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HomeMy WebLinkAboutMITIGATION (8) August 24, 1987 -- CRIMINAL DIVISION Kern Co. Justice Building I 1215 Truxtun Avenue Bakersfield, California 93301 (805) 861 ·2421 EDWARD R. JAGELS_ District Attorney Pat Steele Deputy County Counsel Kern County County Counsel IS Office 1415 Truxtun Avenue Bakersfield, CA 93301 Re: People v, B, C. Chemicals Dear Pat: I am enclosing a packet of supplemental laboratory results, which were apparently not a part of the misdemeanor file and which were not relied upon by our office in filing our criminal complaint. Sample 172 pertains to the 4th count of the criminal complaint. which was dismissed in plea negotiations. I have reviewed the file for any interpretive reports etc., from Kern County Health Department, and none are contained therein, As I indicated to you, there are voluminous laboratory results in the Kern County Municipal Court's file, These are a matter of public record and may be requested by counsel for the trust, Should you have any questions or comments, please contact me, Sincerely, EDWARD R. JAGEí~/ Distri,ct At~~ØY), _ ( ,} /i\j(' ( f2- "'-._ /1'. /.:~; '. By .. -.,-.. ..-" ' -~:~~y~~;::~-~\::::~----- JGV&'/ /) cc: Richard Cas1gra~de K ern C 0 u n t y 'if.e-( 1 thO e par t men t I . REMEDIAL INVESTIGATION PLAN B.C. CHEMICALS SITE 1511 SOUTH UNION AVENUE BAKERSFIELD, CALIFORNIA 93307 March, 1986 Prepared by EMCON Associates 445 West Garfield Avenue Glendale, California 91204 Project: 773-01.01 emcon Associates TABLE OF CONTENTS 1.0 INTRODUCTION 1.1 Project Overview 1.2 Guidance Documents 2.0 REMEDIAL INVESTIGATION PLAN 2.1 Site Background 2.1.1 Site Maps 2.1.2 Regional Hydrogeology 2.1.3 History of Chemical Usage 2.1.4 Disposal Activities and Spills 2.1.5 Suspected Contamination Areas 2.1.6 Past Remedial Actions 2.2 Quality Control/Quality Assurance Plan 2.2.1 Sampling QA/QC 2.2.2 QA/QC Aspects of Laboratory Analysis 2.3 Health and Safety Plan 2.3.1 Worker Safety 2.3.2 Community Safety 2.4 Community Relations and Notification 2.5 Sampling Plan 2.5.1 Surface Sampling 2.5.1.1 Dirt Piles 2.5.1.2 Stained Surface Areas 2.5.2 Soil Sampling Program 2.5.3 Ground-Water Sampling 2.5.4 Drum Sampling Page 1 1 4 5 5 5 8 8 9 9 9 10 10 10 12 12 12 13 14 14 14 18 18 20 26 emcon Associates TABLE OF CONTENTS (Cont.) 2.5.5 Surface Water Run-off 31 2.5.6 Air Quality 2.6 Schedule 31 32 Figures Figure 1 - Site Location Map Figure 2 - Site Map Figure 3 - Schematic Plot Plan Figure 4 - Preliminary Environmental Assessment Figure 5 - Ground-Water Movement Figure 6 - Water Wells Figure 7 - Well Details Figure 8 - Remedial Investigation Schedule 2 6 7 15 21 22 24 33 Tables Table 1 - Recommended and Required Sampling and Analytical Methods CAC, Title 22, Article 11 11 Table 2 - Summary of Field Soil and Water Sampling Plan 27 Table 3 - Preliminary Drum Inventory 28 Table 4 - Drum Profiling 30 Appendices Appendix A - B.C. Chemicals' Product List Appendix B - DOHS RI Workp1an Outline Appendix C - Ground Water Sampling Protocol emcon Rssociates B.C. CHEMICAL COMPANY SITE REMEDIAL INVESTIGATION PLAN 1.0 INTRODUCTION 1.1 Project Overview The project site is located at 1511 S. Union Avenue, Bakers- field, California (see Figure 1), and contains an estimated 6,000 drums and chemical containers. These drums are in various conditions, ranging from full to empty, some are clearly labeled while others are not, and some are physically intact while others are damaged. In addition to the drums, the si te has several 1 arge storage tanks, and some chemi ca 1 processing equipment. At various locations at the site there is evidence of spills (discolored soils), and some spills may have migrated a short distance off site. In addition to chemical containers, the site has three build- ings. One is a small open sided structure formerly used as a diesel engine repair shop. The others are warehouses, and contain unopened packages of chemicals, some of which are in a re-useab 1 e form. B.C. Chemicals handled a wide range of materials. Appendix A gives their product list, together with some relevant Mater- ials Safety Data Sheets. 1 emcon Rssociates -..iI.ANOARO RD. '>. . -. -,---- 'I :1 :1 :1 RO, I y ? DISTRlCT BOUNDARY .....-=.".=- "-- ,--:-'':- .:;.' '- ::;:.;- -ð'~"''''Dr '''~ -= :':';.';::,:'..:::':.,:-::: ,... .. ~ ::, '.'. .:::".,.-::;.,-<,:;. .::' :..:::..-....:..,' : }~::.\>:::..:)(.. "'. ~:-: ;" ."" """"':~ :"t'"',:,",' :.:;}:::.::,;.;:;::::,. \.<:.::':!';/~\~.'/::::'> :'.. -.:.,:..::':::',:.::: :'i:,'\H::'!'" .......;:: .. :·;:.=;::Ú·:· ':':'.::.' ....:...~. :0 : '" ;:~ "".' . ....:.. ,..... --,,-. .;.... ...:.... .':..' ........ .. ~:..':... .' :.,::.....:-- 'p~~. "" :': ..~~: ! ,; " r·..·· '.-..'..:":" .";'.:.."'" ;_.....,."......,..,......-.' .......-....,..-:"::..:..... '. ";""::''';':'':'' ....' .' .... "~O' .. ..' ....:--. . '- .'-=- ~ . .-:-.=;;p--.==, ~~:-~~~~~:. ',::,.-.,.-'''''"-'''' _. o c:¡ ~ , ¡ 30S. R 2eE, -3~S..R 27E. o J:: ,.:...:...... " '-'-." - '; .. ~---~.- '" ,:,,:1:~~ ~-~r;-' ",--r-.; ~: I I I I. Ilf= 6000' ~ ,,'-_.. -- -, '\ !I! ,I ..,~'.-._-- ~ !¿/ ~ . ~-,\- ~ ___~:::_-:-~u_-ª ::.=.~:~_:=.=-~ :::-=.=: t ._-==:._~~~~:. _-=._ ~~~J. _. ';____ '='~-'_!-- \0.1'1 .... ã5 .~' ;:., =....;:r--=_.---== ==; ~~: '\\\ i~ I ;" :~ L.~.~:"._~~==_~~ __-.= __~~_ , _j _ -"BY'''' _ ~ _~~{OJSaJ _. . _ ';¿VAr.__ Scale: .. ' emcon Associates a WILLIAMS ~ WILLIAMS, INC. REMEDIAL INVESTIGATION PLAN B.C. CHEMICALS BAKERSfIELD, CALIFORNIA FIGURE I SITE LOCATION MAP PROJECT NO. 773-01.01 I.aJ > - 0: o ( ) Z I.aJ ..J ..J <t PHOENIX DRIVE ~ -N- ~ Approximate scale: I": 200' FIGURE eme", 12/85 WILLIAMS t WILLIAMS, INC. REMEDIAL INVESTIGATION PLAN B.C. CHEMICALS BAKERSFIELD, CALIFORNIA SITE MAP ~ emcon ?II)¡ , ·Rssociates I.&J ::) Z I.&J > <t Z o - z ::) . I "'2 PRO' [CT NO. 773-01.01 '''O'¡[CT NO, 173 -01.01 :5 FIGUf'E e...e... 12/115 '- DIRi__ To Union Ave.~ WILLIAMS ~ WILLrAMS, INC. REMEDIAL INVESTIGATION PLAN e.c. CHEMICALS BAKERSFIELD, CALIFORNIA SCHEMATIC PLOT PLAN LEASED WAREHOUSE '--DIRi__ CHEMICAL I I GateJ ISHE~ l J-- Stora9' tank TREATMENT sumP-Ð I Diesel pump~ MOTEL AND COFFEE SHOP WAREHOUSE ---CONCREiE ~ OFFI CE ---------- ---DIRi OVER A/C--.... ] proximate direction oround - wat.r flow I I I I I I I I I I I I I I I I I I I ~ . N· ~ o c o o "-Tank farm are< o DIHr~ Railroad DIESEL REPAIR SHOP DRUM STORAGE PHOENIX AND SON GARAGE AND STORAGE COMPANY ~ em con Associates NOT TO SCALE 2.1.2 Regional Hydrogeology Pub 1 i shed data on the regi ona 1 geology and hydrogeology will be researched. Typi ca 1 sou rces i nc 1 ude pub 1 i cat ions of the U.S. Geological Survey, records and publications of the State Department of Water Resources (DWR) and local authorities (for example Kern County Water Agency, Improvement District No.4). From the data so obtained, a narrative description of the surface and subsurface geology and hydrogeology wi 11 be pre- pared. Included in the description will be appropriate draw- ings, geologic cross sections, and maps. 2.1.3 History of Chemical Usage A wide range of chemicals were handled on this site. Appen- dix A lists the products that were sold by B.C. Chemicals, and inaddition to these, there may have been compounds used in formulations, and/or intermediaries and by-products. The former owner of B. C. Chemi ca 1 s wi 11 be i ntervi ewed to establish the overall history of the site, and to identify any additional chemicals that should be included in the listing. To the extent that former employees of B.C. Chemicals can be reached, they too will be interviewed. 8 emcon Associates 2.1.4 Disposal Activities and Spills Whil e conducti ng the i ntervi ews proposed above, a hi story of disposal activities and spills will also be obtained. To the extent that thi s hi story may be sparse or non-exi stent, an inventory of applicable environmental permits will be obtained, and agency records searched for notices of violation or similar records. A narrative description will be prepared including, where possible, quantities and characteristics of liquid and solid wastes, as well as spills. 2.1.5 Suspected Contamination Areas Since the PI has only consisted of walk through inspections, there is currently no analytical data available on suspected soil and ground-water contamination. There is s i gnifi cant surface stai ni ng in several areas, both on-site and off-site. These areas will be defined in develop- ing the site plot plan (see Section 2.1) and definition of extent of contamination will be an objective of the sampling plan presented in Section 6 below. 2.1.6 Past Remedial Actions The only known remedial actions that have occurred, or might occur pri or to impl ementati on of the RI, are the removal of salvageable chemicals and some interim mitigation measures designed to control storm water run-off. The extent to which these activities have occurred will be documented and verified. 9 emcon Rssociates 2.2 Quality Control/Quality Assurance (QA/QC) Plan 2.2.1 Sampling QA/QC Prior to field entry a QA/QC plan for sampling soils, waters and drums wi 11 be prepared for revi ew and approval by Kern County Health Department (CHD). As a minimum, this will include: · Equipment calibration and maintenance procedures. · Sample collection procedures. · Chain-of-custody procedures. · Sample preservation procedures. Until more site characterization has been carried out, it is not possible to specify precise methodologies. However, generic guidelines will be used. A typical example is given in Appendix C. 2.2.2 QA/QC Aspects of Laboratory Analysis All samp1 es wi 11 be sent to a State approved and cert i fi ed laboratory for analysis. Standard methodologies will be used, as appropriate, using the following protocols given in Table 1. The 1 aboratory QA/QC pl an wi 11 adhere to the requi rements of Section 3.5.2.d of the California Site Mitigation Decision Tree. 10 emcon Associates e e TABLE 1 RECOMMENDED AND REQUIRED SAMPLING AND ANALYTICAL METHODS CAC, TITLE 22, ARTICLE 11 1. "Test Methods for Evaluating Solid Waste, Physical/Chemical Methods" SW-846, 2nd Edition, US EPA 1982. 2. "Standard Methods for the Examination of Water and Waste Water (6th Edition)" American Public Health Association, 1985. 3. "Methods for Chemical Analysis of Water and Wastes" EPA 600/4-79-020 US EPA 1979. 4. "Manual of Analytical Methods for the Analysis of Pesticides in Humans and Environmental Samples" EPA 600/8-80-038 US EPA 1980. 5. Federal Regi ster Vol ume 47, Number 103, Appendi x A, Pages 23376- 23389, May 7, 1982. 6. American Society for Testing and Ma t e ria 1 s, (ASTM) Standards 0-93-79, 0-3278-73. 7. Nat i ona 1 Association of Corrosion Engineers (NACE) Standard TM-01-69. 