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Home My WebLink AboutBUSINESS PLAN ç -, CROS SECTION B ' CALIFORNIA LIVESTOCK SUPPLY/NORIEGA 5 B IV) ~ :t ...: I ~ "" BEND IN ::t $£Cr/ON ~) '-0 r- v ~~~ dr~' "~ ßJfr'l ,---- CONTAMINANT PLUME NOTES: 1. All values listed are ppm T.P.H. gasoline except values in brackets [ ] which are ppm benzene. 2. N.D. refers to None Detected for all constituents tested. 3. [N.D.] refers to None Detected for benzene only. 0.4- 'I [0./) ìT.D. - 50' 'ß~ð ,'^, ..'"", ih\'" ;,. \~ ~þ.t"- COrJ 4.9 (0.~2] 4.9 [0.36J N.D. T.D. - 75' SCALE: 1" = 10' b. R. SMITH & ASSOCIATES Figure 12 I't ~ :t ,.... I SURFAC£ N.D. N.D. 1.4 [N.D.) I. I lo./J 4.8 ['.2) ESTATE NW B' SEPTEMBER 1990 0' 10 20' 30' ~ }.. ~ I¡ Q 40' 50' 60' 70' (}O' r~l AREAL EXTENT OF CONTAMINANT t J'l; PLU~ AT 40 FOOT AEPTH 7,::'êALIFORNIA L~ESTOCK SUPPLy/if/!/bRIEGA ESTATE ~ " ..... CONTAMINANT PLUME \--. ~ t):: J; ~ ~ ~ Test Hole Location - ~ D. R. SMITH & ASSOCIATES Figure 8 ¡" = 10' SEPTEMBER 1990 ¥ ;ã'1 e ~?( ,ê ~' CROSS SECTION A A' CALIFORNIA LIVESTOCK SUPPLY/NORIEGA ESTATE .~" f-r ¡:. ,~;., :;'1~ 1"~ r '¡':" j'ó,' '0 ...!~':;.. 'e ( ,4.'- 4, ;~ ' ., . \' .~, If) ..... -..0 ~ ~ ~ :t:' :t SW .... ¡.... N£ A I I SURFAC~ A' 0' ~~~. " ";\p; .~: ç ~~: ..J~J r~{.( t¡'¡',·,',·,,",t.:,' - ?J",A ' ::1 ~ ','~ ' , .~ " (1 .' \,'" -I (Ó.3 " C"o "'V~ ..,~/~ '4 ?-/ON "".9 1.0 [0.3€.J [0.'0] N.D. T.O. - 75' 5.1 (0.38] . NOTES: . 1. All values listed are ppm T.P.H. gasoline except values in brackets [ ] which are Ppm benzene. 2. N.D. refers to None Detected for all constituents tested. 3. [N.D.] refers to None Detected for benzene only. 1.2 [/11.0.] 2.4 C/II.o. ] T.D. - 95' SCALE: 1" = 10' D. R. SMITH & ASSOCIATES CONTAMINANT PLUME fO' 20' 30' 40' :t '" ~ Iu ~ 50' 'o' 70' 80' 90' 100' SEPTEMBER 1990 '- Figure 11 , ' ,I l " Operil.te Materials/Hazardous Waste Unified Permit to it Per Hazardous CONDITIONS OF PERMIT ON REVERSE SIDE This ermit is issued for the followin azardous Materials Plan ~:[fiJround Storage of Hazardous Materials '" agement Program Waste PERMIT ID# 015-O21.()01293 CALIFORNIA LIVESTOCK SUB SUMNER 531 LOCATION (,I Approved by: Expiration Date: Bakersfield Fire Department OFFICE OF ENVIRONMENTAL SER VICES 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 Voice (805) 326-3979 FAX (805) 326-0576 Issued by: ---- ----'---------~,. tit STATEMENT OF ACCOUNT 4IÞ CITY OF BAKERSFIELD 1501 TRUXTUN AVE BAKERSFIELD. CA 93301-5201 _~"- , . A .N<,""?",' <' f" " ,,-"">- ~ (805)1,326;-3979 ~ : > f r,~: ~ / ~ :: - ~ ~ -~ ~ ~ ~: ¡< TO: //tt \" ,t~:,::"", .,'~) ~< ,'v>. r :" t; \; ~" CALIFORNIA LIVES:rOCK'SUPPLY~'~"',~7-~'v," '::,; . 3105 F ST ",/i\\;;:';;"""'''::_'''::, ,'"c BAKERSFI ELD, i,CA\i~33(}:1 rW ;\~-:;'\Y:3.t:.5Å!¿%, , ',"" "~:,',\,\""r,<,<,_~,:- / < '/~, , _~ 'y ~_,~. ,....-~'+. ''',</1 ; {' ~ ~.. DATE: 9/01/98 , ~"- \,", : ; ',' .~, " ,...¡- ; /i~\:\.~// f~,,", "7 {~~:!' , ' CUSTOMER NO: 1,\";;83707 CUS'rClMÊR':tYPE: ES/ 3376 _________________~~~t~~l~~_~~~__~_~~~~~_~~__________~~;___~~~________________ fr·" '-<'+.11,;'( ". \.; .~"~' _, - ,':',.~ ,,<11, , ~.~ ,.'. --,--' ,'. ,- CHARGE DATE DE:SèRIPTION,,";>,::~;::~h,,;, RER';";NUMBER PU,E!DA'tE TOTAL AMOUNT ______ ________ ~S~1_~~1~_~~:~~~~=~2¡~~£~1~~~~~~~~~_ ~~~__~_~ ______________ ~~,::::,;, ;:;,cz"";,;,:,~/,' ,,"'" '\~ L \' ' ". BEG]Ni\lING BALðNCÈ~}}\ " PA'\~t1ENT \'èc''''~:' ".!, " MR:lhlT REFUND VCRRS' ; ",! ,.,' <..' 8/01/98 7/21/98 8/19/98 .00 128. 50-· 128. 50 REFND -/" , FOR GUESTIONSOR CHANGES TO YOUR ACCOUNT PLEASE CALL THE NUMBER AT THE TOP OF THIS STATEMENT. -------------- -------------- -------------- -------------- CURRENT OVER 30 OVER 60 OVER 90 -------------- -------------- -------------- -------------- DUE DATE: 10/01/98 PAYMENT DUE: TOT AL DUE: 128. 50-- $128. 50-- -.p ~ - e CITY OF BAKERSFIELD CLAIM VOUCHER I Vendor No. I certify that this claim is correct and valid, and is a proper charge against the City Agency and account indicated. CLAIMANT'S NAME AND ADDRESS: California Livestock Supply 31 05 F Street Bakersfield, CA 93301 (AUTHORIZED SIGNATURE OF CITY AGENCY) Date: 08-12-98 Initials of Preparer : CITY DEPARTMENT: FINANCE PLEASE PROVIDE SHORT EXPLANATION OF PAYME (Including Contract Number jf Applicable) This business double paid their Hazardous Materials bill. For that reason they now have a credit of $128.50 which we will be refunding. Fund Dept. Base ,El/Objt Project # Invoice # Amount Date of Invoice 011 0000 123 7900 $128.50 VOUCHER TOTAL $128.50 SECTION 72, PENAL CODE FINANCE DEPT. USE ONLY Section 72, Presenting False Claims. Every person who with intent to defraud. presents for allowance or for payment to any state board or officer, or any county, town, city district, ward or village board or officer, authorized to allow or pay the same if genuine, any false or fraudulent claim, bill, account, voucher, Examined &, Approved for Payment Amount or writing, is guilty of a felony, o;~ ,,,,,,,,-;, :::- ~". ~ . ~ BAKERSFIELD FIRE DEPARTMENT . e - MEMORANDUM DATE: August 5, 1998 TO: Susan Chichester FROM: Esther Duran SUBJECT: Claim Voucher Please issue a Claim Voucher to refund over payment of $128.50 paid by California Livestock Supply. They made a payment on 6/30/98 of$128.50 and again on 7/21/98. The second payment created the credit of$128.50. Please send a refund of$128.50 to: California Livestock Supply 3105 F Street Bakersfield, CA 93301 Thank you, led 'Y~ de ~~ ~p ~0Pe ~ ./6 We/lhU? " .....;~~ '~~ ~ ',....,..... '.... - STATEMENT OF ACCOUNT e CITY OF BAKERSFIELD i 501 TRUXTUN A\iE BAKERSFIELD, CA 93301-5201 (805) 326-3979 DATE: 8/01/98 TO: CALIFORNIA LIVESTOCK SUPPLY 3105 F ST BAKERSFIELD, CA 93301 CUSTOMER NO: 3376 CUSTOMER TYPE: ESi 3376, ---------------------------------------------------------------------------- CHARGE DATE DESCRIPTION REF-NUMBER DUE DATE TOTAL AMOUNT ------ -------- ------------------------- ---------- -------- -------------- 6/30/98 BEGINNING BALANCE 6/30/98 PAYMENT 7/21/98 PAYMENT 128. 50 128. 50-- 128. 50-- FOR QUESTIONS OR CHANGES TO YOUR ACCOUNT PLEASE CALL THE NUMBER AT THE TOP OF THIS STATEMENT. -------------- -------------- --------------- -------------- CURRENT OVER 30 OVER 60 OVER 90 -------------- -------------- -------------- -------------- DUE DATE: 8/31/98 P A YI'1ENT DUE: TOTAL DUE: 128. 50-- $128. 50-- DATE: 8/01/98 DUE DATE: 8/31/98 PLEASE DETACH AND SEND THIS COpy WITH REMITTANCE REMIT AND MAKE CHECK PAYABLE TO: CITY OF BAKERSFIELD PO BOX 2057 BAKERSFIELD CA 93303-2057 CUSTOMER NO: 3376 CUSTOMER TYPE: ESI TOTAL DUE: 3376 $128, 50- ·~ -9" It . CITY OF BAKERSFIELD OFFICE OF ENVIRONMENTAL SERVICES 1715 Chester Ave., Bakersfield, CA (805) 326-3979 INSTRUCTIONS: ~ ~ d7( I'Nß 1. To avoid further action, return this form within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. --~~~--4.-- Be ãs briefánd concise as possible. - -~-'- ., ,. SECTION 1: BUSINESS IDENTIFICATION DATA ~~'5:'( ~ BUSINESS NAME: CALIFORNIA LIVESTOCK SUPPLY 3105 "F" STREET LOCATION: 201 UNION AVENUE MAILING ADDRESS: CITY: BAKERSFIELD. STATE: CA ZIP: 93301 PHONE: (805) 327-0321 77-0003132 SIC CODE: DUN & BRADSTREET NUMBER: PRIMARY ACTMTY: RETAIL FOR LIVESTOCK AND PET SUPPLIES OWNER: DAVE CHERNABAEFF 201 UNION AVENUE MAILING ADDRESS: SECTION 2: EMERGENCY NOTIFICATION CONTACT TITLE BUS. PHONE 24 HR. PHONE 1. 2. 1 . . HAZARDOUSMATE~SMANAGEMENTPLAN SECTION 3: TRAINING NUMBER OF EMPLOYEES: MATERIAL SAFETY DATA SHEETS ON FILE: BRIEF SUMMARY OF TRAINING PROGRAM: SECTION 4: EXEMPTION REOUEST I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAPTER 6.95 OF THE "CALIFORNIA HEALTH & SAFETY CODE" FOR THE FOLLOWING REASONS: WE DO NOT HANDLE HAZARDOUS MATERIALS. x WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIME EXCEED THE MINIMUM REPORTING QUANTITIES. OTHER (SPECIFY REASON) ---~......"._-,.---".......------ ,.. ~....".------- "-.,,-- --. -+---'- - SECTION 5: CERTIFICATION I, DAVE CHERNABAEFF CERTIFY THAT THE ABOVE INFORMATION IS ACCURATE. I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIY. 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND TINA TION CONSTITUTES PERJURY. ESIDENT 03/30/98 DATE SIGNATURE TITLE 2 ~r~# CITY of ~AKEHSHELU RECEIVED Q)t d A t' It 0 OHAZARDOUS MATERIALS INVENToR-J1AY 3 1 1990 '~an 9 ICU ure Standard BusIness 0¡cÆ,tW¡'/I 'I/rsl'-offK NON-TRADE SECRETS Ans'd @2-<;,0.Æ/fJ;¡:j .LPage _____)f_ ,- fI r tJ _ .... ....... ,/,//C'"' ,srcJ (1 ~~.!Ylðft NAME: r§ut2,P~'/j.z:;;(' ~WNER NAME: O/2Þ'o..eA-//tJ,{( NAM~ OF THIS FACILITY: ,-$q~.Lf, ..2Lc.)+'-4-___ tU: :S-~p¡)£1Z T. '___ DDRESS' _~r" ST~ OARO IND. CLASS CODE:J,~~__.__~__~_____¿;(.Q_ _ ¡Ò~È ~~~~":? _n:~.o7.£Li;>. --- 93..30.£__ ~À6~~ á~P:--- --- DU AND BRADSTR~ET NUMB~R' ~·~,~:''iSR.f)HA~-;o.¡:;'3j(P? M1' . REFER TO--INSTRUCTIONS-FOR-PROPER CODES - . - - - - ,--.,.Þ - W _ .:r: 1 2 3 4 5 6 1 8 9 10 II .12 13 Ie Tr~ns Ty~e Max A VI' age Annual Mea$ure , ~ys Cont Cont Cont us~ loc~tlon Whe~e , by »a~es of ~ixture{çorconents Co e Co e Al\t lit Est Un! ts on I te Type Press Temp Co e Store In facl Ity \It See Instruc Ions J:L:WLL'lðo I ~~S-() ~-O_O ~ 365Vo -131 I I LJ I~q FRONJ -C¿JJI-u!. - 13/J r.K ell' , s Phl~ictl ,nd ~eslth HSiard C,A.S. Humber Component " Name I C.A.S. Humber ( ec a, I t at apply )( F ire Hazard o Reactivity o De la{ed ß( SUddf" Re 1 ease ~ Component'2 Name I C.A.S. Number Immed is te Hea th 0 Pressure ' Hea I th Component 13 Name I C.A.S. Number =r=J I D I I I I ~ I Phl~jefJ ,~d ~eslth Hafard C.A.S. Number Component II Name & C.A.S. Number I ee a t at apply ~ '[] Component'2 Name I C.A.S. Number o Fire Hazard o Reactivity o oelared o Suddfn Re I ease Immediate Hea th o Pressure Health Component 13 Name & C.A.S. Number ~ =r=J I D I I l I I Phlsical ,nd ~ealth Hðiard C.A.S. Number Component " Name & C.A.S. Number ( heck a I t at apply o Fire Hazard o Reactivity o Oela{ed o SUddf" Re I ease [] Component'2 Name & C.A.S. Number Immediate Hea th o Pressure Hea Ith . Component'3 Name & C.A.S. Number =r=J I , CI I I I I I Pht~ie~1 ,nd ~eslth ~afard C.A.S. NUllber Component 11 Name & C.A.S. Number I ee a I t at app y o Fire Hazard o Reactivity o De hred [] SUddfn Release [] . Component 12 Name I C.A.S. Number Immediate Hea th o Pressure Health Component ~3 Name & C.A.S. Number EMERGENCY CONTACTS It ì).,p£II}hi,tJPff '" -,.e,o.ll. .1~1£'2 tt2';s/J,fIrt¡ J{E' J..£ 7 -3 ~Þìit~r~- . Tttìe ,Z r on RBllle ' Certifiratio~ \Rerafl I af~~9nr'ftjng ç¡11 rcect,ionS) !cerllyuner. aly,o a ersona /lall1)n 0 III familIar it the InformatIon $U mitte~ in his ond all attaçhed dQe~lIe#~ anij tat... uirl'/f. /~ose Inålvl~ua's responsib1e or obtaIning the In~ormatlon. ¡ belIeve that the 5Ub'ltt.~~,O' " t'Jn ~.. ~-/-90 ../' ~ t rÍ ~~rarorš--ãú1hOr !led representit lYe Slqñãtûfë lin;ë~rão íf1 Vâ n~ iqr.ë'ð '-It ; '1t..:/ 1 "¿-{'f. " r;- L ',' \ , '¡ '\ -; W) . e BAKERSFIELD CITY FIRE DEPARhlli~T 2130 lOG" STREET BAKERSFIELD. CA 93301 (805) 326-3979 RECErVED JUN 6 1988 Ans'd. ........... US I~ESS :iA.'vŒ /ð3-6?~7f ~éÀ Ø/i7 jÞf f 3 HAZARDOUS MATERI.Ai:.S *Cbege .z- BUSINESS PLAN AS A WHOLE~()' FORM 2A /_ e. \Íø2 (yi . OFFICIAL USE ONLY ID:it INSTRUCTIONS: 1. To avoid further action, return this fQrm by 2. TYPE/PRINT ANSWERS I:: E~IGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSI:JESS NMŒCÌ1 !/fo~rvl-4- L,ua-/ho/t S-S! 8. LOCATION / STREET ADDRESS: CITY: 34,f 0 IJ , YvppLtj I stvrv;v~¡rl "r¡! ZIP: 9330:;- BUS,PHONE: (¡oS-) 3 2 7-03 ¿ I SECTION 2: EMERGENCY ~OTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. E~PLOYEES TO NOTIFY IN CASE OF E~ERGENCY: NA~AND TITLYfi/ / DURING BUS. HRS, A . tI:.J:::t2 r 1 -e L::...1t e / l'Ur:J b (J f" f 1- P h# 3 2.. ? - C) .s ¿ ( B .D40 ; IJ {l h p ¡,/VA] h II ~/;I Ph: g..s/~,6 6 s-s- AFTER BUS. HRS. Ph:; ;:(72- J7ðÓ Ph:: g.3 / - )7 I g .. SECTION 3: LOCATION OF UTILIT! SHUT-OFFS FOR BUST~rnSS AS A 'mOLE A. NAT. GAS/PR9¥.ANE: ~ Lu. . e r~e r, Ó f ~~ (p ,:.vIi. B. ELECTRICAL UJ. ftV;¡ -p Bd, .... f ' {J.J, d I'¡V ~ ()V-H-fù t:' C. WATER: D. SPECIAL; E. LOCK BOX: YES ,~ IF YES, LOCATION: ( J .k' rf of- B 0 (.ù ,'IA..) '1 IF YES. DOES IT CONTAIX SITE PLANS? YES / ~O FLOOR PLA~S? YES / ~O ~SDSS? YES ! ~O KEYS? YES! ~O - 2A - e - , :1 ?> -".- ;:: '~<·'0~..:-t ' :' l " j , ~ SECTION 4: PRIVATE RESPO~SE TEA'i FOR BGSniESS AS ..\ \'iHOLE ¡Vó /tI ~ SECTION 5: LOCAL EMERGE~CY ~EDICAL ASSISTANCE FOR YOÚ~ BUSINESS AS A WHOLE /r é" vV (Yl-e D deÞvLev--- SECTION 6: EMPLOYEE TRAINING E~PLCYERS ARE REQCIRED TO HAVE A PROGRAM WHICH PROVIDES E~PLOYEES WI7H IXITIAL A~D REFRESHER TRAIXI~G IN THE FOLLOWING AREAS. CIRCLE YES OR :W A. ~ETHODS FOR SAFE HANDLING OF HAZARDOCS \!ATERIALS:......"..................".......... , B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGE~CIES:,......................... C. PROPER USE OF SAFETY EQUIP~E~T: ... .. . . . . ...... . . . D. E~ERGENCY EVACUATION PROCEDURES:..,......... ..,.. . E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS:. . . . . . . 1X11IAL REBESHER YES ® YES ::0 YES ~ YES :\0 YES ~O YES ~O YES YES ::0 YES YES NO SECTION 7: HAZARDOUS MATERIAL C IRCL~ - NO - NONE DOES Ybü?BGS I:':ESS HANDLE HAZARDOCS :·!..<\TERIAL I:'; Q1JANTITIES LESS n:.~N ,=son ?Or::DS OF A SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A CO~PRESSëD GAS:...... YES ~o . I ~O/' efNtJ bIJ e , certify that the above information is accurate. r under ta.nd that this information '.ÿill be used to fulfill my Eirm's obligations under the new California Health and Safety code on Hazardous ~ateriaIs (Div. 20 C~apter 6.95 Sec. 25500 Et AI.) and that inaccurate information constitutes perjury. SIGNATL~~E S¿a fdl.V',- DATE 6 ---$ -g1 - ~g - , f! >¡.,../ ." - ,:':',-1;'... "\ i, .. e e , " /" ,< /' BAKERSFIELD CITY FIRE DEPART~!EXT 'J 2130 "G" STREET BAKERSFIELD. CA 93301 OF?:CTA~ [SE OXL~ ID~ ------ BUS IXESS X.·\~Œ: ,BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action. this form must be returned hy: 2. TYPE/PRIXT VOGR A~S~~ERS I~ ENGLISH. 3. Answer the questions b~low for THE FACILITY ¡;~IT LISTED BELOW 4. Be as BRIEF and C8NCISE as possible,- FACILITY UNIT:: FACILITY UNIT NA~: SECTION 1: ~ITIGAT!O~. PREVE~lION. ABATE~E~~ PROCEDu~ES If! Ji-tt31<7/19 L. I V S/n /7/ I (!~ ¡/S J Me? /J &'"¿= ¿) (;PI{ if E:S/1¿ E , . '~ SECTION 2: NOTTFTCATTû~ A~~ EVACGATIO~ PROCEDl~ES AT THIS l~ir O~LY () GIZ I? /J-[ C & //Z //l ú ¡e) I (!t19 1-/ c//¿;. (!)l{L 9'/1 .. - .3A - I I 0·[ ·=-'1 L1 Page ÐAK~RSFIELD CITY FIRE FORM 4A-1 NON-TRADE SECRETS HAZARDOUS MATERIALS INVENTORY DEPARTMENT FACILITY UNIT #: UNIT NAME: IOFFICI,A,L USE CFIRS CODE ONLY OWNER NAME ADDRESS: CITY,ZIP PHONE #: o # BUSINESS ADDRESS: CITY, ZIP PHONE #: I 10 HAZARDID.O.T CODE GUIDE 9 fl 7 2. -~ ? ~ 0 8 % BY WT. THIS T IN UN 7 LOCATION FACILITY 5 6 CONTUSE CODE CODE 4 I ()~ç { 3 ANNUM. AMOUNT ~'Z7- 2 MAX AMOUNT 1 TYPE CODE u ry;j( ~ . L /3 3 /:¿" qn L .Y~ 99 .- NAME /- 7 -/()~ COMMON CHEMICAL OR , I ~ µ, ¡Ç '^' Q ð J-5'':¡o'' S .1.,;I..)Q \- S;.." I' f: T UN / ll:¡.. Ppl'A 1 ' /.. eA..h ~/' (Dc9-NtJ, Ä..... ,..s. L ~¿<J..fA -e/ ~~ì.)l.î~~1U , C[OQ , .í I()ðO 9:Q .:£ / (JO ~p e IrJ ! I~ /1 lAI€? -e 1) ó ç. S'I<>,- e s, UJ I !k- I '')"2.. aa L- . J yc¡ é?<.....J- " fool· , i /D P- i --. ¡ i ii ! i>H(~ DATB:0-02-.?1? 'ONE # BU OURS: ð>3(' -~6 rs- ¿¿>31-~1/1.P ' NAM¡qGß>~ "h~"'~ _J'UTLB:~~ SIGNATURB~ EMERGENCY CONTACt: LI _ 1À=t1LL'{\ [-"hertJ&Jhå'P.{L TITIJE:CL...tL ( lL,)R.d--<4~ HRS: HOURS HRS: BUS BUS BUS AFTER PHONE # AFTER " TITLE ACTIVITY EMERGENCY CONTACT: PRINCIPAL RUSINESS / : ....~ A ._~.~':~ I . /' 9 I e e , ~/ / , /' j I" ,SITE/FACILITY FORM 5 DI AGRA..M NORTH SCALE: B '~T"t:'SS YAï~ / ('- -")/~-i'~ '>I-l~ ~eJfo(} A 53/ ð0M.tteF 12.93 -fÎl ~ (. "SI-, :2 52 '?I..OO>,\ : , - :-\,"T~. / ;Nt; ~j;ð FACILIT\:r :\A~'!F.:: r:'~ ~ :- A~ '.J _ (CHECK ONE) SITE DIAG\A~r X FACIL:!Y JIAG~A~ ~C/"., /l) e I' ~-J- ;¡j ,,{Ler ~'Ih ("/' COVÞ¡J'ivt "f - f; L. J'h../"f?J C-- .)'h ...{,~ r ..LJ,... (vi:J \)'\l ) ðf$., L^ $ ~ ~te J ~ ~ Vl ;-f- , ftpf' ) DO Î U ""'<: ~ \~ ,~ \ì ~ fL.,Q ,.< () J L\ Q; ~Où ~ J ~ ~ ,j " or :11° 1 çhr· I ¡¿VJ~ , ~I fr:.J I -. -p..¡S-è(P fs-I 0 -c: S - I ~0 ~ 'f- ~\I ,. 1 ¡/e;k ¡q~, () 'C - r; i-I þ<é'O 1Jd~r' , '" ~/I t- {\ oar"- IC.( r ~ if.; .>\0.__ _. _ _ I o flt€ i' I K. ~~pl(-\' (Inspector's Commetl1:s) : OKLY- - ;')/;' - SITE DIAGRAM (ReqU_' items) . ~...~ "'_.~-_... I. 1. fiJdress: Identify the ~ principle buildings by the Street !lumbers. / Vg, Lock (key) Rox 2. Street(s). Alleys. ~riVeWaYS' and Parking Areas adjacent to the property. Include the street names, vio, ~ISDS Stor01ge Box ~11. Railroad Tracks ~2. Fence or Barrier a. Wire Í' fi' b. Masolll'y Storm Drains, Culverts, Yal'd Drains c. I~ood ~. 0. Drainage Canals. Ditches. Creeks, d. Gates b. Masonry construction ~. ~~. ~. Guard Station Power lines Buildings a. Frame construction c. Metal construction Storage Tanks: rdent ífy the capacity in gal. a. Above ground d. Access Door b. Underground ~. Utility Controls a. Gas c. Water 06. v'Í7. V18. Evacuation Route Diking or Berm b. Electricity :::.. .::::..-:::::=:..::::..~~':==-~ "_. .~:... .._ _ ._.~. ....:...::::-:...._..¿_......_:-:-.~~,.._~~~"""-'""__.4_ _"~' ---.- "._~-~--~-",.~..--- --:>-~~._~-,,------_._.. ..~.--.. ,--- -- .... .' -. - ¥" . . Evacuation Area: Identify the location where employees will lIeet. _._, '0' '. ". _ ~ ~~~-":::',: . ~.~.'::'~_.~:. ,.. '. ::~ _.-..::~::..::~<-,.::~~.~. ~. Fire Suppression Systems: a. Fire Hydrants -- -~-...,.- ,_. -.-' ~.- --..........--».--.. ......-.-- .,,- -~-< ....-~- ,'" ~..-- h. Fire Sprinkler Connections ~19. Outside Hazardous Waste Storage c. Fire Standpipe Connections ~o. Outside Hazardous Material Storage d. Water Control Valves for protection systems ~21. Outside Hazardous Material Use/Handling e. Fire Pump 22. Type of Hazardous Material/Waste Stored or Used (See Below) 8. Fire Department Access TYPE OF HAZARDOUS MATERIAL F Flammable E Explosive L Liquid R Radiological C = Corrosive 0 Oxidizer G Gas P Poison W Water Reacti ve T Tox! c S Solid H Cryogenic D Waste B Etiological Example: Flammable Liquid = FL FACILITY DIAGRAM (Required items in addition to the above) -. 1. Risers for Sprinklers 8. Fire Escapes 2. Part! tions 9. Air Conditioning Units 3, Stairways: Indicate the 10. Windows levels set'ved from highest to lowest. 11. Inside Hazardous Waste Storage 4. Escalator: Indicate the levels sct'veù from 12. Inside Hazardous highest to lowes t. Materials Stot'age 5. Elevator 13. Inside Hazardous MaterIals Use/HandlIng 6. Attic Access 14. Sewer Drain InJets 7, Skyli~hts RECEIVED fJUH 1 6 1989 HA?:. MAT. DIV. ',0 ~~ f2R~· (-~ '~)--~-"0 Bakersfield Fire J:4¡t. ~ Hazardous Materials Inspection Date Completed 6 '. /3 ~ 81 -' , e --- Business Name: L,/.}/,'·blZ(v/4- (.'¡u.eshe-J::. ,.:SC;-40~ Location: S3¡ .5;e;;.rn µc5/2.- Plan ID # 215-000 oOl2Q3 (Top right comer Business'Þlan) Station No. 2 Shift ~ Inspector D'~ Adequate Inadequate , Verification of Inventory Materials ,~ 0', ~ if Verification of Quantities Verification of Location Proper Segregation ofMa~e~al Comments: { , }' . ~:;,' .' ~ . . - f~ , , ' Verification ofMSDS Avail~bility NUD1berofErriploÿ~s . , L-¡' Verification of Haz Mat Traimng ~ Comments: ";. .' Verification of Abatement Supplies & Procedures o Comments: D W Emergency Procedur: Containers ProperI Comments: D'· o D D (§9 D ~ ~ D Verification of Facility Diagram ~ Special Hazards Associated with this Facility: D Violations: FD 1652 (Rev, 3-69) White-Haz Mat Div. Yellow·Station Copy Pink-Business Office .. . "",":, ·r~; ¡-- '..r- .. ( ."-........- ClBVI3:')3H ~)híJr ;\ f ';1i II, ' , ~.. '. I It..- I ;;:.. t.t VIO :::~..M 5AH ...,-.... '. - , , . . .' <~.., . .~r- . ',' : ¡~ '.. f'~: . 6-15" ~ {/16 ... -- ~. 'T;' ,J' .-~~ _".. ·~tÌyìT.,· S .I~ .\ ';",." . ~ :~.. .. -r·o,~ 1 -----' .... . . ...... ........ ........ -. . ---... "--' ........ ....- . .111111 Boehri.er ~, .ßI .. II .....'..011 Ingelheim _I.IM 80E HRINGER INGELHEIM ANIMAL HEALTH, INC 2621 North eell Hiihw,y . SI Joseph, M'$soufl 64502 · Telex 42·6205 . Ph"",. '1&'233-2571 SECTION I. MATERIAL IDENTIFICATION Reviewed: 4/22/85 MA TERIAL NAME: Anchor PerlltCtr In II, 10 J (.ulllflable In'Ktlclde OTHER DESIGNATIONS None CHEMICAL FAMILY Veterinary AntiparasitIc TRADE NAME See Above SECTION II. INGREDIENTS AND HAZARDS % OSHA PEL HAZARD DATA/TOXICITY "Ineral SpIrIt. (.'xed C9,CIO.