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HomeMy WebLinkAboutMITIGATION EMERGENCY RESPONSE NARRAT I ON by Wesley Nicks DATE OF INCIDENT: 10-20-94 DATE OF NARRATION: 10-26-94 LOCATION: Bakersfield Truck Center 7th standard road and Hwy 99 RESPONSIBLE PARTY: Cummings Vacuum Service 5251 Office Park Drive #300 Bakersfield, CA 93309 (805) 631-8362 CONTACTS: 1. Joe Canas (Haz Mat Specialist, K. C. Environmental Health) 2. Dan Starkey (Haz. Mat. Specialist, K.C. Environmental Health) 3. Roger Lee Hurst (Driver, Cummings Vac. Service) 4. Ted Cummings (Owner, Cummings Vac. Service) 5. Mike Bernettie (Supervisor, San Diego Co. Environmental Health) NARRATION: At 16:30 hours I was informed by Canas that Starkey and I were to respond to the above location and sample the contents of a vacuum truck at the request of Bernettie. Canas, Starkey and I arrived at the above location at 17:00 hours. Starkey and I then climbed on the cat walk of the vacuum truck and sampled the liquid inside from two locations. A CGI meter recorded approximately 25 PPM upon opening the hatch. Canas spoke with Hurst and Cummings, and photographed Starkey and I while the samples were obtained. Starkey then labeled the samples and placed them in the refrigerator inside the Haz Mat van V4. On 10-21-94 I took the sample to Zalco labs for analysis. On 10-28-94 Starkey received a call from Ted Cummings regarding the release of the truck in question. Starkey informed Cummings that Kern County did not place any restrictions on the truck and that Cummings needs to contact San Diego County were the case originated. Starkey received numerous calls regarding who would release the truck so it could dump its load. Finely after it was determined that the analysis was non-hazardous the load was dumped. One of the claims was that Canas ordered Cummings not to dump the load until after the samples were analyzed. Canas stated that he told Cummings to contact San Diego County when the analysis was complete. Company Address ZALOO LABORATORIES,' INC. 4309 Armour Avenue · Bakersfield, CA 93308 (805) 3c~5-0539 Office WORK ORDER d city State Attention: ~.'~'q-,i% ~ ,Y ~" cc: YO~'~ - ... SPECIAL INSTRUCTIONS ... Zalco Lab # P.O. # Page :- Invoice # l'I; 028723 / .o~ '* I ws - -Doc# Date Collected Time Collected Container * Sample Sample Description AnalySis Requested Size Type Type 'i*'*", ~- ..'...',~ ~'-i i ' '-' "' - ' ' ' '- · ..' . ~.... ~ ~ , ; ,. : %,.k.~¥ : ' "i.' i'~ ':"' ~,"*~ ~ ~;- '-~ "~ ;" .t?..~ ~ :---, r C/-t , · ,~ .... ;- ' (' i,-' SAMPLES RECEIVED AT ZALCO: Relinquished by:' , Receipt Condition: ,: : AWR: ! i; Date: Terms: Storage: Method of Disposal: Received by: >L. /,..- '[..,..-/~.i Date: C'.O.C.: Quote: Initials: CONTAINER KEY: * G- Glass P- Plastic M- Metal V- VOA O- Other SAMPLE KEY: ' W- Water $- Soil G- Gas P. Petroleum O- Other (805) 861-3636 To PRIORITY ( ) (Explain) PART 1: FIELD SECTION 'n County Environmental Health Ser Department Hazardous Materials SampLe Analy.