11 2.3 Health and Safety Plan 2.3.1 Worker Safety A generic safety plan has already been prepared for this site and is available from EMCON Associates. This plan will be implemented and updated to cover specific activities that will be carried out during the RI. These include: · drum sampling and characterization · exploratory soil borings · equipment decontamination and dismantling · removal and disposal of chemicals and drums For each area the plan will address the following issues in detai 1 : · protective equipment · training · on-site monitoring · base-line health surveillance 2.3.2 Community Safety The site safety pl an revi si ons will address community safety issues such as the possibility of off-site dispersal of hazardous or toxic materials. Issues to be addressed in more detail include: · site access control · off-site air monitoring · contingency planning 12 emcon Associates 2.4 Community Relations and Notification As part of the Remedial Investigation, a Community Relations and Notification Plan will be prepared. This plan will address the following items: A. Public notification via any and all of the following techniques: · newsletters · community meetings · project reviews · technical briefings · telephone hotline B. Desi rabil ity of an i nformati on repository. If warranted, a central depository will be designated either at a local public 1 i brary, or some other nei ghborhood faci 1 i ty such as a hi gh school. C. Public meetings. If public awareness and concern warrants, public meetings will be held, either at specific critical points 'during remedial action, or on a routine regular basis. Information will be disseminated via graphic displays, slide presentations, and technical briefings designed to translate potentially complex technical information in terms understandable by lay people. 13 emcon Associates 2.5 Sampling Plan Figure 4 shows a preliminary environmental assessment of the site, based on a walk through inspection. The sampling plan must address the following issues: A. Nature and type of surface contamination. B. Extent and nature of soil contamination. C. Extent and nature of potential ground-water contamination. D. Nature, type and quantity of residual chemicals contained in drums, tanks and equipment on site. 2.5.1 Surface Sampling 2.5.1.1 Dirt Piles Three piles of dirt are present on site. These piles were created by scrapi ng the superfi ci al soil into pi 1 es by means of a bull dozer. The soi 1 s do not appear to be hi ghly hazardous and do not appear to requi re spec i a 1 precautions in handling. If these piles have not been removed during preliminary site mitigation, the soils will be sampled and analyzed. Representative samples will be obtained by hand coring and mixing the cores to obtain a representative sample. These samples destined for inorganic analysis will be placed in plastic bags, labelled and delivered to a State certified laboratory for analysis. Chain-of-custOdY pro- cedures will be used throughout. Samples for organic and 14 emcon Associates If -5 ite oily ,tains Approximate direction of Qfound-water flow : ....5000 c;¡oU ~¡OJ 7( DIRT ) 0 ~ PILE)O ~¡~ of staining- I cryatal. I I d horizontal .teel Jnk (-10009 __________ Small horizontal tanka ç:;;, \: PILE] \.'-.....J x Area of atainìnQ- whit. cryatoll x x J; .yp.) 2' deep bermed sump i Evid'nce of spillac;¡, and QCid attack -- ,... Plastic tonk label.d .. - 2 OEGREASER" ... ~OOO oollon 'I.voted v.rtical 11..1 tonk !d concret. :1. elevated ydrocllloric k / Oies,l oil staining :TIC DRUMS DEPOSIT" 5000 9allon tank lobel.d "NO SMOKING" Off- aite staininQ -y,lIowish/green cry.tals Qþ Salvageabl. plating chemicals Dirt over concrete floor; Evidenc. of minor spilla ~ABLE x Broken packaging including ammonium perauttate 'IIIe", 12/115 WILLIAMS (. WILLIAMS, INC. REMEDIAL INVESTIGATION PLAN B, C. CHEMICALS BAKERSFIELD, CALIFORNIA PRELIMINARY ENVIRONMENTAL ASSESSMENT FIGUfltE 4 ~ItO, ICT NO, 773-01.01 '-, ~ -N- ~ I ton sulphur dioxide cylind.r Plastic tonk (...!SOOO 901.) on grade label.d "DUST GUARD" Vertical elevated te labeled "# 14" Plait ic tonk (-!SOOO 901.) on orade labeled" -12 05-100" Plastic tonk ("'!SOOO qal.) on grade labeled" . 10 DMS" Plastic tonk ("5000901.) on grade labeled" -9- SILICATE" (-"'"'") f DIRT ") ~,-~J X .,. LEGEND @) Exploratory boring X Surface sample ~ Dup aquifer monitoring well Ele waT E X !SOOl X plast acid Stained dirt P ~// Oily stains on dirt floor M.rcaptan cylinders X / X X MISCELLANEOUS ---- PARTIAllY-FILLED ~ DRUMS EMPTY CF DR Xl Unco nt foiled storm woter runoff in this area Chemical odors in this or.a - Some drums hiss os sun warms th.m; 82 drums hove been characterized and contents ani hazardous t;;;) W em con AssocIates NOT TO SCAl E \wJ¥¡gi¡ij;k;jki~: imt:tflr-·:î -11:;·,:·:r0m1,:'~g~(\i \~ I ~5n! !~H~!¡liHÚ!lt· ~Pfjjrl~'II3D~;~~È111~ij~WilbHflm [1§11J1:m~!lißjr!.lIl!W /lUll It ~¡[lþ!t'I,l!flJ¡ jilt '}';, II JU'! JlILJLJI U¡jll ~:lli¥;}!Î;¡}5¡&J'J~+~'.II!!'(UI~J .....J ::::::@J!ltn\ 111\\\\ :v,I~¡t'!l!!'L~~ læffflAl@g'~nrWijrrJtm;~'i:I~~~lájrd4[)2J~ ,1,;ElIEK f·,j ,~ · £õf'HW¥ .. ,0 ,¡0ttt':1 .j' :::%iF:\I,,,j:""\i\ YlhMilìl! .¡I "n[aBKUNDAGE'vr""b", ~n r LANE4 9[:. 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R;"I''';''/''' ¡..' · '::;:,,:),.; :......: ":""'" :·':I I .y~···..~~.u~~«ff'H~~··~ f ~........~~~~1F,...y.......,f.. . " ~~~..)/~\~'. ~Q ~, tr::::::::::::;·:¡·.;:.~..:.·.···" ....~ ~\~;r;'¡¡jt;";":~i\~¡'¡:j;IIt.I:"" " . ~ ~¡: ~ 11UW1J~us if:·i; > 1 .~ft ~;'"7;¿%1~:~{~." ....~~ I E~~1¡~~!~J-,,'W!!~+I,j~:'1:~ 'III\I~~!_ ~"!~i<;;¡"~~i:1~~1=~~... ~.'",~# ~£ ./ '\&1·' ·:..·,·.....:::~:.:)\:..:.,:::\it~:0 ::if)....:.::,:.:::::'::;.i:."'''',....,.,::,:..:,:,:::! .;':j:··5~'¡:¡:::¡·I:::::ihnnr -.¡'"':mmr::::((\:.. "', lfJnDC!lL=; 0 LEGEND ~ 7 .\:." :.·\::::'}:~\:;::::::::;::::/¡:¡~:A T!è:i;1 -. - ,........ ": .:?,::,::::::::::::;···~::::::::::::::::i~?P1¡· ~::::;¡:¡::::::¡::;::::::::\:¡ i :3B~~~ ~ . ./ '\... . ..u......u..··{d~; · ..ul..····'..··E':":ø:::I:UJ~d::::.}n..::}..... I .Jc::Jnc:JfiSî' 0 /" ~~,f(~~!lt'I.,-!r..tIlW1i1; ¡n~ z~\ ~ · Acti.e well ~~~MA ..~';::~i~~·::;:::·:::.;·;l!;;;;i;;I¡ i~·::::;:::·~¡:·!!n~.~:':'::·ij'~:lii¡]\\ !¡i::¡:j::';~'jl¡i~¡:~II':¡!:!:!'!:¡i!¡I'li!!j!:ii;~ :]i:,;i:::::¡¡¡;¡.li ~ ___ __J __ _ 0 Inactive well l .'. 1-- ~-- ~l. .. ,;J,{l[-j~."..-'i=~ SC.I~~ 200:1t:::·:::~e::el fl 27 ( ~ L \;:;--'f" ., - =-~= -, ... '. .... /" / /. ------- Z8 WILL lAMS t WILLIAMS, INC. REMEDIAL INVESTIGATION PLAN B.C. CHEMICALS BAKERSFIELD, CALIFORNIA WATER WELL LOCATION MAP 1984 ~ em con ?//!; Associates FIGURE 6 PROJECT NO. 773 - 01.01 Figure 8 .EDIAL INVESTIGATION SCHE.E B.-C. CHEMICALS Work RI Work Weeks from agency approval Breakdown Plan Activity Structure Reference 112,31415 6 1 7 1 8 I 9 ,10 11,12,13114,15 16 1.0 2.1 Site Background 1.1 2.1.1 Site Maps 1.2 2.1.2 Regional Hydrogeology 1.3 2.1.3 History of Chemical Usage - 1.4 2.1.4 Disposal Activities & Spills - 1.5 2.1.5 Suspected Areas of Contamination 1.6 2.1.6 Past Remedial Action 1.7 - Draft Report .....,. 2.0 2.2 QA/QC Plan 2.1 2.2.1 Sampling QAlQC 2.2 2.2.2 laboratory QA/QC 2.3 - QA/QC Plan ... 3.0 2.3 Hea lth & Sa fety Plan 3.1 2.3.1 Worker Safety 3.2 2.4.1 Community Safety 3.3 2.4.2 Hea lth & Safety Plan ... 4.0 2.5 Sampling 4.1 2.5.1 Surface --- - 4.2 2.5.2 Soil Sampling -- 4.3 2.5.3 Water Sampl ing - 4.4 2.5.4 Drum Sampling 4.5 - laboratory Analysis ------- 5.0 2.5.5 Surface Water Runoff 6.0 2.5.6 Air Quality 7.0 - Project Management 8.0 - Project Reviews ..... 9.0 - Program Revisions & Implementation 10.0 - RI Report volatiles analyses will be obtained in brass or stainless steel rings from undisturbed portions of the piles. The rings will be sealed, labelled and sent to the labora- tory. The representative sample from each pile will be analyzed for the toxic metals known to have been on-site. These are: · barium · chromium (total and hexavalent) · cobalt · copper · vanadium · zinc · nickel The analysis will be carried out by nitric acid extrac- tion and total metal concentration determined. If ten percent of the metal concentration exceeds the STLC value given in CAC Title 22, Division 4, Section 66696, then the WET extraction procedure (Section 66700) will be used to determine the IIsolublell or lIextractablell metal concen- trations. Since many of the chemical s used on-site were acids, alkalis or salts, the following two tests will be carried out to identify potential contamination: · pH · soil conductivity 16 emcon Associates Exami nat i on of the soil s for organi c chemi cal contami na- tion presents a problem, in that so many different types of material were used on-site. While it is technically feas i b 1 e to analyze for each and everyone, the costs would be extraordinarily high and perhaps yield little or no information. Many of the organic materials are not highly toxic and will have a relatively short life in the environment. These include the esters, glycols, ketones and alco- hols. However, other organic chemicals are more toxic and, some environmentally persistent. These may repre- sent a· public health or environmental hazard and include the organic amines, pesticides, chlorinated solvents, non-chlorinated solvents and miscellaneous materials such as formaldehyde and organic mercaptans. In order to profile this range of compounds at a reason- able cost, it is proposed to analyze one each of the soil samples from each pile for: · chlorinated hydrocarbons · volatile organic compounds (EPA Method 624) · total recoverable petroleum hydrocarbons (EPA Method 418.1) Research into the chemical nature of some of the materials currently only identifiable under trade-names (i.e., Triton M-10 or Dowicide G) will be carried out to see' of other analyses should also be performed (Le., a pesticide/PCB screen). 17 emcon Associates 2.5.1.2 Stained Surface Areas There are a number of areas showing superficial staining, both off-site and on-site. Surface samples representing the interval 011-311 will be obtained at the locations marked on Fi gure 4. These 24 1 ocat ions represent both suspect and non-suspect areas, and together will provide a good profil e of the overall surface condit ions on the site. The chemical analyses will be the same as those proposed above for the soil~ from the dirt piles. 2.5.2 Soil Sampling Program In order to determi ne the extent and depth of pass i b 1 e soil contami nati on, seven exploratory bori ngs wi 11 be dri 11 ed at the locations shown on Figure 4. These sites represent areas of obvious superficial contamination and the exploratory boring, soil sampling and analysis will demonstrate the extent of vertical contamination. Additional exploratory borings may be requi red and the need or otherwi se wi 11 be determi ned by the results of the surface soil analyses performed under section 2.5.1.2. The results will also be used to guide the analytical program, and only those pollutant parameters identified in a surface sample will be sought in the depth profile. The following methodologies will be used in the exploration. All drilling equipment including bits, augers, samplers, etc., will be steam cleaned pri or to commencement of fi e 1 d activities and between each boring.