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Home My WebLink AboutMITIGATION FILE #2 Permi Operate Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE i. ...~,~,~,~,~,~,~,.~,~.~,~,~,%~,,~,,,, .......... This permit is issued for the following: .:~,~/i??.???:i:ii iii!iL :,.iiii!!!!iiii~. iiiiiiiii ii?. ii:ii:~iU~ae[ground Storage of Hazardous Materials PERMIT ID# 015-021000563 ;/~ii'?i ~i,.:,ii!::i'~i';';!!!i!i[ii'~iiill'~' 'i!!i!!'::!!?i!!!i;!!i!!ii";:'i!+[!!?-:~!!i[!i i!!!!,~i! ii ~!~'~i(~anagement Program TAN H~RDOUS SUBSTANCE CAPACi~y,~ ~GAL /: .................... ~' .,,,,,,~,~E, ............. ~,,:, ..,~ANK ,~A~K PIPING PIPING PIPING PIPING ~;::":'":::.~: :" ~'~: I~EL ;:' ~~'~i~'E~,[~I~NI~bR~ :ibNi~OR TYPE TYPE METHOD ONITO ~;:::..--. :~: ~-..:, . ...... 0001 MIDG~DEUNLEADED 10,00~;~0 Gal ;:::'':l .~, D~,.~. f C~~,' ~[?'':~?' dW f PRESSURE CLM 0002 GASOLINE ARCOUNLEADE 10,000[00:GAL '~''~:":~'"'' 'DW ....... F C~M '~ ''''~ DW F PRESSURE CLM 10 ', ' . 0003 GASOLINE ARCO UNLEADE ,000'0~ :G~ ~ ~' :?'?;~;::;;'.:.;;~;~./.~/'.~; .DW . .F., ,~:::d?'.'.L..~,"';:':.~,::CLM ./~"~/~ }~?? DW F PRESSURE CLM 0004 GASOLINE ARCO sUPER UN 10,000.00 'GAD~ ~'::;'~;~ ~'~;~;/;;~:;?'?::';:;:: :"DW' ;~ ~iF '~ ~::~;''~;~; ~?:~ ~CLM ~¢~ '':':~ ~'~' DW F PRESSURE CLM Issu~ by: ~~ B~ersfleld Fke Depa~ment Approved by: ~~~' O~ICE OF E~R ONME~AL SER ~CES 1715 Chewer Ave., 3rd Floor F ~P~e ~;~~ Voice (805) 326-3979 F~ (805) 3~-057~ Expiration Date: ~Un~ 30~ ~OOO D ICA Cert. No. 00746 City of Bakersfield Office of Environmental Services 1715 Chester Ave., Suite 300 Bakersfield, California 93301 (805) 326-3979 An upgrade compliance certificate has been issued in connection with the operating permit for the facility indicated below. The certificate number on this facsimile matches the number on the certificate displayed at the facility. Instructions to the issuing agency: Use the space below to enter the following information in the format of your choice: name of owner; name of operator; name of facility; street address, city, and zip code of facility; facility identification number (from Form A); name of issuing agency; and date of issue. Other identifying information may be added as deemed necessary by the local agency. This permit is issued on this 2nd day of November, 1998 to: AM PM MINI MARKET #6218 Permit #015-021-000563 4203 Ming Ave Bakersfield, California 93309 SITE MAP ALBERTSON ' S STORAGE 8 IRESTI SALES AREA IEMERGENCY PUMP SHUT-OFF SWITCH LOCATED NEAR CASHIER INSIDE SALES AREA GAS ISLAND i/IOK \ ~, FL / / IOK ! FL I / 8K ~ ~, FL /I GAS ISLAND DRIVEWAY DR I VEWAY MT. VERNON AVENUE O MAIN ELECTRIC PANELS MAIN WATER VALVE FIRE HYDRANT Business Name: Address: Phone: AM/PM MINI MARKET//534 2698 Mt. Vernon Avenue, Bakersfield, CA 93306 [805] 872-5862 DRIVEWAY STOR SALES AREA ,/ [GAS ISLAND GAS ISLAND DRIVEWAY PSI #535 4203 MING AVE *NOT TO SCALE N MAIN ELECTRIC PANEL LOCATED AT SE CORNER OF LOT WATER VALVE MAIN SW CORNER OF LOT FIRE HYDRANT PLANTER ON NW CORNER OF LOT MING AVE SITE MAP DRIVEWAY SALES AREAI / I I GAS FSLAND I I PL GAS ISLAND DRIVEWAY MING AVE MAIN ELECTRIC PANELS MAIN WATER VALVE FIRE HYDRANT Business Name: Address: Phone: AM/PM MINI MARKT #535 4203 Ming Avenue, Bakersfield, CA 93309 [805] 834-1076 ! ! MING A VENUE ~rmer Tank Location TPHG= 1 000 . (approximate limits) _~B4 Sidewalk F _ _ ,,o-;,.-; - ~ - _ ~ B~B7 8 TPHG=IO00 . approximafe limits) Poll Box~ LEGEND N Boring Location Boring Location Showing Bottom- hole Deviation Proposed Boring Location SCALE~ 40' 0 20' 40' .022 s,TE, ARCO SS #6218 ~% 0658 S~TEbnO Bakersfield, California MAP TYPE: Proposed Borin9 Locotions I)RAWN 3Y, I ])ATE, I^PP~OVED SY' I ~)^TE' SAB 2/92I JDP 2/92 REV I REVISION DATE BY ,,~o d'2 / &' KERN COUNTY ENVIRONMENTAL HEALTH DEPARTMENT INVESTIGATION RECORD DBA OWNER ADDRESS ADDRESS ASSESSORS' PARCEL # CT CHRONOLOGICAL RECORD OF INVESTIGATION DATE MC:cd F7 ,i KERN COUNTY ENVIRONMENTAL HEALTH DEPARTMENT INVESTIGATION RECORD DBA OWNER .ADDRESS ADDRESS ASSESSORS' PARCEL # CT CHRONOLOGICAL RECORD OF INVESTIGATION DATE MC:cd I I I I Prestige Stations Incorporated Hazard Communication Program am/pm & Conventional Stations I :1 I I I I ! I I I I I I i I I I I I I I i I I PRESTIGE STATIONS, INCORPORATED HAZARD COMMUNICATION PROGRAM I I ! I I I t i ! I I ! I I PRESTIGE STATIONS, INCORPORATED HAZARD COMMUNICATION PROGRAM GENERAL This written Hazard Communication Program describes hoB Prestige Stations, Inc. will communicate to Prestig~ employees and Prestige contractors the hazards of chemicals they may be-exposed to in the workplace. It is the Facility Manager's responsibility to insure that all employees who may be exposed to hazardous chemicals are properly trained as outlined below and that all program components are implemented and kept up-to-date. LIST OF HAZARDOUS CHEMICALS A hazardous chemical includes any chemical which is a physical haz'ard or a health hazard. Chemicals considered to be physical hazards include combustible liquids, compressed gases, explosives, flammables, organic peroxides, oxidizers, pyrophorics, unstables and water-reactives. Chemicals considered to be health hazards include carcinogens, corrosives, toxic or highly toxic agents, irritants, sensitizers and target organ effect toxins such as hepatotoxins, neph=otoxins, neurotoxins, hematopoietic system and reproductive toxins and other chemicals which damage the lungs, skin, eyes, or mucous membranes. Definitions of the above types of physical and health hazards are Presented in Attachment 1. Employers must' maintain a list of hazardous chemicals in the workplace and ensure that there is a Material Safety Data Sheet (MSDS) on-site for each hazardous chemical. Attachment II is a list of hazardous chemicals typically present at Prestige workplace along with designations as to whether these chemicals are considered to be hazardous and the MSDS number for each hazardous chemical. It is the Facility Manager's responsibility to ensure that if different hazardous chemicals are present, that the list is revised and that additional MSDS are obtained. MATERIAL SAFETY DATA SHEETS ARCO Petroleum Products Company (APPCo) has prepared MSDS for ARCO gasolines and diesel products. Lyondell Petrochemical Company, another division of Atlantic Richfield i I I I :i I I Company, has prepared MSDS for motor oils and other Petrochemical products. The responsibility for preparing Purchase Stock MSDS rests with the manufacturer. A periodic review of APPCo, Lyondell and Purchased Stock MSDS will be performed to ensure these sheets are adequate; and that sheets for new hazardous chemicals are included, especially MSDS which reveal new risks or protective measures. Copies of 'MSD$ for hazardous chemicals present ~in the workplace are shown in the Appendix to this booklet. This booklet will be maintained in the workplace, will be accessible to employees throughout each work shift. Employees will be trained in its availability and contents as outlined below. WORKPLACE LABELING It is the Facility Manager's responsibility to ensure that all gasoline pumps are adequately labeled concerning the .health hazards of gasoline. Regarding purchased stock, including APPCo and Lyondell products, it is the manufacturers responsibility to ensure that container labels adequately warn of the hazards of their products. TRAINING Ail employees who may be exposed to hazardous chemicals will be trained in the contents of both this written Hazard Communication program and the pamphlet "What's It All About? The OSHA Hazard Communication Standard". Of particular importance is employee knowledge of the hazardous of chemicals in the workplace (e.g. gasoline) and the proper use of Material Safety Data Sheets (which is explained in the pamphlet). Prestige training for Facility Managers shall include instruction in this program and in the manner in which employees which he supervises are to be trained. It shall then be the responsibility of Facility Managers to train employees in the workplace he supervises. This training shall include: 1) The requirements of this program 2) The operations in the employees work area where hazardous substances are present 3) The location and availability of this document, the chemical lists and MSDS's 4) The way to detect the presence or release of hazardous chemicals -2- I I I 5) Physical and health hazards 6) Protective measures Training materials covering these matters will be prepared, revised from time to time as may be appropriate, and provided to Facility Managers. The Facility Manager will distribute these materials to employees, or otherwise make them available to employees, and assist the employee in understanding these materials. CONTRACTORS Prestige shall inform contractors by giving them a copy of the attachments to this document and any appropriate training materials. It is the contractors obligation to inform and train his employees. Contracts will be requested to advise the Facility Manager concerning any hazardous chemicals the contractor brings into the workplace, to which Prestige employees may be exposed. The Facility Manager shall then advise other employees. It s~.all be the responsibility of the Prestige employee who enters.a contract to insure that, in a timely way, the appropriate information is provided by Prestige to the contractor and that any information obtained, from the. contractor is made available to the Facility Manager. -3- ! I I I I I I I i I I I I 1 I I I I ATTACtD~N? I I pHYSICAL/HF. ALTH HAZARDS I I i Any liquid My·ns a flashpoiat it ac above 1O0O (]TAoC:) IMJt below 2OC)OF (93.3oc:) except &ny mix~u~ hay·ns components vizh fliJhpoiAts of 20Qc'F or hi~hef, ~ tOt~ volume of which make up 99% ac mace of ~ totll volume of iht mixture. (~) A tls or mixture of loses havifll, in & coflu~ner, ia absolute prenure exceed·al ~0 ps~ &t 70ol, (21.Loc). I (ii) ^ lis or mixture of loses hay·tiS, ia · container, ia absolute p~uure exceeclifl$1Of6 psi &t 130OF (J~.~oc) re$irdleu of the pressure at 70oFj I Or (La) A nq~d havinS · vapor pressure exceed·as m0 psi it 100°F O7,1°C1 as determined by ASTM 0-323..72. 3. Ex~losiv~ A chemical that causes · sudden, almost iasy~3nteneous release of pressure, ins and heat when subjected to sudden shock, pressure, or' hiSh temperature. ~. F]~mmlbb~ A chemical ~at fills into one of ~e followinS catesories: "Aerosol, fl·tamable" me&ns an aerosol that, when tested by the method described in 16 CFR 1~00.~, yields a fl·me projection exceediflS 15 inches ·t full valve openin$, or · f¼shback (· fl·me extend~nS back to ~e valve) ·t Any desree of valve oper~ns: (ii) "~as flimm·ble" meiasz A Sis 1hit, at ambient temperature and pressure, forms flammable mixture witJ~ air &t · concentration of t~rt. een (13) percent by volume or less; or {iii) (~) A Sas ~t, at ambient temperature and pressure, forms · ranie of. flammable mixtures wiff~ &~r wider thin twelve (12) percent by volume, resardless of the lower l~mit~ "Liquid, flammable" means any liquid havinS · flashpoint below lO0°F (37.ZoC), except &ny mixture h&vin$ components with flashpoints of 10:o (37.soc) or I~lher, tAe total of wl~c~ mike up 99 percent or more o! the total volume of t~e mixture. ATTACI.,R4ENT I 0 "S~lid,' flammable" means · solid, other than a blLqtinS Ipnt or explosive u defiMd in l~10.10~(a), that is liable to calm fire throulh frictim, Ibsorption of moisture, spontaneous chemical chaflie, or retained heat from manufacturinS or ptocessifls, or ~ich can be isnited reldily ~nd when if/tiled btu'ns so visorously and persistently as to crease i serious hazard. ^ chemicil sAiII be cmuidered to be a flammable s~lid if, when tested by the meuhod described in l& CFR 1,:~00.~, it isrdtes and burns with a self-sustamod flame az a ram Stealer than one-tenm of an inch per second &ionS iU m~jor axis. An orsanic compound that contains the biY&ieflt o 0 - 0 * structure and which mi), be considered to be a structural derivative of hydrosen peroxide where om or bola of. ~ hydrosen atoms has been replaced by an orlaflic radical. Means a chemical other than a blLqthn$ a~ent or explosive ihat lflitlatus or promotes combustion in other materials, thereby causiflS. fire either-of itself or throush the release of ox¥sen or other SIses. I I Pyro~c Means a chemical that will isnite spontaneously in or it a temperature of 13001:. C~f,.~oc) or below. Urutable (reK~ive) I I I Means a chemical which in pure state, or as produced or transported, will visorously Poiymerize, decompose, condense, or become self*reactive under conditions of shocks, pressures, or temperature. ~. Watet-ruactive Means a chemical that reacts with water to release a Sas that is either tZamma~le or presenU a health hazard. I I HEALTH HAZARDS chemical is considered To be & carcinosen if: (a) has been evaluated by the International Asency for Reseatch on Cancer (IARC), and lound to be a carcinosen or potential catcihosefl; or (b) It is listed Lq a carcinogen-or potential carciflosen in me Aflflu&l Report I, of Carcinosens publi~d ~ Natio~ (~P) by Tomcolosy Prosr~ films: e~on); or (c) It is res~dated by OSHA is a carcinosen. ATTACt91ENT I I ! ! I A chtmi,*st tf~t causes visible destl~ctiafl of, or ir~ver~ble ~Mra~s in, liv~l ~ by ~mi~ ac~im at ~ ~m of c~uc~ F~ e~ple, i ~bi~ ra~iU by ~ me~ ~i~ ~ ~ U. S. ~~eflt of Trans~ru~ ~ App~x A to ~t ~ Piti 173, it ~s~ys ~ ~ps irmve~ibly ~ st~ of ~ ~s~ at ~ ~m of c~ fdl~I ~ ex~u~ ~ri~ of fo~ hour. ~ m~ ~1 ~t refer to ~m ~ Hlddy ~oxtc A chemical fallifl$ within any of the followin$ camlories: (a) A chemical that his a median lethal does (LD~0) of ~0 millilrams or less per kilolrim of body veilht when administered orally to albino rats veilhinS between 200 and ~00 Irams each. (C) A chemicLI that. has a median lethal doss 0.D~0) of 200 millllrUms or less per kilosram of body weilht vben administered by c,fltirmous co.~tac~ for 2~ hours (or less it. de·th occurs within 2~ hours) with the bar~ skin of albino rabbits weilhinI between two and three kilosrams each. A chemical that has · median lethal concentration (LC~o) in &ir of 200 ihtrts per million by volume or less of Sas or v·por, or 2 milliSrams per litar or less of mist, fume, or.dust, when administered by continuous in.~alatiofl for one hour (or less if death occurs within one hour) to albino rats veilhins between 200 and ~00 st·ms each. ~. Irt&tent I, A chemical, which is not corrosive, but which causes · reversible inflammatory eifect off livins tissue by chemical action at the site of ~ contact~ A chemical Ls a skin irritant ii, when tested off the intact skin of albino r&bbi~ by the methods of 16 CFR 1~00.~1 for four-hours exposure or ;~· by other appropriate techniques, it results in an empirical score of five or more. ^ chemical is an eye irritant if so determined under the procedure i listed in l& CFR 1~00.~2 or omer. appropriate techniques. A chemical that causes · substantial proportion of exposed people or animals to deve.'3p afl allersic reaction iA normal tissue after repeated exposure to me G~emical. 6. .Toxic i (a) A chemical ~at ~as · median lethal dose (LDs~) of more than ~0 miilisrams per kilosram but not more than ~00 miihsrams per kLlosram o.' body wei[ht when administered orally to ilbino rats we&shins i between 200 afld 300 ~rams each. A.,'.'.'~~ 'ri I it ! I 1 I 1 i I i I I i 1 I I, I Prestige Stations, Incorporated Typical AM-~ Conventional Station List of Hazardous Chemical Product ARCO Clear Gasoline ARCO Diesel ARCO Gasoline ARCO Supreme Motor Oil SAE 30 ARCO SupremeMotor Oil SAE 10w-30 ARCO Unleaded Supreme Gasoline Manufacturer ARCO Petroleum Products Co. ARCO Petroleum Products Co. A~OPetroleumProducts Co. Lyondell Petrochemical Co. Lyondell Petrochemical CO. ARCO Petroleum Products CO. MSDS 306 341 304 793 791 252 I I B 1 I I I APP~qDIX MATERIAL SAFETY DATA SFm~TS MATERIAL SAFETY DATA SHEET ARCOCLEAR' GASOLINE MSDS No. APPC 306 Rev. Date 06/12185 ARCO PETROLEtM PRODUCTS C01~ANY DIVISION OF ATLANTIC RICHFIELD COMPANY SIS SOUTH FLOWER STREET LOS ANGELES. CALIFORNIA 90071 IMPORTANT: Reid this MSD8 ~ ~ lad dlalmitng of thi~ im)cluct Ind'lml~ ~ into~n on to OIHA ~ ~m~n R~ Ti, ada Telephone Numbers Name &RCOCLEAR GASOLINE OR ARCO UNLEADED GASOLINE EMERGENCY 800/,424-9300 CHEMTREC Other Names UNLEADED MOTOR VEHICLE GASOLINE 3:12/2t0-3000 COMPANY UNLEADED REGULAR GASOLINE OR PETROL CUSTOMER SERVICE 213/486-825B INFO ONLY Chemical I DOT Hazardous Materials Proper Shipping Name Family HYDROCARBONS WITH ALCOHOLS AND/OR ETHERS ~1 GASOLINE * I Generic Mime I DOT Hazard Clall PETROLEUM NAPHTHAS (BLENDED) I FLAMMABLE LIQUID CAS No. SEE SECTION IX lID No. 0116001160 UN/NA ID No. UN 1'203. · .... "1'1'" ' '' ' '1 ..... "'' ''" ...... ' ' '1'" .... '"' "' ' ......... ..... I" ..... ' ...... "'' '''' ' '"l ..... '"]'" '1'1'[' '"1' '" "' ']'"r' ' ' "'" ' ' ' 'l'l'l' ' '1' '1' "" '' ..... EXTREMELY FI, JJIMII,E'! 0SHA/NFPA C~LSS-Z'A IIrI, MIMILE LZQUZD. KEEP AYAY PROM NEAT, SPARKS, AND OPEN FLAIdE. NAY CAUSE IRRITATION TO EYES, SICZN, MI) RESPIRATORY SYSTEM! AVOID LIQUID, MIST, AND VAPOR CONTACT. YASH 114OROUGHLY AFTER IM/OLZNG. NAY BE HAIMFUL ZF ZldaAJ. ED Bit ABSORBED THIGIJGH SKZNI AVOID BREAllaZNG VAPORS OR MIST. USE ONLY ¥Z1~1 ADEQUATE VENTILATION. LONe-TERN EXPOSUIE TO CDNPLrrELY VA/K)IZZED GASOLINE HAS CAUSED ZN lABORATORY ANIMALS. VAPORS OR LZQUZD PEMETRATZCW OF SKIN CAN CAUSE CENTRAL. NERVOUS SYSTEM (CMS) DEPItESSZON AND/OR SYSTERZC EFFECTS. HARMFUL OR FATAL ZF SYALI. OVED! CONTAINS PEIltQLEUN DZSTZLI. ATES! ZF SYALI. OVED, DO NOT ZN[XJCE VOMITING SINCE ASPZRATZON INTO 114E LtJNGS ¥,ZLL CJ~JSE CHEMICAL PNEUNDNZA. OBTAIN PROMPT MEDZCAJ. ATTENTION. KEEP (Xrl' OF REACH OF CNZI.DIEN! Flash Point (Metho~ Autoignition Temperature LMetho~ I FiammlOle Lim,~ 4% VOL in I At Normal Atml~eric Ti~rat~e KO Pres~re AP -4S'F '(Ob~8) GT 6~'F (E-GIg) IL~ AP 1.3 U~er AP 8.2 SEE "F~RE & EXPLOSZ~ HAZARDS" BASED ON ACTUAL LAS TESTS I BASED 0N ACTUAL LA8 TESTS I EXTREMELY FLA~ABLE'I THZ.S MATERIAL RELEASES VAPORS AT 0R BELO~ AMBIENT Fire and TEMPERATURES. ~EN MIXED V.ZTH AIR ]N CERTAIN PROPORTZONS AND EXPOSED T0 AN Explosion [GNZT]0N SOURCE. THESE VAPORS CAN BURN :N THE OPEN 0R EXPLODE IN CONFINED Hazards SPACES. BEING HEAVIER T~N J.ZR. FLAWABLE VAPORS MAY TRAVEL LONG 0]STANCES ALONG THE GROU~ BEFORE eEACHZNG J COUNT 0P ZGNZTZLON AN0 FLASHING BACK. 'Extinguishing :Media FOAM CD2 DRY CHEMICAL HALON CONSULT F0&M MANUFACTURERS FOR APPROPRIATE MEDIA. APPLICATION RATES, AND WATER/FOAM RATIO. Special Firefighting Procedures SEC~ SUB-SURFACE APPLILCATZON IS ONLY RECOMMENDED WHERE IT ZS KNOWN THAT THE FUEL CONTAINS LESS THAN 3% OXYGENATED BLENDING COMPONENTS.. FOR FIRES INVOLVING THIS GASOLINE, DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT. THIS MAY INCLUDE SELF-CONTAINED BREATHING APPARATUS TO PROTECT AGAINST THE HAZARDOUS EFFECTS OF COMBUSTION PRODUCTS AND OXYGEN DEFICIENCIES. WATER FOG OR SPRAY ARE OF VALUE FOR COOLING TANK SHELLS AND SURFACES EXPOSED TO FIRE. BUT MAY NOT ACHIEVE EXTINGUISHMENT. 2B :--:7OR 'DISCLAIMER OF LIABILITY,' SEE THE STATEMENT ON PAGE P~gt 1 of ARCOCLEAR GASOLINE MSDS No. API)C 306 Summlry of LIQUID, MXST OR VAPORS CAN CAUSE EYE, SKTN AND RESPIRATORY TRACT ~RR~'TAT1~ON Acmte H~ A~ CNS DEPRESSZ0N. ASPZRATZON INTO LUNGS ~ZCL CAUSE CHEMICAL PNEU~NZA. ROUTE OFEXPOSlJRE SIGNS AND SYMPTOMS EXPOSURE CAN CAUSE IRRITATION TO THE NOSE. THROAT. & LUNGS AND SIGNS OF CMS Inhllation DEPRESSION (DIZZINESS. DROWSINESS. LOSS OF C00RD~NATX0N. COMA AND DEATH). DEPENDING ON THE CONCENTRATION/DURATZON OF EXPOSURE. (SEE *SUMMARY' BELOW.) PrimMy Route~s~ Eye M~LD EYE IRRZTATZON MAY RESULT FROM CONTACT W,ZTH LIQUID. MIST. AND/OR ¢ont~t VAPORS. [] Skin LIQUID CAN PENETRATE SKIN TO CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. Abiorp~on VAPOR PENETRATION CAN ALSO CAUSE SYSTEMIC EFFECTS. [] Skin Irritation SKIN ZRRZTATZON LEADING TO DERMATITIS NAY OCCUR UPON PROLONGED AND REPEATED CONTACT DUE TO SKZN DEFATTZNG. ZRRZTATTON OF THE MOUTH, THROAT & GASTROINTESTINAL TRACT LEADTNG TO NAUSEA, Ingeitiofl VOMITING. DIARRHEA AND RESTLESSNESS. CNS DEPRESSION SIMILAR TO THAT CAUSED [] BY VAPOR INHALATION. ASPTRATZON ZNT0 LUNGS WILL CAUSE CHEMICAL PNEUMONIA. AN A.P.I.-SPONSORED STUDY HAS SHOWN THAT RATS AND MICE DEVELOPED CANCER ~m~ of FOLkOVZ~ C~ZC Z~kATZ:ON EXPOSURE TO THE VAPORS OF UNLEADED ~SOLZNE. C~onic ~MLO~-TERM EXPOSURE TO UNLEADED ~SO~ZNE ~S A~SO PRODUCED KIDNEY DAMAGE ZN LABORATORY ANIMALS. THE EXACT RE~ATZONSHZP BETWEEN THESE RESULTS ~tM ~ POSSZB~E ~AN EFFECTS Z'S ~T ~. PERSOWEL VZTH FRE-EXZSTZ~ SKIN Eff~ DISORDERS. Z~&ZRED ~ZVER OR KZ~EY F~TZ~. OR CE~R~ NERVES SYSTEM CHR~ZC RESPIRATORY DISEASES S~U~ AVOID EXPOSURE TO ~ZS ~TERZA~. · .**'.'~*~'~'~*:*.*~'~'~'~':'~*:':':*'*:' '.'~'~'~'~'~**':'.'~':'~'~*:C'~'~'~'~':*~'~- '~-~'~'~*.':'~'~'.'.'/:*~':*~*. '~*.'.*~'~'**:'~'~C'~'. ~'~' '.'~ ............................. ~' -~ .............................. :.:.~..?.........:........... :.F.....~...?. .?....:........?.~..:.~...;....?-.??~.~?..~.;.?~.?~.?..-.??:.?~ ..~.%...?;.??..-.....?..???????..~.~ -.:.:.'.?:.'.?~.??~.?:.??????:.?-.:.?:.:~'.~.~.'.:.-.~.'.~.'.: :.:.-..... · · USE NZOSH/MS~-APPROVED RESPZRATOR ~EN VAPOR LEVELS EXCEED EX,SURE K~lt~ ZN SECTZ~ VZ. USE FULL-FACEPZECE ~SK A~VE ~ ~ ~SOL~NE VAPORS. SUPPlIED-AIR 0R SC~ E~ZPMENT ABOVE 1~ P~. (SEE 'OT~R' BOX BE~0V.) EYE P~TECTZON ~LD BE ~RN ~ENEVER ~ERE ZS A LZKELZ~ OF SP~ASHZK Eye 0q SFRAYZ~ LZ~ZD. C~ACT LENSES S~ULD ~T IE K~. SUZT~LE EYE MASH WATER S~U~D BE AVAILABLE. AVOID PROLO~ED A~/OR REPEATED SKZN CONTACT. ZF ~ZTZ~S OR FRE~ENCY Skin OF USE MAKE CONTACT SIgnIFICANT. CLEAN A~ ZMPERVZ~S PROTECTIVE SUCH AS G~OVES. APRON. BOOTS. A~ FACIAL PROTECTION S~ULD BE WORN. E~i~Ing USE ADE~ATE VE~ZLATZ~ TO KEEP VAPOR C~ENTRATZONS OF THIS Co~ols BELOW THE OCGUPATZ~L EXPO~RE LIMITS S~ BELOW ZN SECTZON VI. (SEE SECTION XZ.-'GENERAL C~E~S~,.~) USE ~OD PERS~ HYGIENE PRACTICES. ZN CASE OF SKZN CONTACT. WASH ~ ~tMe MZLD SOAP A~ WATER OR A WATERLESS ~ C~EANER. ZWEDZATELY RE~VE SOAKED C~OTHZ~ A~ WASH T~RWLY BEFORE REUSE. DISCARD ~SOLZNE-SOAKED S~ES. Wo~ ~m RESPZRAT~ USE ~ G~LY VZTH OSHA STA~ARDS. C~TROL ~GUPATZ~L EXPOSURES BELOW t P~ 'BENZENE' RATHER THAN THE 3~ P~M '~SOLZNE' T~V. NEVER SZ~ ~SOLZNE BY KUTH. SEE SECT,.ON X~T F~R A~D~T~NA~ ~NF~RMAT~N. I I[ Ill'lTl lilt II ' '1 '1 II I '1 I1111[ *1 I II .... IIIIIIIIITII'II I[ Source D4te TYIN Vllue/Units Time ARCOEL 1883 TVA I PPM 12 HRS PEAK 2S PPM 15 MXN ACGZH 188S TLV 10 PPM e' HRS STEL 2S PPM 15 MZN ACGZH 1985 TLV 300 PP# 8 HRS STEL 5C)0 PPM 15 ACGZH 1SIS TLV 200 PPM 8 Hr STEL 250 PPM 15 ~ ACGZH IBiS TLV 10OO PPM 8 ~ ACGZH 18~5 TLV 100 PPM STEL t~O PPM Subitinci BENZENE (ADOPTED BY ATLANTIC RICHFIELD) BENZENE (TYPE "A2' CARCINOGEN) GASOLZNE (SEE SECTZON XZ.) METHYL ALCOHOL (METHANOL) - SKZN ETHYL ALCOHOL (ETHANOL) TERT-BUTYL ALCOHOL (TEA) P~ge 2 of 4 15 MZN ! 1 I I I I 1 t AECOCLEAR' GASOLINE MSDS No. APPC 306 Rev. Date 06/12/8S ::L:::::::::::::::::::::::::::::::::::::?:: :::::::::::::::::::::::::::::::::: :Emergen and: Flrlt: d:: ::::::: ::::::::: :::: :.:::i:!: :?!:!:!:::::?'::.:::!:!'.' · ::::::-:;"::::::?":i:::::':?:::::::::;::"::" ' . '. .' .:.-.":: · ' :.. ":===============================:::':'":':::':' :'"""::""-'":" ' ' ' · IMMEDIATELY MOVE PERSONNEL TO AREA OF FRESH AIR. FOR RESPIRATORY 13ISTRE$S. Inhalation Eye Contest Skin Contad Ingestion Emergency Medical Treatment Proeedures GIVE AIR. OXYGEN, OR ADMINISTER CPR (CARDIOPULMONARY RESUSCITATION). IF NECESSARY. OBTAIN MEDICAL ATTENTION IF BREATHING DIFFICULTIES CONTINUE. FLUSH WITH CLEAN LOW-PRESSURE WATER FOR AT LEAST 15 MINUTES, IF IRRITATION PERSISTS. OBTAIN MEDICAL ATTENTION. IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH AFFECTED SKIN THOROUGHLY wITH SOAP AND WATER. ZF IRRITATION PERSISTS. SEEK MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE, BUT DISCARD CONTAMINATED LEATHER SHOES/GLOVES. DO NOT INOUCE VOMITING, SINCE ASPIRATION INTO THE LUNGS WILL CAUSE CHEMICAL PNEUMONIA. IF ASPIRATION OCCURS, PROMPTLY OBTAIN MEDICAL ATTENTION. SEE ABOVE PROCEDURES. CONTAIN SPILL. REMOVE ALL IGNITION SOURCES AND SAFELY STOP FLOr OF SPILL. IN URBAN AREAS. CLEANUP AS SOON AS POSSIBLE:; IN NATURAL ENVIRONMENTS. SEEK Preemattolv~ ADVICE FROM ECOLOGISTS, EVACUATE ALL_ NON-ESSENTIAL PERSONNEL. USE PROPER if Materiel PROTECTIVE EOUIPMENT. BLANKET VI-TH FOAM OR USE YATER FOG TO DISPERSE is SI)iliad VAPORS. PADS AND ABSORBANT MATERIAL CAN BE USED. GASOLINE YZLL FLOAT ON or Released WATER AND RESULTING RUNOFF MAY CREATE AN E.XPLOSION OR FIRE HAZARD. COMPLY M,ITH ALI. APPLICABLE LAYS. SPILLS MAY NEED TO BE REPORTED TO THE NATIONAL RESPONSE CENTER (800/424-8802). GASOLINE OR CONTAMINATED MATERIALS NAY BE HAZARDOUS TO HUMAN AND OTHER LIFE. Waste Disposal Methods MAXIMIZE PRODUCT RECOVERY FOR REUSE PRIOR TO DISPOSAL. DISPOSE OF PRODUCT, CONTAMINATED MATERIAL, AND STORAGE TANK MATER BOTTOMS AS AN EPA "IGNITABLE HAZARDOUS WASTE" (DOD1), UNLESS PROVEN OTHER¥ISE. USE APPROVED TREATMENT, TRANSPORTERS, AND DISPOSAL SITES IN COMPLIANCE ¥ITH ALL LAWS. TANK BOTTOMS ANO TANK WATER BOTTOMS MAY BE HAZARDOUS TO HUMAN, AN[MAC AND AQUATIC LIFE. IF SPILL IS INTRODUCED INTO A WASTEWATER SYSTEM. THE CHEMICAL AND BIOLOGICAL OXYGEN DEMAND ~ILL LIKELY INCREASE. SPILL MATERIAL IS BIODEGRADABLE IF GRADUALLY EXPOSED TO MICROORGANISMS. A POTENTIAL DISPOSAL METHOD IS INCINERATION. ;Component Name HYDROCARBONS WITH A BOILING POINT RANGE OF ?O'F. TO 440'F. METHYL TERTIARY-BUTYL ETHER (MTBE) GASOLINE-GRADE TERTIARY-BUTYL ALCOHOL ETHANOL METHANOL BENZENE ~ I~ Ciret.o~M N/AP AP 1634-04-4 N/AP AP ?5-65-0 N/AP AP 64-'17-5 N/AP AP BT-SO-1 N/AP AP ?'I-43-2 1,2, .4 LT COml)Osition mount IVoL) (See Qualification on Peas 4) BR TO 99 PERCENT 0 TO 11 PERCENT 0 TO 10 PERCENT 0 TO 10 PERCENT 0 TO S PERCENT 5 PERCENT #~istMliy~. I = I/TI), 2 · IJ. qC. S · O~I~K, 4 · C)thlt 29 Comllolttionl given ire tR)iMI vlluel, not IpeeificitioaL P~ge 3 of ARCOCLEAR GASOLINE MSDS No. APPC 306 Boiling Point Viaooeity Units, Temp. (bleNd) Dry Point AP ?0' TO 440'F FrHzing Point N/AP Specific Gravity (N,O · I it 39.2'R AP 0.72 TO 0.?? " N/AP VeoorPreasure (REZD-PSIA AT IOO'F) AP 8 TO 15 VN)or S%.G 5. (Air. 1.0 at SO'-OO'lRlSold)ility in Water AP . I SEE BELO,. AP 430'; Volatile Char~*teriitics APPRECIABLE N/AP Hazardous Polymerization Other-ChemifllRiict~ity Stability NOT EXPECTED TO OCCUR N/P ST&BLE Other Phylifll rATER ~N CONTACT VZTH OXYGE~TED ~SOCZNE CAN CON- and C~i~l ~i~ TAZN UP TO 8~ OXYGE~TE & HYDROCARBON ~TERZALS. Ap~inoe COLORLESS TO STRA~-COLORED LZ~ZD; a~Odor PETROLEUM NAPHTHA OOOR. HEAT, SPARKS, A~ OPEN F~AME, Conditions to Avoid Materiels to' Avoid Decoml~oaltion l~'odu~ts ' AVOID CONTACT YZTH YATER. REACTS YZTH STRONG ACIDS AND STRONG OXiDiZiNG MATERIALS. BURNING OR EXCESSIVE HEATING MAY PRODUCE CARBON MONOXIDE AND OTHER HARMFUL GASES AND VAPORS. :...X.L::::::::::::::::::::~:::::::::::::::::::::::::~:::::::::::::::~:::~:::::~:~:::::::::::::~::~dd~t~::~~:~:::::::::::::::::::::::::::::~:~:::::::::::::::::::::::::::::::::::::::::::::::::~::::::::::::::::~ STORE AND TRANSPORT XN ACCORDANCE WiTH ALL APPLICABLE LAt/S. KEEP AYAY FROM HEAT, SPARKS, AND OPEN FLAME I KEEP CONTAINERS CLOSED &NC) NOT iN CLOSED VEHICLES. CONTAINERS SHOULD BE ABLE TO t/ZTHSTAND PRESSURES EXPECTED FROM t/ARMiNG OR COOLING IN STORAGE. GROUND ALL DRUMS AND TRANSFER VESSELS MIEN Handling, HANDLING. THE PRESENCE OF BLENDING COMPOUNDS iN THiS GASOLZNE MAY REQUIRE Storage USE OF SPECIAL PROCEDURES AND PROTECTIVE EQUZPMENT FOR TANK, VESSEL, OR and OTHER ENCLOSED SPACE ENTRY. REFER TO AMERICAN PETROLEUM INSTITUTE PUBLiCA- Decants- TIONS RP 201S AND 2015A FOR SPECIAL PRECAUTIONS. ALL ELECTRICAL EQUIPMENT mination TN GASOLINE STORAGE AND/OR HANDLING AREAS SHOULD BE ZNSTALLED iN ACCORDANCE Procedures t/ITH APPLICABLE REOUZREMENTS OF THE NATIONAL ELECTRICAL CODE, N.F.P.A. ' KEEP OUT OF REACH OF CHILDREN! EMPTY CONTAINERS RETAIN SOME LiQUiD/VAPOR RESIDUES: HAZARD PRECAUTIONS MUST BE OBSERVED t/HEN HANDLING EMPTIES. USE OF ANY HYDROCARBON FUEL iN SPACES t/ITHOUT ADEQUATE VENT;LATION MAY RESULT IN GENERATION OF HAZARDOUS LEVELS OF VAPOR AND/OR INADEOUATE OX¥~E~I I, EyELs, FOR USE ONLY AS A MOTOR FUEL. DO NOT USE GASOLINE AS A CLEANING AGENT. SOME ACGIH AND OSHA EXPOSURE LIMITS ARE NOT L~STED iN SECTION Vi. BECAUSE THEY ARE LESS RESTRiCTiVE THAN THE EXPOSURE LIMITS DISPLAYED. General THE TERTiARY-BUTYL ALCOI43L COMPONENT OF THIS PRODUCT HAS PRODUCED URINARY Comments HYPERPLASZA, TESTICULAR DEGENERATION, AND FETAL TOXICITY iN LABORATORY ANIMALS. THE EXACT RELATIONSHIP BETt/EEN THESE RESULTS AND POSSIBLE HUMAN EFFECTS IS NOT KNQt/N. METHANOL CAN PRODUCE BLINDNESS ZN HUMANS. THERE t/ERE ND BENZENE-INDUCED EFFECTS NOTED iN STUDIES ON LABORATORY ANIMALS AFTER LONG-TERM EXPOSURE TO VAPORS OF AN UNLEADED GASOLINE SAMPLE CONTAiNiNG 2 VOL.% BENZENE, A RECOGNIZED HUMAN CARCINOGEN. HOt/EVER, THE RiSK OF 8ENZENE-ZNDUCED TOXZCITY OR CARCZNOGENZCITY ASSOCZATED t/ZTH THiS PRODUCT iS NOT KNOt~4. 'PETROLEUM DISTiLLATE'--IS CFR 1500.14(B)(3). USE SPECIAL FEDERAL LABELING iF iNTENDED, OR PACKAGED, FOR USE iN THE HOUSEHOLD OR BY CHILDREN. SOME OF THE ZNFORMATION PRESENTED AND CONCLUSIONS DRAMq HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE MIXTURE iTSELF. Qualification.~ EQ · EQuil LT · Loll Thin GT - Gremar Thru U~ - UnKovvrl Trice N/P- Nc) AIX)licl01e inforrrmt~on Found N/AP · Not ADl~liC. lblo N/DA - No Data Avmi4ble Disclaimer of Liabilit~ The iflformmiofl in thai MSDS ~ ~li~ fr~ ~cee ~i~ ~ ~liM me reli~le. ~R, ~ IW~~ ~ PRO~OED ~ A~ WARlA~, l~l~ OR ~D, RI~IOINO ~ ~lll~ FOR ~11 &~ O~l RKM. ~ H ~T M IIFOK A~ ~llT DI~ ~ F~ ~, O~M OR ~ AIIMN ~ M ON IN A~ WAY ~~D ~ ~ ~N. ~IAM. W ~ ~ M ~ PIOO~. P~ 4 of 4 R~ ~ ~ ism ~ 10 ~im ~ ~/11/15 1' ATTACI-L'~.ENT I ~) cMmical ~ut his · mediaA letf~l dose (I. DJ0) of more train 200 mLtlilrlms per kUolrlm but not mo~u tf~fl 1,000 mi~lisrlms per kilolram of body w~ill~t when administered by continuous contact for hours (oe less if death occufl within 2~ hours) with ~lw bar~ skin of ~Jbi~o tab, AU wuill~inS between two ·Ad thl~e I~loSl,~ms each~ (c) A chemical that has 8 median lethal concentration (LC~o) in air of mor~ than 200 peru per million Imf not mo~e than 2,000 ~ per mil, tion by volume of Su or vap~',, or moll then t~o milti~rAml per Li,~r I~t' not more ~ 20 millilrams per tltmr of mist, ~urno~ or dust, when admiflismrud by continuous iAl~l~tiOfl for one hour (or less if delta occurs within one ho.r) to albino rau wilhinI between 200 and MO srams each. 1'he foUowin$ Ls &. tm'set orlafl camlorintion of efbcts which may includiflS examples of silfls and symptoms and chemicals vl~ch have been found to cause such effects. Them examples art petseflwd to iUustrutn the ranp. and diversity of effects and he,za~ds found in the workplace, and broad scope employers must consider' in this. af~a, but aru not intsflded to. be ali-inclusive. HelMtotoxJns Chemicals that produce liver' dam·se Nephrotoxins Chemicals thet produce k~dfley dam·se Neurotox~fls Chemic,Lts th, hat produce their primary effects on the nervous 'system. Hematopoietic System Blood system Reproductive Toxins Chemicals that affect the reproductive capabilities includins chromosomal damase (mutations) and effects on fetuses (teratosens). 6 110785 DANGER GASOLINE (All Grades) MOHAWKR REG. 87 OCTANE NO LEAD R~ULAR EXTREMELY FLAMMABLE MAY CAUSE EYE, SKIN AND RESPIRATORY IRRITATION 'MAY BE HAR~ IF INHALED OR ABSORBED THROUGH SKIN* HARMFUL OR FATAL IF SWALLOWED. CONTAINS PETROLEUM DISTILLATES. ASPIRATION INTO THE LUNGS WILL CAUSE CHEMICAL PNEUMONIA. Keep away from heat, sparks and open flame Avoid breathing vapors or mists Use only with adequate ventilation Avoid liquid, mist and vapor contact Wash thoroughly after handling Keep out of reach of children FIRST AID EYE CONTACT: Flush eyes with clean water for 15 minutes. SKIN CONTACT: Wash affected area thoroughly with soap and water. F~CESSIVE INHALATION: Move immedi.ately to fresh air. ' Administer CPR and obtain medical attention if necessary. SWALLOWING: If swallowed, obtain prompt medical attention. Do not induce vomiting unless directed by physician. Long-term exposure to completely vaporized gasoline has caused cancer in laboratory animals. Vapors or liquid penetration of skin can cause central nervous system (CNS) depression and/or systemic effects. REFF~ TO MATERIAL SAFETY DATA SHEET FOR FURTHER INFORMATION Arco Petroleum Products Company 515 South Flower Street Los Angeles, California 90071 I I t I I I I MATERIAL SAFETY DATA SHEET aRCO' DIESEL MSDS No. Rev, Date 04/' ! 2/ 85 ARCO PETROLEUM PRODUCTS COI~A,NY 515 S~JT" =LOWE~ S~REE? LOS ANGE,E$. CAL~F0~NIA 90071 Trade Name ARCO DIESEL Other Names IMPORTANT: Read this MSDS befor~ hlndlmg and d~mg of th~ Wo~ct ~d ~ th~ i~formltmn on to emp~m$. ~ltom~. Ind uwt of th~ ~Ct This ~o~ct ~ COhered a OSHA HDd Commuflmltiofl Rule. DIESEL FUEL 0IL NC. 2; MOl 2 D[ESE~: DIESE, 0IL (MEDIUM): ASTM NC. 2-D GRADE DIESEL FUEL OIL (D-g75). Telephone NumPers E. MERGEN¢¥ 800/424-9300 CHEMTR£C 312,/210-3OOC C0MP=N~ CUSTOMER SERVICE 213/486-8258 IMF0 0NL¥ Chemical DOT Hazardous Materials Proper Shipping Name Family PETRCLEUM HYDROCARBONS FUEL 0IL. DIESEL, NO. 2 Generic Name DOT Hazard Claes 'ET.OLEU, DISTILLATE FUEL C0M,USTIBLE LIQUID CAS No. 68~76-34-6- ID No. 10371065OO UN/MA ID No. NA 1993 MAY CAUSE IRRITATION OR MORE SERIOUS SKIN O~SORDER$! AVOZD PMOLONQED OR REPEATED LZQUZD, MZST, ~ VAPOR COl~l'&c'r YZTH EYES, SK2N, AJdD RESPIRATORY TRACT. LCiNG-TERN TESTS SHOU THAT PETROLEUId DZSTZLI. ATES ~VE PRODUCED SKZN TLII~R$ ON L~ORATORY W~H THOROUGHLY AFTER MAY BE HARMFUL ZF ZNHALED! (SEE SECTZONS ZV. & V.) CONTAZNS PETROLEUM DZSTZLLATES! ZF SWALLOWED, DO NOT ZNDUCE VOMZTZNG SINCE ASPIRATION INTO THE LUNGS WZL~ CAUSE C:HEMZCAL PNEUMONIA. OBTAIN PROMPT MEDICAL ATTENTZON. MODERATELY COMBUSTIBLE; OSHA/NFPA C~ASS-ZI OR ZZZA COMBUSTIBLE LIQUID. KEEP AWAY FROM HEAT, SPARKS. NqD OPEN FLAME. AVOID THE "$¥ZTCH LOADING" HAZARD. (SEE $ECTZON XZ.) KEEP OUT OF REAC3.1 0F CHZLDREN! Flash Point (Method) t Autoigflition Temperature IMithod) Fllmm~le ~,m,. I% VOL m Air) AP 140'F (0-93) I AP 4gS'F (E-659) Lower AP 0.6 Upper AP 7.5 SEE "FIRE & EXPLOSION HAZARDS' BASED ON NFPA "FUEL 0IL NO. 2" BASED ON NFPA 'FUEL 0IL NO. 2" MODERATELY COMBUSTIBLE! WHEN HEATED ABOVE THE F~ASH POINT, THIS MATERIAL Fire and WILL RELEASE FLAMMABLE VAPORS WHICH IF EXPOSED TO AN IGNITION SOURCE CAN Explosion 8URN IN THE OPEN OR BE EXPLOSIVE IN CONFINED SPACES. MISTS OR SPRAYS MAY Hazards BE =LAMMABLE AT TEMPERATURES BELOW THE NORMAL FLASH POINT. FOR "SWITCH LOAD~NG" PROCEDURES. SEE SECTION XI. Extinguishing Media FOAM. DRY CHEMICAL, HALDN. CARBON DIOXIDE. AND WATER FOG. FOR FIRES INVOLVING THIS MATERIAL, DO NOT ENTER ANY ENCLOSED OR CONFINED ,I i Special Fire fighting Procedures SE~ FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT. THIS MAY INCLUDE SELF- CONTAINED BREATHING APPARATUS TO PROTECT AGAINST THE HAZARDOUS EFFECTS DF COMBUSTION PRODUCTS AND OXYGEN DEFICIENCES. COOL TANKS AND CONTAINERS EXPOSED TO FIRE WITH WATER. 307 :::7OR 'DISCLAIMER OF LIABILITY,' SEE THE STATEMENT ON PAGE 4N4 P~ge 1 of ARCO :)[[SE[. MSDS No. Summary of [.IOUID. MIST. OR VAPOR CONTACT CAN IRR.~TATE EYES. SKIN. AND THE RESPIRATORY ROUTE OF EXPOSURE SIGNS AND SYMP?OMS Prfmary Route(s; VA=~RS OR MISTS FROM THIS M~TER~A~ CAN ~RRIT~TE T~E NOSE. THROAT. AND Inhalation LUNGS. AN0 CAN CAUSE SIGNS AMC SYMPTOMS OF CENTRAL NERVOUS SYSTE~ [] Contact VAPORS. [] iSkin NO SIGNIFICANT SYSTEMIC EFFECTS ARE EXPECTED UNDER CONDITIDNS OF ;Absorption ANTICIPATED USE. [] Skin TH.IS MATERIAL IS LIKELY TO BE A MODERATE SKIN IRRITANT. IRRITATION Irritation LEADING TO DERMATITIS MAY RESULT FROM PROLONGED OR REPEATED EXPOSURES. [] (SEE CHRONIC HAZAROS BELOW.) THIS MATERIAL CAN IRRITATE THE MOUTH. THROAT, AND STOMACH. AND CAUSE ingestion NAUSEA. VOMITING, D~ARRHEA AND RESTLESSNESS. ASPZRATION INT0 THE LUNGS [] WILL CAUSE CHEMICAL PNEUMONIA. THIS PRODUCT CONTAINS PETROLEUM D:ST[L~ATES SIMILAR TO THOSE SHOWN TO Summary of PRODUCE SKIN TUMORS ON LABORATORY ANIMALS. AVOI0 PROLONGED OR REPEATED Chronic Hazards SKIN CONTACT. and Special Health Effects PERSONNEL WITH aRE-EXISTING CENTRAL NERVOUS SYSTEM DISEASE. SKiN DISORDERS. OR CHRONIC RESPIRATORY DISEASES SHOULD AVOID EXPOSURE TO THiS PRODUCT. THIS MATERIAL IS NOT EXPECTED TO PRESENT A RESPIRATORY HAZARD BECAUSE OF Respiratory ITS LOW VAPOR PRESSURE. BUT, IF EXCESSIVE MIST OR VAPORS RESULT FROM CONOZT:CNS OF USE. WEAR ~ROPER NIOSH/MSHA-APPROVEO RESPIRATORY EQUIPMENT. EYE PRDTECTION SHOULD BE WORN ~HENEVER THERE IS A LIKELIHOOD OF SPLASHING Eye OR SPRAYING LIQUID. CONTACT LENSES SHOULD NOT BE WORN. SUITABLE EYE ~ASH WATER SHOULD BE AVAILABLE. AVOI~ ~RDLONGED AND/OR REPEATED SK[N CONTACT. IF CONDITIONS OR FREQUENCY Skin DF ~SE MAKE C~NTACT SIGNIFICANT. CLEAN AND IMmERV[0US PROTECTIVE CLOTHING SUC~ AS GLOVES. APRON, BOOTS. AMC ;AC[AL PROTECT:ON SHOULD BE WORN. Engineering USE ADEOUATE VENTiLATiON TO KEEP VAPOR CONCENTRATIONS OF THIS MATERIAL Controls BELOW APPLICABLE EXPOSURE LIMITS. (SEE SECTIONS VI. ANO XI.) USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANOS BEFORE EATING, 0RINKING, Other Nygienic SMOKING. OR USE OF TOILET FACILITIES. IMMEDIATELY REMOVE SOILED CLOTHING and AND WASH THOROUGHLY BEFORE REUSE. 0ISCARD CONTAMINATED LEATHER GOODS. Work Practices RESPIRATOR USE SHOULD COMPLY wITH OSHA STANDARDS OR EQUIVALENT. SEE SECTION XZ. FOR AODZTION&L ~NFORMATION. Substance Source Date Type Value/Units Time KEROSENE (DHEW PUBLICATION 7'/-192) NIOSH 1977 PEL 100 MG/M3 10 STEL 18OO MG/M3 15 MIN STDDDARD SOLVENT (SEE SECTION XI.) ACGIH 1985 TLV 1OO PPM 8 HRS STEL 200 PPM 15 P~ge 2 of 4 ! I ARCO- DIESEL MSDS No. Rev. Date 04,.' 1 ~- 85 , VI I. Inhalation Eye Contact Skin Contact Ingestion PERS[STS."OBTAIN MEO'[CAL ATTENTION. PROMPTLY REMOVE CONTAMINATED CLOTHING AND ITHOROUGHLY CLEAN BEFORE REUSE. BUT DISCARD CONTAMINATED LEATHER GOODS. THOROUGHLY WASH AFFECTED AREA WITH SOAP AND wATER. 00 NOT INDUCE VOMITING. SINCE ASPIRATION INTC THE LUNGS WILL CAUSE CHEMICAL ONEUMONIA. I; ASPIRATION OCCURS. PROMPTLY OBTAIN MEDICAL ATTENTION. Emergency Medical Treatment Procedures SEE ABOVE PROCEDURES. VIII." · Precautions if Materlai is Spilled or Released · .:. - :. . . ..-'" ... :"-.'... -: and D. osal:! i ii:: : .!:iii CONTAIN SPILL, REMOVE ALL [GNaT[ON SOURCES &NC) SAFELY STOP FLOW OF SPILL MAY CREATE SLIPP!NG HAZARDS. PREVENT FROM ENTERING ALL WATER BDO[ES. [F DOSS:BAR. EVACUATE ALL NON-ESSENTIAL PERSONNEL. IN URBAN AREAS. CLEANUP AS SOON AS POSSIBLE; IN NATURAL ENVIRONMENTS, CLEANUP ON ADVICE FROM ECOLOGISTS. TH{S MATER[AL WILL FLOAT DN WATER. ABSOR~ANT MATERIAL AND PADS CAN BE USE:. CO¥~LY WIT~ ALL APPLICABLE LAWS. SPILLS MAY NEED T0 BE REPORTED TO THE NATIONAL RESPONSE CENTER {BOO/424-BB02). THE MATERIAL AIqO ANY WATER OR SOIL W~ICH IT HAS CONTACTED MAY BE HAZARDOUS TO ANIMAL/'AOUAT[C LIFE. I I I l I 1 I I I MAXIMIZE PRODUCT RECOVERY FOE REUSE OR RECYCLING. UNUSED LIQUID PRODUCT :$ cIKEL~ AN EPA ":C, uNITABLE HAZAROOu~ WASTE' (O00~). USE APPROVED TREATMENT. TRANSPORTERS. AND ~:S=OSA, SITES :N COMPLIANCE WITH ALL APPL:- Waste CAB_E LAWS, :F SPIL~ :S INTRODUCED :NT: A WASTEWATER SYSTEM, THE CHEMICAL Disposal AND ~:OL~G:CAL OXYGEN DE~ANC W:LL- LIKELY INCREASE. SPILL MATERIAL IS Methods B:gD[~RAOAE~E IF GRADUALLY EXPOSED T: ~:CRGCRGAN:SMS. aGTENT[AL DISPOSAL METHODS INCLUDE INCINERATION ANC LAND DISPOSAL, IF PERMITTED. !;~., ..' ..:!:i~i::: ':,.i!':.': ::: :,:.ii:ill i:i:i.i¥.::[i::::i[iiiiii[ii~.'.'-zL''4'~. :i:::ii~sl mw:n~t .be:"a.~,,a..~t.e~::iiii¥i:i:::iiiii:i!i:i:::::::::ii:.¥./.... : :il i .'~':7::- .: :':':'~, : ':" :~': ::/::.:.'.::~:?~:~:~.'~,~,e,~a::::~::.~,~.,..~.~...:.,~t of comao,.,,::::.::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ::' ;Component Name ~S ~. C~ei~ge~ C~lolition amouflt IVolJ ~ee Q~lifieation on Page 4) HYDROCARBCNS W~TH A BOZL]NG POINT RANGE N/AP AP t00 PERCENT O~ 325'F. TO 7~'F. ·#Listed B~ I = NT1), 2 = IARC, ] = OSHA. 4 = Other 307 Gompolitions g~ven Me typiMI velue~, not spe~ifi&~tiona. Page 3 of Boiling Point ~Viscosit~ Units, Temp. (Method) Dry Point 325' '1'0 690' F Al:) 3 CST AT 1OO' F ( D-a.t5 I N/DA Freezing Point Vapor Pressure Volatile Characteristics S~ecifi¢ Gravity IN:O = 1 at 3g,2'F~ Vapor Sa. Or, {Air = 1.0 at 60'-~0'~i Solubility in Water pN Hazardous Polymerization Other Chemical Reactivity Stabili~ N0~ EXPECTED rC 0CC~ N..'= STABLE Other Physical SULFUR CONTENT = LT 0.5 ~T.% and Chemical Propel)es and Odor KEROSENE ODOR. Conditions to Avoid Materials STa0NG AC~DS. ALKaLiES. AND 0X~D:ZERS SUCH AS tO Avoid LZQU[~ CHLORZNE AND OXYGEN. Hazardous BURNING OR EXCESSIVE HEATING MAY PRODUCE CARBON Decomposition MONOXIDE AND OTHER HARMFUL GASES/VAPORS INCLUDING Products 'OXIDES AND/OR OTHER COMPOUNDS OF SULFUR. .: .... .. .. . ,......:. :' . ...... .... . .... . . . . .... ,....:..........:....:.:.::.:.:.:::.:.:.:.:.-...:.... ::..:-..'.:.-.:'..:.:...::.:.':: SPEC:~L SLOW LOA~ oROC~DURES ~0R "SWITCH LOADING" MUST BE FD~0WEO TD AVOID THE STATIC IGNZT[0N HAZARO THAT'CAN EX~ST WHEN THIS MATER:AL ZS LOADED ~NT0 TANKS RREVZOUSLY CONTAINING GASOLINE OR OTHER LOW FLASH POINT PRODUCTS. (SEE A.P.I. PUBLICATION 2003.) KEEP CONTAINERS CLOSED AN0 AWAY FROM HEAT Handling. AND IGNITION SOURCES! ALL ELECTRICA~ EGUIDMENT IN AREAS wHERE PRODUCT IS Storage STORED/HANDLED SHOULD BE ~NSTALLED IN ACCORDANCE W,!TH APPLICABLE REQUIRE- and MENTS OF THE NATIONAL ELECTRIC CODE, N.e.~mA. DO NOT USE THiS PRODUCT AS A Deconta- CLEAN!NC AGENT. EMPTY CONTAINERS RETAIN SOME ~I~UIO ANO VAPOR RESIDUES, mmation AND HAZAR~ PRECAUTIONS MUST BE OBSERVED WHEN HANOL:NG.EMPTY CONTAINERS. Procedures WARNING: USE 0r ANY ~YDROCARBON FUEL IN SaACES W:THOUT ADEDUATE VENTILATION ~A¥ RESULT IN GENERATION OF HAZARDOUS LEVELS DF CDMBUSTION PRODUCTS AND :NAOEQUATE 0XVGEN LEVELS FOR BREATH[NC. General Comments SOME OSHA PERMISSIBLE EXPOSURE L~MZTS ARE NOT SHOWN IN SECTION VI. BECAUSE THEY ARE LESS RESTRICTIVE THAN THE ACGZH EXPOSURE LIMITS ALREAOY LISTED. SINCE SPECIFIC EXPOSURE STANOAROS/CONTROL LIMITS HAVE NOT BEEN ESTABLISHED FOR THIS MATER[AL, THE EXPOSURE L~M~TS SHOWN IN SECTION VI. ARE SUGGESTED AS MINIMUM CONTROL GU:DELZNES. MATER2ALS SIMILAR TO SOME COMPONENTS :N THIS PRODUCT WERE FOUND TO BE MUTAGENIC :N 'IN VITRO" AN0 "IN VIV0" TESTS. THE EXACT RELATIONSHIP BETWEEN THESE RESULTS AND POSSIBLE HUMAN EFFECTS IS NOT KNOWN. "PETROLEUM DISTZLLATE"--~6 CFR ~500.14(E)(31. USE SPECIAL FEDERAL LABELING [F INTENOED. OR PACKAGED, FOR USE IN THE HOUSEHOLD OR BY CHILDREN. SOME OF THE INFORMAT[ON PRESENTED AND CONCLUSIONS 0RAIN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE MIXTURE ITSELF. EQ · EQual AP · Ai3prox~matety - - - Note Qualification~ LT= Less Than UK =, Unkown GT= Greater Than TR · Trace NIP = NO ADphcIIIIi Information Founci N/AP I Not AI301iclOle N/IDA · No Data AvallaOle Disclaimer of Liability ' The information in tflil Maes Wll olotlino4 from sources wtt~cl~ we believe eke reliable. HOWWVER, ~l I~ORMA~ON 18 PRO~DED ~OUT ANY WARRA~, E~RE~ OR IKED, REGARDING i~ The coflditionl or methods of nlndllflg, ItOrlgl, use lfld dllHIII Of t~l WOU~ MI OeyonO our control ~ rely bi Oey~ O~ knowledge. FOR ~IS ANO O~ER REASONS, ~ O0 NOT A~M! RE~ON81I~ ANO E~RES~Y DIE~IM UA~ PeR LOSE, DAMAGE OR E~ENSI ARISING O~ OF OR IN ANY WAY CONNIC~D M~ ~i HAM~NG, STORA~, U~ OR DI~O8~ ~ ~! PROOUCT. P~e 4 of 4 Rev ~ ~ Issue No: 55 Print ~ 00/20/85 ! 110785 DIESELS #2 DIESELS HEATING OILS NAVAL DISTILLATES JP-5 JET FUELS CUTTER STOCKS WARNING MODERATELY COMBUSTIBLE MAY BE HARMFUL IF INHALED 'MAY CAUSE IRRITATION OR MORE SERIOUS SKIN DISORDERS~ CONTAINS PETROLEUM DISTILLATES. ASPIRATION INTO THE LUNGS WILL CAUSE CHEMICAL PNEUMONIA. Keep away from heat, sparks and open flame Avoid breathing vapors or mists Avoid prolonged and/or repeated skin contact Wash thoroughly after handling Avoid eye contact with mist, liquid and/or vapor When loading into tanks previously containing gasoline or other low flash point products, slow loading procedures must be followed to avoid the static ignition hazard. FIRST AID EYE CONTACT: Flush eyes with clean water for 15 minutes. SKIN CONTACT: Wash affected area thoroughly with soap and water. EXCESSIVE INHALATION: Move immediately to fresh air. Administer CPR and obtai'n medical attention if necessary. SWALLOWING: If swallowed, obtain prompt medical attention. Do not induce vomiting unless directed by physician. Long term studies have shown that petroleum distillates similar to those used in this product have produced skin tumors in laboratory animals. REFER TO MATERIAL SAFETY DATA SHEET FOR FURTHER INFORMATION Arco Petroleum Products Company 515 South Flower Street Los Angeles, California 90071 MATERIAL SAFETY DATA SHEET ARCO® GASOLINE ARCO PETROI,EUN PRODUCTS CG#PMIY DZVZS[ON OF ATLANTIC RICHFIELD COMPANY 515 SOUTH FLOWER STREET LOS ANGELES, CALIFORNIA 90071 MSDS NO. APPC ~ Rev. Date 06/12/85 IMPORTANT: Reed this M8DS bMoN handing MM di~maine of ~ ~ md ~ ~ ~n on ~ em~, am, md ~ of Trade I Telephone Numbers Name ARCO GASOLZNE I EMERGENCY I 800/424-9300 CHEMTREC Other Names LEADED. NON-PREMZUM MOTOR VEHZCLE GASOLZNE I 312/210-3000 COMPANY LEADED REGULAR GASOLINE OR PETROL I CUSTOMER SERVTCE I 213/486-8258 XNFO ONLY i Chemical lootI~lZardous Matm'tMs Proper Shipping Name Family HYDROCARBONS WZTH ALCOHOLS AND/OR ETHERS I GASOLZNE Generic Name lootHlzIrd Clill PETROLEUM NAPHTHAS (BLENDED) I FLAMMABLE LZQUZD I compe.y CAS NO. SEE SECTZ0N :ZX I ID NO. 0108001080 UN/NA ID NO. UN 1203 EXTREMEI,Y FLAM4AIL. E! OSKA/NFPA CLASS-ZA FI-AMilAli,E I. ZQUZD. KEEP AYAY FRQII HEAT. SPAIIKS, MI) OPEN FLAME. NAY CAUSE ZRRZTATZON TO EYES, SKZN, NO RESPZRATONY SYSTBill AVOZD I,ZQUZD, #ZST, NO VAPOR CONTACT. WASH THOROUGHLY AFTER IMNDI,ZNG. Avo~rD BREAT14ZNG VAPORS OR NZS?. USE ONLY YZTH ADEQUATE VENTZLATZON. I,ONG-TERM EXPOSURE TO ClXIFI,EYELY VAPORZZED GASOI,ZNE HAS CAUSED r..MICER ZN LABORATORY MIZMALS. VAPORS OR iZQUZD PENETRATZON OF SKZN CAN CAUSE CENTRAL NERVOUS SYSTEM (CMS) DEPRESSZON AND/OR SYSTEIiZC EFFECTS. HARMFUl, OR FATAL ZF SYALLOVED! C:ON'rAZNS PE?ItOI,EI,M OZSTZI,LATES! ZF SYALI,OYED, 130 NOT ZNOUCE VOIIZTZNG SZNGE ASPZRATZ0N ZNTO ~ ~ ¥1~Li, PAUSE C:NEIIZCAL PNEUMQNZA. OITAlrN PROMPT IIEDZGAI, ATTENTZON. KEEPOUT OF REA~N OF C:HZLD~EN! Flash Point (Method) I AutoigMtion Temperature (Method) I Flammm L,m,. 4% ¥ol. m *,r) I At NOfl~lll AtfftOlMleric Temwlture ~nO Prelsure AP -45'F (D-SO) GT 6~'F (E-6Se) iL~ AP 1.3 ~ AP 8.2 SEE "FZRE & EXPLOSZON HAZARDS" BASED UPON ACTUAL LAB TESTS I BASED UPON ACTUAL LAB TESTS I EXTREMELY FLA~ABLE? THZS MATERZAL RELEASES VA~ORS AT 0R BELO~ A~ZENT Fire and TEMPERATURES. ~HEN ~XED ~ZTH AZR ZN CERTAZN PRGPORTZONS A~ EXPOSED TO AN Explosion ZGNZTZON SOURCE, THESE VAPORS CAN BU~ [N THE OPEN 0R EXPLODE ZN CONF]NED Hazards SPACES. BE]NG HEAVIER THAN AZR, FLA~ABLE VAPORS MAY TRAVEL LONG DZSTANCES ALONG THE GROU~ BEFORE REACH.ZNG A POZNT OF ]GNZTZON A~ FLASHZNG BACK. Extinguishing Media FOAM CD2 DRY CHEMZCAL HALON CONSULT FOAM MANUFACTURERS FOR APPROPRZATE MEDIA, APPLZCATZON RATES. AND WATER/FOAM RATZO. Firefightlng Procedures SEC~ SUB-SURFACE APPLZCATZON ZS ONLY RECOMMENDED WHERE [T ZS KNOWN THAT THE FUEL CONTAZNS LESS THAN 3% OXYGENATED BLENDING COMPONENTS. FOR FZRES ZNVOLVZNG TH~S G&SOLZNE, DO NOT ENTER ANY ENCLOSED OR CONFZNED F~RE SPACE WZTHOUT PROPER PROTECT]VE EOUZPMENT. THZS MAY XNCLUDE SELF-CONTAZNED BREATHING APPARATUS TO PROTECT AGAZNST THE HAZARDOUS EFFECTS OF COMBUSTZON PRODUCTS AND OXYGEN DEFZCZENCZES. WATER FOG OR SPRAY ARE OF VALUE FOR COOLZNG TANK SHELLS AND SURFACES EXPOSED TO FZRE, BUT MAY NOT ACHZEVE EXTINGUISHMENT. 10 ::::OR 'DISCLAIMER OF'LIAIlUTY,' SEE THE STATEMENT ON PAGE Page 1 of III ARCO GASOLINE MSDS No. APSe 304 I i i:: :.:.:::::::::::..::..:.:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ""::':: :"': i Summm'y of LIQUID. MiST DR VAPORS CAN CAUSE EYE, SKIN AND RESPIRATORY TRACT iRRITATION A{uteHIzlrdl AN0 CNS DEPRESSION. ASPIRATION INT0 LUNGS WILL CAUSE CHEMICAL PNEUMONIA. ROUTE OF EXPOSURE SIGNS AND SYMIrrOMS EXPOSURE CAN CAUSE IRRITATION TO THE NOSE. THROAT, & LUNGS AND SIGNS DF CNS Inhel~ion DEPRESSION'(DIZZINESS. DR0¥SINESS. LOSS OF COORDINATION. COMA AND DEATH). DEPENDING ON THE CONCENTRATION/DURATION OF EXPOSURE. (SEE "SUMMARY" BELOW.) Eye MiLD EYE iRRITATiON MAY RESULT FROM CONTACT WITH LIQUID. MIST, &ND/OR ContKt VAPORS. [] Skin LIQUID CAN PENETRATE SKiN TO CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. Absorption VAPOR PENETRATION CAN ALSO CAUSE SYSTEMIC EFFECTS. (SEE "SUMMARY OF [] CHRONIC HAZARDS AND SPECIAL HEALTH EFFECTS" BELO¥.) Skin Irritation SKIN IRRITATION LEADING TO DERMATITIS MAY OCCUR UPON PROLONGED AND REPEATED CONTACT DUE TO SKIN DEFATTING. L,YJ. IRRITATION OF THE MOUTH, THROAT &G&STROINTESTZN&L TRACT LEADING TO N~USEA, ingestion VOMITING, DIARRHEA AND RESTLESSNESS. CNS DEPRESSION SIMILAR TO THAT CAUSED II BY VAPOR INHALATION. ASPIRATION ZNT0 LUNGS WILL CAUSE CHEMICAL PNEUMONZA. AN A.P.I.-SPONSORED STUDY HAS SHOWN THAT RATS AND MICE DEVELOPED CANCER Summm~/ of FOLLDVZNG CHRONIC ZNHALATION EXPOSURE TO THE VAPORS OF UNLEADED GJSOI. ZNE. Chronic H~z~rd~LoNG-TEm~ EXPOSURE TO UNLEADED GASOLINE HAS ALSO PRODUCED KIDNEY DAMAGE ZN LABORATORY ANZM~LS. THE EXACT RELATIONSHIP BETYEEN THESE RESULTS AND SI)e~lel Heait~ POSSIBLE HUMAN EFFECTS ZS NOT KNOkIM. LEAD TOXZCZTY LEADING TO DAMAGE OF THE Effects CENTRAL AND PERZPHERAL NERVOUS SYSTEMS. BLODO-FORMING ORGANS. AND KIDNEYS MAY RESULT FROM PROLDNGED AND REPEATED EXPOSURE TO LZQUZD. MIST. OR VAPORS. .... '1 .......... .... ~ ........ '"'' ' '"' '1 ' '' '1'1' ' ' ' ' '1' '1 ..... """ '"" '"" ' "' '1' ""Vl"'l' ViM ' ' '1'"' .... i"'l'lVl°lVl'l·l'"[V'·l"°'Vl°l' '1 ........ " ' '' ' "/ "' USE NZOSH/MSHA-APPROVED 'RESPIRATOR MHEN VAPOR LEVELS EXCEED EXPOSURE LIMITS Respiretory ]N SECTZON VI. USE FULL-FACEPIECE MASK ABOVE BOO PPM G~SOLINE VAPORS. AND SUPPLIED-AIR OR SCBA EQUZPMENT ABOVE 1000 PPM. (SEE "OTHER' BOX BELO¥. ) EYE PROTECTION SHOULD BE WORN II~ENEVER THERE ZS A LIKELIHOOD OF SPLASHZNG Eye OR SPRAYING LZOUZD. CONTACT LENSES SHOULD NOT BE WORN. SUITABLE EYE WASH WATER SHOULD BE AVAILABLE. AV0~D PROLONGED AND/OR REPEATED SKIN CONTACT. ZF CONDZTIONS OR FREQUENCY Skin OF USE MAKE CONTACT S;GNTFICANT. CLEAN AND IMPERVIOUS PROTECTIVE CLOTHING SUCH AS GLOVES. APRON, BOOTS. AND FACIAL PROTECTION SHOULD 8E WORN. Engineering USE ADEQUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF THIS MATERZ&L Con~ols BELOW THE 0CCUPATION&L EXPOSURE LIMITS SHOraN BEL0V ZN SECTZON VI. (SEE SECTION XI.