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Home My WebLink AboutUNDERGROUND TANK (6)Terry Tamminen Secretary for Environmental California RegionalcentralWatervalleyQUalitYRegion Control Board Fresno Branch Office Arnold Schwarzenegger Intemet Address: http://www.svn'cb.ca.gov/-rwqcb5 Governor 1685 E Street, Fresno, California 93706-2020 Phone (559) 445-5116. FAX (559) 445-5910 30 March 2004 Regional Board Case No. 5T'15000885 Mr. Tony Palagyi Shell Oil Products U.S. 2555-T3 th--Avenu, e- SW ............................... Seattle, Washington 98134 UNDERGROUND TANK RELEASE, TEXACO SERVICE STATION, 240! OAK STREET, BAKERSFIELD, KERN COUNTY You submitted Fourth Quarter 2003 Groundwater Monitoring Report (Monitoring Report) dated 2 February 2004 and Site Assessment Report (Assessment Report) dated 20 February 2004. Delta Environmental Consultants, Inc., Monrovia (Delta) prepared the Monitoring and Assessment Reports. The Monitoring Report documents a quarterly groundwater monitoring event at the above-referenced site on 21 October 2003. The Assessment Report summarizes investigation conducted on 5 February 2004. Low concentrations of hydrocarbons not matching the diesel standard were detected in soil samples from borings lateral to the diesel and gasoline underground storage tanks (USTs). Analytes were not detected in samples collected during the fourth quarter 2003 groundwater monitoring event. Previous subsurface soil investigation and groundwater monitoring indicates that gasoline- and diesel- range petroleum hydrocarbons and the fuel oxygenate methyl tertiary butyl ether (MTBE) leaked at the subject facility degrading soil and that MTBE has degraded groundwater. We conclude that previous site investigations suggest that higher hydrocarbon concentrations may exist beneath the UST systems, but that the general absence of analytes detected during groundwater monitoring events and the very shallow-depth to-groundwater suggest that a significant mass of impacted soil is not-present beneath the UST systems. We do not request additional site investigation. Continue quarterly groundxvater monitoring during the first and second quarters of 2004. "Full scan" EPA Method 8260 and dissolved lead analyses may be discontinued. General minerals, nitrate and total Kjeldahl nitrogen analyses may also be discontinued provided that these analyses were conducted during the first quarter 2004. Summaries of the Monitoring and Assessment Reports and our comments follow. Monitoring Report Summary Blaine Tech Services, Inc., San Jose (Blaine Tech) collected groundwater samples from monitoring wells MW-1 through MW-5 on 21 October 2003. Depth-to-groundwater was measured from 19.89 to 24.57 feet below the tops of the casings (below TOC). Groundwater flow direction was toward the south with a water table slope of 0.006 feet per foot. California Environmental Protection Agency Recycled Paper Mr. Tony Palagyi - 2 - 30 March 2004 The samples were analyzed for total petroleum hydrocarbons as gasoline (TPH-g) by EPA Method 8015M, and for the analytes that typically comprise a "full scan" EPA 8260B analysis, including benzene, toluene, ethylbenzene, and xylenes (BTEX), MTBE, TBA (tertiary butyl alcohol), di-isopropyl ether (DIPE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), 1,2-dichloroethane (1,2-DCA) and 1,2-dibromoethane (EDB) by EPA Method 8260B. The samples were also analyzed for dissolved lead by EPA Method 6010B. No analytes were detected in the samples. MTBE was detected in MW-3 at 17 p.g/L during the 18 June 2003 monitoring event. Other analytes were not detected during the 18 June 2003 event. MTBE was detected in MW-4 at 3.4 gg/L during the 3 September 2003 event. Other analytes were not detected during that event. Assessment Report Summary DeltaArilled_barings_SB=Lthro. ugh. SB:32o_ a_maximurn_depth_o f. approximately_3.1_feet bel~w-g.r-ound surface (bgs) using direct-push technology on 5 February 2004. Soil samples were collected at five-foot intervals. Delta logged soils encountered as poorly-graded sands with interbedded layers of sandy silt, silty sand, and clayed silt. Groundwater was encountered at approximately 23.5 feet bgs. Soil samples were analyzed in the laboratory for TPH-g and TPH-d by the DHS LUFT Method, and BTEX and the fuel oxygenates MTBE, TBA, TAME, D~E, ETBE, and ethanol by EPA Method 8260B. Analytes were not detected in SB-1. TPH-d was detected from 5.2 to 390 milligrams per kilogram (mg/kg) in four of five samples collected from SB-2. TPH-d was detected at 5.2 mg/kg in one of the five samples collected from SB-3. Other analytes were not detected in SB-2 and SB-3. Laboratory analytical reports note that chromatographic patterns for these detections do not .match the diesel standard. Delta suggests that TPH-d detections may result from natural compounds present in subsurface soils. Comments A release from the underground storage tank (UST) system has contaminated soil and degraded groundwater quality beneath the site. Previous soil and groundwater investigation was summarized in KHM Environmental Manag_eme__n.t_'s.' G~RA_.SP Site Assessment Report dated 9 May 2003. Low concentrations of TPH-g, TPH-d, MTBE, and TBA were detected in subsurface soils .at sampling point~ adjacent to the gasoline and diesel UST systems. Low concentrations of MTBE were detected in groundwater samples collected from on-site monitoring wells during previous groundwater monitoring events. With one exception, MTBE has not been detected in groundwater during the last two monitoring events. Low concentrations of TPH-d were also detected in soil samples collected from borings adjacent to the diesel and gasoline USTs during the 5 February 2004 investigation. Chromatographs for these detections do not match standard diesel chromatographs and TPH-g and other analytes were not detected. Delta suggests that the TPH-d detections result from natural compounds in subsurface soil. This hypothesis is possible, but should be verified by detections of the same natural compounds in background soil samples. We presently conclude that soil and groundwater investigations conducted lateral to the diesel and gasoline UST systems suggest the possibility of higher petroleum hydrocarbon concentrations beneath V:\UGTkProjectsklDW_filesk2004 C0rrespondencekCity of Bakersfield Cases\Texaco Sm OakSt GW-SA 3-04.doc Mr. Tony Palagyi - 3 - 30 March 2004 the systems. However, we also conclude that a significant mass of impacted soil beneath the UST systems is unlikely based on the shallow depth to groundwater (approximately 16 to 24 feet bgs) and the general absence of analytes detected during groundwater monitoring events. We do not request that you conduct additional site assessment. We request that you continue groundwater monitoring during the first and second quarters of 2004. Analysis by "full scan" EPA Method 8260 and dissolved lead may be discontinued since these analyses were conducted during the third and fourth quarters of 2003 and analytes were not detected. Continue analysis for TPH-g, TPH-d, BTEX, and the fuel oxygenates MTBE, TBA, DIPE, ETBE, and TAME. By our letter dated 6 January 2004, we requested that you conduct general minerals, nitrate, and total Kj eldahl nitrogen analyses during two non-consecutive quarters to characterize groundwater quality. You were ~6' c-ofidflct-thes~ analyses on samples from a~ least one upgradient and two d0wngradient monitoring wells. You conducted these analyses during the third quarter 2003. We requested that you conduct these analyses again during the first quarter 2004. Provided that you conducted these analyses during the first quarter 2004, these analyses may be discontinued. Please submit the First Quarter 2003 Groundwater Monitoring Report by 3 May 2004. As of the date of this letter, soil and groundwater sample analytical data have not been uploaded to Geotracker. We note that Delta has uploaded wellhead horizontal and vertical positioning data (GEO_XY and GEO_Z files), depth-to-water measurements (GEO_WELL files), and site maps (GEO_MAP files). Please contact this office at least five days prior to fieldwork. If you have any questions regarding this correspondence, please contact me at (559) 445-5504. / JOHN D. WHITING Engineering Geologist R.G. No. 5951 c: Ms. Barbara Rempel, SWRCB, UST Cleanup Fund, Sacramento~ . Mr. Howard H. Wines HI, Bakersfield Fire Department, Bakersfield'O Mr. Bradley E. Clark, Delta Environmental Consultants, Inc., Monrovia File: UST/Kern/Texaco Service Station, 2401 N. Oak St., Bakersfield/5T15000885 V:\UGTXProjectsklDW