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Home My WebLink AboutBUSINESS PLAN 1994 Overall Site with 1 Fac. Unit ~ ~]994 Location: 920 34TH ST ~ ~ Map: 103 Hazard: Moderate Com~unity: BAKERSFIELD 'STATION 04 Grid: 19C F/U: 1AOV: 0 0 PHIL GARNER MANAGER (805) 393-0963! ASST. MANAGER (805) 323-9071 x (805) 631=1321] [ ~..~.E FRENCH'- (805) 323-9071 x ---------- Administrative Data Mail Addrs: 920 34TH ST D&B Number: City: BAKERSFIELD State: CA Zip: 93301- Comm Code: 215-004 BAKERSFIELD STATION 04 SIC Code: Owner: CHARLES FENLEY ENTERPRISES Phone: (805) 323-9071 Address:"~1121 0AKDALE ROAD SUITE 7 (209)577-1850 State: CA City: MODESTO Zip: 95355- Summary OTHER CONTACTS: MIKE FENLEY (209) 577-1850 (209) 529-2202 LEE GARNER (209) 577-1850 (209) 521-8581 I, L E E GA R N E R ' ', Do hereby certi~ that ! have reviewed the attached hazardous material6 manage- ment plan for A B 0 V E ,and that it along with (Name of BUsineu) any corrections constitute a complete and correct man- agement plan for my facility. ~ MARCH 1994 / ~ Signature Date BAKERSFIELD .02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 2 Hazmat Inventory List in MCP Order 02 - Fixed Containers on Site Pln-Ref Name/Hazards Form Max Qty MCP 02-002 CAL SODA JO 303 Liquid 55 Extreme · I~m~ed Hlth, Delay HlthGAL 02-014 UNION CARBIDE ACETYLENE Gas 112 High · Fire, Pressure, In~med Hlth FT3 02-005 AMMONIA SOLUTION Liquid 330 Moderate · Immed Hlth GAL 02-001 CHEVRON SUPREME Liquid 12000 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-004 MINERAL SPIRTS SOLVENT Liquid 55 Moderate · Fire GAL 02-003 HEAVY DUTY WHITEWALL CLEANER Solid 900 Moderate · Immed Hlth LBS 02-006 CHEVRON UNLEADED GASOLINE Liquid 12000 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-007 CHEVRON UNLEADED PLUS GASOLINE Liquid 12'000 Moderate · Fire, Immed Hlth, Delay Hlth GAL 02-008 WHITE POWDERED DEGREASER Solid 900 Moderate · Immed Hlth, Delay Hlth LBS 02-009 HEAVEY DUTY COMPOUND Solid 900 Moderate · Reactive, Immed Hlth, Delay Hlth LBS 02-010 USC HIGH SUDS 3Liquid 220 Moderate · Immed Hlth, Delay Hlth GAL 02-011 USC SPPED OFF Liquid 220 Moderate · Immed Hlth, Delay Hlth GAL 02-016 AQUA AMMONIA Liquid 55 Moderate · Immed Hlth GAL 02-017 BLUE FOAMING CONDITIONER Liquid 55 Moderate · Immed Hlth, Delay Hlth GAL 02-018 CHERRY WAX Liquid 55 Moderate · Immed Hlth, Delay Hlth GAL 013 UNION CARBIDE OXYGEN Gas 150 Low · Fire, Immed Hlth, Delay Hlth FT3 02-012 AW68 HYDRAULIC OIL Liquid 55 Unrated · Delay Hlth GAL 02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 3 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-002 CAL SODA JO 303 : Liquid 55 Extreme ~ Immed Hlth, Delay Hlth GAL CAS #: 7664-93-9 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: ETCHING Daily Max GAL Daily Average GAL Annual Amount GAL -.. 55 I 20.00 T 100.00 Storage Press T Temp Location DRUM/BARREL-NONMETAL IAmbientlAmbientlEXTERIOR NW FENCED AREA --C°ncI Components i MCP ----TGuide 20.0% Sulfuric Acid, Spent High ! 39 14.0% Hydrofluoric Acid Extreme I 15 02-014 UNION CARBIDE ACETYLENE Gas 112 High ~ Fire, Pressure, Immed Hlth FT3 CAS #: 74-86-2 Trade Secret: No .. Form: Gas Type: Pure Days: 365 Use: WELDING SOLDERING Daily Max FT3 Daily Average FT3] Annual Amount FT3 112 I 112.00 I 112.00 Storage I Press T Temp Location PORT. PRESS..CYLINDER IAbove I AmbientlWEST BUILDING MIDDLE -- Conc COmponents MCP ---TGuide 100.0% IAcetylene IHigh ! 17 02-005 AMMONIA SOLUTION Liquid 330 Moderate ~ Immed Hlth GAL CAS #: 1336216 Trade Secret: No Form: LiqUid Type: Pure Days: 365 Use: CLEANING Daily Max GAL Daily Average GALT Annual Amount GAL 330 I 330.00 ! 3,850.00 Storage~,Press T Temp 'Location DRUM/BARREL-NONMETAL IAmbient/ambientl~aUNDRY ROOM & OUTSIDE -- Conc Components MCP ----~uide 100.0% Iammonia Solution IModeratel 60 .02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 4 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-001 CHEVRON SUPREME Liquid 12000 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: 8006-61-9 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: FUEL Daily Max GAL Daily Average GAL Annual Amount GAL ,ooo I ooo.oo I oo,ooo.oo Storage Press T Temp Location UNDER GROUND TANK IambientJBelow ISE CORNER -- Conc · MCP ---~uide 100.0% IGasoline Components IModerateI 27 02-004 MINERAL SPIRTS SOLVENT Liquid 55 Moderate · Fire GAL CAS #: 8030306 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: CLEANING Daily Max GAL55I~ Daily Average55.00GAL I Annual Amount275.00GAL ...... Storage~~Press T Temp Location DRUM/BARREL-METALLIC IAmbientJAmbientlWEST BUILDING NORTH OUTSIDE -- Conc Components ~ MCP -~Guide 100.0% IMlneral Spirits IModerateI 27 02-003 HEAVY DUTY WHITEWALL CLEANER Solid 900 Moderate · Immed Hlth LBS CAS #: 131-07-32 Trade Secret: No Form: Solid Type: Pure Days: 365 Use: CLEANING Daily Max LBS ~ Daily Average LBS Annual Amount LBS 900 I 500.00 11,000.00 Storage ~~Press T Temp Location DRUM/BARREL-METALLIC Iambient~AmbientlINTERIOR NW MECHANIC RM -- Conc Components MCP ---~uide 100.0% ISodium Hydroxide IModerateI 60 02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 5 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-006 CHEVRON UNLEADED GASOLINE Liquid 12000 Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: 8006-61-9 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: FUEL Daily Max GAL Daily Average GAL Annual Amount GAL 12,000 I 6,000.00 ----~ 70,000.00 Storage Press T Temp .. Location UNDER GROUND TANK IambientlAmbientlSOUTHEaST CORNER TANK #3 -- Conc Components MCP ---~uide 100.0% IGasoline IModerateI 27 02-007 CHEVRON UNLEADED PLUS GASOLINE Liquid 12000~ Moderate · Fire, Immed Hlth, Delay Hlth GAL CAS #: 8006-61-9 Trade Secret: No Form: Liquid Type: Pure Days: 365 Use: FUEL ,, Daily Max GAL · Daily Average GAL Annual Amount GAL ,ooo I ,ooo.oo 1 o,ooo.oo Storage I Press T Temp Location UNDER GROUND TANK IAmbientlAmbientlSOUTHEAST CORNER TANK #2 -- Conc Components MCP -~Guide 100.0% IGasoline IModeratel 27 02-008 WHITE POWDERED DEGREASER Solid 900 Moderate · Immed Hlth, Delay Hlth LBS CAS #: 111-76-2 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: CLEANING Daily Max LBS Daily Average LBS Annual Amount LBS -- 900 I 900.00 T 3,600.00 Storage Press T Temp Location DRUM/BARREL-NONMETAL Iambient/AmbientlWEST BUILDING NORTH END -- Conc I Components I MCP ---7Guide 4.0%12-But°xyethan°l IModerate~ 26 10.0% Sodium Metasilicate ILow. ! 60 02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 6 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-009 HEAVEY DUTY COMPOUND Solid 900 Moderate · Reactive, Immed Hlth, Delay Hlth LBS CAS #: 1310-73-21 Trade Secret: No Form: Solid Type: Mixture Days: 365 Use: CLEANING Daily Max LBS Daily Average LBS Annual Amount LBS 900 I 900.00 T 2,700.00 Storage Press T Temp Location DRUM/BARREL-METALLIC .IAmbient/AmbientlWEST BUILDING NORTH END -- Conc Components MCP Guide 35.0% ISodium Hydroxide IModeratel 60 02-010 USC HIGH SUDS Liquid 220 Moderate · Immed Hlth, Delay Hlth GAL CAS #: 64-17-51 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING - Daily Max GAL Daily Average GAL Annual Amount GAL 220 I 110.00 I 1,320.00 Storage I Press T Temp Location DRUM/BARREL-NONMETAL IAmbientlAmbientlWEST BUILDING NORTH END -- Conc Components MCP ---TGuide 2.0% IEthanol IModerateI 26 02-011 USC SPPED OFF Liquid 220 Moderate · Immed Hlth, Delay Hlth GAL CAS #: 111-76-21 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING Daily Max GAL Daily Average GAL~ Annual Amount GAL -- 220 I 220.00 ! 1,650.00 StorageI~PressT Temp Location DRUM/BARREL-METALLIC IAmbient/AmbientlWEST BUILDING NORTH END -- Conc Components MCP ---~uide 10.0% 12-Butoxyethanol IModerateI 26 02/16/94. 5 MINUTE CAR WASH 215-000-000301 Page 7 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-016 AQUA AMMONIA Liquid 55 Moderate · Immed Hlth GAL CAS #: 7664-41-7 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: FORMULATION/MANUFACTURING Daily Max GAL Daily Average GAL Annual Amount GAL 55 I 20.00 [ 330.00 Storage I Press T Temp Location DRUM/BARREL-NONMETAL IAmbientlAmbientlMIXED THAT DAY INTO 10 DRUMS -- Conc Components I MCP ---/Guide 26.0% IAmmonium Hydroxide IModerateI 60 02-017 BLUE FOAM.ING CONDITIONER ~- - Liquid 55 Moderate · Immed Hlth, Delay Hlth GAL CAS #: 25155-30-0 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING .- Daily Max GAL Daily Average GAL Annual Amount GAL 55 [ 55.00 [ 165.00 Storage ~~Press T Temp Location DRUM/BARREL-NONMETAL IAmbient[AmbientlWEST BUILDING NORTH END --ConcI Components i MCP ---TGuide 0.0% Sodium Dodecylbenzene Sulfonate Minimal [ 31 0.0% 2-Butoxyethanol ModerateI 26 02-018 CHERRY WAX Liquid 55 Moderate · Immed Hlth, Delay Hlth GAL CAS #: 7732-18-5 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: CLEANING Daily Max GAL Daily Average GAL Annual Amount GAL 55 I 110.00 ] 2,200.00 Storage Press T Temp Location DRUM/BARREL-NONMETAL IambientlAmbientlWEST BUILDING NORTH END -- Conc I Components I MCP ---rGuide 0.0%12-But°xyethan°l IModeratel 26 . 0.0% Gas Oil ILow ! 27 · 02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 8 02 - Fixed Containers on Site Hazmat Inventory Detail in MCP Order 02-013 UNION CARBIDE OXYGEN Gas 150 Low · Fire, Immed Hlth, Delay Hlth FT3 CAS #: 7782-44-7 Trade Secret: No Form: Gas Type: Pure Days: 365 Use: WELDING SOLDERING Daily Max FT3 Daily Average FT3 Annual Amount FT3 -- 150 [ 150.00 I 150.00 Storage I Press T Temp I Location PORT. PRESS. CYLINDER Above IAmbient WEST BUILDING MIDDLE -- Conc Components MCP ---/Guide 100.0% IOxygen, Compressed ILow ~ 14 02-012 AW68 HYDRAULIC OIL Liquid 55 Unrated · Delay Hlth GAL CAS #: 64742-65-0 Trade Secret: No Form: Liquid Type: Mixture Days: 365 Use: LUBRICANT Daily Max GAL Daily Average GAL! Annual Amount GAL 55 I 55.00 [ 110.00 Storage ~ Press I Temp Location DRUM/BARREL-METALLIC IAmbientlAmbientlWEST BUILDING MIDDLE -- Conc i Components ~ MCP ---rGuide · 02/!6/94 5 MINUTE CAR WASH 215-000-000301 Page 9 00 - Overall Site <D> Notif./Evacuatlon/Medical <1> Agency Notification CALL 911 <2> Employee Notif./Evacuation VERBALL AND CALL 911. EMPLOYEES WILL BE TOLD TO EVACUATE TO MEDI ALERT BUILDING ADJACENT TO CAR WASH. <3> Public Notif./Evacuation RESPONSIBILITY FOR NOTIFICATION OF PUBLIC AGENCIES, INCLUDES BAKERSFIELD HEALTH, POLICE, FIRE DEPT. EVACUATION FROM THE PREMISES WILL BE BY VOICE COMMAND AND ALL PEOPLE/EMPLOYEES WILL BE TOLD TO MEET IN THE MEDI ALERT PARKING LOT ADJACENT TO 5-MINUTE CAR WASH <4> Emergency Medical Plan MINOR INJURIES - MEDI CENTER 820 34TH ST (805) 325-6334 MAJOR INJURIES - GOLDEN EMPIRE AMBULANCE 801 18TH ST (805) 327-9000 · 02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 10 00 - Overall Site <E> Mitigation/Prevent/Abatemt <1> Release Prevention STANDARD GAS STATION SAFETY EQUIPMENT. ON PUMPS; SHUT OFF, VAPOR SHIELD, ETC. ALL OTHER MATERIALS STORED IN SAFETY SEALED CONTAINERS. <2> Release containment TO CONTAIN WITH SAND AND OR KITTY LITTER <3> Clean Up DEPENDING ON SIZE OF SPILL, EITHER AIR OUT OR SHIP TO HAZARDOUS DUMP SITE. <4> Other Resource Activation -02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 11 00 - Overall Site <F> Site Emergency Factors <1> Special Hazards <2> Utility ShUt-Offs A) GAS - NORTHWEST CORNER MECHANICAL ROOM EXTERIOR B) ELECTRICAL - EAST WALL SHOP ROOM INTERIOR C) WATER - WEST SIDE O ST (METER BOX) ADJACENT TO SIDEWALK D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS LOCATED THROUGHOUT BUILDINGS FIRE HYDRANT - NORTHWEST CORNER OF 35TH AND O STREET <4> Building Occupancy Level .02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 12 00 - Overall Site <G> Training <1> Page 1 WE HAVE 40 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE INITIAL AND REFRESHER TRAINING OF THE HAZARDOUS MATERIALS WILL BE TAUGHT AND SUPERVISED BY MR. BOB BRIDGES. THIS TRAINING WILL BE MANDATORY FOR EMPLOYEES WHO HANDLE THESE MATERIALS AND ALL OTHER EMPLOYEES WHO WANT TO ATTEND. <2> Page 2 as 'needed <3> Held'for Future Use <4> Held for Future Use Hazardous Materials Business Plan Flammability 4 Extremely flammable 3 Highly flammable 2 Flammable 1 Low flammability 0 Not flammable Health hazard ~eactivlt¥ hazard' 4 Extremely hazardous' 4 Severe explosion risk 3 Moderately hazardous 3 Explosion risk 2 Hazardous 2 Potentially explosive 1 Slightly hazardous- 1 Not violently reactive 0 Not hazardous 0 Normal stability Specific hazard Acid-Acid L.~ Do not use water BAKERSHELD OXY Oxid|zing il~ Radiation haZard Company Name: Charles Feniey Enterprises dba 5 Minute Car Wash Company Address: 1121 Oakdaie Rd Suite 7 Modesto~ CA 95355 Date: Reyi-sed: March 1994 4019-92 HAZARDOUS MATERIALS BUSINESS PLAN FOP, MA PLEASE READ THE INSTRUCTIONS PRIOR TO COMPLETING AND RETURNING THIS FORM. TO AVOID PENALTY, RETURN THIS FORM WITHIN 30 DAYS FROM DATE OF RECEIPT. SECTION I: BUSINESS IDENTIFICATION DATA 1. Full Name of Business or Facility: 5 MINUTE CARWASH 2. Business Address: 920 34TH STREET, BAKERSFIELD CA. 93301 street city state zip code 3. Mailing Address:P.O. BOX 577200 MODESIO, CA. 95357-7200 street city state zip code 4. Business Phone: (805) 323-9071 5. Owner's Name: CHARLES FENLEY ENTERPRISES Phone #( 209 ) 576-038~ ~2~ OAKDALE ROAD SUITE 8 MODESlO,CA. 95355 street city state zip code 6. Operator's Name: PHIL GARNER Phone #805)393_0963 920 34TH STREET, BAKERSFIELD, CA. 93301 street, city state zip code 7. Principal Business Activity: CARWASH / RETAIL GASOLINE 8. Standard Industrial Classification Code: 7542 9. Number of Employees: 25 9A. per shift: 25 9B. shift hours: 8:30 AMI TO 15:00 PM 10. *Emergency Coordinator: LEE GARNER VICE PRESIDENT name title Business Phone:577-.~850 Home Phone:52~-858~ 24 Hr. Phone: 577-~850 11. *Alternate Emergency Coordinator: MIKE FENLEY PRESIDENT name title Business Phone:577-1850 Home Phone:529-2202 24 Hr. Phone: 577-1850 *The emergency and alternate emergency coordinators represent the business and assist emergency personnel in the event of an emergency involving the business during and after business hours. JURIS 2~5-004 2. Fire District:B~FD ETA # 04 13. Dun's Number:04-862-5399 SECTION II: EMERGENCY RESPONSE PLANS AND PROCEDURES A. EXTERNAL EMERGENCY NOTIFICATION PROCEDURES Chapter 6.95 of the California Health and Safety Code requires a business to immediately notify the emergency response agencies listed below if a release or threatened release of a hazardous material occurs. EMERGENCY RESPONSE AGENCIES 1. Local Emergency Response Personnel Fire Agency/Police Agency: Phone: 911 2. Administerina Aaencv Agency: BAKERSFIELD FIRE DEPARTMENT HAZARDOUS MATERIALS DIVISION Phon~£05)'326-3979 After Hours: 9~ 3. State Office of Emergency Services Phone: (800) 852-7550 or (916) 427-4341 4...National ReSponse Center Phone: (800) 424-8802 AGENCIES' PROVIDING EMERGENCY CHEMICAL INFORMATION Chemtrec - Emergency Response Information Service " Phone: (800) 424-9300 Toxic Information Hotline Phone: (510) 8~9-5208 AN IMMEDIATE VERBAL REPORT SHALL BE PROVIDED AS SOON AS: (1) a person has knowledge of the release or threatened release; (2) notification can be provided without impeding immediate control of the release or threatened release; and (3) notification can be provided without impeding immediate emergency medical measures. THE IMMEDIATE VERBAL REPORT SHALL INCLUDE THE FOLLOWING: (1) the exact location of the release or threatened release; (2) the name of the person reporting the release or threatened release; (3) the hazardous materials involved in the release or threatened release; (4) an estimate of the quantity of hazardous materials involved; (5) if known, the potential hazards presented by the hazardous material involved in the release or threatened release. The immediate reporting shall not be required if there i~ reasonable belief that the release or threatened release poses no significant present or potential 6azard to human health aha safety, property, or the environment. SECTI~ II: CONTINUED B. LOCAL EMERGENCY MEDICAL ASSISTANCE APPROPRIATE FOR POTENTIAL ACCIDENT SCENARIOS IN YOUR BUSINESS 1. Facility: MEDI CENTER Address: 820 34TH STREET city: BAKERSFIELD, CA. Zip Code: 93301 Phone: (805) 325-6334 2. Facility: BAKERSFIELD MEMORIAL HOSPIIAL " Address: 420 34TH STREET city: BAKERSFIELD, CA. Zip code: 93301 Phone: (805) 327-1792 3. Emergency Medical Agency (Ambulance): GOLDEN EMPIRE AMBULANCE Phone: (805) 327-9000 3 SITE/FACILITY DIAGRAM FORM 8 ' SCALE:~/~& BUSINESS N~ME: ~. /~A/.,--F ~ ~L/~2// FLOOR: OF DATE: / / FACILITY N~E: UNIT #? OF (CHECK ONE) SITE DIAGR~uM ~ FACILITY DIAGRAM Fire Hydrant / I Block Wall A 35th Street Gas A ~j Turn Off A · A Water ~ A lurn off ~ ~ A A Mechanical/Boiler A A "0" Street J Reta ~Space V Main Elec.~ V V Turn-off ~ , ~ (~Plan.II !vacuation Area ----~ ~ 34th Street ~eator's Co.mments)j -OFEICIAL US~ ONLY- $~E/FACi LITY DIAGR~ FORM ~ · .Revised 3/94 F" None BUSINESS N~q£: 5 Minute Carwash , FLOOR: ! OF / ~ __ UNIT ~: OF .--:------- (CHECK ONE) SITE DIAGR~ ~ FACILITY DIAOR~ Block Hal ! EMERGENCY ·ACTION PLAN Use map to show emergency route (*) Employee Regroup Area exiting the building.(*) designates the 1 regroup area for all employees to check in with there supervisor. · ~~~~ _. Gas A WHOM? Has been assigned the task of Turn off . A getting the Labor sheet [ ~ A .............. terf ~ First Aid kit ...... ._ Turn o : A Hazardous/Material manual Mechanl /Boiler A ........................ ' ........... ' Room I WHOM? Directs customers from the "o" Street facility ............ Reta Space V WHOM? Directs Emergency vehicles. Main E:lec.~ V Turn-nfl V WHOM? Shuts off the utilities gas { v , V electric water when. the emergency ! v deems it necessary. - v ~Plan 'U Underg°un~ Gas lanks 920 34th Street I etot'~s Co.mments): -OFFI(~IAL USB ONLY- CAS Number '~ ~ 8006-61-9 _ , ,,. IName Gasoline M~Aml 72,000 Gals. Mammlacture's Name AHM . Hazardous I'n'gredimlls % Avg Ami 42 ~ 000 Ga l s ,~_~RON & UNION 76 70-440 Degrees F. Methyl /oO-ll 12,00~ Gals. ....................... I ...... ; -- Hydrocarbons with~ a B P of j~ :La~geslConlainer C°mm°nName Tertiary-Butyl Ether Gasol in~oO-l~ a r u a u ~~-- ,, - Ga_~ol~ne (R)(U)(P) Grade Tertiary-Butyl' Alcohol~o ~ ........ ~ ~ A N y ~ DER ID~ 1203 Trade Sacral N Wasle Code 213 Annual Wasle A~nounl .1336-21-6 j_'~-"! Che,,,icalName Ammonia UaxAml 500 Gals. Mmmlactum's Nmno AItM Hazmdou$ Ingrodianls % Avg Ami 300 Ga 1 s. , .- Ammonium HydroxiOe 2.6 LmgeslConlainer common Na,{m -' 55 Ga l s Aqua Ammonia J r t~ a u a a ~ s o ~ / . " ". DER ID~ -0 - Trade Secret N Wasle Coda Annual Wasle Amount N CAS Number Chemical Name Max Ami '920 L b's 1310-73-2 Sodium Hydroxide Mamlulaclure's Name AHM Hazardous Ingredlenls % Avg Amnl 500 L b S P re ] i ne Largesl Conlainer CommonName Heavy Duty 450 Lbs Whitewall Cleaner ~ r u A . J J A s o Hazard Class Guide Chronic Use Code COR 60 N 08 Locallons Container Type 3 F '~ 1824 l'~ade Secret N Wasla Code Annual Wasle Amounl N CAS Number 111-76-2 ChemicaIName Degreaser Max Aint 920 Lbs 'actu~'e's Hame AHM Hazaidous Ingmdienls % Avg Amt 500 Lbs ]ine Butyl Ce] lose] ve Lalgesl ConlaJner ComluonName Sodi, um Metasi ] icate 450 Lbs Powdered Degreaser "' J r M A u J ~ A s ott D Hazard Clas.. Guide # Chronic Use Code N N Locallous N 08 Conlainer Type 2,, 3 G DER ID// Trade Seclel N Waste Code Annual Waste Amounl Mallulaclule's Halite AHM Hazald°us ingredients ..................... ~0 '" Avg Ami 40 Ga ] s. Chevron -C°,ii,ii~n Name .... ~ ~o I 55 Ga ] s. I° . I~ r ,~~}-o . D Solvent , I I Localions Conlainer'rype I Psi I'TeM '. _ 'h~ I Fi,e-- R.Ac~ I sp.c~.i 4 F I1 DER ID~ 1268 Trade Secrel N Wasle Code Annual Wasla Amounl CAS Number "A W Chemical Hame Max Ami 420 Ga ] s ...... Hazardous Ingredlenls % Avg Ami 300 Ga ] s PFo]ine Butyl Ce]lose]ye LmgeslContainer Common Name 55 Gals Speedoff Liquid ~ r u A u ~ ~ ~ s o Hazard CI~ UNINA! Guide fl Chronic Use Code N N N 08 Locallons Conlalner Type 2, 3 6 _ 1'made Secrel N Wasle Code A.nual Wasle Amounl CAS Number 6 4 - 1 7 - 5 1 Chemical Name Max Amt laclure's Name AHM Hazardous Ingredieuls % Avg Ami 40 §a ] $. S. Chemi ca ] Lalgesl Co~{lainar Common Name Etyy ] A ] coho ,.. 55 als. ]e Clean ,~ ~'. n u ~ j ~ s o [lazard Class Guide cot N Chronic Use Code Locallons N 08 Ce.Iai.er Type 2, 3 G DER ID// Trade Seclel N Waste Code Amtual Waste A~nounl CAS Number 7782 - 44 - 7 Chemical Hame Max Ami 124 / F T 3 Manulaclule's Name AHM Hazardous Ingredients % Avg Ami 124/F T 3 La~gesl Conlahmr Common Name 0 X y g e n 124 / F T 3 er] J F 14 A H J J A S O N D Hazard UN/NA Guide # Chronic Use Code ,oxy 14 N 42 Localions Conlainer Type 3 D DER ID# Trade Secret N Wasle Code Annual Wasle Amounl CAS Number A W Chemical Name .i Max Ami 12,4/_F T 3 74-86-2 -- _m AI{M/ . AcPtevl~nm ~ ~ ' Manulaclure's Ha{ne I Hazardous Ingledienls % Avg Ami 124 / F T 3 CAEB ! DE Acety ] ene La~gesl Conlainer Common Name 124 / F T 3 Acetylene J r u ~ ~ ~ ~ ~ s o Hazard Clas.~ Guide Chronic Use Code FG 17 N 42 Locallons Container Type 3 D DER ID# ]'lade Secrel Wasle Code An.ual Waste Amou~l CAS Number AHM ~'--"-"--'~ ~ Chemical Name _ 64-17-57 N Ethanol Alcohol MaxAmi 220 Gals laclure's Name AHM Hazardous Ingredienls % Avg Ami 1 1 0 Ga ] s II~S. Chemicals ~ o 2 LalgeslCorllainer Common Name .... O 5 5 G a ] s Hi Suds o ~ r ~~ Y N N N N ] N LocallollS ~ -- ..... ~ ~ 2,3 co~lainerG Type 1PSI TemP4 NFPA~[ Nlteallh NFire jR~cl ~ Special DER IDfl Trade Secret N Wasle Cede Armual Wasle Amounl N CAS Number AIIM ~' Chemical Name Max Ami 64741-88-4 N ........ Hydraulic Oil 68 tiff Gai~. Ma~ulaclula's Hame ~IiM Naza~dous !ng[adienls % Avg Ami 40 Ga ] s. _ Chevron.... . Lubricating Base 0il o La~geslConlahmr '-comm0-~ Name ........... o99 + 55 6 a ] s. H yd. 0ii 68 o a ~ UN/NA Guide ~ r Llqul~ Gas Purr Mix Olher ReAc Pre~ Acul~ Chronic Use Code C.L 27 N Y .'N N N N N ~ls N N 26 Localim]s '4~ 3 Co~lai~mrF Type 1PSI TemP4 I'IFPA IteallhN FireN ReAClN Special DER ID] . Trade Secml N Wasla Code A~mual Wasle Amounl N OAS Number AHM~ W Chemical Name Max 64-17-5 N Fo~m~n~ C~nditipne~ 55 6als. Manuladum's Name ~HM' Hazardou~ I~]g~edlenls % Avg Ami 55 6 a ] S. Pro] ine Ethyl Alcohol o 2.0 La~geslConlainer CommonN~me o 55 Gals. ]]ue_ Foaming, . .. ,,, .... Conditioner, .,,, , , o ~ x IzlxJx x Ixlx Ix ~ I~1~ Hazard Clas~ UNINA Guide ~ Solk Liquid Gas Purr Mix OIImr Fir~ ReAc Pres Acuh Chronic Use Coda Reis . N N N Y N N Y N N N N N 08 Locations Conlainer Type PSI Temp tieallh Fire ReAcl Special ' ~_ 2,3 G I 4 NFPA N N DER ID~ l'~ade Secml N Wasle Code A~mual Wasla Amou~l CAS Number - Ai-IM W ...... 1~1_1~-76-72 N Chemical Name 2--But.oxyethano ] Max Ami 165 Ga ] s Mauulaclure's Name AHM :" ' ................. - ...... -- O _ Hazardous I,g!edie,ls % Avg Ami 110 Ga ] s --: ,,, Pro] ine Butyl Ce] ]oso]ve 0 La~geslCo,lainer -- Common Na~ne .... 0 55 Ga]s. Rinse Aid/Drying .Agent o ~T Hazard Clas.. UH/HA Guide# Solk Liqui,--"--'--Gas --------"-------'--put, NIix Olhe, r-~T'---'--------ReAcl Pres --" N ._..__~ N N Y N N Y N N ]_.~..N N N[ UseCode08 ~ Reis Locallorm "----- ~ ------ ---.-J -- Conlainer Type I Re~'~-'cl Special DER ID# Trade Sacral N Wasle Code ~ Amlual Wasle Amounl CAS Number AHM W 111 - 76- 2 N Chemical Name Max Ami 165 G a ] s Manulaclura's Name AHM Hazmdous Ingredienls % .... Avg Ami 1 10 G a ] s. Prol;i. ne Butyl Ce]lose]ye o 4 LafgeslConlaluer Cummou Name .......... o 55 Ga ] s. Cherry Wax o .. ~ F H A l{ ~T ~ A $ O II D '-------------- .... __° Hazard Clas.~' UN/NA~ Guide # ~ Liqul[ Gas Pur~ Mi-'-~ Olho--'--~ ReAc Pres Acul~ Chronic Use Code Reis "'N N N Y :N N Y N N N N N 08 Localiolm Conlainer Type PSI Tamp 2, 3 Fire ReAcl Special .. G 1 4 HFPA N N N DER ID# Trade Sacral N Wasle Code Annual Wasle Amounl cAs Number 39- 3 AI-II~W Chemical Name M i n, e r a, l A c i d ( C ] e ,a n e r ),, 7664-93-9 N. , l~tax Ami 40 Ga i s Manulaclure's Name AHM Hazardous Ingledlenls % .... Avg Ami 2 0 G a ] s Jo 303 Hydrogen Acid o 15 LargeslConlainer "'CommonNama "' Sulfuric Acid o 15 30 Gals Acid o JFHAH J',,TA SOHD ------------ ---- ..... ° x-1 HazardClas., UN/HA Guide # Solk Liqul( Gas Pu, Mi"~ Olher Fir~ RoAc Pres Acul~ Chronic Use Code C0R 1786 59 N Y N N Y N N Reis N Y N 08 Locallons ' ' ' ' Conlainer Type PSI Tamp tteallh Fire ReAct Special 3 G 1 4 NFPA N N DER ID# Trade Secret N Wasle Code Armual Wasle Amount CAS Number Chemical Name Max Ami 80 gals. Manulacture's Name AHM : Hazardous Ingmdienls % Avg Ami ~ic Mist Fragrance Petroleum Disti ] ]ates LmgeslCo~lainer ~ Common Name 1 gal. J F H A H J J A S O II D H~ard CI~ Guide ~ Chronic Use Code N N N 08 tocallons Conlai.ar Type 2,3 j DER ID~ Trade Sec~el N Wasle Code Annual Wasle Amounl Chemical Name Max Ami ~AI'IM ...................................................... : ..... Avg Ami Manulaclure's Name Hazardous Ingredienls % c°mmoh Name J FHAH JJAS Olio Use Code Locallons Co,,,ai,mr.rype] PSI i TemPi FPA.ill,~llh iFire ~ DER ID~ T~ade Secrel Wasle Code Am~ual Wasle Amounl CAS Number Chemical Name Max Ami Manulaclure's Name AHM Hazardous Ingredlenls % Avg A~nl La~gesl Conlainer Common Name J F H A t'! J J A S O Il D Hazard Clas., UNINA Guide CI,onic Use Code Locallons Conlainer Type ]¥ade Secrel Wasle Code ^rmual Wasle Amourd SECTION V: RESPONDING TO CHEMICAL EMERGENCIES A. ABATEMENT AND MITIGATION Abatement and mitigation procedures should guide personnel at your business during a chemical spill. DOT Emergency guide number 27. ABATEMENT AND MITIGATION GUIDELINES FOR GASOLINE AND OTHER FLAMMABLE LIQUIDS IN CASE OF SPILL: Follow emergency notification procedures. CONTAINMENT OF SPILLS Avoid breathing fumes/vapors. Use emergency shut off valve. Eliminate all sources of ignition in the vicinity of spill or released vapors. Dike or dam large spills. ' CLEAN UP OF SPILLS Absorb liquids with absorbent materials described above and remove to safe area for evaporation if this can be done without endangering human life, health or safety. DOT Emergency guide number 60. ABATEMENT AND MITIGATION PROCEDURES FOR AMMONIA AND CHEMICAL TIRE APPLICATOR IN CASE OF SPILL: Follow emergency notification procedures. CONTAINMENT OF SPILLS Avoid breathing fumes/vapors. Wear protective equipment including breathing apparatus and protective clothing and safety goggles. Stop leak if possible'without risk. Prevent entry into soil, storm drain, or dry wells by diking with absorbent material. (ie, sand or soil, etc.) CLEAN UP OF SPILLS Do not touch or walk through spilled material; dike or dam spills if you can do it without risk. Absorb liquids with absorbent materials (sand or other noncombustible absorbent) place in safe container. Remove to safe area and dispose of · ' in conformance with local laws. If small spill, flush with water and follow with normal clean-up procedures. DOT Emergency guide number 59. ABATEMENT AND MITIGATION PROCEDURES FOR ACID8 IN CASE OF SPILL: Follow emergency notification procedures. CONTAINMENT OF SPILLS Avoid breathing fumes/vapors. Wear protective equipment including rubber or neoprene boots, gloves, and splash goggles. Stop leak if possible without risk. Prevent. entry into soil, storm drain, or dry wells by diking with absorbent material. (ie, sand or soil, etc.) CLEAN UP OF SPILLS Dike or dam large spills. Neutralize with lime or limestone to de-solublize acid. Absorb liquids with absorbent materials described above and place in safe container. Remove to safe area and dispose of in conformance with local laws. DOT Emergency guide number 14. ABATEMENT AND MITIGATION PROCEDURES FOR OXYGEN IN CASE OF SPILL: Follow emergency notification procedures. CONTAINMENT OF SPILLS Evacuate all personnel from danger area. Immediately cool containers with water spray. Avoid combining with other gases. Result may create additional, unexpected hazards. CLEAN UP. OF SPILLS Shut off leak if without risk. Ventilate area of leak or move container to well-ventilated area. Keep "combustibles (wood, paper, oil, greases, etc) away from gas. Oxygen vigorously accelerates combustion. Slowly release int° atmosphere, in an open, outdoors area. Remove all flammable materials from vicinity. DOT Emergency guide number 17. ABATEMENT AND MITIGATION PROCEDURES FOR ACETYLEN~ IN CASE OF SPILL: Follow emergency notification procedures. CONTAINMENT OF SPILLS Evacuate all personnel from danger area. Use self containing breathing apparatus where needed. Remove all sources of iqnltion if without risk. Reduce vapors withfoam or fine water spray. Shut off' leak if without risk. CLEAN UP OF SPILLS Move container away from fire area if you can do without risk. Prevent waste from contaminating surrounding environment. Keep personnel away. Discard any product, 'residue, disposable container or liner if compliance with state, federal and local laws. ABATEMENT AND MITIGATION PROCEDURES FOR SOAPS and WAXES. IN CASE OF SPILL: Follow emergency notification procedures. CONTAINMENT OF SPILLS Wear full-covered protective clothing as needed. Use self containing breathing apparatus where needed. Dike or dam large spills. CLEAN UP OF SPILLS Move container away from fire area if you can do without risk. Prevent waste from contaminating surrounding environment. Keep unprotected or unnecessary personnel away. Flush. area with water and follow with normal clean-up procedures. Be careful as spills are slippery. B. PREVENTION The written prevention procedures are actions taken at the business to decrease the likelihood of a spill/release. PREVENTION PROCEDURES FOR GASOLINE,.SOLVENTS, LUBRICATING OILS & GREASES AND OTHER FLAMMABLE LIQUIDS. Do not permit unattended filling of storage containers. Do not permit unattended filling of gasoline into vehicles. Do not permit filling of gasoline into unauthorized containers (le, glass bottles, milk cartons, etc). Check gasoline pipes for leakage under dispensers and fill containers. Place solvent drums in an area protected from collisions or other physical damage. Post "NO SMOKING SIGNS" in gasoline area or in use area. Use hand pumps to remove liquids from drums. PREVENTION PROCEDURES FOR OXYGEN AND ACETYLENE Cylinders should be stored upright and firmly secured to prevent falling over or being knocked over. Place cylinders in cool, dry, well ventilated areas away from sources of heat or ignition and direct sunlight. Post "NO SMOKING OR OPEN FLAME" signs in storage area. PREVENTION PROCEDURES FOR AMMONIA Do not allow untrained employees to dilute or work with product. Place in well ventilated area, protected from collisions or other physical damage. Use hand pump, proper clothing and breathing apparatus when transferring or diluting product. Use hand truck to move all drums. PREVBNTION PROCBDUR~S FOR ACIDS Do not allow untrained employees to dilute or work with product. Place in well ventilated area, protected from collisions or other physical damage. Use hand pump, proper clothing and breathing apparatus when transferring product from one container to another. Use hand truck to move all drums. PREVENTION PROCEDURES FOR SOAPS AND WAXES Do not allow untrained employees to dilute or work with product. Place in well ventilated area, protected from collisions or other physical damage. Use hand pump to transfer all products from. one container to another. Use hand truck to move all drums. C. SPILL RESPONSE PERSONNEL See page three (3) of the Hazardous Materials and Accident Prevention Safety Plan. D. LOCATION OF UTILITY SHUT-OFF VALVES FOR YOUR BUSINESS AS A WHOLE Oakdale Road Location: See area map on next page. Natural Gas: South side of building in planter adjacent to bus bench. Electrical: Main electrical panel inside work room on south side of property between carwash line and self-serve gas islands (locked during non-business hours). Water: East planter adjacent to gas price sign. McNenry Road Location: See area map on next page. Natural Gas: On south/west exterior wall of building. Electrical: Main electrical panel in shop area (locked during non-business hours). Water: North exterior wall Just south of entrance. Bakerfield 34th Street Location' See area map on next page. Natura! Gas'Northwest corner mechanical room exterior. Electrical' East w'all shop room interior. Water' West side 0.~'0 st? (meter box) adjacent to sidewalk. SITE/FACILITY D I AGRA.4 :~ORi~ .._Rgvised 3/94 , (CHgCE ONE) SITE DIAGR~ ~ ~ACILI~ DIAGR~ EMERGENCY ACTION PLAN ~se ~ap ~o show e~e~gency ~oute fo~ (*) Employee Regroup A~ea exiting the building.(*) designates the , , '1 regroup area for ail employees to check tn with there supervisor. WHOM? Has been ~ssigned the task of ~urn off getting the Labor sheet First Aid kit._.~~~....,~~.~ t.~. ot Hazardous/Material manual -- · ' - .............. ' ........... -- ~Rom / WHOM? Directs customers from the faci ~ i%y ~~~ "o" Street WHOM? D~rects Emergency vehicles. ..... . ~_s~ ~ .~ ............ .,.,...~.~ .._" . ..... ~Zr~. ~~~D ............. ~ ~ ~t~ ~ I II Undergot - II Ga~ lan~ I t.....~--, ...... 34t1~ Street l (lnspecto~ a Co.mments)~ -OFFICIAL USE ONLY~ SECTION VI: EMPLOYEE T~AINING See page eight (8) of Hazardous Materials and Accident Prevention Safety Plan. SECTION VII: IMMEDIATE NOTIFICATION AND EVACUATION OF YOUR FACILITY The only hazardous material that poses a threat where the whole facility would require evacuation would be a fire or explosion at our gasoline islands. A fire or explosion would be immediately sighted by the manager or assistant manager, the following evacuation plan will take place: 1. All employees will alert the manager should a fire, explosion or hazardous material spill occur. 2. The manager will immediately evacuate all personnel and/or customers from the effected area and instruct them on the appropriate route based on the current circumstances. 3. The manager will determine if the whole facility requires evacuation. If it does, he will then go to the cashier area, if safe, and announce over the public address system of the emergency and routes of escape. He will then personally confirm that all employees and customers have exited the facility. 4. The manager will then begin emergency notification procedures. 5. All employees are to regroup at the marked (*) predesignated area on the Car Wash Facility Map (located in your Haz/Material Manual) as quickly as the emergency will allow, to be accounted for by their supervisor. 6. Designated pesonnel shall shut-off al! unnecessary utilities to building per instructions of supervisor. SECTION VIII: CERTIFICATION I, undersigned, certify that the above information will be used to fulfill my business's obligations under the laws and that inaccurate information constitutes perjury under the law. "MIKE FE~LEY, PRESIDE', IT LEE GARNER, VICE PRESIDENT Iiheuron Emergency Number (800)a. 57-2022 or (510)233-3737 Material Safety Data Sheet CHEVRON Super Unleaded Gasoline w/Oxy CP8201068 Page 1 of 10 CHARLES FENLE¥ 0091152 MATERIAL ORDERED FOR: 5 MIN CAR WASH 920 ]4TH STREET 2133 WYLIE DR BAKERSFIELD, CA 91301 MODESTO, CA 95350 Print Date.' October 29, 1992 This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is given to them. It also contains information to help you meet community right-to-know/emergency response reporting requirements under SARA Title III and many other laws. If you resell this product, this MSDS must be given to the buyer or the information incorporated in your MSDS. Discard any previous edition of this MSDS. Revised to update section 9 (CompoSition). · , 1. PRODUCT IDENTIFICATION CHEVRON Super Unleaded Gasoline w/Oxy DANGER! - HARMFUL OR FATAL IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE - VAPOR HARMFUL - LONG-TERM EXPOSURE TO VAPOR HAS CAUSED:CANCER IN LABORATORY ANIMALS - MAY CAUSE EYE AND SKIN IRRITATION - EETREMELY FLAMMABLE - KEEP OUT OF .REACH OF CHILDREN PRODUCT NUMBER(S):.CPS201068 PRODUCT INFORMATION: (510)242-5357 Revision Number: 3 Revision Date: 01/25/92 NSDS Number: 004271 NDA - No Data Available NA - Not Applicable Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by the Chevron Environmental Health Center, Inc., P.O. Box 4054, Richmond, CA 94804. CHEVRON Super Unleaded ;oline w/Oxy Page 2 of 10 2. FIRST AID - EMERGENCY NUMBER (800)457-2022 OR (510)233-3737 EYE CONTACT: Flush eyes immediately with fresh water for at 'least 15 minutes while holding the eyelids open. Remove contact lenses if worn. No additional first aid should be necessary. However, if irritation persists, see a doctor. SKIN CONTACT: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. INHALATION: If respiratory irritation or any signs or symptoms as described in this document occur, move the person to fresh air. If any of these effects continue, see a doctor. .INGESTION: If swallowed, give water or milk to drink and telephone for medical advice..DO NOT make person vomit unless directed to do so by medical personnel. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. Note to Physician: Ingestion of this product or subsequent vomiting can result in aspiration of light hydrocarbon liquid which can cause pneumonitis. 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS il' & 12) EYE CONTACT: This substance is slightly irritating to the eyes and could cause prolonged (days) impairment of your vision. The degree of the injury will depend on the amount of material that gets into the eye and the speed and thoroughness of the first aid treatment. Signs and symptoms may include pain, tears, swelling, redness, and blurred vision. Eye contact with the vapors, fumes, or spray mist from this substance could also cause similar signs and symptoms. SKIN IRRITATION: Prolonged or frequently repeated contact may cause the skin to become cracked or dry from the defatting action of this material. DERNAL TOXICITY: If absorbed through the skin, this substance is considered practically non-toxic to internal organs. RESPIRATORY/INHALATION: This substance is slightly toxic to internal organs if inhaled. The degree of injury will depend on the airborne concentration and duration of exposure. The target organ(s) is the nervous system. Inhalation of gasoline vapor at airborne concentrations exceeding 1000 ppm may cause signs and symptoms of central nervous system effects such as headache, dizziness, loss of appetite, weakness and loss of coordination. Vapor concentrations in excess of 5000 ppm may cause loss of consciousness, coma and death. Brief exposures to high vapor concentrations may also cause pulmonary edema and bronchitis. Intentional exposures to excessively high Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 004271 NDA - No Data Available NA - Not Applicable CHEVRON Super Unleaded~oline w/Oxy Page 3 of 10 concentrations (e.g., when used as a drug of abuse) have been reported to result in clinical manifestations that may include convulsions, delirium, and hallucinations. These.manifestations are not known to occur following accidental inhalation of gasoline vapor during normal operations. INGESTION: This substance is slightly toxic to internal organs if swallowed. The degree of injury will depend on the amount absorbed from the gut. The target organ(s) is the nervous system. Signs and symptoms of central nervous system effects may include one or more of the following: headache, dizziness, loss of appetite, weakness and loss of coordination. Because of the low viscosity of this substance, it can directly enter the lungs if it is swallowed (this is called aspiration). This can occur during the act of swallowing or when vomiting the substance. Once in the lungs, the substance is very difficult to remove and can cause severe injury to the lungs and death. PROTECTIVE EQUIPMENT EYE PROTECTION: Do not get this material in your eyes. Eye contact can be avoided by wearing chemical goggles. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be minimized by wearing protective clothing. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create airborne concentrations which exceed the recommended exposure standards, the use of an approved respirator is required. Refer to the OSHA Benzene Standard to determine what type of respirator is required based on exposure levels. VENTILATION: Use this material only in well ventilated areas. 5. FIRE PROTECTION FLASH POINT: (P-M) < -49F (-45C) AUTOIGNITION: NDA FLAMMABILITY LIMITS (% by volume in air): Lower: 1.4 Upper: 7.6 EXTINGUISHING MEDIA: Fire Fighting Foams: Alcohol Resistant Type (AR) AFFF, CO2, Dry Chemical. NFPA RATINGS: Health 1; Flammability 3; Reactivity 0; Special NDA; (Least-O, Slight-l, Moderate-2, High-3, Extreme-4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association or, if applicable, the National Paint and Coating Association, and do not necessarily reflect the hazard evaluation of the Chevron Environmental Health center. Read the entire document and label before using this product. Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 004271 NDA - No Data Available NA - Not Applicable CHEVRON Super Unleaded ;oline w/Oxy Page 4 of 10 FIRE FIGHTING PROCEDURES: This product presents an extreme fire hazard. Liquid very quickly evaporates, even at low temperatures, and forms vapor (fumes) which can catch fire and burn with explosive violence. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment. This may include self-contained breathing apparatus to protect against the hazardous effects of normal products of combustion or oxygen deficiency. Read the entire document. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide and water vapor; incomplete combustion can produce carbon monoxide. 6. STORAGE, HANDLING, AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS: NDA. STABILITY: Stable. HAZARDOUS POLYMERIZATION: Polymerization will not occur. INCOMPATIBILITY: May react with strong oxidizing agents, such as chlorates, nit~ates, peroxides, etc. SPECIAL PRECAUTIONS: Never siphon gasoline by mouth. READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. Use only as a motor fuel. Do not use for cleaning, pressure appliance fuel, or any other such use. DO NOT USE OR STORE near flame, sparks or hot surfaces. USE ONLY IN WELL VENTILATED AREA. Keep container closed. DO NOT TRANSFER LIQUID TO AN UNLABELED CONTAINER. DO NOT weld, heat or drill container. Replace cap or bung. Emptied container still contains hazardous or explosive vapor or liquid. 7. PHYSICAL PROPERTIES SOLUBILITY: Soluble in hydrocarbons; insoluble in water. APPEARANCE: Red liquid. BOILING POINT: 25 - 225C (Variable) MELTING POINT: NA EVAPORATION: NDA SPECIFIC GRAVITY: 0.7 - 0.8 VAPOR PRESSURE: 5 - 15 PSI (max.) @ 100F (Variable) PERCENT VOLATILE (VOLUME %): 99+% VAPOR DENSITY (AIR=l): 3-4 Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 004271 NDA - No Data Available NA - Not Applicable " CHEVRON Super Unleadedesoline w/Oxy Page 5 of 10 8. ENVIRONMENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL CHEMTREC EMERGENCY PHONE NUMBER: (800) 424-9300 (24 hour). SPILL/LEAK PRECAUTIONS: Eliminate all sources of ignition in vicinity of spill or released vapor. Clean up spills immediately, observing precautions in Protective Equipment section. This material is considered to be a water pollutant and releases of this product should be prevented from contaminating soil and water and from entering drainage and sewer systems. U.S.A. regulations require reporting spills of this material that could reach any surface waters. The toll free number for the U.S. Coast Guard National Response Center is (800) 424-8802. DISPOSAL METHODS: Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding to larger releases. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Contact local environmental or health authorities for approved disposal of this material. 9. EXPOSURE STANDARDS, REGULATORY LIMITS AND COMPOSITION SPECIAL NOTES: Ethyl Alcohol is only added in limited specific distribution areas. COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control Act Chemical Substances Inventory. The percent compositions are given to allow for the various ranges of the components present in the whole product and may not equal 100%. PERCENT/CAS# COMPONENT/REGULATORY LIMITS 100.0 % CHEVRON Super Unleaded Gasoline w/Oxy CONTAINING 100.0 % GASOLINE (GENERIC) 300ppm ACGIH TLV 500ppm ACGIH STEL 300ppm OSHA TWA 500ppm OSHA STEL INCLUDING Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 004271 NDA - No Data Available NA - Not Applicable CHEVRON Super Unleaded ~oline w/Oxy Page 6 of 10 < 4.9 % BENZENE CAS71432 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 10ppm ACGIH TLV lppm OSHA TWA 5ppm OSHA STEL 25 ppm OSHA CEILING CERCLA 302.4 RQ=10 POUNDS Refer to the OSHA Benzene Standard (29 CFR 1910.1028) for detailed training, exposure monitoring, respiratory protection and medical surveillance requirements before using this product. < 4.0 % ETHYLBENZENE CAS100414 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 100ppm ACGIH TLV 125ppm ACGIH STEL 100ppm OSHA TWA 125ppm OSHA STEL CERCLA 302.4 RQ=1000 POUNDS < 4..3 % XYLENE-P CAS106423 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and. Reauthorization Act of 1986 and 40 CFR Part 372. 150 ppm ACGIH STEL CERCLA 302.4 RQ=IO00 POUNDS < 8.8 % XYLENE-M CAS108383 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 100ppm ACGIH TLV 150ppm ACGIH STEL 100ppm OSHA TWA 150ppm OSHA STEL CERCLA 302.4 RQ=1000 POUNDS < 4.3 % XYLENE-O CAS95476 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 100ppm ACGIH TLV 150ppm ACGIH STEL 100ppm OSHA TWA 150ppm OSHA STEL CERCLA 302.4 RQ=1000 POUNDS < 14.0 % TOLUENE CAS108883 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 004271 NDA - No Data Available NA - Not Applicable CHEVRON Super Unleaded ;oline w/Oxy Reauthorization Act of 1986 and 40 CFR Part 372. 100ppm ACGIH TLV 150ppm ACGIH STEL 100ppm OSHA TWA 150ppm OSHA STEL 300 ppm OSHA CEILING CERCLA 302.4 RQ=1000 POUNDS < 5.0 % HEXANE CASl10543 50ppm ACGIH TLV 1000 ppm ACGIH STEL 50ppm OSHA TWA < 2.4 % CYCLOHEXANE CASl10827 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 300ppm ACGIH TLV 300ppm OSHA TWA CERCLA 302.4 RQ=1000 POUNDS CAN CONTAIN < 15.0 % METHYL TERT BUTYL ETHER CAS1634044 A toxic chemical subject to the reporting requirements of Section 313 of Title I. II of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. OR < 10.0 % ETHYL ALCOHOL CAS64175 1,000ppm ACGIH TLV 1000ppm OSHA TWA TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity RQ - Reportable Quantity cps - CUSA Product Code CC - Chevron Chemical Company CAS - Chemical Abstract Service Number 10. REGULATORY INFORMATION DOT basic descriptions can. vary based on package quantity and may not coincide with international description requirements. Consult the Hazardous Materials Regulations in 49CFR and the appropriate Dangerous Goods Regulations to confirm description applicability to specific shipments. DOT SHIPPING NAME: GASOLINE DOT HAZARD CLASS: FLAMMABLE LIQUID DOT IDENTIFICATION NUMBER: UN1203 SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects; YES Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 004271 NDA - No Data Available NA - Not Applicable Y- FIIq~r191 · CHEVRON Super UnleadedWsoline w/Oxy Page 8 of 10 2. Delayed (Chronic) Health Effects; YES 3. Fire Hazard; YES 4.. Sudden Release of Pressure Hazard; NO 5. Reactivity Hazard; NO The following components of this material are found on the regulatory lists indicated by the number below the component name: ETHYLBENZENE is found on lists: 01,02,10,11,12,13,14,15,17,18,26,28, XYLENE-P is found on lists: 01,02,10,11,12,15,26,28, XYLENE-M is found on lists: 01,02,10,11,12,14,15,17,18,26,28, TOLUENE is found on lists: 01,02,04 10,11,12,13,14,15,17,18,26,28,29, HEXANE is found on lists: 02,10,11 13 14,15,17,28, CYCLOHEXANE is found on lists: 01 02,10 11 12,13,14,17,26,28, METHYL TERT BUTYL ETHER ~s found on lists: 01 10,11 21 24,26, ETHYL ALCOHOL ~s found on lists: 02,10,11,13 14,17,28, BENZENE ~s found on lists: 01 02,03,04 06,10,11,12,13,14,17,18,20,28,29, XYLENE-O ~s found on lists: 01 02,10,11 12,14,15,17,18,26,28, GASOLINE (GENERIC) ls found on lists: 04 08,14,15,17,18,20, REGULATORY LISTS SEARCHED: 01=SARA 313 02=MASS RTK 03=NTP Carcinogen 04=CA Prop. 65 05=MI 406 06=IARC Group 1 07=IARC Group 2A 08=IARC Group 2B 09=SARA 302/304 10=PA RTK ll=NJ RTK 12=CERCLA 302.4 13=MN RTK 14=ACGIH TLV 15=ACGIH STEL 16=ACGIH Calculated TLV 17=OSHA TWA 18=OSHA STEL 19=Chevron TLV 20=EPA Carcinogen 21=TSCA Sect 4(e) 22=TSCA Sect 5(a)(e)(f) 23=TSCA Sect 6 24=TSCA Sect 12(b) 25=TSCA Sect 8(a) 26=TSCA Sect 8(d) 28=Canadian WHMIS 29=OSHA CEILING 11. PRODUCT TOXICOLOGY DATA EYE IRRITATION: The Draize Eye Irritation Score (range, 0-110) in rabbits is 0. SKIN IRRITATION: The Draize Skin Primary Irritation Score (range, 0-8) for a 4-hour exposure (rabbits) is 0.98. This material was not a skin sensitizer in the modified Buehler Guinea Pig Sensitization Test. Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 00¢271 NDA - No Data Available NA - Not Applicable CHEVRON Super Unleaded~soline w/Oxy Page 9 of 10 DERMAL TOXICITY: The dermal LD50 in rabbits is > 5 ml/kg. RESPIRATORY/INHALATION: No product toxicology data available. INGESTION: The oral LD50 in rats is > 5 mi/kg. ADDITIONAL TOXICOLOGY DATA: Lifetime inhalation of whole gasoline vapor has caused increased liver tumors in female mice. The mechanism of this response is still being investigated but it is thought to be an epigenetic process unique to the female mouse. Inhalation exposure to whole gasoline vapor also caused kidney damage and eventually kidney cancer in male rats. No other animal model studied has shown these adverse kidney effects and there is no physiological reason to believe that they would occur in man. The data above is obtained from studies sponsored by the American Petroleum Institute (API). 12 . ADDITIONAL HEALTH DATA ADDITIONAL HEALTH DATA COMMENT: This product contains benzene. The OSHA Benzene Standard (29 CFR 1910'.1028) contains detailed requirements for training, exposure monitoring, respiratory protection and medical surveillance triggered by the exposure level. Refer to the OSHA Standard before using this product. Repeated or prolonged breathing of benzene vapors has been associated with the development of chromosomal damage in experimental animals and various blood diseases in humans ranging from aplastic anemia to leukemia (a form of cancer). All of these diseases can be fatal. No birth defects have been shown to occur in pregnant laboratory animals exposed to doses not toxic to the mother. However, some evidence of fetal toxicity such as delayed physical development has been seen at such levels. The available information on the effects of benzene on human pregnancies is inadequate but it has been established that benzene can cross the human placenta. This product contains n-hexane. Prolonged or repeated skin contact or breathing of vapors may cause nerve damage characterized by progressive weakness and numbness in the arms and legs. Recovery ranges from no recovery to complete recovery depending upon the severity of the nerve damage. This product contains toluene. Toluene has been reported to decrease immunological responses in test animals. It has also been reported that when young rats were exposed to 1000 ppm toluene for 14 hours daily, for two weeks, irreversible hearing loss was detected. The same daily exposure to 700 ppm for as long as 16 weeks was without effect. Since the level necessary to produce hearing loss is greater than 7 times the ACGIH TLV-TWA for toluene, worker exposures at or below 100 ppm is not expected to cause any adverse effects. There are also reports that chronic solvent abusers (glue sniffers, solvent huffers) who deliberately inhale high concentrations (several thousand ppm) of toluene for prolonged periods (up to ten hours/day) have suffered liver, kidney and brain damage. Toluene Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 004271 NDA - No Data Available NA - Not Applicable CHEVRON Super Unleaded ne w/Oxy Page 10 of 10 may also cause mental and/or growth retardation in the children of female solvent abusers who directly inhale toluene when they are pregnant. Toluene caused growth retardation in rats when administered at doses that were toxic to the mothers (1500 ppm). Concentrations of up to 5000 ppm did not cause birth defects. There were no effects in the offspring at doses that did not intoxicate the pregnant rats. The exposure level at which no effects were seen (No Observed Effect'Level, NOEL) is 750 ppm. We recommend that the precautions outlined in this MSDS be followed to keep toluene concentrations below the recommended exposure standards. This product contains xylene, a chemical that has been reported to cause developmental toxicity in rats and mice exposed by inhalation during pregnancy. The effects noted consisted of delayed development and minor skeletal variations; additionally, when pregnant mice were exposed by ingestion to a level that killed nearly one-third of the test group, lethality (resorptions) and malformations (primarily cleft palate) occurred. Malformations have not been reported following inhalation exposure. Because of the very high levels of exposure used in these studies, we do not believe that their results imply an increased risk of reproductive toxicity to workers exposed to xylene levels at or below the exposure standard. Xylene has given negative results in several mutagen testing assays including the Ames assay. In a cancer study sponsored by the National Toxicology Program (NTP), technical grade xylene gave no evidence of carcinogenicity in rats or mice dosed daily for two years. This product can contain methyl tert butyl ether (MTBE). Most mutagenicity data on MTBE, except for the in vitro mouse lymphoma test, indicate that it is not mutagenic. MTBE caused birth defects in mice exposed to 8,000 ppm throughout pregnancy. No birth defects were observed in mice at 1,000 ppm or in rats or rabbits at any dose of MTBE. These results suggest that the risk of birth defects in humans from MTBE is negligible at the anticipated exposure concentrations. Whole gasoline exhaust was reviewed by the International Agency for Research on Cancer (IARC) in their Monograph Volume 46 (1989). Evidence for causing cancer was considered inadequate in animals and inadequate in humans. IARC placed whole gasoline exhaust in Category 2B, considering it possibly carcinogenic to humans. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume any responsibil- ity for the results of its use. This information is furnished upon condition that the person receiving it shall make'his own determination of the suitability of the material for his particular purpose. Revision Number: 3 Revision Date: 01/25/92 MSDS Number: 004271 NDA - No Data Available NA - Not Applicable 'Chevron Emergency Number (1100)457-2022 or (510)233-3737 Material Safety Data Sheet CHEVRON Unleaded Gasoline w/Oxy CPS201118 Page 1 of 11 This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is given to them. It also contains information to help you meet community right-to-know/emergency response reporting CHARLES FENLEY 0091152 MATERIAL ORDERED FOR: 5 MIN CAR WASH 920 34TH STREET 2133 WYLIE DR BAKERSFIELD, CA 93301 MODESTO, CA 95350 Print Date: October 29, 1992 1. PRODUCT IDENTIFICATION CHEVRON Unleaded Gasoline w/Oxy DANGER: - HARMFUL OR FATAL IF SWALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE - VAPOR HARMFUL - LONG-TERM EXPOSURE TO VAPOR HAS CAUSED CANCER IN LABORATORY AN I MALS - MAY CAUSE EYE AND SKIN IRRITATION - EXTREMELY FLAMMABLE - KEEP OUT OF REACH OF CHILDREN PRODUCT NUMBER(S): CPS201118 PRODUCT INFORMATION: (510)242-5357 Revision Number: 1 Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by the Chevron Environmental Health Center, Inc., P.O. Box 4054, Richmond, CA 94804. CHEVRON Unleaded Gasol w/Oxy Page 2 of 11 2. FIRST AID - EMERGENCY NUMBER (800)457-2022 OR (510)233-3737 EYE CONTACT: Flush eyes immediately with fresh water for at'least 15 minutes while holding the eyelids open. Remove contact lenses if worn. No additional first aid should be necessary. However, if irritation persists, see a doctor. SKIN CONTACT: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. INHALATION: If respiratory irritation or any signs or symptoms as described in this document occur, move the person to fresh air. If any of £hese effects continue, see a doctor. INGESTION: If swallowed, give water or milk to drink and telephone for medical advice.. DO NOT make person vomit unless directed to do so by medical personnel. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. Note to Physician: Ingestion of this product or subsequent vomiting can result in aspiration of light hydrocarbon liquid which can cause pneumonitis. 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS 1i & EYE CONTACT: This substance is slightly irritating to the eyes and could cause prolonged (days) impairment of your vision. The degree of the injury will depend on the amount of material that gets into the eye and the speed and thoroughness of the first aid treatment. Signs and symptoms may include pain, tears, swelling, redness, and blurred vision. Eye contact with the vapors, fumes, or spray mist from this substance could also cause similar signs and symptoms. SKIN IRRITATION: Prolonged or frequently repeated contact may cause the skin to become cracked or dry from the defatting action of this material. DERMAL TOXICITY: If absorbed through the skin, this substance is considered practically non-toxic to internal organs. RESPIRATORY/INHALATION: This substance is slightly toxic to internal organs if inhaled. The degree of injury will depend on the airborne concentration and duration of exposure. The target organ(s) is the nervous system. Inhalation of gasoline vapor at airborne concentrations exceeding 1000 ppm may cause signs and symptoms of central nervous system effects Such as headache, dizziness, loss of appetite, weakness and loss of coordination. Vapor concentrations in excess of 5000 ppm may cause loss of consciousness, coma and death. Brief exposures to high vapor concentrations may also cause pulmonary edema and bronchitis. Intentional exposures to excessively high Revision Number: I Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable CHEVRON Unleaded Gasol w/Oxy 3 of 11 concentrations (e.g., when used as a drug of abuse) have been reported, to result in clinical manifestations that may include convulsions, delirium, and hallucinations. These manifestations are not known to occur following accidental inhalation of gasoline vapor during normal operations. INGESTION: This substance is slightly toxic to internal organs if swallowed. The degree of injury will depend on the amount absorbed from the gut. The target organ(s) is the nervous system. Signs and symptoms of central nervous system effects may include one or more of the following: headache, dizziness, loss of appetite, weakness and loss of coordination. Because of the low viscosity of this substance, it can directly enter the lungs if it is swallowed (this is called aspiration). This can occur during the act of swallowing or when vomiting the substance. Once in the lungs, the substance is very difficult to remove and can cause severe injury to the lungs and death. 4. PROTECTIVE EQUIPMENT EYE PROTECTION: Do not get this material in your eyes. Eye contact can be avoided by wearing chemical goggles. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or freqQently repeated skin contact with this material. Skin contact can be minimized by wearing protective clothing. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create airborne concentrations which exceed the recommended exposure standards, the use of an approved respirator is required. Refer to the OSHA Benzene Standard to determine what type of respirator is required based on exposure levels. VENTILATION: Use this material only in well ventilated areas. 5. FIRE PROTECTION FLASH POINT: (P-M) < -49F (-45C) AUTOIGNITION: NDA FLAMMABILITY LIMITS (%'by volume in air): Lower: 1.4 Upper: 7.6 EXTINGUISHING MEDIA: Fire Fighting Foam: Alcohol Resistant Type (AR) AFFF, CO2, Dry Chemical. NFPA RATINGS: Health 1; Flammability 3; Reactivity 0; Special NDA; (Least-O, Slight-l, Moderate-2, High-3, Extreme-4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association or, if applicable, the National Paint and Coating Association, and do not necessarily reflect the hazard evaluation of the Chevron Environmental Health Center. Read the entire document and label before using this product. Revision Number: 1 Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable X-DOSFI?I CHEVRON Unleaded Gasol{ w/Oxy Page 4 of 11 FIRE FIGHTING PROCEDURES: This product presents an extreme fire hazard. Liquid very quickly evaporates, even at low temperatures, and forms vapor (fumes) which can catch fire and burn with explosive violence. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment. This may include self-contained breathing apparatus to protect against the hazardous effects of normal products of combustion or oxygen deficiency. Read the entire document. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide and.water vapor;'incomplete combustion can produce carbon monoxide. 6. STORAGE, HANDLING, AND REACTIVITY HAZARDOUS DECOMPOSITION PRODUCTS: NDA. STABILITY: Stable. HAZARDOUS POLYMERIZATION: Polymerization will not occur. INCOMPATIBILITY: May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. SPECIAL PRECAUTIONS: Never siphon gasoline by mouth. READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. Use only as a motor fuel. Do not use for cleaning, pressure appliance fuel, or any other such use. DO NOT USE OR STORE near flame, sparks or hot surfaces. USE ONLY IN WELL VENTILATED AREA. Keep container closed. DO NOT TRANSFER LIQUID TO AN UNLABELED CONTAINER. DO NOT weld, heat or drill container. Replace cap or bung. Emptied container still contains hazardous or explosive vapor or liquid. 7. PHYSICAL PROPERTIES SOLUBILITY: Soluble in .hydrocarbons; insoluble in water. APPEARANCE: Orange to bronze liquid. BOILING POINT: 25 - 225C (Variable) MELTING POINT: NA EVAPORATION: NDA SPECIFIC GRAVITY: 0.7 - 0.8 VAPOR PRESSURE: 5 - 15 PSI (max.) @ 100F (Variable) PERCENT VOLATILE (VOLUME %): 99+% VAPOR DENSITY (AIR=l): 3-4 Revision Number: 1 Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable CHEVRON Unleaded Gasol~ w/Oxy Page 5 of ll 8. ENVIRONMENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL CHEMTREC EMERGENCY PHONE NUMBER: (800) 424-9300 (24 hour). SPILL/LEAK PRECAUTIONS: Eliminate all sources of ignition in vicinity of spill or released vapor. Clean up spills immediately, observing precautions in Protective Equipment section. This material is considered to be a water pollutant and releases of this product should be prevented from contaminating soil and water and from entering drainage and sewer systems. U.S.A. regulations require reporting spills of this material that could reach any surface waters. The toll free number for the U.S. Coast Guard National Response Center is (800) 424-8802. DISPOSAL METHODS: Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding to larger releases. Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Contact local environmental or health authorities for approved disposal of this material. 9. EXPOSURE STANDARDS, REGULATORY LIMITS AND COI~[POSITION 'SPECIAL NOTES: Ethyl Alcohol is only added in limited specific distribution areas. COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control Act Chemical Substances Inventory. The percent compositions are given to allow for the various ranges of the components present in the whole product and may not equal 100%. PERCENT/CAS# COMPONENT/REGULATORY LIMITS 100.0 % CHEVRON Unleaded Gasoline w/Oxy CONTAINING 100.0 % GASOLINE (GENERIC) 300ppm ACGIH TLV 500ppm ACGIH STEL 300ppm OSHA TWA 500ppm OSHA STEL INCLUDING Revision Number: ! Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable CHEVRON Unleaded Gasol, w/Oxy Page 6 of 11 < 4.9 % BENZENE CAS71432 A toxic chemical subject to the reporting requirements of' Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 10ppm ACGIH TLV lppm OSHA TWA 5ppm OSHA STEL 25 ppm OSHA CEILING CERCLA 302.4 RQ=10 POUNDS Refer to the OSHA Benzene Standard (29 CFR 1910.1028) for detailed training, exposure monitoring, respiratory protection and medical surveillance requirements before using this product. < 1.4 % ETHYLBENZENE CAS100414 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 100ppm ACGIH TLV 125ppm ACGIH STEL 100ppm OSHA TWA 125ppm OSHA STEL CERCLA 302.4 RQ=1000 POUNDS < 0.9 % XYLENE-P CAS106423 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 150 ppm ACGIH STEL CERCLA 302.4 RQ=1000 POUNDS < 4.6 % XYLENE-M CAS108383 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 100ppm ACGIH TLV 150ppm ACGIH STEL 100ppm OSHA TWA 150ppm OSHA STEL CERCLA 302.4 RQ=1000 POUNDS < 2.2 % XYLENE-O. CAS95476 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 100ppm ACGIH TLV 150ppm ACGIH STEL 100ppm OSHA TWA 150ppm OSHA STEL CERCLA 302.4 RQ=1000 POUNDS < 6.5 % TOLUENE CAS108883 A toxic chemical subject to the reporting requirements of Revision Number: ! Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable CHEVRON Unleaded Ga w/Oxy Page 7 of 11 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 100ppm ACGIH TLV 150ppm ACGIH STEL 100ppm OSHA TWA 150ppm OSHA STEL 300 ppm OSHA CEILING CERCLA 302.4 RQ=1000 POUNDS < 3.0 % HEXANE CASl10543 50ppm ACGIH TLV 1000 ppm ACGIH STEL 50ppm OSHA TWA < 2.4 % CYCLOHEXANE CAS110827 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 300ppm ACGIH TLV 300ppm OSHA TWA " CERCLA 302.4 RQ=1000 POUNDS CAN CONTAIN < 15.0 % METHYL TERT BUTYL ETHER CAS1634044 A toxic chemical subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. OR < 10.0 % ETHYL ALCOHOL CAS64175 1,000ppm ACGIH TLV 1000ppm OSHA TWA TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity RQ - Reportable Quantity CPS - CUSA Product Code CC - Chevron Chemical Company CAS - Chemical Abstract Service Number 10. REGULATORY INFORMATION DOT basic descriptions can vary based on package quantity and may not coincide with international description requirements. Consult the Hazardous Materials Regulations in 49CFR and the appropriate Dangerous Goods Regulations to confirm description applicability to specific shipments. DOT SHIPPING NAME: GASOLINE DOT HAZARD CLASS: FLAMMABLE LIQUID DOT IDENTIFICATION NUMBER: UN1203 Revision Number: ! Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable CHEVRON Unleaded Gasol: w/Oxy Page 8 of 11 SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects; YES 2. Delayed (Chronic) Health Effects; YES 3. Fire Hazard; YES 4. Sudden Release of Pressure Hazard; NO 5. Reactivity Hazard; NO The following components of this material are found on the regulatory lists indicated by the number below the component name: ETHYLBENZENE is found on lists: 01,02,10,11,12,13,14,15,17,18,26,28, XYLENE-P is found on lists: 01,02,10,11,12,15,26,28, XYLENE-M is found on lists: 01,02,10,11,12,14,15,17,18,26,28, TOLUENE is found on lists: 01,02,04,10,11,12,13,14,15,17,18,26,28,29, HEXANE ~s found on lists: 02,10,11,13,14,15,17,28, CYCLOHEXANE ~s found on lists: 01,02,10,11,12,13,14,17,26,28, METHYL TERT BUTYL ETHER ~s found on lists: 01,10,11,21,24,26, ETHYL ALCOHOL ~s .found on lists: 02,04,10,11,13,14,17,28, BENZENE ~s found on lists: 01,02,03,04,06,10,11,12,13,14,17,18,20,28,29, ... XYLENE-O is found on lists: 01,02,10,11,12,14,15,17,18,26,28, GASOLINE (GENERIC) ~s found on lists: 04,08',14,15,17,18,20, REGULATORY LISTS SEARCHED: 01=SARA 313 02=MASS RTK 03=NTP Carcinogen 04=CA Prop. 65 05=MI 406 06=IARC Group 1 07=IARC Group 2A 08=IARC Group 2B 09=SARA 302/304 10=PA RTK ll=NJ RTK 12=CERCLA 302.4 13=MN RTK 14=ACGIH TLV 15=ACGIH STEL 16=ACGIH Calculated TLV 17=OSHA TWA 18=OSHA STEL 19=Chevron TLV 20=EPA Carcinogen 21=TSCA Sect 4(e) 22=TSCA Sect 5(a)(e)(f) 23=TSCA Sect 6 24=TSCA Sect 12(b) 25=TSCA Sect 8(a) 26=TSCA Sect 8(d) 28=Canadian WHMIS 29=OSHA CEILING 11. PRODUCT TOXICOLOGY DATA EYE IRRITATION: The Draize Eye Irritation Score (range, 0-110) in rabbits is 0.. SKIN IRRITATION: The Draize Skin Primary Irritation Score (range, 0~8) for a 4-hour exposure (rabbits) is 0.98. This material was not a skin sensitizer in Revision Number: i Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable CHEVRON Unleaded Gasoll w/Oxy Page 9 of 1! the modified Buehler Guinea Pig Sensitization Test. DERMAL TOXICITY: The dermal LD50 in rabbits is > 5 mi/kg. RESPIRATORY/INHALATION: No product toxicology data available. INGESTION: The oral LD50 in rats is > 5 ml/kg. ADDITIONAL TOXICOLOGY DATA: Lifetime inhalation of whole gas01ine vapor has caused increased liver tumors in female mice. The mechanism of this response is still being investigated but it is thought to be an epigenetic process unique to the female mouse. Inhalation exposure to whole gasoline vapor also caused kidney damage and eventually kidney cancer in male rats. No other animal model studied has shown these adverse kidney effects and there is no physiological reason to believe that they would occur in man. The data above is obtained from studies sponsored by the American Petroleum Institute (API). 12. ADD I T ! ONAL HEALTH DATA ADDITIONAL HEALTH DATA COMMENT: This. product contains benzene. The OSHA Benzene Standard (29 CFR 1910.1028) contains detailed requirements for training, exposure monitoring, respiratory protection and medical-surveillance triggered 'bY the exposure level.. Refer to the OSHA Standard before using this product. Repeated or prolonged breathing of benzene vapors has been associated with the development of chromosomal damage in experimental animals and various blood diseases in humans ranging from aplastic anemia to leukemia (a form of cancer). All of these diseases can be fatal. No birth defects have been shown to occur in pregnant laboratory animals exposed to doses not toxic to the mother. However, some evidence of fetal toxicity such as delayed physical development has been seen at such levels. The available information on the effects of benzene on human pregnancies is inadequate but it has been established that benzene can cross the human placenta. This product contains n-hexane. Prolonged or repeated skin contact or breathing of vapors may cause nerve damage characterized by progressive weakness and numbness in the arms and legs. Recovery ranges from no recovery to complete recovery depending upon the severity of the nerve damage. This product contains toluene. Toluene has been reported to decrease immunological responses in test animals. It has also been reported that when young rats were exposed to 1000 ppm toluene for 14 hours daily, for two weeks, irreversible hearing loss was detected. The same daily exposure to 700 ppm for as. long as 16 weeks was without effect. Since the level necessary to produce hearing loss is greater than 7 times the ACGIH TLV-TWA for toluene, worker exposures at or below 100 ppm is not expected to cause any adverse effects. There are also reports that chronic solvent abusers (glue sniffers, solvent huffers) who deliberately inhale high concentrations (several thousand ppm) of toluene for prolonged periods (up Revision Number:~l Revision Date: 01/23/92 MSDS Number: 004276 NDA - No Data Available NA - Not Applicable Page 10 of 11 ed liver, kidney and brain damage. Toluene o ten hours/day) have suffer ....... ~ tn e children of female t and/or growth re%aru~ ..... th may also cause mental. .~ ~_~ ~o~uene when they are pregnant. solvent abusers who Glrectl~ ~"c~7 ~r2ts when administered at doses that m~l~ne used rowth retar~ ....... ;~,~ f u~ to 5000 ppm were toxic ~o ~e mothers (1500 ppm). concen~o~- .... o did not cause birth defects. There were no effects in the offspring at doses that did not intoxicate the pregnant rats. The exposure level at which no effects were seen (No observed Effect Level, NOEL) is 750 ppm. We recommend that the precautions outlined in this MSDS be followed to keep toluene concentrations below the recommended exposure standards. This product contains xylene, a chemical that has been reported to cause developmental toxicity in rats and mice exposed by inhalation during pregnancy. The effects noted consisted of delayed development and minor skeletal variations; additionally, when pregnant mice were exposed by ingestion to a level that killed nearly one-third of the test group, d malformations (primarily cleft palate) ]othalitv (resorptions) an ........ ted following inhalation ccurred alformations have n?.t exposure use in these : o ure ver an ~. ' .... t believe that tnelr re ..... ~ at or below the studies, we ~u ~ ......... ~o~ to xvlene reproductive toxicity to worKer~ ~F~ exposure standard. Xylene has given negative results in several mutagen testing assays including the Ames assay. In a cancer study sponsored by the National Toxicology Program (NTP), technical grade xylene gave no evidence of carcinogenicity in rats or mice dosed daily for two years. This product can contain methyl tert butyl ether (MTBE). Most mutagenicity data on MTBE, except for the in vitro mouse lymphoma test, indicate that it is not mutagenic. MTBE caused birth defects in mice exposed to 8,000 ppm throughout pregnancy. No birth defects were observed in mice at 1,000 ppm or in rats or rabbits at any dose of MTBE. These results suggest that the risk of birth defects in humans from MTBE is negligible at the anticipated exposure concentrations- Whole gasoline exhaust was reviewed by the international Agency for Research on Cancer (IARC) in their Monograph Volume 46 (1989). Evidence for causing cancer was considered inadequate in animals and inadequate in humans. IARC placed whole gasoline exhaust in Category 2B, considering it possibly carcinogenic to humans. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume any responsibil- ity for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination Revision Number: 1 Revision Date: 01/23/92 NSDS Number: 00~276 NbA - No Data Available NA - Not Applicable CHEVRON Unleaded Gaso~ w/Oxy Page 1! of 11 of the suitability of the material for his particular purpose. Revision Number: ! Revision Date: 01/23/92 NSDS Number: 004276 NDA - No Data Available NA - Not Applicable gmerqency Number (800)457-2022 or (415)233-3737 Material Safety Data Sheet CHEVRON Supreme Mo[or Oil SAR 10~-¢0 CPS22 Pa~e 1 o[ 7 This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please ma~e sure this informa=ion is given to them. It also contains information to help you meet Community tight-to-know/emergency response reporting requirements under SARA Ti=in ~[I and many other laws. [f you resell this product, this MSDS must be g[ve~ to the buyer or the in[o~at[o~ incorporated in your HSDS. Discard any previous edition of th~s MSDS. Revised to update Section l0 - DOT Information. 1. PRODUCT IDENTIFICATION CEEVRON Supreme Motor Oil SAR 10W-t0 - A HAZARD WAi~IING IS ~ ~gUI~D FOR ~IS PRODU~ ~DER OS~ ~Z~ ~I~TION ST~ {29 ~ 1910.1200) PRODUCT ~BER(S): CPS220059 PRODUCT ~NFO~TION= (800)582-3835 Revision Nuubec: I Revision Dale: 12/22/90 MSDS ~umber: 004450 NDA -.MO Da~a AvaiXabln MA - No~ Applicable X-~O~ CHEVRON Supreme Motor Oil SAK 10W-40 Page 2 of 7 CHEVRON Supreme Motor Oil SA~ 10N-40 Page 7 of 7 2. FIRST AID - EI4ERGEN~ NUMBER (800)457-2022 OR (&15)233-3737 The above in~ormat:lon is based os the data of which we are aware and is believed to be correct as o! the date hereof. SLnce ~he ~n~o~na~ion contained hera~o may be applied unde~ condiC~ons beyond our contro~ and EY~ CO~A~: vi~h which va may be unfamiliar and since dace ~de available subsequent ~o ~s~ aid procedures a~e ~eqv~ed. However, as a precaution ~us~ e~es ~o ~he da~e hereof may suggest nodi~ication nE the information, we do not vi~ ~eeh ~a~e: ~o~ ~5 ~n~es. ~e~ove cofl~ac~ ~eflses ~ vo~. assume any respons~bl~iW ~or ~he cesu~s o~ its use. This information ~s SKIN CO~A~: ~uFnished upon condition =ha~ ~he person receiving i~ shall make his own ~o f~rs~ aid 9rocedure~are re, ired. ~ a precau=ioa, wash skin da~a~miua~lon o~ ~he sui~abill~ of ~he made,ia1 for his particular =borougal7 wi~n soap and wa=er. Remove and was~ con=amine=ed cinching, purpose. I~LATIOH: ~f respirator7 discomfor~ or ~r=~a~on occurs, move =he person ~o fresh air. See a doc=or if discom~or= or irr~=a=~ofl continues. INGESTION: ~f swallowed, g~ve wa~er or milk ~o dr~n~ and ~e~epboae for medica~ advice. Coflsu~ medical personnel before inducing vomi=~flg. ~f medical advice caflflo= be obtained, ~hefl ~ake ~he person and produc= con~ainer =o ~he neares~ medical emergent7 =:ea=mefl~ cefl~er or hosp~=al. 3. I~D~ATE ~TH EFFECTS - (ALSO SEE SECTIONS 11 & 12) EYE CONTACT: This substance is not expected to cause prolonged or significant eye irritation. This hazard evaluation is based off the data from similar materials. SKIN IRRITATION= This substance is not expected to cause prolonged or significant skin irritation. This hazard evaluation is based on data from similar materials. DERMAL TOXICITY: The systemic toxicity of this substance has not ~een determined. However, it should be practically non-toxic Co internal organs if it gets on the s&in. This hazard evaluation is based on data from similar materials. R~SPIP.&TORY/INBALATION: The systemic toxicity of this substance has not been datelined. However, it should be practically non-toxic to internal organs if inhaled. This hazard evaluation is based on data from similar materials. INGESTION: The systemic toxicity of this substance has not been determined. However, it should be practically non-toxic to internal organs if swallowed. This hazard evaluation is based on data from similar materials. PROTECTIVE EQUIPHENT EYE PROTECTION: No special eye protection is usually necessary. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated s~in con=act with this material. Skin contact can be Revision Number: 1 Revision Date: 12/22/90 D[SDS Number: 004~50 Revision Number: I Revision Date: 12/22/~0 MSDS Number: 004450 D/DA - NO Data Avallabln HA - Not Applicable NDA - No Da~a Available NA - Not Applicable X-005i~21 I01-~9) X-OOS~ CHEVRON Supreme Hotor Oil SAE lOU-40 Page 4 o! 7 CHEYRON Supreae HoCor Oil SAK 10U-40 Page S of 7 100.0 % CHEVRON Supreme Motor Oil SA~ 10W-40 7. P~SZCAL PROPERTIES CONTAINING SOLUBILITY: Soluble in hydrocarbon solvents: insoluble in water. · 70.0 % LUBRICATING BASE OIL APPEARANCe: NDA BOILING POINT: NDA The ~ASE OIL may ~ a mixture of any of the following: ~ 64741884, MELTING POINT: ~A CAS 64741895,CAS 64741964,CAS 64741~7~,CAS 64742014,C~ 64742525, EV~O~TION: ~A CAS ~4742S36,C~ 64742547,~S 64742627,CAS 64742650.~ 72623837. SPECIFIC G~VI~: 0.89~!5.6/15.6C V~OR P~SSURB: ~A < 30.0 ~ ~DITIVES I~CL~I~G T~ FOLLOWING P~RC~T VO~TI~ (VOL~ I): ~DA V~OR D~SI~ (AIR-i)~ ~A < 2.0 ~ ZINC A~L VISCOSITY: li.3 cst ~ 100C (~in.) CAS6864~423 A ~oxic chemical sub~ec~ Co ~he repor~in~ retirements of Section 313 of Title III o~ ~he Superfund ~en~en~s and Reau~horiza~ion ac~ of 1~86 and 40 CFR Par~ 8. ~IRO~ CON~S, SPILL ~SPONSE ~ DISPOSAL TLV - Threshold Limi~ Value ~A - Time ~eigh~ed Average STBL - Short-term ~x~sure Limi~ TPO ~ Threshold Planning Quan~i~y ~C ~RG~ PRO~ ~B~: (800~ lll-~lo0 (1~ hour). RO - Reportable Qvan~i~y C~S - CUSA Produc~ C~e -- SP1LL/L~ P~IONS: CC - Chevron Chemical Compan~ ~S - Chemical ~s~rac~ Service ~r This material is no~ expected ~o presea~ any enviro~en~al proble~ o~her ~han ~hose associated vi~h oil spills. 10. ~GULATOR~ I~O~TION Stop ~he source of the leak or release. Clean up releases as soon as possible. Concaln liquid ~o preven~ iur~her con~ina~ion of soil, surface water or groundwater. Clean up small ~pills using appropriate DOT SHIPPING N~: ~OT D~SIG~ATED ~ A ~OUS ~TERIAL ~echniques such as sorbent ~aterials or p~ping. ~here fe~i~l~ and F~L DOT appropriate, remove contaminated soil. Follo~ prescribed procedures for DOT ~Z~ C~S: ~ ~PLICABLS re~r~in9 and res~adin9 to larger releases. DOT ID~IFI~TION ~B~R~ ~ ~PLIC~LS DIS~S~ Place con~ina~ materials in dts~sable containers and disuse of in a S~ 311 ~T~GORI~S~ 1. I~ediate (Acute) Health ~gfec~s~ ~O -' manner consistent with applicable regulations. Contact local 2. Delayed (Chronic) Health Effects~ NO enviro~ental or health authorities for approved dis~sal of this 3. Fire Hazard~ material. 4. Sudden Release of Pressure Hazard~ 5. Reactivity ~zard: The following com~nents of. this material are found on the regulatory lists indicated by the n~er below the component n~e: 9. EXPOS~ ST~S, ~GULATORZ LIMITS'~ CO~OSITION ZINC A~YL DI~IOPHOSP~ is found on lists~ 01,10,11, COMPOSITION CO~: All the compoaents of this material are on the Toxic Substances Control REGULATORY LISTS SE~ Act Chemical Substances Inventory. 01-S~ 313 02-~S R~ 03-~P Car=inogen ?his pr~uc[ ~[ts ~he ~CGZ~ deE[nit[on ~or mineral o[1 mis[. The ACGZE 04-CA Prop. 65 05-~ 406 06-[~C Group T[V is 5 mg/m3, the OS~ Pg~ is 5 mq/m3. 07-[ARC Group 2A 08-[~C Group 2~ 09-S~ 302/304 10-PA RTK 11-NJ RTK 12-C~C~ 302.t The percent compositions are given to allow fo= the various ranges of 13-~ R~ 14-ACGIH TLV 15-ACGIH STEL the com~nents p~esen= in the whole product and may not e~al 100%. 16-ACG~H Calculated TLV 17-OS~ ~A 18-OS~ STEL 19-Chevron TLV 20-~A Ca=clnoqen 21-TSCA Sect ~(e) ~ERC~/~J CO~[~GU~RY LIMITS 22-TSCA Sect 5(a)(e)(f) 23-TS~ Sect 6 24-TSCA Sec~ Revision Nu~er: 1 Revision ga~e: 12/22/90 ~DS Numar: 004~50 Revision N~er= 1 Revisiou Date: 12/22/90 ~DS Numar: 004450 ~A - Mo Da~a Available NA - NoC Applicable ~A - No Oa~a Available NA - No~ Applicable X-0~S/121 (~1-~g) _ · CHEVRON Supreme Notor Oil S~E 10W-40 Page S of 7 CHEVRON Supreme Hotor 0il S~ 10W-40 Page 3 o! 7 25=TSCA Sect 8(a) 26-~S~A Sect 8(d) 27=TSCA Sect 8('e) minimized b? venting protective clothing. 28-Canadian ~-~tlS 29-O~HA C~LING 30-TSCA Sect 8 FYI RESPIRATOR¥ PROTECTION: No specia~ respiratory protection is normally required. However, .On .... o.,~ create alr~rne coflcent~a:ions which exceed the 11. PRODUCT TOXICOLOGY DATA recommended exposure required. ~TI~TION: EYE ~ITATION: Use adeguate vea:!ia~ion to keep the air.me concentrations of this ........ =, .......... --~. ,.~ hazard eva[ua~ioB va~ base~ on ....... ~ ............... · ......... '~' data from similar mater~ls. SKIN I~ITATION: No prodvc~ toxicology data available. The ~a~ard eva~uation was based on 5. FI~ PROTECTION da~a ~rom simiiar material~. ~ ~XICITY: ,-~ ~v~ ~ox~co~opy data available. The hazard evalua~io~ was based o~ data from similar materials. AUTOIGN~T~ON: NDA ~SPI~TOR~/I~ATION: FL~BILI~ LIMITS (% bF vol~e in air): Lo-er: NDA Upper: ~A No product ~oxicology data available. The hazard evaluation was based on EXTINGUISHING MEDIA: data from similar materials. CO2, d~y chemical, foam and water fog. INGESTION: ~PA ~TINGS: Health ~; Fla~abtlit~ 1; Reactivity 0; S~ecial NDA; No product toxicology data available. The hazard evaluation was based on ~IS ~TINGS: Health 0; Fla~ablli~y 1; Reactivity 0; Othe~ MPA; data from similar materials. (Least-O, Sligh:-l. Moderate-2. High-3, Extreme-4). These values are obtained using the guidelines or published evaluations prepared by the National ~ire Pro~ec=ion ~socia:io~ or, if applicaD!e, ~he National 12. ~DITIONAL ~TH DATA Paint and Coating ~sociation, and do not necessarily reflec: the hazard evaluation of the Chevron Environmental Heai:h Center. Read the entire doc~en~ and label before using :his pr~uc:. ~DITION~ ~AL~ DATA CO~: FI~ FIG~ING P~CEDU~S: This product contains zinc alkyl dithiophosphates (ZDDPs). Several ZDDPs For fires involving this material, do not enter any enclosed or confined fire space without proper protective equi~ent, including se~f-contained have been re.fred to have weak mutage~ic activity in cultured m~alian breathing apparatus. ceils bur only at concentra=iofls that were toxic ~o :he test cells. We do COMBUSTION P~DU~S: not ~ieve that there is any mutagenic risk ~o wor~ers exposed ~o ZDDPs. Normal :o~ustion for~ caren dioxide, water va~r and may produce oxides · This pr~uct contains 9etrole~ base oils which may ~ refined by various of sulfur, nitrogen and phosphorous. Incomplete co~us~ion can produce processes including severe solvent extraction, severe hydrocracking, or caren monoxide. severe hydrotreatinq. None of the oils requires a cancer warning under the OS~ Hazard Co~unication Standard (29 CFR 1910.1200). These oils 6. STOOGE, ~LING,~ ~ACTIVITY have not been listed in the National Toxicology Progr~ (~p) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic :o ~ans (Group 1), probably ~Z~O~S DECOMPOSITIO~ P~DUCTS: carcinogenic to h~ans (Group 2A), or possibly carcinogenic ~o h~ans (Group 2B). ~A ST~ILITT: During use iff engines, cont~inatio~ of oil with low [evels of Stable. cancer-causing co~ustion products' occurs. Used-motor oils have been ~Z~OUS ~LY~RIZATION: shown to cause skin cancer in mice following repeated application and Pol~erization will not occur. INCOMPATIBILI~: continuous exposure. Brief or intermittent skin con,act with used motor May react with strong oxidizing agents, such as chlorates, nitrates, oil is not expected ~o have serious effects in h~ans if the oil is peroxides, etc. thoroughl~ removed by washing with soap and water. See Chevrofl Material SPECI~ P~IONS: Safety Data Sheet No. 1793 for additional information on used motor oil. DO NOT weld, heat or drill container. Residue maF ignite with explosive violence if heated sufficiently. CA~ION~ Do not use ~ressure to empty dr~ or explosion ma~ result. Revistoa Nu~e~: 1 Revisioa Date: 12/22/90 ~DS Nu~er: 00~450 Revision N~er: ~ Revisto~ Date: 12/22/90 MSDS Nu~er: 004450 NDA - No Data Available MA - Not Applicable ~A - No Data Available NA - Not Applicable x-oosg21 (01-89) X-OOS,'~: Emergenc7 Nu~ber (800)t57-2022 or (~15)233-3737 Material Safety Data Sheet CHEVRON Supreme Motor 0il SAE 30 CPS22 Page ! o! 7 This Material Safer7 Data Sheet contains environmental, health and toxicology in!ormation for your employees. Please make sure informa~£on in given to them. It also contains ~nformation to help you meet commufl~Cy r~ghC-to-knov/emer~enc7 response reporting - requirements under SARA Title [~[ and man7 other lays. If you resell" this product, th~a MSDS must be given to the buyer or the information- incorporated ~n your ~SDS. DLscard an~ previous edition of chis HSDS.- Revised to update Sections 9 (Composition Comment) and ~0 (DOT 1o PRODUCT [DENTIFICATIOH CB:EVROi; Supreme ~4otor Oil SAS 30 - X HA?.ARD VXR~III~G IS ~OT ~90I~O O~ ~Z~ CO~I~TION ST~D~ (29 CFR ~910.~200) PRODUCT ~BZR(S): CPS220002 ': PRODUCT I~FO~T~ON: (S00) 582-3835 L Revision Musher: ! Revision Date: 12/27/g0 HSDS Nu~ber: 004440 ~A - Ho Data Available HA - Hot Applicable X-OO~g[ CHEVRON Supreme HoCor Oil SAS 30 Page $ o! 7 CHEVRON Supceae Ho=or Oil SAS 30 Page 3 of 7 0?-IARC Group 2A 08-1ARC Group 29 09-SA.~A 302/304 minimized ~7 wearing protective clothing. 10-PA RTK ll"NJ.,RTK 12-CERCLA 302.4 RESPIRATORY PROTECTION: 13-MN RTK i¢-A~GIH TLV 1S-ACGIH STEL No special respiratory protection is normally required. However, if 15-ACG~ Calculated TLV iT-OSHA T~A 18-OSHA STEL operating conditions create airborne concentrations which exceed the 19-Chevron TLV 20-EPA Carcinogen 21-TSCA Sect 4(e) recommended exposure standards, the use of an aomroved respirator is 22-TSCA Sect 5(a)(e)(f) 23-TSCA Sect 6 24-TSCA Sect 12(b) required. '' 25-TSCA Sect 8(a) 26-TSCA Sect 8(d) 27-TSCA Sect 8(e) VENTILATION: 28-Canadian ~HMIS 29-OSHA CEILZNG 30-TSCA Sect 8 ~YI Use adequate ventilation to keep the airborne concentrations o£ ~ ma~eriai De,ow the ~ecommended exposure standard. 11. PRODUCT TOXICO~"OG~ DATA 5. FIRE PROTECTION EYE IRRITATION: ~o 9~uct =oxicoiogy data available. The hazard evaluation was based on FLASH PO!,~T.: (COC) 428F (220C} Min. data from similar materials. AUTOiGNITION: NDA SKIN IRRITATION= FLAMMABILITy L~MITS (% by volume in air): Lower: NA Upper: NA No product =oxicology data available. The hazar~ evaluation was based on EXTINGUISHING MEDIA: data from similar materials. Co2,.Dry Chemical, Alcohol Foam and ~ater Fog. DERHAL TOEICITY: NFPA RATINGS: Health 0~ Flammability 1Z Reac=lvity 0~ Special NDA~ No product toxicology data available. The ha=etd evaluation was based o~ HHIS RATINGS: Health 0~ Flammablli~ 1; Reactivity 0; O~her NDA; data from similar materials. (Least-O° Slight-I, Moderate-2, High-3, Extreme-4). These values are RESPIRATOR,/INHALATION: obtained using the guidelines or published evaluations prepared by the No product toxicology data available. The hazard evaluation was based on National Fire Protection Association or, if applicable, the National data from similar materials. Paint and Coating Association, and do not necessarily reflect the hazard INGESTION: evaluation of the Chevron Envirom~ental Health Center. Read the entire No product toxicology data availabie. The hazard evaluation wes based on documen= and label before using this product. data from similar materials. FIRE FIGHTING PROCEDURES: For fires involving ~his material, do not enter any enclosed or confined fire space without proper protective equipment, including self-contained 12. ADDITIONAL HEALTH DATA breathing apparatus. COMBUSTION PRODUCTS: Normal combustion form~ carbon dioxide, wa~er vapor and may produce oxides ADDITIONAL ~EALTH DATA COMHENT: of sulfur, nitrogen and phosphorous. Incomplete come, us=ion can produce This product contains zinc alkyl dithiophosphates (ZDOPs). Several 7.moPs carbon monoxide. have been reported to have weak mutagenic activity in cultured mammalian ceils but only a~ concentrations that were toxic to ~he test cells. We do not believe that there is any mu~agenic risk to workers exposed to ZDDPs. 6. STORAGE, HARDLXNG, AND REACTX¥XT~ Th~s product contains petroleum base oils which may be refined by various processes including severe solvent extraction, severe hydrocracking, or HAZARDOUS DSCOMI'OSITION PRODUCTS: Severe hydro=renting. None of the oils requires a cancer warning under NDA. the OS~A Hazard Communication Standard (29 CFR 1910.1200). These oils STABILITY: have not been listed in the National Toxicology Program (NTP) Annual Stable. aepor~ nor have they been classified by the International Agency' for HAZARDOUS POLYMERIZATION: Research on Cancer (~ARC) as; carcinogenic to humans (Group 1), promably Polymerization will not occur. carcinogenic ~o humans (Group 2A), or possibly carcinogenic to humans INCOMPATISILITT: (Group 2B). May react with strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. During use in engines, contamination of oil with low levels of SPECIAL PRECAUTIONS: cancer-causing combustion products occurs. Used motor oils have been CA~TION! Do not use pressure to empty drum or explosion may resul:. DO · shown to cause skin cancer in mice following repeated.application and NOT weld, heat or drill container. Residue may ignite with explosive continuous exposure. Brief or ~n:ermittent skin con:act with used motor violence if heated sufficiently. oil is not expected to have serious effects in humans if the oil is Revision Number: ! Revision Data: 12/27/~0 MSDS Number: 004440 Revision Nu~be~: I Revision Daze: 12/27/~0 HSDS Numbe~: 004440 NDA - No Da~a Available NA - No~ Applicable NDA - No Data Available MA - Mo: Applicable X -DO,Ti)Z1 (01-89) Of EV~ON Supreme Hotor Oil SAE 30 Page 6 o~ 7 CHE~ON Supreme Notor Oil SAE 30 Page 3 of 7 0?-IAHC Group 2A 08-IARC Group 2S 09-SA~A 302/304 minimized by wearing protective clothing. 10-PA RTK ii-NJ HTK 12-CERCLA 302.4 RESPIRATOHY PHOTECTION: !3-MN RTK 14-ACGIH TLV 15-ACG~H STEL No special respiratory protection is normally required. However, 16-ACGIH Calculated TLV 17-OS~ T~A 18-os~ STEL operatlng =onditions =reate air~rne =on=entra~ions whi=h ex=eed the 19-Chevron TLV 20-EPA Carcinogen 21-TSCA Sect 4(e) reco~ended exposure standard, the use of an approved respirato~ 22-TSCA Sect 5(a)(e)(f) 23-TSCA Se== 6 2~-TSCA Sect 12[b) required. 25-TSCA Se=t 8(a) 26-TSCA Se=t 8(d) 27-TSCA Sect 8(e) 28-Canadian ~ls 29-os~ CEILING 30-TSCA Sect 8 FYI Use adequate ventilation to kee9 the air~orne concentrations of this material below the reco~e~ded exposure 11. PRODUCT TOXZC0~OGY DATA 5. FI~ PROTECTION EYE I~ITAT~ON= No 9roduc~ toxicology data available. The hazard evaluation was based on FLAS~ PO~: (COC} 428F (220C) Min. da~a from similar materials. AUTOiGNITION= ~A SKIN I~ITATION: FL~LI~ LIMITS {% by vol~e in air): Lower: NA Upper: NA No 9r~uct toxicology data available. The hazard evaluation vas based on ~TINGU~SHING MED~A: data from similar materials. C02, Dry Chemical, Alcohol Fo~ and Wa~e= Fog. No produce coxicoxog~ da~a available. T~e hazar~ evaluation vas ~esed on ~lS ~TINGS: Health 0; FXambtXtty X; ReactiviW O~ Other data from similar materials. (Least-O, SZt~ht-1, ~odeca~e-2, High-3, Extreme-4). These values are ~SPI~TORY/I~TION: obcained using ~he guidelines or publLshed evaluations prepared by the No p~oduc~ ~ox~co~opF da~a available. The hazard eve~ua~on vas based on Nac&ona~ ~e P~otecc~on ~soc&a~ofl o~, ~f applicable, ~he da~a fF~ sLm&~a~ ma~e~ia~s. Pa~flc and Coacin9 ~soc~a~ion, and do no& necessa:~Z~ ~ef~ec~ ~he INGESTION: eva~uac&on of ~he ChevFofl ~flv~o~efl~a~ HeaZ~h Cefl~e~. Head ~he en~e No p~oduc~ ~oxico~o~ dace ava~Zab~e. The hazard evaluation vas based on doc~en~ and ~abe~ befoFe ~in~ ~h&s p~oduc~. da~a from sim&~a: ~a~e~a~s. FI~ FIG~ING PR~EDO~S: Fo~ E~es tnvoZvifl~ ~h&s ma~e~&a~ do not en~e~ an~ enc~os~ or confined fi~e space vi~hou~ prope~ p~o~ec~ive equipment, including se~f-concained 12. ~DITIONAL ~TH DATA breaching appa~acus. CO~USTION Normal co~us~io~ fo~ ca=~, dtoaide, water va~r and may produce oxides ~DITION~ ~ DATA C0~T: of sulfur, nitrogen and phosphorous. ~ncomplete co~tioa can produce This product contains zinc alkyl dithiophosphates (~PPs). Several ZDDPs caren monoxide. have been re,fred to have weak mutagenic activity in cultured m~alian cells bu~ only at concentrations that were toxic to the test cells. We do not believe ~ha~ there is any mutagenic risk to workers exposed ~o ZDDPs. 6. STOOGE, ~LING, ~ ~ACTIVITT This p=oduc~ contains petrole~ base oils which may be refined by various processes including severe solvefl~ ex~rac~ion, severe hydrocrackinp, or ~Z~OUS DE~M~SITIOM severe hydro,renting. None of ~he oils requires a cancer warning under ~A. ~he OS~ Hazard Co~uflica~ion S~afldacd (~9 CFR 1910.1200). These oils have no~ been l~s=ed iff ~he National Toxicology Progr~ (~P) Annual Stable. ~epor= nor have ~hey been classified by the ln=erna=ional Agent[ for ~Z~O~S ~esea=ch on Cancer (I~C) as; carcinogenic =o h~ans (Group 1), probably Pol~eriza~ion will no~ occur. carcinogenic =o h~ans (Group 2A), or ~ss~bly carcinogenic ~o h~ans INCO~ATIBILITY: (Group 2B). May react wi~h s~roflg oxidizing agents, such as chlorates, n~rates, peroxides, e~c. During use in engines, contamination of oil wi~h low leve~s of SPECIAL P~CA~IONS: cancer-causing combustion pr~uc=s occurs. Used mo=or oils have been CAUTION~ Do no= use pressure ~o empty d=~ or explosion ma~ result. DO · shown to cause skin cancer in mice following repea~ed application and NOT weld, hea~ or drill container. Hesidue may ignite with explosive continuous exposure. Brief or ~n~erm~ten~ s~in con=ac~ wi~h used mo=or violence if hen=ed oil is no~ expected to have serio~ effects ~n h~ans if the oil is Revision N~e=: 1 Revision Date: 12/27/90 ~D$ Numar: 005440 Revision ~er~ I Revision Da~e: 12/27/90 - ~DS N~er: 004~40 ~A - No Data Available MA - Not Applicable NDA - No Data Available NA - No~ Applic~le X-0050~1 (01-85 X-O0~ V v CHEVRON Supreme Motor O11 SAE 30 Page 4 o! 7 CHEVRON Supreme Mo~or Oil BAE 30 Page 5 of 7 :':"f CONTAINING 7. PHYSICAL PROPERTIES · 90.5 % LUBRICATING BASE Oil SOLUBILITY: Soluble in hydrocarbon solvents; insoluble in water. The 3ASS oil may be a mixture of any of the following: CAS 64741884, APPEARANCE: Dark amper liquid. CAS 64741995,CAS 64741964,CAB 64741978,CA$ 64742014,CAS 64?42525, BOILING POINT: NA CAS 64742~36,CAS 64742547,CAS 64742627,CAS 64742650,CAS 72623837. M~LTING POINT: NA EV~uOi~AT ! ON: NA < SPECIFIC GRAVITY.: 0.89-. ~ 15.6/15.6C VAPOR P.R~,SSURB: NA · 1.5 % BUTYL ~=YL PHTHALATE PERCENT VOLATILE iVOLUME %): NA CAS8~687 A toxic chemical subject to the reoo~tino ~,~,,i,,m ..... VAPOR DENSITY (AiR-i): NA Section 313 of Title III of the Su~ .... ' '-~ ............ erfund ~mendments and VISCOSITY: 10.6 cst @ !00C (Mia.) Reauthorization Act of !956 and 40 CFR ~art CERCLA 302.4 RQ-100 POUNDS 8. ENVlRONIdENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL 1.5 % ZINC ALKYL DITHIOPHOSPHATE CAS68649423 A toxic chemical subject to the reporting requirements Section 313 of Title III of the Superfuhd A~endments and CHEMTREc ENERGENC~ PHONE 141;MBSR: (~} ~Z%-~30~ (2% hour}. Reauthorization Act of 1956 and 40 CFR Part 372. SPIL~/LKAK PP.~CA~TIONS: This material is not expected to present any environmental problems other TLV - Threshold Limit Value TWA - Time Weighted Average than those associated with oil spills. STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity RQ - Reportable Quantity CPS - CUBA Product Code Stop the source of the leak or release. Clean up releases as soon as CC - Chevron Chemical Company CAS - Chemical Abstract Service Number possible. Contain liquid to prevent further contamination of soil, surface water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and 1~. I~EGULATORX INFORMATION appropriate, remove containinated soil.. Follow prescribed procedures for reporting and responding to larger releases. DISPOSAL METHODS: DOT SHIPPING NAi~: NOT DESIGNATED AS A HAZARDOUS MATERIAL BY THE Place contaminated materials in disposable containers and dispose of in a FEDERAL DOT manner consistent with applicable regulations. Contact local DOT HAZARD CI2~SS: NOT APPLICABLE environmental or health authorities for approved disposal of this DOT IDENTIFICATION NUMBER: NOT APPLICABLE material. S~A ~11 CATEGORIES: 1. Immediate (Acute) Health Effects: NO' 2. Delayed (Chronic) Health Effects; NO 9. EXPOSUR~ STARDARDS, REGULATORX LIMITS AND COMPOSITION ~- Fire Hazard; NO i. Sudden Release of Pressure Hazard: NO' COMPOSITION COI~T: 5. Reactivity Hazard; NO Ali the components of this material are on the Toxic Substances Control The following components of this material are found on the regulatory Act Chemical Substances Inventory. lists indicated by the number below the component name: This product fits the ACGIH definition for mineral oil mist. The ACGIH ZINC ALKYL DITHIOPNOSPHATE TLV is 5 mg/m3, the OSHA PEL is 5 mg/m3, is found on lists: 01,10,ii, BUTYL BENZYL PHTHALATE The percent compositions are given to allow for the various ranges of is found on lists: the components present in the whole product and maF not equal 100%. REGULATORY LISTS SEARCHED: PERCENT/CASe COMPONENT/REGULATORY LINITS 01-SARA 313 02-MASS RTl( 03-NTP Carcinogen 100.0 % C~VRON Supreme Motor Oil SAg 30 0C-CA Prop. 65 0S-M! ¢06 06-~ARC Group 1 Re~isinn ...... : I Revision Data= ~2/27/90 MSDS Number: 00~0 NSDS Number: 00¢~0 ---.er Revision Number: I Revision DaCe: 12/27/90 NDA - Ho Da~a Available NA - Not Applicable lqOA - No Oa~a Aval~abZe NA - HoC Appiicab~e X-OOS~ ~01-~ X-OOS~' Number (800)457-2022 or (415)233-3737 E]nergenCy Material Safety Data Sheet CHEVRON Supreme )rotor 0il ~ ~0~-30 CPS22001~ P~ge ~ of 7 This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is given to them. It also contains information to help you meet community right-to-know/emergency response reporting requirements under SARA Title ii! and many other laws. If you resell this product, this MSDS must be given to the buyer or the information incorporated in your MSDS. Discard any previous edition of this MSDS. Revised to update Section l0 - DOT Information. 1. PRODUCT IDENTIFICATION CHEVRON Supreme Motor 0il SAS 10W-30 - A HAZARD WARNING IS NOT REQUIRED FOR THIS PRODUCT UNDER OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) PRODUCT. NUMBER(S): CPS220019 PRODUCT ZNFOR~IATIOI~: (800)582-3835 Revision NuBber: I Revision Date: 12/22/90 NSDS Number: 004449 NDA - No Data Available HA - Not Applicable XoDOSO51 !! CHEVRON Supreme Motor O11 SAS 10N-30 Page 2 of 7 ~HEYRON Supreme Notor Oil SAS 20W-30 Page 7 of 7 2. FIRST AID - EHERGENCY NUMBER (800)457-2022 OR (t15)233-3737 The above information is based on the data of ,hich ve are avare and is believed to be correct as of the date hereof. Since the information contaioed herein may.be applied under conditions beyond ou~ con~o~ and EYE ~A~: vl~h vhich we may be unfamiliar and since data nde avaiZable subsequen~ ~o f~s~ a~d p~ocedu~es a~e ~equ~ed. Hoveve~, as a ~:ecaution flusA eyes ~o ~he da~e hereof ~y sugges~ modification of the info,maCinn, ~e do no~ v~ch f~esh vate~ fo~ 15 miflu~es. Remove coA~ac~ ~e~ses ~f vo:~. assume any responsibility for Lhe Fesults of i~s use. This inforRa~ion SKIN CO~TA~: fucnished upon condition tha~ the peFson receiving it shall make his own ~o ~s~ aid p~ocedu~es a~e :eqci~ed. ~ a p~ecauc~o~, rash skin determination of the gut~Abi]tt~ ~f th~ uAt~r~a) ~O~ ~ ~orough~~' wit~ soap and va~e:. Re~ove and vas~ co~:~na~ed c~o~n~, purpose. !f respiratory discomfor~ or irri~ation ut:uts, move ~he person ~o fresh INGESTION: Consult medical personnel before inducing vomiting. If medical cannot be obtained, then take the person and product container co the nearest ~edical emergent~ Crea~ent center or hospital. 3. I~DIATE ~ALTH EFFECTS - (ALSO SEE SECTIONS 11 i 12) EYE This substance is no~ expected ~o cause prolonped or significan= eye irritation. This hazard evalua=ion is based on ~he data from similar . ma~er ials. SKIN I~ITATION= This substance is no~ expected to cause prolonped or significan~ skin irri~ation. This hazard evalua~io~ is based on da~a from similar materials. DE~ ~XlCITY: The systemic ~oxici~y of this substance has not ~en dete~ined. However, it sh0uld be practically no~-toxic to internal orpans i~ it 9e~s on ~he skin. This hazard evaluation is based on da~a from similar materials. ~SP I ~TORY/I ~T I ON: The systemic ~oxici~y of this substance has not been de~ermined. However, i~ should ~ practically non-toxic to internal orpans if inhaled. This hazard evaluation is ~sed on da~a from similar materials. ~GEST I ON: systemic toxicity of this substance has not ~en de~ermined. However, should ~ practically aon-~oxlc to in~er~al orpans if swallowed. This hazard evaluation is based on da~a from similar materials. t. PROTECTI~ EQUIP~ EYE PROTE~I ON: No special eye proteclion is usually necessary. SKIN PR~ECTION= No special skin protection is usually ~ecessary. Avoid prolonged or frequently repea~ed s~in contact vi~h this material. Skin con[ac~ can ~ Revision Nu~e~: 1 Revision Da~e: 12/22/~0 ~DS Nu~er: 00tii~ Revision Nu~er: 1 Revision.Date: 1~/22/~0 NSDS Number: NDA - No Da~a Available NA - No~ Applicable NDA - No Data Available NA - No~ Applicable x-oo$i]21 (D1-89l X_DO$~I (D1-891 CHEVRON Supreme Motor Ol~ SA~ 10g-20 Page 3 of 7 CHEY~OM Supce~e Hotoc Oi~ SAE 10#-30 Page 6 of 7 minimized ~y wearing protective clothing. 25-TSCA Sect 8(a) 26-TSCA Sect 8(d) 27-TSCA Sect 8(e) RESPIRATORY PROTECTIO#: 28-Canadian ~IS 29-OSHA CEILING 30-TSCA Sect 8 FY~ No special ~espiratory protection is normally required. However, if ooerating conditions create airborne concentrations which exceed the r~commended exposure standards, =he use of an approved respirator il. PRODUCT TOXlCOLOG~ DATA required. ~TI~TION: Use adequate ventilation to keep ~he airborne concert=re=ions of E~E I~ITATIO~: material below =he ceco~ended exposure standard. No produc= toxicology da=a available. The hazard evaluation was based on da=a from similar materials.~ SKIN I~ITATI~= 5. FI~ PROTECTION No p~oduc= toxicology data available. The hazard eva~uation was based on data f~o~ similar materials. DE~L ~EICI~: F~SH POINT: (COC) 40!F (205C) Min. No produc= toxicology data available. The hazard evaluation was based on AUTOIGNITION: ~A data from similar ma=eriais. FL~BIL;TY L~MITS (% by vol~e in air): Lower: NA Upper: NA ~SPI~RY/I~TION= EXTINGUISHING No product ~ozicology data available. The hazard eye,ua=ion was based on C02, dry chemlca~, fo~ and water fog. data from similar materials. NFPA ~TINGS: Health 0~ Fla~bllitF 1= Reactivity 0= Special NDA; INGESTION: ~lS ~TINGS: Health 0~ Fishability 1~ Reactivity 0= Other NDA~ No product toxicology data available. The hazard evaluation was based on (Least-O, Slight-1. M~erate-2, High-3, Extreme-4). These values are data from similar materials, obtained using the guidelines' or published evaluations prepared b~ Na=ional ~lre Protection ~sociation or, if applicable, the National Pain= and Coating ~sociation, and do not necessarily =eflec= the hazard 12. ~DITION~ ~ALTH DATA evaluation of =he Chevron Environmental Health Cen~er. Read =he entire doc~en~ and 1abel before using this product. ~OITIONAL ~ DATA CO~: For fires involvin9 =his materiaL, do not enter any enclosed or confined This pr~uct contains zinc alkyl dithiophosphates (ZDDPs). Several ~DPs fire space without proper protective e~i~ent, includin9 self-contained have been re~ted ~o have weak mutapenic activity in cultured m~allan breaching apparatus. cells but onl~ at concentrations ~hat were toxic =o the test cells. ~e do CO~USTION PRODUCE: not believe ~hat khe~e is any mutaqenic risk ~o workers exposed =o ~DPs. No:mai co~ustion for~ car~n dioxide, water vapor and may produce oxides of sulfu=, nitro, eh and phosphoro~. Incomplete co~ustion can This product contai~ petrole~ ~se oils which ma~ ~ refined by various car~n monoxide. processes incl~in9 severe solvent extraction, severe hydrocra~ing, or severe hydrotreatinp. None of =he oils re~ires a cancer warnin~ under the OS~ Hazard Co~unication Standard (29 CFR 1~0.1200). These oils 6. STOOGE, ~LING, ~ ~ACTIVITT have not been listed in ~he National Toxicology Proqr~ (NTP) Annual Re,or= ~or have they been classified by the International Apency fo= Research on Cancer (I~C) as~ carcinogenic =o h~ans (Group !), probably ~Z~OUS DECOMPOSITION P~DU~S: carcinogenic to h~ans (G~oup 2A), or ~ssibly carcinogenic to h~ans (Group 2B). S~able. During use in engines, contamination of oi~ with low levels of ~Z~OUS POLY~RIZATION= cancer-causing co~ustion products occurs. Used motor oils have been ~ol~erization will not occur. shown ~o ca~e skin cancer in mice following repeated application and INCO~ATIBILIT~: continuous ex,sure. Brief or intermit=eat skin contact with used motor May teac= with strong oxidizing agents, such as chlorates, nitrates, oil is not exacted ~o have serious effects in h~ans if the oil is peroxides, etc. thorough1y :e~ved by washing with soap and water. See Chevron Material SPECIAL Safety Data S~eet No. ~793 for addi=ional info~ation on used motor oil. DO NOT we~d, heat o= drill container. Residue may ignite wi=h explosive v~olence if heated sufficiently. ~ION~ Do not ~e pressure =o emp=y dr~ or explosion may resu1=. Revision N~ec: I Revision Da~e: 12/22/90 ~DS NU~a=: 00&449 Revision ~U~eC: I Revision ~a~e: :2/~2/90 ~US Nu~er: 004449 ' ~A - No oa=a Available HA - Ho~ Applicable ~A - ~o Da~a Available NA - ~o~ Applicable CHEVRON Supreme Motor Oil SAE 10W-30 Page 5 of 7 CHEVRON Supreme Hotor 011 SAE 10W-30 Page 4 of 7 ' - 100.0 % CI~VRON Supreme Motor Oil SAE 10W-10 7. PHYSICAL PROPERTIES CONTAINING · 85.0 % LUBRICATING BASE OIL SOLUBILITY: Soluble in hydrocarDon solvents: insoluble in water. APPEARANCE: Ar~er liquid. The SASE OIL may be a mixture of any of the following: CAS 64741884, BOILING POINT: RDA CAS 647¢1895,CAS 64741954,CAS 6474!975,CAS 64742014,CAS 64742525, p£~?iNG POi~= HA CA~ &474~E36,CAS 64742547,CAS 64742627,CAS 64742650,CAS 7265353?. .- EVAPORATION: NA SPECIFIC GRAVITY.: 0.90 @I5.6/15.6C < 15.0 % ADDITIVES INCLUDING TH~ FOLLOWING VAPOR PRESSURE: NA PERCENT VoLATIL~ (VOLUME %): NA ( 2.0 % ZiNC ALKYL DiTHiOPHGSPHAT~ ~VAPOR DENSITY (AIR-l): NA CAS686494~3 A toxic chemical subject to the reporting requirements o~ 10 cst ~ iOOC (Min.) Reauthorization Act of 19S6 and 40 CFR Part 372. 8. ENVIRONMT-~AL CONCERNS, SPILL P~ESPONSE ~ DISPOSAL TLV - Threshold Limit Value T~A - Time weighted Average STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity~ RQ - Reportable Quantity CPS - CUSA Product Code CHEMTREC EMERGENCY PHONE I~ER: (BO0) 424-~00 (2% hour). CC - Chevron Chemical Company CAS - Chemical Abstract Service Number 'SPILL/LEAK PRECAUTIONS) This material is not expected to present any envirol~mental problems other than those associated with oil spills. 10. REGULATORY INFORMATION stop the source of the leak or release. Clean up releases as soon as possible. Contain liquid to prevent further contamination of soil, DOT SHIPPING NA~: NOT DESIGNATED AS A HAZARDOUS MATERIAL BY surface water or groundwater. Clean up small spills using appropriate FEDERAL DOT techniques such as sorbent materials or pumping. Where feasible and DOT HAZARD CLA$S: NOT APPLICABLE appropriate, remove contaminated soil. Follow prescribed procedures for DOT IDENTIFICATION NUMBER: NOT APPLICABLE reporting and responding to larger releases. DISPOSAL METHODS: SARA 31! CATEGORIES: 1. Immediate (Acute) Health Effects; NO Place contaminated materials in disposable containers and dispose of in a 2. Delayed (Chronic) Health Effects; NO manner consistent with applicable regulations. Contact local 3. Fire Hazard; NO environmental or health authorities for approved disposal of this 4. Sudden Release of Pressure Hazard; NO material. 5. Reactivity Hazard; NO The following components of this material are found on the regulatory~ lists indicated by the number below the component n~me: EXPOSUP~ ST)JTDARDS, REGULATORY LIMITS ~ COMPOSITION ZINC ALKYL DITHIOPHOSPHATE is found on lists: 01,10,11, COMPOSITION COMI~ENT: REGULATORY LISTS SEARCI~: All the components oi this material are on the Toxic Substances Control Act Chemical Substances Inventory. 