must be analyzed for total petroleum hydrocarbons (for diesel)
and benzene.. ' ." .:"." '..
c. All soil samples retrieved from beneath waste oil tanks and appurtenances must be analyzed for total organic halides, lead, oil and grease..
d. All soil samples retrieved from beneath crude oil tanks and appurtenances must be analyzed for oil and grease ....
e. Ali soil samples retrieved from beneath tanks and appurtenances that contain unknown substances must be analyzed for a full range
substances that may have been stored within the tank. . ' '...i.'i '.' ".
10. The following timelable lists pre- and post-tank removal requirements:
ACTIVITY DEADLINE 'f: ~ :',':-' ;:::."
Complete permit application submitted Al least two weeks prior to closure .'.
to Hazardous Materials Management Program
Notification to inspector listed on permit of date Two working days '
and time of closure and soil sampling
Transportation and tracking forms sent to Haza~'dous No later than 5 working days for transportation and 14 working
Materials Management Program. All hazardous waste days for the tracking form after tank: removal
manifests must be signed by the receiver of the , -
hazardous waste
Sample analysis to Hazardous Materials Management No later than 3 working days after completion of analysis
Program
i I. Purging/Inerting Conditions: """ '!''''''''-.
a. Liquid shall be pumped from tank prior to purging such that less than 8 gallons of liquid remain in tank. (CSH&SC 41700).
' ' b. Tank shall be purged through vent pipe discharging at least 10 feet above ground level. (CSH&SC 41700)
.... c.' .... No emission shall result in odors detectable at or beyc,nd property line. (Rule 419)
'"~i('?'?'"!'~:'Td.: i":- .i: No emission shall endanger the health, safety, comforl or repose of any person. (CSH&SC 41700) ' "'.."..'. ' ....
~:iT.'-'.ii;i~?.;:t"-'::,:¢..::~;?'~" Vent lines shall remain attached to tank until the inspector arrives to authorize removal.
RECOMMENDATIONS/GUIDELINES FOR REMOVAL OF UNDERGROUND STORAGE TANKS
This department is responsible for enforcing the Kern County Ordinance Code, Division 8 and state regulations pertaining to underground storage tanks.
Representatives from this department respond to job sites during tank removals to ensure that the tanks are safe to remove/close and that the overall
job performance is consistent with permit requirements, applicable laws and safety standards. '].'lie following guidelines are offered to clarify the interests
and expectations for this department.
~%z!2.'l;"i~?:'.lob site safety is one of our primary concerns. Excavations are: inherently dangerous. Il is the contractor s responsibility to know and abide by
~i~:.:~..:::c~!~.-CAL-OSHA regu[attons. The .lob foreman us responstble for the crew and any subcontractors on the .lob. As a general rule, workers are not
:";" "' permitted in improperly slOped excavations or when unsafe conditions exist in the hole. Tools and equipment are to b~ used only for their designed
function. For example, backhoe buckets are never substituted for ladders.
2. Properly licensed contractors are assumed to understand the requirements of the permit issued. The job foreman is responsible for knowing and
abiding bY the conditions of ~the permit. Deviation from the permit conditions may result in a stop-work order.
~.'.-,3. '..'Individual contraclors will be held responsible for their post.-removal paperwork. Tracking forms, hazardous waste manifests and analyses
".'":' documentation are necessary for each site in order to close a case file or move it into mitigation. When contractors do not follow through on
. ' necessary paff, r~an unmanageable backlog of incomplete cases results. If this continues, processing time for completing new closures will
Accepted By: {~__._~ . ~
O W D3dF E
NlJl~, OP, AGENT
MD:ch
driggs\ 1291-15.pta
~?oo~we, s~,ee! KERN COUNTY HEALTH DEPARTMENT H~^ff" OFFIC£.
Bakersfield. Callfofnl,, 93305 Leon ~ Hobert~o~. ~ .??:: :'~ ': .
Telephone (805) 861-3638 ENVIRCNMENTAL HEAL~ OlVISIO~ '. ' ·
~~~~ DIRE~OR OF EN~,ONME~A~ ,~L~ ' ,~.
Vernon'S. Relchard - ;,'~.~ -~.~. '.
..... ~..;~.~: ~.-~'~ ~..
. ,.
~~~acllltyAddre ss ~ Na~e' ~ l ~_ ~-[~ ' ~~ ~ ~~ ~ ~ ~ ' ~ ~~ Kern ~ County.,~,---_ -- / '~'~/~ ;.~ Permit .......' . '...': /~"~" ~ ....' .. · ".'>:'"' ::'-.....':"'":"~:""~:":~-~.,":'"~' ,'-..=:~.,,...' :'"':'" .... ,...:., ..... ...-'"'" .'
"'
. ....,':.... ~..?,
' * UNDERGROUND TAN]~ DISPOSITION T~CKING RECORD'~ ~ '"~""
.~ .. · .~r
Thla for~ 1~ to b~ returned to the Kern Countg ~oalth Depa~t~nt:~lthln'
~ of aeeoptanee of tank{s) by disposal o~
holder o~ the per, It ~lth nu~be~ noted above la reapon~lble
that thta for~.t~ co~ploted and returned. ' .~.
~ ' . .5: :'.' ¢.~ ·
Se,tton 1 - T~ b~ ~tlle~ out ~ tank re~noval .: ..
Tank RemovaJ ~acto~:
Add~ess Phone ~
~ ZIp "'
Dat~ Tanks Removed '' ~'~0'.~: of Tanks'~ ......'~:
Tank "Decontamination" Contractor . · :--~'.~:,'~:.-- -
Addre~ " "' ; ' " Phone ~ ·
representative ~ contractor certifies b~ ,t~nln~ be'lo~ tha~.~'.":'.~{
t~nk(~) have been deconta~tna~:ed tn accordance ~tth ~e~n Count~
~opa~t~ent requirements. . ~ .. ..... ....'?~."~:'~.;'...~"~'.,,.. ~., . .
'.. ..
. . . :' .. -. ?:.~;~:?:.~'::~: ,".
. ..... ? ~ ..... ~ .-.
, ..
' . '~"' ~ ~" '.' "~7,' ~.~-r: ~ .2.
Section ~ -T~ b~ ~llled out .and sl~ned ~ a2 authorized gepresentattve
treatment, storage, o~ disposal faelltt~ aeee~tln~ tank(s):, :....;
. . ..' .:: · ..: :.- :~;~i:~;~.~,,.,. ~ .
- . · y ,.'. /.. ~ -,.,.}~,;.~,..~:? ..
Facility Name ~ · .' ..", ."-'.-,,~-,:-:'.',-,'.:,'..
· ,
Address Phone ~ '
....... .
ZIp " ' ~"
. .., , ..... ~, ,.?~'~;?U?.'.
Date Tanks Received No. of Tanks ..' '"'
Signature Title · : ...:~':...,' .:: :." :-:¥~i{~.~.~:.:.
........... .:.:.,.,,~:~, :~ ...
. . , ~.,... .... .
(Authorized Representative) . ..: ...' ..'..:..-"297~i~.:'..'.'".'
'
· * ~IBI~G I~STR~CTI0~S: Fold fn half and staple. Postage and
lnbol hnve alreadg been a~ftxed to outside fo~ you~
..,~ '.'.2~ . ,
~.~ ..~- ~..):~..
DISTBICT OFFICES
m plot. MATERIAL SAFETY DATA : [ 104_9
IECllON i. INOENTIIqCATION DATE: "08/31/84
~ J.R. Stmplot Company -' *
wi 16777 S. Howland Rd., P. 0. Box 198 I
^oon~m~ Lathrop, CA 95330 COMMONN^M'*
~'"GE'CV ~'ONE'~: (Z09) 858-2511 C,~M,CAL ~ HerbiCide'
C.EMTRE~ (800) 424'9300
,.IE~noH., I. IHIPPING DATA ......
8HIPPING NAIdE: Hot regulat~ by D.0.T. c**~ NUU.~ -
H~RD ~ None o.o.T. NUM8~ None
RE~RTABLE QUA~ (ilO): None HX~nOOUS W~TE ~.: D002
~8ELS .EOUIAE~ None ~P.~ REGiST~ NO.:
~n~ None
SECTION ~. HAZARDOUS INGREDIENTS
J CHEMICAL, NAME AND SYNONYMS CHEMICAL FORMULA WT.~ TLV LDN'
1' Sodium Chlorate NaC103 30 NE 2700
Sodium Metaborate Tetrahydrate NazB204. 41420 66.5
(5-bromo-3- seC. butyl -6-methyl uract 1 ) C9H 13B tN202 1.5
Bromact I
'ORAl. LD-50. ag/kg, male mt
SECTION 4. PHYSICAL PROPERTIES
BOlUNG ~OINT:N/A: ' .... 8OLUBIUTY IN WATER: )' 2 lbs/gal @ 68°F
DeNsn~: 54 1 bs/ft3 ~ VOLAnLES (my VOLUMe: 0
AP~Ju~"c~' Off white, odorl ess VAPOR PRESSURE. mm Hg: N/A
. granular soltd~
FU~H ~OiN~. N/A , ' -' !;:' HAZARO mATING (NFPA). , · ;"".', · ,:..,.v..- .-:
,,.. ..,, ,..
.~ACn0N:~' WAT~ None '-i::. ~ ::'?.-,' ' ' : :: .
~X~NGUm",.G.ED,. Flood' With ::water., .
.- . . ,
FORM L-lO (Rev. 3/83) .
:
! RE(]IST,~T,O..O. 10659--005!--AA D*TE,.UE~ 08/31/84
SECTION $ -- HEALTH HA~RD DATA
Acute oral LDso (~ats) 2330-2700 mg/Kq. Fam Ch~tcals Hand.ok, 1078 2700 mg/Kg. D,
17g, 1~78
~KIN ABSORPTION
Dermal LDso (Rabbit): Greater than 1(I g/Kg.
·KIN CONTACT
Moderate skin irritant.
EYE CONTACT
Moderate eye Irritant. .
EFFECTS OF OVEROO~E
Dust may irritate eyes, skin and mucous membranes. Ingestion of large quantities might
prove fatal with symptoms of gastritis. Abdominal pains, nausea, diarrhea, vomiting,
cyanosts and collapse. May cause methemoglobtnemia and a late toxic nephritis.
EM~OENCY AND FIRST AID PRO~EOL/RU
Eyes - Flush with stream of water for 15 minutes and get medical attention.
Skin - Wash with large quantities of soap and water.
Ingestion - Dilute by drinking soapy water to induce vomiting. Get medical attention.
Gastric lavage followed by saline cathorsis. Test for methemoglobinemia and treat.
.Hemodiolysis is recommended for removal of chlorates.
SECTION ~ -- PERSONAL PROTECTION DATA
VE~I~ON
General room ventilation plus special exhaust at points of dust emission. Systems
should discharge through a water scrubber.
RE.at. TORY ~O~CllON
Oust mask where appropriate.
PROTECTIVE CLO~ING
Washable head covering, cotten coveralls laundered datly; rubber gloves and rubber
footwear.
EYE PROTECTION
Chemical safety glasses.
O~
Safety shower and eye wash fountain.
MATERIAL SAFETY DATA ~ 1049
~°e ~ ' Ureabor
BETON ? -- FIRE AND EXPLOSION H~RD DATA ......
A~OIGNm~TEmE~mRI NO~ Combustible ~..v~u.e Not ~ppltcable
~UISHI~
Flood wtth water. Sodt~ Chlorate gecomposes at'570°F and suppltes 1ts own oxygen,
hence s~thertng type ftre exttngutsl~tng agents are no~.effectJve.
App~ach upwind fr~ fire. Evacuate people do~nwtnd f~ ftre. ~ear self-contained
b~athlng apparatus.
UMJ~UX~ MI AND EXPLO~ON
Sodium Hetaborate ts aftre retardant. Sodt~ Chlorate ts a st~ng °xtdtztng agent and
ts an extr~ ft~ & explosion hazard when tn con.ct wtth organics, actd paper, otl,
or solvents.
~E~ON I -- R~C~Y~ DATA
~T~U~ (~ ~~) ~~ T,0 AV~
Heat, uncont~lled contact wtth strong actds, organics, ch~tcals,
(x],T~ ( )~Ma phosphorus, sulfur, sulfides, po~dered metals, a~nJum co~ounds,
organtc mattera carbon~ etc. ..
~*~w(~auTO*VO~m Sodium Chlorate can react violently ~th strong actds, organic
subs~nces, sulfur and sulfides, po~de~d ~tals, phosphorous, a~ontum compounds.
Oecomoosed by h~oh t~Oerature. .
Oxygen and possJble unstable chlorine dJoxJde which decomposes spontaneously to
chlorine.
~W ~I~ C~OI~ TO AVCO
SE~ON 9 -- ENVIRONME~AL PROLCON ~A~, ,
~IR~M~TAL
Toxic to fish. Low toxicity to wildlife.
~ TO lie TAKEN IN C,A.lir MATEI~IAL IS RELEASED OR ~PIt. LED
Sweep up or vacuum in a dry state on ~ood floors. Sweep up or vacuum, then flush with
water on concrete or metal floors. R~.~nove contaminated clothing at once and wash
before reusing:
Make a slurry using water and blend with bisulfites or Ferrous salts and sulfuric acid.
Neutralize with soda or muriattc acid,, Bury in state approved toxic waste disposal
landfill site.
SECT1ON 10 -- HANOUNG AND STORAGE PRECAUTIONS
PI~CU)JJTK~TOMTAXENINHANOUN(]^NOSTOI~IN(]
(See page 4)
Store Jn cool, dry, fire resistant area; separate from acid, solvents, oils, organic
substances, sulfur, sulfides, powdered metals, aneontum salts, etc. and away from fire
hazards. 0o not store on wood floors.
Not regulated by D.0.T. ° None
.(ou,aeo (,,.OT U~.~'"INone requt red
3
,%** Si plot MATERIAL SAFETY DATA !, 1049
SUPPLEMENT
SECTXON 10: Precautions to be taken in handling and storing.
Ureabor is especially formulated to ;;tntmtze fire and'explosion hazard.
Avoid direct contact with floor and ,=tsture. Store on pallets or skids.
For either granular or spray equipment, cleaning equipment before the application
is a must. After application, clean thoroughly using household ammonia in the
sprayer followed by multiple clean water rinsings.
:,,:'. i ;-IVIonsan[o MATERIAL SAFETY DATA Page l of 6
MONSANTO COMPANY
~' .... ~ 800 N. LINDBERGH BLVD.
MONSANTO PRODUCT NAME ST. LOUIS, MO 63167
Emergency Phone No.
ROUNDUP® HERBICIDE (ca. Collect).
314-694-4000
PRODUCT IDENTIFICATION
Synonyms: None.
Chemical Name: Not Applicabl,e. Formulated Product
Active Ingredient: *lsopropylamine salt of glyphosate .......................................... 41.0%
Inert Ingredients: ............................................................................................. . .... 59.0%
. 100.0%
*Contains 480 g~ms per liter or 4 pounds of the active Ingredient isopropylarnine" ,,
salt of N.(phosp~onomethyl) glycine per U.S. gallon. Equivalent to 356 grams per
liter or 3 pounds per U.S. gallon of the acid, glyphosate.
CAS Reg. No.: Not Applicable, Formulated Product
CAS Reg. No.
Active Ingredient: 38641-94-0
EPA Reg. No.: 524-308
DOT Proper Shipping
Name: Not Applicable
DOT Hazard Class/
I.D. No.: NOt Applicable
. DOT' Label: 'NOt*' Applicable
Reportable.QUantity (RQ) . ., ' ...
. Under,Clean Water Act: Not Applicable
U.s. ' surfaca Freightr ~
Classification: .. '.. .,. Weed Killing Compound, N.O.I.B.N.
The substance, listed below is Identified as a hazardous chemical under the critedalOf the ,OSHA
.... Hazard,,CommuniCation standard (29 CFR I S~10.1200): -' - -.
Keep out'of.reach of'children, -". , ' ", ...... ~,~ .
WARNING! :.: .... " ..- .. '
CAUSES EYE'iRRITATION
"'~ HARMFUL IF SWALLOWED .
*MAY CAUSE SKIN'IRRITATION ,.,
.i~'' '-NOT FOR ,REFORMULATION OR REPACKAGING '.. '"
"'~ .l: /IO San[o MATERIAL SAFETY DATA Page 2 of 6
" PRECAUTIONARY MEASURES
Do not get in eyes, on skin or on clothing.
Wash thoroughly after handling.
Avoid direct applications to any body of water. Do not contaminate water by disposal of waste or cleaning
of equipment.
EMERGENCY AND FIRST AID PROCEDURES
FIRST AID: IF IN EYES, immediately flush with plenty of water for at least 15 minutes. Call a physician.
IF ON SKIN, immediately flush with plenty of water. Remove contaminated clothing. Wash clothing before
reuse.
IF SWALLOWED, this product will cause 9astrointestinal tract irritation. Immediately dilute by swallowin9
water or milk. Call a physician.
OCCUPATIONAL CONTROL PROCEDURES
Eye Protection: Wear chemical splash goggles during mixing/pouring operations or other activities
in which eye contact with undiluted Roundup® herbicide is likely to occur.
Skin Protection: In cases in which prollonged or repeated skin contact with Roundup herbicide
may occur, long-sleeved sl~irt, long pants, and chemical protective (e.g. rubber)
gloves are recommended. * Wash hands and contaminated skin after handling.
Clothing soaked with Roundup solution should be promptly removed and
laundered before reuse..
Respiratory
Protection: Respiratory protection should not be required for normal use and handling. During
pedods of abnormal exposure to heavy spray or mist, use of NIOSH/MSHA
approved equipment for pesticide vapor/mist is recommended. The respirator use
limitations specified by NIOSH/MSHA or the manufacturer must be observed.
Ventilation: No specials precautions are recommended.
Airborne Exposure
Limits: Product: Roundup Herbicide - 100% by wt.
OSHA PEL: No,ne established
ACGIH TLV: Ne,ne established
Surfactant ingredient: Approx. 15% by wt.
OSHA PEL: None established
ACGIH TLV: None established
FIRE PROTECTION INFORMATION
Flash Point: ~200°F. Method: Tag Closed Cup
Extinguishing Media: Water spray, foam, dry chemical or CO2 or any Class B extinguishing agent.
Special Fireflghting
Procedures: Fireflghters and others who may be exposed to vapors or products of
combustion should wear a self-contained breathing apparatus and full
protective clothing. Equipment should be thoroughly cleaned after use.
Unusual Fire and
Explosion Hazards: None.
"IVIOriSa~'[o MATERIAL SAFETY DATA Page 3 of 6
" REACTIVITY DATA
Stability: Stable for at least 5 years under normal conditions of warehouse
storage. Heated facilities are not required.
Incompatibility: This product and spray solutions of this product should be mixed,
stored and applied only in stainless steel, aluminum, fiberglass, plastic
and plastic lined containers.
DO NOT MIX, STORE OR APPLY THIS PRODUCT OR SPRAY
SOLUTIONS OF THIS PRODUCT IN GALVANIZED OR UNLINED
STEEL (EXCEPT STAINLESS STEEL) CONTAINERS OR SPRAY
TANKS. This product or spray solutions of this product react with such
containers and tanks to produce hydrogen gas which may form a highly
combustible gas mixture. This gas mixture could flash or explode,
causing sedous personal injury, if ignited by open flame, spark, welder's
torch, lighted cigarette or other ignition source.
Hazardous Decomposition
Products: None.
Hazardous Polymerization: Does not occur. This product can react with caustic (basic) materials to
liberate heat. This is not a polymerization but rather a chemical ~'
neutralization in an acid-base reaction. ~
HEALTH EFFECTS SUMMARY m
The following information presents both human experience and the results of scientific experiments used by
qualified experts to assess the effects of Roundup herbicide on the health of exposed individuals and to
support the Precautionary Statements and Occupational Control Procedures recommended in this
document. To avoid misunderstanding, the data~ provided in this section should be interpreted by individuals
trained in evaluation of this type of information.
Human Experience
Dermal contact and inhalation are expected to I:)e the primary routes of occupational exposure to Roundup
herbicide. Direct contact with this material may cause temporary eye irritation and conjunctivitis. Prolonged
contact with Roundup herbicide may cause dermal irritation. Ingestion of Roundup herbicide has been
reported to produce gastrointestinal discomfort, nausea, vomiting and diarrhea.
Toxicological Data
Data from Monsanto studies indicate the following:
Oral LDso (Rat): 5,400 mg/kg, Practically Nontoxic
Dermal LD5o (Rabbit): >5,000 mg/kg, Practically Nontoxic
Eye Irritation (Rabbit, 24-hr): (FHSA) Score = 4.1 on a scale of 110.0, Slightly Irritating
Skin Irritation (Rabbit, 24-hr): (FHSA) Score = 4.3 on a scale of 8.0, Moderately Irritating
DOT Skin Irritation (Rabbit, 4-hr): Not Corrosive
Inhalation LCso (Rat, 4-hr): 3.18 mg/I (analytical concentration), Slightly Toxic
Patch testing of 50 human volunteers with Roundup herbicide at use concentration and 5X use
concentration produced no positive reactions folllowing initial application, any of 15 repeated applications in
the induction phase, or on subsequent challenge 2 weeks later. Roundup herbicide is not considered a
primary irritant or a sensitizing agent.
Patch testing of guinea pigs with Roundup herbicide produced essentially no irritation following initial
application; mild to moderate erythema (redness), edema (swelling) and/or mild necrosis (tissue damage)
.... were observed in some animals during subsequent repeated exposures in the induction phase. On
challenge, no dermal response was observed in any of the animals. Roundup herbicide is not considered a
dermal sensitizing agent in guinea pigs.
(Health Effects Summary Continued On Next Page)
,.Monsanto MATERIAL SAFETY DATA Page 4 of 6
HEALTH EFFECTS SUMMARY (Continued)
Single male and female dogs were orally administered Roundup herbicide or a 2 percent aqueous solution
of Roundup herbicide at dosages ranging from 0.3125 to 5.0 mi/kg. No mortality and no inhibition of plasma
acetylcholinesterase activity were reported. The most common effects observed were vomiting and
diarrhea, which occurred shortly after dosing.
A series of 21-day dermal toxicity studies have been conducted in which Roundup herbicide was applied to
the skin of male rabbits 6 hours per day, 5 days per week .at various concentrations. At 5 times the
intended use concentration, severe dermal irritation and systemic toxicity (mortality, reduced food
consumption, body weight loss, and testicular effects) were observed. Rabbits treated with 3 times the
intended use concentration and below, or only with the active ingredient glyphosate, exhibited only slight to ·
moderate local irritation and had no signs of systemic effects. When the surfactant in Roundup formulation
was tested, marked irritation and systemic effects were observed which were similar to those seen with the
higher concentration of Roundup. Effects observed in these studies are considered~ to be a secondary
response to the stress of severe dermal irritation, to which rabbits are particularly sensitive, rather than the
result of direct systemic toxicity.
Rats were exposed by inhalation to aerosol concentrations of 0.05, 0.16 and 0.36 mg of a 33.3% Roundup
solution per liter air 6 hours/day, 5 days/week for a total of 22 exposures over a 4 week period. Minor nasal
irritation was observed in female animals. No adverse hematologic, biochemical or systemic histopathologi¢
effects were noted. The systemic no-effect level was considered to be 0.36 mg of a 33.3% Roundup
solution per liter of air.
Following a 24-hr topical application of Roundup herbicide to the abdomen of rhesus monkeys,
approximately 1.8 percent of the administered dose of the active ingredient (glyphosate) was systemically
absorbed. Excretion in the urine was the major route of elimination following systemic absorption.
ComPonents
O['lSa [O MATERIAL SAFETY DATA Page 3 of 6
REACTIVITY DATA ------
Stable for at least 5 years under normal conditions of warehouse
Stability: storage. Heated facilities are not required.
Incompatibility: This product and spray solutions of this product should be mixed,
stored and applied only in stainless steel, aluminum, fiberglass, plastic
and plastic lined containers.
DO NOT MIX, STORE OR APPLY THIS PRODUCT OR SPRAY
SOLUTIONS OF THIS PRODUCT IN GALVANIZED OR UNLINED
STEEL (EXCEPT STAINLESS STEEL) CONTAINERS OR SPRAY
TANKS. This product or spray solutions of this product react with such
containers and tanks to produce hydrogen gas which may form a highly
combustible gas mixture. This gas mixture could flash or explode,
causing serious personal injury, if ignited by open flame, spark, welder's
torch, lighted cigarette or other ignition source.
Hazardous Decomposition
Products: None.
Hazardous Polymerization: Does not occur. This product can react with caustic (,basic) materials to
liberate heat. This is not a polymerization but rather a chemical
neutralization irt an acid-base reaction.
m
HEALTH EFFECTS SUMMAR_Y
The following information presents both hu---man experience and the results of scientific experiments used-~"'~ .~.
......... ,,-- ..~,.,,,,,o ,..,t I::lnundua herbicide on the health of exposed indivi.cl.ua!s .and.,_t,o_ J~
· " tVlonsallto MATERIAL SAFETY DATA Page 5 of 6
SPILL, LEAK & DISPOSAL INFORMATION
Spill/Leak:
Observe all protective and safety precautions including use of rubber boots or rubber overshoes when
cleaning up spills m See Occupational Control Procedures.
Liquid spills on floor or other impervious surfaces should be contained or diked, and should be absorbed
with attapulgite, bentonite or other absorbent clays (kitty litter, etc.) Collect contaminated absorbent, place
in plastic lined metal drum and dispose of irt accordance with instructions provided under DISPOSAL.
Thoroughly scrub floor or other impervious surfaces with a strong industrial type detergent solution and
rinse with water.
Liquid spills that soak into the ground should be dug-up, placed in plastic lined metal drums and
disposed of in accordance with instructions provided under DISPOSAL.
Leaking containers should be separated fromm non-leakers and either the container or its contents
transferred to a plastic lined drum or other non-leaking container and disposed of in accordance with
instructions provided under DISPOSAL. Any recovered spilled liquid should be similarly collected and
disposed of;
Do not contaminate water, foodstuffs, seed or feed by stOrage and disposal. ...,
.Disposal:
Materials resulting from the use of this product, should be used according to label instructions if possible.
Wastes that cannot be used or chemically reprocessed should be disposed of in a landfill approved for
pesticide disposal or buried on site in a safe place so that it will not contaminate water supplies. All disposal
should be in accordance with applicable Federal, State or local procedures.
Emptied container retains vapor and product ,residue. Observe all labeled safeguards until container is
cleaned, reconditioned or destroyed. DO NOT CUT OR WELD ON OR NEAR THIS CONTAINER.
Metal Drums and Cans: Triple rinse container. Then offer for recycling or reconditioning, or puncture
and dispose of in a Sanitary landfill, or by other procedures approved by
state and local authorities.
Plastic Containers: Do not reuse container. Triple rinse container then puncture and dispose
of in a sanitary landfill, or by other procedures approved by state and
local authorities. Plastic may be burned or incinerated if permissible
under state and local rules. If burned, stay out of smoke.
Bulk: Triple rinse emptied bulk containers. Then offer for recycling or recondi-
tioning or disposal in a manner approved by state and local authorities.
ADDITIONAL COMMENTS
Environmental Toxicity Information:
Oral LDso Goat: 4,860 mg/kg, Slightly Toxic
48-hr LD5o Honeybee: > 100 p.g/bee, Practically Nontoxic
48-hr ECso Daphnia magna
(With Aeration): 37 rog/I, Slightly Toxic
48-hr ECso Daphnia magna
(Without Aeration): 24 rog/l, Slightly Toxic
48-hr ECso Garnmarus pseudolirnnaeus: 42 mg/I, Slightly Toxic
..., 96-hr TL~ Carp: 19.7 ppm, Slightly Toxic
96-hr LCso Bluegill sunfish (Static): 14 rog/I, Slightly Toxic
(Additional Comments Continued On Next Page)
'i lonsanto
MATERIAL SAFETY DATA Page 6 of'6
ADDITIONAL COMMENTS (Contirlued)
98-hr LC5o Bluegill sunfish
(Flow-Through): 5.8 mg/I, Moderately Toxic
96-hr LCso Rainbow trout (Static): 22 mg/I, Slightly Toxic I~
96-hr LCso Rainbow trout
(Flow-Through): 8.2 mg/I, Moderately Toxic
96-hr LCso Channel catfish: 16 mg/I, Slightly Toxic
96-hr LCso Fathead Minnow: 9.4 mg/I, Moderately Toxic
96-hr LCso Crayfish: >1,000 ppm, Practically Nontoxic
Carp contained in a static pond were unaffected at any time during a 90-day observation podod following
exposure by aedal application of Roundup herbicide at the normal use concentration. Tissue residue
analyses indicated that glyphosate, the active ingredient in Roundup herbicide, will not bioaccumulate.
Immersion of chicken eggs at four different embryo ages (0, 6, 12 and 18 days) for about five seconds in 1
or 5% volNol Roundup in water solutions was reported to have no adverse effects on the hatchability or
time to hatch of the eggs.
DATE: November, 1985 SUPERSEDES: March, 1982
MSDS NO.: M00007588
FOR ADDITIONAL NON-EMERGENCY INFORMATION, CALL: 314-694-4000
Ltl
LL Although the Information and recommendations set forth herein (hereinafter "informatto~") are presented In good faith and believed to be
correct as of the date hereof, Monsanto Company makes no representations es to the completeness or accuracy thereof. Information Is
the condition Itmt the will make their determination to its Ior their prior to
supplied
persons
r~c~lving
suitability
purposes
...J use. In no evanl will Monsanto Company be responsible tor damages o! any nature whatsoever resutting trom the t~e ol or re~ance upon
Information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
P^RTICULAR PURPOSE OR OF ^NV OTHER N~URE ~E MA~E .EREUNDER W~T. RESPECT TO ~NFORM~T~ON OR THE
LU PRODU._____C[TO WHICH ~NFORM^TIOH?.__~EFERS~.
ROUNDUP· I~ a registered trademark ot Mon~anlo Company.
Safety Data Sheet
ENERGENCY TELEPHONE NO. CIBA-GEIGY
1-800-33~,-97q8 A~R[C.LTURAC 01VISION
NORTH CAROLINA , P.O. Box 18~00
LCALL 91gr292-7100) ~ GREEmSBORO, NC ' 27q19
TRADE NAME AAtrex®8OW '
SYNONYMS Atra-zine
00T CLA$$[FICAT[0N Not applicable~ No label or placard required.
B/L Freight Classification= Compound, Weed Killing (Herbicides)
EPA SIGNAL WORD CAUTIO~r
[. ACTIVE INGREDIE~T~
HATER[AL OR COMPONENT .~. .' · ,, CAS NUMBER
: 6-isopropylamino-s-triazine 76.0 1912-24-9
Related Compounds 4.0
Inert Ingredients 20.0 '
-AATRF. X 80W- 2
II. PHYSICAL PROPERTY DATA
' PHYSICAl, STATE~ GreYish brown powder
Flash Point
(Test Method} ~ Not applicable
Autoignition
Temperature~ Not applicable
Melting Point~ 175-177'C ('.active in, gredient)
Vapor Pressure~ 4 X 10-7 nun Hg @ 20'C
Solubility in H20, % by Wt.~ Technical: 33 ppm @ 20'C ':..
Evaporation Rate (Butylacet'.ate-1) ~ Not applicable
.~0iling Point, 760 mm Hg: Not applicable
Specific Gravity (H20-~.)~ 1.19 g/cm3 @ 20°C' (activ~
·
Vapor Density (Air - 1) ~ . Not appl.icable
% Volatiles by Vol.~'. Not applicable
Odor: None
III. HEALTH HAZARD INFORMATION
EFFECTS OF OVEREXPOSURE~
Irritation of eyes, skin, .nose or ithroat may occur'~from -.
'overexpOsure to AAtrexe 80W. A.skin sensitization ,reaction
may occUr.~'in, sensitive individualS. Ingestion may cause
nausea,· vomiting or diarrhea... ·
Long-term!exPOSure to:"l&w leVels,of the material isn°tknown·
to causeb:any .ill-.'effects :in.'humans. ' : '-" ·
iThe',LD~"o:'-('~D..-"'lethal .dose)..'is the'amount 'of a Substance.that
will kflI:'.~O '.~rcen~ of a group off exposed animals. :-This
does-not mean ::tha~ the other half of the animals a=e fn'..~oo~
~ -AATR;EX 80W- 3
The LC$o (LC - lethal concentration) is the concentration of
the substance in air which will kill half ofa group of ex-
posed anima, ls in a stated length of time. Again, this does
not mean that the other~half of the animals ar~-~n good
health. ..
There will be signs of poisoning at lower exposure level~
than the LD50 s or LCs0'S.
The degrees of toxicities are defined in this chart*.
Vapor ~
Exposure Probable
(4 Hr. Dose
Degree of Oral LDs0 Inhalation) Dermal LD_~0 That Would
Toxicity for Rats for Rats for Rabbi£s Kill Man ':"
Highly Less than Less than Less than I teaspoon
toxic 50 mg/kg 0.2 mg/L 200 mg/kg
Moderately 50 to 0.2 to 2.0 200-2,000 1 tablespoon
toxic 500 mg/kg mg,{L mg/kg to 1 cup
Slightly Greater .~reatc~r Greater 1 pint' to
toxic than .~han . than 1 quart
500 mg/kg! 2.0 mg/L 2.'~000 mg/kg
Ways that exposure can occur=
SWALLOWING~ - [Acute Oral LDo0 (rat) ~ 5,100 ~g/kg] -
Slightly toxicl Studies with rats have shown
that 50% of the animals can be killed by a
single swallowed amount of 5,].00 milligrams
per kilogr~ of body weight.
SKIN - [Acute Dermal LDo0 (rabbit) - 9,300 mg/kg] -
~ Slightly to~:ic o~-absorption through the
skin.
- Minimally irritating to the skin. Studies
with rabbits have shown slight skin swelling '"
and redness occurred after exposure for 24
hours.
*AIHA Quart. 15 (2)June, 1954.
-' .; , -AATR]~X 80W- 4
- StUdieS in guinea pigs with atrazine
· technical, the active ingredient in
AAtrex 80W, ,produced a skin sensitizing
. _ reaction.{= ....
EYES: - Mildly irritating on contact. Studies with
rabbits have shown redness and swelling of the
eyelids can occur.
INHALATION: - [Acute Inhalation LCs0 (rat) = 2.0 mg/L -
] hour] '- Moderately-£oxic.
IV. FIRST AID PROCEDU~S
If ~ison~ng ~s suspected, do not wa~t for symptoms to de-
velop. I~ed~ate~y ~g~n the recommended procedures below.
Contact a physician, or the nearest hospital or the nearest
Poison Control Center. Tell the person ~ntacted of the type
and amount of exposure, describe the s~ptoms and follow the
~ advice given. For additional information, call day or night
~IBA-GEIGY Corporation (800)334-9748 or (919)292-7100.
INGESTION .~.
If victim is fully conscious, f~ediately give large quanti-
ties of water and induce vomiting..... Never give anything by
mouth to an unconscibus person. Call a physician or the
nearest Poison Control Center f~ediately.
SKIN CONTACT ~.
· ; Immediately remOve. contaminated clothing, wiping -away. exceSs~
-~ material' from the '..skin. WaSh with plenty of .soap and water...'
· ..- ~ not-attempt' to'neutralize with chemical agents' If irri~
· ration -Occurs, .obtain medical advice. ' ' '.
'z e i ei ..flush the eyes with large~ amounts of running~
~water:'fOr~a..minimUm of 15 minutes...Hold the eyelids apart
~' minated atmosphere~r:. If s pt°ms appear or
-AATREX 80W- 5
NOTES TO PHYSICIAN
AAtrex 80W is a triazine herbicide.
- If a large amount has b~en ingested and vomiting, ha§ not -
occurred, induce emesis or lavage stomach. Give a suitable
saline laxative and supportive therapy.
V. HANDLING INFORMATION
INGESTION
All food must be kept in a separate area away from the
storage/use location. Eating, drinking and smoking should be
prevented in areas where there is a potential for exposure to
this material.
SKIN CONTACT
Skin contact with the powder should be prevented through the
' use of rubber gloves and clothing consistent with good pest-
~icide handling practice.
EYE CONTACT ~, ,.
Eye contact with the '~owder should be'avoided thro,ugh the use
of chemical safety glasses or goggtes.
INHALATION
This material should be handled in a well ventilated area.
Where adequate ventilation is not available and exposure to
excessive dust could occur., wear a Conflo II (MSA) or other
approved pesticide respirator.
VI. FIRE HAZARD
This is not a combustible material.
There is a possible dust explosion hazard.
HAZARDOUS DECOMPOSITION PRODUCTS
None
EXTINGUISHING MEDIA
-As in any fire, prevent human exposure to fire, smoke, fumes
or products of combustion. Evacuate nonessential personnel
from the area.
-AATREX 80W- 6
Use standard organic chemical firefighting techniques in
extinguishing fires involving this material --use dry chem-
icals, foam or carbon dioxide. Use of contaminated build-
.' ings, area and equipmerNt must be prevented until they are
properly decontaminated.
VII. SPILL OR LEAK PROCEDURES
Make sure all personnel involved in spill cleanup follow good
industrial hygiene practic.~s (refer to Section V).
Small spills can be handled routinely. Sweep up the material
and place in an appropriate chemica~ waste container. Seal
.' container and dispose of in an approved landfill. Wash the
spill area with water containing a strong detergent. Flush
the spill area with water Ilo remove any residue. Do not
allow wash water to contaminate water supply. ~"
Do not reuse container.
~isposal of material, spill residues and containers must be
by methods consistent with local, state and federal~health
and environmental reguAations.
IN CASE OF E~ERGENCY, CALL .DAY OR NIGHT
(800~24-9300 (CHEMTREC)
VIII. STORAGE REQUIREMENTS
Keep this material out of the reach of childreh.
Containers must be stored in a cool, dry, well ventilated
area. Store away from foodstuffs. .
The information and recommendations contained herein are based upon
data believed to be correct. However, no guarantee or warranty of
any kind expressed or implied*is made .with respect to the informa-
tion contained herein.
....' 'ATERIAL SAFETY DATA SHEET
FOR
KARMEX~ WEED KILLER
MANUFACTU.~ER: E. I. DU PONT DE NEMOURS'& CO. (INC.)
BIOCHEMICALS ~~u~
WILMI.-'~GTON, DE 19S98
EMERGENCY TELEPHONE: Phone CH~2~TREC toll free DATE: June 1977
day or night {800)424-9300
or call Du Pont (302)774-1000
[C~.EbIICAL N.~: 3-(3,4-di~hlorophenyl)-l,l-dimethylurea (diuron)
kTRADE N;U~: Karmex® weed killer
SECTION I - PHYSICAL DATA
PHYSI~%L FORM: Tan powder
· W~.~R. Dispersible
VAPOR PRESSURE: Negligible SOL IN
SPECIFIC GRAVITY: 28~-~i~~ (loose); 31-33 lbs.}~~ (packed)
SECTION II - HAZARDOUS INGREDIENT(S)
WT % Acute 'Oral LD50 (Rats) TLV
'~ Diuron 80 3400 mg/kg 10 m~/m3
SECTION III - Hr-ALTH HAZ~,J~DS
STATEb~NT OF HAZARDS: May irritate eyes, nose, throat and skin·
PRECAUTIONARY MEASURES: Avoid~ breathing dust or spray mist. Avoid
contact with skin, eyes and cl. othing.
SPILL OR LEAK PROCEDURE: Clean up promptly. Do not flush with water,
pick up dry by sweeping or otker effective means·
NOTICE FROM DU PONT
THE INFOP2~_ATION CCNTAINED HEREIN IS OFFERED O}TLY AS A GUIDE TO THE
HA~NDLiNG OF THiS SPECIFIC ~ATERIAL. SINCE SUCH I~'~FOP~'._ATIO~: DOES NCT
RELATE TO USE OF THE M. ATERI-~-''~ WITH A~f OTHER .~t%TERIAL OR iN ANY PROC?SS,
A_NY PERSON USI:{G THiS I!~FOFJ.tATION }TST DETEP2~.INE FOR HI.~!SELF' ITS
S,:~-::,, .~-v FOR $2~Y PARTICULAR. APPLICATION.
3~, '% Material Safety Data Sheet
For
Karmex® Weed Killer
SECTION IV - FIR~ HAZARDS
FLASH POINT: Not found AUTO DECOMPOSITION T~u_~E.'~h, TUP~: 180-190"C
1
MIN. IGNITION ENERGY: 0.075~0.01.joule' MAX. PRESSURE RISE: 2750 psi/se
.. , @ 0.41 g/l
LO~FER EXPLOSIVE LIMIT: 0.07 g/liter
UPPER EXPLOSIVE LIMIT: Not found
.....
dispersed in air (particularly in confined spaces) may ignite if
exposed to high tem-erature igniticn source. These conditions are ;:..
unlik-lv en n,~ ~ normal, outdoor use of this Product.
foam or water spray. If area is heavily exposed to fare and if condiS~o
~ermit, let fire burn itself out since water may increase the
contamination hazard. If conditions do not permit, extinguish with
water spray. If conditions permit, cool containers with water if
exposed to fire. Wear self-contained breathing apparatus.
SECTION V - REACTIVITY
.......
" SECTION VI - TRANSPORTATION, STORAGE AND DISPOSAL
SUGGESTED DISPOSAL ~THOD: Dispose of in accordance with applicable
(LOCAL, STATE. and/or FEDERAL) regulations. If-buried, use-area away
from roots, trees, turf or other desirable plants; disposal site
should'be on level ground and not.close to streams, ponds,.~lakes,
Wells.or ditches. Do not re-use container. Bury when empty.
· ..sPECiAL-pRECAUTIONS: Do not app!y (except as 'recommended for. crop use)'.
