HomeMy WebLinkAboutMITIGATION (8)
August 24, 1987
--
CRIMINAL DIVISION
Kern Co. Justice Building
I 1215 Truxtun Avenue
Bakersfield, California 93301
(805) 861 ·2421
EDWARD R. JAGELS_
District Attorney
Pat Steele
Deputy County Counsel
Kern County County Counsel IS Office
1415 Truxtun Avenue
Bakersfield, CA 93301
Re: People v, B, C. Chemicals
Dear Pat:
I am enclosing a packet of supplemental laboratory results, which
were apparently not a part of the misdemeanor file and which were
not relied upon by our office in filing our criminal complaint.
Sample 172 pertains to the 4th count of the criminal complaint.
which was dismissed in plea negotiations.
I have reviewed the file for any interpretive reports etc., from
Kern County Health Department, and none are contained therein, As
I indicated to you, there are voluminous laboratory results in the
Kern County Municipal Court's file, These are a matter of public
record and may be requested by counsel for the trust,
Should you have any questions or comments, please contact me,
Sincerely,
EDWARD R. JAGEí~/
Distri,ct At~~ØY), _
( ,} /i\j(' ( f2-
"'-._ /1'. /.:~; '.
By .. -.,-.. ..-" '
-~:~~y~~;::~-~\::::~-----
JGV&'/ /)
cc: Richard Cas1gra~de
K ern C 0 u n t y 'if.e-( 1 thO e par t men t
I .
REMEDIAL INVESTIGATION PLAN
B.C. CHEMICALS SITE
1511 SOUTH UNION AVENUE
BAKERSFIELD, CALIFORNIA 93307
March, 1986
Prepared by
EMCON Associates
445 West Garfield Avenue
Glendale, California 91204
Project: 773-01.01
emcon Associates
TABLE OF CONTENTS
1.0 INTRODUCTION
1.1 Project Overview
1.2 Guidance Documents
2.0 REMEDIAL INVESTIGATION PLAN
2.1 Site Background
2.1.1 Site Maps
2.1.2 Regional Hydrogeology
2.1.3 History of Chemical Usage
2.1.4 Disposal Activities and Spills
2.1.5 Suspected Contamination Areas
2.1.6 Past Remedial Actions
2.2 Quality Control/Quality Assurance Plan
2.2.1 Sampling QA/QC
2.2.2 QA/QC Aspects of Laboratory Analysis
2.3 Health and Safety Plan
2.3.1 Worker Safety
2.3.2 Community Safety
2.4 Community Relations and Notification
2.5 Sampling Plan
2.5.1 Surface Sampling
2.5.1.1 Dirt Piles
2.5.1.2 Stained Surface Areas
2.5.2 Soil Sampling Program
2.5.3 Ground-Water Sampling
2.5.4 Drum Sampling
Page
1
1
4
5
5
5
8
8
9
9
9
10
10
10
12
12
12
13
14
14
14
18
18
20
26
emcon Associates
TABLE OF CONTENTS (Cont.)
2.5.5 Surface Water Run-off
31
2.5.6 Air Quality
2.6 Schedule
31
32
Figures
Figure 1 - Site Location Map
Figure 2 - Site Map
Figure 3 - Schematic Plot Plan
Figure 4 - Preliminary Environmental Assessment
Figure 5 - Ground-Water Movement
Figure 6 - Water Wells
Figure 7 - Well Details
Figure 8 - Remedial Investigation Schedule
2
6
7
15
21
22
24
33
Tables
Table 1 - Recommended and Required Sampling and
Analytical Methods CAC, Title 22, Article 11 11
Table 2 - Summary of Field Soil and Water Sampling Plan 27
Table 3 - Preliminary Drum Inventory 28
Table 4 - Drum Profiling 30
Appendices
Appendix A - B.C. Chemicals' Product List
Appendix B - DOHS RI Workp1an Outline
Appendix C - Ground Water Sampling Protocol
emcon Rssociates
B.C. CHEMICAL COMPANY SITE
REMEDIAL INVESTIGATION PLAN
1.0 INTRODUCTION
1.1 Project Overview
The project site is located at 1511 S. Union Avenue, Bakers-
field, California (see Figure 1), and contains an estimated
6,000 drums and chemical containers. These drums are in
various conditions, ranging from full to empty, some are
clearly labeled while others are not, and some are physically
intact while others are damaged. In addition to the drums,
the si te has several 1 arge storage tanks, and some chemi ca 1
processing equipment.
At various locations at the site there is evidence of spills
(discolored soils), and some spills may have migrated a short
distance off site.
In addition to chemical containers, the site has three build-
ings. One is a small open sided structure formerly used as a
diesel engine repair shop. The others are warehouses, and
contain unopened packages of chemicals, some of which are in a
re-useab 1 e form.
B.C. Chemicals handled a wide range of materials. Appendix A
gives their product list, together with some relevant Mater-
ials Safety Data Sheets.
1
emcon Rssociates
-..iI.ANOARO RD. '>. .
-. -,----
'I
:1
:1
:1 RO,
I
y
?DISTRlCT
BOUNDARY
.....-=.".=-
"--
,--:-'':- .:;.' '- ::;:.;-
-ð'~"''''Dr
'''~
-=
:':';.';::,:'..:::':.,:-::: ,...
.. ~ ::, '.'. .:::".,.-::;.,-<,:;. .::' :..:::..-....:..,' :
}~::.\>:::..:)(.. "'. ~:-: ;"
."" """"':~ :"t'"',:,",'
:.:;}:::.::,;.;:;::::,. \.<:.::':!';/~\~.'/::::'>
:'.. -.:.,:..::':::',:.:::
:'i:,'\H::'!'"
.......;::
..
:·;:.=;::Ú·:·
':':'.::.'
....:...~. :0
: '" ;:~ "".' .
....:..
,.....
--,,-.
.;....
...:....
.':..'
........
.. ~:..':...
.' :.,::.....:--
'p~~. ""
:': ..~~:
!
,;
"
r·..··
'.-..'..:":" .";'.:.."'"
;_.....,."......,..,......-.'
.......-....,..-:"::..:.....
'. ";""::''';':'':''
....' .' ....
"~O' ..
..'
....:--. .
'- .'-=- ~
.
.-:-.=;;p--.==,
~~:-~~~~~:.
',::,.-.,.-'''''"-'''' _.
o
c:¡
~
, ¡ 30S. R 2eE,
-3~S..R 27E.
o
J::
,.:...:......
"
'-'-."
-
';
.. ~---~.-
'" ,:,,:1:~~
~-~r;-'
",--r-.; ~:
I
I
I
I.
Ilf= 6000'
~ ,,'-_.. -- -,
'\ !I!
,I
..,~'.-._--
~ !¿/
~ .
~-,\-
~
___~:::_-:-~u_-ª
::.=.~:~_:=.=-~ :::-=.=:
t
._-==:._~~~~:. _-=._ ~~~J. _. ';____
'='~-'_!--
\0.1'1 ....
ã5 .~';:., =....;:r--=_.---== ==;
~~: '\\\ i~
I ;" :~
L.~.~:"._~~==_~~ __-.= __~~_
,
_j _ -"BY'''' _ ~
_~~{OJSaJ _.
. _ ';¿VAr.__
Scale:
.. '
emcon
Associates
a
WILLIAMS ~ WILLIAMS, INC.
REMEDIAL INVESTIGATION PLAN
B.C. CHEMICALS
BAKERSfIELD, CALIFORNIA
FIGURE
I
SITE LOCATION MAP
PROJECT NO.
773-01.01
I.aJ
>
-
0:
o
()
Z
I.aJ
..J
..J
<t
PHOENIX
DRIVE
~
-N-
~
Approximate scale: I": 200'
FIGURE
eme", 12/85
WILLIAMS t WILLIAMS, INC.
REMEDIAL INVESTIGATION PLAN
B.C. CHEMICALS
BAKERSFIELD, CALIFORNIA
SITE MAP
~ emcon
?II)¡ , ·Rssociates
I.&J
::)
Z
I.&J
>
<t
Z
o
-
z
::)
. I
"'2
PRO'[CT NO.
773-01.01
'''O'¡[CT NO,
173 -01.01
:5
FIGUf'E
e...e... 12/115
'- DIRi__
To Union Ave.~
WILLIAMS ~ WILLrAMS, INC.
REMEDIAL INVESTIGATION PLAN
e.c. CHEMICALS
BAKERSFIELD, CALIFORNIA
SCHEMATIC PLOT PLAN
LEASED
WAREHOUSE
'--DIRi__
CHEMICAL I I GateJ ISHE~ l J-- Stora9' tank
TREATMENT
sumP-Ð I Diesel pump~
MOTEL AND
COFFEE SHOP
WAREHOUSE
---CONCREiE ~
OFFI CE
----------
---DIRi OVER A/C--....
]
proximate direction
oround - wat.r flow
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
I
~
. N·
~
o c
o
o "-Tank farm are<
o
DIHr~
Railroad
DIESEL
REPAIR
SHOP
DRUM STORAGE
PHOENIX AND SON GARAGE AND STORAGE COMPANY
~
em con
Associates
NOT TO SCALE
2.1.2 Regional Hydrogeology
Pub 1 i shed data on the regi ona 1 geology and hydrogeology will
be researched. Typi ca 1 sou rces i nc 1 ude pub 1 i cat ions of the
U.S. Geological Survey, records and publications of the State
Department of Water Resources (DWR) and local authorities (for
example Kern County Water Agency, Improvement District No.4).
From the data so obtained, a narrative description of the
surface and subsurface geology and hydrogeology wi 11 be pre-
pared. Included in the description will be appropriate draw-
ings, geologic cross sections, and maps.
2.1.3 History of Chemical Usage
A wide range of chemicals were handled on this site. Appen-
dix A lists the products that were sold by B.C. Chemicals, and
inaddition to these, there may have been compounds used in
formulations, and/or intermediaries and by-products.
The former owner of B. C. Chemi ca 1 s wi 11 be i ntervi ewed to
establish the overall history of the site, and to identify any
additional chemicals that should be included in the listing.
To the extent that former employees of B.C. Chemicals can be
reached, they too will be interviewed.
8
emcon Associates
2.1.4 Disposal Activities and Spills
Whil e conducti ng the i ntervi ews proposed above, a hi story of
disposal activities and spills will also be obtained. To the
extent that thi s hi story may be sparse or non-exi stent, an
inventory of applicable environmental permits will be
obtained, and agency records searched for notices of violation
or similar records.
A narrative description will be prepared including, where
possible, quantities and characteristics of liquid and solid
wastes, as well as spills.
2.1.5 Suspected Contamination Areas
Since the PI has only consisted of walk through inspections,
there is currently no analytical data available on suspected
soil and ground-water contamination.
There is s i gnifi cant surface stai ni ng in several areas, both
on-site and off-site. These areas will be defined in develop-
ing the site plot plan (see Section 2.1) and definition of
extent of contamination will be an objective of the sampling
plan presented in Section 6 below.
2.1.6 Past Remedial Actions
The only known remedial actions that have occurred, or might
occur pri or to impl ementati on of the RI, are the removal of
salvageable chemicals and some interim mitigation measures
designed to control storm water run-off. The extent to which
these activities have occurred will be documented and
verified.
9
emcon Rssociates
2.2 Quality Control/Quality Assurance (QA/QC) Plan
2.2.1 Sampling QA/QC
Prior to field entry a QA/QC plan for sampling soils, waters
and drums wi 11 be prepared for revi ew and approval by Kern
County Health Department (CHD). As a minimum, this will
include:
· Equipment calibration and maintenance procedures.
· Sample collection procedures.
· Chain-of-custody procedures.
· Sample preservation procedures.
Until more site characterization has been carried out, it is
not possible to specify precise methodologies. However,
generic guidelines will be used. A typical example is given
in Appendix C.
2.2.2 QA/QC Aspects of Laboratory Analysis
All samp1 es wi 11 be sent to a State approved and cert i fi ed
laboratory for analysis. Standard methodologies will be used,
as appropriate, using the following protocols given in
Table 1.
The 1 aboratory QA/QC pl an wi 11 adhere to the requi rements of
Section 3.5.2.d of the California Site Mitigation Decision
Tree.
10
emcon Associates
e
e
TABLE 1
RECOMMENDED AND REQUIRED SAMPLING
AND ANALYTICAL METHODS
CAC, TITLE 22, ARTICLE 11
1. "Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods" SW-846, 2nd Edition, US EPA 1982.
2. "Standard Methods for the Examination of Water and Waste Water (6th
Edition)" American Public Health Association, 1985.
3. "Methods for Chemical Analysis of Water and Wastes" EPA
600/4-79-020 US EPA 1979.
4. "Manual of Analytical Methods for the Analysis of Pesticides in
Humans and Environmental Samples" EPA 600/8-80-038 US EPA 1980.
5. Federal Regi ster Vol ume 47, Number 103, Appendi x A, Pages 23376-
23389, May 7, 1982.
6. American Society for Testing and Ma t e ria 1 s, (ASTM) Standards
0-93-79, 0-3278-73.
7. Nat i ona 1 Association of Corrosion Engineers (NACE) Standard
TM-01-69.
11
2.3 Health and Safety Plan
2.3.1 Worker Safety
A generic safety plan has already been prepared for this site
and is available from EMCON Associates. This plan will be
implemented and updated to cover specific activities that will
be carried out during the RI. These include:
· drum sampling and characterization
· exploratory soil borings
· equipment decontamination and dismantling
· removal and disposal of chemicals and drums
For each area the plan will address the following issues in
detai 1 :
· protective equipment
· training
· on-site monitoring
· base-line health surveillance
2.3.2 Community Safety
The site safety pl an revi si ons will address community safety
issues such as the possibility of off-site dispersal of
hazardous or toxic materials. Issues to be addressed in more
detail include:
· site access control
· off-site air monitoring
· contingency planning
12
emcon Associates
2.4 Community Relations and Notification
As part of the Remedial Investigation, a Community Relations and
Notification Plan will be prepared. This plan will address the
following items:
A. Public notification via any and all of the following
techniques:
· newsletters
· community meetings
· project reviews
· technical briefings
· telephone hotline
B. Desi rabil ity of an i nformati on repository. If warranted, a
central depository will be designated either at a local public
1 i brary, or some other nei ghborhood faci 1 i ty such as a hi gh
school.
