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HomeMy WebLinkAboutBUSINESS PLAN Operil.te to it Per Waste Unified Permit Materials/Hazardous Hazardous CONDITIONS OF PERMIT ON REVERSE SIDE i i1iú 61! Hazardous Materials Plan o Underground Storage of Hazardous Materials o Risk Management Program o Hazardous Waste On-Site Treatment :Ii };" ~.. l " Permit 10 #:: 015-000-001278 UNIVERSAL RADIOGRAPH LOCATION: 419 WATTS DR ...' :1.' ~. l t Approved by: Date Issue Expiration Date: Bakersfield Fire Department OFFICE OF ENVIR ONMENT AL SER VICES 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 Voice (661) 326-3979 FAX (661) 326-0576 Issued by: PerDlit to Operate Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE This ermit is issued for the t:'J,;Eardous Materials Plan _·'''''·~[9rOund Storage of Hazardous Materials ;)1/IJQagement Program ';, . ." . Waste followin PERMIT ID# 015-021.001278 UNIVERSAL RADIOGRAPHIC WATTS 419 LOCATION Approved by: Expiration Date: Bakersfield Fire Department OFFICE OF ENVIRONMENTAL SER VICES 1715 Chester Ave., 3rd Floor Bakersfield. CA 93301 Voice (805) 326-3979 FAX (805)326-0576 Issued by: /' r (~~z-~ . ' i' " Ii~.. '.' , .. ,. .. .TE:,"":5" A'-:; L =-- T T""'[ FO R.;Vr 5 --- i/~":l/t{TS- O~ JI (;lIt? / ItlSp 5 t N \'!n¡)"'~"T .',\ J~ t ..;. (" (~iE~I{ n:\TF ,} <;''''~ _ _." L-i f JT.1.G0'.':'J: t)::J 115 D¡^ ì v t' 41q :Lcbll-s {\ -¡..'a{~'~ OFP/~e\ .-J 'Oflì« Dç(i.~C ~. "'..:. .' ..t , ' bpr,ée .. OFf!æ \ DF¡<íù ~+DÝ'-~( rt, s~, ~ -. ~:-T..OC? . T .,.. -..... 953.D/~' :-,~.c ~ L ~ ~'.' J T AC:i\:i: ~ ~tL- Re..st -Pcttn J- "J :> v, v .v v oc:...~. ~ 1/h~A-o ~ r Che,r'M~ ~ .¡ CJ.. z :, <;-/¡p~~e, ! " ð U ~ ,..... ¿ (T I1St)L.I("'TO't""t ¡... ,"", , .. " ~_ '" " c ~, ,..0 mI'! P !' f-" i ' . , .. \~.-J I ' ') ~ ~ ~ \Q ~ ~ ~ .:'\ ;....,. ----- .' . 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" í-/(Wif) . t"j118'7· t./{;wo I ~Clfbí) ~ ~qß' rJ50 ~ . -- UNIVERSAL RADIOGRAPHICS INC Manager : JeY'I""'i/L, {;P~A¿7h Location: 419 WATTS DR City BAKERSFIELD SiteID: 215-000-001278 VI jJ .; BusPhone: Map : 124 Grid: 08C (661) 398-0568 CommHaz : Moderate FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 05 EPA Numb: SIC Code:3844 DunnBrad: Emergency Contact / Title Emergency Contact / Title JOHN SHEA / PRESIDENT JIM RODGERS / TREASURER Business Phone: (805) 398-0568x Business Phone: (805) 398-0568x 24-Hour Phone : (805) 397-5655x 24-Hour Phone : (805) 397-5591x Pager Phone : ( ) - x Pager Phone : ( ) - x Hazmat Hazards: RSs Fire React ImmHlth Contact : Phone: (661) 398-0568x MailAddr: 419 WATTS DR State: CA City : BAKERSFIELD Zip : 93307 " Owner JERRY GOLLEHON I ' , Phone: (661) 398-0568x , ¡ :,1,', Address : 4301 ADELL CT ;/ State: CA Lip City : BAKERSFIELD l 0 ') t: r~ Zip : 93313 - ;,":; // Period : to TotalASTs: = Gal Preparer: TotalUSTs: = Gal Certif'd: RSs: Yes Emergency Directives: One Unified List ì All Materials at Site ì f= Hazmat Inventory f== MCP+DailyMax Order Hazmat Common Name... SpecHaz EPA Hazards DailyMax MCP FIXER PART A DEVELOPER PART A DEVELOPER PART C FIXER PART B DEVELOPER PART B / ~, vt"l"J1 b¿, V~ or prii'lt Mnt:) reviswsd ~ha SltlSlChs©1 tðaæ~mOO$ ml§l~®úi(illl~ mar:ag®~ men~ plein 10r a~~~ ~vJ~hSl~ ¡~ a~~m~ w¡~~ any oou'ij'@di@ú1~ ©©n5m~~® ~ oomp~~~ ®n©1 ©(;}IT(§Jdl m®.fi)- R IH L R IH L R IH L /) R IH , L j ) rr F R IH L /It [)© ~@Ii®[g)1? OOM~ ~ÛiJ~ft ~ ÛiJ®~¡g 397.00 GAL 352.00 GAL 11.00 GAL 25.00 GAL 16.00 GAL Hi Hi Mod Low Low a~emSí1~ pl~81 ~(Q)r m1? ~~m~. ( t 12/21/1999 It \ cusr.e & NO. ES- 33(<)3 - - - MISCELLANEOUS RECEIVABLES ADJUSTMENT DATE3-/G -Ð NEW ACCOUNT 1 ADDRESS CHANGE CLOSE ACCT I : FINANCE CHARGE . OTHER ADJ I CUSTOMER NAME ~; Ve.I-xJ eo.d¡Oj(4-r\';C:::> ::r:nc...., MAILING ADDRESS P.b~ ßO'i L\CJOr n C/lY Qhí":>~¡ e kJ, STATE ('A ZIP CODEq~'ðtf SITE ADDRESS· L\lC\ l~~ OV---· PARCEL NUMBER (lFAPPUCABlE) ADJUSTMENT R~Af~S:b~; ~ ~ùr~~~ ~OJcÁ'if~ APPROVED BY ~ø~/ £ersfield Fire Dept. . ACUTELY HAZARDOUS MATERIALS REGISTRATION AND RISK MANAGEMENT AND PREVENTION PROGRAM CHECK LIST 1. A.H.M. REQUESTED S "' ;}II ~<\ I 2. A.H.M. RECEIVED 3. R.M.P.P.REQUESTED 4. R.M.P.P.REVIEWED 5. R.M.P.P.APPROVED 6. R.M.P.P.INSPECTION COMMENTS: Un;vU.Ar.¡ß M~~cð BUSINESS N # I'd- 76 I.DHUMBER · . CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT D. S. NEEDHAM FIRE CHIEF May 21, 1991 2101 H STREET BAKERSFIELD, 93301 326-3911 Mr., Jim Rogers Universal Radiographics ,419 Watts Dr. "Bakersfield, CA 93307 -.-. ~ -.- ~...-'~-- Dear Mr. Rogers, The enclosed "Acutely Hazardous Materials Registration Form" must . be completed by any business, handling above the minimum reporting quantity of any material on the EPA list of Extremely Hazardous Substances. (Fed. Register Vol. 52,' No 77, P. 13397). Your company has reported handling the following Acutely Hazardous Materials: 325 GAL, 4% HYDROQUINONE (DEVELOPER PART A) The enclosed Facility Information Form must also be completed. Please return the completed Acutely Hazardous Materials Registration Form and Facility Risk Index by June 21, 1991 to: Bakersfield City Fire Department Hazardous Materials Division 2130 G Street Bakersfield, Ca. 93301 The Facility Risk Index is designed to distinguish those facilities that use acutely hazardous materials in chemical processes from those who are involved in limited processes or storage. If you have any questions, please call Barbara Brenner at 326-3979. Sincerely Yours, Barbara Brenner Hazardous Material Planning Technician ,-~--.,::. .¡, . i7-;27-CfO . of-- fY v ~~'-1 -1'" JUNE ..,.., i...' 7 199Ø DEAR MR. RODGERS, NOTICE OF VIOLATION AND SCHEDULE FOR COMPLIANCE ==~============================================ IN THE INSPECTION OF YOUR BUSINESS UNIVERSAL RADIOGRAPHICS LOCATED AT 419 WATTS STREET, BAKERSFIELD, CA 93307 ON JUNE 27, 1990 THE FOLLO(~IN6 HAZARDOUS MATERIALS REGULATION VIOLATIONS WERE IDENTIFIED: 1. HAZARDOUS MATERIALS MANAGEMENT PLANS MUST BE REVIEWED AND UPDATED EVERY TWO YEARS. VIOLATION OF CH. 6.95 CALIFORNIA HEALTH AND SAFETY CODE SEC.Z5S0S (b) In addition to the require~ents of Section 25510, whenever a substantial change in the handler's operations occurs which requires a ~odification of its business plan, the handler shall 5ub~it a copy of the plan revision to the ad~inistering agency within 30 days of the operational change. "' <c} The handler shall, in any case, review the business plan, subMitted pursuant to subdivisions (a) and (b), on or before January 1, 1988, and at least once every two years thereafter, to deterMine if a revision is needed and shall certify to the adMinistering agency that the review was Made and that any necessary changes were ~ade to the plan, A copy of these changes shall be subMitted to the adMinistering agency as part of this certification. Cd) Unless exeMpted froM the business plan requireMents under this chapter, any business which handles a hazardous Material shall annually subMit a cOMpleted inventory forM to the adMinistering agency of the county or city in which the business is located. Notwithstanding any other provisions of the law, an inventory forM shall be filed on or before January 1, 1988, for the 1988 calendar year, and annually thereafter. This inventory shall be filed annually, notwithstanding the review requireMents of subdivision < c } . ........¡;. .:... ~-.. . . 2. HAZARDOUS MATERIALS INVENTORY MUST BE COMPLETE AND ACCURATE. VIOLATION OF CH. 6.96 CALIFORNIA HEALTH & SAFETY CODE 25S0S(A)( 1-4) The annual invento~y forM shall include, but shall not be liMited to, inforMation on all of the following which are handled in quantities equal to or greater than the quantities specified in subdivision (a) of Section 25503.5: ( 1 ) A listing of the cheMical naMe and COMMon naMes of every hazardous substance or cheMical product handled by the business. (2) The category of waste, including the general cheMical and Mineral cOMposition of the waste listed by probable MaxiMUM and MiniMUM concentrations, of every hazardous waste handled by the bU5iness. (3) A listing of the cheMical naMe and COMMon naMes of every other hazardous Material or Mixture containing a hazardous Material handled by the business which is not otherwise listed pursuant to paragraph (1) or (2). (4) The MaxiMUM aMount of each hazardous Material or Mixture containing a hazardous Material disclosed in paragraphs (1), (2), and (3) which is handled at anyone tiMe by the business over the course of the year. 3. ADEQUATE PROVISIONS MUST BE MADE FOR THE CONTAINMENT OF HAZARDOUS MATERIALS SPILLS. VIOLATION OF UFC 80.103(G} Satisfactory provisions shall be Made for containing or neutralizing spills or leakage of hazardous Materials which May occur during storage, handling, transportation or use. The above violations Must be corrected by JULY 27, 1990. The departMent will schedule a re-inspection of your facility to verify cOMpliance. If you have any questions regarding this notice, please contact Ralph Huey at 326-3979. Sincerely, '3 c.\.\~("c... ~-<.r--~:r Barbara Brenner Hazardous Materials Planning Technician . . Bakersfield Fire Dept. Hazardous Materials Division 2130 "G" Street Bakersfield, CA. 93301 .ð¡ REC~'VEO JUl2 it 199ß Ans' d.... ........ HAZARDOUS MATERIALS MANAGEMENT PLAN INSTRUCTIONS: 0 ~ ~ 1, To avoid 'further action, ret~rn this form within 30 days of receipt. <t~ ~ 'J . _ 2. 1YPE/PRINT ANSWERS IN ENGLISH. (¿.A/ ~ 3. Answer the questions below for the business as a whole. . 4. Be brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA BUSINESS NAME: 1liliú~slt'L- /(AD;D~~eS LOCATION: ~ J:>R· 3 AM£- STATE:~ ZIP: ~ PHONE:~-31[-OS6g MAILING ADDRESS: . CITy13ill\. DUN & BRADSTREET NUMBER: SIC CODE: PRIMARY ACTIVITY: OWNER: c1..t.. ~~ MAILING ADDR3r- ~ý¡Q()';() I / ~Sf1.l,£S . 1!);~lel~I/L1, J SECTION 2: EMERGENCY NOTIFICATION: CONTACT TITLE BUS. PHONE 1.~~ 2. ~01Y;Ð2S -:p~ €S ' l!fS. ðq S-oS'f,g ðq~ -oSb~ 1. 93g~c..¡ 24. HR, PHONE 34 () -o!Þl ,ð '1-~"Þ 39K-{)WJ 397-~ FD1590 ·#' - .......~.:;r\ . Bakersfield Fire Dept. . Hazardous Materials Division HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 3: TRAINING: NUMBER OF EMPLOYESS: S"' MATERIAL SAFETY DATA SHEETS ON FILE: t{£.ß, BRIEF SUMMARY OF TRAINING PROGRAM: . £M.pW(.(ï:.£~ 1+'-1.- -rf{A-IÌJrlJ) "TO rO(..U)uJ A-t1~ ::¡::¡J~~ùC.-l/oÁ5 ON .s ft"FT71 D-IfrA s'µ'«::r~ FOIL ð-Pl ~ A1J D bl~ (Jo.s4L . SM=-1l1 ~ 0 ~!.s All..£, oiJ uJ¡fc...L..- ÙJ o"W (lfi-6L /IIUA r SECTION 4: EXEMPTION REQUEST: I CERTIFY UNDER PENALTY OF PERJURY THAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAPTER 6,95 OF THE IICALlFORNIA HEALTH & SAFETY CODE" FOR THE FOLLOWING REASONS: WE DO NOT HANDLE HAZARDOUS MATERIALS. WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANTITIES AT NO TIMEEXCEED THE MINIMUM REPORTING QUANTITIES. OTHER (SPECIFY REASON) SECTION 5: CERTIFICATION: I. Je/'% (Pð/'?k~ft CERTIFYTHATTHEABOVEINFOR- MATlON I.S CCURATE, I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE IICALlFORNIA HEALTH AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIV, 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT INACCURATE INFORMATION CONSTITUTES PERJURY. ' 7,.2 ¿/--f () DATE FD1590 :ç,.:''''~ ~- . Bakersfield Fire Dept. . Hazardous Materials Division . HAZARDOUS MATERIALS MANAGEMENT PLAN .. ... Facility Unit Name: L.ÜJ {U~SItG- ~lO~.+flc.s SECTION 6: NOTIFICATION AND EV ACUATION PROCEDURES: A, AGENCY NOTIFICATION PROCEDURES: CJfu.. qU B, EMPLOYEE NOTIFICATION AND EVACUATION: CAu- 3oS'- Bt}<[-oSÞ~ ;z.t/-IIR-. tY-~&£.- ::fo +f1J $ ~A 3Cl1 - 5"hS'.s- Jí M RODGV2-S a11-5'S'J , C. PUBLIC EVACUATION: D, EMERGENCY MEDICAL PLAN: fYl~~ M. ~(5"í'RtJkrùlJ ~7-331J 3. ~~ . Bakersfield Fire Dept. . Hazardous Materials Division ^-~..;: _. '>-" , "'~'....""" HAZARDOUS MATERIALS MANAGEMENT PLAN -'..... .... . SECTION 7: MITIGATION, PREVENTION AND ABATEMENT PLAN: . .... A. RELEASE PREVENTION STEPS: ÒO fJOí' S1t\-C..K BO)(t.6 MOrL£ --r+l1t1J -3 HiG-H. J)O'¡JO-r Cc.rr ßOV:~ -ro oPW, ,<œ.-P FRo'" bRofJP,ÄJ&, AfL CfJ1JTltliJliIlð ALE. S£AlÆj) · B, RElEASE CONTAINMENT AND/OR MINIMIZATION: l.1&f, OF 6IHJD ~ CIPí LA-itvL 10 A-f>sofP Mq S(J,LLIlGC . C. CLEAN-UP PROCEDURES: CA-LG ~~()PuZ- i>tS(JðS!k, {J€t;fL.e:.,', SECTION 8: UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FACILITY): ~TUR-ÀL G.tWPROPANE: N ~ ~R¡JfIL, obßL.~&ï , ¿ I tJ~· J\ ELECTRICAL:~ IIí fi{O¡./í" !1Jðiðe.. :DoøtL ~+ W~_ WATER: OtJ M£J S"ðL Q'F 13Ùl~,'#J& .... SPECIAL: fJo~E- LOCK BOX: YE@ IF YES, LOCATION: SECTION 9: PRIVATE FIRE PROTECTION/WATER A V AILABILlTY: A. PRIVATE FIRE PROTECTION: {- Ð<í(~&Úìs~ oIJ 5,£. lAJAiL OF SIOflA.bE- ~ 1- ~'LTING-ÚI~E(L (~ =FflÐp-r OFFIC{" B. WATER AVAILABILITY (FIRE HYDRANT): t Bud( tJLAJ OF B0\(1);JJ& 4, FD1590 p..'t:. ,. ~~ . . JUNE 27, 1990 DEAR MR. RODGERS, NOTICE OF VIOLATION AND SCHEDULE FOR COMPLIANCE ~===;======~========~====;==;===========~======= IN THE INSPECTION OF YOUR BUSINESS UNIVERSAL RADIOGRAPHICS LOCATED AT 419 WATTS STREET, BAKERSFIELD, CA 93307 ON JUNE 27, 1990 THE FOLLOWING HAZARDOUS MATERIALS REGULATION VIOLATIONS WERE IDENTIFIED: 1. HAZARDOUS MATERIALS MANAGEMENT PLANS MUST BE REVIEWED AND UPDATED EVERY TWO YEARS. VIOLATION OF CH. G.95 CALIFORNIA HEALTH AND SAFETY CODE 5EC.25505 (b) In addition to the reqUireMents of Section 25510, whenever a substantial change in the handler's operations occurs which requires a Modification of its business plan, the handler shall SUbMit a copy of the plan revision to the adMinistering agency within 30 days of the operational change. (c) The handler shall, in any case, review the business plan, subMitted pursuant to subdivisions (a) and Cb), on or before January 1,1988, and at least once every two years thereafter, to deterMine if a revision is needed and shall certify to the adMinistering agency that the review was Made and that any necessary changes were Made to the plan, A copy of these changes shall be subMitted to the adMinistering agency as part of this ced; i f ieat ion. (d) Unless exeMpted froM the business plan requireMents under this chapter, any business which handles a hazardous Material shall annually sUbMit a cOMpleted inventory forM to the adMinistering agency of the county or city in which the business is located. Notwithstanding any other provisions of the law, an inventory forM shall be filed on or before January 1, 1988, for the 1888 calendar year, and annually thereafter. This inventory shall be filed annually, notwithstanding the review requireMents of subdivision (c) . 4-"'- _1\ . . 2. HAZARDOUS MATERIALS INVENTORY MUST BE COMPLETE AND ACCURATE. VIOLATION OF CH. 5.96 CALIFORNIA HEALTH & SAFETY CODE 25SØS(A)( 1-4) The annual inventory forM shall include, but shall not be liMited to, inforMation on all of the following which are handled in quantities equal to or greater than the quantities specified in subdivision (a) of Section 25503.5: ( 1) A listing of t.he cheMical naMB and COMMon naMBS of every hazardous substance or cheMical product handled by the business. (2) The category of waste, including the general cheMical and Mineral cOMposition of the waste listed by probable MaxiMUM and MiniMUM concentrations, of every hazardous waste handled by the business. (3) A listing of the cheMical naMB and COMMon naMes of every ot.her hazardous Material or Mixture containing a hazardous Material handled by the business which is not otherwise listed pursuant to paragraph (1) or' (2). (4) The MaxiMUM aMount of each hazardous Material or Mixture containing a hazardous Material disclosed in paragraphs (1), (2), and (3) l1Jhich is handled at anyone tiMe by the business over the course of the year. 3. ADEQUATE PROVISIONS MUST BE MAOE FOR THE CONTAINMENT OF HAZARDOUS MATERIALS SPILLS. VIOLATION OF UFC 80.103(6) Satisfactory provisions shall be Made for containing or neutralizing spills or leakage of hazardous Materials which May occur during storage, handling, transportation or use. The above violations Must be corrected by JULY 27, 1990. The departMent will schedule a re-inspeciion of your facility to verify cOMpliance. If you have any questions regarding this notice, please contact Ralph Huey at 326-3979. Sincerely, ~ c.\.\~,c.. ~ç<.. r---t-<....:<"- Barbara Br'enner Hazardous Materials Planning Technician \ \ I ,I " ,"\. ":r ,.\ .ATERIAL SAFETY DATA SHe 4900 EC \.... ., " " HEAL TH '. 'f 11-;' ;J:~i: . -"¡ 1 " ....,. ., FLAMMABILITY, ,. 0, REACTIVITY~ ';" :0 Gogg1u & G10vu R.comm.nd.d , j ,. , I I ,I White Mountain Imaging " P~O. :'80x 216. Salisbury. N.H. 03268 ':' SECTION I Generallnfonnatlon .. , '.! < . 'Product Name: T2 ESC Developer System Cleaner Formula: Aqueous mixture Chemical Family: Photographic Cleaner ,t:,.Catalog number: 4900 EC ; 3 x 101 Information Phone #: (603) 648-2124 . For Emergency Situation Call CHEMTREC 1-800-424-9300 Date Prepared: January 29,1990 Department of Transportation: Shipping Name - Sulfuric Acid Solution 2 %; Hazardous classification - Corrosive Material U.N.# 1830 " ", I . ~ '.~;; ,I . ..': . 'SECTION II Product and Hazardous Inaredlents Infonnatlon A.Principal Components CAS(I) # . . . ~ " ' Pen:ent ACGrn(2) OSHA(3) S.A.R.A TLV PEL TPQ(4) RQ(S) LDSO(6) LCSO Water 7732-18-6 98-99 nla nla nla nla uri((7) Uil . Sulfuric Acid· 7664-93-9 1-2 1.0 m9'm3 1.0 mghn3 nta nla2140mgIKg Uil B.Precaution~ry Label Statements: Contains: SUlf~rIc Acid «2010). .. . , ,banger! Can cause allergic reaction.. Causes severe skin and eye bums. Hannfullf Inhaled. Vapor extremely Irritating. Precautions: Avoid contact with eyes, skin and clothing. AVOid breathing vapor. Do not get in eyes, on skin, or clothing. Use with ,adequate ventilation. Eash thoroughly after handling. First Aid: Call a physician immediately. If inhaled, remove to fresh air. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Remove contaminated clothing. , 1 ·S.A.R.A Sections 302. 304. 313 HazlU'doua Component. , (1) Chemical Abstract Service Registry. (2) American Conference of Govemmentallndustrial Hygienists Threshold Limit Value. (3) Qcçupational Safety and Health Administration Permissible Exposure Limit. (4) Threshold Planriing Quantity. (5) Reportable Quantity. (6)LethalDose administered to _rats (7) Unknown. SECTION III Physical Data' ',I · ,~arance and Odor : Deep blue liquid, Slight odor. e SpecifIC Gravity (Water. 1) : 1.012 . · pH :approx. 1.00 as concentrate . approx 2.50 as working, strength · Percent Volatile by Volume : approx. 85% · SOlubility in Water: Complete · toeff. Water/Oil Dist.: nla · Odor Threshold: n/a · Vapor Pressure: approx. 17 mmHg @ 20°C · Vapor Density (Air = 1): approx. 0.6 mmHg · Boiling Point: > 212°F (100°C) · Freeze point: < 32°F (O°C) · Evaporation Rate (n-Butyl Acetate .1) : nla S~IO-N IV Fire and EJCploslonHuArd Data .. Flash Point: none · Extinguishing ~a : Dry chemical, CO2, Water spray · tJnusuat Fire and Explosion Hazards: none , , , · Flammable Urnits : lEl· none: UEl-none · Special Fire Fighting ProcedJres : none conIiF1J8d 1 .'-, ,:.~...., , . i ' , " I I ' - :¡''':):'f,)'1;MSDS;' T2 ESC DeVel.rsyst~ms CI~an.r " '.j' , " , , ' 'I, , SECTION, V Reactlvny Data ' ;, · Stability: Stable" , , · Hazardous DecompoSition Products : Sunur dioxide 1· . Hazardous Polymerization: Will not occur . 4900EC ,/ ¡ 11 1t~ , , ' , · Incompatibility: Strong Reducing Agents, S.trong , ,Bases and Combustible Matenals. ' , , ,,~I , , SECTION VI Heanh Hazard Data Toxicological Properties · Effects of Over Exposure :' " , EYES - May cause burning or irritation of eyes and mucous membranes. SKIN - May cause irritation and/or allergic reaction. ' · First Aid : , EYES - Flush with water for at least 15 minutes, get medical attention., SKIN - Rinse with ESC Rinse Neutralizer and Wash with plenty of water. If allergic reaction develops seek medical attention. INGESTION - Seek immediate medical advise giving full detaifs of amount swallowed and toxicity. ' , · CARCINOGENOCITY- To the best our knòwledge. this product is non-carcinogenic. ; · Teratogenicity: n/a · Reproductive Toxicity: n/a · Mutagenicity: n/a · Synergistic Products: n/a ,'1 "~! -'I ,i" SECTION VII Precautions for Safe Handllno and Use . , ~~ · Spill Response . " Wear protective clothing as specified in section VIII. Neutralize with ESC Rinse Neutralizer or sodium sulfite. Complete neutalization causes solution to become water white, and pH will then be in range of 6.00 - 9.00. Once neutralized. flush , '. ,', ' neutralized material to sewer with large amounts of water. '. · , Waste Disposal . . If federal. state and/or local laws pennit. ftush neutralized material to sewer with large amountS of water. Otherwise dispose ' ,.:' " ,; of contaminated product and materials used in cleaning up the spill in a manner approved for this material. Consult proper " ' Federal, State and/or local regulatory agencies to ascertain proper disposal procedures. ," ' '; , . ,. HandUng and Storage: -, , \ ' :,,', · Keep container tightly sealed. ' ' , ' ',. . ,',,;; · Do not store or consume food, drink or tobacco In area where they may become contaminated with this' material. ,. Store above 40°F (4°C). ' . ; .. ,':" ,,' , \" · Avoid incompatible substances. ' : · Avoid unnecesary personal contact. ;.:~, i:·' Wash thoroug~y after handling. : SEêTlON VIII Control Measures ,'- .' '\;: . . I . . ~~ , " - -! ~ ',i " .' ,. Respiratory: None shoud be needed · Eye protection: Safety Glasses or Goggles. ' · VentHation: Good general ventilation .. Skin Protection : Impervious gloves shoud be worn. '-- .: Other Protective Equipment: As necessary to prevent e)'é and skin contacl ~f ¡ _ i .