HomeMy WebLinkAboutBUSINESS PLAN lusi ness Name:
IrlMMP
Flintco Inc.
PLAN tv~lA P
FACILITY DIAGRAM
Z~ Area Map * of
NO ET It Name of Area ·
CONDEI"IED CYLINDER STORAGE
EMPTY
TRUCK PARKING
CARBON
DIOXIDE
OUT OF
SERVICE
EPIPTY
F I[.L STA:I'ION
I I ULTRA SORB ON PALLETS
I I MISC. CLDTHING
STORAGE
n
WELD lNG
~ IRE
TOOLS
BOOTS
AEROSOLS
CABLE
OFFICE
ACETYL INE
EI"PTY
EMPTY
ARGON
OXYGEN
NITROGEN
ACETYLENE
FULLS
Imllllll
PARKING
500 Gal.
PROPANE
L
ITE DIAGRAM
Business N~ne
MMP PLAN MAP
FLINTCO INC
Ar'es Mai> -z- of
#0 RT H
N~Qe of' Area-
30th Street
. VACA T'
! laTaN I
I max~£ I
-- - BUILDING FLINTCO
BUILDIN6
OFF RAHP TO GARCES CIRCLE
CHESTER AVE.
Golden State Hwy.
PROPANE SHUTOFF
{ emlr[y ]{ ~nor=RL
cYti~lex {
PROPI"IHE
PLAT
Lots 3 to 8 inclusive of Block.
5~;3 in the 6~ty, of B~kersfie~,
~cept that porti~
the
BAKERSFIELD sc.oot, ms'r. I-/.
CITY
OF
. I '20
'' -- ' ' -- "l oer' - ' - F~ ~ - ' I
~ ( I .;
, , ! ~,~ ·
~ ,., I .. ' ~ "'
. ,. , . ~, ....
,~, -~..., ,. ,. . ..
"
. ~. ...... ~
....... -; ~ ~
'~.
-20-
.dO;
-19 -
I IIIII II
\
771-/]osp 4
I/
CUSTO'4ER
1
L
L
ORDER ~HI P B/O ,~!!ppt,y ,DESCRIPTION : . ...... , ' .. ----
FLINTCO
WELDING SALES & SERVICE
pHnNE -"4 2 ~i-6 9 9 2
1 3rl] - ;3nTH -¢~T., BAKERSFIELD, CALIF.
I 3 .' 06 C ROWNMA R IILE
'FAX
co, center
T R A N $/'1I $ 5 I.O.N
TOTAL; NUll.. BER OF PAGES:
II.'You. ;:..H..~e., Any Difficulties WTth This Tra.nsmis~ion, Please Conlacl The Sender At.The
~hone'Nb~b~t. Usted 'Above. MessagtdCom~ent: '
Ch~qu~ .&. Business. Forms [ .~/~ i -~[?1'v= I'
Custom S,gnS..& Banners - i i P~' ! =~~'/~gg.'.~5.. i'.
'£ l'
Z
t
"
November 17, 1999
COMPOSITES ONE
Durastone Kitchens & Baths
1230 Parallel
Fresno, CA 93700
United States
Our Valued Customer:
In keeping with the federal and state 'RIGHT TO KNOW' laws, we are
enclosing an MSDS for these products:
102017 040-4919 CLEAR
82005A 4 X 8# M-50A CLEAR CADOX
40001 ACETONE ~ i~
--q~203206 RCI 32145-22 MARBLE RESIN DRUM
The OSHA HAZARD COMMUNICATION STANDARD states that employees must
be trained in how to use an MSDS as a source for hazard
information. All relevant sheets must be readily accessible to
employees during each workshift when they are in their work areas.
If you have any questions concerning the information contained in
the MSDS, please contact me as soon as possible.
To make our communications most effective, we would appreciate
knowing who is responsible for your MSDS file. In this way, we can
send new and revised sheets directly to this contact to ensure
that the information in your safety program is current.
Please return this sheet to the Department of Health, Safety, &
Environment or call us at 847/437-0200 FAX: 847/437-6060.
Thanks so much.
MSDS Contact:
MA/8440/7602500
Bill Rudersdorf
Health, Safety, & Environment
CORPORA TE OFFICES
723 W. Algonquin Road
P.O. Box 3208
Arlington Heights, IL 60006-3208
847.437.0200
847.437.0664 FAX
www. compositesone, com
Page ~ of 8
MATERIAL SAFETY DATA SHEET
SECTION I IDENTIFICATION
TRADE NAME: STYPOL e~e-qgl9
DESCRIPTION: MARBLE CLEAR GEL COAT
PRODUCT CODE IDENTITY: e~0~919KCB2
NPCA HMIS RATING: H Z F S R 1
COMPANY NAME: COOK COMPOSITES AND PDLYWERS CO.
ADDRESS: 8Ze E. l~th AVENUE
NORTH KANSAS CITY: MO ~1~
REVISION: lB
L~ST REVISED : G7/~/~SS
DATE OF ISSUE: e7/19/~999
PREPARED BY:
HAZARD COMMUNICATION DEPT,
CUSTOMER: GLS FIBERGLASS CORP
7Z8 ~ ALGONQUIN RD
ARLINGTON HEIGHTS
ATTENTION: ELAINE PlLTZ
IL
INFORMATION TELEPHONE:
COMPOSITES:
GGG~§~3~ POLYMERS: ~-8G~-~88-5§~1
TRANSPORTATION EMERGENCY TELEPHONE (CHEMTREC): 1-see-q2~-93ee
ccP oertlf;es that its products comply uith all the provisions of the
Toxic Substances Control Rct (TSCfl)~ unless otheruise otatsd by
ingredient in Section II.
*** The percent by uelght composition data ~iven in Sections II ***
*** and >O4 are NOT SPECIFICATIONS! but are based on 'tarj~et~ ***
*** formula values for each ingredient in the product. The data
are greeented es ranges for Iou hazard in~redlenta ~nd ainKle
~** point values for ingredients of regulatory concern. Actual
*** batch concentrations ui II vary within limits consistent uith ***
*** separat.el.y established product, s.p~c~f!c.at ions.
Pa e
* COOK COWPOSITES RND POLYWERS CO. *
* MATERIAL SAFETY DRTR SHEET
SECTION II INGREDIENTS
EXPOSURE LI~IT:
ACGIH TLV/~WA:
ACGIH TLV/STEL:
OSHR PEL/TWA:
OSHR PEL/CEILING:
OSHR PEL/STEL:
LD5e, 0ral;
LOSe, Dermal:
OTHER:
OTHER LIMITS:
CAS# eeeeRe-6z-6
METHYL METHACRYLATE
PCT BY WT: 3e.eRee VAPOR PRESSURE: zs.eee WMHG @ 68F
EXPOSURE LIMIT:
ACGIH TLV/TWA: lee PPW (~e WG/CU.W.}
OSHA PEL/TWR: ~ee ppu (~e Me/cu.a.)
LDSe, Oral: 7.9 G/KG (BAT)
LDS~, Dermal: 35.5 G/KB (RABBIT}
LCSe, Inhalation: >12,50e PPW/e. SH (RAT)
STYRENE ~ONOMER
PCT BT ~T: 37.9960 VAPOR PRESSURE: ~.50G MMHG ~ G8F
~GG PPM (8 HR TWA
)
ACCEPTABLE WAX. PERK: see PPM (5 MIN IN FLINT 3 HAS}
ACCEPTABLE CONCENTRATION: zee PPW (15 WIN TWA)
~.37 G/KG (RAT)
>5 G/KG (RABBIT)
LCLO: seee PPW/8H (RAT)
IARC - Group ZB See Section V OTHER HEALTH HAZARDS:
UNSATURATED POLYESTER RESIN
ON TSO~ INVENTORY OAS# PROPRIETARY
~X~OSU~E LIWIT:
ACGIH TLV/~IdA: NONE ESTABLISHED
OSHA P~L/TW~: NONE ESTABLISHED
This product contains one or more reported carcinogens or suspected
oarolno~ens ~hioh are noted NTP, IARC, or OSH~-Z in the appropriate
OTHER LIWIT~: ~ubsection above.
Page 3 of 8
* COOK COMPOSITES RND POLYMERS CO.
* MATERIRL SRFETY DRTR SHEET
* e~eNglgKCBZ
SECTION III PHYSICAL DATA
Bollin~ Ren6e: Hl~h- -N/R F Low- ZlA.e F
Vapor Pressure: Bee Section II
Theoretical Weight per Gallon~ Calculated: 8.5989 LB/GL
Theoretical Specific Gravity~ Calculated: 3.083
Maximum Theoretical VDC, Calculated: ~.A§7 LB/GL
--If appl ieable , see Sect ion IX for further VDC informat ion--
Physical State: LIQUID
Appearanoe: PURPLISH BLUE HRZY
Oder: STYRENE-ACRYLIC
Odor Threshold:
pH:
Freezing Point: -N/R
~ater Solubility:
CoeffioSent of ~ater/Oil
~eehan;eal Impact Explosion:
Static Electricity Explosion:
Distribution:
-N/A
-Nt~
-N/A
* COOK COMPOSITES RNO POLYMERS CO.
* MRTERIRL SRFETY DRTR SHEET
* e~e~9~gKCB2
SECTION IV FIRE liND EXPLOSION HRZARD DATA
FLRMMRBZLIT¥ CHRRACTERZSTICS:
Lowest Closed Cup Fleshpoint: 53.e de, roes F
For Flash Points Z3 to 73 de~. F.
OSHA Flammability ClassiFication: Class
DOT Flammability ClassiFication: Flammable Liquid
Lower Fish, noble Limit in Rir: Lower- 1.1 % by volume
For Flash Points 73 to lee de~. F.
DSHR Flammability Classification: Class IC
DOT Flammability Classification: Flammable Liquid
DOT Shippin~ Name:
Flash Points Z3 to 73 de~. F. = RESIN SOLUTION, 3~ UN~B66, PG II
Flash Points 73 to ~ee de~. F. = RESIN SOLUTION, 3, LIN~866, PG III
EXTINGUISHING MEDIA:
Foam, carbon d~oxlde, dry ohemical, sater fo~.
UNUSUAL FIRE AND EXPLOSION HAZRRDS:
[£ pelymerlzatlon takes place in e container, there is posslbilit~
violent rupture of the container. Vapors are uninhibited and may form
polymers i vent r flame arrestors o~ storage tanks result!n~ in
stoppage o~ vent~ o
· Vapors may cause ¢lash fire. Keep containers
tightly closed and isolate ~rom heat, electrical equipment, sparks and
flame. Never use ueldin~ or cuttin~ toroh on or near drum (even empty)
because product (even just residue) can 16hire explosively.
SPECIRL FIRE FIGHTING PROCEDURES:
Full proteotive equipment includin~ self-contained breathin¢ apparatus
should be used. ~eter spray may be lnefCective. I~ ueter is used,
nozzles are preferable. 8ater may be used to cool closed containers to
prevent pressure build-up and possible euto-i~nit ion or explosion uhen
exposed to extreme heat.
RODITIONRL TRIqNGPORTRTION INFOR~ATION: Freight Classi¢icatlon:
N~FC: ]q998e/SU8 2 RESIN COMPOUNDS, LIQUID LTL CLRSS 55
Page 5 of 8
* COOK C0~POSITES RNa POLY~ERS CO.
* WRTERIRL SRFETY DRT~ ~HEET
* e~eq9~9KCBZ
SECTION V HEALTH H~Z~RD DRT~
~FFECTS OF ~XCE~SIVE OVEREXPOSURE. PRIMRR¥ ROUTES OF ENTRY RRE:
EYE OONTRCT:
Irritation. Symptoms are ~earin~, redness and discomfort.
SKIN CONTRCT;
Irritatlon. Can cause defattin~ o~ skin ~hich may lead to dermatitis.
INHRLRTZDN:
Irr~tatlon to nose and threat. Extended or repeated exposure to can-
cantrations above the recon~endad exposure limits may cause brain or
nervous system depression, elth symptoms such as dizziness, headache
or nausea end if continued indefinitely, loss of consciousness= liver
and kidney damage.
Reports have associated repeated and prolonged occupational over-
exposure to solvents ~ith permanent brain end nervous system dameEe.
INGESTION:
May cause mouth, throat, esophagus and stomach irritation, nausea,
vomiting and diarrhea. Rspiration into lun~s can cause pneumonitls
~hich can be fatal.
MEDICRL COND;T~0NS THRT MRY BE RGGRRVRTED BY EXPOSURE TO THIS PRODUCT.
Preexlstin~ eye~ skin= I iver~ kidney end respiratory disorders.
EMERBENBY FiND FIRST R[D PROCEDURES:
In case of eye contact, flush immediately ~;th plenty of ~ater for at
least $5 minutes and Eot medical attention; ~o skln~ h thorou;hl~
uith soap and ~ater. [f affected by inhalatio~
of vapors or spray m~st,
remove to fresh air. %f sualloued~ ~et medical attention immediately.
C~L%FORN%~ PROPOSITION ~5 INFORMATION:
~RRNZNG - This product c~ntains chemicals knoun to the State of California to cause cancer.
OTHER HERLTH HRZRRDS:
STYRENE MONOMER
The Znternatlcnal R~ency for Research on Cancer (%~RC). has reclassified
styrene as Group 2B "possibly ~arcinoEenlo to humans". This neu
clefsificatlon is not based on naa health data ralatin~ to either
humans or animals, but on a change in the IRRC classlf~catlon system.
The Styrene Information and Research Canto does not e~ree ulth the
reclassification and has published the fol?ouinE statement. "Recently
ublished studies tracln~ 5e~eee uorkera exposed to high occupational
evels of styrene over a per~od of q5 years shooed no assooiation
betueen styrene and :encer~ no increase in cancer amonE styren?
uorkers (as opposed to the average amon~ all uorkers),-and no ,norease
in mortality related to styrene."
An Increased incidence of lunE tumors oas observed in mice fram a recent
inhalation study. The relevance of this findin~ is uncertain. Data
from other Ion~-term animal studies and from epidemiolo~y studies of
uorkers exposes to styrene do not provide a basis to conclude that
¢t~rene is carcinogenic.
Lun~ effect~ have been observed in the mouse follo~in~ repeated exposure
to styrene.
Page
* COOK COMPOSITES RND POLYMERS CO.
* WRTERIRL SAFETY DRTR SHEET
* eqeqS~ 9KCBZ
STABILITY: Stable HRZRRDOUS POLYMERIZATION: May occur.
CONDITIONS TO RVOID:
Elevated temperatures.
INCOWPRTRBILITY (MATERIALS TO RVOID):
0xldizers, peroxides, strong acids, aluminum chloride and vinyl polymers
HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition or combustion can produce fumes containlnE organic
acids, carbon dlox;de and carbon monoxide.
SECTION VII SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED DR SPILLED:
Remove all sources of iEnition (flames, hot surfacea~ and electrical,
static, or frictional sparks}. Avoid breathing vapors. Ventilate area.
Contain and remove with inert absorbent and non-sperkinB tools.
WASTE DISPOSRL METHOD:
Dispose of in accordance ~ith local, state and federal regulations. Do
not incinerate closed containers. Incinerate in approved facility.
SECTION VIII SPEOIRL PROTECTION INFORMATION
RESPIRRTORY PROTECTION:
Do not breathe vapors. Wear an appropriate, properly fitted respirator
(NIDSH/MSHR approved) durin~ use of this product until vapors ara ex-
hausted, unless air monitormng demonstrates vapor levels are below
appl!cable limits. Follow respirator manufacturer's directions for
respirator use. Observe 0SHR Standard 29CFR ~Ble.~@~.
VENTILATION:
Provide ~enaral clean air dilution or local exhaust ventilation in
volume and pattern to keep the air contaminant eonoentratlan below the
Io~er explosion limit and belo~ current applicable exposure limits.
Refer to DSHR Standard lS]e.9~.
NOTE:
Heavy solvent vapors should, be removed from Icier levels of the uork
area and all I;nition sources (nonexplosion-proof motors~ etc.)
should be eliminated.
PROTECTIVE GLOVES:
Use solvent impermeable ~loves to avoid contact $ith product.
EYE PROTECTION;
Do net ~et in eyes. Use safety eye,ear with splash ~uards or side
shields~ chemical ~o~les~ ~ace shields.
OTHER PROTECTIVE EQUIPMENT:
Avoid contact uith skin.
contaminated clothing.
before reuse.
Use protective clothing. Prevent contact ~ith
Wash contaminated clothin~ includin~ shoes~
* COOK COMPOSITES P, ND POLYMERS CO.
* MATERIAL SAFETY DATA SHEET
* e404959KCB2
SECTION IX SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
Do not store above 3ce deg. F. Store le{~e quantities in buildin~s
designed to comply.$ith OSHA 19la.la6. Keep away from heat, sparks and
flame. Keep contalner~ closed ~hen nat in use and upright to prevent
leakage.
OTHER PRECAUTIONS:
Containers should be ~rounded ~han pouring. Do not ta~e internally.
~ash hands after usln~ and before smokln~ or eating. Emptied containers
may retain hazardous residue and explosive vapors. Keep away from haat~
sparks and flames. Do not out, puncture or weld on or near emptied con-
tainers. Folle~ ell hazard precautions ~iven in this date sheet until
container is thorou&hly cleaned or destroyed.
