Loading...
HomeMy WebLinkAboutBUSINESS PLAN 2/1992 ~"":,~\5-::'~~.. . f"'/ (!{~ . H}I\IP SiT EDIAGRAM 0 P L ~\~~ l\1~\P FalllTY ·orA'GRAM @ 3'...:. . ::.~ss ~{ame: Motor City GMCjBUICK ~9 Union Avenue, Bakersfield, Ca. 93307 /'\ / \ A:':!a ~a;: ;r 1 0: 2 ~rame 0:: A:':!a: Buick Shop & Sales Area -_- Nc:-~~ ~ (\-;:J. ~-)(.- 7-V - V 5ítee~ t ~ () ~ ") ~ \1.\ t/oo 6-4-t,.. µÞr$7ß OIl- ftBDJE ~O )IJ~ íA1JIC @ ()f~'G$- V\ ~ ~ ï DFf--1 cê- ~i-'ff)G$ c;VS7"OM .£ ÑOP P-~JNT ß001'1+ ~ ~ CJ w ;l S N ~ or:F,c.ES e>~PI(;($S £ 5 f.fo\)JÍÙ>ÐM <r rt> u pi.} ~ÐtJ fW/Þ " ~.,;;::. ~ -i~ - 06/12/92 - .,~-.j (J ~ Wi;rl4f- 10 ~- Q~ étJJv Page 1 LYDES CUSTOM SHOPPE 215-000-000680 00verall Site with 1 Fac. Unit _~ General Information Location: 149 UNION AV Community: BAKERSFIELD STATION 06 Map: ,103 Hazard: Moderate Grid: 32C- FlU: 1 AOV: 0.0 Contact Name CLYDE CRAWFORD PAT CRAWFORD Title Business Phone (805) 323-0005 x (805) 327-7171 x 24-Hour Phone (805) 831-3821 (805) 831-3821 OWNER SPOUSE Administrative Data Mail Addrs: 149 UNION AV City: BAKERSFIELD Comm Code: 215-006 BAKERSFIELD STATION-06 D&B Number: State: CA Zip: 93307- SIC Code: Owner: CLYDE C. CRAWFORD Address: 3813 LILLIAN WAY City: BAKERSFIELD Phone: (805) 323-0005 State: CA Zip: 93309- Summary /1 /1\DOJ ~~V'@~lf OO~ ~~t ij \h~@ Ûö C/~~.pA ~/'Aw¡...."r~ yp0 Of ilrliï:Horo) . ~1fi1®-- . h ~6\f'lh®d hazardouS mlãl~~i'B$i~ marJ~ rsvI®w®d tG;t2ì @!~~(9.\~ \ -. /1/ (j cld!..~.{o/"In©r~~a~ öt ~~@rJ~ wö~frø m~V\)~ ~~@\n i@(j'~u f"1~90IB~~n) taJOlf oovrrOOi@iî$ oo~~iji~® ~ ©©mpi~~~ ~1J'b©1 OOIT@~ m~rrt- ®@®m®utì Lº>~M ~(Q)1i' Mlf ~~©n~. ì í!f ¡/ ~¡i -~;"~~2- / i ~Ù~i' ~, " ¡, ~ 06/12/92 -- -- CLYDES CUSTOM SHOPPE 215-000-000680 02 - Fixed Containers on Site Page 2 Hazmat Inventory Detail in Reference Number Order , Liquid ~ Moderate GAL 7 S- 02-001 ENAMEL ~ Fire, Immed Hlth, Delay Hlth CAS #: Trade Secret: No Form: Liquid METAL Conc· 40.0% 10.0% 5.0% 5.0% 5.0% Type: Mixture Days: 365 Use: PAINTING DailYMa~ I Daily AVerag~ --y-- ~. ~ Storag 1..-- Press Temp , L CONTAINR-NONDRUM AmbientTAmbien~SHOP Annual7~~ Location Components MCP List Moderate Moderate Moderate Moderate Moderate Xylene, Mixed Toluene n-Butyl Acetate Naphtha Waßte Acids 02-002 THINNER ~ Fire, Immed Hlth, Delay Hlth Liquid 1~ .·U.i.gtf-- GAL 10 CAS #: Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: PAINTING ---- Daily Max GAL ~ Daily Average GAL --r-- lE... I --'uu I Storage ~ Press T Temp ~ ,}/1-- METAL ~ONTAINR-~Ambient Ambient SHOP Conc 30.0% 20.0% 10.0% 10.0% 5.0% 5.0% Annual Amount GAL -- ~6~~ DO Location Components MCP List Moderate Low Moderate Moderate Moderate . High Acetone Trichloroethylene n-Propanol n-Butyl Aceta.te Xylene, Mixed Methanol rl ~ - - 06/12/92 CLYDES CUSTOM SHOPPE 215-000-0006&0 00 - Overall Site Page 3 <D> Notif./Evacuation/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation VERBALLY NOTIFY CUSTOMERS AND EMPLOYEES Oij THE PA SYSTEM. CALL 911 HAVE ALL PEOPLE ASSEMBLE IN THE SOUTH CUSTOMER PARKING AREA. <3> Public Notif./Evacuation NONE LISTED <4> Emergency Medical Plan MERCY HOSPITAL - 2215 TRUXTUN AVENUE - 327-3371 BAKERSFIELD FAMILY MEDICAL CENTER - 4580 CALIFORNIA AVE - 327-4411 '" , ~ e - I. 06/12/92 CLYDES CUSTOM SHOPPE 215-000-000680 00 - Overall Site Page 4 <E> Mitigation/Prevent/Abatemt <1> Release Prevention PROPER CONTAINERS, VALVES AND PROPER HANDLING AND STORAGE OF HAZARDOUS MATERIAL. NO SMOKING SIGNS POSTED IN APPROPRIATE AREAS. REFER TO MSDS SHEETS FOR CLEANUP AND MEDICAL ATTENTION. CALL OUTSIDE HELP ON SERIOUS PROBLEMS. <2> Release Containment ()Se.- t?ðlJé/~I3~A/ '#/&lel'/4/ ~ {J/~--r:: 4;4/ 0 t!(~4Y tI¡o SrI/I. ßspP5~ (pi fiLl! //S T f I // I" /r ¡pe-r JAJ> {' V~;t!;:uv5.. <3> Clean Up I J /J /JJ / ( -I- L LJ (!! /oe ,/J;A.nJ If 'S ~,' 1/' (/$ e f7q So r fJ e.AJ I' If t tZ rI ;n- 1&/ P,' 'C. rlfl/ to I tJ;>ftP6~( pi /l1l1-t #5 ~e.r ]/lXfv¿)¿.ípAl5 <4> Other Resource Activation ~ ~, I e e 06/12/92 CLYDES CUSTOM SHOPPE 215-000-000680 00 - Overall Site Page 5 <F> Site Emergency Factors <1> Special Hazards <2> Utility Shut-Offs A) GAS - NORTHWEST OUTSIDE WALL OF CLYDES CUSTOM B) ELECTRICAL - WEST WALL INSIDE UTILITY ROOM NEXT TO MEN'S RESTROOM ACROSS FROM OFFICE C) WATER - APPROXIMATELY 100 FT SOUTH 7TH AND 2ND STREET INTERSECTION ON SIDE OF FENCE D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINQUISHERS LOCATED THROUGHOUT THE BUILDING WITH APPROPRIATE MARKINGS FIRE HYDRANT - LOCATED AT THE. NORTHEAST CORNER OF 2ND STREET AND V STREET. <4> Building Occupancy Level . I -;-------..., ~-". ã- "....~. ~ : ~\ '~ :. .. e . 06/12/92 CLYDES CUSTOM SHOPPE 215-000-000680 00 - Overall Site Page 6 <G> Training <1> Page 1 WE HAVE ?? EMPLOYEES AT THIS FACILITY ¡Joo~ DO YOU HAVE MATERIAL SAFETY DATA SHEETS ON FILE? i{e$ BRIEF SUMMARY OF TRAINING: fJo £MPl-Dl{éS <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use Õó' ¡ -If")) ~ . ';~ ~/ - BAKERSFIELD CITY FIRE DEPARrI-r R E C E I 2130 "G" STREET V E D BAKERSF IELD. CA 93301 tV 0 CT 2 2 1987 (805) 326-3979 103-3;;) '--- t:\ Ans'd. \fv ~ ¡\)E>P \0 ....... .. .. .:L , --. OFFICIAL USE ONLY ID# _~~ :<.! 6_ 1)()()6 ~() 1Þj~3 \FØ2 Gr':L~ USINESS NAME HAZARDOUS Mh'1:~RI ALS BUSINESS PLAN ~3 A WHOLE FORM :8./:.. INSTRUCTIONS: 1. To avoid further action. return this fo~m by 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: Clyde's Custom Shoooe B. LOCATION I STREET ADDRESS: 149 Un ion Ave CITY: Pakersfield ZIP: Ca BUS,PHONE: (805 )323-000C:; SECTION 2: EMERGEN~! ~OTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material. call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. E~PLOYEES TO NOTIFY IN CASE OF E~ERGENCY: ~AME AND TITLE A. Clyde Crawford Owner DURING BUS. HRS. Ph# 805-323-000C:; AFTER BGS, HRS. Ph;: ROC:;-R~l-~A?l B, Pat Crawford Soouse Ph# 805-327-7171 Ph~ 805-831-3821 SECTION~: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. GAS/PROPANE: \Iorthwest outside wall of Clydes Cl1srom (P;:¡rr of' C;hnp ¡:-;lda) B, ELECTRICAL: West wall inside utility roon next to Men's restroom across off C, WATER: a9prnx 100 feet soutr 7 & 2nd st i ntersert i on on strip of' Fpnrp. D. SPECIAL: . . E. LOCK BOX: YE~(~.. IF YES, LOCAT!ON: IF YES, DOES IT CONTAr~ SITE PLANS? YES / ~O FLOOR PLANS? YES / ~O ~SDSS? YES ! NO KEYS? YES / NO - 2A - I , j. e e .. ¡.- " SECTION 4: PRIVATE RESPONSE TE~~ FOR BUSINESS AS A WHOLE Clyde Crawford, Tony Richardson The above individuals are responsibe to call in help from outside agency and to contain spillS and administer first aid. Stop spill at source, dike area of spill to prevent spreading. 'Pump liquid to salvage tank. Use vermiculite, floor absorbent or other absorbent material to absorb liquid. Dispose of 1n accordance to Regulations. SECTION 5: LOCAL EMERGENCY ~EDICAL kSSIST~~CE FOR YOUR BUSINESS AS A WHOLE Mercy Hospital - 2215 Truxtun Ave. Bakersfield, Family Medical Center 327-3371 4580 Calif Ave. 327-4411 SECTION 6: EMPLOYEE TRAINING E~PLOYERS ARE REQUIRED TO HAVE A PROGRA~ WHICH PROVIDES E~PLOYEES WITH I~ITIAL ~~~ REFRESHER TRAINING IN THE FOLLOWING AREAS. CIRCLE YES OR NO INITIAL A. XETHODS FOR SAFE HANDLING OF HAZARDOUS MATERIALS: . . . . . . . , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . (ÝES__ 'NO B. PROCEDURES FOR COORDINATING ACTIVITIES -_.. WITH RESPONSE AGENCIES:... .. ....... ... .......... .~)NO C. PROPER USE OF SAFETY EQUIPME~l:........,........ .~-E NO D. E~ERGENCYEVACUATION PROCEDGRES:..,.............. - NO E. DO YOU ~INTAIN E~PLOYEE TRAINING RECORDS:....... YES NO REFRESHER YES NO YES NO YES NO YES NO YES NO SECTION 7: RAZARDOUS MATERIAL CIRCLE YES OR NO DOES YOUR BUSINESS HANDLE HAZARDOUS MATERIAL IN QUANTITIES LESS THAN 300 POL~DS OF A SOLID. 55 GALLONS OF A LIQUID. OR 200 CUBIC FEET OF A COMPRESSED GAS:. .,... YES NO I. Clyde C. Crawford , cer'tify that the above information is accurate.. I unde~stand that this information will be used to fulfill my firm's obligations under the new California Health and Safety code on Hazardous Materials (Div, 20 Chapter 6,95 Sec. 25500 Et AI,) and that inaccurate information constitutes perjury. ø' /. // 4;r~ SIGNATURE tV 1" ¿'/ ,-, ¿;;ú . TITLE /Î væJv'e ,/ ·'7 // ff: '/ DATE /6' -/0.':"'- / - 28 - - e .- ~ ., BAKERSFIELD CITY FIRE DEPART~EXT 2130 "G" STREET BAKERSFIELD, CA 93301 OFFICIAL CSE ONLY ID# - - -' - - - BUS INESS NMIE: BUSINESS PLAN SINGLE FACILITY UNIT FORM 3A INSTRUCTIONS 1. To avoid furt11L é!.ction, this form must be returned by: 2. TYPE/PRINT YOUR ANSWERS IN ENGLISH. 3. Answer the question3 below for THE FACILITY UNIT LISTED BELOW . 4. Be as BRIEF and CONCISE as possible. FACILITY trnIT~ 1 ._ FACILITY UNIT NA.'fE:Clyde's Custom Shoppp SECTION 1: MITIGATION. PREVENTION, ABATEMENT PROCEDu~ES ~-. - -- --- ----_._---~-~- Proper containers, valves and proper handling and storage of hazardous material. No smoking signs posted in appropriate areas. Refer to MSDS sheets for cleanup and medical attention. Call outside help on serious problems. SECTION 2: NOTIFICATION ~\~ EVACGATIO~ PROCED~~ES AT THIS L~IT O~LY Verbally notify customers and employees on the PA System. Call 911. Have, all people assemble in the South Customer Parking Area. .. 1.4 - c ' e e '!!/' 0. SECTU).I," 3: H,-\Z.-\RDot;s ~r.-\TER(A[.S fOR THIS r;~rr O\'LY :\, Does th[s f,lC[lLty l'nLt C::H~:-:,~~~~ fi,':H"dlJl.:S .'·(,1:e:-i,1:"'..""" @, \0 If V::S. see B. If SO. continue with S~CTiC\' 4. 8, Are an),' of th~ hazardous materials a bona fid~ Tt'~de Secret YES ® If No, complete a separate hazardous materials inventory form marked: XOS-TRADE SECRETS OXLY (whi:e f0r~ =~A-l) If Yes. complete a hazardQus ~aterials inve~tory form mar~ed: TRADE SECRETS O.\'LY (~!ellow for::! =·L~-2) in ,)l!d[tion r:o the non-trade sec.et form. tist o~l~ t~e tr~ct~ sec"e:s on form 4A-2, SECTro~ 4: PRIVATE FIRS PROTECTrO~ Fire Hydrant. located at the Northeast comer of 2nd Street and V Street. Fire Extlnquishers located t~roughout. the building with appropriate markings. I--~·~~·_·- _. SECTIO~ 5: LOCATION OP WATER SGPPtY FOR ÜS~ BY EXERGE~CY RESPO~ERS Fire Hydrant located at the !fortheast corner of 2nd Street and V Street. . 0,#' SECTro~ 6: LOCATrO~ OF LïrrtrTY SRt7-0FFS AT THIS ~rT O~LY. Å. SAT. GAS~PROPANE~ Gas turnoff located at the Northwest outside wall of Clydes Custom Shop. (Part of shop building) a.ELECTRIC'At: West wall inside utility room next to Men's Restroom across from Suzuki General Office. C. WATER: Approximately 100 feet øath on the V Street and' 2nd street intersection on the street side of the fence. Q. SPECrAL: ~@@~ O~nG'lMj1L . r'\(:" 3~v. ···-::5~. - ~·=:S , :~C,U!OS: _. _\J~^, .1.'\. __ ~ ':::5 "/"1 "j ·.r~c<;s'" ::::''-5'" -::::) ,.,., .,) '- ':':::5, 5 rT:::: ?!:.,..\):5'" :"~COR ?':...\;;S'" '/::5 ::0 ','::5 \",..., .lj ..., . .J (, 1. D. t M M M M M M M M M M M M EMERqENCY' p~'IrC-"I r M. (Jdd I Þ 95-.JtJ9L/3ý 1 2 MAX AMOUNT 3 3 12 6 21'S 3 24 2 20 4 4 10 20 20 3 ANNUAL AMOUNT 48 48 144 72 96 12 96 6 220 48 48 60 200 200 UNIT Gal Gal Gal Gal Gal Gal Gal Gal Gal Gal Gal Gal Gal Gal 4 5 CONT CODE 13 (¡1 g () Page --L- ot c ~ 1 OFFICIAL USE CFIRS CODE ONLY 6 USE CODE 29 7 T. 0 CAT ION FACILITY 'Shop 8 % BY WT. 9 10 HAZARD D.O.T CODE GUIDE 13 13 13 13 13 13 13 10 10 10 13 13 13 IN THIS UNIT CHEMI AL 111S Pa1nt ux Leaded) 11 is Paint 1100 Series Hy-Lux Non Lead rylon Interior/exterior enamel terns 1501 thru 2505 ry10n Chrome Aluminum Spray aint Item 1404 Acrylic Enamel ~-C Primer Enamel Tntermix FLLQ 29 Shop FLLQ 29 FLLQ Shop FLLQ 29 Shop FLLQ 29 Shop FL 29 Shop III -Lit> Illo - 11) 1\ 'b- '5 \ 'J.o3 ~ 1- O¡\- ~ ORMA FL Keik-Slik Primer a easure Up Spray Cleaner 29 Shop 08 Shop 32 Shop FL FLLQ 08 Shop .A.F. Troubleshooter P-33 FLLQ 08 Shop 29 Shop 29 Shop Liquid Rubbing Compound ORMA erryman Blend 5ASolvent Blend ORMA FLL Acrylic Enamel 417-XX FLLQ 29 Shop Enamel 419-XX 60 08 iDhop . ___1.-. d~~& 1'!. 'f!.F.: ". :f:ØIYEtC SIGNATURE: r:(?d£ {! LJ.K~~Æa:....-TITI.E: 4JuJAlÆ.£. CONTACT: dr / (?;¿:uu-::.j/2.~ TITLE: ¡þCtJ;tJ~ vL nus INESS ACTIVITY :-D¿~7/> 'L- d~tÿP- . Brand Super Duty Rubbing - 95 FLLQ ~ DATE :..4.~Jý /~,/~i7 PHONE 11 Btfs HOURS: ""¡I$'- JÉ-:-¡/tJ~~.-!- I AFTER BUS HRS: B..$'·-LJI-Jfè L- PHONE' BUS HOURS :-.fPS"-J~.J -tPoo$"' AFTER BUS HRS: iJL,?~::-.J22-/ - 41\-1 - ·. ~~--"1- r1 ( '. ), )) (, 1\^ln:nr.Flr.I.1I CITY VIRP. )P.P^RTMP.NT (. . (t'// .. I.n. f _q?~tJ2Y397 portM 4^·1 NON-TRAOE SRCRRTS nn~c80 JI^ZARDOUS MATERt ^J-ÞS 1 NVEN~V IìIJSlNESS N^ME:£ßL~~ L~.s}~~wJh1//L OWNER N^MF.: e/4-'d¿:- ¿ ¿'¿¿¿Ð-;4~d F^CILITY UNIT ':-1r._____ ^OnqESS: /~/9 ¿//V/~4I ,-tjCJ¡;~ 7: ADDRESS: ..5,/.37/'///-IA/ ..d~... FACILITY UNIT NAMF.:Shoº-- CTri. ZIP:~Li,.t'é/¿~.-/,t./á {r! ý..;5..$tJ7 CITY.ZIP:~4£~.R.s.,0.../d. /7~ ~.Jf¿9 - ______h_ P¡¡ON1E t: j"ÔS-...:32...3-¿JtJds- PHONE': /~.$--J-~/- A./~~ (OFFICIAl. USE CFIRS conE i ONLY 1 2 3 4 5 Ô 7 8 9 10 TYPE MAX ANNUAL CONT USF. I.OCATTON IN THIS % ny "Al^RO 0.0. T CODE AMOUNT AMOUNT UNIT CODE CODE FACILITY UNIT WT. CHEMICAL OR COMMON NAME CODE GUIDE, M I· 10 60 Gal 13 29 ShOP,) \.l/r- Grow GP Bligh Efflclency ThlnneI . ~ ,ill 0111 1590 Slow FLLQ M ' I 10 60 Gal 13 29 Shop Jf \/ if/" \ Brow GP High Efficiency Thinner r'\' 1516 Medium FLLQ M I ~O 200 Gal 13 29 Shop _ /I¥- ./Grow GP Efficiency Thinner A~UV ~ 1542 Fast to Medium FLLQ M I 5 20 Gal 13 29 Shop )U"")""(Y L',II\I~ -J Grow GP High EfficiencY(Thinner ~ ("fdJM V~ p ¿ 1556 Fast R€ðu.c..e¡q,} FLLQ M I 5 20 Gal 13 29 Shop /' \ Grow GP High Efficiency Peducer 1411 Slow FLLQ M I· 5 20 Gal 13 29 Shop 10010- õt:> Grow GP High Efficiency Reducer I\?,o - õ2.1) ... 1409 Medium FLLQ M I 5 20 Gal 13 29 Shop .;1L/I:>$.CH - IU I Grow GP High Eff iciency Reducer , Ilb'b - It) 1407 Fast to Medium FLLQ M I 5 20 Gal 13 29 Shop 1\\C6 - ~ I, Grow GP High Efficiency Reducer \\45' '0 l~oC; Fö=lSt- FLLO M I· 5 20 if Gal 13 29 Shop \.. ' PPG Ind. Acrylic Enamel Reducer _ . -' we FLLO M I 5 20 I Gal 13 29 Shop PPG Ind. Satin Primer _ _ DPE 1338 FLLQ M I 5 20 Gal 13 29 Shop PPG Ind. Duracryl Acrylic Lacq\ ler DDL FLLQ M I 5 20 Gal 13 29 Shop PPG Ind. Air Dry Enamel DAR 9000 FLLQ M I 5 20 Gal 13 29 Shop PPG Ind Delstar Acrylic Enamel SAR FLLQ M I 5 I 20 Gal 13 29 Shop PPG Ind. Delthane Ultra DXR 8 0 FLLQ M I 5 20 Gal 13 29 Shop PPG Ind. Delstar Reducer .--- DTR 602 ~./ / FLLQ NAMt;:I.:-"'77/é..l"d¿- C é/(:!/l-a./7;}/¿d... TITLE: /!â//y¿.,¿ SIGNATURE: /''/_Æ (7. (_40.~-..,..Å. DATE:A,It-('y/I',lfJ7 EMF¡RIG.ENCN" CONTACT: -L:L:;rd£ è!7/Ae()ï1~~r' I TJ.E: /O//JAlÆ£.. /' pnONE I: B~S "OURS: r,15- ~,.j-¿c~.:/- ___ EH~~II{ìfr.~NeY' r.ON~A~T·:.¡J!-t:.-'~::/t ¡JJ.fl!~-;-;1;.!l¡¿i~~..f)~ITLE: tfaJ~¿ vL PHO:~T:R B~~S H~~~~ :1{;~-1-~f~~~--- PR ...~C r PAL nus j NESS ft" :'.' .' (: __ ~"~·,$,:.:.<,,-/_.:,,:-.::~x';'~.I<':~?::'.k:,._ AFTER BUS "RS: f!.l;.~.~.!1ft-:_:;iff~ / ,. " r. " 2 I, , < 2 ._. - -.. """"TC,-''''':';'''' ,:,' , ;':',~!.'~' . ': -....": ,>.~ "~ .~~~ ::.:-,~".,~.~-~ DATE OF,PREP. " <~ """~,' ,"F"~'''~ ~~.~-...-..._. :~~-'~"'I''' ....~""'~..-.-:...~..._~,; .-'" ';or ·'''~:f.~'''''f;:l·'--;-;:'''!:''~iq,~:~·'''''';;'','1t-r&,~~ì$,"'';!,,·t~~~~~~~~~I " Mal;RIAL S4FEJV DAtKH'E'8":':'3?F> :"".' . ,NPCA.1.-!,~: .,-- - '\ "I FOR COATINGS, RESINS AND RELATE ERIALS '>:'~'~::""',;.,',.,I 7 / 2/ 85 I' IApproved by U,8. Depertment 01 L.bor"E..entlally Similar" to Form OSHA·20) T ',\ .' S ectlonl ). ,: " , . " MANUFACTURER'S NAME GROW GROUPJ INC.' STREET ADDRES~ 3155 WEST BIG BEAVER ROAD CITY.8TATE~ANDZIPCODE ~-~M'ERGENCYTELEP~U 1& #200 , (313)' ·643-4600 , TROY fhCHIGAN 48084' " -- PRODUCT CLASS MANUFACTURERS CODE IDENTIFICATION .' Paint Related Material TRADE NAME NA-1263 '-- High Efficiency Reducer #1411, Slow Section II - HAZARDOUS INGREDIENTS , INGREDIENT CAS REG. NO. PERCENT TLV lEl , VAPOR PRESSURE . PPM maIM' "; .". G5-295 VM&P Naphtha 64742-49-0 40 -50 300 1% Acetone 67-64-1 20-30 750 , , Toluol 108-88-3 10-20 100 , , Butyl Cellosolve Acetate 112-07-2 5-15 25 Oi Bas icEs ters 1119-40-0 1- 5 50 , , , ' -¡-~F ' \ " - 5Ô'~ 7~~ "g '. @ ~8 Fe.; ".' , , " .. ~, ., " Section III - PHYSICAL DATA . BOILING RANGE 142 _ 384°F VAPOR DENSITY [ill HEAVIER 0 LIGHTER. THAN AIR EVAPORATION RATE D FASTER ~,SlOWER. THAN ETHER , PERCENT VOLATILE BY VOLUME 100% WEIGHT PER GALLON 6 . 