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Home My WebLink AboutHAZ-BUSINESS PLAN 2/13/2007~, - ~ M K ~~ ~~ 4800 i_ MEDIAL WHITE LN #L S~P,~~ ~ S~~ { ,.A I ~ ~~ \~~r. Per :..{' ,: . ..t·, .....:. ..... .. ···.··.·,..0 P, ,~ ···.upe~ât'e .,,,,, .-, r· ~ Hazardous MaterialsllÍ~z~rdous' W:åste . Unified· Permit, ~- , , . r:', , . CONDITIONS OF ,PERM'IT ON 'R'EVERSE SIDE Permit ID #:: 015-000-001859 M K MEDICAL LOCATION: 4800 WHITE LN L Issued by: Bakersfield Fire Department OFFICE OF ENVIRONMENTAL SERVICES' 1715 Chester Ave., 3rd Floor Approved by: Bakersfield, CA 93301 Voice (661) 326-3979 FAX (661) 326-0576 Expiration Date: This pennlt Is Issued for the following: ItI Hazardous Materials Plan o Underground Storage of Hazardous Materials o Risk Management Program o Hazardous Waste On-Site Treatment 4 Issue Date . June 30, 2003 PerDl.Ït to Operil.te Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE This permit is issued for the following: ¡¡Hazardous Materials Plan .." ~tp'round Storage of Hazardous Materials " gagement Program Waste 4800 WHITE PERMIT ID# 015-021.Q01859 M K MEDICAL LOCATION Issued by: Bakersfield Fire Department OFFICE OF ENVIRONMENTAL SER VICES 1715 Chester Ave., 3rd Floor Bakersfield, CA 93301 Voice (805) 326-3979 FAX (805) 326-0576 *~ ph Huey, ffiee of ental Servi es Approved by: Expiration Date: J--'lne 30, 2000 .n lV.11Y.l r e sITe DIAGRA"M I Business Name: "" "- r~·' ..L. ,...u: .LJ... e FACILITY DIAGRAM ~ M~~\~L ~ Business Address: L\ ~OO WI-\ r7E:.. L~C. ~ c€... L ~ sf~ , For OHice Use Only FirST in Stetion: Area Meo # of Insoec~ion Station: NORTH 0 -sov\-r(.\ ,.. w/lJ!£.t\o,^ ~"- \e~~-:;-~ 1 "';;70(lJt;.&L. '$,'/ - .~ I L11V.11'.l r '_ SITE DIAGRAM ¢ 8usiness Name: VV\ ~ M~\CAL r ..LJ.t-u ,~- J.. , .u;.'.L.L e FACILITY DIAGRAM Business Address: '-\ ßOO wK..\'l£. ~E.. ~ëc. L ~'¿C;fL~ For Office Use Only FirST !n Stetion: Area Meo ;; Insoec~ion Station: ot NORTH {( ~ ?l ~ <' f- 0 cJ.. C1'l.1 ~~ c;.7~ l..J ~d.~ 1. - ~ V~ï '" CAIlLS C()~\J . So -r o/Lf... :::L. ~ ~ . . w ~ rT(.. ~N--\ £.. r - ..~ Ie ~</ E...Vf\lUt\\\ON ~L~N IJ& \ ~)l ;r-- D r~ . D - g D .0 c. I t . ~" . , f'K .::£~"U~C4\")t\£Il M ~ I"'\t:~, CA..L.. '-\000 WHIîi::. LAÑ£" ~ït:.. L &A.Iú2I2..~PI t::L~ I CA. ~"'.>"'.>o., (f>o'S) :'" -2..(.., I ,./ ~. ~; M K MEDICAL ~S ~,~,~~ SiteID: 015-021-001859 Manager U' ~~' `~" ~~ ~ `` ~r~~Bus Phone : ( 6 61) 3 9 7 - 2 6 91 Location: 4800 WHITE LN L Map 123 CommHaz Low City BAKERSFIELD Grid: 14C FacUnits: 1 AOV: CommCode: BFD STA 07 EPA Numb: SIC Code:4925 DunnBrad:94-256-0044 Emergency Contact / Title Emergency Contact / Title / MANAGER MARIA RUIZ / CSR SUPR ~~u in ssL''~o'ii~: (661) 397-2691x Business Phone: (661) 397-2691x 24-Hour Phone (661) 300-1541x 24-Hour Phone (661) 833-9006x Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: Fire ImmHlth DelHlth Contact tl; cfi~~'-~- ~'-~~k r`~cp f, Phone: (661) 397-2691x MailAddr: 4800 WHITE LN L State: CA City BAKERSFIELD Zip 93309 rrn ~rv~i i~r~~ D G Owner ~9~„ ~ -~~ ~~~D CHOIC rrT r Phone : (~!~) ~-y2 -Y17 ~ x Address 3~~~ 1' CuTFT.TIC Avg 3 Za w G~ ~'~'%~d~ ~""~ State • CA City F~FrSNe ~ /~ v,. dl~ l-e C ~ Zip °~- ~ ,~ Q Y- Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: No ParcelNo: Emergency Directives: PROG A - HAZMAT t3ased on my inquiry of those individuals responsible for obtaining the information, I certify under penalty of law that I have personally examined and am familiar with the information submitted and believe the information is true, accurate, and complete. E~~ 2 / ~ ° ~ F~~ 2 3 ~0 Date ~7 Sig tur . ~Q~P1:~~~..~ o~iGev -1- 02/02/2007 ;. ; F M K MEDICAL SiteID: 015-021-001859 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order Fixed Containers at Site ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP OXYGEN OXYGEN F F IH DH IH DH L G 5450.00 249.00 FT3 FT3 Low Low -2- 02/02/2007 -3- 02/02/2007 F M K MEDICAL SiteID: 015-021-001859 ~ F= Inventory Item 0004 Facility Unit: Fixed Containers at Site ~ COMMON NAME / CHEMICAL NAME OXYGEN Days On Site CRYOGENIC LIQUID 365 Location within this Facility Unit Map: Grid: S WALL WHSE CAS# 7782-44-7 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TPureAbove Ambient Cryogenic INSUL.TANK / CRYOGENIC AMOUNTS AT THIS LOCATION .Largest Container Daily Maximum Daily Average 5450.00 FT3 5450.00 FT3 5450.00 FT3 HAZARDOUS COMPONENTS %Wt. RS CAS# 100.00 Oxygen, Compressed No 7782447 ru~~HtcL s~5 ~ C.a~ri~ly l TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F IH DH / / / Low F= Inventory Item 0003 COMMON NAME / CHEMICAL NAME OXYGEN Location within this Facility Unit S WALL WHSE STATE TYPE PRESSURE _ Gas TPure ~-Above Ambient Facility Unit: Fixed Containers at-Site ~ Days On Site 365 Map: Grid: CAS# 7782-44-7 TEMPERATURE CONTAINER TYPE Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 249.00 FT3 249.00 FT3. 100.00 FT3 rujc~r~cLVUa ~.vi~irvtvnivta °sWt. RS CAS# 100.00 Oxygen, Compressed No 7782447 nt-~~tuu~ r~~ ~~JJi~l~lyla TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F IH DH / / / Low -4- 02/02/2007 F M K MEDICAL SitelD: 015-021-001859 ~ Fast Format ~ ~ Notif./Evacuation/Medical Overall Site ~ ~ Agency Notification 02/23/1998 ~ APPOINTED EMPLOYEE RESPONSIBILITY TO CALL 911 FIRE/POLICE IN CASE OF EMERGENCY. Employee Notif./Evacuation 11/02/2006 INTERNAL ANNOUNCEMENT CODE RED FOR BLDG EVACUATION, MEETING PLACE SET WITH EMPLOYEE ROLL CALL. Public Notif./Evacuation 02/23/1998 CALL 911. Emergency Medical Plan 02/23/1998 911 -5- 02/02/2007 FMK MEDICAL SiteID: 015-021-001859 ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall Site ~ ~ Release Prevention 11/02/2006 ~ ALL CYLINDERS ARE SECURED AGAINST THE SOUTH WALL WITH CHAIN AND IN FLOOR RACKS. Release Containment 11/02/2006 ALL GASES STORED IN SOUTH WAREHOUSE, SOUTH WALL. V1Call VtJ ~,_ v 1~11G1 itG w'7V Ut VG 1'11. 1~1V0.1~.L Vll -6- 02/02/2007 e F M K MEDICAL SiteID: 015-021-001859 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ aNc~..lai nac.ai~.a~ Utility Shut-Offs 12/14/2006 A) GAS - S & W END OF COMPLEX B) ELECTRICAL - NE CRNR REAR OF COMPLEX C) WATER - UNKNOWN D) SPECIAL - NONE E) LOCK BOX - YES ELECT CLOSET LOCKED Fire _Protec . /Avail . Wat. rer , C2l tl c~ ~ ~, ~ ~ ~ -2 Building Occupancy Level 03/09/2006 13 EMPLOYEES -7- 02/02/2007 i ~ ~~ F M K MEDICAL SitelD: 015-021-OQ1859 ~ Fast Format ~ ~~=Training Overall Site ~ Employee Training 11/02/2006 ~` j MSDS SHEETS DISPLAYED AND AVAILABLE FOR EMPLOYEE USE. BRIEF SUMMARY OF TRAINING PROGRAM: CONTINUED TRAINING FOR STAFF COVERING ALL ASPECTS OF MEDICAL SUPPLIES, EQUIPMENT, ETC. rayc c. nc.LU Lvi ru~.ui.c u~c Rc1u 1V1 r u1,..ulC V.7c -8- 02/02/2007 F ,;~_- n Prevention Services UNIFIE~~7PQZt~GRAM INSPECTION CHECKLIST j B_ e_R S F , _D 900'IYuxtun Ave., Suite 210 . .--_-- _----- ---__-- . _,_--__~_ _ __n_~~_~-~___.~~ FARE ~ Bakersfield, CA 93301 SECTION 1: Business Plan and Inventory Program ~; ARTM r ~ Tel.: (661) 326-3979 ~? ~ Fax: (661) 872-2171 • FACILITY NAME !~e ~r INSPECTION DATE lo- 3l -oC INSPECTION TIME o o Z c~ ADDRESS [ ~D~ ~/ /r h h„l ,C ~ ~ PHOr~ NO. 2~ ~ ~- r~ NO OF EMPLOYEES FACILITY CONTACT ~~„ ~ USINESS ID NUMBER 15-021- ~ `~s~ v- Se~tio~ 1. Business Ptah aid inventory t~ro.~ra~ ~ ~ '~l' ROUTINE ^ COMBINED ^ JOINT AGENCY ^ MULTI-AGENCY ^ COMPLAINT ^ RE-INSPECTION C V ( C=Compliance OPERATION V=Violation COMMENTS ^ APPROPRIATE PERMIT ON HAND ^ BUSIIIeSS PLAN CONTACT INFORMATION ACCURATE ^ VISIBLE ADDRESS ^ CORRECT OCCUPANCY ^ VERIFICATION OF INVENTORY MATERIALS ~~ Ltrll>iKq p C~ 0 ~~ ~r{OU ~ 00 O (VrlrO eV~. ~" ^ VERIFICATION OF QUANTITIES I (~ ^ VERIFICATION OF LOCATION L~ ^ PROPER SEGREGATION OF MATERIAL I~ ^ / VERIFICATION OF MSDS AVAILABILITY C~J ^ VERIFICATION OF HAZ MAT TRAINING ^ VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES D ^ / EMERGENCY PROCEDURES ADEQUATE ^ CONTAINERS PROPERLY LABELED ^ HOUSEKEEPING L'~ ^ FIRE PROTECTION ^ SITE DIAGRAM ADEQUATE & ON HAND ANY HAZARDOUS WASTE ON SITE? EXPLAIN: QUESTIONS REGARDING THIS INSPECTION? PLEASE CALL US AT (661) 326.3979 Inspect r (Please Print) Fire Prevention / 1S1 In /Shift of Site/Station # E ^ YES ~NO rcnr-nu» ease Pri White -Prevention Services Yellow -Station Copy Pink -Business Copy FD 2155 (Rev. 09/05 4. <~ ~ ___ dJNIFIED PROGRAM INSPECTION CHECKLIST~r F.