¡C11 Hydrocarbon.) 80.0 200 ppII ~one Reported P.r~thrln (C~lcal NaIe;(3.Phonox~henYI) "'thy I (+,.) cll-trans-)-(2,2-dlchloroethenyl -2,2-dl..thylcyclo- propane-carboxylate> 10.0 - D50 Oral , Rat 3800 Ig/kg I nert I ngred I toh 10.0 - - SECTION III. PHYSICAL DATA Boiling point at 1 atm, deg C 11.0 Specific gravity, 20/4· C 0.85 Vapor pressure at 15· C, mm Hg Evap. Rate (BuAc = 1) Unknown ' '_ ) 5 .. (.iner.1 spirits) Vapor densIty (Air - 1) 48.3 (.iner.' spirits) Volatiles, % 27.0 , 100 degrees C Water solubility at 20·C Product I. "iscible "ith Water Molecular weight Hot appllc.ble - chelllcal .ixture Appearance & Odor ,.....~ I 1...1It! With I\ttt\r "I .. SECTION IV. FIRE AND EXPLOSION DATA D........t! ..... ..¡.....r..1 C....',rlt.. Flash Point and Method Autoignition Temp, Flammability Limits In Air lower Upper .".. r r r .. I I 'I ". I 'I Extingu'išhing media: Carbon Dioxide,Dry Powder, or Alcohol Foa~. Mater ..y cause frothing. Special fire fighting procedures: NOTE-MIOSH approved SC8~ and full protective gear Is rec~nded fore fire- fighters. Mater spr.y..y be used to cool fire exposed containers cool. If a leak or spill has not ignited, use water spr.y to disperse vapors and protect ~n atte.ptlnv to stop a leak. Water spray aay be used to flush spills away fro. exposure and to dilute spills to non- I....ble .Ixtures. Contain runoff froe fire- fighting operations, as this product contains Ingredients that ..y be toxic to aquatic life. SECTION V. REACTIVITY DATA Stable X Conditions to avoid: store away fro. heat and strong oxidizers. Stability Unstable Incompatible with: Strong Oxidizers. Hazardous decomposition products: C.rbon Dioxide, Carbon ~noxlde, HCI gas and other nox I ous fUfts lilY occur dur I ng cOllbust Ion. Hazardous pOlymerizåtion: May occur Conditions to avoid: Will not occur X None KnOMn. SECTION VI. HEALTH HAZARD I NO. 401-4" Effects of overexposure: Rev.rllblt Ikln tingling or nt.IIbMlI,lkln Irrlfltlon .nd unlltlvlty, untr.I n.rvOUI IYlt.. depr.s.lon,r.splr.tory Irrit.tlon,naUl..,dlzzinesl,lntoxlc.tlon, end narcosll Ir. ao.e of the .dYlrs. he.lth .ffects report.ct tor Ingr.ctltnh conhlned In thl. product. Target Organs: Resplretory Syst..,Eyes,Skln,Ctntrll Nervous SYlt... Primary Routes of Entry: Skin and Ey. Contact, Inhalltlon, I need Ion FIRST AID: flulh .yes with wat.r. Notify physlcl.n 1.-.dlat.ly.Contlnue eye flush until help .rrlv'I, Eye contact: R.-ov. eonta.lnated clothing and wash affected ar.as with loap and wat.r. Skin contact: Inhalation' Re.ove vletl. to fresh .Ir. ~pply .rtlflcl.1 resplr.tlon If Indic.ted. . . . Notify physIcian or poison control center i~ediately. DO NOT Induce vOMiting. IngestIon: SECTION VII. SPILL, LEAK, AND DISPOSAL PROCEDURES Contain spill to avoid conta.lnatlon of .nvlronaent. ~bsorb spill using sultabl. absorbent SPILLS. LEAKS: (ver.icullte, .tc,), drUII up into steel conhlners for legal disposal. Dispose of cont.iners and unused product In .ccordance with loc.I, State, and federal Haz.rdous DISPOSAL: Waste Reguletlons. SECTION VIII. SPECIAL PROTECTION INFORMATION Respiratory protection: NIOSH approveO resp I rator equipped wi th organic v.por/pest I c Ide cartr idge. Ventilation: area. Protective gloves: Eye protection: Id. Other protective' equipment Protect I ve outer clothing (long sleeved), rubber boots, rubber or pi est I capron. SECTION IX. SPECIAL PRECAUTIONS AND COMMENTS Storage & Handling Information READ AND FOLLOW ALL LABEL DIRECTIONS DO NOT use near open fla... Store away fro. heat. Keep container tightly closed when not In use. DOT'Class Insect I C ide,llquld,NOS F I.....bl. liquid APPROVALS: DATE: Judgements as to the suitability 01 inlormation herein lor purchaser's purposes are necessarily purchaser's responsibilily, Therelore. although reasonable care has been taken.in the preparation 01 such inlormation, Boehringer Ingelheim Anima' Health. Inc e~tends no warranties. mikes no representations and assumes no responsibility IS to accuracy or suilability 01 such in'ormation lor application to purchaser's intended purposes 01 lor consequences 01 its use, 9·2'-'/)' C:¡/t7/~ .......... . _. ,........ _ V". .;;.'. . "" 1"'\ . """ .,; I I L.. L. I Baehr.ger Ingelheim BOEHRINGER INGElHEIM ANIMAL HEALTH,INC 2621 North Belt Highway. 51 Joseph, Mls!,()ur, &4502 . Telel: 42·6205 . Phone 816·233·2571 SECTION I. MATERIAL IDENTIFICATION MATERIAL NAME: Anchor Perllectrln livestock and litter Dust OTHER DESIGNATIONS Reviewed: 4/19/85 None CHEMICAL FAMilY Veterinary Antiparasitic SECTION II. INGREDIENTS AND HAZARDS % TRADE NAME See Above OSHA PEL HAZARD DATA/TOXICITY ThiS product contains no hazardous Ingredients as defined by 29 eFR Part 1900,Hovember 1983. SECTION III. PHYSICAL DATA Boiling point at 1 atm, deg C Not Appl icable-Sol id Vapor pressure at 15° C, mm Hg V d 't (A' 1) Unknown apor ensl y Ir = Unknown Water solubility at 20°C SI ightly Soluble Specific gravity, 20/4°C Not appl ¡cable-Powder Evap, Rate (BuAc = 1) , Volatiles, % < I J Hot Applicable-Powder Molecular weightHot appl ¡cable - chMical lIIixture Appearance & Odor SECTION IV. FIRE AND EXPLOSION DATA Flash Point and Method Autoignition Temp, lower Extinguishing media: Not Applicable-Product is Non-Fla~ble. Upper Special fire fighting procedures: Not Applicable-Product will not ignite. SECTION V. REACTIVITY DATA Stable X Conditions to avoid: None Known Stability Unstable Incompatible with: No Known I ncompatab I I itles. Hazardous decomposition products: Hone Known Hazardous polymerization: May occur Will not occur X Conditions to avoid: None Known. SECTION VI. HEALTH HAZARD INFORMATION Effects 01 overexposure: ' ,At very high exposure levels, the active ingredient In this product has been report- ed to cause the following adverse health effects: reversIble skin numbness or tlngllng,skin irritation and sensitivity,central nervous syste. depression,resplratory irritatlon,nausea,dizziness,intoxtcation,and narc( gis. Target Organs: Respiratory System,Eyes,Skin,Central Nervous Syste.. Primary Routes 01 Entry: Eye and Skin Contact,lnhalation,lngestion. FIRST AID: Eye contact: Flush eyes with water. Notify physician immediately.Continue eye flush until help arrives. Skin contact: Remove contaminated clothing and wash affected areas with soap and water. Inhalation: Remove victim to fresh air. Apply artificial respiration if indicated. Inges~ion: Notify physician or poison control center immediately. Induce vomiting if victill is conscious- Never induce vomiting in an unconscious person. SECTION VII. SPILL, LEAK, AND DISPOSAL PROCEDURES SPillS. lEAKS: Contain spill to avoid contamination of environment. Absorb spill using suitable ab90rbent (vermiculite, etc,), drum up into steel containers for legal disposal. DISPOSAL: Dispose of containers and unused product in accordance with local, State, and Federal Hazardous Waste Regulations. SECTION VIII. SPECIAL PROTECTION INFORMATION Respiratory protection: NIOSH approved respirator equipped with organic vapor/pesticide cartridge and dust filter. Ventilation: Use product in well-ventilated area. Protective gloves: Rubber, Neoprene or Viton. Eye protection: Safety Glasses/Goggles Other protective equipment: None spec i a Ily recommended. SECTION IX. SPECIAL PRECAUTIONS AND COMMENTS Storage & Handling Inlormation READ AND FOllOW All lABEL DIRECTIONS 00 NOT use near open flame. Store away from heat. Keep container tightly closed when not in use. DOT Class Insecticide,Ory,NOS Poison B APPROVALS: DATE: Judgements as to the suitability of information herein tor purchaser's >-1Þt I ~ q.jo I'J- purposes are necessaroly purchaser's responsibility Therefore, although Delbert T. Jeter ' ~ reasonable care has been taken ,in the preparaloon of such information, Director, Quality Assuranc Boehringer Ingelhelm Animal Health, Inc extends no warranties. makes ~I f\ q¡'..,/f~- no representations and assumes no responSIbility as to accuracy or suitabllily of such information tor appricatlon to purchaser's intended ~.... _\. purposes ot for consequences of its use, John R. Carpenter \.,.--. , ~ , ....... .. . v"''''''', ....''''., e - NO, 404-6' I 'Ut:\';II~'-I""\lU.,~Ç' ,....~..- v ç, ",v'lI",u"1 - I IV"'" .~. ~ - Roussel Uclaf A ~A TERIAL SAFETY DATA SHEET , ~ MANUFACTURER'S NAIE STREET ADDRESS CITY. STATE. AND ZIP OOOE EMERGENCY TELEPHONE NO. TRADE NAME P,RODUCT CLASS MANUF ACTURING IDENTIFICATION , I DATE OF PREPARATION June 1, 1988 Section I Hoechst-Roussel Agri-Vet Company Route 202-206 North Somerville, New Jersey 08876 (201) 231-2000 SAFE-GUARDR (fenbendazole) PASTE 10% DEWORMER (anthelmintic) FOR HORSES AND CATTLE Section II - HAZARDOUS INGREDIENTS INGREDIENT Methyl-5-pheny1thio-2- benzimidazole-carbamate (CAS #43210-67-9) . NATURE OF HAZARD TLV MG/M) MPPCF LEL PERCENT PPM Non-hazardous 10 Section III - PHYSICAL DATA BOILING POINT VAPOR DENSIT'f (AIR=') DENSIT'f (Bulk) Not applicable Not applicable' 220-225 kg/m3 MELTING POINT PERCENT VOLATILE EVAPORATION RATE Not applicable Not applicable Not applicable Section IV - FIRE AND EXPLOSION HAZARD DATA DOT CATEGORY Non-regulated by DOT regulations FLASH POINT LEL Non-applicable UEL EXTINGUISHING MEDIA Water Mist, Foam or dry powder UNUSUAL FIRE AND EXPLOSION HAZARDS SPECIAL FIRE FGHTN; PROCEDURES ] r ~~...... HOEC",' ~_......... -. '" None UEL LD50 - mg/kg per oral route in rat and mouse: more than 10,000 Secti v - HEALTH HAZARD D None known. TOXICITY No health hazards are known LD50 oral Rat: more than 10000 mg/kg. LD50 oral mouse: more than 10000 mg/kg. No skin and eye irritation (5-10% solution in sesame oil at rabbit). THRESHOLD LIMIT VALUE EFFECTS OF OVEREXPOSURE EMERGENCY AND FIRST AID PROCEDURES No health hazards are known Eye Contact: flush with water Skin Contact: Wash with soap and water. Section VI - REACTIVITY DATA ST ABlUTY INCOMPATABlLITY (Materials to avoid) CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID . II! STABlE o UNSTABLE o MAY OCCUR _1151 WILL NOT OCCUR Section VII - SPilL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Sweep clean and dispose as indicated below. WASTE DISPOSAL METHOD by burning or at an official dump Section VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION VENTILATION PROTECTIVE GLOVES EYE PROTE,CTION Goggl es (for bulk use) OTHER PROTECTIVE EQUIPMENT Section IX - SPECIAL PRECAUTIONS . PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING STORE AT ROOM TEMPERATURE. . Vf506CTe 8/85 -----..-..---...- _... --. ---... ..........--. i. .A BoehW1ger "1111,, NO. 411-t21 BOEHRINGIR Ingelheim IHGII NIIM BOEHRINGER INGELHEIM ANIMAL HEAlTH.INC, 2621 North Belt Highway. 51. Joseph. Missouri 64502 · Telex: 42·6205 . Pho'ne: 816-233·2571 SECTION I. MATERIAL IDENTIFICATION Reviewed: 4/19/85 MA TERIAL NAME: Anchor Horse Spray and Rub-On OTHER DESIGNA nONS None CHEMICAL FAMILY Veterinary Antiparasitic TRADE NAME 'See Above SECTION II. INGREDIENTS AND HAZARDS % OSHA PEL HAZARD DATA/TOXICITY Petroleum Hydrocarbons (Naphtha) 88.95 350 mg/m3 LOJu Ipr,"ammal 2500 mg/kg Inert Ingredients and other Active Ingredients at levels < I , and/or determined to be Non-Hazardous as defin~ by 29 CFR Part 1910, November 25,1983. \I .05 - - SECTION III. PHYSICAL DATA 80iling point at 1 atm, deg C 62 Specific gravity, 20/4° C 0.83 Vapor pressure at 15° C, mm Hg Unknown Evap. Rate (8uAc = 1) Unknown Vapor density (Air = 1) Unknown Volatiles, % 80.7 % @ 100 degrees C Water solubility at 20° C S light I Y So I ub I e Molecular weight Not appl icable - chemIcal mixture Appearance & Odor Pale Yellow liquid with Hydrocarbon Odor. SECTION IV. FIRE AND EXPLOSION DATA Based on Petroleum Distillate (Naphtha) Flash Point and Method Autoignition Temp. I Flammability limits In Air Lower Upper -40 to -60 degrees F,C.C 450 degre~s F I I ~ 6 ~ Extinguishing media: D Ch . I Carbon Dioxide, or Alcohol Foam. Hater may be ineffective (see below). ry emlca, Special fire fighting procedures: NOTE -N I OSH approved SCBA and fu II protect i ve gear is recommended for fire- fighters. Hater may be used to cool fire eKposed containers. If a leak or spill has not ignited, use water spray to disperse vapors and protect men attempting to stop a leak. Hater may be used to flush spills away from exposures and to dilute spit Is to non-flammable mixtures. Contain runoff from fire-fighting operation as this product contains ingredients that may be harmful to aquatic life. SECTION V. REACTIVITY DATA Stable X Conditions to avoid: Store away from Heat and Strong Oxidizers. Stability Unstable Incompatible with: Strong Oxidizers. .,. Hazardous decomposition products: Carbon Oloxide, Carbon Monoxide, HCI gas and other noxious fumes may occur during combustion. Hazardous pOlymerization: May occur Conditions to avoid: None Known. . Will not occur ^ . e SECTION VI. HEALTH HAZARD INFORMATION Effects of overexposure: Skin and upper respiratory irrltation,skin burns and photosensitivity,central nerv- ous system depression,inebriation,nausea,headache,dizziness,anorexia,convulsions,nervousness,asthma, and paralysis are some of the adverse health effects reported for ingredients in this product. e NO. 411-121 Skin,Respiratory System,Gastro-lntestinal System,Eye, Centra 1 Nervous System. Target Organs: Primary Routes of Entry: Inhalation, Ingestlon,Eye and Skin Contact FIRST AID: Flush eyes with water. Notify physician immediately.Continue eye flush until help arrives. Eye contact: Remove contaminated clothing and wash affected areas with soap and water. Skin contact· , . . Remove victim to fresh air. Apply artificial respiration if indicated. Inhalation: Notify physician or pOison control center immediately. Induce vomiting If victim is conscious- Ingestion: Never induce vomiting in an unconscious person. SECTION VII. SPILL, lEAK, AND DISPOSAL PROCEDURES Contain spill to avoid contamination of environment. Absorb spill using suitable absorbent SPILLS, LEAKS: (vermiculite, ete, >, drum up into steel containers for legal disposal. Dispose of containers and unused product in accordance with local, State, and Federal Hazardous DISPOSAL: Waste Regulations. SECTION VIII. SPECIAL PROTECTION INFORMATION Respiratory protection: NIU~H approved respirator equipped with organic vapor/pesticide cartridge, Ventilation: use proDucT In welT-venfll afe-d area. Protective gloves: Rubber,Neoprene,or Viton Eye protection: Safety Glasses/Goggles or Full Face Shield. Other protective equipment: trone specially recommended. SECTION IX. SPECIAL PRECAUTIONS AND COMMENTS Storage & Handling Information READ AND FOLLOW ALL LABEL DIRECTIONS DO NOT use near open flame. Store away from heat. Keep container tightly closed when not In use. DOT Class Insecticide,liquld,NOS flammable liquid APPROVALS: DATE: Judgem~nts as to the suitability of information herein for purchaser's purp,>ses are necessarily purchaser's responsibility, Therefore. although reasonable care h"5 been taken.in the preparation of such inltJrmalion, Boehfinger fnge1helm AnImal Health, Inc. extends no warranties, makes no representations and assumes no responSIbIlity as 10 accuracy or su'tab,htf ot suCh information lor applical'on 10 purchaser's Intended purposes 01 for consequences 01 its use, r, Oe I bert T. Jeter ):[ fJ¡j ¡-JlJd--.-- Oirector, Quality ~ssura~ \..1 ~'l ~_\\ John R. Carpenter ( ~.\ "- ManaQer, Environmen~1 & Product Safety q. 30 'k'~- 9Þns- . Material Safety and Health Data Sheet Essentially similar to form LSB-005-4 (ulepl. of Labor) Section 1 e n~Ck '-'lUrK, In 7th AND ORANGE STREETS ASHLAND. OHIO 44605 419/289-9129 ( NAME & PRODUCT 0rodu<:\ Name ZIPCIDE CARTRIDGES Emergency Phone No. 24 Hours CHEM TREC 800-424-9300 800-424-8802 Chemical Name. Trade ,,!ame. and Synonyms O,O-Diethyl-(0-3-chloro-4-methyl-2-oxo-2H-l-benzopyran-7- yl) phosphorodithioate (Coumaphos) Date November 19. 1987 Section 2 INGREDIENTS 0/0 &ME CAS NUMBER RVOR PEL IS COMPONENT USlED AS A CARCINOOEN BY OSHA, NTP, OR IARC? Coumaphos 56-72-4 Inert Ingredients NA Not set* NA No No 1.0 99.0 * PEL recommended £03 coumaphos 0.2 mg/m Section 3 PHYSICAL DATA 2 Boiling Point (OF.) NA 6 Specific Gravity (H20 = 1) 20 to 40 lb I fr-3 3 Vapor Pressure (mmHg at 20" C) NA 7 % Volatile by Volume NA 4 Vapor Density (air = 1) NA 8 Color and Odor Of f-white, mild chemica: 5 Solubifity in Water None 9 Physical State Dust ( Section 4 FIRE AND EXPLOSION HAZARD DATA 11 flammable L M T5 STP 10 flash Point (and Method Used) NA OF L.F.L. NA U.F.L. NA 12 Extinguishing Media ~ater Fog ~ Foam 13 Special Fire Fighting Protective Equipment Wear self-contained breathing apparatus and full protective clo~gA o Alcohol Foam fiJ CO, @ Dry Chemical o Other 14 Unusual Fire and Explosion Hazards If water is used to fight fire, dike area to contain run-off and prevent contamination of water supplies. Dusts may present explosion hazard. Section 5 REACTIVITY DATA 15 Normal 16 CondItions To Avoid Conditions Excessive heat Stability .-. - Fire Conditions X --rr--- - Incompatibility o Water o Acid [XkBase o Corrosive tõl Oxidizing Material (Materials To Avoid) o Other ---..----"-.-------. . - 18 Hazardous Decomposition Products Oxides of carbon, phosphorus and sulfur 19-'-·----·-- ,. ,---- ---------- 20 CondItions To Avoid .---------- \ Uapa,dou, olymerization May OCCUl UOl\e_-".:~_~~1\ _____.____________ _ ___ _. _ ________________._ ------ -- ~ Will Not Occur X (Fro. Seçtlon 6 HEALTH HAZARD DATA " ; 1 Oral Ingestion / Low Toxicity Low Low Toxicity/Low Low Toxicity/Low Hazard '4 Skin Absorption Absorbe~ through the skin. ;S Inhalation (TL V Or Suggl1sted Control Figure) Not known '5 E~ef's From thalalion fder Exp¡sure ~rp~nfed ÍXEosgn:d~til re~ul t ð ch~lin~stera~e. deEre~sion, AtrQ~~n€ '2 Eye Contact .rd Hazard e .'J Skin Contacl su at s ant ota . - ~_,_s La- an ma e a mlnlstf'rp 1n 00Jllnr.t100 Wè '7 Eye: a rop] Flush with water. , First Aid Skin: :>rocedures Flush with water. Inhaiation: Get prompt medical attention. - Ingeslion: G prompt medical attention. et Section 7 SPILL OR LEAK PROCEDURES "8 Steps To Be Taken In Case Material Is Released Or Spilled Clean up spilled material and dispose of it. 19 Disposal Method _Bury, away from water supplies. 30 Ventilation Do not breathe dust. Section 8 SPECIAL PROTECTION INFORMA TION )t Respiratory Protection (Specify Type) Dust mask or respirator may be worn. 12 Protective Clothing Coveralls or other similar clothing should be worn. '3 Eye Protection [XkNot Normally Necessary o Safety Glasses Without Side Shields o Safety Glasses With Side Shields o Chemical Workers Goggles ] Gas Tight Goggles Or Equivalent 0 Other: J': Other Protective Equipment None Section 9 j Precautions To Be Taken In Handling And Storing ~ash after handling. Do not contaminate food or feed. Toxic to fish and birds. Do not SPECIAL PRECAUTIONS OR OTHER COMMENTS contaminate water ._~~pplies .._________ ___ ______.___.________._________ -------- : Other Precautions P~olonged exposure may result in cholio~ster~se depression. ~tropine sulfate i~_antidotal( ~-PAM is also antidotal and may be administered in conjunction with atroEine.