713 Section IV - FIRE AND EXPLOSION HAZARD DATA " DOT CATEGORY Flammable Liquid FLASH POINT SOF 1.C.C. ' lEl 1.0% EXTINGUISHING MEDIA Carbon dioxide and/or chemical foam t:,'pe extinguishers. ~- ,. " UNUSUAL FIRE ANa EXPLOSION HAZARDS , Handle as extrel,nely flammable material. Vapors may spread. Prevent buildup oJ vapors. Extinguish all 'pilot lights and turn off heaters, non-explosion proof electrical equiDment' and other sources of ignition during use or until all vapors are gone. ,SPECIAL FIRE FIGHTING PROCEDURES , Use NIOSH appròved self contained breathing apparatus. Cool exposed containers with water~ ~', 'ò, i I ,,,-...,,; ..._.;. . ,4j .-"!' ..... cUon V - -H EÄLTfi ftAZARD. }~';:'{~~~"- ':;¡'f'Pf:_'r.'!.'~;',/oIjJ~"T!:·::>r1rt'::;--' , . THRESHOLD liMIT VALUE EFFECTS OF OVEREXPOSURE 25 ppm Severe eye irritation, drying of skin leading to dermatitis.' Excessive inhalation causes, headache, diz~iness, nausea to unconsciousness. ~0 EMERGENCY AND FIRST Ala PÀOCEDURES Eye con tac t: Skin contact: Inhalation: I Ingestion: Flush with water. Wash with mild soap and water and apply skin cream. Renmve to fresh air and call a physician; apply artificial respiration if necessary. 00 not induce vomiting; contact a physician. Section VI - REACTIVITY DATA STABILITY D UNSTAaLE IIXJ 8TABLE CONOITIONSTOAVOID Heat, sparks and f1 ames. INCOMPATABILlTYIM.fer'./atuvo/d) Strong oxidizing agents. HAZARDOUS OECOMPOSITION PRODUCTS Thermal decompösition may yield carbon monoxide. HAZARDOUS POLYMERIZATION D MAY OCCUR [XX) WilL NOT OCCUR CONDITIONS TO AVOIO Section VII - SPill OR lEAK PROCEDURES STEPSTOBETAKENINCASEMATERIAlISRElEASEDORSPlllED Flus with water into retaining area or container. If spi II is lar~e, dike area. Evacuate area. Use proper respiratory protection; avoid breat,l1ing , vap'ors. AVOl d ex~osure to sparks, fi re or hot metal surfaces. Remove with inert absorbe"!t I WA~~~D~~Bš~~Jl~bBg kR~1ßérate under safe conditions or dispose of in accordance with local,' , state and federal regulations. Section VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION Self contained breathing apparatus for concentrations above TLV limits~ VENTILATION Use either local exhaust or mechanical to meet TLV requirements. Ventilation must, be sufficien to limit employee exp~sure at, or below, OSHA TLV limit. ..'" PROTECTIVE GLOVES Neoprene or equivalent, EYE PROTECTION Safety glasses or goggles. OTUERPROTECTlVEEOUIPMENT Eye bath and safety shower. Section IX - SPECIAL PRECAUTIONS .PRECAUT~ONS TO 8E TAKEN IN HANDLINe) AND STORING Keep away froll! heat, sparks, open f1 ame. Use with adeqlta te ventllation. Do not breathe vapors, do not get in eyes, on skin or clothing. Accidental·.·.' contact should be washed away inmediate1y. OTHER PRECAUTIONS .... Never use cutting or welding torch on or near containers, even empty, as produc~ or residue may ignite. .... " ...:::_i_:::-~.:.::.:~::::.:.........:-:._.....__._._. :.._-"--".. .---..----.---.'.-..-- ....-..--..--.-----.-.--..-,. ----,..-..-...,-.;~-~._~~.- -. I'·;~.·· " . . '. '. .. :';" I.itiIJ£ MATERIAL SAFETY DATA SHEET I 'r" " COATINGS "AND RESINS GROUP MANUFACTURER'S NAME: PPG INDUSTRIES INC. PRODUCT SAFETY LOC.: 260 KAPPA DRIVE PITTSBURGH. PA 15238 MSDS CONTACT: MANAGER. INDUSTRIAL HYGIENE AND PRODUCT SAFETY (~j^) 963-5822 EMERGENCY TELEPHONE: (304) 843-1300 SECTION II -INGREDIENTS SECTION I - PRODUCT INFORMATION CODE/IDENTITY : DTR600 (030684D) TRADE NAME: ÁCRYLlC ENAMEL REDUCER (FAST) CHEMICAL FAMILY: SOlVENT BLEND DOT CLS : FLAMMABLE LIQUID N.O.S. DATE OF PREPARATION: 6/09/86 CUSTOMER PART #: ' INGREDIENTS APPAOX. % WT. CAS NO. E X P 0 S·U R ELI M ITS ACGIH TLV OSHA PEL PPG IPEL ACETONE VM&P NAPHTHA ALIPHATIC HYDROCARBON N-BUTYL ACETATE 2-BUTOXY ETHYL ACETATE 35 67-64-1 2564742-"89-8 25 64742-89'-8 10 123-86-4 5 112-' 7-2 750.00PPM 300.00PPM NOT EST. 150.00PPM NOT EST. 1000.00PPM 50'.00 PPM NOT EST. 150.0'PPM NOT EST. 750.øøPPM 3U. ø'PPM NOT EST. 15'..0PPM NOT EST. .~ ...-', ,~ . BOILING RANGE: 56 - 192DEG.C VAPOR PRESSURE: 137.9 mmHg VAPOR DENSITY : HEAVIER THAN AIR I VOL/VOLUME : 100.0 EVAP RATE(BuOAc=lOO): 853 SECTION IV - FIRE AND EXPLOSION HAZARD DATA DOT CATEGORY: EXTREMELY FLAMMABLE FLASHPOINT: 10 DEG. F PMCC SECTION iil- PHYSICAL/CHEMICAL CHARACTERISTICS SOLUBILITY IN WATER: 35.2 % NT/GAL (LBS): 6.22 pH : U II J SOLID BY WEIGHT: .0 FLAMMABLE LIMITS: LEL 1.4 UEL UII EXTINGUISHING MEDIA: USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) CLASS B EXTINGUISHERS (CARBON DIOXIDE. DRY CHEMICAL. OR UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA CLASS IB FLAMMABLE LIQUID FIRES. " UNUSUAL FIRE AND EXPLOSION HAZARDS: , KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT. ELECTRICAL EQUIPMENT. SPARKS, AND OPEN FLAMES. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NOT APPLY ON HOT SURF ACES. TOXIC GASES MAY FORM WHEN PRODUCT IS CONTACTED BY FLAME OR HOT SURF ACES. SPECIAL FIRE FIGHTING PROCEDURES: ' WATER SPRAY MAYBE INEFFECTIVE. WATER SPRA Y MAY BE USED TO COOL CLOSEO CONTAINERS TO PREVENT PRESSURE BUIlD-UP AND POSSIBLE AUTO IGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED. FOG NOZZLES ARE PREFERABLE. FIRË2'FIGHTERS SHOULD WEAR SELF CONTAINEO BREATHING APPARATUS. SECTION V - REACTIVITY DATA STABILITY: STABLE HAZARDOUS POLYMERIZATION: NOT EXPECTED TO OCCUR INCOMPATIBILITY (MATERIALS AND CONDITIONS TO AVOID): AVOIO CONTACT WITH STRONG ALKALIES. STRONG MINERAL ACIDS. OR STRONG OXIDIZING AGENTS. HAZARDOUS DECOMPOSITION PRODUCTS: MAY PRODUCE HAZARDOUS OECOMPOSITION PRODUCTS WHEN HEATED. INCLUDING: Carbon Monoxide. SECTION VI" - SPILL OR LEAK PROCEDURES ,""-- STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL EQUIPPED WITH PROPER RESPIRATORY AND SKIN AND I Continued on Back of Page , j --'--~-~-"-'._'--'--"--'-_._--'-'~--'-'------------ .-"------..-'<r-..-_..~_ n. _".~_____.__._ _,__._....___.........-..~_ ."; ,.'t."""":' -?l~,~~~f¡~~;',. . I .~.... J- r ,J- -r--~-~ Continuation of Manufacturer's Code - DTR600 e " ¡; DATE OF PR' ":.;, ~""""",.,.~.,.,"" "''''"''''''..,.."...'~',.,...,',~'!': . "PI ; f";':"/-'Ç~';~{'~;'~i"';¡"t~)'~'i:'<,!)'fi" . 6/09/86 EYE PROTECTION SHOULO BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP SPILLED MATERIAL WITHSAWDUST, VERMICULITE. OR OTHER ABSORBENT MATERIAL AND PLACE INTO CONTAINERS FOR DISPOSAL . WASTE DISPOSAL METHOD: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL ENVIRONMENT AL'CONTROL REGULATIONS. EMPTY CONTAINERS SHOULD BE RECYCLEO OR OISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT FACILTY. SECTION VII - HEALTH HAZARD DATA EFFECTS OF OVEREXPOSURE FROM: INGESTION: HARMFUL OR FATAL IF SWALLOWED. EYE CONTACT: CAUSES SEVERE EYE IRRITATION. SKIN CONTACT: MAY CAUSE MODERATE SKIN IRRITATION. MAY BE ABSORBEO THROUGH THE SKIN. INHALATION: VAPOR AND SPRAY MIST MAY BE HARMFUL IF INHALEO. REPEATED EXPOSURE TO HIGH VAPOR CONCENTRATIONS MAY CAUSE IRRITATION OF THE RESPIRATORY SYSTEM AND PERMANENT BRAIN AND NERVOUS SYSTEM OAMAGE. INTENTIONAL MISUSE BY DELlBERA TEL Y CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL· OR FATAL. CHRONIC OVEREXPOSURE: AVOID LONG-TERM AND REPEATED CONTACT. SIGNS AND SYMPTONS OF OVEREXPOSURE: EYE WATERING, HEADACHES, NAUSEA, DIZZINESS; AND LOSS OF COOROINATIONARE INDICATIONS,THAT, SOL VENT LEVELS ARE TOO HIGH. REDNESS, ITCHING, BURNING SENSATIONS AND VISUAL DISTURBANCES MAY BE INDICATIONS THAT EXCESSIVE EYE CONTACT HAS OCCURED. DRYNESS, ITCHING, CRACKING, BURNING, REDNESS, AND SWELLING ARE CONDITIONS ASSOCIATED WITH EXCESSIVE SKIN CONTACT. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NOT APPLICABLE SECTION VIII - FIRST AID PROCEDURES .,..~ INGESTION: IF SWALLOWED, 00 NOT INDUCE VOMITING. EYE CONTACT: IN CASE OF EYE CONTACT, FLUSH EYES IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN CONTACT: IN CASE OF SKIN CONTACT, FLUSH IMMEOIATEL Y WITH PLENTY OF WATER FOLLOWED BY WASHING WITH SOAP AND WATER. .. INHALATION: IF'AFFECTED BY INHALATION OF VAPOR OR SPRAY MIST, REMOVE TO FRESH AIR. . APPL Y ARTIFICIAL RESPIRATION AND OTHER SUPPORTIVE MEASURES AS REOUIREO. . OTHER: IF ANY OF THE FOLLOWING OCCUR DURING OR FOLLOWING USE OF THIS PRODUCT . CONTACT A POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN IMMEDIATELY; HAVE MATERIAL SAFETY DATA SHEET INFORMATION AVAILABLE. 'INGESTION 'EXCESSIVE EXPOSURE TO A CORROSIVE MATERIAL. . PERSISTENT SKIN/EYE IRRITATION OR BREATHING DIFFICULTIES. SECTION IX - PROTECTION INFORMATION PERSONAL PROTECTIVE EQUIPMENT FOR: EYE PROTECTI ON: WEAR CHEMICAL-TYPE SPLASH GOGGLES OR FULL FACE SHIELD. SKIN PROTECTION: WEAR PROTECTIVE CLOTHING, INCLUOING IMPERMEABLE APRON AND GLOVES CONSTRUCTED OF: POLYVINYL ALCOHOL, NEOPRENE RUBBER, NITRILE RUBBER OR LATEX RUBBER RESPIRATORY PROTECTION: ' (r Continued on Page 2 .......... +---''''---~'-~----~-''~----:-'-'~'-'._--'''''-'~---~-",----~'-- . , . ,. . _. ,~, ~t.;"f' TIl ~ "'~~m;~"'""=""''"'-''"'''''''I),¡¡r :"i~;~1:'~~~'''''''>c- , PAGE 2 ".~.., " >;,,~),.~,1"''''''::'~ ".: ';~';~-.-.r.,~~~~.:.;'}}~~:~~~~~::'~';~~:~'Ti~~~~~;~;,::r~'7~ -:, ';,"~' '~~~;;~'~.'~:}~;~::;:~~"~:';':~~.i - I,' ·5;-' -:...~-_.-__·~:T '---~~ <e . "." ',~ ,.. 7, . Continuation of Manufacturer's éode - DTR600 DATE OF PREP: 6/09/86 OVEREXPOSURE TO VAPORS MAY BE PREVENTEO BY ENSURING VENTILATION CONTROLS. VAPOR EXHAUST OR FRESH AIR ENTRY. NIOSH/MSHA-APPROVED (TC-23C- J PAINT SPRAY OR AIR SUPPLIED (TC-19C- J RESPIRATORS MAY ALSO REDUCE EXPOSURE. IN ALL CASES. REAO RESPIRATOR MANUFACTURER'S INSTRUCTIÒNS AND LITERATURE CAREFULLY TO DETERMINE THE TYPE OF AIRBORNE CONTAMINANTS AGAINST WHICH THE RESPIRATOR IS EFFECTIVE ANO HOW IT IS TO BE PRO PERL Y FITTED. OTHER EQUIPMENT: CLEAN OR DISCARD CONT AMINA TEO CLOTHING ANO SHOES. VENTILATION REQUIREMENTS: PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN VOLUME ANO PATTERN TO KEEP THE CONCENTRATION OF INGREDIENTS IN SECTION II BELOW THE LOWEST SUGGESTEO EXPOSURE LIMIT. ANO LEL IN SECTION IV BELOW STATEO LIMIT. SECTION X - SPECIAL PRECAUTIONS HANDLING AND STORAGE PRECAUTIONS: 00 NOT STORE ABOVE 120 DEGREES F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED ANO PROTECTED FOR STORAGE OF NFPA CLASS IB FLAMMABLE LIQUIDS. OTHER PRECAUTrONS: ' IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT COATING SYSTEM. REAO THE MATERIAL SAFETY DATA SHEET( S J FOR THE OTHER COMPONENT OR COMPONENTS BEFORE BLENOING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PARTS. CONTAINERS SHOULD BE GROUNDEO WHEN POURING. A VOIO FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES. ALL CHEMICAL SUBSTANCES IN THISPROOUCT COMPLY WITH ALL APPLICABLE RULES OR ORDERS UNDER THE ENVIRONMENTAL PROTECTIOi~ AGENCY'S TOXIC SUBSTANCE CONTROLACT. THIS MATERIAL SAFETY DATA SHEET HAS BEEN PREPARED IN ACCORDANCE WITH THE OSHA HAZARD COMMUNICATION STANDARD (29CFR1910.1200J ' U/I = UNKNOWN INFORMATION N/ A = NOT APPLICABLE NOT EST. = NOT EST ABLISHED r", ¡ \. LOCATION: ",' '" , , , ~.' I~'" ---~d'-'~~ ~~'. .' l' .___.'__,"~,:", f,ot \;;; .' ----:-·--,----.--r,-=:=.'. - _:~:---~--_._-:-"-~-",_.,..._.",..,",-,, "-- -,' :',., -~-_,__:-._,_.._:__,.=-,-,_,,=_,,~,--,-,c m_,_ - , ,;, _ ",";;,:i"!:,',: ,-.li,t- I ~ . e " , "I, ,¿ '~ " MATERIAL SAFETY DATA SHEET SECTION I PRODUCT NAME OR NUMBER (AS IT APPEARS ON LABEL) HIGH EFFICIENCY THINNER #1516, MEDIUM MANUFACTURER'S NAME GROW GROUP, INC. ADDRESS (NUMBER, STREET, CITY, STATE AND ZIP CODE) 3155 WEST BIG BEAVER ROAD, SUITE 200 P.O. BOX 7026, TROY, MICHIGAN 48007-7026 MANUFACTURER'S D-U-N-S NO. EMERGENCY TELEPHONE NO. 313 - 643-4600 I" 00-532-0551 HAZARDOUS MATERIALS DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS ID NO. PAINT RELATED MATERIAL NA-1263 ADDITIONAL HAZARD CLASSES (AS APPLICABLE) FLAMMABLE LIQUID CHEMICAL FAMILY SOLVENT BLEND IFORMULA SOLVENT BLEND SECTION II - INGREDIENTS ~~ I EXPOSURE LIMITS IN AIR LISTED AS A CAS (UNITS IN PPM) CARCINOGEN REGISTRY NO. I CHEMICAL NAMES IN NTP IARC ACG lH OSHA VENDOR OR OSHA 1910 64742-89-4 I GS-260 HYDROCARBON PETROLEUM 400 400 400 NO I DISTILLATE OR NAPHTHA 67-56-1 I METHANOL (METHYL ALCOHOL) SKIN 200 200 200 NO 67-63-0 I ISOPROPYL ALCOHOL 400 400 400 NO 67-64-1 I ACETONE 750 1000 1000 NO 108-88-3 I TOLUOL 100 100 100 NO 1330-20-7 I XYLOL 100 200 100 NO 123-86-4 I N-BUTYL ACETATE 150 150 150 NO 108-65-6 I P.M. ACETATE (PROPYLENE GLYCOL 100 100 NO \ I MONOMETHYL ETHER ACETATE) '--' I lOt 100 I 1119-4Ò-0 DIBASIC ESTERS (DIMETHYL 50 I NO SUCCINATE, GLUTARATE, ADIPATE) I e . i' ,\ '\ SECTION III - PHYSICAL DATA 4.c../ BOILING RANGE 135-373 XX OF VAPOR PRESSURE 112.4 @ 68°F °c XX MM HG VAPOR DENSITY (AIR-I) 2.56 °c SPECIFIC GRAVITY (H20-I) 0.7949 PERCENT VOLATILE BY VOLUME 100% PERCENT SOLID BY WEIGHT 0% ¡EVAPORATION RATE SLOWER THAN ETHER PH NOT APPLICABLE PSI SOLUBILITY IN WATER 50% APPEARANCE AND ODOR WATER WHITE LIQUID IS MATERIAL: LIQUID XX SOLID GAS PASTE POWDER SECTION IV - FIRE AND EXPLOSION HAZARD DATA METHOD USED I FLASH POINT BELOW 0 OF °c T. C. C. FLAMMABLE LIMITS EXTINGUISHING MEDIA CO2, DRY CHEMICAL, FOAM, OR OTHER NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) APPROVED METHOD FOR TREATING A CLASS B FIRE. SPECIAL FIRE FIGHTING PROCEDURES SUMMON PROFESSIONAL FIREFIGHTERS. USE FULL PROTEC- TIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS.. WATER SPRAY MAY BE INEFFEC- TIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. IF EXPOSED TO FIRE OR EXTREME HEAT, WATER SHOULD BE USED TO COOL CLOSED CONTAINERS AND PREVENT PRESSURE BUILD-UP OR POSSIBLE AUTO-IGNITION. UNUSUAL FIRE AND EXPLOSION HAZARDS KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND FLAME. VAPORS MAY CAUSE FLASH FIRE. VAPORS MAY IGNITE EXPLOSIVELY. VAPORS MAY SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. DUE TO PRESSURE BUILD-UP, CLOSED CONTAINERS EXPOSED TO EXTREME HEAT MAY EXPLODE. NEVER USE A WELDING OR CUTTING TORCH ON OR NEAR CONTAINER (EVEN EMPTY) AS PRODUCT OR ITS RESIDUE MAY IGNITE. DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS-HAY NOT BE IMMEDIATELY APPARENT, OBTAIN MEDICAL ATTENTION. LEL 0.9% UEL 36% SECTION V - HEALTH HAZARD DATA 10THER LIMIT la/lOa PPM (VENDOR) THRESHOLD LIMIT VALUE 50 PPM (ACGIH) PERMISSIBLE EXPOSURE LIMIT 50 PPM EFFECTS OF OVEREXPOSURE ACUTE - BREATHING - IRRITATION OF THE RESPIRATORY TRACT; HEADACHE, NAUSEA, DIZZINESS, WEAKNESS AND FATIGUE. EXTREME EXPOSURE CAN RESULT IN UNCON- SCIOUSNESS AND EVEN RESPIRATORY ARREST. EYE CONTACT - SEVERE IRRITANT. SKIN CONTACT - PROLONGED AND REPEATED LIQUID CONTACT CAN CAUSE DEFATTING AND DRYING OF SKIN, WHICH HAY RESULT IN SKIN IRRITATION AND DERMATITIS. SWALLOWING - VOMITING MAY RESULT. PULMONARY ASPIRATION HAZARD IF VOMITING OCCURS. CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND IIERv'OUS SYSTEM DAMAGE. I -/ PRIMARY ROUTES OF ENTRY INHALATION, SKIN CONTACT, SWALLOWING. ~~ f1/ ,,( r . e EMERGENCY AND FIRST AID PROCEDURES IF BREATHED - IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED. SUMMON MEDICAL ASSISTANCE IMMEDIATELY. IF BREATHING CEASES. RESTORE USING APPROVED CPR TECHNIQUES AND SUMMON MEDICAL ASSISTANCE IMMEDIATELY. IF IN EYES - FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ASSISTANCE. IF ON SKIN - WASH AFFECTED AREAS WITH SOAP AND WATER. REMOVE SOILED CLOTHING. GET MEDICAL ASSISTANCE IF IRRITATION PERSISTS. WASH CLOTHING BEFORE REUSE. IF SWALLOWED - DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN IMMEDIATELY. ASPIRATION OF VOMITUS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY OVEREXPOSURE NONE WHEN USED IN ACCORDANCE WITH SPECIAL PROTECTION INFORMATION (SECTION VIII). WARNING: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS MAY BE HARMFUL OR FATAL. SECTION VI - REACTIVITY DATA I UNSTABLE STABLE XX INCOMPATIBILITY (MATERIALS TO AVOID) HAZARDOUS DECOMPOSITION PRODUCTS AND CARBON DIOXIDE. ."