HomeMy WebLinkAboutUNDERGROUND TANK (5) California Regional Water Quality Control Board
Central Valley Region
Winston H. Hickox Fresno Branch Office
Secretary.[hr Internet Address: http://www.swrcb.ca,gov/-rwqcb5
Environmental 1685 E Street, Fresno, California 93706-2020
Protection Phone (559) 445-5116 · FAX (559) 445-5910
Gray Davis
Governor
23 July 2003
Regional Board Case No. 5T15000885
Mr. Tony Palagyi
Shell Oil Products U.S.
2255 North Ontario Street
Burbank, California 91504
UNDERGROUND TANK RELEASE, TEXACO SERVICE STATION, 2401 OAK STREET,
BAKERSFIELD, KERN COUNTY
You submitted Second Qurrrrer 2003 Groundwater Monitoring Report (Report) dated 15 July 2003 and
prepared by KHM Environmental Management, Inc. (KHM). The Report documents a quarterly
groundwater monitoring event at the above-referenced site on 18 June 2003. In a letter dated 17 June
2003, the Bakersfield Fire Department (BFD) referred the subject case to our agency for regulatory
oversight. It also provided us with information indicating that gasoline- and diesel-range petroleum
hydrocarbons and the fuel oxygenates methyl tertiary butyl ether (MTBE) and tertiary butyl alcohol
(TBA) leaked at the subject facility degrading s0il and that gasoline range petroleum hydrocarbons and
MTBE have degraded groundwater. The Report indicates that low concentrations of MTBE continue to
be detected in groundwater. By our 3 July 2003 letter, we requested that you submit a work plan to
identify the source of the release, abate the release, and determine the extent of impacted soil and
groundwater. Our letter also requested that you submit quarterly groundwater monitoring reports and
identify sensitive environmental receptors near the site. We reiterate these requests. A summary of the
Report and our comments follow.
Report Summary
Blaine Tech Serv{ces, Inc., San Jose (Blaine Tech) collected groundwater samples from monitoring
wells MW-1 through MW-5 on 18 June 2003. Depthto-groundwater was measured from 17 to 21 feet
below the tops of the casings (below TOC). Groundwater flow direction was toward the southeast with
a'water table slope of 0.016 feet per foot.
The samples were analyzed for total petroleum hydrocarbons as gasoline (TPHg) by EPA Method
8015M and benzene, toluene, ethylbenzene, and xylenes (BTEX), MTBE, TBA, di-isopropyl ether
(DUE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), and ethanol by EPA
Method 8260B. TPHg was not detected. TPHg was detected at 660 and 72 micrograms per liter (pg/L),
in MW-2 and MW-3, respectively, during the 25 March 2003 monitoring event. MTBE was detected in
MW-3 at 17 gg/L. MTBE was detected at 57, 7.3, and 40 gg/L in MW-3, MW-4, and
MW-5, respectively, during the 25 March 2003 event. Other analytes were not detected..
California Environmental Protection Agency
Recycled Paper
Mr. Tony Palagyi 2
23 July 2003
Based on field reconnaissance, KHM has verified that the nearest water well is California Water
Services Company well BK0600-02 is 759 feet east of the site.
Comments
A release from the UST system has contaminated soil and degraded groundwater quality beneath the
site. Investigation summarized in KHM' s GRASP Site Assessment Report dated 9 May 2003, discovered
low concentrations of TPHg; TPHd, MTBE and TBA in subsurface soils adjacent to the UST system.
Higher concentrations of these analytes may be present beneath the UST system. Low concentrations of
TPHg, and MTBE were detected in groundwater samples collected from on-site monitoring wells during
the 25 March 2003 monitoring event. The site is underlain by a transmissive aquifer used for municipal
water supply and municipal wells are within 1,000 feet. We requested by our 3 July 2003 letter that you
identify and abate the source of the release and investigate the extent of impacted soil and__, g.roundwa[er.
-~~W~--al-g-o- reque--~d t~at you Yfibm~t a wO'fk--PT~n proPOsi~ these investigations by 6 October 2003. The
work plan should include the results of an investigation to identify water supply wells within 2,000 feet
of the site.
Our letter dated ~ July 2003 also requested that you conduct quarterly groundwater monitoring beginning
with the Third Quarter 2003. During the Third and Fourth Quarter 2003, we .request that you confirm
chemicals of concern (COCs) by also analyzing at least three groundwater samples for the analytes
usually reported in a full EPA 8260 analysis (approximately 63 to 67 analytes) and dissolved lead.
Samples for dissolved lead should be filtered in the field prior to acid preservation or filtered in the
laboratory prior to acid preservation within 24 hours of sample collection. These procedures should be
noted on chain-of-custody documentation.
Analysis for general minerals, nitrate, and total Kjeldahl nitrogen should be performed during two non-
consecutive quarters to characterize groundwater quality and assess evidence for natural attenuation of
gasoline and diesel constituents. We request that at least one upgradient and two downgradient
monitoring wells be sampled for these parameters.
Please submit a report describing the Third Quarter 2003 groundwater monitoring event by 3 November
2003.
'S~-~io-'h~ZV~J~-~9'TT~"~~-r0tin~"'S~or-~ge ~ks 'were added to the California Code of
Regulations requiring you to submit analytical and site data electronically. Enclosed is our letter
(Required Electronic Deliverable Format for Laboratory and Site Data Submittals to Regulating
Agencies) explaining how to obtain information to implement the requirements.
V:\UGTXProjects\JDW_files\2003 Correspondence\City of Bakersfield Cases\Texaco Stn OakSt GW 7-03.doc
Mr. Tony Palagyi 3 23 July 2003
Please contact this office at least five days prior to fieldwork. If you have any questions regarding this
correspondence, please contact me at (559) 445-5504.
Engineering Geologist
R.G. No. 5951
Enclosure: Required Electronic Deliverable Format for Laboratory and Site Data Submittals...
C~
~i;-. Ba;bara Remp~l'~' SWRCB, Us~ -cleanup FUndl ~sac~tment01 ~)o en~osfir0Q, .....
Mr. Howard H. Wines IH, Bakersfield Fire Department, Bakersfield, w/o enclosurl',~
File: UST/Kern/Texaco Service Station, 2401 N. Oak St., Bakersfield/5T15000885
V:\UGT~Projects\JDW_files\2003 Correspondence\City of Bakersfield Cases\Texaco Stn OakSt GW 7-03.doc
Delta
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july 15, 2003
KHM Project D80-2401
Mr. John D. Whiting
California Regional Water Quality' Control Board
Central Valley Region
1685 E Street
Fresno, California 93706-2020
Re: SECOND QUARTER 2003 GROUNDWATER MONITORING REPORT
Texaco Service Station
2401 Oak Street
Bakersfield, California
Dear Mr. Whiting:
On behalf of Equilon Enterprises LLC dba Shell Oil Products (SHELL), KHM
Emdronmental Management, Inc. (KHM) has prepared this Second Quarter 2003 Groundwater
Monitoring I~eport for the above referenced site.
If you have any questions regarding this site, please contact Brad Clark at (626) 256-66~2.'or'
Tony Palaygi at (425) 377-8530.
Sincerely,
KHNI Environmental Management, Inc.
Bradley E. Clark, P.E.
Senior Project Engineer
Attachment: Second Quarter 2003 Groundwater Monitoring Report
cc:
Tony Palaygi, Shell Oil Products US
Isabel Mejia, Shell Oil Products US
Steve Underwood, City of Bakersfield Fire Department
6284 San Ignacio Avenue · Stdte E
San Jose, California 95119 USA
408,224.4724 · Fax: 408.224.4518
800.477.7411
911 South Primrose Avenue · Suite K
Mo~ovia, California 91016 USA
626.256.6662 · Fax: 626.256.6263
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july 15, 20o3
SHELL QLIARTERLY STATUS REPORT
Station Address:
KHM Project No.
