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J ~lSc>r'ft\<Jo~ - I c!611-~I"\I:t) I' 0 .!:-7Prt.-> \\.1 ~':"'.~" 9\I'(If\"¡''x U-'1 2~OP ~tAL A. ~~lq, t '-J$1(r' ~a \ , _ ~Wu LoJS1t"r Z15 - ' ... , i- 1 ~) \, ir.~, 'Vi'(I'J~ t ~f .. ' S vC'\')J\ ,-' C2 7'~ ) ~: ,.~,..I: ~,,~ .;/ :I:-ô f!)?~ - ,.;to GlAL.o , ' Ili8ß - J40 .\., , ~; l- '. - . . " . . to. .:.øl ......t : i ~t . 1 ' , - -. --. .- 2.7...0 ~I~ "2. &. 20 ~l.- . ' ~ß~ woo ~"")-t.. .\XI,·. "\",f" '''16» ~ Ißol"lf\.... 'lc, . ;;)l~ \ ~ )'iC:) - or Nf'.cC ,tJ:? '30 .c- I ~ '-> ::u... '~1c" - (p" ~8a - 12.0 ¡-f ,ß o· 30\ (rI") . b.L~, ~I~ 'II'\COC'C\~;~-:' @. ~(t!)'i, NO I I' or .'p~, ,~~,~~'" }'On((li\'\\)J.:5'i~ P'^(.\.\.~~..", ~ .'". t t '\3 , I' . , ; + ! I' 1 ; ~~~ 5 ;;)50 In( H-"'" .. "'" "'" .~'.''''J . ..: J r~·t ... -..#" ~....-=-"" - 'a. ." [l.;,.~ I" . "I ~ ~J. L"~\J;~ :'.: !"..:' ' "·4:'1.1-"-:. 'I \., MEMO FROM: J Ralph E. Huey ~B'~ I 5ø-db a&ß fA _ ct ~~ ~ I~~~'··, J ~~. _,.'J)~~ ~~ -- ~ ~ ~ - W\. t1 ~ ~ , P.S. ;;f ~ II~ J)~ oL ¡,. ~/ ì I RCt1~hl i4~ dœsr\ !t ~f\è S'~ As~ \'D~cv~ . tto~~ Å~\~ d.oe5 ~'5~ CÀ/\ ¡vt ·SDS. M. J Sí ~ fèpo 11, 1- -t o¡-[ '. ~ 1'~verH1>~ <I' - '. ,Vi ' /:'r\ 1\ re '\ 0 VI, \; \-.....-- \JL ,~(l . ¡;- _'f ..,)(0 : ¡\\.Y(: 1"\ '. (' (j '~0 " ~ ATOCHEM NORTH AMERICA etf aqultalne ~~ "'=<:'~ u JERALD "JERRY" ACHTERBERG Southern Regional Sales & Service Central California DEcca Atochem North America, Inc, 1525 E, Noble #300, Visalia, CA 93277 4330 Wible Road, Bakersfield, CA 93313 Bakersfield: (805) 397-1087 FAX (805) 397-0813 Visalia (209) 636-1362 FAX: (209) 636-1364 Home: (209) 562,4722 Car: (209) 246-5163 Voice Mail (800) 533-5552 Box 8695 -' .,èf, [r:=-c:--====----==-=--·:' -,'" ~ ¡ J i i ! I I I ::\ ¡ I I \ lL' -, __ . ~ð...-/I,-:~3ð . ¿WI", .'.. / 1 , " BAKERSFIELD CITY FIRE DEPARTMENT HAZARDOUS MATERIALS DIVISION 2130 "G" STREET BAKERSFIELD, CA. 93301 (805) 326-3979 ~ECE'VED ,MAY} 1 .1:1:tJ. HAZA"DeUI UATElitlALS HA7 ~...fAT. "'V. [ FACILITY IESC"I,.TI_" :. __I ~C+-1ECK IF BlISINESS-IS_AJ:ABM [] 5'7 /7 $eutc!Q/¡cJ ~-. BUSINESS NAME £1£ ~('.A'en,f)~r-:,.,~~ -~~t> led ·pa-f¡er&1lì- -.- - , I ' I FACIL.lTY NAME \ SITE ADDRESS '-/.330 úJ ¡lIe ß ad CITY BiJ(e~º1~~_ STATE C-a.I." ç . ZIP q3~l.3 NATURE OF BUSINESS Fruì.:.. <:I- ~<ò~ A-oress -.J:Eefl~.s SiC CODE 2.87 c¡ DUN & BFiADSTREET NUMBER ÒO - ~~q - 077 ?J -- OWNER/OPERATOR ~ Ai-?te-Ae;n ß-ÐìO L;)..f) PHONE gJR 3Sg 183R I MAILING ADDRESS ~ð ICilY ty1 0 rJ OH) : ~ ST ïE C~ 1 r t. ð r/IJ Î .3 ZIP 91 ðll..o II' r ' EMERGENCY CONTACTS I NAME _G~L~J.nL£ëi.:l±.e.r:)ðN _____ TITLE &'uc. Q-e-(?reseNhfl'Jf!- I BUSINESS PHO~~E $QS..397 109 2----, 24-HOUR PHONE 8òs 831 I k>17 I I r--JAM E _11./r k_~iorry'l cs BUSINESS PHONE g-ðS- 3e>¡7 "l () g 7 TITLE ~Jc.. &prc.J eN +- ¡;¡ f-Al{('" , 24-HOUR PHONE?<¡ß-- ~.32- fo~ ò:¿ "- ~ "":jrf(Orrh"( :.'111 .~ REGION V LEP<.:; ST ANQARO F<!'<r¡, -- -J- 1,/ - - //<BAKrEHi6f-u=la- crrv FIRE DE.PAt·f~IEN i / HAZARDOUf MATERIALS INVENTORY JSi)€SS Name £/ ~ ¡fIøo¡é!1Y1 ~ ~eCð ! Address -9'33ð ¿J,.. (' I , 1- Chemicat"Name: 3) DOT.II (optional) Fire [ ] I CHEMICAL DES Revision [ I Dele1n [ , I I PHYSICAL I Reactive 1><1 Sudden Release of Pressure [ ] (3-digit code from DHS Fbrm 8022) , I TRADE SECRET [ I 1) INVENTORY STATIJS: 2) Common Name: "'. AHM [ ] CAS # 7 ft:,RI- s-¿ - Cf. 4) PHYSICAL & HEALTH HAZARD CATEGORIES HEALTH Immediate Health (Acute) Delayed Health (Chronic) ( ] Radioactive ( ] 5) WASTE CLASSIFICATION USE CODE I 6) PHYSlèAL STATE Solid [ ] Uquid þ4 Gas [ ) Pure ) Mixture ~] Waste [ ) Q-IEQC AU. F'HAr APPlY -7) AiviOltiNïANDTIMEAT FACIUTY Maximum Daily Amount: Average Daily Amount: Annual Amount Largest Size Container: _ Days On Site J./'fD 2ÁD '7L.¡ðb .5"'2... ,-.æf..{>. , UNiTS OF MEASURE Ibs [ ) gal ~ ft3 [ ] curies [ ] 8) STORAGE CODES a) Container: 0 7 b) Pressure: I c) Temperature: '¥ Circle Which Months: M. A. M. J. J. A. S. O. N, D 9) MIXTURE: Ust the three most hazardous chemical components or any AHM components 1) (2..5" 010 I s: COMPONENT t'I rll ,... U-W'Z I I II,;' c h£,r-lie CAS # %WT J 2. c;;- AHM [ I [ I [ ] 2) 1 0) Location CeJ =tf at w;¡. Check if chemical is a NON TRADE SECRET [] TRADE SECRET [ ] 3) 1) INVENTORY STATUS: New [ ] Addition [ ] Revision [ ) 2) Common Name: 3) DOT # (optional) Chemical Name', AHM ( 1 CAS # 4) PHYSICAL & HEALTH HAZARD CATEGORIES Fire [ ) PHYSICAL I Reactive [) Sudden R~lease of Pressure [ 1 '- -~'--- -+ - ----'"-- - (3-digit code from DHS ,Form 8022) Liquid {1 Gas (1 I HEALTH Immediate Health (Acute) [) Delayed Health (Chronic) ( ] Ii 5) WASTE CLASSIFICATION I I ---- -- ^.--, -.-.,..-.." --~ - --- - USE CODE 6) PHYSICAL STATE Solid { I Purl! I Mixture {1 Waste { I Radioactive { ] CHEClCAU. T'HAr APPly ! , ! 3) 8) STORAGE CODES a) Container: b) Pressure: c) Temperature: I Circle Which Months: All Year, J. F, M. A. M. J, J. A. S. 0, N, D I COMPONENT CAS # I I I I UNITS OF MEASURE Ibs [ ) gal [) ft3 [ ) curies [ ] 7) AMOUNT AND TIME AT FACIUTY Maximum Daily Amount: Average Daily Amount: Annual Amount: Largest Size Container: # Days On Site 9) MIXTURE: Ust the three most hazardous 1) chemical components or any AHM components 2) %WT AHM [ ] [ I I I 10) Location :..or_c.3Q '88l "f.QlCN'I \..P'(;.""~"G''' FIRE DEPARTMENT S, D, JOHNSON FIRE CHIEF Jerald Achterberg Elf-Atochem Decco 1525 E. Nobel #300 Visalia, CA 93277 Jerry: ,It e 2101 H STREET BAKERSFIELD, 93301 326·3911 We have deleted the calcium hypochlorite from the hazardous materials inventory for the Wible Rd. facility. I conducted the follow up inspection today to verify the inventory changes. You will need to use the enclosed form to add the 12.5% sodium hypochlorite to the haz mat inventory. CITY of BAKERSFIELD "WE CARE" April 1, 1993 . Please complete the inventory addition and return the completed form to me by May 1, 1993. cc: Ralph Huey Sincerely, C-2 (\~_~. 0' or--..' ~ ~ .,,:....y...>-\~ ~ ~,I ''----·cr Barbara Brenner Hazardous Materials Planning Technician e e , 'mt~'" f[ij;~,~~ (~~, -y=v,\~ \,,~, l, \ " " ~ ;)' , "-'-~41~~";;f(Ó; ~.!:-ºß-, ------- CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S D ,IOHNSON FIRE CHIEF April 1, 1993 2101 H STREET BAKERSFIELD, 93301 326-3911 ,., Jerald Achterberg Elf-Atochem Decco 1525 E. Nobel #300 Visalia, CA 93277 Jerry: We have deleted the calcium hypochlorite from the hazardous materials inventory for the Wible Rd. facility. I conducted the follow up inspection today to verify the inventory changes. You will need to use the enclosed form to add the 12.5% sodium hypochlorite to the haz mat inventory. Please complete the inventory addition and return the completed form to me by May 1,1993. Sincerely, ~' - '~) '-----, --~' (\ <- ¿) ",' I~'),::':-Q^-- .....,~) ':_ '-'-.r'--cr Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey ~ "' ~ e e CITY ATIORNEY LAWRENCE M. LUNARDINI CITY OF BAKERSFIELD OFFICE OF THE CITY ATIORNEY 1501 TRUXTUN AVENUE BAKERSFIELD. CA. 93301 PH. 805-326-3721 FAX 805-325-9162 ASSISTANT CITY ATIORNEYS ROBERT M. SHERFY ALAN D. DANIEL LOUISE T. CLOSS JOHN D. CLOSS LAURA C. MARINO DEPUTY CITY ATIORNEYS ALLEN M. SHAW WALTER H. PORR JR. MICHAEL G. ALLFORD r ADMINISTRATOR FRANCES E. THOMPSON !-ilarch 1, 1993 Re: Violations of Uniform Fire Code RE.GE.\'JE.O ~M\ {) 2 \qq") ~A^1" 0\\1· HAl.. WI 1"\ , . Hr. Jerald Achterberg Autochem 1525 E. Noble, Ste. 300 Visalia, CA 93277 Dear Mr. Achterberg: It has come to the attention of this office that your facility locateà at 4330 Wible Road in Bakersfield, California, is in violation of section 80.306 of the 1991 Uniform Fire Code in that more than 20 pounds of 65 percent calcium hypochlorite, a Class 3 oxidizer, is stored there. The specific violation and code section related thereto, as ~ell as the remedial action necessary to correct the violation has been detailed to you in correspondence by Ms. Barbara Brenner, Hazardous Materials Planning Technician of the City of Bakersfield, dated February 23, 1993. The purpose of this letter is to further impress upon you the need to take immediate remedial action. With that goal in mind, I must inform you that failure to correct this violation before March 23, 1993~ may necessitate legal action, including, but not limited tOf misdemeanor citations anà/or injunctive relief. (' ~ .' ~~ e e Mr. Jerald Achterberg Autochem Re: Violations of Uniform Fire Code March 1, 1993 I thank you in advance for your anticipated cooperation and, should you have any questions concerning the necessary remedial action or require further information, please contact Barbara Brenner directly at (805) 326-3979. Very truly yours, -1~d6 ~ MICHAEL G. ALL FORD Deputy City Attorney cc: Barbara Brenner, Hazardous Materials Dept. NGA: gp I'.zRDSMAT\!CHTERBERG. LTR ¢ elf atochem ~ e , RECE\VED MAR' 7 '\993. HAZ. Ml~ T. ow. e IJEI:I:C ELF ATOCHEM NORTH AMERICA, INC, 1525 E. Noble #300, Visalia, California 93277 Tel: (209) 636-1362, Fax: (209) 636-1364 Michael G. Allford, Deputy City Attorney 1501 Truxtun Avenue Bakersfield, California 93301 March 11, 1993 Barbara Brenner, Hazardous Material Technican 2130 "G" St. Bakersfield Fire Department Bakersfield, California 93301 This letter is to advise you that Elf Atochem Decco has deleted / remove from it's inventory, calcium hypochlorite, a Class 3 oxidizer, that was stored at our warehouse, at 4330 Wible Road. Attached is the hazardous materials inventory form as was requested'by Barbara, showi~g the deletion of storage of Calcium hypochlorite. c.o. Robert Johnson Gary Leary Sincerely ~V-¡ ()cA/-~1 Jer~'¡ Achterberg ~ Area Sales & Service .:::-----. o Farm and Agriculture Q stand~rd Business CITY OF BAKERSFIELD HAZARDOUS MATERIALS INVENTORY "> :- Page_of -.-!..:- NON - TRADE SECRET BUSINESS NAME: LOCATION: CITY, ZIP: PHONE I: Elf Atochem - Decco OWNER NAME: Elf'.Aquitaine - Atochem 4330 Wible Road ADDRESS: P.O.· Box 120 Bakersfield. Ca. 93313CITY, ZIP: Monrovia. Ca. 91016 805 - 397 - 1 087 PHONE f: 8 1 8 - 358 - 1838 NAME OF THIS FACILITY: DECCO STANDARD IND. CLASS CODE: 2879 DUN AND BRADSTREET NUMBER/FEDERAL ID f Q. º - ~ g -ª - º Z J _3 1 6 REFER TO INSTRUCTIONS FOR PROPER CODES 7 8 9 10 11 12 /I Days Cont Cont Cont Use Location Where on site Press Temp Code Stored in Facilit Physical and Health Hazard (Check all that apply) e Fire Hazard 0 Sudden Release of Pressure C.A.S. Number Component /I 1 Name & 14 Name,s of Mixture/Components See Instructions Calcium H ochorite 7778-543 Calcium Hypochorite -05 .r,-'! or i ne IXl Reactivity 0 IDD1Iediate 0 Delayed Health Health Component /I 2 Name & C.A.S. Component /I 3 Name & C.A.S. Number Physical and Health Hazard C.A.S. Number (Check all that apply) o Fire Hazard 0 Sudden Release 0 Reactivity 0 IDD1Iediate 0 Delayed of Pressure Health Health Component II 1 Name & C.A.S. Number Component /I 2 Name & C.A.S. Number Component /I 3 Name & C.A.S. Number Physical and Health Hazard (Check all that apply) C! Fire Hazard 0 Sudden Release o Reactivity 0 IlIDDediate 0 Delayed of Pressure Health Health C.A.S. Number Component II 1 Name & C.A.S. Number Component /I 2 Name & C.A.S. Number Component II 3 Name & C.A.S. Number Physical and Health Hazard C.A.S. Number ,,' (Check all that apply) o Fire Hazard Q Sudden Release 0 Reactivity 0 IlIDDediate 0 Delayed of Pressure Health Health Component /I 1 Name & C.A.S. Number Component It 2 Name & C.A.S. Number Component It 3 Name & C.A.S. Number EMERGENCY CONTACTS Ii Gerald Patterson Name Service Rep. Title 831-7617 24 Hr. Phone '2 Kirk Storms Name Service Rep.832~6§02_ Title 24 Hr Phone , Certification (READ AND SIGN AFTER COMPLETING ALL SECTIONS) Ì-c~tifY under peanlty of law that I haver personally examined and am familiar with the information eubmitted in this and individ~~tls responsible for obtaining the information. I believe that the submitted information is true, accurate, and ;4 " '~, '-- 11 attached documents and that ,based on my inquiry of those plete. 1/~ /c2, 19'93 DATE SIGNEDI ' e e . ! CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S, D, JOHNSON FIRE CHIEF February 23, 1993 2101 H STREET BAKERSFIELD, 93301 326-3911 Mr. Jera1d Achterberg: NOTICE OF VIOLATION AND SCHEDULE FOR COMPLIANCE ----------------------------------------------- ----------------------------------------------- The storage of more than 20 pounds of 65% calcium hypochlorite, a class 3 oxidizer, in Atochem's B-2 occupancy warehouse located at 4330 Wible Road, Bakersfield, CA is a violation of the Uriiform Fire Code. VIOLATION OF UFC aO.306 (a) Indoor storage. 2. Exempt amounts. When the amount of liquid and solid oxidizers stored in one control area exceeds that specified in Table No. aO.306-A, such storage shall be within a room or building conforming to the Building Code requirements for the following occupancies: Oxidizer Class Occupancy Group Class 4 H-1 Class 3 H-2 Class 1 and Class 2 H-3 This violation must be corrected by March 23, 1993. Failure to correct this violation will result in enforcement action. The department will schedule a re-inspection of your facility to verify compliance. If you have any questions regarding this notice, please contact me at 326-3979. Sincerely, ~~~r~ ~~~ Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey, Hazardous Materials Coordinat~r Michael Allford, Deputy City Attorney e e February 23, 1993 ~(%) - f-- 3 - ;)3 lÍ/ o ~H..52 CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S, D JOHNSON FIRE CHIEF 2101 H STREET BAKERSFIELD, 93301 326-3911 NOTICE OF VIOLATION AND SCHEDULE FOR COMPLIANC Mr. Jerald Achterberg: -------------------------------------.---------- ------- ------------------------------..---- ------ The storage of more than 20 pounds of 65% calcium hypochlorite, a class 3 oxidizer, in Atochem's B-2 occupancy warehouse located at 4330 Wible Road, Bakersfield, CA is a violation of the Uniform Fire Code. VIOLATION OF UFC 80.306 (a) Indoor storage. 2. Exempt amounts. When the amount of liquid and solid oxidizers stored in one control area exceeds that specified in Table No. 80.306-A, such storage shall be within a room or building conforming to the Building Code requirements for the following occupancies: Oxidizer Class Occupancy Group Class 4 H-1 Class 3 H-2 Class 1 and Class 2 H-3 This violation must be corrected by March 23, 1993. Failure to correct this violation will result in enforcement action. The department will schedule a re-inspection of your facility to verify compliance. If you have any questions regarding this notice, please contact me at 326-3979. Sincerely, ~~~r~ ~~~ Barbara Brenner ' Hazardous Materials Planning Technician cc: Ralph Huey, Hazardous Materials Coordinator Michael Allford, Deputy City Attorney e . , CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S, D, JOHNSON FIRE CHIEF December 15, 1992 2101 H STREET BAKERSFIELD, 93301 326·3911 ., Keith Uyekawa Core-Rosion Products P.O. Box 8652 Long Beach, CA 90808 Keith: The fire sprinkler and secondary containment system outlined in your letter dated 12-11-92 for the Elf-Atochem toxic gas storage container meet the intent of Article 80 of the Uniform Fire Code. It will be necessary for the sprinkler contractor performing installation to supply calculations to the Building Department which verify the adequacy of water flow once the additional heads have been added to the existing system. Please contact Jeff Bryson at (805) 326-3727 if you have questions regarding the type of information required for approval of this addition to the building's sprinkler system. Please give me a call if I can be of further assistance. Sincerely, ~~OA-~ ~~( Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Jeff Bryson Jerry Achterberg ,~. l~ #.~ -,,- - DEC-11-92 FRI 1~:39 ,~- ~ e p _ ø 1 ,r'--/Z L._~' ~ ì~ / ,r-V¡~ :[3) f2 ::"',; ((~(à (Q\ n 11 ~ A ) » '~¿J\:d!Ln:l bc:Jí'!~~UYU~ ~ ÞIMess fqufpmø¡;~ ij, En vlronmenfal Products ,;;r"\., ., , ..~ ) ,,~ /' /' <f.'-..> /' ~, ~ ,,0 , RECEIVED OfC 1 4 1992 December llq 1992 HAT MAT. OIV. City of Bakersfield Bakersfield city Fire D2T~.. '_~ Hazardous Materials Di '\':~': ,:;;' 2130 UlG70 street Bakersfiel&u CA 9~3ûL (SOS) 3?6=39i-9 FAX (BC':", ':;49 , ,\. Ât.tG~:t:..:.(." c;('xbara JBreL' JRêfen,:'),¡Ç.l-'~ "':,.f At.ochént Deccc P:;,oject Dear Be:.?,'baJr& ~ I wo:..Úò! like to address your preliminary review dated Sê¡p\celtl~Ç. 1992 in regards to water sprinkler system and the B-8~,;' CÖ¡¡~:t.ai111ment IOn our relocatable building 0 As per your :rceqè,jì:'.: the code states the capacity of 'the floor sump or §~:: containment shall be designed to retain the laßges~ cçnta:hH~1t q plus 'the flow rates of 'the. automatic s¡prinkL~:,,: lEOK' Bl perioQl of 20 minu:tesa The sump capacity on our ;~ bui~ding is 198 gallonsa 1ès per NFPA 13 sprinkler heads inside a build.ing shou1d ,;..c ~ ~o~t~ut of .35 gallons per minute P$~ s~~are foot- w~ich &~ß~¡~~ ß~e.t[/ A(\V 21 gallons pel" minute by design a P!e¿::,38 ::-:-2t:.:a 'i:.:~é:"(:- '1';.ì:1.e g¡Õl:lc~,g :~$1C '~I\-t~ 1!l'¡hti,:::te varies by system hooked-up tð , oC:" C ?', .,0:".J~::, ,Pc; ", (~~ëm is 8\, !Cir&nch \'0 1 i\.ne of the one that it. is hooked .i."'<~. -::" '?:':c:':':,. Toy desJ_çl, \GlUt' ~~\ -t . ~ump capacity is rat.ed for aPP,~,~x.lma~eJ.Y :1 mi~r¡:~~téS"' OR' ~~:(~~:~ì. in ~Þs(ì ~. 7L~H1aILds to contairJnng asp!....'" 0,,- ,oC. ___,.,"gest Co.,L(D' Jl.ner _ ~ rJ apprQ1d:mð.tély 55 gallons 0 As per our t.e:>;':G<n.<l~:.:ç; convérsa-(e.im¡ this , \~ V?--( Kecp..Ü ir-(Ç,ltì$nt of séco::lda:rry cont.a inment may be we.:i..ved on this bUli:lcling O'V',~ · due co 'tnG:! fe.ct t;h,at the permanent inst~llat1on would be iL:n an '\' \.> axistJ1.ng s'itr~J,t;t.U:rrê wh~>'Ch currently has water sprinkle:rt syst,.~)::8\ 0 cW,O¡V'L> 2 '~v~ter sprinkler:. sy~t~nì1 is .r:-,:,:~:-oved for 'this in5'tb~~u_:";'üi:,) rz-.,Ó 'ì,·~,:t.~'An\:1e1Ç ~]_f Atocn¿~(\ !J:;;;t~;(';O WJ, :~rced 'to install êt d::'::jÎ :":::10m , _ ,:-,[' ~'it a '>:\'I\wh aóìdlç:r ':;C1se 0 ~or the ma111ufa.c'tUìfeIL ot: 'd~ê /,:>,_µ,~j ,10116 bt'.:U,ç '¡.hq~8 'Îd!,é..::e dry chern sys'Ít~m would 1]'W~ íP~;,~~Olt,{R 'ÌL.ö Jl'[:S f\/:::":;' '>;' ::;1 iil! 7!::'8gar(:~s 'ito a chlorine gas spill. an¿ water will h~ve å ~ 3 ~c dilute the chlorinea "~~~T ~~IF'~::~ - 1$62, "vNG BEACH, CALIFORNIA 90808 e 310·596-4113 . FAX #31 0-430-1 058 (lre1Qod, Ino. (11)3 Ç(lre-Roalon Products) ..,-f ,-~_ DEC-11-92 FF~I - 14:39 e P.02 Ci~y of Bakersfisld Bakersfield City Fire Department B&,rioara 1Br€nner December 11¡ 1992 page 2 If you could¡ please tak~ a look at this situation and give us a preliminary ruling of what your decision would be so we may g~t a building ordered and put Elf Atochem Decco in compliance with the local city and fire codeso If you have any questiQns regarding this please do not hesitate to contact me at my officec Look forward to hearing from you soon. !Beat JReg¡Õlrdl.sp '1-// '- / yJ / / j / -< )-&1/c--tí7' (-y U-rA' á..('¡;/tZ.,· Keit~ To ~yek~wa ~erri~cry Bales Manager COg Mrc Jerry Achterberg Elf Atochem Decco ~525 Eo Nobel v Suite #300 vis~lia, CA 93277 FAX (805) 397~OB13 . \. , .~\ ~(~, ~ ./ O~~,//" ,,~ ./;/ ða~ .;.' " /', K'X'U ~ j c Mrc 3ack Leonard city of Bakersfield Building Department city Hall 1501 Truxtun Avec Bakersfieldv CA 93301 (805) 326-3718 .--"' ~.--" ~ \ e e /@ œ: (¡~-i!W,ï~ ~ ~ DEe 1 6 19~2 ~ By_ f , ! Ç£~~;.~2~~2!iduct' ~ --::::::::-.- December 11, 1992 City of Bakersfield Bakersfield City Fire Department Hazardous Materials Division 2130 "G" street Bakersfield, CA 93301 (805) 326-3979 FAX (805) 395-1349 ~',~-t--- - - ---=--- Attention: Barbara Brenner Reference: Elf Atochem Decco Project Dear Barbara: I would like to address your preliminary review dated September 10, 1992 in regards to water sprinkler system and the secondary containment on our relocatable building. As per your requirements the code states. the capacity of the floor sump or secondary containment shall be designed to retain the largest single container, plus the flow rates of the automatic sprinkler system for a period of 20 minutes. The sump capacity on our proposed building is 198 gallons. As per NFPA 13 sprinkler heads inside a building should have an output of .35 gallons per minute per square foot, which results in 27 gallons per minute by design. Please note that the gallons per minute varies by system hooked-up to ours as our system is a branch line of the one that it is hooked into. Therefore, by design our sump capacity is rated for approximately 7 minutes or less in regards to containing a spill of the largest container approximately 55 gallons. As per our telephone conversation this requirement of secondary containment may be waived on this building due to the fact that the permanent installation would be in an existing structure which currently has water sprinkler systems. If a water sprinkler system is not approved for this installation my customer Elf Atochem Decco will be forced to install a dry chern system at a much added expense. Haz-Stor the manufacturer of the relocatable building believes that the dry chern system would not perform to its full potential in regards to a chlorine gas spill and water will have a chance to dilute the chlorine. POST OFFICE BOX 8652. LONG BEACH, CALIFORNIA 90808 . 310-596-4113 . FAX#310-430-1058 (Ireland, Inc. dba Core-Roslon Products) ij- í' ------.~ ~ - - --,- . t. e e City of Bakersfield Bakersfield City Fire Department Barbara Brenner December 11, 1992 Page 2 If you could, please take a look at this situation and give us a preliminary ruling of what your decision would be so we may get a building ordered and put Elf Atochem Decco in compliance with the local city and fire codes. If you have any questions regarding this please do not hesitate to contact me at my office. Look forward to hearing from you soon. Best Regards, ~--nt.'~- -- -- ----- ædc:¿,.. , --- ------ -- -------- -".-- . ~--- --- -- - - - ----- - ----. Keith T. Uyekawa Territory Sales Manager KTU:jc cc: Mr. Jerry Achterberg Elf Atochem Decco 1525 E. Nobel, suite #300 Visalia, CA 93277 FAX (805) 397-0813 Mr. Jack Leonard City of Bakersfield Building Department City Hall 1501 Truxtun Ave. Bakersfield, CA 93301 (805) 326-3718 ~' ".'. , . ' ", ~ .' . . e CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S, D, JOHNSON FIRE CHIEF September 10, 1992 2101 H STREET BAKERSFIELD, 93301 326-3911 Mr. Jerry Achterberg Elf-Atochem Decco 1525 E. Nobel #300 Visalia, CA 93277 Jerry: ..We have completed a preliminary review of the H2/7 occupancy proposed for the storage of gaseous chlorine and 65 %calcium hypochlorite at 4330 Wible Rd. Following is a list of Uniform Fire Code requirements which have either not been addressed in the plans submitted or for which additional information will be required. 1. 2. ôv.-- 5. UFC Article 80.306(a)10 requires an approved, supervised" smoke detection system to be installed in solid oxidizer storage areas. Activation of the detection systems shall sound a local alarm. If the existing fire sprinkler system is supervised, it should be possible to link the smoke detection for the new H occupancy to it. You may want to check with your landlord to find out if the existing sprinkler system is supervised. -~~ e.C(Al út\O-(fYV ~I\\"'( ,. t\i(€l ~tCJr;~ %~ \XX-\@.';) ~N'I~Sì'5 @, ~ßk\ Calculations verifying that the capacity of the floor sump complies with the requirements of UFC 80.301 (1)4 [per 80.306(a)8] will need to be submitted. Secondary containment shall be designed to retain a spill form the largest single container plus the design flow rate of the automatic sprinkler system for a period of 20 minutes. 3. The company which provides the scrubber system will need to submit a plan which certifies that the treatment system complies with UFC 80.303(a)6.D. (iii). 4, Submit specifications for the mechanical ventilation system which verify that the gas storage room will operate at a negative pressure in relation to the surrounding areas. [UFC 80.303(a)6.C(i)] 1'4eti\. V~. (OMtS 6W\. @ ~-\ 4tM? Q\.)tvíY'O=h~\l~. ~~ 1:.\ (~~û9 De.t0fSme.CV). VV1t '3-\ù\s "1~ \, w-~r tOMes Ð^ I ~e. ~C.[\JÐ'ot( ~\aJ5 ¡J,,~ r"""Q.., Standby power supply must be provided for the gas treatment system. [UFC 80.401(1)] Standby power is defined by the Uniform Electrical Code. Contact Russ Combs at the Bakersfield Building Department to discuss standby power requirements. Ü\~ :L\Ùmtí' 'S~ ~ Jpr e..w~~ CkL~~ -lV vJ\-) eft.¡ 7 ~\ 'f.-. -\0 wa~tÄ:;o-U(' ~: ?.J.fV:JiNA ;+--tv ~__ __"-----c-__ _=---_~~=.l~_---- __ _~.-_ _=-~-- ---'- _~ ~~m -$>0 0, __"--=," - , .;it-"f-,~ - --( e . Following are answers to other questions that we have discussed. 6. Per UFC 80.303, a gas detection system will not be required unless it is needed, to activate the scrubber or some other required equipment. 7. An occupancy separation will not be required for the storage of calcium hypochlorite and gaseous chlorine because these materials are of a similar hazard classification. If you wished to use part of the H2/7 occupancy for the storage of flammable liquids or other materials which are incompatible with oxidizers, an occupancy separation would be necessary. 8. A water fire extinguishing system will be acceptable. 9. If you should decide to store only the 65% calcium hypochlorite, the occupancy would not have to meet the H7 building occupancy requirements and th,e scrubbing system would not be required. Interior storage of over 40 Ibs of class 3 solid oxidizers, such as calcium hypochlorite, must b~ stored in a H2 occupancy and must comply with UFC 80.306(a). Exterior storage of class 3 solid oxidizers must be separated from other buildings, property lines and public ways by 50 feet and must comply with UFC 80.306(b). We are willing to review additional plans for scrubber systems or any other components that you may wish to submit. Please inform us of Elf-Atochem's decision to either reduce the quantity of calcium hypochlorite or submit the final plans for the H occupancy by October 9, 1992. The risk management and prevention program must be completed and submitted before storage of gaseous' chlorine is resumed. Please call me if I can be of further assistance. Sincerely, Ç)~~o«- ~~~ Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Jack Leonard ·' -- . ~ '¡; ~ 08/05/92 e e ~cc~~'¥~~ ~ SEP 9199'l.a~ B.L._._ 1 £1f- A~fY\, De-ceo ~~M~~ U S 215-000-000387 Overall Site with 1 Fac. Unit General Information Location: 4330 WIBLE RD Community: BAKERSFIELD STATION 07 Contact Name GERALD PATTERSON KIRK STORMS Map: 123 Hazard: High Grid: 13C FlU: 1 AOV: 0.0 Title SVC REPRESENTATIVE SVC REPRESENTATIVE Business Phone (805) 397-1087 x (805) 397-1087 x 24-Hour Phone (805) 831-7617 (805) 832-6602 Administrative Data Mail Addrs: 4330 WIBLE RD City: BAKERSFIELD Comm Code: 215-007 BAKERSFIELD STATION 07 D&B Number: 00-229-0773 State: CA zip: 93313- SIC Code: 2879 Owner: -A{jTeeH-E-M-N=::A:. ÐE}@GO-tJ-;-S .<¿:\.f -A-\o<:'h.:.rn .. Phone: Address: POBOX 120 ' ' State: CA City: MONROVIA Zip: 91017- Summary (ý~ ~' '~c~tI~¿ \f\~fM-Ð"i, :5hu--r ~::y~ \\e.ç~(µ'+i~ ~J' Ac.~ -t-."S '. ~.~~r 9/;v/t 1'~1 ~"l~(Le(Ó Do hereby certify that I have . (Type or MJfte) reviewed the attached hazardous materials manage- ~ent plan for f/P fI~ tM:' ~CCr) and that it along with ( wna of Buainesa) any corrections constitute a complete and correct man- agement plan for my facility. 9-r2~ 9:1.. Date e e 08/05/92 ATOCHEM N A DECCO U S 215-000-000387 02 - Fixed Containers on Site Page 2 Hazmat Inventory Detail in Reference Number Order 02-002 CALCIUM HYPOCHLORITE · Reactive, Immed Hlth, Delay Hlth Solid 500 Moderate LBS CAS :It: 7778-54-3 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: BACTERICIDE Daily Max LBS ----r-- Daily Average LBS --r-- Annual Amount LBS -- 500 I 100.00 I 1,500.00 Storage DRUM/BARREL-NONMETAL r Press T Temp ~ Location Below AmbientCENTER WEST SIDE - Conc l 65.0% Calcium Hypochlorite Components MCP ~List ;oderate I 02-003 DECCOSOL 122 CONCENTRATE · Immed Hlth, Delay Hlth Liquid 220 High GAL CAS :It: 1310-73-2 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: FUNGICIDE Daily Max GAL ----r-- Daily Average GAL --r-- Annual Amount GAL -- 220 I 220.00 I 220.00 Storage DRUM/BARREL-NONMETAL r Press T Temp ~ Below AmbientCENTER AREA Location - Conc l 7.7% Sodium Hypochlorite Components ~ MCP --,-List High 02~004 DECCOSOL 125 CONCENTRATE · Immed Hlth, Delay Hlth Liquid 240 Moderate GAL CAS :It: 1310-73-2 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: FUNGICIDE Daily Max GAL ----r--, Daily Average GAL --r-- Annual Amount GAL -- 240 120.00 I 165.00 Storage ' r Press T Temp ~ ' DRUM/BARREL-NONMETAL Below AmbientCENTER AREA Location Components Œ MCP ~List Moderate Low Conc 4.8% Sodium Hydroxide 5.0% Sodium Metasilicate e e 08/05/92 ATOCHEM N A DECCO U S 215-000-000387 02 - Fixed Containers on Site Page 3 Hazmat Inventory Detail in Reference Number Order 02-005 APL KLEEN 246 ~ Immed H1th Liquid 240 Moderate GAL CAS #: 7664-38-2 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING Daily Max GAL ~ Daily Average GAL --r-- Annual Amount GAL -- 240 I 120.00 I 720.00 Storage DRUM/BARREL-NONMETAL r Press T Temp ~ Below Ambient I CENTER AREA Location Components MCP mList mOderate Moderate Moderate Conc 50.0% 15.0% 1.5% Phosphoric Acid Sulfonic Acids Isopropyl Alcohol 02-006 DECCOSAN 315 SANITIZER ~ Immed H1th, Delay H1th Liquid 110 Low GAL CAS #: 68391-01-5 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: INSECTICIDE Daily Max GAL ~ Daily Average GAL --r-- Annual Amount GAL -- 110 I 55.00 I 165.00 Storage DRUM/BARREL-NONMETAL r Press T Temp ~ Below ,Ambient CENTER A~EA Location - Conc ~' Components 5.0%' Alkyl Dimethylbenzylammonium Chloride ~ MCP -¡List Low I 02-007 DECCOSAN 320 SANITIZER ~ Immed Hlth, Delay Hlth Liquid 110 Unrated GAL CAS #: 68391-01-5 Trade Secret: No Form: Liquid T¥pe: Mixture Days: 365 Use: INSECTICIDE ---- Daily Max GAL ~ Daily Average GAL --r-- Annual Amount GAL -- 110 ' I 55.00 I 165.00 Storage DRUM/BARREL-NONMETAL r Press T Temp ~ Below Ambient I CENTER AREA Location - Cone Components MCP --,-List e e 08/05/92' ATOCHEM N A DECCO U S 215-000-000387 02 - Fixed Containers on Site Page 4 Hazmat Inventory Detail in Reference Number Order 02-008 APL LUSTR 221 ~ Immed Hlth Liquid 2200 Moderate GAL CAS #: 67-63-0 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: PRESERVATION ---- Daily Max GAL ~ Daily Average GAL ~ Annual Amount GAL -- 2,200 I 1,100.00 I 3,200.00 Storage DRUM/BARREL-NONMETAL r Press T Temp ~ Below AmbientCENTER AREA Location Components MCP 9List ~Oderate Moderate Low Conc 20.0% 2.0% 3.0% Isopropanol Ammonium Hydroxide Morpholine 02~009 APL LUSTR 225 ~Immed Hlth Liquid 220, Moderate GAL CAS #: 67-63-0 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: PRESERVATION Daily Max GAL ~ Daily Average GAL ~ Annual Amount GAL -- 220 I 110.00 I 440.00 Storage DRUM/BARREL-NONMETAL r Press T Temp ~ Below Ambient I CENTER AREA Location Components MCP illList :Oderate Moderate Conc 8.0% 2.0% Isopropanol Ammonium Hydroxide 02-010 SPROUT NIP (VALENT) ~ Immed Hlth Liquid' 30 Moderate GAL CAS #: 94-l1-1 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: PRESERVATION Daily Max GAL ~ Daily Average GAL ~ Annual Amount GAL -- 30 15.00 I 30.00 Storage r Press T Temp -:-1 Location METAL CONTAINR-NONDRUM Below AmbientCENTER WEST WALL - Conc l 64.0% Isopropyl Alcohol Components MCP -:-TList f';oderate I e e 08/05/92 ATOCHEM N A DECCa U S 215-000-000387 02 - Fixed Containers on Site Page 5 Hazmat Inventory Detail in Reference Number Order 02-011 SODA ASH. ~ Solid 500 Low LBS CAS =It: 497-19-8 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: WATER TREATMENT Daily Max LBS ----r-- Daily Average LBS ~ Annual Amount LBS -- 500 I 200.00 I 2,500.00 Storage r Press T Temp ~ Location Below Ambient I CENTER WEST SIDE BAG - Cone l 100.0% Sodium Carbonate Components ~ MCP -¡List Low I e e 08/05/92 ATOCHEM N A DECCO U S 215-000-000387 00 - Overall ,Site Page 6 <D> Notif./Evacuation/Medica1 <1> Agency Notification EMPLOYEES ARE INSTRUCTED TO NOTIFY THE BAKERSFIELD FIRE DEPARTMENT AND THE MAIN OFFICE IN MONROVIA, IN THE EVENT OF A LEAK OR SPILL. CALL 911 <2> Employee Notif./Evacuation ~LOYF.F.C::: ARE IN5TRJTC'T'F.D TO NO'1'TFY 'PilE FIRE DErAR'fMENT AND THE M..