KEEP OUT OF REACH OF CHILDREN FOR INDUSTRIAL U~E ONLY
...........SECTION XX Sere Title III Information
SARA 313 INFORNATION:
This product contains the roi IoulnE substances subject ~o the
reportln~ requirements of Seotlon ~13of Title III of the Superfund
Amendments and Reeuthorizetion Act of 1~86 end qO OFR Part
~ETHYL METHACRYLRTE
CAS# eeeeee-6z-6 PCT BY ~T: ~e.eeee
STYRENE aONOMER
eee~ee-4z-~ PCT BY aT: 37.BB6e
Pa~e 8 of S
COOK COMPOSITES 9ND POLYMERS CO. *
MRTERI~L S~FETY D~T~ SHEET ~
*
DISGLAIWER AND LIMITATION OE LIABILITY
The products ~old hereunder shell meet Sellar'~ applicable ~peciflcations
at the time of shipment. Seller's specifications may be subject to ohan~e
at en~ time uithout notice to Buyer. Buyer must ~lve Seller notice in
~riting of any alleged defect covered by this uarranty (toEether ~ith all
of puro6ase) ulthln thirty ( day~ of the date shipment o .he produot
r prior to the ex iretion of the shipment's quelit life, uhichever occurs
irst. THE ~RRRI:~I.Y DESCRIBED HEREIN SHRLL BE IN L.EU OF RNY OTHER
~RRRRNTY, EXPRESS DR IMPLIED, INCLUDING BUT NOT LIMITED TO. RNY [MPLIED
~RRRRNTY OF HERCHRNTRBILITY OF FITNESS FOR R PRRTICULRR PURPOSE. THERE
RRE NO ~RRRRNTIES THAT EXTEND BEYOND THE DESCRIPTION OF THE FRCE HEREOF.
The Buyer's sole end exclusive remedy a~einst Seller shall be for the
replaoement of the produot or refund of the purchase price in the event
that a defective condition of the product should be found to exist b
Seller. NO OTHER REMEDY ([NCLUDING, BUT NOT L[~ITED TO, INC[DENTRL OR
CDNSE~UENTIRL DRMRGES FOR LOST PROFITS. LOST SRLES, INJURY TO PERSON OR
PROPERTY, OR ~NY OTHER INCIDENTRL OR CONSE~UENTIRL LOSS} SHRLL BE RVR[LRBLE
TO THE BUYER.
The sole purpose of this exclusive remedy shall be to p~ovide Buyer ~ith
replacement of the product or refund of the purchase price of the product
if an~ defect in materiel or uorkmunshi~ is found to exist Thi~ exclusive
remedy shall not be deemed to have failed its essential purposeoo Ion~ as
Seller is uillin~ and able to replace the defective products or refund the
purohase pries.
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Chemicals
MATERIAL SAFETY DATA SHEE"f
PAGE 1
MSDS NO. 11-076289
SECTION '1. CHEMICAL PRODUCT AND COMPANY INFORMATION
PRODUCT NAME
Cadox M-50a
SYNONYM
MEKP
CAS #
MIXTURE
MANUFACTURERS NAME
Akzo Nobel Chemicals Inc.
ADDRESS
300 South Riverside Plaza
Chicago, IL 60606
COUNTRY
USA
PRODUCT USE
Polymerization initiator
ISSUE DATE
2/12/1997
CHEMICAL NAME
Methyl ethyl ketone peroxide in solution
CHEMICAL FORMULA
Mixture
CHEMICAL FAMILY
Organic peroxides/ketone peroxides
PRODUCT/TECHNICAL INFORMATION
1-800-828-7929
MEDICAL/HANDLING EMERGENCY
1-914-693-6946
TRANSPORTATION EMERGENCY
CHEMTREC 1-800-424-9300
REVISION DATE
2/25/1998
REVISION NO.
OO6
SECTION 2. COMPOSITION/INFORMATION ON INGREDIENTS
SUBSTANCE DESCRIPTION
PERCENT
CAS#
Methyl ethyl ketone peroxide (MEKP)
Hydrogen peroxide
2,2,4-Trimet hylpentanediol-1,3-diisobutyrate
Water
30.000- 35.000
0.001- 3.000
50.000- 70.000
0.001- 2.000
1338-23-4
7722-84-1
6846-50-0
7732-18-5
SECTION 3. HAZARDSIDENTIFICATION
Appeamnce & Odor
Clear, colorless liquid with a faint ketone odor.
STATEMENT OF HAZARDS DANGER!
ORGANIC PEROXIDE.
HEAT OR CONTAMINATION MAY CAUSE HAZARDOUS DECOMPOSITION.
CAUSES SEVERE EYE AND SKIN BURNS.
CAUSES RESPIRATORY TRACT IRRITATION.
COMBUSTIBLE LIQUID AND VAPORS.
Fire & Explosion Hazards
This product is a combustible liquid. Peroxides and peroxide
decomposition products are flammable and can ignite with explosive
force if confined.
Prima~ Route ofExposure
Skin and eye contact and inhalation of vapor are the principal
routes of exposure to this product.
Inhalation Acute Exposure
Inhalation of vapor, mist or aerosol is expected to be severely
irritating to the respiratory tract.
DATE PRINTED: 06/22/1999
Akzo Nobel Chemicals I~
MATERIAL SAFETY DATA SHEET
Cadox M-50a
SECTION 3. HAZARDS IDENTIFICATION
(CONTINUED)
PAGE 2
MSDS NO. 11-076289
Skin Contact - ACUTE
Skin contact can cause chemical burns with severe blistering.
Eyecontact-ACUTE
Direct eye contact with this chemical can cause an immediate severe
reaction and may result in loss of functional vision in the involved
eye. Use of fully protective goggles is essential when using this
product.
Ingestion-ACUTE
If swallowed, this material can cause severe irritation or burns of
the mouth, throat, esophagus and stomach.
CARCINOGENICITY
IARC .... NO OSHA .... NO
NTP .... NO ACGIH .... NO
SECTION 4. FIRST AID MEASURES
Inhalation FirstAid
Remove to fresh air. If breathing becomes difficult, oxygen may be
given, preferably with a physician's advice. If not breathing, give
artificial respiration. Get medical attention.
Skin Contact-FirstAid
Immediately remove contaminated clothing and shoes. Wash skin with
soap and plenty of water for at least 15 minutes. Do not attempt to
neutralize with chemical agents. Get medical attention. Wash
contaminated clothing before reuse. Destroy contaminated shoes.
Eye Contact-FirstAid
Immediately flush eyes with large quantities, of running water for a
minimum of 15 minutes. If the victim is wearing contact lenses,
remove them. Take care not to contaminate the victim's healthy
skin and eyes. Hold the eyelids apart during the flushing to ensure
rinsing of the entire surface of the eye and lids. DO NOT let
victim rub eye(s). Do not attempt to neutralize with chemical
agents. Get medical attention immediately. Oils or ointments
should not be used at this time. Continue flushing for an
additional 15 minutes if a physician is not immediately available.
Ingestion-FirstAid
Do NOT induce vomiting. Call a physician or a poison control center
immediately. Give victim plenty of water to drink. Never give
anything by mouth to an unconscious or convulsing person. Get
medical attention immediately.
Medicalconditionsagg~vated
Persons with pre-existing skin and/or respiratory disease may be at
increased risk if exposed to this material.
Noteto Physician
Methyl ethyl ketone peroxide is severly corrosive to the eyes and
may cause delayed keratitis. The normally prescribed 15 minute eye
irrigation after exposure may be difficult because of the severe
pain. The prior installation of a topical ocular anesthetic is
essential to facilitate a comprehensive ocular lavage.
Swallowing of this corrosive material may result in severe
ulceration, inflammation, and possible perforation of the upper
alimentary tract, with hemorrahage and fluid loss. Aspiratio9 9f
this product during induced emesls can result in severe lung ln}ury.
If evacuation of the stomach is necessary, use method least likely
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Chemicals Int
MATERIAL SAFETY DATA SHE
PAGE 3
MSDS NO. 11-076289
SECTION 4. FIRSTAID MEASURES (CONTINUED)
to cause aspiration, such as gastric lavage after endotracheal
intubation. Contact a Poison Control Center for additional treatment
information.
SECTION 5. FIRE FIGHTING MEASURES
FLASH POINT
179.60 F 82.00 C
FLASH METHOD
Setaflash Closed Cup
AUTO IGNITION TEMPERATURE
N/D F N/D C
UPPER EXPLOSION LIMIT
N/D
LOWER EXPLOSION LIMIT
N/D
E~inquishing Media
Use water fog, dry chemical, carbon dioxide, or foam extinguishing
agents.
Extinguish large fires with large amounts of water spray, fog or
foam from a safe/protected position.
Fim Fighting Procedums
As in any fire, prevent human exposure to fire, smoke, fumes or
products of combustion. Evacuate non-essential personnel from the
fire area. Firefighters should wear full-face, self-contained
breathing apparatus and impervious protective clothing. If pos-
sible, move containers from the fire area. If not leaking, keep
fire exposed containers cool with a water fog or spray to prevent
rupture due to excessive heat. High pressure water may spread prod-
uct from broken containers increasing contamination or fire hazard.
Contaminated buildings, areas and equipment must not be used until
they are properly decontaminated. Dike fire water for later dispos-
al. Do not allow contaminated water to enter waterways.
Fire & Explosion Hazards
This product is a combustible liquid. Peroxides and peroxide
decomposition products are flammable and can ignite with explosive
force if confined.
OtherFire+ Explosion Hazards
This product can produce flammable vapors which may travel to a
source of ignition and flash back.
Hazardous Products/Combustion
Thermal decomposition products may include carbon dioxide, water,
acetic acid, formic acid, propionic acid, methyl ethyl ketone and
flammable gases and vapors.
NFPA HEALTH RATING
3
NFPA FLAMMABILITY RATING
2
NFPA REACTIVITY RATING NFPA OTHER
2
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Chemicals
MATERIAL SAFETY DATA SHE
PAGE 4
MSDS NO. 11-076289
SECTION 6. ACCIDENTAL RELEASE MEASURES
C~eanup
Remove all sources of ignition from the spill area. Stop source of
spill. If tools are needed, they should be non-sparking. Dike
area to prevent spill from spreading.
Evacuate all non-essential personnel upwind. Any person entering an
area of a significant spill or of an unknown concentration of a gas
or a vapor should use a NIOSH-approved, positive-pressure/pressure-
demand, self-contained breathing apparatus. Protective equipment to
prevent skin and eye contact should be worn.
Soak up spilled material with a suitable absorbent such as clay, sand
or earth. Sweep up absorbed material and place in a chemical
waste container for disposal.
SECTION 7. HANDLING AND STORAGE
Handling
Wear protective clothing when handling this product to avoid eye and
skin contact. Wash thoroughly after handling.
Electrically grounded tanks and containers should always be used as
should non-sparking, electrically grounded hand tools and
appliances. Ground or bond to ground all vessels when transferring
to prevent the accumulation of static electricity. See National
Electric Code.
Emptied container may retain product residues. Follow all warnings
and precautions even after container is emptied.
Storage
To insure product quality, storage temperatures should not exceed
MAXIMUM STORAGE TEMPERATURE shown below.
To prevent possible self-accelerating decomposition, temperatures
in the storage facility must not exceed 131F (55 C).
Keep containers tightly closed. Store away from amines, acids
alkalis and heavy metal compounds (e.g. driers, metal soaps and
accelerators).
MAXIMUM STORAGE TEMPERATURE
86.00 F 30.00 C
(to maintain product quality)
GenemlComments
Containers should not be opened until ready for use.
non-sparking equipment and tools when handling.
Use clean
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Respimto~ protection
Use a NIOSH-approved organic vapor respirator with dust, mist and
fume filters to reduce potential for inhalation exposure if use
conditions generate vapor, mist or aerosol and adequate ventilation
(e.g., outdoor or well-ventilated area) is not available. Where
exposure potential necessitates a higher level of protection, use a
NiOSH-approved, positive-pressure/pressure-demand, air-supplied
respirator.
When using respirator cartridges or canisters, they must be changed
frequently (following each use or at the end of the workshift) to
assure breakthrough exposure does not occur.
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Chemicals Int
MATERIAL SAFETY DATA SHE
PAGE 5
MSDS NO. 11-076289
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
(CONTINUED)
Skin Protection
Skin contact with liquid or its aerosol must be prevented through
the use of permeation resistant clothing, gloves and footwear.
Unprotected skin exposed to vapor, aerosol or mist must be thorough-
ly washed before eating, drinking, smoking and at the end of the
workshift.
Eye Protection
Because eye contact with this product may cause burns and possibly
permanent damage, chemical goggles and/or a full face shield must be
worn whenever handling this product.
Ventil~ion protection
Local exhaust ventilation, enclosed system design, continuous moni-
toring devices, process isolation and remote control are traditional
exposure control techniques which may be used to effectively mini-
mize employee exposure.
OtherProtection
Safety showers, with quick opening valves which stay open, and eye
wash fountains, or other means of washing the eyes with a gentle
flow of cool to tepid tap water, should be readily available in all
areas where this material is handled or stored. Water should be
supplied through insulated and heat-traced lines to prevent freeze-
ups in cold weather.
APPLICABLE EXPOSURE LIMITS
Available exposure limits applicable to this product are shown
below.
EXPOSURE LIMITS/REGULATORYINFORMATION
(IN MG/M3)
SUBSTANCE DESCRIPTION
REG. AGCY PEL TLV TWA STEL CEIL
Methyl ethyl ketone peroxide (MEKP)
OSHA N/D N/D N/D N/D N/D
ACGIH N/D N/D N/D N/D 1.5000
NIOSH N/D N/D N/D N/D 1.5000
SUPPLIER N/D N/D N/D N/D N/D
Hydrogen peroxide
OSHA 1.4000 N/D N/D N/D N/D
ACGIH N/D 1.4000 N/D N/D N/D
NIOSH N/D N/D 1.4000 N/D N/D
SUPPLIER N/D N/D N/D N/D N/D
2,2,4-Trimethylpentanediol-l,3-diisobutyrate
OSHA N/D N/D N/D N/D N/D
ACGIH N/D N/D N/D N/D N/D
NIOSH N/D N/D N/D N/D N/D
SUPPLIER N/D N/D N/D N/D N/D
Water
OSHA N/D N/D N/D N/D N/D
ACGIH N/D N/D N/D N/D N/D
NIOSH N/D N/D N/D N/D N/D
SUPPLIER N/D N/D N/D N/D N/D
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Che~icals,IE~
MATERIAL SAFETY DATA ~H
PAGE
MSDS
NO.
6
11-076289
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
(CONTINUED)
LEGEND:
EXPOSURELIMITDESCRIPTIONS
CEIL Ceiling Exposure Limit
PEL Permissible Exposure Limit
STEL Short Term Exposure Limit
TLV Threshold Limit Value
TWA Time Weighted Average
N/D = Not Determined
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
VAPOR PRESSURE (mm Hg)
N/D
VAPOR DENSITY (Air = 1.0)
N/D
EVAPORATION RATE
N/D
VOLATILE %
N/D
BOLLING POINT
N/D F N/D C
ODOR THRESHOLD (ppm)
N/D
SPECIFIC GRAVITY
1.0 @ 20 deg C (68 deg F)
SOLUBILITY IN WATER
N/D
BULK DENSITY
N/D
SOLUBILITY IN OTHER SOLVENTS
COEFFICIENT OF OIL/WATER
N/D
POUR POINT
N/D F N/D C
MELTING POINT
N/D F N/D C
pH FACTOR
N/D
CLOUD POINT
N/D F N/D C
FLASH POINT
179.60 F 82.00 C
FLASH METHOD
Setaflash Closed Cup
LOWER EXPLOSION LIMIT
N/D
UPPER EXPLOSION LIMIT
N/D
AUTO IGNITION TEMPERATURE
N/D F N/D C
Other
SADT = 140 F (60 C) (See Sect. 10).
SECTION 10. STABILITY AND REACTIVITY
Stability
This product is stable at temperatures up to 131 F (55 C).
Incompatibilities
Avoid contact with strong acids, strong alkalis, strong
accelerators and reducing agents.
oxidizers,
Polymerization
Hazardous polymerization is
temperatures and pressures.
not expected to occur under
normal
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Chemicals In~
MATERIAL SAFETY DATA SHE
PAGE 7
MSDS NO. 11-076289
SECTION 10. STABILITY AND REACTIVITY
(CONTINUED)
Decomposition
Decomposition products include carbon dioxide, carbon monoxide,
ethane and methane.
Conditionsto Avoid
Hazardous and uncontrollable decomposition may occur if this product
is exposed to temperatures above 131 F (55 C). This temperature is
based on the Self-Accelerating Decomposition Temperature (SADT).
The SADT is an experimentally derived temperature at which a typical
package of the product will undergo self-accelerating decomposition.
For this product, the SADT is 140 F (60 C).
SECTION II. TOXlCOLOGICALINFORMATION
Toxicological-Inhalation
Inhalation toxicity data is not available for this product. However,
the acute LC50 for a similar product is 17.0 mg/L in rats
(4 hr exposure).
Inhal~ion Chronic Exposum
Prolonged and/or repeated inhalation is expected to be severely
irritating to the respiratory system.
Toxicological-Dermal
Dermal toxicity data is not available for this product. However,
the dermal LD50 for a similar product is 4000 mg/kg in rabbits.
A similar product was corrosive to albino rabbits after a 4 hour
occlusive contact.
Skin Contact-CHRONIC
Chronic dermal exposure effects for this product are not known.
In a 13-week study conducted by the NTP, a similar product was
administered topically for 5 days per week to rats at doses of 1.07
to 107 mg/rat and to mice at doses of 0.357 to 35.7 mg/mouse. Necro-
sis, inflammation, and epidermal hyperplasia were observed in both
species. Since toxicity was seen at all dose levels, a no-observed
adverse-effect level could not be determined in this study. The
results of this study suggest that a similar product does not
become systemically available and the primary toxicity associated
with contact to this chemical is limited to the application site.