___..._____________ The information herein is given in good faith buf no warranty. expressed or implied. is made_ .), , . . --~-- - . .', MA TEF&.L SAFETY DATA Se:ET PAGE 1 'u \, ';.. '-10/ 1S!81¡ , HORSE llFAL'l'H PROOOCTS, INC. ,\ NO, 503 SECTION I PRODUCT IDENTIFICATION & EMERGENCY INFORMATION pnODUCT NAME 99% Isopropyl Mcohol . CHEMICAL NAME . Isopropyl Alcohol CH~MICAl FAMIl Y A 1 i pha tic Alcohol pnODUCT APPEARANCE ..' Clear colour less liquid. , Information 803 b48 24Y4 EMERGENCY TELEPHONE NUMBERS: Product CHEMTREC 800-424-9300 SECTION I I HAZARDOUS COMPONENTS OF MIXTURES HIE rRtc I SF. CO""OS IT I ON 0< TH I S III )(tURE IS rnOPRIETARY INFon"ATION, A MOnE COUPLETE OISCLOSURE WILL BE PROVIDED TO A PHYSICIAN OR NURSE IN THE EVENT OF A MEDICAL EMERCENCY, niE FOlLOWINC COMPONENTS ARE DEF INED IIAZAROOUS IN ACCOnDANCE WIlH 29CFR1910.12ool Not applicable for this product. For addi t lonal inforn/at Ion see Sect Ion II 1. SECTION I I I II E ^ L TlI INFORMATION AND PHOTECTION FIRST AID & NATURE OF IIAZARD EYE CONTACT: Immediately f 1 usl, eyes wi th large amounts of water for at least 15 minutes. Get prompt medical at tent ion. I r r ita t i ng . and wi II injure eye tissue if not removed promptly. SKIN CONTACT: Flush wi th large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes, and launder before reuse. Frequent or prolonged contac\ may irritate and cause dermatitis. Low order of toxicity. INII^L^TION: Using pl'oper respiratory protection, immediately remove the affected v Ict im from exposure. Administer' artificial respir'ation if breathing is stopped. Keep at rest. Call for prompt medical attention. High vapor concentrations are irritating to the eyes and the respiratory t rac t , may cause headaches and dizziness. are anesthetic and may have other central nervous system effects. Negligible hazard at ambient temperature (-18 to 38 Deg C' 0 to 100 Deg F) , INGESTION: If swa I lowed, DO NOT Induce vom I t I ng . Keep at rest. Get prompt medical attent Ion. 101 In i lOa I toxicity. ^CUTE TOx\:(CITY D^T^ IS ^V^IL^ßlE UPON REQUEST PERMISSIULE EXPOSURE LIMIT; OSU^ REQUIRES (29CFR1910.1000): A TWA of 400 pprn (980. mg/m3) for Isopropyl A 1 coho 1 , I . . _.. , - .. - . - - --,. . "..M,," .._.0_. '_.M" _..._.___._.._." ___~ ..__ ._._,_,._, _ _..._ ,-.--_.. -- .---- ... ..... i . u THIS IN~ORMATION RELATES TO THE SPECIFIC MLTERIAl DESICNATEO AND MAY NOT BE VALID FOR SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY PROCESS. SUCH INFORMATION IS TO THE BEST OF OUR KNOWLEDCE AND BELIEF ACCURATE AND RELIABLE AS OF THE OATE COMPILED. HowEVER NO REPRESENTATION, WARRANTY OR CUARANTEE IS MAOE AS TO ITS ACCURACY, RÉLIABILITY OR COMPLETENESS. IT IS THE USE"'S "UI'olls'8,dn TC> SATISFY "'ItSElF ..5 TO THE SU'TABILITY ANO COMPLETENESS OF SUCH INFORIIATlON FOR HIS O..,N PARTICULAR l'SE. WE t'') .:~, .cn"T LlA~llITY rOR ANV lO!!" OR cU"'Ct "<iT MAY OCCUR FRC" Tilt UH CF TillS INFonllATION NOR DO wE OFrER WAnRAt/TV .~A'U~_ a"ru· t,·~~'~~cvr~~ " MA Tf¡jIAL SAFETY DATA j-IEET 10/15/87 PRODUCT NAME: IPA - anhydrous THRESHOLD EXPOSURE LIMIT: ACGIH RECOMMENDS: ~ TWA of 400 ppm (980 mg/m3), and a STEL of 500 ppm (1225 mg/m3) for Isopropyl Alcohol. PERSONAL PROTECTION For open systems where contact is likely, wear long sleeves, chemical resistant gloves, and chemical goggles. Where contact may occur, wear safety glasses with side shields. Where concentrations in air may exceed the limits giyen in this Section and engineering, work practice or other means of exposure reduction are not adequate. NIOSH/MSHA approved respirato~s may be necessary to prevent overexposure by Inhalation. . VENTILATION The use of mechanical dilution ventilation is recommended whenever this product is used In a confined space, is heated above ambient temperatures, or is agitated. Use explosion~proof ventilation equipment. SECTION IV FIRE & EXPLOSION IIAZARD t NOTE: TOe: 19 Deg e (66 Deg F) FLASHPOINT DEG. F: 54 METHOD: Tee FLAMMABLE LIMITS-LEL: 2.0 UEL: 12.0 AUTOIGNITION TEMPERATURE DEG. F: 662 NOTE: Minimum GENERAL IIA2ARD Flaoonable Liquid, can release vapors that form flammable mixtures at temperatures at or above the flashpoint. Empty product containers may contain product residue. Do not ~ressurize, cut. heat, weld or expose containers to flame or other sources of ignition. .' FIRE FIGttTING Use water spray to cool fire exposed surfaces and to protect personnel, Shut off "fuel" to fire, If a leak or spill has not Ignited, use water spray to disperse the vapors. Either allow fire to burn under controlled conditions or extinguish with alcohol type foam and dry chemical. Try to cover liquid spills with foam. HAZARDOUS COMBUSTION PRODUCTS No unusual . , SECTION V SPIll CONTROL PROCEDURE lAND SPILL El iminate sources at ignition. Prevent additional discharge of material, jf possible to do so without hazard. For small spills Implement cleanup procedures; for large spills Implement cleanup procedures ~nd, If In public area, keep public away and advise authorit~es. Also, if this product Is an EPA hazardous substance (See Section X, Page 41 notify the U,S. EPA If appropriate. Vapors/dust can be harmful/fatal. Warn occupants of downwind areas. Prevent liquid from entering sewers, watercourses. or low areas. Cqntain spilled lIquid with sand or earth. Do not use combustible materials such as sawdust. Recover by pumping (use an explosion proof or hand pump) or with a suitable absorbent. I c PAGE 2 NO. 503 .- - ..- ... - - ..'-.- - ~ - . e . MATERIAL SAFETY DA Tf SHEET ,.. r.r- . . , .J) PAGE J 10/15/07 PRODUCT NAME: IPA - anhydrous NO. 503 Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. WATER SPILL Eliminate sources of ignition. Vapors/dust can be harmful/fatal. Warn occupants and shipping in downwind areas. Consult an expert on disposal of recovered materfal and ensure conformity to local dIsposal regulations. ;' SECTION VI NOTES CAS NUMBER: 67-63-0 ~ " , a MA TE.L SAFETY D~ T A S~ET 10/15/07 PRODUCT NAHE: IPA - anhydrous PAGE 4 --- NO. 503 ¡ SECTION VII TYPICAL PIIYSICAL & CIIEMICAL PROPERTIES , , SP. GRAIII TY REf/EMPä r, VAPOR PREŽS'gIEï"11II1Q al r 0.767 (II 68.0 6.0 17 . 1 (pi 100 30.003 @> 68 SOLUBILITY IN WATER. WT. % a\ F VISCOSITY OF LIQUID. cST a\ F 100 CiI 66 2.64@> 77 SP. GRAVITY OF VAPOR, at , ATM AIR" FREEZING MELTING POINT/RANGE. F 1.00 Greater than ... 32 Less than EVAPORATION RATE. n·au ACETATE-I BOILING POINT/RANGE, F 2.500 179.7810 . 180.5 SECTION V I I I REACTIVITY DATA ST ABILITY? HAZARDOUS POLyMERIZATION OCCUR? Stable WI II not occur CONDITIONS TO AVOID INSTABILITY CONDITIONS TO AVOIO HAZARDOUS POL YMERZA TlON Not Appl icable Not Applicãble .- MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY Caustics, amines, alkanolamines. a 1 del~ydes, aro:non i a, strong oxidizing agents, and chlorinated compounds. HAZARDOUS DECOMPOSITION PRODUCTS None SECTION IX TRANSPORT AND STORAGE ~rCTROSTATIC ACCUMULATION HAZARD No, but use proper grounding procedure STORAGE TEMPERATURE, F lOADING/UNLOADING TEMPERATURE. F Ambient Ambient STORAGEtTRANSPORT PRESSURE, mmHg VISCOSITY AT LOAOING/UNLOADING TEMPERATURE,cST Atmospheric 2.7 @> 77 SECTION X HAZARD CLASSIFICATION ü.s. DOT CLASSifiCATION EPA HAZARDOUS SUBSTANCE AMOUNT LBS. Flammable 1 iquid Not appl icable , ADDITIONAL INFORMATlor U.S. DOT Identification Number: UN 1219 . ~ Under the provisions of Tit 1 e I II , Sections 311/312 of the Superfund Amendments and Reauthorization Act, t~ls product is classified Into the following hazard categories: Immediate Health, Delayed Health, Fire. ~ . . REHRENCE NUMBER IDA TE PREPARED ISUPERCEDES ISSUE DATE HDI-IA-C-00021 OCTOBER 15,1987 SEPTEMBER 17,1987 FOR AODITlONAL PRODUCT INFORMATION CONTACT YOUR TECHNICAL SALES REPRESENTATIVE FOR ADOITlONAL ilEAL TH/SAFETY INFORMATION CALL 713'870-6885 " ·.....--...".- .....".. -.. -.--..... -~~- ~. - . A Boe~nger .- e 111\1111 NO. "01-431 .OIUINCI' Ingelheim I.,"all. eOEHRINGf~ ".GHMEIM A:-OAAL MEALTM,INC '621 No"n ~;I HI"w'Y · Sf JOWph, M,nou" 64502 · T,I'I: 42·6205 . PhO'n,: 81&-233-2511 SECTION I. MATERIAL IDENTIFICATION Reviewed: 5/03/85 f-.IA TERIAl NAME: Anchor Per~ectrin Pet, Yard, and Kennel Spray OTHER DESIGNA T:ONS. None CHEMICAL FAMIL Y Veter ¡nary Ant iparasitic TRAD SH Above E NAME SECTION II. INGREDIENTS AND HAZARDS % OSHA PEL HAZARD D;. TA/TOXICI' Mineral Spirits (mIxed C9,CI0.&CI1 Hydrocarbons) 80.0 00 PP" tfone Reporteo Permethr,n (Chemical Name;(3-Phonoxyphenyl) Methyl (+,-) cis-trans-)-(2.2-d1chloroethenyl)-2,2-dimethylcyclo- propane-carboxylate) 10.0 - 050 Oral,Rat 3800 mg/kg Inert Ingredients 10.0 - - SECTION III. PHYSICAL DATA Soiling ~Olnt at 1 atf":'. ::eg C 110 Specific gravity. 20/4°C O.t" Vapor pressure at 1S<C, mm Hg ) 5 I1'1III (mineral spirits) Evap. Rate (SuAc = 1) Unknown Vapor d~nslty (Air = ~ i ~8.3 (mInerai spirIts) Volatiles. % 27.0 B 100 degrees C Water soluoility at 20'CProduct Is Miscible with Water Molecular weightNot appl icable - chellical .Ixture Appearance &. Odor A:T1ber liquid With Odor of Kerosene SECTION IV. FIRE AND EXPLOSION DATA Based on Mineral Spirits Flash Po;r.! and Me:n:-::: Autoignition Temp. Flammability Limits In Air Lower Upp 100 de~r~~s F, C.C. Unknown 1. I J 6. I Extingu1sh'r.g media: . Alcohol foall. Water may cause frothing. CaMbon Dioxlde,Ory PONder, or Special I:re f:ghting procedures:NOTE _~ aSH approved SCBA and full protect i ve gear I 5 recolMlend~ fore f ì r~ fighters. Wafer spray ~y be used to cool fire exposed containers cool. If a leak or spill has not Ignlf. use water spray to dIsperse vapors an1 protect men attemptiny to stop a leak. Nater spray ~ay be used to flush spills away from exposure and to di lute Spills to non- lammable mixtures. Contain runoff froa fire- fighting operations, as this product contains ingredients that may be toxic to aquatic life. SECTION V. REACTIVITY DATA Slabie X Conditions to avoid: Store away from heat and strong oxidizers. "Stability , Unsta~:e , Incom~a!lo¡e wi:h; Strong Oxidizers. HazardouS decom;>O$':'on products; Carbon Dioxide, Carbon Honoxlde, HCI gas and other noxious fumes may occur during combustion. . Hazardous pOlymerization: May occur Condilions to avoid: Will not occur " None Known. '- -f ( l - '. ... '. e e NO. 401-431 -'- ;,) SECTION VI. HEALTH HAZARD INFORMATION Elleels of overexposure: Reversible skin tingling or numbness,sk,n irritation and sensitivity, central ( nervous $>'ste~ deprelslon,respiratory Irrltatlon,nausea,diZZiness, intoxication, and narcosis are some ot the adverse health .tt.ct. reported for Ingredients contained in this product. Target Organs: Respiratory System,Eyes,Skln,Central Nervous Syst~. Primary Routes of Entry: Skin and Eye Conhct,lnhalatlon,lngestion FIRST AID: . Eye contact' Flush eyes with water. Notify physician immediately.Continue eye flush until help arrives. . Remove contaminated clothing and wash affected areas with soap and water. Skin contact: Innalation: Remove vlctl~ to fresh air. Apply artificial respiration if Indicated. I I' Notify physician or polson control center Immediately. DO NOT induce vo.ltln9. nges Ion: SECTION VII. SPILL, LEAK, AND DISPOSAL PROCEDURES Contain spill to avoid contamination of environment. Absorb spill using suitable absorbent SPILLS. LEAKS: Cvermicul ite, etc,), drum up into steel conhiners for legal disposal. ( Dispose of containers and unused product In accordance With local, State, and Federal Hazardous ~ISPOSAL: Waste Regulations. SECTION VIII. SPECIAL PROTECTION INFORMATION P.es¡)iratory protection: NIOSH approved respirator equipped with organic vapor/pesticide cartridge. Ven!ilalion: Use product in we I f -vent i I ated area. PrOlacti¡'e gloves: Rubt>er. Neoprene or V I ton. Eye protection: Safety Glasses/Goggles or Full Face Shie I d. O::"Ier prolective equipment: Protective outer clothing <long sleeved>,rubber boots, rubber or plntic apron. SECTION IX. SPECIAL PRECAUTIONS AND COMMENTS READ AND FOLLOW ALL LABEL DIRECTIONS , Storage t. Handling Information I I 00 NOT use near open flame. Store away from heat. Keep container tightly closed when not In use. DOT Class Insecticide,Liquld.NOS F le/lllllllble Liquid APPROVALS: DATE: ( .:~:..,."nIS .s 10 III' .uillÞ,hly 01 ¡,.,Iormalion IItrOin for pureh..,,', ~_:~~'us .re ",cISSlr"y purerlue" r"ponSI~,lily Tller"ore, .lIhough 't'~;'~':lle e.re illS be.n IIk.n,in III, prep".""n 01 such ¡"'orm'llon, e')t--",.çer 'ngelll.,m An,mal t'4nl:h. Ine '.lends no werr.nlles, m.k.. .:- ·t:,'esenlihons .nd .ssu:rn no responS¡þ,lIly .. lu .eeuracy or s. :#.')II'ly 01 Such ¡n'ormll,on lor .pphc."o" 10 purch...,., inl.nd'd C ~'C).., 01 'or eon~tQutnttl of its use, (\ Delbert T. Jeter ~¿ú t ~~ Director, Quality Assuran~-- , ' --.. () John R. C~rpenter\ 'i -~ ,.~ M,...", < , '.,.J _ I . _ . _ _ . q.30'¡..J- 9;17k -- --~------ - - I.;;. .- -of Ij ( ( ~ Boe~ger 11111\11 NO. 402-711 IDI_.I..CI_ Ingelfieim '":.!._... r BCE,.~..·.C.£R INGELHEIM ANIMAL HEAL TH,INC 2621 '.;1":" !ell H,.hw.y · SI. Jo"ph, M,uouro ~S02 · Tel.t; .2·6205 . Phon.' 816-233·2571 SECTION I. MATERIAL IDENTIFICATION Reviewed: 4/19/85 ""A "7"ERIAL NAME: Anchor Pe,..ec tr n ûust Bag ( it OT~ER DESIGNATIONS' Hon. CH:~.IICAL FAMILY Veterinary Antiparasitic TRADE NAME See Above SECTION II. INGREDIENTS AND HAZARDS % OSHA PEL HAZARD DATA/TOXIC I This product contains no hazardous ingredients as def I ned by 29 CFR Part 1900,Nov~ber 1983. SECTION III. PHYSICAL DATA B:¡' .fI:;; point at1 atm, deg C Hot Appt icable-Sol id Specific gravity, 20:4°C Not applicable-Powder Va;:or pressure at 15· C. mm Hg Unknown Evap. Rate (BuAc = 1) Unknown Va::¡: density (Air = 1) Unknown Volatiles, Co < I ~ \\'a:"r solubility at 20·C Slightly Soluble Molecular weight Not appl ¡cable - chMleal .ixtur A"=!'a~ance & Odor Odor less. off-white powder SECTION IV. FIRE AND EXPLOSION DATA Hot Aoollcðble-Prnrluct ic: Nnn-F r:;¿.-. POln! and Method Au!oignition Temp. Flammability Limits In Air Lower Up Nnt .&oDII~l)bl.. Not Aoollcable Not ADDlicðble HA ~ EX:::'I;uishing media: Non-Flalllfllable. Not Applicable-Product Is Spet;lal fire fighting procedures: Not Applicable-Product will not Ignite. SECTION V. REACTIVITY DATA Stable X Conditions to avoid: None Known $!a:> 'If i Unstable Ir.::¡~;::atble with: No Known Incompatabilltles. Hazardous decomposition products; hont Known HaZlr~ous pOlymerization: May occur Conditions to avoid: Will not occur v N,..,..," If"".." ~. , e e NO. 402-711 'ó SECTION VI. HEALTH HAZARD INFORMATION Eflp.cts 01 overexposure: At h h "t very Ig exposure levels, the active Ingredient In his product has been report- .d to cause the folloNlng adverse health effects: reversible skin n~bness or tlngling.skln irritation and sensltivlty,central nervous system depression,respiratory irritatlon,nausea.dizzlness, intoxication, and narce sis. Target Organs: Respiratory System,Eyes.Skin,Central Hervous Syste.. Primary Routes or Entry: Eye and Skin Contact. Inhalation. Ingestion FIRST AID: Eye contact: Flush eyes Nlth Nat.r. Notify physiCian immediately. Skin contact: Remove contaMinated clothing and Nash affected areas with soap and \IIater. , Inhalation: Remove victl~ to fresh air. Apply artificial respiration if Indicated. Ingestion: Notify physician or pOison control center IlMIediately. Never indue. vomiting in an unconscious person. SECTION VII. SPILL, LEAK. AND DISPOSAL PROCEDURES SPILLS. LEAKS: Contain spi II to avoid contamination of environment. Absorb spill using suitable absorbent (verØllcul ite, etc,>. drum up into stee I conh i ners for legal disposal. DISPOSAL: Dispose of containers and unused product in accordance with local, State, and Federal Hazardous Waste Regulations. SECTION VIII. SPECIAL PROTECTION INFORMATION Respiratory protection: NIOSH approved respirator equlpp!d with organic vapor/pesticide cartridge. fi Iter. Ventilation: Use product in well-ventilated area. Protective gloves: Rubber, Neoprene or Viton. Eye protection: Safety Glasses/Goggles ., Other protective equipment: None specially recommended. SECTION IX. SPECIAL PRECAUTIONS AND COMMENTS Storage & Handling 1~lorrnalion READ AND FOLLOW ALL LABEL DIRECTIONS DO HOT use near open flame. Store away from heat. Keep container tightly closed when not I n use. DOT Class Insect, c ,de, Dry, NOS DATE: APPROVALS: r- Judg.m.n" u 10 !1'If t'~III:lo;'I~ 0' inlorm.tion h.r.in lor purchlser', De I bert T. Jeter \.J:!I. p........ Q·30·tr pu:poses are n.c.narlll ~ ..'c"uer's 'esponSibill'y, Therelor.. although reuonable c.r. ".. OU" :lk,n..n Ih. preparalion 01 such ,n'ormlllon. Director, Quality Asšúran Dcwh"ng.' Ing.'''''''' An,,,.,,, HUllh. Inc exl.nd. no wI,r.n"... m.ktt \€ :'\ );> '- n 9!7¡}S' "0 ttP,..OnU.IoIJI\' '''0 IUI."'" no responSlblllly IS 10 .ccuracy 0' .u.:ablhlt' 01 ~ucn ,"','.,.,a:ooll ':lr applicallon 10 purch.ser's ,nltnd.d p",po,-. 01 '...r cc.nn:;u<!"<::" ,1 ,IS ust John R. C~rpenter\\ - \~ .- ~ . - , ..... - ----.. '''''J c ( \ . "~["--'"TC-¡go: .. TERRAMYCIN OPHTHALMIC OINTMENT (6913) DESCRIPTION: Yellow substance which is essentially odorless. Slightly soluble in water. Contains oxy- tetracycline hydrochloride (CAS No. 2058460) and polymyxin B sulfate (CAS No. 1405205). PHYSICAL HAZARD DATA: Use water or a dry chemical fire extinguisher when fighting a fire where this material is located. If the fire is too large to extinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for this material or its active drug ingredients. NOT FOR HUMAN CONSUMPTION. This material or its active drug ingre- dients are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of this material into the human body are through ingestion or skin absorption. Short-term overexposure may cause some undesirable health effects, such as skin rash. Repeated exposure to oxy- tetracycline should be avoided during pregnancy and nursing since the color and structure of the teeth and bones of the unborn or newborn child may be adversely affected due to changes in calcium metabolism. Long-term overexposure to this material may produce an overgrowth of resistant bacteria, yeast and molds in the mouth, stomach, intestines, etc. which may cause upset stomach, diarrhea, itching of genital or rec- tal area, nausea and vomiting. Also, some people may develop excessive skin sensitivity and reddening as a result of direct exposure to the sun. The potential effects of overexposure can be avoided by the use of proper protective equipment. EMERGENCY AND FIRST AID PROCEDURES: If this material gets into your eyes, flush them immediate- ly with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time. If this material gets on your skin, wash with soap and water. Severely contaminated clothing should be removed and washed or discarded. OBTAIN IMMEDIATE MEDICAL ATTENTION if this material is swallowed, gets into your eyes or if one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Recover spills by recovery into a container. Wear all recommended safety equipment to avoid skin or eye contact. Bury all waste material and contaminated personal protective equipment and clothing at a sanitary landfill. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to this material should take steps to avoid skin or eye contact or swallowing of product. Safety goggles and protective gloves may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leaving work or eating food. FOR ADDITIONAL INFORMATION: Write Pfizer Inc., Agricultural Division, 1107 South Missouri 291, Lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 780-8853 after normal working hours. This MSDS is based on a limited review of Pfizer's files, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty of any kind. The determination of whether and under what conditions this material should be used by your employees is yours to make. December 1987 . Material Safety Data Sheet (MSDS) No. 024 '. ¡ r~ TERRAMYCIN SOLUBLE POWDER CONCENTRATE (2819, 5631) TERRAMYCIN SCOURS TABLETS (6912, 8876) TERRAMYCIN EGG FORMULA (0692, 0845) TERRAMYCIN SOLUBLE POWDER (4163) DESCRIPTION: Yellow crystalline powder which is essentially odorless. Moderately soluble in water. Contains oxytetracycline hydrochloride (CAS No. 2058460). PHYSICAL HAZARD DATA: All organic dust can be explosive under certain conditions. Use water or a dry chemical fire extinguisher when fighting a fire where these materials are located. If the fire is too large to ex- tinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for these materials or their active drug ingredient. NOT FOR HUMAN CONSUMPTION. These materials or their active drug in- gredient are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of these materials into the human body are through ingestion, inhalation of dusts or skin absorption. Short-term inhalation of dusts from these products may cause some undesirable health effects, such as skin rash or asthma-like reaction. Repeated exposure to oxytetracycline should be avoided during pregnancy and nursing since the color and structure of the teeth and bones of the unborn or newborn child may be adversely affected due to changes in calcium metabolism. Long-term overexposure to these materials may produce an overgrowth of resistant bacteria, yeast and molds in the mouth, stomach, intestines, etc. which may cause upset stomach, diarrhea, itching of genital or rectal area, nausea and vomiting. Also, some people may develop ex- cessive skin sensitivity and reddening as a result of direct exposure to the sun. The potential effects of over- exposure can be avoided by the use of proper protective equipment and approved dust respirators. EMERGENCY AND FIRST AID PROCEDURES: If these materials get into your eyes, flush them immediately with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time. If these materials get on your skin, wash with soap and water. Severely contaminated clothing should be removed and washed or discarded. If a person is exposed to excessive quantities of dust because of equipment malfunc- tion or other mishaps, move the person to fresh air immediately. If breathing has stopped, initiate artificial respira- tion: Keep the affected person warm and at rest. Do not administer any substance into the mouth of an un- conscious person. OBTAIN IMMEDIA TE MEDICAL ATTENTION jf these materials are swallowed, get into your eyes or if one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Recover spills by sweeping into a container and flushing the area with water. Wear all recommended safety equipment to avoid skin or eye contact or inhalation. Bury all waste material and contaminated personal protective equipment and clothing at a sanitary landfill. