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Home My WebLink AboutBUSINESS PLAN Per it Operüte to Hazardous Materials/Hazardous Waste Unified Permit CONDITIONS OF PERMIT ON REVERSE SIDE Permit ID #:: 015-000-001510 SAMPSON STEEL LOCATION: 701 WILLIAMS ST Issued by: Bakersfield Fire Department OFFICE OF ENVIRONMENTAL SER VICES 1715 Chester Ave., 3rd Floor Approved by: Bakersfield, CA 93301 Voice (661) 326-3979 FAX (661) 326-0576 Expiration Date: This oermit is issued for the following: It! Hazardous Materials Plan o Underground Storage of Hazardous Materials o Risk Management Program o Hazardous Waste On-Site Treatment Issue Dale June 30, 2003 e 5 \~ (0 .:PlSlD =@D- µ $TÞ£ÞrL7 7l-\a !> I H ÞO.z.ÞA.Þ.?\JS l1þ,í /.. Lf'Þ<\~r - ot..D ~ ¡..!a! n-\ µ~6P. ) tl. Ô c::I Q Þf' er--1 ~He.'C " ,c,o\/e(1..s 0 ~Ðp¥- UJ-eþ. ( O~N) T Q t 'C;:>þ"~ 1-1 Â\ N (...c;t-.l~ ~t1 ~ l1) 1 t:1£L.;:( '\24 c... MAl o..J 6C'¡( Otl- ~Þo,;'fe~ r--\P.IN ....,,~ f t= Lyre:) 2i: 1= t-Ð--r2.1 L Mþo.\o..J ~FF'U ~ & c"oYGP-eD )..1Þ?-\.L. ÞO:;~e: ~ (~r-e~) I M~'µ UTI UiY , p.oO!",,\ _\ ~ ~' 7 : ~.sí· 0fI- ~ ~ (\ ð II J. ~ \U ~ 4. ti ~ t- \\ ~\E. ~ ~Ð t>íILI-p.( bb..~ SEf2-V,G.e o-J D.>T\ , ,0i+- I "'" p.:~ e: "I¡..,rf ~ r , I l ~Jb f"Þ<~eL.l.;;>C>,,~ 10\ j.l\u..-.,~~~ CS,.. SAMPSON STEEL CONSTRUCTORS, INC. 3220 Rio Miradø Drive · Bakersfield, California 93308 · Office - 661.631,8979 · Fax - 661.631.2868 ~ N~'· -- . ~ ~ _;.;::;:...~__u__ ......._-' ".h ,~~. ~ ~ ~ r f¡ I, ~ I' ~ ¡ i : 5Tðr9.;J-e $/¡ed .j covered ope/1 Wor Ir or€O ~ ~ c i Ll/nc.A Y()OFÞ? I ¡ Of4c. ~ ¡ i i ¡: ~ " ~ i " ~ I ~ g'\ "- (~ '" /,--,-- r 'f!. ~ T r()ðli"/ of --.,) / j " ,i \ t. -"'--~ "'<; ::Ji~ ~ ./ '- -~..~~~- Wo'OD'C1~J sr¡reer c~ ~(¿,3 · . + SAMPSON STEEL ======================================= S1teID: 015-021-001510 + ,"'- ~ .'Ì Manager Location: 701 WILLIAMS ST City BAKERSFIELD BusPhone: Map : 103 Grid: 28C (661) 631-8979 CommHaz : Minimal FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 02 EPA Numb: SIC Code:3441 DunnBrad:36-127-2727 +==============================================================================+ +=======================================+======================================+ Emergency Contact / Title Emergency Contact / Title MIKE HOCKSTED / PLANT MANAGER TONY LEON / MAINTENANCE Business Phone: (661) 631-8979x Business Phone: (661) 631-8979x 24-Hour Phone : (661) 201-8139x 24-Hour Phone : (661) 201-8182x Pager Phone : () x Pager Phone : () x +---------------------------------------+--------------------------------------+ I Hazmat Hazards: Fire Press ImmHlth DelHlth I +------------------------------------------------------------------------------+ Contact : 'Phone: (661) 631-8979x MailAddr: 3220 RIO MIRADA State: CA City : BAKERSFIELD Zip : 93308 +------------------------------------------------------------------------------+ Owner DUNCAN SAMPSON Phone: (661) 631-8979x Address : 3220 RIO MIRADA State: CA City : BAKERSFIELD Zip : 93308 +------------------------------------------------------------------------------+ Period to TotalASTs: = Gal Preparer: TotalUSTs: Gal Certif'd: RSs: No +------------------------------------------------------------------------------+ Emergency Directives: JR SHORT GENERAL MANAGER. +==============================================================================+ += Hazmat Inventory ========================================= One Unified List + +== Alphabetical Order ================================= All Materials at Site + +--------------------------------+-------+-----------+-----+----------+----+---+ I Hazmat Common Name... ISpecHazlEPA Hazards Frm I DailyMax IUnitlMCpl +--------------------------------+-------+-----------+-----+----------+----+---+ ACETYLENE E F P IH G 30.00 FT3 Hi LUBRICATING OIL F DH L 55.00 GAL Min OXYGEN F IH DH G 15.00 FT3 Low WASTE DIESEL F L 55.00 GAL Mod WASTE OIL F DH L 55.00 GAL Low 5\10 LoN<6-VL IN - ..... B ù ~( Ñ 'Z.5 .s- t4 r I h. I S Loc.ft: ìt oN +==============================================================================+ -1- ~~ 03/27/2002 .. ¡ e e + SAMPSON STEEL ======================================= SiteID: 015-021-001510 + += Inventory Item 0002 =============== Facility Unit: Fixed Containers at Site + +== COMMON NAME / CHEMICAL NAME ==============================+================+ ACETYLENE I Days On Site I 365 +----------------+ I CAS# I 74-86-2 +=============================================================+================+ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+==== CONTAINER TYPE =====+ I Gas I Pure I Above Ambient I Ambient I PORT. PRESS. CYLINDER I +=========+==========+===============+===============+=========================+ +==========================+ AMOUNTS AT THIS LOCATION =========================+ I Largest Container I Daily Maximum I Daily Average I 15.00 FT3 30.00 FT3 20.00 FT3 +==========================+=========================+=========================+ +=======+============== HAZARDOUS COMPONENTS ==============+===+===============+ I %Wt. I IRS I CAS# I 100.00 Acetylene Yes 74862 +=======+==================================================+===+===============+ +=======+===+======+=========== HAZARD ASSESSMENTS ===+=========+========+=====+ I TSecretI RSIBioHaz Radioactive/Amo~nt I EPA Hazards I NFPA I USDOT# I M~P I No No No No/ Curles F P IH / / / Hl +=======+===+======+====================+=============+=========+========+=====+ Location within this Facility Unit VARIOUS LOCATIONS Map: Grid: += Inventory Item 0001 =============== Facility Unit: Fixed Containers at Site + +== COMMON NAME / CHEMICAL NAME ==============================+================+ LUBRICATING OIL I Days On Site I PETROLUEM BASED LUBRICATING OIL/AF PLUS 30 365 Location within this Facility Unit Map: Grid: +----------------+ STORAGE SHED ON N SIDE OF PLANT I CAS # I 64742-65-0 +=============================================================+================+ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+==== CONTAINER TYPE =====+ I Liquid I Pure I Ambient I Ambient I DRUM/BARREL-NONMETAL I +=========+==========+===============+===============+=========================+ +==========================+ AMOUNTS AT THIS LOCATION =========================+ I Largest Container I Daily Maximum I Daily Average I 55.00 GAL 55.00 GAL 10.00 GAL +==========================+=========================+=========================+ +=======+============== HAZARDOUS COMPONENTS ==============+===+===============+ I %Wt. I I RS CAS# I 100.00 Motor Oil, Petroleum Based No 8020835 +=======+==================================================+===+===============+ +=======+===+======+=========== HAZARD ASSESSMENTS ===+=========+========+=====+ I TSecretI RSIBioHaz Radioactive/Amo~nt I EPA Hazards I NFPA I USDOT# I M~P I No No No No/ Curles F DH / / / Mln +=======+===+======+====================+=============+=========+========+=====+ -2- 03/27/2002 " e e + SAMPSON STEEL ======================================= SiteID: 015-021-001510 + += Inventory Item 0003 =============== Facility Unit: Fixed Containers at Site + +-- COMMON NAME / CHEMICAL NAME ------------------------------+----------------+ -- ------------------------------ ---------------- OXYGEN I Days On Site I 365 +----------------+ I CAS# I 7782-44-7 Location within this Facility Unit W SIDE OF MAIN SHOP Map: Grid: +=============================================================+================+ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+==== CONTAINER TYPE =====+ I Gas I Pure I Above Ambient I Ambient I PORT. PRESS. CYLINDER I +=========+==========+===============+===============+=========================+ +==========================+ AMOUNTS AT THIS LOCATION =========================+ I Largest Container I Daily Maximum I Daily Average I 15.00 FT3 15.00 FT3 10.00 FT3 +==========================+=========================+=========================+ +=======+============== HAZARDOUS COMPONENTS ==============+===+===============+ I %Wt. I· IRS I CAS # I 100.00 Oxygen, Compressed No 7782447 +=======+==================================================+===+===============+ +=======+===+======+=========== HAZARD ASSESSMENTS ===+=========+========+=====+ Tsecretl RSIBioHazl Radioactive/Amount I EPA Hazards I NFPA I USDOT# I MCP I No No No No/ Curies F IH DH / / / Low +=======+===+======+====================+=============+=========+========+=====+ += Inventory Item +== COMMON NAME / WASTE DIESEL 0005 =============== Facility Unit: Fixed Containers at Site + CHEMICAL NAME ==============================+================+ I Days On Site I 365 +----------------+ I CAS# I 68476-34-6 +=============================================================+================+ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+==== CONTAINER TYPE =====+ I Liquid I Waste I Ambient I Ambient I DRUM/BARREL-METALLIC I +=========+==========+===============+===============+=========================+ +==========================+ AMOUNTS AT THIS LOCATION =========================+ I Largest Container I Daily Maximum I Daily Average I 55.00 GAL 55.00 GAL 55.00 GAL +==========================+=========================+=========================+ +=======+============== HAZARDOUS COMPONENTS ==============+===+===============+ I %Wt. I IRS I CAS# I Diesel Fuel No. 2 No 68476302 +=======+==================================================+===+===============+ +=======+===+======+=========== HAZARD ASSESSMENTS ===+=========+========+=====+ I TSecretI RSIBioHaz Radioactive/Amount I EPA Hazards I NFPA I USDOT# I MCP I No No No No/ Curies F / / / Mod +=======+===+======+====================+=============+=========+========+=====+ Location within this Facility Unit WHERE IS IT LOCATED???????????? Map: Grid: -3- 03/27/2002 e e + SAMPSON STEEL ======================================= SiteID: 015-021-001510 + += Inventory Item 0004 =============== Facility Unit: Fixed Containers at Site + +== COMMON NAME / CHEMICAL NAME ==============================+================+ WASTE OIL I Days On Site I 365 +----------------+ I CAS# I 221 +=============================================================+================+ += STATE =+= TYPE ===+== PRESSURE ===+ TEMPERATURE ==+==== CONTAINER TYPE =====+ I Liquid I Waste I Ambient I Ambient I DRUM/BARREL-METALLIC I +=========+==========+===============+===============+=========================+ +==========================+ AMOUNTS AT THIS LOCATION =========================+ I Largest Container I Daily Maximum I Daily Average I 55.00 GAL 55.00 GAL 55.00 GAL +==========================+=========================+=========================+ +=======+============== HAZARDOUS COMPONENTS ==============+===+===============+ I %Wt. I I RS CAS# I 100.00 Waste Oil, Petroleum Based No 0 +=======+==================================================+===+===============+ +=======+===+======+=========== HAZARD ASSESSMENTS ===+=========+========+=====+ ITsecret RS \ BioHaz Radioactive/Amo~nt I EPA Hazards I NFPA USDOT# MCP No No No No/ Curles F DH / / / Low +=======+===+======+====================+=============+=========+========+=====+ Location within this Facility Unit WHERE IS IS LOCATED????????????? Map: Grid: -4- 03/27/2002 e e + SAMPSON STEEL ======================================= SiteID: 015-021-001510 + +================================================================= Fast Format + +- Notl'f /Evacuatl'on/Medl'cal ------------------------------------ Overall Sl'te + -. ------------------------------------ +== Agency Notification =========================================== 03/27/2000 + EMERGENCY NUMBERS ARE POSTED ON THE BULLETIN. +==============================================================================+ +=== Employee Notif./Evacuation =================================== 03/27/2000 + ALL EMPLOYEES (6) ARE TO EXIT TO WILLIAMS ST, DO A HEAD COUNT AND CALL 911. +==============================================================================+ +---- Publl'C Notl'f /Evacuatl'on ------------------------------------ 03/27/2000 + ---- . ------------------------------------ EMPLOYEES ONLY. +==============================================================================+ +----- Emergency Medl'cal Plan ------------------------------------- 03/27/2000 + ----- ------------------------------------- THERE IS ONE FIRST AID CERTIFIED EMPLOYEE OVER AT PLANT #2 TO ADMINISTER FIRST AID UNTIL HELP ARRIVES. +==============================================================================+ -5- 03/27/2002 e e SiteID: 015-021-001510 +================================================================= Fast Format Mitigation/Prevent/Abatemt =================================== Overall Site + Release Prevention ========================================================+ I + SAMPSON STEEL --------------------------------------- --------------------------------------- + + += +-- -- I +==============================================================================+ +=== Release Containment ======================================================+ I I +==============================================================================+ +==== Clean Up ================================================================+ I I +==============================================================================+ +===== Other Resource Activation ==============================================+ I I +==============================================================================+ -6- 03/27/2002 .. e e + SAMPSON STEEL ======================================= SiteID: 015-021-001510 + +================================================================= Fast Format + += Site Emergency Factors ======================================= Overall Site + +== Special Hazards ===========================================================+ I I +==============================================================================+ +--- Utl'll'ty Shut-Offs -------------------------------------------- 03/27/2000 + --- -------------------------------------------- A) GAS B) ELECTRICAL - POWER FOR THE LIGHTS ARE IN THE RESTROOM C) WATER - D) SPECIAL - THE PLANT RUNS ON A DIESEL POWERED GENERATOR E) LOCK BOX - +==============================================================================+ +---- Fl're Protec /Aval'l Water ----------------------------------- 03/27/2000 + ---- .. ----------------------------------- PRIVATE FIRE PROTECTION - ????????????? NEAREST FIRE HYDRANT - SW CORNER ON WILLIAMS ST. +==============================================================================+ +===== Building Occupancy Level ===============================================+ I I +==============================================================================+ -7- 03/27/2002 ~ ~ e e + SAMPSON STEEL ======================================= SiteID: 015-021-001510 + +================================================================= Fast Format + += Training ===================================================== Overall Site + +== Employee Training ============================================= 03/27/2000 + THERE ARE 6 EMPLOYEES AT THIS SITE. DO YOU HAVE MSDS SHEETS ON FILE????????? GIVE A BRIEF SUMMARY OF YOUR TRAINING PROGRAM: +==============================================================================+ +=== Page 2 ===================================================================+ I I +==============================================================================+ +==== Held for Future Use =====================================================+ I I +==============================================================================+ +===== Held for Future Use ====================================================+ I I +==============================================================================+ -8- 03/27/2002 ~~ .- - -~. SiteID: 015-å21-001510 SAMPSON STEEL Manager Location: 701 WILLIAMS ST City BAKERSFIELD BusPhone: Map : 103 Grid: 28C (661) 631-8979 CommHaz : Minimal FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 02 SIC Code:3441 EPA Numb: DunnBrad:36-127-2727 Emergency Contact / Title Emergency Contact / Title MIKE HOCKS TED / PLANT MANAGER TONY LEON / MAINTENANCE Business Phone: (661) 631-8979x Business Phone: (661) 631-8979x 24-Hour Phone : (661) 201-8139x ~è..\ \ 24-Hour Phone : (661) 201-8182x Pager Phone : ( )l.oç - 522'1 Pager Phone : ( ) - x Hazmat Hazards: Fire Press ImmHlth DelHlth Contact : Phone: (661) 631-8979x MailAddr: 3220 RIO MlRADA State: CA City : BAKERSFIELD Zip : 93308 fi";-,~ Owner DUNCAN SAMPSON ~ ''It:.([P1:I~~1J Phone: (661) 631-8979x Address : 3220 RIO MlRADA FE/] State: CA City : BAKERSFIELD ~fb. . 0 1 2001 Zip : 93308 Period to . ~ If I f"((Jf!Q TotalASTs: Gal : ", 3ëRVICES = Preparer: TotalUSTs: = Gal Certif'd: RSs: No Emergency Directives: p= Hazmat Inventory One Unified List ì p== As Designated Order All Materials at Site ì Hazmat Common Name.. . SpecHaz EPA Hazards DailyMax MCP LUBRICATING OIL F DH L 55.00 GAL Min ACETYLENE E F P IH G 30.00 FT3 Hi OXYGEN F IH DH G 15.00 FT3 Low WAS T l3-- V\,-..<fí ()íL 0 I~ \ ~ ~ SA I Ian S c,~ TA, M ~p...TË'l) '\;>t' G:. ~£ L ~v-e....- \ S S- G-A' lðAl5 -1- 07/19/2000 -- e CITY OF BAKERSFIELD FIRE DEPARTMENT ) OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3rd Floor, Bakersfield, CA 93301 F ACILITY NAME~ S ò AI Sf -e.L.L ADDRESS 70' ' \A tf'11 S .s.-r FACILITY CONTACT rI'\' ke.. Ho c.J(ç'ìr:2Ak:. INSPECTION TIME ~ S- 'II\.o.~~,J INSPECTION DATE I~ '3 0 I (j I PHONE NO. to '3 ì - ~ 7CJ BUSINESS ID NO. 15-210- {) ~.I s lò NUMBER OF EMPLOYEES Section 1: ~outine Business Plan and Inventory Program o Combined o Joint Agency o Multi-Agency o Complaint ORe-inspection OPERA nON C v COMMENTS Appropriate penn it on hand V Business plan contact infonnation accurate J Visible address V Correct occupancy V Verification of inventory materials .......... Verification of quantities ./ Verification of location v Proper segregation of material v Verification of MSDS availability v . Verification ofHaz Mat training ./ Verification of abatement supplies and procedures V Emergency procedures adequate V Containers properly labeled V Housekeeping V Fire Protection Iv Site Diagram Adequate & On Hand V" C=Compliance V=Violation Any hazardous waste on site?: [9""Yes 0 No Explain: lA J "... ~ "\~ TV\. die] (L 0" ( -- ~/ cß/~ . 1/ Business Site Responsible Party Inspector~~~ Questions regarding this inspection? Please call us at (661) 326-3979 .....,c;;;. White - Env. Svcs, Yellow - Station Copy Pink - Business Copy -q.j ~ ~ -~ - CITY OF BAKERSFIELD OFFICE OF ENVIRONMENTAL SERVICES 1715 Chester Av~akersfield, CA 3 6-3979 ~ \6~D HAZARDOUS MATERIALS OR ~J e; ",7? q1~v ý¡t-,O Jì FACILITY DESCRIPTION ',- BUSINESS NAME SQmLlSon v STeer RFí'.ETVED FEB 1 5 2000 ·BY:~ CHECK IF BUSINESS IS A FARM [ ] FACILITY NAME PlanT #1- SITE ADDRESS 70 I VI'! t'tflp-, r s r CITY (fO(r-er/+,.elcl STATE (,.f- ZIP 9130/ NATURE OF BUSINESS S Te..e- ( 4 hI 'f''' 'cATlo1-'7 .... SIC CODE jL¡y 1 DUN & BRADSTREET NUMBER -:56-/27- 2727 OWNER/OPERATOR jJUJ'1 C fir) '50/hOf on PHONE f MAILING ~DRESS 3220 lfr'l) H, r rJ cia CITY r1¡ K-erj!,--< (d STATE UI ZIP 93 ')o¿ EMERGENCY CONTACTS / NAME l'1il\-e. /-{nC ~"~7'!d BUSINESS PHONE "6 J 1- Je¡ 71 \, NAME Ton y / we On , TITLE Plqri/ /1Q/1 ~ ..p,-- 24HOURPHONE 201-<:!/?9 TITLE .1'10' f 'r7 Tqn CI/? C < BUSINESS PHONE 6 J (- f'i) c¡ 24HOURPHONE 70'7- JJ¿2 1 ~OUS MATERIALS INVENT. Business Name S Qm¡JS 0/1 5' Te.t2 ( Address 7D ( w(/I;on, f CHEMICAL DESCRIPTION 1) INVENTORY STATUS: New ~ Addition [ ] Revision [ ] Deletion [ ] Check ifchemical is a NON Trade Secret [ ] Trade Secret [ ] 2)ConunonName: fcTro !eLf", hQJ-e.cI- It(/;rfo'fi~ 01/ 3) DOT # (optional) Chemical Name: A F ~L {is 10 AHM [ ] CAS # '" .~ __'C . ,-'--' "N Page .l of ~ 4) Physical & Health PHYSICAL HEAL IH Hazard Categories Fire [>(] Reactive [ ] Sudden Release of Pressure L>Ç Immediate Health (Acute) [ ] Delayed Health (Chronic) [ 5) WASTE CLASSIFICATION <is ( (3-digit code from DHS Form 8022) USE CODE 0"7 6) PHYSICAL STATE Solid [ ] Liquid [XJ Gas [ ] Pure [ 7) AMOUNf AND TIME AT FACn..lTY Maximum Dåilý AÍnount 10 6-1110 Average Daily Amount Annual Amount Largest Size Container # Days on Site UNITS OF MEASURE Lbs [ ] Gal [x ] ft3 [ ] Curies [ ] 10<:> '-A-t S 5 (,-Al 3l.S Cirçle Which Months: 9)~: Li~ the three mo~ hazardous chemical components or any AHM components L £) 1/ C~MPONENT 1) ~ Lnll?-( L 2) -cr~rJ -e n-'- 3) 2M~ CI-é..cr 10)LOCATION , 5"7ðrQC1-e .- Mixture [ ] Waste [ ] Radioactive [ 8) STORAGE CODES a) Container: 07 b) Pressure: c ) Temperature ~I, F, M, A. M, I, I, A. S, 0, N, D CAS# 6lf7Y?: 6.f-v 6!(;t¡C}-ÝZ-J %wr {I AHM [ ] [ ] [ ] ~}¡.e cI d-n AlerïA <,.,I-e. 0+ ¿:J Io~,- v I) INVENTORY STATUS: New[)(] Addition [ 2) Common Name: f/ceTy/-eI1-€! . Chemical Name: C T h V 11-e r , ,. ] Revision [ ] Deletion [ ] Check if chemical is a NON Trade Secret [ ] Trade Secret [ ] 3) DOT # (optional) AHM[ ] CAS# 7'1-¿ö-Z 4) Physical & Health Hazard Categori~ Fire [ , ] Reactive [ 5) WASTE CLASSIFICATION PHYSICAL HEALIH ] Sudden Release of Pressure (X] Immediate Health (Acute) rx ] Delayed Health (Chronic) [ (3-digit code from DHS Form 8022) USE CODE 6) PHYSICAL STATE Liquid [ Gas [ ] Pure [ Solid [ 7) AMOUNf AND TIME AT F ACn..ITY 3 Maximum Daily Amount .30 -If Average Daily Amount '2.0 .f r ., Annual Amount 7S00~..,.7 Largest Size Container 15~T7 # Days on Site UNITS OF MEASURE Lbs [ ] Gal [ ] ft3 [X] Curies [ ] Circle Which Months: 9)~: Li~ the three mo~ hazardous 1 ) chemical components or 2) any AHM components 3) COMPONENT Mixture [ ] Waste [ ] Radioactive [ 8) STORAGE COD~ 1 a) Container: L. b) Pressure: I c) Temperature ~ All Year, I, F, M, A. M, I, I, A. S, 0, N, D CAS# %wr AHM [ ] [ ] [ ] IO)LOCATION I'll 1"'1(1/1 V JAiriOf..f I 10<: A-Î/rJ/7 f I certify under penalty of law; that I have personally examined and am familiar with the information on this and aU attached doaJments. I believe the submitted information is true, accurate and complete. ßro.e( Æhf>V o..C ~ JI1o",~.f>r PRINT Name & Title of Atfthorized Company Represen ve a'A ~--- Signa "2-Z-00 Date ... ~~~~ e . CITY OF BAKERSFIELD OFFICE OF ENVIRONMENTAL SERVICES 1715 Chester Ave., Bakersfield, CA (805) 326-3979 INSTRUCTIONS: 1. To avoid further action, return this form within 30 days of receipt. 2. TYPEIPRINT ANSWERS IN ENGLISH. 3, Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA BUSINESS NAME: Sam/Ofon ÇTee( (/ LOCATION: 70 I vtll/(/M J ~ '( MAll..ING ADDRESS: J 22 0 ¡e·o /?f yryc/q CITY: (fa lr~r5-t--e I.L STATE: (,4- ZIP: DUN & BRADSTREET NUMBER: 36 -/2. 7 - '"2- ì L 7 PRIMARY ACTMTY: .S-Teel -4br/'<::.AT¡'on PHONE: 6J/-t979 SIC CODE: J l' c.¡ ( OWNER: I?lInC~n SOI"Y?£?.sO/1 v MAll..ING ADDRESS: fQf;n ~ SECTION 2: EMERGENCY NOTIFICATION CONTACT 1. /1¡'¡f- ~ f/(Jclr, (~¿' 2. Tt,1'1 V t eð r7 / TITLE BUS. PHONE ¡!/lrt",T 1'111:/11~'f'r óJ/-!979 110Ù77"è¡9?(1" ~-e ð'JI--¡§)(:¡ 77 24 HR. PHONE 7ð 1-~r]9 2öl- Jltf2 1 · e - , --,.. ~ ,. ~ \( IlAZARDOUS MATERIALS MANAGEMENT PLAN SECTION 3: TRAINING NUMBER OF EMPLOYEES: MATERIAL SAFETY DATA SHEETS ON Fll..E: - BRIEF SUMMARY OF TRAINING PROGRAM: SECTION 4: EXEMPTION REOUEST I CERTIFY UNDER PENALTY OF PERJURy TIiAT MY BUSINESS IS EXEMPT FROM THE REPORTING REQUIREMENTS OF CHAPTER 6.95 OF THE "CALIFORNIA HEALTII & SAFETY CODE" FOR THE FOLLOWING REASONS: X WE DO NOT HANDLE HAZARDOUS MATERIALS. WE DO HANDLE HAZARDOUS MATERIALS, BUT THE QUANT111.bS AT NO TIME EXCEED THE MlN1MUM REPORTING QUANTITIES. OTHER (SPECIFY REASON) SECTION 5: CERTIFICATION L CERTIFY THAT THE ABOVE INFORMATION IS ACCURATE. I UNDERSTAND mAT THIS INFORMATION WILL BE USED TO FULFILL MY FIRM'S OBLIGATIONS UNDER THE "CALIFORNIA HEAL TII AND SAFETY CODE" ON HAZARDOUS MATERIALS (DIY. 20 CHAPTER 6.95 SEC. 25500 ET AL.) AND THAT INACCURATE INFORMATION CONSTITUTES PERJURy. /h¿Æ ~--- SIGNATURE {),c TITLE I-¡v-dó DATE 2 ........- . .' ~ -\ 1 t' -<>" ~ ~õi> aAous MATERIALS MANAGE&.r PLAN SECTION 6: NOTUFICATION AND EY ACUATION PROCEDURES A AGENCY NOTIFICATION PROCEDURES: Erner9-en~t nWri16w4r~ (jýe pOS r-e~ on Th-e /:;"II-rTiln B. EMPLOYEE NOTIFICATION AND EY ACUATION: q./I .