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HomeMy WebLinkAboutBUSINESS PLAN 7/19/2007~' ~ ~ ~ ~ TODAY CLEANERS _ ~ 8200 STOCKDAI,E FIWY -- ---- - A ~~ ~, I Per it to Operil.te Hazardous Materials/Hazardous Waste Unified Permit ~,_,CONDITIONS,OF ,PERI\II~:ri,ON REVERSE SIQE, , "~;'.>,"" ,', " ';", ,', ,," ~ ;',' ' , ":l?"--<":," " ',: ' ..-" . " ! , This permit Is Issued for the following: It! Hazardous Materials Plan o Underground Storage of Hazardous Materials ; 0 Risk Management Program , 0 Hazardous Waste On-Slte Treatment .'. ' .... . Permit ID #:: 015-000-000635 ,TODAY CLEANERS #10 , . LOCATION: 8200 STOCKDALE HWY . ., ,. ,.f .. , Issued by: Bakersfield Fire Department' OFFICE OF ENVIRONMENTAL SERVICES' 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 Voice (661) 326-3979 ,FAX (661) 326-0576 Ap~roved by: Issue Date ~ ." '. '. .' . '. ,:,..;:." ~'1"';- ." . - -. ~ .' .' ",--",. , Exp,ircition Date: ~ .-;. "t:' ~:'~:7~-:: ;:--.~.~~.":": , 'June 30, 2003 '~--~. -.------------ -._- PerDl.Ït , . to Operate Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE This permit is issued for the following: ardous Materials Plan 'Jground Storage of Hazardous Materials ,.., agement Program Waste 8200 PERMIT ID# 015-021.Q00635 TODAY CLEANERS #10 LOCATION Issued by: STOCKDA Bakersfield Fire Department OffiCE OF ENVIRONMENTAL SER VICES 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 Voice (805) 326-3979 *~ ph Huey, ffiee of ental Servi es "une 30, 2000 Approved by: Expiration Date: ...........'l"--"""'---~._~--.:.- ~ ~ ,___ ------": ~ r:; ~,.q.~~ s....... ,Ç;~ r 'i . NORTH .. ~~ 7 SITE/FACILITY DIAGRAM __ ... FORM ð., 92éJð 57tc ~ FLOOR: ~ ~~~NIT :t:",\OF -:"" .,.. ~ SCALE:, BUSINESS N~~E: '~, I ' DATE: 7/J,-u/¡'; FACILITY NAi\fE: (CHECK ONE) SITE DIAG~~ FACILITY DIAGRAM ~ ~c-' 1- '-- M'k " fu¡ U-- 7;r.&1 'f.r-j...- (Inspector's Comments): :> :t¡u?ll t? \ / ~~:~ t/~~ '1"1t-tu¿'.. L ! .('°raL o 5"M {)-... ''7 d~ L ~~ .:JdN~. ;¿.« J ~ (Y" ~ '..,~~ ~l/!J.r .,. ~p.. ~ 0/1 -OFFICIAL USE ONLY- - 5A - ", f'S' v¡,' 1'f.P. ----.-- ,-.......;- ,.. e ~.Y $2t!JéJ 076cYd Ii). v:Þ ..jþ t.JS lJUSp II , c J. (¿//tU f'R~' .< .# jY¡lt ; )~ ,. :'.... "'-, "'- " :: ''1'1 ,\ "': ~:;~"-", '. ". . . .::?, .:., .:. .~~~. :.., ~.:-.~ ~ . , '.' ., ' ",.¡. ,. ' '.t-:c_ "··:'."t '< :~~~,::, ,.;"~~J: -w~~ .:'~~:' :l :-, .. '..., .., ,''', -_~'t .. . ~.' ...., "" . :"'. ." '."~" . .....'. "':--':~:~(",- ,OJ' .; 'J~ , ~1/\:·'''ì.1 . ~', . ..... .~ .:.:,;.';. .; .'.1-;, ......, ..- , ;.~;:<~' '. ""'OH ,", ~<;' t· ... ; ." I ~:., ,., ..' : ... .~J'. , , ,'. . Hr_ '1 1 EítTIfA~~é " (:'~ë:,:i~:t:"'-::-:b. ' ~. ,. 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[0~' ffJ~ , ,;,- ,~ '-~.. -\ ~ - ._,.. ", f^Z}'" ~'ïJ ~-, c -' , b' I ?UPPEP. m ' W/DS. ~i ,..t !~JP7' SiteID: 015-021-000635 9 Facility Unit: Fixed Containers on Site 9 Days On Site 365 F TODAY CLEANERS 10 p= Inventory Item 0001 = COMMON NAME / CHEMICAL NAME GREEN EARTH Location within this Facility Unit BASE TANK, CLEANING MACHINE, STORAGE Map: Grid: CAS # 127-18-4 STATE - TYPE Liquid Mixture PRESSURE Ambient TEMPERATURE Ambient CONTAINER TYPE IN MACHINE/EQUIP Largest Container 130.00 GAL AMOUNTS AT THIS LOCATION Daily Maximum 200.00 GAL Daily Average 160.00 GAL HAZARDOUS COMPONENTS %Wt. X RS CAS # 100.00 DECAMETHYLCYCLOPENTASILOXANE No 541-02-6 HAZARD ASSESSMENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies DH / / / Min -5- 07/16/2007 ·".,"c"""~~'-"c-''"Tr"'/~~:''~__"~ --- --------.- !Î--' "~ I . I , -,:-.~" -~-'"- ~~.:,~.::..$i'.._'....¿:. ··'..r.'~__ ---- ---- -. I -t- ~ ¡ ! -- -~-~------- ---- ------- -- ---- , I ~ -- - ----- - --- - ------ ~._~ -._'- ------- Ji '-,-, '- '-"- ---.,-,-,,-, -, --'- -, '-., -------~itL2- ----~--- /; _____ ---- ---if -- --~-~-U¥ _______ Ii -~~- =-)-~![ ß::¿;¿~~_~~~=_~~-~= _= ~~. ==~~ _~-~_ _ =====~~=~ --====-- -L,_ -- -- - - _._____ -_m_ ____ _____ __ _____ ______.___ ; I i ~~--~~~-~ ~~~-=---~- : I , , " -- - - -- . -- - - -- - - -- -- -- -- -- - -- - -- ---------- - ---- -- - ~--. ---.- - - ---.--- -- - - -- - --- -.- '---I- -__ ____ _ _ __ _~_____ ___ __ ____ __ _ __ ___ _ _ _ __ ~_____ _ ____._ _ _ ____ _ ' I =-.--=~ ~- ==1t~ ---=C;j- - - . =--~Md~ -.- - ----- - -- LI____ ____ _ ___ ___ __ _ _ _ _ _<_ ___ ____________ __ ___ _. _ II -- .--- ---¡-I_--------_._---- I I - ----- ----/ ,. - --- ----- --- ----------------- --- ------ ------- il ------'t-t--____~______ _.___ __________ _______________ 1/ I, -------¡+----------- -------------------- c---____ ----ft------------_______._ ___ ___ _ ______ __ _________ - - -- --:--- - -i-i-------__ ____._ _ ___________ _.___. 1/ ---- -- -- ---- -- -. -- ------ ---- - .---"I~.,- __ ____,_, _. .______ - -- --, '- - ---'----.. - --- ------....._- '.-- --------_.,---- ---,-- '-----------,----,- ------- ~'" - UNIFIED PROGRAM INSPECTION CHECKLIST SECTION 1 Business Plan and Inventory Program _ _ __ Bakersfield Fire Dept. Enironmental Services 1715 Chester Ave Bakersfield, CA 93301 Tel: (661)326-3979 FACILITY NAME , INSPECTION DATE INSPECTION TIME - ---- - ADDRESS QO PHONE No. No. of Employees FACILITYCONTACT ~ ~ ~ ` ~ Business ID Number ~j~~ ,j] ti/,~~ 15-021-p04lo3~ Section 1: Business Plan and Inventory Pn~gram ~outine ^ Combined ^ Joint Agency ^Mnlti-Agency O Complaint ^ Re-inspection C V ^ 4 d IV=Vioatonncel OPERATION APPROPRIATE PERMIT ON HAND COMMENTS ~ / /lJ ^ t7 ^ BUSINESS PLAN CONTACT INFORMATION ACCURATE VISIBLE ADDRESS ^ CORRECT OCCUPANCY ^ ~ VERIFICATION OF INVENTORY MATERIALS ^ ~ VERIFICATION OF QUANTITIES n'a ~~Kf r~ ~SCKgS PC/C~y~~`p//~ L~' ^ VERIFICATION OF LOCATION ^ ^ PROPER SEGREGATION OF MATERIAL , ~/ ^ LrJ VERIFICATION OF MSDcJ AVAILABILITYE -- - - ---- --------- l~ ^ VERIFICATION OF FIAT MAT TRAINING - of ~-1-~1_^~~r._ear-~iy ---------- ~^ VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES _ l~ ^ EMERGENCY PROCEDURES ADEQUATE la' ^ CONTAINERS PROPERLY LABELED t+Y ^ HOUSEKEEPING l~ ^ FIRE PROTECTION ------ - - h~T~ ~o~ a -------- ---------- l~^ SITE DIAGRAM ADEQUATE & ON HAND eh ~/, ~ ~/~'O/~ // !~'J O ~ J 1 7 ~ ~ ~ d Q ~ ANY HAZARDOUS WASTE ON SITE: AYES O //~ EXPLAIN: ~/D~ ~~r+.~N ~i~J+T17 // QUESTIONS REGARDING THIS INSPECTIONS PLEASE CALL US AT (661) 326-3979 __ _ ~ ~ 90 _____ Inspector Badge No While • Environmental Services Yellow • Slatbn Copy usiness Site R~ sible Perry Pink • Buslnesa Copy I ( C~ ,iit -:~ ...,~ It TODAY CLEANERS #10 ~,,'-, t:EIVED ~/UN ~ 0 2000 Manager : Location: 8200 STOCKDALE City : BAKERSFIELD CommCode: BAKERSFIELD STATION 11 EPA Numb: Emergency Contact MIKE DANIEL Business Phone: 24-Hour Phone : Pager Phone : ~ / 1 Title / VICE PRESIDENT (805) 634-1130x (805) 589-2805x (805) 329-6774x Hazmat Hazards: Contact : MailAddr: 121 MONTEREY ST City : BAKERSFIELD Owner Address City RICHARD K. NEWMAN & ASSOC INC : 121 MONTEREY ST : BAKERSFIELD Period : Preparer: Certif'd: to Emergency Directives: f= Hazmat Inventory p== As Designated Order .; SiteID: 215-000-000635 = 4&1 ~ 634-1210 CommHaz : Moderate FacUnits: 1 AOV: BusPhone: Map : 123 Grid: 05B SIC Code:7216 DunnBrad:02-788-0566 Emergency Contact JEFF NEWMAN JR Business Phone: 24-Hour Phone : Pager Phone : Phone: State: Zip : Phone: State: Zip : / Title / VICE PRESIDENT (805) 634-1130x (805) 872-8047x (805) 329-4346x DelHlth (¿{ )C#:Jo/ - /¡:JOx CA 93305 ~ / ' ~ 634-1130x CA 93305 TotalASTs: = TotalUSTs: = RSs: No Gal Gal One Unified List l All Materials at Site l Razmat Common Name... SpecHaz EPA Hazards PERCHLOROETHYLENE -1- DR DailyMax MCP L 200.00 GAL Min 05/09/2000 .. e e F TODAY CLEANERS #10 f= Inventory Item 0001 = COMMON NAME / CHEMICAL NAME PERCHLOROETHYLENE SiteID: 215-000-000635 1 Facility Unit: Fixed Containers on Site 1 Days On Site 365 Location within this Facility Unit BASE TANK, CLEANING MACHINE, STORAGE Map: Grid: CAS # 127-18-4 STATE - TYPE Liquid Pure PRESSURE Ambient TEMPERATURE Ambient CONTAINER TYPE IN MACHINE/EQUIP Largest Container i30 GAL AMOUNTS AT THIS LOCATION Daily Maximum 200.00 GAL Daily Average 160.00 GAL %'Wt. RS CAS # 100.00 Perchloroethylene No 127184 HAZARDOUS COMPONENTS TSecret RS BioHaz Radioactive/Amount, EPA Hazards NFPA USDOT# MCP No No No No/ Curies DH / / / Min HAZARD ASSESSMENTS -2- 05/09/2000 e . SiteID: 215-000-000635 ì Fast Format ì Overall Site ì 12/17/1992 ] 12/17/1992 ] 12/17/1992 1 12/17/1992 F TODAY CLEANERS #10 I p= Notif./Evacuation/Medical' r=: Agency Notification CALL 911 r=:: Employee Notif.jEvacuation LL 911 & VERBALLY EVACUATE I Public VERBAL Notif./Evacuation Emergency Medical Plan DR WILLARD CHRISTENSEN - 2021 22ND ST - 327-9617 -3- 05/09/2000 .' ~. e e F TODAY CLEANERS #10 I f= Mitigation/Prevent/Abatemt Release Prevention SiteID: 215-000-000635 ì Fast Format ì Overall Site ì 04/02/1996 WE STORE IN METAL CANS, BARRELS ETC. ALL LIQUID HAZARDOUS MATERIAL. OUR HAZARDOUS WASTE IS PICKED UP EACH MONTH BY A LICENSED HAULER. WE HAVE PLANS FOR EVACUATION IN CASE OF A SPILL OF PERCHLORETHLYENE LIQUID. WE SOAK UP VALCLEAN WITH TOWELS & RECOVER PERCHLOROETHYLENE IN DRYCLEAN MACHINE. LOTS OF VENTILATION. Release Containment 04/02/1996 STAINLESS STEEL BASE TANK OF CLEANING MACHINE. Clean Up 04/02/1996 SOAK UP SPILLED PERCHLOROETHYLENE WITH TOWELS AND RECLAIM SOLVENT IN DRYCLEANING MACHINE. Other Resource Activation I -4- 05/09/2000 /. .. e e F TODAY CLEANERS #10 I f= Site Emergency Factors r== Special Hazards Utility Shut-Offs SiteID: 215-000-000635 1 Fast Format l Overall Site 1 I 07/13/1998 A) GAS - E SIDE OF BLDG, COFFEE RD 20 FT S OF BACK DOOR B) ELECTRICAL - W BOILER RM WALL C) WATER - E BOILER RM WALL OUTSIDE - GATE VALVE D) SPECIAL - NONE E) LOCK BOX - NO Fire Protec./Avail. Water 07/13/1998 PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS, PLUS ENTIRE STORE IS SPRINKLERED. FIRE HYDRANT - 100 FT S OF STORE, AT INTERSECTION OF COFFEE/GOSFORD AND Building Occupancy Level -5- 05/09/2000 4 "1', ci.. '., e e f TODAY CLEANERS #10 I F Training Employee Training SiteID: 215-000-000635 ì Fast Format l Overall Site ì 07/13/1998 WE HAVE 10 EMPLOYEES AT THIS FACILITY. WE DO HAVE MATERIAL SAFETY DATA SHEETS ON FILE. ,r BRIEF SUMMARY OF TRAINING PROGRAM: WE HAVE SAFETY MEETINGS. Page 2 [ I I Held for Future Use Held for Future Use -6- 05/09/2000 i". :; e RECEIVED e TODAY CLEANERS #10 Manager : Location: 8200 STOCKDALE City BAKERSFIELD / r::/ BusPhone: Map : 123 Grid: 05B SiteID: 215-000-000635 tCØ~<=-~~~© (805) :J.98 8288 CommHaz : Moderate FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 11 EPA Numb: SIC Code:7216 DunnBrad:02-788-0566 Emergency Contact / Title Emergency Contact / Title MIKE DANIEL / VICE PRESIDENT JEFF NEWMAN JR / VICE PRESIDENT Business Phone: (805) 634-1130x Business Phone: (805) 634-1130x 24-Hour Phone : (805) ~3~~~IX 24-Hour Phone : (805) 872-8047x Pager Phone : (805) 29- 4x Pager Phone : (805) 329-4346x Hazmat Hazards: DelHlth Emergency Directives: One Unified List ì All Materials at Site ì specHaz EPA Hazards Frm I DailyMax Unit MCP f= Hazmat Inventory f== MCP+DailyMax Order Hazmat Common Name... PERCHLOROETHYLENE DH L 200 GAL Min U. rYì 1[,£ ~f\1'!