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HomeMy WebLinkAboutMITIGATION (16) TRIHYDRO ~=_ oorporation Environmental Engineering & Consulting Shell Oil Products US II I Fourth Quarter and Annual 2002 Groundwater Monitoring Report Shell Bakersfield Refinery Bakersfield, California 93302 2002 City of Bakersfield · Required Environmental Clean-up Status as of 01/01/2003 Contact: Ralph E. Huey Phone: (661) 326-3979 e-mail: rhuey @ ci.bakersfield.ca.us 1715 Chester Av. Bakersfield, CA 93301 Hazardous Waste Corrective Actions: Ld Agency Site Name & Address Location Photo Environmental Status RWQCB PG&E Kem Steam Plant Hexavalent Chrome was retested and detected 2401 Coffee Rd. at 3 ppb (drinking water standard is 50 ppb) in ~1the grOundwater near the cOOling tOwers' Water supply wells are non-detect for chrome elsewhere on site. 80 tons of soil containing hazardous levels of heavy metals were removed in Nov. '01 from a former incinerator area.' Additional soil and groundwater sampling for petroleum impacts around fuel oil storage tanks to be conducted in 2002. RWQCB Sunland Refinery Free product removal, air sparging & vapor 2150 Coffee Rd. extraction in progress. A total of 4,520,047 ~ lbs (821,827 gal) of petroleum have been (MTBE in groundwater) removed from the soil and groundwater to (Benzene in groundwater) date, and clean-up is estimated at only 50% (Floating gas on water table) complete. MTBE detected in water under the site up to 90,000 ug/L. Benzene at 16,000 ug/L. Contaminants have moved under PG&E site & deeper water sampling is being required by RWQCB. City's Water Agency well # CBK-25-01, SW of Brimhall & Coffee, is not in service due to contamination in the area. ' RWQCB Shell Refinery ~. tt_~[ ~ ~~ I N°t in City, but within area °f c°ncem. 6451 Rosedale Hwy MTBE in groundwater resulting from (Not in City Limits) previous spill events at the refinery. Aquifer tests were performed in Oct. 2000 to assess (MTBE in Groundwater) water table and water movement in the area. Soil vapor extraction and air sparging.in progress. DTSC Former Tosco Refinery - DTSC has a clean-up order for Tosco to 6451 Rosedale Hwy-~ remove a petroleum coke pile which is on the north side of the Kern River across· from (Not in City Limits, but Tmxtun lakes. The deposition of waste adjacent to Kern Riverbed) petroleum coke in this area was a former practice of the refinery while under Tosco's ownership, over 20 years ago. RWQCB KL Aviation Pesticide contamination assessment still 2014 Union Ay. continuing as an open case from previous Former Garriot Crop Dusters practice of rinsing crop duster tanks into a  i former sump. Additional monitoring well to (Soil assessment req'd)~'' ~ be installed downgradient. Abandoned UST's removed on 12/01/00. Gasoline detected in soil between former tank and dispenser locations and referred to RWQCB for coordination with their existing investigation. RWQCB Former CleanSoil Facility RWQCB requesting new owner to properly 903 E. White Ln. ~!:~! ?;'; abandon groundwater monitor wells 6n site. (Note: adjacent SoilRem facility has been '' :-i[- iP' ' ~- ~~?':9c:;~7%~:~'"~'~'.~d~'~ properly closed under the City of Bakersfield ' ,' ::: ::z:' Permit Consolidation Zone and its monitoring t wells were properly abandoned). DTSC Gibson Oil Refinery .1 Not in City, but within area of concern. End of Commercial St.~ Corrective Action Branch of the Permitting (Not in City Limits) Program (Berkeley Office) is handling the clean-up oversight. All hazardous liquids & (Waste liquids & tanks tanks have been removed. 'Soils currently removed. Soils currently ~¢:~ ~ being classified and removed. Tony Netera, being removed) : DTSC, is case agent at (510) 540-3951. DTSC K&D Salvage DTSC has removed solid wastes from K&D 600 S. Union [-~.- ...... site, and has performed further assessment. ..... ' .... Final remedial action plan proposes to remove 710 cubic yards of soil impacted with (Lead and PCBs on site) leachable concentrations of lead and PCBs ~..~ and place an asphalt covering over part of the site to prevent percolation of rainwater. Cost of cleanup estimated to exceed $1,300,000. USEPA Double D Recycling USEPA repaired fence & returned April 25, Former Benham-Johnson '. ~ 2002 to conduct further assessment. Double 340 Daniels Ln. D has shown high levels (19 ppm) of DDT in (located behind 600 Union) soil (hazardous threshold=lppm). All hazardous waste removed from the surface. (Junk removed by City Code No sample results yet from the latest soil Enforcement in cooperation ',~ assessment in May 2002. with EPA soil sampling activities) Underground Petroleum Storage Tank Release Corrective Actions: Ld Age~'c¥ Site Name " Location Photo Status BFD Freeway Liquors MTBE (295 ug/l), Benzene (95 ug/l), & 2030 E. Brundage Ln gasoline (2,049 ug/l) detected in groundwater :~ (126') beneath site. No water supply wells are (MTBE in groundwater) ..... within one mile. Vapor extraction in (Benzene in groundwater) ~ ~ operation since Nov. '02. 140 gallons of Wlllll product have been removed from the soil and groundwater so far. Latest groundwater monitoring shows low concentrations are decreasing to non-detect last quarter. BFD Elks Lodge Vapor extraction completed. A total of 1414 E. California Ay. ~~ ~ 26,207 lbs. (4,765 gal.) have been removed to ¢:; ~ date by soil vapor extraction. MTBE not (MTBE not involved)~ involved since leak occurred in early 1980's (Clean-up complete.pending before MTBE was added to gasoline. closure report acceptance) Confirmation sampling now performed & report still needs to be approved for closure. BFD St. Vincent De Paul · Vapor extraction completed and confirmation 310 Baker St. sampling required for closure. A total of 8,169 lbs or 1,276 gallons of gasoline has (No MTBE detected) been removed through vapor extraction. (Clean-up complete pending Work plan for confirmation sampling has confirmation) been approved. Sample drilling to occur during January, 2003. RWQCB Downtown Chevron At least 400 gallons of gas leaked through a 2317 L Street hole in an underground pipe before the leak was confirmed. There is now detectable (MTBE in groundwater) benzene (2400 ug/1), and MTBE (4,000,000 ug/1, or 4000 ppm) in the shallow groundwater below the site. Soil vapor extraction has been ordered by RWQCB to begin and is now overdue to begin. RWQCB Mr. Fast Gas Leak from former UST's stopped in 1995. 600 Brundage Ln. Vapor extraction system and add'l groundwater monitoring wells have been (Gasoline floating on installed and operating. On site cleanup is est. groundwater table, no to be 70% complete. Second vapor extraction MTBE detected lately) system to be installed on south side of Bmndage Ln. during January '03. RWQCB Beacon Truck Stop Vapor extraction started on Oct. 15, 1999 and 3225 Buck Owens Blvd. 4,462 lbs (822 gal) of gasoline removed to date. MTBE has not been detected in the (Clean-up was to be groundwater during the past two quarters. completed, but diesel now Vapor extraction completed. However, very appearing in groundwater) minor amounts of diesel (100 ppm) keeps appearing in the groundwater and monitoring & investigation is still continuing because of this recent diesel detection. RWQCB Former Mobil Station Max. MTBE of 16,000 ug/L in groundwater at 4456 California Av 36' beolw surface. Monitoring well to be installed on south side of California Ave. (MTBE groundwater site) Groundwater pumping & vapor extraction pilot study approved for implementation and a schedule for startup is required by 1/21/03. This site has not been meeting regulatory deadlines set by RWQCB & has been granted, and exceeded, several extensions already. RWQCB Minit Stop Market Gasoline detected in groundwater at 380 ug/l 2900 Union Ave. and MTBE detected at 1570 ug/1. Case has been referred to RWQCB for further (MTBE groundwater site) investigation. Approved for three additional groundwater monitoring wells. RWQCB 7-Eleven Small pipe leak discovered & repaired, but 525 W. Columbus I--i; ~~ I I shallow groundwater (15'below surface) [::l i' [ I impacted by MTBE at max. concentration of (MTBE groundwater site, I~-~ [] _ ~--,,,~ ~ / [ 2,600 ug/L. Vapor extraction pilot study now and levels have increased ~li ~ ]lll~ ~ ~ [ required as MTBE has recentlyincreased' since last quarter) ~' ~ ~ ~ ~ I Add'l monitoring well to be installed near · · I [] ~]/1 I dispenser island to determine if dispensers are · III II/l a source of the release. RWQCB Former 7-Eleven [ Leakage from former UST's showed trace 1700 Brundage Ln. ~ '- -- '~ I MTBE in the soil at such depths (150 ft) that | I RWQCB wanted to assess the groundwater · (MTBE in soil only) ~1 [] ~ I quality even· though groundwater is ~ I ~li I approximately 250 below the surface. 7- ~ Il/ill I Eleven's consultants argued that groundwater ~ ~ I monitoring wasn't warranted & RWQCB  ] agreed to shallow soil vapor extraction only. RWQCB Car Wash of America / Unreported release in 1997 has not yet been 1701 Stine Rd. / fully defined, but max. MTBE of 2.8 mg/kg / detected in soil at 85' below surface (that's (Suspected MTBE ~l . ' ~' · ~1 ] deep for max. MTBE). A monitoring well groundwater site) ~ and vapor extraction system to be installed. / Former owner of Niagara Car Wash has taken  i~] over responsibility for clean-up. RWQCB Apex Bulk Commodities ~' ~ Diesel impacted soil & G/W @ 17' BGS. 2111 Bricyn Ln. t ~ ' :7 / MTBE detected in soil at 0.58 mg/kg. Soil [ I / excavation & removal on 8/17/00. Benzene (Benzene in groundwater) I - --~.~ 'F I / originally detected in groundwater at 9.ug/L, (MTBE in soil only) / but has been non-detect last two years. No ~ t ~ ] MTBE in water.' RWQCB will consider case (Groundwater monitoring / closure upon review of next monitoring event completed, closure pending) / / RWQCB Holden Truck Stop I | Gasoline & diesel detected in groundwater. 3775 Buck Owens Blvd ~~l~/ Property is in bankruptcy, but San Joaquin ' [ ~ ~ / Bank, as lien holder, has paid for all UST (Trace gasoline & diesel in I [~-.a~.~ ~[~[~-[ / removals and is funding site assessment work. groundwater, no MTBE) ~~, - ~ / Groundwater monitoring now in Progress. An [ excavation work plan is due 1/15/03 to ~' '~ / remove petroleum impacted soil that was I I ~ ;1 / allowed to be left on site by Kern County I ' ? / dunng a prevmus UST removal ,n 1980 s. KCEH KHSD Maint. Yard [ Over-excavation performed for remediation of 3100 Chester Ay. ] ~ I ~ [ Underground Injection Well. G/W (No MTBE Detected) ~ll!l~ / /m°nit°ringn°winpr°gress' IIi .p · p. g (No MTBE Detected) / [ '~ ~ I risk assessment prior to requesting closure. / ~~lll I Vapor extraction equipment has been / ~.