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Home My WebLink AboutMITIGATION MATERIAL SAFETY DATA SHEET VALVOLlNE, INC. Subsidiary of Ashland oiA P.O. BOX 140. LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency. Telephoné . 1 (800) 274-5263 or 1-800-ASHLAND 72-62-7825-11 -.1' J.1¡/yoüne. ENVIRONMENTAL HEALTH & SAFETY DEPARTMENT Product Safety Group CARQUEST-FRESNO D.B.A. AUTO PARTS WHSLE P.O. BOX 3289 BAKERSFIELD CA 93385 ATTN: PLANT MGR / SAFETY DIR. Dear Customer: Recently, the State of California implemented the "Safe Drinking Water and Toxic Enforcement Act of 1986," commonly referred to as Proposition 65. This law requires, in part, that "No person in the course of doing business shall knowingly and intentionally expose any individual to a chemical known to the State to cause cancer or reproductive toxicity without first giving clear and reasonable warning to such individual..." (Section 25249.10). Proposition 65 assumes that cancer or reproductive toxicity will be associated with low level exposures to the listed chemical. It generally makes no distinction in the warning required for potential exposure to a trace level of a listed chemical. Valvoline, Inc. and its subsidiaries, MAC's Oil & Chemicals, Inc. and IG-LO, Inc. subscribe to the scientific position that the degree of exposure is an essential factor in health hazard determination and that the exposure to low levels of listed chemicals does not necessarily pose a hazard of cancer or reproductive toxicity. However, to qualify for an exemption from the warning requirement, Section 25249.10 states in part: Section 25249.6 shall not apply to any of the following: a. An exposure for which federal law governs warning in a manner that preempts State authority. b. An exposure that takes place less than 12 months subsequent to the listing of the chemical in question on the list required to be pUblished under Subdivision (a) of Section 25249.8. c. An exposure for which the person responsible can show that the exposure poses no significant risk assuminç¡ lifetime exposure at the level in question for substances known to the State to cause cancer, and that the exposure will have no observable effect assuming exposure at one thousand (1,000) times the level in Question for substances known to the State to cause reproductive toxicity based on evidence and standards of comparable scientific validity to the evidence and standards which form the scientific basis for the listing of such chemical pursuant to Subdivision (a) of Section 25249.8. Valvoline, Inc. and its subsidiaries, MAC's Oil & Chemicals, Inc. and IG-LO, Inc. manufacture and market products under numerous health, safety, and environmental regulations designed to protect health and the environment. Many of these regulations already require warnings regarding potential health hazards from certain chemicals. However, it is not yet yet clear in what specific situations additional warnings will be required in order to comply with Proposition 65. Accordingly, given this uncertainty, we are providing to our customers the following warning: WARNING Various products you purchase from us in trace amounts, contain one or more chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm. Read and follow label directions and information given on the Material Safety Data Sheets. Use care when handling any chemical product. You should advise your customers and employees of these possible hazards as is appropriate under the regulations issued pursuant to Proposition 65. If you have any questions or need additional information regarding any of these products, please call us at 1-800-ASHLAND. A copy of this letter can be posted where these product are presented for sale in order to advise the purchaser of the hazard. <: 7Z-62-78Z5-11 ~&, Ya/vo//ne. MATERIAL SAFETY DATA SHEET v ~:~~~ls~};_c. P.o. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND 000487 CARQUEST lOW40 THIS HSDS COMPLIES HITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx Product Name: CARQUEST 101'140 CARQUEST-BAKERSFIELD APH-BAKERSFIELD 200 SONORA STREET 08 70 000 0866600-000 Data Sheet No: 0164091-012.001 Prepared: OS/20/93 Supersedes: 02/04/93 BAKERSFIELD CA 93305 AnN: PLANT MGR / SAFETY DIR. PRODUCT: 52015414 INVOICE: 533186 INVOICE DATE: 08/16/93 TO: ~it~W.;:;!t:"-'7:,~t\,)~.;;t:1,:&jr~~~¿'1;.\~~Bqr;Œ.O N:IÌ1i~,R¡Q'D.U.CiITi:;mD,6NmŒ~0A'IT';illO N~~t<~..i:';;;;;ì;."'i'$.':k;:i:)ph:';Y:',¡;~~9l~~?¡7~~~~ General or Generic ID: PETROLEUM BASED-LUBRICATING DIL DOT Hazard Classification: NOT REGULATED ~~~~t~~}:~t?"?:7-:~~if~~~J;-.~~~~~~}~ ;;f.~).ií~~:,~;;r~l~~4f~~~s:.o;rn:~O N~~l~C:O M RD NlaNírtS:~~:.ï:.:g~;Ð~i~R~~~~~~){\~:.~/~;.r~;·~~..Ji:~;;~:~i~~-;~i~ INGREDIENT DETERGENT/DISPERSANT ENGINE OIL PACKAGE IF PRESENT, IARC. NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION % Ibv HT) lli 10-15 TLY Note I 1) LUBE OIL ADDITIYE 10-15 2) PETROLEUM LUBE OIL CAS #: 64742-65-0 70-85 5 MG/M3 5 MG/M3 3) Notes: ( 1) THIS PRODUCT CONTAINS A MAXIMUM OF 10% ZINC COMPOUNDS. ZINC COMPOUNDS ARE REPDRTABLE UNDER SECTION 313 OF SARA TITLE III 2) PELITLY NOT ESTABLISHED FOR THIS MATERIAL 3) PELITLY IS FOR OIL MIST. ACGIH SHORT TERM EXPOSURE LIMIT ISTEL) FOR OIL MIST IS 10 MG/CUM' .~., ·'~~~Ø(~~il!:fi¡~~~'~'~~:..~fr.'j;~~~~"""-:i};i~~8srmO N~I~HtYiSrllG'A:ß.jWiAmA~'~;;;~~"'~k-?~J?::J::f~'ili~{<·fÚ';:';:}::.~!;">i!;:;¡:~íri~? Boiling Point for PRODUCT Vapor Pressure for COMPONENT( 70-85% ) 570.00 Deg F 298.88 Deg C) ~ 760.00 mm Hg < 0.10 mm Hg ~ 68.00 Deg F I 20.00 Deg C) HEAYIER THAN AIR .877 ~ 60.00 Deg F ( 15.55 Deg C) Specific Vapor Density Specific Gravity Percent Volatiles Evaporation Rate Appearance State Form NOT APPLICABLE SLOHER THAN ETHER LIGHT AMBER LI~UID HOMO SOLN ~'i:',:,*,0;}i:'i~ir (:'þ'(;:;:r>I:;'f,~:'~ .::)~ '~o,':&S.EcmIiO NG'$'IW:::eTIlt8'¡i¡:A'N D]'ffi)ÇE.J;IOSŒO N fjiliN SO RM'A-mIO N[(;-Jii*;;'" ~~t"~'1:,:-;: :]~,::'~:':;;:-:-";~}.;:;So~~:i FLASH POINTICOC > 400.0 Deg F 204.4 Deg C) EXPLOSIVE LIMIT UNAVAILABLE EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS:. CARBON DIOXIDE AND CARBON MONOXIDE. VARIOUS HYDROCARBONS. OXIDES OF SULFUR. NITROGEN AND PHOSPHORUS, ETC. fIRE FIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACEPIECE OPERATED IN THE PDSITIYE PRESSURE DEMAND MODE HHEN FIGHTING FIRES. HATER OR FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER. ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT. BURNING LIQUID. DENSE SMOKE MAY BE GENERATED HHILE BURNING. SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE WELDING OR CU1TING TORCH ON OR NEAR DRUM (EYEN EMPTY) BECAUSE PRODUCT (EVEN ~UST RESIDUE) CAN IGNITE EXPLOSIVELY. CONTINUED ON PAGE: 2 72-62-7825-11 ~A~ Yõlvoúne. v ~~~~!-,.Is~n~4IC. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (6061 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHlAND MATERIAL SAFETY DATA SHEET 000487 CARQUEST lOW40 Page: 2 ;~';.~f.;:-;.; .:;'.;,,~ ' ::\~,~S EO?T¡;I:O N ;j>JN':';:EillRoE!;i¡AN o.:4BX'Rl!o.smO N.~I!N FW RiWA·fnEO,N;-..'t"Go'n\tti:'n'u:e:ct,;)fh~1)'''.~:'?:;''::¡i''';-:::::·;':'i'':',;M NFPA CODES: HEALTH- 1 FLAMMABILITY- 1 REACTIVITY - 0 J0~.<~:C;>;;:i: i>[.'ol.,;.,";.,_.:,::;, :.J>::~"~"':::'<i<' ,~,:';,~ :;,~! ~~:;:" ;",:;;{S EC:TUID NV~'v·S1i,EìA'l~iH ~~H¡A:Z!ARDi¡f,tI;rA'irJiArr:l;U;\?~:~;.{?:;;~:,,~?;:~){\;,;~,~~~T~~;0;~\,;~;; ~'.Í;:\'il PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II. EFFECTS OF ACUTE OVEREXPOSURE: THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA (29 CFR 1910.1200) BASED DN TESTING OF SIMILAR PRODUCTS AND/OR COMPONENTS. EYES - NOT EXPECTED TO CAUSE IRRITATION DURING NORMAL CONDITIONS OF USE. SKIN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. SHALLOHING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PRDPERTIES AND MAY CAUSE NAUSEA. ABDOMINAL CRAMPS AND DIARRHEA. INHALATION - NOT EXPECTED TO BE AN INHALATION HAZARD AT NORMAL ROOM TEMPERATURE. HOHEVER, IF EXPOSURES EXCEED THE PEL/TLV OF 5 MG/H3 FOR OIL MIST. THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCOMFDRT. FIRST AID: IF ON SKIN: THOROUGHLY HASH EXPOSED AREA HITH SOAP AND HATER. REMDVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. ' IF IN EYES: FLUSH HITH LARGE AMOUNTS OF HATER. LIFTING UPPER AND LOHER LIDS OCCASIONALLY. GET MEDICAL ATTENTION. IF IRRITATION PERSISTS. IF SHALLOHED: DO NOT INDUCE VOMITING. KEEP PERSON HARM AND QUIET. AND GET MEDICAL ATTENTION. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT. ADMINISTER OXYGEN. IF BREATHING HAS STDPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM. QUIET AND GET MEDICAL ATTENTION. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNOHN FOR THE PRODUCT. CAUTION: USED MOTOR OIL HAS BEEN SHOHN TD CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPDSED TO USED MOTOR DIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEATED CONTACT TO SKIN. ~~~~~~~·~i:~~~~~:!~-;:·:ß.}~~~~~;,~~·:;.tll.~)~<!~~~:~J~lf$S:Ø!T.ffiO N f3i!V§I~~8A~cmIiWImygD.~~A~~~~~~~&1t¡~"X:~~~~:¿J~f~~ij¡~~J,f~;~~~,!~~~tif~~,~~ HAZARDOUS POLYHERlZATIDN: CANNOT OCCUR STABILITY: STABLE TNCOMPATIBILITY: AVDID CONTACT HITH:. STRDNG OXIDIZING AGENTS id ~~'Bft~~;ßa~~'):&w4W:{f~"~«~lì~=aIIJ:~ ~~~. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID DN VERMICULITE. FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE SPILL: PREVENT RUN-OFF TO SEHERS. STREAMS OR OTHER BODIES DF HATER. IF RUN-OFF OCCURS. NOTIFY PROPER AUTHORITIES AS REQUIRED. THAT A SPILL HAS OCCURED. PERSONS NOT HEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FRDH AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE. DIKE AREA OF SPILL TO PREVENT SPREADING6 PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND. CLAY. EARTH. FLOOR ABSORBENT. R OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. . HASTE DISPOSAL METHOD: SMALL SPILL: DISPDSE OF IN ACCORDANCE HITH ALL LOCAL. STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE HITH ALL APPLICABLE LOCAL. STATE AND FEDERAL REGULATIONS. ,~~I.J \~~,.c'.I.:.,;;. ';Í:"::':'::':;'"':'';;':;,~~''' :~~.'ijSEarmO N ;mvµ:n~BR' íITEC1""'Rn.V.E~aQ U'iFBM BNi1??}ffiO~B E;-'~.USBp:~<~t~~:"';~;:ii·;: ::~:'''~'¡''i)V;:~,,:;'i:.:'~ RESPIRATORY PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOHEVER. IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PELITLV OF 5 MG/H3. THEN A NIOSH/HSHA APPROVED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. (SEE YOUR INDUSTRIAL HYGIENIST). VENTILATION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOHEVER. IF UNUSUAL OPERATING CDNDITIONS EXIST. THEN PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOH PEL/TLV (S). PRDTECTIVE GLOVES: NDT NORMALLY REQUIRED. HOHEVER. HEAR RESISTANT GLOVES SUCH AS NITRILE RUBBER TO PREVENT IRRITATIDN HHICH MAY RESULT FROM PROLONGED OR REPEATED SKIN CONTACT HITH PRODUCT. EYE PROTECTION: NDT REQUIRED UNDER NDRMAL CONDITIONS OF USE. HOHEVERz IF MISTING OR SPLASHING CDNDITIONS EXIST. THEN SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES ARE ADVISEu. OTHER PROTECTIVE EQUIPMENT: NDRMAL HaRK CLOTHING COVERING ARMS AND LEGS. ';~7~~i:::~;'''f ;',~: "!".~; '~~~~:','..¡,:':~"~SECffi;.illO N;'~LXt-::;;SR5C:illA,l-'"SiBRBaA'U~O N S:ç"O R'~m[+.I ER~QO M M ENmS:<i;r:''Þ·;:;:¡¡¡: ';~.£/;h\;;::::';~.";-Æ CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS HHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR. LIQUID. AND/OR SOLID). ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFDRHATIDN ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT HARRANTED TO BE HHETHER ORIGINATING HITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT. APPLICABLE. AND SUITABLE TO THEIR CIRCUMSTANCES. CC~TINUED ON PAGE: 3 72-62-7825-11 V ~~~~~}s~n:~C. P.O. BOX 14. LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000487 CARQUEST lOW40 Page: 3 ,·~,~~~:¡j'--{>It'·I~('p~;:¡'i'¡é"¡;>t,,\i ;,[{~~ç~¿t:.?rti;¿,'t.:,,~;\,;,,'tiSEC;rmO N';~X,:::" 1mB'EbÆŒN F,iO RiM'A';ãIf[iO N!~.1i;¡!;¡,~~.;,¿,;.::~;;,:t., :if;;! ~~f';~,¡~:~'{ ;';:'::'::;,-;'j,"·:"1~;~'Ì;'''¡''1."~ I.iAUTION! HAY CAUSE SLIGHT EYE IRRITATION. PROLONGED OR REPEATED CONTACT HAY CAUSE SKIN DISORDERS. INHALATION OF OIL MIST HAY CAUSE RESPIRATORY IRRITATION. SHALLOHING HAY CAUSE STOMACH CRAMPS AND DIARRHEA. HANDLING & STORAGE: AVOID CONTACT HITH EYES AND SKIN. HEAR SAFETY GLASSES OR GOGGLES, RESISTANT GLOVES, AND OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR YOUR OPERATION. KEEP HORKPLACE AIRBORNE CDNCENTRATIONS BELOH LEGAL AND RECOMMENDED LIMITS. USE NIOSH-APPROVED RESPIRATOR IF EXPOSED TO OIL MIST. DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR HELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE, REVIEW MATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION, INCLUDING CHRONIC HEALTH EFFECTS. FIRST AID: EYES: FLUSH THOROUGHLY HITH HATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: HASH EXPOSED AREAS HITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY OIL MIST, REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON ~ONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPOSURE CURRENTLY UNKNOWN FOR THE PRODUCT. CAUTION! USED MOTOR OIL HAS BEEN SHOWN TO CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEA TED CONTACT TO SKIN. CONTAINS: PETROLEUM DIL *** COMPONENTS APPEAR IN SECTION II *** LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST ~AGE 72-62-7825-11 MATERIAL SAFETY DATA SHEET '.r¿' YalYOÚóe. V ~~~~~lsh~n~_C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERAl:- ~R GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the product. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subiect to the reporting re- quirements of Section 313 of SARA Title III are Identi- fied in the footnotes in this section, along with typical percentages. Other components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELS! and American Con- ference of Governmental Industria Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to sinale or short term overexposure to the eyes and škin or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requiréments. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Contains label information including physical and health hazard warnings. handling and first aid instructions appropriate for the product. ADDITIONAL COMMENTS Containers should be either reconditiqned by.CERTIFIED firms or prqperly dispose~ of by APPROVED firm!!. Disp,!sal. of containers should be in accordance with applicable laws and regulatIons. wEMPTY drums should not be .9lven to indi- viduals. Serious accidents have resulted from the misuse of wEMPTIEDw containers (drums, pails, etc.). Refer to Sect- ions IV and IX. MATERIAL SAFETY DATA SHEET V ~!:~~~ls~n~~C. P.O. BOX 14. LEXINGTON, KENTUCKY 40512 (606) 264-7000 24 hour Emergency Telephone 1 (8001 274-5263 or 1-800-ASHLAND 72-62-7825-11 "Å~ Ya/vonne. 000485 CARQUEST lOW30 THIS HSDSCOMPLIES HITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx Product Name: CARQUEST 10H30 CARQUEST-BAKERSFIELD APH-BAKERSFIELD 200 SONDRA STREET 08 70 000 0866600-000 Data Sheet No: 0170829-010.001 Prepared: OS/20/93 Supersedes: 02/04/93 BAKERSFIELD CA 93305 ATTN: PLANT MGR / SAFETY DIR. PRODUCT: 52015413 INVOICE: 533186 INVOICE DATE: 08/16/93 TO: ~:¡¿;~,;t~,;~;!..~~ití~"~"''Ì,:yi::i;!ß'.J;' '><\:I,1f-k;¡--)~~'$ EGIT"ÆO N~~ßR;OD U;~T¡~IiD.ENmIiijU!,OA~$Q~;~t::i:~~'Jm~1i;"~~~f~,~:t7¥~$~1.4'~ii~ General or Generic ID: PETROLEUM BASED-LUBRICATING OIL DOT Hazard Classification: NOT REGULATED ~!-~'~i~1~1~~-i-~~~~l:;~JE\~;~·~;:A~;:~~:£"r:~~~';~;.:#i~~~~~"Y.6¡~J-.~~EcnmoN-4ID~eo M p~a~ BN;r~~?"ff-:r~:~,?