~i'or drain 0r'~.i'flush. equipment, on or near desirable trees Or~other Plants,'
'.or.!on"areas'iwhere their roots.may extend, or .in locations,where the' ' -
-chemiCalmaY.be.~.washed or moved-into 'con'tact with their, rOots. Do not
'c°nt'aminate~anY'.b°dy~'of water..~'~ Keep..from contact with' fertilizers,' . 'i
insec'ticideS;.~'fUngicides and Seeds. nee. p out of .reach of children. ' ~ "
.'_._'.'._._-__.,__,_.___, ...... --.._- ........................ ~ ..... - ..... '~_.
SECT.ION VII - SPECIAL PROTECTION INFORM2%TION
::.: ;'/MATERIAL SAFETY AND HEALTH DATA SHEET i~ilP
'...~ni--lly limillr to form LSB-OOS-4 (U.S. Department of Libor) ~6ne-poulenc inc.
. . ~4ctlon I NAME & PRODUCT
IEMEflGENCY PHONE NO. 24 HOURS
('~ I'<l'~'~e'Po~enc, :[nc. (~'} 800-624- 9300
;TREET ADDRESS DATE
~c~ ' 120 Jersey Avemm id} June 13, 1979
C~TY. STATE. ZIP CODE
I,I NeW Brunm~ick. New Jersey 08903
i, Chtpco Ronstar ~iV G; Oxadi ~azon '
4.) ClsH18C12N203 C] "N---..~ C(CIt3)3
S~ction 2 INGREDIENTS %
Inert Ingredients 98.0
Section 3 PHYSICAL ~)ATA
3 VAPOR PRESSURE (mmHg at 20°Cl ['~ 7 % VOLATILE BY VOLUME
~ VAPOR DENSITY ,,ir-1) .~ 8 COLOR AND ODOR I G~'e,V-W~l~.t~; sliKht odor
SOLUSILITY IN WATER Insoluble 9 PHYSICAL STATE Flowable solid
Section 4 FIFIE AND EXPLOSION HAZARD DATA
10 FLASH POINT (AND METHOD USEDI " I1 FLAMMAI~L"E'L I~"TSSTP
I
12 EXTIN- OTHER
aU,SH, NG I---IWATER nFOAM nALCOHOL .taCO2 r~-i DRY n
EDIA ~ ' IFOG I )FOAM CHEMICAL
.13 SPECIAL FIRE FIGHTING PROTECTIVE EQUIPMENT
Self-cont~ned breatlztn.~ apparatus
14 UNUSUAL FIRE AND EXPLOSION HAZARDS
Nc~te
Section 5 REACTIVITY DATA
15 NORMAL 16 CONDITIONS TO AVOID
CONDITIONS X * Stable
STABILITY
FIRE
CONDITIONS
17
INCOMPAT. I"-] OXIDIZING
IBttlTY r--]WATER r"--IACID ~.ASE i~ CORROSIVE ~ MA~T~R,~L
(Materiils to
~lvoid~ OTHER: ,
HAZARDOUS DECOMPOSITION PRODUCTS
tlyuro~tl cz'~t"/r~J~ HFtO. rL%UrO~,o~n O.~C~S may D~ emlcceu orr CO~DUS[;]L~, ....
~9 MAY 20 CONDITIONS TO AVOID
HAZARDOUS OCCUR
POLYMERiZA. .
TION WILL NOT'
OCCUR X
' (FRONT)
RA-79-10/78
~ATERIAL SAFETY AND HEALTH DATA SHEET (cont.) ~1111~
- · ". rhOne-poulenc inc.
S~tion 6 HEALTH HAZARD DATA
210RALINGESTION A.D. (rat) LD50:330,000
iYE CONTACT
23 SK,~ CONTACT ~.D. (rabbit) ~50: > 10.000 ~[1~ ~e ~a~ely ~d
24 SKIN ABSORPTION
25 INHALATION (TLV OR SUGGESTED CONTROL mauRm
2e tFFECTS FROM INHALATION OVER EXPOSURE
EYE:
W~h ~~cely
27 ~m
[~ INHALATION: ~ ~m ~ Of ~OS~.
INGESTION~ducM vomi~ and call a phy~sician,
Section 7 SPILl[. OR LEAK PROCEDURES
28 STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILL,ED ,,
.aDs. orp with vermiculite and s~.~ep up'into steel
drum.
29 DISPOS^L UET.Or Bury in an approved che~eal landfill away from men or under,ground ~mter.
_. Follow _local, state, and fede:ral re~tlations.
S~ction S SPECIAL PROTECTION INFORMATION
'ENT,LATION Provide adequate vent£1atiort.
31 RESPIRATORY PROTECTION (SPECIFY TYPE) Use air purifying respLrator with ~a~prop_~r!ate ~J.c~e
32 PROTECTIVE CLOTHING Work %~fortTt, gloves
33 EYE PROTECTION
N NOT NORMALLY r~l SAFETY GLASSES [-'1 SAFETY GLASSES ~ CHEMICAL
WITHOUT SIDE SHIELDS WITH SIDE SHIELDS WQRKERS G .OG. GLE{~
NECESSARY
] GAS TIGHT GOGGLES
OR EOUIVALENT I I OTHER:
34 OTHER PROTECTIVE EQUIPMENT ~ovid~ eye wash :fountain and safet~ shower facilities in the
x~rk a~ea.
Section S SPECIAL PRECAUTIONS OR OT~;;~ COMMENTS ' "'
35 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Avoid contact with eyes, skin .and clo~hin,% Do not store with other pesticides,
foodstuffs, or seeds. Open d~.mpim~ 2; prohibited.
OTHER PRECAUTIONS
Do no~ ea~ c]r/z~, or smoke in the ~c area. Keep out of reach ~ ch'tld~n_ Armed
con~Clon of local water supply, ponds, Or st:rm. Do not allow spray drift to
contact desirable plm'~Cs CoB~;p,~,ners may be d;.~Dn.~.d n~ '~n ~ ,-.~,-.m~ l~mdF';ll .,-,,n
proved for pesticide containers after t,horough '~-~"~s:Ln~. DO hOC allow dcxnestic animals
The informat,on herein is given in good faith
but no warranty, express or implied, is made.
H. ATER ] AL SAFETY DATA SHEET
UNION CARBIDE AGR]CULTURAL PRODUCTS COMPANY, ]NC.
P.O. Box ]2014, T.W. Alexander Drive, Research Triangle Park, NC 27709
24-HOUR EMERGENCY 'TELEPHONE ]-BOO,UCC-HELP
Effective Date: 3/]6/87 Date Printed: MAR.J7, 1987
PRODUCT CODES: S808565050T, H37827, H37818, H378]$, H37849,
H37817. H37827, H398R9
EPA Registration Number: 264-263 Page: ]
PRODUCT HAME: #FLOREL" BRAND PLANT GROt~TH REGULATOR
1. IDENTIFICATION
CHEMICAL NAHE: (2-Chloroethyl) phosphontc actd
FORMULA: C2H6CIO3P MOLECULAR WEIGHT: 144.49
SYNONYMS: Ethephon
CAS # & NAME: 16672-87-0 Phosphontc acid, (2-chloroethyl)-
IMPORTANT HEALTH EFFECT INFORMATION
CAUl I ON !
MAY BE H)~RMFUL IF S~ALLO~/ED.
See Sectton IV for complete Health I~azard Data.
'I1. HAZARDOUS INGREDIENTS
.. MATERIAL ........... ~' ........ 'T .................. ----WEIGHT '~; ........
"!.,,(1),, Ethephon ((Z-Chloroethyl) phosphontc actd) 3.9
· 'ALLO~ABLE EXPOSURE LIMITS: *' "'
.None establtshed
'" ~':': " :"' ' "(c°nt.tnued on .Pa~gei:.2) · ..,~'.'
". i,.:':. ',,.' :':' ' ' ,: .' -: , : ,.. . · ·
.~ .': .: .; .-:~
,, : . ~? . , -. ': -. "., , .. ,,
· ~ ' · i : ' · ' ' ' - ; ' '
MATERIAL SAFETY DATA SHEET
UNION CARBIDE AGRICULTLIRAL PRODUCTS COMPANY, INC.
P.O. Box ]2014, T.W. Alexander Drive,, Research Triangle Park, NC 27709
24-HOUR EMERGENCY TELEPHONE ]'BOO-UCC-HELP
Effective Oate: 3/]6/87 Date Printed: MAR 17, 1987
EPA Registration Number: 264-263 Page: 2
PRODUCT NAME: "FLOREL" BRAND PLANT G~:OWTH REGULATOR
llI. PHYSICAL DATA
SPECIFIC GRAVITY: 1.016 ~ 20/20 Degrees C
BULK DENSITY: Not applicable
BDILING PDINT, 76D mm Hg, Degrees C (FI: Decomposes above 75 Degrees C
MELTING POINT, Degrees C (FI: Not applicable
FREEZING POINT, Degrees C (FI: -1 '( 30 )
VAPOR PRESSURE, 20 Degrees C: 0.0000605 mm Hg
VAPOR OENSITY (air=l): Not Known
pH: Not known ...,
SOLUB]LITY ]N WATER,%/wt ~ Degrees C:
APPEARANCE AND ODOR: Colorless, clear liquid;
characteristic odor
IV. HEALTH HA2ARD DATA
TOXICOLOGY DATA: '")
Oral LDSO (rats): · 20,000 mg/kg body weight
Dermal LDSO (rabbits): · 2,000 mg/kg body weight
]nhalatton LCSO (rats - 4 Hour Exl)osure): No information available
Skin Effects: Not irritating
Eye Effects : Not irritating
EFFECTS OF S]NGLE OVEREXPOSURE:
Swallowing:
May be harmful if swallowed. (See TOXICOLOGY DALAI
May cause nausea, womtttng, and abdominal pains.
Skin Absorption:
No evidence of adverse effects from available information.
(See TOXICOLOGY DATA)
Inhalation:
No information available, but may be slightly irritating to
the respiratory tract.
Skin Irritation:
No significant adverse effects are anticipated based on available
information. (See TOXICOLOGY DATA)
(continued on pa~ge 3)
#AT E R]KL SAFETY DATA SHEET
UNION CARBIDE AGRICULTURAL PRODUCTS COMPANY, INC.
P.O. Box 12014, T.W. Alexander Drive, Research Triangle Park, NC 2770g
24-HObTR EMERGEHCY TELEPHONE I'800-UCC-HELP
'Effective Date: 3/]6/87 Date Printed: HAR ]7,
EPA Registration Number: 264-263 page: 3
PRODUCT NAME: ~FLOREL" ~AND PLANT GROWTH REGULATOR
IV. HEALTH HAZARD DATA (continued)
Eye Contact:
No evtdence of adverse effects from avatlble Information.
(See TOXICOLOGY DATA)
EFFECTS OF REPEATED OVEREXPOSURE:
No adverse effects expected form repeated overexposure except for
slight respiratory irritation.-
OTHER EFFECTS OF OVEREXPOSURE:
No evidence of additional adverse effects from available information.
EXISTING MEDICAL.CONDITIONS AGGRAVATED BY EXPOSURE
Skin irritation may be aggravated in persons with existing skin
lesions.
Breathing of vapor or sprays (mists) may aggravate
&~thma and inflammatory or ftbrottc pulmonary disease.
EMERGENCY AND FIRST AID PROCEDURES:
Swallowing:
If patient ts conscious and alert, give 2-3 glasses of water
or milk to drink. If available, give one tablespoon of Syrup
of Ipecac to induce vomiting. Alternatively, induce vomiting
by touching back of throat with finger. Do not repeat the
Syrup of Ipecac. Do not make an unconscious person vomit.
GET MEDICAL ATTENTION.
Skin:
Immediately wash skin with plenty of soap and water, if available,
while removing contaminated clotlqtng and shoes. Wash clothing
separately before reuse.
Inhalation:
Remove victim to fresh air. If not breathing, give artificial
.respiration. Administer oxygen tf necessary. GET MEDICAL ATTENTION.
Eyes:
Hold eyelids open and flush with a steady, gentle stream of water
for at least 15 minutes. GET MEOIICAL ATTENTION.
(continued on page 4)
HATERIAL SAFETY DATA SHEET
UNION CARBIDE AGR]CULTUIRAL PRODUCTS CCMPANY, INC.
P.O. Box 1~034, T.W. Alexander Drive, Research Triangle Park, NC E770g
~4-HOUR EMERGENCY TELEPHONE I-SOO-UCC-HELP
· Effective Date: 3/36/87 Date Printed: MAR ]7, ]987
EPA Registration Number: Z64-263 Page: 4
PRODUCT NAME: aFLOREL'~ BRAND PLANT GROI~rTH REGULATOR
IV. HEALTH HAZARD DATA (continued)
NOTES TO PHYSICZAN:
No specific antidote ts available.
All treatments should be based on observed signs and symptoms
of distress tn the patient. Overexposure to materials other than
thts product may have occurred.
Based on the results of antmal studies on the acttve Ingredient of this
product, thts product may cause mtld to moderate peripheral choltnesterase
Inhibition, depending on the degree and duratton of the exposure.
The use of conventional treatment for choltnesterase Inhibiting agent,
t.e. atroptntzatton., has not been established for thts product.
Three of stx #tn vttro" mutagentctt¥ studtes of the active Ingredient
of thts product were positive. However, #tn vtvo" mutagentctty
studies ~ere consistently negative. Therefore, the ~etght
of the evidence ~ould.tndtcate that the actlve Ingredient
ts not a mutagen. Zn addition, the active Ingredient has been sho~n
not to be teratogentc or carctnogentic tn antmal studies.
V. F~RE AND EXPL.OS~ON HAZARD OATA
FLASH POINT Degrees C (F): Noncombustible
FLAMMABLE L~MITS ZN A~R (ounces/cubic foot):
Lo,er: None
Upper: None
AUTO]GN]T~ON TEMPERATURE Degrees C (F): None
EXTiNGUiSHiNG MEDIA: Not combustible. Use appropriate extinguishing medta for matertal that ts supplying fuel.
SPECIAL F~RE F~GHTING PROCEDURES: Wear protective clothtng and use self-
contained breathing apparatus. Otke area to prevent runoff and
contamfnat~on of water sources.
UNUSUAL F~RE AND EXPLOSION HAZARDS:
Thermal decomposition products may be hazardous. These may tnclude
hydrogen chloride.
(continued on page 5)
MATER/AL SAFETY DATA SHEET
UNION CARBIDE AGRICULTLIRAL PRODUCTS COMPANY° INC.
P.O. Box ]2014, T.V. Alexander Drtve, Research Trtangle Park, NC 27709
24-HOUR EMERGENCY TELEPHONE ]-800-UCC-HELP
Effective Date: 3/16/87 Date Printed: MAR 17, 1987
EPA Registration Number: 264-263 Page: 5
PRODUCT NAHE: "FLOREL" BRAND PLANT GROW/TH REGULATOR
VI. REACTIVITY DATA
STAB! LITY:
Stable
CONDITIONS TO AVOID:
Temperatures above 75 Degrees C (167 F)
MATERIALS TO AVOID:
Alkaline materials. Corrosive to m.etals such as 1rom, aluminum,
and copper.
HAZARDOUS DECOMPOSITION PRODUCTS:
Decomposition products may be hazar~dous. These may include hydrogen
chloride. Reaction with bases causes evolution of ethylene gas.
HAZARDOUS POLYMERIZATION: Will not occur.
VII. SP!LL OR LFAK PROCEDURES
STEP5 TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Dike large spills.
Absorb small spills on theft matertal such as sand or vermiculite. Wear
appropriate personal protective equ~ipment. Do not contaminate water sources.
WASTE DISPOSAL METHOD: Dispose of tn ~n approved landfill or incinerator
following all applicable federal, state, and local regulations.
(continued on page 6)
MATERIAL SAFETY DATA SHEET
UN]ON CARBIDE AGR]CULT~URAL PRODUCTS COMPANY, ]NC'.
P.O. Box 12014, T.W. Alexander Drtve, Research Trtangle Park, NC 27709
~.4-HOUR EHERGENCY TELEPHONE ],-BDO-UCC-HELP
Effective Date: 3/]6/87. Date Printed: MAR 17, 1987
EPA Registration Number: . 264-263 Page: 6
PRODUCT NAME: "FLOREL" BRAND PLANT GROWTH REGULATOR
VIZI. SPECIAL PRDTECTION INFORMATION
PROTECTIVE EQUIPMENT SHOULD BE USED ]:N THE MANUFACTURE OR FORMULATION OF THIS
PRODUCT, INCLUDING THE FOLLOWING:
RESPZRATORY PROTECTION: Use NIOSH/MSFIA approved respirator for pesticide mist when handling spills or leaks, or ~hen airborne concentrations are high.
VENTILATION: Mechanical (general) ventilation.
PROTECTIVE GLOVES: Impervious gloves.
EYE PROTECTION: Safety glasses.
OTHER PROTECTIVE EQUIPMENT: Protective clothing.
IX. SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Avoid oral ingestion or exposure by inhalation. Avoid getting in eyes
on skin, or on clothing.
Do not store near food, feedstuffs, fertilizers, or seed.
Do not .store at temperatures in excess of 75 Degrees C (167 Fl.
Do not contaminate water, food, or IFeed by storage or disposal.
The opinions expressed herein are thos~e of qualified experts within Union
Carbide Agricultural Products Company,. Inc. We believe that the information
contained herein is current as of the date of tht.$ Material Safety Data
Sheet. Because the use of this tnforma~tton and these opinions and the
conditions of use of the Product are not within the control of Union Carbt~e
Agricultural .Products Company, ]nc., it is the useres obligation to
Uetermtne the conditions of safe use of the product.
"FLOREL" is a registered trademmrk of Union Carbide.
(Last Page)
P.O. BOX 2200 · HI6HWAY52 N.W. · WEST LAFAYETTE, INDIANA4~Vg06 · PHONE: 317-463-26'11 · TELEX: 27-9428 · CABLE: 6LAKCHEM LAFAYETTE
Information on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act of 1970and
shall not be used for any other purpose. Use or dissemination of iii or any pert of thll information for any other purpose may result in
a violation of law or constitute grounds for legal action.
SECTION I °
MANUFACTURE R'S NAME t EMERGENCY TE LE PHONE NO.
GREAT LAKES CHEMICAL CORPORATION '~I . (50.1)' 862-5141
TRADE ~NAME AND SYNONYMS ' METH-O-GASq%~. ' ~ '~"
MET~I-O;GAS® 100'*, .TERR-O-GAS® '10~'~. :
CHEMICAL NAME AND SYNONYMS
Bromomethane, Methyl B~omide '~
CHEMICAL FAMILY I FORMULA CAS .,Re§is try Number
Alky1 BromideI CH3Br 74-83-9
SECTION II - HIAZARDOUS INGREDIENTS
COMPONENT % HAZARD DATA
Methyl bromide ~99.5 ·Methyl bromide is a poison and can cause'
~ respiratory distress, cardiac arrest,
Methyl chloride ~0.2 and central nervous system effects.
Dimethyl ether '~0.2
SECTION III-PHYSICAL DATA
BOILING'POINT(·F-) 38.5 SPECIFIC GRAVITY (H20=l)at :)2cF. 760 m~. ag 1.732
VAPOR PRESSURE (mm H0.) at 10deF. 261)0
at 68cF. 1400
VAPOR DENSITY lAIR-l) ~ 3. :;- 7
SOLUBILITY IN WATER 68CF. g./100 g. 1.75
APPEARANCE AND ODOR Colorless, odorless ~as at normal temperatures and ~ressures.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method used) I FLAMMABLE LIMITS
None I ~10-15% in air
EXTINGUISHING MEDIA
All conventional extinguishing media are suitable.
SPECIAL FIRE FIGHTING PROCEDURES
Wear self-contained breathing apparatus.'
UNUC;UAL ~ :U ANDEXPLOSION HAZAHDS
Combustion in the presence of other fuels may renault in the release of hydrogen bromide and/or bromine or other
toxic gases. Methyl bromide is ignitable by a high energy spark at the flammability limits listed above.
SECTION V · HEALTH HAZARD DATA /
THRESHOLD LIMIT VALUE . TWA - OS~A= C20 ppi (skin)(C80 rog/M3)! ACGIH, 5 p[~a (skin) (20 rog/M3); E~A fumiqatio~ li
TOXICITY ~'equi~i~-~CBA: 15 p
Oral LD50 (rat) 100 mg/kg. Inhalation '~Ci~ (rat) is' 3120 ppm for 15 minutes.
Inhalation LC.~ (human) is 600~0 ppm for ~-hours. M~thyl bromide is a poi~n
and can cause cardiac arrest, and central nervous system irritation in humans.
Methyl bromide is mutagenic in the Ames test at levels above the TLV, but has
not been found to be carcinogenic in a 90-day oral study in rats.
· -- CONTINUED -
GLK 138 1M 10/75 page 1 of
· A§ricul~ural produc~.
SECTION V - HI:ALTH HAZARD DATA (cont.)
EFFECTS OF OVEREXPOSURE
Symptons appear slowly lncluding~ Dizziness, blurring vision, lassitude, sensation of fatigue,
staggering gait, slurring speech, nausea and vomiting, and anorexia.
EMERGENCY AND FIRST AID PROCEDURES
In all cases of overexposure, get medical attention l~rm~ediately. ?aka person to a doctor or emergency
treatment facility. IF INHALED: Remove exposed person from contaminated area. Keep warm. Hake sure
person can breathe freely. If breathing has stopped, give artificial respiration. Give oxygen if needed.
If not .unconscious, rinse mouth out with water. Seek medical attention immediately. IF Oil SKIN:
Immediately remove contaminated clothing, shoes, jewelry, and any other item on skin. 'Wash contaminated
skin area thoroughly with soap and water. IF
stream of water for at least 15 minutes.
SECTION VI- REACTIVITY DATA
[ r'ONI)ITIONS TO AVOID
STABILITY UNSTABLE ~co.?~act with aluminum, magnesium, alkali metals or .strong alkalis
STABLE X I may cause violent reaction liberating toxic
gases.
INCOMPATIBILITY
Aluminum, magnesium, alkali__metals, strong alkalis
HAZARDOUS DECOMPOSITION PRODUCTS In firetl fueled by 6ther materials,· methyl bromide may
release hydrogen bromide or bromine fumes.
CONDITIONS TO AVOID
~ MAY OCCUR None.
HAZARDOUS
POLYMERIZATION WILL NOT OCCUR X
SECTION VII -:SPILL OR LEAK PROCI~DURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED DR SPILLED
Evacuate area immediately. Using appropriate respiratory protection open all windows
and doors. Do not re-enter until detector indicates safe conditions. If outdoors,
evacuate area immediately until gas has dissipated.
~A' '~"w'c ~t~I'~J,~.~L METHOD
1) Return cylinders to Great Lakes Chemical Corl~ration. 2) Ideally should be dissolved in a combustible
solvent and burned in an incinerator with afterburner and alkali scrubber. 3) Very small amounts may be
vented to the air away from streams, lakes, vegetation only if care is taken to insure no humans are in the
vicinity. Do not return to area until safe by detector indication.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPI RAT~I~v
If the concentration of methyl bromide as measured by detector tube exceeds 5 ppm at anytime all
persons in fumigation area must wear NIOSH/HStlA approved SCBA.
VENTILATION I LOCAL L,x. r :E, ! . 5PI::CIA L
I Essential. when indoors. Noue.
{ MECHANICAL - OTHER
Use for ~enez~al area cojl__tr_o..]:_%.__ _ None.
I
PROTECTIVE GLOVES .'F. Pr~r~TFCTION
Do not use. Cup-type s.a~ety...goggles below 5 ppm.
OTHER PROTECTIVE EQUIPMENT
Pump and detector tubes for determining methyl bromide concentrations.
· ' SECTION IX - SPECIAL PRECAUTIONS
PRECAUTION.~ TO BE TAKEN IN HANDLING AND STORING
Can u t be stored in a cool, well-ventilated area. Cylinders should be handled and
s m s
stored with safety_g..ap in plac.e.
OTHER PRECAUTIONS
~'lethyt bromide has no odor at dangerous levels and is extemely hazardous.
The information supplied above is presented in good faith and has been derived from sources believed' to be reliable. However. no warranty.
axpre$l or implied is extended regarding itl accuracy or the results to be obtained from Its use. Since conditions of use are bev.ond our
control all risks ara assumed by the user.
GLK 138 1M ~0/75 Rev. 6/82 10/80 Rev. 3/85 Rev. 10/85 eage2of2
Rev. 3/86
#ATER [AL SAFETY DATA SHEET
Dow Chemtcal U.S.A. #tdland, N! 48674 Emergency Phone: 517-636-4400
hSD: 000506 Page: 1
PRODUCT NAME: V[KANE (R) FUM!GANT
Effective Oate: 09/11/78 Oate Printed: 10/16/85 Product Code: 91503
1. ~NGRED~ENTS:
Active ingredient:
Sulfuryl fluoride
Inert ingredient= 1~ ':.,
2. PHYS!CAL DATA:
BOILING POINT= -67F
VAP PRESS: 235 psi
VAP DENSITY: 3.5
SOL~ IN NATER: Practically insoluble
SP. GRAVITY:. 1.36 (20C-lilq. dens.)
APPEARANCE: Colorless.
ODOR: Odorless conipressed gas.
3. FZRE AND EXPLOSION HAZARD DATA:
FLASH POINT:, None
,' I~ETHOD USED~ Not Indicated
, FLAPd~ABLE Lift:iTS
" :. LFL: Not applicable
',,..~ ~UFL: Not app!icable .'
,.. EXTiNGUiSHING-.i~EDiA: Nonflammabl·. "
· . ...~: .:;.~
· ." ~,. ~-. FIRE'.& EXpLOS. I~ON. HAzARDS:.:,.I.n~'.aifire, cylinders may vent:and.
.,-.:~. . .:., ~ruPtUre and release toxiC; gas. :':' ~'
· .. ,, ,,..?.. , :... ...~ ..:. -., . ~:..:.
.... · , ':. :. ,,,i'-~ :':*F I REL'F 1 GHTt'NG '-E(~'u i PftENTt..,,:sei f'con tai ned' br ea thing appar a tus
(Continued On Page 2)
(R) Indicates a trademark of The Oo~ Chemical Company ,
#ATER[AL SAFETY DATA SHEET
Oow Chemical U.S.A. #~dland, #! 48674 Eamrgency Phone: 517-636-4400
HSD: 000506 Page: 2
PROOUCT NAME: VIKANE (R) FUMIGANT
Effective Date: 09/11/78 Oate Printed: 10/16/85 Product Code: 91503
4. REACTIVITY DATA:
STABILITY: (CONDITIONS TO AVOID) Cylinders may leak or rupture in a fire.
INCORPATIBILITY: (SPECIFIC RATERIALS TO AVOIO) Strong base.
HAZARDOUS OECO/~POSITION PROOUCTS: Sulfur dioxide and hydrogen fluoride under fire conclitions with hydrocarbons.
HAZARDOUS POLYMERIZATION: ~/ill not occur.
5. ENVIRONHENTAL AND DISPOSAL ]:NFORMATZON:
ACTION TO TAKE FOR SPILLS/LEAKS: Use respiratory protection in
correcting source of leaks. Use air-supplied breathing
apparatus remove leaking cylinder to open isolated area.
OISPOSAL ~ETHOO: Allow to. evaporate in open area away from
people.
6. HEALTH HAZARD DATA:
EYE: 'Gas - not considered a problem. Liquid under pressure
could cause frost type burn.
SKIN CONTACT: Gas - not considered a problem. Liquid under
pressure could cause frost type burn.
SKIN ABSORPTION: Gas - not considered a problem.
INGESTION: Gas - Ingestion unlikelyl moderately toxic to lab
animals.
INHALATION: TLV: 5 ppm (1977). Vapors may be harmful, no odor at
, harmful concentrations.
SYSTEMIC & OTHER EFFECTS: Lung edema, central nervous system
depression. Gross overexposure may be fatal.
(Continued on Page ~)
(R) Indicates a trademark of The Dow Chemical Company
#ATERIAL SAFETY DATA SHEET
Dow Chemtcal U.S.A. #tdland, #1[ 48674 Emergency Phone: 517-636-4400
RSD: O00$oG Page: 3
PRODUCT NAME: VIKANE (R) FUMIGI~T
Effective Date= 09/11/78 Date Printed: 10/16/8~ Product Code: 91503
7. FIRST AID:
EYES: Irrigation of the eye immediately with water for ~ minutes
is ,good safety practice.
SKIN: Nash off in flowing water.
INGESTION:
INHALATION: Remove to fresh air if effects occur. Call a ",,
physician and/or transport to medical facility.
NOTE TO PHYSICIAN:
Eyes and skin: Injury is unl'ikely. Ray produce frost-bite type
of injury.
Respiratory: Ray cause moderate irritation.
Systemic: Anesthetic or narcotic effect may occur. Ray cause
neurologlc signs and :symptoms. Consult medical personnel.
Treatment based on the sound judgment of the physician and the
individual reactions of the patient.
8. HANDLING PRECAUTIONS:
VENTILATION: Sufficient 1Co control to TLV for this product.
RESPIRATORY PROTECTION: Air-supplied breathing apparatus.
SKIN PROTECTION: Clean, body-covering clothing.
EYE PROTECTION: Not normally Pecessary. Safety glasses with side
shields - only where liquid may come in contact with eyes.
9. ADDITIONAL INFOP, MATION:
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: See
· label - keep out of'reac:h of children. OD not breathe gas.
Keep all unnecessary people and pets out of area containing.
vikane gas. Store away from heat and dwellings.
RSDS STATUS:
(Continued on Page 4)
(R)....!?dicates a trademark of The Dow Chemical Company
MATER :[AL SAFETY DATA SHEET
Dow Chemical U.S.A. Midland, #! 48674 Emergency Phone: 517-636-4400
/~SD: 00050~ Page:
PRODUCT NAME: ¥!KANE (R) FUM!GAHT
Effective Oate: 0~)/15/78 Date Printed: 10/16/85 Product Code:
(R) Indicates a trademark of The Dow Chemical Company
The Information Herein Is Given In Good Faith, But No Warranty,
Expressed Or Implied, Is Hade. Consult The Dow Chemical Company
For Further Information.
,,o. ]MATERIAL SAFETY DATA SHEET
~.BOX2200 · HIGHWAY~2N.W. · WES~LAFAY[~E, INDIANA4~906 · PHONE:3~7-46~-25~l · TELEX:2L9428 · CABLE:GLAKCHEMLA[AY[TTE
InformatiOn on this form is furnished solely for the purpose of compliance with the Occupational Safety and Health Act of 1970 and
shall not ~ used for any other purpose. Usa or disseminations of allot any part of ~itinformation for any other purpose may result in
I
· violation of taw or constitute grounds for legal action.
SECTION I
MANUFACTURER'S NAME I EMERGENCY TELEPHONE NO.
GREAT LAKES CHEMICAL CORPORATIONI (501) 862-5141
TRADE NAME AND SYNONYMS
Chloropicrin, Chlor-O-Pic '
CHEMICAL NAME AND SYNONYMS
Chloropicrin, Trichloronitromethane, Nitrochloroform
CHEMICAL FAMILY ] FORMUL& CAS Registry No. ,
Ha loni t roa lk ane CC 13NO2 76- 06- 2
SECTION II - HAZARDOUS INGREDIENTS
COMPONENT % HAZARD DATA
Chloropicrin ~>9,6.5 TWA is 0.1 ppm or 0.7 mg./cu.m.
Other halonitroalkanes ~<3.5 Not established.
SECTION III ' PHYSICAL DATA
BOILING POINT (°F'| (112°C.) 233.6 SPECIF lC GRAVITY (H20= 1) 1.66
VAPOR PRESSURE (mm Hg.! ( 20 °C. ) 18.3
VAPOR DENSITY (AIR=ll ~ 5.7
SOLUBILITY IN WATER g./100g. 0 · 2
APPEARANCE ANDODORCo1orless liquid with intensely irritating tear gas odor.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
I
FLAMMABLE LIMITS
F LASH POINT (Method u~d} Not avai lab le. Not avai lab le.
EXTINGUISHING MEDIA Fog.
SPECIA. L FIRE FIGHTING PROCEDURES
Self-contained respiratory equipment mandatory. Evacuate area, cool
with water fog from remote location.
UNUSUAL FI RE AND EXPLOSION HAZARDS
Not combustible, heated material decomposes violently at 112°C. to
severely toxic gases especially in contact with metals.
SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE is 0.1 ppm or 0.7 mg./cu.m.
TOXICITY
Acute Oral LD~n (rats) : 250 mg./kg.
Acute Dermal- LD50 (rabbits): Severe Irritant
Acute Inhalation LC50 (rats): 150 ppm (15 min.)
- CONTINUED -
GLK 138 1M 10/75 page 1 of 2
- , SECTION V - HEALTH HAZARD DATA (cont.)
EFFECTS OF OVEREXPOSURE
Symptoms include eye irritation and tearing, severe skin irritation,
vomiting, bronchitis, nausea, coughing, .~uffocation, and/or death.
EMERGENCY AND FIRST AID PROCEDURES If ingested, promptly induce vomiting unless victim is con-
vulsing or unconscious; obtain medical as~istance immediately. If eyes are contacted, flush
with water for 15 minutes; obtain medical assistance immediately. If skin Ks contacted, flush
with large volumes of water at least 15 minutes; obtain medical assistance immediately. If
inhaled, move victim to fresh air, give artificial respiration if breathing stops; obtain
medical assistance immediately. Donor reuse clothing or shoes until completely free of
chemical odor.
SECTION 'VI - REACTIVITY DATA
STABILITY CONDITIONS TO AVOID
UNSTABLE Unstable under fire
STABLE X conditions - see Section IV.
INCOMPATIB8LITY Organic amines; corttainers or equipment made of aluminum,
.maqnesium or their alloys. _
HAZARDOUS DECOMPOSITION PRODUCTS
Phosgene, nitric oxide.
MAY OCCUR CONDITIONS ID AVOID None.
HAZARDOUS
POLYMERIZATION WI LL NOT OCCUR X
SECTION VII -SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR: SPILLED F. vacuate area. Vapors are extremely
irritating; use full face gas mask or self-contained breathing apparatus. Avoid run-
off to sewers or other waterways by diking. Cover spill with so~a ash, mix and spray
with water. Scoop in~o a bucket ot water and let stand for two hours. Neutralize
with a solution o~ 18% hydrochloric acid in water. Place in a suitable container and
dispose.
WASTE OISPOSAL METHOO Small quantities will vaporize and dissipate rapidly. Pour large
quantities over soda ash. After mixing with the soda ash, drain slowly into a large
vessel. Neutralize with a solution of! 18% hydrochloric acid in water and remove to
~approved incinerator or chemical landfill.
SECTION VIII - SPECIAL PROTECTION INFORMATION
laF.~;PIRATORY PROTECTIONFull-faced gas mask ,,~ith ..yellow type (;Mt, ~&ni~:er f6~: 0.1 ppm to 4 ppm'levels. DO not
use if any odor or irritation is noticed. Self-con~ained breathing apparatus operated in positive pressure mode.
VENTILATION ILOCAL EXHAUST SPECIAL None.
IEssential in enclosed area. .
I MECHANICAL OTHER
~ See above. No~,
PROTECTIVE GLOVES I EYE PROTECTION
Neoprene or other impermeable gloves.I Cup-type safety Eo~les.
OTHER PROTECTIVE EQUIPMENT
Clc~n body-¢overin~ clothinK, apron and face shield desirable.
SECTION IX .. SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANOLING AND STORING Keep containers upright and stored
in a cool,' well ventilated place a.way from dwellings. Do not remove
cylinder safety caps until just prior to use.
OTHER PRECAUTIONS
Avoid any possible contact with liquid or vapor.
The information supphed above is presented in good faith and hal been cle~ived from sources behaved to be reliable. However, no warranty,
control ell risks are assumed by the user.
GLK 138 1M 10/75 page2 of 2
Rev. 6/82
U,~. Ut"FAI"I I l¥1t"l~l I UI- L/-~DUIt OMB No. 44-RJ381
Occupational Safety and Health Administration.
MATERIAL SAFETY DATA SHEET
Required under USDL Safety and Health Regulations for Ship Repairing,
Shipbuilding, and Shipbr~aking (20 CFR i015, 1016, 1017)
SECTION I
MANUFACTURER'S NAME / EMERGENCY TELEPHONE NO,
!
WHITHIRE RESEARCH LABORATORIES, INC. q314) 225-5371
z-tee uourt InGbstrza~ ~vG., St. Louis, MO 63122
CC~foMICAL NAME AND SYNONYMS I TRADE AND SYNONYMS
rpyrifos, Dursban (see chemical name below) I PT N~MOE
CHEMICAL FAMILY I FORMULA
Organic phosphate insecticideI 0.5% Dursban
EPA Reg. No. 499-147-AA
SECTION II - HAZARDOUS INGREDIENTS'
TI..V TLV
PAINTS, PRESERVATIVES, & SOLVENTS % (Ur,Its) ALLOYS AND METALLIC COATINGS % (Units)
PIGMENTS BASE METAL
CATALYST ALLOYS ..
VEHICLE METALLIC COATINGS
SOLVENTS ~ Propellants :~q,~ ~-'~tl~ FILLER METAL
PLus COAT,NG OR CORE FLUX
ADDITIVE5 fJ OTHERS
OTHERS
TLV
... HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES % (Units)
Chlorpyrifos [0,0-Diethyl 0- (3 ~ 5 ~ 6-Trichloro-2-pyridyl) Phosphorothioate] 0.5
SECTION III - PHYSICAL DATA
BOILING POINT (OF,) n/a SPECIFIC GRAVITY (H20=1) 1 · 3~0
VAPOR PRESSURE (mm Hg.) 3620mmH8 PERCENT, VOLATILE 99+%
BY VOLUME (%)
EVAPORATION RATE
VAPOR DENSITY (AIR"I) n/a ( -1) ~/a
SOLUBILITY IN WATER Tnsol.
APPEARANCE ANDODOR Sprays as a strong mist with characteristic Dursban odor.
SECTION IV - FIRE AND EXPLOSION HAZAMD DATA
.blone (la'TIaRA MRthn,rl RI'!7.'~) elonr.l, ammaDle
EXTINGUISHING MEDIA
SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE AND EXPLOSION HAZARDS
PAGE (1) (Continued on reverse side) Form OSHA-20
Rev. May 72
SECTION V - HEALTH HAZARD DATA
TltRES,OEDLIMIT VALUE
3'9 mg/H~ [approx. sol'n method)
EFFECTS OF OVEREXPOSURE
Discomfort or tightness in chest, difficulty in breathing, stomach pains, nausea,
, hca ache nerv usness, w s hours a~er exposure.
vomi~inR,pupxxs or ~urre~arrh a~iston.C amps Symptoms ~ay not occur un~-§' nonact e pin oint
[MERGENCY AND FIRST AIDPROCE~URES
Remove person from area where pesticide is present. Call physician. Atropine is
-~t~e--~-co~51t phySic--i~n--~Sr an emergency supplY, if compe~St
avai]ahl, tn admintmtmr atropine. Also,. 2-PAM is antidotal and may be used in
conjunction with Atropine. Artificial respiration may also be required.
SECTION VI REACTIVITY DATA
STABILITY _CONDITIONS TO AVOID
Indefinite wh{ ;[~-JNSTABLE
, )o not spray into opne flame Or onto very hot
used. acc0rdin~ STABLE surfaces.
ED axrectlons. X
INCOMPATABILITY [~laterial$ to avoid} ·
NONE
HAZARDOUS DEcoMposITION PI~OOUCTS
Thermal decomposition xn open flame will result in halogen acids and carbon dioxide.
CONDITIONS TO AVOID
HAZARDOUS MAY OCCUR
POLYMERIZATION
WILL NOT OCCUR X .o
SECTION VII - SPILIL. OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
in well-ventilated area, then dispose in. safe place. In case of spillage on skin,
wash" thoroughly with soap and water.-~nsuit physician lmmedlateiy if ii,ness
A~ASTE' C~IspOs~L METHOD
rosox cy~xn~er xs not refillable. Do not attempt to recharge. When cylinder is
exhausted, discard in safe place. Do not throw in ~ire.
SECTION VIII - SPECIAL PROTECTION INFORMATION
-~[.~JRATORY PROTECTION (SpeciJ), tj'pc)
None .required--avoid breathing spray mist.
VENT,LA.,ONLOCAL ×.AUST SP C'^L
ovxoe adequate ventilateion of treatmel T~H~a.
Nt'oROTECTIVE GLO,VES ,, I Eh(E PROTECTION , '..
ne require~--avox~ contact-with skin more requ~rea--avoxa contact with eyes
I
[~i'OoTHER PROTE. CTI~/E EQUIPMENT
ne requxrea
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Keep._out_.o£_reach_of...ch~ldren.,__C.on~en~..~_~nde.r_p_r.e~.u_r_e_- Do not puncture. Do not
store near heat or open flame. Exposure to temperatures above 130°F may cause burst lng.
OTHER PRECAUTIONS
_J~hl~ng. Avoid contaminatio~ of food, utensils~ and food
preparation areas.
PAGE (2) Form OSHA-20
GPO 930.540 Re~. I~la~, 12
NA.TER I AL SAFETY DATA SHEET
Dow Chemical U.S.A. Midland, HI'. 48674 Emergency Phone: 517-636-4400
Product Code: 260~R6 Page: 1
PRODUCT NAME: OURSBAN (R) TC TERMITICIDE CONCENTRATE
Effective Date: 08/01/8G Date Printed: 02/06/87 ~SDS:O01~9
1. INGREDIENTS:
O,O,-Oieth¥10-{3,5,6-trichloro-
2-pyridinyl)phosphorothioate,
{chlorpyrifos) CAS# 002921-88-2 &2.8~
Inert ingredients: ~7.2~
Xylene range aromatic solvent CAS# 06~7~2-95-2
Proprietary emulsifiers
Substances listed in the Ingredients Section are those identified "
as being present at a concentration of 1~ or greater, or 0.1~ if
the substance is on the list of potential carcinogens cited in
OSHA Hazard Communication Standard. Where proprietary ingredi'ent
shows, the identity of this substance may be made available as
provided in 29 CFR 1~10.1200(I).
