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MITIGATION FILE #1
GROUNDWATER TECHNOLOGY, INC. 4101Alken Street, Suite B-l, Bakersfield, CA 93308 (805) 589-8601 Fax: (805) 589-8605 March 20, 1992 Mr. Joe A. Dunwoody Hazardous Material Specialist Underground Tank Program City of Bakersfield Fire Department 2101 H Street Bakersfield, California 93301 RE: Transmittal, Site Assessment Work Plan, ARCO Facility #6218, Bakersfield, California Dear Mr. Dunwoody: Enclosed is a site assessment work plan for the subject site. If you have any questions, please contact Jon Parker or myself at 589-8601. Sincerely, OLOGY, INC. ~t~'l~n A. BOi~, REA P r([~j/ect Geologist enclosure Offices throughout the U.S., Canada and Overseas I I I Prepared For: Ms. Kateri Luka I Arco Products Company 17315 Studebaker Road Ceritos, California 90701 i (213) 404-5374 , I SITE ASSESSMENT WORK PLAN I · ARCO SERVICE STATION NO. 6218 4203 MING AVENUE BAKERSFIELD, CALIFORNIA I I i March 4, 1992 I I Prepared by: Groundwater Technology, Inc. I ' 4101 Alken Street, Suite B-1 Bakersfield, California 93308 . · (805) 589-8601 I Wri~ ~ r,,. ,~. R'-'~e s~;e'~d' E~'vi~0"onmental A~[e~Lor / / / .,~.~'.~- Reviewed by: na~than D. Parker Registered Geologist No. 4728 PARKER No. 4728 []13[~ C.OUNDw^T~.. i--]~--H-~ TECHNOLOGY I I I I I I I I I I I I I I I '1 I CONTENTS Page 1.0 INTRODUCTION ............................................... ' ............. 1 2.0 SITE BACKGROUND ......................................................... 1 3.0 PROPOSED SITE ASSESSMENT ........................................... ' .....1 3.1 Borings .................. ~ ......................................... 1 3.2 Soil.Sampling ........................................................ 2 3.3 Laboratory Analysis .................................................... 2 3.4 Waste Disposal ....................................................... 2 4.0 REFERENCES .............................................................. 3 FIGURES Figure 1. Location Index Figure 2. Site Map APPENDICES Appendix A. Background Data Appendix B. Site Safety Plan Site Assessment Work Plan ARCO Products Company March 4, 1992 GROUNDWATER TECHNOLOGY I I 1.0 INTRODUCTION I I I I Groundwater Technology, Inc. has been contracted by ARCO Products Company to perform additional site assessment at facility no. 6218 in Bakersfield, California. The purpose of the assessment is to further define the lateral extent of hydrocarbons at the site. This workplan outlines site background, proposed assessment procedures, sampling protocol and worker safety considerations. 2.0 SITE BACKGROUND I I I I I I I I A preliminary assessment of soil conditions was completed at the site on February 22 and March 5, 1991 (GTI, 1991a). The assessment consisted of drilling four borings at the locations shown in Figure 2. Soil samples were collected and analyzed for benzene, toluene, ethylbenzene, and xylenes (BTEX) and total petroleum hydrocarbons as gasoline (TPHG). None of the samples exhibited detectable concentrations of any of the analytes. On May 15, 1991, Wegener Construction removed three underground storage tanks at the facility. No holes were found in any of the tanks, but rust was observed on all tanks (GTI, 1991b). A total of 26 soil samples'were collected from beneath former tanks, dispensers, and product lines. TPHG concentrations in the samples from beneath the tanks ranged from < 10 to 4,600 mg,/kg. TPHG concentrations in samples collected from beneath the dispenser islands ranged from 24 to 4,800 rog/kg. TPHG was not detected in samples collected from beneath the product lines (Appendix A). On September 11 and 12, 1991, Groundwater Technology completed six borings at the site (GTI, 1991c). TPHG Was not detected in samples from the bOrings near the dispenser islands. TPHG concentrations in samples collected from borings at the former tank location ranged from 40 to 2,700 mg/kg. However, TPHG was not detected in samples from these borings collected below a depth of 40 feet (Appendix A). 3.0 PROPOSED SITE ASSESSMENT I I I I 3.2 .Borings Groundwater Technology will drill three vertical borings at the locations shown in Figure 2. Each boring will be drilled to a minimum depth of 40 feet. If hydrocarbons persist below 40 feet, the borings will be Site Assessment Work Plan ARCO Products Company March 4, 1992 I I I I ! I I I I I I I I I I I I I deepened to 10 feet beyond contamination. No drilling fluids will be utilized during boring completion. The borings will be back-filled with sand-cement grout upon completion .of work. 3.2 Soil Sampling .. Soil samples will be collected from the borings at 5-foot intervals with a split-spoon Sampler. The sampler will be fitted with stainless steel or brass sample rings. The material from one sample ring will be described on the lithologic log of the boring and field screened with a photoionization detector (PID) for volatile organic comPound (VOC) emissions. A second ring will be sealed at each end with a teflon sheet and plastic cap. The caps will be secured with non:hydrocarbon tape and the sample will be preserved on ice. The sample from each boring which exhibits the highest VOC emissions, as indicated by the PID, as well as the deepest sample from each boring will be analyzed by a state-certified laboratory as described below. Between sampling events, the sampling equipment will be cleaned using a three-bUcket wash system., In this system, the rings and samplers are scrubbed in a bucket of detergent, rinsed in a second bucket of tap water and given a final rinse in a bucket of distilled water. 3.3 Laboratory Analysis Soil samples will be shipped via overnight courier to GTEL Environmental Laboratories in Torrance, California (Cert. No.' 723). All samples will be analyzed for TPHG and BTEX concentrations using EPA methods 8015 and 8020, respectively. Standard chain-of-custody procedures will be followed. 3.4 Waste Management Drill cuttings will be stored on site in appropriately labelled 55-gallon drums pending receipt of the analytical results. Once the analytical results are received the drum contents will be disposed of by ARCO in an appropriate and timely manner. If contamination is encountered the drilling augers will be steam-cleaned upon completion of drilling activities. Rinsate from the cleaning operations will be collected in appropriately labelled 55-gallon drums and disposed of by ARCO following laboratory analysis. Site Assessment Work.Plan ARCO Products Company March 4, 1992 C.OVNOw^vE. TECHNOLOGY I I 4.0 REFERENCES I I I I I I I I I i I I I I I I I GTI (Groundwater Technology, Inc.), 1991a, Predrill assessment report, ARCO service station #6218. -- 1991b, Tank removal report, ARCO service station #6218. -- 1991c, Site characterization report, ARCO service station no. 62'18. Site Assessment Work Plan ARCO Products Company March 4, 1992 GROUNDWATER TECHNOLOGY I I I I I I I I I' I I I I I I I I I I FIGURES GROUNDWATER TECHNOLOGY' I I I I I I I I I I I I I I I I I I I 4:.~¢1)'~~ I ., ~,~.,o ' ' O. ~ SCHO0~ ~ ~ -- ~ ...... 7.'~ .... ~ 0 = SU~SE ' ~:~ ,~ ~. ~ . - ,.~,0~0~ ~. ~ ~--~ ,,~,~ I I ~: ~rl;e' ~,~ m lalf~ ~ ~ ~ ~ n ~ o.. .Ia S ~ ~ q ., - -: ~ ~ ~ ~ . ~ c,, J ~,~ ~. ~ ~ ~ ~ ~ .... '" ~ / -- ~;, ~ ~ ~ o, B ~,,,,L~,,,-'~ .... dt~:~'~''-, ' ,~'" ~~ ~?~ ~~ ~T~I. ~ ~=~C'R~lli-~l~ . S : ~ , ;~ . : ~ ~ "~ ,,r s ..- = ~ -A,~ ~LANEO' '~ ~'~ ~z~ - ~ ~ ' '~', ~""~' ~ i~ 1' ~'. :: ~ ' ~.-' ~.-~ ~ ~ ', ~ ~ _. = ' _ ~ / ; .. ,,o ,~ ~S~fe N i~ SITE, ~ ARCO SS ~6218 550 0607 S~TCLOC, 4205 Ming Avenue Bakersfield, California NAP TYPE~ Locafion Index ~CALE: DRA~N DY, DATE~ APPROVED BY, ~ DATE, MH 2/9t JDPI 2/91 ~ REV REVISION DATE 9Y 1/8 0 1/4 1/B mites Source: Hoven & Co. Inc. I FIGURE 1 I ~GRaUNDV'TE"m~m TECMNDLDGY I I I I I I I I I I i I I I I I I I I APPENDIX A Background Data GROUNDWATER TECHNOLOGY I I I I I I ! i Table Al. Analytical results (in mg/kg) of soil samples collected beneath tanks, 5/15/91. Sample No. Benzene Toluene Ethyl- Total TPH as benzene Xylenes Gasoline T1W-2' 0.85 13 5.7 100 1600 TIW-6' 1.8 9.8 8.3 310 4600 TIE-2' <0.005 <0.005 <0.005 0.018 < 10 T1E-6' <0.005 <0.005 <0.005 <0.015 < 10 T2W-2' 24 230 71 460 3000 T2W:6' 4 87 33 300 2000 · T2E-2' < 0.005 < 0.005 < 0.005 0.029 < 10 T2E-6' < 0.005 0.055 0.062 5.7 55 T3W-2' <0.005 < 0.005 < 0.005 <0.015 < 10 T3W-6' < 0.005 < 0.005 < 0.005 0.16 < 10 T3E-2' < 0.005 0.021 0.0'06 0.062 < 10 T3E-6' <0.005 <0.005 < 0.005 <0.015 < 10 I I :1 I I I i I ~-][~][~ GROUNDWATER ~][--1[] TEC"NOLOC¥ I I Table A2. Analytical results (in mg/kg) of soil samples collected beneath dispenser islands and piping. 5/15/91. Sample No. Benzene Toluene Ethyl- Total TPH as benzene Xylenes Gasoline .. DI1-2' 0.11 5.1 3.3 37 280 DI 1-6' 0.009 0.14 0.084 1.7 24 DI2-2' <0.1 5.7 4.9 130 1900 DI2-6' < 0.005 0.42 0.61 17 430 DI3-2' 0.30 25 26 630 4800 DI3-6' < 0.005 0.15 0.34 11 170 DI4-2' <0.1 6.8 7.3 610 2900 DI4-6' <0.10 7.3 6.2 230 2500 PL1-2' < 0,005 < 0,005 < 0,005 < 0,015 < 10 PL1-6' <0.005 <0.005 <0.005 <0.015 < 10 PL2-2' <0.005 <0.005 <0.005 <0.015 < 10 PL2-6' < 0.005 - < 0.005 < 0,005 < 0.015 < 10 PL3-2' <0.005 <0.005 <0.005 <0.015 < 10 PL3-6' <0.005 0.005 <0.005 <0.015 < 10 il '! I i I I I I I I I I I I ! I I I Table A3. Analytical results (in mg/kg) of soil samples from borings, 9/11/91-9/12/91. Sample No. Benzene Toluene Ethyl- Xylenes TPHG benzene B5-35 < 0.005 < 0.005 < 0,005 < 0.015 < 10 B6-15 <0.005 <0.005 <0.005 <0.015 <10 B6-30 <0.005 <0,005 <0,005 <0,015 < 10 B7-25 <0,005 <0,005 < 0.005 <0,015 < 10 B8-20 < 0,005 < 0.005 < 0.005 '< 0.015 < 10 B9-25 0.53 4.1 8.6 150 2700 B9-40 3.2 12 1:4 8.2 40 B9-65 0.027 0.10 0,017 0.14 < 10 B10-45 0,089 0.56 0.11 0.77 < 10 B10-75 0.022 0.10 0,014 ' 0.11 < 10 B10-80 0.11 0.19 0.021 0,17 <10 I I I I I I I I :1 I '1 TECHNOLOGY I I I I I I I I I I I I I I I I I I I APPENDIX B Site Safety Plan I I I I I :1 I I ! I I I I I I ! I SITE SAFETY PLAN ARCO PRODUCTS COMPANY ARCO SERVICE STATION #6218 BAKERSFIELD, CALIFORNIA FEBRUARY 7, 1991 GROUNDWATER TECHNOLOGY, INC. 20000/200 MARINER AVENUE TORRANCE, CALIFORNIA 90503 PROJECT NUMBER: 215-350-0607 CdMpLETE~ MANAGER HEALT[-I~& S,~,FETY MAN~,GER ARC06218.S$P/~20 [[~L"~ GROUNDWATER [~--~ TECHNOLOCY, INC. I I .ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 I I TABLE OF CONTENTS I I I I I I ! I I I I I 1,0 SITE EMERGENCY ..................................................................... 1 1.1 Emergency Telephone Numbers ...................................................... 1 1.2 First Aid ........................................................................ 1 1.3 Emergency Environmental Contacts ................................................... 2 1.4 Encountering Hazardous Situations (requirinq evacuation) ................................... 2 2.0 INFORMATIONAL SUMMARY ............................................................. 2 2.1 Health and Safety Summary ......................................................... 2 3.0 INTRODUCTION ....................................................................... 5 3.1 Background ..................................................................... 6 3.2 Purpose ........................................................................ 6 3.30biective ....................................................................... 6 3.4 Amendments .................................................................... 6 4.0 HAZARD EVALUATION 4.1 4.2 4.3 4.4 Site Conditions .................................................................. 6 Site Tasks ...................................................................... 7 Spill and Disposal Procedures ....................................................... 7 Job Task Hazards ................................................................ 7 4.4.1 All Field Tasks ............................................................ 7 4.4.2 Well Installation; Well Development; Well Gauging; Well Bailing; Soil & Groundwater 4.4.3 4.4.4 4.4.5 Sampling ............................................................. 12 Sample Preservation ...................................................... 12 Cleaning Equipment ...................................................... 12 Confined Space .......................................................... 12 5.0 PERSONAL PROTECTIVE EQUIPMENT .................................................... 13 6,0 DECONTAMINATION PROCEDURES ...................................................... 14 7.0 CHEMICALS OF CONCERN ............................................................. 15 7.1 Health Effects .................................................................. 15 8.0 GAS/VAPOR MONITORING PROCEDURES ................................................. 16 8.1 Tasks Performed Within a Confined Space ............................................. 16 9.0 HEALTH AND SAFETY REQUIREMENTS ................................................... 18 9.1 Medical Monitorinq Proqram 9.2 9.3 9.4 9.5 9.6 ARGO6218.SSP/~20 Training ...................................................................... 18 Work Zones Access ............................................................. 19 Emergency Equipment ........................................................... 19 Carbon Treatment ............................................................... 19 Drillinq Procedures .............................................................. 21 1~]~;~ GROUNDWATER [---~-~ TECHNOLOCY, INC. I I I I I I I I I I I I I I I I .ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 9.7 Electrical Equipment and Ground-Fault Circuit Interrupters ................................. 21 9.8 Fire Prevention ................................................................. 23 9.9 General Health ................................................................. 23 9.10 MSDS Information .............................................................. 23 10.0 PROJECT PERSONNEL ................................................................ 23 10.1 Proiect Manaqer: ............................................................... 23 10.2 Health & Safety Manaqer ......................................................... 24 10.3 Site Safety Officer .............................................................. 25 10.4 Field Team Leader .............................................................. 25 10.5 Other Field Personnel ............................................................ 26 26 10.6 Medical/Technical. Advisors ....................................................... APPENDICES APPENDIX A: Agreement and Acknowledgement Statement APPENDIX B: Site Safety Plan Amendment Sheet APPENDIX C: Definition of Hazard Evaluation Guidelines APPENDIX D: Site Maps APPENDIX E: MSDS APPENDIX F: Accident/Injury Form APPENDIX G: Vapor Monitoring Worksheet APPENDIX H: Excavation/Trenching APPENDIX I: OSHA Inspection Steps [~][---[[] GROUNDWATER ~]l--~-I TEC~-INOLOC¥, INC. I I I I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~/ Plan February 7, 1991 1.0 SITE EMERG!: .~,!; Survey the situation. Do not endanger your' own life. Your site address: Ming Ave. and Stine Rd. Bakersfield, CA 1.1 Emerqenc¥ Telephone Numbers Telephone located at: On Site Ambulance: (911) Fire: (911) Police: (911) Poison Control: 1-800-346-5922 Nearest Hospital: Street Address: Telephone: Directions to: Mercy Flospital 2215 Truxton (805) 32'.8-5275 East on Ming, north on V* to Hospital. 1.2 First Aid: Inqestion: Give water if patient is conscious. Call Poiso necessary. Seek medical attention. Inhalation: Remove person from contaminated evironme attention. Skin Contact: Brush off dry material, remove contaminated attention if irritation develop:s. Eye Contact: Flush eyes and surrounding tissue with water * Exposure Symptoms: Headache, dizziness, nausea, drow difficulties. Report incident to Project Manager and Regional Health an( implemented. ARC06218.SSP/# 20 I I I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 1.3 Emerqency Environmental Contacts Groundwater Technology, Inc.: Contact Person: Jon Parker Home: 805-833-8984 Alternates: Maura Hanning Home: 805-871-5312 Maureen Grant Home: 1-213-379-3055 National Response Center: U.S, EPA (24-hour Hotline): State Regulatory Agency: Kern County Dept. of Env. Health Svs. Client: ARCO Products Co. Contact Person: Kateri Luka TELEPHONE: 1-805-589-8601 1-805-589-8601 1-213-371-1394, X337 t-800-424-8802 1-800-424-9346 1-805-861-3636 1-213-707-5360 1.4 Encounterinq Hazardous Situations (requiring evacuation) In the event of an emergency, i.e. fires, explosions or any unplanned sudden or non-sudden release of hazardous waste or hazardous waste constituents to air, soil or surface water at the facility, the team member that observes this condition shall give an emergency alarm. The emergency alarm signal will be 3 horn blasts on the horn located in the site vehicle. Actions to be taken will be dictated by the emergency. All appropriate local emergency response agencies shall be notified immediately: The police, fire department, emergency response teams and ambulance may be reached via telephone by dialing 911. The nearest hospital and additional emergency contacts are listed on the previous page (Section 1.0). Personnel encountering a hazardous situation shall instruct others on site to evacuate the vicinity immediately and call the (I) Site Safety Officer, (2) the Project Manager, and (3) the Health & Safety Manager for instructions. The site must not be re-entered until back-up help, monitoring equipment, and personal protective equipment is on hand. 2.0 INFORMATIONAL SUMMARY 2.1 Health and Safety Summary Chemicals of Concern: Gasoline, Benzene, Toluene, Ethylbenzene, & Xylene Hazard Determination: Serious_ Moderate_ Low~X Minimum Level of Protection: Modified Level D is the minimum acceptable level for this site. Action Level for Upgrading Personal Protection: Upgrade from Level D to Level C at 100 ppm measured within the breathing zone. This should be determined by a photoionization detector (PID) with a 10.2 lamp or a flame ionization detector (FID). ARco~,s.sSP/,~o 2 ~~ TECHNO~GY, INC. :1 I '1 ARCO PRODUCTS COMPANY- SS #6218 Site Safe~ Plan February 7, 1991 I I I I I I I I Air Monitoring Requirements: PID ~ OVA __ FiE) __ O2/LEL __ DETECTOR TUBES _ OTHER __ TABLE I ACTION LEVELS NOTE: The information in this chart applies to gasoline and its chemical constituents. GASOLINE PEL* = 300 PPM GTI ACTION LEVEL = 100 PPM ACTION LEVELS FOR PPE AIR MONITORING INSTRUMENT LEVEL D LEVEL C LEVEL B LEL <1% 1% - 5% >5% PID/FID <100 ppm 100 -750 ppm >750 ppm 02 19.5 - 23% 19.5 - 23% <19.5% I I I I I I Explanatory Information: LEL Gasoline = 1.4 % or 14,000 ppm 1% LEL = 140 ppm (Wear Level C) 5% LEL = 700 ppm (Wear Level C) >5% LEL = Level B (>700 ppm) NOTE: Withdraw from site and contact the proiect manager if: LEL > 20%, and/or O2 > 23% * PEL = Permissible Exposure Limit (OSHA 1989) ARCO6218.SSP/~20 3 GROUNDWATER TECHNOLOCY, INC. I I I I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 3.0 INTRODUCTION 3.1 Back.qround ARCO Products Co. has retained Groundwater Technology, Inc. (GTI) to perform a site assessment/investigation at their facility located at Ming Ave. and Stine Rd. in Bakersfield, California. 3.2 Purpose The purpose of the site safety plan is to provide Groundwater Technology field personnel and subcontractors with an understanding of the potential chemical and physical hazards that exist or may arise while the tasks of this project are being performed. This SSP describes the procedures to be followed in order to reduce employee exposure to potential health hazards which may be present at the project site. The emergency response procedures necessary to respond to such hazards are also described within this SSP. 3.3 Objective The primary objective is to ensure the well-being of all field personnel and the community surrounding this site. In order to accomplish this, project staff and approved subcontractors shall acknowledge and adhere to the policies and procedures established herein. Accordingly, all personnel assigned to this project shall read this site safety plan and sign the Agreement and Acknowledgement Statement (Appendix A) to certify that they have read, understood and agreed to abide by its provisions. GTI personnel have the authority to stop work performed by our sub- contractors at this site if any work is not performed in accordance with the requirements of this Site Safety Plan. 3.4 Amendments Any changes in the scope of work of this project and/or site conditions must be amended in writing on the Site Safety Plan Amendment Sheet (Appendix B) and approved by Health & Safety Manager. 4.0 HAZARD EVALUATION 4.1 Site Conditions General Site conditions at the ARCO #6218 site include predrill assessment prior to tank removal to check for hydrocarbon-bearing soils near old tank and new tank locations. ARCO6218.SSP/,~20 ~-~[][] GROUNDWATER I~[~--] TECHNOLOGY, INC. I :1 I I I I I I I I ii ARCO PRODUCTS COMPANY- SS #6218 Site Safell/ Plan February 7, 1991 4.2 .SEe Tasks. The field tasks at this site may include: · Soil boring samples · Monitoring well installation · Monitoring well survey · Monitoring well gauging · Monitoring well development · Product bailing · Groundwater and soil sampling · Excavation/trenching · Equipment installation · Operation and maintenance 4.3 Spill and Disposal Procedures Contain spills with an absorbent material (sand, sawdust, dirt, clay). Report spills to client and follow their recommended procedures. If spills occur in transit, report them to the appropriate authorities. 4.4 Job Task Hazards 4.4.1 All Field Tasks: The following hazards may be encountered. · Slippery Surfaces: All employees must wear ANSI approved work boots with steel toe protection. Skid proof soles are highly recommended. I I I I Organic Vapors: The inhalation of volatile organic vapors during all operations can pose a potential health hazard. Hazard reduction procedures include monitoring the ambient air with a PID and/or FID and use of Personal Protective Equipment indicated on Table II. Workers should stand upwind of the source of contamination whenever possible. If ambient air levels in the breathing zone exceed 100 ppm, full face respirators equipped with organic vapor cartridges must be worn. Flammable Vapors: Presence of flammable vapors can pose a potential fire hazard and health hazard. Hazard reduction procedures include monitoring the ambient air with an 02/LEL meter. If the LEL reading exceeds 20%, leave the site immediately and contact the fire department. I I I I · Oxygen: Atmospheres that contain a level of oxygen greater than 23% pose an extreme fire hazard (the usual ambient oxygen level is approximately 20.5%). All personnel encountering atmospheres that contain a level of Oxygen greater than 23% must evacuate the site immediately and must notify the Fire Department. If Oxygen Level is less than 19.5%, do not enter the space. ARCO6218.S~P/~20 [~[~L'~---I GROUNDWATER .[~[~J---][ TECHNOLOGY, INC. I 'i I I '1 I I I .I I I I I '1 I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 Noise: GTI and ANSI approved hearing protection must be worn during noisy operations such as drilling. Surface and Equipment Contamination: Contact with contaminated surfaces, or surfaces suspected of being contaminated should be avoided. This includes walking through, kneeling or placing equipment in puddles, mud, discolored surfaces, or on drums and other containers. Eating, smoking, drinking and/or the application of cosmetics is prohibited on this site in the immediate work area. This reduces the likelihood of contamination by ingestion. Exposure - Heat Stress: Since climatic changes cannot be avoided work schedules will be adjusted to provide time intervals for intake of juices, juice products and water in an area free from contamination and in quantity appropriate for fluid replacement. Heat stress may occur even in moderate temperature areas and may present any or all of the following: A. Heat Rash: result of continuous exposure to heat, humid air, and chafing clothes. Heat rash is uncomfortable and decreases the ability to tolerate heat. B. Heat Cramps: result of the inadequate replacement of body electrolytes lost through perspiration. Signs include severe spasms and pain in the extremities and abdomen. Heat Exhaustion: result of increase stress on the vital organs of the body in the effort to meet the body's cooling demands. Signs include shallow breathing; pale, cool, moist skin; profuse sweating; dizziness. Do Heat Stroke: result of overworked cooling system. Heat stroke is the most serious form of heat stress. Body surfaces must be cooled and medical help must be obtained immediately to prevent severe injury and/or death. Signs include red, hot, dry skin; absence of perspiration; nausea; dizziness and confusion; strong, rapid pulse. Can lead to coma and death. Heat Stress Prevention A. Replace body fluids (water and electrolytes) lost through perspiration. Solutions may include a 0.1% salt and water solution or commercial mixes such as Gatorade and Squench. Cooling devices to aid the natural body ventilation. Cooling occurs through evaporation of perspiration and limited body contact with heat-absorbing protective clothing. Utilize fans and air conditioners to assist in evaporation. Long, cotton underwear is suggested to absorb perspiration and limit any contact with heat-absorbing protective clothing (i.e., coated Tyvek suits). C. Provide hose-down mobile shower facilities to cool protective clothing and reduce body temperature. D. Conduct non-emergency response activities in the early morning or evening during very hot weather. GROUNDWATER AF~:O~,,.SSP/,~O 6 --][~[~J TECEINOI.OC¥, INC. I I I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~/ Plan February 7, 1991 E. Provide shelter against heat and direct sunlight to protect personnel. F. Rotate workers wearing protective clothing during hot weather. Exposure - Cold Stress: Work schedules will be adjusted to provide sufficient rest periods in a heated area for warming up during operations conducted in cold weather. Also thermal protective clothing such as wind and/or moisture resistant outerwear is recommended to be worn. If work is performed continuously in the cold at or below -7°C (20° F), including wind chill temperature, heated warming shelters (tents, cabins, company vehicles, rest rooms, etc.) shall be made available nearby and the worker should be encouraged to use these shelters at regular intervals the frequency depending on the severity of the environmental exposure. The onset of heavy shivering, frostnip, the feeling of excessive fatigue, drowsiness, irritability, or euphoria, are indications for immediate return to the shelter. When entering the heated shelter the outer layer of clothing shall be removed and the remainder of the clothing loosened to permit sweat evaporation. A change of dry work clothing shall be provided as necessary to prevent worker from returning to their work with wet clothing. Dehydration, or the loss of body fluids, occurs in the cold environment and may increase the susceptibility of the worker to cold injury due to a significant change in blood flow to the extremities. Warm sweet drinks and soups should be provided at the work site to provide caloric intake and fluid volume. The intake of coffee should be limited. (Adapted from TLV's and Biological Exposure Indices 1988-1989; ACGIH). Falling Objects: Hard hats must be worn by all personnel whenever construction-type activity is taking place. (ie., drilling, excavation, trenching). Vehicular traffic: All employees will be required to wear a fluorescent safety vest at all times while on site. In addition, the following safety equipment procedures must be adhered to. TASK Drilling A Subsurface Entry A Well Installation A Well Maintenance B Well Gauging B Sampling B Pump Test B TRAFFIC SAFETY EQUIPMENT SAFETY EQUIPMENT KEY: A = Cones and barricades required - tapes and flags are recommended but optional. B = Cones are required - flags are recommended but are optional. ARCO6~18.SSP/#20 7 [--][]~] CROUNDWATER [--][]{---] TECHNOLOGY, INC. I I I I I I I I i I I I I I i I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~y Plan February 7, 1991 4.4.2 Well Installation; Well Development; Well Gauging; Well Bailing; Soil & Groundwater Sampling: Skin and eye contact with contaminated groundwater and/or soil may occur during these tasks. Nitrile butyl rubber or neoprene gloves and approved safety goggles should be worn when contact with contaminated substance and/or splash is possible. 4.4.3 Sample Preservation: When hydrochloric acid is used, skin and eye contact can occur. This hazard can be reduced with the use of Nitrile butyl rubber or neoprene gloves and the use of safety goggles. 4.4.4 Cleaning Equipment: Skin and eye contact with methanol, Alconox, or other cleaning substances can occur while cleaning equipment. This hazard can be reduced with the use of Nitrile butyl rubber or neoprene gloves and the use of safety goggles. 