~jr~~~l::~#~~~11:~~~~·ií~è~.,~~.¥t~~~;}..:f.;~~ INGREDIENT DETERGENT/DISPERSANT ENGINE OIL PACKAGE IF PRESENT, IARC, NTP AND OSHA CARCINDGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATIDN % (bv HT) PEL 10-15 TlV Note ( 1) LUBE OIL ADDITIVE 1-10 2) PETROLEUM LUBE OIL CAS #: 64742-65-0 70-85 5 MG/M3 5 HG/M3 3) Notes: ( 1) THIS PRODUCT CONTAINS A MAXIMUM OF 10% ZINC COMPOUNDS. ZINC COMPOUNDS ARE REPORTABLE UNDER SECTIDN 313 OF SARA TITLE III 2) PELlTLV NOT ESTABLISHED FOR THIS MATERIAL 3) PEL/TLV IS FOR DIL MIST. ACGIH SHDRT TERM EXPOSURE LIMIT (STEL) FOR OIL MIST IS 10 MG/C~1. ",~~:~i~;!;¢~i·"/¡·t"'Ìf*,,~,¥,~.ç·:¡"'\r1[:;':\;;:~&:<,?,,,~:~'asmIDN~ãe?Btf~Y.sœG:'~~A'~iA~~~~~1t:§:,~.~i,:~.,;f;i~¡l':'~,,;;,S:'í~."!1':';'~¿~}¡~ Boiling Point for PRODUCT Vapor Pressure for COMPDNENT( 70-85% ) 570.00 Deg F 298.88 Deg C) ~ 760.00 nun Hg < 0.10 mm Hg ~ 68.00 Deg f ( 20.00 Deg C) HEAVIER THAN AIR .879 ~ 60.00 Deg F ( 15.55 Deg C) Specific Vapor Density Specific Gravity Percent Volatiles Evaporation Rate Appearance State Form NOT APPLICABLE SLOHER THAN ETHER LIGHT AMBER LIQUID HOMOG SOLN ~~ :"1; '~;ê'~'.'{;·2~"~'.>, ';0:: ;~"f;"·';.d ¡;,:.:,'èS E'.CmEO N ,~.nv_:.F.~nR£r4A¡N D~&XBliO sœo N~I~N FIO R;M'AilEO N;::::"-:;\!:¡;::""ê;;~:'~:-';j\;¡;,~?:.:,·,:_~.,,';:",:, y.:: ,,\' FLASH POINT(COC > 400.0 Deg F 204.4 Deg C) EXPLOSIVE LIMIT UNAVAILABLE EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS:, CARBDN DIOXIDE AND CARBON MONOXIDE. VARIDUS HYDROCARBONS, OXIDES OF SULFUR. NITROGEN AND PHOSPHORUS. ETC. FIRE FIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE HHEN FIGHTING FIRES. HATER OR FOAM HAY CAUSE FROTHING HHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER, ESPECIALLY IF SPRAYED INTO CONTAINERS OF HDT. BURNING LIQUID. DENSE SMOKE HAY BE GENERATED HHILE BURNING. SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE HELDING OR CUTTI:NG TORCH ON OR NEAR DRUM (EVEN EMP'TY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. CONTINUED ON PAGE: 2 ¡Z-62-78ZS-11 r£f' Ya/yoli'ne. VALVOLlN C. Subsidiary of Ashland . nc. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (8001 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000485 CARQUEST lOW30 Page: 2 *;;!,~'f;', ,:/»'¡<, "·,:'?:-::SEC!TÆO N ,.trN;~¡F:LR'E:ë¡A'N D.~E~P l\OSíIiO N!i.iI1N RO R:M·AIT':œO.N:-;~Q,G'o'11~eim¡u:e:ä~).'::'~'¡;';r;,rj;th~~..~',f:'~"<'"'<:1,"':1 NFPA CODES: HEALTH- 1 FLAMMABILITY- 1 REACTIVITY - 0 ,~."¡,:P:!-" ,,;.f :"',:, ;",::¡ ;~\::. :,§': ~¿~,J...}';:.)¡};':·Æ.,'::¿::i'~·:-:-J-..y~~~SEcmno NfJoV..,:;f;f;g~H~ttl\¡Z~ß;D~~iA~¿;¡~·~~:~}!i:K~~~¿¿~¥A~;';if,,\~~ì~i:'ì¿-:~:,M'~ PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II. EFFECTS OF ACUTE OVEREXPOSURE: THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA (29 CFR 1910.1200) BASED ON TESTING OF SIMILAR PRODUCTS AND/OR COMPONENTS. EYES - NOT EXPECTED TO CAUSE IRRITATION DURING NORMAL CDNDITIONS OF USE. SKIN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. SHALLOWING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PROPERTIES AND MAY CAUSE NAUSEA. ABDOMINAL CRAMPS AND DIARRHEA. INHALATION - NOT EXPECTED TO BE AN INHALATION HAZARD AT NORMAL ROOM TEMPERATURE. HOHEVER, IF EXPOSURES EXCEED THE PELITLV OF 5 MGIH3 FOR OIL MIST. THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCOMFORT. FIRST AID: IF ON SKIN: THOROUGHLY HASH EXPOSED AREA HITH SOAP AND HATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH HITH LARGE AMDUNTS OF HATER. LIFTING UPPER AND LOHER LIDS OCCASIONALLY. GET MEDICAL ATTENTION. IF IRRITATION PERSISTS. , IF SHALLOHED: DO NOT INDUCE VOMITING. KEEP PERSON HARM AND QUIET. At-¡D GET MEDICAL ATTENTION. IF BREATHED: IF AFFECTEDÉ REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT. ADMINISTER OXYGEN. IF BREATHING HAS STOPP D GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM. QUIET AND GET MEDICAL ATTENTION. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNOHN FOR THE PRDDUCT. CAUTION: USED MOTOR OIL HAS BEEN SHOHN TO CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEATED CONTACT TO SKIN. ~~~r:m;iJ.-:~:R~/~ ~~~\i~~,~~:'~-A(~~F.,'%':1~fi~~r1~~~~:~i~\'¡,~';.~ sarma N~~V41~Rd3'-A\CffiD'ld1tl~Yk1ITAm~7~~1~~~l:~~ç;';c~~:;~4!~'b~)~ç¡~~~~'t';jt~!~~~ HAZARDOUS POLYMERIZATION: CANNDT OCCUR STABILITY: STABLE YNCDMPATIBILITY: AVOID CONTACT HITH:. STRONG OXIDIZING AGENTS _~'\'AI(i~"ì:lt~~~~JW«'J:~:!1'8I3:~~ STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON VERMICULITE. FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE SPILL: PREVENT RUN-OFF TO SEHERS, STREAMS OR OTHER BODIES OF HATER. IF RUN-OFF OCCURS. NOTIFY PROPER AUTHORITIES AS REQUIRED. THAT A SPILL HAS OCCURED. PERSONS NOT HEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADINGÒ PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND. CLAY. EARTH. FLOOR ABSORBENT. R OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. HASTE DISPOSAL METHOD: SMALL SPILL: DISPOSE DF IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE HITH ALL APPLICA8LE LOCAL. STATE AND FEDERAL REGULATIONS. ·'if .::<,;,.:1';-';,,'3.."..,:-:'5:'\ ~.",,;.:.~, :.~';!" ·:!.1fS ECŒI~O N·~V.illIffi-:=,RR-Œ-r;EGmnv.E,R5Q Wr."BM 8N';¡:~0 ~B'E..'1ill:S.ED~;:b5;,,~,,:,~. ,!", -::" /.,v~.-,:,-.;,,:i~: ;j'; ~~ RESPIRATORY PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER. IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PELITLV OF 5 MGIM3, THEN A NIOSH/MSHA APPROVED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. (SEE YOUR INDUSTRIAL HYGIENIST). VENTILATION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER. IF UNUSUAL OPERATING CONDITIONS EXIST. THEN PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LDCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE 8ELOH PELITLV (S). PROTECTIVE GLOVES: NOT NORMALLY REQUIRED. HOWEVER. HEAR RESISTANT GLOVES SUCH AS NITRILE RUBBER TO PREVENT IRRITATION HHICH MAY RESULT FROM PROLONGED DR REPEATED SKIN CONTACT HITH PRODUCT. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER. IF MISTING OR SPLASHING CONDITIONS EXIST. THEN SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES ARE ADVISED. OTHER PROTECTIVE EQUIPMENT: NORMAL HDRK CLOTHING CDVERING ARMS AND LEGS. ,'¡;kJ;"'~~'--i/:,;,i .'"J,,' :S;" ';" ,.:'';''¿'¡S EOlIDO N:~I'.X~.sR.Ear~A,L:!\1iP',R£~OA\UmIiO N S:iJ!O R/~OffiH BR,,~QO:M M 8Na-iS'~~,"~::':i: ,·:,t'!i.i;<:: ~<;'~,~~Ó·....~ CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR. LIQUID. AND/OR SOLID). ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFORMATIDN ACCUMULATED HEREIN IS BELIEVED TD BE ACCURATE BUT IS NOT HARRANTED TO BE HHETHER ORIGINATING HITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT. APPLICABLE. AND SUITABLE TO THEIR CIRCUMSTANCES. CONTINUED ON PAGE: 3 72-62-7825-11 ~Å~ Ya/ro//ne. V ~~~~~ls~n.C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000485 CARQUEST lOW30 Page: 3 tf~';}:~!.~'~;;C<;;·;;;~F ,,,!-(,,~ c._, ;.;,,¡:;::,;:,:;,.~:¡.; ;~,<~ ._ ':~;.f¡,¡t$S ECif.m.D N'?::Xi::;:,@A\B.Eti':àIiN RiO. R MkT;Œo.N·~.:: ",;" \ ~;, "~;¡,:;~",,...<;,~'. ." :;:';, ~ ~';. /',';;~ .,~"~"..: ;,;, ':~ ~AUTION ! MAY CAUSE SLIGHT EYE IRRITATION. PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN DISORDERS. INHALATION OF OIL MIST HAY CAUSE RESPIRATORY IRRITATIDN. SHALLOWING HAY CAUSE STOMACH CRAMPS AND DIARRHEA. HANDLING & STORAGE: AVOID CONTACT WITH EYES AND SKIN. HEAR SAFETY GLASSES OR GOGGLES, RESISTANT GLOVES, AND OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR YOUR OPERATION. KEEP WORKPLACE AIRBORNE CONCENTRATIONS BELOW LEGAL AND RECOMMENDED LIMITS. USE NIOSH-APPROVED RESPIRATOR IF EXPOSED TO OIL MIST. DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR WELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE, REVIEW MATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION, INCLUDING CHRONIC HEALTH EFFECTS. FIRST AID: EYES: FLUSH THORDUGHLY WITH HATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: HASH EXPOSED AREAS WITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY OIL MIST, REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPOSURE CURRENTLY UNKNOHN FOR THE PRODUCT. CAUTION! USED MOTOR OIL HAS BEEN SHOHN TO CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEA TED CONTACT TO SKIN. CONTAINS: PETROLEUM OIL *** COMPONENTS APPEAR IN SECTION II *** LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE 72-62-7825-11 MATERIAL SAFETY DATA SHEET ., Va/roñne. v ~~~~~!~n.C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (8001274-5263 or 1-800-ASHlAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERA~ ~R GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, rARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the product. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subject to the reporting re- quirements of Section 313 of SARA Title III are Identi- fied in the footnotes in this section, along with ty.pical percentages. Other components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PEL5ì and American Con- ference of Governmental Industria Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and skin or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and 'skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR lEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposai. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Contains label information including physical and health hazard warnings, handling and first aid instructions appropriate for tne product. ADDITIONAL COMMENTS Containers should be either reconditioned by CERlï¡"IED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. wEMPTYw drums should not be.Qiven to indi- viduals. Serious accidents have resulted from the misuse of wEMPTIEDw containers (drums, pails, etc.). Refer to Sect- ions IV and IX. 72-62-7825-11 'AI' Ya/ro//ne. V~~i~~~~s~n.C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET ENVIRONMENTAL HEALTH & SAFETY DEPARTMENT Product Safety Group CARQUEST-BAKERSFIELD APW-BAKERSFIELD 200 SONORA STREET 08 70 000 0866600-000 BAKERSFIELD CA 93305 ATTN: PLANT MGR / SAFETY DIR. Dear Customer: Recently, the State of California implemented the "Safe Drinking Water and Toxic Enforcement Act of 1986," commonly referred to as Proposition 65. This law requires, in part, that "No person in the course of doing business shall knowingly and intentionally expose any individual to a chemical known to the State to cause cancer or reproductive toxicity without first giving clear and reasonable warning to such individuaL" (Section 25249.10). Proposition 65 assumes that cancer or reproductive toxicity will be associated with low level exposures to the listed chemical. It generally makes no distinction in the warning required for potential exposure to a trace level of a listed chemical. Valvoline, Inc. and its subsidiaries, MAC's Oil & Chemicals, Inc. and IG-LO, Inc. subscribe to the scientific position that the degree of exposure is an essential factor in health hazard determination and that the exposure to low levels of listed chemicals does not necessarily pose a hazard of cancer or reproductive toxicity. However, to qualify for an exemption from the warning requirement, Section 25249.10 states in part: Section 25249.6 shall not apply to any of the following: a. An exposure for which federal law governs warning in a manner that preempts State authority. b. An exposure that takes place less than 12 months subsequent to the listing of the chemical in question on the list required to be published under Subdivision (a) of Section 25249.8. c. An exposure for which the person responsible can show that the exposure poses no significant risk assuminQ lifetime exposure at the level in question for substances known to the State to cause cancer, and that the exposure will have no observable effect assuming exposure at one thousand (1,000) times the level in question for substanc¡)s known to the State to cause reproductive toxicity based on evidence and standards of comparable scientific validity to the evidence and standards which form the scientific basis for the listing of such chemical pursuant to Subdivision (a) of Section 25249.8. Valvoline, Inc. and its subsidiaries, MAC's Oil & Chemicals, Inc. and IG-LO, Inc. manufacture and market products under numerous health, safety, and environmental regulations designed to protect health and the environment. Many of these regulations already require warnings regarding potential health hazards from certain chemicals. However, it is not yet yet clear in what specific situations additional warnings will be required in order to comply with Proposition 65. Accordingly, given this uncertainty, we are providing to our customers the following warning: WARNING Various products you purchase from us in trace amounts, contain one or more chemicals known to the State of California to cause cancer, birth defects, or other reproductive harm. Read and follow label directions and information given on the Material Safety Data Sheets. Use care when handling any chemical product. You should advise your customers and employees of these possible hazards as is appropriate under the regulations issued pursuant to Proposition 65. If you have any questions or need additional information regarding any of these products, please call us at i-800-ASHLAND, A copy of this letter can be posted where these product are presented for sale in order to advise the purchaser of the hazard. 72-62-7825-11 .. Ya/voüne. v ~~~~~!s~n~~C. P.O. BOX 14. LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHlAND MATERIAL SAFETY DATA SHEET ENVIRONMENTAL HEALTH & SAFETY DEPARTMENT Product Safety Group CARQUEST-BAKERSFIELD APW-BAKERSFIELD 200 SONORA STREET 08 70 000 0866600-000 BAKERSFIELD CA 93305 ATTN: PLANT HGR / SAFETY DIR. Dear Customer: Enclosed are Material Safety Data Sheets (MSDS) for Valvoline products you recently purchased. These MSDSs are provided under our policy of communicating to our customers health, safety, and environmen- tal protection information necessary to ensure safe handling and use of our products and in compliance with the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard 29 CFR. 1910.1200. This information should be made available to health and safety personnel in your firm as well as to all employees handling the product(s). Significant changes in health, safety, environme~tal or formu- lation information will be promptly forwarded to you. If you resell or distribute a Valvoline product, you are required by law to furnish a copy of the MSDS and adequate warning label for that product to your customer. We appreciate your patronage and will continue to provide quality products and service. MATERIAL SAFETY DATA SHEET v ~:~~!-!s~n~_C. P.O. BOX 14.' LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND 72-62-7825-11 ~~, Ya/YOúne. 000481 CARQUEST 20WSO THIS HSDS COMPLIES HITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx Product Name: CARQUEST 20H50 CARQUEST-BAKERSFIELD APH-BAKERSFIELD 200 SONORA STREET 08 70 000 0866600-000 Data Sheet No: 0171982-010.001 Prepared: OS/20/93 Supersedes: 06/04/92 BAKERSFIELD CA 93305 ATTN: PLANT MGR / SAFETY DIR. PRODUCT: 52010425 INVOICE: 533186 INVOICE DATE: 08/16/93 TO: :¡¡;;i"\':;i. '1;'>'!\"""J"~~(i';:;¡i.}¡,¿-,¡';:.£- g[,"''.'-:;:''';;;¡;:·~t~EÐJ?r¡O N~~~R;O:D.trCm::.,nœBNIfiI'FiEC!AYIEO N~i':!"/ij*i:1-1;¡'7Ç~'~1~ji"";"'*;¥ir';~,/;~1':-"i~-¿.;{f';1'::f General or Generic 10: PETROLEUM BASED-LUBRICATING OIL DOT Hazard Classification: NOT REGULATED '~ì'~ ~1 'Jr~'..f,i.::~~{ ;..~~.;;;~~,":.~¥t'Î~,~,,!,: ,'" ~ ~~~.,;oL <~¡~~~~':..,-þ-;:-~~ :<£.t~4)~SEcmmO Nt\~DI~eO M gO N eNiTIS.1!