~ Request . .~r: 2700 'M" STREET, SUITE 300 No BAKERSFIELD, CA 93301 Collector_~-G/~'l/ b) ~/~'-~3 Hours ~ Activity: ~ Enforcement ( ) ASP LOCATION OF SAMPLING: Name C~~ ~//~ Date Sampled /O-20--~y Tim.e~ ( ) H.W. Property ( ) Super ( ) Other Telephone Number ((~'~-~/-- 007 d ~- City Zip No (Lab Only) Collector's Type of Sample No. Sample FIELD INFORMATION Analysis Requested: Chain of Custody: Signature 3. Signature 4. Signature Title Titl~ Inclusive Date~ / Inclusive Dates Title Title Inctusive Dates Inclusive Dates Special Remarks Lc,&. duphcat¢ tampte given to company, ctc. J PART II: LABORATORY SECTION Received By. Sample Allocation: Analysis Required () () () ( ) Other Title qdicate whether sample is studge, sod. etc. \~ou gh~anaiysii\frm ZALCO LABORATORIES, INC. Analytical & Consulting Services San Diego Environmental Health Services P 0 Box 85261 San Diego, CA 82186-5261 Laboratory Date'Receiv. ed: Date Reported: 4]588 10-21-94 10-26-94 Attention: Robert Rapiesta Sample: Liquid Sample Description: 41588-1 DSWN-lO2094-1F 41588-2 DSWN-lO2094-1B Sampled by Wesley Nicks and Dan Starkey of Kern County Environmental Health Department on 10-20-94 at 1755 hours Constituents Flash Point to 200 'F, PMCC Method: ASTM D 93 -1 -2 Resul ts Resul ts None Detected MRL = Minimum Reporting Level = 20 'F None Detected Enclosed please find the results of the analysis of the above described samples by E.P.A. Method 8240 for Volatile Organics. JE/1 b 430~) Armour Avenue Lab Operations Manager Bakersfield, California 9330EB J ,~LATILE ORGANICS ANALYSIS DATA SheET Laboratory Name: ZALCOLABS Concentration: LOW Lab Sample ID: 41588-1 Sample Matrix: WATER Client Sample ID: DSWN102094-1F Percent Moisture: Date Extracted: Date Analyzed: Dilution Factor: 10/25/94 10/25/94 1.0 METHOD 8240 CAS Number ug/1 74-87-3 Chloromethane ...... 5 < 75-71-8 Dichlorodifluoromethane . 5 < 74-83-9 Bromomethane ....... 5 < 75-01-4 Vinyl chloride ...... 5 < 75-00-3 Chloroethane ....... 5 75-69-4 Trichlorofluoromethane . 5 < 75-09-2 Methylene Chloride .... 5 < 540-59-0 cis-l,2-Dichloroethene . . 5 < 67-64-1 Acetone ......... 100 < 75-15-0 Carbon disulfide ..... 5 < 75-35-4 1,1-Dichloroethene .... 5 < 75-34-3 1,1-Dichloroethane .... 5 < 156-60-5 trans-l,2-Dichloroethene . 5 67-66-3 Chloroform ........ 5 < 107-06-2 1,2-Dichloroethane .... 5 < 78-93-3 2-Butanone ........ 100 < 71-55-6 1,1,1-Trichloroethane . . 5 < 563-58-6 1,1-Dichloropropene . . . 5 < 56-23-5 Carbon Tetrachloride 5 < 124-48-1 Bromodichloromethane . . . 5 < 78-87-5 1,2-Dichloropropane . 5 10061-02-6 trans-l,3-Dichloropropene 5 < CAS Number ug/1 79-01-6 Trichloroethene ..... 5 < 74-95-3 Dibromomethane ...... 5 < 124-48-1 Dibromochloromethane . . . 5 < 79-00-5 1,1,2-Trichloroethane . . 5 < 71-43-2 Benzene ......... 5 10061-01-5 cis-l,3-Dichloropropene . 