4.4.5 Confined Space: Manholes, subsurface vaults and sheds are examples of confined spaces that may lack adequate ventilation. Organic and/or combustible vapors may be trapped resulting in a lack of oxygen (anoxia) and/or overexposure to vapors. When site work takes place in a confined space the air must be monitored for (a) oxygen level, (b) flammable vapors, and (c) toxic vapors. The following air monitoring procedures must be followed before entering a confined space. ao Ox'yqen Level: Monitor for % Oxygen with an 02/LEL meter to ensure a minimum oxygen level of 19.5%. Oxygen level monitoring will be done at the top, middle and bottom of the enclosed space to determine if there is a minimum acceptable oxygen level of 19.5% PRIOR to entry. If ox¥.qen is less than 19.5%, do not enter the space. b. Explosive Vapors: Monitor for % of Lower Explosive Limit (LEL) with a 02/LEL meter to determine whether vapor concentrations within the confined space are within the flammable range. If LEL readings exceed 20%, personnel MUST leave the site immediately, and contact the project manager. c. Toxic Vapors: Monitor for toxic vapors with a PID and/or an FID (e.g., HNU or OVA) to determine whether toxic vapors within the confined space exceed the action levels. If the PID and/or the FID readings exceed 100 ppm, a full face respirator must be worn. All monitoring equipment must be calibrated and maintained in accordance with manufacturer's recommendations. If an HNU is used, the 10.2 eV lamp is required for accurate readings. ARCO6218.SSP/~20 []~--]~ GROUNDWATER [][~- TECHNOt.OC¥, INC. I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~y Plan February 7, 1991 d. Summary: Do not enter the confined space unless: · the oxygen concentration is between 19.5 and 23%; · the LEL is less than 20%; · PID and/or FID readings are less than 750 ppm (a full face respirator must be worn if the readings exceed 100 ppm) eo ~: The buddy system must be used when the work in the confined space: (1) requires the person's head to be below ground level; or (2) the person must work in a manhole or other space in which an exit may not be easily accessible, TABLE II HAZARD SUMMARY AIR MONITORING - BREATHING ZONE JOB TASK PPE LEVEL iNSTRUMENT I FREQUENCY* Soil Boring Samples D PID or FID At start of work and 15 min. to continuously Monitoring Well Installation D PID or FID At start of work and 15 min. to continuously Monitoring Well Survey D PID or FID Start-up of work at each well location Monitoring Well Development D PID or FiD Start-up of work at each well location Groundwater and Soil Sampling D PID or FID Start-up of work at each well location. I I I I I I I I * All air monitoring data must be recorded on the Vapor Monitoring Sheet, Appendix G. 5.0 PERSONAL PROTECTIVE EQUIPMENT Modified Level D is the minimum acceptable level for this site. Modified Level D includes: coveralls/work uniform steel toe and shank boots Nitrile butyl rubber or neoprene gloves (optional) splash goggles/safety glasses if potential for splash hard hat fluorescent vest Tyvek suit (optional) hearing protection (as appropriate) ARCO6218,SSP/~20 C.OVNDW^TE" []i--~[~ TECHNOLOCY, INC. ARCO PRODUCTS COMPANY- SS #6218 Site Safe~y Plan February 7, 1991 ,I ,! Level C includes: · full face respirator NIOSH approved with organic vapor cartridges · Tyvek suits (if splash hazard is possible, a coated suit must be worn) Nitrile butyl rubber or neoprene gloves steel toe and shank boots outer boots - chemical resistant · inner disposable gloves (2 pairs recommended) hard hat fluorescent vest hearing protection (as appropriate) Level B includes: · air supplied respirator coated Tyvek suit, such as Saranex Nitrile butyl rubber or neoprene gloves · inner latex or vinyl gloves steel toe and shank boots outer boots - chemical resistant hard hat fluorescent vest hearing protection (as appropriate) 6.0 DECONTAMINATION PROCEDURES All operations conducted at this site have the potential to contaminate monitoring equipment and personal protective equipment (PPE). To prevent the transfer of contamination to vehicles, administrative areas and personnel, the following procedures must be followed: Equipment Decontamination 1. Whenever possible, monitoring equipment should be decontaminated with a solution of Alconox and thoroughly rinsed with water prior to leaving the site. This must be done outside a 5-foot radius of any work area. Personal Decontamination LEVEL D · segregated equipment drop · wash/rinse outer boot (as appropriate) · wash/rinse chemical resistant outer glove, then remove (as appropriate) · remove hard hat, goggles/safety glasses/faceshield · remove and throw out inner disposable gloves in designated lined receptacles (as appropriate) I I ARCO6218.SSP/e 20 10 ~-][--][~ GROUNDWATER [--~[]F-~ TECHNOLOGY, INC. I I I I I I I I ARCO pRODUCTS COMPANY- SS #6218 Site Safely Plan February 7, 1991 LEVEL C segregated equipment drop wash/rinse outer boots wash/rinse chemical resistant outer gloves, then remove remove outer boots and place to dry (if reusable) remove chemical resistant suit (remove by rolling down the suit) remove first pair(s) of disposable gloves remove respirator/hard hat/faceshield dispose of cartridges and wash respirator remove last pair of disposable gloves LEVEL B segregated equipment drop wash/rinse outer boots wash/rinse chemical resistant outer gloves, then remove cross hotline (into clean area) and change air tanks, then redress or cross hotline (into clean area) remove boots and gloves remove SCBA, if worn over chemical resistant suit if SCBA is worn under the suit, remove the chemical resistant suit, then the SCBA remove hard hat 7.0 CHEMICALS OF CONCERN 7.1 Health Effects Potential health effects from a chemical exposure are dependant on several exposure factors such as: toxicity of substances, duration of exposure, concentration during exposure and the overall health of the person exposed. The chemicals commonly at this site are: Gasoline, Benzene, Toluene, Ethylbenzene, and Xylene. The following is a health analysis of these chemicals. Additional information on these chemicals can be found in the Material Safety Data Sheet located in Appendix E. Gasoline constituents can be divided into five major groups: alkanes, alkenes, cycloalkanes, aromatics and additives. The aromatics are the constituents generally regarded to be of greatest toxic concern. The major aromatics in gasoline are benzene, toluene, ethyl benzene and xylene. Of these, benzene is considered to be the most toxic. One characteristic effect of gasoline and its aromatic constituents is their ability to irritate the skin when repeated or prolonged exposure occurs. Benzene Benzene can enter the body through inhalation, ingestion and skin contact. Studies have noted that chronic exposure to benzene vapor can produce neurotoxic and hematopoietic (blood system) effects. Other effects can include headache, dizziness, nausea, convulsions, coma and possible death if exposure is not reversed. One significant effect from chronic benzene exposure is bone marrow toxicity. There is also an association between chronic exposures to benzene and the development of certain types of leukemia. ARCO6218.SSP/~20 11 [--~[][] TECHNOLOCY, INC. ! I I I I I I I I I I i I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~ Plan FebruarY 7, 1991 Toluene Inhalation exposure to toluene vapor can produce effects such as central nervous system depression. Depending on exposure factors signs and symptoms can include headache, dizziness, fatigue, muscular weakness, incoordination, drowsiness, collapse and possible coma. Toluene can be a skin and mucous membrane irritant and studies have shown that high levels of toluene exposure can cause liver and kidney damage. Eth¥1benzene Exposure to ethyl benzene at high vapor concentrations may produce irritation to the skin, eyes and upper respiratory tract. Overexposure to ethyl benzene vapors can produce central nervous system depression with symptoms of headache, nausea, dizziness, shortness of breath and unsteadiness. Prolonged skin exposure to ethyl benzene may result in drying and cracking of the skin (dermatitis). Solvent resistant gloves should be worn during sampling to prevent exposure to the skin. Xylenes Depending on exposure factors, inhalation exposure to xylene vapor may produce central nervous system excitation followed by depression. Exposure to xylene vapor can produce dizziness, staggering, drowsiness and unconsciousness. At very high concentrations, xylene vapor may produce lung irritation, nausea, vomiting and abdominal pain. Xylene is not known to possess the chronic bone marrow toxicity of benzene, but liver enlargement and nerve-cell damage have been noted from chronic overexposure. 8.0 GAS/VAPOR MONITORING PROCEDURES The greatest potential hazards to safety and health at this site are: 1. Exposure to chemical vapors - through inhalation 2. Exposure to chemical contamination - through skin contact and ingestion. Ongoing air monitoring during project tasks will provide data to ensure that vapor concentrations are within acceptable ranges and will provide adequate selection criteria for respiratory and dermal protection. 8.0.1 If PID readings exceed 100 ppm, a NIOSH approved air-purifying respirator with organic vapor cartridges must be worn by all site workers within any area where monitoring results exceed 100 ppm. 8.0.2 If PID readings exceed 750 ppm, level B protection will be required. Personnel must leave site immediately and contact site safety officer or Health & Safety Manager for further instructions. 8.0.3 Respirator cartridges will be changed once per day as a minimum. This can be accomplished at the end of the work day during respirator decontamination. If odor breakthrough is detected while Wearing the respirator or breathing becomes difficult, change cartridges immediately. 8.1 Tasks Performed Within a Confined Space When site work takes place in a confined space the air must be monitored for (a) oxygen level; (b) explosive vapors; and (c) toxic vapors. The following air monitoring procedures must be followed before entering a confined space. ARCO6218.SSP/e20 12 C.OUNDW^TE" --t[]l--]j TECHNOLOGY, INC. ! I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~ Plan February 7, 1991 Oxyqen Level: Monitor for % Oxygen with a O2/LEL Meter to ensure a minimum oxygen level of 19.5%. Oxygen level monitoring will be done at the top, middle and bottom of the enclosed space to determine if there is a minimum acceptable oxygen level of 19.5% prior to entry. If oxyqen is less than 19,5%, do not enter the space, Explosive Vapors: Monitor for % of Lower Explosive Limit (LEL) with a 02/LEL Meter to determine whether vapor concentrations within the confined space exceed 20% of the LEL. If readings exceed 20% LEL, personnel shall shut off accessible equipment, leave the site immediately, and contact the fire department. Toxic Vapors: Monitor the air within the confined space for organic vapors with a PiD or FID following guidelines stated in Section 8.0 (above) to decide on the respiratory protection needed. Enter the space only if the oxygen level is at or above 19.5%, the %LEL is below 20%, the toxic vapor concentration is determined, and the proper respiratory protection is worn. PID or FID readings will be taken at the top, middle and bottom of a vault, shed, or other confined space to ensure that vapors do not exceed acceptable levels. All monitoring equipment must be calibrated and maintained in accordance with manufacturer's recommendations. 9.0 HEALTH AND SAFETY REQUIREMENTS 9.1 Medical Monitorinq Proqram All Groundwater Technology, Inc. field personnel are required to have annual medical evaluations in accordance with the company's Health and Safety Program policy. Additional re-evaluation will be considered in the event of chemical over-exposure while working on this site. The petrochemicals typical of these facilities can affect specific organ systems producing characteristic health effects. The medical evaluation will, therefore, focus on the liver, kidney, nervous system, blood systems, and skin and lung function. Laboratory testing will include complete blood count, and applicable kidney and liver-function tests. Other tests include skin examination. 9.2 Traininq All personnel working at this site should have received a minimum of 40 hours of initial hazardous waste activity instruction, and a minimum of three days of field experience under the direct supervision of a trained, experienced person. Personnel assigned to the site will also receive eight hours refresher training per year. On-site managers and supervisors directly responsible for employees engaged in hazardous waste operations have received an additional eight hours of supervisory training. These training requirements comply with the OSHA Hazardous Waste Operations and Emergency Response regulation, 29 CFR 1910.120. ARCO~8.S,~/,~O 13 [~[~[~-~ GROUNDWATER [~-~[~ TECHNOLOGY, INC. I I I I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 The initial 40-hour training and the 8-hour annual refresher training includes specific details on the following: Regulatory Requirements First Aid/CPR Confined Space Entry Respiratory Protection · Air Monitoring · Decontamination Procedures Hazard Communication Toxicology These specifications are then complimented with actual hands-on experience with the use of personal protective equipment and air monitoring equipment. 9.3 Work Zones Access Access within a 5-foot radius of any on-site operation is prohibited to all but Groundwater Technology, Inc. field personnel and subcontractors. 9.4 Emerqenc¥ Equipment Vehicles used for site work will be equipped with a first aid kit and safety equipment including: fluorescent vests, cones, flags (as needed) barricades (as needed) fire extinguisher-dry chemical ABC-type extinguisher, flashlight, water, suitable for drinking, portable eye wash, appropriate emergency bandage material. 9.5 Carbon Treatment If this site involves the use of a Carbon Treatment System, then the following information will apply. The Carbon Treatment System is equipped with an emergency shut-off. The system will shut off automatically when the non-methane TPH vapor concentrations in the intermediate line reach 5% of the Lower Explosive Limit (LEL) for gasoline as recorded by the system monitors. The suggested equipment for decontamination and spill response procedures includes: wash tubs (3) plastic sheets trash bags scrub brushes detergent sorbent booms (as applicable) The carbon system is a closed system where no chemicals are used. The potential for a spill is minimal and thus spill containment is not addressed in this Site Safety Plan. r--][~[~ GROUNDWATER ARco~,s.ssP/,~o 14 [-~J[~ TECHNOLOGY, INC. I I I ! ,I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 I I 9.6 Drillinq Procedures A Dig-Alert authorization number must be obtained prior to drilling. During the drilling operation, two persons (one designated as "driller" and the other as "helper") must be present at all times. The helper (whether Groundwater Technology, Inc. personnel or subcontractors) must be instructed as to the location of the emergency shut-off switch. Every attempt must be made to keep unauthorized personnel from entering the work area. If this is not possible, the operation should be shut down until the area is cleared. The area where the operation is taking place shall be cordoned off with a barricade. The Site Safety Officer or the Field Team Leader has the authority and the responsibility to shut down the drilling operations whenever a hazardous situation is deemed present. The mast of the drilling rig must maintain a minimum clearance of 20 feet from any overhead electrical cables. All drilling operations will cease immediately during hazardous weather conditions such as high winds, heavy rain, lightening and snow. I I Hart hats shall be worn at all times. Hearing protection shall be worn during noisy operations. If product is encountered during the drilling operation, all work must stop in order for employees to upgrade personal protective equipment to Level C. A full-face respirator should be worn in order to prevent the inhalation of vapors and to provide face and eye protection from splashes. Coated tyvek suits, gloves, and overboots should be worn to prevent skin contact with the soil. Air monitoring must be performed in the work area to document breathing-zone concentrations. If air monitoring results indicate concentrations greater than 700 ppm, then Level B respiratory protection will be implemented. I I Respirator cartridges must be changed at the end of a work period or if "breakthrough" occurs. If employees experience continuous cartridge "breakthrough", then the employees' work procedures and the level of respiratory protection must be re-evaluated by the Site Safety Officer and the Health and Safety Manager in order to determine the necessity of upgrading to Level B respiratory protection. 9.7 Electrical Equipment and Ground-Fault Circuit Interrupters All electrical equipment and power cables in and around wells or structures suspected of containing chemical contamination must be intrinsically safe and equipped with a throe-wire ground lead, rated explosion-proof for hazardous atmospheres. In accordance with OSHA 29 CFR 1926.404, approved ground fault circuit interrupters (GFCI) must be used for all 120 volt, single phase, 15 and 20 ampere receptacle outlets on the site which are in use by employees. Receptacles on the ends of extension cords are not part of the permanent wiring and therefore, must be protected by GFCI's whether or not the extension cord is plugged into permanent wiring. I I The GFCI is a fast-acting circuit breaker which senses small imbalances in the circuit caused by current leakage to ground, and in a fraction of a second shuts off the electricity. However, the GFCI will not protect the employee from line-to-line contact hazards (such as a person holding two "hot" wires or a hot and neutral wire in each hand). The GFCI does provide protection against the most common form of electrical shock hazard - the ground fault. It also provides protection against fires, overheating, and destruction of insulation on wiring. I I I GFCIs can be used successfully to reduce electrical hazards on construction sites. Tripping of GFCIs - interruption of current flow -is sometimes caused by wet connectors and tools. It is good practice to limit exposure of connectors and tools to excessive moisture by using watertight or sealable connectors. Providing more GFCls or shorter circuits can prevent tripping caused by the cumulative leakage from several tools or by leakages from extremely long circuits. (Adapted from OSHA 3007; Ground-Fault Protection on Construction sites, 1987.) [--][--~[~ GROUNDWATER ^,co~,8.ssP/~o 15 I--]~--~--~ TECHNOLOGY, INC. I I i I I I I I I I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 9.8 Fire Prevention During equipment operation, periodic vapor concentration measurements should be taken with an explosimeter or combustimeter. If at any time the vapor concentrations exceed 20% of LEL, then the Site Safety Officer or designated field worker should immediately shut down all operations. Only Factory Mutual (FM) approved fire safety cans will be used to transport and store flammable liquids. All gasoline and diesel-driven engines requiring refueling must be shut down and allowed to cool before filling. Smoking is not allowed during any operations within the work area in which petroleum products or solvents in free-floating, dissolved or vapor forms, or other flammable liquids may be present. No open flame or spark is allowed in any area containing petroleum products, or other flammable liquids. 9.9 General Health Medicine and alcohol can increase the effects of exposure to toxic chemicals. Unless specifically approved by a qualified physician, prescription drugs should not be taken by personnel assigned to operations where the potential for absorption, inhalation, or ingestion of toxic substances exists. Drinking alcoholic beverages is prohibited. Drinking alcoholic beverages and driving is prohibited at any time. Driving at excessive speeds is always prohibited. Skin abrasions must be thoroughly protected to prevent chemicals from penetrating the abrasion. It is recommended that Contact Lenses not be worn by persons working on the site. 9.10 MSDS Information Material Safety Data Sheets (MSDS) on chemical substances encountered at the site shall be made available to all persons (including subcontractors) working at the site. These MSDSs shall be enclosed within this site safety plan in Appendix E. For emergency situations not specifically addressed by this site safety plan, refer to MSDS recommendations for action information. 10.0 PROJECT PERSONNEL Groundwater Technology, Inc. will oversee and act accordingly during all phases of the project. The following management structure will be instituted for the purpose of successfully and safely completing this project. 10.1 Proiect Manaqer: Jon Parker The Project Manager will be responsible for implementing the project and obtaining any necessary personnel or resources for the completion of the project. Specific duties will include: coordinating the activities of all subcontractors, to include informing them of the required personal protective equipment and insuring their signature acknowledging this Site Safety Plan (see Appendix A), } selecting a Site Safety Officer and field personnel for the work to be undertaken on site, e ensuring that the tasks assigned are being completed as planned and on schedule, !C~C~[~ GROUNDWATER ^~z~,,.ssP/,~o ~s [~]C~C~] TECHNOLOCY, INC. I I ! I I I I I I I I I I I I i I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 providing authority and resources to ensure that the Site Safety Officer is able to implement and manage safety procedures, preparing reports and recommendations about the project to clients and affected Groundwater Technology, Inc. personnel, ensuring that persons allowed to enter the site (i.e., EPA, contractors, state officials, visitors) are made aware of the potential hazards associated with the substances known or suspected to be on site, and are knowledgeable as to the on-site copy of the specific site safety plan. ensuring that the Site Safety Officer is aware of all of the provisions of this site safety plan and is instructing all personnel on site about the safety practices and emergency procedures defined in the plan, and ensuring that the Site Safety Officer is making an effort to monitor site safety, and has designated a Field Team Leader to assist with the responsibility when necessary. 10.2 Health & Safety Manager Maureen Grant The Health & Safety Manager shall be responsible for the overall coordination and oversight of the site safety plan. Specific duties will include: approving the selection of the types of personal protective equipment (PPE) to be used on site for specific tasks, monitoring the compliance activities and the documentation processes undertaken by the Site Safety Officer, evaluating weather and chemical hazard information and making recommendations to the Project Manager about any modifications to work plans or personal protection levels in order to maintain personnel safety, coordinate upgrading or downgrading PPE with Site Safety Officer, as necessary, due to changes in exposure levels, monitoring results, weather, other site conditions, approving all field personnel working on site, taking into consideration their level of safety training, their physical capacity, and their eligibility to wear the protective equipment necessary for their assigned tasks (i.e.: Respirator Fit Testing Results), and, overseeing the air monitoring procedures as they are carried out by site personnel for compliance with all company health and safety policies. ARC~18.SSP/#~O 17 CJROUNDW^T..R [~[~[~ TECHNOLOO¥, INC. I I I I I I I I I I I I I. I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safety Plan February 7, 1991 10.3 Site Safety Officer Jon Parker The Site Safety Officer shall be responsible for the implementation of the site safety plan on site. will include: 10.4 Specific duties monitoring the compliance of field personnel for the routine and proper use of the PPE that has been designated for each task, routinely inspecting PPE and clothing to ensure that it is in good condition and is being stored and maintained properly, stopping work on the site or changing work assignments or procedures if any operation threatens the health and safety of workers or the public, monitoring personnel who enter and exit the site and all controlled access points, reporting any signs of fatigue, work-related stress, or chemical exposures to the Project Manager and/or Health & Safety Manager, dismissing field personnel from the site if their actions or negligence endangers themselves, co-workers, or the public, and reporting the same to the Project Manager and/or Health & Safety Manager, reporting any accidents or violations of the site safety plan to the Project Manager and/or Health & Safety Manager, and documenting the same for the project in the project records, knowing emergency proced'ures, evacuation routes and the telephone numbers of the ambulance, local hospital, poison control center, fire and police departments, · ensuring that all project-related personnel have signed the personnel agreement and acknowledgments form contained in this site safety plan, · coordinate upgrading and downgrading PPE with the Health & Safety Manager, as necessary, due to changes in exposure levels, monitoring results, weather, and other site conditions, and · perform air monitoring with approved instruments in accordance with requirements stated in this Site Safety Plan (see monitoring procedures on page 20 for specific information). Field Team Leader Maura Hanninq In the event that the Project Manager and the Site Safety Officer are not on site, the Field Team Leader will assume all responsibility of the Site Safety Officer. AROO6218.SSP/e20 1 8 F--I[][] GROUNDWATER r--iF-~l--I TECHNOLOGY, INC. i I i I I I I I I I I I I ARCO PRODUCTS COMPANY- SS #6218 Site Safe~y P/an February 7, 1991 10.5 Other Field Personnel Technician staff is responsible for system maintenance, calibration and system operation. Records of site visits documenting system conditions are maintained by the technicians. All field personnel shall be responsible for acting in compliance with all safety procedures outlined in the site safety plan. Any hazardous work situations or procedures should be reported to the Site Safety Officer so that corrective steps can be taken. 10.6 Medical/Technical Advisors Frank H. Lawrence, M.D. ENVIROLOGIC DATA, Portland, Maine ................(207) 773-3020 Marilyn E. Grant, R.N., B.S., C.O.H.N ENVIROLOGIC DATA, Portland, Maine ................(207) 773-3020 Lori St. Pierre, I.H.I.T. ENVIROLOGIC DATA, Portland, Maine ................(207) 773-3020 The specific duties of the Medical/Technical Advisors include: providing technical input into the design of the site safety plan, advising worker exposure potential along with appropriate hazard reduction methods, and recommending a suitable medical monitoring program for the site workers. ARCO6218.SSP/#20 19 ~[~]] GROUNDWATER --]l~[~l TF. CHNO~.O¢¥, INC. I I I I I i I I I I I I I I I I I I I APPENDIX A (Agreement and Acknowledgment Statement) ARC06218.SSP/~20 [~l--]['~ GROUNDWATER ~-~[~[~ TECI~INOLOCY, INC. I J[-~ GROUNDWATERSIGN - OFF SHEETS This is to certily that I have read, fully understand and agree to comply fully with the attached Health and SaIet¥ Plan turnished to me by Groundwater Technology, Inc. for the above project, NAME SIGNATURE COMPANY DATE I I I I I I I ,I I I I I I ! I I I I I ARC06218.8SP/#20 APPENDIX B (Site Safety Plan Amendment Sheet) ~--~-'~L~ GROUNDWATER [][~--~ TECHNOLOGY, INC. I I I I i I I I I I i I I I I I I I I APPENDIX B Site Safety Plan Amendment Sheet Project Name: Project Number: Location: Changes in field activities or hazards: Proposed Amendment: Proposed by:__ Date: Approved by: Date: Project Manager Date: Health & Safety Manager Declined by: Amendment Number: Amendment Effective Date: Date: ARCO6218.SSP/~20 [~[]L"~ GROUNDWATER [--][][] TECHNOLOGY, INC. I I ! I I I I I I I I I :1 '1 I I I I APPENDIX C (Definition of Hazard Evaluation Guidelines) ARCO6218.SSP/~20 '[]r--][]l CROUNDW^TER ~---]~--][~J TECHNOLOGY, INC. I I I I I i I I I I I I I I I I I I I Hazard: Airborne Contaminants Guideline' Threshold Limit Value Time-Weighted Average (TLV-TWA) Permissible Exposure Limit (PEL) Immediately Dangerous to Life and Health (IDLH) Hazard: Explosion Guideline Lower Explosive Limit Upper Explosive Limit (UEL) Hazard: Fire Guideline Flash Point (flash p) ARCO6218.SSP/~20 APPENDIX C Definition of Hazard Evaluation Guidelines Explanation The time-weighted average concen- tration for a normal 8-hour work day and a 40-hour work week, to which nearly all workers may be repeatedly exposed without adverse effect. Time-weighted average concentra- tions similar to (and in many cases derived from) the Threshold Limit Values. "IDLH" or "Immediately dangerous to life or health" means any atmospheric condition that poses an immediate threat to life, or which is likely to result in acute or immediate severe health effects. This includes oxygen deficiency conditions. Explanation The minimum concentration of (LEL) vapor in air below which propagation of a flame will not occur in the presence of an ignition source. The maximum concentration of vapor in air above which propagation of a flame will not occur in the presence of an ignition source. Explanation The lowest temperature at which the vapor of a combustible liquid can be made to ignite momentarily in air. [~1--][] (;.OVNDW^TE" [~--~--[ TECHNOLOGY, INC. I I I I I I ,I ,I I I I I I I I I I I APPENDIX D (site maps) ARCO6218,SSP/~20 ~-~[~L~ GROUNDWATER ~--~[--~[--~ TECHNOLOGY, INC. I I I I ! I I I I I I I I I I I I I I _~_ ~ ~ ~ ~ · ~ ~ ~ ~ . . ,- ........... IENUE ~.. . ~ k,~ .~ ~ , ~..-I~.~ ~j ~,~ . ~ ~ , ~ ' ~-'i~ ,~ '~ ~.=g ~-~e · · · ~-~.,,~ - ~ :i~o.,,~ , ~,,,,.~,., *,~,,,~,. I ~ ~ ~ ~IF~r ,, I X~Site SITE, ARCO SS ~6218 550 0607 [ sl~r ~c, 4203 Ming 8okersfiold, HAP TYPE: Loc~tion Index SCALE: ~AWN ~Y= ~ATE: ~APPRDVE~ ~Y: ~ ~ATE: MH 2/91 I JOP, 2/91 REV REV]SigN gATE ~/~ 0 ]/4 ]/~ Source: Hoven A Co. Inc. J FIGURE 1 ~GRO~'VATCR ~ ! / MING A VENUE Planter _~.~ Sidewalk + Poll Building LEGEND Proposed Boring SCALE, 40' 0 20' 40' # 215 ,,,E, ARco ss ~2~8 I;~ o,o~ s~rr t~c, Bakersfield, California MAP TYPE, Site Map CA 2/'91I JDP 2/91 : 12EV REVISIDN DATE ]BY I I I I I I ! I I I I I I I I i I ':h: . ~ % ~: -' . ~": / ~ ".~:-' ~ .~'~-'~r'~c~l.I ' ~; ~--'~ xS"'"~/ .' ~:"-~ '~ ~ ,,. : . ,? ,/~~~.~; '~ ~ ..... ' : .,~:7 ~/' :%:? ".%. "1 - "~, · I :'"~ ' " ~:;~~~i ~"F.-',": ~ ....... '~ =~ '-~ .... - ~ Mercy Hospital 2215 Truxfon Ave. j~ Son Jooquin Hospital 2615 Eye SL l~ Memorio'l Hospital 4'20 34th SI ~ SCALE: 1/~ 0 1/4 1/~ mites U.S.G.S. 7.5 Minute Quadrangle ):. Y.':;, ( '_-.",.';; .- I I I I I I I I I ! I I I I I I I I I I ARC06~I 8.SSP/~20 APPENDIX E (MSDS) [--ll--lC~ CROUNDW^TE:R r-1I--1[-3 TE:CHNO~.OC¥, INC. No. :316 Material ,_Safety Data Sheet~ BENZENE From Genium s Referencealecfion . Genium Publishing Corporati'~Y. (Revision D) 1145 Catalyn Street ....... Schenectady, NY 12303-1836 USA i Issued: November 1978 .... (518) 37%8855 GE.lU~ Puat,8.,.a co~.. Revised: April 1988 SECTION 1, MATERIAL IDENTIFICATION 25 Material Name: BENZENE Description (Origin/Uses): ' Used in the manufacture of medicinal che~cals, dyes, linoleum, airplane dopes, varnishes, and lacquers; and as a solvent for waxes, resins, and oils. HMIS Other Deslgnatlons: Benzol; Phone; Phenylhydride; C,H,; NIOSH RTECS No. CYi400C, C<); H 2 CAS No. C07143-2 F 3 R 1 Manufacturer: Contact your supplier or distributor. Consult the latest edition of the Ct'.errdcalweei R 0 I 4 Buyers' Gu;de (Genium ref. 73) for a list of supplien. PPG* S 2 *See sect. 8 K SECTION 2. INGREDIENTS AND HAZARDS % EXPOSURE LIMITS Benzene, CAS No. 0071-43-2 Ca 100 OSHA PEL g-Hr TWA: 1 ppm 15-Min Ceiling: 5 ppm Action Level: 0.5 ppm ACGIH TLV, 1987-88 TLV-TWA: 10 ppm, 30 mg/m~ Toxicity Data* Human, Inhalation, LC,,: 2000 ppr-.J5 Mia *See NIOSH, RTECS, for additional data with references to in'ita'..ive, mutagenic, Human, Oral, TD,.: 130 mg&g tumorigenic, and reproductive effects. Human, Inhalation, TCu: 210 ppm SECTION 3. PHYSICAL DATA Bolllng Point: 176'F(80'C) Water Solubility (%): Slight Melting Point: 42'F(5.5'C) % Volatile by Volume: 100 Vapor Pressure: 75 Torn at 68'F (20'C) Molecular Weight: 78 Gram.v,Moie Vapor Density (Air = 1): >1 Speclrlc Gravity (H~O = 1): 0.87865 at6g'F (20'C) Appearance and Odor: A colorless liquid; chat,,':eris:ic ator::atic odor. SECTION 4. FIRE AND EXPLOSION DATA ] LOWER [ UPPI~R Flash Point and Me'..hod Autoignition Temperature Flammability Limits in Air 12'F (-1 iA'C) CC 928'F (~98'C) % by Volume 1.3% 7.1% Extinguishing Media: Use dry chemical, foam, or caF:on dioxic.:e to putout benzene fires. Wa'~er may be ineffective ~ an exting'-'isNr, g agent been=se it can scatter and spread the fire. Use wa=r ,.o c~l fire-exposed containers, flush spills away from expos'~,"es, disperse vapor, ar.d protect personnel attempting to step an unigni~e~ benzer, e lea~. Unusual Fire or Explosion Hazards: Benzene vapor is heavier than air and can collect in low-lying areas such ~ samps or we!~. Elimina.'- a~ sources of ignition there to prevent a dangerous fl~hbadc to the original liquid benz~ne. Danger: Explosive and da: ...... e benzene vapor-air mixtures can e~sily form at room tempeav.:'=; always use this material in a way that minimizes dispersion of its va.:er general work: areas. Special Fire-fighting Procedures: Wear a self-contained breathing apparatus (SCBA) with a full facepiece ope,"a,.