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HomeMy WebLinkAboutBUSINESS PLANTo the best of the undersigned's knowledge, information, and Belief formed at~er reasonable inquiry, these corrections and/or Administrative changes are tree, accurate, and complete. Signature Buttons Coleman PfintName Plant Manager Title 09/05/03 Date EPA Facility ID 11100000058206 Section 1. Registration Information' 1.1 Source Identification: a. Facility Name: Nestle Ice Cream Company b. Parent Company #1 Name: Dreyer's Grand Ice Cream Holdings c. Parent Company #2 Name: 1.2 EPA Facility Identifier: 100000058206 1.3 Other EPA Systems Facility Identifier: 93313crntn7301 1.4 Dun and Bradstreet Numbers (DUNS): a. Facility DUNS: b. Parent Company #1 DUNS: c. Parent Company ~2 DUNS: 1.5 Facility Location Address: a. Street 1: 7301 District Bird b. Street 2: c. City: Bakersfield d. State: CA e. Zip: 93313 ¢. County: Kern Facility Latitude and Longitude: g. Lat.(ddrmnss.s): 35 18 41.0 h. Long.(dddmmss.s): -119 05 i. Lat/Long Method: 14 Interpolation - Digital map source (TIGER) j. Lat/Long Description: CE Center of Facility 1.6 Owner or Operator: a. Name: Dreyer's Grand Ice Cream Holdings b. Phone: (510) 652-8187 Mailing address: c. Street 1: 5929 College Avenue' d. Street 2: e. City: Oakland f. State: CA g. Zip: 94618 '- 1.7 Name and title of person or position responsible for part 68 (RMP) implementation: a. Name of person: John Blacksill b. Title of person or position: Utilities/Facilities Supervisor 05.0 9/4/2003 12:30:54 PM Page 1 of 11. 1.6 Emergency contacti a. Name: b. Title: c. Phone: d. 24-hour phone: e. Ext. or PIN: 1.9 Other points of contact: Buttons Coleman Plant Manager (661) 398-3540 (661) 978-1743 a. Facility or Parent Company E-Mail Address: b. Facility Public Contact Phone: c. Facility or Parent Company ~ Homepage Address: 1.10 LEPC: Region 5 LEPC Inland South 1.11 Number of full time employees on site: 400 1.12 Covered by: a. OSHA PSM: Yes b. EPCRA 302: Yes c. CAA Title V: No Air Operating Permit ID: 1.13 osHA Star or Merit Ranking: No 1.14 Last Safety Inspection (by an External Agency) Date: 1.15 Last Safety InsPeCtion Performed by an External Agency: 1.16 Will this RMP inVOlve predictive filing?: No buttons.coleman(~icecream.nestle.com (661) 398-3500 01/16/2002 -OSHA 9/4/2003 12:30:54 PM Page 2 of 11 Section 1.17 Process(es) ,., a, Process ID: I Program L/evel 3 b. NAICS Code 31152 Ice Cream and Frozen Dessert Manufacturing c. Process Chemicals c.1 Chemical Name Ammonia (anhydrous) c.2 CAS Nr. 7664.41-7 c.3 Qty {lbs.) 100,000 Section 2. Toxics: Worst Case Toxics: Worst Case ID: 1 2.1 a. Chemical Name: Ammonia (anhydrous) b. Percent Weight of Chemical (if in a mixture): 2.2 Physical State: Gas Liquified by Pressure 2.3 Model used: 2.4 Scenario: 2.5 Quantity released: 34,276 lbs 2.6 Release rate: 973.0 Ibs/min 2.7 Release duration: 35.0 mins 2.8 Wind speed: 1.5 m/sec 2.9 Almospheric Stability Class: F 2.10 Topography: ' Urban 2.11 Distance to Endpoint: 1.20 mi 2.12 Estimated residential, population within distance to endpoint: 26,617 2.13 Public receptors within distance to endpoint: a. Schools: b. Residences: c. Hospitals: ' g. Other (Specify): EPA's RMP Guidance for Ammonia Refrigeration Reference Tables or Equations Gas Release Yes d. Prisons/Correction facilities: Yea e. Recreation areas: No f. Major commercial, office, or industrial areas: churches 2.14 Environmental receptors within distance to endpoint: a. National or state parks, forests, or monuments: b. Officially designated wildlife sanctuaries, preserves, or refuges: c. Federal wilderness areas: d. Other (Specify): No Yes Yes No No No 2.15 Passive mitigation considered: 9/4f2003 12:30:54 PM Page 3 of 11 a. Dikes: No d. Drains: No b. Enclosures: Yes e. Sumps: No c. Berms: No f. Other (Specify): 2.16 Graphic file name: Section 3. Toxics: Alternative Release Toxics: Alternative Release ID: 1_ 3.1 a. Chemical Name: Ammonia (anhydrous) b. Percent Weight of Chemical (if in a mixture): 3.2 Physical State: 3.3 Model used: 3.4 Scenario: 3.5 Quantity released: 3.6 Release rate: ' 3.7 Release duration: 3.8 Wind speed: 3.9 Atmospheric Stability Class: 3.10 Topography: Urban 3.11 Distance to Endpoint: Gas EPA's RMP*Comp(TM) Rupture disk/Relief Valve failure 18,649 lbs 1700.5 Ibs/min 11.0 mins 3.0 m/sec F 3.12 Estimated residential population within distance to endpoint: 3.13 Public receptors within distance to endpoint: a. Schools: No d. Prisons/Correction facilities: b. Residences: Yes c. Hospitals:. No g. Other (Specify): 3.14 Environmental receptors within distance to endpoint: a. National or state parks, forests, or monuments: b. Officially designated wildlife sanctuaries, preserves, or refuges: c. Federal wildemess areas: d. Other (Specify): 3.15 Passive mitigation considered: a. Dikes: No b. Enclosures: No c. Berms: No 3.16 Active mitigation consideredi a. Sprinkler systemS: b. Deluge system: e. Recreation areas: f. Major commercial, office, or industrial areas: d. Drains: No e. Sumps: No f. Other (Specify): No L Flares: No g. Scrubbers: No No No No No 9/4/2003 12:30:54 PM Page 4 of 11 c: Water curtain: No d.'Neutra!ization: No e. Excess flow valve 3.17 Graphic file name: No h. Emergency shutdown systems: No i. Other (Specify): Ammonia detection for Safety relief valve, High level control float switch and high level alarm float switch. Section 4. Flammables' Worst Case --- No Data To Report · Section 5. Flammables: Alternative Release --- No Data To Report Section 6. Accident History AccidentHisto ID: _8 6.1 Date of accident: 03/18/1995 6.2 Time accident began (HHMM): 6.3 NAICS Code of process involved: 31152 6.4 Release duration: 000 Hours (HHH) 03 Minutes (MM) 6.5 Chemical(s): a. Chemical Name Ammonia (anhydrous) 6.6 Release event: 6.7 Release source: a. Gas release: No a. Storage vessel: No b. Liquid spill/evaporation: Yes b. Piping: No c. Fire: No c. Process vessel: Yes d. Explosion: No d. Transfer hose:, - No 6.8 Weather conditions at time of event (if known): a. Wind speed: Units: meters/second b. Temperature: Degrees Fahrenheit c. Atmoshperic Stability Class: d. Precipitation present: No e. Unknown weather conditions: Yes 6.9 On-site impacts: Employees or contractors: a. Deaths 0 b. Injuries 1 c. Property damage ($): 0 0845 ~iAM ~'PM CAS Number 7664-41-7 e. Valve: No f.' Pump: No g. Joint: No h: Other (Specify): b. Quantity Released (lbs) c.% Weight Direction: 11 99.9 Public responders: * Public: 0 0 0 9/4/2003 12:30:55 PM Page 5 of 11 6.10 Known Off-site impacts: a. Deaths: b. Hospitalization: c. Other medical treatments: g. Environmental damage: 1. Fish Or Animal Kills: 2. Tree, lawn, shrub, or crop damage: 3. Water contamination: 4. Soil contamination: 5. Other (specify)i 6.11 Initiating event: a 6.12 Contributing factors: a. Equipment failure: b. Human error: c. Improper procedures: d. Overpressurization: e. Upset condition: f. By-pass condition: 6.13 otfsite*responders notified: 0 0 0 d. Evacuated: e. Sheltered-in-place: f. Property Damage ($): No No No No Equipment Failure Yes No No No No No Notified and Responded g. Maintenance activity/inactivity: Yes h. prOCess design failure: No i. Unsuitable equipment: No j. Unusual weather condition: No k. Management error: No L Other (Specify): 6.14 Changes introduced as a result of the accident: a. Improved or upgraded equipment: Yes b. Revised maintenance: Yes c. Revised training: yes d. Revised operating procedures: yes e. New process controls: Yes f. New mitigation systems: yes Section 7. Prevention Program 3 Process Id: 1 Prevention Program ID: 1 Prevention Program Description: 7.1 NAICS Code: ' 31152 7.2 Chemicals: Chemical Name Ammonia (anhydrous) g. Revised emergency response plan: h. Changed process: i. Reduced inventory: j. None: k. Other(Specify): No Yes No No The prevention Program 3 applies to the Ammonia Refrigeration system 0 0 0 9/4/2003 12:30:55 PM Page 6 of 11 7.3 Date on which the safety information was last reviewed or revised: 7.4 Process Hazard Analysis (PHA): a. The date of last PHA or PHA update: 11/01/2000 b. The technique used: What If: Checklist: What If/Checklist: HAZoP: Yes No No No Yes No c. Expected or actual date of completion of all changes from last PHA or PHA update: d. Major hazards identified: Toxic release: yes Fire: No Explosion: yes Runaway reaction: No Polymerization: No Overpressurization: Yes Corrosion: Yes Overfilling: Yes e. Process controls in use: Vents: Yes Relief valves: Yes Check valves: yes Scrubbers: Yes Flares: yes Manual shutoffs: yes Automatic shutoffs: yes Interlocks: yes Alarms and procedures: Yes Keyed bypass: Yes f. Mitigation systems in use: Sprinkler system: yes Dikes: No Failure Mode and Effects Analysis: Fault Tree Analysis: Other (Specify): 01/01/2003 Contamination: Equipment failure: Loss of cooling, heating, electricity, instrument air: Earthquake: Floods (flood plain): Tornado: Hurricanes: Other (Specify): ammonia incidents, facility siting, human factor, charging system, emergency systems, staff-up existing systems/modified systems. Emergency air supply: Yes Emergency power: Yes Backup pump: yes Grounding ~luiPn~nt: Yes Inhibitor addition: Yes Rupture disks: Yes Excess flow device: No Quench system: No Purge system: Yes None: No Other (Specify): Water curtain: Enclosure: No 12/01/2005 Yes Yes Yes Yes No No Nor- 9/4/2003 12,30:55 PM Page 7 of 11 Fire walls: No Blast walls: No Deluge sYstem: No g. Monitoring/detection systems in use: Process area detectors: Yes Perimeter monitors: No h. Changes since last PHA or PHA update: Reduction in chemical inventory: Increase in chemical inventory: Change processParameters: Installation of process controls: Installation of process detection systems: Neutralization: None: Other (sPecify): None: Other ISpeci~Y): No Yes Yes Yes Yes No No High level Alarms Installation of perimeter monitoring systems: Installation of mitigation systems: None recommer~ded: None: Other (Specify): 7.5 The date of most recent review or revision of operating prOcedures: 7.6 Training: a. The date of the most recent review or revision of training programs: . , b. The type Of training provided: Classroom: Yes On the job: Yes Other (Specify): No Yes No No 08/29/2003 01/01/2003 on and off site plant contracting training this would included frick, plc and reta certification programs and Site specific training class. c. The type of competency testing used: Written test: Yes Observation: Oral test: Yes Other (Specify): Demonstration: Yes 7.7 Maintenance: Yes a. The date of the most recent review or revision of maintenance procedures: b. The date of the most recent equipment inspection or test: c. Equipment most recently inspected or tested: Portable Emergency Exhaust System 7.8 Management of change: a, The date of the most recent change that triggered management of change procedures: b. The date of the most recent review or revision of management of change procedures: 7.9 The date of the most recent pre-startup review: 7.10 Compliance audits: · a. The date of the most recent compliance audit: 08/01/2003 08/01/2003 12/01/2003 01/01/2003 12/01/2002 0613012001 9/4/2003 12:30:55 PM Page 8'of 11 b. Expected or actual date of completion of all changes resuiting~from the compliance audit: 7.1i Incident investigation: a. The date of the most recent incident investigation (if any): b. The expected or actual date of completion of all changes resulting from the investigation: 7.12 The date of the most recent review or revision of employee participation plans: 7.13 The date of the most recent review or revision of hot work permit procedures: 7.14 The date of the most recent review or revision of contractor safety procedUres: 7:15 The date of the most recent evaluation of contractor safety performance: Section 8. Prevention Program 2 --- No Data To Report Section 9. Emergency Response 9.1 Written Emergency Response (ER) Plan: ' a. Is facility included in written community emergency response plan? ~ Yes b. Does facility have its own written emergency response plan? Yes 9.2 Does facility's ER plan include specific actions to be taken in response to accidental releases of regulated substance(s)? yes 9.3 Does facility's ER plan include procedures for informing the public and local agencies responding to accidental releases? . Yes 9A Does facility's ER plan include information on emergency heath care? ,yes 9.5 Date of most recent review or update of facility's ER p!an: 05/01/2002 9.6 Date of most recent ER training for facility's employees: 01/01/2003 9.7 Local agency with which facility's ER plan or response activities arecoordinated: a. Name of agency: city of bakersfield fire department b. Telephone number: (661) 326-3979 9.8 Subject to: a. OSHA Regulations at 29 CFR 1910.38: ~ yes b. OSHA Regulations at 29 CFR 1910.120: Yes c. Clean Water Act Regulations at 40 CFR 112: Yes d. RCRA Regulatio. ns at 40 CFR 254, 265,~and 279.52: yes e. OPA-90 Regulations at 40 CFR 112, 33 CFR 154, 49 CFR 194, or 30 CFR 254: · Yes f. State EPCRA Rules or Laws: yes 01/01/2003 08/01/2003 12/30/2003 01/01/2003 06/01/2003 10/01/2002 07/01/2003 9/4/2003 12:30:55 PM Page 9 of 11 g. Other (Specify): Executive Summary A. Describe the accident release prevention and emergency policies It is the intent of Nestle ice cream Company to provide a safe work environment for every employee and to protect them from injury and illness resulting from unsafe acts or conditions duringhours of employment. Nestle Ice Cream Company will also qomply with all federal, state, and local laws. The plant manager has the responsibility for leadership of the safety and health program, for its effectiveness and improvement, and for providing the safeguards required to ensure safe conditions. Ammonia safety programs are key components in the plant safety and health program. Nestel Ice cream Company exercises many precautions to prevent or minimize accidental releases of ammonia. These precautions include safety controls (alarms and automatic shutdown devices) which are designed to identify and p?event potentially unsafe conditions like pressure increases that could cause a system failure, a preventive maintenance program designed to maintain the on-going integrity of the system, a training program designed to ensure that the system is operated by qualified personnel, and emergency response procedures which enable trained personnel to respond quickly to upsets in the system. The PSM/RMP Coordinator is responsible for the management °fthe ammonia safety programs. B. Stationary source and regulated substances Handled ~ Nestle Ice Cream Company Bakersfield Plant produces ice-cream products for sale to the public. The facility operates an ammonia refrigeration system to freeze ice-cream products and also to operate the plant air-conditioning. The maximum ammonia inventory at the plant is approximately 101,000 pounds. Ammonia is the on. ly regulated substance handled at tl~e Bakersfield plant. c. Summary of Worst-case and Alternative release scenarios The Worst-Case toxic release scenado at the Bakersfield Plant involves the release of 34,276 pounds of ammonia over a 35 minute period due to the failure of the High Pressure Receiver (HPR), The HPR receiver has the capacity to contain a maximum ammonia inventory of 48,967 pounds at 100%. But because of written administrative procedures and mechanical controls in place at the plant to limit the amount of ammonia stored in the High Pressure Receiver to 70% (34,276 pounds) or less. The release rate also assumes that the enclosed engine room would limit the amount released to the atmosphere. Under worst-case conditions, the resulting vapor cloud could have off-site impacts. The Alternative toxic release scenario at the Bakersfield Plant involves the release of -18,649 pounds of ammonia over 11 minutes due to a pressure relief valve opening. The release duration was assumed to be limited by the response of the Utility Mechanics to the ammonia detector in this line and access platforms to the dual pressure relief valve. Under alternative release conditions, the resulting vapor cloud could have off-site impacts. The Worst-Case and alternative toxic release scenarios are unlikely for the following reasons: 1) Industry standards are followed for the design and manufacture of the equipment in the ammonia refrigeration system. 2) The ammonia receivers are well protected from vehicular treffic. 3) Pressure safety valves on the ammonia receivers should limit any pressure increases inside the receivers. 4) Ammonia detectors should readily detect releases from the pressure relief valves on the ammonia receivers. 5) Ammonia is not corrosive in this sen/ice. 6) The facility has a preventive maintenance program in place to maintain the on-going integrity of the ammonia refrigeration equipment. 7) The Facility has a training program designed to ensure that qualified personnel Operate the system. 8) The facility has emergency response procedures that enable trained personnel to respond quickly to 9/4/2003 12:30:55 PM Page 10 of 11 isolate any potential releases. D. Description of the Accidental Release Prevention program The facility has a program level 3 accident release prevention program for the ammonia system that complies with OSHA's Process Safety Management standard and EPA's Risk Management Program Regulation. The ammonia prevention program consists of the follow elements: 1 ) Employee Participation Program 2) Process Safety Information 3) Process Hazard Analysis 4) Operating Procedures 5) Training Program 6) Contractor Safsty Program 7) Pre-Startup Safety Review Procedures 8) Mechanical Integrity Program 9) Hot Work Permit Procedures 10) Management of Change procedures 11 ) Incident Investigation Procedures 12) Compliance Audit Procedures E. Five Year Accident History One ammonia-related incident was identified for the Bakersfield Plant during the previous five years that resulted in signifiCant on-site consequences. The amount released was eleven (11) pounds of ammonia. The on-site Injury had no offsite consequences. Upgraded oil removing equipment with new process controls were implemented as a result of this accident. F. Description of the Emergency Respor~se Program An Emergency response program is in place at the Bakersfield Plant. This program contains procedures deScribing hew the facility will respond to fires, ammonia leaks and other emergencies, including evacuation pro~:edures.. The Emergency response program includes the following elements: 1) Fi;e Plan 2) Ammonia Leak Procedures 3) EVacuation Procedures ' 4) Responsibilities of the Emergency Response team **The above Program has been coordinated with the Bakersfield fire Departmentl G. Planned Changes to Improve Safety to the ammonia refrigeration system 1 ) Y2K compliant action plan addressed problems and items to bo replaced. Replacement of items will be completed before 12/31/1999. (Completed in 1999) 2) Seismic action plan is in place. Proposals for a Seismic Analysis are pending at this time. Once Seismic items are addressed they will be evaluated and implemented as required. (completed 2002) 3) Pipe insulation action plan is in place. Three-year replacement plan was established- in year 2 of the plan at this time. (Completed in 2001 ) ' ,, 4) Install ammonia to air treatment system for emergency exhaust fans and safety relief valve header. (Completed in 2oo2) RMP~ ValidafionErrors _._ No Data To Report 9/4/2003 12:30:55 PM Page 11 of 11 ~.....Howardwi~ne~ ~.. Ch'eCked O~tside raw tanks, t~rRe'i~ate p__ip_in-_gl._(T~sk~c~eted)... ...... From: To: Date: Subject:' "Balfour, MeI,BAKERSFIELD,Engineering,, <mel.balfour@icecream.nestle.com> <Hwines@ci.bakersfield.ca.us> 6/17/02 4:16PM Checked Outside raw tanks, then Re-insulate piping. (Task completed) 06/17/02 Howard: As in reference t° outside raw tank piping. On our Tuesday walk-through you were concerned about the outside appearance/Mech integrity/or appearance of some corrosion of (2) UN-insulated 2" pipe at the outside raw-tanks #1 & #2. I had Valley x-ray here Saturday 6-15 to do a profile x-ray on both 2" pipe's. The x-ray looked good with no wall loss. Also today 6-17, ASI (insulation contractor) will be here to repair insulation on both pipe's. If You need supporting documentation of the X-ray and insulation repair please give me a call. Mel CC: "Redman,Gary, BK PLANT,Maintenance" <gary.redman@icecream.nestle.com>, "BlacksilI,John,BAKERSFIELD,Maintenance- <john.blacksill@icecream.nestle.com> Cause and Effect of Ammonia Vapor Detection in Machinery Spaces Revised 5/28/02 Prepared for: Ice Cream Partners 7301 District Boulevard Bakersfield, CA 93313 Prepared by: The Stellar Group 2900 Hartley Road Jacksonville, FL 32257 Cause and effect of Ammonia Vapor Detection II. Scope of Document The intent of this document is to define the cause and effect of action to be taken when detecting refrigerant at various ppm levels within the confines of a Refrigeration Machinery Room. These recommendations are in accordance with the 1998 California Mechanical Code and the 1997 Uniform Fire Code, which the City of Bakersfield has adopted and declared to be the code for the city. The State of California has recently adopted the 2000 Uniform Fire Code and it was considered in anticipation of its adoption by the City of Bakersfield. Definitions and assumptions A. Definitions (from 1998 California Mechanical Code unless stated otherwise) 1. PEL (Permissible Exposure Limit) is the maximum permitted eight-hour time-weighted average concentration of an airborne contaminant. The maximum permitted time- weighted average exposures to be utilized are those published in 29 C.F.R. 1910.1000. 2. 'Refrigerant Safety Classifications: are groupings that indicate the toxicity and flammability classes in accordance with Section 1102. 3. IDLH (immediately dangerous to life and health) is a concentration of airborne contaminates, normally expressed in parts per million (ppm) or milligrams per cubic meter (mg/m3), whiCh represents the maximum level from which one could escape within 30 minutes without any escape-impairing symptoms or irreversible health effects. The National Institute of Occupational Safety and Health (NIOSH) establishes this level. 4. LFL (lower flammability limit) is the minimum concentration of a combustible substance that is capable of propagating a flame through a homogeneous mixture of the combustible and a gaseous oxidizer under the specified condition of test. The LFL is sometimes referred to as LEL (lower exposure limit); for the purpose of this definition, LFL and LEL are identical. 5. Machinery is the refrigeration equipment forming a part of the refrigeration system, including, but not limited to, a compressor, a condenser, a liquid receiver, an evaporator and connecting piping. 6. Refrigeration Machinery Room is a space that is designed to safely house compressors and pressure vessels. 7. Pressure Vessel is a closed container, having a nominal internal diameter exceeding 6 inches (153 mm) an a volume exceeding 1 V2 cubic feet (42 L), for liquids, gasses, or vapors subjected pressures exceeding 15 psi (103 kPa). 8. Stop Valve is a device to shut off the flow of refrigerant. B. Assumptions For the purpose of this document the following properties for ammonia will be used as published in the 1998 California Mechanical Code Table 11-A. The limits defined here are the maximum allowable, lower limits as suggested by Jeff Arita can be substituted at your discretion. 1. Safety Group = B 1 2. PEL=25 ppm 3. IDLH = 500 ppm 4. LFL = 15.5% by volume, therefore 25% LFL = 38,750 ppm 2 of 4 04/11/03 Cause and effect of Ammonia Vapor Detection III. Cause and Effect · Ammonia Machinery Room Detection Level (cause) Resultant Actions (effect) 25 ppm Audible and Visual (A/V) ammonia alarms actuated Either ppm detector at 25ppm At this detection level the following will occur: ~ ~^*~ ~ ~ ........ ~ 1. Activate an approved audible signaling device capable of ppm generating a sound pressure level at least 15dB above ambient along with a visual alarm. The audible alarm can be silenced after the ammonia alarm has been acknowledged. The visual alarm shall remain active until the ammonia alarm is reset manually (both detectors below 15 ppm). 2. The ammonia detection system will transmit a 25 ppm ammonia alarm to the plant alarm system and to the local HMI, which will activate the Utility personnel paging system. 3. All non-essential personnel shall evacuate the machine space. .4,~We recommend that enacting the prc;'isicns cf Article ! 107.4 cf 150 ppm Emergency purge fans activated either detector > 150 ppm At this detection level the following will occur: 1. Activate the audible signaling device (a second time if previously activated at 25 ppm): The audible alarm can be silenced after the ammonia alarm has been acknowledged. The visual alarm shall remain active until the ammonia alarm is reset manually (both detectors below 15 ppm). 2. Emergency purge ventilation fans shall be automatically activated. The fans intended for this purpose shall meet the requirements for a Class I, Division I hazardous location and shall be equipped with an airflow s.ensing switch that will control flow/no-flow indicating lamps. Condenser spray pumps are interlocked to this system. The ventilation shall be manUal reset only when all detectors are below 150 ppm. 3. The ammonia detection system shall transmit a second alarm to the plant alarm system and the local HMI to indicate the 150 ppm level. A second alarm will be sent to utility personnel paging system. 3 of 4 04/11/03 Cause and effect of Ammonia Vapor Detection >10,000 ppm One LEL sensor >10,000 ppm Two LEL sensors > 10,000 ppm o_Er one LEL and two ppm sensors in alarm mode or failure mode. Emergency shutoff of electrical equipment At this detection level the ammonia detection system shall transmit a 10,000 ppm alarm to the local HMI which will activate the utility personnel paging system. At this detection level the following will occur: 1. All electrical power, which does not conform to Class I, Division I, Group D requirements shall be automatically de-energized within the machinery space. Emergency fans, emergency lighting and fire and ammonia detection systems must conform and remain energized. If not connected to the emergency power system the ammonia detection system must have a secondary power supply. 2. The ammonia detection system shall transmit a 10,000 ppm\Shut Down alarm to the plant alarm system and the local fire department should be notified. 3. Consider evacuation of all non-essential personnel in facility. Notes on system design: 1. The ppm alarm transmission to the plant alarm system shall be supervisory only. 2. The water pumps to the condenser shall run in the manual mode all the time. 3. The ammonia system controls and the ammonia detection system will have UPS backup. The UPS system shall be feed by a circulate that can be readily switched over to backup power (2.0KVA generator). The LEL sensor/shutdown control system shall have a maintenance mode to prevent false shutdowns during Preventive Maintenance. Flow switches will be installed to the four emergency exhaust fans. Acknowledgment switch will be located in the Room being monitored. The switch must be used for all PEL alarms. Alarms of 150 PPM of more can be acknowledged either by the acknowledgment switch or electronically. An alarm must me acknowledged before it can be silenced. All alarms can be silenced electronically. 8. Rooms being monitored will have both audible and visual alarms. 9. All entrances to rooms being monitored will have visual alarms only. 10. A fire alarm pull station will be installed in the guard station to facilitate an evacuation at the Indent Commander's discretion. 11. Stellars' recommendation (Item 4) under "Resultant Actions (effect)" column at the 25 PPM level to "automatically control one exhaust fan for intermittent operation between 50 'and 35 ppm" is not necessary. Both rooms currently have continuous mid-level exhaust in operation. 12. To limit fault alarms, the 25 PPM alarm shall be activated when any 90 seconds average Of the PPM meter reading equals or exceeds 25 PPM. This running 90 second average will the average of data 90 points taken one ever second. That is, when one data point is taken, the oldest data point will be dropped off of the average. This averaging system will limit our exposure to spikes and or faults alarms. ¸7. 4 of 4 04/11/03 AC#3. HAZARD ASSESSMENT ON ALTERNATIVE CASE SCENARIO Alternative Release scenarios Ice-cream freezer liquid Line Scenarios: Liquid Line at an ice-cream freezer: A forklift hit's the liquid Line on an Ice Cream freezer and caUsed the ½" flange bolts to shear. Using RMP Comp, Urban, inside an enclosed space and liquid under pressure the release amount would be, 587 pounds/min. X 30 ·minutes = ,1 miles to toxic end£oint. Normal Operation: 1. The ice cream freezers are scraped-surface heat exchanger used to freeze ice cieam. The freezers use high pressure pumped liquid ammonia with a suction'pressure of-38 degree/7" vacuum, a suction regulator controls temperature at the freezer. Freezers are feed from the High Pressure Receiver (HPR).' Liquid, hot-gas and suction Stop valves at the freezer are normally open and pumpout stop valve at freezer is normally closed. ' ' ~ The Cause A forklift hitting a ice cream freezer is not likely due to over the last Couple 0fyehrs Ice cream freezer having the potential of being hit by forklift were addressed as a Safety issue so 4" Ballard's were installed for added protection. Other scenario's that could cause 'damage to the liquid and/or hot-gas piping and/or flanges could cOme from a badEarthquake, although pipe braces has been upgraded. Loose flange bOlts and/or faulty flange gaskets. ''2. The Effect from the Scenario Due to the amount of people that may be working on the Production'floor andif this happens during a production time period this would be a major incident. The first main focus would be to safely get the people out and away from the production floor and then get a good; quick and accurate head count. The pounds of liquid ammonia loss in just 4-5 minutes from a 1/2" Line could be' as high as 1,500 pounds. Depending on the leak location, it is important that the people are directed to the proper exits (directed through and away from the leak), so the frrst hi,'ghest priority is proper communication of non-utility trained Haz-mat personal to direct them to proper exits. Utility as a first main focus is tO insolate and ventilate from a remote location outside the production floor perimeters. Do note the ammonia loss vapor would not be washed through the production floor ventilation syStem, so as soon as all personal has left the production both emergency exhaust systems located in stagi~ng area and engine room would need to be turned "On" and production floor exhaust system turned "off". (Mel) .Steps Needed to Correct Deviation (Scenario): 1. Use "All Call" on the Nextel radio's to inform management and the emergency responders to evacuate. the building and deny entry into the building. Personal will need to be directed away from leak during the evacuation process. l 07/22/03 11. Al~o Utility team needs to immediately Inform management 'that the ie~k "hazard risk"']s high, and that' the "Incident command system" (ICS) needs to be formulated ~ing the Nestle Emerge,ncy Response team.and the fire departments Haz-Mat team as a "Unified incident command. System".~ ? The utility team will need io immediately shutdown (Off} the "Emergency shutdown contr0i. valves". At one of three locations, whichever location at'the time is the safes to get to shutoff control switcheS. - · On the mairi Refrigeration control system computer located in the Utilffv office · · On the Laptop Refrigeration control system computer located in AHU#13 equipment room.. ·" On the labeled 'Emergency shutdown control valves' toggle switches located in the MCC ... TOO1TL Do to the leak's high PPM level in the production floor, the Production floor Air handler units should akeady be in the 100% purge mode. The production floor ammonia detectors thrOugh the refrigeration control system activate automatically this purge mode. Note that the production floor AHU's air purge system does not wash the ammonia vapor air released to the outside. Once the entire production floor has been evacuated of personal, then turn "On" the "Engine Room Emergency Exhaust Fans" and "Staging room Emergency Exhaust Fans", Then'mm ?Off" The · production flpor Air handler 100% purge. The emergency exhaust fans 'will force the Airflow of the . ammonia/air, mixture from the production floor area North and South side. The ammoniaJair mixture will then flow into the water/ammonia washers, reducing Or eliminating ammonia outside/offsite consequences. Note leave open engine room door and Staging room door leading into production floor. The Emergency response team must establish site cont[. 01 zones and Incident command post quickly. Using the Laptop refrigeration control computer located in AHU#13 equipment room, establish a safe remote location to monitor the entire plant condition's, such as (PPM, Pressure, etc.) Using the Laptop, Shutdown (de-energize) all positive pressure suctions and their liquid and Hot-gas solenoids. This is to prevent back-feed pressure from getting into the High-pressure liqtiid piping. · All controls for shipping and palletizing. · All controls for 40-degree room. ' ' · · All controls for water and glycol chiller's. ' · All liquid solenoids for all mix and raw tanks. Assess the total incident/situation as a team in a "Unified Incident Command System's. From approval from the ICS: and using a respiratory andbuddy system monitor the ammonia PPM's at the property fence Line and at the roof. (If above 250 PPM's return to the ICS Post). Only from approval from the ICS, will Production floor entry be allowed. With ICS Approval, the emergency response team may enter the Production floor to.get an added assessment of the situation and/or isolating the ice cream freezer, stop valve/valves. Do note; before entering the Production floor make sure that the PPM's are low but also stabilized for a period of time, with a downward trend of lowering PPM levels. (If at all possible and if approved from ICS enter Production floor when the PPM level are less than 300-PPM). .. After incident is over and PPM's are zero, and all affected piping,'stop valves and freezers are tagged and locked-out then schedule for replacement and/or repair. 07/22/03 .,Avoiding Deviation (Scenario)- !. 2. o ProPerly train.f0rklift ' ' ~' ' ' : ' dr!vets of the hazards of ammonia, attached ammonia piping and freezers. During production and clean-up keep forklifts out'of the freezer area, oniy the main isle way'shou!d have motor foiklift traffic and theses freezer are Pr?tect.ed by 4'i Ixaffic Ballard's... contractors that may be working near or on freezer with motor traffic need to be trained in the hazard of ammonia, its freezer with it's attached piping. -~ . Safe . Protective E ui ment and General standardPrecautions: 1. 2. 3. 4. 5. Emergency team. -: Buddy system. · May need SCBA and level "A" suit. Follow emergency response plan guidelines .and safety procedures. Need to use Nestle and the Fire department Haz_Mat teams Unified Incident Command System". .Additional comments Check the mechanical integrity of the flange bolts on ice cream freezers during a yearly shutdown PM. " Need door stops on engine room and staging.room doors leading tothe production side, this will hold doors opening while Emergency exhaust fans are. "on" to lower the levels of ammonia in. the production. .~ Written by Mel Balfour and the Utility Tearh 2002 07/22/03 California Business Search DISCLAIMER: The information displayed here is current as of DE~ 05, 2003 and is updated weekly~ It is not a complete or certified record of the Corporation. Page 1 of 1' DREYER'S GRAND ICE CREAM, INC. 5929 COLLEGE AVENUE OAKLAND, CA 94618 MARK LEHOCKY 5929 COLLEGE AVENUE OAKLAND, CA 94618 Agent for Service of Process For information about certification of corporate records or for additional corporate information, please i'efer to Corporate Records. If you are unable to locate a corporate record, you may submit a request to thig office for a more extensive search. Fees and instructions for requesting this search are included on the Corporate Records Order Form. Blank fields indicate the information is not contained in the computer file. If the status of the corporation is urrenaer, the agent for service of-process is automatically revoked. Please refer to California Corporations Code Section 2114 for information relating to service upon corporations that have surrendered. · http://kepler, ss.ca.gOv/corpdata/ShowAllList?QueryCorpNumber:=_C 1295644&printer=yes 12/9/2003 California Business Search .