5 < 75-25-2 Bromoform ........ 5 108-10-1 4-Methyl-2-Pentanone . 100 < 591-78-6 127-18-4 79-34-5 108-88-3 108-90-7 100-41-4 100-42-5 1330-20-7 108-86-1 95-49-8 106-43-4 541-73-1 106-46-7 95-50-1 2-Hexanone ........ 100 < Tetrachloroethene .... 5 < 1,1,2,2-Tetrachloroethane 5 < Toluene ......... 5 Chlorobenzene ...... 5 < Ethylbenzene ....... 5 < Styrene ......... 5 Xylene (Total) ...... 5 < Bromobenzene ....... 5 < 2-Chlorotoluene ..... 5 < 4-Chlorotoluene ..... 5 < 1,3-Dichlorobenzene . 5 < 1,4-Dichlorobenzene . . 5 1,2-Dichlorobenzene 5 < The Lab ID for data on this page is BP13X881. Partial reproductions of this report are not valid. Above data applies to submitted sample only. < - Compound analyzed for but not detected. The reported value is the minimum attainable detection limit for the sample. Billing Code: 9187 Date Releas~ Authorization: QC report can be made available additional fee. Information concerning non-target analytes can be made available for an additional fee for a period of 90 days after receipt of this report. .JLATTT.R ORGANICS ANALYSIS DATA~bi,F..F:T Laboratory Name: ZALCO LABS Lab Sample ID: 41588-2 Client Sample ID: DSWN102094-1B Concentration: LOW Sample Matrix: WATER Percent Moisture: Date Extracted: Date Analyzed: Dilution Factor: 10/25/94 10/25/94 1.0 METHOD 8240 CAS Number ug/1 CAS Number 74-87-3 Chloromethane ...... 5 75-71-8 Dichlorodifluoromethane 5 74-83-9 Bromomethane ....... 5 < 75-01-4 Vinyl chloride ...... 5 75-00-3 Chloroethane ....... 5 < 75-69-4 Trichlorofluoromethane . 5 75-09-2 Methylene Chloride .... 5 < 75-25-2 540-59-0 cis-l,2-Dichloroethene . . 5 < 108-10-1 67-64-1 Acetone ......... 100 < 591-78-6 75-15-0 Carbon disulfide ..... 5 < 127-18-4 75-35-4 1,1-Dichloroethene .... 5 < 79-34-5 75-34-3 1,1-Dichloroethane .... 5 < 108-88-3 156-60-5 trans-l,2-Dichloroethene . 5 < 108-90-7 67-66-3 Chloroform ........ 5 < 100-41-4 107-06-2 1,2-Dichloroethane .... 5 < 100-42-5 78-93-3 2-Butanone ........ 100 < 1330-20-7 71-55-6 1,1,1-Trichloroethane . . 5 < 108-86-1 563-58-6 1,1-Dichloropropene . 5 < 95-49-8 56-23-5 Carbon Tetrachloride . . 5 < 106-43-4 124-48-1 Bromodichloromethane . 5 < 541-73-1 78-87-5 1,2-Dichloropropane . . 5 < 106-46-7 10061-02-6 trans-l,3-Dichloropropene 5 < 95-50-1 ug/1 79-01-6 Trichloroethene ..... 74-95-3 Dibromomethane ...... 124-48-1 Dibromochloromethane . . 79-00-5 1,1,2-Trichloroethane . 71-43-2 Benzene ......... 10061-01-5 cis-l,3-Dichloropropene 5 5 5 100 Bromoform ........ 4-Methyl-2-Pentanone . . 2-Hexanone ........ 100 Tetrachloroethene .... 1,1,2,2-Tetrachloroethane Toluene ......... Chlorobenzene ...... Ethylbenzene ....... Styrene ......... X¥1ene (Total) ...... Bromobenzene ....... 2-Chlorotoluene ..... 4-Chlorotoluene ..... 1,3-Dichlorobenzene . . 1,4-Dichlorobenzene 1,2-Dichlorobenzene . . 