2. PHYSZCAL DATA: . ..
BOILING POINT: 290F, 1431:
VAP. PRESS: 24 mmHg ~ ~OC
VAP. DENSITY: (Air = 1) :,1
SOL. IN WATER: Emulsifie~)
SP. GRAVITY: 1.1~
APPEARANCE: Yellow liquid. -.
ODOR: Rercaptan type odor.
3. FIRE AND EXPLOSION HAZARD DATA:
FLASH POINT: 122F, 50C
HETHOD USED: TCC
FLA~ABLE LIRITS
LFL: Not determined
UFL: Not determined
(Continued on Page 2)
(R) Indicates a trademark of The Dow Chemical Company
.,:.~ :..:~. Dow Chemtcal U.S.A. #idland, #! 48674 EAm~ency Phone: 517-636-4400
'. Product Code: 26056 Page: 2
PRODUCT NAME: DURSBAN (R) TC TERMITICIDE CONCENTRATE
Effective Date: 08/01/86 Date Printed: 02/06/87 ~SDS:OOI~b9
3. FIRE AND EXPLOSION HAZARD DATA: (CONTINUED)
EXTINGUISHING t~EDIA: Water spray, carbon dioxide, and dry chem i ca 1.
FIRE &. EXPLOSION HAZARDS: Foam fire extinguishing system is
preferred. Toxic irritating gases may be forme~. Rapid
decomposition above 160-200C. Violent rupture of containers
due to over-pressur i zat ion may occur.
..FIRE-FIGHTING .EQU!P/~ENT: Use positive-pressure,, self-contained
breathing apparatus.
4. REACTIVITY DATA:
STABILITY: (CONDITIONS T,D AVOID) Avoid heating above 5bC, 130F
temperature for more than two hours. Chlorpyrifos undergoes
exothermic decomposition which can lead to higher temperatures
and violent decomposition if heat developed is not removed.
Contains petroleum derivative solvent - wi I1 burn.
INCO/~PATIBILITY: (SPECIFIC ~tATERIALS TO AVOIO) Unstable at pH above 10. Consult manufacturer for specific cases.
HAZARDOUS OECO/~POSITION PROOUCTS: Hydrogen chloride, ethyl .sulfide, diethyl sulfides and nitrogen oxides.
"- HAZARDOUS POLYRERIZATION: Will 'nOt occur.
,'." "':5..: -ENVIRONMENTAL AHD .DISPOSAL INFORMATION: " .,, "'":.~" .
':' . ' ACTION TO TAKE FOR SPILLS,/LEAKSt .Absorb spills ' '"
. ~:. ' with!.material such as s~and. Wash.exposed. body areas:thorOughly
'i .- ....... after,handling. :Contain spill, by diking to keep out of sewers,:
-':::' ' ....:~:.:...~.-.. : =.:.:For-..larg· sPiils~.barrlcade.-area, eliminate'ignition-:'sources,~.* ~.
· :::- i" ~::.-' :"..' ".:,":"':and consult manuf.acture~r, i-::: '":" ,,' ' ' :' ,- - , .. '. ' :":, ::'":::.?,!"'~:'. ' :: ::-: '~ :-:. ' ". '::_'
'/.,,:?" !:!: :,',i'i,i!.. '::::,?: .'..r'O.'i sPO'$AL;: J~ETHoD: ;--Bury '.'c I ean":uP:i was te :i'n: :loCati'on::
· ' :'~'' .~.':~.,,i-i-~ ~.~::~.::~.::=,':,--":: .:.-:domesti'¢' ~ater :Suppl i es, ::acco'~:d ing to "local. '.state,.,...and
:..: ~-,.:..::/" ?;i ,:..:...:.:.,,':ii,:i:~:,..-~.': regular 1 °ns. I nc t nerate ~'at' 1800F u ith' 2 ,.'second" ':res i dence:,:!t:
::-:: /:..?,... ~:" .':" ,(R):?:lndi'~:ates a ~r:ademark of Th, Oo~ C' em ' p y . '"':: ".'-:: -' ":'":
,.;,: .,, Dow Chemical U.S.A..Midland, H! 48674 Emergency Phone: 517-636-4400
Product Code: 26056 Page:
PRODUCT NAME: OURSBAN (R) TC TERM!TICIDE CONCENTRATE
Effective Date: 08/01/86 Date Printed: 02/06/87 RSDS:O01449
6. HEALTH HAZARD DATA:
EYE: Ray cause moderate eye irritation. Ray cause slight
corneal injury. Effects may be slow to heal.
SKIN CONTACT: Short single exposure not likely to cause
significant skin irritation. Prolonged or repeated exposure
may cause skin irritation. Ray cause allergic skin reaction
in susceptible individuals. Ray cause increased sensitivity
to sunlight (photoallergy) due to solvent.
SKIN ABSORPTION: A single prolonged exposure may result in the
material being absorbed in harmful amounts. The LDSO for skin
absorption in rabbits is 1265 mg/kg (males) and 930 mg/kg "
(females).
INGESTION: Single dose oral toxicity is moderate. The oral
LO50 for male rats is 226 mg/kg. Amounts ingested incidental
to industrial handling .are not likely to cause injury~
however ingestion of larger amounts could cause serious
.i&jury, even deRth. If aspirated (liquid enters the lung),
may cause lung damage or even death due to chemical pneumonia,
a condition caused by petroleum and,petroleum-like solvents.
INHALATION: The LC$O for female rats is between 2.6-5.6 mg/1
for 4 hours. Excessive exposure may produce organophosphate
type cholinesterase inhibition. Excessive exposure to solvent
may cause, in order of increasing concentration: eye and
upper respiratory tract irritation, feeling of increased body
heat, central nervous s:~stem effects such as headache,
dizziness, incoordination, drowsiness, unconsciousness.
SYSTERIC & OTHER EFFECTS: Excessive exposure may produce organo-
phosphate type cholinesterase inhibition. Signs and symptoms of
excessive exposure to active ingredient may be headache,
dizziness, incoordination, muscle twitching, tremors, nausea,
abdominal cramps, diarrhea, s~eating, pinpoint pupils, blurred
vision, salivation, teaching, tightness in chest, excessive
urination, convulsions. Repeated excessive exposures to
high concentrations of solvent may cause liver and kidney
injury and effects on blood cells. Active ingredient did not
cause cancer in long-te~-m animal stud.ies. Xylene was not found
(Continued on Page 4)
(R) Indicates a trademark of The Oo~ Chemical Company
........ Do~ Chea'ical U.S.A. M*idland, ,M! 48674-. Eaergency Phone: 517-636-4400 ..
· · Product Code: 26056 page: ~
PRODUCT NAtlE: DURSBAN (R) TC TEPJ4ITICIDE CONCENTRATE
Effective Date: 08/01/86 Date Printed: 02/06/87 /~SOS:O01~49
6. HEALTH HAZARD DATA: (CONTINUED)
to be carcinogenic in a National Toxicology Program'bioasssy in
rats and mice, Active ingredient did not cause birth defects in
laboratory animals, Xylene has been reported to cause effects
on the fetus when administered to pregnant laboratory animals.
In animal studies, active ingredient has been shown not to
interfere with reproduction. Based on a majority of negative
data and some equivocal or marginally positive results, active
ingredient is considered to have minimal mutagenic potential.
Results of in vitro ("test tube") and in vivo mutagenicity
tests on xylene have been'negative. · "
7. FIRST AIO:
EYES: Irrigate with flowing water immediately and continuously for fifteen minutes. Consult medical personnel.
SKIN: In case of contact. Immediately flush skin with plenty of
water for at least 15 minutes while .removing contaminat&d.. "
clothing and shoes. Cai1 a physician if irritation persists.
Nash clothing before re~use. Destroy contaminated shoes.
INGESTION: Do not induce vomiting. Call a physician and/or transport to emergency *facility immediately.
INHALATION:, 'RemoVe to fresh air. If not breathing, give mouth-
.to-moUth ~resuscitation. If, breathing is difficult, give· oxygen.
Call a physician. ....
NOTE*TOiPHYSIClAN: . The decision of whether to induce v°m.iting
. 'or'not.~sh°uld..be'made by an .attending physician. If lavage '
is'~..performed, suggest endotracheal and/or esophageal control';'.
".' '~ ,Danger from !,ung aspiration must be weighed against toXicity '?'i':'
.... when.considering emptying the stomach. Suggest serUm and/o'r".~ ..:: :.. :::.'
rbc 'choli nesterase dete~mination..' Atropi ne by i nj ect ion '~.i s'~ ' .::,/:? '
:' ., the:preferabl'e.antidote.-.~:Oximes may·or'may not be'..thej~'apeuti'c,:;~'~ r":'*::'''
· . but':-,:! ti,:' ;t:s:. recommended', they notll be ,used in"place '
- "'SUpport;iveLcare. Treattnent baSed'on Judgment'of the phys'iclan%.:,-*,':~ ~:: '.'.:~.. ..~
· · .. ',.... in response :to..reactiOm~ '-of:the ,patient, ..:.~ .* ~ ,:.:~.~
..... : ...... ": ' ' . :~: "' .... :. ' 'i.,. ?' ??i..*--".:..:::L"
... .'.:;:!.:~.'-:. ...':,' · . , : .,':: ., , ... ~. ,: : . .:~'.:.::
, . '.:.. !~: ~.:.,' ,: .... ...... -. :.. : . , :,.~
· .. '' .::,:: -. . "" ~ ""*~ '.i.' ' :{...;"" ,,, -
. . -. :,. ;'::
'* · ' ' '!i ~ '.
(Cont i nued on .'Page ..$) "' '
(R) Indicates,a trademark of The Dow Chemical Company , - .:
~. - · /- .... ., ~ .. - , ::.'7 .' ,,.. ': . .' .
,::.~ *~ ,. Dow Chemical U.S.A. Nidland, HI 48674 Emergency Phone: 517-636-4400
Product Code: 26056 Page: 5
PRODUCT NAME: DURSBAN (Ri TC TE~[ITIC[DE CONCENTRATE
Effective Date: 08/01/86 Date Printed: 02/06/87 RSDS:OOI~9
8. HANDLING PRECAUTIONS:
EXPOSURE GUIDELINE= ACGIH TLV is 0.2 mg/m.t for chlorpyrifos)
the STEL is 0.6 mg/m3. ACGIH TLV and OSHA PEL are 100 ppm for
xylene) the STEL is lJ~O ppm.
VENTILATION: Control airborne concentrations below the exposure guideline. Us.e only with adequate ventilation.
Local exhaust ventilation may be necessary for some operations.
Lethal concentrations may exist in areas with poor ventilation.
RESPIRATORY PROTECTION= Atmospheric levels should be maintained
below the exposure guideline. When respiratory protection is
required for certain operations, use an approved air.-purifying
respirator. For emergency and other conditions where the
exposure guideline may be greatly exceeded, use an approved
positive-pressure self-contained breathing apparatus.
SKIN PROTECTION: Use protective clothing impervious to this
material. Selection of specific items such as gloves, boots,
apron, or full-body suit will depend on operation. Safety
shower should be located in immediate work area. Remove
contaminated clothin~q immediately, wash skin area with soap
and water, and launder clothing before reuse. Contaminated
leather items, such as shoes, belts and watchbands, should be
removed and destroyed.
EYE PROTECTION= Use chemical goggles. If vapor exposure causes eye irritation, use a full-face respirator.
g. ADDITIONAL INFORI(ATION:
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
RSDS STATUS: Revised sections 1, 2, 3, 6, s, and 8.
(Ri Indicates a trademark of The Dow Chemical Company
The Information Herein Is Given In Good Faith, But No Warranty,
Express Or Implied, Is Hade. Consult The Dow Chemical Company
For Further Information.
U.S. DEPARTMENT OF' LABOR J'-
~ ~ OCCupational Safety and Health Administration
c;:: MATERIAL S.AFET.Y DATA SHEET
Required under USDL Safety &nd Health Regulation~ for Ship Repairing.
Shipbuilding. and Shiobreaking (29 CFR 1915, 1916. 1917)
SECTION I Ch. emtgac 800/4,24-9300
MANUFACTURER°$ N~,M£ ( EIVlF, RGIrNC¥ TELEPHONE NO.
Van Uaters & Ro. gersJ /408/263-~00
ADDIIE$$ (A'umbo, Streel. 00'. Stole. end ZIP CodeJ
8~x gq'f2= San Hat~_~; CA
CHEMICAL N~,I~[ AND SYNONYMS - - - "1 TRADE NAME AND SYNONYI~.~
Ntb'rIco pyrenone concentrate
CHE:MICAL, FAMILY [ FORMULA
SECTION II - HAZARDOUS INGREDIENTS
PAINTS. PRESERVATIVES. & SOLVENTS % TLV ALLOYS AND METALLIC COATINGS % TLV
i , ~. (Unit~) ...... (Units)
I
VEHICLE METALLIC COATINGS
FILLER METAL
SOLVENTS PLUS COATinG OR CORE FLUX
ADDITIVES OTHERS J
(' OTHERS
......
HAZARDOUS.., MIXTURES OF OTHER LIOUIDS. SOLIDS. OR GASES
Pyrethrins ,,, 1 .(~
Technical Piperonyl Butoxide 10 0
" Z~4 .....
Petro. le_um. Hydroc_.arbons (Kerosene)
Emulsifier 15~0
SECTION III - PHYSICAL DATA
BOLLING POINT (cF.) 1 ~0OF SaECIFIC GRAVITY (H2Or]) , ~36
VAPOR PRESSURE {mm HE.) PERCENT, VOLATILE
- BY VOLUMF (%) ~ J I
'VAPOR DENSITY (AIR=J) EVAPORATION RATE
( -2} -
SOLUB~UTY m W~TER Emu 1 s i f i ab 1 e
~PP~A.*~CERNOOOO. Amber ] i_quid w_ith pyre:hrin odor.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
/XTINGUISI41NG MEDIA
Water fog,foam, C02, dry ch.~mi, cal ......
SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
Contact dermatitis is most common manifestation of
pyrethrum, in man. Extrinsic a~thma in a fe~
Eye~:~a~h for 1~ mlnute~ with 1~ pre~,rp water. Skin:~ash ~ith spa and
~ater,remove contaminated clothing. Ingestion:Contains al iphaCic pet oleum
solvents. Induce vomiting only at direction of 'medical auth0'rities.
sufficient pyrethrum ha~ been [r]0eRf~d tO cause nervouR manifestations,
~,henobarbitol should be used
SECTION VI - REACTIVITY DATA
~TABL[ XXXx Combu~rlhlP mixture
None known
None knorr ,.
HAZARDOUS MAY OCCUR
~LYU[ RIZAT ION
WILL ~OT OCCUR (X'~XX Combustible
SECTION VII - SPI, LL OR LEAK PROCEDURES
5T[~ TO B~ TAKEN IN CA~[ MATERIAL I~ RE~[A~[O OR SPILLED
Absorb spi 1 Is ~i ~h i ner~ ma~er ia ] such as sand. Va~h erea
WASTE DIS, I~OSAL METHOD
Dispose of waste on landfill approved for pesticides or bury in non-
crop land away from water supplie~,
SECTION VIII - SPECIAL FROTECTION INFORMATION
RESPIRATORY PROTECTION ~.~p¢¢i.f',t
Required ¢~i.th S_O_ace spray. Rec~,mmended ~irh <,,trace spray.
VENTILATION I LOCAL EXHAUST .... I SPECIAL
I Surface S~ra~_
i~rne.d off during treatmenr;vent]mate.h~Fore r~-~ntr~: .
PROTECTIVE GLOVES ~ EVE PROTECTION
Rubber or polyethylene .
J
Goggler Rhould h~ wnrn
SECTION IX - SPECIAL PRECAUTIONS
PAGE (21 ro~m L)S~A 20
MATERIAL SAFETY DATA SHEET
Emer~ncy Phone No. (504) 8674751 or 346-1410
l_ .' (Central timbre) (7AM~PM) (6PM-7AM)
M-F
Dm Sh~ No. 3:321
' CLINE-BUCKNER, INC. ll/1/os
' Subsidiary of Waterbury Companies, Inc. m~u, of ~ All Previous
SECTION I
TRADE NAME AND SYNONYMS
VW&R Purqe CB S-1000 Insect Killer 23 oz,
CHEMICAL NAME AND SYNONYMS Resmethrin (See Below +)
CHEMICAL FAMILY Synthetic Pyrethroid I FORMULA EPA Reg. # 9444-55-550
SECTION II - PRC)DUCT AND COMPONENT DATA
COMPONENT(S) CHEMICAL NAME
CAS REGISTRY NO. %(Approx)l ACGIH TLV-TWA
+[5-(phenylmethyl)-3-furanyl] methyl 2,2-dimethyl
3-(2-methyl-l-propenyl ) cyclopropanecarboxylate 10453-86-8 1.0 NE
Hydrocarbon Propellant (Propane) 74-98-6 20 1000 ppm
Methylene Chloride 75-09-2 80 350 mg/M3
SECTION III - PHYSICAL DATA
BOLLING POINT (OF.) NA SPECIFIC GRAVITY (H20-1) 1.3
VAPOR PRESSURE (mm .,.) ' 3104 PERCENT, VOLATILE 99%
BY VOLUME (%)
EVAPORATION RATE NA
VAPOR DENSITY (AIR-i) NA
- SOLUBILITY IN WATER ' ' I nsol
APPEARANCEANDODOR Very dry mist with cha~racteristiC sweet Resmethrin odor.
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (MethoduMd) NA I FLAMMABLE LIMIT6 Il Lei Ii Uel .
EXTINGUISHING MEOIAC0 ,Dry Chemical, Foam
sPECIAL FIRE FIGHTING PR0~CEDUREB
Self contained air supply suggested. Keep containers cool to
avoid bursting.
UNUSUAL FIRE AND EXPLOSION HAZARDS Exposure to temperatures above 130 degrees F may cause burstinc
PAGE (1) N,E, m Not Established (Continued on Reverae Side) N,A, - Not Applicable
SECTION V HEALTH HAZARD DATA
TU,?.S,OLD LIMIT V^LUE
4.~7 mg/M3 [appx. soln method)
E'"Ia~ECTS OF OVEREXPOSURE
Headaches. nausea, vomiting, abdominal cramps, dermatitis; however,
nnf ~yn~t~d hpca,_~e RP_~methrin is not considered to be highly toxic to humans or other mammd
EMERGENICY AND FIRST AID PROCEDURES -
Eyes-[trio_ate with plenty of water for 15 minutes. Skin-Wash with soao and water' for 15
minutes. [n_oestton-Oo not Induce vomiting. Orlllk several glasses of water Or milk~ Seek
medtcal attention. ~[nhalatton -Eemove to fresh air. Seek.medical attention tf indicated.
SECTION VI . RI=ACTIVITY DATA
STABILITY CONDITIONS TO AVOID
UNSTABLE Open flames & very hot surfaces cause
STABLE X thermal de¢omp0~il;igll,
INCOMPATABILITY (Materialx to avoid]
None
HAZARDOUS DECOMPOSITION PRODUCTS
Hydrogen chloride & sma1] amountsof Phos=ene & Chlorine
CONDITIONS TO AVOID
HAZARDOUS MAY OCCUR
POLYMERIZATION WILL NOT OCCUR X
SECTION VII - SPILL OR LEAK PROCEDURES
~ TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
__ If container is ruptured or begins to leak.
place in a well-ventilated area, Dispose of container in a safe manner. For skin contact~
wash with soap and water.
WASTE DISPOSAL METHOD
Do not discard empty container in incinerator or fire. Place empty con-
tainer in trash receptacle.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type)
Not required-avoid breathi nq mi st.
LOCAL EXHAUST SPECIAL
VENTILATION I~ECHAH I,CAL (Ge.n~r~/).. OTHER
rrov~ae ventilation according to label.
PROTECTIVE GLOVES I F~,YE. PROTECTION, ..
Not required-avoid contact with skin. i,o: requ~re~-avo~a contact with eyes.
OTHER PROTECTIVE EQUIPMENT
!; SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store ~n a cool dry area away from heat or open
es. Do not store above 130 degrees Farenheit.
PRECAUTIONS DO not ·
spray in areas where food or feedstuff are exposed. Read label
PAGE (2)
THIS INFORMATION IS GIVEN IN GOOD FAITH, BUT NO WARRANTY EXPRE~ED OR IMPLIED IS MADE, WATERBURY COMPANIES BE-
LIEVES THAT IT IS ACCURATE TO THE BEST OF ITS KNOWLEDGE AND RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN
'/
.,,... MATERIAL SAFETY DATA SHEET
Emergency Phor~ No. (504) 86743761 or 3413-1410
(Centrel tim,) (TAM43PM) (SPM-TAM)
M-F
Dete Sheet No. 3301
' CLINE-BUCKNER,INC. S. po~d.'""'O't' , 11/1/85
· Subsidiary of Waterbury Companies, Inc. ,...of I All Previous
* JCA
M~nuf~eturing Division Address: P.O. Box 640, Independence, LA 70443 I.ued By ~
SECTION I
TRADE NAME AND SYNONYMS VW&R Purge CB-40 Aerosol Insect Killer 16 oz., 23 oz., & 2 lb.
CHEMICAL NAME AND SYNONYMS Pyrethrin I & II: Fractions
CHEMICAL FAMILY Natural Pyrethroid IFORMULA EPA # 9444-41-550 ' ' '
SECTION II - PRODUCT AND COMPONENT DATA
COMPONENT(S) CHEMICAL NAME
CAS REGISTRY NO. %(Approx) ACGIH TLV-TWA
Pyrethri ns ' 8003-34-7 .5 5 mg/M~
Odorless Mineral Spirits 64742-48-9 8 NE
Methylene Chloride 75-09-2 70 350 mg/M3
Propane 74-98-6 20 1000 mg/Mj
SECTION III - PHYSICAL DATA
BOILING POINT (OF.) N~ SPECIFIC GRAVITY (H20-1) 1.20
PERCENT. VOLATILE
vAPOR PRESSURE (m~ He.) 336,2 BY VOLUME(%) 97.5%
EVAPORATION RATE NA
VAPOR DENSITY (AIR-l) NA
'SOLUBILITY IN WATER I nsol
APPEARANCE ANDODOR Very dry fog with :haracteristic Pyrethrin odor.
SECTION IV - FIRE! AND EXPLOSION HAZARD DATA
F LASHPOINTi/V/ebgodu,ed) HA I FLAMMABLE LIMITS NA I u., , u.,
I
EXTINGUISHING MEDI~C02,Dry chemica!, Foam,
SPECIAL FIREFIGHTINGPROCEDURES Self contained air supply suggested. Keep containers cool to
avoid bursting.
UNUSUAL FIRE AND EXPLOSION HAZARDSExposure to temperatures above 130 degrees F may cause bursting
PAGE (1) N.E. - Not Estiblbhecl (Contin,ued on Reverie Side) N.A. - Not Appliclble
SECTION V HEALTH HAZARD DATA
~R~.o,o LIMIT VALUE mq/H3
~_~ 333 (appx. soln method) ....
SOF OVEREXPOSURE
Headaches, nausea, vomiting,....abdominal cramps, breathing difficulties,
dermati ti s.
EMERGENCY AND FIRST AID PROCEDURES --1
Eves'Irrigate with oienty of water'.for 15 minutes. Skin-Wash with soap and water for 15
minutes. Ingestion-Do not induce vomiting. Drink several glasses of water or milk. Seek
medical attention. Inhalation -Remove to fresh air. Seek medical attention if indicated.
SECTION VI - REACTIVITY DATA
Open flames & very hot surfaces cause }
STASLE ~X thermal decomposition,
INCOMPATABILITY (Materials to avoid}
None
HAZARDOUS DECOMPOSITION PRODUCTS
Hydro§eh chloride & small amountsof Phosqene & Chlorine
HAZARDOUS MAY OCCUR NA
POLYMERIZATION IWlLL NOT OCCUR I X I
SECTION VII - SPILL OR LEAK PROCEDURES -.
-- 'O BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
)If container is ruptured or begins to leak,
place in a well-ventilated area. Dispose of container in a safe manner. For skin contact,
wash with soap and water.
WASTE DISPOSAL METHOD
Do not discard empty container in incinerator~ or fi re. Place empty con-
tainer in trash receptacle. ~-
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (Specify type) Not requi red-avoi d breathing mi st.
LOCAL EXHAUST SPECIAL
C AN AL G ~ I · OTHER
/ENTILATIONI~'1~1~ VL~R~'~'1~t~on accordin!l to 1 abel.
'~OT. ECTIVE ~LO~ES . IEeE P. ROTECTU3N . . .
.o~ requireD-avoid contact with skin. ~ .o~ requ~reo-avo~ contact with eyes.
)THER PROTECTIVE EQUIPMENT
t; SECTION IX - SPECIAL PRECAUTIONS
RECAUTIONSTO BE TAKEN IN HANDLING ANDSTORING Store in a cool dry area away from heat or open
f_~a,~mes. Do not sto~e above 130 degrees farenheit.
Use 2-3 second sprays/1000 cubic feet. Remove pets, birds and
cover fish aquariums. Do not spray on plastic, painted, or varnished surfaces or directly
~GE m~ into electronic equipment.
HIS INFORMATION IS GIVEN IN GOOD FAITH. BUT NO WARRANTY EXPRESSED OR IMPLIED IS MADE. WATERBURY COMPANIES .BE-
IEVES THAT IT IS ACCURATE TO THE BEST OF ITS KNOWLEDGE AND RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN
Code # 30624
MATERIAL S~FETY DATA SHEETS (MSDA)
FOR
The MSDS sheets for Diazinon 3 Dust are attached.
This product is a formulated product and information is
for ~he technical materi&l and ~he major ingredients.
3223 Diazinon MG-8
1285 Microcel E
~17 ~oaostone
The MSDS sheets for the following product(s) has been
reques=ed. When it is received, we will forward i~ to
you~
msds. tJw
CIBA-GEIGY CORPORATION PRODUCT SAFETY
AGRICULTURAL DIVISION DATA SHEET
DIAZINO]g MG8 (TECHNICAL)
.GENERAL INFORMATION ,
Synon~ Di&z:Lnon
Chemical Cl&se Organophosphate
EPA Signal Word Caution
pivision Address.~ .~nergenc~ Phone Number
cIBA-GEIGY CorPoration 1-800-334-9481 or
P.O. Box 18300 (919)-292-7100
Grienlboro, NC 27419
FIRST AID PROCEDURES
D~ez~on MG8 is an organopholphats ~nsec~icide.
These conpounde ara relat~rely po~sonous to animals and
people. Aa their mode of action is ~he sa~e, poisoning bM
organophosphatee leads to fsinilar e~nnptonJ (due to
inhibitiOn'or ~he enzyne c~Lolinesterese). These can include
headache, g~dd~nese, blurred v~s~on, veakness, nausea,
creeps, diarrhea, discomfoz~ ~n ~he chest, nervousness,
· veat~ng, ~Losim (p~npo~nt pup£1), tanr£n~, salivation,
uncontrollable'nuscle ~v~tc~es, convulsions, con&, and loss
sE re£1exee and sphincter c:on~rol.
Z~ poisort~q is 'suspe~ced, do not vait £or s~npto~t to
develop. YJmned~ately beqin ?.he recon~ended procedures
¢on~ac~ & ph~s~cian,~.he ne~erest hospital or ?.ha neares~
Poison Con,roi Center. Tell ~e person contacted: the
conplete produc~ naris, the tTpe and enount'of exposure,
describe any symptoms and f~ollow the edvicegiven.
NOTZz Be sure to tell ~he F.hysician ~.h~s conpound Is a
cholineeterase
For additional in~ornetion, call day or
CIBA-GEIGY Corp. 1-800-334.-9481 or 919-292-7100.
DIAZINON TECHNICAL
PAGE i
CIBA-GEIGY CORPORATION PRODUCT SAFETY
AGRICULTURAL DIVISION DATA SH~T
EYE CONTACT
Immediately flush with a '.Large amounttt of running water.
Hold eyelids apar~ while flushing to insure t. he entire
surface of ~he eye and lids are rinsed with water. Do not
attempt to neutralize wit~a chemical agents.
SKIN CONTACT
Wear gloves while decont~ainating. Immediately remove
con~.aminated clothing. Diazinon can migrate through the skin.
Wash with plenty of soap ~und water including hair and under
fingernails. Do no= at'c. empf', to neu~ralize with chemical
agen~.
If symptoms occur, remove from contaminated atmosphere.
INGESTION
If victim is fully conscious, immediately give large
~uantities of water and induce vomiting. Never give anything
by mouth to an unconsciousl person. Apply az~cificial
respiration if necessary, preferably by mechanical means.
Avoid mouth-to-mou~ resus~citation. Call a physician or the
nearest Poison Control Canter immedia,c.ely.
NOTES~ TO PHYSICIAN
Diazinon is an organophosphate insecticide. Monitor serum and
RB~ cholines=arase. If ing'ested and vomiting has been
inadequate, induce vomiting or 1swage stomach. Thirty to
fifty grams of activated charcoal in 3-4 ounces of water can
be given. A~ropine is an~idotal for organic phosphate
poisoning and should be given i.v. in multiple doses as
necessary un=il the patien~ is atropinized. 2-PAM may also
be given in severe cases provided ~herapy begins within 36
hours of exposure.
CONDITIONS LIKELY TO BE AGGRAVA.TED BY EXPOSURE
Exposure to cholinesterase lnhibitors should be restricted in
persons being =rested with morphine, theophylline,
aminophylline, and phenothiazine drugs, and in persons with
hemol~cic anemias or pre-existing depression of
cholines=erase.
DIAZINON TECKNICAL
PAGE 2
CIBA-GEIGY CORPORATION PRODUCT sAFETY
AGRICULTURAL DIVISION DATA SHEET
~ERSONAL PROTECTION AND PRECAUTIONS . .
~o,, ayoid ~ °
Ingestion Keep all foo~L in a separate area away from ~he
a~orage/uee location of ~he chemical. Preven~
ea~ing, drinking, ~obacco usage and cosmetic
application in areas where ~hare is a
potential for exposure ~o ~h~s material.
Always.wash hands prior ~o using ~obacco
produc~s, ea~,ing0 drinking or applying
cosme~ics.
Skin con~ac~ Preven~ skin con~actwi~h ~he produc~ by
using rubber gloves, waterproof boo~s and
pro~ec~ive clothing.
Eye con~ac~ Avoid eye con~ac~ wi~h ~he produc~ by using
chemical safe=y glasses or goggles.
Inhala~ion This ~a~erial should be handled in a well
yen=ils=ed area. Where adequate yen=ils=ion is
no~ available or exposure for long periods ~o
· excessive mists or spray could occur, wear an
approved pes=icide respire=or.
Al=er working wi~h Diazincn iKG8, thoroughly clean
con~amina~sd aquipmen=. Wash ~horoughly, change clothing and
clean pro~sc~ive gear. Discard heavily con=aminated articles
which cannot be washed, such as leather shoes.
SPILL~ LEAK AND FIRE PROCEDURES " '
Spill o~ Leak Make a~tre all personnel involved in spill
cleanup follm~ good indus=r£al hygiene
practices.
Small spill's ,=an be handled routinely.Wear
rubber gloves., boo~s, eafe~y
goggles, pro=active clothing and ha~. Cover
~he epill vi~ an abeorben= ma=ariel such as
sweeping compound (ca= lib=er) or lime. Sweep
up ~.ha ma=ariel and place in an appropria=e
chemical waste con=ainer. Wash ~he spill area
wiSh wa=er containing a a=rong de=ergen=,
absorb i=, and place in ~.he chemical waste
DIAZINON TECHNICAL
PAGE 3
CIBA-GEIGY CORPORATION PRODUCT SAFETY
AGRICULTURAL DIVISION DATA SKEET
con:airier. Seal container and dispose of in an
approved manner. Flush t. he spill area with
water to remove any residue. Do not allow
wash water :o contaminate water supplies. Ail
personnel should wash thoroughly after olean-
up is completed.
D~ no= reuse container. Disposal of material,
wash wa:mr, spill residues and containers must
be by. me=hods consistent with local, sta=e and
federal health and environmental regulations.
A spill of one pint or more of =his material
is repoz~cab~e to =he National Response Center,
1-800-424-8802, under =he Comprehensive
Environmental Response, Compensa:ion and
Liability A~:= (Superfund).
IN CASE OF EHER~T~NCY, CALL DAY OR NIGHT
1-800-42,¢-9300 (CHEHTREC)
Firm As in any f~£re, prevent human exposure to
fire, smoke~, fumes or products of combustion.
Evacuate nonessential personnel from =he area.
This material is an organophosphate
insecticide.. Firefighters should wear full-
face, self~:ontained breathing apparatus and
waterproof ¢:lo~hing (gloves, hoods, suits and
rubber boot~m).
Use standard[ organic chemical firsfighting
techniques ~ ex~inguishing fires involving
=hie material - use dry chemicals, foam or
oarbon dioxide. Use of contaminated
buildings, area and equipmen= must be
prevented un=il they are properly
decontaminated.
DIAZINON TECHNICAL
PAGE 4
: CIBA-GEIGY CORPORATION PRODUCT SAFETY
AGRICULTURAL DIVISION DATA SKEET
PHYSICAL HAZARD INFORMATION
FIRE AND EXPLOSION
Flash Point (Test)re,hod} 185 to 200 F (TCC)
· ,.
Autoignition Temperature 360 ¢
REACTMTY INFOPJ~TION
Stability Stable
Razardous Polymerization Will not Occur
Incompatibility (Materials Acids and Bases
to Avoid)
PHYSICAL FROPERTY DATA
Physical State Light Tan to Brown Liquid
Melting Point Not Applicable
Vapo~ Pressure 2 x 10 -4 ~m ag e 20 C
Solubilit~ in H20, % by Wt 40 rog/1 e 20 C (Active Ingrad.
Boiling Point (760mm ag) · 200 C
Denait7 1.12 ~ 20 C
Odor slight sul fur-lika
Evaporation Rate. Not Available
% Volatiles bM VolUae Not Available
Additional Fire~ Explosion and Reactivity Data
Diazinon HG8 is an OSHA class IIIA ~ombustible liquid.
Thermal decomposition products include but are not liaited
various aliphatic organophospha~es, substituted pyrimidines
and hydrogen cyanide. S-TEPP and Diazoxon may form when
Diaz'inon is reacted wl~h frs,ce amounts of water.
.... DIAZINON TECHNICAL
PAGE 5
CIBA-GEIGY CORPORATION PRODUCT SAFETY
AGRICULTURAL DMSION DATA SHEET
ACUTE TOXICITY DATA
S=udies w~ ra~s have
0.72 ~m per ~1~ of b~y weigh=. ~sed on
~ese ~al da=a, ~ges=~on of 2.5 =~lespoons
or moro of Diaz inon KG8 ~y be fa~al ~o a person.
la~e ~1 ~,50 (r~bi~)
M~ra~ly ~oxlc on '~so~ton ~ough ~ skin.
S~udt~s wi~ rabbits hav~ sh~ ~a~ a~ lower
oc~ed after ~os~e for 24 ho~.
~d ~ellhg of ~e eyelt~ ~ cc=,
~ala~ion s~iqht~ toxic
~e I~~on ~S0 (ra~) - 3.5 nq/L air - 4
~O~C ~XICI~ DATA
No widespread dele~erious ef~c=s ~o h~s are ~o~ =o have
cc=ed since Diazinon has be~ ~roduced in 1954 wh~ used
acco~g to l~el dire~tons.
Olaz~on ~s bee ~alua~ed ~ ~e ~ational ~cer Institute
carc~~icity essays. Dia:~inon has be~ sh~ ~o be non-
c~c~~tC ~ ~ese st~da~ l~ora~o~ bt~ssays,
~O~~ ~CI~ DATA
~o rec~= ~era2ol~ s~udi#s (1981, 1083) foll~ing =em=
~ldel~es of re~la=o~ aul~ori~tes as well as ~o older
o=~ies no~ nee~g ~ese sl:~da~s show Olaz~on no~ ~o be a
~era~, A few ~llca=lons have suqqes=ed ~a~ Olazinon
~y be a we~ ~era~. H~;evtr, ~e conclusions from ~ese
m=udtes ~e ~em~ion~le due to
DIAZINON TECHNICAL
PAGE 6
CIBA-GEIGY CORPORATION PRODUCT SAFETY
AGRICULTURAL DIVISION DATA SHEET
~nappropria~e nodels~ and a :Lack of a nome1 dose response
MUTAGENICITY DATA.
~e~ a~udiea ropo~ Diaz:Lnon no~
s~udies ~n~ad~ ~s ~si~:ion, sons of ~ using no~
~lly rec~ized ~d valida~ed assay
~CX~ 0~.,.~ CO~~S
Mo a~e~e e~ec~s ~e ~ for o~er components. Kowever,
a ~ade se~Fe~ conponen~ is ,:onsideFed a nuis~ce na~erial.
ADDITIONAL INFORMATION
CAS # 333-41-S
Cheaical Naae O. O-~iet'.hyl-O,- (2-isopropylo6onet'.hyl-¢- pyrinidinyl) -phosphoro~.hioate
DOT . 1) ~k - Xnse~icide ~id,' N.O.S.
'2) 55 Gal. Dr~ - Diazinon Solution O~-A,
~783, R~i
B/L ~eigh~ Insec~icides or ~gicides, A~i~l~ural,
Classifica~ion N.0.S.
PROCEDURES FOR
DIAZINON TECHNICAL
PAGE 7
.CIBA-GEIGY CORPORATION PRODUCT SAFETY
AGRICULTURAL DIVISION DATA. SHEET
Storage Eeep ~his material out of ~.he reach of '.
child~en. $~ore in accordance wi~.h good
pes~icide.handling practice.
~ues2ions concerning the safe handling of Diazinon HG8 should
be refez~ed to=
Xndus~rial Real~.h Depax-~aent
CIBA-GEIGY Corporation
Agricultural Division
P.O. Box 18300
Greensboro, NC 27419
Issued Date s 11/25/85
Revised Data :
I I
I The lnforna~ion and recommendations contained herein are I
I based upon da~a believed to be co==ec~, However, no I
I guaFan~ee or vaxTant¥ o~ ~ ~d ~re-sed or ~plied is I
I ~de vi~ =espe~ ~o ~e ~o~a~ion con~a~ed herein. I
I
DIAZINON TECHNICAL
PAGE 8
'..' "~'- U.S. DEPARTMENT OF LABOR
" ~.', OMB No. 44-R1387'
' ' ' ' ' 'L . Occupational Safety and Health Administration
MATERIAL SAFFTM .DATA SHEET
Required under USDL Safety and Health Regulations for Ship Repairing, ' ·
Shipbuilding~ and Shipbreakin9 (29 CFR 1915. 1916, 1917)
.I
'-'. SECTION I "' ..
MANUFACTURER~ NAME ';, : .:,.. : ;.~ ......... { EMERGENCY TELEPHONE NO,. .
~I~I~'.~S~RCH ~O~TORIES, INC." ' "" ~:': '~':~':'"'~" :~a.;' q314) 225-5371' ·
~oo Tree ~ourc znaustrzaz ezra., SC. Louis, HO 63122
rpyrifos,' Dursban (see chemicaZ name belo-) PT
.Organic phosphate inSecticide
I
' O. 5l Dursban
~A Reg No.
SECTION II - HAZARDOUS INGREDIENTS '. . .
I[.V ILV
PAINTS, PflESERVAIIViS, $ SOlVEnTS $... [Units[ · . A~LOYS AND METALLIC COATINGS .. % {Uni~}.
PlGMENT$ · . B~M~T~L . ..
CATALYST ACLOY$ .....
VEHICLE METALLIC COATINGS
SOLVENTS & Propellants ~q.~ "LUS COATING OR CORE FLUX
' j .
ADDITIVES .............. OTHERS
OTHERS .... ; .' . ......... "
......... TLV
HAZARDOUS MIXTURES OF OTHER LIQUIDS:"soLIDS, OR GASES % -(Uniul '
..SECTION III - PHYSICAL DATA ' -*
SOILING POINT (°F.) Tt/a SPECIFIC GRAVITY (H]O'I) ..... 1.3~J0
VAPOR PRESSURE (mm Hg.) 3620m~Hs PERCENT, VOLAI~ILE
B~ VOLUME
EVA~ RATION RATE
VAPOR DENSITY (AIRal) fl/a { '. · n/a
SOLUBILITY IN WATER [~S01,
APP[ARANC[ANOOOOR Sprays as a stroh8 ;ts~ vith characteristic Dursban odor.
~ SECTION IV - FIRE AND EXPLOSION HAZARD DATA
F~SH POINT (Methoa u~a) IF~M~BLE LIMITS I Lei Uel
Nnn~ (~T~RA M~rhna R~7_q) I ~onzza~oze
I
[XT~NeU~SH~aO
SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE AND EXPLOSION HAZARDS
PAGE (1) (Continued on reve.rse side) Form OSHA-20
Rev. May 72
V - HEALTH HAZARD
SECTION
DATA
/THRESHOLD LIMIT VALUE - ~ .... ~-- - -
.139 mS/H: (-approx. sol'n method) ' *
mm EFFECTS OF OVEREXPOSURE . · . '
WlDiscomfort o£ tightness in chest, difficulty ~n breathing, stomach pains, nausea,
yom tn arth a c amps, hea ache 'herr usness, ~ s , n0nact ve pin Ding
[antidote--consUlt physician rot'an eme~~~u,me~ 5~e ,
': [conJuncCibn ~ith Atropine; ':Artificial respiration ~y also be required.. :,
'SECTION VI - REACTIVITY DATA .~ .... ;:. ' ,- '
'STAB~L~T~ ~ ~c~OITIONS TO AyO~O '"
~lndefini~e vh~ ~.s~a~[ .~ ~o hoc spray ~nco opne flame or onto Ve~ ho~
se acc rdinl surfaces. ..
