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Home My WebLink AboutMITIGATION (4) APPENDIX A B.C. CHEMICAL'S PRODUCT LIST ject No. A45-01.01 emcon Associates e .C:~~~~I~~A:30' · PO 00<...,_OA93302 . _(B051832-'380 Dear Customer: BC Chemicals is a full line chemical distributor, we also offer a complete line of blended products, (degreasers, mud detergent, etc.). BC Chemicals operates 24 hours a day 7 days a week to fulfill your chemical needs. Should you be unable to find the particular product within these product listings, please contact your sales representative or our office. BC Chemicals has the sources available to obtain whatever product you may require. Richard J. President e e TABLE OF CONTENTS Page Number ACIDS ................................................ 1 ALCOHOLS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 ALKALlI . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 AMINES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 CHLORINATED SOlVENTS.............................. 2 CLEANERS & DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . 11 . 17 DRILLING FLUIDS MATERIALS ........................ 8. 9 ESTERS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 FORMULATED PRODUCTS. . . . . . . . . . . . . . . . . . . . . . . . . 18 . 31 GLYCOLS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2. 3 INORGANIC & ORGANIC CHEMICALS. . . . . . . . . . . . . . . . . . 4 . 7 KETONES. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 ORGANIC ACIDS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 PHOSPHATES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 This product list supersedes any previous product list. i \ - ' e ORGANIC ACIDS Acetic Acid GlaciaJ 480 Ib drum Acetic Acid 80% 477 Ib drum Benzoic Acid 50 Ib sack Boric Acid 1 00 Ib sack Chromic Acid 1 00 Ib drum Citric Acid 1 00 Ib sack Formic Acid 515 Ib drum Oxalic Acid 50 Ib sack Sulfamic Acid 50 Ib sack ACIDS Muriatic Acid (HCL) 535 Ib drum 1 40 Ib carboy Nitric Acid 600 Ib drum 90 Ib carboy Phosphoric Acid 220 Ib drum Sulfuric Acid 750 Ib drum 200 Ib carboy PHOSPHATES Diammonium Phosphate 1 00 Ib sack Disodium Phosphate 1 00 Ib sack Page 1 e PHOSPHATES (con't) Soda Phos 50 Ib sack Sodium Hexametaphosphate Granular 50 Ib sack 100 Ib sack Sodium Hexametaphosphate Plate 50 Ib sack 100 Ib sack Sodium Tripoiyphosphate 1 00 Ib sack T etrapotassium Phosphate 100 Ib sack T etrasodium Pyrophosphate 1 00 Ib sack Trisodiumphosphate 1 00 Ib sack Monosodiumphosphate 100 Ib sack ALKALI Caustic Potash Aake 1 00 Ib drum Caustic Potash Uquid 50% 680 Ib drum Caustic Soda Bead 50 Ib sack Caustic Soda Flake 50 Ib sack Caustic Soda Uquid 25% (bulk) 600 Ib drum Caustic Soda Uquid 50% (bulk) 707 Ib drum Soda Ash 50 Ib sack 1 00 Ib sack Sodium Bicarbonate 50 Ib sack 1 00 Ib sack e AMINES Diethanolamine 99% 480 Ib drum Diethylene Triamine 440 Ib drum Diisopropanolamine 450 Ib drum Ethylene Diamine 4781b drum Isopropanolamine PRG 450 Ib drum Mixed Isopropanolamine 450 Ib drum Monoethanolamine 460 Ib drum Monoispropanolamine 440 Ib drum Morpholine 460 Ib drum Triethanolamine 85% 510 Ib drum CHLORINATED SOLVENTS Aerothene IT 54 gal drum Aerothene MM 600 Ib drum Chlorothene NU and VG 592 Ib drum Dowclene EC 54 gal drum Ethylene Dichloride 565 Ib drum Methylene Chloride 600 Ib drum Orthodichlorobenzene 600 Ib drum Perchloroethylene, Ind. 700 Ib drum Page 2 e CHLORINATED SOLVENTS (con't) 1, 1, 1 Trichloroethane 592 Ib drum Trichloroethylene 600 Ib drum ESTERS Amyl Acetate. Primary 400 Ib drum Butyl Acetate, Normal 400 Ib drum Dalpad A 505 Ib drum EE-Acetate 440 Ib drum Ethyl Acetate 85-88% 400 Ib drum Ethyl Acetate 99% 409 Ib drum Isobutyl Acetate 400 Ib drum Isopropyl Acetate 390 Ib drum N. Propyl Acetate 400 Ib drum Butyl "Cellosolve" Acetate 422 Ib drum "Carbitol" Acetate 463 Ib drum Butyl "Carbitol" Acetate 450 Ib drum GLYCOLS Diethylene Glycol 520 Ib drum Dipropylene Glycol 470 Ib drum Ethylene Glycol 515 Ib drum e Gl VCOlS Hexylene Glycol 424 Ib drum Propylene Glycol, Ind. 480 Ib drum Propylene Glycol, USP 480 Ib drum Triethylene Glycol 520 Ib drum Tripropylene Glycol 470 Ib drum KETONES Acetone 358 Ib drum Cyclohexanone 432 Ib drum Dlacetone Alcohol 430 Ib drum Dllsobutyl Ketone 370 Ib drum Dimethyl Formamide 410 Ib drum 1 ,4 Dioxane 473 Ib drum Ethyl Amyl Ketone 374 Ib drum Isophorone 425 Ib drum Methyl Ethyl Ketone 366 Ib drum Methyl Isobutyl Ketone 365 Ib drum 2 ·Nitropropane 455 Ib drum Pentoxone 410 Ib drum T etrahydroturan 400 Ib drum Page 3 e ALCOHOLS Amyl Alcohol, Primary 370 Ib drum Butanol, Normal 370 Ib drum Butanol, Secondary 369 Ib drum Isobutanol 370 Ib drum Isopropanol, Anhydrous 55 gat drum Methanol 55 gat drum Methyl Isobutyl Carbinol 371 Ib drum Methyl Amyl Alcohol 371 Ib drum Propanol, Normal 370 Ib drum e INORGANIC AND ORGANIC CHEMICALS Acintol FA-2 420 Ib drum Aluminum Sulfate 1 00 Ib sack Ammonia Anhydrous 1 50 Ib cylinder Ammonia Bicarbonate 300 Ib drum Ammonium Alum 1 00 Ib sack Ammonium Biflouride 50 Ib sack Ammonium Chloride 50 Ib sack Ammonium Hydroxide 350 Ib drum Ammonium Nitrate 80 Ib sack Ammonium Sulfate 1 00 Ib sack Asbestos 50 Ib sack Barium Sulfate 1 00 Ib sack Bentonite 100 Ib sack Borax 1 00 Ib sack Butyl Oxitol 415 Ib drum Calcium Carbonate 50 Ib sack Calcium Chloride 80 Ib sack Calcium Chloride Water Bulk Page 4 e Calcium Chloride Powder 1 00 Ib sack Calcium Hypochlorite Granular 1 00 Ib drum Calcium Hypochlorite Tabs 1 00 Ib drum Carbon 50 Ib sack Chain Oil 55 gal drum Chlorine 1 50 Ib cylinder 1 ton Cobalt Sulfate 1 00 Ib sack Copper Sulfate 80 Ib sack Cyclohexylamine '75 Ib drum Deriphat 90 Ib drum Diatomaceous Earth Hyflo Super Cel Bulk 50 Ib sack Standard Super Cel 50 Ib sack Celite 535 50 Ib sack Celite 545 50 Ib sack Fiber Cel 50 Ib sack Dioctylphalate (Depone) 436 Ib drum Dowfax 2·A·1 530 Ib drum Dowicide G 11 O. 1 2 Ib sack e e INORGANIC AND ORGANIC CHEMICALS (con't.) Epsom Salt 1 00 Ib sack Ethyl Mercaptan 5 gal pail Ferric Chloride Bulk Ferrous Sulfate 50 Ib sack Formaldehyde Bulk Gluteraldehyde 50% 500 Ib drum Glycerine 96% 570 Ib drum Glycerine U.S.P. 570 Ib drum Gypsum 1 00 Ib sack Hampene 1 00 58 Ib drum H. T. H. Granular 1 00 Ib drum H.T.H. Tabs 1 00 Ib drum Hydrazene 250 Ib drum 450 Ib drum Hydrogen Peroxide 35% 275 Ib drum 500 Ib drum Kerosene 55 gal drum LAS - 99 (Cal Soft) 480 Ib drum Ume Hydrated 50 Ib sack Ume Quick (Calcium Oxide) 60 Ib sack Methyl Formate 440 Ib drum Metso 20 Sodium Metasilicate 1 00 Ib sack Mineral Oil 55 gal drum Morpholene 460 Ib drum Muriatic Acid Inhibitor Rodine 213 1 gal 5 gal Nickel Brightener 5 gal Nickel Chloride 50 Ib sack 100 Ib sack Nickel Sulfate 100lb Ninol - 1 285 400 Ib drum NTA· NA3 50 Ib sack Orzan 50 Ib sack Pine Oil 55 gal drum Potassium Carbonate 1 00 Ib sack Potassium Chloride (Potash) 1 00 Ib sack Bulk Potassium Ferricyamide 1 00 Ib drum Potassium Metabisulfite 1 00 Ib sack Potassium Nitrate 1 00 Ib sack Page 5 e e INORGANIC AND ORGANIC CHEMICALS (con't.) Potassium Permanganate 330 Ib drum Potassium Phosphate 1 00 Ib sack Potassium Sorbate 1 00 Ib sack Potassium Sulfate 1 00 Ib drum Propylene Dichloride 520 Ib drum Paraformaldahyde 50 Ib sack Quebueuo 50 Ib sack Salt XXX Bulk 50 Ib sack Salt Food Grade 80 Ib sack Soda Ash Bulk 50 Ib sack 1 00 Ib sack Sodium Acid Pyrophosphate 100 Ib sack Sodium Benzoate U.S.P. Flakes 100 Ib sack Sodium Bicarbonate 1 00 Ib sack Sodium Bisulfate Globular 1 00 Ib sack Sodium Bisulfate 1 00 Ib sack Sodium Bromate 200 Ib drum Sodium Bromide 270 Ib drum Sodium Gluconate 50 gat drum 50 Ib sack Sodium Hydrosulfite 250 Ib drum Sodium Hypochlorite 55 gal drum Sodium Hypophosphite 110 Ib sack Sodium Metabisulphite 110.23 Ib sack Sodium Metasilicate 1 00 Ib sack Sodium Nitrate 1 00 Ib sack Sodium Nitrite 1 00 Ib sack Sodium Silicate 40 640 Ib drum Sodium Silicate B.J. 120 640 Ib drum Sodium Silicate D 100 Ib drum Sodium Sulfate 1 00 Ib sack Sodium Sulfite 1 00 Ib sack Sodium Sulfide Flakes 415 Ib drum Sodium Sulfide 425 Ib drum Sodium TripOlyphosphate 1 00 Ib sack Sodium Thiosulfate 1 00 Ib sack Soluble Oil 55 gal drum Page 6 e e INORGANIC AND ORGANIC CHEMICALS (con't.) Solvents Cleaning Solvents 55 gaJ drum Lacquer Thinner 55 gal drum Mineral Spirits 55 gaJ drum Solvents 172-L 55 gaJ drum Solvent 355-L 55 gaJ drum Chevron 11 00 55 gal drum Solvent 1200 55 gal drum Solvent 51 5 55 gaJ drum Solvent 8 55 gal drum Solvent G 55 gaJ drum Stoddard Solvent 55 gaJ drum V. M. &P. Naptha 55 gal drum Sulfamic Acid 50 Ib sack Sulfur Dioxide 1 ton cylinder Tartaric Acid 50 Ib sack Toluene 55 gal drum Triton N-10 475 Ib drum N·1 01 480 Ib drum X-45 480 Ib drum X·100 480 Ib drum as-30 515 Ib drum Urea 46% N 80 Ib sack Versene 1 00 600 Ib drum Venadiam Pentoxide 1 00 Ib sack White Oil 55 gaJ drum Xylene 55 gaJ drum Zinc Carbonate 50 Ib sack Zinc Oxide 50 Ib sack Zinc Sulfate 55 Ib sack Page 7 e e e DRILLING FLUIDS MATERIALS B.C. 25 L.P. 5 gal pail 3Cyanamer P-26 50 Ib sack 3Cypan 50 Ib sack Defoamer 50 Ib pail Defoamer + 40 Ib pail 1 Desco 25 Ib sack DMS 50 Ib pail Drillaid DFLC-L Mud Deflocculant 5 gal pail 7Drillaid FCA·11 Filtrate Control/Shale Stabilizer 50 Ib sack Drilling Starch 50 Ib sack 1 Drispac Super Low 50 Ib sack 1 Drispac Regular ·50 Ib sack 1 Driscose 50 Ib sack 2H E C Polymer 50 Ib sack Ume Hydrated 50 Ib sack Ume-Quick (Calcium Oxide) 60 Ib sack e M.D. 5 gal pail M.D. + 5 gal pail ~Natrasol 50 Ib sack Potassium Bichromate 1 00 Ib sack Potassium Carbonate 1 00 Ib sack Potash 1 00 Ib sack eWes Thin A multi-purpose deflocculant 5 gal pail eWes Vis A bentonite extender & Drilled Solids Flocculant 5 gal pail 5Polysec K. D. 50 Ib carton Sapp 1 00 Ib sack Saw Dust 50 Ib sack Soda Ash 50 Ib sack 100 Ib sack Sodium Bicarbonate 50 Ib sack 100 Ib sack (con't) REGISTERED TRADEMARKS 1. Drilling Specialties Company 2. Union Carbide Company 3. American Cyanamid 4. Hercules Chemical Company 5. American Colloid Company 6. Mud Specialists, Inc. 7. Welchem, Inc. 8. Westbridge Oilfields Products Page 8 e DRILLING FLUIDS MATERIALS Sodium Bichromate 1 00 Ib sack Sodium C.M.C. 50 Ib sack Sodium Chromate 100 Ib sack Sodium Hexametaphosphate Plate 50 Ib sack 1 00 Ib sack Sodium Hexametaphosphate Granular 50 Ib sack 1 00 Ib sack Sodaphos 50 Ib sack 'Soltex 50 Ib sack T.B.P. Defoamer 50 Ib bucket Zinc Chloride 440 Ib drum Page 9 e' Barite 1 00 Ib sack Mica Fine 50 Ib sack Nut Seal Fine 50 Ib sack Nut Seal Medium 50 Ib sack Nut Seal Coarse 50 Ib sack Sawdust 25 Ib sack Cedar Fiber 40 Ib sack Kwik Seal Fine 50 Ib sack Kwik Seal Medium 50 Ib sack Kwik Seal Coarse 50 Ib sack Cottonsead Hulls 50 Ib sack Cottonseed Pellets 50 Ib sack REGISTERED TRADEMARKS 1. Drilling Specialties Company e e CLEANERS AND DEGREASERS Page 1 0 e e DEGREASER Heavy Duty Solvent Emulsion Degreaser Deep Solvent Penetration BC DEGREASER will quickly penetrate Grease, Oil, Tar, Carbon and many other heavy soils. Recommended for use on, production equipment engines, trucks, plant floors and meta! surfaces. After allowing sufficient soak time to penetrate the soil, a steam or pressure washer will remove oil and grease with no problem of oily residue. Surface Safety BC DEGREASER may be used on all metals such as, aluminum and magnesium, glass, concrete, most paints, plastics and rubber. Versatility & Savings BC DEGREASER is used diluted with 1 to 1 0 parts water for most cleaning and degreasing applications. For heavy jobs BC DEGREASER can be diluted with diesel, 1 to 40, this, provides a single product to meet every heavy duty cleaning and degreasing application. Typical Dilution Rates Hardened Carbon and Deposits.. . . . .... . . .. . .... . .. . . . . . . . . " . . . . Up to 2 parts water Thick Grease and Open Gear Lubricants. . . .. . . '" . . . . . . . . . ., . . . . . . Up to 2 parts water Hardened Oils and Compacted Soil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 . 8 parts water Gas and Diesel Engine Deposits .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 . 1 0 parts water Medium to Heavy Deposits of Oil and Grease. . . . . . . . . . . . ~ . . . . . . . . . . Up to 5 parts water Ught to Medium Deposits of Oil and Grease . . . . . . . . . . . . . . . . . . . . . . . . . 