C. Public meetings. If public awareness and concern warrants,
public meetings will be held, either at specific critical
points 'during remedial action, or on a routine regular
basis. Information will be disseminated via graphic displays,
slide presentations, and technical briefings designed to
translate potentially complex technical information in terms
understandable by lay people.
13
emcon Associates
2.5 Sampling Plan
Figure 4 shows a preliminary environmental assessment of the site,
based on a walk through inspection. The sampling plan must address
the following issues:
A. Nature and type of surface contamination.
B. Extent and nature of soil contamination.
C. Extent and nature of potential ground-water contamination.
D. Nature, type and quantity of residual chemicals contained in
drums, tanks and equipment on site.
2.5.1 Surface Sampling
2.5.1.1 Dirt Piles
Three piles of dirt are present on site. These piles
were created by scrapi ng the superfi ci al soil into pi 1 es
by means of a bull dozer. The soi 1 s do not appear to be
hi ghly hazardous and do not appear to requi re spec i a 1
precautions in handling. If these piles have not been
removed during preliminary site mitigation, the soils
will be sampled and analyzed.
Representative samples will be obtained by hand coring
and mixing the cores to obtain a representative sample.
These samples destined for inorganic analysis will be
placed in plastic bags, labelled and delivered to a State
certified laboratory for analysis. Chain-of-custOdY pro-
cedures will be used throughout. Samples for organic and
14
emcon Associates
If -5 ite oily ,tains
Approximate direction of
Qfound-water flow
: ....5000 c;¡oU
~¡OJ
7( DIRT ) 0
~ PILE)O
~¡~
of staining- I
cryatal. I
I
d horizontal .teel
Jnk (-10009 __________
Small
horizontal
tanka
ç:;;,
\: PILE]
\.'-.....J
x
Area of atainìnQ-
whit. cryatoll
x
x
J;
.yp.)
2' deep bermed sump i
Evid'nce of spillac;¡, and
QCid attack
--
,...
Plastic tonk label.d
.. - 2 OEGREASER"
... ~OOO oollon
'I.voted v.rtical
11..1 tonk
!d concret.
:1. elevated
ydrocllloric
k
/
Oies,l oil staining
:TIC DRUMS
DEPOSIT"
5000 9allon
tank lobel.d
"NO SMOKING"
Off- aite staininQ
-y,lIowish/green
cry.tals
Qþ
Salvageabl.
plating chemicals
Dirt over concrete floor;
Evidenc. of minor spilla
~ABLE
x
Broken packaging including
ammonium perauttate
'IIIe", 12/115
WILLIAMS (. WILLIAMS, INC.
REMEDIAL INVESTIGATION PLAN
B, C. CHEMICALS
BAKERSFIELD, CALIFORNIA
PRELIMINARY ENVIRONMENTAL ASSESSMENT
FIGUfltE
4
~ItO,ICT NO,
773-01.01
'-,
~
-N-
~
I ton sulphur dioxide
cylind.r
Plastic tonk (...!SOOO 901.)
on grade label.d "DUST GUARD"
Vertical elevated te
labeled "# 14"
Plait ic tonk (-!SOOO 901.)
on orade labeled" -12 05-100"
Plastic tonk ("'!SOOO qal.) on
grade labeled" . 10 DMS"
Plastic tonk ("5000901.) on
grade labeled" -9- SILICATE"
(-"'"'")
f DIRT ")
~,-~J
X
.,.
LEGEND
@) Exploratory boring
X Surface sample
~ Dup aquifer monitoring well
Ele
waT
E
X
!SOOl
X plast
acid
Stained dirt
P
~//
Oily stains on dirt floor
M.rcaptan cylinders
X
/
X
X
MISCELLANEOUS
---- PARTIAllY-FILLED ~
DRUMS
EMPTY CF
DR
Xl
Unco nt foiled storm woter runoff
in this area
Chemical odors in this or.a -
Some drums hiss os sun warms th.m;
82 drums hove been characterized and
contents ani hazardous
t;;;)
W
em con
AssocIates
NOT TO SCAl E
\wJ¥¡gi¡ij;k;jki~: imt:tflr-·:î -11:;·,:·:r0m1,:'~g~(\i \~I ~5n! !~H~!¡liHÚ!lt· ~Pfjjrl~'II3D~;~~È111~ij~WilbHflm [1§11J1:m~!lißjr!.lIl!W /lUll It ~¡[lþ!t'I,l!flJ¡ jilt '}';, II JU'! JlILJLJI U¡jll
~:lli¥;}!Î;¡}5¡&J'J~+~'.II!!'(UI~J .....J ::::::@J!ltn\ 111\\\\ :v,I~¡t'!l!!'L~~ læffflAl@g'~nrWijrrJtm;~'i:I~~~lájrd4[)2J~ ,1,;ElIEK f·,j ,~ ·
£õf'HW¥ .. ,0 ,¡0ttt':1 .j' :::%iF:\I,,,j:""\i\ YlhMilìl! .¡I "n[aBKUNDAGE'vr""b", ~nr LANE4 9[:. I Flf1[1I <' :...¡ ,2 0
w:(~ïl: - ~: ~~~ 11·-'-"~~¡~·'$J]œlri,~:.~1;t1Il~jl;~f~f~~'}t¡~~{-~~.~1~:\~~1É£f9It~~ir ~ ~~-~J~l3Q~fll::"~~l;':~;~~~:!~- ~ -~~=t;"~'~F~!;Ï~þ='!;;
~rli:fìf' '[f~E- ~\~ '=J W,õ:-::Ll"'11dr I ¡f,~nrlnLJnB lØ ·>~¡(-·l[ - , I~ LJ§f=::" ._~ !tt· ......:., I
fl~;~'4 ~/, r~~ \~ j:~~gf1 !OD~'::JJl~jIL fJnLO~ h_ ~~ . ë~ '- H~:-'-~0 ~rË~8~. {/::'" ;,·<::r I
FY""~;" ~jf~ ~¡;:,. " ;. 'Y~l~"~B~ro--~J][ILI~ln[]B~Ê~r 11\ -I bl[~~~=JU '~~'9 do r:·.,..·,:,' :..:/:¡. _I
.~!¡I~ '. ""~~§irb~trr~Ej'llLJ :=lll~A~~ 0 0 0 pf):';0FMj I
t!®i:url~~'+ .~¡. .' .' " '! . ':rn ';¡:: - :'!#0[illil~']hlilli~Q ~ ~ /9 ~N~' ~~'r- --ç'l~~Îr~~~,tJl-[-- ·JIIRf1aø..!...".4F:,...,..:.,-¡.:L:I:::::i:·.:·.·.,·.:::::t,..,.:.,..:;,.:::...1
'):'{:::g;tH m.f,~~:]; , ,;,.,..":;, ' f· ". '110'\ ~D[=-:ìLJ I .~ :%'h:.,·:::.t :·.::-::'"-·:··':::/:::1::::::::):·:,.·,:.:::·.:::).1··..,""..·.........,.
:t:.( ~:ìki?;;1" ~;~ '" . '~""~ -.'. Ilf' . ..:. LftJ 'ÔC)[:::X:;'l, .Li:::·:::·':·.:~Wtm:p ::"~ :'. '?k':'<:" ':: "::,:. '. ·:·:..::ltt:·...{:\{:jJ}I,1
If¡ t¢.·.. .' '¡(':;~f'¿~ ~ __ ~1J~~r :'111' ,':. ' ~ ~~~~Q]<tj¡~;~!.::'~:·i~ ~~l ~~:.8JI·::;:~llllllli¡III::!
". ";:., '. ':. . , _. : "'~':::';\1 ¡[.--:-;-=i¡:l}lŒ~ \J;::;- . ·.%r-':"·:'~T c _=.JtJ·~n.....' "t!'u,;¡,~
",:":,:,::,{{,,,,: :.:...... ){.~ ",õ~¡""",¡. "':'i" '¡¡~~lli!~~i[:;;';?¡1 ':. ~ . '.":({. .....:: -'::]D ,. ¡"",.:":,.,,." ..!~::.. " '" .,
""". :,."""""":,, ,.),,: :::,::,':',::::::>" ¡ ~;:t<,,; ,>:" /-' l'~" ~5I .~.! -'L . . :' .¡ 0 = ..';' 'Q' . '. .;
:""'. ."."":,,,,:,.,,: . .' :{::. , ',^ ,: z w"""'m' :, ë· . 'Sf · ,. ~: J ~.".' ..... :})':. :"'::::: '.:
~',:::."::i:: E:f:::jt:q·, . 'f' -..p: 'o;:t'i ¿~[ "_;:"~' h. . '~\ '. ':. J. / /' - [,:,:,,(.,.:.,.,.... '., .:.' . . . ...\., .:¡.
;:::;:;:;:' ':~:~:!: !~~t~i¡ff~~ ~ .¡ , ~ '''\f;:~ ~. , r.=)[~ . ~:;; .' . . F ..' . :.:.:.:.:. . : . .
{',::;:::!. ·!':··:mI);:¡: < '¡. . \:1i c ::¡. ~~ . R;"I''';''/''' ¡..' · '::;:,,:),.; :......: ":""'" :·':I I
.y~···..~~.u~~«ff'H~~··~ f ~........~~~~1F,...y.......,f.. . " ~~~..)/~\~'. ~Q ~, tr::::::::::::;·:¡·.;:.~..:.·.···" ....~
~\~;r;'¡¡jt;";":~i\~¡'¡:j;IIt.I:"" " . ~ ~¡: ~ 11UW1J~us if:·i; > 1
.~ft ~;'"7;¿%1~:~{~." ....~~ I E~~1¡~~!~J-,,'W!!~+I,j~:'1:~
'III\I~~!_ ~"!~i<;;¡"~~i:1~~1=~~... ~.'",~#
~£ ./ '\&1·' ·:..·,·.....:::~:.:)\:..:.,:::\it~:0 ::if)....:.::,:.:::::'::;.i:."'''',....,.,::,:..:,:,:::! .;':j:··5~'¡:¡:::¡·I:::::ihnnr -.¡'"':mmr::::((\:.. "', lfJnDC!lL=; 0 LEGEND
~ 7 .\:." :.·\::::'}:~\:;::::::::;::::/¡:¡~:A T!è:i;1 -. - ,........ ": .:?,::,::::::::::::;···~::::::::::::::::i~?P1¡· ~::::;¡:¡::::::¡::;::::::::\:¡ i :3B~~~ ~ .
./ '\... . ..u......u..··{d~; · ..ul..····'..··E':":ø:::I:UJ~d::::.}n..::}..... I .Jc::Jnc:JfiSî' 0
/" ~~,f(~~!lt'I.,-!r..tIlW1i1; ¡n~ z~\ ~ · Acti.e well
~~~MA ..~';::~i~~·::;:::·:::.;·;l!;;;;i;;I¡ i~·::::;:::·~¡:·!!n~.~:':'::·ij'~:lii¡]\\ !¡i::¡:j::';~'jl¡i~¡:~II':¡!:!:!'!:¡i!¡I'li!!j!:ii;~ :]i:,;i:::::¡¡¡;¡.li ~ ___ __J __ _ 0 Inactive well
l .'. 1-- ~-- ~l. .. ,;J,{l[-j~."..-'i=~ SC.I~~ 200:1t:::·:::~e::el
fl 27 ( ~ L \;:;--'f" ., - =-~= -, ... '. ....
/"
/
/.
-------
Z8
WILL lAMS t WILLIAMS, INC.
REMEDIAL INVESTIGATION PLAN
B.C. CHEMICALS
BAKERSFIELD, CALIFORNIA
WATER WELL LOCATION MAP
1984
~ em con
?//!; Associates
FIGURE
6
PROJECT NO.
773 - 01.01
Figure 8
.EDIAL INVESTIGATION SCHE.E
B.-C. CHEMICALS
Work RI Work Weeks from agency approval
Breakdown Plan Activity
Structure Reference 112,31415 6 1 7 1 8 I 9 ,10 11,12,13114,15 16
1.0 2.1 Site Background
1.1 2.1.1 Site Maps
1.2 2.1.2 Regional
Hydrogeology
1.3 2.1.3 History of
Chemical Usage -
1.4 2.1.4 Disposal Activities
& Spills -
1.5 2.1.5 Suspected Areas of
Contamination
1.6 2.1.6 Past Remedial
Action
1.7 - Draft Report .....,.
2.0 2.2 QA/QC Plan
2.1 2.2.1 Sampling QAlQC
2.2 2.2.2 laboratory
QA/QC
2.3 - QA/QC Plan ...
3.0 2.3 Hea lth & Sa fety
Plan
3.1 2.3.1 Worker Safety
3.2 2.4.1 Community
Safety
3.3 2.4.2 Hea lth & Safety
Plan ...
4.0 2.5 Sampling
4.1 2.5.1 Surface --- -
4.2 2.5.2 Soil Sampling --
4.3 2.5.3 Water Sampl ing -
4.4 2.5.4 Drum Sampling
4.5 - laboratory
Analysis -------
5.0 2.5.5 Surface Water
Runoff
6.0 2.5.6 Air Quality
7.0 - Project
Management
8.0 - Project
Reviews .....
9.0 - Program Revisions
& Implementation
10.0 - RI Report
volatiles analyses will be obtained in brass or stainless
steel rings from undisturbed portions of the piles. The
rings will be sealed, labelled and sent to the labora-
tory.
The representative sample from each pile will be analyzed
for the toxic metals known to have been on-site. These
are:
· barium
· chromium (total and hexavalent)
· cobalt
· copper
· vanadium
· zinc
· nickel
The analysis will be carried out by nitric acid extrac-
tion and total metal concentration determined. If ten
percent of the metal concentration exceeds the STLC value
given in CAC Title 22, Division 4, Section 66696, then
the WET extraction procedure (Section 66700) will be used
to determine the IIsolublell or lIextractablell metal concen-
trations.
Since many of the chemical s used on-site were acids,
alkalis or salts, the following two tests will be carried
out to identify potential contamination:
· pH
· soil conductivity
16
emcon Associates
Exami nat i on of the soil s for organi c chemi cal contami na-
tion presents a problem, in that so many different types
of material were used on-site. While it is technically
feas i b 1 e to analyze for each and everyone, the costs
would be extraordinarily high and perhaps yield little or
no information.
Many of the organic materials are not highly toxic and
will have a relatively short life in the environment.
These include the esters, glycols, ketones and alco-
hols. However, other organic chemicals are more toxic
and, some environmentally persistent. These may repre-
sent a· public health or environmental hazard and include
the organic amines, pesticides, chlorinated solvents,
non-chlorinated solvents and miscellaneous materials such
as formaldehyde and organic mercaptans.