~:K~~..~i~š:;;'-'~~~,~·~;:~~~~1~~{;~~:'l:J ~:\:,"~~~:~~Y;'!..;!A~:{"r.'-/?;~1~-g;~ INGREDIENT DETERGENT/DISPERSANT ENGINE DIL PACKAGE IF PRESENT, IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION X (bv HT> Pel 10-15 nï Note 1) LUBE OIL ADDITIVE 1-10 2) PETROLEUM LUBE OIL CAS #: 64742-65-0 70-85 5 MG/M3 5 MG/M3 3) Notes: ( 1) THIS PRODUCT CONTAINS A MAXIMUM OF lOX ZINC COMPOUNDS. ZINC CDMPOUNDS ARE REPORTABLE UNDER SECTION 313 OF SARA TITLE III 2) PEL/TLV NOT ESTABLISHED FOR THIS MATERIAL 3) PEL/TLV IS FOR OIL MIST. ACGIH SHORT TERM EXPOSURE LIMIT (STEL) FOR OIL MIST IS 10 MG/CUM. ·'k·.~"w,::).;,""";~;;!~~Ç'~7~~';.1!fJ'¢.~;':!7..7!,,:?%~¥~~';,~$~O N(~ImL~HtYJSillG"A' l.EbID:AmA\{,0t4!'~;'''''¡~$::,~:}~~~;r.;,'ïi'!;j~¡':'0:.~,:;'''';,:,;'-j:j;;5~~:,';;j,-';'';::~' Boiling Point for PRODUCT ( ã) 590.00 Deg F 310.00 Deg C) 760.00 mm Hg Vapor Pressure NOT APPLICABLE Speci fic Vapor Density Specific Gravity HEAVIER THAN AIR .890 ã) 60.00 Deg F ( 15.55 Deg C) Percent Volatiles NOT APPLICABLE Evaporation Rate Appearance State Form SLOHER THAN ETHER LIGHT AMBER LIQUID HOMOG SOLN '~"'1~~'t{( :^"~;;'¿" "::'(o-':'';{'',c ,,~:, ':::::(.~;SãSEC-ffimO N:r!L~V-7.¡:;-œRE1!;.?A:N D~.EÐN:~~OSffiQN~!:,-;g¡N FiO R'M'Ä,TillO N,,;' ',' "<':__; .~.,;, ",' ;: ,: r.'.; .,',> "<..>,~': FLASH POINT(COC > 400.0 Deg F 204.4 Deg C) EXPLOSIVE LIMIT UNAVAILABLE EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRDDUCTS: MAY FORM TOXIC MATERIALS~~ CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS, OXIDES OF SULFUR, NITROGEN AND PHOSPHORu:s. HC. FIRE FIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACE PIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE HHEN FIGHTING FIRES. HATER OR FOAM MAY CAUSE FROTHING HHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE DF THE FIREFIGHTER, ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT, BURNING LIQUID. DENSE SMOKE MAY BE GENERATED HHILE BURNING. SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE HELDING DR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. ""'PA CODES: HEALTH- 1 FLAMHABILITY- 1 REACTIVITY- 0 CONTINUED ON PAGE: 2 72-62-7825-11 ,~, Ya/yoúne. V ~~i~~~}S~n.C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000481 CARQUEST 20WSO Page: 2 <!>~::"">" ;':',,~, .'!' :,' "::.,,,: ;-'>':" \ .':'., '~";r:~,i:'!'~~"~',;,,,, ~S 8CIijEO N::\V~BA'6F:H""H:A'ZiA'RD~:tD Aff;A' '<,,:~ .;,'~'.:':';' ;:'..:;' ':,: '~~' ,:ë:' "Ì', ;,.,:, .':':' \ , 'j,,';-' -\~ .,~,-: t'ERMISSIBLE EXPOSURE LEVel: NDT ESTABLISHED FOR PRODUCT. SEE SECTION II. EFFECTS OF ACUTE OVEREXPOSURE: THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA (29 CFR 1910.1200) BASED DN TESTING OF SIMILAR PRODUCTS AND/DR CDMPONENTS. EYES - NOT EXPECTED TO CAUSE IRRITATION DURING NORMAL CONDITIONS OF USE. SKIN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. SHALLOHING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PROPERTIES AND MAY CAUSE NAUSEA, ABDOMINAL CRAMPS AND DIARRHEA. INHALATION - NOT EXPECTED TO BE AN INHALATION HAZARD AT NDRMAL ROOM TEMPERATURE. HOHEVER, IF EXPOSURES EXCEED THE PEL/TLV OF 5 MG/M3 FOR OIL MIST, THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCOMFORT. FIRST AID: IF ON SKIN: THOROUGHLY HASH EXPOSED AREA HITH SOAP AND HATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH HITH LARGE AMOUNTS OF HATER, LIFTING UPPER AND LOHER LIDS OCCASIONALLY. GET MEDICAL ATTENTION, IF IRRITATION PERSISTS. IF SHALLOHED: DD NDT INDUCE, VOMITING, KEEP PERSON HARM AND QUIET, AND GET MEDICAL ATTENTION. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM, QUIET AND GET MEDICAL ATTENTION. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNOWN FOR THE PRODUCT. CAUTION: USED MOTOR OIL HAS BEEN SHOHN TO CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEATED CONTACT TO SKIN. ~~~-:;;-~~:1,':¡'~1" ;~t~~~ \~~~:r~-:<l~'~~l.~~;-'~:~'·~~::'~.!~;~'J.;¡¡J.",-:;!-.. ~BG\TmO N}iiVrr-~R8A ~v:mr~V~D AmA¿Zt~~~~¡~~Þ5~'\~;~F-~"-~f1~·I.~!i\1r:¡:¿'~~-:30'~'~~~~~:'¿~::~~~:~,.~ HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOID CONTACT HITH:, STRONG OXIDIZING AGENTS ~i;-t,;{,:,,;:~';"i:bf-:,:;~,ò.~~\,t ';~:'(-N;'1'~I;i;tî~:LI',~5CTI1EO N ·::'\V1EI!dSP.1mlli'.o!o R~Ii!BA'K~P.iRaæÐ,U,Ri8Sp¿~;f~~<'t<!rifJW>.§ ;š,'iìt~~:,?":;.,,;,":."~~ STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR DTHER ABSORBENT MATERIAL. LARGE SPILL: PREVENT RUN-OFF TO SEHERS, STREAMS OR OTHER BODIES OF HATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS OCCURED. PERSONS NOT HEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE.z DIKE AREA OF SPILL TO PREVENT SPREADING6 PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN Ut' ON SAND, CLAY, EARTH, FLOOR ABSORBENT, R OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. MASTE DISPOSAL METHOD: SHALL SPILL: DISPOSE OF IN ACCORDANCE HITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCDRDANCE HITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. ~~~;. ,t.:~: :-::.-';:, ;"',~.ç': '": '...,"'.;~;.'~:~~ßEO:TmO N ~Vmm:' : P,R omEsrã¡\lE~EQ œœM EN;r:~;r¡O'õ-¡B'E~llSED:¡4;~;.-;:f';"~i::~_';'~,.,:;:,,-::,::;';",:'>::;. :7\,~~ RESPIRATORY PROTECTION: NDT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER, IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PEL/TLV OF S MG/M36 THEN A NIOSH/MSHA APPROVED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. (SEE Y UR INDUSTRIAL HYGIENIST). VENTIlATIDN: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOHEVER, IF UNUSUAL OPERATING CONDITIONS EXIST, THEN PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELCH PEl/TLV (S). PROTECTIVE GLOVES: NOT NORMALLY REQUIRED. HOHEVER, HEAR RESISTANT GLOVES SUCH AS NITRILE RUBBER TO PREVENT IRRITATION HHICH MAY RESULT FROM PROLONGED OR REPEATED SKIN CONTACT HITH PRODUCT. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOHEVER.z IF MISTING OR SPLASHING CONDITIONS EXIST, THEN SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES ARE ADVISED. OTHER PROTECTIVE EQUIPMENT: NDRMAL HaRK CLOTHING COVERING ARMS AND LEGS. ':!,;-'-:,'i"!.''-,,-', ',C: j', ',,',..:::, '''4SEC;T~O N'"EiX~SPEQmA LT~BR EGiADITŒO NS(~O R¡:fOiTIH BR~Z}~GUMMENif:S,<,.~~,::;c:-",<:;;,:l(,:'þ2;.';:·"~ ,.;.~ CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS HHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT HARRANTED TO BE WHETHER ORIGINATING HITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE DF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. (' , :~":'.<> ,~<"", f·,:; ""'.' "c,';?" "',' .,,;,.~,,--:. ·:':.tSEc;nEaN~t-)(:::'D'A:B Eb;~":illN ROR1M'A~T~ON'~\:"·~",':·_"J~';:'··'-"·~<:;·";:·,·,,~ ':',¿",;"',;,'"'" 'Í '}:=~ CAUTION! MAY CAUSE SLIGHT EYE IRRITATION. CONTiNUED ON PAGE: 3 72-62-7825-11 ~.~ YaIYoñne. v ~:~~~!s~n~fc. P.O. BOX 140 LEXINGTON, KENTUCKY 40512 (606) 264-7000 /'. tJ . : '-2 - u Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000481 CARQUEST 20WSO Page: 3 ,~;'¡;::"~¡':'::""., .::, 'i~,';:";":""~ EGffiIiO N~<;'X~/~A:B ELi~N EO R;M'ArrŒON~acG.o'næåm;U'Eid,");",~, ':~""r,,·,,¥;,^:f :""/:,:~:";:;,,\..,,f,:~~,o::~,::;, ,,< ''f. PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN DISORDERS. INHALATION OF OIL MIST MAY CAUSE RESPIRATORY IRRITATION. SHALLDHING MAY CAUSE STOMACH CRAMPS AND DIARRHEA. HANDLING & STORAGE: AVOID CONTACT HITH EYES AND SKIN. HEAR SAFETY GLASSES OR GOGGLES, RESISTANT GLOVES. AND OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR YOUR OPERATION. KEEP HORKPLACE AIRBORNE CONCENTRATIONS BELOH LEGAL AND RECOMMENDED LIMITS. USE NIOSH-APPROVED RESPIRATOR IF EXPOSED TO OIL MIST. DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR HELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE. REVIEH MATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION. INCLUDING CHRONIC HEALTH EFFECTS. FIRST AID: EYES: FLUSH THOROUGHLY HITH HATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: HASH EXPOSED AREAS HITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY OIL MIST. REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPOSURE CURRENTLY UNKNOHN FOR THE PRODUCT. CAUTION! USED MOTDR OIL HAS BEEN SHOHN TO CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEA TED CONTACT TO SKIN. CONTAINS: PETROLEUM OIL *** COMPONENTS APPEAR IN SECTION II *** LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE 72-62-7825-11 '...fV Ya/YOI/ne MATERIAL SAFETY DATA SHEET V~~~~~~~n~.C. P.o. BOX 14.' LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERAl:- ~R GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the Jroduct. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subject to the reporting re- quirements of Section 313 of SARA Title III are Identi- fied in the footnotes in this section, along with typical percentages. Other components may be listed If deemed appropriate. Exposure recommendations are for comJonent5. OSHA Permissible Exposure Limits (PEL51 and American Con- ference of Governmental Industria Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and sl<in or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Contains label information including Jh~sical and health hazard warnings¡ handling and first aid instructions appropriate for tne product. ADDITIONAL COMMENTS Containers should be either reconditioned b~ CERTIFIED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. 'EMPTY' drums should not be.9iven to indi- viduals. Serious accidents have resulted from the misuse of 'EMPTIED' containers (drums, pails, etc.). Refer to Sect- ions IV and IX. MATERIAL SAFETY DATA SHEET V~~~~~ls~n~C. P.O. BOX 1~' LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (8001274-5263 or 1-800-ASHLAND 72-62-7825-11 ~.fV Ya/roÑne. 000482 CARQUEST 5W30 THIS HSDS COMPLIES HITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 AXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXX X Product Name: CARQUEST 5H30 CARQUEST-BAKERSFIELD APH-BAKERSFIELD 200 SONORA STREET 08 70 000 0866600-000 Data Sheet No: 0172013-009.001 Prepared: OS/20/93 Supersedes: 01/29/93 BAKERSFIELD CA 93305 AnN: PLANT MGR / SAFETY DIR. PRODUCT: 52015453 INVOICE: 533186 INVOICE DATE: 08/16/93 TO: 'Yif!.;~-t1~fj;~J,~,;ti/.s;''':;~¡ii>:¡i;þr<,;¡;·~i¡,!;::,:·r,,:'0~ EcrrIliaN'~~ R.GD U.Q-n~Jtl) 8N:T,-ù!F.tEGiA'iTfEO N'f¡~~-:;'-f7í,~,fl!',,~,,~~;o¡:,~<,~ ~!:!t,;' t';~;:;i:~i\:),:f,~:~!:"",).~j,~ General or Generic ID: PETROLEUM BASED-LUBRICATING DIL DOT Hazard Classification: NOT REGULATED :~~q¡~~..:~~~~~:t.!~~:~~"f::t.{ '":;I::~~~;f.'4~ ::':"/:Yd.~,~;;~·~~tr~ ?f:>~: ::':..::"ii~SEC;r:mo N !¡:roF~5-~uÐ M F?~'N 8NTS~;&i;~~~:;¡:Á..J;--Þ,I'i1~¿,t-~f!'-~~ KJþ;~,Þ:·~~"1. .~:5~~tK~~ ~~~':i.ìP:1Ä~~f::~''l~~ INGREDIENT DETERGENT/DISPERSANT ENGINE DIL PACKAGE IF PRESENT IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIRÉMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION Yo (bv NT) PEL ill 10-15 Note ( 1) LUBE OIL ADDITIVE 10-15 PETROLEUM LUBE OIL CAS #: 64742-65-0 70-85 5 MG/H3 5 MG/H3 ( 2) Notes: ( 1) THIS PRODUCT CONTAINS A MAXIMUM OF 10% ZINC COMPOUNDS. ZINC CDMPOUNDS ARE REPORTABLE UNDER SECTION 313 OF SARA TITLE III 2) PELITLV IS FOR OIL MIST. ACGIH SHORT TERM EXPOSURE LIMIT (STEL) FOR OIL MIST IS 10 MG/CUM. ">,~~t~;~~.:&.Ii~~ffi{~~;;~~~b~~~~~~~~L;wiS$;~~,~;~~.~E~N~J:mI~8'H~Y~9Al£:~~AWA£:s..i::~~7t(:J..W;'i;."i!;?"'W:.tJ.~{;~~~'~~~{;)- ...~-~l!;:.£ftfrL~ _~iling Point for PRODUCT Vapor Pressure for COMPONENT( 70-85% ) 560.00 Deg F 293.33 Deg C) Q) 760.00 nun Hg < 0.10 nun Hg Q) 68.00 Deg F ( 20.00 Deg C) HEAVIER THAN AIR .879 Q) 60.00 Deg F ( 15.55 Deg C) Specific Vapor Density Specific Gravity Percent Volatiles Evaporation Rate Appearance State Form NOT APPLICABLE SLOWER THAN ETHER LIGHT AMBER LIQUID HOMOG SOLN :;;--- J.t,''''';,· '( p,,,t ;:";:,' ,;;¡":'"i: <'A,.-,.::i;-,;¡SECm.r¡O N"illN-;-:Fi:IiR E~'N Dj&8XP.J10.sHID.N;;~N EO RIM AifillO N,::,'yt'::::.. \' ~'l.' :,,': .':?,,;, -.>,,:_~ ,,:T-J;:;-' FLASH POINT(COC > 400.0 Deg F 204.4 Deg C) EXPLOSIVE LIMIT UNAVAILABLE EXTINGUISHING MEDIA: REGULAR FDAH DR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS:, CARBON DIOXIDE AND CARBDN MONOXIDE, VARIOUS HYDROCARBONS, OXIDES OF SULFUR, NITROGEN AND PHOSPHORUS, ETC. FIRE FIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACE PIECE OPERATED IN THE POSITIVE PRESSURE DEMAND HODE HHEN FIGHTING FIRES. HATER OR FDAM MAY CAUSE FROTHING HHICH CAN BE VIDLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER, ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT, BURNING LIQUID. DENSE SMOKE MAY BE GENERATED HHILE BURNING. SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE HELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. "o:pA CDDES: HEALTH- 1 FLAHHABILITY- 1 REACTIVITY- 0 CONTINUED ON PAGE: 2 72-62-7825-11 ,.f' Ya/ro/ine. v ~:~~~}s~n';_C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHlAND MATERIAL SAFETY DATA SHEET 000482 CARQUEST 5W30 Page: 2 '~+J! ,:,'¡,,~<';,;~~Ò~~,<:::':7 :~'::,/.:"·;$i:~:\:~i'¡'L,,', ", ./\~ BCmO N".~V,SH 8'AL.~,fti')HÄ:Z;A\R.D ~DÄmA:';C';{;:/',~Y",,? ,-,,~.;-: ,¡'-',:;,"i";>ß¡,'!:::',~:¡,;,;;,,::,:t;;::,,;::: ~ERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRDDUCT. SEE SECTION II. EFFECTS OF ACUTE OVEREXPOSURE: THIS PRDDUCT IS NOT HAZARDOUS AS DEFINED BY OSHA (29 CFR 1910.1200) BASED ON TESTING OF SIMILAR PRODUCTS AND/OR COMPONENTS. EYES - NOT EXPECTED TO CAUSE IRRITATION DURING NORMAL CONDITIONS OF USE. SKIN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. SHALLCHING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PROPERTIES AND MAY CAUSE NAUSEA, ABDOMINAL CRAMPS AND DIARRHEA. INHALATION - NOT EXPECTED TO BE AN INHALATION HAZARD AT NORMAL ROOM TEMPERATURE. HOWEVER, IF EXPOSURES EXCEED THE PELITLV OF 5 MGIM3 FDR OIL MIST, THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCOMFORT. FIRST AID: IF ON SKIN: THOROUGHLY HASH EXPOSED AREA HITH SOAP AND HATER. REMOVE CDNTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH HITH LARGE AMOUNTS OF HATER, LIFTING UPPER AND LDWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION, IF IRRITATION PERSISTS. IFSHALLCHED: DO NOT INDUCE VOMITING, KEEP PERSON HARM AND QUIET, AND GET MEDICAL ATTENTION. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STDPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM, QUIET AND GET MEDICAL ATTENTIDN. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNOWN FOR THE PRODUCT. CAUTION: USED MOTOR OIL HAS BEEN SHOHN TO CAUSE SKIN CANCER IN CERTAIN LABORATDRY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEATED CONTACT TO SKIN. ~4':;¡':-~bÞ::::::r~~Y;~;¡~:~~~~:'iP~~, ~~~!,¿:~·;,.f~ ~.;i.~1,i{~::-~}:~,-*~',<,,;:.:;,gsEGfr3LD N~V~liri:ä~8A"crJ}£_VÆEr~y,\~rAmA~~~~f~~;~;!~:,ç?!~J:'~;~ ·.;"·rti\~:.;r;;. \~~) 2t> 7:-:-::";~' J:~:l~ HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AYDID CONTACT HITH:, STRONG OXIDIZING AGENTS ~'f;~"\;;¡:~~;:}-;" -;·;fj:'{;;¡~;nJ;{;:.'~;~;iili:;.;*~:,i¡~ EGmTIO N -,,~VJI..q~PJLG.8~O R~EA\K~~P.iRtrrGED.u;Ri.ES):--fq, ~;!'Ìi't:],;;~',.:(f,;'%~'~?f.,:;~\.Ær:-;;;,;;<'!~;-.;'.r;~ ~TEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE SPILL: PREVENT RUN-OFF TO SEHERS2 STREAMS OR OTHER BODIES OF HATER. IF RUN-OFF OCCURS, NDTIFY PROPER AUTHORITIES AS REQUIRED, THAT A S~ILL HAS OCCURED. PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE2 DIKE AREA OF SPILL TO PREVENT SPREADING6 PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, R OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. HASTE DISPOSAL METHOD: SMALL SPILL: DISPOSE OF IN ACCORDANCE HITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE HITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. ,~)3 .¡¡-~~"i;,\, ,~,(;'!:..; ':\:i,>7.~:.fi::':i;N<~S sarmo N,~\bIrr'I~B.R:Om.EŒP.I~V.E;1.