- 18 emcon Associates A detailed boring log will be recorded for each boring from undisturbed soil samples obtained at 5-foot intervals and drill cuttings. Soil samples will be obtained from each bori ng begi nni ng at a depth 5 feet below the ground surface . and continuing at 5-foot intervals until ground water is encountered or a depth of 40 feet is reached. A modifi ed California split-spoon sampler will be used to collect the soil samples. The sampler will be driven 18 inches into undisturbed ground beyond the tip of the augers by a 140-pound hammer with a 30-i nch drop. The sampl er will be withdrawn from the boring and the undisturbed soil samples removed in 4- inch long brass liners. Soil samples obtained above the water table will be retained in the brass liners, sealed in aluminum foil and glass jars, and stored on ice for transport to the laboratory. Labels will be placed on the jars identifying the project number, date, sampler's initials, boring number, and sampling depth. In addition, each soil sample will be recorded on a chain-of-custody form identifying the soil sample number, sampler's initials, date, any couriers used, and responsible laboratory personnel. If ground water is not encountered, each boring will yield eight soil samples for analysis. Depending on the results of the surface sampling program and field observations (i.e., stained or odiferous soils) these samples may be analyzed either separately, or as composites. For estimating purposes it is assumed that a composite from each boring will be analyzed for the same range of parameters listed in Section 2.5.1.1 above. All samples not immediately submitted for analysis will be archived by EMCON under refrigeration for possible additional analysis. 19 emcon Associates It is not anticipated that there wi 11 be a need for proj ect specific analytical techniques or QA/QC methods, and Health and Safety protocols not already detailed elsewhere in this plan. 2.5.3 Ground-Water Sampling In July of 1984, usable ground water in the regional uncon- fined aquifer was at an elevation of approximately 190 feet above mean sea level (MSL), (Source: Kern County Water Agency, Improvement District NO.4). The site surface elevation is approximately 385 feet MSL, giving a depth to ground water of about 200 feet. Ground-water contours for July, 1984 show a very shallow hydraulic gradient to the east or southeast (see Figure 5). There are approximately 21 active wells within one mile of the site (see Figure 6) and five inactive wells. The nearest active well is approximately 2,000 feet to the west (i .e., it is upgradient) while the nearest wells downgradient (east and/or southeast) are approximately 5,000 feet away. There is a significant well field adjacent to the Central Branch Canal, approximately 3,000 feet to the south. As part of the RI, the above data wi 11 be veri fi ed as bei ng still accurate, and water quality records obtained for the wells within a one mile radius of the site. If the 1330 program has been carri ed out, specifi c knowl edge of specifi c priority pollutant contamination (if any) will be available. If the ,data is not available, or if major data gaps exist, the nearest well s to the west, east, southeast and south wi 11 be sampled and the water analyzed for the priority pollutants and for chlorinated hydrocarbons. 20 emcon Associates . '1-- i \ - _1_- .__ I I ! ! n --- ._. - . --- ~ u' : 'I ~ I' ,,' ~. ~t-......~ PETR~¡ ; ! !( ':" ,\ RD '~r"\,~3" 313-- I ! I ~_____ '/ ~<..~. --',. --, l~ I 'f-""''- : ¡ '\ \\ «~, '--~--'-~11';,' 'K,', I ,:I '," ~ "I. I . ¥ r~FIRSi. 70 , Jt? ~-&' fj d!: -, {I ~ ~ .---- jl: "="P~~... ~.~ - i_ fj" ~~;,,~ ~; - - "- _ð~~.J' ....-- ._'"_nn " , C. CHEMICALS, ò'\ It) - \ r 11 CS(Þ />-11 .---.----.---.-- LEGEND Direction of ground - water flow £~~ -~ .._~; z , 2: I ' ~L-_-'__ P ,I-"'~ SCALE: 0 2000 4000 6000 FEET WILLIAMS t WILLIAMS, INC. REMEDIAL INVESTIGATION PLAN B.C. CHEMICALS BAKERSFIELD, CALI FORN IA GROUND-WATER ELEVATION CONTOUR MAP JULY 1984 FIGURE ~ emcon . AssocIates 5 San Jose, California PROJECT NO. 773-01.01 Potential Disposal Mode Salvage for re-sale. On-site treatment for hazard and volume reduction Non-hazardous materials - [potentially designated wastes] Unknown [potentially hazardous wastes requiring Class I disposal]. TABLE 4 DRUM PROFILING Profiling Required Full, sealed drums, clearly identifiable as unused chemical stock. Acids and alkalis, need pH deter- mination and anion identification by qualitative analysis. Strong brines and crystalline neutral salts. Need pH and qualitative anion determination. Test for legal definition of hazardousness (explosive, toxic, flammable and/or corrosive). Chemically profile to classify nature of toxicity [hydrocarbons, chlorinated hydrocarbons, pesticides, etc.]. Use the HAZCAT screening program. 30 emcon Associates 2.5.5 Surface Water Run-off As indicated elsewhere, some uncontrolled storm water run-off occurs at this site. If a temporary mitigation plan is approved (submitted 12/26/85) and implemented, this problem will be controlled at the time the RI is implemented. The sampling planned under Section 2.5.1 above, should detect any off-site contamination that might have occurred from historic discharges. 2.5.6 Air Quality As part of the RI an assessment of the possibility of contam- inant migration via the air pathway will be made. This assessment will address both current site conditions and planned or possible remedial activities. The assessment will address the followin items: . Potent; al for damaged drums, site treatment release of noxious fumes from either from chemical transfer operations and on- operations. . Potential for release of potentially contaminated dust from wi nd corros i on and uncontroll ed excavations and/or soils handling. Assessment will include nature and quantity of potential toxic air releases, as well as identification of populations at risk. 31 emcon Associates Based on the assessment, an air sampling monitoring plan will be developed for implementation in the RAP. 2.6 Schedule The RI is expected to take about four months (see attached Schedule, Figure 8). Paci ng items for this program are: A. Preliminary Data Gathering 4 weeks B. Field Investigation Including drum profiling 6 weeks c. Laboratory Analysis 3 weeks D. Final Data Reduction and Report 3 weeks The schedule assumes that the assumptions outlined in the program are, in fact, verified in practice. 32 emcon Associates e e APPENDIX A B.C. CHEMICAL IS PRODUCT LIST e .:~. :~.~ =:':~A :307 · PO. 80, 884. .-. ~~, CA 93302 .' Phon. (805) 832·1380 J . , Dear Customer: BC Chemicals is a full line chemical distributor, we also offer a complete line of blended products, (degreasers, mud detergent, etc.). BC Chemicals operates 24 hours a day 7 days a week to fulfill your chemical needs. Should you be unable to find the particular product within these product listings, please contact your sales representative or our office. BC Chemicals has the sources available to obtain whatever product you may require. Richard J. President e e TABLE OF CONTENTS Page Number ACIDS ................................................ 1 ALCOHOLS. . .'.'. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .3 ALKALlI . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 AMINES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 CHLORINATED SOLVENTS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 CLEANERS & DEGREASERS .. .. .. .. . .. .. . .. . . . .. .. 11 - 1 7 DRILLING FLUIDS MATERIALS.. . .. .. .. . .. .. .. . . . .. .. . 8, 9 ESTERS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 FORMULATED PRODUCTS. . . . . . . . . . . . . . . . . . . . . . . . . 18 - 31 GLYCOLS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2, 3 INORGANIC & ORGANIC CHEMiCALS.................. 4-7 KETONES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 ORGANIC ACIDS. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 PHOSPHATES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 This product list supersedes any previous product list. e ORGANIC ACIDS Acetic Acid Glacial 480 Ib drum Acetic Acid 80% 477 Ib drum Benzoic Acid 50 Ib sack Boric Acid 1 00 Ib sack Chromic Acid 1 00 Ib drum Citric Acid 1 00 Ib sack Formic Acid 515 Ib drum Oxalic Acid 50 Ib sack Sulfamic Acid 50 Ib sack ACIDS Muriatic Acid (HCL) 535 Ib drum 1 40 Ib carboy Nitric Acid 600 Ib drum 90 Ib carboy Phosphoric Acid 220 Ib drum Sulfuric Acid 750 Ib drum 200 Ib carboy PHOSPHA TES Diammonium Phosphate 1 00 Ib sack Disodium Phosphate 1 00 Ib sack Page 1 e PHOSPHATES (can't) Soda Phos 50 Ib sack Sodium Hexametaphosphate Granular 50 Ib sack 1 00 Ib sack Sodium Hexametaphosphate Plate 50 Ib sack 1 00 Ib sack Sodium Tripolyphosphate 1 00 Ib sack Tetrapotassium Phosphate 1 00 Ib sack T etrasodium Pyrophosphate 1 00 Ib sack Trisodiumphosphate 1 00 Ib sack Monosodiumphosphate 1 00 Ib sack ALKALI Caustic Potash Flake 1 00 Ib drum Caustic Potash Uquid 50% 680 Ib drum Caustic Soda Bead . 50 Ib sack Caustic Soda Flake 50 Ib sack Caustic Soda Liquid 25% (bulk) 600 Ib drum Caustic Soda Liquid 50% (bulk) 707 Ib drum Soda Ash 50 Ib sack 1 00 Ib sack Sodium Bicarbonate 50 Ib sack 1 00 Ib sack e AMINES Diethanolamine 99% 480 Ib drum Diethylene Triamine 440 Ib drum Diisopropanolamine 450 Ib drum Ethylene Diamine 478 Ib drum Isopropanolamine PRG 450 Ib drum Mixed Isopropanolamine 450 Ib drum Monoethanolamine 460 Ib drum Monoispropanolamine 440 Ib drum Morpholine 460 Ib drum Triethanolamine 85% 510 Ib drum CHLORINATED SOLVENTS Aerothene IT 54 gal drum Aerothene MM 600 Ib drum Chlorothene NU and VG 592 Ib drum Dowclene EC 54 gal drum Ethylene Dichloride 565 Ib drum Methylene Chloride 600 Ib drum Orthodichlorobenzene 600 Ib drum Perchloroethylene, Ind. 700 Ib drum Page 2 e CHLORINATED SOLVENTS (con't) 1 , 1 , 1 Trichloroethane 592 Ib drum Trichloroethylene 600 Ib drum ESTERS Amyl Acetate. Primary 400 Ib drum Butyl Acetate, Normal 400 Ib drum Dalpad A 505 Ib drum EE-Acetate 440 Ib drum Ethyl Acetate 85-88% 400 Ib drum Ethyl Acetate 99% 409 Ib drum Isobutyl Acetate 400 Ib drum Isopropyl Acetate 390 Ib drum N. Propyl Acetate 400 Ib drum Butyl "Cellosolve" Acetate 422 Ib drum "Carbitol" Acetate 463 Ib drum Butyl "Carbitol" Acetate 450 Ib drum GL YCOLS Diethylene Glycol 520 Ib drum Dipropylene Glycol 470 Ib drum Ethylene Glycol 515 Ib drum e Gl YCOlS Hexylene Glycol 424 Ib drum Propylene Glycol, Ind. 480 Ib drum Propylene Glycol, USP 480 Ib drum Triethylene Glycol 520 Ib drum Tripropylene Glycol 470 Ib drum KETONES Acetone 358 Ib drum Cyclohexanone 432 Ib drum Diacetone Alcohol 430 Ib drum Diisobutyl Ketone 370 Ib drum Dimethyl Formamide 41 0 Ib drum 1 ,4 Dioxane 473 Ib drum Ethyl Amyl Ketone 374 Ib drum Isophorone 425 Ib drum Methyl Ethyl Ketone 366 Ib drum Methyl Isobutyl Ketone 365 Ib drum 2-Nitropropane 455 Ib drum Pentoxone 41 0 Ib drum T etrahydroturan 400 Ib drum Page 3 - ALCOHOLS Amyl Alcohol, Primary 370 Ib drum Butanol, Normal 370 Ib drum Butanol, Secondary 369 Ib drum Isobutanol 370 Ib drum Isopropanol, Anhydrous 55 gal drum Methanol 55 gal drum Methyl Isobutyl Carbinol 371 Ib drum Methyl Amyl Alcohol 371 Ib drum Propanol, Normal 370 Ib drum e INORGANIC AND ORGANIC CHEMICALS Acintol FA-2 420 Ib drum Aluminum Sulfate. 