01-SARA 313 02-MASS RTK 03-NTP Carcinogen 04-CA Prop. 65 05-MI 406 06-tARO Group ! This product fits the ACGIH definition for mineral oil mist. The ACGIH 07-IARC Group 2A 0B-IARC Group 2B 09-SARA 302/304 TLr is 5 mg/m3, the OSHA PEL is 5 mg/m3. 10-PA RTK ll-NJ RTK 12-CERCLA 302.4 13-MN RTK, 14-ACG;H TLV 1B-ACGIH STEL The percent compositions are given to allow for the various ranges of 16-ACGIH Calculated TLV 17-OSHA TWA 18-OSF~ STEL the components present in the whole product and may not equal 1004. 19-Chevron TLV 20-EPA Carcinogen 21-TSCA Sect 4(e) 22-TSCA Sect 5{a)(e)(f) 23-TSCA Sect 6 24-TSCA Sect 12(b) PERCENT/CASa COMPONENT/i~GULATOR~ LIMITS Revision Numbe~: I Revision Date: 12/22/90 MSDS Number: 004449 Revision Number: 1 Revision Date: 12/22/~0 MSDS Number: 004449 NDA - No Data Avail&hie MA - Not Applicable NDA - No Data Available NA - Not Applicable X-DeS~l(~-89) Chevron ~nergency Number (800)457-2022 or (510)233-3737 ~ V Material Safety Data Sheet C~EVRON Xutomatic Transmission Fluid (D~-~ON Il) CPS226502 Page ! o! ? ~ H BR~$1~RS XNC 1325808 ~IAT~.IAL 0RDEP~ED FOR~ 1~ BOX 392 723 s ~ HODEb'~C), CA 9S3S3 HOmE, TO, CA gS3S4 This Materia! Safety Data Sheet contains enviror~entelo health and toxicology information for your employeeso Please make sure this information is given to them. It also contains information to help you meet con~unity right-to-knov/emergency response reporting requirements under'SXP~ Title III and many other lays. If you resell this product, this MSDS must be given Co the buyer or the information incorporated in your ~SDS. Discard any previous edition of chis ~SDS. Revised to update section 5 (Ratings) and 9 (Composition). 1. PRODUCT IDENTIFICATION CHEVRON Automatic Transmission Fluid (DEXRON II) - A HA]ARD ~ING IS NOT R~UIP~D FOR THIS PRODUCT UNDER OSHA HAZARD COHHUNICATION STANDARD (29 CFR 1910.1200) PRODUCT NUMBER(S): CPS226502 PRODUCT iNFORMATION: (800) 582-3835 "' Revision Humber: 15 Revision Date: 09/07/91 HSDS Ntmber: 000021 NDA - No Data Available HA - Not Applicable Prepared According ~o tho OSHA Harsrd Co~unication X-DOS051 i06-89) v CHEVRON Automatic Transmission Fluid (DEXRON II) Page 2 of 7 CRL~ON Automatic Transuission Fluid (DEZRON II) Page 7 of ? The above information is based on the data of which we are aware and is 2. FIRST AID - EMERGENCT NIIMBER (800)&57-2022 OR (510)R33-3737 believed to be correct as of the date hereof. Since this information may --' be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may EYE CONTACT: suggest modification of the information, we do not assume any responsibil- No first aid procedures are required. However, as a precaution flush eyes ity for the results of its use. This infornation is furnished upon with fresh water for 15 minutes. Remove contact lenses if worn. condition that the person receiving it shall sake his own determination SKIN CONTACT: of the suitability of the material for his particular purpose. No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash cont~mlaa~ed I~tALATION: Since this material is not expected to be an immediate inhalation problem, no first aid procedures are required. INGESTION: tf swallowed, ulve water or milk to drink and telephone for medical Consult medical personnel before inducing vomiting. If medical cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS 11 i 12) EYE CONTACT: This substance is not expected to cause prolonged or significant eye irritation. This hazard evaluation is based on the data from similar materials. SKIN IP-RITATION: This substance is not expected to cause prolonged or significant skin irritation. This hazard evaluation is based on data from similar materials. D£RltAL TOXICITY: The systemic toxicity of this substance has not been determined. However, it should be practically non-toxic to internal organs if it gets on the skin. This hazard evaluation is based on data ~rom similar materials. RESPIRATOR~/INIiALATION: The systemic taxicity of this substance has not been determined. However~ it should be practically non-toxic to internal organs if inhaled. This hazard evaluation is based on data from similar material~. NGESTION: systemic toxicity of this substance has not ~een determined. ~owever0 should be practically non-toxic to internal organs if ~wallowed. This hazard evaluation is based on data from similar materials. 4. PROTECTIVE EQUIPMENT EYE PROTECTION: No special eye protection is usually necessary. SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or ~- frequently repeated skin contact ~ith this material. Skin contact can be Revision Number: 15 Revision Bate: 09/07/91 NSDS Number: 000021 Revision Number: 15 Revision Date: 09/07/91 NSDS Number: 000021 NDA - No Data Available HA - Not Applicable NBA ~ No Data Available NA - Not Applicable X-005(]211~1-8~) x_DOS021 (01-B9) CHEVRON Auto--tic Transuission Fluid (DEXRON II) Page 6 of 7 CHEVRON Automatic Transmission Fluid (DEXRON II) Page 3 of 7 is found on lists= 14,15,17, minimized by wearing protective clothing. REGULATORY LISTS SEARCHED: RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create airborne concentrations which exceed the 01-SARA 313 02-KASS RTK 03-NTP Carcinogen recommended exposure standards, the use of an approved respirator is 04-CA Prop. 65 05-MI 406 06-I~RC Group 1 required. 07-IARC Group 2A 0B-IARC Group 2B 09-SARA 302/304 V~ITILATION: 10-PA RTK Il-NJ RTR 12-CERCLA 302.4 Use adequate ventilation to keep the airborne concentrations of this !3-~ RTR 14-ACGiH TLr 15-ACGIH STEL material below the recommended exposure standard. 16-ACGiH Calculated TLV 17-OSHA T~A 18-OSP~ STEL 19-Chevron TLV 20-EPA Carcinogen 21-TSCA Sect 4(e) 22-TSCA Sect 5(a)(e)(f) 23-TSCA Sect 6 24-TSCA Sect 12(b) S. FIR~ PROTECTION 2S-TSCA Sect 8(a) 2$-TSCA Sect 8(d) 28-Canadian ~d~4IS 2~-OSHA CEILING FLASH PoI~rr: (coc) l&0c (320F) Min. ll. PRODUCT TOXICOLOGY DATA AUTOIGNITION: NDA FLA/~BILITY LIMITS (t by volume in air): ~over: NA Upper: NA EXTINGUISHING HEDIA: EYE IRRITATION: C02, Dry Chemical, Alcohol Foam and Water Fog. No product toxicology data available. The hazard evaluation vas based on NFPA RATINGS: Health 0; Flammability l; Reactivity O; Special data from similar materials. (Least-O, Slight-l, Moderate-2, High-3, Extreme-4). These values are SRIN IRRITATION: obtained using the guidelines or published evaluations prepared by the National Fire Protection A~sociation or, if applicable, the National No product toxicology data available. The hazard evaluation was based on Paint and Coating Association, and do not necessarily reflect the hazard data from similar materials. evaluation of the Chevron Environmental Health Center. Read the entire DERMAL TOXICITY: document and label before using this product. No product toxicology data available. The hazard evaluation was based on rlR~ FIGHTING PROCSDURES: data from similar materials. For fires involving this material, do not enter any enclosed or confined RESPIRATORY/INHALATION: fire space without proper protective' equipment, including self-contained No product toxicology data available. The hazard evaluation was based on breathing apparatus. data from similar materials. COHBUSTION PRODUCTS: INGESTION: Normal combustion fort~ carbon dioxide, water vapor and may produce oxides No product toxicology data available. The hazard evaluation was based on of sulfur, nitrogen and phosphorous. Incomplete combustion can produce data from similar materials. carbon monoxide. 12. ADDITIONAL HEALTH DATA 6. STORAGE, HAI~DLING, AND REACTIVITY ADDITIONAL I~ALTN DATA COMHENT: H~ZARDOUS DECOHPOSITION PRODUCTS: This product contains petroleum base oils which may be refined by various I~DA. processes including severe solvent extraction, severe hydrocracking, or STABILITY: severe hydrotreating. None of the oils requires a cancer warning under Stable. the OSHA Hazard Communication Standard (29 CFR 1910.1200). These oils HAZARDOUS POLYMERIZATION: have not been li~ted in the National Toxicology Program (NTP) Annual Polymerization viii not occur. Report nor have they been classified by the International Agency for INCOMPATIBILITY: Research on Cancer (IARC) as; carcinogenic to humans (Group l), probably May react with strong oxidizing agents, such as chlorates, nitrates, carcinogenic to humans (Group 2A), or possibly carcinogenic to humans peroxides, etc. (Group 2B). SPECIAL PRECAUTIONS: DO NOT veld, heat or drill container. Residue may ignite with explosive violence if heated sufficiently. CAUTION! Do not use pressure to empty Revision aunber: 1S Revision Date: 09/07/S1 MSDS Numbe~: 00002~ Revision Ntmber: 15 Revision Date: 09/07/91 MSDS Number: 000021 NDA - No Data Available NA - Not Applicable NDA - No Data Available ~A - Not Applicable X-OOSQ21 (01-89) X-OOS~I 15-85 CHEVRON Automatic Transmission Fluid (DEXRON II) Page 4 of 7 CHEVRON Automatic Transmission Fluid (DEXRON II) Page 100.0 % CHEVRON Automatic Transmission Fluid (DEXRON II) 7. PHYSICAL PROPERTIES CONTAINING · 85.0 % DISTILLATES, HYDROTREATED HEAVY NAP~IC SOLUBILITY: Soluble in hydrocarbon solvents; ins~!u~!e in wa~er, CAS64742525 5 mg/m3 mist ACGIH TLV 10mg/m3 mis~ ACGIH STEL APPEA~CE: Red liquid. 5mg/m3 mis~ OS~ ~A BOILING POINT: ~A M~LTING POINT: NA DISTILLATES, ~DROTREAT~D LIG~ N~IC EVAPO~TION: NA CAS64742536 5mg/m3 mist ACGIH TLV ............... 10mg/m] mis~ AC~IH VAPOR PRESSU~: NA 5mg/m3 mis~ OS~ TWA PERC~T VOLATILE (VOL~E %): NA VAPOR D~SXTY (AIR-l): NA D!ST!LLAT~$~ ~ROTR~TED H~ P~FFINIC VISCOSITY: 35.3 cst ~ ~0c CAS647425~7 5m9/3 mis~ AC~XH TLV · !0~/m~ mist ACGXH STEL ~ 8. E~IRO~NTAL CONCE~S, SPILL ~SPONSE ~ DISPOSAL 5rog/m3 OS~ ~A ~E~C ~RGENC~ PHONE ~ER: (800) ~2~-~300 (2% hour). DISTILLATES. SOLV~ D~w~D HEA~ PA~FFINIC SPILL/LE~ P~UTIONS: " This material is no: expected to presen~ any enviro~enZal proble~ o~h~r CAS647%2650 =hah those associa~e~ with oil spills. · 15.0 % ~DITIVES Stop the source of the leak or release. Clean up releases as soon as possible, observing precautions ~n Pro~ective ~ipmen%. Conzain li~id TLV - Threshold Limi~ Value ~A - T~me Weighted Average to prevent further cont~ina~ion of soil, surface wa~er or groundwater. STEL - Short-term ~xposur~ Limi~ TPQ - Threshold Planning Quantity clean up small sp~lls using appropriate techniques such as sorben~ RQ - Reportable Quan~i~y CPS - CUSA Produc~ Code materials or p~p~ng. Where feasible and appropriate, remove cont~ina~ed CC - Chevron Chemical Company CAS - Chemical Abstract Service N~er soil. Follow prescribed procedures for re~rting and responding ~o larger releases. 10. ~GULATORX INFO~ATION DISPOS~ ~ODS: Place cont~ina:ed materials in disposable con%miners and dispose of in a manner consistent with applicable regulations. Con%ac= local enviro~en~al or health authorities for approved disposal of %his DOT SHIPPING N~: NOT DKS~GNATED AS A ~OUS F~TERIAL'BY T~ FKDE~L DOT material. DOT ~ CLASS: NOT ~PLICABLE DOT ID~TIFICATION ~BER: NOT ~PLI~BLS 9. EXPOSU~ ST~S, ~GULATORX LIMITS ~ CO~OSITION S~ 311 CAT~GORIKS: 1. Immediate (Acute) Health Effects; NO 2. D~layed (Chronic) Health Effects; NO 3. Fire Hazard; NO [TION CO~T: All ~he components of this material are on the Toxic Su~ances Control 4. Sudden Release of Pressure Hazard; NO Act Chemical Substances ~nven~ory. 5. Reac~ivi~y Hazard; NO This produc~ fits ~he ACGIH defini=ion for mineral oil mis~. The ACGIH The follow~ng com~nen~s of %his mazerial are found on the regulatory TLV is 5 mg/m3, ~he OS~ PEL is 5 mg/m3, lis~s indicated b~ ~he n~er below ~he componen~ The percen~ compositions are given to allow for'the various ranges o~ DISTIL~TES, ~ROT~TED ~A~ N~IC =he components present in the whole produc~ and may no~ equal 100%. is found on lists: 14,15,17, DISTILLATES, ~ROT~TED LIG~ N~IC PERC~T/~SO COMPON~T/~GU~TORY LIMITS is found on lis=s: 14,15,17, DISTIL~S, ~ROT~A~D ~ P~FINIC Revision Nu~e=: 15 Revision Da~e: 09/07/91 ~DS Nu~e~: 000021 Revision Nu~e=: 15 Revision Date= 09;07/91 ~DS Nu~ec: 000021 ~A - No Da~a Available NA - No~ Applicable NOA - No Data Available NA - No~ Applicable. X-DOSI~21 (01-89) Xo005~71 i01-89) Emergency Number (800)457-2022 or (510)233-3737 ~ Material Safety Data Sheet Cg~.VRON Supreme Unleaded Gasoline CPS201 Paqe I of 10 This Haterie[ Safety Data Sheet contains environmental, health and tox£cology information for your employees. Please make sure this information is given to them. It also contains information to help you meet conwun[ty right-to-knov/emergenc7 response reporting requirements under SARA T[tle III and many other lays. [f you resell this product, this HSDS mus[ be given to the buyer or the information incorporated in your NSDS. Discard any previous edition of this HSDS. Revised to update Sect[on [2 (Additional Health). l. PRODUCT IDENTIFICATION CHEVRON Supreme Unleaded Gasoline DANGERf - KARMFUL OR FATAL IF SMALLOMED - CAN ENTER LUNGS AHD CAUSE DAMAGE - VAPOR HARMFUL - LONG-TER~ EXPOSUI~ TO VAPOR HAS CAUSED CANCER IN LABORATORY ANIMALS - KAY CAUSE EYE AND SKIN IRRITATION - EXTREMELY FLAHMABLE - KEEP OUT OF P~AC~ OF CllILDP~q PRODUCT NUMB~-R(S): ¢PS201060 PRODUCT INFOEP~ATION: (800)582-3835 Revision ~umber: iS Revision Date: 08/06/91 HSDS Hund:er: 001376 NDA - No DaCe Available RA - ~o~ Applicable CHEVRON Supreee Ue~eaded Gasoline Page 2 of i0 2. FIRST AID - EMERGENCY NUMBER (800)457-2022 OR (510)233-3737 Flush eyes in~ediately with f~esh ~ater for at ~east 15 minutes while ho~d~flg the eye~ids open. Remove contact ~eflses if vein. No add~t~ofla~ first a~d should be necessary. However, i~ ~rritat~ofl persists, see a doctor. SKIN CO~A~: No f~rst aid procedures~re required. ~ a precaution, wash skin thoroughly vita soap and water. Remove and wash coflt~inated c:oth~ng. If respiratory ~r~tatton or an~ signs or s~to~ as described ~fl this continue, see a dec,or. INGESTION: If sva~Zoved, give water o~ mi~k to drink and :e~ephofle for medica~ advice. ~O ~OT make.person vomit unless directed to do so by medical personneZ. If medical advice cannot be obtained, then take the person and product container to the nearest med~ca~ emergency treatment center or hospital. Note to Physician: Ingestion of this product or subsequent vomiting can result ~n aspiration of ~ght h~drocat~fl ~iqu~d ~h~ch can cause pne~oflit ~s. 3. IMHEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS 11 & 12) EYE CONTACT: This substance ts slightly irritating to the eyes and could cause prolonged (days) impairment of gout vision. The degree of the injury will depend on the a~ount of materia! that gets into the eye and the speed and thoroughness of the first aid treatment. Signs and s~ptoms may include pain, tears, swelling, redness, and blurred vision. Eye contact with the vapors, fumes, or spray mist from this substance could also cause similar signs and symptoms. SKIN IRRITATION: Prolonged or frequently repeated contact may cause the skin to become cracked or dry from the deferring action of this material. DEI~IAL TOEIClTY: If absorbed through the skin, this substance is considered practically non-toxic to internal organs. RESPIRATORY/INHALATION: This substance is slightly toxic to internal organs if inhaled. The degree of injury will depend on the airborne concenttation and duration exposure. The target organ(s) is the nervous system. Inhalation gasoline vapor at airborne concentrations exceeding 2000 ppm may cause signs and s~nnptoms of central nervous system effects such as headache, dizziness, loss of appetite, weakness and loss of coordination. Vapor concentrations in excess of $000 ppm may cause loss of consciousness, and death. Brief exposures to high vapor concentrations may also cause pulmonary edema and bronchitis. ~ntefltional exposures'to excessively high Revision Number: ~S Revision Date: 08/06/91 NSDS Number: 001376 NDA - No Dsta Available NA - Not AppLicable X-DOSO21 [01-89! CHEVRON Supreme Unleaded GasoLine Page 4 o~ l0 CH~ON Supreme Unleaded Gasoline Page g o! 10 This product presents an extreme fire hazard. Liquid very quickly model studied has shown these adverse kidney effects and there is no evaporates, even at iow temperatures, and for~ vapor (fu~es) which can physiological reason to believe that they would occur in man. catch fire and burn with explosive violence. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, The data above is obtained from studies sponsored by the American welding equipment, and electrical motors and switches. Petroleum Institute {API). For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment. This may include 12. ADDITIONAL KEALTH DATA self-contained breathing apparatus to protect against the hazardous effects of normal products of combustion or oxygen deficiency. Read the entire document. COMBDSTION PRODUCTS= -'~ ADDITIONAL HEALTH DATA COMMENT:. This product conzains benzene. The OSHA Benzene Standard (29 CFR Normal con~ustion forms carbon dioxide and water vapor; incomplete 1910.1028) contains detailed requirements for training, exposure combustion can produce carbon monoxide, monitoring, respiratory protection and medical surveillance triggered by the exposure level. Refer to the OSHA Standard before using this produc=. Repeated or prolonged breathing of benzene vapors has been associated, with S. STORAGE, HAiqDLING, AND REACTIVIT! the development of chromosomal damage in experimental animals and vac~,ous blood diseases in humans ranging from aplastic anemia to leukemia (a form of cancer). Ail of these diseases can be fatal. No birth defects have HAZARDOUS DEC0HEOSITIOR PRODUCTS: been shown to occur in pregnant laboratory animals exposed to doses NDA. toxic to ~he mother. However, some evidence of fetal toxicity such ~ STABILITY: delayed physical development has been seen at such levels. The available Stable. information on the effects of benzene on human pregnancies is inadequ~=e HAZARDOUS POLYMERIZATION: but it has been established that benzene can cross the human placenta. Pulverization will not occur. INCOHPATIBILITY: This product contains n-hexane. Prolonged or repeated skin contact Or May react with strong oxidizing agents, such as chlorates, nitrates, breathing of vapors may cause nerve damage characterized by progressive peroxides, etc. weakness and nu~ness in the arms and legs. Recovery ranges from no SPECIAL PRECAUTIONS: recovery to complete recovery depending upon the severit~ of the nerve Never siphon gasoline by mouth. READ AND OBSERVE ALL PRECAUTIONS ON damage. PRODUCT LABEL. Use only as a motor fuel. Do not use for cleaning, pressure appliance fuel, or any other such use. DO NOT USE OR STO~E near This produc~ contains toluene. Toluene has been reported to decrease flame, sparks or hot surfaces. USE ONLY IN WELL VENTILATED AREA. Keep i~munological responses in test animals. It has also been reported that container closed. DO NOT TRANSFER LIQUID TO A/; UNLABELF, D CONTAINER. DO when young rats we=e exposed to 1000 p.c~ toluene for 1~ hours daily, for NOT weld, heat or drill container. Replace cap or bung. ~ptied container two weeks, irreversible hearing loss was detected. The sa~.e daily exposure still contains hazardous or explosive vapor or liquid, to 700 ppm for as long ss 16 weeks was without effect. Since the level necessary to produce hearing loss is greater than 7 times the ACGIH.~' TLV-TWA for toluene, worker exposures at or below 100 ppm is not expected 7. PHYSICAL PROPERTIES to cause any adverse effects. There are also reports that chronic solvent abusers (glue sniffers, solvent buffers) who deliberately inhale SOLUBILITY: Soluble in hydrocsrbons~ insoluble in Va~er. concentrations (several thousand ppm) of toluene for prolonged periods APPEARANCE: Red liquid, to ten hours/day) have suffered liver, kidney and brain damage. Toluene BOILING POINT: 2S - 225C (Variable) may also'cause mental and/or growth retardation ,in the children of female solvent abusers who directly inhale toluene when they are pregnant. MELTING POINT: NA Toluene caused growth retardation in rats when achninistered at doses that EVAPO;LkTIO~: NDA were toxic to the mothers (1500 ppm). Concentrations of up to 5000 SPECIFIC GI~AV%TY: 0.7 - 0.8 did not cause birth defects. There ~ere no effects in the offspring at VAPOR PRESSURE: $ - 15 PSI (max.) @ 100F (Variable) doses that d~d not intoxicate the pregnant rats. The exposure level at PERC-~NT VOLAT!LE (VOLUME %): 99*% which no effects were seen (No Observed ~ffect Level, NOEL) is 750 ppm. We VAPOR ~F,~sITT (AIR-l): 3-4 recommend that the precautions outlined in this MSDS be followed to keep toluene concentrations below the recommended exposure standards. This product contains xylene, a chemical that has been reported to cause developmental toxicity in rata and mice exposed by inhalation during Revision Number: 15 Revision Date: 08/06/91 HSDS Number: 00~37& Revtsios Number: 15 Revisios Data: 08/06/91 .MEDE Number: 001376 NDA - No Data Available HA - Not Applicable NDA - Ns Data Available NA - Not Applicable x-o051I21 (1]1-85 x-oos~ CHEVRON Supreme Unleaded Gasoline Page 10 of 10 CHEVRON Supreme Unleaded Gasoline Page 3 of I0 pregnancy. The effects noted consisted of delayed development and minor concentrations (e.g., vhen used as a drug of abuse) have been repOrted to skeletal variations: additiQnally,.when pregnant mice were exposed by result in clinical manifestations 'that may include convulsions, delirium, ingestion to a level that k~iled ne~r~y one-third of the test group, and hallucinations. These manifestations are not known to occv~-.following lethality (resorptions) and malformations (primarily cleft palate) accidental inhalation of gasoline vapor during normal operations. occurred. Malformations ~ave not been reported following inhalation INGESTION: exposure. Because of the very high levels of exposure used in these This substance is slightly toxic to internal organs if swallowed. The studies, we do not believe that their results imply an increased risk of degree of injury will depend on the amount absorbed from the gut. The reproductive toxicity to workers exposed to xglene levels at or below the target organ(s) is the nervous system. Signs and sym. ptoms of central nervous system effects may include one or more of the following: Xylene has given negative results in several mutaqen testing assays Because of the low v~scosity of this substance, it can directly enter the including the Ames assay. In a cancer study sponsored by the ~ational lungs if it is swallowed (this is called aspiration). This can occur Toxiculo~ Program (~TP), technical grade ~y!ene gave no evidence of during the act of swallowing or when vomiting the substance. Once in the carclnogenicity in rats or mice dosed daily for two years, lungs, the substance is very difficult to remove and can cause severe injury to the lungs and death. This contains methyl tert butyl ether (MT, BE). Most mutagenicity product data on MTSE, except for the in vitro ~ouse lymphoma test, indicate that it is not mutagenic. MTBE caused birth defects in mice exposed to 8,000 4. PROTECTIVE EQUIPMENT ppm throughout pregnancy. No birth defects were observed in mice at 1,000 ppm or in rats or rabbits at any dose of MTGE. These results suggest that the risk of birth defects in hm~ans from MTBE is negligible at the EYE PROTECTION: anticipated exposure concentrations. Do not get this material in your eyes. Eye contac: can be avoided by wearing chemical goggles. Whole gasoline exhaust was reviewed by the International Agency for SKIN PROTECTION: Research on Cancer (IARC) in their Monograph Volume 46 (1989). Evidence No special skin protection is usually necessary. Avoid prolonged or for causing cancer was considered inadequate in animals'and inadequate in frequently repeated skin contact with this material. Skin contact can be humans. IARC placed whole gasoline exhaust in Category 2S, considering it minimized by wearing protective clothing. possibly carcinogenic to humans. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if mortaring conditions create airborne concentrations which exceed the recommended expOsure standards, the use of an approved respirator is respirator is required based on exposure levels. VENTILATION: The above information is based on the data of which wa are aware amd is Use this material only in veil ventilated areas. believed tn be correct as of the date hereof. Since this information may be applied under conditions beyond our control amd with which we may be unfamiliar and since data made available subsequent tn the date hereof may S. FIRE PROTECTION suggest modification o! the inforuatiou, va do not assume an~ responsibil- ity for the results of its use. This information is ~urnished upon condition that the person receiving it shall make his own determination FLASH POINT: (P-M) c -4.9F (-45C) of the suitability of the material for his particular purpose. AUTOiGNIT~ON: NDA FLAI~LABILITY LIMITS (t by volume in air): Lower: 1.4 Upper: 7.6 EXTINGUISHING MEDIA: Fire righting Foa~: Alcohol Resistant Type (AR) At?F, CO2, Dry ChemicaL. NFPA RATINGS: Health l; Flammability 3; Reactivity O~ Special NDA; (Least-O, Slight-l, Moderate-2, High-3, Extreme-4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association or, if applicable, the national Paint and Coating AssocLation, and do not necessarily reflect the hazard evaluation of the Chevron Enviror~ental Health Center. Read the entire document and label before using this product. FIRK FIGHTING PROCEDURES: Revision Ntmbet: 15 Revision Oate~ 08/06/91 HSOS NtmbeF: 001376 Revision Number: 1S Revision Datsc 08/06/91 HSDS Number: 001376 NDA - No Data Available NA - Not Applicable NDA - No Data Available HA - Not Applicable X-O0' X-OOSOZl Emergency Number (800)457-2022 or (510)233-3737 [ Uateriai Safety Data Sheet CHEVRON Unleaded Gasoline CPS20 Page 1 of 10 This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please ma~e sure this information is given to them. It also contains information to help you meet ,community right-to-know/emergency response reporting requirements under SARA Title III and many other laws. If you resell this product, this MSDS must be given to the buyer or the in:ornation incorporsted in your MSDS. Discard any previous edition of this MSDS. Revised to update Section 12 (Additional Health). 1. PRODUCT IDENTIFICATION CHEVRON Unleaded Gasoline DANGER: - IL~qI4FUL OR FATAL IF SWALLOWED - CAN ENTER LUNGS AND CAUSE O,U'~AGE - VAPOR HARMFUL - LONG-TERN EEPOSURE TO VAPOR HAS CAUSED CANCER IN LABORATOR]r ANIMALS - HAY CAUSE E]~E AND SKIN IRRITATION - EXTREMELY FLA~IABLE - KEEP OUT OF REACH OF CHILDREN PRODUCT ,~UMSER(S): CPS201110 PRODUCT .rNFOPJ4ATION: (800)582-383S Revision Number: 14 Revision Date: 09/12/91 HSDS Number: 000372 MOA - No Data Available NA - Not Applicable ×-~ CHEVRON Unleaded Gasoline Page 2 o! 10 2. FIRST AID - EMERGENCY ~UHBERi800)457-2022 OR (510)233-3737 ~YE CONTACT: Flush eyes immediately with fresh water for at least 15 minutes while holding the eyelids open. Remove contact lenses if worn. No additional first aid should be necessary. However, if irritation persists, see a doctor. No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. INHALATION: !f respiratory irritation or any signs or symptoms as described in this document occur, move the person to fresh air. If any of these effects INGESTION: If swallowed, give' water or milk to drink and telephone for medical advice. DO NOT make person vomit unless directed to do so by medical personnel. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. Note to Physician: Ingestion of this product or subsequent vomiting can result in aspiration of light hydrocarbon liquid which can cause pneumonitis. 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS 11 & 12) EYE CONTACT: This substance is slightly irritating to the eyes and could cause prolonged (days) impairment of your vision. The degree of the injury viil depend on the amount of material that gets into the eye and the speed and thoroughness of the first aid treatment. Signs and symptoms may include pain, tears, swelling, redness, and blurred vision. Eye contact with the vapors, fumes, or spray mist from this substance could also cause similar signs and symptoms. SKIN IRRITATION: prolohged or frequently repeated contact may cause the skin to become cracked or dry from the defatting action of this material. DER~RL TOXICITY: If absorbed through the skin, this substance is considered practically non-toxic to internal organs. RESPIRATORY/INHaLATION: This substance is slightly toxic to internal organs if inhaled. The degree of injury will depend on the airborne concentration and duration of exposure. The target organ(s) is the nervous system. Inhalation of gasoline vapor at airborne concentrations exceeding 1000 ppm may cause signs and symptoms of central nervous system effects such as headache, dizziness, loss of appetite, weakness and loss of coordination. Vapor concentrations in excess of 5000 ppm ~ay cause ioss of consciousness, coma and death. Brief exposures to high vapor concentrations may also cause pulmonary edema and bronchitis. Intentional exposures to excessively high Revision Number: 14 Revision Date: 09/12/9~ ~SOS Number: 000372 NOR - No Data Available NA - Not Applicable X-OOSO21 (01-89) CHEVRON Unleaded Gasoline Page 10 of l0 CHEVRON Unleaded Gasoline Page 3 of 10 pregnancy. The effects noted consisted of delayed development and minor concentrations (e.g., when used as a drug of abuse) have been reported to ske!et&l variatlons~ additionally, when pregnant mice were exposed by result in clinical manifestations that may include convulsions, deliria., ingestion to a level chat killed nearly one-third of the test group, and hallucinations. These manifestations are not known to occur following lethality (resorptions) and malformations (primarily cleft palate) accidental i~halation of gasoline vapor during normal operations. occurred. Malformations have not been reported following inhalation INGESTION: exposure. Because of the very high levels of exposure used in these This substance is slightly toxic to internal organs il swallowed. The studies, we do not believe that their results imply an increased risk of degree of injury will depend on the amount absorbed from the gut. The reproductive toxicity to workers exposed to xylene levels at or below the target organ(s) is the nervous system. Signs and symptoms of cen=ra~ exposure s~andafd, nervous system effects may include one or more of ~he following: headache, dizziness, loss of appetite, weakness and loss of coordination. X~lene has given negative results [n several mutagen testing assays Because of ~he low viscosity of ~h~s substance, ~t can directly enter the including the ~es as~y. In a cancer study sponsored by the ~ational lungs ~f [~ ~s swallowed (~h~s is called aspiration). This can occur Toxicology Progr~ (NTP), technical grade xylene gave no evidence of during ~he ac~ of swa~low~ng or when vomiting ~he substance. Once ~n =he carc~nogenici~y ~n ra~s or mice dosed daily for two years, lungs, the subs=ante ~s very difficu~ ~o remove and can cause severe This pr~uc~ contains methyl ter~ butyl e~her (MT~E). Mos= mu~agenic~y injury ~o the lungs and death. da~a on MTBE, excep~ for ~he ~n vitro mouse l~phoma ~es~, indicate tha~ l~ ~s no= mu~agenic. MTBE caused bir~h defects in mice exposed ~o 5,000 4. PROTECTIVE EQUIP~ p~ throuqhou~ pregnancy. No b~r~h defects were observed ~n mice a~ ~,000 ppm or in rats or rabbi~s a~ any dose of MTBE. These results sugges~ tha~ ~he risk of bir~h defects in h~ans from ~TBE is negligible at =he EYE PRO~ECTION: anticipated exposure concentrations. Do not 9er ~h~s ma~er~al in your eyes. Eye contac= can be avoided wearing chemical goggles. ~hole gasoline exhaus~ was reviewed by =he ~n=ernational Agency for SEIN Research on Cancer (I~C) in ~he~r Monograph Vol~e 46 (1~8~). Evidence ~o special skin project,on ~s usually necessary. Avoid prolonged for causing cancer vas considered inadequate in animals and ~nadequa=e in frequently repeated skin contact wi~h th~s material. Skin con~ac~ can be h~ans. ~ARC p~aced ~hole gasoline exhaust in Category 2B, considering i= minimized by wearing pro~ective clothing. possibly carcinogenic ~o h~ans. ~SPI~TORY ~o special respiratory project,on ~s normally required. However, operating conditions crea~e a~r~rme concentrations which exceed =he recommended exposure standards, ~he use of an approved respire=or is re~ired. Refer to ~he OS~ Benzene Standard =o determine wha~ =~e respirator is required based on exposure ~evels. ~I~TION: The above lnf0r~tion is based on ~he da~a of which we are aware and is Use this material only in well ventilated areas. believed ~o be correc~ as o~ the da~e hereof. Since ~h'is information may be applied under conditions beyond our coa~rol and vi~h ~hich we ~ay be unfamiliar and since da~a made available subsequen~ ~o ~he da~e hereof ma~ 5. FI~ PROTECTION suggest modification of ~he in~or~ioa, we do not assume anF responsibil- ity for ~he results of l~s use. This information IS ~urnished upon c6ndi=ioa tha~ =he person receivin9 l= shall make his own determination FLASH ~OI~: (P-M) c -49F of ~he sui~abili~F o~ ~he ~erial for his pa=~ic~a= purpose. AUTOIGNIT~ON: ~A FL~BILITY L~MITS (% by vol~e ~n air): Lower: 1.4 Upper= 7.6 EXTiNGUISHiNG MEDIA: F~re Fighting Foam= Alcohol Resis~an~ Type (~) AFFF, CO2, Dry Chemical. NFPA ~TINGS: Health 1~ Fla~abllltF 3;. Reactivity 0~ Special NDA= (Leas~-0, Slight-l, Modern=e-2, High-3,' Extreme-4). These values are obtained using ~he 9u~del~nes or published evaluations prepared by the National Fire ~ro=ect~on ~socla~on or, if applicable, the National 9a~2~ and Coating ~soc~a=ion, and do not necessaril~ reflect =he hazard evaluation of the Chevron Environmental Health Cen~er. Read the entire doc~en~ and label before using this product. FI~ FIG~ING Revision Nu~er: 14 Revision Da~e: 0~/12/91 ~DS N~er: 000372 Revision ~er: 14 Revision Da~e: 0~/12/~1 ~DS Nu~ef: 000372 NDA - No Da~a Available NA - No~ A~plicable NDA - No Data Available NA - No~ Applicable x-oOSl~l (01-89l CHEVRON Unleaded Gasoline Page t of l0 CHEVRON Unleaded Gasoline Page 9 of 10 This product presents an extreme fire hazard. Liquid very quickly model studied has shown these adverse kidney effects and there is no evaporates, even at low temperatures, and forms vapor (fumes) which can physiological reason to believe that they would occur in man. catch fire and burn with explosive,violence. :nvis[ble vapor spreads easily and can be set on fire by ~any ~ources such as pilot lights, The data above is obtained from studies sponsored by the American ye!ding equipment, and electrical motors and switches. Petroleum Institute (API). rot fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment. This may include 12. ADDITIONAL I~ALTH DATA self-contained breathing apparatus to protect against the hazardous effects of normal products of combustion or oxygen deficiency. Read the entire document. ~, ADDITIONAL HEALTH 0ATA COMMENT: COMBUSTION PRODUCTS: This product contains benzene. The OSHA Benzene Standard {29 CFR Normal combustion forms carbon dioxide and water vapor; incomplete 1910.1028) contains detailed requirements for training, exposure the exposure level. Refer to the OSHA Standard before using this product. 6. STORAGE, HAJdDLING, A~ REACTIVITT the development of chromosomal damage in experimental animals and various blood diseases in humans ranging from aplastic anemia to leukemia (~:form of cancer). AIl of these diseases can be fatal. No birth defects have HAZARDOUS DECOMPOSITION PRODUCTS: been shown to occur in pregnant laboratory animals exposed to doses not NDA. toxic to th6 mother. However, some evidence of fetal toxicity such as STABILITT: delayed physical development has been seen at such levels. The available Stable. information on the effects of benzene on human pregnancies is inadequate HAZARDOUS POLYMERIZATION: but it has been established that benzene can cross the human placenta. Polymerization will not occur. INCOMPATIBILITY: This product contains n-hexane. Prolonged or repeated skin contact or May react w~th strong oxidizing agents, such as chlorates, nitrates, breathing of vapors may cause nerve damage characterized by progressive SPECIAL PRECAUTIONS: recovery to complete recovery depending upon the severity of the nerve Never siphon gasoline by mouth. READ AND OBSERVE ALL PRECAUTIONS ON damage. PRODUCT LABEL. Use only as a motor fuel. Do not use for cleaning, pressure appliance fuel, or any other such use. DO NOT USE OR STORE near This product contains toluene. Toluene has been reported to decrease flame, sparks or hot surfaces. USE ONLY IN WELL VENTILATED AR~A. Keep im.