(~ DC) \harabv eŒJi1i~ ~~a~ U ~faI\!~ (r~ or ¡¡J VIi namo) rsvi~wsd ~hs atlached ~~taW~OO~ m®~®oi&1~~ mtaJi1~@®- ò 'a¡n ~@fr --r;; D ~ ~OO ~\fð®~ û~ @\~(Q)!fü® ~~Ih mSV"h p 4~~. ) aìU1~ oor&'"®d¡©!n~ OOIrl($~ð~~~® ~ oompis~~ ®lI1lrcl OOW~ ~11- ~~®m~k1~ ~1~[f'ß ~©U' ~~ ~m~. ,[)~ ,/}JJ/Æo ~l(¿r5 . -1- 03/11/1998 r e e F TODAY CLEANERS #10 F Inventory Item 0'001 = COMMON NAME / CHEMI CAL NAME PERCHLOROETHYLENE SiteID: 215-000-000635 ì Facility Unit: Fixed Containers on Site 9 Days On Site 365 Location within this ,Facility Unit BASE TANK, CLEANING MACHINE, STORAGE Map: Grid: CAS # 127-18-4 STATE - TYPE Liquid Pure PRESSURE Ambient TEMPERATURE Ambient CONTAINER TYPE IN MACHINE/EQUIP Largest Container GAL AMOUNTS AT THIS LOCATION Daily Maximum 200.00 GAL Daily Average 160.00 GAL %'Wt. RS CAS # 100.00 Perchloroethylene No 127184 HAZARDOUS COMPONENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies DH / / / Min HAZARD ASSESSMENTS -2- 03/11/1998 !' It e F TODAY CLEANERS #10 I p= Notif./Evacuation/Medical ~ Agency Notification CALL 911 SiteID: 215-000-000635 ì Fast Format ì Overall Site ì 12/17/19921 ] 12/17/1992 ~ Employee Notif./Evacuation LL 911 & VERBALLY EVACUATE Public Notif./Evacuation 12/17/1992 1 12/17/1992 VERBAL Emergency Medical Plan DR WILLARD CHRISTENSEN - 2021 22ND ST - 327-9617 -3- 03/11/1998 e e F TODAY CLEANERS #10 I p= Mitigation/Prevent/Abatemt Release Prevention SiteID: 215-000-000635 ì Fast Format ì Overall Site ì 04/02/1996 WE STORE IN METAL CANS, BARRELS ETC. ALL LIQUID HAZARDOUS MATERIAL. OUR HAZARDOUS WASTE IS PICKED UP EACH MONTH BY A LICENSED HAULER. WE HAVE PLANS FOR EVACUATION IN CASE OF A SPILL OF PERCHLORETHLYENE LIQUID. WE SOAK UP ~LRAN WITH TOWELS & RECOVER PERCHLOROETHYLENE IN DRYCLEAN MACHINE. LOTS ði!' VENTILATION. Release Containment 04/02/1996 STAINLESS STEEL BASE TANK OF CLEANING MACHINE. Clean Up 04/02/1996 SOAK UP SPILLED PERCHLOROETHYLENE WITH TOWELS AND RECLAIM SOLVENT IN DRYCLEANING MACHINE. Other Resource Activation -4- 03/11/1998 ;¡ 'é e e F TODAY CLEANERS #10 I f= Site Emergency Factors r== Special Hazards Utility Shut-Offs SiteID: 215-000-000635 ì Fast Format ì Overall Site ì I 12/17/1992 A) GAS - EAST SIDE OF BUILDING, COFFEE RD 20 FEET SOUTH OF BACK DOOR B) ELECTRICAL - WEST BOILER ROOM WALL C) WATER - EAST BOILER ROOM WALL OUTSIDE - GATE VALVE D) SPECIAL - NONE E) LOCK BOX - NO Fire Protec./Avail. Water 12/17/1992 PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS, PLUS ENTIRE STORE IS SPRINKLERED. FIRE HYDRANT - 100 FT S OF STORE, AT INTERSECTION OF COFFEE/GOSFORD AND Building Occupancy Level -5- 03/11/1998 3 :>, _.. ~ e e F TODAY CLEANERS #10 I F Training Employee Training SiteID: 215-000-000635 ì Fast Format ì Overall Site ì 04/02/1996 WE HAVE 10 EMPLOYEES AT THIS FACILITY WE DO HAVE MATERIAL SAFETY DATA SHEETS ON FILE. BRIEF SUMMARY OF TRAINING PROGRAM: WE HAVE SAFETY MEETINGS. Page 2 r I I Held for Future Use Held for Future Use -6- 03/11/1998 ¡~~ . '" -- · ~~(Ç~@i;I 1 ~ o I 3 11/96 TODAY CLEANERS #10 215-000-000635 Jf~ge Overall Site with I Fac. Unit , APR 1 1998 Ii ijl i: if' General Information c.'1 Bv I ~-~.,-~. ..'-.,-.-.:::=-.:--:=::-- . : Location: 8200 STOCKDALE HWY Map:123 Haz:3 Type: 3 City . Bakersfield Grid: 05B FlU: 1 AOV: 0.0 . - Contact Name Title ~ Contact Name Title MIKE DANIEL I VICE PRESIDENT JEFF NEWMAN JR I VICE PRESIDENT Business Phone: (805) 325 1241uú34f- Business Phone: (805) 325 1241nb34.¡1- 24-Hour Phone · (805) 393-7871x ,,3C> 24-Hour Phone · (805) 872-8047x II"£>o · · Pager Phone · ( ) - x Pager Phone · ( ) - x · · Administrative Data Mail Addrs: 8200 STOCKDALE HWY D&B Number: 02-788-0566 City: BAKERSFIELD State: CA Zip: 93309- Comm Code: 215-011 BAKERSFIELD STATION 11 SIC Code: 7216 Owner: RICHARD K. NEWMAN & ASSOC INC Phone: (805) -32:) 1241' Address: 121 MONTEREY ST State: CA er/5f¡.«I-"3J~ City: BAKERSFIELD Zip: 93305- Summary JmJe~ .' e e "' 03/11/96 TODAY CLEANERS #10 215-000-000635 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site PIn-Ref Name/Hazards Form Max Qty MCP 02-001 VALCLEANE- 1'~~~~y~c ~ Delay Hlth Liquid Page 2 ~~ Minimal GAL ".. . ' " e e 03/11/96 TODAY CLEANERS #10 215-000-000635 02 - Fixed Containers on Site Page 3 Hazmat Inventory Detail in MCP Order 02-001 JJALCLEANE ~~~~~ ~ Delay Hlth Liquid Q6b -6-6=' Minimal GAL CAS #:-l!600 7!=4- Trade Secret: No I ;1.., -t r;-4.t Form: Liquid Type: Pure Days: 365 Use: CLEANING ---- Daily M~ ----r-- Daily Average GAL --r-- Annual Amount GAL -- ~vv - I /(ø!J ~6. 66 I -;;t50 190. 00 Storage IN MACHINE/EQUIP r Press T Temp ~ Location Ambient Ambient BASE TANK, CLEANING MACHINE, STO - Conc -, Components 100.0% !l'EichloretriflueroctA.:m9 ' P~tltÞr&vWy~~ r; MCP --,-Guide Minimal I 58 - Notes ;: e e 03/11/96 TODAY CLEANERS #10 215-000-000635 00 - Overall Site Page 4 <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation CALL 911 & VERBALLY EVACUATE <3> Public Notif./Evacuation VERBAL <4> Emergency Medical Plan DR WILLARD CHRISTENSEN - 2021 22ND ST - 327-9617 , ' . ,~ r. e e 03/11/96 TODAY CLEANERS #10 215-000-000635 00 - Overall Site Page 5 <E> Mitigation/Prevent/Abatemt <1> Release Prevention WE STORE IN METAL CANS, BARRELS ETC. ALL LIQUID HAZARDOUS MATERIAL. OUR HAZARDOUS WASTE IS PICKED UP EACH MONTH BY A LICENSED HAULER. WE HAVE PLANS FOR EVACUATION IN CASE OF A SPILL OF ~~EAN ~PERCHLORETHLYENE LIQUID. WE SOAK UP JlALCLEAN WITH TOWELS & RECOVER YALCLEAN' IN -RECLAn~ TUMBLE¡RG. LOTS OF VENTILATION. DAI~ Mlf¡UtøfoJl$: <2> Release Containment STAINLESS STEEL BASE TANK OF CLEANING MACHINE. <3> Clean Up P~c... SOAK UP SPILLED VALCLEAN WITH TOWELS AND RECLAIM SOLVENT IN DRYCLEANING MACHINE. <4> Other Resource Activation ;¡-" - -!' r. e e 03/11/96 TODAY CLEANERS #10 215-000-000635 00 - Overall Site Page 6 <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - EAST SIDE OF BUILDING, COFFEE RD 20 FEET SOUTH OF BACK DOOR B) ELECTRICAL - WEST BOILER ROOM WALL C) WATER - EAST BOILER ROOM WALL OUTSIDE - GATE VALVE D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS, PLUS ENTIRE STORE IS SPRINKLERED. FIRE HYDRANT - 100 FT S OF STORE, AT INTERSECTION OF COFFEE/GOSFORD AND STOCKDALE HWY. <4> Building Occupancy Level ~ -. ~. ''ó;- tit e 03/11/96 TODAY CLEANERS #10 215-000-000635 00 - Overall Site Page 7 <G> Training <1> Employee Training WE HAVE ;( EMPLOYEES AT THIS FACILITY 10 WE DO HAVE MATERIAL SAFETY DATA SHEETS ON FILE. BRIEF SUMMARY OF TRAINING PROGRAM: WE HAVE SAFETY MEETINGS. <2> Page 2 <3> Held for Future Use <4> Held for Future Use õ ~:... ,) Overall Site with 1 Fac. Unit ' IDEC 17 1992 General Information B e 1 ~ 08/05/92 Location: 8200 STOCKDALE HWY Community: BAKERSFIELD STATION 11 Map: 123 Hazard: Moderate Grid: 05B, FlU: 1 AOV: 0.0 . Ti tle V 4ce 1ti.e;$I8Je¡¡u~ )/~E' -PNe$íD~ Business Phone (805) 325-1241 x (805) '325-1241 x ~ ~ Contact Name MIKE DANIEL Administrative Data Mail Addrs: 8200 STOCKDALE HWY City: BAKERSFIELD Comm Code: 215-011 BAKERSFIELD STATION '11 D&B Number: 02-788-0566 State: CA Zip: 93309- SIC Code: 7216 Owner: RICHARD K. NEWMAN & ASSOC INC Address: 121 MONTEREY ST City: BAKERSFIELD Phone: (805) 325-1241 State: CA Zip: 93305- Summary . . ~, M~e 1?~/~ !D~ hare19y c®últåÛ1f ~~ ~ Û"iræv® JlP9 or print 1I@ffi()) r¡gvåœJw~©1 ~hiS aüaì©lOOd hazardous maî@)ri~i~ ffi®~~@®o msoi ~1@\&1 ff©~ TC>D~ ~nd ~h~~ i~ ®~©ffltf\1 WÔ~~ (l\Iwne BUSloooo) ~ ~fflV ©])/i'!i'®di©n$ ©@ffl$tift~~s ~ OOmplsft~ ®~©1 OOIì'~®©í! m~B10 ~®ffl®~ íQJ~~fii) ff@rr ffiV ~©å~WV. f: ' t{¡~'f!' ~If!/~ lallï/q¡~ ,,7 ;;t' . $!~i'O ~ ;:. '. - - 08/05/92 TODAY CLEANERS #10 215-000-000635 02 - Fixed Containers on Site Page 2 Hazmat Inventory Detail in Reference Number Order 02-001 VALCLEANE ~ Delay Hlth CAS #: 19600-79-4 Liquid 60 Minimal GAL Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: CLEANING Daily Max GAL ~ Daily Average GAL ~ Annual Amount GAL -- 60 I 50.00 I 190.00 Storage IN MACHINE/EQUIP r Press T Temp ~ Location Ambient Ambient BASE TANK, ,CLEANING MACHINE, STO - Conc ~ Components 100.0% Trichlorotrifluoroethane r; MCP ~List Minimal I - Notes L ". -- . 08/05/92 TODAY CLEANERS #10 215-000-000635 00 - Overall Site Page 3 <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 " <2> Employee Notif./Evacuation CALL, 911 & VERBALLY EVACUATE <3> Public Notif./Evacuation VERBAL <4> Emergency Medical Plan DR. WILLARD CHRISTENSEN 20a (, ~þ 5 TGtrerET. 