filesX2004 Correspondence\City of Bakersfield Cases\Texaco Sm OakSt GW-SA 3-04.doc I Delta I Environmental Consultants, Inc; Solving environment-related business problems worldwide www. deltae~v, corn I' 911 South Primrose Avenue · Suite K ' Monrovia, California 91016 USA I ' 626.256.6662 800.477.7411 ~ ' Fax 626.256.6263 ' I February 2, 2004 Proj eot PA2401 O- 1 I Mr. John D. Whiting California Regional Water Quality Control Board Central Valley Region I 1685 E Street Fresno, California 93706-2020 I Re: FOURTIt QUARTER 2003 GROUNDWATER MONITORING REPORT Texaco Service Station 2401 Oak Street - I Bakersfield, California - D~ar Mr. Whiting: ' 'l On behalf of Equilon Enterprises LLC dba Shell Oil Products (SI-~LL); Delta Environmental Consultants, Inc. (DELTA) [formerly KHM Env/ronmental Management, Inc. (KHM)] has prepared this Fourth Quarter 2003 Groundwater Monitoring Report for the above referenced site. . I This quarterly report represent DELTA's professional opinions based upon the currently available information and are arrived at in accordance with currently acceptable professional standards. This report is based upon a specific I scope of work requested by the client. The Contract between DELTA and its client outlines the scope of work, and only those tasks specifically authorized by that contraci or outlined in this report were performed. This report is intended only for the use of DELTA's Client and .-anYone else specifically listed on this report. DELTA will not I and-cannot'be liable for unauthorized reliance by an~ other third party. Other than as contahaed ~, this paragraph, DELTA makes no express or implied warranty as to the coments of tiffs report. I/you have any queslions regarding this site, please contact Brad Clark (DELTA) at (626) 256-6662 or I Tony Palagyi (SHELL).at (425) 3'77-8530. . ' - : Sincerely, : -~ ' I Delta Environmental Consultants, Inc.' C"~'I /' '- i I ,~athryn Ewing~'~' Bradley E. Clark, P.E. ~ Project Geologi st S eni or Project Engineer cc: Tony Pa/agy/Shell O//Products US I Howard H. Wines 1II, City of Bakersfield F/re Department ~ ~.~ o~- I I I I I I I I I I I I I I I I I I SHELL QUARTERLY STATUS REPORT February 2, 2004 Station Address: DELTA Project No. SHELL Environmental Engin./Phone No.: DELTA Site Manager/Phone No.: Primary Agency/Regulatory ID No.: ' Other Agencies to Receive Copies: 2401 Oak Street, Bakersfield, California PA2401 O- 1 Tony-Palagyi/(425) 377-8530 Kathryn Ewing/(626) 256-6662 Central Valley RWQCB / John Whiting City of Bakersfield Fire Dept./Howard H. Wines llI WORK PERFORMED TInS QUARTER ,(-FOURTH - 2003): 1. Quarterly groundwater monitoring and sampling. Submitted quarterly report. 2. Received approval of no-purge sampling in a letter from CVRWQCB dated October i0, 2003. 3. Received work plan approval from CVRWQCB in a letter dated October 21, 2003. 4. Submi'tted Health and Safety Plan dated November 21, 2003 per CVRWQCB request. WORK PRO?OSED FOR NEXT QUARTER (FroST - 2004): 1. Quarterly groundwater monitoring and sampling. Submit quarterly report. 2. Implement no-purge sampling per CVRWQCB letter dated October 10, 2003. 3. Implement approved Work plan per October 21, 2003 approval letter. Current Phase of Project: Groundwater monitoring Frequency of Sampling: Quarterly Frequency of Monitoring: Quarterly Is SeparatePhase Hydrocarbon Present On-site (Well #'s): [] Yes [] No cUmulative SPH Recovered to Date: NA SPH Recovered This Quarter: None Sensitive Receptor(s) and Respective Direction(s): Nearest field verified well is Well BK060-02 (State Well Current Remediation Techniques: Permits for Discharge: Approximate Depth to Groundwater: Groundwater Gradient Current Agency CorrespondenCe: Summary of Unusual ~Activity: No. 29S/27E-25D02M) of the California Water Service Cgmpany in Bakersfield approximately 759 feet East of the site. NOne None 19.89' to 24.57' South ~ approximately 0.0063 ft/ft CVRWQCB letter dated January 6, 2004. .None Kathryn Ewing Site Manager (DELTA) I ATTACltlZ~D: · Table 1 - Historical Groundwater Gauging and Analytical Results · Table 2-- Additional Chemicals o£ Concern · Figure 1 - Site Location Map · Figure 2 - Groundwater Elevation Contour Map · Figure 3 - Hydrocarbon Distr/bution in Groundwater Map · Figure 4 - TPH-g Concentrations in Groundwater Map · Figure 5 - Benzene Concentrations in Groundwater Map · Figure 6 - MTBE Concentrations in Groundwater Map · Appendix A- Field Data Sheets · Appendix B - Field Procedures · Appendix C - Waste Disposal Document · Appendix D - Laboratory Report and Chain-of-Custody Documents I I I I I I I I I I I I I I I I I I TABLES h-~¥O-I~C~-~OUNOWATER GAUGING AND ANALYTICAL DATA -:.:.O~TE:4.:.:.:OF, F1H:':':.:.:'~:. :::::::::::::::::::::::::::~:~:~:~m~:~:~: ............:.:.:~....:.:.~t):.:.:.:.:~:.~[e~:.:~:.:.:.:.m.~sb)~:.:.:.:.:.~g~:.:.:.:.:~.:.:.:.:.~{~¢):.:. ~-1 ?oE~f 3/18/2003 26.81 0.00 375.22 3/2~/2003 28.19 0.00 373.84 ~<1000 ~D<50 ~0,50 6/18/2003 17.70 0.00 384.33 ~<50 ~<0,50 ~/3/2003 16.33 0.00 385.70 ~50 ND<O,50 10/21/2003 21.63. - 0.00 380.40 ND<50 ND<0,50 MW-2 Top of casing elevation (fl): 404.49 3/18/2003 29.70 0.00 374.79 3/25/2003 31.02 0.00 373,47 ~<1000 660 ~<0,50 6/18/2003 20.79 0.00 383.70 ND<50 ~0,50 9/3/2003 19.31 0.00 385.18 ~<50 ~0,50 10/21/2003 24.57 0.00 379.92 ~<50 ~<0,50 MW-3 'T~p o~casing elevation (ft): 403.43 3/18/2003 28.94 0,00 374.49 3/25/2003 30.27 0.00 373~16 ND<I000 72 ~<0.50 6/18/2003 20.98 0.00 382.45 N~50 ND<0.50 9/3/2003 19.0~ 0.00 3~4.42 ~<50 ~<0,50 10/21/2003 23,89 0.00 379.54 ND<50 ~<0,50 MW-4 Top of casing elevation (ft): 400.11 3/19/2003~ 25.42 0.00 374.69 3/25/2003 26.75 0.00 373.36 ~<1~0 ~<50 ~<0.50 6/18/~003 17.31 0.00 382.80 ~<50 ~<0.50 9/3/2003 15.43 0.00 384.68 ~<50 ~0.50 10/21/2003 20.34 0.00 379.77 ~<50 ~<0.50 MW-5 Top 3/19/2003 25.03 0.00 374.88 3/25/2003 26.38 0.00 373.53 ~1000 ND<50 ~<0.50 6/18/2003 16.72 0.00 383.19 ~50 ~0.50 _~/3/~0~__ ___~5~28 0.00 ~ 384.63 ~<50 ~<0.50 10/21/2003 19.89 0.00 380.02 ~ ~<50 ND<0.50 Notes: GW - Groundwater SPH - Separate-phase hydrocarbons TPH-D - Total pe~oleum hydroc~bons as dies~ TPH-G - Total petroleum hydroc~bons ~ g~oline MTBE - Methyl-te~ buWl ether ET~E- E~yt-te~ bu~J et?r _ TAME - Te~-myl me~yl e. ~er , Su~ey data Page I of I ADDITIONAL CHEMICALS OF CONCERN -- TEXACO SERVICE STATION I __ 2401 Oak Street, Bakersfield, California 9/3/2003 ND<10- ND<0.10 0.42 17 ND<0.50 50 50 ND<I.0 ND<I.0 ND<0.01 16.2 ND<0.I 3.63 1.63 29.9 ND<0.005 240 66 6.21 150 MW-2 9/3/2003 NA N~ NA HA NA NA NA NA NA ND<0.01 NA NA N~ NA NA NA NA NA NA NA MW-3 9/3/2003 19 ND<0.10 1.50 20 ND<0.50 56 56 ND<I.0 ND<LO ND<0.01 15.7 0.107 4.06 1.66 31.9 ND<0,005 230 74 6.23 130 MW4 9/3/2003 19 ND<0.10 0.95 ~ 0.56 - 66 66 ND<I.0 ND<I.0 ND<0.01 16.7 0.6 4.14 1.99 33.1 0.0467 250 74 6.1~- 150 9/3/2003 NA NA NA NA NA NA NA -- ~A NA ND<0.01 HA N~ NA HA HA NA NA NA NA NA Notes: TKN - Total Kje(d--ahl Nitr~ogen -- _ -- -- -- TDS - Total Dissolved Solids NA - No~t~ __ __ __ NOTE: Additional Chemicals of Concern Analysis are only for the first and third q~uarters. Page I of 1 FIGURES 119~04'00'' W 119~03'00'' W 119o02'00" W ~VG$84 119~01'00'' W ~ ,~%~. ~ SITE LOCATION 119004'00'' W 119°03'00" ~ 5 119002'00" Wl~~ WGSB4 119°01'00'' W P~ed from TOPOI ~l N~ G~p~ Ho~ (~.to~o~ A D E LTA s~.. o~ ~oouc~s us ~, E~IRONME~ TEMCO SPRUCE STATION ~////A CONSULTING INC. BAKERSFIELD, CALIFORN~ FIGURE SITE LOCATION MAP 240~ OAK STREET BAKERSFIELD, CALIFORNIA m DE~SEL TANK SLAB PLANTER .SERVA~ON WELL MW-2 (5'/9.92', TRASH- OFFICE AND ~ MW-1 MW-5 OISPENSER ISLAND (TY~) SLAB PLANTER LLJ ~ ~ :~80.20 CANOPY/ LEGEND N MW-1 ~- GROUNDWATER MONITORING WELL LOCATION ANDDESIGNA]]ON (;,','380.40) GROUNOWATER ELEVATION IN FEET ABOV~ MEAN SEA LEVEL (Ft/MSL) 379'.60---- GROUNDWATER CONTOUR IN FEET ABOVE MEAN SEA LEVEL (Ft/MSL) CONTOUR INTERVAL~O,20 EEET APPROXIMATE GROUNDWATER FLOW DIRECTION 0 30 60 SCALE IN FEET ,Delta . ENVIRONMENTAL CONSULTANTS INC. SHELL OIL PRODUCTS US TEXACO SERVICE STATION BAKERSF(ELD, CAUFORNIA FIGURE 2 GROUNDWATER ELEVATION CONTOUR MAP 10/21/03 2401 NORTH OAK STREET BAKERSFIELD, CALIFORNIA \\Server\khm_data\Clients~.Shell~-Shell Sites\2\2'~01 Oak\2004-02-0214Q03 (~uartedy Report\FIGURE 2(2401)_GROUNDWA'rER ELEVATION CONTOUR MAP.dwg, Model, 1/28/2004 12:02:32 PM MW-1 DATE TPH-g BENZENE MTI3E (.m/L) tug/L) O~/L) 03/25/03 ND<50 ND<0.50 ND<I.0 06/18/03 N0<50 ND<O.50 ND<I.0 09/03/03 ND<50 ND<0.50 ND<I.0 10/21/03 ND<50 ND<O. bO ND<I.0 OEISEL TANK SLAB -- PLANTER MW-2 MW-2 (~YL~ BENZENE MTBE (JJg/,L) (Jug/L) 680 NO<O.