In order to profile this range of compounds at a reason-
able cost, it is proposed to analyze one each of the soil
samples from each pile for:
· chlorinated hydrocarbons
· volatile organic compounds (EPA Method 624)
· total recoverable petroleum hydrocarbons (EPA
Method 418.1)
Research into the chemical nature of some of the
materials currently only identifiable under trade-names
(i.e., Triton M-10 or Dowicide G) will be carried out to
see' of other analyses should also be performed (Le., a
pesticide/PCB screen).
17
emcon Associates
2.5.1.2 Stained Surface Areas
There are a number of areas showing superficial staining,
both off-site and on-site. Surface samples representing
the interval 011-311 will be obtained at the locations
marked on Fi gure 4. These 24 1 ocat ions represent both
suspect and non-suspect areas, and together will provide
a good profil e of the overall surface condit ions on the
site.
The chemical analyses will be the same as those proposed
above for the soil~ from the dirt piles.
2.5.2 Soil Sampling Program
In order to determi ne the extent and depth of pass i b 1 e soil
contami nati on, seven exploratory bori ngs wi 11 be dri 11 ed at
the locations shown on Figure 4. These sites represent areas
of obvious superficial contamination and the exploratory
boring, soil sampling and analysis will demonstrate the extent
of vertical contamination. Additional exploratory borings may
be requi red and the need or otherwi se wi 11 be determi ned by
the results of the surface soil analyses performed under
section 2.5.1.2. The results will also be used to guide the
analytical program, and only those pollutant parameters
identified in a surface sample will be sought in the depth
profile.
The following methodologies will be used in the exploration.
All drilling equipment including bits, augers, samplers, etc.,
will be steam cleaned pri or to commencement of fi e 1 d
activities and between each boring.-
18
emcon Associates
A detailed boring log will be recorded for each boring from
undisturbed soil samples obtained at 5-foot intervals and
drill cuttings. Soil samples will be obtained from each
bori ng begi nni ng at a depth 5 feet below the ground surface
. and continuing at 5-foot intervals until ground water is
encountered or a depth of 40 feet is reached. A modifi ed
California split-spoon sampler will be used to collect the
soil samples. The sampler will be driven 18 inches into
undisturbed ground beyond the tip of the augers by a 140-pound
hammer with a 30-i nch drop. The sampl er will be withdrawn
from the boring and the undisturbed soil samples removed in 4-
inch long brass liners. Soil samples obtained above the water
table will be retained in the brass liners, sealed in aluminum
foil and glass jars, and stored on ice for transport to the
laboratory. Labels will be placed on the jars identifying the
project number, date, sampler's initials, boring number, and
sampling depth. In addition, each soil sample will be
recorded on a chain-of-custody form identifying the soil
sample number, sampler's initials, date, any couriers used,
and responsible laboratory personnel.
If ground water is not encountered, each boring will yield
eight soil samples for analysis. Depending on the results of
the surface sampling program and field observations (i.e.,
stained or odiferous soils) these samples may be analyzed
either separately, or as composites. For estimating purposes
it is assumed that a composite from each boring will be
analyzed for the same range of parameters listed in Section
2.5.1.1 above. All samples not immediately submitted for
analysis will be archived by EMCON under refrigeration for
possible additional analysis.
19
emcon Associates
It is not anticipated that there wi 11 be a need for proj ect
specific analytical techniques or QA/QC methods, and Health
and Safety protocols not already detailed elsewhere in this
plan.
2.5.3 Ground-Water Sampling
In July of 1984, usable ground water in the regional uncon-
fined aquifer was at an elevation of approximately 190 feet
above mean sea level (MSL), (Source: Kern County Water
Agency, Improvement District NO.4). The site surface
elevation is approximately 385 feet MSL, giving a depth to
ground water of about 200 feet. Ground-water contours for
July, 1984 show a very shallow hydraulic gradient to the east
or southeast (see Figure 5).
There are approximately 21 active wells within one mile of the
site (see Figure 6) and five inactive wells. The nearest
active well is approximately 2,000 feet to the west (i .e., it
is upgradient) while the nearest wells downgradient (east
and/or southeast) are approximately 5,000 feet away. There is
a significant well field adjacent to the Central Branch Canal,
approximately 3,000 feet to the south.
As part of the RI, the above data wi 11 be veri fi ed as bei ng
still accurate, and water quality records obtained for the
wells within a one mile radius of the site. If the 1330
program has been carri ed out, specifi c knowl edge of specifi c
priority pollutant contamination (if any) will be available.
If the ,data is not available, or if major data gaps exist, the
nearest well s to the west, east, southeast and south wi 11 be
sampled and the water analyzed for the priority pollutants and
for chlorinated hydrocarbons.
20
emcon Associates
. '1--
i
\
- _1_- .__
I
I
!
! n
--- ._. - . ---
~
u'
: 'I ~
I'
,,'
~.
~t-......~
PETR~¡
; !
!(
':" ,\ RD
'~r"\,~3"
313--
I
!
I ~_____
'/ ~<..~.
--',. --, l~
I 'f-""''-
: ¡ '\ \\ «~,
'--~--'-~11';,' 'K,',
I ,:I ',"
~ "I.
I
. ¥
r~FIRSi. 70 ,
Jt? ~-&' fj
d!: -, {I
~ ~
.----
jl:
"="P~~... ~.~ - i_ fj"
~~;,,~ ~;
- - "- _ð~~.J'
....--
._'"_nn " ,
C. CHEMICALS,
ò'\
It)
- \
r
11
CS(Þ
/>-11
.---.----.---.--
LEGEND
Direction of
ground - water flow
£~~
-~ .._~;
z ,
2: I '
~L-_-'__
P ,I-"'~
SCALE: 0 2000 4000 6000 FEET
WILLIAMS t WILLIAMS, INC.
REMEDIAL INVESTIGATION PLAN
B.C. CHEMICALS
BAKERSFIELD, CALI FORN IA
GROUND-WATER ELEVATION CONTOUR MAP
JULY 1984
FIGURE
~ emcon
. AssocIates
5
San Jose, California
PROJECT NO.
773-01.01
Potential Disposal Mode
Salvage for re-sale.
On-site treatment for hazard and
volume reduction
Non-hazardous materials -
[potentially designated wastes]
Unknown [potentially hazardous
wastes requiring Class I
disposal].
TABLE 4
DRUM PROFILING
Profiling Required
Full, sealed drums, clearly
identifiable as unused chemical
stock.
Acids and alkalis, need pH deter-
mination and anion identification
by qualitative analysis.
Strong brines and crystalline
neutral salts. Need pH and
qualitative anion determination.
Test for legal definition of
hazardousness (explosive, toxic,
flammable and/or corrosive).
Chemically profile to classify
nature of toxicity [hydrocarbons,
chlorinated hydrocarbons,
pesticides, etc.]. Use the
HAZCAT screening program.
30
emcon Associates
2.5.5 Surface Water Run-off
As indicated elsewhere, some uncontrolled storm water run-off
occurs at this site. If a temporary mitigation plan is
approved (submitted 12/26/85) and implemented, this problem
will be controlled at the time the RI is implemented.
The sampling planned under Section 2.5.1 above, should detect
any off-site contamination that might have occurred from
historic discharges.
2.5.6 Air Quality
As part of the RI an assessment of the possibility of contam-
inant migration via the air pathway will be made. This
assessment will address both current site conditions and
planned or possible remedial activities.
The assessment will address the followin items:
.
Potent; al for
damaged drums,
site treatment
release of noxious fumes from either
from chemical transfer operations and on-
operations.
. Potential for release of potentially contaminated dust
from wi nd corros i on and uncontroll ed excavations and/or
soils handling.
Assessment will include nature and quantity of potential toxic
air releases, as well as identification of populations at
risk.
31
emcon Associates
Based on the assessment, an air sampling monitoring plan will
be developed for implementation in the RAP.
2.6 Schedule
The RI is expected to take about four months (see attached
Schedule, Figure 8). Paci ng items for this program are:
A. Preliminary Data Gathering 4 weeks
B. Field Investigation Including drum profiling 6 weeks
c. Laboratory Analysis 3 weeks
D. Final Data Reduction and Report 3 weeks
The schedule assumes that the assumptions outlined in the program
are, in fact, verified in practice.
32
emcon Associates
e
e
APPENDIX A
B.C. CHEMICAL IS PRODUCT LIST
e
.:~. :~.~ =:':~A :307 · PO. 80, 884. .-.~~, CA 93302 .' Phon. (805) 832·1380
J
.
,
Dear Customer:
BC Chemicals is a full line chemical distributor, we also
offer a complete line of blended products, (degreasers, mud
detergent, etc.).
BC Chemicals operates 24 hours a day 7 days a week
to fulfill your chemical needs.
Should you be unable to find the particular product within
these product listings, please contact your sales representative
or our office. BC Chemicals has the sources available to obtain
whatever product you may require.
Richard J.
President
e
e
TABLE OF CONTENTS
Page Number
ACIDS ................................................ 1
ALCOHOLS. . .'.'. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3
ALKALlI . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
AMINES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
CHLORINATED SOLVENTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
CLEANERS & DEGREASERS .. .. .. .. . .. .. . .. . . . .. .. 11 - 1 7
DRILLING FLUIDS MATERIALS.. . .. .. .. . .. .. .. . . . .. .. . 8, 9
ESTERS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
FORMULATED PRODUCTS. . . . . . . . . . . . . . . . . . . . . . . . . 18 - 31
GLYCOLS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2, 3
INORGANIC & ORGANIC CHEMiCALS.................. 4-7
KETONES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
ORGANIC ACIDS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
PHOSPHATES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
This product list supersedes any previous product list.
e
ORGANIC ACIDS
Acetic Acid Glacial
480 Ib drum
Acetic Acid 80%
477 Ib drum
Benzoic Acid
50 Ib sack
Boric Acid
1 00 Ib sack
Chromic Acid
1 00 Ib drum
Citric Acid
1 00 Ib sack
Formic Acid
515 Ib drum
Oxalic Acid
50 Ib sack
Sulfamic Acid
50 Ib sack
ACIDS
Muriatic Acid (HCL)
535 Ib drum
1 40 Ib carboy
Nitric Acid
600 Ib drum
90 Ib carboy
Phosphoric Acid
220 Ib drum
Sulfuric Acid
750 Ib drum
200 Ib carboy
PHOSPHA TES
Diammonium Phosphate
1 00 Ib sack
Disodium Phosphate
1 00 Ib sack
Page 1
e
PHOSPHATES (can't)
Soda Phos
50 Ib sack
Sodium Hexametaphosphate Granular
50 Ib sack
1 00 Ib sack
Sodium Hexametaphosphate Plate
50 Ib sack
1 00 Ib sack
Sodium Tripolyphosphate
1 00 Ib sack
Tetrapotassium Phosphate
1 00 Ib sack
T etrasodium Pyrophosphate
1 00 Ib sack
Trisodiumphosphate
1 00 Ib sack
Monosodiumphosphate
1 00 Ib sack
ALKALI
Caustic Potash Flake
1 00 Ib drum
Caustic Potash Uquid 50%
680 Ib drum
Caustic Soda Bead
. 50 Ib sack
Caustic Soda Flake
50 Ib sack
Caustic Soda Liquid 25% (bulk)
600 Ib drum
Caustic Soda Liquid 50% (bulk)
707 Ib drum
Soda Ash
50 Ib sack
1 00 Ib sack
Sodium Bicarbonate
50 Ib sack
1 00 Ib sack
e
AMINES
Diethanolamine 99%
480 Ib drum
Diethylene Triamine
440 Ib drum
Diisopropanolamine
450 Ib drum
Ethylene Diamine
478 Ib drum
Isopropanolamine PRG
450 Ib drum
Mixed Isopropanolamine
450 Ib drum
Monoethanolamine
460 Ib drum
Monoispropanolamine
440 Ib drum
Morpholine
460 Ib drum
Triethanolamine 85%
510 Ib drum
CHLORINATED SOLVENTS
Aerothene IT
54 gal drum
Aerothene MM
600 Ib drum
Chlorothene NU and VG
592 Ib drum
Dowclene EC
54 gal drum
Ethylene Dichloride
565 Ib drum
Methylene Chloride
600 Ib drum
Orthodichlorobenzene
600 Ib drum
Perchloroethylene, Ind.
700 Ib drum
Page 2
e
CHLORINATED SOLVENTS (con't)
1 , 1 , 1 Trichloroethane
592 Ib drum
Trichloroethylene
600 Ib drum
ESTERS
Amyl Acetate. Primary
400 Ib drum
Butyl Acetate, Normal
400 Ib drum
Dalpad A
505 Ib drum
EE-Acetate
440 Ib drum
Ethyl Acetate 85-88%
400 Ib drum
Ethyl Acetate 99%
409 Ib drum
Isobutyl Acetate
400 Ib drum
Isopropyl Acetate
390 Ib drum
N. Propyl Acetate
400 Ib drum
Butyl "Cellosolve" Acetate
422 Ib drum
"Carbitol" Acetate
463 Ib drum
Butyl "Carbitol" Acetate
450 Ib drum
GL YCOLS
Diethylene Glycol
520 Ib drum
Dipropylene Glycol
470 Ib drum
Ethylene Glycol
515 Ib drum
e
Gl YCOlS
Hexylene Glycol
424 Ib drum
Propylene Glycol, Ind.
480 Ib drum
Propylene Glycol, USP
480 Ib drum
Triethylene Glycol
520 Ib drum
Tripropylene Glycol
470 Ib drum
KETONES
Acetone
358 Ib drum
Cyclohexanone
432 Ib drum
Diacetone Alcohol
430 Ib drum
Diisobutyl Ketone
370 Ib drum
Dimethyl Formamide
41 0 Ib drum
1 ,4 Dioxane
473 Ib drum
Ethyl Amyl Ketone
374 Ib drum
Isophorone
425 Ib drum
Methyl Ethyl Ketone
366 Ib drum
Methyl Isobutyl Ketone
365 Ib drum
2-Nitropropane
455 Ib drum
Pentoxone
41 0 Ib drum
T etrahydroturan
400 Ib drum
Page 3
-
ALCOHOLS
Amyl Alcohol, Primary
370 Ib drum
Butanol, Normal
370 Ib drum
Butanol, Secondary
369 Ib drum
Isobutanol
370 Ib drum
Isopropanol, Anhydrous
55 gal drum
Methanol
55 gal drum
Methyl Isobutyl Carbinol
371 Ib drum
Methyl Amyl Alcohol
371 Ib drum
Propanol, Normal
370 Ib drum
e
INORGANIC AND ORGANIC CHEMICALS
Acintol FA-2
420 Ib drum
Aluminum Sulfate.
