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Home My WebLink AboutBUSINESS PLAN 10/24/2003 ;. ~i/1' .. "~,, , ;¡¡;,-~ -!_ I . . . ~-- T D WHITTON CONSTRUCTION INC SiteID: 015-021-002170 Manager : Location: 480l WIBLE RD City BAKERSFIELD BusPhone: ~~) Map : 123 ~ t Grid: 13C ~~"f.. C¿ (661) 834-5894 CommHaz : Moderate FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 07 EPA Numb: SIC Code:1611 DunnBrad:77-017-3722 Emergency Contact MARTY WHITTON Business Phone: 24-Hour Phone : Pager Phone / Title / PRESIDENT (661) 834-5894x" (661) 835-8348x- (661) 201-6230xCELL. Emergency Contact / Title TRAVIS/EMOGENE WHIT / BOD/SEC/TREAS Business Phone: (661) 396-0655x' 24 -Hour Phone () x Pager Phone : () X Period Preparer: Certif'd: ,ParcelNo: to Fire Press ImmHlth DelHlth Phone: (661) 834-5894x State: CA Zip 93313-2647 Phone: (66l) 834-5894x State: CA Zip 933l3-2647 TotalASTs: = Gal TotalUSTs: = Gal RSs: No Hazmat Hazards: Contact : MailAddr: 4801 WIBLE RD City BAKERSFIELD Owner Address City MARTY WHITTON 4801 WIBLE RD BAKERSFIELD Emergency Directives: I, Martha Tuck~r Do hereby certify that I have (Type or print name) reviewed the attached hazardous materials manage- Tta- Df- WHITTON CONSTRUCT¡ONI. ::{NC_ ment p n or anâ tnat It along with (Name of BusIness) any corrections constitute a complete and correct man- agement plan for my facility. 10/24/03 Date -1- 10/17/2003 ~/ Per Itr:iij;;ô~per..te 'I " Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE This permit is issued for the following: IíI Hazardous Materials Plan o Underground Storage of Hazardous Materials o Risk Management Program o Hazardous Waste On-Site Treatment 2631 Issue Date . PERMIT ID # 015-021-002164 ALTEC AUTOMOTIVE LOCA nON ".;. Issued by: " . . Bakersfield Fire Department OFFICE OF ENVIRONMENTAL SERVICES 1715 Chester Ave., 3rd Floor Approved by: Bakersfield, CA 93301 Voice (661) 326-3979 , FAX (661) 326-0576 Expiration Date: DEC 1 4 2000 . June 30, 2003 ~.Per it tô Operate I Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE Issued by: This cermit is issued for the following: ~ Hazardous Materials Plan o Underground Storage of Hazardous Materials o Risk Management Program o Hazardous Waste On-Site Treatment LOCATION 4801 , Bakersfield Fire Department : OFFICE OF ENVIRONMENTAL SERVICES' 1715 Chester Ave., 3rd Floor Approved by: I Bakersfield, CA 93301 Voice (661) 326-3979 i FAX (661) 326-0576 Expiration Date: DEC 1. 4: 2000 , Issue Date 'June 30, 2003 -- . . ATTENTION WE ARE MOVING! New Address: T.D. Whitton Construction, Inc. 4801 Wible Rd. Bakersfield, CA 93313 New Location Mar: N MING AVE W E WHITE LANE S ~ CI I ~ ø=: 1&1 0\ ~ 0\ ~ TOW ~ v c¡j := g¡g « ø:lV PACHECO PANAMA LANE *' NOT TO ~ALE TAFTHWY Please make not or our new location. The approximate moving date is mid March, Phone and fax numbers are to remain the same. Office: (661)-834-5894 Fax: (661)-834-7001 Thanks! / 1-- ( r SITE DIAGRAM , 1 FAèILITY DIAGRAM ~ BuúnegN~e: T. D. WHITTON CONSTRUCTION, INC. Business Address: 4801 WIBLE ROADBAKERSFIELD, CALIFORNIA 93313-2647 . , (rp J'S(YJ::I.7 5-11 j.¡v ~ÞV1r. ðJ 'iJO.JQjIj ~AJ(II I ! I ! , ! ì ~o ~~w I I I ' I i ~ h~ _/ I ~?j..~,r' I ,)J~ fit(\' ~Q ~ø ~,/~~ /nJ<Þft7 f \. ) . --1, tI J7U:J ~ (#lI.1J/ , 1 . e=f;='. ; ·I~ ........, 1 ~«t IJ .. ~. ~ ~t()JQ c'~ ~(( ~J1('1 )~~ 4 ~0, N ï T. D. WHITTON CONSTRUCTION, INC. '480Ì WIBLE ROAD ~ BAKERSFIELD, CALIFORNIA ~3-2640 t ? X","' " ~ ,~' W 5 ~+w N .~ ~+5 w ,:' Fire Water Tanks e WATER CONNECTION N. W. CORNER WATER CONNECTION N. E. CORNER SHOP IS NEW AND IN PROGRF.~~ OXYGEN TANKS WILL HAVE RACKS INSIDE AND OUTSIDE OF RITn.nTNG FOR WELDING REPAIRS. FIRE WATER TANKS S. E. CORNER WATER N. E. CORNER OF BUILDING S. E. CORNER OF YARD, FIRE WATER TANKS WITH FIRE HOSE CONNECTION. 1 '- N: ~ x w s ~ W+f- S ~ ~+ e, . e BACK OF SHOP AREA SOUTH SIDE OF BUILDING SOUTH SIDE OF SHOP BUILDING MAIN SWITCH IS-LOCATED ON'BOX ATTACHED TO WALL. INSIDE N. E. CORNER OF BUILDING 110 GAL. HYDRAULIC FLUID 110 GAL. 15/40 MOTOR OIL 110 GAL. 40 WT. MOTOR OIL BAG OF OIL ASBORBANT FOR SPILLS 56 GAL. DRUM OF GEAR OIL ~ - , " ' ., . Main Electrical Switches Located in Northwest Corner of shop building, e MAIN ELECTRICAL SWITCHES ENTIRE CONSTRUCTION YARD. 3 "I~'-M~~;(~#' ~~ ~ - ~ ,..... /\./"\/ '\../ v 'v'" ~ ~ v ~ ----- ~ -=-- - -- r~ - '1:)1) IV' ....... PAC /-feCD 1(0, ~ rd~ '-- .~-v9 c¡j., -::¡ ('1 . -...------ .-.-/ -----.------. 31'dtj' .. ......u· u_. ~-.wV ~\j ~f --¡' -~- \ I It\ ~~~ -,.-- , :t ~y , rrf1~ ,'- ~'~~ð ~I /'^ ~ ,þø lU " ~ ~~ ~I Øf'il ~ r-vJ ~ . , _._------~- -< "'---" e -- SITE DIAGRAM r xx 1 FACILITY DIAGRAM [ Buûn~Nune: T. D. WHITTON CONSTRUCTION. INC. Business Address:4801 WIBLE.ß.-ºAD.l. BAKERSFIELD, CALIFORNIA 93313-2647 .'" , . ~ . 1'" . WHITTON CONSTRUCTION INC . F T D I f= Notif./Evacuation/Medical Agency Notification SiteID: 015-021-002170 9 Fast Format 9 Overall Site 9 12/13/2000 CONTAINERS, MOTOR OIL, HYDRAULIC OIL, TRANSMISSION FLUID, GEAR OIL, GREASE, ALL CONTAINERS ARE CHECKED EVERY MORNING AND EVERY EVENING. Employee Notif./Evacuation 12/13/2000 t\)M!:~ REPAIR AND NOTIFY ARTY CONTACTED IF TANKS NEED IF LEAKS OCCUR, SHOP FOREMAN, RICHARD UMFRESS WILL WHITTON, OWNER. OUR VENDOR, SERVICE OIL CO WILL BE TO BE REPLACED. Public Notif./Evacuation 12/13/2000 SHOP FOREMAN RICHARD UMFRESS, OWNER MARTY WHITTON, VENDOR SERVICE OIL CO OUTSIDE AGENCY NOT NECESSARY. Emergency Medical Plan 12/13/2000 MEDICAL EMERGENCY WOULD USUALLY OCCUR ON THE JOB AND NOT INVOLVE HAZARDOUS MATERIALS. IF BY CHANCE AN EMERGENCY OCCURRED IN THE SHOP AREA, 911 WOULD BE CALLED IF NECESSARY. EMPLOYEE WOULD BE TAKEN TO STOCKDALE KAISER OR NEAREST HOSPITAL. -9- 10/17/2003 J - - ~- CITY ~F BA~RSFIEL;- ~l\-2i OF.E OF ENVIRONMENTAL S.VICES 1715 Chester Ave., CA 93301 (661) 3 " ?-~ID BUSINESS OWNER I OPERATOR IDENTIF C FACILITY INFORMATION 2000 100 2001 101 Bl\'SINESS NAME (Same as FACILITY NAME or DBA- Doing Business As) 3 BUSINESS PHONE 102 T. D. WHITTON CONSTRUCTION, INC. 661/834-5894 I SITE ADDRESS 103 I 4801 WIBLE ROAD f- I CITY BAKERSFIELD 104 CA ZIP 93313-2647 105 I I DUN& 106 SIC CODE 107 I B~DSTREET FED. ID #77-0173722 (4 Digit #) 1611 COUNTY KERN 108 OWNER MAILING ADpRESS 4801 WIBLE ROAD 113 , I CONTACT MAILING AQDRESS 119 4801 WIBLE ROAD NAME MARTY WHITTON 123 NAME TRAVIS & EMOGENE WHITTON 129 ¡ TITLE PRESIDENT 125 TITLE BOARD OF DIRECTORS/SEC./TREAS. 130 , BUSINESS PHONE 661/834-5894 126 BUSINESS PHONE 661/396-0655 131 24-iHoUR PHONE 661/835-8348 127 24-HOUR PHONE 661/396-0655 132 of those individuals responsible for obtainin9 the information. I certify under penalty of law that I have personally examined s bmitted in this inventory and believe the information is true, accurate, and complete. DATE 134 NAME OF DOCUMENT PREPARER 135 '¡ 11/02/00 MARTHA TUCKER 136 TITLE OF OWNER/OPERATOR MARTY WHITTON PRESIDENT i 137 ! i I I UPCF (7/99) S:\CUPAFORMS\OES2730.TV4.wpd ,. ,'~,,'/,j ". ~~,' ~ ~ ., - . CITY OF BAKERSFIELD OFFICE OF ENVIRONMENTAL SERVICES 1715 Chester Ave., Bakersfield, CA (661) 326-3979 HAZARDOUS MATEIDALS MANAGEMENT PLAN INSTRUCTIONS: 1. To avoid further action, return this fonn within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. 5. You may also attach Busiriess Owner / Operator Fonn and Chemical Desëription Fonn(s) to the front of this plan instead of completing SECTION I. below for initial submission. SECTION I: BUSINESS IDENTIFICATION DATA BUSINESS NAME: T. D. WHITTON CONSTRUCTION, INC. LOCATION: 4801 WIBLE ROAD MAILING ADDRESS: 4801 WIBLE ROAD CITY: BAKERSFIELD STATE: CA ZIP:93313 PHONE: 661/834-5894 PRIMARY ACTIVITY: EARTHWORK, ASPHALT PAVING & GRADING AND RELATED ITEMS. OWNER: MARTY WHITTON PHONE: 661/834-5894 ,MAILING ADDRESS: 4801 WIBLE ROAD, BAKERSFIELD,· CALIFORNIA 93313-2647 EMERGENCY NOTIFICATION CONTACT TITLE BUS. PHONE 24 HR. PHONE 661/835-8348 1. MARTY WHITTON PRESIDNET,. 661/834-5894 661/201-6230 2. TRAVIS 'WHITTON BOARD OF DIRECTORS 661/396-0655 661/396-0655~ 1 - - HAZARDOUSMATEmALS~AGEMENTPLAN SECTION 11.1: DISCOVERY AND NOTIFICATIONS A. LEAK DETECTION AND MONITORING PROCEDURES: THREE (3) CONTAINERS, 15/40 MOTOR OIL (120."Lb.), HYDRAULIC OIL (120, LB.), 40 WT. MOTOR OIL (170 LB.), TRANSMISSION FLUID, 55 GAL. DRUM, GEAR OIL, 55 GAL. DRUM, GREASE, 1/4 DRUM. ALL CONTAINERS ARE CHECKED EVERY MORNING AND EVERY EVENING. B. EMPLOYEE :AND AGENCY NOTIFICATION: ~..- --_._-. --_.." -- --. IF LEAKS OCCUR, SHOP FORMAN, RICHARD UMFRESS WILL REPAIR AND NOTIFY MARTY WHITTON, OWNER. OUR VENDOR, SERVICE OIL COMPANY WILL__ BE- . CONTACTED_ IF TANKS NEED TO BE REPLACED. C. ENVIRONMENTAL RESPONSE MANAGEMENT: SHOP FOREMAN, RICHARD UMFRESS OWNER, MARTY WHITTON VENDOR, SERVICE OIL COMPANY OUTSIDE AGENCY NOT NECESSARY. _.. _.,_ ._. .n ~. . .._. _ . ~.... - D. . EMERGENCY MEDICAL PLAN: MEDTCAL'EMERGENCY WOULD USUALLY OCCUR'ONTHEJOB AND--NOT INVOLVE HAZARDOUS MATERIALS. IF BY CHANCE AN ENERGENCY OCCURRED IN THE SHOP AREA, 911 WOULD BE CALLED IF NECESSARY. EMPLOYEE WOULD BE TAKEN TO STOCKDALE KAISER, OR NEAREST, HOSPITAL.' 2 ~~" \- .+:,_., "( ¿'. .;¡ ~ _._--~ - -- .- ,4;. :--~ .,.. ,'.~-, Jot. 't, . ' I~ I - e HAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 11.2: RELEASE RESPONSE PLAN A. HAZARD ASSESSMENT AND PREVENTION MEASURES: MOTOR OI~S AND FLUIDS ARE CONTAINED IN BULK CONTAINERS WITH RELEASE NOZZLES PROVIDED BY THE VENDOR. ALL NECESSARY SAFETY REQUIREMENTS ARE FOLLOWED. B. RELEASE CONTAINMENT AND/OR MITIGATION: IF MOTOR OIL IS SPILLED__IT IS IMMEDIATELY~CLEANED UP BY THE PERSON WHO HAD THE ACCIDENT. C. CLEAN-UP AND RECOVERY PROCEDURES: NO MAJOR CHEMICAL RELEASE, JUST OlD SPILLS ONCE IN A WHILE. DIRTY OIL AND FLUIDS: ASBURY ENVIRONMENTAL SERVICE U~ED OIL fIL_TERS;, KERN OIL_ FILTER RECXCJ,ING PICK-UPS AS NEEDED. UTILITY SHUT -OFFS (LOCATION OF SHUT -OFFS AT YOUR FACILITY) **SEE ATTACHED SHEETS**** NATURAL GAS/PROP ANE: NO GAS. REFILLABLE PROPANF. CONT]!, TNF.R ON F.QfTTPMENT. ELECTFUCAL: MAIN, NORTHE~~T CORNER OF SHOP BUILD~NG WATER: LARGE FIRE WATER TANKS. HYDRANT N_F._~ORNF.R WTRT.'R s;, f'àfluI'L'R DR. SPECIAL: N/A LOCK BOX: YES/NO IF YES, LOCATION: / / / / / / / / / PRlV ATE FIRE PROTECTION/W A TER AVAILABILITY A. PRIVATE FIRE PROTECTION: TWO( (2) LARGE~F;[RE..wATER TANKS B. WATER AVAILABILITY (FIRE HYDRANT): NORTHEART CORNER OF WIBLE ROAD AND CATTLE DRIVE. (ACROSS THE STREET FROM ENTERANCE) 3 - . - ~ '1 ?"~:1;'. I ("~. . - I.. HAZARDOUSMATEmALS~AGEMENTPLAN SECTION III: TRAINING NUMBER OF EMPLOYEES: EIGHT _ ( 8 ) MATERIAL SAFETY DATA SHEETS ON FILE: YES, TWO (2) SETS r MAIN OFFICE AND SHOP OFFICE. BRIEF SUMMARY OF TRAINING PROGRAM: ALL EMPLOYEES ARE TOLD TO BE CAREFUL WHEN WORKING ON THEIR EQUIPMENT. THEY ARE INFORMED WHERE ALL THE "CLEAN-UP" MATERIALS ARE LOCATED, AND TO CLEAN THE AREA AFTER WORKING. WEEKLY SAFETY MEETINGS ARE HELD TO DISCUSS A VARIETY OF SUBJECTS...'. CERTIFICATION I, MARTHA TUCKER CERTIFY THAT THE ABOVE INFORMATION IS ACCURATE. I UNDERSTAND THAT THIS INFORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEALTH AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIV. 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT INACCURATE)NFORMATION CONSTITUTES PERJURY. - <- -, OFFICE MANAGER . TITLE 11102/00 DATE 4 ì t I CITY OF BAKERSFIELJA OF CE OF ENVIRONMENTAL sftVICES 1715 Chester Ave., CA 93301 (661) 326-3979 HAZARDOUS MATERIALS INVENTORY CHEMICAL DESCRIPTION ,",' o REVISE 200 (one {onn pe, metøriø/ pe, building 0' af8a} Page L of 203 oVes ~ 202 204 ';, "~*;>,,:.-i::X:ÎI.~'#~~~IÇM:Î~F~~ArtON s'>r~;;"", TRADE SECRET 0 Ves No 206 If Subjeclto EPCRA. refer to Instructions CHEMICAL NAME P~t«.b) e LL W\ G-^,¿ ~c: (;e£Pr S£... 207 COMMON NAME EHS· oVes ~ 208 FIRE CODE HAZARD ClASSES (Complete If requesled by local fire cIIieI) 209 -:~.ìiEHs¡~~Y~·~ ~)~~,~~,~~~,: 210 Î ! CAS PHYSICAL STATE o I LIQUID o ~ GAS lARGEST CONTAINER CURIES 213 TYPE o p PURE ø s SOLID m MIXTURE o w WASTE 211 RADIOACTIVE 214 215 FED HAZARD CATEGORIES (Check all that apply) ì ANNuAL WASTE I AMOUNT æ(,' FIRE 0 2 REACTIVE o 3 PRESSURE RELEASE o 4 ACUTE HEALTH 05 CHRONIC HEALTH 216 ¡ UNITS· ogaGAL odCUFT . If EHS, amount must be In Ibs. AVERAGE DAIL V AMOUNT o In TONS 219 STATE WASTE CODE 220 217 MAXIMUM CAlL V AMOUNT 221 DAVS ON SITE 222 STORAGE CONTAINER (Check an thaf ,pP/Y) o a ABOVEGROUND TANK Db UNDERGROUND TANK , 0..9 TANK INSIDE BUILDING 6 d STEEL DRUM De PLASTICINONMETAlLIC DRUM Of CAN o 9 CARBOV o h SILO o I FIBER DRUM 0, BAG Ok BOX o I CVLINDER o m GlASS BOTTLE o n PlASTIC BOTTLE 00 TOTE BIN o p TANK WAGON o q RAIL CAR o r OTHER 223 STORAGE PRESSURE o sa ABOVE AMBIENT o ba BELOW AMBIENT 224 225 ... j1, ,,' ~ ,~' ~ ,. ~,ÿ",. i~¡ . j.,! '~CÀS'#'';:,-" ,..,' ";,', ,iI;~,1.., 242 o Ves 0 No 228 231 o Ves 0 No 232 235 o Ves 0 No 236 239 o Ves 0 No 240 243 oVes oNo 244 229 i 2 230 " 3 I 234 4 238 233 237 241 , ¡ 5 I 245 ~:¡;':, ~t~~~~?\.'rz» ~~tt~fAL t0Ç~UL W\6-1e . II ~ ;&() UPCF (7/99) S:\CUPAFORMS\OES2731.TV4.wpd \ " I ~ o NEW . CITY OF BAKERSFIELQa OFPI"cE OF ENVIRONMENTAL SJ.!{VICES 1715 Chester Ave., CA 93301 (661) 326-3979 HAZARDOUS MATERIALS INVENTORY CHEMICAL DESCRIPTION 200 (one fønn per ma/e1ilJ1 per building Ø! ,l.e) Page g of ~ . ~. '.~. ....\ ,.y. , .... ,- ':.\ ·:;;:;'il:~~>·.~Ú·':..t;';~~"~·;:~~:,.:. .~.. . ':, ,; ;ifi~ì=ACia.rr'l'INFORMA TION 3 BUSINESS NAME ( e lIS FACILITY NAME 0# DBA . Doing Business As) -r: .1. . WkcttõAJ ~1Ùg~N ¡ W,b.I€- ~. oVes ~ 202 204 CHEMICAL LOCATION ¿-of . ~p FAÇILITY ID II CHEMICAL NAME ~. 1 MAP II (optional) 203 ·~;.i~i~;<;M':'i\'ï\~;II.,:&~~~I~~~~~~g~"'ATlOt4S~:,:J~:,;":,:';;'"" , . TRADE SECRET 0 Ves No 206 If Subject to EPCRA. retfll' to Instrudions EHS' COMMON NAME CAS' 201 oVes ~ 208 FIRE CODE HAZARD ClASSES (Ccmplele If requested by local fire chief) 209 ";~~;~~si~~Y~"'1II ~~ ~~_,'.,i,'", ~,~;IIJ..'~,~,·..:.t.<':: . , ".;.' <;". ' TYPE OpPURE PHYSICAL STATE o I SOUD EJ1 FIRE 0 2 REACTIVE 219 STATE WASTE CODE FED HAZARD CATEGORIES : (Check aII1h8t apply) I ANNUAL WASTE I AMOUNT UNITS' STORAGE CONTAINER (Check aO 1M/apply) / ci. ABOVEGROUND TANK 0, UNDERGROUND TANK G'c TANK INSIDE BUILDING o d STEEL DRUM STORAGE PRESSURE STORAGe TEMPERATURE m MIXTURE ¡:;¡{¡ LIQUID o w WASTE 211 RADIOACTIVE 210 ! 213 I ! oVes I o 9 GAS lARGEST CONTAINER 215 214 o 3 PRESSURE RElEASE o 4 ACUTE HEALTH o 5 CHRONIC HEALTH 216 ¡ I 2201 217 221 216 AVERAGE DAIL v AMOUNT ga GAL 0 d CUFT 0 Ib LBS 0 In TONS . If EHS. amount must be In Ills. DAVS ON SITE 222 o e PLASTICINONMETALLlC DRUM o/CAN o 9 CARBOY o h SILO o I FIBER DRUM OJ BAG Ok BOX o I CYLINDER o m GLASS BOTTLE o n PlASTIC BOTTLE 00 TOTE BIN o P TANK WAGON o q RAIL CAR Or OTHER 223 o 8. ABOVE AMBIENT o ba BELOW AMBIENT 224 j 2 230 231 o Ves 0 No 232 233 I 3 I 234 235 DYes 0 No 236 237 j 4 238 239 DYes ONo 240 241 L I ¡ 5 242 243 245 UPCF (7/99) S:\CUPAFORMS\OES2731.TV4.wpd HAZARDOUS MATERIALS INVENTORY CHEMICAL DESCRIPTION .. CITY OF BAKERSFIEL-U. OFPfCE OF ENVIRONMENTAL ~VICES 1715 Chester Ave., CA 93301 (661) 326-3979 ,- , D~EW DADD D DELETE D REVISE 200 (one fonn per matarial {IIIr building or Page a of 204 oVes TRADE SECRET 0 Ves No 206 If Subject to EPCRA, refar to instruc:tions 207 COMMON NAME EHS· o Ves No 208 CAS' 209' t~:~~¡~~Y~:ÌD~~¥~~~~i~,! 210 ! FIRE CODE HAZARD CLASSES (Complete If requested by local tire dùel) TYPE o p PURE o w WASTE 211 RADIOACTIVE Dves CURIES 213 I I I PHVSICAL STATE o s SOUD ~IRE 02 REACTIVE O~GAS 214 LARGEST CONTAINER 215 FED HAZARD CATEGORIES (Chedl all thaI apply) I ANNUAL WASTE I At.«)UNT o 3 PRESSURE RELEASE o 4 ACUTE HEALTH o 5 CHRONIC HEALTH 217 218 AVERAGE DAILV AMOUNT 219 STATE WASTE CODE 218 i I 2201 UNITS· ga GAL 0 d CUFT . If EHS. amount must be In Ibs. o Ib LBS o In TONS 221 DAVS ON SITE 222 STORAGE CONTAINER (Cheek an that apply) ~ ABOVEGROUND TANK Db UNDERGROUND TANK ~ TANK INSIDE BUILDING o d STEEL DRUM De PLASTICINONMETALUC DRUM otCAN o g CARBOV o h SILO o I FIBER DRUM OJ BAG Ok BOX o I CVLINDER Om GlASS,BOmE o n PLASTIC BOTTLE 00 TOTE BIN o p TANK WAGON o q RAIL CAR Or OTHER 223 STORAGE PRESSURE o aa ABOVE AMBIENT o ba BELOW AMBIENT 224 225 229 ì 231 I 2 230 Dves DNa 232 3 I 234 235 DYesDNo 236 ; 4 238 239 Dves DNo 240 ~ ¡ 5 242 243 Dyes DNo 244 233 237 241 245 I I L )} ~ DtJ UPCF (7/99) S:\CUPAFORMS\OES2731.TV4.wpd // I CITY OF BAKERSFIEL.u.. OF CE OF ENVIRONMENTAL ~VICES 1715 Chester Ave., CA 93301 (661) 326-3979 HAZARDOUS MA rERIALS INVENTORY CHEMICAL DESCRIPTION ·/·::iJ>:":~~¡·r~".:;h,,~~·,vt,~~·,·(:· ,", . ' /'¡'¡I/ì=ACIÎ.[FY, INFORMATION . as FACILITY NAME 0# DBA . Doing Business As) /I J -r: 1). ~ U»04flw~w~,.J. ~. ðW 'fjß/ LuL6£e d, , 1 MAP # (optional) 203 DNEW DADO D DELETE D REVISE 200 ,- I CHEMICAL LOCATION DYes ~ 202 204 TRADE SECRET 0 Yes No 206 If Subjec:l to EPCRA, refer to Ins\lUclions , , 207 COMMON NAME EHS· o Yes No 208 CAS' 209 ::·~;f~~S¡~~~·'an ~~~~~~,~~*~/ 210 i TYPE o P PURE m MIXTURE o w WASTE 211 RADIOACTIVE 0 Yes CURIES 213 I I ----' i 215 ; , PHYSICALSTATE o s SOLID e{'LIQUID I o 9 GAS 214 LARGEST CONTAINER ; FEDIHAZARD CATEGORIES (Check all that apply) I ANNUAL WASTE I AMOUNT ~ FIRE 02 REACTIVE o 3 PRESSURE RELEASE o 4 ACUTE HEALTH o 5 CHRONIC HEAlTH 216 i 217 218 AVERAGE DAILY AMOUNT 219 STATE WASTE CODE 2201 UNITS· gaGAL OdCUFT . If EHS. amount must be In Ibs. o IÞ LBS o In TONS 221 DAYS ON SITE 222 STORAGE CONTAINER (ChllFk aU /hat apply) ¡g.(' ABOVEGROUND TANK O~NDERGROUNDTANK rn'c TANK INSIDE BUILDING o d STEEL DRUM o I FIBER DRUM OJ BAG Ok BOX o I CYLINDER o m GlASS BOTTLE o n PLASTIC BOTTLE 00 TOTE BIN o p TANK WAGON o q RAIL CAR o r OTHER I i I 223 i I I I 224 225 STORAGE PRESSURE D a AMBIENT D Þa BELOW AMBIENT STORAGE TEMPERATURE o a AMBIEm:: D be BELOW AMBIENT D c CRYOGENIC i 233 : 2 230 231 DYes 0 No 232 I 3 I 234 235 OYesONo 236 237 ¡ 4 238 239 DYes ONo 240 241 L I ¡ 5 242 243 Dyes ONo 244 245 , ' . I DATE 246 I L UPCF (7/99) S:\CUPAFORMS\OES2731.TV4.wpd o NEW HAZARDOUS MATERIALS INVENTORY CHEMICAL DESCRIPTION I CITY OF BAKERSFIELIà OF CE OF ENVIRONMENTAL s1m.VICES 1715 Chester Ave., CA 93301 (661) 326-3979 BUSINESS NAME ( ,':;:':V:",f,;-: )\V~:~"~~~'~':-~~:':J .~. .' ,~.,::~':':;: ;:", "... : ;Yi/FAcii.rI'Y·INFORMATION .". ..' ~tlJ~AJ J ~ M. (one To"" pet m~t building ~f8a) Page ....:L of ~ o REVISE 200 , . '.:.;.....,......y):,.. . - .~.., 3 203 oVes ~/ 202 204 :::~:.wJi~t~~~:i.:2¡~,~*;h..,:¡·i,~~II.,"&~~MI~~~~~9~~ÅTI,O~,.;',':,:::,;;;.·..·;:'··· CHEMICAL NAME Ves 0 No 206 If SubjecllO EPCRA, rei8/' to InsllUdions 7 COMMON NAME EHS· o YIIS No 208 CAS" 209 '~:;;~Its i~iy~.