1 00 Ib sack Ammonia Anhydrous 1 50 Ib cyli:1der Ammonia Bicarbonate 300 Ib drum Ammonium Alum 1 00 Ib sack Ammonium Biflouride 50 Ib sack Ammonium Chloride 50 Ib sack Ammonium Hydroxide 350 Ib drum Ammonium Nitrate 80 Ib sack Ammonium Sulfate 1 00 Ib sack Asbestos 50 Ib sack Barium Sulfate 1 00 Ib sack Bentonite 1 00 Ib sack Borax 1 00 Ib sack Butyl Oxitol 41 5 Ib drum Calcium Carbonate 50 Ib sack Calcium Chloride 80 Ib sack Calcium Chloride Water Bulk Page 4 e Calcium Chloride Powder 1 00 Ib sack Calcium Hypochlorite Granular 1 00 Ib drum Calcium Hypochlorite Tabs 1 00 Ib drum Carbon 50 Ib sack Chain Oil 55 gal drum Chlorine 1 50 Ib cylinder 1 ton Cobalt Sulfate 1 00 Ib sack Copper Sulfate 80 Ib sack Cyclohexylamine 175 Ib drum Deriphat 90 Ib drum Diatomaceous Earth Hyflo Super Cel Bulk 50 Ib sack Standard Super Cel 50 Ib sack Celite 535 50 Ib sack Celite 545 50 Ib sack Fiber Cel 50 Ib sack Dioctylphalate (Depone) 436 Ib drum Dowfax 2-A-1 530 Ib drum Dowicide G 11 0.1 2 Ib sack e e INORGANIC AND ORGANIC CHEMICALS (can't.) Epsom Salt 1 00 Ib sack Ethyl Mercaptan 5 gal pail Ferric Chloride Bulk Ferrous Sulfate 50 Ib sack Formaldehyde Bulk Gluteraldehyde 50% 500 Ib drum Glycerine 96 % 570 Ib drum Glycerine U.S.P. 570 Ib drum Gypsum 1 00 Ib sack Hampene 1 00 58 Ib drum H.T.H. Granular 1 00 Ib drum H.T.H. Tabs 1 00 Ib drum Hydrazene 250 Ib drum 450 Ib drum Hydrogen Peroxide 35% 275 Ib drum 500 Ib drum Kerosene 55 gal drum LAS - 99 (Cal Soft) 480 Ib drum Lime Hydrated 50 Ib sack Lime Quick (Calcium Oxide) 60 Ib sack Methyl Formate 440 Ib drum Metso 20 Sodium Metasilicate 1 00 Ib sack Mineral Oil 55 gal drum Morpholene 460 Ib drum Muriatic Acid Inhibitor Rodine 21 3 1 gal 5 gal Nickel Brightener 5 gal Nickel Chloride 50 Ib sack 1 00 Ib sack Nickel Sulfate 100lb Ninol - 1 285 400 Ib drum NTA - NA3 50 Ib sack Orzan 50 Ib sack Pine Oil 55 gal drum Potassium Carbonate 1 00 Ib sack Potassium Chloride (Potash) 1 00 Ib sack Bulk Potassium Ferricyamide 1 00 Ib drum Potassium Metabisulfite 1 00 Ib sack Potassium Nitrate 1 00 Ib sack Page 5 tit e INORGANIC AND ORGANIC CHEMICALS (con't.) Potassium Permanganate 330 Ib drum Potassium Phosphate 1 00 Ib sack Potassium Sorbate 1 00 Ib sack Potassium Sulfate 1 00 Ib drum Propylene Dichloride 520 Ib drum Paraformaldahyde 50 Ib sack Quebueuo 50 Ib sack Salt XXX Bulk 50 Ib sack Salt Food Grade 80 Ib sack Soda Ash Bulk 50 Ib sack 1 00 Ib sack Sodium Acid Pyrophosphate 1 00 Ib sack Sodium Benzoate U.S.P. Flakes 1 00 Ib sack Sodium Bicarbonate 1 00 Ib sack Sodium Bisulfate Globular 1 00 Ib sack Sodium Bisulfate 1 00 Ib sack Sodium Bromate 290 Ib drum Sodium Bromide 270 Ib drum Sodium Gluconate 50 gal drum 50 Ib sack Sodium Hydrosulfite 250 Ib drum Sodium Hypochlorite 55 gal drum Sodium Hypophosphite 11 0 Ib sack Sodium Metabisulphite 110.23 Ib sack Sodium Metasilicate 1 00 Ib s~ck Sodium Nitrate 1 00 Ib sack Sodium Nitrite 1 00 Ib sack Sodium Silicate 40 640 Ib drum Sodium Silicate 8.J. 120 640 Ib drum Sodium Silicate D 700 Ib drum Sodium Sulfate 1 00 Ib sack Sodium Sulfite 1 00 Ib sack Sodium Sulfide Flakes 41 5 Ib drum Sodium Sulfide 425 Ib drum Sodium Tripolyphosphate 1 00 Ib sack Sodium Thiosulfate 1 00 Ib sack Soluble Oil 55 gal drum Page 6 e e INORGANIC AND ORGANIC CHEMICALS (con't.) Solvents Cleaning Solvents 55 gal drum Lacquer Thinner 55 gal drum Mineral Spirits 55 gal drum Solvents 172-L 55 gal drum Solvent 355-L 55 gal drum Chevron 11 00 55 gal drum Solvent 1 200 55 gal drum Solvent 51 5 55 gal drum Solvent 8 55 gal drum Solvent G 55 gal drum Stoddard Solvent 55 gal drum V. M. &P. Naptha 55 gal drum Sulfamic Acid 50 Ib sack Sulfur Dioxide 1 ton cylinder Tartaric Acid 50 Ib sack Toluene 55 gal drum Triton N-10 475 Ib drum N-1 01 480 Ib drum X-45 480 Ib drum X-100 480 Ib drum as-30 515 Ib drum Urea 46% N 80 Ib sack Versene 100 600 Ib drum Venadiam Pentoxide 1 00 Ib sack White Oil 55 gal drum Xylene 55 gal drum Zinc Carbonate 50 Ib sack Zinc Oxide 50 Ib sack Zinc Sulfate 55 Ib sack - I I -- Page 7 e DRilLING FLUIDS MATERIALS B.C. 25 L.P. 5 gal pail 3Cyanamer P-26 50 Ib sack 3Cypan 50 Ib sack Defoamer 50 Ib pail Defoamer + 40 Ib pail IDesco 25 Ib sack OMS 50 Ib pail Drillaid DFLC-L Mud Deflocculant 5 gal pail 7Drillaid FCA-11 Filtrate Control/Shale Stabilizer 50 Ib sack Drilling Starch 50 Ib sack IDrispac Super Low 50 Ib sack IDrispac Regular ·50 Ib sack IDriscose 50 Ib sack 2H E C Polymer 50 Ib sack Lime Hydrated 50 Ib sack Lime-Quick (Calcium Oxide) 60 Ib sack Page 8 e M.D. 5 gal pail M.D. + 5 gal pail 4Natrasol 50 Ib sack Potassium Bichromate 1 00 Ib sack Potassium Carbonate 1 00 Ib sack Potash 1 00 Ib sack aWes Thin A multi-purpose deflocculant 5 gal pail aWes Vis A bentonite extender & Drilled Solids Flocculant 5 gal pail 5Polysec K.D. 50 Ib carton Sapp 1 00 Ib sack Saw Dust 50 Ib sack Soda Ash 50 Ib sack 1 00 Ib sack Sodium Bicarbonate 50 Ib sack 1 00 Ib sack (can't) REGISTERED TRADEMARKS 1. Drilling Specialties Company 2. Union Carbide Company 3. American Cyanamid 4. Hercules Chemical Company 5. American Colloid Company 6. Mud Specialists, Inc. 7. Welchem, Inc. 8. Westbridge Oilfields Products e DRILLING FLUIDS MATERIALS Sodium Bichromate 1 00 Ib sack Sodium C.M.C. 50 Ib sack Sodium Chromate 1 00 Ib sack Sodium Hexametaphosphate Plate 50 Ib sack 1 00 Ib sack Sodium Hexametaphosphate Granular 50 Ib sack 1 00 Ib sack Sodaphos 50 Ib sack 1Soltex 50 Ib sack T.B.P. Defoamer 50 Ib bucket Zinc Chloride 440 Ib drum Paae 9 e Barite 1 00 Ib sack Mica Fine 50 Ib sack Nut Seal Fine 50 Ib sack Nut Seal Medium 50 Ib sack Nut Seal Coarse 50 Ib sack Sawdust 25 Ib sack Cedar Fiber 40 Ib sack Kwik Seal Fine 50 Ib sack Kwik Seal Medium 50 Ib sack Kwik Seal Coarse 50 Ib sack Cottonsead Hulls 50 Ib sack Cottonseed Pellets 50 Ib sack REGISTERED TRADEMARKS 1. Drilling Specialties Company e e CLEANERS AND DEGREASERS P::>nø 1 n e - DEGREASER Heavy Duty Solvent Emulsion Degreaser Deep Solvent Penetration BC DEGREASER will quickly penetrate Grease, Oil, Tar, Carbon and many other heavy soils. Recommended for use on, production equipment engines, trucks, plant floors and metal surfaces. After allowing sufficient soak time to penetrate the soil, a steam or pressure washer will remove oil and grease with no problem of oily residue. Surface Safety BC DEGREASER may be used on all metals such as, aluminum and magnesium, glass, concrete, most paints, plastics and rubber. Versatility & Savings BC DEGREASER is used diluted with 1 to 1 ° parts water for most cleaning and degreasing applications. For heavy jobs BC DEGREASER can be diluted with diesel, 1 to 40, this provides a single product to meet every heavy duty cleaning and degreasing application. Typical Dilution Rates Hardened Carbon and Deposits. . . . . . . . ., . . . . . . . . . . . . . . . . . . . .. . . . . Up to 2 parts water Thick Grease and Open Gear Lubricants. . . . . . . . . . . . . . . . . . . . . . . . . . . Up to 2 parts water Hardened Oils and Compacted Soil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 . 8 parts water Gas and Diesel Engine Deposits ........................... . . . . . . . . 3 . 1 ° parts water Medium to Heavy Deposits of Oil and Grease. . . . . . . . . . . . . . . . . . . . . . . Up to 5 parts water Light to Medium Deposits of Oil and Grease . . . . . . . . . . . . . . . . . . . . . . . . . 3 . 1 2 parts water Chemical & Physical Characteristics Appearance ...... . . . . . . . . . . . Amber Liquid Weight Per Gallon. . . . . . . . . . . . . . . . . 8.4 Ibs. pH: Concentrate. . . . . . . . . . . . . . . . . . . . . 1 0.5 10% Solution. . . .. . . . . . . . . . .. ......9.65 1 % Solution. . . . . . . . . . . . . . . . . . . . . . . .9.25 Flash Point. . . . . . . . . . . . . . . . . . 174°F (COG) Rinsing ............... Excellent with water Use B C Degreaser to Remove · Greases · Uncured Resins · Tar and Asphalt Stains · Printing Inks . Carbon Stains · Stamping Oils · Rubber Skid Marks · Soot Stains and Smut · Carbon Black · Open Gear Lubricants Use B C Degreaser for Cleaning · Tank Trucks · Diesel Engines · Oil Storage Tanks · Production Machinery · Grease Racks · Plant Floors · Running Gears · Auto Chassis · Fork Lift Trucks · Auto and Truck Blocks Packaging 5 gallon and 55 gallon drums Bulk shipments Page 11 ~¿5 e - DEGREASER II Heavy Duty Solvent Emulsion Degreaser Deep Solvent Penetration BC DEGREASER will quickly penetrate Grease, Oil, Tar, Carbon and many other heavy soils. Recommended for use on, production equipment engines, trucks, plant floors and metal surfaces. After allowing sufficient soak time to penetrate the soil, a steam or pressure washer will remove oil and grease with no problem of oily residue. Surface Safety BC DEGREASER may be used on all metals such as, aluminum and magnesium, glass, concrete, most paints, plastics and rubber. Versatility & Savings BC DEGREASER is used diluted with 1 to 10 parts water for most cleaning and degreasing applications. For heavy jobs BC DEGREASER can be diluted with diesel, 1 to 40, this provides a single product to meet every heavy duty cleaning and degreasing application. Typical Dilution Rates Hardened Carbon and Deposits. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Up to 2 parts Thick Grease and Open Gear Lubricants. . . . . . . . . . . . . . . . . . . . . . Up to 2 parts Hardened Oils and Compacted Soil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 - 8 parts Gas and Diesel Engine Deposits .............................. 3 - 1 0 parts Medium to Heavy Deposits of Oil and Grease. . . . . . . . . . . . . . . . . . Up to 5 parts Ught to Medium Deposits of Oil and Grease . . . . . . . . . . . . . . . . . . . . 3 - 1 2 parts Diesel or Solvent Chemical & Physical Characteristics Appearance ................. Amber Uquid Weight Per Gallon. .. ....... .... . . .8.4 Ibs. pH: Concentrate.. . . . . .. . .. . . . . . . . . . . 10.5 10% Solution. . .. . . . . .. . .. . . . . . . . . . .9.65 1 % Solution ........................ 9.25 Flash Point. . . . . . . . . . . . . . .. . . 195°F (COC) Rinsing ............... Excellent with water Use B C Degreaser to Remove · Greases · Uncured Resins · Tar and Asphalt Stains · Printing Inks · Carbon Stains · Stamping Oils · Rubber Skid Marks · Soot Stains and Smut · Carbon Black · Open Gear Lubricants Use B C Degreaser for Cleaning · Tank Trucks · Diesel Engines . Oil Storage Tanks · Production Machinery · Grease Racks · Plant Floors · Running Gears · Auto Chassis · Fork un Trucks · Auto and Truck Blocks Packaging 5 gallon and 55 gallon drums o. .11, _.....:______..._ n___ .. '" ~^ r e e THREE·W A Y DEGREASER A Safe All Purpose Cleaner BC CHEMICAL THREE-WAY DEGREASER is a liquid cleaning concentrate with these outstanding advantages: Rapidly removes heavy oil, grease and grime from machinery, equipment and floors. Soluble in hot or cold water and can be rinsed off with water leaving a streak-free surface. Safe to use because it is a non-explosive water solution. Non-corrosive to metal and concrete surfaces. Economical to use. How to use B C Chemical Three-Way Degreaser For medium to heavy deposits of oil and grime, dilute all purpose cleaner with 3 to 10 parts of water. For very heavy deposits of oil, grease or dirt, mix concentrate with 3 to 1 0 parts of kerosene or diesel oil. Application Methods B C Chemical Three-Way Degreaser may be applied by wiping, brushing or spraying on the soiled surfaces. The product may also be used in dip tanks or circulated through equipment to remove oily deposits. Vertical surfaces may be cleaned by mixing 4 parts of B C Chemical Three-Way Degreaser with 4 parts of kerosene and 1 part of water. This mixture clings to vertical surfaces until rinsed with water. Handling B C Chemical Three-Way Degreaser is an alkaline solution and contains detergents. Care should be taken to avoid splashing product in the eyes. In case of eye contact, flush eyes with plenty of water. Packaging 5 gallons and 55 gallon drums Page 1 3 ,t '1 D L , , e e CTS-1 CLEANER In the 8. C. Chemical line of cleaner products, this high-alkaline detergent is designed for use in pressure spray or soak type bottle washers. Well adaptable for heavy-duty cleaning of product lines, pasteurizers, mixers, cookers and other processing equipment. CTS-1 Cleaner is a blend of alkalies, organic chelates, sequestrants, wetting agents and other ingredients. These combine to provide a full range of important advantages, such as: A complete bottle washing material. It's very effective in automatic bottle washing machines of all types, including high pressure spray· machines. A thorough cleaning agent for spray washing of reusable plastic milk containers. The high alkaline content provides germicidal protection. CTS-1 provides lubricity to reduce friction and wear in bottle washers. Sequestrants prevent the deposition of scale on bottles and washers. Omanic chelates aid in the control of aluminate scale, caused by dissolved aluminum foil labels. The best in cleaning results from high rinsability. In food plants, CTS-1 is a heavy-duty cleaner for product pipelines, juice pasteurizers, vegetable cookers, and other stainless steel processing equipment. How and where to use CT5-1 Cleaner Bottle Washing: Concentration of CTS-1 depends on the caustic requirements of regulatory bodies in the locality. 