HomeMy WebLinkAboutMITIGATION (3)
I'
I
I
I
I Environmental
I
I
I
I
I
I
I
I
-II
.1
~I
:1
I
I
California
SUPPLEMENTAL SUBSURFACE SITE ASSESSMENT
FUEL IMPACTS IN SOIL
Niagara Car Wash Facility
1701 Stine Road
Bakersfield, CA 93309
SUBMITTED TO
BAKERSFIELD FIRE DEPARTMENT
Office of Environmental Services
1715 Chester Avenue
Bakersfield, CA 93301
Attention: Mr. Ralph E. Huey
FOR
CARWASH OF AMERICA
20280 South Vermont Avenue, Suite 100
Torrance, CA 90502
Attention: Mr. Steve White
CE Job No. EV298-1610 October 1999
EVI61O.RPT
31320 Via Colinas, Suite 104 · Westlake Village, CA 91362 · (818) 991-1542 . (213) 485-0606 · FAX (818) 991-0739
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
TABLE OF CONTENTS
Page
TEXT
EXECUTIVE SUMMARy....................................................................... .... .............. ........................... ii
INTRODUCTION...................................................................................................................... ............1
PREVIOUS WORK................................................................................................................................2
SITE DESCRIPTION.......................................................................................................................... ...4
HYDROGEOLOGy..........................................................................:......... ...........................................5
SUBSURFACE EXPLORATION.................................................................. ............................... .....;...6
SOIL BORINGS................................................................................. ............. ...................................6
SOIL S~LING PROCEDURE......................................................................................................6
EARTH MATERIALS ....................................................................................................................... 7
CHEMICAL ANALySES..................................................................... ............................................... ..8
SOIL................................................................................................................. ........................... .......8
CONCLUSIONS AND RECOMMENDATIONS............................................................................. .... .12
NOTICE..................................................... ........ ............................... ............................................... ....14
TABLE
I. Laboratory Analyses of Soil Samples from Borings.................................................................. ........8
ILLUSTRATIONS
Vicinity Map
Plot Plan
Cross Sections A & B (4 drawings)
Logs of Borings - Plates 1-36
APPENDIX
I. Laboratory Reports and Chain-of Custody Forms
-1-
EVI610.RPT
@
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
I
I
I
I
EXECUTIVE SUMMARY
Three 12,000 gallon underground fuel storage tanks (USTs) and one 2,000 gallon waste oil UST were
installed at the subject site in 1983. A site assessment in February 1997 discovered soil contamination
fÌ"om a release near the northwest corner of the fuel USTs. A leak was found and repaired in December
1997. The USTs were retrofitted to comply with current regulations in 1998. The Bakersfield Fire
Department Office of Environmental Services requested additional assessment of the UST release.
Nine soil borings were excavated to a maximum depth of 140 feet. Soil sampling and analysis was
carried out in accordance with EPA and Regional Water Quality Control Board guidelines. Soil samples
were analyzed in a onsite state certified mobile laboratory. MtBE analyses were confirmed using EP A
Method 8260B.
The maximum contaminant levels found are TPH (gasoline) 290 ppm, benzene 2.9 ppm, toluene 17
ppm, ethylbenzene 4.3 ppm, xylenes 28 ppm, and MtBE 3.2 ppm. TPH, toluene, and xylenes were
detected to a maximum depth of 140 feet in boring B3 but were not found below 105 feet in other
borings. Benzene and ethylbenzene were detected to 120 feet. MtBE was not detected below 110 feet.
No soil contamination was detected in step-out borings. The contaminant plume in soil appears
confined to the subject site.
The estimated depth to groundwater is 170 feet. No continuous saturated zone was detected in the
borings. Thin discontinuous lenses of saturated sand separated and underlain by unsaturated silt layers
were encountered at 60-70 feet bgs. This semi-perched groundwater may originate fÌ"om the nearby
canal. The migration of this water through the vadose zone beneath the property appears to have
assisted in the dispersion and attenuation of fuel hydrocarbons and MtBE. Based on the attenuation of
contaminant levels to non-detect in the vertical and lateral directions and the cessation of the release, it
is considered unlikely that groundwater has been or will be affected by this release. Closure of this case
as a low-risk, soil-only case is recommended.
-11-
EV161O.RPT
@
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 1
INTRODUCTION
The following report presents the findings of the Supplemental Subsurface Site Assessment performed
for the subject property. This work was executed pursuant to a letter request rrom the Bakersfield Fire
Department dated May 24, 1999 and following submittal and approval of a workplan. The purpose of
the study was to determine the current vertical and lateral extent of fuel hydrocarbons impacts associated
with a release of gasoline rrom the underground storage tank system at the subject property.
The scope of work included:
· Preparation of a workplan for approval by the Bakersfield Fire Department.
· Excavation and sampling of seven soil borings.
· Analysis of soil samples in an onsite mobile laboratory.
· Research of standard records sources for nearby groundwater information.
· Preparation of this report.
This report includes GENERAL FINDINGS and CONCLUSIONS AND RECOMMENDATIONS
which together with the remainder of this report are subject to the NOTICE at the end of the report.
EVI61O.RPT
@
I
I
I
I
I
I
I
I
I
I
I
I
I
I
i I
I I
I I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-l61O
Page 2
PREVIOUS WORK
The following documents were reviewed prior to performing the supplemental site assessment:
. Car Wash Partners, Inc. Phase II Site Assessment, Niagara Car Washes, 1701 Stine Road, 23011H"
Street, 7991 White Lane, Bakersfield, CA, dated February 1997 by AJ Environmental, Inc.
Seventeen hand auger borings were excavated on January 21-23, 1997. Borings were placed between
the gasoline USTs, beneath the product piping and dispensers, and near the waste oil UST. Up to 5700
ppm TPH was found at a depth of 18 ft. in boring NCWS#4, near the north end of the easternmost
gasoline UST. Fuel hydrocarbons were found in soil at a depth of 2 ft. beneath all of the dispensers.
TPH levels exceeded 100 ppm at a depth of 6 ft. beneath three of the dispensers. Additional site
assessment was recommended to fully characterize the contaminant plumes.
. Car Wash Partners, Inc., Niagara Car Wash, 1701 Stine Road, Bakersfield, CA 93009, Site
Characterization Report, dated February 1997 by AJ Environmental, Inc.
Four hollow stem auger borings were excavated in the vicinity of the main UST excavation on February
5-6, 1997. Soil types reportedly encountered were sand, sandy gravel, and sandy clay. No groundwater
was encountered in the borings except for a saturated sandy clay reported in boring NCWS#21 at 106 ft.
bgs. A TPH plume estimated at 1,500 cubic yards and extending to a depth of 75 feet was delineated.
The maximum contaminant concentrations found were TPH(gasoline) 12,000 ppm, benzene 52 ppm,
and MtBE 80 ppin. The estimated depth to groundwater based on information from the Kern County
Water Agency was 190 feet. The report concluded that there was no threat to groundwater. The
recommended remedial response was No Action.
EVI61O.RPT
Éi)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-l61O
Page 3
· Preliminary Environmental Site Assessment - Phase I, Niagara Car Wash Facility, 1701 Stine Road,
Bakersfield, California, dated March 25, 1998 by California Environmental.
A Phase I Environmental Site Assessment was performed for the subject property in accordance with
ASTM EI527-97. Historical research showed that the property was occupied by a farm ITom 1937 to
1946. The site was vacant land in 1952. The site was developed with the existing car wash facility in
1983. No conditions of significant environmental concern were discovered other than the gasoline
release from the UST system.
· Workplan, Supplemental Subsurface Site Assessment, Fuel Impacts in Soil, Niagara Car Wash
Facility, UST Permit No. 015-021-000333, 1701 Stine Road, Bakersfield, California 93309, dated
June, 1999 by California Environmental.
Five soil borings were proposed to further define the lateral extent of soil contamination.
· Work Plan for Subsurface Site Assessment at Niagara Car Wash Facility Located at 1701 Stine
Road, Letter ITom Bakersfield Fire Department dated July 22, 1999.
The letter requests revision of the June 1999 workplan to redefme the vertical and lateral extent of
contamination. The letter expressed concern that the leak may have continued for ten months following
the original site characterization in February 1997.
· Revisions for Workplan - Supplemental Subsurface Site Assessment at the Niagara Car Wash
Facility, 1701 Stine Road, Bakersfield, California 93309; UST Permit No. 015-021-000333 dated
August 18, 1999 by California Environmental.
The June workplan was revised as requested by the Fire Department. A total of nine soil borings were
proposed to fully define the vertical and lateral extent of contamination.
EV161O.RPT
@
I
I
I
I
I
I
I
I
I
I
I
I
I
1'1
I
I
I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 4
. Work Plan for 1701 Stine Road, Bakersfield, CA, Letter fÌ"om Bakersfield Fire Department dated
September 1, 1999.
The site assessment workplan was approved.
SITE DESCRIPTION
The subject site is an approximately rectangular parcel encompassing 1.7 acres located between Stine
Road and Hasti-Acres Drive, about 200 feet south ofMing Avenue in the city of Bakersfield, California.
The site is developed with a carwash, gasoline station, Jiffy Lube auto service building, and an auto
detail shop. A lawn area is located to the east of the carwash building and planters are located along the
east and west property lines and west of the carwash building. The balance of the site is paved with
asphalt and concrete. The site features are shown on the PLOT PLAN (see ILLUSTRATIONS).
Three 12,000 gallon gasoline underground storage tanks (USTs) are located west of the carwash
building. One 2,000 gallon waste oil UST is located south of the Jiffy Lube building. Nine fuel
dispenser islands are located beneath a canopy between the carwash and the Jiffy Lube.
The Stine Canal (irrigation and runoft) traverses the site fÌ"om northeast to southwest between the
carwash building and Stine Road. The canal continues beneath the site as a concrete pipe culvert which
extends from north of Ming Avenue to the southern boundary of the site. The canal is an unlined
channel to the south of the site.
EVI61O.RPT
@
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,I
II
I I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 5
HYDROGEOLOGY
The site is located in the Tulare subregion of the Central Valley Groundwater Basin. The basin consists
of a thick accumulation of Quaternary and Tertiary nonmarine sediments. Fresh water occurs in the
sediments to a depth of over 4,000 feet in the vicinity of the site. Texture maps and sections in USGS
Professional Paper 1401-C, Geology of the Fresh Ground-Water Basin of the Central Valley, California
(1986) show that the site is underlain by predominantly coarse-grained sediments including silty sands,
sands and gravels. The laterally extensive clay layers which underlie large areas of the Central Valley
are not shown beneath the subject property.
The Kern County Water Agency was contacted for information on groundwater conditions in the
vicinity of the subject site. Based on their 1998 report of water conditions, the depth to groundwater at
the subject property is approximately 170 feet and the direction of groundwater flow is towards the
southeast.
The current investigation found the site is underlain by silty sand, poorly sorted sand, gravelly sand, and
silt to a depth of 140 feet. Thin discontinuous silt lenses are present in the intervals 65-90 and 105-120
feet bgs. Very little clay is present. Lenses of saturated sand were encountered between silt layers in
some borings. These probable semiperched zones are attributed to percolation of water rrom the unlined
portion of Stine Canal south of the property. No continuous saturated zone was encountered in the
borings.
EV161O.RPT
ɧ)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
'I
II
I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 6
SUBSURFACE EXPLORATION
SOIL BORINGS
Seven soil borings were drilled on September 27-30, 1999 using a CME 85 hollow stem auger drill rig
with 611z inch diameter augers. The locations of the borings are shown on the PLOT PLAN. Borings
Bl, B2, and B3 were placed around the UST pit to determine the vertical extent of contamination.
Boring B4 was placed south of the south middle dispenser island to evaluate the lateral extent of the
UST release and determine whether a significant plume is associated with the dispensers. Borings B5,
B6, and B7 were placed as close as possible to the site boundaries to determine the lateral extent of the
plume from the UST release. Borings Bl, B2, B3, and B7 were drilled to 140 feet bgs. Borings B4, B5,
and B6 were drilled to 90 feet bgs.
All borings were backfilled with high-solids bentonite grout to within 3 feet of the surface and then with
bentonite chips to the surface. The surface was patched with concrete. Soil cuttings were loaded into
lined and covered 10 cubic yard roll-off bins during drilling. The soil was characterized as non-
hazardous and hauled to the USA Waste, Inc. McKittrick Waste Treatment Site by MP Environmental
Services.
SOIL SAMPLING PROCEDURE
During drilling, soil samples were obtained from the borings at five to twenty foot intervals using a
California Split Spoon sampler. The sampling equipment was thoroughly decontaminated between
sampling events using non-phosphate detergent and triple rinsing. The undisturbed samples (no
head space ) were retained in 2 inch diameter by 6 inch long brass tubes which were sealed at both ends
EVI61O.RPT
Éi)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I.
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 7
with teflon film and tight fitting plastic caps. The samples were labeled and submitted to the onsite
mobile laboratory. Chain-of-Custody procedures were followed. The Chain-of-Custody records are
included in APPENDIX I. All laboratory analyses occurred within the allowed holding time. Eighty-
six samples were collected, of which seventy-four were analyzed in the mobile laboratory.
EARTH MATERIALS
Soil encountered in borings consists primarily of cross-bedded, poorly sorted sand, silty sand, and
gravelly sand. Gravel up to 2-3 inches in diameter occurs sporadically in the sands. Gravel is sub-
rounded to rounded. Sand is mostly angular.
Thin (1 in.-l ft. thick) silt layers were encountered in the interval 65-90 feet bgs. A paleosol is
interpreted to be present at depths of 65-70 feet. Silt layers were also encountered in Bl at 105-120 feet.
Silt and silty sands generally contain very little «5%) clay.
Sandy soils are generally light to pale brown except in the intervals 65-90 ft. and 105-120 ft. where silt
and sand are typically yellowish brown to brown.
/""
EV161O.RPT
Éi)
'ÌiIIIIìo....
I'
I'
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1.1
.1
J
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 8
CHEMICAL ANALYSES
SOIL
Selected soil samples were tested in the onsite mobile laboratory for fuel hydrocarbons using EP A
method 8015M and for the volatile compounds benzene, toluene, ethylbenzene and xylene (BTEX) and
methyl tert-butyl ether (MtBE) using EP A method 8021B. MtBE concentrations over 0.10 mg/kg were
confirmed in the fixed base laboratory using GC/MS. The laboratory report is included in APPENDIX
I. The laboratory analyses of soil samples from borings are summarized in TABLE I below. The
laboratory is accredited by the California Environmental Laboratory Accreditation Program.
TABLE I
Laboratory Analyses of Soil Samples from Borings
results in m m
Bl @ 10 ft. nd nd nd nd nd nd
B1 @20ft. 0.1 nd nd nd nd nd
Bl @60ft. 41 0.44 8.0 0.62 4.8 0.050 O.st
Bl @ 70 ft. 60 15 <0.5 4.2 0.93 7.2 8.3 I.~*
Bl @ 80 ft. 7.0 0.13 0.84 0.093 0.76 2.8 /.2.*
Bl @ 85 ft. 0.2 nd nd 0.005 nd 0.006 1.4 /7, ;¡"q*
B 1 @ 90 ft. 0.3 0.014 0.017 nd 0.026 1.9 /,1. ..¡:.
Bl @ 95 ft. 0.1 nd 0.005 nd 0.005 0.16 ONic
Bl @ 100 ft. 0.1 nd 0.006 nd 0.008 0.24 O.D'iflr:/<
Bl @ 105 ft. 0.3 nd 0.031 nd 0.024 0.079
BI @ 110 ft. nd nd nd nd nd 0.10 o. II *
Bl @ 120 ft. nd nd nd nd nd nd
Bl @ 125 ft. nd nd nd nd nd nd
BI @ 130 ft. nd nd nd nd nd nd
BI @ 135 ft. nd nd nd nd nd nd
Bl @ 140 ft. nd nd nd nd nd nd
B2 @40 ft. nd nd nd nd nd nd
B2 @ 60 ft. 0.8 0.057 0.008 0.016 0.014 0.25 0011/':/£
EV161O.RPT
Éi)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 9
TABLE I
Laboratory Analyses of Soil Samples from Borings
results in mglkg (ppm)
Continued
.~ôfm
. .·..w'*~"'~z...·"
".->'".' _::>;'i-,,,~,,<
B2 @ 70 ft. 170 12 0.31 4.2 2.2 17 6.5
B2 @ 80 ft. 0.2 - 0.013 nd nd 0.027 1.0
B2 @ 90 ft. 0.5 - 0.014 0.052 nd 0.043 0.71
B2 @ 100 ft. 0.2 - nd 0.026 nd 0.014 0.034
B2 @ 110 ft. nd - nd nd nd nd nd
B2 @ 120 ft. nd - nd nd nd nd nd
B2 @ 130 ft. nd - nd nd nd nd nd
B3 @ 20 ft. nd - nd nd nd nd nd
B3 @ 40 ft. 0.1 - nd 0.006 nd 0.009 0.014
B3 @ 60 ft. 0.2 - 0.006 0.009 nd 0.011 0.042
B3 @ 70 ft. 6.4 - 0.28 0.98 0.086 0.62 1.3*
B3 @ 75 ft. 290 34 2.9 17 4.3 28 1.3*
B3 @ 80 ft. 0.7 - 0.042 0.015 nd 0.049 1.0*
B3 @ 85 ft. 0.4 - 0.11 nd nd 0.016 0.17*
B3 @ 90 ft. nd - nd nd nd nd 0.058*
B3 @ 100 ft. nd - nd nd nd nd nd
B3 @ 110 ft. 0.5 - 0.015 0.070 0.008 0.052 0.013
B3 @ 120 ft. 0.7 - 0.017 0.091 0.011 0.072 nd
B3 @ 130 ft. nd - nd nd nd nd nd
B3 @ 140 ft. 0.2 - nd 0.018 nd 0.017 nd
B4 @ 10 ft. nd - nd nd nd nd nd
B4 @ 20 ft. nd - nd nd nd nd nd
B4 @ 30 ft. nd - nd nd nd nd nd
B4 @ 40 ft. nd - nd nd nd nd nd
B4 @ 50 ft. nd - nd nd nd nd nd
B4 @ 60 ft. nd - nd nd nd nd nd
B4 @ 75 ft. 0.4 - 0.009 0.006 nd 0.045 1.2*
B4 @ 80 ft. 0.1 - nd nd nd 0.007 3.2*
B4 @ 85 ft. 0.2 - 0.010 0.017 nd 0.021 0.16*
B4 @ 90 ft. 0.2 - 0.018 0.020 nd 0.021 0.46*
B5 @ 20 ft. nd - nd nd nd nd nd
B5 @40 ft, nd - nd nd nd nd nd
B5 @ 60 ft. nd - nd nd nd nd nd
B5 @65 ft. nd - nd nd nd nd nd
B5 @ 70 ft. nd - nd nd nd nd nd
B5 @ 75 ft. nd - nd nd nd nd nd
0.'17*
*
o,'?q
O.S?:I<
0,0'1 ,*-
EV16IO.RPT
@
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 10
TABLE I
Laboratory Analyses of Soil Samples from Borings
results in mglkg (ppm)
Continued
J
w
B5 @ 80 it nd nd nd nd nd
B5 @ 85 it nd nd nd nd nd nd
B5 @ 90 it nd nd nd nd nd nd*
B6 @ 20 it nd nd nd nd nd nd
B6 @ 40 it nd nd nd nd nd nd
B6 @ 60 it nd nd nd nd nd nd
B6 @ 65 it nd nd nd nd nd nd
B6 @ 70 it nd nd nd nd nd nd
B6 @ 75 it nd nd nd nd nd nd
B6 @ 80 ft. nd nd nd nd nd nd
B6 @ 85 ft. nd nd nd nd nd nd
B6 @ 90 ft. nd nd nd nd nd nd
B7 @ 40 ft. nd nd nd nd nd nd
B7 @ 60 ft. nd nd nd nd nd nd
B7 @ 70 ft. nd nd nd nd nd nd
B7 @ 80 ft. nd nd nd nd nd nd
B7 @ 90 ft. nd nd nd nd nd nd
B7 @ 100 it nd nd nd nd nd nd
B7 @ 120 it nd nd nd nd nd nd
MRL 0.1 10 0.005 0.005 0.005 0.005 0.010
TPH = total pe1rolemn hydrocarbons
MRL = Method Reporting Limit
nd = none detected at or above the MRL
* = MtBE analysis by EPA Method 8260 (GeIMS)
EVI61O.RPT
@
I
I
I
I
I
I
I
I
I
I
I
I
I
'1
I
I
, I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 11
GENERAL FINDINGS
Previous site assessments at the subject property produced the following findings:
· The current car wash facility was developed in 1983.
· No recognized environmental conditions were found associated with the uses of the site prior to
1983.
· No recognized environmental conditions other than the UST release were found associated with the
current use of the property.
· In February 1997, subsurface soil sampling revealed a contaminant plume in the vicinity of the
gasoline USTs and minor releases beneath the dispensers.
· A leak in the UST system was found and fixed in December 1997.
The suppiemental subsurface site assessment produced the following findings:
· Maximum TPH and MtBE levels are lower than those found in the February 1997 investigation.
· Maximum contaminant levels found in this investigation are TPH (gasoline) 290 ppm, benzene 2.9
ppm, toluene 17 ppm, ethylbenzene 4.3 ppm, xylenes 28 ppm, and MtBE 3.2 ppm.
· Contaminants were detected to a depth of 140 feet, deeper than the 105 feet found during the
previous investigation.
· Stepout borings near the northeast, southwest, and southeast property boundaries showed no
detectable fuel hydrocarbon impacts.
· Site soils are predominantly sands, with thin silt layers occurring principally in the interval 65-90
feet. Very little clay is present.
· No continuous saturated zones were encountered to a depth of 140 feet bgs. Thin lenses of saturated
sand were found between silt layers in some of the borings.
· Reference sources establish the depth to groundwater at the site at approximately 170 feet bgs.
EVI61O.RPT
Éi)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 12
CONCLUSIONS AND RECOMMENDATIONS
Three 12,000 gallon underground fuel storage tanks (USTs) and one 2,000 gallon waste oil UST were
installed at the subject site in 1983. A site assessment in February 1997 discovered fuel impacted soil
from a release near the northwest corner of the fuel USTs. A leak was found and repaired in December
1997. The USTs were retrofitted to comply with current regulations in 1998. The Bakersfield Fire
Department Office of Environmental Services requested additional assessment of the UST release.
Nine soil borings were excavated to a maximum depth of 140 feet. Soil sampling and analysis was
carried out in accordance with EP A and Regional Water Quality Control Board guidelines. Soil samples
were analyzed in a onsite state certified mobile laboratory. MtBE analyses were confirmed using EP A
Method 8260B.
"f
Q (CÙ C I"'Î. I С ~ ?
( (,.......
The maximum contaminant levels found are TPH (gasoline~ ~pm, ~enz:e 2.9 ppm, toluene 17
'------./
ppm, ethylbenzene 4.3 ppm, xylenes 28 ppm, and MtBE 3.2 ppm. These levels are well below the levels
found during the assessment work conducted in 1997. This pattern of decreasing concentration over
time suggests an ongoing leak was not present onsite. TPH, toluene, and xylenes were detected to a
maximum depth of 140 feet in boring B3 but were not found below 105 feet in other borings. Benzene
and ethylbenzene were detected to 120 feet. MtBE was not detected below 110 feet. The estimated
depth to groundwater is 170 feet.
No soil contamination was detected in step-out borings B5, B6, and B7. The contaminant plume in soil
appears confined to the subject site.
EV16lO,RPT
Éi)
I
I
I
I
I
I
I
I
I
I
'I
I
'I
I
I
I
I
I
I
, 1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 13
No continuous saturated zone was detected in the borings. Thin discontinuous lenses of saturated sand
were encountered at 60-70 feet bgs in borings BI, B2, B3, B5, and B6. Layers of saturated sand are
separated and underlain by unsaturated silt layers. None of the borings had standing water in the hole
after reaching maximum depth. High MtBE levels are associated with saturated samples in several
borings.
The Stine Canal, which traverses the site in a concrete pipe culvert, is an unlined open channel to the
south of the property. Percolation losses from the canal are presumably limited where the canal crosses
the site as a pipe. Infiltration of drainage flow increases to the south where Stine Canal is an unlined
channel. The semi-perched groundwater encountered between silt layers in the southern and central
portions of the site may originate from the canal. The migration of this water through the vadose zone
'"""
beneath the property appears to have assisted in the dispersion and attenuation of fuel hydrocarbons and
~ ~~~~~__- p-" 1 1iØ7!r¡-:---Imt~~~:~~~~~~
MtBE. Based on the attenuation of the contaminant levels to non-detect in the vertical and lateral
~ ---
directions and the cessation of the release, it is considered unlikely that groundwater has been or will be
affected by this release. Closure of this case as a low-risk, soil-only site is recommended.
EV161O.RPT
Éi)
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,
I
I
1701 Stine Road
Bakersfield, California
October, 1999
CE Job No. EV298-161O
Page 14
This report is subject to the following NOTICE:
NOTICE
All properties are subject to some element of environmental risk and the risk cannot be eliminated.
Industrial and commercial properties developed prior to modem environmental laws are especially risk
prone to environmental hazards which include, but are not limited to, wastes which may be toxic,
ignitable, corrosive or reactive. The potential for these environmental hazards to impact the use of the
property can be reduced by the identification and mitigation of the hazards prior to development or
redevelopment of the property. Due to the difficulty in locating underground wastes, in some cases it is
not always possible to ascertain that hazardous wastes are present on the property prior to development.
A Phase I environmental site assessment does not utilize subsurface exploration to check for the
presence of hazardous wastes on the property. The experience of the assessor, along with the research
of available reports, aerial photographs and land use records are used to evaluate the potential for
hazardous wastes to occur on the site. Based on the information gained £rom the audit, subsurface
exploration may be recommended to check for the presence of hazardous wastes. Preexisting
environmental problems such as the presence of hazardous wastes in the soil or groundwater, can be
concealed by grading activities and site improvements. If such wastes are present these wastes cannot
be observed by the auditor.
This report was prepared with the skill and competence as commonly used by environmental
professionals in this area. No warranty, expressed or implied, of any kind is made or intended in
connection with this report, or by the fact you are being furnished this report, or by any other oral or
written statement.
Should you have any questions or desire any additional information, please contact the undersigned.
Respectfully submitted,
Michael R. any
Registered Geologist No. 6750
EV1GIO.RPT
@
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
ILLUSTRATIONS
Vicinity Map
Plot Plan
Cross Sections A and B (4 Drawings)
Logs of Borings - Plates 1-36
EVI61O.RPT
@
B
B1
Patio
B2
AJ18
Bl AJ20
....-.....
, ,
: UST ~
\ I
'--;
,.... .....,
I \
I I
\ I
.... -"
...-.....~
, ,
I \
lUST ND
\ I
'...-;
10
20
30
40
CD
0 50
CO
't:
::s
en
'C 60
c
::s
0
...
CJ 70
a:
0
ã) 80
m
.c
-
c.
CD 90
C
100
110
120
130
Silty Sand
140
~
0.1
1.4
J<'ND
ND Silty Sand
LEGEND
Concentration of TPH in
soil samples, in mg/kg
81
0.1
41
60
7,0
0.2
0.3
TPH >5.0 mg/kg
-NBO·W :>
SCALE
-
o 10 20 feet
1 inch = 20 feet
CROSS SECTION B-B1 - TPH
Niagara Car Wash
1701 Stine Road, Bakersfield, California
CrœÆifo~irœ
ErnwilfornmrernltrϮ
Drawn By:
Job#
ERN
CIB
EV298-1610
Checked By:
Date:
October 1999
1610 cross 99C11on B-B' TPH
B
BI
Patio
B2
AJ18
B 1 AJ20
..-..
, ...
I \
, UST I
\ I
'...-"
.. ..
, ...
t \
, I
\ I
... -;
..-..
, ...
I \
,UST !m
\ ,.
'...-;
10
20
30
40
(1)
0 50
ca
't:
::I
en
"C 60
c:
::I
0
...
~ 70
==
0
ã) 80
m
J:
-
C.
(1) 90
C
100
110
120
130 ND
Silty Sand
140
MtBE >0.05 mg/kg
..~~""","-
~'~<~
""'" " """"~"'I'
"'..."
~~ ).>
LEGEND
Concentration of MtBE in
soil samples, in mg/kg
Bl
ND
0.50
8.3
2.8
1.4
1,9
-N80·W >
SCALE
-
o 10 20 feet
1 inch = 20 feet
CROSS SECTION B-BI - MtBE
Niagara Car Wash
1701 Stine Road, Bakersfield, California
C ([)tÆifOlf7mÆ([)t
lElffvÆlfOnment([)tÆ
Drawn By:
Job#
ERN
CIB
EV298-1610
October 1999
Checked By:
Date:
1610 cross section B-B' MtBE
11 à4 'I ~o.: ,." /)~ .,(,." , '- / . - " II II II' 1L...J~ULJI",a.;1 IUUL...JL:1JL-lL...
d-;" 0 OIIJ~ '0 0 ¡ :' : ~~~. ~~t ~ -.., !f' il==ð \I 110::0\ '~, P1\, ~II¡B:N6PDf1, D/',) ~o[f... C):
'=JJi, 0 I· : : (t~~'~, ¡~~ ¡H : r,"''F1' -"
, I ...JL ~-k {,:: ,,\L
I - .;..:-....1' -l~T! I,~~ f ~¡ . \,..¡..
::l-.!I~~_~_L-:.. .( ~lþ.!J l' -- '\!,,:r i~ : ~~ »r- ' :Ro sev Jt 1,,11"
- .~ :~'~]I / I ~,~~ . II II _ l, f -f .ë! ! ,a.,. 19
~»' " ..,., ." .,' ,,0 ~a , 1'.386 :i il." .. \\ = ~! !; r PI
._ _ J _ :NiB:'.. J. .'.., 1.11, .. r--.. II/' N; .
'- ,,-,,'"'=tiT~.dIT~' ~f'-- / ;-.-.: "..", t - '.1-. : '.. "
~C\ ,=J::11: ,:.;>;~c- ~ = \\ ~ . ö ~. " I,' I ~J~== /: I II.~<""..:
..Ir~~ r ~ ;.;' ".: =," I I " ~ i/ ~
='\. ~ I II II f.'I .q ,L' Mi·
4· '-) " II ""
,J -:--:,"="~¿; If ,,;-. Do"
:;;.--~~~ " ·4 '... _ ~! ,:
~\;.. '. 1;.111'11 '--l t rlll~'.'- ~ - 'I ! \
..~ y~; ~~-~î i'i"\ J! . \ It I o>~j~ ·ægl;, >ey 11 II~' - 1 :
~~ 3 Vi :: ~I~'-'" T, '. i ~U,~JE?T PROPERTYI '-... \~W'l '1'-'-~ \I
JI\il ....~'. ;1:: ,= ~.."...~ -.....J1 '7 [¡Cas r L --n 13'
I, ,::': w, t ~,- ¡:<'O -'=-:Jr.~ ' , i "
~j,~JIíiF.:-;.::., !'~I.~.Hi~:" IGI IL ::.~l~!~h l 1/: ¡SCh:¡1 ,~
... I:: 1..,1 1'1" I . I" I: ~. 1 A t / . .:=
=;~r);:~!.::\; I'"'' .,.1 "; '0 'i2~fI Dê:~ ~~:c=:¡r \ I
?':=;:=~ I . h J' ~ I I II
._.... .-- ~ ,J: . c.. ~ = '_. _ , ._ ==!J ~
.
~ "",:'~:;:I}''-:- . -' I"''':''. . 'II'~ ' - -- ': r ;;;
..'i: ~ i" '" "~ ,!ß1!_¡'~ (\ - · - , ~ rl= ~I \::
, ;.. I Jt:--~'~> ,i=.J. -il n R R ~ Jr---ì1 R!: Tf"er ~fZj .. ,
~ 0 / ... iML ~..J 0 KI:.RN , J \
/~, ,\p=J~;=;", ..-i - Ji' ·1'" I I . ----=-' - If q }
, -" ~.' /' .'11: c:::=J 7: I . ~ 1111 '~
..~,. J/ If . I ·
;1;-' ,:;; /,' ~=-----:I.::'" '. '.' ,i
I /5 :/ . ~ .~... .(' I II- ,.~ '--'" ~... I . = S.ch~ _::I
\ 10/;;0/ : :.' " <' .-JI; JL-J, 1/./. . ILSON ,'- .'. . ROAIb :i_ - -
-..../ ,,' ;;./ ,\ . ill' ,~ .........".,¡ - . : ... \' '.~ . iii 1 ~. .. . ~
~/:" " \~ \f~~ II ~~I ....... ~/ lJL ~ I :
1(.;/ / ~\ - \\.... \\' L: ....... 4 3 I ~
,'" __ -,', ~;f? ~;I 1illlllll -:,.~thl 11-'· II. "-J
./ ~:--~~--' ,,' /-........ r-- ",:]1 =.d=~~ . 'r'- " '~III!I.~: I ;....: ,~::
/ 383 , ' · , I \J '\\ . u:
/--~-'... \ II ' c = ~.\ ,- III/ l
í- '. ;1.,' I L) l'huml"'<>t1 .~. ~' =o,? :-=:J:: ~\ ~PJan·. . ¡ II Þ'
:. I. r HIgh Soh _ II I ;' . II 1. Scb . ~ -¿)' H
. ':.' 37t'-f ..._, - :,~~ Jl7&¡,\\\\:)I ii, it...:..... i, U.ø'
".-.S, ; "/ \~J" \'11" ~H::I: ":",,,,:__,,,",,,.,,-,:.~~~:: .pp a~z/~,
'.... " ,."1'''''''''''' ..' 1;;...."..'''......'''........,:ar,~,I.~
'--', J.:fJ.i .'i.j'::' I ~ . I ./'; ==;¡= =-dL-=lFlnr;;æ'O~~, ...,.'·6 "
\..-,,- I ...r / _ ~ _ _ --,..~! ^ L-JI N:I .. re;.\
':: ';!l2
'.
.
: :')',
"
~:::::"
N
W+E
SCALE
-
o '000 2000feet
1 inch = 2000 feet
s
VICINITY MAP
Car Wash America
1701 Stine Road, Bakeñield
Checked By:
Date:
EV298-1610
October 1999
(California
Environmen7tal
Drawn By:
CER
CIB
Job #
1610 vie map
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B1
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6 Yz inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. I
. I/)
:5 Q) LITHOLOGIC DESCRIPTION Q) 0- 0) -
a. a. u .e: 0 - *' ~
>- 0
Q) t- o CI -I 0 - 1;;
CI Q) u ã: .2 u. ~- c::
Surface Conditions: Asphalt ìñ ::J c:: ~u:
C) a. en ~ .s:::. -Q)
c::Z' U a. :: 1/)-
.¡:: Q) E ~ .- c:: ~O
o Q) en C/) 0 o 0
cc:t:.. C/) ::::> 0 C> ã3 :EO CI~
0
5
- ALLUVIUM -
10 ¡:¡:¡:!§:¡:¡:¡
Silty fine sand, yellow brown, moist, medium dense,
micaceous, no odor.
SM
22
15
20 :¡¡¡¡¡II¡¡¡¡¡¡
Fine to medium sand, pale brown, moist, medium dense, no
odor, occasional gravel to 1/2".
SW
24
25
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
@
PLATE 1
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B 1
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6 Y:z inch
380 feet
. I
~ . I/)
0) LITHOLOGIC DESCRIPTION 0) c- O) ~ Þ
a. "U ,9, 0 -
>- 0 -I 0 0 '00
~ l- e 0 -
ü ,~ LL ~- c
0) a.. - :J C 0)
0) a. en ~ .c:. I/) -0) eLL
c:;:;- ü a. ~ 1/)-
E ~ ,- c ~ü
¡:: 0) (/') 0 o 0
S~ «J :J 0 C> ãi ~ü ee:.
en
26
30 ~¡~I:§m
Fine to medium sand, pale brown, moist, medium dense, no
odor, occasional gravel to 1/2".
SW
36
35
40
::::::::.:.:.:.:.:.
Fine to medium sand, p'ale brown, mois't.-t dense, faint gasoline
odor~ Layer of brown silt, soft, moist in Lnd tube.
SW
ML
48
45
50 i:::i:~I:i:i:i
Silty fine to medium sand, brown, moist, very dense, distinct
gasoline odor.
SM
91
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
@
PLATE 2
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B1
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6Y2 inch
380 feet
. I
. 00
.s=. Q) L I T H 0 L 0 G I C 0 E S C R I PT I 0 N
ã. a. Q) a. C> Õ
.8 - ~
~ "t:I 0 0 è¡':::
Q) 0 0 ...J 0 Q)'- ëñ
0 Q) U .2 LL ....- c:
a.. -- :J c: Q)
C> ëi C/) ~ .s=. 00 -Q) OLL
c:Z" E ü a. 3: 00-
.:: Q) e! .- c: ~ü
o Q) (\ C/) .2 o 0
ID~ U} ::J 0 <.9 ID :2U oe:
52
55
60 ¡¡¡¡¡¡II¡~~¡ Silty fine to coarse sand, pale brown, wet, dense, aromatic SM 47
odor.
65
70 ¡t¡~I¡¡t Silty fine to medium sand, brown, moist, very dense, gasoline SM 86
and aromatic odor.
75
· ·Samp/e Type:
G = Grab
N = No Recovery
SL = Sludge
58 = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610,BG2
@
PLATE 3
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B1
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6 Y2 inch
380 feet
. I
.
.s:::. 0> LITHOLOGIC DESCRIPTION I/)
- c.. 0> a. C> 'ô ~
a. >. -0 .& 0 - ~
0> 0
I- 0 a ...J 0 0>'- ïñ
a 0> ü .2 u. ...- c
Surface Conditions: a.. - :J C 0>
C> ëi en ~ .s:::. I/) -0> au::
.§~ E 0 a. 3: 1/)-
~ .- C è:'U
o 0> co en 0 o 0
(D~ en ::::> 0 (!) m ~U ae:
78
80 ::::::IS¡¡¡¡¡¡
85.
90 I¡1gS¡:¡:¡¡
95 11,···,·,
:¡:¡:¡:::: .....
1 00 11,::,:,:,' '::::::'
::.:.:. ......::::¡¡¡¡¡¡
· ·Sample Type:
EV1610.BG2
Silty fine to medium sand, yellow brown, moist, dense, strong SM
gasoline odor.
Silt and fine sandt mottled brown and dark yellow brown, ML
moist, medium stiff, faint gasoline odor, micaceous, 3 ft.
water in hole.
Silty fine sand, dark yellow brown, moist, very dense, distinct SM
gasoline/aromatic odor.
Silty medium sand, dark yellow brown, moist, very dense, SM
very faint gasoline odor.
Silty fine to medium sand, pale brown, moist, very dense, SM
very faint(?) odor.
G == Grab
N == No Recovery
SL == Sludge
58 == Soil Bulk
5D == Soil Drive
V == Vapor
@
56
39
91
>100
88
W == Water
PLATE 4
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B1
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6 % inch
380 feet
. I
.
