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HomeMy WebLinkAboutBUSINESS PLAN (~]FrTC~[AL. _ . .... ..~,:, ;],Yi'.v- ~-Geotechnical Specialists HAZARDOUS MATERIALS BUSINESS PLAN Presented by: Cai/Oak Shell 1130 Oak Street Bakersfield, California 9330~ BH BH157A ~ B~d BH 103 I05 BH BH BH BH BH BI-I BH BH IO~ ~1~ ~t t33 ..... 70~- -' 17) ~35-590 460 440--- t.064,000E o iooo 2000 1,068,000E 1,070,000E 460 440 Krazan ~ associates, inc. HAZARDOUS MATERIALS BUSINESS PLAK Presented to: Bakersfield City Fire Department by: Cai]Oak Shell 1130 Oak Street Bakersfield, Calfornia 93304 Prepared by: Krazan & Associates, Inc. 3860 North Winery Avenue Fresno, California 93726 (209) 291-7337 CONTENTS BUSINESS PLAN Emergency Response Plan and Procedure Hazardous Materials Training for Employees APPENDICES Summary of Business Plan Requirements General Information and Employee Training Program Introduction to Material Safety Data Sheets (MSDS) BAKERSFIELD CI~/ FIRE DEPARTMENT 2130 "G" S]~REET BAKERSFIELD. CA 93301 (805) 326-3979 iUSINESS NA>IE OFFICIAL USE ONLY ID~ '1 I i I I I I i I HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE FORM 2A INSTRUCTIONS: 1. To avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: Ca]/0ak She]] B. LOCATION / STREET ADDRESS: l l30 Oak Street CITY: Bakersfield ZIP: 93304 BUS.PHONE: (805) 322-2997 I I I SECTION 2: EMERGENCY NOTIFICATIONS In case o'f an emergenCy involving the release or threatened release of a' hazardous material, call'911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire depar~men~ and the State Office of Emergency Services as required by law. '~ EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE DURING BUS. HRS. A. Rick ~Howard Ph~ 322-3127 AFTER BUS. HRS. Ph~ 325-9595 'B. Jimmy Kennedy Ph~ 831-050'2 Ph#. 835-8749 SECTION 3:' LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A W~OLE A. NAT. GAS/PROPANE: B. ELECTRICAL: See page 3B C. WATER: D. SPECIAL: I I E. LOCK BOX: YES / NO IF YES, LOCATION: IF YES. DOES IT CONTAIN SITE PLANS? FLOOR PLANS? - 2A YES / N0 YES / NO MSDSS? %'ES / NO KEYS? YES / NO SECTI'O?I .~.: o~fVAT~ ~ESPq:ISE TEAM .,OR LRI;~t.,n~.S AS A WI{OL'r SEE AITACHED EMERGENCY RESPONSE PLAN & PROCEDURES SECT!O."T 5: LOCAL EM£RGE?iCY M£DICAL ASSTSTANCE FOR TOt;q? BUS!.N£SS AS A WHOLE I I I I I Mercy Hospital 2215 Truxtun Ave Bakersfield 328-5275 Bakersfield Memorial Hospital 420 34th ST Bakersfield 327-1729 SECTION 6: EMPLOYEE TRAINING E.MPLCYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES E:.!PLOYEES WITH i):ITIAL AND REFRESHER TRAI.YING IN THE FOLLOWING AREAS. I CIRCLE YES OR NO INITIAL A. METHODS FOR SAFE HANDLING OF HAZARDOUS : ....................................... ~YES~ .%'0 >L~TER IALS B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGEE;CIES: .......................... E~ XO C. PROPER USE OF SAFETY EQUIPME.~:T: .................. D. E:.!EEGE:':CV EVACUATION PROCEDURES: ................. -:fO E O0 YOU .[A[JT.-,[N EMPLOYEE TRAINING RECORDS: ....... NO REFRESHER ¢~:~o ~0 5:0 NO SECTION 7: RAZARDOUS .~ATERIAL CIRCLE YES - NO - NONE DOES YOUR 3USi>JESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUZDS OF A I underst~d that's' ' '"tg,i"'yinformation will be used to fulfill my firm's obligations underI the new California PIqEalth and Safety code on Hazardous Materials (Div. 20 Chapter 6.95~ -- -- Sec. 25500 Et Al.) and that ~naccurate information constitutes perjury. I I I I I I BAKERSFIELD CITY FiRE DEPARTMENT 2150 "G" STREET BAKERSFIELD, CA 93301 OFFiCiAL USE ONLY BUS IF;ESS NAME: ID# I BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. 'TYPE,"PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as gRIEF and CONCfSE as possible. FACILITY UNIT~ FACILITY UNIT NA~E:' Cal/Oak Shel 1 SECTION I: MITIGATION, PREVENTION, ABATEMEN~ PROCEDURES SEE ATTACHED EMERGENCY RESPONSE PLAN & PROCEDURES SECTION ~: NOTIFICATION AND EVACUATION PROCED~ES AT THIS L~iT 0.~L, SEE ATTACHED EMERGENCY RESPONSE PLAN .& PROCEDURES - 3A - SECTION 3: ItAZARDOUS .~ATERIALS FOR THIS I~IT ONLY A. Does this Facility Unit contain Hazardous Materials? ...... ~ NO If YES, see B. If NO, 'contimm with SECTION 4.. B. Are any of the hazardous materials a bona fide Trade Secret YES O If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (~d~ite form -~4A-1) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow form ~4A-2) in addition to the non-trade s'ecret Form. List only the trade secrets on form 4A-21 SECTION 4: PRIVATE FIRE PROTECTION Fire extinguisher.located in cashier's booth SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS Hydrant located on sidewalk 30 feet south' of site fronting Oak St SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY. A. NAT. GAS,PROPANE': N/A B. ELECTRICAL: Service panel in storage building at south edge of site c. WATER: Located in sidewalk at southwest corner of site D. SPEC!AL: Emergency pump shut-off in cashier's booth E LOCK BOX: v~.s ' NO IF YES LOCATION: BSnder located' ~n cashSer's booth [F \c.s S ~ ~' .'.70 '~', [,,: PL:\.YS? , FLOOR PLAXS? ~/ NO )ISDSs? ~" XO KEYS? YES m m m m m m m I{{mm~m{ER.~m~m{m~LD{Tyim~m{~E___ __ .... __ ~~{m}AR,MJ{!{.~T m m m m m m ~.D. ~ FORM 4A-1 Pa~e ~.~ . NON--TRADE SECRETS HAZARDOUS MATE RI ALS INVENTORY BUSINESS NAME: Cal/Oak Shell OWNER NAME: Del Livingood FACILITY UNIT ~: ADDRESS: 1130 Oak St ADDRESS: 3623 California Ave FACILITY UNIT NA~IE: 2040622-9 CITY, zIpl~akersfield, CA 93304 CITY,ZIP: Bakersfield, CA 93309 · I ' A Jim PHONE #: (805) 322-29g~ PHONE #: (805) 322-31~22 - OFFIC[ USE CFIRS CC, i-~F~ 'i { ONLY i I 2 3 4 5 6 ? 8 9 10 I'YPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD [:ODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE_._.,!i!J!!!~ ~ Near center of site M 10,000 350,000 GAL 01 19 On S. si. deiof ki:osk 100 Shell Regular Gasoline FLLQ R.U. 2000 M 10,000 400,000 GAL 01 19 " " 100 Regular Unleaded FLLQ S.U. 2000 M 10,000 1250,000 GAL 01 19 " " 100 Super Unleaded FLLQ NAME: TITLE: ' /'~'~ S GNATURE: -~3 DATE: ~ ~_.~ KHEROENC¥ CONTACT:R Howard ' ~' II'I~I,E: Manacer ' PIIO~I-E ~/,/~US HOURS: 322-3122 - - AFl'ER BUS HRS: 325-9595 EMERGENCY CONTACT: Jimmy Kennedy TITLE: Manaqer PHONE # BUS HOURS: 831-0502 ('RINCIPAL BUSINESS ACTIVITY: Gasoline sales AFTER BUS HRS: 835-8749 ~/ -"~ __ Drawn by:~ Approved by: ZAN & ASSOCIATES. ~' ~' ~erce~ Frexno Vi~alia gaker~fiel~ ' . ' I o~1 ] KRAZAN & ASSOCIATES, INC. I Construction Testing and Ins ~ection Environmental Engineering Laboratory Soils Testing Monitoring Wells I ~EMERGENCY RESPONSE PLAN & PROCEDURES I 1. Prevention: This station incorporates several features which offer a reasonable level of protection against a hazardous material release or spill. Features such as: emergency shut-offs, vapor recovery, leak detection systems, and approved tanks and containers help to prevent or minimize releases. Regular testing and certification of tanks, product lines, and dispensers as well as inventory records are used to verify the integrity of the fuel storage and delivery systems. 2. Reporting and Notification: In the event of a spill or release of a hazardous material, regardless of size, the event will be reported immediately to the station's designated emergency response coordinator. The coordinator will determine if the spill or release is reportable to the appropriate emergency response agencies. Threatened releases will also be reported if it is determined that a significant threat to individual safety, property or 'the environment is present. If a release is determined to be reportable, this person will immediately contact the emergency response agencies. The agencies and their telephone numbers are: I I I I 911 for 326£3979 for (800) 852-7550 for Police, Fire Department & Medical City of Bakersfield Fire Department Hazardous Materials Control Unit California Office of Emergency Service, warning center, or (916) #27-#341 Main Office: Fresno/Clovis * 3860 N. Winery · Fresno, California 93726 * (209) 291-7337 Bakersfield (805) 393-2343 [] Visalia (209) 625-8251 [] Merced (209) 383-3993 The immediate reporting shall include, as a minimum: 1. the exact location of the release or threatened release 2. the name of the person reporting the release 3. the hazardous materials involved in the release 4. an estimate of the quantity of hazardous material involved; and 5. :if known, the potential hazards presented by the hazardous material involved in the release. 