£EQ,Uæ-P;M EN ffi:$WO Æ3 E:~·m:SED.""';'-:;,:,,', ,,"1', ::!;~",;:::r':"'~c';.· ':.t¿;'-.;::t.~ RESPIRATORY PRDTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HCHEVER, IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PELITLV OF 5 MG/M36uTHEN A NIOSH/MSHA APPROVED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. (SEE Y R INDUSTRIAL HYGIENISTJ. VENTILATION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER, IF UNUSUAL OPERATING CONDITIONS EXIST, THEN PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELCH PELITLV (S). PROTECTIVE GLOVES: NOT NORMALLY REQUIRED. HOWEVER, HEAR RESISTANT GLOVES SUCH AS NITRILE RUBBER TO PREVENT IRRITATION HHICH MAY RESULT FROM PROLONGED OR REPEATED SKIN CONTACT HITH PRODUCT. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HDHEVER, IF MISTING OR SPLASHING CONDITIONS EXIST, THEN SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES ARE ADVISED. OTHER PROTECTIVE EQUIPMENT: NORMAL HaRK CLOTHING COVERING ARMS AND LEGS. 't::i.jò~'~:~·, .,. " 'b:-':::',c "': -:' ::~SEcmnO N:..··¡tB< ,,',5 P. BemA L,->~P.RE0A UmIO N Sim R~(J¡.I"H.BR:.;;æ:O M MENJiS;:¡'.'::-,'f't~: :'\:' ",::<,~ ;',~;:'?: CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS HHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT HARRANTED TO BE WHETHER ORIGINATING HITH THE CDMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. ,~"'.::-:,,~. \: '-";..: ':i::;~ ~-, :.~" ,."; : ; oj"; "~-<.,:,,,,~,.~·è'~:,:-' '1!S ECoTû¡O N;:;X~ ':'l'fA,ß EL\"€H,N 80 R M·A~P:rrO N '¿0';"~~·,,,::.,,;;-o-,:~ :':";:f' -:::~ ,'" ;'" :'""," ,': ".,:".;1',;: -:~:.:;;:~ CAUTION! MAY CAUSE SLIGHT EYE IRRITATION. CONTINUED ON PAGE: 3 72-62-7825-11 " Ya/voüne MATERIAL SAFETY DATA SHEET V ~~~~~ls~n~_C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHlAND 000482 CARQUEST 5W30 Page: 3 . ;':f!i.i: . ;'; F;'2" ." .;~ ~,.:.,,:,;{!,;:,..';.~.¡,~:t.; .:1SEC~T~IíÐ N!;'fX~GAtl3 8t:J:£IDN 177.0 R~M'A'mEOH;'i{;GGo mtåm:u;eid¡J,:·~~,;~',:·; ?' ':¡:.,:~ (t" ",":', ";', ~(o'; : " ,;: ,I: PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN DISORDERS. INHALATION OF OIL MIST MAY CAUSE RESPIRATORY IRRITATION. SHALLOHING MAY CAUSE STOMACH CRAMPS AND DIARRHEA. HANDLING & STORAGE: AVOID CONTACT HITH EYES AND SKIN. HEAR SAFETY GLASSES OR GOGGLES RESISTANT GLOVES, AND OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR YOUR OPERATION. KEEP HORKPLACÈ AIRBORNE CONCENTRATIONS BELOH LEGAL AND RECOMMENDED LIMITS. USE NIOSH-APPROVED RESPIRATOR IF EXPOSED TO OIL MIST. DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR HELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE, REVIEW MATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION, INCLUDING CHRONIC HEALTH EFFECTS. FIRST AID: EYES: FLUSH THDROUGHlY HITH HATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: HASH EXPOSED AREAS HITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY OIL MIST, REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPDSURE CURRENTLY UNKNOHN FOR THE PRODUCT. CAlTTION! USED MOTOR OIL HAS BEEN SHOHN TO CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEA TED CONTACT TO SKIN. CONTAINS: PETROLEUM all *** COMPONENTS APPEAR IN SECTION II *** LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE 7Z-62-7825-11 MATERIAL SAFETY DATA SHEET ~#' Va/vol/ne. V ~~~~~}s~n~_C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERA~ ~R GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present .a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the product. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components 5ubiect to the reportina re- auirement5 of Section 313 of SARA Title III areìdenti- fÍed in the footnotes in this section, along with ty.pical percentages. Otrer components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELs) and American Con- ference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cant.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and sl<in or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Contains label information including physical and health hazard ,!"arning5¡ handling and first aid instructions appropriate for tne product. ADDITtONAl COMMENTS Containers should be either reconditioned by CERTIFIED firms 01 properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. 'EMPTY'" drums should not be.9iven to indi- viduals. Serious accidents have resulted from the misuse of "'EMPTIED'" containers (drums, pails, etc.). Refer to Sect- ions IV and IX. MATERIAL SAFETY DATA SHEET V ~~i~~~}S~n:~C. P.O. BOX 14. LEXINGTON. KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND 72-62-7SZS-11 "Â~ Ya/vo/ine. ENVIRONMENTAL HEALTH & SAFETY DEPARTMENT Product Safety Group CARQUEST-FRESNO D.B.A. AUïO PARTS WHSLE P.O. BOX 3289 BAKERSFIELD CA 93385 ATTN: PLANT MGR / SAFETY DIR. Dear Customer: Recently, the State of California implemented the "Safe Drinking Water and Toxic Enforcement Act of 1986," commonly referred to as Proposition 65. This law requires, in part, that "No person in the course of doing business shall knowingly and intentionally expose any individual to a chemical known to the State to cause cancer or reproductive toxicity without first giving clear and reasonable warning to such individual..." (Section 25249.10). Proposition 65 assumes that cancer or reproductive toxicity will be associated with low level exposures to the listed chemical. It generally makes no distinction in the warning required for potential exposure to a trace level of a listed chemical. Valvoline, Inc. and its subsidiaries, MAC's Oil & Chemicals, Inc. and IG-LO, Inc. subscribe to the scientific position that the degree of exposure is an essential factor in health hazard determination and that the exposure to low levels of listed chemicals does not necessarily pose a hazard of cancer or reproductive toxicity. However, to qualify for an exemption from the warning requirement, Section 25249.10 states in part: Section 25249.6 shall not apply to any of the following: a. An exposure for which federal law governs warning in a manner that preempts State authority. b. An exposure that takes place less than 12 months subsequent to the listing of the chemical in question on the list required to be published under Subdivision (a) of Section 25249.8. c. An exposure for which the person responsible can show that the exposure poses no significant risk assuminQ lifetime exposure at the level in question for substances known to the State to cause cancer, and that the exposure will have no observable effect assuming exposure at one thousand (1.000) times the level in question for substances known to the State to cause reproductive toxicity based on evidence and standards of comparable scientific validity to the evidence and standards which form the scientific basis for the listing of such chemical pursuant to Subdivision (a) of Section 25249.8. Valvoline, Inc. and its subsidiaries, MAC's Oil & Chemicals, Inc. and IG-LO, Inc. manufacture and market products under numerous health, safety, and environmental regulations designed to protect health and the environment. Many of these regulations already require warnings regarding potential health hazards from certain chemicals. However, it is not yet yet clear in what specific situations additional warnings will be required in order to comply with Proposition 65. Accordingly, given this uncertainty, we are providing to our customers the following warning: WARNING Various products you purchase from us in trace amounts, contain one or more chemicals known to the , State of California to cause cancer, birth defects, or other reproductive harm. Read and follow label directions and information given on the Material Safety Data Sheets. Use care when handling any chemical product. You should advise your customers and employees of these possible hazards as is appropriate under the regulations issued pursuant to Proposition 65. If you have any questions or need additional information regarding any of these products, please call us at 1-80D-ASHLAND. A copy of this letter can be posted where these product are presented for sale in order to advise the purchaser of the hazard. 72-62-7825-11 MATERIAL SAFETY DATA SHEET Ya/yoúne. ENVIRONMENTAL HEALTH & SAFETY DEPARTMENT Product Safety Group CARQUEST-FRESNO D.B.A. AUTO PARTS WHSLE P.O. BOX 3289 BAKERSFIELD CA 93385 ATTN: PLANT MGR / SAFETY DIR. Dear Customer: v ~:~~~ls~n~~C. P.O. BOX 14000 LEXINGTON, K'ENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASH LAN 0 Enclosed are Material Safety Data Sheets (MSDS) for Valvoline products you recently purchased. These MSDSs are provided under our policy of communicating to our customers health, safety, and environmen- tal protection information necessary to ensure safe handling and use of our products and in compliance with the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard 29 CFR. 1910.1200. This information should be made available to health and safety personnel in your firm as well as to all employees handling the product(s). Significant changes in hea:th, safety, environmental or formu- lation information will be promptly forwarded to you. If you resell or distribute a Valvoline product, you are required by law to furnish a copy of the MSDS and adequate warning label for that product to your customer. We appreciate your patronage and will continue to provide quality products and service. 72-62-7825-11 VALVO LINE C. Subsidiery of Ashland Oi. nc. 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 000484 CARQUEST DEXRON THIS HSDS COMPLIES HITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx Product Name: CARQUEST DEXRON CARQUEST-BAKERSFIELD APH-BAKERSFIELD 200 SONDRA STREET D8 70 000 0866600-000 Data sheet No: 0200299-005.003 Prepared: OS/25/93 Supersedes: 02/24/93 BAKERSFIELD CA 93305 ATTN: PLANT HGR / SAFETY DIR. PRODUCT: 52015226 INVOICE: 533186 INVOICE DATE: 08/16/93 TO: :1ß ~'t1:"!i.¥%: '~8;;;~i~~¡j~·'¡';7/;~:;~:';(if,~~,1t*~f'''~Eæ~ÆO N~I$P.;RìŒaU:etr«~rro 8Nq-~EBnG'Am~O N:¡:;:±~;:W7--?c~~:,''.;'¡;-;''':.;:'~/1 :;,",?,1.t'·~r';"';\:¡¿:"';1;;;",~,\ .i;:;~ General or Generic ID: PETROLEUM BASED-LUBRICATING OIL DOT Hazard Classification: NOT REGULATED :;tt5~¡~:~~~I.~~~}~::~~ ";~~~;~~:l·~~'f~~t'~!~?i:~~~~tg;:!'.~t¡:~ eCir!ŒÐ,NftITÀh:t..:GO M BO.N BNir~~:.;:.~4ì~;~·,\t:4ç;~f:J.'k~~~?-:~~~:?~,,~~;~~~-b~¢:~:;¡;';"~'~~1 ìc~\~+~ t;~~~~~~ INGREDIENT AUTOMATIC TRANSMISSION FLUID PACKAGE IF PRESENT. IARC. NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION % (bv HT) PEL 10-25 !bY Note 1) PETROLEUM LUBE OIL CAS #: 64742-65-0 85-100 5 HG/M3 .5 HG/M3 2) Notes: ( 1) PELlTLV NOT ESTABLISHED FOR THIS MATERIAL ( 2) PELITLV IS FOR OIL MIST. ACGIH SHORT TERM EXPDSURE LIMIT (STEL) FOR OIL MIST IS 10 MG/CUM. '~Ž1iG11~;~~~K~~~~~~~t:~;;::;~r:g"'.<.,~~~t~Úp5~~~~~f~EGrriTIO Ni~P.lœSßH~Y.$Œ~Uä[)·AmA~J.~~~~it:~~~:;~~ -iGl$.~~;>~~~'W~:;"¡~t.t;$r~~1~-î;~~':.<.~~~:.!! Boiling Point for COMPONENT( 85-1007. ) > 425.00 Deg F ( 218.33 Deg C) Q) 760.00 nun Hg < 0.10 nun Hg Q) 68.00 Deg F ( 20.00 Deg C) HEAVIER THAN AIR .870 Q) 60.00 Deg F ( 15.55 Deg C) .dpor Pressure for COMPONENT ( 85-1007.) Speci fic Vapor Density Specific Gravity Percent Volatiles Evaporation Rate Appearance state Form NOT APPLICABLE SLOWER THAN ETHER RED LIQUID HOMOG SOLN .~.y,,~; ",!::,,~,,~p.';':,,-:;:'~i; ~;'in;,'¡:: ,';"~',:~S E CãæO N ;;;.liV;";;'&TR:E:"·íJA\N DN:iEX:PHOSillO N !'~I1N 60 R M'A"J:illO N"'õ,~;:,"~c'6;; '~~', ':,Ù:, ::",::;':' ,;':'·;F<o_!,"¡i~~ FLASH POINT(COC 320.0 Deg F 160.0 Deg C) EXPLDSIVE LIMIT UNAVAILABLE EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPDSITION PRODUCTS: MAY FORM TOXIC MATERIALS:. CARBON DIOXIDE AND CARBON MONOXIDE. VARIOUS HYDRDCARBONS. ETC. FIRE FIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACEPIECE OPERATED IN THE PDSITIVE PRESSURE DEMAND MODE HHEN FIGHTING FIRES. HATER OR FOAM MAY CAUSE FROTHING HHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER. ESPECIALLY IF SPRAYED INTD CDNTAINERS OF HOT, BURNING LIQUID. SPECIAL FIRE & EXPLDSION HAZARDS: NEVER USE HELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLDSIVEL Y . NFPA CODES: HEALTH- 1 FLAHMABILITY- 1 REACTIVITY- 0 ,~~::., f/~¡Ð:·'·:";\:':,;'í-;':~i;.:-:"~ """:~.-', ~r¿', >..;~"~.'",,,., ';w.S ECillnO N '~i¡.V2H 8"A l1TH"'~H'A'ZWRD'~D A~TA~-:r: <.::.i",-¡":g¿'':,,;:;~~ ,,:,'.,~'''; ,0$-,;' '"0~·~·:·<Jt,:, :"'~'~-:"r:'~ PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRDDUCT. SEE SECTION II. CONTINUED ON PAGE: 2 72-62-7825-11 ev Ya/ro/ine. MATERIAL SAFETY DATA SHEET v ~~~~~!s~n~_C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND 000484 CARQUEST DEXRON Page: 2 ~i,;':;.j~ :~¡æ;:~c;¡¡ "''{.:~':!.'~:,:, }~.;,~':"";¡;' :.....' ~ 6.DT;JiO N.rtW';;H SA l:rnH :?IHiA\ZiA~R;D,iitD·Am;A-~;'ì(~Go:n\t!i.'n·uie:'d');: ",;,.,'2, :<.: è<·,":":¡''-:~:'''';:'~'_:>', \, i~ ::.;:J; ~FFECTS OF ACUTE OVEREXPOSURE: EYES - MAY CAUSE SLIGHT IRRITATION, TEARING, OR BLURRING OF VISION. SKIN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. INHALATION - NOT EXPECTED TO BE AN INHALATION HAZARD AT NORMAL ROOM TEMPERATURE. HOWEVER, IF EXPOSURES EXCEED THE PEL/TLV OF 5 MGIM3 FOR OIL MIST, THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCOMFORT. SHALLOWING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PRDPERTIES AND MAY CAUSE NAUSEA, ABDOMINAL CRAMPS AND DIARRHEA. FIRST AID: IF ON SKIN: THOROUGHLY HASH EXPOSED AREA WITH SOAP AND HATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH WITH LARGE AMOUNTS OF HATER, LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION, IF IRRITATION PERSISTS. IF SHALLOHED: DO NOT INDUCE VOMITING, KEEP PERSON HARM AND QUIET, AND GET MEDICAL ATTENTION. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNOWN FOR THE PRODUCT. ·~OO}<{:1j;r.~:';"',~:::"~;','1'¡¡!,:';¿·~';í-;'€J':5;·.i:\·~i<::,ç.¡~·:?:,:á\ ~::./~:~ BCmnO N~~WI;;Ri8'NQ-PIMIiIW~A~T#\';::;: ;;;¥~"'Je~~;?:~å~j>,~,?;:I!:.'~' 7.1{,; p";' '/;~¡":5,::,~;'J;."'¡};-;'~ HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOID CONTACT WITH:, STRDNG OXIDIZING AGENTS $¡;·~1·µ:;,-;;)<;,,:t'~<7";~Y:;·0~,F'~,::;~:?',,~F:··£;,,;,~~ ECkTiEO N~VillI~Sf?Œili!E.~O R~eA'Q¡£R RiO:GED.uRies;*,;"-,,,·~;·;;':;'::'i'{·):--,~'~i'¡é:;'~~:§~~'~·~'ilfii STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE SPILL: PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF HATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS OCCURED. PERSDNS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE2 DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN U~ ON SAND, CLAY, EARTH, FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. ,...STE DISPOSAL METHOD: SMALL SPILL: DISPOSE OF IN ACCORDANCE HITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. ~w;.'-;::;'~":;.i~~¡';"·.~~:':$(,:,'r;c~"è:é/.¡..~ecrr!$O N ?ií!Va.mr:~"B~.OffiE~V.E..~6.Q.uillßM ENm.~Osm:BiUSBm...r~~é ,:ix';l,~;"',~ d';,:: ·â~~·'::;:'':i·t;,;,~¡,;;r.,i'! RESPIRATORY PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. VENTILATION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. PRDTECTIVE GLOVES: NOT NORMALLY REQUIRED. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIDNS OF USE. OTHER PROTECTIVE EQUIPMENT: NORMAL WORK CLOTHING COVERING ARMS AND LEGS. ~1;'1..',()\\,~"'.:'·Ti/!;-''1~;:~:~,,;"' :-... ¡'~:ftS Ec:r:..'I~O N >~FX~S'P.ECillA l::-:;BREDA UillTIO N SJ!ii.O K~Œr:H ERMGUM M 8N;r.s~; 1,' ," "'l':.;~;,~,,i' ;,....7";', '.,~ ~.~ CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTI~ GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT HARRANTED TO BE HHETHER ORIGINATING HITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. ',~:¿~;;!