3 - 1 2 parts water Chemical & Physical Characteristics Appearance . . . . . . . . . . . . . . . . . Amber Liquid Weight Per Gallon. . . . . . . . . . . . . . . . . 8.4 Ibs. pH: Concentrate. . . . . . . . . ... . . . . . . . . . 10.5 10% Solution. . . . . . . . . . . . . . .. ......9.65 1 % Solution. . .. . . . . . . . . .. . . .. . . . . . .9.25 Flash Point, . . . . . . . . . . . . . . . . . 174°F (COC) Rinsing ............... Excellent with water Use B C Degreaser to Remove · Greases · Uncured Resins · Tar and Asphalt Stains · Printing Inks · Carbon Stains · Stamping Oils · Rubber Skid Marks · Soot Stains and Smut · Carbon Black · Open Gear Lubricants Use B C Degreaser for Cleaning · Tank Trucks · Diesel Engines · Oil Storage Tanks · Production Machinery · Grease Racks · Plant Floors · Running Gears · Auto Chassis · Fork Lift Trucks · Auto and Truck Blocks Packaging 5 gallon and 55 gallon drums Bulk shipments Page 1 1 e e DEGREASER II Heavy Duty Solvent Emulsion Degreaser Deep Solvent Penetration BC DEGREASER will quickly penetrate Grease, Oil, Tar, Carbon and many other heavy soils. Recommended for use on, production equipment engines, trucks, plant floors and metal surfaces. After allowing sufficient soak time to penetrate the soil, a steam or pressure washer will remove oil and grease with no problem of oily residue. Surface Safety BC DEGREASER may be used on all metals such as, aluminum and magnesium, glass. concrete, most paints, plastics and rubber. Versatility & Savings BC DEGREASER is used diluted with 1 to 1 0 parts water for most cleaning and degreasing applications. For heavy jobs BC DEGREASEA can be diluted with diesel, 1 to 40, this provides a single product to meet every heavy duty cleaning and degreasing application. Typical Dilution Rates Hardened Carbon and Deposits. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Up to 2 parts Thick Grease and Open Gear Lubricants . . . . . . . . . . . . . . . . . . . . . . Up to 2 parts Hardened Oils and Compacted Soil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 . 8 parts Gas and Diesel Engine Deposits ......... . . . . . . . . . . . . . . . . . . . . . 3 . 1 0 parts Medium to Heavy Deposits of Oil and Grease. . . . . . . . . . . . . . . . . . Up to 5 parts Ught to Medium Deposits of Oil and Grease . . . . . . . . . . . . . . . . . . . . 3 . 1 2 parts Diesel or Solvent Chemical & Physical Characteristics Appearance ................. Amber Uquid Weight Per Gallon. . . . . . . . . . . . . . . . .8.4 Ibs. pH: Concentrate. . . . . . . . . . . . . . . . . . . . . 10.5 10% Solution... . . . . . . . . . . . . . . . . . . . .9.65 1 % Solution ........ . . . . . . . . . . . . . . . . 9.25 Flash Point. . . . . . . . . . . . . . . . . . 195°F (COC) Rinsing ............... Excellent with water Use B C Degreaser to Remove · Greases · Uncured Resins · Tar and Asphalt Stains · Printing Inks · Carbon Stains · Stamping Oils · Rubber Skid Marks · Soot Stains and Smut · Carbon Black · Open Gear Lubricants Use B C Degreaser for Cleaning · Tank Trucks · Diesel Engines · Oil Storage Tanks · Production Machinery · Grease Racks · Plant Floors · Running Gears · Auto Chassis · Fork Uft Trucks · Auto and Truck Blocks Packaging 5 gallon and 55 gallon drums Bulk shipments Page 1 2 e e THREE·W A Y DEGREASER A Safe All Purpose Cleaner BC CHEMICAL THREE·WAY DEGREASER is a liquid cleaning concentrate with these outstanding advantages: Rapidly removes heavy oil, grease and grime from machinery, equipment and floors. Soluble in hot or cold water and can be rinsed off with water leaving a streak-free surface. Safe to use because it is a non-explosive water solution. Non-corrosive to metal and concrete surfaces. Economical to use. How to use B C Chemical Three-Way Degreaser For medium to heavy deposits of oil and grime I dilute all purpose cleaner with 3 to 1 0 parts of water. For very heavy deposits of oil, grease or dirt, mix concentrate with 3 to 10 parts of kerosene or diesel oil. Application Methods B C Chemical Three-Way Degreaser may be applied by wiping, brushing or spraying on the soiled surfaces. The product may also be used in dip tanks or circulated through equipment to remove oily deposits. Vertical surfaces may be cleaned by mixing 4 parts of 8 C Chemical Three-Way Degreaser with 4 parts of kerosene and 1 part of water. This mixture clings to vertical surfaces until rinsed with water. Handling 8 C Chemical Three-Way Degreaser is an alkaline solution and contains detergents. Care should be taken to avoid splashing product in the eyes. In case of eye contact, flush eyes with plenty of water. Packaging 5 gallons and 55 gallon drums Page 13 e e CT5-1 CLEANER In the 8. C. Chemical line of cleaner products I this high-alkaline detergent is designed for use in pressure spray or soak type bottle washers. Well adaptable for heavy-duty cleaning of product lines, pasteurizers, mixers. cookers and other processing equipment. CTS-1 Cleaner is a blend of alkalies, organic chelates, sequestrants, wetting agents and other ingredients. These combine to provide a full range of Important advantages I such as: A complete bottle washing material. It's very effective in automatic bottle washing machines of all types, including high pressure spray machines. A thorough cleaning agent for spray washing of reusable plastic milk containers. The high alkaline content provides germicidal protection. CTS-1 provides lubricity to reduce friction and wear in bottle washers. Sequestrants prevent the deposition of scale on bottles and washers. Organic chelates aid in the control of aluminate scale, caused by dissolved aluminum foil labels. The best in cleaning results from high rinsability. In food plants, CTS-1 is a heavy-duty cleanèr for product pipelines, jUice pasteurizers, vegetable cookers, and other stainless steel processing equipment. How and where to use CT5-1 Cleaner Bottle Washing: Concentration of CTS-1 depends on the caustic requirements of regulatory bodies in the locality. 1 oz. per 1 gaL of CTS-1 equals .71 % cuastic by weight; or .7 oz.lgal. equals 1/2% caustic by weight. When a code requires 3% caustic. this can be met by using a solution of CTS-1 at 4-1 /4 ounces per gallon. Food Processing Equipment: a 2 to 4 oz./gal. solution at 1600 - 180°F, will handle most jobs. Plants with central alkali system: for all phases of cleaning operations I the centraJ reservoir should contain 4-1/4 oZ.lgal. to handle bottle washing I heavy-duty cleaning and circulation cleaning requirements. CTS-1 is especially useful in breweries, bottling plants, dairies and food canneries. NOTE: Uke any alkaline material, CTS-1 should be added slowly to cold water while stirring - never to hot water either for original makeup or for upkeep. The usual precautions for handling alkaline materials and solutions should be observed. Page 1 4 e -, AST-1 Cleaning Compound AST-1 is a formulated product that quickly and easily removes soils and stains that ordinary cleaners do not. AST-1 is non-toxic, will not cause burns on the skin; has no irritating fumes; is non-corrosive; safe on all plastics and paints; and on electrical insulation. Will not injure acrylic paint or other paints used on equipment, machines or autos. COMPOSITION Water based solution of alkaline ingredients, biodegradable surface, active agents, and emulsifiers. Is non-flammable and has to flash point up to and including its boiling point. AUTO AND TRUCK WASHING Pre-rinse with water. Dilute 1 cup AST-1 per gallon of water. Apply by spray and brush surface, rinse with water. This will not cause any harm to car finish. Leaves a bright and well kept appearance. STEAM CLEANING Dilute up to 20 to 1 in solution tank, no caustic, no odor. Safe on all types of metal. Aluminum and stainless steel especially. Provides spray wetting and penetrating action. PACKAGING 5 gallon and 55 gallon drums Bulk shipments Page 1 5 e e HOT TANK CLEANER A powerful alkaline cleaner fortified with special detergents for rapid penetration and emulsification. Used for removal of caked oil on engine blocks. Protection equipment. Used where a standard degreaser is not enough. Not recommended for use on soft or nonferrous metals, such as aluminum or magnesium. HANDLING PRECAUTIONS ec'S Hot Tank cleaner is a strong alkaline compound and is hazardous to personnel, unless proper safety precautions are exercised when handling. Avoid contact with: Skin, eyes ot clothing. When handling I wear rubber clothing, gloves, and face shield. In case of contact with skin: flush exposed area with water and rub area affected for 15 minutes. For eyes, flush with water. Contact physician. PACKAGING 55 gallon Fiber Drums (405Ibs.) Page 16 RESINS (Bulk or 50 gal bbls.) OIL '1111 '1A1I '1A1I VltCOllTY HIA' FUXUIIAL PLIXUIIAL "NIIL IIINUTEI IIO'HIIIII TIMI ,,, THIIOTIIO,.C .A"COL DEFLICTION I'''ENOTH IIODULUI "RENOTH ILONOATlON ,,,ooue, "PI 'ROMOTED 71' , II'HUTES CPS INDEI HA"DNESS TEMPERATURE PSI I 10' PSI PSI % COMMENTS GENERAl PURPOSE LAIIINA TlNO RISlNS AllIIk 083,11 Rigod V.. 7,11 310,380 18·24 400·800 21,38 38,44 150 14,000 48 1,800 1 7 Modefa.e cure. f&st ...nlOO .e...... ...th ..,elent citAtn reSistance AllIIk 083·14 RIQid V.. 12·18 310,380 27·31 400·800 2.1,38 38.44 150 14.000 48 7.800 1 7 AIIeII 063,18 Rigod V.. 17·21 3 I 0·360 30·35 400,800 27·3.8 38·44 150 14.000 48 7,600 I 7 AllIIk 298·8 Rigod V.. 7·11 330,400 18,20 400,800 27·38 40-44 185 18,000 50 8,500 17 h".. c:..ong. llet*aI purpose _long I..... . ... 063 _... All... 188·14 Rigid V.. 12·18 330·400 22,27 400,600 2.7·38 40·44 165 18,000 50 8,500 I 7 AllIIk 298,18 RIQid V.. 17·21 330·400 30,35 400,600 27·38 40·44 165 18,000 50 8.500 1.7 All... 158·13 Rigod Y" IH5 330·400 22,28 400·800 2.7·38 40·44 185 18,000 50 8,500 1.7 _'1. u-t ...... ...h good ...._.. de~' "ESINS FOR USlIN ALUMINUM HYDIIA TE AND VlTROfIL FILLED SYSTEIII V"Y .....l1/li to 131_ ..hen lolled, QJves good CUI. AllIIk 098 SemAgid V.. 8·10 330,390 12·18 100·130 I 1,2 I 3341 HIA HIA· Flied WIATH and __.. <lewrtlopmenl All... 31 5 SemAgid V.. 8·10 330·390 11·18 100·130 I 1,2 I 34,44 HIA HlA· Flied WIATH Fe.... cunng _..".. 01 A"ek 096 liES INS FOil SYNTHETIC MAIIBLE + ONYX U AllIIk 035 RIQid Y.. 8·12 285,310 18·24 700,IlOO HIA 38·44 150 12,500 5.D 8,400 12 TO)I, ....., """"".1. gel, mode"" cur. I) ) AIIeII 14 I RIQid V.. 7·11 265·310 17·22 IlOO·11 00 HIA 38·44 150 12,500 50 8,400 12 TO)I, ...ts"" ...... .,Iegolb, lasl gel c:... .,., cIemOkJ D ,.) All... 200 Rigid Y.' 8·13 275·305 18'24 Tope, onlegJlI _,.... Ihrllll<age INn AIIeII 035 .) 1300·1700 HIA 37,42 ISO 12,500 50 8,400 12 All... 287 s.m.RIQid Y" 14·18 280290 3034 850,11 50 HIA 34,38 110 11,000 50 8,000 22 Good ....oÞokty lor manuloc:...ong ...... ...- ...... AllIIk 318 RigId V" IH8 310·340 25·35 IOSO·1250 HI" 38·48 185 18,000 50 8.500 I 7 EaC_1 coIor"e<:OIM1'_ lor /IogII quMly ony, ~Þon.·...1s and "',egJ..., 'aøod cIemoId e AII.k 333 RIQid Y.. 58 310,340 10·18 800,1100 HIA 38,48 185 18,000 50 8,500 I 7 Tope and..... . I..' u-t and c"'.. All... 334 RIQid Yea 8·12 285,310 18·24 2800,3400 NI" 38,44 150 12,500 50 8,400 12 E....moly hg\I "'1t""ly lor IOØ. and 11.1. Modet.,. oet. mode,e.e f;ur. e.hDi.. 10..' ""U1II.~ IIESlNS FOil CLUII CASTING AND DECOIIATlVE USES AllIIk 331 Rigod 315,335 30,38 10,000 8,1100 I , fllc.lenl CØOI'. 'ec~ 'or c.... c...eng Of V.. 11·111 400,1100 HI" 311·411 1115 liD deCOIa'l'lI. IlPØk.llIOna. moôIf.le gel. mOdef.... C~. ISOPHTH"LIC IIESINS All... 1880 SemiRogod V.. 11,111 360· 4 20 21·21 400,800 2 4,J 2 30,34 210 11.000 40 10.000 38 MOder a.. COIIO.,on ,elll'ance. .."'lb1hng hIgh etong.1Þon Seploc: ......., S)I.yer ....... "'" ,........ All... 284 RIQid y.. 11-15 400·4211 2"27 400,600 24·32 341·42 220 16.000 110 7,000 18 Moder.I. COIIOIO'I''''Sranc., _al' etor; "'. ' hghef ....1 rlellecÞon tempel.I",e """"'....,... . '~" 10 AIIek 1660 AII.k 338 Rigid y.. 1\·15 400·425 l'{ 27 400600 24,32 Good Corro",," r."slanee OOO ....1 <Ie'''chon 1_...... TRADEMAR\! "'P'a R...... e e CONCENTRATED ALUMINUM BRIGHTENER Concentrated Aluminum Brightener for all non-ferrous metals: CHROME, ALUMINUM, BRASS & COPPER DIRECTIONS: 1. Cut Concentrated Aluminum Brightener with 40 parts water. 