SHELL Environmental Engin./Phone No.:
KHM Project Manager/Phone No.: '
Pr/mary Agency/Regulatory ID No.:
Other Agencies to Receive Copies':
2401 Oak Street, Bakersfield, California
D80-2401
.Tony Palaygi/(425) 377-8530
Gretchen Tagavilla / (626) 256-6662
Central Valley RWQCB / John Whiting
None
WORK PERFORMED THiS QUARTER (SECOND - 2,003):
1. Quarterly groundwater monitoring and sampling. Submitted quarterly report.
2. Submitted Site Assessment Report. '
3. Received agency letter from CVRWQCB on July 3, 2003.
WORK PROPOSED FOR NEXT QUARTER (THIRD - 2;003):
1. Quarterly groundwater monitoring and sampling.
2. Prepare and submit response to CVRWQ CB agency letter.
Current Phase of Project:
Frequency of Sampling: Quarterly
Frequency of Monitoring: Quarterly
Is Separate Phase Hydrocarbon Present On-site (Well #'s):
Cumulative SPH Recovered to Date: NA
SPH Recovered This Quarter: None
Sensitive Receptor(s) and Respective
Direction(s): ~
Current Remediation Techniques:
Permits for Discharge:
Approximate Depth to Groundwater:
Groundwater Gradient
Current Agency Correspondence:
Summary of Unusual Activity:
Groundwater monitoring
[~] Yes [] No
Nearest field verified well is Well BK060-02 (State
Well No. 29S/27E-25D02M) of the California
Water Service Company in Bakersfield
approximately 759 feet East of the site.
None
None
f6.72' to 20.98"
Southeast ~ approximately 0.01666 ft/ft
None
None
ff~/tchen Tagavilla/~/
P(,p~ject Manager (KI4'M)
ATTACHED:
· Table 1 - Groundwater Gauging and Analytical Results
· Figure 1 - Site Location Map
Figure 2 - Groundwater Elevation Contour Map
· Figure 3 - Hydrocarbon Distribution in Groundwater Map
· Figure 4 - TPH-G Concentrations in Groundwater Map
· Figure 5 -.Benzene Concentrations in Groundwater Map
· Figure 6 - MTBE Isoconcentrations in Groundwater Map
· Appendix A - Field Data Sheets
· Appendix B - Field Procedures
· Appendix C - Waste Disposal Document
· Appendix D - Laboratory Report and Chain-of-Custody Documents
TABLE
m m m mm mm m m m m m m m m m m m m m m
TABLE 1 I ~ I I I
HISTORICAL GROUNDWATER GAUGING AND ANALYTICAL DATA
SHELL SERVICE STATION
2401 Oak Street~ Bakersfield, California
::::::::::::::::::::::::::::::::: :~hi~N~: :: ¢~:~i~: ::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::: :::::::::::': :::: b~::::::~::::~:~:~:~b::~:~:~:~:~:~:~:~:~:::
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :::~:~:):::::~:~ ::::::::::::::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
~ I
MW-1 T~p of ¢~sing elevation (ft): 40~,03
~/18/200~ 26.81 0.00 37~.22
3/25/2003 . 28.1~_ 0.00 373.84 ND<1000 ND<~0 ND<0.50 ND<I.0 ND<I.0 ND<I.0 ND<I.0 ND<10 N~<Z.0 NDe.0 ND<2.0 ND<100
6/18/2003 17.70 0.00 384.3~ ND<~0 ND<0.50 ND<I.0 ND<I.0 NB<I.0 N~<I.0 ND<10 ND~.0 ND<2.0 ND<2.0
~W-Z To~ o~as~ng elevadon (ft): 404.4~
3/18/200~ 29.?0 0.00
3/25/~003 ~.0~ 0.00 3?3.4? ND<1000 66~ ND<0.50 ND<I.0 N~<I.0 ND<I.0 ND<I.0 ND<10 ND<2.0 NDe.0 ND<2.0 N~<100
6/18/200~ 20.79 0.00 383.70 ND<~0 ND<0.50 N~<I.0 ND<I.0 ND<I.0 N~<I.0 ND<10 ND<2.0 ND<2.0
MW-3 Top of casin~ eleration (ft):
3/18/2003 28.94 0.00 3?4.49
3~5/2003 30.27 0.00 373.16 ND<1000 72 ND<0.50 ND<I.0 ND<I.0 ND<I.0 57 ND<10 ND<2.0 ND<2.0 NDQ.0 ND<100
6/18/2003 20.98 0.00 382.45 ND<50 ND<0.50 ND<I.0 ND<I.0 ND<I.0 17 ND<10 ND<2.0 ND<2.0 ND<2.0
MW-4 ~op of casing elevation (ft): 400.11
3/19/2003 25.42 0.00 374.69
3/25/2003 26.75 0.00 373.36 ND<1000 ND<50 ND<0.50 ND<I.0 ND<I.0 ND<I.0 7J ND<tO ND<2.0 ND<2.0 ND<2.0 ND<I00
6/18/2003 17.31 0.00 382.80 ND<50 ND<0.50 ND<I.0 ND<I.0 ND<I.0 ND<I.0 ND<10 ND<2.0 NDe.0 ND<2.0
MW-5 Top of casing elevation (ft): 399.91
3/19/2003 25.03 0.00 374.88
3/25/2003 26.38 0.00 373.53 ND<I000 ND<50 ND<0.50 ND<I.0 ND<I.0 ND<I.0 40 ND<10 ND<2.0 ND<2.0 ND<2.0 ND<100
6/18/2003 16.72 0.00 383.19 ND<50 ND<0.50 ND<I.0 ND<I.0 ND<I.0 ND<I.0 ND<10 ND<2.0 ND<2.0 ND<2.0
Notes:
GW - Groundwater
SPH - Separate-phase hydrocarbons
MSL - Mean sea level
ND - Not detected
~g/L Lparts per billion
TPH-D - Total petroleum hydrocarbons as diesel
TPH-G - Total petrolemn hydrocarbons as gasoline
MT~E - Mefl~yl-te~ buWl ether
TBA - Ted-buWl alcohol
DIPE - Di-isopropyl ether
~BE - Ethyl-te~ buW1 ether
TAME - Tert-amyl mefl~yl e~er
\\Server\khm_data\ClientsLShellX_Shell GRAS~_GRASP Site~L2401 OakX2003-07-15_2Q03 Quarterly Repo.\Table I (2401).xls Page ] of I
FIGURES
119°Q4'00" W - 119~03'00" W 119~02'00" ~V WGSB4 119o01'00" W
°
~.~
~, ~:~ ~r~:~ ~ ~ ~ SITE LOCATION j~
I
~04'00" W ~¢~03'00" ~ ' ~9~02'00'' W Wa~B4 ~¢~0~'00" W
BAKERSFIELD, CALIFORNIA
l' ~"> FIGURE 1
SITE LOCATION MAP
2401 OAK STREET
BAKERSFIELD, CAL FORN A
N
DEISEL
TANK
SLAG
PLAN'~R
SERVAllON
WELL
MW-2
DISPENSER
iSLAND
(TYP)
OFFICE
AND
SLAB
P~N~R
ILl
I,I
o
MW-~e
383.00-- -- --
LEGEND
GROUNDWATER MONITORING WELL
LOCATION AND DESIGNATION
C~ROUNDWAT~R ELEVATION
IN FEET ABOVE MEAN SEA
LEVEL (Ft/MSL)
GROUNDWATER CONTOUR
IN FEET ABOVE MEAN SEA
LEVEL (Ft/MSL)
CONTOUR INTERVAL:O,50 FEET
APPROXIMATE GROUNDWAI~R
GRADIENT DIRECTION
,30 60
,
SCALE IN FEET
SHELL OIL PRODUCTS US
TEXACO SERVICE STATION
~/~J BAKERSFIELD,CALIFORNIA
FIGURE 2
GROUNDWATER ELEVATION
CONTOUR MAP
24-O1 NORTH OAK STREET
BAKERSFIELD, CALIFORNIA
K:\Clients~_Shell~_Shell GRASPS_GRASP Sites\2401 Oak\2003-O7-15_2Q03 Quarterly Report\FIGURE 2(2401)_GROUNOWATER ELEVATION CONTOUR MAP.dwg, l-lodeI, 7112/2003 11:58:01 AM