Toxicological-Eye
This product can be expected to be corrosive to eyes based upon
tests with a similar product.
Toxicological-Ingestion
Ingestion toxicity data is not available for this product. However,
the acute oral LD50 for a similar product is 1017 mg/kg in rats
(moderately toxic). The acute oral LD50 for a component of this
product is greater than 3200 mg/kg in rats (slightly to practically
non-toxic).
Ingestion-CHRONIC
Chronic ingestion effects of this product are not known.
A component of this product was administered in the diet of rats
(103 days) and dogs (90 days). The NOAEL for both species was a 1%
concentration (highest dose tested).
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Chemicals
MATERIAL SAFETY DATA SH!
PAGE 8
MSDS NO. 11-076289
SECTION 11. TOXICOLOGICAL INFORMATION
(CONTINUED)
CARCINOGENICITY/MUTAGENICITY
This product is not classified as a carcinogen by IARC, NTP, OSHA
or ACGIH.
There is no mutagenicity data for this product, however, information
is available for a similar product. Four in vitro mutagenicity
assays were conducted by the NTP in the presence and
absence of metabolic activation. The similar product was not
mutagenic in the Ames test. It was mutagenic in mouse lymphoma
cells without metabolic activation and induced sister chromatid
exchanges and chromosomal aberrations in Chinese hamster ovary cells
in the presence and absence of metabolic activation. In the
13-week dermal study in mice, no increase in micronucleated
erythrocytes was seen in peripheral blood samples obtained at the
end of the study.
REPRODUCTIVE EFFECTS
The reproductive toxicity of this product is not known.
NEUROTOXlCITY
The neurotoxic effects of this product are not known.
OtherToxicologicalEffects
No other toxic effects for this product are known.
TargetOrgans
Exposure to this product may affect the skin, eyes, respiratory
system and digestive system.
SECTION 12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
The ecological toxicity of this product is not known.
DISTRIBUTION
Other ecological information on this product is not known.
CHEMICAL FATE
This product is expected to be readily biodegradable.
SECTION 13. DISPOSAL CONSIDERATIONS
Waste Disposal
This unused product is listed by the EPA hazardous waste number U160
(MEKP) and meets the EPA hazardous waste definitions for the
characteristics of reactivity (D003) and corrosivity (D002).
It is the responsibility of the waste generator to evaluate whether
the waste meets EPA's definition of hazardous waste by
characteristic or listing. Dispose of in accordance with all local,
state and federal regulations.
CONTAINER DISPOSAL
Containers should be drained of residual product before disposal.
Empty containers should be disposed of in accordance with all
applicable laws and regulations.
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Chemicals In~
MATERIAL SAFETY DATA SHEE~
PAGE 9
MSDS NO. 11-076289
SECTION 14. TRANSPORT INFORMATION
SHIPPING DESCRIPTION
ORGANIC PEROXIDE TYPE E, LIQUID
(METHYL ETHYL KETONE PEROXIDE, <=40%)
5.2, UN3107, PG II
NORTH AMERICAN EMERGENCY RESPONSE GUIDE NO.: 145
REQUIRED LABELS
ORGANIC PEROXIDE.
ENVIRON. HAZARDOUS SUBSTANCE
This product contains methyl ethyl ketone peroxide (RQ=10 lbs.)
which is an environmentally hazardous substance per 49 CFR 172.101,
Appendix A.
SECTION 15. REGULATORY INFORMATION
Component Methyl ethyl ketone peroxide (MEKP) is subject to the following
Enviromental List
CERCLA
DSL
MA. LIST
NJ R-T-K
PA. LIST
TSCA
CERCLA Hazardous Substances
Domestic Substance List-Canada
Massachusetts Substance List
New Jersey R-T-K Hazard. Sub.
Penn. Hazardous Substance List
Toxic Subst. Cont. Act -listed
Component Hydrogen peroxide is subject to the following
Enviromental List
DSL
MA. LIST
NJ R-T-K
PA. LIST
SARA 302
TSCA
Domestic Substance List-Canada
Massachusetts Substance List
New Jersey R-T-K Hazard. Sub.
Penn. Hazardous Substance List
SARA Title III, Section 302
Toxic Subst. Cont. Act -listed
Component 2,2,4-Trimethylpentanediol-l,3-diisobutyrate is subject to the following
Enviromental List
DSL
TSCA
Domestic Substance List-Canada
Toxic Subst. Cont. Act -listed
DATE PRINTED: 06/22/1999
Cadox M-50a
Akzo Nobel Chemicals
MATERIAL SAFETY DATA SHE]
PAGE 10
MSDS NO. 11-076289
SECTION 15. REGULATORY INFORMATION
(CONTINUED)
Component Water is subject to the following
Enviromental List
DSL
TSCA
Domestic Substance List-Canada
Toxic Subst. Cont. Act -listed
OTHER REGULATORYINFORMATION
No other regulatory information is available on this product.
WHMISHAZARDCLASS
B-3,C,E,F
HAZARD RATING SOURCE
HMIS
HEALTH REACTIVITY
3 2
FLAMMABILITY OTHER
2
SECTION 16. OTHER INFORMATION
OTHER INFORMATION
CADOX is a registered trademark of Akzo Nobel Chemicals Inc.
CREATED BY
Product Safety 914 674-5000
KEY TO ABBREVIATIONS:
EQ=EQual LT=Less Than GT=Greater Than
AP=APproximately TR=TRace ND=No Data available
All infoIT~atioll concerting this product and/or suggestions for handling and use contaii~ed herein are offered in good faith and are believed to be re~able. Akzo Not)el Chemicals Inc.; ho~vever
makes no warranty as to the accuracy, of and/or sufficiency of such information and/or suggestions, as to the i~roduct's merchantability or fitness for any particular purpose, or that any
suggested use wil~ not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent. Buyer must determine for himself, by
preliminar~ tests or othem, ise, the suitability of this product for his purposes. 'l~e information contained herein supersedes all previously issued bulletins on the subject matter covered.
lliedSig J ai
CH EM£CALS
Allied Signal Inc
P.O. Box 1055
Mon'istown, NJ
973 455 2000
ACETONE
CHEMICAL PRODUCT AND COMPANY IDENTIFICATION '
PRODUCT
PRODL~T USlh
M~NUFA~
ACETONE
Acetone NE, 2-Prol:ranone, Dimethyl Ketone, Dknethylketal, Dimerh¥!/brmaldehyde,
Pyroacettc acid, Pyroacettc ether
Chemical intermedime
101 Columbia Road Box 1139
Morri~town, lqew Je~ey 0796~-1139
~ CASE OF ~G~NC'~ C~3_.
(24 Hours/D~7, 7 Dalm/XVeek)
973-455-2OOO
2. COMPOSITiON/INFORMATION ON INGREDIENTS'
_~GREDIEiWr NAMIe C.auS NLrMBER WEIGHT %
Acetone 67-644 99.7
Trace ;.mpuritics and add/donal material names not listed above may al,~o appear in Section 15 towards the e=d of the MSDS.
These materials may be listed for [ocal "Right-To-Know' compliance and for other rermona.
3. HAZARDS IDENTIFICATION
~M~RG~CY OVERVIEW: Acetone is a colOrless liquid possessing a sweet, pungent odor. It
is a volatile substance, extremely flammable and its vapors form explosive mix!utes with air.
Since acetone vapors travel with air curreu~s, thc~f c~ be ignited by flames and sp~ks ~ loca-
tions remote from the site at which the material is being handled. Dangerous fire hazard when
expo$ed to heat, sparks, J%me or oxidants. Eye, sldLI and mucous membrane irritant. Harmful
if swallowed or inhaled.
MSDS Nnmher YRFI-0003
Current Issue Date July, 1997
' iliedSignal
ACETONE
D~ EFFECTS: Acetone in nat known to produce chrordc or cumulative ~temic effects.
~ent$ found on one of the OSHA. designated carclnol~n Lists a~e listed below.
IN~REDI~iNT NA~IE NTP STATUS IAHC STATUS OSHA LIST
*No ingredients listed in this sect/on'
4. FIRST AID MEASURES~
SKIN: In case of conu~ with skin, immediately wash ftdn with soap and warn- wtnle ~ cc~nar~ dothin~
Obtain medical attention Lf defatting action of acetone came$ skin cracking or dermatitis.
EYES: Ia case of contact with eyes, immediately flush .eyes with plenty/of vazter for at least 15 minutes, ;lifting eyelids
occasionally during flushing to ~acilitate irrigation. Get prompt medical mention,
INHALATION: If inhaled, remove the patient from thc contanlinated atmosphere to fr~h air. If not breathing, give
artificial resp/raflon, preferably mouth-to-mouth. If breathing is difficult, give oxTgerl provided a
qualified openttor is present. Get prompt medical attention.
E~IG~.~rlON: If swallowed, do not induce vomiting ,.mle$~ advised to do $o by a physician. If physician advises vomit-
lng and if patient is conscious, immediately give 2 to 4 glasses of water and induce vomiting by
toucking finger to back of throat. Get prompt medical attention.
ADVICE TO PHYSICIAN:
A. Treatment of severe systemic intoxication (narcosis) from either irapor exposure or ingestion is primarily ~upportive.
Acetone has mlntrllal toxicit]r oll other orgall systeln$ and if the victim can be.supported throu~ tire period of
central nervous system depression and respiratory failure, the prognosis is good.
(1) Following recent ingestion, acetone should be removed by emesis ('if not performed by ~,~¢ue personnel) and/or
gastric hvage.
(2) Mechanically assisted ventilation ma). be necessary..
(3) Lq severe cases, an initial period of hypoglycemia may require correction by intravenous solution$ of dextrose.
(4) In some cases, transient hyperglycemia-resembling diabetes-has occurred during the recovery, phase and lasted for a
few days. Treatment with insulin max- be beneficial but should be used cautiously as ~he condition tends to resolve
over a pe,~od of a few days.
B. E?'e exposures usually do not require any speci/!c treatment if tiquid acetone is promptly washed out of eyes. [f
exposure was pro!onged,, some initial corneal damage may be pre$ent. It/s advis able for these individuals.to be seen
by an Ophthalmologist.
5. FIRE FIGHTING MEASURES
FL.4~SH POINT: 1.4°F (-17°C')
FLASH POINT METHOD: Tag dosed cup
AUTOIGNITION ~ 869'F (495°C)
UPPliR PL~Mll I/M1T (volume. % in air),. 12.8
LOgit FLAME I~llT Cvolume % in air):, 2.5
FL.-XMI! PROPAGATION RA3~ (solids):. Not applicable to llquid~..
OSHA. I:~_AMM. ABIIATY' CI.A..~: Flammable liquid.
EXTINGUISHING M~DIA~
Small fire: U~ carbon dioxide or d_~ chemical.
Large fire: Use polar solvent (alcohol) type foant The typical fireflghdng foams that a~ suitable for Sa~oline
or hydrocarbon fires will break and will not extinguish acetone fires. Water spray will reduce the intensity
Acetone/water solutions have Hash points when the acetone concentration is greater than 8% O:)Y' weight).
The fire point, which is the percent by weight when a ~olution !mstairm a flame, is hil/her than that.
MSDS Number FRFI-0003 Page 2
Current Issue Date July, 1997
L
~lliedSignai
Material 5afe~. Data Sheet
ACETONE
UNUSU.~L ~ AND EXPLOSION HAZARDS:
Acetone is extremely -flammable and its vapors form explosive rnlxv,~c~ with air. Dangerou~ when exposed cc
hear. sparks, Ikanc or oxidant.
SPI~CIAL FIRE FIGHTING PRECAIfrIONSflNSTRUCTION$:
Handle as a very flan-unablc liquid. Use wamr spray to kccp firc-~vposed tankz o_nd containers cool. Do not
mater the ftre area without proper personal protective equipment including serf-contained breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES
IN CASE OF SPILL OR OTHER R~vr.FASE: (Always wear recommended personal protective equipment:)
Eliminate ail sources of isrtition in thc vicinity of spill or released vapors. Isolate the spill area. Permit only
trained personnel wearing full per~nal protective equipment to enter thc spill area. Terminate thc leak imme-
diately, If possible. Collect the spill in a waste container for disposal. Flush the spill area thoroughly with water;
wash contaminated equipment thoroughly with water. Flushings and wash water must be contained, and pre-
vented from entering a waterway. Spills of acetone should be reported to Fcderal, State and Local Environmental
Agencies, including thc National Response Center (800424-8802)..
Spills and releases may have to be 'reported to Federal and/or local authorities. See Section 15 regarding
7. HANDLING AND STORAGE
NORMAL HANDLING: 6~lways wear recommended personal protective equipment.)
Dangerl Extremely flammable. Keep away from heat, sparks and flame. FA¢ctrically ground all handling equil>
meat. Keep container do~d. Do not usc air pre,ute to unload acetone from container. Use adequate ventila-
tion (see Section 8 on Respiratory. Protection).
Observe OSHA regulatiot~ on exposure limits. Avoid prolonged or frcquentl?'- repeated breathing Of vapors.
Avoid prolonged or repeated contac~ with skirl. Wear safer3.' glasses with cup-tTpe shields or chemical goggie~,
face shield, natural rubber or neoprene gloves, hard hat and safety, shoes in normal handling operations.
Whenever handling opm'ations are such that unavoidable gross contact with the liquid is likel}; the handler
should wear ~ protective equipment and clothing comprising chemicaJ goggles, face shield, hard hat, and nat-
ural rubber or neoprene jacket, trousers, gloves and shoes or boots. Wash contaminated clothing. Follow manu-
facturer's recommendation on decontaminating and reusing protection equipment and clothing.
STORAGE REC OMMIEWDATION!~.
Protect container al~dnst physical damage. Store in accordance with OSHA Regulation 29 CI=R 1910.106 in a
cool, weE-ventilated location equipped with autof, aatlc sprinklers or fire extinguishing system. Keep away from
sources of ignition and oxidt~trig matextals.
~F. mpty containers, unless thoroughly clemled, must be assumed to have the same b~rds
as full one~'
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGIlWe. Elt~G coNTRoLS:
Good ventilation is esse.~r.L~ ~ ~ where acetonc is handled m prevent the accumuiatinn of explosive mix:
tures. Explosion-proof Dns should be used in mechanical .type ventilation system& Under rmrmal condi-
tions, thc atmospheric concentration of acetone vapor must be kept Iow enough to prevent irritation of the
mucous membranes and discomfort to the wooers. Under abnormal conditions, such as leaks or spills, sp~
cial emergency equipment may be necec~ry.
(Always'wear reeorm'nended personal protective eu_uipment.~
MSDS Number FRFI-0003
Current Issue Date July', 1997
Page3
c ~ ~ .~ z c ,~ L s ACETONE
~;]~50N~L PRO'~E~ EOtJ-~i~r
SKIN PROTECTION:
HANDS,A1LMS AND BODY: Natural rubber or neoprene gloves. Safety shoes arid hard hat.
EYE PROTECTION:
EYES AND FACE:
Liquid colxtact likely:. Wear safet~ glasses with cup-type $i~ shields or chemical, goggles and face shield.
Vapor contact likely:. We~r personal p~otective equipment cle$cribed under Respiratory Protection.
Contact lenses should not b~ worn where working with this ¢hem/caL
RESPIRATORY PROTI!CTION: '
No respiratory protection required for concentrations <750 ppm~
750 to <1,000 ppm: NIOSH half face approved chemical cartridge respirator with organic ~apor cartridges.
1,000 to <12,500 ppm: NIOSH approved full face cartridge respirator with or~eani¢ vapor cani$ter.
12,500 ppm and above: NIOSH approved full face supplied air respirator operated ill pressure dellland or other
positi~ pre~ur~ mode,
F.$cape: I¢IO$H approved air ptu-if3~. ' g full face respirator with organic vapor c-~ni~ter or a. ny escape type self<on-
rained breathing apparatus.
ADDITIONAL RECO~ATIONS:
OTHER CLOTHINGAND EQUIPMF~NT: Natural rubber or neoprene jacket, trousers and shoes or boo~s. Emergency.
showers, emergency, eye wash fountains and tire blankets. Warning $ig~s. Rubber carrier for glass containers.
~EXPOSURE
IA"gGI~DmNT NAME ACGI~ TLr OSHA PEL OTHER LhMIT
Acetone 750 ppm TWA 1000 ppm TW'A None
1000 ppm STEL No STEL
* -- Limit established byAlliedSiEml
*' = Workplace Environmental Exposure Level {AIHA).
'~ = Biological Exposure Index (ACGII-I).
O~ EXPO61.JI~ LIMI'I'$ FOR tK)TENI~L DECOMIaOS1TION i~RODUCI~
None.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPFARANCE:
PHYSICAL ~
MOLI~CUIAR WEI~IT:
~CAL FORMIJIA:
ODOR:
SF~CIFIC GRAvlirY (water = 1.0):.
SOL~ IN WATER (weight %}.
pH:
Colorless liquid.
Liquid.
58.08
CH3COCH3
Swe~t, pungent odor.
0.79 ~ 20/4'C
Complete.