2. Wash surface to be cleaned with soap and water. 3. Spray surface generously and evenly with cut solution of Aluminum Brightener. Allow to soak from 1 to 2 minutes. 4. Rinse thoroughly with water. On very dirty or heavily soiled surfaces, repeated application may be necessary. CAUTION: Be careful not to splash into eyes or on clothing. Do not breath fumes. Keep out of reach of children. Contains: Phosphoric mineral and organic acids. MAY BE HARMFUL OR FATAL IF SWALLOWED. DO NOT INDUCE VOMITING. GIVE MILK OR WATER. CONTACT PHYSICIAN IMMEDIATELY. IN CASE OF EYE CONTACT: FLUSH THOROUGHLY WITH WATER. CONTACT PHYSICIAN IMMEDIATELY. Packaging 1 gallon, 5 gallon, 55 gallon drums Page 1 7 e e TRANSITMIX Packaging 50 gallon bbl. Bulk e e FORMULATED PRODUCTS FOR SPECIFIC APPLICATION Page 1 a e e DATA SHEET 05-100 OXYGEN SCAVENGER FOR DRILLING FLUIDS AND WATER TREATING . Description: 05-100 is a 52% by weight ammonium bisulfite solution and is an oxygen scavenging agent for drilling fluids and other water systems requiring 'oxygen removal. Typical Properties: Appearance Density, Lb/Gal. Sulfite % pH - 50% Solution Clear Ught Yellow Uquid 10.8 55 4.5 Suggested Uses: 05-100 may be substituted directly for catalyzed sodium sulfite as an oxygen scavenger. It is a stable solution and being a liquid, there are no dissolving and plugging problems. Use of 05-1 00 in drilling fluids and other water treatment uses allows protection from Oxygen corrosion of drill pipe, pumps and other metals in contact with the media. 05-1 00 should be added continuously directly at the pump suction utilizing a chemical injection pump. Theoretical treating ratio is slightly less than 9 parts of 05-100 per 1 part of oxygen. Pumping rate is dependent upon the oxygen concentration present. A minimum of 100 ppm excess sulfite is recommended. In drilling fluids, the base line corrosion rate may be established by running drill pipe corrosion rings in the drill string prior to commencing treatment. The coupons should be run in the drill collar cross-over sub, and the kelly saver sub. If only one coupon is to be run, it should be placed in the drill collar crossover sub. Rings should be run a minimum of 50 hours (100 hours is desired). Page 1 9 e e BC MICROBIOCIDES 5 gallons 55 gallons B.C. Mlcroblocide 1000 B.C. Microbiocide 2000 B.C. Microbiocides, available as B.C. 1000, a 25-per cent aqueous solution of glutaral- dehyde, and B.C. 2000, a 50-per cent aqueous solution of glutaraldehyde, are useful as preservatives and in formulating broad spectrum indusbial biocides. B.C. Microbiocides have many important features including: · EP A Registration · Effectiveness against a broad spectrum of microorganisms · Aqueous solutions which are easily and uniformly diluted and mixed · Ability to be easily neutralized for disposal · Effectiveness against aerobic and anaerobic organisms ·Compatible with anionic, nonionic, cationic surfactants · Do not contain or release formaldehyde · Lower vapor pressure than formaldehyde · Diluted product easily analyzed by gas chromatography · Not affected by the presence of hard water [, . STORAGE AND HANDLING OF B.C. MICROBIOCIDES OIL WELL MICROBIOCIDE B.C. Microbiocide 1000 is an aqueous solution of Glutaraldehyde, at 25% (by weight) concentration. It is slightly corrosive to common materials of construction, such as steel, aluminum, and galvanized iron; the corrosion rates are low (equipment would not be severly damaged) but contamination of the product will result if contact is prolonged. Materials which have been tested and found to be suitable are stainless steel, certain fiberglass-reinforced plastics, and polypropylene or polyethylene. Types 304 or 316 stainless steel are suitable. Of the plastics tested, a polyester ("Atlac" 382) and a vinyl ester ("Derakane" 470) were resistant, but an epoxy showed some adverse effect after prolonged exposure to Glutaraldehyde. Uned steel containers are not recommended because iron contamination can result, due to pinholes in the coating. NOTE: Storage tanks, lines, pumps, valves, etc., must not be made of iron or steel. Even trace iron contamination (one ppm or less) can have an adverse effect on the long-term stability of the product. The 25% solution freezes at about -10°C (14°F). Thus, if outside storage is planned, heated and insulated facilities will usually be required. However, the storage stability of Glutaraldehyde is very dependent on storage temperature and storage at temperatures below 100°F is recommended. Preferred locations for a storage tank might be either indoors or underground; drums could be stored in a warehouse or, during hot weather, in a shaded storage area where they are not directly exposed to the sun. If B.C. Microbiocide 1000 is to be heated, warm water is the preferred heating medium, in order to insure that the product will not be exposed to high temperatures. It is suggested that water temperatures should not exceed about 40-500C (1 00-1 20°F) and temperature controls could be set so that the average temperature of the stored liquid is only about 20°C. This should insure a reasonably long storage life for the product. Piping and valves can be of pOlypropylene or polyethylene or stainless steel. A stainless steel centrifugal pump is suitable for transfer service. Asbestos can be used for gaskets and packing. NOTE: If B.C. Microbiocide is to be diluted I use only distilled/deionized water that is low in iron, calcium I and magnesium content. 20 ~~ e e UCARCIDE I MATERIAL SAFETY DATA SHEET Antimicro CHEMICALS PRODUCT .... (.Aþ~Io"ød bl' U.s. D'ø~IVllen, of L.bol.' ".uI,,,;.1I1' .imil.,- 10 Form LSS.QOS4 SECTION I-IDENTIFICATION OF PRODUCT MANUF ACTU A ER'S NAME EMERGENCY TEI.EP...ON£ HO. BC CHEMICALS INC. AOOR ESS (Numbtr, Slutl, Oly, SIGle Gnd ~I' .._6J 1511 South Union Avenue/Bakersfield 805/832-1360 TAAOE NAME CHEMICA\.. HAME MICROBIOCIDE 1000 Not app~icable/Blend of Mate CHEMICAL. FAMILY CHEMICAL FORMULA Aldehyde . . " . . . SECTION II·HAZARDOUS COMPONENTS OF MIXTURES A preCIse composibon 01 this product Is proprtelaty inlonnabon. A more detaJled disclosure wiD be provided by BC èhemicals u privileged ~'~~~t upon request in case 01 need lor specjfic lreatmenL ¡ AQUEOUS: SOLUTION OF ALDEHYDES FREIGHT DESCRIPTION: CHEMICALS, NOlSN DANGEROUS ARTICLE DESCRIPTION: NONE DOT WARNING LABELS REQUIRED: NONE APP~ARA"'CE ANa ODOR Clear liquid, formalin odor BOILING POINT 1°F) PERCENT VOLATILE o 0 (BY VOLUME) Slightly less than 369 F/187 C (decomposes) SECTION IIl,TYPICAl PHYSICAL DATA SPECIFIC GRAviTY-' 1.063 to 1.075/ 20/20oC .-.-- 100 -.------ EVAPORATION I<ATE In- BUTVL ACETATE· 1) --.....---.. VAPOR PA.E!>SUR£ o @20 C = 17 mm Hg "Ai-OR C(N5ITV (AlA 11 Greater than 1 ~ SOLUBILITY 'N WATER Complete . -------.----- --- -- _~~~TIÖf'!.!Y..FIÅ1..!'ND_~!.~<?SION HAZ~_RD~AT~. E =E- . :~.' r!..AS,., POINT {.~f<:lhodJ {'LAMMABLE LIMITS 1.., U.I .. (I'£HCENT BV VOLUME) ._. . - - _ ___None _ ___ __ .__._ __ ______._ _ _!y~_. 1Y~__ ",7,( (XTINGUISHI';,ie ,,,ïËë;jiÃ- --- _. .__. ._~'?LA.pE~j~~l~m~L. ._._.. ~P(CIAL 1'11.,£ FIC,..TlNG PROCEOURES ..---... ~.-_.- ....--.----.... --------..------- __ _.__ ,...~9.~_~lica~.1.!L,_ ...____________,. . -.....--.---.-.-----. -..---.----..--.--. '" ....NL'SUA ~iiRC;::r<OEXPLosïõÑHÄZA 'Rõs-- Not Applicable - --. --- - ---.. -.-..-..--. _._-- .....- ---_. - - ..- ..--......--..--.---... -----.. " I :....i';. R'o-oùi p-'¡õÓü"ëTSO"-'-oM8usrï'õÑ-"- Not Applicable ---..------- --- - --- .... ." _~....:_.._.:....---._~-~~:.:.-.~-...:r....:..__o:.;::.;~- --==--:.:=.. ..~r_-=-..:....,.;,r.~~~-~~'· ----:-'.=~~~.=:al._: .:.#-~:--- TH~S 1'.~::¡:,!.~':'110" RELATES O!'.lLY TO THE SPECIFIC MATERIAl.. CESIG':ATED A"C M.:.V NOT 8: VALID FOR SUCH IAA1ëAIAL USED I,. COM8J"IATlON WITH MIY CT,...ER 1.'Ate.RIALS OR IN IoNY PROCF.SS, Su~ inlolr.\aban is. 10 Ih. besl 01 BC C"c:r..;,a'¡ knc..'ed~e and bel,.'. accwale WId lel,~. as 0/111. &1. ondic.atacl. HOWEVER. NO REPRESEmATION. WARRANTY OR GUARAN1EE IS IU.~;: AS TC ITS ACCURACY. REUAS'UTY OR COMPLf:TENESS. IT IS THE U5ï:RS RëSPO~.SI8IUTY TO SATISFY HII.'SElF AS TO THE SU¡'A9LE~~~ SS ASC COMPLETENESS OF SUCH INFORMAnON FOR HIS O....N pJ..fmCUL:.A USE. 21 e e ¿ SECTION V· HEALTH HAZARD DATA TtofRESHOL.D LIMIT VALUf; Rats survived 8 hour exposure to saturated vaoors. ~~~di~tab1~!ªr~l~ug5? exposure to vapors by humans is irritating to· EFFECTS OF OVEREXPOSURE ACUTE e es res l a or assaoes. CHRONIC Prolonged skin contact causes faint redness & tannina effects. EMERGENCY ANO FIRST AIO PROCEDURES eves , skin with water ~n.,. a - Followina contact: Flush fifteen (15) minutes. Remove victim to fresh air. artifical resDiration if I riecessarv. CALL A PHYSICIAN. -j SECTION VI· REACTIVITY DATA STABILITY CONDITIONS TO "VOID ur~STl.aLE STABLE x NOT APPLICABLE INCOMPATIBIUTY IMATERIALS TO AVOID FOA PURPOSES OF TRANSPOAT, HANDLING" STORAGE ONLY. I Transport: Store in baked phenoliç-lined steel or SS. O%; in approved reinforced vessels. Heating & insulation is indicated, as required. Avoid hi-temp. I tofAZAROOUS DECOMPOSITION PRODUCTS : ; Aldehydes: Avoid inhalation, skin, & eye contact. ì ¡ ; I SECTION VII . SPIll OR lEAK PROCEDURES STEP!> 10 BE TAKEN IN CA!>E MATERIAL IS RELEASED OR SPILLED Shut off source if possible. Advise authorities if substance has entered a water course. WA!>TE O'SPO~AL (INSURE co:rP~fY WIT:1 "'ictk DISPOSAL R.F..GULlHIONSd d' 1 t . th t Recover by ontaln Spl e lqUl 1. sana or ear an 1 u e Wl wa er. pumping or with suitable absorbent. If spilled, it may be possible to deactivate the solution carefully with ammonium hydroxide or w/aqueous sodium bisulfite to sIi Iht.l· baS1.c. g y SECTION VII'· PERSONAL PROjECTION INFORMATION RESPIRA"!'ORV PROTECT'!:)N . Use approved respiratory protection such as air supplled if in enclosed spaces.. ..OCAL. EXHAUST .', . rsPiCiAL Not needed 1.n open/unconflned I MECHANICAL ,C'nud) õTMËR Forced ventilation if needed. _-1-_ P"õT,"cTT\i"Ëd~õ"ES ~EYE PROTECTION Chemically resis~glove~~ Approved chemical splash goggles. C)TroEQ p"'oTEai\iEËÕüIPMENT Protective apron of rubber, neoprene I or plastic. VENTILATION SECTION IX· HANDLING AND STORAGE PRECAUTIONS ;·iiËCAUTON!io TO 8E TÃK£N IN HANDL.'NG ANO STORING Stored in baked-phenolic-lined steel or 55. or aFproved reinforced plastic ..-------...--.. - - vessels. K~ep containers closed when not in use/avoid hi-temp. Wear protective clothing & õr;' ¡:¡ïp'"ËëAUT~' åccessorics ãš dcšcr1bëëL-- ., NONE .-.-------.--- -..-----.--.-.---.-. .- .-s,.--~--~~~ . ",PAOV ;0 BY, 1«.'-'" ¿./.~. / Req__!:hC~~=; ¡B;:':: TITLE:' (/ ndus(rial Hygiene Director --=-. -~ -. -- -- - --.---..--. ".c. T E 0'- ISSUE lì . . NEW ,..._....~.:.~ . - - DR!:vISEO: SUPERSEoes -R_. _ 22 ~-~ -» e e -....--... CHEMICALS MATERIAL SAFETY DATA SHEET PAOOUCT -- IAþþlo"ød by U.S. Døø.'Cln.nr of L.bo'.' ....,.nri.II" .imiJ.,- to Fa"" LSS.oos.." SECTION I·IDENTIFICATION OF PRODUCT MANUFACTUAEWSNAME EMERGENCY TEL£P1-40NE NO. BC Chemicals AOCQESS (/'vu,"bø" SIU~I. Oty. :il"t~ "nd ZJP Cod.) Bakersfield, 1511 SO. Union Ave. Calif. 93307 (805) 832-1360 TRAOE NAME --- C1-4EMlcAL NAME BC Microbiocide 2000 G1uteraldehyde CHEMICAL. FAMILY CHEMICAL FORMULA Aldehydes DHCC3H6CHO SECTION II·HAZARDOUS COMPONENTS OF MIXTURES A precise compositlo:'l of this product is proprietary infonnaUan. A more detailed dlacIoeute wi. be provided by BC Chemicals.. ørMIeged Informaa upon reQuest In case of need for specific treatment. on AQUEOUS: SOLUTION OF ALDEHYDES FREIGHT DESCRIPTION: CHEMICALS , NOIBN DANGEROUS ARTICLE DESCRIPTION: NONE DOT WARNING !ABELS REQUIRED: NONE .---------. SECTION III·TYPICAL PHYSICAL DATA SPECIFIC GRAVITY H20=l APPEARANCE ANO OOOR CLEAR LIQUID I SHARP ODOR 1.131 @ 20/20oC BOIL.ING POINT ¡OF) 760 MM Hg=lOl.2oC (2l4.2Of) ---- --.-----.------ - .-----.-. . ------.-.------- PERCENT VOLATIL.E (BY VOL.UME) 50 (WATER) EvÃPÕRÃrïõÑ' RATi- -------...