.c Q) LITHOLOGIC DESCRIPTION f/)
- a. Q) a. 0) ~
a. >- "C B a - ~
a
Q) I- a a ...I a ~ "jñ
a Q) u 0 LL ~- c:
Surface Conditions: a. :ë -- ~ c: Q)
0) ëi U) f/) au:
c: ........ ~ a. -Q)
.¡: Qj E U ;: f/) -
~ .- c: ~ü
a Q) co C/) ..Q a a
m~ U) :J 0 C!> m ~ü ae:
1 05 ¡¡II~::::::
11 0 ¡¡¡i¡¡I~::iiii
11 5 l:III:¡¡i¡
1 2 0 ~:~i~i!II:¡::::
125 ii:¡iiIS¡¡¡¡¡¡
"Sample Type:
EV1610.BG2
Silty very fine sand, yellow brown, moist, very dense, no SM
odor, micaceous.
Silt, dark yellow brown, moist, medium stiff, no odor, ML
micaceous.
Sandy silt, dark yellow brown, moist, medium stiff, no odor., SM
micaceous. Silty sand layer, 3" thick, wet, in 2nd tube. ML
Sandy silt, dark yellow brown, moist, medium stiff, ML
micaceous. Silty sand, moist, light brown, very dense, no SM
odor.
Silty fine to medium sand, light brown, moist, very dense, no SM
odor.
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
Éi)
81
67
69
91
84
W = Water
PLATE 5
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B1
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1 999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
. >-
. E
.s:::. Q) L I T H 0 L 0 G I C D E S C R I P T I 0 N f/
- c. Q) a. c:n --; Þ
c. >. "0 .s, 0 - c;:.
Q) ..... 0 ...J 0 Q)'- ï;¡
a 0
a Q) ü ã: .~ LL ...- c:
Surface Conditions: - :J c: Q)
c:n a. C/) .s:::. au:
- ~ f/ -Q)
c: - E Ü c. ;: f/ -
.;:: Q) ~ 'õ c: ~~
0 ~ co C/) .Q 0
m C/) ::> 0 (!) m ~ ü a:::::
130 :!:!:!I§¡i:::: Silty fine to medium sand, pale brown, moist, very dense, no SM 88
odor.
135 ¡!!!!!~m!!!!!! Silt mottled brown with dark yellow-brown on partings, moist, ML 76
stiff, no odor.
140 ::::::$.Ö(::: Silty fine sand, light brown, moist, very dense, no odor. SM 93
tt:.::¡:::~;:::mj¡¡
End @ 140 ft., wet at 60 ft., no water in hole.
145
150
155
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
Éi)
PLATE 6
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B2
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. :;-
. w E
.c Q) L I T H 0 L 0 G I C D E S C R I PT I 0 N
- a. Q) a. en ~
a. ~ "C ð 0 - ~
0 ~
Q) 0 0 ...J 0 ëi)
0 Q) U .2 u.. ~- c
Surface Conditions: Asphalt Q. - :J C Q)
en a. C/J .c w -Q) oG:
c:¡:;- E U ~ a. ;: w-
·c Q) ~ .- c c=-U
o Q) ro en 0 o 0
m:=.. C/J ::> 0 <.9 iñ ~U Oe:
0
5
10
15
20 ::::::I§:::::: Silty fine to medium sand, pale brown, moist, dense, no odor. SM 36
25
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
Éi)
PLATE 7
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B2
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6 Yz inch
380 feet
. >-
. I/) E
.L:. 0> L I TH a La G I C 0 E SC R I P T I a N
.... a. 0> c. C) --;) ~
.9: ....
c. >. "0 0 0 ~
0> I- 0 a ...J 0 ïñ
a ü .~ LL. ~.... c:
0> ã: - :J c: ~u:
C) 0.. CJ) ~ .L:. I/) ....0>
c::;:;- E () a. ;: 1/)....
'C: 0> e! .- c: ~()
oJ!! (t CJ) .Q o 0
aJ ....... CJ) ~ 0 C> aJ :2ü ae:
26
30
35
- ALLUVIUM -
40 [\[\[\§Q\[\\j Silty fine sand, light grey, moist, very dense, no odor. SM 89
45
50
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
I EV1610,BG2
Éi)
PLATE 8
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B2
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6 Ÿ2 inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. I
.
.r:. 0> L I T H 0 L 0 G I C D E S C R I P T I 0 N (/)
... a- 0> a. C) ~
a- >- "tJ S: 0 ... ~
0> 0 ~
t- o 0 ...J 0 ïñ
0 0> Ü 0 u.. ~... c:
C) "ã. en a.. :c "- ::J c: ~u:
c: ......... ~ (/) ...0>
... E Ü Co ~ (/) ...
.¡:: Q) ro .Q 'õ c: c:-ü
0 .æ ro (f) ~ 0
a:¡ --- en ::> 0 C> a:¡ :2: Ü oe:
52
- @
55 Gravel 55 ft.
60 ¡::::'=ll:::::: Silty medium to coarse sand, light brown, wet, very dense, SM 70-6"
gasoline odor.
65
70 l:II:::\: Silty fine to medium sand, light brown, moist, very dense, SM 76
gasoline odor.
75
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
Éi)
PLATE 9
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B2
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6 % inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. '>
.
.r:. Q) L I T H 0 L 0 G I C D E S C R I P T I 0 N (J E
.... a. Q) a. C> 'ô ~
a. >- "C .9: 0 .... ():::
Q) I- 0 ...J 0 Q)'- ïñ
a a 0
Q) Surface Conditions: Ü .~ LL ........ c
Q. - :J C Q)
C> c.. U) .r:. au:.
C - ~ (J ....Q)
.... E U a. 3: (J ....
0t: Q) ~ 0- C ~u
0 ~ (IJ U) .Q o 0
a:I - CJ) ::> 0 ø a:I ~ü a~
78
80 ::::::~g:::::: Silty fine to medium sand, light brown, moist, very dense, SM 94
faint aromatic odor.
85
90 ::::::~t-&::: Si!t, mottled brown and dark yellow brown, moist, stiff, ML 83
micaceous, faint aromatic odor.
95
100 ::::::1:1:::::: Silty fine to medium sand, light brown, moist, very dense, ML 76
very faint odor? SM
· ·Samp/e Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610,BG2
GJ
PLATE 10
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B2
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. >-
. E
.c 0) L I T H 0 L 0 G I C D E S C R I P T I 0 N (f)
..... a. 0) a. C> Õ
a. >- "U S: 0 ..... ~
0) 0 ()'::
I- 0 -oJ 0)'- ëñ
C Ü C 0
0) .~ u. ~..... c:
C) ëi (J) D- .c - ::J c: ~u:
.§~ ~ a. (f) .....0)
E Ü ;: (f).....
~ .- c: ~ü
o 0) co en .Q o 0
CIJ~ en ::> 0 <.9 CIJ :2Eü ce:
105
-
110 ::::::11:::::: C1Wey silt, mottled brown and dark yellow brown, moist, ML 90
sti , no odor.
115
120 (\(\(\11;'\(\( Silty fine to coarse sand, light brown, moist, very dense, no SM 79
odor, gravel to 1/2".
125
· ·Samp/e Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
@
PLATE 11
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I.
I
I
LOG OF BORING B2
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 27, 1999
2 inch Split Spoon
CME 85 HSA
6 % inch
380 feet
. >-
. E
..c: Q) L I T H a La G I C D E S C R I PT I a N I/)
- a. Q) c- O> 'õ ~
a. ~ "0 .9: .3 -
Q) 0 c;::.
a 0 a 0 Q)'- ëii
Q) Surface Conditions: ü 0 LL ....- c:
0> ëi (J) a.. :ë -- :J c: ~G:
c:~ ~ I/) -Q)
E ü a. ~ 1/)-
.;:: Q) ~ .- c: ï:=-ü
0 Q) (\ (f) .Q o 0
m~ (J) ::> 0 (!) m :Eü ae:
130 j\j\j\i§\j¡j\j Silty fine to medium sand, light brown, moist, very dense, no SM 87
odor.
135
140 ::::::11::::::
Silty fine to medium sand, light brown, moist, very dense, no SM
odor.
77
End @ 140 ft., show of water @ 60 ft., no water in hole.
145
150
155
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
Éi)
PLATE 12
---=-~-=-
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B3
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6 Y2 inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. I
.
.t: Q) L I T H 0 L 0 G I C D E S C R I PT I 0 N (/
- a. Q) a. C) Õ
a. >. "C a 0 - ~
Q) 0 ~
I- 0 0 ...J 0 Q);::'" "Ii)
0 Ü
Q) Surface Conditions: Asphalt .2 u. ....- c:
C> ëi. CI) a.. .t: -- ~ c: ~u:
c::;:;- ~ a. (/ -Q)
E Ü ;: (/ -
'C: Q) ~ .- c: ~ü
o Q) co CI) 0 00
CD:t:. CI) ::> 0 <.9 ã5 :2U o~
0
5
10
15
- ALLUVIUM -
20 jj¡jjj~§Ijj Silty fine to medium sand, pale brown, moist, dense, no odor. SM 33
25
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610,BG2
Éi)
PLATE 13
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B3
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6 % inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. >-
. E
.r- Q) L I T H 0 L 0 G I C D E S C R I PT I 0 N (/)
+-' a. Q) a. CI --;; Þ
S: +-'
a. >. 'U 0 0 c;:.
Q) I- 0 ...J Q);:;"" ëñ
0 Ü 0 0
Q) 0 u. ::;1: c:
a. :ë - ~LL
0) a. en ~ (/) +-,Q)
c:~ E Ü a. ~ (/)+-'
.¡:: Q) ~ .- c:: ~ü
o~ ro en 0 o 0
aJ_ en ::::> 0 (!) ã5 :2:ü cd!:-
26
30
35
40 ::::::I:g¡¡¡¡¡¡ Silty fine to medium sand, pale brown, moist, very dense, no SM 83
odor.
45
50
· ·Samp/e Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610,BG2
Éi)
PLATE 14
I
I
I
LOG OF BORING B3
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
I
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6 % inch
380 feet
. I
I . I/)
.r::. 0) LITHOLOGIC DESCRIPTION
- a. 0) Co 0') --;;-
.e, - Z-
a. ~ "0 0 0 e:¡::.
0) 0 0 ..J 0 0);:"" ï;)
0 0) () g LL ~- c:
a. - :J c: t3û:
0> a. en ~ .r::. I/) -0)
I c:~ E () a. :;: 1/)-
"L: 0) (I:! .- c: ~()
o 0) (I:! en ~ 0 o 0
cc:t:;. en => 0 <.9 m ::2:ü oe:
52
I
I
55
I
1
60 ¡1¡1¡1111:1:1:
I
I
65 \:\:\:19::::::
I
I
70 11111111&1111
I
I
75.", ':':'
.... ........
I
I
· ·Sample Type:
'I
EV1610,BG2
Silty fine to medium sand, pale brown, very moist, very
dense, no odor, occasional gravel to 1/2".
SM
Silty sand, light brown, wet, very dense, slight aromatic door. SM
Silty fine to medium sand, brown, saturated, dense, aromatic SM
odor, gravel to 2".
Silty fine to medium sand, brown, saturated, very dense,
aromatic door.
SM
G = Grab
N = No Recovery
SL = Sludge
5B = Soil Bulk
5D = Soil Drive
V = Vapor
Éi)
86
90
40
89
W = Water
PLATE 15
I
I
I
I
LOG OF BORING B3
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRill RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
. >-
. E
..r:: Q) LITHOLOGIC DESCRIPTION I/)
..... a. Q) a. C> "';' ~
a. .9: .....
>- "C e e è¡'::
Q) l- e 0 ...J 0 Q)'"'"' ïñ
0 Q) u ã: 0 u.. ........ c:
Surface Conditions: :ë -- :J c: Q)
C> a. C/) ~ I/) .....Q) oíL
c::;:;- E U a. ;: 1/).....
.¡;: Q) ~ .- c: ~u
o Q) ro C/) 0 e 0
m:t:.. en => 0 (9 ã5 :?:u o!?;-
78
I
I
I
I
I
80 jjjjj:§p::::::
85.
I
I
I
I
I
I
I
I
I
I
90.
95
1 00 ::j:::I~jj:::j
"Sample Type:
EV1610,BG2
Sandy silt, mottled brown and yellow brown, moist, stiff,
aromatic odor.
ML
Silt, light brown, moist, stiff, aromatic odor.
ML
Silty fine to medium sand, yellow brown, moist, very dense,
no odor.
SM
Silty fine to coarse sand, pale brown, moist, very dense, no
odor. Sandy silt, brown, in shoe.
SM/ML
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
Éi)
54
52
89
84
W = Water
PLATE 16
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B3
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. I
. (/
L: 0) LITHOLOGIC DESCRIPTION
+-' a. 0) a. C> ~ ~
.9: +-'
a. >. <:J 0 0
0) I- 0 0 ..J 0 ~ ëñ
0 U .2 LL ~+-' I::
0) Surface Conditions: a. - :J I:: 0)
C) a. C/') ~ L: (/ +-,0) oU:
1:::;::;- E U a. 3: (/ +-'
.¡:: 0) co .- I:: è:'u
o 0) co C/') .... .Q o 0
1D:t:.. C/') ::> 0 C> ID ~U oE!:
105
11 0 I::l:g¡¡¡¡¡:
Silty fine to medium sand, light yellow brown, moist, very
dense, no odor, occasional gravel to 1/2".
SM
86
115
1 20 I::~I::::::
Silty fine to medium sand, light yellow brown, moist, very
dense, very faint, aromatic oaor.
SM
101
.
125
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
Éi)
PLATE 17
I
I
I
I
i I
I.
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B3
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6 Yz inch
380 feet
.
.
J:: Q)
- a.
a. >-
Q) l-
e Q)
g>:;:;- "ã.
o¡:: Q) E
OQ) co
a:I:t:.. C/)
130 ::Iiii::::::
:.:.:.:.:.:.:.:.:.:.:.:.:.:
135
140 jjjjjj~gjjjjjj
145
150
155
"Sample Type:
EV161 Q,BG2
LITHOLOGIC DESCRIPTION
(/)
Q)
u
o
U
C/)
Ü
C/)
::>
SM
Surface Conditions:
Silty fine sand, pale brown, moist, very dense, no odor.
Silty fine to medium sand, pale brown, moist, very dense, no SM
odor.
End @ 140 ft., no water.
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
Éi)
>-
E
a.
.B:
0)
o
...J
.2
J::
a.
~
(!)
-
o
o
u.
-
(/
~
o
iñ
83
e
a.
~
o
50-6"
W = Water
õ
~
Q);;:""
...-
:J C
-Q)
(/ -
.- C
00
~ü
~
"Ii)
C
~u:
~U
ee:
PLATE 18
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B4
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6 % inch
380 feet
. î
£ . II)
Q) L I T H 0 L 0 G I C D E S C R I P T I 0 N Q) a. C! ;?
a. S: ..... ~
a. >. "C 0 0
Q) I- 0 C ...J 0 ~ ïii
e U 0 LL ~ ..... c:
Q) Surface Conditions: D- E - :J c: Q)
C! ëi C/) ~ II) ..... Q) eLL
c: ........ Ü a. ~ (f .....
.¡:: ..... E œ '0 c: ~u
Q) en 0 0
0 ~ co :J 0 (9 ã.i ~ u e~
m (j)
0
5
- ALLUVIUM -
10 ::::::11:::::\ Sandy silt, yellow brown, moist, soft, no odor. ML 41
15
20 :¡¡¡¡¡~~¡I: Silty fine to medium sand, light brown, moist, very dense, no SM 65
odor.
25
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
ÉiJ
PLATE 19
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B4
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6 % inch
380 feet
. >-
. I/) E
L: 0> L I T H 0 L 0 G I C D E S C R I P T I 0 N
- C. 0> a. 0) "';' þ
S: -
c. ~ "ö 0 0 ()'<:
0> 0 0 ...J 0 0>'""' ëñ
0 Ü .2 u. c
0> ä: - 51: t3u:
C) - a. en :< L: I/) -0>
c - E Ü c. ~ 1/)-
.¡:: 0> e! .- c ~u
0 ~ ro en > o 0
a:I en ::::> 0 (9 a:I ::æ:u oe:
26
30 :¡:¡:¡~gi:i:¡: Silty fine sand, pale brown, moist, dense, no odor. SM 35
35
40 :::¡::IP¡¡¡¡¡: Silty fine sand, pale brown, moist, very dense, no odor. SM 83
45
50 ::ti.B:t: Silty fine to medium sand with gravel, light brown, moist, SM 71-6"
::::::::::::::::::::::::;:: very dense, no odor.
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
@
PLATE 20
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I.
I
I
LOG OF BORING B4
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6 Yz inch
380 feet
. >'
.
.r:. 0) L I T H 0 L 0 G I C D E S C R I P T I 0 N I/) E
.... a. 0) c. 0> ~
a. ~ "C 8 0 .... C¡:::: ~
0) 0 ....J 0 ëñ
e e 0 0)""'
0) U .~ LL Lo.... c:
0> c.. en a.. .r:. - :J c: 0)
c ......... ~ I/) ....0) eLL
.... E U a. 3= 1/)....
.¡:: 0) !!! .- c: è:'U
0 J!! <11 en 0 o 0
aJ --- en :J 0 ø ëë ~U ee:
52
55 55-60 ft., gravel to 1" .
60 ¡:¡:¡:~I:¡:¡:¡ Silty fine to coarse sand with gravel, light brown, moist, very SM 111
dense, no odor.
65
70 ~:~::~wl::::::
75 ~~~¡~¡8~¡~¡~¡~ Silty fine sand, yellow brown, very dense, moist, distinct SM 67
aromatic odor.
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
@
PLATE 21
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING B4
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28, 1999
2 inch Split Spoon
CME 85 HSA
6 % inch
380 feet
. >-
. E
.s:: 0) LITHOLOGIC DESCRIPTION (/J
- a. 0) 0- 0> --;; ~
a. >. 'U 8 0 - ():::
0) I- 0 ...J 0 0)'- ëñ
a 0 0
0) Surface Conditions: U .2 u. .....- c::
ë: - ::J c:: 0)
0> a. en .s:: (/J -0) aLL
c::z- E () ~ a. ~ (/J-
.¡:: 0) e:! .- c:: è:'U
o 0) ro en > 00
CD~ en ::J 0 (!) ã5 ~U oe:
78
80 :¡¡¡¡¡IR::::::
Silt with very fine sand, yellow brown moist, stiff, aromatic ML
odor, silty fine to medium sand in shoe. SM
67
85 .··::!I:
. .......
...-....
Silty fine to medium sand, light brown, moist, no odor. SM
65
90 ¡¡¡¡¡¡Ifli:i:i:
Silt, mottled brown and dark yellow brown, moist, stiff, no
odor. ML
End @ 90 ft., no water.
75
95
100
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
S8 = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
@
PLATE 22
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING 5
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28 and 29, 1999
2 inch Split Spoon
CME 85 HSA
6 Y2 inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. >-
.
.c:: 0) L I T H 0 L 0 G I C D E S C R I PT I 0 N 00 E
- c.. 0) a. C> ~ ~
c. ~ "0 S: 0 -
0) 0 ...J 0 ~ ïii
0 0 0
0) Surface Conditions: Asphalt U il: 0 LL ~- c:
C> "ã. C/) :.c -- ::J c: 0)
c:Z" ~ 00 -0) OLL:
E u c. == 00-
.e: 0) ~ .- c: ~U
o 0) co C/) .Q o 0
m~ C/) ::J 0 C> m :2:U oe:
0
5
10
15
- ALLUVIUM -
20 !i:i:i~!I¡:¡:¡: Fine to medium sand, pale brown, moist, medium dense, no SW 28
odor.
25
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
Éi)
PLATE 23
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
II
II
I
I
LOG OF BORING 5
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28 and 29, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
. '>
. E
.t: 0) L I T H 0 L 0 G I C D E S C R I PT I 0 N (/
- a. 0) a. C> Õ Þ
a. ~ 1:J 8 0 -
0) ,0 'i3':::
0 0 -..J 0 0);::"" ëñ
CI 0) () .2 u.. ...- c:
C1.. - ::! c: 0)
C> ëi (f) ~ J:: (/ -0) oG:
c::;::;- E () c.. ~ (/ -
.¡: 0) ~ .- c: ~ü
o 0) co (f) o 0
m~ (f) :J 0 C> ã5 ~() oe:
26
30
35
40 ~¡¡¡¡¡~I¡¡¡:¡: Silty fine sand, pale brown, moist, very dense, no odor. SM 85
45
50
· ·Samp/e Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
Éi)
PLATE 24
I
LOG OF BORING 5
I
I
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 28 and 29, 1999
2 inch Split Spoon
CME 85 HSA
6 Yz inch
380 feet
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
I
I
I
I
I
I
. î
.
.c Q) L I T H 0 L 0 G I C D E S C R I P T I 0 N (/)
..... a. Q) a. 0> --;;
a. ~ "0 .8 0 ..... ~
0 C¡:::
Q) 0 a ...J 0 Q)~ ïñ
a Q) u .2 u. ........ c::
a. - :J c:: Q)
0> "õ.. C/) .c (/) .....Q) aU:
c:: ....... ~
..... E u a. 3= (/) .....
.¡:: Q) ~ 'õ c:: ~()
0 ~ ('( en .Q 0
a:I en ::> 0 {!) a:I :E () a~
52
-
I--
55
-
60 III Gravelly silty sand, light brown, wet, very dense, no odor, SM/GW 71-6"
gravel to 2".
65 II Gravelly silty sand, light brown, wet, very dense, no odor. SM 72
70 !!!!!!II!!!!!! Silty fine to medium sand, grey, wet, very dense, no odor. SM 64
Gravelly silty sand, wet. SM
Clayey silt, mottled light brown and dark brown, medium firm, ML
no odor. 21/24/40
75 . Silty fine sand and sandy silt, light brown, moist, very dense, SM/ML 41/50
no odor, thinly bedded.
I
I
I
I
I
I
I
I
I
I
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge'
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
ÉiJ
PLATE 25
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING 5
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
September 28 and 29, 199~
2 inch ~plit Spoon
CME 85 HSA
6 Yz inch
380 feet
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
. >-
. E
.c Q) LITHOLOGIC DESCRIPTION I/)
..... a. Q) c- O) Õ ~
a. ~ -0 .eo 0 .....
0 e;:::
Q) 0 CI -I 0 Q)'- ïñ
CI Q) Ü 0 u. ......... c
Surface Conditions: a. :ë -.. :::J C Q)
0) "ã. (J) ~ I/) .....Q) Clíi
C ....... E ü 0- ;: 1/).....
"¡:: Q) co .- C ~u
o Q) co (J) .... 0 o 0
aJ~ en ::> 0 (!) m ~U Cle:
78
80.""',::::::
...:::if
85 .,.:... .:'",
:':':':', ....:
.:.:.:.:. :.
90 ~i~i~i~ä¡i~i:
95
100
"Sample Type:
EV1610.BG2
Silty fine to coarse sand, light yellow brown, moist, very
dense, no odor.
SM
94
Fine sand, light yellow brown, moist, very dense no odor,
rounded ancf polished, inclined layers of rounded magnetite
grains.
SP
98
Silty fine to medium sand, light yellow brown, moist, very
dense, no odor. Fine silty sand in shoe.
End @ 90 ft., show of water at 60-70 ft., no water in hole at
end.
SM
73
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
Éi)
PLATE 26
I
I
I
I
I
,I
I
II
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING 6
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 29, 1999
2 inch Split Spoon
CME 85 HSA
6 Y2 inch
380 feet
LOGGED By:
. î
. (
..c: Q) L I T H a La G I C 0 E S C R I PT I a N
..... c- Q) a. C) 'Ô ~
8: .....
a. >- "C 0 0 ()::::
Q) I- 0 D ...J 0 Q):::"- "jñ
D Q) u ë: 0 u.. ......... I::
Surface Conditions: Asphalt 1: - ::J I:: ~LL
C) õ.. Cf) ~ ( .....Q)
1:::;::;- E ü c. ~ ( .....
.¡: Q) ~ .- I:: ~u
o Q) co Cf) o 0
m:=. Cf) :J 0 ø ãj ~U De:
0
5
10
15 - ALLUVIUM -
20 ¡!¡~!I~!¡!¡!¡ Fine to medium sand, pale brown, moist, dense, no odor. SW 41
25
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W :::;: Water
EV1610.BG2
~
PLATE 27
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING 6
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 29, 1999
2 inch Split Spoon
CME 85 HSA
6 Ÿ2 inch
380 feet
. I
. 00
..r::. Q) L I T H 0 L 0 G I C D E S C R I PT I 0 N Q) c- O> 'Ô
- a. ð - ~
a. ~ "C 0 0 ()"::
Q) 0 CI ...J 0 Q)'- ïñ
CI Q) Ü .~ LL ....- c
D.. -- :J C Q)
0> Õ. CI) ~ ..r::. 00 -Q) Clí::ï:
cZ' E ü a. ~ 00-
.¡:: Q) co .- C ~ü
o Q) co CI) > .... o 0 CI~
en:::.. CI) ::> 0 C> en ::2:ü
26
30
35
40 ¡¡¡¡¡¡II¡¡¡¡¡¡ Fine sand, pale grey, moist, very dense, no odor. SP 99
45
50
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
Éi)
PLATE 28
I
I
I
I
I,
I
I
I
I
I
I
I
I
I
I
I
I
I
I
LOG OF BORING 6
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 29, 1999
2 inch Split Spoon
CME 85 HSA
6* inch
380 feet
. >-
. E
L: 0) L I T H 0 L 0 G I C D E S C R I P T I 0 N !/)
..... a. 0) a. 0> 'Õ
a. .9: ..... .ì::'
>. -0 0 0 ;)':::
0) I- 0 0 ...J 0 0)'"" ëi)
0 0) ü ä: 0 I.L. ......... c::
0> c.. en :ë -- :J c:: ¡~
....... ~ 00 .....0)
c:: Q) E Ü a. ;: 00.....
.¡;: E .- c::
0 :ê. co en .Q o 0
aJ en ::> 0 (!) aJ ~ü
52
55
60 1:11111111111: Silty sand with gravel, light brown, wet, very dense, no odor. SM 87
65 ::::::11:1: Silty sand with gravel, brown, wet, very dense. SM 65
70 ::::::~I:::::: Silt, mottled brown and dark brown, moist, stiff, no odor. ML 31
75 {::III::1 Silty sand with gravel, brown, wet, very dense, no odor. SM 58
Silt, brown, soft, in shoe. ML
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610,BG2
Éi)
PLATE 29
I
I
I
LOG OF BORING 6
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
I
LOGGED By:
EV298-1610
Carwa5h of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 29, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
. >-
.
.c Q) LITHOLOGIC DESCRIPTION VI E
- a. Q) a. C) Õ ~
c.. >. "C S: 0 -
Q) I- 0 ...J 0 ()1:: ëñ
0 Ü 0 0 Q)~
Q) Surface Conditions: .2 u. ....- r::
CI a. a.. - :J r:: ~u:
r::Z' C/) ~ .c VI -Q)
E () a. ;: VI-
'r;: Q) ~ .- r:: ~~
o Q) ro C/) 0 o 0
aJ~ C/) ::> 0 " ã5 ~() 0,-
78
I
I
:1
I
80 ::::::~I::::::
I
85 ..:...... :.:.:.
:::::::::
I
I
90 !j!j!jii.I¡!
:::::::::::::::::::::::::::
I
I
I
95
I
I
100
I'
I
· ·Sample Type:
.1
EV1610,BG2
Silty fine sand! brown, moist, very dense, no odor, with 2"
silt ayers dipping 20°.
SM/ML
100
Silt with very fine sand, mottled light brown and dark yellow
brown, soft, moist, no odor.
?ilty fine sand, light brown, very moist, very dense, no odor
In shoe.
ML
SM
86
Silt, mottled light brown and brown, very moist, stiff, no
odor; fine silty sand in shoe, brown, very moist, very dense.
End @ 90 ft., show of water @ 60 ft. and 75 ft., no water in
hole at end.
ML
SM
82
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
ÉiJ
PLATE 30
I
I
I
I
'I
I
I
I
I
I
I'
I
I
I
I
I
I
I
I
LOG OF BORING 7
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 30, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
. >-
. E
..c: Q) LIT H a La G I C D E SC R I P T I a N 00
- a. Q) c. C> 'Ô ~
a. >. "C B 0 -
0 ()":
Q) I- 0 0 ....J 0 Q):::'" ïñ
0 Q) ü .~ u. ....- c:
C> a. Surface Conditions: Concrete C/) a.. ..c: -- :J c: ~u:
c: ........ ~ 00 -Q)
"t: Q) E Ü a. ;: 00-
~ .- c: ~ü
o Q) ro C/) 0 o 0
m~ C/) ::> 0 <.9 iñ ~ü oe:
0
5
10 - ALLUVIUM -
15
20 ¡¡¡¡¡¡I,I¡¡¡¡¡¡ Silty fine sand, pale grey, moist, dense, no odor, concrete in SM 70
top of tube.
25
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
@
PLATE 31
I
I
I
I
'I
I
,I
I
I
I
'I
I
I
I
I
I
I
I
I
LOG OF BORING 7
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 30, 1999
2 inch Split Spoon
CME 85 HSA
6 Yz inch
380 feet
. :;-
. E
..c: Q) L I T H 0 L 0 G I C D E S C R I P T I 0 N II)
.... a. Q) c- O> ~ Þ
a. >- "0 .9: 0 .... ():::
Q) I- 0 ...J 0 ïñ
e U e 0 Q)::::'-
Q) .Q u. ....- c
a.. -- ::J C Q)
0> ..-.. "õ.. en ~ ..c: II) ....Q) eLL
C .... E u Q. ~ II) ....
'L: Q) ~ <5 C ~u
0 ~ ro en 0 0
(II en => 0 " ã5 ~ u e~
26
30 ::::::1,11:::::: Silty fine to medium sand, light ~ellow brown, moist, very SM 94
dense, no odor, gravel to 1" In S oe.
35
40 ::::::19:::::: Sand, fine to coarse, light brown, moist, dense, no odor. SW 60
45
50
· ·Samp/e Type:
G = Grab
N = No Recovery
SL = Sludge
S8 = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610.BG2
@
PLATE 32
I
LOG OF BORING 7
I
I
I
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 30, 1999
2 inch Split Spoon
CME 85 HSA
6 Yz inch
380 feet
. '>
I . E
.r:. 0) LITHOLOGIC DESCRIPTION IJ)
+-' a. 0) a. C) 'Õ
a. ~ "0 S. 0 Õ .?;-
0) 0 ..J ~ ïñ
C C 0 0)'-
0) () ,g LL ....+-' c:
a. -- :J c: 0)
C) a. Cf) .r:. ~6
'I c: ......... ~ IJ) +-,0)
"¡:: Q) E u a. 3= IJ)+-'
~ .- c:
o 0) co Cf) .Q o 0
en~ Cf) => 0 (!) en ~() c~
52
I
I
55
I
I
60 j:j:j:III:j
Silty fine to medium sand, light brown, moist, very dense, no
odor, gravel to 1 Y:z" in shoe.
SM
83
I
I
65 ::::::11:::1::
Silty very fine sand, light brown, moist, very dense, no odor.
ML
78
,I
I
70 ::::::§!¡U:::
Silty fine sand, yellow brown, moistb medium dense, no odor.
Silt mottled brown and dark yellow rown, moist, stiff.
SM
32
I
I
75 l::~g:m::
Silt, mottled brown and dark brown, moist, medium stiff, no
odor. Silty fine sand, brown, moist, very dense, no odor.
ML
SM
81-6"
I
I
I
··Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV161 Q,BG2
Éi)
PLATE 33
I
I
I
I
'I
I
JI
I
,I
I
I
I
I'
I
I
I
,I
I
I
LOG OF BORING 7
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 30, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
. >-
. E
.J::. 0) L I T H 0 L 0 G I C D E S C R I P T I 0 N (/)
+-' a. 0) c- O) Õ Þ
a. ð 0 +-'
?:: "U 0 ()1::
0) 0 0 -I 0 0):::- ïii
0 0) () .~ u. ...+-' c:
Surface Conditions: a.. - ::J c: 0)
C> c.. en ~ .J::. (/) +-,0) ou::
c: ....... a. ~ (/)+-'
+-' E ()
'¡:: 0) ~ .- c: è:'U
0 g ro en o 0
cc en ::J 0 (!) cc ~U oe:
78 Gravel to 2 in., 76-80 ft.
80 ::::::§g:::::: Silty fine sand, light brown, moist, very dense, no odor. SM 101
85 t:¡!!I¡:¡:¡: Silty fine sand, light brown, moist, very dense, no odor. SM 71
90 :¡:~1~1~~1~1~1 Silty fine to medium sand, light brown, moist, moist, very ML 78
dense, no odor. Sandy silt in 2nd tube. SM
95
100 mtstft Silty fine to medium sand, pale brown, moist, very dense. SM 9·1
::::::::::::::::::::::::::;
· ·Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV161 Q,BG2
ÉiJ
PLATE 34
I
I
I
I
I
I
I
I
I
'I
I
I
I
I
I
,I
I
I
I
LOG OF BORING 7
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
LOGGED By:
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
September 30, 1999
2 inch Split Spoon
CME 85 HSA
6% inch
380 feet
. >-
. I/) E
.r:- Q) LITHOLOGIC DESCRIPTION
- a. Q) a. 0> ~ Þ
a. S: 0 -
>. "0 0 ;:¡:::
Q) I- 0 a ...J 0 Q)'"' ïñ
a Q) u 0 LL. ...- c
Surface Conditions: a. :E - :J C Q)
C) ëi (j) I/) -Q) aLL:
cZ' E u ~ 0- 3: 1/)-
o¡: Q) ro 0- C ~u
o Q) ro (j) ... .Q o 0
m:t:.. (j) ::> 0 C) m ~u ae:
105
11 0 ¡:::::IB¡:::¡¡
Silty fine to coarse sand, pale brown, moist, very dense. SM
80
115
1 20 !:!:!:!!!:!:!:!
Silty fine to coarse sand, yellow brown, moist, very dense, no SM
odor, occasional gravel to 1/2".
82
125
"Sample Type:
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
W = Water
EV1610,BG2
@
PLATE 35
"
I
I
I
LOG OF BORING 7
JOB NUMBER:
CLIENT NAME:
SITE ADDRESS:
I
LOGGED By:
I
I
I
I
.
.
..c. 0)
ã. a.
0) ~
a 0)
g>:;:;- ëi
.;:: 0) E
00) co
CD:t;.. (/)
130 t:§ii::::::
:.:.:.:.:.:.:.:.:.:.:.:.:.:
135
I
I
I
140 ::::::11\\\\\\
I
145
I
I
I
I
I
I
150
155
"Sample Type:
I·
EV161 Q,BG2
EV298-1610
Carwash of America
1701 Stine Road
Bakersfield, California
Michael R. Tiffany, RG 6750
DATE:
SAMPLING METHOD:
DRILL RIG:
BORING DIAMETER:
ELEVATION:
LITHOLOGIC DESCRIPTION
Surface Conditions:
Silty fine to medium sand, pale brown, moist, very dense, no
odor.
Gravelly sand, yellow brown, moist, very dense, no odor.
End @ 140 ft., no water.
G = Grab
N = No Recovery
SL = Sludge
SB = Soil Bulk
SD = Soil Drive
V = Vapor
Éi)
--
September 30, 1999
2 inch Split Spoon
CME 85 HSA
6 Yz inch
380 feet
>-
en E
0) a. C> ~ Þ
"C S: 0 .....
0
0 a ...J 0 ïi)
Ü .2 u.. 0)- e:
L.. e: ~u::
(j) a.. ..c. - ::J 0)
~ en
Ü c. ~ 00.....
~ .- e: ~ü
(j) o 0
:) 0 c.9 ã5 ~ü ae:.
SM 79
SW
93
W = Water
PLATE 36
---- ---------
I
I
I
I
I
I
I
I.
I
I
I
I
I
I
I
I
I
I
I EV1610,RPT
APPENDIX I
Laboratory Reports and Chain-of Custody Forms
ÉW
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
,I
I
I
October 11, 1999
~~tlumbia
~ Analytical
ServICes Inc.
An Employee-Owned Company
Mike Tiffany
California Environmental
31320 Via Colinas
Suite 104
Westlake Village, CA 913 62
Re: Car Wash of America/Project #EV 298-1610
Dear Mike:
Enclosed are the results of the samples submitted to our mobile laboratory on September 30,
1999. For your reference, these analyses have been assigned our service request number
L99041 04.
All analyses were performed in accordance with our laboratory's quality assurance program.
Results are intended to be considered in their entirety and apply only to the samples analyzed.
Columbia Analytical Services is not responsible for use of less than the complete report.
Columbia Analytical Services - Mobile Laboratory - is certified for environmental analyses by the
California Deparment of Health Services (certificate number: I2351, expiration: February 29,
2000).
If you have any questions, please call me at (818) 587-5550, extension 310.
Respectfully submitted,
Columbia Analytical Services, Inc.
7LlxL
L. Ross Fenstermaker
Project Chemist
LRF /kh
6925 Canoga Avenue . Canoga Pori", CA 91 JOJ . (515) 557-5550 . Fox (515) 557-5555
I
I 8015M
A2LA
ASTM
BOD
I BTEX
CAM
CARD
CAS Nwnber
I CFC
CFU
COD
CRDL
I DEC
DEQ
DLCS
DMS
I DOE
DOH or DHS
ELAP
I EPA
EQL
GC
GClMS
I IC
ICB
ICP
ICY
I J
LCS
LUFT
I M
MBAS
MCL
I MDL
MPN
MRL
MS
I MTBE
NA
NAN
NC
I NCASI
ND
NIOSH
I NTU
ppb
ppm
PQL
I QAlQC
RCRA
RPD
SIM
I SM
I STLC
I SW
I TCLP
TDS
TPH
tr
I TRPH
TSS
TTLC
I VOA
Columbia Analytical Services, Inc.
Acronyms
California DHS LUFf Me1hod
American Association for Laboratory Accredi1ation
American Society for Testing and Materials
Biochemical Oxygen Demand
Benzeneffoluene!E1hylbenzenelXylenes
California Assessment Me1als
California Air Resources Board
Chemical Abstract Service Registry Number
Chlorofluorocarbon
Colony-Forming Unit
Chemical Oxygen Demand
Contract Required Detection Limit
Department of Environmenlal Conservation
Department of Environmen1a1 Quality
Duplicate Laboratory Control Sample
Duplicate Matrix Spike
Department of Ecology
Department of Heal1h Services
Environmen1a1 Laboratory Accredi1ation Program
U.S. Environmenlal Protection Agency
Estimated Qaunti1ation Limit
Gas Chromatography
Gas Chromatography/Mass Spectrometry
Ion Chromatography
Initial Calibration Blank sample
Inductively Coupled Plasma atomic emission spectrometry
Initial Calibration Verification sample
Estimated concentration. The value is less 1han 1he MRL, but greater 1han or equal to 1he MDL.
If1he value is equal to 1he MRL, 1he result is actually <MRL before rounding.
Laboratory Control Sample
Leaking Underground Fuel Tank
Modified
Me1hylene Blue Active Substances
Maximum Contaminant Level. The highest permissible concentration of a substance
allowed in drinking water as eS1ablished by 1he U.S. EP A.
Me1hod Detection Limit
Most Probable Number
Me1hod Reporting Limit
Matrix Spike
Me1hyl-tert-Butyl E1her
Not Applicable
Not Analyzed
Not Calculated
National Council of1he paper industry for Air and Stream Improvement
None Detected at or above 1he Me1hod ReportinglDetection Limit (MRUMDL)
National Institute for Occupational Safety and Heal1h
Nephelometric Turbidity Units
Parts Per Billion
Parts Per Million
Practical Quanti1ation Limit
Quality Assurance/Quality Control
Resource Conservation and Recovery Act
Relative Percent Difference
Selected Ion Monitoring
Standard Methods for the Examination of Water and Wastewater, l81h Ed., 1992.