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to these materials should take steps to avoid skin or eye contact, swallowing or inhalation of product. Wear an approved dust respirator, depending upon the concentration of dust in the work atmosphere. A qualified dealer should be consulted to determine the type of respirator required. Adequate ventilation to reduce exposure below a total dust Tl V of 10 mg/m J is recommended. Safety goggles, protective gloves and disposable overgarments may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leaving work or eating food. FOR ADDITIONAL INFORMATION: Write Pfizer Inc., Agricultural Division, 1107 South Missouri 291, lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 780-8853 after normal working hours. This MSDS is based on a limited review of Pfizer's files, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty of any kind. The determination of whether and under what conditions these materials should be used by your employees is yours to make. December 1987 . Material Safety Data Sheetl,\\SDSI su, ,~ \ TERRA-CORTRI L SPRAY (3462) DESCRIPTION: Yellowish aerosol. Slightly soluble in water. Contains oxytetracycline hydrochloride (CAS No. 2058460) and isobutane (CAS No. 75285). The chemical name for isobutane is 2-methylpropane. PHYSICAL HAZARD DATA: This material may form explosive mixtures with strong oxidizing agents. The boiling point of isobutane is 1 0.9°F. The vapor density and vapor pressure of isobutane are approximately 2.01 and 45.1 psi, respectively. The lEL for isobutane is 1.5% and the UEl is 8.4%. The flash point using an open cup method is 120°F. Use a dry chemical or CO2 fire extinguisher or water spray when fighting a fire where this material is located. If the fire is too large to extinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for this material or its active drug ingredients. NOT FOR HUMAN CONSUMPTION. This material or its active drug ingre- dients are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of this material into the human body are through ingestion, inhalation or skin absorption. Short-term inhalation of this product may cause some undesirable health effects, such as skin rash, drowsiness or asthma-like reaction. Repeated exposure to oxytetracycline should be avoided during pregnancy and nursing since the color and structure of the teeth and bones of the unborn or newborn child may be adversely affected due to changes in calcium metabolism. long-term overexposure to this material may produce an overgrowth of resistant bacteria, yeast and molds in the mouth, stomach, intestines, etc. which may cause upset stomach, diarrhea, itching of genital or rectal area, nausea and vomiting. Also, some people may develop excessive skin sensitivity and reddening as a result of direct exposure to the sun. The poten- tial effects of overexposure can be avoided by the use of proper protective equipment. EMERGENCY AND FIRST AID PROCEDURES: If this material gets into your eyes, flush them immediate- ly with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time. If this material gets on your skin, wash with soap and water. Severely contaminated clothing should be removed and washed or discarded. If a person is exposed to excessive quantities, move the person to fresh air immediately. If breathing has stopped, initiate artificial respiration. Keep the affected person warm and at rest. Do not administer any substance into the mouth of an unconscious person. OBTAIN IMMEDIA TE MEDICAL ATTENTION if this material is swallowed, gets into your eyes or if one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Protect from ignition sources. Wear all recommend- ed safety equipment to avoid skin or eye contact or inhalation. Absorb liquid material in an absorbent recommended for solvent spills and remove to a safe location for disposal by approved methods. Isobutane reacts vigorously with oxidizing materials. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to this material should take steps to avoid skin or eye contact, swallowing or inhalation of product. Safety goggles and protective gloves may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leav- ing work or eating food. FOR ADDITIONAL INFORMATION: Write pfizer Inc. Agricultural Division, 1107 South Missouri 291. lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 78()..8853 after normal working hours. This MSDS is based on a limited review of Pfizer's files, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty of any kind. The determination of whether and under what conditions this material should be used by your employees is yours to make. December 1987 . Material Safety Data Sheet (MSDSI No ,)~ J PEN 8P-48 (1631, 1632) DESCRIPTION: Smooth, white, homogeneous suspension. Contains penicillin G benzathine (CAS No. 1538096) and penicillin G procaine (CAS No. 54353). PHYSICAL HAZARD DATA: Use water or a dry chemical fire extinguisher when fighting a fire where this material is located. If the fire is too large to extinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. Complete combustion of this material may result in emission of toxic fumes, such as various oxides of nitrogen. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for this material or its active drug ingredients. NOT FOR HUMAN CONSUMPTION. This material or its active drug ingre- dients are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of this material into the human body are through ingestion, injection or skin absorption. Hypersensitivity and anaphylactic shock may occur in individuals sensitive to penicillin. The potential ef- fects of overexposure can be avoided by the use of proper personal protective equipment and clothing. EMERGENCY AND FIRST AID PROCEDURES: If this material gets into your eyes, flush them immediate- ly with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time. If this material gets on your skin, wash with soap and water. Contaminated clothing should be removed and washed or discarded. OBTAIN IMMEDIA TE MEDICAL A TTENT/ON if this material is swallowed, in- jected, gets into your eyes or if one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Recover spills by absorption into an inert material and rinsing to drain. Wear all recommended safety equipment to avoid skin or eye contact or injection. Bury all waste material and contaminated personal protective equipment and clothing at a sanitary landfill. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to this material should take steps to avoid skin or eye contact, swallowing or injection of product. Safety goggles and protective gloves may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leaving work or eating food. FOR ADDITIONAL INFORMATION: Write Pfizer Inc., Agricultural Division, 1107 South Missouri 291, lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 780-8853 after normal working hours. This MSDS is based on a limited review of Pfizer's files, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty or any kind. The determination of whether and under what conditions this material should be used by ) our employees is yours to make. December 1987 . Material Safety Data Sheet (MSDS' " RFD LIQUID DOG WORMER (4547) STRONGID T (4329, 4804) NEMEX TABS (4540, 4541) STRONGID PASTE (1156) NEMEX-2 (4505, 4507) NEMEX (4521) DESCRIPTION: Yellowish material with a caramel odor. Insoluble in water. Contains pyrantel pamoate (CAS No. 22204246). The chemical name for pyrantel pamoate is 1,4,5,6-tetrahydro-1-methyl-2-[2-(2-thienyl) ethenyl] pyrimidine pamoate. PHYSICAL HAZARD DATA: Use water or CO2 fire extinguisher when fighting a fire where these materials are located. If the fire is too large to extinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for these materials or their active drug ingredient. NOT FOR HUMAN CONSUMPTION. These materials or their active drug ingredient are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of these materials into the human body are through ingestion or skin absorption. Short-term overexposure to these products may cause some undesirable health effects such as skin rash. The potential effects of overexposure can be avoided by the use of proper protective equipment. EMERGENCY AND FIRST AID PROCEDURES: If these materials get into your eyes, flush them immediately with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time. If these materials get on your skin, wash with soap and water. Severely contaminated clothing should be removed and washed or discarded. OBTAIN IMMEDIA TE MEDICAL A TTENT/ON if these materials are swallowed, get into your eyes or if one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Recover spills by flushing the area with water and removing material to a safe area for disposal. Wear all recommended safety equipment to avoid skin or eye contact. Bury all waste material and contaminated personal protective equipment and clothing at a sanitary landfill. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to these materials should take steps to avoid skin or eye contact or swallowing of product. Safety goggles and protective gloves may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leaving work or eating food. FOR ADDITIONAL INFORMATION: Write Pfizer Inc., Agricultural Division, 1107 South Missouri 291, Lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 780-8853 after normal working hours. This MSDS is based on a limited review of Pfizer's files, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty or any kind. The determination of whether and under what conditions these materials should be used h\' your employees is yours to make. December 1987 . Material Safety Data Sheet (MSDSI \", LlQUAMYCIN LA·200 (4690, 4696, 4697) DESCRIPTION: Yellowish-brown solution with a green tint. Contains oxytetracycline amphoteric (CAS No. 79572) and magnesium oxide (CAS No. 1309484). PHYSICAL HAZARD DATA: Use water or a dry chemical fire extinguisher when fighting a fire where this material is located. If the fire is too large to extinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. Complete combustion of this material may result in emission of acrid smoke and fumes. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for this material or its active drug ingredients. NOT FOR HUMAN CONSUMPTION. This material or its active drug ingre- dients are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of this material into the human body are through ingestion, skin absorption or injection. Repeated exposure to oxytetracycline should be avoided during pregnancy and nursing since the color and structure of the teeth and bones of the unborn or newborn child may be adversely affected due to changes in calcium metabolism. Long-term overexposure to this material may produce an overgrowth of resistant bacteria, yeast and molds in the mouth, stomach, intestines, etc. which may cause upset stomach, diarrhea, itching of genital or rectal area, nausea and vomiting. Also, some people may develop excessive skin sensitivity and reddening as a result of direct exposure to the sun. The potential effects of overex- posure can be avoided by the use of proper protective equipment. EMERGENCY AND FIRST AID PROCEDURES: If this material gets into your eyes, flush them immediate- ly with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time. If this material gets on your skin, wash with soap and water. Severely contaminated clothing should be removed and washed or discarded. OBTAIN IMMEDIA TE MEDICAL A TTENT/ON if this material is swallowed, injected, gets into your eyes or if one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Recover spills by absorption into an inert material and rinsing to drain. Wear all recommended safety equipment to avoid skin or eye contact or injection, Bury all waste material and contaminated personal protedive equipment and clothing at a sanitary landfill. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to this material should take steps to avoid skin or eye con tad, swallowing or injection of product. Safety goggles and protective gloves may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leaving work or eating food. FOR ADDITIONAL INFORMATION: Write Pfizer Inc., Agricultural Division, 1107 South Missouri 291, Lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 780-8853 after normal wôrking hours. This MSDS is based on a limited review of Pfizer's files, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty of any kind. The determination of whether and under what conditions this material should be used by your employees ;s yours to make. December 1987 . Material Safety Data Sheet (MSDS) No, Ooq TERRAMYCIN INJECTABLE SOLUTION (2903, 2907) LlQUAMYCIN INJECTABLE SOLUTION (9179) OXYVET-100 INJECTION (607V) DESCRIPTION: Yellow to yellowish-brown solution. Contains oxytetracycline hydrochloride (CAS No. 2058460), monoethanolamine (CAS No. 141435), sodium formaldehyde sulfoxylate (CAS No. 149440) and propylene glycol (CAS No. 57556). PHYSICAL HAZARD DATA: Use water or a dry chemical fire extinguisher when fighting a fire where these materials are located. If the fire is too large to extinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. Complete combustion of these materials may result in emission of acrid smoke and fumes. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for these materials or their active drug ingredients. Monoethanolamine has an ACGIH TWA exposure limit of 3 ppm and a ceiling exposure limit of 6 ppm. NOT FOR HUMAN CONSUMPTION. These materials or their active drug ingredients are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of these materials into the human body are through ingestion, injection or skin ab- sorption. Repeated exposure to oxytetracyline should be avoided during pregnancy and nursing since the color and structure of the teeth and bones of the unborn or newborn child may be adversely affected due to changes in calcium metabolism. Long-term overexposure to these materials may produce an overgrowth of resistant bacteria, yeast and molds in the mouth, stomach, intestines, ete. which may cause upset stomach, diarrhea, itching of genital or rectal area, nausea and vomiting. Also, some people may develop excessive skin sensitivity and reddening as a result of direct exposure to the sun. The potential effects of overexposure can be avoided by the use of proper protective equipment. EMERGENCY AND FIRST AI D PROCEDURES: If these materials get into your eyes, flush them immediately with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time, If t~ese materials get on your skin, wash with soap and water. Severely contaminated clothing should be removed and washed or discarded. OBTAIN IMMEDIATE MEDICAL ATTENTION if these materials are swallowed, injected, get into your eyes or if one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Recover spills by absorption into an inert material and rinsing to drain. Wear all recommended safety equipment to avoid skin or eye contact or injection. Bury all waste material and contaminated personal protective equipment and clothing at a sanitary landfill. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to these materials should take steps to avoid skin or eye contact, swallowing or injection of product. Safety goggles and protective gloves may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leaving work or eating food. FOR ADDITIONAL INFORMATION: Write Pfizer Inc., Agricultural Division, 1107 South Missouri 291, Lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 780-8853 after normal working hours. This MSDS is based on a limited review of Pfizer's files, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty oi any kind. The determination of whether and under what conditions these materials should be used by your employees is yours to make. December 1987 - Material Safety Data Sheet (MSOS) No, 008 ....:-. ~-, lIQUAMYCIN 100 INJECTABLE SOLUTION (4694) TERRAMYCIN 1 00 INJECTABLE SOLUTION (4692, 4695) DESCRIPTION: Yellowish-brown solution with a green tint. Contains oxytetracycline hydrochloride (CAS No. 2058460) and monoethanolamine (CAS No. 141435). PHYSICAL HAZARD DATA: Use water or a dry chemical fire extinguisher when fighting a fire where these materials are located. If the fire is too large to extinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. Complete combustion of these materials may result in emission of acrid smoke and fumes. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for these materials or their active drug ingredients. Monoethanolamine has an ACGIH TWA exposure limit of 3 ppm and a ceiling exposure limit of 6 ppm. NOT FOR HUMAN CONSUMPTION. These materials or their active drug ingredients are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of these materials into the human body are through ingestion, skin absorption or injection. Repeated exposure to oxytetracyline should be avoided during pregnancy and nursing since the color and structure of the teeth and bones of the unborn or newborn child may be adversely affected due to changes in calcium metabolism. Long-term overexposure to these materials may produce an overgrowth of resistant bacteria, yeast and molds in the mouth, stomach, intestines, ete. which may cause upset stomach, diarrhea, itching o{ genital or rectal area, nausea and vomiting. Also, some people may develop excessive skin sensitivity and reddening as a result of direct exposure to the sun. The potential effects of overexposure can be avoided by the use of proper protective equipment. EMERGENCY AND FIRST AID PROCEDURES: If these materials get into your eyes, flush them immediately with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time. If these materials get on your skin, wash with soap and water. Severely contaminated clothing should be removed and washed or discarded. OBTAIN IMMEDIATE MEDICAL ATTENTION if these materials are swallowed, injected, get into your eyes or i{ one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Recover spills by absorption into an inert material and rinsing to drain. Wear all recommended safety equipment to avoid skin or eye contact. Bury all waste material and contaminated personal protective equipment and clothing at a sanitary landfill. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to these materials should take steps to avoid skin or eye contact or swallowing of product. Safety goggles and protective gloves may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leaving work or eating food. fOR ADDITIONAL INFORMATION: Write Pfizer Inc., Agricultural Division, 1107 South Missouri 291. Lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 78~853 fitter normal working hours, This MSDS is based on a limited review of Pfizer's {iles, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty 0; any kind. The determination o{ whether and under what conditions these materials should be used by your employees is yours to make. December 1987 - Material Safety Data Sheet (MSDS) No ,~,- COMBIOTIC AQUEOUS SUSPENSION (2266, 3805, 3849, 6753) DESCRIPTION: Smooth, white to slightly yellow, homogeneous suspension. Contains penicillin G procaine (CAS No. 54353), dihydrostreptomycin (CAS No. 128461) sulfate and procaine hydrochloride (CAS No. 51058). PHYSICAL HAZARD DATA: Use water or a dry chemical fire extinguisher when fighting a fire where this material is located. If the fire is too large to extinguish in a short amount of time, use a self-contained breathing apparatus and full personal protective clothing. Complete combustion of this material may result in emission of toxic fumes, such as various oxides of nitrogen. HEALTH HAZARD DATA: Neither OSHA nor ACGIH exposure limits have been established for this material or its active drug ingredients. NOT FOR HUMAN CONSUMPTION. This material or its active drug ingre- dients are not carcinogens or potential carcinogens according to NTP, IARC or OSHA. The most likely routes of entry of this material into the human body are through ingestion, injection or skin absorption. Hypersensitivity and anaphylactic shock may occur in individuals sensitive to penicillin. The potential ef- fects of overexposure can be avoided by the use of proper personal protective equipment and clothing, EMERGENCY AND FIRST AID PROCEDURES: If this material gets into your eyes, flush them immediate- ly with large amounts of tap water for at least 15 minutes, lifting the lower and upper lids from time to time. If this material gets on your skin, wash with soap and water. Contaminated clothing should be removed and washed or discarded. OBTAIN IMMEDIA TE MEDICAL ATTENTION if this material is swallowed, in- jected, gets into your eyes or if one is exposed to excessive quantities. PRECAUTIONS FOR SAFE HANDLING AND USE: Recover spills by absorption into an inert material and rinsing to drain. Wear all recommended safety equipment to avoid skin or eye contact or injection. Bury all waste material and contaminated personal protective equipment and clothing at a sanitary landfill. CONTROL MEASURES: Avoid unnecessary exposure. Persons exposed to this material should take steps to avoid skin or eye con tad, swallowing or injection of product. Safety goggles and protective gloves may also be worn, if necessary, to reduce exposure. After handling material, wash thoroughly before leaving work or eating food. FOR ADDlTlONAllNFORMA TION: Write Pfizer Inc. Agricultural Division, 1107 South Missouri 291, lee's Summit, Missouri 64081, phone (816) 524-5580 or phone (718) 780-8853 after normal working hours. This MSDS is based on a limited review of Pfizer's files, standard toxicology handbooks, and published MSDSs on identical or related materials. The information in this MSDS is furnished without warranty oi any kind. The determination of whether and under what conditions this material should be used by your employees is yours to make. December 1987 - Material Safety Data Sheet (MSDSI:'o,;" '" " 7' .... .... .,_. ~.._ M...~· ,.. "", .. ._ ",.I~I... 0 '., I ,', ~;:. ..4tr. ,,' ('. . t", ..., _.:~: .." I'), ... f _,',~, ..' T ._ Y. _ .." '::~ .... l~~, .. Ie- 'o' :~: _.Ij _o' S _,I~ _. T _, __ _, ,., ,.. ... _ _ _ __ __ _, .. _.. .... _.. .~..... _.., _.' 4"'·" _... ':::: Ii: I:: T I I.:, t, , 1, ." ::: . ~, L'T:: r2' T IF;' I: ,f;, T J '} r,J .. en: .,JY I~' ~!I~' I~~ T ... , . " .",.,.. _ ",' _ ._ _. ._ __ ", ,,' ~6UVE6ÇIVR~~:S..NAM[: \1. r:. YC",.'I)13. IlK t 11 l. \/!'1l\t, ~::TnE~~:T SPRINGFIELD~ MA 01103 PPODUCT Cfll,'!,;: ();?;:;, N^ME~ ABSORBINE VETERINARY LINIMENT CIIEt'l N¡.\t"lE: :::':EE ::::ECTII:'I'~ \.11 c. ,.\. :=.::. t"IIJt'1BFR: :::;EF ~::;Fc"r I ot, \) I C . r,. ::: . t'!l\!"!E: ':;r::' :: :::: ~::: '::' T :r Ot'J \,' ¡ C~'IEt'l Fom'lULl~: N/ (\ !1IJL,ECI.JIJ1H l·IC'T: Ni" I,::: HI:: r'il F At'1 I L Y ~ tit 1 /TUPF N. D. C. r·IC). 11/i·:'4 O?(:, XX FDA REG. NO. 1210276 D,O.T. HAZA9D CLASS: QPM-V D.O.T. '='::!"IIPF'Ir'!U t,!<',r'!L: r,rill(;::'::. tl"CJ,':::. ...-......--....................... ..... .... ..... ..... .... . ..' ....- ..... ..... .... .... ......... ..., ... .'~' ..... ."~ ...- ..... '.-. '-' ..... . - .... ..- ...- ..... ..... ._~ ..-- ..... ..- ~... ......... .......- ..... ...~ .- ..... ...~ --. ..... ...- ..... .... ..... ..... ...~ .... "'" - - ..... ..- ............................ .........-.............. SECTIºU_ll_=_EUY~IÇðL_D6JA___________________ ..... -- ... ......... OUOP: SHARP. CHARACTERISTIC t·1~:L.T I ¡,I C) PT: 1'1 /l\ APPEt"rU"I!': !~: : rt,EAR. GDEEN LIQUID I:' (.\ P T ! C t.,I: ';: I Z E : 1\1,': ¡:\ L.B':::: / Üi\L ~ -7 ~ 4 CL C!!Y:\ F'T: N/F CC'UJr~ : UPEE!,; PERCENT VOLATILE: ..,; .":) B 0 I L I N 13 F'T: r,!/E/ EVAPORATION RATE: tl/E V/\F'CiH F'nE:::::::!..IPE: r\¡'" F FL.¡.\';::HPO I '·n: ,::::0. :~~ \J/\POP DFN~::;J'rY: ~,/[ SPEC'IFIC GRAVITY: ()" ::::;::::: BULK DENSITY (FLUFFED): N/A BULK DENSITY (SETTLED): N!A REFRACTIVE INDEX: 1"1/E SOL.UBILITY (OIL): F'(,RTIAL SOLUBILITY (WATER): PARTIAL ..... ..... ...- ...- ....'...- ...- ..... ..... ..... ... - tJ..._ Ô ,'..' T_ f ",' U "I", A "" ~'" _ ,'.. :=:,_ ,/~,., L '.'.' f~,.., T "" Y ,. ," L'_ (1.., T '..' f.~ '... .._~~;.._ tJ_. t:... ~ .,'.' 1,_.._ ,_ _ _ _ ._. .." ..._,_ .., ._ e AG:;:'UKblNt:. Vt:.1 t:.K l\/~~' 1 L.l.I>j.l.I¡LI'I1 ¿;.. ". ..... .......- ..... ..... ~- ..... .... ....________~~ÇTJº~ 1. I, 1 ,:: '..., L T D f ,_ ~.: .... F PlOSION HAZARD DATA ...~."",.~._.",_,_..._...,___._,.__..~...._._,...__"_'ø_'_·__'__'_"·M'_...~...··,.. FLA':::H PO I ~n (MFr.IOn I.J::::E::TI): ?'~I,?'~'F. ( T('C) FLAMt·1t,BL.F:: LI!'1IT (LC!\'!U~ì~ IJ,/E FLAMMABLE LIMIT (UPPER): N'E FIRE EXTINGUISHING MEDIA: FO(¡M, Ci\PE:C'f\1 D10/1DE:, PRY CHEMIC,'\L, & \t,!I\TEP F":)C~. SPECIAL PROCEDURES: t,I':F ':::FLF-CI:'li'.IT/\ T NED BPEr1TH I NCi AF'PARA TU::;. COOL FIRE EXPOSED AREAS & EQUIPMENT. UNUSUAL FIRE ! EXPLOSION HAZARfY':: : 1',(. nOT IY::T' DIHECT ~:::;THEþ,t'1 OF ~'l.t~TER MATERIAL MAY FLOAT AND REIGNITE. ~.., ..... .... ~... "... ,,_. - , ,- .... ... ... ~ - .... ". .... -... ~,.. .... .... ...- .... .,.. .... ~... .... ... ". - -.. .... .... -", .... .,... .... _.. ..." _... ~". _... .... ,,_ 4... M... ........ :~:ECT 101,1 T ',j ..... __, .... _... .._ 4.· _... ~.. .... -... ... _..'.'" ~..... 1.,I!"I.::,I,.;,OI:I1 ! 1/,7 t'ì!) (! ............-.... .. .. "I i' .... .... ...... .... ..... .... .... .... .... ~... .... -.. .... -... ....... ........ .,.. .... -" _. TOXICITY CATEGORY: 111'[\,1 OPt-IL LD''::;O: 1. ;::7'~;i) fr: D ./ k ~~ I: t.. :J t ';:. ) [I ErH'1 td,_ L [! ':) 0 !.! / !~ I NHI\L/\T I ON LC::;(\ = ~? ~::~ or (~ Iii (J / lit ,~: I" '::: f d 1 t- ['t'F:: EFF[:::CT':':; ¡::OP(I[>i;':F': OCUI,i,l~ Ü/~I'V:I'::¡E :¡ J) THE::: F(I!~!'1 UF [P',"Tl1EI"1(~ CfIFt'IC!': I :::, I f~ IT J '::" t'I'.!CCi J L' U I ::':C~II\pIA:: ¡'\Nfl CORNE/\L.. UF' ('IC [ T\{ " ~::::I< I t'l EFFFCT~~;: I :~:: tJOT tj ::::!:: I tiT LP I'li\lll' F r TI !EP PH I 1'1t~F,{ (In SECONDARY AND DOES NOT CAUSE SKIN FATIGUE OR ':::Ft·j:;<I: T I z¡q I UN. THRESHOLD LIMIT VALUE: !--!/E ADDITIONAL COMMENTS: NONE ;f " " ",' : \ ¡" .J. ¡ I L~. I ¡, . .~. ".. I , "--' ........ . e - , . .... ..._. _..... .... .,. '..'., ..., ....t1..,6 '. T .,'~. ...8. _, J, ..,lJ ." ~=, .", .w:~.:, _.0., ...1: _,F: .,1.. .", _. .".P ..,,(\ .wT ....I)... ...'2 ...Ij... t~, _.'i ....I._, _ _. _ _ _.. ... '.' ..., _. _._. ~- -.- .~. -," .... .... -.. ..., ..... .. . ..... -~, -.. _. "". ___.. ..,'... _';:I~/;T, ,~Ç'N .,,\',.. :~, _:~,:!:::,:::,ç ~ (:',l.:.. ...,!~~,U,Qr.t~,çT IQt:]. _. .., _. _.. .,. .', _.. .', _. _..._ _. _" .,'._.._ ...' ...' .'.. _.. ...' EYE PRO TECT I UN: SAFETY GLASSES OR GOGGLES :~:;h I to PROTECT I Ut!: nUE:BFH '::!I~ HIPEP') I 0\..1:::; GLfJl/['::; RESPIRATORY PROTECTI0N: t.IOI,i\:::: L. I I<E.L.r'rO E:E:: !..!f::EU¡:,:' OTHER PRECAUTIONS: NOt,E .... .'~ .... ..... ~ .. ..... _. . . . .. .. . .... ......_. .... ._. ..... _,.' "'," ..... .., _" .... ..... ..... .... ..... _.., .... .... ..... .. .. .... ..... ....... .... ..... ..... _.' ..... _,.. ..... ..... _.. _h' ."_ _,.. ..... _.. "'" ..... .," .... ..,_ .... M,," .._ _. ._ ..... _., .... .... _.- .,....--...... ....-..., ..."........ ..........__. ';,T L';,~U ...,'..} I ," .:,~, .,',U/: Z ('?QIYJ'~, .Ç(/!::W'QUt~,t.:.' T:~,;,Ç!:~ ..IJ, P;TI),t~:I;:~"._ .', .,. .... _..... 1'1,.\TER T I":. PERI:!::!'.IT I:'HLOHCI\\,'LU!()L ~ C.í\:::; ~* ~~:::::::-,.<)i\.u(:'i 75 ~ (~I.) INEJ~T It-ICiPE:DIEt·!T':: (C(~\·::;:t l\ L'~·cDt·iei.:':jt·';' \/,::hicl,:: SYs·t'::~rn: O~:':.)) . .1.- _, _ _ '" ,_._ _._ ._, _. _ t1_, 6... T ...1;.._ ~ _,J~ ...,L .., ...~~, ..,6. .. f., .J:'.... T _., Y... _.. º ...' 6 _ T __ _.:2 _.'j _. s. .... S _. I _..._._ _, _. .... .... ._ __ ._, __ __.. _ ..' __,._ _. _, __, .... ._._ _ _..... ... ._. ._. ._~~:s.Ç~I k'~'t~. .,.1_.:: ._1 ºt~tJI.IE !..ç;Ô I. I'2t'.1..QE -':J~ QÇ!'=:.IÇ I... ._, _. _'.. __._ _.._ _, _ _. _. _.._ .. 1j~.t!I::IE. ~ I~ l':.,! ~ S. ~ ~_ ~ª .._ N 6. tJ Ç,:, : W. F. Y~JNG! INC. ll!. LYMAN ::::TREET SPRINGFIELD! MA 01103 PRODUCT CODE: 054 NAME: ABSORBINE HOOFLEX CHEN NANE~ C.A. S. NUMBEf~: :3EE ::;ECT I ON VI :~ÆE ~=:ECT I Or,) VI :::;EE ::::ECT I ON Ii I C . A. :3. NAt1E : CHEM FORt'1ULA: 1'1/(:, 1"10LECULAR "JGT: N,/A CI-IEM FAMILY: HI XTURE N.D.C. NO. 114q4 054 XX FDA REG. NO. 1210276 D.O.T. HAZARD CLASS: N/A D.O.T. SHIPPING NAME: HOOF DRESSING .________..._......n._____.__.__.......___...___._......._.._n_.__.._.....__M.......___.._.........._._.._._........_.._.,._.......__.______._ø.._..__..._._..__.._..w_____._ SECTION II - PHYSICAL DATA _.__._________._.__..._.._..'.._.,ø..-.._._.........__.._...._..__._....._____._.._.__.____.__._,__.__.______,___.___._..____._____.__._._ ODOR: CHARACTERISTIC t'IEL_ T I t'1C¡ F'T: ~5 5 -- 6 ()t:cC: APPEARANCE: OINTMENT P,t~I~TICL.E ':;IZE: N/ f-~ LBS I GAL: 7.25 CLOUD F'T: N/A COLOR: BROWN PERCENT VOLATILE: 1'1/' Î~ BOILING PT: N/E EVAPORATION RATE: N/A VAPOR PRESSURE: N/A FLA:~;¡'1PO I In: NlE VAPOR DENSITY: N/A SPECIFIC GRAVITY: . ::::7 0 BULK DENSITY (FLUFFED): N/A BULK DENSITY (SETTLED): NiE REFRACTIVE INDEX: 1.4610 - 1.4640 SOLUBILITY COIL): SOLUBLE SOLUBILITY (WATER): INSOLUBLE - .~ e /~1:::=;UH1::1NI::: HUUt-'LI:~" .,;.-' _._ __ _ _..,. _ _.._ ...t1._~ _I _..S....f>: .., "- ._6,..\:: .., _..~~.: _..6 _.1;: _..s _. T. _. Y _.. ....P _.ß _ I _f _.:2 _t! _..~ _..~._ I _. _ _.. _..,_ ... _. _. __ _._. [ , i __________________~~ÇÇ!1ºU_lll_=_E18~_~_ÇXEbºª1ºU_H6~6Eº_º6I~__________ FLASH POINT (METHOD USED): N/E FLAMMABLE LIMIT (LOWER): N/E FLAMMABLE LIMIT (UPPER): N/E FIRE EXTINGUISHING MEDIA: FOAM, CARBON DIOXIDE, DRY CHEMICAL AND ¡"Jt~ TER FOG. SPECIAL PROCEDURES: USE SELF CONTAINED BREATHING APPARATUS, COOL FIRE EXPOSED AREAS AND EQUIPMENT. UNUSUAL FIRE I EXPL..OSION DO NOT USE DIRECT STREAM OF WATER MATERIAL ·-IAZAPfY::: r"1/\TE::RI/\L l'lAY FLOAT t-1t,m REIGNITE. ..... _... _._ .... .._, M.,_ .... _'M _.. .." _n' "... _." M'" _... ".n M'" ..,. ~... .....n ... .... _.o. __. _... .... .... .... .". .... .,n ,.", .... .... .". .... _... _,.. _... .... MO.' .... ... _." M... ..... _.. _h' _.. . _ _ _.. _.n M'" .0" MO" "... _.. M'" _M. ..... ..._ .... _M' '..'" ..... .... _.. ._ _ ... .____.. _.' _. .", ..., .... .... .. .... ..., ..' _., _.. ....~} ~~ç. T I Q tJ .", 1\' .." ~:~ J:J I~ (1.1;:0, J, U JJ, 6, ~~J: 13 P.J;.I ðT 6 ...' _., ... .,. .... .'..... ., _. ..., .'. ..., .... ..' " ..., ..., ..., .... .... ..." TOXICITY CATEGORY: I I I .I I ',) OHAL LD~50: 350/Kq (Male & female rats) DERI'lr-\L L[I~:50 '7')/I";;g (Male & fem31e rabbits) INHAl.ATION LC'5(): t'!/E EYE EFFECTS: NOT AN EYE IRRITANT (FHSLA\ SKIN EFFECTS: NOT A PRIMARY IRRITANT (FHSLA) THRESHOLD LIMIT VALUE: N/E ADDiTIONAL COMMENTS: NONE e AbbU~~lNL HUU~L~^ - e ___________~_6_I_g_E_!_0_b__ª_6_E_~_I_Y__º_6_I_0_~ª_~_~_~_I____________ SECTION V - SPECIAL PROTECTION _________.__._._____.._.._.._...__ø_........__"_.___........_.___.______________._..______.__.__.____.____.__.._.______.__._____._._ EYE PROTECTION: SAFETY GLASSES OR GOGGLES SKIN PROTECTION: N/A RESPIRATORY PROTECTION: N/A OTHER PRECAUTIONS: NONE ----_.._----_._~._...__....._..__...._--_._.._.._......--..----..---.-------.-.-----.-----..-.-----.----.----.---------------..--..--------.-.- _ _. _ _ _. _.._...m '... _ .., 'm,m ...,.... ......, .., .,::::\:::çJ:, J';,I,tJ ....~~, 1"... ::, ....136. ?'(~fi¡}ÇI"'!:~: ..,ç:ç~t1eQI:Jt:~,t!T:].: _..QI:-: ..,,1.1 I 6IVt~.t:,:~;........ .._ ....., .... MI.\TEH It~L PERCENT Phenol (CAS #108-95-2) . ';:~ ~~ i: Turpentine (CAS #8006-64-2' '7 . 5()·': INERT INGREDIENTS: (CAS. The precise composition of this mixture is Proorietary information 05~) e H b :::.1_11"; b ! 1\1 t.:. t·'\I..iI_I" L" C t. e ·t·.. '" _. _. ._ _.. _. ...,.." .., ._ .J~, ..., ~ _. T .,,;~ .. e. .", I. ...' ð, ...1:-::, .." .. ~;: ., ~ _.f::, ... S ... I ... Y _. ... P.. t! _.I _I~, ..' ... ';';, Jj J~ J;' ...T .., ., ... _ _ _.. _, _ _ ..' ." _. ..... _._...". .... _.. .."_" _,..... _ _, '" ...' .", .,~:::L~çr IÇlN ,,,,\:' 1. J, ...':, _..s.t:1.!~ß.I;:~r;,uç,y'_,..~ ..f, L::~}.T .,h I.P _..c:?QÇ:r;:.pl:.:',et:.~~:... ... _. .." ,.. ... IF ~3WALLO¡"JE[I: Induc:e v(:;r(ii!.inq and r:.:ontar::t d ph>'sir:ian Ot.. P.:.ison Control Center immediatelY. IF IN EYES: Flush with plenty of water. Get medical attention if irritation persists. __"_~___H.__~_..___....__._"'__'__'_"'._'.'__".'"_.._.____.._.._..H__...."___..___._......~_.__.___________._____._..____________._______ , ... .,.._ ..,...., ... ..... ._._., _..... .", ...... .'" ..·;;,!;.ÇI J,Ç!U ..,,''/ L I I .",::: ...I~fJ:.,s,Ç: r;:, _..PI:: _Q\~t:.e. .,_F~,~.t:I~.~:;:.I,::!I3.ç,._ _. ".00 __, _. ,. __... _ ....._ N/E _.. ..... ...M.... .... __ .... .... __ _. .... ..... __ _., ..... __ ._. _.. ._. ....~... .... .'N h..... .... _.' _.. ...._ ..... _. .n. .... ~... _.. ..~ .... ~... _.. .". .'" .... _.. _. _ _._ .._ __ _.. _... "'M _" _" ..M -.. _. ..,. _ __. __ __ ~.M _ _.. ~". "". _" _. .." _.._ _.. ......._ .." .", .,..." ..., ..,.", ...,... .., ." .,. .." '''''' ...~J;~:ç T J.QU.., 1.. '(:, _..::, ...:~:t: Jtct('Ç~I~ ..,Ç.!I] _~",I~{::~U:!I;;,I;, ..,eI3.ÇlI~:Jj~Ç!I::!I3.!;;:2 _.... _,._ _. _" ,... LEAKING PACKAGES OF THIS PRODUCT MAY BE DISPOSED OF ON SITE OR AT AN APPROVED WASTE DISPOSAL FACILITY. ','t' e ABSORBINE HUU~LEX e ~~I-' ... ....... .... ...,... _.., ''''.'' ....1:1. _..6 .'.. I...,~~, ...,!] ..', I....6 .,.,~,.., ,:::: _,..~j _..I:. ...,1; ... T ..,Y, __p .,.,6.... 1.,,(:. .,., ._:~: ...t~, ..s .,'~ .,J.: _..... ...' ... .".. .__...., ..,.. SECTION X - WASTE DISPOSAL METHODS -.- -. -.. -- -. .- -..- -. .... .... "oO' ..., .... ..'_ ._. .... _.. _...... .,.. _... .... .... _... .... _" _. .... .... ... .... .." .._ .... _.. ..... _.. _" .." _" .... _.. .... _.. .... .... ..... ..... ._. ._. .... _. __ ._. _.. ..... ._ .... _.. _.. ..... __ _..... _.. _.. __ - _.. N/A -~-~--_....__..__...._--_.._.__.._._.._.._---_..._._.__.-..-..--..-..-..-.-..-.-----..--.-..--......-.-..-.....--..------.--.------..-.-........----..-. ...._, ... .., .... .,. _. ......., .". .", .... ... _.. ..,..., '" ..~~;I::Ç.T, !.I~,IN ...,6 J., _-':: .,.,6.PP!.'r !.QU.6~~, _t.','3,I~.';:6.IJT !,ÇI,t:J.';.:.... _. ...... ". ...,.... .", ...._ .., ...... _. ......... KEEP OUT OF THE REACH OF CHILDREN. FOR EXTERNAL USE ONLY. DO NOT APPLY TO IRRITATED SKIN. IF EXCESSIVE IRRITATION DEVELOPS, DISCONTINUE TREAT- MENT. AVOID GETTING INTO EYES OR ON MUCOUS MEMBRANES. -.......--..-.......-..-..........-.....-.."..--.--.-......-..-...........--.-..............-...........-........-.-.....-.......-...-.....-..-..-....................-..--....-..--.--....--.............-.......-..---.......--.---....--.. SECTION XII - COMMEN'TS ..... ..... ..._ .'" ..... _. ..._ .... ..... .". ..... ..... ..... _.. .." ._. .... .... ... _. ... .". _... ..... .... ._. _.. _. _.. .... ._. _. .... N.' _.. _" ..." ..... _.. .._ _ _" __. _.... .... _... _.. _.. .... .... ..... .... .... ..... _.. _. ..... _.. .... .... _.. .... .... ... ..... _'n _.. _.. ......_ .._. THE INFORMATION CONTAINED HEREIN IS BELIEVED TO BE ACCURATE WHETHER ORIGINATING WITH W. F. YOUNG. INC. OR N01. W. F. YOUNG. INC. PROVIDES NO I,.j(.j:m I\I'IT IE:::;, E IfI-jl::P \:':::i. F'P FS:;::F::O UH n11='1.. H:D. fiND 1\¡:::;:::;I.I·1E:3 1,,10 R E::::;PON:::: I - BILITY FOH THE ¡\CCUH/\C:Y OP CCit'1F'LE1ENE':;:::::; OF TI·I[::: D/~T¡\. RECIPIFHT::; I\RE ADVISED TO CUNFIRM ANY DATA! IN ADVANCE OF NEED. THAT IT IS CURRENT, APPLICABLE AND SUITABLE TO THEIR CIRCUMSTANCES. ø._..___M..._...___._....._....._.__.............._'.·_..··...···········_ø··_,..····__·......·..···_....·._.._._...._._......._.._.._._......._.........................__.__._._,.._._.__..._.__...,,__._.,.__,_._.,._.__.._.._ ___________________fÇÇI!º~_~l!l_=_eEE~~ºlX____________________________ _ MATERIAL SAFETY DA1A SHEET PREPARED BY: DIRECTOR. SCIENTIFIC AFFAIRS CORRECT AS OF FOLLOWING DATE: FEB. 1987 EMERGENCY PHONE NUMBER: 413/737-0201 N/E **** NOT ESTABLISHED N/A **** NOT APPLICABLE DR~:;/ddg ~ .. " " ~ e . .. MATERIAL SAFETY DATA SI-ŒET Dale of Issue: OCT ] 989 ~' I DLC\TRIBUTORS ADDRESS: TELEPHON E NO.: EM ERG ENCY PHONE NO.: LEXTRON, INC. Prepared by: COnlact your local 630 "0" STREET. G REELE Y CO 80632 VJ K (303) 353-2600 Poison Control Ccn ler. ..JlODUCT NAME: CAS NO.: LEXTRON RAT Z A P RO DENT B AR, LEXTRON R AT ZAP 8 2- 66-6 CHEMICAL FAMILY: CHEMICAL NAME " SYNONYMS: I ndandione 2-Diphenylacetyl - 1 , 3-Indandione CHEMICAL FORMULA : TRADE NAME It SYNONYMS: C23H 1 6°3 Diph ac mone : , '::"':'::;:::'¡"!SÊØ'Î}ÎÔNE!:m\:ž~DÔUS:ÍNGREDÍENmS": , , , : , : .. : ..'. , , : ..' .. .. ;~;!:~;~:;{:\!;~:~:f;:;:~;;;!:::;:~;: . : '0' ..:.:..:,....:-.,:. ., :.:..:..-......;....... ,:,.,:-.:,:. : , ...........'.;:;.:;:;::::::::.;.;..;. .. .;.;.:.:.:.';...;............ . : : .... n ........_... : .... . . . . . . . . , . . . .... .. .. ................. ......................'..... .. .:.-,;.:.,.:.;;::.;:::':::;:::;::::.;:;:. , , .. : .. , : , , , , ,', , , , ..... , , , , , , , , , , , , , , , : : , , , ;'.-.'.......-:.:-........'....-:........'.:-,...;.._;..;..:.'..;..<:.;-:.:.;.:.:.;.; , : , , , ...;.;.;.:.;.'.;;.:-:.:.:.:.:.:,:.;.:.:.:-:.'.;.'.:. .. ...... ....... .... ..... .............................'...:...;........;..-:.:.;.:-:.....:.;.:-:.:...:.'.:.:-:.:.:.:.:. .... .. .. ...... ..... , , , , ......................'....... ... ACTIVE ING REDIENTS: % CURRENT TLV Diph aci none .005 N.E. (dry solid) .................... ;.:.;.:.;.;.:.;.;.:.:.:.;.:.:.;.:.:;.;- .................... .................... ............. ...... ..... .... ..' , , ......... . .. APPEARANCE " ODOR: MOLECULAR WElGIIT: MELT POINT: SPECIFIC GRAVITY: Yellow Crystal 340. 36 1 46- 1 47 0 C NA VAPOR D ENSITY (AR= I) : COLOR: BULK DENSITY: (Finished Product) BOILING POINT: NA Yellow Crystal 42. 6 lbs./ft. 3 NA ( \POR PR ESSURE: SOLUBILITY: WATER REACTIVE: EV APORA TION RATE: NA Insoluble In water. NA NA ...........,..........................,..................................... .. .... . .. .'. .......... . !II...... ," ,_', ,...... _, .', , ,."..,'. , :- ...,.... .. ..... .... " ,_ ':",", ...... .,'. . .. ..... .'._ .... .............'