~" ',"'.1. '1 I. : "'A¡ ;~..;(;:';';. "·;"""i:t·'¡;~'3.F}",,~:;;:"'''¿~ECIT:ŒO N .w(~D'A¡B E:12.'~N SO R'M kTã~O N'-",:~;c;-:';-~:.:;y..'7~-:r.i··,.<;':,: ~:";/i,~~;.'i':';' ;"':, ::;'':.&\~f':::.;"'!i CAUTION! MAY CAUSE SLIGHT EYE IRRITATION. PROLONGED OR REPEATED CDNTACT MAY CAUSE SKIN DISORDERS. SHALLOWING MAY CAUSE STOMACH CRAMPS AND DIARRHEA. HANDLING & STORAGE: ~~8f~c¥~~A~~U~~~~Y~Šs~~I~I~åR ~õð~ ~~~~g~~fiŠEo~I~~~~~~O~~~I~l~~Rit8~EïF ~~~O~l~E~OAb~~Dk~!~~E DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR WELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE, REVIEW MATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION, INCLUDING CHRONIC HEALTH EFFECTS. FIRST AID: EYES: FLUSH THDROUGHLY HITH HATER. GET MEDICAL ATTENTION IF IRRITATIDN PERSISTS. CONTINUED ON PAGE: 3 72-62-7825-11 / ..~ Ya/yoüne. V~~~~~s~n.C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264·7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000484 CARQUEST DEXRON Page: 3 , ;:f:i':'~"'~~,7, ,:,;~;.. . :.;:,_;';....,' ,'..".''';;'-'''.ir.,$ Ec.TillO N;:Q('.-7:.!3A'13 EI.:!';~:mN RÐ.RM'A'iß]}O,N;'it.~Q{m:tti~",u;e.'dÐv~ >:'}~~:?i~Ji,L ",¡~t.,;..;,:tl ,«; ',":.{<;;~i":'<i"~"5 SKIN: HASH EXPOSED AREAS HITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY OIL MIST, REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPOSURE CURRENTLY UNKNOHN FOR THE PRODUCT. CONTAINS: PETROLEUM OIL *** COMPONENTS APPEAR IN SECTION II *** LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE 72-62-7825-11 " Va/voline MATERIAL SAFETY DATA SHEET V ~~~~~}s~n~.C. P.O. BOX 14ð LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERAl:- ~R GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the product. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subject to the reporting re- quirements of Section 313 of SARA Title III are Identi- fied in the footnotes in this section, along with typical percentages. Ot~er components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELs) and American Con- ference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. . SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and sKin or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTiON VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Contains label information including physical and health hazard warningshhandling and first aid instructions appropriate for t e product. ADDITIONAL COMMENTS Containers should be either reconditioned by CERTIFIED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. 'EMPTY' drums should not be ,given to indi- viduals. Serious accidents have resulted from the misuse of 'EMPTIED' containers (drums, pails, etc.). Refer to Sect- ions IV and IX. MATERIAL SAFETY. DATA SHEET V ~~;~~~}s~n~~C. P.O. BOX 14.' LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND 72-62-7825-11 ~À~ YalYoúne. 000486 CARQUEST FA THIS HSDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx Product Name: CARQUEST FA CARQUEST-BAKERSFIELD APW-BAKERSFIELD 200 SONORA STREET 08 70 000 0866600-000 Data Sheet No: 0102925-008.000 Prepared: 02/04/93 SUpersedes: 10/07/92 BAKERSFIELD CA 93305 ATTN: PLANT MGR / SAFETY DIR. PRODUCT: 52015219 INVOICE: 533186 INVOICE DATE: OB/16/93 TO: ~\-~·fl-¿f:t:~j.lt:<:';~;~·~l:~'"·~~J;'¿¿:!~i~'I?if~~~~:¡}~(~~sEffiU3naN~~~~aÐU.ŒY,.gJ,[) 8Nil:,mfiüGfA~N:iéi~f';:~~~:~~1l~~~"jt"o(~~~'v~~~A~~,.~S'~~:-ð*j*t~ General or Generic ID: PETROLEUM BASED-LUBRICATING OIL DOT Hazard Classification: NOT REGULATED ~~:·:';i:;~r~;:~.~If~:·1<~~~;~~:"f;::'';:~~'~~1;~i";~~(t::!~;~~{f.~ïf;~?;~lil{~~~~zriRO~ ~iL~ao M P~O N 8NT~J:tf~i~~ti!~:¥6~~0;;5~~;~~~-l;~~~;J¿;.:-~.::i~;·'!~1:l'~~.~. ~~\.~~;:'~¥~ INGREDIENT AUTOMATIC TRANSMISSION FLUID PACKAGE IF PRESENT IARC. NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS DF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION % (bv NT) fß 5-10 TLV Note 1) PETROLEUM LUBE OIL CAS #: 64742-65-0 85-100 5 MG/M3 5 MG/M3 2) Notes: ( 1) THIS PROPRIETARY MIXTURE CONTAINS 1. 2 % TOLUENE AND 1-5 % ZINC COMPOUNDS. TOLUENE AND ZINC CDMPOUNDS ARE REPORTABLE UNDER SECTION 313 OF SARA TITLE III. 2) PEL/TLV IS FOR OIL MIST. ACGIH SHORT TERM EXPOSURE LIMIT (STEL) FOR OIL MIST IS 10 MG/CUM. ~i;,.~r:~ti.~"i~~;;~~~~~~\;~~~;}"-<1;~7??~;:t{Š~~~t0'J.Çl.t'~;,:\:tSEeilJllO N~~eH\~smc'tÄ:~~~AWAt~~~~~1f~::~i~1';~;;~}i:?Íý~:;1~"';;';7~i';'~~$b~;§}.i~¿¡?S\~~~~:i[~~~ Roiling Point for PRODUCT ( :¡¡ 620.00 Deg F 326.66 Deg C) 760.00 nun Hg Vapor Pressure Specific Vapor Density Specific Gravity NOT APPLICABLE AIR = 1 :¡¡ ( > 1.00 .880 60.00 Deg F 15.55 Deg C) Percent Volatiles Evaporation Rate Appearance state Form NOT APPLICABLE SLOWER THAN ETHER RED CDLOR LIQUID HOMOG SOLN :fM~~i&t1~;,,~q£-;:'::':::"''F',f1 (;;'1';;:,<;; ~'.$;fo.s EGlffiiO N'¡~Ii.~~a:[;RE~A':N D:ii&X!FHiOSIDO N ,~N ~O R,M?AWillO N%r;..~,.;¡~,;",~- .!~ ,,-';,..J;it....è',;;!.fo;;~.';,,<'::.f FLASH POINT(COC 390.0 Deg F 198.9 Deg C) EXPLOSIVE LIMIT ( PRODUCT) LOWER - 1.lX EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS).z CARBON DIOXIDE AND CARBON MONOXIDE. VARIOUS HYDROCARBO,,"S. OXIDES OF SULFUR. NITROGEN AND PHOSPHORu:>, ETC. FIRE FIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE HHEN FIGHTING FIRES. HATER OR FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER. ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT. BURNING LIQUID. DENSE SMOKE MAY BE GENERATED WHILE BURNING. SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE WELDING OR CUlTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRDDUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. NFPA CODES: HEALTH- 1 FLAMMABILITY- 1 REACTIVITY- 0 CONTINUED ON PAGE: 2 MATERIAL SAFETY DATA SHEET v ~~~~~!s~n:'C. P.O, BOX 14 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (8001 274-5263 or 1-800-ASHLAND 7Z-6Z-78Z5-11 ~Âf' Ya/vo//ne 000486 CARQUEST FA Page: 2 '~G¡¡~,:,': ¡i2~: -.\Í.~;'::\3'-; .J::'; ';, ~'" ·:t't';";;':", \:..~~', ':"~;;,~,;.:",-S:>~ E.C;iRL:O N '\~VHH B'AümH;;qtHiA'Z1A'R;D~:roAm'A'~\,::";:,¡;::,;:" :],' \. ;,;:~;;,:::. ,'::",,--:c:¡>"' I,(:{, ':'~:',;',;:,,;:,;:.,,~'.~.:..{.7j ~ERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II. EFFECTS OF ACUTE OVEREXPOSURE: THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA (Z9 CFR 1910.1200) BASED ON TESTING OF SIMILAR PRODUCTS AND/OR COMPONENTS. EYES - NOT EXPECTED TO CAUSE IRRITATION DURING NORMAL CONDITIONS OF USE. SKIN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. SWALLOHING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PROPERTIES AND MAY CAUSE NAUSEA, ABDOMINAL CRAMPS AND DIARRHEA. INHALATION - NOT EXPECTED TO BE AN INHALATIDN HAZARD AT NORMAL ROOM TEMPERATURE. HOHEVER, IF EXPOSURES EXCEED THE PEL/TLV OF 5 MG/M3 FOR OIL MIST, THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCDMFORT. FIRST AID: IF ON SKIN: THOROUGHLY HASH EXPOSED AREA HITH SOAP AND HATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CDNTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH HITH LARGE AMOUNTS OF HATER, LIFTING UPPER AND LOHER LIDS OCCASIONALLY. GET MEDICAL ATTENTION, IF IRRITATION PERSISTS. IF SWALLOHED: DO NOT INDUCE VOMITING, KEEP PERSON HARM AND QUIET, AND GET MEDICAL ATTENTION. IF BREATHED: IF AFFECTEDë REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPP D GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM, QUIET AND GET MEDICAL ATTENTION. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNDHN FOR THE PRDDUCT. ~~~:;.~~~:::::~~:~,'t!?t~r~~~· ·f.~'f:.:'¿¡:.~~:.·~'~j"~;H,~3;~:::·~~~;?~;~,~::~~;;;1~ Ecrrmo N~~VITHR,B"A~aThBYwmv~~D'A»~A~;r;~?:.~;'J~ £:~~ '~~'\,,^,,~:}~~';f,-~:1$1:~~: ~~-~~:!!j:·~t~!.r:?R ~~ÿ~.tçá HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOID CONTACT HITH:, STRONG OXIDIZING AGENTS its~?~~~:~:r;.:,,~,,¡;.;;(S','if.~~i;-,;:"i-Y~f;,',.':'t';iï'¡¡l;"':¡:"~$EGimt.O-N:g;væ~Pn:H~l.f~O'R,*,.lI!BA':I~:~ßR;ae:8IlU,RE.S\f,'~t~:;;'J,:~f.è~;'*li5/~~'f,&"~,:¡~,,j:j':'~.,.3t STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. 'RGE SPILL: PREVENT RUN-OFF TO SEHERS, STREAMS OR OTHER BODIES DF HATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS OCCURED. PERSONS NOT HEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA DF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADINGÒ PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, R DTHER ABSORBENT MATERIAL AND SHDVELED INTO CDNTAINERS. HASTE DISPOSAL METHOD: SMALL SPILL: DISPOSE OF IN ACCORDANCE HITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE HITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. >!!¿;::J:¡A¡';""~,'i:"~;'!Þ~; ~,>:,!'-~"-:;;; ~.i''::~E:Cm:nO.N:",W.m:nr:;ßRUffiECrræNE~lE.Q UŒBM B~mF~O~;!J3E~U.s Em::-~~¿:~:~/'~ ;~~':1 ,;{;?~';;:~S;f.;:;.:..",: RESPIRATORY PROTECTIDN: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER, IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PEL/TLV OF 5 MG/M3. THEN A NIOSHIMSHA APPROVED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. (SEE YOUR INDUSTRIAL HYGIENIST). VENTILATION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOHEVER, IF UNUSUAL OPERATING CONDITIONS EXIST, THEN PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELCH PEL/TLV (S). PROTECTIVE GLOVES: NOT NORMALLY REQUIRED. HOHEVER, HEAR RESISTANT GLDVES SUCH AS NITRILE RUBBER TO PREVENT IRRITATION HHICH MAY RESULT FROM PROLONGED OR REPEATED SKIN CONTACT HITH PRDDUCT. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER~ IF MISTING OR SPLASHING CONDITIONS EXIST, THEN SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES ARE ADVISEu. OTHER PROTECTIVE EQUIPMENT: NORMAL HaRK CLOTHING COVERING ARMS AND LEGS. ,¡.;~~é'~\:f.4',. :;;~"'~~:<':,;;.;";~ >:;:{~ EO\TalO N-;:;mX:;;S R EGiDA t:¡tcP.RECAlJ¿TlTIO N Si1{O R,~ŒEH Ë'W;¡C:O M M EN;r,¡S,;" '.:...;;"';:':., ';.~~K~:;',:'·,:7' :y\~ CONTAINERS DF THIS MATERIAL MAY BE HAZARDOUS HHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT HARRANTED TO BE HHETHER ORIGINATING HITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATIDN IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. ';:-~' '<j7t'~',-:; ¡":,," :'~¿'" r;;:-,:¡:..:,-;,.o;. ...."-;,.,~!,.., ".~,,;.':'-:;-,;,'>:: ê~.s EOliLO N ~X' ,; IJA·B.8l:i';':ì:IiN EO RM'AifÆO N,~'ò~' :<k",,;: , :~'~. :':".'$':'_;':;'~';" .-:,.è""'> 'ò: ;;~':~<>:",;;:" i~";">,~ CAUTION! MAY CAUSE SLIGHT EYE IRRITATION. PROLONGED DR REPEATED CONTACT MAY CAUSE SKIN DISORDERS. SHALLOHING MAY CAUSE STOMACH CRAMPS AND DIARRHEA. CONTINUED ON PAGE: 3 72-62-7825-11 Ya/wi/ne. v ~:;:~~Is~n. c. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264·7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000486 CARQUEST FA Page: 3 ·'~;;,;;:r'rJ';,;:f JŽ'il:::":¡~,:;;,~",; :':',~ :" ;::.~j~ 1$ 8QT,JEO N,;1X~,illiJ\)B 81J,~IIN E'~O R:M'A,iftEO N~:>,¡O C4in:b.i."n.u:e!dll;-!.:";i~; ;'~.M(~~'h?,;r,;:.:~<"'::&"d;¡:;?7.'i'F'-";\,~ '*~ HANOLING & STORAGE: AVOID CONTACT HITH EYES AND SKIN. HEAR SAFETY GLASSES OR GOGGLES. RESISTANT GLOVES AND OTHER APPROPRIATE PROTECTIVE EGUIPMENT ESSENTIAL FOR YOUR OPERATION. USE NIOSH-APPROVEO RESPIRATOR IF EXPOSED TO OIL MIST. DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR HELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE. REVIEH MATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION. INCLUDING CHRONIC HEALTH EFFECTS. FIRST AID: EYES: FLUSH THOROUGHLY HITH HATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: HASH EXPOSED AREAS HITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY OIL MIST. REMOVE TO FRESH AIR. INGESTION: DO NDT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPOSURE CURRENTLY UNKNOWN FOR THE PRODUCT. CONTAINS: PETROLEUM OIL *** COMPONENTS APPEAR IN SECTION II *** LAST P~~E--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE 72-6Z-78Z5-11 MATERIAL SAFETY DATA SHEET rIAI' Ya/vo/ine. v ~:~~~!s~n~_C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERAl;. ~R GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the :>roduct. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subject to the reporting re- quirements of Section 313 of SARA Title III are Identi- fied in the footnotes in this section, along with ty'pical percentages. Other components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELS and American Con- ference of Governmental Industria Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposItion in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and sKin or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resuiting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIJI PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Contains label information including :>hysical and health hazard warnings, handling and first aid instructions appropriate for the product. ADDITIONAL COMMENTS Containers should be either reconditioned by CERTIFIED firms or properly disposed of by APPROVED firms. Disposal 0'( containers should be in accordance with applicable laws and regulations. 'EMPTY' drums should not be given to indi- viduals. Serious accidents have resulted from the misuse of 'EMPTIED' containers (drums. pails, etc.). Refer to Sect- ions IV and IX. MATERIAL SAFETY DATA SHEET v ~~~~~!s~n~fc. P.o. BOX 140 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND 72-62-7825-11 ~Â' IfJjvo/ine. 000483 CARQUEST HD 30 THIS MSDS COMPLIES HITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 ~xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx Product Name: CARQUEST HD 30 CARQUEST-BAKERSFIELD APH-BAKERSFIELD 200 SONORA STREET 08 70 000 0866600-000 Data Sheet No: 0178048-010.000 Prepared: 08/13/92 Supersedes: 06/04/92 BAKERSFIELD CA 93305 ATTN: PLANT HGR / SAFETY DIR. PRODUCT: 52015530 INVOICE: 533186 INVOICE DATE: 08/16/93 TO: ;:':;;'J..,,';4;:j?,¡;"';\..i~ ~;~;;;:''i'-,,:~;..;'':~::,~,z;?£;:\..:;'.:<';ij¡¡''~ EQnnONf:.~I~R{o.D U:Gm~8Nm~--ES'A'ITmO N,~~~'-iii{ij\'~,~';~~Rf.-i¡:'.~}'1¡):!Í~;~'1;'«~:.:;'f>:~ General or Generic ID: PETROLEUM BASED-LUBRICATING OIL DOT Hazard Classification: NOT REGULATED .t:0"';:~J~~;f·;~~·~~~,!!L~;::,.~<~~~"')'J~·~~~<;\~~:":;,,:~~:-;::;:'-:~~\~~~'?~E.œrmo N~$~L~:gO M P~O N 8Nffi~~~~:ßI:.~~~;:~"'~~1~r~~~~-Í-~~~1.~;~~:r;~7~~~;1ß~~;;,~::'~f~~/~?~ INGREDIENT DETERGENT/DISPERSANT ENGINE OIL PACKAGE IF PRESENT IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIRÉMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION X (bv o(f) PEL TLV 10-15 Note 1) PETROLEUM LUBE OIL CAS #: 64742-65-0 85-100 5 MG/M3 5 MG/M3 2) Notes: ( 1) THIS PRODUCT CONTAINS A MAXIMUM OF lOX ZINC CDMPOUNDS. ZINC COMPOUNDS ARE REPORTABLE UNDER SECTION 313 OF SARA TITLE III 2) PEL/TLV IS FOR OIL MIST. ACGIH SHORT TERM EXPOSURE LIMIT (STEL) FOR OIL MIST IS 10 HG/CUM. ~+~~~tJ~~~1tJÄ~;~~~:~{;:~~~t~~~é.iJ~t~Y;ij,f~,~~~?-:·¿1¡;-~?'~~~EOOI!O N~:mr~HßH~YsmGA~Ë..~lJ'AmA1if:~-£:B~~~::Ãf~~~·t~~f~~ÞP~';¿~i;';;~~q::~~~i~~~¡ ~iling Point for PRODUCT 575.00 Deg F ( 301.66 Deg C) Q). 760.00 nun Hg 0.00 mm Hg Q) .00 Deg F ( -17.77 Deg C) HEAVIER THAN AIR .890 Q) 60.00 Deg F ( 15.55 Deg C) Vapor Pressure for PRODUCT Speci fic Vapor Density Specific Gravity Percent Volatiles NDT APPLICABLE Evaporation Rate Appearance State Form SLOHER THAN ETHER LIGHT AMBER LIQUID HOMOG SOLN ~,_.. :{j:¡.;:,.,~P/~\', i,,~.~1'''·,'~ "',:?';" :"ì;,'M~S ECm:rrO N ;ÜDV-?;EŒRE~A¡N 0 ,i.i8)('P',t:!OSillO N '~FN ao RM A~T'o\DO N :~<~~'.'è:;h~~~::/-::\;"~~~i11:<.·~,<?