HomeMy WebLinkAboutBUSINESS PLAN
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Warehouse
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Warehouse
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.LEY PROPELLER~
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Roll Door
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Machine
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Tank Room
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Propeller Repair Area
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Anodize Rinse Water Evaporator (ACID)
Cyanide Rinse Water Evaporator (Cyanide)
Cadmium P~~te Tank ( CYANIDE)
Cadmium 1 Rinse Tank ( CYANIDE )
Cadmium Final Rinse Tank ( CYANIDE )
Anodize Rinse Sink ( ACID )
Anodize Tank ( ACID )
Rec t if ier
Shower and Eye Wash
Main Electrical Breaker Box
Rest Rooms
Main Water Shut Off
Office
Fire Hydrant
Caustic Soda Storage Drum
Rectifier
Exhaust Fan
Medical Kit & Oxygen
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.MAR..2..5.1994 -"-Valley Propeller Service· ...-
110 Convair Ave.
HAZ. MAT. DJ\C e - . Chico, CA 95926 -.. , -~~--
916-899·8255
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MEMORANDUM
"WE CARE"
December 23, 1991
TO: Valerie Pendergrass
FROM: Barbara Brenner
SUBJECT: Valley Propeller RMPP billing
The review of Valley Propeller's RMPP is now complete. A total of
16 hours were spent reviewing the hazard, risk and consequence
analyses and the RMPP document. The total hours x 45 $ per hour
need to be entered into the computer so that a bill will be
generated. Please not the date that the entry is made on this memo
and file it in Valley Propeller's RMPP file when you are done.
cc: Ralph Huey
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VALLEY PROPELLOR SERVICE 215-000-001200
Overall Site with 1 Fac. Unit
Page
1
t
02/18/93
General Information
i
Location :, 300 WATTS DR Map: 124 Hazard: Moderate
Community:' BAKERSFIELD STATION 05 Griq: 08C FlU: 1 AOV: 0.0
I
I
- Contact Name Title Business Phone - 24-Hour Phone
CLIFF JOHN;SON LAND OWNER (805) 832-6033 x (805) 366-2347
JOHN HIXON COMPANY OWNER (805) 832-6033 x (805) 322-0807
:
Administrative Data
Mail Add:r;s: 300 WATTS DR D&B Number:
City: BAKERSFIELD State: CA Zip: 93307-
Comm Code: 215-005 BAKERSFIELD STATION 05 SIC Code: 3728
I -
Owner: CLIFF JOHNSON Phone: (805) 832-6033
I
Addres's : 752 PARK DR State: CA
,City: BAKERSFIELD Zip: 93306-
I
Summary
SODIUM CYA:NIDE, AN ACUTELY HAZARDOUS MATERIAL, IS USED IN THE ELECTROPLATING
PROCESS. SEE RMPP NOTES, SECTION <H>.
CALL AMERICAN CYANAMIDE - FOR TECHNICAL ASSISTANCE WITH RESPONSE TO CYANIDE
EMRGENCY 4:16-356-8310.
1. (~~.~t_,£~_.Jqf!./!~cJi b,~r~~bV ;~e~~'~§ 1M:N . t'ìf~\¡ia
t I. Y:."f..· ~(p.::i'¡\· ¡'j ~,~ \~. .
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r¡;;'~!i;;"',lc"~\ "i'I"''') :c';"f;:¡l"hl"(.:i··¡ h']¡7,,:;~\'rdJ~'i If\ "'·j\~t''\n·;''\·'~' """,.i""""J'lÆ\
c v \,,~, ,,~¡.;, ......\~....ø . ¥.~,¡ ¡ ~ç.;(-._... """v ~;;..> II ,,;,¡ \'~ 1'~,\',,1 1: '~;~t. "\~~\~J:;
merit plan for_ _..__ _~3fid that !t along With
(Ñåme vf Bus:riOMJ
any corrections constitute a complete and correct man..
agemant p}an for my facility.
i/ì'ijfit//",:in/,; ,
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VALLEY PROPELLOR SERVICE 215-000-001200
Hazmat Inventory List in MCP Order
Page
2
02/18/93
02 - Fixed Containers on Site
P1n-Ref Name/Hazards Form Quantity MCP
02-002 CHROMIC ACID Liquid 351 High
~ Immed H1th GAL
02-004 LACQUER THINNER Liquid 55 High
~ Fire, Immed H1th GAL
02-001 SODIUM CYANIDE SOLUTION Liquid 148 High
~ Immed Hlth GAL
02-003 NAPTHA SOLVENT Liquid 55 Moderate
~ Fire, Immed Hlth - GAL
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02/18/93
VALLEY PROPELLOR SERVICE 215-000-001200
02 - Fixed Containers on Site
Page
3
Hazmat Inventory Detail in MCP Order
02-002 CHROMIC ACID
~ Immed Hlth
Liquid
351 High
GAL
CAS #: 1333-82-0
Trade Secret: No
Form: Liquid
Type: Mixture Days: 365 Use: PLATING
Daily Max GAL ----r-- Daily Average GAL ~ Annual Amount GAL --
351 I 351.0Q I 351.00
Storage r Press T Temp -,
METAL CONTAINR-NONDRUM Ambient Above NE WALL
Location
Conc l
7.0% Chromic Acid, Solid
Components
~ MCP ----rGuide
High I 42
- Notes
02-004 LACQUER THINNER
~ Fire, Immed Hlth
Liquid
55 High
GAL
CAS #: 64742-89-8
Trade Secret: No
Form: Liquid
Type: Mixture Days: 365 Use: CLEANING
Daily Max GAL ----r-- Daily Average GAL ~ Annual Amount GAL --
55 I 28.00 I 55.00
Storage
DRUM/BARREL-METALLIC
r Press T Temp ~ Location
Ambient AmbientlOUTSIDE NWCORNER OF BLDG
Conc
50.0%
20.0%
5.0%
5.0%
5.0%
5.0%
Components
MCP
Moderate
Moderate
Moderate
Moderate
Moderate
High
uide
27
27
26
26
26
28
Petroleum Distillate
Toluene
Methyl Ethyl Ketone
Isobutyl Acetate
Ethyl Alcohol
Methyl Alcohol
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02/18/93
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VALLEY PROPELLOR SERVICE 215-000-001200
02 - Fixed Containers on Site
Page
4
Hazmat Inventory Detail in MCP Order
02-001 SODIUM CYANIDE SOLUTION
~ Immed Hlth
Liquid
148 High
GAL
CAS #: 143-33-9
Trade Secret: No
Form: Liquid
Type: Mixture Days: 365 Use: PLATING
Daily Max GAL ----r-- Daily Average GAL ~ Annual Amount GAL --
148 , 148.00 I 148.00
Storage r Press T Temp ~
METAL CONTAINR-NONDRUM Ambient Ambient NE WALL
Location
Conc l ' Components
15.0% Sodium Cyanide (Na(CN)) (EPA)
r; MCP ~uide
High I 55'
- Notes
02-003 NAPTHA SOLVENT
~ Fire, Immed Hlth
Liquid
55 Moderate
GAL
CAS #: 64742-88-7
Trade Secret: No
Form: Liquid
Type: Pure
Days: 365 Use: CLEANING
Daily Max GAL ----r-- Daily Average GAL ~ Annual Amount GAL --
55 I 55.00 . I 55.00
Storage r Press T Temp -:ì
DRUM/BARREL-METALLIC Ambient AmbientW WALL
Location
- Conc _I
100.0% Naphtha Solvent
Components
r; MCP ~uide
Moderate 27
-- Notes
;
¡
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VALLEY PROPELLOR SERVICE 215-000-001200
00 - Overall Site
Page
5
02/18/93
<D> Notif./E~acuation/Medical
<1> Agency Notification
CALL 911 FOR EMERGENCY ASSISTANCE
SPILLS OR THREATENED RELEASES OF HAZARDOUS MATERIALS EQUAL TO OR EXCEEDING
42 GALLONS, 500 POUNDS OR 200 CUBIC FEET MUST BE REPORTED IMMEDIATELY. ANY
HAZ MAT RELEASE WHICH THREATENS LIFE, HEALTH OR THE ENVIRONMENT MUST ALSO BE
REPORTED. CALL:
BAKERSFIELD FIRE HAZ MAT DIVISION - 326-3979
CA OFFICE OF EMERGENCY SERVICES - 1-800-852-7550
SODIUM CYANIDE $PILLS ~QUA~TO OR EXCEEDING 10 POUNDS MUST ALSO BE REPORTED
TO THE FEDERAL GOVERNMENT. CALL: -
NATIONAL RESPONSE CENTER - 1-800-424-8802
<2> Employee Notif./Evacuation
IN CASE OF SPILLS, BUILDING WOULD BE EVACUATED EXCEPT FOR CLEAN UP CREW.
EMPLOYEES ARE INSTRUCTED TO MEET NEAR THE FIRE HYDRANT ON THE SOUTHWEST
CORNER OF THE PROPERTY DURING AN EVACUATION. SUPERVISORY PERSONNEL WILL
CONDUCT A HEAD COUNT TO VERIFY SAFETY OF THE STAFF.
<3> Public Notif./Evacuation
WE WILL CALL IMMEDIATE NEIGHBORS AND HAVE THEM EVACUATE.
<4> Emergency Medical Plan
NEAREST HOSPITAL - 911
FIRST AID SUPPLIES ON SITE INCLUDE OXYGEN RESUSITATORS.
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VALLEY PROPELLOR SERVICE 215-000-001200
00 - Overall Site
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02/18/93
Page
6
<E> Mitigation/Prevent/Abatemt
<1> Release Prevention
CHROMIC ACID SOLUTION CONTAINED IN 3/16" THICK STAINLESS TANK WITH LID .
SODIUM CYANIDE SOLUTION CONTAINED IN 3/16" THICK STAINLESS TANK WITH LID.
THESE CHEMICALS CONTAINED IN SEPARATE ROOM FROM REST OF SHOP. THE LACQUER
THINNER AND SOLVENT ARE CONTAINED IN 55 GALLON STEEL DRUMS WITH LIDS.
--- ..:.._~ -
<2> Release Containment
PLATING TANKS ARE EQUIPED WITH SECONDARY CONTAINMENT.
<3> Clean Up
I HAVE A STAINLESS CONTAINER, MOPS AND SPONGES TO CONTAIN AND CLEAN UP. WE
ALSO HAVE RUBBER GLOVES AND RUBBER SUITS FOR TH CLEAN UP CREW.
PLATING ROOM CONTAINS AN EYE WASH AND SHOWER FOR DECONTAMINATION PURPOSES.
<4> Other Resource Activation
AMERICAN CYANAMIDE CAN PROVIDE TECHNICAL ASSISTANCE REGARDING CYANIDE
EMERGENCIES. CALL 416-356-8310.
r.
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VALLEY PROPELLOR SERVICE 215-000-001200
00 - Overall Site
Page
7
02/18/93
<F> Site Emergency Factors
<1> Special Hazards
DIP TANKS CONTAIN SODIUM CYANIDE AND CHROMIC ACID. A MIXTURE OF THESE
SOLUTIONS WILL RELEASE HYDROGEN CYANIDE GAS.
- - .1
<2> Utility Shut-Offs
A) GAS - SOUTHEAST CORNER OF BUILDING
B) ELECTRICAL - INSIDE SOUTHEAST CORNER OF BUILDING
C) WATER - OUTSIDE SOUTHEAST CORNER
D) SPECIAL - NONE
E) LOCK BOX - NO
<3> Fire Protec./Avail. Water
PRIVATE FIRE PROTECTION - SHOP IS EQUIPED WITH FIRE EXTINGUISHERS
FIRE HYDRANT - ON NORTHWEST CORNER OF WATTS DR.
I <4> Building Occupancy Level
'" .......'
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VALLEY PROPELLOR SERVICE 215-000-001200
00 - Overall Site
Page
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02/18/93
<G> Training
<1> Page 1
WE HAVE 6 EMPLOYEES AT THIS FACILITY
WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE
BRIEF SUMMARY OF TRAINING:
LITERATURE AND AMERICAN CYANAMIDE TRAINING FILM USED TO EXPLAIN THE
HAZARDS OF CYANIDE, PROPER HANDLING AND SPILL RESPONSE.
W~~TT~N S~AND~~~~º~~~~I~G~ROCEEDURES ARE AVAILABLE TO PLATERS.
<2> Page 2 as needed
I
<3> Held for Future Use
I <4> Held for Future Use
.., ,'" " ~"''i.
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02/18/93
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VALLEY PROPELLOR SERVICE 215-000-001200
00 - Overall Site
Page
9
<H> RMPP DATA
<1> Release Containment
NO STORAGE OF SOLID SODIUM CYANIDE ON SITE.
LIQUID PLATING SOLUTIONS ARE PROTECTED BY SECONDARY CONTAINMENT.
TANKS TO BE COVERED WHEN NOT IN USE.
