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HomeMy WebLinkAboutMITIGATION (2) Environmental Consultants~ inc. Solving environment-related business problems worhtwide 91'1 South Primrose Avenue · Suite K Monrovia, Ca[iforrda 91016 USA 626.256.6662 ' 800.477.7411 Fax 626.256.6263 www. deltaer~v, com April 15, 2004 Project PA24010-1 CalLforrSa Re~onal Water Quality Control Board CentrM Valley Re, on 1685 B Street Fresno, California 93706-2020 ! I Re: FIRST QUARTER 2004 GROUNDWATER MONITORING REPORT Texaco Service Station 2401 Oak Street Bakersfield, California Dear/Viz. Whiting: On behalf of Eqnilon Enterprises LLC dba Shell 0/2 Products (SHELL), Delta Environmental Consultants, Inc. (DELTA) [formerly KI-IM Environmental Management, Inc. (KH2VD] has prepared th/s First Quarter 2004 Groundwater Monitoring Report for the above referenced site. This quarterly report represent DELTA'S professional opinions based upon the currently available/n_formation and are arrived at in accordance with currently acceptable professional standards. This report is based upon a specific scope of work requested by the client. The Contract between DELTA and its client outlines the scope of work, and only those tasks specifically author/zed by that contract or outlined/n this report were performed. This report is /ntended only for the use of DELTA's CLient and anyone else ~pecifically Listed on th/s report. DELTA will not ~md cannot be liabl-e for unauthorized reliance by any other th/rd party. Other than as contained in th/s para,apb, DELTA makes no express or implied warranty as to the contents of this report. If you have a~y questions regarding this site, please contact Brad Clark (DELTA) at (626) 256-6662 or ti TOnY Palagy/(SHELL) at~(425) 377-85)0. I De!t~ Enj~roumental Consultants, Inc.~ .E. C55425 /I Staff Geolo~st Senior Projec~ Engineer Attachment: First Quarter 2004 Groundwater Monitoring Report I cc: Tony Pata~yi, Shell 0/2 Products US Howard H. W~es I~, City of Bakersfield Fire Department  A membeT off II I I I I I I I I I I I I I I I I SHELL QUARTERLY STATUS REPORT April iS, 2004 Station Address: DELTA Project No. SHiELL Environmental Engin./Phone No.: DELTA Site Manager/Phone No.: Primary Agency/Regulatory ID No.: Other Agencies to Receive Copies: 2401 Oak Street, Bakersfield, California PA24010-1 Tony Palagyi/(425) 377-8530 Kathryn Ewing(626) 256-6662 Central Valley RWQCB / John Whiting. City of Bakersfield Fire Dept./t-Ioward H. Wines III WORK PERFORMED THIS QUARTER (ITIRST - 2004): 1. Quarterly groundwater monitoring and sampling. Submitted quarterly report. 2. Implemented no-pUrge sampling per CVRWQCB approval letter dated October 10, 2003. 3. Implemented approved site assessment activities per CVRWQCB approval letter dated October 21, 2003. 4.. Submitted "Site Assessment Report" dated February 20, 2004. WORK PROPOSED FOR NEXT QUARTER (SEcoND - 2004): 1. Quarterly groundwater monitoring and sampling. Submit quarterly report. Current Phase of Proj eot: Groundwater monitoring Frequency of Sampling: Quarterly Frequency of Monitoring: · Quarterly Is Separate Phase Hydrocarbon Present On-site (Well #'s): [] Yes [] No Cumulative SPH Recovered to Date: NA SPH Recov6red This Quarter: None Sensitive Receptor(s) and ReSPective Direction(s): Nearest field verified well is Well BK060-02 (State Well Current Remediation Techniques: Permits for Discharge: Approximate Depth to Groundwater: Groundwater Gradient Current Agency Correspondence: Summary of Unusual Activity: No. 29S/27E-25D02M) of the California Water Service Company in Bakersfield approximately 759 feet East of the site. None None 16.30' to 20.59' · . South-southeast (~ approximately 0.011 ft/ft cVRWQCB letter dated January 6, 2004.' None / I<lathrsm Ewing Site Manager (DELTA) ATTACI~F,D: · Table 1 - Historical Groundwater Gauging and Analytical Results · Table 2 - Additional Chemicals of Concern · Figure 1 - Site Location Map · Figure 2 - Groundwater Elevation Contour Map · Figure 3 - Hydrocarbon Distribution in Groundwater Map · Figure 4 - TPH-g Concentrations in Groundwater Map · Figure 5 - Benzene Concentrations in Groundwater Map · Figure 6 - MTBE Concentrations in Groundwater Map · Appendix A- Field Data Sheets · Appendix B - Field Procedures · Appendix C - Waste Disposal Document · Appendix D - Laboratory Report and Chain-of-Custody Documents I I I I I I I I I I I I I I I I I I TABLES m m mmm mm m m m mmm m m m m m m m m m m m HISTORICAL GROUNDWATER GAUGING AND ANALYTICAL DATA SHELL SERVICE STATION ._ 2~401 Oak Street, Ba___kersfield, California i:i:i~:~r~:i:i:i:i:~i:::: :~t~ :::: ~ ~;~: :}: ================================================================================================================= :::::::::~: :::::::::::::::::::::::::::::::::::::::::::::::: :::::::: :::::: :~:~:::::::~:~::::::RB~;:::::ff~¢i~i(~::::::::: :::~:~::: :::::::~:~::: :::::~:~:~:~:~::::::: :':: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :~:~:~:~:i~&~: :i:~:~: :(~i :?:: :~:::: :i~i:::: ~:::: ~: :::: ~¢~::: :::: :::: :: :~: :?: :: :::: :: MW-I Top of~asinj elevation~fO: 402.03 3/18/2003 26.81 0.00 375.22 3/~5/2003 28.19 0.00 373.84 ~<1000 ~<50 ~<0.50 ~<1.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ~<2.0 ND<2.0 ~<2.0 ~<10~ 6/18/2003 17.70 0.00 384.33 ~<50 ~<0.50 ND<I.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ND<2.0 ~<2.0 ~<2.0 9/3/2003 16.33 0.00 385.70 ND<50 ~<0.50 ~1,0 ND<I.0 ~<1.0 ~<1.0 ~<10 ~2.0 ~<2.0 ~2.0 ~<100 10/21/2003 21.6~ 0.00 380.40 ~<50 ~0.50 ND<I.0 ~<1.0 ND<I.0 ~<I.0 ~<10 ~<2.0 ~<2.0 ~<2.0 1/13/2004 17.6~ 0.00 384.43 ~<50 ~<0.50 ~<1.0 ~<1.0 ND<I.0 ~<1.0 ~10 ~<2.0 ~<2.0 ~<2.0 Pre-pprge sample 1/13/2004 ~<50 ~0.50 ~l.0 ~<1.0 ND<I.0 ~<1.0 ~<10 ~<2.0 ~<2.0 ~<2.0 Post-purge sample MW-2 Top of~asin~ elevation~t): 404.49 3/18/2003 29.70 0.00 374.79 3/25/2003. 31.02 0.00 373.47 ~<1000 660 ~<0.50 ~1.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ~<2.0 ~<2.0 ~2.0 ~<100 6/18/2003 20.79 0.00 383.70 ~<50 ~<0.50 ~<1.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ~<2.0 ~<2.0 ~<2.0 9/3/2003 19.31 0.00 385.18 ~<50 ~<0.50 ~<1.0 N~I.0 ~<1.0 ~<I.0 ~<10 ~<2,0 ~<2.0 N~2.0 N~100 10/21/2003 24.57 0.00 379.92 ~<50 ~D<0.50 ND<I.0 . ~<1.0 ~<1.0 ND<I.0 ~<10 ~<2.0 ~2.0 ND<2.0 ,~/13~004 20.59 ~ 0.00 383.90 ~<50 ~<0.50 ~<1.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ~<2.0 ~<2.0 ~<2.0 Pre-pur~esa~pl~ 1/13/2004 __ ~<50 ~0.50 ~<1.0 ~<1.0 ~1.0 ~<1.0 ~<10 ~2.0 ~<2.0 ~2.0 Post-purge sample MW-3 T~p of easing elevation (ft): 403.43 3/18/2003 28.94 0.00 374.49 3/25/2003 30.27 ~ 0.00 373.16 ND<1000 72 ~<0.50 ~<1.0 ~<1.0 ~<I.0 57 ~<10 ND<2.0 ~<2.0 ND<2.0 ND<100 6/18/2003 20.98 0.00 382.45 ND<50 ~0.50 ~<1.0 ~<1.0 ~<1.0 17 ND<I0 ~<2.0 ~<2.0 ~<2.0 9/3/2003 19.01 0.00 384.42 ~<50 ~<0.50 ~<1.0 ND<I.0 ~<1.0 ~1.0 ~<10 ~<2.0 ~<2.0 ~<2.0 ~<100 10/21/2003 23.89 0.00 379.54 ~50 ~<0.50 N~l.0 ND<I.0 ~<1.0 ~<1.0 ~<I0 ~<2.0 ND<2.0 ~<2.0 _j/13/2004 20.37 0.00 ~ 383.06 ~<50 ~0.50 ND<I.0 ~<1.0 ~<1.0 ~<I.0 ~<10 ~<2.0 ~<2.0 ~<2.0 Pre-purge sample~ 1/13/2004 ~<50 ~<0.50 ~<1.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ~2.0 ND<2.0 ~2.0 Post-purge sample MW-4 T~p of casing elevation (ft): 400.11 3/19/2003 25.42 0.00 374.69 3/25/2003 26.75 0.00 373.36 ~<1000 ~<50 ~0.50 ~<1.0 ND<I.0 ~1.0 7.3 ~<10 ND<2.0 ~<2.0 ~2.0 ND<100 6/18/2003 17.31 0.00 382.80 ~<50 ~0.50 ~1.0 ~<1.0 ND<I.0 ~<1.0 ~<10 ~2.0 ~<2.0 ~<2.0 9/3/2003 15.43 0.00 384.68 ~<50 ~0.50 ~<1.0 ~<1.0 ~<1.0 3.4 ~<I0 ~<2.0 ~<2.0 ND<2.0 ~<100 10/21/2003 20.34 0.00 379.77 ND<50 ~<0.50 ~<l.0 ~<I.0 ND<I.0 ~<1.0 ~<10 ~2.0 ND<2.0 ~<2.0 1/13/2004 16.77 0.00 383.34 ~<50 ~<0.50 ~<1.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ND<2.0 ~<2.0 ~<2.0 Pre-purge sample MW-5 _Top of casing elevation (ftC: 399.91 3/19/2003 25.03 0.00 374.88 3/25/2003 26.38 0.0O 373.53 ~<1000 ' ~<50 ND<0.50 ND<I.0 ~1.0 ND<I.0 40 ~<10 ~<2.0 ~<2.0 ND<2.0 ~<100 6/18/2003 16.72 0.00 383.19 ND<50 ~<0.50 ~<1.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ~<2.0 ~<2.0 ~<2.0 9/3/2003 15.28 0.00 384.63 ~<50 ~<0.50 ~<1.0 ~<1.0 ~<1.0 ~<1.0 ~<10 ~<2.0 ~<2.0 ~<2.0 ~<100 10/21/2003 19.89 0.00 380.02 ~<50 ~<0.50 ND<I.0 ND<I.0 ~<1.0 ~<1.0 ~10 ~<2.0 ND<2.0 ~<2.0 1/13/2004' 16.30 0.00 383.61 ~<50 ~<0.50 N~I.0 ~<1.0 ~<1.0 ~<1,0 ND<10 ~<2,0 ~<2.0 ~<2.0 Pre-purge sample Page I of 2 HISTORICAL GROUNDWATER GAUGING AND ANALYTICAL DATA SHELL SERVICE STATION I 2401 Oak Street, Bakersfield, California ii ip~i~ i i i i:~i:!:i:i:i:~a.':::: ~;~. ~ .~;i::: ~ :i:i:i:~'i~.'::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: GW - Groundwater S~H - Separate-phase hydroc~bons MSL - Mean sea level ND - Not detected u_~ -~an~per billion ~H-D - Total petroleum h~droc~bons ~ diesel TPH-G - Total petroleum hydrocarbons as gasoline using either EPA Method 8015M or ~e DHS L~T Method M~E - Me~yl-ten bu~ ether ~A - Te~-bu~l alcohol _ D~PE - Di-isopsopyl ether E~E - Ethyl-te~ bu~ e~er T~ - Te~-amyl methyl ether Su~ey dam provided by ~ Enviromenml M~agement, Inc. I I I I Page 2 of 2 TABLE 2~ L I ADDITIONAL CHEMICALS OF CONCERN TEXACO SERVICE STATION 2401 Oak Street, Bakersfield, California -- ~-- :::::::::::::::::::::::::::: ::2 {~i~::: (~i~::::;::::::::::: ~i~¢O~}:: 2~:: ~:~:.~i.~i~a).:.:.:.~.:.:.~.:.:.:.:.:.:~:.:.~.:.:.:.:.:.:.~.:.:.:.:.:.~.X.~.~.~. MW.1 9/3/2003~lO ND<0.10 0.42 17 NDe.50 50 50 ND<I.0 ND<I.0 ND<0.0 16.2 N~0.1 3.63 1.63 29.9 ND<0.005 240 66 6.21 150 1/13/200~ ~ 71 NA 1.0 N~ N~0.50 56 56 N~I.0 N~I.0 N~0.01 NA ~A 0.0128 2.72 33.2 NA 490 140 6.54 300 1/13~004 82 NA~ I.I NA ND<0.50 100 100 ND<I.0 N~I.0 ND<0.01 NA NA 0.0114 2.78 33.6 NA 490 140 6.55 290 MW-2 9B/2003 NA NA N~ NA NA NA NA NA ~ ~NA N~0.0 NA NA NA NA NA NA NA NA NA NA 1/13~004 NA NA NA NA NA NA NA NA NA ND<0.0[ NA NA NA NA ~ NA NA NA NA NA NA ~ple 1/13/2004 NA NA NA NA NA NA NA NA NA ND<0.01 NA NA NA NA NA NA NA NA NA NA P~l-pur~ ~ple ~-3 9/3/2~3 19 I~ 1.50 20 ND<0.50 56 56 ND<I.0 ~1.0 N~0.01 15.7 0.107 4.06 1.66 31.9 ND<0.005 230 74 6.23 130 1/13/2004 67 ] NA 0.54 NA ND<0,50 46 46 ND<I.0 ND<I.0 ND<0.01 NA NA ND<0.005 3.00 30.6 NA 440 120 6.72 260 P~-pu~ ~ple 1/13~0~MW472 ~NA 1.4 NA 0.63 60 ~ 60 N~I.0 ND<I.0 ND<0.01 NA NA 0.114 3.55 31.8/ NA 470 140 6.51 28~ 9/3/2003 19 0.95 22 0.56 66 66 N~I.0 ND<I.0 ND<0.01 16.7 0.6 4.14 1.~ 33.1, 0.0467 250 74 6,14 150 1/13~004 48 - NA I 0.65 NA 0,56 26 26 N~I~ N~I.0 N~0.01 N~ NA 0.0337 3.09 27.2} NA 350 98 6~6~ 210 __ MW-5 9/3~003 ~A NA NA NA N~ - NA NA NA NA N~0.01 NA NA NA NA NA NA NA N~ ~ N~ 1/13~004 ~NA ] NA NA NA NA NA NA NA NA N~0.01 NA NA _~A NA NA NA NA NA NA NA Not~: TKN - Total KjeIdahl Nitm~n ~ ~ TDS - Total Dissolved Solids NA - Not anal~ ~ NOTES: ~ Addlti~al Chemicals of Concern Anai~uring tho fi~~ for wells MW-I~W-3, and MW~. Tw~les were ~en on 1/13~0~ for wells MW-I, MW-2, and MW-3. ~e fi~t eo~s~nd to ~¢ p~-purge ~pl¢. Page 1 of I Fmcs i19'~04!00' W !Igz'0~00'' W !!9°02'00'' W WGS84 119°0I'00'' W 119°04'00" I DELTA I SHELL OIL PRODUCTS US ENVIRONMENTAL TEXACO SERVICE STATI'ON CONSULTANTS INC.I BAKERSFIELD, CALIFORNIA FIGURE 1 SITE LOCATION MAP 2401 OAK STREET BAKERSFIELD, CALIFORNIA I DEISEL TANK SLAB BOOTH MW-1 W LEGEND 384.40-- -- -- MW-1 ~ GROUNDWATER MONITORING WELL LOCATION ANDDESIGNATION (384.43) GROUNDWATERELEVATION IN FEET ABOVE MEAN SEA LEVEL (Ft/MSL) GROUNDWATER CONTOUR IN FEET ABOVE MEAN SEA LEVEL (Ft/MSL) CONTOUR INTERVAL=0.40 FEET ~III APPROXIMATE GROUNDWATER FLOW DIRECTION PLAN~R EXISTING SERVATION WELL SIGN / MW-2 (383.90 DISPENSER ISLAND (TYP) / (383.06 SLAB '~ /~" 1~) PLANTER 4) I 0 30 60 SCALE IN FEET ,Delta ENVIRONMENTAL CONSULTANTS INC. SHELL OIL PRODUCTS US TEXACO SERVfCE STATION BAKERSFIELD. CALIFORNIA FIGURE 2 GROUNDWATER ELEVATION CONTOUR MAP 01/13/04 2401 NORTH OAK STREET BAKERSFIELD, CALIEORNIA \\Server\khm_data\Clients~_Shefl%Shell Sites\Z\2401 Oak\2004-XX-X,X_I(~04 Quarterly Report\FIGURE 2(2401)_GROUNDWATER ELEVATION CONTOUR HAP.dwg, Hodel, 3/2212004 5:31:33 PM MW-1 DATE TPH-q BENZENE MT~E (~/L) (.ug/L) OJg/L) 03/25/0.3 ND<50 ND<O,50 ND<I,0 06/'iB/03 ND<50 ND<0.50 ND<I.0 09/05/05 ND<50 ND<0,50 ND<I.0 10/21/03 ND<50 ND<0.50 NO<I.0 1/13/04 ND<50 ND<O.50 ND<I,0 DEISEL TANK SLAB PLANTER MW-2 'MW-2 TRASH OFFICE AND R.R.- BOOTH DISPENSER '~. SLAB iSLAND (T'rP) 2~7;, "-' OBSERVATIONWELL 7 PLANTER MW-5 DATE ~H- BENZENE MTBE Cu~/~ O~/L) O-~/L) 05/25/05 ND<50 ND<0.50 40 06/18/03 ND<50 ND<O.50 ND<I.0 09/05/05 ND<50 ND<0.50 ND<I,0 1D/21/OSIND<50 ND<0.50 ND<I.0 1/15/04 ND<50 ND<0.50 ND<I.0 MW-4- DATE TPH-g BENZENE MTBE OD/L) (.ug/L) O~g./L) 05/25/05 ND<50 ND<0.50 06/18/05 ND(50 ND(0.50 ND<I.0 09/03/05 ND<50 ND<0.50 3.'3.4 10/21/05 ND(50 ND<0.50 ND<I.0 1/15/04 ND<50 ND<0.50 ND<I.O MW-5 LEGEND TPH-g MTBE ~ug/L ND< GROUNOWAI~R MONITORING WELL LOCATION AND DESIGNATION TOTAL PETROLEUM HYDROCARBONS AS GASOLINE METHYL TERT-BUTYL ETHER MICROGRAMS PER LITER NOT DETECTED ABOVE LIMIT NOTEO 0 20 60 I ~ SCALE IN FEET ADelta ENVIRONMENTAL CONSULTANTS INC. SHELL OiL PRODUCTS US TEXACO SERVICE STATION BAKERSFIELD', CALIFORNIA FIGURE 3 HYDROCARBON DISTRIBUTION IN GROUNDWATER MAP 2401 NORTH OAK STREET BAKERSFIELD, CALIFORNIA \\Server\khm_data\Clients~_Shell~_Shell Sites\2\240~ Oak\2004-x-xx_lQ04 Quarterly Report~FIGURE 3(2401)_HYDROCARBON DISTP,]BUT~ON IN GW MAP.dw9, M~del, 2/g/2004 t0:3t:qB AM TRASH - N S OFFICE AND ~ MW-1 DEISELTANKsLAEi CANOPY LEGEND ~ MW-14~- GROUNDWATER MONITORING WELL LLI LOCATION AND DESIGNATION ~_ ND<50 TPH-g CONCENTRATIONS IN CD MICROGRAMS PER LITER C.ucj/L) x<,' TPH-g TOTAL PETROLEUM HYDROCARBONS ~ AS GASOLINE 0 ND<: NOT DETECTEO ABOVE LIMIT NOTED PLANTER ND<50 ~ EXISTli~ "'""-.,...