-:l in the pr=ss'-'re- demand or ~sitive-pngssure mode. SECTION 5. REACTIVITY DATA Benzene is stable in closed containers during routine operatiova. It does not undergo hazardous polymerization. Chemlcal Incompatibilities: Hazardous chemical reactions involving benzene and the following materials are repor'~d in Genium reference Sa: brom,:ne pentafluofide, chlorine, chlorine trifluoride, chromic anhydride, nitryl perchlorate, oxygen, ozone, perehlorates, perchloi2,.'l fluoride and aluminum chloride, permanganates and sulfuric acid, potassium peroxide, silver pcrchlorate, and sodium peroxide. Condltions to Avofd: Avoid all exposure to sources et ignition a.-.d to incompatible chemicals. Hazardous Products or Decomposition: Toxic gases lite carbon monoxide (CO) may be produced during benzene fires. I I I I I I I I I I I I I I I t' I Col:~'fight ~ l ~$$ Cevj'am l%bli,*'..mg Coqxntion. A~y cc, mm~ci,,~ ~e ~ rtFoducfion '~4[houL ~ publi.~c.~! i:~v.~uioa i~ m ! I I I I I I I I I No. 316 BENZENE SECTION ~. HEALTH"HAZAI~D '~NFORMATION Bc~z, ene is listed a~ a suspecr~! human carcinogen by tI-,~ ACGIH. Summary of Risks: Prolonged sk/n con,.ct with be~z~'~: or excessive inhalation of'its vapor may cause hem:lache, wc~cness, loss of · ppetite, and l~situ~e. Condnu~ exposure can cause cclhpse, bro~hitis, and pneumonia. The most important health hazards are cancer (leukemia), bone marrow effects, and injuries tn the blood-form/ag dssue from chronic low-level exposure. biedlcal Conditions Aggravated by Long-Term Exposure: AiLments of the heart, lungs, liver, kidneys, blood, ~d centr~ ~ervous sysuem (CNS) may be worsened by exposu.~. Ad~rJnist~r grcplacernent md periodic medical exams emphasizL'~g these functions and re,sign workers who ~est positive. Target Organs: Blood, CNS, bone marrow, eyes, and upi:er re~L'au~ry tract (UR'F). Primary Entry: S',.qn contact, inhalation. Acute Effects: Dizziness, mental dullness, nausea, headache, fatigue, giddiness. Chronic Effects: Possible canc~ (leukemia). FIRST AID Eyes: lmmedia~ly flush eyes, including urn/er the e~lids, g-,n~y but thowughly with plenty of running water for at le~t 15 ~.~nu'-'s. Skin: Immediately w~sh the affected area with soap ~nd wat~-r. Inhalation: Remove the exposed person m fresh air; restcr~ an&tcr support his or ha' breathing as needed. Ingestion: Never give anything by mouth tn someone who is un. congious or convulsing. Do not induce vomiting becaus~ of ~e possibility of aspkalion. GET bIEDICAL HELP (IN PLANT, PARAMEDIC, COMMUNITY) FOR ALL EXPOSURES. Seek prompt medical assistance for further treatment, observatlon, and support after first aid. SECTION 7. SP. ILL~ LEAK: AND DISPOSAL PROCEDURES Spill/Leak: Notify s~ety personnel, provide ventilation, a~d eUmL'~a:e all sources ofignltion immediately. Cleanup personnel protection against contact with and inhalation of vat~r (see sec'~ 8). Contain large spills ~d collect waste or ab~rb it with ~ inert mate.ial such ~ sand, e~_rth, or vermkullte. Use uonsp~rldng tool~ ~ pl~c: w~te liquid or absorbent ~ntn closable coutainen for dis.~osai. Keep waste out of sewen, wa~r~heds, a~d waterways. Waste Disposal: Contact your supplier or a licemed con~'gmr for ~etailcd r~ommcndatioms for disposal. Follow F-,~e.'~l, state, and local regulations. OSHA Designations ALt Contaminant (29 CFR 1910.1~X~ Subpan Z) EPA Designations (40 CFR 302.4) RCRA Hazardous W~ste, No. UOI9 CERCLA Hw.~ous Subst,'mce, Reportable Quantity: 1000 lbs (~f.~ SECTION 8. SPECIAL PROTECTION INFORMATION .' Goggles: AN, ay, we~z Vm~ective eyeglasses or che~cfl sge~ gogg!~. ~e~ spl~hing is ~ssible, we~ a ~11 f~e sS2e!d. Follow eye- ~d f~e-pm~cfion guidefines N 29 C~ 1910.133. Respirator: We~ a NIOSH-appmv~ =spearer ~r ~e NIO$~ to C~ h'~a.~ for ~e ~ximum-use ~=~n~ons ~'or ~he ex~s~ U~ ci~d ~ ~cfion 2. Foffow ~e ~sp~r guideI~es in ~ C~ 1910.!3& ~r e~g~cy or eonmu~ u~ (e.g., clewing mgmr v~sels or s~nge mn~), we~ m SCBA with a ~a~ f~eFi~e ~mted in k~c F~=~4c~mzd or ~si~ve-presvarc ~c. Warning: Ak-pufi~ing respka~m will ~t pm~ct workers ~ oxygez- deficient au~osp~ms. Other: We~ im~mious gloves, ~ ~mn~ gaunfle~ e~., m prevent any possibgi~ of s~n cc=~: wi~h uhis suspend hum= c~Nogen. Ventilation: l=~ll and o~r~ gen=fi ~d lccfl venation sys~ powe~l enough m ~me leveis of ~n~ae ~low ~e ~HA FEL su:d~ ci~ in ~cn 2. Safety Stations: M~e cyew~h s~fi~s, w~hNg f~m, ~d sge~ showen syllable in ~e and hand~g ~as. Contaminated Equipment: C~t~t lenses ~ ~ speci:l ha~'d; ~f: ~g ~y ~scr5 ~mU ~d all lenses ~n~n=a~ hhem. ~ ~t we~ cont~t le~e= m any wo~ ~a. Re=nye ~n~na~ clothi~ ~d lae:~r it ~fcm we~ng it ~ah; clan ~is mamfifl ~om shes m~d ~uip~nk Comments: ~cfice g~ ~nocfl hygi~; ~ways w=h ~homughly afar usNg ~is mate~al. Keep it offof)'our clokhkng md equip~t. Avoid =~sfe~g it from your h~s m yo~ ~uuh wNie e~qg, ~nkNg, or sm~ng. ~ ~t coq dd~ er smoke ~y wor~ ~=. ~ not inh~e ~nme v~r! SECTION 9. SPECIAL PRECAUTIONS AND COMMENTS Storage/Segregation: Store benzene in a cool, dry, well-ve:viIa:eg ~::a away from sources of ignition and incompatible :hem/cass. Special Handling/Storage: Protect containcv~ from phyxical da=ag-.. Electrically ground and bond all metal containen :~ed in shipping or tragsfc:'ring operafioaa. Follow all ~ of 29 CFR 1910.102L Engineering Con trois: All engineering sys','ms (production, t,~nspcr,.'qon, em.) must be of maximum explosion-proof design (non- sparking, electrically grounded and bonded, e',".) Comments: If pot, able, substitute less tnxic sotv~ks for benzene; usc ~.hi~ material with cxa'eme caution and only ff it is absolutely essential. Transportation Data {'49 CFR DOT Shipping Na:u~: P..euz..v~c DOT Class: Flammable Liquid DOT Label: Flammable Liquid DOT ID No. UNIll4 LMO Label: Flammable Liquid IMO Class: 3~ References: l, 2. 1L 73, 84-94, 100, 103. Prepared by PJ Igoe, BS Industtfial Hygiene Review: DJ Wilson, CTH MM..ical Review: MJ Hardies, MD I ~cmum ruonsnmg 1145 Catalyn Schenectady, NY 12303~6 USA - ' (518) 377-~5Y"" . ~~. ](-Revision D) ~ [Issue: Au~_ust 1979 ~,~uu uu~u~'ua IRevlsed: ,~oril 1986' 20 I I i I I I I I I I I I I I I SECTION 1. MATERIAL IDENTIFICATION hlAIEIHALIIAME 11~1 Ill'ltl: OTH'~R DESiGNaTIONS: Methyl Benz. eae, Methyl Be':zoL F,,cnyI. m. eLha..'.e, ToluoI, · · C7H8, CAS ~I0g-88-3 ]VfANUFACTUR~,:USUPPL]ER: Available from ~_-.~.y s'.;.:~Ee:'s, h:clud~g: A1Eed Cop., FO Box 2C64R, Morrismw=, NJ 07~50; Te'.e.:b::¢: (201) 45544CO 'Asb. lazd Cne~caI Co., lndustrl,-1 Cne~c~--~' & Solv~:~ ~v., PO Eox 2219, Columbus, OH; Tc!cphonc: (614) 889-3844 1 I,M 125 H: 2 F: 3 ~: 0 PPE* R 1 I 3 52 K4 .;~SECTION 2...INGREDIENTS AND HAZARDS' Tolueae CH3 0 * , Cu,,'x.=t (198546) ACGIH TLV. The OSHA PEL b 2CO Z:..m with an ac. co, table c:,:t?ng concea~at;on cf 3C'0 ~..m rr2:tLmum pe~ cf 500 ppm/lO *' SUn designation D. dica~s that tclue:c can be sldn azd conu'ibute to overall ex.sure. *** Afl. ts t,~ roLM. .,' HAZARD DATA 18-~ TLV: lC0 ~=., er 375 w_4/m3' 100 V~m: Psycho~pic' R~ C>r~ I.Db;: 5CO3 Rat, l=.hal,-2':~ LC'Lo: 4CC0 ppm/4 ~-' Rabbit, S;d_~ LDSC; i4 H'am~ Eye: D:O :::.SECTION 3."PHYSICAL DATA :'- -." "'"" :"' ' "" '"' ........ "'"': "' '" ' ' Boi.l.i. ng ?cizt ... 231'F (111'C) Ev.h.:'craic: R~'- (BuAc = 1) ... 2.24 Va.~r Pr:~,ss,,:re @ 20'C, mm, Hg ... 22 S.:~hqc G.,"avi~ (H20 = 1) ... C..;,.~ Water Solub;2i ,ty @ 20'C, wt % ... 0.05 MelSng Point ... -139'F (-gJ'c) Vapor Dezs{.? (.~; = I) ... 3.14 P:.~"-:t Vcl~c by Votu.~ ... ~ 103 M.o!~u!-'~ Wright ... 92.15 A~c.w:2:c: :rd eden Ciez5 cclcrl-.~x Equid wiS'. a c>.-'-~-'..'s:/: z-o~_a~c c~.'r. 'E,'~ ofcr b d~.~h'.,e ~o rcs: "-dlv!d'~ ir. thc razg: of 10 to 15 ppm. E~au~e.cb'ac:-or/fatigue oc.:'.m pmpe.?. ::SECTION 4..:'FIRE AND EXPLOSION DATA .'.- '. --".-;-..::~ 4 LO~,NTR { L..TPER Flash Poi.hr and Met.hod Autcignidon Te.'r:. I Fla.mmabiliq' LL,-r,.iu Lq Airj 40'F (4'C) CC g96'F (a30'C', J % by Vo?.:':e J 1~7 '7.t F_XT1NGUIS:-'!NG MEDL&: C~= dioxide, d~ che~c£, v4il ~ar2r azd scmad the fwe. U~e wa'--r sFray to ccel L.rNUSU.~L ~R0~XPLOS!ON t4.i7~4~5: h,*~'-d wh~ exr-'o.~ to ox~dizem, beak ~arks, or dista=c: t~ m ig=i~on ~ourr. e a~ fl~h SPECIAL FiRE-FIGHTING PROCEDURES: o~ra::d b a ~sir. ive-pr=ssta-: mode w.he-a figh~g fi~ "-veb~g mlu=~. ;::SECTION 5.:.'REACTIVITY DATA %':'-' ' -.' L CHEMICAL INCOMPATIBI!~i'IES: Tolue~ b s',ble ;--~ clcs~ c.::',:..zL:~v~ at rccm t:r..~n~m u::c~, ncr-~....sd s'-:.-'.4: azd h2mdling conditions. It docs ~ot und .er'go h -az.~ous l:el.v'~:'f'.za'&:. Tr~ ma~---ri,'al i~ irr.~mpa:!blc with s~ o.~d:7:rg agents, dizi~ge: te'~'a3xide, silvc pexhbrate, te~ai~r_.c'-h2:c, ,--.d u:anium bexafluedde. Co='..:~:t with bh~.: may cause f~ or explosion. Ni~c ~::d a:d koluc:¢, cG~i~7 ;" ,2',~ pv-~c~ of suL~"ic acid, w;'._l Froduc2 ni~'--~ com~ueds ~at ar=. d:m. gemuxly explosive. CONDITIONS TO AVOID: Avoid exper',,'= tn G.~a, ¢~n F~a..-x'., bet .,,.~-l'~ex, ar.d ~1 mu.-,..:x cf ~ ~ ',,,511 amok mine forma of phstica, rub!:~:, ~nd coa'"".g~. 'F,'~':~.- '" g..~.~m.>o~it/cn or bumZg p.~.':,duc..~ c:u~'m c~rbon mceo.*2de. I I i'4o. 3~7 4/86 ~ , .. , .. h~utl~u of ~¢ cv~. no~ u~ ~ ~L ~d ~ E~s~ ~ 2~ ~m f~ 8 ho~ ~u~ ' '" ~m mh~ for Fa~h~ ~:k o~ ~ suy~ ~ ~ ~ ~ ~. SE~ION 7. SP~L.':LEAK. AN~ D~FOSAL pROCEDURES :!::;:::~:~f::'~'::;~:~:~'~'~:~:~:;::~:::::'~<'i~i:4 ezplos[ou-~f v~oa limit ~ m ~ ~ m n~c~y ~1 ~Iy. R~ve pla~ Lr f~iblc. Ge=uy ~I ~ ~ ~'~-~: ~:: ~q:h Eq~d ~ ~h~ of va~ (~ ~ 8). 8. SPECML PROTE~ION ~NFORMA~ON-::~"4~:~'~::'::~:::::{: SE~iON S E ~ I O N 9.' S P E C t A L' F R E C A U~ I O ~'S A N D C O ~ E N~S.!;;::~:'~'~ ~u~u. ~PECI*L ~xN~'G/~GE G~u~ ~ ~ ~'2 ~:~ ~ ~7 Wo~ cx~ ~ ~~s g~2~ u~m ~ ~fca ky:! (53 ~) ~ ~ cx~ ~ l~t ~ a yc~. U~ cf d~ Dau ~u~s) C~:: ]-9, 12. 16, ~3, 2}. 2~. 26. 31. 81.82. ~, I~... I' I I I I I I From Genium's R'eferenc~llection ] xYLEN'E (Mixed Isomers) ' Genium Publishing Corpora~$R' ' I (Revision D) 1145 Catalyn Street ' Issued: November 1980 Schenectady, NY 12303-1836 USA Gmu.,o~Us,~,Gco,~. Revised: August 1988 (518) 377-8855 ..SECTION-ll;ilMATERIAL':'IDENTIFICATION :!i!i~!~i::~?~::.~:~;i.~:?:~i:~;?:::~.::.:.?..;~::;:.?~.:::~:~:~::~i:.:/;i~!!~::~!~.{i??:::~:::;:!:.:;4~:~i:i~..?::.~ ..:: :':- '... :: 26! ~laterial Name: XYLENE (Mixed Isomers) - - A Description (Origin/Uses): Used as a raw material for the production of benzoic acid, phthalic (mhydride, isophthalic (md terephthalic acids and their dimethyl esters in the manufacture of polyester fibers; in sterilizing catgut; with Canadian balsam as oil-immersion in microscopy; and as a cleaning agent in microscopic techniques. Other Designations: Dimethylbenzene; Xylol; C,H~o; CAS No. 1330-20-7 NFPA ~,Ianufacturer: Contact your supplier or distributor. Consult the latest edition of the Chemlcalweek HMIS Buyers' Guide (Genium ref. 73) for a list of suppliers. H 2 R 1 Comments: Although there are three different isomers of xylene (ortho, recta, and para), the health and physical F 3 I 3 aazards of all three isomers are you similar. This MSDS is ~'riuen for a xylene mixture of all three isomers, R 0 PPG* S 2 which is usually commercial xylene. *See sect. 8 K 3 /S E C T I O N .2 ?IN G R E D I E N T S'?A N D ::H A Z A R D S ::i:ili::~.5::--:i:~ ::;::ri % :: :.::ir,'. :::~:i;: :.~i:.i:..19.E X P O S U R E L I M I T S ::-.-'.. Xylene ¢.lixed Isomers), CAS No. 1330-20-7' ** IDLH"' Level: lCq'X9 ppm *o-Xylene, CAS No. 0095-47-6 OSHA PEL m-Xylene, CAS No. 0108-38-3 8-Hr TWA: 100 ppm, 435 ~.g/m~ p-Xylene, CAS No. 0106-42-3 ACGIH TLVs, 1987-88 "Check with your supplier to determine if there are additions, contaminants, or TLV-TWA: 1O0 ppm, 435 rog/m: impurities (such as benzene) that are present in reportable qu~tides per TLV-STEL: 150 gpm, 655 mg/m~ 29 CFR 1910. Toxicity Data .... '"Immediately dangerous to life and health. Human, Inhalation, TC~,: 2CO ppm **** See NIOSH, RTECS (No. ZE2100CO0), for additional dam wi~ references Man, Inhalation, LC,..: lC~O3 ppn,,'6 Ers to reproductive, irritative, and mutagenic effects. Rat, Oral, LDso: 4~0,3 rog/kg 'SECTION 3.':PHYSICAL DATA :. '..~:.:::.~:'.:..::: :':i:.. · .::.:~::.i::;..: .!" Boiling Point: 275'F to 293'F (135'C to 145'C)* Water Solubility (%): Insoluble Melting Point: -13'F (-25'C) Molecular Weight: 106 Gra?~x:Mo!e :Evaporation Rate: 0.6 Relative to BuAc = I % Volatile by Volume: Ca Specific Gravity (HaO = 1): 0.86 Vapor Pressure: 7 to 9Tom at63'F (20'C) ' Vapor Density (Air = 1): 3.7 Appearance and Odor: A clear liquid; aromatic hydrocabon odor. *Materials with wider and narrower boiling ranges are ~e,;~_... avadable. SECTION 4.'FIRE AND EXPLOSION DATA ..' '. " ': :.LOWER ! UPPER Flash Point and Method Autoignition TemFeramre Flammability Limits in Air 81°F to 90'F (27'C to 32'C) 867'F (:64'C) % by Volume 1% d.~x:,... Use water soravs to reduce the rate of bumin-_- and tc cool containers. Extinguishing Media: Use foam, dryche.,nical, orca~on :~ '~ , . Unusual Fire or Explosion Hazards: Xylene vapor [s heavier than air and may travel a considerable distance ignition and flash back. Special Fire-fighting Procedures: Wear a self-ccn,,ined breathing apparatus (SCBA) with a full facepiece opera'~d in ~e pressure- demand or positive-pressure mode. SECTION 5. REACTIVITY DATA Xylene is st:ble in closed containers during routine oper,-,ions. I.'- does not undergo hazardous polymerization. Chemical Incompatibilities: This material ma}' react dangerogsly with strong oxidizers. Conditions to Avoid: Avoid any exposure to sourzes ofignit!cn and to strong oxidizers. Hazardous Products of Decomposition: Caren mono.~de (CO) may be evolved during xylene fires. I I I '1 '1 I I I I Co~ri~,hl © I OS~I G¢~um P~bl~ "',inl Corpo~tio~. ,Any cornn':.¢r ¢i~1 uae or :,~x!ucllon without ~,he puPils.her* F."m,.~ion a ~ol'~',"il-~J. No. 318 XYLENrE (Mixed i~'~ers) $/88 ~ · I I I I I I I I I I I I I I Xylene is not listed as a carcinogen by the IARC, NTP, or OSHA. Summary of Risks: Liquid xylene is a skin irritant and causes erythema, dryness, and &fatting; prolonged contact may cause blistering. Inhaling xylene can depress the central nervous system (CNS), and ingesting it can result in gastrointestinal disturbance; and possibly hematemesis (vomiting blood). Effects on the eyes, kidneys, liver, lungs, and the CNg are also reported. Medical Conditions Aggravated by Long-Term Exposure: Problems with eyes, skin, central nervous system, kidneys, and liver may be worsened by exposure to xylene. Target Organs: CNS, eyes, gastrointestinal tract, blood, liver, kidneys, skin. Primary Entry: Inhalation, skin contact/absorption. Acute Effects: Dizziness; excitement; drowsiness; incoordination; s~ggering gait; irritaffon of eyes, nose, and throat; corneal vacuolizafion; anorexia; nausea; vomiting; aMominal pain; and dermatitis. Chronic Effects: Reversible eye damage, headache, loss of appetite, nervousness, pale skin, and skin rash. FIRST AID: Eyes. Immediately flush eyes, including under the eyelids, gently but thoroughly with plenty of running water for at least 15 minutes. Skin. Immediately wash the affected area with soap and water. Inhalation. Remove the exposed person to fresh air; restore and/or support his or her breathing as needed. Have a trained person fidminister oxygen. Ingestion. Never give anything by mouth to someone who is unconscious or convulsing. Vomiting may occur spontaneously, but do not induce it. If vomiting should occur, keep exposed person's head below his or her hips to prevent aspiration (breathing the liquid xylene into the lungs). Severe hemorrhagic pneumonitis with grave, possibly fatal, pulmonary, injury can occur from aspiring very small quantifies of xylene. GET MEDICAL HELP (IN PLANT, PARAMEDIC, COMMUNITY) FOR ALL EXPOSURES. Seek prompt medical assistance for further treatment, observation, and support after first aid. If exposure is severe, hospitilization for at least 72 hours with careful monitoring for delayed onset of pulmonary edema is recommended. Spill/Leak: Notify. safety personnel, provide ventilation, and eliminate all sources of ignition immediately. Cleanup personnel need protection against contact with and inhalation of xylene vapor (see sect. 8). Contain large spills and collect waste or absorb it with a~ inert material such as sand, earth, or vermiculite. Use nonsparking tools to place waste liquid or absorbent into closable con=inen for disposal. Keep waste out of sewers, watersheds, and waterways. Waste Disposal: Contact your supplier or a licensed cona-ac:or for detailed recommendations. Follow Federal, state, and local regulations. OSHA Designations Air Contaminant (29 CFR 1910.1000 Subpart Z) EPA Designations (40 CFR 302.4) RCRA H~ardous Waste, No. U239 CERCLA Hazardous Substance, Reportable Quantity: 1000 lbs (-'.54 kg), per the Clean Water Act (CWA), section 311 (b) (9) Goggles: Always wear protective eyeglasses or chemical saC'e?:' goggles. Where splashing is possible, wear a full face sNeld as a supplementary protective measure. Follow OSHA eye- and face-pretecuon regulations (29 CFR 1910.133). Respirator: Use a NIOSE- approved respirator per be NIOSH Pcc.-ket G,,~.de to Chemical H~..ds for the maximum-use concert=arSons ~d,'or the exposure E~ts cited in section 2. Follow OSHA respirator regulations (29 CFR 1910.134). For emergency or nonroutine use (lem~s or cleaning reactor vessels and storage tanks), wear an SCBA with a full facepiec: opera,ed in the pressure-demand or po.sitive-pressure v-ode. V;arning: AL'- purifying res?amrs will got protect workers in oxygen-de.qcie": atmospheres. Other: Wear irr. pe~'~ous gloves, boo;s, aprons, g~_un:!e:s, etc., as required by the specifics of the work operation to pmve:t pm!onged or repeated skin contact with xylene. Ventilation: Ins.'~ and operate general ~qd local maximum, explosion-proof vet:Eat!on systems powerful enough to maintain airborne levels of xyle=e below the OSHA PEL standard cited in section 2. Lo:al expanse ventilation is preferred because it prevents dispersion of xylene i=to general work areas by eliminating it at its source. Consult uhe la.est edition of Genium reference 103 for detailed recommendations. Safety Stations: Make eyewash stations, safety/quick-d~:ch showers, and washing facilities available in areas of use and h~d~zg. Contfiminated Equipment: Contact lenses pose a s~ci,-! k-,zard; soft lenses may absorb irrit~ts and all lenses co,'con:rate k':em. Do not v,'e~ contact lenses in any work area. Remove centana:ed clork~ng ~d launder it before wearing it again; c!e~ xy!ene from skces . ~ .,ways wash thoroughly after using this material. Keep it off of vour and equipment. Comments: Practice good personal hygiene; ,~ clothing and equipment. Avoid transfen'ing it from your h =-T. ds ~ )'oar mouth while eating, drioklng, or smoking. Do rot eat, d~c, er smoke L,, any work a-ea. Do not inhale xy!ene vapor. ::SECTION :9;-SPECIAL-PRECALTIONS .AND .COMMENTS ...................................... Storage/Segregation: Store xylene in a cool, dry, v. eu-ve:::Ia=d area away from sources of ignition and strong oxidizers. P.wtect containers from physical damage. Special Handling/Storage: Make sure all engineering sys:e.v_a (production, transportation) are of ma.'cimum explosion-proof desigv.. Ground and bond all containers, pipelines, etc., used in shipping, ~-~sferring, reacting, producing, and sampling opera:ions. Transportation Data (49 CFR 172.101-2) DOT Shipping Name: Xylene DOT ID No. UN1307 DOT Label: Flammable Liquid DOT Hazard Class: Flammable Liquid IMO Label: Fiarm--nable Liquid IMO Class: 3.2or3.3 References: 1, 2, 12, 73, 8404, 100, 103. Judgme=t~ ~ :o ~.~.e suit~i!ity of info .rn:.atio,, bm'cia for puahascr's nec~sarily pa.'v, hascr's responsibility. Therefon=, alt.~,ough re..uonable been :akea ia the pre.ration of such info ,rwa:.io.. Ge:Sum P',.'blisN?.g Co..?. extends no v.'a..-r-a~, rcak--~ no reprezenta.':oea :md 2ss.:m,'~ :o ,"~?"s:~=:~:y a~ to the accuracy or ~uitability or s~h iaforma~ioa for application to purc~aser'~ inte:g~ purl~se~ or for co. sequenc~ of i~ ~e.. Prepared by PJ Igoe, BS Industrial Hygiene Review: DJ Wilson, CIE Medical Revie~v: MJ Hardies, MD Cop)Tigk. t ,1~ 1. SS Ge.".iu~. Pub,L~h',g MATERIAL SAFETY DATA SHEET 1145 CATALYN ST~IE.~ T .. SCHENECTADY, NY 12303-1836 USA ' ' (518) 377-8855 GP 385 No. ETHYL B EN'Z ~;E G[NIUMPU,USHINGCCDI: Date August 197~ SECTION I, MATERIAl' IDENTIFICATION I I I I I I I I I I I I I tATERIAL NAME: ETHYL BENZ~NE OTHER DESIGNATIONS: Phenylethane, E:hylbenzol, C2H5C6H5, CAS# 000 100 414 }tA~NUFACTURER: Available from several suppliers. SECTION II, INGREDIENTS AND HAZARDS ~ HAZAAO DATX ca 100 8-hr TWA 100 pp--~, Ethyl Benzene *Current OSHA permissable exposure level. A Standard was proposed by OS~q in October 1975 which includes an action level of 50 ppm, and detailed requirements of monitoring, medical surveillance, employee train- ing, etc.; when exposure exceeds 50 ppn. It has not vet issued as a legal reeuirement. Human, inhalation TCLo lC0 ppm for 8 hr (irritation) Rat, Oral LD50 3500 mg/kg SECTION III, PHYSICAL DATA Boiling point at 1 arm, deg C -- 136 Specific gravity 20/4C Vapor pressure at 25.9 C, ~m Hg - 10 Volatiles. % Vapor density (Air=l) 3.66 Evaporation rate (B~c=!) Water solubility at 20 C Wt. % - 0.015 Melting point, dog C Molecular weight 0.567 ca !00 <! -95 !C6.!5 Appearance & Odor: Clear, colorless liquid with an aromatic hydrocarbon odor, SECTION IV, FIRE AND EXPLOSION DATA JLO'~--~Ijm,~.--R' Flash Poin~ and Me:hod .J A~tot~n[,~ion Te--.o. J Flammability Limits In AirJ 59 F (15 C) (closed cup'~ 810 F (~32 C)~ Volume % ] !,0 6.7 Extinguishing media: Carbon dioxide, dry chemical or "alcohol" foam, A water, s~ra';. . may be ineffective to put out fire, but may be used to cool fire-ex?csed container A stream' of water can spread fire cf burning liquid. This is a'flammable liquid (OS~.~ Class iR) which can readily fo~ e.xpicslve mixtures with air, esoecially when heated. Heavier-than-air vapors can flow a!cr.g surfaces to reach distant ignition sources, and then flash back', Firefi~hters should use self-contained breathing equip=an: and eye protection to fight :ires ir, enclosed places. SECTION V, REACTIVITY DATA This material is.stable in storage in closed containers at room tempera:ute. It does not polymerize. This flammable material should be ke?~ separated from oxidizing agents, strong acids and bases and ammonia. Thermal-oxidative degradation can produce toxic products, including carbon monoxide. Cop.tr~hI ~'. 1~8-1 C~nlutn Publl~hl~ Coe~k~ GENIUM PUBLISHING I I I il I I I I I I I I I I I I I I I :' ; NO. 385 SECTION VI. HEALTH HAZARD INFORMATION TLV 100 DDm Excessive exposure to vapors will irritate the eyes and r~ucous membranes of the upper respiratory tract. Sustained high levels can produce headache, depression of the central nervous system, narcosis and coma. Liquid contact is irritati~g to the eTes and irritation and deferring to the skin, leading to dermatitis on prolonged or repea~ed exposures. Ingestion aspiration of liquid into the lungs small amounts of aspirated ethyl benzene cause extensive edema and hemorrhage of lung tissue. FIRST AID! Eye contact: Wash eyes well with plenty of running water. Get medical help if irritation persists. Skin contact:' Wash exposed areas of skin. Pro~..-rptly remove con~a.~nated clothing. Inhalation: RemDve victim to fresh air. Restore breathing if necessary. Get medical help for serious exposure. Inzes~ion: Get prompt medical he!p~ (~he danger of aspirating ethyl benzene into the lungs indicates medical direction before inducing vomiting.) SECTION VII, SPILL, LEAK, AND DISPOSAL PROCEDURES Personnel involved in leak or spill control and clean-up must use protective equip- menc to avoid inhalation of vapors and contact with liquid. Eliminate ignition sources. Provide maximum explosion-proof ventilation. Pick-up spilled material for recovery er disposal. Absorb with sand, etc. for dis- posal in a sanitary landfill or with paper t~els or cloths for burning. ~ater can be used to flush liquid away from sensitive areas to special ca,ch basins or ground, but no~ to sewer or surface water. DIS?OSA±: Scrap v~terial can be burned in approved incinerators in accordance with Federal, State and local re~u!a~icns. SECTION VIII. SPECIAL PROTECTION INFORMATION Provide expolcsion-proof general and lcczl exhaust ventilation to mee~ iLV require- men~s. Approved respirators mus~ be available for non-rou~ine or emergency use. A full face respirator with organic vapor cartridge can be used up co 1000 ppz; a gas mask with organic vapor canister can be used up to 5000 ppm' a self-con~aized respirator is needed for high and unkzc~v, concentrations of vapor. Use impervious gloves and clothing and a face shield to prevent repeated or pro!cnge contact with the liquid, g%ere splashin~ is possible chemical goggles sh~u!d be used. Clo~hing contaminated witi%'e~hy! ~enzene should be prompc!y removed and no~ reused until free of the contaminant. Exposures above the action level, liquid con,act, or working ~ere fire and explosic hazards exist may require instituting employee training, medical surveillance, vapor concentration monitoring, rec, r~ keeping, etc. ~en the proposed standard issues. SECTION IX. SPECIAL PRECAUTIONS AND CO~ENTS Store this material in tightly closed containers in cool, well-ventilated areas, away from oxidizing agents, heat and sources of ignition. Use non-sparking tools around this material. Containers must be electrically bonded and grounded for transfers of liquid. Use safety cans for s,-.mll amounts. No Smoking'. where this material is stored or used. Screen ~'orkers for history of kidney, liver~ skin and lung problems ~'hich could £iv~ increased sensitivity and risk in ethyl benzene exposure. Avoid brea~hing of vapors and contact ~'ith li(u!d. Do not inKes~. L-nronic proper- ties are no~ fully kno~,~; use with care. DATA SOURCE(S) CODE~ 2-9, 1~, 12-- Corporate Ned,! ca_~3L .... j GENIUM PUBLISHING I I NO. 467 GENIUM PUBLISHING CORPORATION GASOLINE, LEAD-FREE ~r . 1145 CATALYN STREET · '. SCHENECTADY. NY 12303-1836 USA (518) 377-8855 · G~N~UM ~IUSMm~co~. ... Date October 1981 SE'~TION I, .MATERIAL IDENTIFICATION MATERiAL NAME: AUTOMOTIVE GASOLINE, LEA~-~REE DESCRIPTION: A volatile blend of hydrocarbons for automotive fuel OTHER DESIGNATIONS: Petrol, CAS #008 006 619, ASTM D439 MANUFACTURER: Available from several suppliers. SECTION II, INGREDIENTS AND HAZARDS x HAZARD DATA Ga'soline 100' 8-h~' %WA 390 ppm or A hydrocarbon blend that can include normal and branched 900 mg/m~* chain alkanes, cycloalkanes, alkenes, aromatics and other additives.~* (Lead max 0.013 g/L, phosphorus Man max 0.0013 g/L, sulfur max 0.10 wt%. May contain Eye: 500 ppm/1H benzene, <5%; see ASTM D3606). Moderate irritation ~ACGIH 1981TLV (Intended Changes List). See also Am. Ind. Hyg. A. 39 110-1t7 (1978) Inhalation: · *The composition of fuel is varied with altitude and TCLo 900 pDm/1H seasonal requirements for a locality, The blend must TFX:CNS meet antikmock requirements. (Antiknock Index min 85, ASTM D439.) ,, SECTION III, PHYSICAL DATA Distiilation at 1 acm, Initial, dog C >39 Specific gravity, 6'0/60 F - 0.72L0.76 50% distilled - 77-12t Melting point, dog C ....... 90.5-95.4 End point <240 Evaporation rate N/A Vapor density (Air=l) ............. 3.0-4.0 Solubility in water Insoluble Appearance and Odor: A clear, mobile liquid with a characteristic odor which can be recognized at about 10 ppm in air. (Gasoline may be colored with dye.) SECTION IV, FIRE AND EXPLOSION DATA LOWER '~lash Point and' Method" I Autoi~nition Temo. Fl'ammability Limits In Air -45 FI 536-8~3 F .... % by volume 1.~ 7.6 Extinguishing Media: Dry chemical, carbon Jioxide, alcohol fom~. Use of water ma'/ be ineffective to extinguish fire, but usa water spray for cooling fire-exposed drums and tanks to prevent pressure rupture. I: is a dangerous fire and explosion hazard when exposed to heat and flames. Vapors can flow along surfaces, reach distant igni- tion sources and flash back. Can react violently with oxidizing agents. Firefighters should wear self-contained breathing apparatus and full protective clothin~ SECTION V, REACTIVITY DATA This is a stable material in closed containers at room temperature under normal s~orage and handling conditions. It does not undergo hazardous polymerization. This is an OS~ Class IA fla.~mable liquid. A mixture of gasoline vapors and air can be explosive. It is incompatible with oxidizing agents.. Thermal-oxidative degradation can yield carbon monoxide and partially oxidized hydrocarbons. I I I I I I ! I I I I I I I I GENIUM PUBLISHING I I I I I I I I I I I I NO. SECTION VI, HEALTH HAZARD INFORMATION I TLV 300 ppm (See Sect. II) :Inhalation causes intense burning of the mucous membranes, throat and respiratory tract; overexposure to vapors can lead to bro~chopneumonia. Inhalation of high cone. can caus~ fatal pulmonary edema. Repeated or prolonged skin exposure causes dermatitis. Lan cause blistering of skin due to its defatting properties. Exposure to eyes can cause hyperemia of the conjunctiva. Ingestion or excessive vapors can cause inebriation, drowsiness, blurred vision, vertigo confusion, vomiting and cyanosis (2000 ppm produces mild anesthesia in 30 min, higher cone. are intoxicating in less time.) Aspiration after ingestion causes bronchitis, pneumonia, or edema which can be fatal. FIRST AID: Eve Contact: Flush thoroughly with running water for 15 m/n. including under eyelids. Skin Contact: Remove contaminated clothing.' Wash affected area with soap and water. Inhalation: Remove to fresh air. Restore breathing and administer oxygen if needed. Ingestion: Do not induce vomiting. Aspiration hazard. Contact physician. Seek prompt medical assistance for further treatment, observation and support.' SECTION VII, SPILL~ LEAK~ AND D]SFOSAL PROCEDURES Notify safety personnel of leaks or spills. Remove sources of heat or ignition. Pro- vide adequate ventilation. Clean-up personnel require protection against liquid con- tact and vapor inhalation. If a leak or spill has not ignited, use water spray to disperse vapors and to protect men attempting to stop the leakage. Contain spill. Do not allow to enter sewer or surface water. Add absorbent solid to small spills cr residues and pick up for disposal. DISPOSAL: Burn scrap material in an approved incinerator. Burn contaminated liquid by spraying into an incinerator. Follow Federal, State, and Local regulations. SECTION VIII, SPECIAL PROTECTION INFORMATION Use general and local exhaust ventilation (exolosion-proof) to keep vapors below cae iLV requirements in the workplace. Respirators should be available for nonroutine or emergency use above the TLV. Avoid eye contact by use of chemical safety goggles and/or full faceshield where splash- ing is possible. Wear protective clothing appropriate for the work situation to minimize skin contact such as rubber gloves and boots. ClothinK to be changed daily and laundered. Eyewash fountains, showers and washing facilities should be readily accessible Provide suitable training to chose handling and working with this material. SECTION IX, SPECIAL PRECAUTIONS AND COMMENTS Store in closed containers in a cool, dry, well-ventilated area away from sources of heat, ignition and strong oxidizing agents. Protect containers from physical damage. Avoid direct sunlight. Storage must meet requirements of OSP~I Class IA liquid. Outdoor or detached storage preferred. No smoking in areas of use. Prevent static electric sparks and use explosion-proof electrical services. (Must meet code.) Avoid skin and eye contact. Avoid inhalation of vapors. Wear clean work. clothing dail) Indoor use of this material requ~ras exhaust ventilation to remove vapors. ICC Flammable Liquid, Red Label. IAB£L: F!am=able Liauid DOT I.D. No. UN 1203. DOT Classification: FL.