~ I, ' . " ~ - ';,"./, : . ""1 j.·1 . . .¡" ,~,-t:::·}<:{::,?'\~ti:{.~ ~ . '/.~"1'!~. '~::T:·,f>~¿/\.~.':,:_' j;:~ç~' .' . ,'" ...,.... ':..~. :'.:' ~ ......--....----.............. ..........-..........................-........................................ ...... ...............,................._-~....~-~......-. i,. f;~ " ...... .<;\ ".. ~ _', . , " .. . ',..' . ~',- _ ,'Ii '! "". t "1, "" _; . , " _ _¡. :1 (' ¡~ '.f~ """" ~" " "',\1 The Information contained in this material safety data sheet is furnished without warranty 'of, any: kind. ,I . . "The user should consider this data a supplement to other information gathered and must make independent , " ,determination of suitability and completeness of information from this and other sources to assure proper use and disposal of this material and the health and safety of employees and customers. . This statement is incorporated as part of this Material Safety Data Sheet. , '. -' t) ~," ,'~ '. . .., " , " ,.: ¡ ".~ .~ " ".' " )1 .... I' ': i ;,j,.\ '; ..; I ' " ' , ~ ' " " " I . ". .. .~ , "I " ¡, '." . . ' - (~.. - -,' ~ ' " \1 'i . This MSDS (ormat complies with OSHA Regulltion (29 CFR 1910.12(0) and is based on OSHA Fonn i74. 2 ,jçtt~;t~l~rr "::!;!¡f~FETY D~~:S~EE .... ~f;7¡~~!~'ih~~~ ;,}>¥:::~).;':::':;'ë White t10unt8tnlm~gtng ~E~~~~BiUT~" ~.. . .>~ .. ' .' ,,' P.O. BOK 216. Se11sbury;,N.H. 03268 REACTIVITY<,;¿'~ \'0 :" ',;,~ " . '. ¡ 'j¡': ' " . , ',::,;~;¡~ ' ' \, ' G099'es & G10ns Recommended ,-, í:..· . { : , " SECTION I Generallnformatlon , ;.~ k,<~i~ , " ,,' I, . prOduct Name:' T2 ESC.Developer Cleaner Neutralizer Rinse Formula: Aqueous mixture Chemical Family: Photographic Cleaner " . Catalog number: 4900 RN : 3 x 1 at, , ".. ., ~.d,''; -~ . -, ., . Information Phone': (603) 648·2124' ",' :" ,,' I ' For Emergency Situation Call CHE~E;C'I!1-800-424-9300 Date Prepared: January 29,1990 \' ' " ~ /',;;~~ ~ ~ ~ .:. ~.' ::;. t: .:~ i . ,:.-. ,',_of '. " ' . .... I ", ". ~;~,:, . . " " ~ .;.~ ~ 't:-..~, ," ,'- , " . . ,\"i··~..~ (,' 1: . . ,~ : ~ ;I.~t)!..· : . J''f. ..¡' , .;., "t ,', " Deparbnent of Transportation: Shipping Name· Not regulated; Hazardous classification· Not Applicable ~, '.~ . I ~.. " " -. '" t" ,~'. :.." SECTION II Product and Hazardous Inoredlents Information - ;.. , . ;' , OSHA (3) , ' ' A.Principal Components CAS (1) ## ' PerCent ACGIH(2) S.A.R.A TLV PEL TPQ (4) RQ(S) , : LDSO(6) LCSO Water 77J2·18-6 æ95 nla nla nla ' nla..·. Ui<(7) Ui< Sodium Metabiulfite 7581-574 ' 8-16 5mgtm3 nla nla ',' n/à ',', 2GmlKg U't " Sodium Sulfite · TIST.ffJ.7 .3-8 nil nla nla 5CXX)b ' U't '.':. U't; :,' 1. , .~ i.' . " ,t" . " ,> ' B. Precautionary Label Statements: ContaIns: Sulfite , . ' Danger! Can cause allergIc reactIon.. CaUl8ll8vere skin and eye bums. Harmful If Inhaled; Vapor extremely Irrltadng. Precaudons: Avoid rontact with eyes,skin and doihlng. Avoid breathing vapor. Do not get in eyes, on skin, or dothing. Use with adequate ventilation. Eash thoroughly after handling. First Aid: Call a physician Immediately. If inhaled, remove to fresh air. In case of rontact. immediately flush eyes or skin with plenty of water for at least 15 minutes. Ftemove contaminated dolhlng: · S.A.R.A Section 304 HazardoUl Component.. . :. (1) ChemicaJAbalnCt Service Re¡ÎlIly. (2) Amertcm Conf~ of Oovemmental Industrial Hy¡ienilts Threahold Limit Value. (3) , Occupaûona1 Safety and H~th Adminislration Pemúnib1e ExpoÏure UmiL (4) Threshold Plannin¡ Quantity~ (5) Reportable Quanûty. (6)LeIhaJ Dose adminiataed to rats. (7) Unknown. " ... ,. SECTION III Physical Data . .' Appearance and Odor : Clear, colorless ánd odorless liquid · Odor Threshold: nIa . ",1, ,_, ;: ' .. SpecifIC Gravity (Water. 1) : 1.200 ' · Vapor Pressure: approx. 16 mmHg @ 20°C .,. pH: approx. 6.50 ,> ,.';,' ", . ,. Vapor Density(AIr.1) : approx. 0.6 mmHg '. Boiling Point': > 212°F (1 OO°C) , " ',; , '. Percent Volatile by Volume: approx. 96% ',. Freeze point: < 32°F (O°C) ,.", ,!;,\::;' ~ SolubilitylnWater:Complete',,' , · Evaporation Rate (n·ButyI Acetate .1): nla ' ;'" . .. , ,. Coeff. WaterlOU DlsL: nla t.._\" , I . ¡ .¡ ! . , 1 ! i SECTION IV Fire and Explosion HA~Afd Data ~ ::,', I..,. ,t.) !J ';', ',: ,'"I' . ," I ¡ ¡:¡, , .2'. Rash POint: Non Combustible '. .' I';. 1, : " ¡! (':. t. Extinguishing Media: Dry chemical, CO2, Water spray., ! ;~:\ :','il:"f'¡,,"le:uruual Fire and Explosion Hazards' none ..: ;:¡,,:};:::;<:~¡ j' . . .,.,:,:~{i1>t::'<'J:e~<.(>!t;! . þ: ~" I ", '~. . . ! l' , ' ! " contir1J9d ¡;;;" ,.:i ,I ¡ , , 1 ';¡ ~ ; ,J~";';: f', .',~ 1 . ' ,~ " ,I ! ,¡j ¡ ,. Flammable Umfts : LEL . none; UEL -none i , · Special FIl'8 FIghting Proœc1Jres : none :; ; ':¡ ; "; : .¡;J ".; -~:~, '., , ' .1. ' I'! i ',1" , ':;,-j ;/,'~i " .'\ " " ' -- -------~------ ,':":P:.~~~~~?Fft~t~~~~!{.~':·· .' . ' , '"" . ;" ~',:,,::;,,::~\,~!tt)M!jD~;'~, Developer SV. Cläàrie,: Neutralizer Rinse I, " :;"';'ï - ;(J i '.~" .. ", - ._ " . . . ','':' 'i.'SECTION V ReactivItY Däta ¡ '.' " . '," , ~, \-./,- ~::.:·..š·. ~ .'~' ... .' :,J':' '" ,i· Stábllity:Stable "'."" " " ',' . ~';Jiàzardous Decomposition Products: None ~ " '. ~f.:~,f>~:,:;.':t~<~1-.:- ", :1 '".~: ~ . <": :'.,;,; ,:,,:,.._~:"~;\ . . " j ."~ 4900RN " , i. . incompatibility: None Known ',::: t -,~ r. ~ t'. · Hazardous Polymerization : Win not OCCtl' . ", . SECTION, VI He~lth Hamrd Data Taxlcolaolcal Properties ¡ '-. ¡ . : ~EffectsofOverExposure· '.:, ; ',¡':",;' : ' ".',';','.,> " : " INGESTION· May poSe health haÍåÍd to' èëí1àJn individuals, primarily asthmatics sensitive to sulfites. "¡ , , .. " :' EYES· May cause burning or Irritation of eyes and mucous membranes. . .' '" .,': ',\ '. SKIN· May cause Irritation and/or allergic reaction. Non carc:lnogenlc. : . ''', ..', " :. " 1 :r.: i' .. ArsI Aid : . ..... ". ( ~. . i. '," ~~r"-~' ~··i-,(1-.:·Vr' : ~ ~ INGESTION· Seek Immediate medical adVIse giving full details of amount swallowed and toxicity. . , .' '" EYES· Flush with water for at least 15 minutes, get medical attention. , , . ,,', ' , " . , SKIN· Wash with plenty 0' water. If allergic reaction develops seek medical attention.' , . ' . : '. , . .,'. . ~ . '..;.,.~~. ~- · CARCINOGENOCrrv· To the best our knowledge, this product Is non-carclnogenic. ' · Teratogenicity: nla · Reproductive Toxicity: nla · Mutagen/city: nla · Synergistic Products: nla 1 . _i~, . {', ~j-l i'r' ·',.i,.< ·...li~:;· . .;; "I. ,', ': "~.) ...- ~(" i- - '~> . :·,l'. . ,'. .. { .': ' . ~ ", ,,' .; ,; \> : ,',' ',;, ">;I,;r "f.: ~,: .:', ':-:~.; \, ,;.~,,\i , :":' >,'" " . :. .......<J~ " . '. . SECTION VII, Precautions for Safe Handllna and Use , , . , ' ,~~j~ . . i 'n- ,', :"'~~ , · SpiH Response· ," , ,,' : ,: ",:', " . ' Wear protective clothing as specified In section VIII. If federal , state and/or local laws permit ftush to sewer with large . amounts 0' water. Otherwise add dry absoJbent and clean up and place In an approved D.O.T contalner,label and seal for .. ~i :), . cisposal. . , ..' , ...,'. Wåste Disposal· , :;. .If federal, state and/or local laws permit, ftush neutralized material to sewer with large amounts of water. Otherwise dispose . ,of contaminated product and materials used in cleaning up the spill in a manner approved for this material. Consult proper I.." Federal, State and/or Local regulatory agencies to ascertain' proper disposal proœdll'8s. " ;;~:~. Handling and Slorage: " ' . ~ '. · Keep container tighUy sealed. . ' .> , ' . · Do not store or consume food, drink or tobacco In area where they may become contaminated with .thls ma"rIaI. · Store above 40°F (4°C).,l,,{),;-:r; : Avoid incompatible substances., " ,i \ ' ' ;, . " ..'~ '. .> '" " ",: '., Avoid unnecesary personal contact. ,i::' , .;;' 'L ¡>. Washlhoroughly after handling. " ',. : ¡;: ,'1', , " ..... -' '" "'~,,:J't' ,..' ..' .·,·:~·~r 1 d :'-" " ..,'¥"<.." . SECTION VIII Control Measures : ':.. . ....~..> ~~f .' .' :_.~ . . ' _ ,~..,,~\'};:¿;¿~á\~~.~'\"'~1. ~' . .' ','" ,'1 .:.,';1,'.... ,..~" ':-:'~; .' .. Respiratory: None shotJd be needed ;1';¡;i;:~. 'í,-;-!, , "",. Eye J)fOtectlon . Safety Glasses or Gç»ggIes.: :. . , ,,' " ~.'. ,Ventilation': Good general ventilation '<:;~,~;:'~C,<' '. Skin Protection : ImpeNiousgloves shQ~d bewom. ;' , ~'-,'.': , ' · Other Protective Equipment: As necessary to~nt 8)'8 and skin contact. ,", ; " . ""':,'" ,~>·'The use of a non-aIkaline (acid type) hancf cle~~~t~.:mJnJmIze the possibility of allergic ~on. ,,; ~·,:,::iÜ!¡:1j 5' , , '''!':"_~1'(-',~.}.'' ,~:'~_\ A, ~,-;"-¡¡,,:'f ..,!' .'./:' _ . .. ;'3<;~~Þ;"~h~~·=~:~~;;!~:~·ß[~.._--~-----_.~;~--~~~J~¡ ...~.., , '-:Th8lnfôrmation contained in this iTlaterlàlsafét)f data sheet is furnished without warrantY þNiný kin(kThë~; :~; , , - user should consider this data a sùpplement to other information gathered and must makèJndePehdênt ;.. " , ' determination of suitability and completeness' of information from this and other sources to 'assurè proper use :' ',.' ..:,' and disposal of this material and the health and safety of employees and customers. This statement is '" " , incorporated as part of this Material Safety Data Sheet ..../ I.:/,' , : ", ,¡~. "", .......:.;~,..;.' . ~ ,,' ,:"'<~: ',,~ , ,~' , . .",:~ hNI}~ , .-~ ,....~-_.'~. "'.; '. ',' . -". , '.' ',',- .....".,::-þ.,-'; /'11 . .- ,1. ';~'; ,,:1 :~~/~ ,~ ';:1 "~ ,',;~ ..;'~31 .,'i¡'~ :~, I. ¡ I " t':; . . :' -' -, ;'. . ì I " ~ i, ",tj~: '¥~ ' , ' L .". ": }. ¡' , t t -J- ·,JL . : . . " 1'" ";1'1': ,'~' ¡1hiS MSDS format complies With OSHA ReguIl1ion;(29 CPR 1910.1200) and is based on OSHA F~ 174. '1' i¡~ ';JI: : . 1',::1. ~Ædl'!:. ¡:'i,' j '~ <". 1·1~:·t:~·:jli~1 ~,,\, I ,.' ,..'¡;.!!¡¡}¡t, ~ i; ;,::<f'>~r,: r , i, . . ,.~ ~." _ L ' 2 . .:. \,¡hrl' " . :': I~"l ; .~}, .\'/, '" ,I' , " .' L ,. £>' . -.-..\. '. ,.'... . --- ---- ;.', . {,;' :;:" .., ';. · ;~::~~,;:? ;~·~iALLlEDPH.~O pRqí)u~~~~; A subSldury' of Allied Products",Co~poraqon,J~i. :1'-t~,:,¡ , . . " ; . <:. H t:i:,l:r:Ã::ll'<~"~' .,:,}:'. .. i ¡ (MÓ~~flå I' Safety : DÓfâ:,:c:·S·heet,':'M-2'1 . ~"" . ti,,; . ,,_.... . I ; Dote last revis~d;;3/18/86 . :.'., I. General Information . "". t~;'.5 :'" .'j'\f .1 Chemical Name & Synonyms AUTEX FIXER ~ SYSTEMS C.LEANER Chemical Family Photographi,c.. Chemical... Proper DOT Shipping Name So~ium Hydr.oxide Manufactu,rer Trade Na~e & Synonyms; ., , ~.:: iÞ >; ,~';' . .'. . f'~ '. .' ~ .;q",.:,.- It . ~/ . "_._-'~""~'-_.'~"'."'.' ..-..~~..,.~... . ...~............-.."-'...,..-...-..........~ . ~~_',,_,,"_w' '_." 1 ;' ; -¡"'. . ._ _w~~__.._ .....,' ._,_....... ,_ Formula -, }'queoµ~_Mi.xtl,Jre_....,.. "''''':-;-'rT-;;;:'::)'T::::-- DOT Hazard Classificc.. <ion Corrosive Mater.ial, UNf 1824,..._....,.. Manufacturer's Phone Nu ',ber / (404) 448-0250 Chemtrec Phone Number 800 424-9300 redients ... '-:~~;'7t'T~' " '--" ......-.- '-~-' -_..'~..- ----......~._- ;'\': ¡ " .- .--.......--.... .: '? ;;~ ALLIED PHOTO PRODUCTS ,CO. 5440-A Oakbrook Parkway Norcross Geor ia 30093 '; II.!, In ..:. -'''1:'--.:;. "." f'. ,,:j Manufacturer's Address I '1 " . ", ',' . ". J: ; ~J' ).' " ~ , ¡.. . I, ~ i . ;,'f. "'{' "',., . v . ~ , <' .ç -~ '. -, -..'''''' .-<. .-- Principal Hazardous Components Percent Threshold Limit Value (units) . .... ~>.,._. -~ .._..~~ '-'-~--~~'--" .... .....-.. ~ ..-..... ....-._.-.~, .__......:.~....:_;.¡.,...._..:..... , , .", ..' - ~ SODIUM HYDROXIDE CAS' 1310-.7.~,2 ___J,O.~__ 15 _'.' ,2mg/m~ ....-.---0--.- . . .... /. . .~. ~.. -.-.::..:.....2:...2;-- . i "~I ;' ·ò"t~~~~it~, , . , .-. ....- . ,,~. . . ,. -," ~.. ,,- -, . ..". '~'''''~''''''''--'''''-- , ' ,'. , t. ~r;.::'ri'·~~~:-::; ~.' - -- -,---,.,.__..__.~... ....---' ......----~_.._- .... -.- -.. .~ .~_.~ ~~_...-._~_. ~_. - ,__I, _~._ ~ - ,_.. ___._'......~__ .__. '.~ ..:'~-,/' , " ¡ I; ':.,: .:-.. ~'~.:'" " : ,'. ,,'. .) , ' . - . -~-.....-.~. -_.~. --~ -.~- ~- -- . .-.-.~_._.- --- .-- . ,,' . ,'. ",1. ~ .....--~_._"~_.-.--~.-~..- -._>- ---. ~ - . . - . . .'. .__,_-.._ _...____~__....__..._.___,._, .____.~_v..-~. ~~_,.,_. ..-.. .~-_.. -.. -... .n....'~_.'~._~.^~.,,~.~... ....._ ._~"_ ~.. ......,.___,....~_.. ..._ " J. . ~., .' ,/ , ' lit 'Ph sica I Data , " . 1'.' :', . " ~ ':;~., . 'j, I 1.-/ . -- ~ ._..._,_._.....~._......"~ - --~ .. .-- ...~... ..,. .._.~._~.____~_._.__. ,_ _. _'___'r_ .._~.___"... \, " \ . {~ '..,,; " ~ . .... ....... ,. ':1):~'" " ''¡' d ¡ \~~'i.::::. ,.... '." ~ ~ ~',,,, ~': :' ~ ,. /..., ~ ': ... Boiling Point (Of); " :.' :, J ¡ ,:, , .,.;'" ':~, ,.:',:; ~ t ,J)1:;; " - Specific Gravity (H20 =.;1 ) _ :c::;,.I>J..:. ~_<,5'2...1r2L, >2~2~F.ê. (lOO~çl.,::;..~:.~_.:~:~l¡,,:i~:,'·j: :_...,_~pprox. 1...Jº:..:t::":':""· Vapor Pressur,e(mIi:lHg.) ,', i. . ': " , ",; :"", Percent Volatile By Vol.ilme (%) , '__'_-"" ·i,''fl~:?:'·':::'.¡. ·'~I!P~~~J!.:,0:.:.il._~_.!.:~:::J· ~"J'::'::":::._.,~,:".. ...,~pp.~~.... .ª5,,:;.:...,L~~:.:.;l:,_ ,_:...._,;;.L.-ÄL:~ ~__::__.,__.. _¿"".~_~~:~£~~~,. Vapor Density (Air = 1) , ",' ". , " ,.~...' r.: . . _ Evap9~at.ion Rate (-_F 1)· '. .- '", " , ... .:.. Approx. 0.6 ¡',i~:::~;Î,J¡:i(¡:'¡::'",: . Not:Avii1able:' '. " ,." ""^"~' _1- .....:..~_.__.....,.;..~.._"'. -_~ _ ._. ~~'"''''-''-'---'~'''''';'~~'''''-''T'"'''''''-'~-''' _ø___. ._~~~.___~ __..._"~_..~_'_~____.~~_._~_._'~~_..__':""___._______----- Solubility in Water "",~:;;;:;h",;" ,pH '. " , ,;[:¡.';;::""', . I ,Complete.j ..,' " ,::>¡;t.¡A¡,h,~,·" : Approx 12 ,,"¡'n';',',~, ~.. , . ·'''<.h1 t.iZ·:b;::· . -.- ,-- ..... _.'-~. .. -'"""1!"i'--. ...~.J......_ .. . ~ "'-_........~..__.~.~~ ~¡,¡;.~"i~_...:_. '.:--"-. .., .'......~-- ._~-....-~....._....~~.-.-~-_._._._--~"i'~'";~------~._-- -~·~~1~ . - Appearance & Odor " ~':'.~!K,;~;'~;:;~t.¡'h,':"¡ ';,"llY- ':);' ' ',::.. .,... Clear . water white. Odorless...l1 ufd. . ("<'1 , ,:'~';'ir\;',i" . IV. Fire & Ex losion Hazard Data "'; ': ~¡\-~' J"'~.- ~ ~l. ~<;~.(1}J.~.-\. i >,':., :--.. :~~~q:~~..~J~:~~ ~-' -- ·:~~~~~{~-þ;?~t ""-0-,1,: ,':' Flash Point (Test M!,thod) '; ~ . ~ " '. Auto Ignition Temperature , .~ '.:. ¡I, F"INon~..cboml' 'u~u~t) ~ 1 e .. ~_..... ..__ ____ .. _ _.:'; ;:~;~(: rl¡ ,~;'_~~', -leNl0t. Appl ~ ~~b l_~...,_..____... ·"-'u-·e-l :-·:-+H ,;\rt II·t-:~·"-:ï-:--0'.· :Imma emits.:, . (, ...~',~!\".."' 2.1J't;, - ' ' .' I,!:~ :,: ¡Ii '.'ì(,~-" None" j ò s.'·..':;..¡7;, ",~" ' None': ,j : <-No'n"e ,.,~. ."', r,'~.'f::: (:t,.-, . .' ~," I ,.."I.......)} ,f t",~. '/ I r.:.... --£'~·1. ..1, . . ~~. -...... '"'-·7.....~-~ _..~.. ,...-0:'- . ~~ ,- --... ~r---"1.- ~~ . , 1 J J I!~. ¡.. ~,"" - ~~ -.-.--.,-......-,-.- ......~t.._ ~-~-.......i-._.~.. ...-...-....-....._-~~ , ,~~~ .E.Û.t;:U. _i~;g me.M. 7i~, ..s. ugg~,'. sted, ., to .. ext1.'n.' g",: U.\.1.M~"_~k.·.'\~h,1.. ,...~S,'.·,_'~,).,'.:Ü,.~.j, é~, of th ' fi ,,!' .I \' , 1 "'f.:- :11,;· ~ j:~;> ,>~, . - . -. 'm- .. f¡' e. re ..._,_.--:...._..,_.._...:._-:.:!l.;:jf.~.I' :;¡¡~L~i.J.;.: 1, ',,; Sp'eciol Fire Fighting Procedùres ' . '¡:·:lp:l! j IIi:·! ,¡if :i :.' -' 1:í'¡' I , ! :§ II' N . . I Ii' î 1,1.· , ' " .)':,1, ',' ¡¡''l '" ," , ~O::' :~~& ":':".0 H~:.'d' -..--. ~ ~_~-~_,:.':;,~,"i.t: .,~.¡L!i...~Gel'H ... .H - -~: 'j:. :¡ïrJ~1!!I{:~i~::--- None. > ,¡'{I:\'I, .liì¡i,ø¡'~;U .' '", . , .'__H_ . . . .-. -.. . ----dtt :;\.:~~;i~~: eCop,ñefw 1m' ...."'......0; I, I, imn ¡ o$SOCIAtf$, iNt;. - .......h, WI $4.~:161 , .: format Bosed On OSHA Form 20 ' ~,~J;":. ,';:.L";""i~ J-IM'" ' . ¡ ¡ -:,'¡, {!;~ ~·~,.:r;· . ,::L'\~:j.,:!·t. ':' . ,:. Hazardous Ma Occur Polymerization Will Not Occur Hazardous Decomposition Products None ~ , , ~~.,;VIFtfaij:blthiHazcird Data 'Thresh~í~"lii-nitA/olüe . . ", ' .:' ,OSHA Threshold Limit Vàlúe: , ,.1.>¡f;;':£''',i'...!' ; .J. ' ... . "" . . . . ".:.~ ;', -. [ , . ..~ ~ .', ~e.,~ç!tc?'",,¡J r,-c;"' _n .. .".:.' ""'-"';7; .:'",...,. ..".-.., ..... .,.... 't; ..... .' -_...::~; :';'~~:L: .. >:';~·~.1:~ ';':'\~;' ~;;, €.clliiriogen;1.)NT, ~;,~r.,gram' »":;,.~.....,,.~ .--,;".. :"~.. . '>'';~'';';:''':~.'.-''';'''. :"~"I ,Carcinogen - IARC Pr<, iJram··.. . '.'< '_".'f"_;""'.~' ;;....... ~. "'·~ii.'*.'·'''7::''''':<!,~h'''-·'''-'; 'l~~,~f!,~C~~~p, .:'... '.... . ;~' -" ;~~i~6'i'h, lì None" known.~ ,'¡ .'. . ..' ....,:.,~.;,';. ..,' ::':, lf~~"1 ~tr":l·~~~~r;rltlÍ liquid ...;::~~;gétiü~~;p:r" .... '," ,¡::'-;;1¡~~:,;:;.ùfi~~~}j. ! ", ,iT~..)t:i:' .' " . "'-~'r.~'t~,~·~!;L;:~.", If ·tw·~~','~;7<_'l" i ~Ñ~~;I ~-;:r' '...a.aled BY~''':'~'~;'~~?;:~f~:;:~;; . . r: .u"\2~"-",'·~:::-,~r".~.-.;.,,¡,;',,.,:,{,o.·..,1.~.,.,!.':~....,:..¡,.~.... I¡. ..' . ' ,\; " : -.'·~t;~: ·v~ ~,·1b:Y'l~~"(~?j. ¡ ~"-':~/' ; __, .... ~ -. -"~~;~t,~i~·.~~f1<,~~i~~~:t-~:,~:-·~· ." ~'1'" .,,~ .~_..._4~_._:.~ i:_+~·<.i..l.~: -. ,. PË;;~,Ro~~~~,'o~~~t~ngestion ' ';~;~~~t~::~1:..i~L::~:~': ¡ ,......_,...,"_,__~:..~::_:,~.~ ,:~!:;~:~.c_,~;;~,~~..,.. ,H_..~;c;..::~;;.'-;,1 Eme~genéy Firšt'Aid EYES: Flush with'wáïëï-'for':àtJeast 15 minutes and get inedical"attention'.:";'::'·~'f~~':':>:,' SKIN: F1us.h. ski~ wit~ plenty of water.rt;If':'s~1n::Jrritati~n devf!lops, get,' medical ~at,~n.~,i,~n..nc~ INGESTION:~ Seek lnmedute medical advice giving full detal1 s of amount swa1,~o~d and tó~1ci,ty~: .... '.r. VI. Reactivit Data Stability x Unstable Stable Conditions To Avoid None known ,. " ,Materiàls To Avoid Strong Acids, Conditions To Avoid None known. , , Incompatability . VII. EnvironmenttdProtection Proce;~vres ' , Spill Response ear protective clothing. as specified in section VIII'. If Federal ~'State; ~nd/or 1· Local. regu1 ati onspenni t,_ n~ut:r~ Itz~;.~t~þ_, SQdi urn Metabi sul fi t,e and,,!l us~,Jo,:'sewer ~Wit~.1 éirge;:.:; , ,amounts of water. ' Otherwise 'add dry~bs()rþent, ,clean up and place lnan, approved D~O.T.'I : container, .label and seal, for, disposªl/~~_ ~ , : " ..."., '................ .......'.;.,.;. ,".'~, ....," ' _..,.;.;., ,CJ,', . Waste Disposal Methc.d If Federal, State ,and/or Local ~regu1ations pennit" flush neutralized ;1'(;1 f ,í material to sewer with large amount$.:~º:t.water..,1 Otherw.ise dispose,·of.contaminated product ,and 1, materials, used in cleaning up spil1s~~fn~!amanner approved for this materia1.. : Consult"propèr" ; Federal, State and/or Local re u1atór\,äencies to . , . ',' N ~ .. ". . !~;,'. :, , : f"7J~'i"':""¡::'" ",~...,,, l . .' "" ~>:.:,'''(,f!'.;''.:)·''.'i\M~'· : ;, , VIII. S èé.òl:r,Protectlon Information," , ,:':,~' ,;k-:, ì '" . " . .;.,.. A~. I' -,~ , ' .,. - . - , " ,i,' .' ·k "'''1:1)'I,,,·,,,..AI,..'' Eye Protection ..'." , :, '.. n¡: tS in Protection '. ,.,., i¡ . ';~ .,;Y,!~f;~~f~:, ¡ ~a~ety,g~,a~,~~s:or ~~ggles ,.,-'","y,~\~:~~J~~~,,: ¡ Im~e~ious gloves ShOU1(f~~~~~m,.,)¡~{':'·' '1 :1 qesplrotory Protection (Specific Type) . f ",;-.,' l' J' Yentllatlon Recommen~ed ";¡,,,." '-'U' ~ ., None,.~~~uldi;.I;M!. needed .. -'. " ..·",:,:_~~:.~:,:~;;;~:.~f~~ .\Goòd general: ventf1at1ori2:?;'i~~I~, ~~~;,,~~~~~iI ' , .' ." If'" ,".....'''' " "" . ,< \ .' ',: ' '0"" ",,":,'t,\~,.~;.t Ot"f'1r Protect1on ' I,' ""!"" !!~,)jf""':\f',r.i!t,¡jo:f>j· ·'.;:),1'i'1U.:,~''';, >' .', -:.: ' \; ,l', 1 ('.>t,;>~~w,;:~, Ii I! t ' d'· 'ki""'I'!~'W..." 't'" .&:"",,)., ;." . , n" ,.., .+ f ", ,~ t_~..:.}.ec~~!;;ar'i ~ ,~ 'fÚ~Vf.:~fr: ,eye ',an . S ft··con ac......'~..' ' . :,.~~¡;;~ ,~¡~ . .. .:.'''- ~¡,>:~~1:¡:;,¡:>'\"':,,~¡ , -- ~~ .,' f!~,/"_t:. '..' ~...r.o 1-·... ~i:, ~. ~ .~ ':t ~,;.A'~, (it\ ;: ' : .' ';:, ,,:JIXí~~S t!cla Precautions 'ltY'(, 1:1;, ll~!, i":U'.I~ Hygienic Practices In Hondling & Storage Keep ,tightly sealed~ Do notrstore or cons .¡I;ro' "ldrinlC;o!l! r~,':J,ì~;:: tobacco in, area where they may become contàmina~~d !ith thi~ materia1. ';'h~9tèt:~~óv~,;,4P,~,f,!lt~~r'::Pt .(4°C). Avoid unnecessary personal contact..., AVOld lncompatl~le substan ·1, :''.,;\\;:;,1 :"11; \,~+\~'i;:II'h Nash thoro'ughly after hand1i'ng "", '1::'.'\ '¡:' 'J, ~H¡: di"'í"I¡!tr::¡,~~r~ ., ' ,1'1, ", .. . i! I_,,~ " "'!. '1'1 "., r"" 't : " ' . ; ',\' r ., 'J j ~ ' 'i1l 't¥i,~'!,:~'rrï".r"nH ~~~ I~ ~ Precautions For ~epair & Maintenance Of Contaminated Equipment ;\': J .. i ' , ' I¡ \~!~¡,i 1::+: ' ,~;. 'II' ,I 11;"1¡'¡ 't-I " ,I , ".' I . , 1 " , ~ I" r ,f,~ 1 ' j f· " , ' ~IJtj \ l., II" 1 . 4. . , 1. ~:¡ ./'t! '" i, , ': ",~~1 ~1~ 'I{', If,~1. .J. . .'" ~ ' ¡ , ¡, , J I' I .~ !1' t , "~ I'" " I: " I" t ' , I I, . ¡ , ,'" fi l' ·f '" ,>,« ,¡hr¡", :. :/'''; , ','. , ' ,r " :;,;" ~¡: fi' '1,1:\ '.. " " f 'J <~, ]t~ .' ',i 'I; ['.~, 't. (I , .,~¡ " )j,I~' tl¡¡~ ;~,;t i:herPrecoutlons,' ,'....,(.:' ·"";-:1,, I,,:" [','I 0';' 'I :,' : r ~ne. J'?' ),1'.' " 3,:I!j'[;"~I';",:,:,},\.}..,Jl,"", ,':):, ,1:\'Jj;¡;¡:~~,¡.:",!>,::.. <~!"::\f !, :,,·....ri.. ,~.<~~,f~,:, '. ~;. ¡. .. '.' "~'r:'~· 0 .' '" ":'':' '." " ¡, .'.\<.Mr'~__ 1 't.. . ! }I } I 't~~ ~, ì"_i {.1; , .f . , . I I I ~~ ~I' ~,',' ;Ý\ft . r ?!¡lp:Utrf,¡ "\~:'t¡,1¡;;'!,: '. I" ,,' ;:Ji\'fr¡';~ir¡ ¡jeT '.':~TE.:iAL SAFETY DATA SHEET ; " ;¡.1 . ," "'¥ I.: ,,;;~ ,', ' " !' . EASTMAN KODAK COMPANV . '~.'; i:!,~¿'.~.!:~,'.. -:;,~: \ . , 'q':;!1~:Ib'f; ';fi,:,;;;;i.,,::, ~,:,':;,\'~'" , "i1:J.¡-- t· <'.': . (~rtf~' Dat. . of: Revision I 4/09/90 ,¡'.: -;~(:t~ .. ...11..... .............,..............Ii.._............~ .......=-...........1:.=. ,,'I" ,,.', ' .' , . '.;;.'" . ." PRODUCT"INFOftMATlDH ..~ . .' . ',' ,< ............,.......................................... ........................ .... . 'f-I!. . " . ~ .' ': ' . '. '. - I' :.;;~;~tl.t:. Produot . H.",. . ;, KOD~I( CINEFLURE Fixer and R.plenisher, Part A ,', :;,:~:;~;?,~r~: Porlllula.. . . Aqu.ous Mixture . · tçJ)¡~:f: Kodak Cat. log NumberC.). CAT 116 '5013 - To Maka 10 SaUon.. c,jl';d,~ SO'lut1on Number 1 4'50 ; ., 'f'.