~ER VA TI 0 N WELL OISPENSER ISLAND (TYP) PLANTER SLAB 0 30 60 SCALE IN FEET Delta ENVIRONMENTAL CONSULTANTS INC. SHELL OIL PRODUCTS US TEXACO SERVICE STATION BAKERSFIELD, CALIFORNIA FIGURE 4 TPH-g CONCENTRATIONS IN GROUNDWATER MAP 01/13/04 2401 NORTH OAK STREET BAKERSFIELD, CALIFORNIA \\Server\khm_data\Clients~.Shell~_Shell Sites\2\2401 Oak\2004-XX-XXjQ04 Quarterly Report\FIGURE 4(2401)_TPH-g CONCEi~m~,AT]ON HAP.dwg, Model, 3/22/2004 5:32:36 PM TRASH SLAB OFFICE AND :ANOPY LEGEND N -S MW-I~ GROUNDWATER MONITORING WELL LOCATION AN[3 DESIGNATION ND<0,50 BENZENE CONCENTRATIONS IN MICROGRAMS PER LITER (~/L) ND< NOT DETECTED ABOVE LIMIT NOTED PLANTER MW-2 EXISTING  ERVATION WELL "~ SIGN OIS~ ISLAND (TY~) SLAB PLANTER 30 60 , SCALE IN FEET ADelta ENVIRONMENTAL CONSULTANTS INC. SHELL OiL PRODUCTS US TEXACO SERVICE STATION BAKERSFIELD, CALIFORNIA FIGURE 5 BENZENE CONCENTRATIONS IN GROUNDWATER MAP 2401 NORTH OAK STREET BAKERSFIELD, CALIFORNIA \\Server\khm_data\Clients~_Shell~_Shell Sites\2\2401 Oak\2004-x-xx_lQ04 Quarterly Report\FiGURE 5(240~,)_BENZENE CONCENTRATION MAP,dwg, Model, 2/5/2004 10:53:27 AH TRASH - DEISEL TANK SLAB ~ OFFICE AND MW- 1 LEGEND N ~ MW-1 ~ GROUNDWATER MONITORING WELL LLI LOCATION AND DESIGNATION ILl ND<I.O MTBE CONCENTRATIONS r~ IN MICROGRAMS PER LITER cn Cra/L) x~ MTBE METHYL TERT-BUTYL <3~ ETHER o ND< NOT DETECTED ABOVE LIMIT NOTED ~NOPY PLANTER MW-2 NP<.1,0 EXISTING '~.~ERVATION WELL DISPENSER ISLAND (T~) MW-3 SLAB '~ PLANTER 0 30 60 SCALE IN FEET .Delta ENVIRONMENTAL CONSULTANTS INC. SHELL OIL PRODUCTS US TEXACO SERVICE STAtiON BAKERSFIELD, CALIFORNIA FIGURE 6 MTBE CONCENTRATIONS IN GROUNDWATER MAP ol/~ 3/04 2401 NORTH OAK STREET BAKERSFIELD, CALIFORNIA \\Server\khm_data\Clients~_Shell~_Shell Sites\2\2401 Oak\2004-x-xx_lQ04 Quarterly Relx~t~c]GURE 6(2401)_MTBE ]SOCONCENTRATJON MAP,dwg, Model, 2/5/2004 10:53:46 AM AP?ENmX A FIELD DATA SHEETS WELLHEAD INSPECTION CHECKLIST P~ge , or, Client~ 5k,~ t~. . Date I - ~- -too,~ Site Address .3 ~ o~ ~- t ¢~ ~ ~$ ~' e~~~ Job Number o~o~ ~- nician ~. ~~. Well Inspected - No Corrective Well ID A:Uon Required Other AcUon Water Bailed We~lbox Cap Lock Taken From Components Replaced Replaced (explain Wellbox ' .Cleaned ,,. below) Well Nol [nspecf~d (explain Submitted INOTES: eLAINE TECH SERVICES, IHC. SAN JOSE SACR,rd,4ENTO LOS ANGELES SAN DIEGO Site 3 ~q o I o_,~ ~¢ ~+, WELL GAUGING DATA Date Well ID Size (in.) I Sheen / Odor Depth to hnmiscible Liquid (ft.) Ttfickmess of Immiscible Liquid (ft.) Volume of Immiscibles Removed [Depth to water (mO ZO Depth to welt bottom (ft.) Survey [ P oLut: TOB lC,. Blaine Tech Services~ Inc. 1680 Rogers Ave. San Jose, CA 951'12 (408) 573-0555 WELL MONITORING DATA Well I.D.: ~. I We5 Dimeter: 2 3 ~ 6 8 TotM Well Dep~ (TD): q a. o~ Dep~ to Water ~T~: ~ ~. a o Depth to Free Product: ~clmess of Free Product (fee0: Referenced to: ~ O~d~ D.O. Meter (ffreq'd): vs~ ~c~ DTW with 80% Recharge [(Height of Water Cohmn'x 0.20) + DTW]: Purge Method: Bailer · Waterra Disposable Bailer Peristaltic Positive Air Displacement Extraction Pump Electric Submersfble ~ Other Sampling Method: Other:. Bailer Disposable Bailer Extraction Port Dedicated Tubing Well Diamete~ l{Jultiulier Well Diameter Multlalier 1" 0.04 4" -- (Gals.) X ' - = - Gals. ~ 2" 0.16 6" 1.47 I ] Case Volume Specified Volumes Calculated Volume 3" 037 Other mflius2 * 0.16'1 Cond. Turbidity Time Temp (°F) pH (mS or¢[i~;~ (NTUs) Gals. Removed Observations Bailer lowered. "~. ' below DTW to obtotn sample Did well dewater? Yes cl~ Gallons actually evacuated: -- Sampling Date: t. I S. zooq .. Sampling Tkne: totf Depth to Water: ,-,. ~,o Sample I.D.: ~..~. 1 Laboratory: ~ Columbia Other EB I.D. (if applicable): @ -a~, Duplicate I.D. (if applicable): Analyzed for: TPH-G BTEX MTBE TPI-I-D Oxygenates(5) Other: D.O. (ifreq'd): Pre-purge: ma/[ Post-purge: me/[ O.R.P. (if req'd): Pre-purge: mV Post-purge: mV Blaine Tech Services, Inc. 1680 Rogers Ave., San Jose, CA 95112 (800) 545-7558 Screened Interval: IO ' S O Il'well is listed as a no-purge, confirm that water level is below the top of screen. Otherwise, the well must be purged. Sampler: Well I.D.: ,,,,a- ~ Well Diameter: 2 3 d~ 6 8 Total Well Depth (TD): ,~ q .o~, Depth to Water (DTW): t-~. ~,o Depth to Free Product: Thickness of Free Product (feet): Referenced to: ~ arade D.O. Meter (if req'd): vs~ DTW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: Purge Method: Bailer Waterra Sampling Method: Bailer Disposable Bailer Peristaltic ~¢Disposabl~ Bailer Positive Air Displacement Extraction Pump Extraction Port ~Eleclric Submersible Other Dedicated Tubing Other: Screened Interval: ~ot. $ o' Il'well is listed as a no-purge, confirm that water level is below the-top of screen. Otherwise, the well must be Eurged. ~ell Di~mete/" /~uJtiplier" Well Diameter MultiPlier to.,4 (Gals.) X ~ -- &l.~ Gala. 2" 0.t6 6" 1.47 [ 1 C~e yolu~e Spe~fied Volumes CMeulated Volume y' 037 Omer mdi~~ * 0.163 dond. T~bi~ T~xe Temp (°F) I pH (mS or ~) ~s) GMs. Removed Obse~afions  Balier low.ed ~ ' below ~DTW to ubtain sample Did well dewater? Yes ~ Gallons actually evacuated: ~. g S~pling Date: I. ~a. o H .. Smpl~g T~e: -ti q ~ Depth to Water: ~ a. ~ S~ple I.D.: ~ _ ~ Laboratm~: ~ Columbia Other EB I.D. (if applicable): ~ T~,. Duplicate I.D. (if applicable): ~alyzed for: TPH-G B~X MTBE TPH-D Oxygenates (5) Oilier: mgl , D.O. (ifreq'd): Pre-p~ge: 'Li Post-p~ge: ma/L O.R.P. (ifreq'd): Pre-p~ge: mV Post-purge: mV Blaine Tech Services~ Inc. 1680 Rogers Ave., San Jose~ CA 95~'i2 (800)545-7558 WELL MONITORING DATA ~,.cIEET BTS #: o ,a o,, 'a - s ~4. 2.. Site: q .~ ,4 -~, ~-'+o Well I.D.' Total Well Depth (TD): ~ q. ~ ~. Depth to Free Product: Referenced to: ~ Grade Date: , _ ,-~ ~ ~ oo .q Well Diameter: 2 3 ¢I> 6 8 Depth to Water (DTW): ,_ o, s ,~ i Thiclmess of Free Product (feet): D.O. Meter (if req'd): YSI HACH DTW with 80% Recharge [(Height of Water Columnx 0.20) + DTW]: Purge Method: Bailer Waterra Sampling Method: Bailer . Disposable Bailer Peristalt/c ~ Disposable Bailer Positive Air Displacement Extract/on Pump Extraction Port Electric Submersible ~.Other Oe~,-~,~ DedicatedTuhing · Other: Screened Interval: tO' - s o · IfweI1 is listed as a no-purge, confirm that water level is below the..tbp of screen. Otherwise, the well must be purged. Well Blame[er' '"~'ultiplier Well Diameter Multiplier 1" 0.04 4" 0.65 -- (Gals.) X ~ = - Gals. z'. 0.16 6' I Case Volume Specified Volumes Calculated Volume z" o.37 Other rad[u~' · o.~63 Cond. Turbidity Time Temp (°F) pH (mS or ffe~ (NTUs) Gals. Removed Observations Bailer low,w~d "~ ' b~low IDT$¥ to obtain ~ample Did well dewater? Yes ~ Gallons actually evacuated: ~ Sampling Date: ~. c~. o q Sampling Thne: Io-~o Depth to Water: Sample I.D.: ~,,,. ~. ~ Laboratory: .~e Columbia Other Analyzed for: ~ ~-. Mrna TV~-D ~enat~($). ~ ;,, S'o~.,~ EB I.D. (if applicable): ~.,. Duplicate I.D. (if applicable): Analyzed for: TPH-G BTEX IvlTBE TPH-D Oxygenates (5) Other: D.O. (ifreq'd): Pre-purge: ms/t. Post-purge: rog/L O.R.P. (if req'd): Pre-purge: mVI Post-purge: reV' Blaine Tech Services, Inc. 1680 Rogers Ave., San Jose, CA 95112 (800) 545-7558 SH:EL= WELL MONITORING DATA ~rlEET ,BTS #: o,~ o, ,~-.~4- Sampler: IDate: ,- ,-s- Well I.D.: m,,s - ~. Well Diameter: 2 3 · 6 Total Well Depth (TD): u ~t. 5', Depth to Water (DTW): 'z o. ~ q Depth to Free Product: Thiclmess of Free Product (feet): Referenced to: ~ a~de D.O. Meter (ff req'd): YS~ DTW with 80% Recharge [(Height of Water Colurrm x 0.20) + DTW-]: > ~,. :~ ~ Purge Method: Bailer Waterra Sampling Meflmd: Bailer Disposable Bailer Peristaltic ~Disposable Bailer Positive Air Displacement Extraction Pump Extraction Port ~-Etectric Submersible Other Dedicated Tubing Other: Screened Interval: to'- $o ' If well is listed as a no-purge, con_firm that water level is below the.t'op of screen. Otherwise, the well must be purged. we .Diamete~ l~'uldplier Well Diameter Multlnlier ~" 0.04 4- 0.~ .!. Case Volume Specified Volumes Calculated Volume Y' 0.37 Olher radias~ * 0.163 Cond. Turbidity Time Temp (°F) pH (mS o~ (NTUs) Gals. Removed Observations Bailer lowered "~ ' below DTW to obtain sample Did well dewater? Yes d~ Gallons actually evacuated: Sampling Date: I' ~'~- o q Sampling Time: ~'z ~ o Depth to Water: Sample I.D.: ~. a- Laboratory: ~e Columbia Other Analyzed for: ~~ ~rm~ 'rP}? $,,, r~.~... EB I.D. (if applicable): @ ,~ Duplicate I.D. (if applicable): Analyzed for: TPH-G BTEX MTBE TPH-D Oxygenates (5) Other: D.O. (ifreq'd): Pre-purge: m~/~ Post-purge: O.R.P. (ifreq'd): Pre-purge: Il:tV Post-purge: mx/. Blaine Tech Services, inc. 1680 Rogers Ave., San Jose, CA 95112 (800) 545-7558 I r ...... MONITORING' ~ SFI~L~ WELL DAT ,,d:EET Sampler: .,c,_,,,~ /4 -- ~. .,.,,-,, Date: ~_ ,.~. ~oo,~ 8 Well I.D. Total Well Depth (TD): ,j ~. ~..-+ Depth to Free Product: Referenced to: ~ Grade Well Diameter: 2 3 t'~ 6 Depth to Water (DTW): -/~>.-~-+ Thickness of Free Product (feet): D.a. Meter (if req'd): YSI HACH i.DTW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: Purge Method: Bailer Waterra Sampling Method: Bailer Disposable Bailer Peristaltic ~Disposable Bailer Positive Air Displacement Extraction Pump Extract/on Port Electric Submersible ~Other ta~-~-{~ Dedicated Tubing Other: Screened Interval: ~o' -' ~o~ If well is listed as a no-Purge, confirm fl~at water level is below the..t'op of screen. Otherwise, the well must be purged. I ~w. eil Diamem~ Multiplier Well Diam'et~r Multiplier ' I" 0.04 4" 0.65 ~ (Gals.) X. "-- = ~ Gals. 2" 0.16 6" 1.47 1 Case Volume Specified Volumes Calculated Volume 3" 0.37 Other radius~ * 0.163 Cond- Turbidity Time Temp (°F) pH (mS or~l:l~ (NTUs) Gals. Removed Observations Bailer lowered '~- ' below DTW to obtain sample' Did well dewater? Yes ~ Gallons actually evacuated: ~ Sampling. Date: t- ~'l..: o,~ Samplh~g Time: tav~- Depth to Water: Smnple I.D.: ~,,.~- :3 Laboratory: ~ Columbia Other ga~alyzed for: ('?Y~ 6~ MT~. TPn-D ~~: g~, BB I.D. (if applicable): @ T~= Duplicate I.D. (if applicable): Analyzed for: TPI-t-G BTEX MTBE TPH-D Oxygenates(5) Other: D.a. (ifreq'd): Pre-purge: m/L Post-purge: m~/L O.R.P. (ifreq'd): Pre-pt'ge: mV Post-purge: mV Blaine Tech Services, Inc. 1680 Rogers Ave., San Jose, CA 95~12 (800) 545-7558 I BTS #: o ,q o ~, -~ - SHEL~ 'WELL MONITORING DATA ,.,I-IEET Sampler: Date: ,_,~. ~oo~ Well I.D.: t,-,,.~.- '~ Well Diameter: 2 3 icj> 6 8 Total Well Depth (TD): 't q .3 } Depth to Water (DTW): -, o. -~-~ De~to Free Product: Thickness of Free Product (feet): ~Refere~ce-'~o."-~ qa~:. etude D.O. Meter (ifreq'd): ys~ ~L~C~ !IDTW with 80% Recharge [~-Ieight of Water Column x 0.20) + DTW]: a ~,. ,~ Purge Method: Bailer Waterra Sampling Method: Bailer Disposable Bailer Peristaltic ~Disposable Bailer Positive Air Displacement Extraction Pump Extraction Port ~Electric Submersible Other Dedicated Tubing Othen Screened Interval: to ' - ~o' IfweI1 is Iisted as a no-purge, confirm that water level is below the...t'op of screen. Otherwise, tl~e well must be purged. (Well Diaraeter Mu [ip ie'r Well Diameter . Multiplier 1" 0.04 4" tP.9 (Gals.)X ~ = ~ ~. ,.~ Gals. 2" 036 ¢' 1.47 I Cas.~ Volum..e . Specified Volumes Calculated Volume _v, 037 Other radlus~ * 0.1~3 Cond.' Turbidity Time Temp (°F) pH (mS or~"~) (NTUs) Gals. Removed Observations Bailer lowered ~[ ' below DTW tn nhtuln rumple Did well dewater? Yes ~l~ GaIlons actually evacuated: SamptingDate: ~.~-~.oq SmnplingTime: ~.~:,- Depth to Water: Sample I.D.: t~,,-, - '~ Laboratory: ~ce Columbia Other EB I.D. (ifapplicabIe): @ T~..~ Duplicate I.D. (ifapplicable): Analyzed for: TPH-G BTEX MTBE TPH-D Oxygenates(5) Other: D.O. (if req'd): Pre-purge: m§/L Post_purge: m§/L O.R.P. (ifreq'd): Pre-purge: rnV Post-purge: mV 'I Blaine Tech Services, inc. 1680 Rogers Ave., San Jose, CA 951ff2 (800) 545-7558 WELL MONITORING DATA orIEET BTS#: o~o,,-~- s~4- ~_ Site: ~.~, -}l -~-~.o S~pler: S~,, ~ ~ ~ Date: ,_ ,~_ ~ Well I.D.' ~. w Well Dimeter: 2 3 ~ 6 8 Total Well Dep~ (TD): u~. ~ Dep~ to Water ~TW): i ¢.