·~.. .. :. Pagelof:l 5929 COLLEGE AVE OAKLAND, CA 94618 MARK LEHOCKY 5929 COLLEGE AVE' OAKLAND, CA 94618 Mailing Address' Agent for Service of ProCess StatuS: active For information about certification of corporate records or for additional cOrporate information, please~ refer to Corporate Re~ords. If you are unable to locate a corporate record, yOu may submit a request to this ·office for'a more extensive search. Fees and instructions for requesting this search are included on the Corporate · Records Order Form. ' ' · ' - ' ~ i:~ Blank fields indicate the information is not contained in the comp~lter file. ' ' ' ' If the status of the corporation is-"Surrender", the agent for service of proces~ 'is automatically)/evoked:' Please refer to' California Corporations Code Section 2114 for inforrfiati0n relating to service'upon corporations that have surrendered. h~tp://kep~er.ss.ca.g~v/c~rpdata/`Sh~wA~List?QueryC~rpNumb~er=C~9~93&print~r=-yes~:..~. 1~2]9/2003 ~: . '-' Jurisdiction: California Corporation DREYER's GRAND ICE CREAM FOUNDATION .' C1190093. Date Filed: 2/26/i986' DISCLAIMER: The information displ~yed here is current as of DEC 05~ 2003 an~i'isfipdat~d ~ekly. It is no[ a complete or certified {ecord of'the Corporation. - District Boulevard . Response Team Stagir Truck Was ,ge Area . lj]~, ' B:. Response Team Staging Area Wastewater Raw Receiving Front Office Team ~ndler Unit 13, 75 5O 4~ 30 15 0 30 60 90 GRAPHIC SCALE Incident 150 Post (ICP) ce Room Legend Assembly Areas Nestle Ice Cream Company RA.KEP. ut*-, ~u.~, CA 93313 = I~'- "'-I "F'-- District Boulevard 2 Level 5 SCBA West Wall of Drumsticks Area South Truck Wash 2 Level A ge Area :heroical Storage J] Raw Receivfl'~iesmtixities°en~l i i,,1 Front Office Air 5 7560453015 0 30 GRAPHIO SCALE 150 13 ployee y Area __ Lesend Air Meter SCBA/Level A Suits Emergency Response Bags Respirators Spill Kits Nestle lee Cream Compfu~y ::Burrel, Manuel '!Oleveland, Gerald 'i¢~rona; Js Sm ~,J~hnston, Dean Legasey, Leroy Medina, John Ranney, Eric Redman, Gary · 'Facilitie~{ilities -,~aciliti~ities ' ' Faeilifi esPtJtiiities' Facilities/Utilities Faci.lities/adfilities M~nten~ee M~i. nten~¢¢ M~tena~ce Maintenance Maintena. nce Maintenance Maintenance Miihtenance. Ma~t~a'.nce Ma/ntenanee Maintenance · Maintenance Maintenance Maintenance Maintenance Saenz, Alex Maintenance ~'hompson, David Maintenance W~lf, Tommy Maintenance Borg, Jeff - EPSU Calso, Daniel EPSU Gardner, Janice McDaniel, Paul Padilla, Jose Sparks, David Colemanr Buttons EPSU Reinwald, John ' H¢ffmann, Dave EPSU EPSU EPsu Admin · Admin Admin Keenan, Walter HR Carter, Norman Engineering · Gilmore, John Mejia, Tony Friebel, Jennie EHS EHS EHS 2002'HAZWOPEI~ Personnel .List.d°c _ :~'~i:~uia~ce C;~,mpany .'. ~. : . ..':. :...' 327~9~0~,, : :.:'., ~ ' . ..... HosPital ':~. :', 39.523,000 San~Joaqum Commumty , ... ~F&e ~epam~ent Station No. 9 ... G~ R~ Al~mate hcidem Co~d~ Home Phone - 663~869t ' Nextel Name - Nomn C~r- ~o~ C~ef Home Phone - 665-8734 N~tel Nme - C~TER Mel B~om - H~do~ Matefi~s Speci~ist Home Phone - 6~-4535 Nemei Na~ - B~FOU~ Office.- 4829 Jo~ Blac~ill - En~ Tern Leader Cell Phone - 978-1997 Nextel Name - B~S'~L Office - 3590 lohn Gilmore - S~e~e~c~ Officer Cell Phone - 978-1736 , N~xtel Name - GILMO~ Office - 4802 Ca~ Wright - Site Access Leader . Home Phone - 664,0380 J6~ Keinmld - Incident Co~der Cell Phone, 201-9693 '. Ne=el N~ - ' ' ' ~ficc - 3540 Buaom Coleman - Pubhc l~omfion Officer Cell Phone - 978-1743 '. Home Phone- 588-1576 . Nexte! Nme - G~D~R Dave Sparks - Alternate Incident Comnder, ~blic Infom~afion Office, -. Office = 3552 Safety~edical Officer · . Home Phone - 397-5976 ." Nextel N~e - SPA~KS Version of 10/27/03 2003 Emergency Notification Phone List~doc ' ~. '~,:':..~: .... Qom~ugity Hospital San:'loaqum " ', . .... :,, :~ ..... F~e Depa~,ent Station No. 9 · · .: - ,, .., , .. · . .Fw'. <,,[..:: G~y Re~- ~te ~cident Co~der Ho~ Phone - 6~3~869t NeWel Name Nomn C~er - ~mfiom Chef Office - ~ Home Phone - 665-8734 Nex~l Nme - CA~TER. Offi~ - 3568 Mel Balfo~ - H~o~ Matefi~s Sp~iflist Home Phone - 6~-4535 NeWel Na~ - B~O~ Office - 4829 Jo~ Blac~fll - En~ Tern Leader ' Ce~ Phone - 978-1997 Nemel Name - BLA~S~L - · Office - 3590 John Gilmore - S~e~e~cal Officer ' ' Ce~ Phone - 978-1736 Nexml Name - GIL~O~ OffiCe - '4802~ Ca~ Wright ~ Site Access Leader Home Phone -'664.0580 h dent Co der Cell Phone- 201-9693 Nex~l Nm - · Office - 3540 Bu~o~ Coleman - Pubhc I~omfion Offic~ CeB Phone - 978-1743 "~'~:~ '~'?" ~ ...... ........ ? '?' ........ ..... ~ ' ' "Home Phone - 588-1576 J~me G~'~er ~c~aent Co~anaer ............. -' Nextel Nme - G~R Dave Sparks -Alternate Incident Comnder, Public Iffomafion Office, · Office - 3552 Home Phone - 397-5976 S~ety~edical Officer , Nextel Name - SPA~S Version of 10,27/03 2003 Emergency'Notification Phone.l.is~doc Hazaf o, s aSe a h Response Team Training Level & CertifiCation Dates Revised July, ~003 Capt. Engr Battalion Chief Hartley (S) '92 A S,h[ft B Shift J.. Adams (S)'92 Capt. S. Silvius (S)'93 Engr. P. Trembush (S)'96 F.F. E. gaagel (S)'87 Capt. S. Casavant (S)'93 Engr. T. Capehart (8)'9! F.F. c sh t J. Germanetti (S)'95 P. Ponce (S)'95 M. Lencioini (T) '01 Alterna, tes Capt. A. Roberts (S)'92 Capt. G. Moore (T) '01 Capt. P. Caprioli (T) '89 Engr. T. Sturgeon (S)'96 Engr. T. Meert (T)'99 Engr. A. Galagaza (T)'99 Engr. D. Bryan (S)'98 F.F.B. Childress (T)'01 Capt. S. Phillips (S)'92 Capt. B. Ballard (S)'00 Capt. B. Snider (S)'95 Capt. T. Lynch (S) '01 Capt. J. Weber (S) '01 Engr. D. Haining (S) '01 Engr. C. Paulden (S) '96 Engr. D. Tisinger (S) '89 Engr. P. Nunez (T) '01 Engr. A. Moore (T) '01' F.F.T. Payne (S) '96 F.F.J. Powell (S) '91 F.F.T. Ortiz (S)'01 F.F.D. Mojica (T) '01 Capt. B. Perry (S)'93 Capt. T. Martinusen (S)'97 Capt. S. Dietz (T) '01 Eng. J. Cherry (S) '96 · Engr. B. Macauley (S) '93, Engr. R. Tilford (T) '89 Engr. G. Pacheco (T) '01 F.F.J. May (S) '96 F.F.B. ward (T) '01 F.F.R. Pratt. (T) '01 Environmental Services Division R. Huey (T) '94 H. Wines (T) '97 S. Underwood (T) '99 Key. S = Specialist T = Technician * = No Haz Mat Training Arson Investigation Captain E. Watts (S) '93 Confined Space OPerations T. Hartley T. Martinusen B. Ballard A. Galagaza B. Srdder *C. Senior *S.'Smith *J. Yates *M. MaXwell *C. Crawford *S. Myers *R. Groves P. Caprioli T. Ortiz J. Weber P. Trembush C. Paulden ' J. Germanetti P. Ntmez P. Ponce D. Haining *A.J. Clark *M. Taylor *S. Jallo *J. ~Queen *d. Olle ~ *T. Patterson *K. Albertson *C. Bordon *E. Gardner *F. Molina C:\TEMPXHaz Mat Response Teaml .DOE: Bakersfield. Fibre B! pa ment Hazargoas .ReSPonSe Team Training ,Level & Certification Dates Revised July; 2003 Capt. Engr F .F 'Battalion ChiefHartley (S} '92 A S'hffi B Shi,ft J.. Adams (8)'92 Capt. S. Silvius (S)'93 Engr. P. Trembush (S)'96 F.F. E. Rangel (S)'87 Capt. S. Casavant (S)'93 Engr. T. Capehart (S)'91 F.F. C Shift J. Gerinanetti (S),95 P. Ponec (S)'95 M. Lencioini (T) '01 Alternates Capt. A. Roberts (S)'92 Capt. G. Moore (T) '01 Capt. P. Caprioli (T) '89 · gngr. T. Sturgeon (S)'96 Engr. T. Meert (T)'99 Engr. A. Galagaza (T)'99 Engr. D. Bryan (S)'98' F.F.B. Childress (T) '01 Capt. S. Phillips (S)'92 Capt. B. Ballard (S)'O0 Capt. B. Snider (S)'95 Capt. T. Lynch (S)"01 Capt. J. Weber (S) '01 Engr. D. Haining (S) '01 Engr. C. Paulden (S)'96 Eng. D. Tisinger (S) '89 Engr. P. Nunez (T) '01 Engr. A. Moore (T) '01 F.F.T. Payne (S) '96 F.F.J. Powell (S) '91 F.F.T. Ortiz (S)'01 F.F.D. Mojica (T) '01 Capt. B. Perry (S)'93 Capt. T.. Martinusen (S)'97 Capt. S. Dietz (T) '01 Eng. J. Cherry (S) '96 Engr. B. Macauley (S) '93' Engr. R. Tilford (T) '89 Engr. G. Pacheco (T) '01 F.F.J. May (S) '96 F.F.B. Ward (T) '01 F.F.R. Pratt (T) '01 Environmental Services Division R. Huey (T) '94 H. Wines (T) '97 S. Underwood (T) '99 Key. S = Specialist T = Technician * = No Haz Mat Training Arson Investigation Captain E. Watts (S) '93 C:\TEMP\Haz Mat Response Teaml .DO(: Confined sPace OPerations T. Hartley T. Martinusen B. Ballard A. Galagaza B. Snider *C. Senior *S. Smith *J. Yates *M. Maxwell P. Capri01i T. Ortiz J. Weber. P. Trembush C. Paulden J. Germanetti P. Ntmez P. Ponec D. Haining *A.J. Clark *M. Taylor *S. Jallo .*J. Queen *J. Olle *T. Pattersbn *K. Albertson *C. Crawford. *C. Bordon *S.'Mvers *E. Gar&~er *R. Grov~'s *F. Molina AC#3 HAZARD ASSESSMENT 'ON WORST AND ALTERNATIVE CASE SCENARIOS Alternative Release scenarios Ice-cream Freezer LiqUid Line Scenarios: Liquid Line at an ice-cream freezer is struck: A forklift hit's the liquid Line on an Ice Cream freeZer and caused the lA" flange bolts to shear: Using RMP Comp, Urban, inside an enclosed space and liquid under pressure the release amount would be, 587 pounds/min. X 30 minutes = .1 miles to toxic end£oint. Normal Operation: 1..The ice cream freezers are scraped-surface heat exchanger used to freeze ice cream. The freezers use high pressure pumped liquid ammonia with a suction pressure of-38 degree/7, vacuum, a suction regulator controls temperature at the free~.er. Freezers are feed from the High Pressure Receiver (HPR). Liquid,.hot-gas and suction Stop valves at the freezer are normally open and pumpout stop valve at freezer is normally closed. The Cause A forklift hitting a ice cream freezer is not likely due to over the last couple of years Ice cream freezer having the potential of being hit by forklift were addressed as a safety issue so 4" Ballard's were installed for added protection. Other scenario's that could cause damage to the liqUid and/or hotrgas piping and/or flanges could come from a bad Earthquake, although pipe.braces has been upgraded. Loose flange bolts and/or faulty flange gaskets2 ge The Effect from the Scenario Due to the amount of people that may be working on the produCtion floor and if this happens during a production time period tl-/is would be a major incident: The first main focus would be to safely get the people out and awaY from the production floor and then get a good, quick and accurate head count. The pounds of liquid ammonia loss in just 4-5 minutes from a 1/2" Line could be as high as 1,500 pounds. Depending on the leak location, it is important that the people are directed to the proper exits (directed through:and away from the leak), so the first highest pri9rity is proper communication of non-utility trained Haz-mat personal to direct them to proper exits, Utility as a first main focus is.to insolate and ventilate from ~t remote' location outside the production floor perimeters. Do note the ammonia loss vapor would not be washed through the production floor ventilation system, so as soon as. 10/27/03 all perSonal has left the production both. emergency exhaust Systems located in stagi.ng area and engine room would need to be turned "On" and production floor~ exhaust system turned ,,off,,. (Mel) ' Step~ Needed to Correct DeViation (Scenario): 1. o Use "All Call" on the Nextel radio's to infOrm.management and the emergency resPonders to evacuate the building and deny entry into the building. Personnel will need to be directed away from leak during the evacuation Process. Also Utility team needs to immediately inform management thatlthe leak "hazard' risk" is high, and that the"Incident command sYstem" (ICS) needs to be formulated using the Nestle Emergency Response team and the fire departments Haz, Mat team as a "Unified Incident Command System". _ '~. The utility team will need 'to immediately shutdown (Off} the "Emergency shutdown control valves". At one of three locations; whichever location at the time is the safes to get to shutoff control switches. · On the main Refrigeration control system computer located in the utility office · On the Laptop Refrigeration control system computer l°catedin AHU#13 equipment room.. . · On the labeled 'Emergency shutdown control valves' toggle switches located in the MCC room. 4. ' Do to the leak's high PPM level in the production floor, the Production floor Air ' handler traits should already be in the 100%, purge mode: The production floor ammonia detectors through the refrigeration control system activate automatically .this purge mode. Note that the production floor AHU's air purge'system does not wash the ammonia vapor air released to the outside'. Once the entire production floor has been evacuated of personal, then turn "On" .the "Engine Room Emergency Exhaust Fans" and "Staging room Emergency Exhaust Fans", Then turn "Off" The production floor Air handler 100% purge.~The emergency exhaust fans will force the Airflow of the ammonia/air mixture from the production floor area North and South side. The ammonia/air mixture will then flow into the water/ammonia washers, reducing or eliminating ammonia oUtside/offsite consequences. Note leave open engine room d.°or and Staging room door leading'into production floor. 6. The Emergency response team must establiSh site control zones and InCident' · command post quickly. o Using the laptop computer for control located in AHU#13 equipment room,, establish a safe remote location to monitor the entire plant cOndition's, such as (PPM, pressure, etc.) 2 10. 11. 12. 13. Using the Laptop, Shutdown (de-energize) all positive, pressure suctions and their liquid and Hot-gas solenoids. This is to prevent back-feed pressure from ge{ting into the High-pressUre liquid piping. · All controls for shipping and Palletizing. · All controls for 40-degree room. " · ~ All controls for water and glycol chiller's. · All liquid solenoids for all mix and raw tanks. Assess the total incident/situation as a team in a '.'unified Incident Command. System". From approval from the ICS: and using a respiratory and buddy system mOnitor the ammonia PPM's at the property fence Line and at the roof. (If above 250 PPM's return to the ICS post). ' Only from approval from the ICS, will Production floor entry be allowed. With ICS Approval, the emergency response team may enter the Production floor, to get an added assessment of the situation and/or isolating the ice cream freezer stop valve/valves. Do note; before entering the ProduCtion floor make sure that the PPM's are low but also stabilized for a period of time, with a downward trend of lowering PPM levels. (If at all possible and if approved from ICS enter Production floor when the PPM level are less than 300-PPM). After incident' is over and PPM's are zero, and all affected piping, stop' valves and freezers are tagged and locked-out then schedule for replacement and/or repair. Avoiding Deviation (Scenario): 1. Properly train forklift drivers of the hazards of ammonia, attached ammonia piping ' · and freezers. During prodUction and clean-up keep forklifts out of the freezer area, only the main isle way should have motor forklift traffic and theses freezer are protected by 4" traffic Ballard's. Contractors that may be working near or on freezer with motor traffic need to be trained in the hazard of ammonia, its freezer with it's attached piping. ~ .Safe .ty Protective Equipment and General standard Precautions- 1. Emergency team. 2. Buddy system. '10/27/03 o May need SCBA and level "A" suit. Follow emergency response plan guidelines and safety procedures. "~ Need to use Nestle and the Fire department Haz-Mat teams "Unified Incident Command System".. .. Additional Comments Checlc the mechanical integrity of the flange bOlts on ice cream freezers during a yearly shutdown PM. Need door stops on engine room and staging room doors leading to the produCtion side, this will hold doors opening while Emergency Exhaust fans are "on" to lower the levels of monia in the production. Whtten by Mel Balfour and the Utility Team 2002 Revised by: M. Chavez - Utilities Tech. July, 2003 10/27/03 1. CHEMICAL PRODUCT AND COMPANY /DENTIFICATION Date Issued: 01-04-95 Supersedes: 06-15-94 TEXACO _ ". ~4ATERIAL SAFETY DATA SHEET NOTE: Read and understahd Material Safety Data Sheet ~efore handlin~ or dispo~i'n~'of product. MATERIAL IDENTITY ProdHft,Code,.and Name: 01562;~ CAPELEA ,-'~[; 68 ~ Chemical Name and/or Famity or Description: Refrigeration Oils Manufacturer's Name and Address: TEXACO LUBRICANTS COMPANY A DIVISION'OF TEXACO REFINING AND MARKETING INC. P,O. Box 4427 Houston, TX 77210-4427 Telephone Numbers: Transport=tion-Emergency-Company CHEMTREC Health Emergency Genera] MSDS Assistance Technical Information : (914) 831-3400 : (800) 424-9300 -Company : (914) 831-3400 : (914) 838-7204 -Fuels : 914) 838-7336 -Chemical : 512) 459-6543 -Lubricant/: 800) 782-7852 Antifreezes -Additives : 713) 235-62?8 -Solvents : 800) 876-3738 2. COMPOSITION/INFORMATION ON INGREDIENTS THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION IS AS FOLLOWS: CARCINOGENS ARE LISTED WHEN PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER, THIS IS NOT INTENDED TO BE A COMPLETE ,COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND OTHER REGULATORY INFORMATION. PFoduct and/or Component(s) Carcinogenic According to: OSHA IARC NTP OTHER NONE X Composition: (Sequence Number and Chemical Name) Seo. Chemical Name CAS NumDer Range in % 01 # Acid treated heavy naphthenic petroleum 64742-18-3 80.00-94.99 d.istillates 02 # Light naphthenic hydrotreated petroleum 64742-53-6 10.00-19.99 distillate MINERAL OIL MIST HAS A PERMISSIBLE EXPOSURE LIMIT PEL); THEREFORE, THIS PRODUCT, BY DEFINITION, IS CONSIDERED HAZARDOUS BY OSHA (1910.1200). # COMPONENT, BY DEFINITION, IS CONSIDERED HAZARDOUS ACCORDING TO OSHA BECAUSE IT CARRIES THE PERMISSIBLE EXPOSURE LIMIT (PEL) FOR MINERAL OIL MIST, Exposure Limits referenced'Dy Sequence Number in the Composition Section Seq. Limit 01 5.0 mg/m3 TWA-OSHA (MINERAL OIL MIST) 01 5.0 mg/m3 TWA-ACGIH (MINERAL OIL MIST) 01 10 mg/m3 STEL ACGIH (MINERAL OIL MIST) 02 5 mg/m3 TWA-OSHA (MINERAL OIL MIST) 02 5 mg/m3 TWA-ACGIH (MINERAL OIL MIST) 02 10 mg/m3 STEL ACGIH (MINERAL OIL MIST) 3. H~ARD IDENTIFICATION EMERGENCY OVERVIEW Appearance: Clear yellow liquid Odor: Bland odor N.b. -, NOT DETERMINED < - LESS THAN PAGE; 1 N..A. - NOT APPLICABLE > - GREATER THAN NOT TESTED.- PRODUCT CODE: 01562 Date Zssued: 01-04-9~ NAME:' CAPELLA WF 68 Supersedes: 08-15-94 3. HAZARD IDENTIFICATION (CONT)' CAUTION Health: Flammability: · WARNING STATEMENT OIL MIST MAY CAUSE RESPIRATORY IRRITATION HMZS~ . NFPA 0 Reactivity: 0 Health: 0 Reactivity: 0 1 Special : - Flammability: 1. Special : - POTENTIAL HEALTH EFFECTS - EYE SKIN INHALATION INGESTION primary Route of Exposure: EFFECTS OF OVEREXPOSURE .Acute: Eyes: May cause minimal irritation, experienced as temporary discomfort. Skin: Brief contact is not irritating. Prolonged contact, as with clothing wetted with material, may cause deferring Of skin or irritation, seen as local redness with possible mild discomfort. Other than the potential ski'n irritation effects noted above; acute (short term) adverse effects are not expected from brief skin contact; see other effects, below, and Section 11 for information regarding potential long term effects. Inhalation: Vapors or mist, in excess of Dermissible concentrations, or in unusually high concentrations generated from. spraying, heating the material or as from exposure in poorly ventilated areas or confined spaces, may cause irritation of the nose and throat, headache, nausea, and drowsiness'. Ingestion: If more than several mouthfuls are swallowed, and diarrhea may occur.. Sensitization Properties: Unknown. abdominal discomfort, nausea, Chronic: No adverse effects .have been documented in humans as a result of chronic exposure. Section 11 may contain applicable animal data. Medical Conditions Aggravated by Exposure: Because of its deferring properties, prolonged and repeated skin contact · may aggravate an existing dermatitis (skin condition)~ Other Remarks: None 4. FIRST A[D MEASURES Eyes: Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists. Skin: Wash skin with plenty of soap and water for several attention if skin irritation develops or persists., minutes. Get medical Ingestion: If more than several mouthfuls of this material are swallowed, give two glasses of water (16 oz.). Get medical attention. Inhalation: If irritation, headache, nausea, or drowsiness occurs, remove to f~esh air. Get medical attention if breathing becomes difficult od respiratory irritation persists. PAGE: 2 N.D. NOT'DETERMINED N.A. - NOT APPLICABLE < - LESS THAN > - GREATER THAN N.T. NOT TESTED PRODUCT CODE: 01562 Date Issued: 01-04-9~ NAME: CAPELLA NF 88 Supersedes: 06-15-94 4. FIRST AID MEASURES (CONT) .'.Other Instructions: Remove and dry-clean or launder clothing soaked or soiled with this material before reuse. Dry cleaning of contaminated clothing may be more effective than normal laundering. Inform individuals responsible for 'cleaning of potential hazards associated with handling contaminated. clothing.. 5. F/RE-FIGHTING MEASURES Ignition Temperature (degrees F): Not determined. Flash Point (degrees F): . ~55 (coc) Flammable Limits (%): Lower: Not determined. Upper: Not determined. Recommended Fire Extinguishing AgentsAnd Special Procedures: Use water spray, dry chemical, foam, or carbon dioxide to extinguish flames. Us~ water spray to cool fire-exposed containers. Water or foam may cause frothing. Unusual or Explosive Hazards: None Special Protective Equipment ~or Firefighters: No special equipment or procedures required. 6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300) Procedures in Case of Accidental Release, Breakage or Leakage: Ventilate area-. Avoid breathing vapor. Wear appropriate personal protective equipment~ including appropriate respiratory protection. Contain spill if possible. Wipe up or absorb on suitable material and shovel up. Prevent entry into sewers and waterways. Avoid contact with skin, eyes or clothing. ?. HANDLING AND STORAGE Precautions to be Taken*in Handling: Minimum feasible handling temperatures should be maintained. Storage: Periods of exposure to high temperatures should be minimized. Water contamination should be avoided. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Protective Equipment (Type) Eye/Face Protection: Safety glasses, chemical type goggles, or face shield recommended to prevent eye .contact. Skin Protection: Workers should wash exposed skin several times daily w.ith soap and water. Soiled work clothing should be laundered or dry-cleaned. Respiratory Protection: Airborne concentrations should ne kept to lowest levels possible. If vapor, mist or dust is generated and the occupational exposure limit of the product, or any component of the product, is exceeded, use appropriate NIOSH or MSHA approved'air purifying or air supplied respirator after determining the airborne concentration of the contaminant~ Air supplied respirators should always De worn when airDorne ¢~ocentration of the contaminant or oxygen content is unknown. Ventilation: Adequate to meet occupational ~xposure limits (see Delow). PAGE: 3 N.D. - NOT DETERMINED N.A. NOT APPLICABLE N.T. ~ NOT TESTED . < - LESS THAN > - GREATER THAN PRODUCT CODE: 01562 NAHE: CAPELLA WF 58 Date Issued: 01-04-95 Supersedes: 06-15-94 8. EXPOSURE CONTROLS/PERSONAL PROTECTION (CONT) '" Exposure Limit for Total Product: Mineral oil mist: OSHA PEL-TWA 5 mg/m3; ACGIH TLV-TWA 5 mg/m3. 9. PHYSICAL AND CHEMICAL PROPERTIES ~ppearance: Clear yellow liquid Odor: Bland odo~ Boiling Point (.degrees F): Not determined. Melting/Freezingpoint (degrees F): Not applicable. Specific Gravity (~ater=l):. .895 ' pH of undiluted product: Not applicable. Vapor Pressure: Not determined. Viscosity: 64.6 cSt at 40.0 C VOC Content: Not determined. Vapor Density (air:l): Not determined. Solubility in Water (%): Not determined. Other: None 10. STABILITY AND REACTZVZTY This Material Reacts Violently With: (If Others is checked below, see comments for details) Air Water Heat Strong Oxidizers Others None of These X Comments: ..... None Products Evolved When Subjected to Heat or Combustion: Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones. Hazardous Polymerizations: DO NOT OCCUR 11. TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION(ANIMAL TOXICITY DATA) Median Lethal Dose 0rd1: LDSO Believed to be > 5.00 g/kg (Fat) practically non-toxic Inhalation: Not determined. Dermal: LD50 Believed to be > 3.00 g/kg (rabbit) practically non-toxic Irritation Index, Estimation of Irritation (Species) Skin: (Draize) Believed to be < .50 /8.0 (rabbit) no appreciable effect Eyes: (Draize) Believed to De < 15.00 /110 (raDOit)'no appreciable effect Sensitization: Not determined. PAGE: 4 N.b. - NOT DETERMINED N.A. - NOT APPLICABLE N.T. - NOT TESTED - LESS THAN > - GREATER THAN PRODUCT CODE: 01562' Date [ssued: 01-04-9', NA~E: CAPELLA NF 68 Supersedes: 06-15-94 11. TOxicOLOGICAL INFORMATION (CONT) Other: .: Some low viscosity .naphthenic oils have caused skin irritation and skin~. "· tumors in laboratory animals when repeatedly applied and left in piece . . between'applications. The significance of this effect to humans has not.. been establilshed. 12. DISPOSAL CONSIDERATIONS Naste Disposal Methods This product has been evaluated for RCRA characteristics and does'not meet · the criteria of a hazardous waste if discarded in its purchased form.. Under RCRA, it is the responsibility of the user of the product to. deter-. mire at the time of disposal, whether the product meets RCRA criteria for hazardous waste. This is because product uses, transformations, mixtures, processes~ etc. may render the resulting materials hazardous. Reaarks None 13. TRANSPORT INFORMATION Transportation DDT: Proper Shipping Name: Not regulated IMDG: Proper Shipping Name: Not evaluated ICAO: Proper Shipping Name: Not evaluated TOG: Proper ShipPing Name: Not evaluated 14. REGULATORY INFORMATION Federal Regulations: SARA Title ZI[: Section 302/304 Extremely Hazardous Substances Seq.. Chemical Name None Section 302/304 Extremely Hazardous Substances CONT) Seq. TPQ RQ None Section 311 Hazardous Categorization: Acute Chronic Fire Pressure Reactive Section 313 Toxic Chemical Chemical Name None CERCLA I02(a)/DOT Hazardous Substances: Seq,;. Chemical Name None 'CERCLA/DOT .Hazardous Substances (Sequence Numbers and Rq's): Seq. RQ None CAS Number Range N/A CAS Number Concentration (+ indicates DOT Hazardous Substance) CAS Number Range in % TSCA Znvedtory Status: Th'is product is listed on the Toxic Substance Control Substance Inventory. Other: None· PAGE: 5 .N.D, ~ NOT OETERM[NED N.A. - NOT APPLICABLE < - LESS THAN > - GREATER THAN Act (TSCA) Chemical N.T. - NOT TESTED PRODUCT CODE: 01562 Date Issued: 01-04-95 NAHE: CAPELLA NF 68 Supersedes: 06-15-94 14. REGULATORY INFORMATION (CONT) '- '.:State Regulations: California Proposition 65: The following detectable components of this product are substances, or belong to Classes of substances, known to the State of California to cause cancer and/or reproductive toxicity. . Chemical Name CAS Number .- None States Right-to-know Regulations: . Chemical Name State Right-to-know Acid treated heavy naphthenic petroleum MA ". distillates State list: CT (Connecticut), FL (Florida), IL (Illinois), MI (Michigan) LA (Louisiana), MA (Massachusetts), Nd (New dersey), PA (Pennsylvania), RI (Rhode Island), International Regulations: WHMIS Classification: Not regulated Canada Inventory Status: All components are listed on the Canadian Domestic Substance List (DSL). EINECS Inventory Status: All components are listed on the European Inventory of Existing Chemical Substances (EINECS). Australia Inventory Status: All components are listed on the Australian Inventory .of. Chemical Substances (ACIS). dapan Inyentory Status: N.D. 15. ENVIRONMENTAL INFORMATION Aquatic Toxicity: Not determined. Mobility: Not determined. Persistence and Biodegradability: Not determined. Potential to Bioaccumulate: Not determined. Remarks: None 15. OTHER. INFORMATION None THE INFORMATION CONTAINED'HEREIN IS BELIEVED TO BE ACCURATE· IT IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT FOR PURPOSE OF HAZARD COMMUNICATION AS PART OF TEXACO'S PRODUCT SAFETY PROGRAM. IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE FOR ALL TEXACO PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS FOR ALL TEXACO PRODUCTS YOU BUY, PROCESS, USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. TO 'DETERMINE APPLICABILITY OR EFFECT OF ANY LAW OR REGULATION WITH RESPECT TO HHE PRODUCT, USER SHOULD CONSULT HIS LEGAL ADVISOR OR THE APPROPRIATE PAGE: 6 N.D. - NOT DETERMINED N.A. - NOT APPLICABLE N.T. - NOT TE~TED - LESS THAN > - GREATER THAN PRODUCT CODE: 01562' ~ate Issued: 01-04-95 NAI4E: CAPELLA NF 68 Supersedes: 06-15-94 16. OTHER INFORMATION (CONT) GOVERNMENT AGENCY. TEXACO DOES NO'T UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS. Since the last mailing for this customer code, the foll'o~ing sections have been revised: 2,16,17. Date: 01-04-95 New X Revised, Supersedes:'06-tS-94 Date printed: 03-05-9~ -- Inquiries regarding MSDS should De directed to: Texaco Inc. Manager, Product Safety P.O. Box 509 Beacon, N.Y. 12508 PLEASE SEE NEXT PAGE FOR PRODUCT LABEL N.D. - NOT DETERMINED < - LESS THAN 'PAGE: N.A. - NOT APPLICABLE > - GREATER THAN .N.T. - NOT TESTED Date Xssued: O1-04-9i~ *~PRODUCT CODE: 01562 Supersedes: 06-15-94 NAME: CAPELLA WF 68 17. PRODUCT LABEL READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING OF PRODUCT. THIS LABEL COMPLIES WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) FOR USE IN THE WORKPLACE. THIS LABEL IS NOT INTENDED TO BE USED WITH PACKAGING INTENDED'FOR SALE TO' CONSUMERS AND MAY NOT CONFORM WITH THE REQUIREMENTS OF THE coNsuMER PRODUCT SAFETY ACT OR OTHER RELATED REGULATORY REQUIREMENTS. 01562 CAPELLA WF 68 WARNZNG STATEMENT , CAUTION i OIL MIST MAY CAUSE RESPIRATORY IRRITATION PRECAUTIONARY MEASURES -Avoid prolonged breathing of vapor, mist, or gas. -Workers should wash exposed skin several times daily with soap and water. FIRST AID Eye Contact: Flush eyes with plenty of water for several minutes. Get medical attention if eye irritation persists, Skin Contact: Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists. ~ngestton: If more than several mouthfuls of this material are swallowed, give two glasses of water (16 oz.). Get medical attention. [nhalation: If irritation, headache, nausea, or drowsiness occurs, remove to fresh air. Get medical attention if breathing becomes difficult or respiratory irritation persists. Note to Physician: None FZRE In case of fire, use water spraY, dry chemical, foam or carbon dioxide. Water may cause frothing. Use water spray to cool fire-exposed containers. Chemical Name Acid treated heavy naphthenic petroleum distillates Light naphthenic hydrotreated petroleum distillate CAS Number Range in .64742-18-3 80.00-94.99 64742~53-6 10.00-19.99 MINERAL OIL MIST HAS A PERMISSIBLE EXPOSURE LIMIT (PEL): THEREFORE, THIS. PRODUCT, BY DEFINITION, IS CONSIDERED HAZARDOUS BY 0SHA'(1910.1200). # COMPONENT, BY DEFINITION, IS CONSIDERED HAZARDOUS ACCORDING TO OSHA BECAUSE IT CARRIES THE PERMISSIBLE EXPOSURE LIMIT (PEL) FOR MINERAL OIL MIST. Pennsylvania Special Hazardous Substance(s) CAS Number Ranqe in % None HM~S NFPA Health: 0 Reactivity: 0 Health: 0 Reactivity: 0 Flammability: I Special · : - Flammability: 1 Special : - Transportation DOT: Proper Shipping Na~: Not regulated CAUTION: Misuse of empty containers can be hazardous. Empty containers can be hazardous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers might cause fire, explosion or 'toxic fumes from residues. Do.not pressurize or expose to open flame or heat. Keep container closed and drum Dungs in. place. : N.B. NOT DETERMINED LESS THAN PAGE: 8 N,A. - NOT APPLICABLE ' > - GREATER THAN N.T. - NOT TESTED · FRODUCT CODE: 01562 NAIVE: CAPELLA NF 58 17. PRODUCT LABEL (CONT) · Date [ssuecl: 01-04-95. Supersedes: 06-15-94 Manufacturer's Name and Address: TEXACO LUBRICANTS COMPANY A DIVISION OF TEXACO REFINING AND MARKETING [NC." P.O. Box. 4427 Houston, TX 77210-4427 TRANSPORTATION EMERGENCY Company: (914) 831-3400 CHEMTREC: (800) 424-9300 HEALTH EMERGENCY Company: (914) 831-3400 9165i0 *MATERIAL SAFETY DATA SHEET* Page 1 of 2 MEDICAL EMERGENCY ONLY, 24 HOUR SERVICE: 1-800-'328-0026 ECONOMICS LABORATORY, INC. St~Paul MN 55102 Product Information: 1-612-293-2233 Date of Issue: December 18, 1985 1.0 IDENTIFICATION / 1.1 Product Name: AC-300 . 1.2 Product Type: ~Aqueous acid 2.0 HAZARDOUS INGREDIENTS / TLV (mg/m3) % TWA STEL 2.1,Phosphoric acid 7664-38-2 26 1 3 2.2,Nitric acid 7697-37-2 20 5 10 · This product contains no other ingredient considered hazardous according to the criteria of 29 CFR 1910.1200. 3.0 PHYSICAL DATA / 3.1 Appearance and Odor: 3.2 Solubility in Water: 3.3 pH: (1%) 1.5 3.4 Boiling Point:~ WATER Clear colorless liquid with nitric odor Complete Specific Gravity: 1.301 4.0 FIRE AND EXPLOSION DATA / 4.1 Special Fire Hazards: None 4.2 Fire Fighting Methods: Product does not support combustion. 5.0 REACTIVITY DATA / 5.1 Stability: Stable under normal conditions of handling. 5.2 Conditions to Avoid: Mix only with water. Can react violently with alkaline material. Do not mix with chlorinated detergents or sanitizers - will cause hazardous vapors. 6.0 SPILL OR LEAK PROCEDURES / USE PROPER PROTECTIVE EQUIPMENT 6.1 Cleanup: Dike or dam large spills. Pump to containers or soak up on inert absorbent. Flush residue to sewer with plenty of water. 6.2 Waste Disposal: Consult state and local authorities for restrictions on disposal of chemical waste. This product is Corrosive (D002) according to RCRA criteria. ~ UNK = Unknown at this time TLV = Threshold Limit Value _~'. TWA = Time Weighted Average STEL = Short Term Exposure Level ...... ~ = Ceiling Limit, Not To Be Exceeded Product: HIGH FOAMING LIQUID CLEANER II Page 2 of 2 ECONOMICS LABORATORY, INC. 934240 MEDICAL EMERGENCY ONLY, 24 HOUR SERVICE: 1-800-328-0026 7.0 HEALTH HAZARD DATA_/ DANGER 7.1 Effects of Overexposure: Skin and Eyes: CAUSES SEVERE CHEMICAL 'BURNs. Eye contact may cause blindness. Harmful contact may not cause immediate pain. ++ Immediate water flushing is vital in case of eye contact. ++ If Swallowed: HARMFUL OR FATAL. Causes chemical burns of mouth throat and stomach. , If Inhaled: Damages airways and lungs, depending upon amount and .duration of exposure. Effects can vary from slight irritation to bronchitis or pneumonia. People with asthma or other lung problems may be more susceptible. ' 8.0 FIRST AID--/ GET MEDICAL ATTENTION IMMEDIATELY 8.1 Eyes: Immediately flush with plenty of cool running water. Remove contact lenses. Continue flushing for at least 15 minutes, holding eyelids apart to ensure rinsing of the entire eye CALL A PHYSICIAN IMMEDIATELY. ' 8.2 Skin: Immediately flush skin with plenty of cool running water for at least 15 minutes while removing contaminated clothing and shoes Wash clothing before reuse. ' 8.3 If Swallowed: Rinse mouth at once; then drink 1 or two large glasses of water or milk. DO NOT induce vomiting. NEVER give anything by mouth to an unconscious person. CALL A PHYSICIAN IMMEDIATELY. 8.4 If Inhaled: Immediately move to fresh air. 9.0 SPECIAL PROTECTION INFORMATION / 9.1 Respiratory: Avoid misting conditions or dusts. 9.2 Skin: Rubber gloves - protective cuff.or gaUntlet type preferred. 9.3 Eyes: Splashproof glasses, goggles or face shield.' 