32.7- qla~7 " ¡:,Þ.,... "\ tit . 08/05/92 TODAY CLEANERS #10 215-000-000635 00 - Overall Site Page 4 <E> Mitigation/Prevent/Abatemt <1> Release Prevention WE STORE IN METAL CANS, BARRELS ETC. ALL LIQUID HAZARDOUS MATERIAL. OUR HAZARDOUS WASTE IS PICKED UP EACH MONTH BY A LICENSED HAULER. WE HAVE ,PLANS FOR EVACUATION IN CASE OF A SPILL OF VALCLEAN OR PERCHLORETHLYENE LIQUID. WE SOAK UP ~RK WITH TOWELS & RECOVER~ IN RECLAIM TUMBLERS. LOTS OF VENTILATION . "~e \lALCtæ~ <2> Release Containment _ ¡ùjfi· '5mlA'JL!:-'"';S>s 5~ ~t-- ~J{ op - ... , ~1¡1:Hi:> (Oft(..H lIVE', <3> Clean Up SòA1<, Up SP/UEO V~~ (,PITH ~~ þJt> R~Ñ\.. 5DWe?Vr I~ 1Jity~"~ mhUh¡v¡:=-. <4> Other Resource Activation '- 7~", f ,\. . . 08/05/92 TODAY CLEANERS #10 215-000-000635 00 - Overall Site Page 5 <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - EAST SIDE OF BUILDING, COFFEE RD 20 FEET SOUTH OF BACK DOOR B) ELECTRICAL - WEST BOILER ROOM WALL C) WATER - EAST BOILER ROOM WALL OUTSIDE - GATE VALVE D) SPECIAL - NONE E) LOCK BOX -NO <3> Fire Protec~/Avail. Water (;> PRIVATE FIRE PROTECTION - 1111111111111 FiRE" EX.TI¡r.)t.r:.MI.S~ ) fW$ b71I'fE S-~e- ;$ S;?fì/~"LS'iED. FIRE HYDRANT - 1111?1111111 100 fif;er ~rH OF S;;-¡OR.ê, fir .:::QVWAS ecn~ OF Ce>Ffl=E /6e6/õ1V) h<Jtf) S¡-otI<DME ~y. <4> Building Occupancy Level m~ - 10 €/?¡)PLO'Iêe'S . ,- 1-..~ ,.~ :7' .~ . . 08/05/92 TODAY CLEANERS #10 215-000-000635 00 - Overall Site Page 6 <G> Training <1> Page 1 WE HAVE 7 EMPLOYEES AT THIS FACILITY DO YOU HAVE MATERIAL SAFETY DATA SHEETS ON FILE? ~e5 WE HAVE SAFETY MEETINGS. <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use OHAZARD,O. US MATER I. A, LS INVENTORY 1 1 F,f' ,nd Agticulture [J Standard Business "I' R A DES E eRE T S ; Paqe 0' _., nUS¢"íSS flAME: TODAY CLEANERS ~NER NAME:Richard K. Newman & ASftSÀ~~ nn THIS FACiLITY' #10 . I Oç r Otl· A ORES:' ' '51 ^NO 0 I NO CL 5S r.ÖOE r-'-'- .-.-----...---' Cl. I ~IÞ: R200 STOCKD"l\LE HWY C TY Ip:~e~~PIêíar ~~r933ð5 DUN A ~ BRADSTREEr NÚHBE'D.--·.7-61,6-,-:- ,. .....----.., -,-, I'IIOII~ : ,..,_=.:--=~:~~~t;LLJ l~,Tl\gTITT Æ ~Mh to--iWs8fR1ibii'tJi.¡sl#nrPROPER CODES ~ - - _ - - - _2=7]8_-0566 . I 2 3 4 5 & ~ 8 9 10 11 ' IZ 13 It Ir~ns Iyae \lax Average Annual Mea$ure I Js Cant Cont Cont Un location Where 'by Nilles of IIhture{cc,ponents Code Code AIIt Aølt Est Units on te Iyp. Press lellp COd' Stored In facilIty lit See Instrut Ions . ..u '-1M -=r I r 3 _IGAL 360 10 1 4 0 water white/spray P/lUicøl 'pd Health "liard C.A.S. Number 1]n-a~~i gnpr'! COllponent 11 N8I\" C.A.S. NUllber (Check a I that applYl .. Trade Secret sligth COllponent 12 Nail.' C.A.S. NUllber epfire Huard 0 Reactivity ~elared 0 SUdd,n Release 0 III.edlate Hea th 0 Pressure Health Irri tant to Skin & Eyes ' COllponent U HUI' C.A.S. NUllber 3 GAL, C.A.S. HUllber CITY of BAKERSFIELD U M PhYSicøl 'pd Health Halard lçheck I I that apply I slight W<Fire Hlzard TANNIN SPOTTER COllponent II Naill' C.A.S. Nunber Trade Secret Nalle . C.A~S. NUllber COllponlnt U o Reactivlt, 1421 Dehred 0 .Sudd,n Release [] IlIlIedlatl ' Hea th 0 Pressure Health Slight Irritant to Skin & Eyes COlponent f3 Naill' C.A~~; Nunber 360 10 4 08 STORAGE CABINET un-n~~i gnpr'! COllponent II Nalle' C.A.S. NUllber i Trade Secret N'Vh I d 0 dd R I 0 I dl COllpon.nt 12 Nu.' e.A.S. NUllber u,,,e aye Su 'n e elSe IlIe ate , Health 0 Pressure Health Irri tarit to Skin & Eyes COllponent f3 Naill' e.A:,S. NUllber I 3' ~360 I 10 I 1 I 4 I 08 ISToR1.GR CARTNE'r C.A.S. NUllber COllponent II Halle I e.A.S, NUlber Traq,~ Secret Hale I C.A~S. NUllber ,. N U _J Phlsic~' 'nd Hellth Halard I heck I I that applYI =~light ~fire Hazard [] Reactlvit, C.A.S. NUllber Slight ~ I PhISic,I 'nd Health Ualard (check a I that applYI slight 0 I dl Co.ponent U ß<:Fire Ifazard [] Reac~I~lt, '. xQ. DJ~:r:~.,;O sUdgf"pr:~::l: lI"ea~t~ COllponent 13 Nalle' e.A.S. NUllber Slight Irritant to Skin & Eyes EMERGEtlCY CotH ACTS '" KELLEY RROWN' T,D.TRFr''T'()R . 8,7 L ? ~ 31 Ø2 PENNY GEDDES "N m 2.~~~ ~ C~rtifiçatio~ (Re~d tJf1d ~igf1 af1fJr Cnn'f1eting a11 rcectfol1S~ I tertlry under penlltt 0 II. that J have pe{sona I~l exall ne '~d,. faJlllac lit the In(oClat øn subnltted fn this end all attaçhed dQcVllents, an t at based on ., InquIry 0 hose ndlYldUI s responslb. or obtaInIng he Inforllation. I belIeve that the sub~ltted Inlorllat on s true, accurate, and co~plete. . ' REMOVER VICE PRES. T1tle " r;~Ff ;. ¡iij 'õf Ie II r-f I nr-nõVñrrrõpmtðfìJlr"õliñrfTõprflfõf'nüUiMtIfif-rfPfUiñUt he Sl1ñltun 871-1729 2fllfl'Mñe- DlU-SUr:U--' CITY of HAKEH~fl1::LU HAZARDOUS MATERIALS INVENTORY Farl and Agticulture [] Standard Business 0 ' 2 .a ' NON-TRADE SECRETS Page __'uu 0" USINESS.NAME: TODA~ CLEANERS OWNER N~ME: Richard K. Newman & A~ij.~koTHh8 F¿CIlP~¿o ¡UO,n .____,.,. r.f~T1'~p:_-1~~~~~_~~l-r AObQES'!p:=ij.~.~W~få¥ ~~·g~ngs ~uA ~ND B^AOŠTR~Ef NUMBfft-721ú' .' - ".,---.. -,-, o ~ . -- j~èj-tL~UB ' J}F~k TO-INSTRUCTIDNS-FOR--PRDPER CODES - - - - - ô2.::- 28£3-..0566 . I 2 J. 6~ 8 9 10 11 12 I J . U fr~ns fYAe Max Average Mea$ure I rs Cant Cant Cant Use loc,tion "here 'by Nues of Iuture(C~rconents Co~e Co~e AIIt Alt Units on te 'ype Press hIp Co~e Stored In facIlity lit See Jnstru~ Ions U p 1 1 36 08 Storage Cabinet 0 SodiumPerbor~~~ Phlsical 'nd Hulth Halard 7632-04-4 COllponent 11 Nllle I C.A.S. NUllber ( heck a I that apply) [J Fire Hazard [] Reactivity Sli<;¡ht ~1 11 Physical 'Pd Health Halard (Check a I that apply) [J Fire Hazard [] Reactivity [J Fire Hazard [] Reactivity Slight '~35 I 7.0 Physical 'nd Health Hafard (Check a I that apply [] COllponent'2 Nalle I C.A.S. NUllber . IlIlIediate Hea I th COllponent.3 Halle' C.A.S. HUllber ~etared [] Sudden Release Hea th of Pressure trritant~~k;n ~ Eyes 1 5 ~360 I 10 I 1 C.A.S. NUllber unassigned 4 I oá StorH9P rHn;npt COllponent II Halle I C.A.S. NUllber Trade Secret Component 12 Halle' C.A.S. HUllber [] IlIlIediale Hea I th COllponent.3 Halle I C.A.S. HUllber Stora e Cabinet unassiqned COllponent 11 Hue I C.A.S. HUllber Trade Secret COllponent'2 Halle' C.A.S. NUllber ~e tared [] Sudden Re lease 0 IlIlIed iate Hea th Of Pressure Health Irri tant to Skin & Eyes COllponent 13 HaII8' C.A.S. HUllber I is ~ 360 I 07 1 I 4 I 41 Boi'ler Room C.A.S. NUllber ilinassigned COllponent II Nalle I C.A.S. Number 1310-73 . Component 12 Halle' C.A.S. HUllber [] Reactivity 0 Oelared 0 SUddfn Release [] IlImedlate 10037-8 Hea th 0 Pressure Health Mild Irritant to Skin & Eyes COllponent 13 Nllle I C.A.S. NUllber EMERGENCY CONTACTS 111R11'eellev Brown Tfd~i rpî'+-or 2Pì,lpfiinf3-l- 112nünny Goddoo ~HtifitJtiOI fReed Bnd $ ign af1Ðr cpmp let; iog all ~e.ct ions) '·certlf, un~er penallx 0 la_ th,t I have pe{sona I~l exallneq end 01 fA.illac fit the In(oCllat1øn sublltted In this end all Iltaçhed dQCUllents, ano t at based on .Y Inquiry 0 hose IndiViduals responslb e or obtaInIng the Inforllatlon. I belIeve that the ;ubllltled Inforllat on IS true. accurate. and co.plete. U F ire Hazard ì¡;t~rðïõrfëflr-t1(Jf of oVR~rloDerltor UH o~ntrlðJf11tor'l ,utWð711~FI11ñf1tlve ST~¡¡W;n 10 Formula CH .. d 4% Sodium Hydroxide 1% DiethVlaminoethanol Vice. Pres. T1th 871-1729 HHf'fliðñr- pu,")r4r.lð-·' HAZARDOUS MATERIALS INVENTORY Fare and Agticulture [J Standard Business [J 1 NON-TRADE SECRETS Paqe 'U~À~ið~.NAHE:~~ ,p~imr~~H ~~~E~sN~HE:¥~rhfiMtt~rc~e~~n & AS~~b~hDTHhB.FêaLPlòD :_;~~9. 00__ ,-~=,=,.._,_, ;~T~... ~!P:__~J_~_~311 ~lbQ ~ f!P:-=m~f~~ld, Ca 93.3.0.5DU~ AND B^ADSTR~Er NUt1~88-0566 1I0f t: . -- lqR-82n8 ' R;rF~R TO-INSTRUCTIDNS-FDR-PRDPER CODES - - - - - - - - - I 2 3 4 5 6 7 8 9 10 II ,12 13 It Tr~ns TYAe lIax Average Annual Hea$ure . OY5 Cont Cont Cont Use loc4tlon Where 'by Nalles of )lixture{c::roonents Code Code Aet Alt Est Units on Site type Press temp Code Stored In Facility lit See Instruc Ions U P 60GAL 50GAL 360 14 6 1 0 Fluorocarbon 113 Physical fnd Health Halard 196-007940 Nalle' C.A.S. NUllber mach.or, VaA.L\I=~..J'1 (ChHk a I that apply storage cabl e :(i,1;'~'<t:. I 0 C0l1ponent.2 Nalle' C.A.S. Number . 0 F ire Hazard 0 Reactivity ~Delayed 0 Suddfn Release· IlImediate Health 0 Pressure' Health Slight Irritant to Skin & Eyes Component 13 Nue' C.A.S. NUllber 4 I~ 360 113 11 I 4 I 08' I Storaqe Cabinet C.A.S. NUllber unassigned COllponent.1 Nllle I C.A.S. NUllber Trade secf.~t. C0l1ponent.2 Nalle' C. .5. Number [] IlImediate Trade Secret Health Eyes Component t3 Nalle' C.A.S. Nunber CITY of HAKERSrlELIJ ~ I Phlsic~1 '~d Health Halard I heck a I that apply o Fire Hazard o Reactivity fiDelayed [] Sudden Release Health of Pressure Slight Irritant to Skin & U M Phlsical 'nd Health Ha~ard I heck a I that apply) 4 08 Storage Cabinet Component.1 Nalle' C.A.S. Number Trade Secret O Co~ponent '2 jalle I C.A.S·tNunber IlImediate 'Trade S"ecre Health Eyes COlllponent t3 Nllle' C.A.S. NUllber C.A.S. Number unassiqned o f j re Hazard [] Reactivity ~elayed 0 SUddfR Release , Hulth 0 pres.sure Sllght Irrltant to Skln & U 1 Physical 'nd Health Ha~ard . ICheck a I that applYI 4 Component .1 LJ Fire Hazard [] Component.2 Name' C.A.S. NUllber o Reactivity [JJOelayed 0 Sudden Release Il1mediate , He41th of Pressure Health Sllght Irrl tant to Skin & Eyes Component t3 Nue' C.A.S. NUllber EMERGENCY CONTACTS "'R~iLLEY BROWN TPålector 2~-1t-jii6~ l1 112nnrnny ~t=>ddes ~ertifiC3tioq (Reed 8nd s;gn af1ør C9n1plet;f19, fill, rcect;OI1S) . ' I-certify un1er penaltr 0 law th4t I have pe{sona Iy exallneO eqd 'I ill lIar WIt the infornatlpft ,ublltted In this end all Iltaçhed dQcVllents\ anQ t at based on my Inquiry 0 those IndiViduals responsible or obtaIning the Inforllatlon. J belIeve that the ¡ubmltted Inforllat on IS true, accurate, and co.plete. ' Hiié'.rðortffim tie Of o\lner/ ooer Itor UII ollner I oper stor' 5 autliõfT1ëãfëØreseñtãt I ve S1qñnure OH!)