~ ~ Depfl~ to Free Product: ~iclmess of Free Product (feet): Referenced to: ~ ~d~ D.O. Meter (ifreq'd): YsI ~CH DTW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: Purge Method: Bailer Waterra Sampling Method: Bailer Disposable Bailer Peristaltic ~-Disposable Bailer~gl~ Positive Air Displacement Extraction Pump Extraction Port Electric Submersible ,~ Other ~--.~ Dedicated Tubing Other: Screened Interval: to' o ~ o ' If well is listed as a no-purge, confirm that water level is below the..t'op of screen. Otherwise, the welI must be purged. W~'ti'Diamete~ M'ultiplier Well Diameter Multipiler ~ I" 0.04 4" 0.§5 ~ (Gals.) X = -- Gals. 2" 0.16 6" 1.47 1 Case Volume Specified Volumes Calculated Volume 3" 0.37 Other radius2 * 0.163 Cond. Turbidity Time Temp (°F) pH (mS or ~ ('NTUs) Gals. Removed Observations Bailerlowered '~ 'belm¥ 'DTW to 0btaia sample Did well dewater? Yes ~ Gallons actually evacuated: Star, piing Date: ~.~$.0,4 SamptingT/me: tt ~S" Depfl~to Water: Smnple I.D.: ,..~,..., Laboratory: C¢~ii~ Columbia Other EB I.D. (if applicable): @ ,~ Duplicate I.D. (if applicable): gmalyzed for: TPH-G BTEX MTBE 'TPH-D Oxygenates (5) Other: D.O. (if req'd): Pre-purge: mg/L Post-purge: O.R.P. (/freq'd): Pre-purge: mV Post-purge: mM Blaine Tech Services~ Inc. 1680 Rogers Ave. San Jose, CA 951~2 (800) 545-7558 SIiE~',,~ W~ELL MONITORING DATA Date: Well I.D.' ,,,,,,.,. r Well Dimneter: 2 3 ~D 6 Total Well Depth (TD): ~'l-~t~ Depth to Water (DTW): f G. '~ o Depth to Free Product: i Thiclcrtess of Free Product(feet): Referenced to: ~ Grade D.O. Meter (if req'd): YS~ DTW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: Purge Method: Bailer Waterra Sampling Method: Bailer Disposable Bailer Peristalt/c ~:Disposable Bailer Positive Air Displacement Extraction Pump Extraction Port Electric Submersible ~ Other t.~r~l~ ~ Dedicated Tubing Other: Screened Interval: t o' - ~ ~' If well is listed as a no-purge, confirm that water level is below the..t'op of screen. Otherwise, the well must be purged. Well Diamete~ l~a, llipl!er Well Diameter,, Multiplier 1" 0.04 4" 0.65 ~. Case Volume Specified Volumes Calculated Volume y' 0.ay O~er ~di~~ * 0.1 ~3 Cond. T~bi~W T~e Temp (°F) pH (mS or ~ ~s) Gals. Removed Obse~afions Bgller lowered ~ ~ below DT~ to o~taln snmple Did wol] dewater? Yes ~ Gallo~s ac~a~y evacuated: ~ Sampl~g Date: ~.~3. os Smnp~g T~e: f~o Dep~ to Water: fG. ~o S~ple I.D.: ~. ~ Laborato~: ~e Colmbia 'EB I.D. (if applicable): '~ ~ Duplicate I.D. (if applicable) : '~lalyzedfo?: TPH-G BTEX MTBE TPH-D Oxygenates(5) Oilier: D.O. (if req'd): Pre-purge: ~/~' Post.pmge: ~/~ O.R.P. (if req'd): Pre-pmge: mV ?ost-pmge: mV I Blaine Tech Services, inc. 1680 Rogers Ave., San Jose, CA 95112 (800) 545-7558 FIELD PROCEDURES I BLAINE TECH SERVICES,.~ 1680 ROGERS AVENUE SAN JOSE, CA 95112.-1105 (408) 573-7771 FAX (408) 573-0555 PHONE CONTRACTOR'S LICENSE #746684 www. blainetech.com January 29, 2003 Tony Palagyi Shell Oil Products US P.O. Box 7869 Burbank, CA 91510-7869 Fkst Quarter 2004 Groundwater Monitoring at Shell-branded Service Station 2401 Oak Street Bakersfield, CA Monitoring performed on January 13, 2004 I I I I ! I I Groundwater Monitoring Report 040113-SH-2 This report covers the routine monitoring of grotmdwater wells at this Shell-branded facility. In accordance with standard procedures that conform to Regional Water Quality Control Board requirements, routine field data collection includes depth to water, total well depth, thickness of any separate immiscible layer, water column volume, calculated purge volume (if applicable), elapsed evacuation time (if applicable), total volume of water removed (if applicable), and standard water parameter instrument readings. Sample material is collected, contained, stored, and transported to the laboratoryin conformance with EPA standards. Purgewater (if applicable) is, likewise, collected and transported to D.K. Environmental. Basic field' infonnation is presented alongside analytical values excerpted from the laboratory report in the cumulative table of WELL CONCENTRATIONS. The fidl analytical report for the most recent samples and the field data sheets are attached to tiffs report. At a minimum, Blaine Tech Services, Inc. field personnel are certified on completion of a forty- hour Hazardous Materials and Emergency Response trai~xing course per 29 CFR 1910.120. Field personnel are also enrolled in annual eight-horn' refresher courses. Blaine Tech Services, Inc. conducts sampling and docmuentation assi~m~ents of this type as an' h~dependent tl~ird party. Our activities at this site consisted of objective data and sample collection only. No interpretation of analytical results, defining of hydrological conditions or formulation ofrecormuendations was performed Please call if you have any questions. Yours truly, Francis Thie Vice President FT/ks attachments: Cumulative Table of WELL CONCENTRATIONS Certified Analytical Report Field Data Sheets CC: Kathryn Ewing Delta Environmental Consultmats, Inc. 911 S. Primrose Ave., Suite K Monrovia, CA 91016 BLAINE TECH SERVICES, INC. METHODS AND PROCEBURES FOR THE ROUTINE MONITORING OP · GROUNDWATER WELLS AT SHELL SITES Blaine TeCh Services, Inc. performs environmental sampling and documentation as'an independent third party. We specialize in groundwater monitoring assignment, s and intentionally limit the scope of our services to those Centered on the generation of objective information.. To avoid conflicts of interest, Blaine Tech Services, Inc. personnel do not evaluate or interpret the information we collect. As a state licensed contractor (C-57 well drilling -water- 746684 ) performing strictly technical services, we do nOt make any professional recommendations and perform no consulting of any kind. 'SAMPLING PROCEDURES OVERVIEW SAFETY' All groUndwater monitoring assignments performed for Shell comply with Shell's safety guidelir!es,.29 CFR 1910.120 and SB-198 Injury arid Illness PreventiOn I~rogram (IIPP). All Field Technicians receive, the full 40-hour 29CFR 1910.120 OSHA SARA 'HAZWOPER course, medical clearance and on-the-job training prior to commencing any work on any Shell site. INSPECTION AND GAUGING Wells are inspected prior to evacuation and sampling. The condition of the wellhead is checked and noted according to a wellhead i ..nspection checklist. Standard !measurements include the depth to water (DTW) and the total well depth (TD) obtained with industry standard electronic water level indicators that are graduated in inbrements of.hundredths of a foot. The water in each well is inspected for the presence of immiscibleS. When free product is suspected,' its presence is confirmed rising an eleCtronic interface probe (e.g. MMC). No samples are collected from a Well containing over two-hundredths'of a foot (0.02')of product. EVACUATI ON Depth to water measurements are collecte~l by our personnel prior to purging and minimum purge volumes are calculated anew for each well based on the height of the water column and the diameter of the well. Expected purge volumes are never less than three case :volumes and are set at no less than four case volumes in some jurisdictions. Blaine Tech Services, Inc. Standard Methods & Procedures Shell Oil Products'US Page 1 I I I I I I I I ! I I I I I. i I I I I Well purging, devices are selected on the basis of the well diameter.and the total volume to be evacuated. 'In most cases the well will be purged using an electric submersible pump (i.e. · Grundfos) suspended near (but not touching) the bottom of the well. RARAM ETER STAB I LIZATION Well purging completion standards include minimum purge volumes, but additionally require stabilization of specific groundwater parameters prior to sample collection. TypiCal groundWater parameters used to measure stability are electrical conductivity, pH, and temperature. Instrument readings are obtained at regular intervals during the evacuation process (no less thar) once per case volume). Stabilization standards for routine' quarterly monitoring of fuel sites include the following: Temperature is considered to have stabilized when successive readings do not fluctuate more than +/- 1 degree Celsius. Electrical conduotivitY is considered stable when suc(~essive readings are within 10%. pH is considered to be stable when successive readings remain Constant or vary no more than 0.2 of a pH unit. DEWATERED WELLS Normal evacuation removes no less than three Case volumes of water from the well. However, less water may be remOVed.in cases where the well dewaters and does not immediately rech'arge. MEASURING RECHARGE Upon completion of well purging, a depth to water measurement is collected and notated to ensure that the well has recharged to within 80% of its static, pre-purge level Prior to sampling. Wells that dO not immediately show 80% recharge or dewatered wells will be alloWed minimum of 2 hours to recharge prior to sampling. The water level at time of sampling will be nOted. PURGEWATER CONTAINMENT All non-hazardous purgewater evacuated from each groundwater monitoring well is'captured and contained in on-board Storage tanks on the Sampling Vehicle and/or special water hauling trailers. Effluent from the decontamination of reusable apparatus (sounders, electric pUmps and hoses etc.), cOnsiSting of groundwater combined with deionized water and non-phosphate soap, is also captured and pumped into effluent tanks. Non-hazardous purgewater is transported under standard Bill of Lading documentation to a Blaine Tech Services, Inc. facility before being transported to a Shell approved disposal facility. Blaine Tech Services, Inc. Standard Methods & Procedures Shell Oil Products US Page 2 SAMPLE COLLECTION DEVICES All samples are collected using a stainless steel, Teflon or disposable bailers. SAMPLE CONTAINERs Sample material' is decanted directly from the sampling bailer into sample containers provided by the laboratory that will analyze the samples. The transfer of sample material from the bailer to the Sample container Conforms to specifications contained in the USEPA T.E.G.D. The type of sample container, material of construction, method of closure and filling requirements are specific to the intended analysis. Chemicals needed to preserve the samPle material are commonly placed inside the sample containers by the laboratory or glassware vendor prior to deliVery of the bottle to our personnel. The laboratory sets the number of re'plicate containers. TRIP BLANKS Trip Blanks', if requested, are taken to the site and kept inside the sample cooler for the duration of the event. They are turned over to the laboratory for analysis with the samples from that site. DUPLICATES Duplicates, if reqUested, may be collected at a site. The Field Technician uses their discretion in chooSing the well at which the Duplicate is collected, typically one suspected of containing measurable contaminants.' The Duplicate sample is labeled "DUP" and the time of collection is omitted from the COC, thus rendering the sample blind. SAMPLE STORAGE' All sample containers are promptly placed in food grade ice chests for storage in the. field and transport (direct or via our facility)'to, the designated analytical laboratory. TheSe ice chests contain'quantities of restaurant grade ice as a refrigerant material. The samples are maintained in either an ice .chest or a refrigerator until relinquished into the custody of the laboratory Or laboratory courier. , DOCUMENTATION CONVENTIONS A label must be affixed to all sample containers. In most cases these labels are generated by our office personnel and are partially preprinted. Labels can also be hand written by. our field personnel. The site is identified wi[h the store number and site address, as is the particular groUndwater well from which the sample is drawn (e.g. MW-l, MW-2, S-1 etc.). The time and date of sample collection along with the initials of the person who collects the sample are handwritten onto the label. Chain of Custody records are created using client specific preprinted forms following USEPA specifications. Blaine Tectt Services, Inc. Standard Methods & Procedures Shell Oil Products US Page 3 Bill of Lading records are contemporaneous records created in the field at the site whe~-e the non-hazardous purgewater is ganerated. Field Technicians use preprinted Bill of Lading.forms. DECONTAMINATION All equipment is brought to the site in clean and serviceable condition and is cleaned after use in each well and before subsequent use in any other well. Equipment is decontaminated before leaving the site. The primary decontamination device is a commercial steam cleaner. The steam cleaner is de- tuned to function as a hot pressure washer that is then Operated with high quality deionized water that is produced at our facility and stored onboard our sampling vehicle. Cleaning is facilitated by the use of proprietary fixtures and devices included inthe patented workstation (U.S. Patent 5,535,775) that is ncorporated in each sampling vehicle. The steam cleaner is used to decon reels, pumps and bailers. Any Sensitive equipment or pads (i.e. Dissolved Oxygen sensor membrane,, water level · indicator etc.) that cannot be washed using the high pressure water, will be sprayed with a non- phosphate soap and deionized water solution and rinsed with deionized water.. DISSOLVED oXYGEN READINGS Dissolved Oxygen readings are taken pre- and/or post-purge using YSI meters (e.g. YSi Model 54, 58 or 95) or HACH field test kits. The YSI meters are equipped with a stirring device that enables them to collect accurate in-situ readings. The probe/stirring devices are modified to allow downho!e measUrements to be taken from Wells with diameters as Smail as two inches. The probe and reel is decontaminated between wells as described above. The meter is calibrated between wells as per the instructions in the operating manual. The probe and stirrer is lowered into the water Column. · The reading is. allowed t° stabilize prior to collection'. OXYIDATON REDUCTION POTENTIAL READINGS All readings are obtained with either Corning Or Myron-L meters (e.g. Corning ORP-65 or a MyromL Ultrameter GP)..The meter is cleaned between wells as described above. The meter is calibrated at the start of each day'according to the instruction manual. FERROUS-IRON MEASUREMENTS All field measurements are collected at time of sampling With a HACH test kit. Blaine Tech Services, Inc. Standard Methods & Procedures Shell Oil Products US Page 4 DISPOSAL DOCUMENT NON-HAZARDOUS WASTE DATA FORM GI~NI:;RA-r~N G ~I'E'- WIC~ z.,.