10.0 ADDITIONAL INFORMATION/PRECAUTIONS / 10.1 DOT Classification: Corrosive Material NA 1760 KEEP OUT OF REACH OF CHILDREN The above information' is believed to be correct With respect to the formula used to manufacture the product.. As.data, standards and regulations change, and conditions of use and handling are beyond our control, NO WARRANTY, EXPRESS OR IMPLIED, IS MADE AS TO THE COMPLETENESS OR CONTINUING AccURAcy OF THIS INFORMATION. DIVERSEY WATER TECPINOLOGIES INC. P.O. Box 200 Chagrin Falls, OH 44022 (2t6) 247-5000 For sales office or product literature call (800) 669-0053 FOR MEDICAL EMEltGENCY, CALL COLLECT (216) '835-7233 Page 1 of 4 MATERIAL SAFETY DATA ~SHEET Revision # 4. SECTION I: PRODUCT IDENTIFICATION 315 TRADE NAME: ~ CHEMICAL NAME: '~u~araldehyde CHEMICAL FAMILY: IndustrialCooling Water Microbiocide. EPA Reg. No. 10352-23-8591 SECTION II: HAZARDOus INGREDIENTS CAS ~ % TLV 291 Glutaraldehyde (1,5-pentanedial) 111-30-8 15 0.2ppm ceiling Methanol .67-56-1 <0.03 200ppm skin SECTION III: PHYSICAL DATA Boiling point (.F): 212.5 F Vapor Pressure (mm Hg): @ 20C 18.1 Yapor Density (air=l): >1 Solubility in'Water: complete Density: 8.67ihs/gal Appearance and Odor: Specific Gravity:i 1.041' Percent Volatile by volume: Evap. Rate (water=l): 0.91 pH: 3.5 - 4.5 Freezing point: -6.5 C (20.3F) Clear liquid, sharp, aldehyde odor. 100 SECTION IV: FIRE PROTECTION INFORMATION Flash Point: NA Flammable Limits: NA Extinguishing Media: Water, carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Keep drums that are exposed to fire cool with water. Wear protective clothing and SCBA. Unusual Fire and Explosion Hazards: Exposure to fire may cause evolution of toxic gases. National Fire Protection Association (NFPA) Rating (in fire conditions): Toxicity: 3 Fire: 1 Reactivity: 0 Special: - Hazard Rating: 4=extreme 3=high 2=moderate l=slight 0=insignificant Date: 9/92 Page 2 of 4 AG"453 SECTION V: HEALTH HAZARD-INFORMATION PRIMARY ROUTE(S) OF ENTRY: ~. Skin: X Eye: X Inhalation: X Ingestion: X. Acute Effects of Exposure: · Brief skin contact will cause itching with mild to.moderate redness and swelling. Prolonged contact may result in pain, severe redness and swelling, with ulceration, tissue destruction, and possibly bleeding into the inflamed area. Prolonged contact may result in absorption of potentially harmful amounts. Moderately toxic by ingestion. May cause irritation or 'chemical burns of the mouth, th_roar, esophagus, and stomach. There will be discomfort or pain in the chest and abdomen, nausea, vomiting, diarrhea, dizziness, faintness, thirst, weakness, circulatory shock, collapse and coma. Vapor is irritating to the respiratory tract, causing stinging sensations and possibly discharge or bleeding from nose, breathing difficulty and headache. Eye contact may cause severe conjunctivitis or corneal injury. .-- ~ ~ ~ cb~0nic Effects of Exposure: May cause skin sensitization in a small proportion of individuals and present as an allergic contact dermatitis. Not a suspected or confirmed carcinogen. (Reference to OSHA, NTP, I~RC) Medical Conditions Which May Be Aggravated By Handling This Product: Persons with impaired breathing may be at increased risk if concentrated mists are inhaled. Open wounds, rashes or sores may be irritated. Emergency and First Aid Procedures: Skin: Flush with water, then wash thoroughly with soap and water. ~ i' Eyes: Flush with water for 15 minutes and seek medical attention. Ingestion: Drink plenty of water and call collect (216)835-7233 or consult physician immediately. Avoid alcoholic beverages. .Do not give anything by mouth to an unconscious person. Inhalation: Move victim to fresh air. Seek medical attention if breathing difficulty persists. Apply artificial respiration if necessary. NOTE TO PHYSICIAN: Due to its corrosive effects on Mucosal surfaces, any material aspirated during vomiting may cause lung injury. Mechanical or pharmacological induction of emesis is not recommended. If evacuation of stomach contents is necessary gastric lavage, or other means least likely to result in aspiration, is recommended. Due to irritation and possibly ulceration' of the upper alimentary tract, there may be blood and fluid loss. FOR 24 HOUR EMERGENCY MEDICAL INFORMATION CALL COLLECT (216)835-7233 (TEL-SAFE). For additional non-emergency information call: Safety and Regulatory Dept. Diversey Water Technologies Inc. P.O. Box 200 Chagrin Falls, OH 44022. (216) 247-5000 Date: 9/92 ~IUERSEY WATER TECHNOLOGIES INC :P.O. Box 200 Chagrin Falls, OH 44022 (216) 247-S000 For sales of{ice or product literature call (800) 6~9-0053 MEDICAL EMERGENCY, CALL COLLECT (216) 83S-7233 MATERIAL SAFETY DATA SHEET Page 1 of-I Rev. ~1! SECTION I: PRODUCT IDENTIFICATION TRADE NAME= CHEMICAL NAME:-~,Isotbiazoline CHEMICAL FAMILY.- Industrial l~;ater Treatment 53 EPA Reg. No. 8591-34 SECTION II: HAZARDOUS INGREDIENTS !21 !22 5-chloro-2-methyl-4-isothiazolin-3-one 2-methyl-4-isothiazolin-3-one magnesium nitrate magnesium chloride copper nitrate CAS ~ ~ TLU 26i72-55-4 1.15 not est. _=8~ =0 4 O. not 10.377--60-3 1-3 not est. 7786-30-3 1-2 not est. 3~51--:Z3-8 <0.2 0.i (0.3 ag/m3 total isothiazolin - manufacturer STEL) SECTION III: as Cu fumes PHYSICAL DATA B~ling point (F): like water, Specific Gr'aulty: 1 ..OZ L~apor Pressure (mm Hg): O.l(actiue ingredient) L~apor Density (air=l): approx. 0.62 Percent Uo~atile by uoiume= appr. '35 Evap. R~te (water'=Il,: Solubilit? in Water: complete pH: 3 - 5 Density': 8.5lbs./gal. pH (!~ soln.): not: tested ~ppearance and Odor: Pale yellow to green; miid :Jro,','~atic odor. SECTION IV: FIRE PROTECTION INFORMATION Flash Point: ~lammable Limits: £xtinguishing Media= Not applicable Not applicable Water, carbon dioxide, dry chemic,~] or foam. .Special Fire Fighting Procedures: Keep drums th.st ~r.e expos.~d to fi~e cool wi~h ~ater. tdea? MSHA,,NIOSH ap.or'o,Jed p~*essupe- demand, se!f-c:onzained breathing apparatus. ~Jnusual Fire and Explosion Hazards: May generate suifu~-- al;oxide, hydr'ogen' chloride and ni::rogen ox-:,des during ~/ '.oral Fire Protection Association (NFPA) Rating ,;ir, fife .:onditions): Toxicity: 3 Fire: 0 Reactivity: 0 Special: ' - Hazard Rating: 4=extreme 3=high 2=moderate l=s!;gh't O=insignificant Date: 3/95 4', Page 2 of 4 AG-480 SECTION V: HEALTH HAZARD INFORMATION PRIMARY RouTE(s) OF ENTRY: Skin: X Eye:-X Inhalation: Acute Effects of Exposure: DANGER! CORROSIVE! Causes eye damage and skin ~)urns. ,delayed for hours. Can cause allergic skin reaction. inhalation may cause irritation of nose and throat. Ingestion: X Skin burns, may 'be Harmful if swallooJed- Animal Toxicology (active ingredient): Oral LDSO (rat): 457 mg/kg Dermal LDSO (rabbit): 660 mg/kg Skin irritation (rabbit): severe irritation, may be corrosive. Sensitization (human): Can cause allergic contact dermat.itis. Chronic Effects.of Exposure: Material is a skin sensitizer at low concentrations ir; susceptible persons'. Not a suspected or confirmed carcinogen (Reference to OSHA, NTP, IARC) Medical Conditions Which May Be Aggravated By Handl;ng Th~s Product: Persons with, impaired breathing may be at increased risk i.f c:oncentrated mists are inhaled. Open wounds, cashes or- sores may' O,e ir-~isated. Emergency and First Aid Procedures: Flush Nith water, then ,Jash thoroughly with =oa'', and ~,ater Eyes: Flush with watec for !5 minutes and seek ;!iedi,;a! attention. ingestion: Drink plenty' of ~a~er and call coilec:t ~'.2t~)8:35-~7233 o.'.-' consult physician immediately. Awo;.d alcoholic be,Jer'~ge's. Do not give anything by mouth to an unconscious lnha la t ion: Moue ,Jictim to fresh air. Seek med;.cai .~tehticm ~.f c::.reathi, n9 difficulty persists. Apply artificial re.spir'at}or~ if necessar:..,. NOTE TO PHYSICIF, N: Mucosal damage may contraindica;e the use of g~str'io Measures against circulatory shock, r-espira'[or? depr'esseion and ,3cn,.Julsions may be needed. =OR 24 HOUR EMERGENCY MEDICAL INFORMATION CALL COLLECT 7or additional ncn-emer, genc7 ir, formation call: S.afe%'? and Re,~ulator'y Dept. Diwer'sey Water' Technologies P.O. Box 200 Chagrin Fails.. OH 44022 z47-,.:.OOw (216) 3/95 Page 3 of 4 SECTION VI: REACTIVITY DATA Stable: Yes: X No: Co,,ditions to Avoid: None ..known. AG-~80 Hazardous Polymerization: Yes.: 'No: X Materials to Avoid: Strong alkaline materials, oxidizing and/or reducing agents, amines and mercaptans. Hazardous Decomposition ProducTs: Hydrogen chloride and oxides of sulfur and nitrogen. SECTION VII: SPILL OR LEAK PROCEDURES/WASTE DISPOSAL Spill or Leak Procedures: i,Jear protective clothing, splashproo¢ goggles and in, pervious overshoes. Remove contaminated clothing promptly; launder thoroughiy before reuse. Dike and absorb spill with inert material (sand, clay). Sho,..*e! all contaminated solids into corrosion-proof dr~ms 8nd treat with enough decor~t~mioation solution* ~(o ~et the solid thoroughly. Let containers stand open for ~8 F, ou'rs, seal, then d~spome.o¢ in radnor-dance with local, state and federal requirement.s. The contaminated area is then w~shed ~ith additional de~:ontam~nm!'~on s,Dlut~oo 8~ld ¢~ushed into a chemical ~eweP after standing 30 minutes. CAUTION: KEEP SPILLS OUT OF MUNICIPAL SEWERS AND O~'EN BODIE~S OF WRTER. ~. ommended decontamination formulation contains one (1) p,-,',, ..... ~ o~ scdiun~ ,~-~etabisulfite and eight (8) pounds of water. A ~,¢olume ra~:io of deconteminant to microbiocide is recommended. Waste Disposal = This material qualifies as a RCRA hazardous waste i¢ the pH i.s less than or equal to 2.1 at the time o¢ disposal. Dispose of in accordance wi?.h inca!, .state and federal requirements. Additional Regulatory Information: ,]ERCLA: Copper nitrate RQ - lO0 lbs. AG-480 RQ E:2,530 lbs (copper nitrate). SARA Title III: Sec. 313 Toxic Chemical Release - This produo~ is formulated magnesium nitrate and < 0.2~ copper ni't.rate ,...~hi,i:iq ~re or~ ~he List Toxic Chemicals (aqueous nitrates). .~ec. 302-304 Extremely Hazardous Substances - This produc~: dc:es not: ingredients on t~e Extremely Hazardous Suost.ance List. Sec. 311-312 Inwentory Reporting,. Hazard Categor-, .... Immediate (.souse) and delayed (chronic) 'fornia Proposition 65 This produc~ does no~ c,]ntain ingredients known the state of California to cause canner or reproducti,..,e I Date: 3/95 Page 4 of 4 AG-480 ~ECT~ION VIII: Eye: Skin: OCCUPATIONAL PROTECTIVE EQUIPMENT Chemical safety glasses or face shield. Wear~MsHAxNIOSH approved respirator suitable ~or vapor or mist concentrations encountered where exposure limits are exceeded. Butyl' rubber or nitrile gloves. Local Exhaust: Other: Recommended in confined spaces. Mechanical exhaust ventilation sufficient to remove air contaminants from operator's area. Rubber apron if splashing likely, e~.~e wash and emecgency shower equipment. · SECTION IX: PRECAUTIONARY MEASURES Store in ventilated area. Destroy contaminated iea-~ner~artioles and .~ashclothing thoroughly before reuse. This matenia~ is a sensitizer and · :or. rosive. A'Joid skin and eye contact. Do not take iriternail~. Keep container closed when not in use. At, cid breathing ~-,apops or mists'. · :loth'ing thoroughly after handling and before eating, drinking, or' smoking,. Store in well ventilated areas at temperatures between 0 C and 55 C. Refer to the "Diversev Material Safety Data Sneer G!ossar,? o¢ Terms" for ~dditional information. SECTION X: TRANSPORTATION INFORMATION DOT Label: D Proper Shipping Name: DOT Hazard Class/I.D. ~= Corr~>si,.Je Liquid. (5-chloro-2-me~hyi-W-isothiazolin-3-or~e) 8, UN I?GO, PG I~ d.S. Surface Freight Classification= Compounds, Industrial Water Treating. L(qu. id SECTION XI: ADDITIDNAL INFORMATION JSDA-' EPA: Complies with FDA 21 CFR '17~.300 use in paper and paperbo9rd ~,~hioh ma./ cont.~ct food. Maximum dose limit 1.5 l~s per ton o¢ pulp paper. Authorized for non-contact ,zoolin,> water. A11 ingredients are in c,3mp i i.B;-,ce ~,,i !:n TSCA inventory guideiines. ~quatic Toxicitp= (aotiwe ingredient) SOD-5 DAY: :]OD (5520D): }ate': 3/95 96 ~r LCSO: 48 hr LCSO: <1 mg/t <1 mg/1 i44 hr LCSO: Bluegill su~-.~fi-~.n - 0.~. pp,,,~ Rainbow ~rout - i4 ppm Daphnia mag,~a - 0.13 ppm '- information contained hs'rein is furnished without warrant.? o¢ any kind~ _¢=..rs should consider these data onl? as a supplement to other information. ~athered 'by them and must make independent determinations o¢ the s~iitaOiiit,/ -~nd completeness of information from all sources to assure proper use and disposal of these materials and the health of emplo?ees and customers. MSDS CODE NO. MATERIAL SA TY DATA SHEET 5B81-83 ORIGINAL ISsuE DATE: 8~85 REVISED: 2~94 PRODUCT NAME: Anhydrous Ammonia COMMON NAME: Ammonia SHIPPING NAME: Ammonia, Anhydrous, Liquefied, 2.2 UN 1005, RQ, !.nhalation Hazard. MATERIAL FORMULA CAS. NO.: Ammonia Water: Oil 24 HOUR EMERGENCY TELEPHONE NUMBER CHEMTREC 800-424-9300 '%WT. MANUFACTURER AND/OR DISTRIBUTOR: LaRoche Industries Inc. 1100 Johnson Ferry Road N.E. Atlanta, GA 30342 (404) 851-0300; (404) 491-7987 afte~- hours Prepared By: R. C. Cannon EXPOSURE LIMITS NH3 H20 7664-41-7 7732-18-5 C-Grade P-Grade 99.5 99.995 0.4 33 ppm 0.1 2ppm OSHA-PEL ACGIH TLV STEL 5Oppm 25 ppm 35 ppm None Established None Established 5mg/M3 5mg/M3 -- BOLLING POINT (°F) --28.1° SPECIFIC GRAVITY (H20=1) 0.62 @ 60°F MELTING POINT(°F) --107.9° PERCENT VOLATILE BY VOLUME (%)' 100 VAPOR PRESSURE (mm Hg.) 4802.9 (94 psi) @ 60°F pH App~rox. 11.6 for 1 N Soln. in water VAPOR DENSITY (AIR=l) 0.60 @ 32°F SOLUBILITY IN WATER 33% (Wt.) @ 68°F APPEARANCE AND ODOR: Colorless gas or liquid with extremely pungent odor. . REACTIVITY 0 (Least) EXTINGUISHING MEDIA: With a source of ignition, ammonia will burn in the range of 16-25% in air. Use water fog or spray to extinguish flames. SPECIAL FIRE FIGHTING PROCEDURES: Stop flow of gas; move containers from fire zone if possible, staY clear of tank heads. Use water to cool fire-exposed containers and protect personnel. Use water spray to control vapors. Personnel must be equipped with appropriate protective clothing and respiratory equipment. Do not put water on liquid ammonia. Stable X pressure of ammonia to increase rapidly. INCOMPATIBILITY: Ammonia can react violently with strong acids. Under certain conditions, ammonia reacts with bromine, chlorine, fluorine or iodine to form compounds which explode spontaneously. Reactions of ammonia with gold silver or mercury to form explosive fulminate-like compounds have been reported. ' HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen on heating to over 850°F The decomposition temperature 'may be lowered to 575°F by contact with certain metals such as nickel. ' HAZARDOUS May Occur CONDITIONS TO AVOID: Not Applicable. POLYMERIZATION Will Not Occur . X NOTE: Anhydrous Ammonia is subject to the reporting requirements of SARA (1986, section 313 of Title III) and 40 CFR Part 372. LaRocHe InDustries nC. TRANSPORTATION EMERGENCIES Call CHEMTREC 800-424-9300 STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED: Stop leak if feasible. Avoid breathing ammonia. Evacuate personnel not equipped with protective clothing and equipment. Use copious amounts of water spray or fog to absorb ammonia vapor. DO NOT put water on liquid ammonia. Contain run-off to prevent ammonia from entering a stream, lake, sewer or ditch. Release of 100 lbs. or more of ammonia within 24 hours must be reported to the National Response Center at 800-424-8802, as well as appropriate local and state agencies. Immediate (within minutes) reporting is required. WASTE DISPOSAL METHOD: NOt Applicable Recover ammonia if feasible. Otherwise, let ammonia evaporate if appropriate. Only personnel experienced in ammonia spills should add water to liquid ammonia. Dispose of diluted ammonia as a fertilizer or in an industrial process. For hazardous waste regulations, call the RCRA Hotline at 800-424-9346. EFFECTS OF OVEREXPOSURE:' . MAJOR EXPOSURE HAZARD IDLH Level=500 ppm I [~INHALATION ~-~SKIN CONTACT ~]EYE CONTACT ~--~INGESTION Ammonia is a strong alkali and readily damages all body I ~ ~ ~ ' tissues. Ammonia is not a cumulative metabolic poison, nor is it a listed carcinogen by IARC, NPT or OSHA. Inhalation: Depending on exposure concentration and duration, effects can vary from none or only mild irritation, to obstruction of breathing from laryngeal and bronchial spasm, to edema and severe damage of the mucous membranes of the respiratory tract with possible fatal results. Latent edema and residual reduction in pulmonary function may occur. Skin Contact: Prolonged contact with high concentrations can cause painful tissue damage, frostbite and serious chemical burns. Eye Contact: Exposure to liquid or high concentrations of vapor can cause painful, instant and possibly irreversible damage to tissues such as the conjunctiva, cornea and lens. Glaucoma and opacities may occur. Ingestion: Tissue damage, chemical burns, nausea and vomiting can occur. Ammonia is a gas under normal atmospheric conditions and ingestion is unlikely. EMERGENCY AND FIRST AID PROCEDURES: Eye Contact: Flush with large amount of water for at least 15 minutes then immediately seek medical aid. Inhalation: Remove from exposure. If breathing has stopped or is difficult, administer artificial respiration or oxygen as needed. Seek immediate medical aid. Skin Contact: Immediately flush with large quantities of water for at least 15 minutes while removing clothing. Clothing frozen to the skin should be thawed with Water before removal. Seek immediate medical aid. Ingestion: Dc not induce vomiting. Have the victim drink large quantities of water if conscious. Immediately seek medical aid. Never give anything by mouth to an unconscious person. RESPIRATORY: Respiratory protection approved by NIOSH/MSHA for ammonia must be used when exposure limits are exceeded. Whether a chemical cartridge respirator or a self-contained breathing apparatus is sufficient for effective respiratory protection depends on the type and magnitude of exposure. SKIN: Rubber gloves and rubber or other types of approved protective clothing should be used to prevent skin contact. A face shield should be used for increased protection from contact with liquid. EYE: Chemcial splash goggles, approved for use with ammonia, must be worn to prevent eye contact with liquid or vapor. A face shield should be used for increased protection from contact with liquid. VENTILATION AND ABSORPTION: Local positive pressure and/or exhaust ventilation should be used to reduce vapor concentrations in confined spaces. Ammonia vapor, being lighter than air, can be expected to dissipate to the upper atmosphere. Ammonia concentrations may also be reduced by the use of an appropriate absorbent or reactant material. · OTHER PROTECTIVE EQUIPMENT AND MEASURES: Emergency eyewash statiOns and deluge showers must be available in the work area. Post a list of emergency response contacts and telephone numbers. PRECAUTIONS TO BETAKEN IN HANDLING AND STORAGE: Refer to the ANSI K61.1 standard for storage and handling information. Protect containers from physical damage and temperatures exceeding 120° E Use only approved storage systems. Zinc, copper, silver, cadmium and their alloys must not be used in ammonia systems since they can be rapidly corroded by it. Avoid hydrostatic pressure, which can cause equipment rupture, by adhering to proper filling procedures and the use of hydrostatic pressure relief valves where appropriate. OTHER COMMENTS: Contact lenses ·must not be worn when working with ammonia. This information is taken from sources or based upon data believed to be reliable' however, LaRbche Industries Inc. makes no warranty as to the absolute correctness or sufficiency of any of the foregoing or that additional or other measures may not be required under particular conditions. L-4583-C MATERIAL SAFETY DATA SHEET-~ Dec. 1986 AnexplanationofthetermsusedhereinmaybefoundinOSHA29CFR1910.1200, available from OSHA regional or area offices. (Essentially similar to U.S. Department of Labor Form OSHA-20 and generally accepted in Canada for information purposes) Do Not Duplicate This Form. Request an Original PRODUCT '~..Argon- CHEMICAL NAME ~A?gon FORMULA - Ar SYNONYMS- Shielding Gas, Argon-40 CHEMICAL FAMILY (Rare Gas) Noble Gas MOLECULAR WEIGHT 39.948 TRADE NAME Argon (This 3roduct is usually intended for electric welding use.) This section covers the materials from which this product is manufactured. The fumes and gases produced during cutting with the normal use of this product are covered by Section VI. The term "hazardous" in "Hazardous Materials" should be interpreted as a term required and defined in OSHA 29 CFR 1910.1200 and does not necessarily imply the existance of any hazard. MATERIAL (CAS NO.) Vol (%) 1986-1987 ACGIH TLV-TWA (OSHA-PEL) Argon (7440-37-1) 100 Simple asphyxiant (None currently established) ~- , BOLLING POINT, 760 mm. Hg - 185.9°C (-302.6OF) FREEZING POINT - 189.2oc (_308.6OF) SPECIFIC GRAVITY (H20 = 1) Gas VAPOR PRESSURE AT 20°C. Gas VAPOR DENSITY (air = 1) 1.378 @ 21.2°C (70OF) SOLUBILITY IN WATER, % by wt. Neglible PERCENT VOLATILES EVAPORATION RATE BY VOLUME 100 (Butyl Acetate = 1) Not Applicable APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure.I IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 304 -- 744-3487 In Canada 514 -- 645-5311 For routine information contact your local supplier Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards.and safety informatiom .To 'promote safe use~of this product.a user. should (1) notify-its employees,.agentsand co~ractors .... of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) (equest such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION I'-I LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION Copyright © 1985, 1986 Union Carbide Corporation Page I of 4 PRODUCT: Argon · L.4563.C Dec.. 1986 THRESHOLD LIMIT VALUE: Simple a~pi~yxiant -- ACGIH ('1986-1987) - :. ' -; ...... - .................. - ' EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING ~This product is-a gas at normal temperature and presSLire. .' '- SKIN ABSORPTION -- No evidence of adverse effects from availabl'e informat on. INHALATION -- Asphyxiant. Moderate concentrations may cause headache, drowsiness, dizziness, excitati0~, excess salivation, vomiting, and unconsciousness. - --' SKIN CONTACT -- No harmful effect expected from vapor. EYE CONTACT No harmful effect expected form vapor. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: Argon is an asphyxiant. Lack of oxygen can cause death. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: A knowledge of the available toxicology information and'of the physical and chemical properties of the material suggest that overexposure is unlikely to aggravate existing medical conditions. SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAXARD EVALUATION: None currently known. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING -- This product is a gas at normal temperature and pressure. SKIN CONTACT -- Flush with water. INHALATION -- Remove to fresh air. Give artificial respiration if not breathing.~Give~oXyg-e'h~if~bi, bathihg~i~diffi~'i~-I't?.Call a physician. EYE CONTACT Flush with water. NOTES TO PHYSIC/AN: This product is inert~ There is no specific antidote. Treatment of overexposure should be directed at the control of symptoms and the clinical condition. WORKING WITH WELDING AND CUTTING MAY CREATE ADDITIONAL HEALTH HAZARDS. FUME'S AND GASES can be dangerous to your health and may cause serious lung disease.* Keep your head out of the fumes. Do not breathe fumes and gases caused by the process. Use enough ventilation, local exhaust, or both to keep'fumes and gases from your breathing zone and the general area. The type and amount of fumes and gases depend on the equipment and supplies used. Possible dangerous materials may be found in fluxes, coatings, gases, metals etc. Get a Material Safety Data Sheet (MSDS) for every material used. Air samples can be used to find out what respiratory protection is needed. Short term overexposure to fumes may result in discomfort such as dizziness, nausea, or dryness or irritation of nose,.throat, or eyes. *NOTES TO PHYSICIAN: Acute -- Gases, fumes, and dusts may cause irritation to the eyes, lungs, nose, and.throat. Some toxic gases associated with welding and related processes may cause pulmonary edema, asphyxiation, 'and death. Acute overexposure may include signs and symptoms such as watery eyes, nose and throat irritation, headache, dizziness, difficulty breathing, frequent · coughing, or chest pains. Chronic -- Protracted inhalation of air contaminants may lead to their accumulation in the lungs, a condition which may be seen as dense areas on chest x-rays. The severity of change is proportional to the length of exposure. The changes seen are not necessarily associated with symptoms or signs of reduced lung function or disease. In addition, the changes on x-rays may be caused by non-work related factors such as smoking, etc. A detailed description of the Health Hazards and their consequences may be found in Linde's free publication "Precautions and Safe Practices for Electric Welding and Cutting," L52-529. You may obtain copies from your local supplier, or by writing to Union Carbide. C.'3~peratior~, .Lindo Divisicn~-Com.,'mJnica~.ions. Dep~men. t;-39-E)ld-Ridgebury-Road, Danbury., Connecticut;-06817;000?.' .......... MIXTURES:. When two or more gases, or ~iquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards Obtain and evaluate the safety information for each component before you produce the mixture. Consult an ~..~ Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or death. Page 2 of 4 ..' PRODUCT: Argon L-4563-C "~' Dec. 1986 (test method) Not Applicable · · TEMPERATURE . -..~ ~' Not Appli~'able : ". '-- ..' FLAMMABLE LIMITS LOWER. "UPPER IN AIR, % by volume :. Not Applicable .' Not Applicable EXTINGUISHING MEDIA Argon cannot catch fire. Use media appropriate for surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES Evacuate all pers~)nnel from danger area. Immediately co-ol cylinders with water spray from maximum distance until cool then' move containers away from fire area if without risk. Shut off leak if without risk. Arcs and sparks can ignite combustibles. Refer to American National Standard Z49.1 "Safety in Welding and Cutting" for fire prevention information during the use of welding and allied procedures. UNUSUAL FIRE AND EXPLOSION HAZARDS Argon cannot catch fire. Container may rupture due to heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125OF). Most containers are provided with ~. pressure relief device designed to vent contents when they are exposed to elevated temperature. STABILITY CONDITIONS TO AVOID UNSTABLE STABLE High pressure gas. Close valve when not in use and when empty. Use with equipment rated to adequately X withstand pressures to be encountered. Do not strike arc on cylinder. Do not ground cylinder. See Section IX. INCOMPATIBILITY (materials to avoid) None currently known. Argon is chemically inert. HAZARDOUS DECOMPOSITION PRODUCTS Ozone and Nitrogen Oxides may be formed by the radiation from the arc. See Section IV. Other decomposition products of normal operation originate from the volatilization, reaction or oxidation of the material being worked. HAZARDOUS POLYMERIZATION May Occur Will not Occur X CONDITIONS TO AVOID None currently known. STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Argon is an asphyxiant. Evacuate all personnel from danger area. use self contained breathing apparatus where needed. Shut off cylinder if without risk. Ventilate area of leak or move cylinder to well ventilated area. Test area, especially confined areas, for sufficient oxygen content prior to permitting re-entry of personnel. WASTE DISPOSAL METHOD: Slowly release into atmosphere. Discard any product, residue, disposable container or liner in an environmentally acceptable manner in full compliance with Federal, State and local regulations. Page 3 of 4 PRODUCT: Argon .- Dec'. '198'6 RESPIRATORY PROTEOTION (spocily type) -- Use respirable fume respirator or air Suppli0d respirator when working ~n confineo spaco or where local oxhaust or ventilation doos not koop exposuro bolow ~. Solect as per OSHA20. GF~1010.1a4.. LOCAL EXHAUST -- Use enough ventilation, local exhaust or both, to keep the fumes and gases below ' ' TLV's in the worker's breathing zone and the general area. Train th-e worker to keep his head out Of the fumes. MECHANICAL (general) ALWAYS WORK WITH ENOUGH VENTILATION .. ~ ........... .-.~ - ~:~. - VENTILATION SPECIAL - Avoid using electric arcs in the presence of chlorinated hydrocarbon vapors - highly to'xic phosgene may be produced. Avoid arc operations on parts with phosphate residues' (anti:rust, cleaning preparations) - highly toxic phosphine may be produced. OTHER Depends on specific use conditions, and location. Use 'adequate ventilation or personal respiratory protection. See Section IX and OSHA29 CFR1910.252. PROTECTIVE GLOVES Welding gloves recommended EYE PROTECTION -- Wear a' helmet or use a face shield with a filter lens selected as per ANSI Z49.1 ' Provide protective screens and flash goggles, if necessary, to protect others. Select as per OSHA29 CFR1910.133. OTHER PROTECTIVE EQUIPMENT -- As needed, wear hand, head, and body protection which help to prevent injury from radiation, sparks and electrical shock. See ANSI Z49.1. At a minimum this includes welder's gloves and a'protective face shield, an~l may include arm protectors, aprons, hats, shoulder protection, as well as dark substantial clothing. Train the worker not to touch live electrical parts. Fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being worked, the process, procedure and electrodes used. Other conditions which also influence the composition and quantity of the fumes and gases to which workers may be exposed include: coatings on the metal being worked (such as paint, plating, or gaIvanizing),'the number of workers and the volume of the work area, the quality and amount of ventilation, the position of the worker's head with 'respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). One recommended way to determine the composition and quantity of fumes and gases to Which workers are exposed is to take an air sample from inside'the worker's helmet if worn or in the worker's breathing zone. See ANSI/AWS F1.1, available from the American Welding Society, 550 N.W. Le Jeune Rd., Miami, FL 33126. Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard 749.1, "Safety In Welding And Cutting" published by the American Welding Society and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more details. For further safety and health information refer to Linde's free publication "Precautions and Safe Practices for Electric Welding and Cutting" L52-529. OTHER HANDLING AND STORAGE CONDITIONS Arcs and sparks during use could be the source of ignition of combustible materials. Prevent fires. Refer to NFPA.51B "Cutting and Welding Processes." High pressure gas mixture. Use piping and equipment adequate y designed to withstand pressures to be encountered. Gas can cause rapid suffocation.due to oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. Do not sirike arc on cylinder. The defect produced by an arc burn could lead to cylinder rupture. Do not ground cylinder. Never work on a pressurized system. The opinions expressed herein are those of qualified experts within Union carbide. We believe that the information contained herei~ is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation to determine the conditions of safe use of the product. UNION CARBIDE L-4563-C 86-0928,12/86 30M GENERAL OFFICES IN THE USA: Unior~ Carbide Corporation ...... Linde Division 39 Old Ridgebury Road Danbury, CT 06817-0001 Other offices in principal cities all over the world. Lithographed in U.S.A. IN CANADA:' Uni~)n Carb de Canada Limi_ted Linde Division 123 Eglinton Avenue East Toronto, Ontario M4P I J3 Page 4 of 4 I~ Date Printed: 06-14-1990 ' DIVERSEY CORP.~ ! : ~ for~i~N~,:.~- ~ALK~LINE CHLORINATED CLEANER +- Page- 1 -SECTION I - PRODUCT IDENTIFICATION *********--******************************* HOUR EMERGENCY ASSISTANCE******** * , , * DIVERSEY CORP. * MEDICAL[COLLECT] (303)592-1024 * * 1532 BIDDLE AVENUE * CHEMTREC (800)424-9300 * * WYANDOTTE, MI 48192 * DIVERSEY CORP. (313)281-0930 * * . , ******************************************************************************* *HAZARD RATINGS* *HEALTH* *FLAMMABILITY* *REACTIVITY* *SPECIAL/PPE* NFPA: 3 0 0 COR }{MIS: 3 0 0 C KEY:4=EXTREME 3=HIGH 2=MODERATE i=SLIGHT COR=CORROS!VE AC=ACID ALK=ALKALINE OX=OXIDIZER PPE CODES=(REFER TO HMIS SYSTEM DOCUMENTATION) 0=INSIGNIFICANT EMERGENCY OVERVIEW D~,GER - CAUSES SEVERE BURNS TO SKIN AND EYES. HARMFUL IF SWALLOWED. DO NOT GET' IN EYES OR ON SKIN OR CLOTHING. AVOID BREATHING DUST OR MIST. WASH THOROUGHLY AFTER HANDLING OR WORKING WITH PRODUCT. WEAR EYE PROTECTION, ALKALI-RESISTANT GLOVES, CLOTHING AND FOOTWEAR TO PREVENT SKIN CONTACT. KEEP OUT OF REACH OF CHILDREN. CHEMICAL HAZARD - CHLORINATED PRODUCT DILUTE THIS PRODUCT ONLY WITH WATER. DO NOT MIX WITH ACIDIC OR AMMONIA CONTAINING CHEMICALS. TOXIC OR HAZARDOUS CHLORINATED GASES OR VAPORS WILL BE RELEASED. INGREDIENTS * * * * ACGIH * OSHA * HAZARD * * CAS NUMBER * CHEMICAL COMPONENT * % * TLV * PEL * CODES * 1310-73-2 "SODIUM HYDROXIDE 18 2 MG/M3 2 MG/M3 1/2/3 7647-14-5 SODIUM CHLORIDE 1-5 NE NE 0 7681-52-9 SODIUM HYPOCHLORITE 3 NE NE 1/2 7732-18-5 WATER 52-62 NE NE 0 7834-92-0 SODIUM METASILICATE 1-2 NE NE 0 '3-01-4~ SODIUM POLYACRYLATE 5-10 NE NE' 0 Date Printed: 06-14-1990 D~RSEY CORP. for BENEFIT - ALKALINE CHLORINATED CLEANER Page 1 -SECTION I - PRODUCT IDENTIFICATION (continued) HAZARD CODE.KEY: 0=NONREGULATED 3=SARA 311/312 LT = LESS THAN l=OSHA(29CFR1910.1200) 4=SARA 313 NE = NOT ESTABLISHED 2=STATE RTK LAWS GT = GREATER THAN 2 -SECTION II - POTENTIAL HEALTH EFFECTS SYMPTOMS OF EXPOSURE: EYES: CORROSIVE. CONTACT OF EYES WITH.PRODUCT CAN CAUSE SEVERE BURNS OR IRREVERSIBLE EYE DAMAGE INCLUDING BLINDNESS, OR IRRITATION WITH ASSOCIATED PAIN, INFLAMMATION OR BLURRING OF VISION. SKIN-. INGESTION: INHALATION: THIS PRODUCT MAY CAUSE SEVERE IRRITATION OR BURNS. SKIN EFFECTS MAY INCLUDE SWELLING, BLISTERING, ITCHING, REDNESS, AND PAIN. REPEAT EXPOSURE TO DILUTE SOLUTIONS MAy CAUSE DRYNESS, RASH, OR REDNESS. THE SEVERITY OF SKIN EFFECTS DEPENDS ON STRENGTH OF SOLUTION AND LENGTH OF CONTACT. HARMFUL IF SWALLOWED CAUSES SEVERE BURNS TO MOUTH, THROAT, AND MUCOUS MEMBRANES WITH PAIN, REDNESS, OR TISSUE IRRITATION ASSOCIATED WITH NAUSEA AND VOMITING. INHALATION OF AIRBORNE CONCENTRATIONS OF DUST, MIST OR SPRAY OF THIS PRODUCT MAY CAUSE MODERATE TO SEVERE IRRITATIONS OF NOSE AND THROAT AND POSSIBLE PULMONARY EDEMA OF LUNG TISSUES AND UPPER RESPIRATORY TRACT WITH PAIN, WHEEZING, SHORTNESS OF BREATH AND CHOKING. PRINCIPAL ROUTES OF ABSORPTION: DIRECT CONTACT(SKIN,EYES): YES INGESTION: YES INHALATION: SPRAY OR MIST TARGET ORGANS: NONE KNOWN. EFFECTS OF OVEREXPOSURE: ACUTE: CORROSIVE OR SEVERELY IRRITATING TO ALL BODY TISSUES. CHRONIC: NO KNOWN HAZARDS. C AINS LISTED CARCINOGENS: NO NATIONAL TOXICOLOGY PROGRAM: NO IARC MONOGRAPHS: NO Date Printed: 06-14-t990 r~'~RSEY CORP. for BENEFIT - ALKALINE CHLORINATED CLEANER 2 -SECTION II - POTENTIAL HEALTH EFFECTS (continued) Page OSHA: NO MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: DERMATITIS OR RELATED SKIN CONDITIONS UPON PROLONGED CONTACT WITH DILUTE SOLUTIONS. INHALED DUST OR SPRAY MAY AGGRAVATE RESPIRATORY DISEASE OR CONDITIONS. 3 -SECTION III - FIRST AID ****************************************************************************** * FIRST AID PROCEDURES--NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT * * IS UNCONSCIOUS OR HAVING CONVULSIONS. CALL A PHYSICIAN. * ****************************************************************************** IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: PROMPTLY FLUSH SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. LAUNDER CONTAMINATED CLOTHING A~ND EITHER DISCARD SHOES OR THOROUGHLY CLEAN FOOTWEAR BEFORE REUSE. GET MEDICAL ATTENTION FOR ANY PAINFUL, RED, OR INJURED SKIN CONTACT AREAS. INGESTION: IF SWALLOWED, RINSE MOUTH WITH WATER. DILUTE BY DRINKING SEVERAL GLASSES OF WATER. DO NOT INDUCE VOMITING. GET PROMPT MEDICAL ATTENTION. NOTE: NEVER GIVE FLUIDS BY MOUTH OR INDUCE VOMITING IN AN UNCONSCIOUS PERSON. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN UNDER DIRECTION OF TRAINED PERSONNEL OR A PHYSICIAN. GET MEDICAL ATTENTION. 4 -SECTION IV - FIRE AND EXPLOSION FLASH POINT: NOT COMBUSTIBLE EXTINGUISHING MEDIA: WATER, FOAM C02, DRY CHEMICALS LOWER FLAM. LIMIT: UPPER FLAM. LIMIT: NONE KNOWN NONE KNOWN Date Printed: 06-i4-1990 P'-~RSEY CORP. for BENEFIT - ALKALINE CHLORINATED CLEANER' Page 4 4 -SECTION IV - FIRE AND EXPLOSION (continued) SPECIAL FIRE FIGHTING PROCEDURES: WEAR FULL PROTECTIVE GEAR TO PREVENT SKIN CONTACT WITH CAUSTIC SOLUTIONS AND SELF CONTAINED BREATHING APPARATUS IN FIRE AREA. DEGREE OF FIRE AND EXPLOSION HAZARD: NOT A COMBUSTIBLE PRODUCT. STRONGLY ALKALINE LIQUID. CORROSIVE OR 5 -SECTION V - REACTIVITY STABILITY: STABLE TO 250 F. HAZ. POLYMERIZATION: NONE KNOWN. CONDITIONS TO AVOID: DO NOT MIX OR STORE WITH ACIDS AND REDUCING AGENTS. CONCENTRATED PRODUCT IS A MODERATE OXIDIZING AGENT. CONTAMINANTS THAT MAY AFFECT STABILITY: HEAT, IRON, SOFT METALS AND ACID. INCOMPATIBILITY: HAZ. DECOMPOSITION PRODUCTS: DO NOT MIX WITH ACIDS OR NITROGEN CONTAINING CHEMICALS SUCH AS AMMONIA. TOXIC OR HAZARDOUS GASES MAY BE GENERATED. MAY RELEASE CHLORINE OR ORGANO-CHLORINE GASES WHEN MIXED WITH ACIDS OR HEATED ABOVE 250 F. GASES OR FUMES ARE IRRITATING OR TOXIC. 