¿mplo l'..ee~ (b) Or re To -e if rr ,0 Wl/ f,'qh? f <ÇT df) it h ~ 0'" (/0 f/n-¡- On q (ct/l t¡ II C. PUBLIC EVACUATION: ¿m~Æ'y-ees o"(y D. EMERGENCY:MEDICALPLAN: TJ~r-e.. i5 on.e.. t,'rsT ¡4¡'~ C-ern'¡;\e~ -em/, (0 y-e4. (J¡l/e- c:('( ¡olo-,-,r#z TO oJP'I'Ì1,~r~Þ- "/''r<)( r¡,'ro;/ tI C"j, " h~ Ip (Jr/í 't/~ J ...i 3 From-SAMPSON STEEL Center +8818841809 T-911 P.08/08 F-189 e e CITY OF BAKERSFIELD OFFICE OF ENVIRONMENTAL SERVICES 171S Chester Ave., CA 93301 (661) 326-3979 HAZARDOUS MATERIALS INVENTORY CHEMICAL DESCRIPTION Feb-14-00 11 :ZZam ~evv, DADO CJ REvise :zgo CJ Piœre , I.. ' . '~", .........-,.-~ . ~,;7~ ..:·,i"~·~: :~~~' :~""~'" \ ' . ., ·-Büši~ES~fÑÃÑf\sa,;. 86 FAëq..'rr ~ III" ~ - P\:1ong Bw~n~ AG) Sòm¡:;sQr? t)T-er: / CI1EM1CA~LOCATION , J T SIc:( r:? . ; I I ' "H'~' ".',." :~-:':".;1.:, ,", H '. . ¡ ...~ INfOJUlAT1ON FACILlT'r II) /I, 20.1 .¡!Ql; c;r.EMI~1- LO~TION I CCNFIPE«fAL (Ef'C~) --,.., .---....- GRID' (opQl{I) o TIIS D\HO 202 2Øot ~-- -'_.....---_._--..~ ,..¢j:~~INFopAT1ON :':" (0"" fQmr par __I ;¡or l¥IOJt'9 or alBa) Pago cI 3 -,--.... . - . " ,..,. " .:~" 'f~ _. ,.. --------. CI1iMIOU- ~ 0XY.!)'1!!'/7 ~ COMII4CN NAac: : Ox yj e /1 '- VJ£ '(;,,,$. 7 7. , ',.f"Z - '/'1- 7 , FIRe CQDE ~ QAUeS ¡(;Q¡¡pICU ~ A:IC...caI"'" Dl cQt IIro Ø1,d) 21i5mRÃQÊSEèR~T 0 TOO:¡ ~ No _ I II S..þ<Q 1'1 IEPCR¡¡" rfllcr (0 ,nSll\¡a.ans -- 207-r--'------- I EHS- 0 '-IIS ClI'Ø 2011 <!D9 l .lr~~·Tcs.·-~·~'~~~- ¡ ì ' , ' ~ ,"~" . ,,-' ,,'" : T'rfle o .. wASTE 2\' i RAOIOACTl\le 0 T8& ø Nr¡ I --.------------ 2'4 lARGeST C:OHT...IIIISR œ! p PuRS o '" 1'4C11Jf(S PnYSICAI. STATr¡¡ ègGas o $ SQI-ID o I ¡.¡QuID -.----...........-........ I F¡:P t1aZARO CATeGORIE$ ; (C'.rIeø< au lNI8flplyj , AN¡oIUAI. WASTE I AoIOuNT 217 o 2 REACTM: ~ 3 PRESSuRe RELE:ASE 0 4 ...Cuie MEAL TI1 ,wo.IJooIJ1<4 21" : ",VE;~ DAI1-1AI4QuNT IS ~/øÞ'-.(!r ~ ØAII-TAIoQUI'IT 10 c,,6, '- .f/,- o ga GAl- ri. d c:u FT 0 IÞ IJS 0 1/1 TONS . If EI1S. em"",,! ""'6! 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': "', Øa ?-(V~ 00 .--...-- S:\CUPAFORM$\OES2731.1'I4,wpo ¡ ~. .i'" e -- PLANT # 2 EMERGENCY SHUT OFFS ELECTRICITY: The plant runs on a diesel powered generator and power for the lights are in the restroom FIRE HYDRANT: There is one at the south west comer on Williams st. rl'<UM ; ':::)\::G!UULH rHll~1 LU - r-HU¡~t:: ¡,U. . ItJUJ.)¿"'> f OJ ,.... " e :,e~ ¡ ~;.- í : r . I' t. MeI~.Bl.aL_.!:?eFEJY...,_PB.T.e.J~M~.~T. \- PRODUCT NAME: RETARDER LACQUER THINNER PRODUCT CODE; 309-019 HMtS CODES, H F R P Z 3 1 H =.-=.e==-=~..e=.æ SECTION I MANUFACTURER IDENTIFICATION ~=_...e=e=.RÞ=== MANUFACTURER'S NAME. D.J. SIMPSON COMPANY ADDRESS, 111 SOUTH MAPLE AVENUE, SOUTH SAN FRANCISCO, CA 94080 EMERGENCY PHONE, 1-800--42'+-9300 INFORMATION PHONE II 415--S73-5990 DATE REVISED I 06-·e9-93 NAJlfE OF PREPARER ~ P. GANSER REASON REVISED : ÞROP. 65 WRRNINB. ......._1:1:1--=1:: SECTION II HAZARDOUS INGREDIENTS/SARA II,! INFORMATION ClWae-=__==- IJCtUIATJONII.. E'XPOaIAE LINITS ; WJœ PRE9IIJRE aEIIJfT ImRRIXIJS CM(J.ÐfTS CÆ N.MIIEII O!HI PEl flt81H TlV OTHER .. Hv ,_ PERœNT .------------------..-.----.----- --...........-------- UCTt1. 9PIRlTiI 6474e898 5OO11PM 38.0 68F 30 fTll.ø 108883 ~OO mo 100 PPM 22.0 GSF 11 ISOPriOPINl., I¥f4YDfOJS 67630 400 IIPM ~~ SOO PPM 33.0 EN (5.~ fACEl'1J£ 61641 1000 pPM r.so PPIf J86.0 68F 17 BUTYl mAtE 1~ 150 PfItI l~-WR 10.0 6If ( 5.01- IXVlŒ 1330207 100 PPR tOO mt 5.1 6IIF 5 JllE1JM.. NOIØW. Am. KETtlE 1100\30 101J'11M 50WM 2.' 6V < S.()~ f2-9\JJDXYE'MVO.. 111762 25PØM SKIN 25PPM SlUN 1.0 6Sf 13 . lootCt.tu t(ldc c:h.h:aU¡) !lubjRtt to \he reporting requirllenh of søction 313 of TiUII III 1M of 40 aft 372. "', {( WARNIN6!H \..... PRotU:T !:OOAltts A CÆltIal.IS) IUGIN TO 1HE STATE iF CA. TO ~ CIK1.~ BIRTH ŒÆtTB OR tm£R REPROIIœTllJE IV\RM. -=a_.œ~__==.~D SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS ~Þ_eDÞ_==~_== »OILING RANBEI 133 tö 340 DeR F VAPOR DENSITY: HEAVIER THAN AIR COATING V.D..C.: e..73 LB/GL ( SOLUBILITY IN WATER: APPEARANCE AND ODOR. CLEAR LJQUID WITH DISTINCT HYDROCARSPN ODOR SPECIFIC GRAVITY (H2O-I): . 0.8 EVAPORATION RATE I SLOWER TH~N E1HER Boer aIL.> ~ \> \' _~_S=___=___D~ SECTION IV FIRE AND EXPLOSION HAZARD DATA =D_____~=R===~= FLASH POINT: 40 DEß F "ETHOD USED: FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: 1.0~ UPPERr le.8~ "Ú ~\' EXTINGUISHING MEDIA: FOAM, CQ2. DRY CHEMICAL, WATER FOB SPECIAL FIREFIGHTING PROCEDURES SELF-aMA11f.D BR£RTH]N& ~TUS REIXN£NDElI. litTER HAY BE U9ED TO COOl ADJACENT IXIfTAIHERS. AWJ!) SPREADJH8 IMINJNG UOOID WI11f COfLIfiG WATER. IHH usttÐ WATER, Fœ MOmëS ARE PIŒÆRRED. ,. l 1\ ~ ~ \.-' UNuaUA~ FIRE AND EXPLOSJON HAZARDS KEEP WORK AREM FREE a: HOT METAl SUllFlŒS AND OTHEJI SttJ1!ŒS IF I6MlTl~. MATERJIL JS HJIRV VOLATILE AND DllY GJ'ÆS OFF VAPORS HHI(} MAY TRAVEL 1I.0tÐ TtE 6IWI!) DR BE )fMD ." VEHTJlATIIIf TO SWRŒS Cf IGNmlJ4. E'ÆM IlESIIŒ CAM l\JfnE EXPlœlVaV. fU 5-G\.lOO PAllS AND LlIRŒR METAl CONTAI~RS "'¡::T lis:' mnlN~n II"""'D _N"o. "..n"_ ,._..~ _u··., \ ~ FROM SEQUOIA PAINT CO ,. "'I PHONE NO. 18053237973 Apr. 26 1996 0ª:56AM P6 '- .. e e ~ 4· .... ~~. 309-019 MATERIAL SÞFETV DATA SHEET p~aE 2 OF : c , ..'" \ \ ~ =c==_a=_~_-==__=~_a=~ SECTIDN V REACTIVITY DATA =.-=~_~==_.=__=~_==œ== STABILITY: STABLE CONDITIONS TO AVOID STORE /rID HANDtE AHfW FROIIEAT AND 011£R SOURCES Œ nJnT1~ STOR£ IN A WEl.1. VEWTJlATED PUŒ. INCOMPATIalLITV (MATERIALS TO RVOID) S'TRIWS OnnmNG AGENTS, ACJOO OR MSES. rUAlJES AND Ø£1.ECTEJ) mHO. HAZARDOUS DECOMPOSITION OR BYPRODUCTS MRV FORM Toue M1Eftll'U: D\R1tJf DIOXIDE, CAIIIIJN MDl«JXJDE, YARIOO9 ttYÐROCAR~S, ETC. HAZRRDOUS POLYMERIZATIONs WILL NOT OCCUR ae==-e==_~=___.__~=_a SECTION VI HEALTH HAZARD DATA e=-.___~_mc=_a=--.._. INHALATION HËALTH RISKS AND SYMPTOMS OF EXÞOSURE EXŒSSIIIE IItW.An~ OF VAPORS CAN CAœE )WJL ANI) QIRATORV JRRITRTIOH. ÐI2ZItŒ, WEMM:SS, FATJBlIEt tAISEA, H£~, POSSIBLE UlDMCJOIISfESS, JW) EV£H ASPHlXATIDN. . SKIN AND EVE CONTACT HEALTH RISKS AND aY~TOMS OF EXPOSURE EYES: CAlf ma· ŒVEAE IRRlTATIM, IÐt£SS, TE~AIM3, IUJRRED YISIœ. SKIN: PRI1..1»ŒD AND REPEATED aJlTOCT am CAUæ JIIlDE1IATE lR1UTRTlDN, DEFATI1M;, Ð£RWlTlTJS. SKIN ABSORPTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE SEVfIlE MYI/Ð OF SKIN, DEfATTING AN!) DERllATJTIB. 2-BIIJOXY ETIAiIL IS Ot£ OF T1£ 61. YttJ.. ETf£R9 1mT IS CURRENTLY BEINS TESTED FOR TOXlt::O...OGtal.. EVAl~TU).. '\ \.- INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE &t!STROINTESTUW- IRRlTATJltt, NAUSEA, vtJMmoo :W DIARHA. ASPlRAlItH IF MATER]AL INTO I.~ crw CAUSE OÐIIDI. ~ITIS IIHICH CAN æ FAT~. HEALTH HRZARDS (ACUTE AND CHRONIC) £YE COOAC1 . my BE AN EVE IRRITANT. SON COHrACT - pll(JjþŒJ) OR REPEATED StUN COOII:T MAV RESllT 1M Œ~TlTJS. JIIIJI- LATIOO OF HIGt vrroR cotŒNTRAn~ MAY CitJSE CENTRAL NERYIŒ SV9TÐ1 DEPRESSIOO. INGESTJOth IF SWALlOIIED MAV ClUiE CHS. Cl£MI~ OOJIOKms (:tV( RESll1 FR(JI ASPIRAmJt OF ~n\JS INTO UE. TES'rn IN I«)R!lERS ElPCSEO TQ Ht,,*, ~Rl\nOt$ OF TIl.IJÐE Hl\YE ~ WAY A ~T IF THIS tmTERtft. (M CAUæ lR11EVEJ1SI9tE ~ES 10 THE rm OF T1£ tEll. CARCINOGENICITY, NTP? NO IARC MONOGRAPHS? NO OSHA REBULATED? NO THIS HATElIJAl CONTAINS D£IIIJCIU KfOIW TO TtE STATE IF m..lFORNIA TO CAJSE CAtUR, 8IRTH DEFECTS OR O11ER REPIIODltTIYE HARM. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE PRE-£X1SnMB, t£ARTt llJlG, LIVERt KIDt£V, SKIN D19IJRŒR9. EMERGENCV AND FIRS~ AID PROCEDURES EVE CONT~ - FI...lRt E't'E9 &11114 WATER FOR AT LEAST 15 ÞlIIAJTES. IìEEK IllEDJaL ATTOO'JON lItEDIATELY. SKIH COHTACT . REIII\II: COO'l1IlHATE'D ttDTHJMJ IHJ HA!ß IIITH SOAÞ AND UIRŒ IUllTJTJES IF WATER. INJlllATIœ - RaGM TO AREA WITH 600n YEHTllAT1~ iF BREATHltE STIJIoS, 1ÌE6IN ARTIFlCIIt.. R£SPTRATIOO :N SEEK MEDICAl.. ATTENTIIW IMMEDIATELY! IF SHlUOIiElh PO HOT INIRŒ VOKITIto«;. KE£) Plmoo II!Ø, QUJET, rtID GET IÐI~ I£l.Þ IMEDIR1ELY. ASPJRATJOM nrro LlflGS DlE 10 Y~IT1NG CM ~ DÐllm.. PHEtJOtITIS, WHICH !::AN æ: FATAl! \.-. " h , .. . ¡<\. ~ ~~ ~ C.!lIVL~ (: '~ ~~~~~.~o~~J ~~ Fn~ _ þVfJ,v.. P;¡ / Iddtl ¡eft;- Materiallafety Data Sheet ',' LIQUID OXYGEN - PRODUCT NAME EMERGENCY RESPONSE INFORMATION Liquid Oxygen IN CASE OF EMERGENCY INVOLVING THIS MATERIAL, TELEPHONE CALL DAY OR NIGHT .............1-800-231-1366 , (510) 977-6500 OR CALL CHEMTREC AT ...... 1-80D-424-93œ UQUID AIR CORPORATION TRADE NAME AND SYNONYMS CAS NUMBER CAUFORNIA PLAZA. SUITE 350 Please see last page. 7782-44·7 2121 N. CAUFORNIA BLVD. CHEMICAL NAME AND SYNONYMS NFPA 704 NUMBER (HFR) WALNUT CREEK, CAUFORNIA 94596 liquid Oxy~et;l 3 0 0 OXY ISSUE DATE Rev. Sept_ 2, 1991 FORMULA MOLECULAR WEIGHT CHEMICAL FAMll V AND REVISIONS Liquefied 02 31.999 Oxidizer CORPORATESAFETVDEPT. . . - HEALTH HAZARD DATA(See last page). TIME WEIGHTED AVERAGE EXPOSURE UMlT None established (ACGUI, 1989·90). Oxygen is the "vital element" in the atmosphere in which we live and. breathe (approximately 21 molar (volume) percent of the atmosphere). The minimum oxygen content in workplace air is 18% by volume under normal atDlospheric pressure, equivalent to a partial pressure, p02 of 135 torr, (ACGlH 1989-90), SVMPTOMS OF EXPOSURE The primary route of entry is inhalation. Acute health effects: Adults can satisfactorily breathe pure [;", ~ oxygen for extended periods at 0.33 at.m, or at 1 atm for several days at less than 5 hours a day. However, ,< .' irritation to mucous membranes may occur when 100% oxygen is inhaled continuously for several hours. Chest pains and cough can result from breathing O2 at 1 atm for B to 24 hours or 2 atm fOT 2 to 3 hours or from an atmosphere of 60% oxygen for several days. Breathing high concentrations greater than 75 (molar) percent by volume at atmospheric pressure for more than a few hours causes symptoms of hyperoxia (high oxygen exposure) with a variety of central nervous system effects. These symptoms include cramps, nausea, dizziness, hypothermia (low body temperature), ambylopia (rliminished vision), nasal stuffiness, cough, sore throat, chest I>ain.,.respiratory difficulties, bradycardia (slow heart rate), fainting spells, and convulsions capable ofleaaing to death. Breathing oxygen at higher pressures increases the likelihood of adverse effects within a shorter time period. For additional data. on hyperoxia, (high oxygen exposure) as it relates to oxygen pressure and exposure duration, refer to L'Air Liquide's Encyclopedie des Gaz (See References on last page). Prolonged breathing of very cold atmospheres can cause lung dam~ and hypothennia (low body temperature). Chronic health effects: None established. Medical conditions generally aggravated by exposure: See NOTES TO PHYSICIAN, below. NOTES TO PHYSICIAN: fI"'or gaseous exposure, supportive treatment should include immediate sedation, anti-convulsive therapy uneeded. and rest. Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, increases the susceptibility to toxicity trom oxygen at high concentrations or pressures. Animal studies also indicate that vitamin ~ deficiency may increase susceptibility to oxygen toxicity. Airway obstruction during high oxy-gen tension may cause alveolar collapse following absorption of the oxygen_ Similarly, occlusion of the eustachian tubes may cause retraction of the eardrum and obstruction of the paranasal sinuses may produce "vacuum-type" headache. Newborn premature infants exposed to high oxygen concentrations may suffer delayed retinal damage which can progress to retinal detachment and blindness (retrolental fibroplasia). Retinal damage can also occur in aaults exposed to 100% oxygen under greater than atmospheric pressure, particularly in individuals whose retinal circulation has been previously compromised. All individuals exposed for long periods to, oxygen at high pressure and all who exhibit overt oxygen toxicity should have ophthalmologic examinations. Contact with the cryogenic liquid or cold piping containing the liquid can cause tissue freezing or frostbite on dermal contact or if splashed in the eyes, JUdgemerm; iI& 10 IlIe sui1abililv ollnlormBlion lIetein far pun:ha&er's putpD~ are I1ØC8$SIfily purcftuer's ~OII$Ibilily. Therwrore. althOUgh reasoMIIII CBnI ha been \Qken In Ihe preparaûon 01 wch inlonnation. Uquid Air CClrporanon elC!8ndsllO warramies. makes no represenlilt1ons. and .3!I!Iumes no røapoll$ibilìty as to1he ICCUI'IICY or suiIBbDilY 01 Alch Infarmllllon .._ ___..__~__ _ _....