~IN OFFICE -OFDECCO (MONROVTA Cll) TN 'T'I:IE EVEI(T OF A OPILL GR LEAK., EVACUATION IS THROUGH THE LARGE OVERHEAD DOORS WHICH ARE OPEN WHENEVER EMPLOYEES ARE IN THE WAREHOUSE. THE WAREHOUSE DOES NOT HAVE AN EMPLOYEE ASSIGNED TO STAY DURING BUSINESS HOUSE. EMPLOYEES ARE IN THE WAREHOUSE LESS THAN 3 HOURS IN A NORMAL WORK DAY. <3> Public Notif./Evacuation THE FIRE DEPARTMENT ALONG WITH THE LOCAL POLICE DEPARTMENT WILL HANDLE ALL PUBLIC NOTIFICATION, AS MAY BE REQUIRED, THOUGH PERSONEL CONTACT, OR BY WAY OF NEWS TELECAST. EVACUATION INSTRUCTIONS TO BE ISSUED AS FELT NEEDED FOR PUBLIC SAFETY, BY LOCAL AUTHORITY TYPE PERSONNEL. <4> Emergency Medical Plan BAKERSFIELD EMPLYEES ARE ON A SERVICE ROUTE, WORKING OUT OF THEIR VEHICLES. TRUCKS ARE EQUIPPED WITH 2-WAY RADIOS SO REGARDLESS OF LOCATION, HELP CAN BE IMMEDIATELY SUMMONED. ALL TRUCKS AND 2-WAY BASE OPERATORS HAVE EMERGENCY MEDICAL NUMBERS FOR THE VARIOUS , AREAS COVERED BY THE SERVICE ROUTE ;;¡ , . e e 08/05/92 ATOCHEM N A DECCO U S 215-000-000387 00 - Overall Site Page 7 <E> Mitigation/prevent/Abatemt <1> Release Prevention PAINT AND FLAMMABLE PRODUCTS ARE STORED SEPARATELY. CYLINDERS OF CHLORINE GAS ARE STORED UPRIGHT, CHAINED AND SEPARATED BY FULL OR EMPTY. STORAGE IS NEAR A LARGE DOOR TO ALLOW AIR CIRCULATION. THE CHLORINE SUPPLIER KEEPS AN EMERGENCY KIT A FOR CAPPING CYLINDERS THAT MAY DISCHARGE GAS. RESIRATORS ARE ON SIDE FOR USE IN CASE OF A GAS DISCHARGE. TRAINING IS PERFORMED YEARLY FOR SAFETY AND HANDLING. <2> Release Containment AN EMERGENCY KIT FOR CAPPING CYLINDERS IS MAINTAINED FOR LEAKING OR BROKEN VALVES. <3> Clean Up CAPPED CYLINDERS WILL BE PICKED UP BY MANUFACTURER, ALL PURE CO. (209) 297-7665 <4> Other Resource Activation g ,_ ,\ t" e e "- '. 08/05/92 ATOCHEM N A DECCO U S 215-000-000387 00 - Overall Site Page 8 <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - FRONT OF BUILDING OUTSIDE (WEST SIDE OF BUILDING) B) ELECTRICAL - INSIDE WAREHOUSE NORTH OFFICE WALL C) WATER - OUTSIDE SOUTHWEST CORNER OF BUILDINGS D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND OVERHEAD SPRINKLER SYSTEM FIRE HYDRANT - SOUTHWEST CORNER OF BUILDING <4> Building Occupancy Level , ., ," r;,- Jf::. e e ~ '~, '. 08/05/92 ATOCHEM N A DECCO U S 215-000-000387 00 - Overall Site Page 9 <G> Training <1> Page 1 WE HAVE 2 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: ;9Pî,"'/ al- If/I Rtf!>. ;he! Þo-rh ernp/0'1t'-e~ -afh.,Jd c¡Io,,~t! S;;Fè'¡7171~.e--'¡/N) I~ , #¿¡d i ðM -employeel¡ *~/:Veol ON c,J~"1'II·cõJl .$"c) Fe17 '7- 2f· 92.... · <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use j; .. CITY OF BAKERSFIELD HAZARDOUS MATERIALS INVENTORY õ' , b Farm and Agriculturel~standard Business ,j .' page1of-L' I'~,i~~~: NAME4:j~flr;Ie~[)é'CCO CITY, ZIP: ';Z3 _ -1~' :33/ ~ PHONE #: .?o53'77 /ðcP7 NON - TRADE SECRET OWERNMŒ:¿77/-;.0f~~ ADDRESS: /"0 ð..y /J-o CITY, ZIP: /J"/D,.JI'()(,//'-;¡ ,/;¡ PHONE ,t: ' g -Ý..3S9 ..r?~ ¥ 9 REFER TO INSTRUCTIONS FOR PROPER CODES ' 7 B 1/ Days Cónt on site 9/Dn NAME OF THIS'FACILITY: STANDARD IND. CLASS CODE: DUN AND BRADSTREET NUMBER/FEDERAL ID t - -- - - -- Component 1/ 2 Name & C.A.S. NUmber .;¿ 3 6 13 , by wt Physical and Health Hazard' C.A.S. Number fo7 - G:.3- D (Check all that apply) o Fire Hazard 0 Sudden Release 0 Reactivity 1&1 Immediate 0 Delayed 'of Pressure Health Health Component 1# 1 Name & C.A.S. Number ~o ,; Component 1/ 3 Name & C.A.S. Number \ ~ .; ,1 :, Physical and Health Hazard (Check all that apply) o Fire Hazard 0 Sudden Release 0 ,of Pressure C.A.S. Number Component , 1 Name & C.A.S. Number "1 ; Reactivity 0 Immediate 0 Delayed Health Health Component 1# 2 Name & C.A.S. Number Component 1# 3'Name & C.A.S. Number <:, Physical and Health Hazard C.A.S. Number ; (Check all that apply) ~ 'D Fire Hazard 0 Sudden Release 0 Reactivity 0 Immediate 0 Delayed of Pressure Health Health Component 1# 1 Name & C.A.S. Number Component' 2 Name & C.A.S. Number Component , 3 Name & C.A.S. Number -- ·c.i Physical and Health Hazard C.A.S. Number (Check all that apply) " D Fire Hazard 0 Sudden Release 0 Reactivity 0 Immediate 0 Delayed ,," ' of Pressure Health Health Component 1# 1 Name & C.A.S. Number Component II 2 Name & C.A.S. Number Component II 3 Name & C.A.S. Number {, EMERGENCY CONTACTS #1 ..s';Þ('th f: é -. ¡U~ Title g'IJ5' 3'3/ 7¿,/'7 #2 24 Hr. Phone r/Yt's .s¡.ru/èé' FYI ¡J.,-J Title 80 3~ &,6,OJ.. 24 Hr Phone Cert1!ication (READ AND SIGN AFTER COMPLETING ALL SECTIONS) I certify under peanlty ot law that I haver personally examined and am familiar with the information submitted in this and all ached documen individuals responsible for obtaining the information. I believe that the submitted information is true, accurate, and c lete\ ~r-~ ld f+c.Jthrbert¡ f)rfJ ]/e.r fYø/c't NAMB AND OFFICIAL TITLE OF OWNER/OFERATOR OR OWNER/OPJmATQR I S AUTHORIZED REPRESENTATIVE i " . and that based on my inquiry of those SI ?- ."R-/9~ DATE SIGNED ----- --------¡--:-- "'" ~ '# e e ~c!L_f(~LI/1 For :1ôû I ~p:J/1 - -~-t7fLúùlY1 +(~Ior'rt¡: I l~EI~LbecK: A~ all C(5¡2R.C!S-4 OC~~3C--ñN§ I , ci_..---CDIY1 lY1en7S ~. K~DIl~ (l) lJJKhemS_tu-Ö]J{)/15 'R. 2. : ~p_7J:O!:1J_ tÆl.v_~ rJtCtS~ ~ · for 5iD~r-Qz-~~-{~'¡J"1~Ú1~I)ocJ.,{ot;'t: r do "'~-f fond W1~_eú5()h -10 B,u;re" 1!1~ f1¿,-fd'/79 -ro b< dtVI~C i()1o 2 se.1~(ªtL6h2(~ Qr<ec¿5.. 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('iet{;;;i.ër; '{/ñ;Df\ íY'af IJoCY' SJÆf1. uJ;iJ.,~~;/1 ~"/l.¡"r óV\ ¥ IA. -t_ ~~O mi,r" ~fl 4ccAiQn -tv ~ l2ð l v ¡ytQ 1- 1!J~_to.r~LJ1ï~J-ll,Qn~ ú:Jo±a;.rtL( . . . ('Ieee! V~~CIt1íÐn N 61w'Zf (0Q¡f1, w·iL., be ul)ck (\{~ vre--. Cftu::.s~,¿: ";:;L(f4 [)eM¡la:liotLJ~ · rie.ffJ_flWl ur~f-1.d_~~ =ffu+ ~~(~'~~_uFC LornpL:aOLe_pi-: 7P-.eú-fmefJT .s~J'~-rem Q~ ðedJJ.u-Cb (JfY}U/,}--H'a-f¡&o. +0 J!L:r;o¿ff 'i_()Jf:Ie~/YlV7Í5 / {p1JLil!iS: · {)11/~ <<;TQl1db¥-?2IAd~_œðv;œd For (J5R.Ldij~5'·~~f- . 7b~tt~per 66· YO.I(J) . 5iú~Jì» a{5o f'ejU¡red HJr STð;QJe, ?--fk (g¡£¡¡}I>'L ~ch fon -to. fjpwefl<r, 8~3P 3(* ð~ ~;I'~S \~~----FWtr -ff' ÓInrû'tf- 1 Cf6e-o.;s Chlor. ne.-_. T "fI-"nK... . r}J~ r ~ jb(, ìnifñ~ ~ dbt ffid£,-9£i5 {{1(]veJLJkd wheA.- br- ~_ 1"±kc~~'LL ~4& k.fitWi5 Pe':R.r:/Iv Ûl6 'f wI Sr~ it /}n;cf¡lffL ~ ~ --10 ~ P ~~rfnl<1. . . p~ (' &30 3 (t?v 19 - GC6 J,-kúf;OI1 Mf\ 'j- be (t~v(cd un lt55 rt 'I~ ()i(17:Pé~J afilJ£lta o~1i~Æ_~Ubd' r.7 ~ ~ ,. e e I I D~ m --IhLL,q~ff'B'/I".fJ-QÇ 1b¡S_:2cr71dn 7b L{YJ7Q(fJ I ~22 t +~e.a+ ;ge. ~4~5 J_X_LJ..r2v1cL£i/7 1);-f W,:µ' .. rJ J1¡e, if) (g£l( =..;:i~~{¡¿ci -112 ~f"f., a wLocJ± fie~ v; ri 1'19- __ _ --J~pv¡)¡5R:f,---J m oKe cl._-f5£-f; D1..- ~ w;~ I ~~_75~-120cPlr. ~T])O ~DJ ~,-i'1 r:- ? 12d:l-J-_(2ii,{Qf2i: On~'flr . . I :r: IÞ-Ø__ÚZR£-f,C6.;on /fhf)(jr¡~m <-/faT -, CltN I ~_Q0r ~ tf2rn(YlU1l5~1Z.. ~ v.>;Ù/ hLCtI::1M~--±O~-XIQ~. "I'U ry¿ ~C!Ii:- 0,", ~-=3-* W( Ctrn) ell 5-5·- I ~ß a/x,07- I , I ~ ~:, e e .-~- CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S, D, JOHNSON FIRE CHIEF July 27, 1992 2101 H STREET BAKERSFIELD, 93301 326-3911 Jerry Achterberg Atochem North America, Inc. 1525 E. Nobel #300 Visalia, CA 9327-7 Jerry: Following the meeting on July 24, 1992, it is our understanding that the following schedule and conditions will apply to the correction of the occupancy type violations at Atochem's 4330 Wible Rd. storage facility. ~CÀThe quantity of class 1-C flammable liquids will be reduced to that allowed under . í( ;)'. 'Ñ Article 79 _of the 1991 Uniform Fire Code (UFC) by the elimination of storage of \f' ':Jlj fost of the APL Luster 221 and 225. 180 gallons of Class 1-C flammable liquids ~~~ r¡nay be stored in a sprinklered B-2 occupancy. Submit a revision to the existing W I~ÎI ~az~rdous materials inventory which reports the reduced quantities of the 1-C Q.yhqUldS. . 2. A plan will be submitted specifying the details for provision of a H-2 occupancy for storage of the 65 % calcium hypochlorite, a class 3 solid oxidizer. A H occupancy may also be used to store gaseous chlorine, a toxic gas, provided that it meets the requirements for a H-7 occupancy and the requirements of UFC 80.303 for a ventilated gas storage room. The plans submitted should propose a combined H2/H7 portable occupancy to be installed into the existing B-2 occupancy resulting in a mixed use occupancy. , 3. If gaseous chlorine storage is resumed at this facility, the risk management and prevention program must be completed. à.'.. "~~~t-. .-.- e e Submit the plans for the hazardous (H2/H7) occupancy to the Bakersfield Building _ Department by August 25, 1992. The removal of the excess 1-C flammable liquid and submittal of the revised inventory form to the Hazardous Materials Division should also be completed by August 25, 1992. Please call me at (805) 326-3979 if I can be of further assistance. ' Sincerely, t~~Mc-.r-v ~~/ I Barbara Brenner Hazardous Materials Planning Techniciê¡ln cc: Ralph Huey Jack Leonard Richard Harger al)() ~{- c."~ -\b C\,L. KrtL B\~~í /e~r l" Ìblø(" ù S~ C <.(''V-.\ ' 1(1 ù,n(9/.--", < /? ff_: e e CITY of BAKERSFIELD' "WE CARE" FIRE DEPARTMENT S, D, JOHNSON FIRE CHIEF June 4, 1992 2101 H STREET BAKERSFIELD, 93301 326-3911 Jerry Achterberg Atochem North America, Inc. 1525 E. Noble #300 Visalia, CA 93277 Jerry: I have discussed your concerns regarding the Building Department's review of the hazardous materials storage container proposed for the storage of chlorine with Jack Leonard. We have agreed upon the points outlined below. 1. An H1 occupancy was required for the storage of poisonous gases under the 1976 Uniform Building Code. 2. The 1976 Uniform Building Code was in force at the time Pennwalt (Atochem) occupied the facility at 4330 Wible Road. The approved occupancy of this facility is B2. ,The declared the usage of the building 'on the building permits does not include the storage of hazardous materials. 3. Under the 1976 Uniform Building Code the exempt quantity of a poisonous gas allowed in other than a H1 occupancy was 0 cubic feet. 4. A container does not provide an H occupancy. The proposed storage container is considered an lIapproved containerll which, under the 1991 Code, would allow increased quantity of toxic gas storage as outlined in Jack Leonard's memo of 2-6-92. 6. Because the storage of chlorine at was not allowed in a B-2 occupancy in 1976, Atochem's use of this facility cannot be considered lIexisting nonconforming II. c ~ ,--... ...~ e e '- The Fire Department thought it worthwhile to explore all of the possible options toward provision of a H occupancy for Atochem's storage of chlorine. At the time that I suggested the possible use of a hazardous material storage container, I did not know that containers cannot be considered a separate occupancy. Because a container does not qualify as a separate occupancy, the plan for storage of gaseous chlorine inside the container inside a B2 occupancy would not be acceptable under the 1976 or 1991 -Uniform Building Codes. The Bakersfield Building Department is the enforcement authority for the Uniform Building Code. Mr. Leonard indicates that an application for permit to upgrade the Atochem facility to a H occupancy will be reviewed under the 1991 Uniform Building Code. Please contact me at (805)326-3979 if you have any questions regarding the points outlined above. Sincerely, ~ADrCr ~( Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Jack Leonard ~, .; " e e 1 V MEMORANDUM May 26, 1992 TO: Barbara Brenner, Fire Department - Hazardous Materials FROM: Jack Leonard, Civil Engineer III - Building Department SUBJECT: Atochem, 4330 Wible Road Hazardous Material Storage Containers ************************************************************* The Building Department would consider the proposed "HAZ-STOR" fire-rated storage building submitted by Atochem as an "approved storage cabinet". The quantities per container are limited to those outlined in my letter to Atochem dated February 6, 1992 (quantities in an approved storage cabinet may be increased 100%). For permit application, the Building Department would require 2 sets of plans including a detailed site plan showing the locations of the proposed storage containers. The submittal should also include anchorage calculations and details to illustrate how the containers will be secured to the floor. If you have any questions please contact me at 326-3718. cc: Jerry Achterberg, Atochem rt- -- ------- ¡- I L, " ~ -- _/>'" .7" ,,¿Þóé,-~. ,,::;¡;..i:;;;'......~ _ ""', ./':')\ ^. --~ _0 _~,V Vi ~ -_-~~ ,"" 7':- - r' t- CITY OF , IPJA~1E~SIFIT IE IL [0) BUI LDI NG DEPARTMENT C. A, BIDWELL, Director f.?0. February 6, 1992 Jerald Achterberg ATOCHEM 4330 Wible Road Bakersfield, California 93313 Attention: Jerald Achterberg Subject: Hazardous Material Storage at the ATOCHEM Site Dear Mr. Achterberg Per our phone conversation today, I have determined the maximum quantity allowed in a controlled area for your proposed B-2 occupancy. These quantities are as follows; Material Hazard Chlorine Oxidizing Gas/ Toxic Gas Calcium Class III Hypochlorite Oxidizer Cleaning Corrosive/ Products Irritant Flammables Class I-A Class I-B Class I-C Combination of Class I-A, I-B, & I-C Maximum Quantity Per Containers (1,2,3) 650 ft3 10 lbs 500 gal 30 gal 60 gàl 120 gal 120 gal 1. Qu~ntities may be increased 100 percent in sprinklered buildings. 2. Quantities may be increased 100 percent when stored in approved storage cabtnets as specified by the Fire Code. When footnote No. 1 applies, the increase for both footnotes may be applied. 3. You may have a maximum of 4 containers on your site. 1501 TRUXTUN AVENUE . , BAKERSFIELD, CALIFORNIA 93301 (8051 326·3727 ~ --..*.", e e, " /JJf!Y~/,~'-~> ~,Q:;;' .....~~i~ 7ft' -, ð~: ___- ,,-£! -"-,v \.}! ~ ~.. ~ ~;," .. #~~ CITY OF " " I85 ffß 1Th IE ~ S 1F IT IE IL IQ) BUILDING DEPARTMENT C. A, BIDWELL, Director , ' p" -,- Different types of materials may be stored i~ the same container as long as the maximum allowable quantity for each material is not exceeded. Controlled area storage containers are require to be made of 1 hour fire resistive construction. The above are the basic requirements of the Building Department based on the Uniform Building Code. You should contact the Bakersfield Fire Department for other requirements which may apply. If you have any questions or comments, please feel free to contact me at (805) 326-3718. Sincerely, /'J/ì /7 r ...:,.¿.-~<--/./ í// L·0~-~ , \ Jack Leonard Civil Engineer III cc Barbara Brenner Bakersfield Fire Department 1501 TRUXTUN AVENUE BAKERSFIELD,CALIFORNIA 93301 (8051 326·3727 ~~. -, ,-~ 1001·1002 UNIFORM BUILDING CODE :: . Chapter 10 m REQUIREMENTS FOR GROUP H OCCUPANCIES ¡:Group H Occupan~ies Defined , Sec. 1001. Group H Occupancies shall be: Division 1. S~age and handling of hazardous and highly flammable or explosive..mate(Ïals.o.ther-tb.an1Iammame l1QUlãS: ' . Division 2. Storage and handling of Clas;I: II and III-A liquids, as set forth in V.B.C. Standard No. 10-1; dry cleaning plants using flammable liquids; paint stores with bulk handling; paint shops and spray painting moms and shops. The storage or sale of hazardous materials or chf'mil'¡¡l~ nr ('hiss I. II , and III-A liQuids in, amounts that do not exceed those set forth in Table ~o. IO-A is permitted in buildinl!;s or Dortions thereof without classifying such bulldmgsas a 'Group H Occupancy.... provided such chemkals....haz- ardous materiãlšõf'liquiòs are stored and handJed in compliance with the lFõVišiõñšOfTheF'ïrt'code. Division 3. Woodworking establishments, planing mills, box factories, buffing rooms for tire rebuilding plants and picking rooms; shops, fac- , tories or warehouses where loose combustible fibers or dust are manufac- tured, processed, 'generated or stored; and pin refinishing rooms. . Division 4. Repair garages. Division 5. Aircraft repair hangars. In buildings used for educational purposes, vocational shops, laboratories and similar areas need not be classified as Group H Occupan- cies, provided they are separated from each other and from other classrooms by not less than a One-hour Fire-resistive Occupancy Separa- tion. For occupancy separations see Table No.5-B. Where an approved spray booth constructed as specified in the Fire Code is installed, such booth need not be separated from other Group H' or Group B Occupancies. For occupant load see Section 3301. Construction, Height and Allowable Area Sec. 1002. (a) General. Buildings or parts of buildings classed in Group H because of the use or character of the occupancy shall be limited to the . types of construction set forth in Tables No. 5-C and No. 5-D and shall not exceed, in area or height, the limits specified in Sections 50S, 506 and 507. " ,I ' ., (b) Special Provisions. Division 5 Occupancies shall have exterior walls of not less than one"hour fire-resistive construction or shall be surrounded by public space, streets or y~rds, not less than 60 feet in width. Thé area increases allowed by Section 506 (a) shall not exceed 500 per- cent for aircraft repair hangars. ' 74 '---,~( ~ '6 - 6 lt~~ hØ ~' ...,..."I...~ _'_C"~" .:.... "-J .--.-.....-. . ~.,-~. :r·"· ... (DITtON 1002-1005 ! ~' ,l:i , I \tJ ,\ .. &leas where motor vehicles, boats or airplanes are stored, repaired or 4C'~cd and where flammable liquids are stored or used, floor surfaces Aao! be or noncombustible nonabsorbent materials. t:XCEPTION: Floors may be surfaced or waterproofed with asphaltic plving materials where no repair work is done. rOt Jpccial provisions and hazardous chemicals and magnesium see also "'-,,cCode. , ,,', '. " ' , . ,...., 'A Division 4 Occupancy having a floor area not exceeding 2500 square: .... .awl have exterior walls of not less than two-hour fire-resistive con- cuaion when less than 5 feet from a property line and of not less than ODC'-hour fire-resistive construction when more than 5 feet but less than 10 ... from a property line, when located in Fire Zone No.3., For smoke and heat venting, see Section 3206. location on Property , Sec. 1003. For fire-resistive protection of exterior walls arid openings, .. determined by location on property, see Section 504 and Part V. bit Facilities Sec. 1004. Stairs, exits and smokeproof enclosures shall be provided as specified in Chapter 33. (See also Section 3319.) , Ught, Ventilation and Sanitation , Sec. 1005. All portions of Group H Occupancies shall be provided with ill natural light by means of exteriór glazed openings with an area equal to ~ one-tenth of the total floor area, and natural ventilation by means of ex- ~ I terior openings with an area not less than one-twentieth of the total floor I area or shall be provided with artificial light and a mechanically operated lli ventilating system as specified in Séction 605. m In all buildings or portións thereof where flammable liquids are used, - exhaust ventilation shall be. provided sufficient tQ produce four complete i air changes per hour. Such exhaust ventilation shall be taken from a point I~,· at or near the floor level. " In all buildings used for tpe repair or handling of automobiles operating 'I.' under their own power, ventilation shall be provided capable of exhausting , a minimum of I cfm per square foot. Additionally, each engine repair stall ~,' shall be equipped with an exhaust pipe extension duct, extending to the i outside of the building, which, ifover 10 feet in length, shall mechanically I",~, exhaust 300 cubic feet per minute. Connecting offices and waiting rooms shall be supplied with conditioned ¡lir under positive pressure; '. ' . ¡j EXCEPTION. In public repair garages and aircraft hangars not exceeding an area of 5000 square feet, the Building Official maý authorize the omission of such ventilating equipment where, in his opinion, the building is supplied with unobstructed openings to the outer air which are sufficient to provide the necessary ventilation. ' ' " , , Every building or portion thereof where persons are employed shall be provided with at least one water closet. Separate facilities shall be 75 . ,~: l I: i I J . ,~ I; ij " ¡1 II ;;f' ~~~ <, ". >t -----'~- 10·A UNIFORM BUILDING CODE 1976 EDITION 1101·1102 - TABLE NO. 10·A-EXEMPT AMOUNTS OF HAZARDOUS MATERIALS, " . LIQUIDS AND CHEMICALS :::~.~ -:.~ t MAXIMUM QUANTITIES MATERIAL I. Flammable liquids Class I-A - Class I-B ' Class I-C Class II ,," 2. Combustible liquids, Class III-A 3. Combination flammable liquids' 4. Flam¡¡:¡able gases .' 5. Liquefied flammable g~es 6. Flammable fibers:-'loose 7. Flammable fibers~baled 8. Flammable solids 9. Unstable materials' t80rrösive liquids ,': , I I xidizin material-gases . XI Izmg matena - IquI s ' 13. Oxidizing material-':"solids 14. Organic peroxides 15. Nitromethane (unstable Materials) 16. Ammonium nitrate ' 17. Ammonium nitrate compound mixtures containing more than 60%, ~trate by weight, ',' Hi&hly toxicimaterial and olsonous as No exem dons Chapter 11 REQUIREMENTS FOR GROUP S, DIVISIONS 1, 2 AND 3 OCCUPANCIES . NOTE: Tables in Chapter 11 appear at the end of the Chapter~ ,". . G~ouP B:Divisions 1,2 and 3 Occupancies Defined ~>t. ' ',- .' . , . , . . , Sec. 1101. Group B, Divisions 1, 2 and 3 Occupancies shall be: Division 1. Gasoline service stations, storage garages where no repair work is done except exchange of parts and maintenance requiring no\open flame, welding or the use of highly flammable liquids. ; Division 2. Wholesale and retail stores, office buildings, drinking and dining establishments having an occupant load of less than 100, printing plants, municipal poliCe and fire stations, factories and workshops using materials not highly flammable or,combustible, storage and sales rooms for combustible goods, paint stores without bulk handling. (See Section 402 for definition of Assembly Buildings.) Buildings or portions of buildings having rooms used for educational purposes beyond the 12th grade with less than 50 occupants in any room. Division 3. Aircraft hangars where no repair work is done except ex~ change of parts and maintenance requiring no open flame, welding, or the use of highly flammable liquids. ' Open parking garages. Heliports. For occupancy separations see Table No.5-B. For occupant load see Section 3301. Construction, Height, and Allowable Area Sec. 1102. (a) General. Buildings or parts of buildings classed in Group B, Divisions 1, 2 or 3 Occupancy because óf the use or character of the oc- cupancy shall be limited to the types of construction set forth in Tables, No. 5-C and No. 5-D and shall not exceed, in area or height, the limits specified in Sections 505, 506, and 507. ' " Other provisions of this Code notwithstanding, a Group B, Division 1 Occupancy located in the basement or first story of a building housing a Group B, Division 2 or a Group R, Division 1 Occupancy may be classed as a separate and distinct building for the' purpose of area limitation, limitation of number of stories and type of construction, when all of the following conditions are met: . 1. The Group B, Division 1 Occupancy is of Type I Construction. 2. There is a Three-hour Occupancy Separation between the Group B, 'Division 1 Occupancy and all portions of the Group B, Division 2 or Group R, Division 1 Occupancy, ' 3. The basement or first story is restricted to the storage of passenger \1 .., ~ ~ ; , ru rJ ¡ j~ ,~ ~i ' I i %~ ,¡~ 30 gaL' , 60 gal.' 90 gaL' ' 120 gaL', , " 250 gal.' , " 120 gal.' . " ' 3000 cu. f1. at one atmosphere of pressure at 70°F. 60 gal. 100 cu. f1. 1000 cu. ft. 500 lbs. No exemptions' SS gal. 6000 cu. f1. - 50 gal. 500 Ibs. 101bs.' No exemptions 1000 Ibs. ! { ì i ( ! ! ¡: )1 " 1000 Ibs. ¡Containing' n~t 1,11ore1than the ~empt amou~ts of Clas~ 'I-A loB or l-G '. flammable liquIds. . . .. , t 'Q~ntities !Ray be in~~e!ised by '100 pe~cent i':1 areas which ar~' not accessible to t~ ' e ~~bdliC. In bUl~":mgs where. automatIc fire-extinguishing systems are ¡¡~ mhsta e " the quantities may be mcreased 100 percent in areas accessible to '" t e public. . " ~ . . ,'" " --- --" ..... '-....~. - ,.,-- I:.' , I ----I ,:, :1 - . MEMORANDUM "WE CARE" May 13, 1992 TO: Jack Leonard, Building Department FROM: Barbara Brenner, Fire Department - Hazardous Materials SUBJECT: Atochem, 4330 Wible Road ****************************************************************************** Atochem has submitted the specifications for two hazardous materials storage containers for review regarding their ability to provide an acceptable H occupancy for the storage of gaseous chlorine. The HAZ-STOR buildings would be located inside the existing building. Due to Atochem's somewhat questionable status as existing nonconforming, the Fire Department has agreed to consider cómpliance with the provisions of the code in place when they occupied the facility as an acceptable remedy to the chlorine storage problems.' Therefore, I request that the Building Department review these storage containers under the 1976 Uniform Building Code for compliance with the requirements for the appropriate H occupancy. Chlorine is a toxic (poisonous) and oxidizing gas. I have attached a copy of the letter which I sent to Atochem regarding their compliance requirements. If you cannot approve one of these containerized storage areas per the 1976 H occupancy requirements, please state specifically what provisions they fail to meet. If you have any specific questions regarding the equipment please contact Keith Uyekawa directly. His phone number is on the cover letter. Please send me a copy of your response to Atochem. I appreciate your time and efforts on this project. cc: Ralph Huey ~~ ~-~' "~~-", ATOCHEM NORT1i AMERICA elf aquitaine e e ATOCHEM NORTH AMERICA, INC, P,O, Box 174, 21491 East Dinuba Avenue, Reedley, California 93654 Tel: (209) 638-4470. Fax: (209) 638-7796 , Barbara Brenner Hazardous' Material Planning Technican Bakersfield City Fire Department 2130 "G" Street Bakersfield, California 93301 Phone (805) 326-3979' May 11, 1992 Dear Barbara Attached you will find a quote for two dïfferant sizes of HAZ-STOR buildings, that we request you review with your department, and advise us if they will be acceptable for the storage of chlorine gas for us to resume a controlled inventory of cylinders at our ware- house on Wible Road, there in Bakersfield. You may also want toset up a meeting with your department, and our supplier-consultant, to discuss building plans, compliances, etc. so we can proceed with approved plans and conditions as agreed upon, that will meet the 1976 codes you referred to in your letter of Feb- ruary 25, 1992. Sincerely r) /) ~j) /1, ,7:£li,-/ L-t¿/¡/f.i'U>~-J / / Jeriy Achterberg , /' CCj Fred Serr Art Dawson cc: Keith Uyekawa Core Rosion Products P.O. Box 8652 Long Beach, Calif. 90808 213/310 - 596-4113 \ The hentage: JiIEHMAi1 and MIf The future: ATOCHEM NORTH AMERICA ,/ e , ~ nE~~n~:~~s~'ON e May 6, 1992 Elf Atochem Decco 4330 Wible Rd. Bakersfeild, CA 93313 (805) 397-1087 FAX (805) 397-0813 Attention: Jerry Achterberg Reference: Quotation on HAZ-STOR Building Quote #KHS2006 HAZSTOR #P-485 Dear Jerry; Thank You for the opportunity to introduce our HAZ-STOR building as a solution to your hazardous storage problems. HAZ-STOR structures are specifically designed to meet, and in some cases exceed, local building and environment code standards for the storage of hazardous materials. When it comes to compliance with the EPA, NFPA, or OSHA, HAZ-STOR and its parent, the Justrite Manufacturing Company, have over 70 years of dependability. Enclosed is our quotation No. KHS2006 in reference to your recent inquiry. To assure proper compliance and control of your specific hazardous material, HAZ-STORwill provide building plans for client and local authority approval. Delivery will be 8 to 10 weeks after return of approved drawings. Thank you for your interest and this opportunity to quote to you. . We are looking forward to working with you. Please call when I can provide any additional or more detailed information. Cordially, /~~~ Keith T. Uyekawa Territory Sales Manager The HAZ-STOR Company Representative KTU:ku Enclosures: 301, 304, 310, B.C., 001 cc: File - Elf Atochem Decco Steve - Core-Rosion Chuck P. - The HAZ-STOR Co. POSTOFFICEBOXB652,LONGBEACH,CALlFORNIA90B08 . 