Solubility Threshold Limit Concentration
Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW-846,
Third Edition, 1986 and as amended by Updates I, II, IIA, and IIB.
Toxicity Characteristics Leaching Procedure
To1a1 Dissolved Solids
Total Petroleum Hydrocarbons
Trace level is 1he concentration of an analyte 1hat is less 1han 1he PQL but greater 1han or equal to
1he MDL. If1he value is equal to 1he PQL, 1he result is actually <PQL before rounding.
To1a1 Recoverable Petroleum Hydrocarbons
Total Suspended Solids
Total Threshold Limit Concentration
Volatile Organic Analyte(s)
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
Ethylbenzene
I Xylenes, Total
TPH as Gasoline
I Methyl tert-Butyl Ether
I
I
I
I
I
I
I
I
I
t
Approved By:
1 S221020597p
04104YOH.JTl ,Sample 10/11/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV 298-1610
Soil
Service Request: L9904l04
Date Collected: 9/30/99
Date Received: 9/30/99
MTBE, BTEX and TPH as Gasoline
B7 @ 40
L9904l04-002
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 80l5M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MTBE.
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9130/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
7tf
10-/1-11
Date:
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
Ethylbenzene
I Xylenes, Total
TPH as Gasoline
Methyl tert -Butyl Ether
I
I
I
I
I
I t
I
I
I Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV 298-1610
Soil
Senice Request: L9904104
Date Collected: 9/30/99
Date Received: 9/30/99
MTBE, BTEX and TPH as Gasoline
B7 @ 60
L9904 1 04-003
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 80l5M 0.1
EPA 5030 8021B 0.010
TPH as Gasoline does not include MTBE.
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/30/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
7/1
10 -11- ~ ì
Date:
1 S221020597p
I
04104VOHJTI ,Sample (2) 10/11/99
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl ter! -Butyl Ether
I
I
I
I
I
I t
I
I
I Approved By:
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV 298-1610
Soil
Senice Request: L9904104
Date Collected: 9/30/99
Date Received: 9/30/99
MTBE, BTEX and TPH as Gasoline
B7 @ 70
L99041 04-005
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8015M 0.1
EPA 5030 8021B 0.010
TPH as Gasoline does not include MmE.
711
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
I NA 9/30/99 ND
I NA 9/30/99 ND
I NA 9/30/99 ND
1 NA 9130/99 ND
1 NA 9/30/99 ND
1 NA 9130/99 ND
Date:
Jb~I1-~î
1 S22/020597p
04104YOH.ITl ' Sample (3) 10/11/99
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
I
I
I
I
Analyte
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl tert -Butyl Ether
I
I
I
I
t
I
I
I Approved By:
1 S221020597p
I
04104VOH.ITI ,Sample (4) 10/11/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV 298-1610
Soil
MTBE, BTEX and TPH as Gasoline
B7 @ 80
L9904104-007
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
Service Request: L9904104
Date Collected: 9/30/99
Date Received: 9/30/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
TPH as Gasoline does not include MmE.
7if
Date:
fl) -/l-?~
Page No.:
I COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
Client: California Enviromnental Service Request: L9904104
I Project: Car Wash of AmericaÆV 298-1610 Date Collected: 9/30/99
Sample Matrix: Soil Date Received: 9/30/99
I
MTBE, BTEX and TPH as Gasoline
I
Sample Name: B7 @ 90 Units: mg/Kg (pprn)
I Lab Code: L9904104-009 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 NA 9/30/99 ND
Toluene EPA 5030 802lE 0.005 NA 9/30/99 ND
I Ethylbenzene EPA 5030 802lE 0.005 NA 9/30/99 ND
Xylenes, Total EPA 5030 802lE 0.005 NA 9/30/99 ND
TPH as Gasoline EPA 5030 8015M 0.1 NA 9/30/99 ND
Methyl fert -Butyl Ether EPA 5030 802lE 0.010 NA 9/30/99 ND
I
I
I
I
I
I t TPH as Gasoline does not include MTBE.
I
I
I Approved By: 7tf Date: 10-/1-11
I S221020597p
I 04104VORITI . Sample (5) 10/11199 Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
Lab Code:
Test Notes:
I
I
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert-Butyl Ether
I
Analyte
I
I
I
I
I
I
I Approved By:
I
t
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV 298-1610
Soil
MTBE, BTEX and TPH as Gasoline
B7 @ 100
L9904104-OIO
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
Service Request: L9904104
Date Collected: 9/30/99
Date Received: 9/30/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
TPH as Gasoline does not include MmE.
7ff
1 S221020597p
04104VOH.ITl ,Sample (6) 10/11/99
Date:
ID'II-"
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I S221020S97p
I 04104VOH.ITI ' Sample (7) 10/11/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV 298-1610
Soil
MTBE, BTEX and TPH as Gasoline
B7 @ 120
L9904104-012
t
Prep Analysis
Method Method MRL
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 8015M 0.1
EPA 5030 80218 0.010
Service Request: L9904104
Date Collected: 9/30/99
Date Received: 9/30/99
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
NA 9/30/99 ND
TPH as Gasoline does not include MfBE.
7if
Date:
10 -1/ - ,î
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Environmental Service Request: L9904104
Project: Car Wash of AmericaÆV 298-1610 Date Collected: 9/30/99
Sample Matrix: Soil Date Received: 9/30/99
I
MTBE, BTEX and TPH as Gasoline
I
Sample Name: B7 @ 140 Units: mg/Kg (ppm)
I Lab Code: L9904104-014 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lB 0.005 1 NA 9/30/99 ND
Toluene EPA 5030 802lB 0.005 1 NA 9130/99 ND
I Ethylbenzene EPA 5030 802lB 0.005 1 NA 9/30/99 ND
Xylenes, Total EPA 5030 802lB 0.005 1 NA 9/30/99 ND
TPH as Gasoline EPA 5030 8015M 0.1 1 NA 9/30/99 ND
I Methyl tert -Butyl Ether EPA 5030 802lB 0.010 1 NA 9/30/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MTBE.
I
I
I Approved By: 7LI Date: 10 ~ If -11
1 S221020597p
I 04104VOHJTl . Sample (8) 10/11/99 Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl fer! -Butyl Ether
I
I
I
I
I
I
I
I Approved By:
I
t
1 S221020597p
04104VOHJTI ,MB1ank 10/11/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV 298-1610
Soil
Service Request: L9904104
Date Collected: NA
Date Received: NA
MTBE, BTEX and TPH as Gasoline
Method Blank
L990930-MB
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8015M 0.1
EPA 5030 8021B 0.010
TPH as Gasoline does not include MTBE.
7tt
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/30/99 ND
1 NA 9/30/99 ND
I NA 9/30/99 ND
1 NA 9/30/99 ND
1 NA 9/30/99 ND
I NA 9/30/99 ND
Date:
tD -/l-I~
Page No.:
I COLUMBIA ANALYTICAL SERVICES, INC.
I QAlQC Report
Client: California Enviromnental Service Request: L9904104
I Project: Car Wash of AmericaÆV 298-1610 Date Collected: NA
Sample Matrix: Soil Date Received: NA
Date Extracted: NA
I Date Analyzed: NA
Surrogate Recovery Summary
MTBE, BTEX and TPH as Gasoline
I Prep Method: EPA 5030 Units: PERCENT
Analysis Method: 8021B/80 15M Basis: Wet
I Test Percent Recovery
Sample Name Lab Code Notes 4-Bromofluorobenzene 4-Bromofluorobenzene
I B7 @ 40 L99041 04-002 95 83
B7 @ 60 L9904104-003 86 75
I B7 @ 70 L9904104-005 88 79
B7 @ 80 L9904104-007 93 86
B7 @ 90 L9904104-009 88 84
I B7 @ 100 L9904104-01O 86 84
B7 @ 120 L9904104-012 96 93
B7 @ 140 L9904104-0 14 94 91
Method Blank L990930-MB 104 90
I B7 @ 140 L9904104-014MS 71 77
B7 @ 140 L99041 04-0 14DMS 75 77
I
I
I
I
I CAS Acceptance Limits: 60-140
60-130
I
I
I Approved By: 7if Date: IO-I/-1í
SUR2I061197p
I 04104VOH.rn ,SUR2 (2) 10/11/99 Page No.:
Ipproved By:
DMSl020597p
I 04104YOH.JTl ,DMS 10/11/99
I
I
Client:
a-;roject:
~ample Matrix:
I
I
Sample Name:
~b Code:
"est Notes:
I
rnalyte
Benzene
Eluene
thylbenzene
H as Gasoline
I
I
I
I
I
I
I
I
COLUMBIA ANALYTICAL SERVICES, INC.
QAlQC Report
California Environmental
Car Wash of AmericaÆV 298-1610
Soil
Service Request: L9904104
Date Collected: NA
Date Received: NA
Date Extracted: NA
Date Analyzed: 9/30/99
Matrix Spike/Duplicate Matrix Spike Summary
MTBE, BTEX and TPH as Gasoline
B7 @ 140
L9904 104-0 1411S,
Units: mg/Kg (ppm)
Basis: Wet
L9904104-014D11S
Percent Recovery
CAS Relative
Prep Analysis Spike Level Sample Spike Result Acceptance Percent Result
Method Method MRL 11S D11S Result 11S D118 118 D118 Limits Difference Notes
EPA 5030 802lB 0.005 0.0400 0.0400 ND 0,0308 0.0322 77 80 39-150 4
EP A 5030 802lB 0.005 0.0400 0.0400 ND 0.0302 0.0312 76 78 46-148 3
EPA 5030 802lB 0.005 0.0400 0.0400 ND 0.0324 0.0343 81 86 32-160 6
EPA 5030 801511 0.1 2.00 2.00 ND 1.89 1.85 94 92 70-140 2
If
Date:
'I) ~ II ' ~ í
Page No.:
-~I"a- - - -
Analytical
Services 'n< , 6925 Canoga Avenue' Canoga Park, CA 91303' (818) 587-5550' Fax (818) 587-5555
--CH"'" Opll!U~VØBcJlllMTOWP A_V~E_SflPoRP
DATE '1 j3D/9f PAGE.I OF :l
PROJECT NAME (A~w ÄStI_ ðf AM£{t\L.~ ~ \1d.CJ~ - J (, I () ANAL VSIS REQUESTED
PROJECT MANAGER M, I( E- II FfANY C/) ¿ .
COMPANY/ADDRESS C.A t../+ 0(2.r.J I A ~N V I fl o~ flit' /IJ n. L- a: §
w o i? ,~
z .! fJ fi 0
)r~::o \Ii A <l.ðL-If'\'A "b Sr~ IÖI.f <ë
I- Õ 12 CI) {5f:!' c
z 'bf3 ~ ~ f;j 0 ~
.) 0
tJ 6.srL(1. C:.G: V lu..ß<:1i C.A , t 36~HONE ,)(;fpø ~.!!;1 Cl)è§ 80 0
ü .~ 0 (j ,.."
u. ,~80 § ~ c:Ñ:!~ f5
) 0
SAMPLERS SIGNATURE a: 0~ ~I.i. g... -$ ð~ §~ j§
W '1:1 9J. "'0' C <l>~' t::: 0 ((j <l> ((j <l>
ca ø ~_ [;1 't... <l>ò ,-:&C/) <'c/) ~
SAMPLE LAB SAMPLE ::2: i <l> 1:59:> ~ "'" 8'r:o ~~ <l>~ ~
:J
1.0. DATE TIME 1.0. MATRIX z
81- e 30 l1'ð~ L<i'1 ~q,ó'f-· I S~l L.. I i:' ~ Hð LJ\
..,.
01@ <f () I -~ I ;><. ..". ~ I...... ~¿'
H ':J ..... JJ ''¡
B1- @ f.DC) -'3 I X
g-r ~ (os :-4 I iloLb
'ß1~ f.-O -s I- )(
ß1 éJ 1s --lo , - J../ ô LD
B7-é? ~~ / -1- \ X
B1~ cq,ç -1s I !/()LJ::>
ß+~ 40 I -~ I ~
ß7-~ 'ðÔ V .....tC I X 11... .... 111/-jv-
.., '" -''/ J'~n.[....... \
A~~~ tILECE:EO_Y: ~ TURNAROuND REQUIREMENTS REPORT REQWlREMENTS INVOICE INFORMATION: SAMPLE RECEIPT: IO'r~'
24hr _48hr, _5day _ I. Routine Report
Sl'gnð ure 'l P' L/ S ~natu~~ I ~ ,~) ,^ N ~ Standard þ<:. II. Report (includes DUP,MS, P.O,# Shipping VIA:
/ - -, ,~~ Jo'\. MSD, as required, may be
print~ II1rin~d Name _ Other (Specify) charged as samples) Bill To Shipping #:
CAS Provide Verbal _ III. Data Validation Report Cond~ion:
(includes All Raw Data)
Firm //-:;'8/99 1115' 4J1'ð Jq, ///~ Preliminary Results RWacB
-
Date/1fïme I / eatefT'me Requested Report Date Lab No:
RELINQUISHED BY: RECEIVED BY: SPECIAL INSTRUCTIONS/COMMENTS: :Jj) L.tJß VIA-0
5A""pL/E.-S 1'-i¡VIILYl€!) f7 P1ðß/L E
Signature Signature '-t ~ "' AtJ1JLYê.J;. ;:Ji.I ¡:. I X. ~ f) L-A ~
~4Yn p-z.£5> fJ1 A (L tL..~ b ¡.J} rì.l
Printed Name Printed Name
Firm Firm J4 1·1S 'ùÇ "'> loD PÞ!/ r,l" 6<._/ ~ S
c.Z\N~I~~ yY\.-rPJ£
DatefTime DatefTime
...
'lISTRIRIITION' WHITF, return to orioin;,Ior: YELLOW - lat>
400-05
-~I_a -
~ tna1yt¡Cal
-
-
-
-cHn1 O~U~ynBoftTO'" AmYS~EmreS"ORr
Services"" 6925 Canoga Avenue· Canoga Park, CA 91303. (818) 587-5550· Fax (818) 587-5555 DATE 9holirr PAGE ~ OF 1-
PROJECT NAMEfÅ/l UlA SJI ðP AlltR/C.* eV~~-/0/0 ANALYSIS REQUESTED
PROJECT MANAGER C/) Go
COMPANY/ADDRESS erE: II: §
UJ o -e ·52
z ~ tJ § c
;:¡:
I- ~ f2 Go f5E!> 0
z '1:1& ~:§ [J 0 !2
0 ~c.::; .:z:-..!P c:o{§ 80 Ö
PHONE () ð.ç ~O § ~ t?~ «:~ &
u..
0
SAMPLERS SIGNATURE II: ~.... o~;; !!o Ot¿ iff)} -!
UJ
CD (!j ~!J ~&!!-;: ¿gè :§C/J ~C/J :i
SAMPLE :2
LAB SAMPLE :::>
1.0, DATE TIME 1.0. MATRIX z
f3t- é!, 11 ~ '::i1 L L1'1ð9¡o1-11 5ðlL HðLl:>
'7117'
ß1 ~ ð-ö I --/1 J r-.f
,
ßl ~ t ~ "t) -ß l~ ð Lt>
ßl-- f) 1% '" ~ -N ,II )(
~f;.' - ^ ..R. RE~ BY: TURNAROUND REQUIREMENTS REPORT REQWlREMENTS INVOICE INFORMATION: SAMPLE RECEIPT:
Af L-Æ- . - }~
./ t.Yk'./_) Z ~ ~ 24hr _48hr, _5day _ I. Routine Report
Signature .77 - P t I:rnJre J n.l!t, .K. Standard K:' II. Report (includes DUP,MS, P,O,# Shipping VIA:
',I ~ vÆ:MtlJ MSD, as required, may be
p~~me Printed Name _ Other (Specify) charged as samples) 8illTo Shipping #:
'/l,!. /' , a.AS Provide Verbal _ III. Data Validation Report Condition:
- (includes All Raw Data)
Firm 711q7')' ¡II '5 8;hO),~ lilt? Preliminary Results
- RWQC8
DatefTfÍne I / DåtefTime Requested Report Date Lab No:
RELINQUISHED BY: RECEIVED BY: SPECIAL INSTRUCTIONS/COMMENTS: LAG V,qJ
5/./ ¡IJ-t f?L€.S ,4,..1 jJ L Y £ff- b ;J:""¡\) ~ ð@JL.£
Signature Signature
Printed Name Printed Name
Firm Firm (;.c,! 111 S
DatefTime DatefTime ~NF J f.}11 M -p)6.. J..ll 1) ðlF "'> /ðÒ P Pf} 0'('
I"'"\'CTQIQ' 'Tln~r· IMUITr::- _ ........',..'" tf"\ ",..¡ro;,..,,'''''''' Vr::-1 J 1""'1'''' _ '~h
"""'U"I:;
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
October 19, 1999
ê(~O'Umbio
~ Ano!yticol
SerVices INC.
An Employee,Owned Company
Mike Tiffany
California Environmental
31320 Via Colinas
Suite 104
Westlake Village, CA 91362
Re: Car Wash of AmericalProject #EV298-1610
Dear Mike:
Enclosed are the results of the samples submitted to our mobile laboratory on September 29,
1999. The samples were sent to Del Mar Analytical for EP A Method 8260B. Please find their
report (#IJ00643) attached. For your reference, these analyses have been assigned our service
request number L9904071.
All analyses were performed in accordance with our laboratory's quality assurance program.
Results are intended to be considered in their entirety and apply only to the samples analyzed.
Columbia Analytical Services is not responsible for use of less than the complete report.
Columbia Analytical Services - Mobile Laboratory - is certified for environmental analyses by the
California Deparment of Health Services (certificate number: I2351, expiration: February 29,
2000).
If you have any questions, please call me at (818) 587-5550, extension 310.
Respectfully submitted,
Columbia Analytical Services, Inc.
7l~
L. Ross Fenstermaker
Project Chemist
LRF /kh
6925 Canoga Avenue . Canoga Parl"i, CA 91303 . (818) 587-5550 . Fax (818) 587-5555
I
I 8015M
A2LA
ASTM
BOD
I BTEX
CAM
CARB
CAS Number
I CFC
CFU
COD
I CRDL
DEC
DEQ
DLCS
I DMS
DOE
DOH or DHS
ELAP
I EPA
EQL
GC
GC/MS
I IC
ICB
ICP
ICY
I J
LCS
LUFT
I M
MBAS
MCL
I MDL
MPN
MRL
I MS
MTBE
NA
NAN
I NC
NCASI
ND
NIOSH
I NTU
ppb
ppm
PQL
I QAlQC
RCRA
RPD
SIM
I SM
STLC
SW
I TCLP
TDS
TPH
I tr
TRPH
TSS
I TTLC
VOA
Columbia Analytical Services, Inc.
Acronyms
California DHS LUFf Method
American Association for Laboratory Accreditation
American Socie1y for Testing and Materials
Biochemical Oxygen Demand
Benzenerroluenef.Ethylbenzen~ylenes
California Assessment Metals
California Air Resources Board
Chemical Abs1ract Service Registry Number
Chlorofluorocarbon
Colony-Forming Unit
Chemical Oxygen Demand
Con1ract Required Detection Limit
Department of Environmental Conservation
Department of Environmental Quali1y
Duplicate Laboratory Con1rol Sample
Duplicate Matrix Spike
Department of Ecology
Department of Health Services
Environmental Laboratory Accreditation Program
U.S. Environmental Protection Agency
Estimated Qauntitation Limit
Gas Chromatography
Gas Chromatography/Mass Spectrometry
Ion Chromatography
Initial Calibration Blank sample
Inductively Coupled Plasma atomic emission spec1rometry
Initial Calibration Verification sample
Estimated concen1ration. The value is less than the MRL, but greater than or equal to the MDL.
If the value is equal to the MRL, the result is actually <MRL before rounding.
Laboratory Con1rol Sample
Leaking Underground Fuel Tank
Modified
Methylene Blue Active Substances
Maximum Contaminant Level. The highest pennissible concen1ration of a substance
allowed in drinking water as established by the U.S. EP A.
Method Detection Limit
Most Probable Number
Method Reporting Limit
Matrix Spike
Methyl-tert-Bu1y1 Ether
Not Applicable
Not Analyzed
Not Calculated
National Council of the paper industry for Air and S1ream Improvement
None Detected at or above the Method ReportinglDetection Limit (MRL/MDL)
National Institute for Occupational Safe1y and Health
Nephelometric Turbidi1y Units
Parts Per Billion
Parts Per Million
Practical Quantitation Limit
Quali1y AssurancelQuali1y Con1rol
Resource Conservation and Recovery Act
Relative Percent Difference
Selected Ion Monitoring
Standard Methods for the Examination of Water and Wastewater, 18th Ed., 1992.
Solubili1y Threshold Limit Concentration
Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW-846,
Third Edition, 1986 and as amended by Updates I, II, IIA, and lIB,
Toxici1y Characteristics Leaching Procedure
Total Dissolved Solids
Total Petroleum Hydrocarbons
Trace level is the concen1ration of an analyte that is less than the PQL but greater than or equal to
the MDL. If the value is equal to the PQL, the result is actually <PQL before rounding.
Total Recoverable Petroleum Hydrocarbons
Total Suspended Solids
Total Threshold Limit Concen1ration
Volatile Organic Analyte(s)
I
COLUMBIA ANALYTICAL SERVICES, INe.
I Analytical Report
I Client: California Environmental Service Request: L990407l
Project: Car Wash of America/EV298-l61O Date Collected: 9/29/99
Sample Matrix: Soil Date Received: 9/29/99
I
I MTBE, BTEX and TPH as Gasoline
I Sample Name: B5 @ 20 Units: mg/Kg (ppm)
Lab Code: L990407l-001 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 1 NA 9/29/99 ND
Toluene EPA 5030 802lE 0.005 1 NA 9/29/99 ND
I Ethylbenzene EPA 5030 802lE 0.005 1 NA 9/29/99 ND
Xylenes, Total EP A 5030 802lE 0.005 1 NA 9/29/99 ND
TPH as Gasoline EPA 5030 8015M 0.1 1 NA 9/29/99 ND
I Methyl fer! -Butyl Ether EPA 5030 802lE 0.010 1 NA 9/29/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 711 Date: IO'I~-7~
I S221020597p
I 04071 VOH.ITI ' Sample 10/19/99 Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
I
I.
I
t
Approved By:
1 S22/020597p
I
04071 VOHJTI ' Sample (2) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
B5 @ 40
L9904071-002
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 8015M 0.1
EPA 5030 802lE 0.010
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
TPH as Gasoline does not include MTBE.
7ff
Date:
ID-I~-?,
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
I
I
I
I
t
Approved By:
1 S221020597p
04071 VOH,ITI ,Sample (3) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B5 @ 60
L9904071-003
t
Prep Analysis
Method Method MRL
EP A 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 802lE 0.005
EPA 5030 8015M 0.1
EP A 5030 802lE 0.010
TPH as Gasoline does not include MTBE.
711
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
I NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
Date:
10 -/~ ,1 ~
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ter! -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
1 S221020597p
I 04071VOH.JTl, Sample (4) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-161O
Soil
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B5 @ 65
L9904071-004
t
Prep Analysis
Method Method MRL
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EP A 5030 8015M 0.1
EPA 5030 80218 0.010
TPH as Gasoline does not include MTBE.
711
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
I NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
I NA 9/29/99 ND
Date:
IÐ-,~·11
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl fer! -Butyl Ether
I
I
I I
I
I
t
I
I
I Approved By:
1 S22/020597p
I 04071VOHJTI ,Sample (5) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B5 @ 70
L990407l-005
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0,005
EP A 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MfBE,
711
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
Date:
lo-r~-~'
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I S221020597p
I 04071VOH.ITI ,Sample (6) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
B5 @ 75
L9904071-006
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8015M 0.1
EP A 5030 8021B 0.010
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
TPH as Gasoline does not include MmE.
711
Date:
IO-11'~1
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
I Analyte
Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
I
I
I
I
t
Approved By:
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of America/EV298-l61O
Soil
Service Request: L990407l
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B5 @ 80
L990407l-007
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EP A 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MmE.
7tf
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
I NA 9/29/99 ND
1 NA 9/29/99 ND
Date:
1 b - I? . ; 1
1 S221020S97p
04071 VOH.ITJ ,Sample (7) JOI19/99
Page No.:
I
I
I Client:
Project:
Sample Matrix:
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
I
I
MTBE, BTEX and TPH as Gasoline
I Sample Name: B5 @ 85 Units: mg/Kg (ppm)
Lab Code: L9904071-008 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I
Benzene EPA 5030 802lE 0.005 1 NA 9/29/99 ;>, ND
,,",
Toluene EPA 5030 802lE 0.005 1 NA 9/29/99 ND
I Ethylbenzene EPA 5030 802lE 0.005 1 NA 9/29/99 ND
Xylenes, Total EPA 5030 802lE 0.005 1 NA 9/29/99 ND
TPH as Gasoline EP A 5030 8015M 0.1 1 NA 9/29/99 ND
I Methyl tert -Butyl Ether EPA 5030 802lE 0.010 1 NA 9/29/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MTBE.
I
I
I Approved By: 7£1 Date: I b -/~ . ~ 1
J S22/020597p
I 04071VOH.JTI ,Sample (8) 10/19/99 Page No.:
I
I
1 Client:
Project:
Sample Matrix:
I
1
1 Sample Name:
Lab Code:
Test Notes:
I
I Analyte
Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl fer! -Butyl Ether
I
I
I
I
I
I 'I
t
I
I
I
Approved By:
I S22/020597p
04071 VOHJTl ,Sample (9) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B5 @ 90
L9904071-009
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MmE.
7Ü
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Rèsult
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 0.010
Date: _I D -/7 ·~î
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl fer! -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I S22/020597p
I 0407IVOH.m· Sample 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-1610
Soil
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B6 @ 20
L9904071-0 10
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8021B 0.005
EPA 5030 8015M 0.1
EP A 5030 8021B 0.010
TPH as Gasoline does not include MfBE.
71/
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
Date:
ID ~I~ ,11
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
I
I
I
t
Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-1610
Soil
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B6 @ 40
L9904071-011
t
Prep Analysis
Method Method MRL
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 8015M 0.1
EP A 5030 80218 0.010
TPH as Gasoline does not include MfBE.
7if
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
Date:
1 ú - 11 ' ~ ~
I S221020597p
I
04071 VOH.ITI, Sample (2) 10119/99
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
Sample Name:
Lab Code:
Test Notes:
I
I
I
I
I
I
t
I
I Approved By:
IS221020597p
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-l61O
Soil
Service Request: L990407l
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B6 @ 60
L990407l-0 12
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 802lE 0.005
EPA 5030 80l5M 0.1
EPA 5030 802lE 0.010
TPH as Gasoline does not include MTBE.
7U
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
Date:
lfi -11-;~
I
04071 VOH.m ' Sample (3) 10/19/99
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
I Analyte
Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ferf -Butyl Ether
I
I
I
I
I
I
I
I
I
i
Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
B6 @ 65
L9904071-013
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8015M 0.1
EPA 5030 8021B 0.010
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
TPH as Gasoline does not include MTBE,
7ff
I S22/020597p
04071VOH.m, Sample (4) 10/19/99
Date:
ro-'~-1~
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Environmental Senice Request: L9904071
Project: Car Wash of AmericalEV298-161O Date Collected: 9/29/99
Sample Matrix: Soil Date Received: 9/29/99
I
I MTBE, BTEX and TPH as Gasoline
I Sample Name: B6 @ 70 Units: mg/Kg (ppm)
Lab Code: L9904071-014 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802 IE 0.005 I NA 9/29/99 ND
Toluene EPA 5030 802 IE 0.005 1 NA 9/29/99 ND
I Ethylbenzene EPA 5030 802 IE 0.005 1 NA 9/29/99 ND
Xylenes, Total EPA 5030 802 IE 0.005 1 NA 9/29/99 ND
TPH as Gasoline EPA 5030 8015M 0.1 1 NA 9/29/99 ND
I Methyl fert -Butyl Ether EPA 5030 802 IE 0.010 1 NA 9/29/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 7if Date: lo-/~-7í
I S221020597p
I 04071VOH.m, Sample (5) 10/19/99 Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
Lab Code:
I Test Notes:
I
I
I
I
I
I
I
I
Analyte
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl fer! -Butyl Ether
I t
I
I-
I'
I'
Approved By:
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-1610
Soil
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B6 @ 75
L9904071-015
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8015M 0.1
EPA 5030 8021B 0.010
TPH as Gasoline does not include MTBE.
11
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
Date:
'C-'~'~~
I S221020597p
04071 VOH.IT2, Sample (6) 10119/99
Page No.:
Drive
Hestl-Acres
SIDEWALK
I
I
I
~
ø4r~
~
SCALE
0 0 20 30 40 feet
1 inch = 30 feet
PLOT PLAN
Adjacen
Commercial
Property
AI
!!?
.s::='
",'"
~~~?
'~f
'¡~i
:. '~. ".. '. ..,..
:,\71
i."'}Ä
~'i:1
Ff.
.~
.~
B7
I
I
I
j ,. . ~-------
'/(.''1: "'(. "... "... ""''''''''1:,¡-:"...",(.',..."...'''(.'''(.'''''''''''''(' "'(. "..."...''1: "..."..."..."..."i"...""'''''''''C'(."'(.''1: "'(.'...."'(.,,'(."'(."..."'(."...''1:''1:''...'"(.'''(.''...'';-,'''(.'''(.'''(.''1:'''
., y; '..., ...., '1:, '1:, .,(., '1:, '1:, '..., '"-:,"(., '..., ...., ..../ '1:, ...., '1:, .,(., '1:, "(., "(., '1:, '1:, '1:, '1:, '..., ...., '..., "(., ..../ '..., '1:, '..., '..., '1:, '1:/..., '1:, "(., '1:, ,.../ .,(./ '1:, '1:, '1:, '..., ...., '..., '1:, ·"';x, ...., '1:, ...., ·'Ç1.,
,r.;'1:;-...;-...;-...;-...;-...;-",;-,(.;-",;-,¿:"-:;-",;-",;-",;-",;-'à;-'r.;...;-...;-...;-...;-...;-,(.;-...;-,r.;...;-...;-...;-,(.;-,(.;-...;-",;-,r.;,r.;,(.;-,r.;"';-"';-"';-'à;-...;-...;-¿"';-...;-...;-...;-'(.;-'(!:r.;...;-,(.;-,(;-/¿:",;"
,'à;-...;-"';-"';-"';-"';-...;-"';-,(;-,(;-"';-Y!:(;-'(;-",;-",;-",;-"';-,r.;...;-¿...;-...;-...;-...;-...;-...;-...;-,r.;",;-,(;-",;-,(;-",;-,(;-",;-,(;-",;-",;-,r.;...;-"';-...;-"';-"';-...;-"';-"';-"';-'b;-...,~"';-...;-'(;-...;-"';-'(;-"
"r.;,r.;,(;-,(;-,r.;,(;-¿",;-",;-,(;-,r.;...;-"';-',-:;,,,,;-,(;-,,,;-,,,;-,,,;-,r.;,,,;-...;-,¡;...;-...;-...;-...;-...;-...;-...;...;-",;-,¿-:",;-,(;",;-,r.;,r.;"';-"';-'r.!:r.:",;-",;-,(;-...;-...;-,r.:'¿:"';-'¿-:'b;-Ú:r.:,(;-'(;-'(;-'(;-"
.y;-",;-",;-,(;-/(;-",;-/(;-...;...;-...;-...;-,r.:",;-¿-:;-...;-/(;-...;-...;-¿:r.:...;-...~,(;-",;-...;-...;-",;-",;-",;-",;-,(;-",;-,(;-",;-'à!;...;-"';-"';-"';-'(;'...;-...;-"';-'b;-...;-",;-",;-"';-'(;-"';-"';-'r.;:b;-'(.~'('-~
r;-'(. '-/(. ,-,(. ,-,(.,-,(. ,-,/,(.'-...':(.;-... '-/¿,(. ~~,:¿:(.!;,¿... '-...'-...::r.;-< Ii' :'-...'-£,(. '-/(. '-... (...,-,(.{;,(.;¿;:,r.;,(. '-...,;,(.;;... '-...':r.;-... (... (...;-...'-... ,-,(. '-'( '-... ,-...,-,/... ,;...;-,/... '-11 ;...'-r~"
...::(.::¿...!;-;¿,(;;...~...:;...;:(.::...::(.::(.::,(.:; ,:;;-::x;;'ð(.::(.;:(.;:(.;;f(; 'f! :;:';:;...;x:;,(.::(.;:(.;;tx"c¿;é,(.:x;x::(.;:(.::...::(.::(.x...;:¿...;;,ê'(.;:'(.;;:é:(.!:f~(.:xi:')-:'
Wash Canopy
Car
Asphalt
Paving
'1:
'1:
"(.""'''''''Y''1:
.¡-:.,..;;oo;;'~
SIDEWALK
Asphalt
Paving
~B5
er
(¡j
'E
Q)
ü
C)
§
ïii
ã)
o
o
'5
«
I
I
I
Î:
Ff.
I
I
I
I
I
I
I
I
I
Apartments
I
I
I
I
I
I
I
I
I
I
1
'I
I
I<oed
Stine
LE_G.END
II
"({)) 7flJ1},i((}J, E nWilfO nmÆn1t((}J,Æ
. -
Job #
Concrete
<i!. of Stine Canal (buried
concrete pipe culvert
~-
Holes
1997
Location of Borings by CE
Location of Hand Auger Test
Excavated by AJ Environmental
~
87
~
THI?
I
CIB
610
October 1999
CheCked By
EV298-1
ERN
Date
By
I
I
,
\
i
I
'j
)
C((}J,li
Client Car Wash of America
Site Name. C W
Niagara ar ash
Location 1701 Stine Road. Bakersfield. CA
Hl10ptolp61n
Landscaping
Cross section line
t<'~~'~~i
,/'/ '/ '
.A. ....
Location of 8 inch Hollow Stem Auger Borings
Excavated by AJ Environmental 1997
nc.
AJ21
$
REFERENCE: Survey Provided by John B. Abel
I
,I
If.
I AI
CONCRETE
BLOCK WALL
B7
B4
:0 =c
Q) Q)
U U
Q) Q)
'0 '0
... ...
B B
BIAJ18
-~-
THl
I
I
TH3
B3
B6
If.
I
I
A
II
I
o
30
20
30
60
ND
J
I
I
j
¡
¡
~
E-,~
.4
NO
I
0.1
,'--',
, UST J
, ,.
'--'!'
ND
0.1
Silty Sand
Silty Sand
NO
NO
10
110
130
120
20
30
40
80
90
100
50
60
70
Q)
o
as
't:
~
tn
"C
C
~
o
..
CJ
==
o
ã)
m
.s:.
...
Q.
Q)
Q
I
1
I,
Ii
1
1
I'
I
,I
I
I
1
1
15°
-N
w>
-N20°
140
E >
15°
-N
TPH
-
CROSS SECTION MAP
cC({)J,Æi/fo7l7fll,i({)J, Eru,wiJr(())nmeru,t(()J,Æ
- . . Jc;'b'#
Car Wash of America EV298-1610
Niagara Car Wash October 1999
1701 Stine Road. Bakersfield ERÑ Checked By CIB
Date
tt:
L
CA
Client
Site Name
I Location
1elo~~!ÖonA.A·TPH
c
o
:¡::
u
CD
en
.5
'C
c
CD
m
w~
I
-N 20°
40
= 30'
20 30
l'
10
TPH >5 mg/kg
~
LEGEND
Concentration of TPH (gasoline)
in soil samples, in mglkg
Bl
I
i
,
,
,
SCALE
Horizontal
Exaggeration
1.5: 1
10
20
(:)
C'\I
II
.-
0.21
0,3
0,1
0,1
0,3
ND
-I
~I'
,I
If.
CONCRETE
BLOCK WAll I A
B7
Fuel Dispensors
.
:c :c
0> 0>
(3 U
0> 0>
'0' '0'
.... ....
S: .9:
BIAJ18
TH3
B3
B6
If.
I
I
A
o
B4
mt
o
o
120
140
130
ND
Silty Sand
Silty Sand
ND
ND:
20
30
40
50
60
70
80
90
100
110
120
130
140
CI)
o
CIS
't
::s
en
"0
C
::s
o
...
CJ
;:
o
G)
m
.c
-
Co
CI)
C
I
I
!I
I
I
I
I
I
I
I
I
I
I
I
I
E >
15°
-N
w~
¡
-N 20°
=30'
20 30
l'
LEGEND
I
MtSE
CROSS SECTION MAP -
C ({)j,Æil!({)) 1f7fll,i({)j, E nWilf ({))Jinmen7t({)j,Æ
Car Wash of America I Job# EV298-1610
I
. ,~ 0
Niagara Car Wash ctober 1999
1701 Stine Road, Bakersfield. CA r By ERN Checked By CIS
r
Client
SïiãÑame
LõCãiiõñ'
c
o
:;:;
CJ
CÞ
UI
.S
"C
C
CÞ
m
I
"'0~~A-A'''USE
40
SCALE
Horizontal
Exaggeration
1.5: 1
10
10
20
o
C\I
II
....
MtSE >0.05 mglkg
Concentration of MtSE in
soil samples, in mg/kg
81
2.9 I
1.2
0.14 I
0.089
o.
I
,I'
I
------- - - - - ------
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Environmental Senice Request: L990407l
Project: Car Wash of AmericalEV298-161O Date Collected: 9/29/99
Sample Matrix: Soil Date Received: 9/29/99
I
I MTBE, BTEX and TPH as Gasoline
I Sample Name: B6 @ 80 Units: mg/Kg (ppm)
Lab Code: L990407l-0l6 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I
Benzene EPA 5030 802lE 0.005 1 NA 9/29/99 ND
Toluene EPA 5030 802lE 0.005 1 NA 9/29/99 ND
I Ethylbenzene EPA 5030 802lE 0.005 1 NA 9/29/99 ND
Xylenes, Total EPA 5030 802lE 0.005 1 NA 9/29/99 ND
TPH as Gasoline EPA 5030 80l5M 0.1 1 NA 9/29/99 ND
I Methyl fer! -Butyl Ether EPA 5030 802lE 0.010 1 NA 9/29/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MrBE.
I
I
I Approved By: 7i1 Date: (0 -11'~~
I S221020597p
I 04071VOH.m· Sample (7) 10/19/99 Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl fer! -Butyl Ether
I
I
I
I
I
I
I
I
I
t
Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-1610
Soil
MTBE, BTEX and TPH as Gasoline
B6 @ 85
L9904071-017
t
Prep Analysis
Method Method MRL
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 8015M 0.1
EPA 5030 80218 0.010
TPH as Gasoline does not include MmE.
)/
Service Request: L9904071
Date Collected: 9/29/99
Date Received: 9/29/99
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
NA 9/29/99 ND
1 S221020597p
04071 VOH.m - Sample (8) 10/19/99
Date:
IO-f~-1~
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
Ethylbenzene
I Xylenes, Total
TPH as Gasoline
Methyl tert -Butyl Ether
I
I
I
I
I
I t
I
I
I Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
Senice Request: L990407l
Date Collected: 9/29/99
Date Received: 9/29/99
MTBE, BTEX and TPH as Gasoline
B6 @ 90
L9904071-0 18
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 80l5M 0.1
EPA 5030 802lE 0.010
TPH as Gasoline does not include MTBE.
af
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
] NA 9/29/99 ND
I S221020597p
Date:
}O~/'-Î;
I
04071 VOH.m· Sample (9) 10/19/99
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
I Analyte
I
I
I
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl ter! -Butyl Ether
I
I
I
I
I t
I
I Approved By:
I
1 S221020597p
04071 YOH.m· MBlank 10/19/99
COLUMBIA ANALYTICAL SERVICES, 1Ne.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-l61O
Soil
Service Request: L9904071
Date Collected: NA
Date Received: NA
MTBE, BTEX and TPH as Gasoline
Method Blank
L990929-MB
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 80l5M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MTBE.