<~,,:,;i FLASH POINT(COC 430.0 Deg F 221.1 Deg C) EXPLOSIVE LIMIT UNAVAILABLE EXTINGUISHING MEDIA: REGULAR FOAM DR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS~z CARBON DIOXIDE AND CARBON MONOXIDE. VARIOUS HYDROCARBONS, OXIDES OF SULFUR, NITROGEN AND PHOSPHORlJ:j, ETC. FIRE FIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE HHEN FIGHTING FIRES. HATER OR FOAM MAY CAUSE FROTHING HHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER. ESPECIALLY IF SPRAYED INTO CONTAINERS DF HOT. BURNING LIQUID. DENSE SMOKE MAY BE GENERATED HHILE BURNING. SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE HELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRDDUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. NFPA CODES: HEALTH- 1 FLAMMABILITY- 1 REACTIVITY- 0 CONTINUED ON PAGE: 2 72-62-7825-11 ey Ya/vo//ne. V ~~~~~ls~n.C. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHlAND MATERIAL SAFETY DATA SHEET 000483 CARQUEST HD 30 Page: 2 ~¡;:¡-!t~ '7'{¡,;;"¡,'}\;~~ê.~>~;t:' c:i·':~:W.'::?;-" :;:~::~.: ~\_, ;:;:":'~S E..Cili:TIO N-~V~H EiA'l:!ffiH;4H A:Z¡A'RiD/~D:AiliA':::':"';;5: -:_ .'. ~ ',:': ,~':"':~:. -,". .",:~ ,'1;'-::., ·.:t.:'..;i;;~,:[~~ ~ERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II. EFFECTS OF ACUTE OVEREXPOSURE: THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA (29 CFR 1910.1200) BASED ON TESTING OF SIMILAR PRODUCTS AND/OR COMPONENTS. EYES - NOT EXPECTED TO CAUSE IRRITATION DURING NORMAL CONDITIONS OF USE. SKIN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. SHALLOWING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PROPERTIES AND MAY CAUSE NAUSEA, ABDOMINAL CRAMPS AND DIARRHEA. INHALATION - NOT EXPECTED TO BE AN INHALATION HAZARD AT NORMAL ROOM TEMPERATURE. HOWEVER, IF EXPOSURES EXCEED THE PEL/TLV OF 5 MGIM3 FOR OIL MIST, THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCOMFORT. FIRST AID: IF ON SKIN: THOROUGHLY WASH EXPOSED AREA HITH SOAP AND HATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH HITH LARGE AMOUNTS OF HATER, LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION, IF IRRITATION PERSISTS. IF SWALLOHED: DO NOT INDUCE VOMITING, KEEP PERSON HARM AND qUIET, AND GET MEDICAL ATTENTION. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM, QUIET AND GET MEDICAL ATTENTION. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNOHN FOR THE PRODUCT. CAUTION: USED MOTOR OIL HAS BEEN SHOHN TO CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEATED CONTACT TO SKIN. '~·Þ:'~~~,1:,r:~:¡¿~~t~~.(~~;~5::~~;:"~f::;¿,~i~:-'~~'~:.t·,~¿;'; ;;3f::'~T;i,~:\r~}'~-).~~S E.aJmQ.N~it~Vrr.SR,BAJcmríVillt~Y:f~D 'A~~A~;"'~:;l~J~~~'":;~:Þ~ ~··...."8!i!¿:·;·,µ:3J ·::~!:::Y'f. ~1.J~:t.;,'~:~ ~::! '<~~""'l";01¿ HAZARDDUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOID CDNTACT HITH:, STRONG OXIDIZING AGENTS ~;¡¡~'¡~1:'1W:~~iì!,¡J-~"'f'.£?:i7{,;-:;'2.:~¿'(·,"';;;:~N:1;5~SErn:J;ID.O N'!iVt~~':;;iQR:~8Ä~BR'D'.eEÐ,U¡R.E~S;~:£;FÍ,J,:"'';:i·~·~'¥~!fu:~¿i~~~ß':;;;~;'~j~·G:Tiff. ~TEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT DR OTHER ABSORBENT MATERIAL. LARGE SPILL: PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF HATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS OCCURED. PERSONS NOT HEARING PROTECTIVE EqUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING6 PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, R OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. HASTE DISPOSAL METHOD: SMALL SPILL: DISPOSE OF IN ACCORDANCE HITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE HITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. ~¡:b "i;!; ~~;~';f~'.$:;;'fY::~f~~\:::' ,':;¡~~.;:~:"!S 8C.:ræO N:~VmIrr.~R;O:5f<EG'itffiv.Ef~Q.UmßM 8N'i[(~O~ S¡:¡'US8D';"?.:.'!'" :-~ ;?" ~,,;-, 1: :.:,¿:.~,,>y,t~ RESPIRATORY PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOHEVER, IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PELITLV OF 5 MG1M3, THEN A NIOSH/MSHA APPROVED RESPIRATOR IS ADVISED IN ABSENCE OF PRDPER ENVIRONMENTAL CONTROL. (SEE YOUR INDUSTRIAL HYGIENISTJ. VENTILATION: NOT REQUIRED UNDER NORMAL CONDITIONS DF USE. HOHEVER, IF UNUSUAL OPERATING CONDITIONS EXIST, THEN PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOH PEL/TLV (S). PROTECTIVE GLOVES: NOT NORMALLY REQUIRED. HOWEVER, WEAR RESISTANT GLOVES SUCH AS NITRILE RUBBER TO PREVENT IRRITATION HHICH MAY RESULT FROM PROLONGED OR REPEATED SKIN CONTACT HITH PRODUCT. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER6 IF MISTING OR SPLASHING CONDITIONS EXIST, THEN SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES ARE ADVISE . OTHER PROTECTIVE EQUIPMENT: NORMAL HeRK CLOTHING COVERING ARMS AND LEGS. ~i:,(,;,\(;~j:,;::"\i ,~~.:r.'"'~"~"~",,'~:':C..~ EGT,TIO N '..~;LX ,":SP..EClliA't~¿'fßRE.OA U'ŒŒO NS'~O R~O'I-H ER¡f¡iCO MM EN;ijS;,7-':'« ,:- ".:,'-' ",~,-,:", J~,- _''',"..:,},; CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS HHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT HARRANTED TO BE HHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TD THEIR CIRCUMSTANCES. f,~" ,;;,':~" ",:..f'.-,i'i : :;ù",~",,:{. '~J¡, ;:;, :":, ~..;.~\ :c:_~ ~";~S ECIT;illO N ~lX,~l:'ìAìB Eti,¿;U<N 60 RMA}T~EO N'0~,';K"';O":'.~"'- _","",,;l, ,.,,¡,;Ç-'~''':)f;:-:."',c;':';,'',,:c,-''';,::: 73',~ CAUTION! MAY CAUSE SLIGHT EYE IRRITATION. CONTINUED ON PAGE: 3 MATERIAL SAFETY DATA SHEET v ~:~~~!s~n~:..I...~ c. P.O. BOX 14_ lEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (8001 274-5263 or 1-800-ASHLAND 12-62-7825-11 ...~ J1J/vo//ne. 000483 CARQUEST HD 30 Page: 3 :r~,"'~, I~ ¡,,;' ':::.'.,;,:¡ ~~,';'·;·h'/#}':"".;,.,'::~SECTI"illO N'."X~l!;A(B,E:L;"¡;r<N9.0 R:M~TœO N,-;:S:Geo n~~:ù:e,\(D4.:·.~¡]";,:,,/,·o:'~;";'~;";~ ,'t:~ ,:;é' -;';:,-10;;,";.:~":',-~ PROLONGED OR REPEATED CONTACT HAY CAUSE SKIN DISORDERS. INHALATION OF OIL MIST HAY CAUSE RESPIRATORY IRRITATION. SHALLOHING MAY CAUSE STOMACH CRAMPS AND DIARRHEA. HANDLING & STORAGE: ~~gfgcf~~A~¡u~~~~NfY~Šs~~¥I~I~ÖR ~õð~ ~~~~ItIg~~ssR~E~RHg~~~~Ä~E ~ï~ã~~~~cg~g~~RA~~gNgT~~~o~pr~g~EI~õ RECOMMENDED LIMITS. USE NIOSH-APPROVED RESPIRATOR IF EXPOSED TO OIL MIST. DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR HELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE, REVIEH HATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION, INCLUDING CHRONIC HEALTH EFFECTS. FIRST AID: EYES: FLUSH THOROUGHLY HITH HATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: HASH EXPOSED AREAS HITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY DIL MIST, REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPOSURE CURRENTLY UNKNOHN FOR THE PRODUCT. CAUTION! USED MOTOR DIL HAS BEEN SHOHN TO CAUSE SKIN CANCER IN CERTAIN LABORATORY ANIMALS CONTINUALLY EXPOSED TO USED MOTOR OIL BY REPEATED APPLICATIONS. AVOID PROLONGED OR REPEA TED CONTACT TO SKIN. CONTAINS: PETROLEUM OIL *** COMPONENTS APPEAR IN SECTION II *** LAST PAGE--SEE ATTACH~ENT PAGE ENCLOSED--LAST PAGE 72-6Z-78Z5-11 ~ÂfV Ya/yoÜOe. MATERIAL SAFETY DATA SHEET v ~~~~~!s~nE6~ c. P.O. BOX 1. LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERAl:- ~R GENERIC ID: Chemical family or product descnptlon. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the product. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subject to the reporting re- quirements of Section 313 of SARA Title III are Identi- fied in the footnotes in this section, along with ty.pical percentages. Other components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELs! and American Con- ference of Governmental Industria Hygienists (ACGIH) Threshold Limit Values (TLV5) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER"" 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and sKin or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Contains label information including physical and health hazard warnings, handling and first aid instructions appropriate for the product. ADDITIONAL COMMENTS Containers should be either reconditioned by CERTIFIED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. 'EMPTY' drums should not be .Qiven to indi- viduals. Serious accidents have resulted from the misuse of 'EMPTIED' containers (drums, pails, etc.). Refer to Sect- ions IV and IX. . 72-62-7825-11 MATERIAL SAFETY DATA SHEET Jf¡/yoline. v ~~~~~!<~n~_C. P.o. BOX 14.' LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-80Q-ASHLAND ENVIRONMENTAL HEALTH & SAFETY DEPARTMENT Product Safety Group CARQUEST-FRESNO D.B.A. AUTO PARTS WHSLE P.O. BOX 3289 08 70 000 0888950-000 BAKERSFIELD CA 93385 ATTN: PLANT MGR / SAFETY DIR. Dear Customer: Recently, the State of California implemented the "Safe Drinking Water and Toxic Enforcement Act of 1986," commonly referred to as Proposition 65. This law requires, in part, that "No person in the course of doing business shall knowingly and intentionally expose any individual to a chemical known to the State to cause cancer or reproductive toxicity without first giving cfear and reasonable warning to such individual..." (Section 25249.10). Proposition 65 assumes that cancer or reproductive toxicity will be associated with low level expo~)Ures to the listed chemical. It generally makes no distinction in the warning required for potential exposure to a trace level of a listed chemical. Valvoline, Inc. and its subsidiaries, MAC's Oil & Chemicals, Inc. and IG-LO, Inc. subscribe to the scientific position that the degree of exposure is an essential factor in health hazard determination and that the exposure to low levels of listed chemicals does not necessarily pose a hazard of cancer or reproductive toxicity. However, to qualify for an exemption from the warning requirement, Section 25249.10 states in part: Section 25249.6 shall not apply to any of the following: a. An exposure for which federal law governs warning in a manner that preempts State authority. b. An exposure that takes place less than 12 months subsequent to the listing of the chemical in question on the list required to be published under Subdivision (a) of Section 25249.8. c. An exposure for which the person responsible can show that the exposure poses no significant risk assuming lifetime exposure at the level in question for substances known to the State to cause cancer, and that the exposure will have no observable effect assuming exposure at one thousand (1,000) times the level in question for substances known to the State to cause reproductive toxicity based on evidence and standards of comparable scientific validity to the evidence and standards which form the scientific basis for the listing of such chemical pursuant to Subdivision (a) of Section 25249.8. Valvoline, Inc. and its subsidiaries, MAC's Oil & Chemicals, Inc. and IG-LO, Inc. manufacture and market products under numerous health, safety, and environmental regulations designed to protect health and the environment. Many of these regulations already require warnings regarding potential health hazards from certain chemicals. However, it is not yet yet cfear in what specific situations additional warnings will be required in order to comply with Proposition 65. Accordingly, given this uncertainty, we are providing to our customers the following warning: WARNING Various products you purchase from us in trace amounts, contain one or more chemicals known to the State of California to cause cancer, birth defects, or other reproduCtive harm. Read and follow label directions and information given on the Material Safety Data Sheets. Use care when handling any chemical product. You should advise your customers and employees of these possible hazards as is appropriate under the regulations issued pursuant to Proposition 65. If you have any questions or need additional information regarding any of these products, please call us at 1-80Q-ASHLAND. A copy of this letter can be posted where these product are presented for sale in order to advise the purchaser of the hazard. 72-62-7825-11 ~. Ya/vo//ne. v ~:i~~~}S~n~~C. P.O. BOX 14.' LEXINGTON, KENTUCKY 40512 (606) 264-7000 24 hour Emergency Telephone 1 (8001274-5263 or 1-800-ASH LAN D MATERIAL SAFETY DATA SHEET ENVIRONMENTAL HEALTH & SAFETY DEPARTMENT Product Safety Group CARQUEST-FRESNO D.B.A. AUTO PARTS WHSLE P.O. BOX 3289 08 70 000 0888950-000 BAKERSFIELD CA 93385 ATTN: PLANT MGR / SAFETY DIR. Dear Customer: Enclosed are Material Safety Data Sheets (MSDS) for Valvoline products you recently purchased. These MSDSs are provided under our policy of communicating to our customers health, safety, and environmen- tal protection information necessary to ensure safe handling and use of our products and in compliance with the Occupational Safety and Health Administration (OSHA) Hazard Communication Standard 29 CFR. 1910.1200. This information should be made available to health and safety personnel in your firm as well as to all employees handling the product(s). Significant changes in health, safety, environmental or formu- lation information will be promptly forwarded to you. If you resell or distribute a Valvoline product, you are required by law to furnish a copy of the MSDS and adequate warning label for that product to your customer. We appreciate your patronage and will continue to provide quality products and service. 72-62-7825-11 MATERIAL SAFETY DATA SHEET Ya/vo/ine. VALVO LINE, INC. Subsidiary of Ashland .' P.O. BOX 14. LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASH LAN D 000847 CARQUEST 15046 THIS MSDS COMPLIES HITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx x Product Name: CARQUEST IS046 CARQUEST-FRESNO D.B.A. AUTO PARTS HHSLE P.O. BOX 3289 08 70 000 0888950-000 Data Sheet No: 0067073-007.000 Prepared: 08/13/92 Supersedes: 05/02/90 BAKERSFIELD CA 93385 ATTN: PLANT MGR / SAFETY DIR. _~"1~.fj~~,-l~telJ£tJYrHé~_ General or Generic ID: PETROLEUM BASED-LUBRICATING OIL DOT Hazard Classification: NOT REGULATED PRODUCT: 52015200 INVOICE: 497325 INVOICE DATE: 06/08/93 TO: AUTO PARTS HHOLESALE 2324 S. BARTON AVE. '¥ì~};'.::{.,~i~!e,)¡:1~Q§¡~~~¡)'~"[ii:E>:~¡f;,;}~;Wii~%:'~~::~~~~~;~~8G.LmON:;;tD~cm,M p':ON,8NmSi~~;;"i~:l~~~;'J;f.':f;7:1~:~¿:Jø;;iÍ'i¿,Š~,1i;';Ií:'5.'i;;~;;.'(;\1if.tiï":"~$I INGREDIENT PETROLEUM LUBE OIL CAS #: 64742-65-0 IF PRESENT, IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION Y. (bv VOU ill 85-100 5 MG/M3 I!:Y 5 MG/M3 Note (1) Notes: ( 1) PEL/TLV IS FOR OIL MIST. ACGIH SHORT TERM EXPOSURE LIMIT (STEU FOR OIL MIST IS 10 MG/CUM. :§t~~i~'$:r..t·~';,Y{¡}:'J}:þ',,~'t.~c;':¡.W:\~~:~r.~lli:.~:;...-rt'J¡,~~:$í~,~EcmmQN~IIDr-daH\Y:SIT1eA1r;¡,~'A-q-fAtow:.;;t~!f,:Ä'tJ.1i,~i!Ìi~~~t"¿:'¥.i;.--#f3.f,~,¡~,,;,t\t~\f~<ii&i' Boiling Point for PRODUCT Vapor Pressure for COMPONENT ( 25-40Y. ) > 425.00 Deg F ( 218.33 Deg C) ~ 760.00 mm Hg < 0.10 mm Hg ~ 68.00 Deg F ( 20.00 Deg C) HEAVIER THAN AIR .887 Q) 60.00 Deg F ( 15.55 Deg C) acific Vapor Density Specific Gravity Percent Volatiles Evaporation Rate Appearance state Form NDT APPLICABLE SLOHER THAN ETHER UNKNOI'IN LIQUID HOMOG SOLN ~.,¡¡,,~~r.'j';!? )~';;, ';~'~'i;;:,,~..8;, b¡¡:[~?,:,¡S EŒTÆO N,:Æ1W:;':RLR<EE;'¡;A-N D<-~BX ßL;:ŒSmo N~~N 60 RiM'AmEO N,\;9::~:,'i;\~;;j,;)<~~;Xv;,';':¡:;;>'V ~:t+:::~~.;o FLASH POINT 405.0 Deg F 207.2 Deg C) EXPLOSIVE LIMIT UNAVAILABLE EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: HAY FORM TOXIC MATERIALS:, CARBON DIOXIDE AND CARBON MONOXIDE, OXIDES OF SULFUR, NITRDGEN AND PHOSPHORUS, ETC. FIRE FIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE HHEN FIGHTING FIRES. HATER OR FOAM MAY CAUSE FROTHING HHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER, ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT, BURNING LIQUID. DENSE SMOKE MAY BE GENERATED HHILE BURNING. SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE HELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. NFPA CODES: HEALTH- 1 FLAHMABILITY- 1 REACTIVITY- 0 ·:J:kr.\t~';t.¡.:h';¥..yJ,: !~!