!qr.ëð-' of ~, o picrin 1 0 REP 100(water Primary Amyl Acetate .-' OCNAm 1 Acetate 3 5 2-Methyl Butyl Acetate ;'.(. 3-Methyl Butyl Acetate' Vice. Pres. 871-1729 nOe inWfJiõñr-' 'I 0 Iir~ZARDOUS MATERIALS INVENTORY FarllandAgtlcuture Standard Business I.:t NON-TRADE SECRETS Page 3 of 4 TODAY CLEANERS Richard I<'Newman &As~R~ F I IT =#=10 __'u,_ U~l~~S~.NAHE: ~S~~~SN~HE:-í:21 Honterey ~t, sYAND9rmT~~g F~rA~S tÒOE'-· 'ï216'~ p" .......P,,___. ~b~~ î~p:__~~~~~R~;=~,~~H~= ~l b~~ ¡!P:~~~f~~teld, CA YTi05 DUN AND BRADŠTR~E1' NUMB~~2:"'788-Ö566" . "".. -,- .. 398-8208 R~F~R to-rNSTRUCrIDNs-roR-'PRDPER CODES - - - - I 2 ] ~ 5 & ~ 8 9 10 11 12 13 It Ir~ns lYRe Max Average Annual Mel$ure I rs Cont Cont Cont Use location IIhere 'by Nilles of li~ture{C~,ponents Code Code AIIt A.t Est UnIts on te Type Press Tellp Code Stored In facIlity lit, See Instru, Ions U M 1 1 2 GAL 360 9 1 4 08 Storage Cabinet rusticator Rus~'Remover , Physical ,nd Health Halard C.A.S. NUllber un-asslgne Nile I Ç..A.S. NUllber (Check all that applYI 07064-39-3 0 Hale I C.A.S. NUllber 01341-49-7 COllponent.3 Na.e I C.A.S. NUllber 00112-34-5 1 I 4 108' I Storage Cabinet COllponent 11 Nalle I C.A.S. NUllber 9001-92-7 O ,Co.ponent'2 Nalle I C.A.S. NUllber IllIedllte 9000 90 2 Health - - Skin & EyeC~IIPonent 13 NIIII I C.A.S. NUllber 13 1 4 08 storage Cabinet un H!":l':d gnpr'I COllponent 11 Nue I C.A.S. NUllber CITY of HAKEH~~IELU [] Fire Hazard c.orJ;osi VE}, , COllponent 12 Id):.ìtleactlvlty u Delayed 0 SUddfn Release . 0 IlIlIedllte Health 0 Pressure Health IRRITANT TO SKIN & EYES ~1 I Phrsicel ,pd Health Haiard (Check all that apply o Fire Hazard o React ivity 1 2 [QN] C.A.S. NUllber 360 I 13 R--..JIe lared 0 SUddfn Re I ease ~~ea th 0 Pressure Slight Irritant to GAL U M 1 Physical t~d Health Haiard (Check a I that apply C.A.S. Number o Fire Hazard 0 Reactivity ~ 1 11 Phrsicel 'Ød Health Ha~ard ICheck al that apply/ O COllponent.2 Halle I C.A.S. HUllber ~e layed 0 SUddfn Re lease IlIlIediatl Health 0 Pressure Health . , . COllponent 13 HUI' C.A.S. NUllber Sllght Irrltant to Skln & Eyes 2 ~ 360 I 10 I 1 14 I 08 Istoraqe Cabinet C.A.S. NUllber un-assigned COllponent II Nalle I C.A.S. NUllber O . COllponent 12 Hale I C.A.S. HUllber U Fire Hazard 0 Reactivity [JJC!elayed 0 SuddJn Release IlIudlate Health of Pressure Health . . . COllponent 13 Ha.e I C.A.S. NUllber Sllght Irrltant to Skln & Eyes EMERGENCY CONTACTS "1 Kelley Brown . Dlrector 871-2331 112 Penny Geddes Rille TItle 2rRrPfiðñ¡- Rne Htifjç3tioq (Re~d Bnd $igl1 af1er cçmpletiog all rce.ctiOI1S) ·certlfy un~er pen.llr 0 la~ th4t I have peesona IWl,exalllneq ,qd ,. f..illac wit the In(orllatlon sublltted In this end all ltaçhed dOCUllents ano t at based on .y InquIry 0 hose ndlVldualS responsIble or obtaInIng the Infor.aLlon. I belIeve that the ubftltted Informat on IS true, accurate, and coiplete. !If-J.r~·õrl~f1T-Y1fle 01 ovn~r/ODerator UR ownl17ðJ1rl~1:1ütfið111~ffI1ñt1tlv. S11liUù7I ;,2S Ammonium BIPlouoride 1 (2-ButoxyethoxY)Ethanoì' Devour Protease Am lase Jinx-Ink 2 Isopropyl Acetate o Rapid Spot remover Vlce.Pres. 871-1729 nth RRf'fMñ!- 1IJr,")14r.U-' CITY of HAKEH~fIELV ~1 11 Physical fPd Health Hlflrd (Check a ; that apply ~AZARDOUS MATERIALS INVENTORY ¡If. and Agticulture 0 Standard Business ø N- E E R ET S Pa e 4 of 4 ' NO TRAD S C q ___'.. _ TODAY CLEANERS H Rl.chard K. Newman & AS~~~ nlls FAC 1 #10 ð~IY~ð~;..NAHE: ð200 S'I'uCKLJAL.E HW~ ~~~~S~At' E: 121 ~crey St. STARo2foBINo"'TcRLIE~~N~uÓH'R~~~72I~--:'~..,..:.:~.~~...,.~==: M~~ H t": ---ßAK-ER£.F±m:,f), C", I) 3-3-3:+- ß J. Ÿ ~ ~. P:~~Ë - e ld , CA'::J3 j U ~ DUN A~B RAD\:> ~ r ~~'.l 788 - 0566 ,- 398-8LOt! ' R ~Ml? 'to-INSTRUCTIDNS-FVR-PRDPER CODES - - - - - - - - - . I 2 J 5 e ~ 8 t 10 II . 12 I J U Ir~ns l'Ae Max Annual Meuure I vs Cont Cont Cont Use LocatIon Where 'bv Nues of /i.ture{C~'oonents Code Code Al\t Est Units on Ite 'ype Press JeI\P COde Stored In FaCIlIty lit See Instru:: Ions U M 1 3 GA 360 10 1 4 08 Storage Cabinet Yelllow- GO Physical 'nd Health Hllard C.A.S. NUMber un assigned COllponent t1 Nue I C.A.S. NUllber (Check a I that apply/ 13130-44-4 2 Timnium Sulfate O COllponent f2 Hue I C.A.S4. H_ugl\b.er_g U Fire Hazard 0 Reactivity Jg: Delayed 0 Suddrn Release ·IIIMediate 766 j 2 Sulfuric Acid Health 0 Pressure Health Sl' ht I 't t t Sk' & E COllponent 13 Nile' C.A.S. NUllber 19 rrl an 0 ln yes 3 I~ 360 113 I 1 I 4 108) Istoraae Cabinet C.A.S. NUllber un assigned COllponent" Hue I C,A.S. NUllber 64742-95-6 Nllle ~&~1dJ'f~3 paint/oil/Grease Remov~ Petrnlp1Jm niRtilL:!t-PR o Reactivity ~elayed 0 Suddfn Release 0 IlIlIediate COllponent U Health 0 Pressure Health Slight Irritant to Skin & Eyes COllponent 13 Hille I C.A.S. Nueber et,roleum Distillates o fire Hazard Phlsical ,nd ~ealth Hajard C.A.S. Humber COllponent " Hille I C.A.S. Number I heck I I t at apply o Fire Hazard o Reactivity o De Jared [] Suddf" Re I ease [] COllponent '2 Halle' C.A.S. NUllber IlIlIediate Hea th o Pressure Health COllponent t3 Hille I C.A.S. HUllber ==r=1 I D PhlsiCfl fnd ~ealth ~If~rd C.A.S. NUllber COllponent " Nalle I C.A.S. HUllber (hee a I t at IPP y U F ire Hazard o Reactivity [] O~lared [] Suddfn Re lease [] . COllponent 12 Nllle I C.A.S. HUllber limed late II th o Pressure Hea I th COllponent f3 Na.e I C.A.S. HUllber EMERGENCY CONTACTS ", ~pl 1 Py Rrnwn .D~rpí"t-nr R7~1-r~~1 12 Qrll.ny GE>Ó"E>C:: Rill nt 21ì1nllo e Rill :ertifiç!tiol (Re~d and '$lgn af1tJr cpn'f7etif19 all "ectionsl :·certlfy un~er enalt 0 la th t J nlve pe(Sona Iv exa. n ,d II illilll( It the Inforlllt n U mitt d fn his ,nd all Ittlthed dOCUllen~$1 anX t at ~Ise~ on IY InQuiry 0 lhose In~lvI~UI'S responSlb'e or obtllnlng t~e 'ntorllatlon. t belIeve that the ;ubllltted Inlorllat on T. true, accurate, and co~plet8. vice. Pres nth 871-1729 RRfTfiðñr- ¡f;ë-~r~l)rfcflr-rltle of O~nerlooerator UR Okner/ðPIfltOr'. lutftõ111ea-rIJffffñtItlve S1qñiture PHl"1f4r.èd-' .' Lf-. J 5. . ,- ,BakersfIeld FIre DèPt. Hazardous Materials" Inspection Date Completed B,~·<3(r Business Name: T ~r ~I\UJ) , Location: PJ 2ÓO SW~ \in, U (ì'ò ',' .. Plan 10 # 215-000 (P3~ l\ (Top right comer Business Plan) c Inspector _p.>v.....o ~r - Station No. Shift Adequate Inadequate Verification of Inventory Materials ~ 00 ~ Q R,/ Verification of Quantities 't' ¥ Verification of Location R Proper Segregation of Material ~ Comments: jcJ~ Verification ofMSDS Availability Number of Employees \p RECEIVED AUG 0 7 '989 HAZ. MAT. orv. ~ cÆ~ ~~ t-1\9~~' , D Verification of Haz Mat Training ~ Comments: '\\\~DS rrá ~. Verification of Abatement Supplies & Procedures D Comments: C~ . V r QJ\"v~ I\J ~ C~),ÒJ~ Emergency Procedures Posted D Containers Properly Labeled '0 Comments: ß1 D D D ~ D ~ ~ D " Verification of Facility Diagram ~ Special Hazards Associated with this Facility: D Violations: FD 1652 (Rev. 3-89) White-Haz Mat Div. Yellow-Station Copy Pink-Business Office · .' .. >' \:,,:',,':, <:,(;..;,V "f<'F.~;~U.,;.;"",;;..t_.,;rr,;.;;¡" r:! ·.;;\.j¡;¡f~4,::C..,::,;~,',r., , 0,;f,;,,~,·~:t,' :;"f~¡;:','" ". '.' ;,- , fIIÞ . "."",,,.,,,,",. . ~~~._ ~~. (M~'""'?""""~~"i'-'""/'"''':''' ~ _ Z"- % · r~'~ ~~G-¿)J)J-~ k.t1 r- I~' G~\lt3:):1H Pf/,í?: \" 0 (\11 ^ ',V : " 't.!i,.l...·. .vtO .TÞ·.M .St~H ì /. I /' ''''. - '1;\""<1.- ~ e jA:/?" .~AKERSFIELD CITY FIRE DEPAR.' 2130 "G" STREET ., , BAKERSFIELD, CA 93301 (805) 326-3979 \ :;L ~ -0'013 @ JµSp I I OFFICIAL USE ONLY BUSINESS ~A:"Œ ID# _J b~~ HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE FORM 2A INSTRUCTIONS: 1. To avoid further action, return this form by 000635 2. TYPE/PRINT ANSWERS IN ENGLISK. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIPICATION DATA A. BUSIYESS NAME, ~ ~ 1:t- IQ B. LOCATION I STREET ADDR SS: /i)..b{) ~~ /~ CITY: ~ 0/ ZIP: t,?3' '( BUS. PHONE: SECTION 2: EMERGENCY NOTIFICATIONS " - ~ .____ '_r ~~..._ ,_ ._ ~}1 I( <f I}'J) 3 9' Ý #' 2,-0 f' In case of an ~mergency involving the release or threatened release of a hazardous material. call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as req1lired by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: ~A'f~ MiD íI'ITLE . /7 '/J DURING BUS. HRS. A. rr~ ~ Ph# 3~'}...'f-( B. r.l¡ .~µ G=~Ph" 11.'-'....'1-1 AFTER BGS. !fRS. Ph;: } f J - ~I 2--,-/ Ph# 871'" /77.-? SECTION 3: LOCATION OP UTILITY SHUT-OFPS FOR BUSINESS AS A WHOLE ~: ~~~~~~¿~~O~j~~~~ ~4/-::; -::fjfu i ~<4(~ D. SPECIAL: E. LOCK BOX: YES / é!3) IF YES, LOCATION: rF YES, DOES rT CONTAr~ SrTE PLANS? YES .I ~O ~SOSS? YES I ~O FLOOR PLANS? YES I XO KEYS? YES I ~O - 2.'\ - " ¡' ..~ . r , '" Î .." .' .' SECTION 4: PRIVATE RESPONSE TEA~ FOR BUSINESS AS A WHOtE ~~ SECTION 5: ~. tvd!.i~ SECTION 6: EMPLOYEE TRAINING EMPLOYERS ARE REQUIRED TO HAVE A PROGRA~ WHICH PROVIDES ~PtOYEES WITH INITIAL ~~~ REFRESHER TRAIYING IN THE FOttOWI~G AREAS. CIRCLE YES OR YO A. METHODS FOR SAFE HANDLING OF HAZARDOUS :vtA TER IAtS : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. YES @ B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGE~CIES:... ..... .......... ........ YES cBV C. PROPER USE OF SAFETY EQUIPME~T:... .............. .~NO D. E:'-IERGENCY EVACUATION PROCEDGRES: . . . . . . . . . . . . . . . . . ŒD ~O . E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS:. .., ... ~NO ~~ I~ITIAL REFRESHER YES@ YES áñ? YES NO YES~ YES NO SECTION 7: HAZARDOUS MATERIAL CIRCLE YES OR NO DOES YOL~ BGSI~ESS HANDLE HAZARDOUS :vtATERIAL IY QGANTITIES LESS THA~ 500 ?O<=DS~ A ' SOLID. 