~ ~;~-,,dtd I removed from site, but vapor wells and piping KCEH McKenny's Air Cond. 2323 R St. (No MTBE Detected) G/W monitoring in progress. Vapor extraction equipment (owned by the State) still on site but has not operated in two years. Site Investigation Case Closures During the Last Quarter: Ld Agency Site Name Location- Status BFD Former World Oil Station 2101 Brundage Ln. Previously closed site which was re-evaluated for change in property use to commercial retail offices. No further action required. Cases Currently Under Investigation Pending Clean-Up Determinations: Ld Agency Site Name Location Status BFD Golden Empire Transit 1830 Golden State Hwy Soil sampling performed under diesel fuel dispenser, which had leaked. Case to be (Case closure pending) closed after GET completes upgrade to dispenser island. GET is currently out to bid for the upgrade work. BFD Excell Excavation Arrow & Brittan Sts. Illegal dumping of restricted soil from 7- Eleven site assessments from No. Calif. Soil sampling conducted and waiting for results. BFD Former Texaco Station 2601 White Lane UST removal showed tank pit & dispenser islands impacted with petroleum products. (Soil assessment req'd) Work plan currently under review. BFD ARCO AM/PM 900 Monterey St. Leakage detected under a former product line which was removed in May, 2001. Requested (Soil assessment req'd) work plan for further soil sampling. BFD Union Pacific Railroad 700 Sumner St. Ruptured locomotive fuel tank leaked 1700 gallons onto the track area west of Baker St. at depot. Extent of soil impact still to be determined through soil sampling on 1/23/03. BFD 34t~ Street ARCO 1102 34th St. UST lining inspection uncovered petroleum impacted soil surrounding two of the three UST turbine pump areas. UST's are emptied and temporarily abandoned until responsibility for repairs and clean-up is adjudicated in pending law suit. BFD Texaco Service Station 4050 Gosford Rd. 50 cu. yds. of impacted soil excavated & removed during product piping upgrade. (Soil assessment req'd) Detectible MTBE still present in soil. Further soil sampling to be required. ' Key~ BFD = DTSC = KCEH = RWQCB = USEPA = Bakersfield Fire Department (Office of Environmental Services)' Department of Toxic Substances Control Kern County Environmental Health Regional Water Quality Control Board United States Environmental Protection Agency S :\CORRESPONDENCEL2003-01 \Cleanups 1-03.wpd Overman, Steven D SOPUS From: Sent: To: Subject: William D Prevatt [William. D.Prevatt@conocophillips.com] March 18, 2003 1:30 PM Overman, Steven D SOPUS contacts Steve, The individual signing the agreement will be Bob Staab. His contact info. is as follows: Bob:Staab ConOcoPhillips Company 1500 N Priest Dr Tempe, AZ 85281 phone: 602-728-7058 fax: ~ 602-728-5245 email: Robert. F.Staab@conocophillips.com The :ConocoPhillips attorney who will have to sign off on the agreement before Bob will sign it is Derrick Vallance. His contact info is: Derrick Vallance ConOcoPhillips Company 600 'N Dairy Ashford Rd Houston, TX 77079 phone: 281-293-2247 fax:: 281-293-4255 email: Derrick. D.Vallance@conocophillips.com I am your contact for this and I am the person within ConocoPhillips that is reSponsible for shepherding this project. Therefore, it is probably besti if draft documents flow thru me so that I can make sure that they are attended to properly William D Prevatt, PhD Site Manager Con0coPhillips Risk', Management and Remediation 1218 PB Bartlesville, OK 74004 918-661-3616 (bus) 918-661-5664 (fax) 918-~261-6447 (cell) William. D.Prevatt@conocophillips.com <<gO not to the wise for advice, for they will say both yes and no>> ® Steven D. Overman Shell Oil Products US Supervisor, Environmental Environmental Department Bakersfield Refinery 6451 Rosedale H ghway, Bakersfield, CA 93308 P.O. Box 1476, Bakersfield, CA 93302 Tel +1 661 3264351 Fax +1 661 326 4255 Pager +1 661 398 7801 Mobile +I 661 201 2515 Email sdoverman@shellOPUS com Gene Freed Venture Manager Shell Oil Products US Health, Safely & Environment 6451 Rosedale Hwy. Bakersfield, California 93308 Tel +1 661 326 4412 Mobile + 1 661 496 6272 Email eefreed@shellopus.com . - : -; : , ~ -SHELL OIE PRODUCTS u.S: .: : ...... .... ~ ........ . :, :. : RAKI=RRF-iFi.D ~- - - , _. _._.._..___, CALIFORNIA ' - - February 12, 2003 ._ . _ ___ .- : -- . _. _ . ~ __ . ~.,,...,~re,-,~,r",~_~.,..,.. _ - ..... : ..-. .:-:, --' - Shell Oil Products U.S. "- - - : - 6451._. ___.Rose:d~le Highway. ' ~ - .... ': --.- Bakersfield, CA 93308 -~ . Prepared by: .... -- - i- i : _::. ._ TriHydr0 CorpOration -- -- '- -: --~ 920 Sheridan Street _ - - . - : .:i_ ' -.'._Laramie, WY 82070 -. Hydro C po atio idan ' .~...., . :~ - .: ...... - ~ :: :-'_L_aramie, Wy_om qg-82070 - FA_Xi (30?) 'CERTIFICATION FOURTH QUARTER AND ANNUAL 2002 GROUNDWATER MONITORING REPORT SHELL OIL PRODUCTS U.S.. BAKERSFIELD, CALIFORNIA I certify that I have reviewed this document. To the best of my knowledge, the data contained herein are true and accurate and the work was performed in accordance with appropriate and customary professional standards. J. Kirk Hardy Date California Registered Geologist #5273 California Certified Engineering Geologist #1679 Licenses Expire March 31, 2003 H:~Projects~SH ELL~}akersfield~Final~77-O30~ReportO1~RPT01 .doc SHELL OIL PRODUCTS U.S. FOURTH QUARTER AND ANNUAL 2002 GROUNDWATER MONITORING REPORT February 12, 2003 Facility Location: Facility Contact: Primary Consultant/Contact Person Lead Regulatory Agency Lead Regulatory Agency Contact: 6451 Rosedale Highway, Bakersfield, Ca 93308 Steve Overman (661) 326-4351 TriHydro Corporation / Ms. Linda Barnes (307) 745-7474 Regional Water Quality Control Board - Central Valley Region, Fresno Office Mr. Anthony Medrano (559) 488-4395 SECTION 1.0 ANNUAL GROUNDWATER MONITORING SUMMARY- 2002 Current Project Phase: Depth to Groundwater Range in 2002: Groundwater Gradient: MTBE Concentration Range: Well with Highest MTBE Concentration: · Benzene Concentration Range: Well with Highest Benzene Concentration TPHG Concentration Range: Well with Highest TPHG Concentration: Separate Phase Hydrocarbon Thickness Range: Water Supply Wells within 2,000 feet of the Site: Surface Water within 2,000 feet of the Site: Remediation Techniques: Separate Phase Hydrocarbons recovered in 2002: Agency Directives: Groundwater Investigation, Interim Remediation, Ongoing Remediation (Refinery VES/Air Sparge Systems), Groundwater Monitoring 51.51' - 110.9' bgs (Water table declining at approximately 1.7 feet per quarter) 0.0064 - 0.0071 ff/ft westerly to southwesterly in the <110'bgs zone 0.0065 - 0.0074 ftJft westerly to southwesterly in the 110' - 140' bgs zone 0.0078 - 0.0083 ft/ft westerly to southwesterly in the >140' bgs zone <1 - 74,000 ug/L B-159 <0.5- 17,000 ug/L B-159 <100 - 600,000 ug/L B-159 0.13 - 1.56 ft D-l, D-2, D-3, D-4, D-5, D-6, D-7, I-1, I-2, I-3, I-4, I-5, I-6, I- 7, I-8, I-9, 1-10, 1-11, 1-12, 1-13, 1-14, 1-15, 1-16, P-31 Calloway Canal (dry) 500' northwest of Area 1 Refinery, 1,500' northwest of Area 2 Refinery Soil Vapor Extraction, Groundwater Extraction and Treatment, and Air Sparging 790 barrels (33,180 gallons) from the refinery SVE system None H:\Projects\SHELL~Bakersfieid~Final\077-030\Report01~RPT01 .doc 1-1 SECTION 2.0 DATA SUBMITTAL (ATTACHED) Fi.qures · 2 · 3 · 4 · 5 · 6 7 8' 9 10 11 12 13 14 site Vicinity Map Site Plan Potentiometric Map for Groundwater <110' bgs, November-December 2002 Potentiometric Map for Groundwater 110'- 140' bgs, November-December 2002 Potentiometric Map for Groundwater >140' bgs, November 2002 MTBE Plume Contours for Groundwater <110' bgs, November-December 2002 MTBE Plume Contours for Groundwater 110'- 140' bgs, November-December 2002 MTBE Plume Contours for Groundwater >140' bgs, November 2002 MTBE Results for Nearby Water Supply Wells, November 2002 Benzene Plume Contours for Groundwater < 110' bgs, November-December 2002 Benzene Plume Contours for Groundwater 110' - 140' bgs, November-December 2002 Benzene Plume Contours for Groundwater >140' bgs, November 2002 Benzene Results for Nearby Water Supply Wells, November 2002 Air Sparging Well Locations Tables 1 2a 2b 3 4th Quarter- Groundwater Levels, Shell Oil Products U.S. 4th Quarter- Monitoring Well Analytical Results, Shell Oil Products U.S. 4th Quarter - Water Supply Well Analytical Results, Shell Oil Products U.S. 4th Quarter - Quality Assurance Results, Shell Oil Products U.S. Appendices · A · B Field Data Sheets Laboratory Analytical Reports H:~Projects~SHELL~Bakersfleld~Final\077-030~Report0 I\RPT01 .doc 2-1 SECTION 3.0 FACILITY DESCRIPTION Shell Oil Products U.S. (SOPUS) has owned and operated the facility now known as the Shell Bakersfield Refinery (SBR) since October 2001. The Shell Bakersfield Refinery consists of three interconnected operating areas known as Areas 1, 2, and 3. Area 1 was built in 1932 by the Mohawk Oil Company (1932 to 1970) and was subsequently owned by Reserve Oil and Gas Company (1970 through 1980), Getty Oil Company (1980 through 1984), Texaco (1984 through 1998), and Equilon Enterprises LLC (1998 through 2001). The adjacent Area 2 was built by the US Government in 1942 and was subsequently owned by Lion Oil Company, Tosco Oil Company, Texaco (1986 through 1998), and Equilon Enterprises LLC (1998 through 2001). SBR Areas I and 2 encompass approximately 599 acres of land located in the city of Bakersfield, Kern County, California (the Site, Figure 1). Area 3 was built and operated by the Independent Valley Energy Company (1978 to 1987) and was subsequently owned by Texaco (1987 to 1998) and Equilon Enterprises LLC (1998 to 2001). Area 3 is located approximately 1.5 miles northeast of Area 1 and encompasses approximately 357 additional acres of land. The Shell Bakersfield Refinery currently processes about 70,000 barrels of crude oil per day.into products such as automotive gasoline, diesel fuel, petroleum coke, fuel oils, liquefied petroleum gas, asphalt, and sulfur. A site plan showing the Site and adjacent properties is included as Figure 2. H:~Projects~SHELL\Bakersfietd~Final\077-030\Report01~J~PT01 .doc 3-1 SECTION 4.0 GEOLOGIC AND HYDROGEOLOGIC SETTING The Site is located at an elevation of approximately 390 feet above mean sea level (msl) and is underlain by approximately 200 feet of late Pleistocene and Recent alluvial sands and gravel (deposited primarily by the Kern River). The Kern River alluvial fan is a large wedge of sand and gravel on the east side of the valleY that forms where the Kern River exits the Sierra Nevada foothills. Alluvial fan deposition is the geologic response to the change in slope and to the transition from confined to unconfined flow (Dale, 1966). Water runoff from the Sierras flows from the northeast to the southwest down the bed of the Kern River onto the alluvial fan, where water slowly seeps from the river bottom into the distant margins of the fan. Elk Hills, which represents the surface expression of a subsurface anticline, then diverts the subsurface flow southward towards Buena Vista Lake (Dale, 1966). The near-surface aquifer is made up of Pleistocene to Recent sands and gravel. These sediments cut into older alluvial fan and lacustrine sediments of the Plio-Pleistocene Tulare Formation. An angular unconformity then separates the continental sediments from underlying marine deposits of the Pliocene San Joaquin Formation (Bertoldi, 1991). Studies of the Site and surrounding area indicate that the upper' 100 feet of sediments consist primarily of interbedded sands and silts (with minor clay) deposited as the outwash plain of the Kern River. Because of the nature of braided stream deposition, correlation of distinct stratigraphic horizons is difficult and may vary across the Site and vicinity. For monitoring purposes, the site stratigraphy has been divided into three distinct horizons~. Depth of less than 110 feet below ground surface (bgs) (Shallow Zone); Depth of 110 feet to 140 feet bgs (Intermediate Zone); and Depth of greater than 140 feet bgs (Deep Zone). The aquitards that separate these horizons are pervasive and relatively uniform across the Site. Although there may be two or more coarse-grained strata present within any of these horizons, each individual monitoring well is typically screened across only one stratum. The shallowest groundwater in the site vicinity is generally unconfined, with confined conditions occurring locally. The water table elevation has fluctuated by tens of feet per year in response to changes in regional groundwater recharge and pumping conditions. There was approximately 100 feet of water table rise between 1993 and 1999. Since 1999, the water table has been decreasing in elevation and dropped by more than one foot per month during 2001, with an average elevation decrease of approximately 0.57 foot per month in 2002. The current average depth to water is approximately 80 feet bgs. Groundwater flow directions have remained consistently to the south/southwest in 2002, with some local, transient groundwater mounding occurring along the northern portion of the site in the first and fourth quarter monitoring events. The groundwater mounding is likely due to recharge from the H:~Projects~SH ELL~Bakersfield~FinaR077-030~Report0 I~RPT01 .doc 4-1 Calloway Canal in the first and fourth quarter gauging events. Groundwater extraction activities along the northern portion of the site tended to depress groundwater elevations in groundwater monitoring wells located within the extraction wells' radii of influence. Groundwater gradients have remained relatively stable throughOut 2002, ranging from 0.0064 to 0.0071 foot per foot in the Shallow Zone, 0.0065 to 0.0074 foot per foot in the Intermediate Zone, and 0.0078 to 0.0083 foot per foot in the. Deep Zone. Fourth quarter 2002 groundwater levels are summarized in Table 1. Field data sheets for the fourth quarter 2002 groundwater sampling event are included in Appendix A. Po. tentiometric maps for groundwater less than 110 feet bgs, between 110 and 140 feet bgs, and deeper than 140 feet bgs, are included as Figures 3 through 5, respectively. H:~Projects~SH ELL~Bakersfi eid~Final~077-O30~Report0 I~PT01 .doc 4-2 SECTION 5.0 DISTRIBUTION OF PETROLEUM CONSTITUENTS Identification of Source Areas Two source areas for methyl tert-butyl ether (MTBE)-affected groundwater have been identified at the Site. One source area is located at the Sales Terminal (hereinafter referred to as the "Terminal"), along the southwest corner of Fruitvale Avenue and Rosedale Highway. The second source area (Blending Area) is located near the eastern property line within the Refinery, near the railcar-loading area in Area 1. A release of petroleum hydrocarbons containing MTBE first occurred from the Terminal's underground product lines in March 1999. Subsequent releases occurred in December 2000 and April 2001..A soil vapor extraction (SVE) system was installed and is currently operating within the Terminal's source area. Several groundwater extraction wells were installed in the central and down-gradient portions of the Terminal's MTBE plume to provide down-gradient and vertical hydraulic containment of the dissolved-phase MTBE plume. Two IRM treatment systems, IRM-1 and IRM-2, are utilized to treat the extracted groundwater prior to its discharge into the Calloway Canal. An air sparging system has been in operation down-gradient of the Blending Area's MTBE source since 1995. The SVE system was expanded into the Blending Area's MTBE source area (near monitoring well B-116) and is anticipated to be in operation by the second quarter of 2003. A reformate release, in the vicinity of the Area 2 Refinery's hydrocracker, is currently being remediated using a system of four vapor extraction wells and six air sparge wells. Details regarding operation of the air sparging, groundwater extraction, and SVE systems are included in Section 6.0. MTBE Plume Distribution In Groundwater Extensive subsurface investigation has delineated the Terminal's dissolved-phase MTBE plume as being a maximum of 3,300 feet long and up to 800 feet wide in the Shallow Zone (<110 feet bgs), and 2,100 feet long and up to 400 feet wide in the Intermediate Zone (110 to 140 feet bgs) in the 2002. groundwater sampling events. MTBE was not detected above laboratory method detection limits of 1 microgram per liter (ug/L) in the Terminal plume's Deep Zone groundwater monitoring wells (>140 feet bgs) during the 2002 quarterly sampling events,, with the exception of first quarter 2002 samples collected from wells B-126L (3.9 ug/L) and B-176L (1.1 ug/L). Subsurface investigation activities have delineated the Blending Area's dissolved-phase MTBE plume as being a maximum of 3,400 feet long and up to 900 feet wide in the Shallow Zone, 2,600 feet long and up to 1,000 feet wide in the Intermediate Zone, and 3,600 feet long and up to 500 feet wide in the Deep Zone during the 2002 quarterly groundwater sampling events. Both the Terminal and Blending Area's dissolved-phase MTBE plumes trend in an east to west direction, following the local groundwater gradient (accentuated by groundwater extraction in the case H:\Projects~SHELL\Bakersfi eld~Final\077-O30~'RePort01\RPT01 .doc 5-1 of the Terminal plume), with limited north-south expansion over time. No appreciable eastward migration (upgradient) of the dissolved-phase MTBE plumes has been observed. Concentrations of MTBE in wells located in the vicinity of the Terminal source area have dropped significantly between the February and November 2002 quarterly sampling events. Concentrations of MTBE in Terminal source area wells have decreased from 570,000 to 220 ug/L in T-9A, 63,000 ug/L to ND (at a-detection limit of 1.0 ug/L) in T-10A, and 7,700 to 30 ug/L in WIP-W4A. MTBE concentrations in groundwater in the vicinity of the Simpson Property and Blending Area have shown a similar drop in concentrations in 2002, decreasing from 540 to 38 ug/L in B-178U, 270 ug/L to ND (at a detection limit of 1.0 ug/L) in B-187U, 180 ug/L to ND (at a detection limit of 1.0 ug/L) in B-188U, 370 to 64 ug/L in B-195U, and 81 to 11 ug/L in B-098M. Fourth quarter 2002 MTBE plume isoconcentration contour maps for groundwater less than 110 feet bgs, between 110 and 140 feet bgs, and greater than 140 feet bgs, are included as Figures 6 through 8. Fourth quarter 2002 MTBE analytical results for nearby water supply wells are shown on Figure 9. Benzene Plume Distribution in Groundwater DisSolved-phase benzene plumes are located in the Blending Area and the northwestern portions of the Area 2 Refinery. During 2002, the Blending Area dissolved-phase benzene plume was a maximum of 2,200 feet long and up to 800 feet wide in the Shallow Zone, 1,600 feet long and up to 400 feet wide in the Intermediate Zone, and 1;800 feet long and up to 700 feet wide' in the Deep Zone. During 2002, the Area 2 Refinery's dissolved-phase benzene plume was a maximum of 3,000 feet long and up to 2,000 feet wide in the Shallow Zone, 3,000 feet long and up to 1,200 feet wide in the Intermediate ZOne, and 3,200 feet long and up to 1,200 feet wide in the Deep Zone. Both the Blending and Refinery 2 Area's dissolved-Phase benzene plumes trend in an east to west · direction. The down-gradient portion of the Refinery 2 Area's Shallow Zone plume exhibits some lateral (north and south) migration of dissolved-phase benzene. No appreciable eastward migration (upgradient) of the dissolved-phase benzene plumes has been observed. Concentrations of benzene in wells located in the vicinity of the Blending Area have decreased or remained stable between the February and November 2002 quarterly sampling events. Benzene concentrations in groundwater in the Refinery 2 Area plume have dropped in 2002, decreasing from 1,700 to 280 ug/L in R6B, 840 to 280 ug/L in RS-6A, 4,800 to 1,200 ug/L in D2, and 20 ug/L to ·ND (at a detection limit of 0.5 ug/L) in MS2.5A. Fourth quarter 2002 benzene plume isoconcentration contour maps for groundwater less than 110 feet bgs, between 110 and 140 feet bgs, and greater than 140 feet bgs, are included as Figures 10 through 12. Fourth quarter 2002 benzene analytical results for nearby water supply wells are shown on Figure 13. Monitoring well and water supply well groundwater analytical results for the fourth quarter 2002 groundwater sampling event are summarized in Tables 2a and 2b, respectively. Laboratory reports and chain-of-custody documentation are included in Appendix B. H:\Projects\SHELL\Bakersfield~Final\077-O30~Report0 I\RPT01 .doc 5-2 SECTION 6.0 CONCEPTUAL PLAN FOR GROUNDWATER REMEDY The first stage of the groundwater remedy was to identify and eliminate all receptor pathways. Five off-site water supply wells were identified as potential future receptors due to their proximity to the dissolved MTBE plume. Four of the wells (EPC, Gaslight, Simpson,. and IP) have been destroyed. The remaining supply well GD, on the Caza Drilling property is not operating. Other off-site supply wells in the site vicinity are north of the Calloway Canal. The dominant groundwater flow direction is west-southwest, parallel to the Calloway Canal, and sampling results indicate that dissolved MTBE above 1.0 ug/L does not extend north of the canal. Four on-site supply wells provide water to the refinery for both potable and non-potable uses. All wells are screened at depths greater than 500 feet and are separated from the strata of M'l'BE-affected groundwater by a regional aquitard that begins at a depth of approximately 250 feet bgs. The refinery's four on-site water production wells are utilized as a source of process water. The use of two of the wells as a source of potable water for the refinery was discontinued on June 22, 2002, when the potable water distribution systems for Areas 1 and 2 of the refinery were connected to a municipal water supply. Area 3 of the refinery utilizes municipal water for process and potable uses. The MTBE plume originating at the Terminal is contained through operation of a groundwater extraction system. The effectiveness of the hydraulic containment system is provided through the following: 1) extraction from the leading (down-gradient) edge of the plume, 2) extraction from additional wells as necessary to provide capture of the full width of the dissolved plume, 3) extraction from enough locations along the. length of the plume to ensure hydraulic containment under conditions of shifting groundwater flow, and 4) extraction from sufficient depth to capture the vertical extent of the dissolved plume. The hydraulic containment system has been designed with enough flexibility to accommodate the anticipated fluctuations in water table elevation. In anticipation of dropping water levels, groundwater extraction wells have been completed in both the Shallow Zone, at a depth of approximately 80 to 110 feet (currently the primary interval containing dissolved-phase MTBE), and the Intermediate Zone, at a depth of approximately 110 to 140 feet. Extraction from the Intermediate Zone will be a precaution against MTBE bypassing the containment system as the water table drops. Shallow extraction wells that go dry will be temporarily capped and preserved for possible later use in the event that the water table rises in future years. IRM-1 consists of seven extraction wells (EW-3, 4, 5, 6, 7, 12, and 13) located 50 to 200 feet south