Approx. 7 (i.e., 1 vol. a~er. one in 1 vol water)
MSDS Number . FRFI-0003
Current Issue Date J'uly, 1997
iliedSignal
BOU~ING POINT:
VAPOR PRESSURE;
VAPOR D~Ze$ITY (air -- 1.0):
EVAPOR~'IION ~
% VO~:
FLASH ¥OINT:
Materfat Safety Data S/~eet
ACETONE
56.2'C
-95.35'C
18l mm Hg @ 20°C
2.0
>7.0 ~OMPARY~ TO: Butyl acetate: 1
~prox. 100~ ~y volume at
1.40F
(~ash poin; mcrttod and additional flammability ct~ :u-e found In S~cdon
10. STABILITY AND REACTIVITY
NOllMM.L¥ STABLF.2 (CONDITIONS TO AVOID):
Normally stable. Keep away from heat, sparks and flame.
INCOMPATIB~:
Avoid strong oxidizing ag,rats,
HAZARDOUS DECOMIND$1TION PRODUCTS:
Complete combustion ce. suits in the formatloa of carbo~ dioxide and water vapor, lacompiete combustion can
yield carbcm monoxide.
ltAZARDOUS POL~ON~
Haza.Mou$ polymerization will not occur.
11. TOXICOLOGICAL INFORMATION
ll~MEDIA.TE (ACtYr~) EFFECTS:
Oral (mouse) LDso = ~,0~ m~kg
O~ CmO ~50 = 5,~ m~kg
Or~ (mbDiO ~0 = 5,340 m~
Eye ~ = 5~ ~pm
S~ (~bit) 5~ m~24 ~ ~on ~.
DIUAYF_.D (SUBC~RONIC A~D Cti1~O~)
No data a~'ailable. Acetone is ~ot known to produce chronic or cumulative .systemic effects.
OTI-II~ DA2A:
BIOLOGICALACTION ~ 270 mg/L in urinc at cud of work shift = c, ccc~$ivc exposure w acetone..
12. ECOLOGICAL INFORMATION
DEGRADABKH'Y:
~.) Biochemical Ox'Tg~ Dem~,~d (BOD~ Lb./Lb,; acclimated ~): 0.31 - 1.63.
b) Chemical Oxyg¢m Demand (COD Lb./Lb.): 1.12 - 2.07.
OCTAZIOtJWATER PARTITION COEFFI~: 0.58.
MSDS Number FRFI~3
Current Issue Date July, 1997
Page 5
~' ' iliedSignai
3taterial Safety Data Street
ACETONE
13. DISPOSAL CONSIDERATIONS
RCR~
Is the unused product an RCRA hazardous waste if discarded? Yes
If yes, the RCRA ID number is: 0002 and D001
OTHTaR DISPOSAL CON$IDI/RATION$~ The waste material should be treated and/or disposed of, at a sltc authorized to
handle hazardous chemical va~ste. Appropriate Federal, State and Local RegulatotyAuthorities should be contacted
befor~ discharge, treatment or disposal of waste material
The information off~t-~l her~ is for the product as shipped. Use and/or akemt[orm ro the product ~uch as mLxing with
other matermls may significantly change the characteristics of the m~terial and alter ~e RCRA classification and the
proper disposalmethod.
TRANSPORT INFORMATION
Class 3 - Flammable IAquid, AppendL, tA C17'2.101~
Aq~tone. ~. UN 1090, PG II. fRO 5000)
US DOT HAZARD CLASS:.
US DOT ID NUb~Im:
PROPER $Eil:?ING DESCRIFrlON:
For additional information on shipping regulations affecting this rrmted~, contact ~e information n~ found in'Section 1.
15. REGULATORY INFORMATION
TO.-~IC SUBST.~uNCES CONTROL ACT (TSCA)
TSCA INVENTORY STATUS:
' O'I'I-~R TSCA I88UE8:
ACe~;0x3e is Hsted on the TSCA inventory,
Subjec~ ro export notification.
SARA TITLE ffl/CERCLA
"Reportable Quantities' (RQ$) and/or 'Threshold Plalanlng Quantities' (TPQs) exist for the following ing~dients.
Acetotle 5000 None
SpilLs or releases resullin~ in the ~ of any ingredient at or above its RQ requires immediate notification
to the Natiomal l~sponse Cedar. [(800) 424-8802] and to your Local Emerge~ plaon!ng Commttuee.
SV-CTION 311 r4A?ARD CLASS: Immefliaze=Yes Delayed=No Fire=Yes Pressure-No Reactive=No
SARA 313 TOXIC cTm~-MXCAL5: .
The following ingredients are SARA 313 "Toxic Chemicals". CAS numbers and weight percents are found in Section 2.
INGREDI2ENT NAM1/
'No ingredients listed M this section.'
MsDS Number. FRFI-0003 Page 6
Current Issue Date July, 1997
~c. · ~, c & ~ ~ ACETONE
· TATE RIGI~.TO- IQX[OXV
In addition to the ingrectients fotmd ~ Section 2, thc following ate li~ted for state rigl-tt.to-kaow purposes.
INGREDIENT NAMIi WEIGHT % COMaMENT
'No ingr~qltenm ~toa in tht$ section.*
ADDITIONAL REGUI.~TORY ~,~FORMA~ON:
Acetone ~ subje~ to the ~ Diversio~ &T~gA~ of 1988 ~d subject to ce~ record keep~g and
~o~g ~enu. ~1 ~ 1310 ~d 1313).
Acetone ~ aot
Ace~ne ~ not on
wrlM/S CZA.~n~/cATION (CANADA):.
cl:g B, Div~ion 2 '
This product has been cla.s$ificd ia accordance with the hazardo~ criteria of the CPR and the MSD$ contains all thc
information required by the CPR
1~ORFAGN II~OHY
Camadian DSL (Dom~:ic Substances List)
I~q/CS ¢i~ropean In~atory of F,x~t/~ Commercial Chemical Substances)
Ausr. galt~n
Japanese Invmtorr
.16. OTHER INFORMATION
CURRF-~ ISSUIi DATE:
PREVIOUS ISSU-E DATE:
May, 1997
February;, 1997
CHANGI!5 TO MSDS FROM PIL~x'NIOUS ~ DATE ~ DUE TO TI~ FOLLOXlrL-NG:
Chrmge made M H~g md Storage (~cfion ~.
Up~t~ ~pos~ Con~raon~ ~te~n (~on
UpdatedT~flo~ ~o~on (Scion 14)
Up.ted R~to~ ~fion O~ 15)
~ INI~ORMATION:
NFI~A ltAZARD RATINGI: I-~0 CH-l:-IO
~ HAZARD RATINGS: 14-0 CH4tP0"
MSDS Number FRFI-0003
Current I.mue Date July, 1997
Rei~-h~_old, Inc.
P.O. ~x /3582
Research Triangle ParK,
MATERIAL SAFETY DATA S~KET
Info--riCh Telephone No. (800) 275-6353
NC 27709
AL~ CHEMICAL ~GENCTES
1-800-424-9300
Effective'Date: '08-11-98 , ~a~e
!SECTION 'I - PRC~UOT IDENTIFICATION
Number: S0022245
Tra~e Name: POLYLIT~(R) 32145-22
P~C C~s= ~at~at~ Pol~s~er
C.A.S. ~: ~
~t~ ~ = 2' Fire = 3 ~tivi~ - I
/ngr~ents CAS # Content Limits
Polyaster resin Progrietaz~ 69.0 % N~ne assi~d
Btyr~n~ Nonc~sr 100-42~5 31.0 % $0.0 ~
S~CTICHq III, P~fSIC~LDATA
Boil/n~ Point: 295 Deg. F. Va~or Density: Heavier e~,, Air.
Volatile %: 31 by weight. Specific Gra~: 1.14
Eras. Rate: Slower ~h~ n-Butyl Acetate.
Appearance: Light blue liquid. ~e~t odor.
S~CTION IV - FIRE A~D EXPLO~IC~ HAZARD DATA
Fl~"~ability Class: lC Flash Point: 89.. De~. F. n~. : 1..1
-~~HING MEDIA:
Class B ext/x~shincj acjen=.
-SPECIAL FIRE~"II~ ,PE'OC~.ES:
Fir?fi~h~ers an~ other~ exposed to vapors or products of
com~tionshoul4wearaelf-containe~breathin~m~arat~s.
m~uip~_.~t should~e ~oro%~hlydecontaminated after use.
-~~ FIRE
At elevatedt~mp~ratures, such as'ina ~ire, polymerization
may take ~lace. If polymerisation takes place in a closed
container, ~b~re is thepo~sibilityofviolentrup~ureof
the cont~{ner. Product vapors may roman ex~losivemlxture
SECTION V-~EAL~HAZA~DDATA
-PK~MISSLBLE EXPOSURE LEVEL:
T~re is no OS~A ~EL or ACGIH TLV .established for the polyester
OSHA P~L and ~ TLV ~or styreue are bot~ 50 D~a for an 8-hour
(~0==.)
1~ Number= 80022245
~£~ec~ve D=~e= 08-1Z-98
SECT~ V - HEALTH HAZARD DATA
Page
-PERMISSIBLE EXPOSURE ~: (co=t.)
Time We£ghte~ Average (TWA). The OSHA and AC~IH ~rt Term
Exposure Level (STEL) are 100 ppm ,for a 1S-minute period.
Expoevre to s~T'~ ma~ exceed the STEL during a
~pez'iod (no ceil~'~g ~oz: bz"~ef exposures), boweve~ the average
-EFFECTS OF OVEREXPOSURe:
SKIN= Prolonged 'or Erequent cc=t~Ct may cause defatt~_.ff a~
dryness cE the skin with resultan= irritation and possible
~_e~vmatitis. Styrene may be absorbed through the sk/n in toxic
EYES: May cause Irr£tatlon. Liquid splashes may result i~
serious injuries. May cause lachr~ti~n (tears).
INB~LATI~: V~pors may cause mucous membrane irritatio~
u~per respiratory tract disoc~for.~,. High c~ncentrati~n~ may
result in headache, nausea, insen~ibili~y a~d oLher central
nervous syst~n effects. Repeated exposure to high c~ncentrations
may cause liver a~ ki~xe~
INGESTIC~: May cause gaetrointest~-al disturbances, pain
d/sc~.m...~0rt.
-FIRST AID:
SKIN: Wash with soap and water.
EXES: Flush w~th COpiOUS a~0~' of water Eot 1~ minutes.
:I~TION= ~ victim fr~n exposure. If victim is un-
conscious, administer artificial, respiration ancl/or cu~2~jen as
needed. Seek medical aid.
INGESTION: DO NOT iNDUCE VC~ITI~. (aspiration hazard). Seek
ialme~ate med/cal aid.
-~ ROUTE(S) OF ,ENTRY~
Inhalation and Skin Abso~l~tion.
-TO~I~CAL INFORMATION:
The International Agency for Rssear0h o~ Cancer (IARC) has
classified st~. as possibly carcinogenic to Mm~nS, (class
2B). The IARC 2B classification is not based on sign~£can= new
evidence ~ha~ s.~rene might be a aa=cinogen, bu~ ~n a revised
IARC class£ficatx~n sc~m~m~e and new ~ata on styrene o~ide.
LD$0 (ORAL/RAT) S ~/KG; LDS0 (DRML/RABBIT) 2820
M~T~PJ=~L SAFET~ ~ATA
Information T~le~hone ~. (800) 275-6353
P.O. ~x 13582 ~ ~~ ~I~
Rese=~ ~i~le P~k, ~ 27709 1-800-424-9300
~DS Number: 80022245
Ef£ective Date: 08-11-198 Page 3
; SECTION VI - ]~'~I%~TY DATA
STABILITY: [ ] Unstable ~ Stable
~ POLYME~/ZATIC~: ~] May occur
- ]~"'OI~ATIB'r~,TTY: ,
Stron~ acld~ ~ ~z~ ~.
[ ] Will not occur
-ST~PS TO BE TAKEN IN CASE MATERIAL IS P~.~S~D OR SpT~.~.~n:
~e ~1 SO~ of i~i~i~. V~la~e ~a. ~b ~ill
wi~ ~ ~sorb~ ~t~ial ~ as s~t, ve~ite or
s~ ~ place ~ a closed ~=~r. If 1~ ~i11, ~e
This material coota~ns tb~ £ollow~ng ingredients which, if
~illed or released in quantities equal to or ~reater than
Reportable ~uantity (R~), are subject to the repo~cin~ require-
Styrene Monc~er ~Q Value = 1000
This materi~l has been teste~ an~ ~ound to have a flaoh
below 140 .F. If discarded, this material a~d con~a.~.~ers ~hould
Be treated as h~-~rdoue wastes baeed on the characteristic o~
i~nitabili~z as defined unaer the federal RC~A re~ulati~ns
(~0 CFR 261). DiSposal of ~s mater~al an~ its c~nta~ner,
=equires compliance with applicable l~belix~, packa~, and
=ecord keep~ s*_~.-~ts. Extreme care shoul~ he ~aken to
ensure ~hat it £,s dlsl~osed o£ only in a £acility permitted ~or
disposal o~ hasax~ous was~es. .
For further xnfo=m~ti~n, co~tact your state or local soli~
agenc~ or the ~mited States Enviroumental Protectio~ Agency's
RCRA bowline (1-.800-&2&-93A6 or 202-382-3000).
MATERIAL SAFET~ DATA BHEET
Informa~£on Tel~bxme No. (800) 275-6353
Reich~old, ~.
P.O. ~ 13582 ~ ~~ ~~CIES
~s~ ~i~le P~k, ~ 27709 1-800-424-9300
MSDS Number~ S0022245
EfEective Date= 08-11-98
S~OTION VIII - SP~ PROTF~3TI~ INFUR~StTION
Page
-RESPI~ATORT PROTECTIC~:
If a TAV or PEL liste~ in sectio~ V o~ this ~ata sheet
Local ven~ilatio~ may be require4. :~lu_-'ing certain
to keep exposure lewels below ~h~ "TLV liste~ in Section
o£ ~-~e ~ata s~eet.
Wear al~rOpriate impervious ~1o~ to prevent sk-~-n contact.
Wear face shield or chemical gc~g .~ee.
Wear ~=oteotiv~ ,clothin~ to prev~t skin contact.
By~ wash static~ ~ saEety sl~w~ s~ul~ ~e available.
, SECTION IX - SI~CIAL PR~JiUTIONS
-PRECAUTIONS TOBETAK~iN~ANDLIN~ AND STORIN~:
&woid stooge a~ove 100 D~. F. Avoid p~l~-~ or re~eat~
skizi c~ntac~. Avo~ 4,h~] atlo~ o£ ~ated vaI~rs or ~raymists.
Avoi~ im~r~ ~R~tion of prc~=~r ~ur Cat~yst. A
and oat~t ~ed with this p~,t should always be mixed
s~arat~y wi~ ~e p~u=ta~m~st never
SP£TION X - ~AL INF0~MATI0~
- ~EG~TOR~ INFORM~TI(H~:
SCA~MD Rule 1162 ms~lis~ ~fic p~cess, c~l,
~us~~, ~ ~co~e~ ~~s ~or
~~ ~ ~lyes~er res~ ~terials. I~ i~ ~
r~~ili~ of ~ f~ricator to ~ c~li=e wi~
~se r~ts.
~: ~S p~ ~~ a ~c~(s) ~ ~0 ~ State
Of Califo~a t~ c~e o~. S~a ~de (~9 96-09-3).
~s ~teri~ ~ ~ oa=~ze~ as ~v~ ~ foll~!n~
~(s) as ~ef~ ~ ~ Ti~ III r~ati~s (~0 ~ 370):
a~e, ~o~=, f~e, ~ti~.
~ Number; ~0022245
EffectiveDate= 08-11-98
SECTION X - SUPPlemENTAL INFORMATION
Page
-SARA SECTION 3Z3 LISTED ZN~REDIENTS:
~~ ~~ts o~ Secti~'..31~ o~ ~ ~ 40 ~ 372
[s~ Sec~i~ II for p~:age of !n~e~= (s)] ~
St~ ~ (~oo-42-s)
PP~PARED BY: Product Safety & C~m~liance D~l~ar~t
Re~.earch Triangle Pa~k, North Carolina 27709
(9~9) 990-7500
Th~$ ~n~0~tion is provided ~n good fa/~h and is ~ec~ ~ t~m ~ of
~ ~ ~ir ~ ~~~ion as ~ ~ s~t~ility o~ ~ p~t ~
~ir ~se prior ~ ~e. Reic~ld ~scla~ ~~~ili~ to d~s of
P~D~ IT DESk,S.
S.
OSS OF MERCHANTABT~,TTy OR
FITNESS FOR A PA~TICUIAR PURPOSE ~ .~SPECT TO THIS INFOP~ATION OR TO THE
PR~D~' IT DESCRIBES.
eof; however, Re'~chhold-~_kes no
r~=es~tati~ as ~ its,c~le~s ~c~. ~~s ~ ~o~ag~
to ~ ~r ~ ~t~ti~ as to ~ ~t~li~ of this p~t for
~r ~se prior ~ ~e. ~i~1~ ~scl~ re~~ility to ~s of
~ k~ ~t~ ~ ~e use o~ ~h~'~fo~i~. ~ ~ ~ ~~
HAZARDOUS MATERIALS INSI~TION
Business
~l~Bakersfield Fire Dept.
OI$~II~CEOF ENVIRONMENTAL SERVICES
1715 Chester Ave.
Bakersfield, CA 93301
Date Completed ~ - 7- g) 0
Location:
2_qO? L-- $'T'--
Business Identification No. 2!5-000 '7 7 ( (Top of Business Plan)
Station No. L.( Shift ~ Inspector
Arrival Time: 0 q '~ ~ Departure Time: 0 ~ '~ .,,,cInspection Time:
OO/,_,c
Address Visable
Correct Occupancy
Verification of Inventory Materials
Verification of Quantities
Vedflcation of Location
Proper Segregation of Matedal
Adequate Inadequate
[] O
[]
Comments:
Verification of MSDS Availablity
Number of Employees:
Verification of Haz Mat Training []
Comments:
Verification of
Abbatement Supplies and Procedures
Comments:
Emergency Procedures Posted
Containers Properly Labled
Comments:
Adequate Inadequate
[] O
[] []
Verification of Facility Diagram r'l []
Housekeeping [] []
Fire Protection [] O
Electrical [] []
Comments:
UST Monitoring Program [] []
Comments:
Permits~ [] []
Spill Control [] []
Hold Open Device [] []
Hazardous Waste EPA No.
