HomeMy WebLinkAboutHAZARDOUS WASTE
HAZ~US MATERIALS D*SION
TIME CHARGED
BUSINESS/DEAPRTMENT NAME:
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PROJECT DESCRIPTION: ~1-. vJ'k<,1t. Ct.lý>d\J-U'P I.-J'V&>~
PROJECT NUMBER:
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TIME
DATE: NAME: CHGD: COMMENTS:
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. DATE:
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BAKERSFIELD FIRE DEPARTMENT
ENVIRONMENTAL SERVICES DIVISION
CONSENT FOR ADMINISTRATIVE INSPECTION
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to ~ f { F\' (Jvv-~ ¿., ~ 41'VYì rLPS
, give my permission
of the Environmental Services
Division of the Bakersfield Fire Department, and others who may assist him/her, to conduct
an inspection of the real property/premises more particularly described below, including
all buildings, rooms, garages, storage spaces, compartments, storage tanks, and any other
container or item found on the premises:
(NUMBER)
(STREET NAME)
(CITY)
(STATE)
(APT/UNIT)
I am consenting to this inspection freely and voluntarily, without force,
threats or promises of any kind. I understand I have the right to refuse to consent _
to the inspection described above and the right to refuse to sign this form.
J:~O'JM
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(DATE)
(TIME)
(FIRE DEPARTMENT OFFICER SIGNATURE)
WITNESSES:
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ZALCO LABORATORIES. INC.
4309 Armour Ave,
Bakersfield, California 93308
(661) 395-0539
Fax (661) 395-3069
Chain of Custody Record
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lalco Lab ~ ðd.Ó ell OD
Ice Chest #
Turnaround Time:
o RUSH By:
o Expedited (1 Week)
o Routine (2 Weeks)
Project Trtle
Field Log #
, Temperature,OC
Work Order #
Compap~ Name o Phone # ~2~. 2'77'1 ---
¡SA K C..f( 5 Ç", GI.-0 ha.é --()~-r' Results ),
Address ;B,.FAX # l-
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Results oj
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City)-&;;.e, Zip I Report Attention /. W/NC:'$ t'( ë <',
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Lab # Sampled by: ' I Employed by: . > (/) (/)
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Date Time Type" Containers Q) 8 8
Legal Sample Description Q: Remarks
Sampled Sampled See Key Below # Type" «(.
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White· Office Copy
Yellow· Lab Copy
Pink - Client Copy
KEY: · G-Glass P-Plastic M-Metal T-Tedlar V-VOA
.. W-Water WIN-Wastewater S-Solid P-Petroleum L-Liquid O-Other
A-Acid, pH<2 (HCI,HN03,H2S04) S-NaOH+ZnAc C-Caustic, pH>10 (NaOH)
NOTE: Samples are discarded 30 days after results are reported unless other arrangements are made,
Hazardous samples will be returned to client or disposed of at client's expense,
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Hazardous Waste Sarnplling
Generai Sampling Instructions:
1 Accurate and precise sampling is v!iai to the goal 01 good analytical results. it¡¡s can not be overemphasiz.ed!
2 A good sample is one that represents the whole of a waste stream.
3 A sampling plan where mumple samples of a waste are analyzed indep<artCÎently can give in1o¡mî:~ioiì as tG the
quaifty of the sampling techniques emd ;5 recommended (see Chapter nine 01 EPA SW-846.)
4 Strátifiecl liquids require special sampling techniques and equipment (eg. ColilJ\!asa tubes orthief samplers.)
5 complete the sampling information and chain of custody on the rever~e sk:ìe at the Ume of the &ëÜ1îpling,
,
Metals Analysis:
32 to 64 oz. Glass or plastic containers
1 Use of acid rinsed or new bottles is required.
2 For water samples, fill the bottle and preserve with nitric acid to a pH of less the 2, cap and label the bottle.
3 For solids and sludges, fill the bottle and do not preserve, cap and labeL
4 Cool the sample to 4° C. (on ice) and deliver to the laboratory.
Organic Chemical Sampling
40 ml VOA Glass vifils:
1 For water samples, overflow the glass sampling bottles, being careful not to introduce air bubbles. Cap the
bottle immediately, Check to make sure there are no air bubbles present by inverting the bottle and seeing if
any bubbles rise. Ifbubbies are present, uncap bottle and repeat this step,
2 For soil or sludges, fill the vial completely with no headspace and cap immediately,
3 Return the sample on ice to the laboratory as soon as possible.
1 qt. or 16 oz. Glass: Bottles:
1 For water samples, ,fill the bottles to within one inch of the top, but do not fill completely. Replace the cap
immediately.