~ 111'-;;' ~'~,...'.',',,'~.,'~.~~,:, '¡;,:,:.','~.'.:,~.:,:..:' .·:\:·>:';i;::.',"'C tyPE o p PURE m MIXTURE ~IQUID o w WASTE 211 RADIOACTIVE 0 Ves , 05 CHRONIC HEALTH 216 i ~ 210 i 213 I I -----< i 215 : -FIRE CODE HAZARD ClASSES (Complete I requested by local tire chief) PH¥SICAL STATE o s SOLID ..<":::;.' -' < riÌ 9 GAS 214 LARGEST CONTAINER FED HAZARD CATEGORIES (ChecIt aU that apply) ANNUAL WASTE I AMOUNT o 3 PRESSURE RELEASE o 4 ACUTE HEALTH 218 AVERAGE DAIL V AMOUNT 219 STATE WASTE CODE 220 I ~ UNITS· 98 GAL 0 d CUFT . If EHS. amount must be In Ibs. o Ib LBS o In TONS 221 DAYS ON SITE 222 STORAGE CONTAINER (Check aD thaI apply) o a ABOVEGROUND TANK Db UNDERGROUND TANK o 0ANK INSIDE BUILDING ~ STEEL DRUM De PLASTIClNONMETALLlC DRUM o,'CAN o 9 CARBOV o h SILO o I FIBER DRUM OJ BAG Ok BOX o I CVLINDER o m GLASS BOmE On PLASTIC BOTTLE 00 TOTE BIN o p TANK WAGON o q RAIL CAR Or OTHER I WI STORAGE PRESSURE o aa ABOVE AMBIENT o ba BELOW AMBIENT 224 , 3 234 OVes ONo 228 231 oVes 0 No 232 233 235 DYes 0 No 236 237 239 o Ves 0 No 240 241 243 o Ves 0 No 244 245 ì I 2 230 I 4 : ¡- : 5 f 238 242 ·.:·'(~tf~,(.i."~,,¡ . ¡." ! l'~;~"\"'~'M~"" , ·:!.;"~*-'~~~i~~~{f;}l~_¡:·~.:·,:~ I I L UPCF (7/99) S:\CUPAFORMS\OES2731.1V4.wpd HAZARDOUS MATERIALS INVENTORY CHEMICAL DESCRIPTION I CITY OF BAKERSFIELIà OF CE OF ENVIRONMENTAL SlkVICES 1715 Chester Ave., CA 93301 (661) 326-3979 aNEW "-DD a DELETE a REVISE 200 (one fonn per material per building or af8s) Page k of !i- ¡ ," ~. ""'''''',,\ .y, ~.. '" ." BUSINESS NAME ( k, 3 203 oVes ~ 202 204 CHEMICAL NAME TRADE SECRET 0 Yes No 206 : If Subjed 10 EPCRA. refer 10 Instrudions oVes ~ 208 . '·~f~~~;~:;~i~*é<i:..,:;;i;I.,"Ç~~~I£~1~~F9~~AJlÒN:';"{':,<;,;,":;', ,', 207 COMMON NAME ,EHS· CAS" 209 -- ,. .' < ',,, . " '\. 1" ~'I '¡; ]. -it EUS is·Yes . III ~ bèJoW ~ be 'ID'';'' ", . .,..~..~::(:;.' '.'~ ':' <, ':);::~, 210 i ! TYPE o P PURE o m MIXTURE OW, WASTE 211 RADIOACTIVE 0 Yes oNo 212 CURIES 213 i ---' i 215 : FED HAZARD CATEGORIES (Check alllhat apply) ANNUAL WASTE AÞM:>UNT D 2 REACTIVE 214 LARGEST CONTAINER PHYSICAL STATE o s SOLID ~FIRE o I LIQUID 217 MAXIMJM DAll V AÞM:>UNT o 98 GAL cf CU FT . If EHS, amount must be In Ibs, 218 AVERAGE DAll V AÞM:>UNT 219 STATE WASTE CODE 216 i I 2201 3 PRESSURE RELEASE D 4 ACUTE HEALTH D 5 CHRONIC HEALTH UNITS· o Ib lBS o In TONS 221 DAVS,ON SITE 222 STORAGE CONTAINER (Check aU /1Isl apply) o a ABOVEGROUND TANK Db UNDERGROUND TANK DC TANK INSIDE BUilDING o d STEEL DRUM De PLASTICINONMETAlLlC DRUM Of CAN o 9 CARBOV o h SilO o I FIBER DRUM OJ BAG Ok BOX ¡;;r( CYLINDER o m GLASS BOTTLE o n PlASTIC BOTTLE 00 TOTE BIN o P TANK WAGON D q RAIL CAR o r OTHER 223 STORAGE PRESSURE D sa ABOVE AMBIENT o ba BELOW AMBIENT 224 STORAGE TEMPERATURE 225 ¡ 2 230 3 234 i 4 238 I "- I ; 5 242 I Dves DNo 228 229 231 o Yes D No 232 233 235 oVesoNo 236 237 239 oVes oNo 240 241 243 oVes oNo 244 245 ::i::j!it~fà;r'B;}!:. '. /1 ð¿ ¿Jò I I l UPCF (7/99) S:\CUPAFORMS\OES2731.1V4.wpd e CITY OF BAKERSFIEL~ OFFICE OF ENVIRONMENTAL SERVICES 1715 Chester Ave., CA 93301 (661) 326-3979 HAZARDOUS MA rERIALS INVENTORY CHEMICAL DESCRIPTION 200 ~,. ..;" IÆC!... ' CHEMICAL LOCATION 1 MAP 1# (optiona" >\\,t:~t.::t.~~~<;~,.'c{:' ), ,(.., : >:~..; "'" /: ~^:~' . : >~;~:ç:,~¡; ':::',:;;;ì; ;~+~,.; "';:-.' '?'r,"', .' ~~JI. ~~E~I~~ I~FC?~TlON , (one fonn per malerial per building or a188) Pagll !f- of ~ 3 I . , I I o Ves ~ 202 204 CAS/I TRADE SECRET 0 Ves No 206 If Subject to EPCRA, relet to Instructions oVes ~ 208 I 209 .è-~~;~~~¡~~cs.; d -*~;;~,~:*i;:' 210 ! CHEMICAL NAME f} c.edj I &IV€. .tk&fü ~€- 11-r~-~ FIRE CODE HAZARD CLASSES (Ccmpllllllll requested by local II chief) 207 COMMON NAME EHS· TYPE opPURE o m MIXTURE o w WASTE 211 RADIOACTIVE oVes PHYSiCAl STATE o s SOLID o I LIQUID g GAS 214 LARGEST CONTAINER FEDIHAZARD CATEGORIES ~IRE o 2 REACTIVE Ø3 PRESSURE RELEASE o 4 ACUTE HEALTH ~Check &II that apply) ì ANNUAL WASTE 217 MAXIWM 218 AVERAGE I AMOUNT CAlL V AMOUNT DAILY AMOUNT UNITS· o ga GAL d CU FT o Ib LBS o In TONS . If EHS. amount musl bllln Ibs, o 5 CHRONIC HEALTH CURIES 213 ¡ ---i i 215 ; 216 i I I 219 STATE WASTE CODE 2201 221 CAYS ON SITE 222 STORAGE CONTAINER (Check an /hal apply) 223 o a ABOVEGROUND TANK Db UNDERGROUND TANK DC TANK INSIDE BUILDING o d STEEL DRUM 011 PLASTICINONMETALLIC DRUM 01 CAN o g CARBOV o h SILO o I FIBER DRUM OJ BAG o kß'X !Ø'í CYLINDER o m GLASS BOTTLE o n PLASTIC BOTTLE 00 TOTE BIN o p TANK WAGON STO~GE PRESSURE Øa AMBIENT ~ AMBIEN1 o be BELOW AMBIENT o C CRVOGENIC ";X~;J:~~1~~~;J/f:~>,,.. o sa ABOVE AMBIENT o ba BELOW AMBIENT STORAGE TEMPERATURE o 88 ABOVE AMBIENT 1 I ! 2 230 231 o Yes 0 No 232 , 3 234 235 o Ves 0 No 236 ¡ 4 238 239 oVes oNo 240 ~ : 5 242 243 o Ves 0 No 244 o q RAIL CAR o r OTHER 224 225 229 233 237 241 245 m UPCF (7/99) S:\CUPAFORMS\OES2731.TV4.wpd I: .. CITY OF BAKERSFIELD6 OFF~E OF ENVIRONMENTAL S~VICES 1715 Chester Ave., CA 93301 (661) 326-3979 HAZARDOUS MATERIALS INVENTORY CHEMICAL DESCRIPTION i DNEW 200 DADD >:·.~~:;'.J~~:i~'.~;.'·h'·~'\~'r:~·"J _: , ;YliFAciÍ-fT'(,INFORMATlON Lø10¿Ru¿tc;Al I Lvc... ~ ..';";~', ,.',.-:,:"" :....iF'c'::.;, , ", ;.;f.;\' 'o.,',!JI;CHJ:MICAL.'INFORMATJON; ':'!-""(""'-:-'~"-."~<"'~ <'>~'.""':"'!''';''''!'''..'.,''''-r. ....:' :"'.:''';: (one fomr per m~rial Plr building or J B) Page ~ of o Ves ~ , 202 ; I , 204 TRADE SECRET D Ves No 206 : If Subject to EPCRA. refer to Insltudions CHEMICAL NAME HP G£4R. COMMON NAAE ~ CAS' FIRE CODE TYPE' o p PURE m MlX1\JRE , PHYSICAlSTATE D s saUD ~IQUID : FED HAZARD CATEGORIES ø(FIRE D 2 REACTIVE (Ched( Blllhøt apply) I ANNUÀl WASTE 217 ~ AMOUNT DgGAS 214 LARGEST CONTAINER D w WASTE 211 RADIOACTIVE oVes o 3 PRESSURE RELEASE o 4 ACUTE HEALTH D 5 CHRONIC HEAl. TH UNITS· o In TONS 221 DAVS ON SITE 222 218 AVERAGE DAIL V AMOUNT gaGAL odCUFT . If EHS. amount must be In Ibs. o Ib LBS STORAGE CONTAINER (ChllCtc ~aD that apply) o a ABOVEGROUND TANK o Þ UNDERGROUND TANK ~TANK INSIDE BUILDING I!J d STEEL DRUM De PLASTlCINONMETALLIC DRUM o/CAN o CARBOV o hSILO o I FIBER DRUM 01 BAG Ok BOX 01 CVLINDER o m GlASS BOTTlE o n PlASTIC BOTTlE 00 TOTE BIN Op TANKWAGON I , i STORAGE PRESSURE o sa ABOVE AMBIENT o ba BELOW AMBIENT 1 I ; 2 I 230 I 3 I 234 ! Dves ~ 208 210 I ! CURIES 213 I ! i 215 ; 218 i I 219 STATEWASTECOOE 220 o q RAIL CAR o r OTHER I 2231 I 224 231 o Ves 0 No 232 233 235 o Ves 0 No 238 237 239 oVes oNo 240 241 243 oVes oNo 2« 245 ¡ 4 238 I ~ : 5 242 I I ~.,:. 'fj~'!\1Æf9' ':·"·'·';'(A"~.'~""^~'('·' "'··:~··~N~~~~< -·~:·,·;;,;:-:,:j~,1ít,\~. . UPCF (7/99) S:\CUPAFORMS\OES2731.TV4.wpd I 'Î. ~ 'i I SECTION 1 Material Safety Data Sheet CODE: G0449 CHÈMICAl PRODUCT AND COMPANY IDENTIFICATION LUBRICATING SPECIALTIES COMPANY 8015 PARAMOUNT BLVD. PICO RIVERA, CA 90660 PHONE NUMBERS: Business hours: 24 hours: Chemtrec: General MSDS: (562) 776-4000 (800) 424-9300 (562) 776-4000 Product Name: Chemical Name: Common Name: Red-i EP Super Premium Grease #1 Petroleum grease CAS #: Mixture Grease I SECTION 2 COMMON NAME COMPOSITION/INFORMATION ON INGREDIENT$ CHEMICAL NAME CAS NO. % 131 0-66-3 <5 106-14-9 <10 64742-52-5 <80 68037-01-4 <10 64742-52-5 <1 Lithium Hydroxide 12-Hydroxystearic Acid Hydrotreated heavy naphthenic distillate 1 Decene Homopolymer, Hydrogenated Antimony dialkyldithiocarbamate Contains no other ingredients now known to be hazardous as defined by OSHA 29 CFR 1910.1 OOO(z). I SECTION 3 HAZARD IDENTIFICATION Principle Hazards: Slightly combustible Prolonged or repeated skin contact may cause dermatitis. See section 11 for complete health hazard information. Threshold Limits: The PEL (OSHA) and the TLV (ACGIH) is 5 mg/m3 as an oil mists. Primary Routes of Exposure: EYE SKIN May cause eye irritation. No significant adverse effects expected. Repeated or prolonged contact with skin may cause irritation which may lead to various skin disorders. Avoid prolonged skin contact. INHALATION No significant adverse health effects are expected to occur on short term exposure. ORAL I SECTION 4 ORAL Ingestion may cause nausea,diarrhea and stomach discomfort. FIRST AID MEASURES DO NOT INDUCE VOMITING. If conscious, give 2 glasses of water. Get immediate medical attention. EYE Flush with water at least 15 minutes. Get medical attention if eye irritation develops or persists. SKIN Wash immediately with soap and water. Remove soiled clothing. Get medical attention if irritation develops. Launder contaminated clothing. INHALATION Remove exposed person to fresh air. If breathing is labored, administer oxygen and obtain immediate medical attention. If irritation persists or if toxic symptoms are observed, get medical attention. Page 1 of 4 i', I SECTION 5 FLASH POINT: Material Safety Data Sheet FIRE 'FIGHTING MEASURES CODE: G0449 >200° C (COC) >392°F Slightly combustible. May release flammable vapors when heated above flash point. EXTINGUISHING MEDIA HAZARDOUS EXPOSURE SPECIAL FIRE PROCEDURES Carbon Dioxide, dry chemical, or foam. Avoid using water. Carbon monoxide and asphyxiants. Recommend SCBA. Use water only for cooling container. Water may cause splattering, or transport the flame. I SECTION 6 ACCIDENTAL RELEASE MEASURES Evacuate all non-essential personnel. Personal Protective Equipment must be worn, see PPE section 8 & 16. Remove sources of ignition. Prevent entry into sewers and waterways. Contain release, pick up for recycling or disposal. Residual liquid can be absorbed with inert material. Check DOT/CERCLA and other agencies for reporting requirements. Prevent contamination to soil, waterway and sewer systems. I SECTION 7 HANDLING AND STORAGE HANDLING Avoid prolonged skin contact, breathing vapors, and contaminated clothing. Use with adequate ventilation. Wear recommended protective equipment. Practice good personal hygiene after handling. Empty containers retain material residue. Do not cut, weld, braze, solder or expose containers to other ignition sources. STORAGE Store in closed containers of proper construction. Store away from ignition sources and in areas of good ventilation. I SECTION 8 EXPOSURE CONTROLS - PERSONAL PROTECTION EXPOSURE TL V = 5 mg/m3 as oil mist LIMITS VENTILATION Use in areas of adequate ventilation GLOVES Use nitrile or neoprene gloves are recommended. EYE PROTECTION Safety glasses. goggles, or face shield are recommended. RESPIRATORY Self-contained breathing apparatus is recommended for confined space entry. CLOTHING Long sleeve shirt and apron when potential for skin contact. Wear neoprene or nitrile rubber boots when necessary to avoid contaminating shoes. Page 2 of 4 I SECTION 9 Material Safety Data Sheet PHYSICAL AND CHEMICAL PROPERTIES CODE: G0449 APPEARANCE: BOILING POINT: EVAPORATION POINT: FLAMMABILITY: FLASH POINT: ODOR: red grease >300· C less than ether combustible liquid > 200· C petroleum odor Ph: SOLUBILITY: SPECIFIC GRAVITY: VAPOR DENSITY: VAPOR PRESSURE: VOC.%: nld neglibible .929 heavier than air <0.01mm Hg @ 200 C nil ¡SECTION 10 STABILITY CONDITIONS TO AVOID STABILITY AND REACTIVITY Material is normally stable at ambient temperature and pressure. Oxidizing agents. Do not heat above the flash point. POLYMERIZATION DECOMPOSITION Will not occur. Carbon dioxide, carbon monoxide. I SECTION 11 TOXICOLOGICAL INFORMATION ORAL TOXICITY Swallowing material may cause irritation of the gastrointestinal lining. nausea, vomiting, diarrhea, and abdominal pain. EYE IRRITATION SKIN IRRITATION Not expected to cause eye irritation. Not expected to be a primary skin irritant. Prolonged or repetitive contact may cause irritation. CARCINOGENIC This material has not been identified as a carcinogen by NTP. IARC, or OSHA. ¡SECTION 12 ECOLOGICAL INFORMATION This material is expected to have adverse affects on marine and plant life. Spills may contaminate drinking water. ¡SECTION 13 DISPOSAL CONSIDERATIONS DISPOSAL Consult federal, state. and local regulations regarding disposal methods. Recycle used oil. Do not contaminate used oil with solvents or other chemicals. I SECTION 14 TRANSPORTATION INFORMATION See 49 CFR part 171.8 through 178.510 DOT SHIPPING NAME: Oil. n.o.s. DOT HAZARD CLASS: not regulated UNINA NUMBER: GUIDE NUMBER: 27 IMDG CODE: Materials classified as DOT Combustible Liquids (Flash Point> 1410 F and < 2000 F) are not regulated by DOT in containers of 110 gallons, or less for domestic shipments. Page 3 of 4 4\ i "f ¡... I SECTION 15 Ma,terial Safety Data Sheet REGULATORY INFORMATION CODE: G0449 TSCA SARA 311 SARA 312 SARA 313 CAL PROP 65 RCRA CERCLA All components of this material are on the US TSCA inventory. contains <25 ppm antimony dialkyldithiocarbamate not listed not listed listed I SECTION 16 OTHER INFORMATION HMIS CODE: NFPA CODE: Health 1 1 Fire 1 1 Reactivity o o PPE C PRECAUTIONARY LABELS: NA This information has been compiled from sources considered to be dependable and is accurate to the best of Lubricating Specialties Company knowledge. Lubricating Specialties Company makes no warranty whatsoever, expressed or implied, of MERCHANTABILITY OR FITNESS FOR THE PARTICULAR PURPOSE, regarding the accuracy of such data or the results to be obtained from the use thereof. Lubricating Specialties Company assumes no responsibility for injury to recipient or third persons, or for any damage to any property and recipient assumes all such risks. Prepared by: Ron Dickenson Safety Manager Approved by: Mark Negast Technical Manager Page 4 of 4 l' ~ ... . ~ .;¡ Hay 29, 1992 Material Safety Data Sheet USA and WORLDWIDE ',. \ HG TRACTOR FL'UID ". , PHILLIPS 66 COMPANY A Division öf Phillips Petroleum Coapany Bartlesville, Oklahoaa 74004 PHONE NUMBERS Eaergencya · Business Hours (918) 661-38í5 After Hours (918) 661-8118 General MSDS Infor.ationl (918) 661-8321 For Additional MSDSsa (918) 661-5952 ~ ." A. Product Identification Synonyasa Hydraulic fluid, Philube HG, Multi-functional tractor fluid Che.ical Naaea Mixture 'Che.ical Fa.Uya Hydrocarbon Che.ical For.ulaa Mixture CAS Reg. NO.1 Mixture Product NO.1 53130 'tj Product and/or Co.ponents Entered on EPA's TSCA Inventory, YES This product is in U.S. comaerce, and is listed in the Toxic Substances Control Act (TSCA) Inventory of Che.icals; hence, it .ay be subject to applicable TSCA provisions and restrictions. B. Components , " Ingredients CAS Nuaber } / :II: By Wt. OSHA PEL ACGIH TLV This product does not .eet the definition of a hazardous aateria! given in 29 CFR Part 1910.1200(OSHA). Infor.ation on this fora is furnished as a custo.er service. NA - Not App1ic:ab1e NB - Not Established HG Tractor Fluid (USOO3471) Pace I ors c. Personal Protection Information Ventilation. Use adequate ventilation to control exposure below recoaaended levels. Eye Protection. Not generally required. For concentrations exceeding the recommended exposure level, use NIOSH/MSHA approved air purifying respirator. Use safety glasses with side shields. For splash protection use che.ical goggles and face shield. Respiratory Protection. Skin Protection. Use protective garments to prevent skin contact. NOTE. Personal protection information shown in Section C is based upon general information as to nor.al uses and conditions. Where special or unusual uses or conditions exist, it is suggested that the expert assistance of an industrial hygienist or other qualified professional be sought. D. Handling and Storage Precautions Avoid contact with eyes, skin or clothing. Avoid breathing vapors, .ist, fuae or dust. Use with adequate ventilation. Wear protective equip.ent and/or garments described in Section C if exposure conditions warrant. Wash thoroughly after handling. Launder contaainated clothing before reuse. If pressure injected under the skin, can cause gangrene if not treated. Store in closed containers. Store in well-ventilated area. E. Reactivity Data Stability. Stable Conditions to Avoid. Not Applicable Incompatibility (Materials to Avoid). Oxygen and strong oxidizing agents. Hazardous Polyaerization. Will Not Occur Conditions to Avoid. Not Applicable Hazardous Deco.position Products. Carbon oxides and various hydrocarbons for.ed when burned. F. Health Hazard Data Recommended Exposure Limits: OSHA PEL and ACGIH TLV for o'il .1sts is 5 .g/.3. HG Tradcw Fluid (USOO347J) Pa¡c 2 ors Acute Effects of Overexposure: Eye. Hild irritation. Skin. Hild irritation Practically non-toxic by .kin absorption. with prolonged or repeated contact. Inhalation. None expected. Ingestion. Practically non-toxic. Subchronic and Chronic Effects of Overexposure: No known applicable inforaation. Other Health Effects: Pressurized injection of product under the skin can lead to seriously inflaaaed tissue. If left untreated injury can be gangrenous. Prolonged and repeated exposure to oil aist poses a risk of pulmonary disease such as lung infla..ation. This condition usually causes no sy.pto.s. Continuous skin contact with used aotor oils has caused skin cancer in laboratory aniaal.. Avoid prolonged skin contact with used aotor oil. Health Hazard Categories: Aniaal Hwaan Aniad Hn.an Known Carcinogen ___ Suspect Carcinogen ___ Hutagen Teratogen ___ Allergic Sensitizer ___ Highly Toxic Toxic Corrosive Irritant Target Organ Toxin Specify - No known applicahïë inforaation. First Aid and Emergency Procedures: Eye. Flush eyes with running water. If irritation or adverse .yapto.s develop, seek aedical attention. Skin. Wash skin with soap and water. If irritation or adverse .yaptOJlS develoPt seek aedical attention. , ' Inhalation. Reaove froa exposure. If illness or adverse sY1lptoa. develop, seek aedical attention. Ingestion I If illness or adverse syaptOJlS develop, seek aedical attention. Note to Physician. For injection injurie., iaaediate .edical treat.ent is required. Physicians aay call the eaergency nuaber (918) 661-8118. HG Tractor Fluid (USOO3471) raze 3 fAS -, . " G. Physical Data Appearance. Colorless to dark liquid Odor. Mild Boiling Point. > 600F (> 316C) Vapor Pressure. <1 aa Hg a 68F (20C) Vapor Density (Air = 1). > 1 Solubility in, Water. Negligible Specific Gravity (H20 = 1). 0.89 a 60F (16C) Percent Volatile by Voluae. Negligible Evaporation Rate ( = 1). Negligible Viscosity. 