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 5 < 5 < 5 < 5 < 5 < 5 < 5 < The Lab ID for data on this page is BP14X882. Partial reproductions of this report, are not valid. Above data applies to submitted sample only. < - Compound analyzed for but not detected. The reported value is the minimum attainable detection limit for the sample. Billing Code: 9187 Date Release 'Authorization: QC report can be made available f additional fee. Information concerning non-target analytes can be made available for an additional fee for a period of 90 days after receipt of this report. VOLATILE ORGANICS ANALYSIS DATA SHEET Laboratory Name: ZALCO LABS Lab Sample ID: METHOD-BLANK Client Sample ID: METHOD-BLANK Concentration: Sample Matrix: Percent Moisture: LOW WATER Date Extracted: Date Analyzed: Dilution Factor: METHOD 824O CAS Number ug/1 CAS Number 74-87-3 Chloromethane ...... 5 < 75-71-8 Dichlorodifluoromethane 5 < 74-83-9 Bromomethane ....... 5 < 75-01-4 Vinyl chloride ...... 5 < 75-00-3 Chloroethane ....... 5 75-69-4 Trichlorofluoromethane 5 75-09-2 Methylene Chloride .... 5 < 75-25-2 540-59-0 cis-l,2-Dichloroethene . 5 < 108-10-1 67-64-1 Acetone ......... 100 < 591-78-6 75-15-0 Carbon disulfide ..... 5 < 127-18-4 75-35-4 1,1-Dichloroethene . . . 5 < 79-34-5 75-34-3 1,1-Dichloroethane .... 5 < 108-88-3 156-60-5 trans-l,2-Dichloroethene . 5 < 108-90-7 67-66-3 Chloroform ........ 5 < 100-41-4 107-06-2 1,2-Dichloroethane .... 5 < 100-42-5 78-93-3 2-Butanone ........ 100 < 1330-20-7 71-55-6 1,1,1-Trichloroethane . . 5 < 108-86-1 563-58-6 1,1-Dichloropropene . . 5 < 95-49-8 56-23-5 Carbon Tetrachloride . . 5 < 106-43-4 124-48-1 Bromodichloromethane . . 5 < 541-73-1 78-87-5 1,2-Dichloropropane 5 < 106-46-7 10061-02-6 trans-l,3-Dichloropropene 5 < 95-50-1 79-01-6 Trichloroethene ..... 74-95-3 Dibromomethane ...... 124-48-1 Dibromochloromethane . . 79-00-5 1,1,2-Trichloroethane 71-43-2 Benzene ......... 10061-01-5 cis-l,3-Dichloropropene Bromoform ........ 4-Methyl-2-Pentanone . . 2-Hexanone ....... Tetrachloroethene .... 1,1,2,2-Tetrachloroethane Toluene ........ Chlorobenzene ..... Ethylbenzene ...... Styrene ....... Xylene (Total) ...... Bromobenzene ....... 2-Chlorotoluene ..... 4-Chloro~oluene ..... 1,3-Dichlorobenzene . . . 1,4-Dichlorobenzene . 1,2-Dichlorobenzene . . . 10/25/94 10/25/94 1.0 ug/1 5 ~ 5 < 5 < 5 < 5 < 5 < 5 < 100 < 100 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < 5 < The Lab ID for data on this page is BP7MBLK. Partial reproductions of this report are not valid. Above data applies to submitted sample only. < - Compound analyzed for but not detected. The reported value is the minimum attainable detection limit for the sample. Billing Code: 9187 Analyst: ~ ~// fee. ~t~e~lr~acSan be~ AUthm°~eZaatvi~'~able f~a/n additional Information concerning non-target analytes can be made available for an additional fee for a period of 90 days after receipt of this report. page CASE NO 4158S SAS NO LEVEL LOW WATER SURROGATE PERCENT