-"GENERAL COMMENTS".) USE GOOD PERSONAL HYGXENE PRACTICES. XN CASE OF SKIN CONTACT, WASH WITH Other Hygienic MILD SOAP AND WATER OR A WATERLESS IL&ND CLEANER. IWEDIATELY REMOVE SOAKED and CLOTHING AND WASH THOROUGHLY BEFORE REUSE. DISCARD GASOLiNE-SOAKED SHOES. Work Practices RESPIRATOR USE SHOUI, D COMPLY WITH OSHA STANDARDS. CONTROL OCCUPATZDNAL EXPOSURES BELOW 1PPM 'BENZENE" RATHER THAN THE 300 PPM 'GASOLINE" TLV. NEVER SIPHON GASOLINE BY MOUTH. SEE SECTION XI. FOR ADDITIONAL INFORMATION. I ............. I1'1' I I ' I I ' III ' I ...... Ir Ill[ ~Substante Source Dire Type Value/Units ARCDEL 1983 TWA 1PPM PEAK 25 PPM ACGZH 198B TLV 10 PPM STEL 25 PPM ACGZH te8S TLV 300 PPM STEL ~3C) PPM ACGIH 1RRB TLV 200 PPM STEL 2SO PPM ACGIH I~SB TLV 1000 PPM ACGIH 198S TLV 100 PPM STEL 1S0 PPM BENZENE (ADOPTED BY ATLANTIC RICHFIELD) BENZENE (TYPE "&2" CARCINOGEN) GASOLINE (SEE SECTION METHYL ALCOHOL (METHANOL) - SKIN ETHYL ALCOHOL (ETHANOL) TERT-BUTYL ALCOHOL (TBA) Time 12 HRS 15 MiN 8 HRS 15 8 HRS 15 MIN 8 HR' 15 M~. Plge 2 of 4 HRS 15 ARCO® GASOLINE ·aPe 304 Rev. Date 06/12/85 IMMEDIATELY MOVE PERSONNEL TO ARE· OF FRESH AIR. FOR RESPIRATORY OISTRESS, Inhalation GIVE ·IR, OXYGEN, OR ADMINISTER CPR (CAROIOPULMON·RY RESUSCITATION). IF NECESSARY. OBTAIN MEDICAL ATTENTION IF BREATHING D~FF'ICULTIES CONTINUE. Eye FLUSH WITH CLEAN LOW-PRESSURE WATER FOR AT LEAST 15 MINUTES. IF IRRITATION Contact Skin PERSISTS, OBTAIN MEDICAL ATTENTION. IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH AFFECTED SKIN THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEEK MEDICAL ATTENTION. i I I I Cont~t Ingestion Emergent/ Medicel Treatment Procedures ' :.: Pl'es~Jons if Mlterial ia SI)iliad or Keleaeed WASH CLOTHZI~hG BEFORE REUSE, BUT DISCARD CONTAMINATED LEATHER SHOES/GLOVES. DO NOT INDUCE VOMITING, SINCE ASPIRATION INTO THE LUNGS WILL CAUSE CHEMICAL PNEUMONIA. IF ASPIRATION OCCURS, PROMPTLY OBTAIN MEDICAL ATTENTION. PERSONNEL WITH PRE-EXISTING SKIN DISORDERS. IMP·IRED LIVER OR KIDNEY FUNCTION. OR CENTRAL NERVOUS SYSTEM AND CHRONIC RESPIRATORY DISEASES SHOULD AVOID EXPOSURE TO THIS MATERIAL. CONTAIN SPILL. REMOVE ALL IGNITION SOURCES ANC) SAFELY STOP FLOW OF SPILL~. IN URBAN AREAS, CLEANUP AS SOON AS POSSIBLE.; ZN NATURAL ENVIRONMENTS, SEEK ADVICE FROM ECOLOGISTS. EVACUATE ALL NON-ESSENTIAL PERSONNEL. USE PROPER PROTECTIVE EQUIPMENT. BLANKET WITH FOAM OR USE WATER FOG TO'DISPERSE VAPORS. PADS AND ABSORBANT MATERIAL CAN BE. USED. GASOLINE WILL FLOAT ON WATER ·ND RESULTING RUNOFF MAY CREATE AN EXPLOSION OR FIRE ~ZARD. COMPLY · *ZTH ALL APPLICABLE LA~S. SPILLS MaY NEED TO BE REPORTED TO THE NATIONAL RESPONSE CRIER (~/424-~02). GASOLINE OR CONTAMINATED MATERIALS MAY BE HAZARDOUS TO HUMAN A~ OTHER LIFE. MAXIMIZE PRODUCT RECOVERY FOR REUSE. DISPOSE OF PRODUCT. CONTAMINATED ! I I I I ! I I MATERIAL, AND STORAGE TANK WATER BOTTOMS AS AN EPA "IGNITABLE HAZARDOUS Waste Disposal Methods WASTE" (DO01), UNLESS PROVEN OTHERWISE. EPA ALSO LISTS REFINERY LEADED TANK BOTTOMS AS A "HAZARDOUS WASTE" (KOS2). USE APPROVED TREATMENT. TRANSPORTERS, AND DISPOSAL SITES IN COMPLIANCE WITH ALL LAWS. TANK WATER BOTTOMS/SLUDGE MAY BE HAZARDOUS TO HUMAN AND OTHER LIFE. IF SPILL ENTERS A WASTEWATER SYSTEM, THE CHEMICAL AND BIOLOGICAL OXYGEN DEMAND WILL LIKELY INCREASE. SPILL MATERIAL IS BIODEGRADABLE IF GRADUALLY EXPOSED TO MICROORGANISMS. A POTENTIAL DISPOSAL METHOD ZS INCINERATION. Componant Name MYOROCARBONS WITH · BOILING POINT RANGE OF 70'F. TO 440'F. METHYL TERTIARY-BUTYL ETHER (MTBE) GASOLINE-GRADE TERTIARY-BUTYL ALCOHOL ETHANOL METHANOL BENZENE LEAD ALKYLS (MEASURED AS LEAD) CA~,~ ~ Clrcinogln#~ COml)olition amount (Vol.) (S~ Q~iifi~tion on Page 4) N/AP AP 89 TO ' 99 PERCENT 1634-04-4 N/AP AP 0 TO 11 PERCENT 75-65-0 N/AP AP 0 TO 10 PERCENT Gd-IT-B N/AP AP 0 TO 10 PERCENT 6T-56-1 N/AP AP 0 TO 5 PERCENT T1-43-2 1,2, ,4 LT 5 PERCENT N/AP LT 3.2 GM/GAL. ##Listed BT 1 = NTP. 2 = IARC, 3 ~ OSHA, 4 = Other tO Compositions given Ire typical values, not ll)4mtfications. P~ge 3 of B ARCO GA$0L2NE MSDS No. App¢ 30~ · IBoili g ' " ' ' Viscosity Units, Temp. (Method) Dry Point I AP ?0' TO 440' F N/AP AP 430'; Freezing Point VN)or Pressure N/AP (REZD-PSIA AT 1OO' F) A= 8 TO 15 Specific Gravity (HtO= 1 at ~2'F) AP D.73 TO 0.78 .. Hazardous Polymerization VN)or Sp. Gr. LAir= 1.0 at SC)'-g0'l:)iSolubility in Water Other Chemical Reactivity NOT EXPECTED TO OCCUR N/P Other Physical WATER [N CONTACT WtTH OXYGENATED GASOLtNE CAN CON- end Chemical Properties TAIN UP TO SO~ OXYGENATE & HYDROCARBON MATERtALS. Appearance ORANGE-COLORED LIQUID; PETROLEUM NAPHTHA ODOR. end Odor Volatile Characteristics APPI~EC~ABLE pH N/AP Stlbility STABLE Conditions to Avoid HEAT, SPARKS. AND OPEN FLAME. 'Materials to Avoid Hazardous Decomposition Products AVOZD CONTACT WITH LATER. REACTS WXTH STRONG ACIDS AND STRONG OXIDIZING MATERIALS. BURNtNG OR E. XCESStVE HEATtNG MAY PRODUCE CARBON MONDXtDE AND OTHER HARMFUL GASES/VAPORS INCLUDING OXIDES AND/OR OTHER COMPOUNDS OF LEAD. CHLORINE. MANGANESE. AND BROMINE. STORE AND TRANSPORT XN ACCORDANCE WITH ALL APPLICABLE LAWS. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLA#E! KEEP CONTAINERS CLOSED AND OUT OF CLOSED VEHtCLES. CONTAtNERS SHOULD BE ABLE TO WITHSTAND PRESSURES EXPECTED FROM WARMTNG OR COOLTNG IN STORAGE. GROUND ALL DRUMS AND TRANSFER VESSELS WHEN ,Handling, HANOI. tHC. THE PRESENCE OF LEAO COMPOUNDS ZN GASOLtNE REOUtRES THE USE OF IStorege SPECIAL PROCEDURES AND PROTECTIVE EQUIPMENT FOR TANK, VESSEL. OR OTHER lind ENCLOSED SPACE ENTRY. REFER TO AMERtCAN PETROLEUM INSTITUTE PUBL:ZCATtONS Deconte- RP :2015 &ND 2015& FOR SPECIAL PRECAUT20NS. ALL ELECTRICAL. EQUIPMENT ZN minetion GASOLZNE STORAGE AND/OR HANDLING AREAS SHOULD BE INSTALLED tN ACCORDANCE Procedures W~TH APPLICABLE REQUIREMENTS OF THE NATIONAL ELECTRtCAL CODE. N.F.P.A. KEEP OUT OF REACH OF CHILDREN! EMPTY CONTAINERS RETA:~N SOME LIQUID/VAPOR RESIDUES; HAZARD PRECAUTTONS MUST BE OBSERVED WHEN HANDL:iNG EMPTY:ES. USE OF ANY HYDROCARBON FUEL ZN SPACES WITHOUT ADEOUATE VENTILATION MAY RESULT ~:N GENERATION OF HAZARDOUS LEVELS OF VAPOR AND/OR INADEQUATE OXYGEN LEVELS. C'.-mneral FOR USE ONLY AS A MOTOR FUEL. DO NOT USE GASOLINE AS A CLEANING AGENT. SOME ACGZH AND OSHA EXPOSURE L~MZTS ARE NOT LISTED ZN SECTION VI. BECAUSE THEY ARE LESS RESTRICTIVE THAN THE EXPOSURE LIMITS D~SPLAYED. THE TERTIARY-BUTYL ALCOHOL COMPONENT OF TH~S PRODUCT HAS PRODUCED URZNARY HYPERPLASZA. TESTXCULAR DEGENERATION. AND FETAL TOXXCZTY ZN LABORATORY ANIMALS. THE EXACT RELATIONSHIP BETWEEN THESE RESULTS AND POSSIBLE HUMAN EFFECTS tS NOT KNQYN. METHANOL CAN PRODUCE SLZNONESS tN HUMANS. THERE WERE ND BENZENE-INDUCED EFFECTS NOTED ZN STUDIES ON LABORATORY ANIMALS AFTER LONG-TERM EXPOSURE TO VAPORS OF AN UNLEADED GASOLINE SAMPLE CONTAINING 2 VOL.% BENZENE. A RECOGNIZED HUMAN CARC:NOGEN. ~OWEVER, THE RISK OF BENZENE-INDUCED TOXICITY OR CARCZNOGEN~CZTY ASSOCIATED WITH THIS PRODUCT IS NOT KNOWN. 'PETROLEUM DISTILLATE"--t6 CFR 1S00.14(B)(3). USE SPECIAL FEDERAL LABELING ZF INTENDED, OR PACKAGED, FOR USE ZN THE HOUSEHOLD OR BY CHILDREN. SOME OF THE INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE MIXTURE ITSELF. I EQ · EQuil AP - Approximately N/P · No Appliciiote Inforrrmt,on Pounce - - - Note - - - Qualification~ LT · Lass Thin UK · Unkown N/AP · Not GT · Greater Thin TR · Trice N/DA · NO Data Avmtalj)le DisolaimM of LiM)ility The ertl.fruition ih ~hil M~D~ wll M~li/~d frM~l IMl~eel w~tich we believe ire reliable. ~W~LI~R, THE INFORMATION lB PROVIDED WITHOUT ANY WARRANTY, EX~RI~ DR IMFUED, REGARDING Ill CORRECTIIlU. PON THIS AND OTHER REAiOii~, ~1~ DO ~OT AiM REIPONIIIIUTY AND EXPRESSLY DIBCI. AIM UAIM. JTY FOR LOB~. DAMAM OR i IXPliil~ ARlliNO OUT MI OR Ill Al~' WAY C,~iiiil~ ~ THE HAN~LJNQ, BTONAM, UM OR DIM)OBAL OF THE PRODUCT. . I Page 4 of 4 Rev ~ ~ I~ ~ 74 Prin~ ! ! 6 110785 GASOLINE (Ail Grades) MOHAWKR REG. 87 OCTANE NO LEAD REGULAR DANGER EXTREMELY FLAMMABLE MAY CAUSE EYE, SKIN AND RESPIRATORY IRRITATION 'MAY BE HARMFUL IF INHALED OR ABSORBED THROUGH SKIN" HARMFUL OR FATAL IF SWALLOWED. CONTAINS PETROLEUM DISTILLATES. ASPIRATION INTO THE LUNGS WILL CAUSE CHEMICAL PNEL~ONIA. ° Keep away from heat, sparks and open flame ° Avoid breathing vapors or mists ° Use only with adequate ventilation ° Avoid liquid, mist and vapor contact ° Wash thoroughly after handling Keep out of reach of children FIRST AID EYE CONTACT: Flush eyes with clean water for 15 minutes. SKIN CONTACT: Wash affected area thoroughly with soap and water. EXCESSIVE INHALATION: Move immediately to fresh air. Administer CPR and obtain medical attention if necessary. SWALLOWING: If swallowed, obtain prompt medical attention. Do not induce vomiting unless directed by physician. Long-term exposure to completely vaporized gasoline has caused cancer in laboratory animals. Vapors or liquid penetration of skin can cause central nervous system (CNS) depression and/or systemic effects. REFER TO MATERIAL SAFETY DATA SHEET FOR FURTHER INFORMATION Arco Petroleum Products Company 515 South Flower Street Los Angeles, California 90071 I I I I I I I I I I I I I I I I I I MATERIAL SAFETY DATA SHEET ARCOSUPREME® MOTOR OIL SAE 30 MSDS No. APPC 793 Rev. Date 07/19/S5 LYONDELL PETROCHEMICAL COMPANY DIVISION 0C ATLANTIC RICHriE~D COMPANY 12000 LAWNDA~E AVENUE P.O. BOx 2~5~ HOUSTON. TEXAS 77001 IMPORTANT: Read this MSDS before handling and di~e~ing of this pred.¢t and pa.~ this information on to employee& ~stom~, afl~ u~s of Trade Telephone Numbers Name ARCOSUPREME MOTOR OIL SAR 30 EMERGENCY 800/424-9300 CHEMTREC Other Names N/P 71:3/475-4894 COMPANY CUSTOMER SERVICE ,"13/475-4215 INF0 ONLY Chemical Family PETROLEUM HYDROCARBONS & ADDITIVES Generic Name ENGINE 0IL Company CAS No. S£E SECT-'ON IX ID No. 1032810328 DOT Hazardous Materials Proper Shipping Name NOT DEFINED AS A "HAZARDOUS MATERIAL" DOT Hazard Class NOT REGULATED I UN/NA NOT REGULATED ID NO. MAY CAUSE MILO SKIN IRRITATION! AVOID PROLONGED AND/OR REPEATED SKIN CONTACT'. USED OIL MAY BE HARMFUL TO SKIN! LABORATORY STUDIES SPONSORED BY THE AMERICAN PETROLEUM INGTZTLITE SI,ION THAT MICE DEVELOP SKIN CANCER FOLLOWING REPEATED APPLICATION AND CONTINUOUS EXPOSURE TO A USED MOTOR 0IL COMPOSITE. AVOID SKIN CONTACT WITH USED MOTOR OILS. WHEN CONTACT OCCURS, WASH PROMPTLY TO REMOVE. GET MEDICAL A'r"T'ENTZON FOR ANY PERSISTENT SKIN PROBLEMS. Flash Point tMethodl i Auto(gnat(on Temperature (Method) FlammaDle L,mits (% VOL in Aid GT 425' F (D-g2) AP 775' F (EST.) Lower N/AP Upper N/AP SEE "FIRE & EXPLOSION HAZARDS" Fire and Explosion Hazards WHEN HEATED ABOVE ITS FLASH P0[NT, THIS MATERIAL WILL RELEASE FLAMMABLE VAPORS WHICH CAN BURN IN THE OPEN OR BE EXPLOSIVE IN CONFINED SPACES IF EXPOSED TO AN IGNITION SOURCE. MISTS OR SPRAYS MAY BE FLAMMABLE AT TEMPER- ATURES BELOW THE NORMAL FLASH POINT. KEEP AWAY FROM EXTREME HEAT AHD OPEN FLAME. USED MOTOR OIL MAY HAVE A GREATER FIRE HAZARD THAN THE UNUSED CiL. Extinguishing Media DRY CHEMICAL AND CARBON DIOXIDE. FOAM AND WATER FOG ARE EFFECTIVE. BUT MAY CAUSE FROTHING. Special Firefighting Procedures SE~ SLIGHTLY COMBUSTIBLEI OSHA/NFPA CLASS-IIIB COMBUSTIBLE LIOUID. FOR FIRES INVOLVING TH~S MATERIAL, D0 NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EOUIPMENT. THIS MAY INCLUDE SELF- CONTAINED BREATHING APPARATUS TO PROTECT AGAINST THE HAZAROOUS EFFECTS OF COMBUSTION PRODUCTS AND OXYGEN DEFICIENCIES. IF FIREFIGHTERS CANNOT WORK UPWIND TO THE FIRE, RESPIRATORY PROTECTIVE EQUIPMENT MUST BE WORN. COOL TANKS AND CONTAINERS EXPOSED TO FIRE WITH WATER. 227 #~FOR "DISCLAIMER OF LIABILITY," SEE THE STATEMENT ON PAGE Page 1 of ARC0$UPREME MOTOR OIL SAR 30 MSDS No. A~=C 79~ :I¥'!:::::i:i:::i i:i: :i::.': :!:::. :i. :::::" :: :::::' i.:.::: :.:.:i. :'..:.: ::.-. .. ' "" ' .... "' .... Summary of NO SIGNIFICANT ADVERSE HEA~T~ EFFECTS ARE EXPECTED UPON SHORT-TERM Acute Hazards EXPOSURE. ROUTE OF EXPOSURE SIGNS AND SYMPTOMS Primary Routetst NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED TO OCCUR UPON SHORT-TER~ Inhalation EXPOSURE. [] Eye THE BASE 0ILS IN THIS MATERIAL ARE EXPECTED TO BE NON-IRRITATING UPON Contact SHORT-TERM EXPOSURE. THE ADDITIVE MIXTURE COMPONENT MAY BE AN EYE iRRITANT. [] Skin NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED TO OCCUR UPON SHORT-TERM Absorption EXPOSURE. [] Skin ND IRRITATION IS EXPECTED FROM SHORT-TERM EXPOSURE. PROLONGED AND Irritation REPEATED SKIN CONTACT WITH SIMILIAR MATERIALS HAS PRODUCED MILD IRRITATION. ['~. NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED TO OCCUR UPON SHORT-TERM Ingestion EXPOSURE. [] PROLONGED AND/OR REPEATED SKIN CONTACT WITH THIS MATERIAL MAY PRODUCE MILD Summary of SKIN IRRITATION AND INFLAMMATION. Chronic Hazards LABORATORY STUDIES SPONSORED BY THE AMERICAN PETROLEUM INSTITUTE SHOW THAT and MICE DEVELOP SKIN CANCER FOLLOWING REPEATED APPLIATION AND CONTINUOUS Special Health EXPOSURE TO A USED MOTOR 0IL COMPOSITE. AVOID CONTACT WI'TH USEr~ MOTOR OILS. Effects PERSONNEL W,'TH PRE-EXISTING SKIN 0ISORDERS SHOULD AVOID CONTACT WITH THIS PRODUCT, :PrOtecttve:'Equtpmentand:.OtherControt:Measures::: :i: ::: ::::: :: :: :::::: ::::: ::: :: ::: .:.....: ::. :.... : ..... · .: , -. :.:.:.:: :.: . .. :. ':'.:.. ... .:. . · :::....:. :.:: :::::::::::::::::::::::::::::::::::::::::::': :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :.:::::::.:.:-. NONE iS NEEDED UNDER ANTICIPATED USE CONDITIONS WITH ADEQUATE VENTILATION. Respiratory IF EXPOSURE EXCEEDS THE OCCUPATIONAL EXPOSURE LIMITS. FOLLOW OSHA STANDARDS OR EQUIVALENT AND WEAR PROPER NI0SH/MSHA-APPROVED RESPIRATORY EQUIPMENT. WEAR EYE PROTECTION. IN THE LIKELIHOOD OF SPLASHING OR SPRAYING. AND Eye ESPECIALLY IF MATERIAL IS HOT. WEAR GOGGLES AND/OR FACE SHIELD. EYE WASH WATER SHOULD BE AVAILABLE. AV0[~ =ROLONGE0 AND/OR REPEATED SKIN CONTACT, OR WEAR IMPERVIOUS PROTECTIVE Skin CLOTHING, HANDS OR OTHER POTENTIAL SKIN CONTACT AREAS SHOULD BE WASHED WITH SOAP AND WATER WHEN LEAVING WORK. (SEE "OTHER HYGIENIC & WORK PRACTICES".) Engineering USE ADEQUATE VENTILATION TO KEEP 0IL MISTS OF THIS MATERIAL BELOW THE Controls APPLICABLE GUIDELINE(S)/STANDARD(S). (SEE SECTION VI. - OCCUPATIONAL EXPOSURE LIMITS.) WASH HANDS WITH PLENTY OF SOAP AND WATER BEFORE EATING. DRINKING. SMOKING. Other Hygienic OR USE OF TOILET FACILITIES. DO NOT USE GASOLINE, SOLVENTS. KEROSENE, OR and HARSH ABRASIVE SKIN CLEANERS FOR WASHING EXPOSED SKIN AREAS. TAKE A SHOWER Work Practices AFTER WORK IF GENERAL CONTACT OCCURS. REMOVE OIL-SOAKED CLOTHING AND LAUNDER BEFORE REUSE. DISCAR0 CONTAMINATED LEATHER GLOVES ANO SHOES, Substance Source Date Type Value/Units Time 0IL MIST, MINERAL (SEE SECTION XI) OSHA 1985 PEL 5 MG/M3 8 HRS ACGIH 1985 TLV 5 MG/M3 8 HRS STEL IO MG/M3 15 Page 2 of 4 I I I I I I I I I I I I MSDS No. ARCOSUPREME~' MOTOR OIL SAE 30 Rev. Date 07/19/85 VAPORIZATION I5 NOT EXPECTED AT AMEiENT TEMPERATURES AND THIS MATEAiAL Inhalation IS NOT EXPECTED TD BE AN INHALATION PROBLEM UNDER ANTICIPATED CONDitIONS O~ USE. FLUSH EYES W!TN CLEAN, ;Ow-PRESSURE wATER :0; AY LEAST 15 MINUTES. Eye OCCAS!ONALLv LIFTING THE EYELIDS. IF PAIN OR REDNESS PERSISTS AFTER Contact FLUSHING, OBTAIN MEDICAL ATTENTION. REMOVE EY WIPING; THEN WASH SKIN THOROUGHLY WITH PLENTY OF SOAP AND WATER. Skin REMOVE CONTAMINATED CLOTHING AND THOROUGHLY CLEAN BEFORE REUSE. DISCARD Contact CONTAMINATED LEATHER GLOVES AND SHOES. IF MORE THAN A HALF-CUP tULL OF THIS MATERIAL IS SWALLOWED. GIVE OUANTITIES Ingestion OF WATER. INDUCE VOMIT!NG, AND OETAIN MEDICAL ATTENTION. Emergency Medical Treatment Procedures SEE ABOVE PROCEDURES. Precautions if Material is Spilled or Released CONTAIN SPILL AND PREVENT IT FRO~ ENTERING ALL WATER BODIES, IF POSSIBLE. SAFELY STOP FLOW OF SPILL. EVACUATE NON-ESSENTIAL PERSONNEL FROM IMMEDIATE SPILL AREA DUE TO SLIPPING HAZARDS. IN URBAN AREA, CLEANUP AS SOON AS POSSIBLE; IN NATURAL ENVIRONMENTS. CLEANUP ON ADVICE FROM ECOLOGISTS. THIS MATERIAL WILL FLOAT ON WATER. ABSORBENT MATERIALS AND PADS CAN BE USED. COMPLY W~TH ALL APPLICABLE LAWS. SPILLS MAY NEED TO BE REPORTED TO THE NATIONAL RESPONSE CENTER (800/42A-8802). THE SPILLED MATERIAL AND ANY SOIL OR WATER WHICH ~T HAS CONTACTED ~AY BE HAZARDOUS TO ANIMAL/AQUATIC LIRE. I I Waste Disposal Methods MAXIMIZE PRODUCT RECOVER~ FOR REUSE O~ RECYCLING. CONDITIONS OF USE MAY CA~$E TH~S MATERIAL TC BECOME A "HAZARDOUS ~ASTE" AS DEFINED BY STATE OR FEDERAL LAWS, USE APPROVED TREATMENT, TRANSPORTERS. AND DISPOSAL SITE'S IN COMPLIANCE WITH ALL LAWS. CF S~[LL IS IN'RODUCED IHT= A WASTSWATER SYSTEM, THE CHEMICAL AND EIDLOGICAL OXYGEN DEMAND W:LL LIKELY INCREASE. SPILL MATERIAL IS BIODEGRADABLE IF GRADUALLY EXPOSED TO MICROORGANISMS. POTENTIAL TREATMENT AND DISPOSAL METHODS INCLUDE LAND ,FARMING. INCINERATION, AND LAND DISPOSAL. IF PERMITTED. Component Name CAS No. Carcinogen#~ Composition amount IWt.) (See Qualification on Page 4) SOLVENT-DE~*/AXED HEAVY PARAFFINIC DISTIL- 64.742-65-0' N/AP GT 90 PERCENT LATE (PETROLEUM) ADDITIVE MIXTURE CONTAINING COMPOUNDS OF N/AP LT 10 PERCENT CA, IN. S, P, & N ##Listed B~. I = N'I'P, 2 = lARD, 3 = OSHA, 4 = Other SEQ: 227 Compositions given are typical values, not specifications. Page 3 of ARCCSUPREM-- MDTO~ ~;:_ SAE 32 MSDS No. ~mC 793 8oiling Point l Viscosity Units, Temp. lMethod) Dry Point .~.T 600' FI AP 117 CST AT 100' F (D-4~tS) N/AP Freezing Point Vapor Pressure Volatile Characteristics N'Ao {MM HG AT TO' =) LT O. ~ SpecificAp O.89Gravity (HiD = I at 39.2' F): VaporGT Sp. Gr.10 (Air = 1.0 at 60'-90' Fi SolubilitYNEG~iG;SLEin Water pH Hazardous Polymerization Other Chemical Reactivity Stability NOT EXPECTE~ 'r0 OCCUR N/P STAIaLE Other Physical TYPICAL VISCOSITY INDES = 100 (ASTM D-2270), and Chemical Properties TYPICAL SAYBOLT VISCOSITY -- 540 SUS ;, IOOF i Appearance DARK AMBER-COLORED L];OUID: LUBE OIL ODOR. and Odor EXTREME HEAT AND OPEN FLAME. Conditions to Avoid Materials STRONG ACIDS. ALKALIES. AND OXIDIZERS SUCH AS to Avoid LIQUID CHLORINE AND OXYGEN. Hazardous BURNING OR EXCESSIVE HEATING MAY PRODUCE CARBON MONOXIDE AND OTHER HARMFUL Decomposition GASES/VAPORS INCLUDING OXIDES AND/OR OTHER COMPOUNDS OF CALCIUM, ZINC. SULFUR. Products PHOSRHOI~DUS. SODIUM. AND NITROGEN. ~aaltlORal':l.~recaUtlO:Rs ii!iii!ii:iii.i::. :: ' '::':'::':::::: ::'::: ::: :::":::' :::::: ::::::':::: :::::::::':::: : : !i!!i i i i i iii! KEEP OUT OF' REACH OF CHILDREN~ MINIMUM ~EASIBLE HANDLING TEMPERATURES SHOULD BE MAINTAIN-';, PERIODS OF Handling, EXPOSURE TO HIGH TEMPERATURES (GT 200' F. ) SHOULD BE MINIMIZED. WATER Storage CONTAMINATION SHOULD BE AVOIDED. and Dec3nta- ruination Procedures ORGANIC ZINC COMPOUND(S), MEASURED AS ZN = LT 0.2 WT. %. (MICHIGAN WATER RESOURCES COMMISSION CRITICAL MATERIALS REGISTER - 1984. ) General Comments SINCE SPECIFIC EXPOSURE STANDARDS/CONTROL LIMITS HAVE NOT BEEN ESTABLISHED FOR THIS MATERIAL, THE EXPOSURE LIMITS SHOWN IN SECTION Vi. ARE SUGGESTED AS MINIMUM CONTROL GUIDELINES. SOME OF THE INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE MIXTURE ITSELF. EQ = EClual AP = Approximately N/P = No Applicable Information Founcl - - - Note Qualifications: LT = Less Than UK = Unkown N/AP = Not Applicable GT= Greater Than TR = Trace N/DA = No Data Available Disclaimer of Liability The information in this MSDS was obtained from sources which we believe are reliable. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXJ~RESS OR IMPLIED, REGARDING ITS CORRECTNESS. The conditions or methods of handling, storage, usa and disposal of the product are beyond our control and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIASIMTY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, th~s MSDS information may not be aDDhcabla. Page 4 of 4 Rev No: 04 Issue No: 28 Print Date: 09/18/85 I i I I I I I I I I I I I I I I I I MATERIAL SAFETY DATA SHEET ARCOSUPREME® ~OTOR OIL SAE 10W-30 MSDS No. APPC 791 Rev. Date 07/19/85 LYONDELL PETRO~t-IEMZCAL CDMP/U~Y DIVISION Or ATLANTIC RICHFIELD COMPANY 12OCX~ LAWNDALE AVENUE P.O. BOX 2451 HOUSTON. TEXAS 77001 IMPORTANT: Read thi~ MSD$ before heed#ag aad di~eamg of th~ ~ ~d ~ th~ m~n on ~ th~ ITrade ITelephone Numbers Name ARCOSUPREME MOTOR OIL SAR 10W-30 EMERGENCY 800/424-9300 CHEMTREC Other Names N/P 713/475-4894 COMPANY CUSTOMER SERVICE 713/475-4215 INF0 ONLY Chemical DOT Hazardous Materials Proper Shipping Name Family PETROLEUM HYDROCARBONS & ADDITIVES NOT DEFINED AS A "HAZARDOUS MATER[AL" Generic Name DOT Hazard Class MULTI-GRADE ENGINE 0IL NOT REGULATED CAS No. SEE SECTION Ix ID No. 1032610326 UNINA ID No. NOT REGULATED MAY CAUSE MZLD SKIN IRRITATION! AVOID PROLONGED AHD/OR REPEATED SKIN GONTA~. USED OZL MAY BE HARMFUL TO SKZN! LABORATORY STUDIES SPONSORED BY THE AMERZCAN PETROLEI.~ INSTZTUTE SHOW THAT MZCE DEVELOP SKZN CANCER FOLLOWZNG REPEATED APPLZCATION ~ CoJ~rrIHUOUS EXPOSURE TO A USED MOTOR OIL (~:)MPOSZTE. AVOID SKIN CONTACT WITH USED MOTOR 0ILS. WHEN CONTACT OCCURS, WASH PROMPTLY TO REMOVE. GET MEDICAL ATTENTION FOR ~ PERSISTENT SKIN PROBLEMS. Flash Point (Method) GT 4OO'F (D-g2 SEE "FIRE & EXPLOSION HAZARDS' E losion: Autoignition Temperature (Method) AP 750'; (EST.) FlammaOle Limit~ (% Vol. in Air) Lower N/AP Upper N/AP Fire end Explosion Hazards WHEN HEATED ABOVE ITS FLASH POINT, THIS MATERIAL WILL RELEASE FLAMMABLE VAPORS WHICH CAN BURN IN THE OPEN OR BE EXPLOSIVE IN CONFINED SPACES IF EXPOSED TO AN IGNITION SOURCE. MISTS OR SPRAYS MAY BE FLAMMABLE AT TEMPER- ATURES BELOW THE NORMAL FLASH POINT. KEEP AWAY FROM EXTREME HEAT AND OPEN FLAME. USED MOTOR OIL MAY HAVE A GREATER FIRE HAZARD THAN THE UNUSED OIL. Extinguishing Media DRY CHEMICAL AND CARBON D[OXIDE. FOAM AND WATER FOG ARE EFFECTIVE, BUT MAY CAUSE FROTHING. Special Firefighting Procedures u SEO: SLIGHTLY COMBUSTIBLE! OSHA/NFPA CLASS-IIIB COMBUSTIBLE LIOUID. FOR FIRES INVOLVING THIS MATERIAL. DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT. TH~S MAY INCLUDE SELF- CONTAINED BREATHING APPARATUS TO PROTECT AGAINST THE HAZARDOUS EFFECTS OF COMBUSTION PRODUCTS AND OXYGEN DEFICIENCIES. IF FIREFIGHTERS CANNOT WORK UPWIND TO THE FIRE, RESPZRATORY PROTECTIVE EQUIPMENT MUST BE WORN. COOL TANKS AND CONTAZNER$ EXPOSED TO FIRE WITH WATER. 187 e~eFOR 'DISCLAIMER OF LIABILITY,' SEE THE STATEMEN'r ON PAGE Page 1 of ARCOSUPREME MOTOR OIL SAR IOW-30 MSDS No. Apse 79~ ..'.: ::~i:;~:~:¥:~:::~:~.:.;:~:~.;.~:~:~.~.~.~.;~:~:;::.:.::~:;.i:..i::.:~::~.;~:.~:~:;:::.~:.~:.;.~; ' :": '. '. ":':-'i:i:':':i¥:'::">:':":'":'::"':;: '::'"">:" :::'";'"">:': ¥":': :'; "'""" Summary of NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED UPON SHORT-TERM Acute Hazards EXPOSURE. ROUTE OF EXPOSURE SIGNS AND SYMPTOMS Primary Routeis) NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED TO OCCUR UPON SHORT-TERM Inhalation EXPOSURE. [] Eye THE BASE OILS IN THIS MATERIAL ARE EXPECTED TO BE NON-IRRITATING UPON Contact SHORT-TERM EXPOSURE. THE ADDITIVE MIXTURE COMPONENT MAY BE AN EYE IRRITANT. [] Skin NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED TO OCCUR UPON SHORT-TERM Absorption EXPOSURE. [] Skin NO IRRITATION IS EXPECTED FROM SHORT-TERM EXPOSURE. PROLONGED AND Irritation REPEATED SKIN CONTACT WITH SIMILIAR MATERIALS HAS PRODUCED MILD IRRITATION. [] NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED TO OCCUR UPON SHORT-TERM Ingestion EXPOSURE. [] PROLONGED AND/OR REPEATED SKIN CONTACT WiTH THiS MATERIAL MAY PRODUCE MILD Summary of SKIN IRRITATION AND INFLAMMATION. ;Chronic HazardS LABORATORY STUDIES SPONSORED BY THE AMERICAN PETROLEUM INSTITUTE SHOW THAT iand MICE DEVELOP SKIN CANCER FOLLOWING REPEATED APPLICATI:ON AND CONTINUOUS ISpecial Health EXPOSURE TO A USED MOTOR OIL COMPOSITE. AVOID CONTACT WITH USED MOTOR OILS. Effects PERSONNEL WITH PRE-EXISTING SKIN DISORDERS SHOULD AVOID CONTACT WITH THIS PRODUCT. and:OtherCentroli MeasU iiiiii!ii NONE IS NEEDED UNDER ANTICIPATED USE CONDITIONS WITH ADEOUATE VENTILATION. Respiratory IF EXPOSURE EXCEEDS THE OCCUPATIONAL EXPOSURE LIMITS, FOLLOW OSHA STANDARDS OR EOUIVALENT AND WEAR PROPER NIOSH/MSHA-APPROVED RESPIRATORY EOUI~MENT. WEAR EYE PROTECTION. IN THE LIKELIHOOD OF SPLASHING OR SPRAYING, AND Eye ESPECIALLY IF MATERIAL IS HOT, WEAR GOGGLES AND/OR FACE SHIELD. EYE WASH WATER SHOULD BE AVAILABLE. AVOID PROLONGED AND/OR REPEATED SKIN CONTACT. OR WEAR IMPERVIOUS PROTECTIVE Skin CLOTHING. HANDS OR OTHER ODTENTIAL SKIN CONTACT AREAS SHOULD BE WASHED WITH SOAP AND WATER WHEN LEAVING WORK. (SEE "OTHER HYGIENIC & WORK PRACTICES".) Engineering USE ADEOUATE VENTILATION TO KEEP OIL MISTS' OF THIS MATERIAL BELOW THE Controls APPLICABLE GUIDELINE(S)/STANDARD(S). (SEE SECTION VI. - OCCUPATIONAL EXPOSURE LIMITS.) Other Hygienic and Work Practices WASH HANDS WITH PLENTY OF SOAP AND WATER BEFORE EATING, DRINKING. SMOKING, OR USE OF TOILET FACILITIES. DO NOT USE GASOLINE, SOLVENTS, KEROSENE, OR HARSH ABRASIVE SKIN CLEANERS FOR WASHING EXPOSED SKIN AREAS. TAKE A SHOWER AFTER WORK IF GENERAL CONTACT OCCURS. REMOVE OIL-SOAKED CLOTHING AND LAUNDER BEFORE REUSE. DISCARD CONTAMINATED LEATHER GLOVES AND SHOES. :Substance Source Date Type Value/Units Time OIL MIST, MINERAL (SEE SCTION II) OSHA 1985 PEL 5 MG/M3 8 HRS OIL MIST, MINERAL (SEE SECTION II) ACGIH 1985 TLV 5 MG/M3 8 HRS STEL 10 MO/M3 15 MIN I i Page 2 of 4 ARCOSUPREME® ~OTOR OIL SAE 10W-30 MSDS No. APPC 791 Rev. Date 07/19/85 VAPORIZATION IS NOT EXPECTED AT AMBIENT TEMPERATURES AND THIS MATERIAL Inhalation IS NOT EXPECTED TO BE AN INHALATION PROBLEM UNDER ANT[CIPATE~ CONDITIONS OF USE. FLUSH EYES WITH CLEAN, LOW-PRESSURE WATER ;OR AT LEAST 15 MINUTEE. Eye OCCASIONALLY LIFTING THE EYELIDS. IF PAIN OR REDNESS PERSISTS AFTER Contact FLUSHING, OBTAIN MEDICAL ATTENTION. REMOVE BY WIPING; THEN WASH SKIN THOROUGHLY WITH PLENTY OF SOAP AND WATER. Skin REMOVE CONTAMINATED CLOTHING AND THOROUGHLY CLEAN BEFORE REUSE. DISCARD Contact CONTAMINATED LEATHER GLOVES AND SHOES. IF MORE THAN A HALF-CUP FULL OF THIS MATERIAL IS SWALLOWED, GIVE QUANTITIES Ingestion OF WATER, INDUCE VOMITING, AND OBTAIN MEDICAL ATTENTION. Emergency Medical Treatment Procedures SEE ABOVE PROCEDURES. Precautions if Material is Spilled or Released CONTAIN SPILL AND PREVENT IT FROM ENTERING ALL WATER BODIES, IF POSSIBLE. SAFELY STOP FLOW OF SPILL. EVACUATE NON-ESSENTIAL PERSONNEL FROM IMMEDIATE SPILL AREA DUE TO SLIPPING HAZARDS. IN URBAN AREA, CLEANUP AS SOON AS POSSIBLE: IN NATURAL ENVIRONMENTS, CLEANUP ON ADVICE FROM ECOLOGISTS. THIS MATERIAL WILL FLOAT ON WATER. ABSORBENT MATERIALS AND PADS CAN BE USED. COMPLY WITH ALL APPLICABLE LAWS. SPILLS MAY NEED TO BE REPORTED TO THE NATIONAL RESPONSE CENTER (800/424-8802). THE SPILLED MATERIAL AND ANY SOIL DR WATER WHICH IT HAS CONTACTED MAY BE HAZARDOUS TO ANIMAL/AQUATIC LIFE. Waste Disposal Methods MAXIMIZE PRODUCT RECOVERY FOR REUSE OR RECYCLING. CONDITIONS OF USE MAY CAUSE THIS MATERIAL TO BECOME A "HAZARDOUS WASTE" AS DEFINED BY STATE OR FEDERAL LAWS.. USE APPROVED TREATMENT, TRANSPORTERS, AND DISPOSAL SITES IN COMPLIANCE WITH ALL LAWS. IF SPILL IS INTRODUCED INTO A WASTEWATER SYSTEM, THE CHEMICAL AND BIOLOGICAL OXYGEN DEMAND WILL LIKELY INCREASE. SPILL MATERIAL IS BIODEGRADABLE IF GRADUALLY EXPOSED TO MICROORGANISMS. POTENTIAL TREATMENT AND DISPOSAL METHODS INCLUDE LAND FARMING, INCINERATION, AND LAND DISPOSAL, IF PERMITTED. Component Name CAS No. Carcinogen## Composition amount (Wt.) (See Qualification on Page 4) SOLVENT-DEWAXED HEAVY PARAFFINIC DISTIL- 64742-65-0" N/AP GT 90 PERCENT LATE (PETROLEUM) ADDITIVE MIXTURE CONTAINING COMPOUNDS OF N/AP LT 6 PERCENT CA, IN, S, P, & N OLEFIN COPOLYMER N/AP LT 4 PERCENT ##Listed B~ I = NTP, 2 = IARC, 3 = OSHA, 4 = Other t87 Compositions given are typical values, not specificationr. Page 3 of ARCOSUPREME MOTOR OIL SAE lOW-30 MSDS No. Ao~C 791 Boiling Point Viscosity Units, Temp. (Method) Dry Point GT 600' F AP 82 CST AT 100' F (D-445) N/AP Freezing Point Vapor Pressure Volatile Characteristics N/AP (MM HG AT ?0' FI LT 0 1 NEGLIG.~RLE Specific Gravity (HzO--I at 3g.2'FI Vapor Sp, Gr. (Air= 1.0 at 60'-90'F)lSolubilitY in Water pH A~ 0.88 GT 10I NEGLIGIBLE N/AP Hazardous Polymerization Other Chemical Reactivity Stability NOT EXPECTED TO OCCUR N/P STABLE Other Physical TYPICAL VISCOSITY INOEX zl~,O (ASTM 0-2270). and Chemical Properties TYPICAL SAYBOLT VISCOSITY = 380 SUS ·IOOF. Appearance DARK AMBER-COLORED LIQUID; LUBE OIL ODOR. and Odor EXTREME HEAT AND OPEN FLAME. Conditions ltd Avoid IMaterials STRONG ACIDS, ALKALIES. AND OXID~'ZERS SUCH AS !to Avoid LIQUID CHLORINE AND OXYGEN. !Hazardous BURNING OR EXCESSIVE HEATING MAY PRODUCE CARBON MONOXIDE AND OTHER HARMFUL Decomposition GASES/VAPORS INCLUDING OXIDES AND/OR OTHER COMPOUNDS OF CALCIUM. ZINC. SULFUR, Products PHOSPHOROUS, SODIUM. AND NITROGEN. KEEP OUT OF REACH OF CHILDREN~ MINIMUM FEASIBLE HANDLING TEMPERATURES SHOULD RE MAINTAINED. PERIODS OF !Handling, EXPOSURE TO HIGH TEMPERATURES (GT 200' F.) SHOULD BE MINIMIZED. WATER IStorage CONTAMINATION SHOULD BE AVOIDED. and Deconta- mination Procedures ORGANIC ZINC COMPOUND(S). MEASURED AS ZN = LT 0.2 WT. %. (MICHIGAN WATER RESOURCES COMMISSION CRITICAL MATERIALS REGISTER - 1984. ) General Comments SINCE SPECIFIC EXPOSURE STANDARDS/CONTROL LIMITS HAVE NOT BEEN ESTABLISHED FOR THIS MATERIAL, THE EXPOSURE LIMITS SHOWN IN SECTION VI. ARE SUGGESTED AS MINIMUM CONTROL GUIDELINES. SOME OF THE INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE MIXTURE ITSELF. EQ = EClual AP = Approximately N/P = No Applicable Information Found Note Qualifications: LT = Less Than UK = Unkown N/AP = Not Applicable GT = Greater Than TR = Trace N/DA = No Data Available Disclaimer of Liability The information in this MSDS wee oDteinad from sour¢ll which we Oolisve are reliable. HOWEVER, THE INFORMA'RON I$ PROVIDED WITHOUT ANY WARRANTY, EXPRESS OR IMPUED, REGARDING ITS CORRECTNESS. The conditions or methods of handling, storage, use and disposal of the procluc! ere beyond our control and may be beyond our knowledge. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM UABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDUNG, STORAGE, USE OR DISPOSAL OF THE PRODUCT. This MSOS wee prepared and is to be used only for this product. If the product is uae4 as I component in Inothm' product, this MSDS information may not Da ePPlic~la, Page 4 of 4 Rev No: 04 Issue No: 34 Print Oat~. 09/18/85 I i I I ! MATERIALSAFETY DATA SHEET t I MSDS No. J ARCO® UNLEADED SUPREME GASOLINE I I Rev Date ~ ~1~ IM~OR?A~r: Re,a th,- MSOS b.~o~ ~ ~ DIVISION OF ATLANTIC RICHFIELD COMPANY Im~, ~m, ud ~ of ~~ 515 SOUTH FLOWER STREET ~~ LOS ANGELES, CAL[FORNIA 90071 ~.~t 08HA Nm ~m~n~mn Rub. Trade j Telephone Numbers :Name ARCO UNLEADED SUPREME GASOLZNE//ARCO SUPER UNLEADED GASOL2NE ~ EMERGENCY I 8~/424-93~ CHEMTREC O~er Names UNLEADED MOTOR VEHICLE GASOLINE ~ 312/2t0-3~ COMPANY UNLEADED PREMIUM GASOLINE OR PETROL ~ CUSTOMER SERV[CE ' I 213/486-8258 ~NFO ONLY ~he~igal J DOT ~do~ M~erials Proper Shipping Name family HYDROCARBONS ~ZTH ALCOHOLS A~/0R ETHERS I GASOLINE ~Generi¢ Name loot H~ard ~ETROLEUM NAPHTHAS (BLENDED) I FLA~ABLE L~QU[D ID No 1~961~6 ~INA ID No. UN 1203 E~REMELY F~LE! O~Pl ~-Zl F~LE LZ~ID. KEEP A~AY F~ ~AT, SP~, ~ OP~ F~E! ~SE Z~ZTATZ~ T0 EYES, ~ZN, ~ RE~Z~RY SY~! A~ZD BREA~ V~ OR MIST. USE ~LY VZ~ ~E~TE ~-TE~ E~E T0 ~L~ELY V~RZZED ~LZ~ ZN ~O~RY ~ZKS. V~ OR L1~ZD P~TZ~ ~E~ NER~S SYSTEM (~) DEPRESSZ~ ~/~ SYST~Z: EFFE~S. ~FUL 0R FAT~ ZF SV~ED~ ~AZ~ PE~LE~ DZSTZL~TES~ VZLL ~SE ~EMZ~L ~ZA. ~TAZN ~T ~DZ~ A~E~Z~. Flash Point (Method) I AutoigniUon Temperature (Method) I FllmmlOla Lim,~ (% VOl. in AJr~ I At Normal AtmoePheric Tamperltura and Pressure AP -45'F (D-BG)'1 GT 600'F (E-GB9)ilo.,,AP 1.3 UlN)er AP 8.2 SEE "FIRE & EXPLOSION HAZARDS' I BASED ON ACTUAL LAB TESTS I BASED ON ACTUAL LAB TESTS I I EXTREMELY FLAMMABLE! THIS MATERIAL RELEASES VAPORS AT OR BELOW AMBIENT Fire and TEMPERATURES. WHEN MIXED W-ITH AIR IN CERTAIN PROPORTIONS AND EXPOSED TO AN Explosion IGNITION SOURCE, THESE VAPORS CAN BURN IN THE OPEN OR EXPLODE IN CONFINED Hazards SPACES. BEING HEAVIER THAN AIR. FLAMMABLE VAPORS MAY TRAVEL LONG DISTANCES ALONG THE GROUN0 BEFORE REACHING A POINT OF IGNITION AND FLASHING BACK. Extinguishing Media FOAM C02 DRY CHEMICAL HALON CONSULT FOAM MANUFACTURERS FOR APPROPRIATE MEDIA, APPLICATION RATES, AND WATER/FOAM RATIO. Spegial Firef ighting Procedures SUB-SURFACE APPLICATION IS ONLY RECOMMENDED WHERE IT IS KNOWN THAT THE FUEL CONTAINS LESS THAN 3% OXYGENATED BLENDING COMPONENTS. FOR FIRES INVOLVING THIS GASOLINE, DO NOT ENTER ANY ENCLOSED OR CONFINED FIRE SPACE WITHOUT PROPER PROTECTIVE EQUIPMENT. THIS MAY INCLUDE SELF-CONTAINED BREATHING APPARATUS TO PROTECT AGAINST THE HAZARDOUS EFFECTS OF COMBUSTION PRODUCTS AND OXYGEN DEFICIENCIES. WATER FOG OR SPRAY ARE OF VALUE FOR COOLING TANK SHELLS AND SURFACES EXPOSED TO FIRE, BUT MAY NOT ACHIEVE EXTINGUISHMENT. SE(~ 10'/ ===70R 'DISCLAIMER OF LIABILITY,' SEE THE STATEMENT ON PAGE 4m Page 1 of 4 ARCO UNLEADED SUPREME GASOLINE MSDS No. APPC 252 l ~ ,I Summary of LIOUID, MIST OR VAPORS CAN CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION Acute Hazards AND CNS DEPRESSION. ASPZRATION INT0 LUNGS WILL CAUSE CHEMICAL PNEUMONIA. ROUI~OFEXPOSURE SIGNS AND SYMPTOMS Prtmary Route,. EXPOSURE CAN CAUSE IRRITATION TO THE NOSE, THROAT, & LUNGS AND SIGNS OF CNS Inhalation DEPRESSION (DIZZINESS, DROWSINESS, LOSS OF COORDINATION. COMA AND DEATH), [] DEPENOZNG*0N THE CONCENTRATZON/OURATION OF EXPOSURE. (SEE "SUMMARY" BELOW.) Eye MILD EYE IRRITATION MAY RESULT FROM CONTACT WITH LIQUID. MIST. AND/OR :Contact VAPORS. Skin Absorption Skin Irritation Ingestion LIQUID CAN PENETRATE SKIN TO CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION. VAPOR PENETRATION CAN ALSO CAUSE SYSTEMIC EFFECTS. [] u SKIN IRRITATION LEADING TO DERMATITIS MAY OCCUR UPON PROLONGE0 AND REPEATED CONTACT DUE TO SKZN DEFATTING. ~xl IRRITATION OF THE MOUTH. THROAT & GASTROINTESTINAL TRACT LEADING TO NAUSEA. VOMITING, DIARRHEA AND RESTLESSNESS. CNS DEPRESSION SIMILAR TO THAT CAUSED [] BY VAPOR INHALATION. ASPIRATION INTO LUNGS WILL CAUSE CHEMICAL PNEUMONIA. AN A.P.I.-SPONSOREO STUDY HAS SH0¥N THAT RATS AND MICE DEVELOPED CANCER Summary of FOLLOWING CHRONIC INHALATION EXPOSURE TO THE VAPORS OF UNLEADED GASOLINE. Chronic Hazards LONG-TERM EXPOSURE TO UNLEADED' GASOLINE HAS ALSO PRODUCED KIDNEY DAMAGE ZN and LABORATORY ANIMALS. THE EXACT RELATIONSHIP BETWEEN THESE RESULTS A~ Sp~iil ~a~ POSSZBLE ~MAN EFFECTS ZS ~T K~. PERSO~EL VZTH PRE-EXZSTZ~ SKZN Eff~ts D~SOROERS, ZMPAZRED LZVER OR KZONEY FU~T~ON, OR CENTR&~ NERVOUS SYSTEM A~ CHRONZC RESPZRATORY DZLSEASES S~ULD AVOZD EXPOSURE TO THZS MATERZAL. USE NZOSH/MSHA-APPROVED RESPZRATOR ~EN VAPOR LEVELS EXCEED EXPOSURE LZMZTS Respir~o~ ZN SECTION VI. USE FULL-FACEPZECE ~SK ABOVE 6~ PPM ~SOLZNE VAPORS, A~ SUPPLIED-AIR OR SCBA E~ZPME~ ABOVE 1~ PPM. (SEE 'OTHER' BOX BEL0~. ) EYE PROTECTZ~ S~ULD BE ~ ~ENEVER THERE ~S A LZKELZ~OD OF SPLASHING Eye OR SPRAYZ~ LZ~ZD. C~ACT LENSES S~ULD ~T BE ~ORN. SUITABLE EYE WASH ~ATER S~ULD BE AVAILABLE. AVOZD PROLO~ED A~/OR REPEATED SKZN CONTACT. ZF CO~ZTZONS OR FREQUENCY Skin OF USE MAKE CONTACT S[~[F[CANT, CLEAN A~ [MPE~[0US PROTECTIVE CLOTHING SUCH AS GLOVES, APRON, BOOTS, A~ FACIAL PROTECTZON SHOULD BE ~ORN. Engineering Controls Other Hygienic and Work Practices USE ADEOUATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF THIS MATERIAL BELOW THE OCCUPATIONAL EXPOSURE LIMITS SHOtt~t BELOW ZN SECTION VI. (SEE SECTION XI.-'GENERAL COMMENTS".) USE GOOD PERSONAL HYGIENE PRACTZCES. ZN CASE OF SKZN CONTACT, WASH WITH MILD SOAP AND WATER OR & WATERLESS HAND CLEANER. ZMMEOZATELY REMOVE SOAKED CLOTHZNG AND WASH T~OROU(~LY BEFORE REUSE. DZSCARD ~SDLZNE-SOAKED SHOES. RESPIRATOR USE SHOULD COMPLY W~TH OSHA STANDARDS. CONTROL OCCUPATIONAL EXPOSURES BELOW 1 PPM "BENZENE' RATHER THAN THE 300 PPM "GASOLINE" TLV. Substance BENZENE (ADOPTED BY ATLANTIC RICHFIELD) BENZENE (TYPE 'A2' CARCINOGEN) GASOLINE (SEE SECTION METHYL ALCOHOL (METHANOL) - SKIN ETHYL ALCOHOL (ETHANOL) TERT-BUTYL ALCOHOL (TB&) Source Date Type Value/Units ARCOEL 1983 TWA I PPM PEAK 25 PPM ACGIH 1985 TLV 10 PPM STEL 25 PPM ACGIH 1985 TLV 300 PPM STEL 500 PPU ACGIH 1985 TLV 200 PPM STEL 250 PPM ACGZH t985 TLV 1000 PPM ACGZH 19B5 TLV 100 PPM STEL 150 PPM Time 12 HRS 15 8 HRS 15 MZN 8 HRS 15 15 MINI m Page 2 of 4 I I I I I I I I I I I I I MSDS No. ARCO® UNLEADED SUPREME GASOLINE APPC 252 Ray. Date 06/12/85 IMMEDIATELY MOVE PERSONNEL TO AREA OF FRESH AIR. FOR RESPIRATORY DISTRESS, Inhalation GIVE AIR, OXYGEN, OR ADMINISTER CPR (CARDIOPULMONARY RESUSCITATION). IF NECESSARY. OBTAIN MEDICAL ATTENTION IF BREATHING DIFFICULTIES CONTINUE. Eye Contact FLUSH WITH CLEAN LOW-PRESSURE ~ATER FOR AT LEAST 15 MINUTES. PERSISTS. OBTAIN MEDICAL ATTENTION. IF IRRITATION Skin Contact Ingestion IMMEDIATELY REMOVE CONTAMINATED CLOTHING. WASH AFFECTED SKIN THOROUGHLY WITH SOAP AND ~ATER, IF IRRITATION PERSISTS. SEEK MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE, BUT DISCARD CONTAMINATED LEATHER SHOES/GLOVES. DO NOT INDUCE VOMITING. SINCE ASPIRATION INTO THE LUNGS WILL CAUSE CHEMICAL PNEUMONIA. IF ASPIRATION OCCURS, PROMPTLY OBTAIN MEDICAL ATTENTION. Emergency Medical Treatment Procedures SEE ABOVE PROCEDURES. CONTAIN SPILL. REMOVE ALL IGNITION SOURCES AND SAFELY STOP FLOW OF SPILL. IN URBAN AREAS. CLEANUP AS SOON AS POSSIBLE: IN NATURAL ENVIRONMENTS, SEEK Precautions ADVICE FROM ECOLOGISTS. EVACUATE ALL NON-ESSENTIAL PERSONNEL. USE PROPER if Material PROTECTIVE EQUIPMENT. BLANKET WITH FOAM OR USE; WATER FOG TO DISPERSE is Spilled VAPORS. PADS AND ABSORBANT MATERIAL CAN BE USED. GASOLINE WILL FLOAT ON or Released WATER AND RESULTING RUNOFF MAY CREATE AN EXPLOSION OR FIRE HAZARD. COMPL~ WITH ALL APPLICABLE LAWS. SPILLS MAY NEED TO BE REPORTED TO THE NATIONAL RESPONSE CENTER (800/424-8802). GASOLINE OR CONTAMINATED MATERIALS MAY BE HAZARDOUS TO HUMAN AND OTHER LIFE. Waste Disposal Methods MAXIMIZE PRODUCT RECOVERY FOR REUSE PRIOR TO DISPOSAL. DISPOSE OF PRODUCT. CONTAMINATED MATERIAL. AND STORAGE TANK ~ATER BOTTOMS AS AN EPA "IGNITABLE HAZARDOUS ~ASTE' (DO01), UNLESS PROVEN OTHERWISE. USE APPROVED TREATMENT, TRANSPORTERS, AND DISPOSAL SITES IN COMPLIANCE WITH ALL LAWS. TANK BOTTOMS AND TANK WATER BOTTOMS MAY BE HAZARDOUS TO HUMAN, ANIMAL AND ADUATIC LIFE. IF SPILL IS INTRODUCED INTO A WASTEWATER SYSTEM. THE CHEMICAL AND BIOLOGICAL OXYGEN DEMAND WILL LIKELY INCREASE. SPILL MATERIAL BIODEGRADABLE IF GRADUALLY EXPOSED TO MICROORGANISMS. A POTENTIAL DISPOSAL METHOD IS INCINERATION. I ...... " ..... '"'"''" ' ' '1'"'"¥" '"'"'r'"""I"'I'I'T'J'I'"T'I'I "1"¥1'1 '1 ' '1 "1"¥ ' '" '""l'T''~' '" .............................. i : : : : :':':':'":" '/'*" '" ":'"'"'" '"''" Component Name CAS No. Cersinogen## Compoaition amount (VOL) HYDROCARBONS WITH A BOILING POINT RANGE OF 70'F. TO 440'F. METHYL TERTIARY-BUTYL ETHER (MTBE) GASOLINE-GRADE TERTIARY-BUTYL ALCOHOL ETHANOL METHANOL BENZENE N/AR AP (See Qualification on Page 4) 89 TO 99 PERCENT 1634-04-4 N/AP AP 0 TO 11 PERCEN~ 75-65-0 N/AP AP 0 TO 10 PERCENT 64-17-5 N/AP AP 0 TO 10 PERCENT 67-56-1 N/AP AP 0 TO 5 PERCENT 71-43-2 1,2, ,4 LT S PERCENT #~l. isted BT I = NTP, 2 = IARC, 3 = OSHA, 4 = Other IO7 Compositions given ere typical values, not specifications. Page 3 of I ARCO UNLEADED SUPREME GASOLINE MSDS NO. APPC 252 g ....... !i ...... ii ............. .... ........... iii I Boiling Point Viscosity Units, Temp. IMethod) Dry Point 70' TO 440' F N/AP AP 430' F Freezing Point Vapor Pressure Volatile Characteristics N/AP (RE.ID-PSIA AT IOO'F) aP 8 TO t5 APPRECIABLE Specific Gravity (H,O = I at 39.2'F) Vapor Bp. Gr. (Air = 1.0 at 60'-S0'miSolubility in Watari pH AP 0.73 TO 0.78 " AP 3.5 ! SEE BELOW. N/AP Hazardous Polymerization Other Chemical Reactivity Stability NOT EXPECTED TO OCCUR N/P STABLE Other Physical WATER IN CONTACT WITH OXYGENATED GASOLZNE CAN CON- and Chemical Propertlec TAIN UP TO 80% OXYGENATE B HYDROCARBON MATERIALS. Appearance and Odor Conditions to Avoid PINK TO RED-COLORED LIQUID; PETROLEUM NAPHTHA ODOR. HEAT. SPARKS. AND OPEN FLAME. Materials to Avoid AVOID CONTACT WITH WATER. REACT5 WITH STRONG ACIDS AND STRONG OXIDIZING MATERIALS. Hazardous BURNZNG OR EXCESSTVE HEATTNG MAY PRODUCE CARBON Decomposition MONOXIDE AND OTHER HARMFUL GASES AND VAPORS. Products " ~:~~*:~:~:~:~~~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~~~:~:~:~~~:~:~:~:~:~:*:~:~:~:~:~:~:~:~:~:~:~:~:~:~:.:.F:.:.:.:.:.:.:~..~. r'ITI'T I''' ITl ......... IIITI '111'''11'1 I'TI'III' ''1111'1 .................... T'T'I ..... Ill ..... ] 'T .............. STORE AND TRANSPORT IN ACCORDANCE WITH ALL APPLTCABLE LAWS. KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME! KEEP CONTAINERS CLOSED AND NOT TN CLOSED VEHICLES. CONTATNERS SHOULD BE ABLE TO MIZTHSTAND PRESSURES EXPECTED FROM YARMTNG OR COOLTNG ~N STORAGE. GROUND ALL DRUMS AND TRANSFER VESSELS VHEN Handling, HANDLTNG. THE PRESENCE OF BLENDTNG COMPOUNDS ZN THTS GASOLINE MAY REQUTRE Storage USE OF SPECIAL PROCEDURES AND PROTECTIVE EQUIPMENT FOR TANK, VESSEL. OR and OTHER ENCLOSED SPACE ENTRY. REFER TO AMERICAN PETROLEUM INSTITUTE PUBLICA- Deconta- TIONS RP 2015 AND 2015A FOR SPECTAL PRECAUTTONS. ALL ELECTRICAL EQUIPMENT mination IN GASOLINE STORAGE AND/OR HANDLZNG AREAS SHOULD BE INSTALLED ZN ACCORDANCE Procedures WITH APPLTCABLE REQUIREMENTS OF THE NATZONAL ELECTRICAL CODE, N.F.P.A. KEEP OUT OF REACH OF CHTLDRENI EMPTY CONTAINERS RETAIN SOME LTOUTD/VAPOR RESIDUES; HAZARD PRECAUTTONS MUST BE OBSERVED WHEN HANDLTNG EMPTTES. USE OF ANY HYDROCARBON FUEL ZN SPACES WITHOUT ADEQUATE VENTILATION MAY RESULT IN GENERATION OF HAZARDOUS LEVELS OF VAPOR AND/OR INADEQUATE OXYGEN LEVELS. FOR USE ONLY AS A MOTOR FUEL. DO NOT USE GASOLINE AS A CLEANING AGENT. SOME ACGIH AND OSHA EXPOSURE LIMITS ARE NOT LTSTED ZN SECTION VT. BECAUSE THEY ARE LESS RESTRICTIVE THAN THE EXPOSURE LIMITS DISPLAYED. General THE TERTIARY-BUTYL ALCOHOL COMPONENT OF THTS PRODUCT HAS PRODUCED URINARY Comments HYPERPLASIA. TESTZCULAR DEGENERATION, AND FETAL TOXICITY ZN LABORATORY ANIMALS. THE EXACT RELATZONSHTP BETWEEN THESE RESULTS AND POSSIBLE HUMAN EFFECTS ZS NOT KNOWN. METHANOL CAN PRODUCE BLINDNESS ZN HUMANS. THERE WERE NO BENZENE-INDUCED EFFECTS NOTED ZN STUDIES ON LABORATORY ANIMALS AFTER LONG-TERM EXPOSURE TO VAPORS OF AN UNLEADED GASOLTNE SAMPLE CONTAINING 2 VOL.% BENZENE. A RECOGNIZED HUMAN CARCINOGEN. HOWEVER, THE RZSK OF BENZENE-ZNOUCED TOXZCTTY OR CARCZNOGENICZTY ASSOCTATED WITH THIS PRODUCT ~S NOT KNOWN. 'PETROLEUM 0~STILLATE'--16 CFR IBOO. 14(B)(3). USE SPECIAL FEDERAL LABELING IF TNTENDED, OR PACKAGED, FOR USE IN THE HOUSEHOLD OR BY CHTLDREN. SOME OF THE INFORMATTON PRESENTED AND CONCLUSIONS DRAWN HEREZN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE MIXTURE ITSELF. EQ - Equal AP ~ ADProximlteiy Note - - - Qualification~ LT - Less Than UK NIP- No Aplllica~le information Found N/AP - Not AOplicable N/DA - No Data Available Dlacleimer of Liability The information in thai MSDS was Obtoiflld from I~urcel which wi II. lOire Itl reliable. HO~I~rV~R, THE INFORMATION lB PROVIDED WITHOUT ANY WARRANTY, EX, RES8 OR IMPUED, REGARDINI rll ~ORRECTNES~. The conclitlonl or motho(is of handling, ItO~lgl. gll ~ dilpOlll of the prociuct irs I)eyond our cof~rol and rely be beyond our knowlodga. FOR THIS AND OTHER REASONS. WE DO NOT AlllJIdl RP. JPONIJIlUTY AND EXPRESSLY DISCLAIM LJAIILITY FOR LOBS, DAMAGE OR EXPENSE ARI81NO OUT OF OR IN ANY WAY CONNlCr~D WITH THE HANOUNG, ITORAGE, UBS OR OI~POIAL OF THE PRODUCT. Thi~ MSDS w.s Wowed J~d is to be used only for this procure, if the p~educt ii used u i oonNx)Nm in enothM promJct, this MSDS information may not be SlN)liclbie. Page 4 of 4 Rev PiG: 09 Issue ~ 54 Print Date: 0B/11/85 ! ! DANGER GASOLINE (All Grades) MOHAWKR REG. 87 OCTANE NO LEAD REGULAR EXTRDiELY FI.a2i~BLE MAY CAUSE EYE, SKIN AND RESPIRATORY IRRITATION · MAY BE HARMFUL IF INHALED OR ABSORBED THROUGH SKIN* HARMFUL OR FATAL IF SWALLOWED. CONTAINS PETROLEUM DISTILLATES. ASPIRATION INTO THE LUNGS WILL CAUSE CHEMICAL PNEUMONIA. Keep away from heat, sparks and open flame Avoid breathing vapors or mists Use only with adequate ventilation Avoid liquid, mist and.vapor contact Wash thoroughly after handling Keep out of reach of children FIRST AID EYE CONTACT: Flush eyes with clesn water for 15 minutes. SKIN CONTACT: Wash affected area thoroughly with soap and water. EXCESSIVE INHALATION: Move immediately to fresh air. Administer CPR and obtain medical attention if necessary. SWALLOWING: If swallowed, obtain prompt medical attention. Do not induce vomiting unless directed by physician. Long-term exposure to completely vaporized gasoline has caused cancer in laboratory animals. Vapors or liquid penetration of skin can cause central nervous system (CNS) depression and/or systemic effects. I I I REFER TO MATERIAL SAFETY DATA SHEET FOR FURTHER INFORMATION Arco Petroleum Products Company 515 South Flower Street Los Angeles, California 90071 m6110785 GROUNDWATER TECHNOLOGY, INC. 4101^lken Street, Suite B4, Bakersfield, CA 93308 (805) 589-8601 September 21, 1992 FAX (805) 589-8605 Mr. Joseph A. Dunwoody Hazardous Material Specialist Hazardous Material Division Bakersfield City Fire Department 2130 G Street Bakersfield, California 93301 RE: Site Assessment Report, ARCO Facility No. 6218, Bakersfield, California Dear Mr. Dunwoody: Enclosed is an assessment report for the subject facility. A total of nine borings have been drilled and sampled to assess subsurface conditions at the site. Total petroleum hydrocarbons as gasoline (TPHG) and benzene concentrations range from < 10 to 2,700 rog/kg and <0.005 to 3.2 mg/kg, respectively, within a plume associated with former underground storage tanks. Maximum concentrations of TPHG and benzene occur at depths of 25 and 40 feet respectively. A detailed site-specific analysis using the SESOIL and AT123D models indicates that the concentrations of benzene, toluene, ethylbenzene, and total xylenes (BTEX) present at the site will not degrade groundwater throughout a 99 year simulation· A no-action remedial alternative is recommended based on these findings. Groundwater Technology has used this same approach to obtain closure at several sites within Kern County. We would be happy to meet with you and discuss the modeling results. If you have any questions or would like to schedule a meeting, please contact me at (805) 589-8601. Sincerely, GROUNDWATER TECHNOLOGY, INC. · Parker, R~ Operations Manager cc: Kateri A. Luka, ARCO Products Company Offices throughout the U.S., Canada and Overseas Prepared For: Ms. Kateri A. Luka ARCO Products Company 1'43-; 5 ........... otuuuua~, ~or-d Cerritos, California 90701 (213) 402-1281 SITE ASSESSMENT REPORT ARCO SERVICE STATION NO. 6218 4203 MING AVENUE BAKERSFIELD, CALIFORNIA September 14, 1992 Prepared By: Groundwater Technology, Inc. 4101 Alken Street, Suite B-1 Bakersfield, California 93308 (805) 589-8601 Written By: ~ na~than D. Registered Geol~ No. 4728 Reviewed By: S~p~han A. Bork Registered Environmental Assessor No. 3614 TECHNOLOC¥ EXECUTIVE SUMMARY Nine borings have been drilled and sampled to assess subsurface conditions at ARCO facility no. 6218. Laboratory analysis of soil samples collected during this assessment indicates gasoline hydrocarbons are present below the former location of underground storage tanks. Total petroleum hydrocarbons as gasoline (I'PHG) and benzene concentrations range from < 10 to 2,700 mg/kg and <0.005 to 3.2 mg/kg, respectively. Maximum concentrations of TPHG and benzene occur at depths of 25 and 40 feet respectively. Site conditions do not allow the use of leaching potential analysis or general risk appraisal methods to determine acceptable concentrations of hydrocarbons which can be left in place without threatening groundwater (LUFT, 1989). A detailed site-specific analysis using the SESOIL and AT123D models indicates that the concentrations of benzene, toluene, ethylbenzene, and total xylenes (BTEX) present at the site will not degrade groundwater throughout a 99 year simulation. Possible remedial action alternatives considered for the site include no action, soil venting, and excavation. No action is the preferred alternative because contaminant transport modeling indicates groundwater will not be impacted. Soil venting is considered feasible but cost prohibitive. The excavation alternative is not considered feasible because of high cost and the required destruction of surface facilities. Site ,a,~ssessment Report ARCO Products Company September 14, 1992 GROUNDWATER TECHNOLOGY TABLE OF CONTENTS PAGE EXECUTIVE SUMMARY ........................................................... ii 1.0 INTRODUCTION 2.0 SITE BACKGROUND 4.0 SITE ASSESSMENT ......................................................... 2 4.1 Procedures .......................................................... 2 4.2 Analytical Results ..................................................... 3 5.0 RISK ANALYSIS .............................................................. 4 5.1 SESOIL Modeling ...... ...................................... ~ ......... 4 5.1.1 Model Input Parameters .............................................. 5 5.i.1.1 Sediment Characteristics ......................................... 6 5.1.1.2 Contaminant Application ......................................... 7 5.1,1.3 Conservatism ................................................. 8 5.1.2 SESOIL Output .................................................... 8 5,2 AT123D Modeling ...................................................... 8 5.2.1 Model Input Parameters ............................................. 10 5.2.2 AT123D Output ................................................... 10 6.0 FEASIBILITY STUDY ........................................................ 10 6.1 No Action .......................................................... 10 6.2 Soil Venting .......................... ' ............................... 11 6.3 Excavation .......................................................... 11 7.0 REMEDIAL ACTION PLAN .................................................... 12 8.0 REFERENCES ............................................................. 13 Site Assessment Report ARCO Products Company September 14, 1992 ~-~ GROUNDWATER iii I[~][~l TECHNOLOGY LIST OF ILLUSTRATIONS TABLES Table 1. Table 2. Table 3. Table 4. Table 5. Table 6. Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Analytical Results, Soil Samples From Borings ................................... 3 Leaching Potential Analysis .................................................. 5 General Risk Appraisal Applicability Checklist .................................... 6 Maximum Pollutant Depths of Detectable BTEX .................................. 9 Pollutant Mass in Groundwater Runoff ......................................... 9 Maximum Pollutant Concentrations in Groundwater .............................. 11 FIGURES 1. Location Index 2. Site Map/Boring Locations 3. Sample Locations 4. Site Geology 5. Depth to Groundwater 6. Groundwater Gradient 7. Cross-Section Index and TPHG Contours 8. Cross-Section A 9. Cross-Section B 10. Soil Compartments 11. Application Area APPENDICES Appendix A. Background Data Table Al. Analytical Results, Soil Samples Beneath Tanks Table A2. Analytical Results, Soil Samples Beneath Dispenser Islands and Piping Table A3. Analytical results, Soil Samples From Borings Appendix B. Appendix C. Appendix D. Appendix E. Appendix F. Appendix G. Appendix H. Lithologic Logs Disposal Documentation Laboratory Reports SESOIL Climate and Chemical Data Input 95% Upper Confidence Level and Pollutant Load Calculations Abbreviated SESOiL Output Files Abbreviated AT123D Output Files Site Assessment Report ARCO Products Company September 14, 1992 iv C.OUNOWATE. 1.0 INTRODUCTION Groundwater Technology, Inc. has been contracted by ARCO Products Company to perform a site assessment at their facility no. 6218 in Bakersfield, California (Figure 1). The purpose of the assessment is to further define the extent of hydrocarbon contamination which is present at the site. This report documents the findings of the assessment. 2.0 SITE BACKGROUND A preliminary assessment of soil conditions was completed at the site on February 22 and March 5, 1991 (GTI, 1991a). The assessment consisted of drilling four borings (B1 through B4) at the locations shown in Figure 2. Soil samples were collected and field screened with a photoionization detector (PID) at 5- foot depth increments. Two samples from each boring were submitted for laboratory analysis. Those selected included the sample from the bottom of each boring and the sample which exhibited the highest headspace-analysis concentration of hydrocarbons as determined with the PID. The samples were analyzed for benzene, toluene, ethylbenzene, and xylenes (BTEX) and total petroleum hydrocarbons as gasoline (TPHG). BTEX and TPHG were not detected. On May 15, 1991, Wegener Construction removed three underground storage-tanks at the facility (GTI, 1991b). No holes were found in any of the tanks, but rust was observed on all tanks. A total of 26 soil samples were collected at the site following tank removal operations. Tank pit samples were collected at depths of 2 and 6 feet beneath both ends of each tank. Soil samples were also collected from beneath the product lines and the ends of the dispenser islands at depths of 2 and 6 feet. TPHG concentrations in the samples from beneath the tanks ranged from < 10 to 4,600 mg/kg. TPHG concentrations in samples collected from the beneath the dispenser islands ranged from 24 to 4,800 mg/kg. TPHG was not detected in samples collected from beneath the product lines. Laboratory results are summarized in Tables A1 and A2 in Appendix A, and in Figure 3. On September 11 and 12, 1991, Groundwater Technology completed six borings at the site (B5 through B10; GTI, 1991c). TPHG was not detected in samples from the borings near the dispenser islands. TPHG concentrations in samples collected from borings at the former tank location ranged from 40 to 2,700 mg/kg. However, TPHG was not detected in samples from these borings collected below a depth of 40 feet (Appendix A). Site Assessment Report ARCO Products Company September 14, 1992 [][][] C.OUNDWATE. TECHNOLOGY 3.0 REGIONAL SETTING The site is located on the alluvial plain of the Kern River. Topography in the region is fiat, and no natural bodies of water adjoin the site. The station is located in a commercial area and is approximately 2,500 feet southwest of the nearest school. The site overlies alluvial-fan deposits of the Kern River (Figure 4). Sediments underlying the region consist of fluvial deposits including silt, sand and gravel. Sediments encountered during drilling and excavation activities at the site consist primarily of medium- to coarse-grained sand and silty sand, with local deposits of clayey silt. An unconfined aquifer is present below thb site at a depth of approximately 160 feet (Figure 5). The gradient of this aquifer is generally toward the southeast (Figure 6). Shallow, perched water has not been identified in the vicinity of the site (KCWA, 1990). 