~o ~irec~lons STABLE X .; :
INCOMPATABILITY (Mater~l$ to avoid) -
"':" ~AZARD~U5 DECOMPOSITION P~ODUCTS
The~ decomposition zn open fZame. ~ ;~esuZt ~n haZogen acids and carbon d~ox~de
· . - CONDITIONS TO AVOID
HAZARDOUS ........ MAY OCCUR
~bYMERIZATtON
..... .. . . W~LL NOT OCCUR X
SECTIO~ VII - SPILL OR LEAK PROCEDURES .....
STEPS TO BE TAKEN IN CASE MATERIAL I$ RELEASED OR Si ILLED ' ' - '
--in well-ventilated area, then dispose tn safe place.. '"-In case' o, sptllase on ski.,.
wash Cfioroug~ly wiCn soap and 'waCer. '~onsult physician ~edzacely zf illness
roso~ cyzznoer zs hoc regtllable. Do hoc attempt Co recharge. ~en cylinder
exhausted, discard In sale place.. Do hoc throw in Iire ......
· SECTION VIII - sPECIAL PFIOTECTION INFORMATION
· . 41. .~ESPI'RATOR¥ PROTECTI6N/Specify type/
None required--sro.id breathing spray mist.
LOCAL EXHAUST SPECIAL
VENTILATION
~ECHAH ICAL. fGe.ereU OTHER
ovzae a~equace vencilaceio~ of CreaCmel,c area.
ne requ~re~--avoza contact rich skin, ~oge requz~e~avoz~ contact rich etas
oTHER PROT[CTI~[ [~UIPM[NT ' '
ne requzreo .... . .........
' 'SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO B~ TAKEN IN HANDLING AND STORING
~ep our n~ reach of children. Contents urlder pressure. Do hOC puncture. Do hOC
store near heaC or open flame. Exposure co temperatures above 130°F may cause burs~ ing.
OrHEa ~afCAUT,ONS
~Vash rhorouEhly after using. Avoid contamination of food~ ucensils~ and food
~ -- eparaCton' .areas.
PAGE (2) Form OSHA.20
MATERIAL SAFETY DATA SHEET I Msos NuMSE.' . '
MC.x,a~O~" ~ ~ ~ FM 2 610 ~
T~ ~ GENERIC
gZC~O-~ A, B, C~ g ~-26~ ~-38r ~-T0~-400 S~n~he~te Calc~
~nv~lle In~e~a~onal Co~ora~ion , 1344-95-2, '.
~l~ q&T~ ~NE NUMeER
~ 0~ aox ~08 (303) 978-]~20 ....
M4~R~ CAS NUMBER ~ TLV
Svn~eCtc Calct~ ~111cace 1344-95-2 !00 30 m~p~ c
. ~0 mq/m3
dia~o~ao~s e~. .T~ese.v~ cTp~ca~7 cc~ca~n
2~ c~is~obalice.
Use calculaced ~V o~: ~.2 m~/~3
~es~i~a~ie
' ff · ~YSICAL DATA crzscoDall:
Nil,
Gra~ to buff ffne ~wder - no odor , ,
~MMA8~ UMITS I~k
· . ~/x
UNUSU~ F~AE ~ ~Pk~ ~
~ · H~[~ H~D IN~RMATION
H~D BY ROU~S OF ~POSURE (l~cl~e ~c ~
exposes =o excessive concen=ra~Lons of dus= from C ~d T-38 may cause
, None
Transten= mech~lcal
~KIN ~T~T
None
SKiN AB~RP~
None
S~NS AND SYMPTOMS A~IA~D Wi~ ~SO~E OVE~ ~V
Znhal~cion -,txcisl~ve exposures ~y cause upger =esgira~o~ irritation.
· yel - ~empora~ irricacion Or
HEALTH HA~,ARO INFORMATION CONTINUE{:) ON BACK
V · HE~I,I'H I,IAZ,~RO INFOFIYATION
i~m~ve co £resl~
~/~
~/~
I
pna~con~osis p=~uc~nq dusts, For a~ others ~,~ a respirator su~ta~ ~o~
~v~~ - - ' ~ro~ec~Lon aga~ns~ nuisance auscs.
No=. no.ally
~ · n~l~ OATA
!
Vacu~ clean .pi~aqe, If sweep~n~ ts ne~eqsa~ uvq a dqg~ suooressan=.
W~T~~~ D~spose ~ c~osed conc~ne=s. Comply w~ch al~ ~oca~, state
~d f~e~aL =e~latio~.
Avoid c~ea~An~ du~. Repai~ a~ b=~oken ba~s. Keep ~e~e~ial d~.
I',
Ke~e~ A. ~be=~. I 5/2/83 ,
, l gr. Environmental Se~ces
~ U.KE$ ~ WA=RAN~ WI~ qESPECT ~E~O ANO.CI~IM$ A~L UASIU~ ;~OM REUA~E ~EREON.
""' "'"' ' '"' " ~11 ml~l,l(,: t' o r t ~ .,.~'./~.i'1
::t:t.~ance (lti.~t - .';e~ rel,o, rt AHA 4r.chiv. gs. lndu~tri3! .Ileal(h, Vol.. 1!)... '-'
SECTION VI - REACTIVITY DATA
. ;,.~ --~ ..... . ...............
L I x !
SECTION VII - ~ILL OR LEAK PROCEDURES
~ormaA go~a pTacc/c.¢s~ .....................
u~, approyed [or ~ro~ti~_a~,st nuisance (l,st~.
SECTION IX · ~ECIAL PRECAUTIONS
fAG[ (21 ~'hi lO the i,,rormation n,,,l r~commcn(lati(}n~ sec torch herein
f Form OSHA.20
,........ re helleved to he nccttTmte a~ of the (late heroD , _
mee~ me~
· I(IlINS-~IANVfI. I.E COIIPORATI~N HAKIT~ NIl IV,~RRAN'FY ~ITII RI~I'I;~.'I'
~IERETO ANI) II[~CI. AIH~ ALl. l.l,~nll, l'rY I:R(~H RI~I. IANCIT TIII~RI[ON.
U.~. DEPARTMENT OF' LABOR '"' "°"'°'"
' Occu~tion~l Safew I~.He~l~ ~ministration ..~~'~L.
.j'.~'~__~. &~'.~iMi~'~.~E,~ ~ CFR 1915. 1916. lglI} -- ....'
, , . . .
I ~~,~ ~( & ........ ~' '" '" 'i ,-~,o,~ *,~ -o. ' I
SECTION II - H~RDOU~ INGREDIENTS..
. . ,=.-.. .
~T~YIT A~
~~- ~.. ·~.. ·
.
.~o,,harzardous.mtxCures ~,o~; produces are routinely I i .
,- monitored to insure freedom from ha~a~dous mineral species{
t.e. ' asbestos ~
· .SECTION III · PHYSICAL DATA
~ ~,~.r,~ I ~A ~ ,~c,,~.,~,,- ,~o.,, I ' 2.8
,, , ev volume ~t ~A
~-~(~--~[-~o~o.. ~ite to tan po~der -- earthy odor
· SECTION IV - FIRE AND EXPLOSION HAZARO DATA
' '~" ~'""~-- ~' ~A I.~-...~ ~, ,, ~.. , o,.
~&~[ I~ (Co~ti,nu~ Ga r~er~ sldel Form OSHA.20
" U.S. DEPAR/,'MEN ! (IF LAItOH " ..... '~" .........
o-.',~,,o,,, s.,,,, ,,,,,, .,.,,,,, ^~m,,,,,,.,,.,., 'z/~'~ ~?.'/~*'. /' /,2 ~.-~' '
hlATEI]IAL SAFETY DATA SII£ET
· SEC, TION I
Johns-Hnnvtl l_e_.Corp.......[ Suh~ ldiaries
"[u,,~,f.; ~h~,~,,~,. ~,,,..~,,,,. ,~/~ t ~,.. . -- .....
ken-ua[v~mn~J~, uenve~ ,,~oloraqo. 80217,
I SECTION II · HAZAflOOUS INGREDIENTS
I '
................................... ~' TLV
HglRO0~ MIXTUSE[ O~ OT~[R LIQUIOS. SOLIDS. OR GISES
~fnth~[~.[~lcium sillca~e formed from reaction between ,
_~atural (iiatomaceou~ earth and li~e. )ffii *__
aDust rro~ this ~aterial is considered a nui,ance ¢articulat~
Iv VOluME
$~cT~ON IV · FIRE AND EXPLOSION HAZARO DATA
t ~V~U~SHl~ MEDIA
Non- fl a~mab 1. e
, ,
PAGE (11 (Conlineecl: 0. feve,~ I~cleI Form OSHA.20
lev. May 1~
SECTION V · HEALTH HAZARD DATA
i i II I - ~. i~ ·
,..,,-o~u-,,v~u( 20 milli0n p,azl:icles Per cubic foot ,
lu~GC~v~OPi~SVA~O~OCg~*=S~OYe'.J~Offi dusgy area; great as nuisance
.... dusC ."
.......... SECTION VI - P!ACTIVITY DATA
~"'~.' ' I ~"'a ' '~-~... . I~.. i~'~';~'... '~ '~". ..... ~o~ not ~ iv ,, ,
~NOiTIQNi T~ AVQiO
MAY ~N ' ·
' ' -SECTIONVII - SPlLLOR LEAK PROCEDURES
SECTION VIII · ~ECIAL PRO%EcTION INFORMATION '
A~e~&TOlY ~OTECTiG~ /$~lCJ~
-Use nuisance dust mask
V~Ti~T~. ' ]~OC~g ~X~USr ' ' I
' SECTION IX - SPECIAL PRECAUTIONS
~: Revised 12/1/80 .,.
PAGE (21 " ~o,m OSHA.20
'.MATERIAL SAFETY DATA SHEET
· ,; EFFECTIVE DATE: , JULY 1,1980. '
~ ., ,
PRODUCT NAME: SEVINeSLCARBARYLINSEC~CIDE '~
CHEMICAL NAME: !-Naphthyl Methylcartmmate, CarbaryI CHEMICAL FAMILY: Carbamates
FORMULA: Cl0H7OCONHCH3 · MOLECULAR WEIGHT: 201.2 (technical
SYNONYMS: SE'VIN· SL
DEPARTMENT OF I HAZARD CLASSIFICATION ORM A
TRANSPORTATION [ SHIPPING NAME . CarbaryI
CAS # 63-25-2 CAS NAME 1-Naphthalenol, M~thylcarbemate
BOILING POINT. 760 mm. Hg gs~'C FREEZING POINT -3' C
SPECIFIC GRAVITY (H,O ,= 1) 1.10to1.12 VAPOR PRESSURE at 20'C. 17.SmmHg
VAPOR DENSITY (air -- 1) 0.62 SOLUBILITY IN 40 ppm (technical
WATER, % by wt. carbaryI)
PER CENT VOLATILES EVAPORATION RATE
BY VOLUME Nil (Butyl Acetate = 1) 0.82
APPEARANCE AND ODOR Sulpermlon of carbaryI, white liquid, mild odor
MATERIAL % TLV (Units) HAZARD
43 Stag/m3 ACGIH Reversible cholinasterase inhibitor
FLASH POINT
[test method(s)] Not applicable .
FLAMMABLE LIMITS IN AIR, '/. by voIume !L°WER ! Not applicable ! UPPER ! Notepplicable
EXTINGUISHING U~e carbon dioxide or dry chemical for amall flreL
MEDIA U~e water or foam (alcohol, polymer, or ordinary) for large fires.
FIRE DEPARTMENT PREPLANNING
SPECIAL (1) Provide for protection of employE~ and local residents:
FIRE FIGHTING (a) Evacuate re~ident~ who are downwind of fire.
PROCEDURES (b) Prevent unauthorized entry to tim area.
(c) Have a medical check made of employee~ that may have been expoaed to fumes or other m~Ramina-
[ (2) Notify local tim luthorltlal that fllalmefl ahould:
p, (I) Wear protective clothing over the entire body including rubber boots, glove, hat. end coat and avoid
· - oontect with toxic fumes or imoke. Serf. containad breathing ecluiprnent (air packs) is eslentlal for
' tho~ eXl)O~ to fume~ or emoke.
304/744.3487
l'hi~ ~lmb~' b ev~il~ble de.vi, nights, v~tkef,cIs, nM holideys.
e~ 4lulllf~d IKD4ftl Npf(llnl t~ sits of tl~e tilts C~ductN, tN ~tl Ire not to N ~W Il · wirr·flt¥ w N~tl~ f~ ~Kh ~l~ ~
A~ulNrd hWU ~Nny, IK &M ~ ~IIW. Tm m off~ Jdy fg yNf c~ll~rltl~, ~tiptl~ Iai wrlf~tl~, ~y
~1~ ~R~DE AORI~L~RAL'flI~ ~Y, INC · P.O. hx 17610
7~ ~e~ Way, ~ville, FI~. 3~18
I ~.:-:,.:.Z..4 ~my perlon heavily expoeea to peeoca3ee m~ou~a De ex~mmea ~, · pnymaen .mmea,mmy wnnout
J '"--'"" w~i~ing for ~ymplom. to occur. ,
· · ] (d) Be ~left for ~fmplom, of poleoedng during the fire. Symlxom~ rrmy include heedm:hae, oiddine#,
: I biurmcl vision, coughing, tightmms of chest, .alivBtion, twitching, or pinpoim eye pUl)itt. SymlXom~
' :i I of peetidde poisoning nmy be mistaken for hast exgmustiofl or smoke inhalation.
:~* I (e) Avoid Imoking, drinking, or eating while fire fighting m) # not to ingest toxic mJbetino#;
TLr AND SOURCE: 5mg/n~Z~c~eryl)ACGIH
ACUTE EFFECTS OF OVEREXPosuRE
S~liv.tion, n~u~e~, vomiting, headache, ~bdomin~l cmmp~, pinpoint
SWALLOWING pupils.
SKIN ABSORPTION None UI~I prolonged.
OTHER HEALTH '°
HAZARDS -- '--'
AND FIRST AID PROCEDURES:
Wash wfth soap lnd water, induding hair if contJmirmted.
SKIN Remove ·ny comaminated clothing.
'INHALATION Renxwe frc~ expomJm. Seek medical ~bmtion.
NOTE~ TO PHY~GIAN .
~ ii · ~ mvmMble cholinestmmm inhibitor. Aizopine is the ·ntJdote. In ~ poi~oflin~ c#es, I ~rge
~ inlrmmnous ~ ~ ~ ~ be necealaW to mii(rKlin ltn)pinizltJon. Effects of carbaryl leldom I·st mm~ t~ ' ~n 6
STABIUTY
· UNSTABLE bi'ABLE CONDITIONS
TO AVOID NONE
X
INCOMPATIBILITY Avoid c:ont~min~tion wfth ~clueou~ mineral ~ ind alkalies, ¢~rbon monoxide
HAZARDOUS POLYMERIZATION
~ Occur WIll not Ocmur CONDm0Ns
TO AVOID NONE
X
STEPS TO BE TAKEN '
IF MATERIAL IS RELEASED Coverw~h mmmping oompound end mmmp up wflh M little du,t u po~lbie. Pu~ln
OR SPILLED q~te oont~inm, then flush e~ w~th w~tm.
WASTE DISPOSAL METHOD 'Mixwfth equal emmmt, of quiddime orwet thoroughly with ~trong cau~c ~ ~nd
buw In landfill. Ob~we governme~al regul~tion~ rngerding di~x~al.
RESPIRATORY PFK)TECTION
(specify type) Bureau of Mine~ (x NIOSH approved clusl re~mtor for pe~JCtdE~.
OTHER PROTECTIVE
EQUIPMENT I.ong-deev~l do~hing end ~ Eye t~th ~nd .~.ty dxw~er.
PRECAUTIONS TO BE TAKEN IN HANDUNG AND ~TORING
CAUTION: KEEP OUT OF REACH OF a.~I.DREN, HARMFUL IF INHALED OR SWALLOWED. Avoid breathing of ~ly. Do
no( lake intem~lly. Avoid ocmtact with ,kin end eye~ Wear regular k)flg-deeved work clothing. Ch, nge to de, n ckXhing
cbily. Wamh h~cls ~nd face bofom Emting. W~h thoroughly ~ter I~rmling.
AVOID CONTAMINATION OF FOOD, FEED, WATER SUPPUES, STREAMS AND PONDS.
FOR INDUS'IrRY USE ONLY
OTHER PRECAUTIONS
In c~e of prolonged expoeure. ~vmvvers ~fter work and dally change of cJo4~ee mhde~ble.
Store m temperatures nm exneecing IOS'.F whether indoom (smallec cor~iners) or outdoo~ (bulk storage).
AG 80032
~/80 - 2Id I~nted in U~.A.
· · -,-" MATERIAL SAFETY DATA SHEF_T
, ... . .'-' - (Approve(I. by .U.S. Department.. of Lai3or as "Essentially Similar" to Form OSHA-20)
'1. PROIDUCT .IDENTIFICATION
CHEMICAL NAME Bencliocarb: (2,2-climetrtyl-l,3- REGULAR TELEPHONE NO.:
AND SYNONYMS benzodioxol-4-01 metr¥carbamate) EMERGENCY TELEPHONE NO.: 800-424-9300
CHEMICAL .. CAS NO.
FAMILY Carbamate insecticide "
FORMULA 'C~'l~O. ' ";~' ** ' "*'* ... :..,.- MOLECULAR
. · ;-. : WEIGHT ' '
TRADE NAME Bendi(x~arb WP Bulk Pack .. . .
AND SYNONYMS ...........
.... '11. HAZARDOUS INGREDIENTS - ..
TLV-TWA VALUES
MATERIAL ADOPTED BY ACGIH
Bendiocarb ........
Inert ingredients (filler. surfactants}
· · · III. PHYSICAL DATA
BOlUNG POINT, 760 mm Hg FREEZING POINT
N.A.
VAPOR PRESSURE @ SPECIFIC GRAVITY
(at) 5 x 10-* (H~O = 1) N.A.
VAPOR DENSITY (AIR =. 1) PERCENT VOLATILE
· :' N.A. BY VOLUME (%) N.A.
$OLUBIUI~ IN WATER, : ' EVAPORATION RATE
% BY WEIGHT @(at) 0.004% ' (BUTYL ACETATE - 1) N.A.
APPEARANCE AND ODOR: White. odorless powder
... IV. FIRi~ AND EXPLOSION HAZARD DATA
FLASH POINT ' - I AUTOIGNITION .
(TEST METHOD) ":~)oes not flash ! TEMPERATURE -
FLAMMABLE UMrl;'S IN AIR Non- I LOWER I UPPER
PERCENT BY VOLUME ' flammable'! '
I
EXTINGUISHING MEDIA: Dq/chemical, foam or water
SPECIAL FIRE-FIGHTING PROCEDURES: Avoid inhalation of fumes and dust. Wear self-contained breatrting apparatus. Remove
from area of fire at first opportunity,
UNUSUAL FIRE AND EXPLOSION HAZARDS; Bencliocarb gives off methyl isocyanate fumes when heated. ·
NOTES: NA -[NOT APPLIC^$LE
*Use mis emefqency number only aam nmmal business he~m and o~, ~lm emefqencie$ involving safely ancl healtlt '
:- ,,. " '. NOR-AM Chemical Company
';MS,IS'~' DATE: June 14, 11983 PAGE 2 o! 2
· V. HEALTH HAZARD DATA '..
THRESHOLD UMIT VALUE: Not established. AOLD 50 (ra..t): !79 me/kg; ADLO 50 (rat): >1000 mglkg.
EFFECTS OF OVEREXPOSURE: Cholinesterase inhibitor;, constriction of pupils, selwation, muscular incoordination, sweahn[
vomiting.
EMERGENCY AND FIRST AID PROCEDURES: . .
If swal!owed: Drink 1 o~ 2 glasses of water and induce vomiting by touching back of throat with finger. 13o rv3t induce v~3miting or g
-; · anything to an unconscious person. Get medical attention. ".. , .
If Inhaled: Keep patient strictly at rest and transfer to ho:;pital immediately to get medical attention. ... ' ....
If on akin: Wash with soap and water. '"' · ·
If In eyes: Rinse lhoroughly with clean water. ...... · ~ ·
NOTE TO PHYSICIAN: CONTAINS ANTICHOENESTERASE CARBAMATE INSECTICIDE. IN CASES OF OVEREXPOSURE.
ATROPINE SULFATE--2 MG. (EQUIVALENT TO 1/30 GFL~IN ADULT DOSE) SHOULD BE GIVEN AND REPEATED AS NECES$
UNTIL FULLY ATROPINIZED. .~,. · ...~.
· .. ." . ........... . ..... " 'VI. REACTIVITY DATA .
STABIUTY ' J CONDITIONS TO AVOID:
UNSTABLE
I
S/ABLE x .......
INCOMPATIBIMTY (MATERIALS TO AVOID): .....
HAZARDOUS DECOMPOSITION PRODUCTS: Bendiocarb gives oil melhyl isocyanate fumes when heated.
HAZAROOUS MAY OCCUR CONDITIONS TO AVOID:
POLYMERIZATION WILL NOT OCCUR
VII. SPILL OR LIFAK PROCEDURES
STEPS'TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Carefully sweep up. avoid inhalation of dust and skin contaminapO
· "Place in a suit .~3, le container and seal. Area can be washed wilh water tO remove last traces of FICAM W. but keep out of
' ' Watercourses.
WASTE DISPOSAL METHOD: Designated landfill or controlled incineration.
.VIII. SPECIAL PROTECTION INFORMATION i.e.: fires, spillage and emergencies - -
·RESPIRATORY PROTECTION J Self-contained breathing apparatus
'II~PECIFY TYPE) .J , ;' -.
MENTILATION LOCAL EXHAUST
I SPECIAL
MECHANICAL . OTHER
(GENERAL)
PROTECTIVE GLOVES: P,V,C. J EYE PROTECTION: Goggles or face shield
OTHER PROTECTIVE EQUIPMENT: Dust mask
· . .... IX. SPECIAL PRECAUTIONS "
PRECAUTIONARY LABEUNG: Harmful or fatal if swallowed. M~ay be absorbed through the skin. Avoid contact with eyes. skin an
clothing. Il conlact occurs, wash skin and clothing ~mmea~ately with soap and warm water, and eyes w~lh clean waler.
Avoid breathing and working in spray mist or dust.
Wash ham:Is and exposed skin belore eating, drinking or smokmg and alter spraying or handling. Wash all contaminated clothir
Ihoroughly before re-use.
Do not apply Io humans, their clothing or bedding.
Do not permff children or pets near Ireated surlace until spray has clried complelely.
Do nol spray where electrical short circuil might result,
, Do not use on or contammale fruit, vegetables or olher feed or tODd crops. .
· OD not store near feed or food products and do not contammate these or toocl preparation sudaces, dishes, kitchen utensils and fora -,,
Conlainers wilh eilher concentrale or spray.
'~IRONMENTAL HAZARDS. ' · **
~--
-"This product is toxic Io Wildlife. Birds feeding on treated areas may be killed. Do not apply directly to Water. Keep out of lawn an garden lish pools. Do not conlaminate waler by cleaning of equipment or disposal ol wasles.
This pKx:luct is highly Ioxi, c Io bees exposed Io direcl Ireafmenl or Io residues on plants. , '-
OTHER HANDUNG AND STORAGE CONDITIONS: Store in coot. dry place away from fooclstuffs. Do. not slope near proclucts will~ ": '~i
,, slrono odors fha! will be abso~3ed by the FICAM W. Keeo in an area suitable for insecticide sforaqe e,'"e? from children end De, IS ; .:
MATERIAL SAFETY DATA SHEET
EFFECTIVE DATE: JULY 1,
PRODUCT NAME: 8EVINeSLCAP, BARY].INSECTICIDE :'
CHEMICAL NAME: 1-Naphthyt Methylcarbernate, Carban/I CHEMICAL FAMILY: Cart~emates
FORMULA: Cl0HTOCONHCH3 ' MOLECULAR WEIGHT: 201.2 (technical Cart)awl)
SYNONYMS: EEVlN· EL
ENT OF HAZARD CLASSIFICATION ORMI A
SHIPPING NAME Carl)awl
CAS # 63-25-2 CAS NAME: 1-Naphthalenol, Methylcarbamate
BOILING POINT, 760 mm. Hg 96.8'C FREEZING POINT -3' C
SPECIFIC GRAVITY (H,O = 1) 1.10to 1.12 VAPOR PRESSURE at D0'C. 17.8mm Hg
VAPOR DENSITY (air = 1) 0.62 SOLUBILITY IN 40 ppm (technical
WATER, % by wt. carbawl)
PER CENT VOLATILES EVAPORATION RATE
BY VOLUME Nil (Butyl Acetate = 1) 0.82
APPEARANCE AND ODOR Suspension of carban/I, white liquid, mild odor
MATERIAL % TLV (Units) HAZARD
43 Emg/m3 ACGIH Reversible cholinesteraea inhibitor
FLASH POINT
[test method(s)] Not applicable
' FLAMMABLE LIMITS IN AIR, % by volume LOWER Not applicable UPPER Not applicable
EXTINGUISHING ~ carbon dioxide or dry chemtca,I for ·mall fires.
' MEDIA Ute water or foam (alcohol, polymer, or ordinary) for large fires.
RRE DEPARTMENT PREPLANNING
SPECIAL (1) ;',~le for ~on of emplc~eas end local residents:
FIRE FIGHTING (e) Evacuate r~ldents who em downwind of fire.
PROCEDURES (b) Prevent unauthorized ent~, to fire ama.
(c) Have · medical check made of employees that may have been expom~ to fumes or other contamina-
(2) Notify local fire luthoritiea that flren'mn
(I) Wear protective clothing m~er the entire body including rubber boots, gloves, hat, end coat end avoid
oontect with toxic fumes or Imoke. Serf-contained breathing equipment (air pecks) il essential for
3O4/744.3487
This Itumblf is ovtillbde cloys, flights, wl~klflds, Offal hoiicllys.
Whim U~lofl Cl~i41e Agricultural l~O41UCtl Comla4fly, Inc. ~alleves fltet the (lite cofltll~ Mn ltl factual ma the o~4nlom exl)f~#~ iN thole
Air·cultural Pro4uct~ Com~ny, lac. lemamgg ~ reN)o~JHllty. Taey em Otfere~ Iotll), fur your r~nslcleratlofl, Inveltl#tloe eno verification. Any
Mee of tiao# 4ere Ift~l infurm~tlofl muir he la4~rmlfle4 IW tl~ ueet tm, ~e le Icr. o~4ence wltlt a4)p4ica~e Ire4efal, Irate an4 local laws encl relulatloas.
UNION CARBIDE AGRICULTURAL PROI)UCTI COMPANY, IN~ · P.O. BOX 17610
7~25 Beymeaclovll Way, Jickaonville, Flork~ 32216
FIRE FIGHTING' q~hout
PROCEDURES icj W~h thoroughly end immedl~dty w~th Isrge volum~ of
w~ing for ~ to omur.
(d) Be Jlert tot Iyn~otc~ of ~ng cludng the nm. ~ymploml may include I, Nmdm:h~, giddine~a,
al peltldde pole:ming mw be milll~m for heat ~ or lmolm inhllltlO~.
(elAvald ~mldng, drineing, or elting wldle fire fighting lO ii nm 1o ~ ~ ~
(fiMonitor lny warn' nmeff; dike eurmunding ama.
TLV AND 8OURCE: Emg,'Wt.~ (t~chnic~ gmt~yl! ACGIH
AGUTE EFFECTS OF OVEREXPOSURE
$~livltion, ~u~M, vomiting, heec~ohe, ebdomin~l ~lmp~, pinpoint
SKIN ABSOR~K)N None ~
INHALATION MW ~ ~ Ind ~ro~t inttltion.
~E CX)NTAC~ May ~euee eye irritalion, j~
CHRONIC EFFECTS ~ to ~ute ~l~ec~ but more ~evere and prolonged irritation of eyes,
OF OVEREXPOSURE m~, thro~ ~nd Ikn, tg~ mw occur.
OTHER HEALTH '°
HAZARDS ~ '-
EMERGENCY AND FIRST AID PROCEDURES: I
I
SWALLOWING Ind~l~
W~ w~ ~mp ~d w~t~, induding h~ir if oontmntn~L
SKIN Remove ~ny ~t~min~ted dolNng.
Irelveell ind rll~llld doel~ rely be neOllll? I0 mlJnllJn i~oplni~llbn. Ettecll of clrblqil Itldom IIII morl L'
8TABIUTY ' i
. UNSTABLE ~TABLE (X)NDmONS
TO AVOID NONE
'X
INCOMPATIBILITY Avoid ~nt~min~ion with ~lueou~ mineral ictcb and allmllel, c~rbon monoxide
- HAZARDOUS POLYMERIZATION
Mly Occur Will not Occur CONDITIONS
TO AVOID NONE
X
" EYE
PROTECTIVE GLOVES Plmtic o~ mbl~' PROTECTION Monogoggle~
'OTHER PFIOTECTIVE
PRECAUTIONS TO BE TAKEN IN HANDUNG AND STORING
CAUTION:KEEP OUT OF REACH OF CI.ffLDREN, HARMFUL IF INHALED OR SWALLOWED. Avoid I:w~thing of Nx~Y'. Do
no( IMm tnlernelly. Avoid conta~ with Mdn and eye~. Wear regular Iong-Ileeved wow ciMhing. Change ~ cIMn do(hing
Mly. WMh hancb and face before Miring. Wmd't thoroughly ~' h~ndflng.
AVOID CONTAMINATION OF FOOD, FEED, WATER SUPPUE$, STREAMS AND PONDS.
FOR INDUSTRY USE ONLY
OTHER PRECAUTIONS
~. ~:. 6l~m~ttemper~ur~ncXexc~eding 106"Fwh~herindoc~(,mallerconl~ne~)oroutdoo~(bulk.~le).
AG ~032
&10- 2M FtMIId in U.S.A.
U.S. DEPARTMENT OF LABOR -2.
OMB No. 44-R1387
Occupational Safety ~nd Health Administration
·
MATERIAL SAFETY DATA-SHEET
Required under USDL Safety and Health RegulatioO~ Ship Repairing,
Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)
SECTION I
MANUFACTURER'S NAME , i EMERGENC~ TELEPHONE NO.
Bell Laboratories, Inc.[ 608/241-0202
~~N-'~-~mber. Sgrcet.,City ,~b~te. ~nd ZIP C4~le)..
~o~ r. tnsman rove., '~namson, wi u.S.A. 53704
· CHEMICAL NAME AND SYNONYMS ~'~RAOE NAME AND SYNONYMS
Zinc Phosphide I ZP Tracking Powder
CHEMICAL FAMILY
Di-Phosphides J 10~
FORM'ULA
' SECTION II - HAZARDOUS INGREDIENTS
PAINTS. PRESERVATIVES. & SOLVENTS [ % Tt.V TLV
--., (U__r!!~is) ALLOYS AND METALLIC COATINGS % _(.Units)
PIGMENTS BASE METAL
CATALYST ALLOYS
VEHICLE METALLIC COATINGS
FILl_ER METAL .
SOLVENT= PLUS COATING OR CORE FLUX .-
-t --
ADDITIVES OTHERS --
OTHE RS
· TLV
HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS. OR GASES % (Units)
SECTION III - PHYSICAL DATA
BOILING POINT (OF.) N/^ SPECIFIC GRAVITY
PERCENT. VOLATILE
VAPOR PRESSURE imm Hg.) N/~6~
BY
VOLUME
VAPOR DENSITY (AIR=I) N/~l~ EVAPORATION RATE
I
SOLUBILITV IN WATER lnsolubl, ,.
APPEARANCE AND ODOR Lt. Garlic odor - Fine ~ey ~wder ,
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
I u.,
EXTINGUISHING MEOIA
'SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE AND EXPLOSION HAZARDS
PAGE (1) (Continued on reverse side) Form OSHA-20
Rev. May' 7~)
o .... SECTION V - HEALTH HAZARD DATA -'
£MERG~NC¥ AND FIRST AID PROCEDURES .
[f swallowed drink ! or 2 glasses'of'Water and lnduce'vomlttng by touching back °fl
Good
[n presence of Dilute Acids Phos0h~ne t8 liberated, .... - ' "" .. '
CONDITIONS TO AVOID
POLYMERIZATION . · ·
WILL NOT OCCUR ~X~
SECTION VII - SPILL OR LEAK PROCEDURES -..
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED .......
Clean up, General. "
WASTE DISPOSAL METHO~
Bury in approved landfill.
SECTION Viii - SPECIAL PROTECTION INFORMATION ... '..
RESPIRATORY PROTECTION [.~pecif. v type) None ,. "
VENTILATION LOCAL EXHAUST SPECIAL
None
MECHANICAL [GeneraO OTHER
None ....
PROTECTIVE GLOVES None .[ £~OTgCTION
OTHER PROTECTIVE E~UIPIVI~I~r
None
SECTION IX - SPEClIAL PRECAUTIONS
PRECAUTIONS TO BE;TAKEN IN HANDLING AND STORING
Do not contaminate water~ food or feed ,by storage or disposal.
OTHER PRECAUTIG%S
Keeo out of reach of children, pets and dome~:tic animals.
(2) '~ Form OSHA-20
GPO 130.$40 Rev. Ml¥ 7~
r.,Chernpar, ·
'.IPHA CHEMICALS, INC. CHEMPAR PRODUCTS DIVISION .660 MADISON AVENUE NEW YORK. NY
MATERIAL SAFETY DATA SHEET.
Required 'under USDL S~.et¥ seal HMIth:Regulation~ for Ship Rep~iring,
.. ~hipbuilding, end Shipbreaking (29 CFR 11)15, 1916, 1917)
SFCTION I
MANUFACTURER'S NAME ~ · ' I EMERGENCY TEi. EPeIONE NO.
LIPHA CHEHICALS, 'INC./CHEHPAR PRODUCT!; DlVlSl0NJ(212) 223-I}92 or 22]-1283
Madison Avenue, N~... Y.o. rk, #Y 10021
'C~EpI~CAL ,N.AM[ AND SYNRNY, M$ CULOROPU~C I NONE: . .. I TRADE NAME AND SYNONYMS
, Z-Lkp-cnloropnenyllpnen. y/ace[y/j~~ ,.~-inaanalone IROZOL BLUE ,TRACKING POVDER'
CHEMICAL FAMILY i FORMUI.~
Indandione ..J EmPirical: C23H1;;0~CI
SECTION II - H,~ARDOU$ INOREDIENT$
?L¥
PAINTS, PRESERVATIVES, & ~OLVENT8
(I,)fl~11) ALLOYE AND METALLIC COATINGS ~' (Units!
PIGMENTS BASE
CATALYST ALLOYS
V£1'~ICL.£ M£TALL;IC COATINGS
FILL. ER METAL
SOLVENTS PI. US COATING OR CORE FlUX
: .
ADDIT! ¢£S OTHERS
OTHE: R S
' TLV
HAZARDOUS MIXTURES OF OTHE~R LIOU1D$. GOLID$. OR GASES % (Units)
Product contains 0.2~ active pestlc'ide; balance being inert carrier
and dye. This is an anticoagulant rodentlclde.
SECTION III - PHY~;ICAL DATA
lOll. lNG POINT (BF.) 28~° IF ~[c~F~c GRAVITY (I'~30=3) 2
i~RCENT. VOL. ATiI.E
YAI)OR PRESSURE imm He.! : fl~)r~8 I¥ VOi. UME,(%)
YAI)OR DENSITY (AIR-3) EVAPORATION RATE
SOLUlILITY iN WATER
APP[A.ANC[~:)OOO. Blue Powder; odorless.
8ECTI'ON IV - FIRE AND EXPLOSION HAZARD DATA
,tiASH IK:)IHT ',Meth~ M14~,, Nofl-fla.~able. J FL.AMMAII.~ LIMITS !
[XTINGIJIIHINO MEDIA
UNUSUAl. FIRE AND EXPLOSION FIAZARD$
PAGE' (1! -... tContimml ea.mvera..Me) .-~ ~ r-on~ OSHA-20
.lle~. M/y 78
- . ' ~ SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
EfPECTSO~OVEREX~OSU~E Product is an anticoagulant and can cause .bleed lng,
I:MERGENCYANDFIRSTAIOPROGEDURES If O~n skin, wash with soap and water. If in eyes,
by touchlng back of throat ~ith finger. ~o not ~ive an~thin~ by mouth to an
uncons~ious person..Call a physician i~dlately. Administer Virgin K1 intra-
SECTION VI - REACTIVITY DATA
STABILITY C~DITIONS TO AVOID ' '
UNSTABle
STABLE X
INCOMPATABILITY (Maid'IS ~0 ~V~
'HAZARDOUS DE~OM~SIT~ON PRODUCTS
CONDITIONS TO AVOID
HAZARDOUS MAY OCCUR
~LYMERiZATiON ..
WIlL NOT OCCUR X
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
t~ash the area clean.
WASTE DISPOSAL METHOD Bury or discard in safe place away frc~ water supp]ies.
SECTION VIII ' SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION [$peci/~ I~J~) Vear dust respirator.
VENTILATION LOCAL EXHAUST : SPECIAL
MECHANICAL (C~n~1'41) OTHER
"PROTECTIVE GLOVES I EYE PROTECTION
Yes
·I None ind icat;e;J,
OTHER PROTECTIVE EQUIPMENT
SECTION IX - SPECIAL PRECAUTIONS
PRECA~rlONS TO IE TAKEN IN HANDLIN(~ AND STORING Wear gloves. Keep out of reach of
children, Avoid skin contact, Do 'not take Internally, Do not contaminate
OTHER PRECAUTIONS
PAGE (Z) Form OSHA-20
Meeting OSHA Standard 29 CFR § 19 f 0.1200 (g)
P.O. BOX 2235
Smyrna, Georgia 30081
EFFECTIVE DATE[: Nov. 25, 1985
PRODUCT TRADE NAME:-~BO~I~ ~
CHEMICAL NAME AND SYNONYMS: Boric Acid, Orthoboric Acid CAS NO: 10043-35-3
CHEMICAL FAMILY: Borate FORMULA: H=BO=
HAZARD RATING: NFPA: Health 0
Flammability 0
Reactivity 0
Material or Coml~onent % Material or Component
None
Appearance: white crystalline solid (Blue tint) pH ~ 20"C O. 1% solution 6.1
1.0% solution 5.1
Specific Gravity: 1.5128 , 4.72% solution 3.7
Melting Point: 170.9°C (340°.F) (saturated)
Heat of Solution ~ 18°C: 157 BTU/lb
Solubility in Water:
4.7% @ 20°C
27.53% @ 100°C
Soluble in some organic solvents
EFFECTS OF EXPOSURE (SYMPTOMS)
INGESTION:
............ ACUTE.ORAL LD~ (rats) 3..16 g/kg of bodY wei~ght; May_c~u_.s~__ ~n~.~..u~.~e~ .vomiting. dtan'hea in large doses ( 15 grams or..mpre).
EYE: (16CFR§ 1500.42) Not an eye irritant-may cause slight, reversible conjunctivitis.
SKIN: Not an irritant. No evidence of tissue damage. May cause slight irritation on damaged skin.
A(~UTE DERMAL LD~ (16CFR § 1500.40) Greater than 21 g/kg body weight (rabbits).
PRIMARY SKIN IRRITATION INDEX: ( 16CF § 1500.41 ) 0.1
CORROSIVE NON CORROSIVE: X
INHALATION Nuisance dust. May cause transitory sneezing and coughing.
ACUTE LC~ Greater than 16 mg/liter.
ACUTE OVEREXPOSURE/METHOD OF EXPOSURE/SYMPTOMS
Eyes -- may be slightly irritating as dry powder. Reversible.
Skin -- no penetration of intact skin. AbsorptiOn into blood stream through damaged skin may result in erythema, macular rash, CNS
effects slier 24 hours.
Ingestion -- large doses ( .~ 15 grams) may cause erythema, macular rash, di~rhea, nausea, dizziness and CNS effects after 36-72 hours.
CHRONIC OVEREXPOSURE/METHOD OF EXPOSURE/SYMPTOMS
Large amounts absorbed into blood stream from ingestion or through damaged skin may result in erythema, macular rash, nausea, diar-
rhea, dizzinesss, del~ression. No evidence of mutsgenic, oncogenic or teratogenic activity.
" OS~A Permissible Exposure UMIT (PEL) None Usted 29CFR § 1910 Subpart Z
ACGIH Recommended Threshold Emit Value None Usted ,
National Toxicology Program Annum Report on Carcinogens
Year 1983 Usted Not Listed X
International Agency for Research on Cancer (IARC)
Monograph Yes
No X
OSHA CARCINOGEN NO
EYES Flush with tepid water for 15 minutes.
SKIN Flush with water. If skin is damaged. drink large amounts o'f water or milk.
INHALATION Remove to fresh air.
INGESTION Induce emesis. Drink large amounts of water or milk. Consult physician.
NOTE TO PHYSICIAN Gastric isvage with 5% Sodium bicarbonate solution suggested for large amounts ingested. Saline cathartic. Force
fluids. Ringer's solution or normal .saline intravenously.
FLASH POINT (Method used) Not Applicable ..- .' FLAMMABLE UMITS I. el Eel
EXTINGUISHING MEDIA Not Required
SPECIAL FIREFIGHTING PROCEDURES None
UNUSUAL FIRE AND EXPLOSION HAZARDS None
Product is an inherenl fire retardant.
(
STABIUTY UNSTABLE CONDITION TO AVOID
STABLE X Will dehydrate at 100'C to 150'C.
INCOMPATABIUTY (materials to avoM) Acetic Anhydride; ~ntal Potasalum
HAZARDOUS DECOMPOSmON PRODUCTS None
HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR X
CONDITIONS TO AVOID Contact with Acetic Anhydride or elemental potassium.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPI~! ~:D
Sweep or vacuum followed by water rinse'.