3. Mitigation: If the spill, release or threatened release is determined to be minor, and therefore non-reportable, service station employees will immediately commence clean-up and containment of the spill or release, and carry out all necessary action to mitiga.te the release in accordance with standard service station mop-up procedure. These procedures include but are not limited to use of an appropriate absorbant and/or cleaner on spills of gasoline, oils, solvents, etc. Coincident with reporting, employees with emergency response training will take whatever measures are appropriate to assist the emergency response agency and offer the benefit of their knowledge of the station and its contents. Evacuation= Should it become necessary to evacuate the station, the order will be given verbally to evacuate to off-site location indicated on site diagram. 5. Medical Assistance: All employees in need of medical assistance should be transported to Mercy Hospital or Bakersfield Memorial Hospital. If the iniury involves exposure to a hazardous material, a copy of the appropriate Material Safety Data Sheet (MSDS) shall accompany the effected person to the hospital. 6. Additional Information: Telephone numbers for Emergency Response agencies and applicable MSDS's are located in the cashier's station. IKRAZAN iConstruction Testing and Inspection I & ASSOCIA'TES, IN C. Environmental Engineering _ Laboratory Soils Testing ~-~ ~ Monitoring Wells I I I I I I I I I I I I I :1 I I HAZARDOUS MATERIAL TRAINING FOR EMPLOYEES l) All employees will be trained in the contents of the Business Plan, Emergency Response Plan and Procedures (ERP&P), and Material Safety Data Sheets (MSDS). 2) All training will be documented by employee's signature on a training session sign up sheet. This record of training will be maintained by Station Manager. 3) New employees will be trained on Hazardous Materials Emergency Response ProcedUres prior to working with hazardous substances. 4) Employees who handle 'hazardous materials will be trained in the safe handling of hazardous material, and appropriate emergency response actions. 5) Employees will receive training on the location and proper use of on-site emergency response equipment. 6) Personnel responsible for incident reporting will receive special training with regard to the reporting of releases or threatened xeleases of hazardous materials as described in the ERP&P. 7) Refresher training wiii be done on an annual basis and will encompass all aspects of the Business Plan, ERP&P, MSDS, and all facets of' training listed above. Main Office: Fresno/Clovis · 3860 N. Winery · Fresno, California 93726 · (209) 291-7337 Bakersfield (805) 393-2343 ~-~ Visalia (209) 625-8251 L~ Merced (209) 383-3993 I I I I i I I I I I I i i I I I I i APPENDICES ,I I I I I I I I I I I I I I I I I I BUSINESS PLAN REQUIREMENTS SHELL OIL SERVICE STATIONS (City ,of Bakersfield Fire Jurisdiction) Service station businesses are required by law to provide hazardous material information (Business Plans) to local health and safety agencies. Following is a brief outline of City of Bakersfield Fire Department requirements. .The Complete business Plan Includes the Following Forms · Hazardous Materials Business Plan (Forms 2A and 3A) · Hazardous Materials Inventory (Form 4A-1) · Site Map and Facility Diagram (Form 5) Hazardous Materials to be Registered Include: · Gasoline, solvents, and waste oil, in quantities at or above 55 gallons Business Requirements - Initial Compliance · File Plan within 30 days of notification from City of Bakersfield Fire Dept. - File one copy with Fire Department - Fees: Sliding scale, billed after submittal · Copy of Plan to be kept at business · Copy of Material Safety and Data Sheet to be kept at business · Conduct and document Employee Safety Training -New employee hazardous material handling -New employee emergency response training -Annual refresher Business requirements - Continued Compliance · Bi-annual Business Plan review · Annual Hazardous Material Inventory Form update · 30-day notification of major changes in business activity - 100% increase in volume of regulated material - Storing a new regulated material - Change of business name, address, ownership or emergency contact person, or business closure - Other business operation changes Release Reporting Procedures · Must report significant, releases immediately to - City of Bakersfield Fire Department - California Office of Emergency Services 800-852-7550 - Local fire department · Must provide access for emergency response personnd Please Note: This business plan requirement summary was derived from City of Bakersfield Fire Department Guidelines and business plan forms distributed June, 1988 and is not meant as a substitute for these guidelines. For more detailed information, please refer to the specified guidelines, and forms. [KRAZAN ! 1 & ASSOCIATES, IN C. Construction Testing and Inspection Environmental Engineering Laboratory Soils Testing Monitoring Wells I I I I I I I I I I I I I I I I INTRODUCTION In 1985, the California Legislature enacted Assembly Bill 2185, the Hazardous Materials Release Response Plans and Inventory Law. It became effective immediately when Governor Deukmejian signed the bill on September 28, 1985. In 3anuary of 1986, the California Office of Emergency Services (OES) issued emergency regulations that, in conjunction with AB 2185, requires handlers of hazardous materials to report releases or threatened releases to the local administrative agency and the OES. Provisions of AB 2185 require every county to designate an administrative agency to implement a hazardous materials program. In some counties, certain cities have assumed authority for their own programs. BUSINESS PLANS In. addition to the reporting of a release or threatened release of a hazardous material, businesses that handle hazardous materials are required to submit a business plan. The business plan consists of: 1) Specific details of the business, including ownership, address,' description of business, and 2#-hour emergency contact information for the business. 2) An inventory of the hazardous materials on site. 3) A site plan of the business 0) Emergency response procedures in the event of a release or ~threatened release of a hazardous material Main Office: Fresno/Clovis * 3860 N. Winery · Fresno, California 93726 · (209) 291-7337 Bakersfield (805) 393-2343 ~'~ Visalia (209) 625-8251 [] Merced (209) 383-3993 I I I I I I I I I I I I I I I I I I 5) Procedures for immediate notification of releases to the administrative agency and OES 6) Procedures for the .mitigation, minimization, prevention, and abatement bfa hazard resulting from a release 7) Evacuation plans and procedures for the business site $) Training for employees who handle hazardous materials to include the safe handling of such materials and Pr.0Per emergency response procedures in the event of a release or threatened release Who must file Any business which handles a quantity of a hazardous material at any one time during the reporting year equal to at least a total weight of 500 pounds or a total volume of 55 gallons, or 200 cubic feeet of a compressed gas at standard temperature and pressure (STP). HAZARDOUS MATERIALS According to the definition given in AB 2185, "'Hazardous material' means any material that, because of its quantity, concentration, or physical or chemical characteristics, poses a significant present or potential hazard to human health and safety or to the environment if released into the workplace or the environment..." EMPLOYEE TRAINING Businesses that handle