IO MW-1 I
3/25/OSIND<SOINO<0.50j ND<I.0 J ND<lO I
o6/18/o3 J ND<50 J NO<O.~O J ND<tO J ND<10 J
DEISEL
TANK
SLAB ,
PLANTER
MW-2
MW-2
OBSERVATION WELL
DISPENSER
ISLAND
(wP)
OFFICE
AND
BOO3H
PLANTER
CANOPYI
LEGEND
[-- MW-I~ GROUNDWATER MONITORING WELL
LLJ LOCATION AND DESIGNATION
bJ
1~H-g TOTAL PETROLEUM HYDROCARBONS
AS GASOLINE
M~E METHYL TERT-SUTYL ETHER
<~ TBA TERT-BUTYL ALCOHOL
O .ucJ/LMICROGRAMS PER UTER
ND NOT DETECTED
MW-5
MW-4
MW-3
DATE TPH- BENZENE MI~E TBA
03/25/03 72 ND<0.50 57 ND<lO
06/18/03 ND<50 ND<0.50 17 ND<lO
30 60
SCALE IN FEET
SHELL OIL PRODUCTS US
TEXACO SERWCE STATION
BAKERSFIELD, CALIFORNIA
FIGURE 3
HYDROCARBON DISTRIBUTION
IN GROUNDWATER MAP
2401 NORTH OAK STREET
BAKERSFIELD, CALIFORNIA
K:\Cllents~_Shell~_Shell GRASPS_GRASP Sites\2401 Oak~2003-07-15_2(~03 (~uartedy Report\FIGURE 3(2401)_HYDROCARBON D]STPJBUTJON IN GW MAP,dw~J, Model, 7/12/2003 11:58:37 AN
~ASH ~
N
DEISEL
TANK
SLAB
PLANTER
MW-2
(~
EXISTING -
'""--...~,~E R VAll 0 N
WELL
ISLAND
OFFICE
AND
~-MW-1
SLAB
PLANTER
CANOPYJ
LEGEND
MW-1 ~ GR(TdNDWAT~R MONITORIN~ WELL
LOCATION AND DESIGNATION
(ND<50) TPH-g CONCENI~ATIONS
IN MILIJGRAMS PER KILOGRAMS
Om/L)
NO NOT DETECTED
5O 6O
,
SCALE IN FEET
SHELL OIL PRODUCTS US
TEXACO SERV1CE STATION
FIGURE 4
TPI-I-g CONCENTRATION MAP
06/18/03
2~-01 NORTH OAK STREET
BAKERSFIELD, CALIFORNIA
K:\Clients~.Sheli~.ShelI GRASPS_GRASP Sites~240! Oak\2003-07-tS_2Q03 (~uarteHy Report\FIGURE 4(2401)_TPH-g CONCEI'FI~AT]ON MAP.dwg, Model, 7/12/2003 12:00:41 PM
Fl,
DEISEL
TANX
SLAB
PLANER
MW-2
OFFICE
AND
A~' MW-1
CANOPYO<~
-s I
LEGEND
MW-I~' GROUNDWATER MONITORING WELL
LOCATION AND OES~GNATION
ND<O,50 BENZENE CONCENTRATIONS
IN MILUGRAM$ PER KILOGRAMS
O~/L)
ND NOT DETECTED
EXISTING -
ERVATION
WELL
OISPENSER
ISLAND
(r~)
PLANTER
O ,30 60
SCALE IN FEET
SHELL OIL PRODUCTS US
TEXACO SERVICE STATION
BAKERSFIELD, CALIFORNIA
FIGURE 5
BENZENE CONCENTRATION MAP
06/t 8/O3
24-01 NORTH OAK STREET
BAKERSFIELD, CALIFORNIA
K:\Clients~.Shell~_Shell GRASPS_GRASP Sites\2401 Oak\2003-O7-15_2Q03 Quarterly Report~ClGURE 5(240t)_BENZENE CONCENTRA'r]ON MAP.dwg, Model, 7/12/2003 12:02:57 PM
DE[SEL
TANK
SLAB ·
PLANq~R
MW-2
ND<I .O
OFFICE
AND
CANOPY
LiJ
I,I
LEGEND
MW-I~- GROUNDWATER MONITORING WELL
LOCATION AND DESIGNATION
ND<t.0 MTI3E CONCENTRATIONS
IN MILLIGRAMS PER KILOGRAMS
LINE OF EQUAL MTBE CONCENTRATION
MTE]E METHYL TERT-BUTYL
ETHER
EXISTING
'"'"--.... O...~...ER VA TI ON
WELL
DISPENSER
ISLANO
(TYP)
MW-5
17
-~. SLAB
PLANTER
0 50 .60
SCALE IN FEET
SHELL OIL PRODUCTS US
TEXACO SERVICE STATION
BAKERSFIELD,CALIFORNIA
FIGURE 6
MTBE ISOCONCENTRATION
iN GROUNDWATER MAP
06/18/03
24-O1 NORTH OAt( STREET
BAKERSFIELD, CALIFORNIA
K:\ClienLs~_Shell~_Shell GRASPS_GRASP Sites\2401 Oak\2003-07-15_2Q03 (~uartedy Report~=IGURE 6(2401)_MTBE ]SOCONCENI~ATJON MAP.dwg, Model, 7/12/2003 12:08:07 PM
APPENDIX A
FIELD DATA SHEETS
WELLHEAD INSPECTION CHECKLIST
Page
Client .-~'~,1,
SiteA~ldress ~ZL/M 42~.~...<¢.'-~.~,us~C,.~,/~'
Job Number O
Date
Technician
Well Inspected -
No Corrective
Water Bailedj Wellbox Other Action
From Components Cap Lock Taken
Wellbox Cleaned Replaced Replaced (explain
below)
r
Well Not
Inspected
(explain
below)
Repair Order
Submitled
NOTES:
BLAIHE TECH SERVICES, INO.
SAIl JOSE SACPJ',,MEI';TO LOS ANGELES SAI-I DIEGO
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WELL GAUGING DATA
.a~, g/~[/V3
Client
Size [ Sheen/
(in.) [ Odor ·
' '[ Thickness
Depth to I of
Immisc~le [ la~scihle
Liquid (ft.)[ Liquid (fi.)
VoI~e of[
lmmisc~les]
Removed ]Depth to water
(r~) [ (n.)
Depth to well
· bottom (fi.)
qq. 3z
Survey
Po[ut: TOB[
or TOC.
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Blaine Tech Services, inc. 1680 Rogers Ave;, San Jose, CA 95112 (408) 573-0555
S~LL WELL MONITORING DATA S][[EET
BTS #: 0 ~ Ogre' I~F-- 7. Site: t~//'~.. [77' 0 -
Sampler: ./~ ~ Date: ~ ~'/0X
3 4~ 6
Well I.D.: /tx to- ~ Well Diameter: 2
Total Wel-I Depth (TI)): /4 t~. 0 6 Depth to W~er (DTW):
Depth to Free Product: Thickness of Free Product (feet):
Referenced to: r~ Grade D.O. Meter (ifreq'd): YS~
DTW with 80% Rechm'ge [(Height of'Water Column x 0.20) + DTW]:
Purge Method:
Bailer Waterra Sampling Method: ~
Disposable Bailer Peristaltic Disposable Bailer
Ivliddleburg Extraction Pump Extraction Port
~11~ e Other Dedicated Tubing
Other:
I Case Volume Specified Volumes Calculated Volume
!Well DiamelerM~lttiplier Well Diameter Multiplier
l" 0.0,l 4" 0.65
2 ' 0.16 fi" 1
3" 0.37 Other mdi~'- * 0.163
Cond. Turbidity
Time Temp (°F) pH (mS or ~ (NTUs) Gals. Removed Observations
o z7 .[f ,.t4of/ ..... 12o....
Did well dewater? Yes ~ ., Gallons actually evacuated:
Sm~pling Date: 6~[0 >._ Sampling Time: [ ~ { g Depth to Water: ,/
~.ample I.D.: ~ ~- [ Laborato~: Kiff ~ Other
.
Analyzed for: ~ ~ ~IT~E *P.~-~-D Ox~~? Other:
EB I.D. (if applicable): ~ riae Duplicate I.D. (if applicable):
' . ................. L .... .". ..........
~l~zed-f~ TPH-G BTEX MTBE TPH-D Other:
D.O. (if req'd): Pre-purge: me/~. Post_purge: mg/L
O.R.P. (if req'd): Pre-purge: ~}I.V Post-purge: . ,, mV
Blaine Tech Services, Inc. 1680 Rogers Ave.~ San Jose~ CA 95112 (800) 545-7558
SI~LL WELL MONITORING DATA Slq[EET
Site: ~7'q7-177'0
!
Is~p~,': 5 ~
Iwe]l ~.r>.:
Total Wetl Depth (TD): /.{'a~. 5' ?