~12" vK~"aans"..7.kc";J w.>,euo,,.a.5•.:.k:A;` ~... f ., ., : _,.. s. - ~n .~ ~ .. . 3. x , ...~ ~. ........ . ... . s,.. ., ..,,..: f +. ,.., n SECTION 1: Business Plan and Inventory Program ~' Tel.: (661) 326-3979 • Fax: (661) 872-2171 FACILITY NAME NSPECTION DATE INSPECTION TIME ADDRESS HONE NO. O OF EMPLOYEES IT ~ 39 -Z69 / ~ ~ FACILITY CONTACT USINESS ID NUMBER 15-021- oD 18 S9 Section 1: Business Plan and Inventory Program ROUTINE ^ COMBINED ^ JOINT AGENCY ^ MULTI-AGENCY~~ ^ COMPLAINT ^ RE-INSPECTION C C V ~ C=Compliance O P E R AT I O N V=violation COMMENT S ^ APPROPRIATE PERMIT ON HAND ^ BUSIf12SS PLAN CONTACT INFORMATION ACCURATE ~e G tti o~ ^ VISIBLE ADDRESS ^ CORRECT OCCUPANCY ~ ~. / tW ^ VERIFICATION OF INVENTORY MATERIALS ~~ ~ /'O GAS OTC .~Q. ^ VERIFICATION OF QUANTITIES ~/ 4~ ^ VERIFICATION OF LOCATION ^ PROPER SEGREGATION OF MATERIAL E7 ^ VERIFICATION OF MSDS AVAILABILITY ^ VERIFICATION OF HAZ MAT TRAINING ^ VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES ,~ ^ EMERGENCY PROCEDURES ADEQUATE ^ CONTAINERS PROPERLY LABELED ~~ ^ HOUSEKEEPING ^ FIRE PROTECTION f,Y^ SITE DIAGRAM ADEQUATE & ON HAND ANY HAZARDOUS WASTE ON SITE? ^ YES ~NO EXPLAIN: ,.QUESTIONS REGARDING THIS INSPECTION? PLEASE CALL US AT (661) 326-3879 Inspector (Please Print) Fire Prevention / 1s~ Iri /Shift of Site/Station # BAKERSFIELD FIRE DEPT >, p Prevention Services E!R/ 900 Truxtun Ave., Suite 210 A~>r~ ~ Bakersfield, CA 93301 White -Prevention Services Yellow -Station Copy Pink -Business Copy FD2049 (Rev. 02/05) F K MEDICAL SiteID: 015-021-001859 1 Manager RICHARD STEMPSON Location: 4800 WHITE LN L City BAKERSFIELD CommCode: BFD STA 07 EPA Numb: BusPhone: (661) 397-2691, Map 123 CommHaz Moderate Grid: 14C FaCUnits: 1 AOV: SIC Code:4925 DunnBrad:94-256-0044 Emergency Contact / Title Emergency Contact / Title RICHARD STEMPSON / MANAGER MARIA RUIZ / CSR SUPER Business Phone: (661) 397-2691x Business Phone: (661) 397-2691x 24-Hour Phone (661)-R-B~-~x 24-Hour Phone (661) 833-9006x Pager Phone (cec~) ~o a - ~S yl x Pager Phone ( ) - x Hazmat Hazards: Fire Press ImmHlth DelHlth Contact Phone: (661) 397-2691x MailAddr: 4800 WHITE LN L State: CA City BAKERSFIELD Zip 93309 Owner HOMECARE PREFERRED CHOICE INC Phone: (661) 397-2691x Address 3253 E SHIELDS AVE State: CA City FRESNO Zip 93726 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif ~ d: RSs : No ParcelNo: Emergency Directives: J -1- 08/22/2005 " M K MEDICAL . SiteID: 015-021-001859 Manager : RICHARD STEMPSON Location: 4800 WHITE LN L City BAKERSFIELD CommCode: BAKERSFIELD STATION 07 EPA Numb: . ~~~:. ~~~ ~ ~ BusPhone: Map : 123 Grid: 14C (661) 397-2691 CommHaz : Moderate FacUnits: 1 AOV: SIC Code:4925 DunnBrad:94-256-0044 Emergency Contact RICHARD STEMPSON Business Phone: 24-Hour Phone : Pager Phone / Title / MANAGER (661) 397-2691x (661) 835-3742x () x Hazmat Hazards: Contact : MailAddr: 4800 WHITE LN L City BAKERSFIELD Owner Address City Emergency Contact MARIA RUIZ Business Phone: 24-Hour Phone Pager Phone / Title / CSR SUPER (661) 397-2691x (661) 833 - 9006x () x Fire Press ImmHlth DelHlth Phone: (661) 397-2691x State: CA Zip 93309 Phone: (661) 397-2691x State: CA Zip 93726 TotalASTs: = Gal TotalUSTs: = Gal RSs: No HOME CARE PREFERRED CHOICE INC 3253 E SHIELDS AVE FRESNO Period Preparer: Certif'd: ParcelNo: to Emergency Directives: I.\<\~ ~ Do hereby certify that' have (Type Of print name) reviewed the attached hazardous materials manage- ment plan for~and that it along with (Name of BuSInea9) any corrections onstitute a complete and correct man- \ agement plan fa facility. ~ ~ If" , .'< " 9:,(f;~ -1- 09/09/2003 ~ - \ - BAKERSFIELD CITY FIRE DEPARTMENT HAZARDOUS MATERIALS DIVISION 1715 'CHESTERAV£~ BAKERSFIELD, CA. 93301 HAZARDOUS MATERIALS MANAGEMENT PLAN INSTRUCTIONS: . ¡ \15S~ J 1. ìo avoid further action. return this form within 30 days of receipt. Wt.. IL\- dO''""'"<. 2. TYPE/PRINT ANSWERS IN ENGLISH. J 3. Answer the questions below for the business as a whole. ,L\... ~ IRfEC~¡VI{~fi"¡, 4. Be brief and concise as possible. , ?- }.,¡.a.. FE8 'î a "1!;;,1Jd/ r: 1998 i J" 'rJ$1\CA t.Nl/fqOf\f (;Of;: q:>""\ \' \~.r \ ", )'·;:C:¡VlCES SECTION 1: BUSINESS IDENTIFICATION DATA BUSINESS NAME: M ~ M¿~' CAL LOCATION: '-t "00 W H \ '\Z... LI\\'-Jf... S 712... L SA.M,¿ MAILING ADDRESS: \'::¡.\.\LÐlLSfl C.L~ CITY: STATE: tA- ZIP: <;"'''>00, PHONE: 'S'ì'ì -'Lv'; I q«i -z:SlPoOL(!-f DUN & BRADSTREET NUMBER: SIC CODE: t.t '\ ?.-Ç PRIMARY ACTIVITY: V\~\ CAL SùPPLI £~ OWNER: (Lo "DÑ(¿ ~ \LE:.CSO MAILING ADDRESS: 'S2 <S~ .t:. Sl-\\~L$~ pQ.Ë.SND ( CA.. ~'1:.ìLU, SECTION 2: EMERGENCY NOTIFICATION: CONTACT \LE:.'J \ ~ \1\O~S 1. TITLE fv\&fL BUS. PHONE ~~ -, - '2...[,£11 24 HR. PHONE 8~S -~(y,- g~~- ~oo(P " (VI. A fL \ " {L.v\ \ "'L. 2. c,~a... ~ÞJ. ~C)ì -'2..(.p'\ \ , Bakersfield Fire Dept. -,zardous Materials Division e I HAZARDOUS MATERIALS MANAGEMENT P4AN £.. ..--....,; , SECTION 3: TRAINING: NUMBER OF EMPLOYEES: I i i MATERIAL SAFETY DATA SHEETS ON FILE: l{E:.<? \ b\ SPLÞ-..~~D A~~ A\Jf"\..IlÄf:,L£. felL £MPLCI'"((.L i \A,~t:.'.. BRIEF SUMMARY OF TRAINING PROGRAM: I I c.c.».)-rt~\A~ \"M.\N\NV- foIL S'7Aff CòùetL\ ~&- : ALL" A~PCc...(~ of ¡V\~\CAL SV1rPL~E."::::>, E:QlÁ\ PM~( , ere.. Iß SECTION 4: EXEMPTION REQUEST: , I ! I ! ¡ I -I I CERTIFY UNDER PENALTY OF PERJURY THA r MY BUSINESS IS EX~MPT FROM THE REPORTfNG REQUIREMENTS OF CHAPTER 6.95 OF THE "CALlFORNIA HEALTH & SAFETY CODE" ¡:OR THE FOLLOWING REASONS: II . I I WE DO NOT HANDLE HAZARDOUS MATERIALS. ¡ . I . WE DO HANDLE HAZARDOUS MATERIALS, BUT THEi QUA~TITIES AT NO TiMEEXCEED THE MINIMUM REPORTtNG QUANTrnES. ' \ I OTHER (SPECIFY REASON) SECTION 5: CERTIFICATION: I, CERTIFY THAT THE ABOVE INFOR- MATION IS ACCURATE. I UNDERSTAND THAT THIS INFORMATlqN WIll BE USED TO FULF¡L~MY F!RM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND !SAFETY CODE" ON HAzARDOUS MATERIALS (DIV. 20 CHAPTER 6.95 SEC. 25500 ET A:L.) AND THÄT INACCURATE INFORMATIONCONST!TUTES PERJURY. ::1 . ". - I . -Y..: ~: /'"1 L Il . TITLE 2/20/98 DATE SIGNA TURE 2. ,;;v-~. ~., ,6;..-..," Bakersñ~ld Fire Dept. e Hazardous Materials Divisione HAZARDOUS. MATERIALS MANAGEMENT PLAN Facility Unit Name: Vv\ ~ ME:'D\ CAL SECTION 6: NOTIFICATION AND EV ACUATION PROCEDURES: A. AGENCY NOTIFICATION PROCEDURES: ~D\,.:)l~ (.MPCO'-(CC (2£':lo,v,="f\)IC\l'1 ,0 CALL '\\\ fl (l..£(PDlA C)[, \~ CA...SC of- CM~Ci. B. EMPLOYEE NOTIF!CATlON AND EVACUATION: (Ñï~L A,.JtJOV..JLf:.j'\'¿~C: \' c..o~(.. (2..~" FofL P.>~ I L DI ~Ir- £..IJA..L.1-\.A.."TIOA..J f\12a1 ¡...) C;- PLA/..£ SE'.,c , I (,.",,>\ '"TM £,MPLò'tŒ. (2.oLL CAi-L ~ C. PUBLIC EVACUATION: (ALL .~ \ \ D. EMERGENCY MEDICAL PLAN: '\ \ \ ~ ;;;,"<: _ Bakersfield Fire Dept. e: Hazaràous Materials Division i-; _, "~'~ ., &..... ... HAZARDOUS MATERIALS MANAGEMENT PLA,N SECTION 7: MITIGATION, PREVENTION AND ABATEMENT PLA.N:. I A. RELEASE PREVENTION STEPS: A.LLL "C'U ,..n::>e!'l~ f,.fl.£ S¿c.<A.~~ ,~6A.\~S( . . I ~e:.. SOCA.cf-\. vJ~L\... W'ë~ Q.M\~ AND (t-J! FLa6tL fù....LcL~ I i I 8. RELEASE'CONTAINMENT AND/OR MINIMIZATION: I ~LL.(j;A..t:~f.,~_';>7 ~ ë 0 (Lð I µ ~o V\I~ wA.ll£rtoIAJE.C - So V\W (,.,JALL ! C. CLEAN-UP PROCEDURES: ì I I , I I I I . , , I : SECTION 8: UTILITY SHUT-OFFS (LOCATfON OF SHUT-OFFS:AT YOUR FACILITY): ; ~ NATURAL GAS/PROPANE: 'SOL-\ì'1-\ tw~":>'( ~~ of! c.o~rL£~ i ELECTRICAL: fJc>fL-n4.ðA.~-r CD~e:!L - ~fL of ¡ CDIMPu:"r WATER: lA(ÙILNowr0 ¡ -- SPECIAL: LOCK 80X~O !F YES, LOCATION: CL8-ïf2..\ CA-LL..LOse-T U>C.