-. ¡n-SUTYL.ACETATE-l; 0.93 ·,·APOR PRES::'URE ....-. -----.... .----. ..-...-----.....-.- . .-...---......-------..-.....--..... .--...-.........- VAPOq OENSITY (o.IR 1) Greater Than 1 ŠÓï:uBIL.ITY IN WATEï:¡-------- .....-- @ 200C=COMPLETE ---¡-'------'---- ---- SECTION IV·FIRE AND EXPLOSION HAZARD DATA -- - j:·C¡;:;'-;;(;ÏÑ-:-t.lftthod/-Ñõne-;-··ëJ:evéTãñã"Opëñ·-è;up lL.AMMABL.E L'.MiTS-- . -..~_.--:;;- ---r-~ - . ¡PERCENT BY vOL.UME') "'==~.'O-"":.:""-.' ASTMD92; None, Tag Closed cup ASTM D-56 .u me~uano . metua: ~¡¡:¡¡ZË~TïÑëuïs~MEï5iÃlf-water"Is bõiled ó-ff, -res-iduãrcãiiourñ:-"-"iJšë"water sp'ray car oñ-' -- . dioxide I dry chemical I alcohol-type or universal-type foams applied by mfgr. recommended tec: ~pfë.IÃ¡::;¡¡:¡E 'F'ïGH;:i;~'PRÒëED-ÜR'ÈŠ---- - ----.------ --------...-------,- 1--. ..,..,. __.~e~~_:_c~~~~ir:~~_1?re..a.t:!1_~~~_c:!?par~~,~~'_~~~___., ,- ,-----. .. ,- .--.. -,....- --. -..-..--- . -.-.- I 1'-'NÜSUAL·F·¡;fAÑÕ·Ë:-~pl.ÕSïõ¡;¡-HÃ·ZÄRÕŠ-·'- _. ._-- --------,------- .. -..-----.-------,..------ NONE ~.__....._.._.. -.. -. -..-.....-. .--..-..--...-.---.-.-----.----------- .--.- ..__. --....-- --..... .jÃz·...Ãi,cÚ~oõi.ëT1·ÕFëoM-åüš·r;õÑ'·- --- -..--.-----------.-----. ---- ---, .--,--,--. .-- .' - .. """""'.._ ... . _ =-_ ~'JJ.11in.g _may_.pJ:o~,µce ,ca~Þ.Q.n_, ID.Qnøci9.'L ~l1gLQ:r;'..£~J;?q,I) ,.dio~iq~_.....~=...._.......-=-_____. _ .... . T1'S IM':CR'./IAT10N RELATr:S ONLY 10 nie SPECIFIC MATEAIAL DESIGNATED 110WEVER, ~IO REPRt:SENTAiION WAAHAI'ITV OF! GUÞ.RANTEE: ,5 MA"!: ~:> TC. AND MA'{ N01 BE VAI.'O FOR ::;UCH MATERiAL USED IN COMBINATION WITH ITS ACCURACY. AEUABIUTY OR COMPLETENESS, IT 15 THE I.:SH.::. ANY OTHt:H MMERIALS (JA IN ANY PAOCES5 Such Ir.torrnahOl'lll, 10 the best 01 AESPONSl8lUTY TO SATISFY HIMSELF AS TO THE '3UI~~l.ENI:"S.c; ~M BC C~!m.:.. iUI0WI8Clgø and beall' accur.tlll arid ,øloaDl.u 01 th. del. Indicated. COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTCUIAf1 '.::r. 23 e e - SECTION V. HEALTH HAZARD DATA T,..RE:S"'OI..D L.IMIT VAL.UE 0.2 ppm ceiling I ACGIH (1979) .- EFFECTS OF OVEREXPOSURE ACUTE If swallowed-nausea I if inhaled-chest discomfort, bronchitis symptom CHRONICProlonged or repeated skin contact may cause rash & sensitization EMERCfNCY poND F'R$T AIO PR~CEOURES by putting finger Swa low1ng: G1ve 2 g asses of water-induce vomiting down throat. Call phy- sician/Skin: Flush skin with plenty of water-remove contaminated clothing-wash clothing be- fore wearing again/Inhalation: Remove to fresh air, call physician if symptoms persist/Eyes: flush eyes w1th plenty of water at least 15 min. I get medical care eye specialist at once SECTION VI· REACTIVITY DATA ST .\81L.ITY CONDITIONS TC\ "VOID -- ur~STA3LE Avoid high temperatures (removal of water, 200'7) STABLE X IN~OMPATI9H.ITV (MATERIAl..S TO AVOID FOR PURPOSES OF TRANSPOAT, HANDLING a. STOAAGE ONL.YJ Avoid contamination with acids any alkalies. "',\ZAROOuS DECOMPOSITION PRODUCTS Burning may produce carbon dioxide and/or carbon dioxide. SECTION VII· SPILL OR LEAK PROCEDURES Large spills for dis posal. Spilled material can be decontaminated with careful application of sodium hydroxide W"STE DISPOSAL. IN$URE CONFORMITV WITH LOCAL. DISPOSAL RE;CULATIONS , A~nm;~p into very i fi i wi . erate where permitted by Federal, State and local regulations. r--' in¿šPiRÃT"5RŸ-PRonëTiõN-:" . .. . -- .'--.---'-"--J-QC-ÄC£~~li.e.d m;!.!';k In h1.qh cnn~~t:rls;!.p~Í1~n~c;. -- . .. ~ vapors are eye or nose irritating I I-~TI ~TtaN MA""".:tn,,..~l ,..1""\,"""" ,rønr,l,:¡r,cn ~ C,.~. MECHANIc;"AL /c,.."ttjJ IOTHER . . _. __._ _~xpe"::ea to b:. satisfactory L specJ.al forced ventilation may be req~i: 1'''10 rECTI \IE GLOVES =rYE PROTECTION f 1 Rubber Vapor-proo gogg es. ., . --.-- -.... ... -----...-----.---- -.--.-- l.;¡rr1ë:~ PR~HECTIVE ECUIPMENT -'-' ,-" ._____.__ .._._..__Eye bath, safety shower I rubber overshoes SECTION VIII - PERSONAL PRO'iECTION INFORMATION - ! --_.--- i SECTION IX· HANDLING AND STORAGE PRECAUTIONS 1··RE-cAürO;:~~O ë-f. TA-KE-ÑlN-;¡~-Ñoí:jNë"AÑÕSTÕRING Use wï:Enådequate ventJ.latJ.on. Wasn tfiõroughly arter' I I .. ~~.!1dli~ ...~.Avoi,! breathing vapor. Do ~C?.:... ~e~ .:yes I _o!!.._ sk"~n I clothing. Keep container , closed. FOR INDUSTRY USE ONLY. ! íJ..':"E;:¡ PR EëAUTläí~s' .--.-.-, -..--. I we~__~~g~!~~._<?!...J.~~shield and rubber gloves when handling. I I ~ ....." ---- ,_... .-.-------- I:'~' E OF' ;ssu£ l. ) ';fW . []REVISED: SUPERSEDt:S . -.... ~~._._.. - ---- -- -... I-;;;:;;;;)·~~"'_~c (/ Z~~.~~:._u_--._- _.~~ TITLE: 7" Y :.7 --. . - . 24 e e B.C. AMAZING B.C. AMAZING 1 gallon 5 gallons ECOLOGICALLY SAFE: The ingredients in B.C. Amazing products are bio-degradable - they will break down into natural components without harming the environment. There are no phosphates, enzymes, or other chemical ingredients known to cause pollution, in any B.C. Amazing product. ECONOMICAL: B.C. Amazing products are concentrated. That means you use less - a little goes a long way. There are no "fillers" that serve only to bulk up a product and make it look like you are getting more than you are. EFFECTIVE: There are no better products of their kind on the market than B.C. Amazing products. Because they are different, because they do not contain some of the harmful ingredients many people are used to, when they clean their stoves with B.C. Amazing and find there are no dangerous fumes and no skin irritation. The effectiveness of products as good as B.C. Amazing can be unexpected and surprising. When the results are so far superior to most other products, it takes some getting used to. So suggest to every customer that directions be followed carefully, rather than using B. V. Amazing products "the way they've used that kind of product before!" VERSA TIUTY vs OVERKILL: Although we use the term "all-purpose cleaner" on the label of B.C. Amazing I since that has become more or less the generic term for the type of cleaner it represents, there really is no such thing as an "all-purpose" cleaner. So-called all-purpose products tend toward "overkill". They cater to man's search for the easiest way I rather than the best way. But no liquid cleaner designed to be used for scrubbing floors can be made powerful enough to remove stubborn stains, with being too powerful for gentler tasks. That's why B.C. Amazing products have been carefully formulated to provide safe, effective, and appropriate results for the task to be done according to how they are used. The versatility of B.C. Amazing products lets YOU decide how strong a cleaner YOU need for each job. The label on B.C. Amazing describes this product as "a modern, soapless product made from a balanced formula of organic ingredients, completely free of skin and eye irritants". Let's look at each term in the name of this remarkable personal cleaner and see why we can make the claims we do for it: SOAPLESS: There are no alkalies, no phosphates, no soda ash, no artificial chemicals I or other harsh I irritating or polluting ingredients in B.C. Amazing. It will leave behind no soap scum or other residual waste. It rinses away cleanly and completely without drying the skin or leaving residues or washed surfaces. ORGANIC: The ingredients in B.C. Amazing are organic, that is, composed of the same types of carbon molecules that make up natural living matter. Thus, they are not only mild, but also biodegradable - capable of breaking down and returning to the earth, without endangering any living thing. CONCENTRATE: A little bit of B.C. Amazing goes a long way. That's why we offer a mixing bottle to go with it. All directions on the label are for B.C. Amazing diluted half and half with water - then measured in teaspoonfuls! That's real concentrated action· and real economy for any "personal touch" cleaning job! 26 e e IMPORTANT: To prepare B.C. Amazing, fill a mixing bottle half way with water first: then add the Concentrate; stir or mix gently. TO DEMONSTRATE B.C. AMAZING: Always use B.C. Amazing according to directions, in a No. 501 Jiffy Dispenser with No. 502 Flip-top on the 16 oz. size. ECONOMY: Point out that even after dilution, only a very small amount of B.C. Amazing is needed for most ordinary jobs. ' GENTLENESS: Place a drop of B.C. Amazing from the mixing bottle into the hand of your prospect. Ask her to rub it in as she would a hand lotion. As she does, explain that B.C. Amazing is gentle enough to use in bathing an infant, and that in addition to cleaning, it actually acts much like a hand lotion in moisturing and conditioning the skin. Rinse the B.C. Amazing off with a damp washcloth or under a tap. NON-FLAMMABIUTY: Remove the cap from a bottle of B.C. Amazing and wave a match back and forth over the opening. Point out that the fumes do not ignite. Next, extinguish the match by dropping a bit of B.C. Amazing onto the flame. (A wooden match provides a better demonstration than a paper match.) EFFECTIVENESS: Mark the back of your hand with lipstick and with a ball point pen, then massage in a dab of B.C. Amazing. Point out how the two difficult-to-remove blots immediately begin to be lifted from the skin by the B.C. Amazing handkerchief, then. . . . . . show the handkerchief stained with the lipstick and ink to your prospect. Rub the stain in for better effect. Explaining that the dab of B.C. Amazing you cleaned your hand with is still enough to clean the handkerchief I dip the handkerchief' under a faucet, squeeze it clean, and display the spotless handkerchief to your prospect. Point out that B.C. Amazing is harmless to fine fabrics. Smear a steak of shoe polish, paint or grease across your palm (if you want to let this dry, you can demonstrate the match test or ask the prospect to feel B.C. Amazing for herself at this point). Point out that this technique provides excellent protection for the hands while doing a job of painting, repairing greasy machinery, gardening I etc. Finally, rinse your hands in a bowl of water or under a faucet and show how the "invisible gloves" have helped protect your hands. AUTO WASHING: Mix 2 capfuls of B.C. Amazing to a bucket of water. To remove tar from any auto finish, use the Jiffy Sprayer with B.C. Amazing, medium or strong solution, then wash with B.C. Amazing to avoid stripping wax from the finish. SUGGESTED DEMONSTRATION AIDS: Jiffy Dispenser with Pump; bowl of water; damp washcloth; handkerchief; lipstick; etc. You'll want to change or add demonstrations as you gain experience, of course - but always practice before you use them on a prospect. 