2 For soils or sludges, fill the bottles completely and replace the cap immediately.
3 Return the sample 9n ice to the laboratory as soon as possible.
Bottles needed for TCLP Sampling
Liquids:
One 80 oz. Glass bottle on ice.
Three 1 qt. Glass bottles with no headspace on ice,
If no herbicides or pesticides are required, one of the quart bottles may be omitted,
Solids, sludges and semi-solids:
Three 16 oz. Glass botties, two of them with 110 headspace on ice,
Additional sample may be required if the sample contains more thàn 50% liquid or if tests other than TCLP
requirements are ne,eded,
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OES Number Required
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Cover Sheet
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BAKERSFIELD
CALIFORNIA
Bakersfield Fire Dept.
Office of Environmental Services
1715 Chester Ave. · Bakersfield, CA 93301
FAX No. (66q 326-0576 · Bus No. (:661) 326-3979
Today's Date ~ (~.~~ Time
No. of Pages ~ ()
TO:
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CORRECTION NOTIC.
04876
BAKERSFIEL.C FIRE CEPARTMENT
Location 1 30õ W, ßL£ I<ù
\~6-6'Í ~ "3lk
Name
You are hereby required to make the following
corrections at the above location:
Cor. No.
?C(.-ð.5€ )..(Ävt;;. w~-rE: {NSG<.. T1 C10E
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C>«'T'H~"'6 F' ~é p.¡Jí I'< <"('~ ~~I'1CVC:-O
~/2.0M -r¡.(é ØLIO WAST£: ð::>MfAc..~ AND
?(2..ðP(;P-l-Y í)1~fb560 Ll C&vC.€D
tJ.A."2.A(2.I)OùS uJAs1'£ ~AUc..6'l-
Completion Date for Corrections
c¡ /'1lð~
Date
W/~5
Inspector
326-3951
FD 1950
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Or¢beD1~ID ]I~u'e ADI: KillJII!JI'l
NY IDENTIFICATI(92'i
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IJ'II.oDUCT NAME: Orthcne® Fire- t KllJerl
,!I'UOÞUCT DESCRIPTION: Jnsec icide
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T.:IC ;SOLARIS Group
[of Monsanto Company
p,o, &:( 5008
~~:an jltarnon, CA 94583-0808
J~:,.f'A REiG. NO.: 239~2632 PN: 28202822,2824
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J, C1[lM[][J'I)SIT][ON I INFO
24 HR. EMIE][~~(;~JJ:]~IIC"t(
TELEPHONIg
NUMBERS
Emergency PbQoq=; 800-4:54-233J
ATION ON INGREln:E,NTS
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"h.:~.ln,grOOieÐtslt is a term defmed b the U.S. Environmental P.rot~~U{ ln I\,gCJrlcy lw:u{1,e:t 'Un,:
f"I:cl(:raJ Insecticide, Fungicide, and R ticide Act (40 CFR 158. J 53). It re:fi~rs to any
Slllbsta~cc, '!ther t~ an active ingredi nt, whic~ is intentional!y added to a. pC:stÎcidc: ]~.r;dh~t~:.:
$1(JII1e loot mgrechent$ may be II cbeDllcals, ~ defined by the FederaJ OSHA JHaza:I1:!
'Communication Startdard (29 CFR 19 1200). The hazards associatl~d with these i.rIf~rt
í,r:lumdic:nts have been included în this ocu:ment.
4C:!!!~D.dc;!!j J~;¡UDe
At;.~hat.:
n~ ERT INGREDIENTS
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1. ]¡~¡AJ~~\FlDS IDENTIFIC
IE~:MERCæ:NCY OVERVIEW
Wt,,%. 1~;M1¡~11
SO 31~515(~·1'9" I
~·'50.0
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~PHVSICAL APPEARANC : White powder with a strong cBbbag~··líke 01' rr.\(:.¡~mpIH\
typc~ odor_
rM)V [EDIA TE CONCERNS: HARMFUL IF SWALLOWED
.' CAUSES EYE IRRITATION
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- AVOID CONTACT WITH E ES. SKIN OR CLOTHING
-AVOID BREATIUNGDVS OR SPRAY MIST
~ KEEP OUT OF REACH OF HILDREN
POTENTIAL HEAL m EFFE
EYES; This subst.anœ is sligh y ilTÍtating to the eyes.
SI<JN ~ This substHnce is not ex teet to cause prolonged or ei¡gnificant ~:kil) ílti1~:LlJi( n, If
abwrlbed thrm.lgh the skin. this ubstanœ is considered pmcticalBy DOn-·CO:ICÌ(; IX) iín'l:E~' rljil
organs.