---.. HAZARDOUS I MAY OCCUR POLYMERIZATION WILL NOT OCCUR STABILITY I CONDITIONS TO AVOID HEAT, SPARKS, FLAME. STRONG OXIDIZING AGENTS. THERMAL DECOMPOSITION MAY YIELD CARBON MONOXIDE CONDITIONS TO AVOID NOT APPLICABLE XX SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED REMOVE ALL SOURCES OF IGNITION (FLAMES. HOT SURFACES, AND ELECTRICAL. STATIC OR FRICTIONAL SPARKS). DO NOT SMOKE. PREVENT BREATHING VAPORS. VENTILATE AREA. BEFORE ATTEMPTING CLEAN-UP. REFER TO HAZARD CAUTIÔN INFORMATION IN OTHER SECTIONS OF THIS MATERIAL SAFETY DATA FORM. DIKE AND CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. STORE IN CLOSED CONTAINER UNTIL PROPERLY DISPOSED OF. WASTE DISPOSAL ~ETHOD DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULA- TIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. CERCLA (SUPERFUND) REPORTABLE QUANTITY (IN LBS) ONE POUND OR REFER TO. SECTION 311 CLEAN WATER ACT. RCRA HAZARDOUS WASTE NO. (40 CFR THINNER BLEND ONLY. VOLATILE ORGANIC COMPOUND (VOC) XX THEORETICAL 6.644 261.33) D-001, F-003, F-005 NOTE: NUMBERS APPLY TO (AS PACKAGED, MINUS WATER) LB/GAL XX 100% ANALYTICAL 6.618 LB/GAL ~ e e -r '-\ SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION WHEN USED IN RESTRICTED VENTILATION AREAS, WEAR NIOSH/MSHA APP~OVED CHEMICAL/MECHANICAL FILTERS DESIGNED TO REMOVE A COMBINATION OF PARTICULATES AND VAPOR. WHEN USED IN CONFINED AREAS, WEAR NIOSH/MSHA APPROVED AIR SUPPLY RESPIRATORS OR HOODS. FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE. IF RESPIRATORS ARE USED. A PROGRAM SHOULD BE ESTABLISHED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29 CFR 1910.134. VENTILATION USE ONLY WITH ADEQUATE VENTILATION. USE EITHER LOCAL EXHAUST OR MECHANICAL TO MEET TLV REQUIREMENTS. VENTILATION MUST BE SUFFICIENT TO LIMIT EMPLOYEE EXPOSURE AT. OR BELOW. OSHA TLV LIMIT. HEAVY SOLVENT VAPORS SHOULD BE REMOVED FROM LOWER LEVELS OF WORK AREA. PROTECTIVE GLOVES NEOPRENE OR EQUIVALENT. EYE PROTECTION SOLVENT RESISTANT SAFETY EYEWEAR WIT~~ SPLASH GUARDS. OTHER PROTECTIVE EQUIPMENT EYE BATH AND SAFETY SHOWER. SOLVENT IMPERMEABLE CLOTHING TO PREVENT SKIN CONTACT. # SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING KEEP AWAY FROM HEAT, SPARKS AND FLAME. DO NOT SMOKE. EXTINGUISH ALL PILOT LIGHTS AND TURN OFF ALL SOURCES OF IGNITION INCLUDING HEATERS. FANS AND OTHER NON-EXPLOSION-PROOF ELECTRICAL EQUIPMENT. DURING USE AND UNTIL ALL VAPORS ARE GONE. VAPORS MAY IGNITE EXPLOSIVELY. VAPORS MAY SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. PREVENT BUILD-UP OF VAPORS BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR. DO NOT STORE ABOVE 120°F OR NEAR FIRE OR OPEN FLAME. STORE LARGE QUANTITIES IN BUILDINGS TO COMPLY WITH OSHA 1910.106. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELED CONTAINERS. DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. . ' NAME W1i2~ SIGNATURE . TITLE LABORATORY MANAGER 'DATE APRIL 25. 1987 .., THE INFORMATION CONtAINED HEREIN IS BASED ON DATA BELIEVED BY GROW GROUP, INC. TO BE ACCURATE, BUT WE DO NOT ASSUME ANY LIABILITY FOR THE ACCURACY OF THIS INFORMATION. WE NEITHER SUGGEST NOR GUARANTEE THAT ANY HAZARDS MENTIONED ARE THE ONLY ONES WHICH EXIST. ANYONE INTENDING TO RELY ON ANY RECOMMENDATION OR TO USE ANY EQUIPMENT. TECHNIQUE OR MATERIAL MENTIONED SHOULD ALSO SATISFY HIMSELF THAT HE CAN MEET ALL APPLICABLE SAFETY AND HEALTH STANDARDS. DETERMINATION OF THE SUITABILITY OF ANY INFORMATION OR PRODUCT FOR THE USE CONTEMPLATED BY ANY USER. THE MANNER OF THAT USE AND WHETHER THERE IS ANY INFRINGEMENT OF PATENTS. IS THE SOLE RESPONSIBILITY OF THE USER. , ,.--.../ " Î . BNL-RN RAT.RIAL SAFETY DATA SRBST 85 FOR COATINGS, RESINS AND RELATED IlATERlALS (Approved by U.S. Department of Labor 'Essentially Similar' to fot'll. OSBA-20) ',,----".' MANUFACTURER'S NAMB ACMB AUTOMOTIVB FINISHBS 101 Pro.pect Avenue H.W. Cleveland, Ohio 44115 DATE OF PREPARATION 15-Nay-S5 INrORJltATION TELEPHONE: NO. (216) 566-2902 EMERGENCY TELEPHONE NO. (2161 566-2911 -----.-------------------------------------------------------------------------- Section I -- PRODUCT tDBRTtrlCATION -------------------------------------------------------------------------------- PRODUCT NAIIE rLBST-X· Reducer (Non-Photoche.lcal) PRODUCT NUMBERS AND COLORS 65 SPBB-D-FLO. 6061 PLaST-X. .educer PRODUCT CLA8S Reducer ---...--------------------------------------------------------------.----------- Section II -- HAZARDOUS INGRBDIENTS as at. DCJaMaT U.V-fG¡M) -------------------------------------------------------------------------------- 64742-89-8 Lt. Aliphatic Hydrocarbon Solvent. 64742-47-8 Mineral Spirits. 108-88-3 Toluene. 64742-95-6 Light AroNtic Naphtha 61-56-1 "ethanol 111-76-2 2-Butoxyethanol 61-64-1 Acetone. 78-93-3 Methyl Bthyl Ketone, 108-65-6 1-"ethoxy-2-Propanol Autate 30-45 0-10 15-20 0-5 <5 0-5 5-30 0-30 0-5 100, 364, 100. 581. 100. 375. 100, 462, 200, 260. 25, 120. 750. 1780. 200, 590. Not Istab. 1.0 53.0 1.0 2,0 1.0 22.0 0.7 3,8 6.0 92,0 1.1 0.6 2,2 180.0 1.8 70,0 1.3 1.8 Par specific percent hazardous in,red1ents in each product, see Section X -.---------.............---.......---------.-....--.---...-.-----.-.----------.. Saction III -- PHYSICAL DATA -------------------------------------------------------------------------------- BVAPORATION RATE -- Slover than Ether VAPOR DENSITY -- Heavier than Air SOILING IlANGB (F) , VOLATILE VOLU!!E liT/GAL 132 - 395 100.0 6.4 ---..-----------------.---------.----------------...-.-..--.------------------.- Section IV -- PIRE AND EXPLOSION HAZARD DATA -------------------------------------------------------------------------------- FLA!!IIASILITr CLAS81F1CATIDN FLASH POINT 3-11 F TCC LEL 0.7 RED LABIL -- Extremely Plammable, Plash bltlov 21 P EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Faa. UNUSUAL FIRE AND EXPLOSION HAZARDS Keep containus tightly closed. Isolate frOIl heat, electrical equipment, sparks, and open nalle. Closed containers may explode when exposed to extrellle heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products lIay cause a health hazard. Symptoms lIIay not be immediately apparent. Obtain lIIedical attention. \~ Cenu~ _ ,.... 2 BNL-RN e ENL-RN FLEET-X. Reducer (Non-Photoche.ical) page 2 .....-.........-......--.......-......--.--.-....---...------..--...---.--------- SPECIAL FIRE FIGHTING PROCEDURES Full pro!ectJve equipmen! including self-con!a1ned breathing apparatus should b. used. Vuer spray may be ineffective. If vater is used, fOI nozzles are preferable. Vater.., be used to cool closed containers to prevent pressure build-up and possible autoigni tion or explosion when exposed to eXUeme heat. --.--.---.-....-....---...--.-...-...........-------..---.------....-------.-.-- . Section V -- HEALTH HAZARD DATA -------------------------------------------------------------------------------- THRESHOLD LIMIT VALUE -- See Section II EFFECTS OF OVEREXPOSURE ACUTE: In a confined area vapors in high concentration are anesthetic. Overexposure..y result in Hghtheadedness and staggering gait. Irritant to skin and upper respiratory 9YS!e.. CHRONIC: Reports have associated repeated and prolonged overexpolure to solvents vith permanent brain and nervous systell dalllage. EMERGENCY AND FIRST AID PROCEDURes If INHALED: If affec!ed, remove froll exposure. Restore breathin.. Iteep vara and quiet. If on SKIN: Vash affected area thoroughly vhh soap and vater. Remove contaminated do!hing and launder before re-use. If in EYES: Flush eyes with large alllounts of vater for 15 .inut... Get lIIedical atten!ion. If SVALLO\lED: Never give anything by mouth to an unconscious penon. DO NOT IHOUCK VOMITING. Give several glasses of vater. Seek aedicel attenUon. --...---..-.-.......-..............--...-.-........-------------.--.---------.-----.-- Section VI -- REACTIVITY DATA -------------------------------------------------------------------------------- STABILITY -- Stable HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION -- Will Not Occur ---..-.-.-...---.....---.....-.............-...-...--.-.--.----.--..--.----------. Section VII -- SPILL OR LBAK PROCEDURES -------------------------------------------------------------------------------- STEPS TO BE!: TAKEN IN CASE PlATERIAL IS RELEASED OR SPILLED Remove all sour~es of ignition. Venttla!e and remove vith inert absorbent. WASTE DISPOSAL METHOD Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance vith Federal, State, and Local regulations regard in, pollution. -..-.....----................---..........--.-...-.........-------..-------------- Section VIII -- PROTBCTION INFORRATION -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN US!: Use only vith adequate ventilation. Avoid breathing vapor and spray _1st. Avoid contact vith skin and eyes. \lash hands after using. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section II is maintained belov applicable exposure U.tts. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RE!:SPIRATORY PROTECTION If personal exposure cannot be controlled below applicable 1I.its by ventUation, year respiratory device approved by NIOSH/MSRA for protection against atertaIs in Section II. PROTECTIVE GLOVES Vear gloves vhich are recommended by glove supplier for protection ..ahst uterhh tn Section II. EYE PROTE!:CTION Vear safety spectacles vith unperforated sideshields. COtIttau.d _ .... J Section IX -- PRECAUTIONS FLEET-X· Reducer (Non-Photochemical) page 3 -.------.--.........--............-.-...-........-.-.--...--....-..-.-.-..-....-- -------------------------------------------------------------------------------- DOL STORAGE CATEGORY -- 18 PRECAUTIONS TO 8E TAKEN IN HANDLING AND STORING Contents are EXTREMELY FLAMHABLE. Keep avay from heat, sparks, and open flame. Vapors will accumulate readily and may ignhe explosivdy. During use and until all vapors are gone: Keep area ventilated - Do not smoke _ Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consul! NFPA Code. Use approved Bonding and Gcounding procedures. Keep container closed vhen not in use. Transfer only to approved con!ainers vi th complete and appropriate labeling. Do not take internally. Keep out of the reach of children. OTHER PRECAUTIONS Intentional misuse by deliberately concentrating and inhaling the conten!s can be harlllful or fatal. 6S 6061 --------..------...--.--..-----.--.....-.-..------.----....----------.----------.-- Section I -- PBRCBNT HAZARDOUS INGREDIENTS -------------------------------------------------------------------------------- Lt. Aliphatic Hydrocarbon Sohent. Hineral Spirits. Toluene. Lilh! Aromatic Naphtha Methanol 2-Butoxyethanol Acetone. Methyl Ethyl Ketone. 1-Methoxy-2-Propan01 Aceta te , '---- 45 30 10 15 5 <5 5 30 20 <5 <5 30 <5 This Haterbl Safety Data Sheet conforDls to the Ruud Communica!ion standacd, 29 eFR 1910.1200(1)(4), for similu complex mixtuces. The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially slier !he composition and hazards of the produc!. Since conditions of use are outside our control, ve make no varranties, express or illlplied, and assullle no liability in connection vith any use of this informa!ion. 71 · 999 RATSRIAL SAPBTY DATA SSEET 9 'OR COATINGS, RESINS AND RELATED IlATERIALS (Approved by U.S. Department of Labor 'lIsentially SilDllar' to lot1lll OSHA-20) ftANUrACTURER'S NAME ACRE AUTOROTIVS PIMI88B8 101 .ro.pact Avenue .... Cleveland, Ohio CCllS DATE or PRBPARATION I-Jul-85 IMERGENCY TELEPHONE NO. (216) 566-2917 INrORrtATION TELEPHONB NO. (216) 566-2902 ------------------------.---------------.-.-.-.--------------------------------- Section I -- PRODUCT IDBNTIFICATION -------------------------------------------------------------------------------- PRODUCT NUMBER * - Trade "ark 999 PRODUCT NAM! PLEST-X. PLBBT-KTRA* Bardener PRODUCT CLASS Cro..linking Urethane Additive ----------------------------------------------------------------.------------... Section II -- BABARDOUS INGRBDIBNTS TLV-fIO¡M) -------------------------------------------------------------------------------- 100-41-4 Ethylbenzene <5 100, 435, 1.0 7.1 1330-20-7 Xylene. 55 100, 435. 1.0 5.9 64742-95-6 Light ArOlllatie Naphtha 10 100, 462, 0,7 3.8 I 23.S6-4 n-Butyl Acetate. <5 150, 710, 1.3 10.0 Not uail. Isophorone DUaocyanate Pol'l11er. 30 Not Estab. MaxlllU8l fns isocyanate aonolller 0.3 0,01 0,09 (Skin) ........-----..........-........................................................ Section III -- PBYSICAL DATA -------------------------------------------------------------------------------- EVAPORATION RATI -- Slover than Ether VAPOR DENSITY -- Heavier than Air 80ILING RANGE (r) , VOLATILE VOLURE NT/GAL 255 - 360 76,1 7.S0 -..........-.....-...--..............-.--------...-..................--.-..-.--- Section IV -- rIRB AND EXPLOSION DAZARD DATA -------------------------------------------------------------------------------- rLAMKABILITY CLASSIrICATION rLASH POINT 80 r PKCC LEL 0.7 RED LABEL -- Pl.auble, Pluh belov 100 P EXTINGUISHING IIEOIA Carbon Dioxide, Dry Che.ical, Po.. UNUSUAL '"IRB AND EXPLOSION HAZARDS Keep containers ti,htly c:losed. Isolate frOIll heat, electrical equipment, sparks, and open fla.e. Closed containers ..y explode vhen exposed to extullle heat. Application to hot surfaces uquius special precautions. Durina: emeraency conditions overexposure to d~cnlllposition products ..ay nUls a health hazard. SYllptOIllS lIIay not be illlmediately appaunt. Obtain .edical attention. SPECIAL 'IRE rIGHTING PROCEDURES Full protective equipment InclucHn, leU-contained breathing apparatus should be used. Vater Ipray ..y be ineffective. If vater 18 used, foa nozzles are preferable. Vater lIIay be . used to cool closed containers to prevent pressure build-up and possible autoianition or explosion vhen expoled to extre_e heat. c.r.U-.f .. ..... 2 999 FLRET-X* FLEET-XTRA* Hardener ...--..................................-.................-...................... pag_ 3 e 999 FLEET -x* FLEET -ITRA* Hardener pac_ 2 ....-................................-.-.............-..-...----.-.............. Section V -- BBALTB BAZARD DATA -------------------------------------------------------------------------------- 'I I THRESHOLD LIMIT VALUE -- See Section II EFFECTS or OVEREXPOSURE AClITE: In a confined area vapors in high concentration are an.8thetic. Ovenxposure..y result in l1ghtheadedness and stallering gait. Irritant to skin. Hay cause luna irritation and aUulic reaction. CHRONIC: Report! have assoc.1ated repeated and prolonged overexposure to .ohents vith perlllanent brain and nervous system dallage. Hay cause lung irritation and allergic respiratory reaction. EI1ERG£NCY AND FIRST AID PROCEDURES [f INHALED: If any breathing problems oceur dl,lrtng use, LEAVE THE AREA and ,et fnsh air. If problems relllain or occur later, IKMEOIATELJ aet ..dical attention. If on SltIN: Wash affected area thoroush!y with soap and vater. Remove contaminated clothin. and launder before n-use. If in BYESI Flush eyes with larle a.ounu of vater for 15 .inutes. Get medical attention. If SWALLOWED I Never alve anything by lIIouth to an unconscious person. DO NOT INDUCI VOMITIHG. Give several alasses of wuu. Seek .edicd attention. ...