~._"". :A_~""'" ~.._.... .... ....._............"""'" nf it", usO, Since Uouid \Ir Co.""mlian lias no conltOl over !he use 01 INs praauct.1t assumes nD ßebUiIy lor darnagu ...... PAGlii2 '!'" TOXICOLOGICAL PROPERTIES . _ At normal concentration an~ressure, oxygen poses no tox:icity~ards. However, at elevated concentrations and pressures, ~en may cawse adverse effect5 ofbyperoxia (high oxygen exposure) which leads to pnemnonia. Concentrations between 25 and 75 molar percent present a risk of inflammation of or~c matter in the body. Frostbite effects are a change in color of the skin to gray or white possibly followed by blistering. Listed as Carcinogen National Toxicology YES 0 I.A. R. C. YES 0 OSHA YES 0 or Potential Carcinogen Program NO 00 Monographs NO ~ NO 1g WARNING FOR MEDICAL ~or oxygen deficiency in breatþing perso~8 or emergencf z:esusc:ïta- OXYGEN U S.P . tion when used by personnel Instructed In oxygen admm1Rtration. . .. For other medical applications, use only as directed by a licensed practitioner. UnintelTUpted use of high concentrations of oxygen aver a long duration, without monitoring it.s eß'ecL on oxygen content of arterial blood, may be harmful. Use only with pftSsure reducing equipment nnd apparatus designed for oxygen. RECOMMENDED FIRST AID TREATMENT PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO OXYGEN_ RESCUE PERSONNEL SHOULD BE AWARE OF EXTREME FIRE HAZARD ASSOCIATED WITH OXYGEN-RICHATMOSPBERES. REDUCE OXYGENPREBSURES TO 1 ATMOSPHERE AND/OR MOVE VICTIM INTO FRESH AIR. Conscious persons should be assiSted to an uncontaminated area and breathe fresh air. They should be ~ warm and quiet. The physician sbould be informed. that the victim is experiencing (has e2C.perienced) h) p& wua (high OXYgÐn exposure). Unconscious persons should be moved 1.0 an uncunt.::lm;nëJted area and given assisted respiration. When breathing has been restored, treatment should be as above. Continued treatment should be symptomatic and fiUpportive. For skin contact or frostbite, immerse affected areas in lukewarm water. DO NOT USE HOT WATER. Do not rub frozen area. For eye contact, ßush with lot..c; ofwann (tepid) water. For hypothermia (low body temperature), remove victim tu a warm (not hot) area. Remove contaminated clothing, ifpossíble. Wrap himlher in blankets. Slowly restore body temperature. A physican should see "he patient promptly in all cases. HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES Although nut f1ammable itself, uxygen vigorously accelerates fire and combustion (burning). Contact with allf1J!1mm~hle materials should be avoided. Some materials which are not. 03UJUJ:lble in air will bum in pure oxygen or oxygen-enrich.ed atmospheres. Materials that burn in air can burn with explosive violence in a pure oxygen or oxygen-enriched atmosphere DOÌ1öt allow liquid oxygen1ioJeak, ,driP,OTSpi11 onto hydrocarbon-based paving or onto plastic base,or other flammable flooring. Combustibles in' eontact with liqUid DXygên may êXplode on ign.¡tion or impact. PHYSICAL DATA BOILING POINT UQUID DENSITY AT BOIUNG POINT -297.35°F (-182_97°C) 71.2S lb/fts (1141 kglm3); specific gravity ... 1.14- VAPOR PRESSURE @ 70°F (21.1°0) above the CAS DENSITY AT 701 F 1ATM critical temp. of -181.4::I3DF (-118.57-tDC) .0828 Ib/~ (1.326 kglm8) SOLUBILITY IN WATER FREeziNG POINT @ 6BoF (20ClC) Bunsen coefficient = 0.0310; -361.838°F (-218. 799°C) 3.16cm3 / 100g @ 25°0 APPEAAANCEANDODOR Clear, pale blue, odorless liquid. FIRE AND EXPLOSION HAZARD DATA AUTO IGNmON TEMPERATURE FLAMMABLE LIMITS % BY VOLUME NotA licable '. ,~Q~~pplicable ELECTRICAL CLASSIFlCA1l0N Nonhu dous S POI (METHOD USED) Not A licable EXT1NGUISHING MEDIA CO ioua uantities of water for fires with 0 en as the oxidizer. ·SPECIAL FIRE FIGHTING PROCEDURES If possible. stop the flow of oxygen which is supportine: the fire if you can do so without risk. Use media that are appropriate to the SUlToundingfire. Immediately cool fire-exposed container, standing at a safe distance as far away as possible and using a water spray. Iffeasible, remove oxygen containers from me area. Containers may explode in the heat of fire. Though not flammable itself, oxygen vigorously supports combustion. LAC 05128 (912191) .,.1} ':;:. C.,· Ð ~. " V" -z . _ PAGE. 3 I"" ,"'- ~ SPECIAL FlRt: flGKnNG PROCI9)~ .' ' .Matertalsthatdonotburninmu.Jbuminoxygen-enrichedaiT(>23%oxy, . Somemateria1scaneven become spontaneouslyfiammahl.e in ~gen or oxygen-enriched.a1r. Oxygen released in a llre situation ~a:t1yin.cmuJes fire and explosion hazards. (~n containers are equipped wi~ safety devices to releæe 0 ~t exœI5SÏve temperature or pressure). Liquid oxygen can explode on conta.ctwith Ø"mmables. Do not direct wa~ spray into liquid oxygen. UNUSUAL FIRE AND EXPLOSION HAZARDS Vigorously accelerates combustion (buming)- No smoking in container area or while O¥)'gen is in use. Keep oil ana grease'away. Keep oxygen containers away from flammables and 'COmbustibles. REACTIVITY DATA STABILITY CONDmONS TO AVOID I UNSTABLE Liquid OXygen is stable when kept isolated as a cryogen!c liquid in specWl.Y I X designed storage tanks. tankers and DOT 4L liquid containers. This STABLE material is an oxidizing agent that ~sl~ accelerates combustion INCOMPA TlBIUTY IMATERlALSTO AYOIDI (b~ fire). Oxygen Will undergo h:ig.li!y exot ennic reactions or explo- sions WIth many mataials. The greater tlie concentration of 02 in contact All flammable materials. with a fuel or reducing agent, the greater the violence of the re8d:ion. Air HAZARDOUS DECOMPOSITION contains 21 percent oxygen; reactivity with environmental materials is I'AODUCTS substanttal1y increased at above 23 percent oxygen by volume. None ~n reacts ~velY with phosp~~, hydrogen sulfide, ethers, alcohols" ocarbons. etc. Red- steel bums in an ~ HAZARDOUSPOlYMER~~ON atmO$phere. This material is incompatible with oils, grease, lubricants, and MAY OCCUR ßammBble materia1s_ Keep oxygen containers free of on and/or grease. CONDITIONS TO AVOID WILL NOT OCCUR X , Not applicable SPILL OR LEAK PROCEDURES STEPS TO 8~ TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Evacuate all pf:!rsonnel from affected area. Use appropriate protective equipment (Refer to "SPECIAL PROTECTION INFORMATION"" section), Provide optimum exhaust ventilation. Ifat all possible, shut off the source of the oxygen leak if you can do so Without risk. Remove sources of heat, ignition and, if feasible, separate combustibles from the leak.. Shut ofT all internal combustion engines within 50 feet of affected area. Avoid contact with liquid oxygen or its cold boil-off gas. Sma111eaks in an oxygen system in an enclosed, unventilated area can build up â hazardous oxygen-level. I£leak is in user's equipment, be certain to purge pi~ with an inert gas prior to attempting repairs. SNOOP® solutions for oxygen &ervice may: be used to detect gaseous leaks. Ifleak is in containor or container valve, contact the c1oses:t Liquid Air Corporation location. Liquid oxygen, when I:;pilled. will evaporate rapidly causing a. vapor cloud that will be highly oxygen- enriched, which can cause materials in this cloud to i~ite easily. Evacua.te the cloud area and remove any ignition 50urc;es. Vi3ibility may be obscured in this vapor cloud. To increase the rate of contròned evaporation of spilled Jiquid oxygen (when desired), spray the spiJ] with large amounts of water. This may generate a fog and reauce visibility. Liquid oxygen is delivered to a customer into stationary vacuum-jacketed vessels at the customer's location or ÍD portable vacuum-jacketed '"liquid "cylinders (DOT 4L). Stationary customer-site vel:l~els should be operated in accordance with the manufacturer's and Liquid Air CorporaLÏon 's instructions. Do not attempt to repair, adjust or in any other way modify the operation of these vessels. If there is a malfunction or other type of operational problem with the vessel, contact the closest Liquid Air Corporation location immediately. No smoking or open flames should be anowed near these vessels. Bulk liquid oxygen storage must meet exposure separation requirements in National Fire Protection Association Pamphlet 50, '"Bulk Oxygen Systems At Consumer Sites". Liquid oxygen containers should be used only in well-ventilated areas and in accordance with the manufacturer's and Liquid Air Corporation's instructions_ These containers must alwavs be kept in an upright position. SpeciE.ù.ized hand trucks are needed for their movement_ Full and empty containers should be stored away from flammable products. A -first in-first out" inventory system shoud be used with these containers. .~ .'. ...... \. .... WASTE DISPOSAL METHOD Do not attempt to dispose of residual or unused quantities. Return in the shipping container tagged to indicate a defect, and properlY laheled. with any valve outlet plugs or can!; secured and valve protection cap in place to Liquid Air Corporation for proper disposal. For emergency disposal, contact the closest , Liquid Air Corporation location. LAC 06128(9/2191) . ,," -:' ... ePECIAL PROTECTION INF.ATlON RESPIRATORV PROTECTION (SPECIFY TYPE) Not applicable _ VENTÏi.Ai1ÔN -, "ï.:ÖCALEXHAUŠT To prevent accumulation To prevent accumula.tion above 23 molar percent above 23 molar percent MECHANICAL (GEN.) See a e5 PAGE .. SP CIAL See age 5 R See a e5 SPECIAL PRECAUTIONS· SPECIAL LABELING INFORMATION DOT Shipping Name: Oxygen, refrigeraœdliquid DorHazard Class: Nonf1~mm~hle gas; CIass 2, Division 2.2 DOTShippingLsbe1: OxidizerarOxygen ID.No.: UN 1073 SPECIAL HANDLING RECOMMENDATIONS ~ways keep,liquido!)'gen-eontainer (DOT 4L) in upright position. Extremely cold, oxidizing liquid and gas.undcr.prcssure..Vl~t:Ously accelerates combustion. Combustibles in contact with liquid oxygen may explode on ignition or 1Dlpact~ Can cause severe frostbite. Keep oil, ~ase and combustibles away. Use only with equipment cleaned for ~gen service. Store and use with adequate ventilation. Do not get liquid in eyes, on skinti0r clothing. For lIquid withdrawal, wear face shield and gloves. Do not drop or handle container roughly. se hand-truck for container movemcnt. Avoid spills. Do not wallt on or roll equipment over spills. Close valve after each use and when empty. Use in accordance with Commpressed Gas Association pamphlets: G4, 0-.4.1, G-4.4, P-l, P-2, P-12 and P-14, and with Material Safety Data Sheet. _.. For addJtional handing recommendalions ,ee References on IBSt P1IQ8. SPECIAL STORAGE RECOMMENDATIONS Protect containers from physical damage. Store in clean, cool, dry, wen-ventilated area away from heavily trafficked areas and emergency exits, away from combustibles and away from full or empty stored cylinders which contain flAmmable products. Do not allow the temperature where containers are stored to exceed 125°F (52°C). Containers should be stored upright and firmly secured to prevent falling or being knocked over. Full and empty containers should be segregated. Use a "'first in - first out" inventory system to prevent full containers being stored for excessive perioas of time_ Refer in particular to the Compressed Gas Association pamphlets: G-4 "Oxygen"; P-12 "Safe Handling of Cryogenic Liquids"; P-14 "AccidenL Prevention in Oxygen-Rich and Oxygen-Deficient Atmospheres". . For additional storage recommendations see Reference section on this pagø. .. . - SPECIAL PACKAGING RECOMMENDATIONS Liqud oxygen can not be handled in carbon or low alloy steels. Eighteen-eight (18-8) and 18-10 stainless steels are acceptable as are copper and its alloys, nickel and its alloys brass, silicon alloys, MonelŒ>, Inconel®, and beryllium. Telfon® and Kel-F® are the prcfcITcd gaskets. Also see CGA pamphlet G-4. Oxygen. Valve connection: CGA 440 for liquid; CGA 540 for gas(Lo 3,000 psig); CGA 870 for medical gas pin- indexed yoke connection. OTHER RECOMMENDATIONS OR PRECAUTIONS Equipment to cuntain liquid oxygen must be "cleaned for oxygen service." See CGA Pamph1et G-4.1, "Cleaning Equipment for Oxygen Service". Liquefied gas containers should not be refined exce~t by quaJified suppliers of these products. Shipment of 8 compressed gas container which has not been filled by the owner or with his (written) consent is a violation of Federal Law (49CFR). 