BNGESTION: This substanee 5Üghtly toxic to internal organs ifs''\/a.IJI, OWf ( Sl::>~
T o:"jœlogy Infonnation. sectìo 11.
INHfALA TION: Jfinhaled. th s substançe is considered practlcaJl!y non-to;l(,ilc tel
int ~rnal organ!. This substance ay be irritating if inhaled.
SJl,GNS AND SYMPTOMS OF VEREXPOSURE
EYES; May include discomfort tearing, swelting. redness. and! blurred visiøn,
IN'f-ú\LA TION: Respiratory t irritation may include, but may no' be: IÎmø.lic:d t(l" lJ:m~
or more of the foJlowing; nasa! isc;harge, sore throat,. cOUfþ1ng, bronchitis, j;: \.d1JMlrL:II'~1
edem~t and difficulty in brea .
ACUTE EFFECTS: REPR DUCTION AND BIRTH DEFECTS:
ACI:pbate caused pre- and pos } growth retardation. and dec:r~ the Ih¡ebt;1D111litJiIH
size:, when adn1Ïl}jstcred to pre t and/or ]actatåD.g rats at ma.ternally COX LC dl~iC~; (ru:1
effEiCts at 2.5 mgl),:glday). No ad erse effects oocured to thi~ offspring of pl:-egr:IRl1t ;l'abhil!;
dosed at up to 10 mglkglday.
SlJJJCH1RONlCICHlRONIC TO
CHRONIC: Acephate incrcas ' the inddence of liver tumors in high dO:!íe ¡¡¡¡:Nlp
femllle mice, Acephate was not inogenic in male mice, or rats, whe.n tl~:stl~diIllw(l,·
year f~:eding studies.
TARGET ORGANS: Aceph te is an inbibilor of the cholincst.<:rase ef.lzytI!e,. f{m~d !l:1
.ncrvous tissuc, red blood cells. d plasma.
,COMMENTS HEAL 1H: pending upon the extent and degree of (Jive:!,(~,,:pO~j1m: ~;I
'[he product, signs and symptoms of cholinesterase inhibition CMl resuh fonowÌin(: Óthl~ '
;ing~~stion. skin contact or ìnba1 routes of exposure. Sia:PllS 8lì.d $ymptOm5 of .
I:ho:tines:terasc: inhibition can re h ftom either acute (one time), su1!>cht'onÎ:c (n:p~:¡¡ul.ed
~¡¡hoJ~t-term) and chronic (daily Ii -time) overexposure to the produd
:;i.gns and symptomS of cholines,' inhibitioR usœUy occur ~n.thin 11 bour¡¡ :íbUowir¡;:
i)VCI:expOSU1'è. These effects may' lude" but may not be liJIJIÙtedl to. hetldal::hl~. dìz,::ir:I::~I:),
wealmeS$. nausea. \lomiting. d' hea, constriction of the pupil of the e:ye, bh:!r.re:d Œ!' di ~1:
'lis.tlm, cx.ce5si"c sali\'a.lion or 1 discharge, profuse sweating ànd a.bdomimll c:mrrl]f':I.
[nC(.ntìitlence, uncon8c¡ousnes~ ç nvuJsions and breathing difficulties ¡lIrC ündÌ<;a:thN: ,]d'
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se"ere poisoning. In untrealed vere poìsonìng, dettth is due to respiratory J:ailr~JIf: '~'J'
cardiac arrest,
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" ~I, F]LI~tST AID MEASURES
I:YES: FI...,h eyes immediateJ wi1h frtsb water for at lenst 15 minut(:s while tK)1dt:lIg:
the eyelids open. Remove conta t lenses llworn. No additional fir:;1 aid 31~tou]d bl~
necessary. f{owe,,'et', i:fín:itation persists. see a dtJt:tor.
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SIUN: No fus, aid procedures
soap and watcr_ Remove and
œquìmi, As a pre<: aut ion. wash skilO thoJ:tJ~uJ~~tIJ' wilh
h contaminated clothing-
INIGESTION: If!ii\WUowecf, 'vea large quø.ntity ofw3ler tu dri~ ITl.8ilœ pemön.
VQm.it and call a doctor. Never g e anything by mouth to ~1iJ. um:onsciau, :þe~rsOIl.