-.....-.---.--------............-....-......--..........-...-....--.......-.. t Section VI -- REACTIVITY DATA - - -- - -- -- -- --- --- - - -- -- - - -------------------------------------------------- ----- STABILITY -- Stable INCOP1PATIBI LITY Contamination with Vater, Alcohols, Aminu and other co.pounds vhich react vith isocyanates, may result in dangerous pressure in, and possible burstinl of, dOled containen. HAZARDOUS DECO"POSITION PRODUCTS By finl Carbon Dioxide, Carbon Monoxide, Oxides of Nitrolen, possibility of Hydrogen Cyanide HAZARDOUS POLYMERIZATION -- will Not Occur ...-.-.-....-.-.-.-.-....-----.------....-...-..................--..-....--..-.. Section VII -- SPILL OR LEAK PROCEDURES -------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE KATI!:RIAL IS RELEASED OR SPILLED Remove all sources of ilnl tion. VentUate the area. All personnel in tha area .hould be protected as in Section Vln. Cover spill with absorbent _aterial. Deactivate .pilled .aterial with a 10% ammonium hydroxide solution (household aaaonb). Aftar 10.inuta., colhet in open containers and add .ore anonia. Cover loosely. Vash .pill area with loap and vater. WASTE DISPOSAL KETHOD Incinerate in approved fadUty. Do not indnerate closed container. DlIpo.e of In. Iccordance with Pederal, State, and Local regulations reaarding pollution. ...-.............-..--....-.-----.................-.....--.--...--......-....-.. Section VIII -- PRO?ECTION I.rORRA~IO. -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAkEN IN USE NO PERSON SHOULD USE THIS PRODUCT, OR BE IN THE AREA VHERB IT IS BEING USIO. IP TREY 8AYB CHRONIC (LONG-TERM) LUNG OR BREATHING PROBLEMS OR IF THEY EVER HAD A REActION TO ISOCYANATES. Use only "hh adequate ventilation. Avoid breathing vapor and spray .1st. Avoid contact with skin and eyes. Wash hands after us1nl' Protect against dust which ..y be generated by sandin, or abradtna the dri.d fU.. VENTILATION Local exhaust preferable. General exhaust acceptable if the expolure to ..t.riab in Section II is maintained beloy appUcable exposure Haiti. Refar to OSSA Standard. 1910.94, 1910,107. 1910,IOS, a.t~ _ .... J I / '----" RESPIRATORY PROTECTION Vhere overspray is present, a positive air supplied respirator (TC19C NIOSH/MSHA) is recommended. If unavailable, vear a vapor/particulate respirator which respirator manufacturer recommends as effective for Isocyanate vapor or mist. Follow directions for respirator use. Wear the respirator for the whole time of spraying and until all vapors and mists are aone. NO PERSONS SHOULD BE ALLOIlED IN THE AREA VHERE THIS PRODUCT IS BEING USED UNLESS EQUIPPED WITH THE SAME RESPIRATORY PROTECTION RECOMMENDED FOR THE PAINTERS. PROTECTIVE GLOVES Vear Ilove! which are recommended by glove supplier for protection aaainst lIIaterials in Section II. EYE PROTECTION Vear safety spectacles with unperforated sideshlelds. Section IX -- PRBCAUTIONS .-...-.----.-.......-...-...---.---.....-...-.-.........-------.--.............. -------------------------------------------------------------------------------- DOL STORAGE CATEGORY -- lC PRECAUTIONS TO BE TAItEN IN HANDLING AND STORING Contents are FLAMMABLE. Keep away froll heat, sparks, and open flame. Durina use and until all vapors ere gonel Keep area ventilated - Do not IlIIok. - Extinguish all flemes, pilot 11lhts, and heaten - Turn off stoves, electric tooh and appliances, and Bny other sources of Ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Iteep container dosed "hen not in use. Transfer only to approved containers with co.plete and appropriate labeling. Do not take InternaUy. Keep out of the reach of children. OTHER PRECAUTIONS This coating contains materials classified as nuisance particulates, for example titanium dioxide, celciUIII carbonate, etc. (see ACGIH TLV Lht, Preface and Appendix D), vhich lIIay be present at hazardous levels only durina sanding or abrading of the dried fit.. Intentional .huse by deliberately concentrating and inhaling the contents can be harmful or fatal. \-. j _-..-/ 40 The ahove inforllation pertains to th1a product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this produ~t may substantially alter the composition and huards of the product. Since conditions of use are outside our control, ve make no varranties, express or ~.pUed, and aSsulle no Ihbil1ty in connection w1th any use of this information. . L'AC-LL KA~.RIAL SArB~Y DA~A SBBB~ 85 rOR COATINGS, RESINS AND RELATBD PlATBRtALS (Approved by U.S. Departlllftt of Labor 'Essentially Si.Uar' to fOnl OSRA-20) JllANUrACTURBR' 8 NAIIB ACRB AUTOROTIVB PIKlsaBS 101 prospect Avenue H... Cleveland, Ohio 44115 DATE or PREPARATION 17-Jun-85 EltBRGBNCY TELEPHONE NO. (216' 566-2917 INrORMATION TELEPHONE NO. C 216 566-2902 --------.----------------------------------------.------------------------------ Section I -- PRODUC~ IDBNTIFICATION -------------------------------------------------------------------------------- PRODUCT NAIll!: . - Trade "ark PRO-KaIL· Acrylic Lacquer, Lead Color. PRODUCT NUMBERS AND COLORS 6 + 84 Serl.. PRODUCT CLASS Acrylic-cellulose Nitrate Lacquer .----.....---....---..---....................................................... Section JI -- RAIARDOUS INGRaDIEN~S Øl2UMIIft PDCaI'I' ftN-,... nv-øv¡o -------------------------------------------------------------------------------- 108-88-3 1330-20-7 64-17-5 67-63-0 78-93-3 108-10-1 141-78-6 110-19-0 112-07-2 1344-37-2 12656-85-8 Toluene. Iylene. Bthanol 2-propanol Methyl Bthyl Ketone. Methyl Isobutyl ketone. 8thy! Acetate. Isobutyl Acetate. 2-8utoxyethyl Acetate. Lead Chromate. ) Molybdate Oranae. 35 0-5 <5 0-5 15-20 20 0-5 <5 <5 (15 100, 100, 1000. 400. 200, 50. 400, 150. 50, Lead (.. Pb) Chro.iu. VI (as Cr) 0.5-7,0 0,2-1.5 375, 435, 1900, 980, 590, 205, 1400, 700. 330. 0,05 0,05. 0.05 0.05 1.0 1.0 3,3 2.0 1.8 1.4 2.2 1.3 0.5 22,0 5,9 44,0 33.0 70.0 16,0 86.0 12.5 1.0 ...................................-.-.......-......--...---.....-.--........... Section III -- PHYSICAL DAYA -------------------------------------------------------------------------------- EVAPORATION RATE -- Slover than Btber VAPOR DENSITY __ Beavier than Air BOILING IlANGE (r) , VOLATILE VOLUNE 1fT/GAL 172 - 384 75-80 7,7-8,4 ...-............-........................-..-................................... Section IV -- PIRB AND EXPLOSION HAZARD DAYA -------------------------------------------------------------------------------- rLAWIlABILITY CLASSIFICATION rLASH POINT 21 r PNCC L!L 0.5 RED LABEL -- Fla..ble, Plash below 100 , EXTINGUISHING "EDIA . Carbon Dioxide, Dry Cheaical, Poa. UNUSUAL PIRE AND EXPLOSION HAZARDS I(eep containers ttghtly closed. Isolate fro. heat, electrical equipment, sparks, and open flame. Closed containers ..y explode when exposed to extre.e beat. Application to hot surfaces requires spedal precautions. Durin¡ eaergency conditions overexposure to decollposition products ..y cause a health hazard. Syaptou..y not be laedtately apparent. Obtain .et1ical aUenUon. CIIInt;~ ... ,... J LAC-LL . LAC-LL PRO-KRILII Acrylic Lacquer, Lead Colon p... 2 .-............................................................-................-.-..-....... SPP::CIAL FIRE FIGHTING PROCEDURES Full protective equipment tnc:luding self-contained breathin, .pparatus should be undo Vater spray fIIay be ineffective. If water is used, fo, noules an preferable. Vater .ay be used to cool closed containers to prevent pre..ure buUd-up and possibl. autoipition or explosion when exposed to extre.. heat. ......-.....--..............--.........................-........-............... 1> Section V -- DEALTO BAZARD DATA -------------------------------------------------------------------------------- THRESHOLD LIMIT VALUE -- See Section II EFP'ECTS or OVEREXPOSURE ACUTBr In a confined area vapon in high concentration are anesthetic. Overexposure..,. result in l1ghtheadedness and staggering gatt. . Irri tant to skin and upper respiratory .yue.. CHRONIC: Reports have associated repeated and prolonged overuposure to sohent. with peCllanent brain and nervous .,.te. d...... EMERGENCY AND FIRST AID PROCEDURES If INHALED: If affected, remove froa exposure. Restore breathing. Keep wua and quiet. If on SKIN: Vash affected area thoroughly vith soap and vater. Remove contalltnated clothtng and launder before n-us.. If in BYES: Flush eyes with large aaounts of vater for 15 .tnutes. eet medical attenUon. If SVALLOVED: Never give anything by ltOuth to an unconscious penon. DO NOT INDUCI VOMITING. Give several glasses of vater. Seek aed:lcal attenUon. ........-....-.................................................................. SectIon VI -- REACTIVITY DAYA -- - ----------- ------------------------------------------------------------------ STABILITY -- Stable INCOMPATIBILITY Metalltcs contain Alumtnum. Contamination with Vater, Add., or AlbI" tan cause evolutton of hydrogen, which may result in dangerously increased preasure. in dosed contatnen. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dtoxide, Carbon Monoxide, Oxides of Metals in Section II HAZARDOUS POLYMERIZATION -- Kill Not Occur .........--.....--.................................................................... Section VII -- SPILL OR LEAR PROCEDUaES -------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE MATSRIAL IS RELEASED OR SPILLED Remove aU sources of ignitton. Ventilate and rnon with inert ablorbent. KASTE DISPOSAL "ETUDD Incinerate in approved faciltty. Do not incinerate closed conteiner. Dbpo.e of Sn accordance with Federal, State, and Local regulations regudina pollution. .....-.............................................................................. Section VIII -- PROTECTION l"rORRA~IO. - --- -------- -------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN USE . Before tnitial use, consult OSHA's Standard for Occupational Expo.ure to t.ad (29 CPR 1910,1025), Use only with adequate ventUat:lon. Avo:ld breathing vapor and .pra,. allt. '''ot. contact vith skin and eyes. Vash hands after us:lng. Protect against hazardous dust or fu.e. which may be renerated by sandi"" vlrebrusblq, abrading, burning, brazing or velding of the dried fn.. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to ..terlab in Section II 1s maint.ined belov appltcable exposure ltlllitS. a.fer to ~SIIA Standarda: 1910.94, 1910.107, 1910.108, . RESPIRATORY PROTECTION If personal exposure cannot be controlled belov applicable liaft, by yentU.Uoo. ..ar respiratory device approved by NIOSH/MSBA. for protection .lnst ..tedab In Section II. ~_....J ,._~ PRO-UILt Acryltc Lacquer, Lead Colors p..a 3 ........................................-......................................... PROTECTIVE GLOVES Vear gloves which are recolllllended by glove supplter for protectton ..dnlt ..terlab in Section II. BYE PROTECTION Vear safety .pectades with unperforated sideshield.. Section IX -- PRBCAU~IO"9 ..-....-.....-...............................................-.................. -------------------------------------------------------------------------------- DOL STORAGE CATEGORY -- lB PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Contents are FLAMMABLB. Keep 8"ay frOIl heat, sparks, and open flue. During use and until all vapors are gone: Keep area ventilated _ Do not smoke _ Bxtinguhh aU names, pilot lights, and heaters - Turn off stove., electr:lc tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container dosed when not in use. Transfer only to approved containers vt th complete and appropriate labeling. Do not take internally. I(eep out of the reach of children. OTHER PRECAUTIONS This coating contains lIat.rials classified as nuisance parttculates, for exaJllple titanium dioxide, calduII carbonate, etc. (see ACGIH TLV List, Preface and Appendix D), vh:lch ."y be present at hazardous levels only during sanding or abrading of the dried fU.. CONTAINS LEAD. Do not apply on toys and other children's articles, furniture, or any interior surface of a dvell:lng or faciH ty which may be occupied or used by chUdren. Do not apply on any exterior lIurface of dvelling units, such as w:lndow sUb, porches, sta:lrs, or ra:lHngs to which children ..y be cOllllllonly exposed. Intentional _1suse by deUberately concentrating and InhaUng the contenU can be har.ful or fatal. \ ) '~ 26 This Material Safety Data Sheet conforms to the O.zard COlllfllun:lcat:lon standard, 29 cn 1910.12oo(g)(4), for simUar complex JIIixtures. The above tnformation pertains to this product as currently fOrllulated, and is based on the information avaUeble at this time. Addi Uon of reducers or other addi the. to this product may substantially alter the composition and hazards of the product. Since condition. 01 use-are outside our control, ve uke no varranties, express or :I.plied, and aSS\1H no liability in connect:lon vIth any use of this inforution. , LAC-LP RA~BRIAL SAPB~Y DATA SBBB~ 85 POR COA~INGS. RBBINS AND RSLATED IlATERIALS (A¡op"""¡ by U.8, Doput_t of Iàor ·......tlall' 8lollar' to fo.. 0S8A-20) \ ''--- ~ IlANUFACTURBR'S NAIIB AtKa AU~O"O~tV. PIRI8BKS 101 prolplct A.lnul .... el.v.land, Ohio ..115 DATS OF PRSPARATIO. Z3-Ra,-85 INrORIlATION TEUPHONS NO. (Z16 566-Z90Z SRBRGSNCY TELBPHONS NO. I Z16) 566-Z917 ...----.....------....----...-----....----......-----.---------...-.-------.-.-. Saction I -- 'RODUC~ IDSR~IPICA~IO. -------------------------------------------------------------------------------- PRODUC~ NAIlS ..o-.aIL· Acrylic Lacquer, Ron-L.ad Color. 'RODUC~ NUIIURS AND COLORS , + I. S.rl.. 'RODUC~ CLAB8 Acrylic-Cellula.. Nitrate Lacquer ......................-.......-.....---------...---------.-.--.-.-.-....-------. 'ection II -- RASA.DOUB IRGRBDIBNYS CM ... 1..-01.. 'n.¥"""""" -------------------------------------------------------------------------------- 108-88-3 Tolulnl. 1330-20-7 Iylo,". '4-17-5 8thanol 67-63-0 2-Proponol 78-93-3 Mothyl 8thyl lotO.I, 108-10-1 Mlthyl Itobutyl ':'ton.. 123-86-4 .-But,1 AClt.tl. 141-78-6 8thyl Ac.toto. 110-19-0 hobutyl ACltate. 112-07-2 2-lutoXYltbyl AcUat.. 35-40 0-5 <5 <5 15-20 0-20 0-10 0-5 0-5 <5 100. 100, 1000, 400, 200, 50, ISO, 400, ISO. 50, 375. 435. 1900, 980. 590. 205. 710. 1400. 700. 330. 1.0 1.0 3,3 2,0 1.8 1.4 1.3 2.2 1.3 0.5 22.0 5.9 44.0 33.0 70.0 16.0 10.0 86,0 1.5 1.0 .................-----.-.--...----.--------------------------------------------- Saction III -- PBISICAL DA~A -------------------------------------------------------------------------------- IVAPORATIOR UTI -- Slover than Ither VAPoa DBNSITY __ aeavier than Air SOILr.G RAIIOB (P) , VOLA~ILS VOLURS liT/GAL 17Z - 384 75-85 7.5-8.5 .............-.----..---.---......-.-----------------------------------.-------- Sactlon IV -- PIRB AIID ..'LOSION BAIARD DATA -------------------------------------------------------------------------------- rLAIIIlABILITY CLA8BIrICA~ION FLA8B 'OIN~ Z1 F PRCC LSL 0.5 aID LAlBL -- n....bl., nub below 100 , BXTINOUISBrNG RSDIA Carbon Dioxide, Dry Ch..icd, 10.. UNU8UAL rIRB AND BXPL08ION HAZARD8 keep contatn.n Haht1, elOIR. Isolate froa heat, ellctrical equipment, .parlta, .nd open fhlle. Closed container. .IY .xplode vhn expond to extn.. heat. AppUcation to hot Burfac.. requires special pncluthn.. Durin, e..r.ency conditions overexposure to deco.positlon productl .., CIU" . health huard. SY1Iptoms..y not be iu,dietely apparent. Obtain INdica! attention. SPECIAL rlRE rIGR1'ING PROCBDUItBS rull protective ~u1p..nt 1nc:1udin. .elf-contained breathing apparatus should be used. Vater .pra, .., be ineffecthe. If .ater b ueed, fo, noules are preferable. Vater may be used. to cool do.ed containen to pre..nt pra..ure build-up and po..ib1e lutoirnition or .xplolion ¥hen "poled to utr... heat. I \---- c.u..... _ .... 