{ol SHELL OIL PRODUC'I-~ US s'~,-¢¢,~(~, cPr NAME P.O. BOX 71969 ADDRESS BURBANKr CA 91510-786c~ PHONE NO: ( ) CONTAINERS: ~o. , VOLUME ~ ~'o ?~-t' , WaeHm TANK DUMP TYPE:- Tt~UCK []mUQK [] O,UUS NON-HAZARDOUS GROUNDWATER WAbblE DESCRIPTION, co~apot, m,'~'rs o]= WASTS PPM 99-~O%:!.O WATER 1 TPH [] CARTONS [] OTHEP, PURGED GRouFJ DWATER ZNCI'DENT# q BE'SI 4. 7-10' PROPERTIES: oH__ [] HANDLING INSTRUCTIONS: XX ~' SOLID [] UOUIO [] SLUpOE [] SLURRY [] OTHER 24-HOUR EMERGENCY PHONE (1~00) 424-9300 JTH~ GENERATOR CERTIFIES'THAT THE J WASTE .AS DESCRIBED IS 100~ · NON-HAZARDOUS. NAME, ADDRF--.~S. BREA, CAITFORNZA 92821 OITY, ~TA'TE. ZIP.., (714) 990~eB55 PHONE NO,. , TYPED OR PRI~ ~LL NAME & SIGNA~RE DA~ EPA~' '" '"" ..... ~O ~D SONS TRUC~NG, INC. ~.~, NO. I 1281 BR~ ~YON'ROAD I FIRST~~E !1 --a[ml~ ~ , _, ~ ..... _ ;~' u ~ER~'~E.ORDER NO. - I 20 0 (310) 782-2~5 TRUOK, UNIT I.D, NO. TYPED OR PRINTED FULL NAME & SII~NATURE NAM~ DATE D~fK Er~/IRON I~ F__~TAL ~.a, 3630 E, 26TM STREET ADDRESS LOS ANGELEs, CA 510023 CITY, ~'trATE, ZIP (3231 2~-5o56 PHONE NO .DIGPO~AL.b-rHOD [] LANDFILL [] OTHER m TYPED OR PRINTED FULL NAME & SIGNATURE GEN OLD/NEW L A TONS Te~S S B RTI~D HV-~F Cm NONE DISCREFANCY DATE APPENDIX D LABORATORY REPORT AND CHAIN-OF-CUSTODY DOCUMENTS Client Reference: ~=a_. l__science January 20, 2004 Nick Sudano Blaine lech Services, 20360 Gramercy Place Torrance, CA @0501-1511 Subject: Cal$cienceWork Order No.: Client Referenc~ Dear Client: Enclosed is an analytical re included in this report were the attached chain-of-custo, Unless otherwise noted, all guidelines established in ou operating procedures, and subcontracted analysis is pr package. The results in this reproduction thereof must b If you have any questions rE the undersigned. Cal.~,en cez/~ir.on mental (.~r~m'°~s' ,nc' 04-01-0549 2401 Oak Street, Bakersfield, CA Project Manager Quality Assurance Manager 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 Enclosed is an analytical report for the above-referenced project. The samples included in this report were received 1/13/2004 and analyzed in accordance with the attached chain-of-custody, Unless otherwise noted, all analytical testing was accomplished in accordance with the guidelines established in our Quality Assurance Program Manual, applicable standard operating procedures, and other related documentation. The original report of any subcontracted analysis is provided herein, and follows the standard Calscience data package. The results in this analytical repeal are limited to the samples tested and any reproduction thereof must be h~ade in its entirety. If you have any questions regarding this report, please do not hesitate to contact alscience _nvironmental --ab°ratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Analytical Report Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 120.1 Page I of 1 Lab Sample Date Date Date Client Sample Number Number Collected Matdx Prepared Analyzed QC Batch ID Parameter Result RI. D._EF Qual Units Specific Conductance 490 1.0 1 umhos/crn Para meter Result RI. D._~F Qual U nits Specific Conductance 440 1.0 1 umhos/cm I Parameter Result RI. DF: Qual Units Specific Conductance 350 1.0 1 umhos/cm Parameter, Result RI_ D__[F Qual Units Specific Conductance 490 1.0 1 umhos/cm I Parameter Result RI_ D._.~F Qual Units Specific Conductance 470 1.0 1 umhoslcm orhng Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 I --~-~- Analytical Report n_ vironmentai I L-ab°rat°ries'lnc' Blaine Tech Services, Inc Date Received: 01/13/64 i 20360 Gramercy Place Work Order No: 04-01-0549 Torrance, CA 90501-1511 Preparation: N/A Method: EPA 130.2 I Project: 2401 Oak Street, Bakersfield, CA Page 1 of 1 Lab Sample Date Date Date I Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result RI_ I Hardness, Total 140 2 Parameter Result RL I Hardness, Total 120 2 Parameter Result RL Hardness, Total 98 2 Parameter Result RL I Hardness, Total 140 2 I Parameter Result RL Hardness, Total 140 2 I Parameter Result RL Hardness, Total ND 2.0 I ! 7440 lincoln Way, Garden Grove, GA g2841-1427 · ltl[_: (7~4) 895-5494 · FAX: (714) 8~4-7501 1 DF Qual Units 1 mg/L D.~F Oual Unils I mg/L D.__~F Qual Units 1 mg/L D_.~F Oual Units 1 mg/L DF Qual Units I mg/L D__[F qual Units 1 mg/L ~-a!science ~_nvironmental iL_ aboratories, inc.' Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 150.1 Project: 2401 Oak Street, Bakersfield, CA Page I of 1 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result RI_ D._.~F Qual Units pH 6.54 0.01 1 pH units Parameter Result RI.. D._~F Qual Units pH 6.72 0.01 1 pH units Parameter Result RL DF= 9u~l Units. pH 6.62 0.01 I pH units Parameter Result RI- DF Qual Units pH 6.55 0.01 I pH units Parameter Result RL D_..EF Qual Units pH 6.51 0.01 1 pH units Pt. - Reporting Limit , DF - Dilution Factor , QLm! - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 aiscience - vironmental --aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report bate Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 160.1 Project: 2401 Oak Street, Bakersfield, CA Page 1 of 1 Lab Sample Date Date Date Clienl Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result R~L D....[F Oual Units Solids, Total Dissolved 300 1.0 1 mg/L Parameter Result RI. D._[F Qual Units Solids, Total Dissolved 260 1.0 I mg/L Parameter R~,?,ult RL D,_.~F Qual Units Solids, Total Dissolved 210 1.0 I mg/L I Parameter Result RI.. DF: Qua! Unils Solids, Total Dissolved 2go 1.0 1 mg/L Parameter Result RI_ D._[F Qual Units Solids, Total Dissolved 280 1.0 1 mg/L J ~ RL - Reporting Limit , DF - Dilution Factor ' , Oual - Qualifiers  7440 Lincoln Way, Garden Grove, CA 92841-1427 TEL: (714) 895-5494 · FAX: (714) 894-7501 .._a!.science j _nvironmental aboratories, inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 300.0 Project: 2401 Oak Street, Bakersfield, CA Page 1 of 1 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared 'Analyzed QC Batch ID Ii;";:'"' ~/':":::: L!: ~.~i .i:::':".'L:,:.'~:"L..:':.: . -: .... ', ': . !....'.:,-i. :-.::.,::~; : ' ..... .-.' ' .... ' :". · ]:~ L.. '.'.. .: ' · ' '. .... · ': ... · ~' :MWt!~',(.!~!,P.-~g~)i' :i ::;: .... ::'.: .... ' .: '.: . '~:' :. ~ {: .;:; ?.'~!~054S-1~. ~ · :01..~13104..;'.;:..'~kOaS~ '::i '.'.: i.N,'A': .: ". :. 0~/t3104'~:'.'., '0a~1.~13L01 Parameter Result RL D_..~F Qual Units Parameter Result RI_ DF: Qua._._Jl Units Chlodde 71 10 10 D mg/L Sulfate 31 10 10 D mg/L Nitrate (as N) 1.0 0.1 1 mg/L Parameter Result RI_ DF: Qual Unit,~ .parameter Result RL D~F Oua..__.JI Units Chloride 67 10 10 D mg/L Sulfate 24 10 10 D mg/L Nitrate (as N) 0.54 0.10 1 mg/L [ ~ : ~. !~ : , ~ :, , .::; :-::: ,' :~ :..:.';-:...; ~i~:..'~;.:u:.-? ~;::~i.'!~; [i!i~:'='~ ~' ::~:;;:i;:;!'.~i.:..~!/';'!~:': .i: !/'..i!~:.~:: '.: ~,' ?.; :~ .;:~'1..:'." :' : ~ :' .~ "~ .:. :!': :- :i .:"...-:'.rm:i ,: :: -:':'." '.. · -:,. =.. ?'..; '.. '.: · Parameter Result RI- DF Qual Units Parameter Result RI- DF Qual Units Chloride 48 10 10 D mg/L Sulfate 16 10 10 D mg/L Nitrate (as N) 0.65 0.10 I mg/L I Parameter ,Result RI. DF: Oual Units Parameter Result RI_ D_~F (~ual Units Chloride 82 10 10 D mg/L Sulfate 36 10 10 D mg/L Nitrate (as N) 1,1 0.1 I mg/L I Parameter Result RI_ D._.~F Qual Units Parameter Result RI_ D.._~F Qual Units Chloride 72 10 10 D mg/L Sulfate 29 10 10 D mg/L Nitrate (as N) 1.4 0.1 1 mg/L Parameter Result RI_ DF Qual Units parameter Result R~L D._.~F Qual Units Chloride ND 1.0 I mg/L Sulfate ND 1.0 1 mg/L Nitrate (as N) ND 0.10 I mg/L I I J . RL- Repoding Limi! , DF- Dilution Factor , QuaJ- Qualifiers . 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ..alscience -__nvironmental aborat° ries, Inc. B~aine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Rec~i'ved: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 351.3 Project: 2401 Oak Street, Bakersfield, CA Page 1 of 1 Lab Sample Date Date Date Client Sample Number Number Collected Matdx Prepared Analyzed QC Batch ID Parameter Result R__L D._~F Qual Units Total Kjeldah, I Nitrogen ND 0.50 1 mg/L Parameter ~ RL D__F .Qua] Units. Total Kjeidahl Nitrogen ND 0.50 1 mg/L / Parameter Result RI_ D._~F Qual Unlts Total Kjeldahl Nitrogen 0.56 0.50 1 mg/L I I Parameter Result RI. DF: Oual Units Total Kjeldahl Nitrogen ND 0.50 1 mg/L Parameter Result RI_ DF: Qua. I Un.Its Totai Kjeldahl Nitrogen 0.63 0.50 I mg/L Parameter Result RI_ DF Qual Units Total Kjeldahl Nitrogen ND 0.50 I mg/L orhng Limit , DF - Dilution Factor , Qual- Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841~1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~-aiscience ~r.n_ vironmentai ~L ab°ratories, Inc. Blaine Tech' SJ~/ices, I~IcIII 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report ' ' Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: SM 2320B Project: 2401 Oak Street, Bakersfield, CA Page 1 of 1 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID .......... .:..~, .... .......,,.. ...... . .......... ., ~ Parameter Result RI. D__F QuaJ Units Hydroxide (as CaCO3) ND 1,0 1 mgic Parameter Result R__LL DF: Q,'..ual Units Hydroxide (as CaCO3) ND 1.0 1 mg/L ~.,~g~,~.~i~ ............ Pa~meter Result R~ D~ Qua~ Units Hyd~xide (as CaCO3) ND 1.0 I mg/L I Pa~meter Result R~ D~ Qual Uni~ Hyd~xide (as CaCO3) ND 1.0 1 mg/L I Parameter Result R~ D~ Qual Uni~ Hydroxide (as CaCO3) ND 1.0 1 ort~ng Limit , DF - Dilution Factor , Oual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~..~al_science l~- nvironmental ~-- aboratories, inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: Work Order No: · Preparation: Method: 01/13~O4 04-01-0549 N/A SM 2320B Project: 2401 Oak Street, Bakersfield, CA Page 1 of 1 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID I':. ~i~:ii~;~.:~;!; :.iii:!~i ;'i' ili:i;;i':!i;;:;:; :,.'.:: .. ;;..: ... :i, :...!/::.i~:~,~,.~ ;. ;.: ~i~'- :- ~. ~;, '~'::.':;~'-:~:~...~,.... "~ ....... ~:. :~: "'.:~'~' ~ . ......... '~ '~' ": '1 Parameter ,.Result. RL D.._~F Oual Units Carbonate (as CaCO3) ND 1.0 I mg/L [.!:~,~c~i~!!-:,~;!',; ~;~i(;~ ~, ~! i·i:' ::!~;~.~·~i!:..i, :::: ;~::'..,, ':.'~i..-~:..!: ;..:i!~~ :-.:,'~'~'.";;' ~ i~ ~, !~i:;; ~ ;:~:, '~¢~,~::,-:: .e.~..,i '.' 'i Parameter .Result RI. DF: Qual Units Carbonate (as CaC03) ND 1,0 1 mg/L ~ ~ i~[ ~i ~ !i ii; !ii !i~;!i~ ,!'.;:ii:~!i!;:i:, ~ ,?.' ;..~ :;?:~i;ii:~!~ ii:.!~ ;~ :·'·~ ;~:~ i:,~:~ ~!!i!,~i!H~.~,; ~ ~:.:.,; ~a~: :.: ~ ~: Parameter Result R_L_L D__E P~a! Un,its Carbonate (as CaCO3) ND 1,0 1 mg/t. Parameter ReSult RI. D._~F Qual Unil;s Carbonate (as CaCO3) ND 1.0 1 mg/L I I I I I I Parameter Re,~ult RI. D._EF Qual Units Carbonate (as CaCO3) ND 1.0 1 mg/L p· od~ng Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 ° FAX: (714) 894~7501 alscience .nvironmental aboratories, Inc. Analytical Report Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: SM 2320B Project: 2401 Oak Street, Bakersfield, CA Page I of 1 Lab Sample -Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result RI_ D._EF Quat Units Bicarbonate (as CaCO3) 56 1.0 I mg/L Parameter Result Ri_ DF Qual ,Units Bicarbonate (as CaCO3) 46 1.0 1 mg/L ; ;:~:!;~;:i~i'~:i!H;i~i:!~i~{i~iii~[~!H:ii[[!~i~!:i~i~ !~!;~ ;i :'i, ":,i;'~.~i: i:'i!.::!;:'-i:.!;',!~:;~L.;:~'F~;,:.i:.~,:!:-.::..'