- j- 1 ,:o~ ,:',4:;~$J ~o,d~~;;~~z.rd R.Unø Cod.sl ft. l' , '"",-vr(l1t . t·.. .d-..\"~~,~ .:t ._ ,," ('I,lii};'" " '; ~;i<f~t,1(:' Manufaotur.,./SuppUer. ... '.""",~'J.L.f. E..t",sn Kodek Colftþany ;~ : ,<!;\ÎJ~~,:'~; 145 state ~t,.a.t ·hr'i:.~~" Roch..ter iN.", Yvrk 14650 .'\ r¡:('~' USA ". ¡ ,', . -/' .'} t· ~ '. . ',' . 'L~;~Af¡ Forl.ergeney Info,.....tionl (716) 722-I1JSl ~~~~~¡:For,oth.r pu"p08ea, oe11 the Mark.ting and Q!stributiQn C.nt.,. In your ar... ,~~{~~;,.~........=..............................~......=....=........................ ';::~~~+w.t1t,;COMPONEHT INFORMATION " . . ,,·~;i~?~~?:.\,i,···· ......==.. ........~...... ...............'!'I...I:II.............. ..............~. : .:.î2Li.[:;:\;,W,;~:¡};,:¡:;~À¡¡j'~~:'j" > . . \ W_ightP.rcent - CAS Number Ace...1on Number ~~'t.If'V";"i; ,¡.,. ... i ..,'~ ~ ~'\, "H ~ I ,.. I:' I . ./ ,~ ·i""~~"!}': . ~";~~,".4"~V..r~ J7' t \ t.:.: IÌ1I'r,> ,):*;,gJ.;\ W.t.r:;t~;t¡(,,~:, ' " ¡', . '..40-50 7712"-18-5 .; 055290, :.~~~.~\~~ MIIIoniulÌ"thiosulf.te "<. ';' 40-45 ~ 7783~18-8';. 909586 ~,~¡;~~:', Sod!.... .v.tate · .\ "',:;" ;.,1 :::f 'Y', 5-10 127-D9-5 900227 >~~!~f~~:i-:; Ammonium .ulfi"_ ' :,:..;!' ! ':'1" '1-8 10196-04-0 063454 :.' ':~~r',~t;- Aoetio aoid ' ,~ ':' ,... 1-' 64-19-7 900761 ,; :JY~;;it i! ...............I!...............IIÍ.................~..... ...11.....=...···....······ " ",,j 'I' MYS L D TA '. ~.~ ¡ , ,.. ".p ICA A, "" "'\'. i ::'::':' .......................................~...................................... .. 'Arap,.rano. and Odor.', Clear to .lightly ".UOM solution, vin...ar and .ulf"r ;clioxld.::odor ' :};.;'. , . " . 1011in. :Point. :)', GT100 'CCST 212 'f) · . ,;VaPOf"'Pr...urel ' 0.. 18 mmHg 1,,20 'c ; ~Ive~o~etion Rat. (n-butyl eeetat. · I), Not Av.ilabl. ,,,-t: . . .Vapor:Dana1ty CAir· 1).'" o...,O~7.,:·, . ,I Vo1aUle ,fr.otion by W.ight. "..:.'50 ~ Speoifio·Gr.vityCHZO . 1)., 1.11,- 1.14 pH. .,' oa. ~ 1.0 ' . r. . , SolUbility 1" Wat... (by Weight)., ComPl.te . ..............II......................~...D............·..·..···.···.·II.R..==.. , ~.':~t~~'.' jil"';!;:-m' .\ .'. Kod~k Acc...lonNu",berl 3'5859 .j .' S,I 1 F. o o P f. C, '. " \, ' , ~\~, .~ .¡'" ~: . fJ :".~ "¡' ,'¡,: 4, ~ !... f'''' ~"¡t 'f' , ~?J ~.:~ :3!<'.?) t. ~'¡'~ :rm, ¡FLASH, POINT, . Non., noncilmbusUbl. ~ .. :IXTJN8UJSHIN9 MEDIAl, U.. .ppropriate agent for surrounding fire. t1~ í =:~~~~t:~::..:J~~~=:~:~D~!DURE~ ~ W..nol t-oontdn.d b...thing .ÞIi....tu. ~I" } UNUSUAL': FIRE AND EXPLOSION HAZARDS I' fi,..or .)tc...lv. "ollt m.y o.use i:r: :' prodùotle" of hs~.rdou. decolftPo.ltion product.. ,íþ if ~"" ...... ..... .......... _!II_ ......... .... ........... .............................. ¡ j i~i . ¡"'~¡f~ :; 8T · I,...t.r than, L Ti '. L..s th.n ' . ' , ~tji,' ":'~ ..~...~. ........ ......ja.... ............ ............ .... ........................ 'I' ¡. ~" ":,'/l.~.;' f1;.> ;,', ,; I ' D-II.DDS.-OOD ,~¡ ',-." ,~'.~.."r ' 't ,,'. "'., 'I' W iii \, fý'~~ ',,"';. "'.c;:';Ì(' '~',,: '., ,~", ,',.. , r\!'~; Ø~..f.~I..(f.~~' ~ ( (. ,; t1' " 'J. ' '1-00'· ... :.,,'f~~~ {.;:,!'~'. ~¡~~~~ - .....'" ~ 7!, . : ..' t·· - ,.1iI t!Y-'If\ f\¡~ ~ ,-.: )"t .::'~ 'f.~" ,', "," ~ ... t , . ~i! . -...... . ¡.!...)1;'".1 t ,,'!1. ~;!'f ~..r. 1 \} ';: . . . ~ t "~: ~ ;."~ t}í .~~.. ~$:~:';>'.f""~!}( ;c,' ... . "'~'r;;.\¥".", r;~~'f~ ~~i~_J\¡,' .... " . ',". {"~._:< ,1,,;<,'.; '\',. , ~ .) ;·,)if·:~~~.~;.~,~~;i~·'¡J~;~,~ .~.'-:. ~ . ..<~:.f"1.1i,,;~,,f· \1;" ..··"f:.t,.e, .,' '." :~. "'t·:t J.) J~ 'i.oIJ·~:j(ft·f!Ji"!~I-'J' '~.. ~FIRE AND EXPLOSÌON HAZARD ¡...........D.........................················................===..==== I ~ !, " '( . ~~' !):r ..:1 .~ " tJ", " , . ;:~; ",:, , ," .. , ¡ ,. " ~~ I 'I , , ¡ ¡~:' ¡·~'·J~.~~t~¥;:¡~¡:;]::::~:~' ¡:,.~./~';. .0 . 2 , I, t:r:lr,·¡¡f;1!1v. ,,¡, , , . , ¡. iß;,¡1~ì~i',~~~..~.:.~'~::..::..."...~.~~~.m~....m..~..m....~.~...':~.....m.... ' l!;t\,~!.· ""',,:.,,/f..'·-EACTIVITY 'DATA ,. "', .' ' .iþ$t-':I,fi \~I ,...." . .' · . : (~li~~1:'~it:~~';'..........~.... ............,.~~....... ..~........... ..."11111. II..... .....1111..11 II irll.. II ,¡~:;,~~..:;>,i,';.;i~~STAIILlTY' ·St.bl. . .'.... . ' , I;' '/:t¡~<:;:;:~.?INCOMPAT18ILITV. Nona with bommon material. .nd, oontallllnant. wIth which the \ ' i,. ':: :.:' ..r.;:,,; ..tari.l m.y r...'on.bly ODilia into cont8ot,. . . ,: :",~ f.';':"'';fr:.ii;HAZAlfDOUS DECOMPOSITION PRODUCTS. Thermal deoomposition lIIay produoe alllmonia l'f~:;.;¡Ñt'1·?;!~~.nd oxides of nitrogen .nd .ulfur. . 'f·:?~t~.&,ntCONDITI0NS CONTRIBUTING T~.HAZARDOUS POLVMERIZATIONs WUl not occu". ' :' >,¡.~:l,.f.ii¡!~~i.. ...... ..11." !!I I!I.. I!I. .. ....... ............ ...11111..11 lIaall/llIl=II..".." II.. ........... a= II aa.a ,~ ,,!.';~~:~;;;~f.i TOXICOL09ICAL PROPERTIES, . 1,'. ::~~~.............IÌI.............~.......~.......................................... j' .¡;..~".. ,: EXPOSURE LIMITS. :'.j, .. :; '¡'': Component. Aoetio Boid . <,.)" AC9!H nv. 10 pp",-TWA CAC9IH 198'-'0) : :, t. '1<':'; OSHA PEL. ,10 PPIII-TWA if tJ: J ',' , ' ~,'.' ' ",1 " EXPOSURE EFFECTS. ." Inhalation. Low h.zardfor r.oo"''''ènded handling. . ,," ~ . ',\,'j ¡.' .! ' . ,..' Ey... No .p.cific h.za~d known. . M.~ cau.a tran.i.nt ~rrit.tion. . " f : ,:",'Y:, .' ";'.!, ,. , , .' . ~k.ftn i, . Low hazard for r.oommandad industrial handin.8. ." . -;. t· ~: ,,:. . . . , :' '~'.:;(,;~,,:;,: )(;: Inge.Uon I ' E)(p.~tad to ba . low inga.t!:.on· h.z.rd. . ,,: ," '~f~" ..'. .' ,',...............II..lIa......II.a....a.a.......~...~................................. " "'t . " ,;.,;', :;,;';:F, ,PROTECTIVE AND: PREVENTIVE MEASURES ...-' ~- .....-;~,~ . '<.. ' ø . ~~V~~,'~· .............................................................................. "',;:/:i.{~\;; \ . VENTILATION. . 'ood v.ntUÎlltio"M.hÓuld ba"auffloi.nt. Supp1em."t.ry . , >:j!::(~,:\; ;,~.nt!bUon or respirator)' prot.oUon IIIII)' be n.eded in .p.d.l d...euma*.noa.. :{~/~~;J~\}':;~;~.;/ '. f' ':'. :... . . ".' ;,i·,;;~iJjt;"j;-;.Typ10.Uy, ,lO,.ciolft VO~UIft.. p.,. ho",...i. ~onddar.d lood ,an.r.lv.ntil.Uon. :;;~<j'7';l.::f!:':~.¡v.nUlaUon r.t.. -"ould be ",.tohed to oondiUon. ·of'u... "'\~;~:;::);i:<:'~ '. "h, '" ' .'. ' .' " . ;~~~:,ti~;r'i~~\!'~;, SKIN AND EYE PROTECTION. S.f.ty gl..... with eide .hie~ds.hould be worn In . t\l'ì~~:f:~':;~,\;:.! oha..!o.l h.ndUnsr. ,For oper.tione wh.r. ",...long.d ðr ".pa.tad .kin oonteat /,rr:í'~<~:;'§:lí~ ..V oeèu..., im"arv!cuI glove.: should 'be ~,rn, ". . .' .: " ..>! ::y.;n·;;;· :.¡,~¡"... ...... ........ ....... ............ ... .......... ..... ........ ............ II ....... ; fÇ,""" ,!"J ':;;'1;',. : . .,: ' . :~~. ~ 'h "MSTORA9E AND DISPOSAL '", , " "" , ,~~ ,~............................~...~~...............................~.........~.. '. f;' ' ' . " '," ,'.,. ',' ,. ,¡ r~p.Eç.AL STORAG~ AND HANDLIN8"PRECAUTIONS,. Non..' . ,: '.,' ;': ';~;){' t?,., '; ~J,~;!'-~il';: ;.: -. . ,I, ,i" ' ,.¡ . . . . ' ~ \,"; ': "'~',' . ..ti: ~ S"ILl~';'lEAKi AND1DI$POSAL: PRøê~DURESi,"Fiu.h ",.tertll:to, .dd .,,...:'.."ar .lith ~,}~l.rl.,.mount. of w.t-~.· Di.~~.....a, t...a.tmant. or di.pOI.l 1118)' be·~ub~.at to . !t;~~,\;;, fed.r.I, .t.t., or loo.l,l."a¡ ;,' " ' , ':"> , :< ~,~".:^Þ",J¡'..?::J;.~.~.t ..........~.......~..............ÌI.................. ....................... =.....' .' '. ~^T~, $~'.~'" ;t,... , , ,", ' ::' l.''¡;'~''.",:" ,~;,~~i: fIRST AID. . '., . . ~ t~f"'} . _:~rt'l\ ~. "fo'·l . . , , "::¿~"J,¡;;}:t i:¡. >¡:' ....'!"................. ................. .....,....................... .....11..... . ,¡;;~¡(~r.~4~~'~f':J;: E;va., ' An)' m.t.ri.l that oontlot. the.v- .houldba w..had out i_.di.tel)' ;k:;;!. ·!~f(;!;';;.:<::wi ~h, w.br. Sat ",edical .tt.ntion if IYIIIPtDIft. occur, " . . I d:' '1t~Ji!~:.k¡~:~'~ W.sh .ftar~ aach cont.ot~ . . . d' ' ,tr~:4>~~~1. :.:þ ^~'ì ~~.: r ,: . I . . .:" ~:'~~Jní..tton.', If .w.llowed, drink 1-2, .1..... of w.t....i,: S..k IIIIdio;'.'.:itt.ntion. . i ,I "" ,~~i';:':ftp>·!...................................·····...................................... ," 'J.;~tt1.1;~;:(Ji~~ " :;~:::jIØØD ·(lq1;J.:~'j,r1,},¡.\, 1! ;.__ "-<\/~ '.~' >~-:~" !~p~:'~'fr.ñt· ,,, , \ ...r; ~:'t.. ~ "d. , :".f\,', :..jJ~~.:r ~f P: .: . ':" '," ~ :-...,~. ',. >'.: ..';r ': >fí ... -f:f ..;; ~ 'f , ..... , . " ".t., o l' ~ " ' . . " ,~,;,: , . -' " o!' ~~, " ·..i \~~,:. :r',\": ('.t¿;: :~..( ':¡i . .( . ;~\~}'\'1'1 ''1 -: _,'.. '''~' t '!t \' " ,\.:' - :lJ.:;.......!'i .r, "; !...:'.'~,. ' ¡ _ "', iii . . " j . _ jr. ."..~~:~~~~~~'~·.~~.......SCl...~~~............=.........= =........". ........... ¡ .:(:~¡:, Þf!;iJ" ENVIRONMENTAL EFFECTS DATA , " ~ ,,' ; i,¡lii.::~~ f.,;1 ............................_........................"'1111.111.............111.111........ ! ~!.i ;¡:ir~t";1oth Th.l t 1 ' t ':...:!,l,~~;~'~;.'f ~. .n...iron",.n. .ffect. .UIllIft...y i. wri t .n to .Iud.t in .ddr...ing \ 'f}:~~?(!'~~.;'~ alft.r..naies o....t.d by an .odd.ntal .þUl, which Might occur during the ~ '~:"':'t~i:~~~ ahip",.nt of this produot, and in ".n.".l, it :is not m..nt to .ddr..~ .' , f:;~;P::l'"di.oh.,.g.. to ..nit.M" ..w.r. or þublic.Uy owned tr..tm.nt work.. , , ',.1;, ".¡.";;¡;,:....~Ì).,". ,,þ,, , ' ';!:' i1tl.~.''it!''t.,' ¡. ,:'...:' . . ~So~~:labor.tory t..t'd.t. and publish.d data .re availabl. fa,. th.majo,. ".~~:' oOl\lPon.nt. of this forlllulation. Although this 'Product, .. .uoh, h.. not b..n .'~~ t..t.d for .nvb-anmental effect., the 'dat., ..e"U.oned .bov., h.....· 1S..n u..d ,to provide the following ..ti.at.. of ,at.ntial .nvironment.l impaot, in the . .i~v~~t.\o~ ,an .ccid.nt.l .,ill iL~9' ., :, ' 'j 11., I ~'~~'<¡{",'(i~ijl'.;ç,.. 'a,'·;' , ' ,<;:;,;';.: .. " " " , , . t~ '·Thl.,;ohemiq.l fo""'"lation h." .'low biologlc.l' oXyg.n demand,' and it i. ." Y·"". aJQIeot.d to c:.u.. 11ttle oXYlen de;'l.tion in .qu.tio wet.ma. th!. ch.lllical.." " ..fo".uli1Uoni. .xpect.d to h.v...,!o" pot.nUal to .ff.ct .ql.l.t100rl.ni.0,:...,::-::,:·':,.- :'''eond.ry w.ste t,...tm.nt 1110,,00,,8.nl... and the g.rlllin.Uon of .om. ,1ant..~~T·: ";:",.. Iti. .xp.oted to have . mOd.r.t.:potentialto .ff.otth. growth of .0.. ' pl.nt.. The oOIllÞonent.,of thiè,ohelllioal formu18tlon ar. not Uk.ly to ~ biocono.ntr.te., A moderate Cluilnttty of this oh.mic.l formulation r.l....d ~i~)Jinto the .nvironlll.nt i. not: expeot.d to h.ve . significant iMP.ct. . ) t¡f-¡·······..···············..··························..........................=~ ilj~ TRANSPORT A T I ON ~. ".' 1 . .....................................111=.0=111..=................................. : For Tr.n.þo,.t.tlon inform.tion regarding thi.·product, pl..s. phon. the "E..ban Kad.kÐi.trlbuUan Cent.,. n..,...t )'01.1' Rochester, NY C7U) 511-9293, Oalr:lrook,' JL (12) 954-6000, Ch.",bl.., SA (404) 455-0123J D.n..,. TX (214) ..241~1611, Whitti.r, CA (213) "a-1I222, HonolululHl (101) I$S-U61;'" ....................................................................~.......... t ~:1~~ I!PERENCES""" . ~ ;; ¡ .' '".; , , ~_....................................................................~.......... ~~~~Unpubli.h~d,d.t., He.lth .nd Environment Leboratori.., E..tm.n K~dak ~'t:<:'\?f Co..ny, Rooh..t.,. NY, :~ ~~ß..........·.·.........······················~..·····............................ :j".. .;'~;_"'1~) . !;Ur<4; ::;H~/:PøEPARAnDH INFORMATION . . ~. ' ..' :1~,~~;}J.:~¡~ ........... ................ ......... ...... ..... II... II. II............ ...ellll II I! = II = = =. .". ~':-.J ~.....: éJ, _.'" . ,:2;;.iiN Heal th and Environment L.bor.to,.1.. t't,:; !f.i~;'~i E..tm." Kodak Colftø.ny '. . .', ' ' . . :;'~~'~;Ht~~~~loch..t.r" N.w York 14652-5615' .. , . :' . :'. . i{'J·:t·~ -'ii~~f:~'.... .....BIt== .......... ......... ...... ..........'...... ....11 e== =11 II =.....0 1:1. .... (:~¡.i,~,~'~:~lr~~ The infor",ation cont.in.d her.in i. furni.h.d wi thaut werranty' of any kind. ~;1~~f.~~;~ŠU.er. should consider th..e d.t. ònly .. . .uPÞlement to other information ,r~:f·X:¡;},,:,'i'-'(.;.,I.th.r.d by them .nd mu.t take ind.p.ndent d.t.rminations of the .u!t.b!~1ty ~r~;t1~t~1'~'f .nd colftpl.t.nessof inform.tion frolll'.U sourOD. to...u,.. p,.a".,. us. and ',:,~r{;',f f( di.po..l of these mat.,.i.l. .nd the saf.ty end hee1th of .mp1al'... and '~:i':"!~tH,y~~ cu.tom.,.. _ . p ~ ; '-,..... ,~t,f _' 1~ ~!..~~ ,., + ,~~ ~~.I~I.......==..............II...II................................~........DD........ ;j~t.i..;;ft¡~~f1} ;, . :i~::;Š500D ~dj.....: ,., ;(.~~\~....~'>:!..ii:.~¡' Ii.. ;r ~ ,# ~'.~ . '\." '7~lt~~ i'!ß;n\~: : ~, . ".' .-(. :'4'~ f:f :t~:,t.1' "'¡,.- ~j;1t;.?,I'i'~~;' . , . '¡":,,: "tv/' fAl-~~·~f!t·; \"~.f I ~ ,,~- ~./f,f. '_·J..F/~.1FJþr.;.l·"Ji...: !,'j~,.t '. ~. ¡:';~ '"0" j&'~' ,-,.¿1 . ~~.::,....~. ," . ¿¡,;n ._1t ;: ~'r'~ ¡ ·l~l. ,', (.....- /. 'r .{' ~~~~.<., ~.!" }ir·:!!if }~',~:.~ . ;;~:·A:·:~"i:~t.·'~f~' ".Ù. ; :}~::.:¡ \ - .~~ . ., i;.' I~.- ~ ~;..'i. ·~4,,:;i)"..,~ ·-':;i.it~l<,·~. . :~~J,?~!W~~F"· ~\ t~·~:,~~ .f-.';j.. ~ ~. rt.;i< .~ '~.'! "1'" ;.-~ ·::<:·'t, 0,~ ·1·-t" '.::~~··.1~·~~ j.' I: ¡ . .~.. .... , '" .. . .. , . .' ,.. ,.'. . 'I~. .,,:.: :'. ;, :'-:. .'~ '" " " .J . . .~ I,: .: " . '~I ,;" ~ ,: ~ , '), . I· 'I ir~ ".¡' . ;i:l,:,,:t¡~iÍ¡~f ¡:;~ ' .~¡~ì~æ~i1'~" ,'; ,HA~~~~N ~~~:l~ ~:~:~EET ..'. . ,:¡F':¡',' 1\ . ::}!~1\N;{~~t.;~; R.ýi~iDnl·" 7/02/90 .." Kodak Aocess1on Numbe,.. 3~5n4 ·;~~~~.........e.D~...D.............................................................. * ' .~ ;:~'f...H'''',,' . :,':;;ì~(i~'PRODUCT INFORMATION '. . .':'. .' . . t:~df;:!'~~ ......................................... ...... ... ... ....... .................. ;:,;~ ýf'~~~ Produet Name. KODAK CINEFLURE Fixer end Reølen!.h.r J Part B .. .~Formul.. AQuaou. Mixture ' ., .. : ,¿:;:~".:.~ ' .:,kodak C.hloIÍ Nu",b.,.(.) I CAT 18' 501~ -'To Make io OaUons. I, }>;1:~;,:~~y·S01ution Number. 4SUS . ~ ~ ' ¡: ;~7þt~;:;!~~~~~;~~.E.rd, Retina Code.. R. 1 S. '2 F. 0 C. v:¡ . " :ff.:~~~Þ.i.i.t~¡~; Menufeetur.rISuppU.r, .1., ~:a:"f:>::1 ,~ <Ef(~;Y~; I..tm.n Kadafc Camp.n)' ':'.'~:6:1,:\ 345 State street ';i:r~¡~~ Rooheat.,.,Ne.. York 146'0 ;, ~ ,¿;,\¡r' USA,' '. ~,.\}~(~.t~" Far Emergenoy Info,.mation. UIU 722-S1S1 ;';', ,: ~~(Y' 'Fa... other purpa..., caU th. M.,.k.Ung .nd Di.t"ibu'U.tln Center in )four aree. . 1""\ ',,: . .,;~~~'_.......................................................................D.....~ ,,'t€~¡:~h;;;'CgM lDNENT INFORMATION . . ... d ~~1''¡.~{J\.~· \ . ' , ',:';!:~ttl ':": .......111.........,.............. ............... ........... ..................... .;ot}'>:i¡X:::.,.~:Ü:\::.~~~;,"~ -, , Weight P.rc."t CAS Numb.r Aee...ianHúmb.... '}{~f/ .\4J'·...t;~\t jf,;'··ët., ~Jr"/;~' . ~~',,'; .' , .~ ~·..;~1t,r~;~;...- ~. "t .~. ~\)j'~¡¡:}..~ :~.- ", , ¡,,;~~?)~'~íj,~ Water:.-,t¡~'·" ".),: " 70-7S A 7732'-18-5 :','~:,'OSJ2'0 '. . >}" ,A1u.lnulI .u1.,.te. n-ll' 10D41-01-5 '," 907954 ~ ~:~¡ ,',.Sulfuria aaid.. ~. ' 7 7664..,a-9 :":;, ,907411 .; Î'~~J~.t ;æ1tr~:,i~i;·'.~~lr~'<:;i .' ,~j./~~ .,;;}I::: . 'f;,' /,.;;~j5~¡f\~<fiJ:i1ff.í~~J~":~';."~~;;'ir' ~, . I'," .Prindp.!· H...rdau. Call1pone"t<.) ".. :,'" ," f1¥I>:~ ,_Ch.mical subjeot to the reøorting reCluirement. of SeoUanS150f Tin. In,: (. ", i¡''Jf¡~ .of .th.. Superfund A..."dment. . Re.uthar1IE.Uan Aet of 191' .nd 40 CFRPart 572..,'- ..;' ';\~ ....................................... .....................a....~.a.a... ......;'" '" '" \ PHVSICALDATA . ... .'1' . '.' '>. '." ..............................................................................; . ;¡., , . ,ç,'" ,"; , . " , - < " " >~, , , , , Appe.r.ne. .nd Odor. Calar1... .alutian, odo,,1e.. .0iUnll Point.' 8T 100 C ( 8T,212 F) VàÞor:':Pr...ur.. 0.. 18 mmHg a'20'C Iv.poi-.Uan R.t. (n-but)'! .c.t.t. '. 1). Hat' ,Availabl. j. V.øarDen.it)' (Air ., 1), oe.' ',0'.6>: r Vol.tn. Fr.ction liy W.tght. 'è:a.· '15, X 'iSþ.oific'B,..vit)f,(H20 '. I). ,1.17 f~/. pH. \. LT 2.0 ' ~i~:SalubilitY in Wat.r (by W.ight). Comølate ·~;~...D...====a=..=....=a=a=a=.........~.=.....······............................ ~~FIRE AND EXPLOSION HAZARD ~......~.........e..................................~.......................... ,FLASH POINT. ND".,~nQncombu.tJbl. ,EXTIN8UISHINe MEDIA. Use Il'l'rol'r'Sete Iglnt for .urrDunding fire. ..,'.. ; 1SPECIAL~FIRE FIeHTING PROCEDURES. Na,,_ ~ U.NUSUAL· FIRE AND EXPLÒSION HAZARDS. None ;....................................................a......................... <,".-'t' ., t, ". \ . " .~. : ..~................ ............. ..... .... ........... ............... ... .". .......... ;'f ~.....~...,....~,~...)'~tz'd:'.1 J:'¡","\.;.. ',' ': .... D OOOS IDDD ,;,"f/~:~'¡1.~ ;l~f. :~~. ~:~~j:'-t~¿ . t ~ ~t:.: .~ ~ \ .; . . !';'<~h-~ t't"""'J'" 't'>'~f"ff}t..""t\ .~ ...../. 81 0016 '~·:.¡)· ~~"'~f ~I.'~:~......~',''';:>,.;.{.·.!;,', ' " .:.., ' . - -\Ii' ::':~~~'i-f~'l >~'p'~:.Y7}-,.j ~.,,;, :.~ ". "1., d f. .~... .¡ ,..,,,.>*~ "~~1..~:.?-~~~.",~r.~,' . : ~~;:j!¡:,:;"))~'f¡",~;;:" . ~.. 8T ~. er..ter thøn, l T · L... thøn . t'· ",' !.~;" 1r-t;J!I.'il"~ f.~fi' .~¡' {t.'·~r"";·\,/ "~f':I;\,' .' '~j rliÁJnI"''¡~I'¡j'{''';''i "~·r,"'r"'I\.!·L..,t.:"" ¡, ,,' ,',' 1· '1 ..¡ p.r'''" " ~ 11\ "'l'!:;'\¡':A;;\' ;!~í. ,¡.::,~,~;,~':;,t;. ! 'r; ¡ .'1 , ·,'V'!n;:·.~:'·,· ':',;: ;:~:i·.;?\..¡~,:~:~{1~:¡1~.::'ì.!,!> 're, . . ~ "; '.y'.r'?}.;S;'·· '.". ,.:"'. 1rlj'«:~{t~f(V":""";~'~"'~;:':'~ , "..,,~l~~/.';,,), ...:''';', ~i·"I' ",·..I:";"I"~~'¡";' '2 " .:,,:;,:,,',~·:::'tf··\,:':;;':,':· ;J ;, .;..,.'" ,"'·;:;,f":/~·;~';'·'.'·~·;·>':;'':~,;:\\;' " :1' ~.' </ ;~';', ..............."......IÍIÌI...~_~.~~,ÌÌI........... ........"... ...... ..... ........ ...... c.:';:~ "R!ACTIVITY DATA, , ':, \" " ;,' ;,~ '..'.,,' , : · " , ' .. d"'''¡ "¡ '.. " ' . ' ~~2 ~~........III..............~··~···~~~···················..............~........... ':. :i' :'·\th,,,A.''\''.STAULlTY, 'St.bl.; . . ,\..;n,;:p;.;;;' INCOMPATIBILITY' st......b....' , ' . , " ,..¡t\~1t!?% HAZA~DOUS DECOMPOSITION, PRODUCTS. Non. ,.\'!:¡~'t!';",:,;:CONDITIONS CONTRIBUTING TO HAZARDOUS POLVMEIUZATIONI .Will not acour. . ",;;'(~!~:';:~~l.......· ...". ..................... ....... ........ ................. .... .......... <. . _~ '.: _::~ ..l..~,;.:.. ·t' ' .. . -. . . .; ;'/¡r~~rt,::TOXICDL08ICAL "ROPERTIES . ..", . ..'. . . . .. !;". '. '. . i'.i:;/;tii~.it..................1I II~....III.... ........ ........ ....... .....................~~~. ,........ i, .;.:';:<;¡:~i~f~ntJ;;EX..OSURE LIMITS. '. .' '. '.' .;,',. Ç!.,,":':';;; ..' ','!:':V'~~i~~;~;\Compon.ntt. Sulfurioaoid . " '. . . . fi" . '. . ~'.'~~:k'·> ACCUH TLV., ,llllg/m5-TWAJ Smg/IllS-ST!L CAC8IH 1989-90) , ::,r:f'~;;·')·...:^ OSHA P' I TWA : ;¡;,'~'f~%:M¡':,;; . .E'-' '. 111/115- ,.'. ;',.1';~,!.<t.I't.i¡d.¡j.'~.: '.' .' ," )" .. 1 ·..."...·~P'.f .,..w;.'f" ~: ',>.ç~t.;.',;};f:'f;:, Component. 'Alullinum .u1 fate' I l -' ,t_:! '1~ þ"" ,1 ,." . . ':~~~:i:'.::~ ACGIH TLV. 2tftg/mS-TWA (ACSIH 1989-90> : ;~.'r {';'1.'. OSHA PEL. ' 2mg/m5-TWA ' . '~i'~i){~~t~r, .' ~W{:' .':. EXPOSURE EFFECTS. ..., . ,i'~·;}.:, Inhalation. Low h8zerd for. raeommended handling. '¡!::'~:~/ ',~, . { Eye..' C.u.a. eye irritatiGn. · . . ~. ',r, "Skin. .rralonged' ar rep.ated _in oonbct causes Irritation 0 ¡. ,~ :. j:~ .. , ' ~ ',; Inge.tion. May.oause irritation or burns of the ..oph.gus. ..............11........1111....................11.........................118..... ~( "ROTECTION AND PREVENTIVE MEASURES "'1 .",¡ .,;' .,.. 1I..............·····a.II.~..........········8....==II..,.......................... , 1 '. '" . ,<;)' ";,;' VENTILATlO'" 90ad gen.r.l .,enti18tion should be sufficient. . , t .:,¡ ,: .,', ' 'i'i.i,¡i(¡~i,!:· . SKIN AND EVE PROTECTION. I,"pervious glov.. should be wor-n. . Seof.ty ,laa.e. : ;}!,Hi~;.,:,\, ..i th aide shield. or goggl.. er. ..eaommended ,', . ~.' , .; ." '. ',.!¡;I' ".:,:'i, ............................................................. .....~....II.. .... . i' J ~. -i-' . .- , . ::;:~~':!~:.~it.. STORAGE AND DISPOSAL . , . . . " ' ;.,¡~,:.\;ft; ..t,,:J. ...... ..... ........................... ............011111...... ......... .lIa····· ... '-.~iîM(~ ;:~, SPECIAL stORAGE ANO HAMDLlNG PRECAUTioNS, " K..~ ..nbin.. U.~t1" ,alo..d .nd ' , .I:\:''!'~,,;(.II", aw.yfrom strong b..... .' >1.{'J"t-\!H 'r.:f"','t....,' . .'. ". ~J " )l ~)·"t;~,\,;, . ..,", j'~,~~~i~G;;~ SPILL', LEAK, AND DISPOSAL PROCEDURES. We.,. suitable pt'oteoUve .quipman't.~· -; U~;~:~J~,~~:t:.;~ Neutralize with baking .od. (sodium bio.rbonate>. Flu.h materi.l to s.",.'" {.~~i~£;:r:r;:>l'. w1 th 1ar,. amounts of water. Wa.h oontaminated .re. ",ell with soSP ,snd . ~J::/-::;¡r¡:~~;, "ater. Disohe,..e,:tr..tment Dr di.posal may be sub$lot ta f.d.r.~, .tata or , ,~, <.è,I;·'." lacal law. :' .' 'i . (~i'" . ']'~. · I ;';~:~~ L): :.', ."~:~ ' ............DII..............··························.......................... Jì'~':·:f;',¡: 'i FIRST AID, h , ' ' ....c.¡ ~'.~_ :' ~ ..,~,¡ , .' . r ~~;~~i)/~' :t~, ..."..... ......................................." ...... ............. ....... ..... ;í,~~:t~Ji~>:,r' E~..'· Immediately flu.h e~.. >with plenty af w.ta,.. for .t le..t 11 Minute. ("~:h'~"."f !: and g_t medic.l attent!ano ' :'¡:"¡;¥ '" ..,~ ..It" " . ift-. ~:/:~+~~'!.: l"r,;.':.) 1 \ ,,: .,1ft¡¡, , ::::~~{~: Skin.' JIIII"edi.t.ly ,wash' .kin with .081' and plenty of' water ° R.lllove ~~i¡ :', ;t~:· cant.min.tad alathing .nd .hoe.. . W..h oontaminat.d clothing bafor.. rau.e, ~~t ~~i~~~'Da.trOY Of tharaughly olaan co"taminat.d .hoe.. t~ ~; ~ l...;~;·¡,~i·..,~!~tJ;. f , ' t· t~ f4~'~" ~~~~...{;~ ,\i{t;f.~f . ~ f,,!',tf.;' " .'!