hazardous materials, and are not exempt from filing a Business Plan, must provide and document employee training in safety prodecures in handling hazardous materials and in the event of a release or threatened release of a hazardous material. Training should be undertaken a soon as p. ossible for existing employees and before any new employees handle -any hazardous material. Employee training must be documented and signed by the employee. This documentation should be maintained by the station manager and should be made available in the event the administering agency conducts an inspection. (2) I I I I I Training must_include, but need not be limited to: 1. Methods of safe handling of hazardous materials. Several sections of the Material Safety Data Sheets (MSDS) pertain to the .safe handling of hazardous materials. It is recommended that the employee reads a representative sample of MSDS's (i.e., those corresponding to the products on site). The appropriate OSHA Hazard Communication Program also will satisfy training requirements of the' business plan. 2. Procedures for coordination with local emergency agencies. The station manager or a designated emergency response coordinator (ERC) should be on duty during all business hours. If it is likely that only one person is on duty at any time, that person should be a designated ERC and should undergo the appropriate train!ng. It is the responsibility of the ERC to determine if the release or threatened release is reportable. Please note that, according to California Administrative Code, Title 19, Section 2703: "Immediate reporting shall not be required if there is reasonable belief that the release or threatened release poses. no significant present or potential hazard to human health and safety, property, or the environment." This definition of a reportable release is fairly broad and 'the ERC should exercise caution in his/her determination as to whether a release is reportable. 3. Use of on-site emergency response equipment and supplies.. If, in the event there is a release of a hazardous material, and the ERC has determined the release to be minor and therefore does not warrant reporting, the ERC will direct employees to commence cleanup and containment. Proper equipment and supplies for this action are outlined in the correct MSDS. Emergency equipment and supplies for a gasoline station include, but are not limited to: fire extinguishers, absorbants, neutralizers, sand, and underground tank leak detection monitors. Also included should be personnel protective and safety (3) I I I I I I I, I I I I I I I I I I I I equipment such as gloves, safety glasses, face shield, and first aid kits/first'ai'd station. 4. The business Emergency Response Plan and Procedures All employees should be familiar with the contel,ts of the .Business Plan. The employee should read and understand the Emergency Response Plan and Procedures, MSDS, and all other aspects of the Business Plan. (4) [K R A Z'A N ! I & ASSOCIATES , IN C. Construction Testing and Inspection Geotechnical Investigations Environmental Engineering Laboratory Soils Testing Monitoring Wells I I I MATERIAL SAFETY DATA SHEETS (MSDS) Material Safet.y Data Sheets (MSDS) are a valuable tool in hazardous material handling. A considerable amount of information is contained in the MSDS. Of particular importance to the service station employee are: Section III Section V Section VIII Section X Section XI Section XII Health Information Emergency & First Aid Procedure Fire & Explosion. Hazard Employee Protection Environmental Protection Special Precautions It is recommen'ded that all employees who handle hazardous materials (e.g., gasoline, oil, waste oil) become familiar with the Business Plan, Emergency Response Plan & Procedures, and MSDS. A copy of these items should be placed ia a conspicuous location, accompanied by the names and telephone numbers of the appropriate emergency response agencies. Main Office: Fresno/Clovis · 3860 N. Winery · Fresno, California 93726 ° (209) 291-7337 Bakersfield (805) 393-2343 (~ Visalia (209) 625-8251 [] Merced (209) 383-3993 Do ~ereby ce~t ~ ~-- ' _~? that. I have revie~cea the ~H/~¥, 1;6 1989 'HAZi MAT. DIV. attached :Hazardous Materials business plan - (name of business). and that. it along ~'ith the attached or corrections constitute.a complete and correct ' ?'''{''.," Business Plan for my facility. sl~nazur.e da%e. BUSINESS NAME CALl OAK SHELt. LOCATION 1 ~30 OAK ST ID Z 15-0~-¢Y~1 z8.q HIGH HAZARD RATING 1. OVERVIEW JURIS MAP PAGE 10Z LAST CHANGE ;1/14/88' BY VRL Z1S-003 JURIS BAKERSFIELD STATION 03 GRID 3GA FACILITY UNITS I HAZARD RATING Z RESPONSE SUMMARY ZA SEC MOP UP MINOR OIL ANO GAS SPILLS EMERGENCY CONTACTS RICK HOWARO - JIMMY KENNEOY- 83~-~SOZ OR UTILITY SHUTOFFS ~) GAS - NONE B) ELECTRICAL - I/S C~SH~ERS BOOTH NEWALL C) WMTER - ? D~ SPECIAL - NONE E) LOCK BOX - NO ?. NOTIFICATION / PUSLI~C EVACUATION LAST CHANOE / / BY < NO INFORMATION RECORDED FOR THIS SECTION > PAGE I 12/22/88 I?:ZG MATERIAL SAFETY DATA SYSTEMS, INC. <805) 648-8800 BUSINESS NAME cALII OAK' SHELL LOCATION 1130 OAK ST ~. HAZ MAT TRAINING' SUMMARY- ID _hR Z 15-000-001289' HIGH HAZARD RATING < NO INFORMATION RECORDED FOR THIS SECTION ¢, r,,,, ""[' 0 LOCAL EMERGENCY MEDICAL ASSISTANCE HALL AMBULANCE MERCY HOSPITAL, LAST CHANGE SEC 5) 11/14/88 BY UAL ZZlS TRUXTUN AVE, PAGE 2 MRTERIRL SAFETY DRTA SYSTEMS, INC. (805) 648-6800 17:ZG BUSINESS NAME C R O~K. SHELL I_OCAT!ON 1 t ~.~z')' OAK ST FACIt_ITY UNIT' 81 A, ~OVERALL HAZARDOUS MATERIALS iNVENTORY ION R' 'HIGH HAZARD RATING 'Z .' LAST CHANGE tl/14/88 8Y VAL '3' TYPE NAME LOCATION PURE REGULAR G~SOLINE -S 'OF CASHIERS' BOOTH .ID PERCENT COMPONENTS 118~,80 188.8 GASOLINE PURE GASOLINE RU S OF CASHIERS BOOTH ID PERCENT COMPONENTS 118Z~00 100.0 GASOLINE CONTAINMENT UNDERGROUND TANKs UNDERGROUND TANKS- PURE :GASOLINE SU S OF CASHIERS BOOTH ID PERCENT COMPONENTS 118Z.<~)0 80.0 GASOLINE UNDERGROUND TANKS B. FIRE PROTECTION ! WATER SUPPLIES SEC 4) 3A SEC 5) HAVE EXTINGUISHER INSIDE 8USINESS MAX AMT UNIT HAZARD USE 18808 GAL HIGH FUEL HAZARD LIST HIGH 1~8 GAL. HIGH FUEL. · HAZARD LI'ST HIGH . IO~8'GAL HIGH ' .' FUEL -' FIRE HYDRANT - CORNER OF LOT NEXT O00R PAGE MATERIAL SAFETY DATA 'SYSTEMS,· INC. (805) 6¢8-6888 12/22/88 1'7:Z6 BUSINESS NAME CflL. oRi< ,SHELL LOCATION . '~ !]0 [)AK Sl' 0. EMPLOYEE NOTIFICATION / EVRCURTION tD LAST CHANGE 2'15-OOO-<Z~lZB9 HIGH HRZflRO RATING Z 11/1~F88 BY VRL SEC Z) TURN OFF'EL. ECTRICRL CRLL RICK HOWRRD - CRLL FIRE DEPT F.LERVE' ?// · SEC P~GE 4 MI'T.IGRTION / PREVENTION / RBRTEMENT :~-' ' ':~ ': ;'""'~'"' "' .... '~"'~:~:'~'~? .... ': .... ................. ':" L~ST CHANGE · .:: . :-..~.. :-'~:~:... :-' .:, ~ -'.'-:'/'.'' ::':~-~':4:~Vq~"" '~:": 1) AUTOMATIC SHUT OFF ON ·FUEL DISPENSERS MOP US SMRLL SPILLS~ ':-' . (805) $48-G80~ MRTERIRL SRFETY DRTR.SYSTEMS, INC. o.f BA KER SFI£LD CITY · · N O N -- T R AD E S E C R E' T S. , p,9, f,i ,.of ~ . LOCATION: // "~ ~)lJ~ t~.~,~-- ADDRESS: :,STANDARD IND. CLASS CODE CITY, ZIP: /'~.~/;~/~/'~.,~i~..-. "~,~c~/ CITY, ZIP: ~9-~e.~ _~,e'r~ ~'~ ~._~. ~~ DUN. 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"~,*"' ~...:'" BAKERSFIELD CITY FIRE DEPARTMENT 2130 "6" STREET BAKERSFIELD, CA 93301 (805) 326-3979 IUSINESS NAME OFFICIAL USE ONLY ID~ HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE FORM 2A INSTRUCTIONS:, 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. .: SECTION 1: BUSINESS IDENTIFICATION DATA in case of an eaer~ency involvin5 the release or threatened release off a .... : hazardous aaterial, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emersency Services as required by law. ' ...... -' E~PLOYEES TO NOTIFY IN CASE OF E~ERGE~CY: NAME AND TITLE / / DURING BUS. HRS. AFTER BUS. BRS. Ph~: ~ ~W2 ~ ~'~- SECT~0N 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: B. ELECTRICAL: C. WATER: D. SPECIAL: E. LOCK BOX: YES /~ IF YES, LOCATION: IF YES. DOES IT CONTAIN SITE PLANS? FLOOR PLANS? YES /,~ MSDSS? YES~,~ YES KEYS? YES - 2A - SECTION 4: PRIVATE RESPONSE TERM FOR BUSINESS AS A WHOLE LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YO5~ BUSINESS AS A WHOLE SECTION 6: EMPLO%~EE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING .IN THE FOLLOWING AREAS D. EMERGENCY EVACUATION PROCEDURES: ................. .,~'/~' N0/~ N0 E. DO YOU~ MAINTAIN EMPLOYEE TRAINING RECORDS: ....... SECTION 7: HAZARDOUS ,WATERIAL CIRCLE nS ' NO - NON~ DOES YOUR BUSINESS HANDLE HAZARDOUS ~TERIAL IN QUANTITIES LESS THAN 500 POUND~ 0F~ SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A cOMPRESSED GAS: ...... YaS I ,,'z~-~:~___ ____ ~ , certify that the above information is accurate. I understa~nd that this information will. be used to fulfill my firm's obliM~tions under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 28800 Et Al.) and that inaccurate information constitutes perjury. 