Œ~ SECTION 9: PRIVATE FIRE PROTECTION/WATER AVAILABI,lITY: A. PRIVATE FIRE PROTECTION: B. WATER AVAILABILITY (FIRE HYDRANT): {~-r. , - BAKr¡SFIELO CITY FIRE 0fiARTMENT HAZARDOUS MATERIALS DIVISION 1715 CHESTER AVE. . BAKERSFIELD, CA. 93301 (805) 326-3979 HAZARDOUS MATERIALS INVENTORY FACILITY DESCRIPTION I I I CHECK IF BUSINESS IS A FARM ( ] BUSINESS NAME M \L ME:..b\ tAL C ^ I}/\C FACILITY NAME /'" '- , SITE ADDRESS LI ßOO LJH rTE:. , ,CITY ßA\4::.iL '::>rl EL ~ ~ NATURE OF BUSINESS MO~\CJ\L LAt-JC S7- L t.... I I I I ! i , I i¡ I, !1 STATE CALI F. ~PPL\ E:::~ ZIP C1?:> ~oc; qy - 2. S(,;oDOc...l~ SIC CODE It'\ t.ç DUN & BRADSTREET NUMBER OWNER/OPERATOR (LO\:)~C'-( ~(SO PHONJ2D~) '2...~' - Lt'iLIL I i MAILING ADDRESS I \ CITY F(Œ:..~r0 0 í I ! , ~'LS~ t:. ~KIEL~~ .- STATE CAl,I~ Z!P o,~/L0 EMERGENCY CONTACTS NAME ~LV'N -rMOIf'/\A~ TITLE MtJL BUSiNESS PHONE ~c..ì - '2-L.¡c; \ 24-HOUR PHONE B~S' - ~ìL{ '- NAME M~(¿' A (L<A \~ BUSINESS PHONE ~ ~ ì - 2-L/ì , . TITLE c.. ~C<... ~ LAPv'. 2.4-HOUR PHONE ß~"'::> - ~oO(P SecI...-. :JO. 1 ggz REGION V I.E!'C STANCMUJ F- I BAKERSFIELD CITY FIRE DEPARI.~ENT HAZARI'JUS MATERIALS INVENT~ .:. ""-: \ usiness Name M ~ ~~\CAL Address '1 ßOO wI-{ I -rC l..L\NC' 'S:> 7(; L ~~;ge~ ofl. ~SfL.~. i CHEMICAL DESCRIPTION : ..:.; ; ,-' ., . ~,~tÞ ., I . ..-.. Check if chemical is a NON !mAce SECRET 'Þ6' TRADE SECRET [ I : ' 3' DOT # (optional) I AHM [] ¡ CAs#,,7.....ì -7.,ì-'\ 2) Common Name: 1) INVENTORY STATUS: New v4 Addition I J Revision I I Deletion I J µ \-r (Lo &LN ,J \ -rQ.O Ú-E:..N Chemical Name: 4) PHYSICAL & HEALTI-I HAZARD CATEGORIES PHYSICAL Fire (J Reactive {J Sudden Release ot Pressure { J , I HEAL TI-I Immediate Health (Acute) r J. Delayed Health (Chronic) ( I 3) 10) Location SO"" -r~ W A: l..L - '(,..I Nlc..K:OIA. <:> C .I 5) WASTE CLASSIFICATION 6) PHYSICAL STATE Solid [ J 7) AMOUNT AND TIME AT FACIUTY Maximum Daily Amount: Average Daily Amount: Annual Amount: Largest Size'Container: # Days On Site 9) MIXTURE: Ust the three most hazardous chemical components or any AHM components (3-digit code trom DHS Form 8022) USE CODE 'Z.. ì : Uquid [J Gas þ<J Pure ¥í Mixture [J waste! [ ] CHEOUU. TUAT.APPlY I : Radioactive I ] Z. 2... 1"2- ~ '50 UNITS OF MEASURE Ibs [ ] gal [] ft3 [J ~10 curies [ ] £1 c,," f" i ., 8) STORAGE CODES' a) Container: 0 '1 b) Pr~ssure: t c) Teinperature:: 'f I I M, A, M. Ji J, A, 5,,0, N, D ~ Circle Which Months: (All Ye81-:) F, COMPONENT I i CAS # i I , i : I I I %wr AHM [ J [ J [ ) 1 ) 2) tv \,[LO '^ '::> N \"\ (Lo &- €..,..J o 'f.-l b. E:.. ô'l- \ ~£ I I I Check if chemical is a NO~ TRACE SECRET ~ TRADE SECRET ( ] '¡ ;3) DOT # (optional) AHM [] ¡ CAS # \ 0 0 2. to{ - "ì ~ L CHEMICAL DESCRIPTION 2) Common Name: 1) INVENTORY STATUS: New [)(¡ Addition [ ] Revision r ] Deletion [ ] Chemical Name: 4) PHYSICAL & HEALTI-I HAZARD CATÉGORIES PHYSICAL Fire [] Reactive [1 Sudden Release of Pressure [ ] : HEAL TI-I Immediate Healthl (Acute) [) Delayed Health (Chronic) [ ] , : 5) WASTE CLASSIFiCATION I 6) PHYSICAL STATE Solid ( ] I 7) AMOUNT AND TIME AT FACIUTY Maximum Daily Amount: Average Daily Amount: Annual Amount: Largest Size Container: # Days On Site I 1 9) MIXTURE: Ust the three most hazardous chemical components or any AHM components .' (3-digit code trom DHS Form 8022) Uquid [] Gas ~ USE CODE 2.ì Pure [] Mixture [J Waste I [ ] Radioactive [ ] ::;"¡EQ( ALL T'HA r APPl" z. '- \'2... ~ '3D UNITS OF MEASURE 100 [ ] gal [ ] ft3 [ ] z:~D curies [ ] '" f4 , i 8) STORAGE CODES a) Container: I b) P~essure:' : . I c) Temperature: ! I, 0'1 I '1 -=-. Circle Which Months: (All Ye;:Y. F, M. A, M. U. J, A, S~ O. N. D COMPONENT CAS # %wr AHM I , ( ] I [ J I , " [ ] i , , 1) 2) " 3) ; 10) Location S.O\A.1l-\ (¡.IAI.-L - wN1£ttOlÃSC ' , cerafy unaer penalty or law, rt7ar I nave person81ly eJCammea ana am ramlllar WIth the mromaoon suomltted on thi~ and 81/ ~cl1ea documents. I oel/eve rt7e ¡LCI/IN 1110M~ submitted informaCion is true, accurate, and complete. Mt.fl- ~{.:.'--7 2/2.0lcr ø Date Signature PRINT Name & Title of Authorized Company RepresenraCive "-'--'111ia NmCN V UPC"'1IfOIIN3 fICIIIM BAKERSIiLELD CITY FIRE DEPA.iTMENT H~OUS MATERIALS INVENW,RY .:..-. ~ ~~ Page~o~_ 3usiness Name Address CHEMICAL DESCRIPTION 1) INVENTORY STATUS: New ( I Addition ( I Revision ( I Deletion ( ] Check if chemical is a NON TRACE SECRET ( ) TRADE SECRET ( ) 2) Common Name: 3) DOT II (optional) Chemical Name: AHM ( I CAS II 4) PHYSICAL & HEALTH PHYSICAL HEALTH HAZARD CATEGORIES Fire ( ] Reactive ( I Sudden Release 01 Pressure I I Immediate Health (Acute) ( ) Delayed Health (Chronic) I I " 5) WASTE CLASSIFICATION (3-digit code from DHS Form 8022) USE CODE 6) PHYSICAL STATE Solid ( I Uquid I ] Gas I ] Pure I] Mixture ( ] Waste ( ] Rlldioective ( ] CHECKALL THAT APPlY 7) AMOUNT AND TIME AT FACIUTY UNITS OF MEASURE 8) STORAGE CODES Maximum Daily Amount: Ibsl]gall] 1t3 I ] a) Container: Average Daily Amount: curies I I b) Pressure: Annuai Amount: c) Temperature: Largest Size Container: # Days On Site Circle Which Months: All Year, J. F, M, A, M. J. J. A, S. 0, N, D 9) MIXTURE: Ust COMPONENT CAS II %WT AHM the three most hazardous 1) ( I chemical components or any AHM components 2) ( J 3) ( J 10) Location CHEMICAL DESCRIPTION 1) INVENTORY STATUS: New I ] Addition I ] Revision I ] Deletion I ] Check if chemical is a NON TRADE SECRET I ] TRADE SECRET I I 2) Common Name: 3) DOT # (optional) Chemical Name: AHM I I CAS II 4) PHYSICAL & HEALTH PHYSICAL HEALTH HAZARD CATEGORIES Fire I ] Reactive I ] Sudden Release of Pressure I] Immediate Health (Acute) I I Delayed Health (Chronic) ( I 5) WASTE CLASSIFICATION (3-digit code from DHS Form 8022) USE CODE 6) PHYSICAL STATE Solid I] Uquid I ] Gas I ] Pure I] Mixture I J Waste ( ] Radioactive ( J CHfCl<Al.1. THAT APPlY 7) AMOUNT AND TIME AT FACIUTY UNITS OF MEASURE 8) STORAGE CODES Maximum Daily Amount: Ibs [ ] gal I ] ft3 I ] a) Container: Average Daily Amount: curies I ] b) Pressure: Annual Amount: c) Temperature: Largest Size Container: # Days On Site Circle Which Months: All Year. J. F, M. A. M, J. J, A. S. O. N, D 9) MIXTURE: Ust COMPONENT CAS # %WT AHM the three most hazardous 1) ( J chemical components or any AHM components 2) ( J 3) ( ] 10) Location certify under penalty of law, that I have personallyexarmned and am famIliar WIth the Infomaaon submitted on thIS and aJlattacned aocuments. I believe me ubmitted information is true, accurate, and complete. 'RINT Name & Title of Authorized Company Representative Signature Date -,- NmCJiI V t.EPC ST'AfiiGIIfIO FiD''' """J,_~ BAKERSFIELD CITY FIRE DEPART~ENT HAZAWOUS MATERIALS INVENTtfYi . 'f'^. \L. M£,D\(.A.L Address l( ßDO WH- r7C ~~ ~'7('C L. Page~of2. ~[ ,:>Fu~ . Business Name , CHEMICAL DESCRIPTION , I 1> INVENTORY STATUS: New)(J Addition [ ) Revision [ ) Deletion [ ) Check if chemical is a NO~ TRADE SECRET þ(J TRADE SECRET ( ) 2) Common Name: D ~ '-( &-e.N ;3) DOT # (optional) I o 'f.- l.( 6- e. f-..J ! : (I B'2-_L\L\ - ì Chemical Name: AHM ( ) I CAS If , ¡ 4) PHYSICAL & HEALTH PHYSICAL I HEÞ¥-TH HAZARD CATEGORIES Fire [ ] Reactive [ ] Sudden Release of Pressure [ ] Immediate Health, (Acute) [il) Delayed Health (Chronic) [ ) 5) WASTE CLASSIFICATION (3-digit code from DHS Form 8022) USE CODE 2..ì ! , , Gas pQ Pure Þ<i I ,I 6) PHYSICAL STATE Solid { J Uquid { J Mixture { J Weste; ( ) Radioactive ( I I OlEO( ALL. ruAT APPlY I 7) AMOUNT AND TIME AT FACIUTY I UNITS OF MEASURE 21.(<; 8) STO~GE CODES Maximum Daily Amount: \00 100 [ ] gal [ ) ft3 [ ] a) C~ntainer: 0'1 Average Daily Amount: curies [ ] CI1 f7 b) P~essure: I I Annual Amount: c) Temperature: 'f largest Size 'Container: ~ ~ I I # Days On Site 30 Circle Which Months: C All Ye~.), F, M, A, M, I! N. D ~. J, A. S¡ O. I :¡ 9) MIXTURE: Ust COMPONENT ! CAS~ %WT AHM ¡he three most hazardous 1) ¡ , [ I chemical components or any AHM components 2) , ( 1 I ; 3) I [ ] - W A.tlO\OIA ~£ I J 10) Location S C> \I\-rH wl\LL I ! CHEMICAL DESCRIPTION I , I " i 1) INVENTORY STATUS: New ~ Addition [ ] Revision [ ] J Deletion [ ] Check if chemical is a NO('4 TRADE S,ECRET o(] TRADE SECRET [ ] 2) Common Name: . 