\;:'(,tr ',,, <>J'''~ . " "'~r$!" ;~,:"'~:~f'~f~' ;~~,';.~:.: ~'.,,' , . ;~~i;h.:¡:;~j,~iJt~·· "J , J".'¡"~·r"l.:··~,',.,"'· , . ,', ' §..... .~,,~fl'..I~....t:t,!. ,1'_", -.4 »'.' , D-0003.800D " ,~,. 81-0016 ,','.,', : .. . ~. . '.' , . " ", '- , ,.... .,,~,¡¡,',¡,'.'!:,'¡'.,¡ Æ ":"Jt,'~,' ,'.";')':'" ;,r;-; T., ~.~":",i, ~::,.:¡:.:;:~.:,;',::,':.:.,',1"~'~'¡':':';¡':':':':'~'¡;:"'~t':'r;""" ~J., tt ~'i' . o·-¡; ",.i.;¡,.¡ .,~q,< ...;;.< .~;:.,." . s .".'ý:: '$\.i~;·!?: " t":.ltt~~!j¡{ '1.>'·~ f". .,'\"." .", .i', :,,/:,(, ,,;, .?,¡ ',' . ' ' Ing..t.lon. '1: If ...allaw.d, do:NOT .Induce, Volliting. Immedi.t.1y ,iv.'victim e'" :,1... of water. Nevar,iv.;.~thinl by'mouth to an 'fnçCllnsciClluspe~.ôn. c.u, r; ,:~; i\, ~\" ph¥sioian. or poS.O" contréÞî~ó.nt.r' 1111111.d!.'bly. ., "-. !" '~: '~j{~' ............................~~~~~~~~................. ........a....a.~..........~..';,::',. l ',. ~·~·.Ì\~,ENVII0NMENTAL EFFECTS DATA;"/.·:::~;:: }">:;":'" ' , ',.","', ,,':.' ~ ÙT¡r...1 '~·iy.Z~ .................it........~.;.;~~~;ÌI......II...~... .......... ..........~..........'." >, \;:-~~~t ·~~:~fThi.' env1,.onlll."1:a1 effeot.;"ûiftlll.;'~ i. written to a..i.t ih addr...!nli ," ':,;» 1,.m.r..endes oreated by .n accidental spiU, whi"ch might ooour during the :l; .!,Shipment of thia p,.ed'fat, end 'in '.1'1.".1, it!. not meant to addre..' P; ~;U~ diaohal",a. to ..ni tarN .....,.. a,. p'fbUoeUy awned tr.atment work..·" i~\.~l'l:~ .,('-~',...' ~. ~ # . ¡~.".' , '. ... . r' , ":'~~,~~, Sou l.bor.tory t..t d.ta and,ubUshed date' ere available foro }ha ....:for ¡", ~~;.~ 'oomponent. of thia fermul.tion. Although this produot, as suoh, he. not b..n t~;::\~,~~r~:f,l~ ta..'d far environ..nt.l .ff.~t., the dat., mentioned above, heve b.en ".ed .,;,~\r.t¡ ',;" ¡to ,,.ovide rthe followin, ..ti-.t... of potential envil"onm.l'ltel iltP.c~; in the :~.'-:\ ~."~~~~::I.~f an ~oaident.l ...:111, (1-4) , ' .tj·..~. ;.~;:. -~~.... '¿~1)-:' ~,' ,":t. _ . . :<.:: ';¡,,: Thi. chemiael formulation 1. a .trongly aoidio aQueous aolution, .nd this ~;;,:i"= jpropel"ty lIIay oau.e adver.e environmental eff.ct. if di.ch.rg.ddireotly to . 1':~ ~¡~the .nvironment without tl"aatment. It h.. no bIalogloal oxygen demand6 and ," "., ';::p it will not oausa OX2fO.... depletion in aCluat:1o w.t.ma. It la axpeeted to 1f:thava a ~od.r.te to high pot.ntialte .ff.ct aq~.tic crganisms'\nd seoondary ...~¡':41-~ .., ",. h<:: ..est.tr.atm.nt .io,.oo,.,ani.ms. The componenta of thia ch.mical "orlluleticn )~~\ ~£WJ~ a,.a ,\ot likely to biooono.ntrata. The dir.ot . instantaneous disohàr,a to a ~';;~;3~~~F\~'~~f!! receiving body of w.t.,. af an .mount of this ahe'mioa! fOl"mulat1on which will ,,~;fl~~l:~j' repidl", pl"oduea" by diluti~n, . final cono,nt,.aUe" of 10 ",saIL or le.s is not :,,; ,.·,.~t;t&,L;~'f.:¡' .xp.ct.d ta c.u.. an adver.e .nvl"ol'lm.nbl .ff.ct. After neutraUzation ":'~:~';¡t~{/~:~, .nd/Cllr dilution with a la,.ia amount of weter, followed bY seoondary "a.t. .'. ':;:~A~~l:"~? tre.t..nt, the eh.",ie.le in this forlllulation .,.. not .xp.et.d te h.v. .ny. , .<.j:~;~Y;'':';::' adv.r.. environment.l i pllot. ~~.~, .' ..............~............................................................... , . . 1 À~~ ~,'(. 'Q...~" 1'r;tJ.¡~:;£>~~i!'.,':;r TRAN~PORTATION ' ~~t~,,¡~···············································................................ ~ '. I." '. , , . ;:.; .,".'{ For Transportation informaUe" r.garding this product, ple.se phone the 1"';:-' i ,... Eastman Kodak ÞiatribuUD" Canter ne.,...t. your Roch.st.r, NV (716) 588-9293. ". ,,',i-.., '. O.k Brook, IL (312) 954-6000. Chambl.., SA (4D4) 455-0123, DaUa" TX (214) ,"Jt~;J;.:':';;;, 241-1611, Whittier, CA (213) 69S-5222, Honolulu, HI (808) 833-1661. " ,,:,'1', '¡Vf ',"';! .............................tI'................................................ " t1"!~.._r. ~- \,,, r " I." ·yj~<1~¡; .\.,~. REFERENCES . . . . } J7~;.'{r F :\" ....... ...... .................... .............. .a_= ....,eo.. ....... .... ....... ... . , :"'¡",j" . ' .' ;,¡,/; ,!,i:,,:i;:~.·l. UnpubU.h.d d.t., Health end Environment labor.tor1aa, E..tman kodak .\,J"ht,,/x.,., ;,." .,1'" ' .' , ~..::!ft~:1,''1I;OYr!\~ Company, Roahester, N.w Vo,.k., " ;,~~,t}¡¡~';~¡~,. :"J ii,l, :Û.: ; . ,. >}::({~~::i:':~ 2 ..'.};. BetteU~'. Calumb~. L.bDr.to~ie.', Water Quality .Cri teria Data Book - ,; ~..i~~:i;;,iv,:::;": j Vel. 3 .. E11.ote 01 Ch.M1olla on Aqu.tia Life - 5.18cbd D.t. frDIII the .,~\~r¡;~;h.",h~:X{j: L!te,..tur. Thro'fgh 19'8, foro the U.s. Environmental "",ot.oUon A,.ncy, <\::~t'~'i'J~o;\¡¥:'Praj.ct Na. 18050 ewv, Contraot No. 68-01-00076 May 1971. 'i\~~}~~f,;N~}1i ':' :;y " ' . ¡-f;;'~~~ 1~/~,~ S. i Kodak Publioation J-41 ¡laDS .nd CDD ef Phatogr.phh Chemlc.l., E..blln f]~;;\~~~l'i~;..~i.¡;LKod.k ,Co. 6 1981. I};¡"'" '('¡ ~,;, ",\.1' ~ '., .,- r .¡¡<Ili "", ,';'::~,' .: ¡; . "T.7\, ~ ' :d' .n.. , Vi: 4.~~~"ok.., J.Eó end Wolf, H.W., .'. aliforni., Publio.tion No. Ed.., Water Quality Criteria, Stat. of a-A, 1965. :: .. , , D';'0003.800D .11-0016 -' ':"f . { t.. ,! " ; ........,;. ; ~ :; t.. .\' " .. ".' " . r: .' , , ...' , , .' -'.. I " . , ¡ , :d I . 'I I' " I · ~ ~,~l~¡~. ~r '}~~.~i,,_-~ ·~;,f~~~~:;~;:J:t~~j:· . .: '., ".:'.I¡.-::-· ~'v:~i::i1;~~ '<, 'J~'>,' ~ ,~ ;' :L·)~#'~f.~~:~·N ',. .....~.. .... .:. :', ;. ,. I ,"', '~. : .' .' . . :, MATERIAL SAFETY DATA,SHEET EASTMAN KODAK COMPANY , '1;- , . - ~ ,-,. ~. p.:' ,. :. . , . i' . ~ 'L~' Dete of Revisionl Kodak Accession Number I 421764 4/17/90 ....a...===a=========.~=====....==a=========D====·============================= . .', PRODUCT INFORMATION 1.' 1 p ,.' t . 1 '. .; , ..., . ~ J ., '. ~. saaa=========================-================================================= . , . . Product Name I KODAK CINEFLURE'Developer Formulas Aqueous Mixture Kodak Catalog Number(s), To Make 5 Gallons Solution Number: 4864 Kodak Hazard Rating Codess o and ReplenisherÞ Part 8 ¡1 i ii, , CAT. 157 5224 - To Make 10 Gallons; CATf161 9840 \ ;. '.' '. ,\ ." ,I: s' ~ " ( Rs Ss' 3 F: Cî 2 o .;,(, ~ '.:.\.' .~. Manufacturer/Suppliers Eastman Kodak Company 343 State Street Rochester, New York 14650 ' USA , For For "'. , .,'. .. ' "',' "'" ; ~.,. Emergency Information I (716j 72~-5151 . ~t~er purposes, call the Marketing a~dßistrtbution Center in your area. =.=============================a============================================== COMPONENT ,INFORMATION ,t " .===============================.==========~================================== , ,. ,. ':~"''''''', . Waight Percent CAS Number ' Accession Number " \::" II" 'i <"·,~..l · -~' :-: {:,;' .~, ': L . ::~ '~.;' .~.~ , . Water ~j.¡'. iEAceti.c"ecid, ',' .:',. 80-85 '15-20 7732-18-5 .- 64-19-7 '.'" , . 035290 900763 ",; ; , . ;,~ ., " . .'~ !..' ¡~':'" fS. f':', t~:t " . r , t't 0 , '., j ft·) :...,' , . . '1,\)., " ,..: iEPrincipal Hazardous Component(s) : " ..............D==........====.=========================_==_a==a=aaa=========== - , , ' PHYSICAL DATA",'-" !'".,."., . ' ..¡,", aa.~a.a..=.==..===...=a.a====.=.==========~F=============~a=================== ...;. Appear-ance and Odor s Clear, colorless solution; vinegar odor Boiling Point s GT 100 C (GT, 212 F) ." d"':, . r ..", , Vapor Pressure I ,ca. 18 mmHg a, 20 C ;'" . ':~~/';;~;'i~::' Evaporation Rate (n-butyl acetete .,¡) I Not Available ' " "':;':P}~;;'>,Vepor"Density (Air ,. 1)," ca. 0.9' -,t ' \ ,.,,' t.i':':"'\ ,·'>~:;:"~~'tVol.tile Fraction by Weightsce.lOO" .,',", '. .:~,·'i/~;:\;:SP'eei fie Gravity <H20 · 1) s L 02 ~ )~;;~' :i;'!,;'$: pH.:" L T 2.0 · :'. ,'. '..:., ..1'\'J'~~~t'~' ',t ':' ,¡'~ . · :'::,/f:;:~",; Solubility in Watar,'- : Complete, ',):-,;,' >:". , . ~ , ' , , .........=....====..........=...........=============================-======== .....' "i~}(~'... ~ª~::g~~~~:~g~~~~;~~~~:~~::i~I::r::::·:::·:::::::::::~:::::...1.......... , ¡Iv:, SPECIAL FIRE FIGHTING PROCEDURESs Wea;' self-containad breathing apparatus , .)~!i:~ end protectiva clothing., , , , ~,~¡¡i\ ,J;, ',UNUSUAL FIRE AND EXPLOSION HAZARDS I None. ¡; , . ; .!.I~~~~I}·~t-~.~ ~',::;j :. .........a = = II == = ~ = = II II B_a.. II _.= =11 ... a a=D == I: = = == = == == = = = = = = = = == == II.,~ == II I: 1:1 == == == == === = = = = \ .J!¡. rf.!~ f .. l, '. - '. .' , ;;!'tP '}f' GT',.; Greater than; ,LT. Less than ' :,ì! . ,I :¡ d'.;f";' :';.. . ! . I , "'; . , ' , . :~:.:_ ,h ~ i '~'i .........aaa ======........==a...aaD"D.===e==== == = ========o..a=...=....._==a==== .' ;,~\\' >, ;.,' ,>, ... C-0016. 9508 , ··t ~ 82-1314 f l: ' , I, r , ,. r i, .', ¡ \. , . " ' : ' (. " . p~ . . .;,;;¡i I., .), :,' :\:,'::~":';, r'~'f"~' :, :"1 ," ,I , " , .' '~' '. ~ .' '. , .~ " " . " ..' ~ '. , , , ' . -t~ , , ,I :;.\f ., t -,' , ~ .. ..;,~~ . ,. . .- .- · )", 'i , ' "'..;:3{,, j ~\ 2 .......a=====================a=a..=========~================================== REACTIVITY DATA " . . . :\:·~'··3,,:.:: .' .........II.===~CI =.aa_a=:a ==I:I=a:à.~...a= a=========== = ==== = == = = ==== =========== = == · . .'. ..' ~' . ,(.~t-,~ STABILITY,' Stable . ,.'..;;:;:. INCOMPATIBILITY I .' stro'ng oxidizers, Strong elkøU jl' HAZARDOUS DECOMPOSITIOK PRODUCTS. None .~.' . . "~~ CONDITIONS CONTRIBUTING TO HAZARDOUS POLVMERIZATION: Will not· occur. .' , '..===~========================================================================= TOXIC~LOGICAL PROPERTIES I , ¡"', . ."" . ¡. ~'\,.:.. ';'>:' _a.. == ~o= = = = = ===:: = == = == = = == = = = = = == aa= = = = = == = = = = = = = = = = = = = = = = = = = II = == = =::F =s ==== == = = = = . .,' r....·\::;,~):, '. , ", \ _ _ , . . : .;",:f.;:.:EXPOSURE'.LIMITS.'WI. ,.:...~ I,' ,11 ',I ,I," ;! ,II' \ ~ t~' '; ", . Component.' Acetic acid . ,":' r . ..! , ACGIH nv.' 10 ppm-TWAJ 15 ppm-STEL CACGIH 1989-90) ,"ò' ,.' OSHA PEL. ,10 ppm-TWA " ,Ig."·,' I , .,,_....... ....~~ EXPOSURE EFFECTS. Inhalation. Vapor may cause upper respiratory tract irritation.' " ,,' ' !; .~ I , ' . . '. :' Eyes.' Contact with the liquicf:"c,â~~s eye burns. V.por . may cause eya '''::-',.,''~~rritation. . ""'\:;~}~'\:~., , . . ,.,,~~\,,' .' . :' ,I, " Slti~i,~('Prolonged 'or repeated 'skin 'èoritact m,y cause skin :irritation. ;, l' 'I ;';::\.;i·\<-~-.' ...;/~~,~~~-~ti.1". \\r.:.' rt . ,t~· . J ~ .;'::~:\: ,".. ... ,~. -~·"'~'~f:·.~.·tfi·lnlÍ..tion t Mày cause burns Dr' "s.Vere irri tstion of the gastrointestinal ~. ';~::~~i:'i~': trect..~ '*;(1 ~ .' '" -" ~,.., ., ' : '''::~;~(::~' '''. A .<. : :~-¡;~ ;,';'~:'., ............ ... BIID... saa ~ .....~.·I!I......c ~.==a == = == = == = = = == II = = = == = == I: iii II a= === I: = = == ," ':í.:~':,';''';, PROTECTION AND PREVENTIVE MEASURE'S ,.' ,1 " . ,..' , ".' , ','1/.,'1:: . . .." -' ¥; :: <~~~:,,:~\'" ......~..=...==IIDa.........................=a============================_=======. . . , . ..- ~ , " -Typically 10 room volumes per hour is considered good general ventilation: Ventilation ratas should be matched to conditions of use. ' ::: t,VENTILATION. Þ Good general.. ventllationJE should be ','- vent.Uation or an. enclosed handling system may be contamination. ,".', r '" I : " '. , used. Local exhaust needed to control air . ; 1!< .¡..~ '1:' 'It ~~,. ;' ., - r ,-" 1.~ ~ , .' .... " " ',...J : , ' , ;- . . '.' 1 . . . ~ ~ T . , An app'ropriate NIOSH-approved respirator fo~','io¡"ganic if needed.: ,1 [';'it('4",;, ' RESPIRATORV PROTECTION, , '··',;:.;<'·;'"acid ,vapor should be worn ~.., .~.>; ".,,::"~.:,.. . -. . . ~..--¥~.;.... ,.', , . ;>{:~fi~~"SKIN AND EVE PROTECTION, Protective gloves should be worn.' Safety glasses 'I",:;?>~: with sida shields or, goggles are recomme~ded.; :.'; -., .~¡~:j ...~D.=.=.=====.====.========a=.=.============================================= . . ! . {'; \' ~.: . '-, , , . .,.... ~ . , . 'to A .. ..._ ;- ... ~ " , · '- . " .'''. STORAGE AND DISPOSAL ....==.a====================='======.===================~====================== SPECIAL 'STORAGE AND HANDLING PRECAUTIONS: Keep from contact with oxidizing materials,. Keep containar tightly closed and away from bases. ':, ','" , ~.~' .ft~':;' ~ .. SPILL, LEAK, AND DISPOSAL PROCEDURES. Neutralize with baking sods (sodium bicarbonate) . Flush material to sewer with large amounts of water,. Discharge, treatment, or disposal may be subject to federal, state; or local laws. a=== 1:1 ell: s:== = = == =:: = ='= = = = c= = = = = =e all''' I: aa=:I = II = = = =:: = = = = = = = =' = a= ::i.= === = = = II = = = == = = = = =:: = ,.,r i.';1t<"":'; -. . C-0016.950B , '82-1314 , , ~ ~ .~ l"'lt!-"'t' "":- .,.: , , r.: :' t:!~ ' ~ì J r· ~t ..',~ l!'f!' ~"...\ '" ",. '! '~, ,. ":.... .. " .., . , , ., ',-,:.i . ~ - '. ,'.' _',"1' , '- ",' 'l .' .' t h J, li J :, ¡ '<I . ~';';~ ,""j ':{i: :';\; h; 'r:; . 1..!~ ·h . t ~ "'1 ,,';, .~<:J;~' . ," .;+f?;~;:~ '. ' ,,' '.,' .: ,:, , . ~"""';';Y,."~,\:'!'.~.: .,' ," 3 '¡' --; ;,'<~1~:~' .~.: .. ...' . .:; .>','1;; . _.j >, , . ,',,: {\: '., ................. .....ct.... ....~:ir...... 1:.. II ... a 11..= a II =a= 111= =a a === =. = _.= II a= II = = =. II ~,',..i<:,' ' . .<-:." , ,.':.:¡J<¡<'~; '. I ,,'. .,' '::':V:-': FI-RST AID '" _i"·.'::,'· , . ~ -. ~..~ ,. . . , . -. . . :~'~:j¡:";-i. ,.' ...........=...11.. a.a..aa_ II. .a.'a..a .aacr..a Daa II == == 1:1 I: II = III II DIIIII=== II ==== ..a == II = = == = =: II ,:::{t;?:'Inheletionl,',:Remove'from exposure, treat symptomatically,'and aet, medical' " . " , t ·;;ettention. .~ . ",j'''::' "";': ¡",' ,::'! :' ,,' );. ,',"{~:~:;<'~;:I' . :}.~ ,_;·1','~:'\._'-·' , :' " ,~....~_' '-',,':-, J' . ;:"', Eyesl·;:'.'Immèdiately flush ey.s.:,w$.~";plenty of water for at least 15 minutes :, "·"".nd ge"t me'd1"cal att· t" ·"ii~'.c,·t:v':~:<'>"· :',,,' !','~"I , "':';".; "...~ ;-': '. en 10",. :.,I··.,;;::;>.:i:;;:'';:;.:'¡;.. ' .f ":,;, . \' ,.1' .',: ':.J :::~':,',.;':,:: ~";-:;__ . '.' ,," Skin I Flush skin With'·Plêntý:r~f?;·"ater for at least 15 minutes;':: ji; " ,f:J!~' Hr' t ~ ,, t':'! ~-. ." .~ r . ~:' :>':'~""'~' ~ !. ' , ~ ft J ",' IngesUo,;',(: 'If swallowed, do NOT induce vomi Ung" Immediately give victim a ": .~." glass of water. Never give anything by mouth to an unconscious person" Call .,' a physician or poison control center immediately. .. ., ,.{.~: . -, . ," -l - .~ ~ ,:.(:":,,'~. . '.' ...".... " e:, ...==...===========..====a=ca.m..=====================ca=_=a======_aa========: , :;·""~f.' . ENVIRONMENTAL EFFECTS ,DATA- .. ~ '. .....aa..====.=======a====aea.Dma..==.=z===============a.a.====aaaaa....a:==== . " This environmental effects summary is wri Uen to assist in addressing\" '" " emergencies created by an acciden~al spill, w~ich migh.t ,occur during:the,' ¡, , , ': : _ ", shipment of this product, and in general, it is not meant to a,ddress < : 1 discharges to ,sanitary sewers or.publically owned treatment' works.· ,,: .;'~ . . Some laboratory test data and published data are available for the major components 'of 'this formulation.,: Although this product, as such, has not been tested f~r environmental effects". the ,data, p\entioned above, have been used to provide the following estimates of potential "environmental impact, in the event of. an accidental spill, (1-8) , , ' .;',: ,¡ '! ' , " .1,. \ . I : This chemical formulation ~s a strongly acidic aqueous solution, and this pro~erty may cause adverse environmental effects if discharged directly to the environment without treatmant. It is expected to have a moderate biological oxygen demand, and it may cause oxygen depletion in aquatic, systems. It is expected to have a low potential to affect aquatic organisms; secondary waste treatment mi~rooraanisms, ånd the\growth of some plants. If . spilled on the ground, thi's formualUon is expected to have a high potential to affect the germination and early growth of.some plants. The chemical in this formulation is readily biodegradable and is not likely to . '4':),p~'F-' bi.0concèntrate.. After dilution with a large emount of water) followed by secondary waste treatment, the chemicals in this formulation are not expected to have'any adverse environmental impact.' ==========================================='=======================a=========== TRANSPORTATION ==-===========================-.-=====================================:======= For Transportation information regarding ihis product, plea~e phone the Eastman Kodak Distribution Center nearest you: Rochester, NY (716) 588-9293; Oák Brook, IL (312) 954-6000; Chamblee, GA(404) 455-0123;, Dallas, TX (214) 241-1611J Whittier, CA (213) 693-5222; Honolulu, HI (808) 833-1661. ' ==a=:====:=============:====================================================== ',' ~ .::. . , - , ,. '.: ':;, " '" .<::f;\..t;.t'.~ ,.', 1 r:':~;1~ ,': ¡I. '<:";: H;~ . , ~'. C-.0016" 950B 82-1314 '- "'\ " " ' 'þ " ' , ; " . , '". " '. ,,",:."-; :' ~:jII¡ , _'¡" '.., _~_, l' " ;~",' ):"~i;¡! ;' ";, ',f- :',\i:~' ',(."'f; , . , , '~', ,; ., .' ',' " " j. ..' "",.-¡ ~ ',: 5 ... .1 " ,'; "1 " ., '.'¡ · j .t : "; "'~ '~J · ~. : ~ . 'b '.-. , . ~':.?: " ,or; : ';)~:~ ~ 1 . ..... ".".{';' · ~'. £. ; ~~~ t: ;~ " ·f >1'; '.' j, , , ~ il:::; I::' '. :"') ~R.L~ ~2dA{ , \ 0 . Bakersfield Fire D.t. '\-J Hazardous Materials Inspection Date Completed <{ - , 6. - % ( R~J 10 0 ~O\ pk;~~ O~. Business Name: U,^'ve"",... \ Location: 'tl~ \)J 0. its Plan 10 # 215-000"OOI1.ì~ (Top right comer Business Plan) 5 Shift C- Inspector ~ e\-\ 1 V" \ (... t, s 0 V\ Station No. Verification of Inventory Materials Verification of Quantities Verification of Location Proper Segregation of Material "'. '.' .,.. Adequate Inadequate R£C6\VED AUG 2. 2 '~ð~ HAl. MAT. DW. o [!1 [Jð ~ Comments: t'\\J~'o.~·Ic:. ^c:.,:! ~ 55 ~o.\\G'" Jr\J"'" '~t-. ?$U,--,lt {¿,¡,t~ !!I'~-çS~~ Verification ofMSDS Availability Number of Employees ~ Verification of Haz Mat Training Comments: U? o o o ~ o cg.. o Verification of Abatement Supplies & Procedures Comments: N o"'t.... \ ;<j~tJ Emergency Procedures Posted Containers Properly Labeled Comments: o ~ [M ~ o o o Verification of Facility Diagram tJo J.\o. jr","'" w-,\l ('C>lMfll~t""- fi- .~k.J Special Hazards Associated with this Facility: o Violations: FD 1652 (Rev, 3-89) White-Haz Mat Div, Yellow-Station Copy Pink-Business Office " -r-'-.-C-;. ..._...'.:'_.;'_, '''.;-,7':::-;-;-. _: ., _,' . . '"j" ..- . W '" '~'" ?I~,;: ."~" . ;". ." \,~:..};: .':;- .;.!'r'. - ':': /:,-.'~, .-- .~ .. ':-);,":_1,'r:~~-f"_-~-'''---~~-----" >.__ -,-,...-=-",,--"i: 'F:-';';' .'.:\r I II '. ~: -.... _. 1- ,-, ,. . ReV,jfd ~ l 1i7{)/!1t'Þr . , cJu.-L 7- ;2 7 - q ð, No tI ðUL.,' ' C~1LeI<iflh- '1 i/)vV1-Follf:l ûf) ft/Yle11 f fJJul1)Ílt5 i ·~r;~· ~1 ~ ,.. ~_.' ..... 'i' ~ ?~. ~). ~'~,,,,,, ..,..,.,.Iof ~;~¡¡;': ¡'" ,'" , \: \ ,')11 ~ ,; .J (..'()/,{ 'VIQ ',. , . ¡AM 'r-A . ,~"'-.H '" SERVING All YOUR RADIOLOGICAL NEEDS :5¡ ~ -\(cd.c¡t¿tS JA{'I~SttEA SALES & SERVICE Universal V Radiographies Inc. ~ u 0 , I 8 ~º,~I~~ (805) 398-0568 419 Watts Avenue Bakersfield, California 93307 :Sf ~ t?ðl) ~ "'-J 0: "'" .lo' .. . .1\ "' , , 4IÞBAKERSFIELD CITY FIRE DEPAR~ 2130 "G" STREET BAKERSFIELD, CA 93301 (805) 326-3979 RECEIVED MAY 1 6 1988 Ans'd. ........... ;'Y ID# /tG/¥ -06 ~ 5 ~5 Oo127B OFFICIAL USE ONLY !Bus INESS ~A.\fE HAZARDOUS MATERI ALS ~ CøM 3 BUSINESS PLAN AS A WHOLE FORM 2A """--œ &- :J." INSTRUCTIONS: 1. To avoi~ further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS )~ENTI~FICATIO/N DAT~ iij¿/" 'T:~' ." ,'" ___". :: ::::::: ~:~E::::':~?~ itJf-~:;;"-~~~~-"~ CITY: ~ej/'6f)-4/ ZIP: CJ3-¿o7 BUS.PHONE: (~~9'~-'~lcR '. _.- ", ~... ~ . _ .i.~ .'_. .~ ~. . ... ~ ,. - " .. SECTION 2: EMERGENCY NOTIFICATIONS , " In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. ' This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME ~ND TITLE S· ). A . '-../6 ~ /1."--> 'Ø. c3;::7 B. 0)~ ~ oe:"9f>.V'.s DURING BUS. HRS. AFTER BUS. H~S.' Ph# 39B-rs~ Ph# 3C\f- I S<..¡ ~ Ph# 3CfS-O'Sb9) Ph: ~/) - ~4L¡~ -. SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: B. ELECTRICAL: C. WATER: D. SPECIAL: E. LOCK BOX: YES / NO IF YES, LOCATION: \ \ IF YES, DOES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES .I NO FLOOR PLANS? YES .I NO KEYS? YES / NO - 2A - ." . . ~ t·- " , ' . â '. ~ --'., SECTION 4: PRIVATE RESPONSE TEfu~ FOR BUSINESS AS A WHOLE ~... /VfJl 'r'o¡. ';II 1-' ~ ~~<L v "-'" "N 0 N ~ SECTION 5: LOCAL EMERGENCY ~EDICAL ASSISTANCE FOR YOÚ~ BUSINESS AS A WHOLE J _~ } 'ð, ,,-"'- J air; ~= _J!,-,,~v~. ~.~ <:::"'-... M~ SECTION 6: EMPLOYEE TRAINING E~PLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL A~~ REFRESHER TRAI~ING IN THE FOLLOWING AREAS. - -~-, - ., '. CIRCLE YES OR NO DiITIAL REFRESHER A. ~ETHODS FOR SAFE HANDLING OF HAZARDOTJS :'1ATERIALS: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . YES NO YES NO IlJjIJ B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGENCIES: . . . . . . . . . . . . . . . . . . . . . . . . . . YES NO YES NO C. PROPER USE OF SAFETY EQUIP~EXT: . . . . . . . . . . . . . . . . . . YES NO YES NO D. EMERGENCY EVACUATION PROCEDURES:................. . YES XO YES XO E. DO YOU MAINTAIN EMPLOYEE TRAINING RECORDS: . . . , . . . YES NO YES NO SECTION 7: HAZARDOUS MATERIAL CIRCLE YES - NO - NONE DOES YOUR BUSINESS HANDLE HAZARDOUS ~~TERIAL IN QUANTITIES LESS THA~ 500 POLX~F A SOLID, 55 GALLONS OF A LIQUID. OR 200 CUBIC FEET OF A COMPRESSED GAS:,..... ~ NO I, ---ioh A) Sh~~ . certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 Et AI.) and that inaccurate information constitutes perjury. TI~LE2~,Jr DATE c5-¡-J? - 28 - '\ --" . 1 "- y..~~ . \ . . " ~ :; ~ - .¡¡ BAKERSFIELD CITY FIRE DEPART:ŒXT 2130 "Go. STREET BAKERSFIELD. CA 93301 OF?ICTA~ [SE OXLY ID# ------ BUS EESS X.