~>t~.BLE LIOUID MIS ~ATA SOURC~(S) CODE: 2,4-?.~t.~7 APPROVALS: CRD 0, ~'~,'~-~ ,~, ...... : ............... Industrial H~giene MEDICAL REV~E~: GENIUM PUBLISHING I I I I I I I I I I I I I I I I APPENDIX F (Accident Investigation Form) ARC06218.SSP/#20 [-1[][~ C.OUNDW^TE. ~-][]~'-~ TECHNOLOGY, INC. I I I I I I Employee ' s Name: Address: GROUNDWATER TECHNOLOGY, INC. Accident/Incident/Near Miss Report D.O.B. D.O.H. ss# Job Title: Supervisors's Name: office Location: Location at Time of Incident: Date/Time of Incident: Description: Describe clearly how the accident occurred: IWas Incident: Physical Part(s) of body affected: I I I right left Witnesses: 1) 2) Chemical Exposure: Dermal Inhalation Ingestion Conditions/acts contributing to this incident: iExplain specifically the corrective action you have taken to prevent a recurrence: IDid the injured go to a doctor? IDid injured go to a hospital? Where? When? Where? When? I I I I Signatures: Employee Reporting Manager Regional H&S Manager Date Date Date This form must be compteted and returned within 5_ working days to Regions[ Health & Safety Manager, who witt forward a copy to Corporate I~eatth & Safety Manager at ELO. --~[~L~ GROUNDWATER -~[][] TECHNOLOGY, INC. ARC06218.SSP/~20 I I I I I I I I I I I I I I I I I I I APPENDIX G (Vapor Monitoring Sheet Form) ARCO~21S.SSP/#20 I--]1-1[] C.OVNDW^TF~" ~--Ir--~l--I TECHNOLOCY, INC. I I I I I I I I I I I I I I I I I I I APPENDIX H (Excavation/Trenching) ARCO6218.SSP/~20 [~r--~;~ GROUNDWATER [][~[~] TECHNOLOGY, INC. I I I I I I I I I I I I I I I I I I I GROUNDWATER TECHNOLOGY, INC. EXCAVATION AND TRENCHING POLICY - CALIFORNIA SAFE CODE OF PRACTICES Although many of the rules and regulations pertaining to excavation and trenching operations in the State of California closely parallel Federal Standards, this policy specifically pertains to California operations. It shall be the policy of Groundwater Technology, Inc. to ensure that all Groundwater Technology employees and subcontractors comply with the provisions within the California Code of Regulations, Title 8, Chapter 4, Subchapter 4 - Construction Safety Orders. It is inevitable that remediation procedures for which Groundwater Technology is retained will involve some aspect within the jurisdiction of the Construction Safety Orders. Such operations may include: trenching, vault construction, tank removal, and excavation of contaminated soils. DEFINITIONS - EXCAVATION, TRENCHES, EARTHWORK Bank - a mass of soil rising above a digging level. Bell Hole - an additional excavation made into the sides or bottom of a trench to provide additional work space. Belled Excavation - a part of a shaft or footing excavation, usually near the bottom and bell-shaped, that makes the cross-sectional area at that point larger than that above. Benchinq - a method of excavation whereby the faces of an excavation or trench are widened progressively outward with respect to the bottom of a specific series of horizontal and vertical cuts to provide protection against the hazard of moving ground. Braces for Excavation - the horizontal members of the shoring system, the ends of which bear against the uprights or stringers. Earthwork - the process of excavating, moving, storing, placing, and working any type of earth materials. Excavation - a man-made cavity or depression in the earth's surface, including its sides, walls, or faces formed by the removal of materials, and producing unsupported earth conditions by reason of such removal. If installed forms or similar structures reduce the depth-to-width relationship, the excavation may become a trench. Exploration Shaft - a shaft created and used for the purpose of obtaining subsurface data. Geote'chnical Specialist (GTS) - a person registered by the State as a Certified Engineering Geologist, or a Registered Civil Engineer trained in soil mechanics, or an engineering geologist or civil engineer with a minimum of 3 years applicable experience working under the direct supervision of either a Certified Engineering Geologist or Registered Civil Engineer. Hard Compact - all earth material not classified as running soil. Hydraulic Shorinq - a shoring system using hydraufic cylinders, planks, rails, plywood, or steel beams to support the excavated wall of trenches. APNDIX-H/SSP MASTER ' l ~---]~] GROUNDWATER --]l--]~-~J TECHNOLOGY, INC. I I I I I I I I I I il .I I I I I I I I Laqqinq - boards which are joined, side-by-side, lining an excavation. Runninq Soil - earth material where the angle of repose is approximately zero, as in the case of soil in a nearly liquid state, or dry, unpacked sand which flows freely under slight pressure.. Running material also includes loose or disturbed earth that can be only contained with solid sheeting. Shaft - an excavation under the earth's surface in which the depth, is much greater than its cross-sectional dimensions (such as those formed to serve as wells, cesspools, certain foundation footings, and under streets, railroads, buildings, etc.) Shore - a supporting member that resists a compressive force imposed by a load. Shorinq System - a temporary structure for the support of earth surfaces formed as a result of excavation work. Sides, Walls, and Faces - the vertical or inclined e~rth surfaces formed as a result of excavation work. Slopinq - a method of excavation whereby the faces of an excavation of trench are laid back to provide protection from moving ground. Spoil - the earth material that is removed in the formation of an excavation. Strinqers - the horizontal members of the shoring system whose sides bear against the uprights. Stringers are sometimes called whalers. Strut - a structural member designed to resist forces, either tensional or compressional. Trench - an excavation made below the surface of the ground. In general, the depth is greater than the width at the bottom, but the width of a trench at the bottom is not greater than 15 feet. Trench Shield - a protective device which shields workers from the effect of ground movement and which can be moved along as work progresses. Upriqhts - the vertical members of the shoring system. Whaler - a structural member in a horizontal or nearly horizontal position used for stiffening or securing other components of concrete forms, excavation sheeting, or similar temporary structures. EXCAVATION PROCEDURES (also trenches, shafts, and other earthwork) 1. Prior to beginning an excavation, the location of all underground utilities and other underground hazards shall be determined. 2. A hazard assessment shall be conducted by a qualified person to evaluate the potential exposure to employees who may work in or around the excavation. 3. The excavation shall also be inspected by a qualified person after each rain or other hazard- increasing event to evaluate the potential hazards from slides or cave-ins. 4. Anytime an employee enters an excavation 5 feet or greater in depth, that employee must be protected by a system of shoring, sloping, benching, or alternative means addressed in #15 below. APNDIX-H/SSP MASTER [--~[--]~l GROUNDWATER F-~[][~ TECHNOLOGY, INC. I I I I ! I I I I I I I I I I I I I I o 6. 7. 8. 9. 10. The conditions in #4 above, will also require Groundwater Technology to obtain the necessary excavation permit and/or notification procedures with Cai-OSHA. Excavated materials shall be prevented from falling back into the excavation. Spoils should be placed no closer than 2 feet from the ~dge of the excavation. Work which is conducted within the excavation should be under the direct supervision of a qualified person who is capable of modifying the shoring or sloping system. A convenient and safe means of egress shall be provided for employees working within an excavation 4-feet deep or greater. This may consist of a stairway, ladder, or ramp located within 25 feet of lateral travel. Any employee working in the vicinity of an excavator shall not be in a position where that employee might fall into contact with the moving parts of that excavator. E, mployees shall also be wearing a reflective vest. An adequate means of water drainage shall be implemented to reduce the likelihood of run-off entering the excavation. This shall hold true during the rainy season. If the accumulation of water could pose a hazard to employees, the situation should be controlled prior to resumption of operations. 11. All shoring systems shall incorporate the soil specifications and conditions for that particular site. The installation of shoring systems shall be conducted in such a way that the employee is properly protected from the potential of cave-ins. Additionally, the removal of the system shall follow the same requirement. 12. If the excavation exceeds 20 feet, or if an alternative shoring, sloping, or benching system is utilized, a civil engineer currently registered in California shall prepare detailed plans showing the materials and methods to be utilized (Appendix A). 13. The detailed plans in #12 above, shall be available for inspection at the site. 14. Shoring shall be installed in accordance with Table 1-6 located within Appendix B, or as detailed in plans and specifications prepared by a State of California Registered Civil Engineer in accordance with engineering criteria within Appendix A. 15. If protective shields, (i.e., trench shields) are to be utilized for the protection of employees within an excavation, a civil engineer registered in California must prepare the necessary calculations and designs prior to the use of such equipment. 16. When sloping or benching are utilized in lieu of a shoring system, the slope shall be at least three- quarter horizontal to one vertical for excavations up to 8 feet, unless the instability of the soil requires a slope flatter than 3/4:1. For excavations greater than 8 feet but less than 12 feet, a slope of 1:1 shall be utilized (Appendix C). On the following pages are specific requirements as set by California Code of Regulation, Title 8, Chapter 4, Subchapter 4-Construction Safety Outline. The pages are facsimiles of pages from this document. APNDIX-H/SSP MASTER TECHNOLOGY, INC. I I I I I I I I I I I I I I I TABLE 1 WOOD ~-IORINC FOR HARD COMPACT SOIL ~ (su~) ~ · Upr~ ~ S'oa c~t~ (O.C.) (w,~] DEl,TH (F,~] Ho~-,~ Wood W~ ~ (~) W~ (F~) 0~) ~.~ w~ (F~) 0~) 8 3x8 4x4~1~ 5to7 4 ~xlO ix4 ~ 2~8 4x4 8 4 x 10 4x4uptol~ 4 3 x 10 ~l~up~l~, 6 x 8 2 3x8 6x6 5x8 8 6 x 8 4 4 x 8 ~ffup~lY, 8 x 8 2 3x8 6z6 8x8 8 6 x 8 4x4uptoff~t~ 4 4 x 10 ~ff~lY, 8 z I0 2 ~ x !0 6x 5 8 x 10 '8 6 x 10 ~x6uptol~ OY~r 2 8 = 12 8x8 6 x 1~ I I i I i I I I I I' I I I I I I I TABLE ~ WOOD S~-IORING FOR RUNNING SOIL ~ ~ W~ W~ ~ (I~) W~ (F~) ~) ~~ w~ W~) 5~8 ~ ~ ~zlO ~ to 1~ 8 to lO ~p ~ 1~ ~ 6 x 6 up to ~ ~ 3 lO x 12 10 ~ 12 ~ 8 x 8 A~ ~t~ ~ ~ 15 ~ 1o 18' g z 8 up ~ i~ w~ 15 to ~ ' t CEN~~[mTa~ · ~ l~l(aX6~ I L ~ :: I I I I I I I I ,I I I I I I I I I I TABLE 8 METAL WOOD SHORING FOR HARD COMPACT SOIL Hc~izc~tll (F~) 8 8 8 4 4 A~uml~ urn l~pe Wkhh (Ft.} s (1o) 8 ~ (~ E~ (8) g (Il) ~ (~) 8 (zo) ]o (15) 5 (s) · J' (9) g (]3) 4 ('5) 8 (]]) 6 15 ~ (n) lo ]:5 ~6 1:~ (]5) lO (15) I I I I I I I I I I I I I I I I I I I TABLE I~rTAL-WOOD SHORING FOH D~ 2% 8 5~8 ~ 2 8x]0 3 10. 2 6 ~ ~ 6 2 6 8 to 10 3 8 2% 12 ~ 2% 4 2 ~ 3 l0 z 12 10 to 12 3 6 2% 10 ~ 3 10 x 12 12 ~ 15 5 6 5 15 3 6 2% 6 ~er ~ 4 3'4 8 3 12 1~ x 12 15 to ~ 4 10 3% 15 I .. EXCEPTIONS: In hard, compact soil where the depth of the excavation or trench is 8 feet or less, a vertical cut of 3 1/2 f~t with sloping of 3/4 horizontal to 1 verti- cal is pexnfitted. _ I In hard, compact soil where the depth of the excavation or trench is 12 i feet or less, a vertical cut of 3 1/2 feet with sloping of 1 horizontal to 1 vertical is permitted. I 12 . I (2) Benching in hard, soil, is that compact permitted provided a slope ratio of 3/4 horizontal to 1 vertical, or flatter, is used. 2' Min. I ,/_ ' -,(typie~I) 3/4zl 'l Nora Authority cited: Section 142.3, Labor Code. Reference: Section 142.3, La- bor Code. I I I I I I I I I I I I I I I I I I I ARCO6218.$SP/~20 APPENDIX I (OSHA Inspection Steps) [][]1~ C.OVNHW^T~. ~-~-~---~ TECHNOLOGY, INC. I I I I I I I I I' I' I I I I I APPENDIX I Immediate OSHA Inspection Steps Identify the Inspector. (a) Ask to see credentials. (b) Write down the relevant information, including the inspector's name, agency affiliation, address, telephone number and the statutory authority under which the inspection is being conducted. (c) If any doubts, call OSHA office to verify the visit. {d) If inspection occurs at a project site, ask for written certification of medical monitoring (including respiratory evaluation) and for 40 hour hazardous waste training certification. NO ONE may venture out of the clean zone without it. DOUBLE CHECK it with his/her office if in doubt. Notify the Health & Safety Manager and Project Manager immediately. (a) The Project Manager should notify the District Manager. (b) The Health & Safety Manager should notify Corporate Health and Safety (ELD). Take notes on: (a) (b) (c) (d) (e) (0 (g) What is said What is seen Who spoke to whom Any sample or copies taken Any corrective actions done in the inspector's presence Any activity, including where, when, who, and what Any other occurrence, even if seemingly minor When in doubt on any question, DO NOT BLUFF AN ANSWER. Ask the inspector to put the question in writing, addressed to company counsel. Never lie, even by omission; jail can be the penalty. If inspection occurs on site, carefully review the Site Safety Plans with the Inspector if asked to do so. If inspection occurs at an office, have accident reports, OSHA 200 logs ready at all times for inspection. Always make sure OSHA poster is visible. Determine the scope of the inspection: Ask the OSHA inspector what areas of the company activity are of interest and the reason for the inspection. Discover what has triggered the inspection. If complaints initiated the inspection, find out specifically what they were. ARCO6218.SSP/~20 ~---][--][~ GROUNDWATER [-~[~][--] TECHNOLOGY, INC. PREPARED FOR: MS. KATERI A. LUKA ARCO PRODUCTS COMPANY P.O. BOX 6411 ARTESIA, CALIFORNIA 90702-6411 (213) 402-1281 SITE CHARACTERIZATION REPORT ARCO SERVICE STATION NO. 6218 4203 MING AVENUE BAKERSFIELD, CALIFORNIA NOVEMBER 11, 1991 PREPARED BY: 'GROUNDWATER TECHNOLOGY, INC. 4101 ALKEN STREET, SUITE B-1 BAKERSFIELD, CALIFORNIA 93308 (805) 589-8601 REVIEWED BY: AN A. BORK, PROJECT GEOLOGIST [~[~[~ TECHNOLOGY TABLE OF CONTENTS PAGE 1.0 EXECUTIVE SUMMARY ....................................................... 1 2.0 INTRODUCTION ............................................................ 2 3.0 SITE BACKGROUND ......................................................... 2 4.0 REGIONAL SETTING ' 2 5.0 SITE ASSESSMENT .......................................................... 3 5.1 Procedures ..................................................... . .... 3 5.2 Analytical Results ..................................................... 5 6.0 RISK ANALYSIS ............................................................. 5 6.1 SESOIL Modeling ...................................................... 6 6.1.1 Model Input Parameters .............................................. 6 6.1.1.1 Sediment Characteristics ...... ................................... 7 6.1.1.2 Contaminant Application ............................ ' ............. 9 6.1.1.3 Conservatism .' ................................................ 9 6.1.2 SESOIL Output ................................................... 10 7.0' FEASIBILITY STUDY ........ · ................................................ 10 7.1 No Action .......................................................... 11 7.2 Soil Venting ......................................................... 11 7.3 Excavation .......................................................... 11 8.0 REMEDIAL ACTION PLAN ' 11 9.0 REFERENCES 13 Characterization Report ARCO Products Company November 11, 1991 ii tGROUNDWATER TECHNOLOGY LIST OF ILLUSTRATIONS Table 1. Table 2. Table 3. Table 4. Table 5. Table 6. TABLES Analytical Results, Soil Samples Beneath Tanks .................................. 3 Analytical Results, Soil Samples Beneath Dispenser Islands and Piping ........................................................ 4 Analytical Results, Soil Samples From Borings ................................... 5 Leaching Potential Analysis ......................................... ' ........7 General Risk Appraisal Applicability Checklist.... ................................. 8 Maximum Pollutant Depth ................................................. 10 Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure FIGURES 1. Location Index 2. Site Map/Boring Locations 3. Sample Locations 4. Site Geology 5. Depth to Groundwater 6. Groundwater Gradient 7. Cross-Section Index and TPHG Contours 8. Cross-Section A 9. Cross-Section B 10. Soil.Compartments 11. Application Area Appendix A. Appendix B. Appendix C, Appendix D. · Appendix E. Appendix F. Appendix G. APPENDICES. Lithologic Logs Disposal Documentation Laboratory Reports SESOIL Climate and Chemical Data Input 95% Upper Confidence Level and Pollutant Load Calculations Abbreviated SESOIL Output Files SESOIL Output' File Diskettes Characterization Report ARCO Products Company November 11, 1991 iii [~[~]~] GROUNDWATER [~[~[~ TECHNOLOGY 1.0' EXECUTIVE SUMMARY Six borings have been drilled and sampled to assess subsurface conditions at ARCO facility no. 6218. Laboratory analysis of soil samples collected during this assessment indicates gasoline hydrocarbons are present below the former location of underground storage tanks. Total petroleum hydrocarbons as gasoline (TPHG) and benzene concentrations range from <10 to 2,700 mg/kg and <0.005 to 3.2 mg/kg, respectively. Maximum concentrations of TPHG and benzene occur at depths of 25 and 40 feet respectively. Site conditions do not allow the use of leaching potential analysis or general risk appraisal methods to determine acceptable concentrations of hydrocarbons which can be left in place without threatening groundwater (LUFT, 1988). A detailed sit. e-specific analysis using the SESOIL model indicates that the concentrations of benzene, toluene, ethylbenzene, and total xylenes (BTEX) present at the site will not impact groundwater throughout a 99 year simulation. Possible remedial action alternatives considered for the site include no action, soil venting, and excavation. No action is the preferred alternative because cOntaminant transport modeling indicates groundwater will not be impacted. Soil venting is considered feasible but cost prohibitive. The excavation alternative is not considered feasible because of high cost and the required destruction of surface facilities. Characterization Report ARCO Products Company November 11, 1991 GROUNDWATER TECHNOLOGY 2.0 INTRODUCTION Groundwater Technology, Inc. has been contracted by ARCO Products Company to perform a site characteriZation at their facility no. 6218 in Bakersfield, California (Figure 1). The purpose of the assessment is to determine the extent of hydrocarbon contamination which is present at the site. This report documents the findings of the assessment. 3.0 SITE BACKGROUND A preliminary assessment of soil conditions was completed at the site on February 22 and March 5, 1991. The assessment consisted of drilling four borings at the locations shown in Figure 2. Soil samples were collected and field screened with a photoionization detector (PID) at 5-foot depth increments. Two samples from each boring were submitted for laboratory analysis. Those selected included the sa.mple from the bottom of each boring and the sample which exhibited the highest headspace-analysis concentration of hydrocarbons as determined with the PID. The samples were analyzed for benzene, toluene, ethylbenzene, and xylenes (BTEX) and total petroleum hydrocarbons as gasoline (TPHG). BTEX and TPHG were not detected. On May 15, 1991, Wegener Construction removed three underground storage-tanks at the facility. No holes were found in any of the tanks, but rust was observed on all tanks. A total of 26 soil samples were collected at the site following tank removal'Operations. Tank pit samples were collected at depths of 2 and 6 feet beneath both ends of each tank. Soil samples were also collected from beneath the product lines and the ends of the dispenser islands at depths of 2 and 6 feet. TPHG concentrations in the samples from beneath the tanks ranged from < 10 to 4,600 mg/kg. TPHG concentrations in samples collected from the beneath the dispenser 'islands ranged from 24 to 4,800 mg/kg. TPHG did not exceed method detection limits in samples collected from beneath the product lines. Laboratory resUlts are summarized in Tables 1 and 2, and in Figure 3. 4.0 REGIONAL.SETTING The site is located on the alluvial plain of the Kern River. Topography in the region is flat, and no natural bodies of water adjoin the site. The station is located in a commercial area and is approximately 2,500 feet southwest of the nearest school. Characterization Report ARCO Products Company November 11, 1991 2 [~[~] GROUNDWATER [~[~[~ TECHNOLOGY Table 1. Analytical results (in mg/kg) of soil samples collected beneath tanks, 5/15/91. Sample # Benzene Toluene Ethyl- Total TPH aS benzene Xylenes Gasoline T1W-2' 0.85 13 5.7 100 1600 T1W-6' 1.8 9.8 8.3 310 4600 T1E-2' <0.005 <0.005 <0.005 0.018 < 10 T1E-6' <0.005 <0.005 <0.005 <0.015 < 10 T2W-2' 24 230 71 460 3000 T2W-6'. 4 87 33 300 2000 T2E-2' < 0.005 < 0.005 < 0.005 0.029 < 10 T2E-6' < 0.005 0.055 0.062 5.7 55 T3W-2' <0.005 <0.005 <0.005 <0.015 < 10 T3W-6' < 0.005 < 0.005 < 0.005 0.16 < 10 T3E-2' < 0.005 0.021 0.006 0.062 < 10 T3 E-6' < 0.005 < 0.005 < 0.005 < 0.015 < 10 The site overlies alluvial-fan deposits of the Kern River (Figure 4). Sediments underlying the region consist of fluvial deposits including silt, sand and gravel. Sediments encountered during drilling and excavation activities at the site consist primarily of medium- to coarse-grained sand and silty sand, with local deposits of clayey silt. An unconfined aquifer is present below the site at a depth of approximately 160 feet (Figure 5). The gradient of this aquifer is generally toward the southeast (Figure 6). Shallow, perched water has not been identified in the vicinity of the site (KCWA, 1990). 5.0 SITE ASSESSMENT The assessment of subsurface conditions at the site consisted of the completion of soil borings .and the analysis of soil samples by a state-certified laboratory. Field activities were completed on September 11 and .12, 1991. 5.1 Procedures Six borings were drilled at the locations shown in Figure 2. The borings were drilled to further define the vertical and lateral extent of contamination in order to evaluate potential threats to groundwater. Boring Characterization Report ARCO Products Company November 11, 1991 3 [~[~--~ GROUNDWATER [~][~ TECHNOLOGY Table 2.' Analytical results (in mg/kg) of soil samples collected beneath dispenser islands and piping, 5/15/91. Sample # Benzene Toluene Ethyl- Total TPH as benzene Xylenes 'Gasoline DI1-2' 0.11 5.1 3.3 37 280 DI 1-6' 0.009 0.14 0.084 1.7 24 DI2-2' < 0.1 5.7 4.9 130 1900 DI2-6' <0.005 0.42 0.61 17 430 DI3-2' 0.30 25 26 630 4800 DI3-6' <0.005 0.15 0.34 11 170 DI4-2' < 0.1 6.8 7.3 610 2900 DI4-6' < 0.10 7.3 6.2 230 ~ 2500 PL1-2' <0.005 <0.005 ' <0.005 <0.0i5 < 10 PL1-6' <0.005 <0.005 <0.005 <0.015 < 10 P L2-2' < 0.005 < 0.005 < 0.005 < 0.015 < 10 PL2-6' <0.005 <0.005 <0.005 <0.015 < 10 P L3-2' < 0.005 < 0.005 < 0.005 < 0.015 < 10 PL3-6' < 0.005 0.005 < 0.005 < 0.015 < 10 B8 was drilled vertically, whereas the remaining borings were drilled at various angles. Information regarding total depth and inclination angles are presented on the lithologic logs in Appendix A. Soil samples were collected at 5-foot depth increments using a split-spoon sampler lined with brass sample rings. The material from one sample ring was described and field screened with a PiD. A second ring was sealed at each end with a teflon sheet, plastic cap, and non-hydrocarbon tape. The samples were labelled, sealed in waterproof bags and placed on ice pending delivery to an analytical laboratory. 'Between sampling events, the sampler and rings were washed with non-phosphate detergent and rinsed successively with tap and distilled water. All of the borings were back-filled with sand-cement grout upon completion of work. Drill cuttings were stored temporarily on site in appropriately labeled drums. The cuttings were disposed of at Laidlaw's Buttonwillow facility on November 5 (Appendix B). Characterization Report ARCO Products Company November 11, 1991 5.2 Analytical ResUlts The deepest sample from each boring was submitted for laboratory analysis. Selected additional samples were also analyzed to define hydrocarbon concentrations within the contaminant plume. The samples were sent via overnight courier to state-certified GTEL Environmental Laboratories in Torrance, California (Cert.#723). The samples were transported following standard chain-of-Custody'procedures and were analyzed for TPHG and BTEX using EPA methods 8015 and 8020. TPHG and benzene concentrations in samples analyzed from the site range from < 10 to 2,700 mg/kg and <0.005 to 3.2 mg/kg, respectively (Table 3, Appendix C). The maximum values of TPHG and benzene were detected in samples from boring B9 at depths of 25 and 40 feet, respectively (Figures 7 and 8). TPHG was not detected in samples collected from below 35 feet. Furthermore, BTEX and TPHG were not detected in samples from borings B5 through B8 (Figure 9). 6.0 RISK ANALYSIS The state Leaking Underground Fuel Tank Field Manual (LUFT 1988) estab!ishes three'methods to determine if soil contamination can be left in place without threatening groundwater. These methods vary greatly in their specificity and complexity. The most generic and least complex is a leaching Table 3. Anal tical results (in mg/kg) of soil sam ~les from borings, 9/11/91-9/12/91. Sample No. Benzene Toluene Ethyl- Xylenes TPHG benzene B5-35 < 0.005 < 0.005 < 0.005 < 0.015 < 10 B6-15 < 0.005 < 0.005 · < 0.005 < 0.015 < 10 B6-30 <0.005 <0.005 <0.005 <0.015 < 10 B7-25 <0.005 <0.005 <0.005 <0.015 < 10 B8-20 <0.005 <0.005 <0.005 <0.015 < 10 B9-25 0.53 4.1 8.6 150 2700 B9-40 3.2 12 1.4 8.2 ~40 B9-65 0.027 0.10 0.017 0.14 < i0 B 10-45 0.089 0.56 0.11 0.77 < 10 B10-75 0.022 0.10 0.014 0.11 <10 B10-80 0.11 0.19 0.021 0.17 <10 Characterization Report ARCO Products Company November 1.1, 1991 5 GROUNDWATER TECHNOLOGY potential analysis which considers four site characteristics: depth to groundwater, subsurface fractures, precipitation, and the presence of man-made conduits. Based on conditions present at the site, contamination levels exceed those determined as acceptable by the leaching potential analysis. (Table 4). As stated in the LUFT Manual, the leaching potential analysis provides "a simplified way to assess the possible threat to ground water from contaminated soils. Alternative cleanup levels, based on additional site specific analysis, would supersede the initial allowable levels" (LUFT, 1988, p 21). The second method, general risk appraisal, uses a "simulated environmental system that adapts two computer models to estimate the concentration of BTX&E that can be left in place ... without risking ground water pollution" (LUFT, 1988, p 23). These models are SESOIL (B°nazountas and Wagner, 1984) which addresses contaminant transport in the unsaturated zone, and AT123D (Yeh, 1981) which addresses contaminant transport in the saturated zone. These models have been used to create a method to determine the concentrations of BTEX which can be left in place Without threatening groundwater. Work sheets and tables are presented in the LUFT Manual which can be utilized without actually modeling conditions at each specific site. However, this method was developed for sites which meet specific applicability criteria. Conditions present at the ARCO site exceed those criteria (Table 5). At sites where the general risk appraisal is not appropriate, the LUFT manual suggests substituting "a more detailed site-specific analysis, employing the two models (SESOIL and AT123D) used in the general risk appraisal" (LUFT, 1988, p 24). A more detailed analysis of site conditions using the SESOIL model is presented below. 6.1 SESOIL Modeling SESOIL is a mathematical model that simulates long-term environmental fate of pollutants in the unsaturated zone. The model describes water transport, sediment transport, pollutant fate, pollutant migration to groundwater, and soil quality within as many as four user-specified compartments representing different soil t~/pes. 6.1.1 Model Input Parameters A site-specific risk analysis of the potential for BTEX to impact groundwater at the ARCO site requires the determination of several input parameters. Climatologic and chemical parameters are compiled from well-established databases (Appendix D). Several physical parameters require some interpretation. These parameters, and the basis of their determination, are described below. Characterization Report ARCO Products Company November 11, 1991 6 [~[~['~] GROUNDWATER [~[~[~ TECHNOLOGY Table 4. Leaching potential analysis for gasoline using total petroleum hydrocarbons and BTEX. Modified from the LUFT Manual (1988, p 27). Score 10 Score 9 Score 5 Site Feature Score Pts. if Score . Pts. if Score Pts. if Condition Condition Condition is Met is Met is Met Minimum depth to water 10 >100 51 - 100 25 - 50* from the soil sample. Fractures in subsurface (applies to foothills or 10 None Unknown Present mountain areas). Average annual precipitation 10 < 10 10 -25 26 - 40** (inches). Man-made conduits which increase vertical migration of 10 None Unknown Present leachate. Unique site features: recharge area, coarse soil, None 9 At Least More Than nearby wells, etc. One One Column Totals - Total Points 40 + 9 + 0 = 49 Range of Total Points 49 Pts. or More 41 - 48 Pts. 40 Pts. or Less Maximum Allowable BTX&E Levels (ppm) 1/50/50/50 .3/.3/1/1 N/A*** Maximum Allowable TPH Levels (ppm) 1,000 100 lO * If depth is greater than 5 feet but less than 25 feet, score 0 points. If depth is 5 feet or less, this table should not be used. ** If depth is over 40 inches, score 0 points. *** Levels of BTX&E are not applicable toTPH concentration of 10 ppm. 6.1.1.1 Sediment Characteristics Sediment characteristics required as input for SESOIL modeling include bulk density, effective porosity, disconnectedness, organic-carbon content, and intrinsic permeability. Bulk density and effective porosity are estimated to be 1.35 g/cm3 and 30% respectively for this simulation. These values are typical of the sediments encountered during this assessment. The disconnectedness index relates intrinsic permeability to soil moisture. Disconnectedness is defined as: c = A [In(k)]/AIn(so)] Characterization Report ARCO Products Company November 11, 1991 Table 5. General Risk Appraisal applicability checklist. GENERAL RISK APPRAISAL FOR PROTECTION OF WATER QUALITY: YES NO APPLICABILITY CHECKLIST 1. Is the site in a mountainous area (shaded moist areas and/or areas X with rocky subsurface conditions)? 2. Is the site in an area which could collect surface runoff or collect or X intercept water from a source other than natural precipitation? 3. Does the areal extent of soil contamination exceed 100 m27 X 4. Do the concentrations of fuel constituents in any soil samples exceed the following amounts: benzene -- 100 ppm, toluene -- 80 ppm, X xylene -- 40 ppm, ethylbenzene -- 40.ppm? 5. Are their any records or evidence of man-made or natural objects which could provide a conduit for vertical migration of leachate? X 6. Do any boring or excavation logs show the presence of fractures, joints or faults that could act as a conduit for vertical migration of X leachate? 