6 -SECTION VI - SPILL AND LEAK RESPONSE SPILL RESPONSE: PRODUCT IS A STRONG ALKALINE LIQUID. LEAKS SHOULD BE STOPPED. CONTAIN SPILLED MATERIAL AND CLEAN UP IMMEDIATELY. LIQUIDS SHOULD BE VACUUMED UP OR ABSORBED WITH CLAY OR SAND. PLACE WASTE IN AN APPROPRIATE COVERED CONTAINER. NEUTRALIZE RESIDUE WITH SODIUM BISULFITE OR THIOSULFATE FOR AVAILABLE CHLORINE AND WITH DILUTE MINERAL ACIDS OR SODIUM BICARBONATE FOR ALKALINITY. PERSONS DOING CLEANUP SHALL WEAR APPROPRIATE PROTECTIVE EQUIPMENT TO AVOID SKIN AND EYE CONTACT. WASH SPILL AREA THOROUGHLY- WITH WATER FOLLOWING REMOVAL OF PRODUCT.. ~:~'~ERSEY CORP. Date Printed: 06-14-1990 for BENEFIT - ALKALINE CHLORINATED CLEANER Page 5 I_ 6 -SECTION VI - SPILL AND LEAK RESPONSE (continued) WASTE DISPOSAL: LIQUID oR SOLID WASTE FROM A SPILL CLEANUP IS STRONGLY ALKALINE. PACKAGING, LABELING, TRANSPORTING AND DISPOSAL MAY BE REGULATED AS HAZARDOUS WASTE AND.REQUIRE HANDLING BY LICENSED CONTRACTORS. CONSULT LOCAL OR STATE REGULATIONS FOR MANIFESTING AND DISPOSAL REGULATIONS. SMALL AMOUNTS OF LIQUID WASTE MAy REQUIRE NEUTRALIZATION WITH DILUTE ACIDS BEFORE DISPOSAL TO SEWAGE SYSTEMS. 7 -SECTION VII - PERSONAL PROTECTION/EXPOSURE CONTROL RESPIRATORY PROTECTION: VENTILATION: LOCAL EXHAUST: GENERAL: EYE PROTECTION: PROTECTIVE GLOVES: OTHER PROTECTIVE EQUIPMENT: HYGIENE PRACTICES: USUALLY NOT REQUIRED. IF BREATHING DIFFICULTY SUCH AS COUGHING, WHEEZING OR IRRITATION ARE REPORTED BY EXPOSED PERSONS, MONITOR AREAS FOR CONTAMINATION. WEAR NIOSH ALKALINE CARTRIDGE RESPIRATOR WITH ADDED CHARCOAL FILTER IN HIGH MIST AREAS IF EXPOSURE LIMITS (TLV, PEL) ARE EXCEEDED OR WORKERS EXPERIENCE SYMPTOMS OF EXPOSURE. usUALLY NOT REQUIRED EXCEPT IN SPRAY AREAS. FOR SPRAY OR MIST AREAS, USE ADEQUATE VENTILATION TO MAINTAIN EXPOSURE BELOW GUIDELINES. SPLASH GOGGLES OR FACE SHIELD OR SIDE SHIELD SAFETY GLASSES. RUBBER, PVC OR OTHER CAUSTIC RESISTANT CHEMICALLY IMPERVIOUS CLOTHING AND FOOTWEAR TO PREVENT SKIN CONTACT. SAFETY SHOWER AND EYE WASH IN USE AREA. WASH AFTER HANDLING OR USING PRODUCT. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CLEAN OR REPLACE CONTAMINATED FOOTWEAR BEFORE USE. D~VERSEY CORP. Date Printed: 06-14-1990 for BENEFIT- ALKALINE CHLORINATED CLEANER Page 6 8 -SECTION VIII - STORAGE AND HANDLING KEEP AWAY FROM ACIDS. KEEP CONTAINER CLOSED WHEN MOVING OR NOT IN USE. KEEP OUT OF REACH OF CHILDREN. DO NOT STORE WITH FOOD. STORE IN A COOL AREA AWAY FROM DIRECT SUNLIGHT.OR NEAR STEAM PIPES OR OTHER HEAT SOURCES. STORAGE MATERIALS: DRUMS AND TANKS USED FOR STORAGE OR TRANSPORTING OF THE PRODUCT MAy BE STAINLESS STEEL, HIGH DENSITY POLYETHYLENE, OR REINFORCED FIBERGLASS. PIPING CAN BE GLASS, STAINLESS STEEL OR PVC (SCHEDULE 80). CONSULT DIVERSEY CORP. TECHNICAL REPRESENTATIVE FOR ADDITIONAL INFORMATION. DO NOT USE IRON OR UNLINED STEEL CONTAINERS WHICH WILL REDUCE CHLORINATED CHEMICAL STABILITY. 9 -SECTION IX - PHYSICALAND CHEMICAL PROPERTIES APPEARANCE AND ODOR: MELTING POINT: BOILING POINT: 218 DEG. F VAPOR PRESSURE:18.2 MM, HG 20 DEG. F VAPOR DENSITY: NOT KNOWN SOLUBILITY IN WATER: COMPLETE % VOLATILE(BY WT.): 55% CORROSIVE ACTION ON MATERIALS: CLEAR, LIGHT YELLOW LIQUID WITH A STRONG CHLORINE ODOR. NONE SP.GRAVITY(WATER=I): 1.220 EVAP. RATE(WATER=l): FREEZING POINT: PHOSPHOROUS(%p): PH AT 25 DEG. C: OTHER: 1.08 -26 DEG. F NA 1% SOL'N. 13.2% NA CORROSIVE TO ALUMINUM, COPPER, BRASS, TIN AND OTHER SOFT METALS UNLESS USED AS A DILUTE SOLUTION OR WITH A SHORT CONTACT TIME. 10 -SECTION X -TOXICOLOGY INFORMATION SODIUM HYDROXIDE IS CORROSIVE AND CAUSES DESTRUCTION OF TISSUES. SODIUM HYPOCHLORITE IS AN IRRITANT CAUSING SEVERE EYE INJURY. SODIUM HYDROXIDE TOXICITY ACUTE ORAL LD50 - (RABBIT) 500 MG/KG (RTECS) ACUTE ORAL LD50 - (RAT) 140 - 340 MG/KG (MSI) ACUTE DERMAL LD50 - (RABBIT) 1350 MG/KG (MSI) DI-vERSEy CORP. Date Printed: 06-14-1990 for BENEFIT - ALKALINE CHLORINATED CLEANER Page .-+ 7 10 -SECTION X -TOXICOLOGy INFORMATION (continued) SODIUM HYPOCHLORITE TOXICITY ACUTE ORAL (CAT) 3260.MG/KG (PTL) THE ESTIMATED ORAL TOXICITY OF THIS PRODUCT FOR ANIMALS IS 2800 MG/KG. 1800 - 11 -SECTION XI - ECOLOGICAL EFFECTS THIS PRODUCT IS STRONGLY ALKALINE. PROCESS WASTE SOLUTIONS MAY REQUIRE NEUTRALIZATION OF RESIDUAL AVAILABLE CHLORINE OR'TREATMENT TO A SPECIFIC PH STRENGTH BEFORE DISCHARGE TO PUBLIC OR PRIVATE SANITARY SEWER SYSTEMS. SOLUTIONS MAy BE TOXIC TO FISH OR AQUATIC LIFE. DO NOT DISCHARGE UNTREATED SOLUTIONS TO LAKES, STREAMS, OR PONDS. CONTAINER DISPOSAL: WHEN EMPTY, THIS CONTAINER MAy STILL BE HAZARDOUS. TRIPLE RINSE CONTAINER AND LINER WITH WATER AND ADD TO USE SOLUTION OF PRODUCT. DELIVER CLEANED CONTAINER TO A DRUM RECYCLER OR DISPOSE OF IN ACCORDANCE WITH ENVIRONMENTAL REGULATIONS. 12 -SECTION XII - REGULATORY INFORMATION DIVERSEY CORP. COMMODITY CODE': US FRT CLASS: TSCA INVENTORY: DOT NAME: CORROSIVE LIQUID, N.O.S.(SODIUM HYDROXIDE & SODIUM HYPOCHLORITE) UN1760 DOT CLASS: CORROSIVE (IMO CLASS 8) DOT EMERGENCY RESPONSE GUIDE NO. 60 CERCLA RQ: 931, 932, 933 OR 934 LTL 55 ALL COMPONENTS OF THIS PRODUCT HAVE BEEN INCLUDED ON THE TSCA INVENTORY. SODIUM HYDROXIDE 1000 POUNDS = BENEFIT - 5 555 POUNDS OR 524 GALLONS OF PRODUCT. ' SODIUM HYPOCHLORITE 100 POUNDS = BENEFIT - 3 '333 POUNDS OR 313 GALLONS. ' ~ Date Printed: 06-14-1990 D~3~RSEY CORP. for BENEFIT - ALKALINE ,CHLORINATED CLEANER Page 8 + 13 -SECTION XIII - SUPPLEMENTAL INFORMATION THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND DISCLOSES THE KNOWN HAZARDS FOR THIS PRODUCT AS OF THIS DATE BASED'UPON INFORMATION AVAILABLE TO DIVERSEY CORP. NO ADDITIONAL WARRANTIES ARE MADE. DATE PREPARED: JUNE 14, 1990 DEC:-29-94 MATERIAL $ A F .E T Y D A T A SHEET F'.O1 PRODUCT NAME: CAS ~,~UUBER 10043-52-4 HgCC MSDS NO. CC06000 / .40), chemical il Outside Caltf: same i'\~ i n c. Revision issued: 8/1~g3 Supercedes: 5/27/g2 : First. issued: 12/0~/85 IMPORTANT~ n R.~u this MSDS b~fore u~e 0r dlsp0sal ot this product. P~s a~ong the information employees end any o~er ~rsons who could be ex.sad (o the pr~u~ to be sure that they are ~ware of t~e i~fotmaflon belore use ot other ex.sure. ~ls MSDS'ha~ ~een pre~t~ accotdlng to the OSHA Hazard CommunicatiOn St3ndard [29 CFR 1910.1200]. The MSD~ information Is based on sourc~ believed to be tellable. However, since data. ~te'ty stand~rds, and government tegulattoAs ate subject to change and the conditions of handling and use. cr mlsuse are beyond Our con[rot. AmbeT Chemical inc. m~.kes no warranty, either expressed ot tmpl)ed, with respect to the completeness or continuing accuracy cf the i~formaflon con/aln~ here~n and dl~laims ~[ IlablU~ lot. reliance thaFeon. Also. addRional trJo~mallo~ may be nccess~ or helpful for speCifiC conditions end c~rcumstsnces of use. It Is' the ' , ~ ~ determine the su~tab)li~ Of this product and to evaluate rts~ ~tior tO u~e, and then to exercise approprlst~ Dr~6utlOn~ (or protect)on o( employees and others.'' ,~EOTION I PRODUCT IDENTIFICATION' SY~4ONYMS ! COMMON NA.~!ES: CALCIUMCHLORiOE, LIQUID CHEMICAL FAMILY / TYPE: )HORG~tCSALT DOT PROPER SHIPPING NAME: NiA DOT HAZARD CLASS I I.D. NO.: [jiA TREATED REPORTABt. E QUANTITY: NFPA RATING: HEALTH - ;' FIRE-0; REACTiViTY-0 0=lnsigr, ificam 1 =Slight 2=M~Jera(e 3=High 4=E~reme [SECTION II HAZARDOUg INGREDIENTS l CAS Chemical Hame Number C: t, Lc..4 UM C.'H LOf-~ 0 E Exposure :Limits (TWAs) ACGiH TLV OSHA DEL NIA NI;, Ot he," ~ECTION III- - PHYSICAL AND CHEMICAL PROPERTIES Physical State: LIQUID 1 Flash Point: Not flammable Lower Explosive Urn!t: N/A Unusual Fire and Explosion Hazards: E×tinguishing l~edia: NIA N/A Aut°lgnlUon TemPerature: Not flammable Upper Explosive Limit:' NIA Special Firelighting Procedures' iSEC'rloN V - REACTIVITY Siabilily: Stable HazardoUs Polymerization: Wi!I not occur Conditions to Avoid:r NIA Materials to Avoid: are incompatible. Metals wiff slowly corrode in aqueous solutions. I~oric aciO and ca;cium oxide Hazardous Decomposition P~oducts: ISECTION VI . HEALTH HAZARDS Routes of Exposure: Calcium chloride can a~tect the body if it Is in§ested or if it comes in co~tact wit~ lhe eyes or skin. Sua~mary o! ACute Health Hazards: tNOESTIOI',I: Causes irri{~tlon of mouth and s{ornach. INH"S'LATION' Causes irritation ot nose and ibrD.at. SKil't: Causes milo ir¢itation. EYES: Causes Irritation and possible transient corneal Injury, Carcinogcnicity Lisls: NO NTP: HO N/A - Not Applicable Page 2 of 3 ~:~"" For sales-offlce or product literature :calI (800) 669:t053',,~,~f..,.:~ . . RODUC- . ..... FICATION · ".'~.-,):-'+"~'.e,,zr ..... · ~.. CH~I~.~N~ :,:,~pol~er/phosPhOnate/mOly~at~a _~ .,. ,.~_ . ..... ...... ~. ~ ~ILY. Industrial Water Treatment, .~':"~..%~[2 ......... ..... ~ .... ~,z,~.,:.:,..~ SECTION II: ', ~Z~OUS 'ING~DI~TS "' ·" ' ')i~ - 40 potassi~ hydroxide 13i0_58:3 392 potassi~ molybdate 13446-49-6: 290 sodi~ tolyltriazole 64665'57-2 1-4 ~. not ' est (oral LDSO rat (female)-.735 rog/kg); (male)-930 rog/kg); ' ~ ' ' 34 hydr°~ethylidene diphosphonic acid 2809- --~~ .... · 21-4 ': 1-4 ~ --~ · - SECTION III: PHYSI~ DATA -~--~ · Boiling point (F): > 212 " Specific Gravity: 1.096' Vapor Pressure (~ Hg): like.water'' ...percent.Volatile. by vol~e: appr. 85 Vapor Density (air=l): like water ~ap. Rate-(Wate~l): -:. ~ 1 Sol~ility in Water: complete pH: 13.5 Density: 9.14 lbs/ga!- F'.pH (1% soln.): 10.0 ' ' Appearance and Odor: Yellow li~id, 'mild ':~6~or' ' SE~ION IV: FIRE PROTECTION INFO~TION Flash Point: Not applicable Flyable Limits: NA E~in~ishing Media: Water, carbon dioxide, d~ chemical or foam. Special Fire Fighting PrQced~es: Keep d~s that are e~osed to fire Cool with water. 'Wear protective clothing and SCBA. Unusual Fire and E~losion Hazards: Tolyltriazole has the 'potential .to be the~ally hazardous. National Fire Protection Association (NF.PA) Rating (in fire conditions): Toxicity: 2 Fire: 0 Reactivity: 0 SpeCial: _ Hazard Rating: 4=extreme 3=high 2~oderate l=slight 0=insignificant Date: 1/93 ::. SECTION,~V ::~:. · HEALTH. :HAZARD INFORMATION:,'.. , ' :3: . . . Skin: .'.-~'X ' Eye: :;'-X '.ACute. Effects'~Of ;:E~osure: ' ~ .' .: ~':%.:~.. .May cause :seye=e.firritation:- cause burns. and/or d~age-:--skin-,./~Y~s'.~n~..]~m&'Cous. .... me,fane ~-:~tnges~i0n.~?.may~:_caus e :--nausea ,'?vomi%ing, No kno~ c~onic health effects. ?.;Not.~-a::.SUspected~°=~ Medical Conditions ~ich May Be Ag~avated By Handling This:.Product: :?-:'.>:. :'. Persons .with impaired brea~ing may be at increased risk if concentrated' mists · are i~aled. Open. wounds, rashes or sores may be irritated. ~ergency and First' Aid Procedures: . .:~...:;....~...::,,:.:~: .::/. ,~::._ ... Skin: Flush with Water, then wash thoroughly with :soap;;and..water. . ~es: Flush with water for 15 minutes and se~ mediCal'~attention. "'. Ingestion: Dri~ plenty of water and =all colle=t :(216):835-7233 or physician i~ediately. Avoid alcoholic beverages. Do not give an~hing by mouth to .an unconscious person.' :.--.%~; .: I~alation: Move victim to fresh air. Seek medical .attention if breathing difficulty persists. Apply artificial respiration if necessa~. ~ . (TEL_S~E) FOR 24 HO~ ~G~CY MEDI~ INFO~TION CALL COLLECT (216)835-7233' For additional non-emergency information call: Safety and Regulatory Dept. Diversey Water Technologies.. P.O. Box 200 Chagrin Falls, OH 44022 (216) 247-5000 Date: 1/93 ..::.. .... ~N--~i~. ~CTiVITY*..DAT~,~ ........ . . . ..... . :: ?. - . *..~:~...;. Stable: . -.Yes: ~?:X .:;'--No: : Hazardous Poz~erzza~zon:' j' ~ :.-. . :.-.~cOnditi.0ns.to AvOid: .,..~:.-:..~ ..... -:~ ........ . .... -~:~ .~-. ..... ~.e..~, .............. ~ - ~ ::.~ ~'~:~;C~¥ 5~;~-3~?e'~"--:C%:c : ~-- :- .... : ' '7 ' :'~ ~:7~ '/ "':. - " '" ' 3 ~.. ~ ::ZJJ' L~:3~::'.~';/'~ ~ ', .. -., ... . . ~. ~ . :. ::% ?-7: .".;:.-'.:~,.j/ ~. ,~:::,~-r.:'r ,:,,~.,'~.~: ...... ~*- ..... : ~.., . _~: , .... ?.;, ..... ' ' o~ acids 0xidiZi~g and/or · reducing: agents ~,~Zeather';'-~.wo~I~~ :chlO~ihated - ~=:.~hydrocarb~n'S~hd:"ai~ln~, tin, zinc, a~ialloys~of..-,:these-metalsJ:-:.:', Hazardous Dec'omposition Products: ~ .. ~,. - The~al' decomposition may produce carbon monoxide, carbon~dioxide' and/or nitrogen:'oxides. .~: ~.~ :./ SECTION ~VII: ?-'SPILL:' 0R- L~ PROCED~ES/WASTE ~DISPOS~ Procedures: sPill or Leak Contain spill if wi~o~ :rysk~'~"' Neutralize wi~ a weak acid in a well ventilated area and flush small spills to sanitary sewer .if in accordance Qith local~-:state and:~ai~'~idelines- ~sorb larger spills on inert material such~as "clay .or :~'-"and ~iace'' in ~s for disposal. ' . ' '2, ':'~": :-'"" '- ' Waste Disposal: . ' ~&~ pt~du~ doe~ ~aZ&fy a~ ~ R~ ~aza~dou~ ~a~e due Lo ~e. o~ ~ot~o~v~y (DO02). D~po~e of ~n a~ordan~e ~ .Zo~aZz '~a~e and, ~.ede~aZ Additional Regulatory Information: CERCLA potassium hydroxide/1000 lb. RQ; CW-4355/8,500 lb. RQ SARA Title III: Sec. 313 Toxic Chemical Release - This product does not contain ingredients~ on the List of Toxic Chemicals. Sec. 302-304 Extremely Hazardous Substances - This product does not contain ingredients on the Extremely Hazardous Substance List. Sec. 311-312 Inventory Reporting, Hazard Category - Immediate (acute) california Proposition 65: This product does not contain ingredients known.tc the state of California to cause cancer or reproductive toxicity. Date: 1/93 ' " ...... "',':' '. ~6~~' -~.:~'~ '~,'" ,':~' , ~' ~O~ -. . - - .... ' - -' .;-' --' · ': Avoid'Skin and eye contac'.-[' " · ~, ~ot. in use. Avoi~ ~ -~e not take inter .... :... . · ,~=~ullng and ~ .... ~ .~eat~lng vano _ ."~x~Y- Kee co ' _ b~ ea~i~ ~_: .... = rs or mists .... P ~tal~er ulose~ ~__ ~ =, '~lng, or smokin~ ' -ash thoroughly af~=~ u lnfo~ion~. ~nerlal Safety Data Shee'~.t~Gi~-~~. ~.=,Te~.~9,{~u:.L,.L .,:~'-~ ....... ': ": "~' ....-~ a~ditional DOT Label: DOT.Pr6p~(~/ Shippy~g-iName: -~:: "::.:'.. Corrosiv~''r '" '" ' '~:' . : ..... aikaiine: (CorrOsive) Liquid; ~. . .~-: (contains potassium hydroxide) O.S,t~ · ,c DOT Hazard Class/I.D. #:' Users should consider these data gathered by them and must make only as a supplement to other information and completeness of info . independent determinations of the suitabilit disposal of the ...... r~atlon from all sources to ass ~ ~cerla±s and the health of em~- ute_proper use a H Y ' ~y~es an~ customers, n? . Corrosive Material,. NA 1719 U.S. Surface Freight Classification: Compounds, industrial Water · ~DITION~ iNFO~Ti~-~-~~ --~_ .. ~ ' FDA: .... Not applicable ..:... USDA: EPA: Approved for non-contact Cooling and :retort water. Ail ingredients reported on TS~ Inventor. A~atic Toxicity: Ceri°dap~ia Dubia LCS'0- 4 Fa~ead minnows Lm~n; -~ . 8 hfs 368 Date- ---~~----- ___ ' 1/93 -~=~~_~ ...... The info~ation contained herein is furnished without warranty of any kind. t~ ~,,! MSD$' fo~.iDEMAND~-'ANIONIC ACID SANITIZER Date Printed: 04-17-1990 Page 1 -SECTION I - PRODUCT IDENTIFICATION *********--***--************************ HOUR EMERGENCY ASSISTANCE******** * * * DIVERSEY CORP. * M]EDICAL[COT,?.~.CT] (303) 592-1024 · * 1532 BIDDLE AVENUE * CHEMTREC (800) 424-9300 · * WYANDOTTE, MI 48192 * DIVERSEY CORP. (313) 281-0930 · * * ****************************************************************************** *HAZARD RATINGS* *HEALTH* *FLAKMABILITY, *REACTIVITY* ,SPECiAL/PPE. NFpA: 3 0 0 COR }{MIS: 3 0 0 C KEY: 4 =EXTREME 3=HIGH 2=MODERATE 1=SLIGHT COR=CORROSIVE AC=ACID ALK=ALKALINE OX=OXIDIZER PPE CODES= (REFER TO HMIS SYSTEM DOCUMENTATION) 0=INSIGNIFICANT EMERGENCY OVERVIEW '}~GER - CORROSIVE - CAUSES EYE AND SKIN DAMAGE. DO NOT GET IN EYES, ON SKIN, OR CLOTHING. WEAR GOGGLES OR FACE SHIELD WHEN HANDLING. WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. HARMFUL OR FATAL IF SWALLOWED. AVOID CONTAMINATION OF FOOD. KEEP OUT OF REACH OF CHILDREN. ACIDIC PRODUCT - DO NOT MIX WITH OTHER CLEANERS OR CHEMICALS, AS HAZARDOUS GASES OR HEAT MAY BE GENERATED. DILUTE ONLY WITH WATER. INGREDIENTS . CAS NUMBER * * CHEMICAL COMPONENT , * ACGIH * OSHA * HAZARD * * TLV * PEL .* CODES '* 1300-72-7 -SODIUM XYLENE SULFONATE 1-2 NE NE 0 -- 7664-38-2 "PHOSPHORIC ACID 59 I MG/M3 I MG/M3 1/2/3/4 7732-18-5 WATER 20-25 NE NE 0 68988-76-1 SULFONATED OLEIC ACID 14-16 NE NE 0 HAZARD CODE KEY: 0=NONREGULATED 3=SARA 311/312 LT = LESS THAN l=OSHA(29CFR1910.1200) 4=SARA 313 NE = NOT ESTABLISHED 2=STATE RTK LAWS GT = GREATER THAN IDIVERSEY CORP. Date Printed: 04-17-1990 Page . MSDS for DEMAND - ANIONIC ACID SANITIZER 4 + 2 -SECTION II - POTENTIAL HEALTH EFFECTS .... SYMPTOMS OF EXPOSURE: EYES: CORROSIVE. CONTACT OF EYES WITH PRODUCT CAN CAUSE SEVERE BURNS oR IRREVERSIBLE EYE DAMAGE INCLUDING BLINDNESS, OR IRRITATION WITH ASSOCIATED PAIN, INFLAMMATION OR BI//RRING OF VISION. SKIN: INGESTION: INHALATION: CORROSIVE. THIS PRODUCT MAY CAUSE DESTRUCTION OF TISSUES ON CONTACT. SKIN EFFECTS MAy INCLUDE BURNS, BLISTERING, REDNESS, AND PAIN. REPEAT EXPOSURE TO DILUTE SOLUTIONS MAy CAUSE DRYNESS, RASH, OR REDNESS. THE SEVERITY OF SKIN EFFECTS DEPENDS ON STRENGTH OF SOLUTION AND LENGTH OF CONTACT. CORROSIVE. MAY BE FATAL IF SWALLOWED. .MAY CAUSE ESOPHAGEAL OR GASTRIC PERFORATION. CAUSES SEVERE BURNS TO MOUTH, THROAT, AND MUCOUS MEMBRANES WITH PAIN,-REDNESS, OR'TISSUE DESTRUCTION. INHALATION OF AIRBORNE CONCENTRATIONS OF DUST, MIST OR SPRAY OF THIS PRODUCT MAY CAUSE MODERATE TO SEVERE IRRITATIONS OF NOSE AND THROAT AND POSSIBLE PULMONARY EDEMA OF LUNG TISSUES AND UPPER RESPIRATORY TRACT WITH PAIN, WHEEZING, SHORTNESS OF BREATH AND CHOKING. PRINCIPAL ROUTES OF ABSORPTION: DIRECT CONTACT(SKIN,EYES): YES TARGET ORGANS:. NONE KNOWN. INGESTION: YES INHALATION: NOT VOLATILE EFFECTS OF OVEREXPOSURE: ACUTE: CORROSIVE OR SEVERELY IRRITATING TO ALL BODY TISSUES. CHRONIC: NO KNOWN HAZARDS. CONTAINS LISTED CARCINOGENS: NO NATIONAL TOXICOLOGy PROGRAM: NO IARC MONOGRAPHS: NO OSHA: NO MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: DERMATITIS OR RELATED SKIN CONDITIONS UPON PROLONGED CONTACT WITH DILUTE SOLUTIONS. INHALED DUST OR SPRAY MAy AGGRAVATE ~..:. RESPIRATORY DISEASE OR CONDITIONS. -% DiV~RSEY CORP. for DEF~XND - ANIONIC ACID S~NITIZER Date Printed: 04-17-1990 Page 3 3 -SECTION III - FIRST AID ****************************************************************************** * FIRST AID PROCEDURES--NElrSR GIVE FLUIDS OR INDUCE VOMITING IF PATIENT * * IS UNCONSCIOUS OR HAVSNG CONVULSIONS. CALL A PHYSICIAN. , ****************************************************************************** EYES: iN CASE OF CONTACT, I-~DIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET IM2fEDIATE ~DiCAL ATTENTION. SKIN: INGESTION J.~HALATiON: PROMPTLY FLUSH SKIN WITH PLENTY OF WATER. ~.REMOVE CONT~iNATED CLOTHING A/~D FOOTWEAR. LAD~DER CONTAmiNATED CLOTHING AND EITHER DISCARD SHOES OR THOROUGHLY CLEAI~ FOOTW-:3~ BEFORE P~EUSE. GET ~[EDICAL ATTENTION FOR ANY PAINFUL, RED, OR INJUP~ED SKIN CONTACT AREAS. IF SWA~LLOW~D, RINSE MOUTH WITH WATER. DILUTE BY DRINKING SEVERAL GLASSES OF WATER. DO NOT INDUCE VOMITING. GET PROMPT NfEDICAL ATTENTION NOTE: NEVER GIVE FLUIDS BY MOUTH OR iNDUCE VOMITING IN AN O~CONSCIOUS PERSON. IF iNHALED, REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN b~DER DIP~ECTION OF TRAINED PERSONNEL OR A PHYSICIAN. GET M~DICAL ATTENTION. 4 -SECTION IV - FIRE AND EXPLOSION FLASH POINT: NOT COMBUSTIBLE EXTINGUISHING MEDIA: WATER, FOAM C02, DRY C~ICALS LOWER FLAM. LIMIT: UPPER FLAM. LIMIT: NONE K~OW~ NONE KNOW~ SPECIAL FIRE FIGHTING PROCEDURES: W~_tR FULL PROTECTIVE GEAR TO PR~;ENT SKIN CONTACT WITH ACIDIC SOLUTIONS AND SELF CONTAINED BREATHING APPAJtATUS IN FIP~E AREA. DEGREE OF FIP~E AND EXPLOSION PiAZ~_RD: NOT A COMBUSTIBLE PRODUCT. STRONGLY ACIDIC LIQUID. CORROSIVE OR DIVERSEY CORP. "~DS for DEMAND - ANIONIC ACID SANITIZER Date Printed: 04-17'-1990 Page 4 + 5 -SECTION V - REACTIVITY STABILITY: STABLE CONDITIONS TO AVOID: CONTAMINATES THAT MAY AFFECT STABILITY: INCOMPATIBILITY: HAZ. DECOMPOSITION PRODUCTS: HAZ. POLYMERIZATION: NONE KNOWN. USE PLASTIC TAPS OR PUMPS FOR DISPENSING. DO NOT USE ALUMINUM, ZINC OR WHITE METAL FITTINGS OR TAPS. NONE KNOWN. DO NOT MIX WITH ALKALINE MATERIALS, SOFT METALS OR CHLORINATED CLEANERS. NONE KNOWN. 6 -SECTION VI -SPILL AND LEAK RESPONSE iLL RESPONSE: WASTE DISPOSAL: PRODUCT IS A STRONG ACIDIC LIQUID. LEAKS SHOULD BE STOPPED. CONTAIN SPILLED MATERIAL AND CLEAN UP IMMEDIATELY. LIQUIDS SHOULD BE VACUUMED UP OR ABSORBED WITH CLAY ORSAND. PLACE WASTE IN AN APPROPRIATE COVERED CONTAINER. NEUTRALIZE RESIDUE WITH DILUTE ALKALI SUCH AS SODIUM HYDROXIDE OR SODIUM CARBONATE. PERSONS DOING CLEANUP'SHALL k~AR APPROPRIATE PROTECTIVE EQUIPMENT TO AVOID SKIN AND EYE CONTACT. WASH SPILL AREA THOROUGHLY WITH WATER FOLLOWING REMOVAL OF PRODUCT. LIQUID OR SOLID WASTE FROM A SPILL CLEANUP IS STRONGLY ACIDIC. PACKAGING, LABELING, TRANSPORTING AND DISPOSAL MAY BE REGULATED AS HAZARDOUS WASTE AND REQUIRE HANDLING BY LICENSED CONTRACTORS. CONSULT LOCAL OR STATE REGULATIONS FOR MANIFESTING AND DISPOSAL REGULATIONS. SMALL AMOUNTS OF LIQUID WASTE MAY REQUIRE NEUTRALIZATIONWITH DILUTE ALKALI BEFORE DISPOSAL TO SEWAGE SYSTEMS. ~ I DIVERSEY CORP. .. MSDS for DEMAND - ANIONIC ACID SANITIZER Date Printed: 04-17-1990 Page 7 -SECTION VII - PERSONAL PROTECTION/EXPOSURE CONTROL RESPIRATORY PROTECTION: USUALLY NOT REQUIRED. IF BREATHING DIFFICULTY SUCH AS COUGHING, WHEEZING OR IRRITATION ARE REPORTED BY EXPOSED PERSONS, MONITOR AREAS FOR CONTAMINATION. WEAR NIOSH ACID CARTRIDGE RESPIRATOR WITH ADDED CHARCOAL FILTER IN HIGH MIST AREAS IF EXPOSURE LIMITS (TLV, PEL) ARE EXCEEDED OR WORKERS EXPERIENCE SYMPTOMS OF EXPOSURE. VENTILATION: LOCAL EXHAUST: GENERAL: EYE PROTECTION: PROTECTIVE GLOVES: '~ER PROTECTIVE EQUIPMENT: HYGIENE PRACTICES: USUALLY NOT REQUIRED EXCEPT IN SPRAY AREAS. FOR SPRAY OR MIST AREAS, USE ADEQUATE VENTILATION TO MAINTAIN EXPOSURE BELOW GUIDELINES. SPLASH GOGGLES, FACE SHIELD OR SIDE SHIELD SAFETY GLASSES. RUBBER, PVC OR OTHER ACID RESISTANT. CHEMICALLY IMPERVIOUS CLOTHING AND FOOTWEAR TO PREVENT SKIN CONTACT. SAFETY SHOWER AND EYE WASH IN USE AREA. WASH AFTER HANDLING OR USING PRODUCT. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. CLEAN OR REPLACE CONTAMINATED FOOTWEAR BEFORE USE. 8 -SECTION VIII - STORAGE AND HANDLING STORAGE AND DISPOSAL: DO NOT CONTAMINATE WATER., FOOD OR FEED BY STORAGE OR DISPOSAL. OPEN DUMPING IS PROHIBITED. DO NOT REUSE EMPTY CONTAINER. STORAGE MATERIALS: DRUMS AND TANKS USED FOR STORAGE OR TRANSPORTING OF THE PRODUCT MAY BE STAINLESS STEEL, HIGH DENSITY POLYETHYLENE, OR REINFORCED FIBERGLASS. PIPING CAN BE GLASS OR PVC (SCHEDULE 80). CONSULT DIVERSEY CORP. TECHNICAL REPRESENTATIVE FOR ADDITIONAL INFORMATION. ',. MSDS for DEMAND - ANIONIC ACID SANITIZER DIVERSEY CORP. Date Printed: 04-17-1990 Page 6 9 -SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE AND ODOR: M~LTING POINT: NONE BOILING POINT: 246 DEGR F. VAPOR PRESSURE:10.8 MM, HG 20 DEG. F. VAPOR DENSITY: NOT KNOWN SOLUBILITY IN WATER: COMPLETE % VOLATILE(BY WT.): 29% CORROSIVE ACTION ON MATERIALS: CLEAR, BROWN LIQUID WITH A SLIGHT ACIDIC ODOR. SP.GRAVITY(WATER=I): 1.433 EVAP. RATE(WATER=l): 1.1 FREEZING POINT: - 28 DEGR F. PHOSPHOROUS(%p): 18.9% PH AT 25 DEG. C: 1% SOLN. AT 1.6 OTHER: NA CORROSIVE TO ALUMINUM, COPPER, BRASS, TIN AND OTHER SOFT METALS. 10 -SECTION X -TOXICOLOGY INFORMATION PHOSPHORIC ACID IS CORROSIVE AND CAUSES DESTRUCTION OF TISSUES. PHOSPHORIC ACID TOXICITY ACUTE ORAL LD50 - (RAT) 1530 MG/KG (RTECS) ACUTE DERMAL LD50 - (RABBIT) 2740 MG/KG (RTECS) DEMAND ACUTE ORAL LD50 RAT MALE 2620 MG/KG (DWC) DEMAND ACUTE ORAL LD50 RAT FEMALE 1300 MG/KG (DWC) DEMAND ACUTE DERMAL TOXICITY RABBIT - GREATER 2000 MG/KG (DWC) 11 -SECTION XI - ECOLOGICAL EFFECTS PESTICIDE DISPOSAL: PESTICIDE WASTES ARE ACUTELY HAZARDOUS. IMPROPER DISPOSAL OF EXCESS PESTICIDE SPRAY MIXTURES OR RINSATE IS A VIOLATION OF FEDERAL LAW. IF THESE WASTES CANNOT BE DISPOSED OF BY USE ACCORDING TO LABEL INSTRUCTIONS, CONTACT YOUR STATE PESTICIDE OR ENVIRONMENTAL CONTROL AGENCY, OR THE HAZARDOUS WASTE REPRESENTATIVE AT THE NEAREST EPA REGIONAL OFFICE FOR GUIDANCE. CONTAINER DISPOSAL: TRIPLE RINSE (OR EQUIVALENT). THEN OFFER FOR RECYCLING OR RECONDITIONING, OR PUNCTURE AND DISPOSE OF IN SANITARY LANDFILL, OR INCINERATE, OR IF ALLOWED BY STATE AND LOCAL AUTHORITIES, BY BURNING. IF BURNED STAY OUT OF SMOKE. ~' ! DIVERSE~ CORP.' ' MSDS for DEMAND - ANIONIC ACID SANITIZER Date Printed: 04-17-1990 Page 12 -SECTION XII - REGULATORY INFORMATION DOT NAME: DOT CLASS: IMO NAME: DOT EMERGENCY RESPONSE GUIDE NO. 60 DIVERSEY CORP. COMMODITY CODE: US FRT CLASS: TSCA INVENTORY: CERCLA RQ: DISINFECTANT, CORROSIVE LIQUID, N.O.S '(PHOSPHORIC ACID) UN1903 ' CORROSIVE (IMO CLASS 8) DISINFECTANT, CORROSIVE LIQUID, N.O.S (PHOSPHORIC ACID) UN1903 ' 980, 981, 982, 983 LTL 55 ALL COMPONENTS OF THIS PRODUCT HAVE BEEN INCLUDED ON THE TSCA INVENTORY. PHOSPHORIC ACID 5000 POUNDS = DEMAND - 17,857 POUNDS OR 1,498 GALLONS OF PRODUCT. 13 -SECTION XIII - SUPPLEMENTAL INFORMATION i ~'iREG. NO. 875-100 THE ABOVE INFORMATION IS BELIEVED TO BE ACCURATE AND DISCLOSES THE KNOWN HAZARDS FOR THIS PRODUCT AS OF THIS DATE BASED UPON INFORMATION AVAILABLE TO DIVERSEY CORP. NO ADDITIONAL WARRANTIES ARE MADE. DATE PREPARED: MARCH 13, 1990 MATERIAL SAFETY DATA SHEET & BY: REGULATORY ~;/0~/9~ IqEFiERENGE 'NB '~3 APPAItATU5 (5C3A) IN FIR2~ AP~EA. AND LONQ TISSUE. HARMFUL OR 1ATAL IF 4, IN4il~ON Z~ DZ~FI=U~TY BREATHZNQ, ~ET MZ. DZCAL ~MM~O~AT~LY FLUSK THOROU=HL¥ WITH PR~S~ WAT~ POR AT LEAST · Z~ S~E~ =LASSES O~ WATEa. DO NOT ZN~DC~ VOMZTzNo. OR DUSTY OO~ITZONS. ~TLV &NO NOT IN USE. ON ACIDS. WASH S?!LLARF. A THOaOU~HLY NZT~ WATE~. Away UL"rHo08 S~LZN~, REOYOLZN=, OR D=SPO8~ O~ GO'AINU. OTASSIUM HYDROXIDE - OAS OAS POLYACRYLATE - OAS CONTRACTOR'S '~','~~ APPROVAL FOR NEW CHEMICAL/HAZARDOUS MATERIAL/ PAINT AND/OR SEALER The following chemical/hazardous material~ paint and/or sealer requested to be approved for use at the Bakersfield Facility: has been This chemical will be used in the following ·way(s): It will be stored: The expected quantity to be stored at the 'facility: Minimum: / ~ ~-~ Maximum: Average at one time: ~"~-~3 Dates of storage: ~~ 5 ~' to The personal protective equipment (PPE) has been ordered for an arrival date of OR The PPE is already available, The following PPE is to be worn SAFETY~CONNWCHM,DOC- INFORMATION: 708/244-2501 MATERIAL SAFETY DATA SHEET St. Paul, Mim-~ SECTION !. IDENTIFICATION PRODUCT NAME: PRODUCT FORM: Domino/Amjet 3321 Makeup Liquid Mixture DATE OF PREPARATION 6/21/93 Absorbed Through Skin Harmful If Swallowed Vapors are Heavier than Air SECTION Il. HEALTH HAZARD SUMMARY Flammable Liquid Avoid Skin Contact NFPA System SECTION 111. COMPONENT HAZARD DATA COMPONENT TLV/PEL cas Reg. # Hethyl Ethyl Ketone 200 ~pm 78-93-3 r~-Propyl Alcohol 200 ppm 71-23-8 These solvents may be absorbed through skin. Listed Carcinogens: OSHA: None NTP- None ZARC- None #5! 1 0OMINO AM. JET, INC.. 1290 LAKESIDE DRIVE. GURNEE, IL 60031 (708) 244-2501 (REV 1/89) MATERIAL SAFETY DATA SHEET. Fort.- Domino/Amjet 3321 Makeup APPEARANCE AND ODOR: BOLLING POINT: ~75°F. SPECIFIC GRAVITY: .80 % VOLATILE BY WEIGHT: 98+% VAPOR DENSITY COMPARED TO AIR: SOLUBILITY IN WATER: pH: neutral EVAPORATION RATE: 5..7' (n bu ac=l) SECTION IV. PHYSICAL DATA Black liquid, ketone odor. Vapors are heavier than air. Solvents are soluble, solids precipitate. SECTION V. FIRE AND EXPLOSION DATA FLASH POINT: 24°F. LOWER EXPLOSIVE LIMIT: 2.0% AUTO IGNITION TEMPERATURE: 960°F- EXTINGUISHING MEDIA: A1 cobol foam, HAZARDOUS DECOMPOSITION PRODUCTS: carbon dioxide, dry chemical. CArbon dioxide, carbon monoxide, and possib]y %oxic hydrocarbons. SPECIALFiREFiGHTING PROCEDURES: Use self-contained breathing apparatus. UNUSUAL FIRE HAZARDS: Vapors are heavier than air and may %ravel distances along the floor. Keep sources ignition away. long of DOMINO AM JET, lNG., 1290 LAKESIDE DRIVE, GURNEE, IL 60031 (708) 244-2501 DomJno ~ $~- Paul. Minn. SECTION VI. HEALTH HAZARD DATA A. ACUTE EFFECTS OF OVEREXPOSURE. EYES' Ca~n cause severe irritation, redness', blurred vision,tearing. SKIN: Ca~ cause moderate irritation, drying, and dermatitis; ca~ be absorbed through the skin in' ~ox{c amounts from repeated a~d prolonged exposure. BREATHING: Excessive inhalation of vajuors ca~ cause nasal a~d lung irri~tion, dizziness, weakness,' fatigue, nausea, and even possible asphyxiation. INGESTION: Can cause gastrointestinal irritation, nausea, vomiting, diarrhea, blindness, and death. B. FIRST AID PROCEDURES: SKIN: Wash thoroughly with soap &nd wa~ar. Remove contaminated clo- thing and launder before, reuse. EYES- Flush repeatedly with large amount-s of wa~r, lifting upper ~d lower lids occasionally; ge~ ~dical ~t%en~ion. ZNGESTZON: Give two glasses o¢ wa~er ~d induce vomiting i~dieCely. (Stick finger down throat.) Call a physici~. Never give ~y~hing by ~u~h to an unconscious person. ~ZNG: Zf affected, ~ve to fresh air. Zf breathing is difficult, administer oxygen. ~f brea~hing has s~pped, give a~ificiai resoir~ion and ge~ ~dical'~n~ion. C. CHRONIC.EFFECTS OF OVEREXPOSURE: Chronic overexposure to components of this product have been found to have ~he following effects on labor&0ory animals: liver abnormalities, damage to the kidneys, lungs, brain, eyes, spleen, &nd central nervous system. Overexposure of humans tx: component~s of %his product have been suggested as the cause of the following effects in humans: kidney damage, eye damage. Form ~¢512 DOMINO AMJET, /NC.. 1290 LAKESIDE DRIVE, GURNE~, IL 604331 (708) 244-2501 (REV 1/89) MATERIAL SAFETY DATA SHEET FOR: Domino/Amjet 3321 Makeup SECTION Vll. REACTIVIT? HAZARDOUS POLYMERIZATION WILL NOT OCCUR. PRODUCT IS STABLE- IHCOMPATIBLE WITH THE FOLLOWING CHEMICALS. 'strong oxidizers. SECTION Vlll. PERSONAL PROTECTION· AND CONTROLS A. VENTILATION AND RESPIRATION.. Do not; use i n a c] osed area wi thout vent;ilat;ion. Keep vapors below the TLV or use a NZOSH approved resDirat;or fdr org~-nic' solvents. B. EYE PROTECTION: Use safet;y glasses, preferrably wi~h side-shields. C. SKIN PROTECTION: Use solvent resistan% gloves; i.e., nitri'le rubber. D. OTHER Avoid breathi,rig mist;s of ink. Remove stains from skin with pumice soap or.use light rinse of denatured alcohol. SECTION IX. SPILL AND LEAK PROCEDURES A. SMALL SPILL: Cover wi%h sand, vermicu]it;e, eart;h, or other inert m~-- rial. Transfer t;o container for disposal. B. WASTE DISPOSA~e: Do not flush down the drain. Zncinerate according to the law or recycle through licensed firm. SECTION X. STORAGE AND HANDLING PRECAUTIONS Keep sources of ignition away. Storage of this product above 100°F. m~y void the warrant;Y. Containers of t;his material may be hazardous when emptied Since empt;ied containers retain product residues (vapors, l iduid, Solids.) all hazard precaut;ions ment;ioned in this da%'~ sheet must be ob- served when handling emptied containers. This product; contains ~he following chemic&Is subject to reporting under Sec%ion 313 of Title ZZ]:: Hethy1 ethyl ketone = <100%. THE INFORMATION ACCUMULATED IS 8EL/EVED TO 8E CORRECT. BUT IS NOT WARRANTED. DOMINO AMJET, INC., 1290 LAKESIDE DRIVE. GURNEE. IL 60031 (708) 2~4-2501 OIVERSEY WATER TECHNOLOGIES INC. P.O. Box 200 Chagrin Falls, OH 44022 (216) 247-5000 For sales office or product literature call (800) 669-0053 FOR MEDICAL EMERGENCY, CALL COLLECT (21.6) 835-7233 I Z. Ca. Page 1 of 4 SECTION I: PRODUCT IDENTIFICATION TRADE NAME: EG-5680 CHEMICAL NAME: Polymer/phoSphonate/caustic CHEMICAL FAMILY: InduStrial Boiler Water Treatment MATERIAL SAFETY DATA'SHEET Rev. ~ 4 501 SECTION II: HAZARDOUS INGREDIENTS 19 soditlm hydroxide 34 hydroxyethylidene diphosphonic acid 139 sodium polyacrylate copolymer CAS # % 1310-73-2 1-5 2809-21-4 1-5 25987-30-8 5-10 TLV/PEL 2mg/m3 'ceiling not est. not est. SECTION III: PHYSICAL DATA Boiling point (F): Vapor Pressure (mm Hg): Vapor Density (air=l): Solubility in Water: Density: like water like water like water complete 9.22 lbs/gal Specific Gravity: 1.106 Percent'Volatile by volume: 82 Evap. Rate (water=l): like water pH: 12.7 pH (1% soln.): 11.6 Appearance and Odor: Clear brown liquid, slight amm°niacal odor. SECTION IV: FIRE PROTECTION INFORM. ATION Flash Point: NA Flammable Limits: NA Extinguishing Media: Water, carbon dioxide, dry chemical or foam. Special Fire Fighting Procedures: Unusual Fire and Explosion Hazards: Keep drums that are exposed to fire cool with water. Wear protective equipment and SCBA Irritating and/or toxic gases and aerosols may be present during a fire. National Fire Protection Association (NFPA) Rating (in fire conditions): Toxicity: 1 Fire: 0 Reactivity: 0 Special: - Hazard Rating: 4=extreme 3=high 2=moderate l=slight 0=insignificant Date: 11/92 Page 2 of 4 'EG-5680 SECTION V: HEALTH HAZARD INFORMATION PRIMARY ROUTE(S) OF ENTRY: Skin: X Eye: X Inhalation: X Ingestion: X Acute Effects of Exposure: May irritate or damage eyes, skin and mucous membranes. Prolonged skin contact may cause itching, reddening or swelling. Irritating to the respiratory tract on inhalation. Local effects of acrylamide monomer exposure may be peeling redness~of skin or hands, numbness of limbs, and excessive,sweating of hands and feet. Systemic effects include weak or absent reflexes. Chronic Effects of Exposure: No known chronic health effects. (Reference to OSHA, NTP, IARC) Not a suspected or confirmed carcinogen. Medical Conditions Which May Be Aggravated By Handling This Product: Persons with impaired breathing may be at increased risk if concentrated mists are inhaled. Open wounds, rashes or sores may be irritated.. Emergency and First Aid Procedures: Skin: Eyes: Flush with water, then wash thoroughly with soap and water. Flush with water for 15 minutes and seek medical attention. Ingestion: Drink plenty of water and call collect (216)835-7233 or consult physician immediately. Avoid alcoholic beverages. Do not give anything by mouth to an unconscious person~ . Inhalation: MOve victim to fresh air. Seek medical attention if breathing difficulty persists. Apply artificial respiration if necessary. FOR 24 HOUR EMERGENCY MEDICAL INFORMATION CALL COLLECT (216)835-7233 (TEL- SAFE) For additional non-emergency information call: Date: 11/92 Safety and Regulatory Dept. Diversey Water Technologies P.O. Box 200 Chagrin Fal!s,. OH 44022 (216) 247-5000 Page 3 of 4 ....... === ..... = ....... =-== ........ ' EG-5680 SECTION VI: ~ REACTIVITY DATA . . ................ Stable: Yes: X No: Hazardous Polymerization: Yes: No: X Conditions to Avoid: None known Materials to Avoid: Strong acids and oxidizing agents. Hazardous Decomposition Products: Thermal decomposition may produce carbon monoxide, phosphines. carbon dioxide and/or SECTION VII. SPILL OR LEAK PROCEDURES/WASTE DISPOSAL ...................... Spill or Leak Procedures: Contain spill if without risk. Small spills may be neutralized with a weak acid in a well ventilated area and flushed to sanitary sewer with excess water if in accordance with local, state and federal guidelines. Larger spills should be absorbed with inert material such as clay, sawdust or sand and placed in drums for disposal. Waste Disposal: This product may qualify as a RCRA hazardous waste if pH is greater than 12 4 at time of disposal. Dispose of in accordance with local, ' requirements, state and federal Additional Regulatory Information: CERCLA: sodium hydroxide/RQ 1000lbs; EG-5680/RQ 28,000 lbs. SARA Title III: Sec. 313 Toxic Chemical Release - This product does not contain ingredients on the List of Toxic Chemicals. Sec. 302-304 Extremely Hazardous Substances - This product does not contain ingredients on the Extremely Hazardous Substance List. Sec. 311-312 Inventory Reporting, Hazard Category - Immediate (acute) California Proposition 65: This product contains <0.001% acrylamide which is known to the state of California to cause cancer or reproductive toxicity. Date: 11/92 Page 4 of 4 SECTION VI!I: Eye: OCCUPATIONAL PROTECTIVE EQUIPMENT Chemical safety glasses or face shield. EG-5680 Respiratory: Not required under normal .conditions of use. Skin: Rubber or impervious gloves. Local Exhaust: Other: Recommended in confined spaces. Mechanical exhaust ventilation- sufficient to remove air contaminants from operator's area. Rubber apron if splashing likely, eye wash and emergency shower equipment. SECTION IX: PRECAUTIONARY MEASURES Avoid skin and eye contact. Do not take internally. Keep container closed when not in use. Avoid breathing Vapors or mists. 