7//
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
1 NA 9/29/99 ND
Date:
lÓ-I?-;1
Page No.:
I COLUMBIA ANALYTICAL SERVICES, INC.
I QA/QC Report
Client: California Environmental Service Request: L9904071
I Project: Car Wash of America/EV298-161O Date Collected: NA
Sample Matrix: Soil Date Received: NA
Date Extracted: NA
I Date Analyzed: NA
Surrogate Recovery Summary
MfBE, BTEX and TPH as Gasoline
I Prep Method: EP A 5030 Units: PERCENT
Analysis Method: 802lE/80 ISM Basis: Wet
I Test Percent Recovery
Sample Name Lab Code Notes 4-Bromofluorobenzene 4-Bromofluorobenzene
I B5 @ 20 L9904071-001 103 87
B5 @ 40 L9904071-002 94 86
I B5 @ 60 L9904071-003 95 88
B5 @ 65 L9904071-004 87 79
B5 @ 70 L9904071-005 93 84
I B5 @ 75 L9904071-006 87 80
B5 @ 80 L9904071-007 97 90
B5 @ 85 L9904071-008 98 91
B5 @ 90 L9904071-009 98 89
I
I
I
I
I
I
CAS Acceptance Limits: 60-130 60-140
I
I
I Approved By: 711 Date: /D-,~·1í
SUR2IOó 1197p
I 04071 YOH.JTl ,SUR2 (2) 10/19/99 Page No..
--------
I
COLUMBIA ANALYTICAL SERVICES, INC.
I QNQC Report
I Client: California Environmental Service Request: L9904071
Project: Car Wash of AmericaÆV298-1610 Date Collected: NA
Sample Matrix: Soil Date Received: NA
I Date Extracted: NA
Date Analyzed: NA
Surrogate Recovery Summary
I MTBE, BTEX and TPH as Gasoline
Prep Method: EPA 5030 Units: PERCENT
I Analysis Method: 802lE/80 15M Basis: Wet
Test Percent Recovery
I Sample Name Lab Code Notes 4-Bromofluorobenzene 4-Bromofluorobenzene
B6 @ 20 L9904071-OlO 83 78
B6 @ 40 L9904071-011 81 76
I B6 @ 60 L9904071-012 100 100
B6 @ 65 L9904071-013 81 77
B6 @ 70 L9904071-014 94 90
I B6 @ 75 L9904071-015 89 82
B6@80 L9904071-016 86 86
B6 @ 85 L990407l-0l7 85 80
I B6@90 L9904071-018 94 89
Method Blank L990929-MB 97 86
B6 @ 75 L9904071-015MS 88 84
I B6 @ 75 L9904071-015DMS 89 82
I
I
I
I
CAS Acceptance Limits: 60-130 60-140
I
I
I 7il '()-'~-1î
Approved By: Date:
I SUR2I061197p
04071 YOH.m, SUR2 (2) 10/19/99 Page No.:
I
I
llient:
roject:
Sample Matrix:
I
I
~amPle Name:
b Code:
est Notes:
I
Inatyte
Benzene
IOluene
thylbenzene
TPH as Gasoline
I
I
I
I
I
I
I
I
I
Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
QAlQC Report
Service Request: L990407l
Date Collected: NA
Date Received: NA
Date Extracted: NA
Date Analyzed: 9/29/99
California Enviromnental
Car Wash of AmericaÆV298-l61O
Soil
Matrix Spike/Duplicate Matrix Spike Summary
MTBE, BTEX and TPH as Gasoline
B6 @ 75
L990407l-015MS,
L9904071-015DMS
Percent
Prep Analysis Spike Level Sample Spike Result
Method Method MRL MS DMS Result MS DMS MS DMS
EP A 5030 802lE 0.005 0.0400 0.0400 ND 0.0362 0.0362 90 90
EPA 5030 802lE 0.005 0.0400 0.0400 ND 0.0352 0.0353 88 88
EPA 5030 802lE 0.005 0.0400 0.0400 ND 0.0386 0.0387 97 97
EPA 5030 80l5M 0.1 2.00 2.00 ND 1.84 1.87 92 94
7if
Date:
I 0 -I~ - ~ J
IMSl020597P
04071YOH.m, DMS 10/19/99
Units: mg/Kg (ppm)
Basis: Wet
Recovery
CAS
Acceptance
Limits
39-150
46-148
32-160
70-140
Relative
Percent Result
Difference Notes
<1
<1
<1
2
Page No.:
~IU_----
~ Analytical
Services'tIC, 6925 Canoga Avenue. Canoga Park, CA 91303· (818) 587-5550· Fax (818) 587-5555
-eHlfflIor--etJsfe!>V/~OmOm-A~snEcmsmRr
DATE 9/2-"1 /~or
1
PAGE
OF
PROJECT NAME~AJ2.vJAc;.~ ~F AMf 2.IC~# ~v¡"<7~-1 ~ / ()
PROJECT MANAGER CN\ \ k£ ~A~ Y U)
COMPANY/ADDRESS C-AL..I f!- ôi2-t\) \ A ~~ V l!l.ð-"> ýJIt£Ñ í~ ~
<
~13;lO \II f\ ~ðl..lNA.S Sr. I ~Th \ó4- !z
o
w's1'LAI~ V IL.\.. AL..It) c..A , 1"\(, 1- PHONE ~
o
, SAMPLERS SIGNATURE ffi
CJ)
~
::)
z
SAMPLE LAB
I.D, DATE TIME I.D.
~ ç éL ~ ~ 9k1/î"1 L,t:tðtfa1/- J S ð\'-
ßS (2, Ll-l\ I' -l. ,
13<;<2- (oD -)
\)S @., ~S - t.f
9 t; @., 1-0 -(
()ç ~ 1-5 -Co
ßS e <i.O - 1-
ᇒ ~s -<X'
ßS e. Ozo -9
~ in e. ~6 V CIj -l ~ ..,
~y/ #/ ~ /) R~D BY: TURNAROUND REQUIREMENTS
/ r~ '\¡v-':': -'-1- 24hr _48hr, _5Qay
SignaturE v j/ r ¿/ ~rfð'~ rJ "'fA. U. .l'! ...... t ~ Standard ,
Printed Name fJrinted_Name - Other (Specify)
~ ~f -~~
Firr~ I z-~I <2-7 f 7ðO £f.rt.~ J'1&1 I f()'ð Preliminary Results
Daterrïme v [)aterWne Requested Report Date
RELINQUISHED BY:
RECEIVED BY:
Signature
Signature
Printed Name
Printed Name
Firm
Firm
Daterrïme
Datemme
SAMPLE
MATRIX
ANAL VSIS REQUESTED
f!! ~~ /
o .e ,r if£:
'! /J ~ c
õ .ß ~ (6 {!J g
7::J({J ;s;., ~ fJ 0 ~
/Pø :Z:..!!1 "" ·:þc a
. ø '&0 § ~ ~?§:!~ §
"'.... ./:::.... <11 O!=\i::;'0J ¡g
(J cO & QQJ~' Ji:2 QJ '" ~'" $
§P.... ~a _"'" þ)c ~Ci) Ci) ~
c f?:.;p mC J!2Q~ò ~(j,$(j ~
co Q "'co I.JJ..... co 0 "'0 (j
t l\'>é
fv.
1 X
IX
I .)(
\x
l y
[)(
I Y.
I~
~
REPORT REQWlREMENTS
_ I. Routine Report
x:- II. Report (includes DUP,MS,
MSD, as required, may be
charged as samples)
_ III. Data Validation Report
(includes All Raw Data)
RWaCB
INVOICE INFORMATION:
SAMPLE RECEIPT:
P,O,#
Bill To
Shipping VIA:
Shipping #:
Condition:
-
Lab No:
SPECIAL INSTRUCTIONS/COMMENTS: .-or: \
SA"" P Lf£<; 4"" A L( 2.. tr..]) .-L f\J
'5/.JJI'IPLiPS /lVJA/2...I£.tž;D W I rl-/
vAN
M.Q ê I \...~
LAß
t'
\., Ø\ . l ß
V AtJA L Y ~f[. ~¡J FIX(¿.C> LoO'
I:> Y PL/P15
c.Q,J ~ / ¡t../'YJ MTEi£ /ý /1$ ¿jF "710Ù fPC>
nl~TP'R' IT'()~" \NHITF _ rpttrrn tn nri(" inAtrw YFII ow .I~h
d()(),()~
~Iu'- -
~ ~nQlytiCQI
-
-
-
-eH~F'!eS_V/I!ft!O_O~NJl!tSI~EdØ!S~RP
Services'nc, 6925 Canoga Avenue' Canoga Park, CA 91303' (818) 587-5550' Fax (818) 587-5555 DATE Cf/'L't/" PAGE a.- OF
PROJECT NAMEc..Afl...IA.)A~U OF AMEfZ\c.-; ~v).~- (øl\) ANAL VSIS REQUESTED
PROJECT MANAGER (/) ~~
COMPANY/ADDRESS Q..fZ- a:: o .8
w
z ' .S:I
<b <17 c::
:;:¡: ,~8 <17 c
I- o .. Go &~ <:5
z b!3 ~ ~ t:J 0 ~
0 J#C!J .:t' ~ 0è§ ,~o <:5
Ü "_ 0 (j......
PHONE u. ø& go ¡ ~ 'Ii ~~ /5
0
SAMPLERS SIGNATURE a:: OJ ç.... <17 O~::;'0j 11:1
W (5& ':>0 & o..q¡~. ~;2 ,!!! co ~co q¡
cc ;r:~ Qj tJ[5 ;¡y '" 8'[5 ~~ <b~ 1
SAMPLE LAB SAMPLE :;;:
::::>
I.D, DATE TIME I.D. MATRIX z
~/n( oJ t./.â orllJJth~ go.~%l-I..I ~Oll, t Y
(3b~ (~ t ' ,-no' ( X
ß(o~ CoS -r~ \ X
ß(g ~ -:}() .i-- N. I v...
r.>" §, 1-'< ...... 15 J )(
ß~~ ~ð .....[\j f "
86 e ~ç I ....l1 I )(
ß~ e.. "0 .v , / -t<:¿ .,. , 'I...
v
¿'/7~~ - 1iJR~DBY: TURNAROUND REQUIREMENTS REPORT REQIMREMENTS INVOICE INFORMATION: SAMPLE RECEIPT:
--- -,~ I 24hr 48hr, _5day _ I. Routine Report
~ , -X II. Report (includes DUP,MS,
Signature -,tY/ /' ~ ~#:J -. .".-II?£;t1 ¡q¡j X Standard P,Q.# Shipping VIA:
MSD, as required, may be
~ed Name Printed Name _ Other (Specify) charged as samples) Bill To Shipping #:
~ c..AS Provide Verbal _ III. Data Validation Report Condition:
FirrT17, /~7/Cr9 (KJi'Ç ~7Z.t¡/7q J -¡.,u Preliminary Results (includes All Raw Data)
- RwaCB
DateR ime l ~emme Requested Report Date Lab No:
RELINQUISHED BY: RECEIVED BY: SPECIAL INSTRUCTIONS/COMMENTS: -r,J VA;J
'SAmPLES AN A L Y 1:. E.J::::> ¡'Z-p (J 8 / L.- fi- '-Aß
Signature Signature 1>//Þ'J1 L~ S MAR'LoE-£> '''ß) ,1
Wl-rH A tV II L)' '1::./£ -::¡;-,¡ F I X E..b LAB
Printed Name Printed Name
Firm Firm G-G/MS
DatefTime DatefTime LðNr )R~ V'1 f'1J Ii. /;11 T'5 ð F ,>,tJõ PPb ßY
r>ISTRIAI JTION: WHITE· return to oriainAtor: YELLOW - lab
400-05
I
.<
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 80S, San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
I
LABORATORY REPORT
I
I
I
Prepared For: Columbia Analytical
6925 Canoga Avenue
Canoga Park, CA 91303
I
I
I Attention:
Project:
I
I
I
I
I
L. Ross Fenstermaker
L9904071
Sampled: 9/29/99
Received: 10/7/99
Reported: 10/13/99
This laboratory report is confidential and is intended for the sole use of
Del Mar Analytical and its client. This entire report was reviewed and approved for release.
CA ELAP Certificate #1197
AZ DHS Licence #AZ0428
I
I
DEL MAR ANALYTICAL
:~e~
Project Manager
I
Results pertain only to samples tested in the laboratory. This report shalt not be
reproduced, except in full, without wrillen permission from Del Mar Analytical.
IJ00643.COA <1 of 3>
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805. San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
II
.ê6¡G;;;br~A~åiyti~~¡êli~~rp~~j~~t¡b:L99Ô4B71
.6925 Canoga Avenue
. Canoga Park, CA 91303
Attention: L. Ross Fenstermaker
Sample Descript: Soil, B5@90
Lab Number: IJ00643
QC Batch: IJ10071S
...........................,.,.,.,.,.,.,.,.,.,.,.,.,.,"".'.'."""""""""""""'''''''''''''''':''''':':':"':"':':':':':':':':Š'~'~p, ,~'d'~:':'9/2:9/99":':"':',,,,,,,,:-,',.,.,..,.,...
Received: 10/7/99
Extracted: 1 0/1 0/99
Analyzed: 10/10/99
Reported: 10/13/99
I·....·..,··..
...
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.............................................
5.0
.....................................
N.D.
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromof1uoromethane (80-120).....
104%
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced. except in full. without written permission from Del Mar Analytical.
IJ00643.COA <2 of 3>
I
~
Del Mar Analytical
2852 Alton Ave., l!Vine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
I
Columbia Analytical
6925 Canoga Avenue
Canoga Park, CA 91303
Attention: L. Ross Fenstermaker
Extracted: 10/10/99
Analyzed: 10/10/99
Reported: 10/13/99
I
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.............................................
5.0
.....................................
N.D.
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120).....
106%
I
Results pertain only to samples tested in Ihe laboratory. This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
IJ00643,COA <3 of 3>
I
i<
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261-1228
1014 E. Cooley Dr., Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St, Suite B,120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed: 10/10/99
Sample: IJ00643
Batch: IJ10071S
Analyte R1 Sp MS
ppb ppb ppb
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
T etrach loroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
Matrix: Soil
MSD
MEAN
RPD PR
Acceptance
Limits
PR1
PR2
ppb
%
MPR
RPD
%
%
%
0 25 24 21 96% 84% 13% 90% 30 30-160
0 25 25 25 100% 100% 0.0% 100% 40 45-165
1.7 25 28 30 105% 113% 6.9% 109% 40 55-155
0 25 28 27 112% 108% 3.6% 110% 20 55-150
0 25 26 26 104% 104% 0.0% 104% 20 65-140
0.2 25 27 28 107% 111% 3.6% 109% 30 55-145
0 25 25 25 100% 100% 0.0% 100% 25 60-140
0 25 23 23 92% 92% 0.0% 92% 30 60-145
0 25 24 24 96% 96% 0.0% 96% 20 65-140
0 25 23 22 92% 88% 4.4% 90% 50 10-200
0 25 25 24 100% 96% 4.1% 98% 20 70-135
0 25 25 24 100% 96% 4.1% 98% 20 70-140
0 50 50 48 100% 96% 4.1% 98% 20 40-160
0 25 25 24 100% 96% 4.1% 98% 20 65-150
R1. . . . . . . . . . . . . . . . .. Result of Sample Analysis
Sp. . . . . . . . . . . . . . . . .. Spike Concentration Added to Sample
MS. . . . . . . . . . . . . . . . . . Matrix Spike Result
MSD. . . . . . . . . . . . . . .. Matrix Spike Duplicate Result
PR1................. Percent Recovery of MS; ((MS-R1) 1 SP) X 100
PR2. . . . . . . . . . . . . . . . . Percent Recovery of MSD; ((MSD-R1) 1 SP) X 100
RPD. . . . . . . . . . . . . . . . . Relative Percent Difference; ((MS-MSD)/(MS+MSD)/2) X 100
Acceptance Limits. . .. Statistically determined on an annual basis.
DEL MAR ANALYTICAL
I
¡(
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E Cooley Dr., Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406 (818) 779·1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St., Suite 8,120, Phoenix, ÄZ 85044 (480) 785,0043 FAX (480) 785'0851
Date
Analyzed:
10/10/99
Batch:
IJ10071S
Analyte
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
Tetrachloroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
St
Acceptance
PR Limits
R1
ppb
ppb
%
%
25 25 100% 40-145
25 24 96% 55-145
25 25 100% 60-140
25 27 108% 60-140
25 26 104% 65-135
25 25 100% 55-135
25 25 100% 65-130
25 23 92% 70-130
25 24 96% 70-125
25 22 88% 65-130
25 24 96% 75-125
25 25 100% 70-125
50 49 98% 70-130
25 24 96% 70-135
St. . . . . . . .. ......... Concentration of standard added to blank.
R1 . . . . . . .. ......... Standard Result
PR . . . . . . .. ......... Percent Recovery of R1; (R1 / St) X 100
DEL MAR ANALYTICAL
-~I~a- - -
Analytical
Services "I( 6925 Canoga Avenue· Canoga Park, CA 91303' (818) 587-5550· Fax (818) 587-5555
-
-C~ O~U&lPeD'lØB~T"'" A_Y~R~E~O~
DATE lo-t-~; PAGE I OF
PROJECT NAME L ~ ~ D 'i D -.:; I #
PROJECT MANAGER L - ~ò ç, <.. (-~ \'11--11 M It Y fil CJ)
COMPANY/ADDRESS (~L\)""tll A f\ ¡J~L.1nU1{ ~ílJI(£j ~
<1:
f-
Z
o
Ü
11.
o
II:
l1J
cc
:2
=>
z
ANAL VSIS REQUESTED
PHONE
SAMPLERS SIGNATURE
SAMPLE LAB SAMPLE
1.0, DATE TIME 1.0. MATRIX
ß s-@ 1 0 ?ll,Hî SCIL-
I (
.
l.u~
p A~
ù.e ~ ,52
I2J <tJ òC:
C: CJ . <tJ C
~ C ¡¡ CD f?> 8
b Go ¿s;., ,-:::; N 0 ~
'- ~cff :]::. Jff " }?~ a
"," E:: 0 f:} Vi\:' .....
~& go :::i ~ C:fV::!~ (5
(2) CD ~() ..i!' b ¿g~ <tJ~ Go
o è§ '" IJ:. .§..... It ð0r §f(J :&
<tJ '" .....0 0 I2J Q)' C: C <b I2J <b I2J
øfi5 fi5.... & Q...... l2Jã ,~C/) <C/) ~
~i6 i I2J i'Jp;; ÌÌì ~ 8'P;; {fj~ 12J~ .'¿
X
'}
!~«t~7SHED BY:
Sigrr~ ~f--'I W\~ -h
Printed Namtj Cì;v:J'
Firmjoh \ ç í I~o{
Daterrime
rt~r;
Signatr.)oQ lL/, L'J /\
'-..::lL, M - ('j ~~. A'()
printe~ M.W
Firm 10 iT- l()Ö:)
Daterrime
TURNAROUND REQUIREMENTS
24hr _48hr _5day
_ Standard
_ Other (Specify)
Provide Verbal
. Preliminary Results
P,O,#~_
Bill To
Shipping VIA:
Shipping #:
Condition:
Requested Report Date ¡(
REPORT REQUIREMENTS
_ I. Routine Report
~ II. Report (includes DUP,MS,
MSD, as required, may be
chatged as samples)
_ Ill. Data Validation Report
(includes All Raw Data)
RWaCS
INVOICE INFORMATION:
SAMPLE RECEIPT:
-
-
Lab No:
RELINQUISHED BY:
RECEIVED BY:
SPECIAL INSTRUCTIONS/COMMENTS:
\b bt"L Mmt.- \~VltJ€'
Signature
Signature
Printed Name
Printed Name
~ HDLþ \ìMC
Firm
Firm
Daterrime
Daterrime
nl~TD'Q' !TI0""· II\IUITC ~,..,..,,....... +,..., .-.rô,..,;..........t,..,...· vel t n\!II hh
~~,..,.ru::
I
I
I
I
il
I
I
I
I
I
)1
I
I
I
I
I
I
I
II
October 19, 1999
~t~olumbia
~ Ana!ytical
SerVices INC.
An Employee-Owned Company
Mike Tiffany
California Environmental
31320 Via Colinas
Suite 104
Westlake Village, CA 91362
Re: Car Wash of AmericalProject #EV298-1610
Dear Mike:
Enclosed are the results of the samples submitted to our mobile laboratory on September 28,
1999. The samples were sent to Del Mar Analytical for EP A Method 8260B. Please find their
report (#IJ00502) attached. For your reference, these analyses have been assigned our service
request number L9904070.
All analyses were performed in accordance with our laboratory's quality assurance program.
Results are intended to be considered in their entirety and apply only to the samples analyzed.
Columbia Analytical Services is not responsible for use of less than the complete report.
Columbia Analytical Services - Mobile Laboratory - is certified for environmental analyses by the
California Deparment of Health Services (certificate number: I2351, expiration: February 29,
2000).
If you have any questions, please call me at (818) 587-5550, extension 310.
Respectfully submitted,
Columbia Analytical Services, Inc.
L. Ross Fenstermaker
Project Chemist
LRF/kh
6925 Canoga Avenue . Canoga Porl.o;, CA 91303 . (818) 587-5550 . Fox (818) 587-5555
I
I 8015M
A2LA
ASTM
BOD
I BTEX
CAM
CARD
CAS Number
I CFC
CFU
COD
CRDL
I DEC
DEQ
DLCS
DMS
I DOE
DOH or DHS
ELAP
I EPA
EQL
GC
GCIMS
I IC
ICB
ICP
ICY
I J
LCS
I LUFT
I M
MBAS
I MCL
I MDL
MPN
MRL
MS
I MTBE
NA
NAN
NC
I NCASI
ND
NIOSH
I NTU
ppb
ppm
PQL
I QAlQC
RCRA
RPD
SIM
I SM
STLC
SW
I TCLP
TDS
TPH
tr
I TRPH
TSS
TTLC
I VOA
Columbia Analytical Services, Inc.
Acronyms
California DHS LUFf Method
American Association for Laboratory Accreditation
American Society for Testing and Materials
Biochemical Oxygen Demand
BenzeneffoluenelEthylbenzenelXylenes
California Assessment Metals
California Air Resources Board
Chemical Abstract Service Registry Number
Chlorofluorocarbon
Colony-Forming Unit
Chemical Oxygen Demand
Contract Required Detection Limit
Department of Environmental Conservation
Department of Environmental Quality
Duplicate Laboratory Control Sample
Duplicate Matrix Spike
Department of Ecology
Department of Health Services
Environmental Laboratory Accreditation Program
U.S. Environmental Protection Agency
Estimated Qauntitation Limit
Gas Chromatography
Gas ChromatographylMass Spectrometry
Ion Chromatography
Initial Calibration Blank sample
Inductively Coupled Plasma atomic emission spectrometry
Initial Calibration Verification sample
Estimated concentration. The value is less than the MRL, but greater than or equal to the MDL.
If the value is equal to the MRL, the result is actually <MRL before rounding.
Laboratory Control Sample
Leaking Underground Fuel Tank
Modified
Methylene Blue Active Substances
Maximum Contaminant Level. The lúghest permissible concentration of a substance
allowed in drinking water as established by the U.S. EP A.
Method Detection Limit
Most Probable Number
Method Reporting Limit
Matrix Spike
Methyl-tert -Butyl Ether
Not Applicable
Not Analyzed
Not Calculated
National Council of the paper industry for Air and Stream Improvement
None Detected at or above the Method Reporting/Detection Limit (MRUMDL)
National Institute for Occupational Safety and Health
Nephelometric Turbidity Units
Parts Per Billion
Parts Per MilIion
Practical Quantitation Limit
Quality Assurance/Quality Control
Resource Conservation and Recovery Act
Relative Percent Difference
Selected Ion Monitoring
Standard Methods for the Examination of Water and Wastewater, 18th Ed., 1992.
Solubility Threshold Limit Concentration
Test Methods for Evaluating Solid Waste, PhysicaVChemicalMethods, SW-846,
Third Edition, 1986 and as amended by Updates I, II, 1IA, and lIB.
Toxicity Characteristics Leaching Procedure
Total Dissolved Solids
Total Petroleum Hydrocarbons
Trace level is the concentration ofan analyte that is less than the PQL but greater than or equal to
the MDL. If the value is equal to the PQL, the result is actually <PQL before rounding.
Total Recoverable Petroleum Hydrocarbons
Total Suspended Solids
Total Threshold Limit Concentration
Volatile Organic Analyte(s)
'I
I
I
I
I
:1
I
I
I
I
I
I
I
I
I
I
I
I
I
Client:
Project:
Sample Matrix:
Sample Name:
Lab Code:
Test Notes:
Analyte
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl ter! -Butyl Ether
t
Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
B3 @ 20
L9904070-001
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 8015M 0.1
EPA 5030 802lE 0.010
Senice Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 ND
TPH as Gasoline does not include MmE.
7ff
1 S221020S97p
04070VOH,ITI, Sample 10/19/99
Date:
ID -/7 ·~1
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
I
I
I
I
I
I
I
I
I
I
I
I
Analyte
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl ter! -Butyl Ether
t
Approved By:
1 S22/020S97p
04070VOH,ITI - Sample (2) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Enviromnental
Car Wash of AmericalEV298-1610
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B3 @ 40
L9904070-002
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EP A 5030 802lB 0.005
EP A 5030 802lB 0.005
EP A 5030 802lB 0.005
EP A 5030 8015M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MTBE.
II
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
I NA 9/28/99 ND
I NA 9/28/99 0.006
I NA 9/28/99 ND
I NA 9/28/99 0.009
I NA 9/28/99 0.1
I NA 9/28/99 0.014
Date:
16-1~-;1
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
I
I
I
I
I
I
I
I
I
I
I
I
Analyte
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl tert-Butyl Ether
t
Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
B3 @ 60
L9904070-003
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EP A 5030 8021B 0.005
EP A 5030 8021B 0.005
EP A 5030 8021B 0.005
EP A 5030 8015M 0.1
EPA 5030 8021B 0.010
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/28/99 0.006
NA 9/28/99 0.009
NA 9/28/99 ND
NA 9/28/99 0.011
NA 9/28/99 0.2
NA 9/28/99 0.042
TPH as Gasoline does not include MmE.
711
1 S221020S97p
04070VOHJTI . Sample (3) 10119/99
Date:
IO'I?-;~
Page No,:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert-Butyl Ether
I
I
I
I
I
I
t
I
I Approved By:
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-1610
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B3 @ 70
L9904070-004
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8021B 0.005
EP A 5030 8021B 0.005
EPA 5030 8015M 0.1
EPA 5030 8021B 0.010
TPH as Gasoline does not include MmE.
71f
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 0.28
50 NA 9/29/99 0.98
I NA 9/28/99 0.086
1 NA 9/28/99 0.62
1 NA 9/28/99 6.4
1 NA 9/28/99 1.2
1 S22/020S97p
Date:
I D - " ' ; 9
04070YOH.IT1 ,Sample (4) 10/19/99
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
I
I
I
I
Analyte
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl tert -Butyl Ether
I
I
I
I
t
I
I
I Approved By:
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Enviromnental
Car Wash of America/EV298-161O
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B3 @ 75
L9904070-005
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 802lE 0.005
EP A 5030 8015M 0.1
EP A 5030 802lE 0.010
TPH as Gasoline does not include MrBE.
7Lf
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
50 NA 9/28/99 2.9
200 NA 9/29/99 17
50 NA 9/28/99 4.3
50 NA 9/28/99 28
50 NA 9/28/99 290
50 NA 9/28/99 3.1
Date:
/0-11·;1
1 S221020S97p
04070VOHJTl - Sample (5) 10/19/99
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I
Analytical Report
Client:
I Project:
Sample Matrix:
California Environmental
Car Wash of AmericalEV298-1610
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
I
I
MTBE, BTEX and TPH as Gasoline
Sample Name: B3 @ 80 Units: mg/Kg (ppm)
I Lab Code: L9904070-006 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 1 NA 9/28/99 0.042
Toluene EPA 5030 802lE 0.005 1 NA 9/28/99 0.015
I Ethylbenzene EPA 5030 802lE 0.005 1 NA 9/28/99 ND
Xylenes, Total EP A 5030 802lE 0.005 1 NA 9/28/99 0.049
TPH as Gasoline EP A 5030 8015M 0.1 1 NA 9/28/99 0.7
I Methyl tert-Butyl Ether EPA 5030 802lE 0.010 1 NA 9/28/99 0.37
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 7tf Date: /O-I~',~
I S22/020597p
I ~70VOH.rrl ,Sample (6) 10/19/99 Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert-Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I S22/020S97p
I 04070VOH.rn ,Sample (7) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Enviromnental
Car Wash of AmericalEV298-l61O
Soil
MTBE, BTEX and TPH as Gasoline
B3 @ 85
L9904070-007
t
Prep Analysis
Method Method MRL
EP A 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8021B 0.005
EPA 5030 80l5M 0.1
EPA 5030 8021B 0.010
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/28/99 0.11
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 0.016
NA 9/28/99 0.4
NA 9/28/99 0.15
TPH as Gasoline does not include MmE.
if
Date:
'o-I~-11
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
1 S22/020S97p
I 04070VOH.IT1 ,Sample (8) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-1610
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B3 @ 90
L9904070-008
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EP A 5030 802lB 0.010
TPH as Gasoline does not include MmE.
7£1
Units: mg/Kg (pprn)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 ND
I NA 9/28/99 ND
I NA 9/28/99 ND
I NA 9/28/99 ND
I NA 9/28/99 ND
1 NA 9/28/99 0.12
Date:
/ö -/î -11
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
I
I
Sample Name:
Lab Code:
Test Notes:
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert-Butyl Ether
I
I
I
I
I
I
I
I
I
t
Approved By:
I S22/020597p
04070VOH,ITI - Sample (9) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B3 @ 100
L9904070-009
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EP A 5030 802lB 0.010
TPH as Gasoline does not include MmE.
711
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 ND
I NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
Date:
16 -/1- ~í
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Environmental Service Request: L9904070
Project: Car Wash of AmericalEV298-l61O Date Collected: 9/28/99
Sample Matrix: Soil Date Received: 9/28/99
I
MTBE, BTEX and TPH as Gasoline
I
Sample Name: B3 @ 110 Units: mgIKg (ppm)
I Lab Code: L9904070-01O Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EP A 5030 8021B 0.005 NA 9/28/99 0.015
Toluene EP A 5030 8021B 0.005 NA 9/28/99 0.070
I Ethylbenzene EP A 5030 8021B 0.005 NA 9/28/99 0.008
Xylenes, Total EP A 5030 8021B 0.005 NA 9/28/99 0.052
TPH as Gasoline EP A 5030 80l5M 0.1 NA 9/28/99 0.5
I Methyl tert -Butyl Ether EP A 5030 8021B 0.010 NA 9/28/99 0.013
I
I
I
I
I
t TPH as Gasoline does not include MTBE.
I
I
I Approved By: 71f Date: )()-17-1Î_
1 S221020597p
I 04070VOH,Tfl ,Sample (10) 10/19/99 Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
I
t
I
I Approved By:
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-1610
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B3 @ 120
L9904070-011
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EP A 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8015M 0.1
EP A 5030 8021B 0.010
TPH as Gasoline does not include MmE.
7if
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 0.017
1 NA 9/28/99 0.091
1 NA 9/28/99 0.011
1 NA 9/28/99 0.072
1 NA 9/28/99 0.7
1 NA 9/28/99 ND
IS221020S97p
Date:
10-(7-11
04070VOH.ITl - Sample (11) 10/19/99
Page No.:
--- - --
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
I
t
I
I Approved By:
1 S221020S97p
I
04070VOH,JT1 - Sample (12) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B3 @ 130
L9904070-012
t
Prep Analysis
Method Method MRL
EP A 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MfBE.
7#
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
Date:
lo-(~-1L
Page No,:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl tert -Butyl Ether
I
I
I
I
I
I
I t
I
I
I
I
Approved By:
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Enviromnental
Car Wash of AmericalEV298-l61O
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B3 @ 140
L9904070-013
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 80l5M 0.1
EPA 5030 802lE 0.010
TPH as Gasoline does not include MmE.
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 ND
1 NA 9/28/99 0.018
1 NA 9/28/99 ND
1 NA 9/28/99 0.017
1 NA 9/28/99 0.2
1 NA 9/28/99 ND
7f1
Date:
/D'(;-~í
I S221020597p
Q4070VOH,JTI ,Sample (13) 10/19/99
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I S221020S97p
I 04070VOH.m - Sample 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-1610
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B4 @ 10
L9904070-014
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8015M 0.1
EPA 5030 8021B 0.010
TPH as Gasoline does not include MTBE.
7ir
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
Date:
/0-/1-,í
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl telt-Butyl Ether
I
I
I
I
I
I
I
I
I.
t
Approved By:
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Enviromnental
Car Wash of America/EV298-l61O
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B4 @ 20
L9904070-0 15
t
Prep Analysis
Method Method MRL
EP A 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8021B 0.005
EP A 5030 80l5M 0.1
EPA 5030 8021B 0.010
TPH as Gasoline does not include MfBE.
71f
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date ResulL
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
Date:
Ib-{; -71
1 S221020597p
04070VOHJT2 - Sample (2) 10/19/99
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ter! -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-l61O
Soil
MTBE, BTEX and TPH as Gasoline
B4 @ 30
L9904070-0 16
t
Prep Analysis
Method Method MRL
EP A 5030 802lB 0.005
EP A 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EP A 5030 80l5M 0.1
EPA 5030 802lB 0.010
Senice Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 ND
NA 9/28/99 ND
TPH as Gasoline does not include MfBE.
711
I S221020S97p
04070VOH.m, Sample (3) 10/19/99
Date:
10 - I; ,7 ~
Page No,:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl tert-Butyl Ether
I
I
I
I
I
I t
I
I
I Approved By:
1 S221020597p
I 04070VORm· Sample (4) 10/19/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Enviromnental
Car Wash of AmericaÆV298-1610
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B4@40
L9904070-O 17
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MmE.
Jíf
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
Date:
ID-fÎ-71
Page No,:
I
I
I Client:
Project:
Sample Matrix:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-161O
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
I
I MTBE, BTEX and TPH as Gasoline
Sample Name: B4 @ 50 Units: mg/Kg (ppm)
I Lab Code: L9904070-018 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EP A 5030 80218 0.005 I NA 9/28/99 ND
Toluene EP A 5030 80218 0.005 I NA 9/28/99 ND
I Ethylbenzene EPA 5030 80218 0.005 I NA 9/28/99 ND
Xylenes, Total EP A 5030 80218 0.005 I NA 9/28/99 ND
TPH as Gasoline EPA 5030 8015M 0.1 1 NA 9/28/99 ND
I Methyl tert -Butyl Ether EPA 5030 80218 0.010 1 NA 9/28/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 7LI Date: ID-I~-;1
I S221020597p
I 04070VOH,m· Sample (5) 10/19/99 Page No.:
I COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
Client: California Environmental Senice Request: L9904070
I' I Project: Car Wash of America/EV298-l61O Date Collected: 9/28/99
Sample Matrix: Soil Date Received: 9/28/99
I
MTBE, BTEX and TPH as Gasoline
I
Sample Name: B4@60 Units: mg/Kg (ppm)
I Lab Code: L9904070-Ol9 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte # Method, Method MRL Factor Extracted Analyzed Result Notes
I Benzene EP A 5030 8021B 0.005 NA 9/28/99 ND
Toluene EP A 5030 8021B 0.005 NA 9/28/99 ND
I Ethylbenzene EPA 5030 8021B 0.005 NA 9/28/99 ND
Xylenes, Total EP A 5030 8021B 0.005 NA 9/28/99 ND
TPH as Gasoline EPA 5030 80l5M 0.1 NA 9/28/99 ND
I Methyl tert -Butyl Ether EPA 5030 8021B 0.010 NA 9/28/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 7ff Date: ló -f? . ? 1
1 S221020S97p
I 04070VOH.m, Sample (6) 10/19/99 Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ter! -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I
I S221020S97p
04070VOH.IT2 - Sample (7) 10/19199
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Envirorunental
Car Wash of AmericalEV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
B4 @ 75
L9904070-020
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8015M 0.1
EP A 5030 8021B 0.010
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/28/99 0.009
NA 9/28/99 0.006
NA 9/28/99 ND
NA 9/28/99 0.045
NA 9/28/99 0.4
NA 9/28/99 1.1
TPH as Gasoline does not include MmE.
7if
Date:
ló'(7 ,;~
Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
"!PH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I t
I
I
I Approved By:
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Enviromnental
Car Wash of AmericalEV298-161O
Soil
Service Request: L9904070
Date Collected: 9/28/99
Date Received: 9/28/99
MTBE, BTEX and TPH as Gasoline
B4 @ 80
L9904070-021
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EP A 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
"!PH as Gasoline does not include MmE.
1f
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 0.007
1 NA 9/28/99 0.1
1 NA 9/28/99 1.2
1 S221020597p
Date:
'O-'1-~1
04070VOH.m - Sample (8) 10/19/99
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Enviromnental Service Request: L9904070
Project: Car Wash of AmericalEV298-161O Date Collected: 9/28/99
Sample Matrix: Soil Date Received: 9/28/99
I
I MTBE, BTEX and TPH as Gasoline
Sample Name: B4 @ 85 Units: mg/Kg (ppm)
I Lab Code: L9904070-022 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lB 0.005 I NA 9/28/99 0.010
Toluene EPA 5030 802lB 0.005 1 NA 9/28/99 0.017
I Ethylbenzene EPA 5030 802lB 0.005 1 NA 9/28/99 ND
Xylenes, Tótal EPA 5030 802lB 0.005 I NA 9/28/99 0.021
TPH as Gasoline EPA 5030 8015M 0.1 I NA 9/28/99 0.2
I Methyl fert -Butyl Ether EPA 5030 802lB 0.010 I NA 9/28/99 1.2
I
I
I
I
I
t TPH as Gasoline does not include MTBE.