4.0 SITE ASSESSMENT The current assessment of subsurface conditions at the site consisted of the completion of three soil borings and the analysis of soil samples by a state-certified laboratory. Field activities were completed on June 25 and 26, 1992. 4.1 PROCEDURES Three borings (Bll through B13) were drilled at the locations shown in Figure 2. The borings were drilled to further define the lateral extent of contamination in order to evaluate potential threats to groundwater. All of the borings were drilled vertically. Information regarding total depth and the type of sediment encountered is presented on the lithologic logs in Appendix B. Soil samples were collected at 5-foot depth increments using a split-spoon sampler lined with brass sample rings. The material from one sample ring was described and field screened with a PID. A second ring was sealed at each end with a teflon sheet, plastic cap, and non-hydrocarbon tape. The samples were labelled, sealed in waterproof bags and placed on ice pending delivery to an analytical laboratory. Between sampling events, the sampler and rings were washed with non-phosphate detergent and rinsed successively with tap and distilled water. ,. Site Assessment Report ARCO Products Company September 14, 1992 2 GROUNDWATER TECHNOLOGY All of the borings were back-filled with sand-cement grout upon completion of work. Drill cuttings were stored temporarily on site in appropriately labeled drums. The cuttings were disposed of at Laidlaw's Buttonwillow facility on August 1, 1992. Decontamination rinse water was disposed of at Demenno Kerdoon in Compton on July 28, 1992 (Appendix C). 4.2 ANALYTICAL RESULTS The deepest sample from each boring was submitted for laboratory analysis. Selected additional samples were also analyzed to define hydrocarbon concentrations within the contaminant plume. The samples were sent via overnight courier to state-certified GTEL Environmental Laboratories in Torrance, California (Cert.#723). The samples were transported following standard chain-of-custody procedures and were analyzed for TPHG and BTEX using EPA methods 8015, modified and 8020. TPHG and benzene were detected in the sample from a depth of 35 feet in boring Bll at concentrations of 48 and 1.0 mg/kg, respectively (Table 1). Neither TPHG nor benzene was detected in any of the other samples analyzed. Other volatile compounds were detected in all of the samples except B12-40' and B13-35'. Laboratory reports and chain-of-custody documentation are presented in Appendix D. Table 1. Analytical results (in mg/kg) of soil sam 31es from borings, 6/25/92 - 6/26/92. Sample No. Benzene Toluene Ethyl- Xylenes TPHG benzene B 11-30' < 0.005 < 0.005 0.008 0.087 < 10 B11-35' 1.0 7.1 1.3 7.4 48 B11-40' <0.005 0.009 <0.005 0.033 < 10 B11-45' <0.005 0.008 <0.005 <0.015 < 10 B11-55' <0.005 0.023 0.006 0.049 < 10 B 11-60' < 0.005 0.028 0.007 0.046 < 10 B 12-35' < 0.005 < 0.005 < 0.005 0.016 < 10 B12-40' < 0.005 <0.005 <0.005 <0.015 < 10 B13-35' <0.005 <0.005 <0.005 <0.015 < 10 B13-40' . <0.005 0.008 <0.005 <0.015 <10 Site Assessment Report ARCO Products Company September 14, 1992 3 [][][] GROUNDWATER [][][] TECHNOLOGY 5.0 RISK ANALYSIS The state Leaking Underground Fuel Tank Field Manual (LUFT, 1989) establishes three methods to determine if soil contamination can be left in place without threatening groundwater. These methods vary greatly in their specificity and complexity. The most generic and least complex is a leaching potential analysis which considers four site characteristics: depth to groundwater, subsurface fractures, precipitation, and the presence of man-made conduits. Based on conditions present at the site, contamination levels exceed those determined as acceptable by the leaching potential analysis (Table 2). As stated in the LUFT Manual, the leaching potential analysis provides "a simplified way to assess the possible threat to ground Water from contaminated soils. Alternative cleanup levels, based on additional site specific analysis, would supersede the initial allowable levels" (LUFT, 1989, p 28). The second method, general risk appraisal, uses a "simulated environmental system that adapts two computer models to estimate the concentration of BTX&E that can be left in place ... without risking ground water pollution" (LUFT, 1989, p 36). These models are SESOIL (Bonazountas and Wagner, 1984) which addresses contaminant transport in the unsaturated zone, and AT123D (Yeh, 1981) which addresses contaminant transport in the saturated zone. These models have been used to create a method to determine the concentrations of BTEX which can be left in place without threatening groundwater. Work sheets and tables are presented in the LUFT Manual which can be utilized without actually modeling conditions at each specific site. However, this method was developed for sites which meet specific applicability criteria. Conditions present at the ARCO site do not meet those criteria (Table 3). At sites where the general risk appraisal is not appropriate, the LUFT manual suggests substituting "a more detailed site-specific analysis, employing the two models (SESOIL and AT123D) used in the general risk appraisal" (LUFT, 1989, p 47). The goal of the alternative risk appraisal is "to determine if ground water is at risk" (LUFT, 1989, p 48). A more detailed analysis of site conditions using the SESOIL and AT123D models is presented below. 5.1 SESOIL MODELING SESOIL is a mathematical model that simulates long-term environmental fate of pollutants in the unsaturated zone. The model describes water transport, sediment transport, pollutant fate, pollutant migration to groundwater, and soil quality within as many as four user-specified compartments representing different soil types. Site Assessment Report ARCO Products Company September 14, 1992 [~[]~[] GROUNDWATER [~[~[~ TECHNOLOGY 5.1.1 Model Input Parameters A site-specific risk analysis of the potential for BTEX to impact groundwater at the ARCO site requires the determination of several input parameters. Climatologic and chemical parameters are compiled from well-established databases (Appendix E). The rate of natural biodegradation of the compounds simulated has been conservatively estimated to be at 0.002% per day. This is the same rate used by the LUFT Task Force in the development of the general risk appraisal (LUFT, 1989, p A43) Several physical parameters require some interpretation. These parameters, and the basis of their determination, are described below. Table 2. Leaching potential analysis for gasoline using total petroleum hydrocarbons and BTEX. Modified from the LUFT Manual (1989, p 29). Score 10 Score 9 Score 5 Site Feature Score Pts. if Score Pts. if Score Pts. if Condition Condition Condition is Met is Met is Met Minimum depth to 10 > 100 51 - 100 25 - 50* groundwater from the soil sample. Fractures in subsurface (applies to foothills or 10 None Unknown Present mountain areas). Average annual precipitation 10 < 10 10 -25 26 - 40** (inches). Man-made conduits which increase vertical migration of 10 None Unknown Present leachate. Unique site features: recharge area, coarse soil, None 9 At Least More Than nearby wells, etc. One One Column Totals - Total Points 40 + 9 + 0 = 49 Range of Total Points 49 Pts. or More 41 - 48 Pts. 40 Pts. or Less Maximum Allowable BTX&E Levels (ppm) 1/50/50/50 .3/.3/1/1 N/A*** Maximum Allowable TPH Levels (ppm) 1,000 100 10 * If depth is greater than 5 feet but less than 25 feet, score 0 points. If depth is 5 feet or less, this table should not be used. ** If depth is over 40 inches, score 0 points. *** Levels of BTX&E are not applicable to TPH concentration of 10 ppm. Site Assessment Report ARCO Products Company September 14, 1992 [~[~] ~] GROUNDWATER [~][]]]][~ TECHNOLOGY 5.1.1.1 Sediment Characteristics Sediment characteristics required as input for SESOiL modeling include bulk density, effective porosity, disconnectedness, organic-carbon content, and intrinsic permeability. Bulk density and effective porosity are estimated to be 1.35 g/cm3 and 30% respectively for this simulation. These values are typical of the sediments encountered during this assessment. The disconnectedness index relates intrinsic permeability to soil moisture. Disconnectedness is defined as: c = b[In(k)]/bln(so)] where c = soil disconnectedness index, k = intrinsic permeability, and so = the long-term average soil moisture concentration. Disconnectedness in sediment typically ranges from 3 to 12, and can be varied to calibrate the model to reflect expected moisture concentrations. A disconnectedness index of 7.5 is used in the simulation. Table 3. General Risk Appraisal applicability checklist (LUFT, 1989, p 39). GENERAL RISK APPRAISAL FOR PROTECTION OF WATER QUALITY: YES NO APPLICABILITY CHECKLIST 1. Is the site in a mountainous area (shaded moist areas and/or areas X with rocky subsurface conditions)? 2. Is the site in an area which could collect surface runoff or collect or X intercept water from a source other than natural precipitation? 3. Does the areal extent of soil contamination exceed 1000 ft2? X 4. Do the concentrations of fuel constituents in any soil samples exceed the following amounts: benzene -- 100 ppm, toluene -- 80 ppm, X xylene -- 40 ppm, ethylbenzene -- 40 ppm? 5. Are their any records or evidence of man-made or natural objects which could provide a conduit for vertical migration of leachate? X 6. Do any boring or excavation logs show the presence of fractures, joints or faults that could act as a conduit for vertical migration of X leachate? 7. Do any boring logs show that contaminated soil could be within 5 . feet of highest groundwater?. X 8. Do any boring logs show the presence of a layer of material, 5 feet thick or more, which is more than 75% sand and/or gravel? X * "If any of the questions on the checklist cannot be answered no, then the results of the general risk appraisal may be less than valid." (LUFT, 1989, p 37). Site Assessment Report ARCO Products Company September 14, 1992 6 [~[][] GROUNDWATER [~][~ TECHNOLOCY Hydrocarbons adsorb to organic carbon which occurs naturally in sediments. While adsorbed, they are essentially immobile. The adsorptive process thus retards the migration rate of the hydrocarbons. The percent organic carbon present in sediment at the ARCO site has been conservatively estimated to be 0.02%. This is the same value used by the LUFT Task Force in the general risk appraisal (LUFT, 1989, p A42). Intrinsic permeability is determined by comparison of the lithologies encountered at the site with permeability data compiled in Freeze and Cherry (1979). Their data represents ranges of permeability expected for given sediments based on observed grain-size distributions. The value representing the more-permeable upper-75th percentile of their data is used. 5.1.1.2 Contaminant Application A partial list of the application parameters required for the SESOIL simulation includes the number of soil layers present in the system and their respective thicknesses, the area impacted by the contaminant, and the total mass of contaminant in each layer. Four soil layers are simulated for this site (Figure 10). These layers are segregated based on general sediment characteristics. The bottommost layer is assumed to be a well-sorted, permeable sand. Concentrations used in estimating total hydrocarbons in place are determined using the 95% upper confidence level (95% UCL) as described by Witte (1989) at each 5-foot depth horizon where more than one data point is available. The level is derived using the following equation: 95%UCL=x+ (1.96*s/n°'5) where x = mean, $ = standard deviation, and n = the number of samples analyzed (Appendix F). Total hydrocarbons in place are calculated by multiplying the 95% UCL times the mass of soil in each 5-foot subcompartment of soil. At horizons with only one data point, that value is assumed to represent hydrocarbon concentrations at that depth. Note that the concentration used for each layer is the most conservative value reported or calculated. For example, in cases where samples at depth yield higher concentration than data from shallower subcompartments, the higher concentration is substituted (Appendix F). For this simulation, the application area for contaminants is approximated as shown on Figure 11. Pollutant load ~g/cm2) is calculated by dividing the total mass of hydrocarbons per soil compartment by the application area (Appendix F). Site Assessment Report ARCO Products Company September 14, 1992 [~][~--~ GROUNDWATER [~[~[~] TECHNOLOGY 5.1.1.3 Conservatism Input parameters are chosen to represent conservative site conditions. The simulation is calibrated such that all rainfall infiltrates the soil column and evapotranspiration is minimized. Alternately, the simulation is calibrated such that no pollutant is lost to the atmosphere through volatilization. In effect, the site is considered uncapped with respect to precipitation, but completely sealed with respect to pollutant loss to the atmosphere. Using the 95% UCL helps ensure that contaminant concentrations are estimated at their highest level. Additionally, this concentration is used to characterize the entire lateral extent of each compartment simulated, disregarding lateral decreases in pollutant concentrations. 5.1.2 SESOIL Output SESOIL generates data for each month of each year simulated. Condensed SESOIL output files are presented in Appendix G. Output includes information about the hydrologic cycle (e.g. precipitation, evapotranspiration, etc.) and the distribution o~ pollutant in the soil column (e.g. concentration and depth). The period simulated for this analysis is the maximum SESOIL allows -- 99 years. Concentrations of each compound are calculated in several phases (pure, soil moisture, adsorbed, and soil air). A summary of the resultant concentrations is presented in Appendix G, Tables G1 - G4. Note that SESOIL will calculate concentrations which are several orders of magnitude below those which can be detected by laboratory methods. The maximum depth reached by detectable concentrations of each pollutant at intervals throughout the 99-year period is listed in Table 4. Note that none of the pollutants reach the water table at detectable concentrations throughout the simulation. However, the simulation does indicate that benzene, toluene, and xylene isomers are discharged to groundwater in very Iow masses during part of the simulation (Table 5). In order to determine the resulting concentrations of these constituents in groundwater, the SESOIL output data was incorporated into an AT123D input file. 5.2 AT123D MODELING AT123D is an analytical computer model which simulates the transport of chemicals in an aquifer (Yeh, 1981). The model can simulate advective and dispersive transport mechanisms and account for adsorption, biodegradation, and volatilization processes in a three dimensional setting. Point, line, or area sources of instantaneous, continuous, or finite duration releases can be simulated. Site Assessment Report ARCO Products Company September 14, 1992 [~[~L~ GROUNDWATER [~[~[] TECHNOLOGY Table 4. Maximum pollutant depth of detectable concentrations of BTEX for SESOIL simulation Year Maximum Pollutant depth in Soil (Feet) Simulated Benzene I Toluene Ethylbenzene I Xylenes 1 82 81 80 81 10 104 98 84 91 20 128 116 88 103 30 ND 132 93 114 40 N D N D 97 126 50 ND ND 101 136 60 N D N D 106 147 70 ND ND 110 ND 8O ND ND 114 ND 90 ND ND 119 ND 99 ND ND 123 ND Table 5. Pollutant mass in groundwater runoff. All values in/~g. Totals calculated assuming constant discharge for each 10 year interval. Year Simulated Pollutant Mass Discharged to Groundwater Benzene Toluene I Ethylbenzene I Xylenes 1 through 30 0 0 0 0 40 5.1 0 0 0 50 0.22 15 0 0 60 0.18 5.1 0 0 70 0.15 0.23 0 0 80 0.13 0.19 0 1300 90 0.11 0.16 0 150 99 0.090 0.13 0 22 Total 59 I 210 0 130,000 Site Assessment Report ARCO Products Company September 14, 1992 9 5.2.1 Model Input Parameters The AT123D simulation completed for this site assumes an infinitely deep and wide aquifer with a porosity of 30%, a hydraulic conductivity of 1.67 cm/s, and a gradient of 0.01. Other input values include: · longitudinal dispersivity = 30 m; · lateral and vertical dispersivities = 10 m; · adsorption coefficient (K~) = 0; and · decay constant = 0. An area source matching the soil column simulated for the SESOIL analysis is used and pollutant input is derived from the SESOIL output. 5.2.2 AT123D Output Both AT123D and SESOIL will calculate pollutant concentrations at levels several orders of magnitude below typical laboratory method detection levels. As stated above, the SESOIL simulation indicates benzene, toluene, and xylene isomers will reach groundwater during the 99 year period modeled. However, the resulting maximum groundwater concentration calculated for any of these species is less than three parts per trillion, well below either drinking water standards or laboratory detection levels (Table 6). Condensed AT123D output files are presented in Appendix H. 6.0 FEASIBILITY STUDY Three remedial action options are considered for this site. They include no action, soil venting, and excavation. Details of these options are discussed below. 6.1 NO ACTION The no action alternative would involve maintaining the asphalt and concrete cap overlying the areas impacted with hydrocarbons. No further action would be undertaken to mitigate soil contamination, An asphalt cap will minimize human contact with the hydrocarbons and prevent infiltration of rainwater. The SESOIL simulation indicates that under conservative conditions, BTEX will not impact groundwater. The installation of double-walled tanks and piping also helps ensure that no additional hydrocarbons will be introduced into the soil system. With no further addition of hydrocarbons to the plume, natural degradation and dispersion will eventually eliminate soil impaction. No further costs would be incurred with this option, and there will not be any associated worker health and safety risks. Site Assessment Report ARCO Products Company September 14, 1992 10 Table 6. Maximum pollutant concentrations in groundwater in/zg/~ as calculated in the AT123D simulation. Year Maximum pollutant Concentration Calulated Simulated Benzene I To,aerie I Ethy,benzene I Xy,enes 1 through 30 0 0 0 0 35 2.95e-5 0 0 0 40 3.00e-6 0 0 0 45 3.20e-7 0 0 0 50 1.50e-7 9.00e-5 0 0 55 1.39e-7 1.68e-5 0 0 60 1.26e-7 3.10e-6 0 0 65 1.12e-7 5.81e-7 0 0 70 1.03e-7 1.53e-7 0 0 75 9.56eo8 1.40e-7 0 2.27e-3 80 9.03e-8 1.33e-7 0 7.96e-4 85 8.32e-8 1.22e-7 0 2.27e-4 90 7.36e-8 1.09e-7 0 9.56e-5 95 6.49e-8 9.97e-8 0 3.28e-5 6.2 SOIL VENTING Soil venting would entail the installation of vapor extraction wells and equipment and removing volatile organic compounds (VOC's) from soil in an induced vapor-stream. The contaminated vapor stream would be treated with abatement equipment to remove VOC's prior to venting to the atmosphere under an APCD permit. Necessary equipment would include a vapor extraction point(s), an explosion-proof regenerative blower, vapor-abatement equipment (cat-ox, therm-ox, or lC engine) and associated plumbing. The estimated time to complete this option would be one year, with costs ranging from $60,000 to $100,000. Health and safety risks associated with this option are the dangers inherent in heavy equipment operation and the possible creation of explosive atmospheres. 6.3 EXCAVATION Excavation would entail destruction of large portions of the asphalt and concrete slabs and the dispenser island which overlies the plume and physically removing impacted soil. The excavated soil Site Assessment Report ARCO Products Company September 14, 1992 11 C.OVNDWATE. TECHNOLOGY would be disposed of in a Class I landfill. The total volume of impacted soil, as indicated by data from this assessment, is estimated to be 1,200 yds3. The estimated time to complete this option would be four weeks, with costs ranging from $150,000 to $200,000. Possible health and safety risks associated with this option include worker and public exposure to impacted soil, the volatilization of hydrocarbons during excavation activities, and the dangers inherent in heavy equipment operation. Surface structures at the site will also be damaged by excavation. 7.0 REMEDIAL ACTION PLAN The preferred remedial action plan at this site is no action. The buffer zone between impacted soil and groundwater is approximately 80 feet, and the SESOIL simulation indicates that BTEX will not reach groundwater during the 99-year simulation period. New double-walled storage tanks have been installed at the facility, thus eliminating the source of contamination in the area of the former tanks. Soil venting is a proven technology which will remediate the plume in a shorter time frame than natural degradation. However, implementation costs are high. The excavation alternative is not considered feasible due to high costs, worker safety concerns, and damage to surface structures. Site Assessment Report ARCO Products Company September 14, 1992 12 [~][~-~ GROUNDWATER [~[]~][~ TECHNOLOGY 8.0 REFERENCES Bonazountas, M., and J. Wagner, 1984, SESOIL: a seasonal soil compartment model: A.D. Little Inc., for U.S. EPA contract #68-01-6271, Cambridge, MA. California Division of Mines and Geology, 1975, Geologic Map of California, Bakersfield sheet. Freeze, R.A., and J.A. Cherry, 1979, Groundwater: Prentice-Hall, Inc., Englewood Cliffs, NJ. GSC (General Sciences Corporation), 1990, Riskpro -- environmental pollution modeling system: Laurel, MD. GTI (Groundwater Technology, Inc.), 1991a, Predrill assessment report, ARCO service station # 6218. ---, 1991b, Tank removal report, ARCO service station # 6218. ---, 1991c, Site characterization report, ARCO service station No. 6218. Howard, P.H., 1990, Handbook of environmental fate and exposure data for organic chemicals, v. 1 & 2: Lewis Publishers, Chelsea, MI. KCWA (Kern County Water Agency), 1990, 1989 Report on water conditions - improvement district no. 4. LUFT (Leaking Underground Fuel Tank), 1989, Leaking underground fuel tank field manual: guidelines for site assessment, cleanup, and underground storage tank closure: State of California Leaking Underground Fuel Tank Task Force. NOAA (National Oceanic and Atmospheric Administration), 1989, Local climatological data, annual summary with comparative data for Bakersfield, California: ISSN #0198-696, Ashville, NC. Witte, R., 1989, Statistics, third edition: Holt, Reinhart and Winston, Inc., the Dryden Press, NY. Yeh, G.T., 1981, AT123D: analytical transient one-, two-, and three-dimensional simulation of waste transport in the aquifer system: Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN. Site Assessment Report ARCO Products Company September 14, 1992 13 GROUNDWATER TECHNOLOGY FIGURES [~f~ 'r~c.~o~oc¥ LANE w.-~X~ :~.... 3 · :~ II wi Ave. ~ gJ~hJrr~ ~uft T ~n~rra ;, ~ I ~ I - I . /I. 4 X ;'~;~,:~:;~: J'~J~ - ,. .. e.~c X 1, {~ SXTE, ARCO SS ~6218 350 0607 SITE LBC, 4203 Ming Avenue Bakersfield, California HAP TYPE, ,,Location Index SCALE: gRA~N 9Y, ])ATE, APPRBVE9 BY, J 9ATE, MH 2/91 JDPj 2/91 ~ REV REV]SigN gATE BY 1/~ 0 1/4 1/~ mi[es Source: Hoven ~ Co. Inc. I FIGURE 1 I ~~D~Du'T""~I T~CHNDL~Y MING A VENUE BIO Planf~r ~,__ Sidewalk__ /_ -- Poll Box~ B15 Former Tank . Location Buildin LEGEND N Boring Location Boring Location Showing Bottom- hole Deviation SCALE, 40' 0 PO' 40' u JOS . 022 SITE: ARCO SS #6218 50 0658 SITE LOC, Bokorsfield, Colifornio MAP TYPE~ Boring Locofions SAB 8/92 I JDP 8/92 REV REVISIDN DATE BY MING A VENUE Planfer <10 <10 < 1 °-Tb-~ P L$ < 10 '"-.,PL1 < 10 /-. ~'ormer Tank <lO~-~r ~.. LocD~iRn 4600'-.. <10 <10 Planter <10 <1o'--. PLZ Sidewalk Planter 28O DI1 DI2 4800 1900 4,30 2900 :)500 LEGEND N TPH@2' x' TPH@6' Sample Location SCALE: 40' 0 20' 40' .022 SITE, ARCO SS #6218 ~ 0658 SITE LDO Bokersfield, Colifornio HAP TYPE: Somple Resulfs DRA~N DY, DATE, APPROVED ]~Y, DATE, SAB 8/92 JDP 8/92 REV J REVISION DATE DY Legend Sife JOB ~ 215 sz~E, ARCO SS ~6218 ~50 0607 SiTE LDO Bakersfield, California SCALE: M~P TYPE, Sire Geology ~ DRAWN DY:IDATE, APPROVED BY, I DATE: Source: CDMG Bakersfield Sheet i FIGURE 4 I Legend Site Depth to groundwoter oo~. 21 5 sz~'ARCO SS ~6218 ~so o~o7 S~TE ~CALE~ Bokersfield~ ~ ~ ~ Depth ~o Groundwo~er Feet ~H 2/91 I JDP}2/9~ Source: K.C.W.A. Report, 1990 IFIGURE 5 Legend - Sife Groundwoter Elevotion 4000 SouFce: SCALE: 0 2000 4000 ~ee~ K.C.W.A. Report, 1990 JE]]~ # 215 SZTE'ARCO SS #6218 350 0607 SITE LOC: Bokersfield, Colifornio HAP TYPE, Groundwofer Grodienf DRAVN MH IFIGURE I DATE, IAPPRDVED BY, I DATE, 2/911 I JDP ,2/91 ~ TECHNOLOGY B13 311 TPHG- 1 000 limits) MING A VENUE Sidewalk _~/// Planter B3 B5· Former Tone . Location 7 TPHG=IO00 . opproximofe limits) ~-B4 LEGEND N Boring Locofion Boring Locofion Showing Bottom- hole Deviof[on SCALE~ 40' 0 20' 40' ~ 022 S~TE, ARCO SS #6218 ~ 0658 SITE LDC~ Bekersfield, Colifornio HAP TYPE, Cross-Section Index end TPHG Contours DRA~/N BY, DATE: IAPPRrlVED BY, DATE, SAB 8/92'1 JDP 8/92 REV REVISIFIN DATE: BY 10' 15' 20' 25' 50' 55' 40' 45' 50' 55' 60' 65' 70' 75' 80' D~enser Islands A' A BLOB9 "'x B 5 \ / x 0.85 ~ x <0.005 ~ kC/ 1600 "500C~ <10 -- - 1 8 4 <0 005 sandL ~x x46'00 ~/ x <'10 \ o._q_~_5 z ~_ ~ -- - -% x~_. TPHO=IO00 .__ _ ~ (approximate limits) clayey silt -~ clayey silt ~, , ~-' , ' __ <<01.0005-7 sand -~~ ~ - -~ ~k,sand _ gravelly sand -~ % 0.027 - · ~_ gravelly sana ~ silty sand _~ sand ~ 0.02_2 sand ~<10 _ ~ 0.11 <10 10' 15' 20' 25' 30' 35' 40' 45' 50' 55' 60' 65' 70' 75' 80' Legend Scale 10' 0 Strafigraphic Contact 10' 5' <0.005 benzene <10 - TPH6 JBB # 022 SZTC, ARCO SS #6218 5O O658 SITE LDC~ Bakersfield, California DESCRIPTIBN~ Cross-Section A ]DRAWN DY: DATE, SAB 8/92 IK'[GURE 8I APPRDVED BY, dDP 10'-- 15'-- 20'-- 25'-- ,30'-- 35 B$ B5 Di~.y~n se r.n¢ Islands % B6 ,an~~0~ ) ' ' /~ \' / ¢~~si~fy sand ~ ~~silfy sand [~ ) / /<o.oo <o.oo5 X , ~ - ~ sand ~ ~0.005 sand ~silfy sand ~ % <0.005 <10 <10 - 5' -10' -15' -20' -25' -.50' 35 Legend Scale 10 ~~S~rafigraphic Confacf 0 5 10 <0.005 benzene <10 - TPHG JOB # 022 SITE, ARCO SS #6218 5o o658 SITE LBO Bakersfield, California DESCRIPTION~ Cross-Section B DRAWN BY~ DATE~ I APPROVED BY: SAB 10/91I JDP I FIGURE 9 ~6.0UNDVATER TECHNOLOGY 10' 15' 20' 25' 50' 55' 40' 45' 50' 55' 60' 65' 70' 75' 80' Dispenser Islands A' A BIO B9~ '" 1 I '% I B15 __ Soil Loyer 1 .... __ _ Soil La~/t~_r 2 __ _ fTo 120 Feel ~/ - 10' - 15' - 20' - 25' - 50' - .55' - 40' - 45' - 50' 55' 60' 65' 70' 75' 80' Soil Layer 4 Exfends From 120' fo 160" Legend Scale 10' 0 5' 10' JaB # 022 SITE, ARCO SS #6218 50 O658 SITE LBO Bakersfield, California DESCRIPTIDN~ Soil Comportments DRAV/N BY: DATE~ APPROVED BY: SAB 8/92 JDP MING A VENUE B13 Former Tank ;.~Locafion 911 Pollufonf Application Area ~_B4 Planter LEGEND Boring Locofion Boring Locofion Showing Boffom- hole Devio'rio n SCALE, 40' 0 20' 40' JOS ~ 022 SITE: ARCO SS #6218 50 0858 SITE LOC, Bakersfield, California NAP TYPE: Applicofion Area DRAWN ~Y, DATE, APPRDVED ]~Y, DATE, SAB 8/92 JDP 8/92 REV REVISION DATE BY APPENDIX A Background Data [GROUNDWATER TECHNOLOGY Table Al. Analytical results (in mg/kg) of soil sam )les collected beneath tanks, 5/15/91. Sample # Benzene Toluene Ethyl- Total TPH as benzene Xylenes Gasoline T1W-2' 0.85. 13 5.7 100 1600 T1W-6' 1.8 9.8 8.3 310 4600 T1E-2' <0.005 <0.005 <0.005 0,018 < 10 T1E-6' <0.005 <0.005 <0,005 <0.015 < 10 T2W-2' 24 230 71 460 3000 T2W-6' 4 87 33 300 2000 T2E-2' < 0.005 < 0,005 < 0.005 0.029 < 10 T2E-6' < 0.005 0.055 0.062 5.7 55 T3W-2' < 0,005 < 0.005 < 0.005 < 0.015 < 10 T3W-6' < 0.005 < 0.005 < 0.005 0.16 < 10 T3E-2' < 0.005 0.021 0,006 0.062 < 10 T3E-6' <0,005 <0,005 <0.005 <0.015 < 10 [~[~ ~] GROUNDWATER [~[~[~ TECHNOLOGY Table A2. Analytical results (in mg/kg) of soil samples collected beneath dispenser islands and ')ing, 5/15/91. Sample Cf Benzene Toluene Ethyl- Total TPH as benzene Xylenes Gasoline DI1-2' 0.11 5.1 3.3 37 280 DI 1-6' 0.009 0.14 0.084 1.7 24 DI2-2' <0.1 5.7 4.9 130 1900 DI2-6' <0.005 0.42 0.61 17 430 DI3-2' 0.30 25 26 630 4800 DI3-6' <0.005 0.15 0.34 11 170 DI4-2' <0.i 6.8 7.3 610 2900 DI4-6' < 0.10 7.3 6.2 230 2500 PL1-2' <0.005 <0.005 <0.005 <0.015 < 10 PL1-6' < 0.005 < 0.005 < 0.005 < 0.015 < 10 PL2-2' <0.005 <0.005 <0.005 <0.015 < 10 PL2-6' <0.005 <0.005 <0.005 <0.015 < 10 P L3-2' < 0.005 < 0.005 < 0.005 < 0.015 < 10 P L3-6' < 0.005 0.005 < 0.005 < 0.015 < 10 [~][~]~] GROUNDWATER [~[~][~ TECHNOLOGY Table A3. Analytical results (in mg/kg) of soil sam )les from borings, 9/11/91-9/12/91. Sample No. Benzene Toluene Ethyl- Xylenes TPHG benzene B5-35 < 0.005 < 0.005 < 0.005 < 0.015 < 10 B6-15 <0.005 <0.005 <0.005 <0.015 < 10 B6-30 < 0.005 < 0.005 < 0.005 < 0.015 < 10 B7-25 < 0.005 < 0.005 < 0.005 < 0.015 < 10 B8-20 < 0.005 < 0;005 < 0.005 < 0.015 < 10 B9-25 0.53 4.1 8.6 150 2700 B9-40 3.2 · 12 1.4 8.2 40 B9-65 0.027 0.10 0.017 0.14 < 10 B10-45 0.089 0.56 0.11 ' 0.77 < 10 B10-75 0.022 0.10 0.014 0.11 <10 B10-80 0.11 0.19 0.021 0.17 <10 [][][] GROUNDWATER ~][~[~ TECI~NObOCV APPENDIX B Lithologic Logs [~][]~][] GROUNDWATER [~[~[~] TECHNOLOGY Drilling Log GROUNDWATER Soil Boring BI! TECHNOLOGY Prolect ARCO SS No. 8218 Owner ARCO Products Company See Site Map For Boring Location Location 4203 Ming Avenue Proiect No. 022502551 Date drilled 8/25/92 Surface Elev. Total Hole Depth 60 ft. Diameter 0.5 ft. COMMENTS: Top of Casing Water Level Initial ~ Static Screen: Dia Length Type/Size Casing: Dia Length Type Filter Pack Haterlal Rig/Core Type CME-55 Drilling Company Bksfld. k/ell ~, Pump Method 8" Hollow Stem Auger Permit # Driller S. Pacheco Log By F. Perrell Checked By J- Parker License No. RG 4728 [~ oe a, 8~) ~c~ ~ Description E ~ · ~ (Color, Texture, Structure) u~ ~ Trace < IO%, Little IO% to 20%, Some 20% to 35%, And 35% to 50% --2- - 0 .-'::.-'::!: A.S.3" Asphaltic concrete, 3" aggregate base. - 2 - - 4 - 500 B-11 / Sand, silty, fine to medium grained, moderately well graded, - 6 - ,,24,24L subrounded to rounded, dense, light olive gray (Syr 5/2), damp, trace fine gravel, moderate petroleum odor. - JO - 35 S-ll ~ .:'/:::'.:. SW Sand, fine to medium grained, well graded, loose, dark 3/.3/3L~ ....., yellowish brown (10yr 4/2), moist, slight petroleum odor. -12- :::iii."_ - 14 - :::::::: :.:.:.:. 1.5 B-il ,':':':': Sand, medium to coarse grained, poorly graded, medium - 16 -- 3/5/7 ::.':'::': ' dense, moderate yellowish brown (10yr 5/4), moist ::::::':: no petroleum odor. -18 - ,........ ,:.:.:.:. SP ::::::::: 3/~/eJ] :!:!:!.'! pale yellowish brown (lOyr 6/4), slightly damp, slight ::::::::, petroleum odor. - 22 - :::::::: -24- 08/21/1992 lithlog-mar92 Page: I of 3 I~ROUNDNATER TECHNOLOGY Drilling Log Soil Boring Bll Project ARCO SS No. 6218 Owner ARCO Products Co~pany Location 4203 Ming Avenue Project No. 02250255! Date drilled 6/2E/92 t-~ R ~ o ~ eE ~,) o) (Color, Texture. Structure) o U~ ~ Trace < 10~. Little 10% to 20%, Some 20~ to 35~. And 35~ to 50% - 24 - ........= 125 B-S! I ~::~¥ Sand. fine grained, poorly graded, pale yellowish brown (lOyr 6/21, 26 - 0/7/9 .:.:.:.: dry, moderate petroleum odor. ::::::~:, - 2s - - 32 - ,:.:.:.:. -34- 3000 .B-11 [ ~ SH Sand, silty, dark yellowish brown (10yr 4/2), damp, interbedded - 36 - s/9/1o ~ with silt, Fe oxide staining, trace clay, strong petroleum odor. - 38 - ::::::::: - 40- 120 B-11 ~:'?'" Sand, gravelly, fine to medium grained, poorly graded, pale yellowish ~/~/~8 brown (10yr 6/2), very dense, damp, slight petroleum odor. - 42 - .:.:.:.:. 44 , .-.-.-. - 4 6 - ~/~/~ ..... very dense, damp, no petroleum odor. 48 ...'. 5/~/~2 :i (10yr 5/4) very dense, dry, trace fine gravel, no petroleum odor. - 52 - -54- ~ s. 85 B-l! I Sand, silty, gravelly, very fine to coarse grained, well graded, dark - 50 - ~/48/2~ yellowish orange (10 yr 6/61, very dense, dry, no petroleum odor. o7/14/1992 Ilthlog'-mar92 Page: 2 of 3 '-]~-~ I~ROUNDWATER TECHNOLOGY Drilling Log Project ARCO SS No. 6218 Owner ARCO Products Company Location 4203 Min~7 Avenue Project No. 02250255t Date drilled 6/25/92 Soil Boring 07/14/t992 Ilthlog-~ar92 Page: 3 of 3 ~,=c,, _o ~o Description -- E=~ ~ m (Color. Texture. Structure) m~ ~ Trace < 10~, Little 10~ to 20~. Some 20~ to 35~, And 35~ to 5~ -56- ~ s~ -~8 .'..'. - 60 - e3 B-11 ~ '....". (10 yr 6/64 dense, moist, no petroleum odor. 2/24/~8 L -62 - -64 - -66- -68- -70- -72- -74- -76- -78- -80- -82- -84- -86- -88- GROUNONATER Soil Boring TECHNOLOGY Project ARCO SS No. 8218 Owner ARCO Products Co/~pany See Site Nap For Boring Location Location 4203 Mina Avenue Project No. 022502551 Date drilled 6/26/92 Surface Elev. Total Hole Depth 40 ft. Diameter 0.5 ft. CONNENTS: Top of Casing Water Level Initial Static Screen: Dim Length Type/Size Casing: Dim Length Type F~ter Pack Haterial Rig/Core Type C~-55 DrYing Company Bksfld. ~1 & Pu~p Hethod 6" H~lo~ Ste~ Auger Permit Driller S. P~heco Log By F. Checked By J. Parker License No. RG 47~8 ~ - ~ ~ ~ Description ~ Ez~ e~ m (Color, Texture, Structure) m~ ~ Trace < 10~, Little 10~ fo 20~, Some 20% to 35~, And 35% fo 50% ?::.:?.: ~ 3" Asphaltic concrete, 3" aggregate base. - 2 - :..:.::. :.'....: - 4 - :.'....:~ :]']'][:~"- s~J Sand, fine to medium grained, silty, well graded, subrounded to rounded, dense, light olive gray (Syr 5/2), damp, - 6 -- . :~'~.~:, trace fine gravel, moderate petroleum odor. 10_ '.'. 2 a12-1s'[ Sand, fine to medium grained, poorly graded, pale to moderate ~8 4n/e L yellowish brown (10 yr 6/2 - 10 yr 5/4), me,urn dense, damp, - - ...-..... trace fine gravel, no petroleum odor. -20- 2.4 a,2-20r ~ Sand, fine grained, poorly graded, moderate yellouish broun 3~¢- ~:~:j:~:L (10 yr 5/4) uith mottled iron oxide stain, medium de~e, damp, ..:.:.:.:. interbedded uith silt, trace clay, no petroleum odor. -24 - ..-....., 07/14/1992 ,thlog--mar92 Page: ! of 2 I' II I~! e~OUNDWA ~11 II TECHNOLOGY Drilling L°g Soil Boring B12 Project ARCO SS No. 6218 Owner ARCO Products Cor~pany Location 4203 Ning Avenue Project No. 02250255~ Date drilled 6/26/92 =.~. ~ = - e Description "~- ~ ~ ·~ ~ (Color, Texture, Structure) m~ ~ Trace < 10~, Little 10~ to 20~, Some 20~ to 35~, And 35~ to -24 - e/em L brown (10yr 6/21, medium dense, dry, no petroleum odor. -26 - :':E:~: - 28 - ,..:.:.:. -30- !.5 B12_30r ~ SP Sand, fine medium grained, poorly graded, pale yellowish brown ~2/~' :::::::::L (10yr 6/2), medium dense, dry,. no petroleum odor. - a2- - 34 - :.:.:.:.: 5.5 B12-35 Silt, clayey, very fine grained, poorly graded, orange to 36 ,2/./. L NL yellowish orange with iron oxide stain, me,urn stiff to stiff, - - ~;~;~:~:~ damp, no petroleum odor. - 38- ':':'>:' SP Sand, fine to medium grained, poorly graded, pale yellowish brown ::::::::: (lOyr 6/2), very dense, damp, no petroleum odor. - 40- 3.2 BI2-4~ ~3~o~1L -42- -44- -46- -48- -50- -52- -54- -5~- 07/t4~1992 Ilthlog--mar92 Page: 2 of 2 Drilling Log ~'' I- II I1~_1 I~ROUNDNATER Soil Boring B13 ' ~---~-'-~ TECHNOLOGY Project ARCO SS No. 6Zt8 Owner ARCO Products Company See Site Map ' For Boring Location Location ,'4203 Ninl~ Avenue Project No. 0~.250255t Date drilled Surface Bev. Total Hole Depth 40 ff. Diameter 0.,.5' ff. CONNENTS: Top of Casing Water Level [nitial Static Screen: Die Length Type/Size Casing: Dim Length Type F~ter Pack Haterial Rig/Core Type C~E-55. Drilling Company Bksfld. Eel~ $ Pump Hethod 8" Ho//o~/ Stem Auger Permit ~ D[iller S. Pecheco Log By F. Perrell Checked By J. Part(er License No. R(~ 4?'~8 ~_ ~,§~ _o ~ Description ~ ~.~.~ ~.o~s~ .e.~ o~ (Color, Texture, Structure) ~00U.. ~ u3~ ~ Tr~ce < 10%, Little 10% to 20%. Some 20% to 35%, And 35% to 50% '?:[-'!i:' ~ 3" Asphaltic concrete, 3" aggregate base. ..:'..:.:. ..'::::::. · .'. Sand, fine to medium grained, silty gravel, ~tell graded, 8 :..~.~. S~ subrounded to rounded, dense, light olive gray (5yr 5/24 - - ..'. moderate petroleum odor. - 12- ,:.:.:.:. 5 a13_ls.r iiiiiiii Sand, fine to medium grained, poorly graded, dark yellowish orange -~/e/e L (10 yr 6/64 medium dense, dry, no petroleum odor. s/~/~ L' i:i:i:i: (10 yr 6/64 medium dense, dry, no petroleum odor. -24 - °°' °' 07/14/9992 llthlog-mar92 Page: I of 2 '11 I IIGRoUNDNATER III II II TEcHNOLOGY Drilling Log S°il Boring B13 Project ARCO SS No. 6218 ONner ARCO Products' Company Location 4203 tying Avenue Project No. 022502551 Date drilled 8/27/92 [~ oe ~ Description ~ ~ ~ ~ ~ m (Color, Texture, Structure) o~ ~ u ~ ~ Trace < IO~,Little IO~ to 20~, Some 20~ to 35~. And $5~ to 50~ -24- 4.7 B,3-25[iiiiii!i Sand, finetomediumgrained, poorlygraded, darkyello~ishorange ,o/,/,2 L (10yr 6/61, medium dense, dry, no petroleum odor. -26- ........ - 28 - :.:.:.:. - 30 -- 4.6 B13-3 Sand, fine medium grained, very poorly graded, pale yellowish ,o,,s/,eL brown (10yr 6/2),medium dense, dry, no petroleum odor. ~.:.:.:.: - 34 - ::::::::: 3.8 B13-35 Clay, silty, dark yellowish orange (10yr 6/6), ~/32/36 L .L medium stiff, damp, no petroleum odor. -36- Sand, fine grained, poorly graded, damp, no petroleum odor. :::::::::: sP oJ7 ':':':':': - 40 - 3.2 B13-4 Sand, fine to medium grained, poorly graded, moderate yellowish ~/3e/33L brown (I0 yr 8/4), very dense, damp, no petroleum odor. -42- -44- -46- -48- -50- -52- -54- 08/21/1992 lithlog-mar92 Page: 2 of 2 APPENDIX C Disposal Documentation GROUNDWATER TECHNOLOGY ~'" ' ' ' ' NO 0152 NON-HAZARDOUS WASTE DATA FORM Arco PrOdu.~.Cs Company_ ' ~o,i~ (213' ~04-5391 ~,ST~e,~erritos, CA 90701 .~ .. ~ . - ~AINER~: ~ ....... ~u~m,~ ~.T~ --- - TPIi <1 GOMPONENT~ OF: V~,~'I~ PPM PnOPF. RTIUO: f:~ ?,, [] 8OUO [] UOUIO ~ SLUDGE ~ ~LURRY ~ O~HER ,~^,,,uu~c~.~'RU¢,O,e Wear appropriate p~otective ciothing, { TH~ O~E~TOR CERTIFIES ~AT ~a W~TE, As ueeoam~u ts ~ ] Lar~y Moo CO ~ ..o.E NO. (3J.O) 537-.7...100 ~Auu , I)eMenno Kerdoon 2000 North Alameda CnV. mTATm, Z~pCOmpton, CA 90222 } $ ORDER NO.__] · ,,/ - pK::K Up OATE(~,) ,~/,~.~_{/,C~I ,~,,,,. _ _ A B NONE ON.HAZ BDQ S WASTE DATA FORM OTHER, PPM : ~ 99-100. · ~fear..appropriate protcctive c/.o+,hlng. - ~HU ~E~E~TOR C;RTIFIE~ T~T THE '": W~E~ON~US. ~ D~eO~O. ~$ ~. Larry Hoothart as Ag :~ of AECO 8ERVIOE ORDER NO. T'(.PED OR PRINTED FULl,, N~d~l & SlO, NATURf DA11 . ; L'&idla, Envlronu~n~al 8ervt6'~s · 2500 West bokern Road_ _ . : ~ ua~c [] OT, E,L . - L · NONE ~ Cardina/® APPENDIX D Laboratory Reports [~[~"~ GROUNDWATER [~[~[~ TECHNOLOGY TEL ENVIRONMENTAL LABORATORIES, INC. Southwest Region 200001300 Mariner Drive Torrance, CA 90503 (213) 371-1044 (800) 727-GTEL Fax (213} 371-8720 GTEL Client Number:. GTI78.ARC01 Representative: Kateri Luka Facility Number:. 6218 Work Order Number:. T206517 July 14, 1992 Mr. Jon Parker Groundwater Technology, Inc. 4101 Alken Street, Suite B-1 Bakersfie. ld, CA 93308 Dear Mr. Parker, Enclosed please find the analytical results for the samples received by GTEL Environmental Laboratories, Inc. on 6-27-92 under task order number 6218-92-2. A formal Quality Assurance/Quality Control (QA/QC) pr~)gram is maintained by GTEL, which is designed to meet or exceed the EPA requirements. Analytical work for this project met QA/QC criteria unless otherwise stated in the footnotes. GTEL is certified by the state of California under Certification #E723. If you have any questions concerning this analysis or if we can be of further assistance, please call our Customer Service Representative. Sincerely, GTEL Environmental Laboratories, Inc. Minsoon Song Laboratory Director GTEL Torrance, CA T206517.DOC P~ge 1 GTEL Client Number:. GTI78.ARC01 Representative: Kateri Luka Facility Number:. 6218 Work Order Number:. T206517 ANALYTICAL RESULTS Volatile Organics in Soil _ EPA Methods Modified 8020 and Modified 8015~ GTEL Sample Number I.~b Blank 06517-1 06517-2 06517-3 Client Identification - B11-30 B11-35 B11-40 Date Sampled - 6-25-92 6-25-92 6-25-92 Date Extracted - 6-30-92 6-30-92 6-30-92 Date Analyzed 7-2-92 7-2-92 7-7-92 7-2-92 Reporting Analyte Limit, mg/kg Concentration, rog/kg Benzene 0.005 <0.005 <0.005 1.0 <0.005 Toluene 0.005 < 0.005 < 0.005 7.1 0.009 Ethyl benzene 0.005 < 0.005 0.008 1.3 < 0.005 Xylene, total 0.015 <0.015 0.087 7.4 0.033 BTEX, total -- - 0.095 17 0.042 Gasoline 10 < 10 < 10 48 < 10 Dilution Multiplierb 1 I 1 1 Percent solids, % - 92.8 95.5 93.4 TFT surrogatec, % recovery 87.4 72.8 99.1 103 Test Methods for Evaluating Solid Waste, SW-846, Third Edition, Revision 0, US EPA November 1986. Modification for TPH as gesoline as per California State Water Resources Board LUFT Manuel procedures. Results are calculated on a wet weight basis. b. Indicates the adjustments mede for sample dilution. o. TFT surrogate recovery acceptability limits of 72.8-123% are derived from the 99% confidence interval of ,ill samples during the previous quarter. Expected surrogate value is 1.07 rog/kg. GTEL Torrance, CA Page 2 T206517.DOC GTEL ENVIRONMENTAL LASORATORIESo IN~. GTEL Client Number:. GTI78.ARC01 Re~resentative: Kateri Luka Facility Number: 6218 Work Order Number: T206517 'ANALYTICAL RESULTS Volatile Organics in Soil EPA Methods Modified 8020 and Modified 8015a GTEL Sample Number 06517-4 06517-5 06517-6 06517-7 Client Identification B11-45 B11-55 B11-60 B12-35 Date Sampled 6-25-92 6-25-92 ' 6-25-92 6-26-92 Date Extracted 6-30-92 6-30-92 6-30-92 6-30-92 Date Analyzed! 7-2-92 7-2-92 7-2-92 7-2-92 Reporting Analyte Emit, mg/kg Concentration, mg/l<g Benzene 0.005 <0.005 <0.005 <0.005 <0.005 Toluene 0.005 0.008 0.023 0.028 < 0.005 Ethyl benzene 0.005 < 0.005 0.006 0.007 < 0.005 Xylene., total 0.015 < 0.015 0.049 0.046 0.016 BTEX, total - 0.008 0.078 0.081 0.016 Gasoline 10 < 10 < 10 < 10 < 10 Dilut. ion M .ultlplierb I 1 I 1 Percent solids, % 93.2 93.6 91.4 74.3 TFT surrogate©, % recovery 106 105 78.8 104 a. Test Meth~)ds for Evaluating Solid Waste, SW-8460 Third Edition, Revision 0, US EPA November 1986. Modification for TPH as gasoline as per C, alifornia State Water Resources Board LUFT Manual procedures. Results are calculated on a wet weight basis. b. Indicates the adjustments made for sample dilution. TFT surrogate recovery acceptability limits of 72.8-123% are derived from the 99% confidence interval of all samples during the previous quarter. Expected surrogate value is 1.07 mg/kg. GTEL Torrance, CA Page 3 T206517.DOC GTEL ENVIRONMENTAL LABORATORIES. INC, GTEL Client Number:. GTI78.ARC01 Representative: Katert Luka Facility Number:. 6218 Work Order Number:. T206517 ANALYTICAL RESULTS Volatile Organics In Soil EPA Methods Modified 8020 and Modified 8015a GTEL Sample Number 06517-8 06517-9 06517-10 Client Identification B 12-40 B13-35 B13-40 Date Sampled 6-26-92 6-26-92 6-26-92 Date Extracted 6-30-92 6-30-92 6-30-92 Date Analyzed 7-2-92 7-2-92 7-2-92 Reporting Analyte Limit, mg/kg Concentration, mg/kg Benzene 0.005 <0.005 < 0.005 < 0.005 Toluene 0;005 <0.005 < 0.005 0.008 Ethyl benzene 0.005 < 0.005 < 0.005 < 0.005 Xylene, total 0.015 <0.015 <0.015 <0.015 BTEX, total -- -'- -- 0.008 Gasoline 10 < 10 < 10 < 10 Dilution Multiplierb 1 I 1 Percent solids, % 84.4 85.2 93.4 TFT surrogatec, % recovery 92.5 77.8 101 a. Test Methods for Evaluating Solid Waste, SW-846, Third Edition, Revision 0, US EPA November 1986. Modification for TPH as gasoline ss per California State Water Resources Board LUFT Manual procedures. Results are calculated on a wet weight basis. b. Indicates the adjustments made for sample dilution. c. TFT surrogate recovery acceptability limits of 72.8-123% are derived from the 99% confidence interval of all samples during the previous quarter. Expected surrogate value is 1.07 mg/kg. GTEL Torrance, CA Page 4 T206517.DOC /GTEL ENVIRONMENTAl. LA~ORATORIES, INC. GTEL Client Number: GTI78.ARC01 Representative: Kateri Luka Facaity Number:. 6218 Work Order Number:. T206517 CONFORMANCE/NONCONFORMANCE SUMMARY Abbreviations: X = Requirements Met * = See Comments NA = Not Applicable - = Test Not Required VOA = Volatiles SV = Semi Volatiles ND Not Detected VOA VOA . SV SV Wet # Conformance Item GC GC/MS GC GC/MS Metals Chem 1 Holding Time X : 2 Method Accuracy X 3 Method Precision X 4 Surrogate Recovery X 5 Blank ND Comments: GTEL Torrance, CA Page 5 T206517.DOC BGTEL ENVIRONMENTAL LAEORATORIES. INC,.. GTEL Client Number:. GTI78.ARC01 Re~resentative: Kateri Luka Facility Number: 6218 Work Order Number: T206517 QC Check Sample Results Matrix: Soil Date of Expected Analyte Source Analysis Value Units Recoverya, % GC: Benzene Ultra Sclentific 7-2-92 150 ug/L 82.0 (81.1-118) Toluene Ultra Scientific 7-2-92 150 ug/L 83.3 (79.9-123) Ethylbenzene Ultra Scientific 7-2-92 150 ug/L 85.3 (81.1-123) Xylene, total Ultra Scientific 7-2-92 450 ug/L 85.1 (82.9-123)' Acceptability limits are in parentheses. GTEL Torrance, CA Page 6 T206517.DOC IGTEL ENVIRONMENTAl. LABORATORIES. IN~, GTEL Client Number:. GTI78.ARC01 Re~resentative: Kated Luka Facility Number:. 6218 Work Order Number:. T206517 Matrix Spike and Duplicate Spike Results Matrix: Soil Reco- Duplicate_ Sa_m_ple Date of Sample Spike very. Recoverya Analyte ID Analysis Amount Amount Units% % RPDa, % GC: Benzene T206517-10 7-2-92 <0.005 1.71 mg/kg 37.0 30.9 (30.9-82.9) 18.0 (30) Toluene T206517-10 7-2-92 0.008 1.71 mg/kg 43.0 38.4 (29.1-78.7) 11.3 (30) Ethylbenzene T206517-10 7-2-92 <0.005 1.71 ling/kg 50.5 44.8 (31.1-83.9) 12.0 (30) Xylene, total T206517-10 '7-2-92 <0.015 5.14 !mg/kg 52.6 47.5 (37.4-101) 10.2 (30) a. Acceptability limits are in parentheses. GTEL Torrance, CA Page 7 T206517.DOC IGTEL ENVIRONMENTAt. LABORATORIES, INC. ,qr .-~__~'- ~_ Chain of ody ~r~,~.;u~f~,o.~, Task Order No. ~ Clly Project ~ager / -- ~ ~ Umlhod el shipment Water O~er Ice ~ld ' ~'= ~'~ ~ ~= 3~ ~ ~ - So--al det~l~fl ' ',// ~ nu~ / T~nm~ ~e ~~ Tem~raturer~.~: ~ ~' P~i~ R~ , 1 B~ Day OI8~'ibutio~: White copy -- Laboi'atory;, Canary copy -- ARCO Environmental Engineering; Pink copy -- Consultant APPC,-3292 (2-01) APPENDIX E SESOIL Climate and Chemical Data Input C.OUNDWATE. TECHNOLOGY Table El. Chemical input data for the SESOIL simulation. Parameter Benzene Toluene Ethyl- Xylenes Reference benzene Solubility 1790 534.8 161.0 156.0 Howard, (mg/I) 1990 Diffusion Coeff. in Air 0.087 0.083 0.076 0.076 Lyman, et al, (cm2/s) 1990 Henry's Law Constant 0.00543 0.00594 0.00844 0.00768 Howard, (atm-m3/mol) 1990 Adsorption Coeff. on 98.0 331.13 870.96 870.96 GSC, 1990 Carbon (I/kg) Molecular Weight 78.1 92.14 106.17 106.17 Howard, (g/mol) 1990 Table E2. Climate input data for the SESOIL simulation. Precipitation data is from NOAA (1989). Evapotranspiration is at the most minimal level SESOIL will allow. Storm-pulse data is from Riskpro (G$C, 1990) databases. Month Parameter Precipitation (em) 2.62 2.54 2.64 1.55 0.74 0.20 0.03 ' 0.08 0.33 0.84 1.42 1.98 Evapotranspiration 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 (cra/day) Mean Time Rainfall 0.40 0.40 0.37 0.33 0.16 0.04 0.01 0.04 0.10 0.14 0.33 0.37 (days) Mean No. Storms 2.94 2.74 2.42 1.82 0.51 0,14 0.09 0.11 0.41 0.80 1.77 1.85 Mean Season 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 30.4 (days) I[~[]~]L~I GROUNDWATER ~ TECHNOLOGY F ~ Cardim/® APPENDIX F 95% Upper Confidence Level and Pollutant Load Calculations GROUNDWATER TECHNOLOGY Table F1 Calculation of 95% UCL for benzene. Sample - Sample Location With Analyte Concentrations* 95% Upper Depth I I Mean Standard Confidence Represented B9 B10 B11 T1 T2 Deviation Level 0-5' 5-10' 10-15' 0,85 24 12 12 29 15-20' 1,8 4 3 2.9 4.4 20-25' 0,53 0.53 N/A N/A 25-30' < 0.005 0.005 N/A N/A 30-35' 3.2 1,0 2.1 1.6 4.3 35-40' < 0.005 0.005 N/A N/A 40-45' 0,089 <0.005 0,050 0.060 0.13 45-50' 50-55' < 0.005 0.005 N/A N/A 55-60' 0.027 <0,005 0,016 0.016 0.038 60-65' 65-70' 70-75' 0.022 0.022 N/A N/A 75-80' 0.11 0.11 N/A N/A * Blanks indicate no data available. N/A = Not applicable to one data point. [][~[] GROUNDWATER _..~[~[~ TECHNOLOCY Table F2. Calculation of 95% UCL for toluene Sample - Sample Location With Analyte Concentrations* 95% Upper Depth I I I I Mean Standard Confidence Represented B9 B10 B11 T1 T2 Deviation Level 0-5' 5-10' 10-15' 13 230 122 109 272 15-20' 9,8 87 48 39 102 20-25' 4,1 4,1 N/A N/A 25-30' < 0,005 0.005 N/A N/A 30-35' 12 7.1 9.6 3.48 14.35 35-40' 0.009 0.09 N/A N/A 40-45' 0.55 0.008 0.28 0.390 0.83 45-50' 50-55' 0.1 0.023 0.06 0.05 0.14 55-60' 0.028 0.28 N/A N/A 60-65' 65-70' 70-75' 0,1 0.1 N/A N/A 75-80' 0,19 0.19 N/A N/A * Blanks indicate no data available. N/A = Not applicable to one data point. GROUNDWATER TECHNOLOGY Table F3. Calculation of 95% UCL for ethylbenzene. Sample - Sample Location With Analyte Concentrations* 95% Upper Depth I I I I Mean Standard Confidence Represented B9 B10 B11 T1 T2 Deviation Level 0-5' 5-10' 10-15' 5.7 71 38 33 84 15-20' 8.3 33 21 12 38 20-25' 8.6 8.6 N/A N/A 25-30' 0,008 0.008 N/A N/A 30-35' 1.4 1.3 1,4 0.07 1,5 35-40' < 0.005 0.005 N/A N/A 40-45' 0.11 < 0.005 0.058 0,074 0,16 45,50' 50-55' 0.017 0.006 0.012 0.008 0.023 55-60' 0.007 0.007 N/A N/A 60-65' 65-70' 70-75' 0.014 0.014 N/A N/A 75-80' 0.021 0.021 N/A * Blanks indicate no data available. N/A = Not applicable to one data point. Table F4. Calculation of 95% UCL for xylenes. Sample - Sample Location With Analyte Concentrations* 95% Upper Depth I I I I Mean Standard Confidence Represented B9 B10 B11 T1 T2 Deviation Level 0-5' 5-10' 10-15' 100 460 280 180 529 15-20' 310 300 305 5 312 20-25' 150 150 N/A N/A 25-30' 0.087 0.087 N/A N/A 30-35' 8.2 7.4 7.8 0.566 8.584 35-40' 0.033 0.033 N/A N/A 40-45' 0.77 < 0.015 0.39 0.53 1.1 45-50' 50-55' 0.14 0.049 0.095 0.06 0,18 55-60' 0.046 0.046 N/A N/A 60-65' 65-70' 70-75' 0.11 0.11 N/A N/A 75-80' 0.17 0.17 N/A N/A * Blanks indicate nO data available. N/A = Not applicable to one data point. [~][~-] GROUNDWATER [~[~[~ TECHNOLOGY Table F5. Upper confidence levels and mass of hydrocarbons in place per 5-foot depth increment. Total pollutant per compartment is divided by the application area (581,000 cm2) to derive ~ollutant loads. Concentrations in/~g/g, masses in/~g, and pollutant load in/~g/cm2. Depth Benzene I Toluene J Ethylbenzene I Xylenes Interval UCL Mass I UCL. I Mass I UCL I Mass I UCL I Mass 0-5' 29 3.48e9 272 3.26e10 84 1.01e10 529 6.35e10 5-10' 29 3,48e9 272 3,26e10 84 1,01e10 529 6,35e10 10-15' 29 3.48e9 272 3.26el 0 84 1.01 el 0 529 6.35e10 15-20' 4.4 5.28e8 102 1.22e10 38 4.56e9 312 3.74e10 20-25' 4,3 5.16e8 14.4 1.73e9 8.6 1.03e9 150 1.80e10 25-30' 4.3 5.16e8 I' 14.4 1.73e9 8.6 1.03e9 8.6 1.03e9 30-35' 4.3 5.16e8 14.4 1.73e9 1.5 1.80e8 8.6 1.03e9 Mass in Layer 1 1.25el 0 1,15el I 3,71e10 2,48el 1 Pollutant Load 2,15e4 1,98e5 6.39e4 4,27e5 Mass in Layer 2 5.16e8 9.9e7 1.92e7 1.32e8 Pollutant Load 888 170 33.0 227 40-45' 0.131.56e7 .8259.9e7 .161.92e7 1.1 1.32e8 45-50' 0.13 1.56e7 0.825 9.9e7 .16 1.92e7 1.1 1.32e8 50-55' 0.11 1.32e7 0.28 3.36e7 .023 2.76e6 .18 2.16e7 55-60' 0.11 1.32e7 0.28 3.36e7 .023 2.76e6 0.17 2.04e7 60-65' 0.11 1.32e7 0.28 3.36e7 .023 2.76e6 0.17 2.04e7 65-70' 0.11 1.32e7 0.28 3.36e7 .023 2.76e6 0.17 2.04e7 70-75' 0.11 1.32e7 0.19 2.28e7 .023 2.76e6 0.17 2.04e7 75-80' 0.11 1.32e7 0.19 2.28e7 0.021 1.59e6 0.17 2.04e7 Mass in Layer 3 1.10e8 3.78e8 5.47e7 3.88e8 Pollutant Load 189 651 94.2 667 GROUNDWATER TECHNOLOGY APPENDIX G Abbreviated SESOIL Output Files GROUNDWATER TECHNOLOGY Table Gla. Benzene concentrations in soil moisture ~g/m~), adsorbed ~g/g), in soil air (p,g/m~) and in the pure phase ~g/m~). Shaded concentrations are below typical laboratory method detection limits. Pollutant Concentrations in Soil Year I Simulated Compartment I Compartment 2 Moist. Ads. I Air I Pure [ Total I Moist. I Ads. Air I Pure I Total 1 81,6 1,60 19,6 [.:?~![i[i[ ~i:?:~i~i~i~i~i~i 102,8 41,2 0,808 9,89 :::::::::::::::::::::::::::::::::::::::: · 10 0,821 0,0161 0,197 :~ :~ :~ i ::.:: :~ :: :~iiii??:iil 1,03 0,829 0,0163 0,199 iii.i:: ::::::::::::::::::::::::::::::::::::::::: 1,04 , :,::,.:..,:::,:::,::.,.:. .:., .....,., :......:...:.::.,,.....:.:,.::.::.:.:. ,. .... ...:.:::::.::.:...[:.:.:... ,....:..:...:,::,:.::,:.,:::,.:, .:,::>:.::,....:,.,...,.:,..,,,,.,.., :::.:.:.:.:.:.: ..... , . :::::::::::::::::::::::::::::::: ......~., :::;..:::::::::.:..,.............. ::::::::::::::::::::::::: .:,.:.:.:.:.::.:..:.:.::.,:.:: ========================= ...... .~, ...~......,::.:.:.:...... ::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::: ,'. ,....'..':.::.:.:.:.:<::< ...... ...... ::::::::::::::::::::::::::::::::: :.:.::........,,.., ,::.::.:.::.:.: :::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::: ............ .... Table G1 b. Benzene concentrations in soil moisture ~g/m~), adsorbed ~g/g), in soil air ~g/m~) and in the pure phase ~g/m~). Shaded concentrations are below typical laboratory method detection limits. Pollutant Concentrations in Soil Year Simulated Compartment 3 Compartment 4 Moist.I Ads. [ Air Pure [ Total [ Moist.I Ads. ] Air [ Pure I Total I 1.06 0,0208 0,254 ::::::::::::::::::::::::::::: 1,33 ....... 