1 oz. per 1 gal. of CTS-1 equals .71 % cuastic by weight; or .7 oz./gal. equals 1/2% caustic by weight. When a code requires 3% caustic, this can be met by using a solution of CTS-1 at 4-1/4 ounces per gallon. Food Processing Equipment: a 2 to 4 oz.lgal. solution at 1600 - 180°F, will handle most jobs. Plants with central alkali system: for all phases of cleaning operations, the central reservoir should contain 4-1/4 oz.lgal. to handle bottle washing, heavy-duty cleaning and circulation cleaning requirements. CTS-1 is especially useful in breweries, bottling plants, dairies and food canneries. NOTE: Uke any alkaline material, CTS-1 should be added slowly to cold water while stirring - never to hot water either for original makeup or for upkeep. The usual precautions for handling alkaline materials and solutions should be observed. Page 1 4 ~o e e AST-1 Cleaning Compound AST-1 is a formulated product that quickly and easily removes soils and stains that ordinary cleaners do not. AST-1 is non-toxic, will not cause burns on the skin; has no irritating fumes; is non-corrosive; safe on all plastics and paints; and on electrical insulation. Will not injure acrylic paint or other paints used on equipment, machines or autos. COMPOSITION Water based solution of alkaline ingredients, biodegradable surface, active agents, and emulsifiers. Is non-flammable and has to flash point up to and including its boiling point. AUTO AND TRUCK WASHING Pre-rinse with water. Dilute 1 cup AST-1 per gallon of water. Apply by spray and brush surface, rinse with water. This will not cause any harm to car finish. Leaves a bright ,and well kept appearance.' . STEAM CLEANING Dilute up to 20 to 1 in solution tank, no caustic, no odor. Safe on all types of metal. Aluminum and stainless steel especially. Provides spray wetting and penetrating action. PACKAGING 5 gallon and 55 gallon drums Bulk shipments Page 1 5 ie-s e e HOT TANK CLEANER A powerful alkaline cleaner fortified with special detergents for rapid penetration and emulsification. Used for removal of caked oil on engine blocks. Protection equipment. Used where a standard degreaser is not enough. Not recommended for use on soft or nonferrous metals, such as aluminum or magnesium. HANDLING PRECAUTIONS BC's Hot Tank cleaner is a strong alkaline compound and is hazardous to personnel, unless proper safety precautions are exercised when handling. Avoid contact with: Skin, eyes ot clothing. When handling, wear rubber clothing, gloves, and face shield. In case of contact with skin: flush exposed area with water and rub area affected for 15 minutes. For eyes, flush with water. Contact physician. PACKAGING 55 gallon Fiber Drums (405 Ibs.) Page 1 6 ~ò e e CONCENTRATED ALUMINUM BRIGHTENER Concentrated Aluminum Brightener for all non-ferrous metals: CHROME, ALUMINUM, BRASS & COPPER DIRECTIONS: 1. Cut Concentrated Aluminum Brightener with 40 parts water. 2. Wash surface to be cleaned with soap and water. 3. Spray surface generously and evenly with cut solution of Aluminum Brightener. Allow to soak from 1 to 2 minutes. 4. Rinse thoroughly with water. On very dirty or heavily soiled surfaces, repeated application may be necessary. CAUTION: Be careful not to splash into eyes or on clothing. Do not breath fumes. Keep out of reach of children. Contains: Phosphoric mineral and organic acids. MAY BE HARMFUL OR FATAL IF SWALLOWED. DO NOT INDUCE VOMITING. GIVE MILK OR WATER. CONTACT PHYSICIAN IMMEDIATELY. IN CASE OF EYE CONTACT: FLUSH THOROUGHLY WITH WATER. CONTACT PHYSICIAN IMMEDIATELY. Packaging 1 gallon, 5 gallon, 55 gallon drums Page 1 7 \-.J ~ e - TRANSITMIX Packaging 50 gallon bbl. Bulk ~Q,) e e FORMULATED PRODUCTS FOR SPECIFIC APPLICATION Page 1 8 e e DATA SHEET 05-100 OXYGEN SCAVENGER FOR DRILLING FLUIDS AND WATER TREATING Description: OS-100 is a 52% by weight ammonium bisulfite solution and is an oxygen scavenging agent for drilling fluids and other water systems requiring oxygen removal. Typical Properties: Appearance Density, Lb/Gal. Sulfite % pH - 50% Solution Clear Ught Yellow Uquid 10.8 55 4.5 Suggested Uses: OS-1 00 may be substituted directly for catalyzed sodium sulfite as an oxygen scavenger. It is a stable solution and being a liquid, there are no dissolving and plugging problems. Use of OS-1 00 in drilling fluids and other water treatment uses allows protection from Oxygen corrosion of drill pipe, pumps and other metals in contact with the media. OS-1 00 should be added continuously directly at the pump suction utilizing a chemical injection pump. Theoretical treating ratio is slightly less than 9 parts of OS-1 00 per 1 part of oxygen. Pumping rate is dependent upon the oxygen concentration present. A minimum of 1 00 ppm excess sulfite is recommended. In drilling fluids, the base line corrosion rate may be established by running drill pipe corrosion rings in the drill string prior to commencing treatment. The coupons should be run in the drill collar cross-over sub, and the kelly saver sub. If only one coupon is to be run, it should be placed in the drill collar crossover sub. Rings should be run a minimum of 50 hours (100 hours is desired). Page 1 9 r {.,~ () G\. e e BC MICROBIOCIDES 5 gallons 55 gallons B.C. Microbiocide 1000 B.C. Microbiocide 2000 B.C. Microbiocides, available as B.C. 1000, a 25-per cent aqueous solution of glutaral- dehyde, and B.C. 2000, a 50-per cent aqueous solution of glutaraldehyde are useful as preservatives and in formulating broad spectrum industrial biocides. ' B.C. Microbiocides have many important features including: · EP A Registration ' · Effectiveness against a broad spectrum of microorganisms · Aqueous solutions which are easily and uniformly diluted and mixed · Ability to be easily neutralized for disposal · Effectiveness against aerobic and anaerobic organisms .Compatible with anionic, nonionic, cationic surtactants · Do not contain or release formaldehyde · Lower vapor pressure than formaldehyde · Diluted product easily analyzed by gas chromatography · Not affected by the presence of hard water STORAGE AND HANDLING OF B.C. MICROBIOCIDES OIL WELL MICRO BIOCIDE B.C. Microbiocide 1000 is an aqueous solution of Glutaraldehyde, at 25% (by weight) concentration. It is slightly corrosive to common materials of construction, such as steel, aluminum, and galvanized iron; the corrosion rates are low (equipment would not be severly damaged) but contamination of the product will result if contact is prolonged. Materials which have been tested and found to be suitable are stainless steel, certain fiberglass-reinforced plastics, and polypropylene or polyethylene. Types 304 or 316 stainless steel are suitable. Of the plastics tested, a polyester ("Atlac" 382) and a vinyl ester ("Derakane" 470) were resistant, but an epoxy showed some adverse effect after prolonged exposure to Glutaraldehyde. Uned steel containers are not recommended because iron contamination can result, due to pinholes in the coating. NOTE: Storage tanks, lines, pumps, valves, etc., must not be made of iron or steeL:,' Even trace iron contamination (one ppm or less) can have an adverse effect on the long-term stability of the product. The 25% solution freezes at about -10°C (14°F). Thus, if outside storage is planned, heated and insulated facilities will usually be required. However, the storage stability of Glutaraldehyde is very dependent on storage temperature and storage at temperatures below 100°F is recommended. Preferred locations for a storage tank might be either indoors or underground; drums could be stored in a warehouse or, during hot weather, in a shaded storage area where they are not directly exposed to the sun. If B.C. Microbiocide 1000 is to be heated, warm water is the preferred heating medium, in order to insure that the product will not be exposed to high temperatures. It is suggested that water temperatures should not exceed about 40-50oC (1 00-1200F) and temperature controls could be set so that the average temperature of the stored liquid is only about 20°C. This should insure a reasonably long storage life for the product. Piping and valves can be of polypropylene or polyethylene or stainless steel. A stainless steel centrifugal pump is suitable for transfer service. Asbestos can be used for gaskets and packing. NOTE: If B.C. Microbiocide is to be diluted, use only distilled/deionized water that is low in iron, calcium, and magnesium content. ?('\ ~ .í\ ~..... r \1. -~ e e UCARCIDE 12 CHEMICALS MATERIAL SAFETY DATA SHEET Antimicrobië PRODUCT - (Ap~'o~ød by U.S. Dto~',,".nr of L~bo'.' ·'tuMti.lIlIlimil.,· ro F onn LS8·oaS-41 seCTION I-IDENTIFICATION OF PRODUCT . MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. BC CHEMICALS INC. ADO R ESS (Numbtr, Sliter. Qry, :iIiUt Dna ,£.IT ,-pueJ 1511 South Union Avenue/Bakersfield 805/832-1360 TRAOE NAME CHEMICAL NAME MICROBIOCIDE 1000 Not applicable/Blend of Materi¿ CHEMICAL FAMILY CHEMICAL FORMULA Aldehyde II " " II " " " SeCTION II·HAZARDOUS COMPONENTS OF MIXTURES A precise composition 01 this product, is proprietary information. A more detailed disclosure win be provided by BC ChemicaJs as privileged i~I~~~tion upon request 10 case 01 need lor specIfic treatment ; ; AQUEOUS: SOLUTION OF ALDEHYDES FREIGHT DESCRIPTION: CHEMICALS, NOIBN DANGEROUS ARTICLE DESCRIPTION: NONE DOT WARNING LABELS REQUIRED: NONE SECTION III-TYPICAL PHYSICAL DATA APPEARANCE AND ODOR ----. 'SPECIFIC GRAVITY Clear liquid, formalin odor L 063 to L 075/ 20/200C BOILING POINT ¡oF) PERCENT VOLATILE o 0 CBV VOLUME) Slightly less than 369 F/1S7 C (decomposes) 100 VAi-OR OENSITV (AIR 1) EVAPORATION RATE n- BUTYL ACETATE. 1) -- -~~-_. VAPOR PRESSURE o @20 C = 17 mm Hg Greater than 1 1--, SOLUBILITY IN WATER Complete , ---- ------- ~~.£=TIÖ~"~.FIÃI~N~_~j~C?SION HAZ!'3°.E.AT~_ ~ EE- ~~ .~~= f-LÃ'šHPòïÑ-T{.i:Clhodj ¡FLAMMABLE: LIMITS I.., u.. '. (pe:~Ce:NT BV VOLUME) -- '-' , - - -- None __,_, _,______,______,__ __W~_, .BJA__ FIH'EEX1ïNGüišHïNG M-ËõïÃ---- _,_ ,___ __~_o..LA2£~i~~l~m~L,_.,_._"_, ::'PECIAL FlkE FIGHTING PROCEOURES ----....-- -- -...-------- ...-------- ...------.-- - __ _ ,____" _~9!:_~lic~,~J~_"'_ ,.__:____p_____,.. - ._------ ----.-.---.---- -....-.-..-.-- --- .---. l..'NL'S U A CfiR'i:'-Ãr~DExPLosï ÕÑ'HA ZA Res-- Not Applicable --.---' ...- ---- ...---.----. _______ .0_'- ____. _ _.. '".._ . .._-_.~----_._--_. ,.--.--" " I :.....ž';. R"t)OÙ~- p¡¡õ"öüëT'š""Õ-';-C-OMBUSTïõÑ-"- Not Applicable -.