§O ND<I.0 ND<50 ND<O,50 ND<I.0 ND<bO ND<O,50 ND<I.O ND<50 ND<0.50 ND<I.0 EXISTING OBSERVATION WELL DISPENSER 'ISLAND (TYP) OFFICE AND CASHI BOOTH PLANTER W Ld 0 MW-5 BATE ' ~PH- BENZENE MTBE CuB/~-t CuB/L) O-'g/L) 03/25/03 ND<50 NO<0.50 40 06/18/03 ND<50 ND<0.50 ND<I,O 09/03/03 ND<50 ND<0.50 ND<I.0 10/21/03 ND<5O ND<0.50 ND<l,0 I MW-4 BATE ll~R-g BENZENE MTBE (,ug/L) Od(J/L) O Jo/L) ~3/25/05 ND<50 ND<0.50 7,3 06/18/03 N0<50 ND<0.50 Ng<I,O 09/03/05 ND<50 ND<0.50 3.4 !0/21/03 ND<50 ND<0.50 ND<I.0 MW-3 I LECEND MW-1 TPH-g MTBE JJg/L ND< GROUNOWATER MONITORING WELL LOCATION AND DESIGNATION TOTAL PETROLEUM HYDROCARBONS AS GASOLINE METHYL TERT-BU~FYL ETHER MICROGRAMS PER LITER NOT OETECT~D ABOVE LIMIT NOTED 0 30 60 SCALE IN FEET ,Delta ENVIRONMENTAL CONSULTANTS INC, SHELL OIL PRODUCTS US TEXACO SERVICE STATION BAKERSF[ELO, CALIFORNIA FIGURE 3 HYDROCARBON DISTRIBUTION IN GROUNDWATER MAP 240t NORTH OAK STREET BAKERSFIELD,. CALIFORNIA \\Server\khm_data\Cllents~_shell~.bhell GRASPS_GRASP Sites\2401 Oak\2004-XX-X_4Q03 Quarterly Report¥:lGURE 3(2401)_HYDROCARBON DISTRIBUTION IN GW MAP.dwg, Model, 12/7/2003 3:25:17 PM DEISEL TANK SLAB PLANTER MW-2 EXISTING '"'~ERVATION W~LL ISLAND (T~P) TRASH OFFICE AND ~i~ MW-1 CASHI BOOTH SLAB PLANTER LEGEND MW-14~- I'-- GROUNDWATER MONITORING WELL ELi LOCATION AND DESIGNATION ~---- (ND<50) TPH-g CONCENTRATIONS IN I fJ~ MICROGRAMS PER LIaR N'" TPH-g TOTAL PETROLEUM HYDROCARBONS CANOPY0<~ AS GASOLINE NO<, NOT DETECTED ABOVE UMIT NOTED -5 D<50) 0 50 60 SCALE IN FEET Delta ENVIRONMENTAL CONSULTANTS INC. SHELL OIL PRODUCTS US TEXACO SERt4CE STATION BAKERSFIELD, CALIFORNIA FIGURE 4 TPH-g CONCENTRATIONS tN GROUNDWATER MAP lo/2~/o~ 2401 NORTH OAK STREET BAKERSFIELD, CAUFORNIA \\Server\khm_data\Cllents~_Shell~.Shell GRASpS_GRASP Sites\240t Oak\2004-XX-X_4(~03 (~uarterly Report~-lGURE 4(2401)_1PH~j CONCENTP, A'FiON MAP.dwg, Hodel, 12/8/2003 5:52:57 PM I II DEISEL TANK SLAB PLANTER MW-2 TRASH BOOTH OFFICE AND Ld CANbPY 0<:~ -5 LEGEND MW-I~;' GROUNDWATER MONITORING WELL LOCATION AND DESIGNATION NO<0.50 BENZENE CONCENTRATIONS IN MICROGRAMS PER LITER Om/L) ND< NOT DETECl~O ABOVE LIMIT NOTED EXISTING '"'"-,,...~ER VA TIO N WELL DISPENSER ISLAND (TYP) · ~. SLAB PLANTER 0 30 60 SCALE IN FEET Delta ENVIRONMENTAL CONSULTANTS INC. SHELL OiL PRODUCTS US TEXACO SERVICE. STATION BAKERSFIELD CALIFORNIA FIGURE 5 BENZENE CONCENTRATIONS IN GROUNDWATER MAP 2401 NORTH OAK STREET BAKERSFIELD, CALIFORNIA \\Se~,er\khm_data\Cllents~hell~_Shell GRASpS_GRASP Slte$\2401 Oak\2004-XX-X_4Q03 Quarterly Report\FIGURE S(2401)_BENZENE CONCENTRATION MAP.dwg, Model, 12/2/2003 3:41:14 PM DEISEL TANK SLAB ' · PLANTER MW-2 OFFICE AND ~1~ MW-1 CANOPYI 'l Ld EGEND Mw-~e ND<hO MTBE ND< S GROUNDWATER MONITORING WELL LOCATION AND DESIGNATION MTBE CONCENTRATIONS IN MICROGRAMS PEr LITER METHYL TERT-BUTYL ETHER NOT DETECTED ABOVE LIMIT NOTED EXISTING ~.~ERVATION ~LL PLANTER DISPENSER ISLAND (TYP) SLAB \\Server\khm_data\Cllents~_Shell~_Shell GRASPS_GRASP Sites\24ot Oak\Z004-X~-X_4QO3 Quarterly Repott~F]GURE 6(2401)_I~E 1SOCONCENTRA~ON HAP,dwg, Hodel, 12/2/2003 3:44:53,PH O 30 60 SCALE IN FEET ADelta ENVIRONMENTAL CONSULTANTS INC. SHELL OIL PRODUCTS US TEXACO SERVICE STATION BAKERSFIELD, CALIFORNIA FIGURE 6 MTBE CONCENTRATIONS IN GROUNDWATER MAP 1 O/21 2401 NORTH OAK STREET 8AKERSFIEI~D, CALIFORNIA I I I I I I I I I I I I ;, APPENDIX A FIELD DATA SHEETS I WELLHEAD INSPECTION CHECKLIST Page __ I of Client Site Address Job Number Date Well Inspected No Corrective Well ID A~,on Re.uire,~ Technician ~'~o~, ~. Other Action Wager Bailed Wellbox Cap Lock Taken From Components Replaced Replaced (explain Wetlbox Cleaned below) Well Net Inspected (explain below) Repair Order Submitted NOTES: /I BLAII']E TECH SERVICES, IHC. SAH JOSE 8ACR2,ME/;'ro LOS AHGELES S^l.;I DIEGO I I I I I I I I ! I I I I, WELL GAUGING DATA Project# Client Sheea / Odor Depth to Immiscible Liquid (ft.) Volume of [ Immisc~les I Removed [Depth to water (rd) [ (ft.) Depth to well bottom (ft.) Thickness of Immiscible Liquid (ft.) Survey Pohat: TOB TO ~ Blaine Tech Services, Inc. t 680 Rogers Ave., San Jose, CA 95112 (408) 573-0555 SHELL WELL MONITORING DATA SHEET Well I.D.: ~ ~., Date: Well Diameter: 2 3 G) 6 8 Total. Well Depth (TD): '*':t.o ~, Depth to Water (DTW): .a~. t,~ Depth to Free Product: Tl~ickness of Free Product (feet): Referenced to: ~ Grade D.O. Meter (ifreq'd): YS~ ~AC~ DTW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: ~--,. ,~ I Purge Ivlethod: Bailer Waterra Sampling Method: : , ~ Disposable Bailer Peristaltic Disposable Bailer Positive Air Displacement Extraction Pump Extraction Port - ec nc ' Other ~ Dedicated Tubing Other: t 9.~ X ~ = %°%.q Gals. IWell D. iameter Multiplier Well Diameter Multiplier 0.04 0.65 1 2" 0.16 6" 1.4~ Y' 0.37 Other radius~ * O, 163 Case Volume Volumes Calculated Vnlumo - 'Cond. Turbidity I Time Temp (°F) pH (mS orq~..). (NTUs) Gals[ Removed Observations .. :.J( I Did well dewater? Yes ~ Gallons actually evacuated: Sample I,D.:' t~ ~- t Laboratory: ' ~ Columbia Other I' Analyzed for: ~ ~ MTBE TPH-D Oxygenates (5) Otherf ~'**. IEB I.D. (if applicabIe): ~ r,,,,, Dut~.lic~te I.D. (if applicable): Analyzed for: TPH-G BTEX. MTBE TPH-D Oxygenates (5) O~er: I D.O. (if req'd): Pre-purge: ~g/[ Post-purge: ... ~O.R.P. (ifreq'd): Pre-purge: nlV Post-purge: Blaine Tech Services, Inc. J680 Rogers Ave., San Jose, CA 951'!2 (800) 545-7558 #: Sampler: Well I.D.: ~q ~,t- ~. SHELL WELL MONITORING DATA SHEET Site: Date: Well Diameter: 2 3 ~ 6 8 Total. Well Depth (TD): ,~q~. 5, Depth to Water (DTW): :~ q. ~. Depth to 'Free Product: Thickness of Free'Product (feet): Referenced to: ~ Grade D.a. Meter (ifreqld): ysI HACH DTW with 80% Recharge [(Height of Water Colunm x 0,20) + DTW]: .~ '1. ~-? I I I Purge lVlethod: Bailer Waterra Sampling Method: ~ Disposable Bailer Peristaltic Disposable Bailer Positive Air Displacement Extraction Pump Extraction Port ~ Other * Dedicated Tubing Other: (.WelI.Dinmeler Ivlulliplier ,, Well Diameter,. tG,,. ~_.. (Gals.) X ~ = ~.q Gals. Case Volume Specified Volumes Calculated _Volu~* Multiplier l" 0.04 4" 0.65 2" 0.16 6" 1.4'7 3" 0.37 Other radius~ * 0.163 ....... Cond. Turbidity Time Te.m.p ('°Fl!. pH (mS or~).. (NT..Us) Gals: Removed Observations .- o ~.? -4',. ~, t,,. ~t ~ '~2 '~ 2 ~. 3'~- ~ .. Did well dewater? Yes ~ Gallons actually evacuated: -Sampli-ng-Dt~e:wa-/~-/o.~ Samp'li-~g-Tim'e: ff ~t> Em~lFr6-Water: z Sample I.D.: m ~.,. Laboratory: ~ Columbia Other Analyzed for: ~ ~ MTBE TPH-D . Oxygeuates (5) Other: ¢,,'{,~. EB I.D. (if applicable): @ -r,,.~ Duplicate I.D. (if applicable): Analyzed for: TPH-G BTEX ivlTBE TPH-D Oxygenates ~5) Other: D.a. (ifreq'd): Pre-purge: m/t. Past-purge: rog/L O.R.P. (ifreq'd): Pre-purge: mV Post-purge: i Blaine Tech Services, Inc. 1680 Rbgers Ave., San Jose, CA 95112 (800) 545-7558 S}IELL WELL MONITORING DATA SIiEET BTS#:o~jfoztt. s~-~ Sampler: 5co~ + Date: ¢)-6 8 Well I.D.: Fire-3 Well Diameter: 2 3 Total Well Depth (TD): ,~,~. 3 ~- Depth to Water (DTW): Depth to Free Product: Thiclcness of Free Product (feet): !Referenced to: ~ Grade D.a. Meter (ifreq'd): YS[ nACH DTW with 80% Recharge [(Height of Water Colunm x 0.20) + DTW]: I I I Purge Method: Bailer Waterra Sampling Method: ~ Disposable Bailer Peristaltic Disposable Bailer Positive Air Displacement Extraction Pump Extraction Port ~_lec,trm 5ub'mers't~_~ Other ' Dedicated Tubing Other: j/,,. t, (Ca~s.) x 1 Case Volume = ~'t ~- 8' Gals. Specified Volumes Calculated Volume.. _W. ell Dimmer. er,' .Multiplier Well Diameter Multi~!~er 1" 0.04 4" 0.65 2" 0,[6 6" lA7 3" 0,37 Other radius~ * 0,163 '" Cond. 'Tur~iditY ..... Time Temp (°F) pH (mS or OD) (NTUs) Gals: Removed Observations .. Did well dewater? Yes ~ Gallons actually evacuated: ~'o -Sampt-i'ngq3ate:.7~-/t,--/a-5 Smr~pti-n-g-Tn'me: to,~ Depth to Water: Sample I.D.:mia --3 Laboratory: ~ Columbia Other Analyzed for: ~ ~ ~vm3£ TPU-D Oxygenates (5) Other: t>'.',,;, t~-,~d, r~,,~ ~e ,,..,. EB I.D. (if applicable): @,,.~ Duplicate I.D. (if applicable): Analyzed for: TPH-G BTBX MTBE TPH-D Oxygenates (5) Other: D.a. (ifreq'd): Pre-purge: '~/C Post-purge: m~/L O.R.P. (if req'd): Pre-purge: mV Post-purge: mi/ Blaine Tech Services, Inc. 1680 Rogers Ave.~ San Jose, CA 95112 (800) 545-7558 SHELL WELL MONITORING DATA S_t-IEET Sampler: Well I.D.: ~,~. q Total Well Depfl~ (TD): Date: to- ;~ ~ - ~oo3 Well Diameter: 2 3 ~ 6 8 Depth to Water (DTW): Depth to Free Product: Thiclmess of Free Product (feet): Referenced to: ~ ~rade D.O. Meter (ifreq'd): YSr t-IACH DTW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: Purge Metlmd: Bailer Waterra Sampling Method: ~ Dispasable Bailer Peristaltic Disposable Bailer Positive Air Displacement Extraction Pump Extraction Port ~ Other ' Dedicated Tubing Other. (Gals.) X Case Volume -- ~'.,q', '4 Gals. Specified Volumes Calculated Volum~ W~It Diameter Multiplier Well Diameter Multiplier l" 0,04 4" 0.65 2" 0.16 6" 1.47 3" 0.37 Other radius" * 0.163 cond. Turbidity ' ' Time Temp (°F) 15H (mS or~) 0'4TUs) Gals: Removed Observations Did well dewater? Yes . ~ Gal(ohs actually evacuated: rt. s Sample i.D.: ~.