'SIGNATURE~ -~ 2B - BAKERSFIELD CITY FiRE DEPART.~IE.XT ~ 1 ~0 STREET BAKERSFIELD, CA · 93301 BUS IN'ESS ......... USE ON'L\' BUS I NESS PLAN SINGLE FACILITY UNIT FORM SA INSTRUCTIONS I. To avoid further action, this form must be re'turned by: 2. TYPE/PRINT 5'OUR A~YSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY U.YIT LISTED EEi. OW 9. Be as BRiEf' and CONCIS£ as possible.' FACILITY UNIT-~ FACILITY UNIT NAME: SECTION 1: MITIGATION, PREVENTION~ ABATEMENT PROCEDURES SECTION 2: NOTIFiCATiON ANq] ~'~"'~'~'=~.~=, ~., P~0CEDL-RES AT THIS L~."iT O.YLY - SA - SECTION S: HAZARDOI;S .MATERIALS FOR THIS I~'iT ONLY A. Does this Facill~ Unit contain Haznrdous Hateria!s .... X0 If YES, see B. If N0, continue with SECTION 4'. B. Are any of the hazardous materials a bona fide Trade Secret YES ~0 If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form =4A-l) tf Yes, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (yellow 'form =4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-Z. ~ECT!0N 4: PRIVATE FIRE PROTECTION SECTION ~: LOCATION OF W~TER SL~PLY FOR USE BY EMERGENCY RESPONDERS SECTION 8: LOCATION OF L~ILITY SHL~-OFFS AT TMIS %%'IT 0STY. oAo, P~OP.,N ~': A. 5:AT. B. ELECTRICAL: D. SPECIAL: E. LOCK BOX: YES .' iF YES, LOC,.TIO.,. tF YES, S~TE PLA~CS? FLOOR PLA57S? YES J,~ YES MSDSs? KEYS? I.D. # BAKERSFIELD CITY FIRE DEPARTMENT FORM4A-I NON--TRADE SECRETS }IAZARDOUS MATERI ALS I NVENTORY BUSINESS NAME: OWNER NAME: ADDRESS: ADDRESS: CITY, ZIP: CITY,ZIP: " PHONE #: PHONE #: OFFICIAL USE CFIRS COD'~ ONLY FACILITY Page FACILITY UNIT #: UNIT NAME: 1 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS · BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE ,.. . .... . ~NAME: TITLE: ~t~ S :GNATURE: ~' ' ~ . _ ~~ ~ ~ DATE: -EMERGENCY CONTACT: ~,c~, ~ ,~,~,~ TITI. E: ~ ~ PHONE , BUS HOURS: ' ' ' AFTER BUS HRS: ~--q------'~--~ ~>E~EROESCY CONTACT: ~ ~ ~~%~ . T~TLE: ~6[ PHONE m BUS HOUR'S:~%~-e%-c? 7m~-~ · PRINCIPAL BUSINESS ACTIVITY: ~~l%fi~ . ~~ AFTER BUS HRS: MAY 18, 1988 Dear Mr. Livengood · NOTICE OF VIOLATION AND SCHEDULE-FOR COMPLIANCE IN THE INSPECTION OF YOUR BUSINESS ;CAL OAK SHELL STATION LOCATED AT 1130 OAK STREET BAKERSFIELD, CA 93304~ ON.MAY 18TH THE ·FOLLOWING HAZARDOUS MATERIALS REGULATION VIOLATIONS WERE IDENTIFIED.: 1) 'No HAZARDOUS~MATERIALS BUSINESS PLAN ON FILE · ~ '{.~IOLATION OF CH. 6.95 CA!~IFORN~A HEALTH AND SAFETY CODE Sect.25503.5 (a) Any business, except as'provided in subdivision (b), whiDh'handles a hazardous material,or mixture containing a hazardous material which has a quantity at any one time.during the reporting.year"equal .to~ or ' greater than,, a~ total weight of 'SQ0 pounds,,:or a total volume of.55.gallons, or 200 cubiC~, feet~-at standard temperature and,pressure for a compressed gas, shall. ' establish.and implement a busineSs~plan for~.emergency responSe,to a release or threatened rel'~ase.of a hazardOus, material in accordance ~ith the standards in the regulations adopted pursuant to Section 25503 NO EMERGENCY pRocEDURES FOR A~HAZARDous MATERIALS INCIDENT ~,.. VIOLATION OF cALIFORNIAi~HEALTH AND SAFETY CODE CHAPTER'6..95, 25504(B) ' . Business Plans sha~l include ~11 .Of the .following: Emergency-response plans and procedures:in the'event of a reportable of threatened release of a hazardous material, including, but not !imited~ to., all~.of the" following: (1) Immediate notification to the administering agency and to appropriate local emergency rescue persOnnel and the office. (2) Procedures 'for the .mitigation"of. a release~' threatened release to~minimize' any ~Qtential harm or damage to persons, Dr°Derty, or the environment. (3) Evacuation plans and procedures, including o. immediate notice, for the business s. ite. 3) NO MSDS SHEETS AVAILABLE FOR THE HAZARDOUS MATERI~LS"THAT ARE HANDLED VIOLATION OF OSHA 1910.1200 ~.(g)The employer shall maintain Cooies of the required material safety data sheets' for each hazardous chemical in the workplace, an~ shall ensure that they- are readily accessible during each work shift to ~moloyees when they are in their work area(s) ' (h)(1) INFORMATION. EmD!oYeeS shall be informed of: (i)The'requirements of this section (ii)Any operations in their work area where hazardous chemicals are present; and, (iii)The location and availability °f: the written hazard communication program, including the required list(s) of'haZardous chemicals, and material safety data sheets required by-this section. ?4) iNO HAZARDOUS MATERIALS TRAINING'. ~'~ ~ ..... ~ '"-~'~" ' ~:~"~'~"~ 'VIOLATION OF OSHA 1910.1200'(H) (2)Training Employee,training shall include at - least: (i)Methods and observations that may be Used · to detect the presence or-:release of 'a hazardous chemical in the work area (such as monitoring conducted by the employer, continuous monitoring devices, visual appearance or'odor of hazardous chemicals when being released, etc.); (ii)The physical and health, hazards' of the chemicals in the work area; (iii)The measures employees can take.to protect themselves.from these hazards, including 'specific procedures the' employer has implemented to protect employees from exposure to ha'zardous ~ chemicals, such as appropriate work practices, · emergency procedures, and~persona! protective equipment to be used; and~ (iv)The details of the hazard communication program developed by the employer, including an explanation.of the labeling system and the material.' safety data sheet, and how employees can obtain and use the appropriate hazard information. The above violations must be corrected bY.~13ll~ The department will schedule a re-inspection of you? facility to verify compliance. If you have any questions re~arding this notice, please contact Ralph Huey at 326-39?9. · Sincerely, // . · · .~ ..-~ [~ ~alph E.Huey Hazardous Materials Coordinator F~en Ap~oved OMfl Y~o. 2050-00?2 Facility Identification *Owner/Operator Name Tier Two HAZARDOUS Emergency Contact' CHEMICAl. INVENTORY , 24 Hr. ,, O.L~USE Jo.,..~,~ J ~ ~7tY,, ~ZO -/~/y ~,.,.~ ,~oC~y-~q , In~ >arrant: Read all instructions be/ore [/arm neportlng Period ¢,om January t to Physical Inventory Storage Codes and Locations. Chemlcal Description and Health Ma,. ^vg. No. of (Non_Confidential) Hazards. Dally, Dally Daye . Amount Amount On-site Icheek etl tl~at amir) (code) (code) (days) Star, Jo Code Storaae..~cation~ '. :. Trl~ Chem. N~e ~[ ~ ~~ ~ ofS~Pteelu, eRelelle c~sl ) 1.1 I I'1~~ ~.,.."'"'~ _--'"' Chem. N~I __ of P~ellUtl Imm~li te (ICUlI: OIIly~ that o~ly: ~re M.. Sood L;~u~d Certification (R~od and si~ after com~l~tin~ oil j~c~ions) Optional Attachmentl (Check One)' ~ ' CERTIFIED'MAiL Date: REQUESTED Re: ·SERVICE STATION 'PREMISES LOCATED AT: ~.Address' City/S~ate Mr. .lliam Medigovich " State Emergency Response Committee MeadoWview Sacramento, CA 95832· Dear Mr. Medigovich: The SARA Title III Section 311 regulation requires· that all locations submit a copy of the MSDS (Material Safety Data Sheets) or a categorized listingof ·the hazardous substance, to the State'EmergenCy Response Committee.:(SERC), Local Emergency Response COmmittee {LERC), and local fire department by September 24, 1988 .... AttaChed pleas~ find Attachment I, MSDS'categorized listing for products found at·this Shell Station, Attachmen~ II, MSDS sheets for Shell Products found at this Shell Station.