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BUSINESS PLAN 5/5/2008
_ - _ _ h .~ o ii STATE FARM MUTUAL AUTOMOBILE li 900 OLD RIVER RD '_ _ ~~ ---~ ~~~~ ~~~ ~~~ ~~~ ~ ~' ~~ ~ ,~~ (11 (~~ Prevention Services Unified Permit SUBJECT TO CONDITIONS OF PERMIT Issued by: Permit ID# 015-021-001765 .... V ./', '. i .... :", ~,?" .'"i" i 900 OLD RIVER ROAD '~" ' BAKERSFIELD Bakersfield Fire Department OFFICE OF PREVENTION SERlflCES 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 Voice (661) 326-3979 FAX (661) 852-2171 Approved .by: THIS PERMIT IS ISSUED FOR THE FOLLOWING: l Hazardous Materials Plan [] Underground Storage of Hazardous Materials [] California Accidental Release Program [] Hazardous Waste Generator and/or Treatment · Above ground Storage Storage of Petroleum [] Paint Spray Booth [] Industrial Hood Suppression System Expiration Date: ~:/ph Hue~, Director-- ~ Prevention Services June 30, 2006 Hazardous. Materials/Hazardous Waste Unified Permit CONDITIONS, OF PERMIT ,ON REVERSE SIDE Permit ID#:: 015-000-001765 STATE FARM .MUTUAL LOCATION: 900 OLD RIVER RD Thi~ _.ermit is issued for the followin_o: El Hn~,rdous Materials Plan [] Underground Storage of HazardOus Materials [] Risk Management Program [] Hazardous Waste On-Site Treatment Issued by: Bakersfield Fire Department OFFICE OF ENVIRONMENTAL SER VICES' 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 Voice (661) 326-3979 FAX (661) 326-0576 Approved by:. Expi/ation Date: Offic, e of Ev '~nm~aTServices "' Issue Date · June 30. 2003 Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE ......... ,,,,m,~,,;vv~,,,~v,~ ,, .... This permit is issued for the following: ...... :~!i~::?"J~ "3:z ~' :': i:' :: :' .¢,"~: i m ll LOCATION 900 ~,:'..";~T [~h .... m,,::l '"-':':Z~::~u ~],l,.~,~:::. ¥ :~ :.l.lll ~ l I "~ '..::'-' Issued by: Bakersfield Fire Department OFFICE OF ENVIR ONMENTAL SER VICES 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 Voice (805) 326-3979 FAX (805) 326-0576 Approved by: Office of ~aml~ental Servi&s Expiration Date: June 30, 2000 d. 3 STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 Manager ~.r,~3 l~+~kln Location: 900 OLD RIVER RD City BAKERSFIELD BusPhone: (661) 663-1302 Map 123 CommHaz High Grid: 06B FacUnits: 1 AOV: CommCode: BFD STA 15 EPA Numb: SIC Code:6331 DunnBrad:00-692-8097 Emergency Contact / Title Emergency Contact / Title ROD SKINNER / LOSS PREY SPEC ~.~I~3'I~TK~,E Glean Lynch/ SUPERVISOR Business Phone: (661) 663-1378x Business Phone !¢~-'~l5'il~ ~~~~ (¢~~) 24-Hour Phone (661) 304-6483x . ~ 24-Hour Phone (.~%~~) -8~ o~"t~ Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: RSs Fire React ImmHlth DelHlth Contact CMS Phone: (309) 766-0950x MailAddr: 1 STATE FARM PLAZA State: IL City BLOOMINGTON Zip 61710-0001 Owner STATE FARM MUTUAL AUTOMOBILE INS Phone: (309) 766-0950x Address 1 STATE FARM PLAZA State: IL City BLOOMINGTON Zip 61710-0001 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif ' d: RSs : Yes ParcelNo: Emergency Directives: PROG A - HAZMAT A/T PROG T - ABOVEGROUND STORAGE TANK - 'v I ~ ~JUC 3 1 ~~~7 F;a ed on my inr~uiry of thaw individuals respc;~ zible ;ar oct~inir?g the 'snf~>rrnation, t ce;tiYy under penalty of lav~.~ that I have personally examined and am tam~liar with the intormatian submitted and t~;eiieve fhe infarmation is true, accurate, and complete. Signature ____. Date -1- 07/16/2007 ~ '~ F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order Fixed Containers at Site ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP LEAD CALCIUM BATTERY R IH S 192.00 GAL Hi BOILER WATER TREATMENT CHEMICAL R IH L 120.00 GAL Mod MICRO ORGANISM CONTROL CHEMICAL IH L 80.00 GAL Mod DIESEL FUEL #2 F R IH DH L 2000.00 GAL Low COOLING WATER TREATMENT IH G 100.00 GAL UnR COOLING WATER TREATMENT IH L GAL UnR -2- 07/16/2007 ~~ t -3- 07/16/2007 ~ `1~ F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ ~ Inventory Item 0004 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME LEAD CALCIUM BATTERY Days On Site LIBERTY 1000 SERIES 365 Location within this Facility Unit Map: Grid: UNINTERRUPTED POWER SUPPLY RM SE CRNR OF BLDG CAS# ~SolidE TMixtur~ Ambient~E ~ ATiE~MPeRATURE OTHER NTSPECIFYYPE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 1.00 GAL 192.00 GAL 192.00 GAL • t1AG11KLVU5 1.V1~lYV1VJ;1V1A %Wt. RS CAS# 77.00 Lead No 7439921 9.00 Sulfuric Acid (EPA) No 7664939 0.30 Tin No 7440315 nt~~Htcl~ rja~l;~aln~ly l ~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No No/ Curies R IH / / / Hi ~ Inventory Item 0006 COMMON NAME / CHEMICAL NAME BOILER WATER TREATMENT CHEMICAL NEXGUARD 22352 Location within this Facility Unit BOILER RM SE CRNR OF BLDG Facility Unit: Fixed Containers at Site ~ Days On Site 365 Map: Grid: CAS# Liquid TMixture ~ Ambient~E ~ AmbientT~E ~ PLASTOICTCONTAINERE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 120.00 GAL 120.00 GAL 120.00 GAL ns-~~r.,ru~vu~ ~V1~irV1V1;1Vla °sWt. RS CAS# 10.00 Sodium Sulfate No 7757837 5.00 N,N-Diethylethanolamine No 100378 5.00 Potassium Hydroxide No 1310583 I11•iGE-1tCU 1'..7.7J;bJ1~1L'1V 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Mod -4- 07/16/2007 ~'~, F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ ~ Inventory Item 0007 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME MICRO ORGANISM CONTROL CHEMICAL Days On Site STABREX ST20 365 Location within this Facility Unit Map: Grid: CHILLER RM SE CRNR OF BLDG CAS# 1310-73-2 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixtur~ Ambient ~ Ambient ~STIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 80.00 GAL 80.00 GAL 80.00 GAL /'1 nr~c~ru~l~vvJ ~.OMPONENTS %Wt. RS CAS# 5.00 Sodium Hydroxide No 1310732 nrsc~rutl~ r~a ar,JJ1~1~tvtJ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / Mod ~ Inventory Item 0005 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME DIESEL FUEL #2 Days On Site 365 Location within this Facility Unit Map: Grid: OUTSIDE SE CRNR BY GENERATOR RM CAS# 68476-34-6 Liquid TYPE PRESSURE ~ TAmEbMPeRATURE CONTAINER TYPE TMixture ~ Ambient ABOVE GROUND TANK Largest Container 2000.00 GAL rie-~uruuw~a COMPONENTS %Wt. RS CAS# 100.00 Diesel Fuel No. 2 No 68476302 rLti[~tiiCL ti~ 7.7 P~J J1"1~1V1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F R IH DH / / / Low AMOUNTS AT THIS LOCATION Daily Maximum 2000.00 GAL Daily Average 2000.00 GAL -5- 07/16/2007 ,~ ii \~ F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ ~ Inventory Item 0008 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME COOLING WATER TREATMENT Days On Site 53513 365 Location within this Facility Unit Map: Grid: COOLING TOWERS E SIDE OF BLDG CAS# 64665-57-2 STATE TYPE PRESSURE TEMPERATUR CONTAINER TYPE Gas TMixtur~-Above Ambient Ambient OTHER - SPECIFY AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 100.00 GAL 100.00 GAL 100.00 GAL t1AGEitCLVU~J 1.V1~lYV1VL"1V1.~ oWt. RS CAS# 5.00 Sodium Tolyltriazole No 64665572 5.00 Sodium Bisulfate No 7681381 t11~GHKL H~~~~J1~11;1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / UnR ~ Inventory Item 0009 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME COOLING WATER TREATMENT Days On Site ONDEO NALCO DEPOSIT PENATRANT (73551) 365 Location within this Facility Unit Map: Grid: CHILLER RM SE CRNR OF BLDG CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid Mixture Ambient Ambient PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average GAL GAL GAL HAZARDOUS COMPONENTS %Wt. RS CAS# HAZARD ASSESSMENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / UnR -6- 07/16/2007 n ~~ F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ Fast Format ~ ~ Notif./Evacuation/Medical Overall Site ~ ~ Agency Notification 03/27/2006 ~ CITY OF BAKERSFIELD, FIRE DEPT - ALARM AND/OR 324-6551 STATE FARM CENTRAL MONITORING SERVICE - ALARM AND/OR 309-766-0950 WAYNE LEPINE, ADMINISTRATIVE SERVICE MGR - 663-1300 WK/636-5252 PGR VICTOR GREEN, AD SERVICES ASSISTANT MGR - 663-1302 WK/477-4358 PGR ~f[J.D`I ~C~ C R,~'6b3'~l~l~`1 -0' 1`~8~PGR~ ROD SKINNER, LOSS PREVENTION SPECIALIST - 663-1378 WK/304-6483 PGR ~oh~ -NiNkl-e, , A-fJ s~~~~cLS M~t~N7~NnNc~ S~E~. - C~~3 -1~jsl f ~~I -138" ®ER- Employee Notif./Evacuation 01/18/2000 = INTERNAL AUDIBLE AND VISUAL STROBE ALARMS ARE THROUGHOUT THE BLDG TO NOTIFY EMPLOYEES TO EVACUATE. EACH DEPT WITHIN THE BLDG HAS ESTABLISHED EXITS AND GATHERING PLACES OUTSIDE FOR ACCOUNTING OF EMPLOYEES. THE ADMINISTRATIVE SERVICES DEPARTMENT HAS RESPONSIBILITY FOR EVACUATION AND THE MONITORING OF EXITS AND ALARMS. Public Notif./Evacuation 10/20/1997 THERE ARE NO KNOWN HAZARDOUS MATERIALS ON SITE THAT WOULD CAUSE AN EMERGENCY NECESSITATING PUBLIC EVACUATION. Emergency Medical Plan 03/27/2006 THE OFFICE HAS TWO FULL-TIME AND ONE PART-TIME NURSE ON SITE TO HANDLE FIRST AID. EMERGENCY SERVICES THAT ARE SUMMONED ARE DIRECTED TO THE APPROPRIATE LOCATION BY TRANS WEST SECURITY, OUR 24-HOUR GUARD SERVICE CONTRACTOR. THE ADMINISTRATIVE SERVICE DEPT ALSO AIDS THE MEDICAL STAFF AND EMERGENCY PERSONNEL BY CONDUCTING EMERGENCY OPERATIONS THROUGHOUT THE BLDG. -7-_ 07/16/2007 _.a ye F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 Fast Format ~ Mitigation/Prevent/Abatemt Overall Site ~ Release Prevention 04/11/2007 BACK-UP GENERATOR DIESEL STORAGE TANK - OUR ABOVEGROUND 2,000-GAL DIESEL TANK HAS A PROTECTIVE 6-INCH THICK, 400 PSI, CONCRETE ENCLOSURE. THIS TANK IS INTERNALLY SEALED WITH A LINER RESISTANT TO METHANOL-BASED FUELS AND HAS A 3-GAL OVERFLOW TRAP FOR. PROTECTION DURING FILLING. BOILERS/CHILLERS/ COOLING TOWERS - CHEMICALS FOR THESE ARE STORED IN -CORROSIVE PLASTIC CONTAINERS (SERVICE HOPPERS). GEL BATTERIES - THE' ELECTROLYTE OF THE UNINTERRUPTED POWER SUPPLY (UPS) BATTERY BANK IS IN INDIVIDUALLY-SEALED CELLS LINKED TOGETHER. THE MSDS STATES NO RELEASES OR'EMMISSIONS UNDER NORMAL OPERATIONS. Release Containment 04/11/2007 THE DIESEL STORAGE TANK HAS A BELOW GROUND SPILL/LEAK SUMP PIT TO CONTAIN AN ACCIDENTAL RELEASE. THE PLASTIC TANKS THAT CONTAIN THE BOILER, CHILLER, AND' COOLING TOWER CHEMICALS ARE PROTECTED BY CEMENT BERMS SURROUNDING THE TANKS. THESE CHEMICALS ARE PUMPED DIRECTLY INTO THE PLASTIC SERVICE-TANKS FROM THE VENDORS TRUCK. THERE IS NO EMPLOYEE CONTACT WITH THE CHEMICALS AND NO SURPLUS STORAGE OUTSIDE OF THE SERVICE TANKS. THERE IS NO CONTAINMENT BERM AROUND THE UPS BATTERY BANK AS THE GEL ELECTROLYTE DOES NOT REQUIRE ONE. THERE IS A SPILL KIT LOCATED NEAR THE UPS BATTERIES AND THE SERVICE TANKS OF THE BOILER, CHILLER, AND COOLING TOWER CHEMICALS. Clean Up 10/20/1997 SPILL KITS ARE LOCATED IN APPROPRIATE AREAS TO HANDLE SMALL SPILLS. THESE KITS INCLUDE, BUT ARE NOT LIMITED TO, ABSORBENT PILLOWS AND GRANULAR ABSORBENTS. IF A LARGE SPILL WERE TO OCCUR, THE FIRE DEPT WILL BE NOTIFIED. V1..11C1 1ZC.7VU1t1C til: l..1VQl..l V11 -8- 07/16/2007 ~: ~~, F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ JYCC:1d1 rid'GCLICIS Utility Shut-Offs 04/11/2007 GAS - SW CRNR OF BLDG ELECTRICAL - SE CRNR OF BLDG WATER - NW CRNR OF BLDG SPECIAL - SW CRNR OF BLDG LOCK BOX - CHAINS AND PADLOCKS ON WATER VALVES AT NW CRNR OF BLDG. GAS SERVICE HAS LARGE SQUARE NUT COMMON. ELECT SERVICE IN INTERNAL CABINETS SE CRNR OF BLDG WITH NO LOCKS. Fire Protec./Avail. Water 12/27/2006 PRIVATE FIRE PROTECTION - SPRINKLERS, WET-PIPE SYSTEM, EXCEPT DATA PROCESSING EQUIPMENT RM AND MAIN TELEPHONE RM. THESE ROOMS HAVE A DRY-PIPE PREACTION SYSTEM. MAIN ELECTRICAL EQUIPMENT AND UPS ROOMS HAVE SEPARATE DRY-PIPE SUPPRESSION SYSTEM. PORTABLE FIRE EXTINGUISHERS WALL-MOUNTED IN BLDG OF ABC-TYPE, WITH HALON-TYPE IN SENSITIVE EQUIPMENT AREA. Building Occupancy Level 12/27/2006 1200 EMPLOYEES -9- 07/16/2007 -~ ~ ;k. F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ Fast Format ~ ~ Training Overall Site ~ ~ Employee Training 12/27/2006 ~ MSDS SHEETS ON FILE. BRIEF SUMMARY OF TRAINING PROGRAM: STATE FARM EMPLOYEES WHO WORK WITH OR NEAR THE HAZARDOUS MATERIALS ON SITE PARTICIPATE IN HAZARD & CHEMICAL AWARENESS TRAINING, PERSONAL PROTECTIVE EQUIPMENT TRAINING, AS WELL AS, JOB FUNCTION AND EMERGENCY RESPONSE DUTIES. TRAINING PROGRAMS ARE INITIAL AND HAVE ESTABLISHED REFRESHER FREQUENCIES. rayc ~ Held for Future Use nclu tui ru~uic uac -10- 07/16/2007 ~~~~ i STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 Manager JAVIER BERMEA Location: 900 OLD RIVER RD City _: BAKERSFIELD BusPhone: (661) 663-1302 Map 123 CommHaz High Grid: 06B FacUnits: 1 