Proper Waste Disposal 0 []
Secondary Containment [] []
Secudty [] []
Special Hazards Associated with this Facility:
0 fL ~ =~JGO -FO t)fFFe-,"z¢',,JT-
Violations: D,.o cpr-~ = ~J
Business Owner/Manager PRINT NAME
SIGNATURE
VVhite-Haz Mat Div.
Yellow-Station Copy
All Items O.K []
Correction Needed []
Pink-Business Copy
Hazardous Materials/Hazardous Waste Unified Permit
CONDITIONS OF PERMIT ON REVERSE SIDE
............... ,,,~,.~****~.,,~,,,,,,, .............. This permit is issued for the following:
~ ~,~:! ~?i ~,~i :i ?:~a''~:~::;;i ili[i i fill iii;;;:::, ii~iiii~:iU~e[ground Storage of Hazardous Materials
PERMIT ID# 015-021000771 ~,i ~;i"~i~ i;~, ;i;:iiiii!!ii!i? ...;??i ! )j!~:!!!!!~::: iiiill ,~ii~kli~a. agement Program
~h....."".~ ,r..~, " . .,.,~::~.,.a~a,,~m~.~" ~,,..'~:~ j~.;r ~:~h. ~r..'",.'~~
~.--'...~ '[ .~'" ~"~m~"-~,~.. , - ~ ~ -_~
....... , .,,, ~ ...... ~.~- ~-,. ".,.
Issued by:
Bakersfield Fire Department
OFFICE OF £NVIR ONMENTAL SER VICES
1715 Chester Ave., 3rd Floor
Bakersfield, CA 95301
Voice (805) 326-3979
FAX (805) 326.0576
Approved by:
Expiration Date:
June 30, 2000
SOUTHERN CALIFORNIA AIRGAS
Manager : ~4~1~r-5 C.
Location: 2907 L ST
City : BAKERSFIELD
BusPhone:
Map : 103
Grid: 19C
CommCode: BAKERSFIELD STATION 04
EPA Numb:
SIC Code:
DunnBrad:
/
SiteID: 215-000-000771
(805) 327-7509
CommHaz : Moderate
FacUnits: 1 AOV:
Emergency Contact / Title
CAM CUMMINGS / BRANCH MANAGER
Business Phone: (805) 327-7509x
24-Hour Phone : (805) 833-3832x
Pager Phone : ( , ) 932-5~79z ~
Emergency Contact / Title
MIKE BRADLEY / SALES
Business Phone: (805) 327-7509x
24-Hour Phone : (805) 396-1819x
Pager Phone : ( ) - x
Hazmat Hazards:
Fire Press ImmHlth DelHlth
Agency-Defined Topic Title
~ Hazmat Inventory
-- MCP+DailyMax Order
ACETYLENE F P IH G
PROPANE F IH DH L
ETHYLENE F P IH G
OXYGEN F P IH G
CARBON DIOXIDE F P IH G
ARGON F P IH G
HELIUM F P IH G
NITROGEN F P IH G
ARGON/CARBON DIOXIDE F P IH G
One Unified List
Ail Materials at Site
I Unit MCP
DailyMax
20000 FT3 Hi
18000 FT3 Hi
1500 LBS Hi
30000 FT3 Low
20000 LBS Min
12000 FT3 Min
10000 FT3 Min
10000 FT3 Min
5000 FT3 Min
1 06/23/1997
SOUTHERN CALIFORNIA AIRGAS SiteID: 215-000-000771
Inventory Item 0001 Facility Unit: Fixed Containers on Site
ACETYLENE Days On Site
365
Location within this Facility Unit
EAST DOCK CAS#
74-86-2
STATE TYPE
Gas Pure
PRESSURE TEMPERATURE
Above Ambient I Ambient
CONTAINER TYPE
PORT. PRESS. CYLINDER
Lrgst Cont.this Loc FT3
DailyMax Stored FT3
AMOUNTS STORED AND IN USE
DailyMax this Loc FT3
20000.00
DailyMax Open Use FT3
DailyAvg this Loc FT3
17000.00
DailyMax Closed Use FT3
%Wt.
100.00 Acetylene
HAZARDOUS COMPONENTS
EHS
No
CAS#
74862
-2- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS SiteID: 215-000-000771
~ Inventory Item 0007 Facility Unit: Fixed Containers on Site
PROPANE Days On Site
365
Location within this Facility Unit
SOUTHEAST CORNER OF LOT CAS#
74-98-6
F STATE 1TYPE PRESSURE i TEMPERATURE
Liquid Pure Ambient Ambient
CONTAINER TYPE
PORT. PRESS. CYLINDER
Lrgst Cont.this Loc FT3
DailyMax Stored FT3
AMOUNTS STORED AND IN USE
DailyMax this Loc FT3
18000.00
DailyMax Open Use FT3
DailyAvg this Loc FT3
10800.00
DailyMax Closed Use FT3
%Wt.
100.00 Propane
HAZARDOUS COMPONENTS
EHS
No
CAS#
74986
-3- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
Inventory Item 0010
-- COMMON NAME / CHEMICAL NAME
ETHYLENE
Location within this Facility Unit
SiteID: 215-000-000771
Facility Unit: Fixed Containers on Site
Days On Site
365
CAS#
74-85-1
STATE [ TYPE
Gas Pure
PRESSURE TEMPERATURE
!
Above Ambient I Ambient
CONTAINER TYPE
PORT. PRESS. CYLINDER
Lrgst Cont.this Loc LBS
AMOUNTS STORED AND IN USE
DailyMax this Loc LBS
1500.00
DailyAvg this Loc LBS
1500.00
DailyMax Stored LBS DailyMax Open Use LBS DailyMax Closed Use LBS
%Wt.
100.00 Ethylene
HAZARDOUS COMPONENTS
EHS CAS#
No 74851
-4- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
~ Inventory Item 0002
-- COMMON NAME / CHEMICAL NAME
OXYGEN
Location within this Facility Unit
EAST DOCK
SiteID: 215-000-000771
Facility Unit: Fixed Containers on Site
Days On Site
365
CAS#
7782-44-7
rSTATE -- TYPE
Gas Pure
PRESSURE TEMPERATURE
I Above Ambient I Ambient
CONTAINER TYPE
PORT. PRESS. CYLINDER
Lrgst Cont.this Loc FT3
DailyMax Stored FT3
AMOUNTS STORED AND IN USE
DailyMax this Loc FT3
30000.00
DailyMax Open Use FT3
DailyAvg this Loc FT3
27500.00
DailyMax Closed Use FT3
%Wt.
100.00
HAZARDOUS COMPONENTS
Oxygen, Compressed
EHS CAS#
No 7782447
5 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
~ Inventory Item 0005
-- COMMON NAME / CHEMICAL NAME
CARBON DIOXIDE
Location within this Facility unit
Nw CORNER OF PROPERTY
SiteID: 215-000-000771
Facility Unit: Fixed Containers on Site
Days On Site
365
CAS#
124-38-9
r STATE I TYPE
Gas Pure
PRESSURE , TEMPERATURE
Ambient I Cryogenic
Above
CONTAINER TYPE
INSUL.TANK / CRYOGENIC
Lrgst Cont.this Loc LBS
DailyMax Stored LBS
AMOUNTS STORED AND IN USE
DailyMax this Loc LBS
20000.00
DailyMax Open Use LBS
DailyAvg this Loc LBS
10000.00
DailyMax Closed Use LBS
%Wt. I
100.00 Carbon Dioxide
HAZARDOUS COMPONENTS
124389
-6- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
~ Inventory Item 0003
-- COMMON NAME / CHEMICAL NAME
ARGON
Location within this Facility Unit
EAST DOCK
SiteID: 215-000-000771
Facility Unit: Fixed Containers on Site
Days On Site
365
CAS#
7440-37-1
STATE -- TYPE
Gas Pure
PRESSURE TEMPERATURE
I Above Ambient I Ambient
CONTAINER TYPE
PORT. PRESS. CYLINDER
Lrgst Cont.this Loc FT3
DailyMax Stored FT3
AMOUNTS STORED AND IN USE
DailyMax this Loc FT3
12000.00
DailyMax Open Use FT3
DailyAvg this Loc FT3
10000.00
DailyMax Closed Use FT3
%Wt.
100.00 Argon
HAZARDOUS COMPONENTS
EHS CAS#
No 7440371
-7- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
~ Inventory Item 0004
-- COMMON NAME / CHEMICAL NAME
HELIUM
Location within this Facility Unit
EAST DOCK
SiteID: 215-000-000771
Facility Unit: Fixed Containers on Site
Days On Site
365
CAS#
7440-59-7
r STATE TYPE
Gas Pure
PRESSURE , TEMPERATURE
Above Ambient I Ambient
CONTAINER TYPE
I PORT' PRESS' CYLINDER
Lrgst Cont.this Loc FT3
AMOUNTS STORED AND IN USE
DailyMax this Loc FT3
10000.00
DailyAvg this Loc FT3
9000.00
DailyMax Stored FT3 DailyMax Open Use FT3 DailyMax Closed Use FT3
%Wt.
100.00 Helium
HAZARDOUS COMPONENTS
EHS CAS#
7440597
8 06/23/1997
SOUTHERN CALIFORNIA AIRGAS SiteID: 215-000-000771
~ Inventory Item 0006 Facility Unit: Fixed Containers on Site
~u~u~ mann / uU~lU~ ~
NITROGEN Days On Site
365
Location within this Facility Unit
EAST DOCK CAS#
7727-37-9
F STATE ] TYPE
Gas Pure
PRESSURE TEMPERATURE
I
Above Ambient I Ambient
I
CONTAINER TYPE
PORT. PRESS. CYLINDER
Lrgst Cont.this Loc FT3
DailyMax Stored FT3
AMOUNTS STORED AND IN USE
DailyMax this Loc FT3
10000.00
DailyMax Open Use FT3
DailyAvg this Loc FT3
9000.00
DailyMax Closed Use FT3
I%Wt. I
100.00 Nitrogen
HAZARDOUS COMPONENTS
EHS CAS#
No 7727379
-9- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS SiteID: 215-000-000771
~ Inventory Item 0009 Facility Unit: Fixed Containers on Site
ARGON/CARBON DIOXIDE Days On Site
365
Location within this Facility Unit
EAST DOCK CAS#
7440-37-1
FSTATE TYPE
Gas [ Mixture
PRESSURE TEMPERATURE
Above Ambient I Ambient
CONTAINER TYPE
PORT. PRESS. CYLINDER
Lrgst Cont.this Loc FT3
AMOUNTS STORED AND IN USE
DailyMax this Loc FT3
5000.00
DailyAvg this Loc FT3
4500.00
DailyMax Stored FT3 DailyMax Open Use FT3 DailyMax Closed Use FT3
%Wt. EHS CAS#
75.00iArgon No 7440371
25.00!Carbon Dioxide No 124389
-10- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
SiteID: 215-000-000771
Fast Format
Notif./Evacuation/Medical
Agency Notification
CALL 911
Overall Site
03/22/1990
-- Employee Notif./Evacuation
03/22/1990
WE WOULD CONTACT LOCAL AUTHORITIES, CLEAR ALL PERSONS FROM OUR FACILITY AND
START NOTIFYING THE OTHER BUSINESSES IN THE AREA OF THE PRESENT DANGER.
INTERCOM AND LOUD SPEAKERS ON CYLINDER DOCK AND IN WAREHOUSE, ALL EMPLOYEES
ARE INSTRUCTED TO GO TO SOUTH END OF LOT TO SIDEWALK OF GOLDEN STATE HWY OFF
Public Notif./Evacuation
CALL 911
03/22/1990
Emergency Medical Plan
EMERGENCY ROOM AT SAN JOAQUIN COMMUNITY HOSPITAL
2615 EYE ST
(805) 327-1711
FIRST AID KIT LOCATED IN MAIN WHAREHOUSE CENTRAL LOCATION OR CALL 911
03/22/1990
-11- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
SiteID: 215-000-000771
Fast Format
Mitigation/Prevent/Abatemt
Release Prevention
Overall Site
03/22/1990
DUE TO THE NATURE OF OUR BUSINESS, OUR ONLY CONCERN WOULD BE THE RELEASE OF
OUR COMPRESSED GASES. TO PREVENT THIS WE KEEP CAPS ON ALL CYLINDERS AND
HANDLE WITH EXTREME CARE. IN THE EVENT OF A RELEASE WE NOTIFY THE FIRE DEPT
BUT, SINCE THERE IS NO WAY TO CLEAN UP GAS IT WOULD JUST DISIPATE INTO THE
ATMOSPHERE.
ALL FULL CYLINDERS HAVE SAFETY CAPS IN PLACE AND CHAINED TO MINIMIZE CHANCES
OF FALLING OVER.
-- Release Containment
FIRE WALL ON CYLINDER DOCK FOR FLAMMABLE GAS, FULL AND EMPTIES
03/22/1990
-- Clean Up
03/22/1990
IF FLAMMABLE ACETYLENE OR PROPANE CYLINDER HAS DEVELOPED A LEAK, CYLINDER IS
MOVED TO A SAFE LOCATION AND ALLOWED TO EMPTY, ALL OTHER CYLINDER GASSES ARE
NONFLAMMABLE CONDENCED TO ATMOSPHERIC OR MINED GASES THAT CAN DISPLACE AIR
IN A CONFINED AREA BUT NOT HARMFULL OTHERWISE.
Other Resource Activation
-12- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
SiteID: 215-000-000771
Fast Format
Site Emergency Factors
Special Hazards
Overall Site
-- Utility Shut-Offs
03/22/1990
A) GAS - SOUTH END OF MAIN WHAREHOUSE IN DRIVEWAY, WEST SIDE OF BUILDING #2
IN ALLEY
B) ELECTRICAL - MAIN BREAKER NORTHWEST CORNER OF WAREHOUSE
C) WATER - IN ALLEY WEST SIDE OF BUILDING #2
D) SPECIAL - NONE
E) LOCK BOX - NO
Fire Protec./Avail. Water 03/22/1990
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AT VARIOUS LOCATIONS
FIRE HYDRANT - NORTH END OF ALLEY WEST SIDE 30TH ST
Building Occupancy Level
-13- 06/23/1997
SOUTHERN CALIFORNIA AIRGAS
SiteID: 215-000-000771
Fast Format
Training
-- Employee Training
WE HAVE 15 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
BRIEF SUMMARY OF TRAINING: WE HAVE SAFETY AND PRODUCT TRAINING MEETINGS
EVERY WEDNESDAY MORNING, WE ALSO HAVE AT LEAST 1 OR MORE REPRESENTATIVE FROM
FLINTCO ATTEND OTHER RELATED MEETINGS AND SEMINARS PUT ON BY OTHER AGENCIES.
Overall Site
03/22/1990
-- Page 2
Held for Future Use
Held for Future Use
-14- 06/23/1997
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
Overall Site with 1 Fac. Unit
General Information
Page
Location: 2907 L ST Map:103 Haz~3 Type~ 3
City : BAKERSFIELD ~ . _ Grid: 19C F/U. 1 AOV.
_ C~n~act Name~ Tztle :P ,~C~L'/[~t' Name 7 Title
~:: .... ~'~" / ................ ,~- II~ /~~~5 I
Bus~ness ~hone: (805) 327-7509x _ II Bus~ess ~hone: (805) 327-7509x I
24-Hou~ ~hone : (805) ~-~~11 =~-.o~ ~hone : (805)~~
~age~ ~hone : ( ) - x~l/ ~et ~ne : ( ) - x
I
uministrative Data
Mail Addrs: 2907 L ST D&B Number:
City: BAKERSFIELD State: CA Zip: 93301-
Co~ Code: 215-004 BAKERSFIELD STATION 04 SIC Code:
Owner: SOUTHERN CALIFORNIA AIRGAS
Address: 4007 PARAMOUNT BLVD. 100
City: LAKEWOOD
Phone: ( ) -
State: CA
Zip: 90712-4138
Summary
('i'~:~e Or i~int name)
reviewed the attached hazardous mmerials nm. ,~.,';a-
merit plan for ~:' ~,~a ~/:p_r=/~ and that it
any corrections constitute a e~mplete and correct man-
agement plan for my facility.