--------------- ------- -~~- --':--=~-~:':'::';"".~--=--'='''~;';~~----'"''''''='"''~~' ...:.;:-_-==-...:...;..~~~~~~-_. _.:=~..~-:-_::,..:.=:.::::.-.--=-=-::.~~:.-:-;:.=-~-:~ TH:S 1~;~::)?M;.llaN RELATES O~LY TO THE SPECIFIC MATERIA.!.. DESIGNATED A"O I.IAY NOT 8!: VALID FOR SUCH MATêRIAL USED IN COM8J'~ATlON WITH A~IY OTHER I.'AìERIALS OR I~/ ANY PROCESS, Such inlotr.1at,on is, 10 Ihe best of BC Ch;,rn,.:a'$ knC''''''''~1! and bel,e', accurale bI'Id .el;able as of Ihe d3te indicated. HOWEVER, NO REPRESENTATION, WARRANTY OR GUARAN1EE IS MADE: AS TO ITS ACCURACY. REUABIUTY OR COMPLE;TENESS, IT IS THE US[R'S RêSPO';SI8IUTY TO SATISFY HIMSELF AS TO THE SUiìASLE~;~SS A!\¡O COM?LETENESS OF SUCH INFORMAnON FOR HIS O'.vN P;;HlCUL"-R USE, 21 e -- ; SECTION V· HEALTH HAZARD DATA THRESHOL.D L.IMIT VAL.UE Rats survived 8 hour exposure to saturated vapors. )~~dictab1þ:ªr~1~oggd exposure to vapors by humans is irritating to- EFFECTS OF OVEREXPOSURE ACUTE e es & res ~ a or assaoes. CHRONIC Prolonaed skin contact causes faint redness & tannina effects. EMERGENCY .AoNP FIRST .AoID PROCEPURES Followina contact: Flush eves & skin with water for atle...~r fifteen (15) minutes. Remove victim to fresh air. artifical respiration if necessarY. CALL A PHYSICIAN. SECTION VI· REACTIVITY DATA -- ST ABIL.ITY CONOITIONS TC" AVOID U~JSTAalE STABLE X NOT APPLICABLE INCOMPATIBIL.ITY (MATERIA~ TO AVOID FOR PURPOSES OF TR.AoNSPORT. HANDL.ING a. STORAGE ONL.Y) Transport: 5 t.ore in baked phenolic-lined steel or 55. 01; in approved reinforced vessels. Heating & insulation is indicated, as required. Avoid hi-temp. HAZARDOUS DECOMPOSITION PRODUCTS Aldehydes: Avoid inhalation, skin, & eye contact. , SECTION VII . SPILL OR LEAK PROCEDURES : STEPS 10 BE TAKEN IN CASE MATERIAL. IS RELEASED OR SPILLED Shut off source if possible. Advise I I authorities if substance has entered a water course. I WASTE DISPOtAL (lNS,URE c01"P~IIY WIT ,¡ \5'C£'jL DISP~AL REGULffi'ONSci d'l t 'th t Recover by onta~n Sp1 e ~qu~a 1 n san or ear an 1 u e w~ wa er. purnping or with suitable absorbent. If spilled, it may be possible to deactivate the solution carefully with ammonium hydroxide or w/aqueous sodium bisulfite to sT1ghtly baS1C. SECTION VIII - PERSONAL PROïECTION INFORMATION RESPI RATORV PROTECTlpN . . Use approved respiratory protection such as a1r supp11ed if in enclosed spaces.. LOCA'LE~HAUST " . ISPËCÏAL Not needed in open/unconf1ned I MECHANICAL ICUlad)~EA Forced vent~lation if needed. -1-_ __ PR'(:H-¿-é"Ti'VEGLOVES ~EYE PROTECTION . Chemically r~sistant glove~__1 Approved chem1cal splash goggles. ö'-r"Eq PROTECTiVEEãülPMENT Protective apron of rubber, neoprene, or plastic. VENTILATION SECTION IX - HANDLING AND STORAGE PRECAUTIONS ;'RECAUTION5 TO BE TAKEN IN HANOLING ANa STORING Stored in baked-phenol ie-lined steel or 55. or approved reinforced plas!~.<:,_,_ ._--~_. vessels. K~ep containers closed when not in use/avoid hi-temp. Wear protective clothing & --.. ----------- OTHt:R P"ECAUTlONS accessorie'S-as dešcribed':- NONE .-.-.--.---.--.------ ---..-- ---'--'-'---'-" ._.- ~-ÃT-E'-ÕF-;5SUE---"--- APPAOV;D Bv_.ÆÞ'l~~'~:'1 / Reg~,.c~e~g:~'~;18;~ ~ l NEW DREv,SED: SUPERSEDES TITLE:' {/ ~dus{riai -Hygiene Director p~_.'":,:,:. . - - ----..;..--.-=---- - ---.=:-:---....;..-..:..==-.=.=....=: --,:.-.-' - -- _. -=-:.=-=--..._-_._~_.--~ 22 ~~' -: .~" '\? , e e --. ----. .-.--- - CHEMICALS MATERIAL SAFETY DATA SHEET PROOUCT - (ApPlolfød by U.S. Oøparun'lnt of L.bor., ".,unri.//" simil.r· to Fonn LSS-OOS-41 SECTION I·IDENTIFICATION OF PRODUCT MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. BC Chemicals AOCRE5S (Numoer,-slrcu. CilY, ~tatt! and ZiP Code) 1511 SO. Union Ave. Bakersfield, Calif. 93307 (805) 832-1360 , TRAOE NAME CHEMICAL NAME BC Microbiocide 2000 Gluteraldehyde CHEMICAL FAMILY CHEMICAL FORMULA Aldehydes DHCC3H6CHO SECTION II-HAZARDOUS COMPONENTS OF MIXTURES A precise compositlo:1 of this product is proprietary information. A more detailed disclosure win be provided by BC Chemicals 88 privileged Info~ation upon request In case ot need for spec¡ßc lreaÞnent. AQUEOUS: SOLUTION OF ALDEHYDES I FREIGHT DESCRIPTION: CHEMICALS, NOIBN DANGEROUS ARTICLE DESCRIPTION: NONE DOT WARNING LABELS REQUIRED: NONE .-----.--. SECTION III-TYPICAL PHYSICAL DATA SPECIFIC GRAVITY H20=1 1.131 @ 20/200C APPEARANCE ANO OOOR CLEAR LIQUID, SHARP ODOR -,- BOILING POINT (oF) 760 MM Hg=101.2oC (214.20F) PERCENT VOLATILE (BY VOLUME) 50 (WATER) . -.---.-----.----..-... .._--_. .-.--.-----.------ ----- --.-------..--- EVAPORÄTlON RATE (n-8U"rYI..ACETATE-li 0.93 '.'APOR PRES5URE ----- ------.....--.--. ....- --...----.-.-.-. .----------.-..------. .-..---... VAPOR DENSITV (D,IR 1) 'OLUO'L,TY '" ~:~E;:::C:~~:E---- -1------------ L_____~-=-,_______õT--·~~N-~~,(-FIR-E AND ~PLOSION HAZARD D~iA ~'"J:- -.----+------- FLA$:-o ;>ûlNT (.lfe/hod) None, C.Leve.LdJ,anu open cup lLAMMABLE I-IMITS I..el I U.' (PERCENT BY vOI-UME) -""=-C:-:'~''7''i---:"!..--' ASTMD92¡ None, Tag Closed cup ASTM D-56 .U metuano ,U metua 0 FiH'£ËxTINcuïsHIr;¡'GliM::DIATf-Water'is boiled ó-ff, -res-iduãl cãñ'cur~"-'Úsë--water sp'iay car on-" -- '~' dioxide, dry chemical, alcohol-type or universal-type foams applied by mfgr. recommended tee ~pŒiÃL;ïRe:-F-ïG¡::¡;:ii',¡-G'PROëED-URËŠ-'-- _____.._______d_~ -----,-,--._-----'-,----', , 1.._ ,-.-".. ',_,...~e~~~c~~~~~::~,~.Èrea,1:!1_~::,~_~f:?par~.t~~,_.~1;:~___ ,-,. ----". .,., ',- ___.._,___'_d__'_._,,__'_,· -- '1 ~ J [L'NÜSlJÃL"F!RF.AMÖ'Ë;",zPLOŠiÖ¡:¡'H'ÀZ-ÃROŠ--- -, ,--- ____.____.________u __.._____.,_________'u_'_'__·, -' : I I \ I I i NONE ._. _..__.._ .___.._.. __0'_.. _...__._._.__ __.___.__..__.__ ..-.- .--- .-.-..---- .-..-. .. ___.. __. ._0'_'. .... .'Ã-i'"iï(Ir:'..Js-,;;¡oõi.ïu5'Õ'FcoM"åUšï';õÑ'- --- -..-.-,--------- --,---' ---- ---. ,- _'.'_u__, ,-- ~,~"'_,, _~ :~_ ~1J~p.in_pgJ!@y-,.P.~_oßµc.e _,ca:¡;þon_ ffi.QnO.J.Cig,IL é!,I1ªLq!"_S<;1rb_Q~ ,_c;ì..i9;J,:{.iq~""",-~=~,"-,-=-~- ,". . .- - TH'S INFOBMATION AELATE:S '.JNLY 101'1.11:: SPECIFIC MATERIAL DESIGNATED' HOWEVER ~IO R¡;:PRI::SENtATI0N WARRANTY OR GUARANTEE: 15IAA','~ ,\ti TC AND M""f N01 BE VAUC FOR SUCH MATERõAL USED IN COM81NATION WITH ITS ACCURACY. RELIABILITY OR COMPLETENESS IT 15 THE us¡;r, ;', ANY 01 Ht:R M¡. rERI.A,LS OR IN ANY PAOC¡;S5 Such ¡rlarlT,:¡tIOn IS, 10 the besl 01 AESPONSI81UTY TO SATISFY HIMSELF AS TO THE SUI~ "-8l ENI::S5 "~~j1 ac C~,~m"~àl:; kllowledge and bellEfI accur~tø and 'ehaDle liS ot ItIe oate indicated. COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PART CUIAR :,.'::;1: e e SECTION V· HEALTH HAZARD DATA THRESHOL.O LIMIT VALUE 0.2 ppm ceiling, ACGlH (1979) EFFECTS OF OVEREXPOSURE ACUTE If swallowed-nausea, if inhaled-chest discomfort, bronchitis symptom cHRoNlcProlonged or repeated skin contact may cause rash & sensitization EMERGfNCY P.ND FIR$T AID PRS.CEOURES Swa low1ng: G1ve 2 g asses of water-induce vomiting by putting finger down throat. Call phy- sician/Skin: Flush skin with plenty of water-remove contaminated clothing-wash clothing be- fore wearing again/Inhalation: Remove to fresh air, call physician if symptoms persist/Eyes: flush eyes with plenty of water at least 15 min., get medical care eye specialist at once SECTION VI· REACTIVITY DATA -- ST ABI L.ITY CONDITIONS TC'I AVOID UN5TA3LE Avoid high temperatures 200oF) (removal of water, STABLE X IN~OMPATlBIL.ITY (MATERIAL.S TO AVOID FDR PURPOSES DF TRANSPORT. HANOL.ING a. STORAGE ONL.VI , Avoid contamination with acids any alkalies. HAZAROOUS OECOMPOSITION PRODUCTS Burning may produce carbon dioxide and/or carbon dioxide. SECTION VII . SPI LL OR LEAK PROCEDURES STE.PS TO BE TAKEN IN CASE MATERIAL. IS REL.EASEO OR SPIL.L.ED . , 'd disc ar e to natural waters Small spills flush with large quantites of water. Low cone. 0 Large spills posal. Spilled material can be decontaminated with careful application of sodium hydroxide WASTE OISPOS.A.L (lN$URE CONFORMITY WITH L.OCAL. DISPOSAL. REGU1.ATIONS) .' ot inc' e ator fire mix wit -- a where permitted by Federal, State and local regulations. e s l_:rate r--' í fi :;:SPI RATÕf~VPROTËëTïõN ¡--'-----'-J-öë.AL E~~~~S~llP.Pl.ied ma!'>k in .hÜJh, conc~nt~PEÍ'I.ALC;apors are .- r v eye or nose irritating, V-NTI ATlON ~ø('t>"n'C'al ...nnm "ønt-,l"t-,n'" Co,,,, MECHANICAL rGe11uqJ) , IOTHER , , . . d " d__' _' ____ Expecteà to b: sat1sfactory I , spec1al forced vent11at1on may be req 1re 1"~orECTlVE GLOVES =rYE PROTECTION f Rubber Vapor-proo goggles. ~. .. .._-~...- -~... ------.----------.-..-.--..-- . ¡.JrHER PRorECTlvE EQUIPMENT Eye bath, safety shower, rubber overshoes SECTION VIII - PERSONAL PROìECTION INFORMATION ..._____0-_--- .__._...__" ! __0___-.. i SECTION IX· HANDLING AND STORAGE PRECAUTIONS ¡,~'RE-¿Aür:O;:¡~;:¡õè-t=. TÃKE~;¡ NHA-ÑDLïÑGÃÑQ-šTõRING Use w1t:nåàequate vent~lat10n. wasn ¡", ' .l2?E-ª-ling_..__Avo~d breathing vapor. ~~,C?~~e~.:.yes, ~.::.. sk~n, clothing. I closed. FOR INDUSTRY USE ONLY. ! í;:¡¡;"t::'M PÅËëAuTlo-r~-Š'o-:-'-"---, -..--- ,---- I . We~1:'__9..~gg,!~~,_?r;_ J.~~shield and rubber gloves when handling. i , ,. ,on' 0 __n_'_ ,- "_______,__ :;A' E OF ISSUE l ¡ ~;tW ,[]REVISED: SUPERSEDt:5 ..~---.._~.~~;.::~-------- - -. thoroughly arter Keep container -- ..------- },,:::-;:u_/ f/ TITLE: 7" .;¡ - - - -- zt;: ___0 ~" .:_--------- -'-'.-- 24 e B.C. AMAZING e B.C'. AMAZING 1 gallon 5 gallons ECOLOGICALLY SAFE: The ingredients in B.C. Amazing products are bio-degradable - they will break down into natural components without harming the environment. There are no phosphates, enzymes, or other chemical ingredients known to cause pollution, in any B.C. Amazing product. ECONOMICAL: B.C. Amazing products are concentrated. That means you use less - a . little goes a long way. There are no "fillers" that serve only to bulk up a product and make it look like you are getting more than you are. EFFECTIVE: There are no better products of their kind on the market than B.C. Amazing products. Because they are different, because they do not contain some of the harmful ingredients many people are used to, when they clean their stoves with B.C. Amazing and find there are no dangerous fumes and no skin irritation. The effectiveness of products as good as B.C. Amazing can be unexpected and surprising. When the results are so far superior to most other products, it takes some getting used to. So suggest to every ..customer that directions be followed carefully, rather than using B.V. Amazing products "the way they've used that kind of product before!" VERSA TIUTY vs OVERKILL: Although we use the term "all-purpose cleaner" on the label of B.C. Amazing, since that has become more or less the generic term for the type of cleaner it represents, there really is no such thing as an "all-purpose" cleaner. So-called all-purpose products tend toward "overkill". They cater to man's search for the easiest way, rather than the best way. But no liquid cleaner designed to be used for scrubbing floors can be made powerful enough to remove stubborn stains, with being too powerful for gentler tasks. That's why B.C. Amazing products have been carefully formulated to provide safe, effective, and appropriate results for the task to be done according to how they are used. The versatility of B.C. Amazing products lets YOU decide how strong a cleaner YOU need for each job. . The label on B.C. Amazing describes this product as "a modern, soapless product made from a balanced formula of organic ingredients, completely free of skin and eye irritants". Let's look at each term in the name of this remarkable personal cleaner and see why we can make the claims we do for it: SOAPLESS: There are no alkalies, no phosphates, no soda ash, no artificial chemicals, or other harsh, irritating or polluting ingredients in B.C. Amazing. It will leave behind no soap scum or other residual waste. It rinses away cleanly and completely without drying the skin or leaving residues or washed surfaces. ORGANIC: The ingredients in B.C. Amazing are organic, that is, composed of the same types of carbon molecules that make up natural living matter. Thus, they are not only mild, but also biodegradable - capable of breaking down and returning to the earth, without endangering any living thing. CONCENTRATE: A little bit of B.C. Amazing goes a long way. That's why we offer a mixing bottle to go with it. All directions on the label are for B.C. Amazing diluted half and half with water - then measured in teaspoonfuls! That's real concentrated action - and real economy for any "personal touch" cleaning job! 