-<~:~;,.::r.;'~;¡\ .";'(~ ':':¡:;:~ ;;i:;i¡-:; l,",;/ets EcmI¡O Ni'~Vft':H EiAl!mHÏi.ífH'A~zjt>;.,R!.Df>W'Ä~JÄ'f1i-:~;?~:;f'j¡~''%;;::!'t1'~;~:;:~í,.ft~.'Þ;'1:Æ·i;''-,;'!J;~';j''.:~¥'jft. PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II. EFFECTS OF ACUTE OVEREXPOSURE: THIS PRODUCT IS NOT HAZARDDUS AS DEFINED BY OSHA (29 CFR 1910.1200) BASED ON TESTING OF SIMILAR PRODUCTS AND/OR C~P~ENTS. ' :S - NOT EXPECTED TO CAUSE IRRITATION DURING NORMAL CONDITIONS OF USE. ,.IN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. CONTINUED ON PAGE: 2 7Z-62-7825-11 MATERIAL SAFETY DATA SHEET Ya/yoüne. v ~~~~~}s~n~J.N C. P.O. BOX 14_ LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-80Q-ASHLAND 000847 CARQUEST IS046 Page: 2 ]f If) SHALLOWING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PROPERTIES AND MAY CAUSE NAUSEA, ABDOMINAL CRAMPS AND DIARRHEA. INHALATION - NOT EXPECTED TO BE AN INHALATION HAZARD AT NORMAL ROOM TEMPERATURE. HOWEVER, IF EXPOSURES EXCEED THE PELITLV OF 5 MG/M3 FOR DIL MIST, THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCOMFORT. FIRST AID: IF ON SKIN: THOROUGHLY WASH EXPOSED AREA HITH SOAP AND HATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH HITH LARGE AMOUNTS OF HATER, LIFTING UPPER AND LOHER LIDS OCCASIONALLY. GET MEDICAL ATTENTION, IF IRRITATION PERSISTS. IF SHALLOHED: DO NOT INDUCE VOMITING, KEEP PERSON HARM AND QUIET, AND GET MEDICAL ATTENTION. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM, QUIET AND GET MEDICAL ATTENTION. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNOHN FOR THE PRODUCT. .:.";;{~-i;f.iØ;§!!,:J.~~.:~~'~i5'?;?i¡}'~r,;.",'¡;'éW;¡Ó~~~!\,~!<~€!5;<l~~i~~ E!6itmO N~VrroRReA:GffiI~VmnY~rrA\~A4~·ì:'0~&.;-y~ti{of:'!.¥;;;;;~.';;Y,,,ç ;@."~';ài$-~~~i HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOID CONTACT HITH:, STRONG OXIDIZING AGENTS :1'-µ'·~~}>;~iì-f~";·'~""'~!:'¥Y·:~:S~·'''~f',,~;·\~~:~SEœ:mO N~~WGLBSPmI!LS,'ijO ~lli.BA K:!:~R;O.eBD U RES1~~;~¡./?~f;}i"'~¡';3·,.¡1..~{~,~!~ti;~~·.ø.\,:'!.-,g~ STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE SPILL: PREVENT RUN-OFF TO SEHERS, STREAMS OR OTHER BODIES OF HATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS DCCURED. PERSONS NDT HEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING, PUMP LIQUID TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLODR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. 3TE DISPOSAL METHOD: SMALL SPILL: DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE HITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. ;;?:":;f;~,;l~.{~~"h£,i;'ií:~t:;'~~:~'(,rl{i'¿S''¡¡S BOTOO N~VmD~aRtOmEGil!Ij¡\f.E~umRMENID~O¡m,E~UiS8D:~~r:6:;i.;t!~:';!i!!;¡';''¥~;';¡:.:~"'4:%-.':':':{:f'¡' RESPIRATORY PROTECTIDN: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER, IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PEL/TLV OF 5 MG/M3, THEN A NIOSH/MSHA APPROVED RESPIRATOR IS ADVISED IN ABSENCE OF PRDPER ENVIRONMENTAL CONTROL. (SEE YOUR INDUSTRIAL HYGIENIST). VENTILATION: NOT REQUIRED UNDER NORMAL CONDITIONS DF USE. HOWEVER, IF UNUSUAL OPERATING CONDITIONS EXIST, THEN PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW PELITLV (S). PROTECTIVE GLOVES: NOT NORMALLY REQUIRED. HOWEVER, WEAR RESISTANT GLOVES SUCH AS NITRILE RUBBER TO PREVENT IRRITATION HHICH MAY RESULT FROM PROLONGED OR REPEATED SKIN CONTACT WITH PRDDUCT. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOHEVER, IF MISTING OR SPLASHING CONDITIONS EXIST, THEN SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES ARE ADVISED. OTHER PROTECTIVE EQUIPMENT: NORMAL HORK CLOTHING COVERING ARMS AND LEGS. íI;t,: ,"iì:;-;1~\"/':C:0' ;,'f.:"":;~.';;\\,,,,;;SEC:TŒO WIU:X: :.:SREarA:L:¿'-;PREaA llTIIDO N ~'~O Rf~:OmH ER:N',C,O M M ENmS~·;, :vf":";;:~',:,~ ")~',-,:c;" :~'::':~~." CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/DR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT WARRANTED TO BE HHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. ~:&'i:(¡f.:r.;W';""t£;¡<¡'kt,~1',;.o,:;~ ,:: '~:f' \ ';';';'&;':'$i~:i:f,,<·'\'~,~;-t;':;SE&nEO N~X~üA:B Ebj:'~EN 8.0 RiM>ATI".mO N~:{'J'fP"~;¡!::;~~'\'!.:~¡':<~,f!,"¡""'~{:;'/,~"",:'·fÍ'J~;',~::"il";~f:.~~:::f. CAUTION! MAY CAUSE SLIGHT EYE IRRITATION. PRDLONGED OR REPEATED CDNTACT MAY CAUSE SKIN DISORDERS. SHALLOHING MAY CAUSE STOMACH CRAMPS AND DIARRHEA. HANDLING & STORAGE: AVOID CONTACT HITH EYES AND SKIN. HEAR SAFETY GLASSES OR GOGGLES, RESISTANT GLOVES AND OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR YOUR OPERATION. USE NIOSH-APPROVED RESPIRATOR IF EXPOSED TO OIL MIST. DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR WELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE, REVIEH MATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION, INCLUDING CHRONIC HEALTH EFFECTS. CONTINUED ON PAGE: 3 72-62-7825-11 VALVOLlNE, INC. Subsidiary of AShland&::. P.O. BOX 1__ LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000847 CARQUEST 1S046 Page: 3 4ïïmß(i~ FIRST AID: EYES: FLUSH THOROUGHLY HITH HATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: HASH EXPOSED AREAS HITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY OIL MIST, REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPOSURE CURRENTLY UNKNOHN FOR THE PRODUCT. CONTAINS: PETROLEUM OIL (GREASE) *** COMPONENTS APPEAR IN SECTION II *** ------... -. ---- ------ LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE 72-62-7825-11 flit. Ya/vo/ine. MATERIAL SAFETY DATA SHEET VALVOLlNE, INC. Subsidiary of Ashland A. P.O. BOX 14. LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour . Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERA~ qR GENERIC ID: Chemical family or product description. DOT.HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the product. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subject to the reporting re- quirements of Section 313 of SARA Title III are Identi- fied in the footnotes in this section, along with ty'pical percentages. Other components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELs) and American Con- ference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and sKin or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dlingthe product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Contains label information including "hysical and health hazard warnings, handling and first aid instructions appropriate for the product. ADDITIONAL COMMENTS Containers should be either reconditioned by CERTIFIED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. "EMPTY" drums should not be given to indi- viduals. Serious accidents have resulted from the misuse of "EMPTIED" containers (drums, pails, etc.). Refer to Sect- ions IV and IX. 72-62-7825-11 Yalvobñe. V ~~~~~}s~n~~C. P.O. BOX 14. LEXINGTON, KENTUCKY 40512 (606) 264·7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-80Q-ASHLAND MATERIAL SAFETY DATA SHEET 000848 CARQUEST IS032 THIS MSDS COMPLIES WITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) Page: 1 KXXXXXXXXXXKXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXXxxxx Product Name: CARQUEST IS032 CARQUEST-FRESNO D.B.A. AUTO PARTS WHSLE P.O. BDX 3289 08 70 000 0888950-000 Data Sheet No: 0074103-007.000 Prepared: 08/13/92 Supersedes: 04/27/90 PRODUCT: 52015500 INVOICE: 497325 INVOICE DATE: 06/08/93 TO: AUTO PARTS WHOLESALE 2324 S. BARTON AVE. ATTN: PLANT MGR I SAFETY DIR. ~~~~~~nl]mIiiUi;N~D}'~\"~r1!é_ General or Generic ID: PETROLEUM BASED-LUBRICATING OIL DDT Hazard Classification: NOT REGULATED BAKERSFIELD CA 93385 ~~~4.~~,~~¡$}..,e;¡1¿;,.~':iz.¥$1B;:~k:;~~:%J:.'.F:,';;<;:;;:'.!¡,t;Ä"~ EQ.T.illaN~Itr~ao.M PiO N 8Nffi~~i;~~~;]!¡.:1¡\\-[;i$¿~~{;f,'!ú~~~?,i:'ii]~a;:krJ.it~~'ir~W";%® INGREDIENT PETROLEUM LUBE OIL CAS #: 64742-65-0 IF PRESENT, IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEE DEFINITION PAGE FOR CLARIFICATION % (bv VOl) ill 85-100 5 MGIM3 TLV 5 MGIM3 Note ( 1) Notes: ( 1) PElITLV IS FOR OIL MIST. ACGIH SHORT TERM EXPOSURE LIMIT (STEL) FOR OIL MIST IS 10 MG/CUM. .~r:~}~~;t~r;;¡~~t::~~~~.~?k~~;@itt~~¡~J~.:;-'~~~/~¿~~:?~\~SEiCffiŒaN~~BH~V:smGfA~ llitMD·A~l1A:>~:r,:li1~~~.f~;~~~~~i:.st;~?1;ìfi~~~~{~~~t!~~1i);~G;~·t~~?;~~h'; Boiling Point for PRODUCT Vapor Pressure for COMPONENT ( 85-100%) > 425.00 Deg F ( 218.33 Deg C) Q) 760.00 mrn Hg < 0.10 mrn Hg Q) 68.00 Deg F ( 20.00 Deg C) HEAVIER THAN AIR .873 Q) 60.00 Deg F ( 15.55 Deg C) acific Vapor Density Specific Gravity Percent Volatiles Evaporation Rate Appearance state Form NOT APPLICABLE SLOWER THAN ETHER UNKNOHN LIQUID HOMOG SOLN ~t.;4~;¡';~ ~.~'~:";~"/. ~\ ~~l'_~'t-;:~\'.;q,:~ ,-ii!SEC"TŒONí;~:ÚV~F.WR.E~;JA'N D..~~ BIffi:-SillO N;éwN 6;aRiM'AmI:O:N~,,;, ~«,;':;.;i;¡,<~,\;;'::"','~',,:, , t~,~,::-~;~;¡ :;;i~~, FLASH POINT 400.0 Deg F 204.4 Deg C) EXPLOSIVE LIHIT UNAVAILABLE EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS.:..! CARBON DIOXIDE AND CARBON MONOXIDE. VARIOUS HYDROCARBONS. OXIDES OF SULFUR. NITROGEN AND PHOSPHOR~, ETC. FIRE FIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING FIRES. HATER OR FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT AND POSSIBLY ENDANGER THE LIFE OF THE FIREFIGHTER. ESPECIALLY IF SPRAYED INTO CONTAINERS OF HOT. BURNING LIQUID. DENSE SMOKE MAY BE GENERATED HHILE BURNING. SPECIAL FIRE & EXPLOSION HAZARDS: NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE PRDDUCT (EVEN JUST RESIDUE) CAN IGNITE EXPLOSIVELY. NFPA CDDES: HEALTH- 1 FLAMMABILITY- 1 REACTIVITY- 0 ,t;iJ)(.;l'¿'''à;V:'''''ë~';'::i?';¿':'J¡...'!i''~';".!;'ii:::.~'S¡:.;:¡;' ::.'!'\;~:.;: ~~:;t$'E.Gm.nÐ N~V~H,BA\l§ijH~;A'ZiARID~'!IJÄÎiT~'Af:'y%~t;':;"~~~?"{~.t~#~~~ì~'i';:;;.':i¿\!.~;.~'t~;;);{;"1i~-::~.; PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT. SEE SECTION II. EFFECTS OF ACUTE OVEREXPOSURE: THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY OSHA (29 CFR 1910.1200) BASED ON TESTING OF SIMILAR PRODUCTS ANDIOR COMPONENTS. :S - NOT EXPECTED TD CAUSE IRRITATION DURING NORMAL CONDITIONS OF USE. ,.IN - PROLONGED OR REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE DERMATITIS. CONTINUED ON PAGE: 2 72-62-7825-11 V ~~~~~ls~n~_C. P.O. BOX 140'1" LEXINGTON, KENTUCKY 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND MATERIAL SAFETY DATA SHEET 000848 CARQUEST 15032 Page: 2 ~~ SHALLOWING - NOT EXPECTED TO BE TOXIC BY INGESTION. PRODUCT HAS LAXATIVE PROPERTIES AND MAY CAUSE NAUSEA, ABDOMINAL CRAMPS AND DIARRHEA. INHALATION - NOT EXPECTED TO BE AN INHALATION HAZARD AT NORMAL ROOM TEMPERATURE. HOWEVER, IF EXPOSURES EXCEED THE PEL/TLV OF 5 MG/M3 FOR OIL MIST, THEN INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND POSSIBLE DISCOMFORT. FIRST AID: IF ON SKIN: THOROUGHLY WASH EXPOSED AREA HITH SOAP AND HATER. REMOVE CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH HITH LARGE AMOUNTS OF HATER, LIFTING UPPER AND LOWER LIDS OCCASIONALLY. GET MEDICAL ATTENTION, IF IRRITATION PERSISTS. IF SWALLOWED: DO NDT INDUCE VOMITING, KEEP PERSON HARM AND QUIET, AND GET MEDICAL ATTENTION. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM, QUIET AND GET MEDICAL ATTENTION. EFFECTS OF CHRONIC OVEREXPOSURE: NONE CURRENTLY KNOWN FOR THE PRODUCT. ~A:;-:f~!f~::-·;::-,::,..!~,·;,}.\'~¡~~t';,r,~~L';,~:t'¡<?~~'::,\~',tá1it(!~BQ"BIiaNf!f.VfL~R;sNcæmwmwt~D"AWA~'i>ï~<;~"'j;¿~~!;i;i,~~~';f~;;~·1\:;t.<";,~~~~~-,,"i~¡.~S; HAZARDOUS POLYMERIZATION: CANNOT OCCUR STABILITY: STABLE INCOMPATIBILITY: AVOID CDNTACT HITH:, STRONG OXIDIZING AGENTS ~1?1j.?~'¡'~~_;,'~ ;:',>:~-:;·f5>:i;~:":;*,~.ìi'~t~ii:f:"~S EŒTŒO N ,~V$r~.sRm~[;;~OR..~8A;K~p.Im;Genl1iÆes~{~'Wr.í1.:';'¡ }j?1:;~·~~~~i~,?'~~~~~'(:Þ,j8f.; STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL. LARGE SPILL: PREVENT RUN-OFF TO SEHERS, STREAMS OR OTHER BODIES OF HATER. IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS REQUIRED, THAT A SPILL HAS DCCURED. PERSONS NOT HEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING6 PUMP LIQUID TO SALVAGE TANK. . REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORBENT, R OTHER ABSORBENT MATERIAL AND SHOVELED INTO CONTAINERS. 3TE DISPOSAL METHOD: SMALL SPILL: DISPOSE OF IN ACCDRDANCE HITH ALL LOCAL, STATE AND FEDERAL REGULATIONS. LARGE SPILL: DISPOSE OF IN ACCORDANCE HITH ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. _=:IIØ~«'~'AØw=i>~'~~=1:~i-,r,\'_I~~='~ RESPIRATORY PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER, IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PEL/TLV OF 5 MG/M36 THEN A NIOSH/MSHA APPROVED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. (SEE Y UR INDUSTRIAL HYGIENIST). VENTILATION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOWEVER, IF UNUSUAL OPERATING CONDITIONS EXIST, THEN PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW PEL/TLV (S). PROTECTIVE GLOVES: NOT NORMALLY REQUIRED. HOWEVER, WEAR RESISTANT GLOVES SUCH AS NITRILE RUBBER TO PREVENT IRRITATION HHICH MAY RESULT FROM PROLONGED OR REPEATED SKIN CONTACT HITH PRODUCT. EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. HOHEVER1 IF MISTING OR SPLASHING CONDITIONS EXIST, THEN SAFETY GLASSES OR CHEMICAL SPLASH GOGGLES ARE ADVISEu. OTHER PROTECTIVE EQUIPMENT: NORMAL HORK CLOTHING COVERING ARMS AND LEGS. '¡;:;,",,-::;~"'" ;\fc c'f·'é~:.I'~:~? ~7¡f~~S ECrr:'Î'f.O N\'i.WX::S PEcmA t1~~ RECWUffino NS't,iO R~~omH ER¡"i!G.O M'M ENm~t\'·, :",~-6~~·ç~~~!:-;~¿:~".ïJ;~,~':- CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS HHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT HARRANTED TO BE HHETHER ORIGINATING HITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. ,;j£f·),:'L.If;·~·;'} (: ~:~',~~\¡:: "~":;"'<':;'¡~'*'~'t1:~·;".;_,.~ ·G,;,- ~f1'~;äS EaT;$aN'~)(E8íA'B,8t:k1;]N @O 1t1'M\1WO N¿~?~~~r.' ¡r.,~?\.-¡¡~J<:"'~'-':;:¡i!{?-i;fJf:.;->??g~Fr:r$::~~¡.;-'-i"-~~~~ CAUTION! HAY CAUSE SLIGHT EYE IRRITATION. PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN DISORDERS. SHALLOHING MAY CAUSE STOMACH CRAMPS AND DIARRHEA. HANDLING & STORAGE: AVOID CONTACT HITH EYES AND SKIN. HEAR SAFETY GLASSES OR GOGGLES, RESISTANT GLOVES AND OTHER APPROPRIATE PROTECTIVE EQUIPMENT ESSENTIAL FOR YOUR OPERATION. USE NIOSH-APPROVED RESPIRATOR IF EXPOSED TO OIL MIST. DO NOT TRANSFER TO UNLABELED CONTAINER. DO NOT USE CUTTING OR HELDING TORCH ON THIS CONTAINER (EVEN EMPTY). BEFORE USE, REVIEW MATERIAL SAFETY DATA SHEET FOR MORE DETAILED INFORMATION, INCLUDING CHRONIC HEALTH EFFECTS. CONTINUED ON PAGE: 3 72-6Z-78Z5-11 MATERIAL SAFETY DATA SHEET Yã/VQ/ine. VALVOLlNE, INC. Subsidiary of Ashland .' P.O. BOX 14 LEXINGTON, KENTUC Y 40512 (606) 264-7000 24-hour Emergency Telephone 1 (8001274-5263 or 1-800-ASHLAND 000848 CARQUEST IS032 Page: 3 . ~O~ FIRST AID: EYES: FLUSH THOROUGHLY HITH HATER. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: HASH EXPOSED AREAS HITH SOAP AND HATER. GET MEDICAL ATTENTION IF SKIN DISORDERS DEVELOP. INHALATION: IF AFFECTED BY OIL MIST, REMOVE TO FRESH AIR. INGESTION: DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. CHRONIC INFORMATION: OVEREXPOSURE CURRENTLY UNKNOWN FOR THE PRODUCT. CONTAINS: PETROLEUM OIL (GREASE) *** COMPONENTS APPEAR IN SECTION II *** LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE 72-62-7825-11 .AI{ Ya/vo/ine. MATERIAL SAFETY DATA SHEET VALVOLlNE, INC. Subsidiary of Ashland Oil:' P.O. BOX 140 LEXINGTON, KENTUC 40512 (606) 264-7000 24-hour Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company. Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910), particularly subpart G - Occupational Health and Environmental Control, and subpart I - Personal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards. SECTION I PRODUCT IDENTIFICATION GENERAL OR GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP, IARC or OSHA as of the date on the MSDS, it will be listed and footnoted in this section when present at or above 0.1 % in the product. Nega- tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subject to the reporting re- quirements of Section 313 of SARA Title III are Identi- fied in the footnotes in this section, along with ty'pical :>ercentages. Other components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELs) and American Con- ference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the component identification. Other recommendations appear as footnotes. SECTION 11\ PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of prod,-!ct .if known. The highest value of the components IS listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR = 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER = 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above 0.1 mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFIGHTING PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and sKin or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use. SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition. INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment, clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned. SECTION X LABEL INFORMATION Containslabel information including physical and health hazard warnings, handling and first aid instructions appropriate for the product. ADDITIONAL COMMENTS Containers should be either reconditioned by CERTIFIED firms or properly disposed of by APPROVED firms. Disposal of containers should be in accordance with applicable laws and regulations. 'EMPTY' drums should not be given to indi- viduals. Serious accidents have resulted from the misuse of 'EMPTIED' containers (drums, pails, etc.). Refer to Sect- ions IV and IX. I II e e ANn - ¡:-¡¿~€ Zé ALL H S:G, w.y \.\ ET ¡·W LE'¡"¡~ 6(. '/(!.oL EA~<:. e e BASF Corporation Chemicals Division BASF March 2, 1991 AUTO PARTS WHOLESALE POBOX 3289 200 SONORA ST BAKERSFIELD 067402 CA 93385 Attn: Safety Department Our records indicate that you have purchased the following product(s) from BASF Corporatio.nL--, Attached is/are our current Material Safety Data Sheets (MSDS) for the product(s) listed above. We have updated our MSDS in compliance with the requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA TITLE III). Section II of each MSDS contains a statement indicating whether or not the product contains any materials listed in Section 313 and the percentage concentration of the material, if it is listed. If you are unsure of your responsibili.ties under the Emergency Planning and Community Right-To-Know Act; or if you require more information; call the EPA Hotline (1-800-535-0202). Please also note that if you repackage or otherwise redistribute this product to industrial customers, a notice similar to this one should also be sent to those customers. Very truly yours, BASF Corporation Glenn Crawford Industrial Organics Business e e MA TERIAl SAFETY BASF Corporation Chemicals Division 100 (kerry Hill Ro.4, P.,sipp.ny. He. Jersey 070~4, (2011 316-3000 BASF DATA SHEET PRODUCT NUMBER: 547278 Zerex Antifreeze TRADE NAME: Zerex Ant I freeze CHEMICAL NAME: Inhibited Ethylene Glycol SYNONYMS: Permanent >\nt, ifreeze Engine Coolant FORMULA: Mixture CHEMICAL F AMIL Y: Gl yco 15 MOL WGT.: NI A COMPONENT CAS NO. % PEUTL V - SOURCE Zerex Antifreeze 100 Not establ I shed Contains: Ethylene glycol Phosphates Proprietary additives Water Diethylene Glycol '107-21-1 7758-11-4 N/A 7732-18-5 111-46-6 -94 < 2 < 4 50 ppm C ACGIH, OSHA Final Not establ I shed Not estab I I shed SARA Title III Sect. 313: Listed. BOILING/MELTING POINT .760 mm Hg: 330oF/ N/A VAPOR PRESSURE mm Hg .20 C: 18 SPECIFIC GRAVITY OR BULK DENSITY: 1.135 SOLUBILITY IN WATER: Infinite pH: 9.0- 11. 0 APPEARANCE: Green Dyed L I qu i d ODOR: Glycol INTENSITY: Faint ·::¡·¡¡¡¡¡~::~¡¡¡j:::::::¡:¡¡¡:::j:¡\·:¡::\¡:j:\¡:::I\¡¡~:§,§~mÎ~I!¡::¡:;II¡¡I~jl:::¡.:,I!B§,,¡.,:ill'.,:::l§_I~:§ìi!'j¡¡¡¡::,Rmgl::¡:¡:llmæ::~:~:::::'::::'::::¡:'¡':j"¡.::::::,:::: FLAMMABILITY LIMITS IN AIR (% BY VOL) LOWER: N/A AUTOIGNITION TEMP: 775°F UPPER: N/ A FLASH POINT (TEST METHOD): 250°F C.O.C. EXTINGUISHING MEDIUM Use water fog. alcohol foam. .C02 or,dry chealical extinguishing media. NFPA: 1/1/0 SPECIAL FI REFIGHT ING ,PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS Firefighters should be equipped with self-contained breathing apparatus and turnout gear. Avoid breathing va rs or fumes of heated or burni roduct. Vapors from heated {above flash point prodUct may travel to a source of ignition and flash back. e e PRODUCT NUMBER: 547278 Zerex Ant i,freeze . ,,·,":'c:·c.:,:~:· .......,....\...'. SECTION ·V HEAL TH DATA .. 1,<,'.-'. .'C. ..' ,:', ". '" "., ::.,. c':'" . ",....,/.;;.,.,,,., ...."".""", ".,'" TOXICOLOGICAL TEST DATA: RESUL T: Zerex Anti freeze Ethylene glycol data : Rat, Oral lDSO 4700 mg/kg Rabbi t, Skin Irri tat ion Mi Idly I rri ta t i ng Rabbit, Eye Irri tat ion Mi Idly irri tating Rabbi t, Derma 1 lD50 9530 mg/kg Human, Reported lethal Dose 100 ml EFFECTS OF OVEREXPOSURE: Contact with the eyes and skin may resul t In ml ld i rri tatlon. Inhalation of ethylene glycol va.pors resu 1 ts in respi ratory i rrl tation. Ingestion of about 100 ml of ethylene glycOl may result in acute poisoning' which is characterized by severe abdominal di sturb¡¡o,nces, centra.l nervous system depression a.nd possible respiratory or rena 1 fai lure. Prolonged Inhalation of the vapors may cause unconsciousness and increased ly""hocyte counts. Chron I c overexposure may lead to 1 iver degenera t i on and severe rena 1 da.mage. Animal studies indicate that ethylene glycol may be enÐryotoxic and teratogenic by the oral and inhalation routes. Existing medical conc:li tions aggra.vated by exposure to this material : No information found for this mixture. FIRST AID PROCEDURES: Eyes-Immedia.tely wa.sh eyes with runni ng water for 15 minutes. If irritation developS, consul t a physlcia.n. Skin-Wash a.ffected areas wi th soap and wa.ter. Remove a.nd launder contaminated clothing bef ore reuse. If irri ta t i on develops, consul t a physician. Ingestion-If swal lowed, di lute wi th wa.ter and Immediately indUce vomiting. Never give fluids or indUce vomi ting If the victilll is unconscious or having convulsions. Get immediate medical a.ttention. Inhalation-Move to fresh ai r. Aid in breathing, if necessary, a.nd get immediate medica.l attention. -z. ..\':"":.'):::i:::.:.:.:.:.:.:.{..:..}f::.:.:::':":;;::;;:}.::'::::.:):;;:i~:::t:;::.:.:.:.::.t:::::::::}'{:.'SE<lmlC)N't.'XtI?("""':tR:E~'GJ1l~l:';n¥\:"øJ..\;TA"'::"{":.':{:;::.:):{:.:}:{..,}f:f:':)::.'::.':::'::':".'.':':<' ............................................................................. . ........ .. . ....=-.... ... .. ,"' .. n' ...... .. n. ...... .................................................... ~:::::::::::~:}Ç:::::::~:~:~:~:::::~::::;~:~:~:¡:::~:¡:~:::::?t~:::~:t~:~:~:~:~:~:~;~:~:~:~:::::::::~:t:~:~:~:t~:~~:~:~:~:~:~:~:~:~:~;;·.-.:"· ;....-:' ...";..:' .' {. . :::: . ..;;' .::....:. . ::..." ::~::f;... .;:::"._ ::::::::::~:::::::::::;. ::., ~" -,'.' :., .:;:.....:: .:-::. >: -..::::;. . ::::. ':::" .:::....:::::~. . }~:~t- ..:""..::... -:::::. :~:: '.' / -" .::'.' ,: ::::~~::~:::~:;:~:~;::~~:~:::::;::::~::::~:::::::::::::::~:~:~:~:~:~:~:~:;:;:::::::~:::~:~:::}:.:. :.:.: . ST ABILITY: Sta.ble. CONDITIONS TO AVOID: N/A CHEMICAL INCOMPATIBILITY: N/A. v HAZARDOUS DECOMPOSITION PRODUCTS: N/A HAZARDOUS POL YMERIZA TION: Does not occur CONDITIONS TO AVOID: N/A I . CORROSIVE TO METAL: No OXIDIZER: No ·I·::::~:Ii:::::~:~:.::::::.:\:::·::::::::¡·:::~¡::::::.:::¡:::i::::·:::::::::::\~\:::::~::¡¡~i:::::¡¡:¡:\¡¡\~¡:::::::::seßœl~~..:t:'!tlj.J...:.::·~:..:·:,§gE~I.~J.#·:··:;P6ºtœ~ætON·,¡:~::::¡:::.::::¡..::··¡:.:·':::·.:!'::m::::·.:;:.¡,¡.':..:.!'.:,.::..:';.........:..:... RESPIRATORY PROTECTION: NIOSH/MSHA If va.pors or mists are genera ted. wear a a.pproved organic vapor/ mist respira.tor. \ EYE PROTECTION: Chemical goggles; also wear a face shield if sp 1 a.sh,i ng hazard exists. PROTECTIVE CLOTHING: Use rubber gloves, apron and shoes. Remove .c:ontami na.ted clothing illlll8diately and wash before reuse. - . VENT/LA T/ON: Local exha.ust to control va.pors or mists. e e PRODUCT NUMBER: 547278 Zerex Antif~Z. . , ...·.St:CTION).tJíl'!:··::.H:.i·:¡:~N~Îijê)NMEÑtAìJ·.bAìA····......i ENVIRONMENTAL TOXICITY DATA:. Fish Toxicity: LC50 = 1400 mg/l (BlUegill, 96 hour) .......... . ... .... ..............'..,................... . .................-....... . . . .. .....:...:-:...:..:......;..'... .........:...;.;:.::::--::-:::.;::::::::{.::........ .... ...;....:.;.:.;.>...:...;.." SPILL AND LEAK PROCEDURES: Spills should be contained, solidified, and placed In suitable containers for disposal This material is not regulated under RCRA or CERCLA (USuperfund") Clean up quickly as spillS are a slipping hazard HAZARDOUS SUBSTANCE SUPERFUND: No RQ (lbs): WASTE DISPOSAL METHOD: Incinerate or bury In a licensed facility. Do not discharge Into waterways Discharge to sewer systems with prior approvals is acceptable. HAZARDOUS WASTE 40CFR261: No HAZARDOUS WASTE NUMBER: CONTAINER DISPOSAl: Dispose of in licensed facility Recorrwnend crushing or other means to prevent unauthorized reuse D.O.T. PROPER SHIPPING NAME (49CFR172.101-102) HAZARDOUS SUBSTANCE (49CFR CERCLA LIST) None D.O.T. HAZARD CLASSIFICATION (CFR172.101-102) PRIMARY None No REPORTABLE QUANTITY (RQ) SECONDARY N/A None D.O.T. LABELS REQUIRED (49CFR172.101-102) None D.O.T. PLACARDS POISON CONSTITUENT REQUIRED (CFR 172.504) (49CFR 172.203(K)) None NI A BILL OF LADING DESCRIPTION Antifreeze Preparations, Proprietary (Ethylene Glycol Base) CC NO. 332 - UN/NA CODENone . DATE PREPARED: 9 I 29 / 88 UPDATED: 2 I 20 I 90 WHILE BASF CORPORATION BELIEVES THE DATA SET FORTH HEREIN ARE ACCURATE AS OF THE DATE HEREOF. BASf CORPORATION MAKES NO WARRANTY WITH RESPECT THERETO AND EXPRESSLY DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. SUCH DATA ARE OFFERED SOLELY FOR YOUR CONSIDERATION. INVESTIGATION. AND VERIFICATION. . '. e e PRODUCT NUMBER: 547278 Zerex Ant ifreeze .. :.:~:~cïlºN.~i?*·'ßftOºµÇT}·~~f!gg ..,. . d '"--." .'. ... .... .;{:::::;:~::::::;:;:;;:::;:::;::{{':':'." n . ........... . Zerex Ant if reeze CONTAINS ETHYLENE GLYCOL (CAS No. 107-21-1). CONTACT WITH EYES AND SKIN MAY CAUSE IRRITATION. INHALATION OF VAPORS MAY CAUSE RESPIRATORY IRRITATION. ACUTE OVEREXPOSURE TO ETHYLENE GLYCOL CAN CAUSE SEVERE ABDOMINAL DISTRESS, CNS DEPRESSION AND POSSIBLE RESPIRATORY AND/OR KIDNEY FAILURE. ETHYLENE GLYCOL WAS TERATOGENIC IN LABORATORY STUDIES. Avoid contact with eyes, skin or ctothlng. Avoid breathing vapors or mists. Use with tocat exhaust. Wear a NIOSH/MSHA-approved organic vapor/mist respi- rator, chemicat goggtes, gtoves, coveratls, apron, boots and other protective ctothing as necessary to prevent contact. FIRST AID: Eyes-Immediatety wash eyes with running water for 15 minutes. If Irritation devetops,- consutt a physician. Skin-Wash affected areas with soap and water. Remove and taunder contaminated ctothlng before reuse. If Irritation devetops, consutt a physician. Ingestion-If swat towed. dltute with water and immediatety induce vomiting. Never give fluids or indUce vomiting if the victim is unconscious or having convutsions. Get immediate øedicat attention. Inhatatlon-Move to fresh air. Aid in breathing, if necessary, and get Immediate medicat attention. HANDLING .HfJ STORAGE: Keep containers ctosed. In case of spltt, ctean up qulckty as product Is sUppery. Wash away smal1 amounts with cool water. Absorb targe amounts with absorbent materlat or dike and ~ into drums for proper disposa1. Incinerate or bury In an approved tandfi11 under guidance of tocat EPA. Prevent run-off onto public tand or into waterways. IN CASE OF FIRE: Use water fog, atcohot foam. CO2 Or dry chemical ext i ngui shi ng media. F I ref ighters shoUtd be ØCf.Iipped wi th set f-contained breathing apparatus and turnout gear. Vapors from heated prodUct can travet to source of ignition and ftash back. Moderate exptoslon hazard when exposed to f tame. EMPTY CONTAINERS: Att lábeled precautions lUst be observed when hand1lng, storing and transporting empty containers due to produCt residues. Do not reuse this container untess it ts professionatty cteaned and reconditioned. DISPOSAL: $pi 11 lllateri at, unused contents and empty conta lners IllUSt be disposed of In accordance with tocat, state and federat regutatlons. Refer to our Materia1 Safety Data Sheet for specific dlsposat instructions. IN CASE OF CHEMICAL EMERGENCY: Catt CHEMTREC day or night for assistance and information concerning spit led matertat, fire, exposure and other chemicat accidents. 800-424-9300. Refer to our Technicat Buttetin and Materiat Safety Data Sheet regarding safety, usage, apptications, hazards, procedures and disposal of this product. Consutt your supervisor for additional information. CAS No.: 107-21-1. 7732-18-5. Made in USA. Specialty ProdUcts 0290 Ethytene Gtycot; 7758-11-4. Dipotassium Phosphate; Water; 111-46-6. Diethytene Glyco1. "":~~, "'''''''A_',__ ,_,.........._.' ,,~.._._.-...,_ .. \ .... I .~......._._._""~......__.._--. --.- _.__.~. ----.. -" ,r--:' . .of ~ , ... '...~ e I "if,f:~'.'t;.. S·;r·~ .'-''''~', .. it, ~ ~:' . :~'.~ Y, ~t~.~,,'~z¡,;:¡ ~ II iii I·,.,..······' , fJ"'1 .".' :~j'. ~.::.: . . '/<'; ~ t '. :'}.\ I,,' BULLETIN NO. BRAKE SYSTEMS, INC. e11045 GAGE AVE. e FRANKLIN PARK, IL 60131 e (312) 455-2662 DATE: TO: RAYBESTOS WAREHOUSE DISTRIBUTORS ALL SALES PERSONNEL SUBJECT: REVISED DISCOUNT AND TERMS POLICY R 65 June 5, 1987 We are pleased to announce our revised "simplified" discount and terms policy. This change was made to allow for better inventory management, consistent profit margins, and to insure competitiveness. Effective June 26, 1987, the following discounts will be in place: 0-$9999 at Blue Sheet PC Plus and Super Stop 25% Raymold and EL 250/0 t-Jew Hydraulics 25% Qrl:ll 1 I:>, RuLurs 25% Brake Hardware 25% Fluid and Chemicals 25% Heavy Duty-Electric Trai ler Brake 25% $10,000 & Up at Blue Sheèt 32% 28% 28% Jl o¡, í<o þ€'S - l.\¡ 00 ~ j)2.ùMS- L\O ïo 30% 25% 25% Remanufactured Hydrau I ics 25% 28% LDA-j)EDC-~II'pers 2~?: 33 % Emergency orders will conti,nue to be billed at 20% off blue sheet prices. (Over) . Raymark Industries, Inc. regislered trademark, Licensed'to Breke Systems. Inc, . JUNJ 0 198? - ~ P t'Z.tJ VU ~.T·~ 3S % +-5 f{, bn- ~ m tiYl- T!-I- 5 / /6¡GA/E"I- -.. SLEC-T(¿IC A L 400;0 + 2.% b ò Ù4~ u f26 /34 T7E fJr~ïf:A. / ¡17IUI()1\.J ]),LLA¡(J VAfJEY.: mEcH4NIC~ ~5"% + a ¡{; bð fT % !fe¡gA Ie .4-¡øré:'t:- G tlù I\) 0 t2.bj) T¡..k¡ U so AN P VoLL 4<.~ .~- e _ ,...¡t..;. - -- r.... -_ ....- - ,":"'- .-~- ~- ~<..' , ,';¿~< -- I .' .,.. :/e it e e e - -2- Dating terms have been revised to allow for ease In obtaining terms. The following will be in effect as of June 26,1987: Blue Sheet Value Terms 0-$9999 2% 10th - Net 25th $10,000 - $24,999 2% 10th - 30-60 Terms $25,000 - Up 2% 10th - 30-60-90 Terms The early payment discount will still be In effect and will continue to be calculated at 2% above prime rate. The change to blue sheet values for discount and dating qualifications will allow for ease in calculating order size. The reduced order quantities for discounts and terms will allow for better inventory management and higher return on investment on Raybestos brand brake products. Thank you for your business. . . Larry Pavey LP /ibt '.....