~/:iL j~;L'..:'...:,"';. ~: i~t~: i ~; '.i:~ ...':~ ::,;.i.; ..... ~ ....... '.~' .-.. .. .... :.....~. 1 Parameter Result Ri_ D.._~F Qual Units Bicarbonate (as CaCO3) 26 1.0 I mg/L Parameter Result RI_ DF: Qual Uni!s Bicarbonate (as CaCO3) 100 5.0 1 mg/L Parameter Result Ri_ DF' Qual Units Bicarbonate (as CaCO3) 60 1.0 1 mg/L orting Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~.alsclence ~E~vironmen~a! · L_ aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: SM 2320B Project: 2401 Oak Street, Bakersfield, CA Page 1 of 1 Lab Sample Date Date Date Client Sample Number Number Collected Matdx Prepared Anaty-z_ed QC Batch ID ti ~i i~ "~.:. ;~.:~'.!! :'; ili:~i!?.~.!.i'~.:,!~i.:i "~.i: :::/:..';:~.;'~.::.~.~ ....?~,;~.!~. :?,~.: !.:.,~,~..,. ~.~:, ,i:~i,~,,~:~..,:~. :. ~,~ Parameter Result RI_ DF Qual Units Alkalinity, Total (as CaCO3) 56 1.0 1 mg/L Parameter Result RI_ DF' Qual Units Alkalinity, Total (as CaCO3) 46 1.0 1 mg/L Parameter Result RI_ DF' Qual Units Alkalinity, Total (as CaCO3} 26 1.0 I mg/L Parameter Result AJkalinity, Total (as CaCO3) 100 5.0 1 mg/L Parameter Result RI_ DF Qual ,Uni ,ts Alkalinity, Total (as CaCO3) 60 1.0 1 mg/L ep' od~ng Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 m · FAX: (714) 894-7501 ..aiscience F-_nvironmental aboratOries, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 9050'l-15'1 '1 Analytical Report Date Received: Work Order No: Preparation: Method: 01/13/04 04-01-0549 EPA 3005A Flit. EPA 601 OB Project: 2401 Oak Street, Bakersfield, CA Page 1 of 2 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Pa~meter Result R~ DF Qual Uni~ Lead ND 0.0100 I mg/L parameter Result R~ D~ Qual Uni~ Lead ND 0,0100 1 mg~L ~ammeter Result R~ DF Qual Units Lead ND 0.0100 1 mg/L Parameter Result R~ DF Qual Units Lead ND 0.0100 1 mg/L Parameter Result R~ DF Qual Units Lead ND 0,0100 1 mg/L I Parameter Result R~ D~ Qual Units Lead ND 0.0100 1 . mg/L Pa~meter Result R~ DF Qual Uni~ Lead ND 0.0100 1 m~L Pa~meter Result R~ DF Qual Units Lead ND 0.0100 1 mg/L ~ RL - Reporiing Limit , DF - Dilution Factor , Quad - Qualifiers  7440 Lincotn Way, Garden Grove, CA g2841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 mals_cience . -_nvironmental aboratories, Inc. Blaine Tech Services, thc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: Work Order No: Preparation: Method: 01 / 13/04 04-01-0549 EPA 3010A Total EPa 6010B Project: 2401 Oak Street, Bakersfield, CA Page 2 of 2 Lab Sample Date Date Date Client Sample Number Number Collected Matdx Prepared Analyzed QC Batch ID Parameter Result RL DF Qual Units P,~rameter ~Result RI_ DF Qual Units Manganese 0.0128 0.0050 1 mg/L Calcium 43.3 0.1 1 mg/L Potassium 2.72 0.50 1 mg/L Iron 0.302 0.100 1 mg/L Sodium 33.2 0.5 1 mg/L Magnesium 9.09 0.10' 1 mg/L Parameter Result RI. D_.[F Q, ual ~ni~ Parameter .Result RI- DF Qual Units Manganese ND 0.00500 1 mg/L Calciurn 32.3 0.1 1 mg/L Potassium 3.00 0.50 I mg/L Iron ND 0,100 1 mg/L Sodium 30.6 0.5 I mg/L Magnesium 9.82 0.10 1 mg/L Parameter Result RI_ DF Qual Uni_._.~ P~rameter Result RL DF Qual Units Manganese 0.0337 0.0050 1 mg/L Calcium 28.1 0.1 1 mg/L Potassium 3.09 0.50 I mg/L Iron 0.876 0.100 1 mg/L Sodium 27.2 0.5 1 mg/L Magnesium 7.32 0.10 1 mg/L Parameter Result RI. DF' Qual Units Paramete~r Result RI_ D._EF Qual Units Manganese 0.0114 0.0050 I mg/L Calcium 44.4 0.1 1 mg/L Potassium 2.78 0.50 1 mg/L Iron 0.239 0.100 1 mg/L Sodium 33.6 0.5 I mg/L Magnesium 9.36 0.10 1 mg/L Parameter Result RI- DF Qual Units Parameter Result RI_ D._~F ~ual Units Manganese 0.114 0.005 1 mg/L Calcium 37.9 0.1 I mg/L Potassium 3.55 0.50 I mg/L iron 1.70 0,10 1 mg/L Sodium 31.8 0.5 I mg/L Magnesium 11.5 0.1 I mg/L Parameter Result RI_ DF Qual Units Parameter Result RI_ DF Qual Units Lead ND 0.0100 1 mg/L Manganese ND 0.00500 1 mg/L Calcium ND 0.100 1 mg/L Potassium ND 0.500 1 mg/L Iron ND 0.100 1 mg/L Sodium ND 0.500 1 mg/L Magnesium ND 0.100 1 mg/L ortrng Umit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (7-14) 895-5494 · FAX: (714) 894-7501 . -a!science /J -_nvironmentai aboratories, inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: 01/13/04 Work Order No: 04-01-0549 PreparatiOn: EPA 5030B Method: DHS LUFT Project: 2401 Oak Street, Bakersfield, CA Page I of 3 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result RL D.__.~F Oual Uqi.ts TPH as Gasoline ND 50 I ug/L Surroqates: REC {%) Contr01 Limits 1,4-Bromofluocobenzene 82 49-133 Parameter Result RI_ DF' Qual Units TPH as Gasoline ND 50 1 ug/L Surroqates: REC {%) Contra) Qual Limits 1,4-Bromofluorobenzene 83 49-133 Parameter Resutt RL D~F Qual Units TPH as Gasoline ND 50 1 ug/L Surroaates: REC (%) Control Oual Limlt~ 1,4-Bromofluorobenzene 82 49-133 Parameter Result RL ' D__.EF Oual Uni .ts TPH as Gasoline ND 50 1 ug/L SurroRates: ~ Control Limits 1,4-Bromofluorobenzene 80 49-133 Qual iding Limit , DF - Dilution Factor , Oual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~=,-alscience ~.____nvironmental ~c_ aboratories, Inc. Blaine To'ch Services, 'in(:: ' 20360 Gramercy Place Torrance, CA 90501~1511 Analytical Report Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: DHS LUFT Project: 2401 Oak Street, Bakersfield, CA Page 2 of 3 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID '',.'.. ........ i.' ..... o,,:,,.o, Parameter Result Rt_ DF' Qual Units TPH as Gasoline ND 50 I ug/L Surrogates: REC (%) Control .Limits 1,4-Bromofluorobenzene 83 49-133 qual Parameter Result RI_ TPH as Gasoline ND 50 Surrogates REC (%) Control Limits 1,4-Bromofluorobenzene 81 49-133 DF Qual Units I ug/L Qual Parameter Result RI_ TPH as Gasoline ND 50 DF' Qual Units 1 ug/L Surroqates: REC (%) C.q.ntrol. Limits 1,4-Bromofluorobenzene 82 49-133 Qual Parameter Result RI_ TPH as Gasoline ND 50 DF ~al Units I uglL Surrooates: REC, (%) CoO, trol Limits 1,4-Bmmofluorobenzene 78 49,133 Q'ual ortmg Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 ° TEL: (714) 895-5494 FAX:' (714) 894-7501 -_a/s_cience vironmental aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: " 01/13/04~ Work Order No: 04-01-0549 Preparation: EPA 5030B Method: DHS LUFT Project: 2401 Oak Street, Bakersfield, CA Page 3 of 3 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result TPH as Gasoline ND Surrogates; REC (%) 1,4-Bromofluorobenzene 85 R.__~L D__EF Qual Uni!s 50 1 ug/L Control Limits 49-133 Qual Pa~ ,meter Resplt RL TPH as Gasoline ND 50 Surroqates: REC (%) Control Limits 1,4.Bromofluombenzene 84 49-133 DF Qual Units I ug/L Qual J ~ RL - Reporting Limit , DF. Dilution Factor , Oual - Qualifiers  7440 Lincoln Way, Garden Grove, CA 92841-1427 ° TEL: (714) 895-5494 · FAX: (714) 894-7501 ~-alscience ~Epvironmentai ~=~ aboratories, Inc. Analytical Report Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Date Received: Work Order'No: Preparation: Method: 01/1~04 04-01-0549 EPA 5030B EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Lab Sample Date Date Client Sample Number Number Collected Matrix Prepared ,'.::,! Page I of 10 Date Analyzed QC Batch ID Parameter Result R._~L DF Qual Units Parameter Result R__.~L D.._EF Acetone ND 10 1 ug/L l,l-Dichloropropene ND 1.0 1 Benzene ND 0.50 1 ug/L c-1,3-Dichloropropene ND 0.50 t Bromobenzene ND 1.0 1 ug/L t-1,3-Dichloropropene ND 0.50 1 Bromochloromethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 1 Bromodichloromethane ND 1.0 1 ug/L 2.Hexanone ND 10 1 Bromoform ND , 1.0 1 ug/L Isopropylbenzene ND 1.0 1 Bromomethane ND 10 I ug/L p-lsopropyltoluene ND 1.0 1 2-Butanone ND 10 I ug/L Methylene Chlodde ND 10 1 n-Butylbenzene ND 1.0 I ug/L 4-Methyl-2-Pentanone ND 10 1 sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 1 tert-Butylbenzene ND 1.0 1 ug/l_ n-Propylbenzene ND 1.0 1 Carbon Disuifide ND 10 1 ug/L Styrene ND 1.0 1 Carbon Tetrachloride ND 0.50 1 ug/L 1,1,1,2-Tetrachlo~oethane ND 1.0 1 Chlorobenzene ND 1.0 1 ug/L 1,1,2,2-Tetrachloroethane ND 1.0 1 Chloroethane ND 1.0 1 ug/L Tetrachloroethene ND 1.0 1 Chloroform ND 1.0 1 ug/L Toluene ND 1 .O 1 Chloromethane ND 10 1 ug/L 1,2,3-Trichtorobenzene ND 1.0 1 2-Chlorotoiuene ND 1.0 1 ug/L 1,2,4-Trichlorobenzene ND 1.0 1 4-Chlorotoluene ND 1.0 1 ug/L 1 ,l,l-Trichloroethane ND 1.0 1 Dibromochloromethane ND 1.0 1 ug/L 1,1,2-Trichloroethane ND 1.0 1 1,2-Dibromo-3-Chloropropane ND 5.0 1 ug/L Trichloroethene ND 1.0 1 1,2-Dibromoethane ND 1.0 1 ug/L Trichlorofluoromethane ND 10 1 Dibromomethane ND 1.0 I ug/L 1,2,3-Tdchloropropane ND 5.0 1 1,2-Dichlorobenzene ND 1.0 1 ug/L 1,2,4-Trimethylbenzene ND 1.0 1 1,3-Dichlorobenzene ND 1.0 I ug/L 1,3,5-Trimethylbenzene ND 1.0 1 1,4-Dichlorobenzene ND 1.0 I ug/L Vinyl Acetate ND 10 1 Dichlorodifluoromethane ND 1.0 1 ug/L Vinyl Chlodde ND 0.50 1 1,1.Dichloroethane ND 1.0 1 ug/L p/m-Xylene ND 1.0 1 1,2-Dichloroethane ND 0.50 1 ug/L o-Xylene ND 1.0 1 1, i-Dichloroethene ND 1.0 1 ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 1 c-1,2-Dichloroethene ND 1.0 1 ug/L Terl-Butyl Alcohol ('TBA) ND 10 1 t-1,2-Dichloroethene ND 1.0 1 ug/L Diisopropyl Ether (DIPE) ND 2.0 1 1,2-Dichioropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 1,3-Dichloropropane ND 1.0 1 ug/L Terl-AmyI-Methyl Ether (TAME) ND 2.0 1 2,2-Dichloropropane ND 1.0 I ug/L Surro.qates: REC (%) ConlTol Qual Surro_qates: REC {%) Control Limits Dibromofluoromethane 100 84-120 Toluene-d8 100 91-109 1,4--Bromofluorobenzene 100 84-108 .~ Units ug/L ug/L ug/L ug/L ugJL ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/l_ ug/L ug/l_ ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L Qual ~ PI_- Reporling IJmit , DF - Dilution Factor , Qual- Qualifiers  7440 Lincoln Garden Grove, CA 92841-1427 Way, · TEL: (714) 895-5494 · FAX: (714) 894-7501 ! pvironmentai I raboraton'es, Inc. Analytical Report Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: EPA 8260B Page 2 of 10 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID !~;2(~i~!~.,ge):~,:..:~::.:.~,::.~.i~ ~:~.. :::. ~ ~i: :~ !~::: !: ;. :.04~0549~2: -~,' ~O~fl~ .','. ~us ..:~...:~.~NIA .... .. -'.0~1~/15/0~:. 040115L01 Parameter Result RI. DF Dual Units Parameter Result RI. D._~F Oual Units Acetone ND 10 I ug/L 1,1.Dichloropropene ND 1.0 I ug/L Benzene ND 0.50 1 ug/L c-l,3-Dichloropropene ND 0.50 1 ug/L Bromobenzene ND 1.0 I ug/L t-1,3-Dichloropropene ND 0.50 1 ug/L Bromochloromethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 1 ug/L Bromodichloromethane NO 1.0 1 ug/L 2-Hexanone ND 10 1. ug/L Bromoform ND 1.0 1 ug/L Isopmpytbenzene ND 1.0 1 ug/L Bromomethane ND 10 1 ug/L p-lsopropyltoluene ND 1.0 1 ug/L 2-Butanone ND 10 1 ug/L Melhylene Chlodde ND 10 I ug/L n-Butylbenzene ND 1.0 1 ug/L 4-Methyl-2-Pentanone ND 10 I ug/L sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 1 ug/L tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1.0 I ug/L Carbon Disulfide ND 10 1 ug/L Styrene ND 1.0 I ug/L Carbon Tetrachlodde ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 I ug/L Chlorobenzene ND 1.0 1 ug/L 1,1,2,2-Tetrachloroethane ND 1.0 I ug/L Chloroethane ND 1.0 1 ug/L Tetrachloroethene ND 1.0 1 ug/L Chloroform ND 1.0 I ug/L Toluene ND 1.0 1 ug/L Chloromethane ND 10 1 ug/L 1,2,3-Tdchlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4-Trichlorobenzene ND 1 ;0 I ug/L 4-Chlorotoluene ND 1.0 I ug/L 1,1,1-Tdchloroethane ND 1.0 1 uglL Dibromochloromethane ND 1.0 I ug/L. 1,1.,2-Tdchloroethane ND 1.0 I ug/L 1,2-Dlbromo-3-Chloropropane ND 5.0 1 ug/L Trichloroethene ND 1.0 I ug/L 1,2.Dibromoethane ND 1.0 1 ug/L Trichlorofl uoromethane NO 10 I uglL Dibromomethane ND 1.0 1 ug/L 1,2,3~Trichlompropane ND 5.0 1 ug/L 1,2-Dich~orobenzene ND 1.0 I ug/L 1,2,4-Trimethylbenzene ND 1.0 1 ug/L 1,3-Dich/orobenzene ND 1.0 I ug/L 1,3,5-Trimethylbenzene ND 1.0 1 ug/L 1,4-Dichlombenzene ND 1.0 1 ug/L Vinyl Acetate ND 10 1 ug/L Diqhlorodifluoromethane ND 1.0 1 ug/L Vinyl Chloride ND 0.50 1 ug/L 1,1-Dichloroethane ND 1.0 1 ug/L p/m-Xylene ND 1.0 I ug/L. 1,2-Dichloroethane ND 0.50 1 ug/L o-Xylene ND 1.0 1 uglL 1,1-Dichloroethene ND 1,0 1 ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ug/L c-l,2-Dichlor0ethene ND 1.0 1 ug/L Tert-Butyl Alcohol (TBA) ND 10 I ug/L t-1,2-Dichloroethene ND 1.0 1 ug/L Diisopropyl Ether (DIPE) ND 2.0 I ug/L 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 I ug/L 1,3-Dichloropropane ND 1.0 1 ug/L Te~t-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2-Dichloropropane ND 1.0 I ug/L Surro,qates: REC (%) Control Qual Surrogates: REC (%) Control Oual Limits Dibromofluoromethane 103 84.120 Toluene-d8 97 91-109 1,4-Bromofluorobenzene 100 84-108 I I RI_. Reporting Limit , DF - Dilution Factor , Oual - Qualifiers  7440 Lincoln Garden Grove, CA 92841-1427 Way, · TEL: (7t4) 895-5494 · FAX: (714) 894-7501 I I I I I I I I :1 I ! I I I I I -_nvironmental --aboratories, Inc. AnalYtical Report Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page 3 of 10 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result RI_ DF :Qual Units Parameter Result R~L DF Oual Units Acetone ND 10 1 ug/L 1,1.Dichloropropene ND 1,0 1 ug/L Benzene ND 0,50 I ug/L c-1,3Oichlompropene ND 0.50 1 ug/L Bromobenzene ND 1.0 I ug/L t-1,3-Dichloropropene ND 0.50 1 ug/L Bromochloromethane ND 1.0 1 ug/L Ethylbenzene · ' ND 1.0 1 ug/L Bromodichloromethane ND 1.0 1 ug/L. 2-Hexanone ND 10 1 ug/L Bromoform ND 1.0 1 ug/L Isopropylbenzene ND 1.0 I ug/L Bromomethane ND 10 I ug/l_ p-isopropyltoluene ND 1.0 I ug/L 2-Butanone ND 10 I ug/L Methylene Chloride ND 10 I ug/L n-Butylbenzene ND 1.0 1 ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 1 ug/L tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1,0 I ug/L Carbon Disulfide ND 10 1 bg/L Styrene ND 1.0 1 ug/L Carbon Tetrachloride ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 1 ug/L 1,1,2,2-Tetrachloroethane ND 1,0 1 ug/L Chloroethane ND 1.0 1 ug/L Tetrachloroethene ND 1.0 1 ug/L Chloroform ND 1.0 1 ug/L Toluene ND 1.0 1 ug/L Chloromethane ND 10 1 ug/L 1,2,3-Tdchlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4-Trtchlorobenzene ND 1.0 1 ug/L 4-Chlorotoiuene ND 1.0 I ug/L 1,1,1-Trichloroethane ND 1.0 I ug/L Dibromochloromethane ND 1.0 1 ug/L 1,1,2-Trichloroethane ND 1.0 1 ug/L 1,2-Dlbromo-3-Chlompropane ND 5.0 I ug/L Trichloroel~ene ND 1.0 1 ug/L 1,2-Dibromoethane ND 1.0 1 ug/L Trichlorofluoromethane ND 10 1 ucj/L Dibromomethane ND 1.0 1 ug/L 1,2,3-Trichloropropane ND 5.0 1 ug/L 1,2-Dichlorobenzene ND 1.0 I uglL 1,2,~Tdmethylbenzene ND 1.0 I ug/t. 