60 cSt a 104F (40C) H. Fire and Explosion Data Flash Point (Method Used). Flam.able Liaits (r. by Voluae in Air). Fire Extinguishing Medial Special Fire Fighting Procedures. Fire and Explosion Hazardsl 420F (216C)(COC, ASTH D92) LEL - Not Established UEL - Not Established Dry cheaical, foaa or carbon dioxide (C02). Evacuate area of all unnecessary personnel. Shut off source, if possible. Use NIOSH/MSHA approved self-contained breathing apparatus and other protective equip.ent and/or garaents described in Section C if conditions warrant. Water fog or spray .ay be used to cool exposed containers and equipaent. Carbon oxides and various hydrocarbons foraed when burned. I. Spill, Leak and Disposal Procedures Precautions Required if Material is Released or Spilled. Wear protective equip.ent and/or garaents described in Section C if exposure conditions warrant. Shut off source, if possible and contain spill. Keep out of water sources and sewers. Absorb in dry, inert aater ial. Transfer to disposal druas. Waste Disposal (Insure Conforaity with all Applicable Disposal Regulat.ions) I Incinerate or otherwise aanage at a peraitted waste aanageaent facility. HG Tractor F1uÏd (USOO3471) Pace .. 015 .. .. J. DOT Transportation Shipping NaJle I Hazard Class I ID NUllÙ)erl Packing Group. Harking. Label. Placard. Hazardous' Substance/RQ. Shipping Descriptionl Packaging References. Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable K. RCRA Classification - Unadulterated Prod¡¡ct as a Waste Prior to disposal, consult your Environmental contact to determine if TCLP (Toxicity Characteristic Leaching Procedure, EPA Test Method 1311) is required. Reference 40 CFR Part 261. L. Protection Required for Work on Contaminated Equipment Contact imNediate supervisor for specific instructions before work is initiated. Wear protective equipment and/or garaents doscribed in Section C if exposure conditions warrant. M. Hazard Classification This product meets the following hazard definition(s) as defined by --- the Occupational Safety and Health Hazard Coaaunication Standard (29 CFR Section 1910.1200). Flamaable Aerosol Explosive Health Hazard (Section F) ::: Organic Peroxide ___ Oxidizer ___ Pyrophoric ___ Unstable ___ Water Reactive Coabustible Liquid COllpressed Gas FlalUlable Gas ::: Flaa.able Liquid ___ Flaamable Solid _X_ Based on information presently available, this product does not .eet any of the hazard definitions of 29 CFR Section 1910.1200. N. Additional Comments SARA 313 As of the preparation date, this product did not contain a cheaical or chemicals subject to the reporting requireaents of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. ""DUpe PtIroIeu.. Cøm)lIIY (roI_ to PIIIßIpe hIro/eUm c.on.p.nyor Pblllipl indudal\'l dMllons. rtnIilalel and IUbddiaria) beI~ Ulal VIe IlIfOftMlioft _ U;,,'" beni" (iMl....... "" ODd III_IIU) II ea:urete _ or VIe d... lienal. NO WARRANTY OF MERotANTABIUTY. FITNESS FOR A~ PAATtctJUJt PURPOSE OR ANY OTHER WARRANTY. EXPRESS OR IMPLIED. IS WADE AS CONCEJlNS THE INFORMATtON HEREJN PROVIDED. TM lNormaUcla ...-- 1Ieftj" ""'lOt 0II1y to \hi pedfIc ........ud dclip\ated .... may _ .. ...11d -... _ ........_ II _ in _1Ii__ willi lilY CIÜI'" ....teriail or 1ft .ay ...- __ Ful'Uoor.li_ u.e œntIilØl.... meùIodl or _ 01 1M M'Odud and ialonnoUcla memd to hereill In ..,... 1M _IlOl 01 PIIiI\ipI, PhUlipl ~ dÏldIWl MY ..... .1I1101li'''' . to Oft)' IBU/U coMai..... or .riD", I...... I"Y .... 01 1M ........_ or IUds ¡"I_1Iae. No _ _ beftia IbaII .. GW\IINaI U I ponniaa or ___ûoe few 1M _ 01 lilY produd lis . __ Ulal ai&/l11IIÐiDp aillil\& pala'" HG Tractor Fluid (USOO3471) Pace S oIS ì \ . '. , , ... '. '.-J' t_ ¡ ,~,.. ~. Hay 29, 1992 Material Safety Data Sheet USA and WORLDWIDE SUPER HD II MOTOR OIL (ALL GRADES) PHILLIPS 66 COMPANY A Division of Phillips Petroleua Co.pany Bartlesville, Oklaho.a 74004 PHONE NUMBERS Eaergency' Business Hours (918) 661-3865 After Houra (918) 661-8118 General MSDS Infor.ation' (918) 661-8327 For Additional MSDSs' (918) 661-5952 A. Product Identification Synonyas, Super II, HD II, lOW, lSW-40, 20W-20, 30, 40, 50 i the.ical Haae' Hixture Che.ical Faaily' Hydrocarbon Che.ical For.ula, Hixture CAS Reg. Ho.' Mixture Product Ho.' 63160, 49591, 63260, 63360, 63460, 63560 Product and/or Co.ponents Entered on EPA's TSCA Inventory' YES This product is in U.S. co..erce, and ia listed in the Toxic Substances Control Act (TSCA) Inventory of Che.icals; hence, it '.aybesubject to applicable TSCA provisions and restrictions. ' B. Components Ingred1ent. CAS Huaber x By Wt. OSHA PEL ACGIH TLV This product does not .eet the definition of a hazardous aaterial given in 29 CFR Part 1910.1200(OSHA). Inforaation on this fora i. furnished .a a custo.er service. NA . Not App1icable NE· Not Enablilhcd Super HD II Motor 0i1 (AU Grades) (VS036840) Pqel~5 ~ ",f.' ~ I c. Personal Protection Information Ventilation. Use adequate ventilation to control exposure below reco..ended levels. Respiratory Protection. Hot generally required. For concentrations exceeding the reco..ended exposure level, use HIOSH/HSHA approved air purifying respirator. Eye Protection. Use safety' glasses with side shields. For splash protection use che.ical goggles and face .hield. Skin Protection I Use protective gar.ents to prevent skin contact. NOTE I Personal protection infor.ation shown in Section C is based upon general infor.ation as to nor.al use. and conditions. Where special or unusual uses or conditions exist, it is suggested that the expert assistance of an industrial hygienist or other qualified professional be sought. D. Handling and Storage Precautions Avoid contact with eyes, skin or clothing. Avoid breathing vapors, .ist, fume or dust. Use with adequate ventilation. Wear protective equip.ent and/or gar.ents described in Section C if exposure conditions warrant. Wash thoroughly after handling. Launder . contaainated clothing before reuse. If pressure injected under the .kin, can cause gangrene if not treated. Store in closed containers. Store in well-ventilated area. E. Reactivity Data Stability. Stahle Conditions to Avoid. Not Applicable Inco.patibility OSateriù. to Avoid). Oxygen and .tronsr oxidizinsr agent.. Hazardous Polyaerization. Will Not Occur Condition. to Avoid. Not Applicable Hazardou. Deco.position Product.. Carbon oxide. and various hydrocarbon. for.ed when burned. F. Health Hazard Data Recommended Exposure Limits: OSHA PEL and ACGIH TLV for oil .ist. i. 5 .gl'.3. Super HD II Motor 0i1 (All Grades) (US036840) Pa¡eZors . .. .' . " '1'" '. Acute Effects of Overexposure: Eye. Mild irritation. Skin. Practically non-toxic by skin absorption. Hild irritation with prolonged or repeated contact. Inhalation- None expected. Ingestion. Practically non-toxic. Subchronic and Chronic Effects of Overexposure: No known applicable inforaation. Other Health Effects: Pressurized injection of product under the skin can lead to seriously inflaJlUled tissue. If left untreated injury can be gangrenous. Prolonged and repeated exposure to oil aist pose. a risk of pulaonary disease such as lung inflaaaation. This condition usually causes no syaptoas. Continuous .kin contact with used aotor oil. has caused skin cance~ in laboratory aniaals. Avoid prolonged skin contact with used aotor oil. Health Hazard Categories: Aniaal HUllan Aniaal HUllan Known Carcinogen ___ Suspect Carcinogen ___ Mutagen Teratogen ___ Allergic Sensitize~ ___ Highl,. Toxic Toxic Corrosive Irritant Target Organ Toxin ___ Specif,. - No known applicable inforJIation. First Aid and Emergency Procedures: Eye. Flush eyes with running water. If irritation or adverse .yaptoas develop, seek .edical a~ention. Skin. Wash skin with soap and water. If irritation or adverse .yapto.s deve~op, seek .edical attention. Inhalation. Reaove' froa expoøure.', If: 'nIne.. o~ adverse .,..ptoa. develop, .eek aedical attention. Inge.tion. If illness or adverse .yapto.. develop, seek .edical attention. Note to Physician. For injection injurie., iaaediate aedical treataent is required. Ph,..ician. aa,. call the e.ergencJ' nuaber (918) 661-8118. Super HD II Motor Oil (All Grades) (US036840) Page 3 01'5 j ,.' G. Physical Data Appearance I Colorless to dark liquid Odor I Hild Boiling Point I > 600F (> 316C) Vapor Pressurel < 1 .. Hg ¡ 68F (20C) Vapor Density (Air = 1)1 > 1 Solubility in Water. Negligible Specific Gravity (H20 = 1)1 0.875 - 0.895 ¡ 60F (16C) Percent Volatile by Volu.el Negligible Evaporation Rate ( = 1). Negligible Viscosity I 35 - 241 cs a 104F (40C) H. Fire and Explosion Data Flash Point (Hethod Used) I FlaJUlable Liaits (r. by VolUlle in Air) I Fire Extinguishing Hedial Special Fire Fighting Proceduresl Fire and Explosion Hazardsl > 365F (> 185C)(COC, ASTM D92) LEL - Not Established VEL - Not Established Dry che.ical, fOBa or carbon dioxide (C02). Evacuate area of all unnecessary personnel. Shut off source, if possible. Use NIOSH/HSHA approved self-contained breathing apparatus and other protectiveJ equip.ent and/or gar.ents described in Section C if conditions warrant. Water fog or spray .ay be used to cool exposed containers and equip.ent. Carbon oxides and various hydrocarbons for.ed when burned. I. Spill, Leak and Disposal Procedures Precautions Required if Haterial is Released or Spilledl Wear protective equip.ent and/or garaents described in Section C ~ exposure conditions warrant: Shut off source, if possible ancl__ _ __ _______ ___,__ contain spill. Xeep out of water sources and sewers. Ahsorbin . '. , .-- dry, inert .aterial. Transfer to disposal druas. Waste Disposal (Insure Conforaity with all Applicable Disposal Regulations) I Incinerate or otherwise .anage .t a per.itted waste .anage.ent facilit7. Super HD II Motor Oi1 (All Grades) (US036840) Pa¡e 4 tiS " 0,' "'". . rO' . ... Ij--' .. J. DOT Transportation Shipping Naae. Hazard Clasa. ID Nuaber. Packing Group. Harking. Label. Placard. Hazardous Substance/RQ. Shipping Description. Packaging Referencea. Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable Not Applicable' K. RCRA Classification - Unadulterated Product as a Waste Prior to disposal, consult your Environmental contact to deter.ine if TCLP (Toxicity Characteristic Leaching Procedure, EPA Test Method 1311) is required. Reference 40 CFR Part 261. L. Protection Required for Work on Contaminated Equipment Contact iaaediate supervisor for specific instructions before work is initiated. Wear protective equip.ent and/or garaent. described in Section C if exposure conditions warrant. " .L M. Hazard Classification Thi. product aeeta the following hazard definition(s} .s defined by --- the Occupational Safety and Health Hazard Co..unication Standard (29 CFR Section 1910.1200). Coabustible Liquid Co.pressed Gaa Flaaaahle Gaa ::: Flaaaable Liquid _ Fla_able Solid X Based on inforaation preaently available, this product does - - any of the hazard definitions of 29 CFR Section 1910.1200. Flaa.able Aerosol = Explosive Health Hazard (Section F) = Organic Peroxide ___ Oxidizer _ Pyrophoric _ Unstable _ Water Reactive not aeet N. Additional Comments -.- - SARA 313 .....: ...... -.~..... .. d . _ .. - - - - - .--.- A. of the preparation date, this product did not contain a che.ical or che.ical. subject to the reporting requireaent. of Section 313 of Title III of the Superfund Aaendaent. and Reauthorization Act of 1986 and 40 CFR Part 372. . PlUDIII PevoIoUIII Compen, (""- 10 "'ID", PItroIwm eø.np.", « ",m;¡. lftdudlllC'1 dl¥lllolll. 1fII1"-,- .... IllWlIuia) '-'__ GIlt IIIe IIIfbnMtioft _ 1&1..... _n l,ncludiDt dN .... _I II _Ie .. 01 UNo "'1& MNoI'. NO WAJUtANTY 01' WERCHANTAJlIUTY. F1TNESS FOIt ANY PAJtncuLAJt PURPOSE OR ANY OTKER WAJUtANTY.1!XPRESS OR IWPUED.IS MADE AS CONCEJUIIS THE INFOJUU.nON HEJU!JN PROVIDED. T1IIIIaf~ II'IMCIed MRla NIl.. 11ft" 10 l1ooo ~ Jl"ld1lCS ~1eoI .nd mDJ nøc lie ....... -. IUd! Jl"ld1lCS II __ .. _......... WiUt .'" .... -mall . .. .'" ..- -. Foru... a.... \lie _11_ aM ~ 01_ 01 tile pooducs.... 18'___ .._ 10 __.... ..,..... 1M -.IlOl 01.....11... PIIIDIpo -" ÜdaI.. ...., .... .lIliallilirJ . to ...., .-1\1 '*-'- .....81 "- ...., - 01 1M Pf'Od- ,...œ W~ No..-.. ..... __ IlIaD .. __ . .......~ . ~ ,,. 1M _ 01 atIJ poodllCS" . _IUI aIpt lani... ~DI"-II. Super HD II Motor Oil (AD Grades) (US036840) Page 5 0(5 " 1: '¡ , . ì '. MATERIAL SAFETY DATA SHEET Lubricating Speclaltlea Company Lie Dear Customer, You are probably aware of recent developments regarding worker "Right-to-Know" laws and the OSHA Hazard Communication Standard. While these laws and the OSHA Standard have numerous requirements, the development of a Material Safety Data Sheet and its dissemination to the purchaser of the chemical product are among the principal means of achieving an effective hazard communication program and of satisf- ying the "Right-to-Know" need. For the MSDS to serve its purpose as an effective means of hazard communication, the information contained therein must be passed along to all those who handle or use the product and/or are ,involved with thedesign, implemen- tation of control of operations involving the product. We stronglY urge you to forward the MSDS to all parties who have a need for the information contained therein. "EMPTY" CONTAINER WARNING "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. All precautions detailed on the container label applies to partially full or "Empty" containers. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly closed and promptly returned to a drum reconditioner to be commercially cleaned. All other containers should be disposed of in an environmentally safe manner and in accord.ance with governmental regulations. For work on tanks refer to Occupa- tional Safety and Health Administration regulations, ANSI Z49.1, and other governmen- tal and industrial references pertaining to cleaning, repairing, welding, or other con- templated operations. . When a Lubricating Specialties Company product is resold in the original container with an original label, the: reseller has the responsibility for ensuring that the proper Material Safety Data Sheet is provided to its purchaser. Although the information and recommendations set forth herein (hereinafter "Informa- tion") are presented in good faith and believed to be correct as of the date hereof, Lubricating Specialties Company makes no representations as to the completeness or accuracy thereof. Information is supplied upon the condition that the persons receiving same will make their own determination as to its safety and suitability for their purposes prior to use. In no event will Lubricating Specialties Company be responsible for damages of any nature whatsoever resulting from the use or reliance upon information. , NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH THE INFORMATION REFERS. (This MSDS complies with 29CFR 1910.1200) L~bi1catlng Specialties Company 8015 Paramount Blvd, Pica Rivera, CA 90660-4888 Telephone (213) 928-3311 CHEMTREC 24 HR. EMERGENCY NO. 1-800-424-9300 :5:' ~ :J> :M: ,:;2 r-- 1~ c:::J ~ r- c-:> c: c: r7 --f -a ::2. =-a 0 c= ,., ~ :::::c ::x 5' rr1 Ie ,., en t::) ~ OJ :::IIC 0 c:::a ~ -< --t iD ~ III r- ~ 0 c= 0 c::c ~ 3 '0 :::::c I-f III - r-- ::2 CJ '< ~ Con ::I::) - 1""'"1 :;2 Cï:> ' .. ¡ ~ en -0 ::I::) ïT"1 -a S2! I-f :t::- ' ~ I I ,..., ....... - ~ rr1 en c:-:a c-;) c::> as: :r'd ~ ~t""":- =- -- -,.., ,., ~ a::J ~ c".,:a c.a ~ X m ~ ~ ~ -i i~: _ i ~ _ m o -i m ::D o m ~ > o 0 Z -i - ;: ~ =i " -c ~ ci)8 a::(") ::J~ ,...o~ ~:I:~ (").0 'NO CD CD s:~ö ......zw ~wa:: NCI~ ':':'a::~ ~ww <~:I: OwO MATERIAL SAFETY DATA SHEET (Essentially similar to Form OSHA-20) <Complies with 29CFR 1910,1200> .,'a;emÎc~t)l11 CODENUMBE~ 82392' TRADE NAME: XLD SUPREnE. nOT OR 01 L SAE +0 API CHEMICAL FAMILY: PETROL£Un CARCINOGENIC INGREDIEITS/OSHA/NTP/IARC: lONE DATE 89"19 CE/SG SUPER CEDES 890117 C.A.S. NO.: ''ftIXTURE'' TSCA INFORMATION: lOT CURREllTLY LISTED COMPONENTS c"c,]\Jj;gJgÎÅm'.',. TLV/PEL PERCENT BY PPM mg/m3, WEIGHTIVOLUME SOlU REF BASE STOCK SOlU REF RESIDUAl OIL 5 5 00 U (20 U 6''''2-5+- , "''''H1-i TO AFfECT HAZARDOUS THERMAL DECOMPOSITION CARBOIIIIOIIOXIDE AID ASPHYXIANTS FLAMMABLE LIMITS: LEL - UEL NIO ASTII D92 (COC) <..nO f) EXTINGUISHING MEDIA: eawœ oloxlœ. DRY CHEltICtL FOM. IlATERFOG FLASH POINT: >225 0 C DOT INFORMATION: OIL, H.O.S. UNUSUAL FIRE AND EXPLOSION HAZARDS: SlIGHTlY CtIIBUSTIBLE. lID HEATED MOUE FlASH POINT lULL RELEASE FLAlNBLE WiltS IIUCH CAtI BURl III tfEl OR BE EXPlOSI\( III COWIE SPACES IF EXPOS£D TO SOURCE OF IGNITIOII. SPECIAL FIRE FIGHTING PROCEDURES: DO lOT EIITER MY EIClOSED OR COIfIIED AREA IUTHOUT PROPER PROTECTIUE EGUIPlBT AND SELF COITAIIIED BREATHltIe APPARATUS . >3250 C NEGLIGIBlE PH: IIID VAPOR PRESSURE: <0.01løt lit I: 20 0 C VAPOR DENSITY EVAPORATION RATE APPEARANCE AND ODOR: BROUI. OILY LIQUID PETRCUUII OOIXl WEIGHT % VOLATILE PER GALLON BY VOLUME SPECIFIC GRAVITY HEAUIER THAN AIR LESS THAN ETHER 0.893 ,.... NIL INCOMPATIBILITY <MATERIALS TO AVOID>: ST_ OXIDIZIIC AGEtlTS STABILITY: CONDITIONS TO AVOID: STABlE HAZARDOUS DECOMPOSITION PRODUCTS: CARØOII MIIOX1ÐE AlII) ASPHYXIANTS DO NOT HEAT ABOUE FlASH POINT HAZARDOUS POLYMERIZATION OCCUPATIONAL EXPOSURE LInIT TLU = 5mg/m3 AS OIL MIST lONE . ,- iR :0 U T E o F EC YO EN E X P A SC o CK 0 UIN S TN U E R csc E HKO RIN ON N I C """/'~r\'K" ,:-",::~(",:,<,::<.~:º,:~:.:t . ¡ 3:( :J> NFPA :z c=. :Þ: c-> --f c:= ::::0 rrI c:a CJj -< r- c:= CD ;::0 - CJ :X:=¡~ - ,.., ~ c;-:> . ~ ! ~ u:> -0 ::a ïT'"1 -a ~f-o-ot :J> ' c-:J I I ,..., - '- ~ c.n C/:) c:-:Þ š¡¡[lgÎ~,¡eâ~~gQ~âg$·~eR~7J>./··,'",·,·,··, 2 :š: ~ ::x:s- ~ , '.",·,SECŒIQN/MI~.,ME'Ä~ðiM;:.·M~Z~BÐ.Ð,ÄT"", ,,',Ä"','·, . ," '- ..; "-,.-.,- ...;,.,.'_....',,".. '.. -,...,..,.....,.:-:..,:',".:...,_.,..-..,.",.,,-,-.--' .,....,;.-'.....::."-,-'.:...,.:."....,.,..:.....,:..--'.'-.' '.-.........,-.....,-,.:.,.. ;',..