...................................,............................. :::~\~~;::~~;:::>:::;:;:~::::;:~::;::::::::::..:'.:.:::::;:;:::::::;:::;:;::::::::::::.:::::,::,:;:;:;:;:;:;:::::::;:::::::;:;:::::;::.:;:;:::::::::;::;::;:;:::;:;:;:;:;::::.?::::::::;:;:;:::;:;:::;:::::::::;:;:=:::::::::::;:::::::;:;:;:;::::::.::::::::;:::;:::;::;::;:;:;:;:::::::;:;:;:;:::::;::::::;.:::::::::::::;;::::;::::::::::::;::::::::::::::::;:::::::::::~:::::::;::::::::::::::::~::::::::::::::;::::::::::::;::::::::;::;:::;::::;::::::::::::::::::::::::::::::::::::::::::~::::::::::::::::::::::::::::::::::::::::::::::::::::::::::;:::::::;::: ... . .. . FLASH POINT F (METHOD USED) : FLAMMAB LE LlM IT: AUfOIGNrnON TEMP.: NA NA NA EXTIN GUlSHlNG MEDlA: Extin guish with water, foam or inert gas. SPEClAL FIRE FIGHTING PROCEDURES: None UN USUAL FI RE OR EXPLOSION HAZARDS: None STABILITY: CON DITIONS TO A VOID: S table. None POL YMERIZA TlON: CONDmONS TO A VOID: Will not occur. None lNCOMPATABILITY (MA TERlALS TO A VOID): I HAZARDOUS DECOMPOsmON PRODUCfS: None None ~~- \ [Rat J 3 .0 mg/kg ( 1 00% AI) NE NE FISH, LC50 (LETHAL CONCENTRATION): SKIN IRRITATION: OTHER: NE NE NE · e e 'o- " " .. ,." ·....·'·<q·ß~C]'ION:VI. 'llEALTI:!.1{A~~JWPAI~~f'Eß9B~~Æ: PRIMARY ROUTE OF ENTRY: MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: [II Ingestion 0 Skin & eye contact N o Infialation 0 Skin absórotion one HEALTH HAZARDS: SIGNS" SYMYfOMS OF EXPOSURE: ( 1 - Caution may be irritating May reduce clotting ability of the blood and cause bleeding. EMERGENCY flRST AID PROCEDURES: Eyes: Aush wiÙ1 plenty of water. Skin: Wash wiÙ1 soap & water. Inhalation: None Ingestion: Administer Vitamin K intramuscularly or orally as indicated in bishydroxycoumarin overdoses. Repeal as necessary based on monitoring of prothrombin limes. SPECIAL PROTECTION INFORMATION: ~t¥l~ Caution None RESPIRATOR TYPE: None EYE PROTECTION: None OTHER PROTECTIVE MEASURES: None .. , GLOVES: Rubber gloves. I VENTILATION: None , ,"" ", ")SÊCOCíö~¡¡~lnLusPŒûôR::rIÊmPRöc@,~RE'··J:jÊ'ERãnti(i .... ,.... :.;.»:.:.»..:.:.......:.......... ... ,.' .... .. .........................................'.. ......... .......... ..... ...,.. .., :::::::::::.:::::::::::::::::::; ::·:~:::~:¡:~:~:~:t~:Œ~:(ð~:¡:?~:~:~::::::::··: .:->;.::::::;::::::::;:::::::::;:::::;::~:::::::: :. ~:;~~:::?[;¡rt¡(f~it¡ª;!:f;\:.;::::·::· STEPS TO BE TAKEN IN CASE MATERiAL IS RELEASED OR SPILLED: General clean-up. f WASTE DISPOSAL METHOD: Wastes resulting from use may be disposed of on site or at an approved waste disposal facility. ':::!:!::'·:SÈcTÍoNlXi:!sPEêÎÄu:PRE@Ä:UTIONS:&ST0RA:GE'iiJITÆ'ØE:PRê)DÛøi::~i¡M::::::':,;,:: .. .;~;~:~:~:::~:~::;::'.. '.. ."'" -::'..::-: :':'" - :::.::::::.:::::::::.:::.::.:.:.:,..::::::::....:: :::: .-,. ....:-.. - .'--.-,'. .... ." "::'" .';:;". .'. .....'.-...;.'.:. :. .::.. "-':: .-:::-.. .:. .-.-:.-.. :'::"'-:-;':'::: :.::::::. .'. .:<.... .': '-.' .':-.'. -.::-.". :'::~:: .:. -..... ::::::¿::~:::: :.:: :.~:: ~: :':.: :':::- >:..',.... ":;;::', :./:,-.: :':':':':':':-:'~':'" : . .:: :':';,::..;:~~~ :.::/t~tt>t~~} STORAGE TEMERA TURE: A VERAGE SHELF LIFE: Room temperature. Stable. SPECIAL SENSITIVITY (HEAT, LIGHT, MOISTURE): None PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: None - TECHNICAL SHIPPING NAME: Rodenticide containing Diphacinone D.O.T. SHIPPING NAME: Lextron Rat Zap Rodent Bar, Lextron Rat Zap D.O.T. HAZARD CLASSIFICATION: Non-hazardous D.O.T. LABELS REQUIRED: I ON: None . Class 60 ¡,' WARRANTY: "- The information provided in this Material Safety Data Sheet has been obtained from sources believed to be reliable. Lextron provides no wammties. either expressed or implied and assumes no responsibility (or the accuracy or completeness of the data contained herein. This information is offered for your consideration and investigation. You should satisfy yourself that you have all current data relevant to your particular use. , "." · __ _ __ __ __ __ __ _tL0._ U;:_13~__ 1\ _\0__ _"'- l\_tC_L LL __º _"L L '_,,, __t! _ L(;. _L ___ __ __ __ _ ~~__ ___________________§~ÇliºU_l_=_1º~~IIElÇ6I!ºU_ºE_EEºº~ÇI_______________ Ij~, t! 'd E ð ç ~n:!l3. t~, 13, :_ ~~: .}Y\~1, ~, : H. F. YOUNÜ~ IHC. 1. 11 LYl'lAN ~=;TREET SPRINGFIELD, MA 01103 PRODUCT CODE~ 047 NN1E: ~\B::;ORBH!E :=;UPER~;·nEL.D 1. I C. A. :::; . NAME: ~:A'::E :::;ECT I Ot'·~ V I :::;EE: ~;ECTION VI , f r: ':;.ECT I ON ~JI .:. :::.::' CHEt1 NAt'1E: C. A. ~::;. NUt·mER ~ CHEM FORt1ULt-,: N/A 1'10LECULAR I-JGT: N/A CHEM FAMILY: 1'1 I XTUHE F.P.A. REGISTRATION NO: 1543-8 E.P.A. ESTABLISHMENT NO. 1543-MA-l D.O.T. HAZARD CLASS: N/A D.O.T. SHIPPING NAME: N/A _.._.__._.__..__._...........__,.......__.._.._......_,.._._·_.········__·_·,.·__.._·._.·····_····h_.·_____.____..__...__.....____..._.___.,.....__.....__.._.....______.._.._.._.._________.__. .... _.. _.,., ..._.... ...' ...' ,.._ ..., '., ...' ....,.. ..... __,:}t~ç..:r, IQU .'" 1. 1. ...,'::, ..e,lj'.c;: tÇ(:",= ....P6T0, _. _._ ..., _ _.. _..' _.. _ _.. _, _.. _. _ _ ...' ..' ... _" '''''_ _...... _.. _,..__ ODOR: ::::;LICiHT ';IEt.. T I 1-1(; F'T: t\I/E AF'F'EAHANCF: l-JHITF Ft'IUL:::;ION F'~\RT I CLF ::n Lt::: Nh\ U::::; / GAL: :::. ::::() CLOUD F'T: t\/E COL.OF~ : t·.!H I TE: PERCENT VOL.ATILE: t··1/E BOILING PT: N/E r::'.)APOPl~T! C!H Rf~TE: N/E VAPOH F'F{E~;~=;IJF{ E: "1.lE F L,I\:::~'\F'O I NT: "1.1 A ',.JAPOR [tEN~:; I TY: )'1:' E SPECIFIC GRAVITY: () . '~I'~I~.5 BULK DENSITY (FLUFFED): N/A DULY DEN~=; I TY (~::;ETTLED): N.I A REFRACTIVE INDEX: N/E SOLUBILITV (OIL): PARTIAL SOLUBILITY (WATER): EMULSIFIABLE e F~E:::::URE: I NEêUPEP:::H I f::.LIJ J J r':.- ___________~_ð_!_~_E_l_6_~__~_0_E_~_I_Y__~_6_I_0__âJj_~_~_I____________ ...___. _.. _.. .... _, .... _ _.'_ ..., ..., _, _,... u' ..., .,.:~:t:'\J,:,1..\~IU ..., t L t _..':~, .,f,=, U,~,~ ....?~ _,f;}J::~\::,Q:~:, I.'2tJ. __I=!(1 Z.ðI2'J~' _Jj,(! 16 _. _. _.. ....._.... __... _" _._ FLN::H PCHNT (I'1ETHOD IY:::F[t): I\j/I~ -- NOHFLAI'11'1ABLE FL.AMMABL.E LIMIT \LOI·JEP): t'l/l\ FLAMMABLE LIMIT (UPPERj~ NiA FIRE EXTINGUISHING MEDIA: N/A SPECIAL PROCEDURES: N!A UNUSUAL FIRE I EXPLOSION N/A HAU~RD::: : -..--.-----...----.-......--...........-------...............,...--....-......-.-.--.-----.--.-......-.-..---.-.-....-.....--..-.--.....---....------.---.--.-.....,--..--.-.. .... .',.. ..., ..,'.., .... ..., _.'_ _..., ..' ..., .,_ _._ .", .::=:sç,r 1,\~,'N ...,l~·~.m-::~' ....!J~~6l.:,Ilj ..Ij(~, u,\,Ij,r! .",I~~I~\T(~ .,. __ ...' ""'m._'''''' ... _" .... ..' _ _" __.., _" .,. _ _,.... TOXICITY CATEGORY: III,iI\) ORAL L.D~:iO: ~::70()0 ;~:::: 1 00 maiko (Male rats) mg/kg (Female rats; DERI'1AL UY50 :> ;;:(il.)i.) lng/I:: q II'IHALAT I ON LC~50: :> (:'? () rn q I 1. i t E' t· (1 f alt· EVE EF:¡:::l::CT:='::: 1'1II'jlr·1/~l., TP/\!.!'='::IETIT OCUI.J~P RE/>¡CTION It·~ THE FORI'I OF EHYTHEì'I/\ ~ C\!C!"\O:::: I '::: Þ,t'-1D PI ':::UiAPCi[. RETURt,!::;; TO nOm'1AL \oJ I'lH I N OI")E TO FOP TY E I IJHT HOUI~ ::. . DERMAL IRRITATION: MILD DERMAL REACTION. THRESHOLD LIMIT VALUE: N/E ADDITIONAL COI'1MENTS: Not..I[:: :<' e 1\ \:: ~::~ \"ltJ ¡:.: J hI t: :::; \ \ ¡.:., 1.- (j :::; LI l' L l L I 1 1 1 -, .. -, r, .. . ,. t_, e \.:, r, .. IlL:. - , .. _ _ _ _ _. __ ...._ '''' '" _.t~ __ð.m I _'of;., ._e ." I .,,~~ _I,:... ...:~;. ...,(~.._.t: _,t, ...J~ ._,Y ,,_,...l.,I__6 _. I_.(~ _.. _,';;,..Ij _.s _.s .._1 __ .... ..._.. ..., _, _. __ _ _. _. __ ___________________â~ÇILQU_Y_=_âe~çL0~_E~ºT~ÇIIºU______________________ EYE PROTECTIC)t\l: SAFETY GLASSES OR GOGGLES :::;1'; 1 N PROTECT lOt,): PI..IE:E:[H on J I'WEf::V I (11..1:::; ÜLO\}[:::: RESPIRATORY PROTECTION: NONE LIKELY TO BE NEEDED OTHER PRECAUTIONS: t\IONE _~. __ _ .... ..._ ..... ..... _.. ...., ..... _... .... _" ..". ..... _0"' ~........ ..... .._ _.M .... . . _.. ..u ... ..... _.. .,.. .... _.. .._ _.. _" __ _" __ _ .... _.. _.. ..... ..... .", .._ ....' ..... ..... ..... _.N .'" ..... _.. ..... ..... .... ..... '.... _.., ..... _... .... .... ,..,...... ..... _.. _.. .... .._. .'".. _ _" .... _" _...m....'... ", .", .",... ".' .', ..., ..:;:!~:,I;~,:r, L';'U ...\:!, 1. _..·:,...IJ6f.Úr3.PQI::I:~:. ...ç:QI:J.EljIJI;',IJ.I.::;: ,..,Qt":=,J:J. 1. ~.J.:,I=:~U.I~~:;, .._ .... .._ _. _,_, 1'1/>¡r!:::f~ I/iL F'EPCFI'IT Butoxypolvcropylene Glycol (CAS #9003-13-8) 10.00 R '='~, me t ht· in [':'". ( Dh,:''', \' 1 In,:: 1, h v '], ,...:~ fu t":,tn :~' J ] rn,:,·t h:,"' 1 :~~;, ,2. -dimethyl-3-(2-rnethvl-l-D~openYl) cycloproc3necarboxvlate and n E:' 1 =.:t t e d Com¡:::, 01.1 i: I ~ S;, ( C Ii';:, n 1 (0 L! '::~::: ...:::::.-:'. -..::;:, :' O. ':"~~,::;:: INERT INGREDIENTS: conditioning agents c.:,Y"tO;:2rn: 0(17) Mixture of solvents stabilizers and (CAS #A Proprietary surfactar!1 e ,', 1.:::':, Ui'; L: J. r: l::. :~:-u~,..t. ~~ :;::,H J. LL, I) J 1 e ,+.- ...... _,.,.......... .... ..., .,... ...tI._ ~ .",I ...1;:..8 f._(\ .,L.. ,...,:~: .",(1, ..,,!.~ .,_~~, _.1 .".Y..., .', ç,' ,...'~,., I .,0.. __ _..:2 ._~j _us. ...,s _.1 _ _.. __ .,_ _, _.. __ .... __ .... ..., ..... .... ... _. ..., .. ._ ... ....... ..., ... _. ..., _.. ..., .. _" .", :~,;, ~~\:, I !'Q U ..V, 1. I '" :: ._ t~.tl f:, f3{i \;~ tJÇ,]:, .3, _J::~ I 13, :~: I _.. ð H! _ ':J3.1~~ !~,: sJ! 1,).13. ~ :~~ _.. _, .,.. .'_ _.. IF SWALLOWED: Contact a physician or Poison Control Center immediately. IF INHALED: Remove affected person to fresh air. Apply artificial respiration if indicated. IF IN EYE:::;:: Flu~;h '""ith pl('~nt'! of 'fJi::\to::.~t·" Ü.,'"t H1,:;:dical att'2nti.on if irritation persists. IF ON SKIN: Remove contaminated clothinq and wash affected area of skin with soap ~nd water. Contact a physician if irritation pet-sists. __.__.______.__.__._~....__.__...__ø__...___.·__._·.____...__.___...._.._..__._.__._.__............___.__._._._....____.~__._____~__._____ ___________________$~ÇI!ºU_Yl!!_=_~EEÇÇI$_ºE_º~ÇR_Ç~Eºâ~~~_____________ N/E ._.. _.. ._ ~... .... ...~ _.' _... __ .... ..... _., .... _... .... __. .... .... .... .... .... __. .... em.... _.. .... ..., ... .... _.. M"' _.. .... _., .... _.._ .....",. h" .... .... _". ..... .... .... .... .._ .... .... .... .... __ _... _.. "__ __ _.. _. ..... .m .... ._. ._. ... _ _. __ _.. .... _., .... .h, _.~ ._. .". .... .." ..... '.." .". .... __. .... .... "" __ _,.' _ _:~::,I:~Ç,I !ÇI~\I.", IX, _..: ...'~~I:~' II:,I,~/.\Ç¡i:.~ ,,1;,:'13, ...\:r,J::,~:':,~{}{. .J~:,f::Çn;tTII)G:;:,:';: _ _ ... .,. .,. ... ..., .,.. LEAI<ING PACY:,:\UF':::: or=- TIE:::: F'PCJDI.I(T "I/IY CF: DI::::F'(I:::;!::D ()F CII'J :::::1TI:: OR ,'~T I\N APPROVED WASTE DISPOSAL FACILITY. :. e /è', L~' '::, UH \:: 11. ',:.IJt" t: r; ',:, \'\1 Ll. U J. 1 ::'.1-- .., .'. ... _.. ... _, _ ... ". _oO _. tI _. €~ ..., T _. ~, _ e.., I .. fj, ...,1", 'oO .., '~~ .'" (', .,.. ~~, ._ S ._ T, ._, Y. ...' .,. p ... (~" ..' I _.. 6. ...' .... :~~ _...Ij _, S. ._, S _ I _ _, ." _. _ _ _ __ ._ _ _.__ ... _, _. _, ..,._ _._ _ __ _.....m .,. _, .,.. __ _" ._':::!~~{:r, JI)U, ." X, ..,:~ _,.~l,,:~:If,. __p t~:I:,'Çt:~,;f..lt~ .1.~1E:~TIjQP':~.: _. __ _oO _.. _.. _oO _. ....' ...,.. __ _. _. 'oO _.. _. _ DO NOT CONTAMINATE WATER. FOOD. OR FEED BY STORAGE OR DISPOSAL. WASTES RESULTING FROM USE OF THIS PRODUCT MAY BE DISPOSED OF ON SITE OR AT AN APPROVED WASTE DISPOSAL FACILITY. CONTAINER DISPOSAL: TRIPLE RINSE (OR EOUIVALENT) THEN OFFrr FOR RECYCLING OR RECONDITIONl~!G, OR PUNCTURE AND DISPOSE OF IN A SANITARY LANDFILL. OR INCINERATION! OR! IF ALLOWED BY STATE AND LOCAL AUTHORITIES. BY BURNING. IF BURNED, STAY OUT OF SMOKE. _M_..N......__._.._...M._________._.____.____.........._....·,...,..·.·..M......,·......__....._.._·h....._,__._._.,__...__._.._________._._..___.___....,.._..___.....___.._.__......_ ______________...____§CÇIIºN_XI_=_6Pº!!1ºNðl_EB~Ç6VIIºNê_________________ T his p toO 0::< c:I L1 C tis, to:,:: i c t (I f i ~,h . !o:: '::. ;,:' p 0::< L\ t (:1 f 1 d k ,,~ ~:,~ s t toO .:2 am:;, 0 ,., p 0 n d s . Do not applY where runoff is likely to occur. Do not contaminate water by cleaning ~f equipment or dispos31 of wastes. Apply this product only as sp~cified on the label, --...--.....-...-.-..-..--.-.-..--.---......--.-......--_...-..._..__._..........._..__......__._.._.~-_....-.-...---...----..-.----.---...-.-..-..--..-.--..-------.--..-------..-.-.----.-. _____________________3~ÇllºU_XJl_:_Çº~0~UI$____________________________ THE INFOr~t,'1t,TIOt'! i'::OtIT/¡It-.!['rt HFHEIt\! I~:::; E:'=':LIF',)FD TO 1::1:': (:..,CcuP/j·rc \)HETHEP OF: I Ci 11'-11"\ T H'j() h! I T\1 ~1 ~ F. ·¡'C:lIoOHIC~. HIC. Of~ riOT. 1.-1. F. YCUNC~! I NC. F'R 01) I OF:::: NO \.,IAPHANT IF::::;! \: I T\ n:p EfF'PE:::<::,FD I~\r~ nWL I ED ~ (.jlm r<:;::::;UI"IF:5 hlO PE"::;PC1tj':: 1-' BILITY FOR THE ACC0PACY OP COMPLETENESS OF THE DATA. RECIPIENTS ARE AD"iT::;E!) TO CO'!¡::"IH!1 ¡Ü'!,' ¡)fll/>,! 11,1 {\O\,1ANC[ OF NCE::U! TH/1T IT I:::: C:UHREtn ~ APPLICABLE AND SUIT^BLE TO THEIR CIRCUMSTANCES. -----...-.----..---...-............-.............-....... .,.............-.......--...-..--.......p.-.-.......-.--.-.-----.--.-..-..-..--....--....-..-.þ...-.......--.__.._.,-'.._.__.__......_._~..._,_._..,....- ...--............-.- ...--...--......--...... ....... ",,_ ",' ,_. '~C ç I I Q U ",_ \ J I 1_ ::..,I.~ E: [E; t:J D I}::... ..,. ,_ ._,. .., ,.,. " ".. ,...._ ,., ....... ... ..., .._... ,.,.. _ _." .... _._ ... ,_ MATERIAL SAFETY DATA SHEET PREPARED BY: DIRECTOR, SCIENTIFIC AFFAIRS C:OPRECT A:":; OF r=-ou.cl\.-JI tKi N·TE::: FEr::. 1'?'¡':::7 EMERGENCY PHONE NUMBER: 413/737-0201 N/E **** NOT ESTABLISHED N/A **** NOT APPLICABLE DR:::/ddg .. I , ", "., V \ l/V// \ It e . :. AKBRXCAN CYANAMID Dnm, JŒW JERSEY 07470 Page 1 of 5 MATBRIAL SAFETY DATA SHEBT BMERGBNCY TBLEPHONE: (201) 835-3100 MSDS NO. 0975-02 CAS NO. 16595-80-5 DATE: OS/29/86 SYNONYMS : TRAMISOL Levaaisole Phosphate Injectable Solution 13.65% Levamiso1e Phosphate anthelmintic for cattle. PRODUCT IDBN'l'II'ICATION TRADE NAME: CHEMICAL FAMILY: MOLECULAR FORMULA: MOLECULAR WGT.: Not Applicable Not Applicable Not Available WARNING STATBKBNTS KEEP OUT OF REACH OF CHILDREN. IlA2ARDOUS INGREDIENTS COMPONENT CAS. NO. , TWA/CEILING 2.5 mg/m3 TWA 5.0 mg/m3 STEL ,. Levamisole 16595-80-5 13.65% ( - REFERENCE: CYANAMID '83 PHYSICAL PROPBRTIES APPEARANCE Colorless to pale yellow liquid; AND ODOR: odorless. BOILING POINT: Not Applicable MELTING POINT: Not Applicable VAPOR PRESSURE: Not Applicable SPECIFIC GRAVITY: 1.11 VAPOR DENSITY: Not Applicable 'VOLhTlLE (BY VOL.): About 77\ water by weight OCTANOL/H20 PARTITION COEF.: Not Available PH: 3.0 - 3.5 SATURATION IN AIR (BY VOL.): Not Available EVAPORATION RATE: Not ~Plicable SOLUBILITY IN WATER: ' Misc le .' 0····, ,.... . .;.~.:.: ..... . . t '" - 1 - · , e e rses No. 0975-02 Page 2 of 5 I'IU AND FLASH POINT: Not Applicable BXPLOSION FLAMMABLE LIMITS Not Applicable HAZARD (t BY VOL.) Available INJ'ORHATION AUTOIGNITION TEMP.: Not DECOMPOSITION TEMP: Not Available Extinguish fire usinq aqent suitable for surroundinq fire. (Material itself does not burn or burns with difficulty. ) < lŒ'PA HAZARD _. RATING Hazard Ratinq Not Assiqned By NFPA ,REACTIVITY DATA STABILITY: STABLE CONDITIONS TO AVOID: NONE POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NONE No specific incoJlpatibility. Thermal ãecompostion may produce carbon aonoxiãe and/or carbon dioxide. INCOKPATIBLE MATERIALS : HAZARDOUS DECOMPOSITION PRODUCTS: .... é\Ú , .. - 2 - .. e e /, '!SDS No. 0975-02 Page 3 of 5 JlBALT1I HAZARD TOXICITY DATA AND IHFORKATIOH EFFECTS OF OVEREXPOSURE : - No toxicity data is available on this formulation. - The acute oral LDso for technical material is 1.17 g/kg (rat) and 194 mg/kg (mouse) indicating slight to moderate toxicity if ingested orally. EMERGENCY &I FIRST AID 'PROCEDURES: If Ingested: Induce vomiting by giving two glasses of water and (1) touching back ot throat with finger or (2) giving syrup of ipecac, 1 oz. NOTE: Do not induce vomiting in an unconscious person. C' ( .' ({,'.. ..~.. .... ,.( ......; - 3 - ',' '.,~ ...........~_..._..._~,~..._~~/~..:.._...... "'r' . ._ ·~DS No. 0975-02 ... .XPOSORB CONTROL UTBODS e e Avoid ey. or akin contact. Page 4 of 5 SPILL OR LBAJt PROCED01U!:S STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WASTE DISPOSAL: Cover spill with an inert absorbent material such as sawdust or clay, sweep up and place in a container tor disposal. Flush area with water. Dispose in accord with local, state, or tederal requlations. ,. , I \ NONE ("1PBC:tAL Ra:BCAtrrIONS ~::'. r;·;··- . '... HANDLING AND STORAGE/OTHER: - 4 - ~ e e '" I Page 5 of 5 .iPPBJltDIX TRAMISOL IS A REGISTERED TRADEMARK OF THE AMERICAN CYANAMID COMPANY SOURCE AlID SHEET NO.: .,' \ "ATB IItJ'ORJIATIOH DATE : , 0975-02 OS/29/86 ( The information and statements herein are believed to be reliable but are not to be construed as-a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTIC'tTLAR PURPOSE IS MADE. f!.;~.. ." .... ....;. '~.' - 5 - .¡ ¡I F; e ~~~A TERIAL SAFETY OAT A SHEET e ~~ FERMENTA ~~ ANIMAL HEALTh Date l'lepared: I',ay, 19í'8 hTG/JUJ'" ~an\lf.élcturer's Hame: Ilddress: FE ~~!en t a "11 j ~;a 1 lÌl'a 1 t II Company ì:"l(ll~\" 1iíial1Y Splill[,S I'a;'h,:~y ¡;an.sas Ci I~·. ~;{1 (.l. 1 ~O-l~)O EmergclI<-)' Telephone Ho.: Olher ]n!ormatilln Call: {('l)~) :,R:,-';(I"C' «.(IQ) :?7~'-4:~'3 (£10(1) 4:2-{':,::· SECTlON 1 - I DE.t-n TY Common Name: (used on lal/cl) vi ch101"\'<.'5 (Trade Name [, Synonyms): J..q;:ard Svine \.'ormer: Chemical Name: Formula: 2,2-dichloro\'ind dinl!?lhy') phosph2t<.' C4 H7 C12 04 1" C(IS Ho.: l>~-ì5-- A\r.ard V Svine Anthelmintic Chemical Fnmily: Orfanophosphõlt> Eé-H:: SECTION 2 - BAZ/ùWOUS INGREDIENTS Principal Hazardous Component(s) (chemical [, common name(s» ¡ Threshold Lim:. Value (units~ PEL = 1 MG/M3 (TUA) ski Dichlorvos, drug grade 2 1. O;~ Recent dichlorvos studies in laboratory animals by the National ToxicoloGY Program )12\ demonstrated possible evidence of carcinogenic activity. Several other chronic stuói( have not shovn evidence of carcinogenlclty. hTGARD is a resin pelleted dichlorvos formulation reducing human exposure. Avoid contact vith skin. Upon open~ng sealed package, active in¡redient (dichlorvos) release is initiated. This FDA l~gulated dr~ is solely for use in s~ine. Read the product label prior to use for handling procedures and safety precautions to further minimize employee exposure. SECTION 3 - PEYSICAL & CHE~ICAL CHARACTERISTICS (Fire [, E>:plosion Data) !~ / ;.. Specific Gradty: (E~O=l) ¿ Vapor Dens i ty (Ai!: = Vapor Pressure (mm Bg): I~ot .L.;)Pli-:a: Evaporation Rate 1): N/A (--- = 1): Not ADp1i::~ Reac ti vi t)' 1n \"atcr: !~o Eoiling reint: Not Þ.p;:-l::cable Percent Volatile by Voluroe (i:): Solubili ty in Vater: Appearance and Odor: Flash Point: NIP. Ex tinguisher Media: Special Fire Fighting Procedures: ~€ar self contained breathing aD~aratus and i~Der\'io~s ?rote:; clothing. ¡~ee¡:> r~sièue out of sur~ace ','ater ê-r.d se·,·~~·s. Dike liquid. IsC'late ar'2ë and keep unauthorized neoDle a~av. Unusual Fire anà ., . E':plosion Eaz2ròs: ~-=ith s:.!.f:icient h·2ê.t 0: ~u:.-ninb~ 'tc:·:ic ancl/Qr no:·:io\.!s h::~::cg€j"': chloride and ca=bo~ monc~i¿e ~ases and ~i:~~c=vcs V2~0~ :~n Evol~e. 1.2 ..~. E S Clear ~o Dele y€llov g~anula~ res::n FlammêDle Lic:its In Ai: % by Volume: Dellet vith œild : h'2;',j c 21 oò 0:' Lo\.'er lip .~~ ê t ~ :-- Spr2;: . CO2, F02m Not ;'.pplicable Au to-lg-ni tion Temperature: No: l-.pDl:'-:é: SECTION 4 - PEYSIC?~ RA~tS~S Stability Unstable Stable [ ] [¿ J Conditions to Avoid: :¡ e e ]ncompatibilily (Katcria) 10 ~void): Hazardous lIec(lrnpo~;i I ion I'r (ld\lrl~: Jln~ill dCHI,S }'o) :-'mcri z;¡ t i (1n ~'i 11 -- - --- ----- !~{'\I I-1>1·]i(¡¡[,]f' H y 0 ; ~, r. e 11 (( I l {'\ I 1 de \'\ ( 1'11;\' I! ~ t j r>!, . Kay OCCllr I I I~(lt OC('lIr 1>:1 \ 10(,\ n;,,] ò\:'( (lrp('~' j t' j (,". c: t I (111 j II ( (I ~ I' h· \ E:' ((lm j Ii 0115 I (I 1\\' (I i d : ;,[C1'1 or~ J - \I [/,L TII 1I/,7.AlmS Thrc~ho)d Limit Valllc: I,Cc'lJ 1".:/, for ciich](\:"\'os (~'I",il:) = (1.1 /'I'n:. STEL 0.3 I'pm Sir.;ns alld Symptullls oi E>:po511re: 1. 1,('IIIe ()V(?lc>:pO!;lIrc: Conslricted j1upil:, blurred vision, frequent urination. ~;¡)i\'¡Hi()n, he;¡dache. mental confl1sirl1), abdominal cramrs, oi¡¡rrhea. Se\'\:"le oSymptlll11~: plI)IIIOl1ar:,' cdelr.a, c()n\'ulsionoS. 