~ Laboratm~: ~ Columbia Other .., Analyzed for: ~ ~ M~E TPH-D Oxygenates (5) Other: ~.'**. ,,~d, r~,eg,~, EB I.D. (if applicable): ~ ,, .... Duplicate I.D. (if applicable) : Analyzed for: TPH-G BTEX MTBE TPH-D Oxygenates (5) .Other: D.O. (ifreq'd): Pre-purge: mg/L Post-purge: O.R.P. (ifreq'd): Pre-purge: mV P~st-purge: .... . Blaine Tech Services, 'Inc. 1680 Rogers Ave., San Jose~ CA 951~2 (800) 545-7558 SHELL WELL MONITOR/NG DATA SHEET Sampler: Well I.D.: Total. Well Depth (TD): q~,~. ,-fl, Depth to Free Product: Date: to - ~ ~ - .loo3 WellDiameter: 2 3 ~ 6 8 Depth to Water (DTW): ! q~. ~.~ Thickness of Free Product (feet): Referenced to: ~ Grade D.O. Meter (ifreq'd): YSI HA. CH DTW with 80% Recharge [(Height of Water Column x 0.20) + DTW]: Purge Method: Bailer Waterra Sampling Method: ~ Disposable Bailer Peristaltic Disposable Bailer Positive Air Displacement Extraction Pump Extraction Port (E'lectnc ~ Other ' Dedicated Tubing Other: Well Diameter, , Multip[jgr. Welt Di.~meter N. lultlplier I" 0.04 4" 0.65 I~. 'Z (GaIs.) X ~ = b' ~'. G Gals. Y' 0.3'/ Other radius~ * 0.163 Case Volume Specified Volumes Calculated Volume Cond. Turbidity ...... Time Temp (°F) pH (mS or ~) (NTUs) ., Gals: Removed Observations .. Did well dewater? Yes it~ Gallons actually evacuated: ,- ~.. o Sample I.D.: ~ ~,. f Laboratory: ~ Columbia Other EB I.D. (if applicable): @ r~, Duplicate I.D. (if applicable): i Analyzed for: TPH-G BTEX MTBE TPH-D Oxygenates (5) Other: D.O. (ifreq'd): Pre-purge: mg/L Post-purge: ~g/t. O.R.P. (ifreq'd): Pre-purge: mV Post-purge: n~iV Blaine Tech services, lnc. '! 680 Rogers Ave., San Jose~ 'CA 95'112 (800) 545-7558 I I I I I I II i '1 '1 I I I I APPENDIX B FIELD PROCEDuaEs BLAINE TECH SERVICES,~ 1680 ROGERS AVENUE SAN JOSE, CA 95112-1105 (408) 573-7771 FAX (408) 573-0555 PHONE CONTRACTOR'S LICENSE #746684 www. blainetech.com I I I November 12, 2003 Tony Palagyi Shell Oil Products US P.O. Box 7869 Burbank, CA 91510-7869 I I I' Fourth Quarter 2003 Groundwater Mmtitoring at Shell-branded Service Station 2401 Oak Street Bakersfield, CA Monitoring performed on October 21, 2003 I I I I Groundwater Monitoring Report 031021-SH-1 This report covers the routine monitoring of groundwater wells at this Shell-branded facility. In accordance with standard procedures that conform to Regional Water Quality Control Board requirements, routine field data collection includes depth to .water, total well depth, thickness of may separate inuuiscible layer, water column volume, calculated purge volume (if applicable), elapsed evacuation time (if applicable), total volume of water removed (if applicable), and 'standard water parameter insmunent readings. Sample material is collected, contained, stored, and transported to the laboratory in conformance with EPA standards. Purgewater (if applicable) is, likewise, collected and transported to D.K. Environmental. Basic field information is presented alongside analytical values excerpted from the laboratory report in the cumulative table of WELL CONCENTRATIONS. The full analytical report for the most recent samples and the field, data sheets are attached to this report. At a mi~cmmu, Blaine Tech Services, Inc. field persomael m'e certified on completion of a forty- hour Hazardous Materials and Emergency Response trairdng course per 29 CFR 1910.120. Field persormel are also em'oiled in mmual eight-hour refresher courses. Blaine Tech Services, Inc. conducts smupling and docmuentation assigmuents of this type as an independent third party. Our activities at this site consisted of objective data and sample collection only. No interpretation of analytical results, defining of hydrological conditions or fonnulation of recommendations was performed. ~ Please call if you have any questions. Yours truly, Francis Thie Vice President FT/ks attachments: Curnulative Table of WELL CONCENTRATIONS Certified Analytical Report Field Data Sheets Katlu'yn Ewing KHM Environmental Management, Inc. 911 'S. Primrose Ave., Suite K Monrovia, CA 91016 ' I I I I I I I I I I I I. I I BLAINE TECH SERVICES, INC. ,METHODS AND PROCEDURES FOR THE ROUTINE MONITORING OF GROUNDWATER WELLS AT SHELL SITES Blaine Tech Services, Inc. performs environmental sampli_ng and' documentation as an independent third party. We specialize in groundwater monitoring assignments and intentionally limit the scope of our services to those bentered on the generation of objective information. To avoid conflicts of interest, Blaine Tech Services, Inc. personnel do not evaluate or interpret the information we collect. As a state licensed contractor (C-57 well drilling -water- 746684 ) performing strictly technical services, we do not make any professional recommendations and perform no consulting of any kind. SAMPLING PROCEDURES OVERVIEW SAFETY All groundwater monitoring assignments performed for Shell comply with, Shell's safety guidelines, .29 CFR 1910.120 and SB-198 Injury. and Illness Prevention Program (IIPP). All Field Technicians receive the full 40-hour 29CFR 1910.120 OSHA SARA HAZWOPER course, medical Clearance and on-the-job training prior to commencing any work on any Shell site. INSPECTION AND GAUGING Wells are inspected prior to evacuation and sampling. The condition of the wellhead is checked and noted according to a wellhead inspection checklist. Standard measurements include the depth to water (DTW) and the'total well depth (TD) obtained With industry standard electronic water level indicators that are graduated in increments of hundredths of a foot. The water in each well is inspeCted for the presence of immiscibles. When free product is suspected, its presence is confirmed using an electronic interface probe (e.g. MMC): No samples are collected from a well Containing over two-hundredths'of a .foot (0.02') of product. EVACUATION Depth to water measurements are collected by our personnel prior to purging and minimum purge volumes are calculated anew for each well based on the height of the water column and the diameter of the well. Expected purge Volumes are never less than three case volumes and are set at no less than four case volumes in some jurisdictions. Blaine Tech Services, Inc. Standard Methods & Procedures Shell Oil Products US Page 1 I I I I I I I I I I I I I I I I I I Well purging devices are selected on the basis of the'well diameter.and the total volume to be evacuated. In most cases the well will be purged using an electric' submersible pump (i.e. Grundfos) suspended near (but not touching) the bottom of the well.- PARAMETER STABILIZATION Well' purging completion standards include minimum purge volumes; but additionally require stabilization of specific groundwater parameters prior to sample collection. Typical groundwater parameters used to measure stability are electrical conductivity, pH, and temperature. Instrument readings are obtained at regular intervals during the evacuation process (no less than once per case volume). Stabilization standards for routine quarterly monitoring of fuel sites include the following: Temperature is considered to have stabilized when successive readings do not fluctuate more than +/- 1 degree Celsius. Electrical conductivit-y is considered stable when successive readings are within 10%. pH is considered to' be stable when successive readings remain constant or vary no more than 0.2 of a pH unit. DEWATERED WELLS Normal evacuation removes no less than three case volumes of water from the well. However, less water may be removed :in cases where the well dewaters and does not immediately recharge. MEASURING RECHARGE Upon completion of well purging, a depth to water measurement is collected and notated to ensure that the well has recharged to within 80% of its static, pre-purge level prior to sampling. Wells that do nOt immediately show 80% recharge or dewatered wells will be allowed a · minimum of 2 hours to recharge prior to sampling. The water level at time of sampling will be noted. PURGEWATER CONTAINMENT All non-hazardous purgewater evacuated from each groundwater monitoring well is Captured and contained in on-board storage tanks on the Sampling Vehicle and/or special water hauling trailers. Effluent