'I , e e IMPORTANT: To prepare B.C. Amazing, fill a mixing bottle half way with water first; then add the Concentrate; stir or mix gently. TO DEMONSTRATE B.C. AMAZING: Always use B.C. Amazing according to directions, in a No. 501 Jiffy Dispenser with No. 502 Flip-top on the 16 oz. size. ECONOMY: Point out that even after dilution, only a very small amount of B.C. Amazing is needed for most ordinary jobs. GENTLENESS: Place a drop of B.C. Amazing from the mixing bottle into the hand of your prospect. Ask her to rub it in as she would a hand lotion. As she does, explain that B.C. Amazing is gentle enough to use in bathing an infant, and that in addition to cleaning, it actually acts much like a hand lotion in moisturing and conditioning the skin. Rinse the B.C. Amazing off with a damp washcloth or under a tap. NON-FLAMMABIUTY: Remove the cap from a bottle of B.C. Amazing and wave a match back and forth over the opening. Point out that the fumes do not ignite. Next, extinguish the match by dropping a bit of B.C. Amazing onto the flame. (A wooden match provides a better demonstration than a paper match.) EFFECTIVENESS: Mark the back of your hand with lipstick and with a ball point pen, then massage in a dab of B.C. Amazing. Point out how the two difficult-to-remove blots immediately begin to be lifted from the skin by the B.C. Amazing handkerchief, then . . . . . . show the handkerchief stained with the lipstick and ink to your prospect. Rub the stain in for better effect. Explaining that the dab of B.C. Amazing you cleaned your hand with is still enough to clean the handkerchief, dip the handkerchief under a faucet, squeeze it clean, and display the spotless handkerchief to your prospect. Point out that B.C. Amazing is harmless to fine fabrics. Smear a steak of shoe polish, paint or grease across your palm (if you want to let this dry, you can demonstrate the match test or ask the prospect to feel B.C. Amazing for herself at this point). Point out that this technique provides excellent protection for the hands while doing a job of painting, repairing greasy machinery, gardening, etc. Finally, rinse your hands in a bowl of water or under a faucet and show how the "invisible gloves" have helped protect your hands. AUTO WASHING: Mix 2 capfuls of B.C. Amazing to a bucket of water. To remove tar from any auto finish, use the Jiffy Sprayer with B.C. Amazing, medium or strong solution, then wash with B.C. Amazing to avoid stripping wax from the finish. SUGGESTED DEMONSTRATION AIDS: Jiffy Dispenser with Pump; bowl of water; damp washcloth; handkerchief; lipstick; etc. You'll want to change or add demonstrations as you gain experience, of course - but always practice before you use them on a prospect. 27 B'P.W.101 PARAFFIN DISPER!NT 5 gallons 55 gallons BC P.W. 101 Paraffin Dispersant BC P.W. 101, a~ effective w~ter-dispersible par.~ffin-rem~val additive, is a high-flash, low-odor hydrocarbon solvent-d!spers~nt. This bl~nd helps solublh~e and disperse paraffin and asphaltic deposits. A water-external dispersion made with BC P.W. 101 IS an excellent substitute for hot-oil treatments, especially where oil spills and contamination are critical. Most paraffin dispersan,ts do not function in aqueous systems as well as BC P. W. 1 01 nor do they have as effective paraffin-disolving properties. APPLICATIONS Well bore and Tubing Cleanout BC P.W. 101 can be dispersed in water or acid to clean tubular goods of: paraffin and asphaltenes allowing resumption of normal production, paraffins, asphaltenes, and other hydrocarbons prior to other stimulation treatments. BC P.W. 101 can also be used in aromatic solvents and/or mutual solvents to help water-wet solids as the heavy hydrocarbons are solubilized by the solvents. The proper concentration of BC P. W. 1 01 to be added to water for optimum cleaning depends primarily on the amount of paraffin present, the hardness of the deposit, the adhesiveness of the deposit, and the temperature at which the paraffin is deposited. A general recommendation is: Cold Water (below 75°F)· Use 10% by volume of BC P. W. 101 Warm Water (75· 1 OOOF)- Use 5%by volume of BC P.W. 101 Hot Water (1 00 - 150°F) - Use 2% by volume of BC P.W. 101 Very Hot Water (150· 200°F) - Use 1 % by volume of BC P.W. 101 To compute volume: Diameter of casing Standing fluid in casing Feet of perforation in casing CAUTION When used for tubing cleanout, the water temperature should never be hotter than the formation face because any paraffin that has melted in the treated water will re-deposit on the colder formation causing damage. Flow Une Cleanout BC P. W. 101 can be dispersed in water to clean flow lines. The above treat rates apply to flow-line cleanout. However, the water should be heated to as high a temperature as practical for most efficient removal. If the flow line is long and/or cooled by water (offshore), it may be necessary to increase the concentration of BC P.W. 101 to 5%. BC P.W. 101 will work in cold water at higher concentrations. If the water starts off hot then cools, the BC P. W. 1 01 will keep the removed solids dispersed. NOTE If large amounts of paraffin are deposited it may be necessary to use several lower-temperature treatments so as not to remove too large an amount of paraffins at one time, thereby physically blocking system. MIXING PROCEDURES BC P.W. 101 can be added to any aqueous fluis and a uniform dispersion can be achieved with only a small amount of agitation. If left static, the dispersion of BC P.W. 101 in water is stable up to an hour. Reagitation prior to pumping the fluid is recommended. SOLUBILITY Soluble in hydrocarbons Dispersible in fresh water, salt water, acids ?R ~-1, e e This product is available in bulk shipments and 55 gallon NR drums. Keep drum openings closed to prevent product contamination and evaporation. BC P. W. 101 contains no organic halides, heavy metals, or other substances known to be harmful to process equipment or refinery catalysts. No special storage and handling precaution is required. Avoid prolonged and repeated skin contact. In case of contact with skin or eyes, flush exposed area with water. PROCEDURE , Batch feed BC P .W. 101 per general recommendation at point "B". Let it sit for approximately 24 hours. Be sure BC P. W. 1 01 is completely mixed with fluid in well. Put well back on the line. BC P. W. , 1 01 will perform an effective cleaning function throughout the entire system including all flow lines and valves. To eliminate future paraffin buildup, a daily maintenance program should be followed. Inject at point "A" 2 quarts of BC P. W. 1 01 every 24 hours per 1 00 barrels of produced oil. The simple and inexpensive procedures described above will virtually eliminate costly down time due to paraffin cake buildup. 29 · e e -....--..-. ._~.- .---- COREXIT -. MATERIAL SAFETY DATA SHEET (Appro,,"'; þy U.s. DI!P.run.nr of L.bor., ·'.u.nri.lly ';mil.r~ to Form LSB-OOS·4 PRODUCT CHEMICALS SECTION I-IDENTIFICATION OF PRODUCT MANUFACTURER'S NAME EMERGENCV TELEPI-fONE NO. B.C. Chemicals Inc. AODRESS (/Vumlil!,.~rl!u. City. SIIIII! IInlt z./J' c;odlJ (805) 832-1360 1511 South Union Ave. , Bakersfield, CA 933.07 TRADE NAME CHEMICAL NAME B.C. PW 101 Not Applicable: blend of materials CHEMICAL FAMILV CHEMICAL FORMULA Surfactant in aromatic solvents Not Applicable: blend of materials SECTION II·HAZARDOUS COMPONENTS OF MIXTURES A'preclse ~positlon of this product, Is proprietary Information. A more detailed disclosure will be provided by BC ëhemic:als as pr1vileged i~f~Ûon upon request In case 01 need 101 spec¡ftc treatment. Blend of oxyalkylated alcohols and oxyalkylated alkyl Phenol in glycol ether and aromatic solvent. I APPEARANCE AND OOOR Light blue liquid BOILING POINT (OF) 358°F/180°C SECTION III-TYPICAL PHYSICAL DATA SPECIFIC GRAVITV 0.900 @ 60o/60oF .-- VAPOR PRESSURE EVAPORATION RATE In- BUTVL ACETATE" 1) 0.55 VAPOR DENSITV (AIR l) gr~ater than 1 SOL..UBILITY IN WATER 25% by volume, forms emulsion SECTION IV·FIRE AND EXPLOSION HAZARD DATA Fï:'ÚHPOiNT (Method) PM No. 2600 1300F FiFiEIiXTINGUISHING MEDIA _1-,.__.. Extinguish with dry chemical(carbon dioxide or foam)watersp~ay may be in- ',PËï:IA¡:-FIRE FIGHTiNG PROCÊDURES - .----, ,_ ~j:(e~_t,~y~~.~.~ti.~~!.shin(;:L~~nt~..~_L~ir~~~pos~_ð.: ._!!.l:Efa_c_es and protec..E----'-1 __~.E~r,so.~n~l wit~_atersp:r:.~. UNUS~J"'L.. FIRE AND EXPl.OSION i-iAZARCS _,_ª~_~pirator-y"_~~~ct:ion required for fire fiqh,tin~~rsonnel..:.___,_,___J I ----. ---.----.. I~'Ä iÄ p,-óoü-s'p RÒÕÜ-¿i'SCFCõ'M-šuS T ION Carbon monoxide, carbon dioxide, smoke, fumes, aromatic volatiles. ..______ d__ _ _-.:.._~} .._. .. ~--'-"""-_.'-~"--- - ______-----.. .---.__.___0. THIS INFORMATION RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR SUCH MATERIAL US(!D IN COMBINATION WITH ANY OTHtòR MATERIALS OR IN ANY PROCESS, Such information IS. to the best 01 BC Che'!lIcals ~owledge aIId belie:, accurate a.,d reliable as 01 the date indicated. HOWEVER, NO REPRESENTATION. WARRANTY OR GUARANTEJ: IS MADE AS TO ITS ACCURACY, RELIABILITY OR COMPLETENESS. IT IS THE USER'S RESPONSIBIUr¡ TO SATISFY HIMSELF AS TO THE SUITABLENESS AN;) COMPLETENESS OF SUCH INFORMATION FOR HIS OWN PARTICULAR USE 30 e e SECTION V· HEALTH HAZARD DATA TI-fRESI-fOLO LIMIT VALUE UNKNOWN EFFECTS OF OVEREXPOSURE A~t~~~~yJ.E~i¡ß~à~gedOtfi~~ng~n~h~y~~i~~dvã~ð~~r~¡~rïr~îEã£~es. eyes. J?rol~n~ed skin contact may cause dermatitis and skin CHRONIC J.rrJ. a J.on. EMERGENCY ANO FIRST AIO PROCEDURfS Remove to fresh air. I not breathing, apply artificial respiration and CALL A PHYSICIAN. Wash eyes with plenty of water for at least 15 minutes. Wash skin with soap and water., SECTION VI· REACTIVITY DATA STABILITY -- CONDITIONS TO AVOID UNSTA3LE X Not Applicable STABLE INCOMPATIBIL.ITY (MATERIALS TO AVOID FOR PURPOSES OF TRANSPORT, HANDL.ING . STORAGE ONL.Y) Strong oxidizing agents and mineral acids. I-fAZAROOUS OECOMPOSITION PROOUCTS Not Applicable SECTION VII· SPILL OR LEAK PROCEDURES sPéH,o ~V~~Er-rI~8iàs'1r~ífj!êL; IS~b¥sffi<tR !iJ'&èrrct: e , if possible to do so safely. Advise authorities if substance has entered a watercourse, sewer, or has contamin- ated soil or vegetation. wð.