of the Calloway Canal, approximately 450 feet west of the Charity Avenue cul-de-sac. IRM-1 was constructed to provide hydraulic containment at the down-gradient, leading edge of the Terminal dissolved-phase MTBE plume. Treated water from IRM-1 currently discharges to Calloway Canal. During 2002, the average discharge rate was 139 gallons per minute (gpm) or approximately 200,522 gallons per day (gpd). Influent MTBE concentrations for IRM-1 extraction wells ranged from less than 1.0 ug/L to 4,100 ug/L during 2002. · IRM-2 consists of one extraction well (EW-8) north of Charity Avenue and four extraction wells (EW-9, 10, 11, and B-149) south of Charity Avenue. Treated water from IRM-2 also discharges to the Calloway Canal. During 2002, the average discharge rate was 105 gpm or approximately 151,113 gpd. Influent MTBE concentrations for IRM-2 extraction wells ranged from less than 1.0 ug/L to 59,000 ug/L during 2002. H:\Projects\SH ELL\Bakersfi eld~'inal\077-030~Report0 I~RPT01 .doc 6-1 The groundwater treatment technology is a biologically augmented, granulated active carbon system (BioGAC). The BioGAC system utilizes a standard carbon treatment system inoculated with a naturally occurring, MTBE-degrading bacteria that has been isolated and patented by Shell Global Solutions. The BioGAC treatment technology is currently utilized for both the IRM-1 and IRM-2 extraction systems. As a precaution, the process streams from the treatment plants are run through a standard GAC unit before being discharged. Petroleum hydrocarbon-affected soil vapor is currentlY being removed from the source area at the Terminal by means of an SVE system. The SVE well extraction and operating system is being modified to increase mass removal rates and to take advantage of the dropping water levels, addressing residual and free-phase product from progressively deeper strata as the water table continues to drop. The existing SVE treatment system has sufficient capacity to accommodate increased extraction rates in the vicinity of the Terminal. Significant effort has been expended at the Terminal to prevent future releases of product to the subsurface. A series of five underground, pressurized product lines that lead from the Refinery to the Terminal have been replaced with aboveground lines. This modification should minimize the potential for future releases of the type contributing to the Terminal source area. The Blending Area MTBE plume is being contained by enhanced bioremediation through the use of the air sparge system. Historical MTBE concentrations show that the Blending Area MTBE plume is stable and will not affect offsite receptors. In addition, the refinery has installed a vapor extraction well in the Blending Area. The well should be online and operational by the second quarter 2003. In areas of favorable geochemical conditions, aerobic microbial populations are capable of degrading MTBE. Preliminary studies conducted by Shell's Westhollow Technology Center indicate indigenous MTBE-degraders are present at the site, however the rate of biodegradation is relatively slow. In areas within and down-gradient of a product release, groundwater is typically depleted of oxygen. The addition of oxygen to the groundwater system (e.g. through air sparging) is expected to stimulate microbial growth and associated MTBE biodegradation. Air sparging well locations are shown on Figure 14. H:~Projects~SHELL~Bakersfleld~Final\077-O30~Report01\RPTO 1 .doc 6-2 sECTION 7.0 TREATMENT SYSTEM OPERATION SUMMARY - 2002 Soil Vapor Extraction System Operation Summary The SVE system recorded an online operational time of 66.4% during 2002 and recovered approximately 790 barrels (33,180 gallons) of product. The SVE system's down time resulted primarily from the following: 1. Inadequate steam supply from the refinery (14.2% of the available operational time). A planned shutdown to replace the original GAC in all six primary and secondary carbon vessels (5.3% of the available operational 'time). The failure and replacement of the natural gas supply regulator to the oily water separator (4.9% of the available operational time). The length of the shutdown period associated with the regulator failure was exacerbated by a lack of suitable replacement parts within a reasonable timeframe. Not including "scheduled plant shutdown" and refinery-related downtimes (i.e. steam issues), the SVE system recorded a run time of 90.8% of the available operational time. During the scheduled shutdown for. carbon change out, Shell replaced the temporary B-inch HDPE piping from the SVE to the Terminal area with permanent 8- and 10-inch carbon steel piping and installed four knockout pots to remoVe condensate from the system. Frequent interruPtion of the steam supply to the carbon adsorbers was corrected by replacing a faulty 150-pound pressure regulator. Other routine maintenance included: Ten control valves were replaced at the inlet, dilution air, and recycle line of the B, C, and D blowers; Rebuilt the 24-inch vapor inlet valve; Replaced oil pressur;e switches on the B, C, and D blowers; The cooling tower was refurbished during shutdown; Terminal wellhead fittings were upgraded; The Mohawk Area tie-ins were completed; The oily water separator was washed out; and A shed was installed for the OVM meter. These modifications are expected to increase the overall efficiency of the SVE unit. H:~Projects\SH ELL\Bakersfi eld~Final\077-O30~°.eport0 I\RPT01 .doc 7-1 IRM Operation Summary The average efflUent flows from the IRM units were 139 gpm for IRM-1 and 105 gpm for IRM-2. Flow from the individual wells was adjusted based on changing groundwater elevations. Two new extraction wells (EW-12 and EW-13) were brought online for the IRM-1 unit. The pump in EW-3 was malfunctioning and was replaced during the third quarter 2002. The discharge flow from both .of the IRM units was switched out of the Calloway Canal and redirected .to the refinery storage retention pond on September 24, 2002. The North Kern Water District requested this change in order to dry the Calloway Canal for weed removal. Shell notified the California Regional Water Quality Control Board (CRWQCB) of this temporary change, as required by permit. On November 11, 2002, the effluent flow was returned to the Calloway Canal. Air Spar.qin.q Summary The refinery's air sparge system was 100% operational during 2002. The original system consisted of 36 air sparge wells. Ten air sparge wells were installed and added to the system in 2002. Air supply pressure was maintained at 40 psig during the year. Shell redeveloped all of the original air sparge wells to remove accumulated sediments and improve flow in 2002. H :'~Projects\SH ELL~Bakemfield~Final\O77-O30'~eportO I'~.PTO 1 ,doc 7-2 SECTION 8.O GROUNDWATER MONITORING SUMMARY - 4TM QUARTER 2002 Current Project .Phase: Frequency of Monitoring/Sampling: Depth to Groundwater Range: Groundwater Gradient: Groundwater Gradient Consistent with Previous Quarter: MTBE Concentration Range: Well with Highest MTBE Concentration: Benzene Concentration Range: Well with Highest Benzene Concentration: TPHG Concentration Range: Well with Highest TPHG Concentration: Separate Phase Hydrocarbon Thickness Range: Water Supply Wells within 2,000 feet of the site: Surface Water within 2,000 feet of the Site: Current Remediation Techniques: Separate Phase Hydrocarbons recovered this year: Agency Directives: Groundwater Investigation, Interim Remediation, Ongoing Remediation (Refinery VES/Air Sparge Systems), Groundwater Monitoring Quarterly (240 wells) 68.74' - 110.58' bgs (Water table 'declining at approximately 1.7 feet/quarter) 0.0071 ft/ft westerly to southwesterly in the <110' bgs zone 0.0070 ft/ft westerly to southwesterly in the 110' - 140' bgs zone 0.0082 ft#t Westerly to southwesterly in the >140' bgs zone Gradient slightly steeper, but direction unchanged Local, transient mounding occurred due to recharge from Calloway Canal <1.0 - 84,000 ug/L WIP-W3A <0.5 - 4,800 ug/L B-118L <100 - 50,000 ug/L B-118L 0.11 - 1.37 ft D-l, D-2, D-3, D-4, D-5, D-6, D-7, I-1, I-2, I-3, I-4, I-5, I-6, I-7, I-8, I-9, 1-10, 1-11, 1-12, 1-13, 1-14, 1-15, 1-16, P- 31 Calloway Canal (dry) 500' northwest of Terminal, 1,500' northwest of Area 2 Refinery Soil Vapor Extraction, Groundwater Extraction and Treatment, and Air Sparging 160.26 barrels from the refinery SYE system None H:~Projects\SHELL~Bakersfleld~Final\077-030~Report0 I\RPT01 .doc 8-1 SECTION 9.0 DATA QUALITY. REVIEW (FOURTH QUARTER 2002) Seventeen equipment blanks were analyzed in the fourth quarter 2002 groundwater sampling event. One sample (MS2.5A) contained gasoline range total petroleum hydrocarbons at a concentration of 460 ug/L. Benzene, toluene, ethylbenzene, xylene isomers, and MTBE were not detected above analytical method detection limits. No trip blanks were analYzed in the fourth quarter 2002 groundwater sampling event. MS/MSD results for all compounds were generally within control parameters. Ten percent of the results for TBA were out of control parameters due to matrix interference, but, in all cases, the corresponding LCS/LCSD results were within control parameters. LCS/LCSD results for all compounds were generally within control parameters. Fourth quarter 2002 groundwater quality assurance results are summarized in Table 3. Laboratory analytical results and chain-of-custody documentation for groundwater quality assurance samples are included in Appendix B. H:~Projects~SHELL~Bakersfield~Final\077-O30~Report01~RPT01 .doc 9-1 SECTION 10.0 TREATMENT SYSTEM OPERATION SUMMARY The SVE System recorded an online operating time of approximately 79.4%, 39.6%, and 86.4% for the months of October, November, and December 2002, respectively. A substantial amount of downtime for the month of November resulted from the failure of one of the natural gas regulators at the inlet of the OWS unit. The SVE system removed approximately 160.26 barrels of product during the fourth quarter of 2002. The refinery-wide air sparge system operated continuously during the fourth quarter of 2002. The refinery-wide system now consists of 46 well clusters. For the fourth quarter of 2002, all of the sparge well clusters in Area 1 (north of the railroad tracks) were online. In Area 2 (south of the railroad tracks), 28 air sparge wells were online. Both IRM-1 and IRM-2 were fully operational during the fourth quarter of 2002 and operated in accordance with the guidelines provided by Westhollow personnel. H:~Projects\SH ELL~Bakersflelo'~Final\077-O30~,eportO I\RPT01 .doc 10-1 SECTION 11.0 WORK PERFORMED THIS QUARTER (FOURTH QUARTER 2002) Operated and 'maintained the air sparge, SVE, and IRM systems at the Site; Submittal of "3"d Quarter 2002 Groundwater Monitoring Report", prepared by GeoSyntec Consultants; Submittal of the Sales Terminal's "Environmental Indicators Vapor Sampling Report", dated November 11, 2002, prepared by GeoSyntec Consultants; Installed, developed, and sampled groundwater monitoring wells B-201, B-202U, and B-202L in the Westside Industrial Complex. These wells were installed to provide additional sampling points as depth to groundwater continues to increase across the site; Installed and developed groundwater monitoring wells A3-01 through A3-04 in Area 3 of the refinery. Information detailing these well installations will be