-,"',' I N G ADVERSE EFFECTS: (oT NORIIIUY EXPECTED TO CAUSE AWl III EFFECTS EXC9T III UERY SÐfSITIUE IIIDIUIDtMLS FIRST AID PROCEDURES: DO lOT IIIUCE UOIUTIMG. CORSULT PHYSICIAII I N H 110 SIGlUFICttIIT ADUERS£ HEALTH EFFECTS ARE EXPECTED TO OCCUR ON SHORT TERtt EXPOSURE IIOT IIORtIAU. Y EXPECTED TO CAUSE All\' III EFFECTS EXCEPT III UERY SENSlTlUE IIIDIUIDUM.S lOT IIORItAl1. Y EXPECTED TO CAUSE AllY III EFFECTS EXCEPT III UERY SENSITIUE IIDIUIDUAlS PRa.lllCED MO/OR REPEATED cotITACT nAY PRODœE nILD SKIll IRRITATIØI AlII IIRAn- nATION. PERSOIIIElIIITH PRE-EXISTIIIC SIll DISÐRÐER RBIOUE FROII COHTAnIIlATED AREA. APPlY ARTIFICIAl RESPIRflTIOR. IF UMCOIICIOUS COIISUl T PHYSICIM flUSH &11TH COPIOUS AftOUITS OF &lATER. IF IRRITATIOII DEUElOPES COHSUL T PHYSICIAN IItISH InTH SOAP AND !lATER. COMSUlT PHYSICIAII IF IRRITATIOII OR IIIFLMllATIOII OEUELOPES . lOR PROTECTIUE ClOTHIIG TO MID SIll CORTACT. COISUlT PHYSICIAN IF IRRITATION OR IIIFlAMATION OEUElOPES . STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: STOP FLOU. !lIPE OR IIIP II' OR ABSORB !lITH DIATOIlAtEOOS EARTH OR 011lER INERT rtATERIRl. STORE III APPROPRIATE COIITAIIIR flit DISPOSM. . WASTE DISPOSAL METHOD: II( ACCORIIAIU !11TH lOCAL. STATE AIQ) fEŒRIU. REGUlATIOItS. TRANSPORTATION INFORMATION: COtlStU ., CFR PARTS 1-300 AID REÆR TO SECTIotI III OF THIS nsos FOR MlDITIOR RECCØlDATIOIS I ¡.,.'.....·,.....'",i¡Sê~mjâr··' :::;:j~,N';;¡:'.N~·~J¡.t,M~m'ø' , RESPIRATORY PROTECTION: _ IIORIW.l.Y REQUIRED PROTECTIVE GLOVES: RECCOIIIEJIDED EYE PROTECTION: REQUIRED , OTHER PROTECTIVE EQUIPMENT: CHEltICALlY RESISTfIIIT BOOTS MD tIROIIS RECC01IÆJßIED. 'VENTILATION: StfFICIEJO' TO nAINTAIN ATJl)SpÆRE BRill flU lIlIIT :PRECAUTIONS TO BE TAKEN WHEN HANDLING OR STORING: AUOID STORAGE NEAR OPEN FL.AItE OR 0T1£R SOURCES OF IGIIITIOI. EXCESSIUE "ISTlIIe 11M' CAUSE SLIPPERY flOORS. PROPER FOOTIEAR REQUIRED. ¡PERSONAL HYGIENE: IIASH IWI)S !11TH SOAP AND !lATER BEFORE EATING, DR UIC1 NG, OR 5111*11'. OTHER PRECAUTIONS: IIASH OR TAKE SH1IŒR IF GENERAl. ,CONTACT OCCURS. REnOOE DIl- SOAKED a.OTHIIIC All) lMJIŒR BEFORE REUSE. DISCARD COIITAIIIMATED LEATHER GLOUES AltO SI«tES. ~PPROVED BY: tICHRRD J. EBERHRRDT DA TE: 8?O61' lABORATORY ftAhAC£R >C r- c::::I c.n c::: -a =-a ,.., :x ....., ~ r- c 0' ~. o ~ :ï IQ (J :x~ c:::)! ~ ii' ~ 0 o c:::) 3 t-ti r-~ ='" ~ =- =- .... -,.., ,.., ,. c::J:J ~ c".,:) CD '" :I: m "U ~ ~ -. ~~. : - ~ :II -= m o -. m :II o m :j )0- o 0 Z -i Z 5 ." -i "U -< ~ , .. i' . DEFINITIONS ACGIH: American Conference of Governmen.tallndustrial Hygienists DOT: LC50: LD50: LEL: " .. Department of Transportation :~. Lethal Concentration Fifty: A calculated concentration of a substance which is expected to cause death of 50% of an entire defined experimental animal population. ," ., ~" ~: ,; . . . .. .' . ...... Lethal Dose Fifty: A calculateá doséofa substance expected to cause deatD.' of 50% of an experimental animalpopùlatibn.· " ~ ~ ~.~ :-. . Lower Explosive limit '. Fire ~~alt~.. ..~.... ~eactlvlty Personal PrÇ>tec~ion , .. Hazard Category Scheme: This scheme rates health, fire, reactivity' and speciar ", hazards on a scale 6f 0 to- 4. , 1x~r, PEL: N/A: N/D: NFPA: T¡lV: o = no significant hazard' 1 = slight hazard 2 = moderate hazard 3 = high h~iârd 4 = extreme håzard. ·0 " D .' E F G ¡ H I J K X ,!,., . 0.. .' Permissible Exposure limit Not Applicable .... "' PERSONAL PROTECTION INDEX , ' A'-;"~~- : B " "W+lli&r ~+:.+ ¡f [Y+ ~+ ¡f ,~,+...+~ ~+..+ ¡f+~ ~+..+* ~+..+~+~ ~+..+~ -C'"+" + if + '* Q +:..<+ t + L Ask your,supervisor for specialized handling directions TWA: Time Weighted Average ~ e¡ êY Q .. .,' -, S.'." SD'"'' Fue AlrUne Hood 010... Gle.... GogO'" I"\e\d Dr "nk ING: Ingestion ;¡f ~ ~ "" .~ INH: Inhalation .,nlh.hc OUI' Vapo, CO"'bl".tion Dul' : .,..-?~.- . '1; A.ron ".,pi.t.tOt ".&oir.'Of & VaOOf "-.o,,.to, J' CiON: Contact 1t Full P.ol.eli.. Lao... Sull Not Determined National Fire Protection Association .. -- . Threshold Limit Value. A recommended upper limit or TWA concentration of a substance to which' mosfworkerscan' be exposed without adverse effect. . ' ";. , ~ " ,:if:: :', .. Lie . , . .. LubrtcaUng SpeclalUes Company 8015 Paramount Blvd. Pico Rivera. CA 90660-4888 Telephone (213) 928-3311 72-62-'1825'-11 " JIa/vo/ine. V ,...,.L. \I VI-!l,...., "\Iv. Sub!tidiary of Ashhmd Oil, !fI'::. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (6061 264-ìOOO Emergency Telephone 1 (8001 274-5263 or 1-800-ASHlAND 'i' i ( MATERIAL S.AFETY DATA SHEET ~"1277 IG-LO STR FLD P THIS MSDS COMPLIES HITH 29 CFR 1910.1200 (THE HAZARD COMMUNICATION STANDARD) *******MKKMKKKKKKKKKXKKKXXXXXK~XKX..X.KXXXXK.KKXXXKKXXXXXXXXXXX.X.XXX.X.XXXXY.K.XkKX..'XXXXX.******~XKXXXXX.XX Page: 1 Product Name: IG-LO STR FLD P 08 70 000 8735QOO-000 Data Sleet No: 0177783-004.000 P~epared: 07/19/89 Supersedes: 07/06/88 SERVICE OIL COMPANY C H BARKSDALE 107 LAKE STREET BAKERSFIELD CA 93305 ATTN: PLANT HGR / SAFETY DIR. PRODUCT: 80011016 INVOICE: 34&091 INVOICE DATE: 07/07/92 TO: . ;¡S¡'t"'~~' --;-,. , ' ',' . . ~ECTir-ON ..':û--..PRDDUCT ;.;ã;DE-NT.1:F;I£ATl:DN - !" " .' , ,;' ..: .,",. ' General or Generic ID: SOLVENT BLEND DOT Hazard Classification: FLAMMABLE GAS 1173.300) .';~."'~"":", -" "c '" ,"a1iSEC:T:ION:àIiI-':COMPßNE-NT.S." ", '.'.-....;,-,',,'.-"'>:-;:,; THE COMPOSITION OF THIS PRODUCT IS BEING HITHHELD AS A TRADE SECRET. IF PRESENT, IARC, NTP AND OSHA CARCINOGENS AND CHEMICALS SUBJECT TO THE REPORT- ING REQUIREMENTS OF SARA TITLE III SECTION 313 ARE IDENTIFIED IN THIS SECTION. SEe DEFINITION PAGE FOR CLARIFICATION % Ibv HT) PEL 1-10 10000 PPM INGREDIENT CARBON DIOXIDE CAS I: 124-38-9 flV 5000 PPM Note 1) HEPTANE 55-70 400 PPM 400 ppM CAS .: 142-82-5 ETHYL ETHER 25-40 400 PPM 400 PPM CAS .: 60-29-7 HEXANE 1-10 50 PPM 50 PPM CAS .: 110-54-3 iteS: ---. 1 2) 1 3) I 1) PEL NOT ESTABLISHED FOR THIS MATERIAL ACGIH/OSHA SHORT TERM EXPOSURE LIMIT ISTEL) FOR CARBON DIOXIDE IS 30,000 PPM. '2) OSHA/ACGIH SHORT TERM EXPOSURE LIMIT ISTEL) FOR N-HEPTANE IS 500 PPM. NIOSH RECOMMENDS A LIMIT OF 85 PPH - 8 HOUR THA, 440 PPM - CEILING. I '3) NIOSH RECOMMENDS A LIMIT OF 100 PPM - 8 HOUR TIME HEIGHTED AVERAGE, 510 PPM CEILING. THESE LIMITS ARE FOR N-HEXANE. THE OSHA PEL AND THE ACGIH TLV FOR OTHER ISOMERS OF HEXANE IS 500 PPM, THA; 1000 PPM SHORT TERM EXPOSURE LIMIT ISTEL). Bo'iling Point for COMPONENTI 'J:;;.;-?.-l.,........, ,:" ~!SECTuJ)N ""If.I:Œ.-,'PHVS1-CAL JDAT.A .' . ,- ' ~:,-,~,:;'---" 25-40% ) 94.00 Deg F 1 34.44 Deg C) ~ 7&0.00 mm Hg 439.00 mm Hg ~ 68.00 Deg F ( 20.00 Deg C) HEAVIER THAN AIR LESS THAN HATER 100.00% SLOWER THAN ETHER COMP GAS Vaþor Pressure for COMPONENT 1 2,5-40%) Specific Vapor Density Specific Gravity Percent Volatiles Evaporation Rate state ~¡o)¡,:¡.¡", ~.'.- ;'. ,': ,-SECTION -"IN-F.ù:RE·-'IM-NDi1fE>XRüDS1DN ...g:~EORMA T10N ' ""'" ><.. .",...:':,';.:i--~~ FLASH POINT'TC ) < -58.0 Deg F -50.0 Deg C) EXPLOSIVE LIMIT (LOHEST VALUE Of COMPONENT) LOHER - 1.0% EXTINGUISHING MEDIA: REGULAR FOAM OR CARBON DIOXIDE OR DRY CHEMICAL HAZARDOUS DECOMPOSITION PRODUCTS: MAY FORM TOXIC MATERIALS:, CARBON DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC. FIREFIGHTING PROCEDURES: HEAR SELF-CONTAINED BREATHING APPARATUS HITH A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE HHEN fIGHTING FIRES. 'ECIAL FIRE & EXPLOSION HAZARDS: NEVER USE HELDING OR CUTTING TORCH ON OR NEAR DRUM IEVEN EMPTY) BECAUSE . PRODUCT 1 EVEN ~UST RESIDUE I CAN IGNITE EXPLOSIVELY. CONTINUED ON PAGE: 2 ? 72-62-7825-11 I.., MATERIAL SAFETY L DATA SHEET "Â#' J{]/yoline VALVULII\1t::,II"l". SulJliidiary cof Ashland Oil, Inc. P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 (606) 264·7000 -... .,-... Emergency Telephone 1 (800) 274·5263 or 1-800-ASI-iLAND ~"'1277 IG-LO STR FLD..P Page: 2 , .' ,-' .- <~ECT;.I.ON ~IN"':;'F,¡r;RE ~'ND.BXP.UOS1..oN,;!I¡NFiORMATd·.oN~>Con±álßued")'~, ", --, """,''', Y'- r:¡FPA CODES: HEALTH- 1 FLAHt1ABILITY- 4 REACTIVITY - 0 ,',..-' ,'.,' .. ,: l . .··..c'^·,.¡~E-c~J:'ON¿N~tlE~L"T.-H'ltHAZiARD:.iÌDA.;r.A·',,'~·.,,"',':~n."^"'~-': '"f.," ,...~':.,.< ~. PERMISSIBLE EXPOSURE LEVEL: SEE SECTION II EFFECTS OF ACUTE OVEREXPOSURE: SKIN - PROLONGED OR REPEATED CONTACT MAY CAUSE MODERATE IRRITATION, DEFATTING, DERMATITIS. ~~fLÕH~~~ ~A~~~ ~~~~EGI~~ãò~~~~tI~~~N~~~ÌTI~~~~N~Á~~~~R~8M¥f¥~~'AND DIARRHEA. ASPIRATION OF MATERIAL INTO THE LUNGS MAY CAUSE CHEMICAL PNEUMONIA HHICH HAY BE FATAL. BREATHING - EXCESSIVE INHALATION OF VAPORS MAY CAUSE NASAL AND RESPIRATORY IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS INCLUDING DIZZINES, HEAKNESS, FATIGUE, NAUSEA, HEADACHE AND POSSIBLE UNCONSCIOUSNESS AND EVEN ASPHYXIATION. FIRST AID: H ON SKIN: THOROUGHLY HASH EXPOSED AREA HITH SOAP AND HATER. REMOVE CONTAMINATED CLOTHING. LAUNDER COtfrAMINATED CLOTHING BEFORE RE-USE. IF IN EYES: FLUSH HITH LARGE AMOUNTS OF HATER, LIFTING UPPER AND LOWER LIDS OCCASIONALLY, GET MEDICAL ATTENTION. IF SWALLOWED: DO NOT INDUCE VOMITING, KEEP PERSON HARM, QUIET, AND GET MEDICAL ATTENTION. ASPIRATION OF MATERIAL INTO THE LUNGS DUE TO VOMITING CAN CAUSE CHEMICAL PNEUMONITIS HHICH CAN BE FATAL. IF BREATHED: IF AFFECTED, REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. IF . BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. KEEP PERSON HARM, QUIET AND GET MEDICAL ATTENTION. PRIMARY ROUTEISI OF ENTRY: INHALATION, SKIN CONTACT EFFECTS OF CHRONIC OVEREXPOSURE: PROLONGED AND REPEATED INHALATION OF HIGH LEVELS OF MIXED ISOMERS OF HEXANE RESULTED IN KIDNEY DAMAGE IN MALE RATS. THE EFFECTS OBSERVED ARE THE SAME AS THOSE SEEN IN MALE RATS EXPOSED TO OTHER HYDROCARBONS. THE MECHANISM BY HHICH THESE CHEMICALS CAUSE THE CHARACTERISTIC KIDNEY TOXICITY IS UNIQUE TO THE MALE RAT AND THE KIDNEY EFFECTS ARE NOT EXPECTED TO OCCUR IN MAN. ". ..,' "," -' "'iSE:Cif.T.DN· NI-·R-EöACT.I:V.IT-Y .iDAToA "'. '. '. ."" ",'" -. , ~ HAZARDOUS POLYMERIZATION: CANNOT OCCUR \BILITY: STABLE ~NCOMPATIBILITY: AVOID CONTACT HITH:, STRONG OXIDIZING AGENTS , ' ,- _'-''1ISEOTü(ON ..v.l1-:?SP.r1:L:~OR _lÆAK <P.ROCEDURES, K, ,,'. ,":- .-, . :- STEPS TO B~ TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: SMALL SPILL: ALLaH TO EVAPORATE. VENTILATE AREA. ELIMINATE ALL SOURCES OF IGNITION SUCH AS FLARES, FLAMES (INCLUDING PILOT LIGHTS), AND ELECTRICAL SPARKS. L~RGE SPILL: ELIMINATE ALL IGNITION SOURCES IFLARES, FLAMES, INCLUDING PILOT LIGHTS,ELECTRICAL SPARKSI. ALLOH TO EVAPORATE. PERSONS NOT HEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA UNTIL LEAK HAS BEEN REPAIRED. HASTE DISPOSAL METHOD: SMALL SPILL: ALLOW MATERIAL TO EVAPORATE. L~RGE SPILL: VENTILATE AREA OF SPILL. ALLON MATERIAL TO EVAPORATE. , '''!SE.CTII'ON ~V.'IJù:-..p,ROTECT.J:-VE ·;jEQUJ:·PMENT- mo :.tBE.-iWUSED· '.'",'. ....,' ,," " . j RESPIRATORY PROTECTION: IF HORKPLACE EXPOSURE LIMITISI OF PRODUCT OR ANY COMPONENT IS EXCEEDED (SEE SECTION III, A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/HSHA RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS ISEE YOUR SAFETY EQUIPMENT SUPPLIER). ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE. VENTILATION: PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELON nVISJ. PROTECTIVE GLOVES: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE EYE PROTECTION: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. OrHER PROTECTIVE EQUIPMENT: NOT REQUIRED UNDER NORMAL CONDITIONS OF USE. , ~E.OTa::ON'giX.;.;1..sp.E-œ1AL -1PRECAUT.IONS ',¡OR ~OT+ŒR~MMEN;r¡S ".:"" " .. -- . "_:' CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS HHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES IVAPOR. LIQUID. AND/OR SOLIDI. ALL HAZARD PRECAUTIONS GIVEN IN THIS DATASHEET MUST BE OBSERVED. .~ INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT HARRANTED TO BE HHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT, APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. LAST PAGE--SEE ATTACHMENT PAGE ENCLOSED--LAST PAGE I ~Àf' Vö/JllÚl!e 72-02-7325-11 MATEBIAI. SAFETY DATA SHEET ~ V 1-'\.... V -..I....." L., I' ~ '-'. SubSldiarv nf Asþland Oil, Ine, P.O. BOX 14000 LEXINGTON, KENTUCKY 40512 i6061 264-7000 Emergency Telephone 1 (800) 274-5263 or 1-800-ASHLAND DEFINITIONS This definition page is intended for use with Material Safety Data Sheets supplied by the Valvoline Oil Company, Recipients of these data sheets should consult the OSHA Safety and Health Standards (29 CFR 1910). particularly subpart G - Occupational Health and Environmental Control. and subpart I - Penonal Protective Equipment, for general guidance on control of potential Occupational Health and Safety Hazards, SECTION I PRODUCT IDENTIFICATION GENERAL OR GENERIC ID: Chemical family or product description. DOT HAZARD CLASSIFICATION: Product meets DOT criteria for hazards listed. SECTION II COMPONENTS Components are listed in this section if they present a physical or health hazard and are present at or above 1 % in the mixture. If a component is identified as a CARCINOGEN by NTP. IARC or OSHA as of the date on the MSDS. it will be listed and footnoted in this section when present at or above 0.1 % in the product. Nega. tive conclusions concerning carcinogenicity are not re- ported. Additional health information may be found in Section V. Components subject to the reporting re- guirements of Section 313 of SARA Title III are Identi- hed in the footnotes in this section, along with ty.pical percentages. Other components may be listed If deemed appropriate. Exposure recommendations are for components. OSHA Permissible Exposure Limits (PELsl and American Con- ference of Governmental Industria Hygienists (ACGIH) Threshold Limit Values (TLVs) appear on the line with the componenl identification. Other recommendations appear as footnotes, SECTION III PHYSICAL DATA BOILING POINT: Of product if known. The lowest value of the components is listed for mixtures. VAPOR PRESSURE: Of product if known. The highest value of the components is listed for mixtures. SPECIFIC VAPOR DENSITY: Compared to AIR ... 1. If Specific Vapor Density of product is not known, the value is expressed as lighter or heavier than air. SPECIFIC GRAVITY: Compared to WATER - 1. If Specific Gravity of product is not known, the value is expressed as less than or greater than water. pH: If applicable. PERCENT VOLATILES: Percentage of material with ini- tial boiling point below 425 degrees Fahrenheit and vapor pressure above O.1mm Hg at 68 F. EVAPORATION RATE: Indicated as faster or slower than ETHYL ETHER, unless otherwise stated. SECTION IV FIRE AND EXPLOSION DATA FLASH POINT: Method identified. EXPLOSION LIMITS: For product if known. The lowest value of the components is listed for mixtures. HAZARDOUS DECOMPOSITION PRODUCTS: Known or expected hazardous products resulting from heat- ing, burning or other reactions. EXTINGUISHING MEDIA: Following National Fire Protection Association criteria. SECTION IV (cont.) FIREFICHTINC PROCEDURES: Minimum equipment to protect firefighters from toxic products of vaporiza- tion, combustion or decomposition in fire situations. Other firefighting hazards may also be indicated. SPECIAL FIRE AND EXPLOSION HAZARDS: States hazards not covered by other sections. NFPA CODES: Hazard ratings assigned by the National Fire Protection Association. SECTION V HEALTH HAZARD DATA PERMISSIBLE EXPOSURE LIMIT: For product. THRESHOLD LIMIT VALUE: For product. EFFECTS OF ACUTE OVEREXPOSURE: Potential local and systemic effects due to single or short term overexposure to the eyes and sl<in or through in- halation or ingestion. EFFECTS OF CHRONIC OVEREXPOSURE: Potential local and systemic effects due to repeated or long term overexposure to the eyes and skin or through inhalation or ingestion. FIRST AID: Procedures to be followed when dealing with accidental overexposure. PRIMARY ROUTE OF ENTRY: Based on properties and expected use, SECTION VI REACTIVITY DATA HAZARDOUS POLYMERIZATION: Conditions to avoid to prevent hazardous polymerization resulting in a large release of energy. STABILITY: Conditions to avoid to prevent hazardous or violent decomposition, INCOMPATIBILITY: Materials and conditions to avoid to prevent hazardous reactions. SECTION VII SPILL OR LEAK PROCEDURES Reasonable precautions to be taken and methods of containment. clean-up and disposal. Consult federal, state and local regulations for accepted procedures and any reporting or notification requirements. SECTION VIII PROTECTIVE EQUIPMENT TO BE USED Protective equipment which may be needed when han- dling the product. SECTION IX SPECIAL PRECAUTIONS OR OTHER COMMENTS Covers any relevant points not previously mentioned, SECTION X LABEL INFORMATION Contains label information including physical and health hazard warnings, handling and first aid instructions appropriate for the product. ADDITIONAL COMMENTS Containers should be ,either reconditiqned by. CERTIFIED firms or prqperly disposed of by APPROVED firms. Disposal of c~ntalners should be, In accordance with applicable laws and regulations, "EMPTY" drums should not be given to indi- viduals. Serious accidents have resulted from the misuse of "EMPTIED' containers (drums, pails, etc.). ~efer to Sect- Ions IV and IX, . I. - \ ../ MATERIAL SAF~TXsT I DATA SHEET V I""\L.V "".....\lL.., . ,,,""", " Sub!:idiary of Ashland 0;;, Inc, .. P.O. BO.X 14000 AGlI{,hafœ ATTACHMEtijtIN,~) ~~B~B~ZLAST Emergency J Telephone ~ J~) 274-5253 or 1~-ASHLAND ;0 , d ,}:,.,!" ,~ IJ F BOC GASES MA TERIAL SAFETY DA TA SHEET 1. Chemical Product and Company Identification DOC Ga,es. A Division of The BOC Group. Ine 575 Mountain Avenue Murray Hill, NJ 07974 DOC Gases, A Dh'hlion of ßOC Canada Ltd. 89 Queensw;IY 'Vest Mississauga" Ontario LSD 2V2 TELEPHONE NUMBER: (908)464-8100 24-HOUR EMER.(~ENCY 'fF..Lf~N{ONE MJl\nlEl~~ CHEMTREC (800)424-9300 TELEPHONE NUMBER: (905)273-7700 24·HOllR EMERGENCY TELEPHONE NUMBE·R: (905)949-31'17 EMERGENCY RESPONSE PLAN NO: 20101 PRODUCT NAME: OX.....GEN CHEMICAL NAJ\.'IE: OXY1],en COMMON NAMES/SVNONYMS: None TDG CLASSJFJCA1'JON: 2.2 (5.]) w:aMIS CLASSIFICATION: A, C PREPARED BY: Loss Control (908)464-8100/(905)273-7700 PREPARATION DATE: 04/04/98 REVIEW DATES: 04/04198 LA TEST REVISION DA TJ!;: 04/04/98 PREVIOUS REVISION DATE: None 2. Composition, Information on Ingredients Oxygen FORMULA: 02 CAS: 7ì82-44-7 RTECS #: RS2000000 A~ stated in 29 ÇFR 1910, Subpart 7: (lcvi~ed .July 1, 1993) 2 AS stilted in the ACGiH 1994-95 Thrc~hoJd Limit Values ti>r Chemical Sub5tllncC5 IInù fhysiclI! Agen!!; 99,6 to 100,0 Not AvaJlabJe 3. Hazards Identification , ,,'..' ",'. '.,',', ,EMERGENCYOVERVIEW, '.,' ", , " ' Élev~tëp:ÖXYSM lË:!vel~ ri:ïä.Yre$ÜltÎn~ cOyghanq :Þ~h~(p:ulriiPtl~tyé.;'~t1g~$ ,f1¡gþ cônc:ßntfations,Þf oxygeä.(greâtef"than':75%}êaÜses:symþìOmsoffiype'tÞx;iawhich.'ìilct:Jdèd.:cramps,'.naÜseá ,diZziness' ;~:~~1{i~,~::)fJl~:y::ìpp~a~,i~~~,~~r~F~...~iff,f~4Ir~, ~;:,#t~d.}i~r,~'~. ,,:.,:f~¡rit¡~~.,5Þ;~(¡~;.~g~I:,;~mY:~~~~.