~unological responses in test animals. It has also been reported that container closed. DO NOT TRANSFER LIQUID TO AN UNLASEL~D CONTAINER. DO when young rats were exposed to i000 p.cm~ toluene for la hours daily, for NOT weld, heat or drill container. Replace cap or bung. ~ptied container two weeks, irreversible hearing ~oss was detected. The same daily exposure still contains hazardous or explosive vapor or liquid, to 700 ppm for as long as 16 weeks was without effect. Since the level necessary to produce hearing loss is greater than 7 times the ACGIH'-' TLr-TWA for toluene, worker exposures at or below 100 ppm is not ex~ected 7. ~I~SICAL PROPERTIES to cause any adverse effects. There are also reports that chronic abusers (glue sniffers, solvent buffers) who deliberately inhale high concentrations (several thousand ppm) of toluene for prolonged periods (-up SOLUBILITY: Soluble in hydrocarbons; insoluSle in water, to ten hours/day) have suffered liver, kidney and brain damage. Toldene.. APPEARANCE: Orange to bronze liquid, may also cause mental and/or growth retardation in the children of female BOILING POINT: 25 - 225C (Variable) solvent abusers who directly inhale toluene when they are pregnant. MELTING POINT: NA Toluene caused growth retardation in rats when acim. inistered at doses that EVAPORATION: NbA were toxic to the mothers (1500 ppm). Concentrations of up to 5000 ppm SPECIFIC GRAVITY: 0.7 - 0.8. did not cause birth defects. There were no effects in the offspring at VAPOR PRESSURE: $ - 15 PSI (max.) @ 100F (Variable) doses that did not intoxicate the pregnant tats. The exposure level at PERC-:NT VOLATILE (VOLUME %): 99*% which no effects were seen (No Observed Effect Level, NOEL) is 750 ppm. We VAPOR DENSITY (AIR-I): 3-4 recommend that the precautions outlined in this MSDS be followed to keep This product contains xylene, a chemical that has been reported to cause developmental toxicity in tats and mice exposed by inhalation during Revision Number: 14 Revision Oats: 09/12/91 MSOS Number: 000372 Revision Number: It Revision Date: 09/12/91 MSOS Number: 000372 NbA - No Oata Available NA - Not Applicable NOA - No Data Available NA - Not Applicable x-oOSQ29 101-89! X-OOSC21 I01 CREVRO~ Unleaded 0asolise Page 8 o! I0 CHEVRON Unleaded Gasoline Page 5 of l0 XYLF~E-P is found on lists: XYLENE-M 8. ENVIRONMENTAL CONCERNS, SPILL RESPONSE ARb DISPOSAL is found on lists: 01,02010,11,!2,1¢,15,17010,25,28, TOLUENE is found on lists: 01,02.04.10,11,!2,13,:4,15,17,10,26,28,29, CHEMTREC EMERGENCY PRONE NUMBER: (800) 424-9300 (24 hour). ~EXANE SPILL/LEAK PRECAUTIONS: Is found off lists: 02,10,11,13,14,15,17,28, Eliminate all sources of ignition in vicinity of spill or released vapor. CY. CLOF~_XANE is found on lists: 01,02,10,!I,12,13,14,17,26,28, Clean up spills immediately, observing precautions in Protective Equipment METHYL TEnT BUTYL ETHER-.. section. This material is considered to be a water pollutant and releases is found on lists: 01,10,11,21,24,26, of this product shoul~ be prevented from contaminating soil and water and 5ENZENE from entering drainage and sewer systems. ~s found on llsts: 01,02,03.04,06,10,!1,12,13,14,17,18,20.28,29, KYLENE-O U.S.A. regulations require reporting spills of this material that could Is found on lists: 01,02,10,11,12,14,15,17,18,26,28, reach any surface waters. The toll free number for the U.S. Coast Guard GASOL:NE IGENERIC) National Response Center is (000) 424-8802. Is found on lists: 04,08,14,15,17,18,20, DISPOSAL METHODS: REGULATORY LISTS SEARC?~D: Clean up small spills using appropriate techniques such as sorbent materials-or pumping. Where feasible and appropriate, remove contaminated 01-SARA 313 02-MASS RTK 03-NTP Carcinogen soil. Follow prescribed procedures for reporting and responding to.larger 04-CA Prop. 65 05nMI 406 06-IARC Group i releases. Place contaminated materials in disposable containers and 07-IARC Group 2A 08-IARC Group 2B 09-SARA 302/304 dispose of in a manner consistent with applicable regulations. Contact 10-PA RTK il-NJ RTK !2-CERCLA 302.4 local environmental or health authorities for approved disposal of this 13-MN RTK 14-ACGIH TLV 15-ACGIH STEL material. 16-ACGIH Calculated TLV 17-osF~ TWA 18-OSF~ STEL 19-Chevron TLV 20-EPA Carcinogen 21-TSCA Sect 4(e) 22-TSCA Sect 5(a)(e)(f) 23-TSCA Sect 6 24-TSCA Sect 12(b) 9. EXPOSURE STANDARDS, REGULATORY LIMITS AND COMPOSITION 2S-TSCA Sect 0(a) 26-TSCA Sect 8(d) 28-Canadian 2g-OSHA CEILING COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control 11. PRODUCT TOXICOLOGY DATA Act Chemical Substances Inventory. The percent compositions are given to allow for the various ranges of EYE IRRITATION: the components present in the whole product and may not equal 100%. The Draize Eye Irritation Score (range, 0-110) in rabbits is 0. .: SKIN IRRITATION: P£RCENT/CASI COMPONENT/REGULATORY LIMITS The-Dralze Skin Primary Irritation Score (range, 0-8) for a 4-hour exposure (rabbits) is 0.98. This material was not a skin sensitizer in 100.0 % CHEVRON Unleaded Gasoline the modified 5uehler Guinea Pig Sensitization Test. DEI~tAL TOXICITY: CONTAINING The dermal iDS0 in rabbits is · 5 ml/kg. RESPIRATORY/INHALATION: 100.0 % GASOLINE {G-i~IERIC) No product toxlcology data available. 300ppm ACGIH TLV INGESTION: 500ppm ACGIH STEL The oral LOS0 in rats is · 5 mi/kg. 300ppm OSHA ADDITIONAL TOXICOLOGY DATA: 500ppm OSHA STEL Lifetime inhalation of whole gasoline vapor has caused increased liver tumors in female mice. The mechanism of this response is still being INCLUDING investigated but it is thought to be an epigenetlc process unique to the female mouse, inhalation exposure to whole gasoline vapor also caused < 1.4 % ETHYLBENZENE kidney damage and eventually kidney cancer in male rats. No other animal CAS10041¢ A toxic chemical subject to the reporting requirements of Revisio~ Number: 14 Revision Date: 09/12/~1 MSOS Number: 000372 Revision Number: 14 Revision Oats: 09/12/91 HSDS Number: 000372 I~A - No Data Available NA - Not Applicable NDA - No Data Available NA - Not Applicable x-OOS021 I01-89~ X-OQS~' CHEVRON U~e~4ed Gasoline Page 6 oL 10 C~EV~OH U~e~ded Gasolisn Page 7 of 10 Section 313 of Title III of the Sunerfund Amendments and Reauthorization Act of 1986 and 40 CFR ?art 372. Reauthor!zation Act of 1986 and 40 CFR Part 372. 300ppm oSHA .'WA 100ppm ACGIH TLV CERC~A 302.4 RQ-1000 POUNDS -.- 125ppm ACGIH STEL 100ppm OSHA TWA · 15.0 % MET~Y-L TERT BUTYL ETHER 125ppm OSHA STEL CAS1634044 A toxic chemical subject to the reporting requirements of CERCLA 302.4 RQ-1000 POUNDS Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. · 0.9 % XYLENE-P CASi06423 A tOXiC cnem~ca& ~uuj=~ ~ ...... ~ ...... ~ --~--- Section 313 of~.Title III of the Superfund Amendments and · 4.9 % BENZENE Reauthorization Act o~ 1986 and %0 CFR Part 372. CAS71%32 A toxic chemical subject to =he reporting requirements of Section 313 of Title III of the Superfund Amendments and 180 ppm ACGIH STEL aeauthorization Act of 1986 and ~0 CFR Part 372. CERCLA 302.% RQ-1000 POUNDS 10ppm ACGIH TLV lppm OSHA TWA · 4.6 % xYLENE-M 5opm OSHA STEL CAS108383 A toxic chemical subject to the reporting requirements of - Section 313 of Title I~I of the Superfund Amendm. ents and 28 ppm OSHA CEILING Reauthoriza=ion Act of 1986 and 40 CFR Part 372. CERCLA 302.4 hQ-10 POUNDS 100ppm ACGIH TLV Refer to th% OSHA Benzene Standard (29 C~R. 1910.!028) for detailed 150ppm ACGIH STEL training, exposure monitoring, respiratory protection and medical 100ppm OSHA TWA surveillance requirements before using this product. 150ppm OSHA STEL CERCLA 302.~ RQ-1000 POUNDS TLV - Threshold Limit Value TWA - Time Weighted Average STEL - Short-term Exposure Limit TPQ - Threshold Planning Quantity · 2.2 % XYL-2NE-O CAS95476 A toxic chemical subject to the reporting requirements of RQ - Reportable Quantity CPS - CUSA Produc~ Code Section 313 of Title III of the Su9erfund Amendments and CC - Chevron Chemical Company CAS - Chemical Abstract Service Number Reauthorization Ac: o~ 1986 and 40 CFR Par: 372. 100ppm ACGIH TLV 10. REGULATORX INFORMATION 15099m ACGIH STEL 100ppm OSHA TWA I$0ppm OSHA STEL DOT basic descriptions can vary based on package quantity and may not C~RCLA 302.4 RQ-1000 POUNDS coincide ~ith international description requirements. Consult the Hazardous Materials Regulations in %PCFR and the appropriate Dangerous · 8.5 % TOLUENE · CAS108883 A toxic chemical subject to the reporting requirements of Goods Regulations to confirm description applicability to specific Sectio~ 313 of Title III of the Superfund A~endments and shipments. ~ Reauthorization Act of 1988 and 40 CFR Part 372. DOT SHIPPING NAME: GASOLINE 100ppm ACGIH TLV DOT HAZARD C~-ASS: FLAMMABLE LIQUID 150ppm ACGiH STZL DOT iDENTIFICATION NUMBER:. UN1203 .r. 100ppm OSW~ TWA ~a~ 150ppm OSHA STOL SA~A 311 CATEGORIES: 1. Immediate (Acute) Health Effects; YES 300 ppm OSHA CEILING 2. Delayed (Chronic) Health ~ffects; YES CERCLA 302.4 RQ-1000 POUNDS 3. Fire Hazard; YES 4. Sudden Release of pressure Hazard; NO · 3.0 % HEXARE 5. Reactivity Hazard; NO CASl!05¢3 $0ppm ACGIH TLV 1000 ppm ACGIH STEL The following comporients of th~s material are found on =he regulatory 80ppm OSHA TWA lists indicated by the number below the component name: · 2.4 % CYCLOHEXANE CASl1¢827 A toxic chemical subject to the reporting requirements of ~THY-LSERZ=-NE Sec=ion 313 of Title III of the Superfund Amendments and is found on lists: 01,02.10,11,12,13,14,15,17,18,26,28, Revision Number: 14 Revision Da:e: 0~/12/91 HSDS Number: 000372 Revisioo Numbe~: 14 Revision Da~e: 09/12/91 HSDS Number: ~00372 MOA - No Da:a Available HA - No~ ApplicabLe NDA - Ho Da~a Available NA - Ho~ AppLicable X-OOS~I X-005~21 (01-89! Emergency Rubber (800)457-2022 or (415)233-3737 Material Safety Data Sheet CHEVRON Supreme Motor Oil SAg 20W-50 CPS220060 Page I of 7 This Haterial Safety Data Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is give, to them. It also contains information to help you meet community right-to-knov/emergency response reporting requirements under SARA Title III and many other lays. If you resell this product, this HSDS must be given to the buyer or the information incorporated in your HSDS. Discard any previous edition of this HSDS. Revised to update Section lO - DOT Information. 1. PRODUCT IDENTIFICATION CHEVRON Supreme Notor Oil SAg 20R-50 - A HAZARD WAR~IING IS NOT REQUIRED FOR THiS PRODUCT UNDKR OSHA HAZARD COHNUNICATION STAI4DARD (29 CFR 1910,1200) PRODUCT NUMBER(S): CPS220060 PRODUCT INFORHATION: Revision Number: I Revision Date: 12/22/90 MSDS Number: 004452 NDA - Ho Data Available HA - Hot Applicable X -OO~S(~I {06 Supreme Notor Oil ShE 20W-50 Page 2 of 7 CHEVRON Supreme Notor Oil SAS 20W-50 Paqe 7 of 7 2. FIRST AID - EMERGENCY NU~(BER (800)457-2022 OR (415)233-3737 The above information is based on the data believed to be correct as of the date hereof. Since the information contained heteis may be applied under conditions beyond our control and EYE CO~TAC?: with which we may be unfamiliar and since data made available subseguent No first aid procedures are required. However, as a precaution flush eyes to the data hereof may suggest modification of the information, ye do not with fresh water for 15 minutes. Remove contact lenses if yom. assune any responsibility for the results of its use. This information is SKIN CONTACT: furnished upon condition that the person receiving it shall make his nun thoroughly v~th soap and~vater. Remove and rash contaminated c~othing, purpose. :Z resp/rator~ discomfort or ~rritation occurs, move the person ~o ~resh a~r. See a doctor if disco;~orc or ~rri~ation continues. INGESTION: If sun,loved. ~ive va~er or milk to dr~nk and telephone for ;ed~ca~ advice. Consult medica~ personnel before inducing vomiting. [~ ~edical advLce cannot be obtained, then take the person and product container co the nearest med~ca~ emergenc7 treatment center or hospital. 3. I~DIATS ~TH EFFECTS - (~SO SEE SECTIONS 11 & 12) _ EYE CONTACT: This substance is not expected to cause prolonged or significant eye irritation. This hazard evaluation is based on the data from similar materials. SEIN IRRITATION: This substance is not expected to cause prolonged or significant skin irritation. This hazard evaluation is based on data from similar materials. '" DERMAL TOXICITY: The systemic toxicity of this substance has not been determined. However, it should be practically non-toxic to internal organs if it gets on the skin. This hazard evaluation is based on data from similar materials. RKSPIRATORY/II~.ALATION: The systemic toxicity of this substance has not been determined. However, it 'should be practically non-toxic to internal organs if inhaled. This hazard evaluation ~s based on data from similar ~aterials. iN~ES¥iON: The systemic toxicity of this substance has not been determined. However, it should be practically non-toxic to internal organs ~f swallowed. Th~s hazard evaluation is based on data from similar materials. 4. PROTECTIVE EQUIPJ4ENT EYE PROTECTION: No special eye protection is usually necessary. SKIN ~ROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated skin contact with this material. Skin contact can be Revision Number: ! Revision 9ate= 12/22/~0 NSDS Number: 004452 Revision Number: 1 Revision Date: 12/22/90 NSDS Number: 004452 NDA - No Data Available NA - Not Applicable NDA - No Data Available ~A - Not Applicable X-O0S021 t01-89) x-00S~ CHEVROH Supreme Motor Oil SAm 20#-50 Page 4 et ? CHEVRON Supra.e Hotor Oil SAm 20W-50 Page 5 et 7 100.0 % CMEVRON Supreme Motor Oil SA~ 2OW-50. 7. PHYSICAL PROPERTIES CONTAINING SOLUBILITY.: Soluble in hydrocarbon solvents; insoluble in rater. > 80.0 % LUBRICATING BASE OIL ~P~cE: ~er liquid. ~OILIN~ POINT: NA The BASE OIL may be a mix~ure of anF of the following: CAS 64741884, MELTIN~ POINT: NA CAS ~4741895,C~ ~4741954,CAS ~4741975,CAS 6474~014,CAS ~474252S, EVAPO~TION: NA ~ CAS 64742536,C~ 647~2547,C~ 64742627,CAS ~4742650,C~ 72623837. SPECIFIC G~VITY: 0.85 ~15.6/!5.6C VA~OR 9~SSURE: NA ~ ~0.0 % ~DITIVES INCLUDING T~ FOLLOWING PERC~ VO~TILE (VOL~E %): NA VAPOR D~SI~ (AIR-i): NA ~ 2.0 % ZINC A~YL DITHIO~HOSP~TE ' ' VISCOSI~: 15.4 cS% ~ 100C (Min.) CAS6864942~ A toxic chemical subject =o the regor=ing re~ireme~:%. Section 3!3 of Title Iii of ~he Su~erfund ~en~en~s and Reau=horiza=ion AC: of 1986 and 40 CFR Part 372. 8. ~IRO~TAL CON~S, SPILL ~SPONSE ~ DISPOS~ r' TLr - Threshold Limi: Value ~A - Time weighted Average STEL - Shor=-=erm Exgosure ~imit TPQ - Threshold ~lanning Quan~i~y ~C ~G~ PHONE ~BEH: (809} 424-~30~ (24 hour). RQ - ~epor~able Quan=i~y CPS - CUSA ~roduc: Code SPILL/L~ ~UTIONS: CC - Chevron Chemical Company ~s - Chemica~ Abs~rac~ Service?N~er This material [s no~ expected to presen: a~ enviro~en~al proble~ o~her than :hose associated wi~h oi~ spills. "' 10. ~GULATORY INFO~TION Stop the source of the leak or release. Clean up re~eases as soon as ~ssible. Contain ~iquid ~o prevea~ further con~ina~ion of soil, - surface wa~er or groundwater. Clea~ up small spills using appropriate ._ DOT SHIPPING N~= N~ D~IGNAT~ ~ A ~OUS ~TZKIAL BY techniques such as sorben: materials or p~pinq. Where feasible and F~E~L D~ appropria:e, remove con~ina~ed soil. Follow prescribed procedures for DOT ~ C~S= NOT ~PLI~BLE re~r~ing and res~nding to larger releases. DOT ID~IFI~TION N~BER: N~ ~PLICABLE DIS~S~ODS: Place con~inaZed materials in dis~sable containers and disuse of in a S~ 311 ~TEGORIES= 1. I~ediaze (Acute) Health Effects; manner consistent with applicable regulations. Con~ac: local 2. Delayed (Chro~ic) Health Effects; enviro~en:a1 or health authorities fo~ approved disposal of this 3. Fire Hazard~ NO material. 4. Sudden Rele~e of Pressure Hazard; 5. React~vi~F Hazard; NO~ The following com~nen:s of ~his material are found on :he regulatory lis~s indicated by ~he a~er below the componen~ 9. EXPOSU~ ST~S, ~GULATORT LIMITS ~ CO~OSITION ZINC ALKYL DI~IOPHOSP~TE is found on lis~s: 01,10,~, COMPOSITION CO~T: All the com~nen~s of :his material are on ~he Toxic Substances Con~rol ~GU~TOR~ LISTS Ac~ Chemical Substances Inventory. 01-s~ 313 02-~S R~ 03-~P Carcinogen This pr~uc~ fits =he ACGIH definition for minera~ oil mis:. The ACGIH 04-CA Prop. 65 0S-MI 406 06-I~C Group 1 TLr is 5 mg/m3, ~he OS~ PEL is 5 mg/m3. 07-[~C Group 2A 08-[~C Group 2B 09-SA~ 302/304 10-PA R~ i~-NJ R~ 12-CZRC~ 302.4 The 9ercen= c~st~ions are given =o allow fo= the vario~ ranges of 13-~ RTK I~-ACGIH TLV 15-ACGIH STEL the componen:s presen= ~n the ~hole 9=oduc: and may hoc equal 100%. 16-ACGiH Calculated TLV 17-OS~ ~A 1~-OS~ STEL 19-Chevron TLV 20-EPA Carcinogen 21-TS~ Sec~ P~C~/~o ~/~U~RY LIMITS 22-TS~ Sec: 5(a)(e)(f) 23-TS~ Sec: 6 24-TSCA Sec: 12(b) Revisioa N~er: 1 Revision Da~e: 12/22/$0 ~DS Numar: 004452 Revision N~r: 1 Revision Da~e: 12/22/90 ~DS Nu~er: 004452 ~A - No DaZa Available NA - ~oZ AppLicable '~A - ~o DaZa AvaL~ab~e ~ - Not CHEVRON Supreme Motor Oil SAE 20N-50 Page 3 o! 7 CHEVRON Supreme Motor Oil SAE 20N-50 Page 6 o[ 7 minimized by veering protective clothing. 25=TSCA Sect 8(a) 26=TSCA Sect 8(d) 27=TSCA Sect 8(e) RESPIRATORY PROTECTION: 28=Canadlan WHHIS 29-OSHA CEILING 30-TSCA Sect 8 FYI No special respiratory protection is normally required. However, if operating conditions create airborne concentrations which exceed the reconvnended exposure standards, the use of an approved respirator is ll. PRODUCT TOXICOLOGY DATA required. VENTILATION: Use adequate ventilation to keep the airborne concentrations of this EYE IRRITATION: material below the recommended exposure standard. No product toxicology data available. The hazard evaluation was based on data from similar materials. SEIN IRRITATION= 5. FIRE PROTECTION No product toxicology data available. The hazard evaluation was based on data from similar materials. DERNAL TOXICITY: FLASH POiNT~ ' .... 410F ( .... · ":- No product toxicology data available. The hazard evaluation vas based on AUTOIGNITION= NDA data from similar materials. ~L~A=ILITY t ~_ i~ -~-~' ' ~'* " *'~ LIH[T= ,% "-* REEPIRATORY/II~{ALATION: EXTINGUISHING MEDIA: No product toxicology data available. The hazard evaluation was based on CO2, dry chemical, foam and rater fog. data from similar materials. NFPA RATINGS: Health 0; Flammability l; Reactivity 0; Special NDA~ INGESTION: I~IS RATINGS: Health O; Flan~ability ~ Reactivity 0; Other No product toxicolog~ data available. The hazard evaluation ~as based on (Least-O, Slight-1, ~oderate-2, High-3, Extreme-4). These values are data from similar materials, obtained using the guidelines or published evaluations prepared by the National ~ire Protection Association or, if applicable, the National Paint and Coating Association, and do not necessarily reflect the hazard ~2. ADOITIOEAL EEALTE DATA evaluation of the Chevron Environmental Health Center. Read the entire document and label before using this product. FIRE FIGHTING PROCEDURES: ADDITIONAL HEALTH DATA COl~lElqT: T For fires involving this materiel, do not enter any enclosed or confined This product contains zinc alkyl dithiophosphates (ZDDPs). Several ~DDPs fire space ~lthout proper protective equipment, Including self-contained have been reported to have weak mutagenic activity in cultured ma~alian breathing apparatus. cells but only at concentrations that were toxic to the test cells. ~e do COMBUSTION PRODUCTS: not believe that there is any mutagenic risk to workers exposed to ZO~Ps. ~ormal combustion forms carbon dioxide, ~ater vapor and may produce oxides of sulfur, nitrogen and phosphorous. Incomplete combustion can*produce This product contains petroleum base oils ~hich may be refined by various carbon monoxide. processes including severe solvent extraction, severe hydrocrackiflg; or severe hydrotreating. ~one of the oils requires a cancer ~arning under the OSHA Hazard co~unication Staodard (29 C~R ~10.1200). These oils 6. STORAGE, HANDLING, AND REACTIVITY have not been listed in the ~ationel Toxicology Program (~TP) Annual Report nor have they been classified by the International Agency for Research on Cancer (IARC) as; carcinogenic to humans (Group 1), probably HAZARDOUS DECOMPOSITION PRODUCTS: carcinogenic to humans (Group 2A). or possibly carcinogenic to humans NDA (Group 2B). STABILITY: During use in engines, contamination of oil with lo~ levels of Stable. cancer-causing combustion products occurs. Used motor oils have been HAZARDOUS POLYMERIZATION: s~own to cause skin cancer in mice following repeated application and Polymerization vii! not occur. INCOMPATIBILITY: continuous exposure. Brief or intermittent skin contact with used ~otor ~ay react with strong oxidizing a~ents, such as chlorates, nitrates, oil is not expected to have serious effects in humans if the oil is peroxides, etc. thoroughly removed by washing with soap end water. See Chevron Material SPECIA~ PRECAUTIONS: Safet~ Data Sheet No. 1793 for additional information on used motor oil. DO NOT weld, heat or drill container. Residue may ignite with explosive violence if heated sufficiently. CAUTIONI Do not use pressure to empty drum or explosion may result. Revision Number: ! Revision Date: Z2/22/90 MSDS Number: Revision Number: ! Revision Date: ~2/22/g0 MSDS Number: 004452 MOA - No Data Available RA - Not Applicable NDA - No Data Available NA - Mot Applicable x-OOS~I fl31 X-OOSD21 i01-89} O¢ U S Chemical MATERIAL SAFETY DATA'SHEET SECTION I - MANUFACTURER OR SUPPLIER DATA usg~llz 757z MANUFACTURER'S NAME & MAIUNG AOORESS PREPARED BY ~ SIGNATURE U S Ch~mlcal - A DlVlSION OF HYDRITE CHEMICAL CO. Do E° Kenas~)~ ~- . ~ S 316 Hart Street ~L~ I DATE Watertown, W Iscons In 53094 USA Qua I I ty Assurance ManagerI 5-15-91 EMERGENCY TELEPHONE NO. (24 HOUR SERVICE) PRODUCT INFORMATION TELEPHONE NO. (8-5 CST) Medical Emergency ONLY: 1-800-228-5635 Ext. 075 Product Information: 1-800-558-9566 SECTION 2 - IDENTITY OF MATERIAL PRODUCT NAME PR011ne HEAVY DUTY WHITEWALL CLEANER POWDER PRODUCT DESCRIPTION FORMULA ~ CHEMICAL FAMILY Powder Whitewal I Cleaner Proprietary BlendI N.A. DOT PROPER SHIPPING NAME " Corrosive Solid, N.0oSo (Contains Sodium HydrOXide) REGULATED IDENTIFICATION SHIPPING ID NUMBER I HAZARD CLA~ UN17.59I CorrosI ye Meteria I , SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS BOILING POINT SPECIFIC GRAVITY (H2O = 1) PHYSICAJ_ FORM COLOR M.A. N.A. Granular Powder Orange VAPOR PRESSURE (mm Hg) MELTING POINT SOLUBIUTY IN WATER SCENT N.A. N.A. Moderate Pine VAPOR DENSITY (AIR = 1) EVAPORATION RATE pH ~ ppm SOLUTION pH CONCENTRATE M.A. CB~,,.T~'.L ACETATE = 1) /2.1 N.A. OTHER Product ,urns yel Iow when wet. SECTION 4 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION HAZARDOUS COMPONENTS OSHA ACGIH OTHER UMITS PERCENT (CHEMICAL NAME: COMMON NAME) PEL TLV RECOMMENDED Sodium Hydroxide: Caustic Soda 2 mg/m5 2 mg/m3 None 35.0 CAS Registry Number 1310-73-2 Ceiling Value Ceiling Value This product contains no other Ingredient considered hazardous according to the criteria of 29 CFR 1910.i200, OSHA. However, this product contains chemlcals which may be subject to reporting requirements eccordlng the criteria of SARA Title III, 40 CFR, Part 570, Sectlon 311 and Section 512. NFPA RATING: Health-5/Flammabl I lty-O/Reactlvlty-i 1441S RATING: Health-3/Flammabl I Ity-O/Reactlvlty-1 CARC INOGEN lC I TY: Thls product does not contain any known carcinogens or anticipated carcinogens according to the criteria of the NTP Annual Report on Carcinogens, IARC Monographs, and OSHA 29 CFR 1910, Subpart Z. (CONTINUED ON REVERSE SIDE) S VsEcTIoN 5 - SAFE USAGE DATA EYES Splash-proof safety glasses, safety goggles, and an eye-~ash station. PROTECTIVE EQUIINMENT RE SPIRATORY IGLovES ~uD~er (La'tax) * T~S Dust n~sk for handl lng greater than 25 lbs. Protective Cuff o~ Gauntlet Type Preferred. OTHER Wear ful I-cover protectlve clothing to prevent repeated or prolonged ccetact. GENERAL MECHANICAL Satisfactory. Maintain adequate ventilation. Keep levels belo~ m=omnended TLV. LOCAL EXHAUST NOt ordlnarily needed. Avoid inhalati~ of dust coetaining this pn~duct. HANDLING&STORAGE Fei IOW al I label di rec?lonso Instruct personnel al~OUt proper use, hazards, precautions, and first-aid measures. Avoid Inhalation, ingestion and c~ntact with skin and eyes. PRECAUTIONS Do not use on aluminum. Rotate stock regularly° Handle careful ly 'to avoid damaging container. Keep container closed when not In use. Reca~ended storage temp. below 100® F. Keep out of SECTION 6 - HEALTH HAZARD DATA INHALATION Inhalation of dust or mist containing this product may ca,asa irritation to nose, throat, and mucous membranes, tissue damage, and pulmonary Irritation. EFFE~Ir~OF INGESTION Hamful or fatal If swallOWed. Nay cause discomfort, nau:see, vomiting, and severe tissue ~xposbRE dmage to mouth, esophagus, stomach, and to other tissues. Corrosive to mouth, throat and stomach. SKIN&EYES SKIN: Contact may cause severe irritation, dermtitis, and chemical bums. Corrosive. EYES: *Contact may cause tearing, severe Irrltation, burning, vision Icss, and blindness.. ACUTE&CHRONIC ACUTe: Corrosive to all body tissues. Hamful skin 4~ntact may not cause imn~llate pain. CHRONIC: NOne Known. nom~soF II~GESTION-X SKIN ABSORPTION- TARGETORG~NS mY SKIN-X EYES-X INHALATION-X Eyes, Skin, Respiratory System. SECTION 7 - PHYSICAL HAZARD DATA LEL = N.A. ] FLASH POINT = N.A. ME~HOU USEU = N.A. ;L~Ua~tn~ UEL = N.A.I ' STABLE CONDITIONS TO AVOIO Mixing with any other cleaning pmxluc3'. Mix only with <1~0'. F. X water.. Avold temp. >I00' F. and hlgh humldifY to prevent caking. STABIUTY UNSTABLE HAZARDOUSOECOMPOSITIONPROOUCTS Mixing with Incompatible materials may produce hydrogen, ca~bon monoxide, carbon dioxide, and other toxic and irrltating fumes. MAY OCCUR CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION WILL NOT OCCUR X , N.A. MATERIALS TO AVOIO Acidic materials, organic chemicals, and various ;~etals (almin~n, magneslm, ,~cou~TIs,u~ zinc, tin, brass or bronze) which can generate flammable hydrogen gas. SECTION 8 - EMERGENCY RESPONSE DATA · EXTINGUISHING MEDIA For fi res in area, use appropriate media. For examp~le: Water spray, dry chemical, carbon dioxide, or alcohol foam. FIRE SPECIAL PROCEDURES Use protective clothing and a self-contained breathing apparatus should be worn by fire flghte~s in areas where product Is being stored. UNUSUAL HAZARDS PIG, ducT may react with s~me.metals such as aluminum, ;:inc, Tin, etCo~ To release flammable hydrccjen gas. INGESTION= Do not induce vomiting. If patient is conscious and can s~allow, ad~ainlster milk or ware. SKIN.- Remove contaminated clothes, flood with water for 15 minutes. I-:YES: Floo~ with lukewarm (not RRST~JD hot) water poured from a large glass Z or~ Inches trom eyes. Kemove conTacTs. Have paTienT bi InK as ME~SUB;S much as possible while flooding the eyes. Continue for 15 minutes. II~IAL~ION: Nova vlctlm to fresh air. Give ar, ificlal resplratlon If patient is not bresthlng. A~IINI.~ilI~ FIRST ~lO 1REA~acNT AS STATED ABOVE, THEN CALL 1--8(X)-"~8-5635 Ext 075 ~R CONTACT PHYSICMN I"~ FURR*IER NEDICAL INS1RUCTIONS STEPS TO BE TAKEN Use proper protective equipment. Carefully sweep up arid shovel Into dry s~,t~s coctalners without reislng dust. Cover containers and move contairmrs out o'F spl II area. Re Flush area with ~a,er and follow with normal clean-up procedures. -,~ WASTE DISPOSAL METHOD Comply wl,h all federal, sta,e, and local regula,lons. Com;ult s,a,e and local au,hori,les for restrlctlons on disposal of chemical waste. 1HE DATA IN THIS MATERIAL SAFETY DATA SHEET RELATES ONLY TO THE SPEORC MATERIAL DESIGNATED AND DOES NOT RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR PROCESS. THE DATA CONTNNEO iS BELIEVED TO BE ACCURATE. HOWEVER. SINCE USE ~ITIONS V/tRY AND ARE OUTSIDE OUR CONT~[:)L U S OIEMIC/~ · A DIVISION OF HYORITE [:3~cMI~AL CO. M/~ES NO WARRANTIES. EXPRESSED OR IMPUED. AND ASSUMES NO LIABILITY FOR FAILURE TO FOLLOVV PRODUCT USE I[:)IRECTIO~S AND SAFETY PRECALm0~s. O~U S Chemical M )i'ERIAL SAFETY DAT. SHEET SECTION I - MANUFACTURER OR SUPPLIER DATA us93~ 1z 779z xx MANUFACTURER'S NAME & MAILING AOORESS PREPAREO BY SIGNATURE U S Ch~lcal - A DIVISION 0F ,YORITE C,~ICAL C0.'ID. E. Kenas' ''1~ Z. ~ j 316 Ha~ Street ]m TITLE DATE Watertown, Wisconsin 53094 USA ~Oual Ity Assurance Manager ~ 3-15-93 EMERGENCY TELEPHONE NO. (~4 HOUR SERVICE) ~ PRODUCT INFORMATION TELEPHONE NO. [8-5 CS~ Medical ~er~enc~ ONLY: i-800-228-5635 Ext. 075 ~Product Info~atlon: 1-800-558-9566 SECTION 2 - IDENTITY OF MATERIAL PRODUCT NAME PRODUCT DESCRIPTION FORMULA ~ CHEMICAL FAMILY High ~ual Ity Car Wash Detergent Proprleta~ Blend~ N.A. DOT PROPER SHIPPING NAME Not Regulated by D.0.T. REGULATED IDENTIFICATION SHIP.NO ID NUMBER ~ ~RD CLA~ SECTI ON 3 - PHYSlOA~OHEMIOAL CHARACTERISTICS BOILING ~INT SPECIFIC GRAVITY [H~ = 1~ PHYSICAL FORM COLOR N.A. N.A. ~Oranular Powder Blue VA~R PRESSURE [~ H~ MELTING ~INT SOLUBILITY IN WATER SCENT N.A. N.A. M~erate None Added VA~R DENSITY (AIR = 1) EVA~TION RATE DH 2~ ~ SOLUTION DH CONCENTRATE (BUTYL ACETATE = 1) OTHER Pr~ucf has a sIIqht s~l'vent odort SECTION 4 - HAZARDOUS INOREDIENTS/IDENTITY INFORMATION H~ARDOUS COM~NENTS OSHA ACGIH OTHER LIMITS PERCENT [CHEMIC~ NAME: COMMON NAME) PEL TLV RECOMMENDED Sodl um Metasl I Icate Not Not 2 mg/~ TWA CAS Registry Number 6834-92~ Establ Ished Establ Ished (Diamond Shamr~k) 2~utoxyethanol: Butyl Cellosolve ~5 ppm 25 ppm None ~.0 CAS Reglst~ Numar i11-76-2 TWA-Skin TWA-Skin This product contains no other Ingredient considered hazardous according to the criteria of 2~ CFR'1910.1200~ O~A. However~ this pr~uct contains ch~lcals ~hlch may be su~iect to repo~lnq requlr~ents accordinq to the criteria of S~ Title III, 40 CFR, Pa~ 370, Section 311 and Section 312. This product also contains ch~lcals which ~y be subject to repo~lnq requlr~ents accordlnq to the crlferla of S~A Title III. 40 CFR, Pa~ 372~ Section 313. NFPA RATING: Health-2/Flammabl I lty-0/Reactlvlty-0 HM{S RATING: He~lth-2/Flammabll Ity-0/Reactlvlty-0 CARCINOGENICITY: This Droduct does not contain any known carclno~ens or anticipated carcinogens accordln9 to the criteria of the NTP Annual Repor~ on Carcinogens, IARC Monographs, and OSHA 29 CFR 1910, Subpart Z. (CONTINUED ON REVERSE SIDE) I J SECTION 5 - SAFE USAGE DATA EYES Safety glasses and an eye-wash station. PROTECTtYE EQUIPMENT RESPIRATORY I GLOVES If prolonged contact is anticipated, wear Z~PES Dust mask for handl lng greater than 25 lbs.I rubber gloves. ' -'_ OTHER Wear ful I-cover protective clothing to prevent repeated or prolonged contact. GENERAL MECHANICAL Satisfactory. Maintain adequate ventilation. Keep levels below r,~commended TLV. VENTILATION LOCAL EXHAUST NOt ordlnarily needed. Avoid Inhalation of dust containing this product. HANDLING&STORAGE FOI Iow all label dlrectlonso Instruct personnel about prop,ur use, hazards, precautions, and firsl~ald measures. Avoid Inhalation, Ingestion and contac-~ with skin and eyes. PRECAUTIONS Rotate stock regularly. Handle carefully to avoid damaging container. Keep container closed when not in use. Recommended storage temp. below 100' F. Keep od? of chlldranls reach. SECTION 6 - HEALTH HAZARD DATA ,NHALAT~ON Inhalation of dust containing this product may cause irrl'tation to nose, throat, and mucous membranes. EFFECT~OF INGESTION May cause nausea, vomiting, and tissue damage to mouth, esophagu.s, stomach, and to other EXPOSURE tissues wI.~h which contact Is made. S~(IN&EYES SKIN: Contact may cause mild to severe Irritation, dep~rding on d~Jree of exposure. EYES: Contact may cause tearing, severe irritation; burning, vlslon loss, and bllndnesso ACUTE&CHRONIC ACUTE: Irritant to skin and eyes. Prolonged eye cor~tac't may cause permanent damage. CHRONIC: None Known. RourmsaF INGESTION-X SKIN ABSORPTICN- TARGETORG~NS FJ~mv SKIN-X EYES-X INHALAT I 0N-X Eyes. SECTION 7 - PHYSICAL HAZARD DATA LEL = N.A. J. FLASH POINT = N.A. NElrHOD USED = N.A. FLAMMAIUTY UEL = N.A. STABLE CONDITIONS TO AVOID Avoid mixi'ng with any other, cleaning product. Mix only with water~ X Avoid temp. >100° Fo and hlgh humidity as these Conditions contribute to caklngo UNSTABLE HAZARDOUS DECOMPOSITION PROOUCTS Warnlngl Mixing with iricomptible materials may produce carbon dioxide, hydrogen., and other toxic arid Irritating fumes. MAY OCCUR CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION WILL NOT OCCUR X , MATERIALS TO AVOID INCOMI~TIBIUTY Acidic materials and oxidizing agents. SECTION 8 - EMERGENCy RESPONSE DATA ·EXTINGUISHING MEDIA For fires in area, use appropriate media. For e~ample: Water spray, dry chemical, carbon dioxide, or alcohol foam. FIRE SPECIAL PROCEDURES Evacuate area of unprotected and unnecessary personnel. UNUSUAL HAZARDS NOt App I icabl e. INI~ESTI(IJ: Do not induce vomiting. I~f. patient is conscious and can s~allow, administer milk or water S~IN.- Remove contaminated clothes, flood wi~h water for 15 minutes. I-_'~.S: FIo~J with lukewarm (no? FmS~U hot) water poured from a large glass 2 or 3 Inches from eyes. Remove contacts. Have patient bi ink as MEASURE~ much es possible while flooding the eyes. Continue for 15 minutes. II~I&LATI(~I: f4ove victim to fresh air. Give artificial respiration{ If patient is not breathing. AI~II#I.5~ER FIRST AID TREATNENT AS STATED N)0VE, ~TIEN C/iLL !-800-228-5635 F. xt 075 OR (~r~tCT PHYSICINt FOR FIJRTHER I~DICAL INSTRUCTIONS STE~TOBI-'TAKEN ~e proper protective equipment. Carefully sweep up arid shovel ifnto containers without raising dust. Cover containers and move containers out o1~ spill area. Re ~- Flush area with water and tGI Iow with normal clean-up procedures. WASTEOISPOSALMETHOO Ccmply with all federal, state, and local rogulations,, Consult state and local -- authorities for restrictions on disposal of chemical waste. '--.~" llqE DATA IN 3HtS MATERIAL SAFETY OATA SHEET RELATES ONLY TO THE SPECIRC MATERIAL D~SiGNATED AND OOES NOT RELATE TO rr~.; USE IN COMBINaTiON WITH ANY OTHER MATERIAL OR PROCES~ THE DATA CONTAINED IS BEUEVED TO BE ACCUPJtTE HOWEVER. SINCE USE CONDITIONS VARY AND ARE OUTSIDE OUR (Z~TROL U S CHEMICAL · A 0MSION OF HYDRll~ CHFJvlICAL CC[ ~ NO WARRANTIES. EXPRESSED OR IMPUFJ3. AND ASSUMES ~ llABItJTY FOR FAIUJRE ~13 FOUJ3W PRODLIC~r USE DIRECTIONS AND SAFESt PRECAUTIONS. s Chemic , M FERIAL SAFETY DATAHEET SECTION I - MANUFACTURER OR SUPPLIER DATA us~z 7~z ~NUFACTURER*S NAME & MAILING ADDRESS J PREPARED BY J SIGNATURE U S ~emlcal - A DIVISION OF HYORITE CH~I~L CO. ~O. E. K~nas ~~ ¢. K~ I 316 ~ Strut ~ TITLE ~ DATE Wate~own, Wlsc~sln 53094 USA, lQual lty Assuranm ~nager ~ 5-15-91 EMERGENCY TELEPHONE NO. (24 HOUR SERVICE] ~ PRODUCT INFORMATION TELE~ONE NO. (8-5 CS~ ~dl~l ~ergency ONLY: 1-800-~8-5635 ~. 075 lPr~t Info~atl~: 1-800-558-95~ SECTION ~ - IDENTITY OF MATERIAL PRODUCT NAME ~01 Ina SPEE~FF LIQUID P~OUCT OES~ON ~ FORM~ ~ CHEMI~L FAMILY Llquld High Pressure Prettiest Proprleta~ Blend N.A. DOT ~O~R SHIPPING ~ME Not Regulated by D.0.T. REGU~D IOENTIFI~TION ~IPPING ID NUMAR j ~ C~ - . SECTIO~ 3 - PHYSICAUCHEMICAL CHARACTERISTICS BOlUN~ m~NT ~ECm~C ~WW ~ - ~] PHYS[~ FORM COLOR N.A. 1.044 Llqu Id G~en VA~R mESSURE ~ H~ MEL~NG ~ SOLUa~U~ ~N WA~R SCE~ N~. N~. ~plete ~ne Added vA~ OENS~ ~,. ~ ~ EVA~T, ON ~ ,H ~ ~ SOLUTION ,H CONCeNT~TE U L = N.A. 12.0 N.A. ~.~ ACETATE OTHER ~n-Vlscous, Clear Sol~l~. SECTION 4 - H~ARDOUS IN6REDIENTSlIDENTIT~ INFORMATION ~OOUS COM~NENTS OSHA ACGIH OTHER LIMITS PERCENT ~EMI~L ~ME: COMMON NAME) PEL TLV RECOMMENDED 2~u~oxye?hanol: Bu~l ~110solve 25 ppm 25 ppm ~ne ~S Reglst~ N~ber 111-7~2 ~A-Skln ~A-Skln This p~uc~ contains no other Ingr~i~? c~slder~ hazardous according ~o the crl?erla of 0S~. ~wever. ?his p~du~ ~ntalns ch~lcals which ~y be subject ~o reposing requlr~ts according ~o ~e criteria of SARA Tl?le III. 40 CFR, Pa~ 370. S~?lon ~1 and ~c~lon 3~2. Thls p~duc? also contains ch~lcals which ~y be subj~t ~o reposing r~ulre~n?s according to the criteria of SA~ Tl?le III, 40 CFR, NFPA RATING: Health-2/Flammabl I ltT-0/Reac?lvlty-0 l~tlS RATING: Health-2/Flammabll ltT-0/Reactlvlty-0 CARCI NOGEN lC ITY: Thls product does not contain any known carcinogens or antlclpated carCinogens according to the crlterla of the NTP Annual Repor~r on Carclnogens, IARC Honographs, and OSHA 29 CFR lgl0, Subpal-f Z. (CONTINUED ON REVERSE SIDE) i SECTION 5 - SAFE USAGE DATA EYES Splash-proof safety glasses, safety goggles, and an eye-wash station. -, PROTECTIVE EQUIPMENT RESPIRATORY ] GLOVES I~ubt~r {Latex). HroTectl Ye Cuff Or ~Y~S None required with normal use.I Gauntlet Type Preferred. " OTHER Wear ful I-cover protective clothing to prevent repeated or prolonged contact. GENERAL MECHANICAL Satisfactory. Maintaln adequate ventilation. Keep levels below recomnended TLV. VEN11LATION LOCAL EXHAUST NOt ordinarily needed. Avoid Inhalation of mists containing this product. HANDLING&STORAGE Follow all label directions. Instruct personnel about proper use, hazards, precautions, and flint-aid measures. ^void inhala.