'Wash thoroughly after handling and before eating, drinking, or smoking. Refer to the "Material Safety Data Sheet Glossary of Terms" for additional information. SECTION X: TRANSPORTATION INFORMATION DOT Label: DOT Proper Shipping Name: DOT Hazard Class/I.D. #: U.S. Surface Freight Classification: Corrosive Alkaline(CorrOsive)Liquid N.O.S (contains sodium hydroxide) Corrosive Material, NA 1719 Compounds, Boiler Preserving, Liquid SECTION XI: ADDITIONAL INFORMATION FDA: Conforms with 21 CFR 173.310 for boilers producing steam which may contact food. USDA: Approved for use in boilers producing steam which may contact food. EPA: Aquatic Toxicity: Ail ingredients reported on TSCA Inventory. Not tested. Date: 11/92 The information contained herein is furnished Without warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must make independent determinations of the suitability aP completeness of information from all sources to assure proper use and disposal of these materials and the health of employees and customers. ORDER'"'NO, APR"IZ MH ~, . MATERIAL SAFETY DATA sHEET REpoRT' ~ OOI .MOs NO ~z~,'o~o ~F~i~ · . '. , "' ~ :e~e - FOAM[ ' ":- ....... ......... ~== SECTION I --PRO~CT"IDENTIFICATi'~' .... ' ......... '~ ~-" ~*~MRNUFA CTURER ~~.~.~.~~***Z, HOUR 'E~ER~ENC~ AS S ~ ST ANCE.~***~*~ ~ · · D~V ERSEY 'CORP. * MEDICAL-COLLECT- -303~592_ 102~ ~ I53g BIDDLE AVENUE ~ CHEMTREC " ' .800~2~.9.300 ~ WYANDrOTTE~ MI ~8192 * DIVERSEY CORP. -313.281_0930 *HAZARD RATINGS. *HEALTH. *FLAMMABILITY. *REACTIVITYo ' *SPECIAL/PPEo NFPA- 2 0 0 ALK. HMI S- 2 0 0 B K EY-Z~-EXT RiME 3-HIGH 2-MODERATE 1-SLIGHT COR-C '~.RDSI VE AC-ACID ALK'-ALKAL[ NE OX-OXIDIZER PPI CODES--REFER TO HMIS SYSTEM DOCUMENTATION- O-INSIGNIF ICANT EMERGENCY OVERVIEW WARNING - CAUSES EYE AND SKIN IRRITATION OR BURNS. IF SWALLOWED. MAY BE HARMFUL DO NOT GET PRODUCT IN EYES,, ON SKIN,~ OR ON CLOTHING. WEAR EYE PROTECTION SUCH AS GOGGLES OR SIDE SHIELD SAFETY GLASSES~ CLOTHING~ OR RUBBER GLOVES TO PREVENT PROLONGED SKIN CONTACT WHEN USING PRODUCT. WASH 'AFTER HANDLING P.q,'IDUCT O~ PREPARING DILUTIONS. AVOID BREATHING DUST. MIST OR PRODUCT SPRAY. KbcP OUT OF REACH OF CHILDREN. I NC, RE DIEN TS CAS NUMBER CHEMICAL COMPONENT * * ACGIH ~ OSHA . HAZARD * ~ ~ TLV ~ P'EL ~ CODES 5z+08-80-6 C.I. ACID BLUE #1~+5 LT. 1 NE 583~+-92-0 SODIUM METASILICATE 7' NE 7732-19-5 WATER 75-05 NE 3~+590-94-8 · DIPROPYLENE GLYCOL METHYLETHER 3-5 600 MG/M3 55~+39-57-6 SODIUM ALPHA OLEFIN SUL FONA TE ~AZARD CODE KEY- O-NONREGULATEO 3-SARA 311/312 LT - LESS THAN 7-9 NE 1- OS HA-Z 9C FRI 9I O. I200_ 4-SARA 3 I3 NE - NOT ESTABLISHED *=~********~*** SECTION II - POTENTIAL HEALTH EFFECTS SYMPTOMS OF EXPOSURE- EYES- CONTACT OF EYES WITH PRODUCT CAN CAUSE MODERATE TO SEVERE IRRITATION RESULTING IN PAIN, REDNESS, AND POSSISLE REVERSIBLE CORNEAL DAMAGE. NE 0 NE 1/2/3 NE 0 IOOMG/M3 1/2 NE 0 Z-STATE RTK LAWS GT - GREATER THAN SKIN-- THIS PRODUCT MAY CAUSE MILD TO MODERATE IRRITATION AFTER PROLONGED CONTACT RESULTING IN REDNESS~ PAIN,, ITCHING. AND 0.RDER'NO' APR 12 MH OIVERSEY CORP. MATERIAL SAFETY DATA SHEET REPORT MSDS NO -126010 F.A,C. - FOAMING LIQUID ALKALINE CLEANER **~:~****~'~*******~ SECTION II - POTENTIAL HEALTH EFFECTS "PAGE 002 POSSIBLE DRYING OF SKIN. THE SEVERITY OF SKIN EFFECTS DEPENDS ON THE STRENGTH OF 'SOLUTION .AND LENGTH OF CONTACT. I NGES TI'ON- MAY BE HARMFUL' IF SWALLOWED. MAY CAUSE DIARRHEAs· VOMITING, AND GASTRIC DISTRESS WITH PAIN. INHALATION- INHALATION OF AIRBORNE' CONCENTRATIONs-OF DUSTE*MIST OR SPRAY OF THIS PRODUCT MAY CAUSE-SLIGHT' IRRITATIONS OF NOSE AND THROAT. PRINCIPAL' ROUTES OF ABSORPTION- DIRECT CONTACT-SKiN, EYES-- YES TARGET ORGANS- NONE KNOWN. INGESTION- YES INHALATION- ' NOT VOLATILE EFFECTS OF' OVE,~EXPOSURE- ACUTE- CAUSES EYE AND SKIN IRRITATION OR BURNS. CHRONIC- NO KNOWN HAZARDS. CONTAINS LISTED CARCINOGENS- NO NATIONAL TOXICOLOGY PROGRAM- NO IARC MONOGRAPHS- NO OSHA- NO [CAL' 'CONDITIONS GENERALLY A,,,~,RAVATED BY EXPOSURE- DERMATITIS ,IR RELATED SKIN CONDITIONS. INHALED DUST OR SPRAY MAY AGGRAVATE RESPIRATORY DISEASE OR CONDITIONS~ FIRST AID PROCEDURES--NEVER GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAVING CONVULSIONS,. CALL A PHYSICIAN. ~YES- IN CASE OF CONTACTt I~MEDIATELY FLUSH EYES WITH PLENTY OF -WATER. GET MEDICAL ATTENTION. SKIN- [NGESTi ON- INHALATION- FLUSH PRODUCT FROM SKIN WITH WATER. CONTAMINATED CLOTHING BEFORE REUSE. PERSISTS, SEE;< MEDICAL ATTENTION. REMOVE AND LAUNDER IF SKIN IRRITATION IF SWALLOWED, RINSE MOUTH WITH WATER. DILUTE BY DRINKING SEVERAL GLASSES OF WATER. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION. NOTE- NEVER GIVE FLUIDS BY MOUTH OR INDUCE VOMITING IN AN UNCONSCIOUS PERSON. IF INHALED, REMOVE TO FRESH AIR. IF BREATHING'CONTINUES TO ~E DIFFICULT, GET MEDICAL ATTENTION. · :**************~ SECTION IV- FIRE AND EXPLOSION FLASH POINT- NOT COMBUSTIBLE LOWER FLAM. LIMIT- EXTINGUISHING MEDIA- WATER, FOAM C02, UPPER FLAM. LIMIT- DRY CHEMICALS, WATER FOG NONE KNOWN NONE KNOWN M'D~11 DIVERSEY CORP. ORDER' NO APR'I'Z MH MATERIAL SAFETY DATA SHEET .REpoRT.: PAGE 003 M$gS NO '126010 ' 'F.A.C' - FOAMING 'LIQUID ALKALINE CLEANER, 0~/12/91 ****-*****~****~=**** SECTION IV- FIRE AND EXPLOSION ****************** ? ~,CI AL FIRE i .HTING PAOCEDURES- WEAR FULL PROTECTIVE GEAR TD PREVENT SKIN'CONTACT WITH .SOLUTIONS AND SELF CONTAINED BREATHING APPARATUS' IN FIRE AR.EA, DEGREE DF iFIRE 'AND EXPLOSION HAZARD- NOT A COMBUSTII)LE PRODUCT. STABILITY- STA~LE HAZ. POLYMERIZATION- NONE KNOWN. CONDITIONS TO AVOID- TO PREVENT DE£OMPOSING. STORE IN DRY' AREA WITH TEMPERATURES LOWER THAN 2OD.DEGREE F. CONTAMINANTS THAT MAY AFFECT STABI.LITY- NONE KNOWN, INCOMPATIBILITY- AVOID MIXING WITH ACIDS AS CARBON DIOXIDE VAPOR WILL BE RELEASED, HAZ. DECOMPOSITION PRODUCTS- THERMAL DECOMPOSITION MAY FORM CARBON DIOXIDE AND MONOXIDE. ** *~x-~ ,= ** ** ** ~=** *~ SECTION VI- SPILL AND LEAK RESPONSE *=~*******~=~==~e.~ SPILL RESPONSE- CONTAIN SPILl, MOP UP PRODUCT. SMALL AMOUNTS MAY BE FLUSHED TO A SANITARY SEWER, LARGE AMOUFITS SHOULD 8E PACKAGED AND DISPOSED OF IN ACCORDANCE WITH LOCAL REGULATIONS. WASH AFFECTED AREA WITH WATER. WASTE D.I:SPFJSAL- SMALL AMOUNTS MAY ~E DILUTED WITH WATER AND DISCHARGED TO A SANITARY SEWER. LARGE AMOUNTS SHOULD 8E DISPOSED OF IN ACCORDANCE WITH FEOERAL~ STATE, AND LOCAL REGULATIONS, *~'*'~************* SECTI ON VII - PERSONAL PROTECTION/EXPOSU RESPIRATORY PROTECTION- USUALLY NOT REQUIRED. IF BREATHING DIFFICULTY SUCH AS COUGHING~ WHEEZING' OR IRRITATION ARE REPORTED 8Y EXPOSED PERSONS, MONITOR AREAS FOR CONTAMINATION, VENTILATION- L.-~CAL EXHAUST- USUALLY NOT REQUIRED, GENERAL- FOR SPRAY OR ~[ST AREAS~ USE ADEQUATE VENTILATION TO MAINTAIN EXPOSURE BELOW GUIDELINES, EYE PROTECTION- SPLASH GOGGLES OR FACE SHIELD OR SIDE .SHIELD SAFETY GLASSES. PROTECTIVE GLOVES- RUBBER, PVC OR OTHER CHEMICAL RESISTANT 0 .. ~R PROTECTIVE EQUIPMENT- CHEMICALLY IMPERVIOUS CLOTHING AND FOOTWEAR TO PREVENT SKIN CONTACT, SAFETY SHOWER AND EYE WASH IN USE AREA. HYGIENE' PRACTICES- WASH AFTER HANDLING OR USING PRODUCT, LAUNDER MD11' DIVERSEY 'CORP. · . PAGE 004 ORDER 'NO APR 12 MH MATERIAL SAFETY DATA SHEET REPORT MSDS NO ' 126010 FeAeC. - FOAMING LIQUID' ALKALINE' CLEANER L~,..,. ....0~/12/9I ****=m**-~_****=****~ SECTION VII - PERSONAL PROTECTION/EXPOSU CONTAMINATED CLOTHING ~EF~E REUSE. CLEAN OR R~PLACE CONTAMINATED FOOTWEAR 'BEFORE USE. e~e~=~=~=~ SECTIO~ VIII - STORAGE' 'AND HAN~ING KEEP 'AWAY FROM AC[DS. STOLE IN A DRY AREA. KEEP' CONTAINER .CLOSED WHEN MOVING OR NOT IN USE. KEEP O~ OF REACH OF CHILDREN. DO NOT 'STORE WITH FOOD. KEEP FR~M ~EEZING. STORAGE MATERIALS- DRUMS AND CONTAINER USED FOR STORAGE OF TRANSPORTING OF THE PRODUCT MAY BE UNLINED STEELe STAINLESS STEELs HIGH DENSITY POLYETHYLENE't OR REINFORCED FIBERGLASS. CONTAINERS OR TANKS USED FOR 'DILUTING PRODUCT MUST BE CAPABLE OF WITHSTANDING LOCALIZED HEATING OF 200 - 300 DEG. F. PIPING CAN BE CARBON STEEL-SCHEDULE ~O- OR P¥C -SCHEDULE 80-. CONSULT DIVERSEY CORPo TECHNICAL REPRESENTATIVE FOR ADDITIONAL INFORMATION. *'t'****'~"~*~**=~'e-~* SECTION' IX- PHYSICAL AND CHEMICAL PROPE APPEARANCE AND ODOR-' CLEAR~ 6LUE LIQUID WITH A MODERATE SWEET SOLVENT ODOR. MELTING POINT-. NA SPoGRAVIT¥-WATER-1-- 0,96 COILING POINT- 212 DEG.. F VAPOR PRESSURE- 22,6 MM HO/20 DEG, C VAPOR OENSIT¥- - I SOLUSILITY IN WATER- COMPLETE VOLATILE-By ,~/T.-- 12% C IESIVE ACT ION Om MATERI ALS- NONE KNOWN. EVAP. RATE-WATER-I-- - 1 FREEZING.POINT- 29 DEG. :F ~2 DEG. C- PHOSPHOROUS-%p-- NONE PH AT 25 DEG, C- l~ SOLN OTHER- NONE KNOWN *****~**~*~-'~*~*~*e SECTION X -TOXICOLOGY INFORMATION ALKALI~E METAL SILICATES 'ARE A SEVERE IRRITATION TO EYEt MUCOUS MEMSRANES. SKIN~ AND SODIUM -OR POTASSIUM- METASILICATE ACUTE ORAL LDSO -RAT- 1153 MG/KG -RTECS- ACUTE ORAL LDLO -DO~- 250 MG/KG -RTECS- THE ESTIMATED ORAL TOXICITY OF THIS PRODUCT FOR ANIMALS IS 17,00 MG/KG. **~'*~=~'***********~ SECTION X I - ECOLOGICAL EFFECTS ****=***...,~***~,~ THIS PRODUCT IS ALKALI~Eo LA~GE AMOUNTS OF PROCESS WASTE SOLUTIONS ~EQU[~E NEUTRALIZATION TO A SPECIFIC PH STRENGTH BEFORE D[S~HARGE TO PU6L[C O~ PRIVATE SANITARY SEWE~ SYSTEMS. SOLUTIONS MAY ~E TOXIC AQUATIC LIFE. O0 NOT DISCHARGE UNTREATED SOLUTIONS TO LAKES, STREAMS OR PONDS, CONTAINER DISPJ SAL- WHEN EMPTY~ THIS CONTAINER AND LINER MAY STILL BE HAZARDOUS, TRIPLE RINSE CONTAINER AND LINER WITH WATER AND ADO TO USE SOLUTION OF PRODUCT. DELIVER CLEANE~ CONTAINER TO A DRUM RECYCLER OR DISPOSE OF IN ACCORDANCE WITH ENVIRONMENTAL RE GULAT[ ONS. *******~=*********¢ SECTI ON XII - REGULATORY INFORMATION DOT NAME- NON DOT kEGULATED ,DOT CLASS- NON REGULATED 'ORDER '.NO APR 12 MS DIVERSEY CORP, MATERIAL SAFETY DATA SHEET REPORT' MSD5 NO .1260[0' F.A.C.- FOAMING LIQUID ALKALINE CLEANER :e'~.=~,~.~=e~,e,~,~=m-~=:e~ SECTION XII -REGULATORY Ih!::ORMATION P~T ' EMERGENCY ',ESPONSE GUIDE NO. NOT APPLICABLE DIVERSEY CORP. CDMMDDIT¥ CDDE- US FRT CLASS- TSCA INVENTDRY- C ERCL A 'RQ- .PAGE 005 370 LTL 55 ALL 'COMPONENTS OF THIS PRODUCT HAVE BEEN INCLUOEO ON THE TSCA INVENTORY. NO RQ ESTABLISHED FOR THIS PRODUCT. SECTION XIII - SUPPLEMENTAL INFORMATION THE ABOVE iNFORMATION IS BELIEVED TO BE ACCURATE AND DISCLOSES THE KNOWN HAZARDS' FOR-THIS PRODUCT AS OF THIS 'DATE BASED UPON INFORMATION AVAILABLE TO DiVERSE¥ CE~P. NO ADOITIONAL WARRANTIES ARE MADE, ~ATE PREPARED- AUGUST 1~, 1990 ~ END OF MSOS ~.~ .DER NO. APR i2 MH' CUSTOMER NO. z ooooo TOMORROW FOODS 7301 DISTRICT 8LVD DEAR VALUED CUSTOMER- BAKERSFIELD CA 93313 DIVERSEY CORP, IS PLEASED TO PROVIDE THE ENCLOSED MATERIAL SAFETY DATA SHEETS -MSDS- FOR PRODUCTS WHICH YOU HAVE RECENTLY PURCHASED, AS PART OF O~JR CONTINUING COMMITTMENT TO THE HEALTH AND SAFETY OF OUR CUSTOMERS AND PROTECTION DF THE ENVI'RONMENTt ~IVERSEY CORP. HAS ~MPLEMENTED A COMPUTER BASED MSDS FILE AND O!STRI3UTION SYSTEM, THE NEW MSDS' CONTAIN MUCH MORE DETAILED INFORMATION THAN IN THE PAST AND THE DISTRIBUTION TRACKING SYSTEM WILL ENSURE THAT YOU RECEIVE AN MSDS WITH EACH FIRST TIME ORDER OF A PRODUCT OR WHENEVER A REVISION TO THE PRODUCT M-~OS HAS THE OSHA HAZAR~ COMMUNICATION STANDARD REQUIRES THAT THIS .~NFORMATION BE PROVIDED TO ANY PERSON WHO MAY COME IN CONTACT '~ITH THE ~qATERIAL. AS AN EMPLOYER YOU ARE REQUIRED TO MAKE THIS INF~RMATION AVAILABLE TO YOUR EMPLOYEES. IF YOU REDiSTRibUTE THESE PRODUCTS YOU MUST SUPPLY AN MSDS TO THE ~OWNSTREAM USER. ~,~ YOU HAVE ANY QUESTIONS OR REQUIRE ADDITIONAL INFORMATION R-m-GARDING THESE PRgDUCTS~ PLEASE CONTACT YOUR LOCAL SALES qEPRE.SENTATIVE OR THE DIVERSEY CORP, MSDS DISTRIBUTION CENTER -i-800_52i_8iz~0 OR 1-800-z~B2-80iO IN MICHIGAN-. ~ONALD E., 8OSSOW ,MANAGER - HEALTH~ SAFETY ~ ENVIRONMENT ~IVERSEY CORP, ~NCLOSURE 4, T, BAKER CHEMICAL CO, 222 RED SCHOOL LANE, PHILL'IPSBURG, NJ 08865 ~ -"' .... M'A T E R I A L S A F E T y D A T A S H E E T .~ '24-HOUR ENERGENCY TELEPHONE -- (201') 859-2151 CHEMTREC ~ (800) 424-9300 -- NATIONAL RESPONSE CENTER # (800) 424-.8802 a 8 o - o 2 EFFECTIVE: 08/07/86 PAGE: 1 ISSUED: 08/15/86 SECTION I - PRODUCT IDENTIFICATION' PRODUCT.NAME: FORMULA: FORMULA WT: CAS NO,: NIOSH/RTECS NO,: COMMON SYNONYMS: PRODUCT CODES: HC1 36,~6 76~7-01-0 MW~025000 MURIATIC ACID; CHLOROHYDRIC ACID; HYDROCHLORIDE 95~3~9539~9535'5367,9534,95~4,9529,95~2~800,9549,9530,95~8, 9540, 9547, 9546, 9537 PRECAUTIONARY LABELLING ~AKER SAF-T-DATA(TM) SYSTEM HEALTH - 3 (POISON) SEVERE FLAMMABILITY - O REACTIVITY - 2 (MODERATE) CONTACT - 3 (SEVERE) FrqECAUTIONARY LABEL STATEMENTS SECTION II - HAZARDOUS CONPONENTS COMPONENT % C~S NO, HYDROCHLORIC ACID (23 5AUM~) ............................... 35-~0 76~7-01-0 SECTION IIi - PHYSICAL DATA ~O!LING POINT: MELTING POINT: 5CIFIC GRAVITY: (H20:1) ilo C ( 230 ~) -25 ~ ( -13 ~) 1,19 VAPOR PRESSURE(HM HG):N/A VAPOR DENSITY(AIR=I): 1.3 EVAPORATION RATE: N/A (BUTYL ACETATE=l) CONTINUED ON PAGE: 2 J.' I'o BAKER CHEMICAL CO. 222 RED SCHOOL LANE, 'PHILLIPSBURG, NJ 08865 M A T E R I A L- S A F E T y D A T A S H E E T .. 24-HOUR EMERGENCY· TELEPHONE-- (201) 859-2151 CHEHTREC A~ (800) z~2z~-9300. __ NATIONAL RESPONSc CENTER ~ (800) z+2z~-'8802 890-02 HYDROCHLORIc ACID EFF_ECTIVE: 08/07/86 PAGE: 2 ....... ISSUED: 08/15/86 SECTION III - PHYSICAL DATA (CONTINUED) SOLUBILITY(H20): AP ~ARANCE ~ ODOr: p~ COMPLETE (IN ALL PROPORTIONS) % VOLATILES.BY VOLUME: 100 CLEAR, COLORLESS OR SLIGHTLY YELLOW, PUNGENT, FUMING LIQUIO SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT: N/A NFPA 704H EATING: 3-0-0 FLAMMABLE LIMITS: UPPER - N/A .% LOWER - N/A % FIRE EXTINGUISHING MEDIA USE EXTINGUISHING MEOZA APPROPA~ATE FOR SURROUNDING FIRE. FtREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE MOVE CONTAINERS F~OM FIRE AR~A ~F IT' CAN B~ DONE WITHOUT RISK USE ...... · WATER TO KEEP PIRc-:XPOSED CQNTAINEP, S COOL; DO NOT GET WATER iNSIDE CONTAINERS, SECTION V - ifiEALTH HAZ.ARO DATA PEL AND TLV LISTED DENOTE CSILING L!~iT. TH R~_SHOLD LIMIT VALUE (TLV/TNA): 7 MC,/M3 PERMISSISLE EXPOSURE LI¢~IT (PEL): 7 CIG/M3 (5 PPM') TOXICITY: LDEO (ORAL-AA,~ ' , cBIT)(MG/KG):900 LD~O (IPR-~'~OUSE)(,MG/KG): 40 LCSO (INHL-RAT-IH) (ppM): 3124 CARCINOGENICITY: NTP: NO !ARC: ~;O Z LIST: NO OSHA REG: NO ' ,~,~ - n ~. T. BAKER CHEMICAL CO. 222 RED SCHOOL LANE, PHILLIPSBURG, NJ ' 08865 , M A T E R I A L S A F E T Y D A T A S H E E T 24-HOUR EMERGENCY TELEPHONE -- (201) 859-2151 .,. CHENTREC ~ (800) ~24-9300 -- NATIONAL RESPONSE CENTER ~ (800) ~2~-8802 · 880 -02 HYDROCHLORIC ACiD . EFFECTIVE: 08/07/86 PAGE': 3 ===== ====================== ....... ISSUED: 08/i5/86 =============_ : ___===== SECTION VI - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: MILL NOT OCCUR CONDITIONS TO AVOID: HEAT, MOISTURE INCOMPATIBLES: MOST CO~HMON METALS, WATER, AMINES, METAL OXIDES, ACETIC ANHYDRIDE, PROPIOLACTONE, VINYL ACETATE, MERCURIC SUL- FATE, CALCIUM PHOSPHIDE, FORHALDEHYDE, ALKALIES, CARBON ATES, STRONG BASES, SULFURIC ACID* CHL'OROSULFONIC ACID DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE, HYDROGEN, CHLORINE .... SECTION VII - SPILL AND DISPOSAL PROCEDURES ~AR SELF-CONTAINEO BREATHING ,APPARATUS aND-F'U'~-~" PROTECTIV~Z CLOTHING. STOP AK IF YOU CAN DO SO WITHOUT RISK. VENTILATE A,~EA. NEUTRALIZE SPILL WITH SODA ASH DR LI?IE. WiTH CLEAN SHOVEL, CAREFULLY PLACE H.ATERIAL INTO CLEAN, DRY CONTAINER AND COVERi REMOVE FROM AREA. FLUSH SPILL AREA WITH WATER. d. T. ~AKER NEUTRASORE(R) OR ~EUTRASOL(R) "LOW HA+" ACID NEUTRALIZERS ARE RECO,~qHE,~OED FOR SPILLS OF THIS PRODUCT. bzS~OSAL PR, L]C ~DU~ E DISPOSE IN ACCOR£)A?~CE ;'~ITH ALL APPLIC,aELE F~,'-,'- ....... - ENVIRONMENTAL REGULATIONS. . ~:uc~,~_, STATe, AND LOCAL EPA HAZARDOUS ~4ASTE NU;'~ER: 0002 (CORROSIVE WASTE) SECTION VIIi - P?,OTECTIVE E':~UI~Et4T VENTILATIOI',~: USE ~.~c~AL OR LOCAL EXHAUST VFNTILATION Ti] :'iL T TLV REqUIrEmENTS. RESPIRATORy PROTECTION: RESPIRATOry PROTECTION REQUI~ED IF AtR~O:~NE CONCENTRATION EXCEEDS TLV. AT CONCEF~TRATZONS UP TQ 100 Pp~I, A CHE?IICAL CAkT~iDGE R:_fiSPI~ATOR WITH AC!g CA~,T~.IE)GE IS RECO~NDED. ~bOVE THiS-L~VEL~ A SEL~-CC)~,]TAINEO BREATHING APPARATUS IS ADVISED. SECT[O~t iX- STOR,-,,oc A~xlD 'HANDLING PRECAUTIO.,',.;S GAF-T-DATA(TH) ST~j..~,GE COLO~ COD~Z: WHITE ._ 6CIAL PRECAUTIONS . KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA. INCOMPATIBLE HATERIAL$. DO NOT STORE NEAR OX[:DIZING MATERIALS. CONTINUED ON PAGE': ~ ISOLATE FROM EFFECTIVE: 08/07/86 J,~ T. BAKER CHEMICAL CO. 222 RED SCHOOL LANE, PHILLIPSBURG,. NJ 08865 M A T E R I A L S A F E T y D A T A S'H E E T 2Z+-HOUR EMERGENCY TELEPHONE-- (201) 859-2151 CHEMTREC ~ (800) z~2z~-9300 -- NATIONAL RESPONSE CENTER q~ (800) /,24,-8802 ,880 .-02 HYOROCHLORIC ACID PAGE: '4 ISSUED: 08/15/86 SECTION iX - STORAGE ANO HANDLING'PRECAUTiONs (CONTINUED) SECTION X - TRANSPORTATION DATA AND ADDITIONAL INFORMATION · DOMESTIC (D,O,T.) PROPER SHIPPING NAME HAZARD CLASS UN/MA LABELS REPORTABLE ~UANTITY INTERNATIONAL (I.M.O.) PROPER SHIPPING N~ME HAZARO CLASS UN/NA LABELS HYDROCHLORIC ACID CORROSIVE HATERIAL (LIQUID) UN1789 CORROSIVE 5000 LBS, HYDROCHLORIC ACID, SOLUTION UN1789 CORROSIVE ,,zA = NOT APPLICABLE OR b~OT AVAILABLE THE INFORMATION PUBLiSH~D IN THIS MATERIAL SAFETY DA~A SHEET HAS BEEN COMPILED FROM OUR EXPERIENCE ANO DATA PRESENTED IN VARIOUS TECH~i!CAL PUBLICATIONS. IT IS TIiE USER'S RESPONSIBILITY TO DETERMINE THE S[JITAB-ILITY OF THIS INFORMATION FOR THE ADOPTION OF NECSSSARY SAFSTY PR~CAtJTIONS, WS RESERV~ THE RIGHT TO REVISE MATERIAL SAFETY DATA SHEETS PERIODICALLY AS NEW INFORMATION BECOMES AVAILABLE. -- LAST PAGE -- ,~A[IONAL SANITARY SUPPLY CO. '%3217 S. Figueroa Street 'LOS. ~ng'ek es, California 90061 b. mergenc¥ ~IeL. No. ~i3/327-6~9~ ~A~'ERIAL SAFET~ DATA SHEET bE~TION I. iDENT~F~CAT~ON OF PRODUC~ SECTION Cate ISsued: Supercedes: 11101189" .................... hationat Item#:: 2612XX 2. INGREDIENTS C S NUHBER PE~CENI EXPOSUfiE LIMITS IN ,2- BUTO XY ETHANOL ~i ~-- 76-2 1.40 iRi SODtUH PHOSPHATE !0!0 1800 1-Sff~ ~T~ESE MAT~Ri~5 A""= SU~JEC ,m= T TO iHE ~EPORTINE TjTLE ~l), SECTION ~13 AND 40 CFR PART )~. N/.~ = Not Appticable~ N/g = Mot Determined SECTION j. PHYSICAL DATA ...... OSHA PEL ACGT. H TLV RECEIVED OCT 0 8 1990 A-IR OTHER 0 'DETERMINED flE(~.UIREMENTS UNDER SARA Ooi {in~ Poinz (F~: 217_' Specific Gr'avit¥ Vapor Fressure (mm H~.): ( ~? Percent Volatile Vapor ~ensi.t¥ kA. ir=l : N/D Evapcration Rate moluDikity ~n Wa~er: SOLUDLF pH Ranqe: '~ppearance and ODor: PALE b~EEN~ MIL~. SWEETISH SCEMT ~ection 4. ~IKE AND EAPLOSYCN HAZARD DATA FlaSh Point (Test Method): NON FLAMMABLE E lamma~te L (mits: LEI.= N/A UEL= N/A cxt inguishin~ ~eoia: CU~, DRY CHEMICAL, FOAM, WA)ER FOG. apeciaL Fire Fi~htin~ Procedures: NORMAL FIRE F)6NTENG PROCEDURES M~Y BE USEd. C~.~L AN~ USE CAUTION WHEN APPROCHING OR HANDLING FIRE EXPOSED CON[ AtM~R~. unusual Fire 8 Explosion Hazards: CO,TALkERS MAY BURST SECTION (Water:l): 1.02 (By Votume): 86 ( =1): 1 TN.HEAT. atabi tit7: SIASLE ---' ......... incompdtibitit_z - MateriaLs to Avoid: THIS PRODUCT TS ALKALI IN NATURE AND T3 Nul- COiiPATi~L~ WITH STRONG ACIDS DO ~tO~ A~D OXIDIZING AGENTS (OL~ALH) T'O T~T5 PRODUCT. ' ' hazardous PoLymerization: WILL NOT OCCUr. Conditions to Avoid: ¢IONE KNCUN TO NSC ,azardous uecomposition Products: WHEN EAPOSEg TO FIRE, PeODbCES NORMAL SEC TiON o. 5PILL. IEAZ A~U OISPOSAL PROCEDURES 6Pi ll Xesponse: EON SWALL SPILLS. DILI.IT~ WITh WATER AND PICK UP WITH MOP A.,'~D PhIL :dP WET mlC~ U~ VACUUM. FO~ LAREE SPILLS, DIKE AREA TO CONTAIN SKILl_. GLZAN uP I)SINR ~OSOqBENT NATEPIAL. PL.aCE ALL CONTAMINATED ~roducz Oisposat: wASTE FOrt dILUTED PRODUCT ~y BF FLUSHED TG EEWER. U~IDILuTcD ~O~UCT PECOV~[~ FNOM SPILLS MAY ~E SENT TO A L)CKNSED DISPOoAL PAgT~TTY TO ~c DISPOSED OF TN ACCORnANCE WITH FEDER~L/ STATE REGuLATiONS AND LUCAL dR~INANCES. · Container Disposal: TPimu,? RINsm IMPLY CGNT~iHER THqOUGHL~ WITH WATER A[~D DZSC~AD [N RC~ULAR TR,q~H COLLECTION TF AELOW~D 8Y LGCAL, STATE AND Fc DE ~A L PCGULATiQhS. -' P AGE ? ~A[E~[."~L SAFETY-DAi'A SHEFT Da[~e Js Su ea,: .............................. . ..... TiON HEALTH HAZARD DATA ~y,aptoms of Overexposure: ............ E~e Contact: Y6 I~RTTANT. IF NUT PROMPTLy ~REATED. EYE DAMAGE MAy R~ SU LT. -' 5~in Contact: SKIN IRRTT,~NT. [RfiTTATTON MAY OCCUR' F~M FRaLO~GED CO~TACT gTTH THTS P~OgUCT ~EPEATED EKPOSgRE T~ THIS PRODUCT MAY LEAD TO DERHAIiTIS. " Inhalation: NO HEALTH E~FECTS AP~ KNOWN ~0 OCCUR FROM T~HALATION OF THTS PRODUCT.UNDER NORMAL 'USa. TN A ~rLL ~ENTTLAT~D ~REA.: HIGH AirbOrNE CONC~NT~ATION~ OF M~'STS OR ~PRAY OF' T~IS P~ODUCT MAY CAUSE [~RJTATIO~ ~ T~ UPPE~ RESPIRATORY TRACT. Tngeszion: iNGESTION OF THIS PRODUCT 'MAY CAUSE DAMAGE TG THE MeMbRANES OF THE MOuTfi, THROAT, AND GASTROTNTESTTNAL TRACT WHICH T~E P~OOUCT CUNTACTS. BURNS OF THE fiOUTH AND THROAT, ~AUSEA, V~MITING, CRAMPS AND DTARRHEA MAY OCCUR Primary Route(s) of Entry: EYES, SKIN ' E~TiOa ~. EM~RGEN ND FIRST AID F~OCEDURES ContacL: IMMEDiATELy ~LUSH THE EYE ~[TH L~RGE QUANTTTTES OF fiUNNJNG ~,ITE~ FON A'MAXTMU~ O~ 15 ~INUT~. HOLD iHE EYE LIDS *PART DURING THE IR~GAITuN TO INSURE ~LUSHING OF THE ENTIRE SURFACE OF TH~ EYE LID .AfER. ~ET M~OLCAL ,~TTENTTON [F ZRRTT,~TTON PERSISTS. .7 ~kin Contact: FLUSH I'H~ EFFECTEg AREA WITH LARG~ ~UANTITIES CF RUNNING WATER WH~LE REMOVING CONTAMINATED CLOTHES ~NO SHOES. WASH CLOTHING BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. 1n~a(azian: REMOVE FROM CONTAMINATED AREA. IF SYMPTOMS OF RESPIRATORY DISCOMFORT PERSISTS, GET ~E~ICAL ATTENTION. in~estion: R~u~RES IMMEDIATE ME~IC,~L MANAGEMENT. D~INK MILK OR WATER ANu GET MEU~CAL ADVICE. VOMITING SHOULD BE RECCMM~NDA'[~ON O~ MEDICAL PERSONNEL. INDUCED ONLY ON hECTiOa 9. SPECIAL H~OTECT[gN ~NFORHA. T~ON U~DER NOfiMAL USE NORMAL USE CONDITIONS. USE CON~IITONS. OR SKIN CCNTACT MAY' Precautions: STC~E I~ A COOL DRY SA~A i~F~ A ~espiratory Protection: NO SP~C~AL REQUIREMENTS CONgITIgNS. re, ti [ati on: RUQf~ 'VE~TILATION Ic ADEQUATE. Pratection 6(oves: NG SPECIAL ~UIREMENTc U~DER ~ye Proteczion: NO SPEC)AL ~EQUIREHEKTS U~,DER NORMAL btner Protective CLothing/Equipment: WHERE G~OSS EY~ ~ECTION iO. A. JOITiON~ IHFO~MATION AND PRECAUTIONS ma~dting and S~ora~e ............ - us . OuT 0¢ CH ZLOe . AFTER TITLE Iii H~P RATINGS: .acute. YES: [hronic. NO: Fire. NO: Press. Aelease. NO: Reactive. NO: R~TtHuS: ~E~LTN-I FIPE-U qE&(TIVITY-O w A.~ Ni 'N~: ~HIS P~O~UcT CONTAinS5 LESS T~AN 0.1~ OF LE~D. ~H~Cn [H~ JTATc OF CALiFOrNIA HAS D ,.RMIN~g TO a 0:~ -R EU UL a'f EU APSENIC A',iD CADMIUM CAUSE CANCER ~ ~H~ iNhORM~TiOm ON rnTS Ha, T~RrAL SAFETY ~,aTa SHmE~ ~E~RECZNTS THE LATEST UAi A A:~D PcS~' ~PiNION AS TO 'TQE PqOPEP USE ~ ~A~.~DLiNG ~ THiO P~OOUCT ~N~EK aORM~L CONOT[~.t~. ANY USE OF THIS PPCOuCT OR METH:~D OF- AP~LiCATiOr~E~HiCH iS ~OT TN CONFORH.~NC~ WITH THIS DATA SHEET &ND THc ,a,.CTION IS TH~ CFONSI~I~ ITY OF TH~ US~R. THIS mAi'EaIAL SAFeTy DAIA SaEET gA~ PREP~aED le Cg~PLY Wll~ THE OSH~ HAZARD cO~uNiCATiOa a~GU~,t,'[!O~," '" -- IVIODII 602649-00 MATERIAL SAFETY DATA BULLETIN PAGE i OF 1. PRODUCT AND COMPANy IDENTIFICATION PRODUCT N,~ME: MOBIL DTE 26 SUPPLIER: MOBIL OIL CORP. PRODUCTS AND TECHNOLOGY DEPT. 3225 GALLOWS RD. FAIRFAX, VA 22037 24 - Hour Emergency (call collect): Product and MSDS Information: CHEMTREC: 609-737-4411 800-662-4525 800-424-9300 APPROVAL DATE: 703-849-3265 202-483-7616 12/13/94 2. COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS CONSIDERED HAZARDOUS TO HEALTH: This product is not formulated to contain ingredients which have exposure limits established by regulatory agencies. It is not hazardous to health as defined by the European Union Dangerous Substances/Preparations Directives. See Section 15 for a regulatory analysis of the ingredients. See Section 8 for exposure limits (if applicable). 3. HAZARDS IDENTIFICATION US OSHA HAZARD COMMUNICATION STANDARD: Product assessed in accordance with OSHA 29 CFR 1910.1200 ahd determined not to be hazardous. EFFECTS OF OVEREXPOSURE: No significant effects expected. EMERGENCY RESPONSE DATA: Amber Liquid. Note: Pressurized mists may form a flammable mixture. DOT ERG No. - NA 4. FIRST AID MEASURES EYE CONTACT: Flush thoroughly with water. If irritation occurs call a physician. ' SKIN CONTACT: Wash contact areas with soap and water. High pressure accidental injection through the skin requires immediate medical attention for possible incision, irrigation and/or debrldement. INHALATION: Not expected to be a problem. INGESTION: Not expected to be a problem. However, if greater than 1/2 liter(pint) ingested, immediately give 1 to 2 glasses of water and call a physician, hospital emergency room or poison control center for assistance. Do not induce Vomiting or give anything by mouth to an unconsci6us person. Mobil MOBIL DTE 26 602649-00 PAGE 2 OF 7 5. FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA: Carbon dioxide, foam, dry chemical and water fog. SPECIAL FIRE FIGHTING PROCEDURES: Water or foam may cause frothing. Use water to keep fire exposed containers cool. Water spray may be used to flush spills away from exposure. Prevent runoff from fire control or dilution from entering streams, sewers, or drinking water supply. SPECIAL PROTECTIVE EQUIPMENT: For fires in enclosed areas, fire fighters must use self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: Note: Pressurized mists may form a flammable mixture. Flash Point C(F): > 204(399) (ASTM D-92). Flammable limits - LEL: NA, UEL: NA. NFPA HAZARD ID: Health: O, Flammability: i, Reactivity: 0 HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. Metal oxides. Elemental oxides. 6. ACCIDENTAL RELEASE MEASURES NOTIFICATION PROCEDURES: Report spills as required to appropriate authorities. U. S. Coast Guard regulations require immediate reporting of spills that could reach any'waterway including intermittent dry creeks. Report spill to Coast Guard toll free number (800) 424-8802. In case of accident or road spill notify CHEMTREC (800) 424-9300. PROCEDURES IF MATERIAL IS RELEASED OR SPILLED: Adsorb on fire retardant treated sawdust, diatomaceous earth, etc. Shovel up and dispose of at an appropriate waste disposal facility in accordance with current applicable laws and regulations, and product characteristics at time of disposal. ENVIRONMENTAL PRECAUTIONS: Prevent spills from entering storm sewers or drains and contact with soil. PERSONAL PRECAUTIONS: See Section 8 7. HA~NDLING AND STORAGE HANDLING: High pressure injection under the skin may occur due to the rupture of pressurized lines. Always seek medical attention. STORAGE: Do not store in open or unlabelled containers. Store away from strong oxidizing agents or combustible material. Mobil MOBIL DTE 26 602649-00 PAGE 3 OF 8. EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION: No special requirements under ordinary conditions of use and with adequate ventilation. RESPIRATORY PROTECTION: No special requirements under ordinary condltion~ of use and with adequate ventilation. EYE PROTECTION: Normal industrial eye protection practices should be employed. SKIN PROTECTION: No special equipment required. However, good personal hygiene practices should always be followed. EXPOSURE LIMITS: This product does not contain any components which have recognized exposure limits. However, a threshold limit value of 5.00 mg/m3 is suggested for oil mist. 9. PHYSICAL AND CHEMICAL PROPERTIES Typical physical properties are given below. COnsult'Product Data Sheet for speeifle details. APPEARANCE: Liquid COLOR: Amber ODOR: Mild ODOR THRESHOLD: NA pH: NA BOILING POINT C(F): > 316 (600) MELTING POINT C(F): NA FLASH POINT C(F): > 204(399) (ASTM D-92) FLJdTMABILITY: NA AUIO FLAMJTABILITY: NE EXPLOSIVE PROPERTIES: NA OXIDIZING PROPERTIES: NA VAPOR PRESSURE-mmHg 20 C: < 0.1 VAPOR DENSITY: > 2.0 EVAPORATION RATE: NA RELATIVE DENSITY, 15/4 C: 0.89 SOLUBILITY IN WATER: Negligible PARTITION COEFFICIENT: > 3.5 VISCOSITY AT 40 C, cSt: > 63.2 VISCOSITY AT 100 C, cSt: 8.5 POUR POINT C(F): < -24(-11) FREEZING POINT C(F): NE VOLATILE ORGANIC COMPOUND: EXEMPT IN U.S. NA=NOT APPLICABLE NE=NOT ESTABLISHED D=DECOMPOSES FOR FURTHER TECHNICAL INFORMATION, CONTACT YOUR MARKETING REPRESENTATIVE Mobil MOBIL DTE 26 10. STABILITY AND REACTIVITY 602649-00 PAGE 4 OF STABILITY (THERMAL, LIGHT, ETC.): Stable CONDITIONS TO AVOID: Extreme heat. INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers. HAZ~RDOUS DECOMPOSITION PRODUCTS: Carbon monoxide. Metal oxides. Elemental oxides. HAZARDOUS POLYMERIZATION: Will not occur. 11. TOXICOLOGICAL DATA ---ACUTE TOXICOLOGY--- ORAL TOXICITY (RATS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. DERMAL ToxICITY (RABBITS): Practically non-toxic (LD50: greater than 2000 mg/kg). ---Based on testing of similar products and/or the components. INHALATION TOXICITY (RATS): Not applicable ---Harmful concentrations of mists and/or vapors are unlikely to be encountered through any customary or reasonably foreseeable handling, use, or misuse of this product. EYE IRRITATION (RABBITS): Practically non-irritating. (Dralze score: greater than 6 but 15 or less). SKIN IRRITATION (RABBITS): Practically non-irritating. (Primary Irritation Index: 'greater than 0.5 but less than 3). OTHER ACUTE TOXICITY DATA: The acute toxicological results summarized above are based on testing of representative Mobil products. ---SUBCHRONIC TOXICOLOGY (SUM~Y)--- Representative Mobil formulations have been tested at the Mobil Environmental and Health Sciences Laboratory by dermal applications to rats 5 days/week for 90 days at doses significantly higher than those expected during normal industrial exposure. Extensive evaluations, including microscopic examination of internal organs and clinical chemistry of body fluids, showed no adverse effects. ---REPRODUCTIVE TOXICOLOGY (SUMuv~Y)--- Dermal exposure of pregnant rats to representative formulations did not cause adverse effects in either the mothers or their offspring. ---CHRONIC TOXICOLOGY (SUMuVLARY)--- The base oils in this product are severely solvent refined and/or severely hydrotreated. Chronic mouse skin painting studies of severely treated oils showed no evidence of carcinogenic effects. These results are confirmed on a continuing bas.is using the Mobil Modified Ames Test. .. ---SENSITIZATION (SUM2~Y)--- Representative Mobil formulations have not caused skin sensitization in guinea pigs. Mobil MOBIL DTE 26 602649-00 PAGE 5 OF 12. ECOLOGICAL INFORMATION ENVIRONMENTAL FATE AND EFFECTS: Not established. 13. DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Product is suitable for burning in an enclosed, controlled burner for fuel value or disposal by supervised incineration. Such burning may be limited pursuant to the Resource Conservation and Recovery Act. In addition, the product is suitable for processing by an approved recycling facility or can be disposed of' at any government approved waste disposal facility. Use of these methods is subject to user compliance with applicable laws and regulations and consideration of product characteristics at time of disposal. RCRA INFORMATION: The unused product, in our opinion, is not specifically listed by the EPA as a hazardous waste (40 CFR, Part 261D), nor is it formulated to contain materials which are listed hazardous wastes. It does not exhibit the hazardous characteristics of ignitability, corroslvity, or reactivity and is not formulated with contaminants as determined by the Toxicity Characteristic Leaching Procedure (TCLP). However,. used product may be regulated. 14. TRANSPORT INFORMATION USA DOT: NOT REGULATED BY USA DOT. RID/ADR: NOT REGULATED BY RID/ADR. IMO: NOT REGULATED BY IMO. IATA: NOT REGULATED BY IATA. 15. REGULATORY INFORMATION Governmental Inventory Status: All components comply with TSCA, EINECS/ELINCS, and DSL. EU Classification and Labeling: EU labeling not required. U.S. Superfund Amendments and Reauthorization Act (SARA) Title III: This product contains no "EXTREMELY HAZARDOUS SUBSTANCES". SARA (311/312) REPORTABLE HAZARD CATEGORIES: None. (Section continu&d next page) Mobil MOBIL DTE 26 602649:00 This product contains no chemicals reportable under SARA (313) toxic release program. PAGE 6 OF 7 The following product ingredients are cited on the lists below: CHEMICAL NAME CAS NUMBER LIST CITATIONS ZINC (ELEMENTAL ANALYSIS) (0.10%) PHOSPHORODITHOIC ACID, O,O-DI CI-14-ALKYL ESTERS, ZINC SALTS (2: 1) (ZDDP) (0.67%) 7440-66-6 22 68649-42-3 22 1 = ACGIH ALL 2 ~ ACGIH A1 3 = ACGIH A2 4 = NTP CARC 5 = NTP SUS --- REGULATORY LISTS SEARCHED 6 = IARC 1 11 = TSCA 4 17 = CA P65 7 = IARC 2A 12 ~ TSCA 5a2 18 ~ CA RTK 8 ~ IARC 2B 13 = TSCA 5e 19 = FL RTK 9 = OSHA ,CARC 14 = TSCA 6 20 = IL RTK 10 = OSHA Z 15 = TSCA 12b 21 = LA RTK 22 = MI 293 23 = MN RTK 24 = NJ RTK 25 = PA RTK 26 = RI RTK Code key: CARC = Carcinogen; SUS = Suspected Carcinogen Mobil MOBIL DTE 26 602649-00 PAGE 7 OF 16. OTHER INFORMATION CHEMICAL NAMES AND SYNONYMS: PET. HYDROCARBONS AND ADDITIVES USE: HYDRAULIC 0IL NOTE: MOBIL PRODUCTS ARE NOT FORMULATED TO CONTAIN PCBS. See container label for ingredient information. For Mobil Use Only: MHC: 1' l* NA 1' 1', MPPEC: A, REQ: US - MARKETING INFORMATION GIVEN HEREIN IS OFFERED IN GOOD FAITH AS ACCURATE, BUT WITHOUT GU;dlA~NTEE. CONDITIONS OF USE AfqD SUITABILITY OF THE PRODUCT FOR PARTICULAR USES ARE BEYOND OUR CONTROL; ALL RISKS OF USE OF THE PRODUCT ARE THEREFORE ASSUMED BY THE USER BaND WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND ;~ND NATURE, INCLUDING WARRANTIES OF-- MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RE~-~ECT TO THE USE OR SUITABILITY OF THE PRODUCT. NOTHING IS INTENDE-~ AS A -- RECOMMENDATION FOR USES WHICH INFRINGE VALID PATENTS OR AS EXTENDING LICENSE UNDER VALID PATENTS. APPROPRIATE WARNINGS AND SAFE HANDLING PROCEDURES SHOULD.BE PROVIDED TO HANDLERS AND USERS. Prepared by: Mobil Oil Corporation Environmental Health and Safety Department, Princeton, N3 ~.? . _--:'.- .: , . . -"-:-' . ..".:'" - .i'? ':-:.: ....... ,. , - ,-: .. -: " ....:: Pr'o'd,~ c'.~.~ coa,::? '"::'? ~;x :,'::..F' :'age :. :,~ : .~.;:~ ......¥~..~:,,~ ~.~.~, ~ ~. ~ .,.,; ...... .~ ~ ~,. ,- r m n.~' e d: :.., o 8 / f-6 / 8 8 4 :-- ,.-...~..:: M~'r;n' * ' :~* '* :~:' ~" '" '- ' " · ~ : - ' ' ' * ; ~ [:t*~ ('~)~1~*~ *~ .... .'::::.':;':??"_Co~md~nica'~ior~-S-~'andard (29 CF'R 'i9t0,12(~(-))- In a4di.:biOn, 'o'~her'".-.' :;:~':'"'P~s'ubs'~r~ces not 'l-laza¥'dou.:~' per this OSHA Standard may .:.- .... WheTe. pTopr ie~aTy ingredien-~ shows, '~he i (Je~ i'('y [~lay.be mad~e . :' 'avai[abt. e as Provided in this s~:andarct,.. 2 ' F:'I-.! Y S l C A t._ n A'¥' A: BOILING POINT~ 554F, 29(:)C \t A F' ~::' ? !"_-: S :ii.:-'.: < 'i 0 ...... i'~, . .... , ~ .~ ~ ~- ~ .....j _ .'.~! ,.':-, [-- VAF' DENSITY: 3~i SOl...., IN Wr:".'TiEF'.: H i sc i b i. e SF', C. RAVITY: ~ ~2.-.5(!:,'? 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'" Ci i.& ,'-~ 4' m ,.: l.., .,/.=: ',..' 8 i::' o ~" L e '-./ 'T,' t"1 ~:E' f" ~:''': ,"h , ........ , 'i' S "" c-,., .- ,_.i::' .~".4..~',' ~.:"' ;4,:~ ~":, c: f' e a --.--; e d i'" a -!: I. e :./,'..,:, L -':~.. i 'r',. b 1. ,:3 o d., 0 !::, 's e T' V a -i: i ,:::, n .5 i r'~ ...'~ n i n'~ a t. -5 in,::: !. u. ,-! ,'-::. .......... ¢.:: i (:~ 'F~ E' ".:..': ~. '.? 9:' T'., ...~ -¢'I d <.'-j ,::~ !!!- '( T C~ i ~ : ~.:, ':=. ~. i 'F~ ~'~ ......... '-' '- ti (:.~ .5 e .5 ,. ,f.) ', d e 1:' ,.z.:. ,.':: -,~ :5 a 'r e u 'r',. I. i k e I. ';..-' .. E x P o .~:. u ¥' ,:-z. ~.5 h a v i n ,g n o .3 d v e 'r .5 e ,..-:, 'F 'f' e (:: '(' .5 (::, n - -- '~' h e ~','., o 't' h e e.["fec'~.~'~, see'f: in fe~'¢.-':~Le anifnaLs a're believed '((3 be due :~(.--, al.-i:er.ed ..2:;; .~;~2-;';, .Z-... ..... ::: .~ 7. I::'II;;;ST AID: S 1< l N: W a S h ' o f f i 'n i' L ':; w i 'n ,:..'~ w a '",.' e ¥' o r s i"; ,:::,'w e ~'., (-:? X I::' ,O S i.i f' E-? i i] E i (:J (~ i'i t -:~i ]. '!.' C?. i::' T C) l;: .v?.', T' i i'i Ci U. 'Ei. -.I.- T' J ..Ei J'i a ¥i d L i I'i g ,. c: i o t h i 'n ,..=j s h ,:.'.. L( !. d i:) e 'ne e:, ,::! ecl., E Y E i::' i:~ O'T E C'f' ]; 0 N: U ::z e s a '?' ,.'-:-:, i' '::,' g !. a s s e s ,. 9 ~ A D D ;[ T' ]; 0 N A L. ! N F' 0 P, M A'T' ]' ;.-.~ i',.',: SARA t4AZARD u¢-~ i E.i, JI.,,t : Th is F' ¥'oduc .t. has been f'ev i ewed No.t. '(-o h,ave me'i: 8ny h'azard ,::.s, t.' ,s, go¥.y a'c~o.(din"q"-fo -~-h.-... EF'A 'l.-laza'rd Ca'tee;-,¥- e~" "' '- ' '"'- .; ..... ' ' .... ' ~'-' ~ - * Reau'lh'of'iza'iio'r~ Ac't' o'F i986 (:SAF-",A "l"ii'Le III.). and is' '... · ... '..~.~ 'cof~sl-def}ed', under appt. icabl, e ,.':tei:i The In'f'orma't-ion He're r; Is E-iven ;[iq Good F:'aifh Bu'(' N;'~ Wa i. E: .'.,,' ,:. ,' ,-".. ,.; ,:~ iq.~ 'r. ..... i!~ ..... r"ran.y, .~-'An "OF,'era-t- ing Un i '(' Of The Dow Chem. ic,:sl. COml.-,a~.ny ' : . . ....... : .... 7 TECHNICAL IN~O~HATION.?.Fue~s;...(9~4)' 838~733G: ~ubr~a~s/Ant'~free~e~: (914) 838-7509 :~'-C(~NP0$]:TzON/ZNFORNAT/0N ON INGREDIENTS" .._..../ THE. CRITERIA FOR,LISTING COMPON£N~5,':iN THE COMPOSITION SECTION IS AS~FOLLOWS; 'CHRONIC HAZAROS"(C~RCINOGENiC~. TERATOGENIC, ~UTAGENIC. NEU~0TOXIC,. AND SENSITIZERS) .ARE LISTED WHEN PRESENT AT O,O1% 0R GREATER; ACUTE HAZARDS ARE AT 1.O% 0R GREATE~ AND NON-HAZARDOUS C0MP0N~NTS ARE.LISTED WHEN P~£SENT AT 3,0% OR 'GREATER, THIS IS NOT INTENDED TO BE A COMPLETE COMPOS~T;ONA~/*~'S'CLGSU~E. - "- - · 'D~o~uct and/or Component(s) C~r¢lnogenlc A¢¢OrOtn9 tO: CAS'" ':"""' :;' '":"':"-": Chemical/COmmon l~2TpP°panedtoi 57556 None . PPoduot ·is non-h&z&POou$ 8¢COPOing %O0$HA (1910.1200), but is accocdtng to Tex&Co's in~ernal C~iterta. 