0 'f.-.l.( f7E-"J ( CJL'-( () &fjoJ \ C- U &Ù , 'b \ I , 13) DOT #~(optional) I i ì I 82.. - £- I..- "7 Chemical Name: o 'i-. I.( &-E_fo...J AHM [ ] I I CAS # I 4) PHYSICAL & HEALTH PHYSICAL i HEALTH I HAZARD CATEGORIES Fire [ ] Reactive [ ] Sudden Release of Pressure [ ] Immediate Health (Acute) [,,] Delayed Health (Chronic) [ ] , 2-ì : I 5) WASTE CLASSIFICATION (3-digit code from DHS Form 8022) USE CODE I , I Uquid þ{ ~ , i 6) PHYSICAL STATE Solid [ ] Gas [ ] Pure Mixture [ ) Wastl!. [ ] , Radioactive ( ] , I I CHECK ALL THAT APPt'f I I 7) AMOUNT AND TIME AT FACIUTY UNITS OF MEASURE L(SC> 8) STORAGE CODES Oç Maximum Daily Amount: Ibs [ ] gal [] ft3 [ ] -5 ,., a) Container: 1 I Average Daily Amount: curies [ ] tIA f b) ~ressure: ,I Annual: Amount: c) ~emperaturé: 7 Largest Size Container: " # Days On Site Circle Which Months: All Year, J, F, M, A. M, ¡J, J, A. S. O. N.D 9) MIXTURE: Ust COMPONENT ¡ CAS # %WT AHM the three most hazardous 1) I [ ] chemical components or , any AHM components '2) ¡ , [ ] I , 3) [ J 10) Location I , certIfy under penalty of law. that I have personallyexammed and am famlllSf wlm me mfomat1on submitted on U7!S and all ~ttsched documents. I believe the submitted information is true, accurate, and complete. (L£.U I ,.J -rn 0 MA. ~ 1'1 t.A- --x.~ 2/Zv/CJ9 , Date Signature PRINT Name & Title of Authorized Company Representative ~""'3Q 'D82 NœCJII v I.EPC 1T#IND#rN) FCJW APR-11-1996 11:53 MK MEDICAL CUSTOMER SERU 209 228 3014 P.03 -;/.~'"'-_"C;;'.-;- ~ MATERIAl AFETY DATA SHEE LlQtJlD CARBONIC rNDUST1W'UM£DlCAL CORPORATION 135 SOUTl1 LA SALI.E STREET· CHICAGO. ILUNOIS 606~8Z PI1ONE; \312) 355~500 Gaseous . Ni troge.."l AprU 1986 Emergency Phone NUmbers: (312)855-2500; C8EMr.REc (800)424-9300 SF.X:TICN I-PRCOOCl' IDENI'IFICATICNi æ:EMICAL NAME: Ni tzogen C(M.DN Ni\ME Þ.ND SYNCNYMS: ,Gaseous Nitrogen, Nitrogen: Gas, GN3 CHEMICAL FAMILY: Inert Gas roFMJIA: N 2 særICN II-HAZARDCUS INGREDIENl'S vawME % CAS 00. 99.9% 7727-37-9 l-iATERIAL Nitrogen 1985-6 M:Gm TLV UNITS NitJ:ogen is a siItple asphyxiAnt.. .BOII.J:N; POINT (OF.) V1ù?OR PRESSURE (nmBg.) VAPOR DENSITY (AIR=1) SOLtJBJLITY m ~ APPFARANCE MID a:oR SECI'ICN III-PHYSICAL DATA -320.40 SPEx:IFIC GPAvnY (H2CÞ:l) @-320.4° - 760 % VOI:.ATILE¡ BY VOLOME 0.967 ~CN PATE Slightly (Bt:JfiL ÞCETATE=1) Colorless and Cðor1ess 0.809 @B.P. 100.0 Gas Sæ:rICN IV-FmE AND EXPLœICN HAZAroi DATA . ¡ LEE, UE!.. FLASH POINT (MmiOD USED) N/A ~ LIM!TS - N¡¡::- EXTINGUISHING MEDIA: Non-Flamtab1e Inert Gas SPEcrAL FIRE FIœTlNG PK:CEDURES: Non-flanmable and will not support combustion. . tJNUSUAL FIRE AND EXPU:6ICN HAZARDS: Non-flattmable. ~ unusual hazard except when <:aq?ressed gas is ~sed to a fire, containers may npture violently if safety devices fail to relieve pressure. S!x::l'ICN V-HEALTH HAZAID DÞœA I THRESHOLD LIMIT V2WJE: Nitroge.."l is non-toxic and is classified as a siItple asphyxiant by disp1acerœ."1i: of 9Xi-gen. ~'J::.t:L"'TS OF 0VERE:XPœURE: Dizziness, unconciousness, death ; Ð1æGENCY AND FIRST AID PIn:EDURES: If inhaled raroved to fresh air. Þ.ðminisi::.e.r air or oxygen. Cbtain pranpt Iœdica.l attention. Give' cardicpulrrDnar.f resuscitation. Pescuers need to be concerned with their 0W'n safety in oxygen deficient areas. Use self-contained breathing equi-prent. Nitrogen can cause rapid suffocation. Oxygen levels should be maintained :at greater than 18% by volume at nonnal a1::nDspheric pressure which is equivalent to a partial pressure of 135rtm Eg. I RCm.'E (S) OF EN1'.RY: INHALATICN? yes SKIN? ¡ CARC1N:GENICn'Y: NrP? No IARC M)NCX;AAPHS? ~ :m;ESTICN? ŒHA? No PAGE 1 APP-ll-1qqh 11:~h Form ST~4AO :>nq ""R 1n1<1 q7% p rn APR-11-1996 11:54 MK MEDICAL CUSTOMER SERV 209 228 3014 P.04 -A.... ~ --~~ <' e e: I I i SEX:.l'IW VJ.-RFJICrIVI'l'Y DATA 5'rABILI'l'Y: UNSTABLE () STABLE (X) C(N)ITICN; 'ro AVOID: N/A IN:OMPATABILI'l'Y CWœER:1::ALS 'ro AVOID): Inert except at high ~atures BAZA1<IXX1S DEX::X::M:œITICN PRODOCTS: None BAZARIXUS PCLYMERIZATIŒ: MAY ccaJR () ~'T OCOJR (X)· OH>ITIONS 'ro AVOID: N/A særIœ VII-SPILL OR LEAK pKX:E:X.JRES I STEPS TO BE TAKEN IN CASE MATERIAL IS RELFASED OR SPILLID: . ENacuate all personnel fran affected area. To enter spill ~,use self-contained breathing equiprent. Maintain adequate venti1àtion to avoid oxygen ðèficiency. . ¡ , WASTE DISPCSAL ~: a:, waste disposal prcblem. Gas will cIµfuse into ab1Dsphere. : . I i SE1:TICN VIII-SPECIAL PIDl'J::L'J.'.LŒ INroBMATIŒ vmnIATIOO': IœAL EXHAUST RESPIRATORY P.I:«.ll".tk.:J.'lCN: ! Self-contained breathing apparatus or pressure denand air S\JPPly mask. i I Use at };X>ints of ~se·to maintain over 18% oxygen in air. ! I (X) MEX::HANICAL (GENERAL) () PÍVI'Ex.:l·.l. VE GImES: Cotton or leather. FiE Proræll!CN: ~les or glasses , 0l1ŒR ProrECl'IVE EUJIPMENl': ù:M oxygen alarm where necessary; ; Safety shoes , , , SEX:I'ICN IX-SP:æIAL PREX:W1'!CNS PREDillTICES 'ro BE TAIŒN rn HANDI.m; RID S'roRING: Protect containers fran physical damage. Use only DOl' or ASME coded storage vessels. follOW' ncmna.l ,,,;uull;Jressed gas storage practices. ~t9re in cool and dry ventilated areas. ! C7Im:R PREX:W1'!CNS: Refer to ~ Bulletin 5&-2 and panphlets ipt9 and P-14. , SB-2 - "Oxygen Deficient Atrrospheresft : P-9 - "The Inert Gases Argon, Nitrogen 'and Heliun P-14 - "~i ñE'nt Prevention in Cbcygen-Ri~ and Oxygen-Deficient Atm:>spheres" ,i Use a check valve or trap in the nitrogen cylinder discharge :µne to prevent hazardous backflav. Cyl.:inders or containers nust not be recharged e."Cœpt by or with the oonsent of Liquid Ca.tbonic. No guaranty is made as to the accuracy of any data or statement contained he~ein. While this material is furnished in good faith. NO WARRANTY EXPRESS OR IMPLIED, OF MERCJ!.fANTABILlTY. FITNESS OR OTHERWISE IS MADE. This material is offered only for your consideration~ investigation and veri- fication and liquid Carbonic shall not in any event be liable for special, incièlental or consequential damages in connection with its publication. ' PAGE 2 APR-11-1996 11:57 21219 228 312114 98% c__ t:"f' """",.,.. P.ø4 . ";'...)-'"'"'-- t,~ ~ . e- . MATERIAL SAFETY DATA'S'HEET L-4636-B December 1992 l;¡;~pn 11 V ~JR :;::;~, ~ An explanarion of tha terms used herein may be found in OSHA 29 CFR 1910. 1200, aveilable (rom OSHA regional or ilrea offices. (Essentially similar to US Depertment 01 Llllbo, Form OMS No. 1218-0072/ 00 Not DupRcete This Form. Request en Original. o lilfIJIJ¡I~'~lfl¡ii~III¡I~11!¡fI1¡~]j'11¡11¡1¡!I¡IIII¡¡:'::¡¡II:¡¡¡I¡¡fl¡¡I¡I¡¡¡¡I¡¡I!~:I¡glt:g:êMm1[r2:§1Iit1I1~lir;,:~:,~~::>~~:, PRODUCT Nitrous Oxide CHEMICAL NAME Nitrogen Oxide SYNONYMS Dinitrogen Monoxide, Nitrogen(1) Oxide, Factitious Air, Hyponitrous Acid Anhydride, Laughing Gas FORMULA N20 CHEMICAL FAMILY Nitrogen Oxides MOLECULAR WEIGHT 44.013 TRADE NAME Nitrous Oxide For mixtures of this product request ·the respective component Material Data Safety Sheets. See Section IX. MATERIAL (CAS NO.) Nitrogen Oxide (10024-97-2) Wt (%) 100 1992-1993 ACGIH TLV-TWA (OSHA-PEL) 50 ppm (None currently established) 1'111181:: Praxair, Inc. has established its own Internal Exposure Limit as 25 ppm. . ..:.:.~;:;:.::::::::~~~::~::::::::::::::::~~~:;~:}~}»::~~~:·::~:*:~:·:·:::::~·:C:~:::::::?~~f~~~r~r~~:·:· . . 1.¡:PHYSrCJ.U'kÐ'AH~ ·;;::";:;:·X*-::;:$~::,i:ý;?';:,.;«~: ·:~"{{Ÿ;;;'$(~·;·"t:.·:····1(;·CC·; ..