·\~Œ: BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIO~S 1. To avoid further action. this form must be returned hy: 2. TYPE/PRIXT YO!;R AXS~ŒRS I:J ENGLISH. 3. Am:wer the questions bp.lot\" for THE FACUITY I;X1T LISTED BEI.mv 4. Be as BRIEF and C8NCISE as possible.· FACILITY UNIT NA.'IE: a.¿'/Vef~/ Êg¡'~/C.s" SECTION 1: ~ITIGATIO~. PREVE~iION. ABATE~E~-r PROCEDL~ES FACILITY UNIT:!: AJ /,4 . '~'. ,'.. . SECTION 2: ~OTTFTCATTû~ A~~ EVAC0ATIO:J PROCEDlKES AT THIS l~T~ O\LY /IJ/;J / .. - ,3A - . . SECTIO~ 3: HAZ¡\RDOIiS ~ATERIALS FOR THIS G~IT OXT..Y A. Does this Facility Unit contain Hazardous ~aterials?,.", YES XO If YES, see B. If NO, continue with SECTIO~ 4. B. Are any of the hazardous materials a bona fide Trade Secret YES XO If No, complete a separate hazardous materials inventory form marked: ~O~-TRADE SECRETS OXT.Y (white form =4A-1) If Yes, complete a hazaråous materials inventory form marked: TRADE SECRETS O~LY (yellow form .4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. S~CTION 4: PRIVATE FIRE PROTECTIOX - ..- ',' .. ..,. :--.... .... SECTION 5: LOCATTO~ OF WATER SL~PLY FOR USE BY ~RGENCY RESPONDERS SECTIO~ 6: lOCATTOX OF UTILITY SHùï-OFFS AT THIS L~IT O~LY. A. :\AT. GAS/PRO?\XE: B. ::LECTRICAL: c. ~~ATER: D. SPECIAL: .- ~ LOCK BOX: YES' XO ;~ YES, LOCATIO~: IF YES, SITE PLA~S? FLOOR PLAXS'" YES / \"0 YES ! XO ~!SDSs? ~E"'S ? YES XO YES ' XO _ ')0 vU /.t ¿ .,:( ::) .. ~ --.... .. , . , I -.. ~ / of~ - : # UNIT Page FACILITY UNIT NAME: RAKERSFIELD CITY FIRE DEPARTMENT FORM 4A-l NON-TRADE SECRETS HAZARDOUS MATERIALS INVENTORY ~ME' ~~t;jfa/;&~ð 1~:S:~ME' P: ~~I!i q~07_ CITY. ZIP: <l-ð~- -:s .~- ~(-.. PHONE #: D # BUSINESS ADDRESS: CITY, 21 PHONE #: I CODE D.O.T GUIDE CFIRS 9 10 HAZARD CHEMIGAL OR COMMON NAME CODE .l9Sclo J=i,fer' C,fI)T ./>hD¡-£ /JevehL)er- )---ICRI1T , USE 10FFICIAL ONLY 456 7 CaNT USE LOCATION IN THIS UNIT CODE CODE FACILITY UNIT G4L II 10 37 Sö, ~t Co-rNet' I , S,.. l-- \~, ~ .~~ 8 % BY ~ ~ 2 3 MAX ANNUAJ~ AMOUNT AMOUNT ;:--=~~~ 1 TYPE CODE !1t1 /. N e~ if; ,--. -1% 3°%'¿ 1% tfL 2..- r:J ])01.02. . C#ßú7ö; -1J[b~ ~- '? 70Z /oZ ¿;-oz ~~' ,~4J~ . V I~~ B) /11 DA TE : ,"'J'-q-ß ~ 39~~D6(~~ Bq -15~G : HOURS ffRS: HOURS ffRS: ~~b b PiroNE # BUS AFTER BUS PHONE # BUS AFTER BUS : IGNATU~RE '...1-. .2 _ _ . ~sldel7;- ~~S TITLE: : - TITLE -- NAME: ~~ ðhé'~____ ~MER'GENCY CONTACT: -::::/òhA.J " ~ ---- . ~MERßENCY CONTACT: ~/; p~IrièIPAL BUSINESS ACTI . ~"" '~ . ~ãIEBIêL_SãEEIŸ_Dãlå_SHEEI SECIIOM_I_GE~EHåL_INEOH~ãIION EROD!JCLNêt1E.i. AUTEX SE D~v~1op~r Rep1 Co~ce~trate Part A CHEMICàL_Eêt1ILY__ Photographic Deve10per EHOEEH_DLüLIL_SHIEeING_I:Jêt1E___ Not Resu1ated t1êl\lUEêCIUHHL ALLIED PHOTO PRODUCTS CO. 5440-A Oakbrook Parkway Norcross, Georgia 30093 e81l\!CIEêL_8êlëHDüUS_Cüt1EOl\!ENIS_ HYDROilU I NONE ~;OD IUr1 ::lILF ITE SODIUM TETRABORATE POTASSIUM HYDROXIDE BOlLI!J!G_mINL Gr~ater Than 212 Deg. F. (100C) ~êEOH_eaESSUHE_it1M_HGL1_ Appr'.:.>~. 17 ~êeOa_DEl\!SIIY_iëIH_=_11_ Appr..:.x. 0.6 SOLUBILIIY_IN_WãIEH_ COITIP1ete êeeEêHëNCE_ël\!D_ODOH Slisht1y yel10wish odor1ess 1iquid. SECIION_Il_Il\!GHEDIENIS C~â~S~~_ CA::;# 12:3-31-9 CAS:!! 7757-:::~:-7 CA::;# 130:3-96-4 CAS# 1310-58-3 E:EaCEI:JL 4 - ,:;¡ 15 - 30 2 - 4 3 - 6 SECIION_III_E:HYSICëL_Dëlë -1- MSD# M-36 . r,I:" ¡¡ ':'1:';. -L,t'TI:" ,'-J') ,.,.., nL.. \- _ "_1!-1..1 1M ~:iS ! I.~,- LI..I-."j! EOE:l:\ULå Aqu<?!jus Ì'1i:d!Jr'e DLOLIL_8ëZàE:D_CLêSSIEICëIION Not ApplÎ(ab1~ t1ël\!UEêCIUBEeS_E:HOl\!E_NUt1BEH (404) 44:3-0250 CHEt1IE:EC_P.HOl\lE_l\!UMBEE: (800) 424-nOO IHE:ESHOLD_Llt1II_~êLUE êCGIH OSHå_EEL 2NCHB 2t1G-~î:3 iMG-N3 2NCHB (C) SEECIEIC_Geê~IIY_iHëIEE:_=_11 ApPf'Ü::·::. 1. 28 E:EE:CENI_~OLåIILE_BY_VOLUtlE Appro}:: 80 E~å~oeëIIo~_aêIE_i________=11 tM Åvai 1ab1e EH ÅPPPO;{. 11.30 >' '-- ~ . DE!lI,:-r-r¡' ¡;1f\T,....~ð_,j7 1\ 'j ·A:'.!.. .!..i1.¡:~ ..0 I_I! MATERIAL SAFETY DATA SHEET~ M-3b SECIlüM_I~_EI~E_êMD_EX~LOSIQM_8ëZêRD_üèlå ELèS8_eOlNI_iIESI_~EI~ÜÜ1_ Non C¡)mbustibl~ äUIO_IGMIIION_IEM2EBêIURE Not Appli<:abl~ ELi:iI'1!:!ãBLLLl!:!IIS None LEL N')n~ UEL None EKII~GUIS8ING_!:!EDlã Use the media sU9gest~d to extin9uish the sour<:e of the fir~. SEECláL_EIEE_ElGHIING_2EOCEDUBES None UMUSUáL_EIRE_êMD_EK~LOSIOM_HêZáRDS Non~ SECIIOM_~_HEáLIH_8áZêRD_DëIê IHaESHQLD_LIMII_~äLUE ::;ee ~;€cti on II OSHê_IHRESHüLD_LIMII_~ãLUE_ S€e :3€dion II äCGIH_IHaESHOLD_LIMII_~ãLUE SE;~ SectioÏi II CêECINQGEtl_=_MI~_2aOGaã!:!_ Ni)ne Known CäRCINQGE~_=_läaC_~aOGaä!:! None Known SïM2IOMS_OE_EK20SUHE Complaints of burning or irritation of th~ €y~s and mucous membranes as w€il as the development of skin irritation or Dermatitis. !:!EDICëL_CONDIIIOMS_äGGaä~äIED_BŸ_EKeOSuaE None Known eaIMáRŸ_BGUIEiSl_OE_EMIBŸ EYes, skin and ingestion E!:!EBßE~CY_EIBSI_äID EYES: Flush with water for at least i5 minutes and get medical attention. SKIN: Fiüsh skin with pl~nty of water. If skin irritation or aJier9i<: r~action deveJops, set medicai attention. INGEStION: Seek immediate ffi~dica1 advi<:e 9ivin9 fu1l detaii; of amount swa110wed and toxicity. SECIlüM_~I_aEá(Il~lI~_Dêlá SIêBILlIL :3tab 1 e (üMDIIIOMS_IO_è~OlD None Known IMCOMeêIIBILIIY_iMåIE~IäLS_IO_ê~QIDl MinH-al Acids ~åZå~Dous_eOLïMEBIZáIIQW_ ¡,)i 1 J not occür' COMDIIIOMS_IO_ê~QID None Known öäZãHDüUS_DECOM2GSIIIOM_2RODUCIS SIj)fur' [ti.;,}::ide - .. - -~.1'" T.. MATERIAL SAFETY DATA SHEET# M-36 . K-CiJI~~-Lf n~ï~'.ì9_07 I... ....~ I .-·Hle.- .'=' 1..1 { SECIION_~II_EN~laON~EtlláL_£ROIECIlüN_£RQCEnUaES SULUiESE:Of:jSE Wear prot~ctive ciothins as specified in Section VIII. If F~deraì, Stat~ andior Locaì re9ulations permit, n~utralize with Sodium Bisulfate and flush to sewer with large amounts of water. Otherwise add Dry absorbent, clean UP and place in an approved D.O.T. container, label and seal for disposal ~áSIE_DISEOSáL_~Elbon If Fed~ral, State and-or Local re9ulation permit, flush neutralized material to sewer with large amounts of wat~r. Otherwise dispose of contaminated product and materials used in cleanins UP Spills in a manner approved for this material. Consult proper Federal, State and-or Local re9ulatory agencies to ascertain proper disposal procedures. SECIION_~lll_SEECláL_EaOIECIION_INEoaMåIION EYLE:fíOIECIlOt:L Saf~ty Glass~s or Gog91es SkltURüIECIlON Impervious slov~s should be worn HESEIHáIOBY_EHOIECIION_iSEECIEY_IYEE1_ Non~ shouid be need~d ~ENIILãIIOf:j_aECOMMENÐEn Good seneral ventilation OIHER_EaOIECIION As necessary to prevent eye and skin contact. SECIION_IX_S2ECláL_EflECáUIIONS HYGIENIC_EBáCIICES_IM_HátlDLING_BND_SIOBâGE Keep tishtly sealed. Do not store or consume food, drink or tobacco in area where they may become contaminated with this material. Store above 40 Des. F (4C). Avoid unnecessary personal contact. Avoid incompatible substances. Wash thorou9hly afte~ ha~dli~9. OIHEH_2RECãUIIONS The routin~ use of a non-alkaline (acid typ~) hand ci~an~r will minimize the possibility of ailer9ic skiil reaction. Th€ infor'mation contain€d in this Materiai Saf~ty Data Sh€~t is furnished without warranty of any kind. The us€r must mak€ indepèndent determination of suitability and cOffiPlet€ness of information to assure proper use and disposal of this material and safety and health of €ffipioyees and custDm€rs. This statement is incorporated as part of this Material Safety Data Sheet. - :;-::-ì"'r __~ . MãIERlâL_SëEEIY_Dälë_SHEEI SECIIO~_I_GE~ERêL_I~EOR~êIIDM E:RODlJCLIJlf!I1E.:. AUTEX SE DEVELOPER REPL CONC PART B CHEMICëL_EäI1ILi_ Photographic Developer 2RO£EB_D~O~I~_SHIE:21IJlG_lJIå~E_ Acetic Acid t1êfJiUEêCIUBE£L ALLIED PHOTO PRODUCTS CD. 5440-A Oakbrook Parkway Norcross, Georsia 30093 eBI~CleêL_HäZêBDOUS_COME:O~EIJIIS_ ACETI C AC In l-PHENVL-3-PVRAIOLIDONE BOlLlIJIGJ:mIJlL Greater Than 212 Deg. F. (100C) ~êE:OB_eBESSUBE_iMM_~ß~l_ Appr'ox: 15 ~ê£OR_DE~SIIŸ_iêIB_=_11_ Appro>;. L 83 SOLUBILIIY_l~_WëIEB_ Cc,¡¡¡pi'i:te êE:2EëBëIJlCE_êIJlD_ODOB Light brown liquid with odor of vinegar SECIIOIJI_II_IIJIGBEDIEIJIIS U';~S~¡L CA:3!ì 74-19-7 CAS# 000092-43-3 SECIIOIJI_III_2HYSICêL_Dãlë -1- eEBCEIJIL 40 - 70 7 - 15 MSD# M-37 . RF"!C'i:'-11 nATi:" _':":'-':'7 : _VJ.._I;...._ ~I.. L",= ~l) .::.,1_1 '_I. mHt1ULê Aquf'O!j~, ~1i;.;tlJf'f' D~O~I~_HãZêBD_CLêSSlEICêIION Corrosive Material UN# 2789 l1ãIJlUEêCIUBEBS_E:HOIJIE_IJIUMBEB (404) 448-0250 CHEMIBEC_E:HOIJIE_IJIUMBEB (SOO) 424-9300 IHBESBOLD_LII1II_~åLUE ãCGIH OSHã_2EL 10PPM S2ECIEIC_GBë~IIY_iWåIEB_=_11 ApPf'O>;. 1.085 E:EBCEIJII_~OLåIILE_BY_~üLUME ApPi'ox. 90 E~àEü8êIlüM_BêIE_i________=11 N1)t Applicablf' el:J ApPf·OX. 21: 50 #..--;0.. "'_.:1 MATERIAL SAFETY DATA SHEET # M-37 . ¡:';:¡J7':'i:'n rir\Tr-....-'_·::¡~1 HL...ij,,_I!..._' !..in t,. :1:. I...'. ~ I ,I SECIIO~_I~_EI8E_êMn_EXELOSIQ~_8êlàRD_Dàlå ELàSH_20INI_iIESI_tEIHOD1_ 103 DB9r~~s F(39C) TAG CloSBd CUP åUIQ_IGMIIIQM_IE~EEaêIURE Not Applica.bl~ ELêMMàBLE_LIMIIS LEL 143 at 140 D~9rB~S F(60Cì lJEL 378 at 199F(93C) EXIIMGUISHING_MEDlê Wat~r spray, carbon dioxidB, dry chBffiical SEEClàL_E18E_ElGHIING_EBOCEDUBES W~ar self-containBd breathing apparatus and protectiv~ clothing to prevBnt contact with skin and eyes. UNUSUêL_EIBE_àND_EX£LOSION_HãlãBDS FirB or excessive heat may cause production of hazardous decoffiPosition products, SECIION_~_HEêLIH_HàZé8D_Dêlà IHBESHOLD_LIMII_~ãLUE See Section II OSHê_IHBESHOLD_LIMII_~êLUE_ åCGIH_IHBESHOLD_LIMII_~êLlJE - - " I I :)~e ::;~ct1on See ~;ect i on I I CêBCINOGEN_=_MI£_£BOG8êM_ Norl€ Known CêBCINOGEN_=_làBC_2BOGBêM Non~ Known SYM£IOMS_OE_EX£OSUBE Complaints of burning or irritation of the ~Yes and mucous membran~s as w~ll as th~ dev~lopment of skin irritation. Vapor is irritating. MEDICêL_CONDIIIQNS_êGGBB~ãIED_BY_EXeOSUBE None known. eBltlãBŸ_BOUIEiSl_OE_ENIBY Eyes, skin, in9~stion and inhaiation EMERGENCY_EIBSI_êID EYES: Flush with w~t~r for ~t l~~st 15 ffii~ut~s ~ôd s~t ffi~dicai ~tt~tltioô. SKIN: Fiush ski~ ~ith p1e~ty of wat~r. If skin irritation or aller9ic r~action d€v~lops, 9~t m~dical attention, INGESTION: Seek iffiffi€diate medicai advice givins ful1 d~taiìs of amount swallow~d and toxicity. INHALATION: Remov~ to fresh air, SECIION_~I_aEêCII~IIY_Dãlê SIåBlLIIL Stable CQtlDIIIONS_IO_è~OID Non€ KrJl)wf¡ ItlCQ~eãIIBILIIY_i~ãIEBIHLS_Iü_ã~QIDl Str'on9 Alkal i~s HãZBBDOUS_£üLYMEaIZãIIO~_ Wi 1 i not occur' CüNDIIIQNS_IO_B~üID None Knoljjn HãZåBDOUS_DECü~~OSlIION_e80DUCIS CarDon Dioxide and-or CarDon Monoxide -"1- .;.. _,,~ 1'''' MATERIAL SAFETY DATA SHEET ~ M-37 . ¡;'~U-I'-::E-I! r"'ïE.'~":·-'-·'" I\ty_~ _ JHI LV 01 SECllüM_~II_EM~IRQ~MEMlêL_eaOIECIlQN_eRQCEDURES SE:ILLBESE:ONSE W~ar protectiv~ clothing as specified in S~ction VIII. If Fed~ral, stat~ and/or Local r~gulations p~rmit, n~utralize with Sodium Bicarbonat~ and flush to sew~r with larg~ amounts of water. Otherwise add dry absorbent, clean UP and plac~ in an approv~d B.O.T. contain~r, iabel and s~al for disposal WêSIE_DIS£DSëL_MEIHOD If F~deral, Stat~ and/or Local r~gulations p~rmit, flush neutraiiz~d material to s~wer with larg~ amounts of water. Oth~rwise dispose of contaminated product and mat~rials used in cleaning UP spills in a mann~r approved for this mat~rial. Consult proper Federal, State and/or Local r~9ulatorY agencies to asc~rtain proper disposal proc~dures. SECIIÜM_~III_SE:EClêL_eaOIECIlQN_lMEQBMäIIO~ EìLŒDIECIlOIJL Safety Glasses or Gog9les Sf::ltU:ROIECIlOß\ Impervious gloves should be worn. RESE:IBäIOBY_E:BOIECIIOM_lSE:ECIEY_IYE:El_ Approved organic r~spirator in high conc~ntrations ~ENIILäIIO~_BECQMMEß\DED Good ventilation required üIHEB_E:BüIECIIQ~ As n~c~ssarY to prevent eye and skin contact. SECIlü~_lX_SE:ECláL_E:BECãUIIONS I HYGIENIC_tBäCIICES_IM_HåNDLl~G_åND_SIÜRêGE Keep tightly sealed. Do not store or consume food, drink or tobacco in area where they may becom~ contaminated with this mat~rial. Store abov~ 40 D~9. F (4C), Avoid unnecessary personal contact. Avoid incompatible substanc~s. Wash thoroughly after handling. OI8EB_E:BECäUIIONS Material is classifi~d as a combustibl~ liquid, K~ep away from h~at and flaffi~. The information contained in this Material Safety Data Sh~et is furnished without wa~~anty of any kind. The user must make ind~p~ndent deterITlination üf suitability and complet~n~ss of information to assur~ proper use and disposal üf this material and safety and health of emploY~es and customers. This statement is incorporated as part ûf this Mat~rial Safety Data Sh~et. -3- ~- ---.~ --------------------- -- EBOjjUCL~f¡ì1E~ AUïEX SE DEVELOPER REPL CONe PART G CHE~ICãL_EgMILï_ Photo9raphic D~v~1DPer £B02Ea_D_ü~I~_SHIE21~G_Nà~E_ Co~rosive Liquid N;ü*S. t:iâtîUEflCIUHEfi_ ALLIED PHOTO PRODUCTS CO. 5440-A O;kb~~~k Pd~kwdY Nùrc~ùss: G~Gr9ia 30093 ERl~CI2äL_HãIHBüOUS_COB£Q~EruIS_ GLUTAHALDEHYDE BülLIMG_E:OIIJIL Gr2dt~f Than 212 Deg, F. (100C) ~êeOtl_eaESSuRE_iM~_HG~l_ APFTO::{: 17 ~êeQa_DE~SlIÿ_íslB_=_11_ Appr'ü)::: ü: (:. SOLUBILIIY_IN_~êIE~_ Cüm?l~t~ . ~ãIEalgL_SêEEIY_D~IB_SbEEI SECIIQN_l_GE~EaBL_I~EDE~BIIOill SECIION_II_I~GaEDIEruIS .' n , "'.. i...~;:¡~;:;_!±_ EE8CEillI_ CA:3# 1 i 1-:30-::; 15 .)._! SECIIOj_lll_eHYSICBL_DêIê Ht2E8RåtlCE_ã~D_üDûR Cleal dlffiùst co1or1~ss 1iquid with an aid~h,d~ Od0~= -i- M~ú# rn_00 . ! ¡·_'l.·¡r I ¡ ._,,_, REVISED DATE; 10-28-87 EQRt:1ULg A<¡Ui;¡jijS tÜ;:t!Jf'i: D~Q~I._HêlêaD_CL8SS1EICèIIQ~ Cor~Gsiv~ Mat~riaì UN# 1760 MH~UEêCIUREHS_2HQ~E_NU~BE8 \ 404) !}4:3-025Ü C8EöI8Ec_eHü~E_~UtBE8 ~ 80Ü) 424·-9:300 IHaESëüLn_LIMII_~~LUE f!CGl!:! OStifi_tEL ü= 2PFt~1 (C) S2ECIEIC_G~å~IIY_1UBIE~_=_11 {ippr·C(:<1I 1;06 £EaCE~I_~OLâIILE_BY_YQLU~E Appr'::'(:~; 75 E~22QaêIIO~_8~IE_i________=11 Not :4v;i 1 ab: ~ E:~ Appr'o}::~ 7; 00 ~ I f'" ' --:¡ MATERIAL SAFETY DATA SHEET * M-38 . --,'T--- --T- .-- -- ..¡.. . I h ,. 11'1:: ... . . K_V10è~ Jhit4 :j-jÎ SECIlüM_I~_ElBE_ãND_Ex2LOSIO~_dêZg~D_D~IB EL8SH_EOl~I_fIESI_MEIHOül_ f"kiI (:ümbustiblf: êUIQ_IGNIIION_IEMEEH9IuaE Not Applicable EL¿~MêBLE_LI~IIS ¡ !:! UEL --- N¡)Ï!t: NÜf¡:2 Nün~ EXIl~GUISHI~G_~EDlå USB th~ ffiBdia SUgS~stf:d to ~xtin9Uish th2 SûU~C~ ~. th~ tlrea seEClåL_ElaE_EIGHII~G_2HOCEDUHES NÜfïf: UNUSUšL_ElaE_ßND_EïeLOSlû~_8BI~aDS N;)n~ SECIIQM_~_HEêLIH_H¿ZêtiD_DBlê IHaESHOLÐ_LIBII_~åLUE ::;eB Section II üSHB_IHaES~OLÐ_LIBII_~~LUE_ ~;f::2 Sèction II éCGIH_IHHES80LÐ_LI~II_~êLUE S~t: ~:~cti::~f¡ II CGaCIMOGE~_=_Mle_2ROG8ã~_ No;!'? KÏlt)wn c~aCI~OGEM_=_lè2C_EaOGH~~ r~Ü¡¡2 }<nüljJÏI SYMerOMS_OE_ExeOSU8E Complaints Df burni~9 Dr i~rit~tiùn Dt th~ eY~s and mucous ffi~8bran~s as ill~li d~ .1.l.ø Ui'.: d;?v~ 1 opm,~nt of skin i~~it~tio~ o~ Dt:~ffiatitis. V~P¡)~ is i~ritatiD9. oEDICHL_Cü~DIIIQNS_ãGGaãVåIEü_BÏ_ExeOSU8E NÜÏii.? knCi\Lm. eRl~åHŸ_HGUIElSi_OE_ENlaY Eyes, 5kio~ insestioD and inhaìatiûn~ EBEgGE~CY_EIBSI_ålD EYES: Flush with water for at least 15 minutt:s and set medical attt:otion. SKIN: Flush skin ~ith plenty ûf wat~r'c if skin irritatiûü O~ al1~rgic r~actiûn d~veiûps) g~t lli~dic;1 att~ntio~~ INGESTlüN; Se~k iffiID~diat~ medica1 advice 9ivins fu11 d~tai15 of amDunt silidl1Dill~d aDd tD;~icityc INHALATION: R~mov~ to f~~sh ai~, tr~~t SYIT¡ptoili¿tical1v ~nd get m~dic~1 dtt~ntiDõc SECIlüU_~1_8EêCIIVIIï_~gI9 SIåBIlIIY._ CO~D!IIOGS_IQ_ã~OID :3tab 1 e Non~ Known 1~COM£ãIIBILIIY_iBãrEtil~LS_IQ_9~üIDl Min~r~l Acids and Strong ûxi~iz~rs ~HZãHDOUS_20LYMEaIZëllü~_ CGMDIIIGNS_IC;., .8~CID Wi 11 not occur· Non", f<n('ijf¡ 8ãZéBDOUS_DECOM20SIIION_EBODUCIS ~:;Hl fn¡-' Di¡jxid2 and CB.Ï"büÍJ !"k!nüxid~ -2- ~- '" ~~- MATERIAL SAFETY DATA SHEET ~ M-38 . PC¡:r'-'CT¡ ~¡A'TE."X!_'~7 !;t- Y .L.]1.-:'" L, i-'_' ,_~! SECllû~_~II_E~~laO~MEMIãL_e8GIECIlú~_~~QCEDUeES seILL_HESeOr4SE Wf~r prot~ctivë clothing ~s SP€cifi~d in S~ctiDn VIII~ If F~d~ral? Stat~ and/or Local r~9ulations p~rffiit: n~utralize with Sodium Mët~bisulfit~ ~nd flush to S€WBr with la~se amounts ûf wat2r~ OthBr-wise J ' a'll] drY absûrb~nt, clëan UP and p1ac~ in aü approv~d D~OzT: cûntain2r, 1ab~1 anc s~dl fDr disposal ~êSIE_DIStOSBL_~EI80D If F~d~r~i, Stat~ and/or Lûca1 r29ul~tion5 Permit, flush ~~utr~liz~d m~t~rial to S~Wfr with 1argf ~ffiOijnts ûf ~ater: üth~rwis~ dispos~ úf c0nt~minat~d p~oduct and mat~ria1s used in ~leanin9 UP spills in a m~nDer approv~d fûr this mat~ria1: C0~sult prop~r F~d~ral? State and/or Local r~9ulatDrY a9~nci~5 to ~scertain prûPèr disposal prüc~du~ëS: SECIION_VIII_SP.EClêL_P.8QIECIIQ~_INE08~gIIQM E\ŒJ~E:üIECIIQ~L Saf~ty Glas5~s or Gos91fs SKI~_eaOIECIIQN Impervious gloves should be worn: EES£lBêI08Y_ttiOIECIION_iSP.ECIEI_IYP.El_ ~ENIILåIION_BECO~~ENDED Approved organic respir~tor in high concentrations Good v~ntilation re~uirfd OIHER_P.80IECIION As n~(eS5drY to pr~v€nt ~y~ and skIn cont~ct: SECIlûN_IX_SEECI~L_ËBECHUIIO~S BYGIENIC_tRêCIICES_IN_8êNDLING_êND_SI08êGE K~~p tishtly s~alëd: Do not stor~ or' CDnsumë food, drink or tobaccD in ~~~a wnff~ th~y may becüm~ contaminated lùith this matBria1: Storf aDDvf 40 D~9= F ,4C}: Avoid unneCfSSary p~r5Dna1 cüntact~ Avoid incompatible SUDstanc~s: Wash thOfOU9h1y ¿fte~ handlin9t DI8Ea_~BECêUIIONS The routine use of a non-alkaline (acid typ~) hand rlø~n~r will œlD!ffilZ~ th~ possibility of aller~ic skin r-i?aictiof¡: Thi? infür-matiün cünta.ined in this t'~at0f'ial Saf~t·-{ D~ta Sh~~t is fur"niShed !,;.1ith:)ut war-r-ant-f' of a.rr-/ kind: Th~ us~r must m~k~ independènt dët~rffiinatiûn of suita~i1ity and CDmPlët~D~SS of i~f)rm~tiûn tü tiS~·~Jr·E: pr'op~r' U::-~ ~nd disp{!sa.1 (if this IÎrdt-2r-ia1 ~Tld 5~fét--{ arid h2a1th of '2rriF'1üy~~~- a.;id (lJstüIT!~r"::.= This statfffifnt is i~cúrporatëd ~s part of this Mat~ria1 Saf~ty D~t~ Sh~êt: - :- ;¡. E:BOI1UCL~ê jE.:.. AUTEX Fix~r & R~pi Cone Part R CHEMIC8L_E8~ILŸ_ Photo9raphic Fix~r E:BOE:Ea_I1~Q~I~_SHIE:E:I~G_~ê~E_ Not R~9IJ1ati'd !::iêt)UEáCIUBHL ALLIED PHOTO PRODUCTS CO, 5440-A Oakbrûok Parkway Norcross, G~or9ia 30093 ERI~CIE:åL_HåZBRDOüS_CO jE:O~E~IS_ AMMONIUM THIOSULFATE ::;ODIUM ::;ULFITE ACETIC ACID BOILHLE:üHIL Greater Than 212 Des, F: (100C) ~BE:Oa_E:aESSUaE_iM~_HG~l_ Arpr·t)}~: 17 ~êE:üH_DENSIIY_i91a_=_il_ (4FPr'ü::{= 0: f:., SQLUBILIIY_I~_~åIEa_ CoITiPiete 8E:E:Eåaå~CE_ãND_ODoa . MãIERlàL_SêEEIÏ_DêIã_SHEEI SECIIO~_l_GE~EaàL_I~EûRÐãIIO~ SECIION_II_INGREDIENTS C~ê~S~~_ E:EaCE~L MSD# M-l1 . - .. - ---- -- .. rtL,.Ji·f·C'!' I". '/..= "'- IJl ~~vl~~~ ~HI~= VC-k~-VV REV" #Üi EOBt1ULã AqlJ~(i!J~. MixtiJf'i? D~O~I~_tiåZãED_CLåSSlElCBIlO~ Not ApPiicabie ~è~üEåCIUaEaS_E:HQ~E_MUMBEa (404) 448-0250 CHEMIREC_eHONE_~UtlBER (8(0) 424-9:300 IHRESHQLD_LI jII_~åLUE ãCGIH OSHè_E:EL CASt 77:3:;';-18-8 40 - ¡-J) CA::;# 775ï-B3-7 ii - "T - CAS# t,4-19-7 2 - 6 10PPr1 î OPP~1 SECIIO~_llI_E:8YSICåL_DêI9 CD1or1BS5 liguid with a sli9ht ammûniaca1 ûdor: _1_ 1 seECIEIC_Gaå~IIÿ_iWåIEa_=_il ApPf'Ü}::, 1. 335 eEaCE~I_~OLãIILE_BŸ_~OLUBE ApPf":)::-::. 50 E~£eOH9IlüM_BêIE_l________=11 Not Avai1abif! El:i Åppr"((:·::: 5.20 ). "MATERIAL SAFETY DATA SHEET# M-ll . ~'~'JT,-,,..r¡ n'Te...." ,-,! ti.t ~ _ ·JCLI !.) H : L..: ~._¡-I::!.) HEV~ #01 SECIlúM_l~_EIHE_ã~n_ExeLüSlü~_H8ZåBD_DåIë ELêS8_EQl~I_iIESI_~EltiQD1_ Non COIT!bustibl", êUlü_lG~IIlü~_IE~2EBêIURE Not ApplicablE: ElåMMëBlE_LIMIIS NOf¡B Le! ........ UEL None Nüf¡<? EXIIMGUIS81~G_~EDlà USf: the ffif:dia SlJ99fStf:d to extin9uish thf: source D+ th", tire, StEClêL_ElRE_EIG~IlMG_EROCEDuaES Nüf¡", UMUSUêL_EIBE_êMD_EXELOSIOM_HêlêBDS Noni: SECIIO~_~_HEêLI8_8êlê~n_Dêlê IHHESHQLD_LIMII_~ãLUE ~3e:2 SBct ion I I OSHå_IHEESHOLD_LIMII_~êLUE_ Si:i: ~;i:ctiün II êCGIH_IHBESHQLD_lIMII_~êLUE Set: Si2ctiün Ii Nont? Known CàECI~QGEM_=_lêHC_EeOGHê~ Noni: Known CëHCIMQGEM_=_Mle_EEOGHê~_ SYMEIOMS_OE_EXEOSUHE Low hazard for usual industrial handling MEDICêL_COMnIIIQMS_êGGBê~êIED_Bï_EXEOSUßE None known, eRIMãHŸ_EQUIEiSl_OE_EMIHï Ey~s, skin and ingestion EöEEGENCY_EIESI_êlD EYES: Fiush with wati:r for at least 15 minutes and get medical attention, SKIN: Flush skin with plenty of water. If skin irritation or a11~r9ic r~~ction d~v~loPs1 9~t medica1 att~ntion: INCiESTION: ::;€€k imm€dia.te ¡¡I",diea.i advic£' sivin9 fuii d",ta.ih, üf a.1i¡¡)\jf¡'\: s\;)a.l1o\;)¡?d a.nd teo::-:icity, SECIIO~_~I_RE9CIIVIIY_DêIê SIêBILlIL CQMÐIIIO~S_IO_ê~QID ~:;tab i € NOf)'2 Known IMCOM~êIIBILIlï_iMåIERlãLS_IQ_ë~OIDl :::tr'Üf¡9 A H::a.l i\?5 ~êZëRDOUS_£OLYMEHllãIlON_ ¡.Ji 11 nd üccur' CO~DIIIONS_IQ_ã~OID N(,n~ knoù.1n ~êlèHDOUS_DECOMeOSIIION_E80DUCIS Rmmonla - í ~- ~ MATERIAL SAFETY DATA SHEET#. M-ll . RI:!1I ':'¡::-¡I L-,A-Ir-'.·-Jr._¡)!. . !-'~ "_'L._' 'H r: ~ ~"_, ,_,£_, REV~ #01 SECIIOM_~II_E~~IHON~ENIêL_2eDIECIIo~_eBüCEDUBES SeILUiESE:DNSE W,?ar' Pr'ob::dive c1othin9 as sP'2cifi~d in Section VIII. If Ft?dt?r'a], ~:tatB and/or' Loca] f'~9iJlations permit flush to sewer with larse amounts of water= Otherwise add dr"l absor-tH?nt, cit:a.n UP and placE: in .an a,ppr'ovI2d [1:0= T~ cOfltair¡:2r', 1abe1 ;and s~al for- dispo~.a.l ~êSIE_DISE:OS~L_~EIHOD If F~dfral, State andior Lûc~i r~sulatioDs p~rffiit: flush mat~ri~1 to sew~r with lar9~ amounts of wdt~r: Oth~~wis€ dispose of contaminated product ~nd mat~ri~ls us~d in cl~aDin9 UP spills in d ffiann~r approved for this mat~ria12 Consult p~op~r Federa1, StatB and/ûf Local rësu1~tDrY a9fncies tû ascert~in prûp~r disposal procedur~5= r( SECIlûM_~III_seECI~L_E:8QIECIIQM_IMEQ~MêIlOM EìLE:ROIECnŒL Saf~ty Glass~s Of' G099les SUILEBOIECIlQr-.J IffiP~rvious stûves should tB worD. BESEI~~IORY_E:RüIECIID~_íSE:ECIEY_IŸeEl_ Non~ should b~ ne~ded ~E~IIL~IIO~_RECOMMEMDED Good ventilation required OIHEH_E:BQIECIIOill As n~c~ssarY tû pr~vent ~y~ aDd skin contact~ SECIlüM_lz_SEEClêL_ERECeUIIONS ~YGIEMIC_ERêCIICES_I~_~åtlDLIMG_ê~D_SIORêGE Keep ti9htly s€~led= Dü not stûr~ or consume food, drink or tobacco in ~rea wh€re th€y may beCDffi€ contamin~ted with this mat~rial. Store abûv~ 40 D~g= F (4C): Avoid unDfC~SS~rY P€rsûn~l contact: Avoid incoffiPatibl€ sub5tanc~s= Wash thD~OU9hly aft~r hand1in9~ OIHER_ERECêUIIOMS None Th~ information (ontained in this Material Saf~ty Data Sh~~t is furnish~d without warranty of any kind, Th~ us~r must ffiakt? indt?Pt?nd~nt dett?f'ffiination of siJitabiiity and COmP]eten~ss of information to assurt? proper us€ and disposal of this matt?rial and safety and heaith of €ffiP]Oyt?es and custoffi€rS, This stateffi~nt is incûrporat€G ~s part of this Mat~fi~1 S~fety D~ta Sh~et~ -.)