310-596-4113 . FAX#310-430-1058 (Ireland, Inc. dba Core-Rosion Products) e -i ~ '£ Quote #KHS2006 Elf Atochem Decco Jerry Achterberg May 6, 1992 Page 02 e 1. 0 HAZ-STORTH Fire-Rated Buildinq: $11,500.00 Factory Mutual system Approved UL classified #29200, Premier series free standing relocatable chemical storage and containment structure for the storage of flammable/hazardous materials including the following components and features: inside dims. (1 x w xh) : outside dims. (1 x w x h): storage capacity building weight maximum snow load maximum wind load seismic loading design maximum floor load wall structure roof structure floor sump capacity access security door hold open device spill containment gravity ventilation static control interior finish exterior finish handling anchoring hazard labeling certification (s) 61-8" x 6'-8" x 7'-0" 8' X 81 X 81 (9) 55 gallon drums 4,900 pounds 40 psf 30 psf (110 mph) zone IV 300 psf 2 hour fire rated per UL-U425 class "A" spread of flame, UL wind uplift rating 1-60 epoxy coated 1-1/8" removeable plywood panels :- 148 gallons (1) 60" x 80", 1,-1/2 hour fire rated double door-UL labeled 3 point locking system with key on one door fuse linked for standard automatic door closure assembly perimeter drainage into sump l-1/2 hour fire dampers classified static grounding / bonding system, 8' grounding rod chemical resistant epoxy high gloss urethane forklift and crane sling channels (81 forks required) hold down brackets DOT placa~ds, NFPA 704M rating signs Factory Mutual System Approved and UL Classified ,. UL e ~ ~~!" £. Quote #KHS2006 Elf Atochem Decco Jerry Achterberg May 6, 1992 Page 03 e 2.0 HAZ-STOR™ Fire-Rated Building: $13,500.00 Factory Mutual System Approved UL Classified #29201, Premier series free standing relocatable chemical storage and containment structure for the storage of flammable/hazardous materials including 'the following components and features: inside dims. (1 x w x outside dims. (1 x w x storage capacity building weight maximum snow load maximum wind load seismic loading design maximum floor load wall structure roof structure floor sump capacity access security door hold open device spill containment gravity ventilation static control interior finish exterior finish, handling anchoring hazard labeling certification (s) h): 101-8"}{ 61-8" x 71-0" h): 12 I x 8' x 8 I (15) 55 gallon drums 6,200 pounds 40 psf 30 psf (110 mph) zone IV 300 psf 2 hour fire rated per UL-U425 class "A" spread of flame, UL wind , uplift rating 1-60 epoxy coated 1-1/8" removeable plywood panels :- 1989allòns (1) 60" x 80", 1-l/2 hour fire rated double door-UL labeled 3 point locking system with key on one door fuse linked for standard automatic door closure assembly perimeter drainage into sump 1-1/2 hour fire dampers UL classified static grounding / bonding system, 8' g:):"ounding rod chemical resistant epoxy high gloss urethane forklift and crane sling channels (81 forks required) hold down brackets DOT placards, NFPA 704M rating signs Factory Mutual System Approved and UL Classified e e }iè' ",-,. ,t:: Quote #KHS2006 Elf Atochem Decco Jerry Achterberg May 6, 1992 Page 04 3.0 options: 3.1 Steel loading ramp $ 900.00 3.2 Aluminum.loading ramp $1500.00 3.3 Wall mounting racks for gas cylinders (call factory) 3.4 Mechanical ventilation, UL listed (call factory) 4.0 TERMS AND CONDITIONS Drawings Shipment 7-10 days after receipt of order 8-10 weeks after receipt of approved drawings Warranty 90 days from shipment date FOB Point Factory - Charleston, IL Terms Net 30 days . Prices effective 30 days for your acceptance This quotation is subject to the enclosed Haz-Stor Terms and 'Conditions of Sale Prices do not include any applicable sales tax a. Sales tax will be charged unless a resale card is on file Freight will be prepaid and added 5.0 ORDERING INSTRUCTIONS Please issue your purchase order as shown below: The Haz-Stor Company 2454 Dempster st. Des Plaines, IL 60016 c/o Core-Rosion Products P.o. Box 8652 Long Beach, CA 90808 ATTN: Keith T. Uyekawa Be~~R~r?~,/./ _ _ /~~~' Keith T. Uyekawa J: ..at" 1: [en I ," I j",Z:¡:{o '-I iQ:' , ...1 51 IQI ... 1M 1M '... :! ... 'I 1Q;1 ¡:: ~;, '1,1' o u;: . Z': o Z ~".J. Only HcfL.Stor offer^o many ways to keep hazardous . materials in their place. A complete line of high quality buildings that provide såfety, security, segregation and seconâary containment for hazardous materials, chemicals and waste. . ,æ-: " , -: "'.:... 11' x 7' (10 drums) Represented By: CORE-ROSION PRODUCTS 2017 Palo Verde Avenue Long Beach, CA 90815 (213) 596-4113 FAX (213) 430.1058 2454 Dempster Strei9t Des Plaines, IL 60016 708298-9250· FAX: 708 298-9716 ® CIassiIIecI , ~il Haz·Stor Premier Series Buildings " Available with a wide variety ~'--I_-' " ,:. - ,,' of popular, pre-designed options . for general purpose hazardous mat~rial storage applications. These 3-drum deep standard buildings are FM Approved and Ul Classified to certify compliance with environmental regulations and building codes. Haz·Stor Custom Series Buildings Intended for special purpose applications, these 4-drum deep buildings can be custom engineered to any specification. Available with a virtually unlimited selection of pre-designed or specially- engineered options. FM Approved; Ul Classified. Haz·Stor Wide Body Series Buildings* largest practical size and storage capacity in a transportable and relocatable factory assembled structure. These 5-drum deep build- ings feature exclusive fork lift truck entry for maximum ease in handling large volumes of hazardous materials. FM Approved. ~~'ifi1'9Jf!it..¥;ifif;;.:~~"t..4_~~,.!~tÞ-f1+i~t\1it~'W..",,,,-:;'-;t';,:i.~~ ~~-~ . ~ ~ Approved ~ ;";"';:'=--~:;:;:;...c="'",,,,,,~ ,"" ':, '$ :';Uß;>(;1t'~::~:.:, Economical, all metal buildings available for qCick delivery. These 4-drum deep buildings are intended for storage of flammables located remote from a plant, and allow compli- ance with EPA requirements for secondary containment. Wide choice of pre-designed or specially-engineered options. FM Approved. .~ .;~ æ-: " , -: ....:... Approved 8' x 8' (9 drums) 8' x 12' (15 drums) 8' x 16' (21 drums) 8' x 20' '(27 drums) 8' x 24' (33 drums) :_1' '-.. .. " '.!, , :.' ,., ¡.> ~ .." ,., " ,'. ~.~ ~l"~ ", .'..' (>, 'er:" .<,~/..-r, "'''';''', 'e)i.,': ,.' "", .}'.' '., ,: " .Jii.." _ :,~ ~,'_.~:~:'~, I: _ ¥~'>r"~ 10' x 8' (12 drums) 10' x 16' (28 drums) 10' x 24' (44 drums) · · · · · · · · · · "'~~ '. ~'" p:r-:-______' ' '..,.,..-~ Haz·Stor Storage Lockers Comply with the new 1990 N FPA 30 Fire Code for storage lockers. Ideal for small volumes of hazardous materials, these weatherproof lockers feature a wide door opening for easy fork lift access. Sump provides secondary containment. Pre-designed options avail- able. FMApproved. .-11. 7' x 7' (6 drums) 6' x 4' 6' x 6' (2 drums) '(4 drums) Call or write for descriptive literature ____________ ·UL applied for. and detailed specifications. ~ . HAZ~'JSTOR The Haz·Stor Company --------- ~, HAZ*STOR HAZARDOUS MATERIAL STORAGE e e SELLING POLICY Form# 2900 June 1, 1990 Terms and Conditions of Sale Entire Agreement-Modifications Any acceptance of the offer to sell contained herein is limited to acceptance of the express terms of such offer contained in this Quotaiion Letter. Any proposal for additional or different terms or any attempt by the Purchaser to vary, in any degree, any of the terms in the Purchaser's acceptance by purchase order or otherwise shall not operate as a rejection of this offer to sell unless such variance is in the terms of the description, quantity, price or delivery schedule of the goods, but rather shall be deemed a material alteration thereof, and this offer shall be deemed accepted by the Purchaser without 'said additional or different terms. If this Quotation Letter shall be deemed an acceptance of a prior offer by the Purchaser, such acceptance is expressly conditional on the Purchaser's assent to any additional or ,different terms contained herein. This Quotation Letter sets forth the entire agreement between the' parties, and may not be modified except by an instrument in writing signed by all of the parties hereto. This Quotation Letter supersedes any prior agreements, oral or any written, or any correspondence between the parties. Price The price quotations set forth in this Quotation Letter are valid for 30 days from the date hereof unless withdrawn by HAZ- STOR prior to acceptance by the Purchaser. If product shipment extends beyond 90 days from the date of order, the prices will be adjusted to those in effect at the time of shipment. Prices quoted do not include any federal, state or local property, license, privilege, sales, use, excise, gross receipts, value added or other like taxes which may now or hereafter be applicable to. measured by or imposed upon the 'sale of the products purchased hereunder, their use, or any services performed in connection therewith. Except as otherwise required by Illinois law, such taxes are the sole obligation of the Purchaser and the Purchaser agrees to pay or reimburse HAZ-STOR for any such taxes which HAZ-STOR or its contractors or suppliers are required to pay. Terms of Payment The purchaser shall pay the full purchase price for any goods purchased within 30 days from the date of invoice. If payment is not made within the stated period, a service charge will, without prejudice to the right of HAZ-STOR to immediate payment or any other legal or , , equitable remedies, be added to the account of the ,Purchaser in an amount equal to the lower of 1'12% per month or the highest legal rate of the unpaid balance. If the work is in any way delayed by the Purchaser, HAZ-STOR may require payment. in an amount to be 'determined by HAZ-STOR in its sole discretion. for all materials accumulated and work performed under the order. Warranty HAZ-STOR warrants that the products manufactured by it shall be free of defects in workmanship and material for a period of 90 days from the date of shipment. Any such defects shall be corrected by HAZ-STOR by repair or replacement. at HAZ-STOR's sole option, of the defective part or parts, provided HAZ-STOR is notified within such 90 day period in writing of such defects, and further provided the products have been properly installed, operated and maintained in accordance with HAZ-STOR's instructions. In this regard, HAZ-STOR hazardous storage buildings meet the regulations listed in HAZ- STOR's use instructions that accompany the shipment. Buildings are designed and constructed in accordance with Factory Mutual Research and Underwriters laboratories Inc. standards, and when required to be so labeled, as indicated in this Quotation Letter. are approved for limited use in providing safe, secure and detached storage of Class 1.11 and III flammable liquids and hazardous materials contained in maximum 60 gallon drums.1f the building that the Purchaser has ordered has received the above approvals, such approval status is identified in the section of this Quotation Letter in which the Purchaser's order is set forth. No other use is permitted. HAZ-STOR will make available to the Purchaser the original manufacturer's warranty which HAZ-STOR possesses, if any, to the extent transferable, respecting products purchased by the Purchaser hereunder and manufactured by others, which products are supplied by HAZ-STOR seperately or are a component of a HAZ- STOR product. THE FOREGOING WARRANTIES ARE EXCLUSIVE AND IN LIEU OF ALL OTHER WARRANTIES WHETHER STATUTORY, EXPRESS OR IMPLIED, INCLUDING ALL WARRANTIES OR MERCHANTABILITY AND FITNESS FOR PARTICULAR PURPOSE AND ALL WARRANTIES ARISING FROM COURSE OF DEALING OR USAGE OF TRADE. Force Majeure HAZ-STOR shall not be liable for failure to perform or for delay in performance resulting from any cause beyond its reasonable control, including acts of God, acts or omissions of the Purchaser, fires. floods, weather, strikes, lockouts, factory shutdowns, embargoes, wars, hostilities, riots, delays or shortages in transportation or inability to obtain labor, manufacturing facilities or material from HAZ~STOR's usual sources, or due to compliance with any regulations, orders, acts, instructions or priority requests of any federal, state or municipal government, or any department or agency thereof, or of any civil or military authority. Any delay resulting from any such cause shall extend delivery dates to the extent caused thereby and HAZ-STOR shall be reimbursed for any additional expenses resulting from such delay. The Purchaser's receipt of products shall constitute a waiver of any claims for delay. Delivery HAZ-STOR shall deliver to the Purchaser all products purchased hereunder F.O.B. HAZ- STOR's facility at Charleston, Illinois or at such other place as HAZ-STOR shall quote. Shipment from such plant will be made at the sole cost of the Purchaser. All costs of shipping shall be prepaid by HAZ-STOR and invoiced as a separate item for which the Purchaser shall reimburse HAZ-STOR. Quoted shipping dates are approximate and are based on prompt receipt of all necessary information and approvals from the Purchaser to allow release of the product for manufacture. HAZ-STOR shall use all commercially reasonable efforts to meet scheduled delivery dates. HAZ-STOR reserves the right to ship prior to the quoted shipping date. Where the Purchaser makes no prior arrangements for transportation; HAZ-STOR may provide. as a service to the Purchaser, transportation assistance. Such service may involve determining the method of transport, the routing of shipment, selection of a carrier, and/or scheduling of pick-up and drop-off dates. HAZ-STOR reserves the right to group shipments of multiple orders, and in such event. each order will be invoiced the pro- rata amount of freight costs based on the most direct routing of each single order. HAZ-STOR's assistance with transportation arrangements as noted above is not to be construed as a quarantee of delivery, and HAZ-STOR shall not be liable for late deliveries or scheduling delays. Any costs associated with delay. including costs which result from demurrage, idle time of riggers or rented handling equipment. or penalties for failure to meet environmental compliance deadlines. are the sole obligation of the Purchaser, Inspection Any claim for defective materials, imperfect manufacture, shortage or any other claim against HAZ-STOR with respect to the condition of the products purchased e e ::j.. ·.:0 "" \. HAZ-STOR ,è DESCRIPTION: STORAGE UNIT :. PURPOSE: STORAGE OF CLASS I FLAMMABLE LIQUIDS QUALITY ASSURANCE AND REFERENCED STANDARDS 1. AISC "SPECIFICATION FOR THE DESIGN, FABRICATION, AND ERECTION OF STRUCTURAL STEEL FOR BUILDINGS," LATEST EDITION, INCLUDING THE "COMMENTARY" AND SUPPLEMENTS THERETO AS ISSUED. 2. ' 'AISC "MANUÀL OF STEEL CONSTRUCTION, ',' LATEST EDITION. 3. AMERICAN IRON AND STEEL INSTITUTE COLD-FORMED STEEL DESIGN MANUAL, LATEST EDITION. 4. AMERICAN WELDING SOCIETY'S "STRUCTURAL "ŒLDING CODE AWS D1..1.-77." 5. AMERICAN PLYWOOD ASSOCIATION'S "PLYWOOD DESIGN SPECIFICATION," LATEST EDITION. 6. NATIONAL DESIGN SPECIFICATION OF THE AMERICAN SOCIETY FOR TESTING AND MATERIALS. ,7. NATIONAL DESIGN SPECIFICATION AND COMMENTARY FOR WOOD CONSTRUCTION. 8. THE UNIFORM BUILDING CODE. l DESIGN AND LOADING - BASED ON UNIT SIZE AS FOLLOWS: WIDTH: HEIGHT: LENGTH: 7'-1.0" MAX. 8'-1." MAX. 7 ' -1. 0" 11I N . 1.9'-1.0" MAX. SNOW LOAD WIND LOAD STORAGE LOAD 40 PSF 30 PSF (11.0 rnph) - 250 PSF (MAX. RECOMMENDED) "- -1- e e ~. .Q', ;, HAZ-STOR " DESIGN AND LOADING (continued) WALL STRUCTURE ROOF STRUCTURE 2 HOUR FIRE RATED i/a/w D.L. U425 CLASS A FLAME SPREAD RATING - U.L. WIND UPLIFT, RATING, I-60 l! HOUR FIRE RATED - U. L. LABELED . l! HOUR -FIRE DAMPER - U. L. (ALBR) 4" DEPTH, UNDERFLOOR SPILL CONTAINMENT DOOR, FRAME ~ HARDWARE VENTILATION , BASE STRUCTURE SPECIFIC STRUCTURAL NOTES 1. BASE - STRUCTURAL STEEL STRUCTURAL STEEL SHALL BE FABRICATED AND ERECTED IN ACCORDANCE WITH THE AISC "SP~ÇIFICATION FOR THE DESIGN, FABRICATION AND ERECTION OF STRUCTURAL STEEL FOR BUILDINGS" AND THE AISI It CODE OF STANDARD PRACTICE.« ALL SHOP WELDING SHALL BE IN ACCORDANCE WITH A.W.S. DI.I-al "CODE FOR WELDING IN BUILDING CONSTRUCTION. " ALL STRUCTURAL STEEL SHALL BE COATED OR PROTECTED BY CORROSION RESISTANT MATERIAL. 2. SUMP PAN SUMP PAN STEEL SHALL BE COMMERCIAL QUALITY HAVING A MINIMUM YIELD STRENGTH OF 25,000 PSI. SUMP PANS SHALL BE WELDED AS SHOWN ON PLAN TO PROVIDE A LIQUID TIGHT SEAL. SUMP PANS SHALL BE COATED OR PROTECTED BY CORROSION RESISTANT MATERIAL. . 3. BASE - FLOORING FLOOR GRATING FLOOR GRATING SHALL BE CAPABLE OF SUPPORTING A MINIMUM LIVE LOAD OF 250 PSF. GRATING SHALL HAVE ENOUGH VOIDS TO ALLOW PROPER DRAINAGE INTO SUMP PAN WITHOUT BUILD-UP OF WASTE. FLOOR DECKING '. PLYWOOD DECK, SHALL MEET ALL REQUIREMENTS OF U. S. PRODUCT STANDARD, p.S.-I, LATEST EDITION. PLYWOOD SHALL BE A MINIMUM OF 1" THICK. -2- e e ;:¿ ·r;t ;,.;,; HAZ-STOR SPECIFIC STRUCTURAL NOTES (continued) 4. LIGHT GAUGE STEEL STEEL ROOF JOISTS I FLOOR JOISTS AND STUDS SHALL, BE FORMED FROM STEEL MEETING . THE REQUIREMENTS OF ASTM A-570-79 . AND ASTM A-611-79 (16,18 and 20 ga.> MATERIAL WITH A MINIMUM YIELD STRENGTH OF 40,000 PSI. STEEL JOISTS AND STUDS SHALL BE GALVANIZED. SECTION PROPERTIES FOR THE LIGHT-GAUGE SHALL BE AT LEAST EQUAL TO THOSE MANUFACTURED BY THE UNITED STATES GYPSUM COMPANY - USG STEEL FRAMING. CONNECTIONS OF MEMBERS SHALL BE WELDED UNLESS NOTED ON PLAN. MEMBER SIZES ARE AS FOLLOWS: ROOF JOISTS --------------------- 362 SJ 16 STUDS --------------------------- . 362 SJ 20 ( BRIDGING ------------------------ 11 x 16 gauge RUNNERS -------------~----------- 362 CR 18 STRAPPING ----------------------- 3" x 20 gauge 5 . ROOFING THE ROOFING SYSTEM SHALL BE INSTALLED IN ACCORDANCE WITH THE RECOMMENDED PROCEDURES. ROOF DECK ,SHALL BE ~" THICK PLYWOOD AND FASTENED TO ROOF JOISTS. , . ROOF OVERLAYMENT SHALL BE !.. THICK "DENS-GLAS." RUBBER MEMBRANE AND TRIM SHALL BE INSTALLED. 6. SIDING SIDING S~L BE A MINIMUM OF 24 ga. MATE~AL AND PROTECTED TO RESIST CORROSION. . ~~. -3- e e :¿ i';"~' ¡;;:" OPTIONAL EOUIPMENT - HAl STOR 1. Two hour rated firewall.... ........... ............,........ ........ ......... ............................ ,............. ............................... ........... ......... Standard 2. Epoxy coated plywood & steel floor grate ........................................,.......................................................................... Standard 3. Corrosion resistant fiberglass floor grate.................... ..........,.................. ........... ....... ..................................... ............... Optional 4. Crane hook plates....... ....... ................................ ..................... ............................ ,.......................................................... Standard 5. Build ing hold-down assembly... ...................... .............. .............. ....................... '....................................'................,'.... Standard 6. Gas Cylinder wall mounts..................... ....... ......... ................................................................................ ......................... Optional 7. Explosion proof light fixtures, 300 Watt, inside Class I Division I or Class I Division II, one or two per unit............. Optional 8. Exterior lights, photocell sensor, not explosion rated..........................................................................~....................... Optional 9. Bonding, Bus bars, and grounding system ................................................... ............................. .......................,.......... Standard 10. Explosion proof electric service, Class I Division lor Class I Division II panel, wiring. junction box, switch ........... Optional 11. Heat sensor/fan cutoff....... .................. ............. ,............. ...................,.......... ........ ....... ...., ....... ..... '.. '... ................... ..,... Optional 12. Explosion proof ventilation Class I Division I or Class I Division II, Group C & D......................,............................... Optional 13. Loading ramp............................. ........,................;...... ................................................................................................... 0 ptional 14. Special pain finish '........................................................................................................................................... ..... P.O. R. 15. Portable emergency eye/face wash - 5 or 10 gallon ...................................,....,......................................................... Optional 16. Wash station outlet head covers ......... ..... ...... ............ ..~....... ..............................,.......................... ............................... Optional 17. Fire extinguishing systems - ABC dry chemical or Halon 1301.............................,.........,.......................................... Optional 18. Explosion proof heating systems, Class I Division I Group 0 heater with thermostat - 6, 000 BTU, 12,000 BTU or 25,6000 BTU each .................. ....................,. .........,......... ..............,........................................................................... Optional 19. 2 1/2 inch Fire Department connection, with deluge sprinkler heads and piping.................................................... Optional 20. Extra door (maximum 2 doors per structure) Must be same wall - 1 1/2 hour rated (Not available on 8 foot J \ l. -root units) .......... ....................................................................................................................................................... ............ Optional 21. 60 Inch width door - 1 1/2 hour fire rated...........,..........................................................................,............................. Standard 22. Air Inlet vents with fuselink - U.L fire rated .....................................................................................................,............ Standard 23. Class I Division I or II Air.Conditioning System ........................................................................................................... Optional ., 24. D. O.T. placard.. ...............:........,...... ....... ...................... .... ............... ............... ....... ..... ...... ........ ..... .... .,. ...... ............... .... Standard 25. Additional D.O.T. or N.F.P.A. 704M placards .....................................,....,.......................,.................'.......................... Optional e e .! '~I' :c;,; - . - HAZ-S1;'OR LIMITED WARRANTY 1":"1-88 HAZ-STOR wa~~ants that buildings meet the specifications - - de~cribed ~n D.L. classification plates and that_rn~terials used 1n construction. ar~ in compliance with th~ attached specification. HAZ-STOR buildings are covered by a limited warranty for a period of si~~onths from the·date of-ma~ufacture. Warranty does not apply if buildings have been subjected to misuse or abuse including (but not limited to) the following: · Damage b.y freight_ carriex:. '. . Buildings ~hich are altered' in any. way by the user. . Buildings which- are installed in any way contrary to the manufacturer's instructions. · Bùildings.which are subject~~ to corrosive materials. Root is warranted against deterioration of membrane to the point ot fai~ure becaus~ of weathering for a period, of ten years by Firestone Building Products co~~åny. A copy of the limited warranty will be provided on request. All optio~s ~ncluding but limited to electrical, fire protection, heating, and cooling systems are covered by whatever warranty 1S offered by the manufacturer of the component systems. HAZ-STOR warrants these systems have been installed in a workman- , like manner_ - ;:... ;~~<. 4.: Model # Length 29200 OD 7'10" #1,'-';99- ID 6'8" 29201 1r939] ,29202 93'lq 2.9203 t tJ?Jqlf 2!9 222 2~9 2 3 3 29214 29242 29243 29244 OD 11'10" ID 10'8 1/2" OD 15'10" ID 14'8 1/2" OD 1.9'10" ID 18'8 1/2" OD 8'0" ID 7'4" OD 16'0" ID 14'7" OD ~4'O" ID 22'0" OD 12'0" OI 10'8" OD 16'0" ID 14'7" OD 24'0" ID 22'0" e DIMENSIONS Width Height 7'10" 8'1" 6'8 1/2" 7'0" 7'10" 6'8 1/2" 7'10" 6'8 1/2" 7'10" 6' 8 1/2" 10'0" 8'11t 10'0" 8'1" 10'0" 8'1" 12'0" 10'0" 12'0" 10'0" 12'0" 10'0" 8'1" 7'0" 8'1" 7'0" 8'1" 7'0" 9'0" 7'0" 9'0" 7'0" 9'0" 7'0" 9'0" 7'0" 9'0" 7'0" 9'0" 7'0" e Sump Capacity(gal) 105 \ 170 2,30 292 250 500 750 450 625 925 Drum Capacity 9 15 21 27 1,2 28 44 25 35 55 Shipping Weight 4900 6200 7500 8800 6,500 10,500 14,500 10,000 12,000 16,000 ,¡. ~;T(: I ~ . ,- ! piS e mp e Finest Quality Cons.tion Haz"Stor Building~ are fabricated under tightly controlled conditions to ensure that they meet the most stringent requirements for storage of hazardous liquids. All welding meets AWS 01.1-77; seam welds in the sump are leak tested before shipment, Design and Loading Characteristics (Based on a structure 7"0" wide x 8"" high x 7'10"10 '9"0" long) 40 psI 30 psI (110 mph) 250 psI 2 hour Fire Rated i/aJw UL U425 Class A Flame Spread Rating UL Wind Uplift Rating 1·60 1 hour Fire Rated 1'/2 hour Fire Rated-UL Labeled 1 V2 hour Fire Damper -UL (ALBR) 4" depth, Under Floor Spill Containment HAZ-STORTY HAZARDOUS LIQUID STORAGE BUILDINGS DIMENSIONS AND CAPACITIES (Standard building eqUIpped w,ln one 60" double door) , RUM~ ;'\."!ÌsHIPf>ING:~"i '~'." .........a.Ið,,: ~_ 'Ii .ro,~.")..."'t-~ 4· " " , 29200 8x8x8 OUTSIDE 7' '0' 7' '0" 8' '" '05 9 4900 twas 29108\ INSIDE 6' 8'h" 6' 8'h" 7' 0" 29201 12x'8x8 OUTSIDE 11' 10" 7' 10" 8' 1" 170 15 6200 (was 29112) INSIDE 10' 8'h" 6'8'h" 7' 0" 29202 16 X 8 X 8 OUTSIDE 15' 10" 7' 10" 8' 1" 230 21 7500 (was 29116) INSIDE 14' 8'h" 6' 8'h" 7' 0" IiI 29203 2Ox8x8 OUTSIDE 19' 10" 7' 10" 8' 1" 292 27 8800 (was 29120) INSIDE 18'8\07" 6' 8Y.!" 7' 0" r- C311nquire about larger sizes (4)Basis; 55 gaJlon drums %" GYPSUM BOARD - I Maximum Snow Load Maximum Wind Load ' , , , , ' Maximum Floor Load , , , , , , , Wall Structure ",.,.""" Rool Structure , , . . , , Ceiling""""",."",., ' Door, Frame and Hardware, , , , , Ventilation ,,',"",',' Bas'e Structure """",'" The 2 hour fire rated walls in Haz'Stor Buildings are conslructèd of nominal 2 x 4" steel studs, sheathed bolh sides with a double layer of 518" gypsum board, Gypsum will not support combustion, When it is exposed to fire, water of crystallization is released and turns to steam, helping to retard the spread 21 flame, Siding inside and out is 24 ga, steel, finished to resist corrosion, .ide Selection of Options e to Increase the Versatility of Any Haz·Stor Building J.. ~4.!( :'-. I m~-! t. ¡.~_ '-'l" "'(l~U ¡ ¡ J I Th tal' IL au, bui rat of g~r sl~ : t-;, £Jl a \' . - '." .r.. ,,_ ,,~, -'.' _". ·.·.,.._.·_o.._,~......c..>.~-.I,_.........,...=~¡,,~ r Interior view showing optional. FM Approved explosion-relief panel and optional water sprinkler system. (Haz'Stor Buildings are rated at 100 psi internal pressure: panels blowout at 20 psf.) Note finished ceiling, All Haz·Stor Buildings have finished ceilings with 1 hour fire rating, Optional explosion- proof lighting fixtures are available in a choice of wattages, Optional 2W' fire department water connection connects to interior water sprinkler'system, Inclined Loading Ramp makes it easy to move drums in and out of the Haz·Stor Building with a hand dolly, Either water or halon fire protection systems are optionally available, Halon tank and control assembly shown, Haz·Stor Buildings are optionally available with heating and/or air conditioning sys· tems, Electric heater shown,- Available Options Include: · Fire Protection Systems: Water and Halon · Fire Department Exterior Water Connections · Explosion Relief Panels · 2 hour Fire Rated Internal Compartment Walls · Spill, Security and Fire Alarms · Heating and/or Air Conditioning Systems · Exterior and Interior Tungsten Lighting (Standard and Explosion Proof) · Exterior Low Pressure Sodium Vapor Lighting · Corrosion Resistant Floor Grates · Shelveš for Safety Can Storage · Wall Mounting Racks for Gas Cylinders · Additional 60" Double Door · Building Hold-down Assemblies To Build or Buy... Some Important Considerations Discussions of whether to build or buy a building for the storage of hazardous liquids must include both short-range and long-range considerations. In the short term, buying makes more sense, because all of the safety requirements and construction details in a Haz'Stor Building have been researched and designed by experts and approved by code authorities. There is no need for the customer to spend time with these matters on an individual basis, and no need to locate a contractor who can do the work according to spec. Long range, a self-built structure is permanently committed to a site. Buying a Haz'Stor Building gives you the freedom to relocate th~ structure at any time; even to resell it if it no longer serves a need. . -Ef' THE HAZ'STOR" DIFFERENCE . Haz'Stor Premier Series Buildings are hi, qUólity structures, designed, built, inspect and tested by a company with more than 80 ¡, ,,:!!