10 0.330 6.47e-3 0.0793 :: ::?: :: ::: :: ::::::::?::::::::::::: 0.416 :::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::: :.::.: .. :.::-:. :.::.:........::.:::.:...... > :':':::::::'[':::;' !.!. GROUNDWATER TECHNOLOGY Table G2a. Toluene concentrations in soil moisture (~g/m~), adsorbed ~g/g), in soil air ~g/m~) and in the pure phase (~g/m0. Shaded concentrations are below typical labo,ratory method detection limits. Pollutant Concentrations in Soil Year I Simulated Compartment I Compartmen! 2 1 535 35.4 1.40 269 979 109 7.23 28.6 ::f: ::f:f:f:f:f:fj: :::::?:::::?:f: 145 10 21.4 1,41 5.61 :: :::::: ?:::::::::?:?:?: ?:?:::?: 28.4 21.6 1.43 5.66 !ii i f:ii!?:i::i::01 ~???.i::i?? 28.7 20 0.510 0.0338 0.134 ~?:!i~?:f:il 0 i:?:!::f:?:~}~i~ 0,678 0.515 0.0341 0.0135 ?:f:;:f:~ ~ f:~}0 :: ::i}~?:}[?}~ 0.563 30 0.0123 8.15e-4 3.23e-3 0 0.0163 0.0125 }?78;;3~}}?i i?i3i)~9~}}}~} 0.0166 Table G2b. Toluene concentrations in soil moisture (~g/m~), adsorbed (~g/g), in soil air ~g/m~) and in the pure phase (~g/m0. Shaded concentrations are below typical laboratory method detection limits. Pollutant Concentrations in Soil Year I Simulated Compartment 3 Compartment 4 Moist.I Ads. l. Air I Pure ] Total IMoist. I Ads. [ Air I Pure I Total ::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::: , ; ........... ; GROUNDWATER TECHNOLOGY Table G3a. Ethylbenzene concentrations in soil moisture ~g/mO, adsorbed ~g/g), in soil air ~g/mO and in the pure phase ~g/mO. Shaded concentrations are below typical laboratory method detection limits. Pollutant Concentrations in Soil Year I Simulated Compartment I Compartment 2 Moist. J Ads..I Air I Pure I Total I Moist.j Ads. ] Air I Pure [ Total 10 23,7 4,12 88,3 :~ i~i~i~i ?i~i 0~?!~i~i~i~i~?? 116 15,1 2,63 56,3 ii!i!iiiiiiiiiiiiO iii!iii?i!ii 74,0 20 9,35 1,63 34,9 iliii iiiiiiiiii ~.~.iiiiiiii!iiiiill 45,9 8,74 1,52 32,6 ii:f~ iiiiiiiiiiii~iiiiiiiiiiiiiiiii 42,9 30 3,76 0,655 14,0 iiii i?:ii 0!ii:i iiiii:~i::iii 18,4 3,76 0,656 14,0 !iii::ii !iii::i::ii~ !iiiiii::ii iiiiii 18,4 50 0,612 0,107 2,28 ~if.~ i~i~ii ~i!O?i?i:i~i~ii ~i 3.00 0,612 0,107 2,28 [i !?:ili:: ::~:i 0 ::ii?: i:.i ::~;::i 3,00 :::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::: 60 0,247 0,0431 0,923 iiii iiiiiii iiii:~::i:: ::i ?:iill i 1.21 0,248 0,0431 0,923 ~i,~!~i~i,~ ~?iq f:.~ !f~if?!~ 1,21 70 0,0994 0,0173 0,371 iliii i iiiiiii i Q i.i::i.i.:, iiiiii 0,488 0.0995 0,0173 0,371 , ::iii~i:~iii::iiiii::~iiii?:iiiil ii 0,488 80 0,0403 7,01 e-3 0,150 :~iiiiiii:~ili::ii! ~:i.liiii i!i,iiiii 0,197 0,0403 7,02e-3 0,150 iii iiiiiii iiiiiiO i?:?:i::i i::i 0,197 i:i:i:~:i:i:i:i:!.:::.i:i: :!:i:i: :i:i,~.!: i~ i:~i~i;i~: ~¥;i;ii ;¥;.i~ ~ :::: :'::::':: ::: :':::':::~ ::::::::::::::::::::::::::::::::::::::::: 90 · 0.0163 ::i?:i~:~:i::?:ii0.0606 ::::::::::::::::::::::::::::::::::::::::::::::::::::::: 0.080 0.0163 iii??:~:i~!~:,iiii~ 0.0607 :::::::::::::::::::::::::::::::::::::::::::::::::: 0.080 :::::::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::: 99 7,17e-3 :::::::::::::::::::::::::::::::::::: 0,0267 iil;i::i??.~;iiii:ii?!?:i;i;i 0,0351 7,17e-3 iiii::?:~:!~;~i:.?:!i 0,0268 ::;?:;iii;i?:iii~:iii;i;iiiii;ili;i 0,0352 Table G3b. Ethylbenzene concentrations in soil moisture (fi.g/mO, adsorbed ~g/g), in soil air ~g/m0 and in the pure phase ~g/m.0). Shaded concentrations are below typical laboratory method detection limits. Pollutant Concentrations in Soil Year Simulated Compartment 3 Compartment 4 Moist. [ Ads. [ Air I Pure ] Total [ Moist. I Ads. [ Air [ Pure [ Total 1 0.0453 7.89e-3 0.169 ii?. i iiiil iii ~iiiiil i iiiiii!i ' 0.222 :::::::::::::::::::::::::::::::::::::::: , :::::::::::::::::::::::::::::::::::::: 80 0,0269 i:. ii!~i~9~:: ii::i 0,101 i iil ;f:?.}O if:?:?4~:,}:: 0,133 90 0,0132 ii;iii~i~:~ !iiii! 0,0492 i ! ~}}i}i:}}:~}:}i}ii::ii::}'};} 0,0647 I~iil !:; ;:~!:i!!:;;i :::! ::::U: ::i:i;:::: !;;;;:i:!~i;i:; ;i;: ::::::::::::::::: ::::::::::: :::::: ::::::::::::::::::::::::::::::: :::::::::::::::: :::::: ::: :::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::` ' '" '"'"' 99 6.583-3 ' f?::f:;~i :.::.~ :~:~ i :.iii 0.0245 0.0322 TECHNOLOGY Table G4a. Xylene isomer concentrations in soil moisture ~g/m~), adsorbed ~g/g), in soil air ~g/m~) and in the pure phase ~g/m{~). Shaded concentrations are below typical laboratory method detection limits. Pollutant Concentrations in Soil Year Simulated Compartment 1 I Compartment 2 Moist. I Ads. Air I Pure Total [ Moist.I Ads. [ Air I Pure I Total 10 175 30.5 39.4 2.080 2.320 95.2 16.6 21.5 iiiii::iiii?:ii? :? i!! ?~i 133 40 1.49 0.260 - 0,336 0 2.09 1,51 0,262 0.340 i~ii}i~ii:?:i!!i~ii:?~:?:ii!i:?~i:~:~}i?~i 2.11 Table G4b. Xylene isomer concentrations in soil moisture ~g/m~), adsorbed (p.g/g), in soil air ~g/m~) and in the pure phase (/~g/m~). Shaded concentrations are below typical laboratory method detection limits. Pollutant Concentrations in Soil Year Simulated Compartment 3 Compartment 4 40 0.681 0.115 0.149 0.925 0.0993 0.0173 0.0224 0.1~ 60 0.0169 :::::::::::::::::::::::::::::::::::::::::::::::::::::::: :~:~:::~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~:~ ::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::: TECHNOLOGY GROUNDWATER ***** SESOIL-84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. LITTLE INC. ,(617)864-5770,X5871 ***** ***** J. WAGNER ,DIS/ADLPIPE, INC. ,(617)492-1991,X5820 ***** ***** MODIFIED EXTENSIVELY BY: ***** ***** D.M. HETRICK ***6* OAK RIDGE NATIONAL LABORATORY ***** (615) 576-7556 ***** ***** VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION ****** MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : BENZENE WASHLOAD DATA : APPLICATION AREA: ARCO 6218, BAKERSFIELD, CA- BENZENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .100E-07 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E-01 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): .000 FREUNDLICH EXPONENT (o): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBlUTY (UG/ML): .179E+04 OIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .870E-01 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .543E-02 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 98.0 ADSORPTION COEFFICIENT ON SOIL (t0: .000 MOLECULAR WEIGHT (G/MOL): 78.1 VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .(XX) DEGRADATION RATE IN MOISTURE (/DAY): .200E-02 DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND-POLLUTANT STABlUTY CONSTANT (-): .000 NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 UGAND MOLECULAR WEIGHT (G/MOL): .000 - APPUCATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: YEARS TO BE SIMULATED: AREA (CM**2): APPUCATION AREA LATITUDE (DEG.): SPILL (1) OR STEADY APPUCATION (O): DEPTHS (CM): NUMBER OF SUBLAYERS/LAYER PH (CM): INTRINSIC PERMEABlUTIES (CM**2): KDEL RATIOS (-): KDES RATIOS (-): OC RATIOS (-): CEC RATIOS (-): FRN RATIOS(-): ADS RATIOS(-): 4 O.~IE+~ ~.0 1 0.11E+~ 0.15E+~ O.~E+~ 0.12E+~ I 1 1 1 7.0 7.0 7.0 7.0 O. 10E~50.10E~)80.10E~40.10E~5 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 YEAR- I MONTH~ INPUT PARAMETERS - CUMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.(XX) 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 0.000 0.000 0.000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 O.0(X) 0.000 0.000 0.000 0.000 0.000 0.000 REL HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0,330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0,100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30,400 30,400 30.400 30.400 30.400 30.400 30.400 30.400 - POLLUTANT INPUT PARAMETERS - PO[- INP-1 (UG/CM**2) 2.15E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+000.0OE+00 0.00E+00 0.00E+ 00 0.00E +00 LIG.INPUT-1 (UG/CM**2) 0.00E+ 00 0.00E + 00 0.00E+00 0.00E +00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E +00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 VOLATILIZATION MULTo-1 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E+00 SURFACE RUNOFF MULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+ 00 0.00E+ 00 PO[- IN RNN (FRAC~SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 PO[- INP-2 (UG/CM**2) 8.88E+02 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E +00 0.00E+ 00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+OO 1.00E+ 00 1.00E+00 1.00E+ 00 1.00E+00 1.00E+00 1.00E+ 00 1.00E+00 1.00E+00 1.00E+00 1.00E+ 00 1.00E+00 PO[- INP-3 (UG/CM**2) 1.89E+02 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 LIG.INPUT-3 (UG/CM**2) 0.00E +00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+ 00 VOLATILIZATION MULT.-3 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E+ 00 1.00E + 00 1.00E+00 1.00E+00 PO[- INP-L (UG/CM**2) 0.00E+00 0.00E+ 00 0.00E+00 O.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 O.00E+00 TRNSFORMI~L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 · 0.00E+00 0.00E+00 O.00E+00 SINKS-L (UG/CM"*2) O,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O0 O,OOE+O00,OOE+O0 MG,INPUT-L (UG/CM**2) O,OOE + O00,OOE+ O00,OOE+O00,OOE + O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O0 O,OOE+O00,OOE+O0 VOLATIMZATiON MULT,-L 1,00E +00 1,00E +00 1,00E +00 1,00E +00 1,00E +00 1,00E +00 1,00E + O0 1,00E +00 1,00E +00 1,00E +00 1,00E+ O0 1,00E+O0 YEAR - 2 MONTHLY INPUT PARAMETERS - CUMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POL, INP-1 (UG/CM**2) O,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O0 O,OOE+ O00,OOE+O0 TRNSFORMD-1 (UG/CM**2) O,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O0 O,OOE+O00,OOE+O00,OOE+O0 SINKS-1 (UG/CM**2) O,OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 UG,INPUT-1 (UG/CM**2) O.OOE+O00.OOE+O00,OOE+O00,OOE+ O00.OOE+ O00.OOE+O00.OOE+O00.OOE+ O00.OOE+O00.OOE+ O0 O,OOE +00 O, OOE+ O0 VOLATILIZATION MULT,-10.OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00.OOE + O00.OOE + O00,OOE + O00,OOE + O0 O,OOE+O00.OOE+O0 SURFACE RUNOFF MULT, O,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00.OOE + O00,OOE + O0 O,OOE +00 O,OOE+O0 POL IN RAIN (FRAC-SL) O,OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O0 O,OOE+O00,OOE+O0 POL INPo2 (UG/CM**2) O, OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00.OOE+O00,OOE+O00,OOE+O0 O,OOE+O00.OOE+O0 TRNSFORMD-2 (UG/CM**2) O.OOE+O00,OOE+O00.OOE+O00, OOE+O00.OOE+O00.OOE+O00,OOE+O00, OOE+O00,OOE+O0 O,OOE+O00,OOE+O00,OOE+O0 SINKS-2 (UG/CM**2) O.OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O0 O,OOE+ O00,OOE+ O0 LIG,INPUT-2 (UG/CM**2) O,OOE+O00,OOE+ O00,OOE+O00,OOE+O00,OOE+ O00,OOE+O00,OOE+O00,OOE+ O00,OOE+O00,OOE +00 O,OOE+O00,OOE+O0 VOLATILIZATION MULT,-2 1,00E + O0 .I,00E + O0 1,00E + O0 1,00E + O0 1,00E + O0 1,00E + O0 1,00E + O0 1,00E + O0 1.00E+O0 1,00E + O0 1.00E+O0 1,00E+O0 POL, INP-3 (UG/CM**2) O,OOE +00 O.OOE+O00,OOE+O00,OOE+O00.OOE +00 O,OOE+O00,OOE +00 O.OOE+O00,OOE+OO O,OOE+O0 O,OOE+O00,OOE+O0 TRNSFORMD,,3 (UG/CM**2) O,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O0 O,OOE+O00,OOE+O00.OOE+O0 SINKS-3 (UG/CM**2) O,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+(}O O,OOE+O00.OOE+O0 O,OOE+O00.OOE+O0 MG,INPUT-3 (UG/CM**2) O,OOE + O00,OOE + O00,OOE + O00,OOE +00 O, OOE+ O00,OOE + O00,OOE +00 O,OOE + O00,OOE + O00, OOE + O0 O,OOE+O00,OOE+ O0 VOLATILIZATION MULT,-3 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 POL INP-L (UG/CM**2) O,OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O0 O.OOE+O00,OOE+O0 TRNSFORMD-L (UG/CM**2) O,OOE+O00.OOE+O00.OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O0 O,OOE+O00,OOE+O00,OOE +IX) SINKS-L (UG/CM**2) O,OOE+O00,OOE+O00.OOE+O00.OOE+O00,OOE+O00,OOE+ O00,OOE+O00,OOE+ O00,OOE+O00.OOE+O0 O.OOE+O00,OOE+O0 UG,INPUT-L (UG/CM **2) O,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O00,OOE + O0 O,OOE+O00,OOE + O0 VOLATlUZATION MULT,-L 1,00E+O0 1,00E+ O0 1,00E+O0 1,00E+O01,00E+ O01,00E+O01,00E+O0 1,00E + O01,00E+O01,00E+ O0 1,00E+ O0 1,00E+O0 YEAR - 3 MONTHLY INPUT PARAMETERS - CMMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR -99 MONTHLY INPUT PARAMETERS - CUMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - 1 MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. INL1 (%) 11.219 11.279 11.459 11.729 11.939 12.119 12.059 11.849 11.549 11.279 11.0,39 10.889 MOIS. BELOWLI(%) 11.219 11.279 11.459 11.729 11.939 12.119 12.059 11.849 11.549 11.279 11.039 10.889 PREClPATION (CM) 0.841 1.480 2.082 2.646 2,582 2.631 1.605 0,815 0.247 0.156 0.135 0.417 NETINFILT. (CM) 0.839 1,480 2.082 2.646 2.582 2.631 1.605 0.809 0.210 0.149 0.131 0.417 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) -0.363 0.242 0.726 1.059 0.847 0.726 -0.242 -0.847 -1.210 -1.089 -0.968 -0.605 SUR. RUNOFF (CM) 0.000 0.000 0.0(X) 0.000 0.(XX) 0.(XX) 0.000 0,000 0.037 0.000 0.(XX) 0.000 GRW, RUNOFF (CM) 0,898 0.934 1.052 1.253 1.431 1.601 1.543 1.352 1.116 0.934 0.795 0.718 YIELD (CM) 0.900 0.934 1.052 1.253 1.431 1.601 1.543 1.358 1.153 0.941 0.799 0.718 PAU/MPA (GZU) PA/MPA (GZ) 1.001 1.042 1.052 1.010 1.017 0.997 1.0,,'.'.'.'.'.'.'.'.~5 1.102 1.235 5.187 1.683 1,265 1.001 1.042 1.052 1.010 1.017 0.997 1.035 1.102 1.235 5.187 1.683 1.265 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. 0.(XX)E +00 0.000E+00 0.000E +00 0.000E +00 0.000E +00 0,(XX)E +00 0.000E +00 0.000E+00 0.000E+00 0.000E+00 0.000E + 00 0.000E + 00 LOAD UPPER 1.249E + 10 0.000E+ 00 0.000E + 00 0.000E + 00 0.0(X)E + 00 0.000E+ 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+00 0.000E+00 LOAD ZONE 2 5.159E + 08 0.000E + 00 0.000E + 00 0.000E + 00 0.0(X)E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+00 0.000E+00 LOAD ZONE 3 1.098E + 08 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E + 00 0.0(X)E+ 00 0.000E+ 00 0.000E + 00 0.000E+ 00 0.000E + 00 0.000E+00 0.000E+ 00 LOAD LOWER 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E + 00 0.000E+ 00 0.000E+ 00 0.00OE + 00 0.000E+ 00 0.000E + 00 O.000E +00 0.000E+00 TOTAL INPUT 1.312E + 10 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0,000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E+ 00 0 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 DEGRAD MOIS 4.475E + 05 4.302E + 08 4.147E + 08 4.007E + 08 3.850E + 08 3.692E + 08 3.507E + 08 3.325E + 08 3.150E + 08 3.006E + 08 2.860E+05 2.733E+08 IN SOIL MOl 7.312E+09 7.019E+ 09 6.758E+ 09 6.520E+ 09 6.264E+09 6.006E+ 09 5.716E+09 5.429E+ 09 5.151E+09 4.917E+09 4.680E+09 4,470E+09 ADS ON SOIL 1.726E+09 1.647E+09 1.561E+09 1.471E+09 1.388E+09 1.311E+09 1.254E+09 1.212E+09 1.180E+09 1.154E+09 1.122E+09 1.086E+09 IN SOIL AIR 2.953E+09 2.811E+09 2,6,38E+09 2.441E+09 2.277E+09 2.129E+09 2.054E+09 2.009E+09 1.987E +09 1.933E+09 1.904E + 09 1,858E + 09 SOIL ZONE 2: SUBLAYER 1 DEGRAD MOIS 1.051E + 07 2.08OE+ 07 2.238E + 07 2.437E + 07 2.613E+ 07 2.751E+ 07 2.794E+ 07 2.752E+ 07 2.655E+ 07 2.558E+ 07 2,453E+07 2,367E+07 IN SOIL MOl 3,351E +08 3.559E +08 3,952E +08 4,197E +08 4,457E +08 4,662E +08 4,665E +08 4,551E+08 4,354E +08 4.201E+08 4.027E+08 3.897E+08 ADS ON SOIL 7.903E + 07 8.349E + 07 8.894E + 07 9.469E + 07 9.879E +07 1.018E + 08 1.024E + 08 1.016E + 08 9.999E + 07 9.856E+07 9.653E+07 9.470E+07 IN SOIL AIR 1.353E+08 1.425E+08 1.504E+08 1.571E+08 1.620E+08 1.653E+08 1.676E+08 1.684E+08 1.684E+08 1.652E+08 1.638E+08 1.620E+08 SOIL ZONE 3: SUBLAYER 1 DEGRAD MOIS 2.164E + 06 4.706E + 06 5.796E + 06 7.367E + 06 9.184E + 061.108E+ 071.249E + 071.311E+071.310E+ 071.288E + 07 1.256E+07 1.237E+07 IN SOIL MOl 7.106E+07 8.521E+07 1.067E+08 1.367E+08 1.673E+08 1.996E+08 2.168E+08 2.219E+08 2.177E+08 2.134E+08 2.078E + 08 2.060E + 08 ADS ON SOIL 1.676E + 07 1.999E+ 07 2.465E + 07 3.083E+ 07 3.708E + 07 4.358E + 07 4.758E + 07 4.955E + 07 4.988E + 07 5.007E+ 07 4.981E+07 5.005E+ 07 IN SOIL AIR 2.870E+07 3.412E+07 4.167E+07 5.116E+07 6.082E+07 7.076E+ 07 7.790E+ 07 8.209E+07 8.400E+07 8.391E+07 8.455E+07 8.563E + 07 LOWER SOIL ZONE: SUBLAYER I - POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER I MOISTURE 1.048E+02 1.001E+02 9.488E+01 8.943E+01 8.441E+01 7.972E+01 7.625E+01 7.371E+01 7.174E+01 7o013E+01 6.820E+01 6.603E+ 01 %SOLUBILITY 5.854E + O0 5.590E + O0 5.297E + O0 4.993E + O0 4.713E +00 4.451E+00 4.257E + O0 4.116E + O0 4.006E + O0 3.916E + O0 3.808E+00 3.687E+00 ADSORBED 2.055E+00 1.962E+00 1.860E+00 1.753E+00 1.654E+00 1.563E+00 1.494E+00 1.445E+00 1.406E+00 1.375E+00 1.337E+ O0 1.294E+00 SOILAIR 2.529E+01 2.415E+01 2.289E+01 2.149E+01 2.028E+01 1.916E+01 1.841E+01 1.780E+01 1.732E+01 1.661E+01 1.615E+01 1.564E+01 SOIL ZONE 2: SUBLAYER 1 MOISTURE 3.427E+01 3.621E+01 3.857E+01 4.106E+01 4.284E+01 4.414E+01 4.439E+01 4.407E+01 4.336E+01 4.274E+01 4.186E+01 4o107E+01 %SOLU BILITY 1.914E + O0 2.022E + O0 2.154 E + O0 2.293E + O0 2.392E + O0 2.465 E + O0 2.478E + O0 2.461E + O0 2.421E + O0 2.386E + O0 2.337E+ O0 2.293E+00 ADSORBED 6.717Eq31 7.096E-01 7.560E-01 8.048E~1 8.396E~31 8.651E-01 8.700Eq31 8.638E~1 8.498E~31 8.377E~1 8.205E~31 8.049Eq31 SOIL AIR 8.268E+00 8.735E+00 9.305E+00 9.867E+00 1.029E+01 1.081E+01 1.072E+01 1.064E+01 1.047E+01 1.012E+01 9.915E+00 9.727E+00 SOIL ZONE 3: SUBLAYER 1 MOISTURE 4.543E-01 5.418E4~1 6.681E~31 8.357E~1 1.005E+00 1.181E+00 1.289E+00 1.343E+08 1.352E+00 1.357E+00 1.350E+00 1.357E+00 %SOLUBlUTY 2.536E-02 3.025E-02 3.730E~2 4.666E~2 5.612E~2 6.594E~32 7.200E-02 7.499E-02 7.549E-02 7.578E~2 7.538E~32 7.575E~32 ADSORBED 8.903E-03 1.062E-02 1.309E-02 1.638E-02 1.970E-02 2.315E-02 2.527E-02 2.632E-02 2.650E-02 2.660E-02 2.646E-02 2.659E-02 SOIL AIR 1.096E-01 1.307E-01 1.612E-01 2.008E-01 2.415E-01 2.838E-01 3.114E-01 3.243E-01 3.265E-01 3.214E-01 3.198E-01 3.213E-01 LOWER SOIL ZONE: POL DEP CM 2.425E + 03 2.431E+03 2.440E + 03 2.450E+ 03 2.461E+03 2.472E + 03 2.480E + 03 2.486E + 03 2.489E + 03'2.492E + 03 2.495E+03 2.498E+03 YEAR - I ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 1.249E + 10 SOIL ZONE 2' 5.159E+08 SOIL ZONE 3 1.098E+08 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.534 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.534 15.637 15.580 3.648 0.637 13.626 -1.694 TOTAL YIELD (CM) 13.683 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED' FOR FINAL MASS IN SOIL MOL, ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 4.305E+09 2.875 E + 08 1.168E+08 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 8.162E+01 ADSORBED SOIL (UG/G) 1.600E+00 SOIL NR (UG/ML) 1.960E+01 SOIL MOISTURE (UG/ML) 4.121E+01 ADSORBED SOIL (UG/G) 8.078Eq31 SOIL AIR (UG/ML) 9.889E+00 SOIL MOISTURE (UG/ML) 1.061E+00 ADSORBED SOIL (UG/G) 2.080E~32 SOIL AIR (UG/ML) 2.544Eq31 MAY~ POLL DEPTH (M) 2.498E+01 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.(XX)E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 8.671E + 05 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 4.256E+07 6.029E + 06 3.817E+07 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 8.206E-01 ADSORBED SOIL (UG/G) 1.608E-02 SOIL AIR (UG/ML) 1.971E-01 SOIL MOISTURE (UG/ML) 8.292E-01 ADSORBED SOIL (UG/G) 1.625E-02 SOIL AIR (UG/ML) 1.991E-01 SOIL MOISTURE (UG/ML) 3.300E-01 ADSORBED SOIL (UG/G) 6,469E~3 SOIL AIR (UG/ML) 7.924E-02 MAX. POLL DEPTH (M) 3.172E+01 YEAR - 20 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11,364 15.701 15.633 3.648 0.051 12.227 ~3.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.638E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 8.088E+03 TOTAL DEGRADED (MOISTURE) 3.756E+04 SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) 3.563E+03 TOTAL DEGRADED (MOISTURE) 6.64OE+05 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.850E+04 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.088E~33 ADSORBED SOIL (UG/G) 9.972E~)5 SOIL AIR (UG/ML) 1.222Eq33 SOIL MOISTURE (UG/ML) 5.167E~:)3 ADSORBED SOIL (UG/G) 1.013Eq34 SOIL AIR (UG/ML) 1.241E~3 SOIL MOISTURE (UG/ML) 5.721E-03 ADSORBED SOIL (UG/G) 1.121E~34 SOIL NR (UG/ML) 1.374E~33 SOIL MOISTURE (UG/ML) 1.174E~)3 ADSORBED SOIL (UG/G) 2.301E~5 SOIL AIR (UG/ML) 2.818E~4 MA~ POLL DEPTH (M) 3.895E+01 YEAR - 30 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 TOTAL PRECIPITATION (CM) 15.701 TOTAL INFILTRATION (CM) 15.633 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.051 TOTAL GRW RUNOFF (CM) 12.227 TOTAL MOISTURE RETENTION (CM) -0.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.935E+03 1.577E + 02 2.823 E + 02 1.452E+02 7.070E + 03 3.041E+03 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.736E~5 ADSORBED SOIL (UG/G) 7.322E-07 SOIL AIR (UG/ML) 8.970E-05 SOIL MOISTURE (UG/ML) 3.886E-05 ADSORBED SOIL (UG/G) 7.618E-07 SOIL AIR (UG/ML) 9.333E-06 SOIL MOISTURE (UG/ML) 6.089E-05 ADSORBED SOIL (UG/G) 1.193E~6 SOIL AIR (UG/ML) 1.462E-05 SOIL MOISTURE (UG/ML) 5.169E-05 ADSORBED SOIL (UG/G) 1.013E-06 SOIL AIR (UG/ML) 1.241E~5 MA~ POLL DEPTH (M) 4.576E+01 YEAR - 40 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 soIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL Gl:NV RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 1.697E + 01 1.733E+00 2.499E + 00 1,836E+00 7,228E+01 1,196E+00 4.218E+01 5,138E+00 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.280E-07 ADSORBED SOIL (UG/G) 6.428E-09 SOIL AIR (UG/ML) 7.875E-08 SOIL MOISTURE (UG/ML) 3.444E-07 ADSORBED SOIL (UG/G) 6.751E~9 SOIL AIR (UG/ML) 8.270E~8 SOIL MOISTURE (UG/ML) 6.225E-07 ADSORBED SOIL (UG/G) 1.220E~8 SOIL AIR (UG/ML) 1.495E-07 SOIL MOISTURE (UG/ML) 7.146E~37 ADSORBED SOIL (UG/G) 1.401E-08 SOIL AIR (UG/ML) 1.716E-07 MAY~ POLL DEPTH (M) 4.840E+01 YEAR - ~ ANNUAL SUMMARY REPO~ - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 1.768 E + 00 2.44OEq31 2.648E~1 2.138E+00 1.501 E~I 1.770E+00 2.159E~31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOiL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 3.477E-08 ADSORBED SOIL (UG/G) 6.814E-10 SOIL AIR (UG/ML) 8.343E-09 SOIL MOISTURE (UG/ML) 3.717E-08 ADSORBED SOIL (UG/G) 7.285E-10 SOIL AIR (UG/ML) 8.920E-09 SOIL MOISTURE (UG/ML) 1.875E~38 ADSORBED SOIL (UG/G) 3.675E-10 SOIL AIR (UG/ML) 4.499E~:)9 SOIL MOISTURE (UG/ML) 3.053E-05 ADSORBED SOIL (UG/G) 5.985E-10 SOIL AIR (UG/ML) 7.327E~9 MAX, POLL DEPTH (M) 4.840E+01 YEAR - 60 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.(XX)E+00 SOIL ZONE 3 O.000E+00 LOWER SOIL ZONE 0.000E+ 00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 1.434E+00 1.854Eq31 1.606E+00 1.484E-01 1.491E+00 1.820E-01 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.822E~38 ADSORBED SOIL (UG/G) 5.530E-10 SOIL AIR (UG/ML) 6.771E~9 SOIL MOISTURE (UG/ML) 2.600E~8 ADSORBED SOIL (UG/G) 5.096E-10 SOIL AIR (UG/ML) 6.239E~39 SOIL MOISTURE (UG/ML) 1.408E~8 ADSORBED SOIL (UG/G) 2.760E-10 SOIL AIR (UG/ML) 3.380E-09 SOIL MOISTURE (UG/ML) 2.573E-08 ADSORBED SOIL (UG/G) 5.044E-10 SOIL AIR (UG/ML) 6.175E-09 MA~ POLL DEPTH (M) 4.84OE+01 YEAR - 70 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 -0.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.'193E+00 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 5.335E-02 TOTAL DEGRADED (MOISTURE) 1.711E-01 SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.086E+00 LOVVER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.460E-01 TOTAL DEGRADED (MOISTURE) 1.217E+00 TOTAL IN GROUNDWATER RUNOFF 1.485E-01 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 2.347E~8 ADSORBED SOIL (UG/G) 4.599E-10 SOIL AIR (UG/ML) 5.631E~9 SOIL MOISTURE (UG/ML) 2.400E~8 ADSORBED SOIL (UG/G) 4.704E-10 SOIL AIR (UG/ML) 5.759E-09 SOIL MOISTURE (UG/ML) 9.525E-09 ADSORBED SOIL (UG/G) 1.867E-10 SOIL AIR (UG/ML) 2.286E-09 SOIL MOISTURE (UG/ML) 2.059E~8 ADSORBED SOIL (UG/G) 4.114E-10 SOIL AIR (UG/ML) 5.037E~9 MA)C POLL DEPTH (M) 4.840E+01 YEAR - 80 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.0OOE+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) ' TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.026E+00 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.846Eq31 TOTAL DEGRADED (MOISTURE) 1.569Eq31 SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.959E~1 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.677E~31 TOTAL DEGRADED (MOISTURE) 1.066E+00 TOTAL IN GROUNDWATER RUNOFF 1.300Eq31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.019E~38 ADSORBED SOIL (UG/G) 3.958E-10 SOIL AIR (UG/ML) 4.845Eq39 SOIL MOISTURE (UG/ML) 2.200E-08 ADSORBED SOIL (UG/G) 4.312E-10 SOIL AIR (UG/ML) 5.279Eq39 SOIL MOISTURE (UG/ML) 5.225E~39 ADSORBED SOIL (UG/G) 1.024E-10 SOIL AIR (UG/ML) 1.254E~9 SOIL MOISTURE (UG/ML) 1.839E~8 ADSORBED SOIL (UG/G) 3.605E-10 SOIL AIR (UG/ML) 4.413E~9 MAY, POLL DEPTH (M) 4.840E+01 YEAR - 90 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 16.633 3.648 0.051 12.227 ~.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 9.247E~31 2.881E~1 1.497Eq31 2.310Eq31 1.665E~31 8.747E~31 1.057E~31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.819E~8 ADSORBED SOIL (UG/G) 3.566E-10 SOIL AIR (UG/ML) 4.365Eq:)9 SOIL MOISTURE (UG/ML) 2.100E,08 ADSORBED SOIL (UG/G) 4.116E-10 SOIL AIR (UG/ML) 5.039E~39 SOIL MOISTURE (UG/ML) 2.025E-09 ADSORBED SOIL (UG/G) 3.969E-11 SOIL AIR (UG/ML) 4.860E-10 SOIL MOISTURE (UG/ML) 1.509E-08 ADSORBED SOIL (UG/G) 2.958E-10 SOIL AIR (UG/ML) 3.621E-09 MA~ POLL DEPTH (M) 4.840E+01 YEAR - 99 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 TOTAL PRECIPITATION (CM) 15.701 TOTAL INFILTRATION (CM) 15.633 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.051 TOTAL GRW RUNOFF (CM) 12.227 TOTAL MOISTURE RETENTION (CM) ~3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 8.777Eq31 2.806Eq31 1.426E~31 2.168E~31 1.363E~1 7.303Eq31 8.911E-02 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.727E~38 ADSORBED SOIL (UG/G) 3.384E-10 SOIL AIR (UG/ML) 4.143E-09 SOIL MOISTURE (UG/ML) 2.000E~:)8 ADSORBED SOIL (UG/G) 3.920E-10 SOIL AIR (UG/ML) 4.799E-09 SOIL MOISTURE (UG/ML) 1.900E~9 ADSORBED SOIL (UG/G) 3.724Eoll SOIL AIR (UG/ML) 4.559E-10 SOIL MOISTURE (UG/ML) 1.260Eq38 ADSORBED SOIL (UG/G) 2.470E-10 SOIL AIR (UG/ML) 3.023E~9 MAX. POLL DEPTH (M) 4.840E+01 ***** SESOIL-84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. UTTLE INC. ,(617)864-5'/70,X5871 ***** ***** J. WAGNER ,DIS/ADLPIPE, INC. ***** MODIFIED EXTENSIVELY BY: ***** D.M. HETRICK ***** OAK RIDGE NATIONAL LABORATORY ***** (615) 576-7556 ***** VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION ****** MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : TOLUENE WASHLOAD DATA : APPLICATION AREN ARCO 6218, BAKERSFIELD, CA - TOLUENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABIU~Y (CM**2): .100E~37 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E-01 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): .000 FREUNDLICH EXPONENT (-): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 535. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .830E~1 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .594E-02 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 331. ADSORPTION COEFFICIENT ON SOIL (10: .000 MOLECULAR WEIGHT (G/MOL): 92.1 VALENCE (-): .0(X) NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200Eq32 DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND-POLLUTANT STABlUTY CONSTANT (-): .000 NO. MOLES UGAND/MOLE POLLUTANT (-): .(XX) LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPUCATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 4 YEARS TO BE SIMULATED: 99 AREA (CM**2): 0.581E+06 APPMCATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPUCATION (0): 1 DEPTHS (CM): 0.11E+04 0.15E+03 0.24E+04 0.12E+04 NUMBER OF SUBLAYERS/LAYER 1 1 1 1 PH (CM): 7.0 7.0 7.0 7.0 INTRINSIC PERMEABlUTIES (CM**2): 0.10E~35 0.10E~38 0.10E~4 0.10Eq35 KDEL RATIOS (-): 1.0 1.0 1.0 KDES RATIOS (-): 1.0 1.0 1.0 OC RATIOS (-): 1.0 1.0 1.0 CEC RATIOS (-): 1.0 1.0 1.0 FRN RATIOS(-): 1.0 1.0 1.0 ADS RATIOS(-): 1.0 1.0 1.0 YEAR - I MONTHLY INPUT PARAMETERS - CUMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0.(XX) 0.0(X) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 REL HUM.(FRAC.) 0.000 0.000 0.(XX) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0(X) ALBEDO (-) 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1,420 1,980 2.620 2.540 2.640 1.550 0.740 0,200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0,140 0,330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0,510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 - POLLUTANT INPUT PARAMETERS - POL INP-1 (UG/CM**2) 2.00E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 TRNSFORMD~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINK~I (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 UG.INPUT-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+ 00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+00 0.00E + 00 VOLATILIZATION MULT.-1 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 SURFACE RUNOFF MULT. 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E+00 POL IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+ 00 0.00E+00 PO[. INP-2 (UG/CM**2) 1.70E+02 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 TRNSFORMI~2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+ 00 O.00E+00 O.00E+00 0.00E+00 O.00E+00 0.00E+ 00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+ 00 UG.INPUT-2 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.0OE+ 00 0.00E+00 VOLATIMZATION MULT.-2 1.00E+00 1.00E+ 00 1.00E+ 00 1.00E+00 1.00E+O0 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POI.. INP-3 (UG/CM**2) 6.51E + 02 O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+ O0 TRNSFORMD-3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS.-3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+ O00.OOE+O00.OOE+ O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 MG.INPUT-3 (UG/CM**2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT.-3 1.00E+ O0 1.00E+O0 1.00E+ O0 1.00E+O0 1.00E +00 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+ O0 1.00E+O0 1.00E+O0 POL INI~-L (UG/CM**2) O,OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE +00 O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 TRNSFORMD-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+ O00.OOE+O00.OOE+O00.OOE+O00.OOE + O00.OOE+ O00.OOE+O00.OOE+O0 O.OOE+ O00.OOE+O0 UG.INPUT-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE + O00.OOE+O00.OOE+O00.OOE + O00.OOE+O00.OOE+O00.OOE+O0 O.OOE +00 O.OOE+ O0 VOLATILIZATION MULT.-L 1.00E + O0 1.00E +00 1.00E+ O0 1.00E +00 1.00E+O0 1.00E +00 1.00E + O0 1.00E+ O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 YEAR - 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POL INP-1 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+ O0 TRNSFORMD-1 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O,OOE+O00.OOE+O00.OOE+O0 SINKS-1 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00,OOE+O00,OOE+O0 O.OOE+O00.OOE+O0 LIG.INPUT-1 (UG/CM**2) O.OOE+ O00.OOE+O00.OOE+ O00.OOE +00 O.OOE+O00.OOE+ O00.OOE+O00.OOE+ O00.OOE+ O00.OOE+O0 O.OOE+ O00.OOE +00 VOLATILIZATION MULT.-10.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 SURFACE RUNOFF MULT. O.OOE + O00.OOE + O00. OOE + O00.OOE +00 O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 POL. IN FINN (FRAC-SL) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+ O00.OOE+O0 POL INP-2 (UG/CM**2) O,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE +00 O.OOE+O0 TRNSFORMD-2 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS-2 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+ O0 O.OOE+O00.OOE+O0 UG.INPUT-2 (UG/CM**2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT.-2 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 POL INP-3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE +00 O.OOE+O00.OOE+O00.OOE+O00.OOE +00 O.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 TRNSFORMD-3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS..3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 . O.OOE+O00.OOE+O0 UG.INPUT-3 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-3 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POL. INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 VOLATlUZATION MULT.-L 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E+00 1.00E+00 YEAR - 3 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR -99 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR- 1 MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. INL1 (%) 11.219 11.279 11.450 11.729 11.939 12.119 12.059 11.849 11.549 11.279 11.039 10.889 MOIS. BELOWLI(%) 11.219 11,279 11.450 11.729 11.939 12,119 12.059 11.549 11.549 11.279 11.039 10.889 PREClPATION (CM) 0.841 1.480 2.082 2,646 2.582 2,631 1.605 0.815 0,247 0.156 0.138 0.417 NET INFILT. (CM) 0,839 1,480 2.082 2.646 2~562 2.631 1.605 0.809 0.210 0.149 0.131 0.417 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0,304 MOIS. RETEN (CM) ~3.363 0.242 0.726 1.089 0.847 0,726 ~.242 ~3,847 -1,210 -1.089 ~.956 ~3.605 SUR. RUNOFF (CM) 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.637 0.000 0.000 0.000 Gl:WV. RUNOFF (CM) 0.898 0.934 1.052 1.253 1.431 1.601 1,543 1.352 1.116 0.934 0.795 0.718 YIELD (CM) 0.900 0.934 1.002 1.253 1.431 1.601 1.543 1.358 1.163 0.941 0.799 0.718 PAU/MPA (GZU) PA/~MPA (GZ) 1.001 1.042 1.052 1.010 1.017 0.997 1.035 1.102 1.235 5.187 1.683 1.265 1.001 1.042 1.052 1.010 1.017 0.997 1.035 1.102 1.235 5.187 1.683 1.265 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. O.O00E+O00.O00E+O00.O00E+O00.O(X)E+O00.O00E+O00,O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 O.O00E+O00.O00E+O0 LOAD UPPER 1,162E+11 O.O00E+OOO.OOOE+O00.O00E+OOO.OOOE+OOO.OOOE+OOO.OOOE+O00.O00E+OOO.OOOE+OOO.OOOE+O0 O.O00E+O00.O00E+O0 L~AD Z~NE 2 9~877E + ~7 ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ O.O00E+O00.O00E+ O0 LOAD ZONE 3 3.782E + 08 O.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O(X)E + O00,O00E + O0 O.O00E+O00.O00E+O0 LOAD LOWER O.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.(ZX)E + O00.O00E + O00.O00E + O00.O00E + O0 O.O00E+O00.O00E +00 TOTAL INPUT 1.167E+ 11 O.(XX)E + O00.O00E + O00.O00E + O00.O(X)E + O00.O00E + O00.O00E + O00.O(X)E + O00.O00E + O00.O00E + O0 O.O00E+ O00.O(X)E+ O0 0 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 DEGRAD MOIS 2.238E + 09 2.250E + 09 2.286E + 09 2,340E + 09 2.382E + 09 2.417E + 09 2.405E + 09 2.384E + 09 2.304E + 09 2.250E + 09 2.202E+ 09 2.172E+09 IN SOIL MOl 3.730E+ 10 3.750E + 10 3.810E+ 10 3.899E + 10 3.969E+ 10 4.029E+ 10 4.009E+ 10 3.939E+ 10 3.840E+ 10 3.750E+ 10 3.670E+ 10 3.620E+ 10 ADS ON SOIL 2.972E + 10 2.972E + 10 2,972E + 10 2.972E + 10 2.972E + 10 2.972E + 10 2.972E + 10 2.972E + 10 2.972E + 10 2.972E + 10 2.972E+ 10 2.972E+ 10 IN SOIL AIR 1.648E+ 10 1.643E+ 10 1.627E+ 10 1.597E+ 10 1.578E+ 10 1.563E+ 10 1.576E+ 10 1,594E+10 1.621E+ 10 1.613E+10 1.633E+ 10 1.646E+ 10 PURE PHASE 3.019E+ 10 2.738E+ 10 2.407E+ 10 2.041E+ 10 1.679E+ 10 1.319E+ 10 1.035E+ 10 8.216E+09 6.519E+.09 5.145E+09 3.448E+09 1.495E+09 SOIL ZONE 2: SUBLAYER 1 DEGRAD MOIS 4.944E + 061.497E + 07 2.728E + 07 4.287E + 07 5.911E + 07 7.447E + 07 8,516E + 07 8.967E+ 07 8.971E + 07 8.837E + 07 · 8.651E+07 8,567E+07 IN SOIL MOl 1.582E+08 3.326E+08 5.629E+08 8.439E+08 1.104E+09 1.355E+09 1.483E+08 1.521E+09 1.495E+09 1.469E+09 1.436E+09 1.432E +09 ADS ON SOIL 1.261E+08 2.636E + 08 4.392E+ 08 6.433E + 08 8.2/1E +08 9.999E + 08 1.089E + 09 1.148E + 09 1.157E + 09 1.164E + 09 1.163E+09 1.176E+09 IN SOIL AIR 6.991E+07 1.457E+08 2.404E+08 3.456E+08 4.392E+08 5.257E+08 5.828E+08 6.156E+08 6.310E+08 6.317E+08 6.392E+08 6.513E+08 SOIL ZONE 3: SUBLAYER 1 DEGRAD MOIS 5.227E + 06 1.025E+ 07 1.098E + 071.278E + 07 1.562E+ 07 1.936E+ 07 2.274E + 07 2.465E + 07 2.515E + 07 2.508E+ 07 2.480E+07 2.484E+ 07 IN SOIL MOl 1.685E+08' 1.733E+08 1.920E+08 2.322E+08 2.863E+ 08 3.562E+08 4.025E+08 4.232E+08 4.219E+08 4.191E+08 4.136E+08 4.178E+08 ADS ON SOIL 1.343E+ 08 1.374E + 08 1.498E +08 1.770E + 08 2.144E + 08 2.628E + 08 2.984E + 08 3.194E + 08 3.266E + 08 3.322E + 08 3.350E+08 3.431E+08 IN SOIL AIR 7.444E+07 7.593E+07 8.200E+07 9.507E+07 1.139E+08 1.382E+08 1.582E+08 1.713E+08 1.781E+08 1.802E+08 1.841E+08 1.900E+08 LOWER SOIL ZONE: SUBLAYER I - POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 5,348E+02 5.348E+02 5.348E+02 5.348E+02 5.348E+02 5.348E+02 5.348E+02 5.348E+02 5.348E+02 5.348E+02 5.348E+02 5.348E+02 %SOLUBILrrY 1.000E+ 02 1 .(XX)E + 02 1.000E+02 1.000E+02 1.000E + 02 1.000E+02 1.000E+ 02 1.000E+ 02 1.000E+02 1.000E + 02 1.000E+02 1.000E + 02 ADSORBED 3.542E+01 3.542E+01 3.542E+01 3.542E+01 3.542E+01 3.542E+01 3.542E+01 3.542E+01 3.542E+01 3.542E+01 3.542E +01 3.542E+ 01 SOIL AIR 1.411E+02 1.411E+02 1.411E+02 1.406E+02 1.406E+02 1.406E+02 1.413E+02 1.413E+02 1.413E+02 1.386E+02 1.386E+ 02 1.386E+02 PURE PHASE 4.857E+01 4.404E+01 3.872E+01 3.283E+01 2.701E+01 2.121E+01 1.666E+01 1.322E+01 1.049E+01 8.276E+00 5.546E+00 2.404E+00 SOIL ZONE 2: SUBLAYER 1 MOISTURE 1.618E + 01 3.383E + 01 5.637E + 01 8.257E + 01 1.082E + 02 1.283E + 02 1 o411E + 02 1.473E + 02 1.486E + 02 1.494E + 02 1.493E+02 1.509E + 02 %SOLUBIUTY 3.026E+00 6.326E+00 1.054E+01 1.544E+01 1.985E+01 2.400E+01 2.638E+01 2.754E+ 01 2.778E+01 2.794E+01 2.791E+01 2.822E+ 01 ADSORBED 1.072E + 00 2.241E + 00 3.733E + 00 5.468E + 00 7.030E + 00 8.499E + 00 9.345E + 00 9.755E + 00 9.838E + 00 9.897E + 00 9.887E+00 9.995E+00 SOIL AIR 4.271E+00 8.929E+00 1.488E+.01 2.170E+01 2.790E+01 3.373E+01 3.728E+01 3.891E+01 3.924E+01 3.872E+01..;~.~ 3.868E+01 3.911E+01 SOIL ZONE 3: SUBLAYER 1 MOISTURE 1.077E+00 1.102E+00 1.202E+00 1.420E+00 1.720E+00 2,108E+00 2.394E+00 2.562E+00 2.620E+00 2,665E+00 · 2.687E+00 2.752E+00 %SOLUBIMTY 2.014E-01 2.061E-01 2.247E-01 2.654E-01 3.216E-01 3.942E-01 4.476E-01 4.TCJOE-01 4.898E-01 4.983E-01 5.025E-01 5.145E-01 ADSORBED 7.132E-02 7.299E-02 7.959E-02 9.401E-02 1.139E-01 1.396E-O1 1.585E-01 1.697E-O1 1.735E-01 1.765E-01 1.780E-O1 1.822E-01 SOIL AIR 2.842E-01 2.909E-01 3.172E.01 3.731E-01 4.521E-01 5.541E-01 6.323E-01 6.767E-01 6.920E-01 6.905E-01 6.962E-01 7.130E-01 LOWER SOIL ZONE: POL DEP CM 2.423E + 03 2.428E+ 03 2.434E + 03 2.442E + 03 2.450E + 03 2.458E + 03 2.464E + 03 2.468E + 03 2.471E+03 2.473E + 03 2.475E+03 2.477E+ 03 YEAR - 1 ANNUAL SUMMARY REPO~ - TOTAL INPUTS (UG) - UPPER SOIL ZONE 1.162E+ 11 SOIL ZONE 2 · 9.877E+07 SOIL ZONE 3 3.782E+08 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GFNV RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) 11.534 11.534 15.637 15.580 3.648 0.037 13.626 -1.694 13.683 TOTAL YIELD (CM) - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT I$ ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOII~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER I 2.761E+ 10 7.487 E + 08 2.215E+08 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.348E+02 ADSORBED SOIL (UG/G) 3.542E+01 SOIL AIR (UG/ML) 1.404E+02 PURE PHASE (UG/ML) 2.690E+02 SOIL MOISTURE (UG/ML) 1.092E+02 ADSORBED SOIL (UG/G) 7.230E+00 SOIL AIR (UG/ML) 2.861E+01 SOIL MOISTURE (UG/ML) 2.026E+00 ADSORBED SOIL (UG/G) 1.341E~31 SOIL AIR (UG/ML) 5.310E~1 MAX. POLL DEPTH (M) 2.477E+01 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 2.241E + 07 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 1.102E+09 1.560E+08 5.537E+08 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 2.135E+01 ADSORBED SOIL (UG/G) 1.414E+00 SOIL AIR (UG/ML) 5.608E+00 SOIL MOISTURE (UG/ML) 2.157E+01 ADSORBED SOIL (UG/G) 1.428E+00 SOIL AIR (UG/ML) 5.664E+00 SOIL MOISTURE (UG/ML) 4.813E+00 ADSORBED SOIL (UG/G) 3.188Eq)1 SOIL AIR (UG/ML) 1.264E+00 MA~ POLL DEPTH (M) 2.973E+01 YEAR - 20 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O(X)E+O0 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRVV RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.001 12.227 43.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOL, ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 5.353E+05 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER I 2.631E+07 3.725E + 06 4.008E + 07 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.098E431 ADSORBED SOIL (UG/G) 3.376E432 SOIL AIR (UG/ML) 1.339E431 SOIL MOISTURE (UG/ML) 5.149E431 ADSORBED SOIL (UG/G) 3.410E432 SOIL AIR (UG/ML) 1.352Eq31 SOIL MOISTURE (UG/ML) 3.474E431 ADSORBED SOIL (UG/G) 2.301E432 SOIL AIR (UG/ML) ~.124Eq32 MAY~ POLL DEPTH (M) 3.523E+01 · ;~'.~' YEAR - ~ ANNUAL SUMMARY REPO~ - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.001 12.227 ~3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIl~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.349E+00 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 2.465E+04 TOTAL DEGRADED (MOISTURE) 9.007E+04 SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.481E+04 TOTAL DEGRADED (MOISTURE) 1.701E+06 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 2.867E+05 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.231E-02 ADSORBED SOIL (UG/G) 8.151E-04 SOIL NR (UG/ML) 3.233E-03 SOIL MOISTURE (UG/ML) 1.254E~32 ADSORBED SOIL (UG/G) 8.304E~34 SOIL NR (UG/ML) 3,293E~33 SOIL MOISTURE (UG/ML) 1.472E~)2 ADSORBED SOIL (UG/G) 9.749E~34 SOIL NR (UG/ML) 3.866E~33 SOIL MOISTURE (UG/ML) 4.907E-03 ADSORBED SOIL (UG/G) 3.250E.04 SOIL AIR (UG/ML) 1.288E-03 MAX. POLL DEPTH (M) 4.038E+01 YEAR - ~ ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.(XX)E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~3.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOII~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.725E+04 1,340E+03 2,507E+03 1,208E+03 6.049E+04 2,479E+04 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.346E~34 ADSORBED SOIL (UG/G) 2.216Eq:)5 SOIL AIR (UG/ML) 8.787E-05 SOIL MOISTURE (UG/ML) 3.469E-04 ADSORBED SOIL (UG/G) 2.297E-05 SOIL AIR (UG/ML) 9.111E~5 SOIL MOISTURE (UG/ML) 5.234Eq34 ADSORBED SOIL (UG/G) 3.466E~5 SOIL AIR (UG/ML) 1.375E~4 SOIL MOISTURE (UG/ML) 4.231E~)4 ADSORBED SOIL (UG/G) 2.802E~5 SOIL AIR (UG/ML) 1.111E~)4 MAX, POLL DEPTH (M) 4.539E+01 YEAR - 50 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.(XX)E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRVV RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 q3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIl~ SOIL NR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 5.183E+02 5.303E+01 7.618E+01 5.207E+01 2.097 E + 03 3.341E+01 1.212E+03 1.479E + 02 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.006E~)5 ADSORBED SOIL (UG/G) 6.650Eq37 SOIL AIR (UG/ML) 2.641Eq36 SOIL MOISTURE (UG/ML) 1.054E~5 ADSORBED SOIL (UG/G) 6.982E~7 SOIL AIR (UG/ML) 2.769E~36 SOIL MOISTURE (UG/ML) 1.815E~5 ADSORBED SOIL (UG/G) 1.202Eq36 SOIL AIR (UG/ML) 4.766E~6 SOIL MOISTURE (UG/ML) 2.062E~:)5 ADSORBED SOIL (UG/G) 1.366E~6 SOIL AIR (UG/ML) 5.417E-06 MA)C POLL DEPTH (M) 4.840E+01 YEAR o 60 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.0(X)E+O0 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 TOTAL PRECIPITATION (CM) 15.701 TOTAL INRLTRATION (CM) 15.633 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.051 TOTAL GR~V RUNOFF (CM) 12.227 TOTAL MOISTURE RETENTION (CM) ~3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIl, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 1.630E+01 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.58OE+00 TOTAL DEGRADED (MOISTURE) 2.388E+00 SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) 2.013E+00 TOTAL DEGRADED (MOISTURE) 7.220E+01 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.174E+00 TOTAL DEGRADED (MOISTURE) 4.182E+01 TOTAL IN GROUNDWATER RUNOFF 5.103E+00 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 3.162E-07 ADSORBED SOIL (UG/G) 2.094E~8 SOIL AIR (UG/ML) 8.303E-08 SOIL MOISTURE (UG/ML) 3.307E~7 ADSORBED SOIL (UG/G) 2.190E-08 SOIL AIR (UG/ML) 8.686E~8 SOIL MOISTURE (UG/ML) 6.246E-07 ADSORBED SOIL (UG/G) 4.137E~8 SOIL AIR (UG/ML) 1.640E~37 SOIL MOISTURE (UG/ML) 7.117Eq37 ADSORBED SOIL (UG/G) 4.713E~38 SOIL AIR (UG/ML) 1.869E~37 MAX. POLL DEPTH (M) 4.840E+01 YEAR - ?0 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 11.364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS OISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 2.020E+00 5.940E-01 3.225E-01 2.457E+00 1.367E-01 1.844E+00 2.252E-01 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 3.964E-08 ADSORBED SOIL (UG/G) 2.625E~9 SOIL AIR (UG/ML) 1.041E~8 SOIL MOISTURE (UG/ML) 4.525E-08 ADSORBED SOIL (UG/G) 2.997E~9 SOIL AIR (UG/ML) 1.188E~8 SOIL MOISTURE (UG/ML) 2.140E-08 ADSORBED SOIL (UG/G) 1.417E-09 SOIL AIR (UG/ML) 5.620E-09 SOIL MOISTURE (UG/ML) 3.178E~8 ADSORBED SOIL (UG/G) 2.105E-09 SOIL AIR (UG/ML) 8.344E~9 MAX. POLL DEPTH (M) 4.840E+01 YEAR - 80 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2' O.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0,051 12.227 -0.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 1.433E+00 1.925E-01 1.645E + 00 1.694E-01 1.575E + 00 1.924E-01 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 2.819E~8 ADSORBED SOIL (UG/G) 1.867E-09 SOIL AIR (UG/ML) 7.40OE~9 SOIL MOISTURE (UG/ML) 2.700E-08 ADSORBED SOIL (UG/G) 1.788E-09 SOIL AIR (UG/ML) 7.088E~9 SOIL MOISTURE (UG/ML) 1.443E~8 ADSORBED SOIL (UG/G) 9.553E-10 SOIL NR (UG/ML) 3.787E-09 SOIL MOISTURE (UG/ML) 2.717E-08 ADSORBED SOIL (UG/G) 1.800E~9 SOIL NR (UG/ML) 7.134E~9 MA)C POLL DEPTH (M) 4.840E+01 YEAR - 90 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.(XX)E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GFIW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAJ. YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 11.364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 1.270E+00 3.517E-02 1.8OOE-01 1.123E+00 1.680E-01 1.304E+00 1.593E-01 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.497E~8 ADSORBED SOIL (UG/G) 1.654E~9 SOIL AIR (UG/ML) 6.556E-09 SOIL MOISTURE (UG/ML) 2.525E-08 ADSORBED SOIL (UG/G) 1.672E-09 SOIL AIR (UG/ML) 6.629E-09 SOIL MOISTURE (UG/ML) 9.850E~9 ADSORBED SOIL (UG/G) 6.523E-10 SOIL AIR (UG/ML) 2.586E~9 SOIL MOISTURE (UG/ML) 2.249E-08 ADSORBED SOIL (UG/G) 1.490E-09 SOIL AIR (UG/ML) 5.904E~39 MAX~ POLL DEPTH (M) 4.840E+01 YEAR - 99 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.(XX)E+00 SOIL ZONE 3 0.(XX)E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 q3.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIl~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 1.088E+00 1,717Eq31 1,640E~1 5.723E~1 1,829Eq31 1,089E+00 1,330E~31 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.139E-O8 ADSORBED SOIL (UG/G) 1.417E-09 SOIL AIR (UG/UL) 5.615E-O9 SOIL MOISTURE (UG/ML) 2.300E-08 ADSORBED SOIL (UG/G) 1.523E-O9 SOIL NR (UG/ML) 6.038E-O9 SOIL MOISTURE (UG/ML) 5.017E-09 ADSORBED SOIL (UG/G) 3.322E-10 SOIL AIR (UG/ML) 1,317Eq39 SOIL MOISTURE (UG/ML) 1.878Eq38 ADSORBED SOIL (UG/G) 1.244E~9 SOIL AIR (UG/ML) 4.931E-09 MAX. POLL DEPTH (M) 4.840E+01 ***** SESOIL-84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. MTTLE INC. ,(617)864-5770,X5871 ***** ***** J. WAGNER ,DIS/ADLPIPE, INC. *****MODIFIED EXTENSIVELY BY: *****D.M. HETRICK ***** OAK RIDGE NATIONAL LABORATORY ***** (615) 576-7556 ***** VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION ****** MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : ETHYLBENZENE WASHLOAD DATA : APPLICATION AREN ARCO 6218, BAKERSFIELD, CA - ETHYLBENZENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .100Eq37 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .200E~)1 CATION EXCHANGE CAPACITY (MILU EQ./100G DRY SOIL): .000 FREUNDLICH EXPONENT (-): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBlUTY (UG/ML): 161. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .760E~1 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .844E~1 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 871. ADSORPTION COEFFICIENT ON SOIL (10: .000 MOLECULAR WEIGHT (G/MOL): 106. VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200E~32 DEGRADATION RATE ON SOIL (/DAY): .000 MGAN~POLLUTANT STABIUTY CONSTANT (-): .000 NO. MOLES UGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .(XX) - APPUCATION INPUT pARAMETERS - NUMBER OF SOIL LAYERS: YEARS TO BE SIMULATED: AREA (CM**2): APPLICATION AREA LATITUDE (DEG.): SPILL (1) OR STEADY APPUCATION (0): DEPTHS (CM): NUMBER OF SUBLAYERS/LAYER PH (CM): INTRINSIC PERMEABIETIES (CM**2): KDEL RATIOS (-): KDES RATIOS (-): OC RATIOS (-): CEC RATIOS (-): FRN RATIOS(-): ADS RATIOS(-): 4 O.~IE+~ ~.0 1 0.11E+~ 0.15E+~ 0.24E+~ 0.12E+~ I I 1 1 7.0 7.0 7.0 7.0 0.10E-O50. lOE-OSO, lOE-O40, lOE-05 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 YEAR - 1 MONTHLY INPUT PARAMETERS = ~..~ _-- _..~ = ~ == = ======================== - CUMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 · 0.000 0.000 0.000 REL. HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 0.000 0.0(X) 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.320 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 20.400 20.400 30.400 20.400 30.400 - POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 6.39E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 UG.INPUT-1 (UG/CM**2) 0.00E +00 0.00E +00 0.00E + 00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E +00 0.00E + 00 VOLATILIZATION MULT.-1 ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 O.00E+ 00 SURFACE RUNOFF MULT. O.OOE + O00.OOE + O00.OOE + O00.OOE +00 O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00'OOE + O0 0.00E+00 0.00E+00 POL. IN RNN (FRAC-SL) 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.0OE+00 PO[-. INP.2 (UG/CM**2) 3.30E+01 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) O.00E+00 0.00E +00 O.00E+ 00 0.00E +CX) O.00E+ 00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E+00 UG.INPUT-2 (UG/CM**2) 0.OOE + 00 0.00E + 00 0.00E + 00 0.00E + 00 O.00E + 00 0.00E + 00 0.00E + 00 0.0OE + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+ 00 1.00E+00 1.00E+00 1.00E+ 00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 PO[.. INP-3 (UG/CM**2) 9.42E+01 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-3 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E +00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-3 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+ 00 1.00E+00 1.00E+00 1.00E+00 POL. INP-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 O.00E+00 0.00E+00 O.OOE+O00.OOE+O00.OOE+O0 SINKS..L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 MG.INPUT-L (UG/CM**2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE+ O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT.-L 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+ O0 1.00E+ O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 YEAR - 3 MONTHLY INPUT PARAMETERS _..~ ~..~ ~ ~ ~_~ = .~-- = ======================== - CUMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR -99 MONTHLY INPUT PARAMETERS = __. _.~ ~,.~ _.= _-- ~.~ _.~ ======================== - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - 1 MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. INL1 (%) 11.219 11.279 11.459 11.729 11.939 12.119 12.059 11.849 11.549 11.279 11.039 10.889 MOIS. BELO~NLI(%) 11.219 11.279 11.459 11.729 11.939 12.119 12.059 11.849 11.549 11.279 11.039 10.889 PRECIPATION (CM) 0.841 1.480 2.082 2.646 2.582 2.631 1.605 0.815 0.247 0.156 0.135 0.417 NET INFILT. (CM) 0.839 1.480 2.082 2.646 2.582 2.631 1.605 0.809 0.210 0.149 0.131 0.417 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) -0.363 0.242 0.726 1.089 0.847 0.726 -0.242 -0.847 -1.210 -1.089 -0.968 -0.605 SUR. RUNOFF (CM) 0.500 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.637 0.000 0.000 0.000 GRW. RUNOFF (CM) 0.898 0.934 1.052 1.263 1.431 1.601 1.543 1.352 1.116 0.934 0.795 0.718 YIELD (CM) 0.900 0.934 1.052 1.253 1.431 1.601 1.543 1.358 1.153 0.941 0.799 0.718 PAU/MPA (GZU) 1.001 1.042 1.052 1.010 1.017 0.997 1.035 1.102 1.235 5.187 1.683 1.265 PA/MPA(GZ) 1.001 1.042 1.052 1.010 '1.017 0.997 1.035 1.102 1.235 5.187 1.683 1.265 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+ 00 LOAD UPPER 3.713E+ 10 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.CX)0E+00 0.000E+00 O.O00E +00 O.O00E+ O0 LOAD ZONE 2 1.917E + 07 O.O00E + O00.O(X)E + O00.O(X)E + O00.O00E + O00.O00E + O00.O00E + O00'O00E + O00'O(X)E + O00'O00E + O0 O.O00E+OO'O.OOOE+ O0 LOAD ZONE 3 5.473E + 07 O.O00E + O00.O00E + O0 0.005E + O00.O00E + O00.O00E + O00.O00E + O00.O(X)E + 050'O(X)E + O00'O00E + O0 0.000E+00 0.000E+00 LOAD LOWER 0.000E+000.0(X)E+00 0.000E+000.000E+000.000E+000.000E+00 0.000E+000.000E+000'000E+000'000E+00 0.000E+ 00 0.000E+00 TOTAL INPUT 3.720E + 10 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.0(X)E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 O.O00E+O00.O00E+O0 0 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 DEGRAD MOIS 2.367E + 08 2.366E + 08 2.396E + 08 2.456E + 08 2.491E + 08 2.517E + 08 2.471E + 08 2'395E + 08 2'298E + 08 2'242E + 08 2.166E+ 08 2.115E+08 IN SOIL MOl 3.932E+09 3.929E+09 3.978E+09 4.075E+09 4.133E+09 4.177E+09 4.101E+09 3.976E +09 3.818E+09 3.725E+09 3.599E+ 09 3.513E+09 ADS ON SOIL 8.242E + 09 8.192E+ 09 8.163E+09 8.170E+ 09 8.141E+09 8.105E+09 7.997E + 09 7.891E+09 7.774E + 09 7.756E + 09 7.667E+09 7.567E+09 IN SOIL AIR 2.469E+ 10 2.446E+ 10 2.414E+ 10 2.371E + 10 2.335E+ 10 2.302E+ 10 2.290E+ 10 2.286E+ 10 2.290E+ 10 2.276E+ 10 2.276E+ 10 2.270E+ 10 ,~ SOIL ZONE 2: SUBLAYER 1 DEGRAD MOIS 1.554E+05 4.471E+057.925E+ 05 1.265E+ 05 1.789E + 06 2.323E + 06 2.699E+ 06 2.868E + 06 2.879E + 06 2.876E+ 06 2.832E+06 2.831E+ 06 IN SOIL MOl 5.001E+06 9.696E+06 1.628E+ 07 2.501E+07 3.372E+07 4.272E+07 4.747E+07 4.911E+07 4.844E+ 07 4.825E+07 4.744E+07 4.769E+07 ADS ON SOIL 1,048E+ 07 2.022E + 07 3.341E+07 5.015E+ 07 6.643E + 07 8.290E + 07 9.258E + 07 9,748E+ 07 9.864E+ 07 1.006E + 08 1,011E+08 1.030E+08 IN SOIL AIR 3.140E+07 6.035E+07 9.877E+07 1,455E+08 1.905E+08 2.354E+08 2,651E+08 2.824E+08 2.905E+08 2.949E+08 3.