- ~- -- ~, r:BüDUCLl'.;êi1El AUïEX FIXER PARï D Cl:iEi1ICfLEêIJIL:L PhQto9raphic Fix€r EBDEEB_D~O~I~_Sl:iIEr:I~G_~åöE_ Aluminum Sulfate Solution t1ãWJEêCIUBEIL ALLIED PHOïO PRODUCïS CO. 5440-A Oa.kbr"ook Pa.r'kwa.y Norcross, Georgia 30093 eaI~CIEêL_l:iåZêaDOUS_CDMEDNEMIS_ ALUNINUt-1 :;ULFAïE BOlLlNG_E:DltJIL Grfatff Than 2i2 D~9a Fa ( i (¡(u-'; . J. ~_,,_: _. i ~år:OB_E:aESSUBE_IIJM_l:iG~l_ tM Avai labie ~åE:Da_DENSlIï_iêla_=_11_ tM Avai lable SOLUBILIIŸ_IN_WêIER_ C('ITiplete êE:E:EêBãMCE_ëMD_ODü8 ~ hite, color"less, odûr'less 1 iquid, . ~ãIEaIHL_SêEEIY_D¿Iá_SHEEI SECIIDM_I_GEtJ!EBãL_ItJ!EOBi1åIIO~ SECIIO~_II_I~GaEDIEtJ!IS L~ë~::;~~_ EE8CEML CAS# 1 004:~:-Ol-:3 ")(¡ - ::~(¡ SECIIOtJI_III_El:iYSICãL_DãIã -1- MSD# M-12 . E' -- [. ,- -, r-, ,'''',.. 'r"¡ ,;tTr-=. ~., r: t\ 'i l·::tL' ~H I ¡: II t,,!.,: - i ¡-C.":I E!J8i1ULê Aqueous t1i>;tur"e D~O~I~_l:iêZå8D_CLåSSIEICêIIQ~ ORM-B i1êNUEëCIUREBS_E:BOtJIE_NUtlBER (404) 448-0250 Cl:iEMIBEC_E:HONE_NUMBE8 (ØOO) 414-9300 Il:iaESl:iOLD_Lli1II_~ëLUE êCGIH aSHe_EEL 2NG-it3 SE:ECIEIC_GBé~IIY_l~ãIEa_=_il Appr'l)x. 1.32 £EaCE~I_~OLäIILE_BY_~OLUME Nl)t Available E~ä£DRéIIO~_BéIE_l________=11 Not Avaiiable eH ApPi'ü::-::. 3.00 -.r- . - ø¡- MATERIAL SAFETY DATA SHEET # M-12 . R1=\II C:ì:n, n/l'Tí::-'.- 17_qL . .10.. f "_"_1.; ~·n. I .;.. '_"_' SECIIQtl_1~_ElBE_8ND_ExeLûSION_HgZ8ED_DêIH Non Cümbustib1e BUIO_IGNIIION_IEM£EHëIUHE Not App 1i cat.] <2 ELêSH_20INI_iIESI_MEIHOD1_ ELãMtlãBLE_LIMIIS NOil<2 LEL UEL NOf¡<2 Nünt2 EXIINGUISHING_MEDlê US<2 th<2 m~dia sU99~st~d to <2xtifl9uish th~ sourC<2 of th~ fir~, SEEClêL_ElaE_EIGHIING_eROCEDURES Non£? UNUSUêL_EIRE_êMD_EXELOSIOM_HêlêRns Non<2 SECIIQM_~_HEêLIH_öêZêRD_ÐêIê IH8ESHOLD_LltlII_VêLUE OSBê_IHRESHQLD_LltlII_~êLUE_ êCGIH_IHRESHOLD_LIMII_VêLUE ~::<2<2 t;Htion II s~~ S~(tion II S€'~ Section II CêRCIMOGEN_=_NI£_eaOGBêM_ Non\? KMwn CêRCINOGEN_=_lëBC_£aOGBêM Nc.fIê KÏioum SYM2IOMS_oE_ExeOSURE Can CB.1J5f! e"ï't2 and skin bur-ns and/or- ir'f'i tation: MEDICêL_CONDIIIOMS_êGGRê~êIED_BY_EXeOSURE NOÏ!\? knl)wf¡. eRIMêBY_BOUIEiSl_OE_ENIBY Ey\?s, skin and in9\?sticIÍl EMERGENCY_EIESI_êID EYES: Fiush with wat~r for at i~ast 15 minutes and s~t m~dicai att~ntion. SKIN: Fiush skin with pi~Ï!ty of water, If skin irritation or a11<2r9ic reaction d<2v<21ops, set ffi<2oicai att~ntion, INGESTI(~: S~~k imm~diat<2 m~dical advic~ 9ivi~9 fuli d~taiis of amouüt swallow~d and toxicity, SECIIO~_~1_8EãCII~lIŸ_DHIê SIêBILlIL :;tab 1 ~ CO~DIIIQ~S_IO_ã~OlD None ~:ÏiÜwn IMCOMeêIIBILIIŸ_iMêIEBIêLS_IO_ê~úIDl AlkaliE's. 8êlãRDúUS_20LïMEBIZëIlüM_ \.)i 11 ilot (¡CCIJi' COMDIIIOMS_IO_ë~OlD Nont? Kril)wn HëZê8DüUS_DECOMEOSIIIOM_2BODUCIS ~:;IJ 1 fur' O::{Ï 0<2 -2- ~r -~ MATERIAL SAFETY DATA SHEET # M-12 . DE'II':'¡:TI r,r'Tr:e-f-¡-,)! 1\ v ""!-~ _H I L !! ,_,el SECIIOM_~II_EN~IBQNMENlêL_eRüIECIIQM_E8QCEnUHES S2ILU~ESE:DNSE W~ar Prot~ctiv~ clothing as sp~cifi~d in S~ction VIII, If F~deral, stat~ and/or Locai re9ulations permit, n~utraiize with Soda Ash and flush to s~wer with large amounts of water, Othefwise add drY absorbent, clean UP and place in an approved D,G,T, container, lab~l and seal for disposal ~êSIE_nIS20SêL_~EIöQD If Federal, State and/or Local r~9ulations permit, flush neutfalized matefial to sewef with large amounts of water, Otherwise dispose of contaminat~d product and materials used in cleaning UP spills in a mann~f approved for this matefial. Consult proper F~defal, State and/or Local regulatory agencies tù asc~rt~in ?rûp~~ dispos;l prDc~du~esR SECIIQM_~III_seEClêL_EROIECIIQM_lMEOR~åIION tYLŒOIECIlmL SkHLE:F1OIECIlOIJI Safety Glass~s or G0991es Impervious 91ov~5 shûuid be wû~n: EESE:IEêIOEY_EBOIECIION_iSE:ECIEY_IYE:El_ ~ENIILêIION_RECO~BENDED Good gen~ral ventilation. Nûn~ should b~ û~eded OI~EB_EaOIECIION As neC~55afY to prevent fY~ and skin contact: SECIION_IX_SEEClêL_EBECêUIIONS HYGIENIC_EBêCIICES_IN_bêNDLING_BND_SIDEêGE !(eep ti9htly sealed. Dû not stofe or consume food, dfink or tobacco in area where they may become contaminated with this material, Store above 40 De9. F (4Cì, Avoid unn~cessa~y per50nal contact. Avoid incompatibl~ substances, Wash thorou9hly after handling. DIBER_eaECHUIIO~S N(,f¡~ The information contain~d in this Matefial Safety Data Sh~et is fUfnished without warfanty of any kind. The user must make ind€p€ndent determination Df 5uitabilitv and completene5s of if¡fo~mation to assur~ prop~r use and disposal of this mat~~ial and safety and health of employees and customers. This statement is incorporated as part of this Matefial Safety Data Sheet, -:3- ;:£ "" '" eE\QDUCL~åt]E.;, AUTEX D~v~loPBr RBPi CO~(~~tfat~ Part A CHEMICêL_Eà~ILY__ Phot~9raphic D~v~ioPBr ~RO£EB_D~O~I~_SHI221~G_~ê~E___ Nt,t Ri29ul ated t1èr:JUE8CIUiiEB_ ALLIED PHOTO PRODUCT::: eo, 5440-A OakbrooK ParKway Norcross, G~Qr9ia 300~3 eBI~CI28L_8êZêRDQUS_COM2Q~E~IS_ HYDRO(¡!J I Nm~E SODIL!~1 SULFITE SODIUM TETRABORATE POTASSIUM HYDROXIDE BülLlt:JG_2úllJlL GrBater Tha~ 212 DBS, F, i100C) ~ê20R_2aESSURE_it1M_HG~1_ Appr"ü>::, 1 ì ~à20R_DEr:JSIIY_iëIR_=_11_ Appr'o:,;, IJ, ,~, SOLüBILIIY_I~_WãIE8_ CC'ITipletB ã£2EãEêNCE_êr:JD_ODOR Siightly yeilowish odoriBss liquid. . ~HIEEIBL_S~EEIŸ_DHlê_SHEEI SECIIO~_I_GE~EBêL_INEOR~êIIO~ SECIlüt:J_II_llJlG8EDIEMIS C~á~S~iL 2ŒCE~L CAS:!! 123-::::1-9 4 - ij 'j CASU ï757-8~:-7 ,,= - :::u 1"_1 (",N\ 1:3((:-96-4 ~J - .. _·H·:¡ii .. ., CA~;# 1:310-5:::-3 :3 - i;. SECIIQM_III_e~YSICêL_DHI~ -~----~----- ---------- MSD# M-05 . ¡:'¡::¡I¡q:T' PH'"TE' _i ,'-('¿ l\_ i .&. ._.~~!~.1a "\.I._I.!. 't 1_11_1 EQ&~ULå ÃqueülJs r1i>::tur"2 ü~O~I~_HáZêBD_CLêSSIEICêIIQ~ Not Appiicat<le ôêNUEêCIUBERS_2dOtlE_~UöBEB (404) 448-0250 C8EMIBEC_EHONE_~UMBEB (:300) 424-9:300 IH8ESdOLD_LI~II_~ãLUE áCGIH OSHë_2EL 2NCHB 2r~1G-M:3 1 f'ÎIHi:3 2ì'iCi-~E: (c:) seECIEIC_GBë~lIY_iWåIER_=_11 ApPr-((:·~a 1,28 ~EECEMI_~üLBIILE_BY_~QLU~E Appro):: 80 E~82QBãIIO~_RãIE_i________=11 Not Avai 1 ~td ~ _II 1::0 ÃPHO;{, 11.:30 it-"-' MAtERIAL SAFETY DATA SHEET# M-05 ~ . r¡C\¡T, c'cn ['H,\TE'., 11-'')1, I\~ ~ _-_I~:..I _I I! .""1 1.11_' SECIIQM_I~_EI8E_gND_ExELOSIQN_8ãZã8D_Dãlã ELãSH_~OI~I_iIESI_MEI80Dl_ Norl COiTJbljS t ib 1 ¡:; ãUIO_IGNIl10N_IEM£E8ãIU8E Not App 1 i cab 1 <~ ELä~tláBLE_LltlIIS NOf¡~ LEL i\Wne Ur-, 'L.L N,)nl? ExIIMGUlSHIMG_~EDlã Us¡:; th~ ffi¡:;diasIj99~st~d to €:xtin9uish th~ sOljrc~ ~f the fir€:. SEEClãL_EIBE_ElGHIlNG_£80CEDÜBES NOil;? UNUSUãL_EI8E_ãND_ExElOSION_tiêZé8DS Nor!~ SECIIO~_~_8EåLIH_8êlêaD_D9IH IH8ESHOlD_lIMII_~êLUE OSHã_IH8ESHOLD_LIMII_~2LUE_ :3¡:;<~ ::;;?cti on II BCGIH_IH8ESHOLD_Ll~lI_~ãLUE SB~ Sectiün II See S~ctit)n II CáECIMOGEtl_=_MIE_EBOGBêM_ Non€ Known CãBCINOGEM_=_lãBC_£BOGBã~ Non\? Known SŸM£IOMS_OE_EleOSUBE COffiPiaints of burnin9 or irritation of th€: €:YI?S and mucous ffi€:mbran~s ~~ wl?1i as th\? d~v€1oPffi¡:;nt of skin irritation or Dermatitis. MEDICãL_CONDIIIONS_êGG8ã~ãIED_BŸ_EÏeosuaE Nün-e Known ~BIMà8Ÿ_EúUIEiSl_OE_ENIBŸ Ey;?s, skin and in9¡:;stion E~EBGENCŸ_EI8SI_êID EYES: Flush with wat;?r for at l~ast i5 mÍnut¡:;s and get medical att¡:;ntion. SKiN: Fiush skin with pi~nty of w~t€r. If skin irritatio~ or al]~r9ic r~action d¡:;v¡:;]ops, 9~t mèdic~1 att~ntio~. INGEStION: Sèfk iffim€:di~t~ ffi~dic~] ~dvic~ 9ivÍ~9 fu]i d~tai]s of amount swai]ow~d and toxicity, SECIIO~_~1_8EéCII~IIï_DBIB SIBBILlIï_ ~;tab] e CQruÐIIIQMS_IQ_B~OID NOiie Known INCQM2êIIBILIIŸ_iMåIE8IãLS_IO_ë~QIDl Mi ri\~r'a 1 Ac i d;;. 8êZB8DOUS_2QLŸME81ZêIIO~_ COMDIIIO~S_IO_ã~üID Non¡:; K~oWÏi ~Ji 11 not occur- Hêlê8DüUS_DECOMEüSIIlo~_eBODUCIS Sul fur- Diü>Üdf; - ," ~, ....;r_ MATERIAL SAFETY DATA SHEET~ M-05 . r-,rìJT'::p" -lir'Tt--e14-o.f- tu: : ! ._':-1.1 ,¡"'1 I _ or.. 1_.._1 SECIlúN_~II_EN~laONMEMlêL_2aQIECIlQM_eHOCEDuaES S21LUiES20!\!SE W~ar prot~ctiv~ clothing as sPBcifiëQ in S~ctiDö VIII~ If F€deral, Stat~ ~nd!or Lûc~i r~9ulaticns permit, n€utralize with Sodium Bisulfate and flush to sewer with large amounts of water, Otherwis~ add Dry absorbent, clean UP and place in an approved D,O.T, container, label and seal for disposal ~ãSIE_DIS20SèL_~EIBQD If Federal, Stat~ and-or Local resulation permit, flush neutralized material to sewer with larse amounts of water, Otherwise dispose of contaminated product and materials used in cleanins UP Spills in a manner' approved for this material, Consult proper FederaL, State and-or Local regulatory aSfDcies to ascertain PfÛP~~ disposal prQC~dur~5. SECIIQM_~lll_seEClêL_eeOIECIIQM_lMEQeMêIlON EYE-eaOIECIlOtL Saf~ty GlaS5~S or G0991~5 SKULE:ROIECnON Impervious gloves should be worn RESE:IHêIOHY_E:HOIECIION_iSE:ECIEY_IYE:El_ None should be needed ~ENIILBIIO!\!_HECOBöENDED Good seneral ventilation OIHEH_E:HOIECIIO!\! As necessary to pr~vent eye and skin contact, SECIION_lx_seEClêL_2HECëUIIOMS HYGIE~IC_E:aêCIICES_I!\!_Hê!\!DLI!\!G_êMD_SIOaeGE Keep tightly sealed, Do not store or consume food, drink or tobacco in ar~a where they may become contaminated with this material, Store above 40 Des, F (4C), Avoid unnecessary per'sonai contact, Avoid incompatible substances, Wash thorou9h1y after hand1in9, OI8ER_2BECBUIIOMS The routine use of a non-alkaline (acid typel hand cleaner will ffiinimiz~ the possibility of allergic skin r-~;j,ctiünl The informatiDn contained in this Material S~f~ty Data She~t is furnished without ~ar~anty of any kind, The user must make independent determination of suitability and completeness of information to assure proper use and disposal of this materiaì and safety and health of employees and customers, This statement is incorporated as part of this Materia1 Safety Data Sheet, -3- ?f"; ~ . ~BIEalêL_SêEEIŸ_Dålã_SHEEI SECIlû~_1_GE~EaãL_I~Eü8MåIlO~ E:BODUCU:Jêt::1E... AUTEX DEVELOPER CONCENTRATE PART B CHEt::1ICêL_Eét::1ILY_ Photosraphic D~v~lüp~r E:BüE:Ea_D~ü~I~_S~ltEI~G_~ãt::1E_ Ac~tic Acid t:1ét:.iUEãCIUliEtL ALLIED PHOTO PRODUCTS CO. 5440-A Oakbrüük Parkway Norcross, G~o~9i~ 30093 2al~CI2ãL_HêZêliDOUS_COBE:O~E~IS_ ACETI C AC In l-PHENYL-3-PYRAZOLIDONE BDlLli:JGJ::QIr.JL Gr~at~r Than 212 D~9. F. (100C) ~ä2QIi_2aESSUaE_It::1t::1_HG~1_ ApFr'ox. 15 ~êtOB_DE~SlIY_iãIB_=_11_ Appr-o::{. L:::3 SOLUBILIIY_IM_~ãIEB_ C,)IT;P]i:tB êE:tEëBã~CE_ã~D_ODOB Light brown liquid with odor- of vin~sar SECIIO~_ll_I~GBEDIEMIS U',j~S~iL C¡:6# 74-19-7 CAS# 000092-4:3-:=: SECIIO~_111_2HYSICêL_DêIã -1- EEBCEt:JL 40 - 70 7 - 15 MSÐ# M-06 . --..---- - ._- . -- -, HcVl~cV D~ît; UJ-L0-06 EûBt::1ULê A'1u~oiJS Mixtljf'~ D~O~I~_HêZäaÐ_CLãSSIEICãIIOM COfrosive M~tBrial UN# 2789 MB~UEãClüSERs_eHO~E_lliUMBEE (404} 448-0250 CHEMIaEC_e~O~E_~UMBEa (E:OO) 424-9300 IHHESHQLD_LIMII_~ãlUE BCGUJ OSl:ià_EEL 10PPì'1 S2ECIEIC_GEB~IIY_iYãIEE_=_11 ApPr' I);;. 1. 0:35 tEECE~I_~QLãIILE_BY_~OLU~E Appr'((;-::= 90 E~ã2QBêIIQ~_BêIE_i________=11 Not Åppiicatl'2 Et! Appr'ox~ 21150 ~ ~ r1ATERIAL SAFETY DATA SHEET # M-06 . ~'P¡·l':'Fn 'li'T!:" .~_i;'¡. I~_"f '_'__1 L:n 1...1 J '_IL' SECIID~_I~_ElaE_b~Ð_ElELQSIDN_8èZê~D_DåIå ELéS8_EOINI_iIESI_MEIHOD1_ 103 Degrees F(39C) TAG Closed CUP åüIO_IGNIIlûru_IE~EE89IU8E Not Applicable ELå~~ãBLE_LIMIIS LEL 143 at 140 D~9r~es F(60C) UEL 378 at 199F(9~:(:) EXIINGUISHING_~EDlã WdtBr spray, carbon diûxidè: dry ch~mical S£EClêL_ElaE_EIG8IIUG_E80CEDU8ES Wear self-co~taiüed breathi~9 apparatus a~d protective clothing to prevent contact with skin and eYBS. UNUSUéL_EIHE_åND_EX£LOSION_Hálé8DS Fire or ~xcBssiv~ heat may cause production of h~zardDu5 d~COffiPosition prQducts~ SECIIO~_~_HEHLIH_H~ZãBD_Dêlâ I8RESHQLD_LI~II_~éLUE SeB Section II OS8å_IH8ESHQLD_LI~II_~éLUE_ åCGIH_IHRESHOLD_LI~II_~åLUE S~e :J-?ction II ~3E;~ SE:ctiofi II CéRClruOGEN_=_NIE_£ROGRãM_ NonB Known CãRCINQGEN_=_lêaC_eRQGaå~ None Known SY~£IO~S_OE_ExeOSU8E Complaints of burning or irritation ûf th~ éY€S and mucous m~mbfan~s ~~ we11 as th~ dev~ioPffient of skin irritation; Vapor is irritating: ~EnICèL_COMnIIIONS_äGGaå~áIED_Bÿ_EK~OSuaE Nüf¡€ known.. 28IMêRŸ_HOUIEiSl_OE_ENIËŸ Eyes, skin, in9~stion and iDh~iation E~EBGENCŸ_EIRSI_äID tÿES: Flush with water tor at l~ast 15 minutBs and s~t ffiBdical attentiDn, SKIN: Flush skin with plBnty (If W¡¡t~f·, If skin Ìi'r-itation Of' a.lll?f'9ic !'eaction Mvei(lp~" 9é :T!edical attention. INGESTION: Seek imffiediat~ medical advice 9ivin9 full dBtails of amount swallowed and toxicity, INHALATION: Remove to fresh air. SECIIQN_~l_aEäCIl~IIŸ_DåIä SIãBILIIL ::;tabl~ CQNDIIIQNS_IO_à~QID N(,n,? f:;nO\!!r: INCO~2áIIBILIIY_iMêIERlàLS_IO_à~OlDl ~;tr'ons Alkoil ii?S öàZáBDOUS_20LYMEBIZéIIOM_ Wi 1 i f;(lt OCCilr' CONDIIIONS_Iü_ã~OID None Kn«wi! HêZêaDOUS_DECQMeOSlIID~_~aoüUCIS CarDDn DiDXid~ and-or CarDon Monoxide ~ ~ _,5 <. - MATERIAL SAFETY DATA SHEET # M-06 . '-,"'"T.-,r-n ,..lr'''''''.~'J:: '-.L nCV!~tk LH!C £~-Ow SECIIQM_~II_EM~ltiQMjE~IåL_2aQIECIIQ~_2aOCEDuaES selLL_HEseO!::JSE W~ar prot~{tivB clothing as sPBcifi~d in Section VIII; If F~derail Stat~ and/or Locai r~9u1atiDns permit7 neutralize with Sodium Bicarbonate and flush to sewer with large amounts of water= Otherwise add drY absorbent, c1~aü UP añd place in an approved D;ü:T; (Dnt~in~r1 label and s~aj for disposal ~êSIE_nIS2QSêL_~EIHOD if Fed~ral, Stat~ and/or Local r~9ulations permit: flush n~utralized material to s~wer with large amounts of water. Otherwise dispose of contaminated product and materials used in cleaning UP spills in a manner approved for this material. Consult proper Federal, State and/or Local regulatory a3enci~s to ascertain prope~ disposal prüc~dure5: SECIIO~_~III_S2EClèL_e~úIECIIO~_1~EúR~ãIlO~ E'iLE:!iOIECnDrL SKI~_E:RQIECIIO~ Saf~ty Glass~s Of G0991~s Imp~ryious slDv€s should be iliO~O: BESEIBåIOBY_£RûIECIIQ~_iSeECIEY_I1EE1_ Approved or9anic respirator in high concentrations ~E~IILåIIQW_aECQööE~DEÐ Good ventilation r~~uired üI~ER_2ROIECIIOM As nfC~SS~rY to prev~nt eY~ and skin contact; SECIIQ~_lX_S2EClåL_eaECåUIIO~S HYGIE~IC_2BåCIICES_I~_HêMDLI~G_åMD_SIORåGE Keep ti9htly sealed. Do not store or consume food, drink or tobacco in area where they may b~coffie contaminated with this mat~rial, Store abov~ 40 D~9, F (4C). Avoid unn~c~ssarY personal cont~ct; Avoid incompatible substances. Wash thorou9hly after handling, OIHER_2RECãUIIOMS Material is classified as a combustible liquid. Keep away from heat and flame. ¡he information contained in this Material Safety Data Sheet is fUf'nished without warranty of any kind. ihe user must make independent determination of suitability and completeness of information to assure pf'vper use and disposal of this material and safety and health of employees and customers. This statement is incorporated as part of this Material Safety Data Sheet, - - ,f ~:"""'-#~.'~ 2EODUCI_~8jEI AVTEX DEVELOPER REPLENIS~ER PArT C CHEMICêL_E~MILY_ PhDt~gra?hic DtV21c?0P £BQtEH_D~O~I~_SHI2EI~G_~êME_ C~rrosiv~ Liquid N:O.S. t1t~üEfjCIUaEfl_ ALLIED PHüTO PRODUCTS co. 5440-A OakbrDok Parkway Norcross, G~orsia 30093 2aINCleéL_EãZ~8DûUS_COM2ü~E~IS_ GLUTARALDEHYDE BüILI~G_2ülf:JI_ G~~~ter Than 212 D~s. F: (lOOC) ~B20B_EEESSüBE_iMM_~G~1_ ÅP?r"ü}::. 17 ~êeC8_DE~SlIY_iåI8_=_11_ HPP¡-Ü}::. 0; /:.. SOLUBILIIY_IN_~êIEa_ Compl~t;? 82~E~8ê~CE_ê~D_ODGa . ~ãIEEI~L_SBE~IY_DBI£_SbE~I SECIION_l_GE~EB8L_I~EOH~ãIIOlli SECIIQ~_II_I~GaEÐIE~IS C~8J1.S..~_ eŒCH.iL C~¡;:;# 1 i 1-~:O-8 jJ) 40 SECIIQ~_lll_eHYSICåL_Dêlfi Cl~a~ al~Dst cûlori~ss ii~uid with an ald0hyd~ ..oJ... ¡¡!:t!!-. -,- ì~:SD~'f t~1-07 .f._No ,..'. ..... I '_"_' RE\lI~:;ED D;~TE~ E8tt1U~Ð AØJE I GUS ,,~ . I ·!1::-:''L:l:··0 D,Q~:~_b~Z88Ð_SLèSSIEICBIIO~ C0~rjsiv~ M~t2riQl UN# 1760 bB~~~~SIURERS_2HQ~E_~U~BE~ (40~:· j L}i.}t:-Ü250 CtEBIBEC_EHQ~E_JU~BE~ (800) L12lt-9:300 IHtiESHJLD_LI~II_~åLUE èCGI~ GStl~_E:EL O.2PPN {(:) S2ECIEIC_GR8~IIY_1~BIE8_=_11 ¡~\ppr'G::{:< 11; Üf:, 2EaCE~:_~DLëIILE_BŸ_~OLUME Appr!»~= 75 E~êeüBåIIQ~_B9IE_i________=11 Not (ivai 1 db j '2 EtI HPpr':)~; 1:.'= t:Ü NA1tRrA[·-~~~ETY DATA SHEET # ì1-Ü7 . HEVISED DP¡TE: .""-'J ¡-~.!.. , -- SECIION_l~_E18E_~~D_EX~LOSIQ~_8~I~RD_Dêlé ELèS8_2QIUI_iIESI_ôEI~üDl_ 8UIQ_IG~IIIO~_IEMeEaHILaE Nün Cümbu;:.tibì~ N(tt ~ .. . ~ HP¡:-¡lCa~¡¡f: ELåt:1r1êBLE_lliSIIS t i-! l........ ~ lïi !oJ!.-'" Non\? Non~ ¡-~ür¡;2 EXII~GUlSHIMG_~EDI~ Us~ th~ mëdia SU99~Stëd LV extinguish th~ ~·O!jr-C:2 .~..r. .t.t * '~i U¡-;: t If,? . seECI~L_EI2E_EIGdIIUG_EROCEDU8ES ¡':'.I!!;:: UMUSü8l_ElaE_8~D_EX~LüSIO~_bêI8ans NÜi¡:2 SECIlûN_~_bEBLI~_HëZBaD_DâIg IHBESHQLD_LlölI_~ëLüE OS~g_IHaESHOLD_LIMII_~êLUE_ 9CG18_IH8ES~QLD_LIBII_~ÐLUE ::;i?-2 ~;Bct i on I I - - . - ...- ::;;:;.;:: :~'2ctlün 11 ::;'2;2 :::;?d i ün II CHaCI~OGE~_=_~Ie_EaüGaäM_ C8aCl~OGE~_=_lê£C_eaQGHèM Nr)n~ Kn:::wf¡ NOíi;? KnowÏ! Si~~IDMS_OE_ExeüSU2E C(¡ITip1aints i)f burning ÜÏ" l;-o¡-itatiüf¡ of th~ f;'-{BS and ji¡!JC(1IJS f¡;~mt!r~n~~o ~5 llif.'lì as th~ d~v~l::rpmE'n'( of skin irritation or Dermatitis; VaPDf is . "1 l' lr-T-1Ta-Clfì9. ËEDICåL_CO~DIIIOMS_GGGa9~åIED_BY_EX20SuaE NÜf¡2 known: eRl~ãBY_8DUIE1Sl_OE_E~IHY E··{e~.: skin; if¡9~stion and inha1atiün E~EaGE~CY_EI8SI_gID EYE::;: Flush u.!ith ill~t-=r- tOí' at 1-2~5t 15 mir;utês and 92t ITi€:dii:a1 att~f¡tiüf¡; t:¡<IN~ Flush s.kin with plent..{ of water= If skin irritation Dr allergic reaction develops? get ffiedical attentiOD= INGESTlüN~ Se~k imffi~diat~ m~dic~1 advic€ 9iving fu11 d~tai1s of a@Duút silla!;ojed 1nd tDXICIty; INHALATION: R~8Ûve t~ fresh air: tr~at sYmptoillatic~11y and 9~t [~dical att~nti0Dc SECIIO~_~1_8~2CII~IIi_D¿Iª SIëBILIIL CQ~DIIIO~S_IO_~~OID St.;h1ë Nün~ Known IMco~eêIIBILlIY_iMèIEHlBLS_IO_9~OIDl Minera1 Acids and Strons oxidiz~rs HéZHaDoUS_eOLYDEaIZêIIQ~_ CQMDIIIO~S_IO_g~QID Wi]1 not OCCUf Non;? Known HêZãaDQUS_DECQ~eûSIIlüM_2aüDUCIS Sulfur Dioxide aod Carbon Dioxide -2- MA-~AL-~~FETŸ DATA SHEET # M-07 e rrr!!1.-·:-r· r:ATCe.:'"1 I"f.' r~t: Vi .:I!:.iJ !...!H I:'" 1/-0;:· SECIlü~_~II_Etl~IRO~~E~I8L_eaüIECIIO~_E£OCEDuaES seILL_EEseOMSE W~ar' prot~ctlv~ clothing ~; specifiëd in Sèctioú VIII: If Fèd~rd~: Stat~ and/or Local r~suìations pi:ri:¡it: f¡~¡jtr·;:d iZi2 tjth ~:;i)diuITi f~1~tabi51j1fite and fìiJsh to S¡?ill:er' with l~i·S.? ~fi¡(iunt::. of water-. Otht:i'wi::-t? add dry absorbent, clean UP and place in an ~pproved DtO=T= container, label and seal for disposal W~SIE_DISeüSgL_BEIHOD If F~d~ra1: state ~Dd!ûr Loc~l f~9u1ati0DS p~fmit, flush niutraliz~d m~teria1 to sew~r ~ith !dr9~ amounts of water: Otn£rwis€ disPúSf of contaminated product a~d ffi~teri~ls used in cle;üins UP spil1s in a m~nnfr aFPrûv~d for this mat~rial: Consu1t proper F~dfral: Stat~ a~d!Dr LDc~i r0su1atory a9~nci~s to ascertain Proper disposal p~ûcfdu~~s: SECIlü~_~III_S£EClêL_£~QIECIION_lNEOR~8IIO~ EŸE_Ë~OIECIIOtJ_ SUi:LŒÜIECIlQ~ Saf~ty Glass~s or GÛ9g1BS Impervious s1ûves shoUld U~ uorúc RES~IBäIßHY_EeOIECIIO~_iSeECIEY_IYËE1_ ~E~IILåIIO~_BEcüM~E~nED Approved organic respirator in hish concentrations Gùod veDti1~tiGn requir~d OIHER_~EüIECIlüN As n~Cf5SafY to prevfnt - ' - a.nd skin conta.ct: SECllüN_lx_StEClšL_EBECëUIIONS HYGIE~lC_eRêCIICES_l~_HêtlDLI~G_ê~D_SIOaëGE Keep ti9ht1y sealed: Do not store or consume food: drink or tobacco in area where th2Y ma~ b~Cûmf cOutaminated with ~his mat~~iai: Stofe above 40 De9: F (4C): AVDid UDnec~ss;r~ p~rsû~al cûnt;ct= Avoid incDmp~tibl~ substanc~s: W~sh thO~0U9hiy aft~r h~ndlin9: DIHEH_eBECBUIIONS ïh~ routin~ us~ of _ nùn-alk~lin€ (aCId typ~) hand clfa~er will mi ni;;¡iz~ th,o püs~.ibi 1 it\"· ;"¡+ ;¡¡¡~:::r·~pr _. . _. _ M _ skin r·£action= Thè information contained in this Mdt~ria1 Safety D~ta Shè2t is fu~nish~d lliithout Qarrantv Df riuY kind: Th~ us~! must m~k~ ind0P~ndent d~t~rmincitiDn of suitability and c0mp1ët~n~ss of infDr~atiûn to assure prop~~ use and disposal of thi~ material and safety and h~alth of employees and custoœers: This st~teffi~nt is iùcorporated as part of this Mlt~ri~l Safety D~t~ Shèet: - .... j< fBODUCUQt1El . AUTEX Fixer & Repl Cone P~rt A . , æEt!ICêL£êMlLL Photo9raphic, Fixer ER02ER-n.O~I~_SHIe21~G_tlêME-· Not Re9ulated t1AUUEACItÆER_ ALLIED PHOTO PRODUCTS· CO. 6410 Atlantic Blvd. Suite 120 Nor'cr'oss, Gel)r'9i~ 30071 ~RI~C12äL_8êZêRDOUS_COMED~E~IS_ AMMONIl~ THIOSULFATE :::ODI!JM ~;tllF1TE ACETIC ACID BOlLHKLE:OlUL 13rt-ater Than 212 [I~9, F. (1(1(1(:) ~~208_ËaESSU8E_i~~_8G~1_ APrr'ç ì~, 17 Vá20R_DEtlSIIY_iêI8_=_11_ APH't)(. 0.6 SOLUBILIIY_IU_WáIE8_ C,)n¡plete . MêIEBlaL_SêEEIY_DAIA-SHEEI SECIlOtLLGEtÆBALIt£OBMAIlml SECIIOM_II_IMGREDIEMIS C.ê.S.IL CASIt 7783-18-8 CA~;# 7757-33-7 CAS# 64-19-7 , 2EBCENL 40 - 60 4 - 8 2 - t, SECIIQU_III_eHYSICêL_DáIê Q£E~~CE_ê~D_ODoa Colorless liquid with ~ sli9ht ammoniacal odor. -1- t1SD# t1-11 A REVISED DATE: 111'-5-86 REV. #01 ('11 (') 3'aÝ . / EORMULA Aqueous Mixture D~O~I.~HQZêBD_CLQSSIEICêIION Not Applicable MêtlUEêCIUBEBS_2HOtlEJNUMBEB (404) 448-6120 CHEMIaEC_eHO~E_tlUMBEB (800) 424-9300 IHRESHDLD_LIMII_~aLUE êCGIH OSHê_eEl 10PPM 10PPM SE:ECIElC_GE:êV IIL iWêlEE:_ = _,11 ApPf' o::{. 1. :::3~1 EUCENL!20LêIILLBY_\20LUt1E APHO>~. 50 E~êE:OaêIION_8êIE_i_______~=11 Not Ava.ilat.le eH ApPr'c,::<. 5.20 ~Ýô ~.. __+__.~t"-......~:', !~.: " ~~, . . ~ ~ .,¡,:, . , .,' . . , .. i,. MATERIAL SAFETY DATA SHEEn M-tt '. )0' REVISED DATE~2S-86 REV. !lOt SECIIDtLlll_EIILaNILEXELOS1otLliazêBD;,.Dêlê êUIO_I~lIIO~_IEM2EBêIUBE Not Appl~cable El.ASIUOltfi-1IESIJ:!EIl:lODL Non Combustible .'