AOV: CommCode: BFD STA 15 EPA Numb: SIC Code:6331 DunnBrad:00-692-8097 Emergency Contact / Title Emergency Contact / Title ROD SKINNER / LOSS PREV SPEC JOHN HINKLE / SUPERVISOR Business Phone: (661) 663-1378x Business Phone: (661) 663-1951x 24-Hour Phone (661) 304-6483x 24-Hour Phone (663) 301-1388x Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: RSs Fire React ImmHlth DelHlth Contact CMS Phone: (309) 766-0950x MailAddr: 1 STATE FARM PLAZA State: IL City BLOOMINGTON Zip 617.10-0001 Owner STATE FARM MUTUAL AUTOMOBILE INS Phone: (309) 766-0950x Address 1 STATE FARM PLAZA State: IL City BLOOMINGTON Zip 61710-0001 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif~d: RSs: Yes ParcelNo: Emergency Directives: PROG A - HAZMAT PROG T - ABOVEGROUND STORAGE TANK h1~ V tia~,Pd An my inquiry cif thQso individuals roSpr~nt~iF~l~ fpr ak~talr~lnp the infarmptlon, I Certify under pen~ity of Ir~w_thp9 I lave personally information ith th e~ App E ` i 1 207 e examined mnd errs farnlllar w L 1 Oi I submitted and bvlleve the information is true, a urate, and co ete. -~~d 7 ignature ate -1- 02/06/2007 v ~ F STATE FARM MUTUAL AUTOMOBILE INS ~ Hazmat Inventory ~ MCP+DailyMax Order = SiteID: 015-021-001765 ~ By Facility Unit ~ Fixed Containers at Site ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP LEAD CALCIUM BATTERY R IH S 192.00 GAL Hi BOILER WATER TREATMENT CHEMICAL R IH L 120.00 GAL Mod MICRO ORGANISM CONTROL CHEMICAL IH L 80.00 GAL Mod DIESEL FUEL #2 F R IH DH L 2000.00 GAL Low COOLING WATER TREATMENT IH G 100.00 GAL UnR COOLING WATER TREATMENT IH L GAL UnR -2- 02/06/2007 -3- 02/06/2007 ,. F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ ~ Inventory Item 0004 Facility Unit: Fixed Containers at Site ~ COMMON NAME,/ CHEMICAL NAME LEAD CALCIUM BATTERY Days On Site LIBERTY 1000 SERIES 365 Location within this Facility Unit Map: Grid: UNINTERRUPTED POWER SUPPLY RM SE CRNR OF BLDG CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Solid TMixture ~mbient ~ Ambient OTHER - SPECIFY AMOUNTS AT THIS LOCATION Largest ContiioorG~ Daily M92ioom GAL I Daily 192r00e GAL - ti1~GH.hCL V U.7 lr V1~lY V1V I;1V l ~ %Wt. RS CAS# 77.00 Lead No 7439921 9.00 Sulfuric Acid (EPA) No 7664939 0.30 Tin No 7440315 rir-~~sircl~ tiaal~.a~ririVlS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No No/ Curies R IH / / / Hi ~ Inventory Item 0006 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME BOILER WATER TREATMENT CHEMICAL Days On Site NEXGUARD 22352 365 Location within this Facility Unit Map: Grid: BOILER RM SE CRNR OF BLDG CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixtur~mbient ~ Ambient PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Co120100rGAL Daily 120100m GAL I Daily 120r00e GAL L1L"~GKKLVU.7 l..Vl"lYV1V1:,1V 1 ~7 %Wt. RS CAS# 10.00 Sodium Sulfate No 7757837 5.00 N,N-Diethylethanolamine No 100378 5.00 Potassium Hydroxide No 1310583 I11~GHCtL 1-~ JJ1;.751~1~1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Mod -4- 02/06/2007 r F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ ~ Inventory Item 0007 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME MICRO ORGANISM CONTROL CHEMICAL Days On Site STABREX ST20 365 Location within this Facility Unit Map: Grid: CHILLER RM SE CRNR OF BLDG CAS# 1310-73-2 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixtur~mbient ~ Ambient ~ PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 80.00 GAL 80.00 GAL 80.00 GAL I11~GHt(1lVUw7 1.V1~lYV1VI;1V 1 J %Wt. RS CAS# 5.00 Sodium Hydroxide No 1310732 t1E~GL~tCL Hb Jl;SJ1~11;1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / Mod ~ Inventory Item 0005 ~ COMMON NAME / CHEMICAL NAME I DIESEL FUEL #2 Location within this Facility Unit OUTSIDE SE CRNR BY GENERATOR RM STATE TYPE PRESSURE Liquid TMixture r Ambient Facility Unit: Fixed Containers at Site ~ Days On Site 365 Map: Grid: CAS# 68476-34-6 TEMPERATURE CONTAINER TYPE Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 2000.00 GAL 2000.00 GAL 2000.00 GAL --•- IIAGA.tCLVU~ 1..V1~lYV1VL"1V1~ %Wt. RS CAS# 100.00 Diesel Fuel No. 2 No 68476302 riHGHKL tj. 7.7tS.7.71~1L'i1V-1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F R IH DH / / / Low -5- 02/06/2007 F STATE FARM MUTUAL AUTOMOBILE INS ~ Inventory Item 0008 COMMON NAME / CHEMICAL NAME COOLING WATER TREATMENT 53513 Location within this Facility Unit COOLING TOWERS E SIDE OF BLDG STATE TYPE PRESSURE _ Gas Mixtur~Above Ambient SiteID: 015-021-001765 ~ Facility Unit: Fixed Containers at Site ~ Days On Site 365 Map: Grid: CAS# 64665-57-2 TEMPERATURE CONTAINER TYPE Ambient OTHER - SPECIFY AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 100.00 GAL 100.00 GAL I 100.00 GAL ritiGKKLV U ~7 1.V1~1Y V1V L' 1V 1 J %Wt. RS CAS# 5.00 Sodium Tolyltriazole No 64665572 5.00 Sodium Bisulfate No 7681381 11riGH.[tL HJ JP~JJ1.1L,1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / UnR ~ Inventory Item 0009 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME COOLING WATER TREATMENT Days On Site ONDEO NALCO DEPOSIT PENATRANT (73551) 365 Location within this Facility Unit Map: Grid: CHILLER RM SE CRNR OF BLDG CAS# Liquid TMixture ~ Ambient~E ~ AmbientT~E -~STOICTCONTAINERE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average GAL GAL GAL HAZARDOUS COMPONENTS , %Wt. HAZARD RSA CAS# AS SESSMENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / UnR -6- 02/06/2007 F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 Fast Format ~ Notif./Evacuation/Medical Overall Site ~ Agency Notification 03/27/2006 CITY OF BAKERSFIELD, FIRE DEPT - ALARM A] STATE FARM CENTRAL MONITORING SERVICE - WAYNE LEPINE, ADMINISTRATIVE SERVICE MGR VICTOR GREEN, AD SERVICES ASSISTANT MGR JUDI BASSIGNANI, AD SERVICES MAINTENANCE ROD SKINNER, LOSS PREVENTION SPECIALIST STD/OR 324-6551 ALARM AND/OR 309-766-0950 - 663-1300 WK/636-5252 PGR - 663-1302 WK/477-4358 PGR SUPER - 663-1941 WK/635-6078 PGR - 663-1378 WK/304-6483 PGR 9 9 Employee Notif./Evacuation 01/18/2000 INTERNAL AUDIBLE AND VISUAL STROBE ALARMS ARE THROUGHOUT THE BLDG TO NOTIFY EMPLOYEES TO EVACUATE. EACH DEPT WITHIN THE BLDG HAS ESTABLISHED EXITS AND GATHERING PLACES OUTSIDE FOR ACCOUNTING OF EMPLOYEES. THE ADMINISTRATIVE SERVICES DEPARTMENT HAS RESPONSIBILITY FOR EVACUATION AND THE MONITORING OF EXITS AND ALARMS. Public Notif./Evacuation 10/20/1997 THERE ARE NO KNOWN HAZARDOUS MATERIALS ON SITE THAT WOULD CAUSE AN EMERGENCY NECESSITATING PUBLIC EVACUATION. Emergency Medical Plan 03/27/2006 THE OFFICE HAS TWO FULL-TIME AND ONE PART-TIME NURSE ON SITE TO HANDLE FIRST AID. EMERGENCY SERVICES THAT ARE SUMMONED ARE DIRECTED TO THE APPROPRIATE LOCATION BY TRANS WEST SECURITY, OUR 24-HOUR GUARD SERVICE CONTRACTOR. THE ADMINISTRATIVE SERVICE DEPT ALSO AIDS THE MEDICAL STAFF AND EMERGENCY PERSONNEL BY CONDUCTING EMERGENCY OPERATIONS THROUGHOUT THE BLDG. -7- 02/06/2007 F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ Fast, Format ~ ~ Mitigation/Prevent/Abatemt Overall Site ~ ~ Release Prevention 03/27/2006 ~ 1) BACK-UP GENERATOR DIESEL STORAGE TANK - OUR ABOVEGROUND 2,000-GAL DIESEL TANK HAS A PROTECTIVE 6-INCH THICK, 400 PSI, CONCRETE ENCLOSURE. THIS TANK IS INTERNALLY SEALED WITH A LINER RESISTANT TO METHANOL-BASED FUELS AND HAS A 3-GAL OVERFLOW TRAP FOR PROTECTION DURING FILLING. 2) BOILERS/CHILLERS/COOLING TOWERS - CHEMICALS FOR THESE ARE STORED IN NON-CORROSIVE PLASTIC CONTAINERS (SERVICE HOPPERS). 3) GEL BATTERIES - THE GEL ELECTROLYTE OF THE UNINTERRUPTED POWER SUPPLY (UPS) BATTERY BANK IS IN 192 INDIVIDUALLY-SEALED CELLS LINKED TOGETHER. THE MSDS STATES NO RELEASES OR EMMISSIONS UNDER NORMAL OPERATIONS. Release Containment 10/20/1997 1) THE DIESEL STORAGE TANK HAS A BELOW GROUND SPILL/LEAK SUMP PIT TO CONTAIN A ACCIDENTAL RELEASE. 2) THE PLASTIC TANKS THAT CONTAIN THE BOILER, CHILLER, AND COOLING TOWER CHEMICALS ARE PROTECTED BY CEMENT BERMS SURROUNDING THE TANKS. THESE CHEMICALS ARE PUMPED DIRECTLY INTO THE PLASTIC SERVICE TANKS FROM THE VENDORS TRUCK. THERE IS NO EMPLOYEE CONTACT WITH THE CHEMICALS AND NO SURPLUS STORAGE OUTSIDE OF THE SERVICE TANKS. 3) THERE IS NO CONTAINMET BERM AROUND THE UPS BATTERY BANK AS THE GEL ELECTROLYTE DOES NOT REQUIRE ONE. THERE IS A SPILL KIT LOCATED NEAR THE UPS BATTERIES AND THE SERVICE TANKS OF THE BOILER, CHILLER, AND COOLING TOWER CHEMICALS. Clean Up 10/20/1997 SPILL KITS ARE LOCATED IN APPROPRIATE AREAS TO HANDLE SMALL SPILLS. THESE KITS INCLUDE, BUT ARE NOT LIMITED TO, ABSORBENT PILLOWS AND GRANULAR ABSORBENTS. IF A LARGE SPILL WERE TO OCCUR, THE FIRE DEPT WILL BE NOTIFIED. -8- 02/06/2007 F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall Site ~ ~,_ v~.,iic1 iCCavul~.c t]1.1~1VCLl~1V11 -9- 02/06/2007 'E ~ F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ J~JCC:1cL1 rid'GdiuS Utility Shut-Offs 12/27/2006 A) GAS - SW CRNR OF BLDG B) ELECTRICAL - SE CRNR OF BLDG C) WATER - NW CRNR OF BLDG D) SPECIAL - SW CRNR OF BLDG E) LOCK BOX - CHAINS AND PADLOCKS ON SERVICE HAS LARGE SQUARE NUT COMMON. CRNR OF BLDG WITH NO LOCKS. WATER VALVES AT NW CRNR OF BLDG. GAS ELECT SERVICE IN INTERNAL CABINETS SE Fire Protec./Avail. Water 12/27/2006 PRIVATE FIRE PROTECTION - SPRINKLERS, WET-PIPE SYSTEM, EXCEPT DATA PROCESSING EQUIPMENT RM AND MAIN TELEPHONE RM. THESE ROOMS HAVE A DRY-PIPE PREACTION SYSTEM. MAIN ELECTRICAL EQUIPMENT AND UPS ROOMS HAVE SEPARATE DRY-PIPE SUPPRESSION SYSTEM. PORTABLE FIRE EXTINGUISHERS WALL-MOUNTED IN BLDG OF ABC-TYPE, WITH HALON-TYPE IN SENSITIVE EQUIPMENT AREA. Building Occupancy Level 12/27/2006 1200 EMPLOYEES -10- 02/06/2007 ..- F STATE FARM MUTUAL AUTOMOBILE INS SiteID: 015-021-001765 ~ Fast Format ~ ~ Training Overall Site ~ ~ Employee Training 12/27/2006 ~ MSDS SHEETS ON FILE. BRIEF SUMMARY OF TRAINING PROGRAM: STATE FARM EMPLOYEES WHO WORK WITH OR NEAR THE HAZARDOUS MATERIALS ON SITE PARTICIPATE IN HAZARD & CHEMICAL AWARENESS TRAINING, PERSONAL PROTECTIVE EQUIPMENT TRAINING, AS WELL AS, JOB FUNCTION AND EMERGENCY RESPONSE DUTIES. TRAINING PROGRAMS ARE INITIAL AND HAVE ESTABLISHED REFRESHER FREQUENCIES. ruyv ~ [1c 11A 1VL t'll I~UIC U.y-C 1ZC1U 1V.L I'ILI.UIC USC -11- 02/06/2007 Prevention Services UNIFIED PROGRAM INSPECTION CHECKLIST! a E R s F t o 90oTruxtun Ave., Suite 210 --- ~..______-~~~~_ -- ~ _~_ _ _-_._______ -- _-. _ FIRE Bakersfield, CA 93301 SECTION 1: Business Plan and Inventory Program "'~'"' r Tel.: (661) 326-3979 Fax: (661) 872-2171 FACILITY NAME INSPECTION DATE INSPECTION TIME ADDRESS _ HONE NO. NO OF EMPLOYEES FACILITY CONTACT BUSINESS ID NUMBER 15-021- C71~ 145' Section 1: Business Plan and Inventory Pragram 17` ROUTINE ^ COMBINED ^ JOINT AGENCY ^ MULTI-AGENCY ^ COMPLAINT ^ RE-INSPECTION C V ~ C=Compliance OPERATION V=Violation COMMENTS ^ APPROPRIATE PERMIT ON HAND ^ BUSIIIeSS PLAN CONTACT INFORMATION ACCURATE ^ VISIBLE ADDRESS ^ CORRECT OCCUPANCY ENT'D DEC 2 7 2006 ^ VERIFICATION OF INVENTORY MATERIALS ^ VERIFICATION OF QUANTITIES ^ VERIFICATION OF LOCATION ^ PROPER SEGREGATION OF MATERIAL ^ VERIFICATION OF MSDS AVAILABILITY ^ VERIFICATION OF HAZ MAT TRAINING ^ VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES ^ EMERGENCY PROCEDURES ADEQUATE ^ CONTAINERS PROPERLY LABELED ^ HOUSEKEEPING ^ FIRE PROTECTION ^ SITE DIAGRAM ADEQUATE & ON HAND ANY HAZARDOUS WASTE ON SITE? ^ YES ~^ NO EXPLAIN: p // ,,/ QUESTIONS REGARDIN H INSPECTION? PLEASE CALL US AT (661) 326-3979 ~~ Inspector (Pleas Print) Fire Prevention / 1s` In /Shift of Site/Station # White -Prevention Services Busi Site /Responsible Party (Please Print) Yellow -Station Copy Pink -Business Copy FD 2155 (Rev. 09/05 + STATE FARM MUTUAL AUTOMOBILE INS ____________________ SiteID: 015-021-001765 + Manager Location: 900 OLD RIVER RD City BAKERSFIELD BusPhone: (661) 663-1302 Map 123 CommHaz High Grid: 06B FacUnits: 1 AOV: CommCode: BFD STA 09 EPA Numb: SIC Code:6331 DunnBrad:00-692-8097 Emergency Contact / Title Emergency Contact / Title ROD SKINNER / LOSS PREY SPEC ~~,,,,~ ~ta~~ / SUPERVISOR Business Phone: (661) 66.3-1378x Business Phone: (661) 663-~-3-1Dxl~~ 24-Hour Phone (661) 304-6483x 24-Hour Phone (663) 1-3-0x 3pt~ Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: RSs Fire React ImmHlth DelHlth Contact tv~S Phone : (~~) ~~ - ~ x MailAddr: 1 STATE FARM PLAZA State: IL City BLOOMINGTON Zip 61710-0001 Owner STATE FARM MUTUAL AUTOMOBILE INS Phone: ( ) - x Address 1 STATE FARM PLAZA State: IL City BLOOMINGTON Zip 61710-0001 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: Yes ParcelNo: Emergency Directives: PROG A - HAZMAT PROG T - ABOVEGROUND STORAGE TANK EN~''D ~~~ ~ 7 X006 sed on my inquiry of those individuals r aponsible for obtaining the information, I certify U tder penalty of law that I have personally e carnined and am familiar with the information ~~ it~te ~ ~ ~ ~p eie the information is true, ~---- 3 23 Date -1- 03/14/2006 ~'~ ~ ~ Bakersfield Fire Dept. UNIFIED PROGR/4M INSPECTION CHECKLIST ~ Enironmental services ~. ~.