~ion, Ingestion and contac~ with skin an.d eyes. PR£r. AUTIONS Rotate stock regularly. Handle carefully to avoid damaging container. Keep container closed when not in use. Recommended storage temp. below 100° F. Keep ou~ o~ children's reach. SECTION 6 - HEALTH HAZARD DATA INHALATION Inhalation of mists may cause irritation to nose', throat, and mucous membranes, tissue d.amage, and pulmonary Irritation..' E~FE~TSOF INGESTION May cause nausea, vomiting, and tissue damage to mouth, esophagus, stanach, and to o~her EX~esURE tissues with which con~ac~ Is made. SKINSEYES SKIN: Contact may cause mild to severe Irritation, depending on degr~s of exposure. EYES: Coni~ct may cause tearing, severe irritation, burning, vision loss, and blindness. ACUTE&CHRONIC ACUTE: Irritant to skin and eyes. Prolonged eye contac? may cause permanent damage. CHRONIC: None Known. ,OUTESOF IIIGESTION-X SKIN ABSORPTION- I TARGET ORGANS ENTRY SKIN-X EYES-X INHALATION-I Eyes, Slain. SECTION 7 - PHYSICAL HAZARD DATA LEL = N.A. J FLASH POIN[ = N.A. NE~OU USED N.A. . F~.UTY UEL = N.A.I STABLE CONDITIONS TO AVOID Avoid mixing 'with any other cleaning product, only with water, X Do not store at high tamperetures. Recem~ended sto~ge temp. <100° F. STABIUTY UNSTABLE HAZARDOUS DECOMPOSITION PRODUCTS ~ixlng with Incompatible ma'terlal may produce carbon dioxide, hydrogen, and other t~xic and Irritmting rum{ MAY OCCUR CONDmONS TO AVOID HAZARDOUS POLYMERIZARON WILL NOT OCCUR X, N'A' MATERIALS TO AVOIO IN~mu~ Acidlc materials and oxldlzing ogen~rs. SECTION 8 - EMERGENCY RESPONSE DATA EXTINGUISHING MEDIA area, use appropriate media. For example: Water sp,~ay, dry/ chemical, carbon dloxide, or alcohol fram. I SPECIAL PROCEOURES Evacuate area of unprotected and unnecessary personnel. UNUSUAL HAZA~OS NO~ Applicable. SKIN: Remove contaminated clothes, flood with water for 15 minutes. L=YE$1: FIl(x~d wi'th lukewarm (not eyes. Kemove much as posslble while flooding ~he, eyes. Continue for 15 minutes. III~LATION: Hove victim to fresh STATED N~0VE, ~ CALL 1-800-228-56:~5 Ex~ 07~ (IR C~ITACT I~IYSICI~1 FgR FtlR~PrlER HEDICAL INSTRUCT~0NS, S~EPS TO BE TAKEN Wear proper protective equipment Including rubber boots. Stop leak I'~ you can do so without risk. Dike o~ dam large spills. Ventilete area if needed. $(~k up with sand or other non-c0mbustlble iner~ absorbent materials. Flush area with water and roi Iow with .... normal clean-up procedures. Keep combustibles a~ay! Be careful as spl Ils are si Ippery.. WASTEOISPOSALMETHOO Comply with all federal, state, and .local regulations. Consult' state and local '-a-uthoritles for restrictions on disposal of chemical waste. If approved, may be diluted and drained ~ ..- to a municlpal sewer or waste treatment plant. Rinse empty container thoro[~jhly ~'ith water before d iscard~ rig. ~ DATA IN THIS MATERIAL SAFETY DATA SHEET RELATES ONLY 10 THE SPECIRC MATERIAL DESIGNATED ANO DOES NOT RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR PRO~__~e~_. ~ DATA CONTAINED IS BEUEVED TO BE ACCURATE. HOWEVER. SINC~ USE CONDmCINS VARY ANO ARE OUTSIDE OUR CONmOL U S CHEMICAL · A DIVISION OF HYDRITE CHEMICAL CO. MA~S NO WARRANTIES. EXPRESSED OR IMPLIED./tND ASSiJMES NO LIABlU1Y FOR FAILURE 10 FOLLOW PROOUCT USE OlREI.~10NS AI~D SAFETY PRECAtm0NS. [~]U S Chemical MATERIAL SAFETY DATA-SHEET Msos SECTION I - MANUFACTURER OR SUPPLIER DATA us9211z 748z xx MANUFACTURER'S NAME & MAILING ADDRESS PREPARED BY SIGNATURE U S Chemical - A DIVISION OF HYDRITE CHEMICAL C0. O.E. Kenas .~L ~. ~ M 316 Hart Street TITLE I DATE Watertown, W I scons I n 53094 USA Qua I Ity Assurance Mana~lerI 10-6-92 EMERGENCY TELEPHONE NO. (24 HOUR SERVICE) PRODUCT INFORMATION TELEPHONE NO. (8-5 CST) Medlcal Emer,~enc¥ ONLY: 1-800-228-5635 Ext. 075 Product Information: 1-800-558-9565 SECTION 2 - IDENTITY OF MATERIAL PRODUCT NAME PR01 Ina BLUE FON41NG CONDITIOI~R " PRODUCT DESCRIPTION FORMULA I CHEMICAL FAMILY.. Foaming Condltloner Proprietary BlendI N.A'. DOT PROPER SHIPPING NAME REGULATED Not Re~lulated by O.0.T. IDENTIFICATION SHIPPING ID NUMBER I HAZARD CLASS ~ ., SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS _. BOILING POINT SPECIFIC GRAVITY (H20 = 1) PHYSICAL FORM COLOR N.A. 1,040 Llquld Dark BI ue VAPOR PRESSURE (mm Hg) MELTING POINT SOLUBILITY IN WATER SCENT N.A. N.A. Co~pl ere None Added VAPOR DENSITY (AIR = 1) EVAPORATION RATE pR 2500 plan SOLUTION I~1 CONCENTRATE (BUTYL ACETATE = 1) OTHER Vl~cous. Clear Solutlon. SECTION 4 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION HAZARDOUS COMPONENTS · 4OSHA ACGIH OTHER LIMITS . PERCENT (CHEMICAL NAME: COMMONJ~AME) PEL TLV RECOMMENDED Ethanol: Ethyl Alcohol I000 ppm 1000 ppm None <2.0 CAS Reqistry Number 64-17-5 TWA TWA Thls product contains no other Ingredient considered hazardous according fo the criteria of 29 CFR 1910.1200, OSHA,' However, thls product contains chemicals which may be subject to re0ortlng requirements according to the criteria of SARA Title III, 40 CFR, Part 370, Section 311 and Section 312. NFPA RATING: Health-1/Flammablllty-O/Reactlvlty-O ., H~IS RATING: Health-2/Flamma~llltyTO/Reactlvlty~ CARCINOGENICITY: Thls product does not contain any known carclnog~n~ or antlclpntna nnr~lnngnn~ n~nr~ln~ ~n fhn crlf~rln n~ the NTP Annual Report on Carclnogens, IARC Monographs, and OSHA 29 CFR 1910, Subpar~ Z. (CONTINUED ON REVERSE SIDE] M SECTION 5 - SAFE USAGE DATA EYES None required with normal use. PROTECTIVE EOUIPMENT RESPIRATORY I GLOVES T~PES None required with normal use.I Rubber (Latex) For' Prolonged Use. OTHER Use Good Standard Industrlal Hygiene Practlces. GENERAL MECHANICAL Satisfactory. Maintain adequate ventilation. Keep levels below recommended TLV. VENTILATION LOCAL EXHAUST None required wl,h normal use. HANDLING&STORAGE I~OI IOW all label directions. Instruct personnel aEou, proper- use, hazards, precautions, and flrs,-aid measures. Avoid Ingestion and contact wl,h eyes. Rota,e stock PRECAUnO~S regularly. Handle carefully to avoid damaging con,airier. Keep container closed when not in use. Recommended s,orage temp. belo~ I00° F. Keep out of chi Idren's reach. SECTION 6 - HEALTH HAZARD DATA INHALATION None Known. EFFEC~OF INGESTION Nay cause discomfort, nausea, vomiting, and Irritation to moul'h, esophagus, stcmech, and EXPOSURE tO '.other tlssues with which contact Is made. SKIN&EYES 5KIN: Prolonged exposure to concentrate may cause slight Irrltation to hlghly.sensltive skin. EYES.' Contact. may cause tearing, and mild to severe Irritation ¢lependlng upon exposure. ACUTE&CHRONIC ACUTE.' Irritant to eyes. CHRONIC.- None Known. ROUTESOF I qGESTION-X 5KIN ABSORPTION- I TARGET ORGANS ENTRY SKIN- EYES-X INHALATION-t None Known. ' SECTION ? - PHYSICAL HAZARD DATA LP_L = N.A. I FLASH POINT = N.A. IVlETHIOD USED = N.A. FI,.JM~MABlUTY UEL = N.A.I ' ' STABLE CONOITIONSTOA~DIO Avoid mixing with any other cleanl~g product. Mix only with water X Do not store at hlgh temperatures.. Recommended storage temp. <100° F* STABILITY UNSTABLE HAZAROOUS DECOMPOSITION PRODUCTS ~iarningl Nixing wlth Incompatible materials may produce sulfur dioxide, hydrogen sulfide, nitrous oxides, and a~monla vapors. MAY OCCUR CONDITIONS TO AVOIO HAT..~RDOU$ POLYMERIZATION WILL NOT OCCUR X. N.A. MATERIALS TO AVOIO rNCOMPa31BIUTY Strong oxldlzing agents and strong alkali such as caustic soda or caustic potash. SECTION 8 - EMERGENCY RESPONSE DATA EXTINGUISHINGMEOIA For fires In area, use appropriate media. For exampl?: Water spray, dry chemical, carbon--d loxide, or' a Icohol foam'. FIRE SPECIAL PROCEDURES Evacuate area of unprotected and unnecessary personnel. UNUSUAL HAZARDS ; Not Appl Icable. INI~.511UN: Do not induce vomiting. If patient Is conscious and can swami Iow, admlinlster milk or water. SKIN: Remove contamlnated clothes, then flood with water. FroSTinG ~-TP-3: PIOOO with lukewarm (not hot) water poured from a large glass 2 or 3 inches from eyes. Remove M~ASURES contacts. Have patient blink as much as possible while flooding ~he eyes. Contlnue for 15 minutes. N~41NISTER FIRST AID 1RF_AINENT RS STATED N~/E, TI[N CALL 1-800-228-5e;35 Ex'l'. 075 OR CON~ACT A PHYSICIAN FOR FURTIIER NEDICRL II~TRU~TIONS. STEPS TO BE TAKEN Weer proper protective equipment including rubber boots. Stop leak If you can SPILL~ do so without risk. Dike or dam large spills. Ventilate area If needed. Soak up with sand aG- or o~her non-combustible Inert absorbent materials. Flush area with water-and follow with N.A. normal clean-up procedures. Keep combustibles awayl' Be careful as spills are slippery. WASTEOISPOSALMETHOO Comply with all federal, state, and local regulations. Consult state and local authorities for restrictions on disposal of chemical waste. If approved, may be. diluted and dralned to a municipal sewer or waste treatment plant. Rinse empty container thoroughly with water before d I scard Ing. THE OATA I1~ THIS MATERIAL ~ DATA SHEET RELA~:S ONLY ~3 THE SPECIFIC MATERLa~ DESIGNATED AND DOES NOT RELATE TO ITS USE IN COMBINatION WITH ANY OTHER MATERIAL OR PROCES~ THE DATA CONTAINED tS BEUEVEO TO BE ACCURATE. HOWEVER. SINCE USE coNOm0Ns VARY ANO/~IE OUTSIDE OUR CONTROL U $ CHEMICAL · A DIVISION OF HYDRITE C3-1EMICAL CO. MAKES NO WARRANTIES. EXPRESSED OR IMPLIED. AND ASSUMES NO LIABlUTY FOR FAILURE TO FOLLOW PRODUCT LJSE DIRECTIONS AND SAFETY PRECAUTIONS. Dieu S Chemical M /'ERIAL SAFETY DATAHEET sos SECTION I - MANUFACTURER OR SUPPLIER DATA usgli1z 7~z xx U S Chemical - A DIVISION OF HYDRITE CHENICAL CO. D. ED Kenas ' ~ · ~ I )16 Hart Street TITLE I DATE Water'town, Wisconsin 53094 USA ~uali~y Assurance M~nagerI 5-15-91 EMERGENCY TELEPHONE NO. (24 HOUR SERVICE) PRODUCT INFORNL~TION TELEPHONE NO. (8-5 CST) Medical Emergency ONLY: 1-800-228-5635 Ext. 075 Product Informatlon: 1-800-558-9566 SECTION 2 - IDENTITY OF MATERIAL PRODUCT NAME PR01 Ina CHERRY WAX PRODUCT DESCRIPTION FORMULA I CHEMICAL FAMILY Drying Agent Proprle,ary Blendl N.A. DOT PRI~PER SHIPPING NAME No? Regulated by D.0.T. REGULATED IDENTIFICATION SHIPPING ID NUMBER I HAZARD CLASS N.A.I N.A. -' · SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS BOIUNG POINT SPECIFIC C~RAVII~( (H20 = 1) PHYSIr. JM_ FORM COLOR N.A. .990 Liquid Red VAPOR PRESSURE (n~n Hg) MELTING POINT SOLUBIUTY IN WATER SCENT N.A. N .A. Comp I eta Cherry VAPOR DENSI~ L~IR = 1) EVAPOPJ~TION PJ~TE pH 250B ~ SOLUTION pH CDNCENTFL6.TE (BUTYL ACETATE ~ 1) N.A. N.A. N.A. 6.5 OTHER Non-Viscous, Clear Solutlon. SECTION 4 - HAZARDOUS INGREDIENTS/IDENTiTY INFORMATION HAZARDOUS COMPONENTS OSHA ACGIH OTHER LIMITS PERCENT (CHEMICAL NAME: COMMON NAME] PEL TLV RECOMMENDED 2-Butoxyethanol: Butyl Cellosolve 25 ppm 25 ppm None 4.0 CAS Registry Number 111-76-2 TWA-Skin TWA-Skin Thls product contains no other ingredient considered hazardous accordlng to the criterla of 29 CFR 1910.1200 OSHA. However, thls product contains chemicals which may be subject to reporting requirements according to the criteria of SARA Title III, 40 CFR, Part 370, Section 311 and Section 312. This product also contains chemicals which may be subject to reporting requlrements according to the criteria of SARA Title III, 40 CFR, Part 372, Section 313. NFPA RATING: Health-2/Flammabl lity-O/Reactlvlty-0 1~41S RATING: Health-2/Flammabl I lt~/-0/Reactlvlty-0 _. CARC INOGEN ICI TY: This product does not contaln any known carclnoqens or anticipated carclnoqens according to the criteria of the NTP Annual Report on Carcinogens, IARC Monographs, and OSHA 29 CFR 1910, Subpar~ Z. (CONTINUED ON REVERSE SIDE) ; SECTION 5 - SAFE USAGE DATA EYES Splash-proof safety glasses, safety goggles, and an eye-~ash station. PROTEC11VE. EQUIPMENT RESPIRATORY I GLOVES ~ubt)~r (LaTe~:) o HroTecTi ve L;ut I' Or · YpeS ._ None required with nomal use.I Gauntlet Type Preferred., OTHER Wear ful I-cover protective clothing to prevent repeated or prolonged c:ontact. GENERAL MECHANICAL Satisfactory. Nalntaln adequate ventilation. Keep levels below reco~men(led TLV. VENTILATION LOCAL EXHAUST NOt ordinarily needed. Avoid inhalation of mists containing this product.. HANDLING&STORAGE Follow all label directions. Instruc~ personnel about p~er use, hazards, )recautlons, and fi mt-aid measures. Avoid Inhalation, ingestion and contact with skin an.d eyes. PRECAUTIONS Rotate stock regularly. I-~ndle carefully to avoid damaging container. Keep co~tainer closed when not in use. Recommended storage temp. below 100° F. Keep out of chlldrenrs re~ch. SECTION 6 - HEALTH ,HAZARD DATA INHALATION Inhalation of mists may cause irritation to nose, thr~at, and mucous membranes, tissue d~.rfl~ge, and pulmonam/ irritation..' EFFECrsoF ~NGES~JON H~y Douse nausea, vomiting, and tissue d~ge to mouth, esophagus, stomach, and to other F. XPOSU,E tissues ~ith ~hich conl-4c~ is mode. S~N&EYES SKIN: Contac~r may c~use mild to severe irritation, dependin~ on degree of exposure. EYES: Con.ct may Douse tearing, severe irritation, burning, vision loss, and bllndnesso AGU~&¢H;ON$¢ ACUTE: Irritant to skin and eyes. Prolonged eye contact fl~,y caUSe permanent da~ge. CHRONIC: None Known. nOUTESOF INGESTION-X SKIN ABSORPTION- ~ TARGET ORGANS ~.~nY SKIN-X EYES-X INHALATION-I Eyes, Sk'lno SECTION 7 - PHYSICAL HAZARD DATA LEL = NaA. I FLASH POINT = N.A. NETHOU USED = N.A. FLAMMABILITY UEL = N.A.I STABLE CONOITIONSTO'AVOIO Avoid mixing with any other cleaning prc(luct. HIx only with water , X i Do not store at high temperatures. Recommended stor~ge tempo <i00° F. STABIUI~F UNSTABLE HAZAROOUS DECOMPOSITION PROOUCTS Mi X lng w I th i ncompat lb I e materi a I s may produce carbon dioxide, hydrogen, and other to~ic and Irritating f~nes. MAY OCCUR CONDITIONS TO AVOID HAZARDouS POLYMER~.ATION WILL NOT OCCUR X . Ne A. MATERIALS TO AVOID IN~OMPATIBIUTY Acidic materials and o~idizlng agents. SECTION 8 - EMERGENCY RESPONSE DATIt EXTINGUISHING MEDIA FOr fires in ama, use appropriate media. For example: Water sp~ay, dry chemical, ca~oon dioxlde, or alcohol foam. FIRE SPECIAL PROCEDURES Evacuate area of unprotected and unnecessary personnel. UNUSUAL HAZARDS NOt Appl Icable. INI~_511UN: Ua not induce vomiting. If p~~atlent is conscious and can swal Iow, adminilster mi I k or water SKIN: Remove contaminated clothes, flood with wa~er for 15 minutes. EYE~;: Flood with lukewarm (not ~RaS~N~ hot) water poured tn~ a large glass Z or ~ Inches tr~m eyes° ~emove c~?ac'rso Have pa?left? DI InK as MEASURES much as possible while flooding the eyes. Contlnue for ~5 mlnuteso II~IAIJ~T. 10N: I~n~e vlctlm to fresh air. Give artificial respiration I~ patient Is not breathing. ADMI#I$~I~ FIR~ AlII ]REA]NEN~ A~ STATI]) ABOVE, 3HEN CALL 1-800-228-5635 Ex~ 07~ (]R C0NTA~T PHYSlClN~I F(]R FURTHER 14-])ICA1 INSTRUCTIONS STEPS TO BE TAKEN Wear proper protective equipment including rubber boOts. 3top leak If you can 5mu_~ do so without risk. Dike or dam large splllSo Ventilate a~ If needed. Seek up with sand Re = or other non-combustible Inert absorbent materials. F'lush area with water and fol Iow with N.A. normal clean-up procedures. Keep combustibles a~rayl Be careful as spills are slippery° WASTE DISPOSAL METHOD Comply with all federal, state, and .local regulations. (~nsult state and local authorities for restrictions on disposal of chemical waste. If approved, may be diluted and drelned to a municipal sewer or ~aste treatment plant. Rinse empty contalner thoroughly ~lth water before dl scardt rig. THE DATA IN TH~ MA~RIAL SAFETY DATA SHEET RELATES ONLY TO THF SPECIFIC MATERIAL DESIGNATED AND DOES NOT RELATE TO ITS USE IN C01VlBINATION wrrH ANY OTHER MATERIAL OR PROCES~ THE DATA CONTNNED IS BEUEVED TO RE ACCURATE HOWEVER. SINC~ USE c0Nom0~s v~RY ~ ~E 0UmlBE OUR co~m~3L u S CHEMI[~. · A DIVISION OF HYDRrTE CHEMICAL CO. MAX~S NO WARRANTIES. EXPRESSED OR IMPUED. AND ASSUMES NO LIABILITY FOR FAILURE TO ~ PRODUCT USE DIREI.-q3ONS AND SAFE~ PRECAUTIONS. s Cher ic l M 'ERIAL SAFETY DAT iSHEET SECTION I - MANUFACTURER OR SUPPLIER DATA U59211Z 792Z. XX U S Chemlc~l - A DIVISION OF HYDRITE CHEMICAL CO. D.E. KeRBs ' ~* I 316 H~rf Street t TITLE I DATE tfatertown, ~/Iscons in 53094 USA ~)ua I Ity Assurance Manager !-6-92 EMERGENCY TELEPHONE NO. (24 HOUR SERVICE! PRODUCT INFORMATION TELEPHONE NO. 18-5 CST! Medical Emergency ONLY: 1-800-228-5655 ExPo 075 Product Information: 1-800-558-9566 SECTION 2 - IDENTITY OF MATERIAL PRODUCT NAME PRODUCT DESCRIPTION I FORMULA J CHEMICAL FAMILY Rinse trax/Drying Agent Proprietary Blend M.A. DOT PRO~t=R SHIPPING NAME REGULATED Not Regulated by D.0. To IDENTIFICATION SH:Pr~G ID NUMBER I HAZARD CLASS · M.A. M.A. SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS' BOILING POINT SPECIFIC GRAVJTY IHz, O . 1) PHYSICAL FORM COLOR M.A. .985 Liquid Yel Iow ~RPOR PRESSURE Imm Hg~ MELTING POINT SOLUBIUTY IN WATER SCENT N;A. M.A. Compl eta None Added VAPOR DENSITY lAIR = 1 ) EVAPORATION RATE pH ~ IXom SOLUTION ~FI CONCENTRATE M.A. (BUTYL ACETATE = 1! M.A. M.A. 6.6 OTHER Non-Y1 scous Sol ut Ion. SECTION 4.- HAZARDOUS INGREDIENTS/IDENTITY INFORMATION HAZARDOUS COMPONENTS OSHA ACGIH OTHER LIMITS PERCENT (CHEMICAL NAME: COMMON NAME) PEL TLV RECOMMENDED 2-Butoxyethanol: Buty. I Cai Iosolve 25 ppm 25 ppm None 2.0 Registry Number i11-76-2 11fA-Skin TalA-Skin This product contains no other ingredient considered hazardous accordlnq to the criteria of 29 CFR 10 OSHA. Hovever, this product contains chemicals which may be subject to reporting requirements according the criteria of SARA Title III, 40 CFR, Part 370, Section 311 and Section 312. This product also contains chemicals which may be subject to reporting requirements according to the criteria of SARA TItle III 40 CFR Part :372, Section 313. ' NFPA RATING: Health-2/Flammabl I Ity-0/Reactlvlty-0 I~IIS RATING: Health-2/Flammabl I ity-0/Reactlvlty-O CARC I NOGEN I C I TY: does not cont the NTP. Annual Report off Carcinogens, IARC Monographs, and OSHA 29 CFR 1910, Subpart Z. ICONTINUED ON REVERSE SIDE) ~ ECTION 5 - SAFE USAGE D Splash-proof safety glasses, safety goggles, and an eye-wash stati¢>n. EQU~PtMENT RESPIHATORY J GLOVES KUD~r [L;ITex). HrOTeCTi ye ~utt or ~s ~ne mqulr~ with nomal use.J ~untlet Type P~fermd. OTHER ~ear tul I-cover p~ec~lve clo~hin9 ~o p~ven~ mpea~ed or p~l~9;~ ~ENERAL MECHANICAL Satlsfa~o~. ~intain adeq~?e ven?lla?l~. K~p levels bel~ m~nended ~V. LOlL EXHAUST ~? o~inarily needed. Avoid inhalation of mists containing this p~uc?. HANDLING&STORAGE POI IOW all I~1 dictions. Inst~ pe~nel eDiT p~er use~ hazards, eeE~a pm~utions~ and flint-aid m~sums. Avoid Inhalati~, ing~ti~ and c~?a~ with skin and eyes. ~tate st~ ~ularly. ~ndle ~retully to avoid dam~lng ~ntainer. K~p c~Talner closed when not in use. R~nd~ stooge t~. below 100* F. K~p o~ of child~n~s ~ch. SECTION 6 - H~LTH H~RD DATA INHALATION Inhale?l~ of mists ~y cause i rrltatl~ to no~, thm?~ end muco[~ m~b~n~, ?lss~ de,ge, and pul~na~ I rri.tatlm. ~FE~OF ~NGESTION ~y ~use naus~ v~ltlng, and tissue d~ge To ~uTh~ esophagus~ st~ach, and ?o ~her ~es tissues ~lth ~hich conta~ Is SKIN&EYES SKIN: ~ntact ~y cause mild to seve~ irr,~ ri~ d~din~l on de~ of e~osu~. EYES: C~ct ~y ~use teari~, seve~ irrl~tlm, ~ml~, visio~ loss, ae,d blindness.' ACU~&CHRONIC AC~E: Irritant ?o skin a~ eyes. P~l~g~ e~ c~tact ~y cause pe~anen? de, ge. C~0N lC: ~e Kn~n. ~o; 1~5TION-X SKIN ~SORPTI~- I TARGET ORGANS E~V SKIN-X E~S-X I~A~TI0~~ E~S, Skin. SECTION 7 - PHYSICAL H~RD DATA LEL = N.A. I F~ PUI~ = N.A. ME1H~ USED = STABLE CONOI~ONSTOA~IO Avoid mixing ~lth any ~her cloning pr~u, . Mix ~ly ~lth X ~ not sto'm at high tmpemtur~. Re~end~ ~ltorage ?e~. <1~* F. UNSTABLE H~ROOUSDECOM~ON~UCTS Nixing ~l?h Inc~pa?lble ~Te~ s may p~uce ~n dl~ide~ hyd~en, and other ?~lc and irritating 1 MAY OCCUR CONDITIONS ?O ~L~M~ WILL ~T OCCUR X. N.A. MATERIALS TO A~ID Acidic materials and ~ldizlng agent. SECTION 8 - EMERGENCY RESPONSE DATA EX~NGUlSHINGMEOIA EOF f i~s in ama~ use epp~priate m~ia. For ex,pie: ~ater sp~y~ d~ chemical ~ dioxide, or al~hol FIRE SPECIAL PROCEDURES Evacuate a~a of unp~t~t~ and unnec~se~ pe~onnel. UNUSUAL HAZARDS N~ Appl I~ble. ~11~: ~ not induce v~itlng. It pa?lent is c~sci~s and ~n sw,allo~ adnilnlster milk or SKI~: R~ve cont~inat~ cloth~, fl~d ~ith ~eter for 15 minutes. E~:: FI~I ~ith luke~a~ (not ;lA. NB hOtJ ~ater poured r~ a la~e glass Z or ~ incn~ t~ e~s. H~e ,E~nT'~CTS. Have poTlenT DIInK M~UR~ mu~ es p~sible ~hile fl~ing ~e eye. ~n?ln~ for 15 minutes. I~UITI~: ~e vl~lm to fresh air. Give a~iflclal mspi~tlon If patient Is not breathing. ~I~IS~. FIR~X'ID ~~ 5iE~S TO BE TAKEN ~ee~ p~per pro?~tlve ~ulpm~? including ~b~r ~s,. Stop leak If you can do so ~lthout risk. Dike or dam le~e spills. Ventilate a~ If n~.~. S~k up ~i?h sand RQ or other n~-c~bustible Ine~ absor~nt materials. Flush ar~ with ~;a?er and ~ollo~ N.A. noel clan-up p~u~s. Keep c~bustibles a~yl'Be ~ful es spl;lls am slip'pe~. WAS~DIS~LMETHOO ~ly with all f~e~l, state, and Io~1 ~ulati~s. ~sult state and local authorities for ~strl~lons ~ disposal of ch~lcal ~aste. If app~;~, ~y be dll~ and d~ln~ ?o e municipal se~er or waste tmf~nt plant. Rinse ~pty c~tainer tho~hly ~lth water befo~ disca~lng. O?~U S Chemical MATERIAL SAFETY DATA SHEET Msos SECTION I -MANUFACTURER OR SUPPLIER DATA us9111z ~228 U S Chemical - A DIVISION OF HYDRITE CHEMICAL CO. 0o [. Kena5 ' 316 Hart Street TITLE I DATE Watertown, Wisconsin 53094 USA Quality Assurance ManagerI 1-1-91 EMERGENCY TELEPHONE NO I24 HOUR SERVICE} PRODUCT iNFORMATION TELEPHONE NO (B.5 CST} Medical Eme~lency ONLY: 1-800-228-5655 Ext. 075 Product Information: 1-800-558-9566 SECTION 2 - IDENTITY OF MATERIAL PRODUCT NAME ~FSC HI ~ PRODUCT DESCRIPTION FORMULA end CHEMICAL FAMILY Hanual Dlshwashlng Detergent (Anionic Surfactants) Proprietary BI N.A. DOT PROPER SHIPPING NAME Not Regulated by O.O.T. REGULATED IDENTIFICATION SHIPPING ID NUMBER I HAZARD CLASS SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS BO;LING POINT 5PEC,F,C GRAvrT~ .l'~i,O ~) ;~S;CAL FORM COLOR N.A. !.320 Llquid Blue VAPOR PRESSURE (mm Hq) MELTING P0'NT SOLUBIL~T f IN WATER SCENT NoR. M.A. Complete None Added VAPOR DENSITY lAIR = 1 ] EVAPORATION RATE pH 2500 opm SOLUTION oH CONCENTRATE N.A. [BI~?:~.ACETATE ~ N.A. 7. OTHER Viscous, Clear Solution. SECTION 4 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION HAZARDOUS COMPONENTS OSHA ACGIH OTHER LIMITS PERCENT (CHEMICAL NAME COMMON NAN*,E) PEL TLV RECOMMENDED Ethanol: Ethyl Alcohol 1000 ppm 1000 ppm None <2.0 [CAS Registry Number 54-17-5] TWA TWA This produc, con,alns no o, her Ingredlen, consldere~ hazardous according to ,he crl,erla of 29 CFR 1910.1200 OSHA. However, ,his produc, contains chemlcals which may be subjec, ,o repor~rlng requirements accordlng to the criteria of SARA Title III, 40 CFR, Part 370, Sec, Ion 511 and Section 512. NFPA RATING: Health-i/Flammablllty-O/Reactlvlty-O HMIS RATING: Health-2/Flammablllty-0/Reactlvlty-0 CARCINOGENICITY: This product does no, contain any known carclnocJens or anticipated carcinogens according to ,he crlterla o~ ,he NTP Annual Repor~ on Carcinogens, IARC Monographs, and OSHA 29 CFR 1910, Subpar~r Z. (CONTINUED ON REVERSE S~DE) " ~ SECTION 5 - SAFE USAGE DATA · None required with normal use. PROTECTIVE EQUIPMENT RE SPlRATOI4Y TYPES None required with normal use. Rubber (Latex) For Prolonged Use. .... OTHER Use Good Standard Industrial Hygiene Practices. GENERAL MECH^N~CAL VENTILATION Satisfactory. lqalntalrl adequate ventilatlono Keep levels below rec(~mended TLVo LOCAL EXHAUST None required with normal use. HANDLiNG&STORAGE POIIO~ all label directions. Instruct personnel abc)ut proper use, hazards, -- precautions, and first-aid measures. Avoid ingestion and contact wlt'h eyes° Rotate stock PRECAU~ONS 'regularly° Hanoi° car°tully to avoid damaging contain°to Keep c,3ntalner closed when not in use.-- Recommended storage temp. belo~ 100° F. Keep out of chi Idren~s reach,. SECTION 6 - HEALTH HAZARD DATA ~ 'NHAL AT,ON None Known. EFFECTSOF INGESTION Nay cause discomfort, nausea, vomiting, and irrltatlon to mouth, esophagus, stomach, and EXPOSURE tO other tlssues with which contact Is made. I SK~N&E~ES 5KIN: Prolonged exposure to concentrate may cause slight Irrltatlon to highly sensitivE-- skin. EYES: Contact may cause tearing, and mild to severe Irrlt~tlon dependlng upo~ exposure. i ACUTE&CHRCN'C ACUTE: Irritant to eyes. -- J CHRONIC: None Known. ROUTESOF INGESTION-X SKIN ABSORPTION- J TARGETOI~GANS ENTRY 'SKIN- EYES-X INHALATION-J None Known. SECTION 7 - PHYSICAL HAZARD DATA L~_L = N.A. i FLASH POINT = N.A. NETHOD USED = N.A. FLAMMABILITY UEL = N.A. STABLE I CCNDmOr~S.'OAVO,D Avoid mixing with any other cleaning product. Mix only with water {X Do not store at high temperatures. Recommended storage temp. <100' F. STABIUTY J uNSTABLE j HAZAROCUSDECOMPOSIT'C~Nm~ODUC'S ~arnlng! Mixing with Incompatible materials may produce sulfur dloxide~ hydrogen sulfide, nitrous oxides, and a~monla vapors. MAY OCCUR COf~O,T:C~S ~C ~*VCIO HAZARDOUS PQLYMERIZATIONI WILL NOT OCCUR X N.A, J MATERIALS TO AVOID INCOM~A~alUTY!Strong. oxidizing agents and strong alkali such as caustic soda c'.r caustic potash. SECTION 8 - EMERGENCY RESPONSE DATA EXT~NGU~SH~NGMED~A For fires in area, use appropriate media. For example: Wat~r spray~ dry chemlcal~ carbon dioxide, or alcohol 'foam. FIRE SPECIAL PROCEOURES Evacuate area of unprotected and unnecessary personnel UNUSUAL HAZARDS j Not Applicable. INL~.blI~N: IJo not Induce vomiting. If patient is conscious and can swal Iow, administer milk or water SKIN: Remove contaminated clothes, then flood with water. FIRSTAID I;TP.~: PIood with lukewarm (not hot) water poured from a large glass 2 or 5 inches from eyes. Remove MEASURES contacts. Have patient blink as much as posslbl'e while flOOding the, eyes. Continue for 15 minutes. ADMINISTER FIRST AID 1~EAlt,lENT AS STAi'EU ABOVE, TI.EM CALL 1-800-228-5655 Ex't, 075 OR CONT/t~T A PHYSICIAN F(]~ FURTHER MEDICAL INSTRUCTIONS, SPILLS STERST[~BE ~AKEN Weak proper protective equipment including rubber boots. Stop. lleak If you can do so without risk. Dike or dam large spills. Ventilate area If needed. S~k up with sand RO or other non-c~bustible Inert absorbent materials. Flush area with water arid follow with N.A. normal clean-up procedures. Keep combustibles away! Be careful as spills are slippery. WASTEOISPOBALME~HOD Comply with all federal, state, and local regulations. Consult state and local authorities for restrictions on disposal of chemical waste. If approved, may be diluted and dralned To a municipal sewer or waste treel~nent plant. Rinse empty container l'horouqhly with water before I dl scard lng. ' 'rile DATA IN THIS MA~RIAL SAFETY DATA SHEET RELATES ONLY ~0 THE SPECIFIC MATERIAl DESIGNATE0 AND 00ES N0T RELATE T0 ITS USE IN COMBINATION WiTH ANY OTHER MA?ERI~I OR PROC~SS, THE DATA CONTAINED IS BELIEVED ~0 BE AC_~URATE. HOWEVER SINCE USE ~NDITiONS VARY AND ARE OUTSIDE OLIR CONTROL U S CHEMICAL ® A DIVISION OF HYDRITE CHEMICAL C.O MAKES N0 WARRANTIES EXPRESSED OR ~MPLIEO AND ~SSUMES NO llABllff'~ F-OR FAILURE ~0 FOLLOW I~IODUC? USE DIRECTIONS AND S/~FETY PRECAUTIONS © O~USChemical MATERIAL SAFETY DATA SHEET Msos ~ .. SECTION I - MANUFACTURER OR SUPPLIER DATA usglI1Z )Sl l ZX U S Chemical - A DIVISION OF HYDRITE CHENICAL COo D.E. Kenas ' .~16 Har-t' SI' reef TITLE I DATE Watertown, W i scans I n 53094 USA Qua I I ty Assurance Nanag er I- 1-91 EMERGENCY TELEPHONE NO 124 HOUR SERVICE} PRODUCT iNFORMATION TELEPHONE NO (8.,5 CST] . Medical E.nergency ONLY: 1-800-228-5635 Ext. 075 Product Information: 1-800-558-9566 · .. SECTION 2 - IDENTITY OF MATERIAL PRODUCT NAME · Vehicle Wash Shampoo Proprietary Blend N.A. ', DOT PROPER SHIPPING NAME Not Regulated by O.0oTo REGULATED IDENTIFICATION SHIPPING ~0 NUMBER I HAZARD CLASS I " SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS BOLLING POINT ' SPECiFtC., GNAV,TY ~H.~O : 1} PHYSICAL FOI~M COLOR N.Ao 1.040 LI qu I d Red VAPOR PRESSURE imm H0} MELTING POINT SOLUBILtTY IN WATER SCENT N.A; N.A. Complete None Added vAPOR DENSITY (AIR · 1) EVAPORATtON RATE DH 2500 Dom SOLUTION pH CONCENTRATE N.A. (BI~T[L...-. ACETATE -. 1} N.A. 7.3 OTHER Viscous,' Clear Solution. -,'. . SECTION 4 - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION HAZARDOUS COMPONENTS OSHA ACGtH OTHER LIMITS PERCENT ICHEMICAL NAME COMMON NAME} PEL TLr RECOMMENDED Ethanol: Ethyl Alcohol 1000 ppm 1000 ppm None <2.0 [CAS Registry Number 64-17-5l TWA TWA This product contains no other Ingredient considered hazardous according to the criteria of 29 CFR 1910.1200 ':/" OSHA. However, this product contains chemicals which may be subject to reporting requirements according to . the criteria of SARA Title III, 40 CFR, Part 570, Section 511 and Section ~12. NFPA RATING: Health-1/Flammability-O/Reactlvity-O ~41S RATING: Health-2/Fla~nabllity-0/Reectivlty-0 CARCINOGENICITY:. This product does not contain any known ca rclnc~ens or anticipated carcinogens according to the criteria of the NTP Annual Report on Carcinogens, IARC Monographs. and OSHA 29 CFR 1910, Subpar? Zo (CONTINUED ON REVERSE S~OE) " ~' SECTION 5 - SAFE USAGE DATA E'~ES None required with normal use. PROTECTIVE T~PES None required with normal use. I !Rubber (Latex) For Prolorm~ed Use. Use Good Standard Industrial Hygiene Practices. Satisfactory. Maintain adequate ventilation Keep levels below recc~nmended TLV. VENTILATION ' ' None required with normal use. ~,~rJot.~,]:;~',;~,',C;E Pol]~--~iT--f~T-]~rectlons. Instruct personnel about proper use, hazards, .... precautions, and first-ali measures. Avoid Ingestion and contact with eyes. Rotate stock PRECAUTIONS ~ ' regularly. Handle careFUlly to avoid ,damaging container. Keep container closed when not in use. ,Recc~mended storage temp. belo~ 100° F. Keep out of chlldren's reach. SECTION G - HEALTH HAZARD DATA i None Known. E~FECTSO~ [ ~r~.",~rj ~ay cause discomfort, nausea, vomiting, and irritation ?o mouth, esophagus, stomach, and EXPOSURE !tO. other tlssues with which contact Is made. i ~ r~E,Es a~lT4:----]mro¥onged exposure to concentrate may cause slight irritation to highly sensitive ;i skin. EYES: Contac~ may cause tearing, and mild to severe Irrltatlon dependlng upc~ exposure. i :.cu'~-',::~,~;[r~C AC-g-T-E: Irritant to eyes. CHRONIC: Hone Known. ROUTESOF ]-~~ SKIN ABSO~TIOq- ' -:.;,c-;:- ':~.c,~ ;S ENTRY SKIN- EYES-× INHALATION- i None Known. SECTION 7 - PHYSICAL HAZARD DATA Lr.-L = M.A. FLASH POINT = N.A MF-THOD IJSED M.A. UEL = N.A. S'-"-BLE ~.]r:r]'c.i;:-]'~,'.":' Avoid mixing with any other cleaning product. ,'4ix only with water X', Do not store at hlgh temperatures Recommended storage tamp <100° F. ~'~2'.".f~LE i .,c?.'.~::, ~u¢ 2,E':Z'.'; _ :: ' '.'. ;:-C:'r~]%-T~F~i~ ]'' ~1 x lng wi th I ncompat 1 b le maferl a Is may produce sulfur dloxide, hydrogen sulfide, nitrous oxides,, and an~nonla vaPors. ;,'L'.~ OCC,,U : "r,~ ' _r;Z "] .'.'.". ' HAZARDOUS I ' ' ROLYMERIZATIONI ?¢:LL ~(]- CC~Uu X ~ I ~/,A-E[~'CLS -C :..C D ~NCOMPAT~BlUTYiStrongl oxidizing agents ,and strong alkali such as caustic soda or caustic potash. SECTION 8 - EMERGENCY RESPONSE 13A'rA E~%r~C,~S~r4,.~L'eC,.'. For fires in area, use appropriate media. For example: Water spray, dry chemical, carbon dioxide, or alcohol foam. FIRE SPEC.Ct Evacuate area of ,Jnprote~ted and unnecessary personnel. Not Applicable. II~SIION: Do not induce vomiting. If patient is consclous and can swallow, administer milk or water SKIN: Remove contaminated clothes, then flood with water. ~EASUREsF'RS?~Ie kYES: Flood with lukewarm (not hot) w-~er poured ~rom a---~r--~]glass 2 or 3 inches from eyes. Remove contacts. Have patient blink as much as possible while flooding the eyes. Continue for 15 minutes. ADNIINISTB FIRST AID ll~EAll4ENT AS STATED ALCOVE, llIEN CALL 1-800-228.-5635 Ext. 075 OR CONfA~T A PHYSICIAN FOR FtlRIIIB HEDIC~L INSflII~IIOINIS, SmL~S S'EPr<'C~.:t. ','.~['~ 'Hear proper protective equipment including rubber bool's. Stop leak if you can , do so without risk. Dike or dam large shills. Yentllate area If needed. Soak up with sand RO or other non-combustible inert absorbent ma*erials. Flush area with water and follow with N.A. normal clean-up procedures. Keep combustibles away! Be careful as :;pi lis are slippery. ,.~^~.?.-':l,.',~,,~,,.,.'.~ ~..i',.~ Comply with all federal, state, and loc.al regulations. Consult state and local authorities for restrictions on disposal of chemical waste. If approved, may be diluted and dralned ~ to a munlcipal sewer or waste tr~,+m, ent plant. Rinse empty container thoroughly with water before ! discarding. PROCESS THE DATA CONTAIf~ED IS BELIEVED TO BE :CCI;PeTE PO'.'.'[ '~2 -~"'¢= U~E ~,,m .~ c .,_'a 9UTE~D£ CHEMICAL CO MAKES NO WARRANTIES ExPqESSEB (]R 'MCL'EC :-';C '~ZL".'ES ';C t .t~ L ~, ~]~ ~:~LU~;.c TrI r'~ ,. 0',*,' ',p~]r~! CODE NUMBER: H831 ' . · *~ TRADE NAME: MINEERL SPIRITS 8UPERCEDES CHEMICA~ FAMILY: ~~ TSCAINFORMATION: ~T ~1 [IS~ COMPONENT8 C.A.a. TLV/PEL PERCENT NOS.: PPM m~m~ WEIGHT~OLUME 1H18 FI~tXA~T DEFI~EO FLASH POINT: ~ ~T~) EXTINGUISHING MEDIA: ~ OI~ DOT INFORMATION: ~.~ UNUSUAL FIRE AND EXPLOSION HA~RDS: ~l~ ~ IF ~ ~ ~ ~ I~ITI~. SPECIAL FIRE FIGHTING PROCEDURES: ~ ~ ~T~ ~ ~ ~ ~[~ BOLLING RANGE: VAPOR PRESSURE; ~ ~ APPEARANCE AND ODOr: ~ ~IIE LI~IO EVAPORATiOu O~Tc ~ SPECIFIC [ WEIGHT VOLATILE BY VOLUME VAPOR DENSITY I INCOMPATIBILITY ~MATERIALS TO AVOIDS: HAZARDOU~ DECOMPOSITION PRODUCTS: HAZAnDOUSPOLYMERI~TION ~PRTIONflL EXPOSURE LIHIT Material SafeW Data Sheet Prepped Acceding to t~ OSHA hzyd C~icmlion Sm~d (29. ~ 1S10.12001. (Formerly C~led MA~RIAL I~0RMATION B~INI 325 CPS 218223 DAI~! BARMF~ ~ F~?XL Z~ SNAL~ KEEP ~ ~ ~ ~ St~d~d solv~ (~ 8052-~1-3) 100% No F~eral 'OS~ ~sure s~d~d or ACGIH TLr ~s be~ es~lish~ for ~his ~erial. ~s~ on infor~ion review~ ~o ~e, wG reco~ ~ ~5ure s~ard of 100 ppm for a daily 8-hour ~sure. ~SIO~I~ & ~ ~ ~ & F~ A~ ~es E~pec~ ~o cause no more t~ minor eye Flush eyes ~iately with fresh wat~ irri~a~ion. Appli=a=ion of a s~lar for a~ leas~ 15 ~nu~es while holding ~he ~erial in~o ~he eyes of r~bi=s pr~uc~ eyelids op~. If irri~a~ion ~sis~s, ~ee sligh~ m~r~e irri~a~ion wi~hou~ corn~l a ~oc~or. ~u~. Not a pr~ skin irrit~t but ~y ~use Wash skin ~oroughly. with s~p ~ ~ter. skin irritation on prolong~ or fr~tly See a doctor if irritation occurs. ~aund~ rep~t~ contact. Application of a s~l~ cont~t~ clo~ng. ~t~ial onto ~he skin of r~its pr~uc~ ~erate ~be~ ~ ~-~. ~e Draize score ~s 3.7. See ~itio~l H~lth Data. ~pect~ to ~ve slight acute ~oxicity ~ If ~ere ~e si~s or s~t~s, as i~lation. ~e i~lation LCs0 (rat) of a descr~ in ~his ~DS, due ~o br~ing s~l~ pr~uct for a one-hour ~sure this ~t~ial, ~e p~son ~o ~resh air. was gr~t~ ~ 13.3 mg/lit~. Br~thing If br~thing ~s stopp~, apply artificial the ~rs at conc~trations ~e the respiration. ~11 a doctor .~iately. r~~ ~sure st~rd ~ ~use c~tral n~us ~y~ effects. ~iti~l H~lth ~ta. Not ~ect~ ~o ~ acutely :oxic ~ If s~11ow~, give ingestion. ~e acute oral LDs0 (rat) for a ~ telephone for m~i~l ~vice. s~m{l~ pr~uc~ ~s gr~ t~ 15.3 ~e ~son ~ ~less dir~ ~o do so g/kg. ~te ~ ~sl~: Ingestion of ~his ~ m~l ~so~el. If ~i~1 ~vice pr~uc~ or s~s~u~t ~ting ~ result ~o~ ~ ~ain~, ~ ~e ~e p~son in aspiration of light h~r~ar~n ll~id ~ pr~uct contain~ to ~he n~est whi~ ~ ~use ~e~ni~is. ~i~l ~g~ ~r~t c~ or hospital. C~hewor, Envtronmen~BF HellTh Cert,',, Inc. P.O Box 4054, R~chmona. CA 94804-0054 Emergency Phone Number (dlS, 233-3737 No. ¢7 ! Rev. 12 06/29/87 ADDITIONAl. HEALTH DATA ENVIRO~J. P~:OT~C~ION See following pages E~vironmenta~T Ice, act'.: Cer,ain geographical areas have air' pollution restrictions SPECIAL PROTECTIVE INFORMATION concerning the 'use of materials in. wor'.~ Ry. PTo,ection: Do no, ge, in eyes. Eye situa,uions whi.ch r~ay release v0.1atil,, contact can be avoided by wearing chemical components to th~. a~mosphere. At~ safety goggles, pollution regulation!