~ ~. ~ .... i have been advised that the State Emergency Response Committee Staff has·made arrangements whereby they will.distribute the required i·nformation to .th'e'appropriate Local Emergency RespOnse Committee. Therefore, I am~'attaching two copies of the required .information; one'for your file .~.an, one.for .distribution to. the Local~ Emergency Response Committee. PRODUCT CHEMiC~ PETROL .'- .~ ~' :.' CHEMICAL FAMILY II~ 'HYDROCARB'ON SHELL ~ 02200 CODE SECTION ]Z-A. . . . PIQJXIC'r/Z~EDIE~.,...,, .... ,.., ..... ; .......... . ................. .~- I~' ' CI~I~SZTION .. 'C&$ ~ER PERC[~ , ..;, ...................................... ,; ..... , ........... ,-:, ......... ~. ...... --,---, ........... ": ·MIXTURE P SHELL REGULAR GASOLINE I ALKANES. CYCLDALKANES. ALKENES AMD AROMATIC-HYDROCARBONS 2 TOLUENE 3 XYL'ENE . . 4 BENZENE ·· · 5 TETRAETHYL AH TETRAMETHYL LEAD .- -mXTUnE. OF ~8-oo-~ AH ?B-T4-,. ,. · ' II1 XTURE' BALANCE 1C~-88-3 O-25 .o 1330-20-? 0;25.0 71-43-2 . O.5-2.5 ' MIXTURE: ' ' <0..1 ~/GAL .c~=o..-. , ,=,m ~=c,- O,T,.~ .... ; ..... ...,..,..., ..... ; ..... ,..; ....... ; .... . '-' ............. ' ................. "";~.i';~iil;.',.=o - .,~E z--~T:.. ~o P )5 ~/KG (RAT) ' ' )~ MI/KG (RABBIT) bE MG/L/4NR (RAT) ~' ~ALTN EFFECTS ~TED Ilk~ ARE 'IISTI~ lllH IE~IIEE~s ~ll l~ ~ MZ&RD ~ICATI.ON MILMIED' MID IEPEITED LlaO]O CGNTAC: ~ CAUSE·DEFATTING AM).iXIYZNG OF'. 'THE SKIN. RESULTING-IN SKIN. RESULT IN &$PlR&TION PNEUIIONITIS ' ' ~' :"' 'EARLY.TO MODERATE ~NS (CENTRAL NERVOUS SYSTEM) DEPRESSION '~Y BE. %RR]]~A~ ....... ,eM ~&~ACHE, g~&~La' - .... ~,~ '~ED BR~A~n&~ ...... EV;DE~ED B ~XTIS ~V BE E ~Y Ii EVZDE~ED BY.~ES ZN U '.,v n~ g ASPZRATI~ ....... U V OG~R. KZ~Y OA~GE. -. -~ .... ~A~GE ~Y BE .EVXDE~ED &y LOSS'OF APPETITE. v ...... .- . SIDE. RI~T By EXPOSURE TO THIS PRODUcT. ' :'~.EYE SKZN.'A~ RE~ ....... onu oor~]~ DISORDERS ~Y BE A~AVATED BY EXPOSURE ~VAT~ ~DI~ ~%T%~ P%RATO~Y D]SORDEOS MAy RE A~AVATED IMPAIRED LIVER A~ K%D~-- F_.._~I ~ : .T~Z~" pm~. ~ .O~R ~ EFFE~ THAT C~]C ]~ALATZ~ EX.SURE TO AN ~C[kDED mTOi ~SOLINE'. ~ZCH VAS . .. THE STUDIES lT. HAsBEEN REPORTED F~CCY VAPORIZED. ~S pROdUCED KIDNEY A~ LIVER CANCERS ]N S~E LABORATORY RODENTS V[R[SPONSORED BY THE AMERICAN pETROLEUM ZNST2TUTE.. THE--AP~ TEST .~TERZ&L USED VAS 8CEDED TO . 'REPRESE~ A TYP2CAL UNLEADED ~ToR ~SOL]NE.. SHELL'~E&DED'~SOLZNE ~S ~T BEEN EV&LUATED ZN THIS TYPE OF ANZ~L TEST. _ ~ . . p SECTION V - ........................ , ....... - .................. ' · · EYE GGNTA~T : 'FOR. IS .Z~TES ~ILE' ~LDI~ EYELIDS OPEN. GET MEDICAL ATTE~Z~. F~USH WITH WATEU · . FLUSH VZTH rATER ~LE ~[KVZ~ CDNTANZ~TED CLOTHZ~ A~ S~ES' FOLL~ BY VASHZ~ VZTH SOAP ' rATER.. DO ~T REUSE CLOTHZ~ OR ~ES ~TZL CLEANED. IF %RRZTAT%~ PERSISTS. GET 'MEDICAL ATTE~-Z~- %~T%~. ' ' A~ p~VXDE OXYGEN ZF BREATflX~ 2S DIFFZ~LT. GIVE ART%FZCzAL 'or--ur v~CT%'M TO FRESH AIR .~S~A~' ZF ~T BREATHZ~. GET MEDICAL A~E~Zm. ' Z~l~ %F ~IT%~ ~C~S 'S~A~SLY KEEP HEAD BELOV HIPS. T0 PREVE~ ' DO ~T Z~E ASPZRATZ~ OF LZWZO Z~O T~ L~S. GET MEDICAL lNd __. .,-' ~ ~mlTlNg HA'S NOT Q~CURRED~ EMESIS S~CUL3} BE - F ~RE T~N ~.o ~ ~l KG ~S ' v CTIM'S ~AO I~ HIPS_~ ~ ..... e~flm~' K~SIS, ~STRIC z~&u -- ........ G REFLEX, AS ~SS OF ~ E ~ZDERED. SY~T~ ~ T~E ~ B · LAVAM'.~Z~ A ~FFED EGTRA~AL ........ ,,-, ........... .SHELL REGULAR GASOLII~ I~DS 61.1E0-3 PAGE 3 INPIAI. ATION STUDIES ON GASOLINE' vApORs NAVE'CAUSED CENTRAL'NERVOUS' SYSTEM EFFECTS Iu DOGS AT Uf~LEADED GASOLINE b/AS EVAL:uATED FOR GENETIC ACTIVITY. IN A'SSA'¥S USING MICROBIAL CELLS.' CULTU~ED · MAMIdA~IAN CELLS' AND RAT.BONE MARROW CELLS. THE RESUL'TS'WERE ALL NEGATIVE UNLEADED'GASOLINE b/AS' ~coNSIDERED NoN;MuTAGENIC UI'4:)ER THESE CONDITIONS. .*~ ' :_':-. ** ',~ . *** 'NO.REPORTS OF '[EAO TOxXCITV ~VE BEEN AsSocIATED VITH~'TNIS pRoDucT. HO~E~ER. ABUSE 'SKIN. CONTACT... DR.'ExcEssZVELY H]GH CONCENTRATIONS OF /GASOLINE VAPOR MAY RESULT IN ABSORPTION OF. LEAD' INTO THE POTENTIALLY COULD,RESULT IN LEAD TOXICITY. SUFFICIENT LEAD ABSORPTION ']S 'BLOODSTREAM.TO. CAUSE DAM~GEVHICH?o BONE MARROW (ANEMIA). NERVOUS SYSTEM. (BRAIN AND PERIPHERAL NERVE*). K~'DNE¥ ;TOX].CITY'OF BOb/EL (COLIC). ' ''' /: ' , ~HE NANDLING PROCEDURES AND' SAFETY PRECAUTIONS IN THIS MSDS SNOULD BE FOLLOWED TO MINIMIZE EMPLoyEE EXPOSURE · .. . : .~ SE~IONVII' ' PHYSIC~ DATA· · · .................. , .... ? .................... ,.~ ....... '~ .... i...., ....... ~ ..... ~ ...................... . BOILING POINT: ICX:)-AIS' APPROx. SPECIFIC G~qAvITY:' 0'.?2-0.76 (DEG F) (flIO-l) MELTING POINT: NOT AVAILABLE SOLUBILITY: NEGLIGIBLE (DEG F)' .,. : '(IN b/ATER! EVAPORATION RATE (N,BUTYL ACETATE · I): NOT AvAzLABLE AppEARANcE.cAMO ODOR: BRONZE COLOR: CLEAR AND BR*ZGHT LIQUID. ,VAPOR pRESSURE:'?-ld;S PS! (Midi PiG) (REID) VAPOR DENS2T~i, 3.S .' · (AIR-l) ''~ VOLATILE BY VOL- 100 (e. 41~ DEG.' F.) NYOROCARBONOOOR... .... ' .... ' ...... "".:"'T" ....... , .,...,,.....,,.,---,., .......... ,: ............. -,--,---:-,---. ..... ,.., ......... , .................. ,--. FLASH POINT MI) ILrTHDO: " FLAMMLE LZNZTS /1LVOLLME iN AIR' -40 DEG F TAG CLOSED TESTER EXTZNIJZ S)(ZNG IIEOZA . USE rATER FOG. FOAM. DRY CHEMICAL 'OR C02. Aid:) CAN BE REIONITED ON. SURFACE OF WATER. LOVER: ' 1.'3 UPPER: 7.6 DO NOT USE &.DIRECT STREAM OF WATER. .' PRODUCT WILL-·FLOAT SPECIAL. FIRE FIGHTZI~ PROC:EDUIES Ale·PI~tLITIONS DANGER. EXTREMELY FLAMIdABLE., CLEAR FIRE AREA OF UNPROTECTED PERSONNEL &IA) ISOLATE. 00 NOT.ENTER CONFINED FIRE SPACE WITHOUT*FULL BLINKER GEAR ZNCLIA)ING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS WITH WATER. UliJSUAL FIRE Mi).EXPLOSION~ VAPORS ARE HEAVIER TNAN AIR-ACCI,IIlULATIm IN kO'd AREAS 'AND TRAVELING AL~ TIdE GI~O~I,4) AWAY FROId THE HAIA)LING SITE. DO NOT VELD. HEAT OR DRILL'ON OR NEAR CONTAINER,. HDWEV~ER. IF EMERGENCY SITUATIONS REQUIRE DRILLING. ONLY TRAINED EMERGENCY PERSONNEL SHOULD DRILL '.:.S~*az~i?v: ST4~LE mZ4amOUS POLVmRIZ~ON: -CII)~TZ~I6 ielATI~LIM'S TO AVOID: AVOID PIEAT. SPARKS.'OPEN FLAIES"MIDSTIONGOXIDIZINOAmlrNT$i GARION NONOXZDE AND OTHE~UNIDRNTIFIEO DRGINIC:.gOmpOUNOS-CAN PIEVENT VAPOI ACCUMULATION. BE FOIBIED UPON COIBUSTION. -(SEE SEC~Z~ x). PER ~9. CFR tB~O.S~' USE EITHER AN AT~S~ERE-~PPLY]~ IESPZRAT~ ~ ~' A2n-P~ZFYZ~ B[SPZRAT~ FOR ~N]C VA~BS. FOR SERVZCE STATZ~ pERS~EL P~TECT]~, SEE .AS.RE.IRED TO MINIMIZE SKIN A~ EYE C~ACT~ YEAR ]~ERVz~S GLovES.". EYE P~TECTZ~"A~ OTHER ~Z'TI~ ~TE~ZVE ~ES .USE EXP~0S~'PROOF VENTZLAT]~ AS RE~ZRED T0 CONTROL VAPOR C~ENTRATZ~S. ~ZLL ~ LE~ ~E~ES .... ' .... AT' A'L 2~ZT]~ ~URCES ~LZK E~Z~E~ ~ST BE ~0U~ED R~ EXTREMELY FLA~BLE. E~m~N_ &__b ..... ~ ~ul ~B'ABEA A~ DENY E~RY TO ~ECEssART' ~O PREVE~ SPARK~. -"~ LARGE ~ZL~ RESPZRATOR A~ PROTECTZVE-CLOTNZK' ~T. OFF S~C~. ~EL YEAR APPROPRZATE F ' ZN ~PPRESSZ~ VAPOR ~; PERI0 · NTAZN. WATER FOG ~Y BE USE UL p RESIDUE V]TH &BSORBENT ~u~.~.~.~. ~TM UJTFG TO RE~VE TRACE RESZOUt; uJ)FuaG.~.. :.u.~ r~ATNERS; SEAL · SMALL SPILLS ..o TAKE UP lZ]n An .u~v-. ...... -,-' - .' T]~TLY FOR PROPER DISPOSAl. EPA - RESOURCE ~NSERVA~'Z~ &~ RECOVERY ACT (NORA) RE.LATInS.. ~ AS' PRIED,'. THIS ~TERZAL' ZS . 14)ED TO BE DISCARDED &S IS, 'iT IS A LIQUID IGNITABLE T & WASTE. - IF DISCARDED OR INTE ..... '~ARDA~3S WASTE NLJII~,ER %S. DC)C)I. FREE' RECOVERY A~ RECYCL%~ RE . ' WATER ACT. SPILLS [~ ~'S~'~ST R, REPORTED TO THE ~TZ~L' RESP~SE CE~ER. __ T SURFACE VAT.ERS T~T ~AuSE - -' .' YENS E~ERZ~ ~ LE~Z~ TO 0 KEEP WT OF ~FAC[ WATERS A~ ANY WATER C~SES OR SE 1~-42d-1802 · SURFACE WATERS · '' ' ' " · AR~S. C~EN PLANES, ZNcLUOkNG PIL'OT L,XglATS, .AIA) STRONG '- ........... ''AIIIABLE AVOID H~AT: SP _ __L__ ........ "'~ &~'~mILATZON ALI~ 14AI~)LtNG OXIDIZING AGENTS. USE EXlmkQSzi~'v__m~'~a_r_'_~.~_.