55 GALLONS OF. LIQUID. OR 2 0 CUBIC FEET OF A CO~PRESSED GAS:...... YES NO It . certify that the above information is accurate. I understand that this informati n will be used to fulfill my firm's obiigations under the new California Health and Safety code on Hazardous ~aterials (Div. 20 Chapter 6.95 Sec. 25500 Et AI.) and that inaccurate information constitutes perjury. 5 I GNA Tu~E TITLE ~ OATEM 2.v /~¡ 7 32~-- /~~/. ")r) :- , 'J .\ .' .. '~ t. BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY " ~ ID# ------ BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. FACILITY UNIT# FACILITY ù~IT NAME: SECTION 1: MITIGATION, PREVENTION, ABATEMENT PROCEDURES . tv~ ~ '- ~t?~/I9~~~ ~ ~~~. ~ ~~~.~, 7 ~ ~7ðA- ~~. tÁ/~~~ h ~ --- ~7"'- ~ '1 V/~ ""- ~ß~.~~~¡:~~ 1~~ ~~~~ ~~,~ '7 tJ~ SECTION 2: NOTIFICATION k~D EVACUATION PROCEDùKES AT THIS ù~IT ONLY ~ 911 ¢ VQthaLLy ev~cvcl_:6e - 3A - '. . " " :. ¿P .,.~' SECTION 3: HAZARDOUS MATERIALS FOR THIS UNIT ONLY A. Does this Facility Unit contain Hazardous Materials?..... YES NO If YES, see B. If NO, continue with SECTION 4. f No, complete a separate hazardous materials inven ry rm marked: NON-TRADE SECRETS ONLY (white form #4A 1) I Yes, complete a hazardous materials inventory rm marked: TRA E SECRETS ONLY (yellow form #4A-2) in additi n to the non-trade secr t form. List only the trade secrets on fa m 4A-2. YES NO B. Are any of the hazardous materials a bona fide Trade SECTION 5: BY EMERGENCY RESPONDERS SECTION 6: LOCATION OF A. NAT. GAS/PROPANE: B. ELECTRICAL: C. WATER: D. SPECIAL: E. LOCK BOX: YES / NO IF YES, LOCATION: IF YES, SITE PLANS? YES / NO MSDSs? YES / NO FLOOR PLANS? YES / NO KEYS? YES I :';0 - 38 - ~t'-; + ;-' ~. >;-....... -~'-~ . BAKERSF I EJ.D CITY FIRE' DEPARTMENT - .'. ." ,~ "' -, "# . , '". '-. ."-~ FORM 4A-l.. ',._~ -,,\ ;~\ NON-TRADE SECRETS .', HAZARDOUS MATERIALS INVENTORY '~US~NESS::N~ME: Á.~~ OWNER NAME:LL'/:/¡i:,~....... ~.....c;kt-FACILITY UNIT ,~;Ô ADDRESS: i}-()Þ ~ ~ ~ fiJ I ADDRESS: /,),oJ ~r;;..... ~ rrr FACILITY UNIT NAME: CITY. ZIP:~~=~~ ~..uc. CITY.ZIP: ~...h. f/ .11J/1 cu..- '1'~~ðr ' PHONE': . ~ ..:. 1.-ð¡'- " PHONE': A6.('-~!-!"'~/~""1 ,.' 10FF~~~~L USE CFIRS CODE _. " ,-- I ,D. , ~ +' - ", 1 2 3 TvrE MAX ANNUAL CODE A AMOUNT ftfi'1# ~,'D I) ~"/D/ 7() ::-- . fV\ 1 tf MI 2- fit r :> /"\ ~o J... () " .. . , .:' - .'. iF 4 5 CONT UNIT CODE 4~ I~-- 'tJd, ~ ~~ I? 't~ I, '~~ l~' ~oeo ~ J '. " /J J IA L/ 1 I 'lAME: r J.-. FF ., ^ ~MERGE~CY CONTACT: ( H. ~ tJ! 1-? ~MERGENCV CONTACT: 0;; h .~.. >RINCIPAL BUSINESS ACTIVITY: '. .. ,....... " ,.., . + '. 6 USE CODE D~ D,SJ o&" 6Í' 7 LOCATION IN THIS FACILITY UNIT SW~ 5w~ NEE.. ~ ., ~d, . , ok" #1 ~'~ ~ ~, . . 8 ~ BY WT. /00 /00 .("0 . . '10 '. 9 , ¡ -.' Page _,.o.t' ~ .' - . .... ~ 10 HAZARD CODE OR.NlS DIR-!'t1S :!.MLQ öJfA1 S D~M5 o « ht5 \ -- CHEMICAL OR COMM.ON,.NAME II . /J /J . _ II t.-v- Mi." / P ß (/ ~----- ,... fi ., ,f· {)æ~ 7~!rt~~~ ~tA--i-'uJ.-~ ~.' ~ /1. .1 ~ .......- T . .....__... GJ~ -~, ~ t£,.·,t ,/k:~ ,:::;'~' I . ,. . '. ~'-' '.. - 'I.. ,':.J "' ... ~, ".-- '-. ,- . . "'. ' ,~'- .. . ."".. . '. .. ;':' .. -~ . ''''.. ~ ;f " D.O.T GUIDE '.::: . /1 d' /J /7)-" /.,.. " ( TITLE: ,f""" LJ SIGNATURE: JL/b'AII~AA/ £ /L£(L..I/).tA.--. ^ DATE: - TITI.E: h'.A Æ. ~ PHONE' BUS .POURS: 8'()~-~')...s--/1.'" I , ,/ /;) ,,'~ AFTER BUSHRS: K71--..rrf'- l/ ()tt~,L~ PHONE' BUSH()JJR.$: 111).\... ~ ).j'"". 11.'1-/ ~. .. · UP A,.. . 7rTLE' · AFTER RUS. HRS, tor _ ~"" .~H '> ~ - 4A-l - .' -'. , ' '. '.~ ".'~ ".' -;. ::::,,-,".:~: ,. ,:' , BARERSF I ErlD C I TV F IRE cDEP;~~TMÊNT R E eEl V En' '~"-: = ,.' .,...,' .. FORM 4A-l, ." ,""age _ of ~ ,,', :.:, , , " " . NON-TRADE SECR'ETS. 1987 ." HAZARDOUS MATER:I ALS :I NVENTOR~l23 ABUDDSRINEES'SSS: N:A~'E()·~~~~'::· OWNER NAME:~..L,~-1K.~""'--~...A...~S·~A·CrLTl'r UNIT ,:+fro y - /..-.,; ~ I ADDRESS: I~J J?l.trn ~...~ rrr FACILITY UNIT NAME: CITY. ZIP: ~~ . ~? CITY. ZIP: Þ!JI. ~. IHII ~ .:y~;'ðr . PHONE .: _~ - - 1.-ð , ,PHONE ,: Að.\"- ~ !.!""~ '.'1..-~ t IOFF ~~~~L USE CF I RS CODE I. ~~. .'¡···IÍo~?'~ ,.of, . 1 2 3 .. 5 TYPE MAX ANNUAL CONT CODE AMOJJNT AMOUNT UNIT CODE f {D 1tJ. I~ (f /D, 70 1&1. I; 1"\ I ; 'f 'q~ I) M I 2- ~:wf I, M ¡- .3 . ~~ ["2,' /"\ ~ð J-() ~~ o~ 0/ , ~ . . 6 USE CODE D~ ok o&" o¥ 7 LOCATION IN THIS FACILITY UNIT Slu~ 5w~ NEE.. ~ .. ~ ~..- . .. b~ t¡( ~~ ~ . . < . ',,' , . ',... ':". ~~, .¡ t. /: /1 N A ME: r.. i' A .- t-. /1 t.., ^ TIT L E: ~ n~A.I. A'- EMERGE~CY CONTACT: (,~JlA.iJ,.A tJ! 1-1. TITI.E: EMERG~NCY 'C~~~ACT' 0;;. h.~ TITLE, ?RI~CIPALBUSINESS ACTIVITY:,:c.. "~ /1 / A t/ I 'ß " ' 8 ~ BY WT. /00 100 .("0 . , 10 9 CHEMICAL OR COMMON NAME {)~~~~ {)d.~ M-j1~~~ fl_ "r ~ AA.A ~ ~ ~_ \1~ -,(11..JL - ñ ~ V /JA (!~ ...... y GJ~ -~. ~ (J~ 1- '/r~ I 10 HAZARD CODE OR.MS D Jlf't1S ~MLQ. ðJfA1 S ð~¡v 5 f{) If!lt, D.O.T GUIDE . . . ',/1 /J /7L~- / ( SIGNATURE: 1f".J L/.AII __A/ £ /U71.J~ ^ DATE: IYA - ::l..I- PHONE , BUS HOURS: š()[' - ~ "2.-ç-/1.. ~ f I j ~ ' ~ AFTER BUS HRS: .ý"J 2.. - .r.rf t.- V. ~ÇJ¢.../~r-T PHONE 'BUS HOURS: !for _ ~ '15". n~1 AFTER BUS, HRS: rot" - -3"- - So1-l.. ? - 4A-1 , " ....' ,/ . ,.,' .....". . 1 ! . . ;;H' / ~~ VALCLENE ONE PAGE 2 I SECTION V . HEALTH HAZARD DATA / ,SHOLD LIMIT VALUE '--- 1000 PPM ' / EFFECTS OF OVEREXPOSURE Light headedness, shortness of breath, giddiness, possible narcosis, i possible cardiac arrhythmia at high concentrations. No chronic effects are known. I EMERGENCY AND FIRST AID PROCEDURES Inhalation: Remove to fresh air~ Apply artificial resusitation ¡if necessary. Do not give epinephrine or ,other sympatomimetic drugs. Get medical attention. Skin and Eye: Flush with water. . , , ! - SECTION VI . REACTIVITY DATA CONDITIONS TO AVOID UNST AB LE 0 STABILITY Open flames or high temperatures. STABLE ¡¡¡ INCOMPAT ABI LlTY (Materials to avoid) Alkali or alkaline earth metals (powdered aluminum, zinc, etc. ) HAZARDOUS DECOMPOSITION PRODUCTS Thermal: May produce hydrochloric and hydrofluoric acid and possible phosgene. CONDITIONS TO AVOID HAZARDOUS MA Y OCCUR 0 POLYMERIZATION None Known WILL NOT OCCUR IX) SECTION VII - SPILL OR LEAK PROCEDURES Š1 ¿r'S TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILlE,D Ventilate area - especially low areas. d \ I .J Remove open flames. Large spills should be dammed and transferred to closed rums. WASTE DISPOSAL METHOD Evaporate small ,amounts outdoors or send solvent for recovery. Dispose of in accordance with R.C.R.A. and State and Local laws governing hazardous materials. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Speed., type) - Self contained breathing apparatus in high vapor concentrations. LOCAL EXHAUST SPECIAL VENTILATION If large amount is released None MECHANICAL (General) OTHER Acceptable in normal use. PROTECTIVE G'tOVES I EYE PROTECTION Rubber or plastic Goggles or face shield OTHER PROTECTIVE EQUIPMENT '. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING GOOD INDUSTRIAL HYGEINE SHOULD BE PRACTICED l2SoF. Store in cool dry place away from sparks or open flames. Do not heat above Keep tightly covered. Oï ricR PRECAUTIONS Avoid contact witþ liquid or breathing of vapors. We believe ,the ~tatements. technical informati.o,:, and recommendations contained herein are reliable, but given without warranty or 9uarantee of any kind, e~pr:ss or Implied, and we assume no responslbllty for any loss, damage, or expense, direct or consequental, arising from their use. ~. .\ NO· No "'.;,....., .' N' . N'" ,.","""" '. "<" "" T'. >""~'" Th~ ',V'i;)"~':LNUSUAL FI RE AND EXPLOSION HAZARDS ~:.i~:~:i..(;,.",~,\' ~':4 ~11; ~~;! ~_:::';.\ T-LV:·.. . \, .....~,.,NA"'NotApp/icable ;¡ +''\ '. \.' \. . None <, !',; .' . .1. \i ':, ..:;..: . ~!t ~""ö~öL~Un U~ n~~n vapor concen~ra&~ons. , , SECTION III . PHYSICAL DATA Boiling Point (OF) . 117 .6 Specific Gravity (H20: 1) 1.58 . , Percent Volatile Vapor Pressure (mmHg.) 334 (nOy) By Volume (%) 99.5 Evaporation Rate , Vapor Density (Air" 1) 2 . 9 (nOy) , (CCl 4 :1 ) 0.3 ! . - -... .', ..~. "'--" I · Solubility in Water Negligible ~. ...; , . Appearance and Odor , . Clear. colorless liauid with ethereil odor. " -, · .~. '::- ..... SECTION. IV· FIRE AND EXPLOSION HAZARD DATA ¡ ,.. I ....... ...... " FLASH POINT (Method Used) I FLAMMABLE LIMITS 1 Lei I Uel ! ,'None ,(Ta~ Closed Cup) NA " 1 I' ¡ , EXTINGUISHING DWater/Fog D Foam DAlèOhol Foam DCarbon Dioxide DDry Chemical OOther NA··..·,~·, . .-' , . MEDIA SPECIAL FIRE FIGHTING PROCEDURES Use self contained breathing apparatus in confined areas to pre- vent anoxia. Use ~ater to cool containers. Build up of vapors can rup,ture cc:mta.:j.,ners. " " ....'t:.;.. '~i i! ~.~3n ~'. -.......... ·;r;n·í~ -:":.:. ..,~ :r· t ~:n,.2 :'" !'.VJ.1f": ~. .:,; ~.; ..... ",... _.". _v_'" .....-. .~.:: ' SECTION I . MANUFACTURER'S NAME I EMERGENCY TELEPHONE NO. CALED SIGNAL CHEMICAL 201 - 696-7575 ADDRESS 26 HANES DRIVE, WAYNE, N.J. 07470 CHEMICAL NAME AND SYNONYMS I TRADE NAME AND SYNONYMS '. TRICHLOROTRIFIUOROETHANE WT~H 'ANTS VALCLENE ONE CHEMICAL FAMILY I FORMULA HALOGENATED HYDROCARBON C2 F3 CL3 ... SECTION II - HAZARDOUS INGREDIENTS INGREDIENTS CAS NUMBER % TLV,(Units) 1, ,1, 3 Trich1orotrifluoroethane 0(01\ 76-13-1 99+ 1000PPM . - " I I i I . .... j " , , . , I . I · SPECIFIC NATURE OF HAZARD / COMMENTS .C" , . '.'.'1','" ';.. ·...v'· MATERIAL SAFETY DATA SHEET Required under USDL Safety and Health Regulations for Ship Repairing, ShiPbu¡j~jjng, and Shipbreaking (29 CFR 1915, 1916, 1917) --- .~. .... 10/85 ~ bATE PREPARED '.. 1-08500 No. , '. PAGE 1 tt:.'i ~'øul[alf CHEMICALS . MATERIAL SAFETY DATA SHEET "Y' ~.. 