(XX)E + 08 3.082E+ 08 SOIL ZONE 3: SUBLAYER 1 DEGRAD MOIS 1.600E + 05 3.,~30E + 05 3.0~4E + 05 3.8~.E + 05 4.175E + 05 4.,~.3E + 05 4.784E + Off 4.8~E + 05 4.706E + 0S 4.751E + 05 4.650E+ 05 4.611E+05 IN SOIL MOl 5.833E+06 5,899E+06 6.135E+06 6.608E+06 7,158E+06 7.845E+06 8.175E+ 06 8.223E+06 8.032E+06 7.945E+06 7.769E+06 7,734E+06 ADS ON SOIL 1.223E + 07 1.230E + 07 1.259E + 07 1.325E +07 1.410E+07 1.522E+ 07 1.594E + 07 1.632E + 07 1,636E + 07 1.657E + 07 1,655E+07 1,670E+07 IN SOIL NR 3.662E+07 3.672E+07 3.722E+07 3.845E+07 4.045E+07 4,323E+07 4.565E+07 4.728E+07 4.817E+07 4.855E+07 4.913E+07 4.997E+07 LOWER SOIL ZONE: SUBLAYER 1 - POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 5.638E+01 5.604E+01 5.584E+01 5.589E+01 5.569E+01 5.544E+01 5.470E+01 5.398E+01 5.317E+01 5.312E+01 5.245E+01 5.190E+01 %SOLUBIUTY 3,502E+ 01 3.481E+01 3,468E+01 3.471E+01 3,459E +01 3.443E+ 01 3.398E +01 3.353E+01 3.303E+01 3.299E+ 01 3.258E+01 3.223E+01 ADSORBED 9,821E + 00 9.761E + 00 9.727E + 00 9.735E + 00 9.701E + 00 9,657E + 00 9.529E + 00 9.403E + 00 9.263E + 00 9,253E + 00 9,136E+00 9.04OE+00 SOIL AIR 2.114E+02 2.101E+02 2.094E+02 2,067E+02 2,080E+02 2.071E+02 2,053E+02 2.026E+02 1.996E+02 1.956E+02 1.931E+02 1.911E+02 SOIL ZONE 2: SUBLAYER 1 MOISTURE 5.115E-01 9.864E~1 1.630E+00 2.447E+00 3,241E+00 4.045E+00 4.517E+00 4.756E+00 4.813E+00 4.909E+00 4,932E+00 5.026E+00 %SOLUBLES( 3.177E-01 6.127E~31 1,012E+00 1.520E+00 2.013E+00 2.513E+00 2.806E+00 2.954E+00 2.990E+00 3.049E+00 3.063E+ 00 3.122E+ 00 ADSORBED 8,910Eq32 1.718Eq31 2.839E~31 4.262E~1 5.646E~1 7.047Eq31 7.869E~1 8.285E~31 8,384E-01 8.551E~31 8.590E~1 8.755E~31 SOILAIR 1.918E+003,699E+006.113E+009.138E+00 1.211E+01 1.511E+01 1,696E+01 1.785E+01 1.807E+01 1.807E+01 1.816E+01 1.850E+01 SOIL ZONE 3: SUBLAYER 1 MOISTURE 3.729E~32 3.751E432 3,839E432 4,041E432 4.300E~32 4.642E~)2 4.862E432 4.977E432 4.988E~32 5,052E~32 5.047E432 5.094E-02 %SOLUBlUTY 2,316E~2 2.330E-02 2.385E~32 2.510E-02 2.671E~2 2,884Eq32 3.020E-02 3,091E-02 3.098E~2 3.138E~32 3.135E432 · 3,164E~32 ADSORBED 8.873E-03 SOIL NR 1.875E-01 6.495E-03 6.5,'.'.'.'.'.'.'.'.'~.E-03 6.688E-03 7.039E-03 7.490E-03 8.087E-03 8.469E-03 8.670E-03 8.689E-03 8.800E-03 8.792E-03 1.398E-01 1.407E-01 1.440E-01 1.509E-01 1.606E-01 1.734E-01 1.825E-01 1.868E-01 1.872E-01 1.860E-01 1.858E-01 LOWER SOIL ZONE: POL DEP CM 2.421E+03 2.422E + 03 2.423E + 03 2.425E +03 2.427E+ 03 2.429E + 03 2.431 E+03 2.432E + 03 2.433E + 03 2.433E + 03 2.434E+03 2.434E+03 YEAR - 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 3.713E+ 10 SOIL ZONE 2 1.917E+07 SOIL ZONE 3 5.473E+07 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.534 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 11.534 TOTAL PRECIPITATION (CM) 15.637 TOTAL INFILTRATION (CM) 15.580 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.037 TOTAL GRW RUNOFF (CM) 13.626 TOTAL MOISTURE RETENTION (CM) -1.694 TOTAL YIELD (CM) 13.683 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 2.828E+09 2.376 E + 07 5.004E+06 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.455E+01 ADSORBED SOIL (UG/G) 9.502E+00 SOIL AIR (UG/ML) 2.035E+02 SOIL MOISTURE (UG/ML) 3.485E+00 ADSORBED SOIL (UG/G) 6.070E~31 SOIL NR (UG/ML) 1.297E+01 SOIL MOISTURE (UG/ML) 4.527E~)2 ADSORBED SOIL (UG/G) 7.885E~33 SOIL AIR (UG/ML) 1.688E~1 MA)L POLL DEPTH (M) 2.434E+01 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.(XX)E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER I 1,208E+09 1.077E + 08 6.040E + 07 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 2.366E+01 ADSORBED SOIL (UG/G) 4.121E+00 SOIL AIR (UG/ML) 8.825E+01 SOIL MOISTURE (UG/ML) 1.508E+01 ADSORBED SOIL (UG/G) 2.627E+00 SOIL AIR (UG/ML) 5.626E+01 SOIL MOISTURE (UG/ML) 5.309E~31 ADSORBED SOIL (UG/G) 9.248E~)2 SOIL AIR (UG/ML) 1.980E+00 MAX. POLL DEPTH (M) 2.554E+01 YEAR - 20 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIl~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER I 4.772E+08 6.251E+07 8.196E+07 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 9.346E+00 ADSORBED SOIL (UG/G) 1.628E+00 SOIL AIR (UG/ML) 3.486E+01 SOIL MOISTURE (UG/ML) 8.739E+00 ADSORBED SOIL (UG/G) 1.522E+00 SOIL AIR (UG/ML) 3.260E+01 SOIL MOISTURE (UG/ML) 7.179E-01 ADSORBED SOIL (UG/G) 1.250E-01 SOIL AIR (UG/ML) 2.678E+00 MAX. POLL DEPTH (M) 2.688E+01 YEAR - 30 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+ 00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE O.000E+00 TOTAL PRECIPITATION (CM) TOTAL INRLTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 4.222E+06 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER I 1.920E+08 2.694E+07 6.403E+07 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 3.760E+00 ADSORBED SOIL (UG/G) 6.550E~31 SOIL NR (UG/ML) 1.403E+01 SOIL MOISTURE (UG/ML) 3.763E+00 ADSORBED SOIL (UG/G) 6.556E~31 SOIL NR (UG/ML) 1.404E+01 SOIL MOISTURE (UG/ML) 5.602E~1 ADSORBED SOIL (UG/G) 9.758E~2 SOIL AIR (UG/ML) 2.090E+00 MAY~ POLL DEPTH (M) 2.822E+01 YEAR - 40 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+05 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) AVERAGE SOIL MOISTURE BELOW ZONE I (%) TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) 11.364 11.364 15.701 15.633 3.648 0.051 12.227 ~).242 12.295 TOTAL YIELD (CM) - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.689E+05 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: 7.744E + 07 1.057E+07 4.004E+07 SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.517E+00 ADSORBED SOIL (UG/G) 2.642E~1 SOIL AIR (UG/ML) 5.657E+00 SOIL MOISTURE (UG/ML) 1.518E+00 ADSORBED SOIL (UG/G) 2.644E~1 SOIL AIR (UG/ML) 5.662E+00 SOIL MOISTURE (UG/ML) 3.501E-01 ADSORBED SOIL (UG/G) 6.098E~2 SOIL AIR (UG/ML) 1.306E+00 MAX. POLl. DEPTH (M) 2.955E+01 YEAR - 50 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE O.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11,364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl.,' ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 3.122E+07 6.870E + 05 4.381E+06 2.255 E + 07 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 6.115E-01 ADSORBED SOIL (UG/G) 1,065E-01 SOIL AIR (UG/ML) 2.281E+00 SOIL MOISTURE (UG/ML) 6.120E-01 ADSORBED SOIL (UG/G) 1.056E-01 SOIL AIR (UG/ML) 2.283E+00 SOIL MOISTURE (UG/ML) 1.971E-01 ADSORBED SOIL (UG/G) 3.433E-02 SOIL AIR (UG/ML) 7.352E-01 MAX. POLL DEPTH (M) . 3.089E+01 ....... YEAR - 60 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 q3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIl, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 2.776E+05 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER I 1.263E+07 1.772E+06 1.193E+07 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 2.473E-01 ADSORBED SOIL (UG/G) 4.308Eq32 SOIL AIR (UG/ML) 9.226E~31 SOIL MOISTURE (UG/ML) 2.475E~31 ADSORBED SOIL (UG/G) 4,312E~32 SOIL AIR (UG/ML) 9,234E-01 SOIL MOISTURE (UG/ML) 1.043E~31 ADSORBED SOIL (UG/G) 1.817E~32 SOIL AIR (UG/ML) 3.891Eq~1 MAX. POLL DEPTH (M) 3.222E+01 YEAR - 70 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 O.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11,364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.075E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.130E+05 TOTAL DEGRADED (MOISTURE) 7,120E+05 SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.148E+06 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 9.938E-02 ADSORBED SOIL (UG/G) 1.731E-02 SOIL AIR (UG/ML) 3.707E-01 SOIL MOISTURE (UG/ML) 9.946E-02 ADSORBED SOIL (UG/G) 1.733E-02 SOIL AIR (UG/ML) 3.710E-01 SOIL MOISTURE (UG/ML) 5.373E-02 ADSORBED SOIL (UG/G) 9.359E-03 SOIL AIR (UG/ML) 2.004E-01 MA~ POLL DEPTH (M) 3.356E+01 YEAR - 80 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E + O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 4.540E+04 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 2.056E+05 2.885E + 05 3.083E+06 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 4.026E~2 ADSORBED SOIL (UG/G) 7.014E~:)3 SOIL AIR (UG/ML) 1.502E-01 SOIL MOISTURE (UG/ML) 4.030E~2 ADSORBED SOIL (UG/G) 7.019E~3 SOIL AIR (UG/ML) 1.503E~1 SOIL MOISTURE (UG/ML) 2.694E~2 ADSORBED SOIL (UG/G) 4.692E-03 SOIL AIR (UG/ML) 1.005E~1 MAX. POLL DEPTH (M) 3.489E+01 YEAR - 90 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E + 00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.001 12.227 ~3.242 12.295 -.POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 8.296E+05 1.821E+04 1.164E+05 1.510E+00 TOTAL DEGRADED (MOISTURE) 5.554E+02 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.625E~2 ADSORBED SOIL (UG/G) 2.830E~33 SOIL AIR (UG/ML) 6.001E~32 SOIL MOISTURE (UG/ML) 1.626E~)2 ADSORBED SOIL (UG/G) 2.832E-03 SOIL AIR (UG/ML) 6.006E~2 SOIL MOISTURE (UG/ML) 1.320E~)2 ADSORBED SOIL (UG/G) 2.298E~33 SOIL AIR (UG/ML) 4.922E432 SOIL MOISTURE (UG/ML) 1.144Eq35 ADSORBED SOIL (UG/G) 1.992E~36 SOIL AIR (UG/ML) 4.232E-05 MA~ ROLL DEPTH (M) 3.624E+01 YEAR - 99 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 ' SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) AVERAGE SOIL MOISTURE BELOW ZONE I (%) TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) 11.364 11.364 15.701 15.633 3.648 0.001 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOII~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.660E+05 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 8.049E+03 TOTAL DEGRADED (MOISTURE) 5.135E+04 SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 7.531E+05 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 3.462E+04 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 SOIL MOISTURE (UG/ML) 7.167E-03 ADSORBED SOIL (UG/G) 1.248E~3 SOIL AIR (UG/ML) 2.674E-02 SOIL MOISTURE (UG/ML) 7.173E-03 ADSORBED SOIL (UG/G) 1.249E~3 SOIL AIR (UG/ML) 2.676E-02 SOIL MOISTURE (UG/ML) 6.578E~3 ADSORBED SOIL (UG/G) 1.146E~3 SOIL AIR (UG/ML) 2.454E-02 SOIL MOISTURE (UG/ML) 5.976E-04 ADSORBED SOIL (UG/G) 1.041E-04 SOIL NR (UG/ML) 2.229E~3 MA)C POLL DEPTH (M) 3.734E+01 LOWER SOIL ZONE: SUBLAYER I ************************************************ COMPLETED**************************************** ***** SESOIL-84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. LITTLE INC. ,(617)864-5770,X5871 ***** ***** J. WAGNER ,DIS/.~OL~IPE, INC. ,(617)492-1~01,X~--~ ***** ***** MODIFIED EXTENSIVELY BY: ***** D.M. HETRICK ***** ***** OAK RIDOE N~TION~ I.~OI~TORY **~* ***** (615) 576-7556 ***** ***** VERSION : SEPTEMBER 1986 ***** ****** MONTHLY SESOIL MODEL OPERATION ****** MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : 1,2-XYLENE WASHLOAD DATA : APPLICATION AREN ARCO 6218, BAKERSFIELD, CA - BENZENE WARNING- SOIL PERMEABlUTY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .100E~7 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .3(X) ORGANIC CARBON CONTENT (%): .200E~)1 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): .000 FREUNDLICH EXPONENT (-): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 175. DIFFUSION COEFFICIENT IN NR (CM**2/SEC): .760E-01 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .510E~)2 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 871. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): ' 106. VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .200Eq32 DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND~POLLUTANT STABIMTY CONSTANT (-): .000 NO. MOLES UGAND/MOLE POLLUTANT (-): .0(X) LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPUCATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: YEARS TO BE SIMULATED: AREA (CM**2): APPMCATION AREA LATITUDE (DEG.): SPILL (1) OR STEADY APPUCATION (0): DEPTHS (CM): NUMBER OF SUBLAYERS/LAYER PH (CE): INTRINSIC PERMEABIMTIES (CM**2): KDEL RATIOS (-): KDES RATIOS (-): OC RATIOS (-): CEC RATIOS (-): FRN RATIOS(-): ADS RATIOS(-): 4 0.~IE+~ ~.0 1 0.11E+~ 0.15E+~ 0.24E+~ 0.12E+~ I 1 I 1 7.0 7.0 7.0 7.0 0.10E4)50.10E-080.10E~40.10E4)5 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 YEAR - 1 MONTH~ INPUT PARAMETERS - CUMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL ' AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0.000 0.(XX) 0.000 0.000 0.000 0.000 0.000 0.000 0.0(X) CLOUD CVR (FRAC.) 0.000 0.(XX) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.(XX) REL HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 O.(XX) 0.000 0.000 0.000 ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PREClP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (o) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 20.400 30.400 20.400 20.400 20.400 30.400 30.400 30.400 30.400 - POLLUTANT INPUT PARAMETERS - POI- INP-1 (UG/CM**2) 4.30E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E+ 00 0.0OE +00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E +00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E +00 SURFACE RUNOFF MULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E+ 00 POI- IN RNN (FRAC~SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.OOE+00 POi- INP-2 (UG/CM**2) 2.27E+02 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E+00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 VOLATILIZATION MULT,-2 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 POL INP-3 (UG/CM**2) 6.67E+02 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E +00 0.00E+00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-3 (UG/CM**2) 0.00E +00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+ 000~.00E + 00 0.00E+00 0.00E +00 0.00E+ 00 0.00E+00 VOLATIMZATION MULT.-3 1.00E + 00 1.00E + 00 1.00E + 00 1.00E + 00 1.00E+ 00 1.00E + 00 1.00E + 00 1.00E+00 1.00E + 00 1.00E + 00 1.00E+00 1.00E+00 POL INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+O00.OOE+O00.OOE+O0 SINKS-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 MG.INPUT-L (UG/CM**2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULTo-L 1.00E+O0 1.00E+O01.00E+O0 1.00E+ O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 YEAR - 2 MONTHLY INPUT PARAMETERS - CUMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS - POI- INP-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 O.0OE+O0 0.00E+00 0.00E+00 0.00E+OO 0.00E+00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 LIG.INPUT-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 VOLATIMZATION MULT.-1 0.00E + 00 0.00E + O0 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 O.00E + 00 0.00E + 00 0.0OE + 00 0.00E+00 0.00E+00 SURFACERUNOFF MULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E +00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 POL. INP-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 - LIG.INPUT-2 (UG/CM**2) 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POL INP-3 (UG/CM**2) 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-3 (UG/CM**2) 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 LIG.INPUT-3 (UG/CM**2) 0.00E + 00 0.00E + O0 0.0OE + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.00E + 00 0.00E+00 0.00E +00 VOLATILIZATION MULT.-3 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POL INP-L (UG/CM**2) 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-L (UG/CM**2) 0.00E+00 O.00E +00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-L 1.00E + 00 1.00E +.00 1.00E + 00 1.00E+00 1.00E + 00 1.00E+ 00 1.00E+ 00 1.00E + 00 1.00E+00 1.00E+00c ,,;~7 1.00E+00 1.00E+00 YEAR - 3 MONTHLY INPUT PARAMETERS - CUMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR -99 MONTHLY INPUT PARAMETERS - CUMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - 1 MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. INL1 (%) 11.219 11.279 11.459 11.729 11.939 12.119 12.059 11.849 11.549 11.279 11.039 10.889 MOIS. BELOWLI(%) 11.219 11.279 11.459 11.729 11.939 12.119 12.059 11.849 11.549 11.279 11.039 10.889 PREClPATION (CM) 0.841 1.480 2.082 2.646 2.582 2.631 1.605 0.815 0.247 0.156 0.135 0.417 NETINFILT. (CM) 0.639 1.480 2.082 2.646 2.582 2.631 1.605 0.809 0.210 0.149 0.131 0.417 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) -0.363 0.242 0.726 1.089 0.847 0.726 -0.242 -0.847 -1.210 -1.089 -0.968 -0.605 SUR. RUNOFF (CM) 0.000 0.000 0.000 0.000 0.000 0.005 0.000 0.000 0.007 0.000 0.000 0.000 Gl=NV. RUNOFF (CM) 0.898 0.934 1.052 1.2,53 1.431 1.601 1.543 1.352 1.116 0.9,.'.'.'.'.'.'.'.'.~, 0.795 0.718 YIELD (CM) 0.900 0.934 1.052 1.253 1.431 1.601 1.543 1.358 1.153 0.941 0.799 0.718 PAU/MPA (GZU) PA/MPA (GZ) 1.001 1.042 1.052 1.010 1.017 0.997 1.035 1.102 1.235 5.187 1.683 1.265 1.001 1.042 1.052 1.010 1.017 0.997 1.035 1.102 1.235 5.187 1.683 1.265 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.CXX)E+00 0.000E +00 0.000E+ 00 LOAD UPPER 2.498E+ 11 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+ 00 0.000E+00 LOAD ZONE 2 1.319E + 08 0.000E + 00 0.0(X)E + 00 0.0(X)E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 O.O00E+O0 0.000E+00 LOAD ZONE 3 3,875E + 08 O,O00E + O00,O00E + O00.O00E + O00.O(X)E + O00,O00E + O00.O00E + O00,O00E + O00.O(X)E + O00.O00E + O0 0.000E+ 00 0.0(X)E+00 LOAD LOWER ~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~(x)E+~~~~~~~E+~~~~~xx)E+~~~~~~~E+~~ O.O00E+ O00.O00E+O0 TOTAL INPUT 2.503E + 11 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.0(X)E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+00 0.000E+00 0 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 DEGRAD MOIS 7.323E + 08 7.352E + 08 7.480E + 08 7.656E + 08 7.793E + 08 7.910E + 08 7.871E + 08 7.734E + 08 7.538E+ 08 7.352E + 08 7.205E+08 7.108E+08 IN SOIL MOl 1.220E+ 10 1.227E+ 10 1.247E + 10 1.276E+ 10 1.299E+ 10 1.318E+ 10 1.312E+ 10 1.289E+ 10 1.256E+ 10 1.227E+ 10 1.201E+ 10 1.185E+ 10 ADS ON SOIL 2.558E + 10 2.558E + 10 2.556E + 10 2.558E + 10 2.558E + 10 2.558E + 10 2.558E + 10 2.558E + 10 2.558E + 10 2.558E + 10 2.558E+ 10 2.558E+ 10 IN SOIL AIR 4.630E+09 4.615E+09 4.571E+09 4.486E+09 4.435E+09 4.390E+09 4.427E+09 4.479E+09 4.553E+ 09 4.531E+09 4.589E+09 4.625E+09 PURE PHASE 2.066E+ 11 2.057E+ 11 2.046E+ 11 2.034E+ 11 2.022E+ 11 2.010E+ 11 2.001E+ 11 1.994E+ 11 1.988E+ 11 1.984E+ 11 1.978E + 11 1.972E+ 11 SOIL ZONE 2: SUBLAYER I DEGRAD MOIS 1.927E+ 06 4.870E + 06 7.531E + 061.100E+071.471E+071.833E+ 07 2.092E +07 2.208E + 07 2.219E + 07 2.195E+ 07 2.161E+07 2.153E+07 IN SOIL MOl 6.184E+07 9.876E+07 1.490E+08 2.122E+08 2.726E+ 08 3.326E+08 3.647E+08 3.757E+08 3.713E+08 3.663E+08 3.602E +08 3.611E+08 ADS ON SOIL 1.296E + 08 2.059E + 08 3.058E + 08 4.254E + 08 5.370E + 08 6.455E + 08 7.113E + 08 7.456E + 08 7.561E + 08 7.637E + 08 7.674E+08 7.799E+08 IN SOIL AIR 2.346E+07 3.715E+07 5.464E+07 7.460E+07 9.309E+07 1.108E+08 1.231E+08 1.305E+08 1.346E+08 1.353E+08 1.377E+08 1.410E+08 SOIL ZONE 3: SUBLAYER 1 DEGRAD M~~S 3~445E + 08 6~68~E + ~6 6~816E + ~6 7~149E +08 7~617E +088~215E +08 8~672E +~6 8~85~E +088~775E +~6 8~628E +~6 8.456E + 08 8.374E + 06 IN SOIL MOl 1.110E+08 1.114E+08 1.146E+08 1.218E+08 1.306E+08 1.418E+08 1.478E+08 1.491E+08 1.463E+08 1.436E+08 1.407E+08 1.399E+08 ADS ON SOIL 2.326E + 08 2.322E + 08 2.353E + 08 2.441E+08 2.572E +08 2.751E+08 2.883E + 08 2.959E + 08 2.980E + 08 2.995E + 08 2.997E+ 08 3.021E+08 IN SOIL AIR 4.210E+07 4.189E+07 4.203E+07 4.281E+07 4.459E+07 4.721E+07 4.989E+07 5.180E+07 5.303E+07 5.304E+07 5.376E + 07 5.462E + 07 LOWER SOIL ZONE: SUBLAYER I - POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 %SOLUBIMTY 1.0(X)E + 02 1.000E+ 021.000E + 02 1.000E + 02 1.000E + 021.000E + 021.000E + 02 1.000E + 021.000E + 02 1.000E + 02 1.000E+02 1.000E + 02 ADSORBED 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 3.048E+01 SOIL AIR 3.965E+01 3.965E+01 3.965E+01 3.949E+01 3.949E+01 3.949E+01 3.969E+01 3.969E+01 3.969E+01 3.893E+01 3.893E+01 3.893E+01 PURE PHASE 3.323E+02 3.308E+02 3.291E+ 02 3.271E +02 3.252E +02 3.233E+02 3.218E+02 3.207E+02 3.198E +02 3.191E+02 3.182E+02 3.172E+ 02 SOIL ZONE 2: SUBLAYER 1 MOISTURE 6.325E+00 1.005E+01 1.492E+01 2.076E+01 2.620E+01 3.150E+01 3.471E+01 3.638E+01 3.689E+01 3.726E+01 3.745E+01 3.806E+01 %SOLUBIE'rY 3.614E+00 5.742E+00 8.527E+ 00 1.186E+01 1.497E+01 1.800E+01 1.983E+01 2.079E+01 2.108E+01 2.129E+01 2.140E+01 2.175E+01 ..... ~ '.~' ADSORBED 1.102E+00 1.750E+00 2.599E+00 3.616E+00 4.565E+ 00 5.486E+00 6.046E+00 6.337E+00 6.426E+00 6.491E+00 6.523E+00 6.629E+00 SOIL AIR 1.433E+00 2.277E+00 3.381E+00 4.685E+00 5.914E+00 7.108E+00 7.872E+00 8.252E+00 8.368E+00 8.290E+00 8.330E+00 8.466E+00 SOIL ZONE 3: SUBLAYER I MOISTURE 7.094E-01 7.081E-01 7.175E-01 7.445E-01 7.845E-01 8.389E-01 8.792E-01 9.023E-01 9.087E-01 9.134E-01 9.141E-01 9.214E-01 %SOLUBIMTY 4.054E-01 4.046E-01 4.100E-01 4.254E-01 4.483E-01 4.794E-01 5.024E-01 5.156E-01 5.192E-01 5.219E-01 5.223E-01 5.265E-01 ADSORBED 1.236E-01 1.234E-01 1.250E-01 1.297E-01 1.367E-01 1.461E-01 1.531E-01 1.572E-01 1.583E-01 1.591E-01 1.592E-01 1.605E-01 SOIL AIR 1.608E-01 1.605E-01 1.626E-01 1.680E-01 1.771E-01 1.893E-01 1.994E-01 2.047E-01 2.061E-01 2.032E-01 2.033E-01 2.050E-01 LOWER SOIL ZONE: POL DEP CM 2.422E + 03 2.425E + 03 2.429E + 03 2.434E +03 2.439E + 03 2.445E + 03 2.449E + 03 2.451E+03 2.453E + 03 2.454E + 03 2.456E + 03 2.457E + 03 YEAR - 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 2.498E+ 11 SOIL ZONE 2 1.319E+08 SOIL ZONE 3 3.875E+08 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.534 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 11.534 15.637 15.580 3.648 0.637 13.626 -1.694 13.683 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 9.034E+09 1.886E+08 9.168E+07 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 3.885E+03 SOIL MOISTURE (UG/ML) 2.754E+01 ADSORBED SOIL (UG/G) 4.798E+00 SOIL AIR (UG/ML) 6.198E+00 SOIL MOISTURE (UG/ML) 8.285Eq31 ADSORBED SOIL (UG/G) 1.443Eq31 SOIL AIR (UG/ML) 1.867E431 MAX. POLL DEPTH (M) 2.457E+01 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E + O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 TOTAL PRECIPITATION (CM) 15.701 TOTAL INFILTRATION (CM) 15.633 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.051 TOTAL GRW RUNOFF (CM) 12.227 TOTAL MOISTURE RETENTION (CM) ~3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 8.901E+09 6.790 E + 08 6.456E+08 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 3.048E+01 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 2.077E+03 SOIL MOISTURE (UG/ML) 9.522E+01 ADSORBED SOIL (UG/G) 1.659E+01 SOIL AIR (UG/ML) 2.146E+01 SOIL MOISTURE (UG/ML) 5.669E+00 ADSORBED SOIL (UG/G) 9.875E~31 SOIL AIR (UG/ML) 1.278E+00 MA)C POLL DEPTH (M) 2.777E+01 YEAR - 20 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00' SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL Gl=NV RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 8,897E+09 6.869E+08 8.015E+08 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.748E+02 ADSORBED SOIL (UG/G) 3.045E+01 SOIL AIR (UG/ML) 3.939E+01 PURE PHASE (UG/ML) 6.811E+01 SOIL MOISTURE (UG/ML) 9.629E+01 ADSORBED SOIL (UG/G) 1.677E+01 SOIL AIR (UG/ML) 2.170E+01 SOIL MOISTURE (UG/ML) 7.025E+00 ADSORBED SOIL (UG/G) 1.224E+00 SOIL AIR (UG/ML) 1.583E+00 MAX. POLL DEPTH (M) 3.132E+01 YEAR - 30 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.(XX)E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 TOTAL PRECIPITATION (CM) 15.701 TOTAL INFILTRATION (CM) 15.633 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.051 TOTAL GRW RUNOFF (CM) 12.227 TOTAL MOISTURE RETENTION (CM) q3.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOII~ SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1,713E+07 TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER I 8.521E+08 1.209E+08 4.057 E + 08 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.660E+01 ADSORBED SOIL (UG/G) 2.891E+00 SOIL NR (UG/ML) 3.742E+00 SOIL MOISTURE (UG/ML) 1.680E+01 ADSORBED SOIL (UG/G) 2.927E+00 SOIL AIR (UG/ML) 3.788E+00 SOIL MOISTURE (UG/ML) 3.546E+00 ADSORBED SOIL (UG/G) 6.177E~1 SOIL AIR (UG/ML) 7,995E~1 .! · MAX, POLL DEPTH (M) 3.488E+01 YEAR - 40 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E + 00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 -0.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL. SOIL AIR, IMMOBIL CRC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 7.639E+07 1.535E+06 1.084 E + 07 7.599E+07 5.766E+06 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - · UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.488E+00 ADSORBED SOIL (UG/G) 2.592E-01 SOIL AIR (UG/ML) 3.355E-01 SOIL MOISTURE (UG/ML) 1.506E+00 ADSORBED SOIL (UG/G) 2.624E-01 SOIL AIR (UG/ML) 3.396E-01 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.612E-01 ADSORBED SOIL (UG/G) 1.152E-01 SOIL AIR (UG/ML) 1.491E-01 SOIL MOISTURE (UG/ML) 9.933E-02 ADSORBED SOIL (UG/G) 1.730E-02 SOIL AIR (UG/ML) 2.239E-02 MA)C POLL DEPTH (M) 3.827E+01 YEAR - 50 ANNUAL SUMMARY REPORT ================================== - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.0(X)E + 00 SOIL ZONE 3 0.(XX)E+00 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) AVERAGE SOIL MOISTURE BELOW ZONE I (%) TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GFNV RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) 11.364 11.364 15.701 15.633 3.648 0.051 12.227 q3.242 12.295 TOTAL YIELD (CM) - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER I 6.846E+06 1.376E + 05 9.717E+05 1.076E + 07 TOTAL DEGRADED (MOISTURE) 2.122E+05 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.334Eq31 ADSORBED SOIL (UG/G) 2.323Eq32 SOIL AIR (UG/ML) 3.007E~2 SOIL MOISTURE (UG/ML) 1.350E~31 ADSORBED SOIL (UG/G) 2.352Eq32 SOIL AIR (UG/ML) 3.044E~32 SOIL MOISTURE (UG/ML) 9.356E~2 ADSORBED SOIL (UG/G) 1.630E~2 SOIL AIR (UG/ML) 2.109Eq32 SOIL MOISTURE (UG/ML) 3.639E~32 ADSORBED SOIL (UG/G) 6.34OE~:X3 SOIL AIR (UG/ML) 8.204E~33 MA~ POLL DEPTH (M) 4.150E+01 YEAR - ~ ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O00E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E + O0 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.001 12.227 -0.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 6.137E+05 1.234E+04 8.710E+04 1.734E + 02 1.387E+06 4.486E+05 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.195E-02 ADSORBED SOIL (UG/G) 2.082E-03 SOIL AIR (UG/ML) 2.695E-03 SOIL MOISTURE (UG/ML) 1.210E-02 ADSORBED SOIL (UG/G) 2.108E-03 SOIL AIR (UG/ML) 2.728E-03 SOIL MOISTURE (UG/ML) 1.206E-02 ADSORBED SOIL (UG/G) 2.100E~3 SOIL AIR (UG/ML) 2.718E-03 SOIL MOISTURE (UG/ML) 7.685E-03 ADSORBED SOIL (UG/G) 1.339E-03 SOIL AIR (UG/ML) 1.733E-03 MA~ POLL DEPTH (M) 4.473E+01 YEAR - 70 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.(XX)E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E+O0 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 TOTAL PRECIPITATION (CM) 15.701 TOTAL INFILTRATION (CM) 15.633 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.051 TOTAL GRW RUNOFF (CM) 12.227 TOTAL MOISTURE RETENTION (CM) -0.242 TOTAL YIELD (CM) 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.640E+04 2.523E+03 8.121E+03 1.761E+03 1.677E + 05 7.860E+04 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.099E-03 ADSORBED SOIL (UG/G) 1.914E-04 SOIL NR (UG/ML) 2.477E-04 SOIL MOISTURE (UG/ML) 1.129E-03 ADSORBED SOIL (UG/G) 1.966E-04 SOIL AIR (UG/ML) 2.544E-04 SOIL MOISTURE (UG/ML) 1.458E-03 ADSORBED SOIL (UG/G) 2.540E-04 SOIL AIR (UG/ML) 3.287E-04 SOIL MOISTURE (UG/ML) 1.346E-03 ADSORBED SOIL (UG/G) 2.344E-04 SOIL AIR (UG/ML) 3.034E~4 MA)C POLL DEPTH (M) 4.796E+01 YEAR - 80 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE O.O00E+O0 SOIL ZONE 2 O.O(X)E+O0 SOIL ZONE 3 O.O00E+O0 LOWER SOIL ZONE O.O00E + O0 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.6,33 3.648 0.051 12.227 43.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) 5.450E+03 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 3.625E+02 TOTAL DEGRADED (MOISTURE) 7.946E+02 SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) 3.148E+02 TOTAL DEGRADED (MOISTURE) 1.947E+04 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) 6.373E+01 TOTAL DEGRADED (MOISTURE) 1.025E+04 TOTAL IN GROUNDWATER RUNOFF 1.253E+03 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.062E-04 ADSORBED SOIL (UG/G) 1.850E-05 SOIL AIR (UG/ML) 2.394E.05 SOIL MOISTURE (UG/ML) 1.105E434 ADSORBED SOIL (UG/G) 1,924E-05 SOIL AIR (UG/ML) 2.490E-05 SOIL MOISTURE (UG/ML) 1.693E-04 ADSORBED SOIL (UG/G) 2.949E-05 SOIL AIR (UG/ML) 3.816E-05 SOIL MOISTURE (UG/ML) 1.754E~4 ADSORBED SOIL (UG/G) 3.055E435 SOIL AIR (UG/ML) 3.954E~5 MAX. POLL DEPTH (M) 4.840E+01 YEAR - 90 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E + 00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GFNV RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~3.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 5.499 E + 02 4.576E+01 8.094E+01 4.359E+01 2.231E+03 1.779E+01 1.233 E + 03 1.507E + 02 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.072Eq35 ADSORBED SOIL (UG/G) 1.867E~6 SOIL AIR (UG/ML) 2.416E~6 SOIL MOISTURE (UG/ML) 1.125E-05 ADSORBED SOIL (UG/G) 1.960E.O6 SOIL AIR (UG/ML) 2.537E-06 SOIL MOISTURE (UG/ML) 1.939E~5 ADSORBED SOIL (UG/G) 3.378Eq:)6 SOIL AIR (UG/ML) 4.372Eq:)6 SOIL MOISTURE (UG/ML) 2.108E~5 ADSORBED SOIL (UG/G) 3.673E~6 SOIL AIR (UG/ML) 4.753E~36 MA)~ POLL DEPTH (M) 4.840E+01 YEAR - 99 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0,000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE O.O00E+00 TOTAL PRECIPITATION (CM) TOTAL INFILTRATION (CM) TOTAL EVAPOTRANSPIRATION (CM) TOTAL SURFACE RUNOFF (CM) TOTAL GRW RUNOFF (CM) TOTAL MOISTURE RETENTION (CM) TOTAL YIELD (CM) - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 11.364 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 11.364 15.701 15.633 3.648 0.051 12.227 ~.242 12.295 - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAl. MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 TOTAL DEGRADED (MOISTURE) SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) TOTAL DEGRADED (MOISTURE) TOTAL IN GROUNDWATER RUNOFF 7.133E+01 6.664E+00 1.056E+01 6.831E+00 3.156E+02 3.413E+00 1.794 E + 02 2.192E+01 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.390E~36 ADSORBED SOIL (UG/G) 2.422E~7 SOIL AIR (UG/ML) 3.134E437 SOIL MOISTURE (UG/ML) 1.468E~36 ADSORBED SOIL (UG/G) 2.557E~7 SOIL AIR (UG/ML) 3.310E.07 SOIL MOISTURE (UG/ML) 2.743E~:)6 ADSORBED SOIL (UG/G) 4.779E~7 SOIL AIR (UG/ML) 6.185E437 SOIL MOISTURE (UG/ML) 3.058E~36 ADSORBED SOIL (UG/G) 5.343E~7 SOIL AIR (UG/ML) 6.916E~7 MAX. POLL DEPTH (M) 4.840E+01 H ~ Cardinal® APPENDIX H Abbreviated AT123D Output Files GROUNDWATER TECHNOLOGY AT123D OUTPUT FOR BENZENE AT ARCO 6218 NO. OF POINTS IN X-DIRECTION ...................... 6 NO. OF POINTS IN Y-DIRECTION ...................... 5 NO. OF POINTS IN Z-DIRECTION ...................... 5 NO. OF ROOTS: NO. OF SERIES TERMS ................. 400 NO. OF BEGINNING TIME STEP ........................ 61 NO. OF ENDING TIME STEP ........................... 1189 NO. OF TIME INTERVALS FOR PRINTED OUT SOLUTION .... 60 INSTANTANEOUS SOURCE CONTROL = 0 FOR INSTANT SOURCE SOURCE CONDITION CONTROL = 0 FOR STEADY SOURCE .... 1188 INTERMITTENT OUTPUT CONTROL = 0 NO SUCH OUTPUT .... 1 CASE CONTROL -- 1 THERMAI~ -- 2 FOR CHEMICAl. = 3 RAD 2 AQUIFER DEPTH, = 0.0 FOR INFINITE DEEP (METERS) ... 0.0000E+00 AQUIFER WIDTH, = 0.0 FOR INFINITE WIDE (METERS) ... 0.0000E+00 BEGIN POINT OF X-SOURCE LOCATION (METERS) ......... ~3.3811E+01 END POINT OF X-SOURCE LOCATION (METERS) ........... 0.3811E+01 BEGIN POINT OF Y-SOURCE LOCATION (METERS) ......... ~.3811 E+ 01 END POINT OF Y-SOURCE LOCATION (METERS) ........... 0.3811E+01 BEGIN POINT OF Z-SOURCE LOCATION (METERS) ......... 0.0000E+00 END POINT OF Z-SOURCE LOCATION (METERS) ........... 0.0000E+00 POROSITY .......................................... 0.3000E+00 HYDRAULIC CONDUCTIVITY (METER/HOUR) ............... 0.1000E+01 HYDRAULIC GRADIENT ................................ 0.1000E~1 LONGITUDINAL DISPERSIVITY (METER) ................. 0.3(X)0E+02 LATERAL DISPERSIVITY (METER) ...................... 0.1000E+02 VERTICAL DISPERSIVITY (METER) ..................... 0.1000E+01 DISTRIBUTION COEFFICIENT, KD (M**3/KG) ............ 0.0000E+00 HEAT EXCHANGE COEFFICIENT (KCAL/HR-M**2-DEGREE C).. 0.0000E+00 MOLECULAR DIFFUSION MULTIPLY BY POROSITY (M**2/HR) 0.0000E+00 DECAY CONSTANT (PER HOUR) ......................... 0.0000E+00 BULK DENSITY OF THE SOIL (KG/M**3) ................ 0.1350E+04 ACCURACY TOLERANCE FOR REACHING STEADY STATE ...... 0.1000E~31 DENSITY OF WATER (KG/M**3) ........................ 0.1000E+04 TIME INTERVAL SIZE FOR THE DESIRED SOLUTION (HR) .. 0.7300E+03 DISCHARGE TIME (HR) ............................... 0.8672E+06 WASTE RELEASE RATE (KCAL/HR), (KG/HR), OR (CI/HR). 0.O000E+O0 UST OF TRANSIENT SOURCE RELEASE RATE 0.000E+00 0,000E+00 0,000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0,000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0,000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 O.000E+00 0.000E+00 0.000E+00 0,000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 O.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(X)0E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 O.000E+00 0.000E+00 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O. O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O(X)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O(X)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.CX)OE+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O(X)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O(X)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O. O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O(X)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O(X)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.I:X)OE+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O00. O00E+O00.O00E+O00.O00E+O00.O00E+O0 0.281E-11 0.588E-11 0.514E-11 0.502E-11 0.513Eoll 0.565E-11 0.669E-11 0.745E-11 0.826E-11 0.780E-11 0.674E-11 0.550E-11 0.450E-11 0.372E-11 0.324E-11 0.317E-11 0.324E-11 0.357E-11 0.423E-11 0.471E-11 0.522E-11 0.493E-11 0.426E-11 0.348E-11 0.284E-11 0.235E-11 0.205E-11 0.200E-11 0.205E-11 0.226E-11 0.267E-11 0.298E-11 0.330E-11 0.312E-11 0.269E-11 0.220E-11 0.180E-11 0.148E-11 0.130E-11 0.127E-11 0.130E-11 0.143E-11 0.169E-11 0.188E-11 0.209E-11 0.197E-11 0.170E-11 0.139E-11 0.114Eoll 0.939E-12 0.820E-12 0.801E-12 0.818E-12 0.901E-12 0.107E-11 0.119E-11 0.132E-11 0.125E-11 0.108E-11 0.879E-12 0.718E-12 0.593E-12 0.519E-12 0.507E-12 0.518E-12 0.570E-12 0.675E-12 0.752E-12 0.835E-12 0.788E-12 0.681E-12 0.555E-12 0.454E-12 0.376E-12 0.328E-12 0.321E-12 0.327E-12 0.360E-12 0.427E-12 0.476E-12 0.528E-12 0.498E-12 0.429E-12 0.351E-12 0.287E-12 0.237E-12 0.207E-12 0.202E-12 0.207E-12 0.228E-12 0.270E-12 0.301E-12 0.333E-12 0.313E-12 0.270E-12 0.221E-12 0.181E-12 0.150E-12 0.131E-12 0.128E-12 0.130E-12 0.143E-12 0.169E-12 0.190E-12 0.212E-12 0.201E-12 0.174E-12 0.143E-12 0.117E-12 0.969E-13 0.846E-13 0.826E-13 0.840E-13 0.919E-13 0.108E-12 0.120E-12 0.133E-12 0.125E-12 0.109E-12 0.899E-13 0.742E-13 0.619E-13 0.545E-13 0.536E-13 0.550E-13 0.608E-13 0.722E-13 0.805E-13 0.893E-13 0.842E-13 '0.726E-13 0.591E-13 0.481E-13 0.395E-13 0.342E-13 0.331E-13 0.333E-13 0.361E-13 0.418E-13 0.455E-13 0.498E-13 0.468E-13 0.405E-13 0.331E-13 0.271E-13 0.223E-13 0.197E-13 0.199E-13 0.211E-13 0.240E-13 0.291E-13 0.329E-13 0.372E-13 0.358E-131 0.317E-13 0.268E-13 0.228E-13 0.196E-13 0.178E-13 0.180E-13 0.190E-13 0.218E-13 0.267E-13 0.308E-13 0.355E-13 0.347E-13 0.311E-13 0.264E-13 0.224E-13 0.192E-13 0.174E-13 0.177E-13 0.187E-13 0.213Eo13 0.262E-13 0.303E-13 0.349E-13 0.343E-13 0.308E-13 0.261E-13 0.221E-13 0.190E-13 0.173E-13 0.175E-13 0.185E-13 0.211E-13 0.260E-13 0.300E-13 0.346E-13 0.339E-13 0.305E-13 0.259E-13 0.219Eo13 0.188E-13 0.170E-13 0o173E-13 0.183E-13 0.209E-13 0.256E-13 0.296E-13 0.341E-13 0.335E-13 0.301E-13 0.255E-13 0.216E-13 0.186E-13 0.168E-13 0.171E-13 0.180E-13 0.206E-13 0.253E-13 0.292E-13 0.337E-13 0.330E-13 0.297E-13 0.252E-13 0.214E-13 0.183E-13 0.166E-13 0.168E-13 0.178E-13 0.203E-13 0.249E-13 0.288E-13 0.332E-13 0.326E-13 0.293E-13 0.249E-13 0.211E-13 0.181E-13 0.164E-13 0.166E-13 0.176Eo13 0.200E-13 0.246E-13 0.284E-13 0.327E-13 0.321E-13 0.289E-13 0.245E-13 0.208E-13 0.178Eo13 0.161E-13 0.163E-13 0.173E-13 0.197E-13 0.242E-13 0.279E-13 0.321E-13 0,316E-13 0.284E-13 0.241E-13 0.204E-13 0.175E-13 0.158E-13 0.161E-13 0.170E-13 0.194E-13 0.237E-13 0.274E-13 0.316E-13 0.310E-13 0.278E-13 0.237E-13 0.201E-13 0.172E-13 0.156E-13 0.158E-13 0.167E-13 0.191E-13 0.234E-13 0.270E-13 0.311E-13 0.305E-13 0.273E-13 0.232E-13 0.197E-13 0.169E-13 0.153E-13 0.155E-13 0.164E-13 0.187E-13 0.230E-13 0.265E-13 0.305E-13 0.300E-13 0.268E-13 0.227E-13 0.193E-13 0.165E-13 0.150E-13 0.152E-13 0.161E-13 0.183E-13 0.225E-13 0.259E-13 0.298E-13 0.293E-13 0.262E-13 0.222E-13 0.189E-13 0.162E-13 0.146E-13 0.148E-13 0.157E-13 0.179E-13 0.219E-13 0.253E-13 0.291E-13 0.286E-13 0.256E-13 0.217E-13 0.184E-13 0.158E-13 0.143E-13 0.145E-13 0.154E-13 0.175Eo13 0.214E-13 0.247E-13 0.284E-13 0.279E-13 0.250E-13 0.212E-13 0.180E-13 0.154E-13 0.140E-13 0.141E-13 0.150E-13 0.171E-13 0.209E-13 0.241E-13 0.277E-13 0.272E-13 0.244E-13 0.207E-13 0.175E-13 0.150E-13 0.136E-13 0.138E-13 0.146E-13 0.166E-13 0.204E-13 0.235E-13 0.271E-13 0,265E-13 0.238E-13 0.202E-13 0.171Eo13 0.146E-13 0.133E-13 0.134Eo13 0.142E-13 0.163E-13 0.200E-13 0.230E-13 0.265E-13 0.260E-13 0.233E-13 0.197E-13 0.167E-13 0.143E-13 0.130E-13 0.132E-13 0.139E-13 0.159E-13 0.196E-13 0.225E-13 0.259E-13 0.254Eo13 0.228E-13 0.193E-13 0.164E-13 0.140E-13 0.127E-13 0.129E-13 0.136E-13 0.156E-13 0.191E-13 0.220E-13 0.2,53E-13 0.248E-13 0.223E-13 0.189E-13 0.160E-13 0.137E-13 0.124E-13 0.126E-13 0.133E-13 0.152E-13 0.187E-13 0.215E-13 0.248E-13 0.244E-13 0.218E-13 0.185E-13 0.157E-13 0.135E-13 0.122E-13 0.124E-13 0.131E-13 0.150E-13 0.184E-13 0.212E-13 0.245E-13 0.240E-13 0.216E-13 0.183E-13 0.155E-13 0.133E-13 0.120E-13 0.122E-13 0.129E-13 0.148E-13 0.181E-13 0.209E-13 0.242Eo13 0.237E-13 0.212E-13 0.180E-13 0.153E-13 0.131E-13 0.119E-13 0.120E-13 0.127E-13 0.145E-13 0.178E-13 0.206E-13 0.238E-13 0.233E-13 0.209E-13 0.178E-13 0.151E-13 0.129E-13 0.117E-13 0.119E-13 0.126E-13 0.143E-13 0.176E-13 0.203E-13 0.235E-13 0.230E-13 0.206E-13 0.175E-13 0.149E-13 0.128E-13 0.116E-13 0.117E-13 0.124E-13 0.141E-13 0.173E-13 0.200E-13 0.231E-13 0.227E-13 0.203E-13 0.173E-13 0.147E-13 0.126E-13 0.114E-13 0.115E-13 0.122E-13 0.139E-13 0.171E-13 0.197E-13 0.228E-13 0.223E-13 0.200E-13 0.170E-13 0.144E-13 0.124E-13 0.112E-13 0.114E-13 0.120E-13 0.137Eo13 0.168E-13 0.195E-13 0.224E-13 0.220E-13 0.197E-13 0.167E-13 0.142E-13 0.122E-13 0.111E-13 0.112E-13 0.118E-13 0.135E-13 0.166E-13 0.192E-13 0.221E-13 0.216E-13 0.194E-13 0.165E-13 0.140E-13 0.120E-13 0.109E-13 0.110E-13 0.117E-13 0.133E-13 0.163E-13 0.188E-13 0.217E-13 0.213E-13 0.191E-13 0.162E-13 0.138E-13 0.119Eo13 0.107E-13 0.109E-13 0.115E-13 0.132E-13 0.161E-13 0.187E-13 0.215E-13 0.211E-13 0.189E-13 0.161E-13 0.137E-13 0.117E-13 0.106Eo13 0.108E-13 0.114E-13 0.130E-13 0.160E-13 0.185E-13 0.212E-13 0.209E-13 0.187E-13 0.159E-13 0.135E-13 0.116E-13 0.105E-13 0.107E-13 0.113Eo13 0.129E-13 0.158E-13 0.183E-13 0.210E-13 0.206E-13 0.185E-13 0.157E-13 0.134E-13 0.115E-13 0.104E-13 0.106E-13 0.112E-13 0.128E-13 0.156E-13 0.180E-13 0.208E-13 0.204E-13 0.183E-13 0.155E-13 0.132E-13 0.114Eo13 0.103E-13 0.105E-13 0.111E-13 0.126E-13 0.155E-13 0.178E-13 0.206E-13 0.202E-13 0.181E-13 0.154E-13 0.131E-13 0.112E-13 0.102E-13 0.103E-13 0.109E-13 0.125E-13 0.153E-13 0.176E-13 0.203E-13 0.199E-13 0.179Eo13 0.152E-13 0.129E-13 0.111E-13 0.101E-13 0.102E-13 0,108E-13 0.124E-13 0.151E-13 0.175E-13 0.201E-13 0.197E-13 0.177E-13 0.150E-13 0.127E-13 0.109E-13 0.986E-14 0.100E-13 0.106E-13 0.121E-13 0.148E-13 0.171E-13 0.196E-13 0.192E-13 0.173E-13 0.147E-13 0.124E-13 0.106E-13 0.964E-14 0.979E-14 0.104E-13 0.118E-13 0.145E-13 0,168E-13 0.193E-13 0.189E-13 0.170E-13 0.144E-13 0.122E-13 0.104E-13 0.948E-14 0.962E-14 0.102E-13 0.116E-13 0.143E-13 0.164E-13 0.189E-13 0.186E-13 0.167E-13 0.141E-13 0.119E-13 0.102Eo13 0.926E-14 0.940E-14 0.994E-14 0.113E-13 0.139E-13 0.161E-13 0.185E-13 0.181E-13 0.163E-13 0.138E-13 0.116E-13 0.996E-14 0.904E-14 0.917E-14 0.970E-14 0,110E-13 0.136E-13 0.157E-13 0.180E-13 0.177E-13 0.159E-13 0.134E-13 0.114E-13 0.972E-14 0.882E-14 0.895E-14 0.946E-14 0.108E-13 0.132Eo13 0.153E-13 0.175E-13 0.172E-13 0.154E-13 0.131E-13 0.111E-13 0.948E-14 0.860E-14 0,873E-14 0.923E-14 0.105E-13 0.129E-13 0.149E-13 0.171E-13 0.168E-13 0.150E-13 0.127E°13 0.108E-13 0.923E-14 0.838E-14 0.850E-14 0.899E-14 0.102E-13 0.126E-13 0.145E-13 0.166E-13 0.163E-13 0.146E-13 0.124E-13 0.105E-13 0.899E-14 0.816E-14 0.828E-14 0.875E-14 0.995E-14 0.122.E-13 0.141E-13 0.161E-13 0.158E-13 0.142E-13 0.120E-13 0.102E-13 0.875E-14 0.794E-14 0.806E-14 0.851E-14 0.968E-14 0.119E-13 0.137E-13 0.157E-13 0.154E-13 0.138E-13 0.117E-13 0.993E-14 0.851E-14 0.773E-14 0.783E-14 0.827E-14 0.947E-14 0.116E-13 0.134E-13 0.153E-13 0.150E-13 0.135E-13 0.114E-13 0.972E-14 0.832E-14 0.756E-14 0.766E-14 0.809E-14 0.926E-14 0.114E-13 0.131E-13 0.150E-13 0.147E-13 0.132E-13 0.112E-13 0.950E-14 0.814E-14 0.740E-14 0.750E-14 0.792E-14 0.906E-14 0.111E-13 0.128E-13 0.146E-13 0.144E-13 0.129E-13 0.109E-13 0.929E-14 0.796E-14 0.723E-14 0.733E-14 0.774E-14 0.885E-14 0.108E-13 0.126E-13 0.145E-13 0.142E-13 0.128E-13 0.108E-13 0.922E-14 0.790E-14 0.718E-14 0.727E-14 0.768E-14 0.878Eo14 0.108E-13 0.125E-13 0.144E-13 0.141E-13 0.127E-13 0.108E-13 0.914E-14 0.784E-14 0.712E-14 0.722E-14 0.762E-14 0.872E-14 0.107E-13 0.124E-13 0.143E-13 0.140E-13 0.126E-13 0.107Eo13 0.907E-14 0.778E-14 0.707E-14 RETARDATION FACTOR ................................ 0.1000E+01 RETARDED DARCY VELOCITY (M/HR) .................... 0.3333E-01 RETARDED LONGITUDINAL DISPERSION COEF. (M**2/HR) .. 0.1000E+01 RETARDED LATERAL DISPERSION COEFRCIENT (M**2~HR). 0.3333E+00 RETARDED VERTICAL DISPERSION COEFFICIENT (M**2/HR). 0.3333E-01 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT O.O000E+O0 HRS (ADSORBED CHEMICAL CC)NC, = O,O000E+O0 * DISSOLVED CHEMICAL CONC,) Z= 0.00 X Y O. 100. 200. 300. 400. 500. 100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.(XX)E+O00.O00E+O0 50. O.O00E+O00.O(X)E+O00.O00E+O00.O00E+O00.O00E+O00.O(X)E+O0 O. O,O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 -50. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 -100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 Z = 5.00 X Y O. 100. 200. 300. 400. 500. · 100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 60. O.O00E+O00.O(X)E+O00.O00E+O00.O00E+O00.O00E+O00.O(X)E+O0 O. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 -50. O.O00E+O00.O00E+O00.O00E+O00,O00E+O00.O00E+O00.O00E+O0 -100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O(X)E+O00.O(X)E+O0 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O(X)E+O00.O00E+O0 50. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 O. O.O00E+O00.O00E+O00.O(X)E+O00.O00E+O00.O00E+O00.O00E+O0 -50. O.O00E+O00.O00E+O00,O00E+O00.O00E+O00.O00E+O00.O(X)E+O0 -100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O(X)E+O00.O00E+O0 Z = 15.00 X Y O. 100. 200. 300. 400. 500. 100. O.O00E+O00,O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 50. O.O00E+O00.O00E+O00.O(X)E+O00.O00E+O00.O00E+O00.O00E+O0 O. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O(X)E+O00.O00E+O0 -50. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 -100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 Z = 20.00 X Y O. 100. 200. 300. 400. 500. 100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 50. O.O00E+O00.O00E+O00.O00E+O00.O(X)E+O00.O00E+O00.O00E+O0 O. O.O(X)E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 -50. O.O00E+O00.O(X)E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 -100. O.(XX)E+O00.O(X)E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.2628E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0(XX)E+00 * DISSOLVED CHEMICAL CONC.) Z -- 0.00 X Y 0. 100. 200. 300. 400. 500. 100, 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.CXX)E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. O.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z= 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.0(X)E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.0(X)E+00 -100. O.000E+00 0.000E+00 0.000E+00 0.000E+O0 0.000E+00 0.000E+00 Z = 10.00 ' X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.CX)0E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.0(X)E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z -- 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.3066E+06 HRS (ADSORBED CHEMICAL CONC. -- 0.(XX)0E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.965E-11 0.283E-10 0.344E-10 0.254E-10 0.136E-10 0.543E-11 50. 0.670E-10 0.123E-09 0.100E-09 0,586E-10 0.273E-10 0.101E-10 0. 0.295E-09 0.253E-09 0.150E-09 0.787E-10 0.347E-10 0.125E-10 -50. 0.670E-10 0.123E-09 0,100E-09 0.586E-10 0.273E-10 0.101E-10 -100. 0.965E-11 0.283E-10 0.344E-10 0.254E-10 0.136E-10 0,543E-11 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.921E-11 0.272E-10 0.333E-10 0.247E-10 0.133E-10 0.532E-11 50. 0.602E-10 0,115E-09 0.964E-10 0.569E-10 0.266E-10 0.990E-11 0. 0.245E-09 0.232E-09 0.144E-09 0.764E-10 0.338E-10 0.122E-10 -50. 0.602E-10 0.115E.09 0.964E-10 0.569E-10 0.266E-10 0.990E-11 -100. 0.921E-11 0.272E-10 0.333E-10 0.247E-10 0.133E-10 0.532E-11 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.803E-11 0.241E-10 0.302E-10 0.228E-10 0.124E-10 0.500E-11 50. 0.453E-10 0.970E-10 0.860E-10 0.522E-10 0.248E-10 0.930E-11 0. 0.147E-09 0.183E-09 0.127E-09 0.699E-10 0.315E-10 0.115E-10 -50. 0.453E-10 0.970E-10 0.860E-10 0.522E-10 0.248E-10 0.930E-11 -100. 0.803E-11 0.241E-10 0.302E-10 0.228E-10 0.124E-10 0.500E-11 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.644E-11 0.197E-10 0.257E-10 0.200E-10 0.111E-10 0.451E-11 50. 0.307E-10 0.742Eo10 0.714E-10 0.453E-10 0.221E-10 0.838E-11 0. 0.745E-10 0.130E-09 0.104E-09 0.603E-10 0.279E-10 0.103E-10 -50. 0.307E-10 0.742Eo10 0.714E-10 0.453E-10 0.221E-10 0.838E-11 -100. 0.644E-11 0.197E-10 0.257E-10 0.200E-10 0.111E-10 0.451E-11 Z = 20.00 X Y 0, 100. 200. 300. 400. 500. 100. 0.480E-11 0.151E-10 0.206E-10 0.167E-10 0.945E-11 0.391E-11 50. 0.198E-10 0.525E-10 0.555E-10 0.372E-10 0.187E-10 0.724E-11 0. 0.382E-10 0.868E-10 0.797E-10 0.493E-10 0.237E-10 0.891E-11 -50. 0.198E-10 0.525E-10 0.555E-10 0.372E-10 0.187E-10 0.724E-11 -100. 0.480E-11 '0.151E-10 0.206E-10 0.167E-10 0.945E-11 0.391E-11 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.3504E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 '" DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.107E-11 0.327E-11 0.473E-11 0.531E-11 0.586E-11 0.641E-11 50. 0.691E-11 0.130E-10 0.120E-10 0.998E-11 0.925E-11 0.923E-11 0. 0.300E-10 0.263E-10 0.173E-10 0.126E-10 0.109E-10 0.105E-10 -50. 0.691E-11 0.130E-10 0.120E-10 0.998E-11 0.925E-11 0.923E-11 -100. 0.107E-11 0.327E-11 0.473E-11 0.531E-11 0.586E-11 0.641E-11 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.102Eoll 0.315E-11 0.460E-11 0.521E-11 0,577E-11 0.633E-11 50. 0.622E-11 0.123E-10 0.116E-10 0.976E-11 0.910E-11 0.912E-11 0. 0.249E-10 0.241E-10 0.166E-10 0.123E-10 0.107Eo10 0.103E-10 -50. 0.622E-11 0.123E-10 0.116E-10 0.976E-11 0.910E-11 0.912E-11 -100. 0.102E-11 0.315E-11 0.460E-11 0.521E-11 0.577E-11 0.633E-11 Z = 10.00 X Y 0. 100. 2(X). 300. 400. 500. 100. 0.898E-12 0.282E-11 0.424E-11 0.491E-11 0.552E-11 0,611E-11 50. 0.471E-11 0.104E-10 0.105E-10 0.913E-11 0.868E-11 0,878E-11 0. 0.150E-10 0.191E-10 0.149E-10 0.115E-10 0.102E-10 0.995E-11 -50. 0.471E-11 0.104E-10 0.105E-10 0.913E-11 0.868E-11 0.878E-11 -100. 0.898E-12 0.282E-11 0.424E-11 0.491E-11 0.552E-11 0.611E-11 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.732E-12 0.235E-11 0.371Eoll 0.446E-11 0.514E-11 0.576E-11 · 50. 0.323E-11 0.804E-11 0.888E-11 0.818E-11 0.803E-11 0.826E-11 0. 0.767E-11 0.138E-10 0.124E-10 0.102E-10 0.939E-11 0.935E-11 -50. 0.323E-11 0.804E-11 0.888E-11 0.818E-11 0.803E-11 0.826E-11 -100. 0.732E-12 0.235E-11 0.371E-11 0.446E-11 0.514E-11 0.576E-11 Z = 20.00 X Y 0. 100. 200. 300. 400. 5(X:). 100. 0.559E-12 0.185E-11 0.309E-11 0.392E-11 0.465E-11 0.531E-11 50. 0.211E-11 0.580E-11 0,712E-11 0.705E-11 0.722E-11 0,758E-11 0. 0.399E-11 0.934E-11 0.979E-11 0.873E-11 0.841E-11 0.857E-11 -50. 0.211E-11 0.580E-11 0.712E-11 0.705E-11 0.722E-11 0.758E-11 -100. 0.559E-12 0.185E-11 0.309E-11 0.392E-11 0.465Eoll 0.531E-11 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.3942E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z= 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.113E-12 0.347E-12 0.498E-12 0.551E-12 0.600E-12 0.653E-12 50. 0.731E-12 0.138E-11 0.127E-11 0.104E-11 0.951E-12 0.941E-12 0. 0.315E-11 0.279E-11 0.183E-11 0.132E-11 0.112E-11 0.107E-11 -50. 0.731E-12 0.138E-11 0.127E-11 0.104E-11 0.951E-12 0.941E-12 -100. 0.113E-12 0.347E-12 0.498E-12 0.551E-12 0.600E-12 0.653E-12 Z = 5.00 X Y O. 100. 200. 300. 400. 500. 100. 0.108E-12 0.334E-12 0.484E-12 0.540E-12 0.592E-12 0.645E-12 50. 0.659E-12 0.130E-11 0.123E-11 0.102E-11 0.936E-12 0.930E-12 0. 0.262E-11 0.256E-11 0.176E-11 0.129E-11 0.110E-11 0.105E-11 -50. 0.659E-12 0.130E-11 0.123E-11 0.102E-11 0.936E-12 0.930E-12 -100. 0.108E-12 0.334E-12 0.484E-12 0.540E-12 0.592E-12 0.645E-12 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.953E-13 0.298E-12 0.445E-12 0.509E-12 0.566E-12 0.623E-12 50. 0.499E-12 0.110E-11 0.111Eoll 0.952E-12 0.892E-12 0.896E-12 0. 0.158E-11 0.203E-11 0.157E-11 0.120E-11 0.105E-11 0.101E-11 -50. 0.499E-12 0.110E-11 0.111E-11 0.952E-12 0.892E-12 0.896E-12 -100. 0.953E-13 0.298E-12 0.445E-12 0.509E-12 0.566E-12 0.623E-12 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.776E-13 0.249E-12 0.389E-12 0.462E-12 0.526E-12 0.587E-12 50. 0.342E-12 0.854E-12 0.938E-12 0.852E-12 0.825E-12 0.842E-12 0. 0.810E-12 0.146E-11 0.131E-11 0.107E-11 0.966E-12. 0.953E-12 -50. 0.342E-12 0.854E-12 0.938E-12 0.852E-12 0.825E-12 0.842E-12 -100. 0.776E-13 0.249E-12 0.389E-12 0.462E-12 0.526E-12 0.587E-12 Z= 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.592E-13 0.196E-12 0.324E-12 0.405E-12 0.476E-12 0.540E-12 50. 0.224E-12 0.616E-12 0.751E-12 0.733E-12 0.741E-12 0.773E-12 0. 0.423E-12 0.991E-12 0.103E-11 0.910E-12 0.865E-12 0.874E-12 -50. 0.224E-12 0.616E-12 0.751E-12 0.733E-12 0.741E-12 0.773E-12 -100. 0.592E-13 0.196E-12 0.324E-12 0.405E-12 0.476E-12 0.540E-12 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.4380E+06 HRS (ADSORBED CHEMICAL CONC. -- 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.438E-13 0.129E-12 0.169E-12 0.164E-12 0.155E-12 0.147E-12 50. 0.321E-12 0.503E-12 0.462E-12 0.327E-12 0.255E-12 0.219E-12 0. 0.150E-11 0.119Eoll 0.682.E-12 0.422E-12 0.305E-12 0.251E-12 -50. 0.321E-12 0.563E-12 0.462E-12 0.327E-12 0.255E-12 0.219E-12 -100. 0.438E-13 0.129E.12 0.169E-12 0.164E-12 0.155E-12 0.147E-12 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.418E.13 0.124E-12 0.164E-12 0.150E-12 0.152E-12 0.145E-12 50. 0.287E.12 0.529E-12 0.445E-12 0.319E-12 0.251E-12 0.216E-12 0. 0.123E-11 0.109E-11 0.655E-12 0.411E-12 0.299E-12 0.248E-12 -50. 0.2.87E-12 0,529E-12 0,445E-12 0.319E-12 0.251E-12 0.216E-12 -100. 0.418E-13 0.124Eo12 0.164E-12 0.160E-12 0.152Eo12 0.145E-12 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.364Eo13 0.110E-12 0.150E-12 0.150E-12 0.145E°12 0.14OE-12 50. 0.213E-12 0.443E-12 0.399E-12 0.297E-12 0.238E-12 0.208E-12 0. 0.729E.12 0.850E-12 0.581E-12 0.381E-12 0.284E-12 0.238E-12 -50, 0.213E.12 0,443E-12 0.399E-12 0.297E.12 0.238E-12 0.208E-12 -100. 0.364E-13 0.110E-12 0.150E-12 0.150E-12 0.145E-12 0.140E-12 Z = 15.00 X Y O. 100. 200. 300. 400. 500. 100. 0.293E-13 0.908E-13 0.129E-12 0.135E-12 0.134E-12 0.131E-12 50. 0.142E-12 0.337E-12 0,334E-12 0.263E-12 0.219E-12 0.194E-12 0. 0.358E-12 0.598E-12 0.479Eo12 0.336E-12 0.260E-12 0.222E-12 -50. 0.142E-12 0,337E-12 0.334E-12 0.263E-12 0.219E-12 0.194E-12 -100. 0.293E-13 0.908E-13 0.129E-12 0.135E-12 0.134E-12 0.131E-12 Z = 20.00 X Y O. 100. 200. 300. 400. 500. 100. 0.219E-13 0.702E-13 0.106E-12 0.117E-12 0.120E-12 0.120E-12 50. 0.904E-13 0.238E-12 0.263E-12 0.223E-12 0.195E-12 0.177Eo12 0. 