27 e - BC P.W.101 PARAFFIN DISPERSANT 5 gallons 55 gallons BC P.W.101 Paraffin Dispersant BC P.W. 101, an eft'ective water-dispersible paraffin-removal additive, is a high· flash, low-odor hydrocarbon solvent-dispersant. This blend helps solubilize and disperse paraffin and asphaltic deposits. A water-external dispersion made with BC P.W. 101 is an excellent substitute for hot-oil treatments I especially where oil spills and contamination are critical. Most paraffin dispersants do not function in aqueous systems as well as BC P.W. 101 nor do they have as effective paraffin-disolving properties. APPLICATIONS Well bore and Tubing Cleanout BC P. W. 1 01 can be dispersed in water or acid to clean tubular goods of: paraffin and asphaltenes allowing resumption of normal production, paraffins, asphaltenes, and other hydrocarbons prior to other stimulation treatments. BC P. W. 101 can also be used in aromatic solvents and/or mutual solvents to help water-wet solids as the heavy hydrocarbons are solubilized by the solvents. The proper concentration of BC P. W. 1 01 to ,be added to water for optimum cleaning depends primarily on the amount of paraffin present, the hardness of the deposit, the adhesiveness of the deposit, and the temperature at which the paraffin is deposited. A general recommendation is: Cold Water (below 75°F)- Use 10% by volume of BC P .W. 101 Warm Water (75 - 1 OOOF)- Use 5%by volume of BC P.W. 101 Hot Water (100 - 150°F) - Use 2% by volume of BC P.W. 101 Very Hot Water (150 - 200°F) - Use 1 % by volume of BC P.W. 101 To compute volume: Diameter of casing Standing fluid in casing Feet of perforation in casing CAUTION When used for tubing cleanout, the water temperature should never be hotter than the formation face because any paraffin that has melted in the treated water will re-deposit on the colder formation causing damage. Flow Une Cleanout BC P. W. 1 01 can be dispersed in water to clean flow lines. The above treat rates apply to flow-line cleanout. However, the water should be heated to as high a temperature as practical for most efficient removal. If the flow line is long and/or cooled by water (offshore), it may be necessary to increase the concentration of BC P.W. 101 to 5%. BC P.W. 101 will work in cold water at higher concentrations. If the water starts off hot then cools, the BC P. W. 101 will keep the removed solids dispersed. NOTE If large amounts of paraffin are deposited it may be necessary to use several lower-temperature treatments so as not to remove too large an amount of paraffins at one time, thereby physically blocking system. MIXING PROCEDURES BC P.W. 101 can be added to any aqueous fluis and a uniform dispersion can be achieved with only a small amount of agitation. If left static, the dispersion of BC P.W. 101 in water is stable up to an hour. Reagitation prior to pumping the fluid is recommended. SOLUBILITY Soluble in hydrocarbons Dispersible in fresh water, salt water, acids 28 e ,_ This product is available in bulk shipments and 55 gallon NR drums. Keep drum openings closed to prevent product contamination and evaporation. BC P. W. 1 01 contains no organic halides, heavy metals, or other substances known to be harmful to I process equipment or refinery catalysts. No special storage and handling precaution is required. Avoid prolonged and repeated skin contact. In case of contact with skin or eyes, flush exposed area with water. PROCEDURE Batch feed BC P. W. 1 01 per general recommendation at point "B". Let it sit for approximately 2 4 hours. Be sure BC P.W. 101 is completely mixed with fluid in well. Put well back on the line. BC P.W. 1 01 will perform an effective cleaning function throughout the entire system including all flow lines and valves. To eliminate future paraffin buildup, a daily maintenance program should be followed. Inject at point "A" 2 quarts of BC P. W. 101 every 24 hours per 100 barrels of produced oil. The simple and Inexpensive procedures described above will virtually eliminate costly down time due to paraffin cake buildup. 29 . eel _..._......__._ .___ø COREXIT CHEMICALS MATERIAL SAFETY DATA SHEET PROOUCT ... IApp,otl"¡ b~ U.s. Dt".,rm."r of L.bOl'.' ".",."ri.lI~ .imiJM- ro F.onn LSS-DOS-41 seCTION I·IDENTIFICATION OF PROCUCT MANUFACTURER'S NAME B.C. Chemicals Inc. AOORESS (¡Vumbt,. Strttt. ory, Stllttll ,_. _ tJ 1511 South Union Ave., Bakersfield, CA EMERGENCY TELEPHONE NO. (805) 832-1360 93107 TRAOE NAME B.C. PW 101 CHEMICAL. NAME Not Applicable; blend of materials CHEMICAL. FAMIL.Y CHEMICAL. FORMULA Surfactant in aromatic solvents Not Applicable; blend of materials SECTION II·HAZAROOUS COMPONENTS OF MIXTURES A precì3e comøosIllon of this product Is proprtetBrf Infonnauon. A more detailed dlscIoaure wtI be provided by BC Chernlalla .. prtviIeged Inf~Üon upon request In case 01 need for aøeafIc treatment. Blend of oxyalkylated alcohols and oxyalkylated alkyl Phenol in glycol ether and aromatic solvent. APPEARANCE AND ODOR Light blue liquid BOIL.ING POINT (OF) 3sSoF/1800c SECTION III·TYPICAL PHYSICAL DATA SPECIFIC GRAVITY 0.900 @ GOo/GOoF (ls.so/ls.SoC) PERCENT VOL.ATlL.E componenl::s W 1. t:.n ~. t". -.. (fJYVebu~F.t less than 212oF/IOOoC -3 VAPOR PRESSURE EVAPORATION RATE 1"_ BUTYL ACETATE. 1) O. S 5 - VAPOR DENSITV (AIR 11 gr~ater than 1 . - SOLUBIL.ITY 'N WATER 25' by volume, forms emulsion SECTION IV·FIRE AND EXPLOSION HAZARD DATA I "i.ASH POINT (MtrhodJ PM No. 2600 FiA£-¡;x TlNGiUISHING MEDIA 130°F 1-._.. __..Ex_til!guish with__~.:y chemical (carbon dio~~de or foam) waterspray may be ·'PECIA... FIRE FIGHTING PROCEDURES in- -- _ ~% f.e c:_t!.y~~.~~t i.~':!.!.s h in 9,~~ n t :....5 00 l_~ i r~ ~xp 0 s ~.<l._~1} £ f a_c_e sand pro t e c too __, ___£~r_so.~n~l with w_ate,rspr.:.~. UNUSUAL F'RE AND EXPl..OSION HAZAROS - - -_. _.A~spirat£EJL~~~c~ion reauired for fire~~tinS-£~rsonnel. .--. ---. -----.-. ¡:¡Á.!.A R-öOü-Š-PiiõõuèfSoFCõMš"us T ION Carbon monoxide, carbon dioxide, smoke I fumes I aromatic volatiles. ~.---...- _. .- ---. ..-- ... .- , .. -. --- .- -- ..-'- _. THIS 1NF0RMAnON RELATëS ONLY TO THE SPECIFIC MATERiAl CESIGNATëD AND Io,tAV NOT BE VAUD FOR SUCH MATERIAl USED IN COMBINATION WITH ANY OTWER MATERIALS OR IN ANY PROCESS. SUch int0tm81JOn .. 10 tn. best 01 8C ClIencaIs IUIOwlecl(. WIG Þ«IIieI, ecc;g'8t. ..1d rellaDle u 011118 _. ØlCllCated. HOWEVER. NO REPRESENTATION, WARRANTY OR GUARAN'E~ IS MADé AS TO ITS ACCURACY. REUABIUTY OR COMPLETENESS. IT '5 THE U5e¡:;'5, AESPONSlBlUrf TO SATISFY HIMSELF AS TO THE SUITABLENESS A'\:t COMPLETENESS 01' SUCH INFORMAnON FOR HIS OWN PARnCULAR us.. 30 RESINS (Bulk or 50 gal bbls.) Oil T'''' .IAII ....11 'IICOII"" "IAT 'UXURAl PlUUIIAl TlNlll MINUT.. nO'"ER" 'IME ,,, '"IXO'ROPlC 'ARCOL DUlEC liON "RENO'H MODULU' ITAENO'" IlONGUION 'RODUCT "".. 'ROMOTEO ,,, f M'HUn. CPS INOU HARONUS n....ERA TUllE PSI )110' PSI PSI "- COMMENTS GENERAL PURPOSE LAMINA "NO RESINS All... 083, II RIgod V.. 1,11 310,380 18,24 400800 21,38 38·44 no 14.000 48 1,800 I 1 Modera.. cur.. 'ast wen.ng '.SoIOS With ..colen' dra.n '."$ltInCe All... 083·14 RIQicI V.. 12·18 310·380 21·31 400,800 21,38 38.44 ISO 14.000 48 1,000 I 1 .... 083'18 RIQicI V.. \1,21 310·380 30,35 400·600 21·3.8 38'44 ISO 14,000 41 1.800 11 All... 298·9 RIQicI Ye. 1·1\ 330·400 18·20 400,800 21·38 41).44 185 18.000 50 8.500 I 1 F..\.. CU""'II, genet" ""'110M _long In.n ~ ... 063 _... All... 1111·14 fltgid v.. 12·18 330·400 22·21 400·000 2.1·30 40,44 105 18.000 50 8,500 I 1 All... 298·111 RIQicI V.. \1·21 330·400 30,35 400·000 21·30 40·44 105 18,000 50 8,500 11 All... 158·13 RIQicI V.. 11·15 330·400 :l:l,:l8 400·800 2.1·38 40,44 185 18.000 SO 8,500 11 _.,. gel _ ...11> OOCI __sa dev_' RESINS FOR USE IN ALUMINUM HYDRATE AND 'IITROF1l flUID SYSTEMS Very ,...alMat to eJrAAn when 'iUed. g.vel good cur. All... 0110 SemoRogocI v.. 0,10 330,390 12'18 100·130 11'2 I 3341 NJA HIA· Flied WIATH _ __sa dhelOØmen' All... 31 5 SemoRogocI V.. 8·10 330·390 11·10 100·\30 I 1·2 I 34'44 HIA NJA· Flied WIATH Faslll c.n>g _ooon 01 Alleh 098 RESINI FOR IYNTHETIC MARBlE + ONYX 1 All... 035 RIQicI V.. 8·12 285·310 11,24 100,IlOO HIA 30·44 150 12,500 50 8,400 12 Topo, flail, modeI.l. gel, moO,,,... c.... I I .... 141 RIQicI V.. 1·11 :l85·310 \1·22 IlOO·1100 HIA 38·44 ISO 12,500 50 8.400 12 Topo, nota and...... ""eg_, ,.., gel CUI. 11\<1 0em0kI I ) AIIek 200 RIQicI V.. 9·13 215·305 '8,24 '300, \100 HIA 31·42 'SO Topa, oncew" _.......,..~ Ihen All... 035 ) \2,500 SO 8,400 12 All... 291 6emoR1QicI V.. 14,18 260290 3034 9110,11 110 HIA 34·39 110 11,000 SO 6,000 22 Good ....Ibokly 101","",,1",,"""'11 II'oIn ß\IIt)II _II All... 318 R1goc1 Vn 11·18 310·340 25·35 IOSQ·1250 NJA 38,48 185 18,000 SO 1.500 11 b,"'''' GQIOf·lecomm._ 101 hoQII ~Iy any. appIocahonl"14'1 _ onlegtMs, llØod cJemoIØ . AII.k 333 RIQicI V.. lI,g 310,340 '0'18 gOO, \100 HIA 31,48 185 '8,000 50 1,500 I 1 'opallld nail ·1.., geI_,.... All... 334 RIQicI V.. 11·12 285,310 111,24 21100,3400 HIA 38,44 150 12,500 SO 11,400 12 fau.mely hogII "SCOSlly 101 roøl IIId II.'. _... 01" modera.. cur. eahaDlla to... aN...agre RESINS fOR CLEAR CASTING AND DECORAT'V£ USES 11,500 17 fllcelen' COkW. recommended 101 ele., CAI'tng Of All... 331 R1god V.. 11·111 315,335 30,311 400,000 HIA 38·48 1115 111,000 SO decor.C.". apøl.ubOnl. n'tIOdefa.e get mQØef.'~ cOle ISOPHTHALIC RESINS All... 108G SemoR9CI 11,15 380,420 21·21 400'800 24,32 30,34 210 17000 40 10,000 38 MOd.r.'. COrrO"on r......nc.. ..n'Þlhng hIgh Vea ~I"'" Sept.<: ..... .,....y.. '-1 _I_I All... 284 RIQicI V.. 11·15 400·425 2.,21 400,800 24·32 30·42 220 16000 SO 7,000 \ 8 Modefat. c.orfO$O\ t:~Stanc.. modef". etor;. ¡ hogheI...., delleC:hon lemøeJ.'",e .....010< 4)110.. '-". \0 AIIek 16eG AII.k 338 R.god V.I 11·15 400·425 l'\ 21 400,600 24·32 Good COI'O""", .."Slance gooo ...., Oellechon '_'.1.... TRAOEMAIIII AI)ha R...... e e SECTION V· HEALTti HAZARD DATA T...."ES....OL.O L.IMIT VAL.UE UNKNOWN L4quÀd 4šr1t~tin§ dO gkin Gn~heye~.and resPiratorï ªaËs~ges. EFFECTS OF OVEREXPOSURE ACUTE ay e a sor t! t roug e s 1n. Vapors may r 1 a eyes. 1?rol~n~ed skin contact may cause dermatitis and skin CHRONIC 1rr1 a 10n. EMERGENCY AND FIRST AID PROCEOUAtS artificial Remove to fresh air. I not breathing I apply respiration and CALL A PHYSICIAN. Wash eyes with plenty of water for at least 15 minutes. Wash skin with soap and water., SECTION VI· REACTIVITY DATA STA81UTV CONOITIONS TC\ AVOID UNSTA3LE Applicable X Not STABLE INCOMPATl81L.ITY 'MATERIAL..$ TO AVOID FOR PURPOSES OF TRANSPORT, HANOL.ING . STORAGE ONLY) Strong oxidizing agents and mineral acids. HAoZAROOUS DECOMPOSITION PRODUCTS Not Applicable SECTIQN VII· SPILL OR LEAK PROCEDURES sTtéêpo ~fi.l:ÿE"t'~8t'às1rt!l!1~ê': IS~WS~ ~l:Hr¥èe I if possible to do so safely. Advise authorities if substance has entered a watercourse I sewer, or has contamin- . ated soil or vegetation. We~TJ f~r~SA~ ~ ï$fJ:f~ á0r-rf&~'I! w~l~c~ëÆ~O?A~ ~i~j"o~~'d ---.--- dilute with water. Recover by pumping or with suitable absorbent. Consult an expert on disposal of recover- ed material. f . SECTION VIII· PERSONAL PROiECTlON 1~·FORMATlON fR~~~At~õšn~~R~NI~p~ð~gd1Qe~~~rã~ÕryS~~gf.êc~fog sachP~~rarr-snpp 1e mas i..Øë:AI. ~t;1AUST .- h 6 0 f h d fšPËëïAL. t ace ve 0 c 4 y ~ n con Frov~ae greater t an pm 00 I spaces. VE"iTlLATION MECHA¡NICA1. (G~"~ra'¡ .' ~ Expios10n-proof vent11at10n~~~~~~~ "'-Ãõï'iiëTïvE~CQvF.:S -. ---"JE:a: PRoiËCTiON --_. --,---" . .<:.~.:..~ic,~llY resis~~~:_~loV~...,_ '\,;n:...n:~~_ splash gog!Jles UTH£q PROTECTIVE EQUIPMENT -,-- U sua 11 y n<?~_"-eeded ----------- --- [----- SECTION I~-.-~~~-~~AGE PRE~AUTIONS - (R'E-CAüTïoÑ$TÕ"ãËTÃï:¿ËÑÏÑHÁÑõL:ING ANO STORINcObserve hazarã preè'ãütTiJñS-w 1 tñ'-ëiñpf ieãCõñ--= ..t:ai~s. Keep contC:~.E.=.~__clos:..~__whe~..~~~!~._,::.:..:_.~:..e!:_..~~~~ frOl~_ heat, spark.:> and open flames. ÖT."n:R PR£CAU'i-ÍÕÑS--- .-.----..-----.- --. .---- .---.---. --.-------- .--- oÁTt. OF·;~Ë-· "--.- ---.--. . J<.~e.E... .ª'~..ë!~L_;_~.h_e.~~,!. sparl<~~nd ~~_.É.!~.=...:_____..__._ _.__ ._..____._ -- ~ J .. /7 " 7;;;,--:---..- APPRovED 8Y~T':':"- . ~._.__._._-_......- TITLE,: Director 0 Industrial Hygien~ rì , NEW []REV'SED: SUPERSEDES --. ---- ~-- .--.. .....-..~.. 31 lliill This document has been prepared as a guidance and procedura 1 document for the sole use of EMCON employees during on-site remedial action activities. Other site personnel are advised to adopt their own, or similar, safety plan in accordance with applicable federal regulations. Harry Van Den Berg Project Engineer Rev i ewed & Approved., /..--- /.,/; , ~ ....-. ß-·-· -/',' ¿:/ ·~./f__.2:f J ¿;'t:J:'/ Patrick Lacey :// Health and Safety Officer Prepared By A.·I·J ¡-; r -/ II ( ~ . , . ,~' ,¡\ ;ì() c/ ¡ ¡; ~ ,y.,' :' .\.1,-"-7"""/'" ,,1'/..;"" ~"'-;'/ ,> ~/,. emcon Rssociates TABLE OF CONTENTS ~ 1.0 INTRODUCTION 1 1.1 General 1 1.2 Project Overview 2 1.3 Key Personnel and Assignments 5 1. 3.1 Key Personnel 5 1. 