24 Hour Emergency Phone (316) 524-5751 V Aoo.. Division of Vulcan Materials Company / P.O. Box 7689 . Birmingham, AL 35253-0689 I-IDENTIFICATION CHEMICAL NAME CHEMICAL FORMULA MOLECULAR WEIGHT Tetrachlorœtly1ene <QC14 165.82 TRADE NAME peISec8 SYNONYMS DOT IDENTIFICATION NO. Perdùorœt1y1ene. Perc m 1897 11- PRODUCT AND COMPONENT DATA COMPONENT(S) CHEMICAL NAME CAS REGISTRY NO. % (Approx) ACGIH TLV·TWA Tetrac1ùoroetly1ene 127-18-4 100 50 ppn ---- III - PHYSICAL DATA . '? APPEARANCE AND ODOR SPECIFIC GRAVITY Colorless. clear 1iquld; 1.62 @ 25/25°C mildly sæet odor BOILING POINT VAPOR DENSITY IN AIR (Air = 1) 2500F (121.1°C) 5.8 VAPOR PRESSURE % VOLATILE, BY VOLUME 13 DIn Itt @ 20°C 100 EVAPORATION RATE SOLUBILITY IN WATER (etœr = 1): 0.1 0.015 gm!100 gm @ 25°C " IV - REACTIVITY DATA STABll-ITY CONDITIONS TO AVOID Stable Avoid contact with open f1aIœ. electric arcs. or otœr rot surfaces which œn œuæ tœnœl decœposi t:fon. INCOMPATIBILITY (Materials to avoid) Str~ axid1zem. 1ør1U111t 11 ttrlum HAZARDOUS DECOMPOSITION PRODUCTS Hydr<gen dùor1de. plDsgene. clùoIine. HAZARDOUS POLYMERIZATION None , 1. ~:~ v - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method used) N:me (TeC) EXTINGUISHING AGENTS N/A UNUSUAL FIRE AND EXPLOSION HAZARDS Tcndc gpses fonœ.d by tœnnal œcanpœition. Firefightem ressure breat rab.1s ani avoid skin contæt. FLAMMABLE LIMITS IN AIR N:me s1Duld wear se1f-containoo, positive- VI- TOXICITY AND FIRST AID EXPOSURE LIMITS (When exposure to this product and other chemicals is concurrent, the TL V must be defined in the workplace,) AŒIH: 50 p¡:m 1WA (8 hr), no sm œHA: 100 p¡:m 1WA (8 hr), 200 p¡:m Ceili~ (for peåt corx:entration refer to 29 CFR 1910.1000 Z-2) (~or tbresrold appradnøte1y 50 ppn; causes olfactory fat:igue.) Effects described in this section are believed not to occur if exposures are maintained at or below appropriate TL Vs. Because of the wide variation in individual susceptibility, TLVs may not be applicable to all persons and those with medical conditions listed below, MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Alcd:1olism, acute ani d1rOlÚC liver diseæe. rhytlm disoIrlem of tœ œart. ani nwritis. ACUTE TOXICITY Œlnhalation ŒI Skin Absorption Primary route(s) of exposure: o Ingestion Inhalation: Mijor potential rwte of eKp08ure. 100 p¡:m for 7 OOuIS causes mild irritation to eyes, nœe, ani tlrœt; flushing of face ani næk; hea:lache, slurroo sJEech, ani dravsiness. 200 p¡:m for 1 bJur causes tœ sæœ symptoms, plus dizziness ani lightœale.dness. 600 p¡:m for 10 mirutes causes seæation of runDness aramd IlDUth, dizziness, ani incooniination; 2,000 p¡:m Calses mild narcœis within 5 m1rutes. 5,000 p¡:m canmt g!nerally be tolerated ani causes ver- tigo. naJsea. ani rœIltal confusion. thcoœ.:l.œsness or œath can ocwr at extraœly high con- ce1t:ratioœ or on prolo~ed exposures abCNe 500 p¡:m. Skin: Pro1o~ed or repeated coot act of liquid can cause irritation, defattirg of skin, ani denoatitis. Prolo~ed single exposure can result in pr<gressively severe ~ seœation ani rooness. Absorption of liqul.d thrwgh intæt skin is possible, causing systemic effects, rot this is an unlikely rwte of significant exposure. Eyes: Li.qul.d in eyes prcxiuœs pain ani irritation with mild tanporary datœge possible. Vapor can irritate eyes. Ingestion: Single dœe toxicity is JIDderate ani causes severe gpstraintestinal irritation with naJsea, vomit~, stomach cramps, ani diarIhea likely. If \œIit~ OCQ1IS, perdùoro- etlylene can be aspLrated into hmgs, \thich am cause d1emi.ca1 ¡nwIIDnia ani systemi.c effects. .. FIRST AID Inhalation: Ramve to fresh air. If breathing has stopJEd, OOminister artificial respLration. Call a physician. Skin: RerlDve contaminated clothing ani sroes. W:lsh exposed area with 1arge qæ.ntities of water. Wash contaminated clothing before rwse. Eyes: Flush eyes inmEdiate1y with water for at least 15 mirutes. If irritation pemists, call a physician. Ingestion: Ib nct: iniuce \Omi.ting. Contæt physician or aœxgeœy tœdi.ca1 facility :inœ- diate1y. Nom TO PHYSICIAN: Mrena1.in slnuld ne\1er be gi.ven to pemoœ OI1erexposed to perchlorœtlylene. i' '-., '-.../ ',---" --- :. "':""'. 'f. .,;..... '. . CHRONIC TOXICITY '!be fin:li~ of d1ronic toxlc effects in laboratory an:imùs 1IBY iniicate taxicií¥ to huoaœ. O.rer- exposure srould be avoided, failure to do so cwld result in injury, illness or even death. PerdÜorœtly1ene has caused liver anilddn~ toxic effects in d1ronically overexposed experlm:mtal '-.-/ an:imùs. Carcincgerú.ci ty: Three studies have been corrlucted to asæss the carcincgenic ¡x>tential of perd1loro- etly1ene in laboratory aninels. In one study, rats ani mice \<ere exposed by gavage (forœ-fed) at levels of 500 ani 1000 IrYllkg/ðay. Increæed incidence of liver tuIIDIS ~re olserved in mi.ce. 'Iha results of tœ rat study ære incoœ1usive due to an excess in animal deaths. 'Iha secord study in- volved rats exposed to coœentrat:ioœ up to 600 p¡:m via irhalat:ion, six bJurs per day, 5 days per \<eEK for one year. 'Iœ an:inøls \<ere o1:setved until tœ ti1œ of death or until tœ 31st IIDnth ani studies irdicate no statistically B~icant increæe in tuIIDIS. 'Iha s~icaœe of tœ secord Stlldy has been qœst:ioned, since exposure lasted for only one year. A third study corducted for tœ Nat:ional Toxicology Prc:gram (NIP) involved exposure of mice to 100 or 200 p¡:m ani rats to 200 ani 400 p¡:m for six l-ours per day, 5 days per ~EK for 2 years. Increæed incidence of liver tlUIDIS ære olserved in mice. In rats an increæe in a rare kidn~ tunDr was olserved in tœ t1Ble rat, ani bcxh tmles ani feœles had an increæed incidence of mnoruclear œllla1kemia. The Internat:ional Agerr.y for Caœer Researd1 COIBidem liver tUIIDm in mi.ce as limited evidence of animal carcincgerú.cií¥. Epidemiolcgic studies have been incoœh1sive in detetmi~ ntœr perdùorœtly1ene causes cancer in humaœ. PerdÜorœtly1ene has been identifiai as an ani.nal carcincgen by NIP, 00t: is net: listed on the !ARC, OæA or NIP, cardn~en lists, as of Deœober 31, 1986. Repraluct.ive Toxicity: Studies on mce, rats ani rabbLts have been corduct.ed to evaluate tœ poteŒial effects perdùorœtly1ene 1IBY have on repraluction ani offspr~ of laboratory an:imùs. Bard1loro- etly1ene has been found to be eubryotoxic ani has caused delays in the develq>tœnt of fetllses. Perd11orœtly1ene has net: caused teratogelÚC (bi.rth defect) effects in experiJœntal arrl1œls. --- --- VII - PERSONAL PROTECTION AND CONTROLS RESPIRATORY PROTECTION Where vapor conœntrat:ion excee:ls or is likely to exceErl 50 p¡:m,' an apprOled ozganic vapor type respirator is acœptable. Ap¡:ro.red æ1f-containai breat~ appiratus or air line respirator, with full face piece, is ra¡uLred for vapor conœ~rat:ioœ abwe 500 p¡:m am for spills am/or emezgerx:ies. Folw æ:y applicable resplrator use starrlards or regulat:ioœ. VENTILATION Do not use in cl.œed or confined spice. Open doom ani/or winiows. U3e ventilat:ion to IIBintain exposure levels below 50 p¡:m (1WA). ' SKIN PROTECTION Wear solvent-resistant glOl7es such as Viton, ¡x>lyvinyl alcchol, or equLvalent. &Jvent- .. resistant boOCs, apron, œa:i~ar ani/or faceshield sh>u1d be worn .re splas~ is a possibility. EYE PROTECTION Wear safety glasses. <bntæt lemes sbJuld net: be worn. 0enica1 goggles ani/or face shielœ srould be worn ftre splashing is a pœsibility. HYGIENE Avoid contæt with skin ani avoid breathirg vapom. ID noc eat, drirk, or stIDk.e in worl<. area. Wash harrls prior to eating, drinki~, or usi~ restroan. lv:Jy clot~ or sh>es ~ becœe con- taninated with perchlorœtly1ene sh>u1d be reroved imrædiate1y ani th>rwghly 1aunderErl before æarirg ::Iø'::Iin. OTHER CONTROL MEASURES To detetmine exposure level(s), mnitorirg sh>uld be pe1fonœd regularly. Safety srower ani eyewash stat:ion sh>u1d be available. Nom: Ptocective a:¡uLprœnt ani clothirg slDuld be selectai, used, ani tmintainErl accoIdirg to applicable starrlards ani regulat:iom. For furtœr infonnat:ion, contæt the clothirg or equlp- ænt tmrufacturer or tœ Vulcan cœmtca1s Tedmical Service Departtœnt. . . .......;;. ,f' ..; .. '~ VIII- STORAGE AND HANDLING PRECAUTIONS Follow prå:ective controls set forth in Sect:ion VII nn hani1irg this prcxiuct. Store in labeled, tightly sealed containem in a cool, dry, wall-ventilated area. Prevent \tater or mist air fran eI1te~ storage tad<s or containem. Ib nå: œt or ~d on empty or full ,dt\1IlB. Alumi.rum a:¡ui.pmant sh:>uld nå: 12 used for storage am/or traæfer. ',-/ Vapom are heavier than air am will collect in lœ areæ. Do nå: I'E!DDVe or deface label. Do not rwæ drum witrout recyc1irg or recoalitioniI{1; in acconianœ with any applicable federal, s tate or loœl Jaws. IX - SPILL LEAK AND DISPOSAL PRACTICES STF:'¡:~E TA~ IN CASE MATE~ IS RE~SED O~ SPILLED hirg Dlke area to contain sp1.l1. Clean te t area, vent te, avo d bteat vapom. up area (wear prå:ective 8J.ui.poent - refer to Section VII) by mpp1.rg or with aœor12nt matetial ani traæfer to clœed containem for dis¡œal. Avoid contæd.natiDn of gramd am surface ~tem. 10 not flush to sewer. If sp1.l1 OCQ1IS inloom, turn off œatirg ani/or air coniitiDnirg systeœ, to prevent vapom fran contamnatirg entire hrlldlrg. WASTE DISPOSAL METHOD ReOO1eœi 1iqui.ds may 12 sent to a liceæed. recla:úœr or ind.neratiDn facility. Contæd.nated matetial uust 12 dis¡œed of in a pemd.tted waste ~nt facility. Coœult federal, state, or loœl dis¡œal ætrotitiEB for ap¡rwed proœdures. ''--../ X - TRANSPORTATION DOT HAZARD CLASSIFICATION OlM-A Wen traœporte:l in containeIS excee:lirg lIb or nn traœported by air in any quantity. PLACARD REQUIRED None LABEL REQUIRED Label as m¡ui.re:l by OSHA Hazatd Camunication StaRiatd, ani any applicable state ani loœl rEgUlat1oæ. ŒM-1\. label ra:¡ui.re:l for containem exœe:lirg 1 lb. . Medical Emergencies Call collect 24 hours a day for emergency toxicological information 415/821-5338 Other Emergency information CaI/316/524-5751 (24 hours) Jaroary 1, 1987 For any other information contact: Vulcan Chemicals Technical Service Department P. O. Box 7689 Birmingham, AL 35253-0689 205/877-3459 8 AM to 5 PM Central Time Monday through Friday DATE OF PREPARATION: , ----- NOTICE: Vulca'n Chemicals believes that the information contained on this Material Safety Data Sheet is accurate, The suggested procedures are based on experience as of the date of publication, They are not necessarily all-inclusive nor fully adequate in every circumstance. Also, the suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements, NO WARRANTY, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHERWISE IS MADE. Fonn 3233-581 VMC-3239 '\ ~.I . r.....,--!.