~ should be studied Skin Pro~ection: Avoid prolonged or de,ermine if ,his material is regulated frequently repeated skin contac, wi,h ,he area where i., is to be used. material. Skin contacl can be minimized by Precautions £~ Naterial is Released o.r wearing impervious protective clothing Spilledl Eliminate all open flame including rubber gloves, vicini,y of spill or released va~or. StOp Respiratory Protec~ion: Wear approved the source of the leifll or release. Cle~a respiratory protection such as an organic up releases as soon as ~ossible, observing va~or carlridge respirator or an air- precautions in Special Protective supplying respirator unless ventilation Information. Contain liquid to preven~ e<luipmenl is adequate to keep airborne further contamination of soil, surface concentrations below the reco~ended water or groun.dwater. Clean up small exposure standard, spills using appropriLate techniques such Ventilatio~: Use adequate Ventilation ~o as sorbent materials or pumping. Where keep airborne concentrations of this feasible and appropriate, remove material below the recommended exposure contaminated soil. Follow prescribed standard, procedures for reporl:ing and responding to larger releases. FIRE PROT~CTIOII #aste Disposal ~let/~xis: Place contaminated Liquid evaporates and forms vapors (fumes) materials in dispo:~able containers and which Can catch fire and burn with dispose of in a ma~uler consistent with explosive violence. Invisible 'vapor applicable regulations. Con,act local spreads easily and can be se, on fiI_~ by environmental or' he~lth authorities for many sources such as .p£1ot ligh, s, welding approved disposal of .this material. equipmen=, and electrical motor s and swi,ches. Fire hazard is greater as liquid RE~I¥IT~ DATA ~emgerature rises above 85eF. Stability (Ther~ml, Light, ~c.)= Stable Flash Point: (TCC)105~F(41°C) Min. In~ttk~li~y (Na~=ials to &void): May Au~oig~ition Temp.: 500°F· (260°C) teac, with s[ro~g ox:Ldizing materials. Fl~ewn~tlity Lileits: 1.0-6.0% Nazardous Decc~sit.~[on Products= Normal ~-ztinguishing Media: C02, Dry Chemical, combustion forms carkx)n dioxide and water Foam, Waler Fog. vaporl incomple~'.e co~nbustion can produce Special Fire Fighting Procedures: For carbon monoxide. Zires involving this material, do no, Bazardous Pol~m~iza1'-ion= Will no~ occur. enter any enclosed or confined fire spaces withou, proper ~rotective equipment. This PHYSICAL PROPER~IES may include self-con,ained brea,hing Solubility = Solubll-· in hydrocarbons appara,us to pro,ect agains~ the hazardous insoluble in waC;er.- effects of normal products, of combustion Appearance (Color, ~]or, etc.)= Colorless or oxygen deficiency. Read the entire liquid. MSDS. BOiling PO~.=: 166'~C (330 °F) 5% Rec. (Max.) SPECIAL PRECAUTIONS ~alttng Point= n/a See following pages Specific Gravit;y= 0.78 9 15.6/15.6eC Yapor Pressure: 5 n~n Hg @ 77eF Vapor Density (~.~tr=l'.)= ¢.8 Percent Volatile (¥oi[~ %): 99+ Evaporation= (Bu Ac=I) 0.22 ¥1$cosity= 0.96 cst La 37.8°C n/a ~ Not Appli¢:able The move mformmmn iS b~sed on dml of whmh we we Me md ~s beheved To be correct IS of the dire hereof. Since the mformmion comJ~r~ed herc.~ n~y be mpa,ed under conditions beyond our conlTol end w,th wh,cn we miy he unf~m~*~( ~na since ~ mode Ivl[llOle su~$equen! to c~e c~e ~ereot Tray suggeSl modLhc~Tmns ot the mforrn~uon, we od nol Issume my respofl$ib~hx¥ for the res~dts of sts use. ThJs Jnform~fon furn~s~e~ upon ~e condmon ttm t~e person recewmg ~! shall r~ke h~S own deTerm~rmtmn of tha Smtlb~it¥ of thl: mmerml for h~S p~n~cullr p~rpo:se. NO. 2 Material Safety Data Sheet OtEV~)~ Thinne~ 325 CPS 218223 ADDITIONAL g~-~LTH DATA No~ expected ~o be acutely ~oxic by skin absorption; ~he acute dermal LDo0 (rabbi~) for a similar [~roduc~ was grea~er =ban 19.1 g/kg. Signs and symptoms of central nervous $¥$~em effects may include one or more of ~he following: headache, dizziness, loss of appe~i~e, weakness and loss of coord£na=ion. Affected persons usually experience complete recovery when removed from exposure area. SPECIAL PRE~UTI0~iS READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL. DO NOT USE OR STORE near flame, sparks, or ho~ surfaces. USE ONLY IN WELL VENTILATED AREA. Keep con~ainer closed. DO NOT weld, hea~ or drill con=airier. Replace cap or bung. Emptied con=airier contains hazardous or explosive va~or or liquid. CAUTION! Do no~ use ~ressure ~o empty drum or explosion may result. ~MIS ~d Ra~lng: Reactivity: 0, Flanm~bili~y: 2, Health: 1 3 Rev. 12 06/29/87 HILL BROTHERS CHEMICAL COMPANY 1-5017 E. Clark Ave., City of Industry, California 91745 / (213) 333-2251 CAS No. 1336216 SECTION I NA 2672 CHEMICAL NAME: Ammonium Ilydroxide CItFMICAL FAMILY; Inorganic Bases ? SYNONYMS: ~ N~(JL[CUL_A~ W[IGHI: TnAOE NAM[: Aqua ~m~0nia- ~ ~:O.,-',,L~ Ifil,lUll SECTION II- HAZARDOUS INGREDIENTS PAINTS' PRESERVATIVES. & SOLVENTS i N TLV ALLOYS AND METALLIC COATINGS (Un,~tl iUn,~tt PIGMENTS BASE CATALYST ALLOYS V EttlCLE NIETALLIC CO~TItIGS SOLVENTS FILL[l; ME PLUS COATI~G O~ CORE FLUX ~omt,ves OtHe.S Aqt~a ~nmonia 24.5% Nil5 __ _ L~en ~.~'a ~z_ ___, ~ ..... TVL HAZARDOUS MIXTURES OF OTHER LIO~ID~, SOLIDS, Off GASES (Unii,l / SECTION IV- FIRE AND EXPLOSION HAZARD DATA EXTINGUISHING MEDIA Non-Flammable undeF ~L~~~ NFPA 704M I~SOAL FIR~NO EXPLOSION HAZAIID~ ' - (C~tinued on rmYmrtl HRESHOL[:) LIMIT VALUE S ppm (amlnon[a vapor) or 18 ing/H$ EFFECTS OF OVEREXPOSURE _ Irritation of eyes~ upper resl)iratarv tract and skin. EMERaENCY ^NO FIRST ^'O PROCEDURES Inhalation: Remove to fresh air, apply artificial respiration, Ret medical attenti Eye Contact: Flush with water for at least 15 min,~.LE~_/?t medical attentim~. Skin Contact: Flush with water, In2estion' gel mqdi[a} attention, SECTION VI. REACTIVITY DATA STABILITYSTABLE UNSTABLE INCOMPATIBILITY (~lat~alt rD Corrodes cold,er~ and copper alloys. HAZARDOUS DECOMPOSITION PHODUCTS POLYMERIZATIoNHAZAROOUS J MAY OCCUR J CONDITIOr~S TO AVOID I W~LLNOT OCCUR J I SECTION VII - SPILL OR LEAK PROCEDUHES STEPS TO BE TAKEN IN CASE I_MATERIAL IS RELEASED OR SPILLED Flusi~ wit-h plenty of water. I~, WASTE DISPOSAL ME'IHO[3 ....................................... Flush with ple~ty oi: water. DISPOSAL MUST CONFORM TO ALL LOCAL, STATE /AND FEOERAL LAWS SECTION VIII- SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION {Speclf), rypc) , Chemical cartrid2e respxrator; cannister masL, self co LtaJ~ied_brerLching,. app~ :cc. VENTILATION tOJ LO~AL EXHAUST SPECIAL keep NH3 below 25ppm j MECHANICAL /Gcnerall See HCSDS; SD-IS section 6.2 PROTECTIVE GLOVES J EYE PROTECTION ~bber [ Gas tight OTHER PROTECTIVE cotton clothing and rubber nnrm]s are recnmmen:ied_ fihem 5;~fe[y data sheet SD-I3 section 8.5.4 - ' SECIION IX- SPECIAL PHECAUIIONS PRECAUSTIONS TO fie TAKEtJ IN ;tAtqDLING AND StOnltlg · :j Refer to Hanufactu~n~ Ct~emists Associat~onz chemical safe~:)' data sheet ~age 5 wa~ning on ]abels. OTHE~ P~ECAUSTIONS b<.~'~ed ffo~'~ the ~ I~er~O4. Revised: .5/1/8,1 P~ 2 HANUFACTURER ~ Effex Corporation PRODUCT I 5600 NW 12 Avenue ..................................... ; ..................................... t Ft. Lauderdale, FL 33309 Trade Name: Hagic Hlst Fragrance I Product No: 310-340-L I Business Phone: 305-771-4994 I Emergency Phone: 800-952-5223 L. J I " J SECTION I - PHYSICAL DATA Appearance and Odor: Nearly colorless liquld with a fresh, pine-like aroma. Speclfic Gravlty: 0.768 Vapor Pressure: Not determined. Bolllng Polnt: Not determined. Vapor Denslty: Heavler than air. Evaporation Rate: Slower than N-Butyl Acetate. Water Solubility: Insoluble SECTION II - FIRE AND EXPLOSIOH Flash Point: 127 degrees F Tag Closed Cup Flammable Limits: Not determined. Extinguishing Media: Carbon Dloxlde, Foam or Dry Chemlcal 5peclal Fireflghting Class B fire procedures. Wear NIOSH-approved respirator Procedures: and full protective gear. Unusual Flre and None Known. 'Treat as a combustible 11quld, as appropriate. Explosion Hazards: 10/15/90 Page I of 4 /FP Page 2 of 4 /FP SECIION III - HAZARDOUS INGREDIENTS The specific components of this product constitute a trade secret. Listed below are components reported in tests with laboratory animals to have hazardous prop- erties other than combustibility oF flammability or eye and skin irritation from excessive contact. Bott) of these hazards are addressed elsewhere on this data sheet. The relevancy of animal test data on these components to the mixture as a ~hole or to humans has not been established. MATERIAL or COMPONENI HAZARD DAlA Petroleum Distillates PEL: 500 ppm On continual overexposure: irritant vapor. Note that these possible effects in test animals were reported for continual overexposure to components of thls mixture. Many of the substances having such effects are natural components of common foods and are not kno~m to be harmful in normal use. SECTION IV - REACTIVE DATA Stability: Stable. Hazardous Polymerization: Will not occur. Incompatibility: Strqng oxidizing agents. Hazardous Decomposition Products: Carbon dioxide or carbon monoxlde and smoke on combustion. I SECTION V - HEALTH HAZARD INFORtiATION I I I I I I Primary Routes of Exposure: Skin contact and inhalation. I-.. Page 3 of 4 /FP Effects of Overexposure: Eyes: Can cause severe irritation, tearing, and redness, or blurred vision. Skin: Prolonged or repeated contact can cause irritation, defatting or dryness of skin, or dermatitis. Inhalation: Excessive inhalation of vapors can cause irritation of the respiratory tract, nausea dizziness, or headache. Swallowing: Can cause serious health effects including nausea, vomiting, or gastrointestinal irritation. No information is available on chronic overexposure to this product. Available data on components of the product listed in Section IV indicate the following possible hazards. High concentrations of vapor may cause irritation to respiratory tract. Medical Conditions Aggravated By Exposure: None known. Emergency First Aid Procedures: 5kin: Wash thoroughly with soap and water. Remove contaminated clothing. Eyes: Flush with water for at least 15 minutes, get medical attention. Ingestion: Induce 'vomiting. See physician immediately. Inhalation: If affected by vapors, get to fresh air. If breathing is difficult, see physician. Aspiration of substantial amounts of liquids into the lungs can be fatal-get immediate medical attention. I SECTION VI - SPILL OR LEAK PROCEDURES I I I In case of Spill: Remove ignition sources, Contain spill, then absorb I with suitable chemical absorbant material. .I I , Page 4 of 4 /FP e Waste Disposal Method: Soak up with absorbant material for incineration or burial in approved land fill, away from ground waters. Observe local, state, and federal regulat~ions. SECTION VII - SPECIAL PROTECTION INFORMATION Respiratory protection: None normally required with adequate ventilation. Ventilation: Local exhaust is recommended, gener,~l mechanical ventilation is usuaI1y adequate. Eye Protection: Safety glasses or goggles should be worn in industrial operations. Gloves: Rubber or neoprene. Other Protective Equipment: Eye wash and safety shower. r I SECTION VIII - SPECIAL PRECAUTIONS I- I I HandZe as combustible liquid. Avoicl eye contact and prolonged contact with skin. Use only with adequate ventilation. Wash thoroughly after handling. SECTION 313 SUPPLIER NOTIFICATION: This product contains the following toxic chemical's subject to the reporting re- qu[rements of Section 313 of the Emergency Planning and Community Right-to-Knou Act of 1986 and of 40 CFR 372: CAS NUMBER CHEMICAL NAME ~ BY WT I The information in this Material Safety Data Sheet is believed to be reliable, but is provided without warranty regarding its accuracyr Users must determine safe conditions for use and assume liability for any lo;ss, injury, damage, or expense resuIting from use of this product. BEAVER. MATI IIIAL SAFETY DATA ,'IEET ,.,-~,,-, .... -, SECTION 1'- MANUFACTURER OR SUPPLIER DATA BV8611A3340×) [,, ,.~~ MANUFACTURER'S NAME & MAIUNG ,~I~)ORESS PREPARED BY JOHN R. BINGHAH A SIGNATURE BEAVER CHEHICAL COMPANY, INC. ,~LE 1448 SHAW ROAD P.O. BOX' 8'599' ,, QUALITY CONTROL MANAGER STOCKTON. CA 95208 OATE JUNE, 1986 EMERGENCY TELEPHONE NO. 209/9&8-3035 or &14/778-7878 (24 HOUR SERVICE) SECTION 2 - IDENTITY OF MATERIAL PRODUCT NAME AQUA AMMONIA PRODUCT DESCRzP/10N Heavy Duty Alkaline Cleaner FORMULA CHEMICAL FAMILY '- Nlt4 OH Inorganic Base DOT PROPER SHiPP1NG NAME REGULATED Ammonium Hydroxide IDENTIFICATION SHIPPING IO NUMBER HAZARD CLASS NA2672 Corrosive Material SECTION 3 - PHYSICAL/CHEMICAL CHARACTERISTICS BOLING POINT SPECIFIC GRAVITY (H~ · 1) COLOR N.A. .90 Wate.r White VAPOR PR~ (mm Hg.] MELTING POINT SCENT (, '.' ~ 200 @ 32PC 72°C A Burning,, Pungent Odor '~' VAJ:~R [~N~ffY lAIR · 1] EVAPORATION RATE pH CONCENTRATE [I~JTYL ACETATE · 1] · 6 N.A. Greater Than 14.O SOLU~LITY IN, WATER PHYSICAL FORM pH 2500 ppm SOLUTION Complete Liquid OTHER SECTION 4 -HAZARDOUS INGI~IEDIENTS/IDENTITY INFORMATION HAZAROOUS COMPONENTS OSHA ACGIH OTHER LIMITS PERCENT (CHEMICAL NAME: COMMON NAME) REL TLr RECOMMENDED [OPTIONAL] Ammonium Hydroxide: Ammonia Solution 50 PPM 25 PPH 35 PPH STEL )l.0 (CAS Registry No. 1336216) as NH3 as Nil,,,t as NH] (ACGIH) This product contains no other ingredient considered hazardous according to the criteria of 29 CFR 1910.1200, OSHA. CAJ:ICINOGENIClTY NIP IARC OSHA KNOWN CARCINOGEN: .~' None This product does not contain known carcinogens any or anticipated · ANr~A?EOCA~C~OGEN: carcinogens according to t-~ criteria o t e NTP nua eport on None Carcinogens, IARC Monographs, and OSHA 29 CFR 1910, Subpart Z. THE DATA IN THIS MATER~AL SAFETY DATA SHEET RELATES ONLY TO THE .~4:~C~F'IC MATERIAL DESIGNATED AND DOES NOT RELATE TO ITS USE IN COMBINATION WITH ANY OTHER MATERIAL OR Pf:~;)C, ESS. THE DATA CONTAINED IS BEUEVED TO BE AC;O. JRATE. HOWEVER, SiNC~ USE CONDITIONS VARY AND ARE OUTSIDE OUR CONTROL, BEAVER CHEMICAL COMPANY, INC. MAKES NO WARRANTIES, EXPRESSED OR IMPUED. AND ASSUMES NO MA~UTY FOR FAILURE TO FOLLOW PRODUCT USE DIRECTIONS AND SAFETY PRECAUTIONS i EYES PAOTECTIVE .Safety glasses, .sa goggles, and an eyeTvash station.. EOUIPMENT RESPlIqATOn¥ ~ GLO~ES :l~ ... TY~ES None. ~equt~ed vtth no~l use, ' ': '~ Rubbe~ (Latex) o~ Reopteae Gauntlet type. Wear full-cover protective clothing to prevent zepeated or prolonged contact. GENEDAL MECNANICAL . , . LOCAL EXHAUST ' ' .' . '. :.. NOt ordinarily needed. Avoid inhalation of mists containing th:La product. HANOUNG&STOnAGE Follow all label directions. Instruct personnel about p~oper'uae, hazards, PnECAUTtON8 precautions, and first-aid measures. Avoid i~alation, ~ngestton and contact with skin and eyes. omen Rotate stock reguiarly. Handle carefully to avoid da~Einl~ contai~r. ~ep container :losed ~hen no~ in use. ~commended storage te~. bel~ 100CF. Keep out of children's reach. SECTIO~ Z - HEALTH HAZARD DATA~ ,~A~O~ Excessive amounts may cause coughing, irritation to nose, throat and eucoue EFFECTS OF INGESTION Excessive amounts ~y ca~e tissue dmge to the ~8estive tract, na~ea, vo~ttn8, tissue d~aEe, nause% dizziness and headache. EXPOSURE disc0mfort,, dizziness, and headache. " .. . SK~NaEVES.SKIN: Contact ~y cause irritation, d~in8, bu~s, .bli,ters, ~d de~titis, ' Cofitadi ~ cause blinking, teiring, ' irritation,, burns, lo~s of visi0~, and .blindness. '.:. ~ ........ SECTIO~ 7 - PHYSICAL HAZARD DATA UEL = ~.A. M~HOD~ED N.A. STABLE ~ co~omo~s TO avo~oHtxing vi th any other cleaning product. Htx only with water. ~ Do not store at high te~eratures. Be1~ 100e is reco~nded. 'bNS1~BLE F~r~AnOOuSD[COMPOS~1~ON~OUCtS ~arntngl Hydraztne, chlorine, and chlora~nes . may be produced if chlorine is acctdently.mixed ~ith this product. MAY OCCU~ CONDITIONS TO AVOID HAZARDOU~ N.A. POLYMERIZ&TION WILL NO~ 0CCU~ . MATE~;A~ TO AVOIO S~rong oxidizers, hyp0chlori~e bleaches, gold, ~rcu~, sliver, ~alt,~e~, and acids. SECTIO~ 8 - EMERO~CY RESPONSE DATA EXTiNGUiShinG MED~A To fight fire ~e carbon dioxide, d~ che~cal or alcohol foam. Frae S~EC~AL P~OCEDUnE5 Evacuate area of unprotected personnel. ~ear protective c~Lothin8 in~lud~g a NiOSH-approved self-contained breathing apparatus. U~USU~L a~A~5 Fire causes evolution of toxic and irritating f~ee. ~A~O~ Hove victim to fresh air. If breathing is difficult o~ has stopped, give o~8en apply artificial respiration as needed. See a physician. EXPOSURE - FI~STalO INGESTION Rinse mouth at once. Dri~ milk, citrus Juice or water.' Do not induce MEaSUaES give anything by mouth to an unconscious person. See a physician l~diat:ely.. S~&E~ES SKIN: Remove contaminated clothing and flueh with water for 15 minutes. ~ES: Hold eyelids open and i~edia~ely flush with tepid water for 15 minutes. See a physician. 5~EPSTOeE~A~f~ Wear protective equip~nt ~nc]uding rubber b~ote. Stop leak if you can do Sm~LS ~ithout risk. Dike or dam large spills. Soak up with sand or other non-co~ustible i~rt no= ] absorbent ma~::erlals. Flush area with water and foll~ with no~al clean-up procedures. N.A. [ Keep combustibleSM a~ayl ~ careful as spills are slippe~. I ' - ply ~ith all federal, state, and local regulations. Consult state and ' local authorities for restrictions on disposal of chemical ~aste. If approved, may be diluted [~a-'~ai~&~'~UHictpal sever or ~aste treat~nt plant. Rinse empty container thoroughly ~'ith water bt-Tore discardin~. M IrERIAL SAFETY DATA HEET SeptemberL'4638'A1985 An explanation of the terms used herein may be found in OSHA 29 CFR 1910.1200, available from OSHA regional or area offices. (Essentially similar to U.S. Department of Labor Form OSHA-20 and generally accepted in Canada for information purposes) Do Not Duplicate This Form. Request an Original. PRODUCT Oxygen CHEMICAL NAME Oxygen SYNONYMS Not applicable FORMULA 02 CHEMICAL FAMILY Not applicable MOLECULAR WEIGHT 32.00 TRADE NAME Oxygen For mixtures of this product request the respective component Material Safety Data Sheets. See Section IX. MATERIAL (CAS NO.) Wt (%) 1984-1985 ACGIH TLV-TWA (OSHA-PEL) Oxyg(~n (7782-44-7) 100 None currently established (None currently established) BOLLING POINT, 760 mm. Hg -183°C (-297.4°F) FREEZING' POINT -218.4°C (-361.1 °F) SPECIFIC GRAVITY (1120 = 1) Gas VAPOR PRESSURE AT 20°C. Gas VAPOR DENSITY (air = 1) 1.105 @ 25°C SOLUBILITY IN WATER, % by wt. Negligible PERCENT VOLATILES EVAPORATION RATE BY VOLUME 100 (Butyl Acetate = 1) Not applicable APPEARANCE AND ODOR Colorless, odorless gas at normal temperature and pressure. IN CASE OF EMERGENCIES involving this material, further information is available at all times: In the USA 1-800-UCC-HELP (1-800-822-4357) In Canada 514 -- 640-6400 For routine information contact your local supplier Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION [] LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION Copyright © 1985 Union Carbide Corporation Page I of 4 PRODUCT: Oxygen L-4638-A iI e 4) September 1985 '~. ./: THRESHOLD LIMIT VALUE: None currently ~stablished. EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE: SWALLOWING -- No evidence of adverse effects from available information. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- Breathing 80% or more oxygen at atmospheric pressure for more than a few hours may cause nasal stuffiness, cough, sore throat, chest pain and breathing difficulty. Breathing oxygen at higher pressLrre increases the likelihood of adverse effects within a shorter time period. Breathing pure oxygen under pressure may cause IL,ng damage and also central nervous system effects resulting in dizziness, poor coordination, tingling sensation, visual and hearing disturbrances, muscular twitching, unconsciousness and convulsions. Breathing oxygen under pressure may cause prolongation of adaptation to darkness and reduced peripheral vision. SKIN CONTACT -- No evidence of adverse effects from available information. EYE CONTACT -- No evidence of adverse effects from available information. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: See "Notes to Physician." MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: See "Notes to Physician." SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD EV,~.LUATION: None currently known. EMERGENCY AND FIRST AID PROCEDURES: -~.- SWALLOWING -- This product is a gas at normal temperature and pressure. SKIN -- No emergency care anticipated. INHALATION ~ Remove to fresh air. Give artificial respiration if not breathing. Keep victim warm and at rest. Call a physician. EYES -- No emergency care anticipated. NOTES TO PHYSICIAN: Supportive treatment should include immediate sedation, anti-convul-~ive therapy if needed, and rest. Animal studies suggest that the administration of certain drugs, including phenothiazine drugs and chloroquine, /ncreases the susceptibility to toxicity from oxygen at high concentrations or pressures. Animal studies also indicate that vitamin E deficiency may increase susceptibility to oxygen toxicity. Airway obstruction during high oxygen tension may cause alveolar collapse following absorpt, ion of the oxygen. Similarly, occlusion of the eustachian tubes may cause retraction of the eardrum and obstruction of the paranasaJ sinuses may produce "vacuum-type" headache. Newborn premature infants exposed to high oxygen concentrations may suffer delayed retinal damage wl~ich can progress to retinal detachment and blindness (retrolentat fibroplasia). Retinal damage can also occur in adults e;;po.;;ed to 100% oxygen under greater than atmbspheric pressure, particularly in individuals whose retinal circulation has been pre¥iously compromised. All individuals exposed for long periods to oxygen at high pressure and all who exhibit overt oxygen toxicity should have ophthalmologic examinations. WHEN USED IN WELDING AND CUTTING: Read and understand the manufacturer's instructions and the precautionary label on the product. See American Standard Z49.1 "Safety In Welding and Cutting" published by the American Welding Society, RO. Box 351040, Miami, Florida 33135 and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more detail. For further SAFETY AND HEALTH information, refer to Linde's free publication, L-52-529, "Precautions and Safe Practices for Electric Welding and Cutting", as well as L-2035, "Precautions and Safe Practices for Ga,,~ Welding, Cutting, and Heating." You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Linde Division, Communications Department, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. NOTE: Suitability for use as a component in underwater breathing gas mixtures is to be deter'mined by or under the supervision of personnel experienced in the use of underwater breathing gas mixtures and familiar with the eff,;cts, methods, frequency and duration of use, hazards, side effects and precautions to be taken. Page 2 of ,4 PRODUCT: Oxygen L-4638-A September 1985 FLASH POINT AUTOIGNITION (test method) Not applicable TEMPERATURE Not applicable FLAMMABLE LIMITS I LOWER UPPER IN AIR, % by volumeI Not applicable Not applicable EXTINGUISHING MEDIA: Vigorously accelerates combustion. Use media appropriate for surrounding fire. Water (i.e. safety shower) is the preferred extinguishing media for clothing fires. SPECIAL FIRE FIGHTING PROCEDURES: Evacuate all personnel from danger area. Immediately cool containers with water spray from maximum distance until cool, then move containers away from fire area if without risk. UNUSUAL FIRE AND EXPLOSION HAZARDS: Oxidizing agent, vigorously accelerates combustion. Contact with flammable materials may cause fire or explosion. Container may rupture due tO heat of fire. No part of a container should be subjected to a temperature higher than 52°C (approximately 125°F). Most containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. S.moking, flames and electric sparks in the presence of enriched oxygen atmospheres are potential explosion hazards. STABILITY I CONDITIONS TO AVOID: See Section IX. I UNSTABLE STABLE X INCOMPATIBILITY (materials to avoid): Combustible materials, asphalt, flammable materials, especially oils and greases. HAZARDOUS DECOMPOSITION PRODUCTS: None. HAZARDOUS POLYMERIZATION CONDITIONS TO AVOID: None currently known. May Occur Will not Occur X STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Shut off leak if without risk. Ventilate area'of leak or move leaking container to well-ventilated area. Remove all flammable materials from vicinity. Oxygen must never be permitted to strike an oily surface, greasy clothes, or other combustible material. WASTE DISPOSAL METHOD: Slowly release into atmosphere, in an open, outdoors area. Remove all flammable materials from vicinity. Page 3 of 4 PRODUCT: Oxygen {~l L-4638-A ' ~ September 1<-J85 ~-.~. ~, RESPIRATORY PROTECTION {specify type): Not required. LOCAL EXHAUST -- Not applicable. MECHANICAL (general) -- Acceptable. VENTILATION SPECIAL -- Not applicable. OTHER -- Not applicable. PROTECTIVE GLOVES: Preferred for cylinder handling. EYE PROTECTION: Select in accordance with OSHA 29 CFR 1910.133. OTHER PROTECTIVE EQUIPMENT: Metatarsal shoes for cylinder handling. Select in accordance with OSHA 29 CFR 1910.132 and 1.910.133. WARNING: High pressure gas. Vigorously accelerates combustion. Avoid contact with oils, greases and other flammable materials. Never use manifolds for oxygen cylinders unless specifically designed for such use. Use only with equipment conditioned for oxygen service. Use piping and equipment adequately designed to withstand pressures to be encountelred. Protect container against physical damage. Isolate from combustible gas installations and combustible materials by adequate distance or by gas-tight, fire-resistive barriers. Protect against over-heating. Never use an oxygen jet for cleaning purposes of any sort, especially clothing, as it increases the likelihood ~' of an engulfing fire. Note: Reverse flow into cylinder may cause rupture. Use a check valve or other protective apparatus in any line or piping from the cylinder to prevent reverse flow. MIXTURES: When two or more gases, ~3r liquefied gases are mixed, their hazardous propertiies rnay combine to create.additionai, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties' which can cause serious injury or death. Be sure to read and understand all labels and other instructions supplied with all containers of this product. NOTE: Compatibility with plastics should be confirmed prior to use. For safety information oN, general handling of compressed gas cylinders, obtain a copy of pamphlet P- 1, "Safe Handling of Compressed Gases in Containers" l'rom the Compressed Gas Association, Inc., 1235 Jefferson Davis Highway, Arlington, VA 22202. OTHER HANDLING AND STORAGE CONDITIONS: Never work on a pressurized system. If there is a leak, close the cylinder valve, blow down the system by venting to a safe place, then repair the leak. Never lubricate oxygen valves, regulators, etc., with any combustible substance. :, The opinions expressed herein are those of qualified experts within Union Carbide. We believE; that the in[ormation contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and 'these (~,pinions and the conditions of use of the product are not within the control of Union Carbide, it is the user's obligation tc, determine the conditions of safe use of the product. LINDE o .c s ........ IN THE USA: IN CANADA: ~l UNION CARBIDE Union Carbide Corporation Union Carbide Canada Limited Linde Division Linde Division 39 Old Ridgebury Road 1;.)3 Eglinton Avenue East Danbury, CT 06817-0001 Toronto, Ontario M4P 1J3 Other offices in principal cities ali over the world. L-~*~S-~k rSS-O~J2S 9185 45M Lithographed in U.S.A. Page 4 of 4 L-4559-E SAFETY EET Apr, 1987 explanation of the terms used herein may be found in OSHA 29 CFR 1910.1200, available from OSHA regional or area offices. (similar to U.S. Department of Labor Form OMB No. 1218-0072 and generally accepted In Canada for Information purposes) Do Not Duplicate This Form. Request an Original. PRODUCT Acetylene CHEMICAL NAME Acetylene SYNONYMS Acetylen, Ethine, Ethyne, Narcyiene FORMULA C2H2 CHEMICAL FAMILY Alkyne MOLECULAR WEIGHT 26.036 TRADE NAME Acetylene (This product is intended for we~ding and cutting use.) This section covers the materials from which this product is manufactured. The fumes and gases produced during welding and cutting with the normal use of this product are covered by Section VI. The term "hazardous" should be interpreted as a term required and defined in OSHA 29 CFR 1910.1200 and does not necessarily imply the existence of any hazard. MATERIAL (CAS NO.) Vol (e/~) 1986-1987 ACGIH TLV-TWA (OSHA-PEL) Acetylene (74-86-2) 100 Simple asphyxiant (None currently established) Acetylene cylinders are filled with a porous material containing acetone into which the acetylene is dissolved. ACGIH has established a TLV-TVVA of 750 ppm for acetone and a STEL of 1000 ppm. BOILING POINT, 760 mm. Hg Not Applicable SUBLIMATION POINT -84°C (-119.2°F) @ 760mm Hg SPECIFIC GRAVITY (H20 = 1) Not Applicable VAPOR PRESSURE AT 21 °C. 635 psig VAPOR DENSITY (air = 1) 0.91 'SOLUBILITY IN WATER, % by wt. Slight PERCENT VOLATILES EVAPORATION RATE BY VOLUME 100 (Butyl Acetate = 1) Not Applicable APPEARANCE AND ODOR Colorless gas at normal temperature and pressure; garlic-like odor. IN CASE OF EMERGENCIES involving this material, further information is available at all times: m In the USA 1-800-UCC-HELP (1-800-822-4357) In Canada 514-645-5311 ~ For routine information contact your local supplier ~ru~ Union Carbide requests the users of this product to study this Material Safety Data Sheet (MSDS) and become aware of product ', hazards and safety information. To promote safe use of this product a user should (1) notify its employees, agents and contractors of the information on this MSDS and any product hazards and safety information, (2) furnish this same information to each of its customers for the product, and (3) request such customers to notify their employees and customers for the product of the same product hazards and safety information. UNION CARBIDE CORPORATION [] LINDE DIVISION UNION CARBIDE CANADA LIMITED [] LINDE DIVISION Copyright © 1985, 1986, 1987 Union Carbide Corporation Page 1 of 4 PRODUCT: Acetylene ~ ~ L-4559:E April 1987 THRESHOLD LIMIT VALUE: Acetylene - Simple asphyxiant ACGIH 1986-87; Acetone, 750ppm ACGIH 1986-87 EFFECTS OF SINGLE (ACUTE) OVEREXPOSURE SWALLOWING -- An unlikely route of exposure, but frostbite of the lips and mouth may result from contact with the liquid. If the liquid is swallowed, may cause nausea. SKIN ABSORPTION -- No evidence of adverse effects from available information. INHALATION -- Asphyxiant. Moderate concentrations of vapor may cause headache, drowsiness, diz=:iness, nausea, vomiting, excitation, excess salivation, and unconsciousness. SKIN CONTACT -- No harmful effects expected from vapor. Liquid may cause frostbite. EYE CONTACT --Vapor may cause irritation. Liquid may cause irritation and frostbite. EFFECTS OF REPEATED (CHRONIC) OVEREXPOSURE: No evidence of adverse effects from available information. OTHER EFFECTS OF OVEREXPOSURE: None currently known. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: A knowledge of the available toxicol~[ly information and of the physical and chemical propei'ties of the material suggest that overexposure is unlikely to aggravate e):isting mediical conditions. EMERGENCY AND FIRST AID PROCEDURES: SWALLOWING -- If liquid is swallowed, do not induce vomiting. Call a physician. SKIN -- For exposure to liquid, flush with water and warm frostbite area with warm water (not 1:o exceed 1.05 °F). In case of massive exposure, remove clothing while showering with warm water. Call a physician. INHALATION -- Remove to fresh air. If breathing has stopped, give artificial respiration; if breathing is difficult, oxygen may be given; call a physician. EYES -- In case of splash contamination, immediately flush eyes thoroughly with water for at least 15 minutes. Seek the advice .-J **-'~ of a physician, preferably an ophthalmologist, urgently. NOTES TO PHYSICIAN: Aspirated acetone may ca'use severe lung damage, ifa large quantity of niaterial has been swallowed, stomach contents should be evacuated quickly in a manner which avoids aspiration. Otherwise, treatm~=,nt should be directed at the control of symptoms and the clinical condition. No specific antidote is known. WORKING WITH WELDING AND CUTTING MAY CREATE ADDITIONAL HI-'ALTH HAZARDS. FUMES AND GASES can be dangerous to your health and may cause serious lung disease.