1 00 Ib sack
Ammonia Anhydrous
1 50 Ib cyli:1der
Ammonia Bicarbonate
300 Ib drum
Ammonium Alum
1 00 Ib sack
Ammonium Biflouride
50 Ib sack
Ammonium Chloride
50 Ib sack
Ammonium Hydroxide
350 Ib drum
Ammonium Nitrate
80 Ib sack
Ammonium Sulfate
1 00 Ib sack
Asbestos
50 Ib sack
Barium Sulfate
1 00 Ib sack
Bentonite
1 00 Ib sack
Borax
1 00 Ib sack
Butyl Oxitol
41 5 Ib drum
Calcium Carbonate
50 Ib sack
Calcium Chloride
80 Ib sack
Calcium Chloride Water
Bulk
Page 4
e
Calcium Chloride Powder
1 00 Ib sack
Calcium Hypochlorite Granular
1 00 Ib drum
Calcium Hypochlorite Tabs
1 00 Ib drum
Carbon
50 Ib sack
Chain Oil
55 gal drum
Chlorine
1 50 Ib cylinder
1 ton
Cobalt Sulfate
1 00 Ib sack
Copper Sulfate
80 Ib sack
Cyclohexylamine
175 Ib drum
Deriphat
90 Ib drum
Diatomaceous Earth
Hyflo Super Cel Bulk
50 Ib sack
Standard Super Cel
50 Ib sack
Celite 535
50 Ib sack
Celite 545
50 Ib sack
Fiber Cel
50 Ib sack
Dioctylphalate (Depone)
436 Ib drum
Dowfax 2-A-1
530 Ib drum
Dowicide G
11 0.1 2 Ib sack
e
e
INORGANIC AND ORGANIC CHEMICALS (can't.)
Epsom Salt
1 00 Ib sack
Ethyl Mercaptan
5 gal pail
Ferric Chloride
Bulk
Ferrous Sulfate
50 Ib sack
Formaldehyde
Bulk
Gluteraldehyde 50%
500 Ib drum
Glycerine 96 %
570 Ib drum
Glycerine U.S.P.
570 Ib drum
Gypsum
1 00 Ib sack
Hampene 1 00
58 Ib drum
H.T.H. Granular
1 00 Ib drum
H.T.H. Tabs
1 00 Ib drum
Hydrazene
250 Ib drum
450 Ib drum
Hydrogen Peroxide 35%
275 Ib drum
500 Ib drum
Kerosene
55 gal drum
LAS - 99 (Cal Soft)
480 Ib drum
Lime Hydrated
50 Ib sack
Lime Quick (Calcium Oxide)
60 Ib sack
Methyl Formate
440 Ib drum
Metso 20
Sodium Metasilicate
1 00 Ib sack
Mineral Oil
55 gal drum
Morpholene
460 Ib drum
Muriatic Acid Inhibitor
Rodine 21 3
1 gal
5 gal
Nickel Brightener
5 gal
Nickel Chloride
50 Ib sack
1 00 Ib sack
Nickel Sulfate
100lb
Ninol - 1 285
400 Ib drum
NTA - NA3
50 Ib sack
Orzan
50 Ib sack
Pine Oil
55 gal drum
Potassium Carbonate
1 00 Ib sack
Potassium Chloride (Potash)
1 00 Ib sack
Bulk
Potassium Ferricyamide
1 00 Ib drum
Potassium Metabisulfite
1 00 Ib sack
Potassium Nitrate
1 00 Ib sack
Page 5
tit
e
INORGANIC AND ORGANIC CHEMICALS (con't.)
Potassium Permanganate
330 Ib drum
Potassium Phosphate
1 00 Ib sack
Potassium Sorbate
1 00 Ib sack
Potassium Sulfate
1 00 Ib drum
Propylene Dichloride
520 Ib drum
Paraformaldahyde
50 Ib sack
Quebueuo
50 Ib sack
Salt XXX
Bulk
50 Ib sack
Salt Food Grade
80 Ib sack
Soda Ash
Bulk
50 Ib sack
1 00 Ib sack
Sodium Acid Pyrophosphate
1 00 Ib sack
Sodium Benzoate U.S.P. Flakes
1 00 Ib sack
Sodium Bicarbonate
1 00 Ib sack
Sodium Bisulfate Globular
1 00 Ib sack
Sodium Bisulfate
1 00 Ib sack
Sodium Bromate
290 Ib drum
Sodium Bromide
270 Ib drum
Sodium Gluconate
50 gal drum
50 Ib sack
Sodium Hydrosulfite
250 Ib drum
Sodium Hypochlorite
55 gal drum
Sodium Hypophosphite
11 0 Ib sack
Sodium Metabisulphite
110.23 Ib sack
Sodium Metasilicate
1 00 Ib s~ck
Sodium Nitrate
1 00 Ib sack
Sodium Nitrite
1 00 Ib sack
Sodium Silicate 40
640 Ib drum
Sodium Silicate 8.J. 120
640 Ib drum
Sodium Silicate D
700 Ib drum
Sodium Sulfate
1 00 Ib sack
Sodium Sulfite
1 00 Ib sack
Sodium Sulfide Flakes
41 5 Ib drum
Sodium Sulfide
425 Ib drum
Sodium Tripolyphosphate
1 00 Ib sack
Sodium Thiosulfate
1 00 Ib sack
Soluble Oil
55 gal drum
Page 6
e
e
INORGANIC AND ORGANIC CHEMICALS (con't.)
Solvents
Cleaning Solvents
55 gal drum
Lacquer Thinner
55 gal drum
Mineral Spirits
55 gal drum
Solvents 172-L
55 gal drum
Solvent 355-L
55 gal drum
Chevron 11 00
55 gal drum
Solvent 1 200
55 gal drum
Solvent 51 5
55 gal drum
Solvent 8
55 gal drum
Solvent G
55 gal drum
Stoddard Solvent
55 gal drum
V. M. &P. Naptha
55 gal drum
Sulfamic Acid
50 Ib sack
Sulfur Dioxide
1 ton cylinder
Tartaric Acid
50 Ib sack
Toluene
55 gal drum
Triton
N-10
475 Ib drum
N-1 01
480 Ib drum
X-45
480 Ib drum
X-100
480 Ib drum
as-30
515 Ib drum
Urea 46% N
80 Ib sack
Versene 100
600 Ib drum
Venadiam Pentoxide
1 00 Ib sack
White Oil
55 gal drum
Xylene
55 gal drum
Zinc Carbonate
50 Ib sack
Zinc Oxide
50 Ib sack
Zinc Sulfate
55 Ib sack
- I
I
--
Page 7
e
DRilLING FLUIDS MATERIALS
B.C. 25 L.P.
5 gal pail
3Cyanamer P-26
50 Ib sack
3Cypan
50 Ib sack
Defoamer
50 Ib pail
Defoamer +
40 Ib pail
IDesco
25 Ib sack
OMS
50 Ib pail
Drillaid DFLC-L
Mud Deflocculant
5 gal pail
7Drillaid FCA-11
Filtrate Control/Shale Stabilizer
50 Ib sack
Drilling Starch
50 Ib sack
IDrispac Super Low
50 Ib sack
IDrispac Regular
·50 Ib sack
IDriscose
50 Ib sack
2H E C Polymer
50 Ib sack
Lime Hydrated
50 Ib sack
Lime-Quick (Calcium Oxide)
60 Ib sack
Page 8
e
M.D.
5 gal pail
M.D. +
5 gal pail
4Natrasol
50 Ib sack
Potassium Bichromate
1 00 Ib sack
Potassium Carbonate
1 00 Ib sack
Potash
1 00 Ib sack
aWes Thin
A multi-purpose deflocculant
5 gal pail
aWes Vis
A bentonite extender &
Drilled Solids Flocculant
5 gal pail
5Polysec K.D.
50 Ib carton
Sapp
1 00 Ib sack
Saw Dust
50 Ib sack
Soda Ash
50 Ib sack
1 00 Ib sack
Sodium Bicarbonate
50 Ib sack
1 00 Ib sack
(can't)
REGISTERED TRADEMARKS
1. Drilling Specialties Company
2. Union Carbide Company
3. American Cyanamid
4. Hercules Chemical Company
5. American Colloid Company
6. Mud Specialists, Inc.
7. Welchem, Inc.
8. Westbridge Oilfields Products
e
DRILLING FLUIDS MATERIALS
Sodium Bichromate
1 00 Ib sack
Sodium C.M.C.
50 Ib sack
Sodium Chromate
1 00 Ib sack
Sodium Hexametaphosphate Plate
50 Ib sack
1 00 Ib sack
Sodium Hexametaphosphate Granular
50 Ib sack
1 00 Ib sack
Sodaphos
50 Ib sack
1Soltex
50 Ib sack
T.B.P. Defoamer
50 Ib bucket
Zinc Chloride
440 Ib drum
Paae 9
e
Barite
1 00 Ib sack
Mica Fine
50 Ib sack
Nut Seal Fine
50 Ib sack
Nut Seal Medium
50 Ib sack
Nut Seal Coarse
50 Ib sack
Sawdust
25 Ib sack
Cedar Fiber
40 Ib sack
Kwik Seal Fine
50 Ib sack
Kwik Seal Medium
50 Ib sack
Kwik Seal Coarse
50 Ib sack
Cottonsead Hulls
50 Ib sack
Cottonseed Pellets
50 Ib sack
REGISTERED TRADEMARKS
1. Drilling Specialties Company
e
e
CLEANERS AND DEGREASERS
P::>nø 1 n
e
-
DEGREASER
Heavy Duty Solvent Emulsion Degreaser
Deep Solvent Penetration
BC DEGREASER will quickly penetrate Grease, Oil, Tar, Carbon and many other heavy soils.
Recommended for use on, production equipment engines, trucks, plant floors and metal
surfaces. After allowing sufficient soak time to penetrate the soil, a steam or pressure
washer will remove oil and grease with no problem of oily residue.
Surface Safety
BC DEGREASER may be used on all metals such as, aluminum and magnesium, glass,
concrete, most paints, plastics and rubber.
Versatility & Savings
BC DEGREASER is used diluted with 1 to 1 ° parts water for most cleaning and degreasing
applications. For heavy jobs BC DEGREASER can be diluted with diesel, 1 to 40, this
provides a single product to meet every heavy duty cleaning and degreasing application.
Typical Dilution Rates
Hardened Carbon and Deposits. . . . . . . . ., . . . . . . . . . . . . . . . . . . . .. . . . . Up to 2 parts water
Thick Grease and Open Gear Lubricants. . . . . . . . . . . . . . . . . . . . . . . . . . . Up to 2 parts water
Hardened Oils and Compacted Soil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 . 8 parts water
Gas and Diesel Engine Deposits ........................... . . . . . . . . 3 . 1 ° parts water
Medium to Heavy Deposits of Oil and Grease. . . . . . . . . . . . . . . . . . . . . . . Up to 5 parts water
Light to Medium Deposits of Oil and Grease . . . . . . . . . . . . . . . . . . . . . . . . . 3 . 1 2 parts water
Chemical & Physical Characteristics
Appearance ...... . . . . . . . . . . . Amber Liquid
Weight Per Gallon. . . . . . . . . . . . . . . . . 8.4 Ibs.
pH: Concentrate. . . . . . . . . . . . . . . . . . . . . 1 0.5
10% Solution. . . .. . . . . . . . . . .. ......9.65
1 % Solution. . . . . . . . . . . . . . . . . . . . . . . .9.25
Flash Point. . . . . . . . . . . . . . . . . . 174°F (COG)
Rinsing ............... Excellent with water
Use B C Degreaser to Remove
· Greases
· Uncured Resins
· Tar and Asphalt Stains
· Printing Inks
. Carbon Stains
· Stamping Oils
· Rubber Skid Marks
· Soot Stains and Smut
· Carbon Black
· Open Gear Lubricants
Use B C Degreaser for Cleaning
· Tank Trucks
· Diesel Engines
· Oil Storage Tanks
· Production Machinery
· Grease Racks
· Plant Floors
· Running Gears
· Auto Chassis
· Fork Lift Trucks
· Auto and Truck Blocks
Packaging
5 gallon and 55 gallon drums
Bulk shipments
Page 11
~¿5
e
-
DEGREASER II
Heavy Duty Solvent Emulsion Degreaser
Deep Solvent Penetration
BC DEGREASER will quickly penetrate Grease, Oil, Tar, Carbon and many other heavy
soils. Recommended for use on, production equipment engines, trucks, plant floors and
metal surfaces. After allowing sufficient soak time to penetrate the soil, a steam or pressure
washer will remove oil and grease with no problem of oily residue.
Surface Safety
BC DEGREASER may be used on all metals such as, aluminum and magnesium, glass,
concrete, most paints, plastics and rubber.
Versatility & Savings
BC DEGREASER is used diluted with 1 to 10 parts water for most cleaning and degreasing
applications. For heavy jobs BC DEGREASER can be diluted with diesel, 1 to 40, this
provides a single product to meet every heavy duty cleaning and degreasing application.
Typical Dilution Rates
Hardened Carbon and Deposits. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Up to 2 parts
Thick Grease and Open Gear Lubricants. . . . . . . . . . . . . . . . . . . . . . Up to 2 parts
Hardened Oils and Compacted Soil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 - 8 parts
Gas and Diesel Engine Deposits .............................. 3 - 1 0 parts
Medium to Heavy Deposits of Oil and Grease. . . . . . . . . . . . . . . . . . Up to 5 parts
Ught to Medium Deposits of Oil and Grease . . . . . . . . . . . . . . . . . . . . 3 - 1 2 parts
Diesel
or
Solvent
Chemical & Physical Characteristics
Appearance ................. Amber Uquid
Weight Per Gallon. .. ....... .... . . .8.4 Ibs.
pH: Concentrate.. . . . . .. . .. . . . . . . . . . . 10.5
10% Solution. . .. . . . . .. . .. . . . . . . . . . .9.65
1 % Solution ........................ 9.25
Flash Point. . . . . . . . . . . . . . .. . . 195°F (COC)
Rinsing ............... Excellent with water
Use B C Degreaser to Remove
· Greases
· Uncured Resins
· Tar and Asphalt Stains
· Printing Inks
· Carbon Stains
· Stamping Oils
· Rubber Skid Marks
· Soot Stains and Smut
· Carbon Black
· Open Gear Lubricants
Use B C Degreaser for Cleaning
· Tank Trucks
· Diesel Engines
. Oil Storage Tanks
· Production Machinery
· Grease Racks
· Plant Floors
· Running Gears
· Auto Chassis
· Fork un Trucks
· Auto and Truck Blocks
Packaging
5 gallon and 55 gallon drums
o. .11, _.....:______..._
n___ .. '"
~^ r
e
e
THREE·W A Y DEGREASER
A Safe All Purpose Cleaner
BC CHEMICAL THREE-WAY DEGREASER is a liquid cleaning concentrate with these
outstanding advantages:
Rapidly removes heavy oil, grease and grime from machinery, equipment and floors.