---- - --- -
~---- -.-
<2> Offsite Consequences
A MONOTOX HYDROGEN CYANIDE DETECTOR AND ALARM IS ONSITE.
AREAS IN WHICH THE MONOTOX SOUNDS NEED TO BE EVACUATED.
<3> In House Capabilities
MONOTOX ALARM AVAILABLE FOR EMERGENCY RESPONSE USE.
f\LA "^- So v{) è "S. :h
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<4> Plant Shutdown Instruction
SHUT DOWN POWER SOURCE AT THE BREAKER BOX.
· Bakersfield Fire Dept. .
. HAZARDOUS MATERIALS DIVISION . "
Date Completed J- 17-qr~)'
(Top of Business Plan)
Inspector '1?re/lner
Business Name: Val ~
"Location: ~n Wa1í~
?IbDPjJer
(
Dr.
) '200
Business Identification No. 215-000
Station No. Hal [r};rí Shift
Verification of Inventory Materials
Verification of Quantities
Verification of Location
Proper Segregation of Material
Comments:
Adequate Inadequate
~ D
~ D
~ D
~ D
D
D -p;¿ (\/OT dlut...
Verification of MSDS Availablity
Number of Employees
Verification of Haz Mat Training
Comments:
~/
D
D
Verification of Abatement Supplies & Procedures
Comments:
~
Emergency Procedures Posted
Containers Properly Labeled
Comments:
D
~
D d.,d not CJ1( G t..
D
D
Verification of Facility Diagram
Special Hazards Associated with this Facility:
rÝ
Violations: í(¿¡if\í/)J mliX 13t rJocumet1Ted. 'KIY1PP ;WlpiR fWlJ\70-ntfYv ¡j.t-.
Business Owner/Manager
FD 1652 (Rev. 1-90)
All Items O.K. D
Correction Needed . D
White-Haz Mat Div. Yellow-Station Copy Pink-Business Copy
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CfTY of BAKERSFIELD 1£.-00 '2~/:,~'~\LJ/~>i\.
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ItYDe or print name)
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Do hereb:;' certify that I ha",-e revieh-ed
RECEIVED
the JAN 25 1989
Ans'd.
......
......
attached Hazardous Materials business plan
for
J Jt/t//e) PRÐf'êlLL-"lè $I?Jl~
(name of business)
and that, it along with the attached additions
or corrections constitute a complete and correct
BUSine:.:?an for my facility.
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date
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_BUSINESS NAME VALLEY .ELlOR SERvtCE
"LOCATION 300 WAT, R
10 NUaZ1S-ØØØ-Ø0fZØ0
HI AZARD RATING 3
1. OVERVIEW
[ASTtH¡11'i~GE 0IIn/BS BY EVHMC
JURI S CODE Z 15-005 JURI S BAI<ERSFI ELO"STfHI ON 05
MAP PAGE 124 GRID 0aC F'tICTlTT'('UtiffrS r HAZARD RATING 3
RESPONSE SUMMARY
2A SEC 4} NO PRIVATE HESPONSE TEAM . ~
EMERGENCY CONTACTS ZA SEC Z>
tLIFF JOHNSON 832-6033 366-2347
JOHN HIXON 932--6033 322-0807
UTILITY SHUTOFFS 2A SEC 3>
A> GAs· - SE CORNER OF BUILDING B) ElECTRIÇAl. - INSIDE Sf CORNER OF BUILDING
C) WATER - OUTSIDE SE CORNER D) SPECIAL - NONE E> LOCK BOX - NO
Z. NOTIFICATION I PUSLIC EVACUATION 1. Dt:J r.h/7Ú----
. LAST CHANGE I I'" ð f¡v -/1 TI
w 6 {¡.J ( C, C. CtLc.C ( ØI. A. CJ af"¡Ç .. )/ (i'. 'ð Y' ¡¡ '" /<.~. I
Ct.;J/) tfaC/6 ,/lÓIU- C-Vðg; Ua-<-G
< NO INFORMATION RECORDED FOR THIS SECTION>
PHGE I
MfI TERl AL 'SffFETY'[1F1TA5YSTEMS. 'INL' <'805)' 6.l.f.H3BØ0
iZ1Z0/88 tZ:5i
BUSINESS NAME VALLEY PROPEl.LOR SEHVICE
LOCATION 300 WATTS DR
1D NUMBER 215'-00Ø-ØØl2.ØØ
HIGH HAZARD RATING 3
No
bEAST CffANGE I /1 ry .l;:y
3. HAZMAT TRAINING SUMMARY
~ ¥~
Ðo~ ~hsj)s
ye.-s
-, -\
, < NO TNFORMHTTDN'RECURDEDqFUR THIS SEcn ON >
4. LOCAL EMERGENCY MEDICAL' ASSI'STANCE
LAST CHANGE 01/13/B9 BY EVAMC
ZA SEC 5; NEAREST HOSPITAL
PAGE 2
rZ'f't0/ Bfr '1'7: 5'\" ,
MATERIAL SAFETY DATA SYSTEMS. INt. (805) 64B"'6800
.
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.. BUSINESS NAME VALLEY aELl.OR SERVICE
· lOCATI ON 3ØØ Wf'¡T R '
FACILITY UNIT 01
10 NUtA 2: 15-ØØ0-ØØ 1 Z00
HI.HAZARD RATI N6 3
A. OVERALL HAZARDOUS MATERIALS 1 NVENTOHY
lñ5TCHHNGE 0711 vas BY ESTER
10-
TYPE NAME
L.OOHION
CONHHNf1ENT
MAX AMT UNIT HAZARD
USE
{'\.I !~ GAL HIGH
PLATING
MIXTURE SODIUM CYANIDE SOLU1}ON
PLATING ROOM CENTER METAL CONTAINERS-
fD PERCENT COMPONENTS
1098.0'J ¡ 5. ø SODIUM CYANIOE' CNfi(Tl'\1i VCEPAr
HAZARD LIST
HIGH EP
z
MIXTURE CHROMIC ACID
PLATING ROOM CENTER METHL CONTAINERS
10 PERCENT COMPONENTS
1067.00 7~0 CHROMIC ACID. SOLID
J5( ~GAL HIGH
PLATING
HAZARD LI Sl
HIGH
3 PURE MINERAL SPIRITS 55 GAL MODERATE
CLEAN UP R00t1 WEST WALL DRUMS OR BARRELS MET.. CLEANING
10 PERCENT COMPONENTS HAZARD LIST
1203.02 1 Ø0. 0 NAPHTHA SOL VENT EXTREME
4
MIXT\JRE LACQUER THINNER 55 GAL
OUTSIDE NW CORNER OF I3LO DRUMS OR BARRELS MET.. CLEANING
. HJ PERCDff- tÐi1P{)f~EI\! f5'"
HHjl1
I Svi>v-ry L.. Ci C6T$;.-r6. _ ~
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tlL..I!¡µ;f r ,.......,.
'{õ 1-0 6-1""·6
1-- tLl--CtJfló f-
t£1. fir· . ,I t.. f<-G-y(J µ-6
'Ii1 tfí fir t... e r(~ r '- .
PI5õ l3 UTft.- / So 6 v v-yi<-<JJrtS
fYl (ÇYl'f Ó.L (:" (-ýó L-
HAZARD LIST
UNKt.JOWN
UNKNOWN
HIGH
HIGH
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I 0--30 ~
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PAGE 3
I UZQ.1T88 rz~'5l' .
MATERIAL SAFETY Df1Tf\'SYSTEt¡¡-S> INC .-{ H'Ø5 )'648""'131300
BUSINESS NAME VALLEY PROPElLOR SERYICE
LOCATION 3ØØ WATTS OR
10 NUMBER ZIS-0Ø0-Ø01ZØ0
HIGH HAZARD RATING 3
B. FIRE PROTECTION I WATER SUPPLIES
LfIST'CHfí.N8E 07/12/88 BY ESTER
3A SEC 4) NO PRIVATE FIRE PROTECTTOIla.
3A SEC 5) FIRE HYDRANT' ON'm,i'CÇfRNER OF,!lATTS DR.
p. EMPLOYEE NOTfFICATION I EVACUATION
LAST CHANGE 07/11/88 BY ESTER
3A SEC 2) IN CASE OF SPILLS, ROOM WOULD BE EVACUfHEJ; EXCEPT FOR CLEAN UP CREW.
NOTIFIC(-)TION lJQULO NOT BE NECE5SARYI1S WF.' HAVE"fYROÞER EQUIPr1ENT TO CLEAN UP
AND CONTAIN THESE CI'H::rUD1LS,
PAGE 4
. flIZ01Ug· lT~5'r
MATERIAL 'SfìfETY'DfîTA5Y5Tf.'JI15 ,TNt. T80S) '64~F5fJ0Ø
.
.
BUSINESS NAME VAlLEY IIIPELLOR SERVICE
'," l.OCf\TION 300 WATWOR "
10 NU~ ZI5-0Ø0-Ø01ZØ0
HI~HAZARO RATING 3
E. ì1ITI6ATION / PREVENTION! ABATEMENT
lAST CHANGE 01/1~/BB BY EVAMC
3fì SEC I} CHROMIC HOD SOLlffTON 'CONTAINED IN 3116" THICK STAINLESS TANI{ WITH
UD . SODIUM CYHNIDr- SOLUTION CONHHNEO IN 3/16" THICK STAINLESS TANI('Wlni
LID. THE5E CHEMI'CAL.5 CONTI1I'NED IN' 5£PARATEdRQOfll PROM RES! OF SHOP WITH
SHOWER AND EYEWASH FACrLfTrTNRûOrr~- TN CAS'ï:'-aF SPILL I HAVË A STAINLESS
CONTAINER AND MOPS AND SPONGÈ5,-TDCONTAIN AND CLEf\N. HIE ROOM HAS Z nUT
DOORS AND VENTILATION FAN~ WE: AlSO"'HfWE RliBBERBlOVEŠ' AND RUBBER SUITS FOR
ceEAN UP CREW. THE LACQUER THTNNERAND SOLVENT ARE CONTAINED IN 55 GALLON
STEEL DRUMS WITH LIDS.
Lv {{-tf 1-( f} f 5
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PAGE 5
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MATERIAL SAFETY DATA SYSTEMS, INC. (B0S) 648-61300
r2lzø/Btr rZ:1ir-
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CIT}T of BAKERSFIELD
-_./~--
Far. and Aqricu hure
L-J
Standard Business
~
~
HAZARDOUS MATERXA~S XNVENTORY
NON-TRADE SECRETS
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OWNER NAME: 0 ~¡..; ~{ (;< 0 AJ .
~~~~S~~p, 1J~ fl, -ßGCC~a~~((;
PHONE II: _'1: 0 ~
BUD 2"0 IlISrRUcrIOIIS roB PROPD CODa
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BUSINESS NAME: vac...?-.t-y f ~/ç WI...
LOCATION: 3~ ~~ ~f
CITY, ZIP: /dcLI~ . q b-?
PHONE ,: cf-3 À.. s.... ~3
NAME OF Tft1s ~~Ç~L~TY:
STANDARD IND. CLASS CODE
DUN AND BRADSTREET NUMBER
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See InstruetiCIII
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ta.paMnt II ... . C.A.S. ......
to.aønInt 12 ... . U.S. ......
ea..a-t 13 ... . C.A.S. ......
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ea.an.ntl2 ... . C.A.S. ......
ea.an.nt 13 ... . c.a.S. ......
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ta.paMnt 13 ... . C,A.S. ......
fo 0 \U #A. C Va¡..J r I)c ~à L-v &l'V
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PhysiC.1 and HH lth Hu.rd
((heck .11 thet 'l1li1,)
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(theck .11 thet ...1,)
C.A.S. "'**' ____________________,.._ CœDantnt 11
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L V Fire Hlllrd L _.J R..ct;vity L _.J Oel.yed L _.J Sudden RIIHlI LV.. l-.di.t.
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H..lth . of Prtlsure H..lth
Ca.øonent 12
------------------------- ------
I II£RG£NCY C(MUCTS 11 f¡ï!J-U¿----ji.L'1.:-g--~-------____ tri¡Yl..l!-r..-I!::.---------- J-~trøf.-fº2-
T~~fC ------- ~~ç~!3 _'L?
C.rtlfication (Rt!lJd and si/!TI after co.pJp.tiilg all st!ctionsJ
I certifv un r ØIIII\ty of 1.. that I hevI "rlon.11y e...ined .nd .. f"ili.r with the inforNtiCII lu..Htld in this II1II.11 IttlChed cIoc_u, II1II thet blled CII wy inquiry of tho.. individull1 r..pcjnlible .
for 0 .. the inf ICII I belie,,!! thet thl! IU"ittl!d info....tion is tl"Ul!, accurate, .nd cc.plet., ~ J
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CIT}T of BAKERSFIELD
"'
...