7. Do any boring logs show that contaminated soil could be within 5 feet of highest groundwater?. X 8. Do any boring logs show the presence of a layer of material, 5 feet thick or more, which is more than 75% sand and/or gravel? X * "If any of the questions on the checklist cannot be answered no, then the results of the g appraisal may be less than valid." (LUFT, 1988, p 38). where c = soil disconnectedness index, k = intrinsic permeability, and so = the long-term average soil moisture concentratiOn. Disconnectedness in sediment typically ranges from 3 to 12, and can be varied to calibrate the model to reflect expected moisture concentrations. A disconnectedness index of 7.5 is used in the simulation. Hydrocarbons adsorb to organic carbon which occurs naturally in sediments. Once adsorbed, they are essentially immobile. The percent organic carbon present in sediment at the ARCO site has been conservatively estimated to be 0.15%. Intrinsic permeability is determined by comParison of the lithologies encountered at the site with permeability data compiled in Freeze and Cherry (1979). Their data represents ranges of permeability expected for given sediments based on observed grain-size distributions. The value representing the more-permeable upper-75th percentile of their data is used. Characterization Report ARCO Products Company November 11, 1991 8 GROUNDWATER TECHNOLOGY 6.1.1.2 Contaminant Application A partial list of the application parameters required for the SESOIL simulation includes the number of soil layers present in the system and their respective thicknesses, the area impacted by the contaminant, and the total mass of contaminant in each layer. Four soil layers are simulated for this site (Figure 10). These layers are segregated based on general sediment characteristics. The bottommost layer is assumed to be a well-sorted, permeable sand. Concentrations used in estimating total hydrocarbons in place are determined using the 95% upper confidence level (95% UCL) as described by Witte (1989) at each 5-foot depth horizon where more than one data point is available. The level is derived using the following equation: 95%UCL=x+ (1.96*s/n°'5) where x = mean, s = standard deviation, and n = the number of samples analyzed (Appendix E). Total hydrocarbons in place are calculated by multiplying the 95% UCL times the mass of soil in each 5-foot subcompartment of soil. At horizons with only one data point, that value is assumed to represent hydrocarbon concentrations at that depth. Note that the concentration used for each layer is the most conservative value reported or calculated. For example, in cases where samples at depth yield higher concentration than data from shallower subcompartments, the higher concentration is substituted (Appendix E). For this simulation, the application area for contaminants is approximated as shown on Figure 11. Pollutant load ~g/cm2) is calculated by dividing the total mass of hydrocarbons per soil compartment by the application area (Appendix E). 6.1.1.3 Conservatism Input parameters are chosen to represent conservative site conditions. The simulation is calibrated such that all rainfall infiltrates the soil column and evapotranspiration is minimized. Alternately, the simulation is calibrated such that no pollutant is lost to the atmosphere through volatilization. In effect, the site is considered uncapped with respect to precipitation, but completely sealed with respect to pollutant loss to the atmosphere. Using the 95% UCL helps ensure that contaminant concentrations are estimated at their highest level. Additionally, this concentration is used to characterize the entire lateral extent of each compartment simulated, disregarding lateral decreases in pollutant concentrations. Biodegradation rates have also been set at zero. Therefore, the effect of natural biologic degradation in reducing pollutant concentrations is also not considered in this simulation. Characterization Report ARCO Products Company November 11, 1991 C.OUNDWATE. 6.1.2 SESOIL Output SESOIL generates data for each month of each year simulated. Output includes information about the hydrologic cycle (e.g. precipitation, evapotranspiration, etc.) and the distribution of pollutant in the soil column (e.g. concentration and depth). The period simulated for this analysis is the maximum SE$OIL allows -- 99 years. The transport rate and. maximum depth that each pollutant reaches at the .end of the 99 year period is listed in Table 6. None of the chemicals modeled impact groundwater within the simulation period. Condensed SESOIL output files are presented in Appendix F. Complete output files stored on diskettes are also attached (Appendix G). 7.0 FEASIBILITY STUDY Three remedial action options are considered for this site. They include no action, soil venting, and excavation. Details of these options are discussed below. Table 6. Maximum pollutant depth and transport rates for SESOIL simulation. Year Maximum Pollutant Depth in Soil (fi) Simulated Benzene Toluene I Ethylbenzene I Xylenes 1 80 80 80 80 10 86 83 81 81 20 92 85 82 82 30 99 88 83 84 40 105 91 83 85 50 112 94 84 86 60 118 96 85 87 70 128 99 86 88 80 139 102 87 89 90 149 104 88 91 99 159 107 89 92 Transport Rate (ff/yr) 1 0.28 0.09 0.12 Characterization Report ARCO Products Company November 11, 1991 10 GROUNDWATER TECHNOLOGY · 7.1 No Action The no action alternative would involve maintaining the asphalt and concrete cap overlying the areas impacted with hydrocarbons. No further action would be undertaken to mitigate soil contamination. An asphalt cap will prevent human contact with the hydrocarbons and prevent infiltration of rainwater. The SESOIL simulation indicates that under conservative conditions, BTEX will not impact groundwater. The installation of double-walled tanks and piping also helps ensure that no additional hydrocarbons will be introduced into the soil system. With no further addition of hydrocarbons to the plume, natural degradation and dispersion will eventually eliminate soil impaction. No further costs would be incUrred with this option, and there will not be any associated worker health and safety risks. 7.2 Soil Venting Soil venting would entail the installation of vapor extraction wells and equipment and removing volatile organic compounds (VOC's) from soil in an induced vapor-stream. The contaminated vapor stream would be treated with abatement equipment to remove VOC's prior to venting to the atmosphere under an APCD permit. Necessary equipment would include a vapor extraction point(s), an explOsion-proof regenerative blower, vapor-abatement equipment (cat-ox, therm-ox, or lC engine) and associated plumbing. The estimated time to complete this option would be one year, with costs ranging from .r...l~l~.,~ $60,000 to $100 alth and safety risks associated with this option are the dangers inherent in L,~ '~'eavy equipment operation and the possible creation of explosive atmospheres. ~ , 7.3 Excavation Excavation would entail destruction of large portions of the asphalt and concrete slabs and the dispenser island which overlies the plume and physically removing impacted soil. The excavated soil would be disposed of in a Class II landfill. The total volume of impacted soil, as indicated by data from this assessment, is estimated to be 1200 yds3. The estimated time to complete this option would be four weeks, with costs ranging from $150,000 to $200,000. Possible health and safety risks associated with this option include worker and public exposure to impacted soil, the volatilization of hydrocarbons during excavation activities, and the dangers inherent in heavy equipment operation. 'Surface structures at the site will also be damaged by excavation. 8.0 REMEDIAL ACTION PLAN The. preferred remedial action plan at this site is no action. The buffer zone between impacted soil and groundwater is approximately 80 feet, and the SESOIL simulation indicates that BTEX will not reach groundwater during the 99 year simulation period. New double-walled storage tanks have been installed Characterization Report ARCO Products Company November 11, 1991 11 [~[~]~ GROUNDWATER [~[~][~] TECHNOLOGY at the facility, thus eliminating the source of contamination in the area of the former tanks. Soil venting is a proven technology which will remediate the plume in a shorter time frame than natural degradation. However, implementation costs are high. The excavation alternative is not considered feasible due to high costs, worker safety concerns, and damage to surface structures. Characterization Report ARCO Products Company November 11, 1991 12 GROUNDWATER TECHNOLOGY 9.0 REFERENCES Bonazountas, M., and J. Wagner, 1984, SESOIL: a seasonal soil compartment model: A.D. Little Inc., for U.S. EPA contract #68-01-6271, Cambridge, MA. California Division of Mines and Geology, 1975, Geologic Map of California, Bakersfield sheet. Freeze, R.A., and J.A. Cherry, 1979, Groundwater: Prentice-Hall, Inc., Englewood Cliffs, NJ. GSC (General Sciences Corporation), 1990, Riskpro--environmental pollution modeling system: Laurel, MD. Howard, P.H., 1990, Handbook of environmental fate and exposure data for organic chemicals, v. 1 & 2: Lewis Publishers, Chelsea, MI. KCWA (Kern County Water Agency), 1990, 1989 Report on water conditions - improvement district no. 4. NOAA (National Oceanic and Atmospheric Administration), 1989, Local climatological data, annual summary with comparative data for Bakersfield, California: ISSN #0198-696, Ashville, NC. Witte, R., 1989, Statistics, third edition: Holt, Reinhart and Winston, Inc., the Dryden Press, NY. Yeh, G.T., 1981, AT123D: analytical transient one-, two-, ahd three-dimensional simulation of waste transport in the aquifer system: Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN. Characterizat(on Report ARCO Products Company November 11, 1991 13 GROUNDWATER TECHNOLOGY FIGURES [~[~ GROUNDWATER [~][~][~ TECHNOLOGY 8,~,~.~ ,. :~ ,~~ o~ ~'~ ~ %?- wy..s ~ = E~c-. w.~ ~ .~- d E -~ I ~.1~ D~.: '1~ x~x ~--~a~E f~ ~6~xJ~l]L~.rk~t.~..~ll' ~ ~E MING ~ L~K ~AVENUI ~.~,,.;,,6.~1[~¢ ~tna ~,.[~];'l~; u' ~C~' ~" ;~~ '~ ~~!j~ ~A: ~"~. I -~ I~.i.~ ...... .~.~i~ ~ ~ : ' "~ '~ ~ ' ~ c ~ ~ ~ ~ d~.. ~ · ~ = ' ~ t ~ ~0 ~,--~ ~ ~ ~ . p; ~-~to~ ,~nN~[ .... Mar'al "an ' 't g~ Los ~ h WHITEx~-- ~ I I. ;¢, &NE ,¢ Grimm Park .I ~' ~ % % =l T~toml ~a~.~ ~r.~ i ~)J' ~~ I ,3 ~'x ~~u~,~o 7 ~_ I .~ ~~~" ~'. 0 ~ ~/ L/.//~ / ~ · ~ I ~ ,'~:~;~:' ".'-,,.~, ~.- i~z2./~,,*-' - '~,."~,~ ~ U~ 5*eenn ~ only 4. M~nl~t ~. ~ w~dme e~/ MiIo,~ilo iven~e~ e,~ = ~ ~' ~M'rla ' -~/'"'"~':"'i ' ' ~,,-~1 /~'~, d ~ ~ ~ I x ~, ..... ~B~ [~.¢"~, .~1.~,, N Jfl~ ~ 215 ;) site, ARCO SS ¢621 8 350 0607 SZTE LOC, 4203 Ming Avenue B~kersfield, Cdliforni~ NAP TYPE~ LocQtion Index SCALE: DRA~N gY, DATE, APPRDVED ~Y, DATE, MH 2/91 JDP 2/91 ~ REV REV]S]BN ~ATE 3Y 1/B 0 1/4 1/B miles Source: Hoven & Co. Inc. [FZGURE ] MING A VENUE ! ! Sidewalk Planter 7 ! BIO Former Tank Location New Tank ..-... Location % _ Buildin LEGEND N Boring Location Boring Location Showing Bottom- hole Deviation SCALE, 40' 0 20' 40' jns# 022 SITE: ARCO SS #6218 50 0658 SITE LBC, Bakersfield, California MAP TYPE~ Site Map(Borin9 Loc?fion~s, DRAWN BY, DATE IAPPRDVED BY I)ATE SAB ~o/o~ I ~D~ ~o/~ REV REVISIDN DATE BY MiNG A VENUE 280 ! 1900 DI 4800 2900 LEGEND TPH@2' x/~ Sample Location SCALE~ , ~ 40' 0 PO' 40' paB "02250 S]ZE, ARCO SS #6218 | 0658 S~ZE LOC, Bakersfield, California HAP TYPE, Sample Locations JDP 6/91I JDP 6/91 REV ! REVISIDN DATE BY .. :.~ ~,'~I~.,.. C.... '~ · .':-.' :~N. :~.- -:: ~1~~'.t~~~ · .''. '%~.,;,~',, ~-I~~.. , .... '-' ~~~i1:'~:/~ ~~.~.-.;~ ...-.,. "2~ .-. ~:~:~ .. . ~ . . ..... ~-~ .....?~ ~'~~-. . · .. ', .-.:."-. s., '" ' ~ ~ - . · -.- ~ r eJ s . , · - ' ~ , ~. ~,-. ,~ ~~~:.t/.~', . . ~,. .. , ,..',~ (~'-' ='--7---: ~t~ ~ -: ' "'~"". " . . - .. ' ~ ...... ~ ~ ~, ~ .,. .' .... ~ ,~'. ,~ , . .... , , o .;' ~ , · . - :' , ,,?'-.', Oil · ~" · [ . / v~.~.~, u-~,t~.f.. '. ~,~:, ' /.- ".' f.' Legend · '. 0~; deposi~ .': ~'- B~in doposi~ J~ ~ 215 s~mASCO SS ~6218 350 OeO7 SITE LDO BokeFsfield, ColifoFnio SCALE: MAP TYPE, Sile Geology ~ ~A~N ~Y, D~TE, IAPP~OVE~ ~Y' ~ATE= ~ 0 ~ ~ MH 2/91 I JDP 2/91 Source: COMO Bokersfield Sheet FIGURE 4 ~"o'~z",~c.~,~ .\ u . I _,/ / '.-~ 2, ;"~ '~ ~ ' ~°~ Legend S[te ~epth to JO~ ~ 21 5 S~E,ARCO SS ~6218 350 0607 S~TE SCALE~ Bokersfield, Colifornio ~ HAP TYPE, Depfh fo Groundwofer 4000 0 ~000 4000 DRAWN ~Y, DATE, ~APPROVE~ BY, ~ DATE, Feet MH 2/91 I JDP~ 2/91 Source: K.C.W.A. Report, 1990 ILl-- ~ ~ '~ . ' oo Legend Groundwater ElevaUon S~TE, ARCO SS ~6218 ~50 0607 SITE LDC, SCALE: Bmkersfield, Cmlifornim ~ MAP TYPE, Groundwefer Gradient ~000 0 ~000 ~000 DRAWN BY, DATE, IAPPRDVED BY, ~ DATE, Fee~ MH 2/91 I JDP 2/91 Source: K.C.W.A. Report, 1990 I / Planter B1 TPHG= 1000 . approximate limits) 'Planter MING A VENUE Sidewalk Planter B3 B$'+' Former Tank . Location , ~. New Tank '~ /~--..~L~ocation .~.%_ ~--' _~B7 TPHG=IO00 . (approximate limits) Buildinr~ h "_'_ LEGEND Boring Location Boring Location Showing Bottom- hole Deviation SCALE, 40' 0 20' 40' # 022 SITE, ARCO SS #6218 ~a~ 0658 SITE LDC, Bokersfield, Colifornio MAP TYPE: Cross-Section Index ond TPHG Contours DRA~/N BY, DATE, IAPPROVEI) I~Y, DATE, SAB 10/91I JDP 10/91 REV REVISION DATE BY A 10'-- 15'-- 20 - 25 - 30 - 35 -- 40 -- 45 - 50 - 55 - 60 - 65 - 70 -- 80 Dis~penser Islands / BIO B9 I I I I 3.2 clayey silt clayey silt 0.089 <10 sand ~ sand gravelly sand . x'x~_ 0.027 gravelly son~ <10 silty sand Legend sand 0.022 Scale 10' 0 5' 10' <10 0.11 <10 sand Stratigraphic Contact <0.005 benzene <10 - TPHG A~ 5 - 10 15 20 25 30 40' 45' 50' 55' 60' - 65' - 70' - 75' 80' IJnB tt 022 SITE~ ARCO SS -//6218 ,.50 06,.58 SITE LBC~ Bokersfield, Colifornio DESCRIPTIBN, Cross-Section A DRAWN BY, I DATE, APPRDVED BY, ])ATE, SABI lO/gl dDP lO/gl 10'-- 15'-- 20'-- 25'-- 30'-- ~5 Di~nser Islands B$ B5 % B6 sand ~ 2900 4800 - <0 0 silly sand 0 10 ~ I~HG= 1000 / <o.oos - send ~ (epproximefe limits) ~-~ <0.~05 % send -~ ~ ~ /sand <2.995 ~ <0.005 <10 - 5' --10' --15' -- 20' --25' --50' 55 Legend Scale 10 0 5 10 ~/~'~'~ rS~ ratig ra phic Contact <0.005 benzene <10 - TPHG JFIB # 022 S~TE, ARCO SS #6218 5O 0658 S~TE cno Bakersfield, California DE$CRIPTIFIN' Cross-Section B DRAWN BY: DATE: ~,PPRDVED BY, SAB JDP IFIGURE 9 [~ ?[c%u.".~¢~yER Dis.penser Islands A BIO B9 ~ ~' i i '~' Soil Layer 1 To 120 Feei' I 10' 15' 20' 25' 50' ,35' 40' 45' 50' 55' 60' 65' 70' 75' 80' Soil Loyer 4 Lege nd Extends From 120' lo 160" Scale 10' 0 5' 10' SITE, ARCO SS #6218 10' 15' 20' 25' ,30' .35' 40' 45' 50' 55' 60' 65' 70' 75' 80' IJOB # 022 50 0658 SITE LOC, Bokersfield, Colifornio ~ESCRIPTIDN, Soil Comportments ])RA~/N ]~Y, ~)ATE, APPRDVE]) BY, SAB dDP IFIGU'RE 1 0 ! ! Former Tank Locations / Pollutont Appli¢ofion Areo Buildinr~ LEGEND SCALE, 40' 0 20' 40' JaS fl 022 S~TE, ARCO SS #6218 50 0658 S~TELnO,Bokersfieid, Colifornio MAP T~PE, Applicotion Areo ])RAIN BY, I)ATE, IAPPRDVEI) BY, ])ATE, SAB 10/91I JDP 10/91 REV I REVI't IBN I)ATE APPENDIX A Lithologic Logs ~[~ GROUNDWATER TECHNOLOGY Log Legend Lifhology Symbols* Unified Soil Construction Symbols Class. Gravel Group** .~o ~ Sandy GW,GP ~ Neat Cement,Grout o~ aaa Silly GM Bentonite C::)C~ ~ Clayey Ge ~ Filter Pack ~ ~ Natural Fill Sand Cobbly sw , ~..................: ~ ~ Asphalt Paving, '"'"'""'"'"'"'"'""" Concrete '"'""'"'"'"'""""" '~ PebblySW ::::::::::::::::::::::::::::: ~ We II C a s i n g i:i:i:!:!:!:!:!:!:i:!:i:!:i:I:~:d S iHy S M Silt ~ Cobbly Sample Types .... ~ SS - Split Spoon .... Pebbly -_--_-~ ML,MH CC - Continuous Core -- Z_- ~i~ Sandy CO - Cuttings Grab ~ Clayey Fluid Levels Clay ~Cobbly Wafer Product ** --'~ Pebbly O - Gravel ~ CL,CH S - Sand M - Silt Sandy C - Clay Pt - Peat [~ Silly - Well Graded W P - Poorly Graded L - Liquid Limit < 50 H - Liquid Limit > 50 Peat Organic 0 - Organic 'Modified from Compto., 1962. ~[~El~l~(~f" Drillin / Lithologi log m mL__Jm m TECHNOLOGY Boring/Well No. B1 Project ARCO SS#6218 Owner ARCO Products Company Location Ming & Stine, Bakersfield, CA Project Number 215-350-0607 Date Drilled February 22, 1991 Surface Elevation Screen: Dia. Length Casing: Dia. Length Drilling Co. Sierra Pacific Exploration Driller J. Miles Total Depth 20 Feet Depth to Water Slot Size Type Drill Method Hollow-Stem Auger Logged By M. Hanning -~ pi ~ E Sam es . ~-~ Const. o_ o a_ o © Description / Soil Classification '~ ~ _ ® Texture, Color, Structures ~ ~_ = r~ Number ~ ~ou a_ = o - 1,1, ~:~:~:~:~:~:~:~:~:~:~:~:~SP Sand, medium to coarse grained, well ,I,I ............. sorted, subrounded, loose, dark yellowish - I,I, ::::::::::::::::::::::::::: brown dry, very permeable, no petroleum -- , I, I z:':':':':':':':':':':':':~ ' ,I,I -- I, I, 7:.:.:.:.:.:.:.:.:.:.:.:.:~ _ ,I,I :~':':':':':':':-:':':':-:-~ Sand, medium to very coarse grained, 1,1, ~......-.-.... -.-.-.-...-.- - ~ ~ 3W m oderatel y sar ted, su broun dad, loose, 10Z ~- 6 B1-10' SS 5 ~]~]~ moderate yellowish brown, dry, very - 5 ~'~?~'~ permeable, no petroleum odor. ,I,I ~:~:~:~:~:~:~:~:~:??~:~ Sand, medium to very coarse grained, - I,J, ~:~:~:~:~:~:~:~:~:~:~:~:~:S~ moderately sorted, subrounded, loose, ,I,I 7 B1-15' SS 4 ~:~:~:~:~:~:~:~:~:~:~:~:~:~ moderate yellowish brown, dry, very - , I, I 5 ~:]:~:~:~:~:~:~:~:~:~:~:~:~ permeable, no petroleum odor. - ,i,i ................ - I,I, ~:~:~:~:]:~:~:~:~:~:~:~:~:~ Sand, medium to very coarse grained, ,I,I ~;~;~5~ moderately sorted, subrounded, loose, - I,I, ~:.:.:.:.:.:.:.:.:.:.:.:.:~ moderate yellowish brown, dry, very 20Z , I, I 5 B1-20';SS 4 ~':':':':':':':':':':':':'; permeable, no petroleum odor. - 5 8 125Z Page 1 of 1 E3E]i I TECHNOLOGY Project ARCO SS#6218 Location Ming & Stine, Bakersfield, CA Date Drilled February 22, 1991 Surface Elevation Screen: Dia. Length Casing: Dia. Length Drilling Co. Sierra Pacific Exploration Driller J. Miles Drilling / Lithologic log Boring/Well No. B2 Owner ARCO Products Company Project Number 215-.350-0607 Total Depth 20 Feet Depth to Water Slot Size Type Drill Method Hollow-Stem Auger Logged By M. Hanning -~ F Samples J o ~ Const. o_ o o_ o O Description / Soil Classification ~ ~ _c: (Texture, Color, Structures) o_ = ~ Number ~ o u o - I,I,. ~:i:i:i:i:i:i:i:i:;:i:i:i:i Send, fine to medium grained, well sorted, 'l'Ji :;:!:!:!:!:!:!:!:!:!:!:;:!:SP subrounded, loose, dark yellowish brown, - I,I, :.:.:.:.:.:.:.:.:.:.:.:.:.: dry, moderately permeable, no petroleum I, I, :':':':':':':':':':':':':"' odor. 5- I,I, 5 B2-5' SE 5 - I, I, 3 ::::::::::::::::::::::::::: - ,I,1 4:.:.:.:.:.:.:.:.:.:.:.:.~ Sand, medium to coarse grained, well _ I, I, ~:.:.:.:,::,::.:,:.:-:.:.: 10-Z ~]: ~:i:i:i:i:i:i:i:i:i:i:i:i:iSP sorted, subrounded, loose, moderate ,~,~,=~2 B2-10' SS .3iiii!i!iiiii!i!i!iiiii!iiii yellowish brown, dry, very permeable, no - 3 ~!:!:!:!:!:!:!:!:!:!:!:!:!: petroleum odor. , I, I 6 :-*.i:i:i:i:i:i:i:i:i:i:i:i:i~ - I,I, ............ I,I, ~:':':':':':':':':':':':':': Sand, medium to coarse grained, well 15- 1,1, 2 B2-15' SS 3 ::::::::::::::::::::::::::: SP sorted, subrounded, loose, moderate ,I,I .............. yellowish brown, dry, very permeable, - I,t, 5 ~:i:i:i:i:i:i:i:i:i:i:i:i:i no petroleum odor. , I, l 6 ::::::::::::::::::::::::::: - ,I,I ::::::::::::::::::::::::::: Sand, medium to coarse grained, well - ,I,1 :::::::::::::::::::::::::::::: sorted, subrounded, loose, moderate ='.'.'.'.'.':.'.'.'.'.~ yellowish brown, dry, very permeable, 20- I, I, 2 B2-20' SS 5 z-:-:-:-:.:.:-:.:.:.:.:.:.: no petroleum odor. - 9 - _ 10- _ 4 25- Page 1 of 1 [-1E~I~ Drilling / Lithologic log FqFqEZ] R Boring/Well No. B3 Project ARCO SS#6218 Owner ARCO Products Company Location Ming & Stine, Bakersfield, CA Project Number 215-350-0607 Date Drilled February 22, :1991 ... Surface Elevation Screen: Dia. -- Length Casing: Dia. Length Drilling Co. Sierra Pacific Exploration Driller J. Miles Total Depth 20 Feet Depth to Water -- Slot Size -- Type Drill Method Hollow-Stem Auqer Logged By M. Hanninq ~ Well .---. o -~ pi ~ E Sam es - v Const. o_ o ~ Description / Soil Classification ~ ,~ (Texture, Color, Structures) ~ ~ ~ ~ Number ~ ~ o , I, I ~:':'.':':':':':':'?:':: - I,I, ??~:~:~:~:~:?~:~:~:~:~:~ Sand, very fine to medium grained, well ,l, }] ~:~:~:~:~:?~:~:?~:~:~:~:ISP sorted, subrounded, loose, moderate - I,I, ::::::::::::::::::::::::::: yellowish brown, dry, very permeable, no - ,I,I 1,1, :'".'"-'-'"".'.'""~ petroleum odor. ,I,J 2 B5-5' SS 5 ............. - I, l, 3 ::::::::::::::::::::::::::: , I, I~ 5 - l,i, .....-.-.....-.............. - ']~ ]. ~.:.:.:.;?;.;.:.:.:.:~ Sand, medium to coarse grained, well I,I, ::?~:~:~:~:~:~:~:~:~:~:?;Sp sorted, subrounded, loose, moderate ~ 2 B5-10' SS 3 ~:~:~:~:~:~:?~:???~ yellowish brown, dry, very permeable, no - 4 ~?~:~:~:~:~:~:~:??~: petroleum odor. , I, I: 5 ~:~:~:~:~:~:~:~:~:~:~:~:~ - 1,1, . ............ - , l, I~ z.:-:.:.:.:.:.:-:-:.:-?' I,I, ~:.:-:-:.:.:.:.:...:.::.:¢ Sand, medium to coarse grained, well - , I, I ~-:.:.:.:.:.::-:.:.:-'<. 15~ I,I, 2 BS-15'SE 4 ~SP sorted, subrounded, loose, moderate ,I,I ............... yellowish brown, dry, very permeable, no - I, I, 6 ~:~:~:~:~:~:~:~:~:~:~:~:~:~ petroleum odor. , I, I 6 ::::::::::::::::::::::::::: - I~1~ ::::::::::::::::::::::::::: Sand, medium to coarse grained, well I,I, ::::::::::::::::::::::::::::: sorted, subrounded, loose, moderate - ,I,I ~-.-.-.'.'.'.'.-.-.':.'.-, 20Z I,I,' 2 B3-20'SE 3 ~[~ yellowish brown, dry, very permeable, no petroleum odor. ~ 7 - 25~ Page 1 of 1 TECHNOLOGY Project ARCO SS#6215 Location Ming & Stine, Bakersfield, CA Date Drilled March 5, 1991 Surface Elevation Screen: Dia. Length Casing: Dia. Length Drilling Co. Sierra Pacific Exploration Driller J. Miles Drilling / Lithologic log Boring/Well No. B4 Owner ARCO Products Company Project Number 215-350-0607 Total Depth 20 Feet Depth to Water Slot Size Type Drill Method Hollow-Stem Auger Logged By M. Hanning '-" Well ~-~ o ._1 ~ Const. F Samples ~ ~ ._o ~ Description / Soil Classification -~ _c (Texture, Color, Structures) ~ :=_ c3 Number ~- ~ ~- '- · -- ~ 0 0 0 ,I,I :-.-.-.:..........-..: -~ Sand, very fine to fine grained, well sorted I,I, - ~]: i!i!i!i!i!i!i!i!i!i!i!i!i!iSF ............ subrounded, soft, moderate yellowish - i!!!!!i!!i!i!!!!!!!!!!!!!!i brown, dry, moderately permeable, no - , I, I ::::::::::::::::::::::::::: petroleum odor. 5- 1, I, B4-5' SS 5 ::::::::::::::::::::::::::: _ 5 :.:.:.:.:.:.:.:.:.:.:.:.:.:; Sand, medium to coarse grained, well - t/.'.?Z :i:i:i:i:i:i:i:i:i:i:i:i:i:]:~SF sorted, subrounded, loose, moderate 0Z~ B4-10' SS 3 ii!i!i!iiiii!i!!!!!!!!!!!i! yellowish brown, dry, very permeable, 1 - .~-zx.: 4 ::::::::::::::::::::::::::: no petroleum odor. 5 ~-:':':':':':':':': :.:':.:~ / Ox' :...........:.......,.....:: ~ ~_z' :v v.'.' :.v.v.v.: -- ~, ~, :-..'.:.v.v.'.'.':.':: ~+,zo~ ::::::::::::::::::::::::::: .............. Sand, medium to very coarse grained, ;, Z ' 15- ~ B4-15'SS 3 ::::::::::::::::::::::::::::: moderately sorted, subrounded, loose, ;.-...-.-.....-...........: moderate yellowish brown, dry, very - ~ 5 ~:i:i:i:i:i:i:i:i:i:i:i:i:~ permeable, no petroleum odor. - ~!i!!!!!!!!!!!!!!!!!!!!!!!~ Sand, medium to very coarse grained, - ~i!i!i!i!i!i!i!i!i!i!i!iii~S~ moderately sorted, subrounded, loose, 20Z B4-20' SS 6 z.:.:.:.:.:.:.:.:.:.:.:.:.: moderate yellowish brown, dry, very - 6- permeable, no petroleum odor. __ 7 - 252 Page 1 of 1 E3E]i I L__.J~.~JL__J TECHNOLOGY Project ARCO SS #6218 Location Ming & Stine, Bakersfield, CA Date Drilled September 11, 1991 Surface Elevation Screen: Dia. Length Casing: Dia. Length Drilling Co. Consolidated Testing Driller A. Avila Drilling / Lithologic Icg Boring/Well No. B5 Owner ARCO Products Company Project Number 022,500658 Total Depth 35 Feet Depth to Water Slot Size Type Drill Method Hollow-Stem Auger Logged By S. Bark ? Well .._.. c~ E Samples __u°~ v Const. o_ o _c ~ ._o i~ Description / Soil Classification o_ ~ -- ~_ c~ ~ Texture, Color, Structures ~ ~_ ~_ c3 Number o o o '-- ~' ~- Cf) ,I,I ............. '~ 3" Asphaltic concrete, 5" aggregate bose. - , I, I 3:::::::~:::::::~ I,I, ':':':':':':':':':'::':':~ Sand, fine to coarse grained, silty, well - ~1,1, I [tT~':':':'~¥:::bSM graded, subrounded, loose, dark brown, 5- il,l,I80 B5-5' SS ::::::::::::::--7:::::::: moist, PID readings appear erroneously - , I, I, 2_.4, ::::::::::::::::::::::::: high, no odor. ii, I, I ::::::::::::::::::::::::: - ,1,1 ========================== Sand, fine to coarse grained, silty, well 102 1,1, ~':':':-:-:-:-:':':':':cSIvgraded, subrounded, medium dense, ,I,I 50 B5-10'SS ~.:.:.:.~::::::.~ - I,I, 12. ;7.i. ii.!.i.:.:.:.:.:.:.![medium brown, moist, no odor. II ~-:.:.:-:-:.:.:.:.:.:.: :.~ .............. - ~:!:!:!:!:!:!:!:!:!:!:!:!:~Sand, fine to coarse grained, well graded, ,~! ~!i!i!iii!i!i!i!iiiiiiiiiiSw subrounded, loose, light brown, damp, no 15- I, I, I 40 B5-15' SSi6 .............. ~:!:!:!:!:!:!:!:!:!:!:!:i:~ odor. - , I, I, 6. 7 ::::::::::::::::::::::::::: - ,l,I ::::::::::::::::::::::::::: Sand, fine to medium grained, poorly 20- I,t, 70 SS 3 ~:i:i:i:!:i:i:!:i:i:i:i:i~v~ graded, subrounded, loose, medium brown, ,I, I :'"'"'-"'-':-':-'-'-: damp, sample not recovered, no odor. - I,I,8* 5 ::::::::::::::::::::::::::: - ,I,I ::::::::::::::::::::::::::: Sand, fine to coarse grained, well graded, 25- ,Iiii, 40 B5-25'SS 7 i!!!i!!!i!i!i!i!!!i!!!!!!~SW subrounded, medium dense, medium - I,I, 6* 23~i!i!iiiiiiiiiiiii!i!!!i!~ brown, damp, no odor. , I, t 25 ~:i:i:i:i:i:i:i:i:i:i:i:ii~ - I,I, - ............. - ,I,I :::::::::::::::::::::::::::: Sand, fine grained, silty, poorly graded, I.I, ~.]:i:i:i.i.i.i..:.i:i:i:?i~M medium dense, medium brown, damp, no - , I, I .~:':':':':':':':':':':':':- odor. Page 1 of 2 I--II--II il Drilling / Lithologic log Project ARCO SS #6218 Boring/Well No. B5 ,--, Well ~, o -~ E Samples J -~- Const. a_ ~_ .o_ ~ Description / Soil Classification a_ ~-~ ~ ~ (Texture, Color, Structures) o_ = ~ Number ~, o o I,I, ~:::::::~::::::'~. Sand, fine grained, silty, poorly graded, 50- , I, I0 BS-50'!SS1 4 :':':':':':':':':':':':':'; _[~ 19~!:!:i:i~!:!:!:tSlv medium dense, medium brown, damp, no - - ~, -.-...-...................... odor. _ :~ ~o~ 21 ~':Z!:!:!:i'!'!'!':'!:!:!:~ - ~fi,~ ~iiiiiiiiiiiiiiiiiiiiiiiiii .............. Sand, fine to coarse groined, well graded, _ I,I :::::::::::::::::::::::::::: subrounded, medium dense, light brown, 35- ~ 0 B5-55'S~ 11 '"'"'""'"'"'""'"' damp, no odor. _ 23 ~ 28- * Bakersfield Fire Deportment PID - Boring plunges 60° due west. 4O2 ¢5Z 50- 55- 60Z Page 2 of 2 l--I[][il Drilling / Lithologic Icg Boring/Well No. B6 Project ARCO SS #6218 Owner ARCO Products Company Location Ming & Stine, Bakersfield, CA Project Number 022500658 Date Drilled September 11, 1991 Total Depth 30 Feet Surface Elevation Screen: Dia. Length Casing: Dia. Length Drilling Co. Consolidated Testing Driller A. Avila Depth to Water Slot Size -- Type Drill Method Hollow-Stem Auger Logged By S. Bark ~-~ Well ~-~ o '"' pi '*- E Sam es . v Const. ~ ~_ o ~ Description / Soil Classification = ( ) ~ e -- e o_ .--- Texture, Color, Structures ~- = ~ Number ~ o o o I,I, - ............. 3" Asphaltic concrete, 3" aggregate base. I, I, '¢:::::::~:::::::~ ,I,I :.%!:!:!:!~.~;Slv Sand, fine grained, silty, poorly graded, - I,I, ~:::::::~:::::¥ subrounded, loose, dark brown, damp, ,I,I =....:...-.-............~ no odor, no sample recovery. 5- I, I, SS 6 - , I, I 7 ~:.:.:.:.:.:.:.:.:.:.:.:.:~ I, I, 9 ~;-:;:;:;::.;.:.;.;-~;::::::'~ - , I, I :::::::::::::::::::::::: 10- I,I O' :::::::::::::::::::::::: Sand, fine to medium grained, poorly ,1, 0 B6-1 SE 9 ::::::::::::::::::::::::::: - I,I 3~iii!i!i!!!i!i!i!i!i!!!!!~Sp graded, subrounded, loose, light grey, ...............damp, no odor. , I, 4 ::::::::::::::::::::::::::~: _ ii!!!i!i!i!iii!iiiii!iii!!~ Sand, very fine to coarse grained, well ~~! 5' ::':':':':':':':':':':':':~3W graded, subrounded, loose, light ,15- ~o- 20 B6-1 SS l O ~]i!i!i!i!i!i!i!!!!!i? damp, sweet, moderate to strong grey, - 11 ::::::::::::::::::::::::::: petroleum odor. (PID battery Iow) , I, I 1 2 i:i:i:i:i:i:i:i:i:!:i:!:i:i - ,I,I ~i:i:i:i:i:i:i:i:i:i:!:i:ii Sand, fine to coarse groined, well graded, 20- I, I, B6_20,19S10 iiiiiiiiiiiiii!iiiiiiiiiii ~W subrounded, medium dense, light grey, ,I,I :'"'"'"'"'"-'"-"'" damp, weak to moderate petroleum odor, - I, I, 10 ::::::::::::::::::::::::::: .............. PID ~noperoble. , I, I 2C ~:i:i:i:i:i:i:i:i:i:i:i:i: - ,i,i, .............:............. - 1,1,1 i:i:i:i:i:!:!:i:!:i:i:i:i(iSp Sand, fine to medium grained, poorly ,I,I, ' ............ graded, subrounded, medium dense, light 25- I, I, I B 6- 25'IS S 15 ~.i:i:!:!:!:!:!:!:!:!:!:!:!:~ - , I, t, 20~:!:!:!:!:!:!:!:!:!:!:!:!:; grey, dry, no odor. - 1,1,1 :::::::::::::::::::::::::: Sand, fine to medium grained, poorly ,I,I, ~:':':':':':':':':':':':':~SF graded, subrounded, medium dense, -1 I, I, ~:!:!:!:i:!:!:!:i:!:!:!:!~ medium grey, damp, no odor. Page 1 of 2 fi-E][] Drilling / Lithologic log F-II i-I R Project ARCO SS #6218 Boring/Well No. B6 .--- Well --- o ~ E Samples J ~v Const. a. __o o_ .o_ o Description / Soil Classification e (Texture, Color, Structures) '~ ne ~ ~ Number ~ ~oo~ "=o · - ,, ~_ ~iII ¥:::::::::::::::::::::::: Sand, fine to medium groined, poorly 30-, : i ,B6-30'SS15'"'"'""'"'"":"'"~ graded, subrounded, medium dense, _~ 21- medium grey, damp, no odor. 27- - Boring plunges 65° due west. 35-- - 4O- 45-i 50f Page 2 of 2 i--Il--iii Drilling / Lithologic log j~JJ~ J----J GRrlUNI~/ATr'R L_Jt__...JI._~ TFCHNOLDGY Boring/Well No. 87 Project ARCO SS #6218 Owner ARCO Products Company Location Ming & Stine, Bakersfield, CA Project Number 022500658 Date Drilled September 11, 1991 Total Depth 25 Feet Surface Elevation -- Depth to Water -- Screen: Dia. -- Length Slot Size -- Casing: Dia. Length Type Drilling Co. Consolidated Testing Drill Method Hollow-Stem Auger Driller A. Avila Logged By S. Bark -~ Well ~ o ~ E Samples J -~- Const. c~ o_ .o_ o Description / Soil Classification ~: '--' _c: (T ) ~o_ ~ _ ~ ~ o_ = exture, Color, Structures o_ = ~ Number ~ o o o , I, 1 '~';~---~ 3"Asphaltic concrete, ,5" aggregate base. - ,l, I, ~:::::::~::::::::: I, I, I - I,l,I ?:.:.:.~.:.:.:.z Send, fine grained, silty, poorly graded, I.I, ~!:i:i:i'i'i'i~!:i:!:!isM loose, medium brown, damp, no odor. I.I. 7. B7-5' SS 6 5 - I.l.I - 1, I, 6 ,:.:.:.:.:.:.:.:::~ , I, I 1 0 ::::::::::::::::::::::::::: I,I, ;:':':':':':':':':':':':':~ ............. Sand, fine to medium grained, poorly 10- l ili10. B7-10' SS 5 ~:i:!:!:!:!:!:!:!:!:!:!:i:~SP graded, subrounded, loose, medium brown, ~ '' 8 ~:i:!:!:!:!:i:!:i:i:i:!:i:~ dry, no odor. _ ~_ 12 ~i:!:i:i:i:i:i:i:i:i:i:i:~ _ o ~: ::::::::::::::::::::::::::: ,I,I ::::::::::::::::::::::::::: Sand, very fine to fine grained, poorly - I,I, ~:.:.:.:.:.:.:.:.:.:.:.:~ graded, subrounded, loose, medium grey, ,I,1 8* B7-15' SS 6 ::::::::::::::::::::::::::::: dry, no odor. 152 I,I, - I, 1 7 ~:i:i:i:i:i:i:i:i:i:i:i:i:~ 1, I, 13 ~:i:i:i:i:i:i:i:i:i:!:i:!~ I,I ;:':':':':':':':':'::':':4 Sand, fine to coarse grained, well graded, 20-' I,I, 6* B7_20, SS13~::::::::::::::::::::::::~W subrounded, medium dense, light grey, ,I,1 .............. damp, minor fine gravel, no odor. - I, I, 17 ~:i:i:i:i:i:i:}:i:i:i:i:i:~ , I, I 26 ~:i:i:i:i:i:i:i:i:i:i:i:i: - ,I, ~:i:i:i:i:i:i:i:i:i:i:i:i~ Sand, fine to medium grained, poorly I,I ::::::::::::::::::::::::::::: graded, subrounded, medium dense, light 25- ,I,I - B7-25'SS10'"'"'"'"'"'"'"'""'"'grey, damp, no odor, PID inoperable. _ 12 15 · Bakersfield Fire Department PID (~B~oring plunges 65° due west.