from the decontamination of reusable apparatus (sounders, electric pumps and hoses etc.), consisting of groundwater combined with deionized water and non-phosphate soap, is also captured and pumped into effluent tanks. Non-hazardous purgewater is transported under standard Bill of Lading documentation to a Blaine Tech Services, Inc. facility before being transported to a Shell approved disposal facility. Bla/ne Tech Services, Inc. Stmadard Methods & ?rocsdures Shell O/1 Products US Page'2 I I I I I I I I I I ,I I I I I I I I I SAMPLE COLLECTION DEVICES All samples are collected using a stainless steel, Teflon Or disposable bailers. SAMPLE CONTAINERS Sample material is decanted directly from the sampling bailer into sample containers provided by the laboratory that will analyze the samples. The transfer of sample material from the bailer to the sample container conforms to specifications contained in the USEPA T.E.G.D. The type of sample container, matedal of construction, method of closure and filling requirements are specific to the intended analysis. Chemicals needed to preserve the sample material are commonly placed inside the sample containers by the laboratory or glassware vendor prior to 'delivery of the bottle to our personnel. The laboratory sets the number of replicate containers. TRIP BLANKS Trip Blanks', if requested, are taken to the site and kept inside the sample cooler for the duration of the event. They are turned over to the laboratory for analysis with the samples from that site. DUPLICATES Duplicates, if requested, may be collected at a site. The Field Technician uses their discretion in choosing the well at which the Duplicate is collected, typically one suspected of containing measurable contaminants. The Duplicate sample is labeled "DUP" and the time of collection is omitted from the COC, thus rendering the sample blind. SAMPLE STORAGE All sample containers are promptly placed in food grade ice chests for storage in the field and transport (direct or via our facility) to the designated analytical laboratory. These ice chests contain quantities of restaurant grade ice as a 'refrigerant material. The samples are maintained in either an ice chest or a refrigerator until relinquished into the custody of the la.boratory or laboratory courier. , DOCUMENTATION CONVENTIONS A label must be affixed to all sample containers. In most cases these labels are generated by our office personnel and are partially preprinted. Labels can also be hand written by our field personnel. The site is identified with the store number and 'site address, as is the particular groundwater well from which the sample is drawn (e.g. MWol, MW-2, S-1 etc.). The time and date of sample collection along with the initials of the person who collects the sample are handwritten onto the label. C/iain of Custody records are created using client specific preprinted forms following USEPA specifications. Blaine Tech Services, Inc. Standard Methods & Procedures Shell Oil Products US Page 3 I I I I I I I I I I I I I I I ! I I Bill of Lading records are contemporaneous records created in the field at the site whe~-e the non-hazardous purgewater is generated. Field Technicians use preprinted Bill of Lading forms. DECONTAMINATION All equipment is brought to the site in clean and serviceable condition and is cleaned after use in each well and before subsequent use in any other well. Equipment is decontaminated before leaving the site. The primary decontamination device is a commercial steam cleaner. The steam cleaner is de- tuned to function as a hot pressure washer that is then operated with high quality deionized water that is produced at our facility and stored onboard our sampling vehicle. Cleaning is facilitated by the use of proprietary fixtures and devices included in the patented workstation (U.S. Patent 5,535,775) that is incorporated in each sampling vehicle. The steam cleaner is used to deC°n Yeels, pumps and bailers. Any sensitive equipment or parts (i.e.. Dissolved Oxygen sensor membrane, water level indicator, etc.) that cannot be washed using the high pressure water, will be sprayed with a non- phosphate soap and deionized water solution and rinsed with.deionized water, DISSOLVED OXYGEN READINGS Dissolved Oxygen readings are taken pre- and/or post-purge using YSI meters (e.g. YSI Model 54, 58 or 95) or HACH field test kits. The YSI meters are equipped with a stirring device that enables them to collect accurate in-situ readings. The probe/stirring.deVices are modified to allow downhole measurements to be taken' from wells with diameters as Small as two inches. The probe and reel is decontaminated between wells as described above. The meter is calibrated between wells as per the instructions in .the operating manual. The probe and stirrer is lowered into the water column. The reading is allowed to stabilize prior to collection.' OXYIDATON REDUCTION POTENTIAL READINGS All readings are obtained with either Corning or Myron-L meters (e.g. Corning ORP-65 or a Myron-L UItrameter GP). The meter is cleaned between wells as described above. The meter is calibrated at the start of each day according to the instruction manual. FERROUS IRON MEASUREMENTS All field measurements are collected at time of sampling with a HACH test kit. Blairte Tech Services, Inc. Standard Me,ods & Procedures Shell Oil Products US Page 4 , I I I I I I I. I I I I I I I APPEnI~Ix C DISPOSAL DOCUMENT NAME ADDRESS -""JO 640340 -NON-HAZA 'DOUS, WASTE DATA FORM. SHELL OIL PRoDuc3~ US- P.O. BOX 7869' BURBANK, CA 913i0--7B69 /~ TANK DUMP TYPE: TRUCK [] [] DRUMS [] CARTONS [] OTHER TRUCK .. NO N- HAZ~RDOI. J~ GROUNDWATER WASTE DESCRIPTION GE~ERATIN~I PROCESS COMPONENTS OF WASTE PPM W~TER 99-1OO°/. 1, , 5. TPH <:1% 2. S .... PHONE NO. WEIGHT PURGED GROUNDWATER PPM INCIDENT# 4.., .710 PROPERTIES: pH ., [] HANDLIN~ INSTRUCTIONS; .. BE~I # SOUD [] SLU.DGE [] SLURRY [] OTHER 24-HOUR E~ERGENCY PHONE (BO0) 424-5r300 WASTE AS DESCRIBED IS 100% (On behalfofSOPUS),. NON-HAZARDOUS. TYPED OR PRINTED FULL NAME & SIGNATURE DATE NIETO AN D SONS TRUCKING, INC. NAME ADDRESS CITY, STATE, ZIP 12B1 BR~ CANYON ROAD BREA, CAI TFORN:T.A 5rZP_,21 (7;14) 990-6853 PHONE ND ...... TRUCK, UNIT, I.D. NO. TYPED OR PRINTED FULL NAME & SIGNATURE D/K ENVIRONI~tENTAL 3650 E. 26''m STRE _E-ZT NAME ADDRESS LOS ANGELESt C~% 9002.3 CITY, STATE, ZiP (323) 268- 50~5 PHONENO. DATE EPA I,D. ~[{~. .., ~= DISPOSAL METHOD [] LANDFILL [] OTHER... TYPED OR PRINTED FULL NAME & SIGNA'rURE [TN OLO~NEW L A tot~s hANS S B RTICD HWDF leto NONE D)SCREPANCY DATE APPENDIX D · LABORATORY REPORT AND CHAIN-OF-CUSTODY DOCUMENTS I nvironmental I ~ aborat°ries, Inc. I October 30, 2003 ' I Nick Sudano Blaine Tech Services, Inc I 20360 Gramercy Place Torrance, CA 90 I Subject: Calsci Client ! Dear Client: I Enclosed is an a~ included in this r( I the attached chai Unless otherwise I guidelines establi operating proced subcontracted ar I package. The re~. reproduction ther If you have any q I the undersigned. ! ! Torrance, CA 90501-1511 Calscience Work Order No.: . 03-10-1400 Client Reference: 2401 Oak Street, Bakersfield, CA Enclosed is an analytical report for the above-referenced project. The samples included in this report were received 10/23/2003 and analyzed in accordance with the attached chain-of-custody. Unless otherwise noted, all analytical testing was accomplished in accordance with the guidelines established in our Quality Assurance Program Manual, applicable standard operating procedures, and other related documentation. The original report of any subcontracted analysis is provided herein, and follows the standard Calscience data package. The results in this analytical report are limited to the samples tested and any reproduction thereof must be made in its entirety. If you have any questions regarding this report, please do not hesitate to contact //Ca!s~,~Ttic ,e E~/ir,onmental Project Manager 7440 Lincoln Way, Garden Grove, CA 92841-1432 Michael J.'~[ri~sostomo . Quality Ass~rance Manager TEL: (714) 895-5494 - FAX: (714) 894-7501 ~t~-_alscience ~__nvironmental ~r aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street,, Bakersfield, CA ANALYTICAL REPORT Date Received: Work Order No: Preparation: Method: 10/23/03 03-10-1400 EPA 5030B DHS LUFT Page 1 of 2 Lab Sample Date Date Date Client Sample Number Number Collected Matdx Prepared Analyzed QC Batch ID Parameter Resu!t RL. D._~F Qual Units TPH as Gasoline ND 50 I ug/L SurrQ0ates: REC (%) C(;mtml Qual Limits 1,4-B romofluorobenzene 92 49-133 Pa~meter Result R~ D~ qual Uni~ TPH as Gasoline ND 50 1 u~L Su~o~ates: REC (%) ~n~o[ Qual Limi~ 1,4-Bro~fluombenzene 92 4~133 .,,,.