3.2 Assignments 5 2.0 MEDICAL SURVEIllANCE 6 2.1 Base-line Health Monitoring 6 2.2 Emergency Medical Treatment 7 3.0 SITE ACCESS 7 4.0 EMPLOYEE AND VISITOR INFORMATION 8 5.0 PERSONAL PROTECTIVE EQUIPMENT 13 5.1 Introduction 13 5.2 Identification of levels of Protection 15 6.0 WORK ZONES AND DECONTAMINATION PROCEDURES 15 6.1 General 15 6.2 Field Operations Work Areas 16 6.2.1 Exclusion Zone 16 6.2.2 Temporary Procedures 18 6.3 Decontamination Procedures 19 6.3.1 Introduction 19 6.3.2 Decontamination Solution 21 emcon Associates TABLE OF CONTENTS (Cont.) £ue 7.0 EMERGENCY RESPONSE PLAN 21 7.1 Site Emergency Warning Systems 21 7.2 Emergency Equipment 22 7.3 General Emergency Procedures 23 7.4 Personal Injury 24 7.5 Ambient Monitoring Contingencies 24 8.0 RECORDKEEPING 26 8.1 General 26 8.2 Medical Records 26 9.0 TRAINING 26 FiÇlures Figure 1 - Site Location Figure 2 - Schematic of Site Tables Table 1 - ACGIH Heat Exposure Threshold Limit Values Table 2 - Modification of Threshold WGBT Table 3 - Phase I Levels of Protection Appendices Appendix A - B.C. Chemicals' Product List Appendix B - Levels of Protection emcon Rssociates oject No. A45-01.01 B.C. CHEMICAL COMPANY SITE HEALTH AND SAFETY PLAN 1.0 INTRODUCTION 1.1 General The purpose of this Site Health and Safety Plan is to present recommendations for minimum procedural and equipment require- ments for worker protection during the above grade clean-up of the former B.C. Chemicals Company site, located at 1511 South Union Avenue in Bakersfield, California (see Figure 1). The above-grade remediation will be performed by M.P. Vacuum Truck Service (M.P. Vacuum) of Bakersfield, California, who shall be responsible for the safe execution of the work at the site. M.P. Vacuum is under contract with Phoenix Trust/Wells Fargo Bank, represented by Mr. Scott Baker from Kuhs & Parker Law Offices in Bakersfield, California. During the field work a representative of EMCON Associates (EMCON) shall be present at the site on behalf of Phoenix Trust/Well s Fargo Bank to observe and document the above- grade remedial action activities. The field work at the site shall be performed in accordance with the regulatory requirements and recommendations of: . 29 Code of Federal Regulations (CFR) Parts 1900 to 1910. 1 emcon Associates oject No. A45-01.01 . Kern County Health Department Hazardous Substances Management Program (Richard Casagrande, Program Manager) Phone: (805)861-3636 . State of California Department of Health Services (Jerome R. Marcotte, Waste Management Engineer) 1.2 Proiect Overview A schematic plot plan of the former B.C. Chemicals Company Site is shown in Figure 2). The project site contains an estimated 6,000-7,000 drums and chemi ca 1 containers. These drums are in vari ous conditions, ranging from full to empty, some are clearly labeled while others are not, and some are physically intact whil e others are damaged. In addit i on to the drums, the site has several 1 arge storage tanks, and some chemical processing equipment. At various locations at the site, there is evidence of spills (discolored soils), and some spills may have migrated a short distance off site. I n add it i on to chemi ca 1 conta i ners , the site has two buildings. One is a small open sided structure formerly used as a diesel engine repair shop. The other is a warehouse, and contains unopened packages of chemicals, most of which are in a re-useable form. B.C. Chemicals handled a wide range of materials. Appendix A gives their product list, together with some relevant Materials Safety Data Sheets. It should be assumed that any, and all, of the listed chemicals may be encountered on site. 2 emcon Associates ~NDA~D RD ',' ..._- 'DISTRICT BOUNDARY =RIL ._::::=K.,~.=.. . ~-/ ..." .... :;:-;.,. - - ... ..' : " ....-.;::- - -""....., r'I"'" " ,. " :1 Q: , N -~~r - - Li . î~ 5i! . ~ ~....- ~.~¡ - . IQ-.- . ~ jiB21 '- :.-~ - __ I!œ[DALE -. ..,;:j I"~ _, f... -, " :C~'~ .-' -' ~: ,~,~-. f..._,.. " ROAD !:" í~14i~ . ::::::: ;.:."...,...... ,.' ,':': . '.:~ :;'.:~;..: :,:;.: ":: :.: :.:;,:";. :....:. ... .: : ,.. L' ".'..:·L ..}.: ,.'.L"i".'. .....::\ :}',:-:,:.:~:;:. ... ", ....-. .., ',,;'::' ..-', .... . ...: . : ':.~' .: .-...--. ·"O"'· . ~~S,.R 27E, Q Z ·':"v-;:~--- .,.~~-- .,...,.~....- .......,.'"..u-~_"'u·__· ~~~.. -- _....-..~: - -~~.. ~ ~ ~. nos.·::,:' ~ ,..=~,__~=:, :~,!A"~-,-u, ,. I '. ,I' Scale: 1,= 6000' LANE .. ~ ,~ :.:"'-: ::-=.==: .,..~:- -- - : 'í" I .. _.__.L.." _. t ! _r_·~!lY'IiI. - .....' I oI.~." +- iiL:; \\', !~ : ~Ii! , ~ ..-..£~/IRII _ ..__ _ .dL""'-_ "--~'- il '-.1 \1 . :: .. .--. -, ....' emcon Associates PHOENIX TRUST/WELLS FARGO SITE SAFETY PLAN B C CHEMICALS SITE BAKERSFIELD, CALIFORNIA sin LOCATION MAP FI.URE e BANK I ......tICT NO. A45- 01. 01 oject No. A45-01.01 The project is expected to comprise the following phases: Phase I: Sale of useable chemicals, return of some drums to their original supplier, and crushing and disposal of empty drums. Phase II: Segregation of remalnlng drums, identification or characterization of material remaining in drums, development of disposal options, followed by final disposal activities. Phase II I: Initiation of a hydrogeological investigation to assess environmental damage and soil and water con- tamination. This phase will be concurrent with Phase I I, and may 1 ead to the preparat i on of a Remedial Action Plan (RAP). Phase IV: Execution of the RAP. The work out 1 i ned in Phase I was executed between Apri 1 and June, 1986. 4 emcon Associates oject No. A45-01.01 1.3 Kev Personnel and Assignments 1.3.1 Key Personnel The M.P. Vacuum representatives responsible for the development and implementation of task-specific health and safety procedures during work at the site are: Mr. Clint Bolender Project Manager Safety Coordinator Mr. Thomas Pruitt One of the following EMCON employees will be at the site on behalf of Phoenix Trust/Wells Fargo Bank to observe and document the above-grade remediation activities, including health and safety procedures: Mr. Bob Wil son Mr. Chri s Scott Safety Observer Safety Observer The EMCON field personnel will be supported by the following office personnel: Mr. Patrick Lacey Project Engineer EMCON, Burbank Health and Safety Offi cer EMCON, San Jose Mr. Harry Van Den Berg 1.3.2 Assignments The M.P. Vacuum Project Manager and Safety Coordinator will be responsible for field implementation of the Health and Safety Plan. This will include field super- vision, enforcing safe work practices and ensuring the use of protective equipment, and communicating modified site safety requirements to all site personnel. 5 emcon Associates ject No. A45-01.01 The M.P. Vacuum Safety Coordinator is responsible for coordination of the Health and Safety Plan. His duties include but are not limited to: conducting routine safety inspections to identify and correct any unsafe conditions; conducting air monitoring; conducting site safety training sessions and crew briefings; selecting the appropriate protection levels for specific opera- tions; and site safety recordkeeping. EMCON's Safety Observer will be at the site on behalf of Phoeni x Trust/Well s Fargo Bank to observe and document the implementation of the Site Health and Safety Plan by M.P. Vacuum. If in his opinion unsafe practices were to occur at the site he will request M.P. Vacuum'to halt the work and remedy the situation. If the situation is not corrected properly he will report this, after consulting EMCON's Safety Director or Project Engineer to Mr. Scott Baker of Kuhs & Parker (Phone No.(805)322-4004) and Mr. Richard Casagrande of the Kern County Health Department (Phone No. (805)861-3636). 2.0 MEDICAL SURVEILLANCE 2.1 Base-line Health Monitoring All EMCON field personnel have successfully completed a preplacement or periodic/update medical examination prior to their assignment to the project. The medical examination consisted of an occupational and medical history, physical examination, vision testing, audiometry, and the following biological screening: 1. Chest x-ray. 6 emcon Rssociates oject No. A45-01.0l 2. Complete blood count (CBC) with differential and hematocrit. 3. Urinalysis - microscopic. 4. Spirometry - lung function testing, including rEVl, and FVC. 5. Blood chemistry screen - SMAC series. 6. Serum heavy metals. 7. Serum cholinesterase levels. All other personnel visiting the site should consider the advisability of a similar base-line medical examination. 2.2 EmergenCY Medical Treatment In the event of an employee lnJury or illness requlr1ng emergency medical care beyond the first-aid trained personnel, the following resources will be utilized as appropriate: Bakersfield City Police California Highway Patrol Kern County Fire Department Kern County Sheriff Department Hall's Ambulance Mercy Hospital 3.0 SITE ACCESS (805) 327 -7111 (805)327-1069 (805)324-6551 (805)327-3392 (805)327 -4111 (805)327-3371 All gates at the project site are to be kept locked, unless work activity requires them to be open. The project site is secured by a 6-foot chain link fence, which must be maintained intact. 7 emcon Rssociates oject No. A45-01.01 Access to the site shall be arranged through: Mr. Scott Baker Kuhs & Parker 1200 Truxton Avenue, Suite 200 Bakersfield, California 93301 Phone No. (805)322-4004 Access shall be restricted to authorized individuals only. All visitors to the site must be accompanied. It is expressly recommended not to enter the site alone. 4.0 EMPLOYEE AND VISITOR INFORMATION · Personnel should be cautioned to inform each other of subject i ve symptoms of chern; ca 1 exposure such as headaches, dizziness, nausea, and irritation of the respiratory tract, eyes, or skin. · No excessive facial hair, which interferes with a satisfactory fit of the mask-to-face seal, will be allowed on personnel required to wear respiratory protective equipment. · All respiratory protection selection, use, and maintenance shall meet the requirements of established procedures, 29 CFR 1910.134, and recognized consensus standards (AIHA, ANSI, NIOSH) . · Heat Stress Control: Adverse climatic conditions, heat and cold, are important considerations in planning and conducting site operations. The effects of ambient temperature can cause physical 8 emcon Associates oject No. A4S-01.01 discomfort, loss of efficiency, personal lnJury, and increased accident probability. In particular, heat stress due to protective clothing decreasing body ventilation is an important factor (see Table 2). One or more of the following recommendat ions wi 11 help reduce heat stress. Thei r applicability is dependent on evaluating the climatic conditions specific to the operations. · Provide plenty of liquids to replace lost body fluids. Employees should replace water and salts lost from sweating. Use either a 0.1% salt water solution, more heavily salted foods, or commercial mixes such as Gatorade. The commercial mixes may be preferable for employees on low sodium diets. · Establish a work schedule that will provide sufficient rest periods for cooling down. This may require shifts of workers when wearing suits and SCBA (See Table 1). · Cooling devices, such as vortex coolers and cool vests, may be worn under suits. · Establish work regimes consistent with the ACGIH Guidelines given in Table 1, with consideration given to the recommended modifications of the WBGT Index as provided in Table 2. · To assist in determining the body's recuperative ability to excessive heat, one or more of the following monitoring techniques should be used as a screening mechanism for deter- mlnlng recovery. Monitoring of personnel should commence at least when the ambient temperature at any time during the day is 75°F or above. Frequency of monitoring should increase as the ambient temperature increases or as monitoring indicates slow recovery rates (after every work period above 85°). 9 emcon Rssociates oject No. A45-01.01 a. Heart Rate (HR) shoul d be measured by the radi a 1 pul se during 30 seconds as early as possible in the resting period. The HR at the beginning of the rest period should not exceed 110 beats per minute. If the HR is in excess of the above value, the next work peri od shoul d be shortened by 10 minute (or 33 percent) while the length of the rest period stays the same. If the pulse rate is in excess of 110 beats per minute at the beginning of the next rest period, the following work cycle should be further shortened by 33 percent. b. Body Temperature (BT) shoul d be measured orally wi th a clinical thermometer as early as possible in the resting period. Oral temperature (OT) at beginning of the rest period should not exceed 99.7°F (corresponding to 100.4°F BT). If OT exceeds 99.7°F, the next work period should be shortened by 10 minutes (or 33 percent) while the length of the rest period stays the same. However, if the OT is in excess of 99.7°F at the beginning of the next rest period, the following work cycle should be further shortened by 33 percent. OT should be measured again at the end of the rest period to make sure that OT decreased below 99.7°F. 10 emcon Associates e 4Ijoject No. A45-01.01 TABLE 1 ACGIH HEAT EXPOSURE THRESHOLD LIMIT VALUES* WBGT INDEX WORK LOAD WORK-REST REGIMEN LIGHT MODERATE HEAVY C F C F C F Continuous Work 30.0 86 26.7 80 25.0 77 75% Work - 25% Rest, Each Hour 30.6 B7 28.0 82 25.9 79 50% Work - 50% Rest, Each Hour 31.4 88 29.4 85 27.9 82 25% Work - 75% Rest, Each Hour 32.2 90 31.1 88 30.0 86 * Higher heat exposures than shown are permissible if the workers have been undergoing medical surveillance and it has been established that they are more tolerant to working in heat than the average worker. 