100% cotton clothing (underwear and overalls) is highly recommended to wear when handling or transferring liquid oxygen. I I 'I :l 'VariQus GDVCIrnmenl :.gtnc:ies li,e. DeþBnment 01 Tra~riM, ()(:r).,p,riQIW SlIr"" ,nrt H~,,"" lIdminiSlrllllOn. Food IIId Druo I'Gmlrnl\TlOOll and OIller$I may IIavI! IllKiIlc rtguIa1iOnS conceming d... .",nllpll'laIIuII. handling. &IOfage or 11&8 011hÌ5 procluc:t .IIICft may nor Þø øm..,ned llerein. The CUJUlm,,' or us.r 01 Ihb ",__ G/IOUId bel lamIIJ:It willi __ rogutallclnS. ~ I ...... PAGE 5 ~ ADDmONAL DATA TPADENAME AND SYNONYMS (CONTINUED): Liquid Oxygen; LOX; Oxygen, refrigerated liquid (cryogenic liquid). HEALTH AND HAZARD DATA (CONTINUED): Note: Except where specified, the health hazard data and most of the other data in this material safety data sheet are for gaseous oxygen. One volume of liquid oxygen at its boiling point and atmosphemic pressure will vaporize into approximatelv R60 volumeR of ga.c;eow; oxy¡en at 70!;lF (21.1 !;IC) and 1 atmo!;phere. .SPECIAL PROTECTION INFORMATION (SPECIAL, MECHANICAL, OTHER; CONTINUED): Where oxygen may be released, provide adequate ventilation to prevent excessive oxygen enrichment of the workplace atmosphere (holding at less than 23% 02 by YOlume is recommended for fIre safety). Personnel who ha~e been exposed to high concentrations of oxygen should stay in a well-ventilated or open area for 30 minutes before gojng into a. confined space ornes.r an i~tion source. Workers handling or transfening liquid oxygen should wear safety glasses and face shield, clean approved insulated gloves and other protective clothing as required to prevent skin contact. Gloves and protective clothing must be of materials that are resistant to ignition on contact with Iiquid oxygen. Leather gloves and safety shoes are recommended. ' Safety shoes and safety glasses are recommended when handling containers ofIiquid oxygen. Clothing that has been overexposed or contaminated with OxygeD should be removed and considered unsafe (highly flammable) to wear for at least 30 minutes- If oxygen-enriched clothing catches fire, extinguish the flame under a safety shower; a fire blanket may not be effective in this situation. Use a continuous water spray to soak the clothing of a rescuer who must operate in an oxygen-enriched fire area. Contact lenses pose a special hazard; soft lenses may absorb irritants, and all lenses concentrate them. REFERENCES 1. L'Air Liquide Encyclopedie des Qaz. Contact Liquid Air Corporation Corporate Safety Department, 510-977-,6500. 2. Compressed Gas Association (CGA) Pamphlet P-l "Safe Handling of Compressed Gases in Containers"; G4 "Oxygen-; G-4.1 "Cleaning Equipment for Oxygen Service"; G-4.4 "Industrial Practices for Gaseous Oxygen Transmission and Distribution Piping Systems"; P-2 "Characteristics and Safe Handling of Medical Gases"; P-12 "Safe Handlipg of Cryogenic Liquids"; P-14 "Accident Prevention in (ßygen-Rich and Oxygen-Deficient Atmospheres". CGA telephone number is 703-979-0900. ';. . ',. , " , .¡'~ ,,' .. wo"" ,,' ... .. - --..-- ,--......, ,. '\ FEB 02 '00 14:52 P.2/5 of e e MATERIAL SAFETY DATA SHEET DATE ISSUED: 04/07/97 SUPERSEDES DATE: 08/01/96 ******************************************************************************************* PRODUCT: 142 Solvent MANUFACTURER: KERN OIL & REFINING CO. 7724 EAST PANAMA LANE BAKERSFIELD, CA 93307 EMERGENCY PHONE NUMBERS: POISON CONTROL CENTER: 800/346-5922 CHEMTREC: 800/424-9300 KERN OIL: 805/845-0761 SECTION I - MATERIAL IDENTIFICATION TRADE NAME: 142 Solvent PRODUCT CODE NO.: XOPO 2 6 GENERIC NAME: Petroleum distillate CHEMICAL NAME: Mixture of petroleum hydrocarbons Petroleum spirits, high flash naphtha, mineral spirits CAS No,: None SYNONYMS: RTECS No.: None CHEMICAL FAMILY: Aliphatic and aromatic hydrocarbons CERCLA RATINGS: (Scale 0-3) HEALTH 2 FIRE = 2 REACTIVITY == 0 PERSISTENCE o NFPA RATINGS: (Scale 0-4) HEALTH = 1 FIRE 2 REACTIVITY = 0 SECTION II - COMPONENTS AND CONTAMINANTS RECOMMENDED EXPOSURE LIMITS PERCENT COMPONENT CAS ~ 8 HR TWA STEL CEILING AGENCY* 100% 142 Solvent None NON E (see Stoddard solvent) Stoddard Solvent 8052-41-3 100ppm A,e 350mg/M3 180 Omg /M3 N <:O.lt Benzene 71-43-2 lppm 5ppm A,e O.lppm 1ppm N *A=ACGIH; O::OSHA; N=NIOSH .:. ~ , FEB 02 '00 14:53 P.3/5 é~ e e PRODUCT: 142 SOLVEN'l' SECTION III - PHYSICAL AND CHEMICAL CHARACTERISTICS DESCRIPTION: A colorless liquid with a characteristic petroleum hydrocarbon odor. MELTING POINT: NA BOILING POINT/RANGE: 375-415° F VAPOR PRESSURE 0.2 psia @ 100" F % VOLATILE BY VOLUME: 100% VAPOR DENSITY: Heavier than air EVAPORATION RATE: Slower than BuAc = 1 SOLUBILITY (WATER) Negligible SPECIFIC GRAVITY: 0.81 API GRAVITY: 42 VISCOSITY: 1 cSt @ 1000 F POUR POINT: NA SECTION IV - FIRE AND EXPLOSION HAZARD INFORMATION FLASH POINT (METHOD): 1420 F+TCC EXPOSURE LIMITS (% BY VOLUME/AIR): LOWER: 1% FLAMMABILITY CLASS (OSHA): II AUTOIGNITION TEMP: 5000 F UPPER: 7% FIRE/EXPLOSION HAZARDS: This material is a moderate fire and explosion hazard and may be ignited by an ignition source above its flash point. Vapors may travel to ignition source and flash back. Containers may explode in fire. Vapor explosion hazard indoors, outdoors or in sewers. Emptv Containers retain material residue and may generate vapors which may ignite and explode. COMBUSTION PRODUCTS: Carbon dioxide, carbon monoxide and water vapor. EXTINGUISHING MEDIA: Carbon dioxide, dry chemical, foam and water spray. FIRE FIGHTING PROCEDURES: Wear protective equipment and clothing when fighting fires, including a self-contained breathing apparatus for fires in enclosed spaces. Use water spray to cool fire-exposed containers, to dilute and disperse vapors, protect personnel, and to flush unignited spills from fire. SECTION V - CHEMICAL REACTIVITY INFORMATION STABILITY: Stable under normal conditions of storage and handling. REACTIVITY: Reacts vigorously with strong acids and oxidizing agents. INCOMPATIBILITY: Incompatible with strong acids and oxidizing agents, HAZARDOUS REACTION/DECOMPOSITION PRODUCTS: Burning produces carbon dioxide and carbon monoxide. May release acrid smoke and irritating fumes. CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION: Hazardous polymerization has not been reported to occur under normal temperatures and pressures. .:. .' . FEE 02 '00 14:54 P.4/5 e e PRODUCT: 142 SOLVENT SECTION VI - HEALTH HAZARD AND FIRST AID INFORMATION HEALTH HAZARDS: GENERAL: This material is an aspiration hazard and defats the skin. Breathing vapors at high concentrations may cause central nervous system depression. OCULAR/EYE: This material may cause eye irritation, Contact with the liquid may cause burning, tearing, and redness. DERMAL/SKIN: This material may cause skin irritation. Prolonged or repeated contact may cause burning, redness, drying and cracking of the skin, and dermatitis. INHALATION/BREATHING: Exposure to mists or to excessive vapor concentrations may cause irritation of the nose, throat, and respiratory tract; defats the skin; and signs of central nervous system depression; i_e., headache, nausea, drowsiness and dizziness. INGESTION/SWALLOWING: Accidentally swallowing this material can cause irritation of the stomach and digestive tract. Larger ingestions may cause signs of central nervous system depression; i,e" headache, nausea, drowsiness and dizziness. This material is an aspiration hazard and may enter the lungs when swallowing or vomiting and cause serious lung damage. CHRONIC/OTHER: NO known chronic effects. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: pre-existing skin disorders. Chronic pulmonary disease, 'IRST AID: OCULAR/EYE CONTACT: Flush the affected eye(s) with water. If irritation develops, seek medical assistance. DERMAL/SKIN CONTACT: Remove contaminated clothing and flush contact areas with water and then thoroughly cleanse contact area by washing with soap and water. If irritation or redness develop and persist, seek medical assistance. INHALATION/BREATHING: IF VICTIM IS NOT BREATHING OR IF BREATHING DIPFICDLTIBS DEVELOP ARTIFICIAL RESPIRATION OR OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. If symptoms persist, seek medical assistance. INGESTION/SWALLOWING: DO NOT INDUCE VOMITING/ASPIRATION HAZARD. If victim is conscious and alert, give milk or water to drink. Seek immediate medical assistance. ~ FEE 02 '00 14:54 P.5/5 ~ . e e PRODUCT: 142 SOLVBNT SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE SHIPPING INFORMATION: D.O.T. SHIPPING NAME: combustible Liquid, N.O.S. D.O.T. ID NUMBER: NA 1993, III D.O.T. HAZARD CLASSIFICATION: Combustible liquid. SHIPPING REGULATIONS: No label required. See DOT regulations 49CFR 173 for packaging requirements. STORAGE: Store in closed containers in a cool well-ventilated area away from all heat and ignition and strong oxidizing agents. Containers should be electrically bonded and grounded when transferring materials. HANDLING: Uee in a well-ventilated area and wear recommended protective equipment and clothing. Use explosion-proof tools and equipment. Avoid eye contact, breathing vapors or mists and prolonged or repeated skin contact. Label all unattended containers. MISUSE OF EMPTY CONTAINERS CAN BE HAZARDOUS. COMPLETELY DRAIN AND HAVE COMMERCIALLY CLEANED BEFORE ANY REUSE. KEEP CONTAINERS CLOSED. DO NOT USE TO MIX OR STORE ANY OTHER MATERIALS BEFORE THEY HAVE BEEN COMMERCIALLY CLEANED. DO NOT CUT, WELD, DRILL OR SUBJECT CONTAINERS TO HEAT OR FLAMES. VAPORS MAY IGNITE AND EXPLODE. SPECIAL PRECAUTIONS AND COMMENTS; Enclosed or head spaces in material tanks, pipes or containers may contain hazardous concentrations of fumes or vapors. Exercise caution and wear recommended protective equipment and clothing when opening valves or tank and maintenance or sampling where there is a potential for exposure to these fumes or vapors. SPILL OR LEAK PROCEDURES: Evacuate area around large spills. Remove all ignition sources and provide explosion-proof ventilation. Wear recommended protective clothing and equipment. DO not allow spills to enter sewers, streams or surface waters. Dike and contain spills. Use inert absorbent to reduce fumes and to pick up spill. Collect for later disposal. DISPOSAL PROCEDURES: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. SECTION VIII - PERSONAL PROTECTION AND ENGINEERING CONTROLS EYE AND FACIAL PROTECTION: Chemical goggles are recommended to prevent eye contact. SKIN PROTECTION: Protective gloves and clothing are recommended when prolonged contact with the concentrated material may occur. RESPIRATORY PROTECTION: In situations where vapor concentrations exceed the recommended exposure limits, a NIOSH approved organic vapor cartridge or air-supplying respirator should be worn. VENTILATION: Explosion-proof general mechanical ventilation and local exhaust are recommended to maintain vapor concentrations below the recommended exposure limits. OTHER: An eye wash and a source of running water should be available to flush or wash the eyes and skin. .:. "/ c:~ \. . .. Feb-14-00 11 :19am From-SAMPSON STEEL e LIQUID AIR Center +8818841809 T-911 P.OZ/08 F-189 e Material Safety Data Sheet AN AIR ~IQUlpe GROUP COMPANY OXYGEN GAS "'-- " PROOUCT NAMe EMERGENCY RESPONSE INFORMATION , Oxygen Gas J IN CASE OF EMERGENCY INVOLVING THIS MATERIAL., TELEPHONE CALL CAY OR NIG/"IT.....,..,.... '-800·231-,366 (510) 977-6500 OR CALL CHEMTAEC AT ...... 1-800-424-9300 L.IOUID AIR CORPORATION TRACE NAME AND SYNOfl,lYMS CAS NUMBER ¡ CAL.IFORNIA PI-AZA, SUITE 35Q Oxygen 7782-44-7 ¡ 2121 N. CALIFORNIA BL.VD. CHE~CAL.NAMEANDSYNONVMS NFPA'704 NUMBER (IiFR) I WAL.NUT CREEK, CALIFORNIA 94596 Oxygen 0 0 0 0>"1' I ISSUE DATE R S f) 9 FORMUL.A MOLECUL.AR WEIGHT CHEMICAL FAMilY &. REVISIONS ev. ept. -, 1 91 O2 31.999 Oxidizer I CORPORATE SAFETY DEPT, HEALTH HAZARD DATA TIME wEIGHTED AVERAGE EXPOSURE LIMIT ' None established (ACGIH. 