~.. ....................... ~... , ...... ~ .... ,,,, ~ ...... ,.. ,_, .......... Parameter Result RI_ DF Qual Units TPH as Gasoline ND 50 1 ug/L Su~Tofqates:. REC (%) COntrol qual Limits 1,4-Bromofluorobenzene 88 49-133 Parameter Result RI_ D_[F Qual Units TPH as Gasoline ND 5'0 '1 ug/L Surrooates; REC (%) Control Qu;~l Limits 1,4-Bromofluorobenzene 93 49-133 ,rting Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~=~-_alscience ~F-_nvironmental ~.~ aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 ANALYTICAL REPORT Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: DHS LUFT Project: 2401 Oak Street, Bakersfield, CA Page 2 of 2 Lab Sample Date Date Date Client Sample Number Number Collected Matdx Prepared Analyzed QC Batch ID Parameter Result RI_ DF' Qua. I Units TPH as Gasoline ND 50 1 ug/L Surrogates: REC {%) Contrgl Qual Limits 1,4-Bromofluorobenzene 90 49-133 Parameter Result RI_ DF' Qual Units TPH as Gasoline ND 50 I ug/L Surrooates: REC (%) Control Limits 1,4-Bromofluorobenzene 92 49-133 Qual orbng Limit , DF - Dilution FaCtOr , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL:(714)895-5494 · FAX:(714)894-7501 .,=alscience nvironmental abora ories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 ANALYTICAL REPORT Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page I of 6 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result RI_ DF Qual Units Parameter Result R~ D._EF ~ual Units Acetone ND 10 I ug/L 1,1-Dichloropropene ND 1.0 1 ug/L Benzene ND 0.50 1 ug/L c-1,3-Dichloropropene ND 0.50 I ug/L Bromobenzene ND 1.0 1 ug/L t-1,3-Dichloropropene ND 0.50 1 ug/L Bromochloromelhane ND 1.0 1 ug/L Ethylbenzene ND 1.0 1 ug/L Bromedichloromethane ND 1.0 1 ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1~0 1 ug/L Isopropylbenzene ND 1.0 1 ug/L Bromomethane ND 10 1 ug/L p-lsopropyltoluene ND 1.0 I ug/L 2-Butanone ND 10 1. ug/L Methylene Chloride ND 10 1 uglL n-Butylbenzene ND 1.0 1 ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 I ug/L tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1.0 1 ug/L Carbon Disulfide ND 10 1 ug/L Styrene ND 1.0 I ug/L Carbon Tetrachloride ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 1 ug/L 1,1,2,2-Tetrachloroethane ND 1.0 1 ug/L Chloroethane ND 1,0 1 ug/L Tetrachloroethene ND 1.0 I ug/L Chloroform ND 1.0 1 ug/L Toluene ND 1.0 I ug/L Chloromethane ND 10 1 ug/L 1,2,3-Trichlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4-Trichlorobenzene ND 1.0 I ug/L 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Tdchloroethane ND 1.0 1 ug/L Dibromochloromethane ND 1.0 1 ug/L 1,1,2-Trichloroethane ND 1,0 1 ug/L 1,2-Dibromo-3-Chloropropane ND 5.0 I ug/L Trichloroethene ND 1.0 1 ug/L 1,2~Dibromoethane ND 1.0 1 ug/L Trichlorofluoromethane ND 10 1 ug/L Dibromomethane ND 1.0 1 ug/L 1,2,3-Trichloropropane ND 5.0 I ug/L 1,2-Dichlorobenzene ND 1.0 1 ug/L 1,2,4-Tdmethylbenzene ND 1.0 1 ug/L 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3,5-Tdmethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene ND 1.0 1 ug/L Vinyl Acetate ND 10 1 ug/L Dichlorodifluoromethane ND 1.0 I ug/L Vinyl Chlodde ND 0.50 1 ug/L 1,1-Di;;hloroethane ND 1.0 I ug/L p/m-Xytene ND 1.0 1 ug/L 1,2-Dichloroethane ND 0,50 I ug/L o-Xylene ND 1,0 1 ug/L 1,1-Dichloroethene . ND 1.0 1 ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 I ug/L c-1,2-Dichloroethene ND 1.0 1 ug/L Tert-Butyl Alcohol (TBA) ND 10 1 ug/L t-1,2-Dichloroethene ND 1.0 1 ug/L Dlisopropyl Ether (DIPE) ND 2.0 1 ug/L 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L 1,3-Dichloropropane ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2-Dichloropropane ND 1.0 1 ug/L Surroclates: REC (%) Control Qual Surrof:lates: REC (%) Control Qual Limits Dibromofluoromethane 104 84-120 Toluene-d8 97 91-109 1,4-Bromofluorobenzene 96 84-108 ort~ng Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL:(714)895-5494 · FAX:(714)894-7501 I ~=alscience. . ANALYTICAL REPORT i~_~vironmenI~l I &aboratories, lnc. Blaine Tech Services, Inc Date Received: 10/23/03 I 20360 Gramercy Place Work Order No: 03-10-1400 Torrance, CA 90501-1511 Preparation: EPA 5030B Method: EPA 8260B I Project: 2401 Oak Street, Bakersfield, CA Page 2 of 6 Lab Sample Date Date Date I Client Sample'Number Number Collected Matrix Prepared Analyzed QCBatch ID Parameter Result RI_ D.._~F Qual Units Parameter Result RI_ DF Qual Uni~ I Acetone ND 10 1 ug/L 1,1-Dichloropropene ND 1.0 I ug/L Benzene ND 0.50 1 ug/L c-1,3-Dichloropropene ND 0.50 I ug/L Bromobenzene ND 1.0 1 ug/L t- 1,3-Dichloropropene ND 0.50 I ug/L Bromochloromethane ND 1.0 I ug/L Ethylbenzene ND 1.0 I ug/L I Bromodichloromethane ND 1.0 1 ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1.0 1 ug/L Isopropylbenzene ND 1.0 1 uglL Bromomethane ND 10 1 ug/L I>-Isopropyltoluene ND 1.0 1 ug/L 2-Butanone ND 10 1 ug/L Methylene Chloride ND 10 I ug/L i n-Butylbenzene ND 1.0 1 ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 I ug/L tert-Butylbenzene ND 1.0 I ug/L n-Propylbenzene ND 1.0 1 ug/L Carbon Disulfide ND 10 1 ug/L Styrene ND 1.0 1 ug/L Carbon Tetrachloride ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L I Chlorobenzene ND 1.0 I ug/L 1,1,2,2-Tetrachloroethane ND 1.0 1 ug/L Chloroethane ND 1.0 I ug/L Tetrachloroethene ND 1.0 I ug/L Chloroform ND 1.0 1 ug/L Toluene .. ND 1.0 I ug/L Chloromethane ND 10 I ug/L 1,2,3-Trichlorobenzene ND 1.0 1 ug/L I 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4-Tdchlorobenzene ND 1.0 1 ug/L 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Tfichloroethane ND 1.0 1 ug/L Dibromochloromethane ND 1.0 1 ug/L 1,1,2-Trichloroethane ND 1.0 1 ug/L 1,2-Dibromo-3-Chloropropane ND 5.0 1 ug/L Trichloroethene ND 1.0 1 ug/L 1,2-Dibromoethane ND 1.0 I ug/L Trichlorofl uoromethane ND 10 1 ug/L I Dibromomethane ND 1.0 1 ugJL 1,2,3-Trichloropropane ND 5.0 1 ug/L 1,2-Dichlorobenzene ND 1.0 I ug/L 1,2,4.Trimethylbenzene ND 1.0 1 ug/L 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3,5-Trimethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene ND · 1.0 1 ug/L Vinyl Acetate ND 10 1 ug/L I Dichlorodifluoromethana ND 1.0 '1 ug/L Vinyl Chloride ND 0.50 1 ug/L 1,1-Dichloroethane ND 1.0 1 ug/L p/m-Xylene ND 1.0 1 ug/L 1,2.Dichloroethane ND 0.50 1 ug/L o-Xylene ND 1.0 1 ug/L 1,1-Dichloroethene ND 1.0 1 ug/L Methyl-t-Butyl Ether.(MTBE) ND 1.0 1 ug/L i c-1,2-Dichloroethene ND 1.0 1 ug/L Tert-Butyl Alcohol (TBA) ND 10 I ug/L t-1,2-Dichloroethene ND 1.0 I ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L 1,3-Dichtoropropane ND 1.0 1 ug/L ' Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2-Dichloropropane ND 1.0 1 ug/L I Surrogates: REC {%) Control Q~al Surroi:lates: REC (%) Control Qual Limits Dibromofluoromethane 104 84-120 Toluene-d8 97 91-109 I 1,4-Bromofluorebenzene 96 84-108 1 ' . RL - Reporting Limit , DF - Dilution Factor , Qual - Qualifiers I ,.o Lincoln way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894.7501 ~m_nvironmental jae aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 ANALYTICAL REPORT Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page 3 of 6 Lab Sample Date Date Date Client Sarople Number Nurober Collected Matdx Prepared Analyzed QC Batch ID Paramet.e.r Result RI_ DF ,qual ,Lints Parameter Result RL' DF Qual Units Acetone ND 10 1 ug/L 1,1-Dichlompropene ND 1.0 1 ug/L Benzene ND 0.50 1 ug/L c-1,3-Dichloropropene ND 0.50 I ug/L Bmmobenzene ND 1,0 1 ' ug/L t-l,3-Dichloropropene ND 0.50 1 ug/L Broroochioromethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 I ug/L Bromodichloromethane ND 1.0 I ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1.0 I ug/L Isopropylbenzene ND 1.0 1 ug/L Broroomethane ND 10 I ug/L p-lsopropyltoluene ND 1.0 1 ug/L 2-Butanone ND id I ug/L Methylene Chloride ND 10 1 ug/L n-Butylbenzene ND 1.0 I ug/L 4-Methyl-2-Pentanone ND 10 I ug/L sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 1 ug/L tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1.0 1 ug/L Carbon Disulfide ND 10 I ug/L Styrene ND 1.0 I ug/L Carbon Tetrachlofide ND 0.50 I ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 I ug/L 1,1,2,2-Tetrachloroethane ND 1.0 I ug/L Chloroethane ND 1.0 I ug/L Tetrachloroethene ND 1.0 1 ug/L Chloroform ND 1.0 1 ug/L Toluene ND 1.0 1 ug/L Chloromethane ND 10 I ug/L 1,2,3-Td chlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1.0 1 ug/L 1,2,4-Trichlorobenzene ND . 