0.178E-12 0.395E-12 0.371E-12 0.283E-12 0.230E-12 0.202E-12 -50. 0,904E-13 0.238E-12 0.263E-12 0.223E-12 0.195E-12 0.177E-12 -100. 0.219E-13 0.702E-13 0.106E-12 0.117E-12 0.120E-12 0.120E-12 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.4818E+06 HRS (ADSORBED CHEMICAL CONC. = 0.(XXX)E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.408E-13 0.120E-12 0.157E-12 0.153E-12 0.145E-12 0.138E-12 50. 0.299E-12 0.524E-12 0.430E-12 0.306E-12 0.239E-12 0.205E-12 0. 0.139E-11 0.111E-11 0.635E-12 0.394E-12 0.285E-12 0.235E-12 -50. 0.299E-12 0.524E-12 0.4,..'.'.'.'.'.~3E-12 0.306E-12 0.239E-12 0.205E-12 -100. 0.408E-13 0.120E-12 0.157E-12 0.153E-12 0.145Eo12 0.138E-12 Z = 5.00 X Y 0. 100. 200. 300. 400. 500, 100. 0.389E-13 0.116E-12 0.153E-12 0.150E-12 0.143E-12 0.136E-12 50. 0.267E-12 0.492E-12 0.415E-12 0.298E-12 0.235E-12 0.202E-12 0. 0.115Eoll 0.101E-11 0.610E-12 0.384E-12 0.280E-12 0.232E-12 -50. 0.267E-12 0.492E-12 0.415E-12 0.298E-12 0.235E-12 0.202E-12 -100. 0.389E-13 0.116E-12 0.153E-12 0.150E-12 0.143E-12 0.136E-12 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.339E-13 0.102E-12 0.140E-12 0.140E-12 0.136E-12 0.131E-12 50. 0.198E-12 0.412E-12 0.371E-12 0.277E-12 0.223E-12 0.194E-12 0. 0.678E-12 0.791E-12 0.541E-12 0.355E-12 0.265E-12 0.222E-12 -50. 0.198E-12 0.412E-12 0.371E-12 0.277E-12 0.223E-12 0.194E-12 -100. 0.339E-13 0.102E-12 0.140E-12 0.140E-12 0.136E-12 0.131E-12 Z -- 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.272E-13 0.845E-13 0.121E-12 0.126E-12 0.126E-12 0.123E-12 50. 0o132E-12 0.314E-12 0.311E-12 0.246E-12 0.205E-12 0.182E-12 0. 0.333E-12 0.557E-12 0.446E-12 0.313Eo12 0.243E-12 0.208E-12 -50. 0.132E-12 0.314E-12 0.311E-12 0.246E-12 0.205E-12 0.182E-12 -100. 0.272E-13 0.845E-13 0.121E-12 0.126E-12 0.126E-12 0.123E-12 Z -- 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.204E-13 0.654E-13 0.991E-13 0.109E-12 0.113E-12 0.112E-12 50. 0.842E-13 0.222E-12 0.245E-12 0.209E-12 0.182E-12 0.165E-12 0. 0.166E-12 0.368E-12 0.345E-12 0.264E-12 0.216E-12 0.189E-12 -50. 0.842E-13 0.222E-12 0.245Eo12 0.209E-12 0.182E-12 0.165E-12 -100. 0.204E-13 0.654E-13 0.991E-13. 0.109E-12 0.113E-12 0.112E-12 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.5256E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z -- 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.369E-13 0.109E-12 0.143E-12 0.139E-12 0.132E-12 0,126E-12 50. 0,270E-12 0.474E-12 0.390E-12 0.278E-12 0,218E-12 0,187E-12 0. 0,126E-11 0.100E-11 0.576E-12 0,358E-12 0.259E-12 0.214Eo12 -50. 0,270E-12 0.474E-12 0.390E-12 0.278E-12 0.218E-12 0,187E-12 -100. 0.369E-13 0.109E-12 0.143E-12 0.139E-12 0.132E-12 0.126E-12 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.352E-13 0,105E-12 0.139E-12 0.136E-12 0.130Eo12 0.124E-12 50. 0.241E-12 0.445E-12 0,376E-12 0.271E-12 0.214E-12 0.184E-12 0. 0.104E-11 0.916E-12 0.553E-12 0.349E-12 0.255E-12 0,211E-12 -50. 0.241E-12 0.445E-12 0.376E-12 0.271E-12 0.214E-12 0,184E-12 -100. 0.352E-13 0.105E-12 0.139E-12 0,136E-12 0,130E-12 0.124Eo12 Z = 10.00 X Y 0. 100. 2130. 3(}0, 400, 500, 100. 0,307E-13 0,929E-13 0,127E-12 0,128E-12 0,124E-12 0,119E-12 50. 0,179E-12 0.373E-12 0.337E-12 0,252E-12 0.203E-12 0,177E-12 0, 0,612E-12 0,715E-12 0,490E-12 0.323E-12 0.242E-12 0.203E-12 -50. 0,179E-12 0.373E-12 0.337E-12 0.252E-12 0,203E-12 0.177Eo12 -100. 0.307E-13 0.929E-13 0.127E-12 0,128Eo12 0.124Eo12 0.119E-12 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.247E-13 0,766E-13 0.110E-12 0,115Eo12 0.115E-12 0,112E-12 50. 0.120E-12 0.284E-12 0.282E-12 0.223E-12 0,187E-12 0.166E-12 0. 0,301E-12 0.503E-12 0.405E-12 0,285E-12 0.2.21E-12 0,190E-12 -50. 0.120E-12 0.284E-12 0.282E-12 0.223E-12 0.187E-12 0,166E-12 -100. 0.247E-13 0,766E-13 0,110E-12 0.115E-12 0.115E-12 0,112E-12 Z = 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0,185E-13 0.593E-13 0.900E-13 0,995E-13 0,103E.12 0.102Eo12 50. 0.761Eo13 0,201E-12 0,222E-12 0.190E-12 0.166E-12 0.151E-12 0. 0,150E-12 0.333E-12 0.313E-12 0,240E-12 0.196E-12 0.172E-12 -50. 0.761E-13 0.201E-12 0.222E-12 0.190E-12 0.166E-12 0,151E-12 -100. 0,185E-13 0.593E-13 0.900E-13 0,995E-13 0.103E-12 0,102Eo12 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.5694E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.328E-13 0.969E-13 0.127E-12 0.123E-12 0.117E-12 0.112E-12 50. 0.24OE-12 0.421E-12 0.347E-12 0.247E-12 0.193E-12 0.166E-12 O. 0.112E-11 0.892E-12 0.511E-12 0.318E-12 0.2,,',',',',',',',',~)E-12 0.190E-12 -50. 0.240E-12 0.421E-12 0.347E-12 0.247E-12 0.193E-12 0.166E-12 -100. 0.328E-13 0.969E-13 0.127E-12 0.123E-12 0.117E-12 0.112E-12 Z= 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.313E-13 0.930E-13 0.123E-12 0.121E-12 0.115E-12 0.110E-12 50. 0.214E-12 0.396E-12 0.334E-12 0.241E-12 0.190E-12 '0.164E-12 0. 0.921E-12 0.814E-12 0.491E-12 0.310E-12 0.226E-12 0.188E-12 -50. 0.214E-12 0.396E-12 0.334E-12 0.241E-12 0.190E-12 0.164E-12 -100. 0.313E-13 0.930E-13 0.123E-12 0.121E-12 0.115E-12 0.110E-12 Z -- 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.273E-13 0.825E-13 0.113E-12 0.113Eo12 0.110E-12 0.106E-12 50. 0.159E-12 0.331E-12 0.299E-12 0.224E-12 0.180E-12 0.157E-12 0. 0.544E-12 0.635E-12 0.436E-12 0.287E-12 0.214E-12 0.180E-12 -50. 0.159E-12 0.331E-12 0.299E-12 0.224E-12 0.180Eo12 0.157E-12 -100. 0.273E-13 0.825E-13 0.113E-12 0.113E-12 0.110E-12 0.106E-12 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.219E-13 0.681E-13 0.974E-13 0.102E-12 0.102E-12 0.993E-13 50. 0.106E-12 0.253E-12 0.251E-12 0.198E-12 0.166E-12 0.147E-12 · 0. 0.268E-12 0.447E-12 0.360E-12 0.253E-12 0.196E-12 0.168E-12 -50. 0.106E-12 0.253E-12 0.251E-12 0.198E-12 0.166E-12 0.147E-12 -100. 0.219E-13 0.681E-13 0.974E-13 0.102E-12 0.102E-12 0.993E-13 Z = 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.164E-13 0.527E-13 0.800E-13 0.883E-13 0.911E-13 0.908E-13 50. 0.676E-13 0.178E-12 0.198E-12 0.168E-12 0.147E-12 0.134E-12 0. 0.133E-12 0.296E-12 0.278Eo12 0.213E-12 0.174E-12 0.153E-12 -50. 0.676E-13 0.178E-12 0.198E-12 0.168E-12 0.147E-12 0.134E-12 -100. 0.164E-13 0.527Eo13 0.800E-13 0.883E-13 0.911E-13 0.908E-13 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.6132E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.301E-13 0.889E-13 0.116Eo12 0.113E-12 0.107E-12 0.101Eo12 50. 0,221E-12 0.387E-12 0.318E-12 0,225E-12 0,176E-12 0,151E-12 0. 0.103E-11 0.821E-12 0.469E-12 0.291E-12 0.210E-12 0.173E-12 -50. 0.221E-12 0.387E-12 0.318E-12 0.225E-12 0.176E-12 0.151E-12 -100. 0.301E-13 0.889E-13 0.116E-12 0.113E-12 0o107E-12 0.101E-12 Z= 5.00 X Y 0. 100. 200, 300. 400, 500. 100. 0.287E-13 0.853E-13 0.113E-12 0.110E-12 0.105E-12 0.100E-12 50, 0.197E-12 0.364E-12 0.306E-12 0.220E-12 0.173E-12 0.149E-12 0. 0.849E-12 0.749E-12 0.451E-12 0.283E-12 0.206E-12 0.171E-12 -50. 0.197E-12 0.364E-12 0.306E-12 0.220E-12 0.173E-12 0.149E-12 -100. 0.287E-13 0.853E-13 0.113E-12 0.110E-12 0.105E-12 0.100E-12 · Z-- 10.00 X Y 0. 100. 200. 300. 400. 500. 100, 0.250E-13 0.757E-13 0.103E-12 0.103E-12 0.100E-12 0.963E-13 50. 0,146E-12 0.305E-12 0.274E-12 0.204E-12 0.164E-12 0.143E-12 0. 0.501E-12 0.584E-12 0.400E-12 0.262E-12 0.196E-12 0.164E-12 -50. 0.146E-12 0.305E-12 0.274E-12 0.204E-12 0.164E-12 0.143E-12 -100. 0.250E-13 0.757E-13 0.103E-12 0.103E-12 0.100E-12 0.963E-13 Z = 15.00 X Y O. 100. 200. 300. 400. 500. 100. 0.201E-13 0.624E-13 0.891E-13 0.931E-13 0.926E-13 0.903E-13 50, 0.978E-13 0,232E-12 0.230E-12 0.181E-12 0.151E-12 0.134E-12 0. 0.246E-12 0.411E-12 0.330E-12 0.231E-12 0.179E-12 0.153E-12 -50. 0.978E-13 0.232Eo12 0.230E-12 0.181E-12 0.151E-12 0.134E-12 -100. 0.201E-13 0.624E-13 0.891E-13 0.931E-13 0.926E-13 0.903E-13 Z--- 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.151E-13 0.483E-13 0.732E-13 0.807E-13 0.830E-13 0.826E-13 50. 0.622E-13 0.164E-12 0,181E-12 0.154E-12 0.134E-12 0.122E-12 0. 0.123E-12 0.272E-12 0.255E-12 0.195E-12 0.159E-12 0.139E-12 -50. 0.622E-13 0.164E-12 0.181E-12 0.154E-12 0,134E-12 0.122E-12 -!00. 0.151E-13 0.483E-13 0.732E-13 0.807E-13 0.830E-13 0.826E-13 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.6570E+06 HRS (ADSORBED CHEMICAL CONC. = 0.000OE+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.279E-13 0.825E-13 0.108E-12 0.105E-12 0.993E-13 0.943E-13 50. 0.205E-12 0.359E-12 0.295E-12 0.209E-12 0.164E-12 0.14OE-12 0. 0.956E-12 0.762E-12 0.435E-12 0.270E-12 0.195E-12 0.161E.12 -50. 0.205E-12 0.359E-12 0.295E-12 0.209E-12 0.164E.12 0.140E-12 -100. 0.279E-13 0.825E-13 0.108E-12 0.105E.12 0.993E-13 0.943E-13 Z= 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.267E-13 0.792E.13 0.105E.12 0.103E-12 0.977E-13 0.931E-13 50. 0.183E-12 0,337E-12 0.284E.12 0.204E-12 0.161E-12 0.138E-12 0. 0.789E-12 0.695E-12 0.418E-12 0.263E-12 0.192E-12 0.159E-12 -50, 0.183E-12 0.337E.12 0.284E-12 0.204E-12 0.161E-12 0.138E.12 -100. 0.267E.13 0.792E-13 0.105E-12 0.103E-12 0.977E.13 0.931E.13 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.232E-13 0.703E-13 0,957E-13 0.961E-13 0.931E-13 0.895E-13 50. 0.136E-12 0.283E-12 0.255E-12 0.190E-12 0.153E.12 0.133E-12 0. 0.466E-12 0.542E-12 0.371E-12 0.243E-12 0.182E.12 0.152Eo12 -50. 0.136E-12 0.283E.12 0.255E-12 0.190E-12 0.153E.12 0.133E-12 -100. 0.232E-13 0.703E-13 0.957E-13 0.961E-13 0,931E-13 0.895E-13 Z = 15.00 X Y 0. 100. 200, 300. 400. 500. 100. 0.187E-13 0.579E-13 0.828E-13 0.865E-13 0.861E-13 0.839E-13 50. 0.907E-13 0.215Eo12 0.213E-12 0.168E-12 0.140E-12 0.124E.12 0. 0.229E-12 0.382E-12 0.306E-12 0.215E-12 0.166E-12 0.142E-12 -50. 0.907E.13 0.215E-12 0.213E-12 0.168E-12 0.14OE-12 0.124E-12 -100. 0.187E-13 0.579E.13 0.828E-13 0.865E.13 0.861E-13 0.839E.13 Z = 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.14OE-13 0.448E-13 0.679E-13 0.749E-13 0.772E-13 0.768E.13 50. 0.577E-13 0.152E-12 0.168E-12 0.143E-12 0.125E-12 0.113E-12 0. 0.114E-12 0.252E-12 0.237E-12 0.181E-12 0.148E-12 0.129E-12 -50. 0.577E-13 0.152E-12 0.168E-12 0.143E-12 0,125E-12 0.113E-12 -100. 0.14OE-13 0.448E-13 0.679Eo13 0.749E-13 0.772Eo13 0.768E-13 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.7008E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z --- 0.00 X Y 0. 100. 200. 300, 4OO, 500. 100. 0.263E-13 0.777E-13 0.102E-12 0.985E-13 0.932E-13 0.884E-13 50. 0.193E-12 0,338E-12 0.278E-12 0.197E-12 0.154E-12 0.132E-12 0. 0.903E-12 0o719E-12 0.410Eo12 0,254E-12 0.183E-12 0,151E-12 -50. O.193E-12 0.33~E-12 0.275E-12 0.197E-12 0.154E-12 0.132E-12 -100. 0.263E-13 0.777E-13 0.102E-12 0.985E-13 0.932E-13 0.884E-13 Z = 5.00 X Y O. 100. 200. 300. 400. 500. 100. 0,251E-13 0.746E-13 0.986E-13 0.964E-13 0.918E-13 0.873E-13 50, 0.173E-12 0.318E-12 0.268E-12 0.192E-12 0.151E-12 0.130E-12 0. 0.745E-12 0.656E-12 0.394E-12 0,248E-12 0.180E-12 0.149E-12 -50. 0.173Eo12 0.318Eo12 0.268E-12 0.192E-12 0.151E-12 0,130E-12 -100. 0.251E-13 0.746E-13 0.986E-13 0.964E-13 0.918E-13 0.873E-13 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. 0.219E-13 0.662E-13 0.902E-13 0.904E-13 0.875E-13 0.83gE-13 50. 0,128Eo12 0,266E-12 0.240Eo12 0.179E-12 0,143E-12 0.125E-12 0. 0.440E-12 0.511E-12 0,350E-12 0.229E-12 0.171E-12 0.143E-12 -50. 0.128E-12 0,266E-12 0.240Eo12 0,179E-12 0.143E-12 0,125E-12 -100. 0.219E-13 0.662E-13 0.902E-13 0,904E-13 0,875E-13 0.839E-13 Z = 15,00 X Y 0. 100. 200. 300. 400. 500. 100. 0.176E-13 0,546E-13 0.779E-13 0.814E-13 0.808E-13 0.787E-13 50. 0,1~56E-13 0.203E-12 0,201E-12 0,15~E-12 0.132E-12 0.117E-12 0. 0.216E-12 0.360E-12 0.288E-12 0.202E-12 0.156E-12 0.133E-12 -50. 0.856E-13 0,203E-12 0.201E-12 0.158E-12 0.132E-12 0.117E-12 -100. 0.176E-13 0.546E-13 0.779E-13 0.814E-13 0.808E-13 0.787E-13 Z = 20.00 X Y O. 100. 200. 300. 400. 500. 100. 0.132E-13 0.422E-13 0.640E-13 0.705E-13 0.725Eo13 0.720E-13 50. 0.544E-13 0,143E-12 0.158E-12 0.135E-12 0.117E-12 0.106E-12 0. 0.107E-12 0.238E-12 0,223E-12 0.170E-12 0.139E-12 0.121E-12 -50. 0.544E-13 0.143E-12 0.158E-12 0.135E-12 0.117E-12 0,106E-12 -100. 0.132E-13 0.422E-13 0.640E-13 0,705E-13 0,725E-13 0,720E-13 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.7446E+06 HRS (ADSORBED CHEMICAL CONC, = 0,0(XX)E+00 * DISSOLVED CHEMICAL CONC,) Z = 0,00 X' Y 0, 100, 200, 300, 400, 500, 100, 0,244E-13 0,721E-13 0,944E-13 0,917Eo13 0,870E-13 0,828E-13 50, 0,179E-12 0,314E-12 0,258E-12 0,183E-12 0,143E-12 0,123Eo12 0, 0,832E-12 0,665E-12 0,381E-12 0,236E-12 0,171E-12 0,141E-12 -50, 0,179E-12 0,314E-12 0,258E-12 0,183E-12 0,143E-12 0o123E-12 -100, 0,244E-13 0,721E-13 0,944E-13 0,917Eo13 0,870E-13 0,828E-13 Z= 5,00 X Y 0, 100, 200, 300, 400, 500, 100, 0,233E-13 0.692E-13 0.916E-13 0.897E-13 0,857E-13 0,817E-13 50, 0,160E-12 0,295E-12 0.248E-12 0,179E-12 0,141E-12 0,122E-12 0, 0,687E-12 0,607E-12 0,366E-12 0,230E-12 0,168E-12 0,139E-12 -50, 0,160E-12 0.295E-12 0.248E-12 0.179E-12 0,141E-12 0,122E-12 -100, 0.233E-13 0,692E-13 0,916E-13 0,897E-13 0,857E-13 0,817E-13 Z -- 10,00 X Y 0, 100, 200, 300, 400, 500, 100, 0,203E-13 0,614E-13 0.837E-13 0,842E-13 0,817E-13 0,786E-13 50, 0,119E-12 0,247E-12 0,223E-12 0,166E-12 0,134E-12 0,117E-12 0, 0,406E-12 0,473E-12 0,324Eo12 0,213E-12 0,159E-12 0,134E-12 -50, 0,119E-12 0,247E-12 0,223E-12 0,166E-12 0,134E-12 0,117Eo12 -100, 0,203E-13 0,614E-13 0,837E-13 0,842E-13 0,817E-13 0,786E-13 Z = 15,00 X Y 0, 100. 200, 300, 400, 500, 100, 0,163E-13 0.507E-13 0.724E-13 0,758Eo13 0,755E-13 0,737E-13 50, 0.792E-13 0,188E-12 0,186E-12 0,147E-12 0,123E-12 0,109E-12 0, 0,200E-12 0.333E-12 0,268E-12 0,188E-12 0,146E-12 0,125E-12 -50, 0,792E-13 0,188E-12 0,186E-12 0,147E-12 0,123E-12 0,109E-12 -100, 0,163E-13 0.507E-13 0,724E-13 0,758E-13 0,755E-13 0,737E-13 Z= 20,00 X Y 0, 100, 200, 300, 400, 500, 100, 0,122E-13 0,392E-13 0,594E-13 0,656E-13 0,677E-13 0,674E-13 50, 0,504E-13 0,133E-12 0,147E-12 0,125E-12 0,109E-12 0,994E-13 0, 0,994E-13 0.220E-12 0,207E-12 0.158E-12 0,129E-12 0,114E-12 -50, 0,504E-13 0,133E-12 0.147E-12 0,125E-12 0,109E-12 0.994E-13 -100, 0,122E-13 0.392E-13 0,594E-13 0,656E-13.'~0,677E-13 0,674E-13 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.7884E+06 HRS (ADSORBED CHEMICAL CONC, = 0.5000E+00 * DISSOLVED CHEMICAL CONC,) Z -- 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.216E-13 0.640E-13 0.839E-13 0.817E-13 0.777E-13 0.740E-13 50. 0.158E-12 0.278E-12 0.229E-12 0.163E-12 0.128E-12 0.110E-12 0. 0.736E-12 0.588E-12 0.338E-12 0.210E-12 0.152E-12 0.126E-12 -50. 0.158E-12 0.278E-12 0.229E-12 0.163E-12 0.128E-12 0.110E-12 -100. 0.216E-13 0.640E-13 0.839E-13 0.817E-13 0.777E-13 0.740E-13 Z = 5.00 X Y 0. 100. 200. 300. 400. 500, 100. 0.207E-13 0.614E-13 0.814E-13 0.799E-13 0.765E-13 0.731E-13 50. 0.141E-12 0.261E-12 0.220E-12 0.159E-12 0.126E-12 0.109E-12 0. 0.607E-12 0.537E-12 0.324E-12 0.205E-12 0.150E-12 0.124E-12 -50. 0.141E-12 0.261E-12 0.220E-12 0.159E-12 0.126E-12 0.109E-12 -100. 0.207E-13 0.614E-13 0.814E-13 0.799E-13 0.765E-13 0.731E-13 Z = 10.00 X Y 0. 100. 200. 300, 400. 500. 100. 0.180E-13 0.545E-13 0.744E-13 0.750E-13 0.729E-13 0.703E-13 50. 0.105Eo12 0.219E-12 0.198Eo12 0.148E-12 0.119E-12 0.104E-12 0. 0.359E-12 0.419E-12 0.288E-12 0.190E-12 0.142E-12 0.119E-12 -50. 0,105E-12 0.219E-12 0,198E-12 0.148E-12 0,119E-12 0.104E-12 -100. 0.180E-13 0.545E-13 0.744E-13 0.750E-13 0.729E-13 0.703E-13 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. '100. 0.145E-13 0.450E-13 0.644E-13 0.675E-13 0.674E-13 0.659E-13 50. 0.701E-13 0.167E-12 0,165E-12 0,131E-12 0.110E-12 0,976E-13 0. 0.176E-12 0.295E-12 0.237E-12 0.167E-12 0.130E-12 0.112E-12 -50. 0.701E-13 0.167E-12 0.165E-12 0.131E-12 0.110E-12 0.976E-13 -100. 0.145E-13 0.450E-13 0.644E-13 0.675E-13 0.674E-13 0.659E-13 Z = 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.109E-13 0.348E-13 0.529E-13 0.585E-13 0.604E-13 0.603E-13 50. 0.446E-13 0.118E-12 0.130E-12 0.111E-12 0.976E-13 0,889E-13 0. 0.880E-13 0.195E-12 0.184E-12 0.141E-12 0.115E-12 0.102E-12 -50. 0.446E-13 0.118E-12 0.130E-12 0.111E-12 0.976E-13 0.889E-13 -100. 0.109E-13 0.348E-13 0.529E-13 0.585E-13 0.604E-13 0.603E;13 STEADY STATE SOLUTION HAS NOT BEEN REACHED BEFORE FINAL SIMULATING TIME DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.8322E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z= 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.190E-13 0,562E-13 0.737E-13 0.717E-13 0.681E-13 0,648E-13 50. 0.139E-12 0.244E-12 0,201E-12 0.143E-12 0.112E-12 0.964E-13 0. 0,649E-12 0.518E-12 0.297E-12 0.184E-12 0.134E-12 0,110E-12 -50. 0,139E-12 0.244E-12 0,201E-12 0.143E-12 0.112E-12 0,964E-13 -100. 0.190E-13 0.562E-13 0,737E-13 0.717E-13 0.681E-13 0,648E-13 Z= 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.181E-13 0.540E-13 0.715E-13 0.701E-13 0.670E-13 0,640E-13 50. 0.124E-12 0,229E-12 0.194E-12 0.140E-12 0.110E-12 0,951E-13 0. 0.535E-12 0.472E-12 0.285E-12 0.180E-12 0,131E-12 0,109E-12 -50. 0.124E-12 0.229E-12 0,194E-12 0,140E-12 0.110E-12 0.951E-13 -100. 0,181E-13 0,540E-13 0,715E-13 0.701E-13 0.670E-13 0.640E-13 Z = 10.00 X Y 0. 100. 21:)0. 300. 400. 500. 100. 0.158E-13 0,479E-13 0.654E-13 0,658E-13 0,639E-13 0.615E-13 50. 0.924E-13 0,192E-12 0,174E-12 0,130E-12 0.105E-12 0.913E-13 0. 0.316E-12 0,368E-12 0,253E-12 0.166E-12 0.125E-12 0.105E-12 -50. 0.924E-13 0.192Eo12 0.174E-12 0.130E-12 0.105E-12 0,913E-13 -100. 0.158E-13 0.479E-13 0.654E-13 0,658E-13 0.639E-13 0,615E-13 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.127E-13 0.395E-13 0.565E-13 0.592E-13 0,590E-13 0.577E-13 50. 0.617E-13 0,146E-12 0.145E-12 0.115E-12 0.961E-13 0,854E-13 0. 0.155E-12 0.259E-12 0.209E-12 0.147E-12 0.114E-12 0.977E-13 -50. 0.617E-13 0,146E-12 0.145E-12 0.115Eo12 0.961E-13 0,854E-13 -100. 0.127E-13 0,395E-13 0.565E-13 0.592E-13 0,590E-13 0.577E-13 Z = 20,00 X Y 0. 100. 200. 300. 400. 500. 100. 0.954E-14 0.306E-13 0,464E-13 0,513E-13 0.529E-13 0.528E-13 50. 0.392E-13 0.103E-12 0.115E-12 0,978E-13 0.855E-13 0.778E-13 0. 0,774E-13 0.172E-12 0,161E-12 0.124E-12 0.101E-12 0.889E-13 -50. 0.392E-13 0.103E-12 0.115Eo12 0.978E-13 0.855E-13 0,778E-13 -,100. 0.954E-14 0,306E-13 0,464E-13 0.513E-13 0,529E-13 0.528E-13 AT123D OUTPUT FOR TOLUENE AT ARCO 6218 NO. OF POINTS IN X-DIRECTION ...................... 6 NO. OF POINTS IN Y-DIRECTION ...................... 5 NO. OF POINTS IN Z-DIRECTION ...................... 5 NO. OF ROOTS: NO. OF SERIES TERMS ................. 400 NO. OF BEGINNING TIME STEP ........................ 61 NO. OF ENDING TIME STEP ........................... 1189 NO. OF TIME INTERVALS FOR PRINTED OUT SOLUTION .... 60 INSTANTANEOUS SOURCE CONTROL -- 0 FOR INSTANT SOURCE SOURCE CONDITION CONTROL -- 0 FOR STEADY SOURCE .... 1188 INTERMITTENT OUTPUT CONTROL -- 0 NO SUCH OUTPUT .... 1 CASE CONTROL -- 1 THERMAJ~ -- 2 FOR CHEMICA~ -- 3 RAD 2 AQUIFER DEPTH, = 0.0 FOR INFINITE DEEP (METERS) o.. 0.0000E+00 AQUIFER WIDTH, = 0.0 FOR INFINITE WIDE (METERS) ... 0.0000E+00 BEGIN POINT OF X-SOURCE LOCATION (METERS) ......... -0.3811E+ 01 END POINT OF X-SOURCE LOCATION (METERS) ........... 0.3811E+01 BEGIN POINT OF Y-SOURCE LOCATION (METERS) ......... -0.3811E+01 END POINT OF Y-SOURCE LOCATION (METERS) ........... 0.3811E+01 BEGIN POINT OF Z-SOURCE LOCATION (METERS) ......... 0.(XXX)E+00 END POINT OF Z-SOURCE LOCATION (METERS) ........... 0.0000E+00 POROSITY .......................................... 0.300OK+00 HYDRAUMC CONDUCTIVITY (METER/HOUR) ............... 0.10(X)E+01 HYDRAULIC GRADIENT ................................ 0.1000E-01 LONGITUDINAL DISPERSIVlTY (METER) ................. 0.3000E+02 LATERAL DISPERSIVITY (METER) ...................... 0.1000E+02 VERTICAL DISPERSlVITY (METER) ..................... 0.1000E+01 DISTRIBUTION COEFFICIENT, KD (M**3/KG) ............ 0.0000E+00 HEAT EXCHANGE COEFFICIENT (KCAL/HR-M**2-DEGREE C).. 0.0000E+00 MOLECULAR DIFFUSION MULTIPLY BY POROSITY (M**2/HR) 0.0000E+00 DECAY CONSTANT (PER HOUR) ......................... 0.000OK+00 BULK DENSITY OF THE SOIL (KG/M**3) ................ 0.1350E+04 ACCURACY TOLERANCE FOR REACHING STEADY STATE ...... 0.1000E-01 DENSITY OF WATER (KG/M**3) ........................ 0.1000E+04 TIME INTERVAL SIZE FOR THE DESIRED SOLUTION (HR) .. 0.7300E+03 DISCHARGE TIME (HR) ............................... 0.8672E+06 WASTE RELEASE RATE (KCAL/HR), (KG/HR), OR (CI/HR). 0.0000E+00 LIST OF TRANSIENT SOURCE RELEASE RATE 0.000E+00 0.000E+00 0.000E+00 0.00OK+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 O.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 O.000E+00 0.000E+00 0.000E+00 0.000E+00 0.O00E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.00OK+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.00OK+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+.00 -, 0.000E+00 0.000E+00 0.000E+00 0.000E+00 O.O00E+00 O.O00E+O0 O.OOOE+OO O.O00E+O0 O.O00E+OO O.O00E+O0 O.OOOE+OO O.O00E+OO O.OOOE+00 O.OOOE+O0 O.000E+O0 O.O00E+00 O.OOOE+O0 O.O00E+O0 O.O00E+00 O.O00E+OO O.O00E+O0 O.O00E+O0 O.(X)OE+O0 O.O00E+00 O.O00E+00 O.O00E+O0 O.OOOE+O0 O.O00E+O0 O.O00E+00 O.00OE+O0 O.000E+OO O.000E+OO O.O00E+O0 O.O00E+O0 O.000E+OO O.000E+00 O.000E+O0 O.O00E+O0 O.O00E+O0 O.000E+O0 O.O00E+O0 O.OOOE+O0 O.O00E+O0 O.OOOE+00 O.000E+00 O.O00E+00 O.O00E+O0 O.O00E+O0 O.OOOE+00 O.O00E+OO O.OOOE+OO O.OOOE+O0 O.O00E+O0 O.OOOE+00 O.O00E+O0 O.(XX)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+00 O.000E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+OO O.0(X)E+O0 O.O00E+O0 O.0(X)E+O0 O.000E+00 O.0(X)E+00 O.O00E+00 O.000E+00 O.000E+00 O.000E+OO O.O00E+O0 O.O(X)E+00 O.OOOE+OO O.O00E+OO O.000E+O0 O.OOOE+O0 O.OOOE+O0 O.000E+00 O.O00E+O0 O.O00E+OO O.O(X)E+O0 O.000E+00 O.OOOE+00 O.OOOE+O0 O.O00E+00 O.O00E+00 O.000E+O0 O.O00E+O0 O.OOOE+O0 O.000E+00 O.000E+OO O.O00E+00 O.O(X)E+O0 O.O00E+O0 O.000E+00 O.O00E+O0 O.O00E+00 O.O00E+O0 O.O00E+O0 O.O00E+00 O.000E+00 O,O00E+O0 O.O00E+OO O.000E+OO O.0OOE+O0 O.OOOE+00 O.OOOE+O0 O.OOOE+00 O.OOOE+O0 O.O00E+00 O.000E+O0 O.O00E+O0 O.OOOE+OO O.O(X)E+O0 O.OOOE+O0 O.O00E+O0 O.OOOE+OO 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O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 o.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O,O00E+O0 O.O00E+O0 O.O(X)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O(X)E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O,O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O,O00E+O0 O.O00E+O00.O00E+O0 0.288E-10 0.389E-10 0.434E-10 0.521E-10 0.588E-10 0.661E-10 0.630E-10 0.549E-10 0.451E-10 0.371E-10 0.309E-10 0.272E-10 0.269E-10 0.278E-10 0.310E-10 0.372E-10 0.420E-10 0.472E-10 0.450E-10 0.392E-10 0.323E-10 0.265E-10 0.221E-10 0.195E-10 0.192E-10 0.199E-10 0.222E-10 0.266E-10 0.300E-10 0.337E-10 0.322E-10 0.280E-10 0.230E-10 0.190E-10 0.158E-10 0.139E-10 0.138E-10 0.142E-10 0.158E-10 0.190E-10 0.214E-10 0.241E-10 0.230E-10 0.200E-10 0.165E-10 0.135E-10 0.113E-10 0.994E-11 0.983E-11 0.101E-10 0.113E-10 0.136E-10 0.153E-10 0.172E-10 0.164E-10 0.143E-10 0.118E-10 0.968E-11 0.806E-11 0.710E-11 0.702E-11 0.725E-11 0.809E-11 0.971E-11 0.109E-10 0.123Eo10 0o117E-10 0.102E-10 0.841E-11 0.691E-11 0.576E-11 0.507E-11 0.502E-11 0.518E-11 0.578E-11 0.694E-11 0.782E-11 0.879E-11 0.839E-11 0.731E-11 0.601E-11 0.494E-11 0.411E-11 0.363E-11 0.358E-11 0.370E-11 0.413E-11 0.496E-11 0.559E-11 0.628E-11 0.599Eoll 0.522E-11 0.429E-11 0.353E-11 0.294E-11 0.259E-11 0.256E-11 0.265E-11 0.295E-11 0.354E-11 0.400E-11 0.449E-11 0.428E-11 0.373E-11 0.307E-11 0.252E-11 0.210E-11 0.185E-11 0.183E-11 0.189E-11 0.211E-11 0.253E-11 0.285E-11 0.321E-11 0.306E-11 0.266E-11 0.219E-11 0.180E-11 0.150E-11 0.132E-11 0.131E-11 0.135E-11 0.151E-11 0.181E-11 0.204E-11 0.229E-11 0.219E-11 0.190E-11 0.157E-11 0.129E-11 0.107E-11 0.944E-12 0.934E-12 0.964E-12 0.108E-11 0.129E-11 0.146E-11 0.164E-11 0.156E-11 0.136E-11 0.112E-11 0.920E-12 0.765E-12 0.674E-12 0.667E-12 0.688E-12 0.768E-12 0.922E-12 0.104E-11 0.117E-11 0o111E-11 0.969E-12 0.798E-12 0.656E-12 0.546E-12 0.481E-12 0.475E-12 0.491E-12 0.547E-12 0.657E-12 0.741E-12 0.832E-12 0.793E-12 0.690E-12 0.567E-12 0.467E-12 0.389E-12 0.342E-12 0.338E-12 0.349E-12 0.390E-12 0.468E-12 0.528E-12 0.593E-12 0.565E-12 0.492E-12 0.404E-12 0.332E-12 0.277E-12 0.244E-12 0.241E-12 0.249E-12 0.277E-12 0.332E-12 0.375E-12 0.421E-12 0.401E-12 0.349E-12 0.288E-12 0.237E-12 0.198E-12 0.174E-12 0.172E-12 0.177E-12 0.197E-12 0.236E-12 0.267E-12 0.300E-12 0.285E-12 0.248E-12 0.204E-12 0.169E-12 0.141E-12 0.124E-12 0.123E-12 0.127E-12 0.141E-12 0.169E-12 0.190E-12 0.212E-12 0.202E-12 0.175E-12 0.143E. 12 0.118E-12 0.978E-13 0.862E-13 0.851E-13 0.879E-13 0.986E-13 0.119E-12 0.135E-12 0.153E-12 0.146E-12 0.128E-12 0.106E-12 0.873E-13 0.729E-13 0.644E-13 0.637E-13 0,658E-13 0.733E-13 0.879E-13 0.990E-13 0.111E-12 0.105E-12 0.915E-13 0.749E-13 0.613E-13 0.506E-13 0.443E-13 0.433E-13 0.442E-13 0.490E-13 0.585E-13 0.655E-13 0.731E-13 0.693E-13 0.601E-13 0.492E-13 0.402E-13 0.335E-13 0.295E-13 0.291E-13 0.300E-13 0.334E-13 0.399E-13 0.448E-13 0.501E-13 0.474E-13 0.410E-13 0.334E-13 0.272E-13 0.224E-13 0.199E-13 0.202E-13 0.214E-13 0.245E-13 0.301E-13 0.342E-13 0.387E-13 0.372E-13 0.329E-13 0.278E-13 0.234E-13 0.201E-13 0.181E-13 0.184E-13 0.195E-13 0.223E-13 0.275E-13 0.318E-13 0.366E-13 0.354E-13 0.315E-13 0.266E-13 0.224E-13 0.192E-13 0.174E-13 0.176E-13 0.187E-13 0.214E-13 0.264E-13 0.305E-13 0.352E-13 0.344E-13 0.308E-13 0.261E-13 0.220E-13 0.188E-13 0.170E-13 0.173E-13 0.183E-13 0.210E-13 0.259E-13 0.299E-13 0.345E-13 0.337E-13 0.302E-13 0.255E-13 0.216E-13 0.185E-13 0.167E-13 0.170E-13 0.180E-13 0.206E-13 0.254E-13 0.293E-13 0.338E-13 0.330E-13 0.296E-13 0.250E-13 0.211E-13 0.181E-13 0.164E-13 0.166E-13 0.176E-13 0.202E-13 0.249E-13 0.288E-13 0.333E-13 0.326E-13 0.292E-13 0.247E-13 0.209E-13 0.179E-13 0.162E-13 0.164E-13 0.174E-13 0.199E-13 0.245E-13 0.284E-13 0.329E-13 0.321E-13 0.288E-13 0.243E-13 0.206E-13 0.176E-13 0.159E-13 0.162E-13 0.171E-13 0.196E-13 0.242E-13 0.280E-13 0.324E-13 0.318E-13 0.285E-13 0.241E-13 0.204E-13 0.174E-13 0.158E-13 0.160E-13 0.170E-13 0.194E-13 0.239E-13 0.277E-13 0.320E-13 0.314E-13 0.282E-13 0.238E-13 0.202E-13 0.173E-13 0.156E-13 0.158E-13 0.168E-13 0.192E-13 0.237E-13 0.274E-13 0.317E-13 0.311E-13 0.278E-13 0.236E-13 0.199E-13 0.171E-13 0.154E-13 0.157E-13 0.166E-13 0.190E-13 0.234E-13 0.271E-13 0.313E-13 0.308E-13 0.276E-13 0.233E-13 0.197E-13 0.169E-13 0.153E-13 0.155E-13 0.164E-13 0.188E-13 0.231E-13 0.268E-13 0.310E-13 0.304E-13 0.272E-13 0.231E-13 0.195E-13 0.166E-13 0.151E-13 0.153E-13 0.162E-13 0.185E-13 0.228E-13 0.264E-13 0.305E-13 0.300E-13 0.268E-13 0.227E-13 0.192E-13 0.164E-13 0.149E-13 0.151E-13 0.159E-13 0.183E-13 0.225E-13 0.260E-13 0.301E-13 0.295E-13 0.264E-13 0.224E-13 0.189E-13 0.162E-13 0.146E-13 0.148E-13 0.157E-13 0.180E-13 0.221E-13 0.256E-13 0.296E-13 0.291E-i3 0.260E-13 0.220E-13 0.187E-13 0.159E-13 0.144E-13 0.146E-13 0.155E-13 0.177E-13 0.218E-13 0.252E-13 0.291E-13 0.286E-13 0.256E-13 0.217E-13 0.184E-13 0.157E-13 0.142E-13 0.144E-13 0.152E-13 0.174E-13 0.214E-13 0.248E-13 0.287E-13 0.281E-13 0.252E-13 0.213E-13 0.179E-13 0.153E-13 0.139E-13 0.140E-13 0.149E-13 0.170E-13 0.209E;13 0.242E-13 0.280E-13 0.275E-13 0.246E-13 0.207E-13 0.175E-13 0.149E-13 0.135E-13 0.137E-13 0.145E-13 0.166E-13 0.204E-13 0.236E-13 0.273E-13 0.268E-13 0.240E-13 0.202E-13 0.171E-13 0.146E-13 0.132E-13 0.134E-13 0.142E-13 0.162E-13 0.199E-13 0.230E-13 0.266E-13 0.261E-13 0.234E-13 0.197E-13 0.166E-13 0.142E-13 0.129E-13 0.131E-13 0.139E-13 0.159E-13 0.196E-13 0.226E-13 0.261E-13 0.256E-13 0.230E-13 0.194E-13 0.164E-13 0.140E-13 0.127E-13 0.129E-13 0.136E-13 0.156E-13 0.192E-13 0.222E-13 0.257E-13 0.252E-13 0.226E-13 0.190E-13 0.161E-13 0.137E-13 0.124E-13 0.126E-13 0.134E-13 0.153E-13 0.189E-13 0.218E-13 0.252Eo13 0.247E-13 0.222E-13 0.187Eo13 0.158E-13 0.135E-13 0.122E-13 0.124E-13 0.132Eo13 0.150E-13 0.185E-13 0.214E-13 0.247E-13 0.243E-13 0.218E-13 0.184E-13 0.155E-13 0o132E-13 0.120E-13 0.122E-13 0.129E-13 0.148E-13 0.182E-13 0.210E-13 0.243E-13 0.238E-13 0.214Eo13 0.180E-13 0.152E-13 0.130E-13 0.118E-13 0.120E-13 0.127E-13 0.145Eo13 0.178E-13 0.206E-13 0.238E-13 0.233E-13 0.209E-13 0.177E.13 0.149E-13 0.128E-13 0.116E-13 0.118E-13 0.124E-13 0.142E-13 0.175E-13 0.202E-13 0.233E-13 0.229E-13 0.205E-13 0.173E-13 0.147E-13 0.125E-13 0.113E-13 0.115E-13 0.122E-13 0.139E-13 0.172E-13 0.198E-13 0.229E-13 0.224E-13 0.201E-13 0.170E-13 0.144E-13 0.123E-13 0.111E-13 0.113E-13 0.120E-13 O.137E-13'O.168E-13 0.195E-13 0.224E-13 0.220E-13 0.197E-13 0.166E-13 0.141E-13 0.120E-13 0.109E-13 0.111E-13 0.117Eo13 0.134E-13 0.165E-13 0.190E-13 0.219E-13 0.215E-13 0.193E-13 0.163E-13 0.138E-13 0.118E-13 0.106E-13 0.108E-13 0.114E-13 0.130E-13 0.161E-13 0.185E-13 0.214E'13 0.210E-13 0.188E-13 0.159E-13 0.134E-13 0.115E-13 0.104E-13 RETARDATION FACTOR ................................ 0.1000E+01 RETARDED DARCY VELOCITY (M/HR) .................... 0,3333E~1 RETARDED LONGITUDINAL DISPERSION COEF. (M**2/HR)., 0.1000E+01 RETARDED LATERAL DISPERSION COEFFICIENT (M**2/HR). 0,3333E+00 RETARDED VERTICAL DISPERSION COEFFICIENT (M**2/HR), 0,3333E~)1 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.0000E+00 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z= 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.CKX)E+00 0.000E+00 0.0(X)E+00 0. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.0(X)E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.0(X)E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.CXX)E+00 0.000E+00 0.000E+00 0.000E+00 Z-- 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.0(X)E+00 0.0(X)E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.3942E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 50. 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.0(X)E+00 0. 0.(XXIE+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 O. 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 15.00 X Y O. 100. 200. 300. 400. 500. 100. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 20.00 X Y O. 100. 200. 300. 400. 500. 100. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0. 0.IXX)E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.4380E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0,305E-10 0.925E-10 0.130E-09 0.140E-09 0.147E-09 0.154E-09 50. 0.204E-09 0.377E-09 0.337E-09 0.267E-09 0.235E-09 0.224E-09 0. 0.900E-09 0.772E-09 0.488E-09 0.339E-09 0.278E-09 0.255E-09 -50. 0.204E-09 0.377E-O9 0.337E-09 0.267E-09 0,235E-09 0.224E-09 -100. 0,305E-10 0.925E-10 0.130E-09 0.140E-09 0.147E-09 0.154E-O9 Z= 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.292E-10 0.890E-10 0.126E-09 0.137E-09 0.145E-09 0.152E-09 50. 0.183E-O9 0.355E-09 0.325E-09 0.261E-09 0.232E-O9 0.221E-09 0. 0.747E-09 0.707E-09 0.470E-09 0.331E-09 0.273E-09 0.251E-09 -50. 0.183E-09 0.355E-09 0.325E-09 0.261E-09 0.232E-09 0.221E-09 -100. 0.292E-10 0.890E-10 0.126E-09 0.137E-09 0.145E-09 0.152E..09 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.256E-10 0.794E-10 0.116E-09 0.129E-09 0.139E-09 0.146E-09 50. 0.138E-09 0.300E-09 0.293E-09 0.244E-09 0.221E-09 0.213E-09 0. 0.448E-09 0.559E-09 0.419E-09 0.308E-09 0.260E-09 0.242E-09 -50. 0.138E-09 0.300E-09 0.293E-09 0.244E-09 0.221E-09 0.213E-09 -100. 0.256E-10 0.794E-10 0.116E-09 0.129E-09 0.139E-09 0.146E-09 Z = 15.00 X Y O. 100. 200. 300. 400. 500. 100. 0.208E-10 0.661E-10 0.101E-09 0.117E-09 0.129E-09 0.138E-09 50. 0.940E-10 0.231E-09 0.247E-09 0.218E-09 0,204E-O9 0.200E-09 0. 0.227E.O9 0.400E-09 0.349E-09 0.273E-09 0.239E-09 0.227E-09 -50. 0.940E-10 0.231E-09 0.247E-09 0.218E-09 0.204E-09 0.200E-09 -100. 0.208E-10 0.661E-10 0.101E-09 0.117E-09 0.129E-09 0.138E-09 Z = 20.00 X Y O. 100. 200. 300. 400, 500. 100. 0.158E-10 0.518E-10 0.839E-10 0.102E-09 0.116E-09 0.126E-09 50, 0.611E-10 0.166E..09 0.197E-09 0.187E-09 0.182E-09 0.183E-09 0. 0.117E-09 0.269E-09 0.273E-09 0.233E-09 0.214E-09 0.207E-09 -50. 0.611E-10 0.166E..09 0.197E-09 0.187E-09 0.182E-09 0.183E-09 -100. 0.158E-10 0.518E-10 0.839E-10 0.102E-09 0.116E-09 0.126E-09 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.4818E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y O. 100. 200. 300. 400. 5(X). 100. 0,568E-11 0.172E-10 0,242E-10 0,260E-10 0.275E-10 0,289E-10 50. 0.380E-10 0.702E-10 0.628E-10 0.498E-10 0.440E-10 0.420E-10 0. 0.168E-09 0.144E-09 0.910E-10 0.632E-10 0.518E-10 0.478E-10 -50. 0.380E-10 0.702E-10 0,628E-10 0.498E-10 0.440E-10 0.420E-10 -100. 0.568E-11 0.172E-10 0,242E-10 0,260E-10 0.275E-10 0.289E-10 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0,544E-11 0.166E-10 0.235E-10 0,255E-10 0.271E-10 0.286E-10 50. 0,341E-10 0.662E-10 0.606E-10 0,487E-10 0,432E-10 0,415E-10 0. 0,139E-09 0,132E-09 0.875E-10 0.617E-10 0.510E-10 0.472E-10 -50. 0.341E-10 0.662E-10 0.606E-10 0.487E-10 0.432E-10 0,415E-10 -100. 0.544E-11 0.166E-10 0.235E-10 0,255E-10 0.271E-10 0.286E-10 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. 0.477E-11 0.148E-10 0.216Eo10 0,240E-10 0,259E-10 0.275E-10 50. 0,257E-10 0,559E-10 0,546E-10 0.454E-10 0.412E-10 0.399E-10 0. 0.834E-10 0.104E-09 0,781E-10 0,574E-10 0.485E-10 0.454E-10 -50. 0,257E-10 0,559E-10 0.546E-10 0.454E-10 0.412E-10 0.399E-10 -100. 0.477E-11 0.148E-10 0.216E-10 0,240E-10 0.259E-10 0.275E-10 Z = 15.00 X Y O. 100. 200. 300. 400. 500. 100. 0.387E-11 0.123E-10 0.188E-10 0.218E-10 0.240E-10 0.259E-10 50. 0.175E-10 0,431E-10 0,461E-10 0,406E-10 0.380E-10 0,375E-10 0. 0,422E-10 0.745E-10 0.650E-10 0,510E-10 0.447E-10 0,426E-10 -50. 0.175E-10 0.431E-10 0.461E-10 0.406E-10 0,380E-10 0.375E-10 -100, 0,387E-11 0,123E-10 0,188E-10 0,218E-10 0,240E-10 0,259E-10 Z = 20.00 X Y 0. 100. 200. 300. 4(X:). 500. 100. 0.294E-11 0,964E-11 0.156E-10 0,190E-10 0.217E-10 0,238E-10 50. 0.114E-10 0.309E-10 0.368E-10 0.348E-10 0.341E-10 0.344E-10 0. 0.217E-10 0,502E-10 0.510E-10 0.434E-10 0,399E-10 0,389E-10 -50. 0.114E-10 0.309E-10 0.368E-10 0.348E-10 0.341E-10 0.344E-10 -100. -0,294E-11 0.964E-11 0.156E-10 0.190E-10 0.217E-10 0.238E-10 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.5256E+06 HRS (ADSORBED CHEMICAL CONC, = 0,0(X)0E+00 * DISSOLVED CHEMICAL CONC.) Z - 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.105E-11 0.319E-11 0.449E-11 0.483E-11 0.511E-11 0.537E-11 50. 0.703E-11 0.130E-10 0.116E-10 0.924E-11 0.816E-11 0.781E-11 O. 0.310E-10 0.266E-10 0.169E-10 0.117E-10 0.963E-11 0.888E-11 -50. 0.703E-11 0.130E-10 0.116E-10 0,924E-11 0.816E-11 0.781E-11 -100. 0.105E-11 0.319E-11 0.449E-11 0.483E-11 0.511E-11 0.537E-11 Z = 5.00 X Y O. 100, 200. 300. 400. 500. 100. 0.101E-11 0.307E-11 0.436E-11 0.474Eoll 0.503E-11 0.531E-11 50. 0.632E-11 0.123E-10 0.112E-10 0.903E-11 0.803E-11 0,771E-11 O. 0.257E-10 0.244E-10 0.162E-10 0.114E-10 0.947E-11 0.877E-11 -50. 0.632E-11 0.123E-10 0.112E-10 0.903E-11 0.803E-11 0.771E-11 -100. 0.101E-11 0.307E-11 0.436E-11 0.474E-11 0.503E-11 0.531E-11 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. 0.883E-12 0.274E-11 0.401E-11 0.446E-11 0.481E-11 0.512E-11 50. 0.476E-11 0.104E-10 0.101E-10 0.843E-11 0.765E-11 0.743E-11 O. 0.154E-10 0.193E-10 0.145E-10 0.106E-10 0.901E-11 0.844E-11 -50. 0.476E-11 0.104E-10 0.101E-10 0.843E-11 0.765E-11 0.743E-11 -100. 0.883E-12 0.274E-11 0.401E-11 0.446E-11 0.481E-11 0.512E-11 Z = 15.00 X Y O. 100. 200. ,.'..'..'..'..'..'.~0. 400. 500. 100. 0.717E-12 0.228E-11 0.349E-11 0.404Eoll 0.447E-11 0.482E-11 50. 0.324E-11 0.798E-11 0.855E-11 0.753E-11 0.707E-11 0.697E-11 O. 0,781E-11 0.138E-10 0.121E-10 0.946E-11 0,830E-11 0.791E-11 -50. 0.324E-11 0.798E-11 0.855E-11 0.753E-11 0.707E-11 0.697E-11 -100. 0.717E-12 0.228E-11 0.349E-11 0.404E-11 0.447E-11 0.482E-11 Z = 20.00 X Y O. 100. 200. 300. 400. 500. 100. 0.545E-12 0.179E-11 0.290E-11 0.353E-11 0.403E-11 0.443E-11 50, 0,211E-11 0.573E-11 0,682E-11 0,647E-11 0.633E-11 0.639E-11 O. 0.402Eoll 0.929E-11 0.945E-11 0.806E-11 0.741E-11 0.724E-11 -50. 0,211E-11 0.573E-11 0.682E-11 0.647E-11 0.633E-11 0.639E-11 -100. 0.545E-12 0.179E-11 '0.290E-11 0.353E-11 0.403E-11 0.443E-11 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.5694E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.193E-12 0.585E-12 0.817E-12 0.876E-12 0.928E-12 0.979E-12 50. 0.131E-11 0.240E-11 0.213E-11 0.168E-11 0.148E-11 0.142E-11 0. 0.581E-11 0.494E-11 0.309E-11 0.213E-11 0.175E-11 0.162E-11 -50. 0.131E-11 0.240E-11 0.213E-11 0.168E-11 0.148E-11 0.142E-11 -100. 0.193E-12 0.585E-12 0.817E-12 0.876E-12 0.928E-12 0.979E-12 Z= 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.185E-12 0.562E-12 0.793E-12 0.858E-12 0.914E-12 0.968E-12 50. 0.117E-11 0.226E-11 0.205E-11 0.164E-11 0.146E-11 0.140E-11 0. 0.481E-11 0.452E-11 0.297E-11 0.208E-11 0.172E-11 0.160E-11 -50. 0.117E-11 0.226E-11 0.205E-11 0.164E-11 0.146E-11 0.14OE-11 -100. 0.185E-12 0.562E-12 0.793E-12 0.858E-12 0.914E-12 0.968E-12 Z -- 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.162E-12 0.501E-12 0.729E-12 0.808E-12 0.874E-12 0.933E-12 50. 0.883E-12 0.191E-11 0.185E-11 0.153E-11 0.139E-11 0.135E-11 0. 0.288E-11 0.356E-11 0.265E-11 0.193E-11 0.163E-11 0.154E-11 -50. 0.883E-12 0.191E-11 0.185E-11 0.153E-11 0.139E-11 0.135E-11 -100. 0.162E-12 0.501E-12 0.729E-12 0.808E-12 0.874Eo12 0.933E-12 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.131E-12 0.417E-12 0.635E-12 0.733E-12 0.811E-12 0.878E-12 50. 0.600E-12 0o147E-11 0.156E-11 0.137E-11 0.128E-11 0.127E-11 0. 0.145E-11 0.255E-11 0.220E-11 0.172E-11 0.151E-11 0.144E-11 -50. 0.600E-12 0.147E-11 0.156E-11 0.137E-11 0.128E-11 0.127E-11 -100. 0.131E-12 0.417E-12 0.635E-12 0.733E-12 0.811E-12 0.878E-12 Z = 20.00 X Y O. 100. 200. 300. 400. 500. 100. 0.997E-13 0.326E-12 0.527E-12 0.640E-12 0.732E-12 0.807E-12 50. 0.388E-12 0.105E-11 0o124E-11 0,117E-11 0.115E-11 0.116E-11 0. 0.745E-12 0.171E-11 0.172E-11 0.146E-11 0.134E-11 0.132E-11 -50. 0.388E-12 0.105E-11 0.124E-11 0.117E-11 0o115E-11 0.116E-11 -100. 0.997E-13 0.326E-12 0.527E-12 0.640E-12 0.732E-12 0.807E-12 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.6132E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z -- 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.458E-13 0.136E-12 0.180E-12 0.178E-12 0.175E-12 0.175E-12 50. 0.331E-12 0.584E-12 0.487E-12 0.352E-12 0.284E-12 0.257E-12 0. 0.153E-11 0.123E-11 0.717Eo12 0.453E-12 0.338E-12 0.293E-12 -50. 0.331E-12 0.584E-12 0.487E-12 0.352E-12 0.284E-12 0.257E-12 -100. 0.458E-13 0.136E-12 0.180E-12 0.178Eo12 0.175E-12 0.175E-12 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.437E-13 0.130E-12 0.174E-12 0.174E-12 0.172E-12 0.173Eo12 50. 0.296E-12 0.549E-12 0.469E-12 0.344E-12 0.279E-12 0.253E-12 0. 0.126E-11 0.113E-11 0.688E-12 0.441E-12 0.332E-12 0.289E-12 -50. 0.296E-12 0.549E-12 0.469E-12 0.344E-12 0.279E-12 0.253Eo12 -100. 0.437E-13 0.130E-12 0.174E-12 0.174Eo12 0.172E-12 0.173E-12 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.381E-13 0.116E-12 0.160E-12 0.163E-12 0.164E-12 0.166E-12 50. 0.220E-12 0.461E-12 0.421E-12 0.320E-12 0.266E-12 0.244E-12 0. 0.747E-12 0.880E-12 0.611E-12 0.409E-12 0.315Eo12 0.278E-12 -50. 0.220E-12 0.461E-12 0.421E-12 0.320E-12 0.266E-12 0.244E-12 -100. 0.381E-13 0.116E-12 0.160E-12 0.163E-12 0.164E-12 0.166E-12 Z -- 15.00 X · Y 0. 100. 200. 300. 400. 500. 100. 0.307E-13 0.956E-13 0.138E-12 0.147E-12 0.152E-12 0.157E-12 50. 0.147E-12 0.352E-12 0.353E-12 0.284E-12 0.244E-12 0.228E-12 0. 0.369E-12 .0.621E-12 0.505E-12 0.361E-12 0.289E-12 0.260E-12 -50. 0.147E-12 0.352E-12 0.353E-12 0.284E-12 0.244E-12 0.228E-12 -100. 0.307E-13 0.956E-13 0.138E-12 0.147E-12 0.152E-12 0.157E-12 Z = 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.231E-13 0.741E-13 0.114E-12 0.128E-12 0.137E-12 0.144E-12 50. 0.940E-13 0.249E-12 0.279E-12 0.242E-12 0.218E-12 0.209E-12 0. 0.185E-12 0.412E-12 0.392E-12 0.305E-12 0.257E-12 0.237E-12 -50. 0.940E-13 0.249E-12 0.279E-12 0.242E-12 0.218E-12 0.209E-12 -100. 0.231E-13 0.741E-13 0.114E-12 0.128E-12 0.137E-12 0.144E-12 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.6570E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y O, 100. 200. 300. 400. 500. 100. 0.413E-13 0.122E-12 0.160E-12 0.155E-12 0.146E-12 0.139E-12 50. 0.302E-12 0.530E-12 0.436E-12 0.309E-12 0.241E-12 0.207E-12 0. 0.140E-11 0.112E-11 0.644E-12 0.399E-12 0.288E-12 0.237E-12 -50. 0.302E-12 0.530E-12 0.436E-12 0.309E-12 0.241E-12 0.207E-12 -100. 0.413E-13 0.122E-12 0.160E-12 0.155E-12 0.146E-12 0.139E-12 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.394Eo13 0.117E-12 0.155E-12 0.151E-12 0.144E-12 0.137E-12 50. 0.270E-12 0.498E-12 0.420E-12 0.302E-12 0.237E-12 0.204E-12 0. 0.116Eoll 0.103E-11 0.618E-12 0.388E-12 0.283E-12 0.234E-12 -50. 0.270E-12 0.498E-12 0.420E-12 0.302E-12 0.237E-12 0.204E-12 -100. 0.394E-13 0.117E-12 0.155E-12 0.151E-12 0.144E-12 0.137E-12 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.344E-13 0.104E-12 0.141E-12 0.142Eo12 0.137E-12 0.132E-12 50. 0.200E-12 0.418E-12 0.377E-12 0.280Eo12 0.225E-12 0.196E-12 0. 0.684E-12 0.800E-12 0.549E-12 0.360E-12 0.268E-12 0.225E-12 -50. 0.200E-12 0.418E-12 0.377E-12 0.280E-12 0.225E-12 0.196E-12 -100. 0,344E-13 0.104E-12 0.141E-12 0.142E-12 0.137E-12 0.132E-12 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.276E-13 0.857E-13 0.122E-12 0.128E-12 0.127E-12 0.124E-12 50. 0.134E-12 0o318E-12 0.315E-12 0.249E-12 0.207E-12 0.183E-12 0. 0.337E-12 0.564E-12 0.453E-12 0.317Eo12 0.245E-12 0.210E-12 ;50. 0.134E-12 0.318E-12 0.315E-12 0.249E-12 0,207E-12 0.183E-12 -100. 0.276E-13 0.857E-13 0.122E-12 0.128E-12 0.127E-12 0.124E-12 Z = 20.00 X Y O. 100. 200. 300. 400. 500. 100. 0.207E-13 0.663E-13 0.100E-12 0.111E-12 0.114E-12 0.113E-12 50. 0.852E-13 0.225E-12 0.248E-12 0.211E-12 0.184E-12 0.167E-12 0. 0.168E-12 0.373E-12 0.350E-12 0.267E-12 0.218E-12 0.191E-12 -50. 0.852E-13 0.225E-12 0.248E-12 0.211E-12 0.184E-12 0.167'E-12 -100. 0.207E-13 0.663E-13 0.100E-12 0.111E-12 0.114E-12 0.113E-12 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.7008E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y O. 100. 200. ,300. 400. 500. 100, 0.391E-13 0.115E-12 0,151E-12 0.146E-12 0.138E-12 0,131E-12 50. 0.285E-12 0.502E-12 0.412E-12 0.292E-12 0.228E-12 0.195E-12 0. 0.133E-11 0.106E-11 0.609E-12 0.376E-12 0.271E-12 0.224E-12 -50. 0.285E-12 0.502E-12 0.412E-12 0.292E-12 0.228E-12 0.195E-12 -100. 0.391E-13 0.115E-12 0.151E-12 0.146E-12 0.138E-12 0.131E-12 Z = 5.00 X Y 0. 100. 200. 300. 400. 500, 100, 0.373E-13 0.111E-12 0.146E-12 0.143E-12 0.136E-12 0.129E-12 50. 0,255E-12 0.471E-12 0.397E-12 0.285E-12 0.224E-12 0,192E-12 0. 0.109E-11 0.970E-12 0.585E-12 0,367E-12 0.267E-12 0,220E-12 °50. 0.255E-12 0.471E-12 0.397E-12 0.285E-12 0,224E-12 0.192E-12 -100. 0.373E-13 0.111E-12 0.146E-12 0.143E-12 0.136E-12 0.129E-12 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. 0.325E-13 0,982E-13 0.134E-12 0.134E-12 0.130E-12 0.124E-12 50. 0.190E-12 0.395E-12 0.356E-12 0.265E-12 0.212E-12 0.185E-12 0. 0.647E-12 0.757E-12 0.519E-12 0.339E-12 0.253E-12 0.212E-12 -50. 0.190E-12 0.395E-12 0.356E-12 0.265E-12 0.212E-12 0.185E-12 -100. 0,325Eo13 0.982E-13 0,134E-12 0.134E-12 0.130E-12 0.124E-12 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.261E-13 0.810E-13 0.115E-12 0,120E-12 0.120E-12 0.117E-12 50. 0.127E-12 0.301E-12 0.298E-12 0.235E-12 '0.195E-12 0.173Eo12 0. 0.319E-12 0.533E-12 0.428E-12 0.299E-12 0.232E-12 0.198E-12 -50, 0.127E-12 0.301E-12 0.298E-12 0.235E-12 0.195E-12 0.173E-12 -100. 0.261E-13 0.810E-13 0.115E-12 0.120E-12 0.120E-12 0.117E-12 Z -- 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.196E-13 0,626E-13 0.948E-13 0,104E-12 0.107E-12 0.107E-12 50. 0.806E-13 0.213E-12 0.235E-12 0.199E-12 0.173E-12 0.157E-12 0. 0.159E-12 0.353E-12 0.331E-12 0.252E-12 0.205E-12 0.180E-12 -50. 0,806E-13 0.213E-12 0.235E-12 0,199E-12 0.173E-12 0.157E-12 -100. 0.196E-13 '0.626E-13 0.948E-13 0.104E-12 0.107E-12 0.107E-12 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.7446E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0(XX)E+00 * DISSOLVED CHEMICAL CONC.) Z= 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.361E-13 0.107E-12 0.14OE-12 0.135E-12 0.128E-12 0.122E-12 50. 0.263E-12 0.463E-12 0.382E-12 0.271E-12 0.212E-12 0.182E-12 0. 0.122E-11 0.980E-12 0.564E-12 0.349E-12 0.252E-12 0.208E-12 -50. 0.263E-12 0.463E-12 0.382E-12 0.271E-12 0.212E-12 0.182E-12 -100. 0.361E-13 0.107E-12 0.140E-12 0.135E.12 0.128E-12 0.122E-12 Z = 5.00 X Y O. 100. 200. 300. 400. 500. 100. 0,345E-13 0.103E-12 0.136E-12 0.133E-12 0.126E-12 0.120E-12 50. 0.235E-12 0.436E-12 0.368E-12 0.264E-12 0.208E-12 0.179E-12 0. 0.101E-11 0.895E-12 0.541E-12 0.340E-12 0.248E-12 0.205E-12 -50. 0.235E-12 0.436E-12 0.368E-12 0.264E-12 0.208E-12 0.179E-12 -100. 0.345E-13 0.103E-12 0.136E-12 0.133E-12 0.126E-12 0.120E-12 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.301E-13 0.909E-13 0.124E-12 0.124E-12 0.120E-12 0.116E-12 50. 0.175E-12 0.365E-12 0.330E-12 0.246E-12 0.198E-12 0.172E-12 0. 0.595E-12 0.699E-12 0.480E-12 0.315E-12 0.235E-12 0.197E-12 -50. 0.175E-12 0.365E-12 0.330E-12 0.246E-12 0.198E-12 0.172E-12 -100. 0.301E-13 0.909E-13 0.124E-12 0.124E-12 0.120E-12 0.116E-12 Z = 15,00 X Y 0. 100. 200. 300. 400. 500. 100. 0.242E-13 0.750E-13 0.107E-12 0.112E-12 0.111E-12 0.109E-12 50. 0.117E-12 0.278E-12 0.276E;12 0.218E-12 0.181E-12 0.161E-12 0. 0.294E-12 0.492E-12 0.396E-12 0.278E-12 0.215E-12 0.184E-12 -50. 0.117E-12 0.278E-12 0.276E-12 0.218E-12 0.181E-12 0.161E-12 -100. 0.242E-13 0.750E-13 0.107E-12 0.112E-12 0.111Eo12 0.109E-12 Z = 20.00 X Y 0, 100. 200. 300. 400, 500. 100. 0.181E-13 0,580E-13 0.879E-13 0.969E-13 0.998E-13 0.993E-13 50. 0.745E-13 0.197E-12 0.217E-12 0.185E-12 0.161E-12 0.147Eo12 0. 0.147E-12 0.326E-12 0.306E-12 0.234E-12 0.191E-12 0.167E-12 -50. 0.745E-13 0.197E-12 0.217E-12 0.185E-12 0.161E-12 0.147E-12 -100. 0.181E-13 0.580E-13 0.~79E-13 0.969E-13 0.998E-13 0.993E-13 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.7884E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400, 500. 100. 0.323E-13 0.956E-13 0.125E-12 0.121E-12 0.115Eo12 0.109E-12 50. 0.236E-12 0.415E-12 0.342E-12 0.242E-12 0.189E-12 0.163E-12 0. 0.109E-11 0.878E-12 0.504E-12 0.313E-12 0.226E-12 0.186E-12 -50. 0.236E-12 0.415E-12 0.342E-12 0.242E-12 0.189E-12 0,163E-12 -100. 0.323E-13 0.956E-13 0.125E-12 0.121E-12 0.115E-12 0.109E-12 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.309E-13 0.918E-13 0.121E-12 0.119E-12 0.113E-12 0.108E-12 50. 0.211E-12 0.390E-12 0.329E-12 0.237E-12 0.186E-12 0.161E-12 0. 0.904E-12 0.802E-12 0.484E-12 0.304E-12 0.222E-12 0.184E-12 -50. 0.211E-12 0.390E-12 0.329E-12 0.237E-12 0.186E-12 0.161E-12 -100. 0.309E-13 0.918E-13 0.121E-12 0.119E-12 0.113Eo12 0.108E-12 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. 0.269E-13 0.814E-13 0.111E-12 0.111E-12 0.108E-12 0.104E-12 50. 0.157E-12 0.327E-12 0.295E-12 0.220E-12 0.177E-12 0.154E-12 0. 0.534E-12 0.626E-12 0.430E-12 0.282E-12 0.210E-12 0.177E. 12 -50. 0.157E-12 0.327E-12 0.295E-12 0.220E-12 0.177E-12 0.154E-12 -100. 0.269E-13 0.814E-13 0.111E-12 0.111E-12 0.108E-12 0.104E-12 Z = 15.00 X Y 0o 100. 200. 300. 400. 500. 100. 0.216E-13 0.671E-13 0.958E-13 0.100E-12 0.997E-13 0.974E-13 50. 0.105E-12 0.249E-12 0.247E-12 0.195E-12 0.162E-12 0.144E-12 0. 0.263E-12 0.441E-12 0.355E-12 0.248E-12 0.193E-12 0.165E-12 -50. 0.105E-12 0.249E-12 0.247E-12 0.195Eo12 0.162E-12 0.144E-12 -100. 0.216E-13 0.671E-13 0.958E-13 0.100E-12 0.997E-13 0.974E-13 Z = 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.162E-13 0.519E-13 0.787E-13 0.867E-13 0.894E-13 0.890E-13 50. 0.667E-13 0.176E-12 0.195E-12 0.165E-12 0.144E-12 0.131Eo12 0. 0.131E-12 0.292E-12 0.274E-12 0.209E-12 0.171E-12 0.150E-12 -50. 0.667E-13 0.176E-12 0.195E-12 0.165E-12 0,144E-12 0,131E-12 -100. 0.162E-13 0.519E-13 0.787E-13 0.867E-13 0.894E-13 0.890E-13 STEADY STATE SOLUTION HAS NOT BEEN REACHED BEFORE FINAL SIMULATING TIME DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.8322E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.295E-13 0.870E-13 0.114E-12 0.111E-12 0.105E-12 0.998E-13 50. 0.215E-12 0.378E-12 0.311E-12 0.221E-12 0.173E-12 0.148E-12 0. 0.997E-12 0.800E-12 0.459E-12 0.285E-12 0.206E-12 0.170E-12 -50. 0.215Eo12 0.378E-12 0.311E-12 0.221E-12 0.173E-12 0.148E-12 -100. 0.295E-13 0.870E-13 0.114E-12 0.111E-12 0.105E-12 0.998E-13 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.281E-13 0.836E-13 0.111E-12 0,108E-12 0.103E-12 0.985E-13 50. 0,192E-12 0.355E-12 0.300Eo12 0,216E-12 0.170E-12 0.146E-12 0. 0.823E-12 0.730Eo12 0.441E-12 0.278E-12 0.202E-12 0.168E-12 -50. 0.192E-12 0.355E-12 0.300E-12 0.216E-12 0.170E-12 0.146E-12 -100. 0.281E-13 0.836E-13 0.111E-12 0.108E-12 0.103E-12 0.985E-13 Z = 10.00 X Y 0. 100. 200, 300. 400. 500. 100. 0.245E-13 0.741E-13 0.101Eo12 0.101E-12 0.984E-13 0,947E-13 50. 0.143E-12 0.298E-12 0.269E-12 0.200E-12 0.161E-12 0.141E-12 0. 0.486E-12 0.570E-12 0.391E-12 0.257E-12 0.192E-12 0.161E-12 -50. 0.143E-12 0.298E-12 0.269E-12 0,200E-12 0.161E-12 0.141E-12 -100. 0.245E-13 0.741E-13 0.101E-12 0.101E-12 0.984E-13 0.947E-13 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.197E-13 0.611E-13 0.873E-13 0.913E-13 0.909E-13 0.888E-13 50. 0.954Eo13 0.227E-12 0.225E-12 0.178E-12 0.148E-12 0.132E-12 0. 0.240E-12 0.402E-12 0.323E-12 0.226E-12 0.176Eo12 0.150E-12 -50. 0.954E-13 0.227E-12 0.225E-12 0.178E-12 0.148E-12 0.132E-12 -100. 0.197E-13 0.611E-13 0.873E-13 0.913E-13 0.909E-13 0.888E-13 Z= 20.00 X Y O. 100. 200. 300. 400. 500. 100, 0.148E-13 0.473E-13 0,717E-13 0.791E-13 0.815E-13 0.812E-13 50. 0.607E-13 0.160E-12 0.177E-12 0.151E-12 0.132E-12 0.120E-12 0. 0.120E-12 0.266E-12 0.250E-12 0.191E-12 0.156E-12 0.137E-12 -50. 0.607E-13 0.160E-12 0.177E-12 0.151E-12 0.132E-12 0.120E-12 -100. 0.148E-13 0.473E-13 0.717E-13 0.791E-13 0.815E-13 0.812E-13 AT123D OUTPUT FOR XYLENES AT ARCO 6218 NO. OF POINTS IN X-DIRECTION ...................... 6 NO. OF POINTS IN Y-DIRECTION ...................... 5 NO. OF POINTS IN Z-DIRECTION ...................... 5 NO. OF ROOTS: NO. OF SERIES TERMS ................. 400 NO. OF BEGINNING TIME STEP ........................ 61 NO. OF ENDING TIME STEP ........................... 1189 NO. OF TIME INTERVALS FOR PRINTED OUT SOLUTION .... 60 INSTANTANEOUS SOURCE CONTROL = 0 FOR INSTANT SOURCE SOURCE CONDITION CONTROL = 0 FOR STEADY SOURCE .... 1188 INTERMITTENT OUTPUT CONTROL = 0 NO SUCH OUTPUT .... 1 CASE CONTROL -- 1 THERMA~ = 2 FOR CHEMICN~ -- 3 RAD 2 AQUIFER DEPTH. = 0.0 FOR INFINITE DEEP (METERS) ... 0.00(X)E+00 AQUIFER WIDTH, = 0.0 FOR INFINITE WIDE (METERS) ... 0.0000E+00 BEGIN POINT OF X-SOURCE LOCATION (METERS) ......... -0.3811E +01 END POINT OF X-SOURCE LOCATION (METERS) ........... 0.3811E+01 BEGIN POINT OF Y-SOURCE LOCATION (METERS) ......... -0.3811E+01 END POINT OF Y-SOURCE LOCATION (METERS) ........... 0.3811E+01 BEGIN POINT OF Z-SOURCE LOCATION (METERS) ......... 0.0000E+00 END POINT OF Z-SOURCE LOCATION (METERS) ........... 0.00(X)E+00 POROSITY .......................................... 0.3000E+00 HYDRAULIC CONDUCTIVITY (METER/HOUR) ............... 0.1000E+01 HYDRAULIC GRADIENT ................................ 0.1000E-01 LONGITUDINAL DISPERSMTY (METER) ................. 0.3000E+02 LATERAL DISPERSIVlTY (METER) ...................... 0.1000E+02 VERTICAL DISPERSIVITY (METER) ..................... 0.1(XX)E+01 DISTRIBUTION COEFFICIENT, KD (M**3/KG) ............ 0.0(X)OE+00 HEAT EXCHANGE COEFFICIENT (KCAL/HR-M**2-DEGREE C).. 0.0(X)0E+00 MOLECULAR DIFFUSION MULTIPLY BY POROSITY (M**2/HR) 0.0000E+00 DECAY CONSTANT (PER HOUR) ......................... 0.0000E+00 BULK DENSITY OF THE SOIL (KG/M**3) ................ 0.1350E+04 ACCURACY TOLERANCE FOR REACHING STEADY STATE ...... 0.1000E-01 DENSITY OF WATER (KG/M**3) ........................ 0.1000E+04 TIME INTERVAL SIZE FOR THE DESIRED SOLUTION (HR) .. 0.7300E+03 DISCHARGE TIME (HR) ............................... 0.8672E+06 WASTE RELEASE RATE (KCAL/HR), (KG/HR), OR (Cl/HR). 0.0000E+00 LIST OF TRANSIENT SOURCE RELEASE RATE 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E'+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+O0 O.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.00OE+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 O.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 O.000E+00 O.OOOE+O0 O.O00E+00 O.O00E+O0 O.O00E+00 O.OOOE+00 O.O00E+O0 O.000E+O0 O.000E+O0 O.O00E+O0 O.O00E+O0 O.0OOE+OO O.O00E+O0 O.O00E+00 O.O00E+O0 O.O00E+00 O.000E+O0 O.0(X)E+00 O.00OE+OO O.O00E+O0 O.OOOE+O0 O.O00E+O0 O.OOOE+O0 O.O00E+O0 O.00OE+OO O.O00E+OO O.(XX)E+OO O.000E+O0 O.OOOE+OO O.OOOE+O0 O.OOOE+OO O.000E+O0 O.O00E+O0 O.O00E+O0 O.O00E+O0 O.0(X)E+OO O.O00E+O0 O.O00E+00 O.(XX)E+OO O.O00E+00 O.O00E+O0 O.OOOE+O0 O.(XX)E+00 O.000E+O0 O.O00E+00 O.O00E+O0 O.000E+O0 O.000E+OO O.OOOE+OO O.O00E+O0 O.0(X)E+00 O.000E+00 O.O00E+O0 O.000E+O0 O.O(X)E+00 O.O00E+O0 O.000E+O0 O.O00E+O0 O.O00E+O0 O.000E+O0 O.O00E+O0 O.O(X)E+00 0.000E+O0 O.(XX)E+OO O.0OOE+O0 O.O00E+O0 O.O00E+O0 O.0OOE+OO O.OOOE+O0 O.O00E+O0 O.O00E+OO O.0(X)E+O0 O.O00E+00 O.O00E+00 O.O00E+O0 O.000E+00 O.000E+O0 O.000E+00 O.000E+O0 O.000E+00 O.00OE+00 O.000E+00 O.000E+O0 O.O00E+O0 O.OOOE+O0 O.O00E+O0 O.O00E+00 O.O00E+OO O.O00E+O0 O.O00E+O0 O.O00E+OO O.000E+OO O.OOOE+O0 O.OOOE+O0 O.O00E+O0 O.OOOE+O0 O.O00E+OO O.OOOE+OO O.OOOE+OO O.OOOE+OO O.OOOE+O0 O.O00E+O0 O.O00E+OO O.O00E+O0 O.OOOE+OO O.O00E+00~ O.O00E+O0 O,OOOE+O0 O.OOOE+O0 O.O00E+O0 O.000E+00 O.OOOE+00 O.000E+O0 O.O00E+00 O.OOOE+OO O.O00E+O0 O.OOOE+O0 O.