~, ~ ~ L ~ ~.._- k 1715 Chester Ave SECTION 1 Business Plan and Inventory Program Bakersfield, CA 93301 ~ Tel: (661)326-3979 FACILITY NAME / ,-LL ~ INSPECTION DATE INSPECTION TIME Sj/Qi T r ~~/m /??/il ~Gv6O'/ /~ ° Z ~ d ~ ~ i PHONE Noi No. of Employ ADDRESS FACILITYCONTACT '- Business ID Number ,~~ ~/~lZc°4~-- 15-021- ~/7t ~ Section 1: Business Plan and Inventory Program Routine ^ Combined ^ Joint Agency ^Mnlti-Agency ^ Complaint ^ Re-inspection ~C~V (V=VoatioinnCe~ ~P~~q~~®N COMMENTS LT Lt PROPRIATE PERMIT ON HAND ^ BUSINESS PLAN CONTACT INFORMATION ACCURATE VISIBLE ADDRESS C~O CORRECT OCCUPANCY ^ VERIFICATION OF INVENTORY MATERIALS VERIFICATION OF QUANTITIES ^ VERIFICATION OF LOCATION -. ^ PROPER SEGREGATION OF MATERIAL ----- ------ _- ------ ------..._ ___--- ~a~~ -- -„ ^ VERIFICATION OF MSDS AVAILABILITYE ^ VERIFICATION OF FIAT MAT TRAINING ' ^ VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES 1119.` ^ EMERGENCY PROCEDURES ADEQUATE ^ CONTAINERS PROPERLY LABELED ^ HOUSEKEEPING _ --- ^ FIRE PROTECTION ~ i ^ SITE DIAGRAM ADEQUATE Ht ON HAND -- ANY HAZARDODUS WASTE ON~SITE~: ,,.//^ YES NO EXPLAIN: - /~~ 7 / Q ~ /~ ~~ / 8 ~ ,? ~ /` S~G°G~ (/Jti~ r ~ ~CY(r '$~~~ C° QUESTIONS REGARDING THIS INSPECTIONS PLEASE CALL US AT (661 ~ 326-3979 _____ _~_ Ins ecto ~ s rint ~ r~ Fire Pr /~ n 1 s~Shift of Site Hess Site R P ( ~ ~ e ible Party (Please Print) m g N White -Environmental Services Yellow -Station Copy Pink'='Business Copy Bakersfield Fire Dept. UNIFIED PROGRAM INS. ~ECTION CHECKLIST Enironmentai Services 1715 Chester Ave SECTION 1 Business Plan and Inventory Program Bakersfield, CA 93301 ~ ,,y yam- ,<- •- ~,r ,~, Tel: (661)326-3979 FACILITY NAME INSPECT N SATE INSPECTION TI _ ~ _ ______ ' 13 5 ---- ~~~~---_O_~-~ ___ c___~ ~-~ - --------- __-_----- --- ~ - 3//~ -----~ PHON No. No. of Employees ADDRESS / '7 /V'~ _~- ~ ~G' -I~e~ > ~ -LI .~---- ------- -------- - -- --- -' --- -------------- /vl`1J FACILITYCONTACT Business ID juCbe~Di ~~~~~ Section 1: Business Plan and Inventory Program outine ^ Combined ^ Joint Agency ^MulIi-Agency O Complaint ^ Re-inspection C V \V=Vioatonncel OPERATION '~ ^ APPROPRIATE JPERMIT ON HAND -/---- - ---- - d Cd BUSINESS PLAN CONTACT INFORMATION ACCURATE ~^ VISIBLE ADDRESS COMMENTS ~~g,~e.u~ y co~•T•acr--woe.-- o~~oi -~.u- ~r - D / ,y/ ,~/ (J ~_---_ _---- Plj . ~ 6 ~ ~ _ (o (p 3 - (3 /0 ^ CORRECT OCCUPANCY _ -- ---- - - -- ,~Yy~icj~~ ~ ~y~ ~ _ 7 f C{ - !7/ I,3 O ------- -------- -------.....----- S ~ ~ ~~ VERIFICATION OF INVENTORY MATERIALS i e ~ ume A BCD : S -CI~e, r12w S;~P ~t ^ VERIFICATION OF QUANTITIES VERIFICATION OF LOCATION ____ - ~ /- G'O"c~~ 'JoY ~~'v0 /-s5 ©~ 0~1 z ~~ ~J~~-~BLL1.r~.tC:Z~_ Tsr.4r .eeycact-~.. i'~E~'Z R SEGREGATION OF MATERIAL ~ IN r~.C ^ VERIFICATION OF MSDS AVAILABILITYE ^ VERIFICATION OF HAT MAT TRAINING - - ^ VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES ~ ~ - - --- - -- ---_- / G ~ v~t ~ Q ^ EMERGENCY PROCEDURES ADEQUATE f~~/~~ J 6 L .. O ONTAINERS PROPERLY LABELED ^ HOUSEKEEPING FIRE PROTECTION ~^ SITE DIAGRAM ADEQUATE & ON HAND . ANY HAZARDOUS WASTE ON SITE: ^ YES NO EXPLAIN: QUESTIONS REGARDING THI INSPECTION? PLEASE CALL US AT (66')) 3Z6-3979 _ ,~ r'r ~'"-'~-=-s='--`yam - -~-~ ----~ ------- ' -- --- Inspector Badge No. Busl~~ s Slte Responsible Party White -Environmental Services Yellow - Slalion Copy Pink • Bu~tn~ ess Copy /~'! i ti A o= I UNIFIED PROGRAM IN~I~ECTION CHECKLIST, T=~' ~-Ec-i-iO'N"'".ii '~usineSs Plan..~nd 'l'nventorY Pr0gram ~ , FACILITY NAME ADDRESS Bakersfield Fire Dept. Enironmental Services FACILITYCONTACT 1715 Chester Ave Bakersfield~- CA. 9330 l Tel: (661)326-3979 "'. :~/-~ '~':" ~' -",.. :":i',~i':~. .. ~ Secti°nl~'BUsiness Plan and In~/entory Program ~oUtine i-I Combined i-I Joint Agency f'! Multi-Agency ~ Complaint Re-inspection (' C=Compliance '~ OPERATION \ v=violation ,/ APPROPRIATE PERMIT ON HAND ~- I~ BUSINESS PLAN CONTACT INFORMATION ACCURATE [~ VISIBLE ADDRESS COMMENTS _ ~ ~ ~_~_ ~_!. ~ ~ $_ .~ J_ ~ L° ........................................ ..................................................................................... _'~_~ PROPER SEGREGATION OF MATERIAL VERIFICATION OF MSDS AVAILABILITYE -~' [~ VERIFICATION OF HAT MAT TRAINING VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES EMERGENCY PROCEDURES ADEQUATE CONTAINERS PROPERLY LABELED HOUSEKEEPING FIRE PROTECTION SITE DIAGRAM ADEQUATE & ON HAND ANY HAZARDOUS WASTE ON SITE?: EXPLAIN: YES QUESTIONS REGARDING THI~ INSPECTION? PLEASE CALL US AT (661) 326-3979 Inspector Badge No. White . Environmental Services Yellow - Station Copy ./ Z B~~ible Party / Pink - BTiness Copy FACILITY NAME ,,~'T~-re' /~',~,¢~ //,dS'. ADDRESS qOO ~9~_a ~,,,,c-~__ FACILITY CONTACT ',~o ~ ~J INSPECTION TIME_ ..3~'~ ~; ,c/. CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., yd Floor, Bakersfield, CA 93301 INSPECTION DATE PHONE NO. (0(,:,,3 -' ! o o o BUSINESS ID NO. O 15-2-10,-ooo NLIMBER OF EMPLOYEES_d..=~_~2.~ Section 1: Business Plan and Inventory Program [~'/Routine [~ Combined [~ Joint Agency [~ Multi-Agency ['] Complaint {~ Re-inspection OPERATION C VI COMMENTS Appr. opriate permit on hand Business plan contact information accurate C__ Visible address Correct occupancy C._ Verification of inventory materials Verification of quantities Verification of location ~_ ~ ,t ~..~ Proper segregation of material Verification of MSDS availability ~- Verification of Haz Mat training Verification of abatement supplies and procedures ~-- Emergency procedures adequate so Containers properly labeled C. Housekeeping Fire Protection C_ site Diagram Adequate & On Hand C . C=Compliance V=Violation Any hazardous waste on site?: Explain: Yes ~No" Questions regarding this insi~ction? Please call us at (661) 326-3979 White - Env. Svcs. Yellow - Station Copy Pink- Business Copy ~n~s(n~'s~'Site ~e~'pohsibie Party I nspe~tor:L~----~/...~ ,,~9'~~ STATE FARM MUTUAL AUTOMOBILE Manager : Location: 900 OLD RIVER RD City : Bg_KERSFIELD CommCode: BAKERSFIELD STATION 11 EPA Numb: ~' ~';''~''~'~II~D / SiteID: 215-000-001765 JAN 4ZOO0 ~;Pho~;; (805) 663-1302 i CommHaz : Moderate IBY: ' prid 06B FacUnits: '1 AOV: SIC Code:6331 DunnBrad:00-692-8097 Emergency Contac~ / Title B~I-~--W~O~H;~ LOSS PREVENTION Business Phone: 24-Hour Phone : (~7-~-5790x Pager Phone : ( ) Emergency Co~ta~t - / . Title B%q~N--~gNA~D~ ~*~.I~INTENANCE SUP Business Phone: (~) 663-1~6x~9~ 24-Hour Phone : (~) 635~6~-1-9x Pager Phone : (&A~i - ~X)~3~ Hazmat Hazards: RSs Fire React ImmHlth DelHlth Contact : MailAddr: 1 STATE FARM PLAZA City : BLOOMINGTON Phone: ( ) - State: IL Zip : 61710-0001 X Owner STATE FARM MUTUAL AUTOMOBILE INS Address : 1 STATE FARM PLAZA City : BLOOMINGTON Phone: ( ) - State: IL Zip : 61710-0001 X Period : to TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: Yes Emergency Directives: = Hazmat Inventory --MCP+DailyMax Order Hazmat Common Name... LEAD CALCIUM BATTERY BETZ ENTEC OPTI GUARD MCi BETZ ENTEC 368 BETZ ENTEC 559 DIESEL FUEL #2 ISpecHazI R IH S IH L F IH L F IH G r®vi~w~d ~,he a~a0h®d h~ardous mm®dais rnanag~o One Unified List Ail Materials at Site EPA HazardsI Frm ' DailyMaX Unit MCP 192.00 GAL Hi 120.00 GAL Hi 80.00 GAL Hi 200.00 GAL Mod 2000.00 GAL Low 12/20/1999 mere plan ;or 3~;~7~.~ ,t~'>,. ;..nd ~ha~ i~ alor~ ~Rh :~ ' '{l~:~'t~ ef'[l~uoin:~, ~ ' any correcfion~ c~Ru~® ~ comple~® ~nd co;r~c~ man- STATE FARM MUTUAL AUTOMOBILE INS SiteID: 215-000-001765 Inventory Item 0004 Facility Unit: Fixed Containers at Site ~UlV~Vl~ ~Vl~ ! ~± ~_/--~J~ ~Vl~ LEAD CALCIUM BATTERY Days On Site 365 Location within this Facility Unit Map: Grid: UNINTERRUPTED POWER SUPPLY RM, SE CORNER OF BLDG CAS# FSTATE ~ TYPE Solid /Mixture PRESSURE Ambient TEMPERATURE Ambient CONTAINER TYPE OTHER - SPECIFY Largest Containerl.00 GAL AMOUNTS AT THIS LOCATION Daily Maximum 192.00 GAL Daily Average 192.00 GAL %Wt. RS CAS# Lead No 7439921 Sulfuric Acid (EPA) No 7664939 Tin No 7440315 HAZARD ASSESSMENTS Radioactive/Amount EPA Hazards No/ Curies R IH NFPA /// USDOT# MCP Hi Inventory Item 0001 Facility Unit: Fixed Containers at Site ~LV~Vl~ ~vl~ / ~£ ~,/'-LI,.J ~Vl~ BETZ ENTEC OPTI GUARD MC1 Days On Site 365 Location within this Facility Unit Map: Grid: BOILER RM, SE CORNER OF BLDG CAS# F STATE TYPE PRESSURE Liquid Mixture Ambient TEMPERATURE Ambient CONTAINER TYPE PLASTIC CONTAINER Largest Container 120.00 GAL AMOUNTS AT THIS LOCATION Daily Maximum 120.00 GAL Daily Average 120.00 GAL %wt. RS CAS# Sulfurous Acid No 7782992 Diethylaminoethanol No 100378 IMorpholine No 110918 TSecretI ~S BioHaz No N No HAZARD ASSESSMENTS IRadioactive/Amount I EPA Hazards No/ Curies IH NFPA /// USDOT# MCP Hi 2 12/20/1999 STATE FARM MUTUAL AUTOMOBILE INS ~EE~E~E~¢~E~ SitelD: 215-000-001765 i i~ Inventory Item 0003 ~~~ Facility Unit: Fixed Containers at Site i i~ COMMON NAME / CHEMICAL NAME BETZ ENTEC 368 ° Days On Site ° o 365 o Location within this Facility Unit Map: Grid: CHILLER RM, SE CORNER OF BLDG ° CAS# ° O O i~ STATE ~i~ TYPE ~i~ PRESSURE ~i TEMPERATURE ~i~ CONTAINER TYPE Liquid o Mixture o Ambient o Ambient o PLASTIC CONTAINER ° i~~~~i AMOUNTS AT THIS LOCATION Largest Container ° Daily Maximum ° Daily Average ° 80.00 GAL ° 80.00 GAL ° 80.00 GAL o i~i~~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS# o °Magnesium Nitrate °No o 10377603 o o 5_Chloro_2_methyl_4_isothioazoline °No o 0o i~i~i~g~i~8~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount ° EPA Hazards o NFPA o USDOT# ° MCP o No ONoONo o No/ Curies°F IH o /// o OHio i~.Inventory Item 0002 EEEEEEE~EE~EEE~ Facility Unit: Fixed Containers at Site i i~ COMMON NAME / CHEMICAL NAME ~~~~~i~~~i BETZ ENTEC 559 o Days On Site ° o 365 o Location within this Facility Unit Map: Grid: COOLING TOWERS, E SIDE OF BLDG ° CAS# ° o o STATE ~i~ TYPE ~i~ PRESSURE ~i TEMPERATURE ~i~ CONTAINER TYPE Gas o Mixture o Ambient o Ambient o PLASTIC CONTAINER o i~~~~i AMOUNTS AT THIS LOCATION Largest Container o Daily Maximum o Daily Average o 200.00 GAL ° .200.00 GAL o 200.00 GAL ° i~6~i~~ HAZARDOUS COMPONENTS %Wt. o o RSo CAS# o °Phosphonic Acid ONo o 13598362° °l-H-Benzotriazole, Methyl ONo o 136856o °Sodium Hydroxide ONo o 1310732° i~8~i~i~i~~ HAZARD ASSESSMENTS °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o No ONoONo ° No/ Curies°F IH o /// o OModO 12/20/1999 STATE FARM MUTUAL AUTOMOBILE INS ~~~ SitelD: 215-000-001765 i~ Inventory Item 0005 ~~~ Facility Unit: Fixed Containers at Site i i~ COMMON NAME / CHEMICAL NAME ~~~~~i~~~i DIESEL FUEL #2 o Days On Site o o 365 Location within this Facility Unit Map: Grid: OUTSIDE OF BLDG, SE CORNER BY GENERATOR RM o CAS# o o 68476_34_6° i~ STATE ~i~ TYPE ~i~ PRESSURE ~i TEMPERATURE ~ CONTAINER TYPE Liquid o Pure o Ambient ,o Ambient o ABOVE GROUND TANK o Largest Container o Daily Maximum o Daily Average o 2000.00 GAL o 2000.00 GAL o 2000.00 GAL o ~~~~ HAZARDOUS COMPONENTS %Wt. o °RS° CAS# o 100.00ODiesel Fuel No. 2 ONo o 68476302° i~i~i~i~~ HAZARD ASSESSMENTS ~i~~i~~i~i °TSecret° RS°BioHaz° Radioactive/Amount o EPA Hazards o NFPA o USDOT# o MCP o No ONoONo. o No/ Curies°F RIHDH° /// o OLowO -4- 12/20/1999 STATE FARM MUTUAL AUTOMOBILE INS ~/Si~~i~i~ SitelD: 215-000-001765 i~ Notif./Evacuation/Medical ~~~~~~ Overall Site i i~ Agency Notification ~~~~~~~ 10/20/1997 i o ~BAKERSF~FI n, ~n~ DEpT - AI~A8M AND/O~ ~9.4-6551 .... ~J~RM CENT~L MONITOmNG SERVICE- ALAN AND/OR (309) 766-~950 ~J~EPXNE, ADMINIST~TIVE SERVICE MGR-663-1300W~~R o ~j~UCLXS, ASSITANT MANAGER-FACILITIES-663-1317W~635-6648PGR ~, ~GIONAL OFFICE MAINTENANCE SUPER-~~~PGR ~, LOSS P~VENTION SPECIALIST - ~W~~PGR i~ Employee Notif./Evac~tion ~~~g~~~ 10/20/1997 i O INTE~AL AUDIBLE AND VISUAL STROBE.ALA~S ARE THROUGHOUT THE BLDG TO NOTIFY o EMPLOYEES TO EVACUATE. EACH DEPT WITHIN THE BLDG HAS ESTABLISEHD EXITS AND o GATHE~NG PLACES OUTSIDE FOR ACCOUNTING OF EMPLOYEES. THE ADMINIST~TIVE o SERVICES DEPARTMENT HAS ~SPONSIBILITY FOR EVACUATION AND THE MONITO~NG OF o E~TS AND ALARMS. o o i~6~ ~blic Notif./Evacuation ~~6~~~~6 10/20/1997 i O THERE ARE NO ~OWN HAZA~OUS MATE~ALS ON SITE THAT WOULD CAUSE AN EMERGENCY NECESSITATING PUBLIC EVACUATION. o o i~ Emergency Medical Plan 6~~~~~6~ 10/20/1997 i o THE OFFICE ~S TWO FULLTIME AND ONE PARTTIME NURSE ON SITE TO HANDLE FIRST o AID. EMERGENCY SERVICES'THAT A~ SUMMONED AR DIRECTED TO THE APPROP~ATE o LOCATION BY T~NS WEST SECU~TY, OUR 24 HOUR GUARD SERVICE CONT~CTOR. THE o ADMINIST~TIVE SERVICE DEPARTMENT ALSO AIDS THE MEDICAL STAFF AND EMERGENCY o PERSONNEL BY CONDUCTING EMERGENCY OPE~TIONS THROUGHOUT THE BLDG. o o -5- 12/20/1999 Wayne Lepi, ne James Banks, Jucli Bassigi~ni John Hinkle Administrative Services Manager Ad. Servi~:esAssistam Manager Ad. Services Maintenance Supervisor Loss Prevention Specialist (661) 663-1300 WK (661) 663-1336 WK (661) 663-1941 WK (661) 663-1951 WK (661) 636-5252~PGR (661) 636-5233 PGR (661) 635-6078 PGR (661) 336-7502 PGR i STATE FARM MUTUAL AUTOMOBILE INS ~6~6~~ SiteID: 215-000-001765 i i~ Mitigation/Prevent/Abatemt ~~~~~ Overall Site i~ Release Prevention ~~~~~~~ 10/20/1997 O O ° 1) BACKUP GENERATOR DIESEL STORAGE TANK - OUR ABOVE GROUND 2,000 GALLON o ° DIESEL TANK HAS A PROTECTIVE 6 INCH THICK, 400 PSI, CONCRETE ENCLOSURE. THIS o ° TANK IS INTERNALLY SEALED WITH A LINER RESISTANT TO METHANOL BASED DUELS AND o ° HAS A 3 GALLON OVERFLOW TRAP FOR PROTECTION DURING FILLING. ° ° 2) BOILERS/CHILLERS/COOLING TOWERS - CHEMICALS FOR THESE ARE STORED IN' ° o NON-CORROSIVE PLASTIC CONTAINERS (SERVICE HOPPERS). ° 3) GEL BATTERIES - THE GEL.ELECTROLYTE OF THE u INTERRUPTED POWER SUPPLY" ° (UPS) BATTERY BANK IS IN 192 INDIVIDUALLY SEALED CELLS LINKED TOGETHER. THE ° ° MSDS STATES NO RELEASES OR EMMISSIONS UNDER NORMAL OPERATIONS. ° O o i~ Release Containment ~~~~~~ 10/20/1997 i O O ° 1) THE DIESEL STORAGE TANK HAS A BELOW GROUND SPILL/LEAK SUMP PIT TO CONTAIN ° ° A ACCIDENTAL RELEASE. o o 2) THE PLASTIC TANKS THAT CONTAIN THE BOILER, CHILLER, AND COOLING TOWER ° ° CHEMICALS ARE PROTECTED BY CEMENT BERMS SURROUNDING THE TANKS. THESE o ° CHEMICALS ARE PUMPED DIRECTLY INTO THE PLASTIC SERVICE TANKS FROM THE o ° VENDORS TRUCK. THERE IS NO EMPLOYEE CONTACT WITH THE CHEMICALS AND NO o ° SURPLUS STORAGE OUTSIDE OF THE SERVICE TANKS. ° o 3) THERE IS NO CONTAINMET BERM AROUND THE UPS BATTERY BANK AS THE GEL ° o ELECTROLYTE DOES NOT REQUIRE ONE. THERE IS A SPILL KIT LOCATED NEAR THE UPS ° ° BATTERIES AND THE SERVICE TANKS OF THE BOILER, CHILLER, AND COOLING TOWER ° o CHEMICALs. o i~ Clean Up ~~~~~~~~ 10/20/1997 i ° SPILL KITS ARE LOCATED IN APPROPRIATE AREAS TO HANDLE SMALL SPILLS. THESE' ° ° KITS INCLUDE, BUT ARE NOT LIMITED TO, ABSORBENT PILLOWS AND GRANULAR ° ° ABSORBENTS. IF A LARGE SPILL WERE TO OCCUR, THE FIRE DEPT WILL BE NOTIFIED. ° i~ Other Resource Activation O o -6- t2/20/1999 i STATE FARM MUTUAL AUTOMOBILE INS ~/~/~/~/~/~/~/~ SiteID: 215-000-001765 i~ Site Emergency Factors ~~~~~~ Overall Site i i~ Special Hazards o o o o i~ Utility Shut-Offs ~~~~~~~ 10/20/1997 O O ° A) GAS - SW CORNER OF BLDG ° ° B) ELECTRICAL - SE CORNER OF BLDG o ° C) WATER - NW CORNER OF BLDG ° ° D) SPECIAL - SW CORNER OF BLDG ° o E) LOCK BOX -THERE ARE CHAINS AND PADLOCKS ON WATER VALVES AT THE NW CORNER o OF BLDG. GAS SERVICE HAS LARGE SQUARE NUT, COMMON. ELECTRICAL SERVICE IS ° ° IN INTERNAL CABINETS, SE CORNER OF BLDG, WITH NO LOCKS. ° O o iO~ Fire Protec./Avail. Water ~~~6~~ 10/20/1997 O o o PRIVATE FIRE PROTECTION - FULL BLDG SPRINKLER, WET PIPE SYSTEM, EXCEPT DATA ° ° PROCESSING EQUIPMENT RM AND MAIN TELEPHONE RM. THESE ROOMS HAVE A DRY PIPE o PREACTION SYSTEM. THE MAIN ELECTRICAL EQUIPMENT AND UPS ROOMS HAVE A ° ° SEPARATE DRY PIPE SUPPRESSION SYSTEM. PORTABLE FIRE EXTINGUISHERS ARE WALL ° ° MOUNTED THROUGHOUT THE BLDG OF ABC TYPE WITH HALON TYPE IN SENSITIVE ° ° EQUIPMENT AREA. o o o O o o o o o i~ Building Occupancy Level O o o o 12/20/1999 STATE FARM MUTUAL AUTOMOBILE INS i~ Training ~~~~~~~~ Overall Site i~ Employee Trai~ng ~~~~~~~ 10/20/1997 ~ o WE HAV~ EMPLOYEES AT THIS FACILITY. WE DO HAVE MSDS SHEETS ON FILE. B~EF SUMMARY OF T~INING PROG~M: NEAR THE ~ZARDOUS MATE~ALS ON SITE PARTICIPATE IN HAZA~ & CHEMICAL o AWA~NESS T~INING, PERSONAL PROTECTIVE EQUIPMENT T~INING, AS WELL AS, JOB FUNCTION AND EMERGENCY RESPONSE DUTIES. T~INING PROG~MS A~ INITIAL AND ~VE ESTABLISHED REFRESHER FREQUENCIES. o o O i~ Held for Future Use O O i~ Held for Fumre Use o o 0 o STATE FARM EMPLOYEES WHO WORK WITH OR o o State Farm Insurance Companies December 28, 1999 Greater California Office 900 Old River Road Bakersfield, California 93311-6000 City of Bakersfield Fire Department, Office of Environmental Services 1715 Chester Ave. Bakersfield, CA 93301 Attn: Ralph E. Huey Director, Office of Environmental Services Please find enclosed the revisions to State Farm Insurance's Greater California Regional Office Hazardous Materials Business Plan. If questions adse, please contact me at (661) 663-1951. Cc: Wayne Lepine, Administrative Services Manager James Banks, Administrative Services Assistant Manager File HOME OFFICES: BLOOMINGTON, ILLINOIS 61710-0001 HAZARDOUS MATERIALS MANAGEMENT PLAN State Farm Mutual Automobile Insurance Company 900 Old River Road Bakersfield, CA 93311-6000 June, 1997 TABLE OF CONTENTS SECTION 1: BUSINESS INDENTIHCATION DATA ........................................................ 2 SECTION 2: EMERGENCY NOTIFICATION .................................................................... 2 SECTION 3: TRAINING ..................................................................................................... 2 SECTION 4: EXEMPTION REQUEST ...............................................................................3 SECTION 5: CERTIFICATION .......................................................................................... 3 SECTION 6: NOTIFICATION AND EVACUATION PROCEDURES ............................... 3 SECTION 7: MITIGATION, PREVENTION AND ABATEMENT PLAN ......................... 4 SECTION 8: UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT FACILITY) ........ 5 SECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABILITY .......................... 5 APPENDIX A: MATERIAL SAFETY DATA SHEETS ..................................................... 6 APPENDIX B: MAP OF PROPERTY AT 900 OLD RIVER RD, BAKERSFIELD, CA ....... FOLDER APPENDIX C: DETAIL MAP OF HAZARDOUS MATERIAL LOCATIONS .................... FOLDER June, 1997 SECTION !: BUSINESS IDENTIFICATION DATA BUSINESS NAME: State Farm Mutual Automobile Insurance Company LOCATION: 900 Old River Road, Bakersfield, CA 93311-6000 MAILING ADDRESS: Same CITY: Bakersfield STATE: California ZIP: 93311-6000 DUN & BRADSTREET NUMBER: 00-692-8097 PRIMARY ACTIVITY: Insurance OWNER: State Farm Mutual Automobile Insurance Company MAILING ADDRESS: PHONE: (805) 663-1302 SIC CODE: 6331 1 State Farm Plaza, Bloomington, Illinois 61710-0001 SECTION 2: EMERGENCY NOTIFICATION CONTACT 1. Brian Wargo 2. Byron Aoma 3. John Douglas 4. Wayne Lepine TITLE Loss Prevention Specialist Maintenance Sut~amor Assistant Manager-Facilities Administrative Services 1Vlgr. BUS. PHONE (805) 663-1302 (805) 663-1306 (805) 663-1317 (805) 663-1300 24 HR. PHONE (805) 638-5790 (805) 635-6819 (805) 635-6648 (805) 6384242 SECTION 3: TRAINING NUMBER OF EMPLOYEES: 9 MATERIAL SAFETY DATA SHEETS ON FILE: Yes and attached BRIEF SUMMARY OF TRAINING PROGRAM: State Farm employees who work with or near the hazardous materials on site participate m hazard & chemical awareness training, personal protective equipment training, as well as, job function and emergency response duties. Training program~ are initial and have established refresher frequencies. June, 1997 S~cTIo~ 4: ~xzMPTiO~ REOUrST I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAFFER 6.95 OF THE "CALIFORNIA HEALTH & SAFETY CODE" FOR THE FOLLOWING REASONS: N/A WE DO NOT HANDLE HAZARDOUS MATERIALS. N/A WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIME EXCEED THE MINIMUM REPORTING QUANTITIES. N/A OTHER (SPECIFY REASON) SECTION 5: CERTIFICATION I, Brian D. Wargo CERTIFY THAT THE ABOVE INFORMATION IS ACCURATE. I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH & SAFETY CODE" ON HAZARDOUS MATERIALS (DIV. 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT INACCURATE INFORMATION CONSTITUTES PERJURY. SIGNATURE~ Loss Prevention Sl~'ialist June 26, .1997 TITLE DATE SECTION 6~ NOTIFICATION AND EVACUATION PROCEDURES A. AGENCY NOTIFICATION PROCED~S: AGENCY/PERSON City of Bakersfield, CA Fire Department State Farm Central Monitoring Service, Corporate Wayne Lepine, Admimstrative Services Manager John Douglas, Assistant Manager-Facilities Byron Acuna, Regional Office Maintenance Supervisor Brian Wargo, Loss Prevention Specialist METHOD Alarm and/or (805)324-6551 Alarm and/or (309)766-0950 (805)663-1300wk/(805)638-4242pgr (805)663-1317wk/(805)635-6648pgr (805)663-1306wk/(805)635-6819pgr (805)663-1302wk/(805)638.5790pgr B. EMPLOYEE NOTIFICATION AND EVACUATION: Internal audible and visual strobe alarms are throughout the building to notify employees to evacuate. Each depamnent within the building has established exits and gathering places outside for a~counting of employees. The Admim'strative Services delmmncnt has reslxmsibility for evacuation and the momtormg of exits and alarms. June, 1997 C. PUBLIC EVACUATION: There are no known hazardous materials on site that would cause an emergency necessitating public evacuation. D. EMERGENCY MEDICAL PLAN: The office has two full-time and one part-time nurse on site to handle first aid. Emergency services that are summoned are directed to the appropriate location by Trans West Security, our 24 hour guard service contractor. The Admimstrative Service department also aids the medical staff and emergency personnel by conducting emergency operations throughout the building. SECTION 7: MITIGATION~ PREVENTION AND ABATEMENT PLAN A. RELEASE PREVENTION STEPS: Back-up Generator Diesel Storage Tank - our above ground 2,000 gallon diesel tank has a protective 6 inch thick, 400 psi, concrete enclosure. This tank is internally sealed with a liner resistant to methanol based fuels and has a 3 gallon overflow trap for protection during filling. 2. Boilers/Chillers/Cooling Towers - chemicals for these are stored in non-corrosive plastic containers (service hoppers). 3. Gel Batteries - the gel electrolyte of the "Uninte~ Power Supply" (IJPS) battery bank is in 192 indivi&~o!ly sealed cells liniced together. The MSDS states no releases or emissions under normal operation. RELEASE CONTAINMENT AND/OR MINIMIZATION: 1. The diesel storage tank has a below ground spill/leak sump pit to contain a accidental release. The plastic tanks that contain the boiler, chiller, and cooling tower chemicals are protected by eemem brumes surrounding the tanks. These chemicals are pumr~l directly into the plastic service tanks from the vendor's truck There is no employee contact with the chemicals and no surplus storage outside of the service tanks. There is no containment berm around the UPS battery bank as the gel electrolyte does not require one. There is a spill kit located near the UPS batteries and the service tanks of the boiler, chiller, and cooling tower chemicals. C. CLEAN-UP PROCEDURES: Spill kits are located in appropriate areas to handle small spills. These kits include, but are not limited to, absorbem pillows and granular abso~nts, ff a large spill were to occur, the fire depamnent will be notified. June, 1997 SECTION ii: UTILITY SHUT-OFFS {LOCATION OF SHUT-OFFS AT FACILITY} NATURAL GAS/PROPANE: See map location #7, Southeast comer of buildingo color coded orange ELECTRICAL: See map location #8, Southeast comer of building, color coded yellow WATER: Potable Water Service - See map locations #1 & #2, Northwest comer of building, colored blue Fire Protection Water - See map location #3 & ~4, Northwest and Southeast comers of building Non-Potable Imgation Water - See map location #5, Southeast comer of parking lot SPECIAL: Telephone - See map location ~6, Southwest comer of building, color coded yellow LOCK BOX: There are chains and padlocks on water valves at the Northwest comer of building. Gas ' service has large square nut, common. Electrical service is in internal cabinets, Southeast comer of building, with