09/12/96 SOUTHERN CALIFORNIA AIRGAS 215-000-000771 Page 2
Hazmat Inventory List in MCP Order
02 - Fixed Containers on Site
Name/Hazards Form Max Qty
Pln-Ref MCP
02-001 ACETYLENE Gas 20000 High
· Fire, Pressure, Immed Hlth / FT3
/ ~ · ~e, ~
02-007 PROPANE Liquid 18000 High
· Fire, Immed Hlth, Delay Hlth FT3
02-010 ETHYLENE
· Fire, Pressure, Immed Hlth
Gas 1500 High
LBS
02-002 OXYGEN
· Fire, Pressure, Immed Hlth
Gas 30000 Low
FT3
02-003 ARGON
· Fire, Pressure, Immed Hlth
Gas 12000
FT3
Minimal
02-009 ARGON/CARBON DIOXIDE
· Fire, Pressure, Immed Hlth
Gas
5000 Minimal
FT3
02-005 CARBON DIOXIDE
· Fire, Pressure, Immed Hlth
Gas
20000 Minimal
LBS
02-004 HELIUM
· Fire, Pressure, Immed Hlth
Gas
10000 Minimal
FT3
02-006 NITROGEN
· Fire, Pressure, Immed Hlth
Gas 10000
FT3
Minimal
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
Page
3
02-001 ACETYLENE
· Fire, Pressure, Immed Hlth
Gas 20000 High
FT3
CAS #: 74-86-2
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: WELDING SOLDERING
Daily Max FT3
20,000
Daily Average FT3
17,000.00
Annual Amount FT3
204,000.00
Storage
PORT. PRESS. CYLINDER
Press T Temp
IAbove IAmbientlEAST DOCK
Location
-- Conc
100.0% IAcetylene
Components
MCP ---~uide
IHigh ! 17
0~-008 MAPP J Gas 2879 High
~Fi re______~_, Press u r e__, I mme__d H1 t__h __ FT__3 __
C~ Trade Secret: No ~
Form: G_a~~e: Pure Days: 3~DING SO_LDERING
-- Daily Max FT3'~i Daily A~ge FT3 ---[---- Annual Amount FT3 ...
2,879 ~ 1,400.00 I 34,554.00
~ St°rage/~'- I Press TTe~ ~Location- ....
PO_R~LINDER .Above . ~A~~CK M~o __
--~ I Components ~ I MCP ---~uide
J 100.0% .Acetylene ~h / 17
02-007 PROPANE
· Fire, Immed Hlth, Delay Hlth
Liquid 18000 High
FT3
CAS #: 74-98-6
Form: Liquid Type: Pure
Daily Max FT3
18,000 I
Trade Secret: No
Days: 365 Use: WELDING SOLDERING
Daily Average FT3 ! Annual Amount FT3
10,800.00 I 129,600.00
Storage Press T Temp Location
PORT. PRESS. CYLINDER IAmbientlAmbientlSOUTHEaST CORNER OF LOT
-- Conc
100.0% IPropane
Components
MCP ---~uide
IExtreme I 22
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
Page
4
02-010
ETHYLENE
· Fire, Pressure, Immed Hlth
Gas
1500 High
LBS
CAS #: 74-85-1
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use:
Daily Max LBS
1,500
Daily Average LBS
1,500.00
Annual Amount LBS
1,500.00
Storage Press T Temp
PORT. PRESS. CYLINDER Above JAmbientI
Location
-- Conc
100.0% IEthylene
Components
MCP ---~uide
IHigh ! 22
02-002
OXYGEN
· Fire, Pressure, Immed Hlth
Gas
30000 Low
FT3
CAS #: 7782-44-7
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: WELDING SOLDERING
Daily Max FT3
30,000
Daily Average FT3
27,500.00
Annual Amount FT3
330,000.00
Storage Press T Temp
PORT. PRESS. CYLINDER Above JAmbientlEAST DOCK
Location
-- Conc
100.0% IOxygen, Compressed
Components
MCP ---TGuide
ILow ! 14
02-003 ARGON
· Fire, Pressure, Immed Hlth
Gas
12000 Minimal
FT3
CAS #: 7440-37-1
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: WELDING SOLDERING
Daily Max FT3
12,000
Daily Average FT3
10,000.00
Annual Amount FT3
120,000.00
Storage
PORT. PRESS. CYLINDER
Press T Temp
IAbove IAmbiontlEAST DOCK
Location
-- Conc
100.0% IArgon
Components
MCP ---TGuide
JMinimal J 12
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
Page
5
02-009 ARGON/CARBON DIOXIDE
· Fire, Pressure, Immed Hlth
Gas
5000 Minimal
FT3
CAS #: 7440-37-1
Trade Secret: No
Form: Gas
Type: Mixture Days: 365 Use: WELDING SOLDERING
Daily Max FT3
5,000
Daily Average FT3
4,500.00
Annual Amount FT3
54,000.00
Storage
PORT. PRESS. CYLINDER
Press T Temp
IAbove /AmbientlEAST DOCK
Location
-- Conc
75.0% Argon
25.0% Carbon Dioxide
Components
MCP ---~uide
Minimal I 12
Low ! 21
02-005 CARBON DIOXIDE
· Fire, Pressure, Immed Hlth
Gas 20000 Minimal
LBS
CAS #: 124-38-9
Form: Gas Type: Pure
Daily Max LBS
20,000 I
Trade Secret: No
Days: 365 Use: OTHER
Daily Average LBS ! Annual Amount LBS
10,000.00 I 120,000.00
Storage Press I Temp Location
INSUL.TANK / CRYOGENICIAbove /CryogenlNW CORNER OF PROPERTY
-- Conc
100.0% ICarbon Dioxide
Components
MCP ---~uide
ILow ! 21
02-004 HELIUM
· Fire, Pressure, Immed Hlth
Gas
10000 Minimal
FT3
CAS #: 7440-59-7
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: OTHER
Daily Max FT3
10,000
Daily Average FT3
9,000.00
Annual Amount FT3
108,000.00
Storage
PORT. PRESS. CYLINDER
Press T Temp
I Above ~AmbientlEAST DOCK
Location
-- Conc
100.0% IHelium
Components
MCP ---~Guide
IMinimal I 12
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
Page
02-006 NITROGEN
~ Fire, Pressure, Immed Hlth
Gas 10000 Minimal
FT3
CAS #: 7727-37-9
Form: Gas Type: Pure
Daily Max FT3
10,000 I
Trade Secret: No
Days: 365 Use: OTHER
Daily Average FT3 ! Annual Amount FT3
9,000.00I 108,000.00
Location
Storage Press T Temp
I
PORT. PRESS. CYLINDER Above I AmbientlEAST DOCK
-- Conc Components
100.0% INitrogen
MCP ---TGuide
ILow ! 12
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
00 - Overall Site
<D> Notif./Evacuation/Medical
Page
7
<1> Agency Notification
CALL 911
<2> Employee Notif./Evacuation
WE WOULD CONTACT LOCAL AUTHORITIES, CLEAR ALL PERSONS FROM OUR FACILITY AND
START NOTIFYING THE OTHER BUSINESSES IN THE AREA OF THE PRESENT DANGER.
INTERCOM AND LOUD SPEAKERS ON CYLINDER DOCK AND IN WAREHOUSE, ALL EMPLOYEES
ARE INSTRUCTED TO GO TO SOUTH END OF LOT TO SIDEWALK OF GOLDEN STATE HWY OFF
RAMP.
<3> Public Notif./Evacuation
CALL 911
<4> Emergency Medical Plan
EMERGENCY ROOM AT SAN JOAQUIN COMMUNITY HOSPITAL
2615 EYE ST
(805) 327-1711
FIRST AID KIT LOCATED IN MAIN WHAREHOUSE CENTRAL LOCATION OR CALL 911
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
00 - Overall Site
<E> Mitigation/Prevent/Abatemt
Page
8
<1> Release Prevention
DUE TO THE NATURE OF OUR BUSINESS, OUR ONLY CONCERN WOULD BE THE RELEASE OF
OUR COMPRESSED GASES. TO PREVENT THIS WE KEEP CAPS ON ALL CYLINDERS AND
HANDLE WITH EXTREME CARE. IN THE EVENT OF A RELEASE WE NOTIFY THE FIRE DEPT
BUT, SINCE THERE IS NO WAY TO CLEAN UP GAS IT WOULD JUST DISIPATE INTO THE
ATMOSPHERE.
ALL FULL CYLINDERS HAVE SAFETY CAPS IN PLACE AND CHAINED TO MINIMIZE CHANCES
OF FALLING OVER.
<2> Release Containment
FIRE WALL ON CYLINDER DOCK FOR FLAMMABLE GAS, FULL AND EMPTIES
<3> Clean Up
IF FLAMMABLE ACETYLENE OR PROPANE CYLINDER HAS DEVELOPED A LEAK, CYLINDER IS
MOVED TO A SAFE LOCATION AND ALLOWED TO EMPTY, ALL OTHER CYLINDER GASSES ARE
NONFLAMMABLE CONDENCED TO ATMOSPHERIC OR MINED GASES THAT CAN DISPLACE AIR
IN A CONFINED AREA BUT NOT HARMFULL OTHERWISE.
<4> Other Resource Activation
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
00 - Overall Site
<F> Site Emergency Factors
Page
<1> Special Hazards
<2> Utility Shut-Offs
A) GAS - SOUTH END OF MAIN WHAREHOUSE IN DRIVEWAY, WEST SIDE OF BUILDING #2
IN ALLEY
B) ELECTRICAL - MAIN BREAKER NORTHWEST CORNER OF WAREHOUSE
C) WATER - IN ALLEY WEST SIDE OF BUILDING #2
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire Protec./Avail. Water
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AT VARIOUS LOCATIONS
FIRE HYDRANT - NORTH END OF ALLEY WEST SIDE 30TH ST
<4> Building Occupancy Level
09/12/96
SOUTHERN CALIFORNIA AIRGAS 215-000-000771
00 - Overall Site
<G> Training
Page
10
<1> Employee Training
WE HAVE 15 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
BRIEF SUMMARY OF TRAINING: WE HAVE SAFETY AND PRODUCT TRAINING MEETINGS
EVERY WEDNESDAY MORNING, WE ALSO HAVE AT LEAST 1 OR MORE REPRESENTATIVE FROM
FLINTCO ATTEND OTHER RELATED MEETINGS AND SEMINARS PUT ON BY OTHER AGENCIES.
<2> Page 2
<3> Held for Future Use
<4> Held for Future Use
.;
04/24Yg5
~iNTCO INC 215-000-000771
Overall Site with 1 Fac. Unit
General Information
Page
Location: 2907 L ST Map:103 Haz:3 Type: 3
City : Bakersfield Grid: 19C F/U: 1 AOV: 0.0
Contact Name Title~ Contact Na~ ~ Title
Business Phone: (805) 327-7509x /1Business Phone: (805) 327-7509x
24-Hour Phone : (805) 8~--~-~-xE9~4~ 24-Hour Phone : (805) ~9~--4~1x5~
Pager Phone : ( ) - x ' // Pager Phone : ( ) -
Administrative Data
Mail Addrs: 2907 L ST D&B Number:
City: BAKERSFIELD State: CA Zip: 93301-
Comm Code: 215-004 BAKERSFIELD STATION 04 SIC Code:
Owner: DIANE 2 FLINT ~Do779~ ~)~D~/~ ~Hf~k~Phone: (8~5) 327-7599
Address: 6712 DESi~OND ~ F~Du~~O ~,~/~tate: CA
City: BAKERSFIELD ~~,D Zip:
Sugary
reviewed the a~'t~');~c~.: ~ ..... ~ ......
.......... -.~ mana~
merit Plan for~~~a.~
~o~~ ,,~ that i~ a~on~
any corrections constitute a complete and ~rre~
a~ement plan for my facility.
RECEivED
04/24~95
FLINTCO INC 215-000-000771
Hazmat Inventory List in MCP Order
Page
2
02 - Fixed Containers on Site
Pln-Ref Name/Hazards
Form Max Qty
MCP
02-001 ACETYLENE
· Fire, Pressure, Immed Hlth
Gas
20000 High
FT3
02-008 MAPP
· Fire, Pressure, Immed Hlth
Gas
2879 High
FT3
02-007
PROPANE
· Fire, Immed Hlth, Delay Hlth
Liquid
18000 High
FT3
02-002 OXYGEN
· Fire, Pressure, Immed Hlth
Gas
30000 Low
FT3
02-003 ARGON
· Fire, Pressure, Immed Hlth
Gas
12000 Minimal
FT3
02-009 ARGON/CARBON DIOXIDE
· Fire, Pressure, Immed Hlth
Gas
5000 Minimal
FT3
02-005 CARBON DIOXIDE
· Fire, Pressure, Immed Hlth
Gas
20000 Minimal
LBS
02-004 HELIUM
· Fire, Pressure, Immed Hlth
Gas
10000 Minimal
FT3
02-006
NITROGEN
· Fire, Pressure, Immed Hlth
Gas
10000 Minimal
FT3
04/24Y95
FLINTCO INC 215-000-000771
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
Page
02-001
ACETYLENE
· Fire, Pressure, Immed Hlth
Gas
20000 High
FT3
CAS #: 74-86-2
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: WELDING SOLDERING
-- Daily Max FT3
20,000
Daily Average FT3
17,000.00
Annual Amount FT3
204,000.00
Storage
PORT. PRESS. CYLINDER
Press T Temp
IAbove IAmbientlEAST DOCK
Location
-- Conc
100.0% IAcetylene
Components
MCP ---TGuide
IHigh ! 17
02-008 MAPP
· Fire, Pressure, Immed Hlth
Gas 2879 High
FT3
CAS #:
Form: Gas
Type: Pure
Daily Max FT3
2,879
Trade Secret: No
Days: 365 Use: WELDING SOLDERING
Daily Average FT3 I Annual Amount FT3
I 1,400.00 34,554.00
Location
Storage Press T Temp
PORT. PRESS. CYLINDER Above I AmbientlEAST DOCK
-- Conc
100.0% IAcetylene
Components
MCP ---TGuide
IHigh ! 17
02-007
PROPANE
· Fire, Immed Hlth, Delay Hlth
Liquid 18000 High
FT3
CAS #: 74-98-6
Trade Secret: No
Form: Liquid Type: Pure
Days: 365 Use: WELDING SOLDERING
Daily Max FT3
18,000
Daily Average FT3
10,800.00
Annual Amount FT3
129,600.00
Storage Press T Temp Location
PORT. PRESS. CYLINDER IAmbientlAmbientlSOUTHEaST CORNER OF LOT
-- Conc
100.0% IPropane
Components
MCP ---/Guide
Extreme I 22
04/24795
FLINTCO INC 215-000-000771
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
Page
4
02-002 OXYGEN
· Fire, Pressure, Immed Hlth
Gas
30000 Low
FT3
CAS #: 7782-44-7
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: WELDING SOLDERING
Daily Max FT3
30,000
Daily Average FT3
27,500.00
Annual Amount FT3
330,000.00
Storage Press T Temp
PORT. PRESS. CYLINDER Above ~AmbientlEAST DOCK
Location
-- Conc
100.0% IOxygen, Compressed
Components
MCP ---~uide
ILow ! 14
02-003
ARGON
· Fire, Pressure, Immed Hlth
Gas
12000 Minimal
FT3
CAS #: 7440-37-1
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: WELDING SOLDERING
Daily Max FT3
12,000
Daily Average FT3
10,000.00
Annual Amount FT3
120,000.00
Storage
PORT. PRESS. CYLINDER
Press T Temp
IAbove ~AmbientlEAsT DOCK
Location
- Conc
100.0% IArgon
Components
MCP ---TGuide
IMinimal I 12
02-009 ARGON/CARBON DIOXIDE
· Fire, Pressure, Immed Hlth
Gas
5000 Minimal
FT3
CAS #: 7440-37-1
Trade Secret: No
Form: Gas
Type: Mixture Days: 365 Use: WELDING SOLDERING
Daily Max FT3
5,000
Daily Average FT3
4,500.00
Annual Amount FT3 --
54,000.00
Storage Press T Temp
PORT. PRESS. CYLINDER Above ~AmbientlEAST DOCK
Location
-- Conc
75.0%
25.0%
IArgon
Carbon Dioxide
Components
MCP -~Guide
IMinimal I 12
Low ! 21
04/24~95
FLINTCO INC 215-000-000771
02 - Fixed Containers on Site
Hazmat Inventory Detail in MCP Order
Page
5
02-005 CARBON DIOXIDE
· Fire, Pressure, Immed Hlth
Gas
20000 Minimal
LBS
CAS #: 124-38-9
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: OTHER
Daily Max LBS
20,000
Daily Average LBS
10,000.00
Annual Amount LBS
120,000.00
Storage Press T Temp Location
INSUL.TANK / CRYOGENIC Above JCryogenlNW CORNER OF PROPERTY
-- Conc
100.0% ICarbon Dioxide
Components
MCP ---~uide
ILow ~ 21
02-004
HELIUM
· Fire, Pressure, Immed Hlth
Gas
10000 Minimal
FT3
CAS #: 7440-59-7
Trade Secret: No
Form: Gas
Type: Pure
Days: 365 Use: OTHER
Daily Max FT3
10,000
Daily Average FT3
9,000.00
Annual Amount FT3
108,000.00
Storage
PORT. PRESS. CYLINDER
Press T Temp
I Above JAmbient lEAST DOCK
Location
-- Conc
100.0% IHelium
Components
MCP -~Guide
Minimal I 12
02-006
NITROGEN
· Fire, Pressure, Immed Hlth
Gas 10000 Minimal
FT3
CAS #: 7727-37-9
Trade Secret: No
Form: Gas Type: Pure
Daily Max FT3
10,000 I
Days: 365 Use: OTHER
Daily Average FT3 ] Annual Amount FT3
9,000.00 I 108,000.00
Storage
PORT. PRESS. CYLINDER
-- Conc
100.0% INitrogen
Press T Temp
IAbove IAmbientlEAST DOCK
Components
Location
i LowMCP ---~Guide
/ 12
04/24795 FLINTCO INC 215-000-000771 Page
00 - Overall Site
<D> Notif./Evacuation/Medical
6
<1> Agency Notification
CALL 911
<2> Employee Notif./Evacuation
WE WOULD CONTACT LOCAL AUTHORITIES, CLEAR ALL PERSONS FROM OUR FACILITY AND
START NOTIFYING THE OTHER BUSINESSES IN THE AREA OF THE PRESENT DANGER.