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INHALATION: Ifrespirato discooûort {}r irritation ()IX~S. move 'Iht~ pl~son :;0
ftesh a:iT. See a doctor jf discom rt or immrion cOD1in~.
r\lcnrES 1'0 PHYSICIAN:
Mea~u.remelIt of blood choJine
signs and/or s.ymptoms ßf (,holin
2-P,I\M (pROTOP AM] .is aJso
'Ilt sb ~uld oot be used alone.
is material contains a choliru~sterase inltibi¡:oi:.
activity ~y be uself\l1 in r.rt() 1itor1iI)~: e:1Cß)(I!;t¡U!~:t, jl f
terase inhibition appear, atropinf~ sl111få.tm iEi ultjl:!()I~11.
'doœJ 8J1d may be used in conjunctir)fl w:itll. ¡!tI'OJpirø:
:: .
JON: In case of medica1 emc.1gd~ciE!~ in\l'alvrßJ: thi:;
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:L FI[]I;t:I~ F][GHTING MEAS
]~XI'lNGUISHnNG MED
: C02, dry cbemical. foam and water rot!:.
I~A:z.ARDOlJS COMBUS
(;arb on ltioxi<ie, water vapor and
phOliphorous. Inoomplete comb
ON PRODUCTS: No:nnal 'C'Otnbl~;ti( 11I ¡Femls
y produce ox.ide5 of 5dful, i1itl'oge.n aIId
ion can produce carbon ß1onoxid.;:.
llfllRE FIGHTING PRO URES: Products of cO.Q'tbœtioo fÌ'On1 fire!> i:awob/rli.~:
this material may be toxic. Avoid breathìng smoke and mists.. Av( id pcrso![md a:i1.tc1
c:qulpment contact with faHout runoffM.inimize the: amoUhl tx!Wall;:f used ~;.r liir=~
fig, hlting Do not enter any enclos d area without full protc:c1i \Ie equi.pment,' iD>cJlud:Îng
s,c}f·contained breathing equipme t. Contain and holate nmoff 31!'ld debris :lor ¡:1l'1:~fJ~:r
disp;)SaL Decontaminate persona.l protective equipment and. fife figbting C( UipIIJI:nJ
before ~use. Read the entire doc ment.
11ILASHPOINT: Decomposes bove 3OOf.
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II A,C{]OENTAL RELEAS
MEASURES
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S~[Al.L SPILL: Sweep up eriaJ and place in disposable I:orntainl:r. DiS]J( sc.~ (11f i::"
accordance with instructions in ection 13. "DJSPOSAL".
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LARGE SPILL:CIcan up sp Us immedìately, observing precautions jJ)l E;~~>su rt:
Controls! Personal Protection se don. Vacuum with machines et~i1Ì:ppedl With hiltb.
efficiency fi1te:rs or sweep up ma erial and place in a disposable comainer. &:r:Ulb
contaminated.a1'ea with detergen and. water using a stiffJbr.\3orn. Pick 1q:1 UqujidI '¡~itl1 0 [I
DQ', CaI: Jitter, clay, rags or other absorbent and place in a óbìs p0!'3.bKe cont::linl;::t', :tJiJ':JI)~I!:(:
afin a.œordAncewith lnstrUctiO in Section 13. "DiSPOSAL".
HIE:NERAL PROCEDURE : ObseJVe an protection and sufety pn~~I.utjìtJln~i !Jli):'!:1
cI~LC:iII1g up spills ~- see Section . -EXPOSURE CONTRCÞLSlPERSONAL
PR01BCTlON". For help with ,. spH1, leak. fire or exposure involving thftf:1 ItJlJtI:dll,
~J day or night (gOO) 225-2883
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t :mA.t'H)l,ING AND STO
GENERAL 'PROCEDURE : Keep pesticide ìn origir.œ.] cOl1tBiner. A'/oi.d,
coo:aminatioll of feed and foodst. frs. S10re ina secure cool, dry place.
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Ii I )¡~,~~;:P'()SURE CONTROL I PERSONAL PROTECTI(lr~f
IE:ì!~ GJ[N]ŒR(NG CONTROLS: 0 special \ienti1atioo is us~all~' necessary. HO'\ill~~I!~r, iJ
.)PI~t\rtJ.ng :IOl1ditions create high ailbo e concentrations of this tn,ateriøl. ~~:i;a¡ ventiJlttic'l!]
1UP'.~1 bt~ needed,
:f']f~lflSor~AL PROTECTION
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EYIES AND fACE: For appl' 'on of product in accarWU1ce wìtlh labe,l jÌß!jÒ1J,:tio:r,!I,.
110 special eye protection i~ need
H:~d1ing of the product is.11Ot lik Iy to present an eye exposure oonœm dUrlIlg Ilm'ln~lI
Ju~ndJing. In the even1 of an accid tal discharge of the roatuial d,W1ÏD8 marJuhu:tlU'J:' l)r
hand.ling which could caUSe eye ntal;t~ workers should wemr go¡ggles 01' Ii fac::c e~hif:·I,[1.