(XX)E+O0 O.O(X)E+O0 O.OOOE+00 O.O00E+O0 O.OOOE+OO 0.O00E+O0 O. 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0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.538E-09 0.108E-08 0.105E-08 0.920E-O9 0.763E-09 0.632E-O9 0.531E-09 0.472E-09 0.472E-09 0.494E-09 0.557E-09 0.678E-09 0.775E-09 0.882E-09 0.851E-09 0.748E-09 0.620E-O9 0.514E-09 0.431E-09 0.384E.09 0.384E-09 0.401E-09 0.453E-09 0.551E-09 0.630E-09 0.717E-09 0.691E-09 0.608E-09 0.504E-09 0.417E-09 0.350E-09 0.312E-09 0.312E-09 0.326E-09 0.368E-09 0.448E-09 0.512E-09 0.582E-09 0.562E-09 0.494E.O9 0.409E-09 0.339E-09 0.285E-09 0.253E-09 0.253E-09 0.265E-09 0.299E-09 0.364E-09 0.415E-09 0.473E-09 0.456E-09 0.401E-09 0.332E-09 0.275E-09 0.231E-O9 0.206E-09 0.206E-09 0.215E-09 0.243E-09 0.295E-O9 0.337E-09 0.384E-09 0.370E-09 0.325E-09 0.270E-09 0.223E-09 0.188E-09 0.167E-09 0.167E-09 0.174E-09 0.197E-09 0.239E-09 0.274E-09 0.311E-09 0.300E-09 0.264E.09 0.219E-09 0.181E-09 0.152E-09 0.135E-09 0.135E-09 0.141E-O9 0.160E-09 0.194E-09 0.222E-09 0.252E-09 0.243E-09 0.214E-09 0.177E-09 0.147E-09 0.123E-09 0.110E-09 0.110E-O9 0.114E-09 0.129E-09 0.157E-09 0.180E-09 0.205E-09 0.197E-09 0.173E-09 0.144E-09 0.119E-09 0.999E-10 0.888E-10 0.889E.10 0.928E-10 0.105E.O9 0.127E-O9 0.146E-09 0.166E-09 0.160E-09 0.140E-09 0.116E-09 0.963E-10 0.808E-10 0.719E-10 0.719Eo10 0.751E-10 0.848E-10 0.103E-O9 0.118E-O9 0.134E-09 0.129E-O9 0.114E.O9 0.942E-10 0.779E-10 0.654E.10 0.581E-10 0.582E-10 0.608E.10 0.686E-10 0.834E-10 0.953E-10 0.109E-09 0.104E-09 0.919E-10 0.762E-10 0.631E-10 0.529E-10 0.471E-10 0.471E-10 0.492E-10 0.555E-10 0.676E-10 0.772E-10 0.878E-10 0.847E-10 0.744E-10 0.617E-10 0.511E-10 0.429E-10 0.381E.10 0.382.E-10 0.398E-10 0.450E-10 0.547E-10 0.625E-10 0.711E-10 0.685E.10 0.602E-10 0.499E-10 0.413E-10 0.347E-10 0.308E-10 0.309E-10 0.322E-10 0.364E-10 0.442E.10 0.506E-10 0.575E.10 0.554E-10 0.487E-10 0.404E-10 0.334E-10 0.281E-10 0.25OE-10 0.250E-10 0.261E-10 0.295E-10 0.358E-10 0.409E-10 0.465E-10 0.448E-10 0.394E-10 0.327Eo10 0.271E-10 0.227E-10 0.202E-10 0.202E-10 0.211E-10 0.238E-10 0.290E-10 0.331E-10 0.376E.10 0.363E.10 0.319E-10 0.264E-10 0.219E-10 0.184E.10 0.163E-10 0.163E.10 0.171E-10 0.193E-10 0.234E-10 0.267E-10 0.304E-10 0.293E-10 0.258E-10 0.214E-10 0.177E-10 0.148E-10 0.132E-10 0.132E-10 0.138E-10 0.156E-10 0.189E-10 0.216E-10 0.246E-10 0.237E-10 0.208E.10 0.173E-10 0.143E-10 0.120E-10 0.107E-10 0.107E-10 0.111E-10 0.126E-10 0.153E-10 0.175E-10 0.199E.10 0.191E-10 0.168E-10 0.140E-10 0.115E-10 0.969E-11 0.861E-11 0.862E-11 0.900E-11 0.102E-10 0.124E-10 0.141E-10 0.160E.10 0.155E-10 0.136E.10 0.113E-10 0.932E-11 0.782E-11 0.695E-11 0.696E-11 0.726E-11 0.820E-11 0.997E-11 0.114E-10 0.129E-10 0.125E-10 0.110E-10 0.909E-11 0.752E-11 0.631E-11 0.561E.11 0.562E-11 0.586E-11 0.662E-11 0.805E-11 0.919E.11 0.105E-10 0.101E-10 0.886E-11 0.734E-11 0.607E.11 0.510E-11 0.453E-11 0.453E-11 0.473E-11 0.534E-11 0.650E-11 0.742E-11 0.844E-11 0.813E-11 0.715E-11 0.593E-11 0.491E-11 0.412E-11 0.366E-11 0.366E-11 0.382E-11 0.431E.11 0:524E-11 0.599E-11 0.681E-11 0.656E-11 0.577E.11 0.478E-11 0.396E-11 0.332E-11 0.295E-11 0.295E-11 0.308E-11 0.348E-11 0.423E-11 0.483E-11 0.550E-11 0.530E-11 0.466E-11 0.386E-11 0.319E-11 0.268E-11 0.228E-11 0.238E-11 0.249Eoll 0.281E-11 0.341E-11 0.390E-11 0.444E-11 0.428E-11 0.376E-11 0.312E-11 0.258E-11 0.216E-11 0.192E-11 0.192E-11 0.201E-11 0.227E-11 0.275E-11 0.315E-11 0.358E-11 0.345E-11 0.303E-11 0.251E.11 0.208E-11 0.174E-11 0.155E-11 RETARDATION FACTOR ................................ 0.1000E+01 RETARDED DARCY VELOCITY (M/HR) .................... 0.~E-01 RETARDED LONGITUDINAL DISPERSION COEF. (M**2/HR) .. 0.1000E+01 RETARDED LATERAL DISPERSION COEFFICIENT (M**2/HR). 0.3333E+00 RETARDED VERTICAL DISPERSION COEFFICIENT (M**2/HR). 0.3333E.01 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.0000E+00 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z= 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 O.000E+00 0.000E+00 0.000E+00 0.00OE+00 -50. 0.(XX)E+00 0.000E+00 0.0(X)E+00 0.0(X)E+00 0.000E+00 0.0(X)E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 0.0(X)E+00 0.000E+00 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.0(X)E+00 -100. 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 O.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.0(X)E+00 0.(XX)E+00 0.000E+00 0.000E+00 -50. 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 .100. O.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 Z= 20.00 X. Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.0(X)E+00 0.000E+00 0.000E+.00 0.000E+00 0.000E+00 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.6132E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z= 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 0.0(X)E+00 50. 0.0(X)E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 O.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 O.O00E+00 O.000E+00 0.000E+00 0.000E+00 Z= 5.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 O.000E+00 0.000E+00 0.CXX)E+00 0.00OE+00 -50. 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 0.000E+00 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 0. 0.000E+00 0.0(X)E+00 O.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.(XX)E+00 0.0(X)E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.000E+00 0.(XX)E+00 0.000E+00 0.000E+00 0.000E+00 0.0(X)E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 Z = 20.00 X Y O. 100. 200. 300. 400. 500. 100, 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -50. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 -100. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.6570E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.732E-09 0.220E-08 0.299E-08 0.308E.O8 0.310E-08 0.310E-08 50. 0.505E-08 0.918E-08 0.794E-08 0.600E.-08 0.502E-08 0.456E-08 0. 0.227E-07 0.190E-07 0.116E-07 0.767E-08 0.595E-08 0.520E-O8 -50. 0.505E-08 0.918E-08 0.794E-08 0.600E-08 0.502E-08 0.456E-08 -100. 0.732E-09 0.220E-08 0.299E-08 0.308E-08 0.310E-08 0.310E-08 Z = 5.00 X Y O. 100. 200. 300. 400. 500. 100. 0.699E-09 0.211E..08 0.290E-08 0.301E-08 0.305E-O8 0.306E-08 50. 0.453E-08 0.864E-08 0.765E.O8 0.586E-08 0,494E-08 0.450E-08 0. 0.188E-07 0.174E-07 0.111E..07 0.748E-08 0.585E-08 0.514E-08 -50. 0.453E-08 0.864E-08 0.765E-08 0,586E-08 0.494E-08 0.450E-08 -100. 0.699E-09 0.211E-08 0.290E-08 0.301E-08 0.305E-08 0.306E-08 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. 0.612E-09 0.188E-08 0.266E.08 0.283E-08 0.291E-08 0.294E-08 50. 0.340E-08 0.728E-O8 0.688E-08 0.546E-08 0.470E-08 0.432E-08 0. 0.112E-07 0.137E-07 0.992E-08 0.694E-08 0.555E..08 0.493E-08 -50. 0.340E-08 0.728E-08 0.688E-08 0.546E-08 0.470E-08 0.432E-08 -100. 0.612E-09 0.188E-08 0.266E-08 0.283E-08 0.291E-O8 0.294E-08 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.495E-09 0.156E-08 0.231E-08 0.256E-08 0.270E-08 0.276E-08 50. 0.230E-08 0.558E-08 0.579E-08 0.486E-08 0.433E-08 0.405E-08 0. 0.562E-08 0.974E-08 0.823E-08 0.614E-08 0.510E-08 0.462E-08 -50. 0.230E-O8 0.558E-08 0.579E-08 0.486E-08 0.433E-O8 0.405E-O8 -100. 0.495E-09' 0.156E-08 0.231E-08 0.256E-08 0.270E-08 0.276E-08 Z= 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.374E-09 0.121E-08 0.191E-08 0.223E-08 0.243E-08 0.253E-08 50. 0.148E-08 0.398E-08 0.459E-08 0.415E-08 0.386E-08 0.370E-08 0. 0.286E-08 0.652E-08 0.641E-08 0.521E-08 0.454E-08 0.421E-08 -50. 0.148E-O8 0.398E-08 0.459E-08 0.415E-08 0.386E-08 0.370E-08 -100. 0.374E-09 0.121E-08 0.191E-08 0.223E-08 0.243E-08 0.253E-08 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.7008E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y O. 100. 200. 300. 400. 500. 100. 0.257E-09 0.771E-09 0.105E-08 0.108E.08 0.110E.4:)8 0.111E-08 50. 0.177E-O8 0.322E-08 0.279E-08 0.211E-08 0.177E-08 0.162E-08 0. 0.796E-08 0.667E-08 0.407E-08 0.270E-08 0,210E-08 0.185E-08 -50. 0.177E-08 0.322E-08 0.279E-08 0.211E-08 0.177E-08 0.162E-08 -100. 0.257E-09 0.771E-09 0.105E.08 0.108E.08 0.110E-08 0.111E-08 Z: 5.00 X Y 0. 100, 200. 300. 400. 500. 100. 0.246E-09 0.741E-09 0.102E-08 0,106E-08 0.108E-08 0.109E-08 50. 0.159E-O8 0.303E-08 0.269E-08 0.206E-08 0.174E-08 0.160E-08 0. 0.659E-08 0.611E-08 0.391E-08 0.263E-08 0.207E-08 0.183E.O8 -50. 0.159E-08 0.303E-08 0.269E-08 0.206E-08 0.174E-08 0.160E-08 -100. 0.246E-09 0.741E-09 0.102E-08 0.106E-08 0.108E-08 0.109E-08 Z -- 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.215E-09 0.660E-09 0,937E-09 0.998E-O9 0,103E-08 0.105E-08 50. 0.119E-08 0.255E-08 0.242E-08 0.192E-08 0.166E-08 0.154E-08 0. 0.393E-08 0.480E-08 0.348E-08 0.244E-08 0.196E-08 0.176E-08 -50. 0,119E-08 0,255E-08 0,242E-08 0.192E-08 0.166E-08 0,154E-08 -100. 0.215E-09 0.660E-O9 0.937E-09 0.998E-09 0.103E-08 0.105E-08 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0,174E-09 0.547E-09 0.813E-09 0.902E-09 0.956E-09 0.990E-09 50. 0.807E-09 0.196E-08 0,203E-08 0.171E.08 0.153E-08 0,145E-08 0. 0.197E-08 0.342E-08 0.289E-08 0.216E-08 0.180E-08 0.165E-08 -50. 0,807E-09 0,196E-08 0.203E-08 0.171E-08 0.153E-08 0.145E-08 -100. 0.174E-09 0.547E-09 0.813E-09 0,902E-09 0.956E-09 0.990E-09 Z = 20.00 X Y 0. 100. 200, 300. 400. 500. 100. 0.131E-09 0.426E-09 0.672E-09 0.785E-09 0.860E-09 0.908E-09 50. 0.520E-09 0.140E-08 0.161E-08 0.146E-08 0.137E-08 0.132E-08 0. 0,101E-08 0.229E-O8 0.225E-08 0,183E-08 0.161E-08 0.150E-08 -50. 0.520E-09 0.140E-08 0.161E-08 0.146E-08 0.137E-08 0.132E-08 -100. 0.131E-09 0.426E-09 0.672E.-09 0.785E-09 0.860E-09 0.908E-09 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.7446E+06 HRS (ADSORBED CHEMICAL CONC, = 0.0000E+00 * DISSOLVED CHEMICAL CONC,) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.894E-10 0.268E-09 0.366E-09 0.377E-09 0.382E-09 0.385E-09 50. 0.616E-09 0.112E-08 0.970E-09 0.735E-09 0.617E.-09 0.566E-09 O. 0.277E-08 0.232E-08 0.142E-08 0.938E-09 0.731E-09 0.645E-09 -50. 0.616E-09 0.112E-08 0.970E-09 0.735E-09 0.617E-09 0.566E.-09 -100. 0.894E-10 0.268E-09 0.,.'.'.'.'.'.'.'.'.'~6E-09 0.377E-09 0.382E-09 0.385E-09 Z = 5.00 X Y O. 100. 200. 300. 400. 500. 100. 0.854E-10 0.258E-09 0.355E-09 0.369E-09 0.376E-09 0.381E-09 50. 0.553E-09 0.105E-08 0.935E-09 0.717E-09 0.607E-09 0.558E-09 O. 0.229E-08 0.212E-08 0.136E-08 0.915E-09 0.719E-09 0.637E-09 -50. 0.553E-09 0.105E-08 0.935E-09 0.717E-09 0.607E-09 0.558E-09 -100. 0.854E-10 0.258E-09 0.355E-09 0.369E-09 0.376E-09 0.381E-09 Z = 10.00 X Y O. 100. 200. 300. 400. 500. 100. 0.747E-10 0.229E-09 0.326E-09 0.347E-09 0.359E-09 0.367E-09 50. 0.415E-09 0.888E-09 0.840E-09 0.668E-09 0.578E..09 0.537E-09 O. 0.137E-08 0.167E-08 0.121E-08 0.849E-09 0.683E-09 0.612E-09 -50. 0.415E-09 0.888E-09 0.840E-09 0.668E-09 0.578E-09 0.537E-09 -100. 0.747Eo10 0.229E-09 0.326E-09 0.347E-09 0.359E-09 0.367E-09 Z = 15.00 X y O. 100. 200. 300. 400. 500. 100. 0.604E-10 0.190E-09 0.283E-09 0.314E-09 0.333E-09 0.345E-09 50. 0.281E-09 0.681E-09 0.707E-09 0.595E-09 0.532E-09 0.503E-09 O. 0.686E-09 0.119E-08 0.100E-08 0.752E-09 0.628E-09 0.573E-09 -50. 0.281E-09 0.681E-09 0.707E-09 0.595E-09 0.532E-09 0.503E-09 -100. 0.604E-10 0.190E-09 0.283E-09 0.314E-09 0.333E-09 0.345E-09 Z -- 20.00 X Y O. 100. 200. 300. 400. 500. 100. 0.456E-10 0.148E-09 0.234E-09 0.273E-09 0.299E-09 0.316E-09 50. 0.181E-09 0.486E-09 0.561E-09 0.509E-09 0.475E-09 0.460E-09 O. 0.349E-09 0.795E-09 0.783E-09 0.638E-09 0.559E-09 0.523E-09 -50. 0.181E-09 0.486E-09 0.561E-09 0.509E-09 0.475E-09 0.460E-09 -100. 0.456E-10 0.148E-09 0.234E-09 0.273E-09 0.299E-09 0.316E-09 DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0,7884E+06 HRS (ADSORBED CHEMICAL CONC, = 0,0000E+00 * DISSOLVED CHEMICAL CONC,) Z -- 0.00 X Y O. 100. 200. 300. 400. 500. 100, 0,309E-10 0,928E-10 0,127E-09 0,131E-09 0,132E-09 0,134E-O9 50, 0,213E-09 0,387E-09 0,335E-09 0,254E-09 0,214E-09 0,196E-09 0, 0,956E-09 0,802E-09 0,490E-09 0,325E-09 0,253E-09 0,224E-09 -50, 0,213E-09 0,387E-09 0,335E-09 0,254E-09 0,214E-09 0,196E-09 -100, 0.309E-10 0,928E-10 0,127E-09 0,131E-O9 0,132E-09 0,134E-09 Z = 5,00 X Y 0, 100, 200, 300, 400, 500, 100, 0,295E-10 0,892E-10 0,123E-09 0,128E-09 0,130E-09 0,132E-09 50, 0,191E-09 0,365E-09 0,324E-09 0,248E-09 0,210E-09 0,194E-09 0, 0,792E-09 0,734E-09 0,471E-09 0,317E-09 0,249E-09 0,221E-09 -50, 0,191E-09 0,365E-09 0,324E-09 0,248E-09 0,210E-09 0,194E-09 -100, 0,295E-10 0,892E-10 0,123E-09 0,128E-09 0,130E-09 0,132E-09 Z = 10.00 X Y O. 100. 200. 300, 400. 500. 100, 0,258E-10 0,794E-10 0,113E-09 0,120E-09 0,124E-O9 0,127E-09 50, 0,143E-09 0,307E-09 0,291E..09 0.231E-09 0,200E-09 0,186E-09 0, 0,473E-O9 0,577E-09 0,419E-09 0,294E-09 0,236E-09 0.212E-09 -50, 0,143E-09 0,307E-09 0,291E-09 0,231E-09 0,200E-09 0,186E-09 -100, 0,258E-10 0,794E-10 0,113E-09 0,120E,09 0,124E-09 0,127E-09 Z = 15,00 X Y 0, 100, 200, 300, 400, 500, 100, 0,209E-10 0,658E-10 0,979E-10 0,109E-09 0,115E-09 0,119E-O9 50, 0,970E-10 0.236E-09 0,245E-09 0,206E-09 0,184E-09 0,174E-09 0, 0,237E-09 0,411E-09 0,348E-09 0,260E-09 0,217E-09 0,199E-09 -50, 0.970E-10 0.236E-09 0,245E-09 0.206E-09 0,184E-09 0,174E-09 -100, 0.209E-10 0,658E-10 0,979E-10 0,109E-09 0,115E-09 0,119E-09 Z= 20,00 X Y 0, 100, 200, 300, 400, 500, 100, 0,158E-10 0,513E-10 0,809E-10 0,946E-10 0,104E-(}9 0,110E-09 50, 0,626E-10 0,168E-09 0,194E-09 0,176E-09 0,165E-09 0,159E-09 0, 0,121E-09 0,275E-09 0,271E-09 0,221E-09 0,194E-09 0,181E-09 -50, 0,626E-10 0,168E-09 0,194E-09 0,176E-09 0,165E-09 0,159E-09 -100, 0,158E-10 0,513E-10 0,809E-10 0,946E-10 0,1.04E-09 0,110E-09 STEADY STATE SOLUTION HAS NOT BEEN REACHED BEFORE FINAL SIMULATING TIME DISTRIBUTION OF DISSOLVED CHEMICALS IN PPM AT 0.8322E+06 HRS (ADSORBED CHEMICAL CONC. = 0.0000E+00 * DISSOLVED CHEMICAL CONC.) Z = 0.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.106E-10 0.319E-10 0.435E-10 0.448E-10 0.454E-10 0.459E-10 50. 0.731E-10 0.133E-09 0.115E~9 0.873E-10 0.735E-10 0.674E-10 0. 0.328E-09 0.275E~)9 0.168E~9 0.112E-09 0.870E-10 0.769E-10 -50. 0.731E-10 0.133E-09 0.115E~9 0.873E-10 0.735E-10 0.674E-10 -100. 0.106E-10 0.319E-10 0.435E-10 0.448E-10 0.454E-10 0.459E-10 Y 0. 100. 200. 300. 400. 500. 100. 0.101E-10 0.306E-10 0.422E-10 0.439E-10 0.447E-10 0.454E-10 50. 0.656E-10 0.125E~9 0.111E~9 0.853E-10 0.723E-10 0.665E-10 0. 0.272E~9 0.252E-09 0.162E~9 0.109E~9 0.855E-10 0.759E-10 -50. 0.656E-10 0.125E~)9 0.111E~)9 0.853E-10 0.723E-10 0.665E-10 -100. 0.101E-10 0.306E-10 0.422E-10 0.439E-10 0.447E-10 0.454E-10 Z = 10.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.887E-11 0.273E-10 0.387E-10 0.413E-10 0.427E-10 0.437E-10 50. 0.492E-10 0.105E~:)9 0.998E-10 0.795E-10 0.687E-10 0.640E-10 0. 0.162E~)9 0.198E~)9 0.144E-09 0.101E~9 0.813Eo10 0.729E-10 -50. 0.492E-10 0.105E~9 0.998E-10 0.795E-10 0.687E-10 0.640E-10 -100. 0.887E-11 0.273Eo10 0.387E-10 0.413E-10 0.427E-10 0.437E-10 Z = 15.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.717E-11 0.226E-10 0.336E-10 0.373E-10 0.396E-10 0.411E-10 50. 0.333E-10 0.809E-10 0.840E-10 0,708E-10 0.633E-10 0.600E-10 0. 0.814E-10 0.141E-09 0.119E~9 0.894E-10 0.747E-10 0.683E-10 -50. 0.333E-10 0.809E-10 0.84OE-10 0.708E-10 0.633E-10 0.600E-10 -100. 0.717E-11 0.226E-10 0.336E-10 0.373E-10 0.396E-10 0.411E-10 Z = 20.00 X Y 0. 100. 200. 300. 400. 500. 100. 0.542E-11 0.176E-10 0.278E-10 0.325E-10 0.356E-10 0.377E-10 50. 0.215E-10 0.577E-10 0.667E-10 0.605E-10 0.566E-10 0.548E-10 0. 0.415E-10 0.944E-10 0.931E-10 0.758E-10 0.665E-10 0.623E-10 -50. 0.215E-10 0.577E-10 0.667E-10 0.605E-10 0.566E-10 0.548E-10 -100. 0.542E-11 0.176E-10 0.278E-10 0.325E-10 0.356E-10 0.377E-10 PREPARED FOR: MS. KATERI LUKA ARCO PRODUCTS COMPANY P.O. BOX 6411 ARTESIA, C^IIFORNIA 90702-6411 (213) 404-5360 SITE CHARACTERIZATION WORK PLAN ARCO SERVICE STATION #6218 4203 MING AVENUE ' ' BAKERSFIELD, CALIFORNIA AUGUST 14, 1991 PREPARED BY: GROUNDWATER TECHNOLOGY, INC. 4101 ALKEN STREET, SUITE B-1 BAKERSFIELD, CALIFORNIA 93308 (805) 589-8601.. WRITrEN.BY: sxr_,~vm~r,~ D~: I PARKER JONATHAN D. P~ t./ 0 L\~ PROJECT GEOLOGIST REGISTERED GEOLOGIST #4728 I ~-] GROUNDWATER ~][~[~ TECHNOLOGY I I I I I I I I ! I I CONTENTS PAGE INTRODUCTION .................................................. 1 SITE BACKGROUND ............................................... 1 SITE CHARACTERISTICS ............................................ 2 GEOGRAPHY ................................................ 2 HYDROGEOLOGY ........................................... 2 PROPOSED SITE ASSESSMENT ...................................... 3 BORINGS ........ : .......................................... 3 SAMPLING .................................................. 4 LABoRAToRY ANALYSIS ..................................... 4 WASTE MANAGEMENT ....................................... 5 REFERENCES ................................................ · ..... 6 TABLES TABLE 1 - LABORATORY RESULTS - TANKS .......................... 2 TABLE 2 - LABORATORY RESULTS - DISPENSER ISLANDS AND PIPING ... 3 FIGURES FIGURE I - FIGURE 2 - FIGURE 3 - FIGURE 4 - FIGURE 5 - FIGURE 6 - LOCATION INDEX SITE MAP SAMPLE LOCATIONS SITE GEOLOGY DEPTH TO GROUNDWATER GROUNDWATER GRADIENT APPENDIX APPENDIX A - SITE SAFETY PLAN Characterization Workp[an ARCO Products Company August 14, 1991 ~ GROUNDWATER ~[--~[~ TECttNOLOGY MING A VENUE -- -- ..... I %~ ,.' ~ ~ ." · [ ~ .... L I J ~;~_ __,~.-~_= .... ~. ___~_~_/~ ~ __ [_L~ [ J I LEG£ND Boring Location Proposed Boring Location Showing Bottom- hole DeviatTon LOC: NAP TYPE, IREs/ I ~ Bakersfield, California Sile Map'. · ~A~E, ja~'ruveO BY: j DATE:" . z I I I I I I I I I I I I I I I I I I INTRODUCTION Groundwater Technology, Inc. has been contracted by ARCO Products Company to perform a site characterization at facility #6218 in Bakersfield, California (Figure 1). The purpose of the assessment is to determine the extent of hydrocarbon contamination which is present at the site. This workplan outlines site background, proposed assessment procedures, sampling protocol, and worker safety considerations. SITE BACKGROUND A preliminary assessment of soil conditions was completed at the site on February 22 and March 5, 1991.' The assessment consisted of drilling four borings at the locations shown in Figure 2. Soil samples were collected and field screened with a photoionization detector (PID) at 5-foot depth increments. Two samples from each boring were submitted for laboratory analysis. Those selected included the sample from the bottom of each boring and the sample which exhibited the highest headspace analysis concentration of hydrocarbons as determined with the PID. The samples were analyzed for benzene, toluene, ethylbenzene, and xylenes (BTEX) and total petroleum hydrocarbons as gasoline (TPHG) using EPA methods 8020 and 8015, respectively. All samples exhibited non-detectable concentrations for all compounds analyzed. On May 15, 1991, Wegener Construction removed three underground storage tanks at the facility. No holes were found in any of the tanks, but rust was observed on all tanks. A total of 26 soil samples were collected at the site during .tank removal operations. Tank pit samples were collected at depths of 2 and 6 feet beneath both ends of each tank. Soil samples were also collected from beneath the product lines and the ends of the service islands at depths of 2 and 6 feet. TPHG concentrations in the samples from beneath the tanks ranged from < 10 to 4,600 mg/kg. TPHG concentrations in samples collected from the beneath the dispenser islands ranged from 24 to 4,800 mg/kg. TPHG did not exceed method detection limits in samples collected from beneath the product lines. Laboratory results are summarized in Tables 1 and 2, and in Figure 3. Characterization Workptan ARCO Products Company August 14, 1991 I[ ITEc. No o ¥ I I I Table 1. Laboratory results in mg/kg for soil samples collected beneath tanks on May 15, 1991. Sample # Benzene Toluene Ethyl- Total TPH as benzene Xylenes Gasoline TIW-2' 0.85 13 5.7 100 1600 TlW-6' 1.8 9.8 8.3 310 4600 T1E-2' < 0.005 < 0.005 < 0.005 0.018 < 10 TIE-6' < 0.005 ' < 0.005 < 0.005 < 0.015 < 10 T2W-2' 24 230 71 460 3000 T2W-6' 4 87 33 300 2000 T2E-2' < 0.005 < 0.005 < 0.005 0.029 < 10 T2E-6' < 0.005 0.055 0.062 5.7 55 T3W-2' < 0.005 < 0.005 ' < 0.005 < 0.015 < 10. T3W-6' < 0.005 < 0.005 < 0.005 0.16 < 10 T3E-2' < 0.005 0.021 0.006 01062 < 10 T3E-6' < 0.005 < 0.005 < 0.005 < 0.015 < 10 I I I I I I I I I I I I I I I SITE CHARACTERISTICS GEOGRAPHY The site is located on the alluvial plain of the Kern River. Topography in the region is fiat, and no natural bodies of water adjoin the site. The station is located in a commercial area and is approximately 2,500 feet southwest of the nearest school. HYDROGEOLOGY The site overlies alluvial fan deposits of the Kern River (Figure 4). Sediments underlying the region consist of fluvial deposits including silt, sand and gravel. Sediments encountered during drilling and excavation activities at the site consist primarily of medium- to coarse- grained sand. Characterization Workptan ARCO Products Co~pany August 14, 1991 2 I~[~] GROUNDWATER [][][]TECHNOLOGY I I I I I I I I Table 2. Laboratory results in mg/kg for soil samples collected beneath dispenser islands and piping on May 15, 1991. Sample # Benzene Toluene Ethyl- Total TPH as benzene Xylenes Gasoline DI1-2' 0.11 5.1 3.3 37 280 DI1-6' 0.009 0.14 . 0.084 1.7 24 DI2-2' < 0.1 5.7 4.9 130 1900 DI2-6' < 0.005 0.42 0.61 17 430 DI3-2' 0.30 25 26 630 4800 DI3-6' < 0.005 0.15 0.34 11 170 DI4-2' < 0.1 6.8 7.3 610 2900 DI4-6' < 0.10 7.3 6.2 230 2500 PL1-2' < 0.005 < 0.005 < 0.005 < 0.015 < 10 PLlo6' < 0.005 < 0.005 < 0.005 < 0.015 < 10 PL2-2' < 0.005 < 0.005 < 0.005 < 0.015 < 10 PL2-6' < 0.005 < 0.005 < 0.005 < 0.015 < 10 PL3-2' < 0.005 < 0.005 < 0.005 < 0.015 < 10 PL3-6' < 0.005 0.005 < 0.005 < 0.015 < 10 I I 1 I I I I I I I I .An unconfined aquifer is present below the site at a depth of approximately 155 feet (Figure 5). The gradient of this aquifer is generally toward the southeast (Figure 6). Shallow, perched water has not been identified in the vicinity of the site (Kern County Water Agency, 1990). PROPOSED SITE ASSESSMENT BORINGS Groundwater Technology will drill five borings at the site as shown in Figure 2. The boring located near the former tank pit is intended to define the vertical extent of the hydrocarbons in that area and will be drilled to a minimum depth of 30 feet or until 10 feet of uncontaminated soil is encountered. Previously drilled borings BI, B2 and B4 provide Characterization Workptan ARCO Products Company August 16, 1991 ~][][] GROUNDWATER [][][3 TEc"NO[oc¥ I I I I I I I I I I I I I I i I I I horizontal definition of the hydrocarbons in this area. Three borings will be slant drilled beneath the two dispenser islands as shown in Figure 2. These' borings will be advanced to a minimum of 20 feet or until 10 feet of uncontaminated material is encountered. A fifth boring will be drilled vertically near the southeast comer of the islands to estimate the lateral extent of contamination in this area. No drilling fluids will be utilized during boring completion. The borings will be back-filled with 5-sack cement/sand slurry upon completion of work. The depth to groundwater is reported to be in excess of 150 feet in this area (Kern County Water Agency, 1990) and therefore it is not anticipated that groundwater will be encountered. SAMPLING Soil samples will be collected from each boring at 5-foot intervals with a split-spoon sampler. The sampler will be fitted with stainless steel or brass sample rings. The material from one sample ring will be described on the lithologic log of the boring and field screened with a PID for volatile organic compound (VOC) emissions. A second ring will be sealed at each end with a teflon sheet and plastic cap. The caps will be secured with silicon (non- hydrocarbon) tape and the sample will be preserved on ice. Two samples from each boring, that which exhibits the highest VOC emissions as indicated by the 'PID, and the deepest sample, will be analyzed by a state-certified laboratory as described below. If the boring in the former tank pit exceeds 30 feet, a third sample will be analyzed to provide greater definition of the extent of contamination. Between samplingevents, the sampling equipment will be cleaned using a three-bucket wash system. In this system, the sampler is scrubbed with a brush in a bucket of non-phosphate detergent, rinsed in a second bucket of tap water and given a final rinse in a bucket of distilled water. LABORATORY ANALYSIS Soil samples selected for analysis will be shipped via overnight courier to GTEL Environmental Laboratories in Torrance, California (Cert. #723). The samples will be Characterization Workp[an ARCO Products Co~any August 14, 1~1 4 GROUNDWATER TECHNOLOGY I I I I I I I I I I i I I I I ! I I analyzed for TPHG and BTEX using EPA methods 8015 and 8020, respectively. Detection limits for these analyses'will be 10 mg/kg for TPH, 0.005 mg/kg for BTE and 0.015 for X. Standard chain-of-custody procedures will be followed. WASTE MANAGEMENT The drill cuttings from the borings will be stored on site in appropriately labelled 55-gallon drums pending receipt of the laboratory analytical results of soil samples collected from the drums. Following analysis of the samples the drum contents will be disposed of by ARCO in an appropriate and timely manner. Characterization gorkp[an ARCO Products Company August 14, 1991 5 []~-~[] GROUNDWATER ~-~[][] TECtlNOLOGY I I I I I i I I I I I I I I i I I I I REFERENCES California Division of Mines and Geology, 1975, Geologic Map of California, Bakersfield' sheet. Kern County Water Agency, 1990, 1989 Report. on water conditions - improvement district no. 4. Characterization Workptan ARCO Products Colpany August 14, 1~1 6 []~]L~iGRouNDWATER I[~[~[~IT~CHNOLOCV I I I I I I I I I I I I I I I I I I I FIGURES ]~ GROUNDWATER TECHNOLOGY :"1 I I I I I I I I I I I I I I I I mmv~ I ......... I~ '~ ~ ~ ..... ~< ' ' ~ ~'~':~" ~ ~" ~ ~~=1" '; ' m' I I · - t ~ z~;~~ 2 c ~'~ · ~E ~ ~ ' 'arkE ' ~ ~ ~ ~ ' L~ ~ ' .- /- ~,~...,.;.,~s~ ~1 ~/~'~' '~~~ i~Zl~.,,,~' - m~e ~n ~ ,< c 7~ ~ ~ ~ ~"~' .,~ uE' ~. T ~.,,A. , ' ' -x/'"'"~'~"i ......... ~,,,-;~ '/~'/O,~., ~ ~ %~ ~-~, ~Site snr c~c, 4203 Bokorsfield, Colifornio MAP TYPE= Locofion Index SCALE= DRA~N ~Y, DATE, APPRBVED ~Y, ~ATE, MH 2/91 JDP 2/91 ~ REV REV/SION DATE ~Y 1/2 0 ~/4 I/2 miles Source: Hoven & Co. Inc. l FIGURE 1 MING A VENUE Sidewalk V ~ Planter ! ! Planter 0 0 Poll Former Tank Location ) -~g.- ..~;/~. New Tonk / ~ ~.~4 "~ ~ Location ; .~B ~x~ ildin ; r_,_ LEGEND Boring Location : 0 Proposed Boring Location Showing Bottom-hole Deviation SCALE~ 40' 0 20' 40' # 022 SITE, ARCO SS #6218 ~ 0658 S]T~ EriC, Bokersfield, Colifornio NAP TYPE, Site Map DRAWN DY, J DATE, APPRI]V£D BY, I DATE, SABJ 8/91 JDPI 8/91 REV J REVISION ])ATE DY 410 46OO Planter <10 <10 MING A VENUE <10 <10 <10 <10 55 280 900 430 DI1 4800 2900 Building LEGEND TPH@2' ~ Sample Location SCALE, 40' 0 20' 40' I Jot "02250 SITE, ARCO SS #6218 j 0658 SITE LaC, Bakersfield, California MAP TYPE, Sample Locations JDP 6/91 I JDP 6/91 REV REVISION I)ATE I I I I I I I I I I I I I I · x~x%. ~,,,.. .- · .'~ ----.~-~,'~,-~'--~._' ' '~,'~_-..' '1'~. '~, .... ' ' ~ "'"' ~'" "'""." '~' ..:.~.: '. '~ ~~'. :-: :~::: ~X ' - '', ', '',,,~ ~'-. ,,',, .':-"::'.~.. '~~M ' "., ~__ ... ..... ,,. . ....... . ~.' '. ' ' - .$ .. .;:'~'-.~" .. ,, -- -.;,,,-,;~ ,,~.,.'.....s: · I .. .~ ~. .~.... .... -,.........-..~ ..~ , u:,,F~fi:...~~~ . ..--. ~. :.~.. ,, ~~~ ,..-...~.-.. ~, ,.. - ..... ,fl:..~-~~?K~~~.'.~ ,~ z~.'.'.'.". .. '.~ I~ :'. ~~'. ':' -/-' .' .... · :- , .... · . ~q~ '- . ' , :" , :' ~>~ · ~_.-- ' I l',,~z' '- '-'. ~ : '~.:: 't ': ' ~~er~.....~-~-.;' ~q~.' .' .~r~~-~,. ':.~'~.:.'.~Z~....~. t' ' W".' '~ ' "' -'~,~ . ' ..- ...... .'~ . -...-,..~:.'.., · .. ... - ..'f . -. ',¢;/ : '. - ...~ '~'i.'~-: .//,.-. . ' . .., , .. . . ~, ' ~' ~',~ ~.' , , F ~ 5.." ,[v~'l~lF.:~ ~<. '. ' . ~ x .-~ ..[ , o ,./ .... , ~....,.....,.. ~.....~.; .~.:.., - " , - ' ' '~. . '- · ~- I]lt'"'T ~.'~s~ . , ~. ,~.~.. .:.: '- ' I "" ~"~'.'~ -o¢.- ~ 2 ) ~ ":~) · - 334 Ce. nt~r _ . . fielc . ~i~ · /."~ Legend S ~?~'.~: '~:~ Fan deposi~ '.': ~6 '.' B~in deposi~ JOS ~ 215 s~,ARCO SS ~6218 ~so 0~07 S~TE Bokersfield, Colifornio ~CALE: MAP TYPE: Si~e Geology ~ 0 Z ~ MH 2/91I JDP 2/91 mites Source: CDMG Bokersfield Sheet IFIGURE 4 il ~-I I I I I I I I I I I I I I I ~ u ~ ~ U~ ~ , ~~_, ~ ~~~'----~~: - N ~Site Legend t~O'~ Depth to Groundwater JD~ ~ 215 s~Z, ARCO SS ~6218 ss0 o6o7 SITE LDC~ SCALE: B~kersfield, C~liforni~ ~ ~ ~v~z' Depth to 6roundwcter 4000 0 2000 4000 DRAVN BY, ~ DATE, ~APPROVED 9Y, DATE, Feet MHI 2/91 I JDP 2//91 Source: K.C.W.A. Report, 1990 I FIGURE 5 ~ TEC~L~Y '1 I I I I I I I I I I I I I I I ~l~ .... ~ . OOOOOO~==~ B~SB~O ~: ~'~ JUU ~ ~~M o~oooO0000Z ~S~te Legend Groundwater Devotion oo~ ~ 21 5 s~m ARCO SS ~6218 ~50 0607 $~TE LOC, SCALE, Bokersfield, Colifornio ~ HAP TYPE, Groundwofer Grodienf 4000 0 ~000 4000 9PAWN ~Y, ~ 9ATE, APPROVE9 ~Y, 9ATE, ~eet MH~ 2/91 JDP 2/91 Source: K.C.W.A. Report, 1990 I FIGURE 6 I I I I I I I I I I I I I I I I I I APPENDIX A SITE SAFETY PLAN ~-~[~-~ GROUNDWATER I I I I I I I I I I I I I I I I I SITE SAFETY PLAN ARCO PRODUCTS COMPANY ARCO SERVICE STATION #6218 BAKERSFIELD, CALIFORNIA FEBRUARY 7, 1991 GROUNDWATER TECHNOLOGY, INC. 20000/200 MARINER AVENUE TORRANCE, CALIFORNIA 90503 PROJECT NUMBER: 215-350-0607 COMPLETED BY MANAGER HEALTalk& ~,FETY MANAGER ARCO6218.SSP/.it20 [~[--1[] TECHNOLOC¥, IN(::. I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~/ Plan February 7, 1991 TABLE OF CONTENTS I I I I I I I I 1.0 SITE EMERGENCY ..................................................................... 1 1.1 Emerqenc¥ Telephone Numbers ...................................................... 1 1.2 First Aid ........................................................................ 1 1.3 Emerqenc¥ Environmental Contacts ................................................... 2 1.4 Encounterinq Hazardous Situations (requirinq evacuation) ................................... 2 2.0 INFORMATIONAL SUMMARY ............................................................. 2 2.1 Health and Safety Summary ......................................................... 2 3.0 INTRODUCTION ....................................................................... 5 3.1 Backqround ..................................................................... 6 3.2 Purpose ........................................................................ 6 3.30biective ....................................................................... 6 3.4 Amendments .................................................................... 6 4.0 HAZARD EVALUATION .................................................................. 6 4.1 Site Conditions .................................................................. 6 4.2 Site Tasks ...................................................................... 7 4.3 Spill and Disposal Procedures ....................................................... 7 4.4 Job Task Hazards ................................................................ 7 4.4.1 All Field Tasks ............................................................ 7 4.4.2 Well Installation; Well Development; Well Gauging; Well Bailing; Soil & Groundwater Sampling ............................................................. 12 4.4.3 Sample Preservation ...................................................... 12 4.4.4 Cleaning Equipment ...................................................... 12 4.4.5 Confined Space .......................................................... 12 I5.0 PERSONAL PROTECTIVE EQUIPMENT .................................................... 13 6.0 DECONTAMINATION PROCEDURES ...................................................... 14 I7.0 CHEMICALS OF CONCERN ............................................................. 15 7.1 Health Effects .................................................................. 15 I8.0 GAS/VAPOR MONITORING PROCEDURES ................................................. 16 8.1 Tasks Performed Within a Confined Space ............................................. 16 I I I 9.0 HEALTH AND SAFETY REQUIREMENTS ................................................... 18 9.1 Medical Monitorinq Proqram ............................................................. 18 9.2 Training ...................................................................... 18 9.3 Work Zones Access ............................................................. 19 9.4 Emerqenc¥ Equipment ........................................................... 19 9.5 Carbon Treatment ............................................................... 19 9.6 Drillinq Procedures .............................................................. 21 ~--~[--~;~ GROUNDWATER ~:~s.s..~/,,~o i [~[~--~ TECHNOLOGY, INC. I I '1 I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 9.7 9.8 9.9 9.10 Electrical Equipment and Ground-Fault Circuit Interrupters ................................. 21 Fire Prevention ................................................................. 23 General Health ................................................................. 23 MSDS Information .............................................................. 23 10.0 PROJECT PERSONNEL ................................................................ 23 10.1 Proiect Manaqer: ............................................................... 23 10.2 Health & Safety Manacler ......................................................... 24 10.3 Site Safety Officer .............................................................. 25 10.4 Field Team Leader .............................................................. 25 10.5 Other Field Personnel ............................................................ 26 10.6 Medical/Technical Advisors ....................................................... 26 APPENDICES APPENDIX A: Agreement and Acknowledgement Statement APPENDIX B: Site Safety Plan Amendment Sheet APPENDIX C: Definition of Hazard Evaluation Guidelines APPENDIX D: Site Maps APPENDIX E: MSDS APPENDIX F: Accident/Injury Form APPENDIX G: Vapor Monitoring Worksheet APPENDIX H: Excavation/Trenching APPENDIX I: OSHA Inspection Steps ~18.88P/#20 ii [--[[][] GROUNDWATER ~][~[---} TECHNOLOGY, INC. !1 ARCO PRODUCTS COMPANY- SS Site Safety Plan February 7, 1991 I I I I I I I I I 1.3 Emerqen(~y Environmental Contacts. Groundwater Technology, Inc.: Contact Person: Jon Parker Home: 805-833-8984 Alternates: Maura Hanning Home: 805-871-5312 Maureen Grant Home: 1-213-379-3055 National Response Center: U.S, EPA (24-hour Hotline): State Regulatory Agency: Kern County Dept. of Env. Health Svs. Client: ARCO Products Co. Contact Person: Kated Luka TELEPHONE: 1-805-589-8601 1-805-589-8601 1-213-371-1394, X337 1-800-424-8802 1-800-424-9346 1-805-861-3636 1-213-707-5360 1.4 Encountednq Ha~mrdous Situations (requirinq evacuation) In the event of an emergency, i.e. fires, explosions or any unplanned sudden or non-sudden release of hazardous waste or h.?ardous waste constituents to air, soil or surface water at the facility, the team member that observes this condition shall give an emergency alarm. The emergency alarm signal will be 3 horn blasts on the horn located in the site vehicle. Actions to be taken will be dictated by the emergency. All appropriate local emergency response agencies shall be notified immediately. The police, fire department, emergency response teams and ambulance may be reached via telephone by dialing 911. The nearest hospital and additional emergency contacts are listed on the previous page (Section 1.0). Personnel encountering a h~ardous situation shall instruct others on site to evacuate the vicinity immediately and call the (I) Site Safety Officer, (2) the Project Manager, and (3) the Health & Safety Manager for instructions. The site must no__[t be re-entered until back-up help, monitoring equipment, and personal protect.lye equipment is on hand. 2.0 INFORMATIONAL SUMMARY I I I I 2.1 Health and Safety Summary Chemicals of Concern: Gasoline, Benzene, Toluene, Ethylbenzene, & Xylene H_~:,ard Determination: Serious_ Moderate_ Low ~ Minimum Level of Protection: Modified Level D is the minimum acceptable level for this site. Action Level for Upgrading Personal Protection: Upgrade from Level D to Level C at 100 ppm measured within the breathing zone. This should be determined by a photoionization detector (PID) with a 10.2 lamp or a flame ionization detector (FID). C.OUNDW^TE. --il---li--I T CHNO OC¥, INC. I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~/ Plan February 7, 1991 Air Monitoring Requirements: PiE) ~ OVA FID O2/LEL __ DETECTOR TUBES OTHER TABLE I ACTION LEVELS NOTE: The information in this chart applies to gasoline and its chemical constituents. GASOLINE PEL* = 300 PPM GTI ACTION LEVEL = 100 PPM ACTION LEVELS FOR PPE AIR MONITORING INSTRUMENT LEVEL D LEVEL C LEVEL B LEL <1% 1% - 5% >5% PID/FID <100 ppm 100 - 750 ppm >750 ppm 02 19.5 - 23% 19.5 - 23% < 19.5% I I I I I I Explanatory Information: LEL Gasoline = 1.4 % or 14,000 ppm 1% LEL = 140 ppm (Wear Level C) 5% LEL = 700 ppm (Wear Level C) >5% LEL = Level B (>700 ppm) NOTE: Withdraw from site and contact the proiect manager if: LEL > 20%, and/or O2 > 23% * PEL = Permissible Exposure Limit (OSHA 1989) ARCO~S.SSP/~O 3 ~--][~][--[ TECHNOLOC¥, INC. ARCO PRODUCTS COMPANY- SS Site Safety Plan February 7, 1991 I I ! I 3.0 INTRODUCTION 3.1 Backqround ARCO Products Co. has retained Groundwater Technology, Inc. (GTI) to perform a site assessment/investigation at their facility located at Ming Ave. and Stine Rd. in Bakersfield, California. 3.2 Purpose The purpose of the site safety plan is to provide Groundwater Technology field personnel and subcontractors with an understanding of the potential chemical and physical hazards that exist or may arise while the tasks of this project are being performed. I I I I I This SSP describes the procedures to be followed in order to reduce employee exposure to potential health hazards which may be present at the project site. The emergency response procedures necessary to respond to such hazards are also described within this SSP. 3.3 Objective The primary objective is to ensure the well-being of all field personnel and the community surrounding this site. In order to accomplish this, project staff and approved subcontractors shall acknowledge and adhere to the policies and procedures established herein. Accordingly, all personnel assigned to this project shall read this site safety plan and sign the Agreement and Acknowledgement Statement (Appendix A) to certify that they have read, understood and agreed to abide by its provisions. GTI personnel have the authority to stop work performed by our sub- contractors at this site if any work is not performed in accordance with the requirements of this Site Safety Plan. 3.4 Amendments Any changes in the scope of work of this project and/or site conditions must be amended in writing on the Site Safety Plan Amendment Sheet (Appendix B) and approved by Health & Safety Manager. I I I 4.0 HAZARD EVALUATION 4.1 Site Conditions General Site conditions at the ARCO #6218 site include predrill assessment prior to tank removal to check for hydrocarbon-bearing soils near old tank and new tank locations. I I ARCO~S. SSP/~O 4 []r--I[] GROUNDWATER TECHNOLOC¥, INC. I I I I I I I ARCO PRODUCTS COMPANY- SS Site Safety Plan February 7, 1991 4.2 Site Tasks The field tasks at this site may include: · Soil boring samples $ Monitoring well installation · Monitoring well survey · Monitoring well gauging · Monitoring well development · Product bailing · Groundwater and soil sampling · Excavation/trenching · Equipment installation · Operation and maintenance 4.3 Spill and Disposal Procedures Contain spills with an absorbent material (sand, sawdust, dirt, clay). Report spills to client and follow their recommended procedures. If spills occur in transit, report them to the appropriate authorities. 4.4 Job Task Hazards 4.4.1 All Field Tasks: The following hazards may be encountered. · Slippery Surfaces: I I I I I All employees must wear ANSI approved work boots with steel toe protection. Skid proof soles are highly recommended. · Organic Vapors: The inhalation of volatile organic vapors during all operations can pose a potential health hazard. Hazard reduction procedures include monitoring the ambient air with a PID and/or FID and use of Personal Protective Equipment indicated on Table II. Workers should stand upwind of the source of contamination whenever possible. If ambient air levels in the breathing zone exceed 100 ppm, full face respirators equipped with organic vapor cartridges must be worn. · Flammable Vapors: Presence of flammable vapors can pose a potential fire hazard and health hazard. Hazard reduction procedures include monitoring the ambient air with an O2/LEL meter. If the LEL reading exceeds 20%, leave the site immediately and contact the fire department. I I Oxygen: Atmospheres that contain a level of oxygen greater than 23% pose an extreme fire hazard (the usual ambient oxygen level is approximately 20.5%). All personnel encountering atmospheres that contain a level of Oxygen greater than 23% must evacuate the site immediately and must notify the Fire Department. I I If Oxygen Level is less than 19.5%, do not enter the space. ARCOe218.SSP/dL~O 5 [--][][~ GROUNDWATER r--I[][] TECHNOLOGY, INC. I I I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 Noise: GTI and ANSI approved hearing protection must be worn during noisy operations such as drilling. · Surface and Equipment Contamination: Contact with contaminated surfaces, or surfaces suspected of being contaminated should be avoided. This includes walking through, kneeling or placing equipment in puddles, mud, discolored surfaces, or on drums and other containers. Eating, smoking, drinking and/or the application of cosmetics is prohibited on this site in the immediate work area. This reduces the likelihood of contamination by ingestion. · Exposure - Heat Stress: Since climatic changes cannot be avoided work schedules will be adjusted to provide time intervals for intake of juices, juice products and water in an area free from contamination and in quantity appropriate for fluid replacement. Heat stress may occur even in moderate temperature areas and may present any or all of the following: Ao Heat Rash: result of continuous exposure to heat, humid air, and chafing clothes. Heat rash is uncomfortable and decreases the ability to tolerate heat. Heat Cramps: result of the inadequate replacement of body electrolytes lost through perspiration. Signs include severe spasms and pain in the extremities and abdomen. Heat Exhaustion: result of increase stress on the vital organs of the body in the effort to meet the body's cooling demands. Signs include shallow breathing; pale, cool, moist skin; profuse sweating; dizziness. Heat Stroke: result of overworked cooling system. Heat stroke is the most serious form of heat stress. Body surfaces must be cooled and medical help must be obtained immediately to prevent severe injury and/or death. Signs include red, hot, dry skin; absence of perspiration; nausea; dizziness and confusion; strong, rapid pulse. Can lead to coma and death. Heat Stress Prevention A. Replace body fluids (water and electrolytes) lost through perspiration. Solutions may include a 0.1% salt and water solution or commercial mixes such as Gatorade and Squench. B. Cooling devices to aid the natural body ventilation. Cooling occurs through evaporation of perspiration and limited body contact with heat-absorbing protective clothing. Utilize fans and air conditioners to assist in evaporation. Long, cotton underwear is suggested to absorb perspiration and limit any contact with heat-absorbing protective clothing (i.e., coated Tyvek suits). C. Provide hose-down mobile shower facilities to cool protective clothing and reduce body temperature. D. Conduct non-emergency response activities in the early morning or evening during very hot weather. A~CO~s. SS~/~2o 6 , TECHNOLOGY, INC. I I I I I I I I ,I ARC° PRODUCTS COMPANY- SS Site Safe~/ Plan Februa/y 7, i991 E. Provide shelter against heat and direct sunlight to protect personnel. F. Rotate workers wearing protective clothing during hot weather. · Exposure - Cold Stress: Work schedules will be adjusted to provide sufficient rest periods in a heated area for warming up during operations conducted in cold weather. Also thermal protective clothing such as wind and/or moisture resistant outerwear is recommended to be worn. If work is performed continuously in the cold at or below -7°C (20° F), including wind chill temperature, heated warming shelters (tents, cabins, company vehicles, rest rooms, etc.) shall be made available nearby and the worker should be encouraged to use these shelters at regular intervals the frequency depending on the severity of the environmental exposure. The onset of heavy shivering, frostnip, the feeling of excessive fatigue, drowsiness, irritability, or euphoria, are indications for immediate return to the shelter. When entering the heated shelter the outer layer of clothing shall be removed and the remainder of the clothing loosened to permit sweat evaporation. A change of dry work clothing shall be provided as necessary to prevent worker from returning to their work with wet clothing. Dehydration, or the loss of body fluids, occurs in the cold environment and may increase the susceptibility of the worker to cold injury due to a significant change in blood flow to the extremities. Warm sweet drinks and soups should be provided at the work site to provide caloric intake and fluid volume. The intake of coffee should be limited. (Adapted from TLV's and Biological Exposure Indices 1988-1989; ACGIH). · Falling Objects: Hard hats must be worn by all personnel whenever construction-type activity is taking place. (ie., drilling, excavation, trenching). I I I · Vehicular traffic: All employees will be required to wear a fluorescent safety vest at all times while on site. In addition, the following safety equipment procedures must be adhered to. TASK Drilling A Subsurface Entry A Well Installation A Well Maintenance B Well Gauging B Sampling B Pump Test B TRAFFIC SAFETY EQUIPMENT SAFETY EQUIPMENT KEY: A = Cones and barricades required - tapes and flags are recommended but B = Cones are required - flags are recommended but are optional. optional. I I ARCO~e. SS~/~,~O 7 -~J--~L~] GROUNDWATER ~-]~-]1 TECHNOLOC¥, Inc. I I I I I I I I I I I I' I I I I I I ARCO PRODUCTS COMPANY- SS Site Safety Plan February 7, 1991 4.4.2 Well Installation; Well Development; Well Gauging; Well Bailing; Soil & Groundwater Sampling: Skin and eye contact with contaminated groundwater and/or soil may occur during these tasks. Nitrile butyl rubber or neoprene gloves and approved safety goggles should be worn when contact with contaminated substance and/or splash is possible. 4.4.3 Sample Preservation: When hydrochloric acid is used, skin and eye contact can occur. This hazard can be reduced with the use of Nitrile butyl rubber or neoprene gloves and the use of safety goggles. 4.4.4 Cleaning Equipment: Skin and eye contact with methanol, Alconox, or other cleaning substances can occur while cleaning equipment. This hazard can be reduced with the use of Nitrile butyl rubber or neoprene gloves and the use of safety goggles. 4.4.5 Confined Space: Manholes, subsurface vaults and sheds are examples of confined spaces that may lack adequate ventilation. Organic and/or combustible vapors may be trapped resulting in a lack of oxygen (anoxia) and/or overexposure to vapors. When site work takes place in a confined space the air must be monitored for (a) oxygen level, (b) flammable vapors, and (c) toxic vapors. The following air monitoring procedures must be followed before entering a confined space. ao Oxyqen Level: Monitor for % Oxygen with an 02/LEL meter to ensure a minimum oxygen level of 19.5%. Oxygen level monitoring will be done at the top, middle and bottom of the enclosed space to determine if there is a minimum acceptable oxygen level of 19.5% PRIOR to entry. If oxv(~en is less than 19.5%, do not enter the space. b. Explosive Vapors: Monitor for % of Lower Explosive Limit (LEL) with a 02/LEL meter to determine whether vapor concentrations within the confined space are within the flammable range. If LEL readings exceed 20%, personnel MUST leave the site immediately, and contact the project manager. c. Toxic Vapors: Monitor for toxic vapors with a PID and/or an FID (e.g., HNU or OVA) to determine whether toxic vapors within the confined space exceed the action levels. If the PID and/or the FID readings exceed 100 ppm, a full face respirator must be worn. All monitoring equipment must be calibrated and maintained in accordance with manufacturer's recommendations. If an HNU is used, the 10.2 eV lamp is required for accurate readings. ARCO~8.SSP/~O 8 ~]~'~] GROUNDWATER [~r--][] TECHNO[,OC¥, INC. ARCO PRODUCTS COMPANY- SS Site Safety Plan February 7, 1991 Summary: Do not enter the confined space unless: · the oxygen concentration is between 19.5 and 23%; · the LEL is less than 20%; · PID and/or FID readings are less than 750 ppm (a full face respirator must be worn if the readings exceed 100 ppm) so Buddy System: The buddy system must be used when the work in the confined space: (1) requires the person's head to be below ground level; or (2) the person must work in a manhole or other space in which an exit may not be easily accessible. I I TABLE II HAZARD SUMMARY AIR MONITORING - BREATHING ZONE JOB TASK PPE LEVEL INSTRUMENT I FREQUENCY* Soil Boring Samples D PID or FID At start of work and 15 min. to continuously Monitoring Well Installation D PID or FID At start of work and 15 min. to continuously Monitoring Well Survey D PID or FID Start-up of work at each well location Monitoring Well Development D PID or FID Start-up of work at each well location Groundwater and Soil Sampling D PID or FID Start-up of work at each well location. I I * All air monitoring data must be recorded on the Vapor Monitoring Sheet, Appendix G. 5.0 PERSONAL PROTECTIVE EQUIPMENT I I I I Modified Level D is the minimum acceptable level for this site. Modified Level D includes: coveralls/work uniform steel toe and shank boots Nitrile butyl rubber or neoprene gloves (optional) splash goggles/safety glasses if potential for splash hard hat fluorescent vest Tyvek suit (optional) hearing protection (as appropriate) I I ARCO6218.SSP/~20 9 [~C~[~ GROUNDWATER ~--]~-~ TECHNOLOGY, INC. I I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS Site Safe~y Plan February 7, 1991 Level C includes: · full face respirator NIOSH approved with organic vapor cartridges · Tyvek suits (if splash hazard is possible, a coated suit must be worn) Nitrile butyl rubber or neoprene gloves steel toe and shank boots outer boots ~ chemical resistant inner disposable gloves (2 pairs recommended) hard hat · fluorescent vest hearing protection (as appropriate) Level B includes: · air supplied respirator coated Tyvek suit, such as Saranex Nitrile butyl rubber or neoprene gloves inner latex or vinyl gloves steel toe and shank boots outer boots - chemical resistant hard hat fluorescent vest hearing protection (as appropriate) 6.0 DECONTAMINATION PROCEDURES All operations conducted at this site have the potential to contaminate monitoring equipment and personal protective equipment (PPE). To prevent the transfer of contamination to vehicles, administrative areas and personnel, the following procedures must be followed: Equipment Decontamination 1. Whenever possible, monitoring equipment should be decontaminated with a solution of Alconox and thoroughly rinsed with water prior to leaving the site. This must be done outside a 5-foot radius of any work area. Personal Decontamination LEVEL D · segregated equipment drop · wash/rinse outer boot (as appropriate) · wash/rinse chemical resistant outer glove, then remove (as appropriate) · remove hard hat, goggles/safety glasses/faceshield · remove and throw out inner disposable gloves in designated lined receptacles (as appropriate) ARCC~2~.SSP/~,20 10 I~[~ C.OVNDW^TE. [--][][] TECtlNOLOCY, INC. I I I I :1 I I I I I I I I I I I I I ARCO pRODUCTS COMPANY- SS #6218 Site safety Plan FebruarY. 