. E\.At!IABl.E..LUS None LEL None EXIltÐJlSHlOO.JŒDlê Use the. iIIediá SU9gested toextin9IJish the source of the fire.' seECIALElBE..El00II~G.;.2BOCEDUBES None . . lJiUSUAL.ElaE:..atm_EXE1..OS1otl-HêZêRDS None SECIIO~_~_HEaLIH_IiAZêBD_Dala IHBESHOLDJLIMII~~aLUE ~;ee Secti on II OSIiQ.;.IHBESHOLDJLIMII_llêLUE_ See Section II . CêBCI~OGEN_=_NI2_eeOGBAM_ None Known SïM2IOMS_OE_EX20SUBE Low hazard for usual industrial handlin9 MEDIcaL_CONDIIIONS_êGGBê~ê~ED_BY_EXeOSURE N(,ne kn(,wn. E~IMaaY-ROUIEiSl_OE_E~IBY Eyes, skin and'ingestion UEL None aCGlli_lIiBESIiOLD_LIMII_VALUE See Section II CaRCIMQGEM_=_laaC_2ROGBê~ None Known EMERGENCY_EIRST_AID EYES: Flush with water' for at least 15 minutes and 9.et medical attention. SKIN: Flush skin Illith plenh' of water'. If skirt inihtion or' allH9ic reaction develops, get medical att€'ntion. WGESTION: Seek imrrlediate IT,edic;¡,l advice givin9 flJll details of ;¡'ff¡Olmt swallowed and toxicity. SECll~_Ul_REaCIIUIIY_Dala SIêBILlIY- Stable I~COMßaIIBILIIY_IMaIEBlêLS_IO_aVQIDl Strong Alkalies HQZaRDOUS~YMEBIZêIIOM_ Wi I) not o CClJ f' HêZaRDQUS_DECOMEDSIIIO~_EBûDUCIS AJ!JlllorlÍa # -2- CONDIIIQNS_IO_a~OlD N(lne Kn(11I1rI CONDIIIO~S_IO_ê\lOID None known J , ~. \ .;. I :1 I'IATERIALWETY DATA SHEETi 1'1-11. . REVISED DATE~-86 ~' ~.~1 ' SECIl~Yll~~lBOMMENIAL-eBOIEé~l~_eeOCEDUBES 5elLLBESeOtŒ ' W~ar·protectjve 'clothïng as specified in Section VIII. If Federal, State and/or Local regulations permit flush to seWH' with large amounts of water., Otherwise add dry absorbent, clean UP and place ,in an ,approved D.O.T~ container, label and seal for dispo~al wasIE-DISroSaL~OOD , , If. Federal, State and/Qr lQcal regulations permit, flush ~terial tQ sewer with large amounts of water. Oth~rwise dispose of contaminated product and matepials used in cleaning UP spills in a ~nner approved for this material. ' Consult proper Federàl, state and/or Local regulatory agencies to ascertain pr.'oper disposal procedures. SECIl~_U111_SeEClaL-EROIECIlON_lNEOeMQIl~ EYE~IECI1~_ . Safety Glasses or Goggles SIŒLeROIECIlOM Impervious gloves should be worn. B£SeIRaIOBY~~IECIIO~_iSe£CIEY_IYeEl_ None should be needed ~IILaIIOM_BECOMMENDED Good ventilation requirtd OIl:!ER.£Ii'OIECIlON As necessary'to prevent eye and skin contact.' SECIlON_ILseEClêLeRECêUIIOMS ~YGIEMIC_eaêcIICES_IN_8êMDLltlG_B~D_SIOHêGE Keep tishtl..v seaLed. Do not st¿re or consume food, drink or tobacco in area where they may b-?coITie contaminated with this rrl1.tHial. Stof'e above 40 De9. F (4(:), Avo'id UNleCeSS;¡TY PHsorl1.1 C')fltad. Avoid incompatible substances, Wash thorou9hlv after handlin9. QI8EE_eaECêUIIO~S Neonfo The information containfod in this Material Safety Data Sheet is furnished without warranty of any kind. Hi£' us\?(rrlust nlate irld~P\?ndHltdi'tHrrlif¡atiNI of suihbilib' and cO[flplehnf:55 e·f informati')!1 to assure proper use and disposal of this material and safety and health6f employees and custo~~r5. This statement is incorporated as part of this Material Safety Data Sheet. . -3,.. , '~\ (. :,t, :' I ¡ , , , , -' I I , I , .'~ ,',. , .. ~' . 'j ," r /'.~ eBOnuCI-HatIEl AUTEX. FIXER PART B ~tr.AI FQtllLY;,. "" PHOTOGRAPHIC FIXER 1 ". ,~D.O.I._SHI221~G_NêME~ ALUMINUM SULFATE SOLUTION t1êNUEaCIUBEIL ALLIED PHOTO' PRoDUCTS C'O. 6410 Atlàntic 'Blvd. Suit~c120 Norcross, Geor9ia 30071 ~~I~Cl£aL_~aZaaDOUS_COMÐO~E~IS_ ALUMI~JM SULFATE E;ûlLltifLE:Olt:JL GREATER THAN 212 DEG. F. (100C) ~(jE:Oa..E:EESSU¡;Ll~tLtJG~L , NOT AVAIL(:,BLE ~~E:QE_DEUSIIY_1ßIE_=_11* NOT AVAIALABLE SOLUBILIIY_IU_W~IEa_ è:OMPLETE Q£E:EßRê~CE-êUD_OD08 WHITE, COLORLESS, ODORLESS LIQUID. '. \ tlGIEBILSaEEIY_DêIê..Sl:lEEI SECIlOtLLGEtÆBêLltJEOBtJAIlON , -' SECIIO~_II_I~GREDIENIS C.ê.S.1L eEaCENL CASjj 10043-01-3 20 - 30 SECIIO~_III_E:HYSICêL_Dalê ~ -1- I1SDjj M-12 REVISED DATE1a7-86 \ . (G'-~) if -' '- pr-. (6~ .Fr EORMULa AQUEOUS MIXTURE D.O.I._HêZêRD_CLêSSIEICêIION ORM-B t1êNUEêCIUBERS_E:HONE_NUMBER (404) 448-6120 CHEt1IREC_E:~ONE_NUMBEa (800) 424-9300 IHRES~OLD_Llt1II~~êLUE aCGl~ OSHa_tEL 2MCi-M3 SE:ECIEIC_GRê~IIY_iYêIEa_=_11 APPRO X . 1, :;:2 E:E8CE~I_~üLêIILE_BY_VOLUME NOT AVAILABLE E~ßeOEêIIOU_EaIE_i________=11 NOT AVAILABLE EH . APPROX. 3.00 .' .... . '. -."': .... :,' '.' . , ,J :- ¡ .>' ','.-',.'". ".' ., 1";"" ,~" . '\ ~ " .' : ~ . ": "", " (I~ MATERIAL~TYDATA SHEET # M-12.. " REVISED DAT~.17-86 '~~ SECIlaU~IYJE~~DJEleLåsio~_HQZQRD_DQIQ' ' ELêSH..£OltiLiIESLMElOODL NON COI'IBUSTIBLE AUIO_IGNIIIO~_IEM~ERaIURE NOT APPLICABLE F1 AMMARI f I IMIlS ,NONE, , LEL NONE UEL NONE EIIltiGUlSHllMLtIEDIA USE THE MEDIA SUGGESTED TO EXTINGUISH THE SOURCE OF THE FIRE. ' S~E1REJEIGHIl~G_eRQCEDUBES NONE UtillS1JALJElæJlt¡ DJEXrLOSlOtLHQZêRDS NONE SECIIO~_Y_UEQlIU-HQZABD_DQIA lHaESHOLDJLlMlI_QêLUE' :::EE S'ECTI ON II OSUQ_IURESUOlD_LlMII_YQlUE~ SEE SECTION II êCGIU_IURESHOlDJLIMII_~9lUE SEE ~;ECTION I I CêRCINOGEtl_=_NI2_2aOGtiêM_ NONE KNOWN ' CQRCINQGEM_=_lQRC_2ROGaê~ NONE KNOWN SYMeIQMS_OEJEXeOSURE CAN CAUSE EYE AND ~;KIN BURN:, AND/OR IRRITATION. MEDICêL-CO~DIIIOUS_ÊGGaÊ~äIED_BY_E!POSUaE NONE KNOWN, E~IMêaY_aOUIEtSl_OE_EUlaY EYES, SKIN AND INGESTION ," EMERGEtlCY_EIRSI_êID EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. SKIN: FLUSH SKIN WITH PLENTY OF WATER. IF SKIN IRRITATION OR ALLERGIC REACTION DEVELOPS, GET MEDICAL ATTEtHTON. INGESTION: SEEK IMMEDIATE MEDICAL ?¡DVICE GIVING FULL DETAILS OF AMOUNT SWALLOWED AND TOXICITY, SECIION_YI_REêCIIYIIY_DQIQ SIQBIlIrL STABLE COtlDIIIONS_IO_Q~OID NONE KNOWN INCOMEêIIBILIIY_iMêIEBlêLS_IO_êVOlDl ALKALIES; ~êZêBDQUSJeOLYMEBIZêIIQN_ WILL NOT OCCUR CQ~DIIIQNS_IO_êYOID NONE KNOWN HäZQRDOUS_DECOMeOSIIIO~_£aODUCIS SULFUR OXIDE þ -2- 1'1 . I i ,'. r,'-,' _',.'.',;,. . ;.' " . .....; J' " .-": ~!n" " . . . . . ",'" " , ' ;. "" ~.,~' ·C', ',~ ¡ MATrnIAL "SAFETY DATA S'HEET I 11-12 . I . '. . REVISED DATE.-17-S6 ~,.. SECIlClbUllLEtNl ¡ EblIaLeR~}IECIlotLeRQCE~URES . ~. selL.L.BESeOUSE WEAR PROTECTIVE ctOTHING AS SPECIFIED IN SECTION VIII. IF FEDERAL, STATE AND/OR LOCAL REGULATIONS PERI'1IT, NEUTRALIZE WITH SODA ASH AND FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER. OTHERWISE ADD DRY ABSORBENT; ClEAN UP AND FtACE IN AN APPROVED D.O.T~ CONTAINER, LABEL AND SEAL FOR DISPOSAL WASIE..Dlæ05ALl1EliJOD . .. . . . , IF FEŒRAL. STATE AND/OR LOCAL REGULATIONS PERMIT. FLUSH NEUTRALlZED MATERIAL TO SEWER WITH· .. LARGE AI1OONTSOF WATER. OTHERWISE DISPOSE OF CONTAMINATED PRODUCT AND MATERIALS USED IN CLEANING UP SPIllS INA MANNER APPROVED FOR THIS MATERIAL. CQNSULl PROPER FEDERAL, STATE AND/OR LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. SECIIO~_~lll_S~EClQLJeROIECIION~lNEORMaIION EYE.£BOIECIlOtL SAFETY GtASSES OR GOGGLES , . SlmLeBOIECIlON IMPERVIOUS GLOVES SHOULD BE WOh~. RESelRêIORY_~OIECIlON~iSBEClEY_IYeEl_ tK~E SHQIJLD BE NEEDED .~NIILêIION_RECOMMEMDED 1 GOOD GENERAL VEt4TILATION. r OIBER_~ROIECIIOM AS NECESSARY TO PREVENT EYE AND SKIN CONTACT. SECIIO~_IX_S~ECIAL~RECêUIIOMS ' HYGIENIC_eRACIICES_Itl~HêMDLltlG_êMD_SIORêGE f~EEP TIGHTLY SEALED. DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN AREA WHERE THEY MAY BECOME CONTAMINATED WITH THI~; MATERIAL. STORE ABOVE 40 DEG. f (4C). AVOID UNNECE%ARY PERSONAL CONTACT. AVOID INCOMPATIBLE ~;!JK:TANœ::. WA~:H THOROUGHLY AFTER HANDLING. ' · OIHER-PBECêUIIO~S NONE à THE'INFORMATION CONTAINED IN THIS MATERIAL SAFETY DATA SHEET IS FURNISHED WITHOUT WARRANTY OF ANY KIND. THE USER MUST MAKE INDEPENDENT DETERMINATION OF SUITABILITY AND COMPLETENESS OF INFORMATION TO ASSURE PROPER USE AND DISPOSAL OF THIS MATERIAL AND SAFETY AND HEALTH OF EMPLOYEES AND CUSTOMERS, THIS STATEMENT IS rtlCORPORATED AS PART OF THIS MATERIAL SAFElY DATA SHEET. ...' -3':' , . . . , , .'./ ' .. ";',.. ~'..' ,~'. . . , ' .~ þ ~~. -- eRODUCLNêMEi. AUTEX,Developer Repl C~ncentrate Part A ClÐlCaL..EatJILï__ Photo9raphic Developer ERoeEILD.O.I._SHlrElt:JG_t:JêML__. ' Not Re9ulated . t1AlliÐCIUBER_ ALLIED PHOTO PRODUCT;: CO. 6410 Atlantic Blvd. Suit~ 120 Norcross. Geor9ia 30071 ~RIUCI~aL_HêZêRDOUS_COM20UE~IS_ HYIiROQUINONE ::;ODIUM :3ULFITE ~;ODIUM TETRA BORATE F'OTA%IIJM HYDROXIDE BOILlt:J!J_E'ûlt:JL C1ftatH' Than 212 (1"'9, F. nOÜC:) ~B20a_2aEssuaE_iM~_8G~1_ Approx. 17 ~êEOa_DEUSIIY_lêla_=_11_ AFProx. 0.6 SQLUBILIIY_I~_~êIEa_ COßIPlete ê£E'~E..êtJlD_DDOa Sli9htlv yellowish odorless liquid. . ~ MêIEHlêL_SêEEIY_DêIê_SHEEI SECIION_l_G~ERêL_lNEDRMêIIDM SECIIOtl_ll_I~GREDIEUIS C~ê~S6IL E'EaCENL CASJI 123-31-9 CA:3# 7757 -83-7 4 - ::: 15 - 30 CAS# 1303-96-4 2 - 4 CAS# 1310-58-3 \ 3 - 6 SECIlüU_lll_E'HYSICGL_DáIê -1- M:::DJI M-05 . REVISED DA\~ ~3-14-86 (; c z.J-~~i) ': 31aQ ,- ;/'10 . :3 EORI:JULê Aqlje('IJS Mi>::tur'e . ~ D606I._HêZêflD_CLêSSlElCêIIOt:J Not Applicable MêUU£êCIU~ERS_E'HOME_UUMBER (404) 44:::-6120 CHEtlIaEC_eHÙ~E_tlUMBE~ (BOO) 424-9:;:00 IHHESHûLD_LIMII_~àLUE êCGIH OSUã_2EL 2r1Ci-M3 2NCi-M~: 1t'1Ci-M3 2NCHE: (C) S~£CIEIC_G&ê~IIŸ_i~~I£8_=_11 Åppr ü:;{. 1,2::: F:ŒCEt1L~OUH ILLB\L'~OLUt!E {\PPf'Ü\ :::0 EllgE:08iH IOt:LHf¡ICL__ ___. __= 11 1M Av~i iiìb1~ EH Appro>::. 11.30 f,: ~il"t"<'~~~" . ,,' l1ATE8iÞl' -~"':¡~':,,: -:.:.... ;..." ·<..",·,(~'·,·k ,,"., . ""DATA'SHEETI \'1-05 "~ ,'.' ·t. SECIIO~_lY~EIQfANnJE1ElOSION-HQZQBD-DQIQ " . ,;.;."; ~. " .: ~':. :.." -r^ . .' <r".'. " I ." æEClaI.:..E¡BE..EItHIIMG_æüCt:DUBES , Norle lIlUSUAL..ElRUtID-EXrLOSICtLHazaBDS , None lHaESHOLDJL~lI_~êLUE ::;~t! Section II, CêRCl~_=~_eROGRêM_ None Known REVISED DAT~~14-S6 " AUIO_IG~lIIQN_~RQIUBE Not App Ii ca.b 1 e .. LEI. : None SECIlaN_~-HEQLIH-HaZQBD_DQla OSHa_IHBESHOLD_LIMII_~aLUE_ See Section "II UEL None aCGIH_IHBESHOLD_LIMII_~êLUE See SÍ'ction II CQBCINOGt:N_=~IQaC_eROGaã~ None Kn(lwn S~M~IOMS~OE-ExeosuaE C(lITiplaints (If blJf'nirl9 (If' ir'f'itatiofl (If the eyes and mucous meITibf'anes as wÍ'll as the devel(lpment (If skin ittiation Ot Detmatitis. ," .', -I . ~.¡.' . ' .' :. f'A.<:Ii',énttìr: f-n::~I-tIEIIiODL , "NOnC,~ustible' ;-.-.';:...- . .>/.<! i:,::-:~ '. "..' .'.' ~ . :?,,: FI AM\íII=,'1 tMtT~ ' ft.·N~~·\~;::'~;::;;'~'D;; . . , ElIitÄlt~tÞr.lfl'lA , ,. 'Use tile 'lied it. suggested tó extinguish. the source of the 'firé. MEDICêL_CONDIIIQNS_êGGaQ~GIED_BY_EX20SURE None Known ERlMaRï-&]uIEiSl_OE_EUIRï ['ft.-51 skin and in9t.'sti(,n EMERGENCï_EIBSI_êID EYES: Flush with water for at least 15 minutes and get medical attention. SKIN: Flush skin with plenty of water. If skin itrititio~ Ot allet9ic teaction develops. 'get medical attÍ'ntion. INGEStION: Seek ÜI!T!Í'diate !TI?dical advice 9iving full dÍ'tails(lf amount swal10wed and tco:><:idty, , :r' , SIaBIUIY_ Stable' IN~IIBILIIY_lMaIERlQLS_IO_a~OIDl Mineral Acids .... WQBDOUS..eOL.YMERlZêUaN_ Wi 11 not occur HQlQBDOUS~lIION~2aQDUCIS Sulfur Dioxide SECIION-YI_BEêCIIYIIY_DQlê ~ -2- CQMDIIIQMS_IQ_Q~QID None Known COMDIIIOMS_IO-ê~OlD None Known . , , , " -. ":~¡;~:~~::~.~~):' MATERIAt.;~DATA SHEETt M-QS.¡ " REVISED, DATE:.,4-S6 .' SECIlaN_~llJEN~leOü~NlaL~aIECIlaN~RaCEDURES selLLBESmlSE ~ar protective clothin9as specified, in SectionVIU. If Feder'al, ·state and/or Local r'e9ula.tions: permit, neutra1ize with Sodium Bisulfate and flush to selller with largeantOunts of water. . Otherwise add. Dry '1bsor'bent.. clean UP and phce in an approved D.6.T., container, label '1nd seal for disposal ," '.' .. WêSIE..DlseosLtlEIHOD If Federal, State al1d-:-'or Loá1re9ulation permit, flush neutr,a.1iZ'edlnater"ial to sewer with . large amounts of blater'. Other'wi~e disPose of contaminated product and materia.1s used in cleaning UP Bpi 11 s in '1 manner approved for' this lTIiJ,terial., Consult pro:per Feder-aL, State and-or Local r-e9ul'1tof'Y '1gencies to"' ascertain pr~oper' di5P.osa 1 prCtcedures~ ' . '. .. . I'" '. " SECIION_UIIl_SfEClêL_eROIECIlONLINEORMêIION EYLeROIECIlOtL SafetvGlasses or G0991es SKHLreOIECIlON Impervious gloves should be worn aESelaarORY~ØBOIEcIIOtl_lS2ECIEY_IY2El_: None sholJI d be ne~ljed ~NIILêIION_eECOMMENDED Good ~eneral ventilation OIl:!ER~ROIECIlaN A5 hecessarv to prevent eye and,skin tontact~ , . S!CIION_IX_SrEClêL~RECêUII~S' HYGIENIC_eRaCIlCES_ltl_HêMDLl~G_aND_SIOeêGE Keep ti9htly sea.led. Do not. store or consume food, drink or- tobacco in ar-ea where they may become contaminated with this mater'ia1. Store above 40 De9. F (40. Avoid IJnnecessar'yper-sona I ,:?iltad. Avoid incoRIPatible ~ubsta.nces. Wash thorou9hlY after handlin9. . " O:ruEILeRECêUIlONS The routine use of a. ~on-alkaline (acid type) hand clean~r will mi~imize th~ possibility of aller9ic , ~ skin reacti~n. I The information contained in this Material Safety Data Sh~et is furnished without warranty of any kind. The us~r must ma.ke independent determination of suitability and completeness of information to àssure proper use and disposal of this material and saf~ty and health of employees and customers. This statelllent is incorpor-ated a.s part of this Material Saf~ty Data. Sheet. , ."' . j -3- "" ,þi:;" : . æDDUCLNêME.:. AUTEX DEVELOPER CONC~NTRATE PART ,9 ' CHEMICêLJEêMIlY_ PHOTOGRAPHIC DEVELOPER rROeER_DLO¿I~_SUIeeIUG_~êME_ ACETIC ACID MêNUEllCIUBEEL " ALLIED PHOTO PRODUCTS CO. 6410 Atlantic Blvd. tuit@ 120 Norcross, G@or9ia 30071 ERINCleêL~êZêRnOUS_COMeONENIS_ ACETIC ACm 1-PHENYL-3~PYRAZOlIDONE BOILltffi_eOlNL GREATER THAN 212 DEG. F. (10«(.) ~aeaBJeaESSURE_íMM_UG¿l_ ff'PROX. 15 YêfOB-DENSIIY_iêIR_=_11_ APPROX. 1.83 ~II mIl TIY_INJ:JêIElL COI'fLETE e¡, ---" MêIERIêL-SêEEIY_DêIG~SUEEI SECIIOM_l_GEMERêL_IMEO~Il(~ SECIION_II_INGREDIENIS C¿G¿S¿I_ EEBCENI_ CAS# 74-19-7 40 - 70 CAS# 000092-43-3 7 - 15 ' SECIIOM_lll_eHYSICGL_DGIG ~_êtlD_ODQR LIGHT BROWN lIQUID WITH ODOR OF VINEGAR ... -1- ,.-\ .-;,.. MSD# ~ REVIS.TE: 03-25-8t, . . EORMUla AQUEOUSMIXTIJRE D¿Q¿I¿_UêZêBD_ClëSSIEICêIIOM CORROS I 'JE MATER I ~L UN# 27:3':; MêNUEêCIuaEaS_Ë~üNE_~UMBEB (404\ 44::::-t.120 ŒH1IBEC_,ËI:JONE_t.-JUI'JBEB (800) 424-9300 I\; RES\; OLD_LlMIL~áLUE êCGII:J OSHH_ËEl 10PPM seECIEIC_GRê~IIY_iWêIE8_=_11 APPROX. 1.03':, eEBCEMI_~OlaIIlE_BY_~OLUME APPROX.90 E~ê20BaIIOM_aáIE_i________=11 NOT APPLICABLE, j , ! el:l APPROX. 2.50 i '\ ! ! (.f , > . ~ SECIIO~lYJE~E-ê~DJEX~OSlO~_HêZêRD~DQIê REVISED DATE~S-86, , . '. ' . .... . .' . IjATERIAL SAFETY DATA SHEET * 11;..06 ,",.' . ELêSH-fOlNI-iIESI_MEIHOD1_ 103 DEGREES F(39CI TAG.CLOSED CUP êUIO_IG~lIIO~_IEMEERaIUaE NOT APPLicABLE ELêltlaBLLUMlIS lEL 143 AT 140 DEGREES F(óOCI UEL 378 AT 199F(93C> , . EXIl~lSHl~_MEDlê WATER SPRAY, CARBON DIOXIDE, DRY CHEM¡C~L . S£EClêL.ElRE..ElGl::lnt:JG_~aOCEDUaES. , . . . WEAR SELF-CONTAINEtr BREATHING, APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH ~;KIN AND EYES.. UtlUSUêL-ElaE-QtlD_EXELOSlOt:J_~êlêaDS FIRE OR EXCE%IVE HEAT MAY CAU~;E PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. " . SECnotL\l.;.l::IEêLII:Ll::lêZäfiD_DêIê IëBESI::IOLD_LIMII_\lêLUE SEE .sECT! ON I I OSl::lê_II::IBESI::IOLD_LIMII_~aLUE_ SEE SEcn ON I I êCGII::I_II::IEESI::IÙLD_LIMII~~BLUE SEE ~;ECTION II I CBaClt:JúGEU_=-tlIE_~tiüGBaM_ NONE KNOWN UiEiClt:JüGEßL=_lfiBC_ŒüG5:db NONE KNOWN SiMEIDMS_OE_EXEOSÜBE COMFtAINTS OF BURNING OR IRRITATION OF THE EYES AND MUCOUS MEMBRANES AS WELL AS THE DEVELOPMENT OF SKIN IRRITATION. '~APOR IS iERITATING. MEDlCêl_COUDIIlOtlS_åGGBê\lêIED_BY_EXEOSUB£ NONE KNOWN. , tRlMêRY-&~UIEiSl_OE_EUIRY EVES. SKIN, INGESTION AND INHALATION FMFRGFNt.ï-EIRSI_GlD EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND GET'MEDICAL ATTENTION. SKIN: FLUSH SKIN WITH PLENTY (f WATER. IF SKIN IRRITATION OR ALLERGIC REACTION DEVELOPS, GET MEDICAL ATTENTION. INGESTION: ' SEEK IMMEDIATE MEDICAL ADVICE GIVING FULL DETAILS OF AMOL~T SWALLOWED AND TOXICITY. INHALATION: REMOVE TO FRESH AIR. SECIION_~IJaEêCIl~lIYJDêlê SIABILlIï_ STAIU COt:JDIIIONS_IO_ê~OID NONE KNOWN 1~QIIBILlIY_1MêIEalêLS_IO_Q~OlDl STRONG ALKALIES ~Z~9r~S-EOLYMERliêIlO~_ WILL NOT OCClIR Cú~DIIIO~S_IO_ê~OlD NONE KNOWN HäZaBDDUS_DECOM£DSIIID~_eRDDUCIS CARBON DIOXIDE AND-OR CARBON MONOXIDE -'>- ~ , .' - .~. -." . "~TERIA4:'SAFETY DATA SHEET t 11-06 . q..' . . . REVlS~D DAT.-2S-S6 SECIlONJlll..EblUlBBmIAl..ÆROIECIlON..eBOŒDUBES 5elLLBESeONSE WEAR PROTECTIVE CLOTHING AS SPECIFIED IN SECTION VIII. IF FEDERAL, STATE AND/OR LCCAL REGUlATIONS PERMIT, NEUTRAlIZE WITH SODIUM BICARBONATE· AND 'FLUSH TO SEWER WITH LARGE AMO~TS'OF WATER. OTHERWISE ADD DRY ABSORBENT; clEAN UP AND PlACE IN AN APPROVED D.O.T. CONTAINER, LABEl AND SEAL FOR DISPOSAL . , . . , WSS~DIS2üSAL-MEIHOD IF FEDERAL; STATE AND/OR LOCAL REGl~ATIONSPERMIT, FlUSH NEUTRALIZED MATERIAL TO SEWER WITH LARGEAI'1OUNTS.OF 'WATER. OTHERWISE DISPOSE, OF. CONTAMINATEDPRODlICT AND MATERIALS lISED IN CLEANING UP SPILLS IN A MANNER ,APPROVED FOR THIS MATERIAL. ,CONSULT PROPER FEDERAL, STATE'AND/OR LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. . ' SECIIO~_VIII_SeECIAL_eROIECIIOM_I~EORMSIIOM EïLeaOIEcnmL SAFETY GLASSES OR GOGGLES . SKIM_eROIECIIOM IMPERVIOUS GLOVES SHOULD BE WORN. aES~IRAIOaY_eBOIECIION_iSeECIEY_IYeEl_ APPROVED ·ORGANIC RESPIRATOR IN HIGH CONCENTRATIONS· VENIILAIION_RECOMMENDED GOOD VENTILATION·REQUIRED OIHER_eaOIECIIO~ AS NECESSARY TO PREVENT EYE AND SKIN CONTACT. SECIlOM_ILSeECIQLeBECQUIlOMS .. , i HYûI~lC_eaêCIICES_IM_~DLIMG_~D_SIORQûE KEEP TIGHTLY SEALED. [~ NOT STORE OR CONSUME FOOD. DRINK OR TOBACCO IN AREA WHERE THEY MAY BECOME CONTAMINATED.WITH THIS MATERIAL. STORE ABOVE 40 DEG. F (4C). AVOID UNNECESSARY PERSONAL CONTACT. AVOID INCOMPATIBLE '3IJBSTANCES. . WASH THOROUGHLY AFTER HANDLING. OIHEB-~CäUIIO~S MATERIAL IS CLASSIFIED AS A COMBUSTIBLE LIQUID. KEEP AWAY FROM HEAT AND FLAME. THE INFORMATION CONTAINED IN THIS MATERIAL SAFETY DATA SHEET IS FURNISHED WITHOUT WARRANTY OF ANY KIND. THE L~ER MUST· MAKE INDEPENDENT DETERMINATION OF SUITABILITY AND COMPLETENESS OF INFORMATION TO A~JRE PROPER USE AND DISPOSAL OF THIS MATERIAL AND SAFETY AND HEALTH OF EMPLOYEES AND CUSTOMERS. THIS STATEMENT IS INCORPORATED AS PART OF THIS MATERIAL SAFETY DATA SHEET. ø -3- -?~~ E'RODUCLNGME;' Al~EX ~JARDAPAK ~ BIPAK DEV PT C CHEMICêLJEêMILï_ PHOTOGRAPHIC'DEVELOPER E~2ER_D¿O¿I¿_SHIE~lUG_~êME_ ' CORROSIVE LI~JID N,O.S. t1âUUEêCltmEIL (-U I ED PHOTO PRO[rtJCTS CO, &410 Atlantic Blvd, ~:lJit<? 120 Norcross, Geor9ia 30071 E:8 UlC:lE:êLl:JêZêaDOU'3_C0t1E:O~Et:HS,_ GLUTARALDEHYDE. BülLHIG-EOlt~L GREATER THAN 212 DEG. F. (100C), ~êPOB-~BESSUBE_iMM_HG~l_· APPROX. 17 VäEOR-DENSIIY_iêIR_=_11_ APPROX. O.t, SOLUBlUILltLWêIEB_ COMPlETE . -/ MêIEBlêL_SêEEIY_Dêlê_SHEEI SECIIOY_l~GE~aêL_INEORMêIlOY SECIIO~_ll_lNGREDIENIS U~¿SLiL E:ERCENL . CAS# 111-30-8 30- 50 SECIIQN_Ill_EHïSICêLJDQIê ~CEjllirLODO[{ ClEAR ALMOST CClORLESS LIQUID WITH AN ALDEHYDE ODOR. ;'1- . ,.,' MSDtI M-OB REVISED DAT~04-86 '~'" . EOfiMULê AQUEOUS MIXTURE D40414_HQZQaD_CLêSSIEICêIIO~ CORROSIVE MATERIAL UN# 1760· MQNUEQCIUfiERS_E:HONE_NUMBER (404) 448-6120 CHEMIREC_E:HO~E_NUMBE8 !BOO) 424-9300 IHBESHOLD_Llt1II_VêLUE êCGIH OSHê_E:EL O.2PPM (C) seECIEIC_GRQ~IIY_iWêIES_=_11 APPROX. 1. 09 ' EEacENI_~oLaIILE_BY_~OLUME APPRO X . 75 E~åE:ORaIlON_RQILL___ ____,:11 NOT AVAILABLE Ei:I APPROX. 7.00 .... MATERIAl SAFETY DATA SHEET t M-Oa - REVISED DATE~17~a6 ~- ~ SECIION~IV_E~ND_EX~QSiQN_HaZQBD_Dêlê ", \ , - ElQSHJeQINI_1IESI_M~IHODl_ NON COI1BUSl1BLË QUIO~lûNIIION_IEM~EBQIUBE NOT APPLICABLE -' ".. ' E\J\MMêBlLlUurs NONE LEL NONE UEL - NOt. [ , EUI.Mú'UlS1:!ÌMGJÐlê \- l~E THE MEDIA SUGGESTED TO EXTINGUISH THE SOURCE OF THE FIRE. S~CIQL-ElRE_EIGHIltlG_£aQCEDU8ES NONE L~USUêL_ElRE-ê~D_EX~LOSlON_HêZêaDS NONE SECIION_V_HEêLIH_HêZARD_DêIã I~aESHOLD_LIMII~VÚLUE :=H :;:ECTI ON I I _OSHQ_IHRESHOlD_LIMII_~ALUE_, :;:EE SECTION I I êCGll: ...;II: ¡;;ESI: OLD_LlMII,_~èLUE ~:EE ~::ECTlÜN I I CARCIUDGEM_=_~Ie_e80GaAM_ NOt~E KNOWN CABCltlOGE~~=_IAaC_eaOG2d~ NONE KNOWN StM£IOMS_OEJEX£OSURE (~MPLAINTSOF ~JRNING OR IRRITATION OF THE EYES AND MUCOUS MEMBRANES AS WELL AS THE DEVELOPMENT OF S~IN IRRITATION OR DERMATITIS. VAPOR IS IRRITATING. MEDlCäL_CüNDIIIQUS_åGGRê~IED_BYJEX£OSURE' NONE KNOWN. eRlMêRï-BOUIEiSl_OE_E~IRŸ I EYES, SKIN, INGESTION AND INHALATION. : I - 'EMERGENCY_EIRSI_AID EYES:' FLUSH WITH WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION. SKIN: FLUSH SKIN WITH PLENTY OF WATER. IF SKIN IRRITATION OR ALLERGIC REACTION DEVELOPS, GET 'MEDICAL ATTENTION. INGESTION: SEEK IMMEDIATE MEDICAL ADVICE GIVING FULL DETAILS OF AMOUNT SWALLOWED AND TOXICITY. INHALATION: REMOVE TO FRESH AIR, TREAT SYMPTOMATICALLY AND GET MEDICAL ATTENTION. SECIl~_UlJBEACIlYllï_Dälä SIaBlLlIL ! - STABLE CONDIIIONS_IO~ä~OID NONE KNOWN ~QIlBILlIY_1MAIERIQLS_IO_A~OlDl "INERAl ACIDS AND STRONG OXIDIZERS- I I .... ~zaanoUS-eOLYMERIZAIIO~_ WILL NOT OCCUR CO~DIII~S_IO_ä~OID NONE KNOWN HQ1êBDOUS-DEC0M2DSIIID~_~RúDUCIS SULFUR DIOXIDE AND CARBON MONOXIDE -2- -;¿a~. . . SECIION_~llJEN~lRONMENIQL_eeoIECIIQ~-eRQCEDURES REVISED DAT9IIIIr17-86 MATERIA~~SAFETY DATA SHEET . M-OB 5eILLBEseooSE, WEAR PROTECTIVE CLOTHl~3 AS SPECIFIED IN S£CTION,VIJI. IF FEDERAL, STATE AND/OR LOCAL REGltATIONS PERMIT; ~ÆJJTRALIZEWITH SODIUM METABISULF1TE AND FLÙSH TO SEWER WITH·LARGE AMÒUNTS OF WATER. OTHERWISE ADD DRY ABSORBENT, CLEAN UP AND PLACE IN AN APPROVED D.O. r. CONTAINER, LABEL AND SEAL FOR DISPOSAL ,. WêSIE-Dl5eOSQL_MEI80D IF FEDERAL, STATE AND/OR LOCAL REGltATIC~S PERMIT, FLUSH NEUTRALIZED MATERIAL TO SEWER WITH LAFf,f AM~JNTS OF WATER. OTHERWISE DISPOSE OF CONTAMINATED PRODUCT AND MATËRIALS USED IN CLEANING UP ~;PILLSIN A MANNER AF'F'F:OVED FOR THIS MATERIAL. CONSULT PROPER FEDERAL, t;TATE AND/OR LOCAL REGULATORY AGENCIES TO ASCERTAIN PROPER DISPOSAL PROCEDURES. SECIIO~_~lll_SE{CIQL~eROIECIIO~_lNEoaMêIIO~ EYLeROIECIlotL SAFETY GLASSES OR GOGGLES SlŒLeROIECIlON IMF;ERVIOU~; GLOVE:3 SHOULD BE t~ORN. REselBêIOaï_e&DIECIIOtl_lS~EClEï_IYeEl_ APPROVED ORGANIC RESPIF:I\JOR IN HIüH CONCENTRATIONS ~ENIILQII0N_RECOM~ENüED GOOD VENTILATION REQUIRED OIHEa-eaOIECIIOtl ' AS NECESSARY TO PREVENT EYE AND SKIN CONTACT. SECIIO~_lx_SeECIQL~BECêUIIONS 8YGIENILeRêCIICES_Itl..l:JêtlDLltlGJlliD_SIORêGE KEEP TIGHTLV SEALED. ~j NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN AREA WHERE THEY MAY BEC{t[ CONTAMINATED WITH THIS MATERIAL. STORE ABOVE.40 DEG. F (4C). 