Far.. and Agr icu t ture
L-.J
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Standard Business '---'
HAZARDOUS
MATERIALS
I NVENTOR.Y
'",
-í
Page ____ of ___.'
\ /~ /J J2e>flcf'i1¿W _
BUSINESS NAME: /,' r v-____
LOCATION:
CITY, ZIP:
PHONE #:
OWNER NAME:
ADDRESS:
CITY, ZIP:
PHONE #:
RBPER TO INSTRUCTIONS FOR PROPER CODES
NAME OF Ttt!Š ~~JL~TY:
STANDARD IND. CLASS CODE
DUN AND BRADSTREET NUMBER
'\
I
1
Irans
Code
11
Use
Code
12
Locat ion Where
Stored in Faci lity
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u
Physical and Health Hazard
(Check all that apply)
,-~ r-' ,..-, r-"
L_;J Fire Hazard '---' Reactivity '---' Delayed '---' Sudden Release
Hea I th of Pressure
C.A.S. NUllber __________________
Ph~SiCal and Health Hazard U.S. Nu.ber ------COII;:;--I;~::~-Z;~-·-~~-.-~~-ï;~ ---- ?Fïif¡:-- C:lt..-r;;7?G-c~------s:------ ------
r(~:Ck all that aP:I~, ,._, r-' ~~-------- COIIponent 12 NaN' C.A.5. Nu.bar "/6 -_~__-- ïit-~~ïr7í_7A--~--~-~k_-~T;ï(J--r-- _-_-_-_-_-_-.
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(Check all that apply)
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--- ---------------------- = ---- -------::.." -------ë-;;r..¡ut;.---------- ------
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CoIIponent 12 NaN & C.A.5. Nu.bar
,..-, r-" r-' r-" ,..-.,
'-_-' Fire Hazèlrd '---' Reactivity '-_.J Delayed '---' Sudden Release '-_..J IMediate
Heal th of Pressure Hea I th
------------------------------------------ -------
COIIpoIIent 13 NaN & C. 1..5. Nu.ber
___l_____L___________L____________L__________L..__-'_____L__--1_---L_l___-L______
------------ ---- ----------------------------------- -----
Phys ica I and Hea 1 th Huard
(Check all that apply)
C.A.5. Nu.ber ______________
COIIponent 11 NaN & C.A.S. Nu.ber
------ -------------------------------------------------------- ------
r-., ,..-, r-, r---'
'-_..J Fire Haz'ard '-_..J Reactivity '---' Delayed '-_..J Sudden Release
Hea ¡ th of Pressure
,.-,
'-_..J IlIIIIediate
Hea I th
COIIponent 12 NaN & C.A.5, NÙllber
------------------------------------------------------- ----- --
COIIponent 13 NaN & C. 1..5. NUlllber
--------......-------------.---- .----
'\ERGENCY CONTACTS II .2
Aåmë- ~--- ---------- ---------------------- nnë----------------------- 2t-R¡:-Pñõñë------- Riië------------------------------ Titlë------------------------ 21-Rr-Pl\ðñ~-----·---
Certification (Read and sign after completing all sections)
[ certify under pena lty of law that I have persona lIy eKamined and all !allli liar with the information submitted in this and a 11 .tt.ched docu.ents. and that based on IIY inquiry of those individuals responsible
for obta in ing the inforilðt ion. I believe that the sUbmitted informat ion is true, accurate, and COllP lete.
A~;¡,nña~õHìëìãnmë-õrõ;¡ñë¡:iõ¡¡ë¡:ãtõ¡:-On¡¡ñë¡:7õõë¡:m¡:~š_ãütñõ¡:¡iënë¡¡¡:ëšëñtåtiÿë
Sì gñiìü¡:ë-------------------------------------------------------
Oitë"Sìgñëõ------------------------------·
· .
BAKERSFIELD CITY FIRE DEPARTMENT
2130 "G" STREET
BAKERSFIELD, CA 93301
(805) 326-3979
;"
OFFICIAL USE ONLY
</Þb {f~ · 3
~ø¿ (j-I ~
USINESS NAME
ID#~
,~
HAZARDOUS MATERIALS
BUSINESS PLAN AS A WHOLE
FORM 2A
INSTRUCTIONS:
1. To avoid further action, return this form by
2. TYPE/PRINT ANSWERS IN ENGLISH.
3. Answer the questions below for the business as a whole.
4. Be as brief and concise as possible.
SECTION 1: BUSINESS IDENTIFICATION DATA ~
A. BUSINESS NAME: V á-t c: ey f jib t? r; íLG ,z G;L. vi ( C e / tft.-IC ¡
B. LOCATION / STREET ADDRESS: '3 cPO ty-;a;r-rf{J ~ (t/'G-
CITY: ¡3o,{~(s-IL)(l(G("'() ZIP: 9J.3~7 BUS.PHONE: (ðb.J; cf.33.:- ~..J3
SECTION 2: EMERGENCY NOTIFICATIONS
In case of an emergency involving the release or threatened release of a
hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify
your local fire department and the State Office of Emergency Services as required by
law.
EMPLOYEES TO NOTIFY IN CASE OF
NAME~N9 TITLE J
A.(:-0/~F r/oHµ5o-;V
B. \.J 0 t( ¡..) tit xcnJ
EMERGENCY:
DURING BUS. HRS.
Ph# rf J Ã. 6 C> -<'':?
Ph# cf 3 J--6t?~ 3
SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE
A. NAT. GAS/PROPANE: ~/
B. ELECTRICAL: I.' £r f-
C. WATER: {)C/r rF
D. SPECIAL:
E. LOCK BOX: YES / NO IF YES, LOCATION:
A:µ.;rE~ ...ßUS. HRS.
Ph# ..:5 6'6 ' ~3 II ?
Ph# 3 2-J- 0 cfo 7
\ I
IF YES, DOES IT CONTAIN SITE PLANS? YES / NO
FLOOR PLANS? YES / NO
- 2A -
\
\
MSDSS~ YES / NO
KEYS? '" YES / NO
.
.
''¡,.: ~,~~'-._,~:~~~.
i
,
ì
"!',
.
SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE
~. i
"".
!l0µ6
, "" . " I,·'"
~ ~ ~:,' t.t~) f ~ ;
",,' ..,. - ~,
SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE
/if GaA-6Jv
f(o .f ¡ð ( ì r£L"
SECTION 6: EMPLOYEE TRAINING
EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND
REFRESHER TRAINING IN THE FOLLOWING AREAS.
CIRCLE YES OR NO
A. METHODS FOR SAFE HANDLING OF HAZARDOUS
MATERIALS: . . . '. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
B. PROCEDURES FOR COORDINATING ACTIVITIES
WITH RESPONSE AGENCIES:.. . . . . . . , . . . . . . . . . . . . . . . . .
C. PROPER USE OF SAFETY EQUIPMENT: . . . . . . . . . . . . . . . . . .
D. EMERGENCY EVACUATION PROCEDURES: . . . . . . . . . . . . . . . . .
E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS:. ..... .
INITIAL
REFRESHER
GJNO
~.~~
~NO
YES ø
tfil NO
~NO
NO
~S JW
SECTION 7: HAZARDOUS MATERIAL
CIRCLE YES OR NO
DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A
SOLID, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF A COMPRESSED GAS: . .. ... YES NO
Jo(f;<j5ð71/
I, CJ-rç¡: 1<
I understand that this information will be used to fulfill my firm's obligations under
the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95
Sec. 25500 Et AI.) and that inaccurate information constitutes perjury.
, certify that the above information is accurate.
SIGNATURE ~~~
TT'T'r,F _ 0 tV µ GIZ..........
DATE '7 - J... 7-J-?
- 2B -
·' J '
e
.
i:
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!I, "'-.,, J~~
BAKERSFIELD CITY FIRE DEPARTMENT
2130 "G" STREET
BAKERSFIELD, CA 93301
OFFICIAL USE ONLY
ID#
BUSINESS NAME:
------
BUSINESS PLAN
SINGLE FACILITY UNIT
FORM 3A
INSTRUCTIONS
1. To avoid further action. this form must be returned by:
2, TYPE/PRINT YOUR ANSWERS IN ENGLISH.
3. Answer the questions below for THE FACILITY UNIT LISTED BELOW
4. Be as BRIEF and CONCISE as possible.
j /át/ G\f () 1l.D/t'tÛf7( . ~VICv iðJc, '
FACILITY UNIT# FACILITY UNIT N~: ~{. v. / r ,JfJ.
(
SECTION 1: MITIGATION, PREVENTION, ABATEMENT PROCEDURES
Cill~ØfrC Ó-CI! ,['Ot.U?"IOµ CÓI07ëLtll:Yé"tJ IN f?.ç t1ifft'cl< S7ZltÞ/..65S't7:f.#k ôJ/7H
!-rj), 'S'eJ¡)IVµ""" Cya.¡<Jl/JC J'oj(./T{o;J C(1¡t.1~(¡V 6tJ ¡p ~6c'/kICK .t'1ëZt;..J¿&5.f T&-,N¡¿ (.;.J (-r-H
? If). 111G5G CI-f6'ilUC'.ð?I Co¡v,(/.¡,vBD 0'11 ~ 6/!'~1f:o-7G /J.L¡{!)/J1... FI2<JPt /l.65T ¿;¡C '>-/.'0,,:)
W{~f{ SNðWGA... 'lfJ/tJ ~ytfÜ/4-f H ¡Çæ Cl 1.17/ I p ~M..I tlct1.S (i óf' ..r PICe 1. ¡./Ø-//tf
a S 7t1r¡tlA.6.>S' coµ7èitl,/c;~ ¡:1¿r.tJ¡jG/<.. hW-6ð diÞð/l1of/£" (L}Ii) ,ff~jf?cf.J fêJ Cð/,,?'7£,-nv
a,-µ t1 c},.G()¡.J~. -rlf G ~¡tI. lfû-f J2.- G X-I { ¡)ð6/Zj' ðl"¿? I/Gpy I t.øTtð11./ p~..
Lv'€- ~LSc:> 11&..1/& AUt$B~K tJ:t..ð(/tF..f ðL/lt' !<.-u~~elL .{"'UI'T.J Pð/2... Ct6~ u;:J
C /2. G t..U, --rl-f C ?tJ-cg tJ(j-'"i!.. T(-Ia..Jp6'/l... a.AltJ .lot- Vt?"ul ~ cO#/&.tP6-¿J /µ
.J5 flatLop .('T6'(§J- ¡J/CV#f..j' tlJtTk /.-¡f)J:
SECTION 2: NOTIFICATION k\~ EVACUATION PROCEDL~ES AT THIS UNIT ONLY
/ IJ ú:q~ 0;:' .f ¡PllG¡ ¡(ô6m Wc;j..J?¡J ~ € Cl/ac..uc;L7VLl 6'x c 6/-l1 FoÆ
Cl-@M./ ujJ CA..t;,w..¡(/cJífF(Cæ:rtØ~ WD cJt-/J por¡- ¿ (j µ6-c..G-)s~r
0- ~ ÚJ (i /rI(j.(/{j -r lie; ~ I"k,/J G/J. 6 &Ul ¡J /K6-µ({" '(0 CL Ga.µ u ¡O Ci-ø tJ
C6 ¡.rrëP-o.J ({f~S6' C Hð'VIlca?S;
'-3A -
',-
.
.
'ô _
'~,;",,,-,.,,--·J"i··
"
" '-
',-
SECTION 3: HAZARDOUS MATERIALS FOR THIS ú~IT ONLY
A. Does this Facility Unit contain Hazardous Materials?,. .., YES NO
,
\
If YES, see B.
NO, continue with SECTION 4.
B. Are
the hazardous materials a bona fide Trade
NO
If No, com ete a separate hazardous materials inven ory
form marked: NON-TRADE SECRETS ONLY (white form #4A 1)
If Yes, comple a hazardous materials inventory f rm marked:
TRADE SECRETS ON (yellow form #4A-2) in.additi to the non-trade
secret form. List nly the trade secrets on fo m 4A-2.
SECTION 6: LOCATION
A. NAT. GAS!PROPAN~~
SECTION 5:
SECTION 4: PRIVATE FIRE PROTE
B. ELECTRICAL:
I
C. WATER:
-t, LOCK BOX: YES / ~O IF YES. LOCATION:
IF YES, SITE PLANS?
FLOOR PLANS?
YES / NO
YES /NO
MSDSs?
KEYS?
YES / NO
YES/ NO
- 38 -
..