Depth to Free Product:
Referenced to:
Welt Diameter: 2 3 ~ 6
Depth to Water (DTW):
Thiclmess of Free Product (feet):
I D.O. Meter (if req'd):
YSI
DTW w/th 80% Recharge [(Height of Water Colunm x 0.20) + DTW]:
HAClq
Purge Method:
Bailer Waterra
Disposable Bailer Peristaltic
Middleburg Extraction Pump
[~ible Other
Case Volume Specified Volumes Calculated Volume
Sampling Method:
Other:
Disposable Bailer
Extraction Port
Dedicated Tubing
Well Diameter Multiplier Well Dinmeler Multiplier
1" 0.0,1 4" 0.65
2' 0.16 6~ 1.47
3" 0.37 JOker radius: ' 0.163
~ Cond. Turbidity
Time Temp (°F) pH (mS or ~[~ (NTUs) Gals. Removed Observations
Did well dewater? ..Yes ..... (~ . . Gallons actually evacuated: ..C
Sampling Date: D//,~'/,~') Sa..mp..!ing Time: / ._q' 2. ao' Depfll to Water:
Smnple I.D.: ~ [-o ~' ~. . Laboratory: Kiff ~e Other
Analyzed for: '1'1~:;-~ ~ff~ r~rl'13a TPI4-D~ Other:
EB I.D. (if applicable): @ 'r~ .... Duplicate I.D. (if applicable):
Analyzed for: TPH-G BTEX MTBE TPH-D Other:
D.O. (if req'd): Pre-purge: mg/L 'ng/L
Post-purge:
O.R.P. (ifreq'd): Pre-purge: ..... illV Post-purge: Ii'IV
!
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Blaine Tech Ser~ices~ ~nc. t680 Rogers Ave., San Jose, CA 95112 (800) 545-7558
ri'
'S]:[ELL WELL MONITORING DATA SI-fEET
0 Site: qT-qT17'7'O
Sampler: . ~ ~' Date: {~/0 g"/t./~
wen m: / t4- 3
Total Welt Depth (TD): /-{r--t'. '5 ~'
Depth to Free Product:
Well Diameter: 2 3 (~ 6 8
Depth to Water (DTW): 2.0 · q~
.Thiclmess of Free Product (feet):
Referenced to: ~ O~de D.C. Meter (ifreq'd): Ym ~-~^CH
DTW with 80% Recharge [(Height of Water Colmma x 0.20) + DTW]: 2~.o/j'
Purge Method:
Bailer Waterra Sampling Method: ~
Disposable Bailer Peristaltic Disposable Bailer
Middleburg Extraction Pump Extraction Port
e Other Dedicated Tubing
Other:
J 5~" 5; (Gals.)X 3 = ~"~'° q Oa[s.
Case Volume Specified Volumes Calculated Volume
Well Diameter Multiplier Well Diameler Multiplier
I" 0.04 4" 0.65
2" 0.16 6" 1.,17
3" 0.37 Off)er rndiusz ' 0.163
Cond. Turbidity
Time Temp (°F)pH (mS or It~ (NTUs) Gals. Removed Observations
lq/5 ~O.q 7.0 38L ]L{ 3~,,,
Did welI...d~water7 Yes ~ ............. Gallons actually evacuated:
Sampling Date: ~ff[o 3 Sam Ih~g Time: lq 2 { Depth to Water:
Sample I.D.: /M ~- ~ Laborato~7: 3~ff ~ Other'
~alyzedfor: ...~ ~ M'm~ rpl-l-O ~5)Other: ....
EB I.D. (if applicable): ~ =,,,~ Duplicate I.D. (if applicable):
,~alyzed for: TPH-G B~X' MTBE TPH-D Gther:
~D.O. (if req'd): Pre-purge: mg/L Post-purge:
O.R.P. (if req'd): Pre-purge: mV Post-¢urge: mV
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Blaine Tech Services, Inc. 1680 Rogers Ave., San Jose~ CA 95112 (800) 545-7558
S]~ELL WELL MONITORING DATA
BTS¢: Site:
Sampler: 5 ~' Date:
Well I.D.:
Total Wel.! Depth (TD): /,/t~,. ~ 2.
Depth to Free Product:
Referenced to: r(~P Grade
Well Diameter: 2 3 ~ 6 8
Depth to W]aier (DTW): [ 7, 3/
Thiclmess of Free Product (feet):
D.O. Meter (i£req'd):
YSI
DTW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: 2, 3' 5 ?
I-IA CH
Purge Method:
Bailer Waterra
Disposable Bailer Peristaltic
Middleburg Extract[on Pump
~_~[e Other
?a3,q' <oals.)× 3 -- g(.2. oa, s.
Case Volume Seecified Volumes Calculated Volume
Sampling M~thod:
Other:
Disposable Bailer
Extraction Port
Dedicated Tubing
Well Diameter Mul,tjplfer Well Dimneler Multivlier
1" 0.04 4" 0.65
2" 0.16 6" 1.47
Y' 0.37 Other radius~ * O. 163
Cond. Turbidity
Time Temp (°F) pH (mS or ~ (NTUs) Gals. Removed Observations
Did well &water? Yes (N~ Gallons actually evacuated: ~2
Sampling Date: ~/~/'O,3 Sampling Time: It[o ~ Depthto.Water: ! 7-~(f'
Smn.p!.e I.D.: /M-Id- q Laboratory: riff c~4'>~-rv..~ Other
EB I.D. (if applicable): @ ,-~, Duplicate I.D. (if applicable):
Analyzed for: TPIt-G BTEX MTBE TPH-D Other:
D.O. (if req'd): Pre-purge: rog/I: Post-purge:
O.R.P. (if req'd): Pre-purge: ITIV Post-purge: mV
~laine Tech Services~ Inc. 1680 Rogers Ave. San Jose, CA 95~ 12 (800) 545-7558
SHELL WELL MONITORING DATA S~ET
Sampler: .
Well I.D.:
total Welt Depth (TD): /'/g-'Lq[
Site:
Da'tel
Well Diameter: 2 3
6 8
I Deptla to W~t'~er'CDTW): /~', )z ~.
Depth to Free Product: ]Thiclcness of Free Product (feet):
>~eferenced to: ~ Grade ID.0. Meter (if req'd): . YS~ ~_ACH
)TW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: '2-2 2,~/
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Purge Method:
Bailer Wa[erra Sampling Method: ¢:J~r
Disposable Bailer Peristaltic Disposable Bailer
Middleburg Extraction Pump Extraction Port
le Other Dedicated Tubing
Other:
Case Volume Specified Volumes Calculated Volume
Well Diameter Multiplier. Well Diameter Mulliplier
1" 0.04 4" 0.65
2" 0.16 6" 1.47
Y' 0.37 Other radius" · O. 163
Cond. Turbidity
Time Temp (°F) pH (mS or/~._u..(NTUs) Gals. Removed Observations
.,.!5~o ~L ~ 7.~ ~7/ .qq 4 ~ ,,,"
Did well dewater? Yes ~ Gallons actually evacuated: ~ ~
Sample I.D.: ~ - ~ Laborato~: ]dfr ~e Other
~a]yzedfor: ~ ~' MTB~ ...... rm-~-g ~) Other:
EB I.D. (if applicable): ~ ~.,,,~ Duplicate I.D. (if applicable):
~yzed for: TPH-G a'rEX MTBE Tt't4-D Ofl~er:
D.O. (if req'd): Pre-purge: m~/L' Post-purge: ~g/L
O.R.P. (if req'd): Pre-purge: mV~ Post-purge: mV
Blaine Tech Services~ inc. 1680 Rogers Ave., San Jose~ CA 95112 (800) 545-7558
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APPENDIX B
FIELD PROCEDURES
1680 ROGERS AVENUE
SAN JOSE, CA 95112-1105
(4081 573-7771 FAX
(408) 573-0555 PHONE
CONTRACTOR'S LICENSE #746684
www. blainetech.com
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July 17, 2003
Tony Palagyi
Shell Oil Products US
P.O. Box 7869
Burbank, CA 91510-7869
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Second Quarter 2003 Groundwater Monitoring at
Shell-branded Service Station
2401 Oak Street
Bakersfield, CA
Monitoring perforated on June 18, 2003
Grom]dwater Monitoring Report 030618-BF-2
This report covers the routine monitoring of groundwater wells at this Shell-branded facility. In
accordance with standard procedures that conform to Regional Water Quality Control Board
requirements, routine field data collection includes depth to water, total well depth, thiclmess of
any separate immiscible layer, water column volume, calculated purge volume (if applicable),
elapsed evacuation time (if applicable), total volmue of water removed (if applicable), mad
standard water parameter instrument readings. Sample material is collected, contained, stored,
m~d transported to the laboratory in conformance with EPA standards.' Purgewater (if applicable)
is, likewise, collected and transported to D.K. Environmental.