íeart@ experience manufacturing equipment 'forthe handling, use and storage ofhazardous materials, They are built in accordance with various NFPA, PM and Model Building Codes, Construction techniques meet specifications and codes of the American Iron & Steel Insti- tute (AlSI) and the American Welding Society (A WS). Only premium grade materials are used in their construction, to ensure that Haz'Stor Buildings will perform as specified, THIRD PARTY CERTIFICATION Rremier Series Buildings are UL Classified, FM Approved, State Registered and independently QA monitored, UL Classification certifies that every UL labeled building is ins pected before it leaves our factory, These certifications are your assurance that you will be in compliance with national, state and local requirements for storage of hazardous materials, FIRE RATED STORAGE Haz'Stor Premier Series Buildings are designed to be used as separate, detached structures located inside or outside existing facilities, They are intended for the storage of Class I, II and ill flammable/combustible liquids or haz- ardous materials. Premier Series Buildings are weatherproof, vented to prevent accumulation of vapors, and may be used to store a wide range of hazardous or toxic materials, chemicals orwaste. A gen- erously sized sump provides EPA-required secondary spill containment to prevent soil and groundwater contamination, A wide range of pre-designed, UL listed and PM approved qptions is available. Delivered prebuilt right to a plant site, a Haz'Stor building generally needs no founda- tion or prepared slab, only a level area capable of supporting its weight. Haz'Stor Buildings may be relocated with a lift truck or crane, II'C< ~t' _ ;;;',:" ~~ -,~,~,~ i'" 'JJ' ilft :~.--~~ :.p- if<{~n'J,' :":.; ~~{tl " -- ~#! :'-1. -w"~b {if¡~ ~ . Either sprinkler, dry chemical or Hlalon fire protection systems are optionally available. Dry chemical tank and control assembly shown, Hlaz·Stor Buildings may be equipped with heating and/or air conditioning systems, STANDARD FEATURES A · 2 Hour Fire Rated Walls Comply with UL . Classification U425; Walls Constructed of 2" x 4" Galvanized Steel Studs, Sheathed Both Sides with a Double Layerof5/a'; Type X Gypsum Board, Galvannealed steel siding inside and outside, · Extra-wide (60'1,1 '/2 Hour Fire Rated Double Doors, Frame and Hardware, UL Labeled · Roof Exterior Seamless EPDM Synthetic Membrane Carries UL Class A Spread of Flame; Interior Sheathed with Double " Layer 0f5/8'~ Type C Gypsum Board · Interior Surfaces Protected with Chemical-resistant Epoxy Coating · Exterior Surfaces Finished in Special , Weatherproof Coating for High Impact, Corrosion and Abrasion Res~stance · Extra-large Spill Containment Sump (More Than 30% of Rated Storage Capac- ity) Surpasses EPA40CFRRequirements · Plywood Floor Laid in Removable Sections for Easy Access to Sump · Gravity Ventilation System with UL Classified Fire Dampers · Static Grounding/Bonding System · Hazard Labeling (DOT placards; NFPA 704M rating signs) · Forklift and Crane Sling Channels (8 ft. forks required) and Building Hold-down Brackets OPTIONAL FEATURES · Water, Dry Chemical or Halon Fire Protection System, ULListed · Explosion Relief Panels, PM Approved · Mechanical (Forced) Ventilation, UL Listed · Spill, Security and Fire Alarms · Heating and/or Air Conditioning Systems, ULListed · Interior and Exterior Lighting, UL Listed · Corrosion-resistant, High Density Polyethylene Sump Liner · Fire Department Hookup · Shelves for Safety Can Storage · Emergency Eye/Face Wash Station · Additional Doors · Wall Mount~ng Racks for Gas Cylinders · Fabricated Aluminum Loading Ramp Actual configurations of features and options may differ from those pictured. DESIGN AND LOADING CHARACTERISTICS Maximum Snow Load,., 40 psf Maximum Wind Load , ,,30psf(110mph) Seismic Loading, . , Zone 4 Maximum Floor Load", 300 psf Wall Structure, , . 2 hour Fire Rated per UL U425 Roof Structure." Class A Spread of Flame UL Wind Uplift Rating 1-60 Door, Frame and Hardware. ,.1 '/2 hour Fire Rated - UL Labeled, Full Swing Opening, Automatic Closure Ventilation,. ,Natural Ventilation, 11/2 hour Fire Damper- UL Classified Base Structure", 7" deep Spill Contain- ment Sump, Continuously Welded Steel, Liquid Tight, Chemical-resistant Epoxy Coated Exterior view showing optional, FM Approved explosion-relief panel. (Haz'Stor Explosion Resistant Buildings are rated at 100 psi internal pressure; panels blowout at 20 psi.) UL Classified fire dampers are provided in each Haz·Stor Building to promote ventilation, A fusible link on each damper ensures automatic closure in case of fire, Model Number ~~~¿? 29200 q!flL/ qyrS- Nominal Size (LxWxH) 8'x8'x8' Sump Capacity (gal.) Length 148 6'-8" 198 10'-8" ;";"346 '!~!¡';"~((1 ~i.:8":: Weight (Ibs.) 4900 Inside Dimensions ·:·~·fJ6'~;'·~YÊ:C~ ~.,~þ A static groundinglbonding system is a standard feature of all Haz'Stor Buildings. An 8 ft. approved ground- ing rod and cable are supplied for customer installation, Width Door Opening Height (HxW) 7' -0" 6' -8"x5' -0" 7'..fY' 6'-8"x5'-Q" ;!''f:'7':,o":,<£'ß f6~~x5';o¡, 6'-8" 6'-8" -' <~< 'Ä ..,..,-' '. ,,'-'...~',- ~ ,'/.;F,-',"I,--o ~:');,".' " ',,~,,"-'..',',',' .,,,,,,,' ,'.'-,' \",:,*,!,,;' ,<,?~,'<'-" ir,"":o:<;y;"'r-',',, .'-". 40""'1;' 'Z';'f{.i"l':S¡:r,;:¡;" ' " F-""";'ií'S1..".~,,\,,!'-' -' ¡~'-"'-7:¡'\IJ'5~''''~' ;;¡'-t''''''':'H~!!:<4¡;,' ," '-:',,,' \." ..',,:?~,,<¡;!;ë¡;"""'''', --0"..". :.....::::..~~~.~;..rL:'~~fJ~Io.~!..'¡.:~~;(!.L.'.:..,...-~...E.!k,,¡~~'.i:ßw~~~~~~:z..:J~~~~wl:~ .','. , .~. .~,.>.. ~ ~ L~! ~ ,'f.; .;~7'{;, .-~;. ';:...{·~r'...' _ _ ~~:'>~ >:i -:¡:.-::-; ,.)",::....... .' Form No, DB 2920 J90 ŒABs~~~ A Division 01 Science Related Materials. Inc. P,O, Box 1368 Janesvme, WI 53547·1368 Call Toll F,ee 1-800,356-0783 1-608,754,2345 Telex 910,288,2921 Printed in USA 'e Delivered Ready to Us~ .i ,,~ ,(, Haz·Stor Buildings arrive ready to use. The completed structure is trucked to the installation site fully erected and may be positioned with any lift truck of suitable capacity. (8 ft. forks required.) No special foundation is required, and a Haz·Stor Building may be relocated at any time. I , f!.. Wide Range of Standard Features .Give Haz Stor Buildings Exceptional Value . - - , . Haz·Stor Buildings are made in four sizes to accommodate from 9 to 27 55-gallon drums. rNe invite your inquiry about larger buildings,) Floors with a 250 psf load rating and a heavy steel drain grating around the peñmeter are standard features on all Haz·Stor Buildings. Capacity of under-floor spill containment sump is equal to approximately 20% of the total storage capacity of the building (twice the required sump capacity of 40 CFR Par. 264.175.) ··,:::,·:t::'.~~~·;~~)f'.--r~~;;~1~};'·- A metal rail fastened to the interior perimeter of Haz·Slor Buildings allows proper grounding of drums using antistatic cables, Twin UL Rated fire dampers are provided in each Haz·Stor Building to promote ventilation. A fusible link on each damper ensures automalic closure in case of fire. Four auxiliary lifting lugs are provided 10 permit positioning the Haz·Stor Building with an over- head crane, .. í o~ o 102 1/2 78 1/2 D fRONT VIEW RIGHT SIDE VIEW o BACK VIEW lEFT SIDE: VIEW ú COPYRIGHT 199 L I-lAZ -STOR COI.IP"NY F1LE NO, fEBBOOO'¡ SD-lE: 1:50 ~, ~ ~: . <- J", -------------- '-, HAZ ~ STOR HAZAROOUS MATERI....L. STORACE: CHARL.ESTON. IL.UNOIS 11'1120 COllrt~5Y of CORE.ROSION PRODUCTS P.O. Ðox 8652 Long Beach. CA 90808 (213) 596-4113 FAX 430-1058 nRE: DIMENSION IN INCHES UNLESS NOTED ELEVATION VIEWS - MODEL 29200 -- I) . COPYRIGHT 1990 HAZ-STOR COMP.4NY FILE: NO. FV880001 SCALE t:-O ê ~ -------------- ¡,~ HAZ ~ STOR ~ZA~OOUS "'....TERIAL STORAca: C~RL£SõON. ILLINOIS 0' Q:¡O Nominal Size (LxWxH).............8'x8'x8' Weight (Ibs.) ............................4,900 Storage Capacity D ru m s ( 5 5 g a I.) ........... 9 Weight (Ibs.) ................: 13,350 Area (sq. ft.) ...............44 Sump Capacity (gal.) .............200 Inside Dimensions Length.....,................... ...6' - 8" Width ................. ...........6' -8" He i g h t .... . . . . . . . . . . . . . " . . . . . . . . .7' - 0" Door Opening (HxW) ...............6' -8" x 5' Courtesy of '~ CORE-ROSION PRODUCTS P.O. Box 8652 Long Beach, CA 99808 (213) 596-4113 FAX 430-10::>8 roLE: MODEL 29200 DIMENSION IN INCHES UNLESS NOrED 93 1/2 COPYRIGHT 1990 HAl-STOR CO~PANY flU: 110 F?~8000 1 80 1/2 - 111 1 2 93 1 2 9 80 1/2 .\ Lr- 60 I -4-7 1/2 ~ n.,,¡:-'~In", ',^J ,~("'\~¡;-<;" 1ft-II '''~ ~()rFn IS ~ . w ---------- HAZ ~ STOR H"'ZAROOUS '-'AT!!:"''''"" STORACE: ' CH"'''I.£STON. 11.1.NOIS IS 11120 Courte:¡y of CORE·ROSION PRODUCTS PO 80" ¡:¡,j5,~ Lor.g 8each, CA 90808 . (213) 596-4113 FAX 430·1058 TITlE: PI ,6"') \fIFW ~¡j() n FI 29200 e I ':A~~)-,:", -í-:..- :(1ZACt..lL.. ~ . L- ~u;~.!--!l- t. - . ... .. "-..:.- _. ....-. ... . -~..- -E rl.x:><L / ¥~ S!-~ Fc..Ar-]'I<.. 7 L.- , ! . .. I I ! I . i I 1- :'" .:,.. ~~c'-- /' ::51't£~· L-I- 7 ':-- F\P:'~w· . FRAMING. ELEVATION (TYPICAL) ...--.--- -... .. -- . -... .. . , ! . .. I: !. I; , ;. : . ¡ : ,. . i ; I I· i . I: ¡: . . -. . . : I f~~~P _." ·1 - .f : i I , , - ---------- HAZ~~;STOR~ HAZARDOUS MAJIRIAL S10AAGE '":"~¡.~~ :t..: ~. r) \". ..' -. . . ~ ! ! II: . 'I' ,:. : IIi I, I I· I ij. I· I I' I . I, I I . .t' I I: I I I I . , '0 <. \..o~..c.~ / ",.- . . : '. . . - . :"- : , , , - ; <: I : S7!O~ ; ! I ! -~ : . . I ! 1 ! . .. : . e e , - '.-. -. . ..." - - -- , I ~"(.~~~ t'\...,~~ :: I If ;! ::::' . T :~; I , " I' ~:: ~ G " ' <;OOf .o~~~I....) : ~~ - r'~..J~u... (-r<pJ ________ _.:.J_ ROOF & FLOOR CONSTRUCTION, DETAILS ( \.1sa.L (. .~~~ -~r~M -;; . , r=:lcd: .- 1t'i'pn:f> ~...~ ",...,... , ~.J.(. ~~~~ I ! I Í . , I ; II I . . I I ' I ~ i , ......... f J._ .h .~'i ., ( Çl-oc~I..s{..../ £:'UT"- .- ,," &: (e."1' .ç. .~-,- . .- ~ ------------ HAZ~~5STOR~ ¡{A1ARDOUS KfJTIUAL SlOR.r.G£ -2.~~(~m e . -~ ---- -- ..---- --.- MEMORANDUM "WE CARE" March 30, 1992 TO: Chief Toler, Fire Marshal FROM: Barbara Brenner, Haz Mat Planning Technician SUBJECT: Flammable liquid storage at Atochem ****************************************************************************** The Hazardous Materials Division has been working with Atochem located at 4330 Wible Road regarding improper storage of a toxic gas (chlorine) in a B-2 occupancy. Atochem has elected to remove the chlorine from the facility rather than to improve the occupancy to an H7. During my inspection to verify the removal of the chlorine, I noticed that this business also stores substantial quantities of flammable liquids. A product known as Api Luster is a I-C flammable and about 1200 gallons were in storage. This fruit wax is stored in 55 gallon drums and is not dispensed or mixed on site. Atochem's hazardous materials inventory indicates that the maximum quantity of Api Luster at this facility could be 2400 gallons and the average quantity is approximately 1300 gallons. Storage of this material is seasonal due to demand. The existing inventory will soon be sent to another Atochem facility in Northern California. Atochem (then known as Pennwalt) established this facility under the 1976 Uniform Building and Fire Codes. The building is a sprinklered, B-2 occupancy. I am unsure if this storage would be considered existing nonconforming. Because flammable liquid storage is regulated under Article 79 of the Fire Code, Ralph recommended that I refer this location to your Division for follow up. cc: Ralph Huey " I \, ·1 ';'; CITY OF BAKERSFIELD HAZARDOUS MATERIALS INVENTORY [] Farm and Agriculture 0 Standard Business pageLof I NON - TRADE SECRET ~~~~~=, NAME. 7r~~~ CITY, ZIP: ~~r: ~e \ò.. {\ PHONE #: OWNER NAME: ADDRESS: CITY, ZIP: PHONE #: NAME OF THIS FACILITY: STANDARD IND. CLASS CODE: DUN AND BRADSTREET NUMBER/FEDERAL ID# - - -- 1 INSTRUCTIONS FOR 11 14 Names of Mixture/C See Ins (O(:~ hysical and Health Hazard (Check all that apply) C.A.S. Number Component · 1 Name & C.A.S. Number component · 2 Name & C.A.S. Number Component · 3 Name & C.A.S. Number I S<iR... Component · 1 Name & C.A.S. Number Component · 2 Name & C.A.S. Number Component · 3 Name & C.A.S. Number Sudden Release of Pressure ~ Reactivity 'Pi Immediate 0 Delayed Health Health Physical and Health Hazard C.A.S. Number 4'17- I']-l(¡ (Check all that apply) o Fire Hazard 0 Sudden Release 0 Reactivity 0. Immediate 0 Delayed of Pressure Health Health Physical and Health Hazard ,C.A.S. Number Component · 1 Name & C.A.S. Number (Check all that apply) 0 Component II 2 Name & C.A.S. Number 0 Fire Hazard Sudden Release 0 Reactivity 0 Immediate 0 Delayed of Pressure Health Heal th Component · 3 Name & C.A.S. Number o Reactivity o Immediate Health o Delayed Health Component II 1 Name & C.A~S. Number Component · 2 Name & ,C.A.S. Number Component II 3 Name & C.A.S. Number 12 24 Hr. Phone Name Title 24 Hr Phone Physical and Health Hazard (Check all that apply) o Fire Hazard 0 Sudden Release of Pressure C.A.S. Number EMERGENCY CONT~CTS 11 Name Title certification (READ AND SIGN AFTER COMPLETING ALL SECTIONS) I certify under peanlty of law that I haver personally examined and am familiar with the information submitted in this and all attached documents and that based on my inquiry of those individuals responsible for obtaining the information. I believe that the submitted information is true, accurate, and C~Pl~. c, fe('b-er ~ FICIAL TITLE OF e Bakersfield Fire Depte HAZARDOUS MATERIALS DIVISION Business Name: ftr-bch U"fL, 1330 {»I'YJLt- KeY 381 Date Completed 3/;2(P/Qz Location: Business Identification No. 215-000 Station No. ~Cø; (Yttvr Shift (Top of Business Plan) Inspector í3~ Verification of Inventory Materials Verification of Quantities Verification of Location Proper Segregation of Material Comments: Adequate Inadequate D D D D D D D D D D Verification of MSDS Availablity Number of Employees Verification of Haz Mat Training Comments: D D D D Verification of Abatement Supplies & Procedures Comments: Emergency Procedures Posted Containers Properly Labeled Comments: D o D o o o Verification of Facility Diagram Special Hazards Associated with this Facility: ~látibÞ$: G(:~?lO()S cý\lor'-N(0 KeJV1o~ FY'b~ D((/ý·~·S. L{Å«(f Stolh(f- ~:nl~ J..~ ~ &, (Å !I;atJr,'~-j ÆCWO~ . K';¡P't~ --;I'e" . - r¡ (.,~ r/'&-I 72 £; f~,v¡ -¿.. '~''-- , All Items O.K. D Correction Needed D " Business Owner/Manager FD 1652 (Rev, 1-90) White-Haz Mat Div. Yellow'Station Copy Pink-Business Copy -~-FDOOOO9--, Account Number e e ACCOUNTSRECEWABLEADJUSTMENT M;1TC"h 6 r' 1992 Date . Valerie Pendergrass From: Fire Department - Haz Mat Division Department/Division New Account I New Address Close Account Service Change I Other Adj. I Atochem N .A. - Decco U. g,. Billin 9 Name 4330 Wible Rd., Bakersfield, Ca. 93313 Billing Address same Site Address Parcel # (If Applicable) Landlord Name & Address if Applicable ADJUSTMENT I Last 1 I Billed' i ~ '2,922.50 \ I I, I i I ! Correct I BilIin g , ¡ $292.50 I I I i j ¡Adjustment ¡To Billing I i Effective Date 10f Change : ¡ 3/1/92 I ' ! Approved By: Remarks: Keying error. -, ------¡-- :? ,- ;¡. .. e "WE CARE" CITY of BAKERSFIELD FIRE DEPARTMENT S, D, JOHNSON February 25, 1992 FIRE CHIEF 2101 H STREET BAKERSFIELD, 93301 326-3911 Jerry Achterberg Atochem North America, Inc. P.O. Bðx 174 Reedly, CA 93654 I Mr. Achterberg: The plan dated 2-20-92 outlining Atochem's decision to remove gaseous chlorine from the premises of 4330 Wible Road is an acceptable form of compliance with the Uniform ,Fire and Building Codes. Please use the enclosed inventory form to delete the chlorine from Atochem I s hazardous materials inventory for this facility. As we discussed on the phone, Bakersfield Fire will conduct follow up inspections to verify the removal of the chlorine. The removal of the gaseous chlorine fulfills the requirement for preparatio~ of a Risk Management and Prevention Plan (RMPP) at this time. If storage of chlorine is resumed, it will be necessary to complete a RMPP. The document submitted by RAM Environmental in 1991 was a hazard analysis, the basis for a RMPP. Because Atochem occupied this facility under the 1976 Uniform Building Code, to date we have required an upgrade of the facility only to an H occupancy. The current Fire Code is much more stringent regarding the storage and use of toxic gases. Among these requirements is the capability to scrub, treat or neutralize the contents of the largest container. If Atochem submits a plan to resume interior storage of chlorine at this facility by May 25, 1992, Bakersfield Fire will review the plan as existing non- conforming unc~er the 1976 codes. Plans to resume storage of chlorine at this facility outside or those submitted after 5-25-92 will be considered new storage and reviewed under the 1988 Uniform Fire Code or the 1991 UFC if adopted prior to submittal of the plan. .-- e ~; '!; - .~....-- The Hazardous Materials Division is willing to set up a meeting with Atochem, your consultants, the Building Department and any other appropriate parties to discuss the requirements for compliance. Please call me at (805) 326-3979 if we can be of assistance. Sincerely, ~~O^Cc--- ~~ Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Jack Leonard Di'::úJ7XC Ú9"j¡.t\4Ö ~ cµ,.S It If<r oJ! ;:/. AChtirbt1j d»n·"~{..-f ..µ,O-+ ~JpebhßW\- ?J/~/qJ-.. 0 AcJr(;r~~ ~~í~S 0?¡0 --/ a ~ (j1 ~r('rIG 5fvNt'ð- 0 r~ )JN2 cr:r 5/2-5/1;1. '-fhc<-r ,jh¿ £('j/-i~ fr¿ Cob w' LV fµ ~1«C4! . 73 /l7- ¥:l- 1f¡Z. · e ~ ATOCHEM NORTH AMERICA elf aquitaine RECEIVED FEB 2 it 1~~2 Ans'd.......-..-- ATOCHEM NORTH AMERICA, INC, P,O, Box 174, 21491 East Dinuba Avenue, Reedley, California 93654 Tel: (209) 638-4470, Fax: (209) 638-7796 Barbara Brenner Hazardous Material Planning Te6hnican Bakersfield City Fire Department 2130 "G" Street Bakersfield, California 93301 Phone -805-326-3979 February 20, 1992 Dear Barbara, In answer to your request, for a plan to be submitted by Febru~ry 22, 1992, to bring this facility into compliance with the Uniform Fire and BuildihgCodes, for the storage of gaseous chlorine, it will be delayed until futher facts and information can be obtained. During this delay and until submission of a plan, or as the action of mandatory relocating of our present occupancy may be required, to be relieved of the City of Bakersfield enforcememt of the Uniform Fire and Building Codes, we will cease to stock or store full cylinders of gaseous chlorine at this site. During this delay, we will make every attempt to futher evalute and solicit help, to obtain the correct information, to submit a plan for compliance of the Uniform Fire and Building Code. At this time we feel there is not a clear understanding of the determinatian of the code. I have found a number of various interpretations concerning the B-2 building occupancy, H occupancy and the Uniform Fire and Building Codes. With futher help from storage container manufactures, and other representatives, we intend to come up with a plan that will be feasible for us to be able to submit. It is my understanding that the previous submitted Aisk Management and Prevention Plan (RMPP) will be accepted, with the plan to cease storage of the gaseous chlorine at this ~ime. As mentioned before we plan to continue to evaluate the actual feasibility of any modifications of the present location, and subject to. the approval of our landlord, and approval of a plan that meets the compliancy of ths Uniform Firs and Building code. cc: Fred Serr Art Dawson ~re~ ~Jer~y Achterberg The heritage: r:eMw1 and M!!r The future: ATOCHEM NORTH AMERICA SEP-16-91 t'10t-~ 9: 56 e e P.01 ,~ (±'..r''¿- ./ . / \ \ \ ~ D U V © IF @ ~ [~ ~ l~ ~ iF ~ ~ ~~, [?5) cC ~ (L ~ Wi ~ i)~ J~ U f1\ ~£l1 ~fXjC~:[ë: rc~;\ r:rðrf\'~\\ c!;,,»{);Lf\úJ~'(B ~y.. \l>';':~l.bf)~u ~:..,~ -. .:/ \:'w1i ;''V'I.:::/ RECEIVED ~EP 1 6 1991 HAZ. MAT. DIV. [B ~D ~ ~[¡j) U ~ CG] ~t L:~~ lM ~ :; @J s ,vn n !oJ.o n fr't" \ \\/J!1(rrtJ foi;Vl C:::~ ~:-j\..u.J lQJ ~. \.~:; VV \.0 ..:~ ~.~0 I " u~~,Œ;t:(Q)rÍ2;~~~(,:" ','~~~t'\\«J[2~, ')1\'- I ¡('!'-;,¡ J f ) " f I' - + :,'-:/- 0' î ,S~ ,,\L, It. & îs If:: [;0-;3 ~J \J I]' ~~ }" (¡), @; :ô)l()\~~l;(š~;i ri~i" ',,' "'run ~ \.... !. .;'."}--2-- Lr ~VQ..o~).J v tQJ i.:=L.:= lJ I.Jdl::. I\! ^ J\!i f,; 1</, '{" YL:L( f.JÛ-, fó £¡î n '~ ,..~ f ^ t Ò L~.'> L ,r VJ '---'" ~,..,,~- ...... - _ .v____ (./ f ~¡»;! ---.~r r'OV1i,~t':\.¡V/O['1G:('N~'lA"C¡>IOÀ" tV, . tL....- '//L4;/1 ~p I . }'.~l'.: I ·Y.' ,~.; ~........ ,'\j.--.~_..,--.._~_l.-.....-....___~{L<" ~ ~Î Jj .., I' ¿C l :-;:. , / ,':.' ~ L~_~~,~~_ ~'o-l J ~ \ .),. r _L-__~ --~ ~'A}{ :\;0. SL~~\!D~NG :V;S:SS,'4G~ '~'o: i, .\Ai"!: ,-;: fi . ¡: , " fil:~¡P' ~-- ~ L.!U'-,I,:,-" " all)(,, ,; ,/ ;/1-1)' /; L - '._/ !" 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(;Ý CalifQrniSl. 1 Bu Id"'9 D3,m'1 ¡. tj¡t,/. \ )... -4 ~ M'i12 ') ~ \JngQfZ1;un<;] ,hG~ ¡-; I ",,,,ploy \)711;1<:11'10 0" ~ÖI'\"?b)C~ \M~ñ ¡¡mvon" ~o pe~form - ~ ,. I; tho oì:lO\lO wOflt ~h,,~ ~hk pG-:'¡'¡ji~ ¡;;1Q1I bø deømeci vøvDI((,d until ,uch ël"c.~. FcrlT\i\ C! h1 ~! ¡ \lj _ ~15¿j¡° ~ ~Im(, QG <:J Ccwtl1lcÐt41 of WC,kCi'J' CQmpoolV'tlon Insumnco by IIn _.~ ~ IV i--+-f!., ~.- I' cdmlttü<l 'nuuror, I)r on O)<()Ç~ çf¡p'! Of Guplr.::¡;¡~CJ ~",,,,'~"1 cOfti11ød by the ...£:.I!i.r!.!..9:~!':ª-~.!!... _ __ -4l-I(Zf),- ..;ì3-J: ~ ¿, _ ,¡ g:~:~~:~. 01 !ncluc'ð'lsl R31Qtlono or ~h3 Inau7:Jr 10 flied with the BuildIng M"ch, Porm.' _ hi JlJ'¡tkJ _~'.' ,ç¡¡ l!?L__ J~W..k. ¡ _ ': rJ I h~IIO 111",eJ wl~h ~h3 18l.!1I~lníJ blrecwr [] C::>7~11IcQte of Worker.' <'f' ~ry- .IJI-{:F' ~ " eOmp31'\~'[on ,n3U7cncs bv £n cclml'tt¡)d In5\!VC1, 01 an eXQct copy of ciupilcC'l0 tÌl0r0:Jf csni1!cd bV 'Ih3 QI7ccîor Q" I nÙßtrlEJ fjølatlon5 or the Inour21. C/ /\, 3, ¡:¡:, I-C, ;, M, ~, ;;!!, ~U , 3, 4 COM MEA C ¡ A ;" '.:,c b0eiJ~'1.Fire z,)n~.3.....,.... Dct:,..~::..:Z.T~èp" còno,:J:L.If.>J" " / / 1,) I (q.) 'f)!""! ~:::-""""'--~,,""=c-L.-;:::W:> BUil.lIJûNG .,,-~~ ". '"' B.~d~~!!.'-~r ~___',-_- :.ire;: /\rE~ Or I'JISiJ1,JlrU!Jl;Q~ ~~~ ~l. ~CT~ j (;ß1\l\" '__Jî_;C :~ ~"'J_ .._____-Sjzt' SGrv. Wire -_....u.... .___._Nø. __... _.___ ·~!...::,t' __PhaiiÐ NO, Circ ~_",-.,.~ '.~~-~ t."· -,I.. . ~~ ox\. I r ! H,turo~ ,!\o n pj~r=-l·tt:ta1;;)t Lt·v....<;:orL_ .fUn.L... " Ulin(;1 _ W Xc,,, j ."",,~-,,-,~-,..~,,~~~--,-, ,- _.~-.. Jlt-J Lin:: I ' ..=.-f1. TOlal Foo ....:.1 :'1> Lliï(.; --.l¿ '~ --~_//~ - .--- _SI¡)n Pi?rmit --_,._ __J,_ ' \ Approved BUI [,tl~G DIAËCTOR }- 1 ! By-_,.,.c_ I Data -~-õ' h t -- '.$'~ '\ e, P.02 1° APflUCAiW! TO 0 HÆt ~ ®IEGW~~[\J_t"=~~VV liNES A<jdre.~ ~~. ~ {ßJ~ ~ 0 ~::':- :::,..:;"~-:~!,-~=~ Q !!~,M~d~ ~- - -. .------,.------,..- ! M~~_, _r~~_s__~J).-l,/)J"M"'J?~!fid-- City ~-¿<~~~-..-!-a~. No /!.Æ~,:f!/o-2 g § ~-_Á_~,~I4-:ß --. -----..,,-- ~ '5, M&II Adci'9.5 a@O·(}f; ~~'_~n .{ ill C,IV ~ß~~ -,-? '_ '. _,';,ltl-=iJ)t:l1 g NAME ~{~¡g Ufl-:!.ßl ~ ' __ ~_/~___ u ~ ~7 /rrJ:'" I E Mal! Adº!..~5~ -d. ' 2t..~!:..__ .2.,____ ! CiW Acr~k.-{'cfr~/L"'¡¿ ,.J:e'. ,\ Q,,:i:?}.::::../T6 q ~ ~~='W Sr,,19 Lie. No, 1./l'tJ:5;'· ð .__ ~I" j d~O" NAMI: ! Mall Ad.!:i!:."~J...~_----- CltV .·'0. '~ (tASS ür (i\!O~tc{ ii- i"~"~-~+-¡ Der~~!~~~___.__,__i.__J,v;(h:; _C~ il ,..!:.~,~~_!ion !_=r:Rt;t~~_I,!,'C!Üi~'1.'1_____ .L ~ __ ~~:îcr~~,~NEQí!!VìA'u'.:Ü~. ____ ~ Slened thlD _ GOY Of (J¡¡!<.ç¡r¡¡flold. C¡¡fornl... .1Ð_ 8t Owner BP-·OHl 1. ,. II e <1 !./ ,~, , /~_ -9~C~/v. ~~- ,,>-~ 'F¡¡¡ ~l> ~~~~~/ ~y I ~.n "'-;~-~~: ~-- A 'V-? f"" ~~;-Ö·~<~_ 1P9< ?" '~' ',' _ "'~~-~/V .' .- CJ T,Y 0 F ~!Z\ W? 1EfE()~TÞ)7~f(V L,,¿!!JG!S'G l.6 ¿j,~ ~ u d ~ ~ UJ/ BUILDING DEPARTMENT C, A, BIDWELL, Director February 6, 1992 Jerald Achterberg ATOCHEM 4330 Wible Road Bakersfield, California 93313 Attention: Jerald Achterberg Subject: Hazardous Material Storage at the ATOCHEM Site Dear Mr. Achterberg Per our phone conversation today, I have determined the maximum quantity allowed in a controlled area for your proposed B-2 occupancy. These quantities are as follows; Material Hazard Chlorine Oxidizing Gas/ Toxic Gas Calcium Class III Hypochlorite Oxidizer Cleaning Corrosive/ Products Irritant Flammables Class I-A Class I-B Class I-C Combination of Class I-A, I-B, & I-C Maximum Quantity Per Containers (1,213) 650 ft3 10 lbs 500 gal 30 gal 60 gal 120 gal 120 gal ---------- --,------------ -- -.---- 1. Quantities may be increased 100 percent in sprinkle red buildings. 2. Quantities may be increased 100 percent when stored in approved storage cabinets as specified by the Fire Code. When footnote No. 1 applies, the increase for both footnotes may be applied. 3. You may have a maximum of 4 containers on your site. 1501 TRUXTUN AVENUE BAKERSFIELD. CALIFORNIA 93301 (B05) 326-3727 ·:.¡ e CI.T"Y OF e~ ::'-;>.- "/ -0> ~, l'! " BUilDING DEPARTMENT C, A, BIDWELL, Director >.0/ ,,' _/~c>~ ,_ _ ;7;4(;; ~ ,~~~(,- ~, 1 ð O· -~_O=- f- ! -" -~ ~c~ _ ' [85 A 1& IE IR S IF IT IE IL [)) Different types of materials may be stored in the same container as long as the maximum allowable quantity for each material is not exceeded. Controlled ,area storage containers are require to be made of 1 hour fire resistive construction. The above are the basic requirements of the Building Department based on the Uniform Building Code. You should contact the Bakersfield Fire Department for other requirements which may apply. If you have any questions or comments, please feel free to contact me at (805) 326-3718. Sincerely, ~/)/) /1 , "/-/l 1/ \ ,/ ''-7' /. . C·O\~--- Jack Leonard Civil Engineer III cc Barbara Brenner Bakersfield Fire Department 1501 TRUXTUN AVENUE BAKERSFIElD,CAllFORNIA 93301 (8051 326-3727 " '~ ~,~~'" ,e e CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S, D. JOHNSON FIRE CHIEF February 5, 1992 2101 H STREET BAKERSFIELD, 93301 326-3911 Jerald Achterberg Atochem of North America, Inc. 1525 E. Noble #300 Visalia, CA 93277 Mr. Achterberg: On September 16, 1991, notification was sent to Atochem District Manager Fred Serr that use of the Atochem facility located at 4330 Wible Rd. for storage of gaseous chlorine is a violation of the B-2 building occupancy permit. Atochem was given until 10-31-91 to submit a plan to bring this facility into compliance with the Uniform Fire and Building Codes for the storage of gaseous chlorine. Bakersfield Fire then extended the due date to 12-2-91 in order to give Atochem more opportunity to research possible options. ' Neither the Bakersfield Fire nor Building Departments have received any plan for compliance from Atochem. The Building Department is awaiting submittal of a site plan and the specifications for the hazardous materials storage containers which Atochem proposes to use for provision of a H occupancy chlorine storage area. Atochem must submit this plan to the Bakersfield Building Department by February 22, 1992 or enforcement action will be initiated. Bakersfield Fire suspended completion of Atochemls Risk Management and Prevention Plan (RMPP) pending the Company's decision regarding modification of the facility to a H occupancy. The date set for submittal of the occupancy compliance plan, 10-31-91, was the due date for the finished RMPP. This date included a six month extension of the original RMPP due date. Extension of the RMPP due date had been granted to allow Atochem time to evaluate the feasibility of continuing to use the Wible Rd. facility for chlorine gas storage. Failure on the part of Atochem to submit a plan for compliance with building occupancy requirements will also result in enforcement action for failure to complete a Risk Management Plan within the one year allowed by law and the six month extension granted by tHis Administering Agency. '" .( ), ~~":~ e . As we discussed on. the phone, the distance limitation to exposures for toxic gases stored outside is 75 feet. I have attached a copy of the 1988 Uniform Fire Code requirements for exterior storage of a toxic gas. Please call me at (805) 326-3979 or Jack Leonard of the Building Department (805) 326-3727 if you have any questions regarding the plan for code compliance which must be submitted by February 21, 1992. Sincerely, Sd~~~ ~( Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Jack Leonard Fred Serr ;;> e e CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S, D, JOHNSON FIRE CHIEF 2101 H STREET BAKERSFIELD, 93301 . 326-3911 November 15, 1991 Jerry Achterberg Atochem N.A. - Decco U.S. 1525 E. Noble #300 Visaliay CA 93277 Mr. Achterberg: I received the material safety data sheet which you sent us regarding soda ash. I reviewed the information with my supervisor, Mr. Ralph Huey, and he has indicated that soda ash is a hazardous material which must be reported on the inventory for your facility on Wible Rd. Products for which MSDS are prepared and issued are hazardous materials. Under Federal OSHA guidelines, MSDS must be issued for materials which contain 1% or more of, a hazardous material or 0.1% or more of a carcinogen. I have included a blank inventory form which you may use to add the soda ash to Atochem's haz-mat ~nventory. I have also included a copy of Ashland's MSDS wi th the specific hazards of this material highlighted. This inventory addition will be due on 1'2-15-91. I also need to remind you that October 31, 1991 was the date by which you were to have notified Bakersfield Fire of a plan of action for correction of the occupancy problems at 4330 Wible Rd. Please contact me immediately, at (805) 326-3979, regarding Atochem's progress on this matter. Sincerely, ~~rc-- ~~~ Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey e e MEMORANDUM "WE CARE" October 18, 1991 TO: Jack Leonard Building Department FROM: Barbara Brenner Hazardous Materials Division SUBJECT: ATOCHEM (pennwalt-Decco) occupancy rating 4330 Wible Rd. Ralph Huey and I met with Mike Quon regarding the appropriate usage of this B-2 occupancy. We determined that the amount of chlorine in storage exceeds the exempt amounts under the 1976 code, in effect at the time Pennwalt moved into the facility, and also exceeds the 1988 codels exempt quantities. Because Pennwalt has been out of occupancy from the beginning of their use of this building, we have required that they upgrade to an appropriate H occupancy or decrease the quantities of hazardous materials stored. Recent revisions to the hazardous materials inventory report far more than the storage of gaseous chlorine. The hazardous materials inventory and material sa~ety data sheets for the Pennwalt facility are attached. I have evaluated the chemicals listed on the inventory according to hazard and the exempt quantities allowed by the Building and Fire Codes. This information is attached. In addition to the toxic/poisonous gas, pennwal t is also out of occupancy regarding their storage of flammable liquids and oxidizing solids. Because these materials were reported for the first time on the inventory submitted 10-15- 91, it is appropriate to base the exempt quantities on the current code. It appears that to continue storage of all the materials reported on the inventory, Pennwalt will have to meet the combined requirements for H-2 & H-7. I have indicated to Pennwalt that portable storage buildings are available commercially which may provide adequate occupancy separations. They may submit specifications for such a container to you in addition to seeking information regarding the possibilities for retrofit of the existing structure. / # ¡,...... ,.. ~.:f."