INTERCOM AND LOUD SPEAKERS ON CYLINDER DOCK AND IN WAREHOUSE, ALL EMPLOYEES
ARE INSTRUCTED TO GO TO SOUTH END OF LOT TO SIDEWALK OF GOLDEN STATE HWY OFF
RAMP.
<3> Public Notif./Evacuation
CALL 911
<4> Emergency Medical Plan
EMERGENCY ROOM AT SAN JOAQUIN COMMUNITY HOSPITAL
2615 EYE ST
(805) 327-1711
FIRST AID KIT LOCATED IN MAIN WHAREHOUSE CENTRAL LOCATION OR CALL 911
04/2479~5'
FLINTCO INC 215-000-000771
00 - Overall Site
<E> Mitigation/Prevent/Abatemt
Page
7
<1> Release Prevention
DUE TO THE NATURE OF OUR BUSINESS, OUR ONLY CONCERN WOULD BE THE RELEASE OF
OUR COMPRESSED GASES. TO PREVENT THIS WE KEEP CAPS ON ALL CYLINDERS AND
HANDLE WITH EXTREME CARE. IN THE EVENT OF A RELEASE WE NOTIFY THE FIRE DEPT
BUT, SINCE THERE IS NO WAY TO CLEAN UP GAS IT WOULD JUST DISIPATE INTO THE
ATMOSPHERE.
ALL FULL CYLINDERS HAVE SAFETY CAPS IN PLACE AND CHAINED TO MINIMIZE CHANCES
OF FALLING OVER.
<2> Release Containment
FIRE WALL ON CYLINDER DOCK FOR FLAMMABLE GAS, FULL AND EMPTIES
<3> Clean Up
IF FLAMMABLE ACETYLENE OR PROPANE CYLINDER HAS DEVELOPED A LEAK, CYLINDER IS
MOVED TO A SAFE LOCATION AND ALLOWED TO EMPTY, ALL OTHER CYLINDER GASSES ARE
NONFLAMMABLE CONDENCED TO ATMOSPHERIC OR MINED GASES THAT CAN DISPLACE AIR
IN A CONFINED AREA BUT NOT HARMFULL OTHERWISE.
<4> Other Resource Activation
04/24f9:5~ ° FLINTCO INC 215-000-000771 Page
00 - Overall Site
<F> Site Emergency Factors
8
<1> Special Hazards
<2> Utility Shut-Offs
A) GAS - SOUTH END OF MAIN WHAREHOUSE IN DRIVEWAY, WEST SIDE OF BUILDING #2
IN ALLEY
B) ELECTRICAL - MAIN BREAKER NORTHWEST CORNER OF WAREHOUSE
C) WATER - IN ALLEY WEST SIDE OF BUILDING #2
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire Protec./Avail. Water
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AT VARIOUS LOCATIONS
FIRE HYDRANT - NORTH END OF ALLEY WEST SIDE 30TH ST
<4> Building Occupancy Level
04/24/g5' ~
FLINTCO INC 215-000-000771
00 - Overall Site
<G> Training
Page
<1> Employee Training
WE HAVE 15 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
BRIEF SUMMARY OF TRAINING: WE HAVE SAFETY AND PRODUCT TRAINING MEETINGS
EVERY WEDNESDAY MORNING, WE ALSO HAVE AT LEAST 1 OR MORE REPRESENTATIVE FROM
FLINTCO ATTEND OTHER RELATED MEETINGS AND SEMINARS PUT ON BY OTHER AGENCIES.
<2> Page 2
<3> Held for Future Use
<4> Held for Future Use
MATERIAL SAFETY DATA SHEET
LIQUID CARBONIC
INDUSTRIAL/MEDICAL CORPORATION
135 SOUTH LA SALLE STREET · CHICAGO, ILLINOIS 60603-4282
PHONE: (312) 855-2500
f~er~ency Phone Numbers: (312)855-2500; CH~I%q~C
April 1986
(800)424-9300
S~CTICN I--PRODUCT ID~gTIFICATION
CH~4ICALFAMILY:
Ethylene
Ethylene, Acetene, Ethene, Olefiant Gas, Etherin,
Elayl
Alkene, (Olefin) FOP~K~A: C~4
S~ION II--HAZARDOUS INGREDIf~PS
MATERIAL VOLUME % CAS NO. 1985-6 ~GIH TLV UNITS
EthTlene 98.5 74-85-1 Single Asphyxiant
SfLTION III--PHYSICAL DATA
BOILING POINT (°F.) -154°F SPECIFIC GRAVITY (H20=i)@B.Pt. 0.57
VAPOR PRESSURE (nm~g.)@68°F 590 psig % VOLATTT~. BY VOLUME 100
VAPOR D~SITY (AIR=l) @60°F 0.97 EVAPORATION RATE (BUTYL ACETATE=l) Rapid
SOLUBILITY IN ~ATER 0.26 Vol/1 Vol. H20
APPEARANCE AND CDOR Colorless gas with sweet odor
S~CTION IV--FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (METHfD USED) -213°F (C.C.) ~ LIMITS % by Volume 2.7 36.0
EXTINGUISHING MEDIA: Dry chemical, carbon dioxide, water spray
SPECIAL FIRE FIGHTING PROCEDURES: Stop gas flow and remove container if
possible. Do not fully extinguish burning gas until flow is stopped. Allow fuel
to consume itself. Use water spray to cool fire-exposed containers. Fire-exposed
containers could rupture violently if safety devices fail to relieve pressure.
Wear self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Explodes spontaneously when mixed with
chlorine in sunlight. Reacts vigorously with oxidizers. Use suit_able explosi-
meter calibrated for ethylene to confirm atmosphere is below the ethylene T.Rr,.
SfETION V--HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE: Ethylene is a simple asphyxiant. ACGIH TLV requires that
oxygen levels should be maintained at more than 18% by volume at normal atmos-
pheric pressure which is equivalent to a partial pressure of 135 mm of Hg.
Ho~sver, it is recc~uended that the ethylene level in the workplace be limited
to 20% of the T.~r, or 0.6%.
~S OF OVEREXPOSURE: Ethylene at very high concentrations can act as a
simple asphyxiant by displacing oxygen. Inhalation at high concentrations may
cause dizziness, drowsiness, moderate anesthesia, headache, nausea. Liquid
ethylene can cause cryogenic burns on contact with eyes or skin.
EMERG~qCY AND FIRST AID PROCEDURES: If inhaled: Remove to fresh air. Get praupt
medical attention. Quickly restore breathing with artificial respiration; If
breathing is difficult, administer oxygen. Keep warm and at rest. Rescue
personnel should use self-contained breathing apparatus for their own safety
aD~ be cognizant of extreme fire and explosion hazard. Skin/Eye contact:
Prc~Ptly flush affected areas with copious quantities of tepid water. To reduce
freezing of tissue, flush eyes for at least 15 minutes.
ROUTE (S) OF fN~RY: INHALATION? Yes SKIN? INGESTION?
CARCINfXSfIqICITY: NTP? No IARC MO~0~RAPHS? No OSHA? No
PAGE 1
Form ST-03435
S~TION VI--REACTIVITY DATA
~r~BILi'r~: UNS'I~BLE ( ) STABLE (X)
CONDITIONS TO AVOID: Heat and flame and ignition sources
INCOMPATABILITY (MATER/ALS TO AVOID): Chlorine, carbon tetrachloride, aluminum
chloride, nitrogen dioxide, ozone, benzoyl peroxide, brcmotrichlorcmethane, oxygen,
and strong oxidizers
HAZARDOUS D~2OMPOSITION PRODUCTS: N/A
HAZARDCUS POLY~RIZATION: MAY OCCUR ( ) WON'T OCCUR (X)
CONDITIONS TO -AVOID: N/A
S~CTION VII--SPTLT. OR LEAK PROCEDURES
S'r~PS TO BE TAKE~ IN CASE M~r~IAL IS R~.FAS~D OR SP~.L~: ~a~te ~~el ~
a ~fe ~ff~ ~. ~e all fl~s ~d i~ition ~s. S~p fl~ of gas
if ~ss~le. ~ide ~~ ~losion p~f ~tilation. U~ ~lf ~n~
bring a~at~. ~yl~e gas le~s ~ ~ de~ ~ ~t~g su~~
~s ~ a s~ ~ ~luti~ ~d chang for bubble fo~tion. ~r ~r
~ ~e ~~ e~yl~e ~n~a~on is ~1~ T.~..
~ DIS~ ~:~e e~yl~e le~g ~l~ders ~ ~ ~ust h~ or
d~d ~ l~tion. ~1~ gas ~ disc~ge at ~a~ ra~. Tag ~f~ive
~l~ders as "~f~ti~" ~d ret~ ~ s~li~. Flush le~ ~ea ~ ~ ~ray.
~c~a~ gas if ~ss~le. Foll~ F~al, S~, ~d ~1 r~ations.
SECTION VIII--SPECIAL P~ION INFORMATION
RESPIRATORY PROTeCtION: Self-contained breathing apparatus.
VENTILATION: LOCAL EXHAUST (X) Where gas is present, provide ventilatian
to keep 20% of ethylene LEL or 0.6% by
volume in air maximum.
MECHANI~ (G]~TERAL) (X) Provide adequate ventilation to keep
workplace oxygen above 18% by volume.
P~IVE GLOVES: Insulated rubber or plastic
'EYE PROTEETION: Safety goggles or glasses
OTHER PROTEL~ ~3IPM~Tf: Safety shoes, eye wash, safety shawer; Have emergency
self contained breathing 'apparatus and safety line available. Ethylene monitoring
instnanent or explosimeter to check ethylene atmosphere.
SELTION IX--SPECIAL PRECAUTIONS
PPd"]CAUTIONS TO BE TAK~ IN HANDLING AND STORING: Protect cylinders frcm physical
damage. Store in cool, dry, well-ventilated area away from sources of heat and
ignition. Do not subject cylinders to temperatures above 130°F. Isolate frcm
oxidizers, chlorine, and cambustibles. Use a check valve or trap in discharging
line to prevent hazardous backflc~ into cylinder. Cylinders must not be recharged
except by or with consent of Liquid Carbonic. Cylinders should be stored upright
and be secured to prevent falling over or being knocked over.
OTHER PPdDCAUTIONS: Use only DOT or ASME coded containers. Ground and bond all
lines and equipment associated with ethylene system. All electrical equipment
should be non-sparking and explosion proof. Perform periodic monitoring of use
and storage areas to confirm ethylene concentration is belc~ the lc~er flanmable
limit (T.~T.). Reference OGA Bulletin- SB-2 "Oxygen Deficient Atmospheres" and OGA
Pamphlet P-1 "Safe Handling of Compressed Gases in Containers."
No guaranty is made as to the accuracy of any data or statement contained herein. While this material
is fUrnished in good faith, NO WARRANTY EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS
OR OTHERWISE IS MADE. This material is offered only for your consideration, investigation and veri-
fication and Liquid Carbonic shall not in any event be liable for special, incidental or consequential
damages in connection with its publication.
PAGE 2
Form ST-03435
,:"~ 1/29/92 I Page 1
1 Site with 1 Fac. Ur,~
FEI 2 6 19 2
Ger, era 1 I r,f'ormat i o;-, ._.~l~.~ ......,.,.~ ....
I Locatior,: 290'7 L S'1'
ICc'mr'lur'ity: BAKERSFIELD S"t'A'FION 04
I
Map:
GriO:
103 Hazard: Mod?.t~ate
19C F/U: 1 AOV: 0, 0
[]or, tact Name
KEN JACKS[IN
DIANE B FLINT
TMANAG~Ri t 1 e T-'- Bus i ness Phc, ne ---7(805)24-Hour F.'hor, e]
i
IGENERAL ~(8,]5) .... '~'7-7509 x t 861.*-i472~
Administrative Data
Mail Addrs: 2907 L ST
City: BAKERSI= I ELD
Corem Code: 215-004 BAKERSFIELD STATION 04
D&B Number:
St ate: CA Zip: :]~.)i-
SIC Code:
Owr, e¥-: DIANE FLINT '"~ Phor, e: (St,~) ~,=.-..~..:
Address: 6712 DESMOND State: CA
City: BAKERSFIELD Zip: 93301-
Summary
t, KEi~ JACKSON. D~ herel:~, c~rtily th~t I have
reviewed tl~ attached h~.~rdou$ ~rial$ m~naGe-
ment plan for_ F.L. INTC0. - : ar~ ~ it e]ong v~th
any corrections constitute a complete and correct man-
agement plan for my facility.
01/29/92
P 1 ri-Re f
Na~e/Ha z ards
Ha
· I NTCO I NC 215-000-00077
Irlver~tory List ir~ MCP
(:)2 - Fixed Contair:ers on Site
Forr~l
Quar~t i t y
Page
MCP
2
02-001
ACETYLENE
Fire, Pressure, Ir~r~led Hlth
Gas
2£), 000
FT3
High
02-008 MAPP
Fire, Pressu~e, In~ed Hlth
Gas
2,879
FT3
Hi gh
02-007 PROPANE
Fire, Ir~r~ed Hlth, Delay Hlth
Liquid
500
GAl_
Hi gh
02-002 OXYGEN
Fire, Pressure, I~med Hlth
Gas
30,000
FT3
Low
02-003 ARGON
Fire, Pressure, Immed Hlth
Gas
12 ~ 000
FT3
Mirlin~al
02-009 ARGON/CARBON DIOXIDE
Fire, Pressure, Info,led Hlth
Gas
5, 000
FT3
02-005 CARBON DIOXIDE
Fire, Pressure, I~]ed Hlth
Gas
20~ 000
LBS
02-004
HELI UM
F re, Pressure, I~,~ed Hlth
Gas
10,000
FT3
M i r, i ma 1
02 -006
NITROGEN
F re, Pressure, In~n~ed Hlth
Gas
10, 000
FT3
01/29/92
INTCO INC 215
00 - Overall Site
(D} Notif. /Eva~uatior~/Medi~al
Pa ge
(1) AQenoy Notifioation
CALL 911
Employee Notif. /Evaouatior~
WE WOULD CONTACT LOCAL AUTHORITIES, CLEAR ALL PERSONS FROM OUR FACILITY AND
START NOI-IFYING 'THE OTHER BUSINESSES IN THE AREA OF THE PRESENT DANGER.
INTERCOM AND LOUD SPEAKERS ON CYLINDER DOCK AND IN WAREHOUSE, AL.L EMPLOYEES
ARE INSTRUCI'ED TO G[] TO SOUTH END OF LOT TO SIDEWALK OF GOLDEN STATE HWY OFF
RAMP'.
<3> Public Notif. /Evacuatior,
[]ALL 911
<4> Emerger, cy Medical Plar,
EMERGENCY ROOM AT SAN JOAQUIN COMMUNITY HOSPITAL
2615 EYE ST
(805) 327-1711
FIRS'[ Ail} KIT LOCATED IN MAIN WHAREHOUSE CEN'I"RAL LOCATION OR CALL 911
01129192
INTCO INC 215-000-00077
00 - Overall Site
<E> Mit igat inn/Prever~t/Abater~t
Page
4
<1> Release Prever, tion
DUE] TO THE NATURE OF OUR BUSINESS, OUR ONLY CONCERN WOULD BE THE RELEASE OF
OUR COMPRESSED GASES. TO PREVENT THIS WE KEEP CAPS ON ALL CYLINDERS AND
HANDLE WITH EXTREME CARE. IN THE EVENT OF A RELEA~.E WE NOTIFY THE FIRE DEPT
BUT, SINCE ~ THERE IS NO WAY TO CLEAN UP GAS IT WOULD JUST DISIPATE INTO THE
ATM[]SPHE RE.
ALL FULL CYLINDERS HAVE SAFETY CAPS IN PLACE AND CHAINED TO MINIMIZE CHANCES
OF FALLING OVER.
<2> Release Cor, tair,rner, t
FIRE WALL ON CYLINDER DOCK FOR FLAMMABLE GAS, FULL AND EMPTIES
<3> Clean Up
IF FLAMMABLE ACETYLENE OR PROPANE CYLINDER HAS DEVELOPED A LEAK, CYLINDER IS
MOVED TO A SAFE LOCATION AND ALL~[]WED TO EMPTY, ALL OTHER CYLINDER GASSES ARE
NONFLAMMABLE CONDENCED TO ATMOSPHERIC OR MINED GASES THAT CAN DISPLACE AiR
IN A CONFINED AREA BUT NOT HARMFULL OTHERWISE.
<4> Other Resource Activation
INTCO INC 215-000-00077~
00 - Overall Site
<F> Site Emergency Factors
Page
5
<1> Special Hazards
<2> Utility Shut-Offs
A) GAS - SOUTH END OF MAIN WHAREHOUSE IN DRIVEWAY, WEST SIDE OF BUILDING ~2
I N ALLEY
B) ELECTRICAL - MAIN BREAKER NORTHWEST CORNER OF WAREHOUSE
C) WATER - IN ALLEY WEST SIDE OF BUILDING $$2
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire Protec. /Avail. Water
PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AT VARIOUS LOCATIONS
FIRE HYDRAN]' - NORTH END OF ALLEY WEST SIDE 30TH ST
<4> Buildir~g Occupancy Level
01 / ~'.9 / 92
NTCO INC 215-000-000771
00 - Ove~-all Site
<G> Trairsir~g
Pa g e
6
< 1> Paf~e 1
WE HAVE 15 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
BRIEF SUMMARY OF TRAINING: WE HAVE SAFETY AND PRODUCT TRAINING MEETINGS
EVERY WEDNESDAY MORNING, WE ALSO HAVE AT LEAS]' I OR MORE REPRES[--NTATIVE F'ROI'~
FLINTCO ATTEND OTHER RELATED MEETINGS AND SEMINARS PUff' ON BY OTHER AGENCIES.