1.0 1 ug/L 4-Chlomtoluene ND 1,0 I ug/L 1,1,1-Tdchloroethane ND 1.0 I ug/L Dibromochloromethane ND 1.0 1 uglL 1,1,2.Tdchloroethane ND 1,0 1 ug/L 1,2-Dibromo-3-Chloropropane ND 5.0 I ug/L Tdchloroethene ND 1.0 1 ug/L 1,2-Dibromoethane ND .1.0, 1 ug/L Trichlorofiuommethane ND 10 1 ug/L Dibromomethane ND 1.0 1 ug/L 1,2,3-Tdchlompropane ND 5.0 I ug/L 1,2-Dichlorobenzene ND 1.0 1 ug/L 1,2,4-Tfiroethylbenzene ND 1.0 '1 ug/L 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3,5-Trimethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene ND 1.0 1 ug/L Vinyl Acetate ND 10 1 ug/L DIchlorodifluoromethane ND 1.0 1 ug/L Vinyl Chlodde ND 0.50 I ug/L 1 ,l~Dichloroethane ND 1.0 1 ug/L p/m-Xylene ND 1.0 1 ug/L 1,2-Dichloroethane ND 0.50 1 ug/L o-Xylene ND 1.0 1 ug/L 1,1-Dichloroethene ND 1.0 I · ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 I ug/L c-1,2-Dichloroethene ND 1.0 1 ug/L Tort-Butyl Alcohol (TBA) ND 10 1 ug/L t-1,2-Dichloroethene ND 1.0 I ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L 1,2~Dichloropmpane ND -1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L ' 1,3-Dichloropropane ND 1.0 1 ug/L Tert-Amyl-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2.Dichloropropane ND 1.0 1 ug/L Surroqates: REC (%) Control Qual Surroqates: REC (%) Control .Qual Limits Dibromofluoromethane 105 84-120 Toluene-d8 98 91-109 1,4-Bromofluorobenzene 97 84-108 i ' RL - Reporting Limit , . DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Grove, Garden CA 92841-1432 · TEL:(714) 895-5494 · FAX: (714) 894-7501 ~=alscience ~n vironmen tal ~ aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 ANALYTICAL REPORT Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page 4 of 6 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Result RI. D._.[F Qual Units Paremet~r Result RI. D._[F Qual .Units Acetone ND 10 I ug/L 1,1-Dichloropropene ND 1.0 1 ug/L Benzene ND 0.50 I ug/L c-1,3-Dichloropropene ND 0.50 1 ug/L Bromobenzene ND 1.0 I ug/L t-1,3-Dichloropropene ND 0.50 I ug/L Bromochloromethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 1 ug/L Bromodichloromethane ND 1.0 1 ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1.0 I ug/L Isopropylbenzene ND 1.0 I ug/L Bromomethane ND 10 I ug/L lmlsopropyltoluene ND 1.0 1 ug/L 2-Butanone ND 10 I ug/L Methylene Chlodde ND 10 1 ug/L n-Butyibenzene ND 1.0 I ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L sec~Butylbenzene ND 1.0 I ug/L Naphthalene ND 10 1 ug/L tert-Butylbenzene ND 1.0 I ug/L n-Propylbenzene ND 1.0 1 ug/L Carbon Disulfide ND 10 I ug/L Styrene ND 1.0 1 ug/L Carbon Tetrachlodde ND 0,50 I ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 I ug/L 1,1,2,2-Tetrachloroethane ND 1.0 1 ug/L Chloroethane ND 1.0 I ug/L Tetrachloroethene ND 1.0 1 ug/L Chloroform ND 1.0 1 ug/L Toluene ND 1.0 1 ug/L Chloromethane ND 10 I ug/L 1,2,3-Trichlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1,0 1 ug/L 1,2,4-Tdch~orobenzene ND 1.0 1 ug/L 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Tdchloroethane ND 1.0 1 ug/L Dibromochloromethane ND 1.0 I ug/L 1,1,2-Trichloroethane ND 1.0 I ug/L 1,2-Dibromo-3-Chloropropane ND 5.0 1 ug/L Trichloroethene ND 1.0 I ug/L 1,2-Dibromoethane ND 1.0 1 ug/L Tdchlorofluoromethane ND 10 1 ug/L Dlbromomethane ND 1.0 I ug/L 1,2,3-Trichloropropane ND 5.0 I ug/L 1,2-Dichlorobenzene ND 1.0 I ug/L 1,2,4-Tdmethylbenzene ND 1.0 I ug/L 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3,5-Tdmethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene *ND 1.0 1 ug/L Vinyl Acetate ND 10 1 ug/L Dichlorodifluoromethane ND 1.0 1 ug/L Vinyl Chloride ND 0.50 1 ug/L 1,1,Dichloroethane ND 1,0 1 ug/L p/m-Xylene ND · 1.0 1 ug/L 1,2-Dichloroethane ND 0.50 I ug/L o-Xylene ND 1.0 1 ug/L 1,1-Dichloroethene ND 1.0 1 ug/L Methyl-t-Butyl Ether (MTBE) ND 1,0 1 ug/L c-1,2-Dichloroethene ND 1.0 1 ug/L TeA-Butyl Alcohol (TBA) ND 10 1 ug/L t-1,2-Dichloroethene ND 1.0 I ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L 1,3-Dichloropropane ND 1.0 1 ug/L Tert-Amyl-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2-Dichloropropane ND 1.0 I ug/L · Surroqates: REC (%) Control Qu.p! Surroqates: REC (%) Control Qual Limits Dibromofluoromethane 104 84-120 Toluene-d8 96 91-109 1,4-Bromofluorobenzene 97 84-108 i ' RL - Reporting Limit , DF - Dilution Factor , Qual - Qualifiers ' 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL:(714) 895-5494 · FAX: (714) 894-7501 . _nvironmental i__ aboratoHes, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 ANALYTICAL REPORT Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: EPA 8260B I I Project: 2401 Oak Street, Bakersfield, CA Page 5 of 6 Lab Sample Date Date Date Client Sample Number ~umber ~ Collected Matrix Prepared Analyze~. QC Batch ID Parameter Result R_.I= DF' Qu~l Units Parameter Result RI_ DF Qua. I Units Acetone ND 10 1 ug/L 1,1-Dichloropropene ND 1.0 I ug/L Benzene ND 0.50 I ug/L c-1,3-Dichloropropene ND 0.50 1 ug/L Bromobenzene ND 1.0 I ug/L t-1,3-Dichlompropene ND 0.50 I ug/I.. Bromochloromethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 I ug/L Bromodicriloromethane ND 1.0 I ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1.0 1 . ug/L Isopropylbenzene ND 1.0 1 ug/L Bromomethane ND 10 1 ug/L p-lsopropyltoluene ND 1.0 1 ug/L 2-Butanone ND 10 I ug/L Methylene Chlodde ND 10 I ug/L n-Butylbenzene ND 1.0 1 ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 1 ug/L tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1.0 1 ug/L Carbon Disulfide ND '10 1 ug/L Styrene ND 1.0 I ug/L Carbon Tetrachloride ND 0.50 ' 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 1 ug/L 1,1,2,2-Tetrachloroethane ND 1.0 I ug/L Chloroethane ND 1.0 I ug/L Tetrachloroethene ND 1.0 I ug/L Chloroform ND 1.0 t ug/L Toluene ND 1.0 I ug/L Chloromethane ND 10 I ug/L 1,2,3.Trichlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1.0 1 uglL 1,2,4-Trichlorobenzene ND 1 .O 1 uglL 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Tdchloroethane ND 1.0 1 ug/L Dibromochloromethane ND 1.0 I ug/L 1,1,2-Trichloroethane ND 1.0 1 ug/L 1,2-Dibromo-3-Chloropropane ND 5.0 I ug/L Trichloroethene ND 1.0 I ug/L 1,2-Dibromoethane ND 1.0 I ug/L Tdchlorofluoromethane ND 10 1 ug/L Dibromomethane ' ND '1.0 1 ug/L 1,2,3-Tdchloropropane ND 5.0 1 ug/L 1,2-Dichlorobenzene ND 1.0 1 ug/L 1,2,4-Trimethylbenzene ND 1.0 1 - ug/L 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3,5-Tdmethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene ND 1.0 1 ug/L Vinyl Acetate ND 10 1 ug/L Dichlorodifluoromethane ND 1.0 1 ug/L Vinyl Chloride ND 0.50 1 ug/L 1,1-Dichloroethane ND 1.0 1 ug/L plm-Xylene ND 1,0 1 ug/L 1,2-Dichloroethane ND 0.50 1 ug/L o-Xylene ND 1.0 1 ug/L 1,1-Dichloroethene ND 1.0 1 ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 1 ug/L c-l,2-Dichloroethene ND 1.0 1 ug/L Tert-Butyl Alcohol ('rBA) ND 10 1 ug/L t-1,2-Dichloroethene ND 1.0 1 ug/L Diisopropyl Ether (DIPE) ND 2.0 1 ug/L 1,2-Dichloropropane ND 1.0 1 ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 ug/L 1,3-Dichloropropane ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 I ug/L 2,2-Oichlorapropane ND 1.0 1 ug/L Sur~. ates: REC (%) Control Qual Surroaates: REC (%) ContrDI qual Limits Dibromofluoromethane 105 84-120 Toluene-d8 96 91-109 1,4-Bromofluorobenzene 97 84-108 I' .~ j RL - Reporting Limit , DF- Dilution Factor , Qual- Qualifiers ~~Vi~- 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894-7501 iscience [l~-_nvironmental ~ aboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 ANALYTICAL REPORT Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: EPA 8260B Project: 2401 Oak Street, Bakersfield, CA Page 6 of 6 Lab Sample Date Date Date Client Sample Number Number Collected Matrix Prepared Analyzed QC Batch ID Parameter Res..uJt. RI. DF Qual Units Parameter Result RL DF: Qual Units Acetone ND 10 1 ug/L Ethanol ND 100 1 ug/L 1,1-Dichloropropene ND 1.0 1 ug/L Benzene ND 0.50 1 ug/L c-l,3-Dichloropropene ND 0.50 1 ug/L Bromobenzene ND 1.0 1 ug/L t-1,3-Dichloropropene ND 0.50 1 ug/L Bromochlommethane ND 1.0 1 ug/L Ethylbenzene ND 1.0 1 ug/L Bromodichloromethane ND 1.0 1 ug/L 2-Hexanone ND 10 1 ug/L Bromoform ND 1,0 I ug/L lsopropylbenzene ND 1,0 1 ug/L Bromomethane ND 10 I ug/L p-lsopmpyltoluene ND 1.0 1 ug/L 2-Butanone ND 10 1 ug/L Methylene Chloride ND 10 1 ug/L n-Butylbenzene ND 1.0 1 ug/L 4-Methyl-2-Pentanone ND 10 1 ug/L sec-Butylbenzene ND 1.0 1 ug/L Naphthalene ND 10 1 ug/L tert-Butylbenzene ND 1.0 1 ug/L n-Propylbenzene ND 1.0 I ug/L Carbon Disulfide ND 10 I. ug/L Styrene ND 1.0 I ug/L Carbon Tetrachlodde ND 0.50 1 ug/L 1,1,1,2-Tetrachloroethane ND 1.0 1 ug/L Chlorobenzene ND 1.0 1 ug/L 1,1,2,2-Tetrachloroethane ND 1.0 I ug/L Chloroethane ND 1.0 I ug/L Tetrachloroethene ND 1.0 1 ug/L Chloroform ND 1.0 1 ug/L Toluene ND 1.0 1 ug/L Chloromethane ND 10 1 ug/L 