·:~., '" ~ ~t' ·t~~;.·~~,::-~. " . 0 L Ii., \ r . .,~..~ t~E.;)¿~4~.l.~ ~,~ rArERIAl SAFETY DATA .EE1 r- Ei·' ... -.. 0':., _ IAl>o.oved by U.S. Oeo.llmenl 01 L..bo. "Essen1i.lly Simil.'" 10 Fo.m Lsa·OOS·41 ,,- '. '-.' __.-iE~1ICAL NAME: PRIMARY AMYL ACETATE SYNONYMS: CHEMICAL FAMILY: Esters FORMULA: CHJCOOCSHl1 (mixed isomers) MOLECULAR WEIGHT: 130.19 TRADE NAME AND SYNONYMS: Primary Amyl Acetate fE;ii~·"'''''f ' . ..- ,., ·~::I\·~·~¡"-·?""'r-::;¡··"!!:"'~~'·-":"·"'1 ~""-P""''''H~ .y'- S·· · ·C·A' ;:"L·UI"""""ODA"''''T·-A~cr.~.".·~\'.¡'·r::''"I'''~~t'''~;..;:.: ''7.~:.:'''.~ ~'~~...... ~:~£·:;':~:~}ir:S?.:!,::~~~ :'g",'.:(~~ {:,:~-:J:':¿:,~X ~·:.:S~~~''; ',_~,~ ... '. . . -.... .~ ~':·à>;:;::'(~:;~~:~:~Úhi:;;,,;· ',': r ! .:". .=~: ":. .... .J . .... . . .~. .. -'~ = --...... .....1. .. "' ----.........,.......&~~.,..1'& .. . .. ·Set toglass'~-- BOILiNG POINT, 760 mm. Hg 146°C. (294.8 of.) FREEZING POINT below - 100 °C. SPECIFIC GRAVITY (H20 = 1) 0.8757 at 20/20 °c. VAPOR PRESSURE AT 20°C. 4 mm. Hg VAPOR DENSITY (air = 1) 4.5 SOLUBILITY ° 0.2 IN WATER, % by wt. at 20 C. PER CENT VOLATILES EVAPORATION RATE 0.42 BY VOLUME 100 (Butyl Acetate = 1) - I ~F""'~' ~""Y'f:(~'~~~""~' .-.~.~-- .- ~ "~,""""""-""""'- .d....,..~ ...... ,.,.. -. . , ';î:!:;,,,-:.~~:..'.~,::~::....::~;;y.;;'y::~;/';'~:',..:'::~~;::" '" ',:' ·H· Äl· ' ARDOU· S· INGREDIENT' S·· :..,:,: . :-' ~.:.'":.:.~.' :~,':::':':~~~'-::;~~:~';.~: 7:·"::.·-·~:~~ >.:~ ..' .' ..:;:L.,,~·· ~~.. --.~ .:'.' ". APPEARANCE AND ODOR Water·white liquid; mild and characteristic. .....~~b. ..... ... - -...-.,.,....... ,. ...........---.------.-:-----------.-.....--- - ___.0.-. ...............'"'-- _ MATERIAL % TL V (Units) n·Amyl Acetate -60 ACGIH 100 ppm. OSHA (2·Methyl ButYl Acetate) : -35 Not established (3·Methyl Butyl Acetate) - 5 Not established (See Sections III through V III) '. . ....~.".-AJ. .. ._..,,~.~~.~-:-- h. ......~,,~.~ aI ....,...fOI!I!-......~ . J"'~"'''_~'''''T.~ - ..__.._...... . . . -......... .. ...... .~-!.""'-~~-:~_.... . . .... '" ,,-' ~;....;.....,.. ..~.:-,:..: ..... ::'.: "'~' III' li£S:~2~·~~=··~~~··t~·.s.·;~ .. .'.. FLASH POINT I (test m~thodl 101°F., Tag closed cup FIRE AND EXPLOSION HAZARD DATA ..., --~~~~r~~V~~~-r·-oI--·~·--7;:·~F~:·--~~~·'-_·· . LO~ER I 1.1 I UPPER I 7.5 FLAMMABLE LIMITS IN AIR, % by volume EXTINGUISHING MEDIA Use carbon dioxide or dry chemical fõr small fires. Use alcohol foam for large fires. SPECIAL "FIRE FIGHTING PROCEDURES Water spray will reduce intensitY of flames. UNUSUAL FIRE ArlO EXPLOSION HAZARDS None ;0-. ~~~::;:1~EZi:~·a~~~~;:;?=-s.~ E Rq¥NèÿpHÓÑË·~~~f~a~[,:~·:~~~·::::~?:~·=~:~:=;~;~:::.::.;.: ~~ . 3041744·3487 This number is available days, nigh", weekends, and holidays. "- Whd~ Un.on C.'Þlde COløo,atlot\ believel that the data conta.t\ed here.n ale factual and the oPinions eap,",ed ar. tho,. of Qualified .. petti Ut';II(2· ¡ng the '.\""'11 of thl teu, con(Jl",lcted. the data .r. not to be taken ,IS a w."antV or repr.,entltlOn for whach Unton Carb,øe COtpo,.t.on a"...m.. I~'I re,¡)Q""Þ.htv. They 4'. offered SQlely for your con,ider.tion. inv.'t.gation. and vet.fic.tion. Any "s. of thil d,a,a ana information m.." Þe deu,m,neo ov the u'.' to I:e in eeeo.d.nee ....ith epplieaOle lede,.I. ,tate .nd loe.lla....' end ,egul.\tonL \ UNIO~ C,\RSIDE CORPORATION. CHEMICALS AND PLASTICS. 270 PARK AVENUE, NEW YORK. N.Y. ,oon ~~.~~;::J-::::.~~:~:·:~~:.:~:~:::ç:.-'7:·::~:;t:';:·<:\:'~~7:"'~:(~'~,"~"' --. _"'Too ~.,- ....r..~..~.. " ., n.',. 4~:::~~;\?'2?;.::~:I~:'~:;Y~·~:;~~·:·;:;:~=:" ; _....:..:.:.~;" ,.,._..~~..,.-:.:~....¡-:-..~..;~...~.~.....I~.. HEALTH HAZARD DATA.. '<~Vd""''-':'~'''''':'':' ~;::.. .;.,~..:.... ~.:. ,.' '. . .~"':.....;~.~....~..·~L....._~..,;, .',:"rJ_.~.. ~,....' It._. ' ~..:.:........".........:...-." -I~K~'.........~-I·""""-....:..I: ..,.;:.:...:þ....~:..~~~....:.:.........<..~.,~....~~.&.:~...... ". THRESHOLD LIMIT VALUE See Section II. TLV data based on ACGIH (1975) and OSHA CFR 29 §100a Table G 1. -\ .j EFFECTS OF OVEREXPOSURE Dizziness, nausea, vomiting, headache. Contact with skin may be irritating. , I . EMERGENCY AND FIRST AID PROCEDURES Remove to fresh air and administer oxygen. Call a physician. Wash affected skin areas with water. Flush eyes with water. .~~~.'"':.:.. ~i:''':''''''~''. "::. ~.,,:":"·:;·\~~·.1"'~;:.:t;"~:'~.i~£~,:~':F·~::!o-':.~..~...":~.J.~ I." .. J-:"..:..._._ "'~..."~ .r..~.~"''''',-,,~,: ~ ;-"1"'" ·":".::~."!'~~;'2:";;.·:.';.~:,:;:t~~t. .! ,?T¡.··.:~;'!w.~,-.~-:J~·.;~~r.~~::~'_::...:.,'.. ~ '2:':-, "'- ....,...~...... "".. ...-...., .... ...,.... 'V REACTIVI1Y DATA' .' '--".,. ......... ...' . . ~.. ..... ..-.. . ·_·.:~i·:~7.:.;~~i..:.:..'··:·>~·¡::..:~~:.::.1·~~~::::.'~:~~~.~:s.~:L¿':~~.~:<~"~... .'. ..~ . -. ; ::.;~.~~~~~~i.(..\.,~~~...:'~:\::~¿:: .....~,,:.: .~.. . L .. - .. .-.... . ....~~....................... .~,"-~~ -.... . ... ~....... ...... STABILITY UNSTABLE STABLE CONDITIONS Avoid fires, heat, sparks. TO AVOID ...¡ : -- INcm.1PATIBILlTY (materials to avoid) Avoid strong alkalies or acids. :1AZARDOUS JECO~.\?OSITION PRODUCTS . :A. .DOUS POLYMERIZATION May Occur I Will not Occur I . ...¡ Thermal decom~osition or burning may produce carbon monoxide and/or carbon dioxide. 1 '- CONDITIONS TO AVOID None r ~,""'I:-..~- ...~..."'T ':.' ~...--;t. . .......... ~ ....., -.. r .... c .~~.~..:.. '.' .....-":". ........,___....._"':.. ......_._~.. .~' .... _F' ."".. .. '1--="''''2~ ..Z'r~t'r~--¡- ~ {".~ ..... ,,__ ,.n__ ... .-. ¡,;(-'-':"~;':;~'~,-,/:.~; ·.i.~;>: :'., ':~H··_·':-.-·: ,. ·VI SPILL' ·0' R LEAK PRO CEDURES :·'·:·:'·';'~:~::¡~':':';:i¡~'.·:: .;..'.;-';::':<:. ..'..,.........' . ~~;~:~~;<r~.¡~;£'~:··.~: I~).':~~:·~~·~ :.:.:'.~: .,,:.:'~.....::...~;~..:.;..~.~.~. .: .... .:: ·F. ..... , .... . . .'." .. .. _ ..... . '. ,. . .....; ';'·::;·'~!::~,~:·~;:.:·~:·:'·,;~~i:~.';:~.~~· '~~'~.~'~~..~:~~\:'~.:. '.;' .... . ~JTR~SPAp~ TITL;L:E;D~LTI;~~~ :A~~:' .. 'l'=:~:: ,::::~:~:'~':~:~::::::::~:t::~:::,:' - --_... .~.. .; ....~ . . Larger spills should be collected for disposal. 'ASTE DISPOSAL METHOD Incinerate in a furnace where permitted under appropriate Federal, State, and local regulations. . .. \ ::'1 , ~..' ~ '. ," ¡;-......." -, .~-'t~.._. "'-_'., .~ -.r-- - ,-.---- .~.~.,.,~---.... ... ow. -~..--_--.,.-.-~~-...~-!"f!I>---.._......_ ._~'l~~~:;,;.,.>::~:.,:,/..>,...:.:..". SPECIAL PROTECTION I RMATION ,..,' f;-;" ..- _ . .. .." . .. ...",... . ~ ... . '.. . _ . .ø . .. ~;;~;A;;R~;-;~~~N ' ___~~~A.Þ~~' ~-__._·__""'_4h___'M..__.~_~'~."" -;.....-.. f (specifv type! A.r-supplled mask an confined areas. . ,-' , - LOCAL EXHAUST Preferred SPECIAL -- VENTILATION MECHANICAL I (gener all Satisfactory OTHER -- . _. EYE ¡' PROTECTIVE GLOVES Plastic gloves PROTECTION Goggles OTHER PROTECTIVE Safety shower and eye bath EQUIPMENT E'''' .0- ....... . - .~~.. ·'w .._.'~:;:Ir"-~,:",".._--"'"'7'TY---.,....... ~. - - . J,. ----....-.-~.~-~-P.'!':"........,.~..~~..r-.,,..-.,-. ~~:;;.~,: .;; :·:r-<~··":,í,::< ~~.: . ....."..:~. VIII. SPECIAL PRECAUïlONS ": ,. . . '. ., ~'~~.;.:N"""'~.""'''¡'~''''''''':~~'''~_-a..-...~..~....=~.....,-"..,.,__~....:a.''''''''''____. ",..".............._. ......._ ..J.......................~ftvc...."".......',..· .. ,.... -~._.,.,-... PRIMARY AMYL ACETATE Mixed Isomers PRECAUTIONARY LABELING WARNING! HARMFUL IF INHALED CAUSES SKIN IRRITATION COMBUSTIBLE Avoid breathing vapor. Avoid contact with eyes, skin, and clothing. Keep away from heat and open flame. Keep container closed. Use with adequate. ventilation. Wash thoroughly after handling. FIRST AID: If inhaled, remove to fresh air. If t10t breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. In case of contact, immediatelv flush eyes and skin with plenty of water for at least 15 minutes. For eyes, C311 a physician. Wash clothing before reuse. FOR INDUSTRY USE ONLY " .' , , \. OTHER HANDLING AND STORAGE CONDITIONS .. " F·4J072A 8I76-SM " P,inud in U.S,A. ~~~~~'1.'7.·,.<,:~~~~~~:_22:.··Y ::.~., '~.' . . ". ~"..~ .~..,.~. " .,,~'- -. "." . " _....;:\~.~',.. '- ··'ò'. '", . ". "." ~.: '; :: :. ,> . . ':'" .', . 4" ..' . ."~'_J_""':~_'¿"',/":-,~~,~~,,,,~,,~--~" " . .-"o¡.. '. ....., . '". .,- ,;...~~.i~~~__--'-""-_ :-c~ · Material Safe' Data Sheet ~V~. QUI NTIFIER (In Plant Common Name) Formula 36 ~ / Manufacturer's N~e Garratt-Callahan Company Address III Rollins Road Millbrae, CA 94030 Emergency Telephone No. Other Information Calls Use Number Below (415) 697-5811 (Business Hours) SECTION 1 - IDENTITY Date Prepared July 14, 1986 Signature of Person Responsible for Preparation Common Name: (used on label) (TradeName&Synonymsj' Formula 36 Chemical N~e mixture Cas No. mixturA Chemical Family mixture Formula mixture . ,'. ~, "'" .. ':i .