provided to the CRWQCB under separate cover; and Completed the installation of extraction wells EW-12 and EW-13 in the IRM-1 area to increase groundwater production for the remediation systems. The IRM-1 system was modified in the fourth quarter 2002 to connect these new extraction wells to the system. H:~Projects~SH ELL'~Bakersfield~Final\077-030~Report0 I~RPT01 .doc 11-1 SECTION 12.0 WORK PROPOSED FOR NEXT QUARTER (FIRST QUARTER 2003): A technical report will be completed for the installation of B-201, B-202L, B-202U, and A3-01 through A3-04 in the first quarter of 2003; Perform first quarter 2003 groundwater gauging and sampling event; Manifold the Blending Area SVE well to the SVE system; and Submittal of the Fourth Quarter 2002 NPDES Monitoring Report. H:~Projects~SHELL\Bakersfield~'inal\077-030~Report0 I~RPT01 .doc 12-1 SECTION 13.0 REFERENCES Dale, R.H., French, J.J., and Gordon, G.V., 1966, Ground-water Geology and Hydrology of the Kern RiverAIluviaI-Fan Area, California: United States Geological Survey. Bertoldi, G.L., Johnston, R.H., and Evenson, K.D., 1991, Ground Water in the Central Valley, California- A Summary Report: United States Geological Survey, Professional Paper 1401-A. H:\Projects\SHELL'~lakersfield~Final\077-030~Report0 I\RPT01 .doc 13-1 TABLES H:\Projects~HELL\Bakersfi eld~Final\077-030'~Report0 I\RPT01 .doc Table 1. Well ID 4th Quarterl- Groundwater Levels, Shell Oil Products U, S, Elevation of Measurementi Measuring Point Depth to Product Depth to Water Date ~ Time Elevation Product Thickness Groundwater Surface , (ft-msl) (ft-bmp) (ft) (ft-bmp) (ft-msl) Depth to Top of Screen (ff-bgs) Depth to Bottom of Screen (ft-bgs) B-001L 11/11/02 , 14:10 B-001M 11/11/02 ' 14:13 B-001U 11/11/02 ', 14:15 B-003 11/11/02 , 13:46 B-O07 11/11/02 i 10:32 B-008 11/11/02 ! 14:59 B~009 11/11/02 ' 14:35 B-010 11/11/02 i 10:17 B*011 11/11/02 * 14:30 B-012 11/12/02 I 11:48 B-013 11/11/02 14:22 B-014 11/11/02 ' 10:59 B-017 11/11/02 ' 10:36 B-023 11/12/02 , 10:10 B-024L 11/11/02 ; 14:35 B-024U 11/11/02 , 14:38 B-030L 11/11/02 ' 15:04 B-030M 11/11/02 , 15:05 B-030U 11/11/02; 15:08 B-041L 11/11/02 15:15 B-041M 11/11/02 ' 15:17 B-041U 11/11/02! 15:18 B-042 11/11/02 : 11:58 B-043 11/12/02 11:27 B-044L 11/12/02 ' t1:40 B-044M 11/12/02 , 11:42 B-044U 11/12/02 , 11:44 B-050L 11/11/02 : 13:51 B-O50M 11/11/02 ! 13:54 B-050U 11/11/02 : 13:56 B-052L 11/11/02 , 11:38 B-052M 11/11/02 ; 11:42 B-052U 11/11/02 ', 11:46 B-075L 11/11/02 ; 13:40 B-075M 11/11/02 13:42 B-075U 11/11/02 '~ 13:44 B-098L 11/12/02 i 11:51 B-098M 11/12/02 ' 11:53 B-098U 11/12/02 i 11:55 B-099L 11/11/02 ~ 11:15 B-099M 11/11/02 , 11:18 B-099U 11/11/02 ! 11:22 B-100L 11/11/02 10:49 B-100M 11/11/02: ·10:52 B-100U 11/11/02 ! 10:55 B-103L 11/11/02 , 10:39 B-103M 11/11/02 ' 10:42 B-103U 11/11/02 10:45 B-104L 11/11/02 ' 10:22 B-104M 11/11/02: 10:24 B-104U 11/11/02 i 10:26 B-105L 11/11/02· i 11:27 B-105M 11/11/02 '~ 11:29 B-106L 11/11/02 '~ 11:19 B-106M 11/11/02 11:21 ACCESS - Table 1_Groundwater Quarterly 388.35 390.40 390,38 388,74 383.60 388,27 380,77 383.10 387.53 388.47 386.34 385,21 383,53 383.08 384,45 384.45 388.08 388,08 388,08 382.37 382,37 382,37 389,86 390,79 388,40 388,40 388.40 390.62 390,37 390,98. 388,00 388.00 388.00 384.35 · 384,35 384,35 384,79 384,79 384.79 385.35 385,35 385,35 354,91 384,91 384,91 383,73 383,73 383.73 385,26 385,26 385,26 387,58 387,58 386,23 386,23 ND None 95,21 ND None 90.03 ND None 89,78 ND None 91.76 ND None 107,52 N D None 100.85 ND None 99.65 ND None '110.58 ND None 105,29 88,99 1,56 90,55 ND None 106,39 ND None 98,93 ND None 108.37 ND None 88,04 ND None 109,19 ND None 89,19 ND None 96.97 ND None 94,51 ND None 94.83 ND None 87,97 ND None 85.82 ND None 85,99 ND None 81.7 ND None 93,5 ND None 89,02 ND None 89,73 ND None Dry ND None 84.98 ND None 84,79 ND None Dry ND None 99,84 ND None 97.42 ND None 97,93 ND None 76,63 ND None 80.94 ND None 80.62 ND None 79,99 ND None 78,55 ND None 78,69 ND None 96,94 ND None 96.08 ND None Dry ND None 94.61 ND None 94.74 ND None Dry ND None 94.39 ND None 94.42 ND None Dry ND None 93,07 ND None 93,04 ND None 82,3 ND None 74.18 ND None 73.83 ND None 71,59 ND None 70.68 293.14 300.37 300.60 296.98 276.08 287.42 281.12 272.52 282.24 297.92 279.95 286.28 275.16 295.04 275.26 295.26 291.11 293.57 293.25 294.40 296.55 296.38 · 308.16 297.29 299.38 298.67 Dry 305.64 305.58 Dry 288.16 290.58 290.07 307.72 303.41 303.73 304.80 306.24 306.10 288.41 289.27 Dry 290.30 290.17 Dry 289.34 289.31 Dry 292.19 292.22 302.96 313.40 313.75 314.64 315.55 145,00 100.00 30,00 140.00 140,00 143.00 143.00 150,00 155,00 144,36 174.00 140,00 180,00 136.00 162,70 120.00 129,50 101,50 74,50 129.61 101,73 73,82 114,56 130,00 115.00 88.00 63,00 114,00 86,00 61,00 135,00 108.00 83.00 131.00 105,00 78.00 109,81 79,82 49,83 110,00 80.25 50,00 110,00 80,25 50,00 110,00 80,25 50,00 110,00 80,25 50.00 95,00 65,00 110.00 80.00 200,00 140.00 90,00 180.00 180,00 183.00 183.00 190.00 195,00 184.36 194.00 180.00 200.00 176.00 182.70 150.00 160.00 122.00 95.00 149.61 121.73 93.82 154.56 170.00 135.00 108.00 83.00 134.00 106.00 81.00 175.00 128.00 103.00 150.00 125.00 100.00 140.00 109.82 79.83 140.00 110.25 80.00 140.00 110.25 80.00 140.00 110.25 80,00 140,00 110,25 80,00 125,00 95,00 140,00 110.00 Page 1 of 5 Table 1. Well ID 4th Quarter- Groundwater Levels, Shell Oil Products U. S. Measurement Measuring Point Depth to Date Time Elevation Product (ft-msl) (ft-bmp) Product Thickness (ft) Depth to Groundwater (ft-bmp) Elevation of Water Surface (ff-msl) Depth to Top of Screen (ft-bgs) Depth to Bottom of Screen (ft-bgs) B-107L 11/12/02 10:20 390.51 ND B-107M 11/12/02 10:22 390.51 ND B-108L 11/11/02 11:35 388,61 ND B-108M 11/11/02 11:37 388.61 ND B-10gL 11/12/02 11:56 389,11 76.25 B-109M 11/12/02 11:58 389.11 74.33 B-110L 11/12/02 10:30 392.49 ND B-11 OM 11/1 2/02 10:32 392,47 ND B-111L 11/11/02 14:22 381.34 ND B-111M 11/11/02 14:24 381,34 ND B-114L 11/11/02 11:04 387.19 ND B-114M 11/11/02 11:07 387.19 ND B-114U 11/11/02 11:11 387,19 ND B-115L 11/11/02 11:27 387,38 ND B-115M 11/11/02 11:30 387,38 ND B-115U 11/11/02 11:33 387.38 ND B-116L 11/12/02 10:58 389.46 ND B-116M 11/12/02 11:00 389,49 ND B-117L 11/12/02 10:52 393.32 ND B-117M 11/12/02 10:53 393.34 ND B-118L 11/12/02 10:48 393.06 ND B-118M 11/12/02 10:49 392.99 ND B-119L 11/11/02 10:39 389,46 ND B-119M 11/11/02 10:41 389,56 ND B-120L 11/11/02 10:32 388.74 ND B-120M 11/11/02 10:34 388.76 ND B-121M 11/11/02 10:24 390,88 ND B-124L 11/11/02 14:50 390.20 ND B-124M 11/11/02 · 14:53 390.16 ND B-124U 11/11/02 14:55 389.96 ND B-125L 11/11/02 11:18 391,32 ND B-125M 11/11/02 11:20 391.36 ND B-125U 11/11/02 11:22 391.47 ND B-125L 11/11/02 15:33 389.16, ND B-126M 11/11/02 15:37 389.33 ND B-126U 11/11/02 15:35 389.47 ND B-127L 11/11/02 11:25 392.55 ND B-127M 11/11/02 11:27 392.61 ND B-127U 11/11/02 11:29 392,62 ND B-128L 11/11/02 14:30 395.85 ND B-128M 11/11/02 14:32 395.90 ND B-128U 11/11/02 14:34 395.96 ND B-129L1 11/11/02 10:58 391.50 ND B-129L2 11/11/02 10:56 391.31 ND B-129M 11/11/02 11:03 391.67 ND B-129U 11/11/02 11:06 391.85 ND B-130L1 11/11/02 10:34 392,04 ND B-130L2 11/11/02 10:30 392,29 ND B-130M 11/11/02 10:32 391,91 ND B-130U 11/11/02 10:41 391,86 ND B-131L1 11/11/02 10:45 391.17 ND B-131L2 11/11/02 10:44 391.13 ND B-131M 11/11/02 10:48 391.32 ND B-131U 11/11/02 10:49 391,31 ND Bo132 11/11/02 10:57 390.63 ND ACCESS - Table 1 _Groundwater Quarterly None None None None 0,31 0,16 None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None 74.24 73.41 75.6 ' 73.51 76.56 74,49 74.16 73.93 81.59 81.29 96.12 96,35 81.85 96.98 · 96,56 Dry 77.54 75.23 82,09 80.42 80.18 78.48 76,87 75.21 82.99 79.85 80.53 95.9 91.25 89,79 104.6 99.47 72.52 98.78 97,71 Dry 99.7 96.85 79.61 93.67 91.78 69.39 106.15 106.49 101,72 Dry 108.25 108.66 102.89 92.92 110.22 110.45 103.13 88,1 Dry 316.27 317.10 313.01 315.10 312.55 '314.62 318.33 318.54 299.75 300.05 291.07 290.84 305.34 290.40 290.82 Dry 311.92 314.26 311,23 312,92 312,88 314,51 312,59 314.35 305.75 308,91 310,35 294,30 298,91 300.17 286,72 291.89 318,95 290.38 291,62 Dry 292,85 295,76 313.01 302,18 304,12 . 326,57 285.35 284.82 289.95 Dry 283.79 283,63 289.02 298.94 280.95 280,68 288,19 303.21 Dry 110.00 80,00 110,00 80,00 110,00 78.00 110,00 80.00 100.00 70.00 120.00 85,00 40,00 120,00 85,00 40,00 165.00 100,00 165,00 100,00 165.00 100,00 163.00 100,00 165~0 100.00 100,00 160,00 120.00 30,00 160,00 125,00 30,00 160.00 110,00 30.00 160,00 115,00 30.00 162.00 110.00 30,00 180.00 235.00 120.00 30.00 180.00 235,00 125.00 30.00 190.00 243.00 120.00 30.00 30.00 140.00 110.00 140,00 110.00 140,00 108.00 140,00 110.00 130.00 100.00 150.00 115.00 80,00 150.00 115,00 80,00 175.00 110.00 175,00 110,00 175,00 1.10,00 173,00 110.00 175.00 110.00 135.00 200.00 140.00 90.00 185,00 150,00 70,00 180,00 140,00 80.00 185,00 140,00 80,00 182,00 140.00 70,00 200.00 245.00 145.00 90.00 200,00 245.00 145.00 90.00 210.00 253.00 145,00 85,00 90.00 Page 2 of 5 Table 1. Well ID 4th Quarter - GroundWater Levels, Shell Oil Products U. S. Measurement Measuring Point Depth to Date Time Elevation Product (ft-msl) (ft-bmp) Product Thickness (ft) Depth to Groundwater (ft-bmp) Elevation of · Water Surface (ft-msl) Depth to Top of Screen (ff-bgs) Depth to Bottom of Screen (ft-bgs) B-133 11/11/02 11:10 B-134 11/11/02 11:38 B-143 11/11/02 14:51 B-144 11/12/02 11:54 B-145 11/12/02 16:00 B-146 11/12/02 12:00 B-150M 11/11/02 14:05 B-153 11/12/02 10:07 B-154 11/12/02 10:23 B-156 11/1 2/02 12:08 B-157 11/12/02 13:14 B-159 11/1 2/02 13:25 B.161M 11/11/02 11:55 B-161U 11/11/02 11:58 B-162M 11/11/02 14:10 B-162U 11/11/02 14:12 B-163M 11/11/02 13:50 B-163U 11/11/02 13:48 B-164L 11/11/02 14:00 B-164M 11/11/02 14:02 B-164U 11/11/02 14:04 B-166L 11/11/02 11:10 B-166M 11/11/02 11:11 B-166U 11/11/02 11:13 B-167L 11/11/02 10:10 B-167M 11/11/02 10:12 B-167U 11/11/02 10:14 B-168L 11/11/02 11:05 B-168M 11/11/02 11:07 B-169L 11/11/02 11:12 B-169M 11/11/02 11:15 B-169U 11/11/02 11:17 B-170L 11/11/02 10:30 B-170M 11/11/02 10:32 B-170U 11/11/02 10:34 B-171L 11/11/02 14:22 'B-171M 11/11/02 14:24 B-171U 11/11/02 14:26 B-172L 11/11/02 15:10 B-172M 11/11/02 15:15 B-172U 11/11/02 15:20 B-173L 11/12/02 10:40 B-173M 11/12/02 10:42 B-173U 11/12/02 10:44 B-175L 11/12/02 11:08 B-175M 11/12/02 11:09 B-175U 11/12/02 11:11 B-176L 11/11/02 14:38 B-176M 11/11/02 14:40 B-176U 11/11/02 14:42 B-177L 11/12/02 15:04 B-177M 11/12/02 15:06 B-177U 11/12/02 15:08 B-178M 11/12/02 13:33 B-178U 11/1 2/02 13:35 393.06 392.87 389,27 390.30 391,69 393.21 388,94 391.07 391,76 390.91 392,42 390.31 393,08 392.95 398.25 398.37 398.07 398.01 398.71 398.81 398.96 390.04 390.11 390.30 391.59 391.67 391.75 389.77 389.78 391.41 391.47 391.56 389.75 389.86 369.95 392.87 392.95 392.96 382.96 383.01 383.07 385,79 385.85 385.88 388.00 388.07 388.24 391.14 391.27 391.29 383.25 383.32 383.43 385.25 385.49 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None Dry Dry 75.06 75.08 74.87 74.47 87.81 74.62 74.41 74.6 74.31 74.83 95.3 84.17 97.63 97.61 100.18 87.76 98.94 98.37 84.25 105.23 101.56 Dry 106.94 104.95 102.56 103.25 99.48 101.44 98.87 98.45 98.23 96.92 96.87 102.3 100.38 96.14 82.51 84.13 82.1 86.88 85.85 85.58 87.16 85.11 91.67 91.01 89.26 79.48 78.72 78.15 84.65 83.64 Dry Dry 314.21 315.22 316.82 318.74 301.13 316.45 317.35 316.31 318.11 315.48 297.78 308.78 300.62 300.76 297.89 310.25 299.77 300.44 314.71 284.81 288.55 Dry 284.65 286.72 289.19 . 