~iça~~~I,~ ,¿f." i:f 19', þd~:ø: ti.,mO\? arli!m~ ,,' PL dzet) "llIaÇC~,I", a,~e,corn~,Q,.t(ort ,.'"" , ""p" ",.",.,""" "'" ,." ,".", ",' '" nOUTE OF 'ENTRY: Skin Contact No Skin Absorption No Eye Contact -¡- Inha1ation No ¡ Yes T 1ng~~i()n I MSDS: G-1 Revised: 04/04/98 Page I ~d WdS0:v0 000G 90 'AQN ~0Ø6 v£9 S08 'ON 3NOHc 3l~G3S0~ 0S~S 9NIGl3M S3N~~6 WO~~ ~ 'r.,-. ",. ':f'(i'.i¡;'¡''!r!''¡¡,~I¡I(.v.~¡¡1~'""",''''''';¡''''' ;:!tgQJ,;Ìl,,~,\i?\~!::t~I.V"'./";~Ä:r:;~ HEALTH EFFECTS: Exposure Limit,¡; No TeralOgen No Synertistic Effect$ None known Irritant No Reproductive Hazard No Ee~sitiza, tion No Mutagen Yes -- --.--- Carcinogenicity: -- NTP: No !ARC: No OSHA: No EYE EFFECTS: ConÙl.ct with liquid product may cause tissue freezing. SKIN EFFECTS: Contact with Hquid product may cause tissue ftee~ing, INGESTION EFFECTS: Contact with liquid product may cause tissue fh:ezing. INHALATION EFFECTS: High concentrations of oxygen (greater than 75%) causes symptoms ofh/pcroxia which included cramps, nausea, dizziness, hypothermia, arnbylopia, respinltion difficulties, bradycardia, tàinting spells and convulsions capablc ofIeadîng to death. The property is that of hype roxi a which leads to pneumonia. Concentrations between 25 and 7$% present a risk of inflammation of organic matter in ¡he body. Oxyge,n concentrations between 20 to 95% have produced genetic change:s Îl1 manunalian cell assay test systems. NFPA HAZARD CODES HMIS HAZAU» COOES ltA 'ftNGS SYSTEM Health: 0 Flammability: 0 Reactivity: 0 Health: 0 FJarnmabihty: 0 Rr;:activity: 0 o = No Hazard I ,,. Slighl Hazard 2 "~ Moderate Hazard 3 = Se.riO\.!8 Hazard 4 .: Sc,'cn; Ha;¿ard 4. First Aid Measures EYES: Never introduce oinnnent or oil into the eyes without medical advice! In casÇ offree~il1g or cryogenic "bums" caused by rapidly evaporating Jiquid, DO NOT WASH THE EYES WITH HOT OR EVEN TEPID WATER! Remove victim fi:om the source of contamination. Open eyelids wide to-.Uow Jiquid to evaporate. If pain is present, refer the victim to an ophthalmologist for treatment and follow up. If tbe victim tannot tolerate light, protect the eyes with a light bandage. MSDS: O· I Re\'ised: 04/(}4/98 Page :1 cd WdS0:Þ0 000c 90 'AoN 1006 Þ£9 S0S . 01'-1 3NOHc 3l~a3S0~ 0SrS ÐNIOl3M S3N~~8 WO~~ r \ ~ ·1 SKIN: For dermal contact or frostbite: Remove contaminated clothing and flush affec.ted areas with lukewarm water. DO NOT OSE HOT WATER. A physician should scc the patient promptly if the cryogenic "bwn" has resulted in blistering of the dc:nnal surface Or deep ti~~;ue freezing. INGESTION: A physician should see the patient promptly if the cryogenic "bum" has rl~sulted in blistering of the dermal sU1'face 01' deep tissue fteez;ing. INHALATION: PROMPT MEDICAL A TTBNTION IS MANDATORY XN ALL CAS.t~¡ Of OVJ:,RßXPOSUR8 TO OXYGEN. RESCú"E PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTATNEDBREATHING APPARATUS. Conscious persons should be assisted to an lU1contaminal:cd area éU1d inhale fresh air. Quick rt."IIloval nOm the contaminated area is most important. Further trcutm~>n1. should be symptomatic and supportive. Inform the treating physician that Ihe patient could be e.-..:pc:ri::ncing hyperoxia. 5. Fire Fighting Measures - Conditions of FlammabilÜv; Not fiamrn,able. Oxidizer Flash point I Method: I Autoignition None Not ApDlicable Temperature: None: LEL(%): None I UEL(%): non~ Ha7.ardous combustion products: None - Sem¡itivitv to mechanic.a! shock: None - Sensitivity to static discharge: None - FIRE AND EXPLOSION HAZARDS: High oxygen concentrations vigorousty accelerate combustion. EXTINGUISHING MEDIA: Water spray to keep cylinders cool. Extinguishing agent appropriate for ;he combustible material. FIRE FIGHTING INSTRUCTIONS: If possible, stop the flow of oX'ygen which is supporting thc fire, 6. Accidental Release Measures Evacuate all personrtel from affected area. Use appropriEtte protective equipment, If leak is in user's equipment. be certain to purge piping with inert gas prior to attempting repairs. l.fJeak is in container or container valve, contact the appropriate emergency telephone number listed in Section 1 or call'yolU' closest aoc locatiol., 7. Handling and Storage Electrical classificat,ion: Nonhazardous Dry product is noncol1'osive and may be used with all materials of conslmclion. Moistt:.l'e causes metal oxides which are formed with air to b¢ hydrated so that thc)' include volume anó lose their protective role (I'ust formation). Concentrations of S02, C h, saIL, etc. in the moisture enhanc~:; the rllstin~ of metals in air. MSDS: G-I Rc\'iscd: 04/04/98 Page :; £d Wd90:Þ0 000è 90 'AoN 1006 Þ£9 S0S 'ON 3NOHc 3ltlG3S0èl 0S1S :IN I Gl3M S3i'fèltl8 NOH.:! .. ¡.. ~ \ Carbon steels and low aHoy steels arc acceptable for use at lower pressW'(~s. For high pressure applications stainless stcels arc acceptable as are copper and its alloys, nickel and its aUoys, brass bronze, silicoo aUoys, Monel (R), lnconel (R) and beryllium. Lead and silver or kad tin alloys are good gasket ma«::rials, Teflon (R), Tc:flon (R) composites, or Kel-f (R) are prc:felTed l1ol1-meta))jc gasket materials. Check with the supplier to verify oxygen compatibility for the sCTvic,c conditions. Oxygen should not be used as a substitute for compressed air in pneuma.tlc equipment since this t>'Pe generally contains flao:illlable lubrIcants. Stationary customer sitt; vessel:; should Oper&tc in accordance:: with the: manufacturers and BOC's instruction. Do not attempt to repair, adjust or in any other way modify the operation ofthcsc vessels. If there is a malfUnction or other type of operations problem with the vessel, contact the closest BOe location immediately. Valve protection caps must remain in place unless container is secured w:th valve, outlet piped to use point. Do not drag, slide or rollcylinders. Use a suitable hand truck for cylinder movement. U!iie a pre~~ure reducing regulator when connecting cylinder to lower pressure «3000 psig) piping Or systems. Do not heat cylinder by any mean,s to increase the discharse rate of product from the cylinder. U!;e a check valve or trap in the discharge line to prevent hazardous back flow into the system. Protect cylinders 1Ì'om ph)'sical damage. Store in cooJ" dry., weU·ventiJattd area away trom heavily trafficked areas and emergency exits. Do not allo\\' the temperature where cylinders are stored to exceed 130uF (54"C). Cylinders should be stored upright and flfmly secured to prevent fa11ing ,)r being knocl<ed over. Full and empty cylinders should be segregated. Use a "fI.rst in-first out" inventory systeztl to prevent full cylinders being stored for excessive periods oftimc. Post "NO SMOKING OR OPEN FtAMB::;" signs in the storagt area Or us~ area. There should be no sOurCc:s of ignition in the storage or use area. For additional storage reconunendat1ons, consult Compressed Gas Association's Pamphlets P-l, P-14 and Safet.y Bulletin SB-2. Never carry a compressed gas cylinder or a container of a gas in cryogenic liquid f0I111 in an enclosed space such as a car trunk, van or station wagon. A leak can result in a fire, cxplosioI1, asphyxiation Or a toxic exposure. 8. Exposure Controls, Personal Protection Oxygen FORMULA: 02 CAS: 7782-44-7 RTECS II: RSZ060000 99.6 to 100,0 Not Available :~!W¡;;;;;~~illr!!~¡ftJ !¡!;!';::~~t~~~BW~~~t¡i@ ¡¡':~iÆ;;¡\im~¡~~~~~~J!¡;,i~f:dim'ji1i ~l'i,;""."" Refer to individual state or provincial regulations, as applicable, for limits which may be more stringent than those listed hero. ENGINEERING CONTROl's: Usc local exhaust to prcvent acclUnulation of high concentrations that imrease the oxygen level in aír to more than 25~"\\. EYEIFACE PROTßCTI0N: Safety goggles Qr glasses as appropriate for the júb. Faceshicld is recolllt1ended fÖr cryogenic liquids. MSDS: 0-1 Re"ised: ()4/04!98 Page 4 17d l.Jd¿0: 170 000ë: 90 '",oN 1006 17E9 S08 'ON 3NOHc 3l~a3S0~ 0S1S 8NIGl3M S3N~~8 I-<JO~..:! . i .... . ';f.:~;~1Ø~~¡tg.Jii~rtb:f;;!U!Øg~G:~!ìf¡;¡;\¡;+¡11.;)(~;~{.~i~«f§~:¡tm;!]::~~;::j,:;i:)(H;1f;~r;f:SJ;~:;t~t;;~;~:?::W:~;1i1m~\~~j~J?iWtJf;:,@:t¡t;¡;¡'.;i,;;~i:U;:;::}:\\:',<:i:1ii!f:¡~d}'!:\¡~)1!Ç!~¡:;i¡;i:::i SKIN PkOTECTTON: Protective gloves made of any s....itable mutcrial appropriate fol' the job. Insulated gloves recommended for cryogenic liquids. OTHER/GENERAL PROTECTION: Satèty shoes, safety shower. 9. Physical and Chemical Properties PARAMETER Physical state (gas, liquid. solid) Vapor pressure Vapor density Aír= 1 ) Evaporation point Boiling point Freezmg point pH Specific gravity at SIP OiVwater partition coefficient Solubility (H20) Odor threshold Odor and appearance 10. Stability and Reactivity STABILITY: Stable. INCOMPA,TIBLE MATERIALS: AU flammable materials. HAZAJ.tDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION: Will not occur. MSDS: G·I Revised: 04/04/98 Sd Wd¿0:v0 000è 90 'AoN T006 v£9 S0B V ALUE UNITS ; Ga.<; ; Above critic¡\1 temp. ; 1.11 ; Not Avai1abJ.e : -297,3 "F : -182.9 °C : ·361.8 "F ; .2]8.8 °c : Not Applicable ; Not AvailabJe : Not Availab!e ; Slightly soluble : Not Applicable : Colorless, odorless gas Pagè 5 'ON 3NOHc 3l~G3S0~ 0STS 8NIGl3M S3N~~a WO~~ ..' '\... I {'",.,ø '·'.'~;¢.~iN~tii.'.t?;¡irlm~~ê,f!i)j';)ij+bU;UXi\/j::, ,.'" ..¡ ,,',. . ::~;~.:tp };::P;·:f:~~~~'r~:,,~g:~~:,:;,:~~·:?~; :-~:¡';::;'.:A~,::;E;: ~~i.i;::{ :'::~~:},;{;~:;·,(~:;'i::··;~:{~·.:::·;·:'?~.::::;~~,::i:Lfr·'? ;:~~.:~f.{:i}?¡\;:~~F~~{i~H~;~~ii~tfi~;@;:.'~:'!~~:~r, ..... L J .......... 11. Toxicologicallnformatíon MUTAGENIC: Oxygen concentrations between 20 tQ 95% have produced genctic changes in mammalian <.:cll assay test systems. 12. Ecological Information No data given. 13. Disposal Considerations Do not attc:m.pt to disposo of residuul waste or lUlused quantities. Return Ln the shipping cont.ainer PROPêRL Y LABELED. WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VAL VB PROTECTION CAP IN PLACE to Boe Gases Or authorized distributor for prope,r disposal. 14. Transport Information ~.~?·r:~ir?~~i~~.~W$W~M:B1tSR1i~f~~~i~·~;~i~~:;>~ !.{~~~t;:~~~~:~i:;~~r::-i.~:irr,}::·;\:: (~';~~~~t<:\'~~~·J4:$.;i~D':Q¢t~f.~:,;::; ;~i:~ ~~{~:~¡,,;?!~·:}·\·i?:~~:,::'?::g;;~ /f;:: ~:;i,:'{j:~:';';·~i·.;X~::~~i:~~~~' r¡1~::~~:':";:<~1'At·~~;~·~'~;:;<:$t,~ø;G:·;n:,{:;~'{,)¡~~!fJ:;~~i~·;;.;t·;.~(?~ ~F:·\. '~.:;~ii;;:~? PROPER SHIPPING NAME: Oxygen, compressed Oxygen, compressed HAZARD CLASS: -- --- 2.2 :2.2 (5.1) IDENTIFICATION NUMBER: UN 1072 UN 1 072 SHIPPING LABEL: NONFLAMMABLE GAS, OXIDIZER NONFLAMMABLE GAS, OXIDIZER 15. Regulatory Information SARA TITLE III NOTIFICATIONS AND INFORMA TlON SARA TITLE In - HAZARD CLASSES: Fire Hazard Sudden Release of Pressure Hazard 16. Other Information Compressed gas cylinders shall not be refilled without the express writtcn. pernliss.ion of the owner. Shipment of a compressed gas cylinder which has not been t1Ued by the owner Or with his/her (written) consent is a violation oftra.nsportatiQ) regulation:!. DISCLAIMER OF EXPRESSED AND IMPLIED W A.RRANTTES: Although reasonable care has been taken in the preparation ofthi~ document, we extend no warranties and make no represemations as to the accur~cy or completenc~s of the Jnformation cOl1tain<.:d herein, an.d assume no responsibility regarding dle suitabi1ity orthis information for the user's intended purposes or lor the consequences of its use. Each individual should make a determination as to the suitability of the illfOl1llation for their pan,icular purpose{s). M.S1>S: 0-1 Revised: 04(04/98 Pa~e 6 9d Wd80 :170 000C 90 '()oN 1006 17£9 £08 'ON 3NOHc 3l~a3S0~ 0£T£ ~NIal3M S3N~~8 WO~~ :'::"';;;,!;"" ~~. -'-'-.; ',~~ BOC' /"'G A~:S"E" :'S',f.,;Ji~~FXt{::~\i~;::;;~¡;d:I.'::'('" ~~'~;'',,,;,,,::''':,;H'''_'''''~~\ "~'" ;.~~ ,,", " "''':" ,..,,' "; , . MATER1~L SAFETY'DATA;SH'EET" : '. '.. "~";''i..,.~-,:,. ... --.., ,,' ,..¡';',;,.. ~:'''~' ~:. .." ./ " '0 "0"" '" ',I, , , . ." I ~ 1. Chemical Product and Company Identification' , BOC Gues, A Division of The BOC Group, lnc 575 Mountain Avenue Murray HiU, NJ 07974 HOC Gases, A n¡"Îsion of DOC Canada Ltd. 89 Queensway West Mississauga, Ontario L5B 2V2 TELEPHONE NUMBER: (908)464~8100 24-HOUR EMERGENC)' TEL,EPHONE NUMBER: CHEMTREC (800)424·9)00 TELEPHON)~ NUMBER: (905)273-7700 14.HOUR EMER.GENCY TELEPHONE NUMBER: (905)949-377'7 ' EMERGENCY RESPONSE PLAN NO: 20101 PRODUCT NAME: ACETYLENE CHEMICAL NAME: Acetylene COMMON NAMES/SYNONYMS: Ethyne, AcetyJen, Ethine TDG CLASSIFICATION: 2.1 WHMIS CLASSIFICATION: A, B1 PREPARED BY: Loss Control (908)464.8100/(905)273-7700 PREPARATION DATE: 03/17/98 REVIEW DATES: 03/17/98 LATEST REVISION DATE: 03/17/98 PREVIOUS REVISION DATE: None 2. Composition, Information on Ingredients ',: ,:: ,~I~~~¡~~:1~~0(""~" .;~~' Acetylene FORMULA: C2H2 CAS: 74·86·2 RTECS #: A09600000 AcetQne Not Available 1000 ppm TW~ 750 ppm TWA FORMULA; C3H60 10CO ppm STEl CAS: 67·64·, RTECS tI; AL3150000 I As stat~ in 29 CFR 1910, Subpart Z (f~viS~d July I, 1993) 2 As stated in thç ACCIH 1994.95 Thrc5hold Limit VI\I~s for Chcl'l1j~al Substlln~es nnd Physic!!! Agcnts LDso 1297 m\Jl1I.g (mouse) 3. Hazards Identification , " , ,,'.' ' ;,.,." ':, ..,'::¡)¡:EMËRG'~NCY~t)VËRVfEW:'ifJT:¡;:.""'/'" Niii,':j;-;.;',;<;; ';", ',' '..,,:,. ' ", Simple 'Asphyxiant. THis:' 'roëuctidO:és{nôt{CÓnl·irl,'''''·'''a''~.~i(rið;rð'''''è: ." "J, "\'1,' ëleas'ed'in,a:,::,:;' confined area. ,Maintain .t~g' " eiÍ:'I~~ä'š;a'\6(W'~~'~"5 "~~~ä:;::'I'~'JfJn"~r':'" i:'''';'''J:I~~' " ,:,':r-Hr.~','æl~i,;fI· ; , " '..' :"':/~I'~' " . "'" ' ,~:l ,. ;"r\~. " .,,9,""'" J; '. µ$e",.., ~. ",' 'r. IglJ \I amma", e u d ess ' ,,'.. s' 0 :t" "'~.:' C:,;..'..·'. "''::''ti'',''v''lj "~,. ,', ,"'" ""¡'",~,;"",..::,,-,,,;.,¡\;: ::", ' "..~¡¡,...;":':.; ,',' ""'/;"';"". ',..... ";"'~¡","" n" er pr...l,Jr~./ p .11, ~n~>~W~.~:F~m.,.H~t.l,,,a~~l9.¡~¡Jfg;~~~~~~~~ ,.,<#~~MØh~;!.!.qUld¡~,:¡\;:> shock sen~Jt¡v~':' . ~ '~~:~·.F~,::.;~..:·~~' "7:,': :\}::·~}~t~~~:,:!L:~::~';~f.~:~~.'1~~.:·..~}~.:,·':.?:t~~.V~:.,. ;~'~:d:{~~:'~1¿;,j,:~;6t~r~·::~::~.~t;· '.:.~::,~:.;. . ,.,,';:{~~~~::~·~~::~~,7·::;.:~'·;;:'. :," ~::~ ':\'.~':'''>:':; -' ".' ! '. ,.:....'., :" MSDS: G-2 Revised: 03/17/98 Þagc 1 '!d Wdv!:v0 Ø00G 90 'AoN 1006 Þ~9 S08 '01'-1 3t'-IOHc: 3ll:::Ja3S0~ 0£TS ÐNJal3M S31'Id\::l8 Wad.:! " ROUTE OF ENTRY: ," Skin Contact No , "Skin Absorption No Eye Contact No ,. Inhalation ~ l I Inge:;tion No '1, HEALTH EFFECTS' .' - S~tion Exposure Limits Irritant Yes Yes No - Teratogen Reproductive Ha;¡:ard Mutagen No No Nó Synergistic Effects None Reported - Carcinogenicity: .. NT?: No IARC: No OSHA: No EYE EFFECTS: , None k.nown since product is a gas at room temperature. Contact of liquid acetone with the eyes :may cause temporary irritation. SKIN EFFECTS: Skin effccÍ$ are not likely. Contact with liquid acetone may cause irritation and dennatitis upon repeated exposures. INGESTION EFFECTS: Ingestion is unlikely, since acetylene is a gas at rOOm temperature. INHALATION EFFECTS: Acetylene is an asphyxiant and may cause anesthetic effects at high concentr¡~tions. High concentrations may exclude an adequate supply of oxygen to the lungs. Effects of oxygen deficit:ncy resulting from simple asph)'Xiants may include: rapid breathing, diminished mental alertness, impaired muscular coordination, faulty judgement, depression of al1 sensations, emotional instability, and fatigue. As asphyxiation progresses, nausea, vomiting, prostration, and loss of conscio\lsness may result, eventually leadÎ.lig to convulsions, coma, and death. Under normal operating conditions, acetone is not released trom the cylinder, However, jfthe cylinder is overcharged with acetone or acetylene, acetone may occassionalIy "spit" out, Acetone is primarily a central nervous system toxin causing headache, nausea, diuiness, vomiting and fatigue. Moderate concentrations may cause respiralory irritation. Oxygen deficiency durin.g pregnancy has produced developmental abnormalities in humans and experimental animals. NFPA HAZARD CODES HMIS HAZARD CODES RATINGS SYSTEM Health: 0 Flammability: 4 Reactivjty: 0 Health: 0 Flammability: 4 Reactívity: 0 0::: No Hawd 1 ::: Slight Hazard 2::: Moderate Hazard 3 ::: Serious Hazard 4 = Severe Ha.zard MSDS: 0-2 Revised: 03/17í98 Page 2 èd WdS~:v0 Ø00è 90 '~oN tø06 v£9 S08 ·ON 3NOHc 3ltlQ3S0èl 0ST S 8H I al3f1 s3t'-l~tla WOèl.:l ·-.1 '.' . I 4. First Aid Measures EYES: None normally required. Consult a physician if direct contact with pressurizf:d material occurs. Immediately flush with low pressure, cool water for at least t 5 minutes, opening eyelids tl;l en<jure flushing. Get medical attention. SKIN: Wash affected areas with soap and warm water. If irritation develops, seek nledical attention. INGESTION: None nonnally required. INHALATION: PROMPT MEDICAL ATIENTION IS MANDATORY IN ALL CASES OF' OVEREXPOSURE. PERSONNEL SHOULD BE EQUIPPED WITH SELF·CONT AlNED aREA THING APP ARA tuS. Victims should be assisted to an uncontamÏJ1ated area and inhale fiesh air. QIJick removal from the contaminated area is most important. Ifbreathing has stopped administer artificial resuscitation and supplemental oxygen. Further treatment shoutd be symptomatic and supportive. Keep victim warm and quiet. 5. Fire Fighting Measures Conditions of Fla.mmabili Flash point: Not Available LE %; 2.2 Ha:z.ardous combustion roducts: Carbon Monoxide, Carbon Dioxide Sensitivity to mechanical shock; Not Available Sensitivity to static discharge: Not Available FIRE AND EXPLOSION HAZARDS: ·Pure acetylene ca.n ignite by decomposition above 15 psig; therefore, the UEL is 100% ìfthe ignition source is of suftlcient intensity. GASEOUS ACETYLENE IS SPONTANEOUSLY COMBUSTIBLE IN AIR A T PRESSURE ABOVE 15 PSI (207 kPa.). It requires a- very low ignition energy so that fU'es which have been extinguished without stopping the flow of gas can easily reignite with possible explosive force. Acetylene has a density very similar to that of air so when leaking it does not readily dissipate. Gas may travel to a source Qfignition and flash \:lack. Fires involving acetylene occur occassionalIy at fusible metal pressure relief plugs at the tops and bottoms of cylinders, commonly due to hot metal or slag being dropped on the fusible ph;!gs. When the fusible plug releases a large volume of acetylene will rush out, creating a "roaring" sound. The flame may extend a foot or two away fromJhe cylinder until the pressure is reduced. In some cases, the Qther end oCthe cylinder may devclop a coating of fÌ'ost. EXTINGUISHING MEDIA: Carbon dioxide, dry chemical. MSDS: G-2 Revised: 03/17/98 Fage 3 £d Wd9t:Þ0 000è 90 'AoN tø06 Þ£9 S0S 'ON 3NOHc 3l~a3S0~ 0StS ÐNlal3M S3N~~8 WO~~ ..' ,»' ~ 'Ëíð(~i:jl;'I'ñ;Ji~-Ki""¡Mi::&.t'~~I~ëi.