~ Page 1 of 1 EZ]I] Dril in / Lithologic log 1-11-3J g Boring/Wel No. B8 Project ARCO SS #6218 Owner ARCO Products Company Location Ming 84 Stine, Bakersfield, CA Project Number 022500658 Date Drilled September 11, 1991 Total Depth 20 Feet Surface Elevation -- Screen: Dia. Length Casing: Dia. Length Drilling Co. Consolidated Testing Driller A. Avila Depth to Water -- Slot Size Type Drill Method Hollow-Stem Auger Logged By S. Bark ~v Const. E Samples o_ .o_ o Description / Soil Classification _~ ®_ ~ ~ _c a_ .--_ (Texture, Color, Structures) e o_ = cz Number ~, o o o iiii .......... ............... 3" Asphaltic concrete, 5" aggregate ~ose. - I, I, 4 ......... ~:-:-:-:.:.:.:.:.:.:.:.:.:~ -~ 12 16- · Bakersfield Fire Department PID 25- Page 1 of 1 TECHNOLOGY Project ARCO SS #6218 Location Ming & :tine, Bakersfield, CA Date Drilled September 11, 1991 Surface Elevation Screen: Dia. Length Casing: Dia. Length Drilling Co. Consolidated Testinq Driller A. Avila Drilling / Lithologic log Boring/Well No. B9 Owner ARCO Products Company Project Number 022500658 Total Depth 65 Feet Depth to Water Slot Size Type Drill Method Hollow-Stem Auger Logged By S. Bark --. Well .--. o ~ -~ pi ~- E Sam es j ~ ~-- Const. o_ o _c ~ .o_ © Description / Soil Classification -~ ~ _c (Texture, Color, Structures) a_ = o Number ~- a- ._ --- >~ 0 0 0 ,I,I ........... 3" Asphaltic concrete, 3" aggregate bose. - I, I, Z:::::::~::::::? - , I, I ':':':':':':':':':':':.:.:~ I,I, :.-.-.'..................~ Sand, fine to medium grained, silty, well - ,I,I "_":':':':':':':':':':':':]SM graded, subrounded, medium dense, 5- I,I, 1.5 B9-5' :::::::::::::::::::::::::::: medium brown, damp, no odor. ,1,1 .............. - I, I, 17 ~:~:::::::~; ,1, I 21 ~:.:.:.:-:.:.:.:.:.:.:.:.:e - 1, I, ..-_..:::::::+x::::::: 1,1, ::::::::::::::::::::::::::: Sand, fine to coarse grained, well graded, ,t,1 I.I,i i 0.5 B9-10' SS 6 ~:i:i:i:i:i:i:i:!:i:i:!:!i~w subrounded, loose, light grey, dry, no 10- , , - ............. odor. - ], 1, 8 ::::::::::::::::::::::::::: , l, 1 14 ::::::::::::::::::::::::::: _ I~]:- !:!!!!!!i!:!!!!!!!!!!!!!!!i~ Sand, fine to medium grained, poorly 15- 0 ! 2 B9-15' SS 6 i:!:!:!:i:!:!:i:!:i:i:i:i?SP graded, subrounded, medium dense, - 13~:!:!:!:!:!:!:i:!:!:i:!:!~ medium grey, damp, .no odor. , I, I 17 ~:i:i:i:i:i:i:i:i:i:i:i:i: I,I, ' ........... - ,I,I o .............. ~:!:!:!:!:!:!:!:!:!:!:!:i:': Sand, fine to medium grained, poorly i,i, o ;'.'.'.'.'.'.'.'.'.'.-.'.~ 20- ,I,1,1 ~o Bg_20, SSiO~:!:!:!:!:!:!:!:!:!:!:!:!?Sp graded, subrounded, medium dense, - .,I,I, A 1317!:!:!:!:!:!:!:!:!:i:!:!~ medium grey, moist, strong gasoline odor. I, I, I 18 ::::::::::::::::::::::::::: - ,t,1 o ~'.'-'-'-'-'.'.'.'.'.".'* Sand, fine to medium groined, poorly 25- I, I, o x-:-:-:-:-:.:-:.:-::~ ,I,I o~ ~9-25' SS:.................-.-....:~:!:!:!:!:!:!:!:i:!:!:!:!:!:SP graded, subrounded, medium dense, light - ,IiiI A i!iiiii!i!i!i!i!i!i!i!i!i.i grey, damp, strong gasoline odor. _ 1,1,1 ...-..................:.-.- - I, I, I ::i:i:i:i:i:i:i:i:i:i:2 Page 1 of 3 []l--II-]l~[~'~fR P ri I lin g / Lit h al ag ic I o g Project ARCO SS t/6218 Boring/Wel! No. B9 v Const. Ea. Samples . o o. o ~ Description / Soil Classification ~ .~ ~: ( ~ ~ _ ~ ~ = Texture, Color, Structures) ~ = ~ ~umber ~ o ~ o 1,1,1 ::::::::::::::::::::::::::: Send, fine to coerse groined, well graded, , I, I 587 B9-50' S~ 10 ~?:~:~:~:~:~:~:~:~:~:? 30~ I I,~, 8 .............. :.:.:.:.:.:.:.:.:.:.:.:.:.:S~ subrounded, medium dense, light grey, - ,I,I .-.'.'.'.'.'.'.-.'.'.'.'.'.'.' damp, moderate gasoline odor. - I, I, 24 ~:~:~:~:~:~:~:~:~:~:~:~:~ , I, I ¥:':':':':':':':':':':"~ - I,I, ~.'.'.'.'.'.-.'.'.'.'.'.'.~ ,I,I ~:~:~:~:~:~:~:~:?~:?~:~:~ Send, fine to coarse grained, well graded, - I,I, ~?~:?~:~:~:~:~:?~:~S~ subrounded, medium dense, light grey, 35~ i~i~522~B9-35' SS ~ d~mp, weak gasoline odor. ,I,t ........................-.-.. - I, I, ::::::::::::::::::::::::::: ,I, I ~.-.'.'.'.'.'.'..'.' '.'.: - I,t, _ ~1~1 ~---- Silt, clayey (40%), medium dense, greenish ,,,, -ML grey, moist, occasional wood debris, 40Z ,1,1 ,779~B9-40'S5 6 :___ I,I, 9=-- moderate to strong gosoline odor. - ,i,i ---:- _ I,I, 12b--:_ _ ,,,,i Ii ] ~::~?:?~::~ S~nd, fine to medium groined, poorly 45E B9-45'!SS '~:::~:~:~:~:~:~:~:~:~:~:~:~SP graded, subrounded, medium dense, light ~:~]~[ brown, damp, incomplete sample, strong , I, 1 "':':-:':-:':':':':-:-:':'; - I, I, :.:.:.:.:.:.:.:.:.:.:.:.:4 , I, I ~:~:~:?~:~:~:]:~:~:~:~:~? Send, fine groined, poorly graded, - I,I, :::::::::::::::::::::::::::: subrounded, very dense, light grey, damp, 50~ i I il 222 B9-50' SS17 ~:~]~ refusal of sampler, weak gasoline odor. - , i, i 70 ::::::::::::::::::::::::::: i~ ~:~:~:~:?~:~:~:?~:?~:~ S~nd, medium to coarse groined, poorly 55~ i,i 122B9-55' SSIO~SP graded, subrounded, very dense, light I,I, ::::::::::::::::::::::::::::: brownish grey, moist, refusal of sampler, - ,I,I ::.:.:.:.:.:.:.:.:.:.:.:.~ minor coarse grovel, no odor. , I, I .~:~:;:~;:;:~:;:;::~ - I, I, ;:m:.:.:e.:.~ _ ,I,I .'.'??~'~'~'~'~'.7 ....... Sand, medium to coarse groined, fine - I,',, ~:~:.:.:e.:.~ grovel (30%), well graded, rounded, very ~0- , I,I B9-60' SS37 !~:?~:~::'~:~:~::~ ~W dense, light brown, wet, refusal of sampler, 1, I, 70,.":~::::?.:?: - , I,I ¥:::.S:::::;::¥ not enough sample for PID reading, - I,I, ~:~:.:.:e.:.~ occasional coarse gravel, feint odor. ,I,i .............. -- ~, I, :::::::::::::::::::::::::::: it, I .t.:.:.:-:-:-:.:-:.::.:.? Page 2 of 3 II--II--I[ill Drilling / Lithologic log ~lF-li--ll G~OUN~WTE~ I I~L__JJ TECHNOLOGY Project ARCO SS #6218 Boring/Well No. B9 'G' Well ~-- o ~- E Samples -- v ConsL ~_ o cz .o_ © Description / Soil Classification ~ v ~ _c (Texture, Color, Structures) ® _ X ~ = cz = c~ 4umber~ o o o J, ============================= Sand, fine grained, poorly graded, 65- _LU- 80 B9-65' S5© ""'"'"'""'""'""" o SF subrounded, very dense, medium grey, - ~- moist, faint odor. - Boring plunges 60° toward N52°E 70- 75Z 80- 85- 90Z 95E je ['~r~[-'-] iE CHNOL Project ARCO SS #6218 Locotion Ming & Stine, Bokersfield, CA Dote Drilled September 12, 1991 Surface Elevation Screen: Dia. Length Casing: Dia. Length Drilling Co. Consolidated Testing Driller A. Avila Drilling / Lithologic log Boring/Well No. BIO Owner ARCO Products Company Project Number 022500658 Total Depth 80 Feet Depth to Water -- Slot Size Type Drill Method Hollow-Stem Auger Logged By S. Bark ---._~ Well ~ o ~-c Samples j ~-- Const. o_ o z: ~ ._o ~ Description / Soil Classification ~- o_~~ c~ Number ~ o~_coo. ~ (Texture, Color, Structures) I,I .......... 5" Asphaltic concrete, .3" aggregate base. I, I, ~::::::;~::;::;:~ - 1,1, :::::::::::::::::::::::::: Sand, fine to medium grained, silty, well ,I,I ~:':':':':':':'::':':'::~Sk/ graded, subrounded, medium dense, - I, I, E:::::::~:::::::..: I 15 B10-5' medium brown, damp, no odor. 5- ,li,t · :SS15 - I, I, 17 ;:.:.:.:.:.:.:.:.:.:.:.:.:~ , I, I 21 ::::::::::::::::::::::::::: - ,I,I I,I, ::::::::::::::::::::::::::: Sand, fine to coarse grained, well graded, - ,I,I BI O- :~:i:i:i:i:i:i:i:i:i:i:i:i:-3W subrounded, loose, light grey, dry, no 102 ,Iiii, 0.5 10' SS 6 .......... ~:i:i:i:i:i:i:i:i:i:i:i:i:i. odor. - I, I, 8 ::::::::::::::::::::::::::: - I,I, - ,I,I - J:i~:l: ~'i:i:i:i:i:i:i:i:i:i:i:i:i: Sand, medium to coarse groined, poorly 15-,~ ~ 25 BIO- SS 9 ~:i:i:i:i:i:i:i:i:i:i:i:iiSp graded, subrounded, medium dense, _ ,o,:_ 15' i15~!i!i!i!i!i!i!i!i!i!!!i!ii medium grey, damp, no odor. , I, I 21 - ,I,1 ;':':':':':':':':':':':':'~ Sand, fine to coarse groined, well graded, I,I, m© BI O- ~:':':':':':':':':':':':'::S~ subrounded, medium dense, damp, strong ?0Z ~1, I, I 0o 20' SS12 ::::::::::::::::::::::::::: - I, I, ~ 17 iiiiiiiiiiiiiiiiiiiiiiiiii odor. , t, I 2~ ::::::::::::::::::::::::::: - ::::::::::::::::::::::::::: Sand, fine grained, poorly graded, 25Z 1,1,1'1'1'11' I, ~o°© B10-25,SS 10 ~-:':':':':':':':':':.:.:+~:':':':':':':':':':':':'~SF. .............. subrounded, medium dense, medium grey, - , I, I,^ 19..i!i!!!i!i!!!i!!!!!!!!!i!ii damp, strong odor. I, 1, I 29 ~:i:i:i:i:i:i:i:i:i:i:i:i~ - ,I,I, ' ............... ~ ~ ~ T':-:-:.:.:.:.:.;.:.;.:.:.2 I,I, ,,..-.-...................~ - , I, I ":':':':':':':':':':':':':'": Page 1 of ._3 E]E31 I R Drilling / Lithologic log Project ARCO SS #6218 Boring/Well No. BIO -~- Well ~ o ~ E Samples j -~ Const. o_ o ~1 Description / Soil Classification ~ ~ _c (Texture, Color, Structures) ~- = ~ Number ~ o o_ .-, o [3~0- ¢:.:.:.?:cc.:.:.:.:.:; Sand, fine to medium groined poorly 50- o© 30' SS :::::::::::::::::::::::::::: ' _ 04 ~:i:i:i:i:i:i:i:i:i:i:i:i:':.SP graded, subrounded, medium dense, light A ~i:i:i:i:i:i:i:i:i;i:i:i:i~ grey, damp, interbedded clayey silt, - ::::::::::::::::::::::::::: strong odor. - o +:.:.:.:.:.:.:.:-:.:.:.:+ Sand, fine to medium groined, poorly o B10- ~:.'.:.:.:.:.:.:.:.:.:.:.:~ 35Z o SS55::::::::::::::::::::::::::: 5P graded, subrounded, very dense, light 04 ,55' -- A 70iii!i!!!iii!i!!!i!ii!!!!i!:i brown, damp, strong odor. o [310- +_--- qL Silt, clayey (407o), very dense, medium 40Z o SS° ..... greenish grey, moist, moderate to strong - 04 40' o odor. - ~':':':'::':::::':':':':'? Sand, fine grained, poorly graded, _ ;i:i:i:i:i:i:i:i:i:i:i:i:i; subrounded, very dense, medium grey, - o ~::i:!:!:!:!:!:!:!:i:!:!:i'.E'SP damp to moist, interbedded clayey silt, 0 B 1 O- ::::::::::::::::::::::::: '45- o ::::::::::::::::::::::::::::::: strong gasoline odor. 04 45' ~!iii!i!i!i!iiiiiii!iii!i!~ Sand, fine grained, poorly graded, - [310- ~iiiiiiiiiiiiiiiiiiiiiiii~SP subrounded, very dense, medium grey, 50- 315 50' ::::::::::::::::::::::::::::::: moist, weak gasoline odor. __ ~-~....0...,.~.....~ ~:~i:i:i:~!:!~ Sand, medium to coarse grained, fine 55-- BIO- SE 40 ~:::::~;::::2::::'¢::::::::::::::::::::::::C :W gravel, well graded, subrounded, very ~:.a:.:.:0.:.~ dense, medium brown, moist, minor 55' 50~.:.:.:.:.:.:-:.:.:.:.:.:.~ coarse gravel, not enough sample for "'""~"'"~'"'"' PID, Bakersfield Fire Department PID - -- - ~i 200, faint odor. - '~:a:.:.:0:.:.~rSand, medium to coarse grained, fine to 30- I126 B10 '.'.'.'.'.'.'-'.'.'.'.'., 60' SS40~i~!i.~A coarse gravel, well graded, rounded, very - 90~.:.:.:.?:':-:':-:-?: dense, medium brown, damp, faint odor. Page 2 of 3 Drilling / Lithologic log Project ARCO SS //6218 Boring/Well No. B10 Const. F Samples C~. 0 ~ o_ o © Description / S0il Classification - o_ = (Texture, Color, Structures) ~ o_ = ~ Number .~, o o o I,I, B10- z.:.:-:.:.:.:.:.:.:.:.:.:.z Sand, very fine to fine grained, silty (30%), , I, I 135 SS 25 ;':':':::::::~::¥ 65z I,I, 65' . ............. Sk/ well graded, very dense, medium greenish - ,I,I 35~!i!i~i!i!i!i~ brown, damp, faint gasoline odor. _ I, I, :: ¥:::::::::::::::::::::::: _ ,I,I ~!:!:!:!:!:!:!:[:i:i:? Sand, fine to medium grained, poorly I,I, BIO- ?:'::':':':':':':':':" SP graded, subrounded, very dense, medium 70- , I, 1 256 5S26 ~i:i:i:i:i:i:i:i:[:i:[:i:ii _ I,I, 70' 50~:i:i:i:i:i:i:i:i:i:i:i:i:~ rusty brown, damp, faint gasoline odor. - :1:§3 - :1:,o, :::::::::::::::::::::::::::: _ , I, I ':~:i:i:i:i:!:!:!:i:!:!:!:i? Sand, fine grained, poorly graded, I,I, BIO- + ::::::::::::::::::::::::::::: subrounded, very dense, medium rusty ,I,I 440 S~ o ~!:i:i:i:!:i:!:i:i:i:i:i:ii brown, damp, weak odor. 75- I, I, 75' ~ ::'t::::::::::::::::::::::::: --..'.::.-.::.-.=- Silt, very fine grained, sandy, very dense, - I, I, ~7.4 :.-7.4 :--7.~: M L _ ,I,I ~..-:z..-:~..-:~- medium rusty brown, damp, faint odor. t,I, B la- SS 29 BO-Z ' ~ 133 80' - 75- Boring plunges 75° toward N52°E ~5- - 90Z 95Z Page 3 of 3 B APPENDIX B Disposal Documentation [GROUNDWATER TECHNOLOGY ~.HAZARDOUS (Non-RCRA) '~NON HAZARDOUS LA IDLA W En,ironmenta, Services (Lokem), Inc. 2500 West Lokern Road · Buttonwillow, CA 93206 - (805) 762-7372 ~u~frrY CCldP/INY I C[:RIIFY THAT ]IH[ 1~51:RI~][I"J WASIE WAS .IJAU[ED BY M! 10 Itt[ OI~J~DSA[ fAC(I. ITY iNAM[:.[)AHOVF DESCt:I:J~rlON: :S(~JD '.,,~ SLUDGE LKXJI] 00231 LAIDLAW EI~VIi:~Et~rAJ. ~a~l~ WEIGIIMASTER IEST.__._L RESLI,..T YES NO TES~ ~ RESULT Y~S _wo~ TESI" I FIE:SIJI..T YES I'JO I CERTIFY1H~T ll-IE HAULER ~ DELNEllED TIlE OI~CFII~O WASTE TO TillS ~ FACIIIY ~ D IT WA~/CC[:~ASIJ? I~UL'~R ~ UNCIER ERM S ~ I~i~or.~oR[][R NUMSEll B9-15~. ICZ:JTrlFY'THATIHE JliKWE IDE~TJ:III~D WJ~VtrE IIR5 pI~OF~RLY FitACE. O i~i*D-illE DESaC, J~TE~ Wj~TEiVANAC~t,~k,] UNIT UNI~R MY $UP~R~,F~IC~J.Ad~I3 I~-~URED SI~I~TU~ ~F TSDF (FE~ATCR :.- Tralm Lic. I~. %01.' WATER:" · O.- No Uli FlmSeet · '[o ~ drab o. bmrd~ kl~d~ qdtr. ilmd' Grab lop._...~om NON-HAZARDOUS WASTE DATA,FORM uJ~ZI Z 2~...?G C APPENDIX C Laboratory Reports GROUNDWATER TECHNOLOGY Tier ENVIRONMENTAL LAI~ORATORIES, INC. Southwest Region 20000 / 300 Mariner Drive Torrance, ~ 90503 (213) 371-1044 (800) 727-GTEL Fax {2]3) 371-8720 Mr. Jon Parker Groundwater Technology, Inc. 4101 Alken Road, Suite B-1 Bakersfield, CA 93308 Client Number. GTI78.ARC01 Arco Representative: Fated Luka Arco Facility Number. 6218 Work Order Number:. T1-09-274 September 27, 1991 Dear Mr. Parker, Enclosed please find the analytical results report prepared by GTEL for samples, received on 9/13/91, under task order number 6218-91-2. GTEL is certified by the California State Department of Health Services to perform analyses for drinking water, wastewater, and hazardous waste materials according to EPA protocols. A formal quality control/quality assurance program is maintained by GTEL, which is designed to meet or exceed the EPA requirements. Analytical work for this project was performed in strict adherence to our QA/QC program to ensure sample integrity and to meet quality control criteria. All procedures and quality control have been met unless otherwise noted on the report. If you have any question concerning this analysis or if we can be of further assistance, please call our Customer Service Representative. Sincerely, GTEL Environmental Laboratories, Inc. Minsoon Song Laboratory Director GTEL Torrance, CA Page 1 of 4 T109274.DOC Client Number:. GTi78.ARC01 Arco Representative: Kateri Luka Arco Facility Number:. 6218 Work Order Number:. T1-09-274 Table 1 Con't ANALYTICAL RESULTS Aromatic Volatile Organics and Total Petroleum Hydrocarbons as Gasoline in So~ EPA Methods 8020 and modified 8015a GTEL Sample Number lA 2.A 3A 4A Client Identification B5-35 B6-15 B6-30 B7-25 Date Sampled 9/11/91 9/1-!/91 9/11/91 9/11/91 Date Extracted 9/16/91 9/1,6/91 9/16/91 9/16/91 Date Analyzed 9/21/91 9/2!./91 9/21/91 9/21/91 Detection Analyte Umit, rog/Kg Concentration, mg/Kgb Benzene 0.005 <0.005 <0.005 <0.005 <0.005 Toluene 0.005 <0.005 <0.005 <0.005 <0.005 Ethyl Benzene 0.005 <0.005 <0.005 <0.005 <0.005 Xylene (total) 0.015 <0.015 <0.015 · <0.015 <0.015 BTEX (total) ..... TPH as Gasoline 10 <10 <10 <10 <10 Detection Limit Multiplier I I I 1 Percent .Solids, % 91.2 97.8 96.4 97.2 a Test Methods for Evsluating Solid Waste, SW-846, Third Edition, Revision O, US EPA November 1986;Methanolic extraction ~y EPA Method 5030 (purge and trap) for sromafic volatile organics; modification for TPH as gasoline as per California State water Resources Control BoaJ'd LUFT Manual protocols,May 1988 revision. b. Concentrations calculated on wet basis. GTEL Torrance, CA T109274. DOC Page 2 of 4 GTEL ENVIRONMENTAL LABORATORIES. INC. Client Number:. GTI78.ARC01 Arco Representative: Kateri Luka Arco Facility Number:. 6218 Work Order Number:. T1-09-274 Table 1 Con't ANALYTICAL RESULTS Aromatic Volatile Organics and Total Petroleum Hydrocarbons as Gasoline in Soil EPA Methods 8020 and modified 8015a GTEL Sample Number gA 6A 7A 8A Client Identification B8-20 B9-25 B9-40 B9-65 Date Sampled 9/11/91 9/1.1/91 9/11/91 9/11/91 Date Extracted 9/16/91 9/16/91 9/16/91 9/16/91 Date Analyzed 9/21/91 9/22/91 9/25/91 9/21/91 Detection Analyte Limit, mg/Kg Concentration, mg/Kgb Benzene 0.005 < 0.005 0.53 3.2 0.027 Toluene 0.005 <0.005 4.1 12 0.10 Ethyl Benzene 0.005 <0.005 8.6 1.4 0.017 Xylene (total) 0.015 <0.015 150 8.2 0.14 .BTEX (total) -- - 160 25 0.28 TPH as Gasoline 10 < 10 2700 40 < 10 Detection IJm. it Multiplier 1 10 I 1 Percent Solids, % 95.8 95.4 75.0 94.0 a Test Methods for Evaluating Solid Waste, SW-846, Third Edition, Revision O, US EPA November 1986;Methanolic exh'act[on .by EPA Method ~ (purge and trap) fo~' aromatic volatile organics; modification for TPH as Qasoline as per California ~te Water Resources Control Board LOFT ManuaJ protocols,May 1988 revision. b. Concentrations calculated on wet basis. GTEL Torrance, CA T109274. DOC Page 3 of 4 GTEL EHVIRONMI~NTAL LABORATORIES. INC. Client Number:. GTI78~J~C01 Arco Representative: Kateri Luka Arco Facility Number:. 6218 Work Order Number:. T1,09-274 Table 1 Con't ANALYTICAL RESULTS Aromatic Volatile Organics and Total Petroleum Hydrocarbons as Gasoline in So~ EPA Methods 8020 and modified 8015a GTEL Sample Number 9A 10A 1 lA Client Identification B10-45 B10-75 B10-80 Date Sampled 9/12/91 9/12/91 9/12/91 Date Extracted 9/16/91 9/16/91 9/16/91 Date Analyzed 9/21/91 9/21/91 9/21/91 Detection Analyte IImit, mg/Kg Concentration, rog/Kgb Benzene 0.005 0.089 0.022 0.11 Toluene 0.005 0.56 0.10 0.19 Ethyl Benzene 0.005 0.11 0.014 0.021 Xylene (total) 0.015 0.77 0.11 0.17 BTEX (total) -- 1.5 0.25 0.49 TPH as Gasoline 10 < 10 < 10 < 10 Detection limit Multiplier 1 I 1 Percent Solids, % 91.8 91.2 77.2 a Test Methods for Evaluating Solid Waste, SW-846, Third Edition, Revislon...O, U.S E.PA _Nov.ember 1 ,.9~6;Methan_oli.c..extr. a~.o_n._ by EPA Method 5030 (purge end trap) for aromatic vo[ati, le or~gani_cs; .m.o<3mcatlon ~'or/1~1'~ as gasoune as per ~umrnla ~am Water Resources Control Board LUFT Manual protocols,May l~ rewslon. b. Concentrations calculated on wet basis. GTEL Torrance, CA T109274. DOC Page 4 of 4 GTEL ENVIRONMENTAL LABORATORIES. INC. ~ °' ~'"m'cR~h"°'"C~r""""~' ' Task Order N.c. ~../.~_ ~ ~~ (ARCO) ~__~O (Consultant)~,~~ I(~nsultant~.~ ~~ ~.act.umber . . ~ ' Meth~ ol shipment e 6 .~ ~il Water Other Ice Acid ~ ' ~ ~ o ~ ~pecial detection Prlod~ Rush Condition orsample: ~ ~ ~ - Temperature received: ~-'" ~ -- ~ ' Date / / Time Received by 2 Busine~ Days ~pedited · Time Received by Distribution: White copy -- Lsboratory; Canary copy -- ARCO Environmental Engineering; Pink copy APPC-3292 (2-91) D APPENDIX D SESOIL Climate and Chemical Data Input ' ~-~GROUNDWATER ~___~T. zc"sonoc¥ Table D1. Chemical input data for the SESOIL simulation. Parameter Benzene Toluene Ethyl- Xylenes Reference benzene Solubility 1790 534.8 161.0 156.0 Howard, (mg/I) 1990 Diffusion Coeff. in Air 0.087 0.083 0.076 ~).076 Lyman, et al, (cm2/s) 1990 Henry's Law Constant 0.00543 0.00594 0.00844 0.00768 Howard, (atm.m3/mol) 1990 Adsorption Coeff. on 98.0 331.13 870.96 870.96 GSC, 1990 Carbon (I/kg) Molecular Weight 78.1 92.14 106.17 106.17 Howard, (g/mol) 1990 Table D2. Climate input data for the SESOIL simulation. Precipitation data is from NOAA (1989). Evapotranspiration is at the most minimal level SESOIL will allow. Storm-pulse data is from Riskpro (GSC, 1990) databases. Month Parameter .l u.I u,l .l .lo l .ovl "- Precipitation (cm) 2.62 2,54 2.64 1.55 0,74 0.20 0.03 0.08 0,33 0.84 1.42 1.98 Evapotranspiration 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0.01 0,01 (cm/day) Mean Time Rainfall 0.40 0.40 0.37 0,33 0.16 0.04 0.01 0.04 0.10 0.14 0.33 0.37 (days) Mean No. Storms 2.94 2.74 2.42 1.82 0.51 0.14 0.09 0.11 0.41 0.80 1.77 1.85 (--) Mean Season 30.4 30.4 30.4 30.4 30.4 30,4 30.4 30.4 30.4 30,4 30.4 30.4 (days) CROLTNDWATER E APPENDIX E 95% Upper Confidence Level and Pollutant Load Calculations [~ITEcl-INOLOC¥ Table El. Calculation of 95% UCL for benzene. Sample - Sample Location W'~h Analyte Concentrations* g5% Upper Depth I I I Mean Standard Confidenc Represented B9 BIO T1 ' T2 Deviation · Level 0-5' 5-10' 10-15' 0.85 24 12 12 29 15-20' 1.8 4 3 2.9 4.4 20-25' · 0.53 0.53 N/A N/A 25-30' 30-35' ' 3.2 3.2 N/A N/A 35-40' 40-45' 0,089 0.089 N/A N/A 45-50' 50-55' 55-60' 0,027 0.027 N/A N/A 60-65' 65-70' 70-75' 0.022 0,022 N/A N/A 75-80' 0.11 0.11 N/A N/A Blanks indicate no data available. N/A = Not applicable to one data point. GROUNDWATER TECHNOLOGY Table E2. Calculation of 95% UCL for toluene Sample - Sample LocalJon W'~h Analyte Concentrations* 95% Upper Represented B9 BIO 11 12 Deviation e Level 0-5' 10-15' 13 230 122 109 ' 272 15-20' 9.8 87 48 39 102 20-25' 4.1 4.1 N/A N/A ~ 25-30' 30-35' 12 12 N/A N/A 35-40' 40-45' 0.56 0.56 N/A N/A 45-50' 50-55' 0.1 0.1 N/A N/A 55-60' 60-65' 65-70' 70-75' 0,1 0,1 N/A N/A 75-80' 0.19 0.19 N/A N/A * Blanks indicate no data available. N/A = Not applicable to one data point. GROUNDWATER TECHNOLOGY Table E3. Calculation of 95% UCL for ethylbenzene. Sample - Sample Location W'~h Analyte Concentra§ons* g5% Upper Dept~ I I I Mean ~a~ndard Confident Represented B9 B10 T1 T2 Deviation e level 0-5' 10-15' 5.7 71 38 33 84 i5-20' 8.3 33 21 12 38 20-25' 8.6 8.6 N/A 25-30' 30-35' 1.4 1.4 35-40' 40-45' 0.11 0.11 N/A N/A 45-50' 50-55' 0.017 0.017 N/A N/A 55-60' 60-65' 65-70' - 70-75' 0.014 0.014 N/A N/A 75-80' 0.021 0,021 N/A * Blanks indicate no data available. N/A = Not applicable to one data point. GROUNDWATER TECHNOLOGY Table E4. Calculation of 95% UCL for xylenes. Sample - Sample Location Vath Analyte Concentre~ons* g5% Upper Depth "I I I Mean Standard Confldeno Represented B9 BIO , T1 T2 Deviation e Level 0-5' ,, 5-10' 10-15' 100 460 280 180 529 15-20' 310 300 305 5 312 20-25' 150 150 N/A N/A 25-30' ,, 30-35' 8.2 8.2 N/A N/A 35-40' 40-45' 0.77 0,77 N/A N/A 45-50' 50-55' 0,14 0,14 N/A N/A 55-60' 60-65' 65-70' 70-75' 0.11 0.11 N/A N/A 75-80' 0.17 0.17 N/A N/A Blanks indicate no data available. N/A = Not applicable to one data point. --~ GROUNDWATER TECHNOLOGY Table E5. Upper confidence levels and mass of hydrocarbons in place per 5-foot depth increment. Total pollutant per compartment is divided by the application area (367,000 cm2) to derive 3011utant loads. Concentrations in/~ g/g, masses in/~ g, and pollutant load in/~ g/cm2. Depth Benzene I Toluene I Ethylbenzene I Xylenes Interval UCL ] Mass I, UCL'I MassI UCL Mass [ UOL I Mass 0-5' 29 2.2009 272 2.06010 84 6.3609 529 4.00010 5-10' 29 2,2009 272 2.06010 84 6.3609 529 4.00010 10-15' 29 2.2009 272 2.06010 84 6.3609 529 4.00010 15-20' 4.4 3.3308 102 7.7209 38 2.8809 312. 2.36010 20-25' 3.2 2.4208 12 9.0808 8.6 6.5108 150 1.14010 25-30' 3.2 2.4208 12 9.0808 8.6 6,5108 150 1.14010 30-35' 3.2 2.4208 12 9.0808 1.4 1.0608 8.2 6.2108 Mass in Layer I 7.6609 7.22010 2.34010 1.67011 Pollutant Load 2.0904 1.9705 6.3804 4.5505 35-40' I 3.2 2.4208 12 9.08e8 1.4 1.0608I 8.216.21o8 Mass in Layer 2 2.4208 9.0808 1.0608 6.2108 Pollutant Load 660 2470 289 1690, 40-45' O. 11 8.3306 0.564.2407 O. 118.3306 0.775.8307 45-50' 0.118.3306 0.191.4407 0.11 8.3306 0.775,8307 50-55' O. 11 8.3306 O. 19 1.4407 0.0211.5906 O. 17 1.2907 55-60' 0.118.3306 0.191.4407 0.0211.5906 0.171.2907 60-65' 0.118.3306 0.191.4407 0.0211.5906 0'.17 1.2907 65-70' 0.118,3306 0.191.4407 0,0211.5906 0,171.2907 70-75' 0,118,3306 0.191,4407 0,0211,5906 0,171,2907 75-80' 0.118.3306 0.191.4407 0,0211.5906 0.171.2907 Mass in Layer 3 3.3304 5,7604 6.3603 5.1604 Pollutant Load 181 390 71.4 529 GROUNDWATER TECHNOLOGY F APPENDIX F Abbreviated SESOIL Output Files GROUNDWATER TECHNOLOGY ***** SESOIL~4: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. LITTLE INC. ,(617)864-5770,X5871 ***** J. WAGNER ,DIS/ADLPIPE, INC, ***** MODIFIED EXTENSIVELY BY: ***** D,M. HETRICK ***** OAK RIDGE NATIONAL LABORATORY ***** (615) 576-7556 ***** VERSION ; SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION ****** MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : BENZENE WASHLOAD DATA : APPLICATION AREA: ARCO 6218, BAKERSFIELD, CA - BENZENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS -- SOIL INPUT PARAMETERS o- SOIL DENSITY (G/CM**3): 1,35 INTRINSIC PERMEABILITY (CM**2): ,000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300~/-'~000 ORGANIC CARBON CONTENT (%): CATION EXCHANGE CAPACITY (MILLI EQ./IOOG DRY $ FREUNDLICH EXPONENT (-): 1.00 -- CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): .179E+04 DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .870E-01 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .543E~2 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 98.0 ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 78.1 VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION.RATE IN MOISTURE (/DAY): .000 DEGRADATION RATE ON SOIL (//DAY): .000 LIGAND-POLLUTANT STABILITY CONSTANT (-): .000 NO. MOLES LIGAND/MOLE POLLUTANT (-): ,000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPLICATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 4 YEARS TO BE SIMULATED: 99 AREA (CM**2): 0,367E+06 APPLICATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPLICATION (0): 1 DEPTHS (CM): 0.11E+04 0.15E+03 0.24E+04 0.12E+04 NUMBER OF SUBLAYERS/LAYER 1 1 1 1 PH (CM): 7.0 7.0 7.0 7.0 INTRINSIC PERMEABILITIES (CM**2): 0.10E-05 0.10Eq38 0.10Eq34 0.10E~35 KDEL RATIOS (-): 1.0 1.0 1.0 KDES RATIOS (-): 1.0 1.0 1.0 OC RATIOS (-): 1.0 1.0 1.0 CEC RATIOS (-): 1.0 1.0 1.0 FRN RATIOS(-): 1.0 1.0 1.0 ADS RATIOS(-): 1.0 1.0 1.0 YEAR - I MONTHLY INPUT PARAMETERS -- CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 REL. HUM.(FRAC.) 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 0.000 0.000 0.000 0.0(X) ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1.980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 -- POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 2.09E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) ~~~~E+~~~.~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E+00 O.00E+00 VOLATILIZATION MULT.-1 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E +00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E+00 SURFACE RUNOFFMULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+ 00 0.00E+00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 POL INP-2 (UG/CM**2) 6.60E+02 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+ O00.OOE +00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 0.00E+ O0 0.00E+00 0.00E+ 00 0,00E+ 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E +00 0.00E+ 00 O.00E + 00 0.00E+ 00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+O0 1.00E+O0 POL, INP-3 (UG/CM**2) 1.81E+02 O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+ O0 TRNSFORMD-3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINK~3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 LIG.INPUT-3 (UG/CM**2) O.OOE +00 O.OOE +00 O.OOE + O00.OOE+O00.OOE +00 O.OOE +00 O.OOE+O00.OOE+O00.OOE +00 O.OOE+ O0 O.OOE + O00.OOE+ O0 VOLATILIZATION MULT.-3 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 POL. INP-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 TRNSFORMD-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O,OOE+O00.OOE+O00.OOE+O0 SINKS-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+ O0 LIG.INPUT-L (UG/CM**2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT.-L 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1,00E+ O0 1.00E+O0 1.00E+ O0 1.00E+O0 1.00E+O0 YEAR- 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ~- POL. INP-1 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+ O00.OOE+O00.OOE+O00.OOE+ O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+ O0 TRNSFORMD-1 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS-1 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00.OOE+O0 O.OOE +00 O.OOE +00 LIG.INPUT-1 (UG/CM**2) O.OOE+O00.OOE+ O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT.-10.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE +00 O.OOE + O00.OOE +00 O.OOE + O00.OOE+ O00.OOE +00 O,OOE + O00.OOE+O0 SURFACE RUNOFFMULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~`~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ O.OOE+O00.OOE+O0 POL. IN RAIN (FRAC-SL) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+ O0 O.OOE+ O00.OOE+O0 POL. INP-2 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE + O0 TRNSFORMD-2 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O,OOE+O00.OOE+O00.OOE+O0 SINKS-2 (UG/CM**2) O.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+ O00.OOE+O0 LIG.INPUT-2 (UG/CM**2) O.OOE +00 O.OOE + O00.OOE + O00.OOE + O00.OOE+O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE+ O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT.-2 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1,00E+O0 1.00E+O0 POL. INP-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE +00 O.OOE+O0 TRNSFORMD-3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O,OOE+O00.OOE+O00.OOE+O0 SINKS-3 (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 0.00E+00 0.00E+00 LIG.INPUT-3 (UG/CM**2) 0.00E+ 00 0.00E+ 00 0,00E + 00 0.00E+00 0,00E +00 0,00E+00 0,00E + 00 0.00E+00 0,00E+00 0,OOE+00 O.OOE + O0 0.OOE+ 00 VOLATILIZATION MULT,-3 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1.00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1.00E+00 1.00E+O0 1.00E+O0 POL. INP-L (UG/CM**2) O.OOE+O00,OOE+O00.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O0 0.00E + 00 0,00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0:00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 O.OOE+O00.OOE+O00.OOE+O0 SlNK~L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 0.00E+00 0.00E+00 LIG,INPUT-L (UG/CM**2) 0,00E + 00 0,00E +00 0.00E+ 00 0.00E+00 0.00E +00 0.00E+ 00 0,00E+ 00 0,00E + 00 0,00E +00 0.00E +00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-L 1,00E+O0 1,00E+00 1.00E+00 1.00E+00 1,00E+00 1,00E+00 1.00E+00 1.00E+00 1,00E+00 1.00E+00 1.00E+00 1.00E+00 YEAR -99 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - I MONTHLY RESULTS (OUTPUT) ======================== - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. IN L1 (%) 9.637 9.697 9.847 10.117 10.297 10,477 10.387 10.177 9.907 9.637 9.397 9.247 MOIS. BELOWL1 (%) 9.637 9.697 9.847 10.117 10.297 10.477 10.387 10.177 9.907 9.637 9.397 9.247 PREClPATION (CM) 0.973 1.601 1.980 2.705 2.528 2.736 1.540 0.829 0.344 0.127 0.090 0.368 NET INFILT. (CM) 0.973 1.601 1.980 2.700 2.528 2.738 1.540 0.829 0.336 0.126 0.090 0.368 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 Moms. RETEN (CM) -0.242 0.242 0.605 1.089 0.726 0.726 -0.363 -0.847 .1.089 -1.089 -0.968 -0.605 SUR. RUNOFF (CM) 0.000 0.000 0.000 0,000 0.000 0.050 0.000 0.000 0.050 0.050 0,000 0.000 GRW. RUNOFF (CM) 0.911 0.955 1.071 1.312 1.498 1.700 1.599 1.372 1.121 0.911 0.754 0.669 YIELD (CM) 0.911 0.955 1.071 1.312 1.498 1.706 1.599 1.372 1.129 0.912 0.754 0.669 PAU/MPA(GZU) 1.159 1.057 1.000 1.033 0.995 1.036 0.993 1.120 1.721 4.229 1.130 1.114 PA/MPA (GZ) 1.159 1.057 1.000 1.033 0.995 1.036 0.993 1.120 1.721 4.229 1.130 1.114 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. 0.O00E+00 0.000E+00 0,000E+00 O.000E+00 0.000E+00 0.000E+ 00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E + 00 0.000E + 00 LOAD UPPER 7.670E+ 09 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E +00 0.000E + 00 0.000E+ 00 0.000E +00 O.O00E + O00.O00E + O0 LOAD ZONE 2 2.422E + 08 O.O00E +00 O.