1,2,3-Tfichlorobenzene ND 1.0 1 ug/L 2-Chlorotoluene ND 1.0 I ug/L 1,2,4-Trichlorobenzene ND 1.0 I ug/L 4-Chlorotoluene ND 1.0 1 ug/L 1,1,1-Tdchloroethane ND 1.0 1 uglL D[bromoch~oromethane ND 1.0 1 ug/L 1,1,2-Trichloroethane ND 1.0 I ug/L 1,2-Dibmmo-3-Chloropropane ND 5.0 1 ug/L Trichloroethene ND 1.0 1 ug/L 1,2-Dibmmoethane ND 1.0 1 ug/L Tdchlorofluoromethane ND 10 1 ug/L Dibromomethane ND 1.0 1 ug/L 1,2,3-Tfich$oropropane ND 5.0 1 ug/L 1,2-Dichlorobenzene ND 1.0 1 uglL 1,2,4-Tfimethylbenzene ND 1.0 1 ug/L 1,3-Dichlorobenzene ND 1.0 1 ug/L 1,3,5-Trimethylbenzene ND 1.0 1 ug/L 1,4-Dichlorobenzene ND 1.0 1 ug/L Vinyl Acetate ND 10 1 ug/L Dichlorodlfluoromethane ND 1.0 I ug/L Vinyl Chloride ND 0.50 1 ug/L 1,1-Dichloroethane ND 1.0 1 ug/L p/m-Xyiene ND 1.0 I ug/L 1,2-Dichloroethane ND 0.50 I ug/L o-Xylene ND 1.0 I ug/L 1,1-Dichloroethene ND 1.0 1 ug/L Methyl-t-Butyl Ether (MTBE) ND 1.0 I ug/L c-1,2-Dichloroethene ND 1,0 1 ug/L Tert-Butyl Alcohol (-rBA) ND 10 1 ug/L t-1,2-Dichloroethene ND 1.0 I ug/L Diisopr°pyl Ether (DIPE) ND 2,0 1 ug/L 1,2-Dichloropropane ND 1.0 I ug/L Ethyl-t-Butyl Ether (ETBE) ND 2.0 1 . ug/L 1,3-Dichloropropane ND 1.0 1 ug/L Tert-AmyI-Methyl Ether (TAME) ND 2.0 1 ug/L 2,2-Dichloropropane ND l J0 1 Ug/L Surroqates: REC (%) Control Qual Surroqates: REC (%) Control Qual Limits Dlbromofluoromethane 102 84-120 Toluene-d8 g7 gl-lOg l',4-Bromofluorobenzene g7 84-I 08 ii I RL - Reporting Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL:(714) 895-5494 · FAX: (714) 894-7501 I ',1 ~.~=alscience ~_nvironmental Laboratories, Inc. Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 ANALYTICAL REPORT Date Received: Work Order No: Preparation: Method: 10/23/O3 03-10-1400 EPA 3005A Flit. EPA 6010B Project: 2401 Oak Street, Bakersfield, CA Page I of 1 Lab Sample Date Date Date Client Sample Number Number Collected Matdx Prepared Analyzed QC Batch ID Parameter Result RI_ D._.[F Qual Units Lead ND 0.0100 1 mg/L Parameter Result RI_ DF .Q. ual Units Lead ND 0.0100 1 mg/L Parameter Result RI_ D._[F Qual Units Lead ND 0.0100 I mg/L Parameter Result RI- DF Qual Units Lead ND 0.0100 1 mg/L Parameter Result RI_ D__F ~ual Units Lead ND 0.0100 I mg/L Parameter Result R~ D~ qu~! Units Lead ND 0.0100 I m~L i I RL - Reporting Limit , DF - Dilution Factor , Qual - Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894-7501 I j~_nvironmental I ~aboratories, lnc. IBlaine Tech Services, Inc " i 20360 Gramercy Place Torrance, CA 90501-1511 I Project: 2401 Oa~; QuaSi. Control Sample ID I Parameter TPH as Gasoline i I I I I I I I Quality Control - Spike/Spike Duplicate 2401 Oak Street~ Bakersfield~ CA ... Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: DHS LUFT Date Date MS/MSD Batch Matrix Instrument Prepared Analyzed Number MS %REC M,..SD %REC %REC CL RPD RPD CL OJJa!ifiers 92 92 70-112 0 0-17 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~._n vironmental ~ aboratories, Inc. Quality Control - LCSILCS Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: DHS LUFT Date Date LCS/LCSD Batch Quality Control Sample ID Matrix Instrument Prepared Analyzed Number Parameter LCS %REC LCSD %REC %REC CL RPD RPD CL Qualifiers TPH as Gasoline 106 105 72-114 1 0-10 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 ° FAX: (714) 894-7501 ! i ~=-alscience ~_nvironmental I ~-' aboratories, Inc. I I Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 i Project: 2401 Oak Street~ BakersfieldT CA Quality Control Sample ID I Parameter Benzene 1,2-Dichlorobenzene 1,1-Dichloroethene I ~r~;;reoethene I Vinyl Chloride Methyl-t-Butyl Ether (MTBE) Tert-Butyl Alcohol (TBA) Diisopropyl Ether (DIPE) Ethyl-t-Butyl Ether (ETBE) I I I I I Quality Control - Spike/Spike Duplicate Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: EPA 8260B Date Date MS/MSD Batch Matrix Instrument Prepared Analyzed Number MS %REC MSD %REC %REC CL RPD R.PD CL Qualifiers 104 117 102 100 112 102 103 114 106 111 105 105 105 111 106 84-120 2 0-13 115 72-132 2 0-15 105 87-117 3 0-12 103 86-116 3 0-13 113 77-137 I 0-15 104 85~121 2 0-15 106 66-120 3 0-13 113 68-140 I 0-16 110 68-128 3 0-18 116 30-156 5 0-26 107 75-123 I 0-14 108 66-132 3 0-33 108 59-131 3 0-47 115 20-176 4 0-42 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 ° FAX: (714) 894-7501 _nvironmental aboratories, lnc. Blaihe Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Quality Control Sample ID Parameter Benzene Carbon Tetrachloride Chlorobenzene 1,2-Dichlombenzene 1,1-Dichloroethene Toluene Trichioroethene Vinyl Chloride Methyl-t-Butyl Ether (MTBE) Tert-Butyl Alcohol (-I'BA) Diisopropyl Ether (DIPE) Ethyl-t-Butyl Ether (ETBE) ;:~t~nA(3r~yl.M ethyl Ether (TAM E ) Quality Control - LCS/LCS Duplicate Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 5030B Method: EPA 8260B Date Date LCS/LCSD Batch Matrix Instrument Prepared Analyzed Number LCS %REC LCSD %REC %REC CL RPD. RPD CL 101 102 87-117 1 0-5 115 112 77-137 3 0-9 102 100 89-113 I 0-5 99 99 90-114 0 0-8 110 110 81-129 0 0-15 100 100 88-118 0 0-71 101 102 67-121 1 0-21 111 111 71-131 I 0-34 101 104 65-125 3 0--49 85 103 38-140 20 0-98 104 104 77-119 0 0-53 105 106 73-121 1 0-31 102 103 71-119 I 0-33 110 102 54-132 7 0-55 Qualifiers 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 ° FAX: (714) 894-7501 ~ alscience ~F-_nvironmental Laboratories, ~. Quality Control - Spike/Spike Duplicate Blaine Tech Services, Inc 20360 Gramercy Place Torrance, CA 90501'-1511 Date Received: Work Order No: Preparation: Method: 10/23/03 03-10-1400 EPA 3010A Total EPA 601 OB Project: 2401 Oak'StreetT BakersfieldT CA ,,, I t Date Date Quality Control Sample iD , Matrix instrument Prepared Analyzed MS/MSD Batch Number Parameter ~ MSD %REC %REC CL R..I~D RPD CL ~ Lead 104 105 80-120 I 0-20 I I I I I 744'0 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~m~al$cience _nvironmental Quality Control - Laboratory Control Sample i=~ aboratories, Inc. Blaine Tech ServiCes, Inc 20360 Gramercy Place Torrance, CA 90501-1511 Project: 2401 Oak Street, Bakersfield, CA Date Received: 10/23/03 Work Order No: 03-10-1400 Preparation: EPA 3005A Filt. Method: EPA 601 OB Quality Control Sample ID Matrix Instrument Date Analyzed Lab File ID LCS Batch Number Parameter Conc Added Conc Recovered %Rec %Rec GL Qualifiers Lead 1.00 1.06 106 80-120 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894-7501 ~m~-alscience GLOSSARY OF TERMS AND QUALIFIERS ~_nvironmental ~ aboratories, Inc. Work Order Number: 03-10-1400 Qualifier ND Definition Not detected at indicated reporting limit. 7440 Lincoln Way, Garden Grove, CA 92841-1432 · TEL: (714) 895-5494 · FAX: (714) 894-7501 SAMPLE RECEIPT FORM TEMPERATURE - SAMPLES RECEIVED BY: CALSCIENCE COURIER: __ Chilled, cooler with temperature blank provided. Chilled, cooler without temperature blank. ~,--~'C~illed and placed in cooler with wet ice. Ambient and placed in cooler with wet ice. Ambient temperature. 0 C Temperature. blank. LABORATORY (Other than Calscience Courier): __ °C Temperature blank. o C IR thermometer. __ Ambient temperature. Initial: CUSTODY SEAL INTACT: Sample(s): ~ Cooler:__ No (Not Intact) SAMPLE CONDITION: Chain-Of-Custody document(s) received with samples ........... Sample container label(s) consistent with custody papers ..................... __.___~__/~ .... Sample container(s) intact and good condition ................................... /~-~//- .~, .... Correct containers for analyses requested ......................................... ~ .... · Proper preservation noted on sample label(s) ..................................... // ..,~'.... VgA vial(s) free of headspace ............................................. . ........... '/ ...... Tedlar bag(s) free of condensation ...................................................__ ...... COMMENTS: Not Applicable (N/A): No N/A Initial: SHELL Chain Of Custody Record Blaine Tech Se~ices, Inc. BTST 2401 Oak Street, Bakersfield Pending 20360 Gramercy Place, Torrance, CA 90501-1511 ~O~EC~ ~mA~ (H.~p, = PO~ ...~ ,Dy Kath~n Ewlng] 626-256~662 kewln~del~env.~om .... ~BTS · , ,, TURNAROUND TIME {BUSINESS DAYS): ~ 10 DAY5 ~ 5 DAY5 ~ 72 HOU~ ~ 48 H~ ~ 24 HOU~ ~ LESS THAN 24 HOURS REQUESTED ANALYSIS ~ ~ - RW~8 REPORT FOEHAT ~ U~ AGENCY[ General Minerals ..... = % ~ ~ FIELD NOTES: GCIMS MTBE CONF~R~ION: H~GHEST HtG~ES~ per ~RING ALL SPECIAl- INSTRUCTIONS OR NOTES: CHECK BOX IF EDD IS ~ NEEDED ~~ ~ ~ · o ~ ~ ; . ~ a ~ ~ ContainerlPrese ~atlve ~ ~ ~ ~ ~ o = " E or PID Readings HNO~ poly's were field filtered prior to prese~ation (CaCO.), or bicarbonate (HCO,) *Must s~te whether bicarbonate Is repoAed as either calcium carbonate [