'AVOID UNNECESSARY PERS~NAL CONTACT. AVOID INCOMPATIBLE SUBSTANC£S. WASH THOROl~HLY AFTER HANDLING. OIHER-eRECêUII~S THE ROUTINE l~ OF A NON-ALKALINE (ACID TYPE) HAND CLEANER WILL MINIMIZE THE POSSIBILITY OF ALLERGIC SKIN REACTION. THE INF~ATION CONTAINED IN THIS MATERIAL SAFETY ,DATA SHEET IS FURNISHED WITHOUT WARRANTY OF ANY . KIND. THE USER MUST MAKE INDEPENDENT DETERMINATION OF SUITABILITY AND COMPLETENESS OF INFORMATIm~ TO'ASSURE PROPER USf AND DISPOSAL OF THIS MATERIAL AND SAFETY AND HEALTH OF EMPLOYçES AND CUSTOMERS. THIS STATEMENT IS INCORPORATED AS PART OF THIS MATERIAL SAFETY DATA SHEET.· ¡ , .. f¡ ; ¡ t': !,,' ,¡ I , " ! -3- . . -~ ~~ . :..." ~ ilfjiøJK ~/ øèlI Þ yØØ~ /¡;;~!1J . ~J/¡'M .~....t.' ~~"ol",;Y""R:~~-t-'.or".~: . ...' ~.~ .... :tç" ".-;'~"';:. ~~ -- -----. . ~ ,~~-~~~.~...:-#.. ~ ..: Page ~"""-..''-' , ' CITY of BAKERSFIE '.,~ 'dHAZARDOUS MATERIALS. ?=.NV~~~OR.Y: R, NON-TRADE SECRETS'.. ::-' " - ',,' , :, ,,__','.. '. ..... - _. '., '., ;;1... . ,', ~AME OF THIS FACILITY· "f:: ST ANDARD IND~ CLASS CÖOE:". . , ' DUN AND BRADSTREET NUHBER:-:--~~' CODES --;...: :.. - - ;.:.' ~".::. ~' "''''?', ....,--~ ,.... ~ ,.,.. . '''!_~·'''''''',1·.~''':'''_"'' : "...:,~. 1~'~:~r. ", - ~.: ~ .';"",\ -:- ,.', . . ,,. ~', ...":,, LD OWNER NAME ADDRESS· CITY' Z,tp: PHON~ It· ' REFER to-r -~~..... Standard BusIness ,~....~~ '·.~.,t~~·~7:=- ~-'"t1f'.;}--~;......-~.... f~'':i.:-l.tN>· ",-t., I~', .------... '.... t;++'J:!'~~'"~ -:-"~ i;;:~i~~]l~'-!:~ ;~", hriïÌl{ÃgÚcu1ture' I] ~=l',..::-_ ~:~~.'~i4_,,:\J:,;.ö .-:;'1:>"';'-:-' ._ '..\'... .-:;.......,. . ,.: ~ ~ ~~~f!~~i:i*ít:"}" 1~~HbN~ ¡:~ ~~ ." ''; U ~i.ture{C~,~onents Instru: Icns Nar.eser See , .3 , by Wt 6 7 8 ·9 t2 Measure . ~ys Cont Cont on Vhe~e UnIts on I te Type Press n Fael Ity '32.0 ~ 8~ 110 T Ii. ¡JfL-. C.A.S. Number - Component' 1 Name & C.A.S. Number 11·g3-cg-Z o De lared o Suddf" Re I ease ~ Component.2 Name & C.A.S. Number lr.mediate 1151- 53-7 " Hea th o Pressure Health C~~o"Ent i3 N!me & C.A.S. Number -I· f1c..cJm IfJlJ/V1 SUI.., FAr£- ~. Number NUllber Component JI Name too,+3-Ð/-3 Component.2 Hame & C.A.S IIImediate Health Component.3 Name & C.A.S :. Ph~~ic~1 t~d ~ealth Ha¡ard ( ec a , t at apply o Fire Hazard ctivity ~ Suddfn He I ease o Pressure o De lared Hea th o Reactivity '( Hazard Fire o ;S IiJ C/), :3br-- c;J(L,..t DO Humber NUllber S A.S C,A Component. Name '{~-3/-q \¡{ , ,Collponent.2 Hau & C ?\lr.mHeedalNhe '11~Î-~3-1 Com~cnent ,. Hall' & C SUddfn Re I ease o Pressure NUrlber o De Jared Hu th C.A.S ô Physical tnd Health Halard (Check a I that apply) )(ReaCtiYity Hazard Fire o Nur.ber A.S ;; .'''~': ::rJ'" ".£S':·i~;~':' ~::~··:ij~~~t"r~"'~-!!~ t.·~ . COmp\lnènt . Nue C.A.S. NUllber Component'2 Haze & C.A.S. Humber o luediate Hea I th COllponent.3 Hall &"C.A.S. HUllber . .'......... ..,f ihis end 111 believe that , , ~ -- PhH ic~ I t~d ~ea tth ~IJard C.A.S. NUllber ( ec a t at app y .. 1]' f ire Huard I] React hitr o D~lared o Suddfn Re lease , ea th o Pressure - í'-~ NAM' OF T':' ,~~,~":~jì.~ OSUTAhDARO YNIoS FA'CIi.ITy:Y;'~;· :,:'.. : ~:':'i;:;:~>':"'.'·jlàge.<}.·Q.· '~~~..'.~..' .~..T.~.::..:~~.",.~4: N ANDBRAD~TfilASSCÕD '; . ";"';" :;-f?;:';"""~';:!}'!~ CODES> '. EET NUMBfn~ _. ,. ,,", ",v·",.,w"%-"" - - --"" - -- :C'~~;;~';':~_:~;~~~¡J.'~ "',~'''> ..... . -!~': --' ~f;šr~~l;,',: '?~~~~~.' ,':f:T"" ", ~::~~:W~~~:;~:"·~;-:~.Ai~ : ~;.,,'~:~"'/",::~:"~~:>\'>"<":: CITY of BAKERSFI ELD.,.. 1': ~.'.'y.~.~ "::..:.:é'Z\?'t"-.,,:;t-:I....4>: ::.'.. .-:-:: :" .,~; ,.>é·';-:';;" ,;::" HA Z A R 0'0 U S M AT E R I A L S I N V E N T 0 R V fIk.' ,f' -..~«.. -:-.... '.'. ~., " ... ;..... . - . , ¿.. hi. ~~,(~gticu1tu,. , [] r, .Sta~d.,d Business n·,::~' .. . . . ",.. "",-"",.",...-." '", -"~'. ...4...··,..;...', .. ".,., NON-TRADE SECRETS ,,:, ~..., ~.Æl~~:-=~ ~~;;;:7~~;;:~"1' .~~·::.:··:"~··_:~:~~:~~r.\r'0-~~~~"_'t~:-~ ,::":'r;\·~ . . . ~'œ' ~~.i~tf¡-~·~ ~w" '~''''70k'''''~'' " ;, -" ,C .. HI- '. .. ~. c ... ~~ " .. ~- " - : ....... '-. WNER NAME: ADDRESS· ' CITY~ zIp: PHON tt· - REFE to-r U ~i~ture{COtPor.ents Instr~: Icns 13 S by Vt N:i ~UH fJRUPER 12 . loc~tion Vhere Stored In FacIlIty s(6~lUlfIL 6 Measure UnIts 2 TYD' Code I Tr~ns Code Nar.es of See , on C,A.S.Number C.A.S. NUllber C.A.S. Number co"p~nt'l Nalle c~one~(q2 ~ue r.:.ediate Health Cor,p9nent ¥ 3~ Sudd¡n Re I ease o Pressure ~ C.A.S. NUMber o De Jayed Hea Ith o tJ Phl~icfl ,~d ~ealth Hajard t ec a t at apply . )( Fire Hazard )( Reactivity NUle s~7liJtII.- Nalle& e.A.S. 'Nu~ber ~~ Na~& C.A 13 Nur.ber S Cor,ponent . ·13ID~7. Cor.ponent 12 luediate . Health C )( Sudden Release of Pressure )(React ivi ty Number S o De I B-yed Hea Ith o Hazard re F o Co:.ponent'l Nalle & C.A.S :1~-q3-1 Co:.ponen .2 Na:.e C.A.S o Ir.mediate . Health Cc:.pcneDt'3 Nalla C.A.S NUMber C.A.S end Health Ha¡ard all that apply, Phnica (Check ; . '...:..~~.: :.;;'~~ Ihis end 'a11 be II eve tha ," " --- Sudden Re lease of Fressure o De Jayed Health o Reactivity Ph~~iC~I' ,~d ~ea}th ~alard ( ee a t atapp y .. , Hazard [] React hi ~: o Hazard re F o ~~~~,:::~Zci .. I· ~;, Faf;ind Ägticu1tur.' [] . ~'....... "--~:'.'... _I'''' ... ..: ¿,.ti.f~.....,.. ~ -.,!:..."...~-~,,,,~ '.. ",~.' '$'.'-. r. "~..! ~':.~ ~ y,it::,~-"\';":t':"'''''1 ',;:·.;r>~-,;"'-:'7.'J(,·t'.,".:t··- uñHf~r··;[·'~'· .~ ' ,~ r¡- Tr4ns Code ::~·:,;;:~~~~'~~~fS~vr~~~::.~~~: . . ". ~ . ;: '¡è:;:?$' ;1f}.:.;: ... .$: . . ',; ~a'g'~:>~3:~: or ~ ., .....;.. , ~.. ' . '1 -.ly. .' . "-, J: < CITY of BAKERSFI ELD ,:,':~:~'~;'~:;;;~::::""> . . . ., . . . .. '. ,.:,~ .- ~J;:'-', :""',' -. -.~.' " ,:'. . _..".. . .¡' HAZARDOUS MATERIALS INVENTORY,.:f,,>'·;"~·':\, .~~, nes~:;~,~:,:,:,.:" :;:,,:" N'ON-T,RA~Ê'" S EC~~T'~:':,;;;~:l?r~l~Vi{::;~~2.~,'~{f:j~:?;J¡:t' ~ OWNER NAME: " :,' NAME 00 TÄIB"FACllITYò·~'··:' - ADDRESS· , ST NDA 0' N .-' CAS C 0 - ..', , ~h~~~ 3!P: " . " . .' DU~ ~~<i~,~ "~i¡.~J~~E¥ NU~B!Ã:-:~-7tv/l REFER t01N5TRCJ~'1 J.uN~ J-Uff fJffOPER CODES,:k -~~':,' ,- ~,- -- '~'7'"'< ;;~:¡'~:~::~~::~1j:~~~J~.- .' " ,~ .,..- . ....~ .' . ~ . --,:-,-.~~-,.-..~.~ i:::~t;:~I,~~~,~~ Standard Bus u , Nar.es of ~ixture{c:~por.ents See Instru: Icns ,13 , by lit ... C.A.S. Number C.A.S. NUllber C,A.S. Number 5 6 7 Annua Measure . ~ys Est UnIts on I te ~O m8~ C,A.S. Number (] De Jared (] Sudd¡n Release X Hea th o Pressure 2 Type Code PhtSicfl tnd ~ealth Hàjerd (nec a I taat apply , (] Fire Hazard ~eactiVity =r=1 [ Phl~ iCf I Hd ~ea Ith ~ajard I ec a· t at app y . Average ht 3 Mu Allt Co~ponent Nalle & t.A.S. Number ø. . (] Cor.ponent.2 Nalle & C.A.S. Number luediate Health Component.3 Halle & C.A.S. Humber '. Nuriber C.A.S React Sudd¡n Release o Pressure (] De Jared Hea th (] vity (] Hazard re F (] £iL, NUllber A.S. NUllber .A.S. Number COllpone~}.1 Halle C.A.S rOo Lf-3 -Of-3 Component'2 Halle & C 1 bf4 -1.3 -q COllpcne~t.3 Har.e t C Phlsical ·,nd ~ealth ,ajard C.A.S. NUllber I heck a I t at app y (] Fire Hazard )(ReactÍYity (] De Jared (] SUdd¡n Re I ease ~lImediate Hea th o Pressure Health NUllber ~{'i~~~~r~1~: :. ~!;~~~;ii!~;:g~'"':t .. -. S C.A.S. NUllber I C. ..,-.-.-.... >:.. > C.A Nue Nue , CO:lpilnènt IIIClediah COllponent 12 Health ,~;-- Component ~4-~ (] , Suddfn Re lease o Pressure NUllber o De Jared Hea th C.A.S o Physic,l '~d Health Halard tCheck a I that apply, Reactivity o e Hazard ~r "'t·'Il"_,*~~"I"--~~5· ~'Jk:'::,'i ;6:;; ,.' . ~' . " - - .-.- :.-..-:........ ....t..;,; .~...,. .:.j-...-if".; ').':_-:J;,;:Z:~!!.:::. . ,. .' . <' . . ~... .. " :-:~..;.:. ,,' ~ ~ ,I :.. ~-_- I '.. '._ . -,.J~. -.., ~-:-. ~~ ,- . '. '..,- ;: :,' ,:~- /:2i':i' ~g e;: :..->..~ . ..2.';..... :::..; ...;, :.:'. .')~~ NAME OF THIS FACILITY· ST ANOARDINO. CLASS CODE: ___'-:..~,__._ DUN AND BRADSTR~ET NUHB~R : ?,.: .-">-.-Ò .f'-'-. - -' - - - - - 12 on Vhere n FacIlity ~ &¡t{!J)MffL. NUllber : '-"'-..-r:-~ .. '.. -" 3 , by Vt ~2:f::T~1·:~:P7~;':':-~J~~:j?~"; " .' ..,_.,,-y.,'.:,.:......,',",~.$.'~~:,i!.,,"'..:. '.'t :'·'à.li<".'"":¡''''c,: """~, .... . CITY Of BAKERSF r~;;;:r:-'.::.b~';~~:~~~~"')':'~7:'::'-'~ .~'i;~>'~·:">?c'~;:;"-:::.;,<~':;' ~:?,(':-'~:.. ..,:, . , . . r~~l~tL~I~~}gtJEult~!i~it_~:.Stä~ðl~·~-~'u~i~e~~::ot!~~;:~~_~~,US MAT E ~I A LS !- NV E NT ORY _\r,7_~~-~:i'~i'i'~)o"#'·f¡:;Z~Øk~~r""''''';'~~?':è·:·'''-' .,./;,~,·.~""",,·.c ·:;t'-";·-'1·~-·',··,,·-· NON-TRADE S ECR ET ~~a~~~~-."Ì.NÍ·~ŠI.·:~~î\1i:'af~~~:r:¡j[Ãbf6;;{}A7:~~~~6~~~~v1AM.E: .;. ': .:" . S :,. Y 91 N~ . .f}, . ..... ADDRESS· . ~' .~~~. ~ .-.~ . ~ ~l~~~ ~!P:_ ,:;:' p. _ - . : R~FER 7'0-r !:' r; 1r4 Cod IELD CODES . IN::; rUff fJROPER locH Stored ~. NUllber COIIPo~nt'l Na~e 1t.f-tQ-1 , Cor.ponent.2 ~alle I C.A.S r.r.HeedNtthe {)()Ooq~ - 43 --3 Cor.ponent.3 Nalle I C,A.S S A C J( Humber C.A.S ood Health Halard a II that applJl )(Reaetivit, Physica ( Check ~ Number Sudd;n Re lease o Pressure [] De Jared Hea th [] ire Hazard F COllponent .1 It/-&;)- C.A.S. NUllber D Fife Hazard )( React1Y1t,. o De tared [] Suddfn Release ~ Cor.ponent '2 IlllIIediate Hea th o Pressure . Health .' Component 13 NUle C.A.S. NUllber . IJll []qo LJo~{) ~3~. UQJ l [¿S.te,. CfJR;. Ph!sical fnd ~ealth ~ajard C.A.S. Number r.e C.A.S. Number ( heck a I t a~ app y , o Fire Hazard )(:eactiYitJ [] De Jared [] SUdd¡n Re 1 ease X Ir.mediate C.A.S, Nur.ber Hea th o Pressure Health C.A.S. Nur.ber Cor.p~nènt.1 Nalle ¡ C.A.S. Number [] COlllponent.2 Name & C.A.S. NUllber IlImediate Health COllponent.3 Nalle & C.A.S. Number . Phlsiefl f~d ~ealth·,ajard C.A.S. NUllber ( hee a t at app ,. ' re Hlurd uethit, o D31ared . [] Suddfrl Re lease . ea th o Pressure ~~~ 'I,: - :<..> s /~ " end 111 leve that '.- S1Jñ: '" ~'. , this I be 5 6 t2 Annua1 Measure on Vhe~e Est Units n FacI Ity CŒ ] GALt ;o~Nfß- Phï~icfl f~d ~eaJth H!jard C.A.S. Number compo+t It NUle I C.A.S. NUllber (thee a t at applr ' , 1-(q-7 )( Fire Hazard )(ReactivitJ ' 0 oeJared 0 Suddf" Re1ease ~ . Cor.ponent.2 Na~& C.A.S. Number 1r.~eedaIJatthe 00007 d- - 8-3 , . Hea th 0 Pressure Component 3 Nalle & C.A.S. Number 1LIEJ'j. I~ I j0 00 ~~S-. I (0 I {~R1JeL. Phl~iefl fld ~ealth ,ajard ,C.A.S. Number . COllponent It Nllle I e.A.5. NUllber . .( ee a t at app r · II( - 30-~, o Fire Hazard )(Reaeti~itY, o De Jared o Suddf" Re 1 ease '" . Cor.ponent.2 ame & C.A.S. Number I lied late . . Hea th o Pressure . Health' . . ~ COllponent 13 Name & C.A.S. NUllber ' ,., ~j1.~ Qk"o 1~3b¡- I 10 L.LJ 1] ~]Sø..Cc~ 'Pht~ical fnd ~ealth ,ajard C.A.S. HUllber nt 1 Nalle & C.A.S. Number ( neck a I t at app' y )( ReactivitJ OSiJddf" Re lease )t1r.l\ediate I C.A.S. Number 0 re Hazard o De Jared Hea th o Pressure Health I C.A.S. Nur.ber " ~. ---_.. I' ~itt~re{ç:rpor.ents Ir.s~r~: Ions ' of .~...' -15._ .', i'aqe ~....__. '. - , . NAME OF THIS FACIlITYÒ· STANDARD IND'. CLASS C 08 DUN AND BRADSTREET NUHBER-- . - :- - - - - - -" - Nar.es cf See --, .,' 0_ ~~;rèl~~ BAKERSFI ELD '\IH. ~"Z' ~R,~., O,'~~, MATER:I,A,LS ~NVENTORY !j.'::::':'?'-'>:'<'·;"iNON~TRADE, SECRETS .. It'_ ''''.' _. t- ...."" ... _ ,6' _ ~ .' " _ ' . -. - , _ - . r, -. " ,~ . . . . ts ~~~~~'~~~HE-: : ,'.: - " :-<^'(,~ ;i.; ~": CITY zlp:- PHON~ It· - REFER to-r, .- "'-i;;, -, CODES '. £R " " ;:;~;:~~::¡;~~~;~~~: . . Standard Business .. r. ..,...... ~. '/ !:~'~:,';<' --"~:;/~~~:~:'. '.' ~'.'~.,:~~,."~...:.: ',' ,-' -~. :'':'¿'' ~~';/:':...~;~';<~:~.~'-, .:.. ,~ . . ~'\: Far. iì;dAgticulture D ~t~~~N~?~E~1/Þ::;'''~:~;~:,~.à:.~;~~~i:~ :.' r~~¢YÍð~~~ : "v'!m '~HbN~ ¡ Cozp~nènt.t Hane C.A.S. Number .' .' o ,Component 12 Nue I C.A.S. HUllber ImmedIate' . ': .' Health . ..,,' . ".. COlponent 13 Hale & C.A.S. HUllber . t. P+loro6W>*i<:., ÐI Ac£íÌc.. kìù NUlber Sudd;n Re hase o Pressure o C.A.S o De Jared . Hea th - '~., "..,,:.:;;-:" : ':::',. . PhIsical ond Health Halard (theek all that app1YI Reactivity o reHllud .. '. ,.,,, :P9·.,~ :";'I:'i:.~.oi:! "/~'I""'; ~.;,,;.---~.¡..¡;,¡."..~? - . ··\~~·-"I\~.>~:::l '",....¡: .. C'::' '·~:ff~~.~~~'~' ~ (lUf,)rqr.u " ';";, ~~":';:r ,,',. ..~,:::._~~:: }:¿~~~fi;z;:~ :~ ., .,.. t·f ,- ,. .' -. , , . . ..., .JL this end a11 .~ I believe that the " '. , :.. :-.~.~ ~ >. " .~..~:;t~ ,,-~--- -:. j. ~. : ~ ,j . . ~. '" -';¡ '0,' r .~ : .' ',':: 'l ;~MATÊRiA~SAFETY DATA SHEET EASTMAN KODAK COMPANY . '. ~> , , c· .- t' ~ ' . "::5é" . ¡... , . ~ . . .' '. '.' ..,. .. I: ' ,. Date' of Revision. Kodak'Accession Number. 454790 09/11/85 ........a.....D..................~~....a......aa..=a.a.........aa.........==as PRODUCT INFORMATION . . ================================================0============================= Product Namel KODAK CINEFLURE'DevelOper and Replenisher; Part A Formula. Aqueous Mixture Kodak Catalog Number(s)I CAT 157 5224 - To Make 10 Gallons Solution Number 5189 Kodak Hazard Rating Codes:.' R. 1 S I 3 F: 0 C I 0 Manufacturer/Supplier. Eastman Kodak Company 343 State Street Rochester, New York 14650 USA ',' For Emergency Information 1',(716) .722-5151 .For other purposes, call the Marketing and Distribution Center in your area. ============================================================================== COMPONENT INFORMATION .. =========================,==~=================================='========:======= Weight· Percent CAS Number Accession Number Water ' .. Sodium/Potassium sulfite mixture': .Potasium hydroxide .Hydroquinone.. .p-Methy1aminophenol sulfate Sodium tetraborate ,i ,65-70 20-25 5-10 " 1-5 1-5 I. 7732-18-5 035290 1310-58-3 123-31-9 55-55-0 1303-96-4 901383 900356 900615 901365 .PrincipleHazardous Component(s) ..Chemical subject to the reporting requir~~entsof Section ,313 of Title III of the Superfund Amendments and. Reauthorization Act of 1986 and 40 CFR Part 372., ',' ==·====~==============a~===================================~=================== PHYSICAL' DATA ==~==.=========================aa============================================= I Appearance and Odor. Pale straw-colored sol~tionJ faint odor Boiling Poin" ·GT 100 C (GT 21Z:F) a 760 mmHg Vapor Pressure, ca. 18 mmHg a:20 C' Evaporation Rate (n-butyl acetate III 1) I Not Available Vapor':Density (Air = 1). ca. 0.6' vol'ad.leFraction by Weight: ca~ ,65 ): Specific Gravity (H20 = 1). 1'..289; pH I C8.. ,12.10 ' . ", ' i SolùbiUty in Water (by Weight> I:/';Complete , ; / .f· ~, , ...aDa.e.==a:a===caD...==...a..........:=====:==:=:=:========================= GT · Greater thanJ LT,= Les8then ......111..111...=.==111..=...=................111=.........=...=............=....===a " C-0016.900E $5-0050 I. ¡ '\ , I ~ ·~·r-,. " : .\: ""-'f .. , ; ) , ".., ... ·"1 . t'· , " f' ... ,;>-- . ::;/ . ; ~ - 2 c.=~.==~==e=~~=~~=============a====~=a===================:=========::========= FIRE AND'EXPLOSI,ON HAZARD =========================~========================================:=========== FLASH POINT: None, noncombustible EXTINGUISHING MEDIAl Use ag~nt appropriate for surrounding fire. SPECIAL FIRE FIGHTING PROCEDURES. Wear self-contained breathing apparatus and protective clothing. UNUSUAL ~IRE AND EXPLOSION HAZARDS, Fire or'excessive hea~ may cause, production of ha~ardou~ decomposition ~roducts. =ec=:c=====e======::===:==_=::_:=:==::===:================================'==== REACTIVITY DATA .D==Da=======================....====D======~=======~================:=:====== STABILITY: Stable INCOMPATIBILITY: Strong acids 'HAZARDOUS DECOMPOSITION PRODUCTS, ,Thermal decomposition may produce oxides 'of sulfur. ~ :CONDITIONS CONTRIBUTING,TO HAZARDOUS POLYMERIZATION: W~¡l not occu~;, . , . . . ===========================c==..===============~==================~=========== TOXICOLOGICAL PROPERTIES .==================a==============~=·=========~================================ EXPOSURE LIMITS:~' Component: Hydroquinone . ' , ' ACGIH TLVs 2 mg/m3~TWA (ACGIH:1988-89) OSHA PEL, 2 mg/m3-TWA ,- " Compone"tl 'ACGIH TLV, .. OSHA,PEL, Potassium hYdro~ide', ' , 2 mg/m3-ceiling (ACGIH1988-89) 2 mg/m3-ceiling ^ . " ~. " . . -:... '." . ',>: > Component I '" ACGIH, TLV, OSHA PEL. . ' ,,' Sodium .tetrab,orete . ' , 1 mg/m3-TWA(ACGIH,1988-89) . -.' >:;..~~. :". ',: ' 10 mg/m3-TWA, "elL':;,:'" > ,~:~t~i)~"; " EXPOSURE EFFECTS: c ~; Inhalation: Low ha~ard for 'recommended hèndling. ..'" Eyes, Causes burns. , . " ·'.",i, Skin. Causes burns..: May cause aUergic'skin rea~tion. " ...:=aa======================..a======================a=aa========_.o._=:====: .. ' /PROTECTION AND PREVENTIV~ MEASURES ~... ,~.' .! . . ~ ...=..a===========================================================....=..===== VENTILATIONs 'Goo~ general ventilation should be sufficient. . ~ " SKIN'AND EVE PRO.TECTlON, Safety gbsses with sidè shièlds. or goggles are recommended. Impervious gloves should be worn~ The routine use of,a non-alkaline (acid) type of skin cleaner and regular cleaning of working surfaces, gloves, etc,will help minimi~e tha possibility of allergic skin reaction. ,! , .==========.=c~==~e==~=========~============~==========~=========,=~=========== C-0016.900E 85-0050 r. I r. .1 ~ ,. , " ·'"ì,:. " '>:i , t. .... I:. . . t· ~. :: .. ~, ¡ '" ,,:,,\,' ,. >' : -. ~ . .,'~ ~ ....!~ ..:.:-- ~ ~.._~" ~~:' 3 ' . < ~:. ~, . C/ " - ;e===.===============.=.~====.======a====================a=========~===~==~===.= STORAGE AND DISPOSAL =======a==~==========a======.==a============~===============================F=· Keep container, tightly closed and, 'SPECIAL: STORAGE AND HANDLING"PRECAUTIONSs away from acids. . ( .",' ·r". : '" ';;" ,I ',,"', " SPILL'-: LEAK, AND DISPOSAL PROCEDURES i ' ,Neùtrslize with sodium bisulfate. ',Flush',material to an acid-free:-~.wer' wi th 'large amounts of. water. ischarge, 'treatment, or disposal may bes~bjecttó federal, state, or local laws. .==.==========================~..==.=====================a=======:===:======== ,', 'FIRST,,'AID , ,1" ~ ¡, . -~ .j.. ' ::~a..~..~===~================a...*~..D=========================================~ Eyess :- Immediately flush eyes .~~thplenty of water for at least 15 minutes 'and Get medical attention. ',,;,>':> ',: . . "),:~.~".1">~'>i" "-~.. , t' .... ,: r";: .. . .·r_....· , Skins' Immediately flush with plenty"of water for' at least 15 minutes while removing contaminated ,e,1ðthing.'andshoes. Get medical attention; Wash contaminated clothing before reuse. 'if an allergic skin reaction develops, get medical attention. ' : I \ .h , , ================================.====================~===========:=:========== , ' ~ENVIRONMENTAL EFFECTS DATA , ' ., ; ==D~======~===============~===.===~=================~=============~==.==~===== " :: Some ,lsboratory test data and published datÐ are available for theínâj~r:-: : 'components of this chemical formulatio'n and these ,data have been !Jsedto;" provide. the following estimate of environ mente 1 impacts 1-12' ~ . This chemical formulation is a strongly alkaline aqueous solution, and this prQperty ·may cause adverse environment effects. It is expected to have a modera~e biological oxygen demand, and it may cause oxygen depletion in aquatic systems. It is expected to have a high 'potential to affect aquatic organisms, and secondary waste treatment microorganisms and a moderate potential to affect the germination and growth of some plants. The direct instantaneous discharge to a receiving body of water of ~n amount of this chemical formulation which will rapidly produce, by dilution, afin81 concentration of 0.036 mg/L or less is no~ expected to cause an adverse environmental effect. After dilution with a large amount of water, followed by secondary waste treatment, the chemicals in this formulation are not expected to have any adverse environmental impact. ============================================================================== TRANSPORTATION ===========================================================~================== For Transporation information regarding this product, please phone the Eastman Kodak Distribution Center nearest you: Rochester, NY (716) 588-9293; Oak Brook, IL (312) 954-6000; Chamblee, GA (404) 455-0123; Dallas, TX (214) 241-1611; Whittier, CA' (213) 693-5222; Honolulu, HI (808) 833-1661. ============================================================================== REFERENCES ~=e=~eem~=eeeœ=e~e~e~.ee~=eem.e..ae...=B.ms.eee~me~~=~=~~~~~==~=e=~=~eae==:=~= " 1. Unpublished data, Health and Environment Laboratories, Eastman Kodak Company, Rochester, NV. 2. Verschueren, K., Handbook of Environmental Data on Organic Chemicals, Second Edition, Van. Nostrand Reinhold Company, New Vork, N.V., 1983. ': C-0016.900E 85-0050 ... -<. '.. ~I e' .' " . -'; ..,. ..'1; ::f i. , ' :1. ». · .--.--...--- . C I TV, ZIP: CITY,ZIP: PHONE #: PHONE #: 10FFICIAL USE CFIRS CODE ONLY 1 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUATJ CONi USE LOCATION IN THIS % BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE ~H J(C¡~ I :rc£2 % I:~ 7 ,C;. 0. r'~ Vi)(eR CCJYlIð. Pcw:J- 11 , ./ IV 16ô~ IJ H 1-1. 0 N , I.J. f<!h)O $ú 1 ~. t'6 -j-..ç;/9ð 41 r%. --,- 3D J / UK SU [ t 1+..0 Qc5 ;;t;2- GZ ac.e-bc a c, J ' - l /().0(, [) ''L..- I I I )/'1 L 1"'? qcJ2 'g 37 s¿u.~ 'T, ~-elè P~6 ~ I I IV (~o~ /ì/uu INI1H St.( J f.Q,t4.\1'þ~ ) .~ I "'--- Page 2..dOt\?- FACILITY UNIT # UNIT NAME B ^ K E R S FIE I. U C I T Y F J R E U E I' ART MEN T FORM 4A-l NON-TRADE SECRETS HAZARDOUS MATERIALS INVENTORY ß FACILITY I D # BUSINEgS NAME ADDRESS: ~ ~ .' DATE PHONE # BUS HOURS AFTER BUS HRS: PHONE # BUS HOURS AFTER BUS HRS: SIGNATURE 41\-1 TITLE TITLE TITLE NAME: EMERGENCY CONTACT EMERGENCY CONTACT: PRINCIPAL BUSINESS ACTIVITY