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00'O00E + O00'O00E +00 0.000E + O00.000E + 00 L~AD Z~NE 3 6~643E + ~7 ~~~(X)E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~~~~~E + ~~ ~-~~~E + ~~ ~-~~~E + ~~ O.O00E + O00.O00E + O0 LOAD LOWER O.O00E+ O00.O00E + O00.O00E + O00.O00E+ O00.O00E + O00.O00E + O00.O00E + O00.O00E + O00'O00E + O00'O00E + O0 0.000E+ 00 0.000E+ 00 TOTAL INPUT 7.979E + 09 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.0(X)E + 00 0.000E + 00 0.000E + 00 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBI~YER 1 IN SOIL MOl 1.980E+09 1.797E+09 1.657E+09 1.529E+09 1.462E+09 1.405E+09 1.440E+09 1.607E+09 1.582E+09 1.643E+09 1.678E+09 1.676E+09 ADS ON SOIL 4.077E + 09 3.677E + 09 3.340E + 09 3,000E + 09 2.818E +09 2.661E+09 2.751E+09 2.939E + 09 3.168E + 09 3.384E + 09 3.543E+09 3.598E+09 IN SOIL AIR 1.009E+09 9,075E+08 8,183E+08 7.223E+08 6,722E+08 6.290E+08 6.566E+00 7.089E+08 7.747E+08 8.224E+00 8.713E + 08 8.911E+08 SOIL ZONE 2: SUBLAYER 1 DIFFUSED UP 0.000E+ O0 1.119E+08 3.618E+08 5.602E + 08 6.908E + 08 7.592E+ 08 7.763E + 08 7.074E + 08 5.984E+ 08 4.683E + 08 3.624E + 00 3.025E + 00 IN SOIL MOl 2.366E+00 4.260E+08 5,855E+08 7.527E+08 8.417E+08 9.186E+08 8.603E+08 7.539E+00 6.317E+00 5.285E+ 08 4.514E+08 4.252E+08 ADS ON SOIL 4.872E+ 08 8.718E +08 1.180E + 09 1.476E+09 1.622E + 09 1.74OE+09 1.644E+ 09 1.470E +09 1.265E+09 1.088E+09 9.533E + 08 9.124E+08 IN SOIL AIR 1.206E+08 2.152E+08 2.891E+08 3.554E+08 3.870E+08 4.113E+08 3.923E+08 3.546E+08 3.094E+08 2.645E+08 2.344E+ 08 2.260E+ 08 SOIL ZONE 3: SUBLAYER I IN SOIL MOl 1.920E+07 2,159E+07 2.831E+07 3,478E+ 07 4.417E+07 5.545E+07 6.170E+07 6.447E+ 07 6,491E+07 6,460E+ 07 6.395E+07 6.410E+07 ADS ON SOIL 3.953E + 07 4.419E+ 07 5.303E+07 6.822E+07 8.512E+ 07 1.050E +08 1.179E + 08 1.257E+08 1.30OE+08 1.330E + 08 1.350E+08 1.376E+08 IN SOIL AIR 9.785E+06 1.091E+07 1.299E+07 1.642E+07 2.031E+07 2.483E+07 2.813E+07 3.033E+07 3.179E+07 3.233E+07 3.321E+07 3.407E + 07 LOWER SOIL ZONE: SUBLAYER 1 POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER I MOISTURE 5.231E+01 4.718E+01 4.286E+01 3,850E+01 3.616E+01 3.415E+01 3.530E+01 3,771E+01 4.066E+01 4.343E+01 4.547E+01 4.617E+01 %SOLUBILITY2.921E+OO2.634E+OO2.393E+OO2.150E+OO2.019E+O0 1.907E+00 1.971E+00 2.106E+002.270E+00 2.425E+00 2,539E + 00 2.578E+ 00 ADSORBED 7.690E+ 00 6.936E+00 6.300E+00 5.659E+00 5.315E+00 5.020E+00 5.189E+00 5.544E+00 5.976E+00 6.384E+00 6.684E+00 6.787E+ 00 SOIL AIR 1.262E+01 1.138E+01 1.034E+01 9.251E+00 8.689E+00 8.205E+00 8.525E+00 9.107E+00 9.818E+00 1.029E+01 1.077E +01 1.093E+ 01 SOIL ZONE 2: SUBLAYER 1 MOISTURE 4,460E+01 7.980E+01 1,080E+02 1.351E+02 1.485E+02 1.593E+02 1.505E+02 1.346E+02 1,158E+029.962E+01 8.726E+01 8,352E+01 %SOLUBILITY 2.490E + 00 4.456E + 00 6.032E + 00 7.546E + 00 8.290E + 00 8.893E + 00 8.400E + 00 7.513E +00 6.467E + 00 5.562E + 00 4.872E+00 4.663E+ 00 ADSORBED 6.556E+00 1.173E+01 1.588E+01 1.987E+01 2.183E+01 2.341E+01 2,212E+01 1.978E+01 1.702E+01 1.464E+01 1.283E+01 1.228E+01 SOIL AIR 1.076E+01 1.925E+01 2.606E+01 3.247E+01 3.568E+01 3.827E+01 3.633E+01 3.250E+01 2.797E+01 2.359E+01 2.067E+01 1.978E+01 SOIL ZONE 3: SUBLAYER 1 MOISTURE 2.261Eq31 2,528E-01 3.034E~1 3.903Eq31 4,870E~1 6.008E-01 6,744E-01 7.192Eq31 7.438Eq31 7,611E~1 7.726Eq31 7.870Eq31 %SOLUBILITY 1.263E~2 1.412E~32 1.694E~)2 2.179Eq32 2.719E~)2 3.355Eq32 3.765E~32 4.016Eq32 4.153E-02 4.249E~32 4.314E~2 4.394Eq32 ADSORBED 3.324E~2 3.716E~2 4.460E~32 5.737E-02 7.159E~)2 8.832E~2 9.914E~)2 1.057E~1 1.093E~1 1.119E-01 1.136E-01 1.157Eq31 SOIL AIR 5.456E~)2 6.099E-02 7.319E-02 9,377E-02 1.170E~)1 1.444E-01 1.629E-01 1.737E-01 1.796E-01 1.803E-01 1.830E-01 1.864E~)1 LOWER SOIL ZONE: POL DEP CM 2.421E+03 2.423E + 03 2.425E + 03 2o428E +03 2.431E+03 2.434E + 03 2.436E + 03 2.438E + 03 2.439E + 03 2.440E+ 03 2.440E+03 2.441E+03 YEAR - I ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 7.670E + 09 SOIL ZONE 2 2.422E+08 SOIL ZONE 3 6.643E+07 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 9.902 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 9.902 TOTAL PRECIPITATION (CM) 15.721 TOTAL INFILTRATION (CM) 15.712 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.0(X) TOTAL GRW RUNOFF (CM) 13.879 TOTAL MOISTURE RETENTION (CM) -1.815 TOTAL YIELD (CM) 13.888 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS, ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 5,699 E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4.166E+01 ADSORBED SOIL (UG/G) 6.124E+00 SOIL AIR (UG/ML) 9.994E+00 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.122E+02 ADSORBED SOIL (UG/G) 1,650E+01 SOIL AIR (UG/ML) 2,694E+01 SOIL MOISTURE (UG/ML) 5.599E~31 ADSORBED SOIL (UG/G) 8.230E~2 SOIL AIR (UG/ML) 1.341 E~)I MAX. POLL, DEPTH (M) 2.441E+01 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0,0(X)E+00 SOIL ZONE 2 O.O00E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E + 00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 9.725 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 9.725 TOTAL PRECIPITATION (CM) 15.606 TOTAL INFILTRATION (CM) 15.599 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.0(X) TOTAL GRW RUNOFF (CM) 12.193 TOTAL MOISTURE RETENTION (CM) ~).242 TOTAL YIELD (CM) 12,200 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOILAIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 5.341E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 3.311E+01 ADSORBED SOIL (UG/G) 4.867E+00 SOIL AIR (UG/ML) 7.943E+00 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 9.619E+01 ADSORBED SOIL (UG/G) 1.414E+01 SOIL AIR (UG/ML) 2.310E+01 SOIL MOISTURE (UG/ML) 5.331E+00 ADSORBED SOIL (UG/G) 7.836E-01 SOIL AIR (UG/ML) 1,279E+00 MAX. POLL. DEPTH (M) 2.618E+01 YEAR - 20 ANNUAL SUMMARY REPORT - POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 4,221E+09 LOWER SOIL ZONE: SUBLAYER I - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 2,616E+01 ADSORBED SOIL (UG/G) 3,846E+00 SOIL AIR (UG/ML) 6,276E+00 SOIL MOISTURE (UG/ML) 7,601E+01 ADSORBED SOIL (UG/G) 1.117E+01 SOIL AIR (UG/ML) 1,826E+01 SOIL MOISTURE (UG/ML) 9,563E+00 ADSORBED SOIL (UG/G) 1,406E+00 SOIL AIR (UG/ML) 2,295E+00 MAX. POLL. DEPTH (M) 2.815E+01 YEAR - 30 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EJ~CH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 3.336E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 2.068E+01 ADSORBED SOIL (UG/G) 3.039E+00 SOIL AIR (UG/ML) 4.960E+00 SOIL MOISTURE (UG/ML) 6.007E+01 ADSORBED SOIL (UG/G) 8.831E+00 SOIL AIR (UG/ML) 1.443E+01 SOIL MOISTURE (UG/ML) 1.276E+01 ADSORBED SOIL (UG/G) 1.875E+00 SOIL AIR (UG/ML) 3.061E+00 MAY~ POLL. DEPTH (M) 3.012E+01 YEAR - 40 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 2.632 E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.631E+01 ADSORBED SOIL (UG/G) 2.398E+00 SOIL AIR (UG/ML) 3.913E+00 SOIL MOISTURE (UG/ML) 4.740E+01 ADSORBED SOIL (UG/G) 6.968E+00 SOIL AIR (UG/ML) 1.139E+01 SOIL MOISTURE (UG/ML) 1.524E+01 ADSORBED SOIL (UG/G) 2.240E+00 SOIL AIR (UG/ML) 3.656E+00 MAY~ POLL DEPTH (M) 3.208E+01 YEAR - 50 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 2.072E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.284E+01 ADSORBED SOIL (UG/G) 1.888E+00 SOIL AIR (UG/ML) 3.081E+00 SOIL MOISTURE (UG/ML) 3,732E+01 ADSORBED SOIL (UG/G) 5.485E+00 SOIL AIR (UG/ML) 8.963E+00 SOIL MOISTURE (UG/ML) 1.716E+01 ADSORBED SOIL (UG/G) 2,523E+00 SOIL AIR (UG/ML) 4.118E+00 MAX. POLL DEPTH (M) 3.405E+01 YEAR - 60 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 1.630E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.010E+01 ADSORBED SOIL (UG/G) 1.485E+00 SOIL AIR (UG/ML) 2.424E+00 SOIL MOISTURE (UG/ML) 2.935E+01 ADSORBED SOIL (UG/G) 4.315E+00 SOIL AIR (UG/ML) 7.051E+00 SOIL MOISTURE (UG/ML) 1.861E+01 ADSORBED SOIL (UG/G) 2,735E+00 SOIL AIR (UG/ML) 4.465E+00 MAX. POLL. DEPTH (M) 3.602E+01 YEAR - 70 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) LOWER SOIL ZONE: SUBLAYER 1 1.292 E + 09 1.412E+06 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 8.005E+00 ADSORBED SOIL (UG/G) 1.177E+00 SOIL AIR (UG/ML) 1.920E+00 SOIL MOISTURE (UG/ML) 2.326E+01 ADSORBED SOIL (UG/G) 3.429E+00 SOIL AIR (UG/ML) 5.588E+00 SOIL MOISTURE (UG/ML) 1.782E+01 ADSORBED SOIL (UG/G) 2.620E+00 SOIL AIR (UG/ML) 4.277E+00 SOIL MOISTURE (UG/ML) 3.697E+00 ADSORBED SOIL (UG/G) 5.434Eq31 SOIL AIR (UG/ML) 8.869Eq31 MAX. POLL DEPTH (M) 3.910E+011 YEAR - 80 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 1.049E+09 SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) 4.819E+06 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 6.484E+00 ADSORBED SOIL (UG/G) 9.532E-01 SOIL AIR (UG/ML) 1.555E+00 SOIL MOISTURE (UG/ML) 1,887E+01 ADSORBED SOIL (UG/G) 2,775E+00 SOIL AIR (UG/ML) 4.534E+00 SOIL MOISTURE (UG/ML) 1.655E+01 ADSORBED SOIL (UG/G) 2.432E+00 SOIL AIR (UG/ML) 3.970E+00 SOIL MOISTURE (UG/ML) 7.694E+00 ADSORBED SOIL (UG/G) 1.131E+00 SOIL AIR (UG/ML) 1.846E+00 MAX~ POLL. DEPTH (M) 4.229E+01 YEAR - 90 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 8.782E+08 SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) 7.169E+06 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 5.413E+00 ADSORBED SOIL (UG/G) 7.957E-01 SOIL AIR (UG/ML) 1.298E+00 SOIL MOISTURE (UG/ML) 1.578E+01 ADSORBED SOIL (UG/G) 2.320E+00 SOIL AIR (UG/ML) 3.791E+00 SOIL MOISTURE (UG/ML) 1,513E+01 ADSORBED SOIL (UG/G) 2.224E+00 SOIL AIR (UG/ML) 3.631E+00 SOIL MOISTURE (UG/ML) 1.131E+01 ADSORBED SOIL (UG/G) 1.662E+00 SOIL AIR (UG/ML) 2.714E+00 MAX~ POLL. DEPTH (M) 4.548E+01 YEAR - 99 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO E~CH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) 7.647E+08 SOIL ZONE 3: SUBLAYER 1 TOTAL DIFFUSED (UP) 8.153E+06 LOWER SOIL ZONE: SUBLAYER 1 TOTAL DIFFUSED (UP) 3.457E+06 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 4.705E+00 ADSORBED SOIL (UG/G) 6.917E~31 SOIL AIR (UG/ML) 1.129E+00 SOIL MOISTURE (UG/ML) 1.373E+01 ADSORBED SOIL (UG/G) 2.019E+00 SOIL AIR (UG/ML) 3.299E+00 SOIL MOISTURE (UG/ML) 1.384E+01 ADSORBED SOIL (UG/G) 2,035E+00 SOIL AIR (UG/ML) 3.322E+00 SOIL MOISTURE (UG/ML) 1.419E+01 ADSORBED SOIL (UG/G) 2,085E+00 SOIL AIR (UG/ML) 3.404E+00 MAY~ POLL. DEPTH (M) 4.836E+01 ************************************************ COMPLETED**************************************** ***** SESOIL.-84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. MTTLE INC. ,(617)864-5770,X5871 ***** ***** J, WAGNER ,DIS/ADLPIPE, INC. ***** MODIFIED EXTENSIVELY BY: ***** D.M. HETRICK ***** OAK RIDGE NATIONAL LABORATORY ***** (615) 576-7556 *****VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION ****** MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : TOLUENE WASHLOAD DATA : APPLICATION AREA: ARCO 6218, BAKERSFIELD, CA - TOLUENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .150 CATION EXCHANGE CAPACITY (MILLI EQ./100G DRY SOIL): FREUNDLICH EXPONENT (-): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 535. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): ,830E-01 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .594E-02 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 331. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 92.1 · VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .000 DEGRADATION RATE ON SOIL (/'DAY): .000 LIGAND-POLLUTANT STABILITY CONSTANT (-): .000 NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): ,000 - APPLICATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 4 YEARS TO BE SIMULATED: 99 AREA (CM**2): 0.367E+06 APPLICATION AREA LATITUDE (DEG,): 36.0 SPILL (1) OR STEADY APPMCATION (0): 1 DEPTHS (CM): 0.11E+04 0.15E+03 0.24E+04 0.12E+04 NUMBER OF SUBLAYERS/LAYER I 1 1 1 PH (CM): 7.0 7.0 7.0 7.0 INTRINSIC PERMEABILITIES (CM**2): 0.10E~5 0.10Eq38 0.10E-04 0.10Eq:)5 KDEL RATIOS (-): 1.0 1.0 1.0 KDES RATIOS (-): 1.0 1.0 1.0 OC RATIOS (-): 1.0 1.0 1.0 CEC RATIOS (-): 1.0 1.0 1.0 FRN RATIOS(-): 1.0 1.0 1.0 ADS RATIOS(-): 1.0 1.0 1.0 YEAR - 1 MONTHLY INPUT PARAMETERS -- CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 0.000 0.000 0.(XX) 0.000 CLOUDCVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 REL. HUM.(FRAC,) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY} 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1,980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1,770 1.850 2,940 2.740 2.420 1.820 0.510 0.140 0,090 0,110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30.400 20.400 30.400 30.400 20.400 - POLLUTANT INPUT PARAMETERS -- POL. INP-1 (UG/CM**2) 2.00E+05 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 SINKSol (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E+00 0.00E + 00 0.00E+00 0,00E + 00 0.00E+ 00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 0.00E + 00 0.00E + 00 0.OOE + 00 0.00E + 00 0.00E + 00 0.00E + 00 0,00E + 00 0.00E +00 0.00E + 00 0.00E+ 00 0,00E+00 0,00E+00 SURFACE RUNOFF MULT, 0,00E + 00 0,00E + 000,00E +00 0,00E+ 00 0.00E + 00 0.00E+ 00 0.00E + 00 0,00E + 000.00E+ 00 0,00E +00 0,00E+00 0.00E + 00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 POL. INP-2 (UG/CM**2) 2.47E+03 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 SINK~2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+ 00 LIG.INPUT-2 (UG/CM**2) 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E +00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 0,00E +00 0.00E +00 VOLATILIZATION MULT,-2 1.00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1.00E+00 1.00E+00 POL. INP-3 (UG/CM**2) 3.90E+02 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.0OE+00 0.00E+00 0,00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 SINKS-3 (UG/CM**2) 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 LIG,INPUT-3 (UG/CM**2) 0.00E+ 00 0.00E+00 0.00E + 00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E +00 0.00E+00 0.00E+ 00 0.00E+00 O.OOE + O0 VOLATILIZATION MULT.-3 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POL. INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 TRNSFORME~L (UG/CM**2) 0.00E+O0 0.OOE+00 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SlNKS-L (UG/CM**2) O.00E+00 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E + 00 LIG.INPUT-L (UG/CM**2) 0 00E+00 0.00E+ 00 0.00E + 00 0 00E+00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+00 0.00E + 00 0.OOE + 00 0.00E+O0 VOLATILIZATION MULT.-L 1.00E+00 1.00E+00 1,00E+00 1.00E+00 1.00E +00 1.00E+00 1.00E+O0 1.00E+ 00 1.00E+00 1.00E+O0 1.00E+00 1.00E+00 YEAR- 2 MONTHLY INPUT PARAMETERS -- CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT iNPUT PARAMETERS - POL. INP-1 (UG/CM**2) 0.00E+00 0.00E+00 O.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 O.OOE+O0 0.OOE+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+00 0.00E+ 00 VOLATILIZATION MULT.-1 0.00E + 00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E+00 SURFACE RUNOFFMULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0,OOE + 00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+00 POL. INP-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 LIG.INPUT-2 (UG/CM**2) 0.00E+00 0.00E + 00 0.00E + 00 0.00E +00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E +00 0.00E +00 0.00E + 00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+O0 1.00E+00 1.00E+00 1.00E+O0 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POL. INP-3 (UG/CM**2) 0.00E+00 0.00E+00 0,00E+00 0.00E+00 O.OOE+00 0,00E+00 O.00E+O0 0.OOE+00 O.00E+00 O.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-3 (UG/CM**2) O.OOE+O00.OOE+O00,OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE +00 O.OOE+O0 LIG,INPUT-3 (UG/CM**2) O,OOE + O00.OOE + O00,OOE + O00.OOE + O00.OOE + O0 0 IX)E+ O00.OOE + O00,OOE +00 O,OOE + O00.OOE+ O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT,-3 1.00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1,00E+O0 1.00E+O0 1,00E+O0 1.00E+O0 1,00E+O0 POL. INP-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE +00 O.OOE+O0 TRNSFORMD-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O00.OOE+O0 O.OOE+O00,OOE+O00.OOE+O0 SINKS-L (UG/CM**2) O.OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00,OOE+O00.OOE+O00,OOE+O00.OOE+O0 O.OOE+O00.OOE+ O0 LIG,INPUT-L (UG/CM**2) O,OOE+ O00.OOE + O00.OOE+ O00.OOE+ O00,OOE +00 O.OOE+O00.OOE+ O00,OOE + O00.OOE+ O00.OOE + O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT,-L 1.00E+O0 1,00E+O0 1,00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1,00E+O0 1.00E+O0 1.00E+O0 1,00E+O0 1.00E+O0 1,00E+O0 YEAR -99 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR- 1 MONTHLY RESULTS (OUTPUT) ====~.~=== ======================== - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. INL1 (%) 9.603 9.663 9.813 10.083 10.293 10.473 10.383 10.173 9.903 9.633 9.393 9.243 MOIS. BELOWL1 (%) 9.603 9.663 9,813 10,083 10.293 10,473 10.383 10.173 9.903 9.633 9.393 9.243 PRECIPATION (CM) 0.954 1.485 1.966 2.692 2.663 2.750 1.545 0.828 0.340 0.122 0.086 0.366 NET INFILT. (CM) 0.954 1.485 1.966 2.692 2.663 2.750 1.545 0.828 0.333 0.122 0.086 0.366 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOI$. RETEN (CM) ~.244 0.244 0.610 1.098 0.854 0.732 ~3.366 ~3.854 -1.098 -1.098 ~3.976 ~3.610 SUR. RUNOFF (CM) 0.000 0.000 0.000 0.000 0.0(X) 0.0(X) 0,000 0.000 0.000 0.000 0.000 0.000 GRW. RUNOFF (CM) 0.894 0.937 1.052 1.290 1.505 1.714 1.607 1.378 1.127 0.916 0.758 0.672 YIELD (CM) 0.894 0.937 1.052 1.290 1.505 1.714 1.607 1.378 1.134 0.916 0.758 0.672 PAU/MPA (GZU) 1.136 1.046 0.993 1.027 1.048 1.042 0.997 1.120 1.702 4.071 1.073 1.100 PA/MPA (GZ) 1.136 1.046 0.993 1.027 1.048 1.042 0.997 1.120 1.702 4.071 1.073 1.108 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. O.O00E+O00.O00E+O00.O00E+O00.O00E+ O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O00.O00E+O0 0.000E + 00 0.000E+00 LOAD UPPER 7.340E + 10 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E +00 0.000E + 00 0.000E + 00 0.000E + 00 LOAD ZONE 2 9.065E + 08 0.000E + 00 0.000E +00 0.000E + 00 0.000E +00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0,000E + 00 LOAD ZONE 3 1.431 E+08 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E +00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 LOAD LOWER ~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~(X~E+~~~~~~~E+~~ 0.000E + 00 0.000E + 00 TOTAL INPUT 7.445E+ 10 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E + 00 0.000E+ 00 0,000E + 00 0.000E+ 00 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 IN SOIL MOl 8.308E+09 7,959E+09 7,587E+09 7.229E+09 6.922E+09 6.652E+09 6.507E+09 6.447E+09 6.439E+09 6.453E+09 6.459E + 09 6.450E + 09 ADS ON SOIL 5.801 E+ 10 5.523E + 10 5.185E+ 10 4.807E+ 10 4.510E + 10 4.259E + 10 4.202E + 10 4.250E+ 10 4.360E+ 10 4.492E+ 10 4.611 E+ 10 4.679E+ 10 IN SOIL AIR 4.657E+09 4.421E+09 4.119E+09 3.753E+09 3.484E+09 3.260E+09 3.248E+09 3.320E+09 3.452E+09 3.535E+09 3.672E+09 3.753E +09 SOIL ZONE 2: SUBLAYER 1 DIFFUSED UP O.O00E+O00.O00E+O0 6.489E+07 7.016E+08 1.346E+09 1.828E+09 2.153E+09 2.239E+09 2.179E+09 1.987E+09 1.797E+09 1.632E+09 IN SOIL MOl 3.887E+08 7.851E+08 1.275E+09 1.846E+09 2.311E+09 2.712E +09 2.771E+09 2.655E+09 2.440E+09 2.214E+09 2.010E+09 1.893E+09 ADS ON SOIL 2.714E+ 09 5.448E+09 8,714E +09 1.228E+ 10 1.506E + 10 1.736E+ 10 1.790E+ 10 1.750E + 10 1.652E+ 10 1.541E+ 10 1.435E + 10 1.373E+ 10 IN SOIL AIR 2.179E+08 4.361E+08 6.923E+08 9.588E+08 1.163E+09 1.329E+09 1.383E+09 1.367E+09 1.308E+09 1.213E+09 1.142E+09 1.101E+09 SOIL ZONE 3: SUBLAYER 1 IN SOIL MOl 1.714E+07 1.889E+07 2.288E+07 3.110E+07 4.192E+07 5.548E+ 07 6.372E+07 6.784E+07 6.892E +07 6.880E+ 07 6.831E+07 6.907E +07 ADS ON SOIL 1.197E +08 1.311E+08 1.564E+ 08 2.089E +08 2.731E+ 08 3.552E+ 08 4.115E + 08 4.472E+ 08 4.667E+08 4.789E+ 08 4.877E + 08 5.011 E+ 08 IN SOIL AIR 9.609E+06 1.049E+07 1.242E+07 1.615E+07 2.110E+07 2.719E+07 3.180E+07 3.493E+07 3.695E+07 3.769E+07 3.883E+07 4.019E+07 LOWER SOIL ZONE: SUBLAYER I POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 2.203E+02 2.097E+02 1.969E+02 1.826E+02 1.713E+02 1.618E+02 1.596E+02 1.614E+02 1.656E+02 1.706E+02 1.751E+02 1.777E+02 %SOLUBILITY 4.120E+01 3,922E+01 3.682E+01 3.414E+01 3,202E+01 3.025E+01 2.984E+01 3.018E+01 3.096E+01 3.190E+01 3.274E+01 3,323E+01 ADSORBED 1.094E+02 1.042E+02 9.780E+01 9.068E+01 8.507E+01 8.035E+01 7.927E+01 8.016E+01 8,224E+01 8.473E+01 8.698E+01 8.827E+01 SOIL AIR 5.815E+01 5.536E+01 5.196E+01 4.799E+01 4.502E+01 4.252E+01 4.216E+01 4.264E+01 4.374E+01 4.420E+01 4.537E+01 4.604E+01 SOIL ZONE 2: SUBLAYER 1 MOISTURE 7.354E+01 1.476E+02 2.361E+02 3.327E+02 4.079E+02 4.704E+02 4.849E+02 4.741E+02 4.476E+02 4.176E+02 3.886E+ 02 3.720E + 02 %SOLUBILITY 1.375E+01 2.760E+01 4.414E+01 6.220E+01 7.627E+01 8.796E+01 9.067E+01 8.864E+01 8.369E+01 7.808E+01 7.267E+01 6,956E+01 ADSORBED 3.653E+01 7.331E+01 1.172E+02 1.652E+02 2.026E+02 2.336E+02 2.408E+02 2.355E+ 02 2,223E+02 2.074E+02 1.930E+02 1.848E+02 SOILAIR 1.941E+01 3.895E+01 6.230E+01 8.744E+01 1.072E+02 1.236E+02 1.281E+02 1.252E+02 1.182E+02 1.082E+02 1.007E+02 9.638E+01 SOIL ZONE 3: SUBLAYER 1 MOISTURE 1.993Eq31 2.183E-01 2.604Eq~1 3.445E~1 4.548Eq)1 5.916Eq31 6.853E~1 7.447E~31 7.772E~31 7.976Eq~1 8.122Eq31 8.346Eq31 %SOLUBILITY 3.727E~32 4.081E-02 4.870E~32 6.442E-02 8.504E~2 1.106Eq31 1.281E~1 1.392Eq31 1.453E~31 1.491E~1 1.519E~31 1.561E~31 ADSORBED 9.901Eq32 1.084E~31 1.294E~1 1.711Eq31 2.259E~31 2.938E-01 3.404Eq31 3.699E~)1 3.860E-01 3.961E~1 4.034E~1 4.145E-01 SOIL AIR 5.261E~2 5.760Eq32 6.873E~32 9.055Eq~2 1.195E~31 1.555E~31 1.810E~)1 1.967E~31 2,053E~31 2,086E~1 2.104E~1 2.162E-01 LOWER SOIL ZONE: POL DEP CM 2.441E + 03 2.441E + 03 2.442E + 03 2.443E + 03 2.444E + 03 2.446E + 03 2.447E + 03 2.447E+ 03 2.448E + 03 2.448E+ 03 2.449E+03 2.449E+03 YEAR - 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 7.340E+ 10 SOIL ZONE 2 9.065E+08 SOIL ZONE 3 1.431E+08 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 9;888 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 9.888 TOTAL PRECIPITATION (CM) 15.798 TOTAL INFILTRATION (CM) 15.789 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 13.849 TOTAL MOISTURE RETENTION (CM) -1.708 TOTAL YIELD (CM) 13.858 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOILAIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 1.593E + 10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1.794E+02 ADSORBED SOIL (UG/G) 8.910E+01 SOIL AIR (UG/ML) 4.710E+01 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 3.544E+02 ADSORBED SOIL (UG/G) 1.760E+02 SOIL AIR (UG/ML) 9.298E+01 SOIL MOISTURE (UG/ML) 5,600E..01 ADSORBED SOIL (UG/G) 2,782E-01 SOIL AIR (UG/ML) 1.467E-01 MAX. POLL. DEPTH (M) 2.449E+01 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.000E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE 0.000E + 00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 9,710 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 9,710 TOTAL PRECIPITATION (CM) 15.542 TOTAL INFILTRATION (CM) 15.535 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.131 TOTAL MOISTURE RETENTION (CM) -0.244 TOTAL YIELD (CM) 12.138 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 2,478E+ 10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 1,504E+02 ADSORBED SOIL (UG/G) 7.468E+01 SOIL AIR (UG/ML) 3.946E+01 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 4.273E+02 ADSORBED SOIL (UG/G) 2.122E+02 SOIL AIR (UG/ML) 1.122E+02 SOIL MOISTURE (UG/ML) 8.110E+00 ADSORBED SOIL (UG/G) 4,028E+00 SOIL AIR (UG/ML) 2,129E+00 MAX. POLL. DEPTH (M) 2.523E+01 YEAR - 20 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER I 2.247E+ 10 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.363E+02 ADSORBED SOIL (UG/G) 6.772E+01 SOIL AIR (UG/ML) 3.578E+01 SOIL MOISTURE (UG/ML) 3,875E+02 ADSORBED SOIL (UG/G) 1.925E+02 SOIL AIR (UG/ML) 1.018E+02 SOIL MOISTURE (UG/ML) 1.570E+01 ADSORBED SOIL (UG/G) 7,798E+00 SOIL AIR (UG/ML) 4,121E+00 MAX, POLL DEPTH (M) 2.605E+01 YEAR - 30 ANNUAL SUMMARY REPORT ============================ POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 2.034E+ 10 LOWER SOIL ZONE: SUBLAYER I - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.234E+02 ADSORBED SOIL (UG/G) 6.130E+01 SOIL AIR (UG/ML) 3.239E+01 SOIL MOISTURE (UG/ML) 3.508E+02 ADSORBED SOIL (UG/G) 1.742E+02 SOIL AIR (UG/ML) 9.212E+01 SOIL MOISTURE (UG/ML) 2.253E+01 ADSORBED SOIL (UG/G) 1.119E+01 SOIL AIR (UG/ML) 5.914E+00 MAY~ POLL. DEPTH (M) 2.687E+01 YEAR - 40 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 1.840E+ 10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.116E+02 ADSORBED SOIL (UG/G) 5.544E+01 SOIL AIR (UG/ML) 2.930E+01 SOIL MOISTURE (UG/ML) 3.172E+02 ADSORBED SOIL (UG/G) 1.576E+02 SOIL AIR (UG/ML) 8.331E+01 SOIL MOISTURE (UG/ML) 2.869E+01 ADSORBED SOIL (UG/G) 1.425E+01 SOIL AIR (UG/ML) 7,530E+00 MAX. POLL. DEPTH (M) 2,770E+01 YEAR - 50 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 1.666E+10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1,011E+ 02 ADSORBED SOIL (UG/G) 5,021E+01 SOIL AIR (UG/ML) 2.653E+01 SOIL MOISTURE (UG/ML) 2,872E+02 ADSORBED SOIL (UG/G) 1.427E+02 SOIL AIR (UG/ML) 7.543E+01 SOIL MOISTURE (UG/ML) 3.425E+01 ADSORBED SOIL (UG/G) 1.701E+01 SOIL AIR (UG/ML) 8.990E+00 MAX. POLL. DEPTH (M) 2.852E+01 YEAR - 60 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 1.514E+10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 9.195E+01 ADSORBED SOIL (UG/G) 4.567E+01 SOIL AIR (UG/ML) 2.414E+01 SOIL MOISTURE (UG/ML) 2.612E+02 ADSORBED SOIL (UG/G) 1.297E+02 SOIL AIR (UG/ML) 6.860E+01 SOIL MOISTURE (UG/ML) 3.928E+01 ADSORBED SOIL (UG/G) 1.951E+01 SOIL AIR (UG/ML) 1.031E+01 MAX. POLL. DEPTH (M) 2.934E+01 YEAR - 70 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 1.382E + 10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 8.393E+01 ADSORBED SOIL (UG/G) 4.169E+01 SOIL AIR (UG/ML) 2.203E+01 SOIL MOISTURE (UG/ML) 2.384E+02 ADSORBED SOIL (UG/G) 1.184E+02 SOIL AIR (UG/ML) 6.261E+01 SOIL MOISTURE (UG/ML) 4.384E+01 ADSORBED SOIL (UG/G) 2.177E+01 SOIL AIR (UG/ML) 1.151E+01 MAX, POLL. DEPTH (M) 3.016E+01 YEAR - 80 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 1.261E+ 10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 7.658E+01 ADSORBED SOIL (UG/G) 3.804E+01 SOIL AIR (UG/ML) 2.010E+01 SOIL MOISTURE (UG/ML) 2.175E+02 ADSORBED SOIL (UG/G) 1.080E+02 SOIL AIR (UG/ML) 5.713E+01 SOIL MOISTURE (UG/ML) 4.798E+01 ADSORBED SOIL (UG/G) 2.383E+01 SOIL AIR (UG/ML) 1.260E+01 MAX. POLL. DEPTH (M) 3.099E+01 YEAR - 90 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 1.150E+10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 6.985E+01 ADSORBED SOIL (UG/G) 3.469E+01 SOIL AIR (UG/ML) 1.833E+01 SOIL MOISTURE (UG/ML) 1.984E+02 ADSORBED SOIL (UG/G) 9,855E+01 SOIL AIR (UG/ML) 5.210E+01 SOIL MOISTURE (UG/ML) 5.176E+01 ADSORBED SOIL (UG/G) 2,571E+01 SOIL AIR (UG/ML) 1,359E+01 MAX, POLL. DEPTH (M) 3.181E+01 YEAR - 99 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 1.058E + 10 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 6.427E+01 ADSORBED SOIL (UG/G) 3,192E+01 SOIL AIR (UG/ML) 1.687E+01 SOIL MOISTURE (UG/ML) 1.826E+02 ADSORBED SOIL (UG/G) 9.067E+01 SOIL AIR (UG/ML) 4.794E+01 SOIL MOISTURE (UG/ML) 5.486E+01 ADSORBED SOIL (UG/G) 2.725E+01 SOIL AIR (UG/ML) 1.440E+01 MAX. POLL, DEPTH (M) 3.255E+01 ************************************************ COMPLETED**************************************** ***** SESOIL'.84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. UTTLE INC. ,(617)864-5770,X5871 ***** ***** J. WAGNER ,DIS/ADLPIPE, INC. ,(617)492-1991,X5820 ***** ***** MODIFIED EXTENSIVELY BY: ***** ***** D.M. HETRICK ***** ***** OAK RIDGE NATIONAL LABORATORY ***** ***** (615) 576'7556 *****VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION ****** MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : ETHYLBENZENE WASHLOAD DATA : APPLICATION AREA: ARCO 6218, BAKERSFIELD, CA - ETHYLBENZENE WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS - SOIL INPUT PARAMETERS - SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .150 CATION EXCHANGE CAPACITY (MILLI EQ./IOOG DRY SOIL): FREUNDLICH EXPONENT (-): 1.00 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 161. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .760E-01 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .844E-01 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 871. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 106. VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .O(X) DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND-POLLUTANT STABILITY CONSTANT (-): .000 NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPLICATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: 4 YEARS TO BE SIMULATED: 99 AREA (CM**2): 0.367E+ 06 APPLICATION AREA LATITUDE (DEG.): 36.0 SPILL (1) OR STEADY APPLICATION (0): 1 DEPTHS (CM): 0.11E+04 0.15E+03 0.24E+04 0.12E+04 NUMBER OF SUBLAYERS/LAYER 1 1 1 1 PH (CM): 7.0 7.0 7.0 7.0 INTRINSIC PERMEABILITIES (CM**2): 0.10E~5 0.10Eq38 0.10E-04 0.10E~)5 KDEL RATIOS (-): 1.0 1.0 1.0 KDES RATIOS (-): 1.0 1.0 1.0 OC RATIOS (-): 1.0 1.0 1.0 CEC RATIOS (-): 1.0 1.0 1.0 FRN RATIOS(-): 1.0 1.0 1.0 ADS RATIOS(-): 1.0 1.0 1.0 YEAR- 1 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP. (DEG C) 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 CLOUD CVR (FRAC,) 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.000 0.000 REL. HUM.(FRAC.) 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.0(X) ALBEDO (-) 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT, (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0,010 0.010 0.010 PRECIP, (CM) 0,840 1.420 1,980 2.620 2.540 2.640 1.550 0.740 0.200 0.030 0.080 0,330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0,400 0.370 0.330 0.160 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 30.400 30.400 30,400 30.400 30.400 30.400 30.400 -- POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 6.38E+04 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.OOE + 00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E +00 0.00E+00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 0.00E + 00 VOLATILIZATION MULT,-1 0,00E+ 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0,00E + 00 0,00E + 00 0.00E+ 00 0.00E+00 0.00E+00 SURFACE RUNOFF MULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0.00E+00 0.00E+00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 POL. INP-2 (UG/CM**2) 2.89E+02 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0,00E+00 0,00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E+ 00 0,00E+ 00 0,00E+ 00 0,00E +00 0.00E+00 0,00E+ 00 0,00E + 00 0.00E +00 0.00E +00 0.00E +00 0.00E +00 0.00E +00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+O0 1.00E+00 1.00E+O0 1.00E+O0 1.00E+00 1.00E+ 00 POL INP-3 (UG/CM**2) 7.10E+01 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.OOE+O00.OOE+O00.OOE+O0 SINKS-3 (UG/CM**2) O,OOE+O00.OOE+O00.OOE+O00,OOE+O00,OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00,OOE+O0 0.00E+00 O.00E+00 LIG.INPUT-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 0.00E +00 0.00E +00 0.00E+00 0.00E+00 0.00E +00 0.00E +00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-3 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POL. INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 0.00E+00 O.OOE+O00.OOE+O00,OOE+O0 SINKS-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00,OOE+O00.OOE+O00,OOE+O00,OOE+O0 0.00E+00 0.OOE+O0 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0,00E + 00 0.00E + 00 0,00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E+ 00 0.00E + 00 0,00E +00 0.00E+00 0,00E+O0 VOLATILIZATION MULT.-L 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+O0 1.00E+00 1.00E+00 1.00E+00 1.00E +00 YEAR- 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR -- POLLUTANT INPUT PARAMETERS - POL. INP-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E +00 0,00E +00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.OOE+00 O,00E+00 SINKS-1 (UG/CM**2) 0,OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-1 (UG/CM**2) 0.00E + 00 0.00E + 00 0.OOE + O00.OOE+ 00 0.OOE + O0 0.00E+ 00 0.00E + 00 O.00E + 00 0.00E +00 0.00E + 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 0.00E + 00 0.00E + 00 0.00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E+00 0.00E + 00 SURFACE RUNOFFMULT. ~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~~~~~E+~~ 0,00E+ 00 0.00E+00 POL. IN RAIN (FRAC-SL) 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 POL. INP-2 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+ 00 0.00E+00 0.00E+O0 0.00E+00 0.00E+00 0,00E+00 0.00E + 00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0,00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E +00 0.00E +00 0.00E +00 0.00E+ 00 O.OOE +00 O.OOE+O0 VOLATILIZATION MULT.