_~«.:.~~# e e ~ . -~- --- -~~--- Let me know if there is any other information which will assist the Building Department in determining which H occupancy is appropriate for Pennwal t' s chemical storage. Be sure to check over the exempt quantities and hazards to make certain that you agree with my conclusion that an H2/H7 occupancy is appropriate. MATERIAL HAZARD QUANTITY STORED QUANTITY EXEMPT (B2) 1976 - 0 ft3 1988 - 0 ft3 (UFC pg. 331) Quco1T ST(lv 5C{I)'1 1988- 20 lbs IC}SI - 2ù \ b5 Chlorine oxidizing gas toxic gas poison A 26,250 ft3 = 5250 lbs I __,~__.._ ___ _0--- -- .--- Calcium -1\ hypochlorite 65% Class 3 oxidizer 500 lbs ~ ~( Ur:c APPflld,l V¡- It Cleaning products: corrosive/irritant 920 gal 1988 -1000 gal It:¡~1 ~ IOD()~p<1../ /' , Deccosol 122 Deccosol 125 ApI Kleen 246 Deccosan 315 Deccosan 320 220 gal 240,gal 240 gal 110 gal 110 gal I I \ \ \ ~ Flammables: I-C 2420 gal 1988 ** \ Apple luster 221 2200 gal qa) Apple luster 225 220 gal Sprout nip I-A or B ? 30 gal 1988 IA- 60 IB- 120 gal ** 1988 UFC and UBC are inconsistent regarding the exempt quantities for~?lammable liquids. ICBO recommends using the 1991 UBC exempt quantities as a nationally recognized standard. The maximum amounts were calculated based on conditions at the facility currently. The building is sprinklered and the materials are not stored in cabinets. , I I cc: Ralph Huey ~l1Y ur öA~tK~ritLU - fl HAZARDOUS MATERIALS INVENTORY RECEIVED f.'1 .nd ArtiC'uTturt!O St&~d.rd Business ~ NON-TRADE SECRETS OCT 1 5 1991 i'!~~ _1__ , ?US, INE,~S NAME: Atochem N.A.- Decco U.S. 'OWNER NAME:, Atochem N.A. - Decco U.S. NAME 0é THIS FAClfl,TV~. Atochem. - Decc.Q.., ___ ~OCATI N' ~~~2 ån~f ~o~~ A~RES§' P.O. Box lLO STANOA 0 INO Cl ~nl DE: _.u~ZB.79_ - . . , --- 5¡I/Y~ ~Þ: I d lif 93319 ~I Vt a~P:_.J:1QnI:~óC::l1if. 91017 ' DUN AN BRA,DSTR,!E N'ù ~ . , ON . 805- ___- ----, , R ~R TOJrNPRàt!fttjR~ tUn ",ROPER CODES Q Q 2 2 ~ Q Z Z J ¡ 12 J . ~ . 9 10 It U, IJ U ;Ir,ns 'nl till . Is Cant Cant Cant Use loe,tion Where 'by NellIS of tlllt\lre{Ccrcor.ents ¡Code Cod. Alt 011 t. type Press reaø COd' Stored In facllltr n See Instru: Ions r U P 26,250 365 04 2 4 08 N.W. Corner 10 Chlorine I : .Çh~SiCtl tnd ~eflth HI,.rd 7782-50-05 COllponeøt II N.I. I C.A.5. NUlber 4~ 1 I h I t I' C\J;0.ír5(\\,. ,L., ' I' ,ee. · .pp y .' 1- J / J : r.t COllpOllent U Nal. I C. A. S, RUlber ~i· Fire Haurd 91.:lctiYity",,' 0 O:~l/{: (5j $Ud:rpf:i::,: f.I II~eedNt\e . COlponeat U ,/ )¡'JjVror Nale . C. A. S. NUlber ..7 yo'5'v ¡ U M: 500 t ' ¡PhU i cJ I fod Hea mMllard ¡I t;het' I , that l,plU . ¡ , j I U fire HazlfdJi 0 leactiYltr Ia Del"ed [] SUcfd," leleas. He, tb 0 Pressure , I i I !. U M 220 r :PhUicJI 'lid He,ltb M'I". C.A.S. NUlb.r ¡ (Chect . 1 tha, a,~I, 1 I [] fire H.urJ [] InctiYitr 0 oe"l" [] SUcfdr" RelelS' I "HII t~ 0 Pressure 4 05 Center West Side COlponellt" Nale' C.A.S.Mulber , .f D't;~'~ n f COlponlllt n If... I C.A.S. NUlber 1 !,¡II llud at. 0 ' Hea Itb COlpoR.nt'3 N... a C.A.S. Itulb.r 20 Center Area Co.ponllt" ...., C.A.S. NUlb.r ¡ ,.¡L ITI . Co.ponllt U ..... C, A. 5. NUlber to((O~:r, (\.\: ~ r..edllt. ,,((.v- Hea I t. CO.POII..t 13 , U 240 ¡Phl.iCf' f,d HI,Itb "I,r. : (eltec I I th.t .p, r ! i [] Fir. H.,lid [] '..ctf,ft, 4 20 Center Area COIþOllllt.. N... a C.A.S. N\llber; L ~ I [o(rCF \ ! ' )(A(I-'\ h.. a C.J ,I. Iu.r ',((\ £] D.I.,.cf [] Slcfdt. .".... HII t. of PrlSlur. IUI Coaøon,lt U ~ laled ,t. He.lt. ¡ COIlOllllt U .... Ie, A. S. Ifulber i ! ¡ , :EHERGEHCV,COHTACTS .1 Gerald Ratterson" f ~ervice Rep. 831-7611__u .2 Kirk Stdrms ! Itlt· T t fflIrma--'1II T !ttific.tioll lRe~d .nd Iffn afîør Ci:l~ti(Jg Itll rcfl.ctionS) ! certlff uM., O,".nl 0 I., nit I.IV per SOli. I, eUIIII . 'I fI.illlf wit the Inforutlol ,ublittl4 III this ,nd UI ,:t.ch,d docvaellt, 'If t .t D.I.' 01 I' InQuir" thos., "I UI I responslbl' or obt.lnìftt t~. Iftforllt,ol. I b., 'I thlt thl JbllUed IlIforl.t 01 .. tru., ICC,.,.t , an. coap It.. ~ ., \ . I. :::Jérr :c +-e-ro -en (t"\1 'f'J tJ" ~t'(l}1 C~ finRõ v mTñtlt I vi II o-r.! ,~' o Calcium Hy ochorite 7778-543 (0'0 ~ Calèium H ochorite '--'\-~---'~- concentratV henol Detcosol 125 Concent te 1310-73-2 Sqdium Hydroxide 90-43-7 13 2 Orthophenylpheno1 6834-92-0 5 Sodium Metasilicate iervice ReD. nr. 832-6602 ll1frnðf'i /i~- Ll'Y ur ~A~cKðr~~LU HAZARDOUS MATERIALS INVENTORY fir. and A'.:iC(I~~: [] Stl~dlfd Business 8 NON-TRADE SECRETS f4;l ~_ ~3 ¡ ';¡JS1N€~S NAHE: Atochem N.A.- Decco U.S. OWNER NAHE: Atochem N.A. - Decca U.S. NAME ~ THIS FAClfITVò' Atochem - Decc.Q, _OC TI H' ~~2 8i~~f ~o~~ JDjo RES~' P.O. Box 1.20 STARD 0 If40 Cl S C Ofl __ 28.79_ _ ,. }jb~t !Þ:, _. -Í d lit 93319 1 Yt j~P:_~~ócal if. QI017 OUH AN BRAOŠTR!E NUH8!A . . -,- ---- ~ to-¡,.¡ypRòt!f/tJtI$ tUN fJROPER CODES Q Q. 2 2 j Q I Z J , J. f I , 18 II II 11 u 'r'''1 1111 hJra,. 'r' Cont COllt Cont Ust loc,tioft WhUt 'h 1(a", of "utiJre{C:'c~rents Cod. AIt.t 01 t. Typ. Press re.. C04. Stored II fJc:llltr Wt Su Instru: Ions ¡ U M 240 07 4 08 Center Area A 1 Kleen 246 ~hrsic.' fnd ",,It_ M'J". Mixture COlpon,"t II KIM I C.A.S. IUlber '~ 7664-38-2 , IChec. . I th.t ,,pI, co{(D'ð' 50 Phos horic Acid 27176-87-0 15 Sulfonic Acid 67-63-0 15 Isopropyl ~lcöhöl / Deccosan 315 Sanitizer~ 68391-01-5 N Alkyl Dimethyl Benzyl Ammonium Chloride o Fir, H.lII' e () ,uctjyitrj ~ ,. Co.pallllt" .... I C. A. $. lu.ber W> llltedllt. "ealt~ CO.pOllltt u ..... C.A. S. Jlu.ber o Dellr'd () SlIdd1I ','use He. t. 01 Pressure U M' 11 ~hrsic,' fOd /f.lm f'f.r. . ~"lCi I I tb.~ 'PJ , Mixture 4 24 Center Area. Co.poII,.t.1 .... I C.A.S. Hulb" : éor(íf):'If, n f CO.pOlot" .... & C.A.S. lu.., w I..ad .t. Heal t. CO.,OIl..t n .... I (. A.'. Jlu'" CJ Fill H.Zlr,1 : (l'uc:tiYltr ~ O"'Yd (] SaU'.,.I.... H.,lt. II Pr,ssuI' U ,v{, . ((oz} [.0 4 24 Center Area COIþOllllt" I.. Ie. A. S. lu"" :hUìc,J 'nd He,m faru. I tll.e' · I t.., ~ II 1 o fire .anrJ 0 ...(tly't,. Mixture EJ De'.y" 0 s.... '.'IIH H"I~ .f "lIllIre fa!: I (OIpollltt II I.u I C.A.S. lu,", III I_d ate h"~ ' C..1It II ... I C.A.S. lu"" ;rE&:~rr,tt't~:rI~:'f;III' i ' (] Fire N.n;' 0 'tacthtt, 18 07 ' Center Are Mixture (OIIGlut II ... & C.A.'. 'UIW I .¡(,., (.¡ ,:;- ç('-' lit f COIfO_ II I'u' e..... Iv'" ý'(N (] O.hY~ (] SIddø,..,.... IQI ''''H.d.Jtte ,i H"'Witf I rill'" 11~' CotpOllrt.J ..... C.A.'. lu"" EMERGENCY 'CONTACtS . "~erald Ra~terson' T't~ervice Ren. ~ .2.niirk St4fms !(tifiuti,. fRrcd .nd - f,n .'fer Cf:l ~t jOg .11 tect ;on.} , ¡ . , ~.(rll, .ø~ "'"M ra, C..f I .'Y "(1011 'Il 'I'" . f' ,..i'llr ,It t" '.rorlltJ" ,.blltttl I. f." .Id ." .£I('hd doer'" r, r ,t I"" It " IIGII'" MI, I mat. I..ponlb'. or obtll.i., tae ,dol..t'o.. "'"IIY' t..t t~. . ,~.lttN "01" . . tl". Kurate, ... co., .h. , : I '·Jerald¡ Achterberg A~a. s. 1 .s....~v:i.cg 'i~flc..t (1(11 It cwttr/o,."Uf III a~II.'~dM'tII''1-ntlOrll" rtlftSlIlUtlwl $TJilml , 5. s (\- (k\~'1.lQ.;('('.O..~, Q;~~'01~ ; A-f'îMòhìJr<\ c\'\ (~ óJ25 v I 3 Deccosan 320 Sanitizer 68391-01-5 Quartanary Amines Surfactant Mixture Neutron x 656 Detergent Mixture Perma Kleen lOO 5 2.7 A 1 Lustr 221 67-63-0 20 ~sopropanol 1336-21-6 , 2 Ammonium H droxide 110-91-8 3 Mor hbline r"Service Ren. 832-6602 .TI 11 Rf11fr' mnr'fj'- LilY ur ~A~tK~~~tLU gHAZARDOUS MATERIALS INVENTORY f". .nd A9,ti.Çdµ;' f) Stand'" Business ø ", . NON-TRADE SECRETS r!;l _J__ ~ 3 , ¡ ;I)SINE~S NAME: Atochem N.A.- Decco U.S. OWNER NAME: Atochem N.A. - Decco U.S. NAME 00 THIS FACl~ITYò' Atochem - Decco _OCATI N' ~ê~S ~i~H ~o~~ ~WRES~' -L..O. Box lLO STANOA 0 IHO Cl S C OP- ZBJ9 -.-, :M)~~ ~Þ: 805- -I d lif 933]9 }fPii a)~~Æ~~l~~ q:~~PER :::5 BRAgŠÓR~E2 ~U~8~Å~-I I J ~- ,. I J f . , 10" 12 U U 1'4"1'" . rf Cont Cont Cant use loc,tjon Where ,by Na'e5 of ll1t~relc:'c~rents ,COal &It 01 . Typ. PrUI re.. Cod. Stored 1ft fmllt, wt S!e Instru; Ions ! U 220 07 4 32 Center Area ApI Lustr 225 ,;h~sic.' fnd Heflt. MIJ.rd Mixture COlponellt" N,U I C.A.S. lIulb., 67-63-0 ¡ (Chec. I I th, appl, -y-c-- 8 Isopropanol , IV! . COlPOIIIllt U "I' I C.A.S. IUlber ç\()~(f\. 7664-41-7 ; 0 fire Huard O.",ctifit,, [] OeJa,'d 0 Sudd,1I R.I.II. i!:j I..edllt. \ 2 Amonium Hydroxide all. Hu t~ of Pressure Hu tb ,..., Coaponelt.3 I.... C.A.S. .u.b.r u : PhIS ierl I,d "fllt~ '1,lrd tllee I thl~'" J . I J [] Fir. HIUf'] I] leactiYtt, o O"IJ" [] sudd" '.Ieas. H,.,t. 0 pr'llur. Coaponut " iJ ¡..edl.t. Hult' CO.pOII.1t IJ 4 32 Center West Wall COIþOntlt.. N..., C.A.S. NUlbtr , I\. o( \? 1, -)-''\ 36 .... . C.A.S. lIu.b., ; \" Çt¡I"- 64 ¡v(\\(..~· .... . C.A.'. Jlulbt, ~:r ! . Sprout Nip (Valent) 94-11-1 Isopropl-m~chlorocarbanilate 67-63-0 Isopropyl Alcohol Mixture ,?hflic,1 tlld ".,m '.jar.' (Cllee. · I t.. I~'. 1 [] Fire IIlurJ D 'tlctlYttr, C.A.'. b.r C",Gllnt.. .,., C.A.S. IU.lr [] O".J" D SIdâII.I.... "..Ita of 'rllsurt . Coapoaut II ... Ie. A. S. lIuU., [] JUJ.d.II·~ tOlPQIIIt 13 ..... C.A.S. luabtr .... I C.A,I. ....., prl&~~".tf'tf:r'~:,t;jl" 1 i . [] Fire IIIl.i, D ...¿tI,ft, " COIPOHIt II .... I C .1. t. IU_ [] ¡"J,d.' ftV ¡ C",Hllt II .... C.A.'. I...., i ¡ EHERGEHCV:OOHTACT&. .trmlferald Ra~terson' T,(~ervice ReD. ~ .2.niirk St4fmS Htifintt.. 1Rrcd .nd .t,n .')_r Cli~t;nø 1111 rcectfon.J j art", II~" '..,nl fì, o.r I an p.rs... "l.1I11 . II ".ill.c fit t~. )"'oeIlU,, ,IIUIU.-t.,... ,14 ... : tI(htd dge,... f, ... t t ¡DI... II I' IlQlir" ... I In .,1. ,..pOIII" or O.tl..I., tat "'orllt,.....",,. tht t~. .~IIU.d II or.. ... t,.., ."".u, .111 cOIIp .ta. , . , I o o'''r'' D Sid.. I. ,.,.. HI. ~ of 'rl..I" ìer, vice Reo. Tit, 832-6602 11 Hf TIN, ¡ ¡¡,-¡¡r-¡flct.. tltl. It o.I"/O,"ltO' UI ~.lr/lft'lt"'1 tltlO'IZIt 'e"'t'ftt.tIW' , $!,..w, OItn.f4,.u- e e CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S, D JOHNSON FIRE CHIEF September 23, 1991 2101 H STREET BAKERSFIELD, 93301 326-3911 Fred Serr District Manager ATOCHEM - Decco Division 1525 E. Noble # 300 Visalia, CA 93277 Mr. Serr: It has come to my attention that there are portable hazardous material storage rooms on the market which may be able. to provide a suitable H occupancy for the storage of gaseous chlorine. It may be possible to install such a storage room inside the existing B-2 warehouse facility to create an occupancy separation for the chlorine storage. Safety supply vendors should have information on the various types of portable hazardous materials storage buildings and rooms. Be sure that the structures which you consider for this purpose are rated to provide a H occupancy for both the oxidizing and toxic hazards of chlorine. Please send me specifications for any of the storage rooms which you may wish to use so that we may verify their compliance with the Fire and Building Codes. Call me at (805) 326- 3979 if I can be of any assistance. 8.incerely, n (\~~(~ \~~~ Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Gary Leary ¡ '" \ . - CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT S D JOHNSON FIRE CHIEF September 16, 1991 2101 H ST.REET BAKERSFIELD, 93301 326,3911 Fred Serr District Manager ATOCHEM - Decco Division 1525 E. Noble # 300 Visalia, CA 93277 Mr. Serr: As we discussed on the phone today, the Bakersfield Fire Department has determined that the Pennwalt-Decco facility located at 4330 Wible Rd. was permitted in 1979 as a B-2 occupancy for warehouse storage. The storage of gaseous chlorine was not allowed in a B-2 occupancy under the 1976 Uniform Building Code which was in effect when the permit was issued nor is gaseous chlorine storage permitted in a B-2 occupancy under the current Building and Fire codes. 'At this time it is appropriate to suspend work on the Risk Management and Prevention Plan and to review Pennwalt' s options to rectifY,the occupancy problems. The Uniform Building and Fire Codes contain the requirements affecting the possible options for conversion of the present location to ~ H occurancy. The Bakersfield Building Department should be consulted concerning the specific requirements of the Building Code as they relate to the characteristics of the building at 4330 Wible. The Building Department can be contacted at (805) 326-3727 for assistance. We need an updated copy of pennwal t' s hazardous materials business plan for the facility at 4330 Wible immediately. During the site inspection on 6-17-91, I left a computer printout of the business plan with Mr. Achterberg for revision within one month .An accurate, up to date reporting of hazardous inventory is essential to our review of your facility. Be certain that all hazardous material inventory stored or used in quanti ties equal to 500 pounds of solids, 200 cubic feet of gases or 55 gallons of liquids are . reported. Please attach the materiål safety data sheets for each inventory item so that I will have access to the manufacturer IS report of the physical and chemical characteristics of these compounds. oJ \ 4t, ." ... e e Pennwalt-Decco's plan to conform with the Building Code should be submitted to the Hazardous Materials Division of the Bakersfield Fire Department by October 31, 1991. This was the date on which the RMPP was to be due. We will discuss an extension of the RMPP due date once the building occupancy questions have been resolved. The revised hazardous material management plan should be submitted as soon as possible but no later than October 11, 1991. ~leas~ contact me at (805) 326-3979 if I can be of any assistance or provide interpretation of the 1988 Uniform Fire Code. Sincerely, . ~O\~(c/~~ Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey Gary Leary , I Nancy Johannesmeyer '--.. e e CITY of BAKERSFIELD "WE CARE" FIRE DEPARTMENT D, S, NEEDHAM FIRE CHIEF June 21, 1991 2101 H STREET BAKERSFIELD, 93301 326-3911 Mr. Jerry Achtererg Atochem North America, Inc. r:l.é ~"1"::> 7~\"\.,,~-\ G~.p -I\::.. 367 Decco Division 1525 E. Noble #300 Visalia, CA 93277 Dear Mr. Achtererg: Enclosed is a computer printout of the Hazardous Materials Management plan submitted in May 1989 for the Pennwalt facility at 4330 Wible Road Bakersfield. It is time to review and update this plan. Please mark any changes to the text directly on the printout. I have enclosed an inventory form so that you may make additions to the inventory for any materials which contain 1% or more of a hazardous material or .1% or more of a carcinogen. As we discussed during my inspection, the material safety data sheets for a product will disclose the percentage and identity of hazardous materials. The calcium hypochlorite and soda ash will definitely need to added to the inventory. Please review the fruit wax and detergent MSDS to determine if they must be reported as hazardous materials. All hazardous materials store in quantities equivalent to 55 gallons of liquid, 500 pounds of solid or 200 cubic feet of a gas must be reported. Please complete this business plan update and return it by July 22, 1991. Be sure to add responses under any area highlighted in yellow. Call me at (805) 326-3979 if I can provide any assistance. Sincerely, Barbara Brenner Hazardous Materials Planning Technician cc: Ralph Huey ¡p/17}91 th-Oêh. N. A: - t)e.CCo Ù v S . a -PENNW. CORP DEcca DIVISION 215-~0-000387 Overall Site with 1 Fac. Unit Page 1 I ....._...._~ General Information Location: 4330 WIBLE RD Ident Number: 215-000-000387 Map: 123 Hazard: High Grid: 13C Area of Vu1: 0.0 - Contact Name GERALD PATTERSON . Title Business Phone ~e..rJ,O ~~~~û-ñl"l (805) 397 -1087 x R t--Q12t x i1\ c.., \ if'I 24 Hour Phone (805) 831-7617 2 Administrative Data Mail Addrs: 4330 WIBLE RD City: BAKERSFIELD Corom Code: 215-007 BAKERSFIELD STATION 07 D'B Number: 00-229-0773 State: CA Zip: 93313- SIC Code: 2879 Owner: flNNWAL'i' CORP DECCa f)IV~1'Y"\ ('J.A -1)aoU.S.. Phone: (805) 397-1087 Address: POBOX 120 State: CA City: MONROVIA Zip: 9l017- 'fsummary I ·.·~r ê .1J\· ~ 1,:::Jér(" Ach+e{ b.f(j Do hereby certify that I have --; (Type or print name) reviewed the attached haz2rdous materials manage- ment plan for AfocÅP,"- ¡t)A--DUCD U:nd that it along with (t~n¡; ;,: iJu"ine¡¡sj any corrections constitute a complete and correct man- If" , V{iÁi-:ÙillJ., . RECEIVED OCT 1 5 1991 Ans·d.... ........ )6/17/91 /tit; t>4::.Ja.¡V A-- --- . t) ~c c-() () S . PJ4'N~CORì? D1',;I,;l,;O DIVI3ION 215'.0-000387 02 - Fixed Containers on S~ . Page 2 Hazmat Inventory Detail in MCP Order 02-001 CHLORINE GAS Gas 26250 Extreme Pressure, Reactive, Immed Hlth FT3 CAS i: 7782-50-5 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: CLEANING Daily Max FT3 26,250 Daily Average FT3 1,500.00 Annual Amount FT3 180,000.00 Storage r Press T Temp ~ PORT. PRESS. CYLINDER Above AmbientNW CORNER Location - Conc l 100.0% Chlorine (EPA) Components ~ MCP --'(List Extreme EPA - Notes ·/11/91 ff-¡ffÁfn- tV If - De{(() P£!tMWAJ..T CORP ut.l:l:Ü b 1 'J 1 L 1 ON 1. 1 ~ U U U ' 00 - Overall Site e " OUUJu'} lJúy\.: <D> Notif./Evacuation/Medical .> Agency Notification EMPLOYEES ARE INSTRUCTED TO NOTIFY THE BAKERSFIELD FIRE DEPARTMENT AND THE MAIN orrICB IN MOØROVIA, IN THE EVENT OF A LEAK OR SPILL. CALL 911 ¿> &.ploy.. Not1f./Evacuat1on EMPLOYBES ARE INSTRUCTED TO NOTIFY THE FIRE DEPARTMENT AND THE MAIN OFFICE or DECCO (MONROVIA CA) IN THE EVENT OF A SPILL OR LEAK. EVACUATION IS THROUGH THE LARGE OVERHEAD DOORS WHICH ARE OPEN WHENEVER EMPLOYEES ARE IN THE WAREHOUSE. THE WAREHOUSE DOES NOT HAVE AN EMPLOYEE ASSIGNED TO STAY DURING BUSINESS HOUSE. EMPLOYEES ARE IN THE WAREHOUSE LESS THAN 3 HOURS IN A NORMAL WORK DAY. 1> ,Public Hotif./Evacuat1on THE FIRE DEPARTMENT ALONG WITH THE LOCAL POLICE DEPARTMENT WILL HANDLE ALL ~UBLIC NOTIFICATIONS, AS MAY BE REQUIRED, THOUGH PEASONEL CONTACT, OR BY WAY OF NEWS TELECAST. EVACUATION INSTRUCTIONS TO BE ISSUED AS FELT NEEDED FOR PUBLIC SAFETY, BY LOCAL AUTHORITY TYPE PERSONEL. .> Emergency Medical Plan BAKERSrIE~ EMPLYEES ARE OM A SERVICE ROUTE, WORKING OUT OF THEIR VEHICLES. TRUCKS ARE EQUIPPED WITH 2-WAY RADIOS SO REGARDLESS OF LOCATION, HELP CAN BE IMN&DIATELY SlßQIOlŒD. ALL TRUCKS AND 2-WAY BASE OPERATORS HAVE EMERGENCY 'KKDlCAL MUMaEØ8 rOR THE VARIOUS AREAS COVERED BY THE SERVICE ROUTE , . "6/17/..91 - ' í}-T~ III It - Dee ( I? , P£:N OR' QEGcu UJ. ..I5.!GR- 215-_-000387 00 - Overall Site Page 4 <E> Mitigation/Prevent/Abatemt 1> Release Prevention PAINT AND FLAMMABLE PRODUCTS ARE STORED SEPARATELY. CYLINDERS OF CHLORINE GAS ARE STORED UPRIGHT, CHAINED AND SEPARATED BY FULL OR EMPTY. STORAGE IS NEAR A LARGE DOOR TO ALLOW AIR CIRCULATION. THE CHLORINE SUPPLIER KEEPS AN EMERGENCY KIT A FOR CAPPING CYLINDERS THAT MAY DISCHARGE GAS. RESIRATORS ARE ON SIDE FOR USE IN CASE OF A GAS DISCHARGE. TRAINING IS PERFORMED YEARLY FOR SAFETY AND HANDLING. 2> Release Containment AN EMERGENCY KIT FOR CAPPING CYLINDERS IS MAINTAINED FOR LEAKING OR BROKEN VALVES. 3> Clean Up CAPPED CYLINDERS WILL BE PICKED UP BY MANUFACTURER, ALL PURE CO. (209) 297-7665 :4> Other Resource Activation _1 \ .. ~61.17J91 ~~T_~1~Ee~C~15ION~ 2lSeO-000387 00 - Overall Site Page 5 ~', <F> Site Emergency Factors 1> Special Hazards :2> Utility Shut-Offs A) GAS - FRONT OF BUILDING OUTSIDE (WEST SIDE OF BUILDING) B) ELECTRICAL - INSIDE WAREHOUSE NORTH OFFICE WALL C) WATER - OUTSIDE SOUTHWEST CORNER OF BUILDINGS D) SPECIAL - NONE E) LOCK BOX - NO ~3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS AND OVERHEAD SPRINKLER SYSTEM FIRE HYDRANT - SOUTHWEST CORNER OF BUILDING <4> Building Occupancy Level \,~ ..;, . ~6r.!~f?t(~~Ifi4· 215.0-000387 00 - Overall Site Page 6 )6/.11-/91 ,,' . <G>- Training ~1> Page 1 WE HAVE 2 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING: <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use ~':;,:~~~~Æd~;:~/:.:;. " LT "". ,,'::-;":::""!,:::"'_""" , , "" "'-.""1""', ' _ - - "" . . ow . :': . ...:: ~ > . -.... -Þ"-"~' ',' -- .. ~, ~ ." ," -y~ 0' M E M 0 RAN DUM .' JULY 2, 1991 TO: RALPH HUEY, HAZARDOUS MATERIALS ' , ~SUSAN CHICHESTER, ACCOUNTANT II FROM: SUBJECT: UNDERGROUND STORAGE TANK REVENUES We have assigned three revenue codes to the underground storage tank program and one trust account: 011-56067 is for tank installation, tank removal, and tank modification. These fees will not be billed; they will be collected at the Fire Department and remitted to Finance on the Report of Monies Collected. The trust account for the $53 for the State for tank installations will be'coded to 811-26115. 011-56068 is for the tank tightness test and the.. annual operating permit. These two charges will be' billed by Finance in Accounts Receivable. The account receivable will be 011-11117, as are the other five receivables. ,011-56069 is for the $45 hourly fee charged by Fire. This will be billed by Finance in Accounts Receivable. This charge is a fee and must be' separated in the City Annual Financial Report, therefore, it has a distinct revenue account. The account receivable will be 011-11117. ~ krc MSC /'<7' -;;..~~_ """0 Post·W"rOUJquest pad 7664 """' "'--/ ',------" ROUTING - REQUEST To ~-!faz-¡t(af- {/a/..en è- Please DREAD o HANDLE o APPROVE and o FORWARD o RETURN o KEEP OR DISCARD o REVIEW WITH ME Date /~h9 / Fro~ - ... --" - - --. ------ - -- - - .illJ@) .,.-~ ATOCHEM NORTH AMERICA elf aquitaine ·e e DEcca AGRICHEMICALS DIVISION 1713 S. California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838. Tlx: 4720597, Fax: (818) 359-7248 MATERIAL SAFETY DATA SHEET Page 1 DATE: 01/01/91 ---------------------------------------------------------------------------- MANUFACTURER'S INFORMATION ATOCHEM NORTH AMERICA, DECCO 1713 South California Ave. Monrovia CA 91016-0120 EMERGENCY CONTACT Robert J. Johnson 818-358-1838 ---------------------------------------------------------------------------- SECTION I - IDENTITY Quick I.D.: DECCO APL KLEEN 246 Chemical Name: N/A Trade Name Synonyms: ACID SOAP CONCENTRATE Chemical Family: N/A Formula: MIXTURE DOT Freight Classification: Corrosive material ---------------------------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME % TLV UNITS CAS Number -------------------------------------------------------------------------- PHOSPHORIC ACID 75% Dodecylbenzenesulfonic acid ISOPROPANOL 50 1.0 15 1.5 400.0 Mg/M3 00766-48-2 27176-87-0 Mg/M3 00067-63-0 HAZARDOUS INGREDIENTS DESCRIPTION: FOR'PHOSPHORIC ACID. LD50 (ORAL)=1530 MG/KG (RAT) LD50 (DERMAL)=2740 MG/KG (RABBIT) PHOSPHORIC ACID IS CORROSIVE! CONCENTRATED SOLUTIONS MAY CAUSE SERIOUS BURNS OF SKIN AND EYES. PROMPT TREATMENT IS IMPORTANT TO MINIMIZE EFFECTS OF OVEREXPOSURE. FOR DODECYLBENZENE SULFONIC ACID. A STRONG ACID WILL CAUSE BURNS OF THE SKIN AND EYES. LD50=650 MG/KG (RATS) FOR ISOPROPANOL. A FLAMMABLE LIQUID, BUT CONCENTRATION IS TO LOW TO EFFECT PRODUCT. HEATING MAY DRIVE OFF ALCOHOL AND CAUSE A POTENTIALLY EXPLOSIVE CONDITION. ---------------------------------------------------------------------------- SECTION II~, - PHYSICAL DATA Boiling Point: >212 F Vapor Density: N/A (Air = 1) Specific Gravity: 1.31 ~ Evaporation Rate: N/A EPA Physical State Catagory: Vapor Pressure: N/A mmHg Solubility in Water: 100 Percent Volatile by Volume: Comparison Material: N/A Liquid Mixture 35% APPEARANCE AND ODOR DESCRIPTION: The hentage: IõIEHMIaJ and MB" The future: ATOCHEM NORTH AMERICA - h__ __ ____._~,_ _~." .~ _.~ ~-.:-_~_...... _E.: "-";'~-';-::¡:d'd:...;...,:.u_,,,,,,,''::~'-::.'_.-'';;';-.~-_~"':'..'-'';;:'I<_-:';''':::''-i:........:,-.. ..<, .......::t'-',·.: , ..i.._~."o:. ....J·;.oM~ ..._..~':".J.!,:... _ :'...;~...:;i: .,........;.......tL.u._"".&.;. .:!I:.~~~~~-:.....:.!;,;.'__ ._ ...... e e Page 2 YELLOW TO AMBER CLEAR LIQUID. SOME S02 ODOR. pH IS <2.0. ---------------------------------------------------------------------------~,~ SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A F Lower Flammable Limit: N/A NFPA Code: 300A EPA Hazard Codes: Reactive Method Used: N/A Upper Flammable Limit: N/A EXTINGUISHING MEDIA: N/A SPECIAL FIRE FIGHTING PROCEDURES: OVER HEATING OF DRUMS COULD RUPTURE THEM, RELEASING HOT ACID. ALCOHOL PRESENT WOULD BURN AS WELL AS THE ORGANIC ACID. ACID COULD REACT WITH OTHER MATERIALS PRESENT. DIRECT FLOW OF WATER OVER DRUMS TO KEEP THEM COOL. WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FACEPEICE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE AND FULL BODY PROTECTION WHEN FIGHTING FIRES INVOLVING ACID. UNUSUAL FIRE AND EXPLOSION HAZARDS: ACID WILL REACT WITH MOST METALS AND PRODUCT HYDROGEN. HYDROGEN IS FLAMMABLE AND EXPOSIVE. HEAT WILL ACCELERATE THIS REACTION. ---------------------------------------------------------------------------- SECTION V - HEALTH HAZARD DATA Route(s) of Entry Inhalation: No Potential Carcinogen lists -- N.T.P.: No I.A.R.C. Monographs: No Skin: Yes Ingestion: Yes OSHA Regulated: No EFFECTS OF OVEREXPOSURE: PRODUCT IS CORROSIVE AND COULD RESULT IN BURNS TO EXPOSED BODY PARTS. INHALATION OF FUMES (ALCOHOL AND S02) COULD BE IRRITATING TO MUCUS MEMBRANES AND LUNGS. INHALATION OF PRODUCT FUMES OR MIST CAN CAUSE BURNS OF NASAL AND RESPIRATORY PASSAGES. EMERGENCY AND FIRST AID PROCEDURES: EYES: & SKIN:ln case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes, Get medical attention. INGESTION:lf swallowed, do NOT induce vomiting; if conscious, give large amounts of water, follow with milk of magnesia. Get medical attention. INHALATION:If inhaled, remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. ---------------------------------------------------------------------------- SECTION VI - REACTIVITY DATA STABILITY: PRODUCT IS STABLE UNDER NORMAL CONDITIONS. INCOMPATABILITY: PRODUCT IS INCOMPATABLE WITH STRONG ALKALIES AND OXIDIZERS. e e Page 3 ~ :HAŽARDOUS DECOMPOSITION PRODUCTS: COMBUSTION WITH LIMITED OXYGEN MAY PRODUCE CO, C02, SUFFUR OXIDES AND PHOSPHOROUS PENTOXIDE FUMES. PRODUCT WILL REACT WITH MOST METALS. HAZARDOUS POLYMERIZATION: N/A ADDITIONAL DESCRIPTION: PRODUCT WILL CORRODE MOST METALS. IF A PUMP SYSTEM IS USED TO DELIVER ACID SOAP TO WASH LINE, PLASTIC OR TEFLON TUBING AND PUMP MUST BE USED. ---------------------------------------------------------------------------- SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE OF SPILL: SMALL SPILL--NEUTRALIZE SPILL WITH SODIUM BICARBONATE OR OTHER WEAK ALKALIE. WASH NEUTALIZED SPILL DOWN DRAIN WITH LARGE AMOUNT OF WATER. LARGE SPILL--EVACUATE ALL UNNECESSARY PERSONNEL. DIKE SPILL TO PREVENT SPRED OF SPILL. WEAR PROTECTIVE CLOTHING. NEUTRALIZE SPILL WITH SODA ASH. IF SPILL IS ABSORBED ON INERT MATERIAL, CONTACT LOCAL, STATE OR FEDERAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES. CAUTION: ABSORBED MATERIAL IS STILL HAZARDOUS. WASTE DISPOSAL METHOD: CONSULT WITH LOCAL, STATE OR FEDERAL AUTHORITIES FOR PROPER PROCEDURE. ---------------------------------------------------------------------------- SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: INORGANIC ACID RESPIRATOR. Local Exhaust Ventilation: REQUIRED Mechanical Ventilation: N/A Special Ventilation: N/A Other Ventilation: N/A Protective Gloves: PLASTIC OR PLASTISIZED RUBBER. Eye Protection: GOGGLES OR FACE SHIELD. Other Protective Equipment: EYE WASH AND SAFETY SHOWER. ADDITIONAL DESCRIPTION: SEC. 311 OF THE CLEAN WATER ACT LISTS PHOSPHORUS AS A HAZARDOUS SUBSTANCE WHICH, IF DISCHARGED INTO OR UPON WAATER, WILL PRESENT AN IMMINENT AND SUBSTANTIAL DANGER TO PUBLIC HEALTH OR WELFARE. SPILLS OF 5000 POUNDS OR MORE MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER 1-800-424-8802. ---------------------------------------------------------------------------- SECTION IX - SPECIAL PRECAUTIONS HANDLING AND STORING PRECAUTION: EMPTY CONTAINER MAY CONTAIN HAZARDOUS RESIDUES. Wash thoroughly after handling. Keep in tightly closed container. STORAGE: Store in a cool, dry place. Emits toxic vapors, especially when heated. Avoid breathing vapors and contact with skin and eyes. OTHER PRECAUTIONS: Mi® ATOCHEM NORTH AMERICA elf aqLitai1e e e DEcca AGRICHEMICALS DIVISION 1713 S. California Avenue. Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 - . \." Page 4 Store and use with adequate ventilation. ATOCHEH NORTH AHERICAL, INC. MONROVIA, CA 91016 APL KLEEN 246 The heritage: õII&¡NWU, and MIl' The future: ATOCHEM NORTH AMERICA ~&_.a_7aao_o~ e '. . ..' >":,~~~.")~ i:_~_.~'i .". ';";.;,:1._", ;:¡i~~~"I;'~~~~",.....û~~:""Ár'~".;.c.:...&.........~~~...............:._......,..~ -AllhlamltClremlca/Cømpat. ' IJIVI6ION OF ASHLAND OIL. INC. p, 0, 80X 2219. COLUMBUS. OHIO 43216 . 18141 8S9-3333 .. '" \ ".,; .:,,:",' _~ . ';d_>'~':"~"'~" .1..,...¡ ,.-.~··,,:,,'l: :MATERIAL SAFETY DATA SHEET Ashland~ ! oooa..a 24-HOUR EMERGENCY TELEPHONE (606) 324-1133 i " ; '. ,'~ ':~ ~~~i?f~~~Æ:;:-:1~,",,-., aODA A8H DEN8E ~OO. BAG PAGE, ~ \ THX. M.DS COMPLXE8 WXTH a. C~R ~.