~.';~ ' HARMFUL, OI FATAL IF SMALL~ED. EOU%PMENT MUST BE GROUNDED TO PREVENT ~m,A~cw,mu, ..... ~ . GASOLINE BY ~{~'JTH. · * ' ' ' ' ' A CLEANZ'4 SOLVENT Oe FOe 'orr,4, ,O,-mTOe ,,u,.L_U_S_ES. ' FOR. USE A.S A ,,-TOe FUE_L_?e.v. ~O NOT USE...A.S.,._. '"''INO Oe USINO TOILET' COKTAiIIN&TED CLOTHING ltPUwt K~v~s ....... . . . , . '~' RESPZIATM IS NOT WARRANTED. ' ' .... DEPARTMENT OF TRANSPORTATION CI, J&SSIFIC&TION:' ~ D.O.T. PROPEl SNZPPZNO. N&M~: U~LINE FLJUm&BLE LIQUID -D.O..T~ %.D.-#UN 1203' GU]DE NO:. 27. ' ' PAGE ~S · ' '~ '' -" ~' ' " OTHER REI~LJLATORY (~k'TRoLS~ ' ~' · THE COMPDNENT~ OF ?HIS pRODUCT ~RE. LISTED ON 'THE EPA/TSCA. INVENTDRY OF CHEMICAL~., SUBSTANCES. 'TH~:'iNFORMATIDN coNTAINED HEREIN IS BASED ON THE-DATA AVAILABLE TO US AND, IS BELIEVED,TO BE HOVEVER. SHELL MAKES NO WARRANTY.'EXP;ESSED OR IMPLIED REG&;D2NG THE ACCURACY,OF T,ESE DATA ~SULTS TO BE 0BTA~NED FROM THE USE THERED~:. SHEL~,'ASSUMES, NO RESPONSiBiLITY FO; ;NUU;Y FROM T~E DATE. PREPAaED:0CTOBER 11. 1~85 · , ' ~ P. SEPESZ SHELL OZL CONPMIY · '.. PRDI~JCT SAFETY MiD CONP~ZKE 'P. 0.'lOX 4~20 HIXJSTON. TX .?7210 'BE SAFE READ OUR ~PROIXICT SAFETY INFORMATION ...AND PASS ZT ~ (~ LZ~ZLZTY ~ RE~ZRES ZT ) · . MATERIAL,:$AF'ETY DATA. sHE:ET PAGE 1 tSI. ELL: -713 : 473'9461 CHEMTREC: 8'00-424.9300'[. SHELL: 713-241/ 4819 ~E SA P~ODUCT' I), CHEMICAL RU 2000 (REGULAR UNLEadED GASOLINE) * .i .CHEMIC/~. FAMILY ~ HYDROCARBON.: . r.,· BHEL~ · 02100 · CODE ...':. ....... ,.' ............ '.., .......... :~ .......... ; .... ,,.-; ....................... , ....... SECTZON ZZ-A. . P,OOUCT/Z,~EDZ'.."T...~ ..... . ...... , ..... . ................... ~ ......... ............... :'. ...... . ' c,, -.,-ER ' -' ........ '"--. .... -' ...... -"': ...... '"'": ..... :"~:,'"'"'T" ...................... '"' ..... ~' "U 2(XX) ("REGULAR 'UNLEADED GASOLINE) -", .'.' '... ".. . MIXTURE 1OO . I-' &LK&NE$', .CYCL0&LKANES', .ALKENE5 AND AROMATIC HYDROCARBONS MIXTURE BALANCE ..... . lOI-IB-3 -0-25.0 2 TOLUENE. ..** -.' .. 1330-20-?~ O-IB.O :3 , XYLENE ' 71-43-= ' O.~-~.B . 4 BENZENK: - ... -. ...... , ......................... : ......... .... , ..... :..~ .... ,..:;.:...., .............. ~-,, ........... SECTI014 :ZZ-I ' AO, JTE TOXZCITY'0ATA' . '. ........ ' . .............. ..................... · ~ ..................... ,...---,o-, .... ~ ..... ,, .......... -. ' ~ I~IllAL LOIO IIOJTE llIMLATIMi LC:ID 14). ACUTE OIAL LD60 · . ...................... . ............ P >S ~II/KG (RAT) .)2 OM/KG (RABBIT). ' )S I~/L/414R (RAT) TM HEALTH EFFECTS NOTED BELO¥ ARE CONSISTENT· IIZTH IEQUZREI~ENTS IJM)ER THE OSIM HAZARD .COIIJNZCATION STAId)ARD (20 CFR 10~O.t~OO). ' ~ I&SED ON PRODUCT TESTZNG PRODUCT IS li00ERA;rELi IRRITATING TO TI, IE EYES: · · ~: '::._INIOLONGED dj4) REPEATED LIQUID C01(TACT GAN CAUSE OEFATTING AND DIYXNG OIr ~ SKIN RESULTING~... lid SKI# ~'mzs Pu0OKT my CAUSE ~R. tTA'rtoN 'TO THE NOSE, ~aOAT ifc luspxuAToitY ~ ~zs p. O0~T mY SE ,4Mm'U~ O~ ~ATAL , Su[LOdO.' Z.MsTzON Of NOOUC, mY .tSU~T Z. V~.ZTZNG; &SPIIATION (BIEATHIm) Of VOMITUS INTO THE LLIIGS IIJS? IE :&VQIDEO AS EVIN' SIMLL·QUANTTTZES lily RESULT IM ASPZbTZON'' PefLmoNZTZS. O GASOLZNE) ~Z~E~ED BY GZ~ZNESS.~ HEADACHE. DiZZiNESS A~ ~USEA: ZN EXTREIE ~JS[S. X~2OUSNESS 'A~ E~ED BY COUSin. ~JlORED IREATHZ~ A~ CYA~S~Sr T ~ PNE~ZTZS ~Y~BE EVZD ' E~ED BY ~ES ZN'~RZNE y OCCUR. ASPZR& Z ' KZ~EY DA~GE .~Y BE EVZD _ MA -. CASES DEATH ~Y KCUR. . ~' GE ~Y BE EVZDE~ED ZSfl SKIN); ~N SEVERE. F~ ~LUZD RETE~Z~). ~ LXVER D~ - · (B~ p ARA~E OR ED[~ (SVELLZ~ * ' ~ &iN ZN ~ ~PEl ~EN ~ TNE DUTP~Y. U~E AP E ' Y LL~2~ ~ZN COLOR) A~ S~ETZMES ~ ~ . · ....... ~' . VA~.MDZ~ ~~ ....... *V ~,cnB"rec ~Y BE A~AVATED BY'EXPOSURE-TO THiS PR~UCT. ~ZSTZK EyE~ ~K2.~.~~:~'F~E~STZ~ DISORDERS ~Y BE A~RAVATED By.ExPoSURE TO' THIS pRaT .. OT~R G~ EFFR~S IT ~S BEEN REPORTED T~T C~ONZC .Z~ATZ~ ExPOSUR[ TO iN ~E~DEO ~TOR ~SO~ZNE. ~2CH vAS FU~Y. VAPORIZED. ~S PRODUCED KIDNEY A~ ~2VER. C~ERS IN S~E ~ABORATORY R~ENTS.. THE ST~ZES WERE SPaSORED~BY THE .AMERICAN PETRO~E~ Z~TZTUTE. THE APX TEST ~TERXAL USED WAS B~E~ED TO REPRESE~ A TYPlCA~ ~[AD[D KTOR ~SO~INE. SHE~ ~LEAOED ~1'NE ~S'~T' BEEN E.VALU&TED IN T~S TYPE 0F ANZMA~ ~E.S~; . ' - . . ... ............. ~...-'-~,~---~'-~ ........... ,--.--, .... ~,~ ............ ~ ............ ' ...... ~~ EWE LiMiTS.' ''. - · ' ............ ' SE~Z~ IV' ' ' ' ~ M T-v/~A- ,- ' TLV/STEL . ~ ~ ~L/~A ' PEL/~ZL%~ ~ ; .~ .... 6~ ..... ~..~ ....................... ..: ..... ~, .............. ~ ....... ---~, ........ ;~-;;~-,- .. ~ ,- - .. . . .- . .' ~. .. , .- . .......," ....... ~ ..... : ..:',......~ .... ~ ..... , .............. ':...~ .... -,~-; ............. , ..... ~---~~, ~ ,~ .0 ~~ ......... ,..~, ............ , ....... FLUSH ¥%T)i WATER FOR 1'S M%NUTES VH%~E' HOLDING EYELIDS 'OPEN. GET ,EDZCA~ ATTEN~%~. ' FLUSH VZTH WATER ~%LE RE~VZK CONTAMZNATED CLOTH%~ A~ S~ES. FOLLOW BY wATER. DO ~T REUSE CLOTH%~ OR S~ES ~%L. CLEANED. %F %RR%TAT%~ PERSISTS. GET MEDICAL '%~T%~ R~VE VZCT%M TO FRESH A%R A~ PROV%DE OXY~N RESP%RAT%~ %F ~T BREATH%~. GET NED%CAL A~TE~%~- . DO ~T Z~UCE ~ZTZ~ ZF V~2TZ~ ~CURS Sp~A~SLY KEEP HEAD BELOW flZPS TO PREVE~ ASP2RATZ~ OF LZ~ZD ~NTO THE L~S. MT iEDZCAL ATTE~Z~.' NOTE TO Im)ws%c%Mi ~ . ___ KG HAS BEEN %M,2fCTED AND V~li%T*%NG'HAS NOT' OCCURRED .EMES%S ~O BE · iF ~gE T~N 2.0 ML %GEED V%Tfl NED%C~_~E~S~vK~~~ ~ ~SGZ~ESS ~CUR BEFORE' ENESZS~ ~ST'RZC '. .... -~,~_~ ................................................ ~ ..... . , ~ . A c~c z~zm sTwv T~T FULLY V&~%ZED ~EADEO M~L%~ EX~SWRE P~ED ~SE~BE~TED REP[~TEO HX~ LEVEL %~LAT$m S~%ES ' ~Quc-r NME: .U 2O0O ~QULL~ ~L[&D[D MSO~XN£) · PAGE . 3' UNLEADED GASOLINE VAS EVALUATED FOR GENETIC ACTIVITY'IN ASSAYS'USING MIcRoBIAL CELLS',. CULTU~E~' MAMMALIAN CELLS AND RAT BONE MARRDU CELLS.. THE RESULTS YERE ALL NEGATIVE. UNLEADED-GASOLINE CONSIDERED NON-MuTAGENIC UNDER THESE CONDITIONS: THE HANDLING PROCEDURES AND SAFETY'PRECAUTIONS IN THiS MSDS SHOULD BE FOLLOVED TO MINIMIZE EMP_LOYEE EXPOSURE. . - . ** -' ..... ' ........ .... .... · .... .............. · ................. , ....... .', ....... ' ........... -',"'.,',,'"",'""" BOILING POINT.: 100-425 APPROX. SPEClFI~ GRAVITY:' O.?2-O.?B VAPOR PRESSURE.: 1-"14.5 PSI (DEG.F) .... (H20-1) . ~* (MM HG) ..'.~. (-RE]D)'" MELTING POINT: NOTAVAILABLE SOLUBILITY: NEGLIGIBLE VAPOR DENSITY: 3.S. (OEO F). (IN YATER) . (AIR,l) EVAPORATION RATE (N-BuTyL ACET&TE - 1): NOT AVAILABLE ' '~ VOLATILE BY ,VOL- 1OO (. 115 DEG. F) ' APPEARANCE AND ODOR: BRONZE COLOR: CLEAR AND BRIGHT LIQUID'. HYDROCARBON DDOR,. " '"" ...... '"'"' ....... ;' ........ -r ........... '":'", .... '. .... - ....... "" .......... :":, .... ""-", FI. ASHPOZNT MO ME~rHDD: FLJMMABLE LZ#ZTS /%'VOLUME ZNJLTR -40 DEG F TAG CLOSED TESTER LOVER: 1.3 UPPER: 7.6 EXTzNalJZSHZNG ilEOZA ' '. ' ' USE YATER FOG.'FOAM.".DRY CHEMICAL OR C02. DO NOT USE A DIRECT STREAM OF YATER. P.ODUCT ¥ILL FLOAT AND. CAN BE REIGNITED ON,SURF&CE OF YATER. SPECIAL .FIRE FXGI4TZNG PROCEDURES MD PREGAUTIONS *' .' ' DANGER.':EXTREMELY'FLAMMABLE. CLEAR FIRE AREA OF*uNpRoTECTED PERSONNEL &NO ISOLATE. DO MOT. ENTER CONFINED FIRE SPACE YXTI.IOUT FULL BUNKER GEAR INCCUOING A POSITIVE PRESSURE NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. COOL FIRE. EXPOSED CONTAINERS VITH YATER. UI4JSUAL FIRE Mi)'ExpLOSzoN~ .' '' VAPORs AREFlEAV]ER TI. MN AIR ACCUMULATING IN LOV AREAS AND TRAVELING ALONG THE MOUND &rAY FROM THE HANDLING SITE. DO NOT WELD, HEAT OB DRILL ON'OB NEAR CONTAINER. HOWEVER, SF EMERGENCY SITUATIONS REQUIRE DRILLING, ONLY, TRAINED EMERGENCY PERSONNEL SI, CU~D-DRILL. sTABILITY': STABLE . HAZARDOUS POLYMERIZATION: IIISLL NOT OC~,JR GgWDSTSONS MI:) IMTERZM,.S TO AVOID: AVOID HEAT. SPARKS. OPEN FLAMS AND STIK]NG OXSDIZING AGENTs. PREVENT VAPOR ACCLMULATION. C&IIGN IIDNOXXD[ AM:) OTHER UNIDENTIFIED OIGANIC (~:)M)OUI4)S C4Jd Il FORMED UPON CGI~LISTSON. .'. ~ X BIPLDYEE FMYTEcrIall UIOEB CQKDITIONS Of POTENTIAL I, ISel,,r EXPOSUI~E. THE USE OF A NIOSI4-APPBOVED II~SPSRATOI IS iECOINENOED : (SEE SECTION X). PER ~l CFI 1110.134 USE ESTHER AN ATIIDSPHERE-SUPPLYZNG IESPIIATOII OR AN AZB-PUIIFYING IESPEBATOB FOil MImiC VAPOIS. 'FOil SEBVZCE STATION PEISOI4~L PIOTECTZON..SEE-SECTIQN nu ~ooo (~EOULJ~ U)LbMD GASOL~ZN[) AS REOUIRSO TO #lHlalZt ~K~N AND EYE CONTACT.' pROT[CTilVE CLOTHING. YEAR Zi~ERVIOUS-GCOvEs'·'EYE' PROTECTioN'. 