WASTE DISPOSAL METHOD
Solid waste disposal site. Sanitary sewer for small quantities.
RESPIRATORY PROTECTION (Specify Type) Nuisance Dust Mask
VENTILATION LOCAL EXHAUST X SPECIAL
"MECHANICAL (General) OTHER
PROTECTIVE GLOVES None unless skin Is damaged. EYE PROTECTION Dust Goggles
OTHER PROTECTIVE EQUIPMENT None
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Dry indoor storage. Retain package Integrity.
U.S. DEPARTMENT OF LABOR Fo,,,, App,o,,,4
OMa No. 44-R13S1
OCcupational Safety and Health Administration
MATERIAL SAIFETY DATA HEET
R~quir~ under USDL S~f~ty ~nd He~lth R~18tion~ for Ship Re4iriq.
Shipbuilding, ~ ~ipbrflkin~ (29 CFR i91~, 1916,
· .SECTION I
MANUFACTURER'S NAME I EMERGENCY TELE~ONE NO.
~HITHIRE RESEARCH LABO~ATORI~;S, INC.I 31~-225-5371
AOORE$S (Number, Steer. Oty, $tete,*e~ ~P
3568 Tree Court Industrial Blvd.. Sc. Louts. ~0 63122
CHEMICAL NAME AND SYNONYMS I TRADE NAME AND SYNONYMS
Resme~hr~n (~ee below under hazardous m/xturee)l ' ?T 550
CHEMICAL FAMILY I ~OnMU~
Synthetic ~re~hro~dI 0.52 ResmethrlR
- EPA Reg. No. ~99.169
SECTION II - HAZARDOUS INGREDIENTS
PAINTS, PRESERVATIVES, & SOLVENTS ~ TLr TLV
(Vni~) ALLOYS AND METALLIC COATINGS % (Unlu)
PIGMENTS 8ASR META~
CATALYST ALLOYS
VEHICLE METALLIC COATINGS
FIL~ER
METAL
~US COATING OR CORE FLUX
ADDITIVES.. 4~ ~HERS
OTHERS
TLV
HAZARDOUS MIXTURES OF OTHER LIQUIDS, ~LIOS. on GASES % IUfllul
ResmeCh~tn (5-Senzyl-3-~l) HeChyl 2,2-Dtmechyl-3-(2-Hethylptopenyl) 0.5
c~c/optopanecatbo~late
SECTION III *, PHYSICAL DATA
BOLLING POINT (oF.) ~'l/a SPECIFIC GRAVITY (H2Oel) 0.93
PERCENT. VOLATILE
VAPOR PRESSURE (mm HE.) 310ZG=~.$ S¥ VOLUME: (%) W 90Z
VAPOR DENSITY (AIR'e() ri/A EVAPORATION RATE
( - 1 } zt/a
SOLUBILITY IN WATER ~[nso~..
APPEARANCE AND ODOR Sprays as a strong, dim/ ac(st with a slight odor
SECTION IV '- FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method used) IFL.~MMABLE: LIMITS I Lei [ Uti
NONE (ASTM Desigmation D-1310-SST: Tag I n/a
EXTINGUISHING MEDIA Open Cup)
SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE AND EXPLOSION HAZARDS
Form OSHA-20
EcTION'v - HEALTH HAZARD DATA
T. RESHOLD LIMIT V~LUE ' _ .
320 mg/H~ (approx. soI'n methOd)
EFFECTS OF OVEREXPOSURe
. ~VE .~ ~SH AIR. Treat S~p~omttcally
................. :: ....... SECTION VI - REACTIVITY DATA
VD not spr~ into open fla~~ or onto ve~ ho~
Indefinite .Th ~
usna. accorazn gSTAOCE -. '~' surfaces.
CO ~I:.ecclO~S
INCOMPATAeILITY (ll~te~ll to
HAZAR~US DiCOM~SITION PRODUCTS
:~e~l deComo0$iClon in Open flame ~v result in haloRen acidaa carbon dioxide
co.omo, s ~o .vom
.AZnnOOUS ~*V OCCUn
~LYMERIZATION
WILL NOT OCCUR
SECTION
VII - SPILL OR LEAK PROCEDURES I
STEPS TO BE TAKEN IN CASE MATERIAL IS RELE:ASEO OR SPILLED
(~4 If container begins to leak (thru puncture, etc.) alloy it to discharse completel,v
· in a veil-ventilated area, then dispose of in a safe place. In case of spillage
on. akin. 'rash ihoroughly vith soap mid Tater.
WASTE DISPOSAL METHOD
AerosoI cTiinder..is not. refillable, Do not attempt to recharge, Vhen cTlinder
18 exhausted, discard in safe place,, Do usc chrov in fire.
...... : ....................... SECTION VIII -" SPECIIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION ' ' '
· ~ liasplrator capable/~fd~'t~'~ring out 2-15 micron particles (See"Govt. Spec AI~ 33-7 ;-2)
LOCAL EXHAUST -., SPJ~ClAL
::V!~TI~ATIO~ None required ~ona required
:. : flone requzrea °~o~n~e required
P~OTECTIVE G~.OV~S I ~[[~E JPROTECT. ION
none requzrea aarecy szasses should be vor~
" :SECTION IX. SPECIAL PRECAUTIONS
'' PAECAUTIONS TO.SE TAKEN IN HANDLING AND STORINO
Contains-'coneentrated insecticide u~der pressure. ThereforeL 'do not: exnose Co
temperatures above 130er. Do not at:ore near heat or open fl'azaeL
OTHER PRECAUTIONS · ·
Do not contaminate vater, food or foodst~fs. Remove all pete. Cover fish
Can~ or remove. Avoid akin contact., Avoid inhalation..Ventilate area a~ter
treatment zs toepiece..
J
PAGE (2} Form OSHA-20
GPO I~.S~ Rev.
~ ..... U.S. DEPARTMENT OF LABOR Form Approwd
............ OMB No. 44-R1387
} Occu .pationa!-Safety and. Health AdministratiOn
! ......... *'MATE'RIAL' SAFETY 'DATA SHEET
Required under USDL Safety and Health Regulations for Ship Repairing,
....... Shipbuilding, and Ship,breaking (29 CFR 1916, 1916, 1917)
' :,.~:. ;'~".?. :..' : i'{'~; .. .. :"' SECTION I
; MANUFACT:URER'S NAMErI EMERGENCY TELEPHONE NO.
" .................. Wilco "'Dtstributors-;~'"'~j~'c'; ..............I (gn5 ) 735:?/,76
ADDRESS ()VI4/fib~, $/7~t,'Oty, S/gte;g/Id ~./~ Cod~) ...............
~' CHEM I C['AL"'NAM[ AND SYNONYMS ...... 8tr~;c~tz2e 'Alkal0~c] -
SECTION II - HAZARDOUS INGREDIENTS
TLV TLV
PAINTS. PRESERVATIVES, & SOLVENTS % (i.Jl~i~} ALLOYS AND METALLIC COATINGS %
(U.its)
PIGMENTS BASE METAL
CATALYST AL. LO¥S
· ..V,EHI~:LE. METALLIC COATINGS
i '" $O'LgENTS FIL. LER METAL
PkUS COATING OR CORE FLUX
ADDITIVES OTHERS
OTHERS , . .....
· : "* " ' ~ ' TLV
....... HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS. OR GA~ES % (Units)
"' . . 'sECTION' I ll 'PHYSICAL'DATA
.,. BOlUNG PO~N'r (_o.~.) ...: ............ _'..~ ............... _S. pEC~FJC G~_AVffy CP,30_"J! ................................
PE RC£NT, VOLATI CE:
VAPOR.PRESSURE (mm Hg.) ......... ~O]3.~ BM VOLUME (%)
EVAPORATION RATE
VAPOR DENSITY (AIR-I) ...... ]3.o1.1e ( -1) 'nolle.
SOLUBILITY IN WATER
APPEARANCE AND ODOR 'Green "(mtln~ ~-~4n 1/~', a4= ~4,,~+ A,,<~,,
SECTION.I¥'- FIRE AND EXPLOSION H.~.ARD DATA
FI-~SH POINT.~ .'.' (Method. ,'.' .:used) ,. Non-flammable FkAMMABI. E LIMITS ! L.el
EXTINGUISHING MEDIA
SPECIAL FIRE FIGHTING PROCIrDURF~
UNUSUAL FIRE AND EXPkO$1ON HAZARDS
PAGE (1) (Continued on rwe. dde) Form OSHA-,~
SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
EFFECTS OF
~tryehnir)4~m - condition of ~remh,'~[n_~ nr c~nvul~ve order
EMERGENCY AND FIRST AID Pk~CEDURES
Call a doctor. A~ister milk or ~ater freely.
~duce vomit~g ~y touch~g back of throat ~i~h f~ger. Do ~OT ~duce vomi~g
or give any~h~g by ~u~h ~o ~ ~conscious per~n.
SECTION VI - REACTIVITY DATA
STABILITY CONOII'IONS TO AVOID
UNSTABLE
STABLE X'
INCOMPAT.~BILITY [M~ter~ls to
None
HAZARDOUS OECOM~OSITION PROOUCTS
None
CONO,V,O~S TO AVO,O
HAZAa~US MAY OCCUa
~CYM~RIZAT~ON
WlCC NOT OCCUR X
SECTION VII - SPILL OR LEAK PROCEDURES
SVE~ TO BE TAKEN IN CA~E MATERIAL IS RELIV. A~EO OR SPILLED
Toxic to wildlife, do not contaminate water by cleaning area. Sweep area clean
and dispose of seeds by burial.
WASTE DISPOSAL METHOD
Dispose all seeds or wastes~by burial in safe place awa
from water supplies.
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION (,~¢i~ /~') None
VENTILATION LOCAL EXHAUST ~I~ClAL
MECHANICAL [G¢~Ig~"~/~/ OTHER
PROTECTIVE GLOVES NO I EYE PROTECTION NO
OTHER PROTECTIVE EQUIPMENT
SECTION IX o SPI-'CIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
See label. Kee~ out o.f the reach
of chLldren. Do not take internally.
OTHER PRECAUTIONS
PAGE (2) Form OSHA.20
Gf'O IX).S,40 Rev. M,.¥ 7~'
..... ~tional Safety I~d Health Adminbtrlti~a '
'MATERIAL SAFETY' DATA SHEET .
Required under USDL S4f~ly incl Heillh Regulations for Ship
/ Shipbuilding. and Shiiplxe~kif~29 CFR 1915. 1916. 1917)
- SECTION I
Los Angeles Chemical CompanyI ..,
· , /~.%.5 Ardine ~t...South Gate. CA ~02~0-1987
Gamma .isomer benzepe b¢~ch~or~e in xylene I ' Ltndane 1.0 E.G.
C~M,C~FAM,~.Y chlorinated hydrocarbon "1 ~O~MU~A C6H6C1.6+CsHi0 . , , ·
SECTION I! - MAZARDOU$ INGR£DIENT~.
PIGMENTS lAS[
CATAL. YST AI.I. OYS
VEHICI,.[ Id(:TALL,IC COATINGS
SOLvENTS×~lene CAS" ]330-20-T ~ 100 D~I.p,L.USCOATiNGOn¢OnE:FL.U
AOOITIVES OTHE RS
TLV
NAZAROOU~ MtXlIJRE~ O4~ Ol~IER 'UQUIO~. &OLI~. O~ QA~$
Hexac~orocyc~ohexane - ga~a i~omer CAS #~8-$~-~ ~.Z ~.~
· SECTION III - PHYSICAL DATA
· o,u~ ~o,~f'P.! 760 mm HI~ 275°F ~ !'S~c'~'con~v'TvINa°'~! 0.93
BY VOLUMe ~l 78.3
~dlLI%Y IN WATER emulsifia' ,le
~NK[ ~~ Mobile amber, li~utd~ .hTdrocarbon odor ,, ,
:.. ~ION W - FI~E ,~D ~PL~ H~D DATA
~ ~'~ (~ ~J 70°F (cc) F~ LIMI~ ~
IXTINUI~INMi~ ~oam, ca~bo~ d~ox~de, d~7 chem~ca~ ''
KI~ Pill WlQ~IN PI~I~ Co01 intact container6 with water
none
PAGE (1! ICeatt~.d .. feve,..kkl · F.n. OSHA-20
122
: SECTION V - HEAL fH HAZARD DATA
Tfi~I~$flOLJ)/,~IMITYdM. U~ oral LDso(Rats) 125 rog/kg
'~'gc~s of OV~gx~E Hucous membrane -irritation, headache, nausea, abdominal pain
- ~tver and kidne~ damage, possible dermatitis
f,.M(J~G(J~C¥ MO Ill'ST AID
Skin: F1u.sh with soap and water, ll~es: Flush rich rater for at least 15.minutes.
Inhslltinn! ~emove to fresh air. In~estion: Induce vomitinl and ~et i~edi'ate '
.., medics1 stren~ion for all overexoos~res, . ,
ST~lU~ CC~S TO AVOID
sT~ X
~ZAA~ DEC~ITI~Pn~TS ~OX~C and acrid fumes Lf involved Ln a fire,
~ION VII - ~1~ OR LEAK PR~EDURES
Take Up on aavdust, evaporate tn 1solaced area, burn sawdust in /nc/negator.
Arnm~e to ~nctnerator,
SECTION VIII - SPECIAL PROTECTION INFORMATION
.C"-'~,~ATON¥. · fnOTgCTm~ ~/~ f~eJUse, - approved respirator to avoid breathtnR mist.
~i~T~ G ~T
. General room ventilation
PAOT~,VS ~v~ Impervious I M KT~ Ch~tcal safety
OT~ ~T~lvs ~~T
~~ ~., ~EC~ PRE~I~
P.E~~ TO ~ T~ ~ ~ ~ STOi~ ' '
~ Store tn ~ool p~ce~ ~w~ fro~ oxt~ers
o,~.~e~-~ Foll~ label directions and cautions carefully.
'- A T E'R I A [:~ $ A F E T Y D A T A S H E E T PAGE: t
DOW CHEMICAL"U.S.A..MIDLAND MICHIGAN 48640 EMERGENCY PHONE: 5t7-636-4400
EFFECTIVE"-'~DATEi 24 FEB 83 . PRODUCT CODE: 26e66
PRODUCT NAME: DURSBAN ,(R) L.O. INSECTICIDE HSD: t556
INGREDIENTS (TYPICAL VALUES-NOT SPECIFICATIONS) : % :
O,O,-DIETHYL O-(3,5,6-TRICHLORO-2-'F'YRIDYL) : :
F'HOSF'HOROTHIA~E, (CHLORPYRIFOS) : 41.5 :
XYLENE RANGE AROMATIC SOLVENT : ii.5 :
INERTS : 47.0 :
SECTION I PHYSICAL DATA
BOILING POINT: 298F, t4~C : SOL. IN WATER: EMULSIFIES
VAF' PRESS: 24 MMHG ~ 48C : SP. GRAVITY: t.t6
VAP DENSITY (AIR=t): : % VOLATILE BY VOL APPROX.
,RANGE AND ODOR: CLEAR LIQUID WITH AROMATIC TYPE ODOR.
SECTION 2 FIRE AN~ EXPLOSION HAZARD DATA
FLASH POINT: t~F, 50C : FLAMMABLE LIMITS
METHOD USED: TCC : LFL: t% -UFL: 6% (XYLENE)
EXTINGUISHING MEDIA: WATER SPRAY, CARBON DIOXIDE, AND DRY CHEMICAL.
sPECIAL FIRE FIGHTING EQUIPMENT AND HAZARDS: FOAM SYSTEM IS PREFERRED.
USE POSITIVE-PRESSURE BREATHING APPARATUS. TOXIC IRRITATING GAZES
MAY BE FORMED. RAPID DECOMPOSITION ABOVE..t60-200C. VIOLENT RUPTURE
OF CONTAINERS DUE TO OVERPRE$$URIZATION MAY OCCUR.
SECTION 3 REACTIVITY DATA
STABILITY: AVOID HEATING ABOVE 54C, t3OF TEMPERATURE FOR MORE THAN TWO HOURS.
CHLORPYRIFOS UNDERGOES EXOTHERMIC DECOMPOSITION WHICH CAN LEAD TO
HIGHER TEMPERATURES AND VIOLENT DECOMPOSITION IF HEAT DEVELOF'ED IS NOT
REMOVED. .CONTAINS PETROLEUM DERIVATIVE SOLVENT - WILL BURN.
INCOMPATIBILITY: UNSTABLE AT PH ABOVE tO. CONSULT MANUFACTURER FOR
SPECIFIC CASES
~RDOUS DECOMPOSITION PRODUCTS: HY)DROGEN CHLORIDE, ETHYL suLFIDE, DIETHYL
FIDES AND NITROGEN OXIDES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.
(CONTINUED ON PAGE 2 )
(R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
.I>OW C'H£MICAL U.S.A. MIDLAND MICHIGAN 48640 EMERGENCY PHONE: 5t7-636-4400
EFFECTIVE DATE: 24 FEB 83 PRODUCT CODE: 26066
PF 'CT (CONT'D): DURSBAN (R) L.O. INSECTICIDE HSD: t556
SECTION 4 SPILL, LEAK, AND D][$F'OSAL PROCEDURES
ACTION TO TAKE FOR SPILLS: ~B$ORB SPILLS
WITH MATERIAL SUCH AS SAND'° WASH EXPOSED BODY AREAS THOROUGHLY "
AFTER HANDLING. CONTAIN SPILL BY DI)~ING TO KEEP OUT DF SEWERS.
FOR LARGE SPILLS, 'BARRICADE AREA, ELIMINATE IGNITION SOURCES, AND
CONSULT.~ANUFACTURER.
]DISPOSAL 'METHOD: DO NOT CONTAMINATE FOOD, FEED, OR WATER BY STORAGE
OR CLEANING OF EQUIPMENT° OPEN BURNING IS PROHIBITED.
PESTICIDE, SPRAY MIXTURE OR RINSE WATER THAT CANNOT BE USE~
ACCORDING TO LABEL INSTRUCTIONS MUST BE DISF'OSED OF ACCORDING
TO APPLICABLE FEDERAL, STATE OR LOGAL F'ROCEDURE$. IF BURIAL
IS PERMITTED; BURY iN ISOLATED, NON-CROF' LOCATION AWAY FROM
DOMESTIC OR NATURAL WATER SOURCES. KEEF' OUT OF DOMESTIC OR
NATURAL WATER SOURCES.
SECI'ION 5 HEALTH HAZARD DATA
EYE: MODERATE IRRITATION AND CORNEAL INJURY; EFFECTS SHOULD HEAL WITH TIME.
SKIN CONTACT: PROLONGED CONTACT: MODERATE IRRITATION.'
$1,x.~.' ABSORPTION; LDSO RABBIT )50~ MG/KGo LOW TOXICITY.
INCI:.$1'ION: P~Oi)ERATE SINGLE DOSE TOXICITY; LDSO MALE RATS 5~ MG/KG, FEMALE RATS 834
INHALATION: ACGIH TLV ~.2 MG/M3 CHLORF'YRIFO$, te~ PPM XYLENE.
~Y£TEMIC & OTHER EFFECTS: DROWSINESS (SOLVENT); CHOLINESTERASE ~,,Hi~:~:T~U~ (CHLORPYRIFO$).
SECTION 6 FIRST AID .-
~Y£~: I~RI~A'IE WITH FLOWING WATER IMMED]:ATE~Y AND CONTINUOUSLY FO~ ~ iiii'4UT£$. CONSULT MEDICAL PERSONNEL.
;KIN: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF W~TER FOR AT LEAST t5 MINUTES WHILE REMOVINg. CONTAMINATED CLOTHING
AND SHOES. CALL A PHY£ICIAN IF IRRITATION F'ER$I£T$. WASH
CLOTHING BEFORE REUSE. DESTROY CONTAMINATED SHOES.
NGESTION: DO NOT INDUCE VOMITING. GIVE: LARGE AMOUNTS OF WATER
OR MILK!~F ~VAILABLE, AND TRANSPORT TO MEDICAL FACILITY. :.....
.~.~.
NHALATION: REMOVE TO FRESH AIR IF EFFECTS OCCUR. CONSULT MEDICAL.
D'{ l'O F'H¥~ICIAN:
.~L .$: MAY CAUSE CORNEAL INJURY OR BURN. STAIN FOR EVIDENCE OF
~CORNEAL INJURY. IF CORNEA IS BURNED INSTILL ANTIBIOTIC ~TEROID
PREPARATION FREQUENTLY. CONSULT OPHTHALHOLOGIST.
SKIN: MAY BE SLOWLY ABSORBED. CHRONIC LOW GRADE EXF'OSURE MAY RESULT
~ONTINUED ON PAGE J )
~) INDICATES A TRADEMARk.OF THE DOW CHEi~ICAL COMPANY
..... 'MATERIAL SAFETY DATA SHEET PAGE:3
DOw"C~EMICAL U.S,A, MIDLAND MICHIGAN 48640 EMERGENCY PHONE: 5t7-636-440~
FPCTIVE DATE: 24 FEB B3 PRODUCT CODE: 26e66
CT (CONT'D): DURSBAN (R) L.O. INSECTICIDE MSD: t556
SECTION'6 FIRST AID (CONTINUED)
NOTE TO PHYSICIAN: (CONTINUED)
IN ILLNESS, '"~ ~'~'
RESPIRATORY: VAPORS OR MISTS MAY DEl TOXIC IF PRODUCED,
ORAL: MAY CAUSE REACTIONS SIMILAR TO PETROLEUM OR PETROLEUM-LIKE
SOLVENT, IF LAVAGE IS PERFORMED SUGGE£T ENDOTRACHEAL AND/OR
E$OPHAGO$COPIC CONTROL, DANGER OF CHEMICAL PNEUMONIA MUS~ BE
WEIGHED AGAINST TOXICITY WHEN CONSIDERING EMPTYING THE STOMACH..
SYSTEMIC: MAY PRODOCE ORGANO-PHOSPHORU$ TYPE CHOLINESTERASE
INHIBITION. ATROPINE BY INJECTION I$ ANTIDOTE OF CHOICE. OXIME$
MAY OR MAY NOT BE THERAPEUTIC, BUT MUST NEVER BE USED IN PLACE OF
ATROPINE.
SECTION ? SPECIAL HANDLING INFORMATION '
VENTILATION: RECOMMEND CONTROL OF XYLENE AND CHLORPYRIFO$ TO SUGGESTED
GUIDES.
RESF'IRATORY PROTECTION: APPROVED ORGANIC VAPOR-TYPE RESPIRATOR REQUIRED
IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL.
PROTECTIVE CLOTHING: RUBBER GLOVES, BOOTS, APRON, GAUNTLETS DEPENDING
aN THE EXTENT AND SEVERITY OF EXPOSURE LIKELY.
~ F'ROTECTION: CHEMICAL WORKERS GOGGLES.
SECTION 8 SPECIAL PRECAUTIONS AND ADDITIONAL INFORMATION
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: --~-
ADDITIONAL INFORMATION: 24 FEB 83 REVI~ION$, INGREDIENTS AND PHYSICAL DATA.
LAST PAGE
(R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
THE INFORMATION HEREIN I$ GIVEN IN GOOD. FAITH, BUT NO WARRANTY,
EXPRESSED OR IMF'LIED, IS MADE. CONSULT'THE DOW CHEMICAL COMPANY
FOR FURTHER INFORMATION.
· .,.~.A T E R I A-L .'$'A F El T Y D A T A $ H E E T PAGE: i
DOW CHEMICAL-,:U.$,A. MIDL~ND MICHIGAN 48640 EMERGENCY PHDNE:.St?-636-440~
EFFECTIVE ~ATE.: ~t AUG ?? PRODUCT CODE: 26~5
~'RODUCT NAME: DURSBAN (R) 2E INSECTICIDE MSD: 0223
,.~GREDIENT$ (TYPICAL VALUES-NOT SF'ECIFICATION~) : .% :
ACTIVE INGREDIENT: ' : :
CHLORPYRIFO$ ¢O,O'-DIETHYL O-(3oS,6-TRICHLORO-2- : :
F'YRIDYL)F'HOSPHOROTHIOATE! : 22.4 :
AROMATIC PETROLEUM DERIVATIVE SOLVENT (XYLENE) : 42.i :
' INERT INGREDIENTS: : :
EMULSIFIERS AND CHLORINATED SOLVENT (METHYL : :
CHLOROFORM) ': 35.5 :
SECTION t PHY.~ICAL DATA
BOILING POINT:-t4eC (XYLENE)***** : SOL. IN WATER: EMULSIFIABLE
l e&xte-5, MHHG ~ 2ec : sP. GRAVITY: t.eTe
V~(,~ JEN£ITY (AIR=i): NOT APPLIC. : Z VOLATILE BY VOL': 74
APPEARANCE AN~ DOOR: YELLOW LIQUID. · #~**BDILING POINT: 73-84C (METHYL CHLOROFORM)
· VAPOR PRE$£URE: FOR CHLORPYRIFO$'
SECTION 2 FIRE AND EXPI_O$ION HAZARD DATA
F;.,r~!'; F',.~.T~?T (~) BIF (2) 88F : FLAMMABLE LIMITS
METHOD USED: (t) TCC (2) TOC : LFL: NOT DETER. UFL: NOT DETER.
~V~"$'~"'F~'r MS'IA: FOAM, CO2, DRY CHEMICAL..
SPECIAL FIRE FIGHTING EQUIPMENT AND HAZARDS: FOAM SYSTEM I$ PREFERRED.
USE SELF-CONTAINE~ AIR SUPPLY. VIOLENT ERUPTION DF CONTAINERS MAY
OCCUR. TOXIC IRRITATING GASES MAY BE FORMED. RAPID DECOMF'D$ITIDN AT
t6e'-200C~
SECTION 3 REACT][VITY DATA
,$TABILITY~.PETROLEUM DERIVATIVE SOLVENT - WILL BURN. ..,.
CONSULT MANUFACTURER FOR SPECIFIC CASES ..... ~ ,.
' ,~.,.HK,~:':!';DOU£~ DECOMPOSITION PRODUCTS: ON HEATING WILL DECOMPOSE TO FORM
~ ¥OLATILE, FLAMMABLE, ODOROUS ORGANIC SULFATES.
(CONTINUED ON PAGE 2 )
(R) iNDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
.i ;.'.?.~ ' M fl T E R I A L $ A F E T Y D A T A $ H E E T PAGE: 2
DO~ ~MI~AL U.S.A. MIDLAND MICHIGAN 48640 EMERGENCY PHONE:
c;:~'?:EEFECTIVE DATE: 0t AUG 79 PRODUCT CODE: 26005
PRF"~CT (CONT'D): DURSBAN (R) 2E INSECTICIDE .HSD: 0223
~:;' SECT%ON 3 REACTIVITY DATA (CONTINUED)
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR. FLAMMABLE. STORE
AT AMBIENT.'.TEMPERATURE~,. '- ..
sEcT.~ON'4. .'SPILL, LEAK, AND DISPOSAL PROCEDURES
- ACTION.'¥ TA E FOR SPILLS: CONFINE
'"'~ SPILLS,' 'ELIMINATE IGNITION SOURCES. ABSORB SPILLS WITH DRY-
· ' MATERIAL SUCH AS SAND AND SWEEP UF' FOR DI£POSAL.. FOR LARGE
:' ' SPILLS, BARRICADE AREA AND CONSULT MANUFACTURER,
DISF'OSAL METHOD: BURY CLEANED UP WASTE IN LOCATIONS'AWAY FROM DOMESTIC
WATER SUPF'LIE$.
SECTION 5 ~ HEALTH HAZARD DATA
EYE: MAY CAUSE SEVERE IRRITATION AND MODERATE CORNEAL INJURY
WHICH SHOULD HEAL IN 1-2 WEEKS.
SKIN CONTACT: MAY CAUSE MILD TO MODERATE IRRITATION
UPON PROLONGED CONTACT, POSSIBLY A BURN UPON REF'EATED CONTACT.
SKIN ABSORPTION: MAY BE ABSORBED IN TOXIC AMOUNTS, BUT IS LOW IN
. ICITY BY THIS ROUTE. LB50 RAB])IT 4000 MG/KG. SHOULD NOT BE
,-'ROBLEM UNLESS A GRO~£ EXPOSURE OCCURS.
· .'INGESTION: MODERATE ORAL TOXICITY. LD50 (MALE RAT) 94t MG/KG; (FEMALE RAT) 620 MG/KG.
INHALATION: TLV: CHLORF'YRIFO$; G.2 MG/CUBIC METERS (1977). TLV:
XYLENE; t00 PF'M (t977). TLV:METHYL CHLOROFORM~ 35G F'F'M (t977).
SYSTEMIC & OTHER EFFECTS: CHOLINERG][C EFFECTS, SYSTEMIC AND RESPIRATORY
-'" INTOXICATION, NAUSEA, TROUBLED BREATHING.
£ECTID).! 6 FIRST AID ' --
'-EYES: IRRIGATE WITH FLOWING WATER IMMEDIATELY AND CONTINUOUSLY FOR FIFTEEN MINUTES. REFER TO MEDICAL PERSONNEL.
· SKIN: IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF
WATER FOR AT LEAST t5 MINUTES WHILE REMOVING CONTAMINATED
CLOTHING AND SHOES. CALL A PHYSICIAN. WASH CLOTHING BEFORE
REUSE. DESTROY CONTAMINATED SHOES.
INGESTION:'DO NOT INDUCE VOMITING. CALL A PHYSICIAN AND/OR TRANSPORT
TO EMERGENCY .FACILITY.
INH^'.ATION: REMOVE TO FRESH AIR IF EFFECTS OCCUR. CALL PHYSICIAN
"'/OR TRANSPORT TO MEDICAL FACILITY.
(CONTINUED ON PAGE 3 )
(R) INDICATES A TRADEMARK OF THE DOW CHEMICAL COMPANY
'° M A T E R I A L $ A F E T Y b A l' A $ H E E 1 h'Ab~:
';~""-~:~: DDW Cl'IEiM~CAL UJ$.A. MIDLAND'MICHIGAN 4B64~ EMERGENCY F'HONE:..StT-636-44~
~.,".{~.¥ PRPqUCT (CONT'D): DURSBAN (R) 2E IN$ECTICIDE MSD: G223
-. - ~? SECTION 6 FIRST ~IID (CONTINUED)
' NOTE TO PHYSICIAN: -' ... "
'/,'""i: EYES: ~MAY. CAUSE CORNEAL.INJURY [IR BURN, STAIN FOR EVIDENCE OF
~.~::. -.L.CORNEAL INJURY,":"IF CORNEA IS BURNED, INSTILL ANTIBIOTIC
'~'~:~;i "STEROID PREPARATION FREQUENTLY, CONSULT OPHTHALMOLOGIST,
". '.. SKIN: ' TREATA$ ANY CONTACT DERMATITIS, IF BURN IS PRESENT, TREAT
· .-.-~/ AS ANY THERMAL.BURN.
.... "~- RESPIRATORY: MAY CAUSE MODERATE IRRITATION.
"-~ii..~ ORAL: TOXIC BY INGESTION, MAY CAUSE REACTION SIMILAR TO PETRO-
LJ'.- LEUM OR F'ETRO£EUM-LIKE SOLVENT, MAY CAUSE CHEMICAL
'.' "~' PNEUMONIA IF ASPIRATED INTO LUNGS IF LAVAGE IS PERFORMED
· ": 'SUGGEST ENDOTRACHEAL AND/OR E$OPHAGO$COPIC.CONTROL.
? SYSTEMIC: MAY PRODUCE ORGANO-PHOSPHORU$ TYPE CHOLINESTERASE INHI-
BITION, AT~OPINE,-ONLY BY .INJECTION, IS ANTIDOTE OF CHOICE, OXIME$
MAY. OR MAY NOT BE THERAPEUTIC, BUT MUST.NEVER BY USED IN PLACE OF
'L' ATROPINE. MAY~.CAU$E NAUSEA OR VOMITING. MAY CAU$E HEADACHE. MAY
'~:' INCREASE.MYOCARDIAL.IRRITABILITY, (SOLVENT EFFECT), AVOID EPINE-
PHRINE OR SIMILAR ACTING DRUGS IF AT ALL F'O$£IBLE. CONSULT STANDARD
LITERATURE, TREATMENT BASED ON THE SOUND JUDGMENT OF THE PHYSICIAN
AND THE INDIVIDUAL REACTIONS OF THE PATIENT.
SECTION ? ~F'ECIAL HANDLING INFORMATION
VE~,--'LATION: RECOMMEND CONTROL OF VAPORS TO SUGGESTED GUIDES.
RE~F'IRATORY PROTECTION: NONELIKELY TO BE NEEDED DURING ANTICIPATED
OF'ERATION$.
'" ".~PROTECTIVE CLOTHING: CLEAN, BODY-C[IVERING CLOTHING.
""' EYE PROTECTION: CHEMICAL WORKERS GOGGLES,
:'~ ...... '' SECTION 8 SF'ECIAL PRECAUTIONS AND ADDITIONAL INFORMATION
"'~i~ PRECAUTIONS TO BE'TAKEN IN HANDLING. AND"$TORAGE: CHECK LABEL - KEEP
~' OUT OF REACH OF CHILDREN. DO NOT SWALLOW, DO NOT GET IN EYES OR 'ON
/- SKIN. AVOID BREATHING MIST OR VAPORS." KEEP AWAY FROM HEAT AND OPEN
..... FLAME, HANDLE CONCENTRATE IN A VENTILATED AREA, WASH THOROUGHLY
.:.~ . AFTER HANDLING. DEPENDING ON DEGREE OF EXPOSURE OF F'ER$ONNEL,
CON£IDER MONITORING BLOOD CHOLINESTERASE LEVELS. IF IN DOUBT SEEK
ADVICE OF EXPERIENCED INDIVIDUALS. KEEP AWAY FROM FOOD, FEEDSTUFF$
AND DOMESTIC WATER SUPPLIES.
ADDITIONA~ INFORMATION: REVISIONS 8/t/77 -- NOTE TO PHYSICIAN,
: .. '. LAsT PAGE
2."(R) INDICATES 'A TRADEMARK OF THE DOW CHEMICAIC COMPANY ~'" ~"
THE'INFORMATION HEREIN I$ GIVEN'IN GOOD FAITH, BUT NO WARRANTY~
--i EXE'RE$$ED OR IMPLIED, IS MADE. CONSULT THE .DOW CHEMICAL COMPANY
F£~!:i~'URTHER~ INFORMATION.,
":::* ' ' ' ',"' ' . OccuPatiOnal salrety and Health Administration
MAIERIAL SAFETY' DATA SHEET ..
I. ' - Required under USDL Sifetv and Health Regulal;ont for ~hip Repairi~.
~ipbuilding. and Shil>breaki~ (29 CFR 1915, 191~. 1917)
' ! ' ~ · "*: .... ' * SECTIONI .. ' Chemtrac 800/42~_9~.
IVan Waters & Rogers . - J(408) 263-9900 .
'lBox. 5932 San Mhteo.-. California 94403 · . ' .
I ~EMJCAL FAMILY ' - ~ ' ' / FORMULA .
lmethvl-4-py~imi~invi) phosphor?thi~ate * *. ' ·
, .. SECTION If - HAZARDOUS INGREDIENTS
PAINTS. PRESERVATIVES. & SOLVENTS % TLV .
. ~ . ;[~_ ALLOYS AND METALLIC COATINGS ~JJ TLV
CATALYST ALLOYS
_ ,,
VEMICL[ METALLIC COA~INGS
--5
HAZARDOUS MIXTURES OF OTidER LIOUIDS. SOLIDS.* OR GASES
Xylene =anqe a=omatic solvent . 3~._l.~,om
.... SECTION IIII. PHYSICAL DATA '~: ...... - "*
SOCU,,c,T~ ,~ w~,cA Emul ~ifiable
~:';' { ...... ~.~
..' A""C~"~C:[A~D°D°"Light tan to brown ]~qu~~~.~r-]~P
:/' ' SECTION IV . .FIRE AND EXPLOSION HAZARD DATA
[XTINGUISI~ING MEDIA '.
UNUSUAL FIRE AND EXPLOSION t~AZARD5
PAGE (1) (Con,inu,,d on rever~ side)
SECTIONV - HEALTH HAZARD DATA
.THR[~,HOLO LIMIT VALUEr
Acute aerosol inhalation LC SO (rat):~.ZSmo/I alt.
[FF[CT~, OF Ov£1~r. xeC)$ula£
See qeneral formal;, . ,
SECTIONVI · REACTIVITY DATA
8q'ABILITY' 'C:Oe~DI*rlONS TO AVOID
L)NST ABL, Ir
--~Z~DOuS DtC'O~;O~,~,O~P~0~uC*~ Ka~,ed on s~Orape Stabi i ity .~ th smal 1 am un
' ' CONDITIONS TO AVOID
~'ILL NOT OECOg
SECIIONVll - SPILLOR LEAK PROCEDURES
SECTION VIII - SPECllAL PROTECTION INFORMATION
~ c c ~ e~ c r~_o~ ma~ ._
J
OTH[R PROI[CTIv[ EQUIPMENT
SECTION IX - SPECIAL PRECAUTIONS
PF)£CALJTIOr'~'S, TO BE TA.K£1~r IN HANDLING A~O STORING
~-: ..... 5 ~. e ~.r~_J~ma t ~
~ OTI~ER PRLCAUTIONS-- --
PAGE (2) Folm OSH.~,.20
GENERAL FORMAT .
ORGANOPHOSPHATE INSECTICIDES - MAT£RIAL SAFETY DATA SHEET
IV FIRE AND EXPLOSION DATA
Extinguishing Media: Fo~,m, dry chemical, CO2 ·
Special Fire Fighting Procedures: Foam system prefer'red. Use self-
contained air sHpply. Treat the same as an oil/gasoline/cheri-
cai type fire where vapors and d~scharges to the environment
are to be contained and reduced as quickly as p0ssibl~.
Unusual Fire and Explosion Hazard: Upon heating or burning this
product may 'form irritating/toxic g~ses. Violent eruption
of containers may also occur.
V HEALTH HAZARD INFORHATION
Effects of Overexposure:
Acute: Headache, blurred vision, n~rvousness, wea'kness, nausea,
cramps, salivation, respiratory difficulty, muscle
twitches, convulsions, loss of reflexes.
Chronic: Cholinesterase'~nhlbition. Severe overexposure coul¢
produce acute effects.
Emergency.and First Aid Procedures:
Eyes: Imn~diately begin flushing eyes with plenty of iow
pressure, flowing water for at least 15 minutes. Get
· medical attention.
Skin: Immediately begin flushing skin with plenty of water
while removing contaminated clothing, shoes and perso-
General Format
Organophosphate Insecticides-Material Safety Data Sheet
Page Two of Four
hal articles,. Continue flushing operation for at lea~t
I~ minutes, using ~oap if available. Wash contaminate~
clothing before reuse. Destroy co. ntaminatea shoes. ·
Inhalation: Remove to fresh air, it' effects occur. Get mad;cai
" ~ assistance,and/or transport to medical facility. Apply
respiration if indicated.
Ingestion: Get immediate medical assistance. Gastric lav~ge is
indicated if material was taken internally. DO ROT INDUC[
VOMITING unle~ss other treatment is not available.
may cause aspii rat ion pneumonia.' It' it is necessary to in-
duce vomiting,, give victim one or two glasses of water
and insert fir~ger in bact: of throat, or, give syrup
ipecac under the guidance of medical authorities. Do
induce vomiting or give anythi'ng by mouth to an unconscious
person.
Notes to Physician: ..
Atrophine !s antidotal pro~vided it is used as soon as early
poisoning symptoms appear and the dose of this product ~s not
too gre.at. It is important to give large dosages of atropine.
In severe cases of poilsoning, proceea as follows: (I) artificial
respiration; (2) Atropine sulfate, 2-q m9. i~v. at 5- 10- minute
intervals until atropinlzation; (3) 2-PAH slowly i.v. (1 g. for
aduits,.O.2$ 9 for infants) if patient fails to respond to
atropine; Lavage stomach.
General Format
Organophosphate InsecticJdes-Haterial, Safety'Data Sheet
Page Three of Four
VI. REACTIVITY DATA
Conditions Contributing to Instability: Combustible. Do not over-
heat. Do not freeze. Store at ambiant temperatures. Protect
from moisture.
In'c~mpatibility: Avoid contamination with water, bases, and alkalies.
~Hazardous' Decomposition Products: '(see individual form).
Conditions Contributing to Hazardous Polymerization: Will ~ot occur.
VII DISPOSAL, SPILL OR LEAK PiROC£DURES
Aquatic Toxicity: (see individual form)
Waste Disposal: Reclaim. Burn in approved incinerator. Dispose of
in landfill approved for pesticides. Bury in a safe place ~way
from water supplies.
Steps to Be Taken if Material is Released' or Spilled: Ei'iminate
ignition sources. 'Shut off leak if it can be done safely.
Dike. Remove ilquld'by pumping into salvage tank. Soak up
residues or small spills with absorbant such as "kitty litter"
Put in tight container. Decontaminate spill area with agents
listed below and detergent. Keep material out ~f sewers 'and
waterways.
Neutralizing Chemicals: Bleach, sodium hypochio.rite solution or
weal: alkali.
VIII SPECIAL PROTECTION INFORMATION
Ventilation Requirements: As required to keep vapor concentration
below TWA (TLV).
General Format
Organophosphate Insecticides-19aterlal Safety Data Sheet
Page Four of Four
specific Personal Protect'ire EquSpment: None likely to be needed
during anticipated operat-ions.
Respiratory (specify in detail): For protection in unusual
cases, a respirator approved by NIOSH for
is recommended. ,
Eye: None likely to be needed during anticipated operations. In
cases where likelihood of eye ~:ontact is present, chemical
~vorker's goggles are recommended.