1. D. #
BAKEHSFIELU CITY FIRE UEI'AH1'HEN1'
-
FORM 4A:-l
NON-TRADE SECRETS
_ _HAZARDOUS MATERI ALS· I NVENTORV --
BUSINBSS NAMB, ViUtf,:i ,-~.·.Â.<u .¡/ifW«- >?1lÙ, (.ú<ÖWNER NAME: C ?,/,P¡? /ð&'µ..s~ FACILITY· UNIT # ::...~,:
ADDRBSS, '3~ W~._.: ..0. £(__~ ADDRESS: 7óÄ ;<J¿¡.ø./<. /f'/(( FACILITY UNIT NAME: 'i
~ ~ ~~É ~: p, -j¡jf!~'f¡'fftJ-:-, C[3:t 0"7 ~ ~~~É z ~ ~ ' A-f:?f!<~~i"¡¡~ '? J' ;;> ~ FF I C I A L US B C FIR S CD 0 B
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CODE AMOUNT
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ANNUAL CONT USE LOCATION IN THIS % BY HAZARD D.O.T
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MATERIAL SAFETY DATA SHEET
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IDENTIfICATION
NAME
Sod'um Cyanide
GRADE
Cyanobr1k*; Cyanogran*;
, 'Compounders Grade
CHEMICAL FAMILY
,AJkal' Metal Cy~n'de
FORMULA NaCN
SYNONYMS
Cyanide of Sod'um; Prussiate of Soda
1. O. NOS ./COOES
NIOSH Registry No. VZ7525000
CAS REGISTRY NO. 143-33-9
PRODUCT INFORMATION PHONE
(800) 441-9442
MEDICAL EMERGENCY PHONE
(800) 441-3637
( In c .) ~~~~RA~)~Iîfifi':Ê¡t~èitit~Y~=~HOÑE~7't
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CAS NAME Sodium Cyan'de
MANUFACTURER/DISTRIBUTOR
E. I. du Pont de Nernours & Co.
ADDRESS W11~ington, DE 19898
PHYSICAL DATA
BOILING POINT. 760 mmHg
14960C (27250F)
SPECIfIC GRAVITY 1.6
VAPOR DENSITY
Not vo1atne
MELTING POINT
5640C (1047oF)
VAPOR PRESSURE Neg1ig'b1e
SOLUBILITY IN H20
37% at 200C (6BOF)
EVAPORATION RATE (BUTYL ACETATE=l)
Not appl1cable
pH INfORMATION 11.3 to 11.7
(Typical for 5 to 25% solutions with
no pH adjustment)
APPEARANCE Granular or Briquettes
fORM So 11 d
ODOR None (but can have slight
COLOR: White ammonia and/or HCN odor if damp)
*Reg. U.S. Pat. & Tm Off., Ou Pont Company. Cyanobrik@ and Cyanogran@ Sod1um
Cyan'de are made only by Du Pont~
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[-79954
Date: 10/85
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HAZARDOUS COMPONENTS
MATERIAL( S)
Sodium Cyanide
APPROXIMATE "
100
HAZARDOUS REACTIVITY
INSTABILITY
Very stable when dry.
INCOMPATIBILITY
Large amounts of highly toxic, flammable hydrogen cyanide (HCN) gas
will be evolved from contact with acids. Reacts violently with
strong oxidizing agents. Water or weak alkaline solution can produce
dangerous amounts of HCN in confined areas.
DECOMPOS I TI ON
Moisture.wi11 cause slow decomposition, releasing poisonous HCN and
ammonia gas.
POL YMERIZATION
Will not occur.
FIRE AND EXPLOSION DATA
FLASH POINT Will not burn.
FLAMMABLE LIMITS IN AIR, % BY VOL.
LOWER Not applicable.
UPPER Not applicable.
AUTOIGNITION TEMPERATURE
Not applicable.
FIRE AND EXPLOSION HAZARDS
Will not burn. Sodium cyanide will not be destroyed in an ordinary fire
involving combustible materials such as paper or wood.
EXTINGUISHING MEDIA
Water on fires near sodium cyanide, but minimize amount of water if
containers are opened or burned (see "Incompatibility", above) DO NOT use
carbon dioxide (C02) which reacts with sodium cyanide to produce hy~rogen
cyanide if moisture is present.
SPECIAL FIRE FIGHTING INSTRUCTIONS
Sodium cyanide dissolves readily in water, therefore
runoff may occur if containers are opened or burned.
contained to avoid environmental or safety problems.
solution can be detoxified with hypochlorite.
cyanide solution
Runoff should be
Contained cyanide
E-79954
Date: 10/85
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HEALTH HAZARD INFORMATION
PRINCIPAL HEALTH HAZARDS (Includ1ng S1gn1f1cant Routes, Effects, Symptoms
of Over-Exposure, and Med1cal Cond1t1ons Aggravated by Exposure)
May be fatal 1f 1nhaled, swallowed, or absorbed through sk1n. Contact with
ac1ds or weak alkalis liberates poisonous gas. Causes eye burns and may
1rrHate skin.
Oral LD50: 6 mg/kg in rats
Tox1c effects descr1bed in animals from exposure include asphyxia, dyspnea,
ataxia, tremors, coma, and lethality by_disrupting oxidative metaboli5m.
- Tests in bacterial and malTímalfan- ÙTi-cultures demonstrate no mutagenic
act1v1ty. Tests 1n some animals 1ndicate that the compound may affect the
fetus, that is, 1t may be a developmental tox1n.
Human health effects of overexposure may 1n1t1ally 1nclude: sk1n
1rr1tat1on w1th d1scomfort or rash, eye 1rritation or burns with
d1scomfort, tear1ng, or blurr1ng of vis1on, and poss1ble permanent eye
damage; and nonspecif1c d1scomfort such as nausea, headache, dizziness,
vomitin~, and weakness. H1gher exposures may lead to these effects: rapid
respirat1on; lowered blood pressure; unconsciousness; convulsions; and
fatality. Ev1dence suggests that significant skin permeation can occur.
Individuals with preexisting diseases of the central nervous system may
have increased susceptibility to the toxicity of excessive exposures.
CARCINOGENICITY
Not listed as a carcinogen by IARC, NTP, OSHA, ACGIH, or Du Pont.
EXPOSURE LIMITS (PEL (OSHA), TlV (ACGIH), AEl (OU PONT), ETC.)
The OSHA 8-hour Time Weighted Average (TWA) and ACGIH TlVe-TWA are 5 mg/m3,
as CN. Both carry a "skin" notat1on indicating that cyanide may penetrate
the sk1n (especially 1f the skin 1s broken). Control of vapor, dust, and
m1st 1nhalation alone may not be suff1cient to prevent absorpt1on of an
excessive dose. .
SAFETY PRECAUTIONS
Do not breathe dust, mist, or HCN gas. Do not get in eyes. Av01d contact
with sk1n and cloth1ng. Do not carry foodstuffs, beverages, or tobacco
where contaminat10n with cyanide 1s poss1ble. Wash thoroughly after
hand11ng. Wash contaminated clothing before reuse.
FIRST AID AND MEDICAL TREATMENT
Actions to be taken in case of cyanide exposure should be planned and
pract1ced before beginn1ng work with cyanides. In most cases, cyan1de
poison1ng causes a deceptively healthy pink to red sk1n color; however, if
a physical injury or läck of oxygen 1s 1nvolved, the sk1n color may be bluish.
Treatment for cyan1de poison1ng can be provided 1n two ways, "First A1d"
and "Med1cal Treatment". Both requ1re immediate act10n to prevent further
harm or death. First aid using amyl nitrite and oxygen 1s generally given
by a layman before medical help arrives. Medical treatment involves
E-79954
Date: 10/85
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intravenous injections and must be administered by qualified medical personnel. )
Even if a doctor or nurse is present, the need for fast treatment dictates
using first aid treatment with amyl nitrite and oxygen while medical treat-
ment materials for intravenous injection are being prepared. Experience
shows that first aid given promptly is usually the only treatment needed.
Medical treatment is given if the victim does not respond to first aid. It
provides a larger quantity of antidote including sodium thiosulfate to
chemically destroy cyanide in the body. However, even under optimum
conditions, amyl nitrite can be administered faster and should be used even
if medical treatment follows. 00 not overreact. Fast treatment is needed,
but a conscious person usually does not need treatment beyond oxygen, Amyl
nitrite and medical treatment kits for cyanide poisoning are available,
with doctor's prescription, from pharmacies.
A. First Aid - Directions for Giving Amyl Nitrite Antidote and Oxygen
1. Conscious:- For inhalation and/or absorption if the victim is alert,
oxygen may be all that is needed. But if he is not fully conscious
or shows signs of poisoning, follow paragraph A-2 below. For
swallowing, see below paragraph C, "First Aid - Swallowing Cyanide".
2. Unconscious But Breathing: Break up amyl nitrite ampule in a cloth
and hold lightly under the victim's nose for 15 seconds, then take
away for 15 seconds. Repeat 5-6 times. If necessary, use a fresh
ampule every 3 minutes until the victim regains consciousness
(usually 1-4 ampules). Give oxygen to aid recovery. Where more
severe poisoning has occurred, consider holding the amyl nitrite
,under the nose continuously for the first ampule or more.
3. Not Breathing:
a. Give artificial respiration, preferably with an oxygen
resuscitator. Give amyl nitrite antidote by placing a broken
ampule inside the resuscitator face piece, being careful that
the ampule does not enter the victim's mouth and cause choking.
b. If using manual artificial respiration, give amyl nitrite
antidote as in paragraph A~2 above except"keep the first amyl
nitrite ampule under the nose with replacement every 3 minutes.
4. Amyl Nitrite Notes:
a. Amyl nitrite is highly volatile and flammable; do not smoke or
use around source of ignition.
b. If treating poison victim in a windy or drafty area, provide
something - a rag, shirt, wall, drum, cupped hand, etc. - to
prevent the amyl nitrite vapors from being blown away. Keep the
ampule upwind from the nose. The objective is to get amyl
nitrite into the victim's lungs.
c. Rescuers should avoid amyl nitrite inhalation so they won't
become dizzy and lose competence.
d. Lay the victim down for treatment to maintain a good blood
supply to the victim's head. Since amyl nitrite dilutes the
blood vessels and lowers blood pressure, lying down will help
prevent unconsciousness.
E-79954
Date: 10/85
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e. Do not overuse; excess1ve use m1ght put the v1ct1m 1n shock.
Th1s has not occurred 'n pract'ce at Du Pont plants and we are
not aware of any death or ser'ous after effects from treatment
w,th amyl n'tr1te. (See paragraph E, "Medical Treatment".)
B. F1rst Aid - Inhalat10n of Cyanide - Carry the viet 1m to fresh air.
Lay victim down. Administer amyl nitrite antidote and oxygen (Paragraph
A). Check for and remove contaminated clothing. Keep patient quiet and
warm. Call a phys1ci~n.
C. F1rst Aid - Swallow1ng Cyan1de
1. Consc1ous: Immed1ately give patient one pint of 1% sqd1um,
th10sulfate solution (or plain·-water) by mouth- and' 1ntluce vomH1ng
with finger 1n throat. Repeat unt1l vomit fluid is clear. Never
give anyth1ng by mouth to an unconscious person. Call a physician.
2. Unconscious: Follow first aid procedure as 1n paragraphs A-2 and
A-3 (and/or medical treatment in paragraph E) and call a physic1an.
If the victim revives, then proceed with paragraph C-l.
D. First Aid - Skin or Eye Contact (Skin Absorption)
1. ~Contact: Immediately flush eyes with plenty of water, remove
contaminated clothing, and keep victim quiet and warm. Call a
physician. '
2. Skin Contact: Wash skin to remove the cyanide while removing all
contaminated clothing, including shoes. Do not delay. Skin
absorption can occur from cyanide dust, solutions, or HCN vapor.
Absorption is slower than inhalation, usually measured 1n minutes
compared to seconds for 1nhalation.
Follow F1rst Aid procedures in Paragraph A if treatment 1s needed,
but even severe skin contact usually will not requ1re treatment if
1) no inhalation or swallowing has occurred and 2) the cyan1de is
promptly washed from the skin and contam1nated clothing and shoes
are removed. If skin contact is prolonged, HCN poisoning may occur
with nausea, unconsciousness, and then death possible if the source
of cyan1de intake is not removed and treatment provided. Even after
wash1ng the skin, the victim should be watched for at least 1 to 2
hours because absorbed cyanide can continue to work 1nto the blood-
stream. Wash cloth1ng before reuse and destroy contam1nated shoes.
E. Medical Treatment
Medical treatment is normally provided by a phys1c1an, but might be
provided by a professionally trained "qualified medical person" where a
need exists and where state and local laws perm1t.
)
While preparing for sodium nitrite and sodium thiosulfate injections,
use amyl n1trite and oxygen as outlined in paragraph A. When ready and
if the victim 1s not responding to first aid, first inject the solution
E-79954
Date: 10/85
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of sod1um n1tr1te (10 mL of a ~% solut10n) 1ntravenously at the rate of
2.5 mL/m1nute, then 1mmediately inject the sodium th10sulfate (50 mL of
a 25% solut10n) at the same rate, tak1ng care to av01d extravasation.