I
I
I Approved By: 71f Date: lö-, ~ ,71
1 S221020S97p
I 04070VOHJT2, Sample (9) 10119/99 Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Environmental Service Request: L9904070
Project: Car Wash of America/EV298-1610 Date Collected: 9/28/99
Sample Matrix: Soil Date Received: 9/28/99
I
MTBE, BTEX and TPH as Gasoline
I
Sample Name: B4@90 Units: mgIKg (ppm)
I Lab Code: L9904070-023 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 1 NA 9/28/99 0.018
Toluene EPA 5030 802lE 0.005 1 NA 9/28/99 0.020
I Ethylbenzene EPA 5030 802lE 0.005 1 NA 9/28/99 ND
Xylenes, Total EPA 5030 802lE 0.005 1 NA 9/28/99 0.021
TPH as Gasoline EP A 5030 8015M 0.1 1 NA 9/28/99 0.2
I Methyl ter! -Butyl Ether EP A 5030 802lE 0.010 1 NA 9/28/99 0.53
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 7ff Date: ID-/7-91
1 S221020597p
I 04070YOH.m, Sample (10) 10/19/99 Page No.:
I COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
Client: California Enviromnental Service Request: L9904070
I Project: Car Wash of AmericaÆV298-1610 Date Collected: NA
Sample Matrix: Soil Date Received: NA
I
MTBE, BTEX and TPH as Gasoline
I
Sample Name: Method Blank Units: mg/Kg (ppm)
I Lab Code: L990928-MB Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 8021B 0.005 1 NA 9/28/99 ND
Toluene EP A 5030 8021B 0.005 1 NA 9/28/99 ND
Ethylbenzene EPA 5030 8021B 0.005 I NA 9/28/99 ND
I Xylenes, Total EPA 5030 8021B 0.005 I NA 9/28/99 ND
TPH as Gasoline EP A 5030 8015M 0.1 1 NA 9/28/99 ND
Methyl tert-Butyl Ether EPA 5030 8021B 0.010 1 NA 9/28/99 ND
I
I
I
I
I
I t TPH as Gasoline does not include MmE.
I
I 7£f
I Approved By: Date: JÕ-I~-;í
I S221020.s97p
I 0-4070VOH.ITI - MB1ank 10/19/99 Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I QNQC Report
I Client: California Enviromnental Service Request: L9904070
Project: Car Wash of ArnericaÆV298-161O Date Collected: NA
Sample Matrix: Soil Date Received: NA
Date Extracted: NA
I Date Analyzed: NA
Surrogate Recovery Summary
MTBE, BTEX and TPH as Gasoline
I Prep Method: EPA 5030 Units: PERCENT
Analysis Method: 8021 B/80 15M Basis: Wet
I Test Percent Recovery
Sample Name Lab Code Notes 4-Bromofluorobenzene 4-Bromofluorobenzene
I B3 @ 20 L9904070-00 I 98 91
B3 @ 40 L9904070-002 103 105
I B3 @ 60 L9904070-003 96 88
B3 @ 70 L9904070-004 99 96
B3 @ 75 L9904070-005 105 114
I B3 @ 80 L9904070-006 96 90
B3 @ 85 L9904070-007 97 92
B3 @ 90 L9904070-008 87 81
I B3 @ 100 L9904070-009 76 71
B3 @ 110 L9904070-01O 94 89
B3 @ 120 L9904070-011 88 81
B3 @ 130 L9904070-0 12 83 77
I B3 @ 140 L9904070-013 95 88
I
I
I
I
CAS Acceptance Limits: 60-130 60-140
I
I
I Approved By: 7Lf Date: If)-I;- ?L
SUR2l061197p
I 04070VOH,1n . SUR2 (2) 10/19/99 Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I QA/QC Report
I Client: California Environmental Service Request: L9904070
Project: Car Wash of AmericaÆV298-1610 Date Collected: NA
Sample Matrix: Soil Date Received: NA
Date Extracted: NA
I Date Analyzed: NA
Surrogate Recovery Summary
MTBE, BTEX and TPH as Gasoline
I Prep Method: EPA 5030 Units: PERCENT
Analysis Method: 802lB/80 15M Basis: Wet
I Test Percent Recovery
Sample Name Lab Code Notes 4-Bromofluorobenzene 4-Bromofluorobenzene
I B4@1O L9904070-014 76 68
B4 @ 20 L9904070-0 15 81 74
I B4 @ 30 L9904070-016 98 89
B4 @ 40 L9904070-017 93 87
B4 @ 50 L9904070-O 18 86 80
I B4@60 L9904070-019 91 82
B4 @ 75 L9904070-020 89 83
B4 @ 80 L9904070-021 91 84
I B4 @ 85 L9904070-022 92 85
B4 @ 90 L9904070-023 96 89
Method Blank L990928-MB 93 86
B3 @ 20 L9904070-00 1MS 109 106
I B3 @ 20 L9904070-001I>MS 96 97
B4 @ 20 L9904070-015MS 86 88
B4 @ 20 L9904070-015I>MS 75 96
I
I
I
I
CAS Acceptance Limits: 60-130 60-140
I
I
I Approved By: 11 I>ate: 10 '/~ - f1_
SUR2l061197p
I 04070VOH.m, SUR2 (2) 10/19/99 Page No.:
I
I
Elient:
roject:
ample Matrix:
I
I
Sample Name:
aab Code:
lIrest Notes:
I
ra1yte
Benzene
IOluene
thylbenzene
1PH as Gasoline
I
I
I
I
I
I
I
I
lpproved By:
COLUMBIA ANALYTICAL SERVICES, INC.
QNQC Report
California Environmental
Car Wash of AmericalEV298-161O
Soil
Service Request: L9904070
Date Collected: NA
Date Received: NA
Date Extracted: NA
Date Analyzed: 9/30/99
Matrix SpikelDuplicate Matrix Spike Summary
MTBE, BTEX and TPH as Gasoline
B3 @ 20
L9904070-001MS,
Units: mg/Kg (ppm)
Basis: Wet
L9904070-00 lDMS
Percent Recovery
CAS Relative
Prep Analysis Spike Level Sample Spike Result Acceptance Percent Result
Method Method MRL MS DMS Result MS DMS MS DMS Limits Difference Notes
EPA 5030 8021B 0.005 0.0400 0.0400 ND 0.0427 0.0400 107 100 39-150 7
EPA 5030 8021B 0.005 0.0400 0.0400 ND 0.0431 0.0391 108 98 46-148 10
EPA 5030 8021B 0.005 0.0400 0.0400 ND 0.0459 0.0425 115 106 32-160 8
EP A 5030 8015M 0.1 2.00 2.00 ND 2.48 2.27 124 114 70-140 9
71J
Date:
I D -/7 -11
DMSl020S97p
I 04070VOH.rn ,DMS 10119/99
Page No.:
I
I
COLUMBIA ANALYTICAL SERVICES, INC.
QAlQC Report
Senice Request: L9904070
Date Collected: NA
Date Received: NA
Date Extracted: NA
Date Analyzed: 9/30/99
'Iient: California Environmental
roject: Car Wash of AmericaÆV298-161O
ample Matrix: Soil
'pproVed By:
~MSl020597P
. . 04070VOH.m, DMS 10119/99
I
I
Sample Name:
tb Code:
est Notes:
I
talyte
Benzene
IOluene
thylbenzene
TPH as Gasoline
I
I
I
I
I
I
I
I
Matrix SpikeIDuplicate Matrix Spike Summary
MTBE, BTEX and TPH as Gasoline
B4 @ 20
L9904070-0 ISMS,
L9904070-O 15DMS
UIÙtS: mgIKg (ppm)
Basis: Wet
Percent Recovery
CAS Relative
Prep Analysis Spike Level Sample Spike Result Acceptance Percent Result
Method Method MRL MS DMS Result MS DMS MS DMS Limits Difference Notes
EPA 5030 802lB 0.005 0.0400 0.0400 ND 0.0371 0.0330 93 82 39-150 12
EPA 5030 802lB 0.005 0.0400 0.0400 ND 0.0369 0.0323 92 81 46-148 13
EPA 5030 802lB 0.005 0.0400 0.0400 ND 0.0381 0.0346 95 86 32-160 10
EP A 5030 8015M 0.1 2.00 2.00 ND 2.07 2.05 103 102 70-140 <1
7U
Date:
'D--/~~~i
Page No.:
~~---
~ S...VlCes'nc, 6925 Canoga Avenue· Canoga Park, CA 91303. (818) 587-5550. Fax (818) 587-5555
~H.O~sfebvmO.Om-A~SnE~SmRr
DATE 9/'J.z/~'i PAGE l
OF
tJ
PROJECTNAMEct\(tV>fótl OF AME.tuC.t.# E\I~~i - I ~ I ð
PROJECT MANAGER t'\'\ \ 't....~ 11 r: F l\ tJ )1
COMPANY/ADDRESS ~4 L I Fð1Z-N \ Þ. GEtJ'J ~~ IkttJíAL
3ß~~ V!A <!.ðLIPJA~ c:m;: ló4
W~STL.A~E. VL\,..\'f¥...(. '-A. I ,)3'~ PHONE
J
SAMPLERS SIGNATURE
SAMPLE
1.0.
~6 @-:lö
ß~ @., +t)
133 @ ~6
~"ê ï-D
ß? ~ ..,.c;
ß1@, ~ð
ß1 e ff)
ß~ ~ o,ó
~) e (ðÖ
ß=s @ IIC
I~~//
SIgna ure v /t' ¿/
pri~e
Fir~ /~ 9fi
Dattf/Time"
DATE
bL I
, r~.xA'
I
TIME
LAB
1.0.
ANAL VSIS REQUESTED
~
~ ~
.8 <. "\
o <: ~ t)~ .~
cz¡ /J r:::
,Ii; 0 0 & c
õ' '/j & ço '" g
b'" ".-:::; roO '"
cz¡ q;¡ -;:".... :,;
,'f:; ø .... ~ Çl)o '¿)c $?
~. -gO § ~ gr: "<~ &
ø ",I.i. e....f!! ð~ §/fJ ~
~q;¡ èO & o..Qf~ §;2 ~ (¡) ~(¡) Qf
~Q ~~ - ~ Ç])~ :;:;!¡fJ cz¡!¡fJ :$
... ;1:",!Jj S ~"..[p~ "'~ ~
SAMPLE
MATRIX
C/)
a:
w
z
<{
I-
Z
o
ü
u..
o
a:
w
CD
::2:
::>
z
L ttct l)~~lð- \ 'Sål\... {~
-~ ,^
-, , 'I...
-I} , '" 'ì'1è
-s 1><- ( ><:
-Cø -i. ~
-1- ~ X)
-~ I 't.. ,(>(
-~ IÝ- --
-/0 IX.
Y:
ED BY:
.oL /I
IA j/~J.
~nature ~ "'-
II ":1ð~ N 'Th r-J~ ""''''....,
Printed Name
c.~s.
~i '£<6/o.c;
Date/Time
.~ REL gY: . J RECEIVEq BY:
. ~ (i'L._ -- ~~ I/V\,y
~\lc¡t}lre) ~. t' £J ~. Signatur '. ì -5 " 1_
.~ I£: 71" '" AI.,.., I"/P1.-""" ,À'"
Printed Name printedßa.t\lé.L U ~
aA~ LÂ~~
,717lt1 /z4t; Fir3Zb.c./s, l~4.('
I'" D~}efflme Date~lme
'~M,~ tIh/L-"" ~c-
('P(""> I r ~ ,
TURNAROUND REQUIREMENTS
24 hr 48 hr, 5 day
Á Standard
_ Other (Specify)
Provide Verbal
Preliminary Results
REPORTREQ~EMENTS
I. Routine Report
Å. II. Report (includes DUP,MS,
MSD, as required, may be
charged as samples)
_ III. Data Validation Report
(includes All Raw Data)
_ RWaCB
INVOICE INFORMATION:
SAMPLE RECEIPT:
P.O,#
Bill To
. Shipping VIA:
Shipping #:
Condition:
-
Requested Report Date
Lab No:
SPECIAL INSTRUCTIONS/COMMENTS: 'Ý A. ~
SA N\ ~ \.. ~ SAN A L Y 1:dž.b .::r:N )'Y\Qß t L , c....A 13
$ A Mp\...£LS #11\ A'R ¥-[. 'D IN lí"H \. \. í1J (( 1.\ rJ A L'i '2:. r;: ~t0
MNrlf2fV\ JV\we:.. H rTS OF 7/ðõ rrß ~y ¿;c.!fI1S
f' I ~€'b L.A I)
r""C.,-OlOl "'0"" '~'1-I'T~ + r'/':'It.'r.... t,..., ""''';'''';1"'I'1Itl'"\''' vel I""^,. '~h
jlf"'If"!J,r:;
«=~~ :5Ca":~"":ooga:CA9::'~,=~~.~~:~~~~::N~:~"Ef:S~Rr
PROJECT NAME f' A~LÙA SJ./ ~F AM~""l~-A ~ \I ¡q "i - I it, It) ANAL VSIS REQUESTED
'~ CI) tN> .
§ ~
o -e It'.~
,/! fJ ,,§ 0
'8 e CI) fgP> 0
b& ~ ~ ¿J 0 ~
~ .~ø ~ § fl>d 80 ~
!Jj~ 80 §.::>:"8~ "'<~ 0
/.::.fg Q) b <I1R;j ~R;j co
ø& 0 & o.ti; {::: ~fJ jfJ J
~ _ ~o "'" 0,0 .~Ç/) Ç/) «::
3ì 'è) ctJ& /.::.IJJ ~& '::>:e¡ Qje¡ (j
IX
t,X
, '-/.,
I ~
Jý
I. X
I )(...
Ix.
~ J)(
ß ~ ~ ~ f) -..JI¡ ,/ -7JJ" I X.
~ ~ (\ /")REC~Y: TURNARðuND REQUIREMENTS
/ ~ /~ ~ .... y ~1t:JA1f.' A. 24hr 48 hr. _5(jay
Signature '/' L-/ ~~~¡J ~{)¿ J ~S1andard
print~~me, Primed Name ~11"4 _ Other(Specify) .
G.-if:I I ~....A<" Provide Verbal
Firlf/L. ../7_"" F~/2-S2 m Preliminary Results
Da'têfTime'" Da(efTime I Requested Report Date
PROJECT MANAGER
COMPANY/ADDRESS c..£..
C/)
II:
W
Z
<;:
I-
Z
o
ü
u.
o
II:
W
In
~
::J
Z
PHONE
SAMPLERS SIGNATURE
SAMPLE
I.D.
ß~ l:tÖ
~'3 e t') 1)
ß3 @. 1t.J.õ
B4 ~ I Ò
(34- e :lð
ß\f ~ ,6
1:>t e +ö
ßl . ~ ç~
B~,~ ~a
LAB
I.D.
SAMPLE
MATRIX
DATE
'VPt/,,,
TIME
L cri l)«f-\"1 t) -0
-n
-r~
-1'1
-IS
\ -l~
\ -'t
-l~
-l~
SÕ}L
I
f
6è
INVOICE INFORMATION:
REPORT REQWlREMENTS
_ I. Routine Report
.x. II. Report (includes DUP,MS.
MSD. as required, may be
charged as samples)
_ III, Data Validation Report
(includes All Raw Data)
_ RWaCB
P,O,#
Bill To
ð R""IN~D BY:
nY I ,. IJ
V"
~H,J 7lJ,J~A~
~~ Name
~ «1/0/1 IX""Ç
()atefTJfne
SPECIAL INSTRUCTIONS/COMMENTS:
SAY"1~ ArJALYê.E.î>
SA rvt f'\-~ 'f\I1 A R l'- '- [)
.JjJ Þ"iOB1Lt. Lt\G vAtJ
VI Î~ \\ fij" AN A L"{ 1:f:..
hI~C~.~_Dk
SirjñatuO /d ~ J ~ ~
Printed ~"rT-) (J' ~
FirE11 ìc. Ie y I f\q ¡(""
Da1efTime
a~ (rY-t..Jv--
,
t!AN F I ~IY> 1'VI'Tß1í..
Ht1"$ ðF ?Ioð p,~
.
..-,
r"\1~TPIRIITlnM' '^, ...flTr= _ røtllrn tf""'1 ",.i,,;,,~tru" VJ='I' (")'M _ '~h
SAMPLE RECEIPT:
Shipping VIA:
Shipping #:
Condition:
.
Lab No:
:IN F I x.~f) wi
f3v (;c. / JI11. 5
11""_""
-~I.øla - - - -
Analytical
ServiceS'lI(,
PROJECTNAMµ~Atsµ cç AlKi(tt;#. tV ~q~-Ibla
-tHmR of!leus~vadJ!ltr~ AmvSftE~sflllbRr
DATE 9/di/~~-
6925 Canoga Avenue' Canoga Park, CA 91303· (818) 587-5550' Fax (818) 587-5555
PROJECT MANAGER
COMPANY/ADDRESS c.E..
SAMPLERS SIGNATURE
SAMPI,.E_
1.Q...t-J' _ À DATE
Btt @ .~\)V ~/'l.,blt
ß'f @ ~~: . 1
ß II ~ 'io "'1ft ~ . .,
PHONE
LAB
TIME 1.0.
I ~bc .?1ð-)t
I -ll
or -z.~
ANAL VSIS REQUESTED
SAMPLE
MATRIX
$ð\\-
J
~
Co} "".)..,
1:: i;:>oJ
o ~
o -e ~ 0 ,!¿
<l.> /J c::
.f; 0 ¿g 0
õ fj ~ (60' g
b !3 ;>,;;§ r;::;
,~c:J ~ -! CfJè§ Bc ~
/JJ -gO §:S; g~ ~~ &
ài& It) If. .§- If ð?t §?iJ ¡g
$:I $:I.... '- c:; _ "-c .-:::; '" '"
;;t:0 ~ <l.> Qr:o ~ ~ õJ9:j (¡j;Jf <l.>;Jf ~
\ X ~
I JC t;(-
f >< VX""'
(/)
a:
w
z
<ë
I-
Z
o
Ü
LL.
o
a:
w
m
:2
::J
Z
~
J ¡1Ifi ""''J.ØS~BY: ^ JlFCE~Y: 'TURNAROUND REQUIREMENTS
',!:<,'£,A// _ ~ ~ -t::....... I "'; ~ ~ ft 24 hr _ 48 hr, _ 5 day
g at re // / ./ ~~~ ~~,J 1A1Jc1J."", A~ Á Standard ,
Pril]!.e~me ~n ed Name - Other (Specify)
/~ A c.::.., ~ _ Provide Verbal
0/12A-7 1"1 ~iz.y¡'ti Preliminary Results
D¡{tefTimd' [yitefTime Requested Report Date
~R~N~BY:
.L ,_ I>
nat~;:w ~ ' [ 14 ,.)
~~~Name I
C¡7t-'J 19r Ii ~
~tefTit\le \~
":'.r 11'_. ,
_ / RECf,lVED BY:
'cJ(1n t. k
Sign8¡tlJj"! J J
/""'1 e..1...... /I ^A-
printed~m¡. ~
Fir~ /)G /"4 IRét!f
DatefTime
4.--/ !Tl/-J-=---
()
{ft ~,
REPORT REQWlREMENTS
I. Routine Report
K II. Report (includes DUP,MS.
MSD, as required, may be
charged as samples)
_ III. Data Validation Report
(includes All Raw Data)
_ RWaCB
INVOICE INFORMATION:
P,O,#
Bill To
SPECIAL INSTRUCTIONS/COMMENTS:
5Ar'I1 PLf-S ANALY1-1;.. D ::IN fk()ß Lft LA'>
\.\ "3\ ( ,
51J1I1 PLl<; MA~"fC..~ £¡.) ITH :tV AtJALY l [;
CðN~ p..~ MíߣL H!'r:; ôf= Ì'ICJð PPB By
nl~TRIRIITlnN' WHITF· r"'lIm In nrlnlnn!",' YFII nw . Inh
PAGE
3
OF
SAMPLE RECEIPT:
Shipping VIA:
Shipping #:
Cond~ion:
Lab No:
V'Aß
:LJ f I X{;.. )
6,-1 Jh S
"3
LAß
4nn·no;
I
.<
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr,. Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr.. Suite 805, San Diego, CA 92123
9830 South 51st St., Suite B'120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785·0043 FAX (480) 785,0851
I
LABORATORY REPORT
I
I
I
I
I
I .
II
Project:
I
I
I
I
Prepared For:
Columbia Analytical
6925 Canoga Avenue
Canoga Park, CA 91303
L. Ross Fenstermaker
L9904070
Sampled: 9/28/99
Received: 1 0/6/99
Reported: 10/12/99
This laboratory report is confidential and is intended for the sole use of
Del Mar Analytical and its client. This entire report was reviewed and approved for release.
I
CA ELAP Certificate #1197
AZ DHS Licence #AZ0428
I
I
I DEL MAR ANALYTICAL
.~e~
" Project Manager
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00502.COA <1 of 13>
I
~ Del Mar Analytical
1 ::::::::::::::::::::,::::::::::::::::::::::::.::::.......... ..................,.......................... :-:.:.:::::::::::::::::::::::::::::::::::::::.:.:.:............
¡¡¡¡rc6iÚnïb¡a . AiiáIŸÜëàl" ········c¡ienfPro ediÓ:C99ó4ÔfÔ··
1 f¡ 6925 Canoga Avenue
:¡:¡:Canoga Park, CA 91303 Sample Descript: Soil, B3@70
¡¡¡¡¡Attention: L. Ross Fenstermaker Lab Number: IJ00502
::::: QC Batch: IJ08011 S
1·:·:·:·:·:·:·:·:·:·:-:·:·:·:·:·:·:·:···:..········
2852 Alton Ave,. Irvine, CA 92606
1014 E Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'II, Van Nuys, CA 92406
9484 Chesapeake Dr" Suite 805, San Diego, CA 92123
9830 South 51st St.. Suite 8'120, Phoenix, AZ 85044
(949) 261·1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785-0043 FAX (480) 785.0851
. ...............................................:.:.:.:.;.;.:.;.:.".:.:.:.:.:.:.:.:;:;:.:;::>:::::::::::::::::::::::::::::.:::::::::::;:::::::::::::::::::::
. ..... .... .... ... ..... .....................
Sampled: 9/28/99
Received: 10/6/99
Extracted: 1 0/9/99
Analyzed: 10/9/99
Reported: 10/12/99
. . .. ... ...................................
. ......................
.... ;:::::::;:;:;:;::::::::::::.:.;.....
MTBE (EPA 8260B)
1
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
1 Methyl tert-Butyl Ether... ........ ........... ...... .................
25
.....................................
1,300
1
1
1
1
1
I
1
I
I
I
1
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 5,
1
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120)..... 95%
1
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
IJ00502.COA <2 of 13>
I 2852 Alton Ave" Irvine, CA 92606 (949) 261,1022 FAX (949) 261-1228
~ I 1014 E. Cooley Dr., Suite A, Colton. CA 92324 (909) 370,4667 FAX (909) 370,1046
Del Mar Analytlca 16525 Sherman Way, Suite C-11, Van Nuys. CA 92406 (818) 779,1844 FAX (818) 779,1843
I . 9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505'9689
9830 South 51st St, Suite 8'120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
:;:;:;:;:;:;:;:;:;:::;:;:;:::::;:;:;:;:;:::;:;:;:;:;:::::;:::::::;:;:;:;:;:;:;:::;:;:;:;:;:::;:;:;:;:;:::::::;:;:::;:;:;:::;:;:;:;:;:;:::::;:;:;:;:::::;:;:;:;:;:;:;:;:;:;:;:;:::;:;:;:;:;:;:;:;:;:::::;:::::::;:;:;:;:::::;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:::::;:;:;:;:;:::::::;::;:::.:.:...:.:...;.;.................... . .................;.:.:.:.;.:.:-:-:.:.:.:.:.:.:.:.:.:.:.:.:-:0:->:':':':';';':-:':-:';':':':«':':':':';':':-:':':';':-:.;.;.:.;.:.;.;.;.;.:.: ... ........
~:~:~Columbia Analytical Client Project ID: L9904Ö70 HHHSampied:'g/2'8Χ9
I m:!6925 Canoga Avenue Received: 10/6/99 "
:::::Canoga Park, CA 91303 Sample Descript: Soil, B3@75 Extracted: 10/9/99
:¡:¡:Attention: L. Ross Fenstermaker Lab Number: IJ00503 Analyzed: 10/9/99
}; QC Batch: IJ08011 S Reported: 10/12/99
I:}:;;;:;:;;;;;;::::::::::::;:;:;::: H H .... H H H .. .., H .. .. H' H H" H H H
MTBE (EPA 8260B)
...
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether........ ................ .......... ...........
50
.....................................
1,300
I
I
I
I
I
I
I.
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 10.
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Dibromofluoromethane (80-120).....
Results pertain only to samples tesled in the laboralory. This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
92%
IJ00502.COA <3 of 13>
I
I~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A. Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 80S, San Diego, CA 92123
9830 South 51st St, Suite 6,120, Phoenix. AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
::::rCoiÙ~b¡~Ä~aiyticai ... ... ··,····;C¡¡~gtP;~J~albtL99Ô4870 . .....
I ::::: 6925 Canoga Avenue
m:; Canoga Park, CA 91303 Sample Descript: Soil, B3@80
:;;:;Attention: L. Ross Fenstermaker Lab Number: IJ00504
I ..' QC Batch: IJ10071S
.......................
......................
....................
............... .
........................;...;.;.;...;.;.;;;;;;,,',',',',',""""""":':';':';';';š'~'~p'i~~r=':'9ì2;âí99 :':':';;:';';;';;;;':':':':':':':"';':':';';';'
Received: 1 0/6/99
Extracted: 1 0/1 0/99
Analyzed: 10/10/99
Reported: 1 0/12/99
.... ... .............
........-.......... ..
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...........................
.....................................
. ..................................................................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.....................
................................;.:.:.:.:.:.:.:.:.:.:.:.:........
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether...... ....................... ................
25
.....................................
1,000
I
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 5.
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromoftuoromethane (80-120).....
101%
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00502.COA <4 of 13>
I
L' Del Mar Analytical
I~;:.."..,.................:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:':.:.:.:.:.:-:.:-:.:.:::::.:.:::::.::::::::::::::;:;:;:::::;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:::;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:;:::::;:::;:;:;:::::::;:;:::;:;:;:;:;:;:::::;:::;:::;:::::::;:::::
:jjjjColumbia Analytical Client Project ID: L9904070
I :r 6925 Canoga Avenue
:¡::¡ Cano~a Park, CA 91303 Sample Descript: Soil, B3@85
/:Attentlon: L. Ross Fenstermaker Lab Number: IJ00505
QC Batch: IJ10071S
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys. CA 92406
9484 Chesapeake Dr,. Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8'120, Phoenix. AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785-0851
I HHH'HH'H
......... .
............................:...:-:.:.:.:-:-:...:.:.:-:':':.:.:.:.:.:-:.:-:-:-:-:.:-:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:':':':':':':':':Sâ'~pl~a~:':'9ì2:âí9i~f':':':"
Received: 10/6/99
Extracted: 1 0/1 0/99
Analyzed: 10/10/99
Reported: 10/12/99
.....................
...................
...................
...................
...................
...................
....
.....................................
.....................................
.................................
............................................................................................................................
...... ....................................................................
...................................................... .
.... .............................
........................................................................................................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.................
. . . . . . . . . . . . . . . . . . . . . . . . . . .
. .......................
MTBE (EPA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether........ ...... ...............................
5.0
.....................................
170
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120).....
101%
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00502.COA <5 of 13>
I
.<
Del Mar Analytical
2852 Alton Ave.. Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8'120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370·1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
...............................................................................................
...............................................................................................
..................................................... ...............................................................................................
..................................................... ...............................................................................................
::{c6iÚii1b¡aÄiïälÿtiëäl" ........ ..... ... .......... C¡¡eiït'Þr6jedib:"L99Ó4Ö'iÖ"
I :::: 6925 Canoga Avenue
:::::Canoga Park, CA 91303 Sample Descript: Soil, B3@90
:::::Attention: L. Ross Fenstermaker Lab Number: IJ00506
QC Batch: IJ10071S
......................
.......................
......................
.......................
.....................
.....................
.....................
.....................
":':':"':"""::"":':'::"':'::':':':':':':š'~'~p1~a~:':':9/2:â/99':':"""·'·'······H
Received: 10/6/99
Extracted: 1 0/1 0/99
Analyzed: 10/10/99
Reported: 10/12/99
. ....................."
I····················································.......................................................................
.....,.................................................................................................................................................................................................................................................
................................................................ .
..............................................................
........................................................... .
............................................... .
.......................
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
1 Methyl tert-Butyl Ether........,............................. .......
5.0
.....................................
58
1
I
1
1
I
1
1
1
1
1
Analytes reported as N.D. were not present at or above the reporting limit.
1
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120).....
100%
1
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00502.COA <6 of 13>
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8'120, Phoenix, AZ 85044
(949) 261-1022 FAX (949) 261·1228
(909) 370,4667 FAX (909) 370·1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
.......... -...................................................................................
.... ...... ......... ....................................................................................................................................................................................
:::¡:C6iumb¡a'Änálÿt¡ëàl' .......... ·'··Cllenfþ·rojecfiÓ:L§§Ö4õiÖ··
II: 6925 Canoga Avenue
::::Canoga Park, CA 91303
'(Attention: L. Ross Fenstermaker
Sample Descript: Soil, B4@75
Lab Number: IJ00507
QC Batch: IJ11051S
.. .,..'............................................,.,...,""'.".""'.""""""""""""""""""'"S'~'~pI~'d'~""9n~'8ì99";::""""
Received: 10/6/99
Extracted: 10/11/99
Analyzed: 10/11/99
Reported: 1 0/12/99
........................................... .................................................
......... ........ .................................................
................. .
..................
. . . . . - . . . . . . . . . . . .
. . ............
I......'..
...
......
..........................................................:.:.....:...:.....:.:.:.:.:.:.:.:.:.:.:...:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:........
.. ..... . ..... .........................................................................
... .......... ..........................
MTBE (EPA 8260B)
1 Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.............................................
50
.....................................
1,200
1
1
I
1
1
1
1
1
1
1
1
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 10.
1
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
1
Dibromofluoromethane (80-120).....
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
105%
IJ00502.COA <7 of 13>
I
I~d
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E, Cooley Dr., Suite A, Colton. CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego. CA 92123
9830 South 51st St., Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
... .................
. . .............
.. ',' ...,..................................................,.,...,.,.,.,.,.""'."""""""""""""'S'~'~'p '~'d'~'""èì2'âìég' """,:,:,:,:,:,,::,:,:,:,:,:::,:,:,:,:,:,::.:.
Received: 1 0/6/99
Extracted: 1 0/11/99
Analyzed: 10/11/99
Reported: 1 0/12/99
...
¡:¡rcô¡û~biâÂ~:âìytiêâf·· ·················cÚenfÞrojedìÓ:I9§Ò4ôiÓ········
I :m: 6925 Canoga Avenue
¡¡¡¡Canoga Park, CA 91303 Sample Descript: Soil, B4@80
:}Attention: L. Ross Fenstermaker Lab Number: IJ00508
I ::::: ..........:...............:.,..,.,.,.:.,..,.,.,:::............... QC Batch: IJ11051S
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether....... ............. .........................
50
.....................................
3,200
1
I
I
I
I
I
I
I
I
I
'I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 10.
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120).....
106%
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in lull, without written permission lrom Del Mar Analytical.
IJ00502.COA <8 of 13>
I
t:,
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr., Suite A. Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys. CA 92406
9484 Chesapeake Dr" Suite 805. San Diego, CA 92123
9830 South 51st St., Suite 6·120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261·1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505·9689
(480) 785,0043 FAX (480) 785,0851
:.:.:.;.;.:.:.:.:.:.:.:.:.:.:-:.:.:.:::::;:::::::::::::::;:::::;:::::::::::::::::::::::::.;.;........
............................................................
.. ..... ..............................................
................................
.... .....................
....................... .
....................... .
........................ .
· . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
· . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
............................
· . . . . . . . . . . . . . . . . . . . . . . . . .
........................................................................ ........................................... ............................................
......................
......................
. ..·..··..···....·Sampied:···gï2·šï99··· .. .................
Received: 10/6/99
Extracted: 10/11/99
Analyzed: 10/11/99
Reported: 10/12/99
. ............ . ............
::::¡Columbia Analytical Client Project ID: L9904070
It' 6925 Canoga Avenue
:::::Cano~a Park, CA 91303 Sample Descript: Soil, B4@85
:::::Attentlon: L. Ross Fenstermaker Lab Number: IJ00509
I"' QC Batch: ~~~:5(1:PA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether...... ......................... ,...... .......
5.0
.....................................
160
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120).....
109%
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in lull, without written permission lrom Del Mar Analytical.
IJ00502.COA <9 of 13>
I
.<
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C·11, Van Nuys, CA 92406
9484 Chesapeake Dr.. Suite 805. San Die90, CA 92123
9830 South 51st St., Suite 8'120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779·1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
..... :.:.:.:.:.:.:.:.;.:.:.:.:-:.:.:.:.:.:.:.;.;.;.:.:.;.;.:.;.:.:.:.:.:.:.:.:.;.:-:-:.:.:.:.:.;.:.:.:.:-:-:.:.;.:.;.;.;.;.;.;.:.;.:.:-:.:.:.:-:.:-:.;.:-:-:-:.:.:.:-:.:.:.;.;.;.;.;.:.:.:.:.;.:-:.;.>:-:
:::(CoiiJrnhfå'ÂnaìyÚcaf ···dien(ProjedTÓ:·L99Ò4ÒiÔ··'····
I :r 6925 Canoga Avenue
:::::Canoga Park, CA 91303
/Attention: L. Ross Fenstermaker
..........................
. . . . . . . . . . . . . . . . . . . . . . . . .
..........................
.......................
""""""""""""""""""",.,,',',',',',',"""""""""""""""""'s'~'~8i'~'d:""'9ì2'å!'99"""""·'·'··..····
Received: 1 0/6/99
Extracted: 10/11/99
Analyzed: 10/11/99
Reported: 1 0/12/99
I;·;·;·;·;·;·;';·;·;·;·;·;.;·;·;.;·;··....·······
Sample Descript: Soil, B4@90
Lab Number: IJ00510
QC Batch: IJ11051S
. ..........................................................:.:.:.:.:.:-:-:.:.;.;.;.:.;.:.:.:.:.:.:.:.:.:.:-:-:.:-:.:.;.:.;.;.;.:.:.:-:.;.>:-:.:-:.;.;.;.;.;.:.:.:.:.:.:-:.:.:.:........
.....................................................
................................... .
....... ............
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.............................................
25
.....................................
460
I
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 5.
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Dibromof1uoromethane (80-120).....
113%
Results pertain oniy to samples tested in the laboratory, This report shall not be
reproduced. except in full. without written permission from Del Mar Analytical.
IJ00502.COA <10 of 13>
I
.<
Del Mar Analytical
2852 Alton Ave.. Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Collon, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego. CA 92123
9830 South 51st St, Suite 8'120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785-0043 FAX (480) 785,0851
I
Columbia Analytical
6925 Canoga Avenue
Canoga Park, CA 91303
Attention: L. Ross Fenstermaker
.:.:.:.:.:.:.:.;.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.;.:.:.;.;.;.:.;.;.;.;.:.;.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:
:·::·····[··Mäthða'Bìäfi~:
.....................
...... ...........
........ ..............
.........................
.........................
.........................
.........................
.........................
.........................
......................
....
......
......
Extracted: 1 0/8/99
Analyzed: 10/8/99
Reported: 10/12/99
.. ...................
.............................. .
...........................
I
. . .. . . . . . . . . . . . . . . . . .. .. . . . . . . . . . . . . . . . . . . . . .
.............................. ............................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .. ..,..........................................
.............................. ............................................
.............................. .............................................
~~~~~~~~~~~~~~j~j:~:)~~~:~~~~~~¡~~~¡~~~¡~~~~~~~~~~~~~~~~~:~:::~:~:~:~:~:~:~:~:~:~:~:~:~:::~:~:~::::::::::::;::::::::::::::::::::::::::::::::::::::
··ciC···'t~atch·:········· .. .. ········..,J08·0·1···1""8·· ......
................. ..
· . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...............................
· . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...............................
· . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.............................................................
...........................................................
................................................
MTBE (EPA 8260B)
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I
I
I.
Methyl tert-Butyl Ether.... .................................... .....
5.0
.....................................
N.D.
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
DibromoRuoromethane (80·120)..... 92%
I
Results pertain oniy to samples tested in the laboratory. This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
IJ00502.COA <11 of 13>
I
.<
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'll, Van Nuys, CA 92406
9484 Chesapeake Dr" Suite 80S, San Diego. CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505·9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
I
Columbia Analytical
6925 Canoga Avenue
Canoga Park, CA 91303
Attention: L. Ross Fenstermaker
Extracted: 10/10/99
Analyzed: 10/10/99
Reported: 10/12/99
I
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether......... ........ ...... ......................
5.0
.....................................
N.D.
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
purrogate Standard Recovery (Accept. Limits):
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
Dibromoftuoromethane (80-120).....
106%
IJ00502,COA <12 of 13>
:<
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'II, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St.. Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
Columbia Analytical
I 6925 Canoga Avenue
Canoga Park, CA 91303
Attention: L. Ross Fenstermaker
........................
.........................
........................
.........................
........................
.........................
........................
.........................
........................
.........................
........................
.........................
........................
........................
...............................................
.............................................. .
..............................................
............................................
...........
Extracted: 10/11/99
Analyzed: 10/11/99
Reported: 10/12/99
......................
.........................
. . . . . . . . . . . . . . . . . . . . . . . .
.........................
. . . . . . . . . . . . . . . . . . . . . . . .
.........................
........................
........................
......................
....................
.................
. . . . . . . . ...............................
.............................................. .
::líèfhod]3J'ankr:
................
....
I
........................
.........................
"dC'Batch: ························iJf1ó"S"1S···
....... ......................
..................................
.................................
..................................
.................................
..................................
.................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...............................
.............................
......................... .
. ....................
...................... .......... ...
.............................................. .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...............................................
...............................................
:.:.:.:.:.:::::::::::.:::::::::::::::::::;:::::::::::::::::::::::::::::::.:-:..........
MTBE (EPA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.............................................
5.0
.....................................
N.D.
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
Dibromofluoromethane (80-120).....
104%
IJ00502.COA <13 of 13>
I
.<
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E. Cooley Dr.. Suite A. Colton, CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suile 805, San Die90, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St, Suite 6,120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed: 10/8/99
Sample: IJ00488
Batch: IJ08011 S
Analyte R1 Sp MS
ppb ppb ppb
Vinyl Chloride
1,1-Dichloroethene
MTBE*
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
Tetrachloroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
Matrix: Soil
MSD PR1
PR2
MEAN
RPD PR
Acceptance
Limits
ppb
%
%
MPR
RPD
%
%
0 25 27 27 108% 108% 0.0% 108% 30 30-160
0 25 23 24 92% 96% 4.3% 94% 40 45-165
53.7 25 62 86 33% 129% 32% 81% 40 55-155
0 25 24 25 96% 100% 4.1% 98% 20 55-150
0 25 24 24 96% 96% 0.0% 96% 20 65-140
0.1 25 22 23 88% 92% 4.4% 90% 30 55-145
0 25 24 24 96% 96% 0.0% 96% 25 60-140
0 25 25 25 100% 100% 0.0% 100% 30 60-145
0.8 25 25 25 97% 97% 0.0% 97% 20 65-140
0 25 25 25 100% 100% 0.0% 100% 50 10-200
0 25 24 24 96% 96% 0.0% 96% 20 70-135
0.1 25 25 25 100% 100% 0.0% 100% 20 70-140
0.3 50 53 53 105% 105% 0.0% 105% 20 40-160
0.1 25 26 26 104% 104% 0.0% 104% 20 65-150
. Due to high levels of analyte in the sample, the MS/MSD calculation does not provide useful spike
recovery information. See LCS for batch validation.