<ršg¡t~~~~ '~. .,.d.~,-.....:..9..~.j,i;f,,'71.r;;l~ '~.""" ,~~~t~!'~~I'..~~,...õA'~'¡"~*:"'~' ,.... " FIRE FIGHTING INSTRUCTIONS: W ARN1NG: ALWAYS EXTINGUISH A ,FIRE,BEFORE, CLOSING mE ,CYLINDER V AINE. lithe flame is.smatl ñ:o~ ~lè 'fusib~¡::',p1ug,or.valve stem, try to put it out:~:Wear SGBAar;.d:fullY'proœctive clóthing for flr~'" ' :, fighting. If the fire is allowed to keep burning it is likely that the fusible plug will melt and result in a large release of acetylene. A glove or heavy cloth or any wet material slapped on 111e flame will trequcntly extinguish it. , , .~, .,',. r"'." . . ~ .... If the flame is large, burning from a fusible plug, DO NOT try to put it out unless the cylinder is outdoors or in a very well ventilated area fi'ee trom SOurces of ignition. Usually it is very difticult to extinguish large fu-es because the escaping acetylene may be reignited by adjacent ignition sources, thereby possibly creating; a confIDcd space explosion. Keep containers cool with water spray. 6. Accidental Release Measures Evacuate all personnel trom affected areas. Isolate the area for over 1/2 mile in all directions in tl1e event of leakage of a tank, rail car or tank truck. Use appropriate protective equipmellt. If possible to do safely, shut off ignition sourCes and stop the leak by closing the valve. For $T11allleaks, cylinders may be moved to an area outdoors and away from any SOurce of ignition. Circumstances which, it is advisable to attempt removal of the cylirtder are when cylinders are in close proximity to other compressed gases. when highly flanunable'materials or hazardous materials are in the vicinity ofthc: acetylene cylindcr(s), or where protection of the building is unusually difficult and spreading of a tire may produce a major loss of life or property. When the cylinder is removed, it may be hosed down with water te, keèp it cool. Open valve slowly to let the acetylene escape. Tag the cylinder with "WARNING ~ Leaking Flanunable Gas". Close valve when empty . Evacuate a/1 personnel tì:om affected area. Use appropriate protective equipment. If leak is in user's equipment, be certain to purge piping with inert gas prior to attempting repairs. ICleak is in container Or container valve, contact the appropriate emergency telephone number listed in Section I or call your closest BOC location. 7. Handling and Storage Electrical Classification: Cla.ss 1. Group A. Acetylene is shipped in a cylinder packed with a porous mass material, and a liquid solvent, commonly acetone. Acetylene is dissolved in the acetone solution and dispersed throughout the p')rous medium. When the valve of a charged acetylene cylinder is opened, the acetylene comes out of solution and passes out in the gaseous form. IT IS CRUCIAL THAT FUSE PLUGS IN THE TOPS AND BOTTOMS OF ALL ACETYLENE CYLINDERS BE THOROUGHLY INSPECTED WHENEVER HANDLED. REMOVE AND QUARANTINE IN A SAFE LOCA TION ANY DEFECTIVE CYLINDER. Post "NO SMOKING OR OPEN FLAMES" signs in the storage area or use 2,rea. There should be no sources of ìgnition in the storage Or use area, Use only in well-ventilated areas. Stationary customer site vessels should be ::>pera:ed in accordance with the manufacturer's and BOC instructions. Do not attempt to repair, adjust or in any other way modify the operation ,of these vessels, If there is a malfunction or other type of operations problem with the vessel, contact the closest 'Boe location immcdiately for assistance. MSDS: G-2 Revised: 03/17/98 Pa~¡; 4 vd Wd9~:v0 000è 90 'AoN ~006 v£9 £08 'ON 3NOHc 3l~a3S0~ 0S~S ~Nlal3M S3N~~8 WO~~ /')~::iïíttø'l'$l1Im~ìlð."Yi'¡iß¡\' ~~{ë'k'(ë;Wø:~ ,. ' Y'. I.~.;¡.,...._~'~, '4..,v.,,~"!-a~~~~\_.,~ir'.'~.:tfiil/.¡~...1".~~ . / , / '.' í-" i~<'i' . ...... .. ..-".-.-..-... . . Protect cylindel'$ from physical damage. Store in cool, dryj,.wdl-ventilated a¡~ea away from heavily trafficked are3ðand emergenc)"exitsc' DO NOT'allow the temperature where,cylinders' no Gtored tQ exceed 125°F (52?C). " Cylinder1 shol.lld'be stored'upright a.ndf1ttt1lysecured'to'þrevei1t falling'or bE,ing' knocked OVer. Full and'empty' cylinders should be segregatcd. Use a "fll'st in-fl!st out" inventory system to prevent full cyli.nders ITom being stored for excessive periods of time. ' Valve protection caps must remain in place unless container is secured with. "alve ouClct piping to use point. Close valve after each use and when the container is empty. Do not drag, slide or roll cylinders on their sides. Use a suitable hand trUck for container movement. Use a pressure reducing regulator when connecting contaim~r to piping or systems. Do not use gas directly from container. Do oot heat container by any means to incrc:ase the discharge rate of product from the container. Never attempt to repair Or alter cylinders. Never tamper with pressure relief :ievices or fusible plugs, Under no circumstances allow a torch flame to contact the fusible plug. While welding, avoid contact of the cylinder welding equipment or electrical circuits. If rough handling or other occurrCnces should cause any fusible plug to leak, move:: the cylinder to an open space well away from an possible source of a sign on the cylinder warning of "Leaking Flammable Gas". Unless oxygen and acetylene are separated, there should be a non·combustib]e partition of at least 5 ft hig.b with a fll'c resistance rating of one-half hour between cylinders. In the U.S. cylinders stored inside a bùilding near user locations must be limited to a total capacity of 2500 fe of gas, exclusive of in-use Or attached fQr use cylinders. Do not store cylinders On their side. This makes the acetylene less stable and less safe, and increas=s the likelihood of solvent loss and resultant decomposition. for additional information, consult the Compres$ed Gas Association (COA) pamphlets p. I, 0-1, 8B.4-1990; NFPA #51-1984, and OSHA 1910 Subpart H & Q, 8. Exposure Controls, Personal Protection EXPOSURE LIMITS: ',:, '1~~1;~P'~~T,,~:,·~'~ti','··';};: ,:;~~~~g~~~~:;,i,j' fj)j~: :,,·:}~~r~~~~~1,r:;:;:,:;:;': .,:,':~t.¥,:~~~~ltf· ,':/;: :;:::~hrJW:~i1,RÞiö :i;' ;:~". ':¡;Rop\ëfSpè~¡,es;': Acoty/el'lQ 95.0 to 99.6 Not Available Simple AsphyxIal'll Not Available FORMUlA C2H2 CAS: 74-86-2 RtECS #; A09600000 Acetone Not Available 1000 ppm TWA '750 PÞI'!'I TWA LDsa FO~MUtA; C3H60 1000 ppm 5TEL 1297 mgll<9 CAS: 67·64·1 (mouse) RTECS #: Al3150000 Refer to individual state or provincial regulations, as applicable, for limits wtlÎch may be more sttingent than those listed here. MSD$: 0·2 Revised: 03/17/98 Page 5 Sd Wd¿I:Þ0 000è 90 'AQN rø06 Þ£9 S0S . ON 3NOHc 3l1jG3S0;:¡ 0S I S ::IN I Gl31'1 S3t..;:¡1j8 WO;:¡..:t /' .,' ,',' , ,,' " 'f~;í.t11i~F~~æ~~"if~Y~~,," ,',", ':,~ __?_~¿i~j~~,wni'if_ "IJ:....~.._\l.;.WfÁJ..i~...;o".. ~ ....~'.... ."'. '.' \for ~ . ~.. ..~' tp: '\"", 'It,; . "t~·, ¡æ.~..~.,:¡ . . '",: . : ~ . ., . . , ." .. ,. .': . .~. . ......... .,' ,'~' ", ' ~ ENGINEERING CONTROLS: ,,', " ", , ' Provide gener~l room ve~tHation and local exhaust toprev.ent accumulation ;lbove the exposure limit and to , maintain oKY&en leyels a.bove 1-9.5%. Mechanical venti1atîon shói.11d,bc designed in accordMc~'with electrical ' codes. , \ ,"'" EYE/vACE PROTECTION: Safety goggles 01' glasses as appropriate for the job. SKIN PROTECTION: PVC or rubber in laboratory; as required for cutting and welding, RESPIRATORY PROTECTION: Positive pressure air line with full-face mask and escape bottle or self-contained breathing apparatus should be available fQr emergency use. OTHER/GENERAL PROTECTION: Safety shoes, 9. Physical and Chemical Properties FreeZ1..ïg point VALUE UNITS : Gas : 635 psia : Not A vaiJaòle : Not Available : -118.8 PF : -83.8 °e : .113 of : -80.6 (Ie : Not A vaiJabJe : 0.906 : Not Available : Soluble : NQt Available : Pure acetylene h;iS an ethera] odor. Commercial (carbide) acetylene has a distinctive garlic-like odQr; A calorIes!: gas.' PARAMETER Physical state (gas, liquid, solid) VapQr pressure Vapor density (Air=1) Evaporation point Boiling point pH Specific gravity Oil/water pal1ition coefficient Solubility (H20) Odor threshold Odor and appearance 10. Stability and Reactivity STABILITY: Unstable. shock sensitive in the liquid state. Do not allow free gas (out:$ide (lfcylînc:Jer) to exceed S psig. Do not expose cylinders to sudden shock or heat. Acetylene will decompose violently with cylinder failurE:. INCOMP A TIBL£ MATERIALS: Oxygen and Qther oxidizers including all halogens and halogen compounds. Forms explosive acetylide compounds with coppe-r, mercury, silver, brasses containil1g >66% copper and brazing materials containing silveror copper. MSDS: 0-2 Revised: 03/17/98 Page 6 9d Wd81:Þ0 000~ 90 '^ON rø06 Þ£9 £08 'ON 3NOHc: 3l~Q3S0~ 0srS 8NIQl3M S3N~~a WO~~ Under certain conditions, acetylene forms readily explosive acetylidc compounds when in contact with copper, silver, and mercury. Therefore, use ofacétylene and these metals, or thcir sal:S, compounds, and high concentration alloys should be avoided. The presence of moisture, certain acids or alkaline materials tends to enhance the formation of copper 8cetylides. HAZARDOUS POLYMERIZATION: Temperatures as low as 250°F (121°C) at high pressure. or at low pressure in ;:he presence of a catalyst are sufficient to initiate a polymerization reaction. The hazard here is that the polymerízatíon nonnally liberates heat and may, therefore, lead to ignition and decomposition of acetylene if conditions pennit. 11. Toxjcorogicallnformation Low concentrations (10-20% in air) cause symptoms similar to that of being intoxicated. As a narcotic gas Or intoxicant. it causes hypercapnia (an excessive amount of carbon dioxide in tIle blood). Repeated exposures to tolerable levels has not shown deleterious effects. TCLO, human ~ Inhalation of20 ppb inhaled has been shown to cause headache and dyspnea. Oxygen deficiency during pregnancy has produced developmental abnormalít: es in humans and experimental animals. 12. Ecorogicallnformation No data given. 13. Disposal Considerations Do not attempt to dispose of residual waste or unused quantities. Return in thl: shipping container PROPERLY LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS SECUUD AND VALVE PROTECTION CAP IN PLACE to BOe Oases or authorized distributor for proper disposal. 14. Transport Information "'::,-'·'PA8ÄMETEø...'·"·,''''''< . :;~:~.~:.~?~~~~~::.:;~.:¡.:.;.:~:~~~g:~;.{~;.~ ~·.:.;·¡~ø:~~.º]it¿~t~~:·:·,,~:<~~~~j~¥;...:~.{S~~:.;:~·:;,' ';~~ : ,:' }:."~: ~~~·~f:J;?Vt:~~7~~~;:Jff.~~?~~þTD,~?:'i~;\\·;~ ~i/~~;~~:µ::~~:n~~J~~;r;;..· ~_:' ,:,} .,' ,',.- .".. :-,~ ., ':':··J{~(:~~r¿~:~ ! PROPER SHIPPING NAMe: Acetylene, di$$olved Acetylene. dissolved HAZÅRO CLASS: 2.1 2.1 IDEN'rIFICA TION NUMBER: UN 1001 UN 1001 SHIPPING LABEL: FLAMMABLE GAS FLAMMABLE GAS - 15. Regulatory Information U.S. FEDERAL REGULATORY INFORMATION MSDS: G·2 Revised: 03/17/98 Page 7 Ld WdS1:Þ0 000G 90 'AON 1006 Þ£9 S0S 'ON 3NOHc 3ìli03S0èl 0S1S 8NIOì3M S3t-'èlli8 WOèI..:I Acetone is regulated as a Hazardous Substance under CERCLA. SARA TITLE IXX NOTIFICATIONS AND INFOIlMATION SARA TITLE III - HAZARD CLASSES: Acute Health Hazard Fire Haurd Sudden Rckase of Pressure Hazard Reactivity Hazard SARA TITLE III - SECTION 313 SUPPLIER NOTIFICATION: This product contains the following toxic chemicals subject to reporting requirements of section 313 of the Emergency Planning and Community Rìght- To-Know Act (EPCRA) of 1986 and of 40 CFR 372: CAS NUMBER 67-64-1 mOREDIENT NAME Acetone PERCENT OF VOLUM1~ UnknOWl1 This infonnation must be included on all MSDSs that are copied and distribll':ed for this mat~rial. RECULATEDJNGREDIENTS INGREDIENT: Acetone CAS NUMBER.: 67»64-1 REGULA TIONS: ILL MAS NJS NJW PAW STC \VHIYt ILL - Illinois Toxic Substance MAS - Massachusetts Hazardous Substance NJS ·'New Jersey Special Health Hazardous Substance NJW - New Jersey Workplace Hazardous Substance PAW - Pennsylvania Workplace Haz.ardol,lS SubstancE: src . SARA Section 313 Toxic Chemical WHS . WHMIS (CMada) fNGREDIENT: Acetylene CAS NUMBER: 74-86-2 PERCENT BY VOLUME; 95.0 to 99.6 REGULATIONS: ILL MAS NJS NJW PAW WHM ILL - Illinois Toxic Substance MAS - Massachusetts Hazardous Substance NJS - New Jersey Special Health Hazardous Substance NJW . New Jersey Workplace Hazardous Substanoe PAW - PeMsylvania Workplace Hazardous Substance STC . SARA Section 313 Toxic Chemical WHS - WHMIS (Canada) CANADIAN REGULATORY lNFORMA TION: In Canada, regulations limit the capacity of acetylene cylinders stored inside a, building at USer locations to a total capacity of2160 ft3 of gas in unsprinklered combustible structures, or 6130 ft3 in sprinklcred buildings of (;ombustible or non-combustible structures. 16. Other Information ~ompressed gas cylinders shall not be refilled without the express written pennission of the owner, Shipmcnt of a compressed gas cylinder whiëh has not been filled by the owner or with hislller (written) consent is å violation of transportation regulations, MSDS;G·2 Revised: 03/17/98 Page 8 Sd Wd6t:Þ0 000ë 90 'AON 1006 Þ£9 S0S 'ON 3NOHc 3l~G3S0~ 0S1S 8NIGl3M S3N~~8 WO~~ DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this doeu.ruent: we extend no warranties and make no representations as to the accuracy OJ' completeness of the infonnation contained herein, and assume no responsibility regarding the suitability ofthi5 information for thc user's intended purposes or for the consequences ofìt.s use. Each individual should make a determi.nation as to 1he suitability of the infornlation fOr their particular purpose(s). MSDS: 0-2 Revised: 03/17/98 Page 9 6d Wd0è:Þ0 000è 90 'AON m06 Þ£9 £08 'ON 3NOHc: 3l~G3S0~ 0STS 8NIGl3M S3N~~8 WO~~ . P.l i': " NOV 07 '00 08:19 SERVICE OIL CO ..: ""'. ...~ .' {'. .". , I ,-""The Vf.\lvoline Company MA TERIAL SAFETY DATA SHEET Page 001 Date Prepared: 03/04/98 Date Printed: 10/03/98 MSDS No: 505.0173308·012.009 HP GEAR 85-140 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Hate~l&l Identity Product Name: HP GEAR 85-140 Product Code: 61633895 General or Generic ID: PETROLEUM BASED-LUBRICATING OIL Company The Valvoline Compa~y P.O. Box 14000 Le~ington. KY 40512 TeleÞhone Numbers Emergency: 1-800-274-5263 Information: 1-606-357-784ï 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredient(s) _.____..~._..__________.__u~~.___.__________ PÈTROLEUM DISTILLATES LrffBE OIL ADDITIVE CAS Number % (by weight) ------------- --------.---- 64742-65-0 87.0- 97.0 2.8-' 13.0 3. HAZARDS IDENTIFICATION ~,pôtential HeaIth Effeots Eye Unlikely to cause eye irritatic)n or injury. Skin May cause mild skin irritation. Prolonged or repeated contact may dry the skin. Symptoms may include redness, bUring) dl"ylng a.nd cracking of skin I and skin b'.Jrns Swallowing Swallowing small ~mounts of this material during normal handling is not likely to cause narmful effects. Swallowing large amounts may be harmful. Inhalation It is possible to breathe this material under certain conditions of handling and use (for example, during hoating, spraying, or stirring). Symptoms usually occur at air concentrations hi~:her than the recommended exposure limits (See Section 8). ' Symptoms of Exposute stomach or intest.inal uJ?set (nnuses. vomiting. diarrhea), irritation (no$e, throat, airways), pain ).n the lLbdomàn. Target Organ Effects No data Dev.eJopmental Information No data .....> Continued On Next Page o ~, " . " , .'....: , ~ , :\t',' ' <.f>' , . II: .' ~ ~J ,.,ì '~ ~~~; '.!, ,:, .', ,~ ;,1 ;1 'I ~i ';~ ~: " ~ ':~ . ... ,~ '. " , .~ J) 'I ,~¡ '. NOV 07 '00 08:19 SERVICE OIL CO P.2 f ~¡The Valvoline Company MA TEF~IAL SAFETY DATA SHEET Page 002 Date Prepared: 03/04/98 Date Printed: 10/03/98 MSDS No: 505.0173308-012.009 HI' GEAR 8S -140 Cancer Information No data Other Health Effeots No data P~tmary Route(s) of Entry No data 4. FIRST AID MEASURES Eyes If symptoms develop, move indh'idua1 away from exposure and into frf!sh air. Flush eyes gently w~th water ~lhile holding eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention. skin Remove contaminated clothIng. Wash exposed area with soap and water. If symptoms persist, seek medical attention. Launder clothing before reuse. SwaIJow1ng Do not induce vomiting. Give one glass of milk or water, and get medic~l atten~ion immediately. If po!sible. do not leave victim unattended. ~ In!hal at j on . , If symptoms develop, immedia.tE.ly move individual away from exposure and into . fresh air. Seek immedia.te meç.ical att~ntion; keep person warm andq1Jiat. If person is not breathing, begirt artificial respiration. If breathing is difficult, administer oxygen. No~e to Physioians No data 5.. FIRE FIGHTING MEASURES Flash Point > 300.0 F (148. 8 C) Explosive Limit , No data Autoignition Temperature . No datil Hazardous Produots of Combustion May form: carbon dioxide ,and carbon monoxide. various hydrocarbons. Fire and Explosion Hazards Néver use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosively. Dense smoke may be generated while burning. '-"' Continued 011 Next Page " t (j. I 1 ,,~ .' ~ ,. , ~ 'j, :~. ~, ,; \ ¡, Þ ;, .~ ':~ ' \. j :.., .,~ "'. , . r l t ';1 :i ~;t .'. ."": , .,~' ¡ ~:.I; ~, .~ , I '. .1: ~ ·f~i Jj,,:,', , , i . ',~ ':f. '.' . NOV 07 '00 08:20 SERVICE OIL CO P.3 ." , ; ,,-The Valvoline Company MA TERrAL SAFE'rY DATA SHEET Page 003 Date Prepared: 03/04/98 Date Printed: lO/03í98 MSDS No: 505.0173308~012.009 HP GEAR 85-140 Extinguishing Media regular foam, carbon dioxide, dry chemical. Fire Fighting Instruotions Water or foam may cause frothing which can be violent and possibly endanger the life of the firefighter. Wear a self-contained brêathing apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical résistant personal protective equipment. Refer to the persona 1 protective equip,nent sect ion of this MSDS. NFPA Rating' Health - 1. Flammability - 1, Reactivity - 0 \.,.. 6. ACCIDENTAL RELEASE MEASURES Small Spill Absorb liquid on vermiculite, floor absorbent or other absorbent material. Large $pj 11 Prevent run6of£ to sewers, streams or other bodies of ~ater. If run·off occurs, notify proper authori.ties as required, that a spill has occured. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Stop spill at source, dike area Ot spill to prevent spreading, pump liquid to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent, or other absoróent mat~rial and shoveled into containers. --...