This 1s a fairly lengthy treatment (24 minutes) since a total of 10 +
50, or 60 mL 1s injected at a rate of 2.5 mL/minute. Cons1deration
should be g1ven to the s1ze and cond1t10n of the vict1m as treatment 1s
proceeding. The above sodium nitrite injection is about one third of a
lethal dose, so care should be taken to avoid excessive use. It is not
essential that full quant1ties be given, just because treatment was
started. Injections can be stopped at any point if recovery 1s ev1dent.
Watch pat1ent cont1nuously for 24-48 hours if cyanide exposure was
sever~.· If there is any return of symptoms dur1ng this period, repeat
th1s treatment using one-half the amounts of sodium nitr1te and sodium
thiosulfate solutions. Caution should be used to av01d overuse of
mediëal treatment chemicals as the prescribed dose is about 1/3 the
lethal dose for an average individual.
If signs of excessive methemoglobinemia develop (i.e., blue skin and
mucous membranes, vomit1ng, shock and coma), 1% methylene blue solution
should be given intravenously. A total dose of 1 to 2 mg/kg of body
weight ~hould be administered over a period of five to t~n minutes and
should be repeated in one hour if necessary. In addition, oxygen
inhalation will be helpful. Transfusion of whole fresh blood may be
considered if there has been mechanical injury with external or internal
bleeding and simultaneous cyanide exposure.
Du Pont's exper1ence in treating cyanide poison cases is that first aid
procedures using amyl nitrite and oxygen were effective and the only
treatment needed in most cases. Medical treatment, using intravenous'
injections, was used in a few cases. Both procedures have been
successful.
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PROTECTION INFORMATION
GENERALLY APPLICABLE CONTROL MEASURES
Good general ventilation should be provided to keep dust, mist, and HCN gas
below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Recommended Minimum Protection - chemical splash goggles and rubber gloves
(butyl or neoprene preferred).
Have available and use as appropriate: face shields; rubber suits, aprons,
and boots; disposable toxic dust and mist respirators; self-contained
breathing air supply (in case of emergency); HCN detector; first aid and
medical treatment supplies*, including oxygen resuscitators.
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*See Du Pont Sodium Cyanide Storage and Handling Bulletin for list of supplies.
E-79954
Date: 10/85
6
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SPILL, LEAK OR RELEASE
Swee~.u~_ and shovel into a covered container or plastic bag, pending
IOENfyl¡¡:J~ripNto secure the spill. Cover and keep spillage dry. Flush spill
area with a dilute solution of sodium or calcium hYPochlorite. Comply with
~~ral.State, and local regulations on reporting releases.
Sod\um Cyah\de
WASTE DISPOSAL
§B~ø.~~ .':'Iith Federal ~ state" and local regult\.iW\t·AJ ~AÞOffi.!v flush cyanide
1!:!£~~,gew~H!rWhîtj'DnlÐ'YdMJ)tai n ,anac id. _Detox~~/í~'a~~t}.,e\0ã.or'~' ,h..>'\~ochlori te,
orCR'JIOtal:lg~~r~eßøaQlee; flush, to wastewater treatment system~dd'r ~all a
.~jce~~~~ dispósal contractor; FORMULA NaCN
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PRâ~ ~ 1(PÞ7¡~O IÑAME'
, . Sodtum Cyanide
. ;:·<O'i.~t-::./?~:,. ò~~~'~~~':,': ~~~.; -
HAZARD CLASS 6.1
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, Sodium tyan,f~e
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Cyan1de are made only by Ou Pont.' J' yanobr1k@ and Cyanogran@ Sod\um
E-19954
E--79954
Date: 10/85
Date: 10/85
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OTHER INFORMATION
REPORTABLE QUANTITY 10 lb/4.54 kg
SHIPPING CONTAINERS
"Wet Flo" ra11cars and trucks; hopper ra11cars; Flo-B1ns@ (3000 lb. net);
2000 lb. bag 1n a box; 100 k110, 100 lb., and 200 lb. steel drums
)
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STORAGE CONDITIONS
Store 1n properly labeled conta1ners 1n dry, vent11ated, secured areas.
Keep conta1ners closed and contents dry. Do not store w1th ac1ds or acid
salts, conta1ners w1th water or weak alkalis, or oxid1z'ng agents. Donot
handle or store food, beverages~ or tobacco 1n cyan1de areas. 00 not store
near combust1bles or flammables because of cyan1de solut1on runoff from
water used for fire fighting.
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ADDITIONAL INFORMATION AND REFERENCES
For further information, see Ou Pont Sod1um Cyanide Storage and Handling
Bulletin.
DATE OF LATEST REVISION/REVIEW: 8/85
PERSON RESPONSIBLE FOR MSDS: J. C. Watts, Du Pont Co., C&P Dept. I Chestnut Run,
Wilm1ngton, DE 19898, (302) 999-4946
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E-79954
Date: 10/85
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KEkN COUNTY FIRE DEPARTMENT
5642 VICTOR STREET
BAKERSFIELD. CA 93308
(805) 861-2761
"
OFFICIAL USE ONLY
ID#
BUSINESS ~AME
HAZARDOUS MATERIALS
BUSINESS PLAN AS A WHOLE
FORM 2A
INSTRUCTIONS:
1. To avoid further action, return this form by
2. TYPE/PRINT ANSWERS IN ENGLISH.
3. Answer the questions below for the business
4. Be as brief and concise as possible.
Jt[ 2 9 19B7
as a whole.
SECTION 1: BUSINESS IDENTIFICATION DATA
B, LOCATION / STREET ADDRESS:
CITY: '&--I<~RE¿"D
tJ A¿LCj rt2c:>~Vée
;;$êê) Cù A--rr~
ZIP: 9:3307
cSs-eLJ /(1 d-
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BUS.PHONE: (g'of) ?$~-toéJ3å
A. BUSINESS NAME:
SECTION 2: EMERGENCY NOTIFICATIONS
In case of an emergency involving the releas~ or threatened release of a
hazardous material. call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify
your local fire department and the State Office of Emergency Services as required by
law.
EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY:
NAM~D TITLE DURING BUS.HRS.
A..... /nl/J.J ilt Xo J f)rJJ J}elZ. PhI )?3;l-ttV:33
a.CLI"c"c ~~J t:'!l?JlJ(Di?:r;Ph# ~~r2-(óð53
AFT~R BUS. HRS. 1
PhI ;;)d-2. -o??ð _
PhI .3ro 6 -C:;3¥-1
SECTION 3: LOCATION OF UTILITY SHuT-OFFS FOR BUSlNESS,AS A WHOLE
A. NAT. GAS/PROPANE:
B. ELECTRICAL: AI I
r. WATER:
D. SPECIAL:
E. LOCK BOX: YES/ NO IF YES. LOCATION:
IF YES, DO~S IT CONTAI~ SITE PLANS? YES / NO MSDSS? YES / NO
FLOOR PLANS? YES / NO KEYS? YES / NO
-Over-
HMCU-4
.
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SECTION 4: ÞRIVATE RESPONSE TEAM'FOR BUSINESS AS A WHOLE
¡V (!)¡¡) E
SECTION 5: . LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOUR BUSINESS AS A WHOLE
µe4-f2.f3"7T . ÄSf(TA'L'··
SÊCTION 6: EMPLOYEE TRAINING
EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND
REFRESHER TRAINING IN THE FOLLOWING AREAS.
CIRCLE YES OR NO
INITIAL
REFRESHER
@) NO
i NO
NO
NO
NO
A. METHODS FOR SAFE HANDLING OF HAZARDOUS
MATERIALS: . . . . . . . . . .' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ NO
B. PROCEDURES FOR COORDINATING ACTIVITIES
WITH RESPONSE AGENCIES: . . . . . . . . ..' . . . . . . . . . . . . . . .. ¡ .NO
C. PROPER USE OF SAFETY EQUIPMENT:....~... ..,....... NO
D. EMERGE~CY EVACUATION PROCEDURES:..,.............. NO
E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS:.. . . . . . ES NO
. certify that the above information is accurate.
this i formation will be used to fulfill my firm's obligations under
the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95
Sec. 25500 Et AI.) and that'inaccurate information constitutes perjury.
SIGNATUd-~ TITLE
~ IJ.-11fUì
DATE 1,.-22"'~
HMCU-4
· VALLEY PROPELLER SERVt INC.
300 WATTS DRIVE Phone (805) 832-6033 7 _ /~. _ Þ--=
BAKERSFIELD, CALIFORNIA 93307 Ó ~ 0 0
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BUSINESS NAME VALLEY PROßIILOR SERVICE
LOCATION 300 WATTS D~
ID N~ER 215-000-001200
HIGH HAZARD RATING 3
1. OVERVIEW
LAST CHANGE 01/13/88 BY EVAMC
JURIS CODE 215-005 JURIS BAKERSFIELD STATION 05
MAP PAGE 124 GRID 08C FACILITY UNITS 1 HAZARD RATING 3
RESPONSE SUMMARY
2A SEC 4) NO PRIVATE RESPONSE TEAM
EMERGENCY CONTACTS 2A SEC 2)
CLIFF JOHNSON 832-6033 366-2347
JOHN HIXON 832-6033 322-0807
UTILITY SHUTOFFS 2A SEC 3)
A) GAS - SE CORNER OF BUILDING B) ELECTRICAL - INSIDE SE CORNER OF BUILDING
C) WATER - OUTSIDE SE CORNER D) SPECIAL - NONE E) LOCK BOX - NO
4. LOCAL EMERGENCY MEDICAL ASSISTANCE
LAST CHANGE 01/13/88 BY EVAMC
2A SEC 5) NEAREST HOSPITAL
&
PAGE 1
07/12/88 14:54
MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800
BUSINESS NAME VALLEY PROPELLOR SERVICE
LOCATION 300 WATTS DR
FACILITY UNIT 01
ID NUMBER 215-000-001200
HIGH HAZARD RATING 3
A. OVERALL HAZARDOUS MATERIALS INVENTORY
LAST CHANGE 02/18/88 BY EVAMC
ID TYPE NAME MAX AMT UNIT HAZARD
LOCATION CONTAINMENT USE
1 MIXTURE SODIUM CYANIDE SOLUTION 200 GAL HIGH
PLATING ROOM CENTER METAL CONTAINERS PLATING i
ID PERCENT COMPONENTS HAZARD LISTS I
1098.00 15.0 SODIUM CYANIDE (NA(CN) ) (EPA) HIGH EPA!
2 MIXTURE CHROMIC ACID 470 GAL HIGH
PLATING ROOM CENTER METAL CONTAINERS PLATING
ID PERCENT COMPONENTS HAZARD LISTS
1067.00 7.0 CHROMIC ACID, SOLID HIGH
3 PURE MINERAL SPIRITS 55 GAL MODERATE
CLEAN UP ROOM WEST WALL DRUMS OR BARRELS MET.. CLEANING
ID PERCENT COMPONENTS HAZARD LISTS
1203.02 100.0 NAPHTHA, SOLVENT EXTREME
4 MIXTURE LAQUER THINNER 55 GAL UNKNOWN
OUTSIDE NW CORNER OF BLD DRUMS OR BARRELS MET.. CLEANING
ID PERCENT COMPONENTS HAZARD LISTS
B. FIRE PROTECTION / WATER SUPPLIES
LAST CHANGE 01/13/88 BY EVAMC
< NO INFORMATION RECORDED FOR THIS SECTION >
PAGE 2
07/12/88 14:54
MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800
.
.
BUSINESS NAME VALLEY PROßIILOR SERVICE
LOCATION 300 WATTS dI'
FACILITY UNIT 01
ID N~ER 215-000-001200
HIGH HAZARD RATING 3
D. EMPLOYEE NOTIFICATION / EVACUATION
LAST CHANGE 01/13/88 BY EVAMC
3A SEC 2) IN CASE OF SPILLS, ROOM WOULD BE EVACUATED EXCEPT FOR CLEAN UP CREW.
NOTIFICATION WOULD NOT BE NECESSARY AS WE HAVE PROPER EQUIPMENT TO CLEAN UP
AND CONTAIN THESE CHEMICALS
E. MITIGATION / PREVENTION / ABATEMENT
LAST CHANGE 01/13/88 BY EVAMC
3A SEC 1) CHROMIC ACID SOLUTION CONTAINED IN 3/16" THICK STAINLESS TANK WITH
LID . SODIUM CYANIDE SOLUTION CONTAINED IN 3/16" THICK STAINLESS TANK WITH
LID. THESE CHEMICALS CONTAINED IN SEPARATE ROOM FROM REST OF SHOP WITH
SHOWER AND EYEWASH FACILITY IN ROOM. IN CASE OF SPILL I HAVE A STAINLESS
CONTAINER AND MOPS AND SPONGES TO CONTAIN AND CLEAN. THE ROOM HAS 2 EXIT
DOORS AND VENTILATION FAN. WE ALSO HAVE RUBBER GLOVES AND RUBBER SUITS FOR
CLEAN UP CREW. THE LACQUER THINNER AND SOLVENT ARE CONTAINED IN 55 GALLON
STEEL DRUMS WITH LIDS.