Gloves: Impervious neoprene gloves recommended.
Other Clothing and Equipment: Ordinary conditions typ;ca'lly require
only clean body coverings.. Special circumstances may require
"rain-gear°'.
SPEC IAL PR£ CAUT I Ot,'S
Frecautionary Statements: ConSult label. Keep out of reach of childreo~
irresponslble persons, and pets. Do not take internally. Do not get
eyes, on skin or clothing" Avoid breathing spray mist or vaoors.
Other Handling and Storage Requirements: Consult label. Combustlble
mixture: Do not use, pour, spill, or store near heat or open flame.
Keep container closed. Hanclle concentrate in a ventilated area. ~/ash
thoroughly after handling and before smoking'or eating. Depending on
degree of exposure of personnel, consider monitor'ing bloo0 cholineste-
rase levels. If in doubt, :Leek advise of experienced individuals. Keep
away from food, feeds, clol:hing and domestic water supplies.
· RF- 245
A Dtvtson of Zoecon Corporation
... ' Dallas, Texas, 75234
*:; .~ H A T E,,R,Z~A'L .S A F,E T:¥. D A T A S H E E T
(Approved by U.S. ~Par~ent of; Labor es "Essentially Simi]ar".,t~ Fom OSHA-20)
'A;' 'PRODUCT ~DENTZFZ~TiON
TRADE ;N~E: SafrotJn '~ulsifJble Concentrate ]nsect, Jcide
CHEHZCAL ,N~E (and synon~s): , Propet~phos ,,
~HOLECUL~..~O~ULA.OR DESCRZPTZON: .,.,. Organophosphorus ~nsecttcJde
: .....' ?::':i: Page, 1 of 5
.~gJ'O t 6 lg84
: =' Unknown , ,,
VAPOR DENS[TV (atr· I): Unknown , ,
MOLECULAR I/EIGHT: , N/A
SOLUBILITY [N ICATER: Form:; mtlkY Whtte emUlston
......... PERCENT*' VOLATILE (by 'vq I uae ) :: ...... 38
EVAPORATION RATE:""*""'*"Unknown'--' '-
..... APPEARANCE ANO O00R:*' .. Ltght' Yellow t° brown
O. FI~E ANO EXPLOSION HAZARO OATA
FLASH POINT (Method): 114°C (TCC), 126.6°C- (TOC)
I~CA~t4AeLE.. CIa.ITS (~ b~¢ volume): upper - unknown
lower - unknown
EXTINGUISHING MEoIA: Ory Chemical, Halon, .'alcohol foam,' carbon dioxide, water
.:. :. :~..-AU~TOIGNITIoN TEMPERATURE:.. 'Unknown
..SPECIAL FIRE 'FIGHTING -PROcEOUREs:
........ i~hen'entertng, area where 'SafrotJn Js exposed to fire, wear' P°sJttve pressure
self-COntained breathing apparatus.
UNUSUAI~..'~'~RE.'.ANO EXPLOSION HAZAROS.: Not known
Page.2 of 5,
· . ., "'. ...... '~'::' E, ;HEALTH,HAZARD DATA "-
EFFECTS OF OVER ExpOsuRE:~
Those ~of -~a 'choltnesteraSe 'inhibitor: nausea,· headache, 'diarrhea, ataxt a,
'salt,ration, sweattng,"teartng, pin-point :puptls, cyanosts
EMERGENCY AND FIRST AID PROCEDURES:
~Xf'~'tngested, get'medical'attention, tf tn eyes flush wtth gently flowing
· water, get medtcal attention; ~f on sktn wash wtth soap and water. Remove
'contaminated clothtng and launder before re-use.
F. REACTIVITY DATA
STABILITY: .Unstable
Stable XX'
CONDITIONS TO AVOID: N/A
INCOMPATIBILITIES (materials to, avotd): N/A
. ,' .'.. 'HAZARDOUS DECOHPOSXTION PRODUCTS: N/A
; HAZARDOUS-':POLYMERIZATION: Wtll occur :
Will not occur XX
Page 3 of 5
· *,: G. .SPILL OR LEAK PR.pCEDURES
STEPS TO BE TAKEN XN CASE HATERZAL [S RELEASED OR SPILLED:
· Provide ventilation, wear dual cartridge respirator with organic vapor
ca'pabtltty. Absorb"all 11qutd ~tth floor-dry, place absorbent tn metal drum
that can~be:effecttvely.sealed.
wAsTE DISPOSAL METHOD:
~Offer sea]ed..contatner for dtslmsa! at an approved waste site according to
...state and*:federalregulattons.
.................. H,' SPECIAL'PROTECTION INFORHATION "
RESPIRATORY PROTECTION (sPecify type): ,,, N/A ,
VENTILATXON: LOCAL EXHAUST - .N/A
· MECHANICAL (general) - N/A
SPECIAL OR OTHER: .,
Preparation of the spray mixture and loading of application equipment must be
dOne tn'the open air.
,.PROTECTIVEGLOVES: N/A
: -"' ..-.: EYE PROTECTION:' N/A
... '"' OTHER'iPROTECTIVE EQUZPHENT:
In case.of prolonged eXpOsure, ~,ear rubber 9loves, protective clothing, and
goggles.
.'PRECAUTiOnS ~OR'HAND[I'NG'ANO STORING: '
~,~. ,. Hamful.or:fatal tf s'wallowed, Inhaled. or absorbed through skin, eyes. or
~ ...... ~, ..*. clothing. Store tn a cool. dry and ventilated area away from humans, pets,
:'~:'i'~' ,-*:' foodstuffs and feed.· Do not use, pour, or store near heat or open flame. Do
:" .... not breathe vapors. Do not get 'In eyes, on skin or on clothing.
Page 4 of 5
C12H21N203~ .. ;
Dlazino ' ' ..* - 0r anD os a~e ..
A' MATERIA~ OR C~NE~S % w~ H~ARD DATA ~LV, ~DS0,'~S0,'~)
?DLaz~on :... '; 23.0 This fo~lati°n has reduced .
;COntained,in pol~ric ~crockpsules dis- ~he ~za~. of ~he active in-
,.~ ~rsed and s.us~nded in va~er gredien~. Please see reverse
~or data. ~ ~o~Btion.
DO~ Shippin8 Hame - P.Q Hazardous Substance, Liquid, HO~ (Diazinon)
DOT Hazard Class - ORH-E
DOT Identification 14o. - ~-9188
ca 100 °C ca 2~ °F °C °F < 0 °C. <32 °F J ~A
S~fK. Gra~ty (H2~I) ] Va~r ~su;e (mm Hg) ~ Vapor ~sity (AIr-1)
:,, 1.036 ~ 20 / 20 °CI e °C °F
· ~? 96 oc >'205 oF "TCC ii~- % up. ~ %1"1" . °C ~ °F
S~CIAL FIRE FIGHTING PR~EDUR~ ~ear self-contained breathl~ ap~ratus
~lldmo ' to bum ~m fmthl~ ~tw and protective c~thi~
~U~'FIRE AND EX~OSION H~ARDS
~nrd ,. (~lfy), Possible t~ic
~ABI~ITY ] CONDITIONS CO~RIBU~ING TO
INCOMPATIBI LI~- A~td ~ntl~ w~h ·
0 ~g ~ Strong
~o~
~her
· ~ ~al~.s. ~ox~ ~ (~,dfv), NaCerials that react vtth va~r
~AR~US D~M~SmON PROOFS- THg~M~C AHO OTHER
'[OSaib~',tOXiC substances fr~ the~l, de~ada~ion
~NDITI~S TO AVOID "
~TE~ TO BE TAKEN IF MATERIA~ I~ R~EO OR ~PILLEO .,
- ~ 0 ~ OKNp u'lnd' O''v'nt .prMd
~ Fi~ w~h' ~b wire Mhd N~tril~e SwN0 or ~ ~vac~te en~ or spill
Dispose of accordt~ to ~ederal~ S~aCe~ or local proced~es under ~ ~s~rce Con-
sedation and ~c~e~ Act. See bM1 for addttto~l instructions. I CONTINUEDON
REVERSE SIDE
NA--Nor~bl,. -. HE - Noc Established ~A - Data Not Available
....... -~ ....... %/, ........ '. . .~ .. . .- ,. . . . ,
. The active ingredte'nC~ dtazin~ ts a choltnes~erase tfi't~'ttoi to which re~a~ed
e~oaure ~y pr~UCe effects' virhou~ s~r~, · ·
~..:.:..S~C~ ~.of acu~e':'orsanoPhoSp~e poisonin8 include headache ~ diz~ineas
' '~./inc'oordina~i~. ~sc ~ .'~l~chi~ ~ ~re~r ~ nausea ~ abd~ina 1 cramps ~ dtarr~a ~ and
, .];,~.~... -. .. ....... ; '., .. .. .. ,.
PERMISSIBkE EX.SURE LIMIT (S~fY ILTLV~A Or Cllll~ Ecl } I ~h~z
ACGIH 1981 ' '..~LV.~. [OSHA' 19 81 ~a ~
M~lte~ ~ Mild (trlns~)
' ~ *~" Eye' · ."':*- .' ~Y~u~bUndn~ -' ' .'
,, ..... "'" n- · '" , -
(S~clfy): :
(S~y)~
ING~TION * ~NOT ~ Ot.e Atropine is antido:
Induce -' ~ ~u~ ~ ~1~ plenty ~-G~ medl~l
~m~t~ ~'~miting ~ ol water ~ attent~n
DERMA~ I~ warM"
~ Flush w~h ~p * attem~n~'m~l~l ~ntamlMte~ ~ ot,., Gec ~dical. attention
EYE CONTACT
G~ me~l~l Other .. ~. ,.
Flush w~h PMnty of w~ f~ ,'~ .. , , .. .. - .
It ~st 15 min~, ' attent~n (~lfy): ·
VENTI~TION REQUIREMENTS -- ~y~ ~;nMin e~ure ~/ow perm/./~e ex~u~
~ i~kon~n~l ~lth ~cilM ,:.f~,'.. ~ ~ exeunt ' ~ Nfltlbtlon . ~ ~ and o~
' I ~ rub~ ~ iI~l
. ~ (~c~v)~
'," '" N~Pr~~vlnyl ~ly-
ru~r ·
~ ESPI RATO R TYPE - ~ ~/~ N/OSH/MESA 4pp~
lf- - ~ ~n or ~rtrld~ FIIt~ -
Other
Ilr ~ ~s or ~por ~ rural, m~t
OTHf~ PROTfCTIVE
0 ,- O""' '.... ..
PRECAUTIONARY ~9ELING · - '
4ftw ~fldlt~ / lA l on ~ln or , · [~ I oust, vi~r,.m~t, clo~ I I h~t, sparkS, and clo~ ~ntilners
· .- -- - '- ' :L-- ~hl~ .' ~ . -- pS ~ Open IMm.
)~ ' ' ',- *'~.'-/:."K~pfrom~ntl~
Oth~ ~mOu~l~ll ' ~y ~ntaln proof ~ (specify) s
~mbustlb~ ' "~ ~t~ . ~zifOous resides equlP~t
~h~ ha~ling and ltOrl~ ~nd~Mns
Do ~o~ 8~oce oc ~caGspoc~ v~h ~ood oc ~eed. ~e~ec ~o ~bel. ~_/
~e~re~ by . '"' . ~* I ~aress
Obren ~cke~c 10/10/83 1 2952 Taylor ~a7, Taco~, ~ashingCon 9~21'! (206) 627r9101
~EASE ~ 'T~ a~e Infor~tlon ~ ac~rate to the ~t of our knowl~l. Howev~, since Oata, Misty Stan~arOs, and go~n~nt regulations are subject tO
c~n~ an~ the condtt~nl of ~ndll~ and u~, or milu. ire beyond our control, Plnnwllt MAKES NO WARRANTY. EITHER
NOTE ~ IMPLIeD, WITH R[S~CT TO THE COMPL[TENE$S OR CONTINUING ACCURACY OF THE INFORMATION CONTAIN[O HEREIN AND
OISCLAIMS ALL LIABILITY FOR REUA~CE THEREON. U~r ShoulO ~tlsly him~lf t~at he has .11 cu.ent Oata ~elev4nt to his ~rt~u~
· ,.!,~-'.: ' ."~,i .-'~:-'~.~;~:-i
' i ~:~;':,~. ' ' "~ ':"'~$/~ :: ~"" :' , ~?-" '~ - :~ '~ ~''~ ~:~?~)-, ,~ ~/~47 ~-~'? '?': · .' ' .' ;. ~ ' V'-" .- ' ' ' ,, .: ":' ~,V,'~ :: '~ ;~ ...;"'~ :: :'/¥'~.
~..' ~ ~ .,~
~:,. Itr~'.lddrfl8 : , · I ,~ Mtm ... ~ Oate m~ f~ wrl~ ' ·
'
~?.~' ;'~;Itate zip ~e ..
.k ~-: ~' ,'~ , , '" ' ' I '
.....
.... ~!f~ ...... ·
~[~' ~ ~: ·
~:,~'~i~ :~.~um.(mmHg at ~c) ~[ .~~ 7 ~ ~ ~ v~u~ ....- , '~ '
· :~: f~.:, ~ , . .... . ~ ,, , - .... ·
'.y~?~;~: ~ou,~ m wat~.'.. · ~ .... . ':~: ~'' ' · ~ rote ]' . ~io[~aecs ~/.~6,'~ ~/~Z"dia
. -. ~0~ ~ml,(and meth~.u~) , ,.,.r . . 11 ~am~llm~ (~) . i - .
:':~::.;"~;.:~c-; appli~ble-' ' '" .... '?:'"'" ' '" L~F.L. ~C a~li~ble. ] U.F.L. ~C a~lt~le
?~'~'""~"" '"~'~:' ' ' '~" ?'"' ..... '"" :' ~ ~ ....... "~'"' '"'~ ~ ~ any:'
,~. ~.; .... ~'self~m~i~' ~'i~ a~ra~'~in.:cl~e.~ox~t -'
. ,
. . .... . ,: .... :_,,: .... . .;...'. '~.;,. _: .... ~ ; ............. ',',~'.~., ',.~'
~:' ~" ....... ' ' :'~';':""' :~ . ' ,L.: ';.' ,',:~, , ,'"
~:n~mal -.; .: .- ...... : ..... , ......... ,. ,..,
....... , ~:,
:;:.,;:?~'.; ,-~ ~::,~ ,4C~i~* . ,,,~ .. ,,~ .... . .... :..,: , . .
·. ):,:.'(m~ler~ lo /
~ ,: avoid) J' ~ · ' , ;:... , .... -
~' ,",~';,,~r-.,~ : ,4maY., ;~', ~nd~~td '. , .'.~..'
~1~- will not ..... ,., - , :'::.- ·
!: lion ~cur ' X '
· '~ ~' . .--i ~;: ...~;:.~ ...... . · .,;: .'i-~:.~.!'4;.'. U;S. D PARTMEN 'OF LABOR ~,.-,,'. Ar.,,:,,~,,,,o
" ;" ' ' omni NO.
· .,. ,, .. . , _... ~':OccUpational Safety and Health Administration .,
" MATERIAL SAFE'TY DATA SHEET,
Required under USDL Satety and Health Regulations for Ship Repairing,
· . Shlpbu$1d~ng. and Shipbr{eaklng (29 CFR ~1915, 1916, 1917)
.... ' '::' :" · SECTION I
MANUFACTuRER's NAME ' · ' ; I'~.MERGENCV TELEPHONE NO.
~I1ilTMIRE .RESF..ARCIt~. , LA~OKATORIES, INC. [ 316-225-5371
.. A_D_O_~ESS ii, umber. 'Street,_Cl't,~'. St~te..~n~ ZLIa. Cc~. e]
3568 Tree Court Inaustrxal uiva., St. Louis, }tO :63122
CHEM)CAL NAM[ AND SYNONYMS I TRADE NAM[ AND SYNONYMS
n/a , . [ ~itmire PT 565
CHEMICAL,T~/SI FAMILY · ; ] FORMUI. Azl/B ' '
FPA l~ec,, tin_ 699-1R:)AA
SECTION II - HAZARDOUS INGREDIENTS
PAINTS, PRESERVATIVES, & SOLV£NT,S i~.V TLV
IL~nillJ ALLOYS AND METALLIC COATINGS % (Units)
PIGMENTS 1' BAS[ METAL
CATAL.¥ST ALLOYS
V[HIOLE METALLIC COATINGS ·
PLUS COATING OR CORE FLUX. ,
ADDITIVES OTHERS
OTHERS
TL¥
.. HAZARDOUS MIXTURES OF OTHER LIOUID$. SOLIDS. OR GASES % (Unite.)
?echnic,l ?lperon¥1 ~tOxide
N-octyl .Btcycloheptene' Dtcarboxtmtde 1.0
Refined ~'crol&u~.0t! ...... ,, 8.1~ ;
' :': ',:i':::~_.-:"', ;,."'..2':"; ':, "SECTION III . PHYSICAl. DATA
BOLLING IK:)INT,(0F.), "".' , , ~/& SPECIFIC GRAVITY(HID-Il 07~1
VAPOR ~,RrssuR£'lmm.~.) in aerosol ' ~'£.C£N'L VOLATILE: ~89,,5~
concaxner , 3,102xmJ'],p, my vOLUM~ m)
I;VAP~ RATION RATE Z~/~,
VAIN)R D(NSITY (AIR-I) ~/Ji ( .,1) ,
SOLUBILITY In WATER. {egligibl, 4
AppIrA .I~.ANCE AND ODOR . .,
........ -': *'":. "~ SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT. (Melhogl uSe{I) FL~MMABI, E; LIMITS Lei [ L)el
EXT INGUI.~HING ME
'SPEC/AL FIRE FIGHTING PROCEDURES
U~'iU.~UAL FIRE AND EXPLOSION HAZARDS
~,Concacc. de~ctcus ts'.Che most co~on manifestation of pyrethrum toxicity.tn
{A.f~ cases of ex[rtnsic 'asC~ due ~o pyrechr~ mixtures have been ~eporced.
prosaic., ~tlhlstlmlnes are o~ value.
· STABI~IT~ ." ' -[ N ' , C~OITIDN$ TO AVOID
lndeftnl~e'.vh~nu ST~"~ ' Do no~ ~sp~ay tn~o open fla'me or onto yew
usea. acco~a ~nA ' '
rD a~recc~oas~ s~ae~ . X hoc surfaces.
HAZAR~US'DECOM~SITi~ PRODU~S
~e~l decompostc~on ~n open fl~me ~y result tn halogen acids and 'carbon
CONDITIONS TO AVOID
HAZAROOU~ . ~" ~. .., MAY OCCUR ,
~LYME RiZATiON
W~L~ ~OT OCCUR X
. .SECTION VII - SPILL'O~ LEAK PfiOCEDUfiES
l~ container begins Co leak (through. puncture, etc,) alloy tC Co discharge
complecely.ln:a ~vell-venctlaced area, then dispose tn a sa~e place. In case
spillage on skin, rash thoroughly rich soap and racer. ''
WASTE OI$~$AL METHOD
Aeroso~ cylinder ts hoc re~tllabie. Do hoc attempt co recharge. ~en cyllnder
ts exhausc~d.'-dtscard .tn safe.place~ Do hOC throw into fire.
~.... ~one required ';- S-~one r~qutred
~cHANICAL (Gr.~IJ. · OT~ER
,. ~one requlreu ~one required
ne requzrea .[ flone requzrea
~THER' P~OTECT~VE EQUI~ENT~
~one rcequtged
PRECAUTIONS TO BE TAKEN IN ~A~DUNG AND STORING . .
Contents-~der pressure. Do nor puncture. Do no~ s~ore near hea~ or open ~lame.
o hOC re~n 1~ treated areas. :Exposure co ~empe~acures a~ove' 130~'F ~y cause
urstln~. Avoid skin con~ac~.
OT~E~ P~/CAUT~ONS
Foods or eactn8 utensils should be removed, or covered durin8 treatment. Remove
pets 'bi d and fish bowls durin8 :treatment Ventilate area atrer crea~
~omp[e~}d. cover ·
PAGE (2) Form OSHA-20
· .- ' i., .M~TERUU. WETY DATA SHEET (continu(~l) . :TAIJ~'~ ..G (rodenCicide) .... ' -' J
DATA 'SHEET
':..i~: i:ii'?::~ ~'~:~::,.'~':, ,i,::?i.,: :' :'~ ,:~;!i:i ?ii;' :": ..... ~:~,s.:! o...,,,.,,., :~.. i,' ;,'~,, ." ,~.-;',"',. '~.~,,.~ '° .o.., os.^.~o~
.; .-: , ,,~.;:. .
~I~~E ~nd~a~: (2,2~i~t~-1, ;%~z~xol~ REGU~ TELEPHONE NO.: ~-~11~ ·
~ S~Y~S ~lh~a~le); ~rethrins; pi~m~ ~loxide EMERGENCY TE~PHONE NO.: ~24-~
~1~ ~te; pyre~; -. ~ NO.
F~ILY · ~N ~oxi~ ',
~U~ .. ' .... -'~ ~ECU~
.:, -. '~ N~. ' .,.. ', ~G~ N.A.
-. .t~E~E. ,.: . :,. ~.. -
,..:.:: .,-: . ~...,
~ ~:~ "' ........ ~ .... ~:~: ' ~"--::: ':' ',11. H~ARDOUS INGREDIENTS
'-;' : : " : '. ~ ~VA-~A VALUES
~..::;;- , ?: ." .. ,':: ,: ' .,. .
': % ~ A~PTED BY ACGIH
· ~TERIAL
,.~:;.-. .. ~ · .,. .., .': .
· ~.~
' ' :3.~
.... ~", .. " III. PHYSIOAL DATA v~ous ~R~u~ONs)
'.". ~ ~, 7~ ~ ~ N.A. N.A.
.- V~ ~RE ~ ~ · ~PECI~C G~V~
_ .. :,-....:-.:..: -: ,' ..,".".:':,-., N.A... (H~-~)'.
V~ ~ (~R = 1) '-- ~' .: ' PER~ V~
- .:-':.~',:.~ :~'::',.~}...-:... ~ :: ·..: ,.' '. - N.A.: BY V~ME (%) N.A.
: ~~IN WA~. :: ':, ~'' ~A~T~ ~
I -..%BY'~~,./ :' ~. ~:'A. (~A~A~- ~) 'N.~
. .:: . ~:~..'.: :~ : ~. ~. , ,
. ::~:, : -:.~ .."~::"".:?'?:~'~'/, :', ', ,- · ~-' ~.': '. i ~ld~. '. - ·
~ -.'~': ' '" .- ~. L..- '" ~-' - .
.. "::'/~: :"~~1~ M~ ~; ~':~ ~ ~i~u~r": '::,.~ -":'::. ~ :" :~, :" ' : :.- :-
~..:' ~ ~G~ING ~~R~: A~d i~l~ M ~ ~ d~t. W~r ~~ brea~i~ ~pamtus. Remove
' ~~ ~ ~D ~ ~~: ~k~ g~ ~ ~ ~te ~s ~ ~at~.
.~ ,,..:......., ...~ .',.~. : '. ~. : . - . .. . .....
.. ,, ~:~..~~~, .. .. ., ......
~~ 43~ ~ ~~ PAe, P.O. ~x ~
. ~ ~t~, .DE ~5 ' '
· ~RESH~D..LIMIT VALUE: Not establ~, AOX- (Rat): 'IZ4 ~g; ADLD, (rat); >3~ ~g: .'
,EFFE~S OF OVER~POSURE: ~te ms~: '~;tric~.of ~Pils. ~livati~. muscular i~dination;
EMERGENCY AND FIR~ AID PR~EDURES: E ~allOw~l ~11 a ~ician or ~n'control center. Give 1 or 2 gl~s
:. of water ~ i~uce v~iting ~.t~ching fl~er t0 ~ck of ~r~t or administer'l~ac S~p USP. Adult dose ~ ml;'chiidr~ 10 mi.
~ ~ i~uce ~iting ~ give~a~hi~ :by ~th to 'an' unc~ci~s ~ c~lsi~ .~. ~t medical aaention.
. ~ inhal~ ~:Keep patient str~t~ at rest ~d.tr~fer to ~pit~ immediately to get m~ical aaenti~. ·
'~ on ~e'skin ~.Wa~ With,,~p and wa~ 'water f~ 15 minutes. ' ~''' .-
E In eyes.~ RushWith Plenty of wate~ f~.,~5.min~es: Get ~ical aEent~. ".', ..
Note For Physician: ~ntains antic~inestemse ~rbamate in~ticide. In ~ses of ~erex~sure. atropine sulfate -- 2
(equivalent to '11~ grain adult dose) s~ld ~' given, and re~at~ as n~es~ until fully atropinized. Pralidoxime (P2S)
. is ineff~tive; ~hine ,c~traindicated.' ~ntrol ~lsions ~ Diozepam 1~20 ~, intrave~sly.
· ,.. - -VI. REACTIVITY DATA
STABILITY ..... ' CONDITIONS TO AVOID: ' - :,
INCOMPATIBILITY (MATERIALS TO AVOID):. ':. ·
'HAZARDOUS DECOMPOSITION PRODUCTS: Bendiocarb gives off r~ethyl isocyanate fumes when heated.
HAZARDOUS :.-; MAY OCCUR ~ CONDFIFIONS TO AVOID:
POLYMERIZATION :WlU. NOT OCCUR · ," ';' ', ': .... ' :' -
STEPS 3'0 BE TAKENIFMATERIAL: IS. RELEASED OR SPILL]ED: Carefully sweep up, avoid inhalation of dust.and skin
contamination. Placein suitable container and seal. Area mtn be washed with water to remove last traces of FICAM PLUS
but keep out of waterCOUrses. " '-' ,
'. .... ', ,'.:.~.,,,~IVlSDG..,. ':. ':,~,:~,~?,i~.:i:,:,.i}~.: .'~.~ '..~.:i ~.~,;i~.i?.....' :: .,.~._?! '.'~,DATE: FEI~. 14, 1983'. . .:
'~. p~ ~1: ~, spray ~um ~' ~n~' ~t~ ~t ~ ~ ~
· ~ ~ ~d~ ~ ~~ f~ml, state, ~ ~1 ~ur~.
' .:., · .' ~':' .,. ,.~.:
.. ........ .;~:' :'.:.~ ~'.::/'.~::'~:~}:'. VIIL~PEC~':: OTECTION INFORMATION Le.: ~,
.. ." PR
.. ~I~T~Y P~~' :1., ~~~ ~ea~i~ ~at~
· ' ~ef~
. ~::': I (GENE~.. -..:
PRO~.GLO~S: P.V.C~ .: ~" "" I E~ PRO~:
O~ER PRO~ E~i~: ~ ~
"'" ..' ' IX. SPECIAL PRECAUTIONS
PRE~~Y. ~EU~: ~1 ~ ~1 ~ swaillo~. ~y ~ e~ ~.
A~'.~ ~-~;'~ ~ ~. II ~ct ~, ~ ~ .~ cb~
'"' '-~s'-~'~ ~'~'.~, ~;'~:'~ ~Mliie. ~ n~ ap~ dir~ to ~ter. Ke~ '.: ~ ~ ~te' ~t~ ~ ~ M ~nt o~ dis~l ~ wastes.
,.., ? .:- ',:.. '...:': .... .
,' : -.: '. ".':-:..:....:....,'-, .."' . ':: ':-, .: ,' ..:'":. "~ -' .:.
,:.~" '-".'." .L' .'~:...~'? .:". ' ' : . .
,. '. .....".:.......
Hazardous Materials/Hazardous waSte Unified Permit
CONDITIONS OF-PERMIT ON REVERSE:SIDE
. · 2' -'~ This _oermit is issued for the following_:
· . ' [] Hazardous Materials Plan
· . .~, 121'Under,round Stomg® of H~rdous
Permit ID #:: 015-000-000439 .r ~:O RiskManagementProgmm.
BANKS PEST CONTROL INC I-IHazard°usWasteOn'SiteTmatment
'LOCATION: 215 GOLDEN'STATE . IELD .. -,:=.! :?.
.~'
OFFICE OF ENVIRONMENTAL SER VICES' " ' .ca'
1715 Chester Ave., 3rd Floor Approved by: ¥C~v~"~'~,m'~'~'~i .
Bakersfield, CA 93301 om~o~£~i~s~i¢~ ~
Voice (661) 326-3979
FAX (661) 326-0576 Expiration Date: 'June 30; 2003
Hazardous Materials/Hazardous Waste Unified Permit
CONDITIONS OF PERMIT ON REVERSE SIDE
..... ,~ ,,; ~,~,~ ~,~,,~;~,,~..,,,,,,~,~,~ ......... This permit is issued for the following:
,,,¢i'?:'[' ,',i ?"~:::;i ii :ii!.!ii i?:' i~ii:~al;iU~erground Storage of Hazardous Materials
PERMIT lO# 015-021~00439 :¢~i¢i ~i ,:~ iii }~;~:','~' !![:~.:!i!?:',~:! !=: i! ?.::!!!!i,!}!!! ~!ii~i~, ~ ~'~kli~:.nagement Program
~"-'.... "4~ :: ,~: ............. ::'.~,~ .... , ', 'i;;'..'~ ~ . ~ .~ '., .,~ :~ ~ ' ' ' ,' !~% ~ '~ '-. "-,: ~
'~["':-.. ".~ .¢~..~ ~[.~! ~¢ ...................... ' ~ ',¢;'~i~~ ¢*' ¢~ii~'~;~';~,,~;,¢~,~h~;,~-'. ¢"~ ¢'.! ~'..'-.::,.':~
,~ · ........... ,..~....;;
B~ersfield Fke D~ment Approved by:
O~CE OF E~ O~E~AL S~ ~CES ~ ~ph Hu~~
1715 Chewer Ave., 3rd Floor Office off.mi S~id~
B~e~fiel~ CA 93301
Voice (805) 326-3979 Expiration Date: June 30, 2000
F~ (805) 326-0576
~ :., :~ ?.~ ' TE/FACI LI -'fY DI{ R;klVl.
NORTH SCALE:l/8,,=2O, BUSINESS N~uME: Banks Pest Control, Inc. FLOOR: 1' OF 1
~ DATE: / / FACILITY NAME: n/a .. UNIT m: 1OF 1
(CHECK ONE) SITE DIAGRAM X FACILITY DrAGRAM
Inspector's Comments): -OFFICIAL USE ONLY-
~. S~reet(a), Alters, ii. K&tiroa4 ~racka
Drlveeeye, and Perkins
Areas adjacent to the 12. Fence or Barrier
property. IBel~de the a. Wire
lariat nlBel.
b. #asoary
3. Store Drains. Culverts.
Yard Drain. c. ¥ood
4. DralnsEe Canals. Ditches, d. Oaten
Creeks.
13. Po~rllnua
$. Bulldlncs
a. Yraue construction 14, O~rd Stntton
b. IAaa.tifF construction 15. SI.rife Tankl:
Identify the
e. Metal construction capacity la fsi.
a. ~bove ErOUEKI
d. Access Oo~r
b. U~der(round
Utility Controls
a. Gas 16. Diking or Bern
b. Electricity , 17. Ev&cuatLoa Route
c. Mater 18. Evacuation Area:
Identify the
?. Fire Suppression Systems: loeatLon where.
a. Fire Hydrants employees #Ill
b. Fire Sprinkler lO. Outside Hazardous '"
CoflAectiona Miata ltorqa
c. Fire Standpipe 20. Outside I(azerdous
Connactlon~ I~atariaJ It.rase
d. Water ~ofltrol Valves 21. Outside Ilezardous
£or protectl~ systems #aterlaI
'' e. I~lre Puap ~2. Typo of liazardoua
Stored
S. Flit ~r~nt ~ceea or ~e~ (~
Reactive T - Tea:lo S - Solid I - Cryo[enic
O - Waste B - ltl.logical
f~aaple~ flamaable Liquid - fL
~.~ (Kequlred Item, in addltl6n to the above)
I. Risers for Iprlmlders I. Fire Es.apes
J. Partitions O. Air Coadltionln( ~fllto
3. ltaJmfsf Indicate the 10. Wlndo~s
levels served fro~
highest to Jesuit. il. IMIM laurdoua Waste
d. hea~'ator= Indl~atl"tbe
levels 8erred fi, on l~, ln~lde Ifasardous
highest to lmseat. Natoriela 8teroge
S. Elevator lO. %sside hsardeu~
Naterlele Une/landJ/nl
e. Atria Aeeese ........ . , .
14. 8e~er Orals Inlets
Y. S&yl tt~t,
~' "NORTR $~LE: 1"-20' Bt]$INE$$ N~: Banks Pest Control, Inc. F~R: OF
CITY OF BAKERSFIELD FIRE DEPARTMENT
OFFICE OF ENV]IRONMENTAL SERVICES
UNIFIED PROGRAM INSPECTION CHECKLIST
1715 Chester Ave., 3r~ Floor, Bakersfield, CA 93301
FACILITY NAME ~^~-5 ~Z~- Co,,,~,qoC INSPECTION DATE ~ ~ ~'
FACILITY CONTACT ~>D/~ f'~Z/o[< 5 BUSINESS ID NO. 15-210-
INSPECTION TIME [,q"- .~.,!.d NUMBER OF EMPLOYEES
Section 1: Business Plan and Inventory Program
~RRoutine [2] Combined [~ Joint Agency [~1 Multi-Agency ~ Complaint [~ Re-inspection
OPERATION C V COMMENTS
Appropriate permit on hand
Business plan contact information accurate
Visible address
Correct occupancy
Verification of inventory materials
Verification of quantities ~/'
V/
Verification of location
Proper segregation of material /
Verification of MSDS availability / //
Verification of Haz Mat training
Verification of abatement supplies and procedures
Emergency procedures adequate
Containers properly labeled
Housekeeping
Fire Protection
Site Diagram Adequate & On Hand
C=Compliance V=Violation
Any hazardous waste on site?: [~] Yes No
Explain:
Questions regarding this inspection? Please call us at (661) 326-3979 ible Party
White- Env. Svcs. Yellow- Station Copy Pink- Business Copy Inspector:
BANKS PEST.CONTROL INC "~ SiteID: 015-021-000439
Manager : ~o~ ~$ ~ ~%/%%%% BusPhone: (661) 323-7858
Location: 215 GOLDEN STATE ~.~ Map : 103 CommHaz : High
City : BAKERSFIELD '~ Grid: 30B FacUnits: 1 AOV:
CommCode: BAKERSFIELD STATION 04 SIC Code:7342
EPA Numb: DunnBrad:07-618-5644
Emergency Contact / Title Emergency Contact / Title
DON BANKS / CEO FRANK DAIGLE / SUPERVISOR
Business Phone: (661) 323-7858x Business Phone: (661) 323-7858x
24-Hour Phone : (661) 588-2472x 24-Hour Phone : (661) 871-8272x
Pager Phone : ( ) x Pager Phone : ( ) x
Hazmat Hazards: Fire Press ImmHlth
Contact : Phone: (661) 323-7858x
MailAddr: 215 GOLDEN STATE State: CA
City : BAKERSFIELD Zip : 93301
Owner ORLAND BANKS Phone: (661) 323-7858x
Address : 4406 KNOLL DR State: CA
City : BAKERSFIELD Zip : 93308
Period : to TotalASTs: = Gal
Preparer: TotalUSTs: = Gal
Certif'd: RSs: No
ParcelNo:
Emergency Directives:.
-~t_~~;r DO hersby cer~ih/~ha~ ~ have
~vie~ed ~he a~ached h~ardou~ mmsria~s manage-
plan fo~ ~~
corrosions ~ns~i~u~s a compls~s and ~rr~
~msn~ plan ~or my faciJi~y.
Signature Date
1 07/15/2003
BANKS PEST CONTROL INC SiteID: 015-021-000439
Fast Format
~ Training .' Overall Site
-- Employee Training·/ 12/01/1999
WE HAVE EMPLOYEES AT FACILITY.
·
WE HAVE MATERIAL SAF DATA SHEETS ON FILE
BRIEF SUMMARY OF TR3tINING PROGRAM: ALL EMPLOYEES HAVE BEEN TP~AINED AND
INSTRUCTED ON WHO TO NOTIFY AND HOW TO HANDLE HAZARDOUS SPILLS.
lPage 2
--Held for Future Use
Held for Future Use
-7- 07/15/2003
BANKS PEST CONTROL INC SitelD: 015-021-000439
Manager : BusPhone: (661) 323-7858
Location: 215 GOLDEN STATE Map : 103 CommHaz : High
City : BAKERSFIELD Grid: 30B FacUnits: 1 AOV:
CommCode: BAKERSFIELD STATION 04 SIC Code:7342
EPA Numb: DunnBrad:07-618-5644
------+
~Emergency Contact / Title Emergency Contact / Title
~O~~ BANKS / O~qER ~.~2. FRANK DAIGLE / SUPERVISOR
Business Phone: (661) 323-78~8x Business Phone: (661) 323-7858x
24-Hour Phone : '(661) ~l-9~-~-~Z 24-Hour Phone : (661) 871 052Dx-~3~-
Pager Phone : ( ) - x Pager Phone : ( ) - x
Hazmat Hazards: Fire Press ImmHlth
Contact : Phone: (661) 323-7858x
MailAddr: 215 GOLDEN STATE State: CA
City : BAKERSFIELD Zip : 93301
Owner ORLAND BANKS Phone: (661) 323-7858x
Address : 4406 KNOLL DR State: CA
City : BAKERSFIELD Zip : 93308
Period : to TotalASTs: = Gal
Preparer: TotalUSTs: = Gal
Certif'd: RSs: No
Emergency Directives:
+= Hazmat Inventory One Unified List +
+== Alphabetical Order Ail Materials at Site +
+ ................................ + ....... + ........... + ..... + .......... + .... +- - -+
I Hazmat Common Name... ISpocHazlEPA HazardsI Frm I DailyMax IUnitlMCPI
+ .................... ~ ........... + ....... + ........... + ..... + .......... + .... +- - -+
SULFURYL FLUORIDE F P IH G 475.00 FT3 Ext
~, ~-")~,~ ~/¢~ Do hereby certify that ~ ,have,
Uype or print name)
reviewed the attached hazardous materials manag®-
merit plan for~---'~,¢,,,.~~ (.~a.~o~,......);~/-~'~"~;/-~ that it alone with
any corrections constitute a complete and correct man-
agement plan for my facility.
+__ . ......... ~ ........ ~ .... == +
-1- 03/21/2002
+ BANKS PEST CONTROL INC == SiteID: 015-021-000439
+= Inventory Item 0003 .... Facility Unit: Fixed Containers on Site
+== COMMON NAME / CHEMICAL NAME ~
SULFURYL FLUORIDE I Days On Site
365
Location within this Facility Unit; Map: Grid: + ................
STORE ROOM E WALL CAS#
2694-79-8
+ .... 4
+= STATE =+= TYPE ===+== PRESSURE ===4- TEMPERATURE ==+ .... CONTAINER TYPE
I Gas I Pure I Above Ambient I Below Ambient I PORT. PRESS. CYLINDER
+=========+ .... ~ ~ ~
+ -+ AMOUNTS AT THIS LOCATION
Largest Container I Daily Maximum I Daily Average
475.00 FT3 475.00 FT3 285.00 FT3
q =4 4 ==+
4 i = HAZARDOUS COMPONENTS +===+ --+
99.00 Sulfuryl Fluoride No 2699798
+ + --+===4
+ +===+ ~ HAZARD ASSESSMENTS ===4 + +=====
ITSecret N~SIBi°Hazl Radi°active/Am°unt I EPA Hazards INo No No/ Curies F P IH NFPA/// I USDOT# MCP [Ext
+ +===+======4 ~ ~ + ~=====+
-2- 03/21/2002
+ BANKS PEST CONTROL INC SiteID: 015-021-000439
+ Fast Format
+= Notif./Evacuation/Medical Overall Site
+== Agency Notification = 12/01/1999
CALL 911.
+=== Employee Notif./Evacuation 05/17/1990
INTERCOM SYSTEM AND CALL 911.
+ .... Public Notif./Evacuation 12/01/1999
ALL EMPLOYEES HAVE BEEN INSTRUCTED IN CASE OF EMERGENCY INVOLVING RELEASE OR
THREATENED RELEASE OF A HAZARDOUS ~RTERIAL, TO CALL 911 AND 1-800-852-7550
OR 1-916-427-4341. THIS WILL NOTIFY THE LOCAL FIRE DEPT AND THE STATE OFFICE
OF EMERGENCY SERVICES AS REQUIRED BY LAW.
+=
Emergency Medical Plan 12/01/1999
MINOR INJURIES, FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN OR
TRANSPORT TO BAKERSFIELD MEMORIAL HOSPITAL WHICH IS THE CLOSEST HOSPITAL
FROM OUR PLACE OF BUSINESS.
-3- 03/21/2002
+ BANKS PEST CONTROL INC SiteID: 015-021-000439 +
+ Fast Format +
+= Mitigation/Prevent/Abatemt Overall Site +
+== Release Prevention = 07/14/1992 +
TRAINING PROCEDURE FOR PROPER MIXING AND HANDLING OF HAZARDOUS MATERIALS.
TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN.
+=== Release Containment == 12/01/1999 +
TRAINING PROCEDURE FOR PROPER CONTA][NMENT USING SPILL SOAKUP AND OTHER
METHODS, SAND VERMICULITE.
..... Clean Up 07/14/1992 +
TRAINING AND PROPER CLEANUP USING PI~STIC BAGS APPROVED BARRELS AND FINDING
OUT PROPER WASTE DISPOSALS.
+ ..... Other Resource Activation
4 03/21/2002
+ BANKS PEST CONTROL INC SiteID: 015-021-000439 +
~ Fast Format +
+= Site Emergency Factors - Overall Site +
+== Special Hazards 05/17/1990 +
HAZARDOUS POWDER INSECTICIDE CHEMICALS STORED IN STOREROOM IN QUANTITIES
LESS THAN REPORTABLE.