no locks. SECTION 9: PRIVATE FIRE PROTECTION/WATER AVA[LABILITY Bo PRIVATE FIRE PROTECTION: Full building sprinkler, wet pipe system, except data processing equipment room and main telephone room; These rooms have a dry pipe pre- action system The main electrical equipment and UPS rooms have a separate d~ pipe suppression system. Pollable fire extinguishers are wall mounted throughout the bUilding of ABC type with Halon type in sensitive equipment areas. WATER AVAILABILITY (FIRE HYDe: See the circle locations on the map desi~oted by the nationally observed color code of blue. June, 1997 HAZARDOUS MATERIALS INVENTORY FACILITY DESCRIPFION CHECK IF BUSINESS IS A FARM BUSINESS NAME FACILITY NAME SITE ADDRESS CITY BAKERSFIELD NATURE OF BUSINESS SIC CODE 6331 STATE FARM MUTUAL AUTOMOBILE INSURANCE COMPANY STATE FARM GREATER CALIFORNIA REGIONAL OFFICE 900 OLD RIVER ROAD STATE CALIFORNIA ZIP 93311-6000 INSURANCE DUN & BRADSTREET NUMBER 00-692-8097 OWNER/OPERATOR STATE FARM MUTUAL AUTOMOBILE INSURANCE COMPANY MAILING ADDRESS 1 STATE FARM PLAZA CITY BLOOMINGTON STATE ILLINOIS ZIP 617100001 NAME BUSINESS PHONE NAME BUSINESS PHONE EMERGENCY CONTACTS (805) 663-1302 BYRON ACUNA (80~) 663-1306 TITLE LOSS PREVENTION SPECIALIST 24 HOUR PHONE (805) 638-5790 TITLE MAINTENANCE SUPERVISOR 24 HOUR PHONE (805) 6356819 June, 1997 6 Business Name ~ARDOUS MATERIALS INVEN~RY ~ ~,_r'm. ~r~ccr'c~rtCe Address~/OO Oid ~;u,_~.r- CI~MICAL DESCRIPTION 1) INVENTORY STATUS: New ~ddition [ ] Revision [ ] Deletion [ ] Check if chemical is a NON Trade Secret ~rade Secr~ [ 2)Commen ame: Ee'+z Ch,-mi~ame: 5~- =~9 Am,~{~ CAS# 4) Physical & Health PHYSICAL HEALTH Hazard Categories Fire [ I ] Reactive [ O ] SUdden Release of Pressure [ ] Immediate Health (Acute) [~ ] Delayed Heal~ (Chronic) [ 5) WASTE CLASSIFICATION /4//4 (3-digit code from DHS Form 8022) USE CODE C) [ 6) PHYSICAL STATE Solid [ ] Liquid [,~ G-as [ ] Pure [ ] Mixture [~]~ Waste [ ] RafliOa~ve [ ] 7) AMOUNT AND TIME AT FACILITY Maximum Daily Amount Average Dally Amount Annual Amount Largest Size Container I~o_0~a~lc'~3' # Days on Site ~..%- UNITS OF MEASURE Lbs[ Curies [ ] Ckcle W'hich Months: 9) MIXTURE: List ~ COMPQNENT . . CAS# % WT )L~A~ON .~ ~ ~ORY STA~S: New ~Addition [ ] Re,sion [ ~ ~!e~on [ ] Ch~k ~ch~ is a NON T~ S~ [ ] T~ S~ [ 2', Common Name: ~Py.~ ~'~C.. ~.%'Sc:~ 3) DOT # (optional) 60 Chermcal Name: S~c-'~'-- ~ (~ ' ?&IM [ ~ CAS # 4) Physical & Health PHYSICAL HEALTH Hazard Categones Fire [ I ] Reacuve [O ] Sudden Release of ~essure [. ~ Immediate Health (Acute) [~2] Delayed Health (Chronic) [ 5) WASTE CLASSIFICATION ~OO.2. (3-digit code from DHS Form 8022) USE CODE 6) PHYSICAL STATE Solid[/ Liquid[ ] Gas[ ~ Pure[ ] Mixture[~ Waste[ ] Radioactive[ ] AaMOUN-I' A.\'D TLME AT FACILITY Maxamum Daily Amount Average Dailv Amount Annual Amount Largest Size Container ~ # Days on Site ~3/.~ 9) MIXTURE: List the three most hazardous chermcal components or any AHM components Curies [ ] Circie \%'tach Months: · COMPONENT,, . .. , CAS# 3) ..~vdt-~.tn,~ tbt,,,dr"o,~: [dd * i 3 i o -73 / [ ] [ ] { I lO)LOCATION '- , Cool,,q., ovoe-c ) rAe cC. I c~i~ ~ ~ of law. ~t [ Mve ~mlly exm~ ~a ~ f~lig ~ ae ~bmfion on ~ ~ ~ ~ ~~ I ~lieve ~e su~u~ ~omUon is ~, a~ate ~d complete. P~ N~e ~ Yifle of~o~ Comply Repre~mUve g '" Si~ CgF.~CAL DES~ON 1 ) INVENTORY STATUS: New lYe"Addition [ ] Revision [ 2 Co o ame: Ee-tz. -n eC- Ch ,l me: -SC:ca- ]D~l~dou[ ] Check if chemical is a NON Trad~ S~c~ [ ]TradeS~[ ] 4) Physical & Health PHYSICAL HEALTH IaaTurd Categories Fire [ ~ ] Reactive [0 ] Sudd~ Release of Pressure [ ] Immediate Health (Acute) [~] Delayed Health (Chnmic) [ 5) WASTE CLA~SWICATION /I'//~ (3-digit coc~ from DHS Form 8022) . USE CODE OS/20 6) PHYSICAL STATE Solid [ ] Liquid [~ Gas [ ] Pure [ ] Mixture [~ Wasm [ ] Radioa~ive [ ] 7) AMOUNT AND TIME AT FACII2TY Maximum Daily Amount Average Daily Amount Annual Amount Larges~ Size Contain= # Days on Site u rrrs oF trRS Lbs[ ] Ctal [~ ft3 [ cuti~s [ ] Ci~le Which Months: 8) STORAGE CODES., ~O! .a) Container:. FlHtc b) Pressure: t~mbie,,r't c) Temperature A,',,b¢ 9) MIXTURE: List the three most hazardous chemical components or any AHM components COMPONENT CAS# 3) " %WT [ l [ ] [ ] ] Check if chemical is a NON Trad~ Secret [ 3) DOT # (optional) <-nv~ [ ~f cas# ] Trad~ Sem~ [ ] 4) Physical & Health PHYSICAL HEALTH Hazard Categones Fire [O] Reacuve [ / ] Sudden Release of Pressure [ ] Immediau~ Health (Acute) [~] I~lay~ Health (Chronic) [ 5) WASTE CLASSntICATION'bOO~, ~00 ~) (3-digit code from DHS Form 8022) USE CODE J=//7 6) PHYSICAL STATE Solid[ ] Liquid[ ] Gas[ ] m=e [ ] MLx-ture [ ] Waste [ ] Radioa~ive [ ] 73 AMOb2NT A_'CD TLME AT FACILITY Ma.X~num Daiiv ~o=t /~ Av~age Daily ~o~t / ~ .~ ~o~t / 0 ~ L~gest She Con~ / ~e~ ~ Days on Site ~ L~'ITS OF MEASURE ~s[ !oai[ ]~[ Curies[ ] Circle ~,Vaich Months: 9) MIXTURE: List the three most b~ardous chenUcal components or any AHM components g) STORAGE CODES . b) Pressure: c) Temperature , J, F, M, A, M, J, J, A, S, O, N, D CAS# % WT AHM - 92- / 6,7- 7l '70 [ ] 766~q-~-~ 6-7 10)LOCATION . · ' ~ ' I certify under penalty, of law, tlmt I l~ave personally examined and am t~m{liar~vith the mformatmn on this and all attalr, tmd doo~rm'n~a. I believe the submitted information is true, accmte and complete, PRINT Name & Title 6f~uthonzed Company RepresenmUve ~ARDOUS MA~~S INVEN~RY CHEMICAL DESCRIPTION INVENTORY STATUS: New [t~ldition [ ] Revision [ Commo. ame: i i ] l~letion [ ] Check ffchemical is a NON Trade Se~a~ [ ] Trade ~ [ ] 3)DOT#(optienal) 3, /[/.4 IgG/3, ~-- 'i'{/&~cat~X aim[ ] ca# 67~qT~-3q-g' 4) Physical & Health Hazard Categories ] 5) WASTE CLASSIFICATION .~//A O-digit cod~ from DHS Form 8022) 6) PHYSICAL STATE Solid [ I Liquid [,~" Gas [ ] Pure [,~ PHYSICAL Fire [,2. ] Reactive [ O ] Sudden Release of Pressure [ UNITS OF MEASURE Lbs[ ] C_~ [~lT3 [ curia [ ] Circle Wb_ich Months: Immediat~ Health (Acute) [~] De2ay~d Health (Chronic) [ USE CODE Ic~ 7) AMOUNT AND TIME AT FACILITY Maximum Daily Amount Average Daily,~anount .:2_0 Annual Amount ~_O Largest Size Container ~C, CO # Days on Site Mixture [ ] Waste [ ] Radioactive [ ] 8) STORAGE CODES a) Conta/ner: b) Pressm~: All Year, J, F, M, A, M, J, J, A, S, O, N, D %wr AH/vi /oo "7o [ ] [ ] [ ] CoMpONENT CAS# 9) M/XTLrRE: List the three most hazardous chemical compenents or 2) fi'/M~.r-ct I ally AHM componc~nts 3) l ) 2¢VENTORY STATUS: Nexv [ ] Addition [ ] Revision [ ] 2eletion [ ] Check if chemical is a NON Trade Secret [ ] Trade Secret [ ] 2'~ Common Name: 3) DOT # (optional) Chemical Name: AHM [ ] CAS # 4) Physical & Health PHYSICAL HEALTH HazardCategones Fire[ ]Reactive[ ] Sudden Release of PresSUre [ ] Immediate Health (Acute) [ ] Delayed Health (Chronic) [ ] 5) WASTE CLASSIFICATION (3-digit code from DHS Form 8022) USE CODE 6) PHYSICAL STATE Solid[ ] Liquid[ ] Gas[ : Pure [ ] ~.xture [ ] wa.sm [ ] Radioactive [ ] .4.MOUNq' .4.N'D TLME AT FACILITY Maxunum Daily Amount Average Daily Amount Annual Amount Largest Size Container # Days on Site L.'NTT. S ©F ME4SUXE 8) STORAGE CODES Lbs( 'Gall iR3[ ] a) Conrainer: Curies [ ] b) Pressure: c) Temperature Circle ~%.ich Months: All Year, J, F, M, A, M, J, J, A, S, O, N, D 9) MIXTURE: List COMPONENT CAS# % WT AHld the three most hazardous 1) [ ] chermcal components or 2) [ ] any AHM components 3) [ ] I 0)LOCATION I cerut?, trader p~alty of law. that I have personally examined and am familiar with the inI~rmation on this and all attimh~ dominants. I believe the submitted informauon is true, accurate and complete. , ?~JN'r Name & Ti~e of Ai~tho~Zed Company R~mm~ve/ ' Si~ Busin~s~ Name BAYOUS MATERIALS INVENTO~ Address CheMICAL DESCRIPTION f !) INVENTORY STATUS: N~v [ 2) Common Name: Chemical Name: ] Additiou [ ] l~visiou [ ] D~letiou [ ] Ch~ ffch~micai is a NON Trad~ ~ [ ] Trad~ .~ [ ] 4) Physical & Health Hazard Categories Fire [ ] Reactive [ 3) DOT # (optional) AHM[ ] c~s# PHYSICAL HEALTH ] S.aa~ Releas~ of Pressure [ ] Tmmo~i.~!~ Health (Acute) [ (3.digit code from DHS Form 8022) 5) WASTE CLASSIFICATION 6) PHYSICAL STATE Solid [ ] Liquid [ ] USE CODE ] D~)~d H~m (cm~m~) [ ] Oas[ ] eure[] ,~Ux~-~[ ] Wadi ] UNITS OF MEASURE 8) STORAGE CODES Lbs [ ] Gal [ ] ft3 [ ] a) Conmu~ Curia [ ] b) ~: c) Temp~a~ Ra~ioa~v¢ [ ] Cfi'cie Which Months: All Year, J, F, M, A, M, J, J, A, S, O, N, D 7) AMOUNT AND TIME AT FACILITY Maximum Daily Amount Average Daily Amount Annual Amount Largest Size Contame: # Days on Site 9) MIXTURE: List COMPONENT CAS# % WT AHM the three most hazardous 1 ) [ ] chemical components or 2), [ ] any AHM components 3) [ ] 1 o )LOCATION 1 ) INVENTORY STATUS: New [ ] Addition [ ] Revision [ ] Deletion [ ] Check if chemical is a NON Tracl~ Secret [ ] Trade Secret [ ] 2) Common Name: 3) DOT # (optional) ChenUcal Name: .43-IM [ ] CAS # 4) Physical & Health PHYSICAL HEALTH Hazard Categones Fire [ ] Reactive [ ] Sudden Release of Pressure [ ] Immediate Health (Acute) [ ] Delayed Health (Chronic) [ 5) WASTE CLASSIFICATION (3-ctigit code from DHS Form 8022) USE CODE 6) PHYSICAL STATE Solidi ] Liquid[ ] Gas[ ] Waste [ ] ~dioactive [ ] ,&MOb~q' .4.NqD TLME AT FACILrUY Ma?CUrium Daiiv .-~,ount Average Daily Amount A.nnual Amount Largest Size Container # Days on Site L~'ITS OF :.MEASURE 8) STORAGE CODES Lbs[ !Gal[ ]R3[ ] a) Contame~. CUries [ ] b) Pressure: c) Temperature Circle ~Vn./ch Months: All Year, J, F, M, A, NL J, J, A, S, O, N, D 9) MIXTURE: List the three most ba?urdous 1) chermcal components or 2). any AHM components 3) COMPONENT CAS# [ ] [ ] [ ] 10)LOCATION I certify under penalty, of law, that I have personally examined and am familiar with the imbrmalion on ~ and all ~ d~'unm~m~ I believe the submitted information is true, accurate and complete. PRINT Name & Title of Authorized Company Refn-esenmtive Signatur~ Dat~ BetzDear orn s~FZDEARBORN MATERIAL ETY DATA SHEET EFFECTIVE DATE: 18-SEP-1996 PRINTED DATE: 5-DEC-1996 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ENTEC OPTI-GUARD MC1 PRODUCT APPLICATION AREA: INTERNAL BOILER TREATMENT. COMPANY ADDRESS: BetzDearborn Inc., Water Mana.aement Group 200 Witmer Road, Horsham, P/~ 19044 Information phone number (215) - 773-6269 EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800)-877-1940 (USA) 2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. AZARDOUS INGREDIENTS: CAS# CHEMICAL NAME 10117-38-1 SULFUROUS ACID,DIPOTASSIUM SALT Transient irritant; potential sensitizer (skin and respiratory) 100-37-8 DIETHYLAMINOETHANOL (DEAE) Combustible liquid; corrosive (eyes and skin); irritant (respiratory); absorbed by skin 110-91-8 MORPHOLINE Flmmmmble liquid; corrosive; toxic (by skin absorption); potential liver and kidney toxin ro component is considered to be a carcinogen by the National. Toxicology ogram, the International. A.qencv for Research on Cancer, or tl3e.. cc.upat~onal Safety and Health Administration at OSHA thresholos tor carcinogens. PAGE I CONTINUED )EDUCT NAME: ENTEC OPTI-GUARD MC1 CTIVE DATE: 18-SEP-1996. 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING May cause moderate irritation to the skin. Absorbed by the skin. Potential sensitizer. Severe irritant to the eyes. Irritation of the upper respiratory tract. Prolonged exposure may cause dizziness and headache. DOT hazard is not applicable Emergency Response Guide is not applicable Odor: Strong; Appearance: Colorless To Light Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS .~CUTE SKIN EFFECTS: Primary route of exposure; May cause moderate irritation to the skin. Absorbed by the skin. Potential sensitizer. ACUTE EYE EFFECTS: Severe irritant to the eyes. ACUTE RESPIRATORY EFFECTS: Primary route of exposure;Irritation of the upper respiratory tract. Prolonged exposure may cause dizziness and headache. INGESTION EFFECTS: May cause gastrointestinal irritation with possible nausea, vomiting, diarrhea, incoordination, mental confusion, dizziness and lethargy. TARGET ORGANS: Prolonged or repeated exposures may cause skin sensitization and/or toxicity to the liver, kidney, and nervous system. MEDICAL CONDITIONS AGGRAVATED: Not known. SYMPTOMS OF EXPOSURE: Inhalation may. cause irritation of the respiratory tract. Skin contact may cause itching and/or redness. PAGE 2 CONTINUED L PRODUCT NAME: ENTEC OPTI-GUARD MC1 EFFECTIVE DATE: 18-SEP-1996 4) FIRST AID MEASURES SKIN CONTACT: Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 1,5 minutes. EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment. INHALATION: Remove victim from contaminated area to fresh air. Apply appropriate first aid treatment as necessary. INGESTION: Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician. Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS: Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F P-M(CC) 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT: Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container. Remove ignition sources. Flush area with water. Spread sand/grit. DISPOSAL INSTRUCTIONS: Water contaminated with this product may be sent to a sanitary sewer treatment facility, in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill. 7) HANDLING AND STORAGE HANDLING: Normal chemical handling. STORAGE: Keep containers closed when not in use. Do not freeze. If frozen, thaw and mix completely prior to use. PAGE 3 CONTINUED )EDUCT NAME: ENTEC OPTI-GUARD MC1 CTIVE DATE: 18-SEP-1996 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME SULFUROUS ACID,DIPOTASSIUM SALT PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED DIETHYLAMINOETHANOL (DEAE) PEL (OSHA): 10 PPM(SKIN) TLV (ACGIH): 2 PPM(SKIN) MORPHOLINE PEL (OSHA): 20 PPM-SKIN(30PPM-STEL) TLV (ACGIH): 20 PPM-SKIN(30PPM-STEL) ENGINEERING CONTROLS: Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT: Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION: A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS. If air-purifying respirator use is appropriate, use a respirator with organic vapor cartridges and dust/mist prefilters. SKIN PROTECTION: gauntlet-type neoprene gloves', chemical resistant apron-- Wash off after each use. Replace as necessary. EYE PROTECTION: splash proof chemical goggles, face shield 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (7OF) 1.183 Freeze Point (F) 19.00 Viscosity (cps 7OF) 13 Vapor Pressure (mmHG) Vapor Density (air-l) % Solubility (%ater) Odor Appearance Physical State Flash Point (F) pH As Is (approx.)' poration Rate (Ether-l) NA = not applicable ND = not determined Strong Colorless To Light Yellow Liquid · 200 P-M(CC) 11.0 < 1.00 - 18.0 · 1.00 100.0 PAGE 4 CONTINUED PRODUCT NAME ' ENTEC OPTI-GUARD MC1 EFFECTIVE DATE: 18-SEP-1996 10) STABILITY AND REACTIVITY STABILITY: Stable under normal storage conditions. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITIES: May react with strong oxidizers. DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: 1 1) TOXICOLOGICAL INFORMATION Oral LDS0 RAT: >2,000 NOTE - Estimated value Dermal LDSO RABBIT: >2,000 rog/kg NOTE - Estimated value 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Fathead Minnow 96 Hour Static Renewal Bioassay pH of test solutions was adjusted to a level of 6-9. LC50:1930 mg/L No Effect Level: 1370 mg/L Daphnia magna 48 Hour Static Renewal Bioassay pH of test solutions was adjusted to a level of 6-9. · LC50:570 mg/L No Effect Level: 125 mg/L BIODEGRADATION COD (rog/gm): TOC (mg/gm): BOD-5 (mg/gm): BOD-28 (mg/gm): 237 Calculated 78 Calculated 0 Calculated 68 Calculated PAGE 5 CONTINUED )EDUCT NAME: ENTEC OPTI-GUARD MC1 CTIVE DATE: 18-SEP-1996 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is: Not applicable. Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material. 14) TRANSPORT INFORMATION DOT HAZARD: Not Applicable UN / NANUMBER: Not applicable DOT EMERGENCY RESPONSE GUIDE ~: Not applicable 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory. CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): No regulated Constituent present at OSHA thresholds FOOD AND DRUG ADMINISTRATION: All ingredients in this product are authorized for use as boiler water additives where the steam produced may contact food. SARA SECTION 312 HAZARD CLASS: Immediate(acute);Delayed(Chronic) SARA SECTION 302 CHEMICALS: No regulated constituent presen~ at OSHA thresholds SARA SECTION 313 CHEMICALS: No regulated constituent present at OSHA thresholds CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds PAGE 6 CONTINUED PRODUCT NAME: ENTEC OPTI-GUARD MC1 EFFECTIVE DATE: 18-$EP-1996 16) OTHER INFORMATION NFPA/HMIS Health 2 Fire 1 Reactivity 0 Special NONE (1) Protective Equipment D CODE TRANSLATION Moderate Hazard Slight Hazard Minimal Hazard No special Hazard Goggles,Face Shield,Gloves,Apron (1) refer to section 8 of.MSDS for additional protective' equipment recommendations. CHANGE LOG EFFECTIVE DATE MSDS status: 22-AUG-1995 18-SEP-1996 REVISIONS TO SECTION: REVISED FORMAT 12 SUPERCEDES ** NEW ** 22-AUG-1995 PAGE 7 MATERIAL ,AFETY DATA SHEET EFFECTIVE DATE: 25-JUN-1996 PRINTED DATE: 29-JUL-1996 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: BETZ ENTEC 559 PRODUCT APPLICATION AREA: CORROSION INHIBITOR/DISPERSANT. COMPANY ADDRESS: BetzDearborn Inc., Water Management Group 200 Witmer Road, Horsham, P/~ 19044 Information phone number (215) - 773-6269 EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800)-877-1940 (USA) 2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. HAZARDOUS INGREDIENTS: 2809-21-4 pHOSPHONIC ACID, (1-}{YDROXYETHYLIDINE) BIS- (HEDP) Corrosive (eyes) 29385-43-1 1-H-BENZOTRIAZOLE,METHYL- (TOLYLTRIAZOLE; TTA) Solid is an irritant (by all routes); liquid is corrosive 1310-73-2 SODIUM HYDROXIDE (CAUSTIC SODA) Corrosive; toxic (by ingestion) 0o component is considered to be a carcinogen by t_he National. Toxicology rogram, the International A.qencv for Research on Cancer, or the cc.upat~onal Safety and Health Administration at OSHA thresholds for carcinogens. PAGE I CONTINUED )EDUCT NAME: BETZ ENTEC 559 CTIVE DATE: 25-JUN-1996 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING May cause slight irritation to the skin. Severe irritant to the eyes. Mists/aerosols may cause irritation to upper respiratory tract. DOT hazard: Corrosive to aluminum, RQ Emergency Response Guide #60 Odor: Mild; Appearance: Yellow, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; May cause slight irritation to the skin. ACUTE EYE EFFECTS: Severe irritant to the eyes. ACUTE RESPIRATORY EFFECTS: Mists/aerosols may cause irritation to upper respiratory tract. INGESTION EFFECTS: ~ May cause slight gastrointestinal irritation. TARGET ORGANS: No evidence of potential chronic effects. MEDICAL CONDITIONS AGGRAVATED: Not known. SYMPTOMS OF EXPOSURE: May cause redness or itching of skin. PAGE 2 CONTINUED PRODUCT NAME: BETZ ENTEC 559 EFFECTIVE DATE: 25-JUN-1996 4) FIRST AID MEASURES SKIN CONTACT: Remove contaminated clothing. Wash exposed area with a large quantity of soap solution or water for 15 minutes, EYE CONTACT: Immediately flush eyes with water for 15 minutes, Immediately contact a physician for additional treatment, INHALATION: Remove victim from contaminated area, Apply necessary first aid treatment, Immediately contact a physician. INGESTION: Do not feed anything by mouth to an unconscious or convulsive victim, Do' not induce vomiting, Immediately contact physician, Dilute contents of stomach using 3-4 glasses milk or water, 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS: Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water o)HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F SETA(CC) MISCELLANEOUS: Corrosive to aluminum,~ RQ NA1760;Emergency Response Guide #60 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT: Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container. Flush area with water. Wet area may be slippery. Spread sand/grit. DISPOSAL INSTRUCTIONS: Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Incinerate or land dispose in an approved landfill. 7) HANDLING AND STORAGE HANDLING: Alkaline. Do not mix with acidic material. STORAGE: Keep containers closed when not in use. Protect from freezing. PAGE 3 CONTINUED E/~%UCT NAME: BETZ ENTEC 559 TIVE DATE: 25-JUN-1996 8) EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE LIMITS CHEMICAL NAME PHOSPHONIC ACID,(1-HYDROXYETHYLIDINE)BIS- (HEDP) PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED 1-H-BENZOTRIAZOLE, METHYL- (TOLYLTRIAZOLE; TTA) PEL (OSHA)' NOT DETERMINED TLV (ACGIH): NOT DETERMINED SODIUM HYDROXIDE (CAUSTIC SODA) PEL (OSHA): 2 MG/M3 TLV (ACGIH): 2 MG/M3(CEILING) ENGINEERING CONTROLS: Adequate ventilation to maintain air contaminants below, exposure limits. PERSONAL PROTECTIVE EQUIPMENT: Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION: A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS. If air-purifying respirator use is appropriate, use a respirator with dust/mist filters. SKIN PROTECTION: rubber gloves-- Wash off after'each use. Replace as necessary. EYE PROTECTION: splash proof chemical goggles 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Gray. (7OF) 1.245 Vapor Pressure (mmMG) ~ 18.0 Freeze Point (F) 18.00 Vapor Density (air=l) < 1.00 Viscosity (cps 70F) 48 % Solubility (water) 100.0 Odor Mild Appearance Yellow Physical State Liquid Flash Point (F) > 200 pH As Is (approx.) 12.8 E~oration Rate (Ether=l) < 1.00 NA = not applicable ND = not determined SETA (CC) PAGE 4 CONTINUED PRODUCT NAME · BETZ ENTEC ,559 EFFECTIVE DATE: 25-JUN-1996 10) STABILITY AND REACTIVITY STABILITY: Stable under normal 'storage conditions. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITIES: May react with strong oxidizers. DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: 1 1 ) TOXICOLOGICAL INFORMATION Oral LD50 RAT: 3,775 mg/kg NOTE - Estimated value Dermal LDS0 RABBIT: >5,000 mg/kg NOTE - Estimated value 12) ECOLOGICAL INFORMATION .AQUATIC TOXICOLOGY Daphnia magna 48 Hour Static Screen 0% Mortality: 500 mg/L Bluegill Sunfish 48 Hour Static Screen 0% Mortality: BIODEGRADATION COD (mg/gm): TOC (mg/gm): BOO-5 (mg/gm): BOD-28 (rog/gm): 1000 mg/L 298 Calculated 114 Calculated 6 Calculated 20 Calculated 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is: D002 = Corrosive(pH). Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material. PAGE 5 CONTINUED E/~%UCT NAME : BETZ ENTEC 559 TIVE DATE: 25-JUN-1996 14) TRANSPORT INFORMATION DOT HAZARD: UN / NA NUMBER: DOT EMERGENCY RESPONSE GUIDE #: Corrosive to aluminum, NA1760 6O RQ 15) REGULATORY INFORMATION TSCA: All components of this product are listed in the TSCA inventory. CERCLA AND/OR SARA REPORTABLE QUANTITY (RQ): 3,572 gallons due to SODIUM HYDROXIDE (CAUSTIC SODA); USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS: SEC.G5,G7 SARA SECTION 312 HAZARD CLASS: Immediate(acute) SARA SECTION 302 CHEMICALS: No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS: No regulated constituent present at OSHA thresholds (~.IFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds PAGE 6 CONTINUED PRODUCT NAME: BETZ ENTEC 559 EFFECTIVE DATE: 25-JUN-1996 16) OTHER INFORMATION NFPA/HMIS Health 2 Fire Reactivity 0 Special ALK (1) Protective Equipment B CODE TRANSLATION Moderate Hazard Slight Hazard Minimal Hazard pH above 12.0 Goggles,Gloves (1) refer to section 8 of MSDS for additional protective equipment recommendations. CHANGE LOG EFFECTIVE DATE MSDS status: 22-AUG-1995 25-JUN- 1996 REVISIONS TO SECTION: REVISED FORMAT 2 SUPERCEDES ** NEW ** 22-AUG-1995 PAGE 7 S-IS-1GG? 2:S~PP~ ~RO~ P~CI~IC PWR SYS 310G~9~221 COM A Division o/C&D Charier Powe~ Systems. Inc. FAX TO MIKE CONNER (805) 663-'1309 SIX (6) TOTAL PAGES May 15, 1997 Dear Mr. Conner: I think this document MSDS 14-312 may assist you, particularly the middle of numbered page four. Should we be able to provide you with any additional information, please don't hesitate to call. Your sales representative is John Lane, and information on how to reach him is shown below. Thanks very much for your call. Sincerely, David T. Auten Supervisor, Branch Administration cc: John Lane I: COM A Division of C&D Charter Power Systems, lng. John Lane Sales Reptese~tative 3220 Norwa[X Bouleva:~/ 5ante Fa Springs. CA. 908,70 'Telephone (562) 6~9.1950 (800) 300-0045 (562) 780-8130 (562) 659-8,221 S-1S-1997 2:SVPN FROI~ALPACIFIC PwR SYS 310699822; C & D POWER COM A DIVISION OF C & D CHARTER POWER SYSTEMS,INC. MATERIAL SAFETY DATA SHEET 14-312 SECTION I: CHEMICAL PRODUCT AND COMPANY iDENTIFICATION. PRODUCT IDENTITY: Sealed, Lead-Calcium Battery 'CDID: UBERTY SERIES LS 12-25, 6-50, 12-100, 6-200, 4-300 & 2-600 MANUFACTURER NAME: C & D Charter Power Systems, Inc. ADDRESS: 1400 Union Meeting Road P. O. Box 3053 BlueBell, PA 19422-0858 TELEPHONE: (215) 619-2700 EMERGENCY: (610) 828-9309 24 HOUR EMERGENCY TELEPHONE: (.CHEM TEL) 1-600-25.