RECOVERY SUMMARY LABORATORY ZALCO LABS REPORTED 10/26/94 13:37 MATRIX WATER CONTRACT CUSTOMER SAN-DIEGO UNITS ug/1 CODE CS05 CS10 CS15 COMPOUND Toluene-d8 Bromofluorobenzene D4 1,2-Dichloroethane TYPES LOW LIMIT HIGH LIMIT 50.000 164.000 35.000 165.000 35.000 165.000 SAMPLE ID FILE NAME DSWN102094-1F BP13X881 DSWN102094-1B BP14X882 METHOD-BLANK BPTMBLK PERCENT RECOVERIES BY COMPOUND CODE CS05 CS10 CS15 94 84 83 90 82 82 88 80 82 Notes and summary data for this report. Number of compounds outside QC limits: 0 of 9 CROSS-REFERENCE CASE NO 41588 SAS NO TUNE SAMPLE ID BP1BFB OF FILES BY PERFORMANCE TUNE CONTRACT CUSTOMER LAB SAMP ID FILE NAME BFB BFB BPiBFB 100PPB-STD 100PPB-STD BP2S100 80PPB-STD 80PPB-STD BP3SS0 50PPB-STD 50PPB-STD BP4S50 30PPB~STD 30PPB-STD BP5S30 20PPB-STD 20PPB-STD BP6S20 METHOD-BLANK METHOD-BLANK BP7MBLK DSWN102094-1F 41588-1 BP13X881 DSWN102094-1B 41588-2 BP14X882 page AND DATE ANALYZED REPORTED 10/26/94 13:36 INST ANALYZED FINN 10/25/94 FINN 10/25/94 FINN 10/25/94 FINN 10/25/94 FINN 10/25/94 FINN 10/25/94 FINN 10/25/94 FINN 10/25/94 FINN 10/25/94 07:38 07:52 08:28 09:00 09:31 10:01 10:38 13:41 14:i2 WATER MATRIX SPIKE / MATRIX SPIKE DUPLICATE RECOVERY page 1 CASE NO 41561 SAS NO LABORATORY ZALCO LABS REPORTED 10/26/94 15:39 CONTRACT CUSTOMER MCLB FILE NAME BP9X611 SPIKE BP15X61MS DUP SPIKE BP16X61SD SAMPLE ID ZX14-1-4 LAB SAMP ID 41561-1 ANALYZED 10/25/94 11:48 LEVEL LOW MATRIX WATER UNITS ug/1 COMPOUND 1,1-Dichloroethene Trichloroethene Benzene Toluene Chlorobenzene CONC CONC CONC % CONC % TYPES SAMPLE SPIKED MS REC MSD REC V 50.00 V 50.00 V 50.00 V 50.00 V 50.00 51.80 104 58.70 117 51.90 104 48.60 97 55.70 45.30 91 55.70 49.20 98 44.70 89 54.30 109 RPD 13 5 5 8 3 Notes and summary data for this report. % REC = ( MS - SAMPLE ) / SPIKE * 100 RPD = ( MS - MSD ) / ( ( MS + MSD ) / 2 - SAMPLE ) * 100 Underlined values are outside of QC limits. RECOVERY: Number outside QC limits: 0 of 5 RPD: Number outside QC limits: 0 of 5 page 1 INITIAL CALIBRATION DATA VOLATILE HSL COMPOUNDS Min AVE RF for SPCC is 0.300 (1) Max %RSD for CCC is 30% CASE NO 41561 SAS NO LABORATORY ZALCO LABS REPORTED 10/26/94 14:13 CONTRACT CUSTOMER 1ST FILE BP6S20 2ND FILE BP5S30 3RD FILE BP4S50 ANALYZED 10/25/94 4TH FILE BP3S80 5TH FILE BP2S100 INST FINN LEVEL MATRIX COMPOUND Chloromethane Dichlorodifluoromethane Bromomethane Vinyl chloride Chloroethane Trichlorofluoromethane Methylene Chloride cis-l,2-Dichloroethene Acetone Carbon disulfide 1,1-Dichloroethene 1,1-Dichloroethane trans-l,2-Dichloroethene Chloroform 1,2-Dichloroethane 2-Butanone 1,1,1-Trichloroethane Carbon Tetrachloride BromOdichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromomethane Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-l,3-Dichloropropene Bromoform 4-Methyl-2-Pentanone 2-Hexanone 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Styrene Bromobenzene 2-Chlorotoluene 4-Chlorotoluene 