2. Chronic (I\lcrc>:pu~ure: 1~(11 e':p(!ctl'd fl(lm drllG prl'p(1:ë~li(1n ...'hen lIsed ?:' Hcd i cn 1 CUlld i t i IIIlS Gellc r a 1) y I,r,gr;¡\';¡tcd by E>:po"urc: Dich]o:'\'o~ is a cI1(llille~lc:'(1:e inhibitor tC¡¡rill[:, n(1\\~t:ò , Ò en t i; . òir(;'(\(;'d. Contraindicated ?re .s\l\.J~tances .such 2S morphine, aòren;:¡])ne or trônCj\dlizer. Chem:ical Listed as CartÏllo¡::en or l'otent:ial Carc.ino¡::ell: Nat:ional Tox:icoloGY Yes IX) possible I.A.R.C. Yes I ) Program No I I Honor,raphs No I>: J OSH1\ Permi~;.si hIe ACGIU Threshold Other E>:posure Exnosure Limit: L:imit Value: as Hbove Limit Used: Emergency and Atropine intravenously at 10 minute intervals in doses of 2-Ä m First A:id Procedures: or in conjunction ~ith 2-PAM chloride is antidotal. 1. lnhalat:ion: Remove person to tresh ai~. ResuscitBte and/or administer oxygen i1 s:-·mptorr.s appear. 2. Eyes: Flush e~es vi¡h plenty of vater. holding eyelids apart to ensu~e flushin~. 3. Skin: ~ash co~tamina¡e~ are~ vith plen¡v ot soap and ~ater. L.. Ingestion: I~e\'er b'ive anything by ~outh" to unconscious pe:.-son. Eave conscio:ls persons drink several ~lasses of ~at~r and induce vom:itin~. Seek medical attentJon. OSUA Yes r~o I ) 1>: I SECTION 6 - PITYSIChL BhZÞ~S Respiratory Protection (Specify Type): Use resDirator for Ventilation: ~an¿i€ Local i!ì ':entila:eè area E;.:haust: P::otective Gloves: !\(',¡ r·:?':t.:::"ed Other Protective Clothing or- Equipœent: 1;(',: ~:'2C'J: :'e: orf.anopr.osDhates Meehani eal (General) : Eye ?rotectio:1: ::; ~2se C'! fire. Special: Other: Sê:'=::'o Ç"~2SS~S £o~ l~~·~~le~ ~!~e. SECTION 7 - PEYSIChL Bf..ZlJ'illS Precat.;t:ions to be Taken Use pac¡:age ·..:itr.i;¡ a short time ai:ter opening. Do not S¡O in Ba.nàling ariå Storage: openeå pa:::b:~e. St0:'e above 32~: a~d less ¡nan ôOc: in è:-' ~lace inaccessible ~o children. Other Precautions: For emergency pla~ning are e~e~~t) ~e recommend reporting stor2~e (¿,BOO pC''Jn¿s 0: p:·oòuctL. Steps to be T;0~en in Case :;G~ii::: ;~a:a:'dot)2 co:::r(~ a~e:¡cy ·.·;¡e:: l'~! po\.::;cs c': Material is Released or Spilled: ¿i:::hlor~cs (~8 pou~¿s 0: product) ~s 2ccide~tly :- e 1,= 2. sed i r: : a : h 0:= ~ ;:1"" ~ :. S:1 ~ '2 ~ t (.; E "..: ~ ~- ~. :.: ~ :.." '= ë. rr.. l2::.). ~aste Dispos21 S~~e~ or ~'ac\~u~ s~i~l$ 2r~d ~la~e in cc~:ains: ~O~ ~i~ ~sa~. bt:~~ Methods: 5pil:~~e ~r unused :rE2:~d ~eEd ~B inchEs deep i~ the ~~o~~ ~~nciErin~ i: un2~ailable to ~a~~ ani~21s 0= ~o:·l. Co~:a:: ca~uf~:¡ure: £c= ¿is~cs tic~ 0~ 0t1¡-¿¿ ~ê.te:-ië.l. êild communi ~y :-ibht- to-.·..~Q·..· ~n ~~:C€SS cf ~OOO pounds cf (al i:h(\'J~h 0:'1.1 èi:hlc:.-\'os ",",~ . { ~ Kopertox¿N ltort DOdger QUICK II?~FlER Common "W (used on label U1d lieU Material Safet~ata Sheet Ma!" Ix> used ~o coml'ly with OSHA'e Huard Communication Standard, 2~FR 1910, 1200. Standard must be conaulted for specific r~uirementa. SECTION 1- Manufacturer's Name Fort Dodge Laboratories, Inc. Addrell8 Fort Dodge, Iowa 50501 Emer~ency Telep one No. 515-955-4600 Other Infonnetion N/A Calla Date Prepared May 29, 1986 P.O. Box 518 City, State, and ZIP Signature or Person Responøible ror Preparation (Optional) SECTION 2 - HAZARDOUS INGREDIENTSIlDENTITY Hazardous ComponenUs) (chemical & common namels)) OSHA ACGlH Other Exposu~ ~ CAS PEL TLV Limita loptionall NO. Not Not Copper Naphthenate (Active Ingredient) Known 500 ppm NfA 3~.5 Known Not Not Butyl Alcohol Known 100 ppm N/A o , 1<~g'tn NOt. Mineral Spir its Known 100 ppm nfA 62.3 'Known ( SECTION 3 - PHYSICAL & CHEMICAL CHARACTERISTICS Boiling Point 150- 204 °C· Specific Gravity IH,O= I) O. 86 Vapor Pressu~tmm HgI Not determined Vapor Density (Air .. 11 3.9. Reactivity in Water Not reactive with water Solubility ¡"Water negligible - Appearance Green liquid with petroleum and Odor solvent odor. Melting Point N/A SECTION 4 - FIRE & EXPLOSION DATA . Pertains to mineral solvent ortion. Flash C Method Flammable LimitB LEL Not UEl. Not Point F. C Used open cup in Air 'i by Volume Lower -' '.3 Upper . !1Pt"Pym1 np!1 nøt-~Tm; nød Auto-Ignition Temperature Not determined Extinguisher Media Foam, dry chemical, CO2, halon or water mist. Spedal Fire FIghting Procedures Do not use water hose directly on fire. Use self-contained breathing apparatus. Unusual Fire end Exploaion Haz.arda I . , Storage in hot area will develop pressure in container only. Use water as cooling media around fire. Î tSECTION 5- PHYSICAL HAZA_ (REACTIVITY DATA) 'f e Stability UnSlable 0 Conditions . St~ble K1 to Avoid None known Jncompatebì\ity 1M ateriala to A,'oidl Peroxides and stronq oxidizinq agents. Huardous Decomposition Producta Thermal decomposition releases carbon dioxide and monoxide Huardous May Occur 0 Conditioll$ Polymerization Will Not Occur C to Avoid None known SECTION 6 - HEALTH HAZARDS 1. Acute Inhalation of vapors could cause headache, anesthesia. nausea. Signs and Symptoms of Exposure Toxic if ingested. 2. Chronic U~known \ Liquid and vapor irritating to eyes. Inhalation of vapors could cause headache, nausea, anesthesia. Medical Conditions Generally Aggravated b)' Expoaure Possible irritation. to eyes. headache. nausea~ anpsthp~ia_ Chemical Listed as Carcinogen or Potential Carcinogen Emergency and First Aid Procedures f 1 h . h Eyes - us w1t water. no National Toxicology Yes 0 Program No ~ I.A.R,C. Yes 0 Monographs No IX OSHA Yes 0 No o¡¡ Skin - remove with liqht qrade fuel oil and then and water. Inhalation - fresh air. ROUTES OF ENTRY 2. Eyes Moderate - irritating with possible anestheia effect. Moderate - irritating 1. Inhalation Unknown ( 3. Skin High - toxic. Obtain medical help. Do not induce vomiting. SECTION 7 - SPECIAL PRECAUTIONS AND SPILL/LEAK PROCEDURES ~. Ingestion Precautions to be Taken in Handling aDd Storage Store in cool, dry place. Not for use on horses intended for food. Other Precautions Combustible mixture. Do not use near flames. sparks. or heaters. Keep out of reach of children. Avoid breathing vapors. Avoid contact with eyes. Steps to bt Taken in Case Materiali~Rele8sedorSpilled Absorb with filter aid or dry inert powder. Scrape up and deposit in suitable container. Ventilate area. No neutralizing chemicals. Wa~~ Diaposal Methode (Consult federal, .la~, and local ~gulations) Incinerate. Do not incinerate closed containers. SECTION 8 - SPECIAL PROTECTION INFORMATION/CONTROL MEASURES Respiratory Protection 'Specify ~. N/A With adequate ventilation - not required. Local Mechanical Special Exhaust Preferred IGenerall Acceptable N/A Eye recommended Protection Qoqqles or full Other Ventilation N/A Recommended neoprene Other Protective Clothing or Equipment Protective Gloves face shield. l Suitable coveralls to protect against skin contact. WorkIHygienic Practices None - follow label àirections. IMPORTANT . Do not leave any blank spaces. If required infonnation is unavailable, unknown, or does not apply, 80 indicate. CU-F1R Prinled by Labelmasler, Division 01 American Labelmark Company, Inc. Chicago, IL 60646·6719 1-8()().621-5806. (321) ~ .~ MATEH I AL. SAFETY DATA SHEET :M$OSI A030'" ~--- ,~___ ,\1..'-**********".-***""* SECTION 1 - IDENTIFI~N **************'*'*** IDENTITY: ALL-WEATHER PAINTSTIK - ALLC:OLÖRS MANUFACTURER EMERGENCY TELEPHONE NO. 312-826-1700 LA-CO INDUSTRIES, INC. INFORMATION TELEPHONE NO. 312-826-1700 250 N. WASHTENAW AVE. DATE PREPARED 09/27/89 CHiCAGO, IL, 60612 NFPA: 110 LABELING WHMIS(CANADA): NONE HMIS: 010 EPA HAZARDS: NONE BILL OF LADING: O.D.T. : U.P.S.: .._------~----_.- ---- * * * * * * * * * * * * * * * SECTION 2 - HAZARDOUS INGREDIENTS **************'* ----~_.- ------ -- SUPERFUND INGREDIENT C.A.S.# OSHA PEL ACGIH TLV RQ % NO INGREDIENTS CONSIDERED HAZARDOUS UNDER OSHA COMMUNICATION STANDARD 29CFR1910-1200 SARA TITLE III, SEC. 313 RED ONLY: CONTAINS AN INSOLUBLE BARIUM COMPOUND. PRODUCT CONTAINS 0.3% AS ELEMENTAL BARIUM. * THE ABOVE TOXIC CHEMICAL(S) ARE SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND OF 40 CFR 372. ******** SECTION 3 - PHYSICAL / ---~---- .--_.._-. BOILING POINT: N.A. VAPOR PRESSURE(mmHg): N.A. VAPOR DENSITY(AIR=!): N.A. SOLUBILITY IN WATER: INSOLUBLE APPEARANCE: SOLID MARKER ODOR: MILD ODOR -"-- *********** SECTION 4 - FIRE AND EXPLOSION HAZARD DATA ********** FLASH POINT (method used):APPROX.500 deg.F FLAMMABLE LIMITS - LEL:N.A.UELN.A EXTINGUISHING MEDIA: WATER, CARBON DIOXIDE, FOAM, DRY CHEMICAL. SPECIAL FIRE FIGHTING PROCEDURES: NONE UNUSUAL FIRE AND EXPLOSION HAZARDS: N.A. CHEMICAL CHAR}~.~'l'.ER I ~TJ.C_S...~ *_~_*_~~_*-__ SPECIFIC GRAVITY(H20=1): N.A. MELTING POINT: N.A. EVAP. RATE(butyl acetate=1): N.A. ****************** SECTION 5 - REACTIVITY DATA ****************** STABILITY: STABLE CONDITIONS TO AVOID:NONE INCOMPATABILITY (MATERIALS TO AVOID): OXIDIZERS HAZARDOUS DECOMPOSITION PRODUCTS: CARBON DIOXIDE IF BURNED HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: N.A. ***************** SECTION 6 - HEALTH HAZARD DATA **************** ROUTES OF ENTRY: INHALATION? NO SKIN? NO INGESTION? NO HEALTH HAZARDS: NONE CARCINOGENICITY: NTP? NO IARC? NO OSHA? NO SIGNS AND SYMPTOMS OF EXPOSURE: NONE MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE EMERGENCY AND FIRST AID PROCEDURES: USE GOOD INDUSTRIAL HYGIENE AND WASH HANDS AFTER USE. VVVVVVVVVV CONTINUED ON BACK PAGE VVVVVVVV\ .:L- '--------..- -----,-------, ,____...__._,u -----, --"------------------'-----:;A.---.----- ---=- ~ 'It 'It * 'It *.... SECTION - PRECAUTIONS FOR SAFE H{~ING AND US-È----*** * * 'It ,-- it RELEASË AND SPILL PROC-EDURES:S-WEEP--UP ANÖPLAC-E---iN CONTAINER----· "- WASTE DISPOSAL METHOD: DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. HANDLING AND STORAGE PRECAUTIONS: N.A. OTHER PRECAUTIONS: N.A. --~- ~--- *~**************** SECTION 8 - CONTROL MEASURES RESPIRATORY PROTECTION: NONE VENTILATION LOCAL EXHAUST: OK MECHANICAL(GENERAL) : NONE PROTECTIVE GLOVES: NONE EYE PROTECTION: OTHER PROTECTIVE EQUIPMENT: N.A. WORK/HYGIENIC PRACTICES: WASH AFTER USING. ***************** SPECIAL: OTHER: NONE N.A. N.A. N.A. = NOT APPLICABLE N.D. = NOT DETERMINE[ The information contained herein is based on data available to us and is ac- curate and reliable to the best of our knowledge and belief. However, LA-CO Industries, Inc./Markal Co. makes no representations as to its completeness or accuracy. Information is supplied upon condition that persons receiving such information will make their own determination as to its suitability for their purpose~ prio. to use. In íJ(} event. will LA-CO Industries, Inc./1'1arkaj Co. be responsible for damages of any nature whatsoever resulting from the use of or reliance upon the information corltained herein. NO REPRESENTATION OR WARRAN- TIES, EITHER EXPRESSED OR IMPLIED, OF ANY NATURE, INCLUDING MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARE MADE HEREIN WITH RESPECT TO THE INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. -------..---------,----- --- -.--- -.- ...- ---------..---------.----- MSDS# A030 PRODUCT: ALL-WEATHER PAINTSTIK - ALL COLORS ; I\, e e Ectrino!!' Insecticide Cattle Ear Tag .~ f. ~~FERMENTA,~ ~~ ANIMAL HEALTH Fermenta An'mal Health Company 7410 NW, Tittany SprIngs Parkway P,O, Box 901350 Kansas CIty, MO 64190-1350 Material Safety Data Sheet June 8, 1988 GENElW.. JNFœMATlŒ R:IJUNIÞ :nm:ITcrœ CATI1.E FÆ Tl!G Animal Insecticide 2 Moderately Hazardous 1 Slightly CarbJstible o Nooreactive Ratings based upon NI09i "Identificatioo Systen for Occupationally Hazardous Materia1s" (1974) 'IRANSPŒI'ATIŒ INFœMATIŒ: This product is regulated for transportation ¡:mposes as follows: Yes tb IATA (air) 1=1 I X I 00 ('Water) 1=1 I X I oor (land) 1=1 1 X I O:xltact the Transportatioo DepartIœnt at (816) 891-5566 for any addi tional infornation. I I:'ROa.cr IŒNITFICATIœ Manufac turer' s Na1œ FmŒNrA ANIMAL HEAL1H WlPANY Ccrnpany Tele~ (00) 422-0333 Ðœrgency MediCal (009) 585-4040 or (009) 275-4353 Produc t Name æmJNI' JÆOCITCIŒ CATn.E EAR TN; (56493-1) O1antrec (800) 424-9300 Synonyms Pydrin@, Fenvalerate; Synthetic Pyrethroid II HAZAROOUS llŒEDIENrS Material or Canponent CAS No. t Cyano(3-phenoxypheny 1 )rœthy 1-4- 51630-58-1 clùoro-alpha( 1-1œthy 1ethy 1 ) benzene- acetate (&trin) % 8.6 Hazard Iß ta PEL* = None (See Section V) Product contains polyvinyl thloride (I'VC) and trade secret plasticizer ingredients cOOJroIÙY used in polynEric food packaging articles. Fol:111l.Ùation of tags can refer to MSDS for prcxiuct ingredients non-insecticidal. t<11anical Abstract Service NLmber *09iA Permissible Exposure AH-MS-ll All mformatlon contained In ""' M.lefl.1 ~'ery Olla Sheet J' lumIS"6Ø ftee 0' chlrge InO I' Inltnaeø for your ev.lual.on In our opInion tne ,"torma',on IS. as of ttle date ot tt\4l.....'ellll $at~tV Dati Shef::t. 'ehabte. however. It'S your resPOnSlb,lIly to delermlne 1M 'U,IJib'''Iy ot the ''''O"".IIOn lor your use YOu ar. advlH'O nOt tOCOf"Islrue the Informallon IS JiÞS01ulefy comþlele Since Jiddl11()nallntormaltOn may De fM!'C"UI')' or deslraþle when panlcular. t!.cephonll or vaflaDle CondlltOn, or Circumstances e.lsl or because of aøøhcIþle la.sor government r!!QulallOnS Therefore. yOu Should use th,s ,,,.ormlllO" only IS a SUþo"m~llo other InlormlllOf' gllhered !)y you. .no you musl make lr\Øependenl tletermlnallOns of Ihe su'tablhly and comþleteness Of ,he Informatl()t\ r,om 111 sourus 10 aSSure Golh proper use at tne mllen,tdeSCffDe<" nereln end' rne ",,'y anCf hðallh of emplo~ Accordlno'Y. no gUI"nllte ..tpreneo or ,mplled " m,~ by Fermfnra Animal He"ln Comø.ny as 10 rf)e rnuU. to be OI)I,I.MQ based upOn your use Of the In'ounlhon. nor does F.rmentl An.mal Heallh Company assume any hablllty .tlSlng out of YØ\.lr use oflhe Informahon Printed in U,S,A, e e : ~ In:gecticlde O1tt1e Ear 'lag (56493-1) Page 2 of 5 ill PHYSICAL IY\TA Boiling Point, 7fIJ nm fig Not Available Helt~ Point &t Available Specific Gravi ty <"zÛ=1} Not Available Freezing Point Not Applicable Vapor Pressure Not Available Vapor Density (Air=l) Not Applicable Solubili ty in "z0' % by \II'. Not Applicãble Evaporation Rate (Butyl Acetate=l) Not Applicable % Volatiles by Vol. Not Applicable Appearance arxl ()jor YellOlrl Tag (10 gms.) Density at 20°C: Not Available ¡if Not Available IV FIRE AID EXPWSlœ IY\TA Œ.VELœ Ð1EHECf ACrIrn PlAN Flash Point (Test Method) Not Available Autoigni tioo Temperature Not Available Flannable Limi ts in Air, % by Vol. Not Available Lower Not Available Upper Not Available EXtinguishing Media Use dry chemical or carbon dioxide. Avoid action causing spread of IIBterial. Utilize vater under severe fire condi t ions if necessary. Special Fire Fighting Procedures Pressure demnd self-contained breathing app:uatus should be 'WOrn by fire fighters in Wildings or confiœd areas \</here Ð::IRJN!' INSOCTICIŒ CATI1E EAR TN; is stored. Unusual Fire and Explosion Hazard Treat as a polyvinyl chloride canpound. e e B::JlUN8 Insecticide Cattle PM Thg (56493-1) Page 3 of 5 V HEAL'IH HAZARD JNFœMATlrn The Ear Tag is a 10 gram PVC device ÌJ!VrEgnated wi th 8% by Yeight of the insecticide. It provides slow release (5-6 IJØlths) of the chanical. Health hazard is expected to be mininBl. 'IBE FUI.J1NJ}{; INRJttATI(fl IS IWÐ) (fl A \lA1m BASI!D UWID RRUAT1(fl a:MAIN.IJ{; lot BY WIœI' OF '1BE nm;ncnw. :IlŒWIFNI' /W 'IDE IÐM. sæm:IZATI(fl IS BASÐ> (fl'llJE 'JB1t«CAL a;JRIN!>. Heal th Hazard ~ta Oral I.D'j) rat: 1.2-2.0 ml/kg lÆrnBl Sèlsi tiza t 100 guinea pig: Prlrœry Skin Irrita Uoo rabbi t: (Draize) Demel ID::o rabbi t : negative (Technical) mild irritant Eye Irritatioo iabbit: rosive (Draize) no overt tOOd ty at 2, (0) rrglkg mild irri tant/not cor- Inhalation ~ rat (4 hr.): >7.17 rrg/L (ncminal) >0. 94 IIß/L (rœasured) Rootes of ~ Exposure possible via all belw-listed roote5¡ however, greatest occupational exposure hazards fron ear tags are through skin contact while hamling. Inhalation No adverse reactions 'Were noted in test aninals exposed to the aerosol. Skin Contact Laboratory test an:im31s exposed to a 10% liquid fornulation displayed a mild skin irritatiro. 9cin Absorption May be absorbed through the skin, wt not expected to be absorbed in toxic quantities. Eye Contact May cause mild transient irritation. Ingestion Ingestion of the insecticide device is lD11ikely because of its dirœnsions. Effects of OverE!XJX>SUre Transient skin rashes lasting fran 24--48 hours, burning of the skin around the eyes and nose and red- ness of the hands have bee1 reported in atq)loyees wi th and without tactile contact. Acute Overexposure Short-term studies iT! laboratory anillBls orally administered toxic doses of the chemjr;¡l h;:¡vl> produced the following symptOOl$: hypoactivity, folloved by loss of muscular coordination, drool- ing, hyposensi tivi ty, and tramrs and convulsions. Nerve danage resulting fran ingestion or skin exposure was witnessed in laboratory an:im31s receiving toxic doses. Acute overexposure symptcms fron the ear tag device have not been witnessed. O1ronic Overexposure (Wikely fran ear tag device) Hurœn data on long-term effects is not currently available. Long-term studies in laOOratory aru- rrals have produced evidence of adverse neurological effects. NJ indication of teratogenic. ruta- genic or internal reproductive effects were detected in chrcnic aninal studies. (Stuiies a:r.- ducted with technical chanical.) " "'.:' . e e IClRIN'» Iœecticide Oittle Ear Tag (5649>-1) Emergency and First Aid Procedures Page 4 of 5 SÐC tlmCAL ATŒNl'Im I1tØ1IA1JU Eyes: Flush eyes with plenty of \later hold~ eyelids apart to ensure flushing of the entire e¡e surface. Seek rœdical attentioo if irri tatioo persists /ll)re than 24 hours. Skin : \lipe off wi th vegetable oil. \lash cootaminated areas wi th plenty of soap arxt \later. Inhalation: (Hazard not expected fron insecticidal tag except in fires.) Reoove persoo fron cmtaminated area to fresh air. Resusci tate aOO/or administer oxygen as neces- sary. Seek medical attentioo inrœdiately. Ingestion: (Ingestioo of insecticidal tag in toxic quanti ty is urùike1y) NEVER give anything by !IOOth to an lD1COOScious person. Have cooscious person drink several glass- es of \later then irxluce voodting by tickling back. of throat with finger. Seek medical attention imœdiately. Notes to Physician Product cmtains a synthetic pyrethroid 1Jhich can result in nervous systen stinWation and eventual ¡malysis. VI REÞCITVITY Ot\TA Qnii tions Contriwting to Instabili ty Stable Incanpatibili ty Not Determined Hazardous D:!canposi tion Products lßier extraœ dec<Jn¡X)sition corditions, such as a najor fire, hydrogen cyanide and hydrogen clùoride, as 'Æil as other clùorinated or cyanide canpotD1ds, nay be formed. Condi tions Contributing to Hazardous Polymerization \lill not urrlergo further ¡x>lymerization. vn SPDL œ lEAK PRCUDJRES IEVELDP SPilL Pll1N Steps to be TaIœn if Material is Released or Spilled Avoid any contact. Keep people a\laY. \lear protective clothing and equipnent. Notify State and Feder- al agencies according to Spill Plan. \laste Disposal Method Manufacturing process only (not applicable to fomulated tag). Absorb rmterial ",i th clay, sarxl or other absorbent mterials. Contaminated mterials must be roved IJy an EPA and State approved trans- porter accanpanied by a rranifest. Contaminated naterials must be disposed of at an approved hazardous disposal area by an EPA and State approved rrethod. Containers must be cleaned by approved procedures and residue dis¡x>sed of in a penni t ted disposal area. 1 e e I , i ~ Imectlclde Cattle Far Tag (56493-1) Page 5 of 5 i i ¡ I I ¡ VIII llUJS1R1AL HYG:llNE aNlROL HFASœES Ve1tilation Requiraœnts No special ve1tilatioo requireœnt urxler nor:mù use. Specific Persooal Protective Equipœnt Respiratory Respiratioo protectioo is not required urxler nornal use. Eye [b not rub or tooch ~es 1Jhile harxll~ roolded tags. Gloves \Jear rubber gloves to minimize skin cootact. IX SPOCIAL PREX:AUI1rn5 mv:I1UHMAL UAZARŒ Toxic to fish. [b not apply directly to Vciter. LO not contaminate Vciter by disposal of waste (spent tags) . srœtŒ Nf) IJISlWJAL Store in a cool place in original container. LO not contaminate Vciter, food or feed by storage or dispo- sal. \Jaste (spent tags) resulting fran the use of this product nay be disposed of on site or at an ap- proved waste disposal facili ty. Dispose of ES11pty container in a sanitary landfill or by incineration, or, if allOlo'ed by State and local authori ties, by bunùng. If OOrned, stay out of srooke. } e e Ectrin'~ Insecticide 10 WDL -; i' ~~FERMENTA,~ ~~ ANIMAL HEALTH Ferments Animal Health Company 74 to NW Tilfany Spnngs Pa'kway POBox 901350 Kansas CIty, MO 64190-1350 Material Safety Data Sheet June 8, 1988 QHRAL :ooœMATlOO æIJUNIÞ :JNæITCIIE 10 \I[L Lives tock & Pool try Insecticide 2 t-kxierate Health Hazard 1 Slightly CanI:Alstible o Nonreactive 'I II Ratings œsed upon NIOSH "Identification System for Occu~tionally Hazardous Materials" (1974) TRANSKmATIOO 1NFœMATIOO: This product is regulated for transportation p.lIpOses as follows: Yes No IATA (air) ,=, I X I IMJ (water) '=1 I X I . oor (land) '=1 I X I Contact the Transportation ~partJœnt at (816) 891-5566 for arr¡ additional infomation. I PROIJJ:A IJEIlITFICATIœ Manufacturer's NaIre FrnMENI'A ANIMAL HEAL'IH <lliPANY Canpany Tele¡j1Ol1e (8ùJ) 422-0333 Ðnergency Medical (609) 585--4040 or (609) 275-4353 Produc t Name ~ nœ;rrCIIE 10 \IlL (56493-1t8) O1antrec (800) 424-9300 Synonyms Fenvalerate¡ Pydrin@, Synthetic pyrethroid family II HAZAROOUS llŒEDIENfS Ma terial or Componen t Cyano (3-phenoxypheny 1) methyl-4-clùoro-alpha- (l-ÐEthylethyl) benzeneacetate Solvent (contains TriJœthyl Benzene) ('AS No. t 5163{}-58-1 % 10.0 Hazard La ta PEL* = None (See Section V) 25551-1.3-7 'fLV = 25 ppn, 8 hr. 