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Basic field information is presented alongside analytical values excerpted from the laboratory
report in the cumulative table of WELL CONCENTRATIONS. The fid/analytical repoz~ for
the most recent samples and the field data sheets are attached to this report.
At a minimum, Blaine Tech Services, I. nc. field persom~el are certified on completion of a forty-
hour Hazardous Materials and Emergency Response training course per 29 CFR 1910.120. Field
personnel are also enrolled in annual eight-hour refresher courses.
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Blaine Tech Services, Inc. conducts sampling and documentation assignments of this type as an
independent third party. Our activities ,at this site consisted of objective data and sample
collection only. No interpretation of analytical results, defining of hydrological conditions or
formulation of recommendations was performed.
Please call if you have any questions.
Yours truly,
Francis Thie
Vice President
FT/ks
attachments:
Cumulative Table of WELL CONCENTRATIONS
Certified ,Analytical Report
Field Data Sheets
CC:
Gretchen Tagavilla
KHM Environmental Management, Inc.
911 S. Primrose Ave., Suite K
Monrovia, CA 91016
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-BLAINE..TE'CH SERVICES; .!NC..
METH..O~:S' AND PROC-EDUI~ES
· ' FO.R THE ROU. T!.NE"M.ON!TORING'0F.
" GROUNDWATER-'WELLS AT,EQUWA SITES
Blaine' Tech. Serdces; Init, perfSrms en:vironme, ntal sampl!ng.a, nd:~docume'nt~ti.e_'n aS
indelSendont third par~.'. NEe .speoialEe in ¢¢ou~d~a'[6r monitoring asS~ig/iments and intention~j-ly
limit the. scope of'out' serv. i'~es ia thos&"cknterad On 'rifle gederation ~f Objective i'.n.formatiam.: '
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aoai'd cOr~tlict~ bf intems~t,. Blaine Tecl~ Servi.c6s,-ibc. personnel do n~)t, ev'aluafe,or interpret
die in'formation we collect. As'~ ..state licen's'ed 'c0ntr:,~ctor (C-57 Well drilling -~atei~
perfb. F.~,!ng s~icfl¥ technical. §arviC. i~s,'we db not.' make an¥~professiohai rebommendations .and.'._.'
per,btm no &onsulting ~:f any; kind.
.sAFETY,.
7sAMP[I'NG' PRoCEDuRES .OVE~VJ EW
I .
Al[~'mu'n~..water.~onitoring aSsi. g.nment~ Oed~rrnkdlfaf Eq. Uiva ~mp!.y with-Equiga~s safeby
: gui'deiine~s., .2.9 ors: 191'0.,.i20 .and-SB-198. In'jbr}, and illness ,Prevention Prog:.r. ar~ .(IIPP); Ail,.
~ Field T~chniciahS .receive the.full 40 hour 290FR 1'9i"0'.120 OSHA SARAHAZWOPER courge~
I-r~edi'c;al i~iearance' and o~-.the~J'~iB trairiir~g 'p.'dor. to-'cbmmenci'mg any wo~'k ori a~y. E~Lli¢:~ alta.'
i1.N~INEdTiONANDGAEiGiNG ,..; , : .,
.' W'e'll~ ar~ i'n-sPec~'bd-~d0r-to e~a~a~tSn, arid SampJin¢ The c6ndifion of: th6 ~.'elih~d .is.:ch~ckeci
and noted according fo'a wel'[head inOection: checklist. .. . %:, '.
Standard measurement~ incJude, t~e ;cJ&.p~h'to Wa't~r (DTWi and ~he total W~lldePth'..(TD)
· obtaihe~ with'industry, st'~'ndard;'elecf~'or~ic' sourid~rs. Which' erie gr~adu'a'ted in¢ihcreriien{s
hundredths of.a f6mL .... .. ., $.
The wafer i'r~'each moil is in~ected-.for'-tbe.pr&sence Of [mmisoibtes O~: ~deen a'nd'whb'n :free:.
produd 'is. sUs~e¢~d, i:t is_ confirmed u..~ing an ¢leiSt. ro-nic ihtsrface probe .(e.g.: .:MMG).- NO
sarhples ar~ chi ected from .a vCell containing Over ~wO-hundre'dfhs of a fo6f (0..02')' of product.
I. Deb¢'t0 w~ter.TmeaSUi:ernentsar& collected by our ~er~'o.n~e:(pfibr tb pu~ging and .minimum
I¢urge'vdlame~ ape ~lcula'ted anew for each Well' based.on the height o{ (he.~ater ~lumn and '
th~ diame'fer of thb well Exp~cte.d,~urge volumes are-n~ver ~ass, thah three ~s~ volumes hnd
.re set af n~ less-~han four ~se
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Well purElihg' devices are .selected .~n '~e basis of the well ~iame'ter.Ann the rot'a! 0Ium 'o be
evacuated, In 'most-cases:the welt.will be pdr~ed using an electS-lc submersii:ile i~ump (i.e.
Grundfc~s) susP'ended near (but no~ tou~l-iing) the :b'ot[~m ~f the~weil. Small ~)otum~s .of
I purgewater are ellen removed by hand bailing With si ~i.i~posable Isa.tier. :' - . ·
Well purg.ing 'corriFileIion' s.t'andai-cls' include minimu .re.purge voiflmes, .l~ut additierially requi~:~,
~ stab/li~atior~ .of sp.ecifi, c Or~und ,wa.tot parameters prior, ici'sAmple .c'0llec.tion,,T~Pi'cal groundwater
· par.'ame{e.rS dsed:tc~.meas.ure. ~tabilily are electrical c0rMdCl:ivity::PH, and.,temp-i~[ature,."
Instrument r.¢adings are ,dbtai.nod at re~l'uiar.inlervai~ d'udi~g ~he '~'vaouat. ion' p¢0cess (t'io b.ss
I' -than 5nce. pe'~casevol.ume), - ' ' - .. ' ' . '" ,'.-' ;- '
: stab~lJzatio,~· standards fo'r. rautine cluAderly mOnitaring Eib' ft]¢i, slt~s'include the foiioWing:. '
~ "Temi~eratUre.is conSicler~d t.5 ~a~)~ :stabilized when"Succes¢ive, readings dO 'not'fliiCtuate mere
~1 than 4-/= ~1 'degree Celsius. Electrical.csnductivi¢i~. con~iider-ed.stable.Wh~.n' sub6es-siv¢. '
· read'in'Ds are w~thin 1.0%, pH is i2on'siderecl to be stable' whe, n su&cess'ive readings :remain .
I Constant' ~r varY n'o .mo're than 0,2 of a. pHuniL' ' - .. · -- '" ' .' · '
I -D~WATtEREDWEI"L$ · ' .':' ':" ' ':"" ' ·
· Narma:l eV,~C.Liatimi~ removei~'no less than tl~i'ee'cas& volUme~ of wa.tgr :~roni the ~eli; Hovi/eV~r,
I "l'eS"wa"~r maY- be~;: ie~v~Se?h~'i~e th~ w~ll cl"ew~ters and ~Ide'~ n°t '~eC~ge' ' ' '
"-W¢iis known to-de' ' '"'" 'uat d ~ earle.as J~O~s~ble during each site :~i~!t'ir:i orClerto
_. ;al'iOw fo~' the grAatest amount 0fr. ecovering; A~ well ~ha~ does not-r,echarge'te .80% of Ifs.