SKJN= Wear protective c]olhing hen bandJing Of applying: this pwdwr.1 iDÞchIdÌl'~ß Ik~r.: !
pants> lQrJg ,'~ved shirt, socks, s 5. and chemizaJ resis1af1t glt)'lfe$. Wí!lSb
Il.Ondi.¡p()sable gloves throughJy 'rb soap and water befun::romovilllg. Rtmo,'e
c:ontm:ninaled clothing IlI\.d laund separately bc=fure reuse. PJI'ompdy and tbro1JJp ])" w~l:ih
han,:s rUJd exposed skin with soa and water after using this prodl~n.
RJESP][RA TORY: No s~ciaJ "rato.ry pro1ecUorn:is nonnally rfl:(UÜ"f:d, How :'JI~r" JJI'
<;rperatmg condì1ions create airbo c:onccntmt1ons wbicl1 ~'tceed th~!: re"~onunl~ltdc~d
.expcJ·SIJf~ srandaros, the use of aD pproved respirator is required.
O~!!,lmA HA:URDOUS COMPO
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~HA PEL ACG~flLJ'1L V A~I~~,~J~[ ~mlH"
None None None
None '3 mß¡'m3 NOtle
None None :l\1clnte
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CAL PROPER1rlJES
APPEARANCE: White powd with a stro1'18 cabbage·Jike UJ: l11erca:pÙID-!!YP'~' c·dt) '
liB: No Data Available
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V A]flOR DENSITY: No data vl.ÚJable
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SOI..UBILITY IN WATER: Soluble
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nENSITY: Bu1k Density = 181 .leu ft.
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STABLE: YES
HAZARDOUS POL YMERlZA
C::~ONDITIONS TO A VOID: Avoid contact with alkaline mate1:ia.h
EIAZARDOUS DECOMPO ITION: Contact with alkaIiJ1~~ material'l ind1lldilJlg
hYPO~hlorine oxidants, may produ e noxious gases.
Il~COMPA TJrBLE MATE ALS: Reacts with bases or strong OJddt.~:it1g ag,enn:,.
SlIch!lS chlorates, nitrates. peroxì 5, etc_
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A'CUTE
EYES: Corneal involvement an irritation clearing in 7 days or less.
DERMAL LD oO: Mild to s1ight irritation at 72 hours. 'Ib(: dea.oal LD:50 ÌJJ1 raIJbfl~:5: i:¡
greater than 10 gtkg.
ORA L LD~: The oral LDSO in ts is 1494 mglkg.
INHALATION LC~o: The )-h ur inhalation LCSO ín rats is gre.ucr than 111!i:lg/L
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: ~ !~.. .I~:~C ~)L 3(';ICAL INFO
J~N'VIRONMENT AL DA T
~.__'_I"'_I._'alm.alll..,.,."
nON
ICCOTOXICOLOGICAL FORMATION: This pesticìdle i~, £mlÍc to ÓiJ,d!l, Do
t1,ot elpply directly to water. Do n t contamìnate water by cleaning of equipment m
disp')F.I!11 of wastes. This product' highly toxic 10 bees exposed to dirœt tl'eatml=n1: '~'J'
r,e8id,ues on blooming crops or weds. Do pot allow tivestQCk to grau on 1:reoated é'Ll1i:;)!,
Do r.ot feed treated grass 10 lives k.
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I~OR LARGE SPILLS: Ma rial collèC:ted that cannot be reprocessed shouù,cll:Þf:
d¡sposed of in alandtiH approved for pesticide disposal or in accordanc,~ with applkaì:JII:
Federal, State or local procedures
]f·RODUCT DISPOSAL: T Solaris Group is çommitted to reSJPullsiblt:
c,l1vj '()nmenta) practices and reco mends that all of the product be used up, (:é!n:fu¡[]v
f~)Uowing aJllabcl dirc:~1ions and reçautions. .
If no::essary to dispose of panlall filled product container. then securdy WnlJP il: ¡IiI
s.=verallayers of newspaper and scard in trash.
E:M:JPTY CONTAINER: Do ot reuse empty container. Di!;(:ard COl1ltai,nl:T iill ml~:kl,
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I'· ': Tjft!~~:~rSJPORT INFO
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PROPER SBJIPJPING N
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TION
SPORTATION)
: Not Applicable
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)1t]iUMlARY HAZARD CL SJDMSION: None
IJN/NA NUMBER: NONE
IJACKING GROUP: NO
s]f1»I~CIAL SHIPPING NO ES: The descriptiQn shml\'I1 may oot íilppl)' to nil
shipping situations, Consult 49C R. or appropriate Dang~us Goods J{e~~lati )nc!¡. (ilt
~idditional descriptíon requireme 15 (e.g., technical name) and mode-speclfir.: 11;11: qu~mlj"~I'"
~:pedfic shipping requírements.