11. 270-4 4 AND OTHER USE EXPLOS~ON~PRQOF VENTILATION AS REO~XRED TO CONTROL VAPOR cONCENTRATIONS. ECTZQN Itl".. - .~ ................... ~ ................ ' ............ DANGER EXTREMELY FLAMI4ABLE:__E~ .... ,eR-ATE THE HAZARD AREA AND U~NT IN/KT ~ .v~-_~--:~ PERSONNEL-' wEAR APPROPRZAz~ KG3~, MAY BE USEFUL iN SUPPRESSING VAPOR CLDUO~ CONTAIN KE AND C0NT&IN.' WATER FOG L SOAK UP RESIDUE WITH &N .,E To DO so. VACUU. ,UCKS O. STO,, E/SALVA y S EAKiNG CONTAiNE"S '0" RuN-OFF. REMOVE iTAB~E MATERIAL; PLAC- - '-- · '. &nc~aRENT SUCH AS CL&Y,.SAND OR OTHER SU ..... , BItT~IK. nISPOSE OF FLUSH SOLUTIONS AS ABOVE. D~.~PO~AL." FLUSH AREA W~T~ WATE~ ~e~nl~c~ ~i~°~d~'~L~CE ,IN G-LEAKiNG CONTAINERS; SEAL' ' SMALL SPILLS .ne TAKE'. UP wITH AN TIGHTLY FOR PROPER DISPOSAL. .VASTE DISPOSAL ' ~EPA - RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) REGI,ILATZONS. AS PRODUCED, THiS NATERZA~ iS, A PRODUCT. AND NOT A WASTE: iF DISCARDED OR IH"rENDED TO BE DISCARDED AS iS, iT iS J LiQI, IZD iGNiTABlE · HAZARDOUS WASTE AS D£FZHED. ZN RCRA (40 CFR 2~1.21)..THE EPA.HAZARDOUS WASTE NUMBER ZS DOG1. FREE L20~ZD 2GNZTABLE·wAST[S ARE BANNED FROM DISPOSAL By. LANDFZ~LZNG BULK'OR'iN CONTAINERS'. PRODucT· RECOVERY AND'RECYCLZNG ARE RECOmdENDED in-IERE' POSS3BLE. ' ENVIROIIilENTAL, HAZARDS ' THiS PRODUCT iS CLASSIFIED AS AN OiL U~ER SECTION 3tl OF THE C~EAN. EPA'' CLEAN WATER ACT(CWA). wATER ACT. SPILLS. ENTERING (A) SURFACE iATERS OR (B) ANY WATERCOURSES OR SEWERS ENTERING/LEADING TO SURFACE WATERS THAT CAUSE & SHEEN IWST BE REPORTED TO THE NATIONAL RESPONSE CENTER, · BOO-424'BR02. .KEEP OUT OF SURFACE WATERS AND ANY WATER COURSES OR SEVERS -ENTERING OR LEADING_TO SURFACE WATERS. ...... ,.....'.".-' ......................... ........... .---, ........... S.~_...... . . SFFECXALI~r.M/TTONS . ' ................................ · ' ' . PAR~S OPEN FL~ES;' ZNCLUOiNG pZLOT LI~TS. AND ST BANGER EXTREMELy FLAmI&BLE. AV~.?~E~,?,AT?~ Tn PREVENT VAPOR ACOUilULATION. ALL OXIDIZING ..... _ ........ ~.tNT SPAI~ClNG HANI.rUL km · ..... F S · 'E.QUZPMEN? NUST BE GROUNUtU ~u r-G~ · · ' . GASOLINE 8Y MOUTH. ' ~ - ' · ' A CLEANING SOLVENT OR FOR O?HER NO~-UOTOR FUEL'USES: ~o"'ufE AS A MGTOR FUEL ONLY. DO NOT USE_~_. ....... ~- aR USING TOILE? FACILITIES. LAUNDER ..... TING DFFINKZN~. aNk~,, -- . . A . -. WASH WITH SOAP AND WAT~_!~?~..~ ~,~mER NORMAL WORKING C0~ZTZOm AT SERVICE STATIONS. C0NTAMII~TED CLOTHING BEFOK~ K~u~. ~--- RESpiRATOR iS NOT WARRANTED. IF A MAJOR SPILL'OCCURS, GET UPWIND AND NOTIFY LOCAL EMERGENCY PERSOI~iEL. REMEMBER EXPLOSION &ND FIRE iS THE NDST iIBliEDIATE DANGER. .. .. . . . . .... ' .~ '; , · ', ~- . ..... ....................................... - · DEPAITiI/J~ Of TIANSPOITATIoN'cLAssIFzcATION: D .o.T. :.PlO/El SHIPPING HAME: GASOLINE OTHER ~l~rumlx11.: .' eUZDE ND. 2?. ..;;, .................................. ............. .. : -;--;-.'~ .... :"'"~ .... · o~R R~DUL~TO~Y-c~rrRoLS. ;..: ........... : ..... : .... :; .... THE COMPONENTS OF THIS PRODUCT ARE LISTED ON THE [PA/TSCA' ~NVENTORY ,0F CHEMICAL SUB~,TANCE$. . ..... : .......... :-:',.- .... :... ........ : ..... :-:,-.-~--:.'~-,-:-,?--.-, .... ; ........ ,: ............. :-- THE ZNFORMATZON CONTAINED HERE]N IS BASED ON THE DATA'AVAILABLE TO US AND IS IEL]EVED TO BE.CORRECT. - &KES NO ¥&RRANTY. EXPRESSED OR'ZMPL]ED REGARDZNG'THE ACCURACY OF' THE.SE DATA D~ THE ~EVER. SHELL ~ ............ t .ct THrREDF .SHELL. AsSuMES*~ gESPDNSZB]LZT~ FOR ]NUURY FgO~ THE ' -~ ~ ~- .- -..~j. .............................. ---.---~--.-. ......... . .BATE PREPARED:OCTOBER 11. 1985 BE SAFE READ OUR PRODUCT SAFETY ZNFORMATZON ..'.MID.PASS XT ON ~REGU]RES ]T) -SHELL 0ZL C:G~MY ' PRODUCT S,~FETY MiD C0MPLZANCE P. 0. BOX 4220 HOUSTON. TX ?7210 713-473-9461 ' ~Or ~ute ~d c~c ~th etlects refmt° ~ d'scds'~ m ~ct,on ltl . She.'."'" MATERIAL SAFEi;y -D: A EE CHEMTREC: 800-~24-9300 '. 'sHELL: "~3-241'4e10 ~ SAFE '. RE &C?I~,'T'" 0 'HAZARD RATING I~:L? · ~CTIO~. i~IOOUCT 1~' SU 2000 (SUPER UNLE&--"~""GA$0L]N[) ......... ARBONS M! XTURE BALANCE ~}~ENE~' CYCLOALKANES. ALKENES AND &RON&TI~,, I'lTlaKU~ .. .. 1OB-BO*-3 0-25 0 XYLENE ':" . . ~ 1330:20-? 0.-25:0 BENZENE - ' ' 91-d3-2 0.5-2.5 ::":=.'::': .................... ~,~'E .TOxzCZ~ O*TA .' ' . . .... .... : ..... ? ..... ' ...... ~I'~I&I,IN &6-m. ' . ................. , .......... - · ................................... ."'~,'~.; ,,mku. LM,0 ' . ... ' M:UT~-ZWUU.~'rz0N. LCS0'., JOJT~ ~ LD, O '"' .... ..,~ ...... . ................ ~ ........... "' ', . CHEMICAL PETEDL .' ~ I~ HYDROCARBON ' ... _.___._____ "' '"---'~------' FAMILY ' ' .- '. , ~ p O4362 ' _______----. " CODE - ' - . ' .......... · .... : ..... , .... ':--, .......... ; ............ ,....--,--; ........... .... ;;';;-; ........... . .'-. ...... ,., ........ ...... .-'--. ..... ..... ............. CAS )Uer~ ~rBCE~ COUPOUT]ON ' ,': . , .,..;.; ............. ,..' ........ ' .... , ...... NO. ' ............................... ''"T', ........ " · ' - miXTURE S~ 2°00 (SUPER UNLEADED GASOL1NE) .'_' 'p ' )S' GM/KG (RAT) )2. GM/KG:(R~BBIT) ),S IIG/L/4t4R (RAT) · THE' I.I[&LTN EFFECTS NOTED BEL.OV ARE CQNSZSTENT wITH IEQUIBE#ENTS LI4)ER ~ OSI4A HAZARO 'C0eIIJNICATION ST&NDARD (2B .CFB 1110.1200). I~SED ~ PROOUCT 'TESTING PROOU~T SS GEt&TEI-Y IRRITATING TO' THE EYES. ~'~?XOI4 "' ' _ ...... '~ee 114~T 'MM) IESP'IIIAT01IY TIACT MiD ADOITI0NALLY, '~._-THIS PI(X)UCT I~Y'C&USE 'IlIITA.~gN Tla ,~..w... . .'." .. -.. . WE LIVll dal) KIDNEY. D61A . , . ' . . -::~' ... IIIIESTION "~: _ ...... '""--''" '&T&L. IF sI~L.LOvLrD'' 'lldB~STION 0Ir PI01XICT'?-V-.'.IIE_SU.L.T_.I.,.N,,?tli:TtVNG: THIS I~IOOUC'r mT ir, .nM,,/,/,/,/~__v,- u. ,- T Il AVOIDID AS EVEN IlU, LL, ASPZI&TI~N (BIEATHING) OF V~ilITUS ZMTO THE I.M485 ~ ilISULT IN.&SPIibTION PNIUii~NITIS. .: ·. ... I~'~: St).20OO ( .MILE*lID Ill) .... ' ,SOS. '11,111-4 .iIRR]T&TZON'AS NOTED'ABOVE. EARLY TO MDOERATE CNS .(CENTRAL EVIDENCED.BY GZDDINESSo'HEADACHE. DIZZINESS AIM). NAUSEA; ZN 'EXTREME CASES. UNCONCIOUSNESS AND DEATH*. N" ]N SEVERE CASES DEATH lily .OCCUR KZDNEY DAMAGE MAT er. ~,v,.,,,~,.-,-- (BLUISH SK! ), ' T · EVER DAMAGE MAY BE EVIDENCED ' MA SMELLING FROM FLUID RE ENTZON). L - OUTPUT,' UIZNE,APPEAR&NCE 0l .EDE ' ( · ~ ' - A N ZN THE UPPER AIOOMEN ON THE Y LOSS;0~ APPETITE. dAUNDZCE (YELLOUISH SKiN COLOR) A/4) SOMETZNES P ] . . ~ RIGHT SZDE.~: · :. - AgGI~VATEO NEOiC~ C:~ZT:~ ....... · PREEXISTING EYE. 'SKIN. AND RESP]RATORY DiSORDERs MAY ·E'.AGGRAVAtED BY' [XPOSURE-.T0 THIS PRODUCT. iMPAIRED kZYER AND KIDNEY FUNCTION(S) FROM-PREEXISTING DISORDERS ?lAY, ·E AGGRAVATED AY. EXPOSURE T.0 · THIS PRODUCT ~!' ~ ' ' OTHER HEALTH EFFECTS IT HAS BEEN REPORTED THAT CHRoNIc' INNALAT'ZON EXPOSURE TO AN-UNLEADED ICT011 GASOLINE. iM.Ii'CH VAS FULLY' VAPORIZED. HAS PRODUCED KIDNEY AND LIVER CANCERS INSOME LABORATORY RODENTS. THE STUDIES .'I~ERE -SPONSORED BY THE 'AIIERZCAN PETROLEUM INSTITUTE. THE &PI. TEST MATERIAL USED I~AS BLENDED TO REPRESENT A.TYPZCAL UNLEADED MOTOR GASOLINE. SNELL UNLEADED GASOLINE HAS NOT BEEN EVALUATED ZN 'THIS'TYPE OF ANIMAL TEST · . · .~" . · ~ . .................. , ' .' .... , ....... ~ . --~,-.'- .... . .... ,-- .................. ; ..... .'.','. .... ~,~A, DNAL ~ ,.z;~TS' ' '" '~ " .. ...... ........ .-., ....... ,,.*, ...... , ...... ,..--~ ........ ,~.~--,-, ....... ,, ..... ~:~· ' ~.. os.,. zm T,.V/TVATLV/ST,~. /TVA · PEk/CEZL '~ , ' . ........... ND. PEk . . .................................................................. '''''' ............... ' . ' - .' 300 PPM '- · SOO pptl' . ' . . ---::"-.*----.-:-..-"i.-'" .... "-"' .... ' ......... "::"" """ ""'; ...... "'"' .... SECTION V '- - . EMERGENCY N4) I']RST JGD PI~OURES . . ..... ~ ..... FLUSH VITH rATER FOR"IS MINUTES ~ILE HOLDING EYELIDs OPEN. GET MEDICAL ATTENTION. 'SKIN CQNTJ!CT ' ' FLUSH ¥ITH rATER ~ILE REMOVING cONTAMINATED CLOTHING .AND SHOES'.' FOLLOV BY VASHING ¥ITH SOAP AND YATER. DO NOT REUSE CLOTHING OR. SHOES UNTIL CLEANED.' ZF IRRITATEoN-'PERSISTS. GET MEDICAl; ATTENTION. .' · ]I44AI. ATEON ' ' . . REMOVE VICTZM TO ·FRESH AIR 'AND PROVIDE OXYGEN IF BREATHING ~S DIFFICULT. GIVE ARTiFiCiAL RESPIRATZON IF NOT BREATHING.