£O.iaOO (THE HAZARD COMMUNXCATXON STANDARD) ................................................................................... . ':,PROD'UCT NAME, CAB NU"'tlER, 80DA ASH DENsE iooe BAG ..97 i9 8 ATTN, PLANT MGR./SA~ETV DXR. os so O~~ 69&6800- DATA SHEET NO, OOOiii~-OO~ LATEST REVXSXON DATE, 0~/B6-&606~ PRODUCT, ~920iOS XNVOXCE, ~02B7" XNVOXCE DATE, iO/OB/86 TO, PENNWALT DCCO DXVXSXON i?i~ SOUTH CALX~ORNXA MONROVXA CA .iOi6 PENNWALT ,DCCO DXVXSXON i?i3 BOUTH CALX~ORNXA MONROVXA CA .iOi6 ----------------------------------------------------------------------------------- SECTXON X-PRODUCT XDENTX~XCATXON ------------------------------------------------------------------------------.---- GENERAL OR GENERXC XD, ALKALX DOT HAZARD CLA.SX~XCATXON, NOT APPLXCASLE ----------------------------------------------------------------------------------- SECTXON XX-COMPONENTS -----.----------------------------------------------------------------------------- ~-"- _.--- ·-'-~XI\l1HiIl:DJ:'II:N,.- - --- --- -y,-('B-' WT) -~. -'- - -~~~- --~--- - -~-- TLV NOTE ---------- ---------- .ODXUM CAABONATE CAB ., ".7_i._B i), PEL/TLV NOT ESTABLxsHED ~OR THXS MATERXAL >.5 i) ----------------------------------------------------------------------------------- SECTXON XXX.PHVSXCAL DATA ----------------------------------------------------------------------------------- PROPERTY RE~XNEMENT MEASUREMENT -------- ---------- ----------- IIOXLXNG POXNT VAPOR PRESSURE .PECXFXC VAPOR DENSXTV .PECX~XC GRAVXTV NOT APPLXCABLE ----------------------------------------------------------- NOT APPLXCABLE ----------------------------------------------------------. NOT APPI.XCABLE ------------------------------------------------------.---- G ( 2.533 68.00 DEG F' 20.00 DEG C) ------------------------------------------------------.---- PERCENT VOLATXLES EVAPORATXON RATE NOT APPLXCABLE ----------------------------------------------------------- NOT APPLXCABLE ------------------------------------------------------------------.---------------- BECTXON XV-~XRE AND EXPLOSXON XN~ORMATXON ------------------------------------------.---------------------------------------. ~LA.H POXNT NOT APPLXCABLE EXPLoeXVE LXMXT NOT APPLXCABLE EXTXNGUXBHXNG MEDXA, WATER ~OG HAZAQDOUS DECOMPOSXTXON PRODUCT., NOT APPLXCABLE ~XRE~%GHTXNG PROCEDURES, WEAR SEL~_CONTAXNED BREATHXNG APPARATUS WXTH A ~U~~ FACEPXECE OPERATED XN PRESSURE-DEMAND OR OTHER P05XTXVE PRESSURE MODE WHEN ~XGHTXNG ~XRES. .PECXAL ~XRE . EXPLOSXON HAZARDS, NOT APPLXCABLE ----------------------------------------------------------------------------------- SECTXON V_HEALTH HAZARD DATA ----------------------------------------------------------------------------------- E~~ECTS O~ ACUTE OVEREXPOSURE, ~OR PRODUCT ------------------------------ EVES _ CAN CAUSE XRRXTATXON. .KXN - CAN CAUSE XARXTATXON. BREATHXNG _ O~ DUST CAN CAUSE %RRXTATXON O~ NASAL AND RESPXRATORY PASSAGES. aWALLOWXNG - CAN CAUSE GASTROXNTESTXNAL XARXTATXON, NAUSEA, VOMXTXNG, AND D%ARRHEA. ~XA.T AXD, ---------- X~ ON SKXN. THOROUGHLV WAsH EXPOSED AREA WXTH SOAP AND WATER. CLOTHXNG. LAUNDEA CONTAMXNATED CLOTH%NG SE~ORE RE_USE. X~ XN EVES, ~LUSH WXTH LARGE AMOUNTS O~ WATER, LX~TXNG UPPER AND LOWER LXDS OCCASXONALLV, GET MEDXCAL ATTENTXON. X~ .WALLOWED, XMMEDXATELV DRXNK TWO GLASSES O~ WATER AND XNDUCE VOMXTXNG By EXTHER GXVXNG XPECAC BYRUP OR BY PLAC%NG F'XNGER AT BACK OF' THROAT. NEVER GXVE ANVTHXNG IIV MOUTH TO AN UNCONSCXOUS PERSON. GET MEDXCAL ATTENTXON XMMEDXATELV. REMOVE CONTAMXNATED X~ .REATHED, REMOVE XNDXVXDUAL TO ~AESH A%R. , , ",.',,,,,..,,;0,, " " " "" .", ". c.~" e"',; ,,", d''¡'.:2¡:"JC'''¡"",:,,,, ",,¡,,"~ _"''"'"\\'"'''",'''''....._"òi"~.tJ'"''''''..,~,,¡;,,J-<''''' "'"'''''.......... ...........$, 5"~· ':, '72. U. '782.0.01. Ashlaøtl Clremlcal Cømpanq" . DIVISION OF ASHLAND OIL, INC. 11_'" II. 1f::JI."aft tÞ :,' MATERIAL SAFETY P. 0, BOX 2219. COLUMBUS, OHIO 43216 . 18141 BB9-3333 . t DATASH,~ET, , " 24-HOU~ EMERGENCYT~~~~!-~t}!:'I~,I~t~~4-!~~ ".,.__~,"..,..".."" , "''''~F-,.J w ~, ,~:~~:~{i~_~~~~~\~Im~~.;à~~!J~iiAP;)~~~~J~~~...::..:,.~.~,.~ 0008~2 SODA ASH DENSE ~OO. BAG PAGE. 2 :::::::::::::::::::::::::::::~~~~~~~:~~:~~~~~~~~~~:~~~~:::::::::::::::::p~r:~jj¡Ë{} HAZA~DOUS POLVMERIZATION. CANNOT OCCUR STABILITY. STABLE OCT 1 7 1991 INCOMPATIBILXTY. AVOXD CONTACT WXTH" ST~ONG MXNERAL ACXDS. Aßs'd. .~'.... ..... --------------------------------------------------------------------------------.-. SECTXON VXX.SPXLL O~ LEAK PROCEDU~ES ----------------------------------------------------------------------------------- STEPS TO BE TAKEN XN CASE MATERXAL XS ~ELEASEO OR SPXLLED, ------------~--------------------------------------------- SMALL SPXLL, SWEEP UP MATERXAL ONTO PAPER. LARGE SPXLL. SHOVEL MATERXAL INTO CONTAXNE~S. CLEAN UP ANY RESXDUAL MATE~XAL. THOROUGHLY SWEEP AREA O~ SPXLL TO WASTE DXSPOSAL METHOD. ------------.--------- SMALL SPXLL, DX5POSE O~ XN ACCORDANCE WXTH ALL LOCAL, STATE AND ~EDERAL REGULATXONS. LARGE SPXLL, DXSPOSE O~ XN ACCORDANCE WITH ALL LOCAL, STATE AND ~EDERAL REGULATXONS. ----------------------------------------------------------------------------------- SECTXON VXXX.PROTECTXVE EQUXPMENT TO BE USED ----------------------------------------------------------------------------------- RESPXRATORY PROTECTXON, X~ NEEDED USE A NXOSH/MSHA JO%NTLV APPROVED DUST RESPXRATOR. (ASK YOUR SA~ETY EQUIPMENT SUPPLXER) VENTXLATXON, PROVXDE SU~~XCXENT MECHANXCAL (GENERAL AND/O~ LOCAL EXHAUST) VENTXLATXON TO MAXNTAXN EXPOSURE BELOW LEVEL O~ OVEREXPOSURE (~ROM KNOWN, SUSPECTED OR APPARENT ADVERSE E~~ECTS). PROTECTXVE GLOVES, WEAR RESXSTANT GLOVES (CONSULT YOUR SA~ETY EQUXPMENT SUPPLXER). EVE PROTECTXON, CHEMXCAL SPLASH GOGGLES IN COMPLXANCE WXTH OSHA REGULATXONS ARE ADVXSEDJ HOWEVER, OSHA REGULATIONS ALSO PERMXT OTHER TYPE BA~ETV GLASSES. (CONSULT YOUR SA~ETY EQUXPMENT SUPPLXER) OTHER PROTECTXVE EQUXPMENT. TO P~EVENT REPEATED OR PROLONGED SKXN CONTACT, WEAR XMPERVIOUS CLOTHXNG AND BOOTS. NORMAL WO~K CLOTHXNG COVERXNG ARMS AND LEGS. -----------------------------~----------------------------------------------------- SECTXON XX.SPECXAL PRECAUTXONS OR OTHER COMMENTS ----------------------------------------------------------------------------------- CONTAXNERS O~ THXS MATERXAL MAY BE HAZARDOUS WHEN EMPTXED. SXNCE EMPTXED CONTAXNERS RETAXN PRODUCT RESXDUES (VAPOR, LXQUXD, AND/OR SOLXD), ALL HAZARD PRECAUTXONS GXVEN XN THXS DATASHEET MUST BE OBSERVED. THE XN~O~MATXON ACCUMULATED HEREXN XS BELXEVED TO BE ACCURATE BUT XS NOT WAR~ANTED TO BE WHETHE~ ORXGXNATXNG WXTH THE COMPANY OR NOT. RECXPXENTS ARE ADVXSED TO CON~X~M XN ADVANCE O~ NEED THAT THE XN~O~MATXON XS CURRENT, APPLXCABLE, AND SUXTABLE TO THEXR CXRCUMSTANCES. -~--- ---.----- --------- "'- -- - - ------ ',,~ l ATOCHEM NORTH AMERICA etf ØCJitaN e RECE1VED OCT-1,5: 1991 DECCD e AGRICHEMICALS DIVISION 1713 S. California Avenue. Monrovia. California 91016-0120 Tel: (818) 358-1838. Tlx: 4720597. Fax: (818) 359-7248 Ans'd·..··..M-A1'ERIAL SAFETY DATA SHEET DATE: Page 1 01/01/91 ---------------------------------------------------------------------------- MANUFACTURER'S INFORMATION ATOCHEM NORTH AMERICA, DECCa 1313 South ~alifornia Ave. Monrovia CA 91016~0120 EMERGENCY CONTACT Robert J. Johnson 818-358-1838 ---------~----------~~--~--~------------------------------------------------ SECTION I - IDENTITY Quick I.D.: DECCO 240 LIQUID CHLORINE Chemical Name: CHLORINE GAS Trade Name Synonyms: LIQUIFIDY CHLORINE GAS Chemical Family: HALOGEN ,Formula: C12 DOT Freight Classification: Nonflammable gas -----------~-~-------~------~----------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME % TLV UNITS CAS Number -------------------------------------------------------------------------- CHLORINE GAS, LIQUIFIED UNDER PRESSURE HAZARDOUS INGREDIENTS DESCRIPTION: STEL FOR CHLORINE IS 1.0 PPM 100 0.5 PPM 07782-50-5 INHALATION: LC50=137 PPM/1 HR (MUS) LCLO=800 PPM/30 MIN (DOG) LCLO=660 PPM/4 HR (CAT) DANGEROUS EXPOSURE=25 PPM; OSHA/NIOSH HAZARD 1-NON-FLAMMABLE COMPRESSED GAS HAZARD 2-POISONCOMPRESSED GAS (POISON A) -------~------------------~------------------------------------------------- SECTION III - PHYSICAL DATA Boiling Point: -34. F Vapor Density: >1 (Air = 1) Specific Gravity: 1.47 Evaporation Rate: <1 EPA Physical State Catagory: Pure Vapor Pressure: 48.0 mmHg Solubility in Water: 10MG/ Percent Volatile by Volume: Comparison Material: ETHER Liquid 100% APPEARANCE AND ODOR DESCRIPTION: AMBER LIQUID OR GREEN, YELLOWISH GAS WITH SHARP, IRRITATING ODOR. , FORM:LIQUID/GAS/VAPOR ---------------------------------------------------------------------------- SECTION IV - FIRE AND EXPLOSION HAZARD DATA' The heritage: PIiNMU and.... The future: ATOCHEM NORTH AMERICA e e 4",~ Page'" Z : Flash Point: N/A F Lower Flammable Limit: NFPA Code: 301C EPA Hazard Codes: Sudden N/A Method~s~d~ ~/A Upper Flammable' Limit: N/A ¡ . . Release of pressure; Reactive EXTINGUISHING MEDIA: N/A .' .-. SPECIAL FIRE FIGHTING PROCEDURES: EXTINGUSH FIRE USING AGENT SUITABLE FOR TYPE 'OF SURROUNDING FIRE (CHLORINE ITSELF DOES NOT BURN OR BURNSWITH,DIFFICULTY). COOL ALL AFFECTED CONTAINERS WITH FLOODING QUANTITIES .OFWATER. APPLY WATER FROM AS FAR A DISTANCE AS POSSIBLE. USE WATER SPRAY 10 ABSORB VAPORS. DO NOT APPLY WATER TO POINT OF LEAK IF CYLINDER OR VALVE IS LEAKING. WEAR FULL PROTECTIVE CLOTHING (FIREMANS GEAR IS INADEQUATE) ALONG WITH WITH SELF-CONTAINED BREATHING APPARATUS. MIXTURE WITH FUELS MAY EXPLODE. MAY IGNITE OTHER COMBUSTIBLE SUBSTANCES. CHLORINE IS AN OXIDIZER. " UNUSUAL FIRE AND EXPLOSION HAZARDS: . PRODUCT IS UNDER PRESSURE. HEATING OF CYLINDER COULD RESULT IN AN EXPLOSIVE RELEASE OF TOXIC AND REACTIVE GAS. -,---------------------------------------------------------~----------------- S:ECTION V - HEALTH HAZARD DATA Route(s) of Entry Inhalation: No Potential Carcinogen lists -- N.T.P.: No I.A.R.C. Monographs: No Skin: 'Yes Ingestion: Yes OSHA 'Regulated: No EFFECTS OF OVEREXPOSURE: SYSTEMS OF EXPOSURE ARE SEVERE EYE, NOSE AND ORAL IRRITATION WITH POSSIBLE NAUSEA, VOMITING, HEADACHE, DIZZINESS AND UNCONSCIOUSNESS. - POISONOUS BY INHALATION, INGESTION OR SKIN CONTACT. CONTACT MAY CAUSE BURNS TO SKIN AND EYES. EMERGENCY AND FIRST AID PROCEDURES:, EYE CONTACT--FLOOD EYES WITH WATER FOR 15 MINUTES, HOtDING EYELIDS APART DURING WASHING. DO NOT USE CHEMICAL ANTIDOTES. ·GET MEDICAL ATTENTION. SKIN CONTACT--FLOOD SKIN WITH WATER FOR 15 MINUTES. IF CLOTHIG IS CONTAMINATED, DIRECT A FLOW OF WATER UNDER THE CLOTHING WHILE CLOTHING IS BEING REMOVED. GET MEDICAL ATTENTION. . . INHALATION--REMOVE TO FRESH AIR. MAINTAIN AIRWAY AND USE ARTIFICAL RESUSCITATION IF NEEDED. GIVE OXYGEN IF BREATHING IS DIFFICULT. TREAT FOR SHOCK. KEEP PATIENT WARM AND AT REST. GET MEDICAL ATTENTION. , ' ---------------------------------------------------------------------------- SECTION VI - REACTIVITY DATA STABILITY: CHLORINE REACTS WITH MANY OTHER MATERIALS. ., -ING"OMPATABILITY: e e , WILL REACT VIOLENTLY WITH STRONG ACIDS AND OXIDIZERS. Page 3 REACTS VIGOROUSLY OR VIOLENTLY WITH WATER. MAY CAUSE FIRE FROM REACTION WITH ORGANIC MATERIALS. HAZARDOUS DECOMPOSITION PRODUCTS: REACTION WITH OTHER MATERIALS MAY PRODUCT TOXIC FUMES. HAZARDOUS POLYMERIZATION: N/A ADDITIONAL DESCRIPTION: N/A ---------------~---------------------------------~-------------------------- SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE OF SPILL: IF TANK IS RUPTURED AND LIQUID CHLORINE IS SPILLED OR TANK VALVE OR PIPING LEAKS, IMMEDIATELY EVACUATE ALL PERSONNEL FROM THE AREA AND NOTIFY LOCAL EMERGENCY RESPONSE TEAM, USUALLY THE FIRE DEPARTMENT. EVACUATE PERSONNEL IN THE UPWIND DIRECTION. IN PRESENCE OF FIRE EVACUATE A MINIMUM OF 1,500 FEET IN ALL DIRECTIONS. IF THERE IS NO FIRE, EVACUATE 1,000 FEET IN ALL DIRECTIONS. ALSO EVACUATE 1,500 FEET IN ALL DIRECTION IF THERE IS A VAPOR CLOUD. DO NOT ATTEMPT TO CONTAIN A SPILL OR FIX A LEAK UNLESS YOU ARE WEARING SELF-CONTAINED BREATHING APPARATUS, HAVE A LEAST ONE BACKUP PERSON, HAVE THE PROPER EQUIPMENT AND TRAINING IN ITS USE. WASTE DISPOSAL METHOD: DO NOT ATTEMPT DISPOSAL. NOTIFY LOCAL AUTHORITIES. ---------------------------------------------------------------------------- SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: NIOSH APPROVED MASK Local Exhaust Ventilation: ABLE TO MAINTAIN >0.5 PPM LEVEL. Mechanical Ventilation: N/A Special Ventilation: N/A Other Ventilation: N/A Protective Gloves: PLASTIC, AVOID RUBBER Eye Protection: AIR TIGHT GOGGLES. Other Protective Equipment: N/A ADDITIONAL DESCRIPTION: CHLORINE ODOR IS A GOOD WARNING PROPERTY. ALTHOUGH IT CAN' BE DETECTED BELOW THE PERMISSIBLE EXPOSURE LIM'rT, OLFACTORY FATIGUE CAN OCCUR. --------------------------------------------~------------~------------------ SECTION IX - SPECIAL PRECAUTIONS HANDLING, AND STORING ,PRECAUTION: STORAGE: Store in a cool, dry place. Do not contaminate water,food or feed by storage or disposal. REGULAR INSPECTED CYLINDERS, TANKS AND ALL EQUIPMENT INVOLVING CHLORINE. ffi]@ ATOCHEM NORTH AMERICA elf aq&itaine '- .e e ~~ ._-4--';'- ~"i!'! DECCD , . , AGRICHEMICALS DIVISION 17135, California Avenue, Monrovia. California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 35!H248 Page 4 Keep away from heat, sparks, flame. Use with adeqùate ventilation. Wash thoroughly after handling. EMPTY CONTAINER MAY CONTAIN HAZARDOUS RESIDUES. OTHER PRECAUTIONS: Contact with skin or eyes may cause severe irritation or burns. Contact with skin has a defatting affect, causing drying and irritation. . I SPILLAGE OF 10 POUNDS OR MORE OF CHLORINE (THE 'RQ AMOUNT) REQUIRES IMMEDIATE NOTIFICATION OF FEDERAL, STATE AND LOCAL AUTHORITIES. FAILURE TO MOTIFY "ALL" AFFECTED AGENCIES WILL RESULT IN LARGE FINES. The heritage: ~ and t.Wr The future: ATOCHEM NORTH AMERICA .. .-....J-: f1 If ,. " ~ MATERIAL SAFETY DATA SHEET e e ALL PURE· CHEMICAL COMPANY Post Office Box 268 · Tracy, CA 95376-0268 · Telephone (209) 835-5423 ALL PURE CHEMICAL CO. P.O. BOX 268 TRACY. CA 95376 EMERGENCY NUMBERS: (209) 835-5423 (209) 836-5405 ---- -------------------------~-------------------------------- PRODUCT IDENTIFICATION ----------------------------------------------------------- TRADE NAME: 1) ALL PURE APH CALCIUM TABS 2) ALL PURE CALCIUM HYPOCHLORITE GRANULES 3) ALL PURE SHOCKING GRANULES ------------------------------------------------------------ CHEMICAL NAME/SYNONYMS: CALCIUM HYPOCHLORITE, CAL HYPO CALCIUM HYPOCHLORITE TABLETS CHEMICAL FAMILY: HYPOCHLORITE FORMULA: CA(OCL)2 CASH: 07778-54-3 SUBSIDIARY RISK: N/A ------------------------------------------------------------ PHYSICAL DATA ------------------------------------------------------------ BOILING POINT @ 760 MM HG: DECOMPOSES AT 180 C VAPOR DENSITY (AIR=1): N/A SPECIFIC GRAVITY (H20=1): N/A PH OF SOLUTIONS: ALKALINE FREEZING/MELTING POINT: N/A SOLUBILITY (WEIGHT % IN WATER): 217 G/L @ 27 C BULK DENSITY: N/A VOLUME % VOLATILE: N/A VAPOR PRESSURE: N/A EVAPORATION RATE: N/A HEAT OF SOLUTION: SLIGHTLY EXOTHERMIC APPEARANCE AND ODOR: WH I TE POWDER W I HI SL I GHT CHLOR I NE ODOR ------------------------------------------------------------ INGREDIENTS ------------------------------------------------------------ MATERIAL CALCIUM HYPOCHLORITE (65% AVAILABLE CHLORINE) INERT (INCLUDES 5.5 - 20% MOISTURE) PERCENT 65% 35% PAGE 1 . e e ~ MATERIAL SAFETY DATA SHEETS (CO NT.) ------------------------------------------------------------ FIRE/EXPLOSION HAZARD DATA ------------------------------------------------------------ FLASH POINT (METHOD USED): NONE FLAMMABLE LIMITS IN AIR (% BY VOLUME): LEL: N/A UEL: N/A EXTINGUISHING MEDIA: WATER ONLY! SMOTHERING INEFFECTIVE- PRODUCT SUPPLIES OWN OXYGEN SPECIAL FIRE FIGHTING PROCEDURES: FIRE FIGHTERS MUST WEAR NIOSH/MSHA APPROVED. PRESSURE DEMAND SELF-CONTAINED BREATHING· APPARATUS WITH FULL FACE PIECE FOR POSSIBLE EXPOSURE TO HAZARDOUS GASES. UNUSUAL FIRE AND EXPLOSION HAZARDS: DECOMPOSES AT 180 C RELEASING OXYGEN GAS; CONTAINERS MAY RUPTURE. ------------------------------------------------------------ HEALTH HAZARD DATA ------------------------------------------------------------ TOXICITY DATA: LC50 INHALATION: (RAT) NO MORTALITY @ 3.5 MG/L (1 HR) LD50 DERMAL: (RABBIT) °1000 MG/KG SKIN/EYE IRRITATION: SEE SECTION 5 LD50 INGESTION: SEE SECTION 5 FISH. LC50 (LETHAL CONCENTRATION: TLM 96 HR: 10-1 PPM CLASSIFICATION: (POISON, IRRITANT. ETC.) INHALATION: IRRITATING SKIN: SLIGHTLY TOXIC SKIN/EYE: CORROSIVE INGESTION: SLIGHTLY TOXIC AQUATIC: HIGHLY TOXIC ------------------------------------------------------------ EFFECTS OF OVEREXPOSURE ------------------------------------------------------------ THIS SECTION COVERS EFFECTS OF OVEREXPOSURE FOR INHALATION. EYE/SKIN CONTACT. INGESTION AND OTHER TYPES OF OVEREXPOSURE INFORMATION IN THE ORDER OF THE MOST HAZARDOUS AND THE MOST LIKELY ROUTE OF OVEREXPOSURE. CHEMICAL IS NOT LISTED AS ^ CARCINOGEN OR POTENTIAL CARCINOGEN WITH NTP, IARC OR OSHA. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: NONE KNOWN PAGE 2 ... e e j MATERIAL SAFETY DATA SHEETS (CONT.) EFFECTS OF OVEREXPOSURE (CONT.) ------------------------------- PERMISSIBLE EXPOSURE LIMITS: NONE ESTABLISHED BY OSHA OR ACGIH FOR THIS PRODUCT. ACUTE: INHALATION: INHALATION OF CALCIUM HYPOCHLORITE DUST AND DEPOSITION OF PARTICLES IN THE RESPIRATORY TRACT CAN LEAD TO IRRITATION OF THE TISSUE AND CAUSE A VARIETY OF EFFECTS. THESE EFFECTS ARE DEPENDENT ON CONCENTRATION AND INCLUDE: UPPER RESPIRATORY TRACT IRRITATION. NASAL CONGESTION. COUGHING, SORE THROAT. LARYNGITIS AND SHORTNESS OF BREATH. IN OPERATIONS WHERE THERE ARE HIGH CONCENTRATIONS OF RESPIRABLE PARTICULATES. PULMONARY EDEMA (FLUID IN THE LUNG) MAY BE PRODUCED. IF NOT TREATED IMMEDIATELY. PULMONARY EDEMA CAN BE LIFE THREATENING. SINCE THIS PRODUCT IS IN TABLET FORM, PARTICLES OF RESPIRABLE SIZE ARE NOT GENERALLY ENCOUNTERED. EYE/SKIN: CALCIUM HYPOCHLORITE IS CORROSIVE TO THE EYES. CONTACT OF CALCIUM HYPOCHLORITE DUST WITH THE EYES. EVEN A MINUTE AMOUNT FOR A SHORT DURATION, CA CAUSE SEVERE IRRITATION AND EVEN BLINDNESS. CONTACT WITH THE SKIN MAY CAUSE SEVERE IRRITATION, BURNS, OR TISSUE DESTRUCTION. , IN STUDIES UTILIZING RABBITS, THE SKIN IRRITATION SCORE WAS 98.5/110 AND THE EYE IRRITATION SCORE WAS 8/8. THE CLASSIFICATION FOR BOTH OF THESE IS CORROSIVE. INGESTION: CALCIUM HYPOCHLORITE, IF SWALLOWED, CAUSES SEVERE BURNS TO THE DIGESTIVE TRACT AND CAN BE FATAL. CHRONIC: GENOTOXICITY: CALCIUM HYPOCHLORITE PRODUCED POSITIVE RESPONSES IN IN-VITRO ASSAYS USING BACTERIAL SYSTEMS (THE AMES TEST) AND CHROMOSOMAL ABERRATIONS IN CHINESE HAMSTER FIBROBLASTS. IN A WHOLE ANIMAL EXPERIMENT (MOUSE MICRONUCLEUS TEST), EXPOSURES RANGING FROM 20 TO 160 MG/KG PRODUCED NO COMPOUND RELATED CHROMOSOMAL ABNORMALITIES. HYPOCHLORITE, THE CARCINOGENIC POTENTIAL OF SODIUM HYPOCHLORITE WAS STUDIED IN F344 RATS. AFTER 104 WEEKS OF DRINKING WATER CONTAINING UP TO 2000 PPM SODIUM HYPOCHLORITE, THERE WAS NO EVIDENCE THAT THIS CHEMICAL PRODUCED ANY CARCINOGENIC RESPONSE. IN ADDITION, THIS EXPOSURE DID NOT RESULT IN ANY ADVERSE EFFECTS IN BLOOD, CLINICAL CHEMISTRY, OR OTHER TARGET ORGANS. PAGE 3 e e ~ t ~ MATERIAL SAFETY DATA SHEET (CO NT.) PERMISSIBLE EXPOSURE LIMITS (CONT.) ----------------------------------- ONE OF THE MAJOR USES OF CALCIUM HYPOCHLORITE IS AS A SOURCE OF CHLORINE FOR WATER SANITIZATION IN DRINKING AND RECREATIONAL WATER. STUDIES HAVE BEEN CONDUCTED TO DETERMINE THE LONG-TERM EFFECTS OF CHLORINATED DRINKING WATER. SEVEN GENERATIONS OF RATS WERE GIVEN 100PPM CHLORINE IN THEIR DRINKING WATER. NO DIFFERENCE IN FERTILITY, GROWTH, BLOOD PARAMETERS, OR SPECIFIC ORGAN TOXICITY WAS OBSERVED BETWEEN CONTROL AND EXPOSED ANIMALS. TWO SEPARATE ANIMAL STUDIES CONDUCTED BY DIFFERENT GOVERNMENT AGENCIES DETERMINED THAT THE CHLORINATION OF MUNICIPAL DRINKING WATER DID NOT RESULT IN TOXICITY TO THE DEVELOPING MOUSE FETUS. SAFE HANDLING OF THIS MATERIAL ON A LONG-TERM BASIS SHOULD EMPHASIZE MINIMIZING REPEATED ACUTE EXPOSURES. ------------------------------------------------------------- EMERGENCY AND FIRST AID PROCEDURES ------------------------~----------------------------------- INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING. GIVE ARTIFICIAL RESPIRATION. PREFERABLY MOUTH TO MOUTH. IF BREATHING IS DIFFICULT. GIVE OXYGEN. CALL A PHYSICIAN. EYE OR SKIN CONTACT: 'FLUSH, WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. FOR EYE CONTACT, GET IMMEDIATE MEDICAL ATTENTION. IF SKIN IRRITATION OCCURS, GET MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, DRINK LARGE QUANTITIES OF WATER AND ANY COMMON COOKING (VEGETABLE) OIL, IF AVAILABLE. 00 NOT INDUCE VOMITING. TAKE IMMEDIATELY TO A HOSPITAL OR PHYSICIAN. IF UNCONSCIOUS, OR IN CONVULSIONS, TAKE IMMEDIATELY TO A HOSPITAL. DO NOT ATTEMPT TO INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NOTES TO PHYSICIAN (INCLUDING ANTIDOTES): TREAT SYMPTOMATICALLY. ------------------------------------------------------------ REACTIVITY DATA ------------------------------------------------------------ STABILITY: UNSTABLE CONDITIONS TO AVOID: CONTAMINATION OR EXCESSIVE HEAT ABOVE 177 C HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NONE - WILL NOT POLYMERIZE INCOMPATIBILITY (MATERIALS TO AVOID): ACIDS. COMBUSTIBLE MATERIALS, ORGANICS, REDUCING AGENTS PAGE 4 7,' ! .. e ·e MATERIAL SAFETY DATA SHEET (CONT.) REACTIVITY DATA (tONT.) ----------------------- HAZARDOUS DECOMPOSITION PRODUCTS: ACIDS OR AMMONIA CONTAMINATION WILL RELEASE TOXIC GASES. EXCESSIVE HEAT WILL CAUSE DECOMPOSITION RESULTING IN THE RELEASE OF OXYGEN AND CHLORINE GAS. ------------------------------------------------------------ SPILL OR LEAK PROCEDURES ------------------------------------------------------------ STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED: NOTE: USE EXTREME CAUTION IN HANDLING SPILLED MATERIAL. CONTAMINATION WITH ORGANIC OR COMBUSTIBLE MATERIAL MAY CAUSE FIRE OR VIOLENT DECOMPOSITION. IF FIRE OR DECOMPOSITION OCCURS IN AREA OF SPILL. IMMEDIATELY DOUSE WITH PLENTY OF WATER. OTHERWISE. SWE~P UP ALL VISIBLE MATERIAL USING A CLEAN. DRY SHOVEL AND BROOM AND DISSOLVE MATERIAL IN WATER. DISPOSE OF WASTE MATERIAL AS OUTLINED. WASTE DISPOSAL METHOD: SPILLED MATERIAL THAT HAS BEEN SWEPT UP AND DISSOLVED IN WASTER SHOULD BE USED IMMEDIATELY IN THE NORMAL APPLICATION FOR WHICH CALCIUM HYPOCHLORITE IS BEING CONSUMED. IF THIS IS NOT POSSIBLE. CAREFULLY NEUTRALIZE DISSOLVED MATERIAL BY ADDING HYDROGEN PEROXIDE (ONE PINT OF 35% HYDROGEN PEROXIDE SOLUTION PER POUND OF CALCIUM HYPOCHLORITE TO BE NEUTRALIZED) THEN DILUTE THE NEUTRALIZED MATERIAL WITH PLENTY OF WATER AND FLUSH TO SEWER. NOTE: ONLY PROPERLY NEUTRALIZED MATERIAL SHOULD BE FLUSHED TO SEWER. UNNEUTRALIZËD MATERIAL CAN CAUSE ENVIRONMENTAL DAMAGE TO RECEIVING WATER OR CAN INTERFERE WITH TREATMENT PLANT OPERATION. FOR ON-SITE NEUTRALIZATION. CAREFULLY AND SLOWLY POUR THE APPROPRIATE QUANTITY OF 35% HYDROGEN PEROXIDE SOLUTION OVER ALL SPILLED MATERIAL THEN FLUSH AREA WITH PLENTY OF WATER. COMMENTS: CARE MUST BE TAKEN WHEN USING OR DISPOSING OF CHEMICAL MATERIALS AND/OR THEIR CONTAINERS TO PREVENT ENVIRONMENTAL CONTAMINATION. IT IS YOUR DUTY TO DISPOSE OF THE CHEMICAL MATERIALS AND/OR THEIR CONTAINERS IN ACCORDANCE WITH THE CLEAN AIR ACT. THE CLEAN WATER ACT. THE RESOURCE CONSERVATION AND RECOVERY ACT. FIFRA. AS WELL AS ANY OTHER RELEVANT FEDERAL. STATE. OR LOCAL LAWS/REGULATIONS REGARDING DISPOSAL. PAGE 5 e, e I';:> _ í ~ MATERIAL SAFETY DATA SHEET (CONT.) ------------------------------------------------------------ SPECIAL PROTECTION INFORMATION ------------------------------------------------------------ RESPIRATORY PROTECTION: IF DUSTY CONDITIONS ARE ENCOUNTERED. USE NIOSH/MSHA APPROVED RESPIRATOR WITH ACID GAS CARTRIDGE AND DUST PREFILTER. THE RESPIRATOR USE LIMITATIONS SPECIFIED BY NIOSH/MSHA OR THE MANUFACTURER MUST BE OBSERVED. RESPIRATORY PROTECTION PROGRAMS MUST BE IN ACCORDANCE WITH 29 CFR 1910.134. VENTILATION (TYPE): NONE. UNLESS DUSTY CONDITIONS ARE ENCOUNTERED EYE PROTECTION: CHEMICAL SAFETY GOGGLES GLOVES: NATURAL OR SYNTHETIC RUBBER OTHER PROTECTIVE EQUIPMENT: BOOTS. APRONS. OR CHEMICAL SUITS SHOULD BE USED WHEN NECESSARY TO PREVENT SKIN CONTACT. PERSONAL PROTECTIVE CLOTHING AND USE OF EQUIPMENT MUST BE IN ACCORDANCE WITH 29 CFR 1910.132 AND 29 eFR 1910.133. ------------------------------------------------------------ SPECIAL PRECAUTIONS ------------------------------------------------------------ PRECAUTIONS TO BE TAKEN DURING HANDLING AND STORING: DO NOT GET IN EYES. ON SKIN OR ON CLOTHING. KEEP IN ORIGINAL CONTAINER IN A COOL. DRY PLACE. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT SOURCES. SPARKS, OPEN FLAMES AND LIGHTED TOBACCO PRODUCTS. USE ONLY A CLEAN. DRY SCOOP MADE OF METAL OR PLASTIC EACH, TIME THIS PRODUCT IS TAKEN FROM CONTAINER DO NOT ADD THIS PRODUCT TO ANY DISPENSING DEVICE CONTAINING REMNANTS OF ANY OTHER PRODUCT. SUCH USE MAY CAUSE VIOLENT REACTION LEADING TO FIRE OR EXPLOSION ADD THIS PRODUCT TO WATER/NEVER ADD WATER TO PRODUCT MAY CAUSE FIRE OR EXPLOSION IF MIXED WITH OTHER CHEMICALS FIRE MAY RESULT IF CONTAMINATED WITH ACIDS OR EASILY COMBUSTIBLE MATERIAL SUCH AS OIL. KEROSENE. GASOLINE. PAINT PRODUCTS AND MOST OTHER ORGANIC MATERIALS. WASH HANDS AFTER HANDLING. PAGE 6 ,:t¡. ,,1 . e e MATERIAL SAFETY DATA SHEET (CONT.) SPECIAL PRECAUTIONS (CONT.) --------------------------- DO NOT REUSE CONTAINER. RESIDUAL MATERIAL REMAINING IN EMPTY DRUM CAN REACT TO CAUSE FIRE. THOROUGHLY FLUSH EMPTY CONTAINER WITH WATER THEN DESTROY BY PLACING IN TRASH COLLECTION. WASTES RESULTING FROM THE USE OF THIS PRODUCT MAY BE DISPOSED OF ON SITE OR AT AN APPROVED WASTE DISPOSAL FACILITY. DO NOT CONTAMINATE WATER, FOOD, OR FEED BY STORAGE OR DISPOSAL. OTHER PRECAUTIONS: KEEP OUT OF REACH OF CHILDREN STRONG OXIDIZER - FIRE MAY RESULT FROM CONTACT WITH HEAT, ACIDS, ORGANIC OR COMBUSTIBLE MATTER. MAY BE FATAL OR HARMFUL IF SWALLOWED MAY CAUSE CHEMICAL BURNS. IRRITATING TO NOSE AND THROAT - AVOID BREATHING DUST. COMMENTS: TSCA - CALCIUM HYPOCHLORITE SARA TITLE III - A) 311/312 CATEGORIES - ACUTE AND REACTIVITY, B) NOT LISTED IN SECTION 313, C) NOT LISTED AS AN /I EXTREMEL Y HAZARDOUS SUBSTANCE /I I N SECT ION 302. ' CERCLA - LISTED IN TABLE 302.4 DF 40 CFR PART 302 AS A . HAZARDOUS SUBSTANCE WITH A REPORTABLE QUANTITY OF 10 POUNDS. RELEASES TO AIR, LAND OR WATER WHICH EXCEED THE RQ MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER, 800-424-8802 FIFRA - CALCIUM HYPOCHLORITE IS REGISTERED WITH EPA AS A PESTICIDE. ------------------------------------------------------------ U.S. DEPT. OF TRANSPORTATION (D.O.T.) SHIPPING INFORMATION ------------------------------------------------------------ PROPER SHIPPING NAME: CALCIUM HYPOCHLORITE, HYDRATED IDENTIFICATION NUMBER: UN2880 HAZARD CLASS: OXIDIZER LABELS REQUIRED: OXIDIZER REPORTABLE QUANTITIY: 10 Ibs./4.5 kg --~--------------------------------------------------------- PAGE 7 - e ~ ""..-. ~ MATERIAL SAFETY DATA SHEET (CONT.) THE 'INFORMATION IN THIS MSDS HAS BEEN ASSEMBLED BY THE MANUFACTURER BASED ON WORKS OF OTHERS WHICH ARE FOUND IN LITERATURE IN THE PUBLIC DOMAIN. IT RELATES TO THE SPECIFIC MATERIAL DESIGNATED HEREIN AND DOES NOT RELATE TO USE IN COMBINATION WITH ANY OTHER MATERIAL IN ANY PROCESS. THE INFORMATION SET FORTH HEREIN IS FURNISHED FREE OF CHARGE AND IS BASED ON TECHNICAL DATA THAT All PURE CHEMICAL CO. BELIEVES TO BE RELIABLE. IT IS INTENDED FOR USE BY PERSONS HAVING TECHNICAL SKILL AND AT THEIR OWN DISCRETION AND RISK. SINCE CONDITIONS OF USE ARE OUTSIDE OUR CONTROL, THE MANUFACTURER SHALL NOT BE LIABLE (REGARDLESS OF FAULT) TO THE VENDEE, THE VENDEE'S EMPLOYEES OR ANYONE ELSE FOR ANY DIRECT. SPECIAL OR CONSEQUENTIAL DAMAGES ARRIVING OUT OR IN CONNECTION WITH THE ACCURACY. COMPLETENESS, ADEQUACY OR FURNISHING OF SUCH INFORMATION. NOTHING HEREIN IS TO BE TAKEN AS A lICENSE TO OPERATE UNDER OR A RECOMMENDATION TO INFRINGE ANY PATENTS. DATE OF lATEST REVISION; MARCH 1, 1990 PAGE 8 "~¡':'.b"_" "..., "0 / ' , L. , ATQCHEM ~~RTH AMERICA etf aquitaine e ,-e IJEI:I:D ~':;~" ", ,.'...' .... , , "'0,'" '''''1 ' " j" ,.~ ...'¡ _.:'!t:....~.,':':..:: . ".;,1 ',,':"", .~;.:L:··{'- " AGRICHEMICALS DIVISION 1713 S, California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 MATERIAL SAFETY DATA SHEET Page 1 ' DATE: 01/01/91 ---------------------------------------------------------------------------- MANUFACTURER'S INFORMATION ATOCHEM NORTH AMERICA, DECCO 1713 South California Ave. Monrovia CA 91016-0120 EMERGENCY CONTACT Robert J. Johnson 818-358-1838 ---------------------------------------------------------------------------- SECTION 1- IDENTITY Quick I.D.: DECCOSOL l22 Chemical Name: N/A Trade Name Synonyms: ortho-PHENYLPHENOL AND CLEANER CONCENTRATE Chemical Family: FUNGICIDE & CLEANER Formula: MIXTURE DOT Freight Classification: Irritating material ----~-,------------~--------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME % TLV UNITS CAS Number -------------------------------------------------------------------------- ortho-PHENYLPHENOL (SODIUM SALT) SODIUM HYDROXIDE DOWFAX 2A1 (MIXTURE) SODIUM METASILICATE 13.2 4.80 7.5 5.0 2.0 5.0 00090-43-7 Mg/M3 01310-73-2 Mg/M3 06834-92-0 HAZARDOUS INGREDIENTS DESCRIPTION: O-PHENYLPHENOL LD50(ORAL)=2000 MG/KG (RAT) SODIUM HYDROXIDE EXTREMELY CORROSIVE DOWFAX 2Al EYE & SKIN IRRITANT SODIUM METASILICATE SEVERE EYE & SKIN IRRITANT FOR THE PRODUCT: LD50(ORAL) = >5 G/KG (RAT) LAD50(DERMAL) = >2 G/KG (RABBITS) ------------------------------------------------------------~--------------- ,SECTION III ~ PHYSICAL DATA Boiling Point: 220 F Vapor Density: N/A (Air = 1) Specific Gravity: 1.11 Evaporation Rate: N/A EPA Physical State Catagory: Vapor Pressure: N/A mmHg Solubility in Water: 100% Percent Volatile by Volume: Comparison Material: N/A Liquid Mixture 73% APPEARANCE AND ODO~A¡~~~Ig¡~QN: CLEAR AMBER LIQt[Îïf'WÍT'ir'A~~ m- T~~f~tt1e: ATOCHEM NORTH AMERICA e e Page 2 -~--------------------------------------------------------------~----------- SECTION IV - FIRE AND EXPLOSION HAZARD DATA .., ·"11 " Flash Point: N/A F Lower Flammable Limit: NFPA Code: 200K EPA Hazard Codes: N/A Method Used: N/A Upper Flammable Limit: N/A EXTINGUISHING MEDIA: NON-FLAMMABLE. SPECIAL FIRE FIGHTING PROCEDURES: N/A UNUSUAL FIRE AND EXPLOSION HAZARDS: HEATING OR SPILLAGE OF THIS PRODUCT MAY RELEASE ORTHOPHENYLPHENOL VAPOR. ---------------------------------------------------------------------------- SECTION V ~ HEALTH HAZARD DATA Route(s) of Entry Inhalation: No Potential Carcinogen lists -- N.T.P.: No I.A.R.C. Monographs: No Skin: Yes Ingestion: Yes OSHA Regulated: No EFFECTS OF OVEREXPOSURE: TOXICITY OF THE MIXTURE. LD50(ORAL)=5G/KG (RAT) LD50(DERMAL)=2G/KG (RABBIT) SEVERE IRRITATION OF EYES & SKIN EMIERGENCY AND FIRST AID PROCEDURES: EYES: & SKIN:In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. INGESTION:If swallowed, do NOT induce vomiting; if conscious, give large amounts of water. Follow with diluted vinegar, fruit juice òr white of eggs, beaten with water. Get medical attention. --1---------------------------------------------------_________~_____________ SE~TION VI - REACTIVITY DATA STABILITY: PRODUCT IS STABLE. NOTE-ortho- PHENYLPHENOL is present as the sodium salt'. If the pH is allowed to drop below 12.0 the ratio of OPP to NaOPP will increase greatly. This condition could result in fruit damage and an increase in the escape of volitle OPP to the atmosphere. INCOMPATABILITY: PRODUCT IS INCOMPATIBLE WITH STRONG ACIDS AND OXIDIZERS. HAZARDOUS DECOMPOSITION PRODUCTS: HEAT OR A DROP IN pH WILL RESULT IN o-PHENYLPHENOL VAPOR. HAZARDOUS POLYMERIZATION: ¿\. -." , . .. 