òV¡ €1ff9,.SA's P '1$ffé á°r-r£&~'Ð1 w~lrtficb9Œ'O~t ~M1f-ð1I°â'Wd ---' dilute with water. Recover by pumping or with suitable absorbent. Consult an expert on disposal of recover- ed material. f SECTION VIII- PERSONAL PROïECTlON INFORMATION ¡:ŒšpiRAiQ~Y PRO;(E.!:'t!ON It used J.n con J.ne sºaces or 0 er poor v yen ~ use NrOSH7ML~A approved respJ.ratory protect~on such as a1r-supp i..OCAL Ot;iAUST SPECIAL t ace ve 0 C J. Y J. n PrOV~de greater than 60 fpm hood spaces. VENTILATION MECI-fANICAJ,..IG~""'al) ., ~OTHER Explos~on-proof vent11at1on equJ. ment __._.__..___ 4'_ .______._-....-.- ...---.--. PROTECTiVE ':;LOVF;S J E,:o'£ PROTECTiON Chemically resistant gloves, ~nemica splash 90gŒles ÜT-HË'¡¡-PROTËëï'ïVE eQUIPMENT·---'--·n'-,-_-- ---,--, ---' Usually nc:~~eded ----------- ----- --- [------ SECTION IX· HANDLING AND STORAGE PRECAUTIONS (R'ECAUiïòNS TOB"ETÃ-K'E"NiN HANDLING AND STORINcObserve hazarã preéau~To-ñ-Š-w~ tñ--empEieaëo-ñ-'= I, _t:ë;iir:!.~ s. Ke ep con t~,~ n~.::.;;__c 1 0 s:..~__whe ~.,_~:,~,!..::__~,:.=-.:_.~~~ ~_,~~~~~¡~ hea t, s p¿¡ r k s , and open flames. . M ___..__. . .0.. ..______._.__~._._. _________.______..__________.__.__..___ OTHER PRECAUTIONS ~~E!2.._awªy__~_rom If_~~,~,L spark~..2nd ~pen _ flame s . -----.... --_#- -..-.- .--.--------- r' NEW L]RE'.JISEO: SUPERSEDES ":a"'-_':~-"~ -.--..----- ----- .- . .'0 1 ,--------' --'-----~ /7 ' ' j;;PPROVED 8Y-...J:~' ~U.;!::I..<._..____,____"_.._ '.- ,,-, TITLE: Director O( Industrial Hygien~ .' 'or' - _ - DATE:.OF'~~'E-'·-------·--- ----- 31 RESINS (Bulk or 50 gal bbls.) GEL TIME PEAK PEAK VISCOSITY HEAT FLEXURAL FLEXURAL TENSIL MINUTES EXOTHERM TIME 77F THIXOTROPIC BARCOL DEFLECTION STRENGTH MODULUS 'STRENGTH ELONGATION PRODUCT TYPE PROMOTED 77 F F MINUTES CPS INDEX HARDNESS TEMPERA TURE PSI X 10' PSI PSI % COMMENTS GENERAL PURPOSE LAMINATING RESINS Allek 063,9 Rigid Ves 7·11 310,360 16'24 400,600 2,7'3,6 38,44 150 14,000 48 7,600 1,7 Moderale CUle, lasl weUinQ resins with excellent drain resistance. Allek 083, 14 Rigid Ves 12,18 310,360 27,31 400,600 2,7,3,6 38,44 150 14.000 46 7.800 1,7 Allek 063·19 Rigid Yes 11·21 310,360 30,35 400,600 2,7·3,8 38·44 150 14,000 48 7.600 1,7 Allek 298,9 Rigid Yes 7·11 330,400 16,20 400,800 2,7'3,6 40·44 165 18,000 5,0 8,500 1,7 fasler curing. general purpose laminating resin than the 063 series, Allek 198·14 Rigid Yes 12,18 330,400 22,27 400,600 2,7·3,6 40·44 185 16,000 5,0 8,500 1,7 Allek 2i!8·19 Rigid Yes 11,21 330,400 30,35 400,600 2,7'3,8 40·44 165 16,000 50 8.500 1,7 Allek 156,13 Rigid Yes 11-15 330·400 22,26 400,600 2,7·3,8 40·44 165 16.000 5,0 8,500 1,7 Moderele gel lime wilh good hardness developme RESINS FOR USE IN ALUMINUM HYDRATE AND VITROFIL FILLED SYSTEMS Very resistant 10 drain when '.Ued. gtves good cure Altek 098 SemiRigid Yes 6·10 330·390 12·18 100·130 1,7'2,1 33,41 NIl. NIl.· FiUed WIATH and hardness development. Allek 315 SemiRigid Yes 6,10 330·390 11-18 100,130 1,7·2,1 34,44 NIl. NIl.· FiUed WIATH Fasler curing verSion 01 Allek 096, RESINS FOR SYNTHETIC MARBLE + ONYX Allek 035 Rigid Yes 8,12 265,310 18'24 700,900 NIl. 36·44 150 12,500 5,0 6.400 1,2 Tops. llals. moderale gel. moderale cure, Allek 141 Rigid Yes 7·11 265,310 11·22 900·1100 NIl. 36·44 150 12.500 5,0 6,400 1,2 Tops, llats _ &mal integrals, last gel cure _ darnold, Allek 200 Rigid Yes 9·13 275,305 18,24 1300,1100 NIl. 37·42 150 12,500 5,0 6.400 1,2 Tops. inlegral bowls·IeSS shrinkage lhan Allek 035, Allek 297 SemiRigid Yes 14·18 260,290 30,34 950·1150 NIl. 34·39 110 11.000 5,0 6,000 22 Good lIe.ibiüty lor manufacturing then marble sheet. Altek 319 Rigid Yes 11-16 310,340 25'35 1050·1250 NIl. 38,46 165 16,000 5.0 6,500 1,7 E.ceUent color,recommended lor high quality ony. applicalions,llals and inlegrals. rapid darnold, Allek 333 Rigid Yes 5,9 310·340 10,16 900·1100 NIl. 38'46 165 16.000 5,0 8,500 1,7 Tops and llals . lasl gel and cure, Allek 334 Rigid Yes 8·12 265,310 16,24 2600,3400 NIl. 36·44 150 12.500 5,0 6.400 1,2 E.lremely high viscosily lor lops and llals, Moderale gel. moderate cure. Exhi~ts Aow8r shrinkage RESINS FOR CLEAR CASTING ANO DECORATIVE USES Allek 331 Rigid Yes 11-16 315,335 30,38 400,600 NIl. 38,46 16,000 50 8,500 1,7 Excellent color. recommended tor clear cashng Of 165 decorat",. appbcations. moderate gel. moderate cure. ISOPHTHALlC RESINS Allek 1660 SemiRigid Yes 11-15 360,420 21,27 400,600 2,4,3,2 30·34 210 17 ,000 40 10.000 3,6 Moderate corrosion resistance. e_hlbihng high elongation. Septic tanks. aprayer lanks and 'eeders AlIQk 264 Rigid Yes 11-15 400,425 21,27 400,600 2,4'3,2 38·42 220 16,000 5,0 7,000 ' 1,8 Moderate corroSion reslslance. moderale elor¡:.'·..·· higher heal deflecllon lemperalure. Similar apph"'°I,,'It:) 10 Allek 1660, Allek 336 Rig,d Yes 11-15 400,425 l'\ 27 400,600 2,4,3,2 Oood Corrosion resistance. good heal detlecloon temperalure TRADEMARK Alpha Resins e e 6. Justification and rationale for locations, construction, sampling contaminants to be analyzed. monitoring well frequency, and 7. Sampling equipment and procedures. 8. Analytical methods and QA/QC procedures. E. Surface Water Runoff (off-site) 1. Facility map showing on-site drainage patterns and evaluation of off-site migration. 2. Area map showi ng off -site drainage patterns and potentially impacted surface water bodies. 3. Off-site surface soil and surface water sampling plans. F. Air Quality 1. Assessment report addressing potential for air borne mi g rat i on of contami nants and thei r pub 1 i c hea 1 th and environmental impacts. 2. Air Sampling Program. VI. Time Schedul e for RI Work Pl an Impl ementati on From Date of DOHS Approva 1 A. Field Investigation B. Laboratory Analysis C. Interim Reports Submittal D. Engineering Analysis of Data Collected during RI Process E. Submittal of Final RI Report e e APPENDIX B DOHS - SITE CHARACTERIZATION WORKPLAN OUTLINE I. Site Background A. Si te Maps 1. Topographic maps showing site location. 2. .Site specific plot plan (including all process equipment, surface and subsurface piping, tanks and waste handl ing units) . B. Nature of Problem (Description of Past and Presnet Disposal Activities, spills and waste handling practices both on site and off site). C. Extent of Problem (Documentation of Suspected On-site and Off- site Contamination Areas). D. History of Response (General Description of any Past Remedial Actions). II. Quality Control/Quality Assurance (QA/QC) Plan A. QA/QC Aspects of Sampling 1. Collection of field samples a. personnel training b. equipment calibration and maintenance c. sample collection procedures d. chain-of-custody forms and procedures e. sample preservation procedures B. QA/QC Aspects of Laboratory Activities 1. Verification of laboratory certification by DOHS 2. Laborat.ory sample analysis qual ity, control program a. internal spikes b. internal duplicates c. blind duplicate d. internal blanks e e Duri ng the purgi ng operati on, purged water wi 11 be monitored for tem- perature, pH, or conductivity as a function of time or volume. All records of the above data will be kept in a water-proof fi e 1 d notebook in the following format: WELL # DATE PROJ. # TOTAL DEPTH TOC ,211 PUMP # RECORD DEPTH TO WATER TOC 411 PUMP # GL TOC GL = BAI L/ I N PLACE PUMP CALC~ EVAC. VOL. ACT. EV AC. VOL. SAMPLES: COMMENTS: After the cal cul ated purge vol ume has been removed, sampl es wi 11 be collected. With as little interruption in pumping rates as possible, the pump effl uent is di rected into appropri ate containers. For the volatile organics, care must be taken not to allow the force of the sample stream to introduce air bubbles into the sample. These bottles must be filled completely such that no air is present in the bottle. Invert the bottle after capping and tap to see that no air bubbles are present. Appropriate containers for volatile organics are glass bottles of at least 40 milliliters in size fitted with teflon-faced silicon septa. Appropri ate contai ners for semi -vol atil es (BNA) are one gallon amber bottles fitted with teflon-lined seals. All samples will be collected in duplicate. Field blanks made with organic-free water will be carried into the field and delivered with samples to the laboratory. All sampling containers will be labeled with the following information upon sampling and then immediately placed on ice: t;;;), Job No ~Date (meOn Sampler " ~ ~ .;J (. .. I t \ Source Preservetlon Sample No Samples will remain on ice until delivered to the laboratory. Also at the time of sampling, the sample will be logged on a chain-of-custody form whi ch wi 11 accompany the sampl e to the 1 aboratory. One out of every 10 samples will be submitted to a laboratory other than the primary laboratory to confirm the accuracy of results. e - Prior to sampling at a site, all equipment which will be placed in the well or come in contact with ground water will be disassembled and cl eaned thoroughl y with detergent or tri sodi umphosphate water and then boil ed or steamed with dei oni zed water. Any parts that may have a memory for organics, such as plastic pump valves, bladders, etc., will be cleaned as described above and sonicated, or replaced with new parts. The inside surfaces of pump tubing will be mechanically cleaned to remove adhering silt by blowing cleaning wads through the tubing with compressed nitrogen. Steam condensed deionized water will then be pumped through the lines to chemically clean them. Once cl eaned and reassembl ed, pump bl anks will be obtai ned from each pump by pumpi nÆ; organi c-free water through as when sampl i ng. The pump effluent will be sampled and analyzed for indicator compounds. The results of this analysis must be satisfactory before the pump is taken to the field for use. During field sampling, all equipment surfaces to be placed in the well or that will come in contact with ground water will be cleaned prior to purging or sampling of each well. This cleaning will be performed by boiling or steaming said surfaces with deionized water. Immediately prior to purging each well, the depth from top of well casi ng to top of water surface wi 11 be determi ned to the nearest 0.1 foot and recorded as a portion of the well sample data. The top of well casing elevation will be determined to the nearest 0.1 foot by conventional survey methods. Immediately prior to sampling, standing water in the casing and gravel pack will be purged from the well using a submersible pump or suction pump. Any pumping method that introduces air into the well (such as jet pumping) is unacceptable. For permanent installation, a PVC or Teflon pump such as the Well Wizard Model 1100 or equivalent will be used. Portable units for periodic sampling will be Geotech Small Diameter Well Pump #0500 or equivalent. The amount of water purged pri or to sampl i ng wi 11 be greater than or equal to one bore volume, which is calculated to include the casing volume and the void volume in the gravel pack. Regardless of which pump is used to purge the well, samples will be taken with a submersible sampling pump constructed of inert nonwetting materials, typically teflon and stainless steel. In the event that the well goes dry duri ng the purgi ng operati on, the well will be allowed to recharge before sampling. This period will preferably be less than eight hours, but in no case shall it be more than 24 hours. If the well has not recharged sufficiently within 24 hours to obtain a sample, it will be considered dry and deleted from the program.