R1. . . . . . . . . . . . . . . . .. Result of Sample Analysis
Sp. . . . . . . . . . . . . . . . .. Spike Concentration Added to Sample
MS. . . . . .. . . . . . . . . . . . Matrix Spike Result
MSD. . . . . . . . . . . . . . .. Matrix Spike Duplicate Result
PR1................. Percent Recovery of MS; ((MS-R1) 1 SP) X 100
PR2................. Percent Recovery of MSD; ((MSD-R1) 1 SP) X 100
RPD. . . . . . . . . . . . . . . . . Relative Percent Difference; ((MS-MSD)/(MS+MSD)/2) X 100
Acceptance Limits. . .. Statistically determined on an annual basis.
DEL MAR ANALYTICAL
j(
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave" Irvine, CA 92606 (949) 261-1022 FAX (949) 261,1228
1014 E. Cooley Dr., Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370'1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044 (480) 785·0043 FAX (480) 785,0851
Date
Analyzed:
10/8/99
Batch:
IJ08011S
Analyte
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
T etrach loroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
St
Acceptance
PR Limits
R1
ppb
ppb
%
%
25 26 104% 40-145
25 24 96% 55-145
25 23 92% 60-140
25 24 96% 60-140
25 24 96% 65-135
25 23 92% 55-135
25 24 96% 65-130
25 24 96% 70-130
25 24 96% 70-125
25 24 96% 65-130
25 24 96% 75-125
25 24 96% 70-125
50 51 102% 70-130
25 25 100% 70-135
St. . . . . . . .. ......... Concentration of standard added to blank.
R1 . . . . . . .. ......... Standard Result
PR . . . . . . .. ......... Percent Recovery of R1; (R1 I St) X 100
DEL MAR ANALYTICAL
I
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave.. Irvine, CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E. Cooley Dr., Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C'II, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505·9689
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed: 10/10/99
Sample: IJ00643
Batch: IJ10071S
Analyte R1 Sp MS
ppb ppb ppb
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
T etrach loroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
Matrix: Soil
MSD
PR1
MEAN
RPD PR
Acceptance
Limits
PR2
ppb
%
%
MPR
RPD
%
%
0 25 24 21 96% 84% 13% 90% 30 30-160
0 25 25 25 100% 100% 0.0% 100% 40 45-165
1.7 25 28 30 105% 113% 6.9% 109% 40 55-155
0 25 28 27 112% 108% 3.6% 110% 20 55-150
0 25 26 26 104% 104% 0.0% 104% 20 65-140
0.2 25 27 28 107% 111% 3.6% 109% 30 55-145
0 25 25 25 100% 100% 0.0% 100% 25 60-140
0 25 23 23 92% 92% 0.0% 92% 30 60-145
0 25 24 24 96% 96% 0.0% 96% 20 65-140
0 25 23 22 92% 88% 4.4% 90% 50 10-200
0 25 25 24 100% 96% 4.1% 98% 20 70-135
0 25 25 24 100% 96% 4.1% 98% 20 70-140
0 50 50 48 100% 96% 4.1% 98% 20 40-160
0 25 25 24 100% 96% 4.1% 98% 20 65-150
R1. . . . . . . . . . . . . . . . .. Result of Sample Analysis
Sp. . . . . . . . . . . . . . . . .. Spike Concentration Added to Sample
MS. . . . . .'. . . . . . . . . . . . Matrix Spike Result
MSD. . . . . . . . . . . . . . .. Matrix Spike Duplicate Result
PR1................. Percent Recovery of MS; «MS-R1) 1 SP) X 100
PR2. . . . . . . . . . . . . . . .. Percent Recovery of MSD; (MSD-R1) 1 SP) X 100
RPD. . . . . . . . . . . . . . . . . Relative Percent Difference; «MS-MSD)/(MS+MSD)/2) X 100
Acceptance Limits. . .. Statistically determined on an annual basis.
DEL MAR ANALYTICAL
:<
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 6,120, Phoenix, AZ 85044
Date
Analyzed:
10/10/99
Batch:
IJ10071S
Analyte
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
Tetrachloroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
St
R1
Acceptance
PR Limits
ppb
ppb
%
%
25 25 100% 40-145
25 24 96% 55-145
25 25 100% 60-140
25 27 108% 60-140
25 26 104% 65-135
25 25 100% 55-135
25 25 100% 65-130
25 23 92% 70-130
25 24 96% 70-125
25 22 88% 65-130
25 24 96% 75-125
25 25 100% 70-125
50 49 98% 70-130
25 24 96% 70-135
51. . . . . . . .. ......... Concentration of standard added to blank.
R1 . . . . . . .. ......... Standard Result
PR . . . . . . .. ......... Percent Recovery of R1; (R1 / St) X 100
DEL MAR ANALYTICAL
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
:<
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261-1228
1014 E. Cooley Dr., Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370·1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St, Suite B,120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed: 10/11/99
Sample: IJ00679
Batch: IJ11051S
Analyte R1 Sp MS
ppb ppb ppb
Vinyl Chloride
1,1-Dichloroethene
MTBE*
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
Tetrachloroethene
Ch lorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
Matrix: Soil
MSD PR1
MEAN
RPD PR
Acceptance
Limits
PR2
ppb
%
MPR
%
%
%
RPD
0 25 23 23 92% 92% 0.0% 92% 30 30-160
0 25 26 26 104% 104% 0.0% 104% 40 45-165
383 25 324 237 NC NC 31% NC 40 55-155
0 25 26 25 104% 100% 3.9% 102% 20 55-1 50
0 25 27 26 108% 104% 3.8% 106% 20 65-140
0.1 25 26 26 104% 104% 0.0% 104% 30 55-145
0 25 25 25 100% 100% 0.0% 100% 25 60-140
0 25 29 31 116% 124% 6.7% 120%' 30 60-145
0.1 25 24 25 96% 100% 4.1% 98% 20 65-140
0 25 25 26 100% 104% 3.9% 102% 50 10-200
0 25 25 26 100% 104% 3.9% 102% 20 70-135
0.1 25 25 26 100% 104% 3.9% 102% 20 70-140
0 50 48 50 96% 100% 4.1% 98% 20 40-160
0 25 25 26 100% 104% 3.9% 102% 20 65-150
* Due to high levels of analyte in the sample, the MS/MSD calculation does not provide useful spike
recovery information. See LCS for batch validation.
R1. . . . . . . . . . . . . . . . .. Result of Sample Analysis
Sp.. . . . . . . . . . . . . . . .. Spike Concentration Added to Sample
MS. . . . . .. . . . . . . . . . . . Matrix Spike Result
MSD. . . . . . . . . . . . . . .. Matrix Spike Duplicate Result
PR1. . . . . . . . . . . . . . . " Percent Recovery of MS; ((MS-R1) 1 SP) X 100
PR2. . . . . . . . . . . . . . . .. Percent Recovery of MSD; ((MSD-R1) 1 SP) X 100
RPD. . . . . . . . . . . . . . . . . Relative Percent Difference; ((MS-MSD)/(MS+MSD)/2) X 100
Acceptance Limits. . .. Statistically determined on an annual basis.
DEL MAR ANALYTICAL
k
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave" Irvine, CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E Cooley Dr" Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C'11, Van Nuys. CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr" Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St., Suite 8'120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785·0851
Date
Analyzed:
10/11/99
Batch:
IJ11051S
Analyte
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
T etrach loroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
St
Acceptance
PR Limits
R1
ppb
ppb
%
%
25 23 92% 40-145
25 25 100% 55-145
25 23 92% 60-140
25 24 96% 60-140
25 26 104% 65-135
25 24 96% 55-135
25 24 96% 65-130
25 25 100% 70-130
25 24 96% 70-125
25 25 100% 65-130
25 25 100% 75-125
25 25 100% 70-125
50 48 96% 70-130
25 25 100% 70-135
St. . . . . . . .. ......... Concentration of standard added to blank.
R1 . . . . . . .. ......... Standard Result
PR . . . . . . .. ......... Percent Recovery of R1; (R1 I St) X 100
DEL MAR ANALYTICAL
-~kØIIIIQ - - - -
~ Analytical
Services'n< 6925 Canoga Avenue· Canoga Park, CA 91303· (818) 587-5550· Fax (818) 587-5555
-CH. Of!leUslmDvnB~T~ AmV~Ee!7ES"'OR1r
DATE rD -.Ç -7; PAGE~OF /
PROJECT NAME L- ~Î ö 'i 0] 0 #'
PROJECT MANAGER L, ~c S) ~N ~ ft;.Jt t1 A ~d:: en
COMPANY/ADDRESS Co LV '1 a 1 ~ ArJlT\,'(1)Lf¡L- h'€)t\.I)t€S ~
:;¡:
t-
Z
o
ü
u.
o
a:
w
( )
::E
::>
z
SAMPLERS SIGNATURE
SAMPLE
I.D.
ß3 @ 70
&"1 e 7-S"'
ß3 (? ~O
.ß3 ~ ~r-
£3 (,J "D
ß ~ ~ --:¡.ç
.ß\ e g-a
ß' fJ ~S-
ßl ~ ~ D
t ~ELlNQ SHED BY:
þ( f/Y) W
Srg?ri~ r../-
Printed ~5
Fir{O/~/1~ to}':)
Dateffime
RELINQUISHED BY:
Signature
Printed Name
Firm
Dateffime
PHONE
ANALYSIS REQUESTED
-
'" ~ ~~ ,
g ¡.:.~'
o f? ~ ,52
CZJ fJ 13§
.f; 0 ø, 0
õ {j!J (£j 0.;: [5
b(3 ;¡;,,:¡j§ NO !'.
~c:J .:t- -!!' '" ð'o è:i
(J0.J '&0 § ~ #rt"'f:[:j &
15& ~() ~ b ~~ ìi7~ '"
'0cr ",Ii. g......Sf ð?t §KJ s
<b'0.J .....0 0 CZJco' ¡Yo (¡j CZJ(¡j CZJ
ø$] ~... f!j Q...... CZJõ ,~0 ¿0 :!
;z:t'ð ~ CZJ (JP:J ìi7 "1- 8'P::¡ ~~ CZJ~ ~
')(
K
X
X
IX
~
~
)<
)<
LAB SAMPLE
DATE TIME I.D. MATRIX
~hKhQ Sf>\L...
,
.
,II
,l/
---
A ,~I~Il1Y: TURNAROUND REQUIREMENTS
(( ,/ill) _ 24hr _48hr. _5day
Sign ~ \. rJa. \!)S et.D - Standard ,
Print~arn.e A A r - Other (Specify)
~ IVL t.l Provide Verbal
Firm lD I (p { 0 ::3 0 - Preliminary Results ,
Dateffime Requested Report Date ~
INVOICE INFORMATION:
SAMPLE RECEIPT:
REPORT REQUIREMENTS
_ I. Routine Report
.JS.. II. Report (includes DUP,MS.
MSD, as required, may be
charged as samples)
_ III. Data Validation Report
(includes All Raw Data)
AWaCB
P.O,# ~ ~ b ~ D fO
Shipping VIA:
Shipping #:
Condition:
Bill To
-
Lab No:
RECEIVED BY:
SPECIAL INSTRUCTIONS/COMMENTS: Tò ~t'"L M.I\~ - '1l..J I ~ t
Signature
Printed Name
~ HtLD lìMC
,
Firm
DatefTime
.....''''............"-,, ,-r,......., "" 'IT.... _~..... .,,.. ,: .:,_ _.~_. \/1"'"' I """'AI I,,'.
.. I "
I
I
:1
! I
I
I
I
I
I
'I
I
'I
,I
I
I
il
I
I
II
I
October 21, 1999
êt~o'umbia
~ Ana!ytical
SerVices INC.
An Employee-Owned Company
Mike Tiffany
California Environmental
31320 Via Colinas
Suite 104
Westlake Village, CA 91362
Re: Car Wash of AmericalProject #EV298-1610
Dear Mike:
Enclosed are the results of the samples submitted to our mobile laboratory on September 27,
1999. The samples were sent to Del Mar Analytical for EP A Method 8260B. Please find their
report (#IJ00487) attached. For your reference, these analyses have been assigned our service
request number L9904049.
All analyses were performed in accordance with our laboratory's quality assurance program.
Results are intended to be considered in their entirety and apply only to the samples analyzed.
Columbia Analytical Services is not responsible for use of less than the complete report.
Columbia Analytical Services - Mobile Laboratory - is certified for environmental analyses by the
California Deparment of Health Services (certificate number: I2351, expiration: February 29,
2000).
If you have any questions, please call me at (818) 587-5550, extension 310.
Respectfully submitted,
Columbia Analytical Services, Inc.
7L 1:AL
L. Ross Fenstermaker
Project Chemist
LRF /kh
6925 Canoga Avenue . Canoga Porl"í, CA 91303 . (818) 587-5550 . Fox (818) 587-5555
I
I 8015M
A2LA
ASTM
BOD
I BTEX
CAM
CARD
CAS Nwnber
I CFC
CFU
COD
CRDL
I DEC
DEQ
DLCS
I DMS
DOE
DOH or DHS
ELAP
I EPA
EQL
GC
GCIMS
I IC
ICB
ICP
ICY
I J
LCS
LUFT
I M
MBAS
MCL
I MDL
MPN
MRL
I MS
MTBE
NA
NAN
I NC
NCASI
ND
NIOSH
I NTU
ppb
ppm
PQL
I QAlQC
RCRA
RPD
SIM
I SM
STLC
SW
I TCLP
TDS
TPH
I tr
TRPH
TSS
I TTLC
VOA
Columbia Analytical Services, Inc.
Acronyms
California DHS LUFf Method
American Association for Laboratory Accredi1ation
, American Society for Testing and Materials
Biochemical Oxygen Demand
Benzeneffoluene/EthylbenzenelXylenes
California Assessment Metals
California Air Resources Board
Chemical Abstract Service Regis1ry Number
Chlorofluorocarbon
Colony-Forming Unit
Chemical Oxygen Demand
Con1ract Required Detection Limit
Depar1ment of Environmental Conservation
Depar1ment of Environmen1a1 Quality
Duplicate Laboratory Con1rol Sample
Duplicate Ma1rix Spike
Depar1ment of Ecology
Depar1ment of Health Services
Environmental Laboratory Accredi1ation Program
U.S. Environmen1a1 Protection Agency
Estimated Qaunti1ation Limit
Gas Chromatography
Gas ChromatographylMass Spec1rome1ry
Ion Chromatography
Initial Calibration Blank sample
Inductively Coupled Plasma atomic emission spec1rome1ry
Initial Calibration Verification sample
Estimated concen1ration. The value is less than the MRL, but greater than or equal to the MDL.
If the value is equal to the MRL, the result is actually <MRL before rounding.
Laboratory Con1rol Sample
Leaking Underground Fuel Tank
Modified
Methylene Blue Active Substances
Maximum Con1aminant Level. The highest permissible concen1ration of a substance
allowed in drinking water as eS1ablished by the U.S. EP A.
Method Detection Limit
Most Probable Number
Method Reporting Limit
Ma1rix Spike
Methyl-tert -Butyl Ellter
Not Applicable
Not Analyzed
Not Calculated
National Council of the paper indus1ry for Air and S1rearn Improvement
None Detected at or above the Melltod Reporting/Detection Limit (MRUMDL)
National Institute for Occupational Safety and Health
Nephelome1ric Turbidity Units
Parts Per Billion
Parts Per Million
Practical Quanti1ation Limit
Quality Assurance/Quality Con1rol
Resource Conservation and Recovery Act
Relative Percent Difference
Selected Ion Monitoring
Standard Methods for the Examination of Water and Wastewater, 18th Ed" 1992.
Solubility Threshold Limit Concen1ration
Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, SW-846,
Third Edition, 1986 and as amended by Updates I, II, IIA, and lIB,
Toxicity Characteristics Leaching Procedure
To1a1 Dissolved Solids
To1a1 Pe1roleum Hydrocarbons
Trace level is the concen1ration of an analyte that is less than the PQL but greater than or equal to
the MDL. If the value is equal to the PQL, the result is actually <PQL before rounding.
To1a1 Recoverable Pe1roleum Hydrocarbons
To1a1 Suspended Solids
To1a1 Threshold Limit Concen1ration
Volatile Organic Analyte(s)
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I
I
I I
I
I
I
I
I
I
I
I
I
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl ter! -Butyl Ether
t
Approved By:
I S22/020597p
04049VOH.ITl ' Sample 10/21/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
Bl @ 10
L9904049-001
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EP A 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
TPH as Gasoline does not include MmE.
7if
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
I NA 9/27/99 ND
I NA 9/27/99 ND
1 NA 9/27/99 ND
I NA 9/27/99 ND
I NA 9/27/99 ND
1 NA 9/27/99 ND
Date:
/6-21,11
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
B I @ 20
L9904049-002
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EP A 5030 8021B 0.005
EP A 5030 8015M 0.1
EPA 5030 8021B 0.010
TPH as Gasoline does not include MTBE.
ìif
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 0.1
1 NA 9/27/99 ND
1 S221020S97p
Date:
'I} -l/-97
04049VOH.JTl ,Sample (2) 10/21/99
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ter! -Butyl Ether
I
I
I
I
I
t
I
I
I
I
Approved By:
I S221020597p
04049VOHJTI ,Sample (3) 10/21199
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Enviromnental
Car Wash of AmericalEV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
BI @60
L9904049-006
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 802lE 0.005
EP A 5030 802lE 0.005
EPA 5030 8015M 0.1
EPA 5030 802lE 0.010
TPH as Gasoline does not include MlBE,
7ff
Units: rngIKg (pprn)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
I NA 9/27/99 0.44
100 NA 9/27/99 8.0
I NA 9/27/99 0.62
100 NA 9/27/99 4.8
100 NA 9/27/99 41
I NA 9/27/99 0.50
Date:
/b-L'-~1
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert-Butyl Ether
I
I
I
I
I
t
I C2A
I
I Approved By:
I S2V020597p
I 04049VOH.ITI ,Sample (16) 10121/99
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
B1 @ 70
L9904049-007
t / C2A
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 8015M 0.1
EPA 5030 802lE 0.010
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
100 NA 9/28/99 <0.5
100 NA 9/28/99 4.2
100 NA 9/28/99 0.93
100 NA 9/28/99 7.2
100 NA 9/28/99 60
100 NA 9/28/99 8.3
TPH as Gasoline does not include MmE.
MRL is elevated because of matrix interferences and because the sample required diluting.
7tf
Date:
1 ö ~ ll-17
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Environmental Service Request: L9904049
Project: Car Wash of America/EV298-161O Date Collected: 9/27/99
Sample Matrix: Soil Date Received: 9/27/99
I
MmE, BTEX and TPH as Gasoline
I
Sample Name: B I @ 80 Units: mgIKg (ppm)
I Lab Code: L9904049-008 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 I NA 9/29/99 0.13
Toluene EPA 5030 802lE 0,005 I NA 9/29/99 0.83
I Ethylbenzene EPA 5030 802lE 0.005 I NA 9/29/99 0.092
Xylenes, Total EPA 5030 802lE 0.005 I NA 9/29/99 0.76
TPH as Gasoline EPA 5030 8015M 0.1 I NA 9/29/99 7.0
, Methyl tert -Butyl Ether EP A 5030 802lE 0.010 I NA 9/29/99 2.8
I I
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 7tf Date: fb-II-;1
I S22/020597p
I 04049YOH.JTI . Sample (4) 10121/99 Page No.:
I
I
Client:
I Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ter! -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I S22/020597p
I
04049VOH.JTI ,Sample (5) 10121/99
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
BI @ 85
L9904049-009
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 8015M 0.1
EPA 5030 802lE 0.010
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/27/99 ND
NA 9/27/99 0.005
NA 9/27/99 ND
NA 9/27/99 0.006
NA 9/27/99 0.2
NA 9/27/99 1.4
TPH as Gasoline does not include MmE.
711
Date:
If> -llo ~1
Page No.:
I
I
Client:
I Project:
Sample Matrix:
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
I
MTBE, BTEX and TPH as Gasoline
I
I Sample Name: Bl @ 90 Units: mg/Kg (ppm)
I Lab Code: L9904049-0 1 0 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 80218 0.005 1 NA 9/29/99 0.014
Toluene EP A 5030 80218 0.005 1 NA 9/29/99 0.017
I Ethylbenzene EPA 5030 80218 0.005 I NA 9/29/99 ND
Xylenes, Total EPA 5030 80218 0.005 1 NA 9/29/99 0.026
TPH as Gasoline EPA 5030 8015M 0.1 1 NA 9/29/99 0.3
I Methyl tert -Butyl Ether EPA 5030 80218 0.010 1 NA 9/29/99 1.9
I
I
I
I
I
t TPH as Gasoline does not include MTBE.
I
I
I Approved By: 71f Date: 1 b - ¿I- '11
1 S221020597p
I 04049VOHJTI ' Sample (6) 10121/99 Page No.:
I
¡. COLUMBIA ANALYTICAL SERVICES, INC.
I
Analytical Report
I Client: California Enviromnental Service Request: L9904049
Project: Car Wash of AmericalEV298-1610 Date Collected: 9/27/99
Sample Matrix: Soil Date Received: 9/27/99
I
I MTBE, BTEX and TPH as Gasoline
Sample Name: BI @ 95 Units: mg/Kg (ppm)
I Lab Code: L9904049-OIl Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802 IE 0.005 I NA 9/27/99 ND
Toluene EPA 5030 802 IE 0.005 1 NA 9/27/99 0.005
I Ethylbenzene EPA 5030 802 IE 0.005 1 NA 9/27/99 ND
Xylenes, Total EPA 5030 802 IE 0.005 1 NA 9/27/99 0.005
TPH as Gasoline EPA 5030 8015M 0.1 I NA 9/27/99 0.1
I Methyl tert-Butyl Ether EPA 5030 802 IE 0.010 I NA 9/27/99 0.16
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 7tf Date: 'b-lf-l~
1 S2V020597p
I 04049VOH.ITl ,Sample (7) 10/21/99 Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I S22i020S97p
I 04049VOH.JTI ,Sample (8) 10/21/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Enviromnental
Car Wash of America/EV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
Bl @ 100
L9904049-012
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802IB 0.005
EP A 5030 8015M 0.1
EPA 5030 802lE 0.010
TPH as Gasoline does not include M1BE,
7Lf
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/27/99 ND
I NA 9/27/99 0.006
1 NA 9/27/99 ND
1 NA 9/27/99 0.008
1 NA 9/27/99 0.1
1 NA 9/27/99 0.24
Date:
II) - 2.1 ~ '1 i
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I
I S221020597p
04049YOH.JTl ' Sample (9) 10/21/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Enviromnental
Car Wash of America/EV298-l61O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
Bl @ 105
L9904049-0l3
t
Prep Analysis
Method Method MRL
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80l5M 0.1
EPA 5030 80218 0.010
TPH as Gasoline does not include MTBE,
7U
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/27/99 ND
1 NA 9/27/99 0.031
1 NA 9/27/99 ND
1 NA 9/27/99 0.024
1 NA 9/27/99 0.3
1 NA 9/27/99 0.079
Date:
fðrllrr'
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Environmental Service Request: L9904049
Project: Car Wash of America/EV298-161O Date Collected: 9/27/99
Sample Matrix: Soil Date Received: 9/27/99
I
I MTBE, BTEX and TPH as Gasoline
I Sample Name: Bl @ 110 Units: mgIKg (ppm)
Lab Code: L9904049-014 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
Toluene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
I Ethylbenzene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
Xylenes, Total EPA 5030 802lE 0.005 1 NA 9/27/99 ND
TPH as Gasoline EPA 5030 8015M 0.1 1 NA 9/27/99 ND
I Methyl tert-Butyl Ether EPA 5030 802lE 0.010 1 NA 9/27/99 0.10
I
I
I I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 711 Date: 10'ZI-;1
1 S22/020597p
I 04049VOH.rn ,Sample (10) 10/21/99 Page No.:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Client:
Project:
Sample Matrix:
Sample Name:
Lab Code:
Test Notes:
Analyte
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl tert-Butyl Ether
t
Approved By:
I S22/020597p
04049YOH.JTl ,Sample (II) 10/21/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
B1 @ 120
L9904049-016
t
Prep Analysis
Method Method MRL
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EP A 5030 80218 0.005
EPA 5030 8015M 0.1
EPA 5030 80218 0,010
TPH as Gasoline does not include MfBE.
7LI
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
Date:
Ib'll-1i
Page No.:
I
I
I
I
I
II
I
Client:
Project:
Sample Matrix:
Sample Name:
Lab Code:
Test Notes:
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl fert -Butyl Ether
I
I
I
I
I
I
I
I
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MillE, BTEX and TPH as Gasoline
B1 @ 125
L9904049-017
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EP A 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 802lE 0.005
EPA 5030 80l5M 0.1
EPA 5030 802lE 0.010
t TPH as Gasoline does not include MmE.
Approved By:
1 S221020597p
04049VOH.rn ,Sample (12) 10/21/99
7ff
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
Date:
1b-ll-it
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I
Analytical Report
I Client:
Project:
Sample Matrix:
California Environmental
Car Wash of AmerÍcalEV298-l61O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
I
I
MTBE, BTEX and TPH as Gasoline
Sample Name: B 1 @ 130 Units: mg/Kg (ppm)
I Lab Code: L9904049-0l8 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
Toluene EP A 5030 802lE 0.005 1 NA 9/27/99 ND
I Ethylbenzene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
Xylenes, Total EP A 5030 802lE 0.005 I NA 9/27/99 ND
TPH as Gasoline EPA 5030 80l5M 0.1 1 NA 9/27/99 ND
I Methyl ten -Butyl Ether EPA 5030 802lE 0.010 1 NA 9/27/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MfBE.
I
I
I Approved By: 7U Date: lo-11--Î1
1 S22/020597p
I 04049VOH.ITl ,Sample (13) 10121/99 Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INe.
I Analytical Report
I Client: California Envirorunental Service Request: L9904049
Project: Car Wash of America/EV298-l61O Date Collected: 9/27/99
Sample Matrix: Soil Date Received: 9/27/99
I
I MTBE, BTEX and TPH as Gasoline
I Sample Name: Bl @ 135 Units: mg/Kg (pprn)
Lab Code: L9904049-0 19 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 8021B 0.005 NA 9/27/99 ND
Toluene EPA 5030 8021B 0.005 NA 9/27/99 ND
I Ethylbenzene EPA 5030 8021B 0.005 NA 9/27/99 ND
Xylenes, Total EPA 5030 8021B 0.005 NA 9/27/99 ND
TPH as Gasoline EPA 5030 80l5M 0.1 NA 9/27/99 ND
I Methyl fert -Butyl Ether EPA 5030 8021B 0.010 NA 9/27/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MTBE.
I
I
I Approved By: 7U Date: Ib'Llr"
I S221020597p
I 04049VOH.fn ' Sample (14) IOnI/99 Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I
I S221020597p
04049VOHJTl ' Sample (15) 10121/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-1610
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
Bl @ 140
L9904049-020
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 8015M 0.1
EP A 5030 802lE 0.010
TPH as Gasoline does not include MmE.
7tf
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
Date:
fO'L'~~1_
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ter! -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I S221020597p
I 04049VOH.m, Sample 10/21/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
B2 @ 40
L9904049-022
t
Prep Analysis
Method Method MRL
EP A 5030 802lE 0.005
EP A 5030 802lE 0.005
EP A 5030 802lE 0.005
EP A 5030 802lE 0.005
EP A 5030 8015M 0.1
EPA 5030 802lE 0.010
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/27/99 ND
NA 9/27/99 ND
NA 9/27/99 ND
NA 9/27/99 ND
NA 9/27/99 ND
NA 9/27/99 ND
TPH as Gasoline does not include MTBE.
71i
Date:
/D-Ll-i1
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ter! -Butyl Ether
I
I
I
I
I
I
t
I
I Approved By:
I
I S221020597p
04049YOH.m, Sample (2) 10121199
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericalEV298-l61O
Soil
MTBE, BTEX and TPH as Gasoline
B2 @ 60
L9904049-023
t
'Prep Analysis
Method Method MRL
EP A 5030 80218 0.005
EP A 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80l5M 0.1
EPA 5030 80218 0.010
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/27/99 0.057
NA 9/27/99 0.008
NA 9/27/99 0.016
NA 9/27/99 0.014
NA 9/27/99 0.8
NA 9/27/99 0.25
TPH as Gasoline does not include MmE.
7U
Date:
Ib'll-~1
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I
I
Sample Name:
Lab Code:
Test Notes:
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
I
I
I
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Envirorunental
Car Wash of AmericaÆV298-1610
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
B2 @ 70
L9904049-024
t
Prep Analysis
Method Method MRL
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8021B 0.005
EPA 5030 8015M 0.1
EPA 5030 8021B 0.010
t TPH as Gasoline does not include MmE.
Approved By:
I S22/020597p
04049VOH.m - Sample (3) 10121/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
50 NA 9/27/99 0.31
50 NA 9/27/99 4.2
50 NA 9/27/99 2.2
50 NA 9/27/99 17
50 NA 9/27/99 170
50 NA 9/27/99 6.5
7U
Date:
Ib-L/-7L
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert-Butyl Ether
I
I
I
I
I
I
I
II
I
I
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of AmericalEV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
B2 @ 80
L9904049-025
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 8015M 0.1
EPA 5030 802lE 0.010
t TPH as Gasoline does not include MmE.
Approved By:
7i!
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
I NA 9/29/99 0.013
I NA 9/29/99 ND
1 NA 9/29/99 ND
I NA 9/29/99 0.027
I NA 9/29/99 0.2
1 NA 9/29/99 1.0
Date:
II)·L I,. ~~
1 S221020597p
04049VOH.m, Sample (4) 10/21/99
Page No.:
I
:.
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
Client:
Project:
Sample Matrix:
California Environmental
Car Wash of Arnerica/EV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
I
I
MTBE, BTEX and TPH as Gasoline
Sample Name: B2 @ 90 Units: mg/Kg (ppm)
I Lab Code: L9904049-026 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 1 NA 9/27/99 0.014
Toluene EPA 5030 802lE 0.005 1 NA 9/27/99 0.052
I Ethy1benzene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
Xy1enes, Total EPA 5030 802lE 0.005 1 NA 9/27/99 0.043
TPH as Gasoline EPA 5030 8015M 0.1 1 NA 9/27/99 0.5
I Methyl tert -Butyl Ether EPA 5030 802lE 0.010 1 NA 9/27/99 0.71
I
I
I
I
I
t TPH as Gasoline does not include MTBE.
I
I
I Approved By: 7u Date: lo-LI"~
1 S22/020597p
I 04049VOH,m, Sample (5) 10/21/99 Page No,:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
B2 @ 100
L9904049-027
t
Prep Analysis
Method Method MRL
EPA 5030 802lB 0.005
EP A 5030 802lB 0.005
EPA 5030 802lB 0.005
EP A 5030 802lB 0.005
EPA 5030 8015M 0.1
EPA 5030 802lB 0.010
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
NA 9/27/99 ND
NA 9/27/99 0.026
NA 9/27/99 ND
NA 9/27/99 0.014
NA 9/27/99 0.2
NA 9/27/99 0.034
TPH as Gasoline does not include MfBE,
7it
I S221020S97p
04049VOH.m ' Sample (6) 10121/99
Date:
10 -l/~ 11
Page No.:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
I
Analyte
Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl fer! -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
1 S221020S97p
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
B2 @ 110
L9904049-028
t
Prep Analysis
Method Method MRL
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 80218 0.005
EPA 5030 8015M 0.1
EPA 5030 80218 0,010
TPH as Gasoline does not include MmE.
7ft
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
I NA 9/27/99 ND
I NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
1 NA 9/27/99 ND
Date:
/0 ·Llo ~~_
I
04049VOH.m, Sample (7) 10121/99
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I Analytical Report
I Client: California Environmental Service Request: L9904049
Project: Car Wash of AmericalEV298-l61O Date Collected: 9/27/99
Sample Matrix: Soil Date Received: 9/27/99
I
I MTBE, BTEX and TPH as Gasoline
I Sample Name: B2 @ 120 Units: mg/Kg (ppm)
Lab Code: L9904049-029 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 NA 9/27/99 ND
Toluene EPA 5030 802lE 0.005 NA 9/27/99 ND
I Ethylbenzene EPA 5030 802lE 0.005 NA 9/27/99 ND
Xylenes, Total EPA 5030 802lE 0.005 NA 9/27/99 ND
TPH as Gasoline EPA 5030 8015M 0.1 NA 9/27/99 ND
I Methyl fert -Butyl Ether EPA 5030 802lE 0.010 NA 9/27/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MIBE.
I
I
I Approved By: 7tf Date: 10 -lJ· Îî_
,
I S221020597p
I 04049VOH,m, Sample (8) 10/21/99 Page No.:
I
'I
I
I
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
Client:
Project:
Sample Matrix:
California Environmental
Car Wash of America/EV298-l61O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
MTBE, BTEX and TPH as Gasoline
Sample Name: B2 @ 130 Units: mg/Kg (ppm)
I Lab Code: L9904049-030 Basis: Wet
Test Notes: t
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I Benzene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
Toluene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
I Ethylbenzene EPA 5030 802lE 0.005 1 NA 9/27/99 ND
Xylenes, Total EP A 5030 802lE 0.005 1 NA 9/27/99 ND
TPH as Gasoline EPA 5030 80l5M 0,1 1 NA 9/27/99 ND
I Methyl tert -Butyl Ether EPA 5030 802lE 0.010 1 NA 9/27/99 ND
I
I
I
I
I
t TPH as Gasoline does not include MmE.
I
I
I Approved By: 7/f Date: lo-LI-~~
I S221020597p
I 04049VOH,m, Sample (9) 10/21199 Page No,:
I
I I
I
I Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl ter! -Butyl Ether
I
I
I
I
I
t
I
I
I Approved By:
1 S22/020597p
I 04049VOHJTl ,MBlank 10121/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of America/EV298-161O
Soil
MTBE, BTEX and TPH as Gasoline
Method Blank
L990927-MB
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 802lE 0.005
EP A 5030 802lE 0.005
EP A 5030 8015M 0.1
EP A 5030 802lE 0.010
Service Request: L9904049
Date Collected: NA
Date Received: NA
Units: mgIKg (ppm)
Basis: Wet
Dilution Date Date Result
Factor ExtI'acted Analyzed Result Notes
NA 9/27/99 ND
NA 9/27/99 ND
NA 9/27/99 ND
NA 9/27/99 ND
NA 9/27/99 ND
NA 9/27/99 ND
TPH as Gasoline does not include MfBE,
7U
Date:
./
10 -2/-71
Page No.:
II
I
I
Client:
Project:
Sample Matrix:
I
I
I Sample Name:
Lab Code:
Test Notes:
I
Analyte
I Benzene
Toluene
I Ethylbenzene
Xylenes, Total
TPH as Gasoline
I Methyl tert -Butyl Ether
I
I
I
I
I
I
I
I
I
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
CalifollÚa Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904049
Date Collected: NA
Date Received: NA
MTBE, BTEX and TPH as Gasoline
"
Method Blank
L990928-MB
t
Prep Analysis
Method Method MRL
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EPA 5030 802lE 0.005
EP A 5030 8015M 0,1
EPA 5030 802lE 0.010
t TPH as Gasoline does not include MmE.
Approved By:
7Lf
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
1 NA 9í28/99 ND
1 NA~ 9/28/99 ND
1 NA 9/28/99 1-ID
1 NA 9/28/99 ND
1 NA 9/28/99 ND
1 NA 9/28/99 ND
"'"
Date:
lú-lI·1~
I S22/020597p
04049YOH,rrI ,MBlank (2) 10121199
Page No,:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
I
I
I
I
I
I
I
I
I
I
I
I
Analyte
Benzene
Toluene
Ethylbenzene
Xylenes, Total
TPH as Gasoline
Methyl tert-Butyl Ether
t
Approved By:
1 S221020S97p
04049VOH.m - MB1ank 10121/99
COLUMBIA ANALYTICAL SERVICES, INC.
Analytical Report
California Environmental
Car Wash of AmericaÆV298-161O
Soil
Service Request: L9904049
Date Collected: NA
Date Received: NA
Method Blank
L990929-MB
t
Prep
Method
EPA 5030
EPA 5030
EPA 5030
EPA 5030
EPA 5030
EPA 5030
MTBE, BTEX and TPH as Gasoline
Units: mg/Kg (ppm)
Basis: Wet
Analysis Dilution Date Date Result
Method MRL Factor Extracted Analyzed Result Notes
802lB 0.005 1 NA 9/29/99 ND
802lB 0.005 1 NA 9/29/99 ND
802lB 0.005 1 NA 9/29/99 ND
802lB . 0·905 1- NA 9/29/99 ND
~
8015M 0.1 1 NA 9/29/99 ND
802lB 0.010 1 NA 9/29/99 ND
TPH as Gasoline does not include MmE.
7IJ
Date:~()-} 1- ~1
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INe.
I Analytical Report
I Client: California Enviromnental Service Request: L9904049
Project: Car Wash of AmericalEV298-l61O Date Collected: 9/27/99
Sample Matrix: Soil Date Received: 9/27/99
I
Hydrocarbon Scan / Fuel Characterization
I
Sample Name: Bl @ 70 Units: mgIKg (ppm)
I Lab Code: L9904049-007 Basis: Wet
Test Notes: X5
I Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
I C4 - C12 GRO EPA 3550M 8015M 10 9/28/99 9/28/99 64
C13 - C22 DRO EPA 3550M 80l5M 10 9/28/99 9/28/99 15
I C23 - C32 HRO EPA 3550M 80l5M 10 9/28/99 9/28/99 ND
Total Petroleum Hydrocarbons EPA 3550M 80l5M 10 9/28/99 9/28/99 79
Fuel Characterization EPA 3550M 80l5M Gasoline
I
I
I
I
I
I GRO Gasoline Range Organics
DRO Diesel Range Organics
HRO Heavy Oil Range Organics
I X5 Quantified with diesel fuel.
I
I Approved By: 7tf Date: 'b-L'~f~
.
I I S221020597p
04049SOH.rn ,Sample 10/21/99 Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INe.
I
I Client:
Project:
Sample Matrix:
I
I
I
I
Analytical Report
California Environmental
Car Wash of AmericalEV298-l61O
Soil
Sample Name:
Lab Code:
Test Notes:
Bl @ 85
L9904049-009
X5
Prep
Method
Analyte
I C4 - C12 GRO EPA 3550M
C13 - C22 DRO EPA 3550M
I C23 - C32 BRO EPA 3550M
Total Petroleum Hydrocarbons EPA 3550M
Fuel Characterization EPA 3550M
I
I
I
I
I
I
I
I
I
I
GRO
DRO
HRO
X5
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
Hydrocarbon Scan / Fuel Characterization
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
9/28/99 9/28/99 ND
9/28/99 9/28/99 ND
9/28/99 9/28/99 ND
9/28/99 9/28/99 ND
NA
Analysis
Method MRL
80l5M
80l5M
80l5M
80l5M
80l5M
10
10
10
10
Gasoline Range Organics
Diesel Range Organics
Heavy Oil Range Organics
Quantified with diesel fuel.