PAGE 3
07/12/88 14:54
MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800
F:ii'a;~~EÆI[~:¡til"[~'%f';E'::i~~I~~:~]:g3;~~:7~i:~\:~~i~~)~J;?1;~f:1'ZiY~~";';::1::::¡;¡:2L~:r:1'~~ŒI{"
V'f!ÌV-"- 72-62--7820-0~ .' ,AslìlandChemical£i1mpant( ,~ r ';
,;.t;7'S'î DIVISIDI\ DF ASHLAND OIL. INC'. 'A' 'h" ·.wI ¡
. ~f~i MATERIAL SAFETY p, 0, BOX 2219, COLUMBUS,OHIO 43216 . 16141 33~®è
~~~~ß~~~~;!Î'~~~;~fR1m:i'r:'5Ji:~,,:p:9;NE,1~61:"¡i'i~~5.:';:Z;¿L:~;2:-::;g¡¡;_i!~,
00~93'1-
~SHLAND THINNER 666 B MEDIUM
PAGE: ~
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THIS MSDS COMPLIES WITH 29 CFR ~9£Ð.~20Ð, (THE HAZARD COMMUNICATION ~TANDARD)
S; S;!Ii!li!li!li!li!li!li!liiJi!li!li;1('!Ii iJi!li S; iJi iJi!li!li !Ii',l;iJi iJi iJi!li iJiiJi!li iJi iJi iJi!li!li!li!lli!li!liiJi;:r; iJi;:r;;:r;!Ii !Ii !Ii !Ii iJi iJi iJi iJi!li;:r; iJi!li!li!li S; iJi iJi S;!liS; S; iJi S;!Ii!li;,r¡ '-";';!Ii;,r¡;,r¡. ",.;,r¡!Ii;,r¡;,r¡
, , .
PRODUCT NAME:
ASHLAND THINNER 666 B MEDIUM
" -
VALLY PROPELLER SERVICE
300 WATT,S DRIVE
BAKERSFIELD CA 93309
05 50 033 93'1-9760-
DATA SHEET NO: 002~20S-0U~
LATEST REVISION DATE: 0~/96-S6063
PRODUCT: 7S~~562
INVOICE: 969~20
INVOICE DATE: 0'1-/1'1-/86
TO: VALLY PROPELLER SERVICEE
300 WATTS DR
BAKERSFIELD CA ~3309
~TTN: PLANT MGR./SAFETY DIR.
--!-------------~----------------------------------------------------------------~--
,SECTION I":PRODUCT IDENTIFICATION
--------------------------------------.------------.--~--------------------------------
GENERAL OR GENER~C ID: SOLVENT BLEND
DOT' HAZARD CLASSIFICATION: FLAMMABLE, LJ:'QUID (173,1'15')
---------------------'----_._------------~_._--------------------.------.-.----.--.---------
SECTION II-'COMPONENT.S
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -, - - - - -.- - - -,,- - _.- -'- - - - ;. - - - - -'- - - - - - - - - - - - - - -
XNGREDIENT Z (,BY V,OL'), ,PEL TLV NOTE
---------- - - - - - - -.'- - -
ESTER ;1' ~W30 ~,50 ~,50 PPM
, ,31:'-:, 3~ er !}31..9· -.
ALIPHATIC 500 PPM 1)
HYDROCARBON ;1' I
AROMATIC ~ Jb~, ~ 0 -30 33;t9·, 200 100 PPM ,¿~' .
HYDROCARBON !Ii
ALCOHOL ;II! 1''-16- ~r" 'f00 '1-00 PPM
KETONE ;a¡ /006 - -~O 200 '200 ,PPM
~ ) NIOSH RECOMMENDS A LIM T 0 350 MG/CUM S HOUR TIME WEIGHTED AVt::RAGE, ~SOO
MG/CUM AS DETERMINED BY 5 MINUTE SAMPLE.
;ll!THE ~PECIFIC CHEMICAL IDÉNTITY HAS BEEN WITHHELD AS A TRADE SECRET.
"I
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--------------------------------------------------------------------.---------------
S~CTION II%-PHYSICAL 'DATA
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--------------_._----------~---------------~-------------.-------------------.--------
' ,
'PROPERTY
.-'- - ,- - - - -
,REFI:NEMENT
----------
MEASUREMENT
-----------
BOILI'NG POINT
FOR :COMPONENT c.~,- ~ 0
Z)
VAPOR PRESSURE
FOR COMPONENT(
-----------------------------.-----------------.---------------
(
a
~ 75 . 'DO
79, ''I-'"
,760.' 0:0
DEG F
DEG C)
MMHG
~-~OZ)
a
(
70.0D
6S.00
20,00
MMHG
DEG F
DEG C)
SPECIFIC VAPOR DENSITY
-------------------------------------------.-----------------
SPECIF:'C GRAVIT'Y
- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -.- - - - - - - -
HEAV~ER THAN AIR
PERCEr;'" VOLATILES
EVAPORATXON RATE
-----------------------------------------------------------
LESS THAN 'WATER
-----------------------------------------------------------
100.00Z
SLOWER THAN ETHER
~---------------------------_._-----------------------------------------------------
SECTION IV-FIRE AND EXPLOSXON INFORMAT~ON
-----------------------------------------------.------------------------------------
FLASH POINT
< 73 DEG F
< 23 DEG C)
EXPLOSI,VE LIMIT
(LOWEST VALUE PF COMPONENT) LOWER _
1.2Z
~.TINGU~SH~NG MED~A: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMXCAL
~AZARDOUS DECOMPOS~TION PRODUCTS: MAY FORM TOXIC MATERIALS:, CARBON DIOXIDE AND
CARBON MONOXIDE, V~R~OUS HYDROC~RBONS,ETC, '
~IREFJ:GHTING PROCEDURES: WEAR SELF-CONT'AINEDiBREATHING APP'ARATUS WITH A FULL
FACEPIECE OPERAYED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE WHEN
FIGHTING FIRES.
!'~ECIALFIRE & EXPLOSION HAZARDS: VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG
THE GROUND OR MAY BE MOVED "BY VENTILATION AND IGNITED BY PILOT LIGHTS, OTHER
FLAMES, SPARKS, HEATERS, ~SMOKING, ELECrRIC MOTORS, STATIC DISCHARGE, OR OTHER
IGNITION SOURCES AT LOCATIONS D~STANT FROM MATER~AL HANDLING POINT.
NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE
PRODUCT (EVEN ~UST RESIDUE) CAN ~GNITE EXPLOSIVELY,
ALL F~VE GALLON PAILS AND LARGE~ ~ETAL CON~AINER~ SHOULD BE GROUNDED AND/OR
B-ONDED WHEN MATERIAL IS TRANSFERRED.
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--------------------------------------.-------------------.---------------------------
SECTION V-HEALTH HAZARD DATA
e
------------------------------------.------------.-----------------------------------
PERMISSIBLE EXPOSURE LEVEL: NOT ESTABLISHED FOR PRODUCT.
- EFFECTS "OF ACUTE ,OVEREXPOSURE: FOR PRODUC,T
SEE SECTION XI.
_.- - - - - - - - - - - - - - - - - - - - - - - - - - - - -
EYES - CAN 'CAUSE SEVERE IRRITATION, -REDNESS, TEARING,
BLURRED VISION,
COPYRIGHT ~9,86
:CO,NT:INUED 'ON' PA'GE: 2
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~:;>t~~;~~~7Z::~~ -;~V~:,~:;ì:u ~~:' ls:: ~~J~~~l:'~~ '"~~~~~~. f1t þ:-:~~~~~~ ~~)~7" _~_: ~ r':~~i.~7:·~c .='"::;~¡; :..~':-:;:~ ~1
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t ~ '. DIVISION OF ASHLAND OIL. INC'. II 'hl d r
·l;:;~j MATERIAL SAFETY P 0' BOX 2219, COLUMBUS. OHIO 43216 . (614) "333~~® ¡.,
1" <; DATA SHEET 24-HOUR EMERGENCY TELEPHONE (606) 324~1133 . }'
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0'0193~
ASHLAND THINNER 666 B MEDIUM
PAGE: 2
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- - - - - - - - - - -"- - -.- - - - - - - - - - - - - - - - - - - - - -'.... - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - -
SECTION V-HEALTH HAZARD DATA (CONTINUED)
-----------------------------------------------------------------------------------
SKIN PROLONGED OR REPEATED CONTACT CAN CAUSE .MODERATE IRRITATION. DEFATTING.
DERMATITIS,
BREATHING EXCESSIVE INHALATION OF ~APORS CAN CAUSE NASAL AND RESPIRATORY
IRRITATION. DIZZINESS. WEAKNESS. FATIGUE. NAUSEA. HEADACHE. POSSIBLE
UNCONSCIOUSNESS. AND EVEN ASPHY,XIATION,
SWALLOWING CAN CAUSE GASTROIN'(ESTINAL IRRITATION. NAUSEA. VOMITING. AND DIARRHE·A,
ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN
BE FATAL,
FIRST AID:
----------
IF ON SKIN: THOROUGHLV WASH EXPOSED ~REA WITH SOAP AND WATER,
, CLOTHING. LAUNDER CONTAMINATED CLOTHINGBEFORE~E~USE.
IF IN ~VES: FLUSH WITH LARGE AMOUNTS OF WATER. LIFTING UPPER AND LO~ER LIDS
OCCASIONALLY. GET MEDICAL ATTENTION.
REMOVE ~ONTAMINATED
-I·F ',SWALLOWED: DO·NOT INDUCE VOMITING. KEEP P.ERSON WARM. QUIET. 'AND ',GET MEDICAL
ATTENTION. ASPIRATION OF MATERIAL INTO THE .LUNGS DUE TO VOMITING CAN CAUSE
CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.
IF ;BREA'THED: IF AFJ=:ECTED.'REMOVE INDI,VIDUAL TO FRESH AIR, I·F BREATHI'NG I·S
DIFFICULT. ADMINISTE,R ,OXYGEN, 'I'F BREA'THING HASSTOPP'ED GIVE ARTIF'rCIAL
RESPIRATION, -KEEP PERSON WARM.' QUIET AND ·GET MEDICAL ATTENTI'ON,
PRIMARY ROUTE(5) OF' ENTRY:
--.------------"------------
INHALATI,ON
SKIN CONTACT
EFFECTS OF' CHRONI,C OVEREXPOSURE: F'OR' ',P;RODUCT
- - - - - - - - - - - - - - - - --- - -'- - - - - -,- - - - -.-
MINOR EMBRYOTOXIC/FETOTOXIC EF'FECTS HA~EBEEN OBSERVED IN LABORATORY RATS EXPOSED
TO METHYL "ETHY.L ·KET.ONE ·BY .INHAL·AT'I'ON ,AT ,LEVELS GREATER T"HAN '1.000 P,PM·(S TIMES
THE OSHA-PEL/TWA) FOR MOST OF THE GESTATION PERIOD,
OVEREXPOSURE TO THIS MATERIAL (OR ITS COMPONENTS) HAS APPARENTLY BEEN FOUND TO
CAUSE THE F:OI..;LOW'I·NG,EFFEC'T,S 'IN L:A'BORATORY A'NIMALS:. L,IiVER ABNORMAL'ITI-ES.
·KIDNEY- 'DAMAG·E. BR.AIN-cDAMA-GE." LUNG-DAMA·GE. SPL·EEN ,DAMA'GE
OVEREXPOSURE TO THIS ,MATERIAL (.OR ,IT,S COMPONENTS,) HAS BEEN 'SUGGESTEDAS A CAUSE 'OF
THE F.OLL·OWING EF'FECTS IN HUMANS,:, KIDNEY DAMAG'E. L'IV'ER ABNORMALITIES
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- - - - - - - -.- -- - - - - - - - - - - -"- - - - -- - - - _.- - - - - - - - - -^- - - - - - - - - - -'- - - - - - - - - - - - - -- --- -'- - - - - - -.- - - --
SECT:ION VI-REACT:IVITY DATA
---.---"-----------------------------------------------------------------------------
HAZARDOUSPOLVMERIZATION: CANNOT OCCUR
STABILITY: 'STABLE
INCOMPATIBILITY, AVOI,D CONTACT WITH:, ~TRONG OXIDIZING AGENT.S.
-------------------------------,-------------------------------_._-------------------
SEdTION VII-SPXLL OR LEAK PROCEDURES
-.---_._-------------'------------------------------------------.------------------------
STEPS TO BE TAKEN IN CASE ·MATERI'AL IS RELEASED OR 'SPILLEr:J:
-------------------------------.---------------------------
SMALL SPILL: A.BSORB LIQUID ON PAPER. VERMICULI·TE. FLOOR ABSORBENT. OR OTHER
ABSORBENT 'MATERI'AL AND TRANSFER TO HOOD.