I or.i~inal volume will be. sampled Prior td the d'~'parture' of our pefsor~nei from' the :site in Order to
I e'Iiminata-the need of a ~eturri'-~,isit. · :". : '... . .," - ' ' · "'
i. in:jbrbSi.¢ions_where a-oe~tain perdantaOe of i;ecO.veiry i~ inclbded, in.~bS'.iecai comp.lotion '
I standard' OUr i~ersonne:l,follow the' regUlatorY expectat~io~ ' . _. ,.-.' . ' ' -- ' - '
I PuRGEW;ATER'CONTAINMENT' ' ' . ' '.. .' .. ' "" ' . .. '"' "
~" Ail .non-hazaEdouS purge~ate¢ eva'cuated fr:orn:-L~a~l~ .g~-oLindwater'monitoring t~ll is ~captur;ed .:
land 'ccintained tn oh-bOard s'torage .tanks tin th~'Sa..mpiin~ veHi'Cle'.ahd/or sped~l w~ter ha'uli~ig
· trailers, Effluent from the. decontarriina[i0n' of-reusab'le appara(us .(sounder¢,. eie~tdc,purdps' and
--hoses.~[c,),, consisting c~.grod~dwater' comb.ined With.'di~idnized.Water and nor~pl~oS, pt~e soap,·
S-also c_~'p['U~d .and-pdmped into-effluent-tanks. ' ,'
. Non-hazardous purgb~,vater iS trar~spoded Unde~r.~ta.n'dard. B[Ii of ~.a~Jing documentation tO t~ .
,~.alain~ Tecl~ Services', inc, facility b, efore being banS.ported .to.an Equiya at~proved disposal
cility, ~ ..'. : ..
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,AMPL= COLLECTION DEVICES i .. :
ISAIgI-PLE CONTAINERS -.. ..
Sar:nple' material i's d.ebanti~d directly frown the sampling bailer into' sample.containers'provial&d
I by the laboratory ~vhich-wi'If aflaIYZ¢ 'the ~r~p]e~."The tPnsf~r of sarhpl~ matert, ial 'from. the '
" i'bail~r to the s.~mple containercon, fo .r(nls to spec!fi~dOns contained in the-U'SEPA'T2E. G.D.. The',
ty~e of sample contai, ner; material of oo'nstmdion, method· .of closure and filling req~iPem~nts
I are slp~ciflc to the intended~ ~nalysis. chemica, is needed, tO prese~v& the sa.mpl~ rha:-te,rial are
common, ty' placed 'inside the' gahnple conta, iners by ±he. le. bo~'atory or, §!asswai'.e vendhr prior to
'delivery of the. bot~l~ to aur'.personne!. The. la.borate, ry sets..~he number of replicate.~n~ainers.
TRIP BLANKS- , ' ' ' .-
Ot~on .reqoest, a Tril~ Blank is carded to.ea~h~si, te and is kept :insid.e the coo!~ ~dr the .dUralion. of
, the 's.r:impl!ng event~ it is ~umed. o~.er t6 the laboi=a[ory-¢or a,nalygis with ~ke .samples f~:om that
UpSn request, on~ DUpli -¢--.~.l;e sample is .colle~teUl al each site. It' is up. :to'.~e Fie. Id Technician to
ChOose the well at w. Nch the DUplicate is calle.cted, Typically, a duPli~,a-te is'~51ie6tSd -from one'
I- 0fthe mosul contaminated Wells, ':Fh¢ Duplicate sample is labeled DUP.·thus i-endering the
I.Ail people c~OntaTnefS are promptly F~laced iri' rood'grade ice cheSCt~S ~'or st~rag&, in the field and
;, transpoR (dir,'ect or via .oU¢ Cecilia) tb llhe,anal.ytica!'la.'borat0~ that will perform .the iritended' ..
· .analYtical' pr6cedui-es.' 'These. ice chests o6'nt.a.'in, quantitle~ of.i-.estaumnt grade :ice as a.
I.refdgerant mated~l. The sample~'ar~-maintained i.n .,eith~er art'-ice-cBesf oF a refrigerator'ur!tii.
re-linq.uished into..the CUS~oSy of the labbr..ator~; or laboi-ator3i Courier. '.. '.' ,-
I. DOCUMENTATION CONVE~TiONS. ., ,. "
~'a~h'and every sO,pie' =ont~iner'has a label affixed to. it, In most oas&S these, l~'bets are ,
IDen'~ra~ed by .our o~'ice p~rsoh-nel and are pailia!iy peep.tinted. :Labels re'ri ai~o. Be hand writ!.eri
by our field. Fier:Sonn_.ei.' ' T The Site is'ipentifie.d_ .With the':~;tore numb~r'a,nd ~;ite .ad,Ii;ess, as is.the .'
p~iiicular groundwater w..ell Eom'which. the, sample~ is drawn (e.g., MWzi ;. MW~2, 'S~1 .~tc,)', The.
Itime.af WhiCh ~he shmple ~as 'Coll:ec~ed and the init!als ot~ the per~;Or~ colle6tl;~g the sample, are .
I~phain of Custo'dy;:records are-created using 0lient specific ~epi-inted-forms'following UsEPA"
I3il.l'of Ladin~l records-are conlempbraneSus 'records. Creeled in th~ field al. the site whe'Fe the
I~o'~-ldazardous pur;geWa~er is -generate6I. riel8 T~6hnicia.~s use'prePFifited Biil'of Lading forms,
'All equipmen,t is brought to the site :in 61.e;an and s~r~iceabb conditio~ and-is ctea~'ed after Use,
'in each weJl' and before.subseq~ent~use, ih anyoth~ well.. Equipment. is de~ontambated before-
.leaving th~ site. " , ·
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· ~e pdma~ decontamination d~vic~ is a commercial Ceam cleaner. ~e steam' cl~aner is de~
t~ned to functi~n-~S a hot pf&s~ure washer which i~ 'then opefated wi~.'high qu.aii~'d¢'io~zed
Water which 'is p~oduced ~t' ob~ f~cifi~ and' stored o~board our ~am~liflg. Vehicle,. Cleani. ng
facilitated by the use 0~ prop~ieta~ fi~urCs a.~d devices indfud.ed iq' the.patented Wofkstation
(U.'s;: Pa~ent 5,535,7¢5)-tba't is incoMorated' ih eauh sampling' vehicle: TSe, steaW'
used to deOon reei~ pum~s and baiters. ~ . ..
AnY, sensitive e~uipmed[ar p~'~. (LC.' Diss~}~ed 'O~eh sensor mem-braqe;' souhde[ etc.)'-~at..~'
~nnOt be ~,ashed using' ~¢.h'ot high pt~ssu~e:,W&te~, will be ~yed -~ith a, non~Ph.o~ph~te'
soap ~nd ~ionized.~ater s~iufion'and rinsed with d~ioni~ed wa[er, : .., ...
~MPLE: The sbun~er ~-~ban~d 5e.~een'w~!ls.~sing-~e ~n0mphbsp.hate ~oap and ~ei°nized
Water.sol~ien ¢ollbwad-by d¢iohi~ed'water ~inS~s.. T~e ~ou~de~is. then, Was~ed wi~ th'e ste'~m
cleansr beseem sites or as necessita{ed b~ Use' i~ a :pa~icut-arlY con~amiflated-welL, ' ' '
., DISsOLVe: O~G~N R~DINGS ' . . - -
,; Ail.'Diss4t~ed O~eq' ~¢,a.diags-are taken u~i~g YSI]me~ers (e.g, YSl'Mbd~i 58 or eqdiv~tent ySi
"~eter). These'meters are' equipped'Wi, th.a YSf s'ti~i~g deYide ~t~nables them-to ~[le~.
-abcurate i~-situ.readings.. ,The'.prob~/sd~ng deeices:.ape medified ~o allow doWnho~e -"
meaSqrements tu be taken fr~m we.IlS as ~m'al~ as ~oqn'ch dia~&te~ - ,,
' ~he'probe and 'reel is dec~btami~'a~ed 5e~eeh W~l~' aS deEc~ibed abo~e~ ThC ~'¢ter is
~librated 'be'~een 'weljs ~s per'the instmC[i'ohs Jh'..th~ opeCati¢~*manuaL Th~ prCbe-and ~iffer.