1989-90). Oxygen is the "vÜ:¡,] element" in the atmosphere in which we live I and breathe (approximately 21 molar (volt...me) percent of the atmosphere). The minimum oxygen I content in workplace air is 18'70 by volume under normal atmospheric pressure, equivalent to a partial I pressure. pO:! of 135 torr, (ACGIH 1989-90). SYMPTOMS OF EXPOSURE The primary route of entry is inhalation_ Acute health effects: Adults can satisfactorily breathe pure oxygen for extended periods at 0_33 atm, or at 1 atm for se\'eral days at less than 5 hours a day. However, irrit~tion to mucous membranes may occur when 100% oxygen is inhaled continuously for several hours. Chest pains and cough can result from breathing 0.. at 1 atm for 8 to 24 hours or 2 atm for 2 to 3 hours I or from an atmosphE-r~ of60~ oxygen for se"el'sl days, Breathing high concentrations gre¡¡tl!r than 75 (mobn percent by vohlm~ at :ltmospheric pressure for more than a few hours cau~e:s symprum:s ul hyperoxl;l (high oxyge;:n exposure) with a vane~y of cr=ntral nervous system effects_ These $ympcomj include cramps, nausea, dizzmess, hypotht:rmia <low body temflerat\.4re), ambylopia (dIminished "isian),' nasal stuffiness, cough, sore throat, chest p~un, respiratory ddTIculties, bradycardia (slow h~an r;:¡re>, faiming spells. and convulsions capable of leading to death, Breathing oxygen :it higher pressures increases the likelihood of ;:¡dverse effects within a shorter tim~ ::¡erioc! For addlt10nal d:1t:l on hyperoxb (hIgh oxygen e~po:;url!i 3,:> it re!Jtes to oxygen prL!ssure .,md ~xpo~ure dUl":ltlOn, refei' tu L'Air Liquide'.:ò £ncyc!opedit:' d~:; G:.J~_ Chronic health efft.:cts: ~one ·:!:3t3bhshed. !\ledic~l conditions gener~lly ;lgb'":r:.lv;.tted by e~posure: See NOTES TO PHYSI· . ClAN, below. i NOTES TO PHYSICIAN: , Supportive treatment should inc1ude immediate sedation, anti-convulsive therapy ifneeded. and resr. : Anim:¡l studies suggest that the administration of cert:un drugs, including phenothiazine drugs and i chloroqumt:'. increases the :>usceptibility to toxlcny from oxygen :It high concenrraÜons or pr/:!$sures Anim::t studies ::llso Indic::l[~ th;lt \"it<.1rnin 12 dCtìCI\1[1\:y m:ly inc:re;¡:)e ::il.l~c;:epnbihty to oxygen [(¡xit:ity . Airway obstr~ction during þigh oxygen tension may C:luse al "eolar collapse following absorption ofrhe i o:xygen. SImIlarly, occluslOn of the eu:)tachlan tubes may cause refraction of the eardrum and ObStruc:tIOn of the paranasal sinuses may produce ·vacuum~type" headache. I Newborn premature infants exposed to hìgh oxygen concentratlons may suffer delaved retinal damage which can progress to retinal detachment and bhndness (retrolental fibroplasia). Retinal damage can also Occur in adults exposed to 100% oxygen under gre9.ter than 3.tmosphel-ic pressure, particu1::.Jrly in , indiV1duals whose retmal cIrculatIon has been previously compromis~d. All individl.lals expos~d fOl'long periods to oxygen at high pressure and all \'I'ho exhibit overt oxygen j toxiClt)' should have ophthalmologic ex~mi:¡.arluns. : -- , _. ~ " --... JyC¡;I:rr:I:"'I~ ". ,g ,nl ~",,~g,lol, or tnJormal,on n('Sln 10' þw'eI\ase(s Pu,PC>d> ~,e "'Þ~~.:~r~y p~rc~aSQ' S 'ds,ons.II"rf "nere~O'D all~:uQn ,..~O/l¡C:S earl /las IIdD/I la~ð(l ,n " . ¡:rCP¡:¡¡Lor: ç: S~C:1.:IIOIITl¡;~on. '-'QWlO ¡¡,I Ccr¡¡:lr:tLgn .Jlcntl~ r,o ..¡¡¡¡ro,es 11":,65 ~o ,e:res~n:~I,o"'$ ¡¡~J JSs..ncs no ,,,spon"",,I, ¡s to \!'Ie :lCe.ri;) oJ: _w,...o...l, 01 ,..,n .r.,.;¡::,~¡:.:" I~r ::¡:..C:l1 " 1:1 :_,cnaS8r S ¡/)Isnosq P,",POSltS '" e:M"qw~nces 01 .S ~se j,nco L,:t..g "'·r C~.':>:r~"cn "as "'0 coml<:" o-er ,n.. uS.. O'ln,$ ~ro:.~I, .. J5$w~6S n::l "a:.,,!, rOr '.m~~. Cr <:n Cf ;r,;__"- :"S~ .,,,,~ "om )Iote, (01 ,rr.ÇfJ;~:, ~se (I ~:;..c_I:n .1 '~d :':J_=: C:.'. S~.~fl; rr::. ce e,ançdO .'Jm I rre Ie :..'T:C i!e ~..f' 10 C:~h~ :n: ;:t:..I;1 ':':.1,<::\ L.\C 05,;,;; ·';,'"!"9U -- ,. T-911 P,03/06 F-169 Feb-14-00 11:2~~~om-SAMPSON S EL Center +6618641609_ ! TOXICOL.OGICAL. PRO~ERTIE ,., At normal concentration and pressurc, CJ~ygen pos<t$ no toxÜ;lt~ h:l'~:J,rd~. Howen~r. at ele,,:ned ' concentrations and preisurcs, oxygen may C"I\..L;'í~ ad,,!:!,:>!:! effc¡;t~ I,It hyperu:<la \hlgh oJç.yg~n cxp\J;,>ur~ which leµds to pneumonia. COnC¡;ntl"at:lons betwel:!lì 25 and 75 molar p~n:ent present a risk of, inflammation of organic matter in the body. Listed as Carcinogen National Toxicology YES 0 l.A. R. C_ YES 0 OSHA YES 0 or Potential Carcinogen Program NO !XI Monographs NO IXJ NO Œi WARN1NG FOR MEDICAL For oxygen deficiency In breathÜ"I.g persons or emergency resuscita- OXYGEN U.S.P.: tion when used by personnel instructed in oxygen administration. fvr oth~r m~di,al applications, u~e only as difec.:ted by a licen:ied practitioner. Uninterrupted use of high concentrations of oxygen over a long dUfaÜan, without monitoring its effect on oxygen content of arterial blood. may be harmfuL. Use only with pressure reducing equipment and apparatus designed for oxygen. RECOMMENDED FIRST AID TREATMENT PROMPTMEDICAl.ATIENTION IS MAN'DATORYIN ALL CASES OF OVEREXPOSURE TO OXYGEN. RESCUE PERSONNEL SHOULD BE AWARE OF EXTREME FIRE 1L\2ARD I ASSOCIATED WITH OXYGEN·RICHATMOSPHERES. REDUCE OXYGEN PRESSURES TO 1 ATMOSPHERE AND/OR MOVE VICTIM INTO FRESH AIR. Conscious persons should be assisted to an uncontaminated area and breathe fresh air. They should be kept warm and quiet, The physician should be informed that the victim is experiencing (has experienced) hyperoxia (high oxygen exposure). Uncon5cio~s persQns should be mo"ed to::in uncontaminated tlrea and gwcn 3ssisted rcspi'3tion. When breathing has been restored, treatment should be as above. Continued treatment should be symptom- atic and s~pportÍ'o'e.· . HAZARDOUS MIXTUReS OF OTHER LIQUIDS, SOLIDS, OR GA.SES Although not flammable itself. oxygen vigorously accelerates fire and combustion (burning). Contact with aU flammable materials shoulr:! be avoided. Some m:iterlals which are not flammable in air wIll burn in pure o:(ygen or oxygen-enriched atmospheres. Materials that burn in air can burn with ~xplosíve ....iolence in a pure oxygen or o;<ygen-~nriched atmosphere. PHYSICAL DATA BOIL.ING POINT LIOUIO DENSITY AT BOILING POINT I -297,35"F C-182.97°C) 71.23 IbtftJ (1141 kglm]J; specific gravity = 1.1-'1 vAPOR PRESSURE @ 70°F (21.1"CJ a.bove the GAS CEt.-cSITv AT7Qi F lATM I critical temp. of ·181.433°F (-118574°C) , 0828 lbtft) n.326 kg/mJ) SOlUSI\..IT\' IN WATER FREEZING POINT @ 68°F (20°C) Bunsen coeffiClent = 0.0310; , -36L838°F (-218.799°C) j 3.1ëcmJ 11COg @ 25"C I APPEARANCE AND ODOR I Colorless, odorless and tasteless gas_ Specific gravity @ 70"F (Air = 1.0) is 1.11. FIRE AND EXPLOSION HAZARD DATA IAUTO IGNITION TEMPERATURE FL.AMMASL.E LIMITS % BY VOLUME. Not A licable Not A licable . EL.ECTRICAL. CL.ASSIFICA TIO/ll Nonhazardous FLASH pOINi lMETMOD USEO) Not Apphc::able EXTINGUISI1ING MEDIA CO ious uantities of water fOT fires with OXy en as the oxidizer. SPECIAL. FIRE FIGHTING PROCEDURES If possible , seop the flQW of oxygen which is supponmO" the fire if you can do so wjthout risk. U f~ media that are appropriate to t:he sWTol,mdmg fire. Immediately coo, fire-exposed comainer, standing at: a :safe dist:anl.:e as far away;.1S possIble and using:1 Water spr:ìy. IffE:i3..sible, remove oxygen containers from fir~ ares. Containers may e;..plode m t:he heat of fire. Though not t1JJnmable itsdf, oxygen V1gorously supports combustiCln. Matenals that do not burn In wr may bLlITl in oxygen-ennched air (::-23% oxygen). Some materials can eVen become spontaneously flammable in oxygen or oxygen-enriched air. Oxygen released in a fire situation greatly , increases fire and explosion hazards. (Oxygen cylinders are equipped with safety device~ to release 02 at excessive temperature or pressu.re). UNUSUAL fiR!: AND EXPLOSION I1/1.ZARDS Hiah pn:~;)~ur~ oxidizmg g::¡s. Cyhndl:1" pre:::SU1"c Io:Jn Ot' :2,UOU - J,OOO pSI G íO~F 1J1" up to Ö.\JUU P::¡I ~ 7lrF fur ultra- high pre~sure cylindtfs. VIgorously acceler::¡te::i combustion lburnmgJ. No smoking 10 c.:ylinQ~1" .!1'I:/:IlJr \~ hUe oxyge!1 J5 In u.se. !{~ep oil3.nd grease aW:lY. K~ep oxygt:n ~yhnders aW:lY from fbmrn~,ble:i anci comcu:)[lol=::¡ ", Feb-14-DD 11 :2Dam From-SAMPSON SIEL Center +88188418D9 ~ I·{I:::AL: IIVII V UA I A ., STABILITY CONDITIONS TO AVOIC UNSTAeL~ Oxygen is stable when kept isolated as a compressed gas in cylinders. " _, rhis material is an oXIdIzing '!-gent that vigorously accele~ates combus- t STABLE X hon (burning, fire). Oxygen wIll undergo hIghly exothermIc reactIOns or ' 'NCOMPATIBILITY explosions with m3.ny materials. The greater the concentration of 0 in " : .' IhI'&T£RIA~S TO AVOID, . h r. 1 d h h' I f ih '- ' contact Wlt a ¡ue or re uClOg agent t e greater t e VIO ence 0 l e T-911 P,D4/D8 H69 , , All flammablt:' matenals. ¡ fe¡,¡ction. Air I.:untgin~ 21 percent oxygen; real.:twity with envIronmenlal ~ HAZARPOuS PECOMPOSITICN materials is $ubst3f1t1ally increased D.t above 2:j p~rct::nt oxygen by I PROOUCTS volume_ , Oxygen reacts eX~OSively with phosphine, hydrazine, hydrogen sulfide, I None ethers, alcohols, ydroc:lrbons, etc. Red-hot steel burns in an oxygen HAZARDOUS POLYMERIZATION atmospnere. This material is incompatible with oils, grease, l~bricants, MA Y OCCUR asphalt, and flammable materials, Keep oxygen cylinders free 0[01] and! or grease. , , CONDITIONS TO AVOID , WilL NOT OCCUR X Not applicable , I SPILL OR LEAK PROCEDURES STEPS TO BE TAI<EN IN CASE MATERIA~ IS REL.EASED OR SPIL.LEC Evacuate all p~rsonnel from affected ares. Use appropriate protective equipment (Refer to "SPECIAL PROTECTION INFORMATION" section). ProvIde optimum eJChaust ventilat.ion. If at all possible, shu~ off the so~rce of the oxygen 1eak ifyo~ C:in do ::\0 without risk. Remove sources of heat, ignition and, if feasible, separate combustibles from the leak. Shut off all internal combustion engines within 50 feet of affected area. Small leaks in an oxy~en system in an enclosed. unventilated area can build up .,. hazardous oxygen level. Ifleak is in user s eq1..upment, be certam to purge pIping wIth an inert gas prior to attempting repairs. SNOOPØsolutions for oxygen service may be used to detect gaseous leaks. Ifleak is in container Or container valve, contact the closest Liquid Air Corporation location_ WASTE PISPOSA~ METHOD Do not attempt to dispose ofre~iduJ.l or unl.lsed qu:mtities. Return in the shipping container tagged to indicate a defect, and properlv !ahp!ed, with ~\nv valvE' outlet nlu~s or caps secured and v~l\1e protection { . cap in nlact" to Liquid Air Corporation for proper di$po~n1. For emergency disposal. comact the closest _ ÜqulCi Ale Corporation 10cat1on. '-- .'~: SPECIAL PROTECTION INFORMATION RESPIRATOR.,. PROTECTION (SPECIFY TYPE) Not applicable VENTILATION To prevent ;.iccumulation above 23 molar percent Loe AL. EXHAUST. . To prevent :lccl.lmu!:.1til,Jn :lbov£? 23 mO,l" pcn.:ent MECHANICAL (GEN.) See a e 4 SPECIAL PRECAUTIONS· SPECIAL LABEL.ING INFORMATION DOT Shipping Name: Oxygen, compressed DOT Shipping Label; Oxidiz~r or O~ygt:n SPECIAL HANDI-ING RECOMMENOATIONS Use only in well-ventilated areas. Valve protection C:lp:) and ....alve oudet threaded plugs must rem:3.in in place unless cylinder is secured with valve o~t1et piped to use point. Do nOt drag, slide or roll cylinders. Use a suitable hand. truck for cylinder movement. Use a pressure redudng regulator when connecting cylInder to lower pressure «3,000 psig) pi ping or syste ms. Do not heat cy linder by any means to increase . the discharge rate of pre duct from the cylinder. Use 3. ch~ck v;.llv~ or tl"3p in th~ discharge line ty prevent ' hazardous back flaw into the: ~yiinder. Close cylineter vah'e alter each use and ',-hen cylinder is empty, , I DOT H:lzard Class: Nonflammable gas; Class 2. D¡\.1~¡on 2.2 I I.D. ~o . U:'-J' 1072 ~ '--- rOI :"QOlltOn~t n,Jr,.Q~ti 1....~clT'lmlþr¡,,:~..o(\~ ~..G r1cH..rc;'n~~t Of1 ..J.ill j:).J.,;e ·V&,,~..~ .,..q"CfM..;n, .111C'tC.c~ ~t" Oap~"me"l or T,),n~~I.Qn. Qc:(:~~l~n"'l $"~~'r ..:-;0 n"..._n ,....n.·n':IIZtJ~.on p'coa ~:".q; ~I_" ..g:T1·n·,;,.·..lIcn .na o¡nilln, rr., nø.. ~ø\"-c., c rc;....a',on.. conc-.rn.ng ~". ,ra.~øQn4hon "ancl.·ne ,~r~;a or ",¡lit or ,P\tS prOCS...C1 ..f'oCn l!\~, t'tO: c.. CQ,.~·t\.G rw.Q·" Tne '...~tOmt'( cn ...:'4;lJ a. ''''130 pfOCl...,~ $I\O...IØ 00 f.II1.I.