Soluble in hot or cold water and can be rinsed off with water leaving a streak-free
surface.
Safe to use because it is a non-explosive water solution.
Non-corrosive to metal and concrete surfaces.
Economical to use.
How to use B C Chemical Three-Way Degreaser
For medium to heavy deposits of oil and grime, dilute all purpose cleaner with 3 to 10
parts of water.
For very heavy deposits of oil, grease or dirt, mix concentrate with 3 to 1 0 parts of
kerosene or diesel oil.
Application Methods
B C Chemical Three-Way Degreaser may be applied by wiping, brushing or spraying
on the soiled surfaces. The product may also be used in dip tanks or circulated through
equipment to remove oily deposits.
Vertical surfaces may be cleaned by mixing 4 parts of B C Chemical Three-Way
Degreaser with 4 parts of kerosene and 1 part of water. This mixture clings to vertical
surfaces until rinsed with water.
Handling
B C Chemical Three-Way Degreaser is an alkaline solution and contains detergents.
Care should be taken to avoid splashing product in the eyes. In case of eye contact, flush
eyes with plenty of water.
Packaging
5 gallons and 55 gallon drums
Page 1 3 ,t
'1 D L
, ,
e
e
CTS-1 CLEANER
In the 8. C. Chemical line of cleaner products, this high-alkaline detergent is designed
for use in pressure spray or soak type bottle washers. Well adaptable for heavy-duty
cleaning of product lines, pasteurizers, mixers, cookers and other processing equipment.
CTS-1 Cleaner is a blend of alkalies, organic chelates, sequestrants, wetting agents and
other ingredients. These combine to provide a full range of important advantages, such as:
A complete bottle washing material. It's very effective in automatic bottle washing
machines of all types, including high pressure spray· machines. A thorough cleaning
agent for spray washing of reusable plastic milk containers.
The high alkaline content provides germicidal protection.
CTS-1 provides lubricity to reduce friction and wear in bottle washers. Sequestrants
prevent the deposition of scale on bottles and washers. Omanic chelates aid in the
control of aluminate scale, caused by dissolved aluminum foil labels.
The best in cleaning results from high rinsability.
In food plants, CTS-1 is a heavy-duty cleaner for product pipelines, juice pasteurizers,
vegetable cookers, and other stainless steel processing equipment.
How and where to use CT5-1 Cleaner
Bottle Washing: Concentration of CTS-1 depends on the caustic requirements of regulatory
bodies in the locality. 1 oz. per 1 gal. of CTS-1 equals .71 % cuastic by weight; or .7 oz./gal.
equals 1/2% caustic by weight. When a code requires 3% caustic, this can be met by using
a solution of CTS-1 at 4-1/4 ounces per gallon.
Food Processing Equipment: a 2 to 4 oz.lgal. solution at 1600 - 180°F, will handle most
jobs.
Plants with central alkali system: for all phases of cleaning operations, the central
reservoir should contain 4-1/4 oz.lgal. to handle bottle washing, heavy-duty cleaning and
circulation cleaning requirements.
CTS-1 is especially useful in breweries, bottling plants, dairies and food canneries.
NOTE: Uke any alkaline material, CTS-1 should be added slowly to cold water while stirring -
never to hot water either for original makeup or for upkeep. The usual precautions for
handling alkaline materials and solutions should be observed.
Page 1 4
~o
e
e
AST-1
Cleaning Compound
AST-1
is a formulated product that quickly and easily removes soils and stains that ordinary
cleaners do not.
AST-1
is non-toxic, will not cause burns on the skin; has no irritating fumes; is non-corrosive;
safe on all plastics and paints; and on electrical insulation. Will not injure acrylic paint
or other paints used on equipment, machines or autos.
COMPOSITION
Water based solution of alkaline ingredients, biodegradable surface, active agents, and
emulsifiers. Is non-flammable and has to flash point up to and including its boiling point.
AUTO AND TRUCK WASHING
Pre-rinse with water. Dilute 1 cup AST-1 per gallon of water. Apply by spray and brush
surface, rinse with water. This will not cause any harm to car finish. Leaves a bright
,and well kept appearance.' .
STEAM CLEANING
Dilute up to 20 to 1 in solution tank, no caustic, no odor. Safe on all types of metal.
Aluminum and stainless steel especially. Provides spray wetting and penetrating action.
PACKAGING
5 gallon and 55 gallon drums
Bulk shipments
Page 1 5
ie-s
e
e
HOT TANK CLEANER
A powerful alkaline cleaner fortified with special detergents for rapid penetration and
emulsification.
Used for removal of caked oil on engine blocks.
Protection equipment.
Used where a standard degreaser is not enough.
Not recommended for use on soft or nonferrous metals, such as aluminum or magnesium.
HANDLING PRECAUTIONS
BC's Hot Tank cleaner is a strong alkaline compound and is hazardous to personnel, unless
proper safety precautions are exercised when handling.
Avoid contact with:
Skin, eyes ot clothing.
When handling, wear rubber clothing, gloves, and face shield.
In case of contact with skin: flush exposed area with water and rub area affected for
15 minutes. For eyes, flush with water. Contact physician.
PACKAGING
55 gallon Fiber Drums
(405 Ibs.)
Page 1 6
~ò
e
e
CONCENTRATED ALUMINUM BRIGHTENER
Concentrated Aluminum Brightener for all non-ferrous metals:
CHROME, ALUMINUM, BRASS & COPPER
DIRECTIONS:
1. Cut Concentrated Aluminum Brightener with 40 parts water.
2. Wash surface to be cleaned with soap and water.
3. Spray surface generously and evenly with cut solution of Aluminum Brightener.
Allow to soak from 1 to 2 minutes.
4. Rinse thoroughly with water. On very dirty or heavily soiled surfaces, repeated
application may be necessary.
CAUTION:
Be careful not to splash into eyes or on clothing.
Do not breath fumes.
Keep out of reach of children.
Contains: Phosphoric mineral and organic acids.
MAY BE HARMFUL OR FATAL IF SWALLOWED. DO NOT INDUCE VOMITING.
GIVE MILK OR WATER. CONTACT PHYSICIAN IMMEDIATELY.
IN CASE OF EYE CONTACT: FLUSH THOROUGHLY WITH WATER.
CONTACT PHYSICIAN IMMEDIATELY.
Packaging
1 gallon, 5 gallon, 55 gallon drums
Page 1 7 \-.J ~
e
-
TRANSITMIX
Packaging
50 gallon bbl.
Bulk
~Q,)
e
e
FORMULATED PRODUCTS FOR SPECIFIC APPLICATION
Page 1 8
e
e
DATA SHEET
05-100 OXYGEN SCAVENGER FOR DRILLING FLUIDS AND WATER TREATING
Description:
OS-100 is a 52% by weight ammonium bisulfite solution and is an oxygen scavenging
agent for drilling fluids and other water systems requiring oxygen removal.
Typical Properties:
Appearance
Density, Lb/Gal.
Sulfite %
pH - 50% Solution
Clear Ught Yellow Uquid
10.8
55
4.5
Suggested Uses:
OS-1 00 may be substituted directly for catalyzed sodium sulfite as an oxygen scavenger.
It is a stable solution and being a liquid, there are no dissolving and plugging problems.
Use of OS-1 00 in drilling fluids and other water treatment uses allows protection from
Oxygen corrosion of drill pipe, pumps and other metals in contact with the media.
OS-1 00 should be added continuously directly at the pump suction utilizing a chemical
injection pump. Theoretical treating ratio is slightly less than 9 parts of OS-1 00 per 1 part
of oxygen. Pumping rate is dependent upon the oxygen concentration present. A minimum
of 1 00 ppm excess sulfite is recommended.
In drilling fluids, the base line corrosion rate may be established by running drill pipe
corrosion rings in the drill string prior to commencing treatment. The coupons should be
run in the drill collar cross-over sub, and the kelly saver sub. If only one coupon is to be
run, it should be placed in the drill collar crossover sub. Rings should be run a minimum of
50 hours (100 hours is desired).
Page 1 9
r {.,~ () G\.
e
e
BC MICROBIOCIDES
5 gallons
55 gallons
B.C. Microbiocide 1000
B.C. Microbiocide 2000
B.C. Microbiocides, available as B.C. 1000, a 25-per cent aqueous solution of glutaral-
dehyde, and B.C. 2000, a 50-per cent aqueous solution of glutaraldehyde are useful as
preservatives and in formulating broad spectrum industrial biocides. '
B.C. Microbiocides have many important features including:
· EP A Registration '
· Effectiveness against a broad spectrum of microorganisms
· Aqueous solutions which are easily and uniformly diluted and mixed
· Ability to be easily neutralized for disposal
· Effectiveness against aerobic and anaerobic organisms
.Compatible with anionic, nonionic, cationic surtactants
· Do not contain or release formaldehyde
· Lower vapor pressure than formaldehyde
· Diluted product easily analyzed by gas chromatography
· Not affected by the presence of hard water
STORAGE AND HANDLING OF
B.C. MICROBIOCIDES OIL WELL MICRO BIOCIDE
B.C. Microbiocide 1000 is an aqueous solution of Glutaraldehyde, at 25% (by weight)
concentration. It is slightly corrosive to common materials of construction, such as steel,
aluminum, and galvanized iron; the corrosion rates are low (equipment would not be
severly damaged) but contamination of the product will result if contact is prolonged.
Materials which have been tested and found to be suitable are stainless steel, certain
fiberglass-reinforced plastics, and polypropylene or polyethylene.
Types 304 or 316 stainless steel are suitable. Of the plastics tested, a polyester
("Atlac" 382) and a vinyl ester ("Derakane" 470) were resistant, but an epoxy showed
some adverse effect after prolonged exposure to Glutaraldehyde. Uned steel containers
are not recommended because iron contamination can result, due to pinholes in the
coating.
NOTE: Storage tanks, lines, pumps, valves, etc., must not be made of iron or steeL:,'
Even trace iron contamination (one ppm or less) can have an adverse effect on
the long-term stability of the product.
The 25% solution freezes at about -10°C (14°F). Thus, if outside storage is planned,
heated and insulated facilities will usually be required. However, the storage stability of
Glutaraldehyde is very dependent on storage temperature and storage at temperatures
below 100°F is recommended. Preferred locations for a storage tank might be either
indoors or underground; drums could be stored in a warehouse or, during hot weather,
in a shaded storage area where they are not directly exposed to the sun.
If B.C. Microbiocide 1000 is to be heated, warm water is the preferred heating medium,
in order to insure that the product will not be exposed to high temperatures. It is
suggested that water temperatures should not exceed about 40-50oC (1 00-1200F) and
temperature controls could be set so that the average temperature of the stored liquid is
only about 20°C. This should insure a reasonably long storage life for the product.
Piping and valves can be of polypropylene or polyethylene or stainless steel. A stainless
steel centrifugal pump is suitable for transfer service. Asbestos can be used for gaskets
and packing.
NOTE: If B.C. Microbiocide is to be diluted, use only distilled/deionized water that is
low in iron, calcium, and magnesium content.
?('\ ~ .í\ ~..... r \1.
-~
e
e
UCARCIDE 12
CHEMICALS
MATERIAL SAFETY DATA SHEET
Antimicrobië
PRODUCT
-
(Ap~'o~ød by U.S. Dto~',,".nr of L~bo'.' ·'tuMti.lIlIlimil.,· ro F onn LS8·oaS-41
seCTION I-IDENTIFICATION OF PRODUCT .
MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.
BC CHEMICALS INC.
ADO R ESS (Numbtr, Sliter. Qry, :iIiUt Dna ,£.IT ,-pueJ
1511 South Union Avenue/Bakersfield 805/832-1360
TRAOE NAME CHEMICAL NAME
MICROBIOCIDE 1000 Not applicable/Blend of Materi¿
CHEMICAL FAMILY CHEMICAL FORMULA
Aldehyde II " " II " " "
SeCTION II·HAZARDOUS COMPONENTS OF MIXTURES
A precise composition 01 this product, is proprietary information. A more detailed disclosure win be provided by BC ChemicaJs as privileged i~I~~~tion
upon request 10 case 01 need lor specIfic treatment
; ;
AQUEOUS: SOLUTION OF ALDEHYDES
FREIGHT DESCRIPTION: CHEMICALS, NOIBN
DANGEROUS ARTICLE DESCRIPTION: NONE
DOT WARNING LABELS REQUIRED:
NONE
SECTION III-TYPICAL PHYSICAL DATA
APPEARANCE AND ODOR
----.
'SPECIFIC GRAVITY
Clear liquid, formalin odor L 063 to L 075/ 20/200C
BOILING POINT ¡oF) PERCENT VOLATILE
o 0 CBV VOLUME)
Slightly less than 369 F/1S7 C (decomposes) 100
VAi-OR OENSITV (AIR 1)
EVAPORATION RATE
n- BUTYL ACETATE. 1)
-- -~~-_.
VAPOR PRESSURE
o
@20 C = 17 mm Hg
Greater than 1
1--,
SOLUBILITY IN WATER
Complete
, ---- ------- ~~.£=TIÖ~"~.FIÃI~N~_~j~C?SION HAZ!'3°.E.AT~_ ~ EE- ~~ .~~=
f-LÃ'šHPòïÑ-T{.i:Clhodj ¡FLAMMABLE: LIMITS I.., u..