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3,5-Tdmethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene ND 1.0 1 uglL Vinyl Acetate ND 10 1 ug/L Dichlorodifluoromethane ND 1.0 1 ug/L Vinyl Chloride ND 0.50 1 ug/L 1,1 -Dichloroethane ND 1.0 I ug/L p/m-Xylene ND 1.0 1 ug/L 1,2-Dichloroethane ND 0.50 1 ug/L o-Xylene ND 1.0 I ug/L 1,1-Dichloroethene ND 1.0 I ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 I ug/L c-l,2-Dichloroethene ND 1.0 1 ug/L . Ted-Butyl Alcohol (TBA) ND 10 1 ug/L t-l,2-Dichloroethene ND 1.0 1 ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L t ,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L 1,3-Dichloropropane ND 1.0 1 ug/L Tert-Amyl-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2-Dichloropropane ND 1.0 1 ug/L Surrogates; REC (%) Control Qual Surroflate~; REC {%) .Control Qual Limits Dibromofluoromethane gg . 84-120 Toluene-d8 100 91-109 1,4-Bromofl uorobenzene 101 84-108 ortlng Limit , DF - Dilution Factor , Oual- Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 u · TEL: (714) 895-5494 · FAX: (714) 894-7501 nvironmental ~ Analytical Report ~-- aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Method: Project: 2401 Oak Street, Bakersfield, CA Lab Sample Client Sample Number Number Parameter , RestJlt RL D~ Qual Units Acetone ND 10 ug/L Benzene ND 0.50 1 ug/L Bmmobenzene ND 1.0 1 ug/L Bromochlorome~ane ND 1.0 1 ug/L Bromodichloromethane ND 1.0 1 ug/L Bromoform ND 1.0 1 ug/L Bromomethane ND 10 1 ug/L 2-Butanone ND 10 I ug/L n-Butylbenzene ND 1.0 I ug/L sec-Butylbenzene ND 1.0 1 ug/L tert-Butylbenzene ND 1.0 1 ug/L Carbon Disulfide ND 10 1 ug/L Styrene Carbon Tetrachloride ND 0.50 1 ug/L 1,1,1,2-' Chlorobenzene ND 1.0 1 uglL 1,1,2,2-' Chloroethane ND 1.0 1 ug/L Tetrachl Chloroform ND 1.0 1 ug/L Toluene Chloromethane ND 10 I ug/L 2-Chlorotoluene ND 1.0 I ug/L 4-Chlorotoluene ND 1.0 I ug/L Dibromochloromethane ' ND 1,0 1 ug/L 1,2-Dibromo-3-Chloropropa ne ND 5.0 1 ug/L 1,2-Dibromoethane ND 1.0 I ug/L Dibromomethane ND 1.0 1 ug/!- 1,2-Dichlorobenzene ND 1.0 1 ug/L 1,3-Dichlorobenzene ND 1.0 I ug/L 1,4-Dichlorobenzene ND 1.0 1 ug/L Dichlorodifluorometh ane ND 1.0 1 ug/L 1,1-Dichloroethane ND 1.0 1 ug/L 1,2-Dichloroethane ND 0.50 1 ug/L 1,1-Dichloro~thene ND 1.0 1 ug/L c-1,2-Dichloroethene ND 1.0 1 ug/L t-1,2-DichlOroethene ND 1.0 1 ug/L 1,2-Dichloropropane ND 1,0 1 ug/L 1,3-Dichloropropane ND 1.0 ' 1 ug/L 2.,2-Dichloropropane ND 1.0 1 uglL Surroqates; REC (%) Control Qual Surrogates: Limits Dibromofluoromethane 100 8-~'-120 Toluene-d8 t ,4-Bromofluorobenzene 99 84-108  7440 Lincoln Way, Garden Grove, CA 92841-1427 Date Received: Work Order No: Preparation: 01/13/O4 04-01-0549 EPA 5030B EPA 8260B Page 4 of 10 Date Date Date Collected Matrix Prepared Analyzed QC Batch ID ..: · . . ...... ..... Parameter 1,1-Oichloropropene c-1,3-Dichior0Propene t-1,3-Dichloropropene Ethylbenzene 2-Hexanone Isopropylbenzene p-lsopropyttoluene Methylene Chloride 4-Methyl-2-Pentanone Naphthalene n-Propylbenzene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachlomethene 1,2,3-Trichlorobenzene 1,2,4-Tdchlorobenzene 1,1,1-Trichloroethane 1,'I ,2-Tdchloroethane Tdchloroethene Tric~lorofluorometha ne 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl Acetate Vinyl Chloride p/m-Xylene o-Xylene Methyl-t-Butyl Ether (MTBE) Tert-Butyl Alcohol (TBA) Diisopropyl Ether (DIPE) Ethyl-l-Butyl Ether (ETBE) Tert-AmyI-Methyl Ether (TAME) Result RL D_[F Qual Unit._._~s ND 1.0 I ug/L ND 0,50 1 ug/L ND 0.50 1 ug/L ND 1.0 1 ug/L ND 10 I ug/L ND 1,0 1 ug/L ND 1.0 I ug/L ND 10 I ug/L ND 10 1 ug/L ND 10 1 ug/L ND 1.0 1 ug/L ND 1.0 1 ug/L ND 1.0 1 ug/L ND 1.0 1 ug/L ND 1.0 I ug/L ND 1.0 1 ug/L ND 1.0 1 ug/L ND 1.0 I ug/L ND 1.0 1 ug/L ND 1.0 1 ug/L ND 1.0 1 ug/L ND 10 I ug/L ND 5.0 1 ugfL ND 1.0 I ug/L ND 1.0 I ug/L ND 10 I ug/L ND 0.50 I ug/L ND 1.0 1 ug/L ND 1.0 1 ug/L ND 1.0 1 ug/L ND 10 1 ug/L ND 2.0 I ug/L ND 2.0 1 ug/L ND 2.0 1 ug/L REC {%) Co,ntro, 100 91-109 Qual · TEL: (714) 895-5494 · FAX: (714) 894-7501 ,,alscience J ._n vironmental aboratories, Inc. Analytical Report Blaine Tech Services, Inc Date Received: 01/13/04 20360 Gramercy Place Work Order No: 04-01-0549 Torrance, CA 90501-1511 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page 5 of 10 Lab Sample Date Date Date Client Sample Number Number Collected Matdx Prepared Analyzed QC Batch ID ....... ' ......... ,~;,,~;,;i~ .......... "' ,, ',,' ............................................. 'ii '':' ..... ,,'~t" ' ,,,,, ', ......... ,,' ' .. Parameter Result RI. DF Qual Units Parameter Result RI. DF Qual Units Acetone ND 10 1 ug/L 1,1-Dichloropropene ND 1.0 I ug/L Benzene ND 0.50 1 ug/L c-1,3-Oichloropropene ND 0.50 I ug/L Bromobenzene ND 1,0 1 ug/L t-1,3-Dichloropropene ND 0.50 1 ug/L Bromochloromethane ND 1.0 I ug/L Ethylbenzene ND 1.0 1 ug/L Bromodichloromethane ND 1.0 I ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1.0 1 ug/L Isopropylbenzene ND 1.0 1 ug/L Bromomethane ND 10 1 ug/L p-lsopropyltoluene ND 1.0 1 ug/L 2-Rutanone ND 10 1 ug/L Methylene Chloride . ND 10 I ug/L n-Butytbenzene ND 1.0 1 ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 1 ug/L tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1.0 1 uglL Carbon Disulfide ND 10 1 ug/L Styrene ND 1.0 1 ug/L Carbon Tetrachloride ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 I ug/L 1,1,2,2-Tetrachioroetha ne ND 1.0 I ug/L Chloroethane ND 1.0 I ug/L Tetrachloroethene ND 1.0 I ug/L Chlorofom3 ND 1.0 1 ug/L Toluene ND 1.0 I ug/L Chloromethane ND 10 1 ug/L 1,2,3-Trichlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4-Trichlorobenzene ND 1.0 1 ug/L 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Tdchloroethane ND 1.0 1 ug/L Dibromochloromethane ND 1.0 1 ug/L 1,1,2-Trichloroethane ND 1.0 1 ' uglL 1,2-Dibromo-3-Chloropropane ND 5.0 1 ug/L Trlchloroethene ND 1.0 I ug/L 1,2-Dibromoethane ND 1.0 1 ug/I. Trichlorofiuoromethane ND 10 I ug/L DIbromomethane ND 1.0 1 ug/L 1,2,3-Tdchloropropane ND 5.0 1 ug/L 1,2-Dichi0robenzene ND 1.0 I ug/L 1,2.4-Trimethylbenzene ND 1.0 1 ug/L 1,3-Dichlorobenzene ND 1.0 I uglL 1,3,5-Tdmethylbenzene ND 1,0 1 ug/L 1,4-Dichlorobenzene ND 1.0 I ug/L Vinyl Acetate ND 10 1 ug/L Dichlorodifluoromethane ND 1.0 1 ug/L Vinyl Chlodde ND 0.50 1 ug/L 1,1-Dichloroethane ND 1.0 t ug/L p/m-Xylene ND 1.0 I ug/L 1,2-Dichloroethane ND 0.50 1 ug/L o-Xylene.. ND 1.0 1 uglL 1,1-Dichloroethene ND 1.0 1 ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 1 uD/L c-'J ,2-Dichloroethene ND 1.0 1 ug/L Tert-Butyl Alcohol (TBA) ND 10 1 ug/L t-l,2-Dichloroelhene ND 1,0 1 ug/L Diisopropyt El~er (DIPE) ND 2.0 1 ug/L 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L 1,3-Dichloropropane ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2-Dichloropropane ND 1.0 1 ug/L Surro,qates: RFC (%) Control Oual Surro.qates: EEC (%) Control Qual Limits DIbmmofluoromethane 102 84-120 Toluene-d8 97 91-109 1,4-Bromofluorobenzene 98 84-108 ort:ng Umit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 I -alscience m nvironmental ,,. ~ .... Analytical Report I b aDorarones, inc. Blaine Tech Services, Inc Date Received: 01/13/04 · 20360 Gramercy Place Work Order No: 04-01-0549 · Torrance, CA 90501-1511 Preparation: EPA 5030B Method: EPA 8260B I Project: 2401 Oak Street, Bakersfield, CA Page 6 of 10 Lab Sample Date . .. Date Date ....... · Client Sample Number, Number Collected Matnx Prepared Analyzed _ Parameter .R~ult RL DF QUal Unit~ Parameter Result RL DF Qual Units B ND 10 1 ND 1.0 1 Acetone u~I/L 1,1-Diahloropropene u~/L · Benzene ND 0.50 1 ug/L c-1,3-Dichloropropene ND 0.50 I ug/L Bromobenzene ND t .0 1 ug/I. t-l,3-Dichloropropene ND 0.50 1 ug/L Bromochloromethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 1 ug/L Bromodichloromethane ND 1.0 1 ug/L 2-Hexanone ND 10 1 ug/L · Bromoforrn ND 1.0 1 ug/L .Isopropylbenzene ND 1.0 1 ug/L ~ Bromomethane ND 10 1 uglL p-lsopropyltoluene ND 1.0 1 ug/L 2-Butanone ND 10 1 ug/L Methylene Chloride . ND 10 1 . ug/L I~ n-Butylbenzene ND 1.0 1 ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L · sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 I ug/L ~ tert-Butylbenzene ND 1.0 I ug/L n-Propyll~nzene ND 1,0 I ug/L - Carbon Disulfide ND 10 1 ug/L ~ Styrene ND 1.0 1 ug/L __ Carbon Tetrachloride ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 I ug/L 1,1,2,2-Tetrachloroetha ne ND 1.0 1 ug/L · Chloroethane ND 1.0 I ug/L Tetrachloroethene ND 1.0 1 ug/L Chloroform ND 1.0 1 ug/L Toluene ND 1.0 I ug/L Chloromethane ND 10 1 ug/L 1,2,3-Trichlorobenzen e ND 1.0 I ug/L · 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4.T richlorobenzene ND 1.0 1 ug/L. B 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Tfichloroethane ND 1.0 1 ug/L Dibromochloromethane ND ' 1.0 1 uglL 1,1,2-Trichloroethane ND 1.0 1 ug/L 1,2-Dibromo-3-Chlorop ropa ne ND 5.0 1 ug/L Trichloroethene ND 1.0 1 ug/L B~ 1,2-Dibromoethane ND 1,0 1 u§/L Trichlorofluoromethane ND 10 1 ug/L · Dibromomethane ND 1.0 I ug/L 1,2,3-Tdchloropropane ND 5.0 1 ug/L · 1,2-Dichlorobenzene ND 1.0 1 ug/L 1,2 4-Trimethylbenzene ND 1.0 1 ug/L ' 1,$-Dichlorobenzene ND 1.0 I ug/L 1,3,5-Trimethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene ND 1.0 1 ug/L Vinyl Acetate ND 10 1 ~ ug/L · Dichlorodifluoromethane ND 1.0 1 ug/L Vinyl Chloride ND 0.50 1 . ug/L ' · 1,1-Dichloroethane ND 1.0 1 ug/L p/m-Xytene ND 1.0 1 ug/L ~' 1,2-Dichloroethane ND 0.50 I . ug/L o-Xylene ND 1.0 1 ug/L 1,1-Dichloro~thene ND 1.0 1 ug/L Melhyl-toButyl Ether (MTBE) ND 1.0 t ug/L lEI c-l,2-Dichloroethene ND 1.0 1 'ug/L Tart-Butyl Alcohol (-FBA) ND 10 I ug/L · t-l,2-Dichloroethene ND 1.0 1 ug/L Diisopropyl Ether {DIRE} ND 2.0 1 ug/L ~ 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) . ND 2.0 1 uo/L 1,3-Dichloropropane ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L i 2,2-Dichloropropane ND 1.0 1 ug/L · Surroclates: REC i'%} Control Qual Surroqntes: REC {%) Control Qual -- Limits Dibromofluoromethane 101 '--~'~'20 Toluene-d 8 100 91 -109 I 1,4-Brom ofluorobenzene 102 84-108 ! alscience n vironmental · --aborato es, Inc. Analytical Report Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: Work Order No: Preparation: Method: 01 / 13/04 04-01-0549 EPa 5030B EPA 8260B Page 7 of 10 Lab Sample Date Date Client Sample Number Number Collected Matrix Prepared Date Analyzed .: o!