Approved By:
7ff
Units: mg/Kg (ppm)
Basis: Wet
Date:
Ib-ll-;í
Page No.:
I S22/020597p
04049S0HJTI ' Sample (2) 10121/99
I
I
I Client:
Project:
Sample Matrix:
I
I
I
I
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of America/EV298-l61O
Soil
Service Request: L9904049
Date Collected: 9/27/99
Date Received: 9/27/99
Hydrocarbon Scan / Fuel Characterization
Sample Name:
Lab Code:
Test Notes:
B2 @ 70
L9904049-024
X5
Units: mg/Kg (ppm)
Basis: Wet
I
Prep Analysis Dilution Date Date Result
Analyte Method Method MRL Factor Extracted Analyzed Result Notes
C4 - C12 GRO EPA 3550M 80l5M 10 9/28/99 9/28/99 25
C13 - C22 DRO EPA 3550M 80l5M 10 9/28/99 9/28/99 12
C23 - C32 HRO EPA 3550M 80l5M 10 9/28/99 9/28/99 ND
Total Petroleum Hydrocarbons EPA 3550M 80l5M 10 9/28/99 9/28/99 37
Fuel Characterization EPA 3550M 80l5M Gasoline
I
I
I
I
I
I
I
I
I
I
I
GRO
DRO
HRO
XS
Gasoline Range Organics
Diesel Range Organics
Heavy Oil Range Organics
Quantified with diesel fuel.
Approved By:
711
Date:~
I S221020597p
04049SOH,rn . Sample (3) 10/21/99
Page No,:
I
I
I Client:
Project:
Sample Matrix:
I
I
Sample Name:
I Lab Code:
Test Notes:
I
Analyte
COLUMBIA ANALYTICAL SERVICES, INe.
Analytical Report
California Environmental
Car Wash of AmericalEV298-1610
Soil
Method Blank
L990928-MB
X5
Prep
Method
I C4 - C12 GRO EPA 3550M
Cl3 - C22 DRO EPA 3550M
I C23 - C32 HRO EPA 3550M
Total Petroleum Hydrocarbons EPA 3550M
Fuel Characterization EPA 3550M
I
I
I
I
I
I GRO
DRO
HRO
I X5
I
I
II S221020S97p
04049S0H.JTl ,MBlank 10121/99
Approved By:
Service Request: L9904049
Date Collected: NA
Date Received: NA
Hydrocarbon Scan / Fuel Characterization
Analysis
Method MRL
8015M
8015M
8015M
8015M
8015M
10
10
10
10
Gasoline Range Organics
Diesel Range Organics
Heavy Oil Range Organics
Quantified with diesel fuel.
Units: mg/Kg (ppm)
Basis: Wet
Dilution Date Date Result
Factor Extracted Analyzed Result Notes
9/28/99 9/28/99 ND
9/28/99 9/28/99 ND
9/28/99 9/28/99 ND
9/28/99 9/28/99 ND
NA
7tr
Date:~
Page No.:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I QNQC Report
I Client: California Enviromnental Senice Request: L9904049
Project: Car Wash of AmericaÆV298-1610 Date Collected: NA
Sample Matrix: Soil Date Received: NA
I Date Extracted: NA
Date Analyzed: NA
Surrogate Recovery Summary
I MTBE, BTEX and TPH as Gasoline
Prep Method: EPA 5030 Units: PERCENT
Analysis Method: 802lB/80 15M Basis: Wet
I Test Percent Recovery
Sample Name Lab Code Notes 4-Brornofluorobenzene 4-Brornofluorobenzene
I Bl @ 10 L9904049-001 85 84
Bl @ 20 L9904049-002 88 96
I Bl @ 60 L9904049-006 101 109
Bl @ 70 L9904049-007 98 93
Bl @ 80 L9904049-008 87 83
I Bl @ 85 L9904049-009 100 83
Bl @ 90 L9904049-01O 96 94
Bl @ 95 L9904049-011 98 96
I Bl @ 100 L9904049-012 96 95
Bl @ 105 L9904049-013 93 89
Bl @ 110 L9904049-014 88 88
I Bl @ 120 L9904049-016 83 81
Bl @ 125 L9904049-017 80 78
Bl @ 130 L9904049-018 83 80
Bl @ 135 L9904049-O 19 77 75
I Bl @ 140 L9904049-020 75 73
I
I
I
I CAS Acceptance Limits: 60-130 60-140
I
I 7lf
Approved By: Date: Ib-ll-~'1
I 04049VORITl . SUR2 (2) 10/21/99 Page No.:
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
COLUMBIA ANALYTICAL SERVICES, INC.
QNQC Report
Client:
Project:
Sample Matrix:
Service Request: L9904049
Date Collected: NA
Date Received: NA
Date Extracted: NA
Date Analyzed: NA
California Envirorunental
Car Wash of America/EV298-161O
Soil
Surrogate Recovery Summary
MTBE, BTEX and TPH as Gasoline
Prep Method: EPA 5030 Units: PERCENT
Analysis Method: 802lB/80 15M Basis: Wet
Test Percent Recovery
Sample Name Lab Code Notes 4-Bromof1uorobenzene 4-Bromof1uorobenzene
B2 @ 40 L9904049-022 93 88
B2 @ 60 L9904049-023 102 87
B2 @ 70 L9904049-024 115 108
B2 @ 80 L9904049-025 91 84
B2 @ 90 L9904049-026 86 79
B2 @ 100 L9904049-027 88 81
B2 @ 110 L9904049-028 85 75
B2 @ 120 L9904049-029 99 97
B2 @ 130 L9904049-030 96 77
Method Blank L990927-MB 99 95
Method Blank L990928-MB 93 86
Method Blank L990929-MB 97 86
Bl @ 135 L9904049-0 19M5 79 77
Bl @ 135 L9904049-0 19DMS 71 76
B2 @ 120 L9904049-029MS 84 95
B2 @ 120 L9904049-029D11S 84 94
CAS Acceptance Limits:
60-130
60-140
Approved By:
lLf
Date: --'()"L'~ '1
SUR2/061197p
04049VOH.IT2, SUR2 (2) 10/21/99
Page No.:
I
I
~lient:
IProject:
Sample Matrix:
I
I
Sample Name:
~b Code:
.est Notes:
I
rnalYte
Benzene
!OIUene
thylbenzene
TPH as Gasoline
I
I
I
I
I
I
I
I
I
Approved By:
COLUMBIA ANALYTICAL SERVICES, INC.
QAlQC Report
California Environmental
Car Wash of AmericalEV298-161O
Soil
Matrix Spike/Duplicate Matrix Spike Summary
MTBE, BTEX and TPH as Gasoline
BI @ 135
L9904049-019MS,
L9904049-0 19DMS
Percent
Prep Analysis Spike Level Sample Spike Result
Method Method MRL MS DMS Result MS DMS MS DMS
EPA 5030 802lB 0.005 0.0400 0.0400 ND 0.0332 0.0347 83 87
EP A 5030 802lB 0.005 0.0400 0,0400 ND 0.0323 0.0338 81 84
EPA 5030 802lB 0.005 0.0400 0.0400 ND 0.0356 0.0372 89 93
EPA 5030 8015M 0.1 2.00 2.00 ND 1.82 1.88 91 94
ìtl
Date:
'b-l.I,1~
DMS/020597p
I 04049VOH,rn ,DMS 10/21/99
Senice Request: L9904049
Date Collected: NA
Date Received: NA
Date Extracted: NA
Date Analyzed: 9/29/99
Units: mgIKg (ppm)
Basis: Wet
Recovery
CAS Relative
Acceptance Percent Result
Limits Difference Notes
39-150 4
46-148 5
32-160 4
70-140 3
Page No,:
I
I
,lient:
roject:
ample Matrix:
I
I
Sample Name:
Ib Code:
st Notes:
I
ralyte
Benzene
II'luene
pylbenzene
TPH as Gasoline
I
I
I
I
I
I
I
I
'pproVed By:
COLUMBIA ANALYTICAL SERVICES, INC.
QAlQC Report
California Environmental
Car Wash of America/EV298-1610
Soil
Service Request: L9904049
Date Collected: NA
Date Received: NA
Date Extracted: NA
Date Analyzed: 9/27/99
Matrix SpikelDuplicate Matrix Spike Summary
MTBE, BTEX and TPH as Gasoline
B2 @ 120
L9904049-0291ÆS,
Units: mg/Kg (ppm)
Basis: Wet
L9904049-029D1ÆS
Percent Recovery
CAS Relative
Prep Analysis Spike Level Sample Spike Result Acceptance Percent Result
Method Method MRL 1ÆS D1ÆS Result 1ÆS D1ÆS 1ÆS D1ÆS Limits Difference Notes
EPA 5030 802 IB 0.005 0.0400 0.0400 ND 0.0334 0.0355 84 89 39-150 6
EPA 5030 802 IB 0.005 0.0400 0.0400 ND 0.0324 0.0344 81 86 46-148 6
EP A 5030 802IB 0.005 0.0400 0.0400 ND 0.0357 0.0378 89 94 32-160 6
EPA 5030 80151Æ 0.1 2.00 2.00 ND 2.22 2.16 III 108 70-140 3
7#
Date:
'b-ll-1~
DMSl020S91p
I 04049VOH,m, DMS 10121/99
Page No,:
I
COLUMBIA ANALYTICAL SERVICES, INC.
I QAlQC Report
I Client: California Environmental Service Request: L9904049
Project: Car Wash of AmericalEV298-1610 Date Collected: NA
Sample Matrix: Soil Date Received: NA
I Date Extracted: NA
Date Analyzed: NA
Surrogate Recovery Summary
I Hydrocarbon Scan / Fuel Characterization
Prep Method: EPA 3550M Units: PERCENT
Analysis Method: 8015M Basis: Wet
I
Test Percent Recovery
Sample Name Lab Code Notes p - Terphenyl
I B1 @ 70 L9904049-007 115
B1 @ 85 L9904049-009 115
I B2 @ 70 L9904049-024 92
Method Blank L990928-MB 111
B 1 @ 85 L9904049-009MS 109
I B1 @ 85 L9904049-009DMS 113
I
I
I
I
I
I
CAS Acceptance Limits: 50-140
I
I
I Approved By: 7lf Date: IÐ -ll- ; 1
I SURI/061197p
04049SOH.ITl ,SURl 10/21/99 Page No..
I
I
COLUMBIA ANALYTICAL SERVICES, INC.
QNQC Report
_lient:
roject:
ample Matrix:
California Environmental
Car Wash of America/EV298-161O
Soil
Service Request: L9904049
Date Collected: NA
Date Received: NA
Date Extracted: 9/28/99
Date Analyzed: 9/28/99
I
I
I Sample Name:
lab Code:
est Notes:
Matrix Spike/Duplicate Matrix Spike Summary
Hydrocarbon Scan / Fuel Characterization
Bl @ 85
L9904049-009MS,
L9904049-009DMS
Units: mg/Kg (ppm)
Basis: Wet
I
InalYte
Diesel
Percent Recovery
CAS Relative
Prep Analysis Spike Level Sample Spike Result Acceptance Percent Result
Method Method MRL MS DMS Result MS DMS MS DMS Limits Difference Notes
EPA 3550M 8015M 10 200 200 ND 201 193 100 96 41-136 4
I
I
I
I
I
I
I
I
I
'pproved By:
~MSl020597P
. 04049S0H,ITI - DMS 10/21199
7ff
Date:
' )-Ll-~1
Page No,:
m=~-:25ca:A"":M~:'CA::~,~.~~.~~~~~~~:~~~S"Rr
PROJECT NAMEc..A~(p"~ . ðf-~1't\(P,'~~ ~,,~~~...I føtO ANAL VSIS REQUESTED
PROJECT MANAGER fk.l K-ü.. \\ FF~~ V
COMPANY/ADDRESS C.AL FORÑ 11\ (;.tJVH~ÓµY!.1'N1"'L.
'St3~ \JIA ~LIJ..)~S Sib.- lcH
J
W~5íLA.~~ \llLLM,.~ ~A 4/3c"d..PHONE
I
SAMPLERS SIGNATURE
SAMPLE LAB SAMPLE
I.D. DATE TIME I.D, MATRIX
ßt ~ {Ö· ~/').1/qo¡ ~'c.'ió4'ì- ( S.O tL-
"I ~~ .
-1."
BI@ ~O ...':J
~\ @J 4-~ -t¡
81 ~ C)l\ ,-5
~ I@, ~ ...:."
ß l @'¡C) , -1
~I (Q> ~[) -~
Iß\ ~ ~5 -9
ßl @ '\0 -.: -r'1 ~
RY:
(....-~/..J........- ./ .//
/,
Signatur ' // L/
Pri.J)tejl,þlame
C/(jiI , "
Firr1'\a/_ / _ _
7/2-71c.J '"
DatefTïmef' '
r fY:LlN -BY:
\,JL kt~ /~ ,
ðr.=ft~~,J 17.MEJ1oAt-
Ij'in¡ed "Name
c..A S
I q1'i,o¡ Ic, t
.~~ 1
~ () R~D BY: TURNAROUND REQUIREMENTS
~ I/)ßA~ " ,... . 24hr 48hr, 5 day
~~~ ~ ,..1\. , 1. M"~ ;X. Standard
Primed Name _ Other (Specify)
c..- A. -s. _ Provide Verbal
~T~';' ktq Preliminary Results
15é1tefTlrtie Requested Report Date
¡)~~:k:
signaft /) I A,.
Printed NameT:J ~
í~'I-<; FiThû CZ.J¡ IR'1:!
Date/Ttme
II ~ IníJA 'e>'''''
rf'\.... ,
C/)
II:
W
z
<1:
t-
Z
o
ü
u..
o
II:
W
a:I
:2:
::>
z
!?
, 0
o ~ ,~
./# tJ ~ c
?5 e '" (5/:!' 0
b(3 ¿¿ ~ f)j 0 ~
~ .J!ø :]:.!Y "'è§ Be :2
~ 0 § ~ -§?t «[;5 &
ø pj!) '- & Q... Cbè ·.f!!0 ~0 ~
:S:Cb "'pj.....'1- Þ>pj"''''' Cb""
J:",~ ~'!'l: ~~.!!J::;; "'::;; ~
,
1 Y..
I
I ~~:
{ '/~'1'
I
\
{
\XX
tx
.
¡'¡Ol.-b
I-/ðl...b
~~L.D
9>
5d
Sè
~
.:=-.
X'~
REPOR ~WIfIEMENTS
I. Routine Report
X II, Report (includes DUP.MS,
MSD, as required, may be
charged as samples)
_ III. Data Validation Report
(includes All Raw Data)
_ RWaCS
y
~X
'X
,
'11-., .... ..tl~1
.
..:t,L:;, ,1"r/'*
SAMPLE RECEIPT: '
-
INVOICE INFORMATION:
P,Q.#
Sill To
Shipping VIA:
Shipping #:
Condition:
Lab No:
"
SPECIAL INSTRUCTIONS/COMMENTS:
5 A M.PL.E. ~
SAMPL-G5
u\& V A.,.J
ÄNAL'< '2:E t>
(V1 A~~£
MTB fE. H l -rS
.IN rhcßllt.-
\\ /~X /¡
l..J líl--l ~
LA 13
AN A L- Y If.. 1íJ F1 X £Þ
G-e-( m ~
C.ONF \ ~w.
O'Ç
.., u::l> p r Þ
BY
('1 ""'9. rl'"
ç-..-,....."
r¡ISTRIRIITION' WHITF· rp.I",n In nrininAtnr: YFLL ow' IRh
<lOO-OS
~----
~ Analytical
Services"lC. 6925 Canoga Avenue. Canoga Park, CA 91303. (818) 587-5550· Fax (818) 587-5555
~H_ofll!lJS1eÐY~O_o,pplA~sftE_S-mRr
L/-
PROJECTNAMEC.AtU>AS~ OF A1":f.rt\"l' ~\Q.O¡~-Ito'~
PROJECT MANAGER
COMPANYMDDRESS QL£:
SAMPLERS SIGNATURE
SAMPLE
1.0,
DATE
:,/, _I
ßf e 95'
r.>l ~ (O~
ßl éJJ IOS
ß\ ~ l l [)
ß, e- It '5
ß l é3 \ 'Lð
BI r! ld.-5
ßI @., )Ó
BI e.. t3S
ß\ é:l"-/.~ '¥'
~~
; oal"
prin~ ,
Firm" j)--;7 / ~
Datel1ïme P .,
,~I BY:
~. I""
v , --'r
.~a?J;.J ~~EÅA"
eA~ame
['1rlJ /~ I ~ 'f<:
~:rr:J-
('{(\ ,
PHONE
TIME
LAB
1.0.
I
L~l)44-1t Sðll
-(2
~13
-- (~
-It;
-1(0
-i1-
-IZ
-I,Or
Q'" -20 ~
r\ /)~BY:
Y In....... -
::JgrJ~N nNQ.~WI~~
Ftinted Name
C-A~
¡}~m_ I n..ð
f .L...f -,
Daterrime
.
¡j ~e;¡ED BY:
Si7~~A1 h
priY1tedQjåm~ "
FilJ c¡/J&J ß /~C¡./
DatefTime
11.,_
I
( j)~ 1'1. '-
,-...." ..
'~ Go
§
Ö ~ ,~
Cl.>!fJ c::
.S 8 <t1 C
Õ '" Go {5[!> C
'b/(/ ~ ~ ~ 0 ~
~;f#ø .:t' ~ (/)è§ '!'o <:5
wrv '$/00. f: ~ ,$!-:v-~" è
¡...;; 0 ~.<.J àJ 'b ~~.....r;¡ (6
'f tf "W õ.g: [!>;;j: ~ i;§ .!(¿
<t1 rv c ~; /Yo OfJ àJf;j ~
ø~ !2 & It- Cl.>è .~0 <'0 :i
~
tl
"Ç7
SAMPLE
MATRIX
en
II:
UJ
Z
<
I-
Z
o
Ü
LI-
o
II:
UJ
cc
:::E
::J
Z
l~
I [)(
f I~
\)(
AI" I' ~ "i-L
I :s,m"
I~
\ I:x-
\><
Ib{..
IX
('X'
~
TURNAROUND REQUIREMENTS
_ 24hr _48hr, _5day
.K Standard
_ Other (Specify)
Provide Verbal
Preliminary Resu~s
REPORT REQWlREMENTS
_ I. Routine Report
\ / II. Report (¡ndudes DUP,MS.
r MSD, as required, may be
charged as samples)
_ III. Data Validation Report
(includes All Raw Data)
RWacB
-
-
Requested Report Date
SPECIAL INSTRUCTIONS/COMMENTS:
SIkI'1PLf. C; AN,it L Y l £1)
SAm p~ mARt.tt> tV líH
MN F I ~lfVIv ~£. ~ 11>
DATE g / 'J.ì- loA
PAGE
ANALYSIS REQUESTED
INVOICE INFORMATION:
P,O,#
Bill To
:!tJ Mðß/L£ LAB
\\ 0) [.( 4tJALVl£ .1JJ
ðt= ?/tJõ' PPI> BY
nlSTRIRIJTION WHITE, return to oriainator. YELLOW, lab
J-
I-IOl )
SAMPLE RECEIPT:
Shipping VIA:
Shipping #:
Condition:
Lab No:
F ~ E..t>
&L!Wt5
OF
L.,Ä~
400-05
-~I~ -
~ ~nQlytiCQI
-
-
-
IIIItH.O~sftJbyaO_O""A~sftE_S-mRr
11
Services"\(' 6925 Canoga Avenue· Canoga Park, CA 91303· (818) 587-5550· Fax (818) 587-5555 DATE 9/)..1-/0, O¡ PAGE 3> OF
PROJECT NAMFfA~\.Úp.:;).\ ~1t~c..A
t\P A # EV1."~ - \b \0 ANAL VSIS REQUESTED
PROJECT MANAGER (/) ~ k
o.G- a: § 'if
COMPANY/ADDRESS w o ~ .~
Z <lI <t1 . c:
« ,S g <t1 0 .
I- Õ ",,-, t5f!> 0
z bf{J J¿ ~ ro 0 ~ .
0 ,$! .:t.!!! ~ s 0
PHONE ü ~ .'EC!J f: 0 /Jo CJO "-
u. ~& g :::J ~ ?:?t ~~ f5
0 {J:J~ ~ -S! àJ Æ~ ~~ "-'
SAMPLERS SIGNATURE a: ø& èO & o..<lI~' §;2 <lI (Q:!(Q ~
W
cc ~_ ~o ..". ÞJo ,-;::0 0
SAMPLE LAB SAMPLE ::2: ;l: ~ <lI 4.i~ ~ o~ <ìi;$ <lI;$ ~
::::>
I.D. DATE TIME I.D. MATRIX z
B~@ ~ ì 1'l1-/rtc, Lo,ttldf7- j.,1 CS~l L HðLD
,. 8d-@ 4-D , -1.1 ~
" Bd- ~ Gð -V¡ X >('.
... B,). @.. 1- D -lLf )( X )tj
ß:;) ~ ~a -l.S \~ ~.......
ß~ ~ ð -1" I ~ T tð
ß;}. @ lð6 ...-"J.1 ) ~ ) ~
v ß':). @... I\D -d~ , )t
J 0). @ \~(:) .-a~ Ix
'" 13)... ~ \~ð ~I ... -10 "";11/ , X
( ';j./~ ,. R~D BY: TURNAROUND REQUIREMENTS REPORT REQWlREMENTS INVOICE INFORMATION: SAMPLE RECEIPT:
(¿7// --- \ 71 .. f ,,{U ~ - 24 hr 48hr. _ I. Routine Report
" '"'1 V' - _5day .¡(:... II. Report (includes DUP,MS,
tiignature , 0 fl~ïí~ ntS};,£JMþ..L )C.. Standard MSD, as required, may be P,O,# Shipping VIA:
p~~ame F rint~~ame _ Other (Specify) charged as samples) Bill To Shipping #:
I a..ll _ Provide Verbal _ III. Data Validation Report Cond~ion:
Firm~ ~ /"2-r1/11 .úrJl1.- fA _ Preliminary Results (includes All Raw Data)
II ¿"1'IÎ '\ - RWaCB
Date.tPl'me ' v DfitefTifne Requested Report Date Lab No:
I :f1.~Y: ¿~VEDBY: SPECIAL INSTRUCTIONS/COMMENTS: ~tI /I1(j 8 I Li.. L4ß ..
. I~ $l\M,(>LJt$ AtJAL-Yêé.D -
~ ~rÏJ Al í2l V1 A.o A )SirjrJl1~~ '" ~ ~ tjj'l AN A L'l ~Vi. %,.1 F ~i:t> tAf
,1 $AMrL..E"~ WIA f"...¥-Jž... ~ WlTU
CJt~ Name Printed N~ ~
ppß By &C /~ s
~1t711' / fl.J.< Fir~ b d/ç 1 /X(.Ji C!.ð1J fd<M. Ml8~ tins ~F "")[C:ð
i!::\N DatelTime
tJ~ L~
CJV'f:'> I f , ' ¿ ,_ _t nl~TRIRI ITI()N' WHITF= ' ,,,llIrn In nrl in~'nr' YFII ()W - I~h 400-01;
"
~IU~----
~ Analytical
Services"\(' 6925 Canoga Avenue. Canoga Park, CA 91303. (818) 587-5550· Fax (818) 587-5555
PROJECT NAMEtA~lPAS!-l CF Amt!~IG1 (vd<18 - "dQ
PROJECT MANAGER
COMPANY/ADDRESS C-Ë-
PHONE
SAMPLERS SIGNATURE
SAMPLE
I.D.
TIME
LAB SAMPLE
I.D, MATRIX
DATE
~/- ./
I/:.lln't
, I
R~ ~ it+D
lè}9å-J.o'f.1-1ÞJ ~ ~) L
-- A~ I BY: to. ..QECEIV.5IlPY:
( /' '.// í ~ ("/ LA- {/ -.:11"¿~-'" ~
'Signature :/1 ð /-'7 ~H,J í'A¡J~,.,,14. J
Prin~<!.Þ!ame ~ Print~~ Name
~ J c..y"\S
Firm~ Þ//9f 0/1,,1. r/'7tt
DatEHT'ime . / D'tefTiræ
~QU~Z ¡{~j;DBY:
,'W$~ í21tJt-.r\L..AJ Sign~__~....,~
¿~t~ Name Printed Nat1 CP6
qir¡¿, Þc " I <;;.-C Fir~ li1 /I J r: t; I XY ('"
'r5~fTfme Datef1ime' ,
I M~ ¡J¡~~þ-
<..A>,. r,,., .' '. V
-eH.O~sftft>vao_oIftllA~sftE_s1ft}Rr
DATE 9 b..ÿ A9
ANAL VSIS REQUESTED
PAGE
¿¡.
OF
~
en
a:
w
z
:;:¡:
I-
Z
o
()
u.
o
a:
w
cc
::¡:
:J
Z
~ -
§
o ~,~ '
.! /J § 0
õ [2 ¡" (5f!> <:)
'b((f ~ ~ fJ 0 ~
k ,<!ø ~ -! o,ð Eo ~
~f:j go §:>: f?iJ ~~ {5
¡:t} ~ ~() .!J! 'b ¿g~ 1t7~ ~
~ç§ ~I.f.. [2.... IE ð?ff §~ ~
<t7 rv....'" 0 Q;Q;J' /?C co cz> co Q;
ø~ ~:::! [1 Q.... cz>ò ,;Í#(/) <"(/) ~
~id if CZ> t]P::J ~ "1- 8'P::J ~~ CZ>~ ~
1
TURNAROUND REQUIREMENTS
_ 24hr _48hr, _5day
X Standard
_ Other (Specify)
_ Provide Verbal
Preliminary Results
REPORTREQ~EMENTS
_ I. Routine Report
X II, Report (includes DUP.MS,
MSD, as required, may be
charged as samples)
_ III. Data Validat,ion Report
(includes All Raw Data)
_ RWaCB
Requested Report Date
SPECIAL INSTRUCTIONS/COMMENTS:
n ~TRIRIITI()"I' WHITF, rpll Irn In nrinin~lnr' YFIJ OW, IRh
INVOICE INFORMATION:
P,Q.#
Bill To
Shipping VIA:
Shipping #:
Condition:
Lab No:
UðLD
.
SAMPLE RECEIPT:
.
,¡no-o<=;
I
~
I
I
I
I
I
I
I
I
I
I
II
!
I
II
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261-1022 FAX (949) 261,1228
1014 E, Cooley Dr., Suite A, Colton. CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779·1843
9484 Chesapeake Dr.. Suite 805, San Die90, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St., Suite 8'120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
QA/QC PACKAGE: LEVEL III
PREP ARED FOR COLUMBIA ANALYTICAL
LABORATORY NUMBER: IJ00481.COA
PROJECT: L9904049
SAMPLED: 9/27/99
II
!~
II
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261-1228
1014 E. Cooley Dr., Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370·1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805. San Diego. CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St, Suite 6'120, Phoenix, AZ. 85044 (480) 785,0043 FAX (480) 785,0851
QA/QC REPORT: LEVEL III
PREPARED FOR COLUMBIA ANALYTICAL
PROJECT: L9904049
LABORATORY NUMBER: IJ00481.COA
TABLE SUMMARY
Page Number
CASE NARRATIVE .. ........................................ ............................... 000001
CHAIN OF CUSTODY FORM ........................................................ 000003
ANALYTICAL REPORT .........oò...................................................... 000007
QUALITY CONTROL SUMMARy................................................ 000022
METHOD BLANKS
MS/MSD DATA REPORTS
LCS DATA REPORTS
EPA 8260B LABORATORY RAW DATA ..................................... 000032
INITIAL CALIBRATION
CONTINUING CALIBRATION
TUNE REPORT
RUN LOG
QUANTITATION REPORTS
CHROMATOGRAMS
Page 1 of 1
I
.<
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C~11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51 st St. Suite S'120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261-1228
(909) 370,4667 FAX (909) 370·1046
(818) 779,IB44 FAX (BI8) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
CASE NARRATIVE
llient:
Project:
lab#:
Columbia Analytical
L9904049
IJ00481.COA
Date Sampled:
Date Received:
9/27/99
1 0/6/99
Sample Description
I B 1 @60
I B 1 @70
B 1 @80
I B1@85
I B1 @90
I B 1 @95
I B 1 @1 00
B1@110
I B2@60
I B2@80
I B2@90
I B2@1 00
B2@70
I
I
I
Del Mar Lab #
Sample Matrix
Analyses Performed
IJ00481 Soil MTBE by 8260B
IJ00482 Soil MTBE by 8260B
IJ00483 Soil MTBE by 8260B
IJ00484 Soil MTBE by 8260B
IJ00485 Soil MTBE by 8260B
IJ00486 Soil MTBE by 8260B
IJ00487 Soil MTBE by 8260B
IJ00488 Soil MTBE by 8260B
IJ00489 Soil MTBE by 8260B
IJ00490 Soil MTBE by 8260B
IJ00491 Soil MTBE by 8260B
IJ00492 Soil MTBE by 8260B
IJ00519 Soil MTBE by 8260B
Page 1 of 2
í " (, f¡ n t', i
J \.! '.,: ',-, u1
I
~
Del Mar Analytical
2852 Alton Ave" Irvine, CA 92606 (949) 261,1022 FAX (949) 261-1228
1014 E. Cooley Dr" Suite A, Colton, CA 92324 (909) 370-4667 FAX (909) 370,1046
16525 Sherman Way, Suite C'II, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr" Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505·9689
9830 South 51st St, Suite 6,120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785-0851
I
Ilient:
roject:
Columbia Analytical
L9904049
IJ00481.COA
Ib#:
CASE NARRATIVE
Date Sampled:
Date Received:
9/27/99
10/6/99
'AMPLE RECEIPT:
I
HOLDING TIMES:
IROBLEMS
INCOUNTERED:
OAlOC CRITERIA:
I
I
I
I
IBSERVA TIONS:
I
I
jEL MAR ANALYTICAL
r::e~
¡roject Manager
Sample was received intact, on ice, and with chain of custody documentation.
The cooler temperature was measured at 4 °C upon receipt at the laboratory.
All samples were analyzed within holding times.
No problems were encountered during sample analysis.
OAlOC parameters met acceptance criteria with the following exceptions:
Due to high level of MTBE in sample IJ00484, MS/MSD calculation does not
provide useful spike recovery information for QC batch IJ07011 S. Please refer
to LCS for batch validation.
MS/MSD recovery for Toluene, m,p-Xylenes and o-Xylenes were outside of
acceptance limits due to sample matrix interference for QC batch IJ07011 S.
Please refer to LCS for batch validation.
MS/MSD recovery for MTBE were outside of acceptance limits due to sample
matrix interference for QC batch IJ08011 S. Please refer to LCS for batch
validation.
No significant observations were made.
Page 2 of 2
t", t"'¡ r~ f1 !h~ .::'
; \.... 'v' '..,) ....: .1'.1
I
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave" Irvine, CA 92606
1014 E Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr" Suite 805, San Diego, CA 92123
9830 South 51st St, Suite B'120, Phoenix, AZ 85044
QNQC PACKAGE: LEVEL III
PREP ARED FOR COLUMBIA ANALYTICAL
LABORATORY NUMBER: IJ00481.COA
PROJECT: L9904049
CHAIN OF CUSTODY FORM
(949) 261,1022 FAX (949) 261,1228
(909) 370·4667 FAX (909) 370·1046
(818) 779,1844 FAX (818) 779·1843
(619) 505,9596 FAX (619) 505,9689
(480) 785-0043 FAX (480) 785,0851
r ;', f' n n ,)
'.JUJu'....",
~t~um- - - - -
~ Analrtical
SerVlCeSItI(, 6925 Canoga Avenue. Canoga Park, CA 91303· (818) 587·5550. Fax (818) 587-5555
PROJECTNAME~ .
PROJECT MANAGER ~
COMPANYIADDRESS (DLIi N;~ ~:~~ (¡;-ç
r I ~ bO
J 1 c¿ìö
ßI (.J_ ~b
&1 r? ~s-
.ßI ~ ~ó
ß/ e. c S'
ß I ~ I DO
13>r ~ I/ó
ß2- (r;J 'D
ß2... (~7D ~l
r IELlNQU~HED BY:
k IV! /'.Ã
Signatlfr'!eJ-.' IV1M¡-'
Printed Name O<1'~
Fir'?tJ /" / ~ ~ 10 l:?
SAMPLERS SIGNATURE
SAMPLE
1.0,
Datefflme
·.....v.l
RELINQUISHED BY:
,..'
"-,....'
~-....
........J
(?_ignature
·~'·'1
",rtlnted Name
.....
Firm
DatefTime
_ 24hr _48hr, _5day
Signa~ U. &r\Stl ~ Standard
PrintEN. Na¢é - Other (Specify)
l)e \ May Provide Verbal
Fi rm I 0 I ~ lD ~ 30 Preliminary Results
DatefTime I Requested Report Date if
PHONE
DATE
LAB
1.0,
SAMPLE
MATRIX
Sbl L-
TIME
~h,1 h4
,
V'
1fY17J:
RECEIVED BY:
Signature
Printed Name
Firm
DatefTime
~AtftF ee'sT~/L"RIJ!ft:>RflftNelma~T ~M-
DATE lD -f -11 PAGE 1 OF 2-
ANAL VSIS REQUESTED
U)
a:
w
z
;:¡:
f-
Z
o
Ü
LL
o
a:
w
en
:E
=>
z
~ 'Juf
t) ß ~ 1·~
Ib (J ..§
,:;; 0 0, C
o -13 & ~ '" g
b~ ;>;. ~ ro 0 {;::
.S! (!) ~ ~ '" .þ 0
~'~ r:- 0 () ()o_
/:!!¢j go §:S; è:f? ~~ &
ro ~ ~() ~ b ~§I rb'~ '"
~ç§ ",I.£. .§_.!E O"'~ §~ ;¡¡
rb'fv - C IbCti /!O co IbCO Qf
(!)~ (g!) & ct - Ibè ,f!0 ~0 ~
;t-ið £ ClJ t;PJ ~ "" 8'ro ~~ ClJ~ ~
X
~
~
~
X
X-
X.
X
)(
~
TURNAROUND REQUIREMENTS
REPORT REQUIREMENTS
_ I. Routine Report
..K. II. Report (indudes DUP,MS.
MSD, as required, may be
charged as samples)
_ III, Data Validation Report
(includes All Raw Data
_ RWOCB
INVOICE INFORMATION:
SAMPLE RECEIPT:
P.O.#~
Bill To
Shipping VIA:
Shipping #:
Condition:
Lab No:
SPECIAL INSTRUCTIONS/COMMENTS:
ÐtL- MFrtl- '~V 1 ~ é:"""
1ò
~ HOL~ 1ìM("
,
Ã~A~~I- - - -
SerVices"\( 6925 Canoga Avenue' Canoga Park, CA 91303' (818) 587·5550· Fax (818) 587-5555
~AlmF ~ST~/LmOR~OR"NmSlmQðftT ~M-
DATE 'Ó - S' -7/ PAGE 2- OF 2-
PROJECT NAME L ~~ () b ~ ~ #
PROJECT MANAGER L, fLo ç \ hc-rJS 'i\..~ AA A-i pt
en
COMPANY/ADDRESS (c\.Ut~t1n'\ A~ flL'f nl11L.(~.J\(Ë"ç ~
«
I-
z
o
o
u.
o
II:
W
cc
~
::>
z
ANAL VSIS REQUESTED
~.'
/!! :t'
8 ~ .
() -e "' .~
,~{J C § ,
~ e '" ~ g
Jeff } ¡ "";0 &
i:50v '& E: ~ .!,¿"" "," è
¡..:,C~O g b §f¿....f;j((j
P:J!tj <() 'S Qj p,s. l!!-s: '"
~& ",I.i. .g- ~ ð~!itß ¡¡¡
ð 0 è 0 &"I1J~' §:2 Qj ((j ~ c:o ,$
$:j 10.... '-0.... "0 .-:::;Ç/) ""Ç/) <
;t: <ð ;t I1J (í) 10 êì7 ~ õ'¡O ~;:!i 11J;:!i ~
ç:z
"
X
PHONE
SAMPLERS SIGNATURE
SAMPLE LAB SAMPLE
I.D, DATE TIME I.D. MATRIX
ß2.. ~ ~O I cr/1.7 /ql $otL..
ß2- r¡) ~O f
£¿ (~ /öO \1/ W
¿ ~E~kUISHED BY:
Si!;¡nat Ie ~ rr
Printed Nanièl ~
Firìo I Cð ~ '1 ' \d'p
DatefTìme
RELINQUISHED BY:
S~1ture
'--'
PtJí:ifed Name
::)
Fjr".')
# ..
Datt!ìTime
-
....- "
/ ~)1'VE F,Ö':
{! ~ /l
Sign~tÙ(.e I .<::2: III.. d D
.......... -rr f \ eo. v\.s, t.L
Print)~1e M Q(
Firm 01 ft¡ LO:~O
DatefTìme
RECEIVED BY:
Signature
Printed Name
Firm
DatefTìme
TURNAROUND REQUIREMENTS
_ 24hr _48hr, _5day
_ Standard
~ Other (Specify)
_ Provide Verbal
Preliminary Results
REPORT REQUIREMENTS
I. Routine Report
X II, Report (includes DUP.MS,
MSD, as required, may be
charged as samples)
_ III. Data Validation Report
(includes All Raw Data)
_ RwaCB
INVOICE INFORMATION:
SAMPLE RECEIPT:
P,O.#~
Bill To
Shipping VIA:
Shipping #:
Condition:
Requested Report Date
:r
Lab No:
SPECIAL INSTRUCTIONS/COMMENTS:
Tta
ÐQ MItl'l- - ,~v IN e
'f
HOLð
./
Tì~t
I ,- - - - - - - - - - - - - -
Q Del Mar Analytical . . StMPLE RECEIPT FORM Part_ 01_
CLIENT: CO 11 rJ PROJECT: Lttq D404Q CUENTPM: f-. eoss PRESERVATfVEONC.O.C._
DMAPM: 1(l-\" RECEIVEDBY:v..E. DATE: ¡of (R COOLER TEMP: 4C
SAMPLE SAMPLE DATE
NUMBER DESCRIPTION MATRIX SAMPLEC ANALYSES & PRESERVATIVE COMMENTS
)..\ O() -4- <ll '5'~ 6D ? 101 $I ~~KZ-~ 0 12u¿( 11I ~c.,
~t Ì'\ :¡O
<65 <bO I J
~+ ~5
<6) qD
~fø q5
81- lOa /
8'i ~ 1 I 0
'52. ~ I
~ feD
so J <6Ú
~( £tD
9't- J lro ~ J ~ ~
~
ld ~b¡J '8 ¿ cØ) T-ð -
Ci
(" ,
C'~
,--
C:J . .
( :', ' '.
- . SD 24 48 (£) 5 Normal
N=None; HA=HCI; NA=HN03; SA=H2S04 /'
SH=NaOH; SHZA=NaOH+ZnAcetate; ST=Na2S203
W\c;,
Written UD bv:
Labels: ,
DATE DUE}Olt (
Page_of_
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261-1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779·1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
I
I
I
I
I
I
I Attention:
Project:
I
I
I
I
I
LABORATORY REPORT
Prepared For:
Columbia Analytical
6925 Canoga Avenue
Canoga Park, CA 91303
L. Ross Fenstermaker
L9904049
Sampled: 9/27/99
Received: 1 0/6/99
Reported: 10/11/99
This laboratory report is confidential and is intended for the sole use of
Del Mar Analytical and its client. This entire report was reviewed and approved for release.
CA ELAP Certificate #1197
AZ DHS Licence #AZ0428
I
I
I DEL MAR ANALYTICAL
11::1~
Project Manager
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced. except in rull, without written permission from Del Mar Analytical.