'i·.~ ~:".~"" ,., , . .._i;;~~. ' " , " 'J""f"~ ~¡f:'.~ I; '~j::?,.-r~~, .t. " . . - ". . .-. . .. .... ...'~.....,.¡; ~ .~:.·t.~...,:. ;.c. .;'::;'.~';..-~).~~.~.: -f~ ~ .. AtOèHEM NORTH AMERICA elf aquitaine '~',a .,- ~~. . .:. ~,-~:;- . .'.:~~ '.'¡." . CECCO AGRICHEMICALS DIVISION 1713 S, California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 Page 3 N/A ADDITIONAL DESCRIPTION: N/A ---------------------------------------------------------------------------- SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE OF SPILL: ABSORB WITH INERT MATERIAL AND SCOOP UP INTO WASTE CONTAINER. NEUTRALIZE WITH A WEAK ACID. PREVENT SPREAD OF THE SPILL. WASTE DISPOSAL METHOD: CONSULT WITH LOCAL, STATE OR FEDERAL AUTHORITIES FOR PROPER DISPOSAL METHODS. ---------------------------------------------------------------------------- SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: NIOSH approved dust & nuisence mask Local Exhaust Ventilation: CAPABLE OF REDUCING LOCAL EMISSIONS Mechanical Ventilation: N/A Special Ventilation: N/A Other Ventilation: N/A Protective Gloves: RUBBER Eye Protection: GOGGLES Other Protective Equipment: RUBBER BOOTS, EYE WASH & SHOWER. ADDITIONAL DESCRIPTION: N/A ---------------------------------------------------------------------------- SECTION IX - SPECIAL PRECAUTIONS HANDLING AND STORING PRECAUTION: Wash thoroughly after handling. Use with adequate ventilation. Do not contaminate water I food or feed by storage or disposal. STORAGE: Store in a cool, dry place. Store in tightly closed container. EMPTY CONTAINER MAY CONTAIN HAZARDOUS RESIDUES. OTHER PRECAUTIONS: PESTICIDE DISPOSAL: Pesticide, spray mixture or rinse water that cannot be used according to label instructions must be disposed of according to applicable Federal, State or Local procedures. CONTAINER:TRIPLE RINSE CONTAINER AND ADD RINSATES TO APPLICATION SYSTEM RINSED CONTAINER CAN THEN BE OFFERED FOR RECYCLING OR DISPOSED OF. ATOCHEM NORTH AMERICA, INC. MONROVIA, CA 91017-0120 DECCOSOL 122 The heritage: foJEtMWI and M8f The future: ATOCHEM NORTH AMERICA - :---,.-~ . . (~i~ 1\~~) ATOCHEM NORTH AMERICA elf aquitaine e e DECCC AGRICHEMICALS DIVISION 1713 S. Califqrnia Avenue, Monrovia, California 91016,0120 Tel: (818) 358-1838. Tlx: 4720597. Fax: (818) 359-7248 MATERIAL SAFEæy DAT~SHEET DATE: Page 1 01/91/ 1 ".- ------------------------------------\-~-------~~---------------------------- MANUFACTURERIS INFORMATION ATOCHEM NORTH AMERICA, DECCO 1713 South California Ave. Monrovia CA 91016-0120 ,. EMERGENCY CONTACT Robért J. Johnson ., 818 -'358 -18 3 8 ---------------------------------------------------------------------------- SECTION I - IDENTITY .. Quick I.D.: DECCOSOL 125 Chemical Name: N/A Trade Name Synonyms: ortho-PHENYLPHENOL &"CLEANER CONCENTRATE Chemical Family: FUNGICIDE & SOAP Formula: MIXTURE DOT Freight Classification:lrritatingnÌá.t~·riaï ,::. J. ¡. ---------------------------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME %, TLV UNITS CAS Number ----------------------------_._-------------~~----------------------------- ortho-PHENYLPHENOL (SODIUM SALT) SODIUM HYDROXIDE SODIUM METASILICATE 13.2 4.'80 5.0 2.0 00090-43-7 Mg/M3 01310-73-2 06834-92-0 HAZARDOUS INGREDIENTS DESCRIPTION: ortho-PHENYLPHENOL LD50(ORAL)=2,OOO MG/KG (RAT) SODIUM HYDROXIDE EXTREMELY CORROSIVE SODIUM METASILICATE SEVERE EYE & SKIN IRRITANT FOR THE PRODUCT, DECCOSOL 125 LD50(ORAL)=>5,OOO MG/KG (RAT) ---------------------------------------------------------------------------- SECTION III - PHYSICAL DATA Boiling Point: 220A F Vapor Density: N/A (Air = 1) Specific Gravity: 1.09 Evaporation Rate: N/A EPA Physical State Catagory: Vapor Prèssure: N/A mmHg Solub{li~y in Water: 100 Percent Volatile by Volume: Comparison Material: N/A Liquid Mixture 77.5% APPEARANCE AND ODOR DESCRIPTION: CLEAR AMBER LIQUID WITH A pH OF 13.0 ---------------------------------------------------------------------------- SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A F Method Used: N/A Lower Flammable Limit: N/A Upper Flammable Limit: N/A NFPA Code: 200K EPA Hazard Codes: The heritage: ~ and MBiI" Thefuture:ATOCHEMNORTHAMERICA ., ... -,_._"-k._J..._'-'':;--""=<~'-;:;'''''''' e e -~' 'ì ~age 2 EXTINGUISHING MEDIA: PRODUCT IS NON-FLAMABLE. SPECIAL FIRE FIGHTING PROCEDURES: N/A UNUSUAL FIRE AND EXPLOSION HAZARDS: HEATING OR SPILLAGE OF THIS PRODUCT MAY RELEASE ORTHOPHENYLPHENOL VAPORS. ---------------------------------------------------------------------------- SECTION V - HEALTH HAZARD DATA Route(s) of Entry Inhalation: No Potential Carcinogen lists -- N.T.P.: No I.A.R.C. Monographs: No Skin: Yes Ingestion: Yes OSHA Regulated: No EFFECTS OF OVEREXPOSURE: TOXICITY OF THE MIXTURE LD50(ORAL)=>5 G/KG (RAT) LD50(DERMAL)=2 G/KG (RABBIT) SEVERE IRRITATION OF EYES & SKIN. EMERGENCY AND FIRST AID PROCEDURES: INGESTION:lf swallowed, do NOT induce vomiting; if conscious, give large amounts of water. Follow with diluted vinegar, fruit juice or white of eggs, beaten with water. Get medical attention. EYES & SKIN: In case of .contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. ---------------------------------------------------------------------------- SECTION VI - REACTIVITY DATA STABILITY: PRODUCT IS STABLE NOTE-ortho-PHENYLPHENOL is present as the sodium salt. If the pH is allowed to drop below 12.0, the ration of OPP to NaOPP will increase greatly. This condition could result in fruit damage and an increase in the escape of volitle OPP to the atmosphere. ·INCOMPATABILITY: PRODUCT IS INCOMPATABLE WITH STRONG ACIDS AND OXIDIZERS. HAZARDOUS DECOMPOSITION PRODUCTS: HEAT OR A DROP IN pH WILL RESULT IS o-PHENYLPHENOL VAPOR. HAZARDOUS POLYMERIZATION: N/A ADDITIONAL DESCRIPTION: N/A ---------------------------------------------------------------------------- SECTION VIr - SPILL OR LEAK PROCEDURES /~ !~¿, ATOCHEM NORTH AMERICA elf aquitaine e e IJE[:[:C AGRICHEMICALS DIVISION 1713 S, California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 Page 3 STEPS TO BE TAKEN IN CASE OF SPILL: NEUTRALIZE WITH A WEAK ACID SUCH AS VINEGAR. ABSORB WITH ABSORBANT AND SWEEP UP. PREVENT SPREAD OF THE SPILL. WASTE DISPOSAL METHOD: Do not contaminate water, food or feed by storage or disposal. CONSULT WITH LOCAL, STATE AND FEDERAL AUTHORITIES FOR PROPER PROCEDURES. ---------------------------------------------------------------------------- SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: NIOSH approved dust & nuisence mask Local Exhaust Ventilation: CAPABLE OF REDUCING LOCAL EMISSIONS Mechanical Ventilation: N/A Special Ventilation: N/A Other Ventilation: N/A Protective Gloves: RUBBER Eye Protection: GOGGLES Other Protective Equipment: RUBBER BOOTS, EYE WASH & SHOWER. ADDITIONAL DESCRIPTION: N/A ---------------------------------------------------------------------------- SECTION IX - SPECIAL PRECAUTIONS HANDLING AND STORING PRECAUTION: Store and use with adequate ventilation. Avoid contact with eyes, skin I clothing. Keep in tightly closed container. Wash thoroughly after handling. Empty container may contain hazardous residues. OTHER PRECAUTIONS: STORAGE: Store in a cool, dry place. PESTICIDE DISPOSAL: Pesticide, spray mixture or rinse water that cannot be used according to label instructions must be disposed of according to applicable Federal, State or Local procedures. CONTAINER:TRIPLE RINSE CONTAINER AND ADD RINSATES TO APPLICATION SYSTEM. RINSED CONTAINER MAY BE RECYCLED OR DISPOSED OF. ATOCHEM NORTH AMERICA, INC. MONROVIA, CA 91016 DECCOSOL 125 The heritage: fõJEtHW\I1 and MB" The future: ATOCHEM NORTH AMERICA ~;:-=/~ ~~\:::J ATOCHEM NORTH AMERICA elf aquitaine e e IJEI:I:D AGRICHEMICALS DIVISION 1713 $, California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 MATERIAL SAFETY DATA SHEET Page 1 DATE: 06/25/91 ---------------------------------------------------------------------------- MANUFACTURER'S INFORMATION ATOCHEM NORTH AMERICA, DECCO 1713 South California Ave. Monrovia CA 91016-0120 EMERGENCY CONTACT Robert J. Johnson 818-358-1838 ---------------------------------------------------------------------------- SECTION I - IDENTITY Quick I.D.: DECCOSAN 315 Chemical Name: N/A Trade Name Synonyms: DISINFECTANT-DEODORIZER-SANITIZER Chemical Family: N/A Formula: MIXTURE DOT Freight Classification: Irritating material ---------------------------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME % TLV UNITS CAS Number -------------------------------------------------------------------------- ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDE 5 n-ALKYL DIMETHYL ETHYLBENZYL AMMONIUM CH 5 HAZARDOUS INGREDIENTS DESCRIPTION: n-ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDES. LD50(ORAL)=477 MG/KG (RATS) n-ALKYL DIMETHYL ETHYLBENZYL AMMONIUM CHLORIDES. LD50(ORAL)=477 MG/KG (RATS) DANGER--CORROSIVE, CAUSES SEVERE EYE AND SKIN DAMAGE. ---------------------------------------------------------------------------- SECTION III - PHYSICAL DATA .Boiling Point: 212 F Vapor Density: N/A (Air = 1) :Specific Gravity: 0.99 Evaporation Rate: >1 EPA Physical State Catagory: Vapor Pressure: N/A mmHg Solubility in Water: 100 Percent Volatile by Volume: Comparison Material: WATER Liquid Mixture 90% APPEARANCE AND ODOR DESCRIPTION: CLEAR, WATERY LIQUID WITH A pH OF 8. ---------------------------------------------------------------------------- SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A F Lower Flammable Limit: N/A NFPA Code: 200C EPA Hazard Codes: Method Used: N/A Upper Flammable Limit: N/A The heritage: fõI9HWW' and M!Jf The future: ATOCHEM NORTH AMERICA · '.<;;10'-'" e e ~-.......... ..,.Pa" ge~·2· '" 't;¿J1 EXTINGUISHING MEDIA: N/A SPECIAL FIRE FIGHTING PROCEDURES: N/A UNUSUAL FIRE AND EXPLOSION HAZARDS: N/A ---------------------------------------------------------------------------- SECTION V - HEALTH HAZARD DATA Route(s) of Entry Inhalation: No Potential Carcinogen lists -- N.T.P.: No I.A.R.C. Monographs: No Skin: No Ingestion: Yes OSHA Regulated: No EFFECTS OF OVEREXPOSURE: EYES:CONTACT WITH EYES IS IRRITATING AND MAY CAUSES PERMANENT DAMAGE IF NOT TREATED 'IMMEDIATELY. SKIN:PROLONGED OR REPEATED CONTACT WTIH SKIN MAY CAUSE IRRITATION. INHALATION:MIST CAUSED BY CLEANING OPERATIONS MAY IRRITATE NASAL PASSAGES. PROLONGED INHALATION OF VAPORS CAUSES NAUSEA, LOSS OF MOTOR SKILLS AND DISORIENTATION. UNNECESSARY EXPOSURE TO THIS PRODUCT OR ANY CHEMICAL SHOULD BE AVOIDED. EMERGENCY AND FIP.ST AID PROCEDURES: EYES: & SKIN:ln case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. INHALATION:lf inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. INGESTION:IF SWALLOWED, CONSULT A PHYSICIAN IMMEDIATELY. IF CONSCIENCE GIVE MILK, EGG WHITES OR GELATIN SOLUTION OR IF THESE ARE NOT AVAILIABLE, GIVE LARGE VOLUME OF WATER. DO NOT INDUCE VOMITING. NOTE TO PHYSICIAN--Probably mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression, and convulsion may be needed. ---------------------------------------------------------------------------- SECTION VI - REACTIVITY DATA STABILITY: PRODUCT IS NORMALLY STABLE. INCOMPATABILITY: AVOID STRONG OXIDIZERS. HAZARDOUS DECOMPOSITION PRODUCTS: NITROUS OXIDES AND AMMONIACAL VAPO HAZARDOUS POLYMERIZATION: N/A ~r~ ~\0J ATOCHEM NORTH AMERICA elf aquitaine - e CECCC AGRICHEMICALS DIVISION 1713 S, California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 Page 3 ADDITIONAL DESCRIPTION: N/A ---------------------------------------------------------------------------- SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE OF SPILL: N/A WASTE DISPOSAL METHOD: N/A ---------------------------------------------------------------------------- SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: NIOSH MASK FOR ORGANIC VAPORS. Local Exhaust Ventilation: RECOMMENDED Mechanical Ventilation: N/A Special Ventilation: N/A Other Ventilation: N/A Protective Gloves: RUBBER Eye Protection: GOGGLES OR FACE SHEILD Other Protective Equipment: EYE WASH & SAFETY SHOWER ADDITIONAL DESCRIPTION: N/A ---------------------------------------------------------------------------- SECTION IX - SPECIAL PRECAUTIONS HANDLIN8~D STORING PRECAUTION: PESTICIDE DISPOSAL: Pesticide, spray mixture or rinse water that cannot be used according to label instructions must be disposed of according to applicable Federal, State or Local procedures. CONTAINER DISPOSAL: Triple rinse drum or pail with water and add rinsates to tank. Container may then recycled or disposed of locally. Wash thoroughly after handling. Store and use with adequate ventilation. Avoid breathing vapors and contact with skin and eyes. Do not contaminate water, food or feed by storage or disposal. EMPTY CONTAINER MAY CONTAIN HAZARDOUS RESIDUES. Keep away from heat, sparks, flame. Keep in tightly closed container. OTHER PRECAUTIONS: DECCOSAN 315 ATAOCHEM NORTH AMERICA, INC. MONROVIA, CA 91016 The heritage: ~ and MI' The future: ATOCHEM NORTH AMERICA , J ~mJ@ ATOCHEM NORTH AMERICA elf aquitaine -- e Der:r:[] AGRICHEMICALS DIVISION 1713 S, California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 MATERIAL SAFETY DATA SHEET Page 1 DATE: 07/17/91 ---------------------------------------------------------------------------- MANUFACTURERIS INFORMATION ATOCHEM NORTH AMERICA, DECCO 1713 South California Ave. Monrovia CA 91016-0120 EMERGENCY CONTACT Robert J. Johnson 818-358-1838 ---------------------------------------------------------------------------- SECTION I - IDENTITY Quick I.D.: DECOSAN 320 Chemical Name: N/A Trade Name Synonyms: CLEANER AND SANITIZER. Chemical Family: N/A Formula: MIXTURE DOT Freight Classification: Irritating material ---------------------------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME % TLV UNITS CAS Number -------------------------------------------------------------------------- n-ÀLKYL DIMETHYL BENZYL AMMONIUM CHLORID 3 NEUTRONYX 656 5 PERMA KLEEN 100 2.7 HAZARDOUS INGREDIENTS DESCRIPTION: n-ALKYL DIMETHYL BENZYL AMMONIUM CHLORIDES. LD50 (ORAL) = 477 MG/KG (RATS) CORROSIVE-EYE IRRITANT NEUTRONYX 656(NONIONIC ALKOXYLATE). EYE AND SKIN IRRITANT PERMA KLEEN 100 (CHELATING AGENT) CORROSIVE-EYE IRRITANT. ---------------------------------------------------------------------------- SECTION III - PHYSICAL DATA Boiling Point: 198 F Vapor Density: N/A (Air = 1) Specific Gravity: 1.04 Evaporation Rate: >1 EPA Physical State Catagory: Vapor Pressure: N/A mmHg Solubility in Water: 100 Percent Volatile by Volume: Comparison Material: WATER Liquid Mixture 82% APPEARANCE AND ODOR DESCRIPTION: LIQUID WITH A pH OF 12 ---------------------------------------------------------------------------- SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: N/A F Lower Flammable Limit: N/A Method Used: N/A Upper Flammable Limit: N/A The heritage: ~ and tIM The future: ATOCHEM NORTH AMERICA .." . .". -. . -' ,:..-_-;,.;,-'....:"'''~....·,:.)~.d~·,:;,!.-'"'t!í~.:~,:.!.~"'!;;!..r:··:~.\ -.,\.;$ ;:J~~".C::::: - .~._ ._''::. : ~~, . L·.' .~.~'1.~.~_.".. . "·,·'.r..,:"'" .~: . :..'.,:. :__~. \.\:-~'¡1: ~Ct7,·:~~i-;''5ij'Iii,,.~¿;t~c~.. 'I \ e e d.~, Page 2 NFPA Code: 200C EPA Hazard Codes: EXTINGUISHING MEDIA: N/A SPECIAL FIRE FIGHTING PROCEDURES: N/A UNUSUAL FIRE AND EXPLOSION HAZARDS: N/A ---------------------------------------------------------------------------- SECTION V - HEALTH HAZARD DATA Route(s) of Entry Inhalation: No Potential Carcinogen lists -- N.T.P.: No I.A.R.C. Monographs: No Skin: No Ingestion: Yes OSHA Regulated: No EFFECTS OF OVEREXPOSURE: CONTACT WITH EYES IS PAINFUL AND IRRITATING. PROLONGED OF REPEATED CONTACT WITH SKIN CAUSES IRRITATION. MIST CAUSED BY MANUFACTURING OPERATIONS IRRITATES NASAL PASSAGES. PROLONGED INHALATION OF VAPORS CAUSES NAUSEA, LOSS OF MOTOR SKILLS AND DISORIENTATION. CHRONIC EFFECTS AND MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE TO THIS PRODUCT HAVE NOT BEEN ESTABLISHED. UNNECESSARY EXPOSURE TO THIS PRODUCT OR ANY CHEMICAL SHOULD BE AVOIDED. EMERGENCY AND FIRST AID PROCEDURES: EYES-FLUSH EYES IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN-WASH OFF SKIN WITH WATER, REMOVE CONTAMINATED CLOTHING AND CLEAN BEFORE REUSE. INHALATION-IF VAPORS OR MIST CAUSE IRRITATION OR DISTRESS, GO TO FRESH AIR. GIVE OXYGEN OR APPLY ARTIFICIAL RESPIRATION, IF NEEDED. INGESTION-IF SWALLOWED, CONSULT A PHYSICIAN IMMEDIATELY. ---------------------------------------------------------------------------- SECTION VI - REACTIVITY DATA STABILITY: PRODUCT IS NORMALLY SABLE. INCOMPATABILITY: AVOID STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS: NITROUS OXIDES AND AMMONIACAL VAPORS. HAZARDOUS POLYMERIZATION: N/A ADDITIONAL DESCRIPTION: N/A __'-'--_'___h,_";".. '~--"~""">I'-_~~' 'mJ@) ATOCHEM NORTH AMERICA elf aquitaine - e DECCD AGRICHEMICAlS DIVISION 1713 S. California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 I. Page 3 ---------------------------------------------------------------------------- SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE OF SPILL: CONTAIN ALL SPILLS AND LEAKS TO PREVENT DISCHARGE INTO THE ENVIRONMENT. SMALL SPILLS-SOAK UP WITH ABSORBANT, SHOVEL INTO WASTE CONTAINER, FLUSH AREA WITH WATER. LARGE SPILLS-RECOVER LIQUID FOR REPROCESSING OR DISPOSAL. RECOVER MATERIAL OR DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. WASTE DISPOSAL METHOD: CONSULT LOCAL, STATE OR FEDERAL AUTHORITIES FOR PROPER PROCEDURES. ---------------------------------------------------------------------------- SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: NIOSH APPROVE ORGANIC VAPOR MASK. Local Exhaust Ventilation: ADEQUATE TO MAINTAIN TLV LEVELS. Mechanical Ventilation: N/A Special Ventilation: N/A Other Ventilation: N/A Protective Gloves: RUBBER Eye Protection: GOGGLES Other Protective Equipment: EYE WASH & SAFETY SHOWER. ADDITIONAL DESCRIPTION: N/A ---------------------------------------------------------------------------- SECTION IX - SPECIAL PRECAUTIONS HANDLING AND STORING PRECAUTION: PESTICIDE DISPOSAL: Pesticide, spray mixture or rinse water that cannot be used according to label instructions must be disposed of according to applicable Federal, State or Local procedures. CONTAINER DISPOSAL: Triple rinse drum or pail with water and add rinsates to tank. Container may then recycled or disposed of locally. EMPTY CONTAINER MAY CONTAIN HAZARDOUS RESIDUES. Avoid contact with eyes, skin, clothing. SPILLED MATERIAL IS SLIPPERY. Wash thoroughly after handling. Keep in tightly closed container. Avoid breathing vapor. OTHER PRECAUTIONS: DECCOSOL 320 ATOCHEM NORTH AMERICA, INC. MONROVIA, CA 91016 The heritage: I'1ENMAII and M!r The future: ATOCHEM NORTH AMERICA ~.~ ¡~ ~\U \:::J . ATOCHEM NORTH AMERICA elf aquItakIe e e IJEE:E:C AGRICHEMICALS DIVISION 1713 S, California Avenue. Monrovia. Calilornia 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 MATERIAL SAFETY DATA SHEET DATE: Page 1 01/01/91 ---------------,--------------------------------------------------------~---- MANUFACTURER'S, INFORMAT~ON ATQCHEM NORTH AMERICA, DECCO 1713 South California Ave. Monrovia CA 91016-0000 EMERGENCY CONTACT Robert J. Johnson 818-358-1838 ---------------------------------------------------------------------------- SECTION I - IDENTITY Quick I. D.: DECCO APL LUSTR 221 Chemical Name: N/A Trade Name Synonyms:' HI-SHINE APPLE WAX Chemical Family: WAX Formula: MIXTURE DQT Freight Classification~ ---------------------------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME % TLV UNITS CAS Number ---------------------------------------------.----------------------------- MORPHOLINÈ AMMONIUM HYDROXIDE ISOPROPYL ALCOHOL 3.0 2.0 20.0 20.0 25.0 400.0 PPM PPM PPM 110-91-8 1336-21-6 67-63-0 HAZARDOUS INGREDIENTS DESCRIPTION: FOR MORPHOLINE LD50(RAT) = 1050, MG/KG (ORAL) LD50(RABBIT) = 500 MG/KG (SKIN) FOR AMMONIUM HYDROXIDE LDLO(HUMAN) = 1,000 MG/KG (INHALATION) LC50(MOUSE) = 4847 MG/KG (INHALAATION) ,ODOR THRESHOLD = 5 PPM FOR ISOPROPYL ALCOHOL LD50(RAT) = 5840 MG/KG HUMAN LETHAL DOSE = 250 ML. ---------------------------------------------------------------------------- SECTION III - PHYSICAL DATA. Bóiling Point: N/A F iVapor Density: N/A (Ai~ = 1) : Specific Gravity: .995 Evaporation Rate: N/A EPA Physical State Catagory: Vapor Pressure: N/A mmHg Solubility in Water: 100 Percent Volatile by Volume: Comparison Material: N/A Liquid Mixture 80% APPEARANCE, AND ODOR DESCRIPTION: ,APL LUSTR22,l IS A BROWN, TRANSPARENT LIQUID, WITH AN ALCOHOL ODOR. pH RANGE IS 8.0 TO 8.5. --------------------~----~---------------------~---------------------------- The heritage: Ii1EtNWU and MIr The future: ATOCHEM NORTH AMERICA ---~--.-._-.-" --- e e Page 2 .. .'.; - ~ SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: 85 F Lower Flammable Limit: N/A NiFPA Code: 230 EPA Hazard Codes: Fire; Method Used: CLOSED CUP Upper Flammable Limit: N/A EXTINGUISHING MEDIA: APPLY ALCOHOL-TYPE OR ALL-PURPOSE-TYPE FOAMS BY MANUFACTURER'S RECOMMENDED TECHNIQUES FOR LARGE FIRES. USE C02 OR DRY CHEMICAL MEDIA FOR SMALL FIRES. SPECIAL FIRE FIGHTING PROCEDURES: USE FULL FIRE FIGHTING CLOTHING AND SELF CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS: EXTREME HEAT MAY CAUSE CONTAINERS TO RUPTURE OR EXPLODE. VAPORS FORM FROM THIS PRODUCT AND MAY TRAVEL OR BE MOVED BY AIR CURRENTS AND BE IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPARKS, HEATERS I ELECTRICAL EQUIPMENT, STATIC DISCHARGES OR OTHER IGNITIN SOURCES AT LOCATIONS DISTANT FROM PRODUCT HANDLING POINT. VAPORS MAY SETTLE IN LOW OR CONFINED AREAS, OR TRAVEL A LONG DISTANCE TO AN IGNITION SOURCE AND FLASH BACK EXPLOSIVELY. THIS MATERIAL MAY PRODUCT A FLOATING FIRE HAZARD. ---------------------------------------------------------------------------- SECTION V - HEALTH HAZARD DATA Röute(s) of Entry Inhal~tion: Yes Pötential Carcinogen lists -- N.T.P.: No I.A.R.C. Monographs: No Skin: Yes Ingestion: Yes OSHA Regulated: No EFFECTS OF OVEREXPOSURE: INHALATION: LOW CONCENTRATIONS MAY CAUSE MILD IRRITATION. CONCENTRATIONS ABOVE TLV MAY RESULT IN HEADACHE AND DROWSINESS. EYE CONTACT: CAUSES SLIGHT TO MODERATE IRRITATION, WITH POSSIBLE CORNEAL DAMAGE. ' THERE IS NO EVIDENCE OF ADVERSE EFFECTS FROM REPEATED OVEREXPOSURE. EMERGENCY AND FIRST AID PROCEDURES: INGESTION:IF PATIENT IS CONSCIOUS, GIVE TWO GLASSES OF WATER AND INDUCE VOMITING. OBTAIN MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. OBTAIN MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER AND CONTINUE WASHING FOR SEVERAL MINUTES. OBTAIN MEDICAL ATENTION. SKIN; REMOVE CONTAMINATED CLOTHING AND WASH SKIN WITH SOAP AND WATER. WASH CLOTHING BEFORE REUSE. ,'NOTES TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE FOR ALCOHOL POISONING. TREATMENT MAY BE COMPLICATED BY BURNS CAUSED BY MORPHOLINE AND AMMONIA. ---------------------------------------------------------------------------- SECTION VI - REACTIVITY DATA STABILITY: e ~ ~.c .~ S'!t¡\BLE UNDER NORMAL CONDITIONS. INCOMPATAB.ILITY: HEAT OR STRONG ALKALIES WILL CAUSE AMMONIA AND ALCOHOL FUMES TO BE GIVEN OFF. e Page 3 HAZARDOUS DECOMPOSITION PRODUCTS: COMBUSTION WITH LIMITED OXYGEN MAY PRODUCE CO, C02, NITRUS OXIDES AND OTHER TOXIC FUMES. HAZARDOUS POLYMERIZATION: N/A ADDITIONAL DESCRIPTION: N/A --------------------------------------------------------------------------- SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE OF SPILL: EXTINGUISH AND DO NOT TURN ON ANY IGNITION SOURCE UNTIL AREA IS DETERMINTED TO BE FREE FROM EXPLOSION OR FIRE HAZARDS. COLLECT LARGE SPILLS FOR DISPOSAL. FLUSH SMALL SPILLS WITH WATER. HEAR SUITABLE PROTECTIVE EQUIPMENT, ESPECIALLY EYE PROTECTION. WASTE DISPOSAL METHOD~ CONSULT FEDERAL, STATE, OR LOCAL AUTHORITIES FOR PROPER DISPOSAL. ---------------------------------------------------------------------------- SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: SCBA FOR HIGH VAPOR CONCENTRATIONS Local Exhaust Ventilation: ADEQUATED TO MAINTAIN TLV LIMITS. Mechanical Ventilation: VENTED TO OUTSIDE. Special Ventilation: N/A Other Ventilation: N/A Protective Gloves: RUBBER Eye Protection: GOGGLES Other Protective Equipment: EYE WASH AND 'SAFETY SHOWER ADDITIONAL DESCRIPTION: CAUTION:Alcohol fumes are heavier than air and may collect in low areas. Use with explosion-proof equipment if th~s situation may occur. ---------------------------------------------------------------------------- SECTION IX - SPECIAL PRECAUTIONS HANDLING AND STORING PRECAUTION: WASH THOROUGHLY AFTER HANDLING. DO NOT GET IN EYESt ON SKIN OR CLOTHING. DO NOT BREATH DUST, VAPOR, MIST OR GAS. ,KEEP CONTAINER CLOSED. 'KEEP AWAY FROM HEAT I SPARKS AND OTHER FLAMES. EMPTY, CONTAINER MAY CONTAIN HAZARDOUS RESIDUES. KEEP AWAY FROM CHILDREN. USE WITH ADEQUATE VENTILATION. OTHER PRECAUTIONS: STORE IN A COOL PLACE. mK0 ATOCHEM ,NORTH AMERICA elf aquìtaine e e DECCD AGRICHEMICALS DIVISION 1713 S. California Avenue. Monrovia. California 91016-0120 Tel: (818) 358-1838. Tlx: 4720597. Fax: (818) 359-7248 .\ ,."1 .....__;:~ Page 4 SUDDEN RELEASE OF HOT ORGANIC CHEMICAL VAPORS OR MISTS FROM PROCESS EQUIPMENT HAY RESULT IN IGNITION WITHOUT THE PRESENCE OF OBVIOUS IGNITION SOURCES. ATOCHEM NORTH AMERICA, INC. MONROVIA, CA 91016 DEcca APL LUSTR 221 The heritage: IõIÐHwu and MIl' The future: ATOCHEM NORTH AMERICA ' "1' ;~ ATOCHEM NORTH AMERICA . elf aquitaine e e DEI:I:[J AGRICHEMICALS DIVISION 1713 S. California Avenue, Monrovia, California 91016-0120 Tel: (818) 358-1838, Tlx: 4720597, Fax: (818) 359-7248 MATERIAL SAFETY DATA SHEET Page 1 DATE: 01/01/91 -------------------~-------------------------------------------------------- MANUFACTURER'S INFORMATION ATOCHEM NORTH AMERICA, DECCO 1713 South California Ave. Monrovia CA 91016-0120 EMERGENCY CONTACT Robert J. Johnson 818-358-1838 -------------------------------------------------------------------------'--- SECTION I ~ IDENTITY Quick I.D.: DECCO APPLE LUSTR 225 Chemical Name: N/A' Trade Name Synonyms: HI-SHINE APPLE WAX, MORPHOLINE FREE. Chemical Family: N/A ,Formula: MIXTURE DOT Freight Classification: ---------------------------------------------------------------------------- SECTION II - HAZARDOUS INGREDIENTS INGREDIENT NAME % TLV UNITS CAS Number -------------------------------------------------------------------------- ISOPROPANOL AMMONIUM HYDROXIDE 8 400.0 2 25.0 PPM PPM 00067-63-0 07664-41-7 HAZARDOUS INGREDIENTS DESCRIPTION: FOR ISOPROPYL ALCOHOL LD50(RAT) = 5840 MG/KG HUMAN LETHAL DOSE = 250 ML. FOR AMMONIUM HYDROXIDE LDLO(HUMAN) ,= 1,000 MG/KG (INHALATION) LC50(MOUSE) = 4847 MG/KG (INHALAATION) ODOR THRESHOLD = 5 PPM -------~-------------------------------------------------------------------- SECTION III - PHYSICAL DATA Boiling Point: 209 F V~por Density: N/A (Air = 1) Specific Gravity: 1.00 Evaporation Rate: >1 EPA Physical State Catagory: Vapor Pr~ssure: N/A mmHg Solubility in Water: 100 Percent Volatile by Volume: Comparison Material: WATER Liquid Mixture 80% APPEARANCE AND ODOR DESCRIPTION: CLEAR, AMBER LIQUID WITH ISOPROPANOL ODOR. ---------------------------------------------------------------------------- SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flash Point: 87 F Lower Flammable Limit: NFPA Code: 130 N/A Method Used: CLOSED CUP Upper Flammable Limit: N/A' The heritage: Iõ1EtMw1 and MIl' The future: ATOCHEM NORTH AMERICA e e Page EPA Hazard Codes: Fire; r¡ EXTINGUISHING MEDIA: APPLY ALCOHOL-TYPE OR ALL-PURPOSE-TYPE FOAMS BY MANUFACTURER'S RECOMMENDED TECHNIQUES FOR LARGE FIRES. USE C02 OR DRY CHEMICAL MEDIA FOR SMALL FIRES. SPECIAL FIRE FIGHTING PROCEDURES: USE WATER SPRAY TO COOL FIRE-EXPOSED DRUMS AND TANKS. USE WATER SPRAY TO DISPERSE VAPORS; REIGNITION IS POSSIBLE. USE SCBA AND PROTECTIVE CLOTHING. UNUSUAL FIRE AND EXPLOSION HAZARDS: VAPORS FORM FROM THIS PRODUCT AND MAY TRAVEL OR BE MOVED BY AIR CURRENTS AND IGNITED BY PILOT LIGHTS, OTHER FLAMES, SPARKS, HEATERS, ELECTRICAL EQUIPMENT, STATIC DISCHARGES OR OTHER IGNITION SOURCES AT LOCATION DISTANT FROM PRODUCT HANDLING POINT. VAPORS MAY SETTLE IN LOW OR CONFINED AREAS, OR TRAVEL A LONG DISTANCE TO AN IGNITION SOURCE AND FLASH BACK EXPLOSIVELY. THIS MATERIAL MAY PRODUCE A FLOATING 'FIRE HAZARD. ---------------------------------------------------------------------------- SECTION V - HEALTH HAZARD DATA Route(s) of Entry Inhalation: No Potential Carcinogen lists -- N.T.P.: No I.A.R.C. Monographs: No Skin: No Ingestion: Yes OSHA Regulated: No EFFECTS OF OVEREXPOSURE: INHALATION: LOW CONCENTRATION MAY CAUSE MILD IRRITATION. CONCENTRATIONS ABOVE TLV MAY RESULT IN HEADACHE AND DROWSINESS. EYE CONTACT: CAUSES SLIGHT TO MODERATE IRRITATION, WITH POSSIBLE CORNEAL INJURY. THERE IS NO EVIDENCE OF ADVERSE EFFECTS FROM REPEATED OVEREXPOSURE. EMERGENCY AND FIRST AID PROCEDURES: INGESTION:IF PATIENT IS CONSCIOUS, GIVE TWO GLASSES OF WATER AND INDUCE VOMITING. OBTAIN MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. OBTAIN MEDICAL ATTENTION. EYES: IMMEDIATELY FLUSH EYES THOROUGHLY WITH WATER AND CONTINUE WASHING FOR SEVERAL MINUTES. OBTAIN MEDICAL ATTENTION. SKIN; REMOVE CONTAMINATED CLOTHING AND WASH SKIN WITH SOAP AND WATER. WASH CLOTHING BEFORE REUSE. NOTES TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE FOR ALCOHOL POISONING.TREATMENT MAY BE COMPLICATED BY BURNS CAUSED BY MORPHOLINE AND AMMONIA. ---------------------------------------------------------------------------- SECTION VI - REACTIVITY DATA STABILITY: PRODUCT IS STABLE AT NORMAL CONDITIONS. HEATING WILL RESULT IN ALCOHOL & AMMONIA FUMES. INCOMPATABILITY: , r ßif@ ATOCHEM NORTH AMERICA elf aquitaine - e DEI:I:D -< AGRICHEMICALS DIVISION 1713 S. California Avenue, Monrovia, California 91016-<1120 Tel: (818) 358-1838. Tlx: 4720597, Fax: (818) 359-7248 , Page 3 PRODUCT IS 'INCOMPATIBLE WITH STRONG ACIDS AND OXIDIZERS. HAZARDOUS DECOMPOSITION PRODUCTS: N/A HAZARDOUS POLYMERIZATION: ". N/A ADDITIONAL DESCRIPTION: N/A ------------------------------------------------------------------------~--- SECTION VII - SPILL 9R LEAK PROCEDURES STEPS TO BE TAKEN IN CASE OF SPILL: EXTINGUISH AND DO NOT TURN ON ANY IGNITION SOURCE UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLOSION OR FIRE HAZARDS. COLLECT LARGE SPILLS FOR DISPOSAL. FLUSH SMALL SPILLS WITH WATER~ WEAR SUITABLE PROTECTIVE EQUIPMENT, ESPECIALLY EYE PROTECTION. WASTE DISPOSAL METHOD: INCINERATE IN A FURNACE WERE PERMITTED. CONSULT LOCAL, STATE OR FEDERAL AUTHORITIES FOR PROPER PROCEDURES. ---------------------------------------------------------------~------------ SECTION VIII - SPECIAL PROTECTION INFORMATION Respiratory Protection: SCBA IN HIGH VAPOR CONCENTRATIONS Local Exhaust Ventilation: SUFFICIENT TO MAINTAIN TLV LIMITS. Meèhanical Ventilation: VENTED TO OUTSIDE. Special Ventilation: N/A Other Ventilation: N/A Protective Gloves: RUBBER OR PLASTIC Eye Protection: GOGGLES Other Protective Equipment: EYE WASH AND SAFETY SHOWER. ADDITIONAL DESCRIPTION: N/A -----------------------------------------------------------"----------------- SECTION IX - SPECIAL PRECAUTIONS HANDLING AND STORING PRECAUTION: WARNING! FLAMMABLE Do not get in eyes, on skin, on clothing. KEEP AWAY FROM HEAT, SPARKS AND FLAME. KEEP CONTAINER CLOSED USE WITH ADEQUAATE VENTILATION. WASH THROUGHLY AFTER HANDLING. KEEP AWAY FROM CHILDREN. Vapors may be irritating tõ skin, eyes, nose and throat. OTHER PRECAUTIONS: SUDDEN RELEASE OF HOT ORGANIC CHEMICAL'VAPORS OR MISTS FROM PROCESS EQUIPMENT MAY RESULT IN IGNITION WITHOUT THE PRESENCE OF OBVIOUS IGNITION SOURCES. The heritage: PENMAI1 and MJf The future: ATOCHEM NORTH AMERICA -# \¡ . MATERIAL .. SAFETY DATA-··SHEEJ U.S. DEPARTMENT OF LA Occupa~1 Safety and Healtt¡ I\dminiltration form APPfovecI 0". No. 4+81117 Ó r:¡ ,2 y- b 75 D e.. Q. <!...