'NA**, AŒIH***, 1984-5 t01emical Abstract Service Number *OSHA Permissible ~sure Limi t *"Time 1Jeighted Average ***American Conference of Governmental Industrial Hygierùsts AH-MS-23 An '"'ormI1Ion Contllhed in tr\lS Mlterlal Safety CIII Sheet is fumlthed free ~ charge and IS InlenØed for YOU' eva1uattOh In our OO'"tOn the 1010""11100 IS. as of the date 0' the Mlte,.,1 Satety Cata Sheet reliable. nowever. it ~ your resoons1tuI,'y to C1etermlne the SI,Uf.tUhty of the ,ntorm.tlon tOt your use. You ar. 'dVfSed' nOt to con,true the fftlOImartOn as aDSOItJrely complele s'nce~ddtonalln'o"'n.IO" may De r)Ke$S.JIry or deSirable when panlcull'. ellcfPhonal 0' Vlrtablt Condlttons orCI'Cumstancfs ellls1 or becluse of aøøhClbte 11\fIrS Of ~mment rtogull"OnS. T".."lore. you ShOUld use thIS tntormaltan only IS' luþptem.,,1 to Olher 1"'ann.'lon g'lnered!)y you: Ind you must mi., lnøeøenøent delermlnallonS Of tne sUllablllty and compleleness Of the Infor"'-IIOI'I from aff$OUt'ces 10 ISlure bOrh proper use 0' rnemaletfal descobe<' nete/n,nd the' satety and heallh of employees Accordingly. no guarentH ell pressed Of Imphed I' made by F,rm.nll Anlmll Heallh ComÞany IS to ItIe '"ull,IO be oDlllned based upon your use 01 the In'ormallOn. no' ØQes Fermenta Animal .....lIh Comøeny assume any IIlblllty InSll''9 out; 01 You' use of 1M Informahon. Printed in U,S,A, ~ , ¡ I t I I I I ! e e æIRJN8 IRæITCIIE 10 n (5649)...48) ill PHYSICAL rmA / Melting Point Not Applicable Boiling Point, 700 nm Hg Not Applicable Sped fie Gravi ty ("20=1) @ 24°C, 0.991 Freezing Point Solidifies @ -4°C Vapor Pressure Not Available Vapor Densi ty (Air:1) Not Available Solubility in ",0, % by \It. ean be dilUted 100J: 1 wi thoot impairing em.ù.sion stabili ty Evaporation Rate (Butyl Acetate=l) Not Available % Volatiles by Vol. 78.5% v/v Appearance and Q:lor \/hi te emiLsi on wi th a slight aromatic odor IÆnsi ty at 20°C: 8.27 Ibs./gal. pi 6.8 - 7.1 IV FIRE AM) EXPlDSlæ OA.TA IEVELIJP Ð1ÐQN;Y ACITŒ PlAN Flash Point (Test Method) >97°C Tag Closed OJp Autoignition Tanperature Not Available Flannable Limi ts in Air, % by Vol. ÙJ\.'er Not Available Upper N Extinguishing Media Use wter spray, dry chanical, or carbon dioxide. Special Fire Fighting Procedures Use wter spray to keep fire-exposed containers cool. Pressure demnd self- paratus should be provided for fire fighters in I:cildings or confined areas vi \JDL is stored. Unusual Fire and Explosion Hazard None V HfAL'lli HAZARD INFORMATIæ Heal th Hazard rata Acute Otcù LD 1.2-2.0 mllkg (Rat) Primary Skin Irritation - Mildly Acute ramal I£50 >200J /I~;lkg (Rabbit) Prirmry Eye Irri tation -Mildly Acute Inhalation lC50 (4 hr., rat) >7.17 ~/L (noorinal) >0. 94 ~/L (measured) e æJRINID :nœ;rICIIE 10 \Ð.. (56493-48) e Page 3 of 5 Routes of Exposure Inhala t ioo Hayfever-like syrnpt(JTL$, \lheezing aM breath~ difficulties can result fron exposure. No adverse reactions 'Were noted in test anilÆÙS e>qx>sed to a 10 1JDL aerosol. i " i ~ Skin Contact Transient skin rashes lasting up to 24-48 hoors, OOming of the skin around the eyes am nose, ani redness of the hams have been reported in employees with or witlnlt tactile cootact. Laboratol.)' test aniIÆÙS exposed to the product displayed a mild skin irri tatioo. Skin Absorptioo Hay be absorbed through the skin, rot not expected to be absorbed in toxic quantities. Eye Contact Hay cause mild transient irri tation. Ingestion Ingestion of rrassive doses nay result in systEmic effects vhich include IlUScular fibrillation, diarrhea and convulsions leading to (mCLlysis. Effects of Overexposure Acute Overexposure Hay cause irritation of skin and eyes. Ingestioo of rrassive doses my result in systemic effects. Chronic Overexposure H\JTE11 data on long term effects is not currently available. Long term studies in laboratory aniJrals have produced evidence of adverse neurological effects. No iroication of -teratogenic, nutagenic or internal reproductive effects 'Were detected in chronic arùnal studies. (Studies coOOucted with technical chanical.) Emergency and First Aid Procedures Eyes: Flush eyes vi th large alTO\.U1ts of vater, holding lids apart to ensure flushing of the entire eye surface. Seek. rædical attention imœdiately. Skin: \.lipe off vi th vegetable oil. 1Jash vi th plenty of soap and vater. Raoove contaminated clothing and footwear. \.lash clothing before reuse and discard footw'ear wiùch cannot be decontaminated. Seek rædica.l attention if symptOOlS develop. Inhalation: Rarove person fran contaminated area to fresh air. Resusci tate and/or administer oXYga1 as necessary. Seek rœdical a ttent ion inmedia tely . 1nges tion: NEVER give anything by rrouth to an lU1consdous person. Have conscious patient drink several glasses of vater then induce vooú ting by having patient ticlùe back. of throat vi th finger. Keep airvay clear. Seek. rædical attention imnediately. Notes to Physician Product contains a synthetic pyrethroid \l!1Ích can result in nervous system stimulation and eventual paralysis. ". .,...~~.,. .:/ ·~·.~.:}~'.~~~.?t~ :.~~.~:.,~: -r>./:· ~~~;~¡;3~~'b~~ ~;~~t~:~14:~1~r~ii~~~: e - .' æ1JUNIÞ :r;tm;nCIIE 10 \IlL (5649:µ.ß) Page 4 of 5 ' VI REACrIVITi OOA CmU tions CootrilAlti~ to Instabili ty \bier nonml corditions, the naterial is stable. Incanpatibili ty Avoid alkaline substances such as soda ash anllye. Hazardous ~i tion Pro:\ucts lh:Jer extreœ decanposition conditions, such as a najor fire, hydrogen cyanide ard hydrogen clùoride, as 'Æll as other clùorinated or cyarùde canpcuxls, nay be formed. ConcH tions ContrilAlting to Hazardous Polynerizatioo Material is not known to poly¡œrize. VII SPIll. œ LEAK PRcx:m.RES IJMl.OP SPllL PLAN Steps to be Taken if Material is Released or Spilled Leaks should be stoppped. Spills should be cleaned up imœdiately. large spills should be contained and raroved by vaCU\.ll\ tr\lc:k.. $iraller spills nay be soaked up vi th absorbent naterials (rags, etc.), IJhich should be placed in approved containers, labeled, and stored in a safe place to aVcÙt proper disposal. This naterial is EXIRFJ1ELY 'IDXIC 'ID FISH. Keep out of sewers and vater vays. If entry occurs or is threatened, notify authorities. Persons performing this wrk. should wear adequate per- sonal protective equi(X!e1t and clotlùng. \laste Disposal Method Dispose in accordance vi th all Federal, State and local regulations regarding health and pollution. ~ quantities nay be disposed via a licensed chanica! VclSte hauler. VIII INIJJSIRIAL HYGIENE aMROL MFA5URES Ventilation Ra:¡uiraœnts Use adequate local exhaust ventilation. \lork. up-....inci in batch operations out of doors. Specific Personal Protective EquiµnerJt Respiratory Use a NIOSH/MSHA approved respirator following nanufacturer's recOOlÆ!l:1dations. Eye Face shields or chanica! goggles should be wm. Gloves Rubber gloves should be VJOm. Other Clothing and Equipænt Standard wrk. clothing. Standard wrk shoes. \lash contaminated clotlùng wi th sœ.p and vater and dry before reuse. Advise the latmdry of the rraterial contaminating the clothing. e e ~ n&crICIIE 10 \IlL (~9}J.ß) Page 5 of 5 IX SPOCIAL PRæAIJI1<JJS 1NJJKN1IMAL ßAZIIR) This product is higtùy toxic to fish. [)) not apply directly to \.later. [)) not contaminate \.later by clean- ing of equipœnt or disposal of wastes. Apply this product orùy as specified on this label. SImIŒ fW msmw. D:> not contaminate 'Water, food or feed by storage or disposal. Store in a secure area above 32°F. D:> not reuse container. Triple rinse, then plD1cture am dispose of container in a sanitary landfill, or by in- cineration, or, if allO'Æd by State and local authori ties, by burning. If burned, stay out of srooke. Wastes resulting fran the use of this product nay be disposed of on site or at an approved waste disposal facility. ¡, ., .~ e e -, , Issue Date 8/21/87 Supersedes TCfŽl784 Page 1 õf~'5'"- -- -'- AATERIAl SAf£rt OI\TA SH(£T SfcnON I. IOFJITIFICATION OF PRODUCT -------------.--.---.--- -. ._._-~_.._--- rRODUCT¡¡RÞD~ N~~ZS: u~ 1 f\;;\'¡ E:,¡¡~ 1 s: i f¡ ab '1 ç L ~ qi.tÍ d {De 1 - To;:ò>/Cc.-N.2 '/~ ¡Berea tof.} ßASE EPA REG. NO.: 59-128 (Del- T\.;i(~1. 59-113 (Co-1~a~ì REGISTRANT: Coopers Anima1 Hea1L~ Inc. 2000 South 11th Street Kansas City; Kansas 66103-1438 ~:~ERGENCY 7Et.EPHOr1E: MO:'ld¿y thnt F íi d.;.)' "7 ::,0 -l.m. to 5:00 ? .m. carl {9131 321_ ~107D 01' 1·-80G-6~8··C126 {La K¿11SaSJ 01- 1--300-255- 4456 (O~tside Kansas). r~~GftCD 1 c~rrs ~ D·¡ ()".x:.;' t.h·I or [2:. 3-µ·... di 0.(;:: r~-:;d! ~i1 ~ 01 :;» 1'1'('< ,,¡,"I r·r;r! .¡ ti',' en" t",) -,j . ¡,~...;~...... k~ .............. I. , ..... 10"..0- $-1: i s {O.û--ó¡ethy1 20_i\O~ 79_60'l', lUQ.O~ 0[1(> qu.2.~t (;o;~t.~i~t:; 0_54 pGu;:(t<; of lJeln",v"'~ '*?J;gi s t:.;: !.<?;'~ tr.:.(b:ì'-l rk ilS~\:i ":'j' ~!IJ~~·Y;~ Cht.;.,,:~ ~ Loll Còmµiln)'- SHIPPING ~~ .~_t~~:~?, O[~..-~;-_!?~· ,~~~f t;.]$f:./....tf;~;(!:~':, :)1" ~¡·<:'-"d' p~;::::11,:,":t:;. O/T AS:-·, ~LÜ_L. itðn 1U2130 Sub 2. f. L !:~~1:,~~~:n(!:-~~:; ("),:t~q~.;_trf~.: G~.a ~:.IX1ttftE .-----..-..--- -~-'---'. - -. ....---. ." -: r(;R.Efj ~ ENT : n~l--~:.~¥ (JiG~a~~~~0~) T~(h;lic21 ~':)ï.( '~'u~ . " ~ T' I. !.' ~~ . ~ I E;~ T : Mi ~(ed ~_,rc·D.~ t 1 c 11.y !,1r(;c>; {';-"G~¡:" ~ - ~---...\ ... "'T~:~~~ ~f(_ PR(1DUC.l PitY5IC.?,L OAT.!. ---- G0@@œ ~1J®O~ffi Pf,:~,:,'dHY r~[::;CR1PTroN : Clear. ¿f,-,b0r «(lì,),;;;0., frec ne"''''g 1i~:.dd with è. foul pu tri. d odor- SOUJBILlTY H! WATER: Emulsifies in water. SPECIFIC ~RAVITY (H20 '" 1): 0.986 @ 25"C ------ -- --- ---- -- ------ . -'-- Post·1t- brè!'1o fa~ !r2nSm~é:! m~mJ 7671 r; ct ~"'9t;S» r- ~~_~ ..J;; To Lf< w ,.: ¡() r1 i\ L From .c '·/:--~ .ð . - d Co. I ~~.~~) I-~tt-~t-ø/\ _ Co. / ~ Oøpt. ~ I}\ ,I Phone I/~ -- J<C-L_.c~i'-<.!-kL 113- '3d. 1- )&';,1) Fax;;""", ~.,' .' ~II ~~~- "/' " . ~ - '_~~_?S -r , J :;. - 5"''-, '> - tJJ"tp<¡ ,~ RA2660 - De1-Tox/Co-·NavfBêccotox ? '.. e e Issue Date 8/61/87 Supersedes Ii /21784- Page 2 of---5- --- -------"- FIRE ANt) EXPLOSION DATA S£CHOH IV * FlAMMABILITY (Flashpoint): 105°F minimum (Tee) EXTINGUISHING MEC~A: Carbon di,ydde. d,y che¡T;lca1 fO.iín. \.[,:.te:-- SP¡·3.y (fc;lj) m.l,)' be used to tool CO:ìt2. i ner$ - ~. w·:JL.er stredm may $pr~ùd f1 arr-r€:S or calise f.j21ln1 no) of t,ot r;¡,3teri at. SPECIAL FrREFlGHTING PROCEDURES: He,:sr fú ì 1 protec t i "Ie c1 oth 1 (\9 bre;;th'iog ¡jppar-dtus. Water r..ay e>.x:posed cC'iltainer-s ,::001 IInti1 breathing vapor of fumes. dnd self contained be u~ed to keep fire fi re is ouL rlVol d UNUSUAL FIRE AND EXPLOSIVE HA2AgDS: 1\,l-ti;i.v 1~ highly taxi.;:.. Drulii rupture flí'IY ~pre¿¡d m.;tE:r1 a 1. RUí1<)ff to wJ.te:Ï\';,:ìYs wi 11 ,.:re2.te t::.x.ic h.~ZèJ'ds, N(¡Ufial1~~:¡ol'Ît1es and ;~¿ép people and 1 'f ·~··~;:·s t~~~~~_ ú'¡:t(1:i.: Do ~\)t :¡;) ~ ù;' .; ~~:)"[~ wi th 5 trong C,Çi((;:¡¡its lfke 1fquid .::h10f1nê û( corn::entrï1to?d O:-\jgt:l~£ PreSS-Hrt: ~2..Y :¿0v.?-.lt"fJ· in (lû~~~.j ,:cntain~',['~~ .; ø. i.,'.Y(;C;;c:-:àted. \-Iater !7\d.j"" (::iilS~: spatt2r-in:] or fû~t111~~-:.., hot material. S.'ECTtof{ V, Hf:M. TIt HAZARD ·Of.1 A ---_._~--.----------._---------- .--.------ -- T1-~:~.tSHO~_D ~.,rMTT ~....~~~t:; F,)r ,~~.fi..;-·~~nt. th(~sht)1d l~;;¡:it \;·¡~lu~:. of \-.::c'ioj;$ ingi~e- (!.i;;_n;:~·Þ (L:;r\?t r.o 2"3 CF~ p¿¡..t 19iO ~';ut¡p,::rt: Z :tToxic and Hazardou£ Sub~tances.M t i l EC rs 01 . ..-,,-. - .,......... '-'. ..~,... -: c :'" _.:...~ ,~, ~ _ , ;"'!.~ ....~! .~ 0:; '~:/~:-;ptOi;'~'2~ : ;-~c 1 IJdt: 1 G ';; ~.; () f dpp~ t i tf: 10 t12:U S:~?! . v (j¡;; ! t.. i;)g J abdoDI1 n"-~ 1 C f ..::1;1pS ) d f ;~ f i' h~.::: . e ':Less i ve ::.:;tJe.~t:ng. çco~tr~ctiQj"1 ..l~: ;J~~4 is. b1ur-reJ \"i<;1Qns» 9idf~~f?j:-S~. 2nd re~t1é~~:ft~~~~.. Ca11 a physic'ian L-:~¡h~d~¿.t~~ly ~n a.l1 ':.:as,C$ or :~:":'~µ!;:t,.4~f;d pUls(.)ntng. EMERGENCY fiRST A f.D PROCf::OUR E S : f;"O;f~vt tceJtnH:.:.{~t (\/le¡·e ph,y~:;·ici':'(~/·/'2t:..~·r';n.;lr1,~:1 is not <"iv.,,'\1';ìb1fO>) ·,.¡iU¡ 1~~Lt.¡vî:1f 12I'9è dOSGS of atrcplue is f>:,:c:Jín;ìie¡h1(:J. The. t.reè tmefìt IndY be îe~e¿ ted in 1/2 hOt!f. [;<:pOSü¡-~ s},'Juld h,,-' ter1TIi;-¡::tèd .;s rapidly as possZbìe by n:JIì')ÿ,d of vid.ïæ to an lincontamin~ted area. fE:¡:ioval Qf cont.s,m:na.tE:d c1üth1!ìg dod thorough c1eans1ng of the sUr. H1i:h SO.1p ¿~l.d p1enty' of water. cc;-~ RA2660 - Oel-Tox/Co-Nav{Berc.otGx [pooœ ~~~~&Jlb , .. e '. ~ SW.I\LLOi-lEO: IF ON SKI!'!: I fIN EYE S : rro- 1.;* I NH.t\L£D : NSTE TO PHYSICIA~: e Issue Date 8/21/87 Supersedes TI!2T78¡r Page _~_ of-~__ 5 _ c-an a physl(i..1n!vet¿.:cinari¿r'i O¡- PoiSQn Contro1 c.~:nt€r Ü¡-~'11er,L~teì'y. DO nOT INDIJCE VD;';IrlNG. U¡¡11?5$ under' i:i,~djc¿:' super-vIsion. VomiUng may C;':tlSE- a:;,p1¡-~1tiQCl pneumonia. i-!~._Sh 1ri1medï.~telj wj~h pl~f~tJ' of $r)::P .3d "'èt~'f'_ !;:1r.H::di.:.te~'y flush 2ye..S wlth p1enty of water. medical ~ttenticn if irritJtion persists. Get Remove victim to f:~esh ð1r~ A~µ1y respiratiún if indicated. Th i:.< P[ÎJG:.~c:t con t ,;~ i n ~ .? r: (:¡('g,~ no;;h :..~<~ phò t ~ t1~!,d p~~. ro 1 t--:tur: .. "1' ..Tnl"\t'T~I¡: r'" ····,·T{no...·· f- h ij ì r;;t 1! -3.ces. [",.I\,',,!" - 'k ,,) ,,1;_, d I h __ 0r t e orgal1o- phûspha te i ngl'edient. S£CTION 'If. RfACfIVITY DATA STABILITY: Stable. HAZARDOUS PaL YMER rzr-.T rON~ INCOMPA1Aß1LI n (:.~~ t ~rl1"11 s -'-. ; . ~ ': . .' : ~.\ , '"' HAlAROOU5 [;ECO~lP"DS iT7 ~0NTJ!.TIGrJS TO t:",VOIU: -, Will not Arror ",.._ '..\...I! .. .j i "j (:¡~. ~7~,1 t t~ :'~1 ~~.1 .; 'r:' i i .~ ~~:/d!" (~ 1 ~{7:. ~~. 0~:.1 ï¡:~ ÿ ~ .-~ ;:. í jJP~ ~);~.-~rj¿'.nt::: lik~ liq\)id c,l·tlç·('in~. ·:~}:·~Cf~f!':"r·dteÇ; {j~.('jg~~n. sodiuEi ¡:)r calc1~1~~~ h.YrH1(:~1or-Ite ","i11 react with the product. . C,3. f;·<;;; ~(;r;.()~1( i ('¡t, ¡ () ':( 1: dt':"_; (\ f (;~::,:_;,,;: l-~O°C) ¡:).'\,y r¡O- ph·.~·s ~}hoc ~)d it h i una t~: ,2 ..p..... '}~JQsphoroditt1ion~te)~ fiittog;'_n,;uìfuî o:dcte'>, '-~ 1 ~'jI ~ _. ":... f.~f;·.;:; ;~:.; !.-. ,; t~) r:" (\.:; (: ¡-~':;:~-..)~.'~ ;:, .~ ":: :-. fi¡.,i!:-e 0 ~ n·" d i ~~th j 1 h y~.1r·(; -jf-;¡ ti i Ú ;:~2 n t~ t h '~ d 1 S ,- (0 )0 0 ~J. ~ ~-: ~.'. ~l.)' 1 c2.rb~n dioxide) tJx~c ·'¡3.~Qr:; 2nd ~00~e.. ~lev~t:crj t~mp~ratur·e~_ SECTION VI [_ SPILLS fiNO lEAKS ~--'- ----~--_. ----- -----.----- STEPS TO BE TAKEN IN CASE MATERiAL IS P£LEASED OR SPILLc:.û; ~ie.¿tr" (¡ean protec-ti1¡e c.:l(ti~~1nSI tt?spirò.tor-.. rubber g1ðYE:S and gOggtê<;. Recove,- freE: llquid by .addio~l ;;.bsorbent (clay, earth. s~nd. $~wdu$t. ven¡,1c.ulite, fìo.:)r' -3.bsor·bent. rags. kitty litter. etc.) to the <;µi11 area. S·,.¡eep and 5hove1111to a metal co!:~ L:¡lner. A'y-oid prolùng~ or ¡'E-peated' 'Yf-eathinl] of vapor. Avoid -:ontact hith skin or c1,.tÞing. Ä',{oid contaLt with eyes. !.-,..,\ rw(ó)@~ @æ~@U~£[b \ RA2660 - Oel-Tox/Co-Nav/BercotoX '4 e e [ssue Date 8/21/87 Super:;edes T17lï7M- Page _~_ 0¡--5- DECONT A!~l Nl\-; rON: TJ.,] :-"ot .::~~ÜI,-i Ç;(-~:,C't.:ct to t-'f~(.ei O~\c;-i ~e!;,:?r, dr.~;jn or 'N.;iter(~OlJr~fé':?. ~.dv ï '~,e ;!,UUlorÎ ties if prcdtjct has ente~~d 01-- mðy E!1t~er s~w~r'S, ~r~te;~Catìr5~S Of exten$ive l¿¡nd arC4$. F{;~lo\..,"i;-!g clean LIp of ~pil1~ \..{úsh ~-·¡lh del~-~r"'IJèi-¡t .;.nd wa~2'(' $()lution~k ? ;uitable container for disposal. (o;¡tarn; nat.ed Jt'ea C~o11¡.:~ct IrlJ.~.p:r· in PROOUCT DISPOSAL: ? r00l!C t 1 S .3(:tJ ~~ é"l '.f t-i\l Z-t:i ¡' \!\)U~; .. ri'npt0p~~I~ d i spos a 1 (' f t:.Xê~·)S pi2St.1C.i:J>:-, ,>pr;!.; mïxt1.ln;:. QC r10sate is ,~ v1ü1ótion of F~~d~ral la.w~ If t.hese ',-(ctste:, cannot be rj';spOS¿(i of by use ¿¡(.cörd~n9 to 12t'1.c;1 in$tructi('"~. c(,ntact j'¡)U~- StJt.~ P\:~:;tî(ide Of' tnv1cúnnietltal Contc-'ol ;~':::;h=Y t G [" :.h~ H':L~ 3. r d (H": S ~!¿¡ ~ t e rf'p t"t.:S,':~J~ tat: ve ë1t thQ f1,~,òj,·ec;t. [J',t. RE-giona1 Offi(\? fli( G!jîi~i1nc.:-.. CONTATNER D1S?OSAi_: ~~~tp'r_ ~·-j()5·r:' (cr E;,,:¡u~\'21.ef'!t): l1!~~,('. off~_(' f(;~" féc.Yc1-in;j (;["' ;-~(t~JHdftflH"4fng ()f' µunct~)re .:tn,j d{'5pü:;.~ of 1ft ::!. s~';r¡It¡;;·:;, 1~ndf1 ~ t 0(- h.y ':ith¡~:r' pr·f.l<::-::d:J(e~· dppr·üv~d State dnd local authorities. , , SECTION HE. ~;p£(,iAL PROïECTION H.rORt-\ATlON ..--_._~--~ -.---.---- - -'- ...--------.. .-. .-.-- -'-- RESPIRATORY PROr[CnON {Sp2.<:i fy : 1:"*' ~,.. '.¡ V'--;' - , - j,-: - -' .,! ; . ; '- .,. . . - ~ '-. '--.,!": 1 f (:1)(;~. ,'.: i ~!~'.:~': h ""-.;~ -< t· ~-: ~~ ,- 'I ','; ,~... -." "J .::;Jp;~ {'2 t u·~ ;)¡} ~";I' ,_ ~,~~.: {' e d ~ ~"t--..=t ~.~' i. pc- ~f U tr.. t (; ';.rr"f~:/ r1 i :;t. 01- 'i r) f\(,j/:", ît; 11'ke~y t'.J be E:ncounti2c~:~~ "fÍ'2èf ~ re';p1r~tOf' iippro¥t:o !,':.1' ~-~~..:;.. D£:p.~;~tr¡!en;~. \..if r~.gi·~t..1l1turt."1I U",S. :':J;""' e,;~! ~.; ¡A¡ ;:-~~.~: ........ N I (1 :~~;.{ /~~~~;"L~ ~ Ef"; 9 f u c.. ~ ( ~ ;1 g .:"j r· '~"~~íf~ i [i ~ s: .: ~". t ~ '\i f': (·.·~·:n t r (i 1 '~) S !;I)U 1·": ~".ç. i ~ì!p 1 ~rn¿·(t té:j to ,,'-j>J(C E<;~'¡;';u;·('. F,r f):>.lk11 u;~~',-:f prodli(.t òs. ·.~~s,~~·-iG;~,~j ~'''J' -i~:.¡)~:·1 {j~:,.·~;...t~(¡r~=;1r ¡'t;·:·P'~~'lt;'.(d)" equií~i;h;r¡t is not specified. VEi' , U~f eX~¡2us: ~o ca~~ur\~ fV:~2S 2f\d Y2PQrS~ PRUTEí:T!Vf CL QT~-~ T J?:~ = . ,: ,~~ r- ..: 1 ¡;:"~1:' i=; .'-·c; tt~;: t i \;'\:' (.1 ;)..~ h i'r~ i; ~ r ~,:~ ¡)) ¡- I:: tor ~ 9 1 ~:- lJ' ~.~ ~ ç ! ~ .:~ ç;,j q g 1 (: ~~ 'rJ h c.~: l (1 i~;! n i r~ 9 ü P ': µ 1 ~ 1 So ú r· d 1 ¡" i-= ( :: 1.y 'ri 1" ;:, L 1 (J !.:~ '2 q li ~'-1 t .; l i t~ ~ G f t h (: P r- ¡"jJ \J c t .. .. ut, b :,:r- ',;'::; d: \ f\ 9 ~_YE PROTECTiON: ~fe2!.r ;.r',h¿'·~·~·d(d~ g<]{;gi¿.~~ '-;i~·(~.',...f" plz..:..t.~i2 f-:~.·~e shie1d f,'r whei1 eYt' contact ma.y be ex per..:. tf:'d . *Thl? p('oduct i:; tûx1 c to fish.. ¥i-¡ ¡ ê1 i f e i.1i1d hi nl.$. ~p out of any bödy ùf water.. Do not C<Jotat.riñ.:::te .,Qter by cleaning of equipfl1€'nt Or' by dispo$a1 of wdStes. 00 not apply "F:tler.:~ nmüff -is lii:.ely to oéC!Jr. RA2660 - Oet-Tox/Co-Nav/Bercotox LV@@m ~Q®O~&[6 " "II - ~ e . Issue Date 8/21/87 -- Supersedes TI7217M Page ~_n_ of _~-= SECT ION CC Sí'CLr:'L FREU\UT f(:¡;S OR CTHC' co~orrs - ------ PRECAUTIONS TO 6£ TAKf~: IN HANDLING AND STOR1NG: Kf:~:2 ri c<;r; t 31 ¡;er c 1 ~)~.2Ú , (,.n~·;. ilel!: i {~ USe... Do flÇ,:.; L: ~.) €' Ú .. store nea~ heatj oppp fl~.fî¡.~ O( ·~tr-G!ì'~ oxidant~. OTHER p~rC~UTrONS: Oc, r~at ~Jet CH1 st:in 0r ·:18th1:!:j., 00 not Or spray mist. Avoid contact ~ith c~sp i (·.ltor- ù(' gog9 I f~<; if nec€s sU-.)'_ Dreèth V2.PQ('s PYf:-''>. U::>e ;I: ,. * * .. .... * .... NQT! Cf.: The ÍnfOfíTi2tiol1 hêr~in i: 9~'lt:n in gçü.J faILr1 h~t i:~ futnisheJ1 ~~it.hDt!,t ;,,:arrJ(1t.t (It gLiJ.rantê.è Of any kind. U.1t:i1ir.y!s ;:.:x:pr-e:;:-;1j disc1d~med (.:)!, 3ny 1055 Of' injury 2rí::ing out of ~J¡<' IJSê (.f U;is inform¿tion 01' the use of any m3teria1~ d2sign~ted_ ~@@œ @ffi~®~~[@~, , & RA2660 - Oel-Tox:/Co-Nav/8enotm.