11 e 4jþject No. A45-01.01 TABLE 2 MODIFICATION OF THRESHOLD WGBT2 MODIFICATIONS3 FACTORS WGBT (0C) WCBT (OF) 1. Unacclimatized/not physically fit -2 -4 2. Ai r velocity: Velocity above 1.5 mps (300 fpm) and air temperature below 35 C (95°F) +2 +4 3. Clothing: Shorts, semi-nude armor1 +2 +4 Impermeable jacket or bodr -2 -4 Raincoats, fireman's coatI -4 -7 Completely enclosed suits -5 -9 4. Obese/elderly -1 to -2 -2 to -4 5. Female -1 -2 1 Modification for increased air velocity not appropriate with imper- vious clothing. 2 Add or subtract value from WGBT Index Values, Table 1. 3 From Ramsey, J.D.: "Abbreviated Guidelines for Heat Stress Exposure". American Industrial HV9iene Journal 39:491:495 (1978). 12 P 'ect No. A45-01.01 c. Body Water Loss (BWL) due to sweat i ng duri ng the work day should be measured by the difference between body weight in the morning before work and body weight in the evening after finishing work. The clothing worn should be similar to both weighingsj preferably the worker should be nude. The scale should be accurate to ± 1/2 pound. BWL should not exceed 1.5 percent of total body weight. If BWL exceeds 1.5 percent, the worker should be instructed to increase his daily intake of fluids by the amount of total deficit (morning body weight minus evening body weight). 5.0 PERSONAL PROTECTIVE EQUIPMENT 5.1 Introduction It is important that personal protective equipment and safety requirements be appropriate to protect against the potential hazards at the site. Protective equipment will be selected based on the contaminant type(s), concentration(s), and routes of entry. In situations where the type of materials and possibilities of contact are unknown or the hazards are not clearly identifiable, a more subjective determination must be made of the personal protective equipment for initial safety. The appropriate level of protection shall be determined prior to the initial entry on-site based on best available informa- tion. Subsequent information may suggest changes in the original level selected. Descriptions of basic levels of protection are given in Appendix II. I 13 emcon Rssociates e 4iÞject No. A45-01.01 TABLE 3 PHASE II RECOMMENDED LEVELS OF PROTECTION (See Appendix II) Act i vity Level of Protection Modifi cat ions Walk through inspections Level D Handling undamaged chemical supplies Level D Handling empty drums have Level C Sampling & field testing contents of drums Level B Sampling soils Level C Handling of damaged chemical supplies Level B Street clothes with disposable plastic over-shoe is an a lternat i ve Hard hats and gloves needed Face mask to organic vapor and acid gas cartridge 14 oject No. A45-01.01 5.2 Identification of Levels of Protection Table 3.0 identifies the levels of protection recommended for activities expected to be performed during Phase II of this project. Subsequent phases may require different safety procedures and these will be identified later. 6.0 WORK ZONES AND DECONTAMINATION PROCEDURES 6.1 General A site must be controlled to reduce the possibility of exposure to any contami nants present and thei r transport by personnel or equipment from the site. A control system is requi red to assure that personnel and equipment working on the hazardous waste site are subject to appropriate health and safety surveillance. The possibility of exposure or translocation of contaminants can be reduced or eliminated in a number of ways, including: · Setting up security or physical barriers to exclude unnecessary personnel from the general area. · Minimizing the number of personnel and equipment on site consistent with effective operations. · Establishing work zones within the site. · Establ i shing control points to regul ate access to work zones. 15 emcon Associates oject No. A45-01.01 · Conducting operations in a manner to reduce the exposure of personnel and equipment. · Minimizing the airborne dispersion of contaminant(s). · Implementing appropriate decontamination procedures. As work proceeds on this project the Project Manager and/or the Safety Coordinator shall make any necessary decisions, or changes in procedures. 6.2 Field Operations Work Areas 6.2.1 Exclusion Zone Work areas (zones) shall be established based on anticipated contamination. Within these prescribed zones, operations shall occur utilizing appropriate persona 1 protective equi pment. Movement between areas shall be controlled at check-points. The future planned zones are: · Exclusion Area (contaminated) · Contamination Reduction Area and · Support Area (non-contaminated) 16 emcon Associotes Project No. A45-01.01 The Safety Coordinator shall establish these zones prior to the commencement of Phase II activities, using the following guidelines: 1. Exclusion Area The Exclusion area is the innermost area of three concentric rings and is considered contaminated, dirty or "hot". Within this area, prescribed protection must be worn by any entering personnel. An entry checkpoi nt shall be establ i shed by the Safety Coordi nator at the peri phery of the Exclusion Area to control the flow of personnel and equipment between contiguous zones and to ascertain that the procedures established to enter and exit the zones are followed. The Exclusion Area boundary shall be established initially based on the presence of the actual wastes or hazardous materials within the area. Subsequent to initial entry and as clean-up proceeds, the boundary shall be readjusted based on observations and/or measurements. The boundary shall be physically secure and posted. 2. Contamination Reduction Area Between the Exclusion Area and the Support Area is the Contami nat ion Reduct i on Area. The purpose of thi s zone is to provide an area to prevent or reduce the transfer of contaminants which may have been picked up by personnel or equipment returning from the exclusion area. All decontamination activities shall occur in this area. 17 emcon Associates ject No. A45-01.01 The boundary between the Support Area and the Contamination Reduction Area is the contamination control line. This boundary separates the possibly-contaminated area from the clean lone. Entry into the Contamination Reduction Area from the Clean Area must be through an access control point. Personnel entering at this station shall be wearing the prescribed personal protective equipment for working in the Contamination Reduction Area. Exiting the Contamination Reduction Area to the clean area requires the removal of any suspected, or known, contaminated persona 1 protect i ve equi pment and comp 1 i ance with decontamination procedures. At the boundary between the Contami nat i on Reduct i on Area and the Exclusion Area is the hot line and access control station. 3. Support Area The support Area is the outermost of three ri ngs and is considered a non-contaminated or clean area. It contains the Command Post (CP) for field operations and other elements necessary to support site activities. Normal street clothes or Level 0 work clothes are usually the appropriate apparel within this lone. 6.2.2 Temporary Procedures Figure 2 identifies the area adjacent to the entrance and the office as the support area. Individuals, equipment and vehicles that only enter this area will be considered free from contamination and need not undergo decontamination procedures. The assumption that this 18 emcon Rssociates Project No. A45-01.01 the on-5 He equipment will only 1 eave the contaminated area at the end of the project. 6.3 Decontamination Procedures 6.3.1 Introduction As part of the system to prevent or reduce the physical transfer of contaminants by people and/or equipment from on-s ite, procedures shall be i nst ituted for decontam- inating anything leaving the site. These procedures include the decontamination of personnel, protective equipment, monitoring equipment, clean-up equipment, etc. Unless otherwise demonstrated, everything leaving the site should be considered contaminated and appropriate methods established for decontamination. In general, decontamination at the site consists of rinsing equipment, personnel, etc., with copious amounts of water and washing same with detergent/water solution. If contaminants are known, then a specific detergent and/or solvent can be used to decontaminate. High pressure steam cleaning can also be an effective decontamination method in some instances. Disposable protective clothing sha-ll be placed in on-site drums for ultimate disposal at a Class I landfill. All decontamination washes and rinses must be contained so that they too can be properly disposed of. emcon Associates ~ -N- ~ 1&1 > - 0: Q en z 1&1 ..J ..J c( 1&1 ::;) Z 1&1 ~ Z o - z ::;) PHOENIX DRI VE Approximate lea'e: ,": 200' FIGURE e~s~~~~ ' PHOENIX TRUST/ WELLS FARGO BANK SITE SAFETY PLAN B C CHEMICALS SITE BAKERSFIELD, CALIFORNIA SITE MAP 2 PIIOoIlCT ..~ A45 -01.01 Project No. A45-01.01 ~--- 6.3.2 Decontamination Solution Based on U. S. EPA recommendat ions for decontami nat ion procedures, the sol ut i on for the decontami nat i on shall be as follows: For every 10 gallons of water, add 4 pounds of sodium carbonate (soda lime) and 4 pounds of trisodium phosphate, stir until evenly mixed. This solution is designed to react with and neutralize the inorganic acids and to remove the organic hydro- carbons. If contaminants are known then a specific detergent and/or solvent can be used to decontaminate. The decontami nat i on process uses water and ri nse solutions for washing down personnel and equipment. The spent solution, brushes, sponges, containers, stands, etc., used in the decontamination process must, unt i1 shown otherwi se, be cons i dered contami nated and must be properly disposed of. 7.0 EMERGENCY RESPONSE PLAN 7.1 Site Emergencv Warnin9 Systems Several warning systems may be utilized depending on the work site conditions or emergency involved: 1. Verbal communications. 2. Verbal communications assisted with a bull horn. 3. Verbal communications assisted with a site PA system. 21 ---.,..---.-- --. emcon Associates- e e ject No. A45-01.01 9. Litters. 10. Portable two-way radio equipment. (Optimal, perhaps Phase II et.seq.) . 11. Combustible gas and oxygen detector alarm. Auto alarm set at 20% LEL and 19.5% oxygen (OSHA limits). 12. Organic vapor detection instruments - HNU photoionizer detector or Foxboro Analytical (formerly Century Systems) OVA. 13. Inorganic vapor detector tubes and air supply pumps - Draeger and/or MSA. 14. Hand-held compressed gas horns. 15. Bull horns. 16. Appropriate spill cleanup supplies and equipment. 7.3 General Emergency Procedures In case of an emergency or hazardous s ituat ion, the team member that observes this condition shall immediately give the alarm. 1. Upon hearing an alarm, all communications will cease and the member giving the alarm will proceed to give the Project Manager or Safety Coordinator all pertinent information. 2. Actions to be taken will be dictated by the emergency. 3. Power equ i pment wi 11 be shut down and operators wi 11 stand by for instruction. 4. Injured personnel will be processed to the Personnel Decontamination Trailer (PDT). 