-..........- ~--- 7,. HANDLING AND STORAGE Handling Containers of this material may be hazardous when emptied. Since containers retain product resiaues (vapor, liquid, and/or solid), precautions given in the data sbeet must be oOserved. Sltorage Not applicable emptied all hazard 8. EXPOSURE CONTROLS/PERSC)NAL PROTECTION EYe Protection Not re~uired under normal condition~ of use. However, if misting or splashing condit~ons exist, then safety glasses or chemical splash goggles are advised. Skin Protection Not normally required. However, wear resistant gloves such as nitrile rubber , to prevent irritation which mav result from prolonged or repeated skin contact with product.~ Wear normal work clothing covering arms and legs.. Respiratory Protections Not required under normal conditions of use. However, if oil mists are generated above recommended PEL/TLV of 5 mg/m3 then a NIOSH/MSHA approved respira~or is advised in absence of proper env1ronmental control. (See your industrial hygi~nist.) \..,..-' Continued On Next Page \j. , ¡ (, i! :! '\ , .~ " ~. , ~' i '·r ;~ :i ! 1 . +. .,~ ' , , , ,- ¡ ,;.).1 J , 'Ð j i . .. ~ .... l oj: , 1 .'1' ,~ ~; 'I f ~ ... t ï;Ì' , '~ , , '~' , "I': , ' : . , -r- NOV 07 '0Ø 08:21 SERVICE OIL CO ~ '. . '. . ' . 'l P.4 r~,The Valvoline Company MA TEltIAL SAFETY DATA SHEET Page 004 Date Prepared: 03/04/98 Date Printed: 10/03/98 MSDS No: 505.0173308·012.009 ,HP GEAR 85 -140 Engineering Controls Not t"equlred under normal conditions of use. HO\l.!ðVer if unusual operating conditlons exist, then provido sufficient mechanica.1 ,general and/or local exhaust) ventilation to maintain exposure below PEL/TLV (s). ~xposure Guidelines E~~~~~~~:_ PETROLEUM DISTILLATES (64742-65-0) OSHA VPEL 5.000 mg/m3 - !WA Oil Mist ACGIH TLV 5.000 mg/m3 - TWA Oil Mist LUBE OIL ADDITIVE No exposure limits established 9. PHYSICAL AND CHEMICAL PROPER TIES Boiling Point (for component) > 425.0 F (218.3 C) @ 160 mmHg Viaþor Pfessure Not applicable ,-:speoific Vapor Density No data Specjfio G~avity .906 @ 60.00 F Liquid Density 1.550 Ibs/gal @ 60.00 F .906 kg/l @ 15.60 C Peroent Volatiles {'Including Water) ·No data Evaporation Rate SLOWER THAN ETHYL ETHER Appearance DRY, CLEAR & BRIGHT state LIQUID Physioal Form No datA Co'lor No data Odor No data Continued On Next Page .,'-' j " ,J -:'. , .. '~ :ï ,~ ·~t, ,I, , :I'~ i ,,' ;!, : ~;;.'. ~t,' " '. .: I '~ 1 't ~: "I' .: . " .. ., ~~ '" õ'. ,I ,I , , I.:. ;.J :.¡ , " , I NOV 07 '00 08:21 SERVICE OIL CO P.5 . . ~ . " ¡ . HP GEAR. 85-140 MATER.IAL SAFETY DATA SHEET Page 005 Date Preparêd: 03/04/98 Date Printed: 10/.03/98 MSDS No: 505.0173308·012.009 , 1~ .,1 " \.....,., The Valvoline Comps-ny '\),,, , t J it. ¡ ;:¡ . ~ . pH ': I Not applicable Visoosity 26.0 . 2i.O cst @ ,. , I I ... .~,' . i' *-1 '10. STABILITY AND REACTIVITY Hazardous POlymerization Product will not undergo hazardous polymerization. Hazardous Decomposition . May form: carbon dioxide and carbon monoxide, various hydrocarbons. Chemica1 Stability Stable. fnoompatibility Avoid contact with: strong oxidizing agents. / ,l '~, , 1 .~ ,/, .\: I~" "~I t @~ ..I,~, .' ., t i . ,': , , . -.ì. ,~ ',i ,¡ ,~ j; ~! J .,:~ ,...., ~ I ~ : ~ ""I 11. TOXICOLOGICAL INFORMATION' \..,..' No data 12. ECOLOGICAL INFORMATION No data 13. DISPOSAL CONSIDERATION Waste Management InÝormation Dispose of in accordance with all applicable local, state and federal regulations. 14. TRANSPORT INFORMATION DOT Information - 49 CPR 172.101 :OOT Desoription: Not Regulated Container/Hode: CASES/SURFACE w NO EXEMPTIONS NOS Component: None .:~ '~ '" I . .~ 'J) Continued On Next Page ,..'> " P.6 t'JOV 07 ' 00 08: 22 ?ERVICE OIL CO '. . , . . '. .~ ~.,Tbe Valvoline Company MATERIAL SAFETY DATA SHEET }?age 006 Date Prepared: 03/04/98 Date Printed: 10/03/98 MSDS No: 505.0173308-012.009 HP GEAR 85-140 RQ (Reportable Quantity) - 4~ CFR 172.101 Not applicable \...-' 15. REGULATORY INFORMATION VS Federal ReguIQtions TSCA (Toxio Substances Control Aot) status TSCA (UNITED STATES) Tha intentional ingredients of this product ar$ listed. CERCLA RQ - 40 CFR 302.4 None SARA 302 Components - 40 CFR 355 Appendix A Nona Section 311/312 Hazard Class - 40 CPR 370.2 Immedlate(X) Delayed() Fire() Reactive() Sudden Release of Pressure( ) SARA 313 Components - 40 CF~ 372.65 None Internationa1 Regulations Inventory Status DSL (CANADA) The 'intentional ingredients of this produc.t arã listed. state and Looa] Regulations California Proposition '5 None 16. OTHER INFORMATION The information acc.umulated he]~ein is believed to be accurate but is not warranted to be whether originnting with tbe company or not. Recipient$ are advised to confirm in advance of need that the. informa.tion is current, applic.able, and suitable to thilÌr c.ircumstances. .~, Last Page , \ i. t~ \ll' ", , '~i' i ~' ,:t ,f. '.! , :ï ~/I . '~ ~, " ~' \ 1~·¡ .' ~ ,~ " , 'J) ;, j\ 'I ! ',-I ~I '~ " " ji t1 ;\ Jt ,If '~ .:a¡ :;f1 {- :.í , ~, "., HI\ ..JI ~. ~ .,' .- . ~. ...~ ~!' .. ...À' - -,- IN.::TUR. Y PREVENTION PROGR..AM 'HITTON CONSTRUCTION ASPHALT PAVING & GRADING PROGRAMA. DE PREVENCION DE LESION · - ; .. .' T_D_ WHITTON CONSTRUCTION, INC_ INJURY PREVENTION PROGRAM TABLE OF CONTENTS INTRODUCTION Page 1 A. SUPERVISORY RESPONSIBILITIES Page 3 B. EMPLOYEE RESPONSIBILITIES Page 4 C. SAFETY WALK-THROUGH Page 4 D.. TERMINATION PROCEDURE Page 5 E. THEFT Page 5 Page 5 F. PERSONAL PROTECTIVE EQUIPMENT G. CLOTHING Page 7 H. PERSONAL SAFE WORK PROCEDURES Page 7 I. TRAINING/FITNESS Page 14 J. TRANSPORTATION & SAFE FUELING Page 14 K. SIGNS Page 16 L. ALCOHOL, ILLEGAL DRUGS AND WEAPONS Page 16 N. EMPLOYEE INFORMATION BOARD Page 17 Page 17 M. FIRST AID O. HAZARD COMMUNICATION PROGRAM Page 17 , -. T_D_ WHITTON CONSTRUCTON INC_ PROGRAMA DE PREVENCION DE LESION LA TABLA DE CONTENIOOS INTRODUCCION La pagina 22 A. RESPONSABILIDADES RELATIVES A LA SUPERVISION La Pagina 24 B. LAS RESPONSABILIDADES DE EMPLEADO La Pagina 25 C. EL PASEO DE SEGURIDAD A TRAVES La pagina 25 E. ROBO La Pagina 26 La Pagina 26 D. PROCEDIMIENTO DE TERMINACION F. EQUIPO DE PROTECTIVO PERSONAL La pagina 26 G. VESTIDOS La Pagina 28 La pagina 28 H. PROCEDIMIENTOS DE TRABAJO Y SEGURIDAD PERSONALES I. ENTRENAMIENTO Y ADECAUCION La Pagina 36 La Pagina 36 J. TRANSPORTACION K. SIGNOS La pagina 38 L. ALCOHOL, DROGAS Y ARMAS ILLEGALES M. PRIMEROS AUXILIOS La Pagina 38 La Pagina 39 N. TABLERO DE INFORMACION DE EMPLEADO O. PROGRAMA DE COMUNICACION DE PELIGRO La Pagina 39 La pagina 39 · ~ ,~ T.D. WHITTON CONTRUCTION, INC. INJURY PREVENTION PROGRAM INTRODUCTION The welfare of our employees is of strong interest to us. Accordingly, it is important that each individual recognize and obey certain rules when doing their job. The rules included in this manual are basic and general in nature and cannot cover every possible working condition. Additional local rules and procedures may apply in certain circumstances. You should consult with a T.D. Whitton Construction, Inc. Supervisor, on safety procedures before proceeding with your work. The cooperation of each employee is a necessity so that operating procedures and work methods do not expose you or your co-workers to injury. Remember that safety is a team effort in which each individual must share to eliminate or reduce the risk of loss or damage to personnel or property. Good judgment and common sense are required to supplement any rules. T.D. Whitton Construction, Inc. intends to maintain an independent relationship with each employee while insisting on good safety performance. If you are in doubt at any time about safety, consult your employer. T.D. Whitton Construction, Inc. believes that all activities should be governed by the principles on the following pages and expects each person working for T.D. Whitton Construction, Inc. to understand and accept them. 1 ; WORKPLACE SAFETY PRINCIPLES 1. All work can be done safely. 2. All accidents and injuries can be prevented. 3. The'workplace will be free from unreasonable risk. 4. Each worker must understand his task and how to accomplish it safely. 5. No business objective, is more important than the safety of people. 6,. Unsafe acts in the performance of your work are neither expected nor condoned. 7. Each person has the responsibility for his own safety as well as the safety of his associates. T.D. Whitton construction, Inc. will maintain an effective injury prevention program. The program will include a minimum: 1. commitment to safety by management through engineering controls, administration controls, and personal protective equipment 2. Safety training 3. Safety monitoring 4. Regularly scheduled safety meetings 5. Comply with all applicable Governmental rules and regulations 6. Safety walk-through inspections quarterly 2 " A. T. D. WHITTON CONSTRUCTION, RESPONSIBILITIES INC. SUPERVISORY 1. Marty Whitton of T. D. Whitton Construction, Inc. is responsible for seeing that proper instructions, equipment, training and guidance in correct work procedures are provided to each employee. All employees will be trained initially, and thereafter, all new employees, and all employees given a new job assignment, and when new substances, processes, procedures, or equipment are introduced to the workplace. Labor Code 6401.7(1) and 6401.7(4) 2. Unless otherwise specified, T.D. Whitton Construction, Inc. is responsible to provide you with tools and equipment including personal protective equipment which are appropriate for the purposes intended. Employees will replace any tools and equipment which is lost by them. New tools and equipment will be provided to any employee upon the return of the broken tools and equipment. Labor Code 6401.7(3) 3. T. D. Whitton Construction, Inc. supervisor, Marty Whi tton, and onsi te foreman are responsible for enforcing all rules which are contained in this manual and all regulations and rules of your employer which apply to the operation for which your supervisor is responsible. Labor Code 6401.7(6) 4. Martha Tucker of T. D. Whitton Construction, Inc. has the responsibility to provide T.D. Whi tton Construction, Inc. and our clients with a written report of any accident or injury to contract personnel as soon as possible following the accident (within 24 hours). Labor Code 6401.7(2) 5. T.D. Whitton Construction, Inc. field supervisors are responsible for safely planning the work. Should an unexpected hazard develop during the course of the job, the supervisor has the responsibility to stop work until the hazardous condition can be corrected. Should any unsafe condition be discovered, corrections will be made immediately, when possible, by company personnel or by outside contractors when 3 · company personnel are not qualified. Code 6401.7(2) and 6401.7(3) Labor 6. T.D. Whitton Construction, Inc. field supervisors are responsible for holding "tailgate safety sessions" at least every 10 working days. Labor Code 6401.7(5) 7. A T.D. Whitton Construction, Inc. supervisor is responsible for consul ting wi th our client's representative on jobs where safety is in question. Labor Code 6401.7 (1) and 6401.7(6) B. EMPLOYEE RESPONSIBILITIES 1. Each employee must read, be thoroughly familiar with and understand the contents of this manual. Labor Code 6401.7(6) 2. Each employee shall follow safe procedures for the work being performed, conduct operations safely and immediately report any unsafe conditions or practices without fear of reprisal to his foreman, supervisor or proper authority. ,3. Employees are expected to assist each other, especially new employees, in safely performing their work. 4. Each employee shall report any accident or injury to his supervisor as soon as possible. Labor Code 6401.7(5) C. SAFETY WALK-THROUGH (Labor Code 6401.7(2) A safety walk-through program shall be conducted a minimum of once each quarter. Marty Whitton will work with safety consultants in problem solving. Documentation of findings and corrections will be t.D. WHITTON CO kept in a saf~ty File at t~e company headquarters ~01MB NST.t4NC~763 s. Wh1tton, Bakersf1eld, CA. IAKERSFlf Lf RD. LO, CA 9331Addi tional safety walk-throughs may be made by outside independent consultants if management deems necessary. 4 " D. TERMINATION PROCEDURE FOR SAFETY VIOLATIONS (Labor Code 6401.7(6) 1. Oral warnings given three (3) times for failure to follow proper safety procedures - documentation to file 2. written warnings (2) - documentation to file 3. written termination notice - documentation to file Blatant disregard for company safety policy resulting in an injury can be cause for immediate dismissal. In the event an employee is terminated, he must receive his paycheck at that time. E. THEFT Incidents of confirmed theft or unauthorized removal of property belonging to T.D. Whitton Construction, Inc. will be reported to legal authorities and will result in immediate termination. F. PERSONAL PROTECTIVE EQUIPMENT (Labor Code 6401.7(6) Specific items of personal protective equipment are required apparel while on the job. In other instances, the work activity, local environment or unit policy will dictate the need for additional items of personal protective equipment. This protective equipment will be inspected daily by the user. These requirements may include, but are not limited to, the following: 1. Head Protection Hard hats are required at all times while on the job except while in vehicles or offices. 5 2. Foot Protection Appropriate safety footwear shall be worn where foot injuries by crushing, falling objects, etc., might occur. Leisure footwear, such as sandals, shall not be worn by shop personnel or by heavy equipment operators. other footwear must be approved by onsi te foreman. 3. Face and Eye Protection Protecti ve spectacles and goggles or face- shields are to be worn when performing work which could injure your eyes. Such work would include, but not be limited to, welding, cutting or when there is airborne debris due to high winds. Sunglasses are not considered goggles. 4. Hand Protection Gloves are to be worn to protect the hands against extremely hot or cold equipment, and sharp edges. 5. Respiratory Protective Equipment a. T. D. Whi tton Construction, Inc. is responsible for providing you wi th appropriate protective breathing equipment for the work to be performed. You must wear respiratory equipment whenever you enter or work in an atmosphere known or suspected to contain dangerous concentrations of gas, vapor, dust or mist or when there is a deficiency of oxygen. Work will not normally be permitted in atmospheres that are immediately dangerous to life or heal th (IDLH). Where IDLH conditions cannot be eliminated, special procedures shall be developed for the work. The procedures are required to be approved by aT. D. Whitton Construction, Inc. supervisor prior to entry into the IDLH atmosphere. b. When you are required to wear or use any breathing equipment you must have a good face seal for the equipment to be 6 .' effective. Beards and other facial hair such as long sideburns are not allowed due to the possibility a worker may be required to use a respirator at any time. c. Whenever a self-contained breathing apparatus (SCBA) is required, a standby person who is appropriately equipped and trained shall be at the worksite to give assistance in the event of emergency. For further information, please refer to General Industry Safety Order (GISO) 5144. G. CLOTHING (Labor Code 6401.7(6) Each employee shall wear clothing appropriate for the work to be performed. contaminated or oil saturated clothing shall be changed as soon as possible. Loose or frayed clothing will not be worn at any time around the shop or equipment. Sleeveless shirts, tank tops, and shorts are not permitted. Full length pants and shirts are mandatory in shop and equipment areas. Shop employees must wear long sleeved shirts. Neckties, neck chains, loose jewelry and rings shall be removed when working around moving/rotating machinery. H. PERSONAL SAFE WORK PROCEDURES 1. Housekeeping Employees are expected to keep the worksi te clean and orderly. Emergency access and egress ways shall not be obstructed. Trash and debris shall be cleared away as it accumulates (at least daily). contaminated waste shall be handled in a proper manner and taken to a proper disposal facility. 2. Slips, Trips, and Falls a. Be aware of the hazards around you taking care to walk around them or step over them if they cannot be removed. b. Report any hazards which you may find. 7 c. Do not overreach causing you to lose your center of balance. d. When the surface is wet take short steps and make wide turns at corners. Wear slip-resistant shoes if necessary. e. If you create a spill or find one, either clean it up or mark it until it can be cleaned up. f. Don't walk pockets. balance. with Keep your your hands hands in your free for g. Keep work areas well lit and free from clutter. h. Use proper equipment for the job. Don't use makeshift ladders. i. Don't leave tools lying around. 3. Lifting and Carrying To protect your back always use proper techniques to lift and carry. a. Bend with your knees and hips keeping your back straight. Use the legs to lift and lower. Do not lean from the waist. b. Do not try to lift more weight than you can easily handle and keep load close to the body. c. Wear protective gloves if necessary. d. Keep your back straight when carrying a load. Maintain good balance by counterbalancing your load by shifting part of your body in the opposite direction. 4. Repetitive Motion Injuries a. To avoid wrist and hand injuries caused by repeti ti ve motion choose tools that fit your hand, are properly shaped, and produce ~he least amount of vibration. b. stand above the object. 8 c. Use as much of your hand as possible reducing finger strain, keep your wrist straight, and try alternating hands when one becomes tired. d. Reduce elbow and shoulder injuries by keeping your elbows bent. This keeps loads close to your body and puts less weight and pressure on your shoulder. e. Use as much of your arm as you can while keeping your wrist straight. f. Don't lock your elbow when working over your head. By making broad arm strokes less of your forearm is used taking force off your elbow. 