~ater C~lu~n alluw~'~O use: .
in~0,'~he.
b'e¢oCe
bXYIDATON'REDDOTiON :PO~IAL REAblNGS -
,Ail ~eadingS .are ¢b~ained With .either taming: or My~onzL meters (e::g, C°'mb¢ 'oRpL6'5 or a'
Myron.-L:'ultrame~er GP)..The-me:tecis cleaned b'e;~een' wellS. &s described a~ave. ~'e meter
~S ~librated ~t. ~he s.ta~ of.e~ch day aceohdi.~g tb ~he"ihStructio~ ~anua. L in: U. se.-th~
:Placed jna cup of freshly obtained..mOnTtofing ~el] w~ter.and alld~ed, to stabilize. *'
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APPENDIX C
DISPOSAL DOCUMENT
NO. 63537
NON-HAZARDOUS WASTE DATA FORM
G I::: N F: R A-13'N,:.;
oHELL OIL PRODUCTS U--.'~ ['=..-'.-=~
NAME ......
BURBANK. CAg1510-Tm9 C/ / . D .- , /'. 713 241-1516
...... / u~V i'~[fl'gyF - " "
TAINERS: No. VOLUME ._
NON-H~DOUS GROUNDWATER PURGED GROUNDWATER
WAS~ DES~I~ION , GENE~TING PROOES~
COMPONENTS OF WAS~ PPM ~ COMPONENTS Of WAS~ PPM
WATER 99-100%
TP H ' < 1% IN CID E
RiP R ~
~- · ~ ~ -- ~m ~
"' ' ,-~0 vv ~ . .....
PROPERTIES: pH__ ~ SOLID ~ L[QUID ~ SLUDGE ~ SLURRY ~ OTHER
24-HOUR E~{ERGEHCY PHONE (BO0) 424-9300
HANDLING INDUCTIONS: ~ ....
'THE GENE~TOR CERTIRES THAT THE ~ ~
WASTE AS DESCRIBED IS 100°~ [ ~ ~ / /// ~ ~On ~hal-of
~PED OR PRIED FU~ NAME & SIGNATURE .,". DATE
1281 BR~ CAIWON
BR~ CA~FORN~ 92821 ] Blaine Te~ Se~s. Inc.
(7 ~4) ~90-6955 To~an~, CA 90501
PHONE.O ...... (310) 782-2J65
~UCI(, UNE, I,D. NO. ~PED OR PRINTED FULL N~E & SIGNATURE
3650 E. 26TM STRE~ DISPOSALM~HOD
ADDRESS ~ ~NDFiLL ~ OTHER
LO~; AJ~GELES, CA 90023
C~, STA~. ZIP
~PED OR PRINTED FULL NAME & SIGNA~RE
DATE
c/o ] NONE DISCREPANCY
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APPENDIX D
LABORATORY REPORT
AND CHAIN-OF-CUSTODY DOCUMENTS
I ~alscience
~ff._nvironmental
I ~aboratories,,nc.
I June '25, 2003
I Nick Sudano
I Blaine Tech Services, Inc
I Subject' Calscience Work Order No · 03-06-1102
i ' Client ReferenCe: " 2401 Oak Street, Bakersfield, CA
I Dear Client~
Enclosed is an analytical report for the above-referenced project. The samples
~ included in this report were received 6~20~2003 and analyzed in accordance with
I the attached chain-of-custody.
· Unless otherwise noted, all analytical testing was accomplished in accordance with the
· guidelines established in our Quality Assurance Program Manual, applicable standard
operating procedures, and other related documentation. The original report of any
· subcontracted analysis is provided herein, and follows the standard Calscience data
· package. The results in this analytical report are limited to the samples tested and any
reproduction thereof must be made in its entirety.
I If you have any questions regarding this report, please do not hesitate to contact
the undersigned.
I Sincer..~y'
tal ~ --
I r s, '.c. Quality Assurance Manager
I Project Manager ,
I' ~ 7440 Lincoln Way, Garden Grove, CA 92841-1432· TEL:(714)805-5494 · FAX:(714)894-7501
clence ANALYTICAL REPORT
-
~.. aboratones, Inc.
Blaine Te, ch Services, Inc Date Received: 06/20/03
20360 G~amercy Place Work Order No: 03-06-1102
Torrance, CA 90501-1511 Preparation: EPA 5030B
· Method: EPA 8260B M
Project: 2401 Oak Street, Bakersfield, CA Page 1 of 2
Lab Sample Date Date Date
Analyzed QC Batch ID
Prepared
Client Sample Number Number Collected Uatdx
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~MW~I,.~'~:~:~:~,-~F~'~:~i~:~'.i~'.? ::~i { .!-!~: ~:::~.=~.~j~:~:~i~:~ i: i~[~03~I~02,~1~.~ ?~.~.
Parameter Result 'RL DF Oual Units Parameter Result RL D~F Qual Units
~ ND 0.50 I ug/L Tert-Butyl Alcohol (TI3A) ND 10 I ug/L
Ethylbenzene ND 1.0 1 ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L
Toluene ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L
p/m-Xylene ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L
o-Xylene ND 1.0 1 ug/L Total Purgeable Petroleum ND 50 1 ug/L
Hydrocarbons
Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ucj/'L
Surrogates: REC (%) Control Qual Surrogates: REC/%) Control Qual '
Limits
1,4-Dichlorobenzene-d4-TPPH 98 70-130 1,4-Difluorobenzene 103 70-130
1,4-Dichlorobenzene-d4 98 70-130
Parameter Result RL DF Qual Units Parameter Result RL DF Qual Units
~ ~ -'~. 50 '--'1
Ethylbenzene ND 1.0 I ug/L Diisopropyl Ether (DIPE) ND 2.0 I ug/L
Toluene ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L
p/m-Xylene ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L
o-Xylene ND 1.0 1 ug/L Total Purgeable Petroleum ND 50 I ug/L
Hydrocarbons
Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ug/L
S~rro,qates: REC (%) Control Qu.a,I Surro;l. ates: REC (%) Control Qual
Limil~s 7 1
1,4-Dichlorobenzene-d4-TPPH 99 70-130 1,4-Difluorobenzene 93 0- 30
1,4-Dichlorobenzene-d4 99 70-130 ~ ·
Parameter Result RL DF Qual Units Parameter Result RI_ DF Qual Units
Benzene ND 0.50 1 ug/L Tert-Butyl Alcohol (TBA) ND 10 1 ug/L
Ethylbenzene ND 1.0 I ug/L Diisopropyl Ether (DIPE) ND 2.0 I ug/L
Toluene ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2,0 1 ug/L
p/m-Xylene ND 1.0 1 ug/L Tert-Amyt-Methyl Ether (TAME) ND 2.0 1 ug/L
o-Xylene ND 1.0 1 ug/L Total Purgeable Petroleum ND 50 1 ug/L
Hydrocarbons
Methyl-t-Butyl Ether (MTBE) 17 I 1 ug/L
Surrogates: REC {%) Control Qual Surrof:l. ates; REC (%) Control Qual
Limi~
1,4-Dichlorobenzene-d4-TPPH 98 70-130 1,4-Difluorobenzene 96 70-130
1,4-Dichlorobenzene-d4 98 70-130
RL - Reporting Limit , DF - Dilution Factor , Qual - Qualifiers
I. I
J~,'~ I I~ ,. 7440 Lincoln Way, Garden Grove, CA92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894-7501
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.aiscience
vironmen tal
aboratories, Inc.
Blaine Tech Services, Inc
20360 Gramercy Place
Torrance, CA 90501-1511
ANALYTICAL REPORT
Date Received: 06/20/03
Work Order No: 03-06-1102
Preparation: EPA 5030B
Method: EPA 8260B M
Project: 2401 Oak Street, Bakersfield, CA Page 2 of 2
Lab Sample Date. Date Date
Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID
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Parameter Result R~L DF Oual Units Parameter Result RL D__F Qual Unit._.._~s
Benzene ND 0.50 1 ug/L Ted-Butyl Alcohol (TBA) ND 10 1 ug/L
Ethylbenzene ND 1.0 1 ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L
Toluene ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L
p/m-Xylene ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 I ug/L
o-Xylene ND 1.0 1 ug/L Total Purgeable Petroleum ND 50 1 ug/L
Hydrocarbons
Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ug/L
Surrogates: REC(%) Control Qual SurroR, ates: REC (%) Control Qual
Limits
1,4-Dichlorobenzene-d4-TPPH 98 70-t 30 1,4-Difluorobenzene 97 70-130
1,4-Dichlorobenzene-d4 99 70-130
Parameter Result RI.