3. HAZARD.IDEN'1'zFICATZ0N EMERGENCY OVERVIEV ADpea~a~ce and Odor: mobile.¢oloPle$$ liq,,51tght odor ~A~NING STATEHENT NONE CONSIDERED NECESSARY H~alth: 0 Flammability; POTENTIAL HEALTH EFFECT$ NFPA Reactivity: O He~l'~h: 0 Reactivity,: 0 Special: ' FlammaDt I lty: I Special - EYE SKIN INHALATION INGESTION . Acute 2 . :, -.' . ..' '~ay CauSe i-.i~tton, axP~'r~ence~ as mild'dfsco~oFt'an~ Seen as ~'1'tgh{' "; ' .-L"~.S~:~ -.'.'~:: * :~.: excess' re~ness Of the eye ' .. ' :"~ .'~ ";" . . : '..: . · .: . , g,.~-. :~/..::.,:,..:::.~:.,, , ,-..~:.~ . .._ ,., . . · - ......... ~ .'..,..:,.,. -~ _.-.,..~/ . : . ... : :."~, :¥-~ .'~'-' ':'. "-:" .~n~O~' ;' :'-'~':'~'~"-'~" .'" 'No adver~e'ef~ecis ~exPe~t~d. I~ 'mere than ~eve~al mOUt'~fU!S a~e ~walloweu, · . a~Oomt~al -discomfort. nausea, and dtarPhee may occur, " 5ansi tiZation Ne~lcal Conditions Agg~avat~ by Exposure: Other None : .~. FZRST AID NEA~URE$ Eyesi F1u~h eye~.wt~ Dl~nty of uater ~or several mlnute~. Get medtca~ Ski~: : . Wash skin with ~tenty o? soaD abc water for ~evePel ~inutes, Get m6~ifal attention if skin irritation ~evelops or persists. Xngestion: I water (16 oz.). Get ~edl¢~)'attentlon. XnhmlattOn: If irritation, headache, ~ausea. or Urowsiness OCcurs. remove to fresh Other lnstr~cttons: None MEASURES Ignition Temp. Degrees F.: N,O. Flasa pot~t Degrees F. Flammable Limits (~) Lower:~.~-2,$ _.: .upper: . 12.,5' Re¢o~r~ecl Fire Extln~uJshlr~ Agents ~ Special P~e~U~: . ~j~I~e.' Water' ep foam ~ay cause frothing Use uateP tO ~, , .......... ' '" . . .- ~9n:elnors ' if a leak ~- ---,, ~ ' - -~- -,-~'~vocu - . ,... . ~ t e vapors an~ to provide pffotectton fo~ persons attempting to  : .'-,., .' stop'the'leak. . . - . , ~?~;-';7..~'...'~:,,;.,!~-.,:,h~-:¥-~'.., ~. .. . .... . . . ::.~~;~.;,:,~4';?'b.~:~ ',~.¢. ;-?;/.,,.,~.:-'V,,;.':~,/' -'- /'~; ~:.,:L':.':,,..,;:~.SL'.'.~, .'.'.: :'.- ,~..- :' .,, ~'~: ",;~, ~.~:'-:., ;;': .'- 8, EXPOSUR[ CONTROLS/PERSONAL PROTECTION Eye/Face Protection: .: .... .. · Chemtcal-&ype goggles or care.shield recommsnoeo to prevent'~eye ¢Gntect. Skin P~otection: . :~ ,. ' Worker's Should wash exposed skin several times ~a~ly~wlth 'sOap eno water. SOlled work clothing shoulO be laundered or Ory-cleaned at ]east once a Respiratory Protection: .- Airborne concentratiOnS shQ~10 be kept to lowest levels possible, If vapor, mist or ~ust Is generatea, use respirator approveO by ~$HA Or 'NIOSH as appropriate, Supplie~ a~r respiratory protection shou~ be used for cleaning large sp~11s Or upon entry fmto tanks, vessels, or other confined spaces. See below for aPP!icable permlsstDle concentrations. ventitatlon: Local exhaust ventilation recommended 1? generating vapor, O~3t. or mist. Zf exhaust ventilation iS not evatlaDle or inadequate, use MSHA or'NIOSH approvea resDirator as appropriate. Exp~$Ur~ Llmtt ~oP TOtal PPO~Iuct: Nome estaOtiYhe~ g. PHYSZCAL AND CHENZCA~ PROPERTZE$ APpearance enO Odor: mobile.colorleSS 11q..sltght DOOr Boiling Point '(Degrees F.): 36~ Percent VOC: N.D. vapor Pressure: 0.05 mmhg . . Viscosity: 58 CSt ~ G8 F Other: - > 10% AIr=l 10. STABZLZTY AND REACTZVZTY 12. NecHan Lethal Dose (LDBO kCSO) '(Species) .':L. : Oral; >.5 g/kg '(rat): Practically 'non-toxic Innalatton: No a.ovepae dF?act 'in saturated atmosphere (human) Derm~t: > 3 g/kD (r~bbtt); P~actlcally hOn'-tOxiC Skln: bslleve~ to De < 0.5/8.0 (rabb~t); nO'appreciable Eyes: believed to be < 15/110 (raD~tt): mO appreciable e~fec~ Sensitization: N.D. · None DISPOSAL CONSIDERATIONS -:~'- This Product has ~en ~valuated For ~CRA CharactertSt '" ' · purchased form. un~e~ RCRA ~ ~s the responsibility or the user 0? the Pro~uet'to ~eter- hazardous ~aste. This is because Product uses', trans~orma~lon$, mixtures, processes, etc. may render the rest!ting materials hazardous. REMARKS ; '. Aeuattc toxicity ra~tinG: LCSO (~6 h~) ~ greate~ t~an lO00'~p~m: ~etatlvely harmless, TRANSPORT INFORJqATION TRANSPORTATION DOT: PROPER SHIPPING NANE: Not regulate~ HAZARD CLASS: N,D. ZDENTZFICATION NUMBER: N,D, LABEL REQUIRED: -N.D. ZMDG: PI~3PER SHZppzNG~.i~.iAME.:: ,N.D. TD~: PROPER SHZPPZN~ ~E: .Not regulated. HAZARD IDENTIFiCATiON NUMBER: N.D. LABEL REQUIRED: N.D.. No~ R~gula~eO 15, .0THER INFORMATION "' ':" THE INFORNATION CONTAINED H£REIN IS BELIEVED TO BE ACCURATE. IT IS PROVIDED INDEPENDENTLY OF ANY SALE OFTHE PRODUCT FOR PU~POSE OF HAZARD ¢0~MUNICAT~0N AS PA~T OF TEXACD'$ PRODUCT SAFETY PROGRAH. IT IS NOT INTENDED TO CONSTITUTE PERFORMANCE ~NF0~ATIDN CONCERNING THE PRODUCT. NO EXPRESS WARRANTY. 0~ ~MPL~D WARRANTY OF NERCHANTABILTIY OR FITNESS FOR A PARTICULAR PURPOSE [5 MADE WITH RESPECT TO THE PRODUCT OR THE INFORMATION CONTAINED HEREIN. DATA SHEETS ARE AVAILABLE ~OR ALL TEXACO PRODUCTS. YOU ARE URGED TO O~TAIN DATA SHEETS'FOR ALL TEXACO PRODUCTS YOU EUY. PROCESS. USE OR DISTRIBUTE AND YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE ~HO MAY COME ZN CONTACT WITH SUCH PRODUCTS OF THE INFOR~ATZON CONTAINED HEREIN. TO DETERMINE APPLICAbILiTY O~ EFFECT OF ANY LAW OR REGULATION ~ITH RESPECT TO THE P~0DUCT, USER SHOULD CONSULT HIS LEGAL ADV~SOR O~ THE APPROpR[AT[ G0VERNUENT AGENCY. TEXACO' DOES NOT UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS. Date: O8-O5-91 New X Re¥tsed, Superseoes; t2-05-~0 Date PrOnto0: O4-16-93 - - Texaco C~emtcal Co. Pro~uct Sagety Coordinator P.0. Box 27707 HouSton, TX 77227-?707 PLEASE SEE NEXT PAGE FOR PRODUCT "' :' '~'; . ' : - WORKERS SMOULO WASH EX~0SED $'KIN wa~er (I~ cz,), 'Gmt mm~tcml a~en.tton, Get medical attention tf b~eat~tng becomes d~ffi¢ult or symptoms.persist. EYE CONTACT: · FlusM eyes with plenty of water for several'minutes, .Get me, ica1 SKiN CONTACT: ~&$M Skin ~th p~lenty Of sOa~ a~ ~ater foe several mtnutes, Get ~edica! attention If skin Irritation ~evelop$ or persists. .' ', -'. ,-" -., containers COol - ' Chemical/Common Name CAS No. Ran~e tn I, 2opeopane0tO! . 57556 Proauct ~e no~-~azaro~us acco~n~ to OSHA ('1~IO.~2OO), but ~S ~'azaraous accoeo~ng to Texa¢o's trite,mai criteria. · , ~ . ,.~. Heelt~ : 0 Reactlvltyl ; .O DOT Proper $~tpptng Name: NOt regulete~ DOT Hazaraous Class : N,D. Natlona) EI~.a. PrOteCtion Asgoctation Health{.... : O Reactivity : 0 Flammability: 1 Specter : - CAUTION: to store t~xtc, Flammable, or reactive materials. Cutting or ~elalng of emp:y or expose ~o opem flame Or heat. Keep container close~ end drum bunds ~n place. Manufacturer's Name: Texaco C~emtce! Company ; P.O. ~ox 27707 HOUStOn. TX 77227 -. TRANSPORTATZON EMERGEN~ Company: (409) 727-0831 CHEMTREC: (800) 424-9300 HEALTH E~ERGENcY Company: ($14) 831-3400 '24 HOUR EMERGENCYASSISTANCE~;-,,~':~-,~ '' ~ r ~ ~DIVERSEYWYANDOTTE (313) (800} 424--9300 ..... ' SECTION I -- PRODUCT4DENTIFICATION ...... ''~'~ ..... ~I MEDICAL [col .[~t] (303!; 592-1024 t 2~1~0~3~~. :: ~:'~' CHEMTREC Product Z)iverae7 1~Taad°~e':SOL~!'[~'j~'' Description: . ~ ~j;a ~"" Chemical Mixture* ' ],tquid ';Ltkaline ,Cleane~:.,a:a~: ~'a:':: :~" ..... '~ ......... SECTION III -- PHYSICAL/CHEMICAL DATA andOdor Clear, green liquid with a solvent odor Ide~ing Point Boiling Point VNx~ N.A. 216'F (M~) 22. !/20'C O.~ ~w.~ IO0~ ~wegh~ 81~ ~"~'~} I.O85 ~.~} i.O~ 22'F I I. N-A- sEcTION IV -- FIRE AND EXPLOSIVE HAZARD DATA· , N.A. ~ I.i.~ {aa} N.A. N.A. Media I~ Water I~ Wate~ Fog {~ CO~ {~ Dry ~ ~~ None kn~. ~~ L~ f i r~:~zard. ' SECTION V -- REACTIVE HAZARDS I D Un~ab~ ! .aza~kxa ~flm~r~a~m 13 May Do not mix with acids as heat may be generated. Keep from freezing. Majcx C, ot~amanate~ That May Comrllx~ To mbli~y None kncx~n. ~~l~ Avoid mixing with acids. ~ Hay form caren dioxide and ~noxlde during hlgh~t~p~[~.~.Ure c~bustlon. R-462 (866) < - Less Than > · More Than ,I . .~DER NO,,, JUNE 7 MH CUSTOMER NO. 6812800000 TOMORROW FOODS 7301 OISTRICT BLVD ?EAR VALUED CUSTOMER- BAKER SFIELD CA 93313 ~'[VERSEY CORP. IS PLEASED TO PROVIOE THE ENCLOSEO MATERIAL SAFETY DATA SHEETS -MSOS- FOR PRODUCTS WHICH YOU HAVE RECENTLY ~U~C,HASEO. AS PART OF OUR CONTINUING COMMITTMENT TO THE HEALTH AND SAFETY OF OUR CUSTOMERS ANO PROTECTION OF THE ENVIRONMENT~ ']IVERSEY CORP,. HAS IMPLEMENTED A COMPUTER BASED MSDS FILE AND · ZISTR, IBUT!ON S~.~T:,,.,. TH~ NEW MSDS~ CONTAIN MUCH MORE DETAILED ~ NFOR MA Ti ON THAN IN THE PAST ANO TH~ OISTRIBUTION TRACKING SYSTEM 'WILL ~.NSU~ THAT YOU ~BOEIV~ AN HSDS WITH EACH FIRST TIME O~OER OF A PRODUCT OR WHENEVER A R~VISION TO TH6 PRODUCT -HE OSHA HAZARO.COMMUNICATiON STANDARD REQUIRES THAT ~HIS ,, ORMA~ON ~.~ PRO'FI~EO TO ANY PERSON ~1t0 MAY CO,ME IN CONTACT -:!TH TH~ MATERIAL. AS AN EMPLOYER YOU ARE REQUIRED TO MAKE THIS INF~RMATIOq AVAiLAELE TO YOUR E~PLOYEES. IF YOU · ,cD*c - UTE '~ · ~ ~ ~ z~%qT~ THcaE PROdUcTS YOU MUST SUPPLY AN MSDS TO THE .... ~NSTKEAH USER, YOU HAV,E ANY '~UESTI~h~S OR REQUIRE ADDITIONAL INFORMATION <EGARDING THESE PRCDUCTS~ PLEASE CONTACT YOUR LOCAL SALES :.EPRESENTATIVE O~ THE DIV~RSEY CORP. MSDS DISTRIBUTION -ENTER -I-a'O0-BZ1-;~160 OR 1-300-482-8010 IN MICHIGAN-. .... ALDE. 50SSGW "~,'":AGER - HEALTH~ SAFETY ~ ENVIRONMENT ¢ ~ V.--.~. SEY CSRP. '-' NCLO SURE SECTION VI --HEALTH HAZARDS Ac~e:lrr~atlon Ot e¥ , skin.'·nd membranes :~hemical Listed os Carcinogen ~ra~t~E~sure: FrO onged *cOntact ~y aggravate demititis and_~elat~ skin cepditions; FIRST AID PROCEDURE ~ NEVER GIVE FLUIDS OR'INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAVING CONVULSIONS. CALL A PHYSICIAN. . :~-s Flush eyes with plenty of water for at least 15 minutes. Get prompt medical attention. ~kin Flush skin with warm water. Remove contaminated clothing. If irritation develops, .... cOntact'· physician. .... *~es'.~O~,I,f~.swallowed, drink large amounts of water or milk. O0 NOT induce vomiting. Get medical attention. ' ................... : ........... . l .~.~o. RemOve to fresh air. If breathing difficulty 'continues, get medical ·ttention. SECTION VII -- HANDLING PROCEDURES/PROTECTIVE INFORMATION )recaufionstobelaken Keep from freezing. Close container when moving or not in use. nHam~ingandSa~age: KEEP OUT OF REACH OF CHILDREN. Do not store or use container around sparks or open flames. Do not s~ke over open drum. JMIS WARNING SYSTEM: HEALTH 2 FLAMMA~LITY ] REACTMTY 0 PROTECTIVE EOUIPMENT Pv ~espiraton/Protection: D Yes ~ No If yes. type: ll~ua] ]y not required tenlilafio~ I Local Exhaust: O Yes I~ No II~,a]ly not reauired ! Mechanical(General): q~ Yes 1:3 NO S{) cfm in hiph mist areas -:~eFbo4ectio~: ~) Yes O No Uyes:~/pe: l'~ogle~ er ~tde-~hield ~afety 01a~es )rotectiveGIoves: ~] Yes O No ayes. type: R, hh~r nr chemical resistant :)~he~Pm~ectlveEquil~ent Clnthino tn prevent .nrnlnn_ned Kkin cnntact. 4ygienel~amicese~q~oyeesshoulduse: Wash after using or handling product. Launder contaminated · clothinq before reuse. .~ SECTION VIII -- SPILL OR LEAK CONTROL PROCEDURES *' ~o. os~ve Action on None known. ~ ~o be ~ke~ Contain spill. Hop up or dilute with water and discharge to · sanitary sewer system. Wash spill areas thoroughly. - Dilute with water and discharge to sanitary se~er as for soap solution. Hay be toxic to fish. Do not discharge to lakes or streams. Contains biodegradable detergents. -. .... D~VERSEY W~(ANDO TTE CORPORATION HONfO ~ NC TFI D:~te: Sept 94 ManufaCturer: Hondo Product Name: Sulfuric Acid 93% 3984860 F'. 82 Il"lC, Address: 20803' Smckdale Hv, T. Bakersfield, CA 93312 Phone: 805-589-1042 Pein: of Contact: Greg Bakar Chemical Name: Sulfuric Acid Trade Name:. Sulfuric Acid Formula: H2SO4 CAS #: 7664-93-9 Ha,za ,,ntous Ingredients.. Sulfuric Acid 70 -80 % EvapcraUon Rate: Odur. Solubility In Water: 100% AFpearance: Clear to water pH: i '- Sh ppmg lnformatmn il NFI'A DOT - t Health: 3 II Flammability: Name LrN 1830 I~ Reactive: 2 Class: Corrosive Material !i Placard Corrosi,e 1' ; " ' lV~ Labetin8 l~¢quiremems: Corrof [f_ , , =, ,,.. .................. Physical Data BoEing ~ch~t'. 530 SpecLfic Oravity: 1,83 Vapor Density: N/A Melting Point: NA Volume % VolatSe: AppreciaNe Acute: TKL~ Chronic: FALSE PELt 'ting/em TLV: NA Carcinog~: FALSE Mutagen: FALSE Health Hazard Data Inhalation: Can cause damage to upper respiratory :tact axed lungs. Remove to fresh air. if necessary, apply 'escue breat.hi~g. C~et medical help irmmediately. Absorption:Rapidly damaging to ail dssue. :rw-nediatte!y ~sh eyes or skin w;,th copious zmounts of wat~ for at le~-t t 5 minutes and remove clothing whiie rnder shower Get medical attention ASAP. Teramgen: FALSE Ingestion: May cause severe iniur; or death. Dilute acid irv_mediatley with [arge amounts efnfi_4k er water. Reproductive:FALSE ~'-" '"' ~,_n-ve ..~mL< of magnesia to neuirzlize. Dc not :nduce ~,emiting. Obtain medical attention i~,media~eiy M&D$ c'- .Flash Point: NA loEL: LEL: Extinguishing Media: NA HCII, IDOI NC TI] 39:~--4E:60 Fire ExPlosiou Data Unusual Fire And Explosion Hazards: A strcng mineral acid reacting with bases and metals. rhe concentrated acid is a strong o.,ddizing agent and can cause ignition of combustible materials >n contact. The concentrated acid is also a dehydrating agent, picking up moisture readily from :he air. Special Fire Fighting Procedures: Wear self contained brcatking aparar4s and appropriate lresonal protective equipment. Acid can react with metals to liberate hydrogen Reactivity Data ;table? TRUE 2ondltlons to Avoid: Vlaterials to Avoid: Reacts exothermically wit,ti water, als may be released. [tazardous Polymerization: Not .,.xpected to occur. Jazardous Decomposition Products: NA .................Material Managemeni ' Spill Response: Supply vemilation to ~,-Tected area to meet TLV. We~ prorec:ive clo,2~ing, loves, boots, goggles, apron=, to avoid contact. Co,:tam and absorb material and place in ~itabie comainer for disposal. Comam SpiE. Material ltandling: Avoid contact with skin, eyes, and ¢l~.king. Material Storage: Store in col, du, we~-ventilated area. Segregxte fi'cra incompatible naterials. Waate Disposal: Dispose in accordance wid~, local st?.;e and federal regulations_ Dispose of :ontanfinated material in accordance with local, sta~e, and rede:it reg'u/arions ~ud Izws. Special 'C/orR l'racric~s: Read entire MSDS before using this product. '¢&ere mists aze o 50 rog/m3, a kigh efficiency, paNculate respira:or with gu/.~l hceplese is warranted; a type mlpplied ,a/r respirat~cr with ~il hoe piece operated, in pressure demand mode is used to 100 P. 03 ~AmbNIAL ,5~%FE'FY DAIA ~HI=I~T ~UL. FU~IC ACID, 77 TO 1007, , 'i: L_ Sulfuric Acid, 77 to 100% Me'"~acturer/Distributor Phone Numbers Product Information 1-800-441-9442 Transport Emergencu CHEMTREC... 1-800-424-9300 Medical Emergencu 1-800-441-3637 ~rade 77 to 100 % TECHNICAL Chemical Familg MINERAL ACID · CAS Name CAS Numbee SULFURIC ACiD .... 7~64-93-9 Formula H2804 Molecular Weight 98.08 TSCA Inventoru Status Reported/Included NFPA Ratings Health 3 Flammabilitu 0 React.ivit~ Water Reactive NPCA-HMIS Ratings Health 3 Flammabilitg 0 Reactivitg Personal Protection rating to be supplied bg user depending on use conditions. 1082-00 1082-05 Revised 15-Aug-91 !083-00 1083-05 Du Pont 1007 Market Street Wilmington, DE 19898 3004-00 3004-05 3004-30 3004%35 _..: ************************* ~. :_WEBER SCIENTIFIC 2732 Kuser Road, Hamilton, NJ 08691 ~. 800-32g-837~ # 609-584-7677 24 Hr. Emer. Number:. g00-255-3924 CC, ONENTS Mateeial *SULFURIC ACID ~0 DE~ TECHNICAL' 66 DEQ TECHNICAL 1.835 ELECTROLYTE 98% TECHNICAL 99% TECHNICAL 100% TECHNICAL WATER CAS Number 7664-93-9 Percent 77. 7 93. 2 93. a 100 7732-18-5 0-~2 *Regulated as'a Toxic Chemical under Section 313 oP Title III o~ the SuperPund Amendments and Reauthorization Act oP 1986 and 40 CFR pa~'t 372. - PHYSICAL DATA Boiling Point Vapor Pressure Vapo~ Densitq Melting Point 193 to 327 DegC '380 to 621DegF' at 7&O mm Hg. less than 0.3 mm HG at 25 DegC '77 DegF' less than 0.6 mm Hg at 38 DegC ~IOODe~F' 3.4 -35 to 11DegC.'-31 to ~1DegF~ The information herein is Given in Good ~aith, but no ~arrantu0 expeess oe implied, is made. ~I~IRL ~A~EIY DAI'A ~HEET SULFURIC ACID', 77~T0 lOOX Evaporation Rate ~"! · Less than 1 Water Solubilitg 100 WT % pH Less than 1 .Odor Odorless Form Oilu, clear to turbid liquid .Color ~ Colorless to light grag GRADE BOILINg PT. DEO C DEO F MELTINg.. ,PT.-{.,', SPECIFIC DEG C DE~ F · ~R, AVITY ~,. 60. DEG TECHNICAL' 193 380 -15 66 DEG TECHNICAL 279 535 -35 1.835 ELECTROLYTE 279 535 -35 98% TECHNICAL 327 621 -2 99% TECHNICAL 310 590 4 100% TECHNICAL' 274 52& 11 -31 -31 40 51 1 706 1 835 1 835 I 844 1 842 I 839 HAZARDOUS REACTIVITY :nstabilitg... Stable, but reacts violentlg with water and organic materials with evolution of heat. Decomposition... Releases sulfur dioxide at extremelu high temperatures. Polumerization... polumerization will not occur. Incompatibilitg... Vigorous reactions with water, alkaline solutions, metals, metal powder, carbides, chlorates, ruminates, nitrates, picrates, strong oxidizing, reducing, or combustible organic materials. Hazardous gases are evolved on contact with :hemicals such as cganides, sulfides, and carbides. FIRE AND EXPLOSION DATA Flash Point... Will not burn Fire and Explosion Hazards... Reacts mith most metals, especiallq~when dilute, to give flammable, potentiallu explosive hudrogen gas. Follow appropriate National Fire Protection Association 'NFPA' codes. Extinguishing Media... Use media appropriate for surrounding material. Jse mater sprau to cool containers exposed to ~ire, do not get zater inside containers. Special Fire Fighting' Instructions... Evac~Jate personnel to a safe area. Keep personnel removed and upmind of fire. ~ene~ates heat upon addition o~ mater, miti: possible spattering. Wear full,, protective clothing. Runoff from fire control ma~ cause pollutibn. Neutralize'run-o~ mi~h lime, soda ash, etc., to prevent corrosion o~ metals and ~ormatio~ o~ hBdrogen gas. Wear self- contained breathing apparatus if ~umes or mists are present. HEALTH HAZARD INFORMATION Causes severe burns to ages, skin, and all bodg tissue. Ege damage The information herein is given in good faith, bUt no warrantg0 express or implied, is made. MATERIAL SAFETY DATA SHEET SULFURIC ACID, 77 TO 100% ~may..be permanent. Destruction oF tissue may result from direct chemical reaction with tissue, from thermal burns, and 'from dehydration 'removal of water' of the tissue. A. IAL DATA... Inhalation 1-hour LC30... 347 ppm in rats Oral LDSO... 2140 mg/kg in rats The concentrated compound is corrosive t.o the skin and eges of animals. Bg ingestion it is moderatelg toxic in animals causing corrosion of mucosal surfaces. Toxic e~ects described in animals from single exposures bg inhalation incll, de respiratorg irritation. Animal testing indicates that this compo~Jnd does not have carcinogenic, mutagenic, emb~gotoxic, or reproductive effects. HUMAN HEALTH EFFECTS... Human health effects of overexposure to the liquid bu skin or ege contact may cause eye corrosion with corneal or conJunctival ulceration, or skin burns or ulceration. Ingestion of the liquid mag cause severe burns to the mucous membranes of the mouth and esophagus. Repeated or prolonged contact with mists mag cause eye irritation with discomfort0 tearing or blurring of vision, or s-kin irritation with discomfort or rash. Human health e~fects o~ overexposure by inhalation mag include il~ritation of the upper respiratorg passages, or erosion of dental surfaces. Higher exposures by inhalation mag lead to temporarg lung irritation e~fects with cough, discomfort, di~icult~ breathing, or shortness of breath, or possiblu modest initial sumptoms followed in hours by severe shortness of breath, requiring prompt medical attention. though t~o epidemiologg studies did suggest a possible a~_~ciation between, sulfuric.acid exposure and respiratoru tract tumors, conclusions ~rom these studies are verg limited because o~ significant deficiencies. In one studu, ~or example, onlg a small number o~ workers were sampled, and there was exposure to other materials including diethu1 sulfate, an IARC and NTP carcinogen. In the other study there was exposure to other acids, plus the smoking histories o~ the workers ~ere ignored in the development o~ the studu conclusion. Based on the overall weigh~ o~ evidence ~rom all human and chronic animal studies, we conclude that no causal relationship between sulfuric acid exposure and respiratorg tract tumors has been shown. Individuals with preexisting diseases o~ the lungs may have increased susceptibilitg to the toxicitg of excessive exposures. Carcinogenicity None o~ the components in this material is listed bg IARC, NTP, OSHA, or ACQIH as/a carcinogen. Exposu+e Limits Sulfuric Acid, 77 to 100% AEL~ 'Du Pont' I mg/m3 - 8 & 1~ Hr. TWA TLV 'ACQIH' I mg/m3 - 8 Hr TWA STEL... 3mg/m3 PEL 'OSHA' I mg/m3'- 8 Hr TWA * AEL is Du Pont's Acceptable Exposure Limit. Where. governmentally J The information herein is given in good faith, but no warrant~, express implied, is made. MATERIAL SAFETY DATA SHEET SULFURIC ACID, 77 T0.100% imposed occupational exposure limits which are lower than the AEL ate e~ect, such limits shall take precedence. .Sa~etg Precautions . Avoid breathing vapors or mist. Do not get in eges, on skin, or on ' clothing. Wash thoroughlg a~ter handling. .. ~eep containers closed. Do not add water to contents while in container because o~ violent reaction. FIRST AID INHALATION I~ inhaled, remove to ~resh air immediatelg and have patient lie down and remain ~uiet. Applg artificial ~espiration i~ breathing has stopped. ~ive oxggen i~ breathing is difficult. Call a phgsician. INGESTION I~ swallowed~ do not induce vomiting. Qive large ~uantities water. Call a phgsician. Do not neutralize the acid. Never give angthing bg mouth to an unconscious person. S~IN OR EYE CONTACT ~ In case o~ contact~ immediatelg 'within seconds' ~lush eges or skin with p,lentg o~ water 'pre~erablg cold water' ~or at least 15 minutes ~hile ~emoving contaminated clothing and shoes. Call a phgsician. Wash clothing before reuse. While the patient is being transported to'a medical ~acilitg applg compresses o~ iced water. I~ medical treatment must be delaged~ immerse the a~ected area in iced water. I~ immersion is not practica'l, compresses o~ iced water can be applied. Avoid ~reezin~ tissues. Notes to Phgsician Continued washing o~ the a~ected area with cold or iced water will be helpful in removing the last traces o~ sulfuric acid. Creams or ointments should not be applied before or during 'the washing phase o~ the treatment. PROTECTION INFORMATION ~enerallg Applicable Control Measures and P~ecautions Qood general ventilation should be provided to keep vapor and mist concentrations below the exposure limits. Personal' Protective E~uipment Have.available and wea~ as appropriate ~oT exposure conditions When handling containers or operating e~uipment containing sulfuric acid., chemical spiash goggles~ ~ull-length ~ace shield/chemical splash goggle combination~ acid-proo~ gauntlet gloves~ apron~ and boots~ long sleeve wool~ acrglic~ or polgester clothing~ acid' proo~ suit and hood~ and appropriate NIOSH/MSHA respiratoru Pr°tection, In case o~ emergencg or where there is a strong possibilitg o~ considerable exposu~e~ wear a complete acid suit with hood~ boots~ and gloves. I~ acid vapor or mist are present and exposure limits mag be exceeded~ wear appropriate NIOSH/MSHA respi~atorg protection. The information herein is given in good ~aith, but no warrantg, express o~ implied~ is ~made. ~ MATERIAL SAFETY DATA. SHEET SULFURIC ACID, 77 TO 100% P'SPOSAL INFORMATION A~uatic Toxicity The 48-hour TLm in flounder is 100-300 ppm. SPill, Leak, or Release NOTE*** Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EGUiPMENT during clean up. Superfund reportable discharge - 1OOO Ihs. Stop flow if possible. Reviem 'Fire and Explosion Hazards' and 'Safety Precautions' before proceeding ..* ~,.lth clean up. Use appropriate Protective e~uipment during clean up. S~k up small spills mith drg sand, clay or diatomaceous earth. Dike large spills, and cautiously dilute and neutralize with lime or soda ash, and transfer to maste water treatment system. Prevent liquid from entering Sewers, watermays, or low areas. Comply with Federal, State, and local regulations on reporting releases. The EPA reportable discharge is 1oOo lbs. Waste Disposal Cleaned-up material mag be a RCRA Hazardous Waste on disposal. Do not flush to surface water.or sanitarU sewer system. Comply with Federal, State, and local regulations. If approved, neutralize and transfer to waste treatment sgstem. ' 'TPPING INFORMATION 'DOT Proper Shipping Name Hazard Class UN/NA No. DOT Labels's' DOT Placard DOT/IMO Proper Shipping Name Hazard Class UN No. Special Information Packaging Group Reportable Guantitg SULFURIC ACID~ CORROSIVE MATERIAL UN 1830 CORROSIVE CORROSIVE SULPHURIC ACID CORROSIVE MATERIAL, 8 1830 IMO LA~EL... CORROSIVE II 1000 lbs. Shipping Containers Tank Ca~ Tank Truck Steel Drums - 55-gallon stainless steel *If material is shipped in*~uantities greater than 1000 lbs. per container, the Proper Shipping Name is RG SULFURIC ACID. STORAGE CONDITIONS ~p out o~ sun and amag from heat, sparks, and flame. ~eep container tight, lq closed and 'drum~ closure up to prevent leakage. The information herein is given in good ~aith, but no warranty, expeess oe implied, ts made, MATERIAL .SAFETY DATA SHEET SULFURIC.~'ACID, 77 TO 100% ~. ~ Loosen closure careFullg. Relieve internal pressure when received and at least week. lg thereafter. Do not Use peessure to emptg. Be suee closure is secu~el~ Fastened before moving containe~. Do not wash out container or use it ~or other purposes, replace closure a~tee each withdrawal and ~eturn it with emptg containe~. TITLE III HAZARD CLASSIFICATIONS Acute Chronic Fire Reactivitu Pressure LISTS... Yes No '¥~s No Extremelg Hazardous Substance CERCLA Hazardous Substance Toxic Chemical -Yes -Yes -Yes ADDITIONAL INFORMATION AND REFERENCES For Further information, see Du Pont SulF:Jric Acid 'Storage and Handling Bulletin' The data in this Mater~al Sa~etg Data Sheet relates onlg to the speFiFic material designated herein and does not relate to use in combination with ang other material or i~ an~ process. SulFuric Acid Drain Cleaner Policg... This is to advice gou that we do not sell SulF'u~ic Acid ¢o~ use as a drain cleaner, and that such is contrarg to our ~ecommendations. We believe this use to be hazardous. The in¢oemation herein is given in good Faith, but no waeeantg, e~peess of implied, is made.'" MATERIAL SAFETY DATA SHEET ~ULFURIC ACID FOR THE GERBER TEST SEcTIoN 0i IDENTiFIcATION ' '~' .FURNISHED BY..,.. WEBER SCIENTIFIC ADDRESS ....... ~ ......... DATE EFFECTIVE .......... CHEMICAL NAME/SYNONYMS.. CHEMICAL FAMILY ......... EMERGENCY PHONE ~ ....... CAS # .................... Division of NJDL .SUPPLIES, INC. ETRA ROAD EAST WINDSOR, NJ 08520 o6/88 MINERAL ACID AND PRODUCT INFORMATION 3'02-774-2421' 7664-93,9 % VOLATILE'BY VOLUME... MELTING POINT .......... VAPOR PRESSURE ......... VAPOR DENSITY/AiR IS1. SOLUBILITY IN WATER .... APPEARANCE & COLOR ..... SPECIFIC GRAVITY ....... 0% @ 70DEG F -35DEG TO PLUS 10.6DEG C°-31DEG TO PLUS 51DEG F' LESS THAN 0.3 @25DEG C,LESS THAN 0.6 @ 37.7DEG C APPROX 3.4 COMPLETE CLEAR TO TURBID,OILY LIQUID* 1.800 - 1.825 @ 60DEG F EVAPORATION RATE ....... 'BUTYL ACETATE IS 1' -LESS THAN'i *COLOR-COLORLESS TO LIGHT BROWN - ODOR NONE ~ORM - LIQUID ' INFORMATION - LESS THA_N 1 SECTION 03 FIRE & EXPLOSION HAZARD DATA FLASH POINT ............ NONrFLAMMABLE FLAMMABLE LIMITS IN AIR.% BY VOL - WILL NOT BURN. FIRE AND EXPLOSION HAZARDS - REACTS WITH MOST METALs ESPECIALLY WHEN DILUTED, TO YIELD FLAMMABLE HYDROGEN GAS. ' EXTINGUISHING MEDIA -WATER, DRY CHEMICALOR CARBON DIOXIDE 'FOR FIRES IN AREA' DO NOT GET WATER IN TANK. SPECIAL FIRE FIGHTING'INSTRUCTIONS- GENERATES HEAT UPON ADDITION OF WATER. WITH POSSIBLE SPLATTERING. WEAR FULL PROTECTIVE CLOTHING'SEE SECTION 8 USE CARE NOT TO IGNITE HYDROGEN GAS WHICH MAy ACCUMULATE FROM REACTION WITH METAL. CHEMICAL FORMULA ........ TRANSPORTATION EMERGENCY PHONE~'i'_ '800,424-9300 CAS NAME - SULFURIC.ACID ID NOS/CODES NIOSH REGIsTRy NO. WS 5600 - WISWESSER CODE WSQG SECTION 02~ PHYSICAL DATA ~BOILING POINT. ......... 760 MMHG 193-327DEG '379-621DEG F' . MATERiAL~SAFETY DATA SHEET SULFURIC ACID FOR GERBER TEST ~CTION'04 REACTIVITY DATA ~ - . .. . STABILILTY - ~ · S.ABLE - WILL R~ACT WITH · MANY MATERIALS. INCOMPATIBILITY - COMBUSTIBL MATERIALS~ OXIDIZING MATERIALS-· ORGANIC PEROXIDES. STRONG REDUCING AGENTS, POWDERED METALS, CYANIDES, CARBIDES,' CHLORATES, NITRATES, FULMINATES, PICRATES, SULFIDES. · DECOMPOSITION. RELEASE SULFUR DIOXIDE AT EXTREME HIGH TEMPERATURE.-REACT!ON WITH ABOVE MAY RELEASE TOXIC GASES, SUCH AS HYDROGEN CYANIDE OR RYDROGEN' SULFIDE. POLYMERIZATION...NONE SECTION 05 SPIL;' ---- ......... L, LEAK AND DISPOSAL 'PROCEDURES.. SPILL,' LEAK OR RELEASE...iF POSSIBLE, STOP FLOW. DIKE LARGE SPiLLS. NEuTRALizE SPILLS WITH LIME OR SODA ASH AND FLUSH 'FO WASTE WATER' TREATMENT SYSTEM. WEAR PROCTECTIVE CLOTHING IF NECESSARY TO ENTER SPILL AREA. R UTR R E×POSURE"LIMITS'<" AIR-CONCENTRATION...TIME WEIGHTED'AVERAGE,OSHA, MO/M3 ROUTES OF EXPOSURE AND EFEFCTS. CAUSES SERVmRE BURNS OF'SKIN, EYES AND ALL .... ~;~ CAUSES SEVERE BURNS OF ~OUTH,' ESOPHAGUS AND STOMACH. 'INHALATION.OF VAPORS OR MISTS MAY'CAUSE RESPIRATORY IRRI~ATION. LONG TERM OVEREXPOSURE-.TO..~VAPORS OR MISTS MAY RESULT IN'DAMaGE .TO TEETH. AID. .IN' CASE OF CONTACT, IMMEDIATELY FEUSH EYES OR SKiN WITH PLENTY WATER FOR AT' LEAST 1'5 MINUTES WHILE REMOVING CONTAMINATED'CLOTHING AND SHOES. CALL A PHYSICIAN. WASH CLOTHING BEFORE REUSE. IF SWALLOW~D~ GIVE LARGE QUANTITIES OF WATER UNTIL PHYSICIAN IS CONTACTED. NEVER GIVE ANYTHING BY ~OUTH TO AN UNCONSCIOUS PERSON. iF INHALED, REMOVE TO FRESH AIR. HAVE' PATIENT LIE 'DOWN AND KEEP QUIET. IF NOT BREATHING, GIVE ART.IFICAL RESPIRATION, PREFERABlY MOUTH_TO_~OuTH IF'BREATHING IS DIFFICULT~GI. VE OXYGEN. CALL A PHYSICIAN. " ' SECTION OB SPECIAL HANDLING INFORM VENTILATION. '~um~u ~UUM. USE ONLY WITH ADEQUATE PERSONAL PROTECTIVE EQUIPMENT _ COVERALL CHEMICAL SPLASH GOGGLES. RUBBER OR PLASTIC GLOVES, RUBBER. PROTET!VE FOOTWEAR, FULL RUBBER CHEMicAL SUIT." OTHER - RESPIRATORy PROTECTION NOT REQUIRED FOR NORMAL USE. · ~ ~-CTION 09 ~0- ~ ~ ~-CIAL PRECAUTIONS A~D ADDITIONAL TRANSPORATION'- DOT SHIPPING NAME-SULFURTC AC~Z*~*:j~*~j~j~*~j~j~***~ MATERIAL. STCC CODE IS 4930040. UN NO~ ..1831. IMCO CLASS SHIPPING CONTAINERS - TANK CARS, TANK TRUCKS, 55GAL STAINLESS STEEL DRUMS. STORAGE CONDITIONS...KEEP OUT O~ SUN AND AWAY FROM HEAT. KEEP FIRE, SPAR~<S AND FLAME AWAY FROM OPENING. KEEP CONTAINER TIGHTLY CLOSED AND cLoSURE 'DRUMS~ UP TO PREVENT LEAKAGE. LOOSEN CLOSURE CAREFULLY. DO NOT USE PRSSSSRE TO'E~PTY. RELIEVE INTERNAL P ~ ~ RESoU~ WHEN RECEIVED AND AT LEAST WE~KLY ~HEREAFTER. BEFORE MOVING CONTAINER-BE SURE CLOSURE IS ~EFERENcEs AND ADDITIONAL INFORMATION DO NOT WASH OUT CONTAINER OR USE FOR OTHER PbRPOSES~ REPLACE =~)u~n~ AND RETURN WITH EMPTY CONTAINER. DO NOT GE~-~iN~EYES, n~ OR n, A90~!'D'~'~:B~R~A~H i NG: VAPOR OR M I STS DO NOT ADD WATER TO CONTENTS WH~u= IN' CONT~R ~EC~U~= DF VIOLENT :.=Pc ~ON. WASH T,~ORObm~Y AFTER HANDLING. MAT~RiAL~ S~ APPROXIMATE % 1.8~ - 1.825 SP. GRAVITY 88% - SECT~ON 99 ~00~NO~Eo R~FERENCES...DU PONT wU~pU~xTC AC~D DATA DU PONm ~, ~ ~ ~ oT.JRAG~ & ,~AND-iNG DU PONT SULFURIC ACiD COMMODITY DISTRIBUTION DATA. THE iNFORMATION HEREIN IS GIVEN iN GOOD FAITH, BUT NO WAR2ANTY, EXPRESS iMPLIED, iS MADE.~ DIVERSEY CORP. .' -" - MATERIAL SAFETY DATA SHEET REPORT · ~i~ER-"~'S'~E~- LIQU£D ACID CLEANER ' .~C'TioN"i"2~PROOUCT IDENTIFICATION' ............. ~ HOUR EMERGENCY ~ DIVERSEY CORP. ~ MEDICAL-COLLECT- -303-592- 102~ ~ .15~2 BIDDLE AVENUE * CHE~T~EC _800_42~_9]00 · WYANOOTTE~ MI ~8192 ~ · ¢ ',: DJ VERSEY CORP. ~313.Z8 l-.0930 ~HAZARO RAIING5, ~' ~ ' ~-d c~,LY H~ *FLAMHABI LITY, *REACTIVITY. *SPECIAL/PpE. NFPA- 3 HMIS- 3 KEY-~-EXT'REME 3-H ICH COR-C ORROSI VE AC-ACID PPE CODES--REFER TO tJMiS · ' PAGE 001 Oz/zo/9 o o COR.. 0 0 'D '' O-INSIGNIF ICANT 2-NODERAT E 1-SL IGHT ALK-ALKAL IdE OX-OXIDIZER SYSTEM DOCUMENTATION- £MERGENCY OVERV.IE./ DANGER - CORROS!V6 - CAUSES SEVERE BURNS TO SKIN AND EYES. MAY 5E FATAL iF S;,!ALLOWED. MAY CAUSE RESPIRATCF:.y TRACT IRRITATION. DO NOT GET It,i EYES~ ON SKId, OR CLOTHIhiG. Avoro ~REATHING OUST, MIST~ OR ' 'ORS. KEEP CON'FAiN~-, ~,. ~'~ CLGS(~D WHc~ NOT ~E[NG USED. ,~, Tm :' !JSE OR HANDLE NITH A. _~A, .. VENTILATION TG MAZNTAiM ANY EXPOSURE LIMITS FOR TH~ PRODUCT ,~ASH THOROUGHLy AFTER HA'iDLING OR WORKING ,~I'TH PRODUCT "~" ES .... NEAR C, OG.~LSS~ FACE SH~EcO~ k~..E;:_.~R GLSV_ ~ PROTECTIVE CLOTHIdG AND FOOTWEAR ~IHEN HANDLING THIS CHENICAL, KEEP OUT ?F REACH OF CH!LDx. EN. THIS PRO'DUCT CC!i',iTAIbiS STROFiG AC~,C'S ~,J?'JT£J~ MAY RE'C-*cc - -- ~ ...... TOXIC.OR, IRRITATING '~APORS OR C. AS .,F ,ALI_C~WEO T~ ?;IX ~ITH CHL;DRI,.iA~:O ~ ,, ....... CL~AN~S 0~ ~LGACH. I t"ig RE gl .E." TS '"'" * ACGIH ~= OSHA , HAZARD · CAS NU;.'I~DER ::~ CHiS.."-IIC,AL CO~IPO~wE'~jT :'~ -:; * TLV * PEL * CODES "- 915-67-3 C.[. ACID b~E'_, 27 DYE 'TRACE NE NE O 3.520-~Z-I L.l. ACID '~Ei5 52 DYE -' ' ' -~ -, :' TRACE NE NE rbo'~.-~3-c * F'HOSPHL~".~iC ACIL 7697_3? -~ ,. , " iL 1 MG/,H3 1 ME/M3 1/2/3/~+ ,-~ ..~ITP~.C ACIO 20 5 ME/N3 5 ME/M3 1/2/3/4 7732-i ~-5 ¥~ A ~ S,:i 65-S9 NG ~-IE 0 9003-ii-6 POLYALKOxy SLY(SOL I-2 NE NE 0 CODE KEY- O- NL~:~'fi'~ E G UL AT 50 1-'-3S HA-:/-; 9C FRI 9 ! 9. i 20 O- 3-SARA 311/312 z~-SARA 313 LT - L~SS THAN NE - NOT ESTAgLISHE9 SYHPTOMS OF EXPOSUR EYES- CORR BURN '~-~-,', ~[- PSTENFIAL HEALTH EFFECTS Z-STaTE P~TK LA..S ,,,/ GT - GREATER THAN OSIVE. CONTACT OF EYeS WITH PRC, DUCT 'CAN CAUSE SEVERE S OR iRREVERSIBLE EYE DAMAGE INCLUDING BLINDNESSt OR .Mbl'l " ' - ' ' , DIVERSEY CORP. ORDER NO FEB 2:0 MH 'MATE2, IAL SAFETY DATA SHEET REPORT MSDS NO 129260 -SUPER SHEEN - LI:;~UiO ACID CLEANER *~*~~~-.~ SECTION II - POTENTIAL HEALTH EFFECTS IRRITATION ,~'II'H ASSOCIATED PAIN~ OF VISION. PAGE:OD2 OZ'/ZO/91 INFLAMMATION. OR BLURRING SKIN- I NGESTI ON- INHALAT ION- CORROSIVE. THIS PRODUC[ MAY CAUSE'OESTRUCTION OF TISSUES ON CONTACT. SKI?.] EFFECTS MAY INCL~JDE BURNSt BLISTERING, REDNESS, ANL') PAIN. REPEAT EXPOSURE TO DILUTE SOLUTION-S MAY CAUSE DRYNESS~ RASH~ OR REDNESS. THE SEVERITy OF 'SKIN EFFECTS DEPENDS ON STRENGTH OF SOLUTION ANG LENGTH OF CONTACT. CORROSIVE. ~'!AY BE FATAL iF SWALLOWED. MAY CAUSE ESOPHAGEAL OR GASTRIC PERFORATION. CAUSES SEVERE 9URNS TO MOUTH, THRF~AT~ AND MUCOUS HEI'iBRANES WITH PAINt REO,"-IESS~ f3R TISSUE DESTRUCTION. I;',i.'-tALAT,~O.~t F AI,,.~OP, N~E CONCENTRATIONS OF DUST~ MIST OR SPRAY OF THIS PROD~JCT PAY CAUSE .'IGOERATE 'TO SEVERE IRRITaTiONS OF NOSE AND THEO.AT AND POSSI~3LE PUL~4ONARY EOEMA OF LUNG TISSUES AND UPP;S;~. RESPIRATORY TKACT WiTH PAIN, WHEEZING~ SHO~qTNESS OF bREATH AND CHOKING. PRINCIPAL ROUTES OF ABSORPi'~UN- D · ,,,_CT C 0,"~ TA C T- SKI :l, ~z y F_- L~-- Y~S , ,,,~,:: S T I O~',~- YES INHALATION- :~iOT VOLATILE TARGET ORGANS- ArUTE- CO.RRn~V~ OR SEVERELY ~,HRO,NIC- ~iO KF~OvlN HAZARDS. IRP. ITAT!;",iG TO ALL ~OOY TISSUES. CONTAINS LiSTEC: CA~C!:-',~OGENS- NATIONAL TOXlCF~LOGy PROGRAi',I- ·" .i A ?, C M J N 0"" ~";EDICAL CO?;9IT.[Of,tS GENERALLY AGGRAVATED ~y EXPOSURE- OERRATITIS OR R - ,ELA :~D SKI?4 CONOZTI]N_S UPON PROLONGED CONTACT WiTH DILUTE S~2LUTZO.'.~S. IhHAI ~P gU.ST OP. SPRAY -~: SPI,qA~-:-~,.. · _ ...... ~,~Y DIS~SE Of,: CO~r]~TiO;,,~S. :;: FIF!.ST AID S'P, OC~:Dj,'~S--:iF:~,iER G[:/E FLUID': gp, [,Jog~ VOHITING IF PATTEr,iT' '' ~ -- . ~ ~ I · ;. ' ~ CALL A PHYSICT . EYES- Z~'~ CAS: OF Cg~;TACI'~ IHM%DIATELY FLUSH EYES WITH PL~N'TY :.4ATER FLIP AT LEAST 15 .HI,lUTES. GET TM~ED[ATE MEDICAL PROHPTLY FLUS.W SKiN WiTH PLENTY OF WATER. REMOVE C[}?'iTAMINATED CLOTHING AND FOOTWEAR, LAUNDER COt'iTAHINATEO CLOTHIN~G AND EITHER DISCA2D SHOES OR THOROUGHLY CLEAN FOOTWEAR BEF'L)RE REUSE. GET MEDICAL ATTENTION' FOR ANY PAINFUL~ RED, OR INJURED 'SKIN CONTACT AREAS. M CiI'I .: DI V Efi';SE Y CORP. ~ORDE.R NO FEB"20 MH ?-IATERIAL SAFETY DATA SHEET REPORT NSDS NO '129260 SUPER SHEEN - LIQUID ACID CLEANER .........-,- qECTION III - FIRST AID PAGE 003 0Z/20/91 1 ~GES TI IF SWALLOw, ED, RINSE !~OUTH WITH WATER. DILUTE BY DRINKING. SEVERAL GLASSES OF WATER. 00 NOT INDUCE VOMITING. GET PROMPT MEDICAL ATTENTION. NOTE- NEVER GIVE FLUIDS BY MOUTH OR . INDUCE VF]MII'ING IN AN UNCONSCIOUS PERSON, I NH AL AT I IF INHALED, REMOVE TO FRESH AIR, IF BREATHING IS DIFFICULT, GIVE OXYGEN UNDER DIRECTION OF TRAINED PERSONNEL OR A PHYSICIAN. GET MEDICAL ATTENTION. .........