1 LAC-LP , LAC-Lr PRO-ItRIL· Acrylic Lacquer, Non-....ad Colon pql2 -......---..-.-----.-.....-..---.--..----....----..---------.------------------. Slet10' V -- BBALTB BAIARD DA~A -------------------------------------------------------------------------------- THRESHOLD LIMIT VALUE -- Se. Section II EFFECTS or OVEREXPOSURE ACUTE: In a confined area vapon in biBh concentration are .....thetic. OYez-exposure_, I'esult in lightheadedness and staggering gait. 1 Irritant to skin and upper respiratory 5Yst... CHRONIC: Reports have assodated repeated and prolonged Oyuexposure to .oheDt. with penanent brain and nervous 5YSt.. d...... EMERGENCY AND FIRST AID PROCEDURES If INHALED: It affected, rellove fro. exposure. Restore breathin¡. KHp wara and quiet. It on SUN: Vash affected area thoroulhly with soap and vatu. Re~ve cont8llinated: clothing and launder before re-us'. If in BlESI Flush eyes with large uounU of vater for 15 .taut... Get medical attention. If SVALLOVED, Never give anything by .outh to an unconscious penon. DO ROT IMDUCI VOMITING. Cive several ,lasses of vater. Seelt. ..died attention. ----.-..---..-.-.----.-.--.....-.-.-....----.--...---.---.----------.----------- Section VI -- REACTIVITY DATA - - ------- - ---- ------------------------------------------------------------------ STABILITY -- Stable INCOMPATIBILITY Metallics contain Aluminum. Contamination with V.ter, Acide, or AlbU. can caul. evolution of hydrogen, vhich lIay result in ,d.ngerousl, increased pressur.. in dosed containen. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION -- will Not Occur ----...-..-.--....------.---.------.......--.....-------.----------..-------.--- Section VII -- SPILL OR LEAK PROCBDURBS ----------------------------------------------------------------..--------------- STEPS TO 8E TUEN IN CASE IlATERIAL IS RELEASED OR SprLLBD Remove all sources of ignition. Ventnate and re.,ve with inert .baorbent. WASTI!: DISPOSA.L "ET80D Indnerate in approved facility. Do not indnerate closed container. Dlspo.e of in accordance with Federal, State, and Local regulations teaard!", pollution. ----.-.------..------.....-------...----.....-------..----.----..-.--..----..-.. Section VIIr -- 'RO~BC~IO. I.PORRATIO. -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid bnathinl vapor and Ipray .tat. 'void contact vith sUn and eyes. Vash hands after usinl' Protect .,ainst dust which ..y be .enerated b)r .andina or abradina the dried fn.. VENTILATION Local exhaust preferable. General exhaust 8Cceptlble if the "po.ure to ..terhla in Section II is .a1ntained below applicable exposure 11.iu. aefer to OSØA Standardl 1910.94, 1910.107, 1910,108, RESPI RATORY PROTECTION . If penonal expo3ure cannot be controlled belov applicable U.its by ventUation, waar respiratory device approved by NIOSR/MSRA for protection ..a!nst atedab 1n Section 11. PROTECTIVE GLOVES Veer gloves which an ncoll!llended by alove euppUer for protectloD ..ainst ..tertall in Section II. EYE PROTECTION Veu .afety .pectacle. vi th unperforeted .id..hields. c..u.M .. .... J Section IX -- PRECAU7IONS PRO-UIL· Acrylic Lacquer Non-Lead Colors P&le 3 ------.-------------...-.--.--..---....-----------.--.---.-.--------...--------- -------------------------------------------------------------------------------- DOL STORAGE CATEGORY -- 18 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Vaporl will accumulate readily and may ignite explosively. Durin. use and until all v.pon .re gone I J.:eep area ventilated _ Do not slIoke _ Extinguish all names, pilot Hghu, and heaters - Turn off stoves, electric toob and appliances, .nd any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. It.eep container closed vhen not in use. Transfer only to approved containers vi th complete and appropri.te labeling. Do not take internally. K!ep out of the reach of children. OTHER PRECAUTIONS This coating contains materials classifhd as nuisance p.rtlculates, for example titaniulD dioxide, CalciUID carbonate, etc. (see AcelR TLV List, Preface and Appendix D), which ..y b. present at hazardous levels only durin, sandin. or abrading of the dried fll.. Intentional mbuse by deliberately concentnths and inhaling the contents can be har.ful or fatal. '. L- This Material Safety Data Sheet con fortis to the Hazard COUlunication standard, 29 CFR 1910.1200(1)(4), for similar complex mixtures. The above infonation pertains to this product as currently formulated, and is bas.d on the information available It this time. Addition of reducers or other additive. to thh product .ay subst.ntially alter the composition and hazards of the product. Since conditions of us. are outside our tontrol, ve lIIake no varrantiea, express or i.plied, and as.u.e no Uabni ty in connection vith any ue. of thh hforution. 25 . BHL-LL RATBRtAL BArB~Y DATA saSST BS rOR COATINGS, RBSINS AND RELATED ftATBRIALS (Approved by U.S. Departllent of Labor '!.ssenUaUy S1.Uu' to foCII 0SBA-20) PlANurACTURBR'S HAft£' ACMB AUTOROTIV& PIRIBRKS 101 Prospect Avenue H.W. Cleveland. Ohio CCIIS DATE or PREPARATION 28-lIay-85 EftBRGENCY TELEPHONE NO. (216) 5&&-2917 INrORPlATION TELEPHONE NO. (216) 5U-2902 --------------------------------------------------------------------..----------- Section I -- PRODUCT IDBNTIFICATION - ------------------------------------------------------------------------------- PRODUCT NAPlE FLEBT-X· Ina..l, Lead Color. PRODUCT NUMBERS AND COLORS 2 + 83 Serie. PRODUCT CLASS Alkyd Enamel ------------------------------------------------------.------.................... Section II -- HAZARDOUS INGREDIENTS -- ....-<a,1U - ------------------------------------------------------------------------------- &4742-48-9 Y. N, , p, Naphtha. 5-15 300, 1350. 0.9 12.0 64742-47-8 "ineral Spirits. 15-35 100, 581. 1.0 2,0 108-88-3 Toluene. 0-5 100. 375. 1.0 22.0 1330-20-7 Xylene. 1-30 100. 435, 1.0 5.9 &4742-95-6 Light Aro.attc Naphthá 0-20 100, 462. 0,7 3,8 123-86-4 n-Butyl Acetate. 0-5 150, 710, 1.3 10.0 7758-97-6 Lead Chroma Ie. } 0,05 1344-37-2 Lead ChrOll4te. <30 0.05 12656-85-8 Molybdate Orana:e. 0,05 Lead (as Pb) 0,3-18,5 0.05 Chro.i UIII VI (as Cr) 0.0-4,0 0,05 ----.--------------.------.---.--------.----------------------.-.--------------- Section lIt -- PHYSICAL DA~A -------------------------------------------------------------------------------- EVAPORATION RATE -- Slower than Ither' VAPOR DENSITY -- Beavier than Air BOILING RANGE «r) , VOLATILE VOLUME WT/GAL 222 - 395 59-&5 1.8-10,0 --------------------..---------------..------------------------.--------..------ Section IV -- rlRS AND EXPLOSION HAZARD DA~A -------------------------------------------------------------------------------- FLMIlABILITY CLASSIPICATION PLASH POINT 12 P PIICC LEL 0,1 RED LABBL -- Plaaab1e, Fluh below 100 P EXTINGUISHING NEOlA Carbon Dioxide, Dry Clte.ical, Poelll UNUSUAL rIRE AND EXPLOSION HAZARDS Keep containers tightly closed. lIohte froa heat, electrical equiplllent, sparb, and open flame. Closed containers lIIay explode when exposed to extreme heat. Application to hot surfaces requires special precautions. Dur::ing emergency conditions overexposure to decomposition products .ay cause a health h....rd. SYJlptoms..y not be immediately .pparent. Obtain medical .ttentlon. c.aU~ _ .... J BRL-LL FLEET-X* Enalllel, Lead Colors ---.----------.----------------------------------------------------------------- page 3 . ENL-LL FLEET-X. Enallel, Lead Colors ,ace 2 ------------------------ --.-- ------------..------------------------------------- SPECIAL "IRE ..IGHTING PROCEDURES Full protective equipment Including self-contained breathlnc apparatuI should be UI.d. \later spray lIIay be ineffective. If vater 1s used, fog noulel are prefer.ble. Vater.., 1M und to cool closed. containers to prevent pressure build-up and po.llble .utoicnhton or explosion vhen exposed to extrellte heat. ----------------- ------------------------------------------------------..------ ~~/ Section V -- BEAL~H HAZARD DA~A -------------------------------------------------------------------------------- THRESHOLD· LIMIT VALUE -- See Section It EFFECTS or OVEREXPOSURE ACUTE: In 8 confined area vapors In high concentntion are anelthetic. O'Ierupoaure..,. result in lightheadedness and staggering gsh. Irritant to skin and upper resphatory syst... CHRONIC: Reports have associated repeated and prolonged oVllfrezpolure to 80hent. with permanent brain and nervous SystH da..,e. Repeated and prolonged exposure to .pray .1st ..y Uuse perforation of oaaa1 septum and ulcers of the skin. EMERGENCY AND FIRST AID PROCEDURES If INHALED: If affected, remove froll exposure. Restore breathing. llteep war'll and quiet. If on SKIN: Vash affected area thoroughly with soap and vater. Remove contaminated clothing and launder before r.-uI.. If in EYBS: Flush eyes with large utounU of vater for 15 .lnut.l. Get medical attention. -.-------.-------- -------------------------------------.------------------------ Section VI -- REACTIVITY DATA ------------------------------------------------------------------------------- STABILITY -- Stable INCONPATIBILITY Metallics contain Aluminum. Contallinatlon vith Vater, Addl, or AlkaUs can, c.us. .volutlon of hydrogen, vhich fIIay result in dangerously Increased pressure. In clOled eontalnen. HAZARDOUS DECO"POSITION PRODUCTS By fire: Carbon Dioxide. Carbon Monoxide, Oxides 01 Ketah In Section II HAZARDOUS POLYMERIZATION -- Will Not Occur ---- ----------.------- ---.------------------------------------------------------ Section VII -- SPILL OR L.A. PROCEDO... -------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE IlATBRIAL IS RELDSBD OR SPILLED Remove all sources of ignition. Ventilate and retlOve vith tnert ablorMat. WASTE DISPOSAL METHOD Incinerate in approved facility. Do not incinerate closed container. 018,0.. of 1ft .ccordance vith Federal, State, and Local regulations regudlRl' polluttoa. ------------.----------------------------------------.------------.------------- Section VIII -- PRO~EC~IO. I.rO..AYIO. -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN USE Before initial use, consult OSHA'I Standard for Occup.tlonal Bxpolur. to Lead (19 CPR 1910.1025). Use only with adequate ventilation. Avoid breathlnl vapor and spray .ht. ,yold eon tact vith skin and eyes. Vash hands after using. Protect against hazardous dust or fumes vhich ..y be g.nerated by sandlnc, vlnbrusblq, abrading. burning. brazing or welding of the dried fU.. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to utul.b In Section II is maintained belov applicable exposure Ibite. Refer to OSHA StlDd.rd. 1910.94, 1910.107. 1910.108. . RESPIRATORY PROTECTION If personal exposure cannot be controlled belov applic.ble 11.1 U by yetilatlon, wear .respiratory device .pproved by NIOSB/MSBA for protection ...Iut _teriab In 5eet1on II. CIIIat~ _ .... J ',---/) PROTECTIVE GLOVES Vear gloves vhich .re recommended by glove supplier for protection againlt aateria1s in Section II. BYE PROTECTION Vear safety spectacles vith unperforated sldesh1elds. Section IX -- PRBCAUTIONS -.--.------..----------.-------------.--------.----------..---..--..------..---- -------------------------------------------------------------------------------- DOL STORAGE CATEGORY -- lC PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Contents are FLAMMABL8. Iteep away frolD heat, sparks, and open flame. During use and until all vapors are gone: hep area ventilated - Do not IlIIok. _ Extinguish aU flames, pilot lights, and heaters - Turn off stoves, electric toob and appliances, and any other sources of igni tion. Consult NPPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in use. Transfer only to approved containers with co.plet. and appropriate labeling. Do not take internally. Keep out of the reach of children. OTHER PRECAUTIONS This coating contains materials clusHied as nuhance particulates, for exa.ph titaniulII dioxide, calciulII carbonate, etc. (see ACGIH TLV List, Preface and Appendix D), vhich may be present at hazardous levels only during sanding or abrading of the dried fil.. CONTAINS LEAD. Do not apply on toys and other children's articles, furniture, or any interior surface of a dvelUng or facility vhich may be occupied or used by chlldren. Do not apply on any exterior surface of dwelling units. such as window sills, porches, Itatrs, or raiUngs to which children may be cOllllllonly exposed. Intentional misuse by deliberately concentrating and inhaUn. the content. can be harmful or f.tal. ! \ i ""--..._/ 24 This "aterial Safety Data Sheet conforlls to the Hazard Coltlllûnicat1on standard, 29 CPR 1910.12oo(g)(4), for simUar complex mixtures. The above inlonation pertains to this product as currently formulated, and 1a based on the information .vailable at this time. Addition of reducers or other additives to thh product .ay substantially alter the cOllposition and hazards of the product. Since condition. of use are ouuide our control. we .eke no warranties, express or illplied, and a..u.. no liability In connection with any use of this inforution. · ENL-LP 85 RATERIAL SAFETY DATA 99EET FOR COATINGS, RESINS AND RELATED KATERIALS (Approved by U.S. Departllent of Labor 'Essentially SimUar' to fona OSHA-20) \ ,_. ltANUFACTURER'S NAIIE ACRE AUTO"O~IVB FINISHBS 101 Prospect Avenue H... Cleveland, Ohio ..115 DATE or PRI!:PARATJON Z8-Ray-85 INFORMATION TELEPHONE NO. (Z16) 566-Z90Z EMERGENCY TELEPHONE NO. (H6) 566-Z9I7 ...--------.------------------------------------..-------...-------------------- Section I -- PRODUCT IDENTIPICATION -------------------------------------------------------------------------------- PRODUCT NAME PLEET-X· Bna..l, Non-Lead Colors PRODUCT NUMBERS AND COLORS 2 + 83 Seri.s PRODUCT CLAS S Alkyd Enamel ---------------------..---------------------.-.--..----------------------------- Section II -- HAZARDOUS INGREDIEN~S ...._"" -------------------------------------------------------------------------------- 64742-48-9 V. N. " P. Naphtha. 5-15 300. 1350, 0.9 12,0 64742-47-8 Hinenl Spiri ts. 1-35 100, 581. 1.0 2,0 108-88-3 Toluene. 0-5 100, 375, 1.0 22.0 1330-20-7 Xylene. 1-30 100, 435, 1.0 5.9 64742-95-6 Light Arolllatte Naphtha 15-20 100. 462, 0.7 3.8 -------------------------------------------------------------------------------- Section III -- PHYSICAL DATA -------------------------------------------------------------------------------- BVAPORATION RATE -- Slover than Ether VAPOR DENSITY __ Heavier than Air BOILING RANGE I r) , VOLATILE VOLUKE NT/GAL ZZZ - 395 58-65 7.8-10.0 -------------------------------------------.-.-.-.-.----...--------.---.-------- Section IV -- FIRE AND EXPLOSION BAZARD DATA -------------------------------------------------------------------------------- FLAKIlABILITY CLASSIFICATION FLASH POINT 73 r PACC LBL 0,7 RED LABEL -- Flalllmable, Flash belov 100 P EXTINGUISHING "EDIA Carbon Dioxide, Dry Chemical, Poa. UNUSUAL FIRE AND EXPLOSION HAZARDS Keep containers tightly elosed. Isolate from helt, electrical equipment, sparks, and open flame. Closed containers ..y explode vhen exposed to extreme heat. Application to hot surfaces requires special precautions. During elllerlency condi tions overexposure to decomposition products lIay cause a health hazard. Symptoms...y not be ieediately apparent. Obtain lIedical attention. SPECIAL rIRI!: rIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Vater spray ..y be ineffective. If vater is used, fog nozzles are preferable. Vater may be used to cool closed containers to prevent pressure build-up and possible autolgn1tion or explo8lion when exposed to extreme h.at. \ "'--- OcIIIoU..... _ ,.,. J BNL-LP FLEET-X· Enamel, Non-Lead Colors --.