~,~. SECTION 2 - HAZARDOUS INGREDIENTS : .:·\::~'~~::f~;·~ Principal Hazardous Component(sl (chemical & common name(sll % Threshold Limit Value (unitsl ,(;, sodium dichloro-s-triazine trione (sodium dichloroisocyanurate) none* L *TLV of 1 ppm for chlorine Suggested limit of 2 mg/m3 for Formula 36 as a nuisance dust. SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS (Fire & Explosion Data) Boiling Point N/A Percent Volatile N/A Vapor N/A by Volume (%1 Density (Air = 11 Solubility in Water moderate Specific G'ravity(H,o=I) N/A ~vmY1t&~a~ N/A Vapor Pressure (mm Hg) "N/ A Reactivity in Water none Appearance and Odor ... White granules with chlorine odor. Flash none Point Flammable Limits N/A Lower Upper EMxedi~aguisher any in Air % by Volume Auto-Ignition unknown Temperature ~~::~oou~ Wear SCBA, as heat or water may release chlorine gas. High temperatures may also release sulfur dioxide. c Unusual Fire and . Explosion Hazards Thl.s product contains an oxidizing material (organic chlorine donor). Contact with flammable orqanic materials may ignite them. ~ CU-F1 Printed by INTEREG. CHiCAGO, Il60646 1-800-621·5808 SECTION 4 - PHYSICAL HAZAÆ . Formula 36 Stability Unstable O. Conditions Stable Ià to Avoid Incompatability (Materials to Avoid) (Decomposes at 325°F to release chlorine gas.) Reducing materials. Acids. '- Hazardous Decomposition Products Hazardous May Occur Q. Conditions Polymerization Will Not Occur C1{ to Avoid Chlorine gas, sulfur dioxide. SECTION 5 - HEALTH HAZARDS Threshold See Section 2 Limit Value Signs and 1. Acute Symptoms of Exposure Overexposure 2. Chronic E I Overexposure ye or ung Irritation of P'YP ñ;:¡m;:¡g¡::o. damage. eyes, skin, lungs. May cause Medical Conditions Generally Aggravated by Exposure Asthma, bronchitis, emphysema. Chemical Listed as Carcinogen National Toxicology Yes 0 1.A.R.C. Yes 0 OSHA Yes 0 or Potential Carcinogen Program No 5( Monographs No ~ No f1 OSHA Permissible See ACGIH Threshold See Other Exposure Exposure Limit Limit Value Limit Used EmergencÞr and Section :2 Seotion 2 First Aid ocedures Also see IIFirst Aid in Poisoningll page sent with MSDS. 1. Inhalation 4. Ingestion Remove to fresh air and call a physician. Flush with water and call a physician. Flush with water. Call a physician if owe y 0 1ve 01 or raw Induce vomitinq. Call a phvsician. SECTION 6 - SPECIAL PROTECTION INFORMATION ersists. 2. Eyes 3. Skin Respiratory Protection (Specify Type) Ventilation NIOSH dust mask. NIOSH chlorine gas mask if chlorine is rel¥oPáPd. Mechanical Special Other Exhaust Pre f erredJeneral) Eye Protection Chemical worker's goggles or f;:¡('!p ma6k. Protective Gloves Rubber Other Protective Clothing or Equipment Rubber apron SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to be Taken in Handling and Storage Store in a cool, dry area. .. ... . Other PrecautioDs See attached label facsimile. Steps to be Taken in Case Material is Released Or Spilled Keep dry. Sweep up hn+: ño not mix with other æatcrialo. w~~ iHto olean, dry container for disposal. as e ISpOS Methods Äppro'tTE'd waste management faGili ty. '- IMPORTANT I . di te Do not leave any blank spaces. If required information is unavailable. unknown. or does not app y, so m ca . CU-F1 Pri'nted by INTEREG, CHICAGO. IL 60646 1-800-621·5808 (j (-, l ~ c; , r. Material SAy Data Sheet 4~fr~ , IDENTIFIER ( n Plant Common Name) Formula 80-S Manufacturer's Name Garratt-Callahan Company Address 111 Roll~ns Road Mi11brae, CA 94030 Emergency Telephone No. Other Information Calls Use Number Below (415) 697-5811 (Business Hours) Signature of Person Responsible for Preparation March 31, 1986 Date Prepared SECTION 1 - IDENTITY Common Name: (used on label) (Trade Name & Synonyms) Formula 80-5 Chemical Name Cas No. Chemical Family Mixture Mixture Formula Mixture Mixture SECTION 2 - HAZARDOUS INGREDIENTS Principal Hazardous Component(sl (chemical & common name(s)) Threshold Limit Value (units) % None SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS (Fire & Explosion Data) Boiling Point N/A Percent Volatile by Volume (%) None Solubility in Water Specific G'ravity (H.O=l) N /A Evaporation Rate , BuAc = 11 N/A Reactivity in Water Vapor Pressure (mm Hg) N/A Vapor Density (Air = 11 N/A Appearance and Odor MnnE"T"::!tp None Odorless white powder and granules. .. Flash Point None Flammable Limits Lower Upper Extinguisher in Air % by VOlumeN/A Media Any Auto-Igniti<1n Temperature N/A SPI7ial Fire Fighting Procedures Hiqh temperatures may cause release of SO 4 fumes and require self-contained breathing apparatus. Unusual Fire and Explosion Hazards See above. CU-F1 Printed by INTEREG, CHICAGO, IL 60646 1·800·621-5808 -::::-:-- - SECTION 4 - PHYSICAL HAZARDS . Formula 80-S Stability Unstable 0 Conditions Stable XI to Avoid lncompatability (Materials to Avoid) Strong acids. Hazardous Decomposition Products Hazardous May Occur 0 Conditions Polymerization Will Not OccurXD to Avoid See Section 3 \.. SECTION 5 - HEALTH HAZARDS Threshold Limit Value Signs and Symptoms of Exposure 2. Chronic Overexposure Nn n;:¡t-;:¡. Medical Conditions Generally Aggravated by Exposure None established for mixture. 1. Acute Overexposure May irritate eyes or skin. No data. Chemical Listed as Carcinogen or Potential Carcinogen OSHA Permissible tiee Exposure Limit Section 2 Emergency and First Aid Procedures Al so see 1. Inhalation National Toxicology Yes 0 LA.R.C. Yes 0 OSHA Yes 0 Program No XJ Monographs No Q{ No ~ ACGlH Threshold tiee Other Exposure Limit Value Section 2 Limit Used "First Aid in Poisoning" page sent with MSDS. T-f nIB:t- ;~ :i,..,..;t~tinO'I "'ernoue to fresh air. 2. Eyes Flush with water and call a physician if irritation persist¡:;. 3. Skin Flush with water and call a physician if irritation persists. 4. Ingestion Drink water and induce vomiting. Call doctor. a SECTION 6 - SPECIAL PROTECTION INFORMATION Respiratory Protection (Specify Type) Ventilation Normal room Protective Gloves NT()8H ð'l$t mask~f q~st is a pr~blJu¡t. Local echamc pecl Exhaust (General) Other Rubber Other Protective Clothing or Equipment Rubber apron Eye Protection Chemical worker's goggles or faC'!P m;:¡sk. SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to be Taken in Handling and Storage Store in a cool, dry area. .. Other Precautions None Steps to be Taken in Case Material is Released or Spilled Sweep Up. Small spills may be flushed to drain with water. Waste Disposal Methods Approved waste management facility. \..... IMPORTANT Do not leave any blank spaces. If required information is unavailable, unknown, or does not apply, so indicate. CU·F1 Printed by INTEREG, CHICAGO. IL 60646 1·800-621·5808 *r~~ ~ßtH~ .,K IDENTIFIER (In Plant Common Name) Material salty Data Sheet Formula 101 \...../ Emergency Telephone No. Other Information Calls Use Number Below (415) 697-5811 (Business Hours) ~=~factu'(;ãrratt-Ca11ahan Company Address 111 Rollins Road Mi11brae, CA 94030 Signature of Person Responsible for Preparation Date Prepared November 13 1985 Common Name: (used on label) (Trade Name & Synonyms) Formula 101 Cas No. mixture Chemical Name Formula mixture Chemical .. Family mixture mixture SECTION 2 - HAZARDOUS INGREDIENTS Principal Hazardous Component(sl (chemi<::aI & common name/sll % Threshold Limit Value (unitsl none l~ SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS (Fire & Explosion Data) Boiling Specific Vapor Point C ire a 212 0 F Gravity (H,o= 1) 1. 0 1 Pressure (nun Hg) Percent Volatile Vapor Evaporation Rate by Volume (%) 93% Density (Air = 1) unknown ( BuAc = 1) < 1 Solubility Reactivity in in~w ~w .-, .....~. ," . unknown Appearance and Odor .. complete none Black to brown liquid with musty odor. Flash Point none Flammable Limits N/A in Air % by Volume Lower Upper Extinguisher N/A Media Auto-Ignition Temperature N/A S~ial Fire FIghting Procedures none , L- Unusual Fire and Explosion Hazards none . " .. CU-F1 Printed by INTEREG. CHICAGO, IL 60646 1-800-621-5808 S~CTION 4 - PHYSICAL HAZAR. . Formula 101 Stability Unstable 0 Conditions Stable IX to Avoid I ncompatability (Materials to Avoidl none , Hazardous Decomposition Products none Hazardous May Occur 0 Conditions Polymerization Will Not Occur XJ to A void SECTION 5 - HEALTH HAZARDS Threshold Limit Value none established I ¡ , 'I,:' May irritate eyes.;__ .-. _.0. ,. " ..-" - . -- ..... -. ~ 'cþ',:.J:J Ä '::"-:1 _ L .. _.. ........ ..~ "'1'''o·F.~· . , " Signs and 1. Acute, " , Symptoms of Exposure Overexposure'" 2. Chronic Overexposure no data ~... -.... Medical Conditions Generally Aggravated by Exposure no data National Toxicology Yes 0 LA.R.C. Yes 0 OSHA Yes 0 Program No IX Monographs No }C No ~ ACGIH Threshold see Other Exposure Limit Value Section 2 Limit Used "First Aid in Poisoning" page sent with MSDS. Chemical Listed as Carcinogen or Potential Carcinogen OSHA Permissible see Exposure Limit Section 2 Emergency and First Aid Procedures Also see 1. Inhalation Does not emit fumes. 2. Eyes Wash with water. Wash with water. Call a doctor if irritation persists. 3. Skin -- 4. Ingestion Drink water and induce vomitinq. SECTION 6 - SPECIAL PROTECTION INFORMATION Call a doctor. Respiratory Protection not required (Specify Typel Ventilation normal room Local Exhaust Mechanical {Generall Special Other .! Eye Protection cnem~cai WOrKer'S goggies or face mask. Protective Gloves Rubber Other Protective Clothing or Equipment Rubber apron o SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES Precautions to be Taken in Handling and Storage store in a cool, dry area. ..' Other Precautions none Steps to be Taken in Case " Material is Released or Spilled Contain with absorbent. Small spills may be flushed to õr;:iin. Waste Disposal 'Methods Approved waste manaqement facility. '- IMPORTANT Do not leave any blank spaces. If required information is unavailable, unknown, or does Dot apply, so indicate. t' .' CU·F1 Printed by INTEREG, CHICAGO. IL 60646 1-800-621-5808 ~