+ ------+
+=== Utility Shut-Offs -- 12/01/1999 +
A) GAS - W OUTSIDE WALL ADJACENT TO V ST
B) ELECTRICAL - W OUTSIDE WALL ADJACENT TO V ST
C) WATER - W OUTSIDE WALL ADJACENT TO V ST
D) SPECIAL - NONE
E) LOCK BOX - NO
+ .... Fire Protec./Avail. Water 12/01/1999 +
PRIVATE FIRE PROTECTION FIRE EXTINGUISHERS.
FIRE HYDRANT - NW CORNER OF V ST AND GOLDEN STATE AVE.
+ ..... Building Occupancy Level ---+
-5- 03/21/2002
+ BANKS PEST CONTROL INC SiteID: 015-021-000439
+= = Fast Format
+= Training Overall Site
+== Employee Training 12/01/1999
WE HAVE 32 EMPLOYEES AT THIS FACILITY.
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE.
BRIEF SUMMARY OF TRAINING PROGRAM: ALL EMPLOYEES HAVE BEEN TRAINED AND
INSTRUCTED ON WHO TO NOTIFY AND HOW TO HANDLE HAZARDOUS SPILLS.
+=== Page 2
+ .... Held ~or Future ~se --
Held for Future Use ~
-6- 03/21/2002
CITY OF BAKERSFIELD FIRE DEPARTMENT
OFFICE OF ENVIRONMENTAL SERVICES
UNIFIED PROGRAM INSPECTION CH ECKLIST
1715 Chester Ave., 3rd Floor, Bakersfield, CA 93301
FACILITY NAME l~,~l/-,g ~'V--$-C Eo~'Tgo/.. ! INSPECTION DATE 0~. ~
ADDRESS ZI~ ~OLD~,O ~~ PHONE NO. ~&3-. ~
FACILITY CONTACT ~O fi~9 BUSINESS ID NO. 15-210-
INSPECTION TIME Il :O0 NUMBER OF EMPLOYEES
Section 1: Business Plan and Inventory Program
Routine [] Combined [] Joint Agency [] Multi-Agency [] Complaint [] Re-inspection
OPERATION C V COMMENTS
Appropriate permit on hand
Business plan contact information accurate
Visible address
Correct occupancy
Verification of inventory materials
Verification of quantities
Verification of location
Proper segregation of material
Verification of MSDS availability
Verification of Haz Mat training
Verification of abatement supplies and procedures
h
Emergency procedures adequate
Containers properly labeled
Housekeeping
Fire Protection
Site Diagram Adequate & On Hand
C=Compliance V=Violation
Any hazardous waste on site?: ~Yes i~/~io
Explain: //IJ,,~5']"~-~ ~4:;1~"i".~1- t/x, if_./'~.~ .__
/ \Business Site Responsible Party
Questions regarding this inspection? Please call us at (805) 326-3979 D
White- Env. Svcs. Yellow- Station Copy Pink- Business Copy Inspector: C'_~
BANKS PEST CONTROL INC SiteID: 215-000-000439
Manager : /. /' 0~'i': ]~0gy BusPhone: (805) 323-7858
Location: 215 GOLDEN STATE '"-3~"X;-:,~, Map : 103 CommHaz : High
City : BAKERSFIELD ?:,?~z,p~ Grid: 30B FacUnits: 1 AOV:
Emergency Contact / Title Emergency Contact / Title
ORLAND BANKS / FRANK DAIGLE / SUPERVISOR
Business Phone: (805) 323-7858x Business Phone: (805) 323-7858x
24-Hour Phone : (805) 399-1591x 24-Hour Phone : (805) 871-0529x
Pager Phone : ( ) - x Pager Phone : ( ) - x
Hazmat Hazards: Fire Press ImmHlth
Contact : Phone: ( ) - x
MailAddr: 215 GOLDEN STATE State: CA
City : BAKERSFIELD Zip : 93301
Owner ORLAND BANKS Phone: (805) 323-7858x
Address : 4406 KNOLL DR State: CA
City : BAKERSFIELD Zip : 93308
Period : to TotalASTs: = Gal
Preparer: TotalUSTs: = Gal
Certif'd: RSs: No
Emergency Directives:
i 11/01/1999
BANKS PEST CONTROL INC SiteID: 215-000-000439
= Hazmat Inventory By Facility Unit
-- MCP+DailyMax Order Fixed Containers on Site
Hazmat Common Name... ISpocHazlEPA HazardsI Frm I DailyMax IUnitlMCP
SULFURYL FLUORIDE F P IH G 475.00 FT3 Ext
-2- 11/01/1999
BANKS PEST CONTROL INC SiteID: 215-000-000439
~ Inventory Item 0003 Facility Unit: Fixed 'Containers on Site
%.:l.)lVliVlt.)l~l J.M.Z-'~Vl{'', / I.:i'J.l";iVl.L %..:./'-~J-, £~{.Z'&.iVl{'',
SULFURYL FLUORIDE Days On Site
365
Location within this Facility Unit: Map: Grid:
STORE ROOM E WALL CAS#
2694 -79-8
F STATE ~ TYPE i PRESSURE . TEMPERATUREI CONTAINER TYPE
Gas /Pure Above Ambient Below Ambient PORT' PRESS. CYLINDER
AMOUNTS AT THIS LOCATION
Largest Container I Dai].y Maximum I Daily Average
FT3I 475.00 FT3I 285.00 . FT3
HAZARDOUS COMPONENTS
99.00 Sulfuryl Fluoride N 2699798
HAZARr) ASSESSMENTS
TSecret oRS l Bi°Has Radioactive/AmountNo N No No/ Curies FEPA HazardSp IH NFPA/// I USDOT# IMCPEXt
3 11/01/1999
BANKS PEST CONTROL INC SiteID: 215-000-000439
Fast Format
~ Notif./Evacuation/Medical Overall Site
-- AHency Notification 05/17/1990
CALL 911
-- Employee Notif./Evacuation 05/17/1990
INTERCOM SYSTEM AND CALL 911.
Public Notif./Evacuation 05/17/1990
ALL EMPLOYEES HAVE BEEN INSTRUCTED lIN CASE OF EMERGENCY INVOLVING RELEASE OR
THREATENED RELEASE OF A HAZARDOUS ~ERIAL, CALL 911 AND 1-800-852-7550 OR
1-916-427-4341. THIS WILL NOTIFY THE LOCAL FIRE DEPARTMENT AND THE STATE
OFFICE OF EMERGENCY SERVICES AS REQUIRED BY LAW.
EmerHency Medical Plan 05/17/1990
MINOR INJURIES FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN OR
TRANSPORT TO BAKERSFIELD MEMORIAL HOSPITAL WHICH IS THE CLOSEST HOSPITAL
FROM OUR PLACE OF BUSINESS.
-4- 11/01/1999
BANKS PEST CONTROL INC ~~~&~~~~ SiteID: 215-000-000439
i~ Mitigation/Prevent/Abatemt ~~~~~~~ Overall Site
i~ Release Prevention ~~~~~~~~~ 07/14/1992
TRAINING PROCEDURE FOR PROPER MIXING AND HANDLING OF HAzARDoUS MATERIALS.
TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN.
TRAINING PROCEDURE TO PROPER CONTAInmENT USING SPILL SOAKUP AND OTHER'
METHODS, SAND VERMICULITE.
a~e~~e~eeee~e~ee~eeee~e~eeee~eeeee~eeeeeeeeeeee~e~eeeeee~ee~eeef
i~ CleanUp ~~~~~~~~~~~ 07/14/1992
TRAINING AND PROPER CLEANUP USING PI~STIC BAGS APPROVED BARRELS AND FINDING
OUT PROPER WASTE DISPOSALS.
aeeee~~eeeeeeeeee~~ee~ee~~e~~~ee~~ee~e~~eeee~~eeeeeeee~~eee~ee~~e~~eeee~eee~e~~~f
-5- 11/01/1999
i BANKS PEST CONTROL INC ~&&&&&&~~&&~&&&~&&~ siteID: 215-000-000439
i~ Site Emergency Factors ~~~~~~~~ Overall Site
i~ Special Hazards ~~~~~~~~~~ 05/17/1990
O
o HAZARDOUS POWDER INSECTICIDE CHEMI~S STORED IN STOREROOM IN QUANTITIES
o LESS THAN REPORTABLE.
O
a~ee~e~eeee~ee~ee~eeeee~e~e(~ee~eee~e~eeeeeeee~e~eeee~eeef
i~ Utility Shut-Offs ~~~~~~~~~ 05/17/1990
O
o A) GAS - WEST OUTSIDE WALL ADJACENT TO V ST
o B) ELECTRICAL - WEST OUTSIDE WALL ADJACENT TO V ST
o C) WATER - WEST OUTSIDE WALL ADJACENT TO V ST
o D) SPECIAL - NONE
o E) LOCK BOX - NO
O
i~ Fire Protec./Avail. Water ~i~~~~~~ 05/17/1990
O
o PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS
O
O
O
O
o FIRE HYDRANT - NORTHWEST CORNER OF V ST AND GOLDEN STATE AVE.
O
0
0
6 11/01/1999
BANKS PEST CONTROL INC ~~~i~~~~ SiteID: 215-000-000439
Training ~~~~~~~~~~&~ Overall Site
i~ Employee Training ~~~~~~~~~ 09/il/1996
WE HAVE 32 EMPLOYEES AT THIS FACILITY
WE HAVE M~TERIkL SAFETY DATA SHEETS ON FILE
BRIEF SUMMARY OF TRAINING PROGRAM: ALL EMPLOYEES HAVE BEEN TRAINED AND
INSTURCTED ON WHO TO NOTIFY -~-N'D HOW TO I4_g2qDLE H-~Z~DOUS SPILLS.
aeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeceeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeeef
a~~~~~~~~e~~~~~~~e~f
i~ Held for Future Use ~&~&~&&~~~&&~&~&~&&&&&&~&&~&~&&&&&~l
? 1 /Ol/1999
B A K E R S F I E L D
FIRE DEPARTMENT
February 4, 1998
RI~ CHIEF
~O.U~L U. mtV Mr. Don Banks
Banks Pest Control
~N~'mav~ sma:ts 215 Golden State Hwy
2101 'H' Street
~. CAr'S01 Bakersfield, CA 93301
(805) 326-3941
FAX (805) 395-1349
NO FURTHER ACTION REQUIRED
SU~N SEEVICES
2101 'H' ~eet
8ake~"flek:l, CA93301 RE] 215 Golden State Hwy
(805) 326-394 I
FAX (805) 395-1349
Dear Mr. Banks:
msc. he~^~. This is to inform you that this department has reviewed the results of the
Bakersfield, CA 93,301
(805) 326-3951 laboratory sample analysis associated with the soil contaminated by waste paint
FAX (805) 326-0576
improperly disposed of on the above referenced property.
l?15Che~ter^w. Based upon the information submitted, this office is satisfied with the
Bakerff~td. CA 93301
(805)326.3979 corrective action performed and requires no further action at this time in the
FAX (805) 326-0576 above referenced matter.
TRAINING DIVISION
5642 Vlcto, Stmet If you have any questions regarding this matter, please contact me at (805)
~:~k~::10 CA 9~308 326-3979.
(805) 3994697
FAX (805) 399-5763
Sincerely,
Howard H. Wines, III..
Hazardous Materials Specialist
Office of Environmental Services
HHW/dm
LABORATORIE S, IN
January 27, 1998
DON BANKS
BANKS PEST CONTROL
215 GOLDEN STATE AVE.
BA/<ERSFIELD, CA 93301
Subject: Laboratory Submission No.: 98-00400
Samples Received: 01/13/98
Dear Mr. Banks:
The samples(s) listed on the Chain of Custody. report were received by BC
Laboratories, Inc. on 01/13/98.
Enclosed please find the analytical data for the testin~ requested. A copy
of the results for this submission will be sent to the following: CITY OF
B3LKERSFIELD - HOWARD H. WINES III. If you have any questions re~ardin~, th±s
report please contact me at (805)327-4911, ext. 204.
Any unused sample will be stored on our premises for a minimum of 30 days
(excludin~ bacteriolo~icals) at which time they will be disposed unless
ot .... wise
requested at the time of sample receipt. A disposal fee of $5 per sample may
apply for solid! Dample matrices.
Please refer to submission number 98-00400 when 'caltin~ for assistance.
Sincerely,
Tina Green
Client Services
BC Laboratories, Inc.
i--~i 41 O0 Atlas Ct. · Bakersfield, CA 93308 · (B05] 327-491 I · I=AX [805) 327-191B
State: ~ ~1/~ ~~
CH ~C
· . ~ Send uopy to v
. Attention:. . . '., . -Relinquish~ by: (~gnature) ~eceived by: (Si~a~re) [ Date: ~me: , '
: '' ' ' ' , ' . ~olinquishod ~y: (Si~naturo) ~ocoivod by: (Signature) ~atO: ~mo:
Equipmont: ' ~1~o~~ ~ ~olinquishod by: (Si~namro) ~ocoivod by: (Si~aa~uro) Dato: ~mo:
flovisod ~/O7....Samplo ~isposal by BG.Labs may bo billod at $5.00 / samplo ~or non-aqueous Samplos:
Submission #: ~)~ 'Project Code:
SHIPPING INFORMATION SHIPPING CONTAINER
Federal Express [] UPS [] Hand Delivery [] Ice Ches~ None
BC Lab Field Service/~ Other [] (Specify) Box [] Other [].(Specify)
Refrigerant: IceFl Blue Ice ~'-, None FI Other Fl Comments:
Temperature: '7 - ~__°C Temperature: °C
Thermometer ID: Thermometer ID: .
Emissivity Emissivity
Container C..}r~OkV-~.~ {.0~ Container
S^M ECONT^ NE.S I' J' I' I' I' I' I"1' I' I'ol',l-I,
QT GENERAL MINERAL/GENERAL PHYSICAL
PT P£ UNPRESERVED
QT INORGANIC CHEMICAL METALS
PT INORGANIC cHEMIcAL METALS
PT CYANIDE
PT NITROGEN FORMS
PT TOTAL SULFIDE
2o7. NITRATE / NITRITE
100mi TOTAL ORGANIC CARBON
QT TOX
Pl' CHEMICAL OXYGEN DEMAND
100mi PHFNOLICS ·
40mi VOA VIAL TRAVEL BLANK
40mi VOA VIAL
VOA SET (3 VIALS. 1TB)
QT EPA 413.1. 413.2. 418.1
PT ODOR
RADIOLOGICAL
BACTEPJOL OGICAL
PT EPA 50~.
QT EPA 50~/60e/eo80
QT EPA 515.1/8150
QT EPA 525
QT EPA 525 TRAVEL BLANK
1OOmt EPA 547
t
100rnl EPA 531.1
QT EPA 548
QT EPA 549
QT EPA 632
QT EPA 8015M
Q.T QA/QC
QT AMBER
8 OZ. JAR
32 OZ. JAR
SOIL SLEEVE
PCB VIAL
PLASTIC BAG
"
Comments:
Compleled by:.,''~ ' , [F:~WP~QtLAB_DOCS~FORMS~SAJ~IREC2.WPD]
LABORATORIES Page 1
TOTAL CONCENTRATIONS
(California Code of Regulations, Title 22, Section 66261)
BAi~KS PEST CONTROL Date Reported: 01/23/98
215 GOLDEN STATE AVE. Date Received: 01/13/98
BAKERSFIELD, CA 93301 Laboratory No.: 98-00400-1
Attn: DON BAigKS 323-7858
Sample Description: S.P. ~1 SAMPLED BY MIKE GRAHAM
Sampling Date/Time: 01/13/98 @ 09:40AM
Title 22 Waste Type: Type i: Millable Solid - No Free Liquid
Regulatory
Criteria
Method STLC TTLC
Constituents Sample Results Units P.Q.L. Method mq/L. mq/kq
Lead 46. mg/kg 2.5 SW-6010 5.0 1000.
Comment: Ail above constituents are reported on an as received (wet) sample basis.
Results reported represent totals (TTLC) as sample subjected to appropriate
techniques to determine total levels.
P.Q.L. = Practical Quantitation Limit (refers to the least amount of analyte
quantifiable based on sample size used and analytical technique employed).
STLC = Soluble Threshold Limit Concentration
TTLC = Total Threshold Limit Concentration
REFERENCES:
SW = "Test Methods for Evaluating Solid Wastes Physical/Chemical Methods",
EPA-SW-846, September, 1986.
Dan Schultz
Laboratory Director
cc: CITY OF B~uKERSFIELD - HOWARD H. WIS[ES III
All results listed in this report are for the exclusive use of the submitting party. BC Laboratories, Inc. assumes no responsibility for report alteration, seperation, detachment or third party interpretation.
4100 Atlas Ct.. B3kersfield, CA 951308 . (805) 327-4911 . FAX (805) 327-1918
Page 1
LABORATORIES CHEMICAL ANALYSIS
B~NKS PEST CONTROL Date Reported: 01/22/98
215 GOLDEN STATE A~-E. Date Received: 01/13/98
BAICERSFIELD, CA 93301 Laboratory No.: 98-00400-1
Attn: DON B~NKS 323-7858
Sample Description: S.P. ~1 SAMPLED BY MIKE GRAHAM
Sampling Date/Time: 01/13/98 @ 09:40AM
Method
Constituents Sample Results Units P.Q.L. Method
TOX * None Detected mg/kg 5.0 SW-9020
P.Q.L. = Practical Quantitation Limit (refers to the least amount of analyte
~tifiable based on sample size used and analytical techni~e employed).
~FERENCES:
SW = "Test Methods for Evaluating Solid Wastes P~sical/Chemical Methods",
EPA-SW-846,. Septe~er, 1986.
Flag E~lanations:
* = Note: S~ple analyzed by Adv~ced Tec~olo~ Laboratories.
D~ Schultz
Laboratory Director
cc: CITY OF BAKERSFIELD - HOWARD H. WI~S III
All results listed in this report are for the exclusive use of the submitting party. BC Laboratories, Inc. assumes no responsibility for report alteration, seperation, detachment or third party interpretation.
4100 Atlas Ct. · Bakersfield, CA 93308 . (805) 327-4911 . FAX (805) 327-1918
Te nology - -
Laboratories
January 21, 1998 ELAP No.: 1838
BC Laboratories, Inc.
4100 Atlas Court
Bakersfield, CA 93308
ATTN: Ms. Cheryl Ferguson
Client's Project: 98-00400
Lab No.: 23189-001
Gentlemen:
Enclosed are the results for sample(s) received by Advanced Technology Laboratories
and tested for the parameters indicated in the enclosed chain of custody. , .
· Thank you for the opportunity to service the needs of your company. Please feel free
to call me at (310) 989 - 4045 if I can be of further assistance to your company.
Sincerely;
Edgar P. Caballero
Laboratory Director
EPC/ms
Enclosures
This cover letter is an integral part of this analytical report.
This report pertains only to the samples investigated and does not necessarily apply to other apparently identical or similar materials. This report is submitled for the exclusive
use of the client to whom it is addressed. An)' reproduction of this report or use of ~.'; Labomtor~s name for advertising or publicity purpose w/thout authorization is proh/bited.
Mailing Address: P.O. Box' 9108 Newport Beach, CA 92658
1510 E. 33rd Street Signal Hill, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040
Client: BC Labs . _
Attn: Ms. Cheryl Ferguson
Client's Project: 98-00400
Date Received: 01/15/98 Lab No: 23189-001
Date Sampled: 01/13/98 Sample ID: 98-00400-1
Matrix: Soil
EPA 9020 (TOX) 01/15/98 ND mg/kg 5.0 5.0 IG
MDL = Method Detection Limit
ND = Not Detected (Below DLR)
DF = Dilution Factor (DLR/MDL)
Reviewed/Approved By: (~///,t t; ~ ~ ~: {' ~( ~ Date: //~///~oc/
Cheryl,~le los Reyes
Department Supervisor
Thc cover letter is an integral part of this analytical report.
~l~ ~dvanced Technology
~ J Laboratories 1510 E. 33rd Street Signal Hill, CA 90807 Tel: 562 989-4045 Fax: 562 989-4040
' Methodi: 9020 Date: 01/15/98
Analyst: IG Sample ID: 23147-002
Data File: 8015~1S Matrix: Solid
ANALYTE UNITS LCS Conc LCS Res % Rec ME:I'H BLANK SPL CONC SPK ADDED MS RESULT MSD RESUL'f %MS REC %MSD REC % REC Limit RPD ~ RPD Limit MDL
TOX mg/kg 200 207 104 ND ND- 50 56 52 112 104 55 - 160 7 40 5.0
,
Approved by: _~/'"f./'--~ ~' ?-'/-' ¢'¢,~-''f'-''~'' Date:
Cheryl De Lo~'Reyes ·
Inorganics Supen/isor
~ ~dvanced Technology
Laborato. ries
SUBCONTRACT CHAIN-OF CUSTODY Page 1
Subcontract Lab: ADVANCED TECHNOLOGY LABORATORIES (ADVNC)
1510 E. 33RD STREET
SIGNAL HILL, CA 90807
Attn: PLTRI F. ROMUALDO
Phone: 562-989-4045
FAX: 562-989-6348
Report To: BC Laboratories
4100 Atlas Court
Bakersfield, CA 93308
Attn: Cheryl Ferguson
Bill To: BC Laboratories
4100 Atlas Court
Bakersfield, CA 93308
Attn: Accounts Payable
Sample Sample Sample Requested Tests
Sample ID Matrix Date Time 0_~1
98-00400-1 ~ Soil 01/13/98 09:40 X
Requested Tests Legend
01 HZ-TOTAL-TOX
Relinquished By: ~~.~.~~,~~__~~. ' Date/Time[~[q
Relinquished By:
Received By:
CORRECTION NOTICE
'BAKERSFIELD FIRE DEPARTMENT ,~,..
Sub Div. Blk. Lot
You are hereby required to make the following corrections
at the above location:
Co~. No
Completion Date for Corrections - ':.'::~ ' '~ , ,'~"' ~i' ;'?: . -
Inspector
PEST CONTROL, INC.
P. O. Box 113, Bakersfield, CA 93302-0113 · 323-7858
11 November 1997
Bakersfield Fire Department
Hazardous Materials Inventory
2101 "H" St.
Bakersfield, CA 93301
To whom it may concern,
A correction needs to be made to delete Dursban 50W
Chlorpyrifos and Dursban TC Chlorpyrifos.
Sincerely,
Orland Banks
Owner
OB/tip
BANKS PEST CONTROL INC SiteID: 215-000-000439 +
Manager : BusPhone: (805) 323-7858
Location: 215 GOLDEN STATE Map : 103 CommHaz : High
City : BAKERSFIELD Grid: 30B FacUnits: 1 AOV:
CommCode: BAKERSFIELD STATION 04 SIC Code:7342
EPA Numb: DunnBrad:07-618-5644
Emergency Contact / Title Emergency Contact / Title
ORLAND BANKS / FRANK DAIGLE / SUPERVISOR
Business Phone: (805) 323-7858x Business Phone: (805) 323-7858x
24-Hour Phone : (805) 399-1591x 24-Hour Phone : (805) 871-0529x
Pager Phone : ( ) - x Pager Phone : ( ) - x
+ -+
Hazmat Hazards: Fire Press ImmHlth DelHlth I
+
Emergency Directives:
+= Hazmat Inventory One Unified List +
+== MCP+DailyMax Order Ail Materials at Site +
+ + -+- ~ -+- -+ .... +- - -+
I Hazmat Common Name... ISpeoHazlEPA HazardsI Frm I DailyMax IUnitlMCPl
+ + + ~ + + .... +- - -+
SULFURYL FLUORIDE ., F P IH G 475 FT3 Ext
4Fo5~°~ ....... ~2~J~R=o~-R~-~O~ F DH S 300 LBS Hi
-DL~SB~rTC CIILQ/~?_~2P, I-~S y' F IH L 100 GAL Hi
I, Orland Banks DO hereby cedi~ that I have
(Type or print name)
reviewed the attached hazardous materials manage-
ment plan for Banks P~st Co~t~b~at it along with
(Name of
any corrections constitute a complete and correct man-
agement plan for my facility.
Si gn a~: u re Date
+
-1- 11/04/1997
+ BANKS PEST CONTROL INC SiteID: 215-000-000439 +
+-- Fast Format +
+= Notif./Evacuation/Medical - Overall Site +
+== Agency Notification 05/17/1990 +
CALL 911
+=== Employee Notif./Evacuation 05/17/1990 +
INTERCOM SYSTEM AND CALL 911.
.... Public Notif./Evacuation 05/17/1990 +
ALL EMPLOYEES HAVE BEEN INSTRUCTED IN CASE OF EMERGENCY INVOLVING RELEASE OR
THREATENED RELEASE OF A HAZARDOUS MATERIAL, CALL 911 AND 1-800-852-7550 OR
1-916-427-4341. THIS WILL NOTIFY THE LOCAL FIRE DEPARTMENT AND THE STATE
OFFICE OF EMERGENCY SERVICES AS REQUIRED BY LAW.
+
Emergency Medical Plan 05/17/1990 +
MINOR INJURIES FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN OR
TRANSPORT TO BAKERSFIELD MEMORIAL HOSPITAL WHICH IS THE CLOSEST HOSPITAL
FROM OUR PLACE OF BUSINESS.
-2- 11/04/1997
BANKS PEST CONTROL INC SiteID: 215-000-000439 +
Fast Format +
+= Mitigation/Prevent/Abatemt Overall Site +
+== Release Prevention 07/14/1992 +
TRAINING PROCEDURE FOR PROPER MIXING AND HANDLING OF HAZARDOUS MATERIALS.
TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN.
+=== Release Containment 07/14/1992 +
TRAINING PROCEDURE TO PROPER CONTAINMENT USING SPILL SOAKUP AND OTHER
METHODS, SAND VERMICULITE.
.... Clean Up 07/14/1992 +
TRAINING AND PROPER CLEANUP USING PLASTIC BAGS APPROVED BARRELS AND FINDING
OUT PROPER WASTE DISPOSALS.
Other Resource Activation
3 11/04/1997
+ BANKS PEST CONTROL INC SiteID: 215-000-000439 +
+ Fast Format +
+= Site Emergency Factors Overall Site +
+== Special Hazards - -- 05/17/1990 +
HAZARDOUS POWDER INSECTICIDE CHEMICALS STORED IN STOREROOM IN QUANTITIES
LESS THAN REPORTABLE.
+
+=== Utility Shut-Offs 05/17/1990 +
A) GAS - WEST OUTSIDE WALL ADJACENT TO V ST
B) ELECTRICAL - WEST OUTSIDE WALL ADJACENT TO V ST
C) WATER - WEST OUTSIDE WALL ADJACENT TO V ST
D) SPECIAL - NONE
E) LOCK BOX - NO
+ =====+
+ .... Fire Protec./Avail. Water 05/17/1990 +
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS
FIRE HYDRANT - NORTHWEST CORNER OF V ST AND GOLDEN STATE AVE.
Building Occupancy Level +
+
-4- 11/04/1997
BANKS PEST CONTROL INC SiteID: 215-000-000439
............................. Fast Format
+= Training = Overall Site
+== Employee Training 09/11/1996
WE HAVE 32 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
BRIEF SUMMARY OF TRAINING PROGRAM: ALL EMPLOYEES HAVE BEEN TRAINED AND
INSTURCTED ON WHO TO NOTIFY AND HOW TO HANDLE HAZARDOUS SPILLS.
+=== Page 2 ........
.... Held for Future Use ==
...... Held for Future Use
-5- 11/o /,].997
09/07/95 BANKS PEST CONTROL INC 215-000-000 ge 1
Overall Site with 1 Fac. Unit~/U~\$~ 11 7996
' General Information ~;
Loc~tion: 215 GOLDEN STATE Map:103 Haz:4 Type: 3
City : BAKERSFIELD Grid: 30B F/U: 1 AOV: 0.0
Cpn~act Name Title - Contact Name Title
ORLAND BANKS / FRANK DAIGLE /SUPERVISOR
Business Phone: (805) 323-7858x BusineSs Phone: (805) 323-7858x
24-Hour Phone : (805) 399-1591x 24-Hour Phone : (805) 87I~'0'529X
Pager Phone : ( ) - x Pager Phone : ( ) - x
Administrative Data
Mail Addrs: 215 GOLDEN STATE D&B Number: 07-618-5644
City: BAKERSFIELD State: CA Zip: 93301-
Comm Code: 215-004 BAKERSFIELD STATION 04 SIC Code: 7342
Owner: ORLAND BANKS &~-~aM-~~~)aceqs~ Phone: (805) 323-7858
Address: 4406 KNOLL DR /~9F~-~W~D State: CA
City: BAKERSFIELD Zip: 93308-
Sugary
I, 0RLAND BANKS Do hereby certify !hat i have
(Type or p:'int nasa) : :
reviewed the attached h~ardous m~tefiais manage-
BA~S PEST CONTROL- INC .
a~tha~ ~t ~ong with
meat plan for
any corre~ions ~nsti~u~e a oomple~e and ~[e~ man-
agemen{ plan for my fac, i!~U.
09/07/95 BANKS PEST CONTROL, INC 215-000-000439 Page 2
Hazmat Inventory List in MCP Order
02 - Fixed Containers on Site
Pln-Ref Name/Hazards Form Max Qty MCP
02-003 SULFURYL FLUORIDE Gas 475 Extreme
· Fire, Pressure, Immed Hlth FT3
02-002 DURSBAN 4E CHLORPYRIFOS Liquid 100 High
· Fire, Immed Hlth GAL
02-004 DURSBAN 50W CHLORPYRIFOS Solid 300 High
· Fire, Delay Hlth LBS
09/07/95 BANKS PEST CONTROL, INC 215-000-000439 Page 3
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
02-003 SULFURYL FLUORIDE Gas 475 Extreme
W Fire, Pressure, Immed Hlth FT3
CAS #: 2694-79-8 Trade Secret: No
Form: Gas Type: Pure Days: 365 Use: PESTICIDE
Daily Max FT3475I~ Daily Average285.00FT3 I Annual Amount475.00FT3 -- i~
Storage Press I Temp~ Location
PORT. PRESS. CYLINDER Above JBelow ISTORE ROOM E WALL
-- Conc Components MCP -~Guide
99.0% ISulfuryl Fluoride IExtreme I 15
02-002 DURSBAN 4E CHLORPYRIFOS Liquid 100 High
~ Fire, Immed Hlth GAL
CAS #: Trade Secret: No
Form: Liquid Type: Mixture Days: 365 Use: PESTICIDE
Daily Max GALI Daily Average GAL I Annual Amount GAL
100 i 40.00 1,600.00
Storage Press T Temp} Location
METAL CONTAINR-NONDRUM AmbientJAmbientlSW WALL
-- Conc Components MCP ---~uide
100.0% IDursban IHigh ! 55
02-004 DURSBAN 50W CHLORPYRIFOS Solid 300 High
~ Fire, Delay Hlth LBS
CAS #: 2921882 Trade Secret: No
Form: Solid Type: Pure ]Days: 365 Use: PESTICIDE
Daily Max LBS I Daily Average LBS I Annual Amount LBS --
300 ~ 75.00 3,264.00
Storage Press T Temp Location
BOX IAmbientlAmbientlSW WALL
-- Conc Components MCP --~Guide
100.0% IDursban IHigh ' I 55
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 4
00 - Overall Site
<D> Notif./Evacuation/Medical
<1> Agency Notification
CALL 911
<2> Employee Notif./Evacuation
INTERCOM SYSTEM AND CALL 911.
<3> Public Notif./Evacuation
ALL EMPLOYEES HAVE BEEN INSTRUCTED IN CASE OF EMERGENCY INVOLVING RELEASE OR
THREATENED RELEASE OF A HAZARDOUS MATERIAL, CALL 911 AND 1-800-852-7550 OR
1-916-427-4341. THIS WILL NOTIFY THE LOCAL FIRE DEPARTMENT AND THE STATE
OFFICE OF EMERGENCY SERVICES AS REQUIRED BY LAW.
Emergency Medical Plan
<4>
MINOR INJURIES FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN OR
TRANSPORT TO BAKERSFIELD MEMORIAL HOS]?ITAL WHICH IS THE CLOSEST HOSPITAL
FROM OUR PLACE OF BUSINESS.
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 5
00 - Overall Site
<E>Mitigation/Prevent/Abatemt
<1> Release Prevention
TRAINING PROCEDURE FOR PROPER MIXING AND HANDLING OF HAZARDOUS MATERIALS.
TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN. .. ,~
<2> Release Containment
TRAINING PROCEDURE TO PROPER CONTAINMENT USING SPILL SOAKUP AND OTHER
METHODS, SAND VERMICULITE.
<3> Clean Up
TRAINING AND PROPER CLEANUP USING PLASTIC BAGS APPROVED BARRELS AND FINDING
OUT PROPER WASTE DISPOSALS.
<4> Other Resource Activation
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 6
00 - Overall Site
<F> Site Emergency Factors
<1> Special Hazards
HAZARDOUS POWDER INSECTICIDE CHEMICALS STORED IN STOREROOM IN QUANTITIES
LESS THAN REPORTABLE. ~ ,~
<2> Utility Shut-Offs
A) GAS - WEST OUTSIDE WALL ADJACENT TO V ST
B) ELECTRICAL - WEST OUTSIDE WALL ADJACENT TO V ST
C) WATER - WEST OUTSIDE WALL ADJACENT TO V ST
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire Protec./Avail. Water
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS
FIRE HYDRANT - NORTHWEST CORNER OF V ST AND GOLDEN STATE AVE.
<4> Building Occupancy Level
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 7
00 - Overall Site
<G> Training
<1> Employee Training
WE HAVE 32 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
ALL EMPLOYEES HAVE BEEN TRAINED AND INSTURCTED ON WHO TO NOTIFY AND HOW TO
HANDLE HAZARDOUS SPILLS.
<2> Page 2
<3> Held for Future Use
<4> Held for Future Use
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 1
Overall Site with 1 Fac. Unit
General ]information
I Location: 215 GOLDEN STATE Map:103 Haz:4 Type: 3
City : BAKERSFIELD Grid: 30B F/U: 1 AOV: 0.0
Contact Name Title Contact Name Title ,
ORLAND BANKS / FRANK DAIGLE /SUPERVISOR
323-7
Business Phone: (805) 323-7858x Business Phone: (805) 858x
24-Hour Phone : (805) 399-1591x 24-Hour Phone : ('805) 87i'~'0529~ ........
Pager Phone : ( ) - x Pager Phone : ( ) -
x
Administrative Data
Mail Addrs: 2~5 GOLDEN STATE D&B Number: 07-618-5644
City: BAKERSFIELD ..... State:--CA- Zip: 93301- - -
Comm Code: 215-004 BAKERSFIELD STATION 04 SIC Code: 7342
Owner: ORLAND BANKS &~-l~~~)~aeq~ Phone: (805) 323-7858
Address: 4406 KNOLL DR A2~e__-'. C.~,~JD State: CA
City: BAKERSFIELD Zip: 93308-
Summary
I, ORLAND BA['~S DO hereby certify that I have
(Type o~ print name)
reviewed the aflached hazardous materials msnage-
BANKS PEST CONTaRl.~ha]~,long with
ment plan for
-- (N.~me of Bu~Ine3s)
any corrections constitute a complete and correct man-
agemem plan for my facility.
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 2
Hazmat Inventory List in MCP Order
02 - Fixed Containers on Site
Pln-Ref Name/Hazards Form Max Qty MCP
02-003 SULFURYL FLUORIDE Gas 475 Extreme
· Fire, Pressure, Immed Hlth FT3
02-002 DURSBAN 4E CHLORPYRIFOS Liquid 100 High
· Fire, Immed Hlth GAL
02-004 DURSBAN 50W CHLORPYRIFOS Solid 300 High
· Fire, Delay Hlth LBS
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 3
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
02-003 SULFURYL FLUORIDE Gas 475 Extreme
· Fire, Pressure, Immed Hlth FT3
CAS #: 2694-79-8 Trade Secret: No
Form: Gas Type: Pure Days: 365 Use: PESTICIDE
Daily Max FT3 I Daily Average FT3 I Annual Amount FT3
475 ~ 285.00 475.00
Storage I Press T Temp I Location
PORT. PRESS. CYLINDER Above ~Below STORE ROOM E WALL
-- Conc Components MCP --[Guide
99.0% ISulfuryl Fluoride IExtreme ! 15
02-002 DURSBAN 4E CHLORPYRIFOS Liquid 100 High
· Fire, Immed Hlth GAL
CAS #: Trade Secret: No
Form: Liquid Type: Mixture Days: 365 Use: PESTICIDE
Daily Max GALI Daily Average GAL I Annual Amount GAL
100 I 40.00_ 1,600.00
Location
Storage Press T Temp
METAL CONTAINR-NONDRUMIAmDiont/AmbiontlSW WALL
-- Conc~ Components MCP ---~uide
100.0% IDursban High ~ 55
02-004 DURSBAN 50W CHLORPYRIFOS Solid 300 High
· Fire, Delay Hlth LBS
CAS #: 2921882 Trade Secret: No
Form: Solid Type: Pure Days: 365 Use: PESTICIDE
Daily Max LBS I Daily Average LBS I Annual Amount LBS
300 ~ 75.00 3,264.00
Storage Press T Temp Location
BOX Ambient/AmbientlSW WALL
-- Conc Components MCP ---~uide
100.0% IDursban [High ~ 55
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 4
00 - Overall Site
<D> Notif./Evacuation/Medical
<1> Agency Notification
CALL 911
<2> Employee Notif,/Evacuation
INTERCOM SYSTEM AND CALL 911.
<3> Public Notif./Evacuation
ALL EMPLOYEES HAVE BEEN INSTRUCTED IN CASE OF EMERGENCY INVOLVING RELEASE OR
THREATENED RELEASE OF A HAZARDOUS MATERIAL, CALL 911 AND 1-800-852-7550 OR
1-916-427-4341. THIS WILL NOTIFY THE LOCAL FIRE DEPARTMENT AND THE STATE
OFFICE OF EMERGENCY SERVICES AS REQUIRED BY LAW.
<4> Emergency Medical Plan
MINOR INJURIES FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN OR
TRANSPORT TO BAKERSFIELD MEMORIAL HOSPITAL WHICH IS THE CLOSEST HOSPITAL
FROM OUR PLACE OF BUSINESS.
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 5
00 - Ow~rall Site
<E>'Mitigation/Prevent/Abatemt
<1> Release Prevention
TRAINING PROCEDURE FOR PROPER MIXING AND HANDLING OF HAZARDOUS MATERIALS.
TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN.
<2> Release Containment
TRAINING PROCEDURE TO PROPER CONTAINMENT USING SPILL SOAKUP AND OTHER
METHODS, SAND VERMICULITE.
<3> Clean Up
TRAINING AND PROPER CLEANUP USING PLASTIC BAGS APPROVED BARRELS AND FINDING
OUT PROPER WASTE DISPOSALS.
<4> Other Resource Activation
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 6
00 - Overall Site
<F> Site Emergency Factors
<1> Special Hazards
HAZARDOUS POWDER INSECTICIDE CHEMICALS STORED IN STOREROOM IN QUANTITIES
LESS THAN REPORTABLE.
<2> Utility Shut-Offs
A) GAS'- WEST OUTSIDE WALL ADJACENT TO V ST
B) ELECTRICAL - WEST OUTSIDE WALL ADJACENT TO V ST
C) WATER - WEST OUTSIDE WALL ADJACENT TO V ST
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire'Protec./Avail. Water
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS
FIRE HYDRANT - NORTHWEST CORNER OF V ST AND GOLDEN STATE AVE.
<4> Building Occupancy Level
09/07/95 BANKS PEST CONTROL INC 215-000-000439 Page 7
00 - Ow~rall Site
<G> Training
<1> Employee Training
WE HAVE 32 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
ALL EMPLOYEES HAVE BEEN TRAINED AND ][NSTURCTED ON WHO TO NOTIFY AND HOW TO
HANDLE HAZARDOUS SPILLS.