¡¡, p.,n ","05. ''''9_I.u.on:a. LAC OS12719/~911 ,,-. \.... '"- T-911 P,05/08 F-189 Feb-14-00 11 :21am From-SAMPSON STEEL Center +8818641609 e ..' e spetlAL STORA~~ RECOMMENDATIONS ' P.rotect cylinders from physical c!amage. Store in clean, cool, dry, well-V'entilated area away from heavì1)' trafficked areas and emergency exits, away from combustibles and away from fun or empty stored cylinders which contain flammable products. Do not allow the temperature when~ cylindtrs are ~:ìtored to exceed 125QF t52QC>. Cylinders should be ~tored upright ::md firmly secured to pre....C!nt falling or being knocked over. Full :md empty cylinders sho~¡ld be 5egregated. Use a "fïfst in - tir5t uut" 111"~ntory ~y:)lem to prevent fl1.l1 cylinders being stored for excessive periods of time. For add.llonal storage recommendallons see Aelerence seellon cm In'S page. "Ill-I:: . .: SPECIAL. PACKAGING RECOMMENDATIONS Carbon steels and low alloy steels are acceptable for use at lower pressures (less than 1,000 psig), For higher (to 2900 psig) pressure appJicJ.tions, use stainless steels, copper and its aHoys, nickel and its alloys, brass, bronze, silicon alloys. Mone@, Inconel@, or beryllium. Lead and silver or lead and tin alloys an: good. gaskeung matenals. Teilon® and Kel-F@ 3re the preferred nonml:t3l gaskets. CGr.. valvt! o~tlet for oxygen gas is CGA 540 {to 3,000 psigJ; CGA 870 for medical gas pin-indexeci yoke (onnect:Ïon. Special Note: It should be recognized that the 19nLtion temperature of metals and nonmetals in "pl,¡re oxygen service decreases with increasing oxygen pressure. For addltlonal information refer to L'A:r Liquide's Encyclopedie des Gaz. It is also important to avoid high Eas velocities which tend to increase the possibility of ignition by fnction, impact and static dischacge. Refer to Compressed Gas Association Pamphlet G-4,4 for velocity limits. OTHER RECOMMENDATIONS OR PRECAUTIONS Oxygen must not be used as a substitute for compressed air in pneumauc equipment since this type generally contains flammable lubricants. Do not l1.se oil or grease to lubricate the valve on an oxygen cylinde. or regu1s.;or. Equipment to contain oxygen mu.st be ~cleaned for oxygen service" a.nd rated for cylinder pressure. See Compressed Gas Associatlon Pamphlets G-4 and G-4_1. Open and close cylindel' valve slowly, Ground equipment to eliminate buildup of static charge. Keep sparks, flame and lighte¿ cigarettes away from cylinders and under no circumstances allow a torch flame to come in contact with cylmders, valves, or pressure relief devices. Should the valve outlet of a cylinder become clogged with ice, thaw with warm.. not boiling u Water. Compressed gas cylinders should not be refilled except b) qualified suppliers of compressed g3ses. Shipmem of a compressed gas cylinder which has not been fillec by the owner or with his (written) consent is a violation of Federal Law (49CFR). WHEN USED 11\ WELDING AND CU'M'IN"G: Read and understand the manufacturer's instructions and thej)rec8uo donary label on the product. See American National Standard 249.1 "Safety in Welding and C¡,¡tting' published by the Americ:ln Welding SocietY, P,O. Box 351040, Miami. Florida 33135 and O:3H.~ Publ~catlon 2206 (29CFR1910J, U.S. Goyernment Printing Office, Washington. D.C: 20402 for mor~ dt?t:li1. NOTE: Suitability for use <.l:S a component in underwater breathing gas mixtures is to bl determined by or under the supervIsion of personnel experienced in the use ofunderwater breathing ga~ mixtures and familiar with the effects. methods, frequency and duration of use, h3zards, side effects anc precautions to be taken. Use in accordance with Material Safety Data Sheet. SPECIAl.. PROTECTION INFORMATION (SPECIAL, MECHANICAL. OTHER; CONTINUED): Where oxygen may be rele¡:¡sed. provide adequate ventilation to prC!\'C!nt exce;;si\'e o~ygen enrichment of the workplace atmo::)phere (holding J.t <23'1(10, by volume IS recomml:'nded tor fire :iafety). Personne' who have been exposed to high concentratIons of oxygen should stay, in a well-ventilated or open are~ for 30 minutes before going into a confined space or near an ignition source, Safety shoes and. safety glasse~ are recommended when handHng cylinders of compressed gas. Clothinf that: has been overexposed or contammated with oxygen should be removed and considered unsaft (highly flammable) to wear for at least 30 minutes, If oxygen-enriched clothing catche5 tire. o;:<ttinguiÛ' the f1am~ under a safety shower, 3 fire blanket may not be effective in this situation. Use a contin1J.OU~ water spr:\y to o:¡o3k the ch~thingofa n;!sc~er who must operate in :.m a:xygen-enrichè!d t1re area. Contac lenses pose a spec~al haz;.1rd; soft lense.; mè:\Y absorb irriti:lnt.:ö. and all lenses conc~ntr:3.t.e them. REFERENCES 1. L'Air Liquide Encyclopedie des Gaz, Contact Liqu.1dAlr Corporation Corporate Safety Department, 510-977-6500. 2. Compressed Gas Association (CGAJ Pamphlet pol "Sa~e Handling of CO!J1pressed Gases .m Containers"; 0-4 "Oxvgen"; G·4.1 "C!~:¡nl1ìg Eql-upmem lor O:'l.)'gen ServIce: G-4.4 "Indusmal Pr:lctlce~ fot' G~s~ous Òxygen Tr=:Ln~mis,;ion and Distribution Pipmg Systems". CGA telephone number is 703-979-0900. 1.-\(.; 031:.2';' 19/2/911 ~~ ~ _, ,.... "'..... r'o¡¡' '-'v f.r vnMI IUI'4 .... e e IN~USTRIAL GASES DIVISION :¡ \..-t Material Safety Data Sheet JQUID AIR CORPORATION ..OUSTRIA" GASES DIVISION One Calitornia Plaza, Suite 350 2121 N. California Blvd. Walnut Creek, California 94596 SSUE DATE OCTOBER 1, 1985 ~ND REVISIONS CORPORATE SAFETY DEPT. PRODUCT NAME Acetylene TELEPHONE (415) 977·6500 EMERGENCY RESPONSE INFORMATION ON PAGE 2 TRADE NAME AND SYNONYMS Acet lene Eth ne CHEMICAL NAME AND SYNONYMS CAS Numher: 74-86-2 MOLECULAR WEIGHT C H 26.0 CHEMICAL FAMILY Alk ne HEALTH HAZARD DATA TIME WEIGHTED AVERAGE EXPOSURE LIMIT Acetylene is defined as a Slmp e asp YXlant. s should be maintained at greater than 18 molar percent at normal atmospheric t!hich is e uivalent to a artial res sure of 135 mm H. ACGIH 1984-85 SYMPTOMS OF EXPOSURE Inhalation: Low concentrations (10-20% in air) cause symptoms similar to that of being intoxicated. Higher concentrations so as to exclude an adequate supply of oxygen to the lungs cause unconsciousness. \..J TOXICOLOGICAL PROPERTIES As a narcotic gas or intoxicant causes hypercapnia (an excessive amount of carbon dioxide in the blood). Repeated exposures to tolerable levels has not shown deleterious effects. The major property is the exclusion of an adequate supply of oxygen to the lungs. listed as Carcinogen or Potential Carcinogen National Toxicology Yes 0 Program No ~ I.A.R.C. Yes 0 Monographs No [8J OSHA Yes 0 No [8] RECOMMENDED FIRST AID TREATMENT PROMPT t1EDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO ACETYLENE. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED 'BREATHWG APPARATUS AND BE COGNIZAN~OF EXTREME FIRE AND EXPLOSION HAZARD. Inhalation: Conscious persons should be assisted to an uncontaminated area and inhale fresh air. Quick removal from the contaminated area is most important. Unconscious persons should be moved to an uncontaminated area, given mouth-to-mouth resuscitation and supplemental oxygen. r1edical assistance should be sought immediately. "-- Juogemems as:o the s~ltablhly of IOlormatlon hewn far purChaser's purposes are necessarily purChaser's le~con~lUlllty Theretore. al:nougn re:¡sona~!e care nas neen ta"e~ In tne ?reJa:J:lor:: ~:;c., n:orma:lon. LIOUI:! Air Co:por7.1Ion extenas no warranties. ma~es no representatIons. and assumes no respons:bll~y as to tile aee:me;' or S¡;,'lob,iI!v 01 sucn ¡:¡lormwJI1 101 :¡~~JI:~:,cr.:: :U::~.¡¡e; s 'Ien~eo ~urposes or conseouences at Its use, Since Llouid Air Corporation has no control over the use 01 thiS prooucl. It as~umes no ilabli:ty 101 damag;: or lOSS Gt prOQuCt resu,:'~~ :,::;-, ::::er I:' rnprooen use or apancallon 01 the proOuc:, Data SheetS may be changeO 110m time :0 lime. Be sure to consult the latest eOltion. ,~:: CSIC~ ,-- - ~,_, ~"'-/,I..ICIIICIJ \'iIUC lall~C III air. tXplOSlve reaC-¡:lons may occur on i:¡n~*tion. Reacts eXP10SiiY v/ith halogens and h~lOgena. compounds. ~ f~:\ \ ," ,", ,~.~ '- 0 PHYSICAL DATA 'ILING POINT ublimation point = -118.8°F PcM PRESSURE 45 ps;a (4450 kPa) @ 70°F )LUBILITYINWAT~R @ 68°F (20°C) :oefficient = 1.047 'PEARANCE AND ODOR Pu re carbide acet lene (-83.8°C) (21.1°C) Bunsen = FREEZING POINT Tr' le oint = acetylene is a colorless gas with an has a distinctive qarlic-like odor.S FIRE AND EXPLOSION HAZARD DATA .ASH POINT (METHOD IJSED) 1 AUTO IGNITION TEMPERATURE " I FLAMMABLE LIMITS % BY VOLUME L EL =2 .2 ; ~as 565°F (296°C) UEL=80-85* *See nute on last :TlNGUISHING MEDIA I ELECTRICAL CLASSIFICATION :arbon dioxide; dry chemical Class 1, Group A 'ECIAL FIRE FIGHTING PROCEDURES :f possible, stop flow of escaping gas. Use water spray to cool surrounding :ontainers. Keep personnel away since heated or burning cylinders can rupture tiolently. -¡USUAl.. FIRE AND EXPLOSION HAZARDS i JASEOUS ACETYLENE IS SPONTANEOUSLY COMBUSTIBLE IN AIR AT PRESSURES ABOVE 30 PSIA (207 kPa). page. (Continued on last page.) @,:" ······t 01::.::: 1 -A..J T Ab,...ITY Unliable x REACTIVITY DATA CONDITIONS TO AVOID Do not a to exceed 30 psia. Stable ICOMPATlBILITY(Materlalltoayojd) Oxygen and other oxidizers including all of thE: halogens and Jen compounds. Forms explosive acetyl ide com ounds ~Iith Continued on last AZARDOUS DECOMPOSITION PRODUCTS n CONDITIONS TO AVOID Will Not Occur x SPILL OR LEAK PROCEDURES , TEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Evacuate all personnel from affected area. Use appropriate protective equipment. If leak is in user's equipment, be certain to purge piping with an inert gas prior to attempting repairs. If leak is in container or container valve, contact the closest Liquid Air Corporation location. '{ASTE DISPOSAL METHOD Do not attempt to dispose of waste or unused quantities. Return in the container properly labeled, with any valve outlet pluqs or caps secured : fO ·ection cap in place to Liquid Air Corporation for proper disposal. , ~,osal contact the closest Liquid Air Corporation location. shipping and valve For emergency c~ - '--, EMERGENCY RESPONSE INFORMATION IN CASE OF EMERGENCY INVOLVING THIS MATERIAL, CA~L DAY OR NIGHT (800) 231*1366 OR CALL CHEMTREC AT (800) 424-9300 ~ , :'SPIR~,TORYPROTECTION (SpocHy type) Pas it i ve pressure air 1 i ne vlith masf~ or se If-conta i ned breathi~a aooaratus should b vailable for emer enc use. ËÑm,,ATION LOCALE ST To prevent accumulation SPECIAL Hood with forced ventilation OTHER . " - 'r 'TIVE..GLOVES ~~ or rubber in laborator :YE PROTECTION Safet 0 1 es or 1 asses )THER PROTECTIVE EQUIPMENT uired for cuttin & weldin. SPECIAL PRECAUTIONS· SPECIAL LABELING INFORMATION DOT Shipping Name: DOT Shipping Label: Acetylene Flammable gas DOT Hazard Class: 10 No.: UN 1001 Flammable gas SPECIAL HANDLING RECOMMENDATIONS Use only in well-ventilated areas. Valve protection caps ~ust remain in place unless container is secured with valve outlet piped to use point. Do not drag, slide or roll cylinders. Use a suitable hand truck for cylinder movement. Use a pressure reducing regulator when removing gas from the cylinder. DO NOT ALLOW THE FREE GAS TO EXCEED 30 PSIA (207 kPa) @ 70°F (21.1°C). Do not heat cylinder by any means to increase the discharge rate of product from the cylinder. Use a check valve or trap in the discharge line to prevent hazardous back flow into the cylinder. For additional handling recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Association Pamphlet p.', SPECIAL STORAGE RECOMMENDATIONS ìtect cylinders from physical damage. Store in cool, dry, well-ventilated area of ~~,1-combustible construction away from heavily trafficked areas and emergency exits. Do not allow the temperature where cylinders are stored to exceed 130F (54C1. Cylinders must be stored upright and firmly secured to prevent falling or being knocked over. Full and empty cylinders should De segregated. Use a IIfirst in-first outll inventory system to prevent full cyl inders being stored for excessive periods of time. Post "No Smoking or Open Flames" signs in the storage or use area. There should be no sources of ignition in the storage or use area. For addihonal storage recommendations consult L'Air Liquide's Encyclopedia de Gaz or Compressed Gas Associahon Pamphlet P-1. SPECIAL PACKAGING RECOMMENDATIONS Since acetylene will explode or combust if its pressure exceeds 30 psia (207 kpa) it is shipped dissolved in acetone or dimethyl formam ide which is dispersed in a porous mass within the cylinder. Follow Liquid Air Corporation's instructions for the maximum withdrawal rate for each size cylinder so that solvent is not withdra\~n with the acetylene. Most metals, except silver, copper, mercury or brasses~/ith more than 66% copper, are compatible (non corrosive) with acetylene. OTHER.8ECOMMENDATlONS OR PRECAUTIONS Earth-ground and bond all lines and equi~~ent associated with the acetylene system. Electrical equipment should be non-sparking or explosion proof. Compressed gas rylinders should not be refilled except bj qualified producers of compressed gases. .