/14/o4 QC Batch ID '1 I I I ! i I ! i I I I I Parameter Result RI_ D__~F Qual Units Parameter Result Acetone ND 10 1 ug/L 1,1-Dichloropropene ND Benzene ND 0.50 1 ug/L c-1,3-Dichloropropene ND Bromobenzene ND 1.0 1 ug/L t-1,3-Dichloropropene ND Bromochloromethane ND 1.0 1 ug/L Ethylbenzene ND Bromodichloromethane ND 1.0 1 ug/L 2-Hexanone ND Bromoform ND 1.0 I ug/L Isopropylbenzene ND Bromomethane ND 10 I ug/L p-lsopropyltoluene ND 2-Butanone ND 10 1 ug/L Methylene Chloride ND n-Butylbenzene ND 1.0 I ug/L 4-Methyl-2-Pentanone ND sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND Carbon Disulfide ND 10 1 ug/L Styrene ND Carbon Tetrachloride ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND Chlorobenzene ND 1.0 1 ug/L 1,1,2,2-Tetrachioroethane ND Chloroethane ND 1.0 1 ug/L Tetrachloroethene ND Chloroform ND 1.0 1 uglL Toluene ND Chloromethane ND 10 1 ug/L 1,2,3-Trichlorobenzene ND 2.Chlorotoluene ND 1.0 I ug/L 1,2,4-Trlchlo~obenzene ND 4-Chlorotoluene ND 1.0 I ug/L 1,1,1-Trichloroethane ND Dibromochlommethane ND 1.0 1 ug/L 1,1,2.Tdchloroethane ND 1,2-Dibromo-3-Chloropropane ND 5,0 I ug/L Trichloroethene ND 1,2-Dibromoethane ND 1.0 I uglL Tdchlorofluoromethane ND Dibromomethane ND 1.0 1 ug/L 1,2,3-Trichloropropane ND 1,2-Dichlombenzene ND 1.0 1 ug/L 1,2,4-Trimethylbenzene ND 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3,5-Trimethylbenzene ND 1,4-Dichlorobenzene ND. 1.0 1 ug/L Vinyl Acetate ND Dichlorodifluoromethane ND 1.0 1 uglL Vinyl Chloride ND 1,1-Dichloroethane ND 1.0 1 ug/L p/m.Xylene ND 1,2-Dichloroethane ND 0,50 1 ug/L o-Xylene ND 1,1-Dichloroethene ND 1.0 1 ug/L Methyl-t-Buty~ Ether (MTBE) ND c-1,2-Dichloroethene ND 1.0 I ug/L Ted-Butyl Alcohol (TBA) ND t-1,2-Dichloroethene ND 1.0 I ug/L Diisopropyl Ether (DIPE) ND 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 1,3-Dichloropropane ND ' 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2,2-Dichloropropane ND 1.0 1 ug/L Surrogates: REC (%) Control Qual Surrogates; REC {'%) Limits Dibromofluoromethane 101 84-120 Toluene-d8 94 1,4-Bromofluorobenzene 99 84-108 RI_ DF Qual Units 1.0 I uglL 0.50 1 ug/L 0.50 I ug/L 1.0 I ug/L 10 1 ug/L 1.0 I ug/L 1.0 I ug/L 10 1 ug/L 10 1 ug/L 10 1 ug/L 1.0 I ug/L 1,0 1 ug/L 1.0 1 ug/L 1.0 1 ug/L 1.0 I ug/L 1.0 I ug/L 1.0 1 ug/L 1.0 1 ug/L 1.0 1 ug/L 1.0 1 ug/L 1.0 1 ug/L 10 1 ug/L 5.0 I ug/L 1.0 I ug/L 1.0 1 ug/L 10 I ug/L 0.50 1 ug/L 1.0 I ug/L 1.0 1 ug/L 1.0 I ug/L 10 I ug/L 2,0 I ug/L 2.0 1 ug/L 2.0 1 ug/L ~.ontrol 91-109 Qual ortlng Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501. -_als=cience vironmen tal aboratories, inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page 8 of 10 Lab Sample Date Date Date Client Sample Nurnber Number Collected Matrix Prepared Analyzed QC Batch ID i: ..... .' :1 param, ete[ Result RI. D._.~F Qual Units Parameter Result RI_ D__~F Qual ~ Acetone ND 10 1 ug/L 1 ,l-Dichloropropene ND 1.0 1 ug/L Benzene ND 0.50 1 ug/l_ c-1,3-Dichioropropene ND 0.50 I ug/L Bromobenzene ND 1.0 1 ug/L t-1,3-Dtchloropropene ND 0.50 I ug/L Bromochlorornethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 1 ug/L Brornodichloromethane ND 1.0 1 ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1.0 I ug/L Isopropylbenzene ND 1.0 I ug/L Bromomethane ND 10 I ugfL p-lsopropyltoluene ND 1.0 I ug/L 2-Butano~e ND 10 1 ug/L Methylene Chloride ND 10 I ug/L n-Butylbenzene ND 1.0 1 ug/L 4oMethyl-2-Pentanone ND 10 1 ug/L sec-Butylbenzene ND 1,0 1 uglL Naphthalene ND 10 1 ug/l. tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1.0 I ug/L Carbon Disulfide ND 10 1 ug/L Styrene ND 1.0 1 ug/L Carbon Tetrachlodde ND 0,50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1,0 I ug/L 1,1,2,2-Tetrachioroethane ND 1.0 1 ug/L Chloroethane ND 1.0 I ug/L Tetrachloroethene ND 1.0 I ug/L Chloroform ND t .0 '1 ug/L Toluene ND 1.0 1 ug/L Chloromethane ND 10 1 ug/L 1,2,3-Trichlorobenzene ND 1.0 1 uglL 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4.Trichlorobenzene ND 1.0 1 ug/L 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Trichloroethane ND 1.0 1 ug/L. Dibromochloromethane ND 1.0 I ugJL 1,1,2-Trichloroethane ND 1.0 I ug/L 1,2-Dibromo-3-Chloropropane ND 5.0 1 ug/L Tdchloroethene ND 1.0 1 ug/L 1,2-Dibromoethane ND 1.0 1 ug/L Tdchlorofluoromethane ND 10 1 ug/L Dibromomethane ND 1.0 1 ug/L 1,2,3-Tdchloropropane ND 5.0 1 ug/L 1,2-Dichlorobenzene ND 1.0 1 ug/L 1,2,4-Tdmethylbenzene ND 1.0 1 ug/L 1,3-Dichlorobenzene ND 1.0 I ug/L 1,3,5-Tdrnethylbenzene ND 1.0 1 ugfL 1,4-Dichlorobenzene ND 1.0 1 ug/L Vinyl Acetate ND 10 I ug/L Dichlorodifluoromethane ND 1.0 1 ug/L Vinyl Chloride ND 0.50 I ug/L. 1,1-Dichloroethane ND 1.0 I ug/L p/m-Xylene ND 1.0 1 ug/L 1,2-DichloroebSane ND 0.50 I ug/L o-Xylene ND 1.0 1 ug/L 1,1-Dichloroethene ND 1.0 1 ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ug/L c-1,2-Dichloroethene ND 1.0 1 ug/L Ted-Butyl Alcohol ('F'BA) ND 10 1 ug/L t-1,2-Dichloroethene ND 1.0 1 ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 I ug/L 1,3-Dichloropropane ND 1.0 1 ug/I. Tert-AmyI-Methyl Ether (TAME) ND 2.0 I ug/L 2,2-Dichloropropane ND 1.0 1 ug/L Surrogates: REC (%). Controt ' Qual Surroqates: REC {%) Control Qua! Limits Dibromofl uoromethane 1 O0 84-120 Tol uene*d8 99 91-109 1,4-Bromofluorobenzene 101 84-108 o~ng Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~ra!science ~E~vironmental i--a~to~es, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-151 Analytical Report Date Received: 01113/04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page 9 of Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID 10 Parameter Result RI_ DF Qual .Units Parameter Result R~L DF Qpal Units Acetone ND 10 1 ug/L 1 .l-Dichloropropene ND 1.0 1 ug/L Benzene ND 0.50 1 ug/L c. 1,3-Dichloropropene ND 0.50 1 ug/L Bromobenzene ND 1.0 I ug/L t-1,3-Dichloropropene ND 0.50 1 ug/L Bromochloromethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 1 ug/L Bromodichloromethane ND 1.0 1 ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1.0 1 ug/L Isopropylbenzene ND 1,0 I ug/L Bromomethane ND 10 1 ug/L p-lsopropyltoluene ND 1.0 I ug/L 2-Butanone ND 10 1 ug/L Methylene Chloride ND 10 1 ug/L n-Butylbenzene ND 1,0 1 ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L sec-Buty~benzene ND 1.0 I ug/L Naphthalene ND 10 I ug/L tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1.0 1 ug/L Carbon Disutfide ND 10 1 ug/L Styrene ND 1.0 I ug/L Carbon Tetrachlodde ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 1 ug/L 1,1,2,2-Tetrachloroetha ne ND 1.0 1 ug/L Chloroethane ND 1.0 1 ug/L Tetrachloroethene ND 1.0 1 ug/L Chlorofon~ ND 1.0 1 ug/L Toluene ND 1.0 I ug/L Chloromethane ND 10 I ug/L 1,2,3-Trichlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4-Trichlorobenzene ND 1.0 1 ug/L 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Trichloroethane ND 1.0 1 ug/L Dibromochloromethane ND 1.0 1 ug/L 1,1,2-Tdchloroethane ND. 1.0 1 ug/L 'l,2-Dibromo-3-Chloropropane ND 5.0 1 ug/L Trichloroethene ND 1.0 1 ug/L 1,2-Dibromoethane ND 1.0 1 ug/L Trichlorofluoromethane ND 10 1 ug/L Dibromomethane ND 1.0 1 ug/L 't ,2,3-Trichloropropane ND 5.0 1 ug/L 1,2-Dichlorobenzene ND 1.0 1. ug/L 1,2,4-Trimethylbenzene ND 1.0 1 ug/L 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3, 5--Trimethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene ND 1.0 1 ug/L Vinyl Acetate ND 10 1 ug/L Dichlorodifluoromethane ND 1.0 1 ug/L Vinyl Chloride ND 0.50 1 ug/L 1,1-DlchJoroethane ND 1.0 1 ug/L p/m-Xylene ND 1,0 1 ug/L 1,2-Dlchloroethane ND 0.50 I ug/L o-Xylene ND 1.0 1 ug/L 1,1-Dichloroethene ND 1.0 I ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ug/L c-l,2-Dichloroethene ND 1.0 I ug/L Tert-Butyl Alcohol (TBA) . ND 10 I ug/L t-1,2-Dichloroethene ND 1.0 I ucj/L Diisopropyl Ether (DIPE) ND 2.0 I ug/L 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L 1,3-Dichloropropane ND 1.0 1 ug/L Tert-Amyl-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2-Dichloropropane ND 1.0 I ug/L Surrooates: _REC {%) Control Qual Surrofl. ates: REC (%) _Control Qual Limits Dibromofluoromethane 98 84-120 Toluene-d8 100 91-109 1,4-Bromofluorobenzene 99 84-108 RL - Repoding Limit , DF - Dilution Factor , Oual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 als_cience r_nvironmental j aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Analytical Report Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page 10 of Lab Sample Date Date Date C~ient Sample Number Number Collected Matdx Prepared Analyzed QC Batch ID 10 Parameter Result RI_ D_~F Qual Acetone ND 10 t Benzene ND 0.50 1 Bromobenzene ND 1.0 1 Bromochloromethane ND 1.0 1 Bromodichloromethane ND 1.0 1 Bromoform ND 1.0 1 Bromomethane ND 10 1 2-Butanone ND 10 1 n-Butylbenzene ND 1.0 1 sec-Butylbenzene ND 1.0 1 tert-Butylbenzene ND 1.0 1 Carbon Disulfide ND 10 1 Carbon Tetrachloride ND 0.50 1 Chlorobenzene ND 1.0 1 Chioroethane ND 1.0 1 Chloroform ND 1.0 1 Chloromethane ND 10 1 2-Chlorotoluene ND 1.0 1 4-Chlorotoluene ND 1.0 1 Dibromochloromethane ND 1.0 1 1,2-Dibromo-3-Chloropropane ND 5.0 1 1,2-Dibromoethane ND 1.0 1 Dibromomethane ND 1.0 1 1,2-Dichlorobenzene ND 1.0 1,3-Dichlorobenzene ND 1.0 1 1,4-Dichiorobenzene ND 1.0 1 Dichlorodifluoromethane ND 1,0 1 1,1 -Dichloroethane ND 1.0 1 1,2-Dichloroethane ND 0.50 1 1,1-Dichloroethene ND 1.0 1 c-1,2-Dichloroethene ND 1.0 1 t-1,2-Dichloroethene ND 1.0 1 1,2-Dichloropropane ND 1.0 1 1,3-Dichloropropane ND 1.0 1 2,2-Dlchloropropane ND 1.0 1 Surro,qates: REC (%) Control Qual Limits Dibromofiuoromethane 104 84-120 1,4-Bromofluorobenzene 104 84-108 Units Parameter Result RI.. DF Qual Units ug/L 1,1-Dichloropropene ND 1.0 1 ug/L ug/L c-1,3-Dichloropropene ND 0.50 1 ug/L ug/L t-1,3-Dichloropropene ND 0.50 1 ug/L ug/L Ethylbenzene ND 1.0 I ug/L ug/L 2-Hexanone ND 10 1 ug/L ug/L Isopropylbenzene ND 1,0 1 ug/L ug/L pqsopropyltoluene ND 1,0 1 ug/L ug/L Methylene Chlodde ND 10 1 ug/L ug/L 4-Methyl-2-Pentanone. ND 10 I ug/L ug/L Naphthalene ND 10 I ug/L ug/L n-Propylbenzene ND 1,0 I ug/L ug/L Styrene ND 1.0 I ug/L ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L ug/L 1,1,2,2-Tetrachloroetha ne ND 1.0 1 ug/L ug/L Tetrachloroethene ND 1.0 I ug/L ug/L Toluene ND 1.0 1 ug/L ug/L 1,2,3-Trichlorobenzene ND 1.0 I ug/L ug/L 1,2,4-Trichlorobenzene ND . 1.0 I ug/L ug/L 1,1,1-Tdchloroethane ND 1.0 I ug/L ug/L 1,1,2-Tdchloroethane ND 1.0 1 ug/L ug/L Trichloroethene ND 1.0 1 ug/L ug/L Trichlorolluoromethane ND 10 1 ug/L uglL 1,2,3-Trichloropropane ND 5.0 I ug/I. uglL 1,2,4-Tdmethylbenzene ND 1.0 I ug/L ug/L 1.3,5-Trimethylbenzene ND 1.0 1 ug/L ug/L Vinyl Acetate ND 10 1 ug/L ug/L Vinyl Chloride ND 0.50 1 ug/L ug/L p/m-Xylene ND 1.0 I ug/L ug/L o-Xylene ND 1.0 1 ug/L ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ug/L ug/L Tert-Butyl Alcohol (TBA) ND 10 I ug/L ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L uglL Ethyl-t-Butyl Ether {ETBE) ND 2.0 1 ug/L ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L ug/L Surroqates: REC (%) Control Toluene-d8 101 91-109 orting Limil , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 Qual · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~,~lscience ~ nvironmental i_ aboratories, Inc. Quality Control - Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 120.1 Date Date Duplicate Batch Quality Control Sample ID Matrix Instrument Prepared: Analyzed: Number l~i;~;~il;.::.;;.;:~.:i..i:~:'~:~!:::i:.'::.:..¢ ,:.:.i'.:..::. ;'.. ;=::' :i. ,i;':,:. . :.:; :~:.-i.i':::'!:;' '. '?: ,,~::'" '""" i, · ':, "" :;'::,, ;;i; .... ,' ' Parameter Sample C0nc DUP Conc ~ RPD CL Specific Conductance 950 960 1 0-25 7440 Lincoln Way, Garden Grovel CA 92841-1427 · TEL: (714) 895-5494 · Qualifiers FAX: (714) 894-7501 · ~nvironmental Quality Control - Duphcate I j~aboratories, Inc. _ I Blaine Tech Services, Inc " Date Received: 01/'13/04 20360 Gramercy Place Work Order No: 04-01-0549 · Torrance, CA 90501-1511 Preparation: N/A [] Project: 2401 Oak Street, Bakersfield, CA Meth°d:, EPA 130.2 I Duplicate Batch · Quail' Control Sam le ID Matdx In trument Date Date Number [Y p S~ Prepared: Analyzed: Parameter Sample Oonc DUP Conc RPD PD L Qualifi~r~ I Hardness, Total 98 96 2 0-25 I~~ 7440 Lincoln Way, Garden Grove, CA g2841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 I . ~alscience ~nvironmental ~--ab°ratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 O Quality Control Sample ID Parameter Quality Control - Duplicate 2401 Oak Street, Bakersfield, CA Matrix Samole Conc 6.22 Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 150.1 Date Date Duplicate Batch Instrument Prepared: Analyzed: Number Dup C0nc,. RPD RPD CL 6.22 0 0-25 Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841:1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~.~aiscience ~_nvironmental ~.~ aboratOries, Inc. Quality Control - Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 150.1 Date Date Duplicate Batch Quality Control Sample ID Matrix Instrument Prepared: Analyzed: Number t:i~i~i~);ii!~ ;?!?.~:' ii;'.~! ii:. :i:! ii f':.i,!'.?:-i:i': :~. ?~': ?:' !.:, :i: i: i:i.?.~!i:~-"~: :.:i' ::' :' :i: ?!'f.'-:~.:.!~i:.'.~:~'~i~i!: i:i;i'?i~ii.i~!~.~ ;.': !...:.o~,!.,~,,,~:-. '..: ..,,,r~.