LARGE SPILL: ELIMINATE ALL IGNITION SOURCES (FLARES. FLAMES .INCLUDING PILOT LIGHTS.
ELECTRI,CAL SPARKS). PERSONS NOT WEARI·NGP.ROTECT,IVE EQUIPMENT SHOULD BE
EXCLUDED FROM AREA OF SPIL'L UNTIL CLEAN-UP HAS BEEN COMPLET,ED, STOP SPILL AT
SOURCE. DIKE AREA OF SPIl.L TO ,PREVENT SPREA'DING. PUMP .LIQUID TO SALVAGE TANK.
REMAINING LIQUID MAY BE TAKEN UP ON SAND. CLAY, EARTH. FLOOR ABSORBENT. OR
OTHER ABSORBENT MATERIAL 'AND SHOV'EL'ED ,I'NTO CONTAI'NERS,
WASTE DISPOSAL METHOD:
----------------------
SMALL SPILL: ALLOW VOLATILE PORTION TO£VAPORATE IN HOOD. ALLOW SUFFICIENT TIME FOR
VAPORS ~O COMPLETELV CLEAR"HOOD DUCT WDRK, DISPOSE ÐF REMAINING MATERIAL IN
ACCORDANCE WITH APPLXCABLE REGULATIONS.
LARGE SPILL: ·DESTROy BY LIQUID'INCINERA'T'ION,
CONTAMINATED ABSOR.BENT MAY BE DEPOSITED IN A LANDFILL IN ACCORDANCE WITH
LOCAL. STATE AND FEDERAL REGULATIONS.
----------"--------------.----.---------------------------------------------------------
SECTION NIIX-PROTEC~IVE EQUIPM~NT TO BE USED
-----.-------------.------------------.------.---------..-----------------------------"--
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RESPIRA'T,ORY PROTECTION: IF T·LV OF T.HE PRODUCT OR ANY COMPONENT IS EXCEEDED. A
NIOSI:i/MSHA .JOINTLY '-'APPROVED'A:I-R 'SUPPL'IED RESPI'RATOR IS ADVISED INA'BSENCE OF'
PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PE~MIT OTHER NIOSH/MSHA
RESP:IRATORS UNDER SPECIFIED CONDITIONS. (SEE YOUR 'SAFET'Y ,EQUI'PMENT SUPPLIER).
ENGZ'NEERING OR ADMINISTRATIVE CONTROL-S SHOULD BE IMPLEMENTED TO 'REDUCE
EXPOSURE.
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VENTILATION: PROVIDE SUFFICrENT MECHANZ'CAL (GENERAL AND/OR LOCAL EXHAUST)
VENTILATI,ON TO MAINTAIN EXPOSURE ';BELOW TLV·(,S).
PROTECTIVE GLOVES: .WEAR RESI'STANT 'GLOVES SUCH AS:. 'NEOPRENE
EYE PROTECTION: CHEMI'CAL 'SPLASH GOGGL'ES IN COMPL'IANCE WITH OSHA REGULATI·ONS "ARE
ADVISED} HOWEVER. OSHA REGULATI,ONS ,ALSO PERMIT OTHER TVPE SAFETY GL'ASSES.
,COPYRIGHT ,:1.986
CONT.INUED ON PA:GE: '3
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F·····.·};~~~:i.:J}::;;,~~Ç;~2;:Iif·,,,¡;~~:iii:::Jfll$)~·~ili~~~¡t~~~m:~~i1~'if'i.~~~rSÐ~ G:¿~s:i:rt~rZif:;&;-:~,~:2Slj;;l::~E~:1~3i2j~',.
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~éì . DIVISION OF ASHLAND OIL.INC,. A fill! t .
. k··'j MATERIAL SAFETY P. o. BOX 2219, COLUMBUS, OHIO 43216. (614) 33 ~~®t:
ì~ ~ DATA SHEET 24-HOUR EMERGENCY TELEPHONE (606)324-1133¡"
r '~'¿R';=~.:;I:-£2i:ll~g~~';~:;:¿::S}';~~7I~~~:L:~~C.,;Z~,~;';:~:i:I;:~~,:';::ÝJ.;L;,:;.&l~,~::~~;'! . ~~.:;:;~ (:J.l:~'~:~;='>'-':=ZiL~
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ASHLAND THINNER 666 B MEDIUM
pAGE: a
-------------------..--------------------.-------------------------------------------
SECTI.;JN VIII-PRO'TECTIV'E EQUIPMENT ,TO BE USED (CONTINUED)
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-------------------~---------------------------------------------------------------
(CONSULT YOUR =RFETV EQUIPMENT SUPPLIER)
OTHER PROTECTIVE EQIJZPMENT: TO PREVENT REP~ATED OR PROLONGED SKIN CONTACT. WE~R
IMPERVIOUS CLCTH%NG AND BOOTS.
-----------------------------------------------------------------------------------
SF.CTION IX-SPECIAL PRECAUTIONS OR OTHER COMMENTS
-----------------------------------------------------------------------------------
CONTAINERS OF THIS MATER~AL MAV BE HAZARDOUS WHEN EMPTIED.EINCE EMPTIED CONTAINtRS
RETAIN PRODUCT RESIDUES (VAPOR. LIQUID. AND/OR SOLID). ALL HAZARD PRECAUTIONS
GIVEN IN THE DATA SHEET MUST BE OBSERVED.
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT I'S NOT. WARRA'NT,ED
TO ~E WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO
CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT. APPLICABLE. ~ND
£UITABLE TO THEIR CIRCUMSTANCES.
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DIVISION DF ASHLAND OIL, INC,
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MÞ,TERIAL SAFETY
DATA SHEET
P,o, Bo;~ 2219, COLUM!JUS, OHIO ':3216 .1614! B!H)'3333
005880
KW:tK DR:t 66
PAGE, 1
ACCEPTED BY O.S.H.A, AS ESSENT:tALLY S:tM:tL:tAR TO O.S.H.A, ~ORM 20
2~-HOUR EMERGENCY TELEPHONE, 606-32~-1i33 (LOCATED AT ASHLAND, KENTUCKY)
~~~~~~*~~~~**~*~~~~~~~~~~*~~*~~*~*~~~~~~~~~~~~~~*~~~~~~*~~~~~~~~~~œ~œ**~~*~~~~~~~~~~
ASHLAND PRODUCT NAME: KW:tK DR:t 66
ASHLAND CHEMrCAL CO.
i331 A ROBERTS LANE
BAKERs~rELD, CA ~3302
ATTN: CHR:tS ~EVRrs
OS +50
DATA SHEET NO: 00i39~7-ooi
LATEST REV:tsrON DATE: 12/77-773~B
PRODUCT, 2~9S000
:tNvorCE, ACCLOC
:tNvorCE DATE; oS/10/S3
TO,
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INTERCOMPANY
MAIL
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-----------------------------------------------------------------------------------
SECT:tON :r-PRODUCT ZDENï~~rCAT:tON
-----------------------------------------------------------------------------------
GENERAL ORGENERZC :rD, ALZPHATZC HYDROCARBON
HAZARD CLASS:t~rCATZON, (io)'COMBUST:tBLE Ci73.iiS)
-----------------------------------------------------------------------------------
SECT:rON :t:t-HAZARDOUS COMPONENTS
-----------------------------------------------------------------------------------
INGRED:tENT
PERCENT
PEL
'"',
----------
-------
KW:tK DR:t
100,00;..0:
i )
500
PPM
i): NIOSH RECOM'MENDS A TLV O~ 350 MG/CUM.
------------------------------------------Ñ----------------________________________
SECT:tON J:I:t-PHYS:tCAL DATA
-----------------------------------------------------------------------------------
PROPERTY
RE~:tNEMENT
MEASUREMENT
--------
----------
:tNIT:tAL BO:tL:tNG PO:tNT
-----------
~OR PRODUCT
300,00
1"B.9B
760.00
DEG ~
DEG C)
MMHG
VAPOR PRESSURE
(
~
-----------------------------------------------------------
~OR PRODUCT
. .'_.~ -. .._._~.-.~- -.,....
< i2.00
S 100.00
( 37.77
MMHG
DEG F
CEG C)
VAPOR DENS:tTY
SPEC:t~ZC GRAV:tTY
-----------------------------------------------------------
A:tR
i
~,7
-----------------------------------------------------------
PERCENT VOLATILES
EVAPORAT:tON RATE
~
(
.750
60.00 DEG F'
15.55 DEG C>
-----------------------------------------------------------
100.00 ;..0:
-----------------------------------------------------------
(ETHER
= i)
36,00
-----------------------------------------------------------------------------------
SECTXON :tV-~:tRE AND EXPLOS:tON DATA
-.----------------------------------------------------------------------------------
~LASH PO:tNT(CLOSED CUP)
LOWER EXPLOS:tVE LXM:tT
ioo,OO
37.77
(PRODUCT)
='-
DEe:; ~
DEG C)
1.0
EXT:tNGUZSH:tNG MED:tA: REGULAR ~OAM OR CARBON D:tOX:rDE OR DRY CHEM:rCAL
HAZARDOUS DECOMPOS:tTXON PRODUCTS: MAY PORM TOXIC MATERIALS:, CARBON D:tOX:tDE AND
CARBON MONOX:tDE, VAR:tOUS HYDROCARBONS, ETC.
SPEC:rAL ~:tRE~:tGHTING PROCEDURES, SEL~-CONTAZNED BREATH:tNG APPARATUS WZTH A ~ULL
~ACEP:tECE OPERATED IN PRESSURE_DEMAND OR OTHER POSIT:tVE PRESSURE MODE.
UNUSUAL ~:tRE & EX~LOSION HAZARD~: VAPORS ARE HEAV:tER THAN AZR AND MAY TRAVEL
ALONG THE GROUND OR BE MOVED BY VENTJ:LATION AND IGNITED BY HEAT, P:tLOT
LIGHTS, OTHER ~LAMES AND IGNITION SOURCES AT LOCAT:tONS D:tSTANT ~ROM
MATERIAL HANDL:tNG PO:tNT,
NEVER USE WELDING OR CUTT:tNG TORCH ON OR NEAR DRUM (EVEN EMPTY) BECAUSE
PRODUCT (EVEN JUST RES:tDUE) CAN :tGN:tTE EXPLOS:tVELY,
-----------------------------------------------------------------------------------
SECTION V-HEALTH HAZARD DATA
-----------------------------------------------------------------------------------
PERM:tSSJ:OLE EXPOSURE LEVEL,
EF'~ECTS OF' OVEREXPOSURE; ~OR PRODUCT
500
PPM
--- ----- - - - - - - -- ---- -- --
EYES CAN CAUSE SEVERE :tRR:tTAT:tON, REDNESS, TEAR:tNG, BLURRED VZS:tON,
SK:tN - PROLONGED OR REPEATED CONTACT CAN CAUSE MODERATE :tRRITATZON, DEF'ATTJ::,:'(,....',;
----::.... CERMAT:ITIS. ~.....
BREATHING EXCESS:tVE INHALATION O~ VAPORS CAN CAUSE NASAL AND RESPZRATORY
:tRR:tTATXON, OJ:ZZINESS, WEAKNESS, ~ATJ:GUE, NAUSEA, HEADACHE. POS~~BLE
_UNCONSC:tOUSNESS, AND EVEN ASPHYXJ:AT:tON,
SWALLOW:tNG CAN CAUSE GASTRO:tNTEST:tNAL :tRR:tTAT:tON, NAUSEA, VOMZT:tNG, AND
D:tARRHEA, ASP:tRAT:tON or- MATER:tAL :tNTO THE LUNGS CAN CAUSE CHEMICAL
PNEUMONJ:Trs WH:tCH CAN BE FATAL,
CONTINUED ON PAGE, 2
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Ashland Chemical camoenr.
DIVISION OF ASHLAND OIL. INC,
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MAïERIÞ,L SAFï:TY
DATA SH~ï:T
P,O, ao:; 2219, COLUM[JUS. OHIO 43216 -16141 88;-3333
005BBO
KWIK DRI 66
PAGE, 2
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SECTION V-HEALTH HAZARD DATA (CONTINUED)
-----------------------------------------------------------------------------------
F'IRST AID:
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IF' ON SKIN: THOROUGHLY WASH EXPOSED AREA WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING. LAUNDER CONTAMINATED CLOTHING BEF'ORE RE-USE.
IF IN EYES, FLUSH WITH LARGE AMOUNTS OF WATER, LIFTING UPPER AND LOWER LIDS
OCCASIONALLY, GET MEDICAL ATTENTION,
IF SWALLOWED: DO NOT INDUCE VOMITING, KEEP PERSON WARM, QUIET, AND GET MEDICAL
ATTENTION. ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN CAUSE
CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.