IJ00481.COA <1 of 17>
,-.~ '. . ~ ; }t .~-.~ :-.~. :;
\.,1 \..... '--- ...... -'
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,II, Van Nuys, CA 92406
9484 Chesapeake Dr" Suite 805, San Diego, CA 92123
9830 South 51st St, Suite B,120. Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261-1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785-0043 FAX (480) 785,0851
.;.:.>:.:. ...........:.:.:.:.:.. ... :.:.:.:.:-:.;.:.:.:.:.;.;.;.:.:.:.:.:.:.:.:.:.:.;.:.:.:.:.:-:-:.:<.:.:-:.;.:.:.:.:.:.;.:.:.:.:.;.:.:.:.:.;.:.:.:.:.:.:.:.:.:->;.:.:.:.:.;.:.:.:.:.:.:.;.:.:.:.;.:.:.:.:.:.:.:.:.:.:.:-:-:-:.:.:.:.:.:.
:::::Columbiä Änaiytlcái qqq qqq·q·qtÙen(proJedTÓ:L99Ò4049q···
I::::: 6925 Canoga Avenue
¡::: Canoga Park, CA 91303 Sample Descript: Soil, B 1 @60
iAttention: L. Ross Fenstermaker Lab Number: IJ00481
QC Batch: IJ07011 S
................,....................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.........,.....,.....,..............
.... ........................
...................
....................:.:.;.:.:.:.:.:.:.:.:.:.:.:.:.:.
........
q
qq.qq qqqsampiëid:""èïiii99H .
Received: 10/6/99
Extracted: 10/7/99
Analyzed: 10/7/99
Reported: 1 0/11/99
......
'H
I {::}}::"}:::::::::o:O:OOOOO:O:O:::'::::O
...........,.....,......................
..................................
. . . . . . . . . . . . . .. ...........
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.. ..................
....................,.........................................
... ..... ..... .....
MTBE (EPA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether............... ...... ........ ............ ....
50
.....................................
510
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
I required dilution. Reporting limits for this sample have been raised by a factor of 10.
I DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Dibromofluoromethane (80-120).....
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
93%
IJ00481,COA <2 of 17>
"1 . "j r ~, ~'; ;-~ :]
..1 \... ...... .... '$
I
«
Del Mar Analytical
2852 Alton Ave., Irvine. CA 92606
1014 E, Cooley Dr., Suite A, Colton. CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr" Suite 805, San Diego, CA 92123
9830 South 51st St.. Suite 8,120, Phoenix. AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505·9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785-0851
.............. .................. .. ........ ...........................................................................................
¡ii:(2g¡~Înh¡a-Ânaiytið~(····· ........... ·····:2¡¡~:~tp¡~j~a:¡b!T99Ô4Ô49:
I :::¡: 6925 Canoga Avenue
:;:Canoga Park, CA 91303
:Attention: L. Ross Fenstermaker
........................ ........
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
....... .....................
........
:·::::::::::::::::::::::::::::::,:,:,:,:'s:~~8I~:d'~':,:9'/2'7/9'9':':':::::·:·:·:·:·:·····..·
Received: 10/6/99
Extracted: 1 0/7/99
Analyzed: 10/7/99
Reported: 1 0/11/99
...
Sample Descript: Soil, B1 @70
Lab Number: IJ00482
ac Batch: IJ07011S
I
...............................
............................................................
............................................
... . ............ ...............
.................................. .
................................
...................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..
..............................................
............................................
. ....................................
. . . . . . . . . . . . . . . . . . . . . .
...................................................................
.................................................................
.... ................................................ .
. . . . .. . ..............................
.......... ...........
...
MTBE (EPA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.............................................
50
.....................................
1,500
I
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 10.
I
DEL MAR ANALYTICAL (ElAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
DibromofluDromethane (80-120).....
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in full. without written permission from Del Mar Analytical.
94%
IJ00481.COA <3 of 17>
,.~ : . ~ rì r~i -1 ~
\.1 .... ...... .... ...... ~.
I
~m mm~":I~~~~~~~~i=~lmmmww
:j:¡:-colunibia Analytical·'· ······C¡¡ãnfPro]ediÖ:L99ö4Ò¡·g··
I ¡t 6925 Canoga Avenue
¡¡¡¡Canoga Park, CA 91303 Sample Descript: Soil, B1@80
:¡:¡:Attention: L. Ross Fenstermaker Lab Number: IJ00483
I :::':..:::::::. ;::::;::::::::::::::::::;;:::;:::::::::::;:;:::::::;:::;::::::::::::::::::::::::::::::::.:.:. ........". .........9.~.. ~.~~~.~..:...................................I.~..?!..?..~...~..~..........,.....,.. ..................................:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
MTBE (EPA 8260B)
, 2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way. Suite C'11, Van Nuys. CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8'120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370-4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785-0851
..............................................................................................................
.. ...........................................................................................
... ........... ......................... ············§·ai1ì·plê·a·:·····ghil/§g· . . ..
Received: 10/6/99
Extracted: 1 0/7/99
Analyzed: 10/7/99
Reported: 10/11/99
. . . . . . . . . . . . . . . . .
.................
.............,...
. . . . . . . . . . . . . . . . .
.................
...........................................................
.......................................................... .
...........................................................
...........................................................
.....
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether........... ......... ..... ....................
25
.....................................
1,200
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
I required dilution. Reporting limits for this sample have been raised by a factor of 5.
I DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Dibromofluoromethane (80-120).....
Results pertain only to samples tested in the laboratory. This report shalt not be
reproduced, except in fult, without written permission from Del Mar Analytical.
90%
IJ00481.COA <4 of 17>
,.. " n ~-\ "1
\ ' , II ! \. : j
,-) \0'. 'V ..: ,¡, '
I
~
Del Mar Analytical
2852 Alton Ave" Irvine. CA 92606
1014 E Cooley Dr.. Suite A. Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St, Suite B·120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1 Q.46
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
..................... .......... ...................................................................................................... ...............................
..................................................................................................... ...............................
...................................................................................................... ...............................
:::!:cofUilìhfa'ÄiíîiiyHêi3f"'cÙenfÞrojea¡Ó:L§9Ò4Ò49'" ....... .,.... .......... ......
1 /!6925 Canoga Avenue
!:!!Canoga Park, CA 91303 Sample Descript: Soil, B1@85
:/Attention: L. Ross Fenstermaker Lab Number: IJ00484
I.. QC Batch: IJ08011S
MTBE (EPA 8260B)
............
. . . . . . . . . . . . . . . . . . .
...................
...................
...................
...................
................................................................u.
...............................................................---..
.....................---.
Sampled: 9/27/99
Received: 10/6/99
Extracted: 1 0/8/99
Analyzed: 10/8/99
Reported: 1 0/11 /99
..
.....................................----.
. . .................----
...................
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
1 Methyl tert-Butyl Ether.. ..... ......................................
50
.....................................
2,900
I
1
1
I
I
1
1
1
1
1
1
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 10,
1
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120)..... 92%
1
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in full. without written permission from Del Mar Analytical.
IJ00481.COA <5 of 17>
I ~. ,f""\ r), -'! .'-,
1'"lid; : "
V ~ ......' .,/ ..... #-
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr.. Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suile 805, San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
..........................................................................................
.........................................................................................
......................................................................................... .
:::(CoiUmbiaXnaiyÜca(······ ··············CiierÏfPrûjedT5:I§§Ò4Ô49··
If 6925 Canoga Avenue
:::::Canoga Park, CA 91303
: Attention: L. Ross Fenstermaker
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785-0851
. . . . . . . . . . . . . . . . . .
..................
.......................'.............................................................................................................................................................................................
. .... ......... ......... .............................................................. ······s·arnple·d·:·····9Î2·7Î99· .....
Received: 10/6/99
Extracted: 1 0/9/99
Analyzed: 10/9/99
Reported: 1 0/11/99
I::
Sample Descript: Soil, B1@90
Lab Number: IJ00485
QC Batch: IJ09091S
MTBE (EPA 8260B)
...........................................................................................................................................:.:.:.:.:.;.;.;.:.:.:-:.:.;.;-:.:-:.:.:.:-:-:.:-;.:.:.:.:.:.:.;.:-;.:.:.:.:.:-:-;.;-:.;.:-:-:.;.:.:.:.:.:.:-:.:-:-:.:.:.:.:-:.:.;.;.;.;-:-:.;-:.:.;-:.:.;.:-:.:.:-:.:.:.;.:.:.:.:.:-:.:.:.;.;.;.:.:.:.:.:.:..-:..............
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ' , . , . . . . , ,
""..",.".,""""
....",.".....",
1 Analyte
Reporting Limit
µg/Kg
(ppb)
I Methyl tert-Butyl Ether... ................. .... .....................
50
.....................................
I
1
1
I
1
I
I
1
1
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
I required dilution. Reporting limits for this sample have been raised by a factor of 10.
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120)..... 95%
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
Sample Result
µg/Kg
(ppb)
1,200
IJ00481.COA <6 of 17>
r' _~, ('\ r,.., ;)
t; i.J U '. ~ ~, .J
I
.<
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton. CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr" Suite 805. San Diego, CA 92123
9830 South 51st St., Suite 8'120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
.................... ................... ................. .............................................................................
.................................. ..........................................................................................................................................................
j:{CoìlimhlaÅnaiyÜcåi .......H. ...... ·,·······ClienfPrôjedìö:'[§§Ò4Ô49
I ::::: 6925 Canoga Avenue
:::::Canoga Park, CA 91303 Sample Descript: Soil, B1@95
::::Attention: L. Ross Fenstermaker Lab Number: IJ00486
QC Batch: IJ07011 S
IH
......--....................................................................
...........,.,.........................................................................................................................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...................................................... .
......................................................................................
................................................................................. .
............................................................................ .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.............................................
.... .................
.......................................................................... ......... ... .............................. . ...
........................................................................... ..................................................
..............................................,...............'..,'..................,..' Sampied:§Fiii§9 ...,.
Received: 10/6/99
Extracted: 1 0/8/99
Analyzed: 10/8/99
Reported: 10/11/99
..................................................
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether... ..........................................
5.0
.....................................
140
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
DibromDfluoromethane (80-120)..... 91 %
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
IJ00481.COA <7 of 17>
" ~ (' r~ A "
lj d U I.': ,;. .,}
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr.. Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785-0043 FAX (480) 785,0851
::{Coiüïiïb¡a'Änä"lÿi,ëäi ..
I :m: 6925 Canoga Avenue
:::::Canoga Park, CA 91303
¡::"Attention: L. Ross Fenstermaker
I :'...,.,..qq
..................................................................................................
..................................................................................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
·······CÙen(Pro}edîÓ:T99Ó4Ò49·····
.......................
........................
. . . . . . . . . . . . . . . . . . . . . . .
.....................
. . . . . . . . . . . . . . . . .
.........................................................................................................................................................................................................
...............................................................................
...... ··········ŠampieêE9ÎiiÎ99··
Received: 10/6/99
Extracted: 1 0/8/99
Analyzed: 10/8/99
Reported: 10/11/99
. . . . .. ................................................................... ...................
................................. .
. ............ .
Sample Descript: Soil, B1@100
Lab Number: IJ00487
QC Batch: IJ07011 S
MTBE (EPA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether....... ............ ..........................
5.0
.....................................
89
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120)..... 92%
I
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00481.COA <8 of 17>
r' '\ [' r" ", ~.:'
tJ iJ U ~; -~ .)
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370-1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505-9689
(480) 785,0043 FAX (480) 785-0851
:::rêõ¡ûmb¡âAnåiytiêåi'h::::Ci'i~~tp~~J~~r¡Õ:L998404:9:
I }:6925 Canoga Avenue
¡¡:¡Canoga Park, CA 91303 Sample Descript: Soil, B1@110
:}Attention: L. Ross Fenstermaker Lab Number: IJ00488
QC Batch: IJ08011 S
I \}::;::::::::::::::::::::::::::.:.:.....:..........
.;.:.....:.;.:.:.:.:.:.:.:.:.:.:.:.:.:;:::::;:::::;::::;:::;:;:::::::;::::::::::::::::::::::::: .:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:. ::::::::::::::::::::::::::::::::::::
hh h h'hhhSämpied:hg/27 /99
Received: 10/6/99
Extracted: 10/8/99
Analyzed: 10/8/99
Reported: 10/11/99
...... .................................................................
::;:::::::::::;:::::;:::::::::;::::::;:.
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.... ..................... ........ ............
5.0
.....................................
110
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120)..... 94%
I
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00481.COA <9 of 17>
r'_ : -'\ r'\ ...\ .. t·,
U· ·UiUi i: .,
v --" "
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A. Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr.. Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 6,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
........................................................................................
........................................................................................
........................................................ ........................................................................................
:::(Colum6IaÄnalyibír·················'CÙen(ProjecC¡Ô:····I9904049······
I ¡:i 6925 Canoga Avenue
¡!¡:¡Canoga Park, CA 91303 Sample Descript: Soil, B2@60
):Attention: L. Ross Fenstermaker Lab Number: IJ00489
QC Batch: IJ07011 S
.................
. . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . .
..................
I ::::;:;:}}}::;:::::;::::::.:-:......
... ...... .......... ................ .... .............. .". ....... ········'····§ampIed:9ïiii99
Received: 10/6/99
Extracted: 1 0/8/99
Analyzed: 10/8/99
Reported: 10/11/99
.......................................................... ...,..............
.. .... .......................................................................
.................................,.............
....... ........ .
.............................................................................................................................. .................. .
............................... -.............................................................................................................
........... .. ........................... ................................................................................................
........... .... ....................................
MTBE (EPA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.................. .... .......................
5.0
.....................................
18
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Dibromofluoromethane (80-120)...,. 93%
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced. except in full. without written permission from Del Mar Analytical.
IJ00481.COA <10 of 17>
r' . .', (' (\" ,")
\.ì d U .,.:.¡. t
I
.<
Del Mar Analytical
2852 Alton Ave., Irvine. CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr.. Suite 805, San Die90, CA 92123
9830 South 51 st St., Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785·0851
¡:'ê6¡G;;;h¡~Xnâiyti2âi"':'ê¡¡~~rp~ôjê2r¡b~L99Ó4ò49
I ::: 6925 Canoga Avenue
:¡:Canoga Park, CA 91303 Sample Descript: Soil, B2@80
\ Attention: L. Ross Fenstermaker Lab Number: IJ00490
QC Batch: IJ08011 S
luuuu
..........................................................................................................................................................................................................................
:-:.'.:-:.:.:...:-:.:-:.:-:.:-:.:-:-:.:..-:.'.:-:-:-:-:.:-:-:.:.:-:.:-:.:-:.:-:-:-:.:.:-:-:.:.:.:.:.:.:.:.:.:.:.:.:.:.:.:':.:.:.:.:·:·:·:-:·:·:,:·:·:·:·'··š-~·n;pì~(r:·:''9/2:7/9?r:·········
Received: 1 0/6/99
Extracted: 1 0/8/99
Analyzed: 10/8/99
Reported: 1 0/11/99
,- . . . ......... ...
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether............ .......................... .......
25
.....................................
390
I
I
I
I
I
I
'\
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 5.
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120)..... 91 %
I
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00481.COA <11 of 17>
{'. ..... ('o ,...··1 ~ ç¡
vuuL....·:.)
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr" Suite 805. San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
......................................................................................................................................................................... .................................................................................................................
.................................................................................... ....................................................
:¡:(Coii.Únb¡å·Ânâíyticí3( ······ClleñfProjecC¡Ö:L99Ò4Ò49· .............,.......... ... .... ....... .........,....
I ::::: 6925 Canoga Avenue
:¡::Canoga Park, CA 91303 Sample Descript: Soil, B2@90
::::Attention: L. Ross Fenstermaker Lab Number: IJ00491
QC Batch: IJ07011 S
..............................
Sampled: 9/27/99
Received: 10/6/99
Extracted: 10/8/99
Analyzed: 10/8/99
Reported: 10/11/99
.....................
..................... .
. . . . . . . . . . . . . . . . . . . . .
......................
.....................
u.
I uuuUPPp.
....
...............................
.............................
..........................
MTBE (EPA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether............... .............. ................
25
.....................................
580
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
I required dilution. Reporting limits for this sample have been raised by a factor of 5.
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Dibromofluoromethane (80-120)..... 95%
Results pertain only to samples tested in the laboratory. This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00481.COA <12 of 17>
\J"', ~ ~t r\ íi ~ ~
I...) ~ ,.1_
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E Cooley Dr" Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr.. Suite 80S, San Diego, CA 92123
9830 South 51st St., Suite B'120. Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785·0851
............................................................ ................................................ ............. . ......................................................
............................................................ .....................................................
............................................................ ......................................................
:::rcoiÙmhiaÅr,8iyÙca( ............... ····C¡ieiïf·ProjedìÓ:·T9904Ö49·· . . ..........................................
1 fi 6925 Canoga Avenue
~~Canoga Park, CA 91303 Sample Descript: Soil, B2@100
Attention: L. Ross Fenstermaker Lab Number: IJ00492
QC Batch: IJ07011 S
I:
................................................................
................................................................
................................................................
·······················,··············Sampíed:·gìifì§9·
Received: 10/6/99
Extracted: 10/8/99
Analyzed: 10/8/99
Reported: 10/11/99
. . . . . . . . . . . . . . . . . . . . .
......................
...................
.................
MTBE (EPA 8260B)
1 Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
1 Methyl tert-Butyl Ether............ .......................... .......
5.0
.....................................
95
1
1
1
,I
1
,I
1
I
1
1
Analytes reported as N.D. were not present at Dr above the reporting limit.
1
1
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
1
Dibromofluoromethane (80-120)..... 91 %
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced. except in full, without written permission from Del Mar Analytical.
IJ00481.COA <13 of 17>
'" .', ,.-, r r\ ,~\
I;; II; i ~ d
V _ V ./.... ...
I
~ Del Mar Analytical
...'..........-:".......... ........................'.......'.'............................................,'............................................................................................,.................................. .;.;.;.;.;.;-:.;.;.;.;.;.;-:.;.;.;-:.;-;-;-;.;.;.;-:.;-:-:.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;.;-;.;.;-:-;-:.;.;.;.;.;.;.;.;,;.;.;.;.;
¡:¡::Cofumh¡aÂnalyÜêa(;;';"ê¡¡e~rp¡:ôjêaib:L99Ô4ð4å . ... ...,.. H "H .......... .......... ........ .....,.'.
I ::::: 6925 Canoga Avenue
¡.¡.¡ Cano~a Park, CA 91303 Sample Descript: Soil, B2@70
}:Attentlon: L. Ross Fenstermaker Lab Number: IJ00519
......mm ... QC Batch: M~::1;:PA 8260B)
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st SI., Suite 8,120, Phoenix, AZ 85044
I Analyte
Reporting Limit
µg/Kg
(ppb)
I Methyl tert-Butyl Ether...... ....... ............. ...................
50
.....................................
I
I
I
I
I
I
I
I
I
I
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
.............................................................
.........................................................
......................................................
S"ampìed:1ù2ii§9····
Received: 10/6/99
Extracted: 1 0/8/99
Analyzed: 10/8/99
Reported: 10/11/99
Sample Result
µg/Kg
(ppb)
770
I
Analytes reported as N.D. were not present at or above the reporting limit. Due to matrix effects and/or other factors, the sample
required dilution. Reporting limits for this sample have been raised by a factor of 10.
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromofluoromethane (80-120)..... 95%
I'
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced. except in full. without written permission from Del Mar Analytical.
IJ00481.COA <14 of 17>
'-' ' " p n ') 1
U \J ,...,1 (,_; k _If-
I
.<
Del Mar Analytical
2852 Alton Ave" Irvine, CA 92606
1014 E. Cooley Dr" Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr" Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 6,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505·9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785-0851
I
Columbia Analytical
6925 Canoga Avenue
Canoga Park, CA 91303
Attention: L. Ross Fenstermaker
Extracted: 10/7/99
Analyzed: 10/7/99
Reported: 10/11/99
I
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether. ........ ....................... .............
5.0
.....................................
N.D.
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
Dibromoffuoromethane (80-120)..... 91 %
I
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
IJ00481.COA <15 of 17>
I'. '.', "', r~ .)
I ~ : , ~ í t : ;~. J
.I ,; ..... ...
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr.. Suite 805, San Diego, CA 92123
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
Columbia Analytical
I 6925 Canoga Avenue
Canoga Park, CA 91303
Attention: L. Ross Fenstermaker
I
Extracted: 1 0/8/99
Analyzed: 10/8/99
Reported: 10/11/99
MTBE (EPA 8260B)
I Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.................... .... .....................
5.0
.....................................
N.D.
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Results pertain only to samples tested in the laboratory, This report shall not be
reproduced, except in full, without written permission from Del Mar Analytical.
Dibromofluoromethane (80-120)..... 92%
IJ00481.COA <16 of 17>
,--. '. r', ("', ~) /1
v· - · ç ; ~ ~ .,' ...~
\..~ ,J ....~....ø
I
~
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606
1014 E. Cooley Dr., Suite A, Colton, CA 92324
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123
9830 South 51st St. Suite 6'120, Phoenix, AZ 85044
(949) 261,1022 FAX (949) 261,1228
(909) 370,4667 FAX (909) 370,1046
(818) 779,1844 FAX (818) 779,1843
(619) 505,9596 FAX (619) 505,9689
(480) 785,0043 FAX (480) 785,0851
I
Columbia Analytical
6925 Canoga Avenue
Canoga Park, CA 91303
Attention: L. Ross Fenstermaker
Extracted: 1 0/9/99
Analyzed: 10/9/99
Reported: 10/11/99
I
MTBE (EPA 8260B)
I
Analyte
Reporting Limit
µg/Kg
(ppb)
Sample Result
µg/Kg
(ppb)
I Methyl tert-Butyl Ether.....................................,......,
5.0
.....................................
N.D.
I
I
I
I
I
I
I
I
I
I
Analytes reported as N.D. were not present at or above the reporting limit.
I
I
DEL MAR ANALYTICAL (ELAP #1197)
Fred Haley
Project Manager
Surrogate Standard Recovery (Accept. Limits):
I
Results pertain only to samples tested in the laboratory. This report shalt not be
reproduced, except in full, without written permission from Del Mar Analytical.
Dibromofluoromethane (80-120)..... 95%
IJ00481.COA <17 of 17>
I', . ": Ct f1 t) ~)-
t. t·f ...:.....
I '-' .... .....,.-
I
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E. Cooley Dr., Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr.. Suite 805. San Die90. CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St., Suite B,120, Phoenix. AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed: 1 0/7/99
Sample: IJ00484
Batch: IJ07011 S
Analyte R1 Sp MS
ppb ppb ppb
Vinyl Chloride
1,1-Dichloroethene
MTBE*
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene *
Tetrachloroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes *
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
Matrix: Soil
MSD
PR1
MEAN
RPD PR
Acceptance
Limits
PR2
ppb
%
RPD . MPR
%
%
%
0 25 31 29 124% 116% 6.7% 120% 30 30-160
0 25 29 27 116% 108% 7.1% 112% 40 45-165
1377.1 25 1649 1371 1088% 0% 18% 544% 40 55-155
0 25 30 28 120% 112% 6.9% 116% 20 55-150
0 25 29 27 116% 108% 7.1% 112% 20 65-140
0.1 25 27 25 108% 100% 7.7% 104% 30 55-145
2.4 25 30 29 110% 106% 3.4% 108% 25 60-140
0 25 28 27 112% 108% 3.6% 110% 30 60-145
24.5 25 74 59 198% 138% 23% 168% 20 65-140
0 25 28 28 112% 112% 0.0% 112% 50 10-200
0 25 27 27 108% 108% 0.0% 108% 20 70-135
5.5 25 39 36 134% 122% 8.0% 128% 20 70-140
28.3 50 121 101 185% 145% 18% 165% 20 40-160
11.9 25 52 45 160% 132% 14% 146% 20 65-150
. Due to high levels of analyte in the sample, the MS/MSD calculation does not provide useful spike
recovery information. See LCS for batch validation.
R1. . . . . . . . . . . . . . . . .. Result of Sample Analysis
Sp. . . . . . . . . . . . . . . . .. Spike Concentration Added to Sample
MS. . . . . . , . . . . . . . . . . . Matrix Spike Result
MSD. . . . . . . . . . . . . . .. Matrix Spike Duplicate Result
PR1. . . . . . . . . . . . . . . . . Percent Recovery of MS; ((MS-R 1 ) I SP) X 100
PR2. . . . . . . . . . . . . . . . . Percent Recovery of MSD; ((MSD-R1) I SP) X 100
RPD. . . . . . . . . . . . . . . . . Relative Percent Difference; ((MS-MSD)/(MS+MSD)/2) X 100
Acceptance Limits. . .. Statistically determined on an annual basis.
DEL MAR ANALYTICAL
" -. (-,. r.., t·..... (.....
\ ' ' ¡¡I \ : " lJ
..J \J "'" -.'~"
I
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E, Cooley Dr., Suite A, Colton, CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C'11, Van Nuys, CA 92406 (818) 779·1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St, Suite 8,120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed:
1 0/7/99
Batch:
IJ07011S
Analyte
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
Tetrachloroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
St
Acceptance
PR Limits
R1
ppb
%
%
ppb
25 25 100% 40-145
25 24 96% 55-145
25 23 92% 60-140
25 24 96% 60-140
25 24 96% 65-135
25 24 96% 55-135
25 24 96% 65-130
25 24 96% 70-130
25 24 96% 70-125
25 25 100% 65-130
25 24 96% 75-125
25 25 100% 70-125
50 53 106% 70-130
25 26 104% 70-135
St. . . . . . . .. ......... Concentration of standard added to blank.
R1 . . . . . . .. ......... Standard Result
PR. . . . . . .. ......... Percent Recovery of R1; (R1/ St) X 100
DEL MAR ANALYTICAL
(" ,'" ,',\ r~ l") r..;
, . , Ii I '. .
.) ',-: ...... ..,I ._þ
I
~
I
I
I
I
I
I
I
I
I
I
I
I
II
!.
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine. CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E, Cooley Dr.. Suite A, Colton, CA 92324 (909) 370-4667 FAX (909) 370,1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St. Suite 6,120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed: 1 0/8/99
Sample: IJ00488
Batch: IJ08011 S
Analyte R1 Sp MS
ppb ppb ppb
Vinyl Chloride
1,1-Dichloroethene
MTBE*
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
T etrach loroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
. Definition of Terms:
EPA METHOD: 8260B
Matrix: Soil
MSD PR1
MEAN
RPD PR
Acceptance
Limits
PR2
ppb
%
RPD
%
%
%
MPR
0 25 27 27 108% 108% 0.0% 108% 30 30-160
0 25 23 24 92% 96% 4.3% 94% 40 45-165
53.7 25 62 86 33% 129% 32% 81% 40 55-155
0 25 24 25 96% 100% 4.1% 98% 20 55-150
0 25 24 24 96% 96% 0.0% 96% 20 65-140
0.1 25 22 23 88% 92% 4.4% 90% 30 55-145
0 25 24 24 96% 96% 0,0% 96% 25 60-140
0 25 25 25 100% 100% 0.0% 100% 30 60-145
0.8 25 25 25 97% 97% 0.0% 97% 20 65-140
0 25 25 25 100% 100% 0.0% 100% 50 10-200
0 25 24 24 96% 96% 0.0% 96% 20 70-135
0.1 25 25 25 100% 100% 0.0% 100% 20 70-140
0.3 50 53 53 105% 105% 0.0% 105% 20 40-160
0.1 25 26 26 104% 104% 0.0% 104% 20 65-150
. Due to high levels of analyte in the sample, the MS/MSD calculation does not provide useful spike
recovery information. See LCS for batch validation.
R1. . . . . . . . . . . . . . . . .. Result of Sample Analysis
Sp. . . . . . . . . . . . . . . . .. Spike Concentration Added to Sample
MS. . . . . . . . . . . . . . . . . . Matrix Spike Result
MSD. . . . . . . . . . . . . . .. Matrix Spike Duplicate Result
PR1................. Percent Recovery of MS; ((MS-R1) 1 SP) X 100
PR2. . . . . . . . . . . . . . . . . Percent Recovery of MSD; ((MSD-R1) 1 SP) X 100
RPD. . . . . . . . . . . . . . . . . Relative Percent Difference; ((MS-MSD)/(MS+MSD)/2) X 100
Acceptance Limits. . .. Statistically determined on an annual basis.
DEL MAR ANALYTICAL
(', ~'~ ['~ (~ T) :".;;.
.; "",,' °v ...' ..:,ø J
I
((
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261-1022 FAX (949) 261,1228
1014 E. Cooley Dr., Suite A, Colton, CA 92324 (909) 370-4667 FAX (909) 370,1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr,. Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St, Suite 6,120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed:
10/8/99
Batch:
IJ08011 S
Analyte
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
Tetrachloroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
St
Acceptance
PR Limits
R1
ppb
%
ppb
%
25 26 104% 40-145
25 24 96% 55-145
25 23 92% 60-140
25 24 96% 60-140
25 24 96% 65-135
25 23 92% 55-135
25 24 96% 65-130
25 24 96% 70-130
25 24 96% 70-125
25 24 96% 65-130
25 24 96% 75-125
25 24 96% 70-125
50 51 102% 70-130
25 25 100% 70-135
St. . . . . . . .. ......... Concentration of standard added to blank.
R1 . . . . . . .. ......... Standard Result
PR . . . . . . .. ......... Percent Recovery of R1; (R1 I St) X 100
DEL MAR ANALYTICAL
(... :'. (\ r'\ r-, ; ~
t· ' I ' .. , ,
¡ '\.._- '...../ '..,1 J.Þ '-'"
I
~
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E. Cooley Dr., Suite A, Colton, CA 92324 (909) 370-4667 FAX (909) 370,1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805. San Diego, CA 92123 (619) 505,9596 FAX (619) 505·9689
9830 South 51st St., Suite 6'120, Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed: 10/9/99
Sample: IJ00258
Batch: IJ09091 S
Analyte R1 Sp MS
ppb ppb ppb
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
Tetrachloroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
Matrix: Soil
MSD
MEAN
RPD PR
Acceptance
Limits
PR1
PR2
ppb
%
MPR
RPD
%
%
%
0 25 28 28 112% 112% 0.0% 112% 30 30-160
0 25 25 26 100% 104% 3.9% 102% 40 45-165
7.8 25 36 35 113% 109% 2.8% 111% 40 55-155
0 25 27 27 108% 108% 0.0% 108% 20 55-150
0 25 27 27 108% 108% 0.0% 108% 20 65-140
0.2 25 26 26 103% 103% 0.0% 103% 30 55-145
0 25 26 26 104% 104% 0.0% 104% 25 60-140
0 25 26 28 104% 112% 7.4% 108% 30 60-145
0.1 25 26 26 104% 104% 0.0% 104% 20 65-140
0 25 25 26 100% 104% 3.9% 102% 50 10-200
0 25 25 26 100% 104% 3.9% 102% 20 70-135
0 25 26 27 104% 108% 3.8% 106% 20 70-140
0.1 50 53 55 106% 110% 3.7% 108% 20 40-160
0 25 26 27 104% 108% 3.8% 106% 20 65-150
R1. . . . . . . . . . . . . . . . .. Result of Sample Analysis
Sp. . . . . . . . . . . . . . . . .. Spike Concentration Added to Sample
MS. . . . . . . . . . . . . . . . . . Matrix Spike Result
MSD. . . . . . . . . . . . . . .. Matrix Spike Duplicate Result
PR1. . . . . . . . . . . . . . . . . Percent Recovery of MS; ((MS-R1) / SP) X 100
PR2. . . . . . . . . . . . . . . . . Percent Recovery of MSD; ((MSD-R1) / SP) X 100
RPD. . . . . . . . . . . . . . . . . Relative Percent Difference; ((MS-MSD)/(MS+MSD)/2) X 100
Acceptance Limits. . .. Statistically determined on an annual basis.
DEL MAR ANALYTICAL
r ',r'; 1_, ¡'; ,"}
.t . ~ t- i·' ~ . 10 f
\J ...... "_, ·...1 V \....
I
.<
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
Del Mar Analytical
2852 Alton Ave., Irvine, CA 92606 (949) 261,1022 FAX (949) 261,1228
1014 E, Cooley Dr., Suite A. Colton, CA 92324 (909) 370,4667 FAX (909) 370,1046
16525 Sherman Way, Suite C,11, Van Nuys, CA 92406 (818) 779,1844 FAX (818) 779,1843
9484 Chesapeake Dr., Suite 805, San Diego, CA 92123 (619) 505,9596 FAX (619) 505,9689
9830 South 51st St, Suite 6,120. Phoenix, AZ 85044 (480) 785,0043 FAX (480) 785,0851
Date
Analyzed:
10/9/99
Batch:
IJ09091 S
Analyte
Vinyl Chloride
1,1-Dichloroethene
MTBE
1,1-Dichloroethane
Chloroform
1,2-Dichloroethane
Benzene
Trichloroethene
Toluene
T etrach loroethene
Chlorobenzene
Ethylbenzene
m,p-Xylenes
o-Xylene
Definition of Terms:
EPA METHOD: 8260B
St
Acceptance
PR Limits
R1
ppb
ppb
% %
25 25 100% 40-145
25 25 100% 55-145
25 25 100% 60-140
25 25 100% 60-140
25 25 100% 65-135
25 24 96% 55-135
25 24 96% 65-130
25 24 96% 70-130
25 25 100% 70-125
25 24 96% 65-130
25 24 96% 75-125
25 25 100% 70-125
50 51 102% 70-130
25 26 104% 70-135
St. . . . . . . .. ......... Concentration of standard added to blank.
R1 . . . . . . .. ......... Standard Result
PR . . . . . . .. ......... Percent Recovery of R1; (R1 I St) X 100
DEL MAR ANALYTICAL
(' " "', r, ...., .6
, ~ t ì i i ~ .;'
) \....- .__ ",.,1 _... J~
GCIMS DAILY LOG SUMMARY
QC BA TCH#
tV/A
I
I
I
I
I
I
I
I
I
1
1
1
1
1
1
1
I
I:
l(~'I:
DATE: /0 /1-1 e,~
DATAFILE: C:\GCMSl\DATA\ ~CfDCTc:r
ANALYST: UF!rzPP/S5/",Æ-/¡,wV J INSTRUMENT: GCIMS # 1
EPA METHOD: 8260
#ALS SAMPLE NAME
,~y.s.~~~, ba.~.I{~~~,s~.e.~.~"q~/ .,
FILENAME
MATRIX CLIENT
RESULTS/RECOVERIES
............... ..........
...................................
....... ....................... .... .................. ...
.........
............
........
.........
.....................................
dir.in.i. 50 NG BFB VTUNO I ***** ***** Pass @ /I- 0 ç 1\).\'1
q,..., qqq~~*~~hioii(m qqqqqq ..~q ·qqq·q·~~r qqq .q, ***~~q q,~*~~~qq,\ Sl s;qqqq .q. qs~ q,qqq........q
2- .. ~i&2D2¡è~£~.... ............. ..~~' ·..·..·....'J~r.. ...... ......'=......... ......~.~~'~.;..... ...., ., .......... ..q'" "'q'q... q............... ..........
........... .... .............................................. .............. ... ..... ............................................... ...................... ....................... .... .... ......... .. ...... ............ .,. ............. .......................
-
......~.., .. ..~,p..r..~..,~~~¿..~..~.. ...... n' ....~... ,. ....,~,~~,~........ ..........,........, ,.... ..=............. ........ .......,..,......................... .....................
- ~ ~ C
.......'1.... ..~.r.P~.~z.:t'.~.~,~:~...,...... ..~...... .....................~,~........................n ....,......r..~~~ ~..~.h~v."f¡,~,........~ ..........
...,..?..,.. ...J..O'.r.r.~...,~.~~.~,¿..~.t~.., ........ ..=.... ..........................c;>..I~................=...............~,............ ..................... .......'n............................. ..'n................
...""b......... ..".~,r.p.,~...e..~.~,~.~.~~.........., .,=.... ..........................~.~~,........,. .......,::,.......... .........~........., ......"......,.. ......................., .."......,.......... ..',.......,...........
......,-:....... ...~,)..p..P.þ...~,~~~'~~~~.n ,.........,~.. ..............,....,o..~......... .......,=.........., q........~ ............ ....,......,.... ........., ....... ,................., ......................
......~..,....J~..r&...~,~,(;)~.~.~......... ...=,.....................nnt..~.............,..~,........ ...,.. ~.............. q.......... ..n,"" ..n........ ....,..,....,.....................n..
,......,~...., ...,~,fP.~,.e..~~~,¿,~.~Y.',.,....,.. ,.,~.. ..............,..........,'~....,... ..,."'."=."..... ....,..~......,",... ,.................... .................."...., .................... ,...,.....,..........,
,................ ................. ........~.................... ..n.... .. ...... ..q..........,............................. ....................... .........'............. ..................... ..,.................... 7 þ).................
..','.',..'.',.,'...','.'....... ..,..",.......,..'.,..,............,....,....',..,',. ..,..',.,....'....., ..,',....',...,........... .'....'....,.,.. ,.,..,.......,..','.,.,.,......".','.'.,........'..,.,......'.......,..,'.'.',' .,'.,...,.,'...',..'.'.'..,......',.,.,'...'. .,'.·,·.·.'.·,·.·..·.','.'.'.'.'.··,·,',·,·,'.',·.,~l~,.,.'..,'.....'.',',',','.....'.',." ,.'.'.',',.,','..,',.,'.,.,..',',.,..,',..
,- ---
................. ..,...............,..n..... "'''''''''''n........ ........ ........, .......... .................. 'n, ................. _,~...............,............ .............n. ..,.................. .............,........
.---.
,.--'
................. ............... .... ....... ................ .............. .......... .........................
,/
.................\~ ...........................................................................
.................... .......................
"
~
./
,
................. ..
................ ............ ............................ .... ..... ......
.....................
................
.. .................... ......
....... ........ .. ............ .. .................
...... .................... .........
....... ..
",,/'
~.
,
................
.........
..........
.............
... ............ .......
/~...'
./
....................... ................... ................... .. ....................... ..................... ......... ............. ..................... .................... ..
.................
...............
..... ................
........ ..
....................... ... ..... ....... ........ ............. ....................... ..................... ...... ................ .................... ......................
,
.... ......, ........,..,...... ..........~~.. ,.... n ........ """""'n'" ..,.... n'........ ...... .........,..
/'
//
............. """"'''''/ ...... ..nnn............ nn ....nn.. ....nnnn..',nn n "nnq..... n......nn........
........,...... qn;/' .... ""nn..n...... .. n. ........ nnn....
........ ,..n /..
/
....¡..n .. n
,..~..
....................... ," ................ ... ..... ............. ..................... ......................
........................
.......................
...... .......................
...... .'
.......... ......
........ .................. ................. .......... .........
.... ... ................ ......................... .................... ........... ....
..........
...-
_,n
initial.
-
CCV:
, [-I::£&'
5v ",yo
.-,., ~ SPIt:
US:
BFB:
'!:Ç..~~~
1: Y "f \J WI l> ()cA L. S
;j;TG I Vm boCAL.A-
:I::yc. 'I V.I-1/:;CCAL!3
TJOIV"'~0SS A
:¡.. :Ju III VI" b ú 55 ß
TTc¡,v~'VI hcZ¡:{s B
:IJ'o' VV\^1?'F5
IJ'"ú iv,,1tt c:C5
S 1: Dibromofluoromethane
S2: Tolucne-d-S
S3: 4-bromofluorobenzene
SURROGATE RECOVERY LIMITS:
SOILS
80-120
81-117
74-121
WATERS
86-118
88-11 0
86-115
Data Sent
initial.
Data Validated
. ' t' (' ,-','1
f. : ¡ : j' , ¡ . ¡, ,',
V 'v. ',J '..
//