286.52 290.30 289.97 292.60 293.11 291.52 292.94 293.08 290.57 292.57 296.82 300.45 298.88 300.97 298.91 300.00 300.30 300,84 302.96 303.40 299.47 300.26 302.03 303.77 304.60 305,28 300.60 301.85 30.00 30.00 40.00 40.00 40.00 40.00 90.00 35.00 35.00 35.00 35.00 35.00 110.00 75.00 115.00 80.00 116.00 68.00 114.00 89.50 170.00 120.00 70.00 160.00 120.00 70.00 160.00 118.00 150,00 120.00 90.00 125.00 108.00 92.00 154.00 120.00 80.00 235.00 176.00 148,00 225.00 190.00 150.00 210,00 172.00 140.00 175.00 145.00 115.00 222.00 172.00 144.00 115.00 90.00 90.00 90.00 75.00 75.00 75.00 75.00 110.00 75.00 75.00 75.00 75.00 75.00 120.00 85.00 125.00 100.00 126.00 88.00 134.00 104.00 64.00 185.00 140.00 95.00 1~0.0~ 140.00 105.00 180.00 138.00 170.00 140.00 110.00 140.00 118.00 102.00 164.00 140.00 100.00 245.00 196.00 168.00 240.00 210.00 170.00 225.00 192.00 160.00 190.00 160.00 135.00 232.00 192.00 164.00 120.00 95.00 ACCESS - Table 1_Groundwater Quarteity Page 3 of 5 Table 1. Well ID 4th Quarter - Groundwater Levels, Shell Oil Products U. S. Measurement Measuring Point Depth to Date Time Elevation Product (ft-msl) (ft-bmp) Product Thickness (ft) Depth to Groundwater (ff-bmp) Elevation of Water Surface (ft-msq Depth to Top of Screen (ft-bgs) Depth to Bottom of Screen (ft-bgs) B-179M B- 179U B-180L B-180M B-180U B-181L B-181M B-181U B-182M B-182U B-185L B-185M B-185U B-186L · B-186M B-186U B-187L B-187M B-187U B-188L B-188M B-188U B-195L B-195M B-195U B-196L B-196M B-196U B-201 B-202L B-202U D2 D3 DP2 M14S MN1Z MN2AU MS2.5A PW-L23 PW-L26 PW-L28 PW-U4 R1 R3 R4 R6B RS-6A RS-BW4 RS-DP4 RS-DP5 RS-DP6 RS-DP7 RS-HC7 RS-HC8 11/13/02 g:00 383.03 11/13/02 9:02 383.10 11/11/02 12:00 390.06 11/11/02 12:02 390.18 11/11/02 12:04 390.30 11/11/02 11:48 391.23 11/11/02 11:49 391.30 11/12/02 15:21 391.23 11/12/02 10:50 385.47 11/12/02 10:52 385.54 11/11/02 15:22 391.57 11/11/02 15:24 · 391.69 11/11/02 15:26 391.79 11/11/02 15:13 392.32 11/11/02 15:15 392.43 11/11/02 15:17 392.56 11/11/02 14:50 389.33 11/11/02 14:55 389.60 11/1 2/02 13:29 389.80 11/11/02 14:59 388.57 11/11/02 13:20 388.72 11/12/02 13:22 389.12 11/11/02 15:24 389.67 11/11/02 15:26 389.44 11/11/02 15:28 389.36 11/12/02 15:00 388.42 11/12/02 15:02 388.51 11/12/02 15:03 388.66 12/30/02 9:38 394.16 12/30/02 9:46 388.62 12/30/02 9:43 388.64 11/11/02 11:17 388.29 11/11/02 14:32 378.44 11/1 2/02 11:10 386.07. 11/12/02 13:41 391.55 11/11/02 14:26 389.40 11/11/02 14:21 387.50 11/11/02 14:07 384.62 11/11/02 14:44 382.22 11/11/02 14:40 381.18 11/11/02 14:44 364.01 11/11/02 11:46 388.16 11/1 2/02 11:38 383.42 11/11/02 14:10 '387.20 11/11/02 14:04 388.70 11/12/02 10:29 390.04 11/12/02 16:00 383.41 11/12/02 11:23 379.99 11/11/02 10:28 385.30 11/11/02 13:57 386.27 11/11/02 14:17 381.07 11/11/02 14:56 387.07 11/11/02 14:12 385.77 11/12/02 10:16 381.43 11/11/02 15:26 385.60 ACCESS - Table 1_Groundwater Quarterly ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 80170 ND ND ND ND ND ND ND ND ND ND ND ND None None None None None None None None None None, None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None None 0.13 None None None None None None None None None None None None 80.25 79.16 97.21 95.16 95.01 95.3 93.98 89.66 82.68 81.89 101.03 101.11 97.69 102.31 102.29 98.16 95.50 90.12 89.94 88.81 89.46 97.47 94.31 91.46 104.04 97.08 95.24 89.70 83.70 85.26 90.56 79.75 96.48 88.79 97.41 Dry 88.09 73.77 77.67 75.80 77.12 80,83 83.80 82.58 85.25 82.99 79.47 94.77 98.42 83.60 96.08 92.97 81.66 77.30 302.78 303.94 292.85 295.02 295.29 295.93 297.32 301.57 302.79 303.65 290.54 290.58 294.10 290.01 290.14 294.40 293.83 299.48 299.86 293.73 299.91 299.66 292.20 295.13 297.90 284.38 291.43 293.42 304.46 304.92 303.38 297.73 298.69 289.59 302.76 291.99 Dry 296.53 308.45 303.51 308,21 311.04 302.59 303.40 306.12 304.79 300.42 300.52 290.53 287.85 297.47 290.99 292.80 299.77 308.30 113.00 76.00 150.00 125.00 95.00 150.00 125.00 90.00 120.00 85.00 190.00 165.00 126.00 182.00 165.00 125.00 160.00 125.00 70.00 160.00 110.00 70.00 165.00 122.00 BO.O0 160.00 125.00 75.00 75.00 114.00 97.00 54.00 40.00 92.00 70.00 14.00 20.00 18.00 100.00 90.00 70.00 100,00 12.00 12.00 12.00 12.00 18.00 88.90 105.00 125.00 98.00 129.25 100.00 74.00 74.00 133D0 106.00 170.00 140.00 115.00 165.00 140.00 110.00 135.00 105.00 205.00 180.00 146.00 202.00 175.00 145.00 180.00 145.00 100.00 180.00 140.00 95.00 180.00 152.00 180.00 145.00 105.00 95.00 134.00 105.00 114.00 100.00 105.00 90.00 104.00 80.00 108.00 144.50 138.75 143.00 140.00 105.00 117.00 117.00 117.00 98.00 148.90 134.00 150.00 138.00 149.25 130.00 134.00 134.00 Page 4 of 5 Table 1. 4th Quarter - Groundwater Levels, Shell Oil Products U. S. Measurement Well ID Date Time Measuring Point Depth to Product Depth to Elevation Product Thickness Groundwater (ft-msl) (ft-bmp) (ft) (ft-bmp) Elevation of Water Surface (ff-msl) Depth to Top of Screen (ff-bgs) Depth to Bottom of Screen (ft-bgs) RS-MNIZ 11/11/02 14:02 387.54 RS-MN2B 11/11/02 14:06 385.36 RS-MS2.5 11/12/02 14:11 384.26 RS-MS3A 11/11/02 14:17 384.71 T10A 11/12/02 10:30 391.45 T16A 11/12/02 10:10 390.03 T3B 11/12/02 10:50 391.92 T8B 11/12J02 11:40 390.22 T9A 11/1 2/02 11:46 390.40 TR-2 11/12/02 11:08 390.73 U4 11/11/02 11:50 386.86 WI P-W1 11/11/02 11 .'35 387.39 WIP-W2 11/12/02 13:38 388.43 WIP-W2A 11/12/02 11:30 388.28 WIP-W3A 11/11/02 13:03 390.67 WIP-W4 11/12/02 14:20 389.52 WlP-W4A 11/11/02 12:02 389.61 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND None None None None None None None None None None None None None None None None None 98.26 94.21 87.85 91.95 82.34 80.73 82.73 81.95 82.27 81.71 73.60 Dry 68.74 82.66 83.03 Dry 82.45 289.28 291:15 296.41 292.76 309.11 309.30 309.19 308.27 308.13 309.02 313.26 Dry 319.69 305.62 307.64 D~ 307.16 125.00 105.50 100.00 100.00 73.00 20.00 59.00 70.00 70.00 42.00 35.00 50.00 50.00 20.00 20.00 50.00 19.00 150.00 150.50 149.00 130.00 95.00 50.00 89.00 90.00 90.00 82.00 95.00 70.00 70.00 50.00 50.00 70.00 49.00 ACCESS - Table 1_Groundwater Quarterly Page 5 of 5 Table 2a. 4th Quarter - Monitoring Well Analytical Results, Shell Oil Products, U.S. Gasoline Range . Ethyl- Sample Organics Benzene Toluene benzene Sample ID Date (pglL) (pg/L) (pg/L) (l~g/L) o-Xylene (pg/L) m,p-Xylene (pg/L) MTBE (pg/L) B-O01U B-O01M B-O03 B-O07 B-O08 B-009 B-010 B-011 B-013 B-014 B-017 B-023 B-O24U B-O24L B-O3OM B-O30L B-041U B-041M B..041L B-042 B-043 B-O44M B-O44L B-O50M B-OSOL B-O52U B-O52M B-O52L B-O75U B-O75M B-O98M B-O98L B-O99M B-O99L B-100M B-100L B-IO3M B-IO3L B-104M B-104L B-IOSM B-108L B-111M B-111L B-114M B-114L B-115M B-115L B-116M B-116L' B-117M B-117L B-118M B-118L B- 120M B-120L 11/19/02 ND(lO0) ND(0.5) ND(l) 11/13/02 ND(lO0) ND(O.5) ND(l) 11/13/02 ND(lO0) ND(O.5) ND(l) 11/19/02 ND(lO0) ND(O.5) ND(l) 11/15/02 ND(1 00) ND(O.5) ND(1 ) 11/15/02 ND(lO0) ND(0.5) ND(l) 11/14/02 ND(lO0) ND(0.5) ND(I) 11/19/02 560 23 ND(l) 11/19102 2700 77 140 11/14/02 ND(lo0) ND(0.5) ND(l) 11/14/02 ND(lO0) ND(O.5) ND(l) 11/18/02 ND(lO0) ND(O.5) ND(l) 11/14/02 ND(lO0) ND(O.5) ND(l) 11/14/02 ND(lO0) ND(0.5) ND(l) 11/15/02 2900 2.7 ND(l) 11/15/02 750 ND(0.5) ND(l) 11/18/02 180 ND(0.5) ND(l) 11/18/02 4000 7.8 N D(5) 11/18/02 850 ND(0.5) ND(l) 11/19/02 12000 120 ND(25) 11/20/02 32000 870 1800 11/18/02 ND(lO0) ND(0.5) ND(l) 11/19/02 ND(lO0) ND(0.5) ND(l) 11/12/02 ND(loo) ND(0.5) ND(I) 11/13/02 ND(lO0) ND(0.5) ND(l) 11/19/02 NO(lO0) ND(0.5) ND(l) 11/14/02 ND(lO0) ND(0.5) NO(l) 11/13/02 ND(lO0) ND(0.5) ND(l) 11/13/02 ND(lO0) 2.1 ND(l) 11/13/02 210 4.8 ND(1 ) 11/20/02 ND(lO0) ND(0.5) ND(l) 11/19/02 ND(lO0) 0.52 ND(l) 11/13/02 ND(lO0) ND(O.5) ND(l) 11/14/02 ND(lO0) ND(O.5) ND(l) 11/14/02 ND(lO0) ND(0.5) ND(l) 11/14/02 ND(lO0) ND(O.5) ND(l) 11/12/02 ND(lO0) ND(O.5) ND(l) 11/12/02 ND(lO0) ND(0.5) ND(l) 11/13/02 ND(lo0) ND(O.5) ND(l) 11/13/02 ND(lO0) ND(O.5) ND(l) 11/19/02 430 440 ND(lO) 11/19/02 4000 7.2 N D(5) .11/14/02 ND(lO0) 4.3 2.3 11/14/02 ND(100) 5 ND(1 ) 11/12/02 ND(lO0) ND(0.5) ND(l) 11/12/02 ND(lO0) ND(0.5) ND(l) 11/12/02 ND(lO0) ND(0.5) ND(l) 11/12/02 ND(lO0) ND(0.5) ND(l) 11/20/02 17000 62 41 11/20/02 42000 280 3500 11/20102 19000 · 22 170 11/20/02 46000 820 3000 . 11120102 39000 620 6400 11/20/02 35000 4800 2000 11/14/02 ND(lO0) ND(O.5) ND(l) 11/14/02 ND(lO0) ND(O.5) ND(l) ACCESS - ¢ptGroundwater Quarterly_Table 2a ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) NO(l) 140 NO(l) ND(l) ND(l) ND(l) ND(l). 1.6 ND(l) ND(l) 14 ND(l) 230O 3100 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 1.2 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 18 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 2900 610 2200 1700 1800 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 190 ND(l) ND(l) ND(l) ND(l) ND(l) 1.9 ND(l) . ND(l) ND(5) ND(l) N0(25) ND(l) ND(l) ND(l) ND(t) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) NO(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(lO) ND(5) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 140 5200 2600 4500 3300 ND(l) ND(l) NO(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 1 210 ND(l) NO(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) NO(5) ND(l) 4500 93O0 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 1.7 ND(l) ND(l) ND(l) ND(l) ND(l) ND(t) ND(l) ND(l) 350 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 2800 12000 4900 9600 9300 71 O0 NO(l) ND(l) ND(l) ND(l) ND(l) ND(l). ND(l) ND(l) ND(l) ND(l) ND(2) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) NO(l) NO(5) ND(l) ND(25) ND(25) ND(l) 1.5 ND(l) ND(l) ND(l) ND(l) ND(l) 5.1 9.8 11 42 NO(l) NO(l) NO(l) ND(l) ND(l) ND(t) ND(l) ND(l) ND(lO) ND(5) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 93O ND(25) ND(50) ND(50) ND(SO) ND(l) ND(l) Page 1 of 3 Table 28. 4th Quarter - Monitoring Well Analytical Results, Shell Oil Products, U.S. Sample ID Gasoline Range Ethyl- Sample Organics Benzene Toluene benzene Date (pg/L) (pg/L) (pg/L). (pg/L) o-Xylene (pg/L) m,p..Xylene (pg/L) MTBE (pg/L) B-121M B-124L Bo125M B-125L B-126M B-126L B-128M B-128L B-129M B-129L1 B-130M B-130L 1 B-130L2 B-131 L1 B-15OM B-161M B-152U B-164M B-1 56M B-156L B-167U B-167M B-167L B-168M B-168L B-169U B-170U B-170M B-170L B-171 U B-171M B-171L B-172U B-172M B-172L B-173U B-173M B-173L B-175U B-175M B-175L B-176U B~176M B-176L B-177U B-177M B-177L B-178U B- 178M B-179U B-179M B-180U B-180M B-180L B-181U B-181M 11/14/02 ND(100) .ND(0,5) 11/13/02 ND(100) ND(0,5) 11/13/02 ND(100) ND(0,5) 11/13/02 ND(lO0) ND(0,5) 11/14/02 ND(lO0) ND(0.5) 11/14/02 ND(lO0) ND(0.5) 11/15/02 ND(lO0) ND(0.5) 11/15/02 ND(lO0) ND(O.5) 11/12/02 ND(lO0) ND(O.5) 11/12/02 ND(lO0) ND(O.5) 11/12/02 ND(lO0) ND(O.5) 11/12/02 ND(lO0) 1 11/12/02 ND(lO0) ND(O.5) 11/12/02 ND(100) ND(0.5) 11/13/02 ND(lO0) ND(0.5) 11/14/02 ND(lO0) ND(0.5) 11/18/02 ND(lO0) ND(O.5) 11/20/02 ND(lO0) ND(0.5) 11/13/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) ND(0.5) 11/13/02 ND(lO0) ND(O.5) 11/12/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) N D(O.5) 11/14/02 ND(lO0) ND(O.5) 11/18/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) ND(0.5) 11/13/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) ND(0.5) 11/13/02 ND(lO0) ND(O.5) 11/14/02 N D(100) N D(O.5) 11/14/02 ND(lO0) ND(0.5) 11/1 4/02 ND(100) ND(0.5) 11/14/02 ND(lO0) ND(O.5) 11/14/02 ND(lO0) ND(0.5) 11/14/02 ND(lO0) N D(0.5) 11/19/02 23000 2400 11/19/02 3000 220 11/19/02 570 8 11/15/02 'ND(lO0) ND(0.5) 11/14/02 ND(lO0) ND(0.5) 11/14/02 ND(lO0) ND(O.5) 11/20/02 6300 · 160 11/18/02 9000 420 11/18/02 N D(100) 1.8 11/19/02 ND(lO0) ND(0.5) 11/19/02 N D(100) N D(0.5) 11/20/02 410 N D(1 ) 11/20/02 ND(lO0) ND(O.5) 11/14/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) ND(O.5) 11/13/02 ND(lO0) ND(0.5) 11/20/02 140 ND(lO0) 11/13/02 ND(lO0) ND(0.5) ACCESS - ~ptGroundwater Quarterly_Table 28 ND(l) ND(l) ND(l) ND(I) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 2.1 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(I') ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(I) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(I) ND(l) ND(l) ND(l) ND(I) ND(l) ND(l) ND(l) ND(1) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(I) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(1) . ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(1) 16 ND(l) ND(l) ND(l) ND(l) 56' ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(I) 3.1 ND(l) ND(l) ND(l) ND(l) 1.6 ND(l) ND(I) ND(I) ND(l) ND(I) 7700 620 3200 6600 ND(50) ND(5) 160 ND(5) 38 ND(5) 7.4 26 6.7 62 7.2 ND(l) ND(l) ND(l) ND(l) 4 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) . ND(l) ND(l). ND(20) 1300 240 3300 ND(20) 59 1500 760 2600 ND(20) ND(l) 6.7 4 12 ND(l) ND(l) ND(l) ND(l) ND(l) 38 ND(l) ND(l) ND(l) ND(l) 170 ND(2) ND(2) 7.3 4 260 ND(l) ND(l) ND(l) ND(l) 81 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(200) ND(200) ND(200) ND(200) 9800 ND(l) ND(l) ND(l) ND(l) ND(l) Page 2 of 3 Table 2a, 4th Quarter - Monitoring Well Analytical Results, Shell Oil Products, U,S. Gasoline Range Ethyl- Sample Organics Benzene Toluene benzene Sample ID Date (pg/L) (pg/L) (pg/L) (l~g/L) o-Xylene (pg/L) m,p-Xylene (pg/L) MTBE (l~g/L) B-181L 11/13/02 ND(lO0) B-182U 11/18/02 ND(lO0) B-182M 11/18/02 ND(lO0) B-185U 11/15/02 N D(IO0) B-185M 11/15/02 N D(100) B-185L 11/1 5/02 ND(100) B-187U 11/20/02 ND(lO0) B-187M 11/13/02 ND(100) B-187L 11/13/02 ND(100) B-188U 11/19/02 ND(lO0) B-188M 11/19/02 ND(100) B-188L 11/13/02 ND(100) B-195U 11/20/02 ND(lO0) B-195M 11/20/02 ND(lO0) B-195L 11/20/02 ND(lO0) B-196U 11/13/02 N D(100) B-196M 11/13/02 N D(100) B-196L 11/13/02 ND(100) B-201 12/30/02 N D(100) B-202U 12/30/02 ND(100) B-202L 12/30/02 ND(lO0) D2 11/20/02 8800 D3 11/19/02 ND(lO0) DP2 11/18/02 ND(100) M14S 11/19/02 ND(100) MN1Z 11/19/02 2700 MS2.5A 11/20/02 39000 PW-L23 11/14/02 N D(100) PW-L26 11/1 4/02 3400 PW-L28 11/14/02 N D(100) PW-U4 11/1 4/02 N D(100) R2 11/18~02 970 R4 11/19/02 1000 R6B 11/20/02 20000 RS-6A 11/20/02 7600 RS-BW4 11/15/02 ND(lO0) RS-DP4 11/15/02 ND(lO0) RS-DP5 11/15/02 . ND(lO0) RS-DP6 11/19/02 ND(lO0) RS-DP7 11/18/02 ND(lO0) RS-HC7 11/19/02 1700 RS-HC8 11/14/02 ND(lO0) RS-MN1Z 11/18/02 220 RS-MN2B 11/15/02 ND(lO0) RS-MS2.5C 11/14/02 ND(lO0) RS-MS3A 11/15/02 ND(lO0) T9A 11/20/02 1 40 TIOA 11/20/02 ND(lO0) T16A 11/19/02 ND(lO0) WIP-W2A 11/19/02 ND(lO0) WIP-W3A 11/20/02 50000 WIP-W4A 11/20/02 ND(lO0) Notes: ND(0.5) ND(l) ND(l) ND(l) ND(2) ND(2) ND(0.5) ND(l) ND(l) ND(O.5) ND(I) ND(l) ND(0.5) ND(l) ND(l) ND(0.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(O.5) ND(1 ) ND(1 ) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(0.5) ND(l) ND(!) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(l) ND(2) ND(2) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(0.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(0.5) ND(l) ND(l) ND(0.5) ND(l) ND(l) ND(0.5) ND(1) ND(l) 280 6 590 ND(50) 280 5100 ND(0.5) ND(l) ND(l) 110 2300 160 ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) 1.2 77 4.9 1.5 280 1 40 1700 280 56 540 ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(0.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(0.5) ND(l) ND(l) ND(0.5) 16 130 ND(0.5) ND(l) ND(l) 0.53 ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(O.5) ND(l) ND(l) ND(2.5) 5.1 ND(S) ND(O.5) ND(1) ND(l) ND(O.5) ND(l) ND(l) ND(0.5) ND(l) ND(l) ND(lO0) ND(200) ND(200) ND(0.5) 1.3 ND(l) ND - Indicates Not Detected at the detection limit shown in parentheses. ND(l) ND(2) ND(l) ND(l) · ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l)' ND(l) ND(l) ND(l) ND(2) ND(l) ND(l) ND(l) ND(l) ND(l) NO(l) 180 ND(l) ND(l) ND(I) ND(5) 7900 ND(l) 360 ND(l) ND(l) ND(l) 3.6 190 ND(l) ND(l) ND(l) ND(l) ND(l) 87 ND(l) ND(l) ND(l) ND(l) ND(l) 5.7 ND(l) ND(l) ND(l) ND(200) ND(l) ND(l) ND(2) 1.5 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(2) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(I) 33 25000 ND(l) ND(I) ND(l) 1.8 10 1100 1600 ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(1) 13 ND(l) ND(l) ND(l) ND(200) 1.9 ND(l) 130 1,3 2.3 7.4 4.4 ND(l) 47 NO(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(lO) ND(l) ND(l) 1.7 ND(5) ND(lO0) ND(l) N0(25) ND(l) ND(l) ND(l) ND(l) ND(25) ND(20) ND(l) ND(l) NO(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) ND(l) 84000 ACCESS - rptGroundwater Quarterly_Table 2a Page 3 of 3 Table 2b. 4th Quarter - Water Supply Well Analytical Results, Shell Oil Products, U.S. Gasoline Range Ethyl-. Sample Organics Benzene Toluene benzene Sample ID Date (pg/L) (pg./L) (pg/L) (pg/L) o-Xylene (pg/L) m,p-Xylene (IJg/L) MTBE (pg/L) 0-3 11/14/02 ND(lO0) ND(O,5) ND(l) ND(l) ND(l) ND(l) ND(l) D-6 11/14/02 ND(lO0) ND(0.5) ND(l) ND(l) ND(l) ND(l) ND(l) I-1 11/14/02 ND(lO0) ND(0.5) ND(l) ND(l) ND(l) ND(l) ND(l) I-2 11/14/02 ND(100) ND(0.5) ND(l) ND(l) ND(l) ND(l) ND(l) I-3 11/14/02 ND(100) ND(0.5) ND(l) ND(l) ND(l) ND(l) ND(l) I-6 11/14/02 ND(lO0) ND(0.5) ND(l) ND(l) ND(l) ND(l) ND(l) I-9 11/14/02 ND(100) ND(0.5) ND(l) ND(l) ND(l) ND(l) ND(l) 1-12 11/14/02 ND(100) ND(0.5) ND(l) ND(l) ND(l) ND(l) ND(l) Notes: ND - Indicates Not Detected at the detection limit shown in parentheses. ACCESS - rptGroundwater Quarterly_Table 2b Page 1 of I Table 3 4th Quarter - Quality Assurance Results Shell Oil Products U. $. Well ID B-001U B-008 B-041L B-044M B-100L B-103L B-117M B-130U B-131L B-! 62U B-168L B-175M B-176U B-181U MS2.5A PW-U4 RS-DP6 B-201 B-202L LCD LCD LCD LCD LCD LCD LCD LCD LCD LCD LCD LCD LCD LCS LCS LCS LCS LCS LCS LCS LCS LCS LCS LCS LCS LCS MS MS MS MS MS MS Sample Type EB EB EB EB EB EB EB EB EB EB EB EB EB EB EB EB LCD LCD LCD LCD LCD LCD LCD LCD LCD LCD LCD LCD LCD LCS LCS LCS LCS LCS LCS LCS LCS LCS LCS LCS LCS LCS MS MS MS MS MS MS Sample Date 11/19/02 11/15/02 11/I 8/02 I 1/18/02 11/14/02 11/12/02 11/2O/02 11/13/02 11/12/02 11/18/02 1 !/12/02 11/19/02 11/15/02 11/20/02 11/20/02 11/14/02 11/19/02 12/30/2002 12/30/2002 11/17/02 11/18/02 11/19/02 11/20/02 11/21/02 11/22/02 1 !/24/02 11/25/02 11/26/02 11/27/02 11/30/02 12/01/02 12/02/02 11/17/02 11/18/02 i 1/19/02 11/20/02 11/21/02 11/22/02 1 !/24/02 11/25/02 11/26/02 11/27/02 11/30/02 12/01/02 12/02/02 11/17/02 11/I 8/02 11/19/02 11/20/02 11/21/02 11/22/02 Units %REC %REC OAREC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC %REC TPHG <100 <I00 <100 <100 <100 <100 <100 <100 <100 <I00 <i00 <100 <100 <100 460 <100 <100 <100 <100 93 96 96 102 85 95 107 94 109 93 99 106 99 99 107 88 99 93 87 BENZENE TOLUENE <0.5 <I <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <! <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0.5 <1 <0;5 <1 <0.5 <1 98 97 101 98 96 99 99 97 94 98 109 109 99 109 92 99 92 98 100 102 99 98 100 98 98 99 97 95 94 98 i12 111 93 109 99 98 93 99 100 101 90 88 95 94 98 95 99 96 96 88 ETHYL BENZENE o-XYLENE p/m-XYLENE MTBE <i <1 <1 <1 <1 <1 <I <1 <1 <1 <1 <1 <l <l <l <l <1 <1 <1 <I <l <l <l <l <1 <1 <1 <! <l <l <l <l <l <l <l <l <! <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l· <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l <l _ -- -- 93 .... 95 .... 95 ...... 96 .... 97 -- -- -- 99 _ -- -- 99 .... 97 ..... 96 ..... 102 .... 96 -- -- -- 94 ..... 94 .... 95 ..... 97 ..... I00 .... 92 ..... 98 .... 95 .... 99 ..... 81 ..... 85 ..... 87 ...... 84 .... 80 TAME 89 91 9O 92 97 102 102 94 93 100 90 89 89 92 95 104 91 95 92 97 78 81 82 82 91 ETBE 95 96 98 99 89 108 108 98 96 104 96 95 96 98 90 107 95 98 96 103 83 86 89 88 88 DIPE 93 97 97 104 87 118 95 94 102 96 97 98 103 87 119 94 96 94 101 83 89 92 93 90 TBA 94 97 81 84 76 91 91 95 103 97 98 89 82 82 96 103 96 74 87 '95 74 83 85 86 75(4) Well ID Sample Type Sample Date Units MS MS 11/24/02 %REC MS MS 11/25/02 %REC MS MS 11/26/02 %REC MS MS 11/27/02 %REC MS MS 11/30/02 %REC MS MS 12/01/02 %REC MS MS 12/02/02 %REC MSD MSD 11/17/02 %REC MSD MSD 11/18/02 %REC MSD MSD 11/19/02 %REC MsD MSD 11/20/02 %REC MSD MSD 11/21/02 %REC MSD MSD 11/22/02 %REC MSD MSD 11/24/02 %REc MSD MSD 11/25/02 %REC MSD MSD 11/26/02 %REC MSD MSD 11/27/02 %REC M SD M SD 11/30/02 %REC MSD MSD 12/01/02 %REC · MSD MSD 12/02/02 %REC Notes: '--' = indicates not analyzed '<' = indicates not detected above reporting detection limit '*' = indicate multiple analytical results: Maximum detected value used for detects. Minimum reporting detection limit used for non-detects. Maximum sample date used. Qualifiers: (3) MS/MSD compound out of control-marl'ix interference (4) MS/MSD RPD out of control-maUix interference Table 3 4th Quarter - Quality Assurance Results Shell Oil Products U. S. TPHG BENZENE -- 113 112 ~ 97 93 98 ~ 86 94 99 ~ 98 93 98 -- -- 100 101 -- 108 -- -- ~ 97 -- -- -- 107 91 88 -- 91 95 93 -- a_. 99 97 -- -- 93 98' -- -- 94 98 -- -- 112 111 -- 100 93 99 -- 86 93 98 -- 80 92 99 -- -- 102 102 -- 106 .... 99 -- -- -- TOLUENE ETHYL BENZENE o-XYLENE p/m-XYLENE MTBE 99 96 109' 93 100 83 87 90 89 95 98 88 91 90 101 TAME 101 100 99 90 96 79 82 84 85 92 101 92 96 88 97 ETBE 108 107 111 95 102 84 88 91 92 86 108 97 99 92 104 DIPE 124 96 98 94 101 84 91 95 96 85 120 97 95 91 103 TBA 94 81. 121 97 101 74 85 91 85(4) 78 88 ' 86 81 92 97 Page-I of I FIGURES H:\Projects\SHELL\Bakersfi eld\Final\077-030~Report0 I\RPTO 1 .doc 0 2000 ft. SCALE from U.S.G.S. 7.5 MIN. QUADRANGLE GOSFORD, CA 194-9, PHOTOREVISED 1969 AND OILOALE, CA 1954. PHOTOREVlS£0 1968 ~ FIGURE 1 SITE VICINITY MAP, SHELL BAKERSFIELD ~ REFINERY AND SALES TERMINAL, BAKERSFIELD, TdHydro Corporation CALIFORNIA 920 Sheddan Stme~ Laramie. Wyoming 820}'0 DrawnBy: BW l Checked By: JR I Scale: ASSHOVVN I Date: 01113/03 J Reference: 077USGSSlTE L.__] /i° ROSEDALE HIGHWAY CHARI'P( AVENU[%~tC-R'~UiTVAL£ ¢.XTiCNSiON) AREA 94, ¸OO oO, AREA 91 STREET ._i) EXPU4NA T/ON .... PROPERTY BOUNDARY AREA 92 o o~ ?. AREA 95 (""1 OOO O 0 000 00000 00000 O O O oooo 90' II TriHydro Corpo-r~tl~h 920 Sheridan Street Laramie, Wyoming 82070 Drawn By: DS I Checked By: ,~R,11 Scale: 0 600 ft. SCALE FIGURE 2 SITE PLAN, SHELL BAKERSFIELD REFINERY, BAKERSFIELD, CALIFORNIA 1"= 600' I Date: 01/30/03 J Reference: 077SlTEPLAN 'x%xX --- (._ _. ', /' ..r~B-L15:7 L_ ~: ~ I~ , "% ~-~.~ ~ _~ Cd _ --~ ' - ~- B-'lr6'4'U ~-Bm+62~. ~. , -~ - ~ ~ -~ .... --' ~ ~ ~ , L~ i--Pi ~' LJ ' ' .... ~' ~ ~2 - -: .... ~ ~ , 2 ' ' ' ' .....,' i . '~ [ a C: 16.45 ~ ~ ~] ia 310.35 I ~- I ~---- LINE OF EQUAL EL~ATION OF "-- ~ ~" ~'~ (~ i i POTENTIOM~RIC SURFACE ;... , __, ,,,j~ . __ _ % --~ .. ~ doshed where inferred; hochures : - .... -" ~' [,'/ -. .................... :~-.~ ..... ¢~ .~)~:~ ._j~ ~ delineete depressions in the .~ ~ DIRECTION OF GROUNDWATER FLOW ~! bgs BELOW GROUND SURFACE Il 290.82 ~ 290.07 ~; ~ , b~-n~ ~ J ~ '-- 289 3~ ~ CB- 10~ ....... ~-'-/ .......... I .~ ~'~'Y ~ ~ / ./ l D~, ~ ~ / /' --'V '/~:~/ I' %. I_Z:' ' -'" ;[: B- 1 0 M ~. ' ~.