23 emcon Associates ject No. A45-01.01 5. In case of a fire, explosion or hazard alarm, individuals will proceed immediately to assigned pre-located safe sites. 6. Upon arrival at the safe sites, a complete head count shall be given to the Project Manager and individuals shall stay at the safe site until the area is secured. 7.4 Personal Iniurv If an injury occurs due to an accident or exposure to a hazardous substance, the Project Manager and the Safety \ Coordinator shall be immediately notified. The Safety Coordinator shall be given all appropriate information concerning the nature and cause of the injury so that treatment preparations can be initiated. The Project Manager shall be informed and shall investigate the cause of the injury and make any necessary changes in work procedures. The injured person shall be transported to the hot line where appropriate first aid and treatment can begin. 7.5 Ambient Monitoring Contingencies 1. When any of the following ambient monitoring readings are encountered, the Safety Coordinator and Project Manager should i~nediately shut down the area and return a 11 staff to the contami nat i on reduct i on 1 i ne unt i1 the levels decrease or the cause is identified: a. Combustible vapors in excess of 20 percent LEL. b. Oxygen level below 19.5 percent. c. Organic vapors in excess of 500 ppm. d. Radiation in excess of recorded background levels. e. Hydrogen Sulfide* 300 ppm. 24 emcon Rssociates ject No. A45-01.01 f. Hydrogen Cyanide 50 ppm. g. Hydrochloric Acid 100 ppm. h. Acetic Acid 1,000 ppm. 2. When any of the following ambient monitoring readings are encountered, work shall stop, all power shall be shut down, and the alarm shall be given to evacuate the immediate work area: 1. Combustible vapor in excess of 50 percent LEL. 2. Radiation levels in excess of 2mR/hour. The Safety Coordinator and Project Manager shall be informed. The cause of the conditions shall be determined and changes in work procedures or practices shall be made if appropriate. 3. When ambient monitoring on the downwind edge of the site indicates higher than background levels of any contaminant, the Safety Coordinator and Project Manager shall immediately be requested to determine the cause, make changes to work pract ices or procedures, and if necessary, make changes in site layout (i.e., change the location of the CP, decon area, or Exclusion Area), warn unprotected personnel to evacuate or wear protective equi pment, coordi nate with 1 oca 1 authorit i es to effect off-site evacuation. * See NIOSH/OSHA Pocket Guide to Chemical Hazards 25 em<on Rssociates ject No. A45-0l.0l 8.0 RECORDKEEPING 8.1 General Recordkeeping shall be consistent with OSHA regulations in all respects. The following permanent records shall be maintained by the Safety Coordinator: l. Respiratory Protection Training Records 2. Respirator Assignment Records 3. Respiratory Protection Medical Evaluations 4. Safety Inspection Reports 5. Personnel Exposure Monitoring Records (spiral or bound permanent log books will be used) G. OSHA 200 - Current to within 24 hours 7. Accident reports 8.2 Medical Records Permanent medical records should be maintained in confidential files by the regional contract physician and by each individual's company Health and Safety Manager. 9.0 TRAINING During field operations, safety meetings shall be held as needed by the Safety Coordi nator to revi ew spec ifi c health and safety aspects of scheduled work. 26 emcon Rssociates ject No. A45-01.01 Before beginning the project,training sessions should be conducted for all individUals engaged in field activities. The following safety items and procedures should be discussed: · Emergency procedures and equipment (fire extinguishers, spill control kits, emergency eyewash, and emergency oxygen kit) · Basic first-aid procedures and cardiopulmonary resuscitation · Non-emergency health and safety procedures · Procedures for donning protective equipment · Procedures for decontamination · Consideration of heat stress when wearing protective clothing and procedures for monitoring heat stress · Potential chemical hazards at the site under investigation · OSHA requirements for personal protective equipment · Toxicological concepts and classification schemes · Standards: permissible exposure limits (PELs), threshold limit values (TLVs), and immediately dangerous to life or health (IDLH) concentrations · Personal protective methods: foot, body, hand, eye, ear, and head protection 27 emcon Associates ject No. A45-01.01 · Respiratory protection: respirator factors, chemical cartridge selection 1 imitat ions types, protect ion charts, respi rator · Respiratory use: isoamyl acetate qualitative fit testing, maintenance; cleaning, inspecting, and storing respirators · Medical surveillance requirements: baseline, surveillance, and acute exposure physicals; common laboratory tests and their significance · Air monitoring: capabilities and limitations of Draeger tube detection systems, photoionization detection systems, flame ionization detection systems, and explosimeters · Levels of protection: requirements for levels A, B, C, and D protection · Employee rights and responsibilities In addition, field personnel must receive safety training to comply with OSHA hazardous waste operations training requirements mandated by the Superfund Amendments and Reauthori zat i on Act of 1986. 28 emcon Associates APPENDIX 8 LEVELS OF PROTECTION P 'ect No. A45-01.01 emcon Associates e 4liroject No. A45-01.01 APPENDIX B LEVELS OF PROTECTION I. Leve 1 A Level A protection should be worn when the highest level of respiratory, skin and eye contact protection is needed. Level A provides the maximum available protection but does not protect against all possible airborne or splash hazards. (Level A protec- tive clothing material selected should be based on chemical per- meability and resistivity. For example, suit material may be rapidly permeable to certain chemicals in high concentrations). Level A protection is the minimum level recommended for initial site entri es, unt il the hazards have been defi ned and the appro- priate personal protective equipment is utilized. II . Leve 1 B leve 1 B protect ion should be se 1 ected when the hi ghes t 1 eve 1 of respiratory protection is needed but a lesser level of skin pro- tection is required. II 1. Leve 1 C level C protection should be selected only when the airborne contami nant type (s) and concentrat i on (s) are known; the criteri a for using air-purifying respirators are met; and the exposed skin in the few unprotected areas (i.e., neck and back of head) is unlikely to cause any adverse health effects. 1 e 4ÏÞ0ject No. A45-01.01 IV. Level D Level D is the basic work uniform. Level D protection should only be selected when the work area is positively identified as having no toxic hazards. Level D alone will only be authorized in the Support Area and after contamination is removed. EQUIPMENT AND SELECTION CRITERIA I . Leve 1 A A. Personal Protective Equipment 1. Open circuit positive pressure SCBA (MSHA/NIOSH Approved) . 2. Totally encapsulating suit (boots and gloves attached). 3. Gloves - Inner (tight fitting and chemical-resistant). 4. Boots Chemical-protective, steel toe and shank. Depending on suit boot construction - worn over suit boot. 5. Gloves - Outer, chemical-resistant. Depending on suit construction worn over suit gloves. May be replaced with tight-fitting, chemical resistant gloves worn inside suit gloves. 6. Hard Hat (under suit) (Optional). 7. Disposable protective suit, gloves and boots. (Worn under or over encapsulating suit) (Optional). 8. Coveralls (under suit) (Optional). 9. Underwear - Cotton, long-john type (Optional). 10. Two-way Radio Communications. 2 e 4ÏÞ0ject No. A45-01.01 B. Criteria for Use 1. When the type(s) and concentration(s) of toxic sub- stances are known and require the highest level of combined protection to the respiratory tract, skin and eyes. These conditions would be: a) Atmospheres which are "Immediately Dangerous to LHe and Health" (IOLH). b) Known atmosphere or potential situations that would affect the skin or eyes, or could be absorbed into the body through these surfaces in toxic quant it i es. 1) Potential situations are those where vapors may be generated or splash i ng occur through site activities. 2) Standard reference books should be consulted to obtain concentrations hazardous to skin, eyes or mucous membranes. c) Oxygen deficient atmospheres with above conditions. I I. Level B A. Personal Protective Eauioment: 1. Open circuit positive pressure SCBA (MSHA/NIOSH approved) or type C hoseline pressure/demand respirator with escape unit. 2. Hooded, two-piece chemical-resistant suit. 3. Gloves - Outer, chemical-protective. 4. Gloves - Inner, tight-fitting, chemical-resistant. 5. Boots shank) . Outer (chemical-protective, steel toe and 3 e ,oject No. A45-01.01 6. Two-way radio communications. 7. Hard Hat. 8. Face shield (Optional). B. Criteria for Use 1. When the type(s) and concentration(s) of hazardous substances are known and require the highest degree of respiratory protection; but a lower level of skin protection. a) Atmospheres which are IDLH. Type(s) and concentra- tion(s) of vapors in air do not present a hazard to the small, unprotected areas of the body. b) Atmospheres with concentrations of known substances greater than protection factors associated with full-face, air-purging respirators with appropriate cartridges. c) Atmospheres with less than 19.5 percent oxygen. 2. A determination is made that potential exposure to body parts not protected by a fully encapsulating suit (primarily neck, ears, etc.) is highly unlikely. a) Known absence of cutaneous or percutaneous harmful agents. b) Activities performed preclude splashing of indi- viduals. 3. Total vapor levels range from 5 ppm - 500 ppm on instru- ments such as the photoionizer or Organic Vapor Analyzer 4 · ~oject No. A45-01.01 and do not contain high levels of toxic substances affecting skin or eyes. I I I. Leve 1 C A. Personal Protective Equipment 1. Full - face, approved} . 2. Chemical-resistant clothing. a i r-purifyi ng respirator (MSHA/N IOSH 3. Overalls and long - sleeved jacket or coveralls; hooded two-piece chemical splash suit (when applicable-hooded disposable coveralls) (Optional). 4. Gloves - Outer (chemical-protective) 5. Gloves - Inner (tight-fitting, chemical-resistant type). 6. Cloth Coveralls Fire resistant (inside chemical protective clothing) (Optional). 7. Escape Mask. 8. Hard Hat. 9. Boots - Outer (chemi ca l-protect i ve heavy rubber throw- aways) . 10. Boots shank). Inner (chemical-protective, steel toe and 11. Two-way radio communications. B. Criteria for Use 1. Site known to contain potential hazards not to exceed: a) Air concentrations of material not greater than the protection factor afforded by a full-face mask (normally considered to be 50). Material must have good warning properties. 5 e ~oject No. A45-01.01 b) Body exposure to unprotected areas (face, neck, etc.) non-exi stent or 1 ess than any amount that wi 11 cause harm. c) Well-documented, reliable history of site and patterns of prior entry. d) No evidence of acute or chronic effects to exposed personnel. 2. Total vapor reading between 0 ppm and 5 ppm above background on instruments such as the photoionizer and OVA, and no evidence of airborne contaminants for which the air-purifying respirator would be contra-indicated. 3. Continuous area and personnel monitoring is required while wearing Level C protection. II I. Leve 1 0 A. Personal Protective Equipment I. Boots/shoes - safety or chemical-resistant steel-toe boots. 2. Boots - outer (chemi ca l-protect i ve heavy rubber throw- aways) . 3. Safety glasses or safety goggles. 4. Hard Hat (Optional) (Face shield optional). 5. Gloves (Optional). B. Criteria for Use I. No indication of airborne health hazards present. 6 · 4IÞoject No. A45-01.01 2. No gross indications above background on the photoionizer and/or Organic Vapor analyzer. 3. Continuous area and personnel monitoring is required while wearing Level 0 protection. 7