7, 1991 LEVEL C LEVEL B · segregated equipment drop · wash/rinse outer boots · wash/rinse chemical resistant outer gloves, then remove · remove outer boots and place to dry (if reusable) · remove chemical resistant suit (remove by rolling down the suit) · remove first pair(s) of disposable gloves · remove respirator/hard hat/faceshield dispose of cartridges and wash respirator ~ remove last pair of disposable gloves · segregated equipment drop · wash/rinse outer boots · wash/rinse chemical resistant outer gloves, then remove · cross hotline (into clean area) and change air tanks, then redress o_[r · cross hotline (into clean area) · remove boots and gloves · remove SCBA, if worn over chemical resistant suit · if SCBA is worn under the suit, remove the chemical resistant suit, then the SCBA · remove hard hat 7.0 CHEMICALS OF CONCERN 7.1 Health Effects Potential health effects from a chemical exposure are dependant on several exposure factors such as: toxicity of substances, duration of exposure, concentration during exposure and the overall health of the person exposed. The chemicals commonly at this site are: Gasoline, Benzene, Toluene, Ethylbenzene, and Xylene. The following is a health analysis of these chemicals. Additional information on these chemicals can be found in the Material Safety Data Sheet located in Appendix E. Gasoline constituents can be divided into five major groups: alkanes, alkenes, cycloalkanes, aromatics and additives. The aromatics are the constituents generally regarded to be of greatest toxic concern. The major aromatics in gasoline are benzene, toluene, ethyl benzene and xylene. Of these, benzene is considered to be the most toxic. One characteristic effect of gasoline and its aromatic constituents is their ability to irritate the skin when repeated or prolonged exposure occurs. Benzene Benzene can enter the body through inhalation, ingestion and skin contact. Studies have noted that chronic exposure to benzene vapor can produce neurotoxic and hematopoietic (blood system) effects. Other effects can include headache, dizziness, nausea, convulsions, coma and possible death if exposure is not reversed. One significant effect from chronic benzene exposure is bone marrow toxicity. There is also an association between chronic exposures to benzene and the development of certain types of leukemia. ARCO~S.SSP/.'~O 1 1 [~-~L~ GROUNDWATER [~1--~[--] TECHNOLOGY, INC. ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 I ! I I I I I I I I I I I I I I Toluene Inhalation exposure to toluene vapor can produce effects such as central nervous system depression. Depending on exposure factors signs and symptoms can include headache, dizziness, fatigue, muscular weakness, incoordination, drowsiness, collapse and possible coma. Toluene can be a skin and mucous membrane irritant and studies have shown that high levels of toluene exposure can cause liver and kidney damage. Ethylbenzene Exposure to ethyl benzene at high vapor concentrations may produce irritation to the skin, eyes and upper respiratory tract. Overexposure to ethyl benzene vapors can produce central nervous system depression with symptoms of headache, nausea, dizziness, shortness of breath and unsteadiness. Prolonged skin exposure to ethyl benzene may result in drying and cracking of the skin (dermatitis). Solvent resistant gloves should be worn during sampling to prevent exposure to the skin. X¥1enes Depending on exposure factors, inhalation exposure to xylene vapor may produce central nervous system excitation followed by depression. Exposure to xylene vapor can produce dizziness, staggering, drowsiness and unconsciousness. At very high concentrations, xylene vapor may produce lung irritation, nausea, vomiting and abdominal pain. Xylene is not known to possess the chronic bone marrow toxicity of benzene, but liver enlargement and nerve-cell damage have been noted from chronic overexposure. 8.0 GAS/VAPOR MONITORING PROCEDURES The greatest potential hazards to safety and health at this site are: 1. Exposure to chemical vapors - through inhalation 2. Exposure to chemical contamination - through skin contact and ingestion. Ongoing air monitoring during project tasks will provide data to ensure that vapor concentrations are within acceptable ranges and will provide adequate selection criteria for respiratory and dermal protection. 8.0.1 If PID readings exceed 100 ppm, a NIOSH approved air-purifying respirator with organic vapor cartridges must be worn by all site workers within any area where monitoring results exceed 100 ppm. 8.0.2 If PID readings exceed 750 ppm, level B protection will be required. Personnel must leave site immediately and contact site safety officer or Health & Safety Manager for further instructions. 8.0.3 Respirator cartridges will be changed once per day as a minimum. This can be accomplished at the end of the work day during respirator decontamination. If odor breakthrough is detected while Wearing the respirator or breathing becomes difficult, change cartridges immediately. 8.1 Tasks Performed Within a Confined Space When site work takes place in a confined space the air must be monitored for (a) oxygen level; (b) explosive vapors; and (c) toxic vapors. The following air monitoring procedures must be followed before entering a confined space. ARCO~8.SSP/~O 12 [--]~-~[~ GROUNDWATER [-~[][~ TECHNOLOGY, INC. I I i I I I I I I I I I I ,I i ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan £ebruaq/ 7, 1991 ao Oxygen Level: Monitor for % Oxygen with a O2/LEL Meter to ensure a minimum oxygen level of 19.5%. Oxygen level monitoring will be done at the top, middle and bottom of the enclosed space to determine if there is a minimum acceptable oxygen level of 19.5% prior to entry. If oxygen is less than 19.5%, do not enter the space. bo Explosive Vapors: Monitor for % of Lower Explosive Limit (LEL) with a 02/LEL Meter to determine whether vapor concentrations within the confined space exceed 20% of the LEE If readings exceed 20% LEL, personnel shall shut off accessible equipment, leave the site immediately, and contact the fire department. Co Toxic Vapors: Monitor the air within the confined space for organic vapors with a PID or FID following guidelines stated in Section 8.0 (above) to decide on the respiratory protection needed. Enter the space only if the oxygen level is at or above 19.5%, the %LEL is below 20%, the toxic vapor concentration is determined, and the proper respiratory protection is worn. PID or FID readings will be taken at the top, middle and bottom of a vault, shed, or other confined space to ensure that vapors do not exceed acceptable levels. All monitoring equipment must be calibrated and maintained in accordance with manufacturer's recommendations. 9.0 HEALTH AND SAFETY REQUIREMENTS 9.1 Medical Monitorinq Proqram All Groundwater Technology, Inc. field personnel are required to have annual medical evaluations in accordance with the company's Health and Safety Program policy. Additional re-evaluation will be considered in the event of chemical over-exposure while working on this site. The petrochemicals typical of these facilities can affect specific organ systems producing characteristic health effects. The medical evaluation will, therefore, focus on the liver, kidney, nervous system, blood systems, and skin and lung function. Laboratory testing will include complete blood count, and applicable kidney and liver-function tests. Other tests include skin examination. 9.2 Training All personnel working at this site should have received a minimum of 40 hours of initial hazardous waste activity instruction, and a minimum of three days of field experience under the direct supervision of a trained, experienced person. Personnel assigned to the site will also receive eight hours refresher training per year. On-site managers and supervisors directly responsible for employees engaged in hazardous waste operations have received an additional eight hours of supervisory training. These training requirements comply with the OSHA Hazardous Waste Operations and Emergency Response regulation, 29 CFR 1910.120. ARCO~8.SSP/~O 13 ~--][][~ GROUNDWATER -~--~ TECHNOLOCY, INC. '1 ! I I I I I I I ARCO PRODUCTS COMPANY- SS #6215 Site Safe~/ Plan February 7, 1991 I I I I I I I I I I The initial 40-hour training and the 8-hour annual refresher training includes specific details on the following: Regulatory Requirements · First Aid/CPR Confined Space Entry Respiratory Protection Air Monitoring Decontamination Procedures Hazard Communication Toxicology These specifications are then complimented with actual hands-on experience with the use of personal protective equipment and air monitoring equipment. 9.3 Work Zones Access Access within a 5-foot radius of any on-site operation is prohibited to all but Groundwater Technology, Inc. field personnel and subcontractors. 9.4 Emergency Equipment Vehicles used for site work will be equipped with a first aid kit and safety equipment including: fluorescent vests, cones, flags (as needed) barricades (as needed) · fire extinguisher-dry chemical ABC-type extinguisher, flashlight, water, suitable for drinking, portable eye wash, appropriate emergency bandage material. 9.5 Carbon Treatment If this site involves the use of a Carbon Treatment System, then the following information will apply. The Carbon Treatment System is equipped with an emergency shut-off. The system will shut off automatically when the non-methane TPH vapor concentrations in the intermediate line reach 5% of the Lower Explosive Limit (LEL) for gasoline as recorded by the system monitors. The suggested equipment for decontamination and spill response procedures includes: · wash tubs (3) plastic sheets trash bags scrub brushes detergent sorbent booms (as applicable) The carbon system is a closed system where no chemicals are used. The potential for a spill is minimal and thus spill containment is not addressed in this Site Safety Plan. ~GROUNDWATER ^Rco~s.ss~/,~o 14 ~__JL__L_J,J TECHNOLOGY, INC. 1 ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan IFebruary 7, 1991 '! I i I I 9.6 Drillinq Procedures A Dig-Alert authorization number must be obtained prior to drilling. During the drilling operation, two persons (one designated as "driller" and the other as "helper") must be present at all times. The helper (whether Groundwater Technology, Inc. personnel or subcontractors) must be instructed as to the location of the emergency shut-off switch. Every attempt must be made to keep unauthorized personnel from entering the work area. If this is not possible, the operation should be shut down until the area is cleared. The area where the operation is taking place shall be cordoned off with a barricade. The Site Safety Officer or the Field Team Leader has the authority and the responsibility to shut down the drilling operations whenever a hazardous situation is deemed present. The mast of the drilling rig must maintain a minimum clearance of 20 feet from any overhead electrical cables. All drilling operations will cease immediately during hazardous weather conditions such as high winds, heavy rain, lightening and snow. I ! Hart hats shall be worn at all times. Hearing protection shall be worn during noisy operations. If product is encountered during the drilling operation, all work must stop in order for employees to upgrade personal protective equipment to Level C. A full-face respirator should be worn in order to prevent the inhalation of vapors and to provide face and eye protection from splashes. Coated tyvek suits, gloves, and overboots should be worn to prevent skin contact with the soil. Air monitoring must be performed in the work area to document breathing-zone concentrations. If air monitoring results indicate concentrations greater than 700 ppm, then Level B respiratory protection will be implemented. i I Respirator cartridges must be changed at the end of a work period or if "breakthrough" occurs. If employees experience continuous cartridge "breakthrough", then the employees' work procedures and the level of respiratory protection must be re-evaluated by the Site Safety Officer and the Health and Safety Manager in order to determine the necessity of upgrading to Level B respiratory protection. 9.7 Electrical Equipment and Ground-Fault Circuit Interrupters I I All electrical equil:ghent and power cables in and around wells or structures suspected of containing chemical contamination must be intrinsically safe and equipped with a three-wire ground lead, rated explosion-proof for hazardous atmospheres. In accordance with OSHA 29 CFR 1926.404, approved ground fault circuit interrupters (GFCI) must be used for all 120 volt, single phase, 15 and 20 ampere receptacle outlets on the site which are in use by employees. Receptacles on the ends of extension cords are not part of the permanent wiring and therefore, must be protected by GFCI's whether or not the extension cord is plugged into permanent wiring. I I I I I The GFCI is a fast-acting circuit breaker which senses small imbalances in the circuit caused by current leakage to ground, and in a fraction of a second shuts off the electricity. However, the GFCI will not protect the employee from line-to-line contact hazards (such as a person holding two "hot" wires or a hot and neutral wire in each hand). The GFCI does provide protection against the most common form of electrical shock hazard - the ground fault. It also provides protection against fires, overheating, and destruction of insulation on wiring. GFCIs can be used successfully to reduce electrical hazards on construction sites. Tripping of GFCIs - interruption of current flow -is sometimes caused by wet connectors and tools. It is good practice to limit exposure of connectors and tools to excessive moisture by using watertight or sealable connectors. Providing more GFCIs or shorter circuits can prevent tripping caused by the cumulative leakage from several tools or by leakages from extremely long circuits. (Adapted from OSHA 3007; Ground-Fault Protection on Construction sites, 1987.) [[][~]] GROUNDWATER .~co~,,.ss,/o~o 15 [--][~][~/TEC HNOLOGY, INC. I I I I I I I I I I I I I ! I ARCO PRODUCTS COMPANY- SS Site Safety Plan February 7, 1991 9.8 Fire Prevention During equipment operation, periodic vapor concentration measurements should be taken with an explosimeter or combustimeter. If at any time the vapor concentrations exceed 20% of LEL, then the Site Safety Officer or designated field worker should immediately shut down all operations. Only Factory Mutual (FM) approved fire safety cans will be used to transport and store flammable liquids. All gasoline and diesel-driven engines requiring refueling must be shut down and allowed to cool before filling. Smoking is not allowed during any operations within the work area in which petroleum products or solvents in free-floating, dissolved or vapor forms, or other flammable liquids may be present. No open flame or spark is allowed in any area containing petroleum products, or other flammable liquids. 9.9 General Health Medicine and alcohol can increase the effects of exposure to toxic chemicals. Unless specifically approved by a qualified physician, prescription drugs should not be taken by personnel assigned to operations where the potential for absorption, inhalation, or ingestion of toxic substances exists. Drinking alcoholic beverages is prohibited. Drinking alcoholic beverages and driving is prohibited at any time. Driving at excessive speeds is always prohibited. Skin abrasions must be thoroughly protected to prevent chemicals from penetrating the abrasion. It is recommended that Contact Lenses not be worn by persons working on the site. 9.10 MSDS Information Material Safety Data Sheets (MSDS) on chemical substances encountered at the site shall be made available to all persons (including subcontractors) working at the site. These MSDSs shall be enclosed within this site safety plan in Appendix E. For emergency situations not specifically addressed by this site safety plan, refer to MSDS recommendations for action information. 10.0 PROJECT PERSONNEL Groundwater Technology, Inc. will oversee and act accordingly during all phases of the project. The following management structure will be instituted for the purpose of successfully and safely completing this project. 10.1 Project Manaqer: Jon Parker The Project Manager will be responsible for implementing the project and obtaining any necessary personnel or resources for the completion of the project. Specific duties will include: coordinating the activities of all subcontractors, to include informing them of the required personal protective equipment and insuring their signature acknowledging this Site Safety Plan (see Appendix A), selecting a Site Safety Officer and field personnel for the work to be undertaken on site, ensuring that the tasks assigned are being completed as planned and on schedule, ARCO6218.SSP/e20 1 6 CROUNDWATER TECHNOI,OC¥, INC. ,i I I I I I I I I I I I I I i I I I ARCO PRODUCTS COMPANY- SS Site Safety Plan February 7, 1991 · providing authority and resources to ensure that the Site Safety Officer is able to implement and manage safety procedures, · preparing reports and recommendations about the project to clients and affected Groundwater Technology, Inc. personnel, ensuring that persons allowed to enter the site (i.e., EPA, contractors, state officials, visitors) are made aware of the potential hazards associated with the substances known or suspected to be on site, and are knowledgeable as to the on-site copy of the specific site safety plan. ensuring that the Site Safety Officer is aware of all of the provisions of this site safety plan and is instructing all personnel on site about the safety practices and emergency procedures defined in the plan, and ensuring that the Site Safety Officer is making an effort to monitor site safety, and has designated a Field Team Leader to assist with the responsibility when necessary. 10.2 Health & Safety Manaqer Maureen Grant The Health & Safety Manager shall be responsible for the overall coordination and oversight of the site safety plan. Specific duties will include: approving the selection of the types of personal protective equipment (PPE) to be used on site for specific tasks, monitoring the compliance activities and the documentation processes undertaken by the Site Safety Officer, evaluating weather and chemical hazard information and making recommendations to the Project Manager about any modifications to work plans or personal protection levels in order to maintain personnel safety, coordinate upgrading or downgrading PPE with Site Safety Officer, as necessary, due to changes in exposure levels, monitoring results, weather, other site conditions, approving all field personnel working on site, taking into consideration their level of safety training, their physical capacity, and their eligibility to wear the protective equipment necessary for their assigned tasks (i,e.: Respirator Fit Testing Results), and, overseeing the air monitoring procedures as they are carried out by site personnel for compliance with all company health and safety policies. mlS.SSP/~20 17 J--I[][] GROUNDWATER [~[---[[~] TECHNOLOGY, INC. I I I I ARCO PRODUCTS COMPANY- SS Site Safety Plan FebruarY 7, 1991 I I I I I I I I I I I I I I I 10.3 Site Safety Officer Jon Parker The Site Safety Officer shall be responsible for the implementation of the site safety plan on site. Specific duties will include: monitoring the compliance of field personnel for the routine and proper use of the PPE that has been designated for each task, · routinely inspecting PPE and clothing to ensure that it is in good condition and is being stored and maintained properly, stopping work on the site or changing work assignments or procedures if any operation threatens the health and safety of workers or the public, monitoring personnel who enter and exit the site and all controlled access points, reporting any signs of fatigue, work-related stress, or chemical exposures to the Project Manager and/or Health & Safety Manager, dismissing field personnel from the site if their actions or negligence endangers themselves, co-workers, or the public, and reporting the same to the Project Manager and/or Health & Safety Manager, reporting any accidents or violations of the site safety plan to the Project Manager and/or Health & Safety Manager, and documenting the same for the project in the project records, · knowing emergency procedures, evacuation routes and the telephone numbers of the ambulance, local hospital, poison control center, fire and police departments, ensuring that all project-related personnel have signed the personnel agreement and acknowledgments form contained in this site safety plan, · coordinate upgrading and downgrading PPE with the Health & Safety Manager, as necessary, due to changes in exposure levels, monitoring results, weather, and other site conditions, and perform air monitoring with approved instruments in accordance with requirements stated in this Site Safety Plan (see monitoring procedures on page 20 for specific information). 10.4 Field Team Leader Maura Hanninq In the event that the Project Manager and the Site Safety Officer are not on site, the Field Team Leader will assume all responsibility of the Site Safety Officer. ARCC~S.SSP/,20 1 8 ~-~'[] GROUNDWATER ~--]~ TECHNOLOGY, INC. I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS Site SafeSt Plan February 7, 1991 10.5 Other Field Personnel Technician staff is responsible for system maintenance, calibration and system operation. Records of site visits documenting system conditions are maintained by the technicians. All field personnel shall be responsible for acting in compliance with all safety procedures outlined in the site safety plan. Any hazardous work situations or procedures should be reported to the Site Safety Officer so that corrective steps can be taken. 10.6 Medical/Technical Advisors Frank H. Lawrence, M.D. ENVIROLOGIC DATA, Portland, Maine ................(207) 773-3020 Marilyn E. Grant, R.N., B.S., C.O.H.N ENVIROLOGIC DATA, Portland, Maine ................(207) 773-3020 Lori St. Pierre, I.H.I.T. ENVIROLOGIC DATA, Portland, Maine ................(207) 773-3020 The specific duties of the Medical/Technical Advisors include: $ providing technical input into the design of the site safety plan, advising worker exposure potential along with appropriate hazard reduction methods, and recommending a suitable medical monitoring program for the site workers. ARCO~ S.SSP/~O 19 [~[~[~] GROUNDWATER TECHNOLOGY, INC. I I I '1 I I I I I I I I I I I I I ARC062~ 8.SSP/~f 20 APPENDIX A (Agreement and Acknowledgment Statement) [-]~[~ TEC.NOLOGY, INC. __J ll O OUN W^T [[ II I TECHNOLOGY, INC. SIGN- OFF SHEETS This is Io cerlily that I have read, fully undersland and agree to comply fully with the atlached Health and Safety Plan furnished 1o me by Groundwater Technology, Inc. for the above project. NAME SIGNATURE COMPANY DATE I I I I I I I I I I I I I I I APPENDIX B (Site Safety Plan Amendment Sheet) ARCO6218.~SP/~20 r~[--~L~-I GROUNDWATER ~'--~-'~[~ TECHNOLOGY, INC. ' '1 I I I I I I i I I I I I I I ! I I I APPENDIX B Site Safety Plan Amendment Sheet Project Name: Project Number: Location: Changes in field activities or hazards: Proposed Amendment: Proposed by:,__ Date: Approved by: Date: Project Manager Date: Health & Safety Manager Declined by:. Amendment Number: Amendment Effective Date: Date: ARCOOa'Ia.&,qP/~2o [~[--'[[~] GROUNDWATER [--~[][] TECHNOLOGY, INC. '1 I I I I I I I I I I I I ! I I I I I ARCO6218.SSP/f20 APPENDIX C (Definition of Hazard Evaluation Guidelines) it-1~1 C,~O~JXDw^T~.~ I---]~JTECHNOLOCY, INC. I I I I I I I I I I I I I I i I I I Hazard: Airborne Contaminants Guideline. Threshold Limit Value Time-Weighted Average (TLV-TWA) Permissible Exposure Limit (PEL) Immediately Dangerous to Life and Health (IDLH) Hazard: Explosion Guideline Lower Explosive Limit Upper Explosive Limit (UEL) Hazard: Fire Guideline Flash Point (flash p) APPENDIX C Definition of Hazard Evaluation Guidelines Explanation The time-weighted average concen- tration for a normal 8-hour work day and a 40-hour work week, to which nearly all workers may be repeatedly exposed without adverse effect. Time-weighted average concentra- tions similar to (and in many cases derived from) the Threshold Limit Values. "IDLH" or "Immediately dangerous to life or health" means any atmospheric condition that poses an immediate threat to life, or which is likely to result in acute or immediate severe health effects. This includes oxygen deficiency conditions. Explanation The minimum concentration of (LEL) vapor in air below which propagation of a flame will not occur in the presence of an ignition source. The maximum concentration of vapor in air above which propagation of a flame will not occur in the presence of an ignition source. Explanation The lowest temperature at which the vapor of a combustible liquid can be made to ignite momentarily in air. ARCO6218.SSP/~20 [][]1~ C.OVNDW^TE. [~[~[] TECHNOLOGY, INC. I I I I I I I I I I I I I I I I I APPENDIX D (site maps) ARCO6218.~SP/#20 r--][---][--~ TECHNOI~OC¥, INC. I I ! I I I I I I I I I I I I I I I I " ~ ' '~,.,~..., Dr," Z: :~ ,~. .*..~' ~.hnm .-Giomquis~ .~..~ : M~Y ~ ~ ~ , ,, ~,. ._...,... , ....... .., ,.. ........ ~ ~....~,. ~., ~, ~ ~:~j =~:~, ~ , . ~ ........ · ~'t -.. -~ ......... ' · · .... ~Site ! N i~ JO~ ~ 215 SZTE, ARCO SS ~6218 $5O 06O7 ~ s~[~c, 4203 Ming Avenue B~kersfield, C~liforni~ HAP TYPE~ Locetion Index DRAWN DY, DATE: APPROVED DY: I DATE, SCALE, MH 2/91 JDP1 2/91 REV REV]S]BN DATE 3Y 1/2 0 114 1/2 ~i~e$ ! ! MING A VENUE Planter Planter . Building Poll Box~ LEGEND N Proposed Boring SCALE, 40' 0 20' 40' jnB # 215 SITE, ARCO SS #6218 350 0607 site LOc, Bakersfield, California MAP TYPE, Site Map ])RAWN ~Y, I DAT£' APPRI3V£D BY' I I)ATE' CA 2/91 JDP 2/91 REV REVISION DATE BY i I I I I I I I I I I I I I I I .I.. ~ · >~. ~' / ;~ >~'~-~~:~,,~lr,~ll::ll.:.:li::~ ~ .... ......... :(~~---~~-~~, ~,~ :~ : / ~ Mercy Hospifal 2215 Truxfon Ave. San Joaquin Hospital 2615 Eye St. Memorial HospHal 420 54th St. ~ ' SCALE~ 1/~ 0 1/4 mi[es U.S.G.S. 7.5 Minute Quadrangle I I I I I I I I I I I I I I I I I I APPENDIX E (MSDS) ARC~O6218.SSP/~20 []1--!1~ C, ROUNDW^TER I---1[~ T~'.CHNOLOG¥, INC. I I ! I I I I I I I I ! 1' I Material Safety Data Sheet No. 316 BENZENE From Genium's Reference C~fion Genium Publishing Corporation'~~ ~Revision D) 1145 Catalyn Street ] Issued: November 1978 Schenectady, NY 12303-1836 USA {'518) 377-8855 GENlUu puau..,~a coap. Revised: April 1988 SECTION 1. MATERIAL IDENTIFICATION 25 A Material Name: BENZENE Description (Origin/Uses): ' Used in the manufacture of medicinal chemicals, dyes, linoleum, air, lane dopes, varnishes, and lacquers; and as a solvent for waxes, resins, and oils. HMIS Other Designations: Benzol; Phene; Phenylhydride; C,H~; NIOSH £T£C$ No. CYi400CC~; H 2 CAS No. C07143-2 F 3 R 1 R 0 I 4 Manufact~,rer: Contactyour supplier or distributor. Consult the latest edition of the Ch. errdcalweek Buyers' Guide (Genium ref. 73) for a list of suppliem PPG* S 2 *See sect. 8 K 4 SECTION 2. INGREDIENTS AND HAZARDS % EXPOSURE LIMITS Benzene, CAS No. (X)71-43-2 Ca 103 OSHA PEL 8-Hr'I'WA: 1 ppm 15-Min Ceiling: $ ppm Action Level: 0.5 ppm ACGIH TLV, 1987-88 TLV-TWA: 10 ppm, 30 mg/m~ Toxicity Data* Human, Inhalation, LCd: 2003 ppr"../5 Min *See NIOSH, RTECS, for additional data with references to ;.crita~ve, mutagcnic, Human, Oral, TD,$ 130 md/kg tumorigenic, and reproductive effects. Human, Inhalation, TCu: 210 ppm SECTION 3. PHYSICAL DATA Bolling Potnt: 176'F(80'C) Water Solubility (%): Slight Melting Point: 42'F(5.5'C) % Volatile by Volume: 103 Vapor Pressure: 75 Torrs at 68'F (20'C) Molecular Weight: 78 Gram_vMoie Vapor Density (Air = 1): >1 Specific Gravity (H:O = 1): 0.$7865 at6,VF (20'C) Appearance and Odor: A colorless liquid; char<::.-:sti¢ azom:tic odor. SECTION 4. FIRE AND EXPLOSIONDA. TA [ LOWER I UPPER Flash Point and Me,od Autoignition Temperaw. re ] Flammability Limits in Air 12'F (-1 lA'C) CC 928'F {'495'C)]. % by Volume 1.3% 7.1 Extinguishing Media: Use dry chemical, foam. or casa. on dioxide to putout benzene fires. Water may be ineffective ~ an exti::g'.'L<:icg agent because it can scatter and spread the fire. Use wa'"r ,..o c~el f~.exposed containers, flush spills away from exposures, dLspcrse vapor, ara protect personnel attempting to stop an unigniteg ~egzer. e leak. Unusual Fire or Explosion Hazards: Ben.ne vapor is heavier than air and can collect in low-lying ~reas such ~ sumps or wel~. ELiminate a~ sourers of ignition there to prevent a dange:'~us fl~shback to the original liquid benzene. Danger: Explosive and flammable benzene va?or-aiz mLxtures can e~ily form at mom tempe.'-.v,:'~; always use this material in a way that minimizes dispersion of its va~r general work areas. Special Fire-fighting Procedures: Wear a se!f-c~ntaL':.ed breathing apparatus (SCBA) with a full facepiece ope,'-a~ in the press=re- demand or ~sitive-pressure mode. SECTION 5. REACTIVITY DATA Benzene is stable in closed containers d ,u.rbg routine operations. It does not undergo hazacdous polymerization. Chemical Incompatlbllltles: Hazardous chemical re~tions involving benzene and the following materials are repor'~ed in Genium reference 5~: bromine pentafluoride, chlorine, chlorine triaquoride, chromic anhydride, nitryl perehlorate, oxygen, ozone, perehlorates, perchlo~'l fluoride and aluminum chloride, permanganates and sulfuric acid, potassium peroxide, silver perchlorate, and sodium peroxide. Conditions to Avotd: Avoid all exposure to sources cf ignition :md to incompatible che,-dcals. Hazardous Products of Decomposition: Toxic gags like carbon monoxide (CO) may be produced during benzene fires. Co~fight D 1955 Gcv. i~m P~li.~",~I C~q:,cntion. An)' carn:x~'c~J ~e pi' :'t~odu:,tion without ~c ~cmum r'LlOllSFllrlg t, OIp()IritllUll 1145 Carolyn Street Schenectady, NY 19303-11 ~USA ' (518) 377-8855 SECTION 1.' MATERIAL IDENTIFiCATiON ~~.~ I('RevisiOn D) ]Issue: Au,2_ust 1979 ~..u,. ~u~u~ ~Revised: ~vfil 1986 20 IMAIEIH,M..HAMI2 llll Ill'Ill: IlMI~ '1 I OTHER DESIGNATIONS: Methyl B¢:;ze~e, Methyl B~mk l~,,enylz::¢~h~''e, ToP',mi, . · C7H8, CAS ~108-8,~-3 I~{ANUFACTURE,RYSUPPU~,R: Av~able from m_~.y r;ppE¢:'s, includ~g: -A1Eed Car7., FO Box 2064R, Morrism',,m, NJ 07.~60; Tek.:ho:¢: (201) 455-42,00 'Ashh.ud Cne~caI Co., Inc!us~i~ C'r,e~c-~-- & S~Iv~ Div., FO Box 2219, Columbus, OH; Telephone: (614) 889-31L14 H: 2 F: 3 R: 0 P?E* *See s~.:. 8 I 3 S2 K4 I .:~SECTION 2,-.INGREDIENTS AND HAZARDS" : ..: :-....:....:.-.:~..-% .-- .,'HAZARD DATA Tolueae ca 103 I I I ~3 * . Cu..-:.-.t (1985-86') ACGIH TLV. "Fr.e OSHA ?EL ac~puble cs..'h'ng co:c~n~a~on of 303 ~rn rr2zLmum ix22r cliO0 pp~YlO ** Skin desigv, at/on k,.dica'--: that mluc:c can be s~ azd coa~bu'.e ~ or,all ex,sum. *** Aff~ts the mL,',d. :)SECTION 3,"PHYSICAL DATA . :' .... .. -".'. ::-' " -'- ..:. ....... '...-': .'- ... . . ! I I BoLling ?o~: ... 231'F (iIi'C) Ev~"cr:'"c: Razz (BuAc = 1) ... 2.2.:' Vapor Fre..ss,~z-e @ 20'C, rm,-n Hg ... 22 $._u.c Gravity (H20 = 1) ... C,.~.f6 Water Sclub~r'/@ 20'C, wt. % ... 0.05 Md~g To;mt ... -139'F (-PJ'C) Va~r Dezsi..'y (?dr = 1) ... 3.14 Pe.~."zt ",'cI~.~.2e by "/olu=e ... ~ ICG ,V.c!m',:'! --z '¢,'c:.gh: ... 92_. 15 A77¢.?:'-:c: ........ '-'~ od,','- Cie,...,, cclcrl.cru Squid ~d£'; a ck---~'_-.hff: a"o.m2'dc o.Sz.'r. 'Er.c o:cr b dz_,m:.,¢o'--, ' ' ~2 rcs: "-dh'!d",-',~ ;-- u.e r.:i: cf I0 r~ 15 ppm. E-~-ause. cb~3c:zry fafig'.'c oc.:'zn ..:....--:-:::v u:c'a, exTosu~ ko ~u=:, c~r is r~ot a gxd wa--;-g grope.?. :SECTION 4.'FIRE AND EXPLOSION DATA ' '- '.". :-..:~ :'i LOWER[ Fl~h Pom¢ a~d Me'~,cclI Autcignidon Te:r.z. I Fia.m. m2b iii %. LLm, jts L,~ ALt I 40'F (4'C) CC 89-5'F (4~0'C~ I % by Vo:....~.: 127 7.1 I LXTINGUISE!NG MEDIA: C~'oon dio~dc, d~ chem"cfi, £cc'.'.cl fcam EYo not ,u~ a I I :SECTION 5.:-'REAcflVITY DATA '":--.-. -:'- .... - I 'l CHEMICAL t.x,'COMPATtBI~2'TI~$: Toluene is suble ;,' clc~:d ccc~ at rc~m tez--..,'~:'a--'.~ h~dliag co,"ditio~s. It does r<~t und~'rgo h-aza..~ous l:cly'~_--.'.za'Jc:. 'Fr~ maL-fi.'al h ioco~-~-':'ble wi~h s~--m=g o~d~ agents, d'-~,$en re'o'-aox[de, silver, p,:xh;cra~, te:-ar.-;~:--.eLkar,:, ~':.d u.'-a.n[um ]-,exa.t'iucfid~. C~oL~t wiLh rr2y cause f4": or explosion. Ni~c ~:d a,,d ~Iuez, e, e~e.:f~y h tY,~ pr-_~-~ca of suLeu,"ic ac:d, w;',l Frcduc.: compour~ds ~at a.~ dange.musly explosive. CONDITIONS TO AVOID: Avoid ex.~svzr: to ~a"ks, c~.n fh..-:¢., b.:t .,,.u4aces, a=d ~I mu.,'-,2s cf ~ ~ ig::i.':c-:. Tol,-'--:: ~,511 aruck some fom",a of pla/tics, rub!:~r, c:u'bou me:ox/de. I From Oenium's Reference C,~ection ~{ " CeRium Publishing Corporafic~ - XYLENrE D)(Mixed Isomers) 1145 Catalyn Street Schenectady, NY 12303-1836 USA Issued: November 1980 (518) 377-8855 GENIUM ~'U"US.~.C CO... Revised: August 1988 Material Name: XYLENE (Mixed Isomers) - - /~, Description (Origin/Uses): Used as a raw material for the production of benzoic acid, phthalic anhydride, isoph~alic a~d terephthalic acids and their dimethyl esters in the manufacture of polyester fibers; in sterilizing catgut; with Canadian balsam as oil-immersion in microscopy; and as a cleaning agent in microscopic techniques. Other Designations: Dimethylbenzene; Xylol; C,H,o; CAS No. 1330~20-7 NFPA Manufacturer: Contact your supplier or distributor. Consult the latest edition of the Chemicalweek I-t5fi5 Buyers' Guide (CeRium ref. 73) for a llst of suppliers. H 2 R 1 Comments: Although there are three different isomers of xylene (ortho, ,zeta, and para), the health and physical F 3 hazards of all three isomers are very similar. This MSD5 is v, Titten for a xylene mixture of all three isomers, R 0 I 3 which is usually commercial xylene. PPG* S 2 *See sect. 8 K 3 Xylene (3,fixed Isomers), CAS No. 1330-20-7' ** IDLH"' Level: 1¢~ ppm *o-Xylene, CAS No. 0095-47-6 OSHA PEL m-Xylene, CAS No. 0108-38-3 8-Hr TWA: 1(30 ppm, 435 ' p-Xylene, CAS No. 0106-42-3 ACGIH TLVs, 1987-88 i "Check with your supplier to determine if there are additions, contaminants, or TLV-"I%VA: 100 ppra, 435 mg/m~ impurities (such as benzene) that are present in reportable qu~tides per TLV-STEL: 150 ppra 655 mg/m~ 29 CFR 1910. '"Immediately d~gerous to life and health. Toxicity Data .... Human, Inhalation, TC~: 2C0 ppm **** See NIOSH, RTECS (No. ZE_100C~30), for additional dam with references Man, Inhalation, LCt~: lCCCO ppm'6 Ers to reproductive, irritative, and mutagenic effects. Rat, Oral, LDso: 450,3 md/kg SECTION 3. PHYSICAL DATA :- . '+.":.:-' ...? ' ::..:~:.':::'.. : .:" Boiling Point: 275'F to 293'F (135'C to 145'C)* Water Solubility (%): Insoluble Melting Point: -13'F (-25'C) Molecular Weight: 106 Evaporation Rate: 0.6 Relative to BuAc = I % Volatile by Volume: Ca Specific Gravity (H:O = 1): 0.86 Vapor Pressure: 7 to 9 To,Ts at6$'F(20'C) Vapor Density (Air = 1): 3.7 Appearance and Odor: A clear liquid; aromatic h.vdr.gcarbon odor. *Materials with wider and narrower boiling ranges are ccmmercia!!y available. SE. CTION4.'FIRE AND EXPLOSION DATA ' " " LOW£R I UPPER Flash Point and Method Autoignition Tem?erat'dre Flammability Limits in Air 8 i'F to 90'F (27'C to 32'C) 867:F (~64'C) % by Volume 1% 7.% . d.,~x,,.~. Use water sprays to reduce the rate of burning a.-_.d tc cool con:a!.-.ers. Extinguishing Media: Use foam, dry chemical, or ca,on :~ Unusual Fire or Explosion Hazards: Xvlene vavor is ~eavie: than air and may travel a considerable distance to ~ !ow-~vir, o source ~gnition and flash back. Special Fire-fighting Procedures: Wear a self-ccntaZed breathing apparatus (SCBA) with a full facepiece opera,~d in dne pressure- demand or positive-pressure mode. SECTION 5'. REACTIVITY DATA Xylene is stable in closed containers during routine o~r'.'ions. Ir does not undergo hazardous polymerization. Chemical Incompatibilities: This material may react dangerously with strong oxidizers. Conditions to Avoid: Avoid any exposure to sources ofignit!cn and to strong oxidizers. Hazardous Products of Decomposition: Carbon monox/de (CO) may be evolved during xylene fires. ! I I I I I I I I I I I I .I I I Colas'right ~ 19:g,i Ge=Jam Publ;,,.~'.;,',l: Coq:~'atioa. I I I I I I I I I I I I I I I MATERIAL SAFETY DATA SHEET 1145 C, AIALYN SIRE: f .. SCHENECTADY. NY 12303-1836 USA ' ' (518} 377.8855 385 No. ETHYL OtN~UMPUBUS~¢CC~ Date August 1978 SECTION I, MATERIAl' IDENTIFICATION MATERIAL NAME: ETHYL BENZ~-NE OTHER DESIGNATIONS: Phenylethane, Ethylbenzol, C2H5C6H5, CAS# 000 100 4!4 btANUFACTURER: Available from several suppliers, SECTION II, INGREDIENTS AND HAZARDS = I-tAZA~.D DATA Ethyl Benzene ca 100 8-hr *Current OSHA permissable exposure level. A Standard was proposed by OS~& in October 1975 which includes an action level of 50 ppm, and de:ailed requirements of monitoring, medical surveillance, employee train- ing, etc.; when exposure exceeds 50 ppm. It has not vet issued as a legal reouirement. Huron, inhalation TCLo lO0 ppm for 8 hr (irritation) Rat, Oral LD50 3500 mg/kg SECTION III, PHYSICAL DATA Boiling point at 1 arm, deg C -- 136 Vapor pressure at 25.9 C, ram. Hg - 10 Vapor density (Air=l) 3.66 Water solubility a~ 20 C W~. % - 0.015 Specific gravity 20/4C ....... 0.867 Volatiles. % ca !00 Evaporation ra~e (B~c=!) ..... <l Melting point, dog C -95 Molecular weight !C6.!6 Appearance & Odor: Clear, colorless liquid with an aromatic hydrocarbox odor, SECTION IV, FIRE AND EXPLOSION DATA Flash P°int and Meth°d / Au[°i~n[:ion Tenm' I Flammabili[v Limits In Airl i 59 F (15 C) (closed cu¢~ 810 ~ (~3'.~ C) Vol=to % ,], 1.0 6.7 Extinguishing media: Carbon dioxide, dry chemical or "alcohol" foam. A wate~ spray may be ineffective to put out fire, but may be used to cool fire-ex?=sed ccm:ainer A strea~ of water can spread fire cf burning liquid. This is a'flammmble liquid (OSH.& Class lB) which can readily fo~ exp. lcsive mixtures with air, esoecially when heated. Heavier-than-air vaoors can flow a!cng surfaaes to reach distant ignition sources, axd then flash back' Firefi~hters should use self-contained breathing equipment azd eye protection ~o fight ~ires i~ enc!csed places. SECTION V, REACTIVITY DATA This material is s~able in storage in closed containers at room temperature. It does not polymerize. This flammable material should be kept separated from oxidizing agents, strong acids and bases and ammonia. Thermal-oxidative degradation can produce toxic products, including carbon monoxide. I Cop.~r~hl ~'. 19~.1 GerJ~m Publ~r'4 Corpor~km A~.~ ¢ch~vflcrr~J u~" ~,~1~o~1 p~Jb[J~.~r's ,pe~-t~c ~:~t~m~on b, pruJllb~l~cl GENIUM PUBLISHING I ~ ~ NO. 467 Ab~OMOTIVE GENIUM PUBLISHING CORPORATION GASOLINE, LEAD-FREE 1145 CATALYN STREET SCHENECTADY, NY 12303-1836 USA (518) 377-8855 . O[NJUM ~mUSMm~CO~P. Date October 1981 SECTION I, .MATERIAL IDENTIFICATION ~ATERIALN~ME: AUTOMOTIVE GASOLINE, LEAD-¥REE DESCRIPTION: A volatile blend of hydrocarbons for automotive fuel OTHER DESIGNATIONS: Petrol, CAS #008 006 619, ASTM D439 MANUFACTURER: Available from several suppliers. SECTION II, INGREDIENTS AND HAZARDS x HAZARD DATA Gasoline 100 8-hr TWA 3~0 ppm or A hydrocarbon blend that can include normal and branche¢ 900 mg/m°* chain alkanes, cycloalkanes, alkenes, aromatics and other additives.** (Lead max 0.013 g/L, phosphorus Man max 0.0013 g/L, sulfur max 0.10 wt%. May contain Eye: 500 ppm/1H benzene, <5%; see ASTM D3606). Moderate irritation *ACGIH 1981TLV (Intended Changes List). See also Am. Ind. H¥8. A. 39 110-117 (1978) Inhalation: **The composition of fuel is varied with altitude and TCLo 900 ppm/1H seasonal requirements for a locality. The blend must TFX:CNS meet antiknock requirements. (Antiknock Index min 85, ASTM D439.) SECTION III, PHYSICAL DATA Distillation at 1 a~m, Initial, dog C >39 Specific gravity, 60/60 F - 0.72-0.76 50% distilled - 77-12t Melting point, dog C ....... 90.5-95.4 End point ..... <240 Evaporation rate N/A Vapor density (Air=l) ............. 3.0-4.0 Solubility in water Insoluble Appearamce and Odor: A clear, mobile liqui~ with a characteristic odor which can be recognized at about 10 ppm in air. (Gasoline may be colored with dye.) SECTION IV, FIRE AND EXPLOSION DATA LOwEA 'Flash Point and ~ethod I Autoi~nition ~e~. I Flammmbility Limits I~ Air -45 E 536-853 ? % by volume 1.4 7.6 Extinguishing Media: Dry chemical, carbon dioxide, alcohol fom~. Use of wa:er may be ineffective to extinguish fire, but use wa:er spray for cooling fire-exposed drums and tanks to prevent pressure rupture I: is a dangerous fire and explosion when exposed to heat and flames. Vapors can flow along surfaces, reach dis:ant igni- tion sources and flash back. Can react violently with oxidizing agents. Firefighters should wear self-contained brea[hing apparatus and full protective clothing SECTION V, REACTIVITY DATA This is a stable material in closed containers at room temperature under normal s~orage and handling conditions. It does not undergo hazardous polymerization. This is an OS~ Class IA fl~=nable liquid. A mixture of gasoline vapors and air can be explosive. It is incompatible with oxidizing agents. Thermal-oxidative degradation can yield carbon monoxide and partially oxidized hydrocarbons. i I i I I I I I I :1 I I ;I I Cop~,r~,~ ~ 1~,~ G~u~ Pub~,.bu~ Ca'-pa~k~ GENIUM PUBLISHING I I I I I I I I I I I I I I I I I I APPENDIX F (Accident Investigation Form) ARCO6218.SSP/e20 [--][][] GROUNDWATER [~[~--~ TECHNOLOCY, INC. Employee's Name: IAddress: GROUNDWATER TECHNOLOGY, INC. Accident/Incident/Near Miss Report D.O.B. D.O.H. ss# IJob Title: Office Location: Supervisors's Name: I I Location at Time of Incident: Date/Time of Incident: Description: Describe clearly how the accident occurred: Iwas Incident: Physical Part(s) of body affected: Iright left iWitnesses: 1) 2) Conditions/acts contributing to this incident: Chemical Exposure: Dermal Inhalation Ingestion iExplain specifically the corrective action you have taken to prevent a recurrence: IDid the injured go to a doctor? iDid injured gO to a hospital? Where? When? Where? When? I ! I I Signatures: Employee Reporting Manager Regional H&S Manager Date Date Date This form must be completed and returned within 5_ working days to Regional Health & Safety Manager, who wi[[ forward a copy to Corporate .aa[th & Safety Manager at ELD. :j--]i--]r~-]GROUNDWATER~_~_~.~, [--][~/TECHNOLOCY, INC. ARCO6218.SSP/~20 ! I I I ! I I I I I I ! ! I I ! I I APPENDIX G (Vapor Monitoring Sheet Form) ARCO(~18,SSP/#~O E~]F-~[~ GROUNDWATER []E~]F-! TECHNOLOC¥, INC. I I i I I I I I I I I I I I I ! i I I APPENDIX H (Excavation/Trenching) ARCO6218.SSP/~20 [~[][~ GROUNDWATER [][~[~ TEC~-INOLOCY, INC. I I I I I I I ! I I I I I I I I i I I GROUNDWATER TECHNOLOGY, INC. EXCAVATION AND TRENCHING POLICY - CALIFORNIA SAFE CODE OF PRACTICES Although many of the rules and regulations pertaining to excavation and trenching operations in the State of California closely parallel Federal Standards, this policy specifically pertains to California operations. It shall be the policy of Groundwater Technology, Inc. to ensure that all Groundwater Technology employees and subcontractors comply with the provisions within the California Code of Regulations, Title 8, Chapter 4, Subchapter 4 - Construction Safety Orders. It is inevitable that remediation procedures for which Groundwater Technology is retained will involve some aspect within the jurisdiction of the Construction Safety Orders. Such operations may include: trenching, vault construction, tank removal, and excavation of contaminated soils. DEFINITIONS - EXCAVATION, TRENCHES, EARTHWORK Bank - a mass of soil rising above a digging level. Bell Hole - an additional excavation made into the sides or bottom of a trench to provide additional work space. Belled Excavation - a part of a shaft or footing excavation, usually near the bottom and bell-shaped, that makes the cross-sectional area at that point larger than that above. Benchinq - a method of excavation whereby the faces of an excavation or trench are widened progressively outward with respect to the bottom of a specific series of horizontal and vertical cuts to provide protection against the hazard of moving ground. Braces for Excavation - the horizontal members of the shoring system, the ends of which bear against the uprights or stringers. Earthwork - the process of excavating, moving, storing, placing, and working any type of earth materials. Excavation - a man-made cavity or depression in the earth's surface, including its sides, walls, or faces formed by the removal of materials, and producing unsupported earth conditions by reason of such removal. If installed forms or similar structures reduce the depth-to-width relationship, the excavation may become a trench. Exploration Shaft - a shaft created and used for the purpose of obtaining subsurface data. Geotechnical Specialist (GTS) - a person registered by the State as a Certified Engineering Geologist, or a Registered Civil Engineer trained in soil mechanics, or an engineering geologist or civil engineer with a minimum of 3 years applicable experience working under the direct supervision of either a Certified Engineering Geologist or Registered Civil Engineer. Hard Compact - all earth material not classified as running soil. Hydraulic Shoring - a shoring system using hydrauJic cylinders, planks, rails, plywood, or steel beams to support the excavated wall of trenches. APNDIX*H/SSP MASTER [--]~' ~'~1 GROUN DWAT E R [~-~ TECHNOLOGY; INC. I I I I I I I I I I I I I I I I I I Laaaina - boards which are joined, side-by-side, lining an excavation. Runninq Soil - earth material where the angle of repose is approximately zero, as in the case of soil in a neady liquid state, or dry, unpacked sand which flows freely under slight pressure.. Running material also includes loose or disturbed earth that can be only contained with solid sheeting. Shaft - an excavation under the earth's surface in which the depth, is much greater than its cross-sectional dimensions (such as those formed to serve as wells, cesspools, certain foundation footings, and under streets, railroads, buildings, etc.) Shore - a supporting member that resists a compressive force imposed by a Icad. Shorinq System - a temporary structure for the support of earth surfaces formed as a result of excavation work. Sides, Walls, and Faces - the vertical or inclined earth surfaces formed as a result of excavation work. Sloping - a method of excavation whereby the faces of an excavation of trench are laid back to provide protection from moving ground. Spoil - the earth material that is removed in the formation of an excavation. Strinqers - the horizontal members of the shoring system whose sides bear against the uprights. Stringers are sometimes called whalers. Strut - a structural member designed to resist forces, either tensional or compressional. Trench - an excavation made below the surface of the ground. In general, the depth is greater than the width at the bottom, but the width of a trench at the bottom is not greater than 15 feet. Trench Shield - a protective device which shields workers from the effect of ground movement and which can be moved along as work progresses. Upriqhts - the vertical members of the shoring system. Whaler - a structural member in a horizontal or heady horizontal position used for stiffening or securing other components of concrete forms, excavation sheeting, or similar temporary structures. EXCAVATION PROCEDURES (also trenches, shafts, and other earthwork) 1. Prior to beginning an excavation, the location of all underground utilities and other underground hazards shall be determined. 2. A hazard assessment shall be conducted by a qualified person to evaluate the potential exposure to employees who may work in or around the excavation. 3. The excavation shall also be inspected by a qualified person after each rain or other hazard- increasing event to evaluate the potential hazards from slides or cave-ins. 4. Anytime an employee enters an excavation 5 feet or greater in depth, that employee must be protected by a system of shoring, sloping, benching, or alternative means addressed in #15 below. APNDIX-H/SSP MASTER ~--~[-~ GROUNDW^TER '--lr~--~l TECHNOLOGY, INC. I I I I I I I I I I I I I I I I I o o 10. 11. The conditions in #4 above, will also reqUire Groundwater Technology to obtain the necessary excavation permit and/or notification procedures with Cai-OSHA. Excavated materials shall be prevented from falling back into the excavation. Spoils should be placed no closer than 2 feet from the ~dge of the excavation. Work which is conducted within the excavation should be under the direct supervision of a qualified person Who is capable of modifying the shoring or sloping system. A convenient and safe means of egress shall be provided for employees working within an excavation 4-feet deep or greater. This may consist of a stairway, ladder, or ramp located within 25 feet of lateral travel, Any employee working in the vicinity of an excavator shall not be in a position where that employee might fall into contact with the moving parts of that excavator. E, mployees shall also be wearing a reflective vest. An adequate means of water drainage shall be implemented to reduce the likelihood of run-off entering the excavation. This shall hold true during the rainy season. If the accumulation of water could pose a hazard to employees, the situation should be controlled prior to resumption of operations. All shoring systems shall incorporate the soil specifications and conditions for that particular site. The installation of shoring systems shall be conducted in such a way that the employee is propedy protected from the potential of cave-ins. Additionally, the removal of the system shall follow the same requirement. 12. If the excavation exceeds 20 feet, or if an alternative shoring, sloping, or benching system is utilized, a civil engineer currently registered in California shall prepare detailed plans showing the materials and methods to be utilized (Appendix A). 13. The detailed plans in #12 above, shall be available for inspection at the site. 14. Shoring shall be installed in accordance with Table 1-6 located within Appendix B, or as detailed in plans and specifications prepared by a State of California Registered Civil Engineer in accordance with engineering criteria within Appendix A. 15. If protective shields, (i.e., trench shields) are to be utilized for the protection of employees within an excavation, a civil engineer registered in California must prepare the necessary calculations and designs prior to the use of such equipment. 16. When sloping or benching are utilized in lieu of a shoring system, the slope shall be at least three- quarter horizontal to one vertical for excavations up to 8 feet, unless the instability of the soil requires a slope flatter than 3/4:1. For excavations greater than 8 feet but less than 12 feet, a slope of 1:1 shall be utilized (Appendix C). On the following pages are specific requirements as set by California Code of Regulation, Title 8, Chapter 4, Subchapter 4-Construction Safety Outline. The pages are facsimiles of pages from this document. APNDIX-H/SSP MASTER C_~[~,~ ~.~' G ROU N DWAT ER [--] [--1[-~.,~ TECHNOLOOY, INC. I I I I I I I I I I I I I I I I TABLE 1 WOOD ~-IO~ING FOB HARD COMPACT SOIL U~tgl~ ~t ~',~ ~ (~c.) (w~) D~ (F~) H~ W~ W~ ~ (~) W~ (F~) 0~) ~,t~ w~ (F~) 8 4 x4 Ml.~ 5to7 4 ~xlO 4x4 ~ to 1~ ~ 2~8 4x4 8 4 x 10 4x4uptol~ ~r 4 3 x 10 ~l~up~l~, 8 x 8 7~10 ~ fix8 6x6 6x8 8 6x8 4x4~ff~d~ .... 4 4 x 8 ~ffup~lY. 8 x 8 10 Io 12 8 6 x 8 4 x 4uptoff~t~ 4 4 x 10 ~ff~lm. 8 z I0 12 ~ 15 2 8 · 10 6x 6 8 x 10 '8 6 x 10 6x6uptol~ OYeT 15 to ~ 2 3 x 12 8x8 6 x 12 (~ ~init~~ 1~) ~ ~, ,~ l~l(s~6~ I I I I I I I I. I I I I I I I I WOOD SHORING FOP, EU'NNING SOIL ~ 6 · 6 ~p to 1~ ~ 3 8 x 8 ~r l~ g ~o lO ~ 4 10 x 10 ~ 1~ I I I I I I I I I I I I I I I I TABLE ~ METAL WOOD ~FIOI~INC FOB HARD C.~OMPACT SOIL 8 4 8 4 8 4 8 4 s s (s) s (~) 1o I I I I I I I I I I I I I I I I I TABLE 4 MLrTAI.,-WOOD SlqORING FOR RUNNING SOIL Stub (F,,~) 8 {o 10 10 to 12 6 2 6 8 2% 12 6 2'4 10 12 to 15 3, ~.',4 8 6 3 15 1{ to ~ 6 2% 6 8 ;3 12 10 3% 15 may h,~ modified by a civil CI-t.A_~N 0~ C~S~O~ 2.~COI:L/D Location of Samm!inq Name: ~,.¢o ~5~.z ~ ~ Address: ~z~,% tv/,,~ ,~v~. Te!ephcne: ( ) Collector Company: j~' Address: ~/e/ ~f/o.~ %~. 5~ 2-~ . Telephone: ( ~_} .¢~ -~o/ Laboratory 31~5 Pe§asus Drive Bakcrst~¢ld, CA 93308 Telephone: ('805) 393-3597 FAX: (805) 393-3623 Samo !in~_ Method: Samo!e No. /-Fff Date Time $ :50 Samo!e Tvoe: Descriotion Preservation Methods: Ana!vsis Requested Laboratory No. Relinquished Received By: Re !_.._cia_ s aea By: Company: . .,~ j__ ~ s Date Company: Date: Received By: Company: Date: Relinquished By: Comp any: Date: Received By: Company: Date: Sheet of