~:::~*~: ~:~ ~ ~ r SCALE , ~ PW-E28 ~' ~ ~ ~ ~ E' ' ¢ 292.22 I ' ~= ~ ~ .I ~ ,,, I~ uu ~ C "~:::::-I ~' il~ ..... ~ ......... :~ ~::::~--¢: ~ ~ ,_ ' ~ ,," ' " .............. =~ ...... - ....... ,- i FIGURE 3 i ' -' ....... ~'~/7. ' , , I . a , U,! ..... POTENTIOMETRIC MAP FOR GROUNDWATER i I : ~ ,~,' ~; j~ L~ ~ '.~:.=~ ,.,- ~ Jj, _.~.~ ~<110'bgs, SHELL BAKERSFIELD REFINERY,' ' ~ ,~'. ', -=~+ ~.- ~ ......... ~'~' ' ..... ~" ._~ I Irl.y=ro i I : -~' - . . ':-Z --. - - ~' ;: ~ ~ ' ~ Corporation ~1 BAKERSFIELD, CALIFQRNIA (November December I 2002) I- · ~-Ii i ~ i = ~ i.i ~ '-:~--; --~'- .... :~ , : I Laramie, Wyoming 82070 '} B-1 6~M \' 290.3 ~- ....... ' _B- f~TM 286.72 / eB- 1 3OM / 288.19 eB- 1 29M 289.95 I I- I- I' 291.52'~' ROSE, 126M I B-165M 297.89 ' 300.l / 128M 304.12 B-131M )M 288.19 B-196M 291.43 290.4 i290.58 eB-O99L RS-MN1Z, 288.4~ 289.28 ]4L LO7 : ! .3 ~ . -.~ .... I i 3A ' 6 . 296.41 ! RS-P6-~ 290,99 AREA 92 /' AREA/~'I I OL 318.33 ! I A~NI. IE B- 1 28M · 304.12 a, EW-09 -....--312-- '-"' bgs EXPLANA ?~ON MONITORING WELL AND NAME (showing potentiometric-surfoce elevation in feet above mean sea level) EXTRACTION WELL AND NAME LINE OF EQUAL ELEVATION OF POTENTIOI~IETRIC SURFACE (in feet above mean sea level; dashed where inferred; hachures delineate depressions in the potentiometric surface) DIRECTION OF GROUNDWATER FLOW BELOW GROUND SURFACE PROPERTY BOUNDARY 0 600 ft. I i I SCALE  FIGURE 4 P, OTENTIOMETRIC MAP FOR GROUNDWATER ~ 1110'- 140' bgs, SHELL BAKERSFIELD REFINERY, TriHydro / BAKERSFIELD, CALIFORNIA Corporation 920 Sheridan Street (November - December 2002) Laramie, Wyoming 82070 By: BW I Checked By: KH Scale: AS SHOWN I Date: 01/29103,I Reference: 077PS1102M Drawn ~ ' L' 1 D 29255 , - 'i ' ~ .......... (, ~ / ~ , (showing potentiometric-surface elevation feet above meon / / j / /, _.7, j ". I i J ~'~29e'471ij .... J~J¢~ Z~ '-I z[ -,'-- ' ,EW-07 EXTRACTION WELL AND NAME // -(:~ i~0 POTENTIOMETRIC SURFACE J .... i : --'; ~- potentiometric surface) ~ L2 : 284.38 j i ' L.._~ ~ 292 2 " " '"~ ~ ' -~,~',~'~"- *' =OTENTIOMETRIC MAP FOR GROUNDWATER >140' bgs, SHELL BAKERSFIELD REFINERY, ___ BAKERSFIELD, CALIEORNIA ............ ....... (November 2002) d y: KH Scale: AS SHOWN J Date: 01129103 J Reference: 077PS1102L B-167U B-1 71 U, <1 B-1 TO,M: EW-04 ~'~; B- 1 g 6 U ·. l "' '~-= ........ =:=~" t-180U· ,, B ~'1,8'.1U 11 B-170U B-04¢M, <1 B-187LJ. ~--~110 ., <1 B-100M · · B-105M <1 DP2 I ,i B-104M 1 AREA 92 MS2.5A <100 4S B-050~t i 1.7 <1 B-'150M <1 ~ AR~ 94 B-O01U 130 AVENUE I AREA 91 B-121M <1 : ! I I B-116M · 9~30 <11] ~,REA 90% ! B-121M .EW-08 MTBE bgs ~g/L £XPLANA T/ON MONITORING WELL AND NAME (showing MTBE concentration in micrograms per liter) EXTRACTION WELL AND NAME LINE OF EQUAL METHYL TERT- BUTYL ETHER (MTBE) CONCENTRATION (in pc~/L; doshed where inferred) METHYL TERT-BUTYL ETHER BELOW GROUND SURFACE MICROGRAMS PER LITER PROPERTY BOUNDARY NOTE: ALL CONCENTRATIONS SHOWN IN jug/L. <1 N 600 ft. i I SCALE TrlHydro - - Corporation 920 Sheridan Street Laramie, Wyoming 82070 Drawn By: DS J Checked By: FIGURE 6 MTBE PLUME CONTOURS FOR GROUNDWATER <110' bgs, SHELL BAKERSFIELD REFINERY, --BAKERSFIELDr CAEIFORNIA ........... (November - December 2002) JL ~'0S£ D~L.~ HIC HWAY .J B-126M ®B~ 150M B-129M* B-lg6M ¢1 EXTENSION ) B-OSOL® <1 B-178M '11o eB-115L <1 <1 B-O99L · · B-11¢L <'1 RS-MN 1Z ® <1 B- 100L · · -~103L I · ~ RS-BW4 ! i~TIO4L· ! ! ! 'F ! RS-MN2B ~ RS-DP7 RS-MS3A RS-DPt5 B-O24U <1 · RS-MS2.5C® <'1 ;-DP6 / <1 eT__ -~ 9.8 AREA 92 i 5~.oo I:M AREA 91 -'i <1 ! B- 108L 90 ! ! TrlHydro 920 Sheridan Street Laramie, Wyoming 82070 Drawn By: DS J Checked By: JR EXPLANA ?ION B-IO8L MONITORING WELL AND NAME (showing MTBE concentrotion in microgroms per liter) AEW-O9 EXTRACTION WELL AND NAME ~!---- LINE OF EQUAL METHYL TERT- BUTYL ETHER (MTBE) CONCENTRATION (in pq/L; dashed where inferred) MTBE METHYL TERT-BUTYL ETHER bgs BELOW GROUND SURFACE flg/L MICROGRAMS PER LITER PROPERTY BOUNDARY NOTE: ALL CONCENTRATIONS SHOWN IN jug/L. 0 600 ft. I ~ I SCALE FIGURE 7 MTBE PLUME CONTOURS FOR GROUNDWATER 110' - 140' bgs, SHELL BAKERSFIELD REFINERY, __BAKERSEIELD,_CALIEORNIA ................ (November - December 2002) Scale: 1" = 600' I Date: 01129/03 J Reference: 077MTBEll02M -- ' ....... , EXPLANA T/ON 'r':. ?'.": ..... j.. _. :t..' -:' ;;i7' ;[, '7 : '-~'J :f "2:':' ' ] '- " ' -':':7~1' ,-12 ., m O<1 :-¥'i ~-'~:T, : i ;: ._.f .. ..... :: ..... ].; .... -.. "-'] :- WATER SUPPLY WELL AND NAME / /'//~' : ~ ¢' :~ ~n .... "; o ~ ' ~ <' , ~~;I E .' i gMTBE METHYL TERT-BU~L ETHER /J /.' : ~ ........... :->=,-:-. ..... u~ 8 ' '- ~~ ..... J:::L ........ I ~g/L ~ICROORA~S PER LITER //- ....,: ,_, .... .... CHCRI A~ ~E ._L~ i '. ..... .- ~ ~ , t J , ___,, : ,. ~k~ ALL CONCENTRATIONS SHOWN IN ~g/L. ._j V , ' - k ~ ' '~ ..... · L, ~-~ · ~ a_ ~, ~- ,~- ....... k*-~] , ~-~4,%M~-~4 ~-~ m~b~-=~-- ~ v~q:=~ ~ ...... ~.~. · ,.,~-~. ~ , .~.,...~~..., , ~ ............. .... ~--I~ , .~3-------. .... ~- . <: ~ ~--- ~. ~J ,' ' i · I . ~~ ~F= ~-'F'-~ ~tE -- !1 .... ~ ,, ~ ;,~ . I ' ~ " ~' JE~''~ ~ ".N ~--'"'~ J : ....... J~ ' ' t ,. , ;il, . ', ' ~2~ :. :~ '. : :: ~ .'" ~ '1-~ //..:'1 SCALE I ' ~ ~ 'll '~ 'ii '~' bi - ~ .- ' ~,~ ~ '~ , f ! [ ' "I~1 ' S , ' ' _ .......... ~ ~ ~: , FIGURE 9 ~ ~ MTBE RESULTS FOR , ~- ...... :-- ...... ~ xx ...... ,~ ~, ~.. . . ,~, ,. ~ .... ~ .i NEARBY WATER SUPPLY WELLS, ~ J ' : .... '~=<~ ~"i I TrlHydro SHELL BAKERSFIELD REFINERY, ..... ~ ............................. ~- - : ,,,,~. ,,, :,. ~,~,~ . ,', - !'l ....................... ~oratio.- - ~l~flfkOr~lkl~O~ll , ' ; ~ '~ -:~.i *::,' ,..." , 920 s~.~., s~, (November 2002) I ' :' - ..... '/ :/~ Drawn By: DS J Checked By: JR I S~le: 1" = 600' I Date: 01~9~3 I Reference: 077MTBEH1102 <0.5 B- 130L2 eB- 1 30L1 <0.5 · :eB-151L1 : <0.5 BiS 166L · <0.5 ieB-O07 <0.5 B-017 <0.5 I eB_010 <0.5 B-O52L · <0.5 ~ 23 RS-DP4 <0.5 <0.5 80Le-"], :'-~B-181L <0.5 \ ~. _...' CHARITY A'~'ENU~-~FRUFP4AI F EXTE~NSION) B-171L <0.s <0.5 B_~75~u <0.5 B-173L <0.5 <0:5 ' AREA 92 <0.5 B-009 B-O24Le <0.5 187L <0.5 B-O03 <0.5 AREA 9~- AREA 91 C STREET, ;q 77,, U"; 16o B-.~ 77M. 420 .~ B-;1771 B-023 17.5U 2,400 0<2~0 Be- 1.1 6L AREA 90':' ! RFFIN£RY A','~NU E ~ eB- 128L <0.5 EXPLANA l/ON MONITORING WELL AND NAME (showing benzene concentration in micrograms per liter) AEW--07 EXTRACTION WELL AND NAME ~ 1---' LINE OF EQUAL BENZENE CONCENTRATION (in p<~/L; doshed where inferred) bgs ~g/L BELOW GROUND SURFACE MICROGRAMS PER LITER .... PROPERTY BOUNDARY NOTE: ALL CONCENTRATIONS SHOWN IN t~g/L. 600 ft. I I SCALE TrlHydro ----C~flO--~-- 920 Sheridan S~eet Laramie. Wyoming 82070 Drawn By: DS I Checked By: JR II Scale: 1" = 600' FIGURE 12 BENZENE PLUME CONTOURS FOR GROUNDWATER >140' bgs, SHELL BAKERSFIELD REFINERY, BAKERSFIEI-D;-GAI-IFORNIA- (November 2002) I Date: 01129/03 I Reference: 077BEN1102L B-167U B-171U, <0.5 '\ 4S ifa, B- 17OM, 1 ~ <o.5 B-05OM<o.5 <0.5 ~-u- B- 170U -'150M EW-O¢ Ic <0.5 <0.5 ,= ;~ ..- B-001U AR~ ~* <0.5 '~,I 178U ' B-044M " ,, B-187U, <0.5 ,- ...... ", T <0.5 ~ ,. ....... F:~ B-195U· ~ ' ¢_-_-' oi <0.5 · B-115M e B-05: <0,5 <0.5 <0,5 B-O99M~ · I-114M <0.5 7 <0.$ B- 100M 103M DP2 I <0.5 D3 .e ~, <0,5 B-030N '~R'6 ~1 d~ 77 ~ I' AREA 92 o~ ~'~ "3 ,~ 3-111M 4,3 AREA 91 B-121M t C STREET, ~440 AREA 90' AVENUE TrlHydro ----Corporation- ' 920 Sheridan Slreet Laramie, Wyoming 82070 Drawn By: DS I Checked By: JR EXPb~NA flOfl eB-121M <0,5 MONITORING WELL AND NAME (showing benzene concentrotion in microgroms per liter) · EW-08 EXTRACTION WELL AND NAME .-----1--' LINE OF EQUAL BENZENE CONCENTRATION (in laC~/L; deshed where inferred) bgs BELOW GROUND SURFACE pg/L MICROORAMS PER LITER PROPERTY BOUNDARY NOTE: ALL CONCENTRATIONS SHOWN IN ~ug/L. 600 ft. i I SCALE FIGURE 10 BENZENE PLUME CONTOURS FOR GROUNDWATER <110' bgs, SHELL BAKERSFIELD REFINERY, BAKERSFIELD,-CALIFORNIA (November - December 2002) B-167L ,~, <1 B,.-=_ 1 66L 7- B=1150L2 eB ~-11 50L1 B-1 29L1 · <1 B-131L1 <1 B-196Le <1 ".LIB_-_ 128L :1 , B-176M LJ B-126L ~, ', CHAR~¥¢ AVEt, IUE'"(¥RuITVALE EX.'~Nfi~ON) B-171L <1 ~!175U :3.1 B-173M ~ 1.6 B- 175L B- 124L <1 <1 B-188L <1 B-003 <1 AREA AREA c STREDr · <,50 <1 · <1 AREA 92 <5¸ 1,,16L 'i AREA 90' ! EXPLANA T/ON · B~128L MONITORING WELL AND NAME (showing MTBE concentration in micrograms per liter) .EW-O7 EXTRACTION WELL AND NAME ~I---' LINE OF EQUAL METHYL TERT- BUTYL ETHER (MTBE) CONCENTRATION (in pg./L; doshed where inferred) MTBE METHYL TERT-BUTYL ETHER bgs BELOW OROUNB SURFACE /Jg/L MICROGRAMS PER LITER .... PROPERTY BOUNDARY NOTE: ALL CONCENTRATIONS SHOWN IN pg/L. B-O52L ·, i m: '~ B-O1 1 I RS-DP4 & <1 : B-014· , ,TOO7 i · } .... ';-- · - I B-O1 7 ~ i <1 , . ',," J - B-O24L· j .J '%T -j AREA 93 <1 B-O09 |mmmmmm mmmm. mm ,? ! TrlHydro --Corporation-- 920 Sheridan Street Laramie, Wyoming 82070 Drawn By: DS 1 Checked By: JR 0 600 ft. SCALE FIGURE 8 MTBE PLUME CONTOURS FOR GROUNDWATER >140' bgs, SHELL BAKERSFIELD REFINERY, BAKERSEIELD,_CALIEORNIA (November 2002) LScale: 1"=600' ~129103 iReference: 077MTBEll02L <0.5 Bi~166M EW-03* · · B- 130M <0.5 <0.5 B- 126M <0.5 ~ B- 1 29 M· <0,$ B-196M <O.S B-171M "='~ <0.5 :'" <0,5 B- <o.5125M 8ti <0.5 " ~'i B- 187M ! j~ <0.5 · 1,~._ ~-:: ~ B-195M .. L ~-~ <0.5 i <0,$ B-050Le <0.5 B - 0 0 I:M AR~ ~a <0.$ 94. ,B-178M <0.5 i-DP6 ' '~ RS-MN 1Z .4/ 0,53 AREA 92 -- r 5RD AVENUE ~J · B-1 15L ·E :<0.5 <O.S ~ B-099Lj · oB-1 1¢L ~ <O,S ; <O.S ! <0,5 I/ '0 AREA 91 ! STREET <0.5 Fq R E'FINE~' A~NUE ~ TrlHydro - --cifloh--- 920 Sheddan S~t Laramie. W~min9 ~?0 Drawn By: DS I Checked By: JR EXP/_,4N,,4 T/ON B-108L i 7.2 MONITORING WELL AND NAME (showing benzene concentrotion in microgroms per Ii[er) ~EW-09 EXTRACTION WELL AND NAME LINE OF EQUAL BENZENE CONCENTRATION (in /Jq/L; deshed where inferred} bgs BELOW GROUND SURFACE lag/L MICROGRAMS PER LITER .... PROPERTY BOUNDARY NOTE: ALL CONCENTRATIONS SHOWN IN pg/L. 600 ft. I I SCALE FIGURE 11 BENZENE PLUME CONTOURS FOR GROUNDWATER 110' - 140' bgs, SHELL BAKERSFIELD REFINERY, BAKERSFIELDFCAUFORNIA (November - December 2002) , S~le: 1"= 600' i Date: 01~9~3 I Re~mn~: 0~BENll02M ,,/ RO S ED,~,LE HICNWA¥ I-6:q ,: ,i_,/1'_-9 -Z<°'5, ,,<tl._~ ' '~ CHARITy AvENu~¢(FR. UrtVALE £XF~NSION) ! ~ ? ~- <, .....0 <0.5 ,,. <0.5 --" I--2 AREA AREA 92 AREA 93 AREA 91 TriHydro --Corporation-- 920 Sheridan Street Laramie. Wyoming 82070 Drawn By: DS [ Checked By: JR EXPLANA 1-ION 1-12 0 <0.5 WATER SUPPLY WELL AND NAME (showing benzene concentration in microgroms per liter) jug/L MICROGRAMS PER LITER .... PROPERTY BOUNDARY NOTE: ALL CONCENTRATIONS SHOWN IN pg/L. 0 600 ft. I 1 I SCALE FIGURE 13 BENZENE RESULTS FOR NEARBY WATER SUPPLY WELLS, SHELL BAKERSFIELD REFINERY, BAKERSFIELD,-CALIFORNIA (November 2002) Scale: 1" = 600' I Date: 01129/03 I Reference: 077BENH1102 / _J i HIGHWAY C ~Rli'r' AVENU~FRUITVALE EX'I'~NS ON) B-198L B- 197L/M .B-049 L/ivi/U i0 0 o00 IB"=-048L/M/U E~ AREA 94 mB-O47L/M/U ~. ~ · m B-074L/ AR-----------------CA 91 C ~TREET ._[1 o8 ,,~- ~ g ~L/M/U., · B- 193L/bl/U mB- 192L/M/U mB- 191L/M/U · B- ~ 90L/M/!. · B- 189L/M, ~< O-078L/M/U m AR~ 92 B-01 AREA 93 · '{3 B-039L/bl/U AV~.NUE 0 j 000 O O 000 00000 00000 0 0 0 ooooo ~ B-O9¢L :,. ..... , u?' ':--- ' 90 1 TriHydro --Corporation .... 920 Sheridan Slmet Laramie. Wyoming 82070 Drawn By: DS I Checked By: JR E,,,vpL~N,4 Z/ON mB-°97L/u/u AIR SPARCING WELL AND NAME .... PROPER'FY BOUNDARY 0 600 ft. I I I SCALE FIGURE 14 AIR SPARGING WELL LOCATIONS, SHELL BAKERSFIELD REFINERY, BAKERSFIEL-D;-C-AL-IFORNIA Scale: 1' = 600' I Date: 01/30/03 I Reference: 077ASWI=I I $