1,3-Dichlorobenzene 1ST' 2ND 3RD 4TH 5TM AVE % TYPES RF RF RF RF RF RF RSD C C S C~ C S $ C C 0.326 0.318 0.333 0.329 0.325 0.025 0.023 0.023 .0.025 0.027 0.176 0.187 0.184 0.169 0.156 0.265 0.307 0.300 0.274 0.267 0.280 0.302 0.303 0.291 0.285 0.375 0.405 0.421 0.433 0.443 0.216 0.230 0.243 0.243 0.217 0.519 0.569 0.592 0.598 0.579 0~006 0.007 0.006 0.811 1.502 0.940 0.910 0.877 0.527 0.561 0.582 0.615 0.579 0.581 0.610 0.638 0.656 0.602 0.448 0.484 0.515 0.519 0.485 0.581 0.584 0.596 0.589 0.552 0.246 0.272 0.284 0.290 0.279 0.028 0.030 0.025 0.496 0.518 0.546 0.563 0.565 0.422 0.440 0.451 0.473 0.500 0.281 0.293 0.306 0.299 0.282 0 288 0.322 0.336 0.338 0.314 224 0.266 0.294 0.297 0.277 331 0.333 0.342 0.340 0 349 064 0 069 0.072 0.069 0 168 0 184 0.189 0,183 0 114 0 129 0.140 0.141 0 237 1 317 1.394 1.414 1 281 0 317 0 348 0.346 0 294 0 332 0 0 0 0 293 0 342 0 1 627 1 710 1 0 817 0 849 0 1 836 1 921 2 0 787 0 848 0 0 237 0 253 0 0 339 0 350 0 0.339 0.351 0 0.498 0.510 0 070 174 132 358 316 346 0.333 0.324 071 0.069 0.062 032 0.032 0 029 360 0.343 0 322 905 1.908 1 791 892 0.911 0 889 064 1.958 1 851 900 0.939 0 917 261 0.255 0 238 348 0.356 0 343 357 0.363 0.365 527 0.538 0.550 0.326 0.025 0.174 0.283 0.292 0.415 0.230 0.571 0.006 1.008 0.573 0.617 0.490 0.580 0.274 0.028 0.538 0.457 0.292 0.320 0.272 0.339 0.069 0.180 0.131 1.344 0.322 0.326 0.067 0.031 0.332 1.788 0.872 1.926 0.878 0.249 0.347 0.355 0.525 1.7 6.8 7.1 6.9 3.5 6.4 5.8 5.5 9.1 27.8 5.6 4.8 5.9 2.9 6 2 9 1 5 6 6 6 3 7 6 3 10 8 2 1 4 3 4 7 8 3 5 2 8 5 6 0 7 0 5 6 7 7 6 9 4 4 4 8 7 0 4 3 1 9 3 0 4 0 CASE SAS Minimum RF for CONTINUING CALIBRATION CHECK VOLATILE HSL COMPOUNDS SPCC is 0.300 (1} Maximum NO 41561 NO LABORATORY ZALC0 LABS REPORTED 10/26/94 14:11 %D for CCC CONTRACT CUSTOMER page 1 is 25% FILE NAME BP4S50 TYPE IC-050 INST FINN SAMPLE ID 50PPB-STD LAB SAMP ID 50PPB-STD ANALYZED 10/25/94 09:00 LEVEL MATRIX UNITS [ 2ND CODE C010 C012 C015 C020 C025 C028 C030 C031 C035 C040 C045 C050 C055 C060 C065 CllO Cl15 C120 C130 C140 C145 C150 C153 C155 C160 C165 C170 C180 C205 C210 C220 C225 C230 C235 C240 C245 C250 FILE BP6S20A COMPOUND Chlorome=hane Dichlorodifluoromethane Bromomethane Vinyl chloride Chloroethane Trichlorofluoromethane Methylene Chloride cis-l,2-Dichloroethene Acetone Carbon disulfide 1,1-Dichloroethene 1,1-Dichloroethane trans-l,2-Dichloroethene Chloroform 1,2-Dichloroethane 2-Butanone 1,1,1-Trichloroethane Carbon Tetrachloride Bromodichloromethane 1,2-Dichloropropane trans-l,3-Dichloropropene Trichloroethene Dibromomethane Dibromochloromethane 1,1,2-Trichloroethane Benzene cis-l,3-Dichloropropene Bromoform 4-Methyl-2-Pentanone 2-Hexanone Tetrachloroethene 1,1,2,2-Tetrachloroethane Toluene Chlorobenzene Ethylbenzene Styrene Xvl~n, (T~ta]l ANALYZED 10/25/94 10:01 RESP TYPES FACTOR S 0.333 0.023 0.184 C 0.300 0.303 0.421 0.243 0.592 0.006 0.940 C 0.582 S 0.638 0.515 C 0.596 0.284 0.028 0.546 0.451 0.306 C 0.336 0 294 0 342 0 072 0 189 0 140 1 394 0 348 S 0 346 0 071 0 032 0 428 S 0 360 C 1 9O5 0 892 C 2 064 0 900 RESP .FACTOR 0.326 0.025 0.174 0. 