*. GET MEDICAL ATTENTION.. · . ZNG~STZGId Z'F V011ITZNG OCCURS SPONTANEOUSLy KEEP HEAD ·EL0V HiPS T0;~PREVENT '- · DO' NGT II4)UCE VOMITING. . · ASPIRATION OF LIOUID INTO THE LUNGS, GET NEDZCAL. ATTENTZON~ .* NOTE TO I~_. S.ZCZ_M~_ -- '...,,,.,.,,, ,,,,,., 'NGESTED AND VOMITING HAS NOt OCCUtRED~ .EMES]s sHOULD l[ IF il0gE · , HIPS TO PREVENT ASPIRAT~0N. ZF ERVISION KEEP VICTIM S HEAD ·ELON . II~)UCED VZTH MEDICAL SLIP _~:.-_.. BEFORE EMESIS, ~STRIC. GAG IIEFL~X. C0NVULSZDNS 01 UNCDNSCICUSNESS 0CCUI . . SYMPTOMS SUCH AS LOSS OF .......... , ..... R'D · LAVAGE USING A CUFFED EI~IX)TRACHEAL TUIE SHIX]L.g lc ,~NaZ. ur. s · . . ' ~ . 'INSTITUTE pOUND T14AT_F_U~L?_ V&_m~._~_.4:.~.u_~..~._~,~_u,."~,,~',,~',Mvvt, &N tAlc·EASE Of LIVER CIJ4CEI AT HZe~4 KIDNEY CANCEl Z, IALI__IAT~_._._iA_I'U'-&_.NI'~_~'.A_"'~,,mM,.~st:b~"nm';".'~--;;D~Ay · DOSES* ~ PI~) ZN FEMALE lICK. txmamawr.a ~,,u ,-_-~_ -___---.:._-_:.._, ........ --. ,,,, unq* ,nam,~. ]' . .. ( T IP ~d) SleNIFZG&I~E TO INN Of TI~ Il14Jl,.~l. Ur. u,q&.l, ),w-- 6~ ....... · · IIICKI~4S.~ THE BELA IONSI, I · , · . . ..... - .. . - · E.AT,O .,*" '.'YE'- ,,HZ'NE ,X'"""' .~' PE'"'~' ,__,~__'_.O_P' ~__:~_~.:m:..,,.~_!,~S,.~',,--~G~,~ ' '.,,' EI4COU~rEIIID ZN eAIOLZNE VAIKXI DUE TO THI ~ BINZENE CGNTE --' 'ZI4,1LATIDN'S1;UOIES all e&SOLzNE:'VL"<glS HAVE CJ~JSE0 CENTI~I. 'NEIVaUS sYsTEIII."EFFEC~TS*'ZN D0~S AT u · ~. HANDLING PROCEDURES AND SAFETY PRECAUTIONS IN THIS MSDS SHOULD BE FOi~LDt~ED TO .Mi[ SU 2000 ER UNLEADED GASOLINE) ' MSDS S1.181-4 * PAGE' 3 ED GASOLINE MAs'EVALUATED FOR GENETIC ACTIVITY iN ASSAYS-USING MICROBIAL ,lAN CELLS AND RAT BONE MA~RO¥ CELLS. THE RESULTS WERE ALL NEGATIVE. U~LEADED GASOLINE WAS ~DERED NDN-MUTAGENIC UNDER THESE CONDITIONS. -.. , EMPLOYEE SE'CTEON VII PNYSIGAL I~ATA BOILING*POINT: 100-425 APPROX. SPECIFIC GRAVITY.:*O.?2-O.?G (DEG F) (H~0-1) MELTING POINT: NOT AVAILABLE .sOLuBILITY: NEGLIGIBLE (DEG F) *_ (IN WATER)~, EVAPORATION RATE (N-BuTYL ACETATE $ 1): NOT AVAILABLE . APPEARANCE' AND ODOR RED COLOR; CLEAR AND BRIGHT LIQUID. vApOR PRESSURE: ?-t4.S PSI (MN HG) (REID). VAPOR DENSITY: 3.5- ~ VOLATILE BY VOL- '' 100 (,'dtS DEG. F) NYDROCARBON ODOR. .. . SECTION VIII FIRE AND EXPLOSION 14AZAROS -40,DEG F TAG CLOSED.TESTER'. LOWER: t.3 UPPER: ?.6 . EXTENGUZSNZNG MEDZA .-'~ * ' USE wATER FOG. FOAM. DRY'CHEMICAL OR C02.. DO NOT'USE A DIRECT STREAM DF MATER. PRODUCT ¥ILL. FLOAT AND CAN BE REIGNITED ON SURFACE OF WATER. · ' '* SPECIAL,FIRE FIGHTING'PROCEDURES ~ PREGAUTEONS . " DANGER. EXTREMELY FLAMMABLE.;,CLEAR FZRE AREA OF UNPROTECTED PERSONNEL AND ISOLATE. DO NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR INCLuDING A POSITIVE PRESSURE NIOSH iPPROVED SELFo¢Oh'TAINED-BREATHING APPARATUS. COOL FIRE EXPOSED CONTAINERS MITN WATER.~ .IAI,'SUAL FIRE MI) EXPLOSION IMZMU~ VAPORS ARE HEAVIER THAN AIR AcGUIEJLATING IN LOW AREAS ANOTRAVELING ALONG THE GROIJ~I3 AWAY FROM THE HANDLING SITE. DO NOT MELD. HEAT OR DRILL ON OR'NEAR CONTAINER. IOWEVER. IF EMERGENCY SITUATIONS REQUIRE DRILLING. ONLY TRAINED EMERGENCY PERS01~dEL SHOULD DRILL. ..........................o. . .~ ......... 0... . .. ..... ., .... ,-. ......... ~ .... . ,0.., .... ..~ ............... . SECTION IX ' REACTIVITY , ,~' STABILITY STABLE flAZABOOUS POLYMERIZATION: : MILL NOT OCCUR ~DI4)ITII~S MI) liATERIJU.S TO'AVOID: AVOID HEAT, SPARKS. OPEN FLAMES AlO STIltING OXIDIZING AMENTS. PREVENT VAPOR ACGUNULATIDN. MGGI/OSETZON PIIXIUCTS . . ~ X . lPL,OI'EE Klan . '. ~. ** .; . ,, LNDEB C., ITIONS OF ,'OT[,,TIAL NE,,4 X,OSU,,E. Tm' USE O"'A ,zOS'4-L.,,,MD ,W'ItATO' IS BECC,.,ENOEO ..- -(SEE SECTION X). .PER '~J CFR 1010.1~4 USE EITNER AN ATI)SP~RE-SUPPLYING RESPIRATOR OR AN .&ER-PUIIFYING IESPEIAT011 FOIl 01GANIC VAPOIS. PUl SEIVICE STATION.PEISMMEL PIOTECTION; SEE SECTION- XII ; ' SU 2000 (SUPER LI4'EJIOiD IASQLINE) mos BS.li~'4 PAne .4 pRDTECTZli'l CLOTHING SKIN AND EYE CONTACT WEAR ZUI)ERV2DUS GLOVES EYE pROTECTZON:'AND OTHER AS REQ4,JZRED TO MZN'IMZZE · . ' .~ . PROTECTZVE CLOTHTNG. AZX)ZTZONAL PROTECTZVE' IIASU~__~S.. CONTROL VAPOR CONCENTRATZONS- '~' ' ' USE EXPLOSZ0NoPR00F VENTILATION AS SPZ'LL 0l LE,MC ImOCZDUi~E_S.. ....... '~',,.... ,':'d'TTZ0N SDURcLrs. HANDLING EQUIPMENT MUST BE POUNDED DANGER. EXTREMELY FLAleiABLE._'_or'.~.~,r~.'~.:'"~'S~)~'~E THE HAZARD.AREA AND DENY ENTRY TO UNNECESSARY TO PREVENT SPARKZNG~ ' '"'" _Li_ff~r'___~.&..b.b~n -,d,~'.,onTtCTTVE CLOTNZNG SHUT OFF SOURCE OF LEAK ONLY 'iF -'PERSONNEL WEAR APPROPRZ&T__E_~E'_~vJ'K~..u~en"~"DG~i~Y)BE'USEFUL ZN .~IPPRESSZNG VAPOR CLOUD: c0NTAZN SAFE TO ~) SO. DIKE AND CONTAIN. li~Kn vq, " H AS CLAY. SAND R 0 FLUS~ SOLUTZ0NS AS ABOVE. ABSORBENT SUC R TO REIdQVE TRACE RESIDUE: DISPOSE OF · EAL DISPOSAL. · FLUSH AREA WZTI, i_U_.&.T? ........ ~'~T' MATERIAL AND PLACE ZN NON-LEAKING CONrTA`iNERS. S SMALL SPTLLS e,* TAKE' UP WITH AN AOa, tJND~,~ .. TIGHTLY' FOR PROPER D%SPOSAL. : YASTE DISPOSAL EPA o RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) REGULATTONS' AS PRDOUCED.. THIS 'MATERIAL `iS A PRODUCT AND NOT A WASTE. TF DISCARDED OR `INTENDED TO BE DISCARDED AS HAZARDOUS WASTE. AS DEF`INED 'IN RCRA (40 CFR 'J61.21). THE.. EPA HAZARDOUS WASTE IId, MBER ZS DOD1. FREE LIQUID TGHZTABLE WASTES ARE BANNED FROM DZSPOSAL BY LANDFZLLZNG BULK.OR *EM DOh'TAZNERS.~ pRaT RECOVERY AND RECYCLING ARE RECOMMENDED UI. IERE POSSIBLE: SURFACE WATERS.. DANGER, ' EXTREMELY FLAMMABLE. 'AVOZD 'HEAT, SPARKS. OPEN FLAMES, ZNCLUO%NG P~LOT LZGI'fl'S. A/d) STRONG' OX%D~Z%NG AGENTS. USE .EXPLDSZON-pROOF VENT'%LAT%ON TD PREVENT VAPOR ACCLJIIAJLAT%C~I. ALL HAI4)LZNG' ~ EC)U%PtlIENT I~JST, BE GROUNDED TO PREVENT SPARKZNG. HARIIFUL OR FATAL· %F SIIIALLOVED. DO.NOT SZPHON GASOLZNE BY NOUT.H.' · ' . FOR uSE AS A "OTOR FUEL, ONLY. DO NO? USE AS A-CLEANZNG SOLVENT OR FOR O~ER.NDN;MOTOR FUEL USES~ WASI. I w%TH SGAP AND wATER BEFORE EATZNG', DRZI4CZNG. SIIIOKTNG OR .USZNG TOZLET FAC`IL%TTES. LAUI~)ER CONTAMINATED CLOTHZNG BEFORE REUSE. UNDER NORMAL NDRK`IND C~m%TIONS AT SERV%CE RESPIRATOR IS NOT YARRANTEO. ' %F A-MAJOR SP%LL OCCURS. G~T UPW%ND AI~ ND?~FY LOC;AL EI~IIGENCY.PERSG44~I~L. REI~NBER EXPLOS%ON FIRE IS THE NC)ST ZIdIEDIATE DANGER. .. DEPAR~ OF TIANsPOITATZON.cLASSZFZCATZalI: FLAIIMILE LIQUZO D.O.,T.~ I)101)il'St''IZPPZNG M: · &ISOLZNE D.D.T. Z.D'. /LiN 1~0~. eU%0E NO. ~?. Su~ ' ~ .. ' MSDS Sl. 16~'4 pR:DZ:N,JC'T NNG ER UNI,.E&DED GASOI,.ZNE~) ~'' ' ';* '~ ' ~' -' PAGE S ~. .:- . · · ..,.~:.~.~ ..... ~ ..... ,;.;',~.....,,~-.-,-"-'--'~: .... ......... . ...... ~ .... ' ......... ' .............. *'"' OTHER REGUL.ATORY~ GGI4TRGLS ~ . ' ' . ' SECY%ON'XZV · - - ' ' ' ' ..... ~ .................. ~ ..... ............ -- ........ , ............ -."~' .... ., .... ."".'"'".""iT.. '. ' '. ' ':~ . THE COMPONENTS OF THIS PRODUCT ARE L.'ISTED' ON:TI~E EPA*~TSCA'*zNVENTDRYL DF. 'CHEMICAL SUBSTANCES.. · ,. '.: :'. .: : ' .. ......... , ........ ......, .............. .,.,..,;,'-:,,:-.;---.-~:-.,-' .... ;... -.:..---.--,;, ...... :-:-:--~- ~Tt,~E INFORMAT2ON CONTAZNED :NEREZN.ZS BASED ON THE* DATA AVAZLABLE-TO US AND 3S BEL.ZEVED'.TO BE CC)R~ECT 'TY 'EXPRESSED OR ']MPL'IED .REGARDING THE ACCURACY' OF THESE DATA 0R THI: k/~MEVER SHEL.L. MAKES NO V&RR&N ' *_ ...... '..~.e.. Aee~Ml:'S' NO RESPDNSZB'~L''~TY FOR ]NUURY FROM THE -'::?.,-;. ,e~ ms: nBTA]NED FROM THE USE THERI;U/' .' ~,r. bb. m.~..~v~k . : . ,~ . , USE OF THE PRODUCT DESCRIBED HERE.tN ....· ' '' ' ' :.,, .................... . ........... ,.;-,-..:,---,,-:,~ .... ::-:-::-:-~--',--~.,:-,-;--,,.,-.:.',:--,'.: ..... DATE PREPARE.O,:OcTOBER 11. 1985 ~E SAFE SJ~ZTY ZNFORNATZON ...MID pASs ZT ON.- (PRMXJCT LZAIZLZTY .. REGUXRES ST ) " . M P. sEP[SZ' : .' :. ' SHELL OZL.C:OIM)MiY ..... PBIXlUCT SAFETY' AND (:~IIPLZMICE :' 'P. O. BOX. 4320 " -' · ~ HOUSTON. TX ?7210 PRODUCT MSDS CATEGORIZED LISTING ~HAZARD 'CATEGORI ES m SU2ODO(R) (Super Unleaded Gasoline) ~H'I, Hi2, P-3 RU2000 (R) (Regu!.ar Unleaded Gasoline) Shell Regular Gasoline H-l, H'2, P-3 H-l, H-2; P-3