Benzene ND 0.50
Ethylbenzene ND 1.0
Toluene ND 1,0
p/m-Xylene ND 1.0
o-Xylene ND 1.0
Methyl-t-Butyl Ether (MTBE) ND 1.0
Surroqates: REC (%) .Co.n. trol
Limits
1,4-Dichlorobenzene-d4-TPPH 97 70-130
1,4-Dichlorobenzene-d4 97 70-130
DF
Oual Units Parameter Result RI.
1 ug/L Tert-Butyl Alcohol (TBA) ND 10
1 ug/L Diisopropyl Ether (DIPE) ND 2.0
1 uglL Ethyl-t-Butyl Ether (ETBE) ND 2.0
I ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0
1 ug/L Total Purgeable Petroleum ND 50
Hydrocarbons
1 ug/L
Qual Surro.qates: REC..{%) Control
1,4-Difluorobenzene 97 70-130
D_..~F .Qual Units
1 ug/L
I ug/L
1 ug/L
I ug/L
I ug/L
Qyal
Parameter Result RI_ DF: Qual Units Parameter Result RI. DF Qual Units
Benzene ND 0.50 1 ug/L TeA-Butyl Alcohol (TBA) ND 10 1 ug/L
Ethylbenzene ND 1.0 I ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L
Toluene ND 1.0 I ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 uglL
p/m-Xylene ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L
o-Xylene ND 1.0 1 ug/L Total Purgeable Petroleum ND 50 1 ug/L
Hydrocarbons
Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ug/L
Surrogates: REC (%) Cont. rpl Qual Surrogates; REC (%) Control Qual
Limits
1,4-Dichlorobenzene-d4-TPPH 96 70-130 1,4-Difluorobenzene 100 70-130
1,4-Dichlorobenzene-d4 96 70-130
RL - Reporting Limit , DF - Dilution Factor , Oual - Qualifiers
7440 Lincoln Way, Garden Grove, CA 92841-1432
· TEL: (714) 895-5494 · FAX: (714) 894-7501
~ alscience
j~ nvironmental
~A~ aboratories, Inc.
,
Blaine Tech Services, Inc
20360 Gramercy Place
Torrance, CA 90501-1511
Project: 2401 Oak Stree ~ B;
~uallty C°ntr°l Sample ID '
Parameter
Benzene
Ethytbenzene
Toluene
p/m-Xylene
o-Xylene
Methyl-t-Butyl Ether (MTBE)
Tert-Butyl Alcohol (TBA)
Diisopmpyl Ether (DIPE)
Ethyl-t-Butyl Ether (ETBE)
Tert-Amyl-Methyl Ether (TAME)
Total Purgeable Petroleum Hydrocarbons
Quality Control - Spike/Spike Duplicate
Date Received: 06/20/03
Work Order No: 03-06-1102
Preparation: EPA 5030B
Method: EPA 8260B M
2401 Oak Street~ Bakersfield~ CA
Date Date MS/MSD Batch
Matrix Instrument ' Prepared Analyzed Number
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MS %REC MSD %REC %REC CL RPD RPD CL Qualifiers
105 112 61-139 6 0-27
95 109 81-123 13 0-16
96 103 76-124 7 0-12
98 110 85-121 12 0-15
94 107 85-121 14 0-14
98 104 73-127 6 0-18
82 90 40-172 9 0-31
100 102 73-121 3 0-14
95 103 77-125 7 0-15
87 97 74-128 11 0-16
91 103 82-118 13 0-13
7440 Lincoln Way, Garden Grove, CA 92841-1432 o TEL: (714) 895-5494 · FAX: (714) 894-7501
nvironmental
I j aboratories, lnc.
Quality Control - Laboratory Control Sample
Blaine Tech Services, Inc
20360 Gramercy Place
Torrance, CA 90501-1511
Project: 2401 Oak Street, Bakersfield, CA
Date Received: 06/20/03
Work Order No: 03-06-1102
Preparation: EPA 5030B
Method: EPA 8260B M
Quality Control Sample ID Matrix Instrument Date Analyzed Lab File ID LCS Batch Number
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Parameter
Benzene
Ethylbenzene
Toluene
p/m-Xylene
o-Xylene
Methyl-t-Butyl Ether (MTBE)
Tert-Butyl Alcohol (TBA)
Diisopmpyl Ether (DIPE)
Ethyl-t-Butyl Ether (ETBE)
Conc Added Conc Recovemd %Re; %Rec CL
50 59 118 80-122
50 54 108 87-117
50 55 110 81-123
100 110 114 85-122
50 54 108 85-121
50 53 107 81°117
250 220 86 68-128
50 56 112 78-120
50 51 102 81-123
50 47 94 78-126
750 760 102 88-112
7440 Lincoln Way, Garden Grove, CA 92841-1432
· TEL: (714) 895-5494
qualifiers
· FAX: (714) 894-7501
~=-alscience GLOSSARY OF TERMS AND QUALIFIERS
~nvironmental
~ aboratories, Inc.
Work Order Number: 03-06-1102 .......
I Qualifier Definition
ND Not detected at indicated reporting limit.
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WO.K 0~ #: 03 -~-
' ' o / o,/
SAMPLE RECEIPT FORM /
TEMPERATURE - SAMPLES RECEIVED BY:
CALSCIENCE COURIER:
Chilled, cooler with temperature blank provided.
..,Chilled, cooler without temperature blank.
~"'Chilled and placed in cooler with wet ice.
__ Ambient and placed in cooler with wet ice.
Ambient temperature.
__ o C Temperature blank.
CUSTODY sEAL INTACT:
Sample(s): __ Cooler:__
No (Not Intact)
LABORATORY (Other than Calscience Courier):
° C Temperature blank..
o C IR thermometer.
Ambient temperature.
SAMPLE CONDITION:
Chain-Of-Custody document(s) received with samples ........................
Sample container label(s) consistent with custody papers .....................
Sample container(s) intact and good condition ...................................
Correct containers for analyses requested ........................................
Proper preservation noted on sample label(s) .................................... ,. · __
VOA vial(s) free of headspace ....................................................
Tedlar bag(s) free of condensation ........................................................
COMMENTS:
Initial:
Not Applicable (N/A):
No N/A
~.~ 2"":',..~; ' '
Initial:
LAB:__.~(~'O'¢v~'g SHELL Chain Of Custody Record
Lab i
................. [, necessary): Shell Project Manager to bl invol'~d: il i~ ~ h~U~ {~N~¥:~ !ii
~~::~ :~:.:::~ :: ]~'~ ....................................................................... PAGE:
~ LOG ~DE: SITE ~ {Steer and C~y): OLO~ mO NO
Blalne~.Ess:Tech Se~lces, Inc. BTST 2401, Oak Street, Bakersfield Pending
20360 Gramercy Place Torrance, CA 90501-1511
PROJECT ~NTACT H~m ~ ~to~ Gretchen Tagavitla 626-256-6662
Nick Sudano ~. ~s)(~r .... gtagavilla~KHM 1 .com[~[~~ ~ ~ ~ [ ::
310'782-2465 310-782-2958 nsudan~blainetech.co~ g~
TURNAROUNDTIME (BUSINESS DAYS): " ~ ~ { :::{ ~ ~ ~ ~ ~ :~;~
0 DAYS ~. 5 DAYS ~ 72 HOU~ ~ 48 HOU~ ~ 2~ HOU~ LESS ~AN ~4 H~ REQUESTED ANALYSIS
~ ~- RW~Ca RE~ET FORHAT ~ U~ AGENt:.
GC/MS M~BE CONFIR~TION: HIGHEST HIGHEST pe~ ~OmN~ ~- A~L ~ ~ ~ FIELD NOTES:
SPECI~ INSTRUCTIONS OR NOTES: CHECK BOX IF EDD IS NO~ NEEDED ~ ~ ~
~ · ~ ContalneflPrese~atlve
~ ~ or PID Readings
~ ~ ~ ~ ~~ ~ m ~~ ~ ~ ~ ~ ~ ~ ~ ' ~ -- ~ ~ ~ ~ ~ ' ~ · ~ ~ . ~ ~ ~ ~ or Labora,o~ Notes
~0~ Field Sample Identification ~TmX ~ ~ ~ ~
~ ~ DATE TIME CONT. ~ ~ ~ ~ ~ ~
~:~:~:~:~; ,,
Rel~h~ b~ (~nalure) ' R~eiv~ b~ (Sl~~ ~ ~ ~ Da[~ ~ Time:
10/16/00 R evisk3n