-2 1.00E+O0 1,00E+O0 1.00E+O0 1,00E+O0 1.00E+ O0 1,00E+O0 1.00E+O0 1,00E+O0 1,00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 POL. INP-3 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 O.OOE+00 0.OOE+O00.OOE+00 SINKS-3 (UG/CM**2) 0.00E+00 0.00E+O0 0.00E+00 0,00E+00 0.OOE+00 0.00E+00 0.00E+00 0;00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 LIG.INPUT-3 (UG/CM**2) O.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE + O00.OOE+ O00.OOE + O00.OOE + O00.OOE + O00.OOE + O0 O.OOE+O00.OOE+O0 VOLATILIZATION MULT.~31.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 1.00E+O0 POL. INP-L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+ O00.OOE+ O0 TRNSFORMD~L (UG/CM**2) O.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O00.OOE+O0 O.OOE+O00.OOE+O00.OOE+O0 SINKS-L (UG/CM**2) O.OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00,OOE+O00.OOE+O00.OOE+O00,OOE+O0 O.OOE+ O00.OOE+O0 LIG.INPUT-L (UG/CM**2) O.OOE+O00.OOE + O00.OOE +00 O.OOE+O00.OOE+ O00.OOE +00 O.OOE+ O00.OOE+O00.OOE+ O00.OOE + O0 O.OOE+ O00.OOE+O0 VOLATILIZATION MULT.-L 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E + O0 1.00E+O0 1.00E+O0 YEAR -99 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - 1 MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. INL1 (%) 9.603 9.663 9.813 10.083 10.293 10,473 10.383 10.173 9.903 9.633 9.393 9.243 MOIS. BELOW L1 (%) 9.603 9.663 9,813 10.083 10.293 10.473 10.383 10,173 9.903 9.633 9.393 9.243 PRECIPATION (CM) 0.954 1.485 1.966 2.692 2.663 2,750 1.545 0.828 0.340 0.122 0.086 0.366 NET INFILT. (CM) 0.954 1.485 1.966 2.692 2.663 2.750 1.545 0.828 0.333 0.122 0.086 0.366 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0,304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) -0.244 0.244 0,610 1.098 0.854 0.732 -0.366 -0.854 -1.098 -1.098 -0.976 -0.610 SUR. RUNOFF (CM) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 GRW. RUNOFF (CM) 0.894 0.937 1.052 1.290 1.505 1.714 1.507 1.378 1.127 0.916 0.758 0.672 YIELD (CM) 0.894 0.937 1.052 1.290 1.505 1.714 1.607 1.378 1.134 0.916 0.758 0.672 PAU/MPA (GZU) PA/MPA (GZ) 1.136 1.046 0.993 1.027 1.048 1.042 0.997 1.120 1.702 4.071 1.073 1.100 1.136 1.046 0.993 1.027 1.048 1.042 0.997 1.120 1.702 4.071 1.073 1.100 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E +00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E + 00 0.000E + 00 LOAD UPPER 2.341 E+ 10 0.000E + 00 0.000E + 00 0.000E +00 0.000E + 00 0.000E + 00 0.000E+00 0.000E + 00 0.000E + 00 0.000E+ 00 O.O00E + O00.O00E+ O0 LOAD ZONE 2 1,061E+08 O.O00E + O00.O00E + O00,O00E + O00.O00E + O00.O00E + O00,O00E + O00.O00E + O00.O00E + O00.O00E + O0 0.000E+ 00 0.000E + 00 LOAD ZONE 3 2.606E + 07 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+00 0.000E + 00 0.0(X)E + 00 0.000E + 00 0.000E +00 LOAD LOWER ~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~ 0.000E+ 00 0.000E+ 00 TOTAL INPUT 2,355E + 10 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E + 00 0.000E+00 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOILZONE: SUBLAYER 1 IN SOIL MOl 8.477E+00 8.406E+08 8.383E+00 8.419E+08 8.383E +00 8.307E+08 8.112E+08 7.921E+00 7.714E+00 7.548E +00 7.357E + 00 7.224E+00 ADS ON SOIL 1.557E+ 10 1.534E + 10 1.507E + 10 1.473E+ 10 1.437E + 10 1.399E+ 10 1.378E+ 10 1.373E + 10 1.374E+ 10 1.382E + 10 1.382E + 10 1.379E+ 10 IN SOIL AIR 6.752E+09 6.635E+09 6.467E+09 6.212E+09 5.995E+09 5.785E+09 5.753E+09 5.795E+09 5.876E+09 5.876E+09 5.943E + 09 5.973 E + 09 SOIL ZONE 2: SUBLAYER 1 DIFFUSED UP 0.000E+00 0.000E+00 0.000E+00 0,000E+00 0.000E+00 1.351E+05 1.052E+00 1,943E+08 1.801E+08 1,335E+08 9.571E+07 8.796E+07 IN SOIL MOl 1.280E +07 2.575E+07 4.282E+07 6.685E+07 9.124E+07 1.167E+00 1.254E + 08 1.233E + 00 1.172E+00 1.119E+00 1.073E+00 1.057E +00 ADS ON SOIL 2.351E+08 4.700E +00 7.696E + 00 1.169E+ 09 1.583E +09 1.966E + 09 2.130E + 09 2.138E+09 2.088E+ 09 2.048E +09 2.014E+09 2.018E+09 IN SOIl. AIR 1.020E+08 2.032E+08 3.303E+08 4.932E+08 6.524E+08 8.128E+08 8.892E+08 9.023E+08 8.929E+08 8.708E+08 8,663E +08 8,742E+ 08 SOIL ZONE 3: SUBLAYER 1 IN SOIL MOl 9.573E+05 9,807E+05 1.036E+06 1,153E+06 1,303E+06 1,498E+06 1,604E+06 1,644E+06 1,636E+06 1,619E+06 1,593E+06 1,595E+06 ADS ON SOIL 1.758E + 07 1.790E + 07 1.862E + 07 2.018E + 07 2,233E + 07 2,523E + 07 2,724E + 07 2.851E + 07 2.914E + 07 2,965E + 07 2.991E+07 3.043E+ 07 IN SOIL AIR 7,625E+06 7,740E+06 7.994E +06 8,509E+06 9,318E+06 1,043E+07 1,137E+07 1.203E+07 1,247E+07 1,261E+07 1.286E+07 1.318E+07 LOWER SOIL ZONE: SUBLAYER 1 POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 2,248E+01 2,215E+01 2,175E+01 2.126E+01 2,074E+01 2,020E+01 1.990E+01 1.983E+01 1,984E+01 1.996E+01 1,995E+01 1,990E+01 %SOLUBILITY 1.396E+01 1.376E+01 1,351E+01 1.321E+01 1,288E+01 1.255E+01 1,236E+01 1.232E+01 1.232E+01 1,239E+01 1,239E+01 1.236E+01 ADSORBED 2.937E+01 2.894E+01 2.842E+01 2.778E+01 2,710E+01 2,639E+01 2.599E+01 2,591E+01 2.591E+01 2.607E+01 2.606E+01 2,600E+01 SOILAIR 8.430E+01 8.307E+01 8.158E+01 7.942E+01 7,747E+01 7,544E+01 7.468E+01 7,443E+01 7,446E+01 7,346E+01 7.343E +01 7,328E+01 SOIL ZONE 2: SUBLAYER 1 MOISTURE 2.422E+00 4.840E+00 7.926E+00 1.204E+01 1.610E+01 2.025E+01 2.194E+01 2,202E+01 2,150E+01 2,110E+01 2.074E+01 2.078E+ 01 %SOLUBILITY 1,504E+003.006E+00 4.923E+00 7,481E+001,000E+01 1.257E+01 1.362E+01 1.368E+01 1,335E+01 1.310E+01 1,288E+01 1.291E+01 ADSORBED 3,164E+00 6.324E+00 1.036E+01 1,574E+01 2,104E+01 2.645E+01 2.866E+01 2.877E+01 2,809E+01 2.756E+01 2.710E+01 2.715E+01 SOILAIR 9,082E+00 1.815E+01 2,972E+01 4.499E+01 6.014E+01 7.561E+01 8,234E+01 8,267E+01 8.070E+01 7,766E+01 7.637E+01 7.650E+01 SOIL ZONE 3: SUBLAYER 1 MOISTURE 1,113Eq32 1,133E~2 1,179Eq32 1,277E~2 1,414E~)2 1,598Eq32 1,725E~32 1,805E~32 1.845Eq32 1,877Eq32 1,894Eq32 1,927Eq32 %SOLUBILITY 6.915E~3 7,040Eq33 7,325Eq33 7.934Eq33 8,781Eq:)3 9,922E-03 1.071 E~2 1.121 E~32 1.146E~)2 1.166Eq32 1.176E~32 1,197Eq32 ADSORBED 1,454E~)2 1.481E~32 1.541E~2 1.669Eq32 1.847Eq32 2,087E~2 2,254Eq32 2,358E-02 2.411Eq32 2,453E~32 2,474E~2 2.517E-02 SOIL AIR 4,175E~)2 4.25OEq32 4,422E~2 4.771Eq32 5,280Eq~2 5.966Eq32 6,475E-02 6,776E~32 6.927E~32 6.911E~)2 6,971E~32 7,093Eq32 LOWER SOIL ZONE: POL DEP CM 2.440E + 03 2.440E + 03 2.441E+03 2,441E+03 2,441E+03 2.442E + 03 2.442E +03 2,442E+03 2,442E +03 2.443E+03 2,443E + 03 2,443E + 03 YEAR - I ANNUAL SUMMARY REPORT - TOTAl.. INPUTS (UG) - UPPER SOIL ZONE 2.341E+ 10 SOIL ZONE 2 1.061E+08 SOIL ZONE 3 2.606E+07 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 9.888 AVERAGE SOIL MOISTURE BELOW ZONE I (%) 9.888 TOTAL PRECIPITATION (CM) 15.798 TOTAL INFILTRATION (CM) 15.789 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 13.849 TOTAL MOISTURE RETENTION (CM) -1.708 TOTAL YIELD (CM) 13.858 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 7.969E+08 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL MOISTURE (UG/ML) 2.066E+01 ADSORBED SOIL (UG/G) 2.700E+01 SOIL AIR (UG/ML) 7.709E+01 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.597E+01 ADSORBED SOIL (UG/G) 2.087E+01 SOIL AIR (UG/ML) 5.949E+01 SOIL MOISTURE (UG/ML) 1.566E-02 ADSORBED SOIL (UG/G) 2.045E-02 SOIL AIR (UG/ML) 5.835E-02 MAX. POLL. DEPTH (M) 2.443E+01 YEAR - 10 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 0.000E+00 SOIL ZONE 2 0.0(X)E+00 SOIL ZONE 3 0.000E+00 LOWER SOIL ZONE O.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 9.710 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 9.710 TOTAL PRECIPITATION (CM) 15.542 TOTAL INFILTRATION (CM) 15.535 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 12.131 TOTAL MOISTURE RETENTION (CM) -0.244 TOTAL YIELD (CM) 12.138 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 3.235E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER I SOIL MOISTURE (UG/ML) 1.930E+01 ADSORBED SOIL (UG/G) 2.521E+01 SOIL AIR (UG/ML) 7.198E+01 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 2.213E+01 ADSORBED SOIL (UG/G) 2.891E+01 SOIL AIR (UG/ML) 8.256E+01 SOIL MOISTURE (UG/ML) 1.343E-01 ADSORBED SOIL (UG/G) 1,755E-01 SOIL AIR (UG/ML) 5,009E-01 MAX. POLL. DEPTH (M) 2.466E+01 YEAR - ~ ANNU~ SUMMARY REPORT ====================== POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 3.162E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.886E+01 ADSORBED SOIL (UG/G) 2.465E+01 SOIL AIR (UG/ML) 7.036E+01 SOIL MOISTURE (UG/ML) 2.163E+01 ADSORBED SOIL (UG/G) 2.826E+01 SOIL AIR (UG/ML) 8.071E+01 SOIL MOISTURE (UG/ML) 2.634E~31 ADSORBED SOIL (UG/G) 3.441Eq31 SOIL AIR (UG/ML) 9.823Eq31 MAX. POLL. DEPTH (M) 2.492E+01 YEAR - 30 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 3.091E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.844E+01 ADSORBED SOIL (UG/G) 2.409E+01 SOIL AIR (UG/ML) 6.877E+01 SOIL MOISTURE (UG/ML) 2.114E+01 ADSORBED SOIL (UG/G) 2.762E+01 SOIL AIR (UG/ML) 7.888E+01 SOIL MOISTURE (UG/ML) 3,894E-01 ADSORBED SOIL (UG/G) 5,087E-01 SOIL AIR (UG/ML) 1.452E+00 MAY~ POLL. DEPTH (M) 2.518E+01 YEAR - 40 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 3.020E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1,802E+01 ADSORBED SOIL (UG/G) 2,354E+01 SOIL AIR (UG/ML) 6.719E+01 SOIL MOISTURE (UG/ML) 2.066E+01 ADSORBED SOIL (UG/G) 2.699E+01 SOIl_ AIR (UG/ML) 7.707E+01 SOIL MOISTURE (UG/ML) 5.125E-O1 ADSORBED SOIL (UG/G) 6.695E-01 SOIL AIR (UG/ML) 1.911E+00 MAX. POLL. DEPTH (MI 2.544E+01 YEAR - 50 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 2,950E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.760E+01 ADSORBED SOIL (UG/G) 2.299E+01 SOIL AIR (UG/ML) 6.564E+01 SOIL MOISTURE (UG/ML) 2.018E+01 ADSORBED SOIL (UG/G) 2.637E+01 SOIL AIR (UG/ML) 7,530E+01 SOIL MOISTURE (UG/ML) 6,328Eq31 ADSORBED SOIL (UG/G) 8,267Eq31 SOIL AIR (UG/ML) 2.360E+00 MAX. POLL. DEPTH (M) 2.570E+01 YEAR - 60 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 2.882E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.719E+01 ADSORBED SOIL (UG/G) 2.246E+01 SOIL AIR (UG/ML) 6.411E + 01 SOIL MOISTURE (UG/ML) 1.971E+01 ADSORBED SOIL (UG/G) 2.575E+01 SOIL AIR (UG/ML) 7.354E+01 SOIL MOISTURE (UG/ML) 7.502Eq31 AOSORBED SOIL (UG/G) 9.801E~31 SOIL AIR (UG/ML) 2.798E+00 MAY~ POLL. DEPTH (M) 2.596E+01 YEAR - 70 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 2.814E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.679E+01 ADSORBED SOIL (UG/G) 2.193E+01 SOIL AIR (UG/ML) 6.261E+01 SOIL MOISTURE (UG/ML) 1.925E+01 ADSORBED SOIL (UG/G) 2,515E+01 SOIL AIR (UG/ML) 7.182E+01 SOIL MOISTURE (UG/ML) 8,649E~1 ADSORBED SOIL (UG/G) 1,130E+00 SOIL AIR (UG/ML) 3.226E+00 MAY~ POLL. DEPTH (M) 2.622E+01 YEAR - 80 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 2.748E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LowER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.639E+01 ADSORBED SOIL (UG/G) 2.141E+01 SOIL AIR (UG/ML) 6.113E+01 SOIL MOISTURE (UG/ML) 1.879E+01 ADSORBED SOIL (UG/G) 2.455E+01 SOIL AIR (UG/ML) 7.012E+01 SOIL MOISTURE (UG/ML) 9.771E-01 ADSORBEO SOIL (UG/G) 1.277E+00 SOIL AIR (UG/ML) 3.644E+00 MAX. POLL. DEPTH (M) 2.648E+01 YEAR - 90 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 2.682E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.600E+01 ADSORBED SOIL (UG/G) 2.090E+01 SOIL AIR (UG/ML) 5.967E+01 SOIL MOISTURE (UG/ML) 1.834E+01 ADSORBED SOIL (UG/G) 2.397E+01 SOIL AIR (UG/ML) 6.844E+01 SOIL MOISTURE (UG/ML) 1.073E+00 ADSORBED SOIL (UG/G) 1.402E+00 SOIL AIR (UG/ML) 4,003E+00 MAX. POLL. DEPTH (M) 2.674E+01 YEAR - 99 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 2.623 E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: suBLAyER 1 SOIL ZONE 3: SUBLAYER I LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.565E+01 ADSORBED SOIL (UG/G) 2.044E+01 SOIL AIR (UG/ML) 5.836E+01 SOIL MOISTURE (UG/ML) 1.794E+01 ADSORBED SOIL (UG/G) 2.344E+01 SOIL AIR (UG/ML) 6.694E+01 SOIL MOISTURE (UG/ML) 1,155E+00 ADSORBED SOIL (UG/G) 1,509E+00 SOIL AIR (UG/ML) 4.307E+00 MAX. POLL. DEPTH (M) 2.698E+01 ************************************************ COMPLETED**************************************** ***** SESOIL-84: SEASONAL CYCLES OF WATER, SEDIMENT, AND POLLUTANTS IN SOIL ENVIRONMENTS ***** DEVELOPERS: M. BONAZOUNTAS,ARTHUR D. UTTLE INC. ,(617)864-5770,X5871 ***** ***** J. WAGNER ,DIS/ADLPIPE, INC, ***** MODIFIED EXTENSIVELY BY: ***** D.M. HETRICK ***** OAK RIDGE NATIONAL LABORATORY ***** (615) 576-7556 *****VERSION : SEPTEMBER 1986 ****** MONTHLY SESOIL MODEL OPERATION ****6* MONTHLY SITE SPECIFIC SIMULATION REGION : BAKERSFIELD WSO AP SOIL TYPE : SAND COMPOUND : 1,2-XYLENE WASHLOAD DATA : APPLICATION AREA: ARCO 6218, BAKERSFIELD, CA - XYLENES WARNING- SOIL PERMEABILITY VARYS CONSIDERABLY AMONG LAYERS SESOIL MAY NOT BE ACCURATE FOR SUCH AN INHOMOGENEOUS COLUMN GENERAL INPUT PARAMETERS -- SOIL INPUT PARAMETERS SOIL DENSITY (G/CM**3): 1.35 INTRINSIC PERMEABILITY (CM**2): .000 DISCONNECTEDNESS INDEX (-): 7.50 POROSITY (-): .300 ORGANIC CARBON CONTENT (%): .150 CATION EXCHANGE CAPACITY (MILLI EQ./IOOG DRY SOIL): FREUNDLICH EXPONENT (-): 1.00 1 - CHEMICAL INPUT PARAMETERS - SOLUBILITY (UG/ML): 175. DIFFUSION COEFFICIENT IN AIR (CM**2/SEC): .760E-01 HENRYS LAW CONSTANT (M**3-ATM/MOLE): .510E-O2 ADSORPTION COEFFICIENT ON ORGANIC CARBON(KOC): 871. ADSORPTION COEFFICIENT ON SOIL (K): .000 MOLECULAR WEIGHT (G/MOL): 106. VALENCE (-): .000 NEUTRAL HYDROLYSIS CONSTANT (/DAY): .000 BASE HYDROLYSIS CONSTANT (L/MOL-DAY): .000 ACID HYDROLYSIS CONSTANT (L/MOL-DAY): .000 DEGRADATION RATE IN MOISTURE (/DAY): .000 DEGRADATION RATE ON SOIL (/DAY): .000 LIGAND-POLLUTANT STABILITY CONSTANT (-): .000 NO. MOLES LIGAND/MOLE POLLUTANT (-): .000 LIGAND MOLECULAR WEIGHT (G/MOL): .000 - APPLICATION INPUT PARAMETERS - NUMBER OF SOIL LAYERS: YEARS TO BE SIMULATED: AREA (CM**2): APPLICATION AREA LATITUDE (DEG.): SPILL (1) OR STEADY APPLICATION (0): DEPTHS (CM): NUMBER OF SUBLAYERS/LAYER PH (CM): INTRINSIC PERMEABILITIES (CM**2): KDEL RATIOS (-): KDES RATIOS (-): OC RATIOS (-): CEC RATIOS (-): FRN RATIOS(-): ADS RATIOS(-): YEAR- 1 MONTHLY INPUT PARAMETERS 4 30.0 1 0.11E+~ 0.15E+00 0.~E+~ 0.12E+~ 1 1 I 1 7.0 7.0 7.0 7.0 0.10Eq350.10Eq380.10E~340.10Eq35 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 - CLIMATIC INPUT PARAMETERS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP TEMP, (DEG C) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 CLOUD CVR (FRAC.) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 REL, HUM.(FRAC.) 0,000 0,000 0.000 0.000 0,000 0.0(X) 0.000 0.000 0,000 0.000 0.000 0,000 ALBEDO (-) 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 EVAPOT. (CM/DAY) 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 0.010 PRECIP. (CM) 0.840 1.420 1,980 2.620 2.540 2.640 1.550 0.740 0,200 0.030 0,080 0.330 M.TIME RAIN(DAYS) 0.140 0.330 0.370 0.400 0.400 0.370 0.330 0.150 0.040 0.010 0.040 0.100 M. STORM NO. (-) 0.800 1.770 1.850 2.940 2.740 2.420 1.820 0.510 0.140 0.090 0.110 0.410 M. SEASON (DAYS) 30.400 30.400 30.400 30.400 30.400 50.400 30.400 30.400 30.400 30.400 30.400 30.400 - POLLUTANT INPUT PARAMETERS- POL. INP-1 (UG/CM**2) 4.50E+05 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+ 00 LIG.INPUT-1 (UG/CM**2) O.OOE+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 ~~~~E+~~~~~~E+~~~~~~E+00~~~~E+~~~~00E+00~~00E+~~~~00E+00~~00E+00~~00E+00~~00E+~~ 0.00E+00 0.00E+00 SURFACE RUNOFF MULT. ~~~~E+~~~-~~E+00~~00E+00~~00E+~~~~~~E+00~~~~E+00~~00E+~~~~00E+00~~00E+~~~~00E+~~ 0.00E+00 0.00E+00 POL, IN RAIN (FRAC-SL) 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 POL. INP-2 (UG/CM**2) 1.69E+03 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 0.00E+ 00 TRNSFORMD-2 (UG/CM**2) 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0.00E+ 00 0,00E+00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1,00E+00 POL, INP-3 (UG/CM**2) 5.28E+02 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-3 (UG/CM**2) 0,00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 LIG,INPUT-3 (UG/CM**2) 0.OOE+ 00 0.00E + 00 0,00E + 00 0 00E+00 0.00E+ 00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E + 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-3 1.00E+00 1.00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1,00E+00 1.00E+00 1.00E+00 1.00E+00 POL. INP-L (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 TRNSFORMD-L (UG/CM**2) 0.00E+00 0.OOE+00 0.00E+00 0,00E+O0 0.00E+00 0,00E+O00,00E+O00.OOE+00 0.00E+O0 0.00E+00 0.00E+00 O.00E+00 SINKS-L (UG/CM**2) 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+ 00 0.00E +00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 0,00E+00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+ 00 0.00E+00 VOLATILIZATION MULT,-L 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1,00E + 00 1,00E+ 00 1.00E+00 1,00E+00 1,00E+00 1.00E+00 YEAR- 2 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS -- POL, INP-1 (UG/CM**2) 0,OOE+00 0.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,OOE+00 0.00E+00 0,OOE+00 0,00E+00 0.00E +00 0,00E+ 00 TRNSFORMD-1 (UG/CM**2) 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-1 (UG/CM**2) O.00E+00 0.00E+00 0,00E+00 0,00E+O0 0.00E+00 0,00E+00 0.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 LIG,INPUT-1 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+ 00 0,00E+ 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-1 0.00E + 00 0,00E +00 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0,00E+ 00 0.00E + 00 0.00E+00 SURFACE RUNOFFMULT, ~.~~E+~~~.~~E+~~~~~~E+~~~~~~E+~~~.~~E+~~~~~~E+~~~.~~E+~~~~~~E+~~~.~~E+~~~.~~E+~~ 0.00E+00 0,00E+00 POL, IN RAIN (FRAC-SL) 0.00E+00 0,00E +00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 O.00E+00 0.00E+00 POL, INP-2 (UG/CM**2) 0,00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+ 00 0.00E+00 0.00E+00 0.00E + 00 0.00E+00 TRNSFORMD-2 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-2 (UG/CM**2) 0,00E+O0 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 LIG.INPUT-2 (UG/CM**2) 0.00E + 00 0,00E + 00 0.00E + 00 0,00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0,00E +00 0.00E+ 00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-2 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1,00E+00 1,00E+00 1,00E+00 1.00E+00 1.00E+00 1,00E+00 1.00E+00 POL INP-3 (UG/CM**2) 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0,00E+00 0,00E+00 0.00E + 00 0.00E+00 TRNSFORMD-3 (UG/CM**2) 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0,00E+00 0.00E+00 0,00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 SINKS-3 (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 LIG.INPUT~3 (UG/CM**2) 0.00E + 00 0.00E + 00 0.00E +00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E + 00 0.00E+ 00 0.00E+00 VOLATILIZATION MULT.~3 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 POL. INP-L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E +00 0.00E+ 00 TRNSFORMD~L (UG/CM**2) 0.00E+00 0.00E+00 0.00E+00 0.0OE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+O0 SINKS-L (UG/CM**2) O.OOE+00 O.00E+O0 0.00E+00 0.00E+00 0.00E+00 0.00E+00 O.00E+00 0.OOE+00 0.00E+00 0.00E+00 0.00E+00 0.00E+ 00 LIG.INPUT-L (UG/CM**2) 0.00E + 00 0.00E + 00 0.OOE +00 0.00E +00 0.00E+00 0.00E + 00 0.00E+00 0.00E + 00 0.00E+00 0.00E+00 0.00E+00 0.00E+00 VOLATILIZATION MULT.-L 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1,00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 1.00E+00 YEAR -99 MONTHLY INPUT PARAMETERS - CLIMATIC INPUT PARAMETERS ARE SAME AS LAST YEAR - POLLUTANT INPUT PARAMETERS ARE SAME AS LAST YEAR YEAR - 1 MONTHLY RESULTS (OUTPUT) - HYDROLOGIC CYCLE COMPONENTS - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP MOIS. INL1 (%) 9.603 9,663 9.813 10,083 10.293 10,473 10,383 10.173 9.903 9.633 9.393 9.243 MOIS, BELOW L1 (%) 9.603 9.663 9,813 10.083 10.293 10.473 10.383 10,173 9.903 9.633 9,393 9.243 PREClPATION (CM) 0.954 1.485 1.966 2.692 2.663 2.750 1.545 0.828 0.340 0.122 0.086 0.366 NET INFILT. (CM) 0.954 1.485 1.966 2.692 2.663 2.750 1.545 0.828 0.333 0.122 0.086 0.366 EVAPOTRANS. (CM) 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 0.304 MOIS. RETEN (CM) -0.244 0.244 0.610 1.098 0.854 0.732 -0.366 -0.854 -1.098 -1.098 -0.976 -0.610 SUR. RUNOFF (CM) 0.000 0.000 0.000 0.000 0.000 0.000 0.0(X) 0.0(X) 0.000 0.000 0.000 0.000 GRW. RUNOFF (CM) 0.894 0.937 1.052 1.290 1.505 1.714 1.607 1.378 1.127 0.916 0.758 0.672 YIELD (CM) 0.894 0.937 1.052 1.290 1.505 1.714 1.607 1.378 1.134 0.916 0.758 0.672 PAU/MPA (GZU) PA/MPA (GZ) 1.136 1.046 0,993 1,027 1,048 1,042 0.997 1,120 1.702 4,071 1.073 1.100 1.136 1.046 0.993 1.027 1.048 1.042 0.997 1.120 1.702 4.071 1.073 1.100 - POLLUTANT MASS INPUT TO COLUMN (UG) - OCT NOV DEC JAN FEB MAR APR MAY JUN JUL AUG SEP PRECIP. 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0,000E+00 0.000E+00 0.000E+00 0.000E+00 0.000E+00 0,000E+00 0.000E+ 00 0.000E+ 00 LOAD UPPER 1.651 E+ 11 0.000E + 00 0.000E+ 00 0.000E + 00 0.000E + 00 0.000E + 00 0,000E +00 0,000E + 00 0.000E+ 00 0.000E+ 00 0.000E + 00 0.000E +00 LOAD ZONE 2 6.202E + 00 0.000E +00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.O00E + 00 O.000E + 00 0.000E + 00 0.000E + 00 LOAD ZONE 3 1~938E+00~~~~~E+~~~~~~~E+~~~~~~~E+~~~-~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~~~~~~E+~~ 0.O00E + OO 0.000E + 00 LOAD LOWER 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E + 00 0.000E+ 00 0.000E+ 00 0.000E + 00 0.000E+ 00 TOTAL INPUT 1.660E + 11 0.000E + 00 0.000E + 00 0.000E +00 0.000E + 00 0.000E+ 00 0.000E+ 00 0.000E + 00 0.000E +00 0.000E+ 00 0.000E+00 0.000E + 00 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 IN SOIL MOl 6.599E+09 6.640E+09 6.743E+09 6.929E+09 7,073E+09 7.197E+09 7.135E+09 6.991E+09 6,805E+09 6.620E+09 6.455E + 09 6.352E + 09 ADS ON SOIL 1.212E+ 11 1.212E+ 11 1.212E+ 11 1.212E + 11 1.212E+ 11 1.212E+ 11 1.212E+ 11 1.212E+ 11 1.212E+ 11 1.212E+ 11 1.212E+ 11 1,212E+ 11 IN SOIL AIR 3,176E+09 3.167E+09 3.144E+09 3.089E+09 3.056E+09 3.029E+09 3.058E+09 3.090E+09 3.133E+09 3.114E+09 3.150E+09 3.173E+09 PURE PHASE 3.228E + 10 2.951 E+ 10 2.589E + 10 2.097E + 10 1.602E + 10 1.086E + 10 7.765E + 09 5.971E+09 5.098E + 09 4.708E+09 4.368E+09 3.580E + 09 SOIL ZONE 2: SUBLAYER 1 IN SOIL MOl 1.264E+08 2.658E+00 4.515E+00 7.149E+08 9,878E+00 1.009E+09 1.000E+ 09 9.800E+ 00 9.540E + 08 9.280E+ 00 9.049E +00 8.904E+08 ADS ON SOIL 2.321E+09 4.852E+09 8.116E+ 09 1.251 E+ 10 1.693E + 10 1.699E + 10 1.699E + 10 1.699E+ 10 1.699E + 10 1.699E + 10 1.699E + 10 1.699E + 10 IN SOIL AIR 6.084E+07 1.268E+00 2.105E+00 3.187E+00 4.268E+08 4.246E+08 4.287E+08 4.332E+00 4.391E+08 4.365E+08 4.416E+00 4.448E+ 00 PURE PHASE O.O00E +00 O.O00E +00 O.O00E+O00,O(X)E + O00.O00E + O0 4.941E+09 8.049E + 09 9.954E +09 1.098E + 10 1.160E+ 10 1.208E+ 10 1.295E+ 10 SOIL ZONE 3: SUBLAYER I IN SOIL MOl 9.817E+06 1.011E+07 1.082E+07 1.233E+07 1.438E+07 1.683E+07 1.806E+07 1.854E+07 1.851E+07 1.830E+07 1.806E + 07 1.813E+07 ADS ON SOIL 1.803E+08 1.846E+00 1.944E+00 2.156E+00 2.463E+08 2.834E+00 3.068E+00 3.215E+08 3.298E+08 3.351E+08 3.392E+08 3.460E +08 IN SOIL AIR 4.725E+06 4.822E+06 5.043E+06 5.496E+06 6,212E+06 7.001 E+00 7.739E+06 8.197E+00 8.523E+06 8.607E+06 8.816E+06 9.059E+00 LOWER SOIL ZONE: SUBLAYER I POLLUTANT CONCENTRATIONS (UG/ML) OR (UG/G) - NOTE: IF CONCENTRATIONS ARE ZERO FOR EACH MONTH, THEY ARE NOT PRINTED - UPPER SOIL ZONE: SUBLAYER 1 MOISTURE 1.750E+02 1.750E+02 1.750E+02 1,750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 %SOLUBILITY 1.000E+02 1.000E+02 1.000E +02 1.000E+ 021.000E +02 1.000E+021.000E+021.000E+02 1.000E+ 02 1.0(X)E +02 1.000E+02 1.000E+02 ADSORBED 2.286E+02 2.286E+02 2.286E+02 2.286E+02 2.286E+02 2.286E+02 2.286E+02 2.286E+02 2.286E+02 2.286E+02 2.286E+02 2.286E+02 SOILAIR 3.965E+01 3.965E+01 3.965E+01 3.949E+01 3.949E+01 3.949E+01 3.969E+01 3.969E+01 3.969E+01 3.893E+01 3.893E +01 3.893E+01 PURE PHASE 8.221E+01 7.515E+01 6.592E+01 5.340E+01 4.000E+01 2.766E+01 1.977E+01 1.521E+01 1.298E+01 1.199E+01 1.112E+01 9.116E+00 SOIL ZONE 2: SUBLAYER 1 MOISTURE 2.391E+01 4.997E+01 8.359E+01 1,288E+02 1.743E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 1.750E+02 %SOLUBILITY 1.366E+01 2.855E+01 4.776E+01 7.360E+01 9.962E+01 1.000E+ 02 1.000E+021,000E+02 1.000E+02 1.000E+02 1.000E +02 1.000E+02 ADSORBED 3.124E + 01 6.528E + 01 1.092E + 02 1.683E + 02 2.278E + 02 2.286E + 02 2.286E + 02 2.286E + 02 2.286E + 02 2.286E + 02 2,286E+02 2.286E+02 SOIL AIR 5.418E+00 1.132E+01 1.894E+01 2.907E+01 3.934E+01 3.949E+01 3.969E+01 3.969E+01 3.969E+01 3.893E+01 3.893E+01 3.893E+01 PURE PHASE O.O00E + O00.O00E + O00.O00E + O00.O00E + O00.O00E +00 8.975E+ 01 1.462E +02 1.800E + 021.995E +02 2.107E +02 2.195E+02 2.353E+ 02 SOIL ZONE 3: SUBLAYER 1 MOISTURE 1.142E-01 1.169E~)1 1.231E~1 1.365Eq31 1.560E~1 1.794Eq31 1.942Eq31 2.036E~31 2.008E~31 2.121E-01 2.148E~1 2.191E~1 %SOLUBILITY 6.524E~32 6.677Eq32 7.035Eq32 7.802E~2 8.913Eq32 1.025Eq)1 1.110Eq31 1.163Eq31 1.193Eq31 1.212Eq31 1.227E~31 1.252E~31 ADSORBED 1.491Eq31 1.527E-01 1.600E~31 1.784E-01 2.038E-01 2.344E~31 2.538Eq31 2.659E~31 2.728E~31 2.772E~)1 2.800E~31 2.862E-01 SOIL AIR 4.874E-02 2.587E-02 2.648E-02 2.790E-02 3.081E-O2 3.520E.O2 4.050E-02 4.406E-02 4.617E-02 4,736E-02 4.719E-02 4.777E-02 LOWER SOIL ZONE: POL DEP CM 2.440E+03 2.441E+03 2.441E+03 2.441E +03 2.442E + 03 2.442E+ 03 2.443E + 03 2.443E + 03 2.443E+03 2.444E+ 03 2.444E + 03 2.444E + 03 YEAR - 1 ANNUAL SUMMARY REPORT - TOTAL INPUTS (UG) - UPPER SOIL ZONE 1.651E + 11 SOIL ZONE 2 6.202E+08 SOIL ZONE 3 1.938E+08 LOWER SOIL ZONE 0.000E+00 - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE 1 (%) 9,888 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 9.888 TOTAL PRECIPITATION (CM) 15,798 TOTAL INFILTRATION (CM) 15.789 TOTAL EVAPOTRANSPIRATION (CM) 3.648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRW RUNOFF (CM) 13.849 TOTAL MOISTURE RETENTION (CM) -1,708 TOTAL YIELD (CM) 13.858 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED FOR FINAL MASS IN SOIL MOl., ADS. ON SOIL, SOIL AIR, IMMOBIL CEC, COMPLEXED, AND PURE PHASE FOR EACH SUBLAYER, SEE ABOVE (MONTH SEP) UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 4,253E+02 SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.405E+02 ADSORBED SOIL (UG/G) 1.835E+02 SOIL NR (UG/ML) 3.162E+01 PURE PHASE (UG/ML) 1.282E+03 SOIL MOISTURE (UG/ML) 1.732E-01 ADSORBED SOIL (UG/G) 2.263E-01 SOIL AIR (UG/ML) 3.900E-02 MAX. POLL, DEPTH (M) 2.444E+01 YEAR - 10 ANNUAL SUMMARY REPORT - HYDROLOGIC CYCLE COMPONENTS - AVERAGE SOIL MOISTURE ZONE I (%) 9.710 AVERAGE SOIL MOISTURE BELOW ZONE 1 (%) 9.710 TOTAL PRECIPITATION (CM) 15.542 TOTAL INFILTRATION (CM) 15.535 TOTAL EVAPOTRANSPIRATION (CM) 3,648 TOTAL SURFACE RUNOFF (CM) 0.000 TOTAL GRw RUNOFF (CM) 12.131 TOTAL MOISTURE RETENTION (CM) q3.244 TOTAL YIELD (CM) 12.138 POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 8.202E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER I SOIL MOISTURE (UG/ML) 5.959E+01 ADSORBED SOIL (UG/G) 7.785E+01 SOIL AIR (UG/ML) 1.343E+01 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 2.182E+04 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 1.418E+00 ADSORBED SOIL (UG/G) 1.853E+00 SOIL AIR (UG/ML) 3.196E-01 MAX, POLL DEPTH (M) 2,476E+01 YEAR - 20 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 8,751E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.199E+01 ADSORBED SOIL (UG/G) 6.792E+01 SOIL AIR (UG/ML) 1.172E+01 SOIL MOISTURE (UG/ML) 1,750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3,944E+01 PURE PHASE (UG/ML) 2.251E+04 SOIL MOISTURE (UG/ML) 2.796E+00 ADSORBED SOIL (UG/G) 3.653E+00 SOIL AIR (UG/ML) 6.302E-01 MAX. POLL, DEPTH (M) 2,511E+01 YEAR - 30 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 8.773E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.168E+01 ADSORBED SOIL (UG/G) 6.752E+01 SOIL AIR (UG/ML) 1.165E+01 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 2,202E+04 SOIL MOISTURE (UG/ML) 4.174E+00 ADSORBED SOIL (UG/G) 5.453E+00 SOIL AIR (UG/ML) 9.407E-01 MAX. POLL DEPTH (M) 2,547E+01 YEAR - 40 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 8.774 E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3' SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5,167E+01 ADSORBED SOIL (UG/G) 6.750E+01 SOIL AIR (UG/ML) 1.165E+01 SOIL MOISTURE (UG/ML) 1,750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3,944E+01 PURE PHASE (UG/ML) 2.147E+04 SOIL MOISTURE (UG/ML) 5.551E+00 ADSORBED SOIL (UG/G) 7,252E+00 SOIL AIR (UG/ML) 1,251E+00 MAX~ POLL. DEPTH (M) 2.582E+01 YEAR - 50 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 8.774E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.167E+01 ADSORBED SOIL (UG/G) 6.750E+01 SOIL AIR (UG/ML) 1.165E+01 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 2.093E+04 SOIL MOISTURE (UG/ML) 6.929E+00 ADSORBED SOIL (UG/G) 9.052E+00 SOIL AIR (UG/ML) 1.562E+00 MAX. POLL. DEPTH (M) 2.618E+01 YEAR - 60 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 8.774 E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.167E+01 ADSORBED SOIL (UG/G) 6.750E+01 SOIL AIR (UG/ML) 1.165E+01 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 2.038E+04 SOIL MOISTURE (UG/ML) 8.306E+00 ADSORBED SOIL (UG/G) 1.085E+01 SOIL AIR (UG/ML) 1.872E+00 MAX. POLL. DEPTH (M) 2.653E+01 YEAR - 70 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER I 8.774E + 09 LOWER SOIL ZONE: SUBLAYER 1 -- AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.167E+01 ADSORBED SOIL (UG/G) 6.750E+01 SOIL AIR (UG/ML) 1.165E+01 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 1.983E+04 SOIL MOISTURE (UG/ML) 9.684E+00 ADSORBED SOIL (UG/G) 1.265E+01 SOIL AIR (UG/ML) 2.183E+00 MAY~ POLL DEPTH (M) 2.689E+01 YEAR - 80 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 8.774 E + 09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.167E+01 ADSORBED SOIL (UG/G) 6.750E+01 SOIL AIR (UG/ML) 1,165E+01 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 1.929E+04 SOIL MOISTURE (UG/ML) 1.097E+01 ADSORBED SOIL (UG/G) 1.433E+01 SOIL AIR (UG/ML) 2.472E+00 MAX. POLL, DEPTH (M) 2,724E+01 YEAR - 90 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 8.774E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER 1 SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.167E+01 ADSORBED SOIL (UG/G) 6.750E+01 SOIL AIR (UG/ML) 1.165E+01 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 1.874E+04 SOIL MOISTURE (UG/ML) 1.223E+01 ADSORBED SOIL (UG/G) 1.597E+01 SOIL AIR (UG/ML) 2.756E+00 MAX. POLL. DEPTH (M) 2.760E+01 YEAR - 99 ANNUAL SUMMARY REPORT POLLUTANT MASS DISTRIBUTION IN COLUMN (UG) - NOTE: IF COMPONENT IS ZERO EACH MONTH, IT IS NOT PRINTED UPPER SOIL ZONE: SUBLAYER 1 SOIL ZONE 2: SUBLAYER 1 TOTAL DIFFUSED (UP) SOIL ZONE 3: SUBLAYER 1 8.774E+09 LOWER SOIL ZONE: SUBLAYER 1 - AVERAGE POLLUTANT CONCENTRATIONS - NOTE: ONLY NON-ZERO VALUES ARE PRINTED - UPPER SOIL ZONE: SUBLAYER I SOIL ZONE 2: SUBLAYER I SOIL ZONE 3: SUBLAYER 1 LOWER SOIL ZONE: SOIL MOISTURE (UG/ML) 5.167E+01 ADSORBED SOIL (UG/G) 6,750E+01 SOIL AIR (UG/ML) 1.165E+01 SOIL MOISTURE (UG/ML) 1.750E+02 ADSORBED SOIL (UG/G) 2.286E+02 SOIL AIR (UG/ML) 3.944E+01 PURE PHASE (UG/ML) 1.825E+04 SOIL MOISTURE (UG/ML) 1.336E+01 ADSORBED SOIL (UG/G) 1.745E+01 SOIL AIR (UG/ML) 3.011E+00 MAX, POLL, DEPTH (M) 2,792E+01 ************************************************ COMPLETED**************************************** G APPENDIX G SESOIL Output File Diskettes GROUNDWATER TECHNOLOGY