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H:;;. RJE~ GUl..ATORY INFO
UNìl1l'EIJI STATES
!;¡!\ÆtJ~ TITLE In (SUPERF
'U~A1Jl18[ORJZATION ACT)
~S
CARCINOGEN: Acephab:: [
STATJ£ REGULA T]ONS
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GENERATI:NCI~ : NO
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S Can;inogen Assessment is: C
IPRO][)OSITION 65 STAT
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I: \' Ir~b,']"I[ER INFORMATI
"I,Þ. IrP " .
¡.mUIS CODES
1FJIRE: 1 HEALTH: 1 REACT VITY: 0 PROTECTION: -
NF!I~A CODES
:FIRE: 1 HEALTH: I REAC VITY: 0 SPECW,.: -
APIPROVAL DATE: 05/19/ 000
REVISION SUMMARY N w MSDS
COMlMENTS: For additional information concerning tills product, call1tþ: :~OU\,J~~I:::¡
Groups Consumer Hclp1ine at 8 0-225-2883.
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r.IASUF ACTURER DISC MER: This Material Saf(¡:ty Data Sh,~t (l',!SICI::::'!
~)nuLÍns health, safety and enviro ental information for you. and. ~'ou.'I' ernp1IoY'I>eS. It
does not replace the precaution language, use directions" or the storage ,and d.í5lJI(J:;il~,
iJlformation found on the product label. Information contained in thJs MSÐS will h~~I~1'
you to prepare for emergency Te nsc and to meet community I'ight-to,· ol.ow,
emelgency regponse and reportin requirernents under SARA Title HI and. man]' otlH:I'
l:lW!I. Emergency response agenc ai1d health cæe providers wñl1 aho6nrd uhi~,
addillional infonnatioo useful.
'Use of this product is: regulated b the U.S. Environmental protc:ction A$"!!nC:,Y (EŒ'I\)
thro'1ßh the approved label copy. It is a '\IiolatioD of Federal law to ll15L~ thi:!í produ.4~t in !L
manner inconsistent with its lab(! ing.
ABtho\l.gh the ínfonnation and re om.mcndations set fortb. blerein. (herinnJro::r
"Information") are presented in od faith and believed to be correct as. ofthe dute
ltere:<>f. MonsantQ Company and Solaris Group make no represefiilæiC!flf! lIS 1t( tt~:~
l~oŒlpJeteness or accuracy thereo . lnfonmttiOJ1 is S\Jpplied upm1 the ccmdi1ti(m t11811]u
!~~.on.s receiving same will m their own determínatioD5 as to Ì1ts su:i1ibiHty (eif tnil~il
purpO!leeS priQr to us~. In no ev t will Monsanto CompatlY 01' Tne SQ11uris Gm1.1p h:
re!.1lOtdsíble for damages of any ture whatsoever resulting ftom the use I:>f or n~l¡M ::~~
upon Information. NO REPRES T A TIONS OR W ARRANTIES, l~rnœR ;1~XP1~~,mìS
OR IMPL1ED, OF MERCHAN ABlLITY~ FITNESS FOR A :PARTltCULAR
PlJifl.POSE OR OF ANY OTH NATURE ARE MADE WITH RESPECT Tn
n..¡¡:üRMATION OR TIlE PR1 DUCT TO WHICH JNIFOR,MATION REFEJI;:S,
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ZALCO LABORATORIES. INC.
Analytical & Consulting Services
4309 Armour Avenue
Bakei~field. California 93308-4573
. (p6: l'395,-q5~'~ ' ,"
Page Number: l'
Contract Number:
Delivery Group:
Received:
, '. p aypten t pue:
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09/09l°? "
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Bakersfield Fire Dept.
2101 H Street
Bakersfield, CA 93301
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At.tn:Howard,H. Wines'
Bakersfield Fire Department
1715 Chester Avenue
Bakersfield, CA 93301
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ZALCO W.O. #
0209100
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Ship Date
09123/02,
F,o.a.
'Jnv. ,Date
09/'23/'02
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Description
. Unit
, Price.
.. Amqunt .
"".! .
. $237,.00,
$5.0,Q . .
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$237.'00 .