~3924 SECTION I!: COMPOSmON I INFORMATION ON INGREDIENTS NOTE: The C&D "Liberty Series" batteries are sealed, recombinant design. Under normal use and handling the customer has no contact with the internal components of the battery or the chemical haT=rds. Under normal use and handling these batteries do not emit regutated or haT=rdous substances. HAZARDOUS OSHA ACGIH % BY COMPONENT CAS# PEL .TLV WEIGHT 'Lead, Lead compounds 7439-92-1 0.05rog/m3 0.15mglm3 67-71% *Sulfuric Acid 7664-93-9 1.0rog/m3 1.0mgJ m3 6 - 7% Tin 7440-31-5 2.0mglm3 2.0mg/m3 < .1% Aluminum 7429-90-5 NtA 10.0mg/m .3 < .01% Copper 7440-50-8 1.0rog/m3 1.0mglm3 < .01% NON-HAZARDOUS INGREDIENTS Water 7732-18-5 N/A NIA 14 -16% Calcium 7440-70-2 NIA NIA .01% Inert Components NIA N/A N/A ,-t 7 - 12% SECTION 313 (40 CFR 372.). USTED TOXIC CHEMICALS ARE PRECEDED BY AN % S-1S-1997 2:S8~ :nLPnCIFIC Pw~ SYS 3106998221 P. 3 14-312 LSECTION !11: HAZARDS IDENTIFICATION APPEARANCE AND ODOR: Colorless, Oily Fluid, Vapors are Colorless; Acrid Odor when Hot or Charging.. HMIS RATING: 0=Insignificant, 1=Slight 2=Moderate 3=High 4=Extreme Health:_2.. Flammability:._O_ Rea~ivity:_l_ Other:._. 0_ NFPA RATING: 0=Insignificant, 1=Slight 2=Moderate 3=.High 4=Extrern~e Health:_2_ Flammability:_0_ Reactivity:_1_ Other.'__CORR_ ROUTES OF ENTRY: Inhalation X Skin_X, Ingestion_X_ TARGET ORGANS: Skin, Eyes, Upper Respiratory Tract HEALTH HAZARDS (ACUTE AND CHRONIC): ACUTE: Tissue destruction on contact. May cause 2nd and 3rd degree bums ¢,r blindness. Ingestion will cause corrosive burns on contact. May be fatal if swallowed. CHRONIC: Inhalation of mists may cause upper respiratory irritation. SIGNS AND SYMPTOMS: Irritation and burning of exposed tissues. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Respiratory disorders may be aggravated by prolon~led inhalation of mists. SECTION IV: FIRST AID MEASURES EMERGENCY AND FIRST AID PROCEDURES: SKIN ! EYES -Flush with water for 15 minutes -Remove contaminated clothing -If irritation continues, seek mediCal attention. INGESTION -Do not induce vomiting -Drink large quantities of milk or water -Give CPR if breathing has stopped -Seek medicalattention immediately SECTION V: FIREFIGHTING MEASURES i FIRE AND EXPLOSIVE PROPERTIES: Flash Point: _N/A_ Oxygen Index:__>32__ Flammable Limits: LEL:_N/A_ UEL:_N/A_ UNUSUAL FIRE AND EXPLOSION HAZARDS: Hydrogen gas maY be present. Hydrogen gas and acid mist is generated upon overcharge or in fires. Ventilate area. EXTINGUISHING MEDIA: Dry Chemical, Halon, or Carbon Dioxide SPEC[AL FIREFIGHTING PROCEDURES: Ventilate the area well, SCBA and acid protective clothing are recommended. 2 14-312 SECTION VI: ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IF BATTERY IS BROKEN: NeutraFrze any spilled electrolyte or exposed battery parts with soda ash or sodium bicarbonate until fiT:,ing stops, pH should be netrtral at 6-8. When neutralized, the spill is non-hazardous. Keep untrained individuaLs away from the spilled material. Place the broken battery in a heavy guage plastic bag or other non-metallic container. Provide adequate ventilation, hydrogen gas may be given off durin~l neutralization. SECTION VII: HANDUNG AND STORAGE IStore in a cool, dry area away from combustibles. Do not store in sealed, unven'[ilated areas. Avoid overheating and overcharging. Do not use organic solvents or other than recornmended chemical cleaners on the batteries. SECTION VIIi: EXPOSURE CONTROLS I PERSONAL PROTECTION ENGINEERING CONTROLS: General room ventilation/s sufficient during nonn;] use and handling. Recommend 2 to 3 room air changes per hour to prevent buildup of hydrogen gas. PERSONAL PROTECTIVE EQUIPMENT (IN THE EVENT OF BATTERY BREAKAGE): Eye Protection= chemical goggles or safety glasses with sideshields and a full f, ace shield. Protective Gloves= rubber or neoprene Respiratory Protection= NIOSH approved acid mist respirator, if OSHA PEL is exceeded. Other Protective Equipment=- acid resistant apron or clothes. WORK PRACTICES: Do not wear metallic jewelry when working with batteries. Use non-conductive tools only. Discharge static electricity prior to working on a battery. Maintain an eyewash, fire extinguisher and emergency communication device in the work area. SECTION IX: PHYSICAL AND CHEMICAL PROPERTIES ACID: Boiling Point:__N/A_ Vapor Pressure:_NIA_ Vapor Density:_(air=l):_>l_ Melting Point:_NIA_ Evaporation Rate (water=l):_N/A_ Solubility in water_N/A_ Specific Gravity (contained in battery):_l.300+l-.010_ Appearance / Odor: colorless, oily fluid I acrid odor when hot. S-1S-lgg-7 2:SgP~4 F'ROh~ :IF[C PWR S¥S 3101Sgg8221 14-312 ~SECTION X: STABILITY AND REAC'FlVFFY STABILITY: This battery and contents are stable. CONDITIONS TO AVOID: Overheating, overcharging which result in acid mist ,' hydrogen generation. INCOMPATIBILITY: Strong alkaline materials, conductive metals, organ (MATERIALS TO AVOID) solvents, sparks or open flame. HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Hydrogen gas may be generated in an overcharged condition, in fire or at very high temperatures, in fire may emit CO, CO2 and Suffur Oxides. HAZARDOUS POLYMERIZATION WILL NOT OCCUR. SECTION Xh TOXICOLOGICAL INFORMATION - SULFURIC ACID The ~Liberty Series" batteries are sealed, recombinant design. Under normal u-~e and handling the customer has no contact with the intema! components of the battery or the chemical hazards. Under normal use and handling these batteries do not emit regulated or hazardous substances. These batteries meet the definition of 'Article'* under 29 CFR 1910.1200 (OSHA Hazard Communication Standard) and the SARA Community-Right-To-Know requirements. TOXICOLOGICAL INFORMATION' DOES NOT APPLY. SECTION XII: ECOLOGICAL INFORMATION Lead compounds can pose a threat released to the environment. See waste disposal method in Section XilI. SECTION XlJl: DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD: This battery is recyclable. It is illegal to dispose of lead-acid batteries by any means other than recycling. C&D provides an environmentally responsil)le nation wide lead acid battery collection and recycling program. Contact your local C&D sales representative for more information. HAZARDOUS WASTE CODES: D002, D008 2:S9P~ FROP~LP4CIFIC PwR SYS 3106998221 14-312. SECTION XIV: TRANSPORTATION INFORMATION All DOMESTIC SHIPMENTS: BATTERY, I~LiE, CTRIC STORAGE. WET, NON- .s. pILLABLE, NOT REGULATED. NO PLACARDS OR LABELS REQUIRED. FOR WATER EXPORT AND CANADIAN SHIPMENTS: UN OR NA IDENTIFICATION: UN-2800 PROPER DOT SHIPPING NAME: _Ba~eries. Wet. Non-sa..i.!lable, Electric_ Stora.q?_ HAZARD CLASS: 8_L PACKING GROUP: II_LI LABEL: Corrosive (NOT REQUIRED FOR CANADA} SECTION XV: REGULATORY INFORMATION {See 29 CFR lglo.268(b)(2,) .. [SECTION XVI: OTHER INFORMATiON I I I I I _ IIII II I The information herein is given in good faith, but no warranty, expressed or implied, is made. MSDS Preparation Date: 4/11/96 Revision Number: 5, Preparer: $. J. Kelly OBetzDe born i~.~"JETZDEARBORN MATERIAL ~AFETY DATA SHEET EFFECTIVE DATE: 28-$EP-1996 PRINTED DATE: 28-FEB-1997 1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME :BETZ ENTEC 368 PRODUCT APPLICATION AREA: BIOCIDE COMPANY ADDRESS: BetzDearborn Inc., Water Management Group 200 Witmer Road, Horsham, P/~ 19044 Information phone number (215) - 773-6269 EMERGENCY TELEPHONE (HEALTH/ACCIDENT): (800)-877-1940 (USA) 2) COMPOSITION / INFORMATION ON INGREDIENTS Information for specific product ingredients as required by the U.S. OSHA HAZARD COMMUNICATION STANDARD is listed. Refer to additional sections of this MSDS for our assessment of the potential hazards of this formulation. HAZARDOUS INGREDIENTS: CAS~ CHEMICAL NAME 10377-60-3 MAGNESIUM NITRATE Oxidizer; irritant (eyes and skin) 26172-55-4 5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE Corrosive; toxic (by ingestion and skin absorption); sensitizer (skin) p~O component is considered to be a carcinogen by the National. Toxicology rogram, the International A.qencv for Research on_C_ancer, or ,tl3,e, . cc.upat~onal Safety and Health Administration at OSHA tl3resnolos tor carcinogens, PAGE I CONTINUED t~FODUCT NAME: BETZ ENTEC 368 ECTIVE DATE: 28-SEP-1996 3) HAZARDS IDENTIFICATION EMERGENCY OVERVIEW DANGER Corrosive to skin. Skin sensitizer with delayed onset of symptoms. Corrosive to the eyes. Mists/aerosols cause irritation to the upper respiratory tract. DOT hazard: Corrosive to skin Emergency Response Guide #153 Odor: Aromatic; Appearance: Light Yellow To Green, Liquid Fire fighters should wear positive pressure self-contained breathing apparatus(full face-piece type). Proper fire-extinguishing media: dry chemical, carbon dioxide, foam or water POTENTIAL HEALTH EFFECTS ACUTE SKIN EFFECTS: Primary route of exposure; Corrosive to skin. Skin sensitizer with delayed onset of symptoms. ACUTE EYE EFFECTS: Corrosive to the eyes. ACUTE RESPIRATORY EFFECTS: Mists/aerosols cause irritation to the upper respiratory tract. INGESTION EFFECTS: May cause severe, irritation or burning of mouth, throat, and gastrointestinal tract with severe chest and abdominal pain, nausea, vomiting, diarrhea, lethargy and collapse. Possible death when ingested in very large doses. TARGET ORGANS: Prolonged or repeated exposures may cause tissue necrosis and/or skin sensitization. MEDICAL CONDITIONS AGGRAVATED: Not known. SYMPTOMS OF EXPOSURE: Direct contact with skin will cause severe delayed skin reactions or burns if not washed off immediately- follow first aid instructions. PAGE 2 CONTINUED PRODUCT NAME · BETZ ENTEC 368 EFFECTIVE DATE: 28-SEP- 1996 ¢) FIRST AID MEASURES SKIN CONTACT: Remove clothing. Wash area with large amounts of soap solution or water for 15 min. Immediately contact physician. EYE CONTACT: Immediately flush eyes with water for 15 minutes. Immediately contact a physician for additional treatment. INHALATION: Remove victim from contaminated area. Apply necessary first aid treatment. Immediately contact a physician. INGESTION: Do not feed anything by mouth to an unconscious or convulsive victim. Do not induce vomiting. Immediately contact physician. Dilute contents of stomach using 3-4 glasses milk or water. 5) FIRE FIGHTING MEASURES FIRE FIGHTING INSTRUCTIONS: Fire fighters should wear positive pressure self-contained breathing apparatus (full face-piece type). EXTINGUISHING MEDIA: dry chemical, carbon dioxide, foam or water HAZARDOUS DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. FLASH POINT: > 200F P-M(CC) MISCELLANEOUS: Corrosive to skin UN3265;Emergency Response Guide #153 6) ACCIDENTAL RELEASE MEASURES PROTECTION AND SPILL CONTAINMENT: Ventilate area. Use specified protective equipment. Contain and absorb on absorbent material. Place in waste disposal container. Do not add decontaminant solution to waste drum containing biocide or adsorbent. Decontaminate floor residual with 10% metabisulfite solution. Use 10 volumes of solution to one volume of spill. DISPOSAL INSTRUCTIONS: Water contaminated with this product may be sent to a sanitary sewer treatment facility,in accordance with any local agreement,a permitted waste treatment facility or discharged under a permit. Product as is - Dispose of in approved pesticide facility or according to label instructions. PAGE 3 CONTINUED i~ODUCT NAME: BETZ ENTEC 368 FECTIVE DATE: 28-SEP-1996 7) HANDLING AND STORAGE HANDLING: Contains an oxidizer. Avoid all contact with reducing agents, oils, greases, organics and acids. Corrosive to skin and/or eyes. STORAGE: Keep containers closed when not in use. Store between 20-100F for no more than 6 months. Store upright in original vented containers. Product evolves CO2 slowly. Store samples in plastic bottles due to pressure build-up. 8) EXPOSURE CONTROLS/PERSONAL PROTECTION CHEMICAL NAME EXPOSURE LIMITS MAGNESIUM NITRATE PEL (OSHA): NOT DETERMINED TLV (ACGIH)' NOT DETERMINED 5-CHLORO-2-METHYL-4-1SOTHIAZOLIN-3-ONE PEL (OSHA): NOT DETERMINED TLV (ACGIH): NOT DETERMINED MISC: Note-mfg. sugg. exp. limit:O.1 mg/m3 TWA;O.3mg/m3 STEL total isothiazoline). ENGINEERING CONTROLS: Adequate ventilation to maintain air contaminants below exposure limits. PERSONAL PROTECTIVE EQUIPMENT: Use protective equipment in accordance with 29CFR 1910 Subpart I RESPIRATORY PROTECTION: A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA'S 29 CFR 1910.134 AND ANSI Z88.2 REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A RESPIRATOR'S USE. USE AIR PURIFYING RESPIRATORS WITHIN USE LIMITATIONS ASSOCIATED WITH THE EQUIPMENT OR ELSE USE SUPPLIED AIR-RESPIRATORS. If air-purifying respirator use is appropriate, use a respirator with organic vapor/acid gas cartridges and dust/mist prefilters. SKIN PROTECTION: gauntlet-type butyl gloves, chemical resistant apron-- Wash off after each use. Replace as necessary. EYE PROTECTION: splash proof chemical goggles, face shield PAGE 4 CONTINUED PRODUCT NAME: BETZ ENTEC 368 EFFECTIVE DATE: 28-SEP-1996 9) PHYSICAL AND CHEMICAL PROPERTIES Specific Grav. (7OF) 1.033 Freeze Point (F) 28.00 Viscosity (cps 7OF) 8 Odor Appearance Physical State Flash Point (F) pH As Is (approx.) Evaporation Rate (Ether-l) Vapor Pressure (mmqG) Vapor Density (air-l) % Solubility (~ter) Aromatic Light Yellow To Green Liquid > 200 P~M(CC) 3.5 < 1.00 NA = not applicable ND = not determined 20.0 < 1.00 100.0 10) STABILITY AND REACTIVITY STABILITY: Stable under normal storage conditions. HAZARDOUS POLYMERIZATION: Will not occur. '1N CO M PATI BI UTI ES: May react with strong oxidizers. DECOMPOSITION PRODUCTS: Thermal decomposition (destructive fires) yields elemental oxides. BETZ INTERNAL PUMPOUT/CLEANOUT CATEGORIES: 1 1 ) TOXICOLOGICAL INFORMATION Oral LD5ORAT: Teratology : Dermal LD5ORABBIT: NOTE - Estimated value Skin Sensitization HUMAN: Non-Ames Mutagenicity : >5,000mg/kg NEGATIVE >2,000m g/kg POSITIVE NEGATIVE PAGE 5 CONTINUED i~ODUCT NAME: BETZ ENTEC 368 FECTIVE DATE: 28-SEP-1996 12) ECOLOGICAL INFORMATION AQUATIC TOXICOLOGY Rainbow Trout 96 Hour Static Acute Bioassay LC50:8.7 mg/L No Effect Level: 6.5 mg/L Daphnia magna 48 Hour Flow-Thru Bioassay Mortality was observed in lowest concentration tested. Test concentrations were analytically verified. LC50:2.9 mg/L 10% Mortality: .6 mg/L Bluegill Sunfish 96 Hour Static Acute Bioassay LC50:' 12.1 mg/L No Effect Level: 6.5 mg/L Fathead Minnow 96 Hour Flow-Thru Bioassay Test concentrations were analytically verified. LC50:6.6 mg/L No Effect Level: 2.5 mg/L BIODEGRADATION COD (rog/gm): TOC (mg/gm): BOD-5 (mg/gm).' BOD-28 (mg/gm): 14 Calculated 9 Calculated 0 Calculated 0 Calculated, 13) DISPOSAL CONSIDERATIONS If this undiluted product is discarded as a waste, the US RCRA hazardous waste identification number is: Not applicable. Please be advised; however, that state and local requirements for waste disposal may be more restrictive or otherwise different from federal regulations. Consult state and local regulations regarding the proper disposal of this material. 14) TRANSPORT INFORMATION DOT HAZARD: UN / NA NUMBER: DOT EMERGENCY RESPONSE GUIDE ~: Corrosive to skin UN3265 153 PAGE 6 CONTINUED PRODUCT NAME .' BETZ ENTEC 368 EFFECTIVE DATE: 28-SEP-1996 15) REGULATORY INFORMATION TSCA: This is an EPA registered biocide and is exempt from TSCA inventory requirements. CERCLA AND/OR SARA REPORTABLE QUANTITY {RQ): No r~gulated constituent present at OSHA threshOlds FIFRA REGISTRATION NUMBER: 3876-143-34571 USDA FEDERALLY INSPECTED MEAT AND POULTRY PLANTS: SEC.G7 SARA SECTION 312 HAZARD CLASS: I mmed iate(acute); Delayed (Chronic) SARA SECTION 302 CHEMICALS: No regulated constituent present at OSHA thresholds SARA SECTION 313 CHEMICALS: CAS# C[~J~CA~ NAM~ 10377-60-3 MA(;N~SIUH NI~L¥I~ I~J~GE 2.0-5.0% CALIFORNIA REGULATORY INFORMATION CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65) CHEMICALS PRESENT: No regulated constituent present at OSHA thresholds MICHIGAN REGULATORY INFORMATION No regulated constituent present at OSHA thresholds PAGE 7 CONTINUED P~DUCT NAME: BETZ ENTEC 368 EPPECTIVE DATE: 28-SEP-1996 16) OTHER INFORMATION NFPA/HMIS Health 3 Fire 1 Reactivity 0 Special CORR (1) Protective Equipment D CODE TRANSLATION Serious Hazard Slight Hazard Minimal Hazard DOT corrosive Goggles,Face Shield,Gloves,Apron (1) refer to section 8 of MSDS for additional protective equipment recommendations. CHANGE LOG EFFECTIVE DATE MSDS status: 22-AUG-1995 12-MAR-1996 28-SEP-1996 REVISIONS TO SECTION: REVISED FORMAT ;EDIT:9 3,5,14 SUPERCEDES ** NEW ** 22-AUG-1995 12-MAR-1996 PAGE 8 / ~UN-l~-1997 14:15 ~i~ENCE PETROLEUM 805 589 288--~ P. 02 MATERIAL SAFETY DATA SHEET DATE ISSUED: 08/01/96 SUPERSEDES DATE: 01/02/92 PRODUCT: DIESEL NO. 2 .CARB-RED DYE EMER~£NCY PHONE WUMBER$: POISON CONTROL CENTER: 800/346-5922 MANUFACTURER: K~RNO!L & REFININ~ CO. C~MTREC= 800/424-9300 7724 FAST PANAMA LANE KER/~ OIL: $0~/B45-0761 BAKERSFIELD, CA ~3307 TRADE NAMe: GENERIC NAME: CHEMICAL NAME: CH~4I CAL FAMILY C~_-RCLA RATINGS: NFPA RATINGS: Diesel No. 2 Diesel fuel Mixture of pe=roleum hydrocarbons Middle distillate, diesel oil'' Alipha=ic and aromatic hydrocarbons (Scale 0-3) HEALTI{ = 3 FIRE = 2 (Scale 0-4) HEALTH = 0 FIRE ~ 2 SECTION I - MATERIAL IDENTIFICATION PRODUCT CODE NO.: CAS NO.: 68476-34-6 RTEC$ NO.: None .... REACTIVITY = 0 REACTIVITY = 0 KOP009 PERSISTENCE = 1 100% SECTION II - COMPONENTS AND CONTAMINANT~ Diesel Fuel No. 2 CAS ~ 68476-34-6 R~COM}~-'NDmD EXPO-~URE LIMITS TWA STOL ~ NONZ Mineral oil mist 8012-95-1 5mg/M~ 0 5m~/M~ 10m~/M~ ~ACGI~; O=OS~IA; N-NIOS~ 3UN-12-1997 14:16 PENCE PETROLEUM 805 589 2883 P.OJ ODUCT: DIESEL NO. 2 SECTION III - PHYSICAL AND CHEMICAL CHARACTERISTICS DESCRIPTION: odor. A straw or amber colored liquid with a characteristic petroleum hydrocarbon MELTING POINT: NA BOILING POINT/RANgE: 3S0-700e VAPOR PRESSURE 0.01 mm H9 ~ 68" F % VOLATILE BY VOLUME: 100% VAPOR DENSITY: H~avier than air EVAPORATION RATE: Slower than BuAc SOLUBILITY (WATER) Negligible SPECIFIC GRAVITY: 0.86 - 0.87 API GRAVITY: 31-33 VISCOSITY: 33-40 SSU % 100° F POUR POINT: -20 to +100 F SECTION IV - FIRE AND ~XPLOSION HAZARD INFORMATION FLASH POINT (METNOD) 150-180" F/PMCC EXPOSURE LIMITS (% BY VOLUME/AIR): LOWER: 0.6% AUTOIGNITION T~MP: 475" F UPPRR: 7.5% FLAMMA~'ILITY CLASS' (OSHA): II FIRE/£XPLOSION HAZARDS: This material is a moderate fire and explosion hazard and may be i~ni=ed by an igni=ion source above i~s flash point. Vapors may travel to ignition source an flash back. Containers may explode in fire. Vapor explosion hazard indoors, outdoors or in sewers. Empty ~gntainers retain material residue and may generate vapors which may ignite an e%lode. USTiON PRODUCTS: Carbon dioxide, carbon monoxide and water vapor. EX. TINGUISWTN~ MEDIA: Carbon dioxide, dry chemical, foam and water spray. FIP~ FIGRTING PROCE, DUR~S: wear protective equipment and clothing when fighuiu~ fires, including a self-contained brea~hin~ apparatus for fires in enclosed spaces. Use water spra~' :o aool fire-e~osed containers, to ailu:e and disperse vapors, protect personnel, and to flu unignited spills from fire. SECTION V - cw~MICAL REACTIVITY INFORMATION ST~ILITY: Stable under normal conditions of storage and handling. REACTIVITY: Reacts vigorously with szrong acids and oxidizing agents. INCOMPATIBILITY: Incompatible with strong acids and o~idizin~ agen=s. i~j. ARDOUS REACTION/DECOMPOSITION PRODUCTS: Burning produces carbon dioxide and carbon monoxide. May release acrid smoke and irritating fumes. COh'DITIONS CONTRIB~3TING TO HAZARDOUS POLYMERIZATION: Hazardous polymerization has no: been reporued to occur under normal temperatures and pressures. 3UN-12-1997 14:16 (~i~ENCE PETROLEUM 805 589 2883 P.04 PRODUCT: DZ~S~L NO. 2 SECTION VI - HT3~LTR KAZARDAND FIRST AID INFORMATION KEALT~ HAZARDS: GENERAL: This material is an aspiration hazard and a skin irritant. IC may be a skin cancer hazard based on laboratory animal tests. Breathing vapors at high concentrations may cause central nervous system depression. OCULAR/EYE: This material may cause eye irritation. Contact with the liquid may cause burning, tearing, and redness. DERMAL/SKIN: This mauerial may cause ~kin irri~anion. Prolonged or repeated contact may cause burning, redness, drying and cracking of the skin, and dermatitis. INhALATION/BREATHiNG: Exposure to mists or to excessive vapor concentrations may cause irritation of the nose, throat, and respiratory tract; defers the skin; and signs of central nervous system depression; i.e., headache, nausea, drowsiness and dizziness. INGESTION/SWaLlOWING: Accidentally swallowing uhis material can cause irritation of the' s~omach and digestive tract. Larger ingestions may cause signs of. central nervous system depression; i.e., headache, nausea, drowsiness and dizziness. This material is an aspiration hazard and may enter the lungs when swallowin~ or vomitin~ and cause serious lung damage. CHRONIC/OTHER: Repetitive lon~-term skin application of similar pe=roleum distillates has been shown to cause skin 'cancer in laboratory animals.' M~DICAL CONDITIONS AGGRAVATED ~Y EXPOSURE: Pre-existing skin disorders. Chronic pulmonary disease. OCULAR/EYE CONTACT: Flush the affected eye(s) with water. If irritation develops, seek medical assistance. /SKINCONTACT: Remove contaminated clothing and flush with and ~on~c~ areas =~ thoroughly cleanse con=act area by washing with soap and wauer. If irritation or redness d~veloD and persist, seek medical assis:ance. T/THALATION/B~T~IN~: IF VICTIM IS NOT ~RF-AT~IN= OR 'IF BREAT~I/~G DIFFICULTIES DEVELOP ARTiFICiAL R~SPIRATION OK OXYGEN SHOULD BE ADHINISTF~ED BY QUALIFIED PERSONNEL. If symptoum per~isu, seek medical a~sistance. INGESTION/SWALLOWINg: DO NOT INDUCE VOMIT/N~/ASPIRATION NA~ARD. If victim iS conscious and alert, give milk or water :o drink. Seek immediaue medical assistance. $UN-12-1997 14:17 PETROLEUM 885 589 2883 P.05 ClDUCT: DIESEL NO. 2 SEC-lION VII PRECA~/TIONS FOR SAF~ F~LING ~ USE $~IPPIN~ INFO~4;~TTON= D.O.T. SHIPPING NAME: Diesel fuel D.O.T. ID NU~ER: 3, NA 1993, III D.O.T. H~ CI~%SSIFICATION: Combustible liquid. SHIPPING P, EGL~TIONS: No label reql/ired, See E~DT re~ulations 49CFR 173 for packaging reqUirements. STORAGE: Store in closed containers in a cool. well-ventilated area away from all heat and ignition and strong oxidizing agents, containers should be electrically bonded and grounded when transferring materials. bL%-%TDLING: Use in a well-ventilated area and wear recommended protective equipment and clothing. Use explosion-proof tools and equipment. Avoid eye contact, breathing vapors or mists and prolonged or repeated skin contact, Label all unattended containers. MISUSE OF EMPTY CONTAINERS CAN BE HAZARDOUS. COMPLETELY DRAIN A/4D }{A%rE COMMERCIALLY CLEANED BEFORE ANY REUSE. KEEP CONTAINERS CLOSED. DO NOT USE TO MIX OR STORE ANY OTHER MATERIALS BEFORE THEY HAVE BEEN COMMERCIALLY CLEANED, DO NOT 'CUT. WELD, DRILL OR SUBJECT CONTAINERS TC HEAT'OR FLA~s". V;~O~'MA¥ IGNITE ARD EXPLODE. ' ..... SPECIAL PRECAUTIONS AND COMMENTS; Enclosed or head spaces in material tanks, pines or ~gD/~may contain hazardous concentrations of fumes or vapors. Exercise'.caution and wea 'recom~ended protective equipment and clothing when opening valves or tank and maintenance or sampling where there is a potential for exposure to these fumes or vapors. ~P!LL OR LEAK PROCEDURES: Evacuate area around large spills. Remove all ignition sources ~n~ provide exploslon-proof ventilation. Wear recommended protective clothing and equipment. Do not allow spills to e~ter sewers, streams or surface waters. Dike and contain spills. Us ~n~rt absorbent to reduce fumes a~d to pick up spill. Collect for later disposal, D~_~POSAL PROCEDURES: DISPOSE OR IN ACCORDANCE WITH FEDERA/~, STATE AND LOCAL R~GI/LATIONS. Tkls ~erial is class~_fied by the EPA as a hazardous waste under RC~, NO. D001 Igllit~ble Waste. Empty contsiner~ should be c6mmercially cleaned and reconditioned for reuse. gECTION VIII - PERSONAL PROTECTION A/~D ~NGINEERING CON~fROLS _=%.~ AND FACIAL PROTECTION: Chemical goggles are recommended to prevent eye con:act. SKiEN PROTECTION: Protective 91oyes and clothing are recommended when prolonged contac: with th~ c~ncentrated material may occur. RESPIRATORY PROTECTION: In situations where vapor concencrations exceed the recommended exp_osure limits, a NIOSH approved organic vapor car=ridge or air-supplying respire:or should VE/~TII~ATION: Explosion-proof ~eneral mechanical ventilation and local exhaust are recommended no maintain vapor concentrations below the recommended exposure limits. O~R: An eye wash and a source o~ runnin~ water should be available to flush or wash th eyes and skin. TOTAL P.05