5. Lock-OutjBlock-Out Lock-out and block-out procedures are essential to prevent accidental movement of machinery or contact with energized electrical equipment. a. Lock-out Turn off and padlock the MAIN energy source. Attach a tag with pertinent information concerning the Lock-out to the padlock. b. Block-Out Block equipment that could fall, slide, roll, descent, rotate, or otherwise move. Use blocks, chains, or other equipment of sufficient strength to support or stop the movement. 6. Electrical Safety a. Be certain when serv1c1ng, maintaining, or adjusting electrical equipment that the switches are opened, locked-out and tagged. b. Portable tools and equipment must be grounded or of the double insulated type. c. Extension cords must have a grounding conductor. 9 " d. Never use multiple plug adaptors or flexible cords and cables that have been altered. e. Check all cord, cables, etc., for any exposed wiring or deterioration of any type. f. Do not use metal ladders, metal measuring tapes, ropes, etc., with metallic thread where they can come in contact with energized parts of equipment or circuit conductors. g. Do not block labels on disconnecting switches and circuit breakers. h. Always open disconnecting means before fuses are replaced. i. Take care not to block mqtor disconnecting switches or circuit breakers. j. In wet or damp locations, make sure that electrical tools and equipment are appropriate for the use or locations or otherwise protected. k. Watch for standing water when working with electrical equipment. 7. Compressed Gas Cylinders a. Do not block identifying label on cylinders. b. store cylinders in areas where they are protected from external heat sources, falling objects or tampering. c. When storing or transporting be sure the safety relief device is always in direct contact with the vapor space in the cylinder. Prevent cylinders from tipping, falling or rolling. d. Valve protectors should be placed on cylinders when not in use or connected for use. 10 " e. Close all valves before' moving a cylinder, when the cylinder is empty and at the completion of each job. f. Check cylinders periodically for corrosion, distortion, cracks or other defects. Be sure to inspect the bottom of the cylinder. 8. Welding and cutting a. Only those personnel who are qualified by training and experience shall be allowed to operate any welding equipment. b. Bystanders should be cautioned not to look directly at the arc. c. Metal ladders are not to be used during any welding procedures. 9. Tractor Safety Only those personnel who are qualified by training and experience shall operate tractors. Training will be annually. a. Have Roll-Over Protection (ROPS) and use seat belt. b. Reduce speed on slopes and turns; avoid driving near embankments and steep slopes. c. Keep Power Take-Off (PTO) shield in place. d. Only one person to a seat - no riders. e. Shut off engine when you leave the driver's seat. f. Hitch only to the drawbar. g. Operate equipment when well-rested and sober. 10. Graders a. Only those personnel who are qualified by training and experience shall be allowed to operate graders. 11 Co' b. Equipment operators shall use adequate respiratory protection when needed. c. Keep equipment under control at all times and keep in gear when descending grades. d. Do not drive at a speed greater than is reasonable and proper with due regard for weather, traffic, roadway characteristics, etc. e. Make sure required warnings are displayed on machine when roading. f. When scarifying across a slope, keep blade crossway and carry it low to provide some protection against tipping. 11. Skip Loaders a. Only those personnel who are qualified by training and experience shall operate skip loaders. b. All persons involved with skip loaders should be aware of underground lines. 12. Loaders a. Only those personnel who are qualified by training and experience shall operate loaders. b. Observe gauges, instruments, and warning lights to assure that they are functioning and their readings are within the operating range. c. stay in the operator's seat at all times when operating and keep your seat belt/operator restraint fastened when operating a machine. Be in control of your machine at all times. d. Operate at speeds slow enough so you have complete control at all times. e. Avoid sideslope travel whenever possible. Drive up and down the slope. In steep slope operation, do no tallow engine to over speed. Select proper gear speed before starting downslope. 12 13. Hydraulic Excavator a. Only those personnel who are qualified by training and experience shall operate heavy equipment. b. All persons involved with excavators should be aware of electrical lines. c. Never attempt to operate the excavator except from the approved operator's position. d. Do not load a truck unless the driver is in a safe place. e. Avoid swinging or extending the bucket farther than necessary in a downhill direction. f. Never exceed manufacturer's recommended bucket size. 14. Truck Safety a. Check engine oil, radiator water, and tires, lights, brakes., etc. daily. b. No truck will be driven faster than the posted speed limit - loaded or empty. c. Drivers are required to wear their seat belts. d. Passengers are not permitted without prior authorization. e. The parking brake shoüld be set and any other steps taken to keep the truck from moving before the driver leaves it unattended. f. After making an emergency stop, driver has ten minutes to put emergency warning devices. the out g. Fuses may not be attached to any part of a truck. h. Use headlights one-half hour after sunset and one-half hour before sunrise or anytime there is not enough light to see 13 clearly 500 feet away. Lights and reflectors are to be kept clean. 15. Roller compactors a. When roading or operating a machine, always stay in the operator's station. Never mount or dismount a machine that is moving. Maintain control of your machine at all times. b. Never jump on or off the machine. the steps and handholds provided. Use c. Be alert to potential caving edges, falling rocks and slides. d. When loading, always use adequate strength. Be sure sufficiently wide, and long provide a safe loading slope. e. only those who are trained and qualified, shall operate Roller Compactors. ramps of ramps ~re enough to I. TRAINING/FITNESS (Labor Code 6401.7(4) T.D. Whitton Construction, Inc. employees are physically fit for the job to be performed and have been trained and qualified to perform the work. J. TRANSPORTATION AND SAFE FUELING By Motor Vehicle Practice defensive driving and good vehicle mainte- nance at all times. 1. Use of seat belts is required for all T.D. Whi tton Construction, Inc. employees. Any employee who receives a citation for not wearing a seat belt will be solely responsible for that fine. 2. No passengers, other than authorized employees, are permitted in vehicles. 3. Adhere to speed limits. Speeding will not be tolerated. 14 T------ 4. To properly park a vehicle: o turn off engine o set emergency brake o transmission in park (auto) or in gear (manual) o some locations and/or equipment require back in or drive through parking. Check with local supervision o chock wheels, if necessary, to prevent movement of vehicle o trucks having rear V1S1on impairment; i.e., welding trucks, cranes, etc., must have a back-up alarm device which is operational 5. Make sure engines are shut off before fueling. 6. Should a spill occur, it must be contained removed according to local, county, state, federal laws. Check with management proper procedure. and and for 7. Replace fuel tank cap before starting the engine. 8. Do not handle or transfer gasoline in open containers. 9. Take care that no open lights, open flames, or sparking or arcing equipment are near fueling operations. 10. Do not smoke in the vicinity of fueling operations. 11. Do not fuel any equipment in enclosed areas that are not specifically ventilated for this purpose. 12. NEVER tow a trailer without securing the connecting parts. Safety chains must ALWAYS be used. 13. All gasoline containers must be DOT approved. 15 K. SIGNS (Labor Code 6401.7(6) T.D. Whitton Construction, Inc. personnel need to be especially conscientious to observe all posted signs and warnings. L. ALCOHOL, ILLEGAL DRUGS & WEAPONS (Labor Code 6401.7(6) The use, possession, transportation, promotion or sale of illegal drugs, controlled substances without a valid prescription, and/or drug paraphernalia by anyone while on "company premises" or off duty is absolutely prohibited. Any employee using prescribed medication must notify a T.D. Whi tton Construction, Inc. supervisor. Except where specifically authorized, the use, possession, or transportation of alcoholic beverages, firearms or weapons is also prohibited. Violation of these rules by an employee while on company business or premises will be cause for disciplinary action up to and including discharge and referral to law enforcement agencies. T.D. Whitton Construction, Inc. employees who violate these prohibitions will not be allowed on "company premises" and may be referred to law enforcement agencies for their action. The term "company premises" in this notice is used in its broadest sense and includes all land, property, buildings, structures, installations, cars, trucks, and all other means of conveyance owned by or leased to T.D. Whitton Construction, Inc. or otherwise being utilized for company business. Entry onto "company premises" constitutes consent to and recognition of the right of the company and its' authorized representatives to search the person, vehicle, other property of individuals while entering, on, or departing "company premises". Such searches may be initiated by the company without prior announcement and will be conducted at such times and locations as deemed appropriate. Refusal of an individual to cooperate will result in appropriate disciplinary action. 16 M. FIRST AID First aid supplies for small injuries are kept in the shop, the office and in all company trucks for the use of our employees. Call 911 for more serious injurie~. N. EMPLOYEE INFORMATION BOARD (Labor Code 6401.7(5) An employee information board will be set up in a conspicuous area where all required California and federal notices may be posted, such as the Workman's Compensation Notice, Discrimination in Employment signs, Pay Day Notice, Emergency Phone Numbers, etc. O. HAZARD COHMUHICATION PROGRAM (Labor Code 6401. 7( 5) Company Name: T.D. Whitton Construction, Inc. Address: 8763 s. uðANl,Hn8f!1CC')f$T~tc.CA 93307 4801 WIBLE RD. BAKERSFIELD, CA 93313 1. Person responsible for the Hazard Communication Program: Marty Whitton 2. Inventory of hazardous substances is located at: . TrO- WHItTON. CONST., INC. . Off1ce at ~63~1~!R!, BàKersf1eld, CA BAKERSFIELD, CA 93313 3. ,Material Safety Data Sheets (MSDS) for all hazardous substances are located at: Office at 8763 S. Union, BakIïPš)yJf~~~f&~~T.IINC. BAKERSFIELD CA 9::1313 A copy of the Hazard Communication Standard (GISO 5194) and company program are kept with the MSDSs. 4. Employees may review MSDSs and the Standard by following this procedure: Ask Martha Tucker 17 :i ~ MSDSs not on hand which are requested by employees will be requested of suppliers within seven (7) days by letter. 5. The MSDS filè is updated with new information and new hazards identified by: Martha Tucker Any new hazards will be reported immediately to: Marty Whitton All affected employees will be notified within 30 days 6. containers of hazardous materials entering the plant will be checked by: Martha Tucker This will assure that they are properly labeled with the chemical name of the contents, the appropriate hazard warning, and the name and address of the supplier or manufacturer. Labels on incoming containers are not to be removed or defaced. containers without labels will not be accepted. 7. In-plant containers of hazardous materials will be labeled with the chemical name and hazard warning. Exceptions must be approved by: Marty Whitton The following exceptions have been approved: None at Present 8. Non-routine tasks materials are: involving hazardous / None at Present 18 .. Procedures for complying with the Hazard Communication standard for these jobs are the following: None at Present 9. Employee training is provided initially to all employees. This training covers the following areas: a. The basic requirements of the Hazard Communication standard and their right to information on chemical hazards. b. Our company's program to comply with the Standard, and procedures to follow to see the Standard, company program, and MSDSs. c. How to interpret and use the labels on containers of hazardous materials. d. The potential physical hazards and health effects of the hazardous substances and how to use MSDSs for more information. e. How to handle the hazardous substances safely and other protective measures in place. f. What to do in an emergency, release or over-exposure to the chemicals. g. How the presence of hazardous chemicals can be detected in the work area. 10. This training is documented in the following manner: Roll sheet and individual records signed and kept in the employer's file Records are maintained at the following 1.0. WHI'M'ONCO~;ation: ~1M8lE~I~MC.at 8763 s. Union, Bakersfield, CA . SFlEI.D, CA 83313 11. Training concerning new hazards (new chemicals or new information on MSDSs) will be provided within 30 days and documented. 19 t, 12. Periodic refresher training will be provided and documented as follows: Annually recorded by signup sheet and indi- vidual records signed and kept in the employer's file 13. Outside employees (subcontractors and visitors) will be advised of chemical hazards in our plant in the following manner: Posted Notices Contractors will be required to provide infor- mation on any chemicals used in our facility as a condition of their contract. Our company relies on the MSDSs as permitted 1:>Y the Standard and does not determinations. Reviewed information contained in OSHA Hazard Communication perform independent hazard and approved: Date Owner 20 t.> NOTICE TO ALL EMPLOYEES Access Safet.y t.o Mat.erial Dat.a Sheet.s BY CAL/OSHA REGULATION - GENERAL INDUSTRY SAFETY ORDER 5194 YOU, YOUR PHYSICIAN, AND YOUR COLLECTIVE BARGAINING AGENT HAVE THE RIGHT TO SEE AND RECEIVE COPIES OF: Material Safety Data Sheets for substances used in the workplace that are on the State Department of Industrial Relations Director's List of Hazardous Substances (Section 339, Title 8, California Administrative Code) Attached is a list of substances present in this employment which are on the Director's List of Hazardous Substances. Material Safety Data Sheets are available at: Office at 8763 S. Union, Bakersfield, CA T.D. WHITTON CONST. 'NC 4801 WIBLE RD' · BAKERSFIELD, CA 93313 FROM: Martha Tucker Copies of General Industry Safety Order 5194 and the Director's List of Hazardous Substances are available from: Martha Tucker NOTE: No employee may be discharged or discriminated against in any way for exercising the rights afforded them under the Hazardous Substances Information and Training Law 21 :,b :; ......<0-.. EMPLOYEE RECEIPT OF INJURY PREVENTION PROGRAM I have received a copy of the T.D. Whitton Construction, Inc. Injury Prevention Program and acknowledge that I have read this program or it has been read to me and I am familiar with its contents and will abide by its guidelines. Name Date Signature T.D. WHITTON CONST. 'He. 4801 WIBLE RD. Of BAKERSFIELD, CA 93313 , ,~ föDDI~~tt®e-C@.m(8n~·~tm©Ð General Engineering o \'''f~; )-..\. :=J..- ,: " ".." ' !.\~\ _J;! -< _,', P,',. ' ~'" """, ,',,',' " ",!, r.,,";:~,: '" f:¡'\ ",¡¡¡,;,¡m'wo,;': :~ " ,""'" 'V""'.." C" "".,", '" ' /':\C~~);.':~:::.,,~~" ',.,,; ,:' "."'--"" .¡ ~j~'~"Jjt~¡l'~:"" ","""'0': "'_C',' "'., ' "(1' . .,.~. \. '., :.':,:~: ;,';" .~';';,:,','~' , ,1iI,II!~_" :1'~;J'1ií ';,~ ,,::' '(O::,CD:~~ ·,ft .,.¡¡¡¡",¡¡.~ :.<~',;,~-."'-,.- ~.<, :Id.'\~<"" .,,'~, ~.'."','.",:ì,I!J,~",:,,, "'liS"'" . :)' ~'--l~' r¡:./J., o-='~"j, "J:~'~, ,.:""." ,," , ~ <. . ;.~::' .,-~ I \!'": ~. ..~ , "',' ,~,' ,. r) , , '111e ',".'(' C" ~'"t~ '\ " ; ,- IC...:·;_~) Contractors License 681947 The combination of Vulcan Materials/CalMat Division and Topcon Laser West, keep us a GRADE above the rest. 4801 Wible Rd. Bakersfield, CA 93313 Phone (661) 834-5894 Fax (661) 834-7001 Ø'TOPCOI\ &ASER:WEST . Laura & MïiëhineCòntrol UulEan MåterlalsComp¡¡ny " _.~, ,'o""'i' ~--- In 1982, T.D. Whitton Construction Inc. began serving Kern County with complete site-work capabilities for demolition, earthwork, underground drainage, asphalt paving, and related needs. As our company has grown, our area of operation has, expanded to include F,tesno, Kings, Tulare'iil!(FLos Angeles counties. ~¡,~ ',. -- ,-- I .. ~~ _ó~il,al!~"operat~:,the 'most I)}-:)dern equipment t~ assuré"on-tim~'completion ofý~ur: job ~ithin -- ~(nlr b!l~g"t..';, ~Our extensivet'l~et hicl1Jdës /:v,ariòus. ,:~~ '·of:;:éa-;1hmovers and gradeì;s;,'" ·~spIiålt· -":p~vers; ,:ëompactors, and suppoÌ1ilÍg dúmp truèkS, Jö~4ieds, water trucks, bottom dumps, transfers, etc.. Our philosophy is simple: competitive prices and quality work means repeat customers. We can provide a list of satisfied customers, and we would like your firm to be on this list as well. . Rip Rap Placement · Storm Drain Levee'Repair · . Reclamite · Excavation . Fog Seal Marty D. Whitton, President I ., I Travis D. Whitton, Chairman I I T.D. Whitton Constructi~n, ~nc. As halt Paving - General Engmeermg 4~01 Wible Road - Bakersfield, CA 93313 License #681947- A " .,',-",C·'<=:;-,-Vr[ .' \' ¡ 1 ¡ ) ~ 't, 11 ¡.~ ~ :r__-:, I,' j" '¡, f=-'--' {: , ',' . ~~:::: L' r~£'~,;',:;.~',. ,"-',,; " ,",': ~'?,~'.',- ~', ,}¿,1)'\~~" J'~ ' 't , (, ': -" ,,' I :" >,1 - ':.~: ~:~;.~l.' ,2;':.-" / ,i - - :.- ~....~, (661) 8"34·5894 OFFICE (661) 834-7001 FAX TDWHITTON@AOL.com :D\~ ;Urn.~-e.sS 9+cP FC>RPhIJN"---" J __ '--., ~ ._~'-- .... r.D. Whitton Construction, Inc. Asphalt Paving - General Engineering License #681947-A ~ Marty Whitton 4801 Wible Road Bakersfield, CA 93313 Location map on reverse side (661) 834-5894 OFFICE (661) 834-7001 FAX tdwhitton@aoLcom --- - --- .--. --'- -- --- ---~ - N W+E S MING AVE WHITE LAN£ ... 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