283 0.292 0.415 0.230 0.571 0.006 1. 008 0.573 0.617 0.490 0. 580 0.274 0.028 0. 538 0.457 0.292 0.320 0.272 0. 339 0.069 0. 180 0. 131 1. 344 0.322 0.326 0.067 0.031 0.431 0. 332 1.788 0. 872 1.926 0.878 /'~ "/10 % DIFF 2.1 -8.0 5.7 6.0 3.8 1.4 5.7 3.7 0.0 -6.7 1.6 3.4 5.1 2.8 3.6 0.0 1.5 -1 3 4 8 5 0 8 1 0 9 4 3 5 0 6 9 3 7 8 1 6 1 6 0 3 2 -0 7 8 4 6 5 2 3 7 2 2 5 page 2 CONTINUING CALIBRATION CHECK VOLATILE HSL COMPOUNDS Minimum RF for SPCC is 0.300 (1) Maximum %D for CCC is 25% CASE NO 41561 LABORATORY ZALCO LABS CONTRACT SAS NO REPORTED 10/26/94 14:11 CUSTOMER RESP RESP % CODE COMPOUND TYPES FACTOR FACTOR DIFF C260 Bromobenzene 0.261 0.249 4.8 C270 2-Chlorotoluene 0.348 0.347 0.3 C275 4-Chlorotoluene ' 0.357 0.355 0.6 C294 1,3-Dichlorobenzene 0.527 0.525 0.4 C298 1,4-Dichlorobenzene 0.492 0.484 1.7 C300 1,2-Dichlorobenzene 0.415 0.393 5.6 C$05 Toluene-d8 1.614 1.513 6.7 CSl0 Bromoflu0robenzene 0.504 0.473 6.6 CS15 D4 1,2-Dichloroethane 0.243 0.222 9.5 Notes and summary data for this report. RF(100) - - Response Factor from daily standard file at 100 ug/1 AVE RF %D CCC SPCC (1) - - Average Response Factor from initial calibration Form VI Percent Difference Calibration Check Compounds (C) System Performance Check Compounds (S) Minimum RF for Bromoform is 0.250 Form VII Tuning Report 10/25/94 7:38:00 + Instrument: FINN Case Numbe~: m/z Intensity BROMOFLUOROBENZENE 7:51 Data: BPIBFB #1243 Call: CALTAB # 3 Analyst: SVM Labo~ato~g: %. RA Ion Abundance C~iteria Min % Max % Mass 50 10672. 27.3 15.0 40.0 95 75 20736. 53.0 30.0 &O.O 95 95 39104. 100.0 100.0 ...... 96 2732. 7.0 5.0 9.0 95 173 O. 0.0 --- 2.0 174 174 24896. 63.7 O0. O --- 95 175 1718. 4.4 5.0 9.0 174 176 23680. 60.6 95.0 101.0 174 177 1&22. 4.1 ~.0 9.0 176 Base m/z: 95 RIC: 182~72. Acct. No.: Contract: Actual 27.3 53.0 100.0 7.0 0.0 63.7 6.9 95.1 6.8 Status PASS PASS PASS PASS PASS PASS PASS PASS PASS CASE NO 41561 SAS NO page 2 INITIAL CALIBRATION DATA VOLATILE HSL COMPOUNDS Min AVE RF for SPCC is 0.300 (1) Max %RSD for CCC is 30% LABORATORY ZALCO LABS CONTRACT REPORTED 10/26/94 14:13 CUSTOMER COMPOUND 1,4-Dichlorobenzene 1,2-Dichlorobenzene Toluene-d8 Bromofluorobenzene D4 1,2-Dichloroethane 1ST 2ND 3RD 4TH 5TH AVE % TYPES RF RF RF RF RF RF RSD 0.470 0.482 0.492 0.491 0.486 0.380 0.408 0.415 0.405 0.359 1.390 1.434 1.614 1.571 1.555 0.420 0.457 0.504 0.498 0.487 0.200 0.220 0.243 0.228 0.217 0.484 0.393 1.513 0.473 0.222 1.8 5.9 6.3 7.4 !7.1 Notes and summary data for this report. RF Response Factor AVE RF - Average Response Factor %RSD - - Percent Relative Standard Deviation CCC - - Calibration Check Compounds (C) SPCC - - System Performance Check Compounds (S} (1) - - Minimum AVE RF for Bromoform is 0.250 Form VI