~.;. -88.5°C (-127.3°FJ FREEZING POINT -90.BoC (-131.5°FJ BOIliNG POINT, 760 mm. Hg SPECIFIC GRAVITY (H20 = 1 J 1.226 @ -89°C VAPOR PRESSURE AT 21°C. 745 psig 1.53 @ 20°C SOLUBILITY IN Slight WATER, % by wt. 100 EV APORA TION RATE High (Butyl acetate = 1) V APOR DENSITY (air = 1) PERCENT VOLATILES BY VOLUME APPEARANCE AND ODOR Colorless gas at normal temperature and pressure; sweet odor. IN CASE OF EMERGENCIES involving this material, further information is available at all times: .. Call CHEMTREC 800-424-9300 only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. For routine information contact your supplier. :0 , ',:) M ~ <1" I -I This product is subject to the Pennsylvania Worker and Community Right-To-Know Act (35 P.S. Sections 7301-7320). Praxair requests the users of this product to study this Material Safety Data Sheet (MSDSJ and become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safèty information. PRAXAIR, INC. Printed on recycled paper. Copyright <P 199 Z Praxair Technology, Inc. o Page 1 of 4 -- .e e ¡.,-.. PRODUCT: Nitrous Oxide L-4636-B December 1992 THRESHOLD LIMIT VALUE: See Section II. EFFECTS OF A SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING-An unlikely route of exposure. This product is a gas at normal temperature and pressure, but frostbite of the lips and mouth may occur. SKIN ABSORPTION-No evidence of adverse effects from available information. '" INHALATION-May cause excitation, euphoria, dizziness, drowsiness, incoordination, and narcosis. Exposure to concentrations of 50% and greater will produce clinical anesthesia. High concentrations may cause asphyxia and death. Lack of oxygen can cause death. SKIN CONTACT-Cryogenic burns ,(similar ,to severe frostbite) may occur as a result of the rapid- evaporation of the" liquefied gas. EYE CONTACT -Cryogenic burns to the eyes may occur as a result of contact with the liquefied gas. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: Metabolic injury to the nervous system has resulted from frequent exposure to anesthetic concentrations of nitrous oxide. Complaints include numbness, tingling of hands and legs, loss of feeling in fingers, poor balance, and muscular weakness. OTHER EFFECTS OF OVEREXPOSURE: Exposure to nitrous oxide has produced embryofetal toxicity in laboratory animals as evidenced by reduced fetal weight, delayed ossification, and increased incidence of visceral and skeletal variations. Exposure to nitrous oxide may be associated with an increased incidence of abortion in humans. Single prolonged exposure to high concentrations of nitrous oxide has resulted in bone marrow injury and adverse effects on the blood. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Anesthetic gases in general, and nitrous oxide in particular, may suppress immunological function when administered for anesthetic purposes. This may reduce the resistance to infection and other immuno-dependent disease processes. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING-This product is a gas at normal temperature and pressure. SKIN CONTACT -For exposure to liquid, immediately warm frostbite area with warm water (not to exceed 105 OF). In case of massive exposure, remove clothing while showering with warm water. Call a physician. INHALATION-Remóve to fresh air. Give artificial respiration if not breathing. Oxygen may be administered when necessary. Call a physician. EYE CONTACT ":'For contact with the liquid, immediately flush eyes thoroughly with water for at least 15 minutes. See a physician, preferably an ophthalmologist, immediately. NOTES TO PHYSICIAN: Nitrous oxide may cause vitamin 8'2 deficiency. Megaloblastic anemia and nervous system disorders can occur as a result of this chemically induced deficiency. i ." Page 2 of 4 .-- ;1'- PRODUCT: . Nitrous Oxide e- e L-4636·B December 1992 ".<,:,"'j~llilÊt¡]111!§I~!g!!t§lg~~!~(~r9IF\"":':~,'" AUTOIGNITION TEMPERATURE FLASH POINT (test method) Not applicable Not applicable FLAMMABLE LIMITS IN AIR, % by volume EXTINGUISHING MEDIA: Oxidizing agent. May accelerate combustion. Use media appropriate for surrounding fire. LOWER Not applicable UPPER ~o applicable SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Do not approach area without self· contained breathing apparatus and protective clothing. Immediately cool containers with water spray from maximum distance until cool then move containers away from fire area if without risk. If containers are leaking reduce vapors with water spray or fog. Shut off leak if without risk. Move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxidizing agent, may accelerate combustion. Contact with flammable materials may cause fire or explosion. Container may rupture due to heat of fire. Decomposes explosively at high temperature. No part of a container should be subjected to:a temperature higher than 52°C (approximately .125 OF). . ..' Vapors form' from this' product and may travel or be moved-by air currents and ignited by pilot lights, other flames, smoking,- sparks,' !:Ieaters, electrical equipment,' static discharges or other. ignition ,sources at locations distant from' p'roduct handling point. Most containers are provided with a pressure-relief device designed to vent contents when they are exposed to elevated temperature... ' . ii¡I[~:~i¡~~¡j~Jllj.lfl~ '11ITllml~r.[fiŒg~1!fti~)ml!:t STABILITY CONDITIONS TO AVOID: See Section IX. UNST ABLE STABLE X INCOMPATIBILITY (materials to avoid): Oils, greases, flammable materials, alkali metals, aluminum, boron, tungsten carbide. HAZARDOUS DECOMPOSITION PRODUCTS: This compound decomposes explosively at high temperature forming a mixture of nitrogen and oxygen in a 2: 1 ratio respectively. This reaction will occur at lower temperatures in the presence of catalytic surfaces such as silver, platinum, cobalt, copper oxides or nickel oxides. HAZARDOUS POL YMERIZA TION CONDITIONS TO AVOID: None currently known. May Occur Will not Occur X l@ì~¡~flllll\lI: .¡¡I!JiI§Rlçg1g:ß]ß]!1SIg;ßgl~~!I§~I<i~~*, \~:!ill¡~l}II'j¡t¡ll~~k STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Immediately evacuate all personnel from danger area. Use self-contained bseathing apparatus where needed. Contact with flammable materials may cause fire or explosion (see Section VI. Reduce vapors with fog or fine water spray. Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area. Vapors may spread from spill. Before entering area, especially confined areas, check atmosphere with appropriate device. See Section V: Unusual Fire and Explosion Hazards. WASTE DISPOSAL METHOD: Prevent waste from contaminating surrounding environment. Keep personnel away. Discard any product, residue, disposable container or liner in an environmentally acceptable manner, in full compliance f with federal, state and local regulations, I i , 1 l f \ . . , ~ \ Page 3 of 4 .;;,--~.c::' . e- e L-4636-B December .1992 ?:ìODUCT: Nitrous Oxide li:~¡~¡f~M~~~¡w¿~fl~I['IIIII:II¡¥Jl¡~lm€!!:m1tR:[2;j;!!I!g:~)!:¡!~E[~!!I~!]¡IITI~!~~~¡~1¡IIIII~¡lrji¡III¡llf¡1111lfrrffllrJIJ.JIíI ESPIRATORY PROTECTION (specify type): Use air-supplied respirator in a continuous flow mode for concentrations up J 10 times the applicable permissible exposure limit. A self-contained breathing apparatus in a positive pressure '.:emand mode is required for higher concentrations. The respiratory protection use must conform with OSHA rules as soecified in 29 CFR 1910.134. . LOCAL EXHAUST -Use local exhaust ventilation with sufficient air flow velocity to maintain the its concentration below its TlV in the worker's breathing zone. ....·ENTILATION MECHANICAL (general)-Not recommended as a primary ventilation system to control worker's exposure. SÆCIAL-None OTHER-None ?ROTECTIVE GLOVES: Preferred for cylinder handling and liquid exposure. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cyl!nder handling~Protective clothing where·needed. Select in accordance with OSHA 29 CFR 1910.132 and 1910.133. 