----..-----------....-------.--.----..----..-----.-----.-..------.-------------.-- pale 3 Section IX -- PRBCAUTIONS I B:NL-LP FLEET-X· Ena.el, Non-Lead Colors P... 2 --.---..-..---.--.--....--.-.--..--.---..--.---.------.---.---.------------.------ Section V -- BEAL~B DAIARD DATA -------------------------------------------------------------------------------- THRESHOLD LHIIT VALUE -- See Section II EFFECTS or OVEREXPOSURE ACUTE: In a confined area vapors in high concentration are ane.thetic. Ovenxpolure ...y result in Hghtheadedness and staggering gait. I hl'itant to skin and upper respiratory system. ' CHRONIC: Reports have associated repeated and prolonged overexposure to 10lvenU with permanent brain and nervous system dau¡e. EMERGENCY AND FIRST AID PROCEDURES If INHALED: If affected, remove frOIl exposure. Rutore breathina:. ke.p var. and quiet. If on SKIN: Vash affected area thoroughly vith soap and vater. Remove contaminated clothing and launder befon u-use. If in EYES: Flush eyes vith large amounts of vater for U· .!nut... eet IIH!dical attention. -..---.---..---...------.----.----..--.--..--..--..-...-.----.-.-.------.------- Section VI -- RI!:AC~IVITY DA~A -------------------------------------------------------------------------------- STABILITY -- Stable INCOMPATIBILITY Hetallics contain Aluminum. Contamination with Vater, Acids, or Alkalil can cause evolution of hydrogen, vhich lIIay result In dangerously increased pressures in closed eontatnen. HAZARDOUS DECOPlPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Honoxide HAZARDOUS POLYPlERIZATION -- Will Not Occur -..--.....---...-----.....--...----.---.--....-..--....--...----.---.------------------- Section VII -- SPILL OR LEAK PROCBDURES -------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE I'IATERIAL IS REL!ASED OR SPILLED Remove all sources of ignition. VentUate and re.ove vith Inert .b.orbent. WASTE DISPOSAL METHOD Incinerate in approved facUity. Do not indnerate closed container. Dispos. of in accordance vlth Federal, State, and Local regulations regarding pollution. ------.---.----..---.-......--..---......--....--..----.---..---.------------------ Section VIII -- PROTBCTION INFO.RATIOR -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN USE Use only vith adequate ventUation. Avoid breathi", vapor .,.d .puy .ilt. Avoid contact vith skin and eyes. Vash hands after using. Protect against dust vhich ..y be generated by sanding or .bradin¡ the dried (U.. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to aterials in Section II is lIaintained below applicable exposure Ii.itl. Refer to OSHA Standards 1910.94. 1910.107, 1910,108, RESPIRATORY PROTECTION If personal exposure cannot be controlled belov applicable li.lts by ventUation, veal' respiratory device approved by NIOSH/HSHA for protection ...a1nst ..terlab in Section II. PROTECTIVE GLOVES Vear gloves which are nconended by glove supplier for protection qainst ..teriah in Section II. EYE PROTECTION Veal' safety spectacles vi th unperforated lideshieldl. c.ti.... _ .... J ¡ i -------------------------------------------------------------------------------- DOL STORAGE CATEGORY -- 1C PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Contents are FLAHHABLB. Keep avay from heat, sparks, and open nallle. During use and until all vapors are gone: Keep area ventilated _ Do not smoke _ Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed vhen not in use. Transfer only to approved containers vith complete and appropriate labeling. Do not take internally. Keep out of the reach of children. OTHER PRECAUTIONS This coating contains materials classified as nulsance particulates, for example titanium dioxide, calc:tum carbonate, etc. (see ACGlH TLV List, Preface and Appendix D), vhich may be present at hazardous levels only during sanding or abrading of the dried fn.. Intentional lIIisuse by deliberately concentrating and inhaHng the content. can be hr.ful or fatal. '-. \'--./ Tbis Haterial Safety Data Sheet conforllls to the Hazard COlllllunication standard, 29 CFR 1910. 1200(g)(4), for similar complex mbtures. The above information pertains to this: product as currently formulated, and Is based on the information available at this time. Addition of reducers or other additives to this product lIIay substantially alter the composition and hazards of the product. Since conditions of use an outside our control, ve make no varranties, express or implied. and .s.u.. no liability in connection vith any use of this information. 23 · ACR-LP "A~ERJAL SAraTY DATA SRRST 85 rOR COATINGS, RESINS AND RgLATED MATERIALS (Approved by U.S. Department of Labor 'Essentially Sf.Uer' to fom OSBA-20) \ \ '--. MANUFACTURER'S NAft! ACRB AUTOMOTIVB FINISHES 101 Prospect Avenue N... Cleveland, Ohio 44115 DATE or PREPARATION 30-Apr-B5 INrORfIlATION TELEPHONE NO. (216 566-2902 EPlERGENCY TELEPHONP; NO. (216) 566-2917 ------------------..-..---------------------------------...------------------------ Section I -- PRODUCT IDBNTIFICATION -------------------------------------------------------------------------------- PRODUCT NAME Acrylic Bna.el, Ron-Lead Color. PRODUCT NUMBERS AND COLORS 3 + 85 Sert.s PRODUCT CLASS Acrylic Enamel --------------------....--------------------------......----------------------------- Section II -- HAZARDOUS INGREDIEN~S CAS Ita, II'GJ!IÐtDl't TtP-,,,. TtP-tG/!U -------------------------------------------------------------------------------- 64742-47-8 "ineral Spirit!. 108-88-3 Toluene. 100-41-4 Bthylbenzene 1330-20-1 Xylene. 64742-95-6 Light Aro'lIIatic Naphtha 123-86-4 n-Butyl Aeetate. 111-76-2 2-Butoxyethanol 112-07-2 2-Butoxyethyl Autat.. <5 1-10 <5 30-40 <5 0-10 0-5 <5 100, 100. 100, 100, 100. 150. 25. 50. 581. 315. 435, 435. 462. 110. 120, 330, 1.0 1.0 1.0 1.0 0,1 1.3 1.1 0.5 2.0 22,0 1.1 5,9 3.B 1D,O 0,6 1.0 -----------------------.--------..---------------------------------...---...---. Section III -- PBYSICAL DATA -------------------------------------------------------------------------------- EVAPORATION RATE -- Slover than Bther VAPOR'DENSITY -- Reavier than Air BOILING RANGE (r I , VOLATILE VOLUME WT/GAL 222 - 395 55-65 B. 0-9.5 --.---.---.-..---.-.....----------..-..-..------------.--.---.-.---------.------ Section IV -- FIRE AND EXPLOSION HAZARD DATA -------------------------------------------------------------------------------- FLAMMABILITY CLASSIFICATION FLASH POINT 50 r PMCC LEL 0.5 RBD LABEL -- PIU111&ble, Plash below 100 P EXTINGUIBHING MEDIA Carbon Dioxide, Dry Chemieal, Po.. UNUSUAL rlRE AND EXPLOSION HAZARDS Keep contaln.n tightly dosed. Isolate frolll heat, electrical equipment, sparks, and open fhllle. Closed containers .ay explode vhen exposed to extreme heat. Application to hot surfaces requires special precautions. During emergeney conditions overexposure to decomposition products .ay cause a health hazard. SymptOIllS oy not be iIImediately 8ppannt. Obtain .edical attention. SPECIAL rIRE rIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Vater spray ..y b. ineffective. If vater is used, fog nozzlea are preferable. Vater 1118Y be used to cool closed containers to prevent pressure build-up and possible 8utoignhion or explosion when exposed to extreme heat. \ '-.--' ContiNMd .. ,... J , ACR-Lr Acrylic Enalllel, Non-Lead Colors pag. 2 ----......--....----...-.......----.---..----...--.....-.---.---------------.------------- Section V -- BIALTB BAIARD DATA -------------------------------------------------------------------------------- THRESHOLD. LIMIT VALUE -- See Section II EFFECTS OF OVEREXPOSURE ACUTE: In a confined area vapors In high concentntton are anesthetic. o..rexpolure..,. result in lightheadedness and staggering gait. . Irrl tant to skin and upper resphatory syate.. CHRONIC: Reports have associated reputed and prolonged overexposure to sohenr. vith permanent brain and nervous syste. da....e. EMERGENCY AND FIRST AID PROCEDURES If INHALED: If affected, remove fro. exposure. Restore breathtna. Ite.p vara and quiet. If on SKIN: Vash affected area thoroughly with soap and vater. Remove conta.inated clothing and launder before r.-use. lf in BYESt Flush eyes with large allOunts of vater for IS .inut.l. Get medical attention. ----.----.....-------.------...----------.------.------------..-..-----------.------- Section VI -- RaACTIVI~Y DATA -------------------------------------------------------------------------------- STABILITY -- Stable INCOMPATIBILITY "etalltcs contain Aluminum. Contaainltion with Vatu, Acids, or AlbUs can CIUse evolution of hydrogen, which may result in dangerously increased pressures In clos.d containan. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon "onoxide, Oxides of Nhrogen, possibiUty of Hydrogen Cyanide, and Oxides of Metah in Section II HAZARDOUS POLYMERIZATION -- will Not Occur .----..------..----------...---.--.----...---....----.--.----.------.------------- Section VII -- SPILL OR LEAK PROCEDURES -------------------------------------------------------------------------------- STEPS TO BE TA~EN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate and re~ve vith Inert absorbent. WASTE DISPOSAL METHOD Incinerate in approved facility. Do not Indnerate closed container. Dlspo.. ot In accordance with Federal, State, and Local reguletions regarding pollution. .--.-----------..-------.------.--.-.-----.----.-----.--.------------------------ Section VIII -- PRO~BC~ION INPO.KAYIOR -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAkEN IN US! Use only with adequate ventilation. Avoid bre.thin. vapor and .pray .ht. Avoid contact with skin and eyes. Vash hands after using. Protect against dust which Ny be ,enerated by sandin, or .bradine the dried tn.. VENTILATION Local exhaust preferable. General exhaust acceptable If tbe .xposure to ..teri." in Section II is maintained below appl1cable exposure U.itl. Rd.r to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable li.lts by ventilation, wear respiratory device approved by NIOSR/MSRA for protection apinst ..teriab In S.ction II. PROTECTIVE GLOVES Vear gloves which are recouended by glove supplier for protection ..al...t ..tuiab in Section II. EYE PROTECTION Vear safety spectacles with unperforated stduhield3. c.t;..... _ .... ) ACR-LP Acrylic Enamel, Non-Lead Colors page 3 --------.---------------.-----..--..----..----.-----.---------------------.----- Section IX -- PRICAU~IONS -------------------------------------------------------------------------------- DOL STORAGE CATEGORY -- la PRECAUTIONS TO BE TAREN IN HANDLING AND STORING Contents are FLAMMABLE. K.eep away froll heat, sparks, and open flame. Durin, use and until all vapors are ,()Oe: hep area ventilated _ Do not s.olte _ Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not in USe. Transfer only to approved containen with co.pl.t. and appropriate labeling. Do not take Internally. Keep out of the reach of children. OTHER PRECAUTIONS This coating contains materials classified as nuisance particulates, for exa.ph titanium dioxide, calcium carbonate, etc. (see ACGIH TLV List, Preface and Appendix D), which .ay be present at hazardous levels only during sanding or abrading of the dried til.. '- Intentional misuse by deliberately concentrating and inhaltnl the contents can be har.tu! or fatal. \, '-- \ This Material Safety Data Sheet conforms to the Hazard COllUllunieaUon standard, 29 CrR 1910.1200(<<)(4), for similar complex mixtures. The above information pertains to this product as currently fOl.':lIulated, and is based on the infonation available at this time. Addition of reducen or other additives to this produet ltIay substantially alter the co"posltion and hazards of the product. Since eondltlon. of use are outside our control, ve make no varranties, expreu or impUed, and asaUH no liability in connection with any use of thh information. 21 · ACR-LL RAYS RIAL SAFETY DATA SRBBT 85 FOR COATINGS, RESINS AND RELATED ftATERIALS (Approved by U.S. Depa.rt~t of Labor 'Essentially 51111lar' to fom OSHA-20) MANUFACTURER'S NA"B ACRE AUTOKOTIVK FINISBBS 101 Prospect Avenue N.W. Cleveland. Ohio 44115 DATE or PREPARATION 6-lIa)'-85 E"ERGENCY TELEPHONE NO. (1161 566-2917 INrORJltATION TELEPHONE NO. (116) 566-2902 ------------.------------------------------------------------------------------- Section I -- PRODUCT IDENTIFICATION -- ----------------------------------------- --------------------------- ---------- PRODUCT NAPlE Acrylic ana..l. Lead Colors PRODUCT NUMBERS AND COLORS 3 + 85 serie. PRODUCT CLASS Acrylic Iname1 --------...-----------------------------------------.--....------------------------- Section II -- RAZAROOUB INGRBDIBNTS I1IDSDIIÞI't I'DCØI' 'I'LV-IIJ/IO -------------------------------------------------------------------------------- 64142-41-8 Mineral Spirits. <5 100, 581. 1.0 2.0 108-88-3 Toluene. 1-10 100, 315. 1.0 22,0 100-41-4 Ethylbenzen. <5 100. 435. 1.0 1,1 1330-20-7 Xylene. )0-40 100. 435. 1.0 5.9 64142-95-6 Lipt Aromatie Naphtha 1-10 100. 462, 0.1 3.S 112-01-2 2-Butoxyethyl Aeetat.. <5 50. 330. 0.5 1.0 123-86-4 n-Butyl Acetate. 0-5 150. 110, 1.3 10,0 1344-31-2 Lead Chro..te. } (15 0,05 12656-S5-8 Molybda te Oranae. 0,05 Le.d (as Pb) 0,)-11.0 0.05 Chromium VI (a. Cr) 0.0-2,5 0.05 --------------.-----------.------.-.-----------..------------------.------------- section III -- PHYSICAL DATA -------------------------------------------------------------------------------- BVAPORATION RAT! __ Slower than Bther VAPOR DENSITY -- Heavier than Air BOILING RANGB (F) , VOLATILB VOLUME liT/GAL 222 - 384 55-65 8,0-9.0 -----------...---------..-.--------.....-.-..---...--.....-----------..-..-..... Section IV -- rlRB AND· BZPLOSION HAZARD DATA -------------------------------------------------------------------------------- FLAMMABILITY CLASSIFICATION FLASH POINT 50 F PIICC LEL 0,5 RED LABEL __ Pla...ble, Plash below 100 r EXTINGUISHING MBOIA Cubon Dioxide, Dry Che.ical, Poa. UNUSUAL FIRI AND f;ZPLOSION HAZARDS Keep containers tilhtly dosed. Isolate fro. heat, .lectrical equipment, aparh, and open name. Closed containers .ay explode when exposed to extreme heat. Applleatlon to hot surfaces requires special precautions. Durinl emerlency condl tions overexposure to decolllposltlon producu lIIay cause a health hazard. Sympto.s .ay not be loedlately apparent. Obtain .edied attention. SPECIAL rIRB rIGHTING PROCEDURES Pull protective equlp.ent Includlnl self-contained breathine apparatus should be used. Vater spray ..y be ineffective. If vater is used, fOI nozzles are preferable. Vater may be used to cool dosed eontahers to prevent pre..ure build-up and possible autolrnition or explosion when exposed to exU... heat. Conti..cl CIJI ,.,. J I ACR-LL AcryUc Enamel, Lead Colon pa¡e 2 ---.---- --.------ ----- ---.--------------------------.....-............-......