~'",~:,. '1 Parameter Sample Cea3_q_ DUP Conq RPD RPD CL~ pH 6,51 6,53 0 0-25 Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~r_als_cience EEpvironmental [J~ aboratories, Inc. Quality Control - Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 160.1 Date Date Duplicate Batch Quality Control Sample ID Matdx Instrument Prepared: Analyzed: Number Parameter Sample C0nc DUP Conc RP._..._~D RPD CL, .qualifier~ Solids, Total Dissolved 270 270 0 0-25 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~alscience ~-__nvironmental ~r---aboratories, Inc. Quality Control - Spike/Spike Duplicate Blaine Tech Services, Inc 20360 Gramercy PEace Torrance, CA 90501-1511 Project: 2401 Oak Streetr Bakersfield~ CA Quality Control Sample ID Matrix Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: N/A Method: EPA 300.0 Date Date MS/MSD Batch Instrument Prepared Analyzed Number Parameter MS %REC MSD %REC %REC CL RPD RPD CL Qualifiers Chloride 100 98 50-150 2 0-25 Nitrate (as N) 101 101 50-150 I 0-25 Sulfate 98 96 50-150 1 0-25 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~F._nvironmental Quality Control - LCSILCS Duplicate ~ aboratories, Inc. Blaine Tech Services, Inc Date Received: N/A 20360 Gramercy Place Work Order No: 04-01-0549 Torrance, CA 90501-1511 Preparation: N/A Method: EPA 300.0 Project: 2401 Oak Street, Bakersfield, CA Date Date LCS/LCSD Batch Quality Control Sample ID Matrix Instrument . Prepared Anatyzed Number Parameter LCS %REC LCSD %REC %REC CL RPD RPD CL Qualifier~ Chloride 101 100 80-120 1 0-25 Nitrate (as N) 102 102 80-120 0 0-25 Sulfate 102 104 80-120 2 0-25 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 Caiscience ~.~ n vironmental ~ aboratories, Inc. Quality Control - Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Quality Control Sample ID Date Received: Work Order No: Preparation: Method: Date Date Matrix Instrument Prepared: Analyzed: 01/13/04 04-01-0549 N/A EPA 351.3 Duplicate Batch Number Parameter ~.ample Conc DUP Conc RPD RPD CL Total Kjeldahl Nitrogen 0.56 0,56 0 0-25 Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~nvironmental Quality Control - Duplicate ~- aboratories, Inc. ,, ' Blaine Tech Services, Inc Date Received: 01/13/04 20360 Gramercy Place Work Order No: 04-01-0549 Torrance, CA 90501-1511 Preparation: N/A Method: SM 2320B Project: 2401 Oak Street, Bakersfield, CA Date Date Duplicate Batch Quality ~trol Sample ID Matrix Instrument Prepared: Analyzed: Number ........ :..::.. ............... ~ ;. ~,.~ ................................. .... ......... ~..., ~.,..,,;,. ..... ......~.,.....:.; ;:.~.,.. ........ ~.: ~:.. ..... ..:.~.....::..:... .......... ,...:........:':,O~:~Ad< Parameter. Sample Conc DUP Conc RPD RPD GL Qualif~r~ Alkalinity, Total (as CaCO3) 56 54 4 0-25 Bicarbonate (as CaCO3) 56 54 4 0-25 Carbonate (as CaCO3) ND ND NA 0-25 Hydroxide (as CaCO3) ND ND NA 0-25 I . /~/~j~/J~ j~ ~j~ 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~alscience ~, nvironmental -~- aboratories, Inc. Quality Control - Spike/Spike Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Streetr,BakersfieldI CA Quality Control Sample ID Matrix Date Received: Work Order No: Preparation: Method: Date Date Instrument Prepared Analyzed 01 / 13/O4 04-01-0549 EPA 3010A Total EPA 601 OB MSIMSD Batch Number Parameter MS %REC MSD %REC %REC CL RPD RPD CL Qualifiers Lead 98 97 80-120 1 0-20 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 FAX: (714) 894-7501 I ~_n vironmental I ~aboratories, lnc. I Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 I Project: 2401 Oak Street, Bakersfiefd, CA I Quality Control sample ID I Parameter Lead I IrCo;~cium Magnesium Sodium I I I i I I I I Quality Control - LCS/LCS Duplicate Date Received: Work,Order No: Preparation: Method: N/A 04-01-0549 EPA 3010A Total EPA 6010B Date Date LCS/LCSD Batch Matrix Instrument Prepared Analyzed Number 101 100 99 98 102 96 95 LCS %REC LCSD %REC %REC CL RPD RPD CL Qualifier8 101 80.120 ~1 0-20 100 80-120 0 0-20 99 80-120 0 0-20 98 80.120 0 0-20 101 80-120 O 0-20 98 80-120 2 0-20 97 80-120 2 020 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~_aiscience ~F-_nvironmental #~ aboratories, Inc. Quality .Control - Spike/Spike Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street~ Bakersfield~ CA Quality Control Sample ID Matrix Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: DHS LUFT Date Date MS/MSD Batch Instrument Prepared Analyzed Number Parameter MS %REC MSD %REC %REC CL RPD RPD CL Qualifiers TPH as Gasoline 90 93 70-112 4 0-17 I I I 7440 Lincoln Way, Garden Grove, CA92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 · ~a!science ~.nvironmental ~-aboratories, Inc. Quality Control - Spike/Spike Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street~ Bak,e[$field~ CA Quality Control Sample ID Matrix Date Received: 01/13/04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: DHS LUFT Date Date MS/MSD Batch Instrument Prepared Analyzed Number Parameter MS %REC MSD %REC %REC CL RP,D RPD CL C~ualifiers TPH as Gasoline 86 90 70-112 4 0-17 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~,-_als_cience ~vironmental ~.- aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-15t 1 Quality Control - LCS/LCS Duplicate Project: 2401 Oak Street, Bakersfield, CA Date Received: N/A Work Order No: 04-01-0549 Preparation: EPA 5030B Method: DHS LUFT Date Date LCS/LCSD Batch Quality Control Sample ID Matrix Instrument Prepared Anaryzed Number I:..~~.!~!,.~.,:. ,i~:~i.:.i~. !~: '", :,i? i:.;i~:.:.::?,~!,.. ?i~.~a~i:.~:...?;~!, i? !,~,~,~'.3~ i..:.~?.:. :,::: ..~,~.~:[.~ .. i:~ .i.., ~?ii~ ii:,:~i~i: ~.-::" :'i' :.?~"~,,, '. i."' -...~ ~:: '] Parameter LCS %REC LCSD %REC. %REC CL RPD RPD CL Qu~31ifiers TPH as Gasoline 98 96 72-114 1 0-10 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~.nvironmental i~l..aboratories, lnc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, ,,CA Quality Control Sample ID Matrix Parameter TPH as Gasoline 96 Quality Control - LCS/LCS Duplicate LCS %REC Date Received: N/A Work Order No: 04-01-0549 Preparation: EPA 5030B Method: DHS LUFT Date Date LCS/LCSD Batch Instrument Prepared Analyzed Number LCSD %REC %REC CL RPD RPD CL Qualifiers 96 72-114 '1 0-10 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 alscience _nvironmental Quality Control - LCS/LCS Duplicate aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: N/A Work Order No: 04-01-0549 Preparation: EPA 5030B Method: - EPA 8260B Date Date LCSfLCSD Batch Quality Contmt Sample 1D Matrix Instrument Prepared Analyzed Number Parameter Benzene Carbon Tetrachloride Chlorobenzene 1,2-Dichlorobenzene 1,1-Dichloroethene Toluene Tdchtoroethene Vinyl Chloride Methyl-t-Butyl Ether (MTBE) TeK-Butyl Alcohol (TBA) Diisopropyl Ether (DIPE) Ethyl.t-Butyl Ether (ETBE) Tert-AmyI-Methyl Ether (TAME) Ethanol LCS %REC LCSD %R. EC %REC CL RPD RPD CL 96 96 67-117 0 0-5 103 101 77-137 2 0-9 98 98 89-113 0 0-5 99 99 90-114 0 0-8 108 104 81-129 4 0-15 98 97 BB-118 2 0-71 100 98 67-121 1 0-21 101 99 71-131 3 0-34 104 97 65-125 6 0-49 110 95 38-140 15 0-98 96 93 77-119 2 0-53 100 98 73-121 2 0-31 99 96 71 - 119 3 0-33 101 90 54-132 12 0-55 Qualifiers 7440 Lincoln Way, Garden Grove, CA92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 I ,I ! I I I I I I I I ~-aiscience ~F-n_vironmentai Quality Control - LCS/LCS Duplicate E--aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: N/A Work Order No: 04-01-0549 Preparation: EPA 5030B Method: EPA 8260B Date Date LCS/LCSD Batch Quality Control Sample ID Matrix Instrument Prepared Analyzed Number Parameter LCS %REC L¢$D,%REC %REC CL RPD RPD CL Benzene 94 94 87-117 1 0-5 Carbon Tetrachlodde 109 107 77-137 I 0-9 Chlorobenzene 98 100 89-113 I 0-5 1,2-Dichlorobenzene 100 100 90-114 1 0-8 1,1 -Dichloroethene 113 106 81-129 6 0-15 Toluene 96 97 88-118 I 0-71 Trichlor0ethene '103 105 67-121 2 0-21 Vinyl Chloride 97 90 71-131 8 0-34 Methyl-t-Butyl Ether (MTBE) 103 106 65-125 2 0-49 Ted-Butyl Alcohol (TBA) 84 89 38-140 5 0-98 Diisopropyl Ether (D[PE) 94 92 77-119 2 0-53 Ethyl-t-Butyl Ether (ETBE) 101 101 73-121 1 0-31 Tert-AmyI-Methyl Ether (TAME) 98 99 71-I 19 1 0-33 Ethanol 70 93 54-132 27 0-55 Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 I I I I I I I I I I I I I I I I ~-alscience ~--- _n vironmental · ~--aboratories, inc. Quality Control - Spike/Spike Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 2401 Oak Street~ Bakersfield~ CA Project: Quality Control Sample iD Matrix Date Received: 01/13~04 Work Order No: 04-01-0549 Preparation: EPA 5030B Method: EPA 8260B Date E~ate M~/~SD B;tch Instrument Prepared Analyzed Number Parame. ter MS %REC MSD %REC %REC CL RPD RPD CL Q~ualifiers Benzene 94 95 84-120 0 0-13 Carbon Tetrachloride 102 106 72-132 3 0-15 Chlorobenzer{e 98 99 87-117 I 0-12 1,2-Dichlombenzene 98 99 86-116 I 0-13 1,1-Dichloroethene 106 104 77-137 I 0-15 Toluene 96 96 85-121 0 0-15 Trichtoroethene 99 100 66-120 1 0-13 Vinyl Chloride 96 99 68-140 3 0-'~6 Methyl-t-Butyl Ether (MTBE) 98 106 68-128 7 0-18 Tort-Butyl Alcohol (TBA) 97 119 30-156 21 O-Z6 Diisopropyl Ether (DIPE) 92 94 75-123 3 0-14 Ethyl-t-Butyl Ether (ETBE) 98 102 66-132 4 0-33 Tert-AmyI-Methyl Ether (TAME) 96 100 59-131 4 0-47 Ethanol 91 108 20-176 17 0-42 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 J rnvironmental Quality Control - Spike/Spike Duplicate Blaine Tech Services, Inc Date Received: 01/13/04 20360 Gramercy Place Work Order No: 04-01-0549 Torrance, CA 90501-1511 Preparation: EPA 5030B Method: EPA 6260B Project: 2401 Oak Street, Bakersfield, CA , Date Date MS/MSD Batch Quality Control Sample ]D Matrix Instrument Prepared Analyzed Number Parameter MS %REC MSD %REC %REC CL RPD RPD CL Qualifiers Benzene 95 93 84-120 2 0-13 Carbon Tetrachl0ride 111 105 72-132 5 0.15 Chlorobenzene 100 99 87-117 1 0-12 1,2-Dichlorobenzene 99 99 86-116 0 0-13 1,1-Dichloroethene 117 108 77-137 8 0.15 Toluene 94 95 85-121 0 0-15 Trichloroethene 104 104 66.120 0 0-13 Vinyl Chloride 98 96 68-140 2. 0-16 Methyl-t-Butyl Ether (MTBE) 106 104 68-128 2 0-18 Ted-Butyl AlcohoJ (TBA) 84 95 30-156 13 0-26 Diisopropyl Ether (DIPE) 95 91 75-123 4 0-14 Ethyl-t-Butyl Ether (ETBE) 102 99 66-132 3 0.33 Tert-Amyl-Methyl Ether (TAME) 97 97 59-131 0 0-47 Ethanol 72 79 20-176 10 042 I~ 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~_als_cience ~-_ nvironmental ~ abOratories, Inc. Glossary of Terms and Qualifiers Work Order Number: 04-01-0549 Qualifier Definition D E ND The sample data was reported from a diluted analysis. Concentration exceeds the calibration range. Not detected at indicated reporting limit. 7440 Lincoln Way, Garden Grove, CA 92841-1427 · TEL: (714) 895-5494 · FAX: (714) 894-7501 WORK ORDER #: Cooler I of / SAMPLE RECEIPT FORM' CLIENT:~ ~~_._,~ ~ TEMPERATURE - SAMPLES RECEIVED BY: CALSClENCE COURIER: ~ Chilled, cooler with temperature blank provided. cchilled, cooler without temperature blank. hilled and placed in cooler with wet ice. __ Ambient and placed in cooler with wet ice. __ Ambient temperature. _._~_ o C Temperature blank.. CUSTODY SEAL INTACT: Sample(s): __ Cooler:__ No (Not In~act) ' LABORATORY (Other than Calscience Courier): __ ° C Temperature blank. ° C IR thermometer. SAMPLE CONDITION: Yes Chain-Of-Custody document(s) received with samples ......................... ~ ....... __ Sample container label(s) consistent with custody papers ..................... ,,~--~.. ...... __ Sample container(s) intact and good condition ........ ~ .......................... ~. ...... __ Correct containers for analyses requested ......................................... / ....... Proper preservation noted on sample label(s) .......................... · ........... f Tedlar bag(s) free of condensation .......................................................... COMMENTS: __ Ambient temperature. Initial: Not Applicable (N/A): Initial: No N/A SHELL Chain Of Custody Record ~.b,,er~,,~,on (,r ~=~): Shell Project Manager to be invoiced: ...... .................. ..~... ............ ~.. Blaine Tech Se~lces, Inc. BTST 2401 Oak Street, Bakersfield Pending 20360 Gramercy Place, Torrance, CA 90501-15~1 ~CT co~c~ ~-~v ~"~.~ ~}: Brltney O underso~ 626-256-66~ b~underson~d~l~aenv.com BTS TURNAROUND TIME (~SINESS DAYS): ~ to ~AYS ~ ~A~ D ~ ~OU~ ~ ~ HOU~ D ~ HOUND LE~T~N ~ ~OU~ REQUESTED ANALYSIS ~ ~-RW~B RE.ATilT ~ U~AG~: Genera[ Minerals ' ' ~ - ~ FIELD NOTES: GC/MS MT~ CONFIR~ON:. HIGHE~ ~HIGHE~ per ~Rl~ , ~L ~ ~ ~ ~ ~ Co.~iner~r.e~ative SPECIAL INSTRUCT~NBO~'NoTEs: 'CHECK~XIFEDDIS~EED~ ~ [ ~ ~ ;~ ~ ~ ~ ~ or PlO Readlngs HN~ poly's were fleta filtered prior to prfle~ation ; .- .° ~ ' ~ --~ ~ ~ ~ or Labomto~ Not. ~.~[~Field Sample IdentEication M~.~ .... . ._ SHELL Chain Of Custody Record Lab Identlfic~tlon (1! necessary): Shell Project Manager to be invoiced: Blaine tech Se~lces, Inc. BTST 2401 Oak Street, Bakersfield Pending  . "' ~: " '- I ~0~T~.o~' 20360 Gramercy Place, Torrance, CA 90~1-1Sll ' , mo~m ~T (~v ~ ~ ~e~ ~): Briery Gunderson 626-256~662 bgunderson~delt ~nv.com JBTS Nick Sudano s~P~ ~u~ {~: . 310-782-2465 310-782-2958 nsudano~blainet ech.com ~[~ ~ TURNAROUND TiME (BUSIN~S~ DAYS): ~ [0 DAYS ~ 5 DAYS ~ ~ HOU~ ~ 48 HOU~ ~ ~4 ~U~ ~S~ 2~ ~U~ REQUESTED ANALYSIS ~ ~ - R~ RE~RT ~AT ~ U~ AG~: Genial Minerals B~SMTaE~NFIR~TION:HIGHE~ HIGHE~.rBOR, NG .... ~L .... ~ ~ ~~ ~ FIELD NOTES: SPECIAL INSTRUCTIONS OR NO~S: ' CH~CK ~X IF E~ IS ~ NEEDED ~ ~ ~ ~ -: g ~ ~ { ,. Conainar~r. ew~lVOor PlO readings 'Must state whether bicarbonate Is reposed as elthe~ calcium car~n~e [ DATE ~ME ~:~'~ DISTRI~TION: ~i/e ~ ~1 t~ ~ean t0 Far. Y~10w ~n( ~ lO ~OR~