'vARNING: Uquefied oxidizing gas under pressure. Vigorously accelerates combustion, use piping and equipment adequately Je$;gned to withstand pressures to be encountered. Store and use with adequate ventilation at all times. Use only in closed :ystem conditioned for nitrous oxide service. Close valve when not in use and when empty. Store away from flammable :-:aterials. ,:IXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create ,;dditional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the . mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. . ~emember, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all 3bels and other instructions supplied with all containers of this product. "OTE: Compatibility with plastics should be confirmed prior to use. For safety information on general handling of compressed . :s cylinders, obtain a copy of pamphlet P-1, ""Safe Handling of Compressed Gas in Containers" from the Compressed Gas ;sociation, Inc., 1725 Jefferson Davis Highway, Suite 1004, Arlington, VA 22202. THER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder ;;ve, blow down the system by venting to a safe place, then repair the leak. '\.. . j I .. .. -he opinions expressed herein are those of qualified experts within Praxair, Inc. We believe that the information :Jntained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and iI~se opinions and the conditions of use of the product are not within the control of Praxair, Inc., it is the user's Jbligation to determine the conditions of safe use of the product. :i[ilfffPRAXAIR GENERAL OFFICES Praxair, Inc. 39 Old Ridgebury Road Danbury, CT 06810-5113 '<:Ige 4 of 4 Printed in USA .. MA~IAL SAFETY DATA stEET L-463S-C December 1992 ff!j~PRAXAJR An øxplanation of thø terms usød hørøin m"y bø found in OSHA 29 CFR 1910.1200, eveilable from OSHA regional or are" offices. IEssentlally sImilar to US Depertment of Lebor Form OMS No. 1218·00721 Do Not Duplicate This Form. Requ..t IIn Original. o li¡it1tli\~~II"Jillllf~¡i:~¡¡~~~¡t\I~~~Ii.¡¡I¡II~i¡~~]i~gl!i9Hm)rq§a;I¡III;!li~~~ft¡lliMti::,~:~~úi~1¡~1¡1)IIJIII_il'~!!Jf[{1 PRODUCT Oxygen CHEMICAL Oxygen SYNONYMS Not applicable NAME FORMULA O2 CHEMICAL Not applicable FAMILY MOLECULAR 32,00 WEIGHT TRADE NAME Oxygen 1IIIIIIItIIIlllllli!¡lilr~ili!lf¡¡il¡!i!it¡~1IE!~ð:H§!tlrl!q!:m1i;¡~ji!111111tIíIIIIIIIJ¡~ For mixtures of this product request the respecdve component Material Safety Data sheets. See Section IX. MATERIAL (CAS NO.) Oxygen (7782-44-7) Wt (%) 100 1992·1993 ACG'IH TlV-TWA (OSHA-PEL) None currently established (None currently established) "Jlt¡jf~i¡¡;¡llllf'ïjl_ii~iIM;~l!lÆJi'II~JJ:::':'::,. , '1Iífil~I_ljllfIIJ!I,~ìlll; SPECIFIC GRAVITY (H20 = 1) Gas FREEZING POINT -218.4 °C (-361.1 OF) VAPOR PRESSURE AT 20°C. Gas SOLUBILITY IN WATER, % by wt.. Negligible EVAPORATION RATE (Butyl acetate = 1) Not applicable BOILING POINT, 760 mm. Hg -183°C (-297.4°F) VAPOR DENSITY (air = 1) 1.105 @ 25°C PERCENT VOLATilES BY VOLUME 100 APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure. IN CASE OF EMERGENCIES involving this material, further information is available at all times: .. , I i ¡ , ~ ~ Call CHEMTREC 800-424-9300 only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident ;nvolving chemicals. For routine information contact 'your supplier. ¡his product is subject to the Pennsylvania Worker and Community Right-To-Know Act !35 P.S. Sections 7301-7320). ,raxair requests the users of this product to study this Material Safety Data Sheet IMSDS) and become aware of product azards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same 'formation to each of its customers for the product, and (3) request such customers to notify their employees and customers :.;r the prodûct of the same product hazards and safety information. . PRAXAIR, INC. Printed on recycled paper. :opyright @ 199Z Praxair Technology, Inc. o Page 1 of 4 :-' e e PRODUCT: Oxygen L4638-C December 1992 :;.m ::}it:~:· :llltIl¡II~li)JI.11Jll!II;!~JfJ!1Ê¡!~:!llt1IJf.!111l1Illilili};1fl¡IIJf!iilill!illfÌ[~f THRESHOLD LIMIT VALUE: None currently established. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING-No evidence of adverse effects from available information. SKIN ABSORPTION-No evidence of adverse effects from available information. INHALATION-Breathing 80% or more oxygen at atmospheric pressure for more than a few hours may cause nasal stuffiness, cough, sore throat, chest pain and breathing difficulty. Breathing oxygen at higher pressure increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause lung damage and also central nervous system effects resulting in dizziness, poor coordination, tingling sensation, visual and hearing disturbances, muscular twitching, unconsciousness and convulsions. Breathing oxygen under pressure may cause prolongation of adaptation to darkness and reduced peripheral vision. SKIN CONTACT -No evidence of adverse effects from available information. EYE CONTACT -No evidence of ,adverse effects from available information. ~¡:fECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. .. THER EFFECTS OF OVEREXPOSURE: See MNotes to Physician. M AEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: See "Notes to Physician." SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None -::urrently known. :MERGENCY AND FIRST AID PROCEDURES: SWALLOWING-This produc~ is a gas at normal temperature and pressure. SKIN-No emergency care anticipated. INHALATION-Remove to fresh air. Give artificial respiration if not breathing. Keep victim warm and at rest. Call a physician, EYES-No emergency care anticipated. IOTES TO PHYSICIAN: Supportive treatment should include immediate sedation, anti-convulsive therapy if needed, and 'S:. Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, =:eases the susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate ,Jt vitamin E deficiency may increase susceptibility to oxygen toxicity. way obstruction during high oxygen tension may cause alveolar collapse following absorption of the oxygen. '.nilar/y, occlusion of the eustachian tubes may cause retraction of the eardrum and obstruction of the paranasal "uses may produce "'vacuum-typeM headache. !wborn premature infants exposed to high oxygen concentrations may suffer delayed retinal damage which can 'ogress to retinal detachment and blindness (retrolental fibroplasia). Retinal damage can also occur in adults exposed I 100% oxygen under greater than atmospheric pressure, particularly in individuals whose retinal circulation has been 'eviously compromised.. . .. individuals exposed for long periods to oxygen at high pressure and all who exhibit overt oxygen toxicity should 'e ophthalmologic examinations. =N USED IN WELDING AND CUTTING: Read and understand the manufacturer's instructions and the precautionary ·1 on the product. See American Standard Z49.1 "Safety In Welding and Cutting" published by the American ding Society, PO Box 351040, Miami, Florida 33135 and OSHA Publication 2206 129CFR19101, US Government ring Office, Washington, DC 20402 for more detail. For further SAFETY AND HEALTH information, refer to (air's free publication, L-52-529, "Precautions and Safe Practices for Electric Welding and Cutting," as well as L- : 5, ·Precautions and Safe Practices for Gas Welding, Cutting, and Heating." You may obtain copies from your focal _pHer. ' 'rEo' Suitability for use as a component in underwater breathing gas mixtures is to be determined by or under the '~rvision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the effects, "ods, frequency and duration of use, hazards, side effects and precautions to be taken. . "f 4 c ,. I . . I J \ PRODUCT: Oxygen e-- e L-4638-C December 1992 ð'- .~ J:1 ¡'(îI1'11¡~J~j~I_lllllí¡lllllflltll1~Jj!BBb~!I~llltfÍ~1Iml!111[1ffiII~III11111¡¡¡r~l~ FLASH POINT (test method) Not applicable AUTOIGNITION TEMPERATURE Not applicable FLAMMABLE LIMITS IN AIR, % by volume LOWER Not applicable UPPER Not applicable EXTINGUISHING MEDIA: Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (i.e. safety shower) is the preferred extinguishing media for clothing fires. SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately cool containers with water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxidizing agent, vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion. Container may rupture due to heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125 OF)., Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevàted temperature. Smoking, flames and electric sparks in the presence of enriched oxygen atmospheres are potential explosion hazards. "li~¥íi!m¡:lçM!I¡1MIII.h: ~:~:j~~ljIIL,: ! I ) STABILITY CONDITIONS TO A YOlO: See Section IX. UNSTABLE STABLE X INCOMPATIBILITY (materials to avoid): Combustible materials, asphalt, flammable materials, especially oils and greases. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POL YMERIZA TION CONDITIONS TO AYOID: None currently known. May Occur Will not occur ". X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Shut off leak if without risk. Ventilate area of leak or move leaking ccrniainl!r to well-ventilated area. Remove all flammable materials from vicinity. Oxygen must never be . permitted to strike an oily surface, greasy clothes, or other combustible material. WASTE DISPOSAL METHOD: Slowly release into atmosphere, in an open, outdoors area. Remove all flammable materials from vicinity. I . . f ¡ 4 '1 I ¡ ¡ PSIJ'! 3 of 4 'i ;;J<~ .' e e- L-463S-C December 1992 'RODUCT: Oxygen ::"'Jtt._JI1!~1i~pJ!~~h!!i~IIJ&~!I¡¡11¡¡it, Y.', RESPIRATORY PROTECTION (specify type): None required under normal use. However, air-supplied respirators are ( required while working in confined spaces with this product. The respiratory protection use must conform with OSHA rules as specified in 29 CFR 1910.134. LOCAL EXHAUST -Use local exhaust system, if necessary, to prevent the build up of oxygen concentration. VENTILATION MECHANICAL (general)-Acceptable SPECIAL--Not applicable OTHER-Not applicable 'AOTECTIVE GLOVES: Preferred for cylinder handling. IE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. 'THER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 310.132 and 1910.133. ':::Q1f!iafllli>Jlliltlll!¡:¡: A:-:INING: High pressure gas. Vigorously accelerates combustion. Avoid contact with oils, greases and other flammable -,!erials, Never use manifolds for oxygen cylinders unless specifically designed for such use. Use only' with equipment '~ditioned for oxygen service. Use piping and equipment adequately designed to withstand pressures to be encountered. ¡tect container against physical damage. Isolate from combustible gas installations and combustible materials by adequate ~ance or by gas-tight, fire-resistive barriers. Protect against over-heating. Never use an oxygen jet for cleaning purposes ,ny sort, especially clothing, as it increases the likelihood of an engulfing fire. Note: Reverse flow into cylinder may cause '..:re. Use a check valve or other protective apparatus in any line or piping from the cylinder to prevent reverse flow. ':URES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create onal, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the ,: Ae. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. -'~mber, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all and other instructions supplied with all containers of this product. , Compatibility with plastics should be confirmed prior to use, For safety information on general handling of compressed 'Iinders, obtain a copy of pamphlet poT, "Safe Handling of Compressed Gas in Containers" from the Compressed Gas _.:iation, Inc., 1725 Jefferson Davis Highway, Suite 1004, Arlington, VA 22202. :;t HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder ~Iow down the system by venting to a safe place, then repair the leak. Never lubricate oxygen valves, regulators, etc., 3ny combustible substance. .. .. opinions expressed herein are those of qualified experts within Praxair, Inc. We believe that the information dned herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and. opinions and the conditions of use of the product are not within the control of Praxair, Inc., it is the user's tion to determine the conditions of safe use of the product. '~PRAXAIR GENERAL OFFICES Praxair, Inc. . 39 Old Ridgebury Road Danbury, CT 06810-5113 :¡f 4 Printed in USA . ¡ 1 J i ¡ I I I I ! ¡ ì I ~ ~ .. :-C-, > e e MATERIAL SAFETY DATA SHEET L-4637-D December 1992 ff!!apRAXAIR An expkmtJtion of thtJ ttJrms USlld hllrllin l71tJy bll found in OSHA 29 CFR 1910.1200, tJwi/tJblll from OSHA rllgiontJl or IIr. officIIs. IEssentJel1y slmiler to US Department of Labor Form OMS No. 1218-00721 Do Not Dupllcat. Thle Form. Requ..t IIn Origlnlll. o PRODUCT Oxygen (Cryogenic Liquid) CHEMICAL Oxygen SYNONYMS Not applicable NAME FORMULA O2 CHEMICAL Not applicable FAMILY MOLECULAR 32.00 WEIGHT TRADE NAME Oxygen Liquid For mixtures of this product request the respective component Material Safety Data sheets. See Section IX. MATERIAL (CAS NO.) Oxygen (7782-44-7) Wt(%) 100 1992-1993 ACGIH TLV-TWA (OSHA-PEL) None currently established (None currently established) BOILING POINT, 760 mm. Hg -183°C (-297.4°F) FREEZING POINT -218.4°C (-361.1 OF) SPECIFIC GRAVITY (H20 = 1) 1.141 @ -183°C VAPOR PRESSURE AT 20°C. Gas VAPOR DENSITY (air = 1) 1.105 @ 25°C SOLUBILITY IN Not applicable WATER, % by wt. PERCENT VOLATILES 100 EVAPORATION RATE High BY VOLUME (Butyl acetate = 1) i r ¡ , ¡ t I r ,I ¡ ¡ . I APPEARANCE AND ODOR Light blue cryogenic liquid, odorless. IN CASE OF EMERGENCIES involving this material, further information is available at all times: Call CHEMTREC 800-424-9300 only in the event of chemical emergencies involving a spill, leak, fire, exposure or accident involving chemicals. For routine information contact your supplier. c . ,... M <C qo I .... This product is subject to the Pennsylvania Worker and Community Right-To-Know Act (35 P.S. Sections 7301-7320). Praxair requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product. and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. PRAXAIR. INC. Printed on recycled paper. Copyright ~ 1992 Praxair Technology, Inc. o Pegs 1 of 4 ~. e PRODUCT: Oxygen (Cryogenic liquid) e L-4637-D December 1992 THRESHOLD LIMIT VALUE: See Section II. --. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWAUOWING-Severe frostbite may result from contact with liquid. No harmful effects expected from vapor. SKIN ABSORPTION-No evidence of adverse effects from available information. INHALATION-Breathing 80% or more oxygen at atmospheric pressure for more than a few hours may cause nasal stuffiness, cough, sore throat, chest pain and breathing difficulty. Breathing oxygen at higher pressure increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause lung damage and also central nervous system effects resulting in dizziness, poor coordination, tingling sensation, visual and hearing disturbances, muscular twitching, unconsciousness and convulsions. Breathing oxygen under pressure may cause prolongation of adaptation to darkness and reduced peripheral vision. SKIN CONTACT -liquid may cause sèvere frostbite. No harmful effects expected from vapor. EYE CONTACT - Liquid may cause severe frostbite. No harmful effects expected from vapor. . .. . . . EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: See -Notes to Physician.- , MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: See -Notes to Physician.- SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EVALUATION: None currently known. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING- This product is a gas at normal temperature and pressure. SKIN-For exposure to liquid, immediately warm frostbite area with warm water (not to exceed 105°F). Remove and thoroughly air contaminated clothing. In case of massive exposure, remove clothing while showering with warm water. Call a physician..'" ;..: INHALATION-Remove to fresh air. Give artificial respiration if not breathing. Keep victim warm and at rest. Call a physician., , EYES-In the case of splash contamination, immediately flush eyes with w'äter for at least 15 minutes. See a physician, preferably an ophthalmologist, immediately. NOTES TO PHYSICIAN: Supportive treatment should include immediate sedation, anti-convulsive therapy if needed, and rest. Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, increases the susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate that vitamin E deficiency may increase susceptibility to oxygen toxicity. Airway obstruction during high oxygen tension may cause alveolar collapse following absorption of the oxygen. Similarly, occlusion of the eustachian tubes may cause retraction of the eardrum and obstruction of the paranasal sinuses may produce "'vacuum-type" headache. Newborn premature infants exposed to high oxygen concentrations may suffer delayed retinal damage which can progress to retinal detachment and blindness (retrolental fibroplasia). Retinal damage can also occur in adults exposed to 100% oxygen under greater than atmospheric pressure, particularly in individuals whose retinal circulation has been previously compromised. All individuals exposed for long periods to oxygen at high pressure and all who exhibit overt oxygen toxicity should have ophthalmologic examinations. Page 2 of 4 " )., , . ... . - f '1 ~j o· 1 " ¡ " \ ; ./ ,'}.- PRODUCT: Oxygen (Cryogenic .d) e L-4637-D December 1992 FLASH POINT (test method) FLAMMABLE LIMITS IN AIR, % by volume Not applicable AUTOIGNITION TEMPERATURE· Not applicable LOWER Not applicable UPPER Not applicable EXTINGUISHING MEDIA: Oxidizing agent. Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (i.e. safety shower) is the preferred extinguishing media for clothing fires. , , j j ~ SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately cool containers with water spray from maximum distance until cool, then move containers away from fire if without risk. Do not dis~harge water sprays into liquid oxygen. . '-. UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxidizing agent, vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion. Closed container may rupture due to heat of fire. Liquid oxygen will freeze water rapidly. Containers are provided with pressure relief devices that are designed to vent the contents when they are exposed to elevated temperatures. Do not walk on or roll equipment over spill as this could cause explosion. Liquid causes cryogenic -burns" (frostbite-like injury; see Section IV). Smoking, flames and electric sparks in the presence of enriched oxygen atmospheres are potential explosion hazards. :¡:¡:::::¡¡¡¡¡:¡¡¡¡¡¡¡¡~~¡:¡I¡:¡~¡¡¡¡:¡:¡~¡;ì~~~¡¡J¡®¡::::®¡¡¡¡:¡:::¡::¡~M¡~:¡:¡t:ll::m¡¡¡¡::¡¡1¡¡¡¡¡:¡¡i¡¡¡¡::~¡:¡¡m¡¡¡:¡¡¡¡:::¡¡¡i¡¡¡¡¡:¡¡¡¡¡¡í:¡¡VìI¡¡ãËÃCTim¥tDÃTI®~~:¡@¡¡m¡*~¡:¡~0i:¡::¡¡:¡::¡:¡¡:¡¡¡¡¡¡:¡:¡i¡¡;:¡Iii¡i~:í¡ii¡¡::¡¡¡¡iiii::¡¡:I¡i¡mi¡¡ií¡¡~¡N¡¡;l¡¡¡¡~~;¡¡íí:~::i:::~¡*í¡~j¡¡¡;ì¡í¡¡~ :::;::::::::~.:::::::::~:::::::::x:::::.:::~~~;::::-~:::~x::::.::æ.::~:~:;:::ii~:~::::::;::W::::::~~:::::=;~:::::::".::;~::::~~~::~::;::::::::::~:::~::~i:::~:~~::::~:*:::=::~:j:i::>:::;;:::>:::;:·;::;·:;~:::;~:~;:i;::::::~::~:::::~:i::;::::~:~::::~~~:::;:::::::::~::.:;:::~::::;;::::::~~~~:;:;;:;:::~~:::~::~:?-::ø:::·:::;:;:=::::::~:::::::;:::::~::::~~:::::::::~~~:=:::?~::~:::::::::::::::::::::;:::::~=*::.::::.::::~';~:;:::;::~:::,?*::::~~::::::~~:::::::~~ STABILITY CONDITIONS TO AVOID: Heat (see Section IXI. Oxygen reacts with many materials. Refer to NFPA 491 M -Manual of Hazardous Chemical Reactions. " UNSTABLE STABLE - .' X INCOMPATIBILITY (materials to avoid): Flammable combustible materials, especially oils and greases, including many materials not normally considered flammable. ' HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POL YMERIZA TION CONDITIONS TO AVOID: None currently known. May Occur Will not occur X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Immediately evacuate all personnel from danger area. Extremely cold oxidizing liquid and gas. Allow spilled liquid to evaporate. Do not walk on or roll equipment over spill as this could cause explosion. Contact with flammable materials may cause fire or explosion. Shut off leak if without risk. Ventilate area of leak or move leaking container to ventilated area. WASTE DISPOSAL METHOD: Keep personnel away. liquid oxygen should be dumped into an outdoor pit filled with clean, grease-free and oil-free gravel, it will safely evaporate. Page 3 of 4 ...,.....' '... '. e e PRODUCT: Oxygen (Cryogenic Liquid) L-4637-D December 1992 ¡li¡lr1~i~¡:lili¡!¡_1¡~lil']¡¡¡¡I¡¡lllilillr~I¡¡I¡I!!Jlt!§lli¡¡liiiiilili!lllll:alllllirt¡¡I¡¡ii¡IIII¡¡¡¡¡¡!¡I:¡¡I¡¡¡r~¡:I¡!¡:!rr¡[jIS]11111f:1 RESPIRATORY PROTECTION (specify type): Not required. However, air-supplied respirators are required while working in confined spaces with this product. The respiratory protection use must conform with OSHA rules as specified in 29 CFR 1910.134. LOCAL EXHAUST-Use local exhaust system, if necessary, to prevent the build up of oxygen concentration. VENTILATION MECHANICAL (general) - Adequate SPECIAL-Not applicable OTHER-Not applicable PROTECTIVE GLOVES: Loose-fitting cryogenic gloves. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EOUIPMENT: Metatarsal shoes for cylinder handling. Protective clothing where needed. Cuffless ,trousers should be worn outside the shoes. High top shoes are preferred. Select in accordance with OSHA 29 CFR 1910.132and 1910.133. ' Extremely cold 'oxidizingliqüid -and gas. Vigorously accelerates combüStion. Contact with liquid or 'cold gas causes severe frostbite. Combustibles with liquid oxygen may explode on ignition or contact. Keep oil, grease and combustibles away. Use only with equipment conditioned for oxygen service. Use piping and equipment adequately designed to withstand the pressures and temperatures to be encountered. Do not get liquid in eyes, on skin or clothing. Store and use with adequate ventilation. Close valve when not in use and when empty. Clothing exposed to oxygen should be removed immediately and aired out to reduce the likelihood of an engulfing fire. Ignition sources, such as static electricity generated in clothing by walking, etc., should be prevented. Protect container against physical damage. Isolate from combustible gas installations and combustible materials by adequate distance or by gas·tight, fire-resistive barriers. Protect against overheating. Depending upon the end use of this product, additional toxic fumes and gases may be generated. Consult an Industrial Hygienist or other trained person to evaluate such operations and for employee protection measures. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the final product. Remember, gases and liquids have properties which can cause serious injury or death. Be sure to read and understand all labels and other instructions supplied with all containers of this product. NOTE: Compatibility with plastics should be confirmed prior to use. For safety information on general handling of compressed gas cylinders, obtain a copy of pamphlet P-1, ·Safe Handling of Compressed Gas in Containers,· pamphlet P-12, ·Safe Handling of Cryogenic Liquids, " and pamphlet G-4, "Oxygen," from the Compressed Gas Association, Inc., 1 725 Jefferson Davis Highway, Suite 1004, Arlington, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: For storage and use a consumer sites, refer to NFPA 50, uBulk Oxygen Systems, .. and NFP A 51, ·Oxygen-Fuel Gas System for Welding, Cutting and Allied Processes, . available from National Fire Protection Association, Batterymarch Park, Quincy, MA 02269, Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. Never lubricate oxygen valves, regulators, etc., with any combustible substance. The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Praxair, Inc., it is the user's obligation to determine the conditions of safe use of the product. kf£fffilPRAXAIR GENERAL OFFICES Praxair. Inc. 39 Old Ridgebury Road Danbury, CT 06810-5113 Page 4 of 4 Printed in USA ..../ ) 1 ¡ f t I f 1 , i Of