ò - ,~ Required under USDL Safety and Health Regulations for Ship Repeiring, Shipbuilding. inet Shipbreaking (29 CFR'1915. 1916, 1917) Se tember 1978 SECTION I MANUf''''CTUREA'S NAMa EMERQENC't TEL.EPHONE NO. (304) 843-1300 ... ' . - .... SECTIO'f11 .- HAZARDOUS INGREDÆNTS . ._, .- PAINTS, PRESERVATIVES, .IOLVENTI " TLV ALLOVS AND METALLtC COATINGS " (rLV 1u",1..1 UNo) PIGMENTS BASE METAL .. CATALYST ALLOYS VEHICLE METALLIC COATINGS SOLV.....TS FILLER METAL. PLUS COATING OR CORE FLUX ADDITIVES OTHERS OTHERS HAZARDOUI MIXTURES OF OTHER LIQUIDS, SOLIDS, OR QA8&8 " TLV IUnhsI Isopropyl m-ehloroearbanilate 36 None I sooroo.vl Alcohol and inerts 64 400 ODin 1 seC;TION III . PHVSICAL DATA 801L.ING POINT co...) Unknown SPEC:I..IC GRAVITY (~0-1) Un known VAPOR PRESSURE 1m... HI.) " PERCENT, VOL.ATILE N/A aY VOLUME I~) VAIIOR DENSITY IAt....) " EVAPORATION RATE N/A I -1) 5OLU.ILITY IN WAn. FormS" emulsion APPEARANCE AND ODOII L iaui d with al coho lie odor SECTK*IV ~ FIRE AND EXPLOSION HAZARD DATA ..~ POINT (........ .... 65 of t EXTINGUISHING MUt" a..1 \.leI self-contained breath in a aratus. UNUSUAL "'IIIE AHD axltl.OStON HAZARDS I form chloroaniline and isoc anates PAGE C1t (Continuld on .... IidIÞ Form 0SHA-20 III... ... 71 e e SECTION V . HEALTH HAZARD DATA -,,~ THRESHOLO LIMIT VALUa Is 8-hour t1me-we1 EFFECTS .. OVEAE)(POSUR ,'. EMIIRGENCV AND ,.IRST AID PROCEDURES ,- See attached sheet SECTION VI . PEACTIVITV DATA STABILITV - CQNDITIONS TO AVOtD Contamination with materials UNSTABU STABLE X listed bela.1. - INCOMPATA81LITV (Mill."'" 10 lllIØ4IIJ Strong acids or bases : HAZARDOUS DIICOMPOSITIDN PRODUCTS chloroan1line. isocyanates I I MAV OCCUR CONDITIONS TO AVOID I HAZARDOUS I I POL VME R IZATIDN ! WILL NOT OCCUR X '\ , ' , - - SECTION VII . ~ILL OR LEAK PROCEDURES . STEPS TO 11£ tAKEN IN CA$£ MATERIAL IS REL.EASED OR SPILLED venni culi te 'or Absorb sDi lled material on sand and Dlace in plast1c or metal container for disposal. Wash area with soap -and water. . " WASTE DISPOSAL. METHOD EPA-a d incineratfon or an EPA-aDDroved chemf cal 1 andf111 . SECTION VIII· SPECIAL PROTECTION INFORMATION A~rw~ ..ROTECTION I!~t¡¡ f-fVá i , SA-approve re p tor for organ1 c vapors . LoçAL ~HAUST S~CIAL VENTILATION ' I M!!CHANICAL (Cìønwl) X 01;H£" , I PAOTIICTIV. QLOVU I EYE PROTECTION . Rubber gloves Chemical goggl es OTHER PROTIICTIVE IIQUIN&HT SECTION IX . SPECIAL PRECAUTIONS flR.CAUTIONS TO 811 TAKaN IN HANDLING AND STORING See attached sheet OTH"" '''.CAUTIONS See attached sheet .' :PAO£ (2. ¡¡"O 'ID.NO Form OSHA·. ..... ...~ 71 e '"', '. ~4J ." ADDENDUM TO MATERIAL SAFETY DATA SHEET ON SPROUT NI~ EC ,,".. (SEPTEft8ER. 1978) ........ " ..' ..r SECTION V - HEALTH HAZARD DATA Acute Toxicit.t: Except for vapor inhalation, no specific studies of this fonnulation have been made. Based on the toxicity of the com- ponents of ,the mixture. the following toxicity estimates can be made. Oral L~O(2):,;" . 4000 mg/kg Dermal LDso(2): 10,QOO mg/kg Vapor Inhalat10n(4) (rats): 28.7 mg/l/one hour produced no effects Eye Irritation(2h" Moderately to severely 1 rri tati ng Skin Irritat10n(2): Mildly irritating Chronic Toxicity(2): None known. Emergency and Fi rst Aid Procedures Eye Contact: Flush with plenty of water for at least 15 minutes. Call a physician. ' Skin 'Contact: Wash with plenty of soap and water. If irritation pccurs. consult a physician. Swallowing: I~ CDn6Wu.ð, drink a quart of water. Then induce vomiting by placing a finger far back in the 'throat. Call a physician. If vomiting cannot be induced, take imnediately to a hospital or physician. I~ uncon6c..i.ou.ð or in convulsions. take inmediately to a hospital or physician. [k) not attempt to induce vomiting or give anything by mouth. ' . '.: :~ . . , - -2- SPrtJUT NIp· E" ~ SECTION IX - SPECIAL PRECAUTIONS Precautions to be Taken in Handling and Storing · Avoid storage below freezing te~eratures. Prolonged storage may result in crystal formation. Warming contents and agitation will restore material to usable condition. but do not heat above 2500F. · Do not store in open. unlabeled or mislabeled containers. · Avoid exposure to air to prevent undue moisture pickup. · Wear rubber gloÝes and goggles when handling. - · Do not reuse container. [k) not bum. Destroy by burying in a safe place. · Avoid contamination of fertilizers. seeds. plants and pesticides. This product inhibits germination. Other Precautions · Keep away from heat, sparks and flames. · Avoid contact with skin and eyes. · Avoid breathing vapor or spray mist. · Do not take internally. · Use only with adequate ventilation. · Keep out of reach of children. REÆRENCES 1. Material Safety Data Sheet: Isopropyl m-chlorocarbanl1ate PPG Industries. Inc.. March. 1978 2. EPA Registration No. 748-182 3. Registry of Toxic Effects of Chemical Substances. NIOSH. 1975 4. Report to PPG Industries by Industrial 8iotest Laboratories. 1971 ^./ e - ~tU7s--Pl--=-- Bakersfield Fire Dept. Hazardous Materials Inspection '/ / 10- I Y ~ 9'0 Business Name: I~ Date Completed ¡Q' . , tV,'JOV\ (Top right comer Business Plan) Shift c.. Inspector~;(¡ /!;.fb .fe~ Adequate Inadequate r1 V) Wtl \+ W;k/e t () .(' .¡J . , r<.oI Location: Lf.{ S () Plan ID # 215-000 Station No. 7 Verification of Inventory Materials Verification of Quantities Verification of Location Proper Segregation of Material Comments: ()'l-Áe1('" ~+e.(",'cxJ.j /J¡7-r Dv1 ~ j,e,.e+- , ~76(ltllJ ~~ ~"-~+e,. <Ôð~.;led Verification ofMSDS Availability Number of Employees ~ Verification of Haz Mat Training Comments: o ¡q o ~ [12( 0 [Ø" D I¡¡, £ode! ClJ In ~;II\£ :ru i. EJ' 0 ' [Ø' D Verification of Abatement Supplies & Procedures Comments: ~ D Emergency Procedures Posted Containers Properly Labeled Comments: ~ [Ø" D D Verification of Facility Diagram Special Hazards Associated with this Facility: ~ D Violations: FD 1652 (Rev, 3-89) White-Haz Mat Div. Yellow-Station Copy Pink-Business Office ".. :Ji' 'á"'~:';/~ . / '/~AK;;"', . /"0" ;;"~I?.5'¿,, , "..)" #1>" f'\\ ¡ ,'-. -, t'" \ .0 ~ -~.A,~ 0;) \'\":'0:~)~ ,// ":'1I../~-·i..\\.~/ . '-~!t....o...ß~~,/ "~ e e CITY of B",AKERSFIELD@ "WE CARE" ~ \\\\úmmT/ì... ~\ ,,~~,:;:':!!"" '" I ,.."Û -'-~ ¿//':,~' /~'>\: =~;; \', <"j ~,-=== ~\;; <:; ::}~ ~.... ...." ,~ ~~",::.,::~\\".,¡I_~ áJjhíÍ~ KD b ~ vi- '""J:sD h Ii\. oS ð to (tYDe or print name I RECEIVED MAY 2 3 1989 HAZ. MAT. DIV. Do hereby certify that I have revie~ed the attached Hazardous Materials business plan for ~~~~~~~:::~ f') · and that it along with the attached additions or corrections constitute a complete and correct 5 -Ie ~1 date ,"- .' ~ .., e PENNWAL T CORP DECCa DIVIstN Site as a Whole Page 001 .05/10/89 , , Gen~ral Information I Location: 4330 Wible Rd I Ident Number: 215-000-000387 r I I YJiap: 123 Gt~ i d : 13C Hazat~d: High At~ea of Vul: I i I 3 W'"I_I ;'\A~miY'listt~ative Data Mail Addt~s: 43 0 ..&:1....e ~d City: Bet4'tafs1,'t let Gec,Subd i v: D D&B Num9.e~: oO-").2tt ..0,-,3 State: (;..L.IZ i p: 1'1'.:3 SIC Cc.de: ~g7 f , Phc'Y',e; 81 t;-, B ~r -/fr3g' State: CA Zip: 9/011 Titlè I ~iness PhclY'le 24 H..9J-lr Pho1'",e ' (ðoS) 3'37-1087 ("OS) 831-7517 R()(ILl Q t-I D~ ~ l¡) ~ I ( ~I '() $~~ ~J_~J( ('If[{) Sf7~a'-'f'2...1 I I I OW1'"let~: ~tJu,)oLt <!c')",~, 'D~CQù C, Ù Addt~s: 'Pb 60"" 11Ð City: M C)tJ ~ð"lt).. ~Itact I GERALD' PATTERSON I ROÞ~£I-t:r:rð ~lø4st>"'> I Summary: 2A SEC 4) A HAZARDOUS MATERIAL TRAINING AND RESPONSE PROGRAM HAS BEEN CREATED FOR THE DECCO DIVISION OF PENNWALT. THE EMPLOYEES IN BAKERSFIELD ARE TRAINED IN THE ,¡PROPER HANDLING AND CLEANUP OF OUR HAZARDOUS MATERIALS STORED AT OUR WAREHOUSE 2A SEC 2) ·' 4IÞ PENNWALT CORP DECCO DIVIS~N <D> Notif./Evacuation/Medical for: Overall Site Page 002 ,05/10/89 . . .---- <1> Agency Notification ~ ËI'Vlð'l0'ôf'r' ~ OV-e. /J)S f..lAc t-eø 1¡¡.. /Ùð-tt6 ~ +l-e... 'ßø K~.... b ~td 6' ye. Pe.(J i . / "f- ~ e WI a. "ù ð It / C. e... I µ M 0 ~v 00 \ ct- I I þ) t: k ~ .(> V ~ "^ -to /; ~ L-eø.. t< ~ c;, ð" LL <2> Employee Notif./Evacuation 3A SEC 2) EMPLOYEES ARE INSTRUCTED TO NOTIFY THE FIRE DEPARTMENT AND THE MAIN OFFICE OF DECCO (MONROVIA CA) IN THE EVENT OF A SPILL OR LEAK. EVACUATION IS THROUGH THE LARGE OVERHEAD DOORS WHICH ARE OPEN WHENEVER EMPLOYEES ARE IN THE WAREHOUSE. THE WAREHOUSE DOES NOT HAVE AN EMPLOYEE ASSIGNED TO STAY DURING BUSINESS HOUSE. EMPLOYEES ARE IN THE WAREHOUSE LESS THAN 3 HOURS IN A NORMAL WORK DAY. <3> Public Notif./Evacuation í05/1~)/8'3 e PENNWAL T CORP DECCO D I V I.N (D) Notif./Evacuation/Medical for: Overall Site Page 003 Med. PlaY'1 2A SEC 5) BAKERSFIELD EMPLYEES ARE ON A SERVICE ROUTE, WORKING OUT OF THEIR VEHICLES. TRUCKS ARE EQUIPPED WITH 2-WAY RADIOS SO REGARDLESS OF LOCATION, HELP CAN BE IMMEDIATELY SUMMONED. ALL TRUCKS AND 2-WAY BASE OPERATORS HAVE EMERGENCY MEDICAL NUMBERS FOR THE VARIOUS AREAS COVERED BY THE SERVICE ROUTE · e PENNWALT CORP DECCO DIVHIN <E> Mitigation/Prevent/Abatemt for: Overall Site Page 004 -05/10/8'3 , . <1> Release Prevention 3A SEC 1) PAINT AND FLAMMABLE PRODUCTS ARE STORED SEPARATELY. CYLINDERS OF CHLORINE GAS ARE STORED UPRIGHT, CHAINED AND SEPARATED BY FULL OR EMPTY. STORAGE IS NEAR A LARGE DOOR TO ALLOW AIR CIRCULATION. THE CHLORINE SUPPLIER KEEPS AN EMERGENCY KIT A FOR CAPPING CYLINDERS THAT MAY DISCHARGE GAS. RESIRATORS ARE ON SIDE FOR USE IN CASE OF A GAS DISCHARGE. TRAINING IS PERFORMED YEARLY FOR SAFETY AND HANDLING. <2> Release Containment A II\. e VI\.-t"'ò.ell\ e it k \ 4:- r ~¡?''';Î I ~ 1Ik.Q.C/.) t- o..-L i) e d D 0 V L1?'<t t( ,tJd \J Q.. Lv-e~. (! Ô ~InJJ-er ~ Ð <I" Jp .,,, k. etJ <3> Clear. Up Q.o..lff4.el- ~Òl/.,.>d~,c¡, 1,.IJlL'~-e a>,cu.ed L.<.r :, ô I¡I.,-ØAlLc.vl DI. f- (þ. '" e 11.... ) Ú L L H.. V -e.. C ð l ?O~- ;'~Î"-7~~S) .., '" e . PENNWALT CORP DECCO DIVI~N <E> Mitigation/Prevent/Rbatemt for: Overall Site Page 005 " ;05/1Ç1/89 Resclu1'~ces I) tLLor I tJe.. - G lL R...e. C!.Ð (:2aS-::l'f7-7, h~:> .;2) D..LL Ð ~\.~II" tl~.vk I c!" ls - 11. e: fJo H,¡.) ð' '6. 1M... 1 So <.\(1. L ('bI'iS-2.tb--;/D'0 :" 'I'~ ~ .~ 05/19/ Br::3 4t PENNWALT CORP DECCO DIVI~N Page 007 Over~ll Site HAZMAT INVENTORY - LIST 01-001 Chlorine Gas > 1,500 Extr~eme FT3 ~, I: ¡~ 3- ,. o.:=;/ í.o / 89 e PEI\II\IWALT CORP DECCO DIVIlrN Page 008 . Ove~~ll Site HAZMAT INVENTORY - DETAILS . .1:;. 01-001 Chlorine Gas > 1 , 500 Extt~erne FT3 Form: Unknown Type: Pure Days in use: Use: - Dai ly Max Arnt T Dai ly Avet~age Amt 1 , 500 A1"l1"lual Arnc,u1"lt 1 :30 -----yU1"1 i t - IFT3 --- Container ¡rressTTemp PORT. PRESS. CYLINDER I I r- INW CORNER Lc.cat i C'1"I - Conc" 1 Components 100"0~ Chlorine (EPA) MCP îist- I _ I Extt~eme EPA , ~ I ~ " - ..,,,,'."<" ','t:" , I'" ','.... '. . ~ ;~;' 'J'- ; .. ~ ,. ,.,:. .. h,. . i~ , "Y ~/", ð> ~>, ,jt '" ~.:t.::'c'FJ''' . , .# {{.~ ~#,<P ~ . I ~J! CIT}T of BAKERSFIELD ,. 'I ... ,. I' .. ,~ FarM and Agricu 1 turf ';K.. .--, Standard Bus in!ss '--' MATERIALS INVENTORY SECRETS BUSINESS NAME, 9?1Ù~ o.JtL L ~ LOCATION, !~-,' ~:¡~¡to CITY. ZIP: If'!o 9~~/~ PHONE ,: t - 9 - (t p,.. .+. ;' :,~ L NAME OF Tft1S ~~JL~TY: ~~~ STANDARD IND. CLASS CODE 7 DUN AND BRA~TR:ET ~~:R 07 73 _ 1) 2-_:J _ __ e:- OWNER NAME: ADDRESS: CITY, ZIP: PHONE II: RDlfR TO I 2 'rans Type Cod! Cod! 3 ""~ Mt 5 Annu.1 Est . Avlr.g. Mt 6 IIItesure Units 7 'Oys an Sit. r--., L _.J Fir. Hazard ,.-.,,.v ,.10 L _.J DlI.yed L l' Sudden RII.II. L -' IMtdi.t. H,a Ith of P....sur. 11M Ith CODllS , 10 Cont Cant Pmt U 11_ of IIhlturt/Colløonentt Set Inttruc:ti_ 11 Us. Cod. 12 Loc.tian 11'-1" StOl'tcl In f.ei lity 1] 'by lit ------...-- --- ..-------- ... . C.A.S, .... ~ {!i~/.t;-'t.u~J!2:__77~2-_?ëJ_-~_ _____ to.OIIIIIt 12 ..... C.A.S, bbtr ea.pon.nt IJ ... ¡ U.S. ...,. Phys ic.1 end H..I th H'lIl'd (Check .11 thet .pply) ---- ---- .----- - ----- C.A.S. bbtr ________ eo.panent II ._ ¡ C.A.5. ...,. ,..-, r-, ~-., ,.-., r-' L_-' Fir. HII.rd L_-' Re.ctlvlty L_-' Otl..,.d L_-' Sudden R.I".. L_-' IMtdtlt. , Htt Ith of PI'ftSUrt ""Ith - ---- ----------- ----- CaIIcIonInt 12 ._. C.A.5. bber to.øonent I] ... ¡ U.S. bbtr Physic.1 IIId H"lth H.l'I'd ICheck .11 thet .pply) --- -..--- -------- ----- U.S. IIu8btr ________ eo.panent 11 .... ¡ U.S. IIuMItr Co.ponent 11 ..... C.A.S. .uMer r-, r-" r-., r-" r-~ L _.J Flrl Hllard L_.J Rllctiv,fty L_.J Del.yed L_.J Suddtn II,IIISI L_.J l.edl.t. Hla Ith of Pressure H"lth ----------- ------ ------------------- ---- COII~t 13 11_' C.A.S. IIuaber Physic.1 end H"lth H.urd (Check all that 'l/IIly) ---l-_L__________L____________l__________l___.l___l__L_-L__l___-L___ ..-- C.A.S. lIullbtr _______________________ COIIIOIItI'It 11 II.., C.A.S. IIUIIbtr ,.-, r-' r-, ,..-, ,..-.., L_.J Fir! Hazard L_.... Rllctivity L_.J Delayed L_.J Suddtn R!leas! L_.J (.edlate , Hlllth of Pressurl Hlllth --------------- ------ COIIIØItI'It 12 11_' C.A.S. lIù.ber . ---- --------..------...----------------------------- ------.. CoalOlltl'lt 13 ._. C.A.S. lIu.bel' -- _ERGENCY CONTACTS II 12 liãiii-~----------------------------------- nn¡----------------------- 7r-R;:-POOñi-------- lliii----------------------------- T1t1ë------------------- n,.I'-PIlðll~----- \ I , Certification (Read and sign after co.p1ering all sections) I C~rt1f dlr IIII.lty of 1.. that I havl PlrsOII.lly IXI.intd .nd .. f..ili.r .ith the Inforllðtian sublli for ta' ~ht int~.L~~v, that t;:JUblliJ;Mj in~ti()(l is tru;jcur.tl. .nd pllt. Ii- --- D. ----1'-..1-- -:1~To~---~-$DJ!Þ-----7-J-J:;~t¿--u~--tt l1____._..__ S· ~.e a Or ICla t" I 0 o""lr operator owner ¡roeralor 5 aUlllllr1Z~ rgrlsen'al1V! I t . .nd that based on Iff inquiry of thos. Indiviclu.ls rlSIO/1sibl. S---¡&' ~ n¡1¡-siqñëa-------~-.f'---------------- i e e BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 (805) 326-3979 1d3-\3t S- @.-l1J5P~f -' OFFICIAL USE ONLY ID# ()lD\~ BUS INESS NA.\1:E HAZARDOUS MATERIALS BUSINESS PLAN AS A WHOLE -FORM 2A 000$87 -, INSTRUCTIONS: . . , . . 1. To avoid further action, return this form by . 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: re\"\"WA-LT G,,,,? Ye'-l.-O 'J);Vì5t'O"'- B. LOCATION / STREET ADDRESS: 4330 LJ;t,{-c.. 'R& ZIP: 133 /3' BUS. PHONE: (gOS') CITY: ß~l<er5'e ltÁ 317-IOCJì SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NA;'1E AND TITLE A. Q-e-ra..lJ ?o.-",e~l)V\ - :;'rv/c.t.. 1<e p. , B. 1?OjeY" 1<y»O Se-v-\J"\'(t!, ~Y". DU~NG BUS. HRS. Ph#(~05 3'l7-/og7 Ph# (tO$) Lfß7-0~q, L( (AFTER BrS. HRS. Ph# ~ö5') 9J(- 7(P17 Ph#.( ~O.r) I,sS -:2120 ~- SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. B. ELECTRICAL: C. WATER: D. SPECIAL: E. LOCK BOX: YES /~ IF YES, LOCATION: IF YES, DOES IT CONTAIN SITE PLANS? YES / NO FLOOR PLANS? YES / NO MSDSS? YES / NO KEYS? YES / ~O - 2A - ~~ e e "., 'qj . . - ~:.~~~ \'" , ... '. SECTION 4: PRIVATE RESPONSE TEAM FOR BUSINESS AS A WHOLE Pi ~~r-'~ 'Ï'V\4.~rl'A.( tr-/Å.("-'J ct~~. resp6YIse. P'rð<1r"A.#L, Ad S k"L ~ reJd ..(.cy- -tk. D~CC.D ])¡"is,'D'\1 (¡.f. 'P~VlJ\~ð-lt. ,he.. €.~pl~rees p\ "&.~,...s -h'e!" 0..'(0{, -fv.A.ì~et ;~ -+~~ r 'Xr ~ø..\-\.J.l;~ tu\d. df~"-f of Okr- h1"rd0'((5 /ltttiftv,'ðJ5 ~d, d-- Ouv- Wú-r~,^-O\~~" SECTION 5: LOCAL EMERGENCY MEDICAL ASSISTANCE FOR YOL~ BUSINESS AS A WHOLE '&.Kel'"sJ~ßG 8tØfJoye~.~ Me. ~ , 6e.r'V'1 'C~ rõ,ðe I VJCY~\t:ô,.",:l I'{ "~t.~Y" \f¿kìdes." Trkc1Ls a.v~ €~, 'ff~J ljl'~ ,;2- ~ï r4.eUt?7 50 Y"~o-vdre~~ ~.f (ðC~'h\, hel f c~ he ; p\1\nH,J ,'J7 Su-ßl~f)l\eJ. ~,*lAqL& ~ .J~ ~ b45e t)re.M.~r5 h~~ t:Me.....je.tc7 rn<'cJ t\,&l.J\.\~s .,ç,.". "-!-4e. VtU'tðk$ ,a,;.-.e.~ S cO ~~J b, ~ e s€rvÙ.-e Y'O Joe SECTION 6: EMPLOYEE TRAINING '\ ' '. '.- EMPLOYERS ARE REQUIRED TO HAVE A PROGRAM WHICH PROVIDES EMPLOYEES WITH INITIAL AND REFRESHER TRAINING IN THE FOLLOWING AREAS. 'CIRCLE YES OR NO " A. METHODS FOR SAFE HANDLING OF HAZARDOUS MATERIALS:....................................... @) NO B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPONSE AGENCIES:.......................... ~ ~O C. PROPER USE OF SAFETY EQUIPMENT:.........~........ ~ NO D. EMERGENCY EVACUATION PROCEDURES:............,.... ~ ~O E. DO Y_O(J .MAINTAIN EMPLOYEE TRAINING RECORDS:::. :.:.:_. ,<1§> .NO, INITIAL.' R,EFRESHER á?s> NO ~ NO ¡NO S NO YE NO SECTION 7: HAZARDOUS MATERIAL CIRCLE YES OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 500 POUNDS OF A SOLID, 55 GALLONS OF A LIQUID. OR 200 CUBIC FEET OF A COMPRESSED GAS:... ... YES ~ r. 1?"g'-v- 1(1",0 . '. certify that the ab~ve i~formau'on is accurate. I unders and that this Information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 E~ AI.) and that inaccurate information constitutes perjury. .... . '--"'---~/' /,,~-'''l ./ /" ",/, '~ /L, SIGNATURE c~ ~ U tJ ~.. ~ . TITLE'JMf ~rviu ~DATE ~-3o-n - 2B - I " . e e 5';' -.'\;-r' i, :.' ,,~. BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 OFFICIAL USE ONLY BUSINESS NAME: 1'-e.Y\.V\.wa.....tt LßV- \,,:þe.CCO þ;v. ID# - - -' - - - BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid further action, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the questions below for THE FACILITY UNIT LISTED BELOW 4. Be as BRIEF and CONCISE as possible. FACILITY UNIT# N/ff FACILITY UNIT N~: J)-eCCO WO-V"~Óll-S~ SECTION 1: MITIGATION. PREVENTION, ABATEMENT PROCEDù~ES fð..\VI.J Ov~ -f1(l~~~Ie...· procb..vis (ÁY~ s~...e.cl Se..F-vJt¡. c...y liv..J'€V's d f.. cl.!O"'"'' ~"5 <tiE- ,s'¡"reJ ."f';#' e-ko.'''..,I. a-J $e~dl ~ I/J{ ð" ~. ~j,,~ IS he,,: "- ("'"j~ door {..o ("' .:j- a.11>«r ,,-i~ d",~JiCM' -ri1.e c.klð....,~e Sl.o<-ff (-€.¥- ~f, ~ -f/wt..e-r(J~cr K.t'7- A .fo,r ~ ¡' 'j 1:.) It' ,J<'k~ . ~ ~ ,,1.-15 cLt" rj e J" 5 · /Ze5 f .. V' "- {" r '" "'- "... &Y\ ~ (+~ -þr tø..- I k. CAà ~ ~ ~ Jet. "5 J./S k V'cr- . '('ra.£' t-L ¡ ~ :.s- f ~y-\,-,~~ Ý~7 -f;r- 5cvfe~ tÞu) h~j/~.. SECTION 2: NOTIFICATION AND EVACUATION PROCEDL~ES AT THIS ù~IT ONLY f ~ploy.ee7 a-r-e /I.t d'-k.&d iÐ ho {-¡l.ç) +k {F,-e. Þe.ro.v~d- ~ 'tL- VWJ.i " ð If' G ~ ? :þa:o C /11<1"1"0<1 ¡ I.L (II· ) ; ~ -+4 -ue..:f ðÓ "'- spill or (4¥-. EV'<kCu,j'IM-;'Ó -fhrouik ...¡t. e la-vJ e . ov-4'h... J &-OV'7 ()ltc1. OJI'€- 0p~ vJkeAtl~ ..e..A/~i;!(j,/-ees a.V'~ )1-,. ~ (,JM J-)<' . 1i e. t;Jo..r~ J,e 5 fl' + h<L<A- ,^,,,- ..e..../o¡., "- ð ççtj · e4 f> ~),...: J iw','hNS hOlW'ç. E""-Ifoyee s <I1ve 1"-- 'f-Í..e- 0JeK~ le~S ~ '3 koc..Y5 ;h. 0-- f/ov-~ w-<>--k~. _. 3A - · e ," _ ".,:" ~'(_' 't 2- ,~.. A·-I ....,;. SECTION 3: HAZARDOUS l'.fATERIALS FOR THIS UNIT ONLY A. Does this Facil i ty Uni t contai n Hazelrcl011S Mater Í;) 1 s? . , . , " ®t NO If YES. see B. If NO, continue with SECTtON 4, B. Are any of the ,hazardous materials a bona fide Trade Secret YES <ThY If No, complete a separate hazardous materials inventory form marked: NON-TRADE SECRETS ONLY (white form #4A-l) If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS,ONLV (yel~ow form #4A-2) in addition to the non-trade secret form. List only the trade secrets on form 4A-2. SECTION 4: PRIVATE FIRE PROTECTION hf'f Q..)<+"~UI~5 h €-vs ~ .{; .,.. e. a... We Wt. .ej ~~~~ çp-r~ut(~ Sy 5+~ ~ SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY E~ERGENCY RESPON~ERS 5 ~. C DY'vt ~v- o{ bwltÁi ~ (T.o..yl Oy We--U 1ë c ~ -(D. c: I /-I¡ ). SECTION 6: LOCATION OF UTILITY SHUT-OFFS AT THIS UNIT ONLY, .ð.. NAT. C;AS/PROPAiÜ:': We~r 5Ù,{-e, of j,w~(J.;~ /JK ,. .xvt ? hie WC4¥~ ~ +4- ~('k B. ELECTRICAL: Db >-rk- No r+t.. w-JJ ~ ~ o-F{,' ( €. -- --;-- ---- -----..-..-,-. C. WATER: S~ t..u . Co V" \1\ -e........... a¡ bUl'loLtf~ D. SPECIAL: E, LOCK BOX: YES / €V IF YES, LOCATION: IF YES, SITE PLANS? YES! NO FLOOR PLA~S? YES / NO MSDSs? KEYS? YES YES (\0 :\'0 ,- 3B - BAKERSFIELD CITY FIRE DEPARTMENT FORM 4A-l NON-TRADE SECRETS HAZARDOUS MATERIALS INVENTORY ~rp J)ee-co S);" OWNER NAME' J. ~{4..0 ~r JUar þe(cc J),'V Page Í- o/~ . < , I FACILITY UNIT #. --- I. D. # BUSINE~S NAME' -..12e.~"Wð..\.\- J' . ADDRESS: L.{330 Wible. R4 ADDRESS: lit3 oS. CÄ. (i.ç"". t\" ð.. 4", FACILITY UNIT NAME: BKrL-1) WIlSE CITY, ZIP: ~~sNe{~ Q3'3(3 CITY,ZIP: ""J-Y\o \. Y'ø V , . ~ CA- e¡ 11)1" PHONE #: ~o~, 7-10 7 PHONE # : (!I~) 3S~ -tß?>c& IOFFICIAL USE CFIRS CODE ONLY 1 2 3 4 5 6 7 8 9 10 TYPE MAX ANNUAL CONT USE LOCATION IN THIS % BY HAZARD D.O.T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE M 30 50 ~. 13 ;2..4 5ou..fk w4..lf VA iNTS FLL(j) P ;"'500 J'30' \J ':-Ç O~ l. D ;;y'ß' ~ 30 N or+hwe S + Cb h\ -e Y" ¡vo71) c..h If>t'' I'''' e" ~ OX ID - l^A 99- Q tGOlð I v d-.,O lðO 9LJ 13 No~ wøJ,l 8] r/J,'ce ,."X \,J~ [lPG Pr.T. FLLØ u '" I' I I I I I ~ p~-\t S p rc¡.j :,,-~;b ,. -fÐ .... i! . /'Î ~) I NAME: Roe¡ev- K '0'\ 0 TITLE: NA..+¡~""{ SIWV.'CC. ~NATURE (~ -~c:::k' ./1~ DATE: EMERGENC~ CONTACT: ~Id Vd1t~'ioI- TITLE: . Se.¥'vlc.-e. ~ C/, PHOm: # BUS HOURS: (~"5') 3"f7-1o~7 ~~ 1{y"-O AFTER BUS HRS: g;I -76/7 EMERGENCY CONTACT: TIT L E : ~ s~' "'1 ~ PHONE t 8U S HOURS: ($ír) '4H-.' gf{ , PRINCIPAL BUSINESS A C I V I TY :6~rvl'CI\ 0- Fr-e~k FrlAi+ ,r e. e. f&.M 1å.&K1'j h"t.rs'$ AFTER BUS, HRS: ~5"ß -2.IZ-o - 4A-l - ~ '.;: __ a. ~ ".,;--:-'~- ." .. . ~ filE~W\LT CORPORATION - CECCO TILTEJELT DIVISION 1713 S, California Avenue, Monrovia, California 91016-0120 (818) 358-1838 · TLX 4720597 CHEMICALS. EQUIPMENT. HEALTH PRODUCTS ... r eEl V F. 0 .; ;,'! "; ¡f'; 1987 ,u~. [.!J £¡liô' iI.... ........ Mr. Ralph E. Huey Bakersfield City Fire Dept. Hazardous Material Div. 2130 "G" Street Bakersfield, Calif. 93301 RE: ID# 07018 Dear Mr. Huey: Enclosed are the or incomplete forms you requested for the Haza Material Business Plan. I trust this complete the package of information. RR:cmc enclosers Thank You, /~~~ National Services Mgr. J~ .~' " ."y _ .....15. ',,;:, .,...... -r . (>¡-~ , , e· aL).J36 ~ SITE/FACILITY iflfAGRAM:!-J, 9-7' FORM 5 ~r 30 IN5P 7 NORTH SCALE: /'1_1 " BUS INESS NAME: t D€(:(ð Þ:V FLOOR: ( OF , ~ - () ~t\MvJ; c'rp , DATE: CR/J-'i/~1 FACILITY NA.'tE: ~ k. UNIT ~: , OF 1 e..u.o Wø.t"i.- 011 ~ (CHECK ONE) SITE DIAGRA)I FACILITY DIAGRA't ".- "Cl ~þ..'" ~ ~\~()..~ 1) ("A.i \\j. ~ ~ ~ \ yo!. ~{. "c..l~ \lo.L'o.,..,$ fØ-~e. " , Hiw4.Y 1 q (Inspecto~ls Comments): ~---k-X-)C )l X-\ ^ ~ x. ~ x.. ~ (!) \1 <.'" ~t ...J DÐO'" me -hJ 'ßttì(A ¡~j 1. :¡f4M5 ~ , TAYLOR WELL TECH PENNWALT D ECCO . 4_i_~30 WIBLE RD f I e Alto". I r t?~s.. ~- r-~ r - I ~ E o.ç.ç¡,~ ;,,1 I è , ÐV~I'"'~eJ dooV'J ~~ ~ F;,., ftyJ.,...¡J- ~ Fire.. /t-l-f~Jt4iiJ ~{'7 fj,.¡\J(.WA.Y - fø.V~J -OFFICIAL USE ONLY- ,- 5A - SITE DIAGRAM (ReqUirlte..) ~. Address: IdentifY e principle bulldln¡s by the Street nuabers. 9. Lock (key.x 10. MSDS Storl!¡e Box 11. Railroad Tracks 12. Fence or Barrier a. Wire b. Masonry c. Wood d. Gatel 13. Powerl1nea 14. Guard Station 2. Street(s), Alleys, Driveways, and Parkln¡ Areas adjacent to the property. Include the street naaes. 3. Stora Drains, Culvert., Yard Dralne 4. Draina¡e Canals. Ditches. Creeks. 5. Bulldin!ts a. Fraae construction b. Masonry construction 15. Stora!te Tanks: Identify the capazity In !tal. ~e. Above ¡round c. Metal conltruction d. Acce.. ,Door b. Under¡round ® Utility Controls a. Ga. 18. Dikln¡ or Ber. b. ElectZ'icity 17. Evacuation Route c. !fateI' 18. Evacuation AZ'ea: Identity tha location where eaployee. will ..et. ~ Fire Suppression Systeas: a. Pire HydZ'aDta b. ,Fire Sprinkler Connection. Ie. Outside HazardQu. "e.t. Storero c. PireStandpipe Connections 20. Outside Hazardous Material Storase d. WateZ' Control Valves for protection syste.. 21. Outside Hazardous Material Ule/Handlin¡ e. FIre PWlp 22. Type ot Hazardous MaUZ'ial/Walte Stored 01' U.ed (See Below) 8. Fire DepaZ't.ant Access TYPE OF KAZAIU}OUS MA fER I At. P " Pluanble I . £XplosJve L . Llq\lid R " Red:tolo(ical -~~- C . Corro.ive 0 OJddh:eZ' 0 0.. P pobon W . Water Reactive T . Toxic S - Solid ' R - Cryo¥enic D . Wute B . Etiolo(leal Exa.ple: Pla..able Liquid· PL PACILITY DIAGRAH (Required it..s in addition to the above) 1. Rl...r. tor SpZ'inJclere IS. Fire S4capee 2. parti tions ~ Air Condi tionip( Uni ta 3. Stairways: Indicate tbe 10. Window. level. served rro. hi~he.t to lowe.t. U. Inside HazaZ'doua Waste Storace 4. Escalator: Indicate the levels .erved fro. U. In.ide Hazardoua hi¡h..t to lo.elt. NatlZ'1all Stora~e 5. Elevator 13. Inside Hazardoua Material. Use/H.ndlin~ 8. At tic Access ~ Sewer Drain Inlets r. sky lichts -, '".,' .;..- ";;,~''''':~'f'' . #,",. .. :=-.''C" .j.~, .. z.;·t, . ~ ,,"1 ..' .. if ", .~ . to i:'~::.f.' II.. /.J ~/" ...t;:~ ~ "01' ,. ~, -, ~ e~ITE/FACILITY FORM 5 . 'f 3 5 c> ~1L' l/ - /Ì; D~AGRAM j::t:- :3 ~ r ¡T1J5'fJ I L- .0 r 1 ~ NORTH SCALE: . BUSINESS NA.'lE: FLOOR: , OF , t //1:: ð ^ I ~_.... 'Pt.."-,,,-wcJ. +- þ.e..c. (. 0 I DATE:b ~ /f&7 FACILITY NA.'fE: De.~ Wc..\"'tkðb ~ UNIT ~: \ OF , ceo (CHECK ONE) SITE D IAGRA.\{ /" FACILITY DIAGR.~\{ . t \Me ~+Ct-'" V\~"ì~(f [ if , 'f,lJ Þq 1 : ø.>I~ð "j ~~ «q ~ ~ ,,-\A.' r- i>Þq .;s. ~i~ .. 'It ~(' - ~ ~ - .' ~ " \ : ) . .8130 ;;;k) f\.l M r l.tìs...~¿ f{,,-,- t. Wø..V'"-('" ~o \4.Sl.- ",It\{ Tì "'~ ~~ tv "\ ~ClO '1 ";J:~c. U\ CtJv . "~-~ . t .. cœ ,\ð.I[ (o.. r- ~ '^'~t Et) -r~c -- t. J)r; V~ \,oJ"', - - ~ ~ , U\ ~ ,0#' LV O-H'.~J^.Q't(. Se- t Wo-r~Sl- '" ~ wesftrt\ ~ r .,. . -J. ~- ^ , \ f>k,/~/('¡ ~> F.D D r-Ne, v(þ. Y " B4.K~V"5 ~o(IJ A-lIì~ MðVt.rs \[ t ~"o. ""'1 WtLY't. tAOIt S~ ~~I"'~( (Inspector's Comments): -OFFICIAL USE m LY- 1 s , .... t 7d ~ . , ~\ \ I \ ¡ \ ~ :f '>" .--.:::. ~ ,.....s::¡ E:'.I:. _.\1-1 ro ;"0 ~ ... ',t - r ~ () ~ ,- 5A - SITE D[AGRAH (Req~lr~teas) cJ. Address: Identity. principle bulldin¡s by the Street nuabers. 3. Store Drains. Culverts. Yard Dra1ns 9. Lock (key.x 10. MSDS Stors2e Box 11. Railroad Tracks 12. Fence or Barrier a. Wire b. Masonry c. Wood d. Gates ~;-" . . ;., -, r.: .... .. ,~..èi 2, Street(s). Alley.. Driveway.. and Parkln¡ Area. adjacent to the property, Include the atreet na.ea. 4. Drainaie Canala. Ditcbea. Creeks. 13. POlferllnea 5. 8ulldlnlls a. Fre.e construction 14. Guard Station b. Nasonry constructIon 15. Stora¡e Tanks: Identity the cepaci ty in Kill. ... Above ¡round b. Underground c. Metal constructIon d. Acce.. Door @ Utility Controls a. Ga. 18. Dlkln¡ or 8era b. Electricity 17. Evacuation Route c. Water 18. EvacuatIon Area: Identity the locaUoo where eaployeea wIll ..et. 1) Fire Suppression Sy.te..: a. Fire Hydrants Þ. FIre SprInkler Connection. Ig. Outside Hazardou. !fa.t. Staraio c. Fire Standpipe Connection. 20. Outside Hazardous Kater!al Storals d. Water Control Valves Cor protection syste.. 21. Outside Hazardous Material U.e/Handllnr e. Fire PWlp 22. Type oC Hazardou. Material/lfuta Stored or Used (See Below) TYPE at HAZARDOUS MATERIAL 8. Pire Depart.ent Ace... P '" FlllJiliable ! · bplodve L · ~~u!d R . RadloloJical C . Corro.lve 0 · Oaldlzer 0 · Ga. P . POhon If . Water Reacti ve T · Todc S · SaUd ' H . Cryo~enJc D . Ifute 8 · Bt1oIo,lcal Exa.ple: Flaaaable Liquid· PL FACILITY OIAGRAM (Require( it... in addition to tbe above) 1- R.t...r. tor Sprinkler. 2. Pllrt! tionl \ 3. Stairwaya: IndIcate the 1eveh served Cro. hi¡¡:hut to lowe.t. 4. Escalator: Indicate the leveh served Cro. hl.hu t to lowe.t. 5. Elevatol" 8. Attic Accen 1. Sky Urhta ----...---- --"--- . - a. Fire E.cape. ~Alr CondltlonJnr Unita 10. WInd_a 11. Inaide Hasardoua Waate Storac. 1~. In.lde Hazardous Mat.riall Stor'~e 13. Inlide Hazardoul MaterIal. Uae/H.ndlin~ '€!> Sewer Drain Inlets