-.- ~-.--.--,--~--,--,-~-.-.--,- SECTION IV - FIRE AND EXPLOSION FLASH POINT- NOT COMBUSTIBLE LOWER FL,aM, LIMIT' ,. - "" LIPPER FLAM. LIMIT- EXTINGUISHING MEOIA- HATEo~ FO~ COZ, DRY CHE.'q ICAL S NONE 'KNOWN NONE KNOWN SPECIAL FIRE FIGHTING PROCEDURES- WEAR FULL P~OTECTiVE GEAR TO PREVENT SKIN CO;'iTACT WITH ACIDIC SCLUTIO,"~S AND SELF CONTAINED iOREAT!-IING APPARATUS ~"] FIRE AREA. .CEGREE OF FIRE AND EXPLOSI n'~ HAZARD- ;q0'r A CLIHSUST!~LE PROUtJCT. T~.uNG~ Y ACIDIC L]:QIjID. CORROSIVE OR ............................ ,- ......... SECTIO;.i V- REACTIVITY ~:," BILI TY- ST;.~> ~ -, ~- '- HAZ. POLYMER.I Z AT I O,~- NONE KNOWN. C 0 N O I T i o,~, ~ 5' PLASTIC TAPS OP, PUHPS ,=OR DISPENSING. DO ElSE ALUHI,-qUcq~ ZINC ,'JR WHITE HETAL FITTINGS TAPS. CONTAHINAFil'S TitAT ?~AY AFFECT STAFOILITY- ~--IETALS AND Oa. GA;.;ICS SUCH AS OILS, GREASE DETERG~hTS ?,AY CAUSe VIOLENT DECOMPOSITION OF F~ITRIC AC!C,S WITH RELEASE OF TOXIC OXIDES OF N I'FRDGEN. i NCO4PATI BI L.I TY- DO ~.~OT MIX ~'~ITH ALKALINE MATERIALS, SuF, :.lr:r,~LS DP, CHLORI.~'IATED CLEANERS, }iAi. DECOMPOSITIOH P P~]DUC'TS- 'F,iER~4AL OECOM?OSITiON -9, R HEX~'.;.G WITH COPPER, E, FLA:SS~ ZR~N OR ORGANICS MAY C.~USE TOXIC NITROGEN OXIDES TO BE RELEASED. ................................. SEC TiO?-,J I - SPILL AND LEAK RESPO;ISE SPILL RESPD?'JSE- PROi)UCT IS A STROtlG ACIDIC LIQUID. LEAKS SHOULD ~C,_~ :STOPPED. CONT,~I!'.I SPILLED MATERIAL AN_r) CLEAN UP IN.MEDiATELY. LIQUIDS SHOULD [SE VACUUNED UP OR A.~SORbED WITH CLAY ,UR SAND. PLACE WASTE IN AN APPRF~PRIATE COVERED CONTAINER. NEUTRALIZE RESIDUE WiTH DILUTE ,ALKALi SUCH AS SODIUM HYDROXIDE OR SOOILIM CARBONATE. PERSONS DOING CLEANUP SHALL WEAR A?PROPRIATE PROTECTIVE EQUIPMENT TEl AVOID SKIN AND EYE CONTACT. WASH SPILL AREA THOROUGHLY WITH WATER, FOLLO[~ING REMOVAL OF PRODUCT. -:oRDER NO FED 20'MH MATERIAL SAFETY DATA SHE'ET "'REPORT.. NSDS NO 129260 SURER SHEEN - LIQUID ACID CLEANER W~STE. DISPOSAL- PA~E 00~ 02/20/~1' LIQUID OR SOLID WASTE FROM A SPILL CLEANUP IS STRONGLY ACIDIC. PACKAGING~ LABELING~ TRANSPORTING AND DISPOSAL HAY': BE REGULATED AS HAZARDOUS WASTE AND REQUIRE HANDLING ~y LICENSE_D CONTRACTORS. CONSULT LOCAL OR STATE REGULATIONS FOR MANIFESTING AND DISPOSAL REGULA'FIONS. SMALL AMOUNT.S OF LIQUID WASTE MAY REQUIRE NEUT~.ALIZATION WITH DILUTE ALKALI BEFORE DISPOSAL TO SEWAGE SYSTEMS, ~-~e-~,.,~:~,~,: SECTION VII -PERSONAL PROTECTZON/EXPOSU ~~~~ RESPIRATORY PROTECTION- USUALLY NOT REQUIRED. IF BREATHING DIFFICULTY SUCH AS COUGHING~ WHEEZING OR IRRITATION ARE REPORTED BY EXPOSED PERSONSt MONITOR AREAS FOR C~?]TAMI~,~ATION. WEAR NIOSH ACID CARTRIDG~ RESPIRATOR WITH A SPECIAL NITRIC ACID COMPATIBLE SORGANTS OR SUPPLIED AIR RESPIRATOR WITH FULL FACE PIECE iN HIGH MIST AREAS IF EXPOSURE LIMITS -TLV~ PEL- ~RE EXCEEDED O~ WORKERS EXPER[E?:~CE SyMoTOMS OF EXPOSUF;E. '~-,,TtLATION- LOCAL EXHAUST- G~NE RA L- EYE ? R,jTc'~T .[ ON- PROTECTIVE GL O'V ES- OTHER P '~ ' R.JTECTiVE i.iYGIENE PRACTICES- USUALLY NOT P, EQUIREO EXCEPT IN S?RAY AqEA$. FOP, SPRAY OR ~",!ST AREASt USE ADEQUATE V~N'TILATION TO MAINTAIN EXPOSURE :3ELO~ GU IDEL IN~S. SPLASH GOGGLES, FACE SHIELD 'OR SIDE SHIELD SAFF-TY GLASSES. RUSEE?,, PVC OR OTHER ACID RESISTANT. CHE~.~!CALLY IMPERVIOUS CLOTHING A~'ID FOOTWEAP TO PREVE~,[T SKIW CONTACT. SAFETY SwDWER Arid EYE WASH IN USE ~REA. W.~.S~ AFFEF,', HAJ'~DLING OR USING PR. ODUC'T. LAUNDER C 0 ~'.i T A!'.I ~,,ATEO CLOTHING 5EFOP, E REUSE. CLEAN DP, REPLACE C,]"TAMINATEO FOOTNEAR ~ L,~E USE. .................... , ..... - S TIO,~ v~[T - STOF',A(;E .AN~ HANDLING ;qE~? AWAY FROH C~-~LC~R[~.jATED CL~ ~,- ,,~ .... cA ~R,S .a~.~O bLEACHES. KEEP CONTAINER CLOSED WHEN ,.,_,VZHG OR F~O'T .[,,q U.';m. ~EP OUT ~]F R~ACH OF CHILD ...... DO NOT STORE WITH ~K ,ING TO THE ~URFAC5 OF S:3LUTIC~[ T:] AVOID VIOLE?~T SP~TTE?iN,i~ .A~O HE.~T GENERATIO;-,i. .STORAGE MATERIALS- Omc. MS AND TANKS USED FOR STORAG~ OR TRANSPORTING GF T;-t£ PRODLICT MAY BE STAINLESS STE[L~ HIGH OENSITY POLY5THYLENEt GLASS OP, ACID RESISTANT COATI~,!G LINED ,'.~F'£AL. PIPI?.~G CAi,; RE GLASSt PVC .-SCNEDULE .~0-~ !]R STAINLESS STEEL-300 SERIES-. CONSULT DIVER'SEY COP, P. TECHNICAL REPRESENTATIVE FOR ADDITIONAL [ NFO,qMA TI ON. '" '"' ..... ~~¢ SECTION IX- PHYSICAL AND CHEMICAL PRDPE APPEARANCE AND ODOR- CLEA:P,I R~.D LIQUID WITH A SHARP P~NGENT ODOR. D'l'l ' '" ¢ '" . DIYERSEY CORP. ~3R.DER N'O FEB 20 HH MATERIAL SAFETY DATA SHEET REPORT PAGE 005 t. iSDS NO i29260 SUPER SHEEN LI~JID ACID CLEANFR ~~~=~:~ SECT[ON IX - PHYSICAL AND CHEMICAL PROPE ~*~~~~ ~' ' ?' '? " 02/20/91 TING POINT- NONE' SP- GRAVI TY-~A TER-1-_ 1.180 b,,JILING POINT- 25Z DEG,~, F. VAPOR-'PRESSURE-]0.5 'NM, HG 20 DEC_,. F. VAPOR DENSITY- NOT KNO~'N SOLUBILITY '[t~ WATER- COMPLETE :~ VOLATILE-3y ~T.-- ~8% CORROSIVE ACTION JN MATERIALS- EYAPo RATE-WATER-I-- - 1 FREEZING POINT- - 30 DEGR Fo PltOSPHOROUS~%p-_ 3,3% PH AT 25 OEG.._C- I% SOLNo AT OTHER- 'NA CORROSIVE TO ALUMINUM~ COPPER, BRASS~ TIN AND OTHER SOFT METALS° ....................... ' .... SEC 'TION X -TOXICOLOGY INFORMATION PHOSPHORIC ACID IS CORROSIVE AND CAUSES 9ESTRUCTZON OF TISSUES. NITRIC ACCO IS CORROS.[VE AND A SEVERE-IRRITANT TO TISSUES, ~MOSPH ' ,.. ORIC ACID TOXICITY ACUT~ C~AL LDEO - -RAT- 1530 MG/KG -RTECS- ACUTE DERNAL LDSO - -RABEIT- 2'7~0 MG/KG -RTECS- K~TRIC ACZb I'OX~C ACUT6 CRAL LDLO -MAN- 430 ;'!G/KG -P-FL- ACUTE ~NHALAF~ON LC50 -RA~ 67 PPN -H02-/~ HOUR~ 'THEE EST.[M~TED []RAL TOXICITy OF THIS ~RODUCT FOR AN~-~ALS IS 932 ................. ScbT~ON X~ - ECOLOGICAL EFFECTS ~**:~**~:...~ THIS P/<~]OUCT ~S S Ti< {]:q GL Y ACI~'[c AND ZS TOXIC TO 3IOLOGICAL FO~,hlS ........ ~ 4ASTE SOL'"' U, I~H5 ~qAY RE:~UZRE HEUT:~.~LIZATI~N TO A SPECIFIC PH ....... D[SCHARG~ T9 PUBLIC OR PRIVATE SANITARY c~WE~ SYSTEHc SOLUT'- ..... ;,~ T2 .... .- ~ " .F,_, DO NOT D~SCHAR~E :JN/REATED "~L1j-rld~S TO LAKES, STREA~-IS~ _,r, ~'~ OIS~OSAL- ,4H~N G)!P'TY~ '[;qIS CONTA~)j~R ;"9N'¢ STILL ~E HAZAROOUS FP, LDL: $~INSE C~NTAINER .~.'~ '" ~ ~,'~,-, L~NER WITH WATER AqD TO USE SOLUTTOtl :]~ pR~,t~rT. ~ELIVER CLEANED rONTAiNEp, TO A DRU,H R~CY~LER. OR DISPQSE OF IN ACCDRDANCF WZTH ENV.[RO:WN~NTAL REGULATIONS. '- ~ LI]lJIu N,O,S, -NITP, IC .~ND PHOSPHORTC AClrC U!~ i76j - .]OT CLASS- C~3RROSIVE -.[?C, CL~tSS ,~- .... ~_,IVE LI.~UID N.D.S. -CONT.4ININC NITRIC AND PHOSPHORIC ACIDS- UN t750 " 3;.]T E MERGE~.:C 7 ,i~SPOqS~ SD[SE ~.i0. J'PFIMODI Ty COGE- .~S ~:RT CLASS- TSCA I;'IVENTORY- C b~CL .4 909, 951, 962, '763 LTL ~-: ALL CG?iPO:',jE;,~TS OF THIS PRODUCT HaVE BEEN iNCLiJDEJ ON tHE TSCA INVENTORY. PHOSPHORIC ACID 5000 POUNDS - SUPER SHEE:q- 45,454 POUNDS OR ~629 GALLONS OF PP, ODIJCT. NITRIC AC'[~ ZOO0 POUNOS SUPER 5,000 POUNO5 OR 509 GALLONS.. 3UCARE-8=O0-5%00 EST-MON-FRI 1-800-563-690'6 I~I~JlcAL(-COLL'E[;'r~ $05-592-1026 CHEMTREC !-800-6Zq-9500 HESTLE %CE CREAH COHPAHY D%VERSEY CORP. eMenOe~cYp~o~eNo. 9 _ ~ ~12025 TECH CENTER DRIVE 7501 DZSTR[CT BLVD ~ LIVOHZA~ HZCHZGAN q8150 515-q58-5000 BAKERSFIELD CA 93313 ~ PREPARED BY= REGULATORY REFERENCE ~ ON 06/28/9~ B/L~ 10~678-00 ' ABERraTIONS .... C.CEILING....MP.M~IMUM PEAK....N/A. NOT APPL~ABLE....NtK.NOT KNOWN....P.POTENTIAL...PEL. PERM~SIBLE ~POSUnE LIMIT ' ....P~PENSKY MARTENS....S-SKIN....ST-SHOR% 1ERM..,.TLV-HtRESIIO[D LIMIT VAULE....~A-TIME WE~HT AVERAGE .... ~ioN'l COM~" NAME ~ED ON LABEL ~U_A~56 co~ U)~T CHEM~ALFAMILY SANITIZER AND DEODORIZER/DISINFECTANT SEC'lION-2 PRINCIPAL HA~R~ COMPONENt(S} Clt;UCIAL 8 COMMON NAME % ~XPOSURE UMI[S (]~A 8 ItOURS UNEESS OTHERWISE SPECIFIED) UNI~ ,~.~. EPA REGISTERED PRODUCT ~875-I09 I~a~)~ <o~s QUATERNARY AMMONIUM CHLORIDES ~ (68~9Z-01-5; 68959-79-6) <1~I HOHE ESTABLISHED SECTION-3 eo~um 2 [ q °F 8PEclr~ 0 9 6 8 vA~ 2 2 8 mmH~ 2 0 °C VO~TiLE .I~SlCA[.* APPEARANCEaO~R CLEARx LIGHT YELLOW LZg[[~L MILD ODOR CI~flCAL ~ASH CO~ FLAME FLAMMABLE LIgnITe- LOWER UPPER AUTO ISlICS POINT ~00 °F ~ENSION N/A In. IN AIR BY VOLUME NONE NONE TEMPERATURE NONE °F U.mUAC n.E ~.o N 0 N E SECTION-4 SZAmU~ POLYMERI~I~N STABLE mCO.PATmCE N[TROGEN OX[DES~ SOAPS AND A,N[ON[C MATERIALS. }~TARDS PRO~ SECTION-5 PRIMARY ROUTES OF ENTRY ' ,NHA~.ON y ~ s..~ ~__ y E S ~.o~s~, ~.Acm~ SEVERELY IRRITATING TO SKIN AND EYES. MISTS CAN s=,s' BE STRONGLY IRRITATING OR CORROSIVE TO RESPIRATORY ~ TRACT. AND SY~PTO&~ ~.c,no.~ SAHE AS ACUTE OF ME~ALCONDIT~NSOENEnALLY SENSITIVE SKIN, SENSITIVE EYES, A~VATEO~POSU,~ [ MPA [ RED PU LHONARY FUNCT [ ON. ~S~OCARC~,~. NONE m, NO ~AnC NO ~HA NO EMERGENCY AND FIRST AID PROCEDURES 1.1NHA~TION IF [NHALED~ REHOVE TO FRESH AZR. IF BREATHING D[FFZCULTY~ SEEK MEDZCAL ATTENTION. 2.~ES IMMEDIATELY FLUSH THOROUGHLY N[TH FRESH 'NATER FOR AT LEAST MINUTES. 'GET PROHPT MEDZCAL ATTENTZON. 3. SKIN [MMEDZATELY FLUSH N[TH FRESH NATER. REMOVE CONTAMINATED CLOTHES AND SHOES. GET MEDICAL ATTENTION. 4. INGESTION GZVE NATER. DO NOT INDUCE VOMITING. GET MEDICAL ATTENTZON. NEVER GZVE FLUIDS TO AN UNCONSCIOUS VENTILAT~H L~AL N O S~C VENTILA~HUECHAHCAL HORHAL AIR DZ~OH SPECIAL 'HOHE PRO~ION ~Rm~lOH PROTECTOR ~LOVES HOH- ~OE~EH~E~'~DL ~EPROTEC~N FACE SHZELb-7~ETY GOGGLES NHEH HAHDL~HG OTHER PROECT~E N 0 N E CLOmtN~aUmMEHT ~ECTION-7 HAN~ING DO HOT PRESSURE COHTA~HER TO EHPTY. STORE IH A DRY PLACE AND BETNEEN 50 DEGREES F AND 120 DEGREES F. KEEP BUNGS IN STO~O~ CONTAZNER. [F FROZEN~ THAW AND MIX TO MAKE USABLE PRECAUT~NS ' omen D.O.T. CLASS= DZSZNFECTANTS~ CORROSZVE L[QU[D~ N.O.S.~ .,~o,s ~FaATEn~AL~ FLUSH SMALL AMOUNTS TO DRAIN. COLLECT A~) n~EASEO~P~LCEO AND RETURN LARGE AMOUNTS TO CONTA[NER. WASTE USE UNTZL LESS THAN ONE INCH REMAZNS [N CONTAZNER~ EMPTY DISPOSAL CONTAINER. TR[PLE RINSE NZTH NATER~ ADD TO OPERATION. METHODS REMOVE OR DEFACE LABEL BEFORE SELLING CONTAINER OR DISPOSAL. PH ADJUSTMENT~ NO PHOSPHATES. CONSULT HAZARDOUS ~AS~.. DZSPOSAL REGULATIONS. FOR. PEST[CEDES ' (EPA) · '. HM~ ~TING HEALTH ~ FLAMMABILI~ [ flEACT~I~ 0 PERSONAL P~TECTDN · D ~E III 6EC~ON 313 S~A~e OF N / A CA ~R~¥nON 02/27/96 16:~3 805?251059 · SULLtVAN$ PET. P.09 ~atezial Safety Data Sheet ~ate~£ai Safe%y Data Shee~ C F'~-V20 C~-v'RO 1 of CP$27~113 C~s272293 CP$272125 CP$272;27 · i~F~Y Tv~.~ONE I~OllBEBS (51~)!31-052~ {Intm~nationa%) (8QQ~424-9~0~ cz (2~2)4~3-7~i~ 2. CQ~0$1TION/INFO~AT!ON OH il~MEDI~S LLMIT/OTY .';0?,'2: AG..MN.,,-Y,'TYPE Risk Assessment ~it, ~R~, P.O. BOX 4054, Ricing, .CA.94804 .:.~ chemical <~G~,~PPM COP~0$iTION COnVaLESCe: PEL - P~rmissib!e E~pos~e Limit CAE - Ch~!¢8~1 ~St~aC~ Service N~e TLU - Thre~h~!d LL~it value STOL = ~hort-t~xm Exposure c - ce~ii~g nimit Pale Fellow liquid (u~Fe~) or Ee~ li~Tuid - Cg~USTIBL~ - F2~P/~'~ OR FAT. a_L IF SW~r_~L~ED - CaN ENTF~. Am) CAUSZ D~.~.GE - CAUSES SKiN - ~La_y CAUSE C~d~C'~. ~A$.ID ON ~=~IKar. DAT~ ~te~nal ~Ig~us. Bec~us~ of ~e 10%' viscosity Of ~is ~st~e, i% can " ~i~ c~ C:~r du=i=g th~ ~ct of sw~ilow~g or when vomith~ the s~s%~c~. ~e im the !~, the snhst~cm is ve~ diffi~lt ~ r~e I~TION: Ce~ no. Gus sysuam effects ~y inclu~e one Or more of ~iz~olo=mtiou, ~weliin$, ~ud bli~terimg. This pr~u~ c~tain~ a miznure of p~%role~ hydrocarb~s Called middle dis~il!~tes (whi~a me~ ~ ~il be~we~ a~ro~atoly 35GY ~d 7~P) ~S~ zk~' c~cer whe~ ~epmat~d!y appii~ to mic~ ov, r their iifet~e. ~is produ~ may contra sene ~ddle ~tilla~es found to caus~ ~verse FIRST did ~rE.%$U~$ NC firs= aid procedu_re0 are requ, ired. KOwcve:r as a precaution flush eye SKIN: R~CVS co=t~min~=~ ~o~ing. wash skin thoroug~v ~i~ ~oap Sam a ~o~or if a~y si~s or s}~ptoms' describgd in-~i~ do~% occur. Disc~ cont~n~%~ ~-wa~o~roof shoos and boo~s. Wash if sw~ll~, give water cr mi~ to dr~ ~ %eleph~e for medical n FL~LE PROPERTIES: FLASE POINT: [i~a) I~SP (~C) Min. AUT-O!Gi~TION: P.D.~.~BiLITY LIMITS (% by volume in ai~): LO~C: 0.5 Upper: 4,7 COZ, Pry C~emica!, ~oam aud wa~er Fog. NF~a P~iN¢$: ~ealth 0; Ylanm~ahillty 2; ~eactlvity 5, FIR~ F%GH~G ~NSTRUCT!ONS: Liquid evaporates ~d form~ vapor (fume~) which eau ca=eh fire audkurn' wi~h oxplozive violence. Invi~Lble va~¢r ~p:ead~ easily and c~n be fire by m~y ~ourc~$ S~ch as ~ilcU ~ghts, ~eldiag equipment, and electricml mo=or~ and ~itchss. Firs ha=ar~ is ~reater a~ liquid t~mpera~ure rises ab~v~ 85 ~. fire sp~ce wi~hou~ proper pr~:e~ive eq~ipmant. Thi~ may i~oiud~ s~lf-con~n~ braathln~ a~p~atus to pr~e~ aga~st th~ hazardous ~ntire do~. ' CO~i~ ~RODUCTS: ~o~al ~stiom fo~ ca,ben dicxid~ ~4 wa~er va~or; in::mplete c~us~ c~ produce carbon monoxide. ~. ACCID-~NTAL ~ASE!~_a3Ui{ES CF~:~TP--~CEHZRGZNCY T~--ER (24 hz): (8003424-9300 er (292)4}2-7~1[ ACCIDENTAL R%'~ASE El~na~e all so, cee of ignition ia vicinity cf spill or reiease~ vapor. materi~s or p~pi~, where feasible ~d * t:'...-., J.~ ' ~-."~ -' '""i.": · · :' ""'°0~.'.~[/'~' .[ --?.¥ . .- :- ~ - b.' .'./-t-'~ *: . ~ . '- - ., ~.' .. ~ -, .... '- .. .... - .. ~ .-'. = .'.:."-?'."~.~ "/ .... : ...... ...... .., .,...~. :~.?:(~... '.:. '.'"': .. ~X~T~ ~. K~ep eonta~er close. . . .. ~ N~ w~id, hmat or ~ilt ¢ontain,z. Replace cap oz h~g,mpti~ - " con%a~cr ~ti!! cont~s hazam~ous cz ezp!o~ivc vapor or !igOr.', ~n - No Da~ ~vailable ~ - N~ C~ON Specie! L~ Diesel 2 8 Pagm 5 of explosive force. ' W~N!N~! No% for uae as portable boa%er or appii~r, ce fuel. Toxic fum, o~ may accumulate ~nd cause deaLh. 6. EXPOSURE CONEJROL~/_~.~,RS0,.~AL RNGI~ING Use this material only ia ~=-11 ven%i!a=ed areas. NO ~pocial'~ pz~te~ion is u~uai!y ~ec~ssa~. ~v~id con~a~wi~ skin Or o!~ing, Skin cantact shoed bo minimized by w~ar~9 ~rote~ive clot~ includin~ P~DI~TCRYPROT~CTION: - . . .. no~a=_y r~ixed. Euwever, if opora%ing ccn~tions create high airborne c~ncen~ra~i~net the use of ~ appr~ed r~spirator i~ roco~ended. AND CK~,IC~L P,~0P£RTIE~ Pale yellow !iqui~ ~u~dyed) or Red !iqui~ P~: NDA " VAPOR PRESGUP~E: 0.0~ PSI~ @ 48C VA/=OR fAiR=l): ND~ BOILING POILU: 17~ - 370c Revision ~urabmr: S R~vi~i'e~ Date: 88189195 NDa ~0 Data A'~ailable '~% ' Nc% OF_EVRON $~ec£a~ L~ Diesel 2 Page May rea~wi~ ~trong o~idizin~ ~mnts, ~ a~ chZorates, nltrate~, ~ol~mriza~i~n will not occur. r~nimal effec-,s clmaring in less than 24 hours. SKIN Hodera%e ir~itaticn a~ 72 ~curs. (~erato e~--~.~a). ~ rabbits is >~ ~lk~. ~i~'mat~rial ~a~ not a sk~ sensitizer i~ the Bue~er ~ine~ ~ig Se~sitiz~tic~ The oral ~3~ in rats is > ~he ~-hour i~!~:icn ~O in rat~ is graatet th~ 5 The dc~a ~e is obtained fx~m ~tudie~ s~ons~r~d ~v thc Nc data available. Nc data available. . . ;:,..,,:~ ::-,., :::'..;.;,,¢ .;;.'.;;~..,-....:.. J. Th;~ '~ter I f: ) :??:-, ..., ':..,' '.':., Z, 'facility. '.'-: , · ~-'. :.- - ::--,.~': :.,' ', .' ".~,':,,":' . ":,,':,:~:,~;.. : -. ;'-J~:"'..' ., ':'. ' : '., " . · "~, ' .' :': :':~'' :-' ':' - ..... ':.';;',:': ~ , 'it 4~C~R, o_ a~p:opriate D~gexo~ ~o~ ~lations, for ' . - additic=al descriPtio~ r~ir~en~ (e.g., te~nic~ =~e) an~ . · ' R~vision ~er~ 5 Revision Date~ ~B/09/gS : ~ ~er: 00551 ~A - NO ~ata avail~le ~ - NOt applic~l~ ' C~ON $peci~ LS Dimsel 2 ~ag~ 7 cf mode-specifi~ er T~aati%y-cpecific 5kipping requiremea%$, "_ /.." ·' D~ ~zk~ Ck~S$; CQ~U~TiBLE LIQuiD '' D~ IDZ~IFICATiO~ b~: ~12~2 15, REGv'I~TQR7 INFORr~?ION 1. in~me~ia~e [Acute) £~alth EffeCts: .i~$ 3, ~ire Haz~ ~S 4. Sudden Release of Pressuro'~zar~:'I~ 5. ~eactivity ~azardt · NO RXGUI~%~ORY LISTS ~l=~p~ 213 02=MASS RTK ~$=NT2 Car¢incg=_u 04=¢A P~op 65-Ca~cin 05=CA Prop 65-~epro Tox 0~=I~RC Grcup, l 89~SA~ ~O=~A RTK lists iadic&to~. 11:NJ RTK 22:TSCA aect 1~=~ RTK 24=T~ Sec~ t2(5) 14=aCGZH ~a 25:T$Ca Sect IS:ACGI~ STEL 2~:TSCA So:t I~:AC~!~ Calm TLV 27:T$¢~ Se~t 17=O~ ~ 2~=Canadi~ l~:D~ ~a~ino ~c~iuC~t 2~OSF_~ CEI~NC of this material are foun~ o~ t~.e regulato~ *********************************************************************** $~eci=l L~ Diesel 2 paqe ~ of that th~ persou reo~ivin~ ;t ,h~ , hi~ C,T. det,~ion T~OE NAME Ace~le~ ~ prOdu~ ~s intend~ f~ wetdi~ ~ cut~ u~.) ~ uGe~th~ ~f a~e ~ver~ ~ ~n VI. ~e [~m "h~Td~s" ~l~ ~ ~tar~ed ~ a term ~r~ a~ defi~ ~n ~A ~ CFR 19t0. ~ ~S not nec~r~ly imply ~e exist~ of any ~W~. ~ ; M~Em~ (~ NO.) : Vol (~ I~6-1~7 A~IH ~V-TWA A~ (74~2~ 1~ Simple asphalt-- [N~e currently T~ler ~e~/~e ~lind~ ate fi~ ~h a ~s m~ed~ ~ining dim~hyl f~ami~ (D M~ into ~ the ~ is ~olved. ACG1H ~as esta~i~ a TLV.~A of 10 ppm (s~n) for OMF. BOLLING POINT, 760 mm, 'Hg ' Not Appl~ S~BLIMATIOH POINT -8,('C (-, ~9.2,~) ~ 7~ ~t~C G~VITY (~O'= 1'~ Nct'A~llc~ V~POR "~URE AT 21 ~C. 535 psig ~ SOLU~LtTY IN Slight. ~ VOLUME. 1o0 ~ (Butyl Ac~ate = 1) Not APPEARANCE ANO ODOR Cc~3rle~s ~ iN CA~F_ OI= EM~[g;I.(:~'NCIE~ invO{yi~g [~hi~ material, further reformation ;s a~a~lab~e at aJI t;mes:' In the USA 1-800-UCC.-HELP (1-80G.822-4357) . In Cana~. 514-645-5:31 .. -,. F~ routirt9 info;r~ati<~n c~'~ia;t your local s~lDplier ; .. UNION C~RBtDE CORPORATION O. LINO~ UlVI$~ON UNION CARI~IOEiC, ANA~2A UlII'I"ED ~ ~ DI~ON ~ ~ I~ Un~ C~ C~ ~ · ; LlniO~ ~ide requests the users ~f this p~::<luct to $1. udy tills Material Safety D~ S~et (MSDS) a~ ~me Bw~re ~ ~t ~ ~ ~f~y in~r~ion.. To ~ ~e use ~ this ~t a ~er s~ld (1) n~ im em~. ag~ ~d ~cto~ - ~ ~e in~t~ .o~ th~ M~ ~d ~y pr~da~ ~r~ a~ ~f~ info~ton, (2) furnish this s~e in~rmatio~ ~ ~h ~ i~ ~~ ~r ~ p~. a~ (3) ~ ~_~ cu~Om~ to n~i~ ~ em~ a~ cu~o~rs for ~e p~t ~ the ~ p~ h~ ~ ~y inf~at~n ...... ~_ ... ~ .... FEB-23-1996 15:50 BLdS, INC. PROOUCl'.~ P. 02 Tt~REsHoLD LIMFr vALuE: Acetylene- Simple as~qY'x~tnt ^CGIH 19~.~7 Acetone, 7.~ ACGIH 1986.87 OF ~Cd.E (ACUTe) OV~qEXI~SLIRE b';WALLO~qNG -- An unlikely r~ute of exposure, b~ fmst~ile iof fl~e #ps an~ mouth may result from conla~ wi~ ~'~ lic~Jid, l('the liquid is ~a'allowed. may cause nausea. SKIN AIt"e'ORi~TION ~ No evi<lence ~f adverse effects tromiava~la~e information. tNI.IALA~ION -- A.~yx/ant, Moder~.~e Cence~tratior~ of v~ may cau~ ~eadache, drowsiness, diz2iness, nausea, vomiting. ~¥~ CoN' 1'A~'1' ~ ¥~r may ~ i.-ri~m, i_i~uid ma~' c,~u~ i~ri~t~ ~<~ f~o~te. OTHER EFFECTS OF OVEREXPOSURE: No~e currently known. AGGRAVATED 6¥ OVEREXPOSURE: A knowledge ~ me ava~abte tox~:~/i~fotrnat~o~ ar~ 0t the a~<] Chef~~cal properties of tt~ mat~'ial $~lge~R that Overex;~$ure ~$ unlik~y to aggravate existing rrte01ca; conditions. EbtERGENcl' AND FIRST &lO PlqOCEOI. rRE$: ~ ~F~ ~e ~ ~. tlu~ ~ wa~ warm fr~te ~ w~ wmm ~zet (~t to ~ 1~. tn ~e of e~r~, ~e ~h~ wh~e ~i~ w~h warm ~te~. ~ a ~ian. · E~$ ~ In ~ of ~ ~inat~, ~mm~ia[ely fl~ ey~ thom~ wi~h wate~ f~ ~ ~ 1~ minutes, ~k the ~. t rems ~ ~ ~~ ~t~y tn a ma~ wh~h avo~ ~r~;~. ~~, Z~tment should ~ ~ at ~he : W~ ~H ~ING ~O ~NG ~Y CR~TE AD.TIlL H~ HA~RDS. ~M~ ~D ~$ ~ ~ d~r~ ~ your ~ a~:.~y ~ ~i~ t~ d~a~.* K~ ~ ~ ~t of t~ ~, ~ ~ ~ ~m~ ~ ~ ~ ~y t~e W~. Use e~gh ~mitat~, ~l or ~ to;k~ f~ ~nd ~ fr~ y~r ~i~ zone an~ the ge~r~ ~ea. The ty~ ~d amou~ of ~mes a~ g~ ~ t~ ~t ~d ~ ~. P~ d~ mater~ ~ ~ ~ ~n flux~, ~ati~, g~, meta= e~. Get a Safe~ Data Sh~ (M~S} for e~ ~t~ ~s~. ~r ~ ~n ~ used to fine out what r~at~ p~on is : ~ ~m O~x~ ~O ~U~$ ~y ~tt ~ ~m~o~ $~h ~ dlzzine~, ~a, ~ ~yfl~s or ;tr;;ation o~ n~, thr~t, ~ eyes. ~ ~ t~ ~ may~u~ ~~ ~a, ~iet~n. ~ ~ath. A~te ov~e~ure may incl~ ~ ~ s~s ~ ~ wM~ ~, ~e and ~; ~tr~, h~, ~, d;~<ul~ ~. lr~ ~' ~t~ ~at~ of air ~iami~ may I~ ~ ~r a~um~ in the ~s, a ~ition ~ ~ ~t ~y ~ted w~h ~O~ or s~ of r~ ~ ~ti~ or d~e. tn ~dit~. the cha~ on x-ra~ may ~ ~ ~ ~k ~t~ f~tom ~ ~ ~ ~te ~ ~r ~[r~ W~ng ~ Cu~," ~-5~. Y~ may ob~n ~s ~ ~ ~ ~i~, ~ by writi~ tO Un~ M~S: ~ ~ er ~ ~ ~ ~ ~ a~ ~x~. ~r b~ ~o~d~ may ~bine m ~eate ~. rave .pr~-~ies which can Cause TOTAL P.02 '~ FEB-23-1996 · ,.~ · i~ODIJCT: 15:57 BWS, INC. {teat m~thod) -17.B;C (0"1~ T.C.C. INIAIR, ~/k I~ LIMIT~ LOWER 2.3%: T~a.OERATLIRE IUPPER P.P_31 2~oc (571 °F) 10~ L-4559.,E April 1~7 TOTRI_ P. 01 STF. P~ TO BE TAKEN IF MAI~qlAL IS FIELEASED OR ~e~[LLED Re~' to CGA I:k~rnphlet SB-4, "Har~ing Ace~,lene Cy!inder,~ in Fir, Situations." Evacuate all personnel from ~atlcjer area. Imme<lialely [cool conlaine~ with water sp~ay from max;mum distance taking care not ext~nguLsh flame. Remove ignition s~urces if wither rL~,k, if flam~ are =~¢k~ental[ly extinguished, explo~;ive re-igniTion n~y occur. Use seLf-contained breathing apparatus. Stop flow of 9a$ if without r~k white ¢orrtinkqcj cooling water spray. Remove all Containers from ama ef fife if without dsk.'Allow fire to burn out. O~'site fife br!gades must comply w;th OSHA 2~ CFR 1910.156. UNL~_~J_a£ FI~ AND EXPLOSION HAZARDS : EXtremely flammable gas, Fg~rns expk~sive m~ares wit~ air a~ existing ~en~. ~n~ine[ may rup~{e due ~o heat of fire. Oo n~ ~n~ish flam~ ~ue to ~t~li~y ~ exp~o~ m-lgni~n. Flamma~e ~m may ~ea~ lmm ~ak. ~Ne atm~heres may li~. ~ore ent~ ~ea, e~ ~tin~ areas,[~¢k ~here whh a~m~ expl~ion meter. No ~ of a conlain~ ~ be ~b~ to a tem~mtum high~ t~n 52~C (~oximately ~ 25,~. NI con~rs are ~i~ ~h a pressure te~iet oev~ de~gn~ t0 ve~ c~tenls w~ they are ex~ to el~at~ lem~rature. C~la~ wi~ c~r, silver. ~ m~Cury or {heir or ~s can cau~ ex~on a~ be igni{ed ~ pilo~ I~hts, o~r ~lam~. s~k;~, ~a~ks, heat~s, ~tricai ~pmem, d~he~e or Other ignition ~Ur~ at ~;~s dis~a~[ ~rom pr~ [h~dfi~ ~int. ; STA~ [ ~1~ TO AVCO INCOMPATIBIL~ (mate~ ~ ~ . ~ .' BWS, INC. P.Oi L,4SSs~E AI~I ' ' i ; · eot a,S per 05HA29 CFR1910.134, LO~I~L EXHAUST ~ Use enough ventttaUon, lee. al ext~u~t or ~V's in ~e ~ker's ~eat~ng zone ~ ~ ~r~ a~e~ T~n ~e ~k~ ~ k~ h~ ~ ~t ~ the ~ ME~~L (g~l) ALWAYS WO~ WI~ E~UGH ~TION ~ W~lng ~ r~ehd~ ...... L ~ ~ the ~k ama ~e aual~v .~a .... ~ ...... ~ . as pmnt, pJal~ng, or g~vanizin the Ua~ ~ti~ C~ va~ ~ ~t in use ~ when e~. ~ wo~ on a pr~sur~ sy~e~. ~ ~ol slrike arc on c~inder ~ ~pr~ by an ~ burn ~ ~ to ~find~ rapture. ~ ~t ~r~ ~in~. Stye i~ e~. dry. well venUlat~ area. ~ nm ~ n~r ~n flames, · , ~l~rJ~ ~p~nt ~uld ~e~l~ p~f. ~ not szore ~th Oxygen or other oxldizem. ¢yli~ ~om ~ ~, StYe c~er{ in u~ig~ p~i~on ~re~ ~ Prevent fating ~, Refer to C~ Pamphle~ P-I and m current a~ of tt'm date ~f this Material Sa. fe~ Data S'rm~t, $ic._~ the use of th~ information ar~ these opinions and the conditions of ~e Of trl~, product am not within the conlrot of Union Carbide, it is'the user's obligation to determine the conditions of .~afe use Of ~e product. IN CANADA; Union Carbide Canada Limited Linde Division I2'3 Egtinton Avenue E~sl Torito. Ontario MaP M3 Pagt~ 4 ~t' 4 · ID~IVIlIT CHEMICAL FAMILY u~ MG/M3 FLAME EXI*ENSION FLAMMABt E LIMII~ LOWER UPPER AUTO I~NITION N/A PREV~N~ CONTACT WITH ACIDIC "'"~MP'RAI'URE.q ABOV~ 140 ~ DEGREE~~II BLEACHE~;-'0R"CHI;ORINATED CLEANER~ oF AND OF OVEI~IiPOSURE 1,AOUTE 5K~ DANAGE. IF SW CAUSE SEtFERE IR ALLOWED. MIST p RITATIONS OF NOSE ULNONARY EDE T~ROAT TRACT, MA OF LUNG TISSUE ~D UPPER' SAME AS ACUTE ION NAY AND POSSIBLE RESPIRATORY 11~ __1__~ L CONI~mONS GENERALLY It"tVA'rED BY EXPOBt~I~ EMERGENGY ID FIRST 1. INHALATION 2. EYES 3. ,SKIN 'L*INGE~,TION REMOVE TO FRESH AIR. GET M~DICAL ATTENTION. IMMEDIATELY FLUSH THOROUGHLY WITH FRESH WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. GIVE WATER. DO NOT INDUCE VOMITING. GET MEDICAL A . NEVER GIVE AI~ING BY MO~ ~E~ZON ~ ~ ~CONSCIOUS PERSON. VENTILA'IION U£CK .C,i,,~lC~ L DO NOT PRESSURE CONTAINER TO EMPTY. DO NOT FOOD, OR FEED BY STORAGE OR DISPOSAL, ', (PHOSPHORIC?' APPi -'--,-~, c-uwralNJ~R. NEUTRAL! ~-~,~ VASTE IN ·EXCESS 'ACCORDING TO THE~E NSATE IS A VIOLATION OF 'OR DI: OF BY USE REPRK [VEAT OR PESTICIDE WASTE REGIONAL OFFICE FOR GUIDANCE. CERCLA PRODUCT RQ = 27,027 LBS OR 2,845 , _ '-ISTED ON ,SCA INVeNtORY. WATER - CAS CAS 6 ~z~ ~U~Z~RC~YLE~ ZO CAS ~11096 42 7 ~ 8439-47-4 ' ~ DINE COMPri - - SECTION FR;[I:K OIL PAGE ~tATr.-RIAI. SAFETY DATA SHEET ' 'FI TS pRDOU~T 5AFI~TY 'Zl,iPD1THATZOI"I Z5 T~D'9'IDED ~ REGULATZOHS- PLEASE TOR~ARD ~l~S TO Y~ ~IAGEfl ' ' ~VI~ ~U ~RTED 09/0~/69 ~ ' ..... ~~j~~ ~L~ED PETROLEUT1 LUTTRICAIlT; CODE ~aoooa~7~o~ DCTAtM] L/1~ATER ,~5ECTIDH $~pHySTCAL I]ATAI~ APPEARA~CE$ LIGllT AUItER FLUID, DOOR: LITTLE ODOR. - ..... , ....... --l'Am~' ~cOHTIflU~D gl{ PAGE 2~~ ' . · CTIOH q~FIRE ANU Eli Lubiu~ ~ ~l,~- r ~E --~-- - { ........ ~--~ TE~PERAI~E' 69S ~TI~AT~ F ~ ~8 E~xttkrEo C FIR{ ~ {XPLOSlO}I IIAZ~D~ J ROOODO37$ZO) ' H/A = )lOT APPLICABLE H.D. ~ HO DATA ~ '~'' M^TERZAL.S^FETy OAT^ SHEET OF EXPanSE AI~ ~FFECT8~.. , SKIN PRACI'ZCAI.I.,y NOII-TrJXIC ZF AB-~OI?DED (LO~O GREATER TIIAN ED§O I'~/K~)o MOfJERATE [RI~ITATIDI,I IdT'rl( PROLONGED REPEATED CONTACT. COttTACT HI111 IIIE EYE HAY CAU3E IfZIlIHAL %RI~ZTATZON. PT~ACT~CALLy NON-TOXiC IL l DSO · sWrtl NA~II CLOTII*rt~ BEFORE REUSE. EYE FLUStl N[TII HAT,R. I NO ESrZO~ PffACTICALL¥ NOII-TOX[C -- ZI'a)UCTZON OF VDIlZTZRO UOT flEt~IIRED,, OOTA[N HEDZCAL ASSZSTAtfCE. SrlALL AHO~¢T9 SIA'~LE. PER~JO~'IAL PROTECTIVE EI~"rT~,.,IEI,.,¢'i~~,.._~ PIIOI~LiCT U~flZ~LLY ZRRZTATZltG TO EYES. LOCAL aAFfi~ ~L~CY COI~EN'TRATIOH'IN'AZR DETERll'INl~5 PROTECTZ~I'4 NEEDED. U~E ONLy NIO:~II CERTIFIED RE~PIRATORy P~OTECTI~, RE~PXRATDI~y PROTECTZOll UgUALLY ['~OT HE~DE~ UNI.ES9 PRODUCT 1'9. tlEATED ~ HI':BTED. I'F COlII'AICT ZS Llqa-AVOZI~AE3LEi. HEA.q ~'UPEI~VI(XJ-q pI~DTECi~rVE OEAII'. LAUIIDER ~DILED CLOTItE~. A T ZOH (3I[~'~DISPOSAL PROCEDURES qUATZC ~9P[LL, LSA~ OR RELEASERS' CO~A[N OPZ~L. ~V[SE EPAI ~ATE AGE)~y ZF Re~ZRED. AD~RO ~t /IIERT ~TERZAL. ~~STE ~ ZSPOaA~~ FOLLOH FEDERAL, STATE ~ LOCAL aE~UTZ~, DO I~T true! TO DRAI~ 5t~fl SEHER, C~RACT 10 AUTII~/ZED 9~5PEC~AL PEECAUT EONS ~SECTZON' ZO~I:I~PRECAUTIONARY LABEL t~ ,M]DZTIOt~L PRECAUT1'U2~S ANt] LAEIEL3 APPL[CAEILE) . ~ BtdS~ INC. ' ' AIRCO Safety Data S beet Airco, Division of the BOC Group, Inc. 575 Mountain Avenue Murray Hill, NJ 0?974 Emergency Contact: CHEMTR~C Emergency Phone Number: (800)424-9300 P. 0~ Page: 1 Rev. Date 08/03/89 Telephone: (201)464-8100 SECTION Ii - IDeNTIFICATiON Product: OXYGEN CAS Number: 7782-44-7 Product Code: MSDS CODE G-1 Chemical Family: Oxidizer Chemical Formula: 02 ~ny~s: G-1 NFPA Hazard Rating - Health: 3 High - Fire: 0 Negligi.b~.e - Reactivity: 0 Negligible - Special: Oxy SECTION %2 - CHEMICAL COMPONENTS comPonen~: OXYGEN ~ N~l.ber: 77g~-44-7 Percent of Mixture: 99.6000 to 100.0000 SECTION ~3 - PHYSICAL DATA Boiling Point: -297.~'F .- 182.9'C .Melting Point: - 361.8'F - 218.$'C Vapor Pressure: Above critical.temp. Specific Gravity: 1.11 (gas, air-1.0) Solubility (H20): Slightly soluble Appearance Colorless gas. FEB-2~-1996 BWS~ INC. Mater ia1 Safety Data S ~ SEN SECTION %3 - PHYBZ~tL DATA Continued... Odor Odorless. Flash Point: N/A LOwer Explosive Limit (%)~ N/A Upper Explosive Limit (%) N/A Fire and Explosion Hazards Electrical Classification: Norhhazar~ous Vigorously accelerates combustion. Extinguishing Media p,03. Rev. Date 08/03/S9 combustiSle ~ies of water (or the suitable ~xtinguishing agent for the material) for fires with oxygen ~s the oxidizer. =~ .iai Fire Fighting Instructions If possible, stop the flow of oxygen which i~ supporting the fire. Routes of Exposure - Inhalation igh concentratzons (greater than 75%) causes symptoms of hyperoxia w. hich in¢lu.~ed cramps, nausea( dizziness, hypother$.ia, ambyloDia, respiration difficulties, bradycardla, fainting spells amd convulsions capable .of leading to death. The property is that of hyPeroxia~which lea~s to pneumonia. concentrations between 25 an 75 percent present a risk of inflammation of ~rganio mat~er in the body. First Ai~ - Inhalation PROMPT MEDICAL ATTENTION IS MANDATORY IN ALLi CASES OF OVER~XPOSIrRE TO OXYGEN. RESCUZ PERSONNEL SHOULD BE EQUIPPED WIT}{ SELF-CONTAiNED BRF. ATHING ~EB-~5-199~ M!aterial .'. 11:~ B~S, INC. Safety Data P. ~4 Sheet Page: Rev. Date Aid - ~r~alat~Qn _ ' t d to an uncontaminate~ area and inhale fresh air. removal zrom ~he contaminated area is most important. Unconscious ,:~r~ons should-be moved to an uncontaminated a~ea, and if breathing has ~topped, administer artificial resuscitation aSd supplemental oxygen. ~rther treatment should be sympt=mattc end su~portzve. The physician should z~'informed ~hat ~he victim =ould be ex~erien¢ .rig h~peroxia. ' ._ ioU=eS of Exposure - Skin, :~ntact with liquid ~roduct may cause tissue Aid - Skin d~rm~! contact or frostbi~e~ Remov~ contaminated c!othina and flush :ffe~e~ a~as. wi~h 19~ewarm water. DO NOT US~ HOT WATER. A~physician should r-ne pa=~en~ promptly if ~he cryogenic "bur~" has resulted in blistering :f %he dermal surface or deep tissue freezing. ' - : :ZO~ #$ - EZPOSUI~E and EFFECTS - EYE8 ~outes of Exposure - Eyes lDntac~ wl~h liquid product may cause ~lssue f~eezing. · ~irst Aid - Eyes :aVer introduce ointment or oil into the eyes ~ithout medi=al advice! In :as~ of_freezing or cryogenic "burns" caused b~ rapidly evaporating liquid, ~O~NOT WASH ~ EYES WITH HOT OR EVEN TEPID WA~ER! Remove victim from the ~our¢? ~f ¢on~amina~ion. Open eyelids wide to, allow liquid to evaporate. If :ain ~s presen=, refer the victim to an opthalmologis: for :reatment and ~o!low up. If the victim cannot tolerate light, protect the eyes with a light ~andage. ~CTION #S - MISCELLANEOUS TOXICOLOGIC~tL INI~O~ATION t':arcinogen£city: NTP - No IARC- No OSHA - No , FEB-~3-1996 11:21 BWS~ INC. M · t e r i a i S a f e t y D a t a S hle.e t Stable 2on,ct wi~ all fl~le in=ompa~ible Materials .{1i fla~able materials. 'Eazardous ~ol~eriza=ion: Will Not Occur I Rev. Date | ' SECTION 97 - BPILL, L~AE, & DISPOSAL PROC~D~S ~teps to be Taken in The Event of Spills, Lea~s, or Releas~ ;~atio~ary customer site vessels should operate in accordance with the ~nanufacturer,s and Airco~s instruction. Do no~ attempt to repair, adjust or ~n any other way modify the o erati ~.malf~n¢~ton or othe P _on.of these_vessels. If there is '~ . _ r type Of operations pro~llem with the vessel, contact :ne close~t Airco location immediately. , Disposal Methods Dc not attempt to dispose of waste or unused ~antities. Return in the ~hipping container PROPERLY LABELED, WITH ANY ;VALVE OUTLET PLUGs OR CAPS SECURED AND VALVE PROTECTION CAP IN PLACE to ~irco for proper disposal. SARA Hazard Classes: Fire Hazard Sudden Release of Pressure Hazard ~E¢?ZON ~8 - SPECIAL PROTECTI~ M~.ASURES 'Senti lation ---------- · ~se local exhaust to prevent accumulation of .~lgh concentrations that zncrease the oxygen level in air to more Safe=y g~ggles or glasses plus a face shield. J FEB-23-1996 11:~1 BWS~ INC. Materiel Safety Data S~ee t P. 06 Page: 5 Rev. Date 08/03/89 Skin Protection ' ~oose fitting and insulated. Dther Protection ~a~e~y sAoes, safe~¥ shower. HARDLIN~ SECTION ~g ' SPECIAL PItECAUTIONB - ~TORA~ & ~torage & Handling Conditions Use only i~ Well-ven~ilated areas. Valve protection caps must remain in place i a!ve ?pt~tlpip?d to u~e point: Do not ~ovement. Use a pressure reducing regulator w~en connec~ :ressure <3000 ns'.% ~'~ ....... ~ ........ %n~ cylinder to lower nc i tease the dischar e r g ate of product from the cylinder. Use a check ?alve or trap in the discharge li~e to preven% hazardous back flow into the syste~. -' eot cylinders from mhv$ical :he'temperature where cylinders ~ =~ .-~-g ~y_~}ts. Do not allow .;hould be stored u~ri-h~ and ~i-I~E iri~i¥~Ylexceea }~ ~.(S4'C). C~linders cnocKe~ over. Fu~l and em t ¢ - g or bezng ~ · . P Y ylinders should be se re ate - .~n-f~r~t out".anvento~v s==+~ * ............. ] ..g- g .d: Use a first .~ O SMOKING 0 O N ,, ' ~,ora e area . ~ PE FIJuHES .s~gns ~n =ne' g Or use area There should be no Sources of ignition in the ' ~=orage or use area. ?or additional storage recommendations, consult Compressed Gas Association's ?amphle~s P-l, P-14, and safety bulletin SB-ll '{ever carry a compressed gas cylinder or a cohtainer of a gas in cryogenic i/quid form in an enclosed space such as a ca~ trunk, van or station wagon. A leak can result in a fire, explosion, asphyxiation or a toxic exposure. Compressed SE=TzON 910 - ~HIPPIN~ I~ORMATION ~=oper Shipping Name: Oxygen or Oxygen, ~azard Class: Nonflammable Gas ~OT Identification N%Lmber: UN1072. ~OT Shipping Label: Oxidizer FEB-23-1996 11:22 BWS, INC. ,- P.O? ~aterial Safety Data $~eet I ION Continued~.. 'R), Inconel R ~ys, ~rams ronz copper · ( ] and be~11i~. % e, silicon allo s :a~ket materials. ~_ ,~ ~ad and SilVer or le ' - y ' MOna1. :hack wi~h ~he supplier to verify ~or additional storage re=o~enda~ions, consu~ Compressed Gas Association,s D~en should not be used ns a ~zpment since this * .......... upe.f°r,compresmed a · . sels should ~t b ' ~ oxygen~se~ace., C ~ p nt .ases. Sh~oment of _e_~f~lled.except Dy ~alified ___=__ompre~sed gas .~ r or w~{ ~- .~ Y~mpre~se~ gas vessel whic~ ~_~=~=~rs or compressed ' DIGC~R O~ ~XP~SSED~ IMPLIED W~I~ .lthough reasonable care has - ~ ~ u~ ~e info,atica =ont-~-=~ ~=-a-~-ns a~ to ~e accuramy or -ntended ~u~oses ~r ~r the conse~ences of its use. Each i ' ' :ake a dete~i~ation as to the suitability :~i~lar ~u~ose(s). ~ of~the ~nf~at~on ~r ~heir Material Safety Data Sh t MATERIAL O~DER~.D FOR: FOB EL SEG ~F WRH~E '~l HIGH S?RkET Thi~ Naterial Safety Data Sheet cpn:ai)%s environmental, health and you meet co~unlty rlght-~o-knmw/emerpency response re~tin~ ia~rpora~ed in your MSDS. D{scard any pr~vi~ edition of this with useful hazard warnings and health evalu~tionm and your compliance with local, State and Federalregulat'icns. 1. PRODUCT IDFD~TIFICATION C~E~RON Automatic Tra~smis$io~ Fluid (DEXRD~ I~) ~" - A ~ZJ~,~ WAPJ4ING IS NOT ~QUI~ FOR O~ ~Z~ ~I~TION STm~D~ (29 CFR 19Z0.!2DO) C~VRON PRODUCT }~ER(S): PRODUCT I~FO~TION: Revision Number: NDA - NO Data Available )~A - Not Applicablm - ~o firs~ aid Procedures are re~ired. ~ a p e~aut~on,, wash skin ': thoroughly wi~b soap and voter. R~ovu and ~ah c°nt~ina=~.clothing..' ... . Since thi~ material is ~ot expected to be an i~mediate inhhlation problem,' l NGE~T I ON a advi'ce. Consult medical or milk to drink ~n~ t~lephone ~or medical .' e~Vice canno~ ~ o~taln~d, ~hen take ~he permon and prodhct container to the neare=t m-dtcal emergency ~re=~mcnt center or hospiLal. This substance is nuL ~xpeu:~d to cause Pr~lonped or significant eye irritation.. This hazard evaluation is based 'on the data' from. similar materials. SKIN I~ITATION: This s~stance is not expected to cause or~ irritation. This .... ~eu o~ sipn!flcant ski materials hazard evaluation is based on data n - from similar n~ TOXICI~: skin This hazar¢ 'eValuati~n is based un data ~rom ~tmilar materi~lm. The systemic toxicity of this substan¢~ has not been de,ermined. it should be Practically non-toxic to internal organs !f inhaled. This hazard evaluation is ~sed on data from ~imilar match,aim. The ~YS%emic toxicity of %bls substance has nat been d~te~ined. it ~hould be practically non-toxic to internal orgtus if swallowed. This hazard evaluatian is based on data from similar t~O °d ~ PROT~CTIOH: ' No sp-c{al eye Pro%ection ~- usually SKIN PROTECTION: ~ necessary. No Special ~kin protection is usual~v frequently repeated skin contact w:;~ necessary. Avoid proion~e~ -- ' Revision Number: ~2 Revision Date: 07/D3/~ ~D$ Ntll~bcr: 000021 NDA - Ho Data Av~il~le a - NOt lpplic~i~ "i ',..:" '.,.'i ' . u..i '-~' ,~: .::?i..,:..:.~,... ,. -.:2 ....... -~. · - . · -. ...... ,.. .. : .,.' · ~~ 'z~t~ti~''~';~'?'~,C~O~:-:~;,:'.'?~:.:~;;i~'',;,~:::¢/~--~'~'.,~ .' ':~'.: .~ '.;"..:...t~:::...:.~.,,.: ,...'. ~;%.,.....,.. ~. . ' ., ninimtZea br ~earing.prO~ec~iVe.,C~.~' '. '.'. ·",:-'-.:"',,:.rage 30~ & ,.". ~' '.' ." . · · -~ ~rotectjon.l$ ~o~ally re~Jred ~wev ' ;:: -~o~en~e~ ~., ...... "~ re~Jred, ex~,~, ~an~ar~, the ~e of an approved' respirator Ute adequate Ventilation tO keep the airborne . material ~i~v the reco~nded exposure ~tanda~. ?..-'..'::.%..'./b.- ...-' ......... ..... :' . F:,AsZ{ PoINT~ (COC) 160C AUTOIGN2TZON: ~T~A EXT2NGUlSHING F~ED I A: f320F) Min. CO~, Dry Chemical, Alcohol Foam an~ Water Fog. ' i ' '. obta{ne~ 1/si-- -~ ...... g - , ~ztreme-~) The~ "~ ~'~ guzoei~es or ~ ~*~-~ . .~ e values are Na:ional ~ire Protection rub.~a,=u evazuatzon= prepared by the Association or, ff applicable, the Paint and Coating A~$ociation~ and do no~ neceszm¥ily reflect the hazard evaluation of the Chevron Enviroramenta! ~ealth Center. Rea~ the entire document and label before using th~$ Product. F~R~ F~G~T~NG PROCEDURES: fire space without Proper Protective e~ment, t~cluding self-contained };o~al =ombustion fo~ caren dioxide, ws%er vapor and may produce of ~ulfur, nitrogen and phosphorous~ IncomPlete cobb%ion can produce caren monoxide. :. 6- STOOGE, ~LING, ~ ~IVIT~ - - ~~S DB~osITio~ PROUU~; ' ' ~A. ST~ILITF: stable. ~Z~5 POL~IZATIO~: P°l~erlzation viii n~t o~cur. I)I~ATIBILIT~: May react vi~h ~ren~ oxidizing agents, such au :hlorates, nitrates, Deroxldes, etc. no ~oT we!d, heat or drill container. Residue m~y ignite ~ith explo~ive violence if heated sufficiently. CALTIONI Do not ~e PresSure to empty dr~ Or explosion may NDA - No Data Available ~A ''~ot-Applicable F'EB.-21-96 WED 10: 1 ? ' . .=.:5~&~.. ..... ._.. (~I No~OI p~n~ ~°:ss~ue~~ 'n~o~ '~~ . SOLU~IL!