'. (pe:~Ce:NT BV VOLUME) -- '-' , - - --
None __,_, _,______,______,__ __W~_, .BJA__
FIH'EEX1ïNGüišHïNG M-ËõïÃ----
_,_ ,___ __~_o..LA2£~i~~l~m~L,_.,_._"_,
::'PECIAL FlkE FIGHTING PROCEOURES
----....-- -- -...-------- ...-------- ...------.-- -
__ _ ,____" _~9!:_~lic~,~J~_"'_ ,.__:____p_____,..
- ._------ ----.-.---.---- -....-.-..-.-- --- .---.
l..'NL'S U A CfiR'i:'-Ãr~DExPLosï ÕÑ'HA ZA Res--
Not Applicable
--.---'
...- ---- ...---.----.
_______ .0_'- ____. _ _.. '".._ .
.._-_.~----_._--_. ,.--.--" "
I :.....ž';. R"t)OÙ~- p¡¡õ"öüëT'š""Õ-';-C-OMBUSTïõÑ-"-
Not Applicable
-.---------------
-------
-~~- --':--=~-~:':'::';"".~--=--'='''~;';~~----'"''''''='"''~~' ...:.;:-_-==-...:...;..~~~~~~-_. _.:=~..~-:-_::,..:.=:.::::.-.--=-=-::.~~:.-:-;:.=-~-:~
TH:S 1~;~::)?M;.llaN RELATES O~LY TO THE SPECIFIC MATERIA.!.. DESIGNATED
A"O I.IAY NOT 8!: VALID FOR SUCH MATêRIAL USED IN COM8J'~ATlON WITH
A~IY OTHER I.'AìERIALS OR I~/ ANY PROCESS, Such inlotr.1at,on is, 10 Ihe best of
BC Ch;,rn,.:a'$ knC''''''''~1! and bel,e', accurale bI'Id .el;able as of Ihe d3te indicated.
HOWEVER, NO REPRESENTATION, WARRANTY OR GUARAN1EE IS MADE: AS TO
ITS ACCURACY. REUABIUTY OR COMPLE;TENESS, IT IS THE US[R'S
RêSPO';SI8IUTY TO SATISFY HIMSELF AS TO THE SUiìASLE~;~SS A!\¡O
COM?LETENESS OF SUCH INFORMAnON FOR HIS O'.vN P;;HlCUL"-R USE,
21
e
--
;
SECTION V· HEALTH HAZARD DATA
THRESHOL.D L.IMIT VAL.UE
Rats survived 8 hour exposure to saturated vapors.
)~~dictab1þ:ªr~1~oggd exposure to vapors by humans is irritating to-
EFFECTS OF OVEREXPOSURE ACUTE e es & res ~ a or assaoes.
CHRONIC Prolonaed skin contact causes faint redness & tannina effects.
EMERGENCY .AoNP FIRST .AoID PROCEPURES
Followina contact: Flush eves & skin with water for atle...~r
fifteen (15) minutes. Remove victim to fresh air. artifical respiration if
necessarY. CALL A PHYSICIAN.
SECTION VI· REACTIVITY DATA
--
ST ABIL.ITY CONOITIONS TC" AVOID
U~JSTAalE
STABLE X NOT APPLICABLE
INCOMPATIBIL.ITY (MATERIA~ TO AVOID FOR PURPOSES OF TR.AoNSPORT. HANDL.ING a. STORAGE ONL.Y)
Transport: 5 t.ore in baked phenolic-lined steel or 55. 01; in approved reinforced
vessels. Heating & insulation is indicated, as required. Avoid hi-temp.
HAZARDOUS DECOMPOSITION PRODUCTS
Aldehydes: Avoid inhalation, skin, & eye contact.
,
SECTION VII . SPILL OR LEAK PROCEDURES :
STEPS 10 BE TAKEN IN CASE MATERIAL. IS RELEASED OR SPILLED Shut off source if possible. Advise I
I
authorities if substance has entered a water course. I
WASTE DISPOtAL (lNS,URE c01"P~IIY WIT,¡ \5'C£'jL DISP~AL REGULffi'ONSci d'l t 'th t Recover by
onta~n Sp1 e ~qu~a 1 n san or ear an 1 u e w~ wa er.
purnping or with suitable absorbent. If spilled, it may be possible to deactivate
the solution carefully with ammonium hydroxide or w/aqueous sodium bisulfite to
sT1ghtly baS1C.
SECTION VIII - PERSONAL PROïECTION INFORMATION
RESPI RATORV PROTECTlpN . .
Use approved respiratory protection such as a1r supp11ed if in enclosed spaces..
LOCA'LE~HAUST " . ISPËCÏAL
Not needed in open/unconf1ned I
MECHANICAL ICUlad)~EA
Forced vent~lation if needed. -1-_ __
PR'(:H-¿-é"Ti'VEGLOVES ~EYE PROTECTION .
Chemically r~sistant glove~__1 Approved chem1cal splash goggles.
ö'-r"Eq PROTECTiVEEãülPMENT
Protective apron of rubber, neoprene, or plastic.
VENTILATION
SECTION IX - HANDLING AND STORAGE PRECAUTIONS
;'RECAUTION5 TO BE TAKEN IN HANOLING ANa STORING
Stored in baked-phenol ie-lined steel or 55. or approved reinforced plas!~.<:,_,_
._--~_.
vessels. K~ep containers closed when not in use/avoid hi-temp. Wear protective clothing &
--.. -----------
OTHt:R P"ECAUTlONS
accessorie'S-as dešcribed':-
NONE
.-.-.--.---.--.------
---..-- ---'--'-'---'-" ._.-
~-ÃT-E'-ÕF-;5SUE---"--- APPAOV;D Bv_.ÆÞ'l~~'~:'1 / Reg~,.c~e~g:~'~;18;~
~ l NEW DREv,SED: SUPERSEDES TITLE:' {/ ~dus{riai -Hygiene Director
p~_.'":,:,:. . - - ----..;..--.-=---- - ---.=:-:---....;..-..:..==-.=.=....=: --,:.-.-' - -- _. -=-:.=-=--..._-_._~_.--~
22
~~'
-: .~" '\?
,
e
e
--. ----.
.-.---
- CHEMICALS
MATERIAL SAFETY DATA SHEET
PROOUCT
-
(ApPlolfød by U.S. Oøparun'lnt of L.bor., ".,unri.//" simil.r· to Fonn LSS-OOS-41
SECTION I·IDENTIFICATION OF PRODUCT
MANUFACTURER'S NAME EMERGENCY TELEPHONE NO.
BC Chemicals
AOCRE5S (Numoer,-slrcu. CilY, ~tatt! and ZiP Code)
1511 SO. Union Ave. Bakersfield, Calif. 93307 (805) 832-1360
,
TRAOE NAME CHEMICAL NAME
BC Microbiocide 2000 Gluteraldehyde
CHEMICAL FAMILY CHEMICAL FORMULA
Aldehydes DHCC3H6CHO
SECTION II-HAZARDOUS COMPONENTS OF MIXTURES
A precise compositlo:1 of this product is proprietary information. A more detailed disclosure win be provided by BC Chemicals 88 privileged Info~ation
upon request In case ot need for spec¡ßc lreaÞnent.
AQUEOUS: SOLUTION OF ALDEHYDES I
FREIGHT DESCRIPTION: CHEMICALS, NOIBN
DANGEROUS ARTICLE DESCRIPTION: NONE
DOT WARNING LABELS REQUIRED: NONE
.-----.--.
SECTION III-TYPICAL PHYSICAL DATA
SPECIFIC GRAVITY
H20=1
1.131 @ 20/200C
APPEARANCE ANO OOOR
CLEAR LIQUID, SHARP ODOR
-,-
BOILING POINT (oF)
760 MM Hg=101.2oC (214.20F)
PERCENT VOLATILE
(BY VOLUME) 50 (WATER)
. -.---.-----.----..-... .._--_. .-.--.-----.------
----- --.-------..---
EVAPORÄTlON RATE
(n-8U"rYI..ACETATE-li 0.93
'.'APOR PRES5URE
----- ------.....--.--. ....- --...----.-.-.-.
.----------.-..------.
.-..---...
VAPOR DENSITV (D,IR 1)
'OLUO'L,TY '" ~:~E;:::C:~~:E---- -1------------
L_____~-=-,_______õT--·~~N-~~,(-FIR-E AND ~PLOSION HAZARD D~iA ~'"J:- -.----+-------
FLA$:-o ;>ûlNT (.lfe/hod) None, C.Leve.LdJ,anu open cup lLAMMABLE I-IMITS I..el I U.'
(PERCENT BY vOI-UME) -""=-C:-:'~''7''i---:"!..--'
ASTMD92¡ None, Tag Closed cup ASTM D-56 .U metuano ,U metua 0
FiH'£ËxTINcuïsHIr;¡'GliM::DIATf-Water'is boiled ó-ff, -res-iduãl cãñ'cur~"-'Úsë--water sp'iay car on-" -- '~'
dioxide, dry chemical, alcohol-type or universal-type foams applied by mfgr. recommended tee
~pŒiÃL;ïRe:-F-ïG¡::¡;:ii',¡-G'PROëED-URËŠ-'-- _____.._______d_~ -----,-,--._-----'-,----', ,
1.._ ,-.-".. ',_,...~e~~~c~~~~~::~,~.Èrea,1:!1_~::,~_~f:?par~.t~~,_.~1;:~___ ,-,. ----". .,., ',- ___.._,___'_d__'_._,,__'_,· -- '1
~ J
[L'NÜSlJÃL"F!RF.AMÖ'Ë;",zPLOŠiÖ¡:¡'H'ÀZ-ÃROŠ--- -, ,--- ____.____.________u __.._____.,_________'u_'_'__·, -' :
I
I
\
I
I
i
NONE
._. _..__.._ .___.._.. __0'_.. _...__._._.__ __.___.__..__.__ ..-.- .---
.-.-..---- .-..-. ..
___.. __. ._0'_'. ....
.'Ã-i'"iï(Ir:'..Js-,;;¡oõi.ïu5'Õ'FcoM"åUšï';õÑ'- --- -..-.-,--------- --,---' ---- ---. ,- _'.'_u__, ,--
~,~"'_,, _~ :~_ ~1J~p.in_pgJ!@y-,.P.~_oßµc.e _,ca:¡;þon_ ffi.QnO.J.Cig,IL é!,I1ªLq!"_S<;1rb_Q~ ,_c;ì..i9;J,:{.iq~""",-~=~,"-,-=-~- ,".
. .- -
TH'S INFOBMATION AELATE:S '.JNLY 101'1.11:: SPECIFIC MATERIAL DESIGNATED' HOWEVER ~IO R¡;:PRI::SENtATI0N WARRANTY OR GUARANTEE: 15IAA','~ ,\ti TC
AND M""f N01 BE VAUC FOR SUCH MATERõAL USED IN COM81NATION WITH ITS ACCURACY. RELIABILITY OR COMPLETENESS IT 15 THE us¡;r, ;',
ANY 01 Ht:R M¡. rERI.A,LS OR IN ANY PAOC¡;S5 Such ¡rlarlT,:¡tIOn IS, 10 the besl 01 AESPONSI81UTY TO SATISFY HIMSELF AS TO THE SUI~ "-8l ENI::S5 "~~j1
ac C~,~m"~àl:; kllowledge and bellEfI accur~tø and 'ehaDle liS ot ItIe oate indicated. COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PART CUIAR :,.'::;1:
e
e
SECTION V· HEALTH HAZARD DATA
THRESHOL.O LIMIT VALUE 0.2 ppm ceiling, ACGlH (1979)
EFFECTS OF OVEREXPOSURE ACUTE If swallowed-nausea, if inhaled-chest discomfort, bronchitis symptom
cHRoNlcProlonged or repeated skin contact may cause rash & sensitization
EMERGfNCY P.ND FIR$T AID PRS.CEOURES
Swa low1ng: G1ve 2 g asses of water-induce vomiting by putting finger down throat. Call phy-
sician/Skin: Flush skin with plenty of water-remove contaminated clothing-wash clothing be-
fore wearing again/Inhalation: Remove to fresh air, call physician if symptoms persist/Eyes:
flush eyes with plenty of water at least 15 min., get medical care eye specialist at once
SECTION VI· REACTIVITY DATA
--
ST ABI L.ITY CONDITIONS TC'I AVOID
UN5TA3LE Avoid high temperatures 200oF)
(removal of water,
STABLE X
IN~OMPATlBIL.ITY (MATERIAL.S TO AVOID FDR PURPOSES DF TRANSPORT. HANOL.ING a. STORAGE ONL.VI
,
Avoid contamination with acids any alkalies.
HAZAROOUS OECOMPOSITION PRODUCTS
Burning may produce carbon dioxide and/or carbon dioxide.
SECTION VII . SPI LL OR LEAK PROCEDURES
STE.PS TO BE TAKEN IN CASE MATERIAL. IS REL.EASEO OR SPIL.L.ED
. , 'd disc ar e to natural waters
Small spills flush with large quantites of water.
Low cone. 0
Large spills
posal. Spilled material can be decontaminated with careful application of sodium hydroxide
WASTE OISPOS.A.L (lN$URE CONFORMITY WITH L.OCAL. DISPOSAL. REGU1.ATIONS) .'
ot inc' e ator fire mix wit -- a
where permitted by Federal, State and local regulations.
e s
l_:rate
r--'
í fi :;:SPI RATÕf~VPROTËëTïõN
¡--'-----'-J-öë.AL E~~~~S~llP.Pl.ied ma!'>k in .hÜJh, conc~nt~PEÍ'I.ALC;apors are .-
r v eye or nose irritating,
V-NTI ATlON ~ø('t>"n'C'al ...nnm "ønt-,l"t-,n'"
Co,,,, MECHANICAL rGe11uqJ) , IOTHER , , . . d
" d__' _' ____ Expecteà to b: sat1sfactory I , spec1al forced vent11at1on may be req 1re
1"~orECTlVE GLOVES =rYE PROTECTION f
Rubber Vapor-proo goggles.
~. .. .._-~...- -~... ------.----------.-..-.--..-- .
¡.JrHER PRorECTlvE EQUIPMENT
Eye bath, safety shower, rubber overshoes
SECTION VIII - PERSONAL PROìECTION INFORMATION
..._____0-_--- .__._...__"
! __0___-..
i SECTION IX· HANDLING AND STORAGE PRECAUTIONS
¡,~'RE-¿Aür:O;:¡~;:¡õè-t=. TÃKE~;¡NHA-ÑDLïÑGÃÑQ-šTõRING Use w1t:nåàequate vent~lat10n. wasn
¡", ' .l2?E-ª-ling_..__Avo~d breathing vapor. ~~,C?~~e~.:.yes, ~.::.. sk~n, clothing.