-.. Section V -- DEALTD DASARD DATA -------------------------------------------------------------------------------- THRESHOLD LIMIT VALUE -- See Section II EFFECTS OF OVEREXPOSURE ACUTE: In a confined are. vapon in hilh eoncentrarion .re an..theth. OVeru:po.ure..,. result in Ughtheadedneu and sta,gerin, ,ait. Irritant to skin and upper respiratory syste.. CflRONIC: Reports have associated repeated and prolonled overexposure to .oheota with permanent brain and nervous syste. dallale. Repeated and prolon,ed exposure to .pray .!at .., cau.. perforaUoa· of ..al septum and uleen of the skin. EMERGENCY AND FIRST AID PROCEDURES If INHALED: If affec:ted, remove fro. exposure. Reaton b~eathlna. Keep wan and quiet. If on SKIN: Vash affected area thoroulhl, vith soap and vater. Remove contaminated clothin. and launder before re-u.e. If in EYBS: Plush eyes vith larle a.ounts of vater for 15 .Inute.. Get medical attention. ~: ~!-/ ----------------- -- ----.-----.-.-------.--.---------...---....-....-............ Section VI -~ REACTIVIT! DATA -------------------------------------------------------------------------------- STABILITY -- Stable HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide, Oxides of Metab in Section II HAZARDOUS POLYMERIZATION -- Will Not Occur ------..------------------------------------------------------------...-.-....-.. Section VII -- SPILL OR LEAK PROCEOO.SS -------------------------------------------------------------------------------- STEPS TO BE TAKEN IN CASE PlATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. VentU.t. and rellove vith Inert ab.orbent. WASTE DISPOSAL "ETHOO Incinerate in approved facUity. Do not incinerate closed container. Dbpo.. of In acc:ordance vith Federal, State, and Local regulations reaardin, pollution. .----.------------------------------------------.--------------.....--.......... section VIII -- PROTBCTION INPO.RATIO. -------------------------------------------------------------------------------- PRECAUTIONS TO BE TAKEN IN USE Before initial use, consult OSHA's Standard for Oceupattonal Ixpolure to Lead (29 CPR 1910.1025). Use only vith adequate ventilation. Avoid breathin. vapor and .pn, .1It. &yold contact vith stin and eyes. \lash hands after ullna. Protec~ against haurdous dust or fuau vhich ..y be a.neratad by .anðinc, virebru.h1nc, abrading, burn in" brazing or veldin. of the dried fUa. VENTI LATION Local exhaust preferable. General exhaust acceptable If the exposure to ..tedab In Section II is maintained belov applicable exposure U.its. Refer to OSHA Standard. 1910.94, 1910,107, 1910,108, RESPIRATORY PROTECTION If penonal exposure cannot be controlled belov appUeabl. U.lts by ventUation, vear respiratory device approved by NIOSB/MSBA for protec~ion &pinst ..tedab In Section II. PROTECTIVE GLOVES !lear gloves vhich are recolllllended by «love suppUer for protection qalnat ..terial. 10 Sec:tion II. EYE PROTECTION \lear safety specta~les wi th unperforated s1de.hields. ~-...., Section IX -- PRECAUTIONS ACR-LL Acrylic Inallel, Lead Colors '&Ie' ---------.....----------------------...-------------.------------------------..-.. , ,--.--/1 -------------------------------------------------------------------------------- DOL STORAGE CATEGORY -- 18 PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Contents are FLAMMABLE. Keep avay froll heat, sparks, and open name. Durinl use and untU all vapors are lone: Keep area ventUated - Do not ..oke - Extinguish aU flames, pl10t lights, and heaten - Turn off !!toves, electric tooh and appliances. and any other sources of ignition. Consult NFPA Code. Use approved Bonding and Grounding procedures. Keep container closed when not In use. Transfer only to approved containers with co.pIeta and appropriate labellnø:. Do not take internally. Keep out of the reach of children. OTHER PRECAUTIONS This coatinl contains materials classified as nuisance particulates, for example titanium dioxide, CalciUII c:arbonate, etc. (see ACGIR TLV Lht, Prebee and Appendix 0), vhich msy be present at hazardous levels only during sanding or abradin. of the dried fU.. CONTAINS LEAD. Do not appl, on toys and other children's articles, furniture, or any interior surface of a dvelling or faeility which IISY be occupied or used by children. Do not apply on any exterior surfac:e of dwellinø: units, such as windov sills, porche., stain, or nHings to vhich children may be cOlll1llonly exposed. Intentional misuse by deUberately concentrating and inhaUnø the contenU can be har.ful or fatal. " \ ) ',------" 22 This Material Safety Data Sheet conforms to the Hazard Communication standard, 29 CFR 1910. 1200(g)( 4), for shlUar complex mixtures. The above informat1on pertains to this product as c.urrently formulated, and i. baaed on the information avaUable at this time. Addition of reducen or other additive. to this pro~lJct may substantially alter the composHlon and huards of the produc:t. Since conditlolUll of use are ou~s1de our control, we make no varrant1es, expreu or i.plied, and ..a.e no liabUity in connection vith any use of this infor.ation. ...:-. t:; .. ,,' ,../. - ;.;. 'r' ., .,::;- -- e General Offices/3M 3M Center St. Paul, Minnesota 55144-1000 (612) 733-1110 . e i \J MATERIAL SAFETY 3M DATA SHEET DIVISION: ADHESIVES. COATINGS AND SEALERS TRADE NAME: UNDERSEAL(R) Rubberized Undercoating (P.N. 08883 ) 3M 1.0. NUMBER: 62-5814-4919-6 ISSUED: JANUARY 7. 1986 SUPERSEDES: OCTOBER 2. 1985 DOCUMENT: 10-0194-0 ------------------------------------------------------------------------- ------------------------------------------------------------------------- 1. INGREDIENTS C.A.S. NO. PERCENT EXPOSURE LIMITS ------------------------------------------------------------------------- ------------------------------------------------------------------------- synthetic rubber N/A N/A 5 wood rosin derivatives N/A N/A 5 talc N/A N/A 5 curatives N/A N/A 5 TOTAL OF THE ABOVE N/A 37.0- 39.0 N/A 5 hexane* N/A 20.0- 22.0 500 ppm 1 *contains minimum 44% n-hexane 1l0-54-3 16.0- 18.0 50 ppm 1 propane 74-98-6 14.0- 16.0 1000 ppm 2 asphalt 8052-42-4 7.0- 9.0 5 mg/m3 1 carbon blàck 1333-86-4 0.5- 1.5 3.5 mg/m3 1 ',-. SOURCE OF EXPOSURE LIMIT DATA: 1. ACGIH Threshold Limit Values 2. Federal OSHA Permissible Exposure Limit 3. 3M Exposure Guidelines 4. Chemical Manufacturer Recommended Guidelines S. None Established ABBREVIATIONS: N/O - Not Determined N/A - Not Applicable ------------------------------------------------------------------------- ------------------------------------------------------------------------- 2. PHYSICAL DATA ------------------------------------------------------------------------- ------------------------------------------------------------------------- BOILING POINT: VAPOR PRESSURE: VAPOR,DENSITY IAir=I): EVAPORATION RATE IEther=l): APPEARANCE AND ODOR: SOLUBILITY IN HATER: SP. GRAVITY (Hater=I): PERCENT VOLATILE: VISCOSITY: pH: Compressed Gas Compressed Gas 2.97 1.9 Black. solvent odor Nil <1 Approx. 62% N/A N/A \~) ,. . General Officesl 3M Center St. Paul, Minnesota 55144·1000 (612)733·1110 ., - ;ji' ''- .. , \ , '-, ì } MATERIAL SAFETY DATA SHEET 3M HSDS: UNDERSEALCR) Rubberized Undercoating (P.N. 08883) JANUARY 7, 1986 Page 2 ========================================================================= 3. FIRE AND EXPLOSION HAZARD DATA ========================================================================= FLASH POINT IC.C. - Propane): FLAMMABLE LIMITS - LEL: 1.2 -50F UEl: 6.9 EXTINGUISHING MEDIA: C02, foam, dry chemical SPECIAL FIRE FIGHTING PROCEDURES: Treat as pressurized container. Fire fighters should be equipped with self-contained breathing apparatus when fighting fires involving this material. Keep stacked containers, adjacent to fire, cool. UNUSUAL FIRE AND EXPLOSION HAZARDS: Extremely Flammable. Treat as a pressurized container. Pressurized containers can explode when overheated. ------------------------------------------------------------------------- ------------------------------------------------------------------------- ~. REACTIVITY DATA ------------------------------------------------------------------------- ------------------------------------------------------------------------- -- STABILITY: STABLE INCOMPATIBILITY MATERIALS TO AVOIO: N/A CONDITIONS TO AVOID: Do not store at temperatures above 120F. HAZARDOUS POLYMERIZATION: MAY NOT OCCUR HAZARDOUS DECOMPOSITION PRODUCTS: CO, C02. HCl and possible traces of chlorine and phosgene when subjected to excessive heat or flame. ------------------------------------------------------------------------- ------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ------------------------------------------------------------------------- ------------------------------------------------------------------------- SPILL' RESPONSE: Observe all precautions in Section 7. If any cans rupture, extinguish all ignition sources and ventilate the area. Use absorbent material as needed in cleanup procedure. Place cans in an approved U.S. Department of Transportation container. RECOMMENDED DISPOSAL: Do not puncture or burn cans in household incinerator. Incinerate in permitted hazardous Haste facility that can handle aerosol cans safely. U.S. EPA Hazardous waste Number: D001 (IGNITABLE). ENVIRONMENTAL DATA: N/D i / '---' .. .. e General Offices/3M 3M Center St. Paul, Minnesota 55144-1000 (612) 733-1110 . It " " ,\ - \~.~:;., ~ '--' ,¡ ; MATERIAL SAFETY DATA SHEET 3M HSDS: UNDERSEALCR) Rubberized Undercoating (P.N. 08883) JANUARV 7, 1986 Page 3 ========================================================================= 6. SUGGESTED FIRST AID ======================================================:=:=::===z:=::::=== EVE CONTACT: Flush immediately with plenty of water for at least 10 minutes and call a physician. SKIN CONTACT: Hash affected area with soap and water. INHALATION: Provide fresh air. If,breathing is difficult provide oxygen and call a physician. IF SHALLOHED: Do not induce vomiting. Call a physician immediately. If spontaneous vomiting should occur, lower victim's head between the knees to prevent aspiration into the lungs. ------------------------------------------------------------------------- ------------------------------------------------------------------------- 7. PREèAUTIONARV INFORMATION ------------------------------------------------------------------------- ------------------------------------------------------------------------- Keep product and its vapors away from heat, sparks and flames. Extinguish and do not ignite any flame in the immediate work area. Do not use in confined areas or areas with little or no air movement unless you employ means to circulate air and prevent vapor buildup. Avoid breathing vapor and overspray (airborne adhesive particles). Prevent eye and skin contact. Keep out of the reach of 'children. NOTE: Use protective equipment where possible, i.e. safety glasses and gloves. Local exhaust ventilation should be used if large quantities are sprayed in e short. period of time. "-/ ,," . -- General Offices/3M 3M Center St. Paul, Minnesota 55144-1000 (612) 733-1110 .. e .#.~ :. \ I \ , ·'-.....--F ;1 ,I HATE RIAL SAFETY DATA SHEET 3IVI HSDS: UNDERSEALlR) Rubberized Undercoating (P.N. 08883) JANUARY 7, 1986 Page 4 ========================================================================= 8. HEALTH HAZARO DATA ------------------------------------------------------------------------- ------------------------------------------------------------------------- EYE CONTACT: Hay cause irritation. SKIN CONTACT: Hay cause irritation. liquid may be absorbed through the skin. INHALATION: Hay cause respiratory tract irritation. Inhalation of vapor concentrations above the permissable limit may cause respiratory system irritation and temporary nervous system impairment. Symptoms include dizziness, fatigue, nausea, headache, facial numbness. Repeated or extreme overexposure to n-hexane may cause nervous system damage. "--.-.- INGESTION: Hay cause gastrointestinal irritation. Symptoms include nausea, vomiting, diarrhea. Aspiration into the lungs through vomi ting may cause lung damage. .., ------------------------------------------------------------------------- ------------------------------------------------------------------------- The information on this Data Sheet represents our current data and best opinion as to the proper use in handling of this product under normal conditions. Any use of the product which is not in conformance with this Data Sheet or which involves using the product in combination with any other product or any other process is the responsibility of the user. ., - MATERIAL SAFETY DATA SHEET FOR COATINGS, RESINS, AND RELATED MATERIALS . . R-M ',,-. Section I Products 12-20-84 DATE OF PREP. MANUFACTURER'S NAME Inmont Corporation STREET ADDRESS 6125 Industrial Parkway, P.O. Box 2757 CITY, STATE, AND ZIP CODE Whitehouse, Ohio 43571 EMERGENCY TELEPHONE NO.. (419) 877-5308 or (201) 365-3512 PRODUCT CLASS MANUFACTURERS CODE IDENTIFICATION TRADE NAME 852 Universal Hand Rubbing Compound Section" - HAZARDOUS INGREDIENTS ! \ '--- TLV VAPOR INGREDIENT PERCENT LEL PRESSURE By Weight PPM mg/M' mmHg Silica (60676-86-0) 40-50 20 mp pc -- -- Kerosene (8008-20-6) 20 200 N/A 1.0- 0.1 " : , , , Section III - PHYSICAL DATA BOILING RANGE (EstlmateCl) Unknown VAPOR DENSITY ~ HEAVIER o LIGHTER, THAN AIR EVAPORATION RATE o FASTER ~ SLOWER, THAN ETHER PERCENT VOLATILE BY VOLUME > 5 0 WEIGHT PER GALLON 10 1bs. Section IV - FIRE AND EXPLOSION HAZARD DATA FLAMMABILITY CLASSIFICATION, C ombu s t i b 1 e I I I B FLASH POINT Non e LEL See Section II. EXTINGUISHING MEDIA Foam - Carbon Dioxide - Chemical Powder UNUSUAL FIRE AND EXPLOSION HAZARDS Keep container tightly closed. Avoid heat, open flames, static electricity, electrical equipment and sparks. Closed containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency situation, over-exposure to decomposition products may cause a health hazard with no symptoms Immediately apparent. Obtain medical attention. , . "- SPECIAL FIRE FIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be Ineffective, If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible auto Ignition or explosion when exposed to extreme heat. SR-214S 1& .INÌM.~ -~ ) . - ---- ,I: e e , , Section V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE See Section II. EFFECTS OF OVEREXPOSURE ACUTE: Inhalation - Anesthetic. Irritation of respiratory tract or acute nervous system depression characterized by the following progressive steps: Headache, dizziness, staggering gait, confusion, unconsciousness or coma. Skin or Eye Contact - Primary Irritation. EMERGENCY AND FIRST AID PRocmURES Vapor Inhalation - Restore breathing. Remove to fresh air. Keep warm and quiet. Notify a physician. Eye Contact - Flush Immediately with copious amounts of running water for at least 15 minutes. Take to physician for definitive medical treatment. Skin contact - Clean and wash affected area with water. Consult a physician. Section VI - REACTIVITY DATA STABILITY o UNSTABLE CONDITIONS TO AVOID Heat, open flames, electrical and static discharge. ~ STABLE INCOMPATIBILITY (Materials to avoid) Strong acid, alkalies, 8. oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS Unknown other than CO2 and possibly CO and carbon smoke. HAZARDOUS POL YMERIZA TION CONDITIONS TO AVOID o MAY OCCUR ~ WILL NOT OCCUR Section VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Ventilate area. Remove all possible sources of Ignition. Avoid prolonged breathing of vapors. Confine spill with Inert àbsorbent and clean up with spark-proof tools. WASTE DISPOSAL METHOD Dispose of In accordance with local, state, 8. federal regulations. Land fill or Incinerate In approved facility by licensed contractor. Do not Incinerate In closed container. Section VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION Use NIOSH/MSHA TC23C Chemical/Mechanical type filter system to remove a combination of particles, gas, 8. vapor. Use air line If necessary. VENTILATION Use adequate ventilation In volume and pattern to keep LEL and TLV's In Section II below recommended level to produce explosion or fire. General mechanical ventilation should comply with OSHA 1910.94. PROTECTIVE GLOVES To prevent prolonged exposure, use rubber gloves. EYE PROTECTION Safety glasses or goggles with splash guards or side shields. OTHER PROTECTIVE EQUIPMENT Prevent prolonged skin contact to contaminated clothing. Section IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Do not store over 120QF, When storing large quantities, store In building designed and protected against flammable liquids. Use static lines when mixing and transferring material. Do not allow material to free fall more than five (5) Inches. OTHER PRECAUTIONS "FOR INDUSTRIAL USE ONLY." Do not take Internally. If Ingested, DO NOT Induce vomiting - Consult a physician. Do not flame cut, weld, or braze on coated metal without a NIOSH/MSHA TC23C respirator. THE INFORMATION CONTAINED HEREIN IS BASED ON TECHNICAL DATA WHICH WE BELIEVE TO BE RELIABLE. HOWEVER, SINCE THE CONDITIONS UNDER WHICH THIS INFORMATION MAY BE APPLIED ARE BEYOND OUR CONTROL, WE CAN ASSUME NO LIABILITY FOR RESULTS OF ITS APPLICATION, THIS INFORMATION SHOULD BE USED ONLY BY PERSONS HAVING SUFFICIENT TECHNICAL SKILL TO MAKE INFORMED JUDGEMENTS REGARDING ITS APPLICATION, ~"_01__'''~ ~Æ-? ",', " . ) "'¥ ,:,{ .: í ./ ," 1 ~ ..,.