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Invoice Amount:
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ZalcoPrice. Ð.ook;Effecti,ÿ¡e',:1..l,ì)02.:.;.Tha1'Ùt, 'YoufoI" :yourbu~ÜnesÆ?'
Please Visit Us At http://www.zalcolabs.com
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ZALco4lAeORATORIES, IN_ e
Analytical & Consulting Services'
4309 Armour Avenue
Bakersfield, California 93308
(661 J 395-0539
FAX [661J 395-3069
Bakersfield Fire Department
1715 Chester Avenue
Bakersfield, CA 93301
Attention: Howard H. Wines
Sample Type:
Solid
. -__'_.' _ ___-.._-~_.......,...c-~_~~___________==::~_.,.... ___._0_
Target, Ortho Fire Ant Killer
Sampled by H. Wines
_~____~_<____-..::.. ~,---:o~....=.........- '~_~__--":'--._____.-,-_--,,::",<:"..~~_ -----
Description:
Constituents
Laboratory No:
Date Received:
Date Reported:
Contract No.
Date Sampled
Time Sampled
REPORT OF ANALYTICAL RESULTS
Results
Units
DLR
0209100-1
09/09/02
09/20/02
09/09/02
14:30
Method/Ref
·'LC50
,.,Aquatic Toxi,city LC50
--- __~ ~ ._ _r ~_
> 750
- -_. ..- --,~------ .'--
Date Analyzed: 09/20/02
cc:
Method Reference
4, Caf1f?rnia De~art~~~~ ,?f Fish and Game
.mg/~
. 'I.
~ -------.---
ERW
;Î
DLR
mg/kg
mg/l
ND
NSS
,400
/4
Detection Limit for Reporting Pur
milligrams per kilogram (parts per million)
millig'ram per liter (parts per million) ,.',
None Detected
Not-Sufficient Sample
This report is furnished for the exclusive use of our Customer and applies only to the samples tested, Zako is not responsible for report alteration or detachment,
ZALC04b.ORATORIES, IN. e
Analytical & Consulting Services
4309 Armour Avenue
Bakersfield, California 93308
(661) 395-0539
FAX (661) 395-3069
SAMPLE BIOASSAY INFORMATION
Lnb #:OZ,l.q, Of.) -- \
[X].3510 Aq uatic To>.:icity, 96-hour LCso
Test Type: Screenin~ Flow: Static Tank Volume: 10 liters
Aeration: Sin!:de Bubble Aeration in all tanks Acclimation Temp: 20 C ( .'
Sonicator: Output control: 1.Q Duty Cycle: 50% Cycle Time: I minute Shaker: Time: \Qh. Ý> Container:
-- ___Organism:_ .Zlth,ead min~ . .' . Species::PimeDhalesoromelas_" _ H.Source: -Thomas.F-isn.Cc.----=--=--
Carrier: (\ . j¡¿, 'í..S! Date Rec'd: 'R/'~ì;/¡)'~ Avg.Length: 3.3 mm
pH adjustment require : [ J Yes þ4'No (se~ pH co~trol workSheet) Avg. Weight: 0,52-- g
Methanol carrier solvent required: [ J Yes ¡(J No (see MeOH control work sheet)
No. Organisms/cone: 1.Q . Dilution Water: Reconstituted Fresh Water
Hardness Alkalinity EC,
as CaCO¡. mgll as CaCO¡, mg/I mmho/cm @ 25c
Oil ution Water ' ¡::::' ,,75 \'1-0
li' ->
Initial Control }..i~ -::ç';' I =to
Fin al Control J{í-~ 3"i l-=t5
Initial Sample 45 3J-~ \ -;:¡ 5
Fin al Sample ,:.{- 3\ i~1
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Initinl 2<1 HI' 48 HI' 72 HI' 96 HI'
Date: <=\/\ i(¡f if.~ 'VI -:'t"/ U'........ ~\/{ ~;I ;'!.L- '1 /¡ <-..1 ? c ") I
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Time: V~ i-t5 \55D \355 13+0 \o/~..5
00 c: ,11 00 c: ,H /11 DO c: ,11 //1 00 , ,II /11 00 , ,11 1M
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Co'ntrol # ;;)\,0 -:::¡',4 Ó 1" :2U~\ I JI,I~ ,e- [ì,(,;: "+ ~ '6.~ 70:+ '1.':> .e-
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400 nig/I ~'=\ dùt.i -4-,0 .,.~ ¡,lp ~J; -è I~.i.\ 1-:~ +- ~A 1-.4 ..@- <¿,~ ¡ül
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400 mg/I ~,~ ,;;).1,4 1:.0 fo;ç Ji,l" :lS {} <; I::' 2-\.h HS Ð - ~' J¡,\¡; i< .e- if' ZíH ~: )..~ -ê-
[tJ O· " (í'"ì . ~) ~ .\.