IF BREATHED, IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS
DIFFICULT, ADMINISTER OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL
RESPIRATION. KEEP PERSON WARM. QUIET AND GET ME.CICAL ATTEN1;..I.Q .
----------------------------------------------------------------
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SECTION VI-REACTIVITY DATA
---------------------------------------------------------------.
HAZARDOUS POLYMERIZATION, CANNOT OCCUR
STABILITY: STABLE
INCOMPATABILITY: AVOID CONTACT WITH" STRONG OXIDIZING AGENTS.
---------------------------------------------------------------
SECTION VII-SPILL OR LEAK PROCEDURES
--------------------------------------------------------------.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEA~ED OR SPILLED:
, . .
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SMALL SPILL: ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT. OR OTHER
ABSORBENT MATERIAL AND TRANSFER TO HOOD.
LARGE SPILL, ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES INCLUDING PILOT
LIGHTS, ELECTRICAL SPARKS). PERSONS NOT WEARING PROTECTIVE EQUIPMENT
SHOULD BE EXCLUDED FROM AREA OF SPILL UNTZL CLEAN-UP HAS BEEN COMPLETED.
STOP SPILL AT SOURCE. DIKE AREA OF SPILL TO PREVENT SPREADING. PUMP LIQUID
TO SALVAGE TANK. REMAINING LIQUID MAY BE TAKEN UP ON SAND, CLAY. EARTH,
FLOOR ABSORBENT, OR OTHER ABSORBENT MATERZAL AND SHOVELED INTO CONT^INEPS
PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODZES OF WATER,IF' RUN-OFF
OCCURS. NOTIFV PROPER AUTHORITIES AS REQUIRED. THAT A SPILL HAS OCCURED.
WASTE DISPOSAL METHOD:
- - - - - - - - - - - - - - - - ---- --
SMA~L SPILL: ALLOW VOLATILE PORTION TO EVAPORATE IN HOOD, ALLOW SUFFICIENT TIME
FOR VAPORS TO COMPLETELY C~EAR HOOD DUCT WORK, DISPOSE OF REMAINING
MATERIAL IN ACCORDANCE WITH APPLZCABLE REGULATIONS.
LARGE SPILL: DESTROY BY LIQUID INCINERATION,
CONTAMINATED ABSORBENT MAY BE DEPOSITED IN A LANDFILL IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS,
-----------------------------------------------------------------------------------
SECTION VIII-PROTECTIVE EQUIPMENT TO BE USED
-----------------------------------------------------------------------------------
RESPIRATORY PROTECTION, IF TLV OF THE PRODUCT OR ANY COMPONENT IS EXCEEDED, A
NIOSH/MSHA ~OINTLY APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE
OF PROPER ENVIRONMENTAL CONTROL,. OSHA REGULATIONS ALSO PERMIT OTHER
NIOSH/MSHA RESPIRATORS UNDER SPECIFIED CONDITIONS, (SEE YOUR SAFETY
EQUIPMENT éUPPLIER~, ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE
IMPLEMENTED TO REDUCE EXPOSURE.
VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST)
VENTI~ATION TO MAINTAIN EXPOSURE BELOW TLV(S),
PROTECTIVE GLOVES: WEAR RESISTANT GLOVES SUCH AS,. BUNA-N
EYE PROTECTION: CHEMICAL SPLASH GOGGLES IN COMPLIANCE W7,TH OSHA RECiULATIONS
ARE ADVISED, HOWEVER, OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY
GLASSES, (CONSULT YOUR SAFETY EQUIPMENT SUPPLIER)
OTHER PROTECTIVE EQUIPMENT, TO PREVENT REPEATED OR PROLONGED SKIN CONTACT. WEAR
IMPERVIOUS CLOTHING AND BOOTS,
-------------------------------------~---------------------------------------------
SECTION IX-SPECIAL PRECAUTIONS OR OTHER COMMENTS
-----------------------------------------------------------------------------------
CONTAINERS OF THIS MATERIAL MAY DE HAZARDOUS WHEN EMPTIED, SINCE EMPTIED
CONTAINERS RETAIN PRODUCT RESIDUES (VAPO~, LrQUID, AND/OR SOLID). ALL
HAZARD PRECAUTIONS GIVEN IN THIS DATA SHEET MUST DE OBSERVED,
THE INFORMATrON ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
W~RRANTED TO BE WHETHER ORIGINATING WITH ASHLAND OR NOT, RECIPIENTS ARE
ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT.
APPLICABLE, AND SUITADLE TO THEIR CIRCUMSTANCES,
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LAST PAGE--SE~ ATTACHMENT PAGE ENCLOSED--LAST PAGE
HAZARD~US M~~S Ir!PECTION
- - -
BUSINESS NAME: jLJle f Pro p e 11 () r S e r V; <: e
LOCATION: '300 \}J 0. -it 5 0 r
INSPECTION DATE: '3 - I 5 - ~ «
INSPECTOR: .J:\ e", ~ '( i (', k S 0 V\
PROPER SEGREGATION OF MATERIAL
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VERIFICATION OF INVENTORY MATERIALS
VERIFICATION OF QUANTITIES
VERIFICATION OF LOCATION
COMMENTS :
VERIFICATION OF BAZ MAT TRAINING
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VERIFICATION OF MSDS AVAILABLE
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COMMENTS: J M ~ pJ I ~+(>, \ OCC7< +-I~ ~ o~ M S 0 5
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VERIFICATION OF ABATEMENT SUPPLIES & PROCEDURES [j2j
COMMENTS: Ml't,Jq+,.iVl. - \1'10('.; bbp¡r c:;vJs -jUS} OI'fv'o\o'\..s f B 1óve
COMMENTS: .11 OV1 ~ f" s+-e~
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EMERGENCY PROCEDURES POSTED
CONTAINERS PROPERLY I,AR1U.1m
VERIFICATION OF FACILITY DIAGRAM
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SPECIAL HAZARDS ASSOCIATED WITH THIS FACILITY:
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VIOLATIONS:
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APRIL 15. 1988
Dear ~r. JOHNSON
NOTICE OF VIOLATION AND SCHEDULE FOR COMPLIANCE
IN THE INSPECTION OF YOUR BUSINESS VALLEY PROPELLER
SERVICE INC. LOCATED AT 300 WATTS DRIVE BAKERSFIELD, CA
93307 ON 4/4/88 THE FOLLOWING HAZARDOUS MATERIALS REGULATION
VIOLATIONS WERE IDENTIFIED.:
1) HAZARDOUS MATERIALS BUSINESS PLAN NOT CURRENT (NEW
OWNERSHIP) .
VIOLATION OF CH. 6.95 CALIFORNIA HEALTH AND
SAFETY CODE Sect.25505
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"(b) In addition to the requirements of Section
/ 25510, whenever a substantial change in the handler's
operations occurs which requires a modification of its
business plan, the handler shall submit a copy of the
plan revision to the administering agency within 30 days
of the operational change.
(c) The handler shall, in any case, review the
business plan, submitted pursuant to subdivisions (a)
and (b), on or before January 1, 1988, and at least once
every two years thereafter, to determine if a revision
is needed and shall certify to the administering agency
that the review was made and that any necessary changes
were made to the plan, A copy of these changes shall be
submitted to the administering agency as part of this
certification.
(d) Unless exempted from the business plan
requirements under this chapter, any business which
handles a hazardous material shall annually submit a
~ completed inventory form to the administering agency of
,_c::--:--the--count.y---o-r--ci tY::=in;:'t4tfic11-'''the business is located .----- ----- ..-
Notwithstanding any other provisions of the law, an
inventory form shall be filed on or before January 1,
1988, for the 1988 calendar year, and annually
thereafter. This inventory shall be filed annually,
notwithstanding the review requirements of subdivision
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2) CONTAINERS NOT PROPERLY LABELED - SOLVENT DRUM IN CLEANING
ROOM - (5) GALLON SOLVENT CO~TAINERS, ACID BOTTLES AT EAST
SIDE OF PROPERTY, ACIDE DIP T)\NKS, LJNMAIi',IŒD (30) GALLON
TRASH CANS IN PLATING AREA.
VIOLATION OF OSHA 1910.1200
(l)The chemical manufacturer, importer, or
distributor shall ensure that each container of
hazardous chemicals leaving the workplace is labeled,
tagged or marked with the following information:
(i)Identity of the hazardous chemical(s).
(ii)Appropriate hazard warnings; and
(iii)Name and address of the chemical
manufacturer, importer, or other responsible
party. .,'-
( 4) Except as provided in paragraphs {3 )'tà.nd >( 4) the
employer shall ensure,that each container of hazardous
chemicals in the workplace is labeled, tagged, or
marked with the following information:
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(i)Identity of the hazardous chemical(s)
contained therein; and
(ii)Appropriate hazard warnings.
(5)The employer may use signs, placards, process
sheets, batch tickets, operating procedures, or other
such written materials in lieu of affixing labels to
individual stationary process containers, as long as the
alternative method identifies the containers to which it
is applicable and conveys the information required by
paragraph (2) of this section to be on label. The
written materials shall be readily accessible to the
employees in their work area throughout each work shift.
(7)The employer shall not remove of deface existing
labels on incoming containers of hazardous chemicals,
unless the container is immediately marked with the
required information.
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n._..__ (8) The-employer shall ensure that labels or other__
forms of warnings are legible, in English, and
prominently displayed on the container, or readily
available in the work area throughout each work shift.
Employers having employees who speak other languages may
add the information in their language to the material
presented, as long as the information is presented in
English as well.
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3) EMPTY HAZARDOUS MATERIAL CONTAINERS NOT PROPERLY SEALED OR
STORED OUTSIDE OF BUILDING - NORTH SIDE.
VIOLATION OF UFC ì9.201(C)
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Empty Containers. The storage of empty tanks and
containers previously used for the stora~e of flammable
or combustible liquids, unless free from explosive
vapors, shall be as specified for the storage of
flammable liquids. Tanks and containers when emptied
shall have the covers or plugs immediatelJ' replaced in
openings.
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4) OPEN CONTAINERS VARIOUS LOCATIONS THROUGHOUT THE SHOP
COULD EASILY BE SPILLED.
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VIOLATION OF UFC 80.103(C)
Defective containers which permit leakage or
spillage shall be disposed of or repaired in accordance
with recognized safe practices; no spilled material
shall be allowed to accumulate on floors or shelves.
5) EMPLOYEE HAZARDOUS MATERIAL TRAINING INSUFFICIENT.
VIOLATION OF OSHA 1910.1200(H)
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/'t 2) Training. Employee training shall include at
lea:~t:
1/ (i) Methods and observations that may be used
to detect the presence or release of a hazardous
chemical in the work area (such as monitoring
conducted by the employer, continuous monitoring
devices, visual appearance or odor of hazardous
chemicals when being released, etc.);
(ii)The physical and health hazards of the
chemicals in the work area;
(iii)The measures employees can take to
protect themselves from these hazards, including
specific procedures the employer has implemented to
protect eriJ.pì-o-yee-s·-f~r-6~xposure -to hazardous
chemicals, such as appropriate work practices,
emergency procedures, and personal protective
equipment to be used; and,
(iv)The details of the hazard 8ommunication
program developed by the employer, including an
explanation of the labeling system and the material
safety data sheet, and how employees can obtain and
use the appropriate hazard information.
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6) MATERIAL SAFETY DATA SHEETS NOT READILY AVAILABLE
EHPLOYEES.
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VIOLATION OF OSHA 1910.1200
(g) The employer shall maintain copies of the
required material safety data sheets for each hazardous
chemical in the workplace, and shall ensure that they
are readily acc~ssible during each work shift to
employees when they are in their work area(s)
(h)(I) INFORHATION. Employees shall be informed of:
(i)The requirements of this section
(ii)Any operations in their work area where
hazardous chemicals are present; and,
(iii)The location and availability of the
written hazard communication progràm,
including the required list(s) of hazardous
chemicals, and material safety data sheets
required by this section.
7) EMERGENCY PROCEDURES NOT POSTED.
VIOLATION OF CALIFORNIA HEALTH AND SAFETY
CODE CHAPTER 6.95, 25504(B)
- Business plans shall include all of the following:
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Emergency response plans and procedures in the event of
a reportable of threatened release of a hazardous
material, including, but not limited to, all of the
following:
(1) Immediate notification to the administering
agency and to appropriate local emergency
rescue personnel and the office.
(2) Procedures for the mitigation of a release or
threatened release to minimize any potential
harm or damage to persons, property, or the
environment.
(3) Evacuation plans and procedures, including
- --------'-'-'--'-i-mmed±at-e-'rrot-i'b-e-¡-f'or the business site.
The above violations must be corrected
b'l M - ~1(\8()
.,~, 1988.
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The department will schedule a re-inspection of your facility
to verify compliance. If you have any questions regarding
this notice, please contact Ralph Huey at 326-3979.
Sincerely,
Ralph E.Huey
Hazardous Materials Coordinator
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