I closed. FOR INDUSTRY USE ONLY.
!
í;:¡¡;"t::'M PÅËëAuTlo-r~-Š'o-:-'-"---, -..--- ,----
I . We~1:'__9..~gg,!~~,_?r;_ J.~~shield and rubber gloves when handling.
i
,
,. ,on' 0 __n_'_ ,- "_______,__
:;A' E OF ISSUE
l ¡ ~;tW ,[]REVISED: SUPERSEDt:5
..~---.._~.~~;.::~-------- - -.
thoroughly arter
Keep container
--
..-------
},,:::-;:u_/ f/
TITLE: 7" .;¡
- - - --
zt;: ___0
~" .:_--------- -'-'.--
24
e
B.C. AMAZING
e
B.C'. AMAZING
1 gallon
5 gallons
ECOLOGICALLY SAFE: The ingredients in B.C. Amazing products are bio-degradable -
they will break down into natural components without harming the environment. There
are no phosphates, enzymes, or other chemical ingredients known to cause pollution, in
any B.C. Amazing product.
ECONOMICAL: B.C. Amazing products are concentrated. That means you use less - a
. little goes a long way. There are no "fillers" that serve only to bulk up a product and
make it look like you are getting more than you are.
EFFECTIVE: There are no better products of their kind on the market than B.C. Amazing
products. Because they are different, because they do not contain some of the harmful
ingredients many people are used to, when they clean their stoves with B.C. Amazing
and find there are no dangerous fumes and no skin irritation.
The effectiveness of products as good as B.C. Amazing can be unexpected and
surprising. When the results are so far superior to most other products, it takes some
getting used to. So suggest to every ..customer that directions be followed carefully,
rather than using B.V. Amazing products "the way they've used that kind of product
before!"
VERSA TIUTY vs OVERKILL: Although we use the term "all-purpose cleaner" on the
label of B.C. Amazing, since that has become more or less the generic term for the type
of cleaner it represents, there really is no such thing as an "all-purpose" cleaner.
So-called all-purpose products tend toward "overkill". They cater to man's search for the
easiest way, rather than the best way. But no liquid cleaner designed to be used for
scrubbing floors can be made powerful enough to remove stubborn stains, with being
too powerful for gentler tasks.
That's why B.C. Amazing products have been carefully formulated to provide safe,
effective, and appropriate results for the task to be done according to how they are
used. The versatility of B.C. Amazing products lets YOU decide how strong a cleaner
YOU need for each job. .
The label on B.C. Amazing describes this product as "a modern, soapless product made
from a balanced formula of organic ingredients, completely free of skin and eye irritants".
Let's look at each term in the name of this remarkable personal cleaner and see why we
can make the claims we do for it:
SOAPLESS: There are no alkalies, no phosphates, no soda ash, no artificial chemicals,
or other harsh, irritating or polluting ingredients in B.C. Amazing. It will leave behind no
soap scum or other residual waste. It rinses away cleanly and completely without drying
the skin or leaving residues or washed surfaces.
ORGANIC: The ingredients in B.C. Amazing are organic, that is, composed of the same
types of carbon molecules that make up natural living matter. Thus, they are not only
mild, but also biodegradable - capable of breaking down and returning to the earth,
without endangering any living thing.
CONCENTRATE: A little bit of B.C. Amazing goes a long way. That's why we offer a
mixing bottle to go with it. All directions on the label are for B.C. Amazing diluted half
and half with water - then measured in teaspoonfuls! That's real concentrated action -
and real economy for any "personal touch" cleaning job!
'I ,
e e
IMPORTANT: To prepare B.C. Amazing, fill a mixing bottle half way with water first; then
add the Concentrate; stir or mix gently.
TO DEMONSTRATE B.C. AMAZING: Always use B.C. Amazing according to directions,
in a No. 501 Jiffy Dispenser with No. 502 Flip-top on the 16 oz. size.
ECONOMY: Point out that even after dilution, only a very small amount of B.C. Amazing
is needed for most ordinary jobs.
GENTLENESS: Place a drop of B.C. Amazing from the mixing bottle into the hand of
your prospect. Ask her to rub it in as she would a hand lotion. As she does, explain that
B.C. Amazing is gentle enough to use in bathing an infant, and that in addition to
cleaning, it actually acts much like a hand lotion in moisturing and conditioning the skin.
Rinse the B.C. Amazing off with a damp washcloth or under a tap.
NON-FLAMMABIUTY: Remove the cap from a bottle of B.C. Amazing and wave a match
back and forth over the opening. Point out that the fumes do not ignite. Next, extinguish
the match by dropping a bit of B.C. Amazing onto the flame. (A wooden match provides
a better demonstration than a paper match.)
EFFECTIVENESS: Mark the back of your hand with lipstick and with a ball point pen,
then massage in a dab of B.C. Amazing. Point out how the two difficult-to-remove blots
immediately begin to be lifted from the skin by the B.C. Amazing handkerchief, then . . .
. . . show the handkerchief stained with the lipstick and ink to your prospect. Rub the
stain in for better effect. Explaining that the dab of B.C. Amazing you cleaned your hand
with is still enough to clean the handkerchief, dip the handkerchief under a faucet,
squeeze it clean, and display the spotless handkerchief to your prospect. Point out that
B.C. Amazing is harmless to fine fabrics.
Smear a steak of shoe polish, paint or grease across your palm (if you want to let this
dry, you can demonstrate the match test or ask the prospect to feel B.C. Amazing for
herself at this point). Point out that this technique provides excellent protection for the
hands while doing a job of painting, repairing greasy machinery, gardening, etc.
Finally, rinse your hands in a bowl of water or under a faucet and show how the
"invisible gloves" have helped protect your hands.
AUTO WASHING: Mix 2 capfuls of B.C. Amazing to a bucket of water. To remove tar
from any auto finish, use the Jiffy Sprayer with B.C. Amazing, medium or strong solution,
then wash with B.C. Amazing to avoid stripping wax from the finish.
SUGGESTED DEMONSTRATION AIDS: Jiffy Dispenser with Pump; bowl of water; damp
washcloth; handkerchief; lipstick; etc. You'll want to change or add demonstrations as
you gain experience, of course - but always practice before you use them on a
prospect.
27
B'P.W.101 PARAFFIN DISPER!NT
5 gallons
55 gallons
BC P.W. 101 Paraffin Dispersant
BC P.W. 101, a~ effective w~ter-dispersible par.~ffin-rem~val additive, is a high-flash, low-odor
hydrocarbon solvent-d!spers~nt. This bl~nd helps solublh~e and disperse paraffin and asphaltic deposits.
A water-external dispersion made with BC P.W. 101 IS an excellent substitute for hot-oil treatments,
especially where oil spills and contamination are critical.
Most paraffin dispersan,ts do not function in aqueous systems as well as BC P. W. 1 01 nor do they
have as effective paraffin-disolving properties.
APPLICATIONS
Well bore and Tubing Cleanout
BC P.W. 101 can be dispersed in water or acid to clean tubular goods of: paraffin and asphaltenes
allowing resumption of normal production, paraffins, asphaltenes, and other hydrocarbons prior to other
stimulation treatments.
BC P.W. 101 can also be used in aromatic solvents and/or mutual solvents to help water-wet solids
as the heavy hydrocarbons are solubilized by the solvents.
The proper concentration of BC P. W. 1 01 to be added to water for optimum cleaning depends
primarily on the amount of paraffin present, the hardness of the deposit, the adhesiveness of the deposit,
and the temperature at which the paraffin is deposited.
A general recommendation is:
Cold Water (below 75°F)· Use 10% by volume of BC P. W. 101
Warm Water (75· 1 OOOF)- Use 5%by volume of BC P.W. 101
Hot Water (1 00 - 150°F) - Use 2% by volume of BC P.W. 101
Very Hot Water (150· 200°F) - Use 1 % by volume of BC P.W. 101
To compute volume:
Diameter of casing
Standing fluid in casing
Feet of perforation in casing
CAUTION
When used for tubing cleanout, the water temperature should never be hotter than the formation
face because any paraffin that has melted in the treated water will re-deposit on the colder formation
causing damage.
Flow Une Cleanout
BC P. W. 101 can be dispersed in water to clean flow lines. The above treat rates apply to flow-line
cleanout. However, the water should be heated to as high a temperature as practical for most efficient
removal. If the flow line is long and/or cooled by water (offshore), it may be necessary to increase the
concentration of BC P.W. 101 to 5%. BC P.W. 101 will work in cold water at higher concentrations. If
the water starts off hot then cools, the BC P. W. 1 01 will keep the removed solids dispersed.
NOTE
If large amounts of paraffin are deposited it may be necessary to use several lower-temperature
treatments so as not to remove too large an amount of paraffins at one time, thereby physically blocking
system.
MIXING PROCEDURES
BC P.W. 101 can be added to any aqueous fluis and a uniform dispersion can be achieved with
only a small amount of agitation. If left static, the dispersion of BC P.W. 101 in water is stable up to an
hour. Reagitation prior to pumping the fluid is recommended.
SOLUBILITY
Soluble in hydrocarbons
Dispersible in fresh water, salt water, acids
?R
~-1,
e
e
This product is available in bulk shipments and 55 gallon NR drums. Keep drum openings closed to
prevent product contamination and evaporation.
BC P. W. 101 contains no organic halides, heavy metals, or other substances known to be harmful to
process equipment or refinery catalysts. No special storage and handling precaution is required. Avoid
prolonged and repeated skin contact. In case of contact with skin or eyes, flush exposed area with
water.
PROCEDURE ,
Batch feed BC P .W. 101 per general recommendation at point "B". Let it sit for approximately 24
hours. Be sure BC P. W. 1 01 is completely mixed with fluid in well. Put well back on the line. BC P. W. ,
1 01 will perform an effective cleaning function throughout the entire system including all flow lines and
valves.
To eliminate future paraffin buildup, a daily maintenance program should be followed. Inject at point
"A" 2 quarts of BC P. W. 1 01 every 24 hours per 1 00 barrels of produced oil.
The simple and inexpensive procedures described above will virtually eliminate costly down time due
to paraffin cake buildup.
29
·
e
e
-....--..-. ._~.- .----
COREXIT
-.
MATERIAL SAFETY DATA SHEET
(Appro,,"'; þy U.s. DI!P.run.nr of L.bor., ·'.u.nri.lly ';mil.r~ to Form LSB-OOS·4
PRODUCT
CHEMICALS
SECTION I-IDENTIFICATION OF PRODUCT
MANUFACTURER'S NAME EMERGENCV TELEPI-fONE NO.
B.C. Chemicals Inc.
AODRESS (/Vumlil!,.~rl!u. City. SIIIII! IInlt z./J' c;odlJ (805) 832-1360
1511 South Union Ave. , Bakersfield, CA 933.07
TRADE NAME CHEMICAL NAME
B.C. PW 101 Not Applicable: blend of materials
CHEMICAL FAMILV CHEMICAL FORMULA
Surfactant in aromatic solvents Not Applicable: blend of materials
SECTION II·HAZARDOUS COMPONENTS OF MIXTURES
A'preclse ~positlon of this product, Is proprietary Information. A more detailed disclosure will be provided by BC ëhemic:als as pr1vileged i~f~Ûon
upon request In case 01 need 101 spec¡ftc treatment.
Blend of oxyalkylated alcohols and oxyalkylated alkyl Phenol in
glycol ether and aromatic solvent. I
APPEARANCE AND OOOR
Light blue liquid
BOILING POINT (OF)
358°F/180°C
SECTION III-TYPICAL PHYSICAL DATA
SPECIFIC GRAVITV
0.900 @ 60o/60oF
.--
VAPOR PRESSURE
EVAPORATION RATE
In- BUTVL ACETATE" 1)
0.55
VAPOR DENSITV (AIR l)
gr~ater than 1
SOL..UBILITY IN WATER
25% by volume, forms emulsion
SECTION IV·FIRE AND EXPLOSION HAZARD DATA
Fï:'ÚHPOiNT (Method)
PM No. 2600 1300F
FiFiEIiXTINGUISHING MEDIA
_1-,.__..
Extinguish with dry chemical(carbon dioxide or foam)watersp~ay may be in-
',PËï:IA¡:-FIRE FIGHTiNG PROCÊDURES - .----,
,_ ~j:(e~_t,~y~~.~.~ti.~~!.shin(;:L~~nt~..~_L~ir~~~pos~_ð.: ._!!.l:Efa_c_es and protec..E----'-1
__~.E~r,so.~n~l wit~_atersp:r:.~.
UNUS~J"'L.. FIRE AND EXPl.OSION i-iAZARCS
_,_ª~_~pirator-y"_~~~ct:ion required for fire fiqh,tin~~rsonnel..:.___,_,___J
I
----. ---.----..
I~'Ä iÄ p,-óoü-s'p RÒÕÜ-¿i'SCFCõ'M-šuS T ION
Carbon monoxide, carbon dioxide,
smoke,
fumes,
aromatic volatiles.
..______ d__ _ _-.:.._~}
.._. .. ~--'-"""-_.'-~"---
- ______-----.. .---.__.___0.
THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED
AND MAY NOT BE VALID FOR SUCH MATERIAL US(!D IN COMBINATION WITH
ANY OTHtòR MATERIALS OR IN ANY PROCESS, Such information IS. to the best 01
BC Che'!lIcals ~owledge aIId belie:, accurate a.,d reliable as 01 the date indicated.
HOWEVER, NO REPRESENTATION. WARRANTY OR GUARANTEJ: IS MADE AS TO
ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S
RESPONSIBIUr¡ TO SATISFY HIMSELF AS TO THE SUITABLENESS AN;)
COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE
30
e
e
SECTION V· HEALTH HAZARD DATA
TI-fRESI-fOLO LIMIT VALUE UNKNOWN
EFFECTS OF OVEREXPOSURE A~t~~~~yJ.E~i¡ß~à~gedOtfi~~ng~n~h~y~~i~~dvã~ð~~r~¡~rïr~îEã£~es.
eyes. J?rol~n~ed skin contact may cause dermatitis and skin
CHRONIC J.rrJ. a J.on.