750 mg/I "6. =i k';J.ì,4 lç.<6 1~.4 "j r.: :1:1+ f)- tA 'Z~~':;' M Jí}. ~+ '7..1.7 1-.4 -% ?-t 'oS -, e
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<'J1o ;:21 A b.1 'Dr, . ,{ .t.p l.t e ~h 2:V~ ,A .9- " If 2iS )' .~ ~<.~ 20,( =1:2. .e-
150 mg/l Ö. .,
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Date:
This report ;s furnished for the exclusive use of our Customer ond applies only to the sample~ tested, Zaleo is not responsible for report alteration or detachment,
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~ ZALCO LABORATORIES. INC.
4309 Armour Ave,
Bakersfield. California 9330B .
(661) 395-0539
Fax (661) 395-3069
Chain of Custody Record
TAv<G6r
ï :1'209100
,',
Turnaround Time:
o RUSH By:
o Expedited (1 Week)
o Routine (2 Weeks)
pageiof,d
Zalco Lab # C) Ó q I (J()
Project Trtle
Field Log #
Ice Chest #
. Temperature,oC
Work Order #
Compa~ame
(~A KC-f2 5 Ç', C-7..-0
Ma.E 't)Ef'-r
~ .300
o Phone #
Results
FAX #
Results
32b~ 3.'771
3'2..6 - os 7.6
WtNC-S
ANALYSES REQUIRED
Time Type"
Sampled See Key Below
Legal Sample Description
Containers
# Type>
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Address
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City~tate. Zip
fSAlt:..Ø-SFIL.ï..D,CA <7130 I
LA Sampled by: {
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Report Attention J I
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Employed by: ß F D
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'r NOTE: Samples are discarded 30 days after results are reported unless other arrangements are made,
:, Hazardous samples will. be returned to client or disposed of at client's expense,
White - Office Copy Yellow - lab Copy Pink - Client Copy
KEY: > G-Glass P-Plastic M-Metal T-Tedlar V-VOA
.. W-Water WW-Wastewater S-Solid p-petroleum L-Liquid O-Other
- A-Acid, pH<2 (HCI,HN03,H2S04) S-NaOH+ZnAc C-Caustic, pH>10 (NaOH)
ee e.
Hazardous Waste Sampling
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General Sampling '.nstructions:
1 Accurate and precise sampling,is vital to the goal of good analytical results. This can not be overemphasized!
2 A good sample is o~e that represents the whole of a waste stream.
3 A sampling plan where multiple samples of a waste are analyzed independently can give information as to the
quality of the sampling techniques and is recommended (see Chapter nine of EPA SW-846.)
.4 Stratified liquids require speci~1 sampling techniques and equipment (eg. Coliwasa tubes or thief samplers.)
5 Please complete the' sampling information and chain of custody on the reverse side at the time of the sampling.
Metals Analysis
32 to 64 oz. Glass or plastic containers
1 Use of acid rinsed or new bottles is required.
2 For water samples, fill the bottle and preServe with nitric acid to a pH of less the 2, cap and label the bottle.
3 For solids and s!udges, ,fill the ,bottle and do not preserve, cap and label.
4 Cool the sample to 4° C. (on ice) and deliver to the laboratory.
Organic Chemical Sampling
40 ml VOA Glass vials:
1 For water samples, overflow the glass sampling bottles, being careful not to introduce air bubbles. Cap the
bottle immediately. Check to make sure there are no air bubbles present by inverting the bottle and seeing if
any bubbles rise. If bubbles are present, uncap bottle and repeat this step. '
2 For soil or sludges, fill the vial completely with no headspace and cap immediately.
3 Return the sample on ice to the laboratory as soon as possible,
1 qt. or 16 oz. Glass BQttles:
1 For water samples, fill the bottles to within one inch of the top, but do not fill completely, Replace.thecap
immediately.
2 For soils or sludges, fill the bottles completely and replace the cap immediately.
3 Return the sample on ice to the laboratory as soon as possible.
Bottles needed for TCLP Sampling
Liquids:
One 80 oz. Glass bottle on ice.
Three 1 qt. Glass bottles with no headspace on ice.
If no herbicides or pesticides are required, one of the quart bottles may be omitted.
Solids, sludges and semi-solids:
Three 16 oz. Glass bottles, two of them with no headspace on ice.
Additional sample may be required if the sample contains more thàn 50% liquid or if tests other than TCLP
requirements are needed.
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