\-, lipment of a compressed gas .cyl ;~der vlh~ch has not been filled by the O\'/ner or vlith , nis (written) consent is a vlolatlon of ~~deral Law (49CFR). Transport cylinders, in well-ventilated ve~icles,upright and suitably restrained to prevent movement. \éontinued on last pa~:). . 'Varoous Government ac;enc1es II ~. Depanmenr of Transportalion, Cccupal,cr:a' 'So.,let)' and Healtn Admlnlstralion, Food and Drug Admlnlstrat:on and c¡:,ers) may nave ~oec'!'c r~cuI3tICr:S concern,cr:: T 'I IranSCo~atlon, na, nd"r:';) slorage or use ot ~'S :,roouct wn,cn may not be contained nercln Tne cuSlomer or user of :nls proouct sncula LlQ'~ID AIR CORPORATION e IIi¡OU'STRIAL GASES DIVISION e ®....:. .:;::~ '"-: :;; G· ADDITIONAL DATA 10 DENSITY AT BOILING POINT: (Continued) d density @ sublimation point = 45.51 lb/ft3 (729 kg/m3) ¡t~ABLE LIr~ITS ~~ BY VOLUr·íE: (Continued) ,. Pure acetylene can ignite by decomposition above 30 psia (207 kpa); therefore, UEL is 100% if the ignition source is of sufficient intensity. )UAL FIRE AND EXPLOSION HAZARDS: (Continued) ¡equires a very low ignition energy so that fires which have been extinguished stopping the flow of gas can easily reignite with possible explosive force. c=> t)-/_ne has a density very similar to that of air so when leaking it does not readily sipate. . DITIONS TO AVOID: (Continued) inders should not be exposed to sudden shock or sources of heat. OMPATIBILITY (MATERIALS TO AVOID): (Continued) 'per, mercury, silver, brasses containing more than 66% copper and brazing ,erials containing silver or sopper. t~ . e. ........ 1ZJ.~ RECa·~:EL\4'DATIQ.\!S OR PRæAUTIOl'IS (Continued) .'. : '.e incr-easing fire intensity and e.:<plosion 'hazard if cylinders are so piled or it~~ t~at burning gas escaping fr-cm a melted fuse plug (pressure relief device) iyS on otrßr cylinders. . ·'._l "-' . FEE 11 J00 14:07 SERVICE OIL CO ···P.2" , ........,..,...... , e e \', ~1· #. The Valvoline Company MATERIAL SAFETY DATA SHEET Page 001 ' Da~e Prepared: 01/21/98 , Date Printed: 02/14/98 HSDS No: 505.0163802-011.001 M PLUS 30 1. CHEMICAL PRODUCT AND COMPANY iD~T1FldATION Material Identity Product Name: AF PLUS 30 Produc~ Code: 39600012 General or Generic ID: PETROLEUM BASED-LUBRICATING OIL Company Telephone Numbers The Valvoline Company Emergency: 1-800-274-5263 P.O. Box 14000 Lexington, KY 40512 Information: 1-606-357-7847 2. COMPOSITION IINFORMA TION ON INGREDIENTS Ingredient(s) CAS Number ALIPHATIC PETROLEUM DISTILLATES DETERGENT/DISPERSANT ENGINE OIL PACKAGE ZINC Cl-C14 ALKYLDITHIOPH05PHATE 64742-65-0 68649-42-3 % (by weight) --.-.---.-.-- 81.0- 91.0 9.0- 19.0 1.4- L 4 ____.___..____~.ø-_---.M---.-----..----..--- -.--.'-. ---.... , , 3. HAZARDS IDENTIFICATION Potential Health Effects Eye . Exposure is not expected to cause eye irritation or injury.. Skin . Exposure may cause mild skiD irritðtion. Prolonged or repeated exposure may d~ the skin. Symptoms may include redness, burning) drying and cracking, and skin burns. Pre-existing skin disorders may be aggravated oy exposure to this material. ' . Swallowing Single dose oral toxicity is low. Swallowing small amounts during normal handling is not likely to cause harmful effectsi swallowin¡ large amounts may be harmful.. This material can enter the lun¡s during swallowing or vomiting and cause lung inflammation andlor damage. Inhalation ' Exposure is possible under certain conditions of handling and use (for example, during heatingl spraying, or stirring). Symptoms are more typically seen at air concentrat ons exceeaing the recommended exposure limits. ' Symptoms of Exposure , gastrointestinal irritation (nausea. vomiting, diarrhea). irritation (nose, throat respiratory tract) (pre-existing lung disorders, e.g. asthma-like conditIons, may be aggravated by exposure to this material), abdominal pain. ~ , , Target Organ Effects No data ,.. Continued On Next Page FEE 11 '00 14:07 SERVICE OIL CO P.3 ;, e e The Valvoline Company MATERIAL SAFETY DATA SHEET Page 002 Date Prepared: 01/21/98 Date Printed: 02/14198 MSDS No: 505.0163802-011.001 - AF PLUS 30 Developmental Information No data Cancer Information Vsed motor oil has been shown to cause skin cancer in laboratory animals continually exposed by repeated applications. Avoid prolonged or repeated skin contact. Other Health Eifeots No data, Primary Route(s) of Entry No data 4. FIRST AID MEASURES Eyes If symptoms develop! move individual away from exposure and into fresh air. Flush eyes gently W th water while holdiñg eyelids apart. If symptoms persist or there is any visual difficulty, seek medical attention. Skin Remove contaminated clothing. Wash e~osed area with soap and ~ater. If symptoms persist, seek medical attention. Launder clothing before reuse. Swa11ow1ng , Do not induce vomiting. This material is an aspiration hazard. If individual , is drowsy or unconscious, place on left sid'e with the' head down. ~8ek medlcal attention. If possible, do not leave individual unat~ended. . Inhalation If symptoms develop, immediately move individual away from exposure and into fresh air. Seek immediate medical attentionj keep pers.on warm and quiet. If person is not breathing, begin artificial respiration. If breathing is aiffi~ult, administer oxygen. Note to Physictans No data 5. FIRE FIGHTING MEASURES Flash Point > 400.0 F (204.4 C) cae Explosive Limit No data Autoignition Temperature No data Hazardous Products of Combustion May form: carbon dioxide and carbon monoxide, oxides of sulfur, nitrogen' and phosphorus, various hydrocarbons. Continued On Next Page FEE 11'0121 14:08 SERVICE OIL CO P.4 .. e e . . Tbe Valvoline Company MATERIAL SAFETY DATA SHEET Page 003 ' Date Prepared: 01/21/98 Date Printed: 02/14/98 MSDS No: 505.0163802-011.001· AF PLUS 30 Fire and Explosion Hazards Never use welding or cutting torch on or near drum (even empty) because product (even just residue) can ignite explosi~ely. Dense smoke may be generated while burning. . Extinguishing Media re¡ular foam. carbon dioxide, dry chemical. Fire Fighting Instructions . Water or foam ma~ cause frothing which can be violent and possibly endanger the , life of the firefighter. Wear a self-contained breathing' apparatus with a full facepiece operated in the positive pressure demand mode with appropriate turn-out gear and chemical resistant personal protective equipmen't. Refer to the personal protective equipment section of this MSDS. HFPA Rating , Health . 1, Flammability . 1. Reactivity - 0 6. ACCIDENTAL RELEASE MEASURES Small Spi1l Absorb liquid on vermiculite, floor absorbent or other absorhent material. Large Spi)) Prevent run-off to sewers, streams or other bodies of water. If run-off occurs, notify proper authorities as required. that a spill has occured. Persons not wearing protective equipment should be excluded from area of s!)iU until clean-up has been complet'ed. S"t'Op spill at: sourc'e. dike area o"f' sp·nl to prevent spreadingJ pump liqui~ to salvage tank. Remaining liquid may be taken up on sand, clay, earth, floor absorbent. or other absorbent material and shoveled into containers. 7. HANDLING AND STORAGE Handl1ng , Containers of this material may be hazardous when emptied. Since containers re~ain product residues (vaporJ liguid"and/or solid). precautions given in the data sheet must De o~served. storage Not applicable emptied a.ll hazard 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eye Protection Not required under normal conditions of use. However. if misting or splashin& conditions exist. then safety glasses or chemical splash goggles are advised. skin Protection Not normally required. However, wear re8istan~ gloves such as nitrile rubber to prevent irritation which may result from prolonged or repeated skin contact with product., Wear normal work clothing covering arms and legs.. Continued On Next Page FEE 11 '00 14:08 SERVICE OIL CO e P.5 e MATERIAL SAFETY DATA' SHEET 'Page 004 Date Prepared: 01/21/98 Date Priñted: 02J14/98 KSDS No:, 505.0163802-011.001 The Valvoline Company AP PLUS 30 Respiratory Protections Not required under normal conditions of use. However, if oil mists are generated above recommended PEL/TLV of 5 mg/m3 then a NIOSH/MSHA approved respirator is advised in absence of proper envIronmental control. (Consult your industrial hygienist.) Engineering Controls " Not required under normal, conditions of use. However if unusual operating condit!ons exist, then provide sufficient mechanical ~general and/or local exhaust) ventila~ion to maintain exposure belowPEL/TLV (5). Exposure Guide1ines Component ------..._-- ALIPHATIC PETROLEUM DISTILLATES (64742-65-0) OSHA VPEL 5.000 mg/m3 - TWA Oil Kist ACGIH TLV 5.000 mg/m3 - TWA Oil Mist DETERGENT/DISPERSANT ENGINE OIL PACKAGE No exposure limits established ZINC Cl-C14 ALKYLDITHIOPHOSPHATE (68649-42-3) No exposure limits established 9. PHYSICAL AND CHEMICAL PROPERTIES B'o i 1 i IIg" P'oì nt No data Vapor Pressure No data Specifio Vapor Density No data Specific Gravity .890 @ 60.00 F Liquid Density 7.400 lbs/gal @ 60.00 F .890 kgll ~ 60.00,C Percent Volatiles (Including Water) No d41:a EV8DOtatton Rate SLOWER THAN ETHYL ETHER Appeayance No data state LIQUID Continued On Next Page FEE 11 '00 14:09 SERVICE OIL CO e P.6 e !he Valvoline Company MATERIAL SAFETY DATA, SHEET Page 005 Dàte Prepared: 01/21/98 Date Printed: 02/14/98 MSDS No; SOS.0163a02~011.001 AF PLUS 30 Physical Form Not applicable Color AMBER Odor PETROLEUK p'H Not applicable Viscosit7 10.0 .. 12.0 cst 10. STABILITY AND REACTIVITY Hazardous Polymerization Product will Dot undergo hazardous polymerization. Hazardous Decomposition May form: carbon dioxide and carbon monoxide, oxides of sulfur, nitrogen and phosphorus, various hydrocarbons. Chemical Stability Stable. fm.compati'bi 1'1 ty Avoid contact wi~h: strong oxidizing agents. 11. TOXICOLOGICAL INFORMATION No data 12. ECOLOGICAL INFORMATION No data 13 ò DISPOSAL CONSIDERATION Waste Management Information Dispose of in accordance with all applicable local, state and federal regulations. .. 14. TRANSPORT INFORMATION DOT Information - 49 CFR 172.101 DOT Description: Not Regula.ted Continued On Next Page ;¡- FEB 11 '00 14:09 SERVICE OIL CO e P.? e The Valvoline Company MATERIAL SAFETY DATA SHEET Page 006 . Date Prepared: 01/21/98 Date Printed: 02/14/98 MSDS No: 505.0163802-011.001 AF PLUS 30 Container/Mode: CASES/SURFACE . NO EXEMPTIONS .NOS Component: None RQ (Reportable Quantîty) - 49 CFR 172.101 Not applicable 15. REGULATORY INFORMATION us Federal Regulations TSCA (Toxic Substances Control Act) status TSCA (UNITED STATES) The intentional in¡redients of this product are listed. CERCLA RQ - 40 CFR 302.4 None SARA 302 Components - 40 CFR 355 Appendix A None Section 311/312 Hazard Class - 40 CPR 370.2 Immediate(X) Delayed(X) Fire() Reactive() Sudden Release of' Pressure( ) SARA 313 Components - 40 CFR 372.65 Section 313 Component(s) CAS Number Max % --_..._-~-_._--_..._--...._----------_.. -....--..---- ....-- ZINC C¡-C14 ALKYLDITHIOPHOSPHATE 68649-42-3 1.38 International Regulations Inventory Status No~ de~ermined State and Local Regulations California ProÞosition 65 None 16. OTHER INFORMATION The informa~ion accumulated herein is believed to be accurate bu~ is not warranted to be whether originating with tbe company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. Last Pale