- e . e -Í" ~ MATERIAL SAFETY DATA SHEET SECTION I ~- PRODUCT NAME OR NUMBER (AS IT APPEARS GROW SUPER KLEANTM #1705 GREASE, ON LABEL) WAX AND SILICONE REMOVER I EMERGENCY TELEPHONE NO., ' 313 - 643-4600 MANUFACTURER'S" NAME . GROW GROUP, INC. ADDRESS (NUMBER, STREET, CITY, STATE AND ZIP CODE) 3155 WEST BIG BEAVER ROAD, SUITE 200 P.O. BOX 7026, TROY, MICHIGAN 48007-7026 MANUFACTURER'S D-U-N-S NO. 00-532-0551 HAZARDOUS MATERIALS DESCRIPTION, PROPER SHIPPING NAME, HAZARD CLASS ID NO. PAINT RELATED MATERIAL NA-1263 ADDITIONAL HAZARD CLASSES (AS APPLICABLE) FLAMMABLE LIQUID CHEMICAL FAMILY SOLVENT BLEND IFORMULA SOLVENT BLEND SECTION II - INGREDIENTS I EXPOSURE LIMITS IN AIR LISTED AS A" CAS (UNITS IN PPM) CARCINOGEN REGISTRY NO. I CHEMICAL NAMES IN NTP IARC ACGIH OSHA VENDOR OR OSHA 1910 64742-49-0 I GS-295 HYDROCARBON PETROLEUM 300 500 400 NO I DISTILLATE OR NAPHTHA 64742-47-8 I GS-380 HYDROCARBON PETROLEUM 100 500 100 NO I DISTILLATE OR NAPHTHA 67-63-0 I ISOPROPYL ALCOHOL 400 400 400 : NO 108-88-3 I TOLUOL 100 100 100 NO I '"T, I I I I '''_.' '~"J '·1 ~ i'" ". ~ .. . ~ ,.-, -- - -., e ... \. " SECTION III - PHYSICAL DATA BOILING RANGE· 179-338 XX OF VAPOR PRESSURE 41.4 @ 68°, °c XX MM HG VAPOR DENSITY (AIR-l) 3.75 °c SPECIFIC GRAVITY (H20-I) 0.7603 PERCENT VOLATILE BY VOLUME 100% PERCENT SOLID BY WEIGHT 0% IEVAPORATION RATE SLOWER THAN ETHER PH NOT APPLICABLE t<_/ PSI SOLUBILITY IN WATER 6% APPEARANCE AND ODOR WATER WHITE LIQUID IS MATERIAL: LIQUID XX SOLID GAS PASTE POWDER SECTION IV - FIRE AND EXPLOSION HAZARD DATA METHOD USED I LEL UEL FLASH POINT 43 OF °c T.C.C. FLAMMABLE LIMITS 0.9% 12% EXTINGUISHING MEDIA CO2, DRY CHEMICAL, FOAM, OR OTHER NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) APPROVED METHOD FOR TREATING A CLASS B FIRE. SPECIAL FIRE FIGHTING PROCEDURES SUMMON PROFESSIONAL FIREFIGHTERS. USE FULL PROTEC- TIVE EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS. WATER SPRAY MAY BE INEFFEC- TIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. IF EXPOSED TO FIRE OR EXTREME HEAT, _/ WATER SHOULD BE USED TO COOL CLOSED CONTAINERS AND PREVENT PRESSURE BUILD-UP OR POSSIBLE AUTO-IGNITION. UNUSUAL FIRE AND EXPLOSION HAZARDS KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND FLAME. VAPORS MAY CAUSE FLASH FIRE. VAPORS MAY IGNITE EXPLOSIVELY, VAPORS MAY SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. DUE TO PRESSURE BUILD-UP, CLOSED CONTAINERS EXPOSED TO EXTREME HEAT MAY EXPLODE. NEVER USE A WELDING OR CUTTING TORCH ON OR NEAR CONTAINER (EVEN EMPTY) AS PRODUCT OR ITS RESIDUE MAY IGNITE. DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION. . SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE PERMISSIBLE EXPOSURE LIMIT 100 PPM (ACGIH) 100 PPM OTHER LIMIT lOa PPM (OSHA) lOa PPM (VENDOR) EFFECTS OF OVEREXPOSURE· ACUTE - BREATHING- IRRITATION OF THE RESPIRATORY TRACT; HEADACHE, NAUSEA, DIZZINESS, WEAKNESS AND FATIGUE. EXTREME EXPOSURE CAN RESULT IN UNCON- SCIOUSNESS AND EVEN RESPIRATORY ARREST. EYE CONTACT - SEVERE IRRITANT. SKIN CONTACT - PROLONGED AND REPEATED LIQUID CONTACT CAN CAUSE DEFATTING AND DRYING OF SKIN, WHICH MAY RESULT IN SKIN IRRITATION AND DERMATITIS. SWALLOWING - VOMITING MAY RESULT. PULMONARY ASPIRATION HAZARD IF VOMITING OCCURS. CHRONIC: REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. PRIMARY ROUTES OF ENTRY INHALATION, SKIN CONTACT, SWALLOWING. ~, ~ .. e ~ ,. .. . - ¡;' ...if ,., , EMERGENCY AND FIRST AID PROCEDURES IF BREATHED - IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, SUMMON MEDICAL ASSISTANCE IMMEDIATELY. IF BREATHING CEASES, RESTORE USING APPROVED CPR TECHNIQUES AND SUMMON MEDICAL ASSISTANCE IMMEDIATELY. IF IN EYES - FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ASSISTANCE. IF ON SKIN - WASH AFFECTED AREAS WITH SOAP AND WATER. REMOVE SOILED CLOTHING. GET MEDICAL ASSISTANCE IF IRRITATION PERSISTS. WASH CLOTHING BEFORE REUSE. IF SWALLOWED - DO NOT INDUCE VOMITING. CONSULT A PHYSICIAN IMMEDIATELY. ASPIRATION OF VOMITUS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. MEDICAL CONDITIONS PRONE TO AGGRAVATION BY OVEREXPOSURE NONE WHEN USED IN ACCORDANCE WITH SPECIAL PROTECTION INFORMATION (SECTION VIII). WARNING:, INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS KAY BE HARMFUL OR FATAL. , , SECTION VI - REACTIVITY DATA . , STABILITY I CONDITIONS TO AVOID HEAT, SPARKS, FLAME. I UNSTABLE STABLE XX INCOMPATIBILITY (MATERIALS TO AVOID) HAZARDOUS DECOMPOSITION PRODUCTS AND CARBON DIOXIDE. HAZARDOUS I MAY OCCUR POLYMERIZATION WILL NOT OCCUR STRONG OXIDIZING AGENTS. THERMAL DECOMPOSITION MAY YIELD CARBON MONOXIDE XX CONDITIONS TO AVOID NOT APPLICABLE '---- SECTION VII- SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, AND ELECTRICAL, STATIC OR FRICTIONAL SPARKS). DO NOT SMOKE. PREVENT BREATHING VAPORS. VENTILATE AREA. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZARD CAUTION INFORMATION IN OTHER SECTIONS OF THIS MATERIAL SAFETY DATA FORM. DIKE AND CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. STORE IN CLOSED CONTAINER UNTIL PROPERLY DISPOSED OF. WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULA- TIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS. CERCLA (SUPERFUND) REPORTABLE QUANTITY (IN LBS) ONE POUND OR REFER TO SECTION 311 CLEAN WATER ACT. RCRA HAZARDOUS WASTE NO. (40 CFR 261.33) D-OOI, F-005 THINNER BLEND ONLY. VOLATILE ORGANIC COMPOUND (VOC) (AS PACKAGED, MINUS WATER) XX THEORETI CAL 6 . 313 LB / GAL XX NOTE: , ,NUMBERS APPLY TO ANALYTICAL 100% 6.330 LB/GAL .~ ~ '. ... e ..: . e ;~ '~ , SECTION VIII - SPECIAL PROTECTION INFORMATION t~ RESPIRATORY PROTECTION WHEN USED IN RESTRICTED VENTILATION AREAS, WEAR NIOSH/MSHA APPROVED CHEMICAL/MECHANICAL FILTERS DESIGNED TO REMOVE A COMBINATION OF PARTICULATES AND VAPOR. WHEN USED IN CONFINED AREAS, WEAR NIOSH/MS~A'APPROVED AIR SUPPLY RESPI~TORS OR HOODS. FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS"FOR RESPIRATOR USE. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE ESTABLISHED TO ASSURE COMPLIANCE WITH,OSHA STANDARD 29 CFR 1910.134. . VENTILATION USE ONLY WITH ADEQUATE VENTIL~TION. USE EITHER LOCAL EXHAUST OR MECHANICAL. TO MEET TLV REQUIREMENTS. VENTILATION MUST BE SUFFICIENT 1'0 LIMIT EMPLOYEE EXPOSURE AT, OR BELOW, OSHA TLV LIMIT. -HEAVY SOLVENT VAPORS SI)9U~D- BE REMOVED FROM LOWER LEVELS OF WORK AREA. PROTECTIVE GLOVES NEOPRENE OR EQUIVALENT. EYE PROTECTION SOLVENT RESISTANT SAFETY EYEWEAR WITH SPLASH GUARDS. OTHER PROTECTIVE EQUIPMENT EYE BATH AND SAFETY SHOWER. SOLVENT IMPERMEABLE CLOTHING TO PREVENT SKIN CONTACT. , '. SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING KEEP AWAY FROM HEAT, SPARKS AND FLAME. DO NOT SMOKE. EXTINGUISH ALL PILOT LIGHTS AND TURN OFF ALL SOURCES OF IGNITION INCLUDING HEATERS, FANS AND OTHER NON-EXPLOSION-PROOF ELECTRICAL EQUIPMENT, DURING USE AND UNTIL ALL VAPORS ARE GONE. VAPORS MAY IGNITE EXPLOSIVELY. VAPORS MAY SPREAD LONG DISTANCES AND BEYOND CLOSED DOORS. PREVENT BUILD-UP OF VAPORS BY MAINTAINING CONTINUOUS FLOW OF FRESH AIR. DO NOT STORE ABOVE 120°F OR NEAR FIRE OR OPEN FLAME. STORE LARGE QUANTITIES IN BUILDINGS TO COMPLY WITH OSHA 1910.106. KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELED CONTAINERS. DO NOT REUSE EMPTY CONTAINERS. KEEP OUT OF REACH OF CHILDREN. , , NAME ~ S~ SIGNATURE TITLE LABORATORY MANAGER DATE APRIL 25 , '1987 ", THE INFORMATION CONTAINED HEREIN IS BASED ON DATA BELIEVED BY GROW GROUP, INC. TO BE ACCURATE. BUT WE DO NOT ASSUME ANY LIABILITY FOR THE ACCURACY OF THIS INFORMATION. WE NEITHER SUGGEST NOR GUARANTEE THAT ANY HAZARDS MENTIONED ARE THE ONLY ONES WHICH EXIST. ANYONE INTENDING TO RELY ON ANY RECOMMENDATION OR TO USE ANY EQUIPMENT, TECHNIQUE OR MATERIAL MENTIONED SHOULD ALSO SATISFY HIMSELF THAT HE CAN MEET ALL APPLICABLE SAFETY AND HEALTH STANDARDS. DETERMINATION OF THE SUITABILITY OF ANY INFORMATION OR PRODUCT FOR THE USE CONTEMPLATED BY ANY USER, THE MANNER OF THAT USE AND WHETHER THERE IS ANY INFRINGEMENT OF PATENTS. IS THE SOLE RESPONSIBILITY OF THE USER. '-- / Coca-Cola Enterprises-West 1334 South Central Avenue Los Angeles, CA 90021 213 746-5555 ~ .' ... ...;,(:;)', - ..'~g System pc r: f.' nn= n . '......-, January 13, 1989 EMERGENCY NOTIFICATIONS .IAN 20 1989 Ao"dl........... Bakersfield City Fire Department 2130 "G" Street Bakersfield, CA 93301 Please amend the Hazardous Materials Business Plan submitted to your department as follows: Section 2: A. Gene Hanson Busine.ss Residence Branch Manager (805) 324-6531 (805) 835-1829 If you have any further questions, please call me in Los Angèles at (213) 746-5555 extension 4455. Sincerely, ~,~.ToJ/lk~ J. E. Todd Manager, Industrial and Environmental Safety JET:mk "' "', . J ~~~~:-~~-~-..--.",,-=- "-"-----~ ,'-:.?.---.....-_~--- ~. ~ I . \\ú~~ / _ ~ ð ~;:'::{~ú;~:'!!~ CITY of BAKERSFIELD LV ()~!;~~ (\ ~\\:=: ., IV E C.-l R E " 93 _ 60 -::X;7, :::~. -- , ~...' jI / ~.."'..., ~ ,J ~--- - , \., " ~ A (!,.¿ ,;ø1/iLcL/' ,Jð1iÍíiW . "" . ~.;;¡ ,./""W-t',. ,····o~ '. .,e. ~-S'i- .' .... . - ,...\. /,.... --:, ~\.\ , f... . . (', iG =-,-J...A,~ d'¡) \\' ~~¡\" ',\('..",' . .'. '.J ::1{ìl-o.'ß~'.;; ".~ (tYDe or print name) P F (' r: \\1 £. 0 t E~· 0 'L '989 the ~ns·Q...········· Doh ere b y c e r t i f y t hat I h a "\' ere'v i e \,' e d attached Hazardous Materials business plan for ~ú&A ;t~hØ~,P> (n ¡e of business) and that it along with the attached additions or corrections constitute a complete and correct " facility. ;µ~#j I ate - .1 I --- ~--.... í I i There is no change in materials or procedures. \~--- ....- 1 Everything remains the same...... \-- . t}i'fl, ~~~ BUSINÈSS NAME CLYDES CUS~ SHOPPE LOCATION i4§ YNI~N AV e ID NUMBER 215-000-000680 HIGH HAZARD RATING 3 1. OVERVIEW LAST CHANGE 06/23/88 BY TERRY JURIS CODE 215-006 JURIS BAKERSFIELD STATION 06 MAP PAGE 103 GRID 32C FACILITY UNITS 1 HAZARD RATING 3 RESPONSE SUMMARY 2A SEC 4: PRIVATE RESPONSE: CLYDE CRAWFORD & TONY RICHARDSON THE ABOVE INDIVIDUALS ARE RESPONSIBLE TO CALL IN HELP FROM OUTSIDE AGENCY AND TO CONTAIN SPILLS AND ADMINISTER FIRST AID. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PREVENT SPREADING. PUMP LIQUID TO SALVAGE TANK. USE VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL TO ABSORB LIQUID. DISPOSE OF IN ACCORDANCE TO REGULATIONS. EMERGENCY CONTACTS 2A SEC 2: CLYDE CRAWFORD, OWNER 323-0005 OR 831-3821 PAT CRAWFORD, SPOUSE 327-7171 OR 831-3821 UTILITY SHUTOFFS 2A SEC 3: A) GAS - NW OUTSIDE WALL OF CLYDES CUSTON; B) ELECTRICAL : W WALL INSIDE UTILITY ROOM NEXT TO MEN'S RESTROOM ACROSS FROM OFFICE; C) WATER - APPX. 100 FT S 7TH AND 2ND STREET INTERSECTION ON SIDE OF FENCE. D) SPECIAL - NONE; E) LOCK BOX - NO. 2. NOTIFICATION / PUBLIC EVACUATION LAST CHANGE / / BY < NO INFORMATION RECORDED FOR THIS SECTION > PAGE 1 MATERIAL SAFETY DATA SYSTEMS, INC. (805') 648-6800 12/28/88 11:59 ';~-'-i;:-;~;_~~~'~·-:·-_~;·~:~:;-'.}·0":,~· --,:~ . ,:~.".-;~~~ ~. : ," --... .--;-::-':" '. ì'~~, " -.rt... BUSINESS NAME CLYDES CUSTOM SHOPPE LOCATION 149 UNION AV ID NUMBER 215-000-000680 HIGH HAZARD RATING 3 3. HAZ MAT TRAINING SUMMARY LAST CHANGE / / BY < NO INFORMATION RECORDED FOR THIS SECTION > 4. LOCAL EMERGENCY MEDICAL ASSISTANCE LAST CHANGE 06/23/88 BY TERRY 2A SEC 5: MERCY HOSPITAL - 2215 TRUXTUN AVENUE - 327-3371 BAKERSFIELD FAMILY MEDICAL CENTER - 4580 CALIFORNIA AVE - 327~4411 PAGE 2 12/28/88 11:59 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 e e '. BUSINESS NAME LOCATION FACILITY UNIT CLYDES CUS" 149 UNION AV 01 SHOPPE e ID NUMBER 215-000-000680 HIGH HAZARD RATING 3 A. OVERALL HAZARDOUS MATERIALS INVENTORY LAST CHANGE 06/23/88 BY TERRY ID TYPE NAME MAX AMT UNIT HAZARD LOCATION CONTAINMENT USE 1 MIXTURE ENAMEL 94 GAL EXTREME SHOP METAL CONTAINERS PAINTING ID PERCENT COMPONENTS HAZARD LISTS I 1118.00 40.0 XYLENE, MIXED HIGH I 1130.00 10.0 TOLUENE HIGH 1168.00 5.0 n-BUTYL ACETATE HIGH 1203.00 5.0 NAPHTHA EXTREME 2291.00 5.0 WASTE ACIDS UNKNOWN 2 MIXTURE THINNER 100 GAL HIGH SHOP METAL CONTAINERS PAINTING ID PERCENT COMPONENTS HAZARD LISTS 1006.00 30.0 ACETONE HIGH 1120.00 20.0 TRICHLOROETHYLENE HIGH 2465.01 10.0 PROPANOL UNKNOWN 1168.00 10.0 n-BUTYL ACETATE HIGH 1118.00 5.0 XYLENE, MIXED HIGH 1145.00 5.0 METHANOL HIGH B. FIRE PROTECTION / WATER SUPPLIES LAST CHANGE 06/23/88 BY TERRY 3A SEC 4: FIRE HYDRANT LOCATED AT THE NORTHEAST CORNER OF 2ND STREET AND V STREET. FIRE EXTINQUISHERS LOCATED THROUGHOUT THE BUILDING WITH APPROPRIATE MARKINGS. 3A SEC 5: FIRE HYDRANT LOCATED AT THE NORTHEAST CORNER OF 2ND STREET AND V STREET. PAGE 3 12/28/88 11:59 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 BUSINESS NAME CLYDES CUSTOM SHOPPE LOCATION 149 UNION AV ID NUMBER 215-000-000680 HIGH HAZARD RATING 3 D. EMPLOYEE NOTIFICATION / EVACUATION LAST CHANGE 06/23/88 BY TERRY 3A SEC 2: VERBALLY NOTIFY CUSTOMERS AND EMPLOYEES ON THE PA SYSTEM. CALL 911 HAVE ALL PEOPLE ASSEMBLE IN THE SOUTH CUSTOMER PARKING AREA. Eo MITIGATION / PREVENTION / ABATEMENT LAST CHANGE 06/23/88 BY TERRY 3A SEC 1: PROPER CONTAINERS, VALVES AND PROPER HANDLING AND STORAGE OF HAZARDOUS MATERIAL. NO SMOKING SIGNS POSTED IN APPROPRIATE AREAS. REFER TO MSDS SHEETS FOR CLEANUP AND MEDICAL ATTENTION. CALL OUTSIDE HELP ON SERIOUS PROBLEMS. PAGE. 4 12/28/88 11:59 MATERIAL SAFETY DATA SYSTEMS, INC. (805) 648-6800 ~ e e I . , I I I .I · J .o¡tll ~-fll . .. ....1 . :~ ,.;. ··J..."\~~L;..·;{· ," . . :~::. , ' -. I '. _.:....._,._-_.._._-_.__._-_..__..-l..-__.__......--.~; :i{':;,,;~'-' ,,' " f +.$ IV rl,cL ¿'.4t/E }~: I . /Ý ',. ';';"".~ (. . . ---"-', f\ J.r:,1( Ir~1~ -,-".-- ""-~'--r'ðÕÕR--'-T""t'JJ\,,~ ' 1 ·\1·...ó·'·) . I . ¡to. .. I '.. :,j! · ..¡¡. . . '::'-!'-" - <'1 I r ~,J...., .' , U"4 . , ....,,( (', \"':, " 10. '\.) t·. \ \, "-\' , . \ : . \./ '~ fj':,J')~1'i' .""'--- ~! " ~ . f::;,;';': : .f--...u...__-.:.-~__ . cJ 1/ t> 5T!:E Er ......... . ". "'-. . . . ',.; ':J'. ," ",. ." ( I ," o '.'~". .:û~:· C £, y () ~,5 "'"~ ' .,. ~ 't. '. ,.,. (1) 5 (ON\ \-". ,1>:. -"I ... ~ ' f....j .... 0..··; ø :~ ~ ., .~ ~ 'ûooQ '. -1 "'. i , i . I ~ " . · . . '. ." .. '. . ."', .'. '., .. .;,;'...·:~:~'~"e.~,'...·~';;~·,4;:·......, ~ :' .- - ,," ,- ." "~:', . '. . - (' .....: -. _.~.' .. . , {or, ....~...:- ..., .. "- p ~ '¡ '. ~ ..... ,\\Q f\ ~_..,.~ I --! ~@@~ O~~Gi~~a, C-I yd~? Cus+o~ ~ hofP<e- 14'1 Un (0/\ Âv: 08° - IvtSf Co