EMERGENCY ANO FIRST AIO PROCEDURfS
Remove to fresh air. I not breathing, apply artificial respiration and CALL
A PHYSICIAN. Wash eyes with plenty of water for at least 15 minutes. Wash
skin with soap and water.,
SECTION VI· REACTIVITY DATA
STABILITY --
CONDITIONS TO AVOID
UNSTA3LE
X Not Applicable
STABLE
INCOMPATIBIL.ITY (MATERIALS TO AVOID FOR PURPOSES OF TRANSPORT, HANDL.ING . STORAGE ONL.Y)
Strong oxidizing agents and mineral acids.
I-fAZAROOUS OECOMPOSITION PROOUCTS
Not Applicable
SECTION VII· SPILL OR LEAK PROCEDURES
sPéH,o ~V~~Er-rI~8iàs'1r~ífj!êL; IS~b¥sffi<tR !iJ'&èrrct: e , if possible to do so safely. Advise
authorities if substance has entered a watercourse, sewer, or has contamin-
ated soil or vegetation.
wð.òV¡ €1ff9,.SA's P '1$ffé á°r-r£&~'Ð1 w~lrtficb9Œ'O~t ~M1f-ð1I°â'Wd ---'
dilute with water. Recover by
pumping or with suitable absorbent. Consult an expert on disposal of recover-
ed material.
f SECTION VIII- PERSONAL PROïECTlON INFORMATION
¡:ŒšpiRAiQ~Y PRO;(E.!:'t!ON It used J.n con J.ne sºaces or 0 er poor v yen ~
use NrOSH7ML~A approved respJ.ratory protect~on such as a1r-supp
i..OCAL Ot;iAUST SPECIAL t ace ve 0 C J. Y J. n
PrOV~de greater than 60 fpm hood spaces.
VENTILATION MECI-fANICAJ,..IG~""'al) ., ~OTHER
Explos~on-proof vent11at1on equJ. ment
__._.__..___ 4'_ .______._-....-.- ...---.--.
PROTECTiVE ':;LOVF;S J E,:o'£ PROTECTiON
Chemically resistant gloves, ~nemica splash 90gŒles
ÜT-HË'¡¡-PROTËëï'ïVE eQUIPMENT·---'--·n'-,-_-- ---,--, ---'
Usually nc:~~eded
-----------
-----
---
[------ SECTION IX· HANDLING AND STORAGE PRECAUTIONS
(R'ECAUiïòNS TOB"ETÃ-K'E"NiN HANDLING AND STORINcObserve hazarã preéau~To-ñ-Š-w~ tñ--empEieaëo-ñ-'=
I, _t:ë;iir:!.~ s. Ke ep con t~,~ n~.::.;;__c 1 0 s:..~__whe ~.,_~:,~,!..::__~,:.=-.:_.~~~ ~_,~~~~~¡~ hea t, s p¿¡ r k s ,
and open flames.
. M ___..__.
. .0.. ..______._.__~._._. _________.______..__________.__.__..___
OTHER PRECAUTIONS
~~E!2.._awªy__~_rom If_~~,~,L spark~..2nd ~pen _ flame s .
-----.... --_#- -..-.- .--.---------
r' NEW L]RE'.JISEO: SUPERSEDES
":a"'-_':~-"~ -.--..-----
----- .- .
.'0 1 ,--------' --'-----~
/7 ' '
j;;PPROVED 8Y-...J:~' ~U.;!::I..<._..____,____"_.._ '.- ,,-,
TITLE: Director O( Industrial Hygien~ .'
'or' - _ -
DATE:.OF'~~'E-'·-------·--- -----
31
RESINS (Bulk or 50 gal bbls.)
GEL TIME PEAK PEAK VISCOSITY HEAT FLEXURAL FLEXURAL TENSIL
MINUTES EXOTHERM TIME 77F THIXOTROPIC BARCOL DEFLECTION STRENGTH MODULUS 'STRENGTH ELONGATION
PRODUCT TYPE PROMOTED 77 F F MINUTES CPS INDEX HARDNESS TEMPERA TURE PSI X 10' PSI PSI % COMMENTS
GENERAL PURPOSE LAMINATING RESINS
Allek 063,9 Rigid Ves 7·11 310,360 16'24 400,600 2,7'3,6 38,44 150 14,000 48 7,600 1,7 Moderale CUle, lasl weUinQ resins with excellent
drain resistance.
Allek 083, 14 Rigid Ves 12,18 310,360 27,31 400,600 2,7,3,6 38,44 150 14.000 46 7.800 1,7
Allek 063·19 Rigid Yes 11·21 310,360 30,35 400,600 2,7·3,8 38·44 150 14,000 48 7.600 1,7
Allek 298,9 Rigid Yes 7·11 330,400 16,20 400,800 2,7'3,6 40·44 165 18,000 5,0 8,500 1,7 fasler curing. general purpose laminating resin than
the 063 series,
Allek 198·14 Rigid Yes 12,18 330,400 22,27 400,600 2,7·3,6 40·44 185 16,000 5,0 8,500 1,7
Allek 2i!8·19 Rigid Yes 11,21 330,400 30,35 400,600 2,7'3,8 40·44 165 16,000 50 8.500 1,7
Allek 156,13 Rigid Yes 11-15 330·400 22,26 400,600 2,7·3,8 40·44 165 16.000 5,0 8,500 1,7 Moderele gel lime wilh good hardness developme
RESINS FOR USE IN ALUMINUM HYDRATE AND VITROFIL FILLED SYSTEMS
Very resistant 10 drain when '.Ued. gtves good cure
Altek 098 SemiRigid Yes 6·10 330·390 12·18 100·130 1,7'2,1 33,41 NIl. NIl.· FiUed WIATH and hardness development.
Allek 315 SemiRigid Yes 6,10 330·390 11-18 100,130 1,7·2,1 34,44 NIl. NIl.· FiUed WIATH Fasler curing verSion 01 Allek 096,
RESINS FOR SYNTHETIC MARBLE + ONYX
Allek 035 Rigid Yes 8,12 265,310 18'24 700,900 NIl. 36·44 150 12,500 5,0 6.400 1,2 Tops. llals. moderale gel. moderale cure,
Allek 141 Rigid Yes 7·11 265,310 11·22 900·1100 NIl. 36·44 150 12.500 5,0 6,400 1,2 Tops, llats _ &mal integrals, last gel cure _ darnold,
Allek 200 Rigid Yes 9·13 275,305 18,24 1300,1100 NIl. 37·42 150 12,500 5,0 6.400 1,2 Tops. inlegral bowls·IeSS shrinkage lhan Allek 035,
Allek 297 SemiRigid Yes 14·18 260,290 30,34 950·1150 NIl. 34·39 110 11.000 5,0 6,000 22 Good lIe.ibiüty lor manufacturing then marble sheet.
Altek 319 Rigid Yes 11-16 310,340 25'35 1050·1250 NIl. 38,46 165 16,000 5.0 6,500 1,7 E.ceUent color,recommended lor high quality ony.
applicalions,llals and inlegrals. rapid darnold,
Allek 333 Rigid Yes 5,9 310·340 10,16 900·1100 NIl. 38'46 165 16.000 5,0 8,500 1,7 Tops and llals . lasl gel and cure,
Allek 334 Rigid Yes 8·12 265,310 16,24 2600,3400 NIl. 36·44 150 12.500 5,0 6.400 1,2 E.lremely high viscosily lor lops and llals, Moderale
gel. moderate cure. Exhi~ts Aow8r shrinkage
RESINS FOR CLEAR CASTING ANO DECORATIVE USES
Allek 331 Rigid Yes 11-16 315,335 30,38 400,600 NIl. 38,46 16,000 50 8,500 1,7 Excellent color. recommended tor clear cashng Of
165 decorat",. appbcations. moderate gel. moderate cure.
ISOPHTHALlC RESINS
Allek 1660 SemiRigid Yes 11-15 360,420 21,27 400,600 2,4,3,2 30·34 210 17 ,000 40 10.000 3,6 Moderate corrosion resistance. e_hlbihng high
elongation.
Septic tanks. aprayer lanks and 'eeders
AlIQk 264 Rigid Yes 11-15 400,425 21,27 400,600 2,4'3,2 38·42 220 16,000 5,0 7,000 ' 1,8 Moderate corroSion reslslance. moderale elor¡:.'·..··
higher heal deflecllon lemperalure. Similar apph"'°I,,'It:)
10 Allek 1660,
Allek 336 Rig,d Yes 11-15 400,425 l'\ 27 400,600 2,4,3,2 Oood Corrosion resistance. good heal detlecloon
temperalure
TRADEMARK
Alpha Resins
e
e
6.
Justification and rationale for
locations, construction, sampling
contaminants to be analyzed.
monitoring well
frequency, and
7. Sampling equipment and procedures.
8. Analytical methods and QA/QC procedures.
E. Surface Water Runoff (off-site)
1. Facility map showing on-site drainage patterns and
evaluation of off-site migration.
2. Area map showi ng off -site drainage patterns and
potentially impacted surface water bodies.
3. Off-site surface soil and surface water sampling plans.
F. Air Quality
1. Assessment report addressing potential for air borne
mi g rat i on of contami nants and thei r pub 1 i c hea 1 th and
environmental impacts.
2. Air Sampling Program.
VI. Time Schedul e for RI Work Pl an Impl ementati on From Date of DOHS
Approva 1
A. Field Investigation
B. Laboratory Analysis
C. Interim Reports Submittal
D. Engineering Analysis of Data Collected during RI Process
E. Submittal of Final RI Report
e
e
APPENDIX B
DOHS - SITE CHARACTERIZATION WORKPLAN OUTLINE
I. Site Background
A. Si te Maps
1. Topographic maps showing site location.
2. .Site specific plot plan (including all process equipment,
surface and subsurface piping, tanks and waste handl ing
units) .
B. Nature of Problem (Description of Past and Presnet Disposal
Activities, spills and waste handling practices both on site
and off site).
C. Extent of Problem (Documentation of Suspected On-site and Off-
site Contamination Areas).
D. History of Response (General Description of any Past Remedial
Actions).
II. Quality Control/Quality Assurance (QA/QC) Plan
A. QA/QC Aspects of Sampling
1. Collection of field samples
a. personnel training
b. equipment calibration and maintenance
c. sample collection procedures
d. chain-of-custody forms and procedures
e. sample preservation procedures
B. QA/QC Aspects of Laboratory Activities
1. Verification of laboratory certification by DOHS
2. Laborat.ory sample analysis qual ity, control program
a. internal spikes
b. internal duplicates
c. blind duplicate
d. internal blanks
e
e
Duri ng the purgi ng operati on, purged water wi 11 be monitored for tem-
perature, pH, or conductivity as a function of time or volume. All
records of the above data will be kept in a water-proof fi e 1 d notebook
in the following format:
WELL # DATE PROJ. #
TOTAL DEPTH TOC ,211 PUMP #
RECORD
DEPTH TO WATER TOC 411 PUMP #
GL
TOC GL = BAI L/ I N PLACE PUMP
CALC~ EVAC. VOL. ACT. EV AC. VOL.
SAMPLES: COMMENTS:
After the cal cul ated purge vol ume has been removed, sampl es wi 11 be
collected. With as little interruption in pumping rates as possible,
the pump effl uent is di rected into appropri ate containers. For the
volatile organics, care must be taken not to allow the force of the
sample stream to introduce air bubbles into the sample. These bottles
must be filled completely such that no air is present in the bottle.
Invert the bottle after capping and tap to see that no air bubbles are
present. Appropriate containers for volatile organics are glass bottles
of at least 40 milliliters in size fitted with teflon-faced silicon
septa. Appropri ate contai ners for semi -vol atil es (BNA) are one gallon
amber bottles fitted with teflon-lined seals. All samples will be
collected in duplicate. Field blanks made with organic-free water will
be carried into the field and delivered with samples to the laboratory.
All sampling containers will be labeled with the following information
upon sampling and then immediately placed on ice:
t;;;), Job No
~Date
(meOn Sampler
" ~ ~ .;J (. .. I t \
Source
Preservetlon
Sample No
Samples will remain on ice until delivered to the laboratory. Also at
the time of sampling, the sample will be logged on a chain-of-custody
form whi ch wi 11 accompany the sampl e to the 1 aboratory. One out of
every 10 samples will be submitted to a laboratory other than the
primary laboratory to confirm the accuracy of results.
e
-
Prior to sampling at a site, all equipment which will be placed in the
well or come in contact with ground water will be disassembled and
cl eaned thoroughl y with detergent or tri sodi umphosphate water and then
boil ed or steamed with dei oni zed water. Any parts that may have a
memory for organics, such as plastic pump valves, bladders, etc., will
be cleaned as described above and sonicated, or replaced with new
parts. The inside surfaces of pump tubing will be mechanically cleaned
to remove adhering silt by blowing cleaning wads through the tubing with
compressed nitrogen. Steam condensed deionized water will then be
pumped through the lines to chemically clean them.
Once cl eaned and reassembl ed, pump bl anks will be obtai ned from each
pump by pumpi nÆ; organi c-free water through as when sampl i ng. The pump
effluent will be sampled and analyzed for indicator compounds. The
results of this analysis must be satisfactory before the pump is taken
to the field for use.
During field sampling, all equipment surfaces to be placed in the well
or that will come in contact with ground water will be cleaned prior to
purging or sampling of each well. This cleaning will be performed by
boiling or steaming said surfaces with deionized water.
Immediately prior to purging each well, the depth from top of well
casi ng to top of water surface wi 11 be determi ned to the nearest 0.1
foot and recorded as a portion of the well sample data. The top of well
casing elevation will be determined to the nearest 0.1 foot by
conventional survey methods.
Immediately prior to sampling, standing water in the casing and gravel
pack will be purged from the well using a submersible pump or suction
pump. Any pumping method that introduces air into the well (such as jet
pumping) is unacceptable. For permanent installation, a PVC or Teflon
pump such as the Well Wizard Model 1100 or equivalent will be used.
Portable units for periodic sampling will be Geotech Small Diameter Well
Pump #0500 or equivalent.
The amount of water purged pri or to sampl i ng wi 11 be greater than or
equal to one bore volume, which is calculated to include the casing
volume and the void volume in the gravel pack. Regardless of which pump
is used to purge the well, samples will be taken with a submersible
sampling pump constructed of inert nonwetting materials, typically
teflon and stainless steel.
In the event that the well goes dry duri ng the purgi ng operati on, the
well will be allowed to recharge before sampling. This period will
preferably be less than eight hours, but in no case shall it be more
than 24 hours. If the well has not recharged sufficiently within
24 hours to obtain a sample, it will be considered dry and deleted from
the program.