<2) Page 2 as rseeded
<3> Held for Futu~e Use
<4> Held fo~~ Futu~e Use
I.D. #
FORM 4A-1
NON--TRADE SECRE"£S
HAZARDOUS MATERI ALS I NVENTORY
Page
'PRINCIPAL
?
NAME: ~"_~/k',4'6~ O~,,~-- TI'TLE:O~Z=~F'~ /'//~,~ SIGNATURE:' ~_~~,'~/~4F
EMERGENCY CONTACT: ~_~'~g-//;/_,,--. · .. TITLE: ~_~/;-~F_,~. PHONE,
BUSINESS ACTIVITY:~~ c~~~~ AFT~
1 2 3 4 5 6 7 8 9 10
TYPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD D.O.T
CODE AMOUNT AMOUNT UNIT CODE CODE · FACILITY UNIT WT. CHEMIqAL OR COMMON NAME CODE OUIDE
-- g.q3~ o/ - .
. . -
/~ I
· y,/,,~,~ i~
' '/Dql
BUSINESS NAME: ~L~/V~¢~., .~/V'( OWNER NAME: ~/VT /'~'~'-..Z"/;/7" FACILITY UNIT
ADDRESS: ~"~97 6- ,-~7" ADDRESS: ~"1;'/-/~ ,4~2~:.~4'~O.rg/z~ FACILITY UNIT NAME:
cITy, ZII~: ,/.~,~',~'/'3. ~.-./~' ~-/~.~/ CITY,ZIP: /'~A"~::/2~ ~/~
PHONE *: ~2C_ ~ ~7~2,~9. , PHONE ~:Z~: og/ Io~c~,t.s~
I 'o.~Y
- 4A-1 -
usINESS NAME
BAI(ERSFIELD CITY FIRE DEPARllI~NT RECEIVED
=z3o "G" S~EET JUL 13 1987
BAKERSFIELD, CA 93301
(80~)
8~6-$9';'9
C~ ~ ............
P.
OFFICIAL USE ONLY
ID#
INSTRUCTIONS:
HAZARDOUS MATERIALS
BUSINESS . PLAN AS A WHOLE
FORM 2A
1. To avoid further action, return this form by
2. TYPE/PRINT ANSWERS IN ENGLISH.
3. Answer the questions below for the business as a whole.
4. Be as brief and concise as possible.
SECTION 1: BUSINESS IDENTIFICATION DATA
A. BUSINESS NAME: F~.,-TNT"(~
B. LOCATION / STREET ADDRESS: ~
CITY: ~K~-o ziP: ~7'~3o/
BUS.PHONE:
SECTION 2: EMERGENCY NOTIFICATIONS
In case of an emergency involving the release or threatened release of a
hazardeus material, call 911 and 1-800~852-7550 or 1-916-427-4341. This will notify
your local fire department and the State Office of Emergency Services as required by
law.
EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY:
NAME AND TITLE DURING BUS. ~RS.
B. ~7~f~Z~ ~--Z.~Z~? Ph~,~7~
AFTER BUS. HRS.
SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE
A. NAT. ~PROPANE:/~C~.~V
C. WATER: U~ .7'
D. SP SC I AL: -~o;~/;~
E. LOCK BOX: YES /~ I~ yES, LOCATION:
IF YES, DOES IT CONTAIN SITE PLANS?
FLOOR PLANS?
YES / NO MSDSS? YES / NO
YES / NO KEYS? YES / NO
- 2A -
SECTION 4: PRIVATE RESPONSE TEA~ FOR BUSINESS AS A
SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE
SECTION 6: EMPLOYEE TRAINING
EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND
REFRESHER TRAINING IN THE FOLLOWING AREAS.
CIRCLE YES OR NO INITIAL
A. METHODS FOR. SAFE HANDLING OF HAZARDOUS
~{ATERIALS ' ' ~h'~
NO
B. PROCEDURES FOR COORDINATING ACTIVITIES
WITH RESPONSE AGENCIES: .......................... (YE~'> NO
C. PROPER USE OF SAFETY EQUIPMENT: .................. ~ NO
D. EMERGENCY EVACUATION PROCEDURES: ............ ..... NO
E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: ....... NO
SECTION 7: HAZARDOUS ){ATERIAL
REFRESHER
NO
~0
NO
CIRCLE YES OR NO.
DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A
SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: ...... YES ~
I,H~/V/V~-7///// d>/~F~~ , certify that the above informatiOn is accurate.
I understand that this information will be used to fulfill my firm's obligations under
the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95
Sec. 25500 Et Al.) and that inaccurate Information constitutes perjury.
- 2B -
./
BAKERSFIELD CITY FIRE DEPARTMENT
2~30 "G" STREET
BAKERSFIELD, CA 93301
BUSINESS NAME:
OFFICIAL USE ONLY
ID#
BUSINESS pLAN
SINGLE FACILITY UNIT
FORM 3A
INSTRUCTIONS 1. To avoid further action, this form must be ~etuvned by:
2. TYPE/PRINT YOUR ANSWERS IN ENGLISH.
3. Answer the questions below for THE FACILITY UNIT LISTED BELOW
4. Be as BRIEF and CONCISE as possible.
FACILITY UNIT#
FACILITY UNIT NAME:
SECTION....I: MITIGATION, PREVENTION, ABATEMENT PROCEDb~ES'
SECTION 2: NOTIFICATION AN~ EVACUATION PROCEDb~ES AT THIS UNIT' ONLY·
SECTION 3: HAZARDOUS MATERIALS FOR THIS UNIT 05~LY
· . Facility ·Unit contain Hazardous Materials? ...... NO
If YES, see B.
If N0, continue with SECTION 4.
B. Are any of the hazardous materials a bona fide Trade Secret YES ~
If No,.complete a separate hazardous materials inventory
fomu marked: NON-TRADE SECRETS ONLY (white form ~4A-1)
If Yes, complete a hazardous material.s inventory form marked:
TRADE SECRETS ONLY (yello~ form ¢4A-2) in addition to the non-trade
secret fo~im. List only the trade secrets on fo~m 4A-2.
SECTION 4: 'PRIVAT~ FIRE PROTECTION
/~ ~~/k~z~/z:a 5 ~ ;//~¢~Zo~:' .~- :2~'/,; ~ :?~5
SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS
SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY.
B. EbECTRICAL:
C. WATER:
D. SPECIAL:
YES INO}
BOX: .I tF YES', LOCATION:
IF YES, SITE PLANS?
· FLOOR PLANS?
YES / NO MSDSs? ¥E$ .." NO
YES, ./ ..NO ,'KEYS? YES ..'" NO
Business Name:
Location: ,~--' ~' 0 "7
Business Identification No. 215-000
Station No. ~ Shift
Bakersfield Fire Dept.
HAZARDOUS MATERIALS DIVISION
Date Completed
RECEIVED
I (l'op of
Inspector
Verification of Inventory Materials
Verification of Quantities
Verification of Location
Business Plan)
Adequate
A,~'~ .....
Inadequate
Proper Segregation of Material
Comments:
Number of Employees
,,~Comments:
Verification of MSDS Availablity
/2--
Verification of Haz Mat Training
Verification of Abatement Supplies & Procedures
Comments:
Emergency Procedures Posted
Containers Properly Labeled
Comments:
Verification of Facility Diagram
Violations:
Special Hazards Associated with this Facility:
/¥7~'
All Items O.K. ~
Correction Needed ~]
White-Haz Mat Div. Yellow. Station Copy
Pink-Business Copy
Business Name:
Location: ~ ~'
Plan ID # 215-000
Station No.
Bakersfield Fire Dep
Hazardous Materials Inspection
Date Completed
(Top right comer Business Plan)
Shift f~ Inspector
Verification of Inventory Materials
Verification of Quantities
Veri of Location
Proper Segregation of Material
Comments:
RECEIVED
g~.R 1 $ I~1
HAZ MAT. DIV.
r._..
Adequate Inadequate
Verification of MSDS Availability
Number of Employees
Verification of Haz Mat Training
Verification of Abatement Supplies & Procedures
Comments:
Emergency Procedures Posted
Containers Properly Labeled
Comments:
Verification of Facility Diagram
Special Hazards Associated with this Facility:
Violations: ~
FO 1652 (Rev. 3-89) White-Haz Mat Div. Yellow-Station Copy Pink-Business Office
Bakersfield Fire Dept.~
Hazardous Materials Division
2130 "G" Street
Bakersfield, CA. 93301
HAR l~ 9 ~
A~'d
HAZARDOUS MATERIALS MANAGEMENT PLAN
INSTRUCTIONS:
2,
3,
4,
To avOicl further action, return this form within 30 clays of receipt.
· TYPE/PRINT ANSWERS IN ENGLISH,
Answer tl~e questions below for tl~e I~usiness as a whole.
Be Oriel ancl concise as possil~le.
SECTION 1' BUSINESS IDENTIFICATION DATA
BUSINESS NAME'
LOCATION:
MAILING ADDRESS: ~ O
CITY' 13~tc<¢.~-~¢,e.. \r.~ STATE:
DUN & BRADSTREET NUMBER:
PRIMARY ACTIVITY:
OWNER' it ~
ZIP: ~']3OI PHONE: ~'oS"-32.'~-73-o~
SiC CODE'
6
MAILING ADDRESS: ~, '7 / 2._ J~& $ r~ ,~,-,- ~
SECTION 2: EMERGENCY NOTIFICATION:
CONTACT
TITLE BUS. PHONE 24 HR, PHONE
G ~. ,,~ /'J~ . ~ t o ~'- 3'z '~ - '~ zo~, f~ o ~' ? z 3 - 'i ¥ ~ ?
;015~C
B~ker$~eld Fire Dept.
Hazardous Materials Divisiol
HAZARDOUS MATERIALS MANAGEMENT PLAN
'SECTION 3: TRAINING:
NUMBER OF EMPLOYESS: / ~
MATERIAL SAFETY DATA SHEETS ON FILE'
BRIEF SUMMARY OF TRAINING PROGRAM'
SECTION 4: EXEMPTION REQUEST:
I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE
REPORTING REQUIREMENTS OF CHAPTER 6.95 OF THE "CALIFORNIA HEALTH &
SAFETY CODE" FOR THE FOLLOWING REASONS:
WE DO NOT HANDLE HAZARDOUS MATERIALS.
WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO
TIMEEXCEED THE MINIMUM REPORTING QUANTITIES.
OTHER (SPECIFY REASON)
SECTION 5: CERTIFICATION:
I, I'~K,,/~.v~_ /~ 1~'1"~'[""'- CERTIFYTHATTHEABOVEINFOR-
MATION IS ACCURATE. I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO
FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND SAFETY CODE"
ON HAZARDOUS MATERIALS (DIV, 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT
INACCURATE INFORMATION CONSTITUTES PERJURY..
SIC~TURE TITLE DATE
~015e0
Bakersfield Fire Dept.
Hazardous Materiats Division
HAZARDOUS MATERIALS MANAGEMENT PLAN
Facility Unit Name:
SECTION 6: NOTIFICATION AND EVACUATION PROCEDURES:
A. AGENCY NOTIFICATION PROCEDURES: ~ / I
EMPLOYEE NOTIFICATION AND EVACUATION:
L o~ ~ ~p~
C, PUBLIC EVACUATION: ~/ /
EMERGENCY MEDICAL PLAN:
c~ll ql I
oa.~ersz.teJ, a..t,~u"e UePC.
Hazardous Ma:erials Divisic
HAZARDOUS MATERIALS MANAGEMENT PLAN
SECTION 7: MITIGATION, PREVENTION AND ABATEMENT PLAN:
A. RELEASE PREVENTION STEPS:
B, RELEASE CONTAINMENT AND/OR MINIMIZATION:
SECTION 8: UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FACILITY)'
~NAT~ RAL GAS/PROPANE:
ELECTRICAL:
WATER:
SPECIAL'
LOCK BOX:
IF YES, LOCATION:
SECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABILITY:
A, PRIVATE FIRE PROTECTION:
WATER AVAILABILITY (FIRE HYDRANT):
4.
Norfk
~D1590
· .. CITY' of BAKERSFIELD
i~bf. HAZARDOUS MATER'rALS TNVENTORY
Farm and Agriculture ri Standard Business ' NON--TRADE SECRETS
0CAIION:, ~.~5 L.
PIlUl,ll" m: -'o o o
OWNER NAME: ~(:<,,~-t ~ F,l,',~-r . NAM OF THIS FACILIIY:
STANDARD IND, CLASS COOn',~ -----
ADDRESS: · '-~71~ 0<~o~ ~ -
CITY. Z~P. nck.~f,~t~ ~0~ _ DUN AND BRADSTREET .HUHBER
.~ ~o~-~b~oas ~-~o~. coo~ ------' ....
Iuns [yqe ~a~ Avfrege Annpal MeaSure I Oys Cone Coat Coat ~sq tocqtjon_¥hece.
cool Ant Ant Est ~ Units On Site lypl Press lemp COOl , Storeo In taclml~
JPhvsicll Iod Hellth Hlzlrd C.A.S. Humber 7q-ga -2_ Component II #lmm I C.A.S. Huber
(Check all thlt ipplyJ ·
. ..,, Cosponent Il lime I C.i.$. Humber
ii,Fire HaZard ri Relctivity ri Oehyed j~$udden leleese ri Immediate
Helle#- '~ of Pressure Health
· Component 13 NIml I C.A.S. Mumber
I ehysicll IOd ~ellth'gallrd C.A.S. Kumber T '7 g~.- V=/- '7 Component II ImM I C.i,S. Kumber
(Check III thlt Ipp/yJ
.... Component 12 hmo I C,A.$, RUBber
JFire Hazard ~ Reectivity ri Delayed J~Jsudden hleese ri amneotete
. ,tilth ~ of PrlsSUrl Hel)Lb Colpoflent I] Nine I C.A.S. Number
Phv:icll lad ~elltb ~lZlrd C.~.S, Number ? -/ 2. ? - 37- ~.. Component II lime I C.A.S. Number
ICh,ok ill that iPp/IJ
Physical lad Health Valard
ICheck ell that Ipplyi
I] Fire Hazard I] Reactivity
C.L.S. KuBber
-~?~c/~ - ,~-'~- ? Component II Kill I C.A.S. Number
Component I! Kine I C.A.S. Kumber
a 0,,,,,d ~S,dd,,,,I,,,, a '.,~g~
He!lib /"~ of Pressure
Component 13 Jllml I C.A.$. Humber
EHERGENCY CONTACTS
:ertifi ratio .(Re~d and sf~n after compleCfna all sections)
.cer m~y .n~er emile o I-
l believe thmt the
IllOrllUfl,
. ,'.J,~.d..-b, ,j &,-,J-.,~ ,.'"~ ~'.'"" '""'"'" '"""'"' '0' ""'"" "'
~, ..,,,. ,,,o,.,,. ,, .., ,c..,,, ,..,,,,,,.
} , ..... ~ - ~ ~ - ~ _ ..... ~': .........
~,.~,,~ .¢,~r ..~r~ y,~:~ . ..~q~..=, . .......... ...,.. - . ..... .~. . ..... , .., . '~.'.;
~.::~ ........ ..,-~. "~.:: . . , .- ~.~ ..... , . ...._ . . . ,~ ,.,.?'L:~ .....
,,. CITY. of BAKERSFIELD
Farm and Agriculture D Standard Business ~-HAZARDOUS
MATERTALS
INVENTORY
NON--TRADE SEC,RETS
BUSINESS NAME: ~ l-c.o ~ ~. (..-
PIiOUE a: ~ · 3 ~ - ~ 3' o 5
01~NER N.AHE: J(~,,-t- /:l P l,,,-f- NAHE OF THIS FACILITY:
AODflESS.. -- 6 ?; ? o~ s.--.,, - ~ c~ . STANDARD IND. CLASS CO0~[
CITY. ZIP. ' 6~,c~,~ e?~o~ DUN ~D BRADSTREEI NUHBER ..... ,.
i erti.fjq;~Uoq .(Rel~d an.d.~fgn afl;pr .cpmplpCipg..a 1 I. sec~f.on~)
s&~4CAeo.o~cvaenU, an~ ~ac oaseo on.ay tnqu~rl 9t.cnose IA~lVlGUIll rlSpOflSlO/t lot OOClIAIA! CAI IAlOril[lOI, ! bllllVl &hlC the
Code cool AK AK Est units off I lypl s leER S~orla I~ fiClll[y
Physicll Iod flellth ~lZlrd C,A,S, Number ~ ~ H -~ - q Component II NiBI I C,i,S, N~ber
ColpOfleflt i3 Nile I C.A,S. Number
Ph~sicll Iod flellth fflllrd C.A.I. lumber- } c/;) O - } 7 - / Component II IIll I C.l.I. lu,ber
(Check III ~hlt iPP/il
Component
Number
~ Fire Hmrd ~ Reactivity ~ DH.ed ~Sudden Release
Helitb .~ of Pressure
COlpOflent 13 Kill I C,A,I, Number
Component
~ Fire Hizlrd 0 gelctivity 0 Oellyed ~Sudden geleise ~ ia~i~ :
Health ~ of Pressure
Co,pofleflt
Physical and H,HIb Uallrd C.A.S. Number ~ ~- ? ~-
[Check iii thlt IpplH
Component