<2> Page 2
<3> Held for Future Use
<4> Held for Future Use
01/17/95 BANKS PEST CONTROL INC 215-000-000439 Page 1
Overall Site with 1 Fac. Unit
General 2Information
Location: 215 GOLDEN STATE AV Map:103 Haz:4 Type: 3
City : Grid: 30B F/U: 1 AOV: 0.0
Contact Name Title Contact Name Title
ORLAND BANKS / WILLIAM H. ROGERS /
Business Phone: (805) 323-7858x Business Phone: (805) 323-7858x
24-Hour Phone : (805) 399-1591x 24-Hour Phone : (805) 397-4214x
Pager Phone : ( ) - x Pager Phone : ( ) - x
Administrative Data
Mail Addrs: 215 GOLDEN STATE D&B Number: 07-618-5644
City: BAKERSFIELD State: CA Zip: 93301-
Comm Code: 215-004 BAKERSFIELD STAg?ION 04 SIC Code: 7342
Owner: ORLAND BANKS & WILLIAM ROGERS Phone: (805) 323-7858
Address: 4406 KNOLL DR /2524 OAKWOOD State: CA
City: BAKERSFIELD Zip: 93308-
Summary
i, ~'/~'...z--~ .~.//.,.'.,~13o hereby certify that I have
(Type or print rfame)
reviewed the at~ached hazardous materials manage-
ment plan for~/~,~'£~,,-~'~'~ar~d that it along with
(Name of Business)
any corrections constitute a complete and.correct man-
agemem plan ~or rny
(..../ - Signatut~ ' ~1e -
01/17/95 BANKS PEST CONTROL INC 215-000-000439 Page 2
Hazmat Inventory List in MCP Order
02 - Fixed Containers on Site
Pln-Ref Name/Hazards Form Max Qty MCP
02-003 SULFURYL FLUORIDE Gas 475 Extreme
· Fire, Pressure, Immed Hlth FT3
02-002 DURSBAN 4E CHLORPYRIFOS Liquid 100 High
· Fire, Immed Hlth GAL
02-004 DURSBAN 50W CHLORPYRIFOS Solid 300 High
· Fire, Delay Hlth LBS
01/17/95 BANKS PEST CONTROL INC 215-000-000439 Page 3
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
02-003 SULFURYL FLUORIDE Gas 475 Extreme
· Fire, Pressure, Immed Hlth FT3
CAS #: 2694-79-8 Trade Secret: No
Form: Gas Type: Pure Days: 365 Use: PESTICIDE
Daily Max FT3 I Daily Average FT3 I Annual Amount FT3
475 ~ 285.00 475.00
Storage Press T Temp~ Location
PORT. PRESS. CYLINDER Above ~Below ISTORE ROOM E WALL
-- Conc Components MCP ---~uide
99.0% ISulfuryl Fluoride IExtreme I 15
02-002 DURSBAN 4E CHLORPYRIFOS Liquid 100 High
· Fire, Immed Hlth GAL
CAS #: Trade Secret: No
Form: Liquid Type: Mixture Days: 365 Use: PESTICIDE
Daily Max GALI Daily Average GAL I Annual Amount GAL --
100 ~ 40.00 1,600.00
Storage ~ Press T Temp Location
METAL CONTAINR-NONDRUMI/~bient[AmbientlSW WALL
-- Conc Components MCP ---~uide
100.0% IDursban IHigh ! 55
02-004 DURSBAN 50W CHLORPYRIFOS Solid 300 High
· Fire, Delay Hlth LBS
CAS #: 2921882 Trade Secret: No
Form: Solid Type: Pure Days: 365 Use: PESTICIDE
Daily Max LBSI Daily Average LBS I Annual Amount LBS
300 i 75.00 3,264.00
Storage Press T Temp Location
BOX IAmbientlAmbientlSW WALL
-- Conc Components MCP ---TGuide
100.0% IDursban IHigh ~ 55
01/17/95 BANKS PEST CONTROL INC 215-000-000439 Page 4
00 - Overall Site
<D> Notif./Evacuation/Medical
<1> Agency Notification
CALL 911
<2> Employee Notif./Evacuation
INTERCOM SYSTEM AND CALL 911.
<3> Public Notif./Evacuation
ALL EMPLOYEES HAVE BEEN INSTRUCTED IN CASE OF EMERGENCY INVOLVING RELEASE OR
THREATENED RELEASE OF A HAZARDOUS MATERIAL, CALL 911 AND 1-800-852-7550 OR
1-916-427-4341. THIS WILL NOTIFY THE LOCAL FIRE DEPARTMENT AND THE STATE
OFFICE OF EMERGENCY SERVICES AS REQUIRED BY LAW.
<4> Emergency Medical Plan
MINOR INJURIES FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN OR
TRANSPORT TO BAKERSFIELD MEMORIAL HOSPITAL WHICH IS THE CLOSEST HOSPITAL
FROM OUR PLACE OF BUSINESS.
01/17/95 BANKS PEST CONTROL INC 215-000-000439 Page 5
00 - Ow~rall Site
<E> Mitigation/Prevent/Abatemt
<1> Release Prevention
TRAINING PROCEDURE FOR PROPER MIXING AND HANDLING OF HAZARDOUS MATERIALS.
TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN.
<2> Release Containment
TRAINING PROCEDURE TO PROPER CONTAINMENT USING SPILL SOAKUP AND OTHER
METHODS, SAND VERMICULITE.
<3> Clean Up
TRAININGAND PROPER CLEANUP USING PLASTIC BAGS APPROVED BARRELS AND FINDING
OUT PROPER WASTE DISPOSALS.
<4> Other Resource Activation
01/17/95 BANKS PEST CONTROL INC 215-000-000439 Page 6
00 - Overall Site
<F> Site Emergency Factors
<1> Special Hazards
HAZARDOUS POWDER INSECTICIDE CHEMICALS STORED IN STOREROOM IN QUANTITIES
LESS THAN REPORTABLE.
<2> Utility Shut-Offs
A) GAS - WEST OUTSIDE WALL ADJACENT TO V ST
B) ELECTRICAL - WEST OUTSIDE WALL ADJACENT TO V ST
C) WATER - WEST OUTSIDE WALL ADJACENT TO V ST
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire Protec./Avail. Water
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS
FIRE HYDRANT - NORTHWEST CORNER OF V ST AND GOLDEN STATE AVE.
<4> Building Occupancy Level
01/17/95 BANKS PEST CONTROL INC 215-000-000439 Page 7
00 - Overall Site
<G> Training
<1> Employee Training
WE HAVE 32 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
ALL EMPLOYEES HAVE BEEN TRAINED AND INSTURCTED ON WHO TO NOTIFY AND HOW TO
HANDLE HAZARDOUS SPILLS.
<2> Page 2
<3> Held for Future Use
<4> Held for Future Use
-- OONTROL
323-7858 P.O. BOX 113
BAKERSFIELD, CALIFORNIA 93302-0113
10 January 1994
Bakersfield~ Fice Department
Hazardous Materials Inventory
2101 "H" St.
Bakersfield, CA 93301
To whom it may concern,
A correction needs to be made for Dursban 4E Chorpyrifos,
daily maximum-100 gallons, daily average-40 gallons, annual amount
gallons- 1600 gallons.
Sincecely,
OwnerOrland Banks
OB/tlr
01/05/94 BANKS PEST CONTROL INC 215-000-000439 Page
Overall Site with 1 Fac. Unit
~- - .2 .General 2Information
I
Location: 215 GOLDEN STATE Map: 103 Hazard: High
Community: BAKERSFIELD STATION 04 Grid: 30B F/U: 1 AOV: 0.0
Contact Name Title Business phOne 24-Hour Phone]
ORLAND BANKS (805) 323-7858 x (805) 399-1591!
WILLIAM H. ROGERS (.805) 323-7858 x (805) 397-4214/
Administrative Data
Mail Addrs: 215 GOLDEN STATE D&B Number: 07-618-5644
City: BAKERSFIELD State: CA Zip: 93301-
Comm Code: 215-004 BAKERSFIELD STA~ION 04 SIC Code: 7342
Owner: ORLAND'~BANKS &-WILLIAM-ROGERS .......... Phone: ,(805) 323-7858
Address: 4406 KNOLL DR /2524 OAKWOOD State: CA
City: BAKERSFIELD Zip: 93308-
Summary
1
HA~ MA~ DI~
~, _d_~tc~c~ .~ r~-_% Do hereby certify that ~ have
(Ty~ ~ ~int ~e)
reviewed ~he a~ached h~ardous materials manage-
~n~ p~an ~or~~ ~ and.~hat i~ along with
01/05~94 BANKS PEST. CONTROL INC 215-000-000439 Page 2
Hazmat Inventory List in MCP Order
~ ~ 02 - Fixed Containers on Site
Pln-Ref Name/Hazards Form Max Qty MCP
02-003 SULFURYL FLUORIDE Gas 475 Extreme
· Fire, Pressure, Immed Hlth FT3
02-002 DURSBAN 4E CHLORPYRIFOS Liquid 100 High
· Fire, Immed Hlth GAL
02-004 DURSBAN 50W CHLORPYRIFOS Solid 300 High
· Fire, Delay Hlth LBS
01/05/94 BANKS PEST CONTROL INC 215-000-000439 Page 3
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
02-003 SULFURYL FLUORIDE Gas 475 EXtreme
· Fire, Pressure, Immed Hlth FT3
CAS #: 2694-79-8 Trade Secret: No
Form: Gas Type: Pure Days: 365 Use: PESTICIDE
Daily Max FT3 ·l Daily Average FT3 I Annual Amount FT3
475 ~ 285.00 475.00
Storage Press T TempI Location
PORT. PRESS. CYLINDER Above ~Below ISTORE ROOM E WALL
-- Conc ....... Compone~t~ ..... ' MCP --~Guide
99.0% Isulfuryl Fluoride IExtreme [ 15
02-002 DURSBAN 4E CHLORPYRIFOS Liquid 100 High
· Fire, Immed Hlth ~ GAL
CAS #: Trade Secret: No
Form: Liquid Type: Mixture Days: 365 Use: PESTICIDE
Daily Max GALI Daily Average GAL ~ Annual Amount GAL
100 I 4,000.00, 5,000.00
Storage Press T Temp~ Location
METAL CONTAINR-NONDRUM Ambient~AmbientlSW WALL
-- Conc Components MCP ---TGuide
100.0% IDursban IHigh ! 55
02-004 DURSBAN 50W CHLORPYRIFOS Solid. 300 High
· Fire, Delay Hlth LBS
CAS #: 2921882 Trade Secret: No
Form: Solid Type: Pure Days: 365 Use: PESTICIDE'
Daily Max LBS300 I Daily Average 75.00 LBS [ Annual Amount 3,264.00 LBS --
Storage Press T Temp ~Location
BOX AmbientlAmbientlSW WALL
-- Conc Components MCP ---/Guide
100.0% IDursban IHigh ~ 55
01/05/94 BANKS PEST CONTROL INC 215-000-000439 Page 4
00 - Overall Site
<D> Notif./Ew~cuation/Medical
<1> Agency Notification
CALL 911
<2'> Employee Notif./Evacuation
INTERCOM SYSTEM AND CALL 911.
<3> Public Notif./Evacuation
ALL EMPLOYEES HAVE BEEN INSTRUCTED IN CASE OF EMERGENCY INVOLVING RELEASE OR
THREATENED RELEASE OF A HAZARDOUS MATERIAL, CALL 911 AND 1-800-852-7550 OR
1-916-427,4341. THIS WILL NOTIFY THE LOCAL FIRE DEPARTMENT AND THE STATE
OFFICE OF EMERGENCY SERVICES AS REQUIRED BY LAW.
<4> Emergency Medical Plan
MINOR INJURIES FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN OR
TRANSPORT TO BAKERSFIELD MEMORIAL HOSPITAL WHICH IS THE CLOSEST HOSPITAL
FROM OUR PLACE OF BUSINESS.
01/05/94 BANKS PEST CONTROL INC 215-000-000439 Page 5
00 - Overall Site
<E> Mitigation/Prevent/Abatemt
<1> Release Prevention
TRAINING.PROCEDURE FOR PROPER MIXING AND HANDLING OF HAZARDOUS MATERIALS.
TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN.
3
<2> Release Containment
TRAINING PROCEDURE TO PROPER CONTAINMENT USING SPILL SOAKUP AND OTHER
· METHODS, SAND VERMICULITE.
<3> Clean Up
TRAINING AND PROPER CLEANUP USING PLASTIC BAGS APPROVED BARRELS AND FINDING
OUT PROPER WASTE DISPOSALS.
<4> Other Resource Activation
01/05/94 BANKS PEST CONTROL INC 215-000-000439 Page 6
O0 - Overall Site
<F> Site Emergency Factors
<1> Special Hazards
HAZARDOUS POWDER INSECTICIDE CHEMICALS STORED IN STOREROOM IN QUANTITIES
LESS THAN REPORTABLE.
<2> Utility Shut-Offs
A) GAS - WEST OUTSIDE WALL ADJACENT TO V ST
B) ELECTRICAL - WEST OUTSIDE WALL ADJACENT TO V ST
C) WATER - WEST OUTSIDE WALL ADJACENT TO V ST
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire Protec./Avail. Water
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS
FIRE HYDRANT - NORTHWEST CORNER OF V ST AND GOLDEN STATE AVE.
<4> Building Occupancy Level
01/05/94 BANKS PEST CONTROL INC 215-000-000439 Page 7
O0 - Overall Site
<G> Training
<1> Page 1
WE HAVE 32 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
ALL EMPLOYEES HAVE BEEN TRAINED AND INSTURCTED ON WHO TO NOTIFY AND HOW TO
HANDLE HAZARDOUS SPILLS.
<2> Page 2 as needed
<3> Held for Future Use
<4> Held for Future Use
01/05/94 BANKS PEST CONTROL INC 215-000-000439 Page 8
O0 - Overall Site
<H> P~PP DATA
<1> Release Containment
<2> Offsite Consequences
<3> In House Capabilities
<4> Plant Shutdown Instruction
$ RECEIVED
02/24/92 BANKS PEST CONTROL INC 215-000-000439 Page 1
Overall Site.with 1 Fac. Unit MAR 3
' General /information Afl$'d ............
¢
Location: 215 GOLDEN STATE Map:'103 Hazard: High
· Community: BAKERSFIELD STATION 01 Grid: 30B F/U: 1AOV: 0.0
. Contact Name i Title Business Phone 24-Hour Phone-
IORLAND BANKS I (805) 323-7858 x (805) 399-1591
IWILLIAM H. ROGERS (805) 323-7858 x (805)
Administrative Data 397-4214
Mail Addrs: 215 GOLDEN STATE D&B Number: 07-618-5644
City: BAKERSFIELD State: CA Zip: 93301-
Comm Code: 215-001 BAKERSFIELD STATION 01 SIC Code: 7342
Owner: ORLAND BANKS & WILLIAM ROGERS Phone: (805) 323-7858
Address: 4406 KNOLL DR & ~~ 2524 Oak~oo4 State: CA
City: BAKERSFIELD Zip: 93308-
Summary
ffooqo _..
,~,,~ -----.,,.
J], Orland Banks DO hom~ c~i~ that i have
...... ' ........ · :. "~..,~,: ~ate~l~ls manage-
~-A,, ....
...... _Z~5 ~lae. state,: 't,,:! that i! along wilh
.... '....~; ....... ~Zj ...... -
~n~ " ..... =~'.':" , ~ .................. .'- ~ ,,. '
egsme~ pl~s ;or my ;acili~y,
gm.re -- Date
TERMITE CONTROL, COMPLETE PEST CC'' ~0I'
AND STATE LI(,'ENSED - Ih[ ~D
~"U M IGAT I ON LOCALLY OWNE~
323-7858
MIKE WEEK5
S~:RVIC£ D£pT. MANAGg~ ~i5 GCLDE~ STATE AVE,
BAKERSFIELD, CA 93301
02/24/92 BANKS PEST CONTROL INC 215-000-000439 Page .2
02 - Fixed Containers on Site
Hazmat Inventory Detail in Reference Number Order
02-001 PETROLEUM OIL Liquid 55 Low
· Fire, Delay Hlth GAL
CAS #: Trade Secret: No
Form: Liquid Type: Pure Days: 365 Use: OIL TREATMENT
Daily Max GALI Daily Average GAL I Annual Amount GAL
55 ~ 40.00 55.00
Storage Press T TempI Location
DRUM/BARREL-METALLIC Ambient.~AmbientlSTORE ROOM'SOUTH WALL
-- Conc Components MCP List
100.0% IPetroleum Unrefined Hydrocarbons ILow [
-- Notes
02/24/92 BANKS PEST CONTROL INC 215-000-000439 Page 3
00 - Overall Site
<D> Notif./Evacuation/Medica1
<1> Agency Notification
CALL 911 ~
<2> Employee Notif./Evacuation
INTERCOM SYSTEM AND CALL 911.
<3> Public Notif./Evacuation
ALL EMPLOYEES HAVE BEEN INSTRUCTED IN CASE OF EMERGENCY INVOLVING RELEASE OR
THREATENED RELEASE OF A HAZARDOUS MATERIAL, CALL 911 AND 1-800-852-7550 OR
1-916-427-4341. THIS WILL NOTIFY THE: LOCAL FIRE DEPARTMENT AND THE STATE
OFFICE OF EMERGENCY SERVICES AS REQUIRED BY LAW.
<4> Emergency Medical Plan
MINOR INJURIES FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN OR
TRANSPORT TO BAKERSFIELD MEMORIAL HOSPITAL WHICH IS THE CLOSEST HOSPITAL
FROM OUR PLACE OF BUSINESS.
02/24/92 BANKS PEST CONTROL INC 215-000-000439 Page 4
00 - Overall Site
<E> Mitigation/Prevent/Abatemt
<1> Release Prevention
TRAINING PROCEDURE FOR PROPER MIXING AND HANDLING OF HAZARDOUS MATERIALS.
TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN.
<2> Release Containment
Training procedure to proper containment using spill soakup and other methods,
sandvermiculite.
<3> Clean Up
Training and proper cleanup using plastic bags approved barrels and finding out
proper waste disposals.
<4> Other Resource Activation
02/24/92 BANKS PEST CONTROL INC 215-000-000439 Page 5
00 - Overall Site
<F> Site Emergency Factors
<1> Special Hazards
HAZARDOUS POWDER INSECTICIDE CHEMICALS STORED IN STOREROOM IN QUANTITIES
LESS THAN REPORTABLE.
<2> Utility Shut-Offs
A) GAS - WEST OUTSIDE WALL ADJACENT TO V ST
B) ELECTRICAL - WEST OUTSIDE WALL ADJACENT TO V ST
C) WATER - WEST OUTSIDE WALL ADJACENT TO V ST
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire Protec./Avail. water
PRIVATE FIRE PROTECTION - FIRE EXTINClUISHERS
FIRE HYDRANT - NORTHWEST CORNER OF V ST AND GOLDEN STATE AVE.
<4> Building Occupancy Level
02/24/92 BANKS PEST CONTROL, INC 215-000-000439 Page 6
00 - Overall Site
<G> Training
<1> Page 1
WE HAVE 32 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
ALL EMPLOYEES HAVE BEEN TRAINED AND INSTURCTED ON WHO TO NOTIFY AND HOW TO
HANDLE HAZARDOUS SPILLS.
<2> Page 2 as needed
<3> Held for Future Use
<4> Held for Future Use
o I~Z~RDOUS P~TERIAtS ~'NV~NTORY
~ Fa~ and Agriculture ~ Standard Business ~' Page 1 of
NON - ~E SEC~T
BUSINESS N~: Banks Pest Control~ Inc. O~ER N~:0rland Banks & ~illiam Ro~ers N~ OF THIS FACILITY:Banks ~est Control
LOCATION= 215 Golden State Ave. ~D~SS:4406 Knoll Dr. & 2~2~ 0akwood ST~D~ IND. CLASS CODE: 7342
CITY, ZIP= Bakersfield~ CA' 9330~ CITY, ZIP= Bakersfield~ CA 93308 & 9330'4 DUN ~D B~ST~ET N~BER/FEDE~ ID ~
PHONE ~: (805) 323-7858 PHONE .%: '(805) 399-1591 & 397-4214 0 7 - 6 1 8 - 5 6 4 4
~ ~ INS~U~IONS ~R PROPER ~D~S
i 2 3 4 5 ' 6 7 8 9 10 11 12 13 . 14
Tr~s ~e ~ Average ~nual Measure ~ Days Cont Cont Cont =Use Location Where % by N~s of M~ture/Com~nents
Code C~e ~t ~ ~t Un,ts on Site ~ Press Temp Code Stored ~n Facility ~ See Instructions
D ~ P ~ 55 ~ 40 ~ 55 ~gallons~ 365 ~ 06 ~ 1 ~ 4 ~ 18~storeroom south~wall 100 petroleum unrefined hydro-
carbons
P~cal and H~lth Hazard C.A.S. Nu~er Component ~ 1 N~e & C.A.S. N~er
(Check all that apply) Component ~ 2 Name & C.A.S. N~er
of Pressure Health H~lth Component ~ 3 Na~ & C.A.S. Nu~er
Physical and H~lth Hazard C.A.S. Nu~er Component ~ I I{~ & C.~ ...... ~-
(Check all that apply) Co~onent ~ 2 Na~ & C.A.S. N~er
~ Fire ,az~d ~ Sudden ~lease ~ ~.a¢tivity ~ Im~i~t. ~ D.l~y~
of Pressure H~lth H~lth Component ~ 3 Na~ & C.A.S. N~er
Physical and H~lth Hazard C.A.S. N~er Component ~ i Na~ & C.A.S. N~er
(Check all t~t apply)
Component ~ 2 Na~ & C.A.S. N~er
of Pressure Health H~lth Component ~ 3 Na~ & C.A.S. N~er
Physical and H~lth ~zard C.A.S. N~er Component ~ i Na~ & C.A.S. N~er
(Check all t~t apply) Component ~ 2 Na~ & C.A.S. N~er
of Pressure H~lth H~lth Co~on~t ~ 3 N~ & C.A.S. Nu~er
E~RGENCY CONTACTS ~1 0rland Banks ~er 323-7858 ~2 Nilliam RoKers 0~er 397-4214
Na~ Title 24 ~. Phone N~e Title 24 Hr Phone
Certification (~ ~D SIGN AFTER COMPLETING ~L SECTIONS)
I certify ~der p~nlty of law that I hayer ~rsonally ~in~ ~d ~ f~lli~ with the info~ation su~itted in ~is ~d all attached d~ents ~d ~at ~sed on ~ in~i~ of those
individuals res~nsible for obtaining the info~tion. I believe that ~e su~itted info~ation is t~e, acc~ate, and c~plete.
~' Orland Banks-~r~Operator 3-2-92
N~ ~ SFICI[ TI~ OF ~OP~R OR ~OP~R'S Au~O~D ~P~'~I~ DA~ SIO~D
CITY OF BAKERSF I EI.D
· I.h%ZARDOUS MATERIALS INVENTORY l'"
t~ Fa~ and Agriculture~ Standard Business : Page lJ of
NON - TRADE sECRET .-. :' ·
BUSINESS N~MEI ~anks Pest Control . . .... /--:'- OWNER NAHEzOrland Ba~ks &"William. R~ge~rfi.~ OF TI~IS F~CILITY* =07.-618-5655 _
LOCATION, .2.15 ~de~-..qt~r,'Stat~' Ave . .. ' ADDRESS'4?.06 KnoLl Dr.--2524 0akw°od'. -' ST~NDABD IND. dLASS f~DEi ~T4% .
CITY, ZIP! ,-, ~4.~ ~. o~qn]' ,CITY, Z~P'. BakerSfield Ca ' q330R'- ' DUN AND BR~DSTREET MBE~/FEbE~
r~FER ~ INSTRU~IONS FOR PIIOPER
~C~e ' C~e ~t ~t ~t ~'UnIte on Site ~ P;eas Tamp Code Stated In Factlit~~ flee Instructions
, Hydrocarbons .~ '. '
(Ch~all that apply) ' '. "'
Component J 2 Na~ & C.A.8.
at Pressure Boalth Bealth Component J 3 Ha~ & a.A.8.
~ ~ursban T¢ Chlorpyr~f. os
~h~l~al and ~lth ~az~rd C.A.S. Numar Component I I Ha~ g C.A.B. N~er
(ch~k oil that apply)
Co~onent ~ 2 Nam ~ C.A.B. ~u~er
or proamuro Health ~ealth Co~onenk J 3 HaM G C.A.B. Humor
AIM 1~75 cut' 285cuf' . ]365 [04 I' 2 16 J 30JStore E wall .._o/~ ' ' .." '..,
(chock all t~t apply) . -- d
~, component f 2 ~a~ a C.A.a. Hu~ec
of Pressure Health Bonita Component f ] Nam t C.A.B. ~u~or ]
~h~leal a~ H~lth ~azard ~.Axa. ~er Component I t Ha~ I C.A.a. H~er
(cheak..'all tbt apply). ........
" . Component I Z Ha~ G C.A.B.
o[ Pressure Ilaalth Bonita Component I 3 H&M I ~.A.B. Humor
E~ROENd~ CONTA~T~ fi Orland Ban~ President 399-1591 12 Wi,l~i~m R08ers ' "S~ec'retdry, Treas. 397'42~
Ce~tlfleatlofl (~AD AND SIGN AFTER COMPLETING ~L SECTIONS)
~ certify ~doF p~nlty of law that I hayer ~reonally ~in~ and ~ familiar with tho lnfo~atlon submitted In this and all attached d~ente ~d that ~eod off ~ ln~l~ at thegn
'fldlvJdualw ree~nelblo for obtaining tho,lnformt~on~ I believe that the submitted Info,arian la t~o, acetate, and o~plote.
Or,and Banks
" JA~ 1 7 1989
Do hereby certify that. i have reviewed the
attached Hazardous Materials business Dian
(name of business)
and that it along with the attached additions
or corrections cons~=,, e a comDlete and correct
Business Plan for my facility.
BUSINESS NAME BANKS P CONTROL INC ID NUM Z1S-0~-0~0439
LOCATION Z15 GOLDEN STATE HIGH HAZARD RATING
1. OVERVIEW
LAST CHANGE 07tlS/88 BY ESTER
JURIS CODE Z1S-~I JURIS BAKERSFIELD STATION 01
MP~ PAGE 103 GRID 308 FACILITY UNITS 1 HAZARD RATING 4
RESPONSE SUMMARY
ZA SEC 4> NO PRIVATE RESPONSE TEAM.
EMERGENCY CONTACTS ZA SEC Z>
ORLAND BANKS - 3Z3-7858 OR 399-1591
WILLIAM H. ROGERS - 3Z3-?BS8 OR 399-t4Z!
UTILITY SHUTOFFS ZA SEC 3)
A) GAS - W OUTSIDE WALL ADJACENT ,TO' V ST 8) ELECTRICAL - W OUTSIDE WALL
AOSACENT TO V ST C> WATER - W OUTSIDE WALL ADJACENT TO V ST
O) SPECIAL - NONE E) LOCK BOX - NO
NOTIFICATION / PUBLIC EVACUATION
LAST CHANGE / / BY
f #2 Notification/Public Evacuation
All employees have been instructed
in case of emergency invloving release
or threatened release of a hazardous
material, call 911 and 1-800-852-7550
or 1-9116-427-4341. This will notify
the local Fire Department and the State
Office of Emergency Services as required
by law.
PAGE 1 tZ/Z3/88 15:'34
MATERIAL SAFETY DATA SYSTEMS. INC. (805) B48-G80~
o.? '" BUSINESS NEME BANKS PEST CONTROL INC I0 NH 45-000-000439
?
LOCATION ZIS GOLDEN STATE HIGH HAZARD RATING 4
3. HAZ MAT TRAINING SUMMARY
LAST CHANGE / / BY
#3 Hazardous Materials Training Sunmlary I
Ail employees have been trained and
instructed on who to notify and how to
handle hazardous spills.
4. LOCAL EMERGENCY MEDICAL ASSISTANCE
LAST CHANGE.O?/tS/88 BY ESTER
SEC S) MINOR INJURIES FIRST AID TREATMENT OR PERSONS OWN PRIVATE PHYSICIAN
OR TRANSPORT TO BRKERSFIELO MEMORIAL HOSPITAL WHICH IS THE CLOSEST
HOSPITAL FROM OUR PLACE OF BUSINESS.
#4 Local Emergency Medical Assistance
Mimor Injuries first aid treatment to:
Dr. W.B. Christiansen, 2021 22nd St.,
Bakersfield 327-9617
Major injuries first aid treatment to:
Memorial Hospital, 420 34th St.,
Bakersfield 327-1792
PAGE Z lZ/Z3/88 tS:34
MATERIAL S~FETY DATA !SYSTEMS, INC. (80S) 848-8800
BUSINESS NAME BANKS PEST CONTROL INC I0 NUN Z15-0~-(~00439
LOCATION ZlS GOLDEN STATE HIGH HAZflRD RATING 4
FACILITY UNIT 01
A. OVERALL HAZARDOUS MATERIALS INVENTORY
LAST CHANGE 0'7/15/88 BY ESTER
ID TYPE NAME MAX AMT UNIT HAZARD
LOCATION CONTAINMENT USE
1 PURE VIKRNE 1425 FT3 HIGH
STOREROOM EAST WALL PORTABLE PRESS. CYL. PESTICIDE
ID PERCENT COMPONENTS HAZARD LIST
ZS73.00 100.0 SULFURYL FLUORIDE HIGH
Z PURE BASE OIL C 55 GAl. UNKNOWN
STOREROOM W WALL DRUMS OR BARRELS MET.. SPRAYING
ID PERCENT COMPONENTS HAZARD LIST
2736,00 100.0 PETROLEUM CRUDE OIL UNKNOWN
FIRE PROTECTION / WATER SUPPLIES
LAST CHANGE 07/tS/88 BY ESTER
3A SEC 4) FIRE EXTINGUISHERS FOR FIRE PROTECTION.
3R SEC S> FIRE HYDRANT NW CORNER OF V ST AND GOLDEN STATE AVE.
PAGE 3 12/Z3/88 1S:34
MATERIAL SAFETY DATA SYSTEMS~ INC. (805) 648-6800
BUSINESS NAME BANKS PEST CONTROL INC ID NUM.___~_ Z1S-OOO-O(~43B
LOCATION Z~S GOLOEN STATE HIGH HAZARO RATING 4
B. EMPLOYEE NOTIFICATION / EVACUATION
LAST CHANGE 07/1S/88 BY ESTER
SEC 2) INTERCOM SYSTEM AND CALL ~11.
MITIGATION / PREVENTION / ABATEMENT
LAST CHANGE 07/1S/88 BY ESTER
SEC ~) TRAINING PROCEDURE FOR PROPER MIXING AND HANDLING OF HAZARDOUS
MATERIALS. TRAINING PROCEDURE FOR CHEMICAL SPILL EMERGENCY PLAN.
PAGE 4 1Z/ZS/88 15:34
MATERIAL SAFETY DATA SYSTEMS, INC. (805) G48-G800
CITY' of BA KERSt':Tt:-LD
Page
!SUSINESS NAME: Banks Pest Control, Inc. OWNER NAME: Orland Banks, Willaim H. Rogers NAME OF T~S FACILITY:~
LOCATION: 215 GOlden State Ave. ADDRESS: 215 Golden State Ave. STANDARD IND.-~S~ ~ODE 7~42
CITY, ZIP: Bakersfield, CA 93301 CITY, ZIP: Bakersfield, CA 93301 DUN AND BRADSTREET NUMBER
?~{ONE ;.: 323-7858 PHONE ~: 399-i591 399-14~1 .,. 0 7 - 6 1 8- 5 6 4 4
R~R TO INSTRUCTIONS FOR PROP~ CODES
Trans Type Max lvera~e Annua{ ~asure I ~s C~t C~t C~c Use I~aKt~ W~re % by Name9 of Mixtuve/Comoon~s
Cooe Cooe im~ lm~ Es~ Units ~ 5t~m TVpm Prmm~ Tem~ C~m .. Store~ {n Fac{{{~y Wt See instructions
Physical and Health Hazard C.A.$. 8u,b,~ 002-699-79-8 C~,nt m~ N,~ ~ C.I.S. ~,b,~ Vikane
(Ch~k all that apply) 002-699-79-8
~ J Fi~e Hazard L__~ Reactivity ~]ay~ ~dd~ E~]ease [~ I~fate ~e~ ~n~ed~en~s
}Physical and Hca th Hazard C,I.5. Nu,~,e 74-83--9 c~mt II Ma~ & C.I.S. Nu~ice
Health of Pre~sure He~tch ................................................................
C~t 13 Na~ & C.I.t. Number
Physical and Health Hazard C.~.~. Numar ........................ C3~t Il NaN & C.&.5. Numbe~
(Ch~ all that apply) ......................................................................
~u Fire Hazard Reactivity Oelay~ Sudd~ Release u_a [~tetm ·
Health o~ Pressure Health .............
C~t 13 N4~ A C.A.S. Numar
~hvsic41 and Health Hazard C.X.S. Numbe~ ~B--89--9 C~ II NaN & C.A.5. Numb.c 1~0
(Ch~k all thai apply) ..........................
~ealth o~ Pressure ~e~ltn 1330-20-7 --,
C~t 13 Na~ & C.A.5. Numar Inert Ingredients
~(~E~CVC0N~AC~S m~ Orland Banks o~er 399-1591 mi William H.Rogers o~er 399-142
Certification (Rend and ~Jgn after completing aJJ secCfons)
I cer=~fy undee ~alry of }am ~ [ have pecs~a]ty exa=in~ and a. fa~Hae ~J~h the ~nfoc~tm sub~t~ In ~hls and aH ~t~c~ d~u~s, and ~ha[ based ~ =y inquiry of c~se individuals ce~p~sib]e
for obtaining the infor~Ci~, ! believe C~t the submi~te~ intormact~ is true, accura¢e, and complete.
U.S. DEPARTMENT OF LABOR
Occupational Safety and Health Administration
Requir~ under USDL Safety and Health ~egulations for [;hip ~epairing,
~ipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)
SECTION I ~Er~C 800/424-9300
MANUFACTURER'S NAME EMERGENCY TELEPHONE NO,
V~ WA~ & ~E~ 408/Z63'9900
ADDRFS5 {Number, Street ~ ~tate; ~"nd ~P CodeJ
~6.~ ~~l~. P~O~ ~ ~9~. ~ t~O. ~. 94403
CHE~Cnm NA~A~YNONYM~ --~ -'-- j TRADE NAME ANDSYNONYM5
~L B~IDE-B~OE~-~ ~{CO ~L B~IDE
' ~ICAL FAMILY J FORMU~
S~CIION II - HAZARDOUS INGREDIENIS
TLV TLV
PAINTS, PRESERVATIVES, & ~LVENTS % {Units) ALLOYS AND METALLIC COATINGS % {Uni~)
PIGMENT5 BASE METAL
CATALYST ALLOY5
VEHICLE METALLIC COATINGS
FILLER METAL
SOLVENT5 PLUS COATING OR CORE FLUX
ADDITIVES OTHERS
OTHER5
TLV PEL
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, Off GASES % (Units)
~L BR~ I DE 00
SECTION III - PHYSICAL DATA
BOILING POINT (°F.) 40 F SPECIFIC~GRAVITY (H20=]) ! . 68
o PERCENT, VOLATILE
VAPOR PRESSURE (mm Hg.) ! 00 F' 30PS ] G BY VOLUME (%) ! 00%
EVAPORATION RATE
VAPOR DENSITY (AIR=l) 3. 5 ( =1)
SOLUBILITY IN WATER 300
CLEAR, COLORLESS LIQUID ~'HICH UNDER NORMAL AT3~IOSPHERIC CONDITION
APPEARANCE AND ODOR
FREEZE.~ TO WH ! TE CRYSTALS WH ! CH SLO~rLY ,~UBL I ME
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (Method used) ]FLAMMABLE LIMITS Lei Uel
I
EXTINGUISHING MEDIA
FOE COOL I NG .' t~JATER FOG , FOAM , ALCOHOL FOAM · COz DRY CHEM I CAL
SPECIAL FIRE FIGH(ING PROCEDURES
SELF CONTA ! NED RESP I RATORY EQU ! PMENT
UNUSUAL FIRE AND EXPLOSION HAZARDS
CONTA I HERS MAY RLIPTURE V I OLENTLY I N F ! RE .
PAGE (1) (Continued on reverse side) Form OSHA-20
Rev. May 72
SECTION V - HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE
~5 PPI~/P~"L 20 PI='M
EFFECTS OF OVEREXPOSURE
NAUSEA, D ! ZZ I NE:SS, U~CONSC I OUSNESS, ~4AY CAUSE RESP I RATOR'Y ! RR i TAT I ~ ( EDEI',IA ) AND
SEVE:R~ I NJUFD/ TO 'n-tE NER'VOI..~ ~J~TEH.
EMERGENCY AND FIRST AID PROCEDURES
NEVER GIVE FLUIDS OR IN~L.ICE VOf,~IITING, IF PATIENT IS ~OI'~;CIOUS OR HAVING CONVtJLSI ',,IS,
PROMPTLY r:'-'-'-'-'-'-'-'-~EMOVE PER~ON TO FRESH A ! R AND G, I YE ART ! F I C I AL tr;~SP I RAT i ON I F BREATH I NG H S
STOPPED. WASH CONTAMINATED SKIN WITH SOAP AND WATER.
....... SECTION VI.; REACTIVITY.DATA
- CONDITION5 TO AVOID
STABILITY UNSTABLE FIRE D~AY CAUSE CYLINDER~ TO RUPTURE VIOLENTL~ -
STABLE ~,,
INCOMPATABILITY r~oter~]$ to ~TvOiZ~)
WATER W ILL CAUSE CORROS I ON OF CONTA !NER. "ALUM I I'~.IM AND [,',ACk,ES I U/.{ AND THE I R ALLOYS.
HAZARDOUS DECOMPOSITION PRODUCTS
HYDROGEN BF~3~tlDE IF E.)Q:'OSED TO HOT FLAJ~E,
HAZARDOUS MAY OCCUR I CONDITIONS TO AVOID
POLYMERIZATION
WILL NOT OCCUR ~
-:"- '? SECTION Vll",-,, SPILL OR LEAK PROCEDURES
STEPS. TO BE TAKEN IN CASE MATERIAL IS RE.LEASED OR SPILLED ........
SEE ATTACHNIENT
WASTE DISPOSAL METHOD
SEE ATTACI-I]~ENT
SECTION VIII - SPECIAL PROTECTION INFORMATION
RESPIRATORY PROTECTION {Specify type)
F"c/r'L;_ FACE GAS MASK..W ! TH' A BLACK ORGAN I C V.t~=~J:~ CANN 1STER OR SELF - CONTA I NED F3;'~ATI-I I
VENTI' ATI--N J LOCAL EXHAUST
PROTECTIVE GLOVES I {YE PROTECTION CHEMICAL ~ORKERS GOGGLES-FUL
'~ ~L~LENE GLO~S [FACE GAS }IASK OR SELF CONTA i NED BREATH I NG [PPAPATIJS
OTHER PROTECTIVE E~UIPMENT ~ENERALLY IT IS RE,COM~EN~E~ THAT ~INIMAL CLOTHINR. ~E BORN.
USE POLYETHYLENE PRO~ECT I VE ~EAR; NOT - RUB BER OR ~EATHER ~
SECTION IX - ~ECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
M~iTOR V/I~ 5UIT~LE DE~CTING E~I~,{E~. ~ W~A~ ~LO~S, FidCOR RIN~ OR
~SI~ B~AGES ~ ~5 ~EN ~LING.
OTHER PRECAUTIONS
~MO~ CLO~ING P~TLY IF SPILLIED. P~VIDE [~H FACILITIES FOR ~S ~D ~KIN ~A
W~ ~A. V~R T~PED ~ TO SKIN t~Y ~USE SE~ DELA~D ~.
PAGE (2) Form OSHA-20
GPO i~-5~ Rev. May 72
· / U.S. DEPARTMENT OF LABOR
. OMI No. 44,-R]317
MATERIAL SAFETY DATA SHEET
RNui~ ul ~L ~f~y ~ Hul~ ~l~i~ for ~ip
/ ~i~ildq, ~ ~ip~miq4~ CFR 1915, 1916, 1~17)
SECTION I
MA~FACTURiR~ N~E I EM[~G~Y T[~(~ON[ NO.
Los Angeles ~nemical Company
~omE~(N~m~'~'C~Y'~e'~PC~)4545 Ardine St~, South Ga~e, ~ 90280-1987
Gamma isomer benzene hexachloride in xylenei L1ndane
' c~E~'~'~Y chlorinated hydrocarbon ~ ~o~u~ C6H6C16+CsH10
SECTION II - H~ARDOUS INGREDIENTS
TkV TLV
PAINTS, PRESERVATIVES, & ~LVEN~ % I~RI ALLOYS ~D METALL~ ~TIKI ~ (~u)
PIGM~NTS BAS~
CATALYST A~OYS
VENIC~ M[TA~C COATI~S
~FI~R M[TA~
AOOITIV[S OTHERS
OT~EAS
TLV
R~ac~o~oc~c~o~a~e - ~a~a Ssome~ CA~ #~8-89-9
SECTION III - PHYSICAL DATA
· o,u.~ ~om~ C'~'.) 760 mm H~ 275OF ' S4~ClFIC G"AVlT-¥ I']0'i} 0. ~ -'- I
VA~R PR[S~R[ (mm ~.) ~RC[N7. VOLATI~
IY VOLUME (~} ~, ~
,
, ;LUIILI~Y IN WATEI emu:Lsifia' ,le'
SE~ION IV - FIRE ~D ~PL~ H~D DATA
~ ~*~ (~~) 70°~ (cc) w~~ ~M~?s ~
~lume
~~ Mmo~ Foam, carbon dioxide, dry chemical '"
~ ~m~ ~m~ 9~.~ Cool intact containers with water
PAGE (11 (~~ ~ ~ ~) F~ ~-~
122
: SECTION V - HEAL I'H HAZARD DATA
T.~eS~L~L,M~TV~.U[ oral LD50(Rats) 125 mg/kg
-(;F----~¢?$OF O¥[R£XPOSUR[ Mucous membrane .irritation, headache, nausea, abdominal pain.
Liver and ki~ney damage, possible de~ati~is
Skin: Flush with soap and water. E~es: Flush with water for at least 15 minutes.
Inhalation: Remove to fresh air. Ingestion: IBduce yomitin~ and ~et i~ed~ate
medical attention for al~ over,exposures. ,..
~ION VI - RE~TIVITY DATA
STABS[
~AZARDOUS UECUM~SITION PRODUCT~
~'o~c and at,Sd ~u~es ~ ~nvolve~ ~n a ~$~e.
COND~TI~S TO AVOID
~ZAR~US MAY OCCUR
wi~ ~T oCCuR
~CTiON VII - ~I~LL OR LEAK PR~EDURES
ST[~ TO ~ TArN IN ~SE ~T~RI~ IS R&~D
w~TE Dl~ METHOD
SECTION VIII - SPECIAL PROTECTION INFoRMaTION ..........
i'~"[S~.~rc)~~'K)N (S/~';i/;, '~Pt)use approved respirator to avoid breathing mist.
YENTII.ATION ~,~X.AUST General room ventilation S4qC~A~.
,~:.,~,,r. AL ta,,-,,~ .......... o'r,~R-'
'"O?'?W' GL~V'S Impervious ,I ~'--'~'' Chemical safet~ goggles
PA[~l~S TO M TArN iN ~OU~ ~ SToi~iM ' · '
S~ore 5p cool place~ away from oxi~zers
or sources of ignirSon.
o~8~8~m1~$ Follow label directSons and cautions carefully.
lie, MOt' 71