~ Solubi~drocarb~n . ~P~CE: Red ~iqui. d. so~ents; iasot~ ~OIL~NG POINT: ~A ...' MELTING POINt: KA ~VA~o~,Ti ON: NA SP~C%F%C G~VITy: 0.89 "~ 15.6/~5i6C P~RCDS~ VOLATILE (VOL~ · · ?: '.. ViSCOSITy: 3~.3 CSt 8. SPILL iRESPORSp, A/TD DISPOSAL Th~s material is no~ expected to Present any env~ronmeata/ Problems. other: ...... than those associated vith oil stop the source o£ t ' _ _ ' ' to ~r~ve~t fu~z~g ~eca~tzo~, ia Protea[~a~ uP. re!eas.s as soon a~ "": :?':": ' clean u~ ...... e:.~o,,tam~nation off so~ e_~_~u~pmen:. Conta~ ' - ' '" - r - =u~aov Prescribed ....... u~ aha appropriate, re .... Place contaminated materials i~ material. ' al or health authorities 7__ 5~o.~..Contict local a ~ '~ ~prove~ disDos, al of thi= All ~he components of this m8~erial ~ on the Toxic Sub=tance~ Cqn=rol A~t Chemical Substances Inventory. This substance is subject to the ~ ~ - Co~-munit¥ Right-to-~now P-OV,S~O~S of the AC~. Specific chem~ca! Pennsylvania WOrker and under the Provis~oD£ of 3~ PennSylvania statuteidentities are trade secret Section ~ased u.Don information reviewed to dat, th{s o- : , . a Available NA . ~ -MSDS Number- - Not Applicable - PEB-21 98 10:17 '' ~ ........... '~uns are g~v~_n ~o ~l~ov.for the various ranges the componen~ PreSent in the ~'ho!'e Pr~uct and may not e~al LZM/TS ~" 100.0 % C-2'{EV'RO~T Automati= Transmission CONTAINING > 85.0 % LUBRICATING BASE OIL The BAS~ OIL may be a'mixture of any of the £oltowinu: CAS 647t1884, ~%_T. 64741895,CAs 6474~9640CA$ 64741975,CAS 647420t~,CA$ 6474252S, ..... CAS 64742536,CAS 647~25~7,CAS 647~2627,CA$' ~47~2650,CAS 726~837. : TLr - Threshold L~mlt Value ST~b - Short-te~m ExpOsure Limit RQ ' ReD°treble Quantity CC ' dhevron C~e~mical company 10~ REGULAToR]~ IArFORKATIO)~ PEL - Permissible TPQ - Threshold FEDERAL DOT DOT HAZARD CLASS: NOT A,OPLiCA~LE DOT ID~NTIFICATIONNu~BER~ NOT ~DPL!Ck~LE SA~A 311 CATEGORiEs: 1. I.%mediate (Acu%e) Health ReactiVity Hazard; NO WH~ A COMPoHENT OF ~"EIS IiATE~iIAL I$ 5~0~ IN TRXS SE~ON, T~ ~G~TORy L~T ON ~ IT ~PE~S ~S ~I~TED. ~GU~ToRY LISTS: 2. Delayed (Chroni~) Health Effects; R0 3. · Fire Hazard; NO 4. Suddea Release of Pressure Mazard; NO 5. 03=RTP' Carcinogen 06=IARc Stoup 1 09=SARA 302/304 15=ACGIH STEL : 21=T$CA S~CT 4' 2~=TSCA SECT 12 EXPORT 27=TSCA SECT ~ 04-CA Prop. 65 D?=IARC Group 2~ 0~=MI 405 10=PA RTK 08=ZARC Group 2B 14~ACG/E TLV 16~ACGIH Calculated TLV !9=Chevron TLr ~0=EDA Carcinogen 22~Ts~ S~ 5 ~ 23=TS~ SECT S RULE 2S=TSCA SECT 8A CAiR kS=Canadian W%~iS 25=TSCA SECT SD ~PORT P, 05/06 Revisioa Number: &2 Revision Date: 07/03/8~ "'""'--'---' MSDS NUmber: ~ ~A NO Data Available ~A Not APPlicable - 000021 . / C~r~VRON AUgo,atic Trans~issi0n Fluid (DSXRON II) P, 06/06 11. PRODUCT TOXICOLOGY DATA gYE IR~ITA? ION: NDA. The hazard --valuation vas b=sed on data from similar materials. SKill IRRITATION: ~:DA. The hazard evaluation was base~ on data from ~imilar materials, D~L TOXICI~; ~;OA. . The hazar~ eva!uatimn ~as based u~ data from :similar materials. F~E S P I ~TORY / l }~AT I ON: NDA. The hazard evaluation was based on data from similar materlals. ~;DA. The hazard evaluation ~as based on data from similar ~atar/als. 12, ADDITIONAL }tEALT~{ DATA ADDITIONAL HTJLSTH DATA COMI~KNT: This produat contains petrole=~ base oils which may be refined by various 9ro~esses including sever9 solvent extraction, severe h~drocrack~ng, or severe hydrot~eating. None of the ~ils require a cancer warning under the OsHA ~aza~d Com,~unication standard (29 cFR 1910.IZ00). These oils have not been listed ~n the National Toxicology Progr~ (NTP) Annual Report nor have they been classified by the International Agency for Research o~ Cancer (IARC) as; carcinogenic to humans (Group !), probably carcinogenic to h~T, ans (G~-OUp 2A), or possibly carcinogenic tO humans (Group 2~), believed to be correct as o£ the ~ate hereo£. Siuce the iniormation ~etermin~tioa of the suitability o[ ~he material ~or his pmrtic~ar purpose. Number: 13 R~visioB Date: 07/03/89 MSD$ N,,~ber: 00~021 NDA - No Data Available NA ~ Not Applica]~le -;':'??-;-'¥74':'.-?.~"~<'-- ";?'"~"-" ;" ;.::'~ ~-'~-~..,; ' ":'~ CiTRiC ACID -SOLUTION 50~ .. .':-,... -.,. -; ,- ?.~ .... ,~;~¢.%~¢¢~.,~;: ~.,. ,,~., .. ,; .;.,-..,..-,~ .~ , - .~ - . ..~..., .~- :-r, : . . . ."~ . ~-..7: ( ~- .,-,-.,:¥.-",; , .,.<r?{g '~,:~.,.;%.:;-5.... -,"::~ ~ ' · ..",';- '- . . '- . '7:- "~ '%.",'.'-, ,. ~ -.-'- .... . ; .,'.h-', -_.", ;,..-,"r ''.'~ 'z-,J-': .- ,--'. ~;:(':;L~f.*¥:'~c.*,cC f-J-.%'7-'; f2' '- ' ;- '~,* .... , ..... .:- ~. J - ., - . . .z. .3. -;2%._ ' ' ' '.';' - '' t' · , -. " ' :.'. --;,.~,, ,. / -.-....,'--*.; .... .7. ....... , ................... , . F~BILiTv ; . ""¢/'777 ;~ ';" ?'. ':~ "*- '. "":';': ';;t:.,::,. ~'.~,.~':~',,'";, "'- , . - -.,-.' "~':"J.';/ ' -'''''~''; ' ? · ' ......t, --,. -- .- , .... ,,., . . ,,,,*;_: :~.0 :v.',, ¢,4'. .............. ~~_~____~ O~M%C&g ............ Ci~rlC acid ~olutlon -,.. 'PRODUC~ USg .... . ........ Scale Dispersan~ SU~L~ER,. , .......... aMBER~~CAL ADDRESS ......................... . ,' INC. ~330 TURCON AVENUE BAKERSFIELD CA. 93308- ~MERSENCY TELEPHONE ~BER ...... (805) 325-~072 ' PREP~D BY ..................... AMBER CHEMZCAL, INC. (805) 325-2072 DATE DR~P~ED ................... January 1990 Supersedes: March 1988 ~%3ARDOU$ COMPONENTS CAS # PERCENT TLV'(UN!TS) OSHA PEL No hazardous ing~e~ten~ DETERMINATION .......... . ......... UPPER.EXPLOSION LIMIT(% BY VOL). LOWER EXPLOS%ON LI~IT(% ~¥ VOL). AUTO-IGNITION TEMPERATURE ....... EXTINGUISHING MEDIA ............. N,A, Aqueous solution N,A, N,A, N,A. Material does no~ burn. Use appropria~.e media SPECIAL FIR~ FIGHTING PROCEDURES None EXPLOSION DATA .................. A~ueous HAZARDOUS surrounding solutions of cinric acid can, if in c~ntact with reactiva menals, form hydrogen which may form explosive ~i×tures~ COMBUSTION PRODUCTS.,, Wone SECTION ~ - ~F__-~LT~ RAZARD DATA .......... PRI~V~R¥ ROUTES OF ENTR~ ......... SKIN CONTACT ..... ~ ......... EYE CONTACT 02/06/z990 Established N,A, = ~ou Applic~b!e INCOMPATIBLE MATERIALS .......... Caustics and reactive metal~ SUch as iron, zinc, aluminum. I/AZARDOU$ POLYMERIZATION ........ DOES NOT POLYMERIzE HAZARDous DECOMPO$ITZON PRODUCTS NoDe R~SPtRATORF PROTECTioN PROTECTIVE GLOVES E¥~ PROTECTION ............... OTHER PROTECTIVE EQUIPMENT ...... VENTILATION ....... The use of mechanical ventilation is recommended Whenever ~his' Product is used in a confi~ed space. Where engineering controls are not feasible, assure use is in an area where there is natural air movement. No~ Required Rubber or Neoprene Eyewash bottles or other rinsing equipment should be easily accessible. SECTION IX - HANDLING PRECAUTIONS N.E.= Not Establimhed N.A.= Not Applicable "'0 ~at~'rials' that':ar'o' no'~'ally ~table aha '~i'!ltnot burn"uni"~ss hea~ed-' '' Dan~ert' E~loSiV~'"~ater'ial at room 4 Danger: ~ay ~e explo~ivo if shocked or hea~ed un~er confinement Caution: May ~eact tf heated or mixed wi%h wa~er but not violently 0 Stablm:' Not rea~giv~ when mixed with water SEE AMBER CHEMICAL pr~du~g label or Soction'VlI~ The info~ation oontaine4 h~in is based on da~a considered accurate. resU~ ~o ~e obtain~ ~ro~ the use thereof. Vendor assumes no responsibility' for injury to V~m o~ third per~ns proximately caused by the material if' reasonable safety procedures are not a~ered to as s~iPulated in the da~a ' sheet. Additionally, v~ndo~ a~sum~s no responsibility for injury ~o vend,e or third persons 9~oX.imately ~aUsed by abnormal use of the ma%erial even if in his use of the material. 03/0~/1~90 ~.E.~ N~ Established N.A.= Not Applicable From; David II/I, Helwig To: Tom Henry Date: 2/21t96 Time: 10:37:49 Page 2 of 2 SENT"BY:DIVERSEY CORP.' ; 6-21-9.5 ; 12:2,5 ; R&D--, "' David 5L Holwi:_.;# 2/ 0 ..... ~. ~tLT. R.E_C 1 - ~ O O - ,~': .... ~ L_[~VO_.N_Z_A, HICHIGAN qB150 I PREP^,ED By, I I~ ON 01/17/9~ REFERENCE ABBREVIATIONS .... ~-CFILI)IQ..-MP-M~XlMIIM IqEAK,,.N/A,NOT APPLID, AI~I F..N~K,N01KNOWH....I,.POlt: U rIAL P£L,P£(IM~RIRI F EXPO.qIIR£ I IMI? COM~N NA~E U~ED ON LABEL .L ~ ~ ~ ~ ~__E L.O 0 ~~ ............. c oi~ 0 2 ~ ~ 2 ..... OH[M~FAMILY L['~U[D FLOOR CLEANER. _ ................................................... POTRSSZUH HYDROXIDE (1~10-58--5) TLr C 2; PEL C ~ --- ........ ~-.~*~-~ .............. · ........ ~.~,~ .............. ...~ .......... ,,,..,,-.. ~__ ~;,~. ......... A~rE~nR.eEao~ ...... ~.~_~.~_._[ Z__~U I~.L.._g~.EE.N ,,COL~.~.L.~J_LD O.~.~..~ ............................. FL,ASH FLAME I I AMMAIII,[ LIMll~ i, OWF[I UPPER Alii(} mm~ NONE "F ~xmm~o. N/A ~.. ,. n,. .wou.~ NONE NONE ~u..,n..,.~ N/A ~m~.~..m~ '~0'~ ~"~R ;' DRY"' C~ ~ H ~ ~A L ~ r~.~.mo gEA~-TURRO~'T'" ~EAR"'ARD"'~E LF Cfl~TA~HED ~REAT'R'~R~"' APPARA'TU~'"'~ N "'F'~RE .... ~I'ECIAL PflOCEDIIRF~ A R E A · UNUSUAL I-IHE AUI'J EXPLOSlOg H AZARO'.~ ~RE ........................................................... GIQHG AND RYMPTOM$ OF OVER~XPO'~3URK ~. 0 H Re}NIl= TO RESPIRATORY TRACT. SAME AS ACUTE AGGRAVATED BY L.TED (~ ARCINOQ"N " I~1~ ................................... EMERGENCY AND FIRST AID PROCEDURES 1. INHALATION REMOV~ TO FRESH AIR 2. EYES FLUSH THOROUGHLY WITtt FRESH WATER, FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. 3. SKIN FLUSH WiTH ~FRESH WATER, WASH WITH SOAP AND WATER REMOVE CONTAMINATED CLOTtlES AND SHOES 4, INGESTION GIVE WATER, I:]0 NOT INDUCE VOHI'rING, GET HEDICAL ATTENT]ON. NEVER CIV~ ANYTUIN~ BY MOUTH TO AN UNCONSCIOUS PERSON, "ER"InATO~PflOTE~T~N ~F' PE[/TLV HAY BE'E~C~D, USE A HIOSlt"AP~OVED HIGH EFFICIENCYJ....nOAbTlrfl/aTEv . ~ F r~ TC R~ V~..,A,..LocnL NO ~"°'.','~-'. 'f ;""~' FROM FREEZING. DO HOT PRESSURE TO EHPTY CONTAINER. PRE~AU~ON~ p ~r.-..l~uA~fl,~ . FLUSH" SMALL AMOUNTS TO DRAIN~ COI..I. ECT AND RETURN LARGE ~MO_U~Ts I~ USE UNT[L LESS THAN ~ INCH REMAINg IN .CO~TAIHEa. ~HPTY RONTAINER o. ' TR~PLE RINSE WITtt WATER, DISPOSE TO INDUSTRIAl OR"SANIT~RY SEWER "REMOVE OR DEFACE t, ABEL BEFORE ~EI..I.[NG CONTAINER OR DISPOSAL ·' ~'ALL CHEMICALS ARE ON TSCA INVENTORY. : ' I ;::;',;';;:;;",,z ........ T -..---:----.:- ..~i~ ~ ~ii 1,,,,,~. ,,,,,,,,, i~-'--j ' :?':"~" -NONE ION: I ' ' ' ' ' / / POTASSIUM HYDROXIDE -. ~CAS POLY(0XY-1,2-ETHANEDIYL)sALPHA,-(NOHYLPHENYL)-OMEGA~HYDROXY - '.CAS. ~9016-45-9 WATER - CAS t7752-18=5 4a.TrmaL sirr. Ty DATA ATTENTIONi; Plant' 5iaaagerlSafety Dlr~tor: Thir MSDS su~m~es ri prior ~m sh~ re~iv~ for ~is desi~; produce. We urg~ you to study i: eare~lly, ~is is provided with ~c~ container as our way of communicating Health, Safety and Environ. memal Prot~::~on ~n~omdon to our customers, ~is info.orion is provided [o e~are safe handlin~ an~ storage our products i~accor~nee wi~ OSHA H~ard Co~fi~icatton d~ 29 C~ 1910.12ffi. ~ infomtion mnmin~ in ~is MSDS bc passed on to all employeas ia your tim that handle and/or become invotvca in the imptemenmion or control of operations involving use of ~e ~r~uct. We strongly urge you to fo~d chis MSD$ ~o all that havc a net:d ;o know th, infomation confined hercinl Pneumatic Pr~ucts PlO. 43U FEB. E3.1~5 1: 43PM ': HANDLING CAUTIONS ygnetr.~t, smn.,..~e ~ ',, =~s=,e~.'e~atmnc~,on or equipment can prooel ~ad with enough vel ;, ~rocecures. sure that bo~ the trans,er ~3 ~tem and rec:~vmg vessels ~m properly ~rou~de~ ~n/ln~ ~, .~. OC,[y [0 .............. tanaka ope~fing SPECIAL CAUTION When disposing of used desiccant, material must be handled with special precautions. Desiccant is an adsorbent material. Following contact with typical petrochemicals or gases, the' combination of desiccant and retained material can be hazardous, toxic and/or flammable. It is highly recommended that all used dealt:ant be analyzed to determine conten~ before disposal. Appropriate care and procedures ~hould be followed in handling and storage of used materials. Once content is determined, containers should be properly labeled and disposed of in accordance with Federal, State and Local Regulations. ADDITIONAL HEALTH F~AZARDS INFO~MA'T!ON Che;mical substance components have been rei:Ormd C0 ~he EPA Office of Toxic Substanc.~s in accordance with the quirernenrs of th~ Toxic Substances Con,roi .kef (Tide -a0 CFR l~arr 710). Tha! reportable chemical substances in :his product are regulated by the OSHA Hazare Communication $~andard (29 CFR I910.1200) solety because they are [isred by ACGIH. However, they do not fit any of the five proposed h~ard under:Sections 311 and 312 of SARA. For purposes of SARA Iii re~ortiag, this sub~tance eont.qns no ingredients listed on the Ex:remely Hazardous, cERCLA, or Se{:tion 313 Lists. D.O.T. Shipping Name, Hazard Class, I.D, No, (if applicable). Not Regulated · CanaCian TDG Hazard Class & PIN -- Not Regulated. The /nformasi'on ~omalne:t herein is baaed u~n d~,a con-" ~r ~¢~acy 0t ~he informafio~ eon,, --~ ~---: ..... .,m~r~d ~e? and a~ur~e HnWCVer, Pne a ' , ~,, ..... 'S ~e[~euseanflcond:ons~fu:eof hsi omar nnndrn .... a~?c~se~er:oL Th~slnformadon~ ~,v...~.~,., ..... 7 P..e~ ~r,m~,ed) as othe~ccu ~a~e limilinl[ w~rr~nlics ~nd r~m;m-."~J~~ ~?~ra ~e~n~. The ma~eria described hem n s*-la ~.h, 2:72.__'"]'.' ~" ~vn~ro~ m Pneumatic Products Cmn P~eumatic Pm~3~,[ r MEMSCO IMC Ma!terial Safety.Data Sheet May b~ used to i~omply w~th OSHA's Hazard Communication 5tan~hard, 29 CFR 1910.1200. Stuadard mu~t be ¢onzulted l'or .q~citle requirements. NO. 45D P. DESICCANT DE4 (~,/~*, Dia,} .%CTIVAi'rglj ALUMINA DE-60 (~," Dla;) D~2S (g" Dia.) DE-38 (~" Dia.) DE-S1 (~" Dia.) Pneumati~ Products Coq=oration Supplier'~ PNEUMATIC PRODUCIS CORPORATION Eme~_~ncy Telephone No. ' 904-2~7-I220 ~647 $.W. 40th AVENUE ;OCALA, FLOR/DA 32674 Inform,don 904-237-1.220 SECTION I - IDENTITY Common Nam,:. (used on label) (Tmd~ Nam, & Synonym~) HARRY M. ,SHAWL Prel:ared MAR. 140'1990 Cas ACTIVATED ALUMINA L344-28-1 Chemical Chemical Name ALUMINA Family ALUMINUM OXIDE Formula .... Ai:O~ (g0-9f~), Inorganic Promoc'.m S]~CTiON 2 .: HAZARDOUS INGREDIENTS ............. - .... Prin¢ioal ~'Is.zarC~us Componam(s) (eh,mical ~ =ommoa ,ama[s]) " ','7o Thr~hcid Limit Value (un{~) Aluminum Oxide (AI~O.~) · ' 90-95% Dust: 1Om[./m~ (ACGH-I TLV) SECTION .3; PHYSICAL & CHEMICAL CHARACTERISTICS (Fire & Explosion 'Data) Boiling Specific Val~e . . Point N/A Gravity (H~O = 1) 32 Pre,sure (mm Rg) N/A Pete,ut Volatile Vapor lival:oration Race by Volum, (%) ? N / A' D~nsity (Air =- l) N / A ($oli~t) (H~.O _- 1) N / A ,.qolubili~y . In W~ter !nS01ubl= R~¢tlvffy in wa~er Generates ~t App~mnce ; ' ~d O~r Whit~ be~ds - odoHess , Bulk Densffv = 45-52 Fish Flammable Limits Lower U~per ~tinguishcr Auto-Ignition ~int N / A in Air % ~ %lume N / A N A M~ia N / .A %mpemnc= N / A $~cial Fir= F~gh{ing Froeedum~ N / A Unusual Fire and gxolosion H~rcs None/Non-Flammable · Form No. MCP.0906 Form Ca[. No. FEB, ~3.19~6~-. l: 44PI~L' MENSCO IHC __ SECTION! 4 - PHYSICAL flA. ZARDS' ~ Conditions to Avoid None'Known ~-n-~°mpatibil ty H~o~ ' May Occur ~ Cou~ifions polymeflzati~n ~ili Not O~cur ~ to Avoid Non~ Known SECTION 5 - I-IEALT~I I-~AZARDS Limit Value TWA: 10 m§/m~ ct' total dust or $ ms/m: res!;ir~l;l: dust, Symptoms of Ex~osur~ None Known 2. Chronic A very rare ,%roses o.f ~e Jun~f~[lowing prqlong:d and heavy inhalation ex, sure aoov~ me t ax. Overexposure None Medical Cor~ditions .G~nerally Aggravmd ~y gx¢oaure Dus~ may cff:ct any condition of tha raspirato~ tract. or Potential Carelnog~n Program No ~ Monographs No ~ N~ ~ OSHA p~mis~ible ACGIE Threshold 0t~er Ex~ur~ Emer~ency First Aid procedures 1. Inhalation: Remove from area of ,x_p_o~ur~. Acim[nister oxyeen if hreathint ia difficult -'S~ak me,ica] attention. 4. Ingestion:. Induce vomltin~. Seek medical attention. S~CT[ON 6 - SPECIAL PROTECTION INFORMATION Re~pimto~ ?ro~ectlon (Sp6elfy Ty~e~ ~se a ~IOSS/~SHA approved dust r~s~ir~cor. ~cal Mechanical Special Other Vendlmlon Rccomm;nde~ Ex~aus~ Recommended (G~n~ral) R~eo~manded N f A Eye ' Gloves ' Recommen&d O;her Prof.:tiro Clothing or'~quipment Work Uniform recomm~nct~.. SECTION: 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions !o be Taken in HanclIing anti .Storage Stor~ in a cool dry place ~n tightly ¢[ose~ containers, Avoid direct or prolonged con.c; with eyes. Precautions .:,void br~thing dusts. Do Cot cat. drink of smoke {n the work area. Wash hands thorcuehly after handllne. Sm~s to ~ Taken in Ca~, Mamrial is ~Letea~ed ct Spilled Sweep or vacuum up immediately. Soilled material can b: sli~ve~. Wasle Dispcsal Methods Disoose of unused desiccant in accordance with Federal. State. and Local R8tulation.~. - ~ (805) 326-3979'. BUSINESS NAME OFFICIAL USE ONLY " -' INSTRUCTIONS; .. I-I Z DOU$ ¢mViSD. 1,,,181M£85 PLAM ^$ A I'IOL£ . ~IVlAY, 1 9 1909 HAL* ~.~.AT, DIv,' 2. 3. 4. To avoid further action, return this from within. 30 days of receipt. TYPE/PRINT ANSWERS IN.ENGLISH. Answer %he ques%ions be.low for ~he business as a whole· Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DAT~ A. BUSINESS NAME: Carnation Company B.' LOCATION '/ STREET ADDRESS: 7301 District Blvd, CITY :. Bakersfield ZIP: 93313 BUS.' PHONE: (805,) 398-3~00 SECTION 2: EMERGENCY NOTIFICATIONS' In case of an 'emergency involving the. release or threatened release, of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This wil.] notify your local fire department and the State Office of Emergency Services as required by law.. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAHE AND TITLE J. Nezu PH#. A. B. N. Shirvanian ~H# DURING BUS. HRS. AFTER BUS. HRS. (805) 664-1811 (~'805) 398-3530 PH# (818) 769-0727 (8057 398-3531 ' PH# (805) 664-8094 SECTION 3: B, C. O. E. LOCATION OF UTILITY SHUT-OFFS FOR BUS[NESS AS NATURAL GAS/pROpANE: Exterior: west end of building between engine room& break roon~ ELECTRICAL: Exterior: south west end of property - . WATER: Exterior: front of building/ north SPECIAL: Ammonia shut off switch location west wall/ outside engine room LOCK BOX: YES / NO IF YES, LOCATION: ~mmmm~ IF YES, DOES IT CONTAIN SITE.PLANS? 'YES /'"No MSDSS? YES / .NO .FLOOR PLANS? YES / NO KEYS? YES / NO .SECTION 4; PRIVATE· RESPONSE TEAM FOR BuSiNESS AS A WHOLE .. In the event of a minor emergency~ the following action will be initiated: 1. Notify the facility management or team c0ordinator. 2. Determine the incident condition. 3. Move employees to a safe area. '4. Take appropiate action to correct the incident, 5. Prepare incident follow-up report and investigation' and rePort to plant safety coordinator and L.A. Loss Control Office. SECTION 5: CA EMERG T F R Dr. Chri'stiansen and Memorial Hospital havebeen designated as' the medical consultants:' we are utilizing for all work related injuries. A. For work related injuries that occur'Monday thru Friday'between 8:00AM thru 5:00PM, Dr. Christiansen~s office handles each case and all other work related injuries and/or emergencies are referred to Memorial Hospital Emergency Room located at 420 34th Street. SECTION 6; EMPLOYEE TRAININg] The Safety Coordinator follows all cases until they are closed. EMPLOYERS ARE REQUIRED TO HAVE A TRAINING PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE SAFE HANDLING OF HAZARDOUS MATERIALS. A. NUMBER OF EMPLOYEES AT THIS FACILITY... Approx. 300 permanent employees B. -DO YOU HAVE 'MSDS (MATERIAL SAFETY DATA SHEETS) FoR EACH HAZARDOUS MATERIAL YOU HANDLE ? Yes C. GIVE A BRIEF SUHMARY OF YOUR HAZARDOUS MATERIALS TRAINING PROGRAM:---- The Carnation Ice Cream Plant has developed a program to educate employees about hazardous chemicais and to train them on how to handle these chemicals~safely. Our Hazardous Communication Program provides the 'following: 'i.) A list of hazardous materials. 2.) Labeling system. 3.) 'Employee education and training. 4.) Proper handling. 5. ) Emergency procedUres in the event '.of accidental exposure to hazardous materials. 6.) Spill incident reporting. 7. ) Location' and availability of our written SECTION '7: EXEMPTION REQUEST] Hazard'Communication..Program. 8.). Location of MSDS sheet: I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREHENTS OF CHAPTER 6.95 .OF THE CALIFORNIA HEALTH AND--SAFETY I CODE FOR THE FOLLOWING. REASONS: WE DO NOT HANDLE HAZARDOUS MATERIALS. WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TINE EXCEED THE MINIMUM REPORTING QUANTITIES. OTHERi(SPECIFY REASON) SECTION 8: CERTIFICATiO.~, I, Nori Shirvani~n , certify that the above information is accurate. I understand that this information will be used. to fulfill my firm's obligations under the new Ca]ifornia Health and Safety code on Hazardous Materials (Div. 20 ChaDter 6.95 Sec. 25500 Et Al.) and that inaccurate~~~tion co?stitut;s perjury. BAKERSFIELD CITY :FIRE DEPARTMENT' 2130 'G' STR==~ BAKERSFIELD, CA, ' ~' 933O1 (805) 326-3979 · BUSINESS NAME ZNSTRUCTION~ HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE FORM 3A 1. To avoid further action, this form 'mUst be returned by: 2. TYPE/PRINT YOUR ANSWERs IN ENGLISH. 3. AnsWer the quesl;ions below for THE ,FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible FACILITY UNIT # I _FACILITY UNIT NANE. , · Carnation Co n 1. All equipment used'to pump or transfer oils or chemicals is being inspected on a regular basis. ' 2. Under no circumstance is any product covered in this order to be transferred from tanker to storage or from Storage t'o equipment without a responsible' person in attendance at all times; 3. Personnel involved with handling Oils or. chemicals are instructed as to the proper procedures necessary to prevent as well as how to perform in an emergency. ~ 4. For proper clean up, if a spill should occur, review MSDS' section on Spill or Leak Procedures. T N · i P ' ' ' A. In plant noti~: .... w~ng people: reported · ~a~lon process Maintenance Engr. Nori Shirvanian UerryNezu Production Jeff Crandell Bob Snook ~ualit~ Mark Imsland ~EXt. 531 530 518. 551 577 .Section 2: Be Type of Spil% Ammonia Notification Cont. · Out of Plant Notification process! Acid/Caustic Bakersfield Public Works Dept.· Bakersfield Fire De'pt. Bakersfield Public Works Dept. BaKersfield Public~ Works Dept~ 326-3238 9ll 326-3238 326~3238 ~TION 3; HAZARDOUS MATERIALS FOR THIS UNIT ONLY Ae Does this Facility Unit cOntain Hazardous Materials?. If Yes, see B. If NO, continue with SECTION 4 Are any of the hazardous materials a bona fide Trade Secret? YES YES NO NO If NO, complete.a separate Hazardous materials inventory.' form marked: NON-TRADE SECRETS ONLY (white form #4A-1) If YES, complete a hazardous materials inventory form marked: TRADE SECRETS ONLY (Yellow form #4a-2) in addition to the non-trade.. · secret form. List only the trade secrets On form 4A-2. SECTION 4; SECTION 5: ~TION 6: A. PRIVATE FIRE PROTECTION LOCATION OF WATER SUPPLY FOR USE BY ENERGENCY RESPONDER~ See ,At.tached Drawing (fire hydrant)- ' 'LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY. NATURAL GAS/PROPANE: B. ELECTRICAL: C. WATER: O. SPECIAL: See Attached-Drawing (Key Plan) E ' LOCK BOX: YES ! NO IF YES, LOCATION: IF YES, 'SITE PLANS? FLOOR PLANS? YES / NO YES'/ NO MSDSs? KEYS? YES / NO YES / NO - 3B - Section 4: Private Fire Protection THe Fire Alarm System Consists. of six major zones,, which are the attached color coded print. TheMajor Fire Zones ~are: Dry Storage (green area)' Utilities (orange area) Mix ~reparati0n (pink area) Production (yellow area) Palletizing · (blue area) · Shipping -~AS/RS (blue area) The Fire Zones are independent from in the particular zones affected. located on each other and wilI only annunciate Section 5: Location of water supply for use (fire hydrant) by Emergency ReSponders, See attached drawing Section 6: Location of utility shut-offs at this unit only. A. Natural Gas/Propane B. Electrical C. Water D. Special See attached drawing: Key Plan Inspector,s Co~.ents):, BUSIXESS ~A~E-"--~ '~ FACILITY ~£: SITE DiAGRA~ 'DZ ,A ~ ]~ A~,,t FACILITy DiAGR~ -OFFICIAL ~SE ONLY- CALE: DATE:, ~tor' s Comments): $ ~ T~"~I~c ~ L I 'Ty D Z A(],RApi B'USI~'ESS ~'A.qE: -- ~ FACILITY ~AqE: ':--'--- SIT£'DIAGRA~ ~ACILIT¥ DIAGR~ .'KII¥.--PLAN,. -OFFICIAL L'S£ ONLy- Fire Alarm Evacuation Plan In event of fire or explosion: 1. Call the fire department (911).' 2. Explain calmly and clearly address and area, what is burning and the extent of the fire. 3. Call Facility/Utility Engr. Deptl 4. Save or help first those who need help. e Avoid panic. Evacuate the building through the emergency exits to the evacuation gathering point located in the front parking lot. 6. Start extinguishing the fire. Fire that is fought early can usually be extinguished. 7. If the fire cannot be extinguished, then close all doors and windows around the point of fire. 8. After the fire, investigate immediately the reaSons for the fire. 9. Team Coordinator to account for all employees working in the affected/all areas. I TE/FACI LI Ty FORM NORTH (CHECK ONE) SITE DIAGRAM / FACILITY DIAGR~ BAKERSFIELD I:IOSEDALE HIGHWAy DIST AD: Inspector's Comments): -OFFICIAL USE ONLY- I T£/F~CI LI T¥ FORM D I A'~ R.~%,M NORTH SCAL£: 9AT£: ' / FACILITY SITE DIAGRAM FLOOR: OF 'UNIT Z: 'OF F'AC IL I TY DIAGRAM FP-1 [~!$1RIC! BD;J;- £ YARD o \\\\\~ Inspectnr's Comments): -OFFICIAL CS£ ONLY- I .usz.£ss .AM£: Carnation Dairy LOCATION:__ 7~01 District Blvd CfTY, ZIP: m PHoN£ I: [~^r\ ~no 93313 CRT)' KER SFIEL D HAZARDOUS MATERI ALS INVENTORY' NON--TI~.ADE S ECREI'S OWN£R NA.£': Carnation C~pany .~.~ OF T~ FACILITY: XDORzss: 5045, Wilshire B%vd. CITY, ZIP~ ' 'T PHONE ~*: ._-. -"_~ ~ ~ 'I~ X ~OP~ COD~ I I .Il II ine ROom west end soul 1310-73-2 ~ ] 4 S S IyN Rem A~If Mit J~4| ~lds~ft I OyI bt bt Code MC M( Est Units an Sl~e I1M ~ STANDARD ]:HD. CLASS CODE DUN AND SRADSTREET NUMBER. 13 14 ' ' I~t~ti~ - ~ ~ous ~onia ~E-IO~ i ospon 0 3 ~odi~ Hydroxide 7.~ Potassi~ h droxide 8 f t/S 1 t/Ph s~te/~ ·Sur actan oven o ust _3.4 2-Butoxgethanol 2.5 S~i~ Hy~oxide ' ~'Mel ~ate Nitrate Borate Poi er 9 S~i~ Nitrite 1.2 Moly~%c Oxide 1.~ Po~ssi~ H droxide , Plant ng~neer~ng r~ - Physical aM ~lth #ezmt'd IChKk all that m~ly) C.A.S. I~ C~t l~ nome & c,..o~,. ~ c.l.s. room p.~. Jcl1 of~d HNJth (C~k mil fmc m~ly) C.i.S. ~ ~t ti ~ & C.A.S. "- - 111-76-2 ~~-l--~~~oom (C~k oil [Mt mMJy) C.A.S. ~ ~t Il b i ~-' ~-, ' - 7G~7-~'~ ..lib o~ ~,.,.. . 1313-27-5 ~--G~K, ~*~C~S m~ Nor1 Shi~anian Facile1 i~': ........ nni .......... ~ .-~r~--~ ~ Jerry Nezu I BUS[NESS NAME: LOCATION: CITY, ZZP:_ PHONE I: Carnation Dairy_ /3ol District mivd. Bakersfield, CA 93313 (805) S i ·C/TY o )t KER SFIEL D HAZARDOUS MATin:RIALS ZNVI~:NTORY' .. NON-- T R AD g S E C R E TS OW. ER .AMs: Carnation Company .AHE Or T~ ADDRESS: 5045 wlis~lr'e ~lvd. STANDARD IND. CLASS CODE CZT¥; ZZe: Los Anmeles, CA . ouN AND BRADSTR~E? NUMBER Code Code Mt Mt Est Physical a~l Health ~zard IC~k ~11 that epat),) 3O 30 C.A.S. maa~e.~~ Fire #~zsed ~---~ h*~ttvlty Oeler~f ~---J Su,~m bl~ ~--J ImMlatl Boiler Room om 30 30 ' (Check ~1! that spply) ¢,4mpe~nt II ~ i C.A.S. ~lth ot ~ ~lth ~. · Boiler Room i._o_71. 1 ! ~)._'~ I Boiler Room !.Ea(;E,C, CaT,~CTS ~t Nori ShirVanian . ,iii'.' ............................... Sodium Sulfite Ammonium hydroxide solution / F~Sfilfuric acid Plant Engineering Mgr. 398-3530 I certify ~.eder lNe41ty of 1~ T~C.! ~ve.~rs~/11yemliind ~ Ii fNiltae .Ith t~ tnf~Ntim suhittd tn this ~ lll IttK~ ~Cl..~ t~t hs~ m ~ iat~ of t~e tMIvl~11 e~sible foe obtaining t~ in~tl~. I ~l)e~e tMc t~ su~ltt~ mloMt~ tlt~. Iccueite, ~ c~letl. BUS[NESS NAHE: LOCAT.~ON:~ CITY, ZEP:__ PHONE $: · CITY ,KERSFIELD , NoN.--TI~ADE S E'CRETS ., Carnation Dairy OWNER .a~£: Carnation C~pany .~.~ or ~ r~cr~zrY: 7301 District Bird, ADDRZSS: 5045 Wi 1.qb{ r~ g]vd. 9akers~;~ld ra 93313 ogre, zz~: ' T~o a.~ ~ STANDARD' IND. --¢~,~,S~- "~oDE DUN AND BRADSTR~'ET .NUMBE:R' I] Ii S~l~cone Sp~ay g~27 1,1,1 Trichleroethane 68476-86-8 '--~h Tech Ele ' ~ ' 97 Trichloro triflouroethane 3 ' ~r~ndioxide ~4 E~hylene Glycel Meno~thyl Ether~ ~:But 1 Ether of Pro lene G1 co 3 ~ ~ __ ~:ol 3 -~-- Plant Engineering ~r~ 398_3530 Ir~ Iy~ R~m avw'~ l~nu41 ~,~ I ~ Cst ~C ~t Est ~,ts m Site I~ ~ i ..... ~tlm ~ 3t~ In .... ~ ~n '~e ir~ ~lt ~c .m~D C.A.S. ~_ 7~A_A!_7 ~ ~c l! ~ & C.A.S. ,~ r--~ ~t 12 ~&C.A.S. ~ IC~k all tMt a~ly) C.A.S. ~ ~t I! ~ & C.4.S. ~ -- --" ~t ~ ~&C.A.S. ~ "- ' ~. ~01 W ~-~ ' ~ ~ ~ 76 k iii that !,f,G[~:, ~,,ac,s ,,~;; .N..ori...S_h. irVanian P,l[?~t/Utili.t~ _[~r.. Gip'tllic.t,m tread and si~n after co.pjfftlng all sectlona) and that beseg on ay inq~try of tho~e lallvt~ls r~sponstble CITY hKERSFIELD ~,..a A;.icul,~.. '7_~ S,,.d,.d 8u,~..,, }{AZARDoU$ MATP'-RI ALS I NVl~NTORY' I N O N -- q? }~ A D E S E C R E T S , ,,~, ~, 0~ 9 BOSZNZSS Na~: ~ation Dairy 0wN~a N..~: ~ation ~apny .aMs o~ r~ FACiLitY: LOCATION: · shire Blvd. ~T~:;Zip.~ · ,.,k,. u~scrlcc Dive. ADDRESS: 3043 Wi/shire Blvd. STANDARD ZND.--C-~S$. coDE -- Ro~F~I~ ~A qqql 2 .C~TY, ZI~:. Lo~_An~]~__CA DUN AND BRADSTRgET NUMBER N M "440 ' . - 766~_8~_2 -~ · r-~ _ .~t 12 ~&C.A.S. ~ ' ' ,,. ~lth o~ P~ ~th 7697-37-2 ' , ........ ~ - ~ s c.~.s. ~ Discontinue ~-19'89 96 Gal 5-01, 89 ................................. ....... ---- --- ~ Klenz Solv P-103' · ~ ~ , ~ S~i~ D~ecyl~nzenesulfonate (C~k ,11 ,~, ,~ly) ' ~, tt ~ s c.A.s. ~. Nonylp~nol Ethoxylate ' 90~6-45-9 ' ' H~lth of Pr~urt Heilth .a ..... ~.~.~a~sn Fa~i~i~/Uti~i~ 39S-353~ ,, 3errw ~ezu P~'~n~ En~i~eeri~ ~39~-3530 sign coJpi~.t'lni[ all sections) .. · . .- ~li'S/~ .......... ~ ....... 7----~---. . · CITY oj i' KERSFIELD· HAZARDOUS MATERI ALS BUS[N£SS.HAM£: LOCAT~ON:~ Carnation Dairy 7301 District ~ivd'. R~k~r~field~ CA 93313 cITY. ziP: 'NON-- T R'.AD E OWN£R ,AMm: ,Carnation Company ADDRESS: 304 SECRETs ..CITY,' ZIP:__ PnO.Z ,:- NAME OF T~'~ FACILITY: p,g, 5 of 9 ~u~J w~l~[llre DIVQ. STANDARD IND. CLASS CODE [.o,~ An~.]o.~. CA DUN AND BRADSTREET, NUMBE~ ~ ~~ -- ~rinci~~ ~ ~-10~ _ ~," ~ ~ c.~.~. ~ Potassi~ HydroXide 1310-58-2 ~' "' ~ ~ c'~'~' ~ 3 ,Potassi~ Hy~chlorite . ~ , 3hosnhor~ 7664-38'2 . -' ' .. ...... ~, ~ ~ ~ c.~.~. ~ ' ,~ · .. ~ (~) Enforce 7778-66-7 ..~ P°tas'si~ Hy~chlorite~ . ~' '* . 1310-58-2 - /~ Potassi~ ~droxide · C~e C~e bt kC "Est *'~its m Site P~icil ~ H~lth ~za~ ' ' ~.l.l. ~ IC~k. 411 t~C 4~1y) . ~lth of P~e ~lth ~500 2000 :6,000 275 220. 2600' ' H~lth of Pmsu~ .~lth · · .......... '1 '~ HNIch Of Pr~sure He41ih ~c~s ,. Nori Shi~anian Facility/Utlilty "' ~ ". "~'7 ....... 7": ....................... "";--~7'"~ ......... ! c,,?f~, uedee IMe41ty.of,1e- ' ' - ' . t~t,!.lMve.*~eSef~dllye,aoifled tfld am fMiJiae ,lib t~ Jflf~Mti~ subitt~ In this ~ oll 'Ott~ ~ts,'.~ t~t ~s~ ~.~ i~t~ of t~l I~ltt~Ts ~siblj "... " ' ' .. . ~;'S;~;~'---= ...... ~ ............ I BUS[NESS· NAME: LOCAT~ON:~ CETY, ZIP: PHONE Carnation Dairy /301 District Blvd. B~rsField. CA q~31,~ (80b) 39~-3500 ! ~ 3 4 S i C~e C~e Mt ~t Est CITY o '3A KERSFIELD HAZARDOUS MATERI ALS INVENTORY' NON--qfRADE . SECRETS. OWNER NAME: Carnation Company ADDRESS:., 5045 Wilshire Bird, CITY, ZIp:__~_3.Cu~_A~I~= gA I I II II OW. Cmt Site 25155-30-0 1344 -09 -8 P,. 6 of 9 NAME OF TJ~'~ FACTLTTY': STANDARD IND. CLASS CODE DUN AND BRADSTREET NUMBER Phy1ical and He,llth Rezard IChKk iii t~c ,~ly) ' C.A.I. i ~lth of Pm~ ~lth 400 200 400 P~ic~l ~ ~lth (c~k 411 t~t apply) C.A.S. ~ '~t I1' IMe i C.i.S. 9001-92-7 ~ d Nt~t~~te Sodium. Dodecylbenzenesulfonate ,Sodium Silicate 2- Propanol Sodium HydroXide t! Prole01ytiC EnZyme Discontinue. ,lalcohol CETY, PHONE C~rnmtion Dairy (~o5) ~98-~5o01 Iranl ' ly;~ Re, Avteiql ~eqJel AEdIVee Code Code Aec Ant [st Units CITY oJ~ .~ KER SFIEL D HAZARDOUS MATERI ALS I NV~-NTORy' ' ' NON--'tRADE S ECREq'S 0WN£R NAME: Carnation ComnaRy ADDRESS: - I I II II I; I OW Cmt C~t Cent U~ Lacatlm ~ t an Site lyre h~efl li~ Code .. Stae~d In Feciilt), iNby .,ge '7 of .-9. ,X~Z or Tg~t~ STANDARD [NO. CLASS CODE: DUN AND BRADSTREET NUMBER ICMck ~11 tt~c al~ly) C.A.$. ~ ~e4 Ith of Pr~s~4-e Nedlth Physical aM ~lth Hazard (C~q:k all that al~ly) C.A.S. ~ blth of ~ ~lth Phl'gical Ir~ ~lth'Haza~ ~ ' (C~ck.all t~t allll) .- C~.J.S. Ilair #eelth of Pr~s su,~ Health Coqxl.~t II Na.I i :.A.S. 67-56-1 107-98 -2 "-D-~ ' c.,.s. Gxecr~t II ~ & C.LS. ~ 532-82'1 CamenmC I] la,l. & ¢.i.S. ~ ~t Il 14.e & C.I.S. Ibee · Ca,,ument I? Nme & C.A.S. bMm- 141-78-6 - 16-7400 Video Ink Methyl Alcohol 1- Methoxy-2- Propanol ~1 Alcohol Solvent e 3 16-3200 Video~iet Clenni: Sol. Ethyl A. cetate l__l...... L.... L . I I ~'-t'0-~ ,c.,.,. ~ thyl Isobutyl Ketone ......................... I__L__A__I__/ - ~-' - ~7-5G-1 L ~Flee Hazard ~ a ~tivity [ ~ ~14M ~m Reline %--u iMlete C~t 12 ~ & C.A.S. ~ ._ NNIch of Pr~sure Health ~t 13 ~&C.J.S. ~ ~ ---.... . . .......... · . . · . . ~ ,,~~~ ..... ~.~~~. ~~ .... ~.l.. ~ ~, IC~I~I, ~ C~II~I. ~1;'~1~ ........................... I C~TY, ZZP: PHONE ~: !C(~se Cade Mt *----i Business Carnation Dairy ~a~&rs~le[O, L~ ~33i3 (805) 398-350Q KERSFIELD HAZARDOUS MAT w-RI ALS I NvENT.oRy' NON--TI?ADE SECRETS 0,NER NAME :_. Carnation Company ADDRESS: -  ZTY, ,ZZP: ' Los ~geies~ ~ I Pq, ..8 o! 9 NAHE OF T~]::~ FACILITY:' STANDARD IND. CLASS CODE DUN AND BRADSTR~'ET NUMBER at II llll [ C.i.S. ~ 7664-38 -2 C4q~nmt 12 Jim &C.A.S. ~ C~t 1:3 ~ & C.l.S. Rel,bl. II ^~ 3 Phosphoric Acid - - 7664-38-2 Acid ~lth ef ~m ~ltk 100 ~ ' ~ ~ cJ.s. ~ 8°di~ Hydroxide ~lth Il Pm~ ~lt. . Discontinue after pr~uct gone ~.o~[K, ~Tacis . Nori Shi~anian Facil~y/Util~cy 398-3532 Jerry Nezu Plant Enginerer~ng 398-3530 .)' I .usE,ESS 'N^~E:_~rnation Dairy ~oc~?IoH:~ 7~01 District Bird, CiTY i KERSFIELD HAZARDOUS MATERI ALS INVENTOR¥' · .NON--TRADE SECRETS OWNER NA~E:. Carnation Company ADDRESS: - - crr¥. ziP:__, 5045 Wil.~hir~ RlvH. 9ak~oF~lA eA 933~_3 : CITY, ZI~:__' T.~o A~I~ ~ PHONE , ~-- ~U3~-3~JDU~- p~:~ =IO~ ~R ~OP. COD, [,-- L~e ~t i~ ~ ~-- I ~ Cml ~t ~--'- '~ Il ] ,, IChack dll that "~ ..9 of ._9. NAME .OF T~'~ FACILITY: STANDARD IND. CLASS ~OD£ DUN AND BRADSTREET 14 SS Polish ~ P13~~ 1,1,1,~ichloroet~ne ~opane ~obutane Plant Engineering ' 398-3530 ~lth o! Prm~dre I~lth 71-55-6 bt 12 M&C.A.S.~ Ca,pan~t II aam & C.a.S. ~ Crammer I~ Jam & c.1.$. ~ Ca,,mmt 11 am, & C.A.S. ~ alt that 'e~iy) C.A.S. ~lth of nam & C.A.$. ~ ~ & c.A.s, a~iar bt I! lint & C.A.S. Ikak~ co.K,,.nt. ~ & c.a.S. ~ -. ~-,~,, - ~.. s c.A.s. ,,.~ 398-3532 Jerry Nezu ~.~,G~,,C, m'~cT~o~i Shirvanian Facilit ty I-. NOTE: THIS DRAWING IS ISSUED FOR INFORMATION ONLY· PROCESS EQUIPMENT'PLAN BAK[._RSFILq. D, 'CAL_IF_O R NrA : pR-O~£CT I.C.P,F- '. PR[LlUll~u~_ pROC£SS ' ~ -, £ouiPu£N~r pLAN ' 147 AS / RS EQUIPMENT STORAGE CHEMICAL ~ CONTAINMENT 0 AREA USED [-~ ~ ~ OIL P.G. & E. MAIN ELECTRICAL SUBSTATION DIESEL FUEL 154 I 155 157 17O EPSU [% L-i2 [~. 128 119 wzs'r u~x 120 ~ 116 128A o TRANSFORMERS 129 ] 130 ROOM 137 CIP ,3 & 4 144 167 155 '" 152 RECLAIM ROOM ~w HALL (~ 104 100 MIX © © @ PRODUCTION LINE LEGEND: LINE #1 = ROLLO #1 LINE #2 = ROLLO #2 LINE #5 = ROLLO #.3 LINE #4 = ROLLO #4 LINE #5 = ROLLO #5 LINE #6 = SPECIALTIES (TANDEM) LINE #7 = SPECIALTIES (HUSKY) LINE #8 - SPECIALTIES (DON-DONS) LINE #10 = DRUMSTICKS (BI(; DRUM) LINE #11 = DRUMSTICKS (BIG DRUM) LINE #12 = DRUMSTICKS LINE #14 = DRUMSTICKS LINE #15 = DRUMSTICKS LINE #16 = DRUMSTICKS LINE #17 = SPECIALTIES (SANDWICHES) LINE #19 = SPECIALTIES (SANDWICHES) LINE #21 = SPECIALTIES (CUPS) LINE #25 = SPECIALTIES (PUSH-UPS) LINE #24 - SPECIALTIES (PUSH-UPS) LINE #25 = SPECIALTIES (PUSH-UPS) 198 %% 25 20 15 10 5 0 10 20 50 40 50 GRAPHIC SCALE REVISIONS PIANT Ice Cream Company BAKERSFIELD, CA 93313 Pv'I F1 h USED OIL DIESEL FUEL I I HYDf~4T · ' i ii 154 I i i il 'IL ! : : II ® ,r,® TRANSFORMERS [7 WEST MIX 1 20 ROOY 1 iii ~ 5 __o U~ UNLOADING AREA FOR DIESEL 107 MAINTENANCE SHOP · REC~M ~M DRY I ~T MIX 188 0 0 0 0 0 187 I 0 0 0 0 0 195 25 20 15 10 5 0 10 20 ~ ~ ~ GRAPHIC SCALE A REVISIONS PLANT LAYOUT Ice Cream Companz BAKERSFIELD, CA 93313 ::',,.,'::'";":,, ,,o. DIESEL FUEL USED OIL 154 !~ ram lB fMIX 107 1~II6ENNqCE ~P 188 0 0 0 0 0 0 0 0 0 0 0 195 / 0 %.... 2~ 20 15 10.5 0 10 ~ 30 40 50 GRAPHIC SCALE IIVIIIO#I /ce Cream Company District Boulevard Post (ICP) i Response Team Staging Area Wastewater ///~,~ ,--~ Front Office ,, --" , ..... '-_i ....... '_~'-'-' ..... . . Incident Ccmmar ~/ .-: .-/~'~ . ~'',, '. ~..., ., Front Conferer Was ~wate~ .---" ..... . ~ ~~ ~~ ~ .-----'"'"/ X m. ' ', - .-" . ~ Re~'n~e Team ' ASRS~''- '' /'' ,, ...... ~?~:;:;,, ~ *-- ~ Air'Handler Unit 13 ....... . ' ;': ~ x xN '>', ,, / ~ ~ _..5;-' ~ .... .. ....... ,-. .......... ' ",. ':' .' ,,--' ~ · ~' '" ' ".,:"- '~ :~/3- .... -¢ - ..- ., _,~ "~, .~ ..~--~ ....... ~.~_ .~ _. - Legend Response Team Staging. ,,. : .... .. --~ "--~ .... - " ' ~- --' ~ "~/ '~._, ~ ,_.' ~, ~ ~ .. . ,.- , , .. .... · .- / ... ~'?" Chemical ~'..... S'torage ' ' 5 :-' -'" Area SITE PLAN  Nestle Ice Cream Company BAKERSFIELD, CA 93313 ~ 10//1 NUkI~ ~UED SF._.EET No. ~ DWG, No. /,,,~,,, I of I · __- 75 60 45 50 15 0 30 60 90 150 ~ ~ .... Raw Receiving ................. _ ORAPHIC SCALF R~pon~ Team Truck District Boulevard Res4~n~e Team Staging Area Wastewater Front Office Front Po~t (ICP) Room lib ca e Area Nestle Ice Cream Company BAKERSFIELD, CA 93313 Raw ceiving GRAPHIC SCALE