* Keep your head out of the fumes. Do not breathe fumes and gases cauSed by the process. Us~e enough ventilation, local exhaust, or both to keep fumes and gases from your breathing zone and the general area. The type and amount of l=umes and gases depend on the equipment and supplies used. Possibly dangerous materials may be found in fluxes, coatings, gases, metals etc. Get a Material Safety Data Sheet (MSDS) for every material used. Air samples can be used to find out what respiratory protection is needed. Short term overexposure to fumes may result in discomfort such as dizziness, nausea, or drynes:~ or irritatie,n of nose, throat, or eyes. *NOTES TO PHYSICIAN: Acute --Gases, fumes, and dusts may cause irritation to the eyes, lungs, nose, and throat. Some toxic gases associated with welding and related processes may Cause pulmonary edema, asphyxiation, and death. Acute overexposure may include signs and symptoms such as watery eyes, nose and throat irritation, headache, dizziness, difficulty breathing, frequent . coughing, or chest pains. Chronic --Protracted inhalation of air contaminants may lead to their accumulation in the I~ng,,~, a condition which may be seen as dense areas on chest x-rays. The severity of change is proportional to the lenglth o! exposure. The changes seen are not necessarily associated with symptoms or signs of reduced lung function or dise;ase. In addition, the changes on x-rays may be caused by non-work related factors such as smoking, etc. A detailed description of the Health Hazards and their consequences may be found in Linde's free publiication "Precautions and Safe Practices for Electric Welding and Cutting," L52-529. You may obtain copies from your local supplier, or by writing to Union Carbide Corporation, Linde Division, Communications Department, 39 Old Ridgebury Road, Danbury, Connecticut, 06817-0001. MIXTURES: When two or more gases, or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an Industrial Hygienist, or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause Serious injury or death. Page 2 of 4 .PRODUCT: Acetylene - L-4559-E April 1987 FLASH POINT I AUTOIGNITION (test method) -17.8°C (0°F) T.C.C. I 299°C (571 °F) TEMPERATURE FLAMMABLE LIMITS I LOWER r UPPER IN AIR, % by volume 2'3% 100% EXTINGUISHING MEDIA See paragraphs below. SPECIAL FIRE FIGHTING PROCEDURES Refer to CGA pamphlet SB-4, "Handling Acetylene Cylinders in Fire Situations." Evacuate all personnel from danger area. Immediately cool containers with water spray from maximum distance taking care not to extinguish flames. Remove ignition sources if without risk. If flames are accidentally extinguished, explosive re-ignition may occur. Use self-contained breathing apparatus. Stop flow of gas if without risk while confining cooling water spray. Remove all containers from area of fire if without risk. Allow fire to burn out. On-site fire brigades must comply with OSHA 29 CFR 1910.156. UNUSUAL FIRE AND EXPLOSION HAZARDS Extremely flammable gas. Forms explosive mixtures with air and oxidizing agents. Container may rupture due to heat of fire. Do not extinguish flames due to possibility of explosive re-ignition. Flammable vapors may spread from leak. Explosive atmospheres may linger. Before entering area, especially confined areas, check atmosphere with approved explosion 'meter. No part of a container should be subjected to a temperature higher than 52°C (approximately 125°F). All containers are provided with a pressure relief device designed to vent contents when they are exposed to elevated temperature. Contact with copper, silver, or mercury or their alloys or halogens can cause explosion and be ignited by pilot lights, other flames, smoking, sparks, heaters, electrical equipment, static discharge or other ignition sources at locations distant from product handling point. STABILITY CONDITIONS TO AVOID UNSTxABLE I STABLE Stable as shipped. Avoid use at pressures above 15 psig. INCOMPATIBILITY (materials to avoid) Copper, silver, mercury or their alloys, oxidizing agents, acids, halogens, moisture. HAZARDOUS DECOMPOSITION PRODUCTS Thermal decomposition or burning may produce CO/CO2H2. The welding and cutting process may form reactionprOducts such as carbon monoxide and carbon dioxide. Other decomposition products of normal operation originate from the volatilization, reaction or oxidation of the material being worked. HAZARDOUS POLYMERIZATION I CONDITIONS TO AVOID MayOc~ur J .......................... Will not OccurI Elevated temperature and pressure andlor the presence of a catalyst. STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Forms explosive mixtures with air (See Section V). Immediately evacuate all personnel from danger area. Use self-contained breathing apparatus where needed. Remove all sources of ignition if without risk. Reduce vapors with fog or fine water spray. Shut off leak if without risk. Ventilate area of leak or move leaking container to well-ventilated area. Flammable gas may spread from leak. Before entering area, especially confined areas, check atmosphere with appropriate device. WASTE DISPOSAL METHOD: Prevent waste from contaminating surrounding environment. Keep personnel away. DiScard any product, residue~ disposable container or liner in an environmentally acceptable manner, in full compliance with Federal, State and local regulations. Page 3 of 4 PRODUCT: Acetylene O ei L'4559"E ~ "' ~' April 1987 RESPIRATORY PROTECTION (specify type) -- Use respirable fume respirator or air supplied respirator when working in confined space or where local exhaust or ventilation does not keep exposure below TLV. Select a.,~ per OSHA29 CFR1910.134. LOCAL EXHAUST -- Use enough ventilation, local exhaust or both, to keep th,e fume:s and gases below TLV's in the worker's breathing zone and the general area. Train the worker to keep h~is head out of the fumes. MECHANICAL (general) ALWAYS WORK WITH ENOUGH VENTILATION VENTILATION SPECIAL Not applicable OTHER Depends on specific use conditions, and location. Use adequate*ventilation or personal respiratory protebtion. See Section IX and OSHA29 CFR1910.252. PROTECTIVE GLOVES Welding gloves recommended EYE PROTECTION -- Wear goggles with filter lens selected as per ANSI Z49.1. Provide prot;;ctive screens and goggles, if necessary, to protect others. Select as per OSHA29 CFR1910.133. OTHER PROTECTIVE EQUIPMENT -- As needed, wear hand, head, and body protection which help to prew~=nt injury from radiation and sparks. See ANSI Z49.1. At a minimum this includes welder's gloves and protective goggles, a,ld may include arm protectors, aprons, hats, shoulder protection, as well as substantial clothing. Train the worker not to touch liw~ electrical parts. Fumes and gases cannot be classified simply. The composition and quantity of both are dependent upon the metal being worked, the process, procedure and electrodes used. Other conditions which also influence the composition, and quantity of the fumes and gases to which workers may be exposed include: coatings On the metal being worked (such a.,~ paint, plating, or galvanizing), the number of workers and the volume of the work area, the quality and amount of ventilation, the position o! the worker's head with respect to the fume plume, as well as the presence of contaminants in the atmosphere (such as chlori~nated hydrocarbon vapors from cleaning and degreasing activities). One recommended way to determine the composition and quantity of fumes and gases to which workers are exposed is to take an air sample from inside the worker's helmet if worn or in the worker's breathing zone. See ANSlIAWS F1.1, available from the American Welding Society, 550 N.W. Le Jeune Rd., Miami, FL 33126. Read and understand the manufacturer's instructions and the precautionary label on the product. See American National Standard Z49.1, "Safety In Welding And Cutting" published by the American Welding Society and OSHA Publication 2206 (29CFR1910), U.S. Government Printing Office, Washington, D.C. 20402 for more details. For further safety and health information refer to Linde's free safety booklet L-2035. OTHER HANDLING AND STORAGE CONDITIONS Heat and sparks during use could be the source of ignition of combustible materials. Prevent Iires. Refer to NFPA 51B "Cutting and Welding Processes" and NFPA 50 "Oxygen-Fuel Gas Systems." IJse piping and equipment adequately designed to withstand pressures to be encountered. Gas can cause rapid suffocation due to 'oxygen deficiency. Store and use with adequate ventilation. Close valve when not in use and when empty. Never work on a pressurized system. Do riot strike arc on cylinder. The defect produced by an arc burn could lead to cylinder rupture. Do not ground cylinder. Sto~re in cool, dry, well ventilated area. Do not store near open flames. Electrical equipment should be explosion proof. Do not store with oxygen or other oxidizers. Protect cylinders from physical damage. Store cylinders in upright position secured to prevent falling over. R,efer to CGA Pamphlets P-1 and G-1 for recommendations. The opinions expressed herein are those of qualified experts within Union Carbide. We believe that the information contained herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and these opinions and the conditions of use of the product are not within the control of Union Carbide, it is.t~.h~ user's obligation to determine the conditions of safe use of the product. o .c s ::::-. IN THE USA: IN CANADA: ~1UNIONC,/I~IBIDE Union Carbide Corporation Union Carbiide Canada Limited Linde Division Linde Division 39 Old Ridgebury Road 1~23 I--glinton Avenue East Danbury, CT 06817-0001 Toro~r~to, Ontario M4P IJ3 Other offices in principal cities all over the world. t.-4559-E I}7-092S 4167 30M Lithographed in U.S.A. Page 4 of 4 eLAMSONCOR H^I IL)H P.O. BOA 4~/SVl~b~J~, ~ YO~K 13~1 PREPARED ACCCP. DZNG TO ll-mE 0Sl'~ HAZARD C(]NVIJNI~TICN STANDARD (29 CFR 1~10,1200). (Fo~'IER[.Y CA,,FD r'IATERIAL INF0~'IATION BULLETIN) · LAMSCNNO. 5 Part # BC-301712 TYPICAL OiMPCSITICN Highly refined base oil (CAS 72623-85-9) ~85% Thickener, rust and oxidation inhibitors ~-15% No Federal CSHA exposure standard or ACGIH TLV has been est_~blished for this material. PHYSIOLOGICAL & HEALTH EFFECTS ~CY & FIRST AID PBDCEDURES Expected to cause no more than minor Flush eyes in~ediately with fresh water eye irritation, for at least 15 minutes while howling the eyelids open. If irritation persists see a doctor. SKIN Expected to cause no more than minor Wash skin thoroughly with soap and water. skin irritation following prolonged Launder contaminated clothing. or frequently .repeated contact. May cause skin discoloration. INHALATION Not expected to be acutely toxic Since this material is not expected to by. inhalation, be an accute inhalation problem, no first aid procedures are re~,~ed. INGESTION Not expected to be acutely toxic If swallow~d, give water or n~lk to dr~r~k by ingestion, and telephone for n~dical adv/ue. Consult medical personnel before inducing v~nit- · ing. If medical advice cannot be obtained, then take the person and product container .. to the nearest medical emergency treat- ment center'or hospital. T~n~on Corporation, P.O. BOX 4857, Syracuse, NY 13221 Emergency Phone No. 315-432-5500 Fonn %0293 i Olz',;. ~Ultomef. Thrl ~4Jlwt,l COntlmS m~:x)ftlnl I~,~I~. ~dlh ~ tOl~y mlmmlt~ I~ y~ ~fft w~ fK~y P~ to h f~ ml~l ~. C~vfm U.S A ~ J cMateriai Safety Data Sheet ~2repared According Io the OSHA Hazard Communication Standard (29 CFR 1910.1200L (Formerly Called MATERIAL INFORMATION BULLETIN} CHEVRON Universal Gear Lubricant SAE 80W-90 CPS 250102 T~PICAL Highly refined base oils (CAS 64742-54-7 or 64742-65-0 or 72623-85-9, and/or 64742-57-0 or 72623-83-7 or 64742-01-4) >90% 'Additives including inhibitors and extreme pressure agent and/or thickener (CAS 9003-27-4) <10% ~3SUI~ STANDARD NO Federal OSHA exposure standard or ACGIH TLr has been established for this material. Based upon information reviewed to date, this product fits the definition for mineral oil mist. The applicable Federal OSHA exposure standard and ACGIH TLV (1985-86) for mineral oil mist is 5 mg/m3. PB~Z$IOLOGICAL & BEALTB EFFECTS EMERGENC~ & FIRST AID ~URES z:yes £xpected to cause no more than minor eye Flush eyes i~ediately with fresh water irritation, for at least 15 minutes while hoid£ng the eyelids open. If irritation persists, see a doctor. · ~.xpected to cause no ~ore than minor skin Wash skin thoroughly with soap and water. irritation .following prolonged or Launder contaminated clothing. frequently repeated contact. Inhalation Not expected to be acutely toxic by If respiratory discomfort or irritation inhalation. Breathing mineral oil mist at occurs, move the person to f:esh air. See concentrations in air that e~ceed the a doctor if discomfort or irritation recommended exposure standard can cause continues· respiratory irritation or discomfort. See Additional Health Data. Ingestion Not expected, to have acute systemic If swallowed, give water or milk to drink toxicity by ingestion, and telephone for medical advice. Consult ~ medical personnel before inducing vomiting. If medical advice canndt be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. Chevron Environmental Heallh Center, Inc.. P.O. Box 4054. Richmond, CA 94804-0054 X-IRCO21 el-BM · Emergency Phone Number {415J 233-3737 No. 86I 1 Rev. 4 10/23/86 AI~.DITIf..~ ~F_J~LTB DATA ENV~AL l:'l~:~ION See'following pages ~vir~~ I~ct: This ~terial is not ~pect~ preset any enviro~ental SP~ ~I~ IN~TI~" probl~s other t~ those associat~ with ~e ~Ot~ti~: ~O Special eye protection oil spills. is necessary. Pr~utions if ~t~l is Rel~s~ c ~ ~o~im: No special skin Spill~: Stop the source of the leak or protection is necessary, release· Clean up releases as s~n as R~{pir~toU ~ot~i~ ~ No special possible. Contain liquid to prevent respiratory protection is normlly further containation of soil, surface r~uir~. However, if operating conditions water or groundwater. Clean up smll cr~t~ air,me conc~trations which spills using appropriate t.chniques such ~ce~ the reco~~ ~Dsur~ standard, as sorbent materials or pumping. Wher~ the us~ of ~ approv~ respirator is feasible and appropriate, r~ove recom~d~, contaminat ~ soil· Follow prescrib~ V~ti~tion: Us~ ad~quat~ v~tilation to proc~ures for r~porting a~ responding to k~ep th~ air,me conc~trations of this larger releases. material below the reco~end~ ~sure Wast~ Dis~Sal S~s: Place containat~ ~tandard. ~terials in dispos~l~ containers ~d dispose of in a ~er consist~t ~ith FI~ B~ION applicable r~gulations. Contact local Fla{h ~t: (COC)392~F(200~C) Hin. enviro[~}ental or health authorities for Autoi~tion ~.: HDA approv~ disposal of this mt~rial. ~t~i~hin~ M~: C02, Dry ~ical, ~IVI~ DATA · Foa,' Wa~r Fog St~ility (~ml, Light, ~tc.): Stable. S~ial Flr~ Fi~ht~ pr~es: For Inc~t~ility (~t~ials to Avoid): ~y fir~s involving this mt~rial, do not react with strong oxidizing ~terials. ~ter ~y ~clos~ or confin~ fire space ~dous D~$sition Pr~uct~: Horml without proper protective equipm~t, co~ustion forms caren dioxide and water including self-contain~ breathing vapor and my pr~uce oxides of sulfur an-' apparatus. Se~ Hazardous DecomDsition phosphorus; incomplete co~ustion ca Pr~ucts. Read the ~tire MSDS. pr~uc~ car~n.~noxide. ~dou~ ~l~iz~tion: Will not occur. SP~ ~~IONS ~ NOT weld, heat or drill container. P~SI~L P~P~IE5 Residue ~y i~ite with ~plosive violence- ~l~ility: Insoluble in water. Miscible Zf heat~ suffici~tly, with h~rocar~n solvents. App~ce (~lor, ~or, etc.): Dark' gre~ ~IONI Do not use pressure to ~pty drum liquid or ~plosion ~y result. ~il~g ~int: n/a Melt~g ~int: n/a 5p~ific Gravity: 0.90 ~ 15.6/15.6oC Va~r Pressure: n/a Va~r D~stty (~r=l): n/a P~c~t Volatile (Vol~e %)1 n/a. Eva~rati~: n/a ~ur ~int: -26oc (~.) Viscosity: 15.1 cst 8 100oC (Min.) n/a = Not Applic~le NDA = No Data Avail~le The above information is based on data of which we are aware and is believed to be correct as of the dale hereof. Since the information contained herein may be aflplied under conditmns beyond our control and w~th which we may be tnfa'~ihar and since data made available subsequenl to the date hereof may suggest modifications of the informat on. we do not assume any responsibibty for the results of its use. lh~s information is furnished upon the condition that the person receh, ing it sf~ll m~,e his own determmalion of the Su~tabihty of the material for his particular purpose. NO. 861 2 Material Safety Data Sheet CHEVRON Urd..versal Gear Lubricant SAE 80W-90 CPS 250102 ADDITIONAL HEALTH DATA Signs and symptoms of respiratory tract irritation ~ay include, but may not be limited to, one or more of the following, depending on concentration and length of exposure: ~asal discharge, sore throat, coughing, bronchitis, pulmonary edema and difficulty in breathing. This product contains base oils which the International Agency for Research on Cancer .. (IARC) lassi~ie$ as having no evidence of carcinogenic potential. This product may contain a 'petroleum base oil refined by a combination of severe hydrocracking and hydrotreatin~. The carcinogenic potential of paraffinic base oils prepared by this process is not specifically addressed by OSHA, NTP, or IARC. However, the process conditions,-chemical analyseS, and the results of Ames tests all suppOrt our opinion that these oils are not carcinogenic. L, Material Safety Data Sheet Prepared According Io the OSHA Hazard Communicalion Standard (29 CFR 1910.1200}. IFormerly Called MATERIAL INFORMATION BULLETIN) AW Hydraulic 0il 68 CPS 234228 TYPICAL COMPOSITION Highly refined base oils (CAS 64742-54-7 or 64742-65-0 and/or 64742-01-4 or 64742-55-8, 72623-87-1 and 72623-85-9) 99% A~ditives including ir~ibitors, demulsifiers, antiwear agent and zinc alkyl dithiophosphate (CAS 68649-42-3) 1% EXPOSURE STANDARD NO Federal OSHA exposure standard or ACGIH TLV has been established for this material. Based upon information reviewed to date, this product fits the definition for mineral oil mist. The applicable Federal OSHA exposure standard and ACGIH TLV (1986-87) for mineral oil mist is 5 mg/m]. PHYSIOLOGICAL & ~R.~LT~ EFFECTS EMERGE~C~ & FIRST AID ~OC~DURES Eyes Expected to cause no more than minor eye Flush eyes immediately with fresh water irritation, for at least 15 minutes while holding the eyelids open. If irritation persists, see a doctor.' Expected to cause no more than minor skin Wash skin thoroughly with soap and water· irritation . following prolonged or- Launder contaminated clothing. frequently repeated contact. See Additional Health Data. Inhalation Not expected to be acutely toxic by If respiratory discomfort or irritation inhalation. Breathing mineral oil mist at occurs, move the person to fresh air. See concentrations in air that exceed the a doctor if discomfort or irritation recon:nended exposure standard can cause continues. respiratory irritation or discomfort. See Additional Health Data. Ingestion Not expected to be acutely toxic ~y If swallowed, give water or milk to drink ingestion, and telephone for medical advice. Consult medical personnel before inducing vomiting. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency .... treatment center or hospital. Chevron Environmental Health Center, Inc.. P.O. Box 4054. R,chmond, CA 94804-0054 X-IRC021 Emergency Phone Number (415) 233-3737 · No. 80 I Rev. 7 01/23/87 expected to present any environmental SPECIAL PROTECTIVE INFORMAT problems ot than those associated with Eye Protection: No special protection oil spills is necessary. Precautions if Material is Released or Skin Protection: No special skin Spilled: Stop the source of th~ leak or protection is necessary, release. Clean up releases as soon as [espiratory Protection: No special possible. Contain liquid to prevent piratory protection is nornhally further contamination of soil, surface required. However, if operating conditions water or groundwater. Clean up small create airborne concentrations which spills using appropriate techniques such exceed the recommended exposure standard, as sorbent materials or pumping. W~ere the use of an approved respirator is feasible and appropriate, remove recommended, contaminated soil. Follow prescribed Ve~tilation: Use adequate ventilation to procedures for reporting and responding to keep the airborne concentrations of this larger releases. material below the recommended exposure Waste Disposal Methods: Place contaminated standard, materials in disposable containers and dispose of in a manner consistent with FIRE PROTECTION applicable regulations. Contact local Flash Point: (COC)428oF(220oC) environmental or health authorities for Autoignition Temp.: NDA approved disposal of this material. Flammability Limits: n/a Extinguishing Media: C02, Dry Chemical, REACTIVITY DATA Foam, Water Fog Stability (Thermal, Light, etc.): Stable Special Fire Fighting Procedures: For Incompatibility (Materials to Avoid): May fires involving this material, do not react with strong oxidizing materials. enter any enclosed or confined fire space Hazardous Decomposition Products: Normal without proper protective equipment, combustion forms carbon dioxide and water including self-contained breathing vapor and may produce oxides of sulfur and apparatus. See Hazardous Decomposition phosphorus; incomplete combustion can Products. Read the entire MSDS. produce carbon monoxide. SPECIAL PRECAUTIONS Hazardous Polymerization: Will not occur. DO NOT weld, heat or drill container. PHYSICAL PROPERTIEs Residue may ignite with explosive violence Solubility: Soluble in hydrocarbon if heated sufficiently, solvents; insoluble in water. Appearance (Color, Odor, etc.): Pale CAUTION! Do not use pressure to empty drum yellow liquid. or explosion may result. Boiling Point: n/a Melting Point: n/a Specific Gravity: 0.88 @ 15.6/15.6oC Vapor Pressure: n/a Vapor Density (Air=l): n/a Percent Volatile (Volume %): n/a Evaporation: n/a Pour Point: -28°C (-18.4OF) Max. Viscosity: 65 cst @ 40°C n/a = Not Applicable NDA = 1Io Data Available above information is based on data of which we are a~.'a-e a~d Is hal,eyed to be co'rest es c! the dm~e hereof. Since the information contained may be applied under conditions beyond our COntrol and w,lh which we real be unta"n,har and Since da~e made avamlable subsequent to date hereof may Suggest modifications of the informal,on we do nO~ aSsu~, an~ 'eS~c~S,b,t,ty ~cr :he resullS of i~S use Th~s information is lurnished, upon lhe cond~Imon lhal the person rece,~,ng ,t shaU r~'e~e r,:s ow~ de:e,,,.,,,.~.:., o~ ll,e 5u,;ab~l~ of ll,e maltr,al for h,s part,cule, purpose. Ho. 80 2 Material Safety Data Sl eet O~rRO~ AW Hydraulic Oil 68 C~S 234228 ADDITIONA~ HEALTH DATA Signs and symptoms of respiratory tract irritation may include, but ~ay not be limited to, one or more of the following, depending on concentration and length of exposure= nasal discharge, sore throat, coughing, bronchitis, pulmonary edema and difficulty in breathing. Several zinc alkyl dithiophosphates (ZDDPs) have been reported to have weak mu/agenic activity in cultured mammalian cells but only at concentrations that were toxic to the test cells. Also, in the past, a ZDDP similar to the one used in this product was reported to cause adverse effects on the testicles of rabbits but not of rats after applications to the skin for several weeks. However, follow-up studies in rabbits indicated that 'the testicular effects were due to a species-specific reaction to stress caused by severe skin irritation and weight loss and not a direct chemical effect of the ZDDP. While toxicologists at Chevron do not believe that there is any mutagenic or testicular risk to workers exposed to ZDDPs as described above, the precautions outlined in this MSD$ should be followed. This product contains base oils which the International 'Agency for Research on Cancer (IARC) classifies as having no evidence of carcinogenic Potential. This product may contain petroleum base oils refined by 'a combination of severe hydrocracking and hydrotreating. The carcinogenic potential of paraffinic base oils prepared by this process is not specifically addressed by OSHA, NTP, or IARC. However, the process conditions, chemical analyses, and /he results of Ames tests all support our opinion that these oils are not carcinogenic. Rev. 7 01/23/87 (Essentially almilar tO I~orm O~HA-20) <~O,,~mplle$ with 2gCFR 19(0.1200~ ~ R~ HYORRULZC FLUID I$0 68 SUPERCEDES COMPONENT8 C.A.~. 'I'LWPEL I PEBGENT NOS.: PPM mg/m~[ WEIGHT/VOLU~ C0~TAI~ IIlIC IaLT 0~ DIAIJ:YL O[TNlOlql0~l~0fllC ~CID, ~ ~T T0 ~ECT T~ ~E~I~ ~ ~ ~1~ I~' ~ T~ ~ ~T. HAZARDOUS THERMAL DECOMPOSITION FLAMMABLE LEL -- UEL ~ ~i~ ~ ~1~5 LIMITS: FLASH POINT: EXTINGMISHING >22S o C FO~, M~ DOT INFORMATION: 0lb ~.0.~. UNUSUAL FIRE AND EXPLOSION HAZARDS: ~]~[[Y ~]~ ~ .~AI~ ~E rL~ SPECIA1 FIRE FIGHTING PROCEDURES'. ~ M~ ~IEE ~Y E~ ~ C~I~ ~ ~l~r ~ ~IECH~ ~[~r ~ ~ ~T~]~ ~ffiE (0,0~ ttI APPEARANCE AND ODOR: RI1BEIb OiLY LIQUID VAPOR pnE.qsun~ 20 aC PEI'ReLEUII 0D~R DENSITY [ ;VADAnATIn~ RaTe SPECIFIC T WEIGHT 1% VOLATI[ '~]~ THANAIR / ~ THANETHER '.' / 7.'0__' INCOMPATIBILITY ~ATERIAE5 TO AVOIDS: S~ ~IDIZI~ STAalLITY'. CONDITIONS TO AVOID: HATAnDOU~POLYeEfllZATIOH --~f~HRL EXPOSURE MATERIAL SAFE'IY i)A'!A SIIEETe CALIFORNIA SODA COMPANY, 355 CYPRESS STREET OAKLAND, CALIFORNIA 9q607 OFFICE (ZI]s) qqq-621? FAX (qlS) qqq-13q3 ProDuct NaMe: CH~I.IlcaL FAMILY: ForMuLa: dO 303 MIneraL ^c~D (cLeaNEr) ProPrIetarY SectIoN ! - llaza~pousjJ~7~~ cAS NuMaer: fiateriaL PerceNt: Re,arKs: 766~-39-3 HYDroGen FLuorIDe j0- 20Z See SectIoN IX 766q-93-9 SULFURIC ACID 10- 20~ SEE SECTION IX SECTION [NI'IAL,IioILIHG I)o~N'r: 68OF FLASII POINT: Not ESTABLISHED SPECIFIC GRAVITY: 2.6 (HF) SOLUBILITY IN WATER:COMPLETE APPEARANCE: CLEAR LiQuiD ODOR:SHARP ACRID ODOR. SECTION .111 - ~!RE ^ND ~×P~QSIQN !NFORMAr~ON EXTINGUISIIING ~EDIA: USE FIRE FIGHTING MEDIA PROPER TO PR[MARY SOURCE OF FIRE. SPECIAL FIRE FIGHTING PROCEDURES: PROTECTIVE EQUIPMENT SHOULD BE USED ~N ALL FIRES INVOLVING FIRES. SECTION I¥ -IIEALTII EFFECTS INFORMATION EFFECTS OF OVER EXPOSURE: SKIN: CAN [MMEDIATELY CAUSE SEVERE PAINFUL BURNS. EYES: CAN IMMEDIATELY CAUSE SEVERE'PAINFUL BURNS. INHALATION: CAN.SEVERELY BURN RESPIRATORY TRACT. INGESTION: CAN SEVERELY BURN TISSUES AND / OR'CAN BE FATAL. ###~~~~~#~~~~~~~~~~#~#~##~~~~~~~~~#~~~~#~####~~~#~~~~~~#~#~~~~####~##~~~######### PRODUCT,NAME: JO ~0~ PAGE 0] OF O~ SECTION IV- CONTINUED EHERGENCY AND FIRST AiD PROCEDURES= SKIN: ]HHEDIATELY WASH CONTAHINATED AREAS FOR AT LEAST ]5 M~NUTES WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND FOOTWEAR-WASH BEFORE REUSE. EYES~ WHILE HOLDING EYELIDS OPEN FLUSH WITH WATER FOR AT LEAST ]5 MINUTES WITHIN SEVERAL SECONDS FOR MAXIMUM'EFFECTIVENESS. iNHALATION= REMOVE To FRESll AIR, IF BREATHING STOPS, GIVE MOUTtI-To-MOUTH RESCITATI(]N ]NGESTATION: NEVER GIVE.ANYTHING TO AN UNCONSCIOUS PERSON. NOT" iNDUCE VOMITING IF AVAILABLE GIVE SEVERAL GLASSES OF MILK. JEEP AIRWAY CLEAR. SECTION V- REACTIVITY INFORMATION STABILITY: STABLE; XX UNSTABLE~ CONDITIONS To AVOID: INCOMPATIBILTY:GLASS, CONCRETE, CERTAIN METALS, NATURAL RUBBER, LEATHER, AND MANY ,ORGANIC CHEMICALS. HAZARDOUS DECOMPOSITION PRODUCTS: HYDROFLUORIC ACID GAS. ~.A.Y PRODUCE FUMES TO DECOMPOSITION WHEN HEATED. POMES MAY CONTAIN HIGHLY ToxIc HYDROFLUORIC AND/OR FLORIDE FuMEs. SECTION VI -SPILL AND DISPOSAL INFORMATION '' STEPS To BE TAKEN IN CASE OF MATERIAL RELEASED ()R SPILLED: GOOD VENTILATION IS A' NECESSITY. SOME 0F THE LIQUID DISCHARGED WILL VAPORIZE QUICKLY AND SPREAD RAPIDLY. BOTH LIQUID AND VAPOR ARE EXTREMELY DANGEROUS. PROTECTIVE EQUIPMENT MUST BE AVAILABLE FOR USE IN REPAIRING LEAKS. FLUSH WITH PLENTY OF WATER..' WASTE DI~P()~A~.: NEUTRALIZE RESIDUE WITH LIME OR LIMESTONE TO DE-SOLUBLIZE FLORIDE. DISPOSE OF IN CONFORMANCE WITH ALL LOCAL, STATE, AND FEDERAL REGULATIONS. ii#Mi###fiG############# Mill) fl##fl#fl#MM##### # #Mil##tiff### ###fl Mil##ii# fiMfl#Mfl##Mifl#######t .~ , SE(:FII)N VI J - PERSONAL PRO'iE£1 ION INFORMATION VENTILATION 'J'YPE: IN PROCESSES WHERE TVL CAN BE EXCEEDED OR M~STS AND/OR VAPORS MAY BE GENERATED PROPER VENTILATION I'S A MUST.. MUST BE SUFFICIENT To REDUCE ACID P LE LEVELS. A NIOSH/.MSHA JOINTLY APPROVED RESPIRATOR Is ADVICED IN ABSENCE 0F PROPER CONTRoLs. PROTECTIVE GI_OVES ~ RUBBER OR NEOPRENE, WHEN NEEDED TO PREVENT CONTACT. EYE PROTECTION: WEAR CHEMICAL SPLASH GOGGLES WHERE THERE IS A POTENTIAL FOR EYE CONTACT. SAFETY GLASSES WITH SIDE SHIELDS UNDER NORMAL CONDITIONS. OTHER PR(HECI'IVE EQUIPMENT.' EYE WASH, SHOWER, PROTECTIVE CLOTHING WHEN NEEDED. WASH HANDS BEFORE SMOLKING, EATING, OR USING BATHROOM. iii#i#### ##fl ### # ~ ## ##ti# PRODUCT NAME: JO ]~0]~ PAGE 02 OF 0]5 I'I/AILItI/IL. ,I,'~rCll tllilll ,.3111'1: SECTION VIII- STORAGE AND IIANDLING KEEP CLOSURE TIGIIT AND CONTAINER UPRIGItT To PREVENT LEAKAGE. KEEP CONTAINER PLAINLY LABELED. ALWAYS ADD ACID TO WATER TO LESSEN TEMPERATURE RISE DANGER. UNNEUTRALiZED ACID MUST NOT CONTACT SuLFITE WASTES (AS IN SEWERS) VENT DRUMS WEEKLY, OR MORE FREQUENTLY IN Hot:WEATHER. Do NOT STORE NEAR ORGANIC MATERIAL OR REACTIVE CHEMICALS SUCH As NITRITES,CARBINES,CHLORATES, OR METALLIC POWDERS. SECTION IX- REGULATORY INFORMATION THIS PRODUCT CONI'AINS hie FOLLONIN6 TOXIC:CtlEHICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SARA TITLE !!I SECTIOH ~J] OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-To-KNo~ ACT OF ]§8~ AND OF qO CFR CAS NUMBER CtlEMICAL NAME PERCENT ~Y ~EIGHT 766q-39-3 HYDROGEN FLUOR I DE (ttYDROFL~IC ACID) 10 - 20% 766q-93-9 SULFURIC ACID 10- 20% SECI'ION X- TRANSPORATION INFORMATION ~OT PROPER StlIPPIHG NAME;~YDROFLUORIC ANBI,SULFURIC ACID MIXTURE -. ~OT IIAZARDOUS CLASS:CORROSiVE MATERIAL ~OT LABEL: ,CORROSIVE HAZARDOUS INGREDIENTS: (CONTAINS HYDROFLUORIC AND SULFURIC ACID MIXTURE) UN/NA NUMBER: UN ]786 ~OT EMERGENCY I{ESPONSE GIIIDE NUMBER: 59 USER'S RESPONSlB~ITY-Tills llUEI. ETIN CANNOT COVER ALL POSSIBi. E SITUATIONS ~HICH T~E USER MAY ~X~ERIENCE DURING PROCESSING. £ACii ASPECT OF YoUR 0PER~TION ~NOULD BE EXAMINED To I)ETERMINE IF, OR ~IIERE, ADDITIONAL PRECAUTIONS HAY RE NECESSARY. ALL IIEALTII SAFETY INFORMAl'ION CONTAINED IN 'Jills flUI_I. ETIN SIIOULD fie PROVIDED To YOUR EMPLOYEES OR CUSTOMERS. IT Is YOUR IIESPONSIBILTY To USE ,Tills INFORMATION TO OEVELOP APPROPIATE ~ORK PRACTICES GUIDELINES AND £MPL.OYEE INSTRUCTIONAL PROGRAM FOR YOUR OPERATION. :' DISCLAIMER OF LIABILITY- 'As TIlE CONDI'I'IONS OR METIIOI)S OF IIsE ARE ~EYOND OUR / CONTROL, NE I)0 NOT ASSUME ANY IIESPONSIBILITY AND EXPRESSLY I)ISCLAIM ANY LIABILITY ~' FOR ANY USE OF TI.liS HATERIAL. INFORMATION CONTAINED IIEREIN Is ~ELIEVEO TO BE TRUE AND ACCURATE RUT ALI. STATEMENTS OR SUGGESTIONS ARE HADE ~ITHOUT ~ARRANTY~ EXPRESS OR IMPLIED, REGARDING ACCURACY OF Tile INFORMATION, Tile IIAZARDS CONNECTED ~ITII TIlE USE OF TIlE MAI'EfllAL OR THE RESULTS To HE OBTAINED FROM TilE.USE THEREOF. COMPLAINCE Nil'Il Al.l_ APPLICABLE FEDERAL, STATE, AND LO£AI. LAWS AND REGULATIONS REMAINS Tile ~ESPONSIIIII.ITY OF Tile USER. THIS. INFOHMA'rION MUST liE INCLUDED IN ALI. MA'TERIAI. SAFE'I'Y [)ATA SIIEETS TItAT ARE COPIED, AND ~ISl'RIIIII'I'EI) FOR Tills MATERIAL. PRODUCT NAME: JO 303 PAGE O~ OF 03 REVISED: MARCH 03, 1991 BY: CARLA HORN HSD HAZARDOUS WASTE REPORTING - STATE CONTACTS Arizona Arizona Dept. of Environmental Quality Waste Assessment Section/IPU 3003 North Central Avenue Phoenix, AZ 85012 Questions: Kathy Feliberty (602) 207-4214 California U.S. EPA Region IX (H-3-4/BRS) 75 Hawthorne Street San Francisco, CA 94105-3901 - Questions: John R. Moody (415) 744-2054 Nevada Nevada Div. of Environmental Protection 333 West Nye Lane, Capitol Complex Carson City, NV 89710 Helpline Inside Nevada (800) 882-3233 Helpline Outside Nevada (702) 784-1717 New Mexico New Mexico-Environment Dept. Hazardous and Radioactive Materials Bureau P.O. Box 26110 Santa Fe, NM 87502-6110 Questions: Anna Walker (505) 827-4308 SCS/1-35C./076 HAZARDOUS MATERIALS BUSINESS PLAN FORM A PLEASE READ THE INSTRUCTIONS PRIOR TO COMPLETING AND RETURNING THIS FORM. TO AVOID PENALTY, RETURN THIS FORM WITHIN 30 DAYS FROM DATE OF RECEIPT. SECTION I: BUSINESS IDENTIFICATION DAT~ 1. Full Name of Business or Facility: 5 MINUTE CARWASH 2. Business Address: 920 34TH STREET, BAKE. RSFIELD CA. 93301 street city state zip code 3. Mailing Address:P.O. BOX 577200 MODESTO, CA. 95357-7200 street city state zip code 4. Business Phone: (805) 323-9071 5. Owner's Name: CHARLES FENLEY ENTERPRISES Phone #( 209 ) 576-0381 1121 OAKDALE ROAD SUITE 8'MODESTO,CA. 95355 · ' street city state zip code 6. Operator's Name:~ PHIL GARNER Phone # 605 ) 393-0963 920 34TH STREET, BAKERSFIELD, CA. 93301 street, city state zip code 7. Principal Business Activity: CARWASH / RETAIL GASOLINE 8. Standard Industrial Classification Code: 7542 9. Number of Employees: 25 9A. per shift': 25 9B. shift hours: 8'30 AMI TO 15'00 PM 10. *Emergency Coordinator: LEE GARNER VICE PRESIDENT name - title Business Phone:577-1850 Home Phone:521-8581 24 Hr. Phone: 577-1850 11. *Alternate Emergency Coordinator: MIKE FENLEY PRESIDENT name title Business Phone:577-~850 Home Phone:529-2202 24 Hr. Phone: 577-~850 · The emergency and alternate emergency coordinators represent the business and assist emergency personnel in the event of an emergency involving the business during and after business hours. JURIS 215-004 12. Fire Dtstrict:BKFD STA # 04 13. Dun's Number:04-862-5399 ~2/16/94 5 MINUTE CAR WASH 215-000-000301 Page 9 00 - Overall Site <D> Notif./Evacuation/Medical i1> Agency Notification CALL 911 > Employee NOtif./Evacuation VERBALL AND CALL 911. EMPLOYEES WILL BE TOLD TO EVACUATE TO MEDI ALERT BUILDING ADJACENT TO CAR WASH. 3> Public Notif./Evacuation RESPONSIBILITY FOR NOTIFICATION OF PUBLIC AGENCIES INCLUDES BAKERSFIELD HEALTH, POLICE, FIRE DEPT. ' EVACUATION FROM THE PREMISES WILL BE BY VOICE COMMAND AND ALL PEOPLE/EMPLOYEES WILL BE TOLD TO MEET IN THE MEDI ALERT PARKING LOT ADJACENT TO 5-MINUTE CAR WASH > Emergency Medical Plan MINOR INJURIES - MEDI CENTER 820 34TH ST (805) 325-6334 MAJOR INJURIES - GOLDEN EMPIRE AMBULANCE 801 18TH ST (805) 327-9000 02/16/94 5 MINUTE CAR WASH 215-000-000301 Page 00 - Overall Site <E> Mltigation/PreVent/Abatemt <1> Release Prevention STANDARD GAS STATION SAFETY EQUIPMENT. ON PUMPS; SHUT OFF, VAPOR SHIELD, ETC. ALL OTHER MATERIALS STORED IN SAFETY SEALED CONTAINERS. <2> Release containment TO CONTAIN WITH SAND AND OR KITTY LITTER <3> Clean Up DEPENDING ON SIZE OF SPILL, EITHER AIR OUT OR SHIP TO HAZARDOUS DUMP SITE. <4> Other Resource Activation BAKERSFIELD CITY FIRE DEPARTMENT 2130 "G" STREET BAKERSFIELD, CA 93301 (805) 326-3979 l OFFICIAL USE ONLY ID# USINESS NAME HAZARDOUS lVb%T E R I ALS BUSINESS PLAN AS A WHOLE FORM 2A INSTRUCTIONS: 1. To avoid further action, return this form by 2. TYPE/PRINT ANSWERS IN ENGLISH. ', 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. SECTION 1: BUSINESS IDENTIFICATION DATA A. BUSINESS NAME: 5-MinUte Car Wash B. LOCATION / STREET ADDRESS~ 920 34th Street CITY: Bakersfield ziP: 93301 BUS.PHONE: (805) 323-9071 SECTION 2: EMERGENCY NOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7550 or 1-916-427-4341. This will notify your local fire department and the State Office of Emergency Services as required by law. EMPLOYEES TO NOTIFY IN CASE OF EMERGENCY: NAME AND TITLE ' DURING BUS. HRS. AFTER BUS. HRS. A. Phil Garner Ph# (805) 32.3-9071 Ph# (805) 393-0963 B. Steve French Ph# (805) 323-907T. Ph~ (805) 392-1932 12:. Michael FenleY (209) 577-i850 (209) 529-2202 SECTION 3: LOCATION OF UTILI/"I SHIrr-OFFS FOR BUSINESS AS A WI~OLE A. NAT. GAS/PROPANE: Ext. north wall behind mechani'cal room B. 'ELECTRICAL: PG&E Transformer box, west. side on '0' st. adj. to sidewalk. C. WATER: Meter box~ west side on '0' st. adj. to sidewalk. ~D. SPECIAL: ~E. LOCK BOX: YES / NO IF YES, LOCATION: IF YES, nilES IT CONTAIN SITE PLANS? YES / NO MSDSS? YES / NO FLOOR PLANS? YES / NO KEYS? YES / NO MEMORANDUM August 26, 1986 To: Al! Managers, Asst. Managers Chuck, Mike and Lee From' Jim Mc Kay Subject. Fue! Response P!an Beginning September l, 1986 we will implement our Fue! Response Plan. What this means to you is that any and all variances of product in excess of the amount specified by law are to be investigated (Response Plan) and documented (Evaluation Report). No exceptions. Attached is our response plan and evaluation report with an.~ example. I wil! be spending some time with each of you to explain the plan and report. Questions, problems, suggestions? Please feel free to discuss them with me, [U[L_V6R~A~[..~ES~PNSE. Pk~N State and local (county) laws 'require all' underground tank owners to develop a Response Plan that would list detailed steps to follow should our daily fuel reconciliation ever indicate a loss of product in excess specified by law. The Response Plan must also provide documentation of these steps which would indicate the date and time these steps were completed and by who. Attached is the evaluation report which was developed for this purpose. If inventory reconciliation indicates a 'loss of product greater than that specified then the operator must implement the following. If the inventory reconciliation indicates a gain in product greater than that specified, then the operator shall implement steps 1, 2, 3, and 5. The steps can can be implemented sequentially or concurrently. However, they must be completed within the specified time period. If completion of steps 2, 3, or 5 indicates inventory reconciliation error that, when corrected cause the levels of variance not to exceed the level specified by law, then the remainder of the steps need not be completed. If completion of the steps described in step 4 or 6 through 8 reveal the source of the loss, then the remainder of the steps need not be completed. ~' The transfer of product into and out of the underground storage tank may continue during implementation of the steps provided that the steps are completed within the specif~d periods and any loss or gain did not exceed two times the specifie~d levels. Daily reconciliation shal! continue during impIementaion of the steps. (1) The operator shall notify the owner verbally of the fact that inventory reconciliation indicates a loss of product or gain of.water within 24 hours of the completion of the daily reconciliation which indicates the loss or gain. (2) The operator Sha]! review the inventory records within 2 hours to determine if an error exists which would cause the gain or loss to be !ess than that specified. (3) The operator shal! have performed, by a qualified person, a complete review of ail inventory records from the last time~a~zero loss or gain condition existed. This shall include a new inventory reconciliation which was taken at least 8 hours after the inventory reconciliation that triggered this evaluation. This reconciliation shall be complete within 24 hours of-'~the~'-¢on¢lu$ion of step 2. (4) The readily accessible physical facilities shall be carefully inspected for leakage. This shall be completed by trained personnel within 24 hours of completion of step 3. (5) All dispenser meters associated with the product shall be checked for calibration within 24 hours of completion of step 4. (6) All piping shall be tested within 24 hours of completion of step 5. The piping shall be isolated and hydrostat- ically pressure tested at 50 psi or greater. If the pressure drops more than 5 psi per minute, it indicates the probability of a leak in the !ine. Repeat the test at least once to ensure against compression of entrained air. Any pressure drop !ess than 5 psi is inconclusive as it may be caused by cooling. This step may be complet- ed after step 7 if excavation is necessary to perform the tests and if step 7 is completed within 48 hours of the completion of step 5. If this occurs, then this step shall be completed within 24 hours of step 7. (7) The underground storage tank shall be tested using an approved method within 48 hours of completion of step 6. (8) Additional tests or investigations ar required by the local agency. F~UEL VARIANCE EVALUATION REPORT Date of Occurrence-~ ............ Time' Facility: ....... r-- Operator:.· ........................... Address: ............ Phone' ..... . ....... Owner' Charles Fenley Enterprises Tank Description: · Tank No ........... State Tank. No.r ......................... Reconciliation Variance Calculation Beginning Balance: Ending Inv (Calc)' Deliveries' ......... ~ ........ Ending Inv. (stick)L .............. Transfers in: Variance: Tota! for Sale- _ ..... Allowable Variance:* Transfers Out: ........... _. Over/Under Variance' Adjustments (+-): .................. Sales: Water 'Leve! Increase' Ending Inv: *(lO0-12,000 gal, 75-10 000 gal) Owner Notified: ................. ~ ....Reconciliation Reviewed'_ ............ . New Stick Reading- By: Complete Reconciliation'_ ......................... ~-,, By:r ........................ · Premises Inspected: By: Pumps Ca ! Pipes Tested: ........ By: _._ Tanks Tested' By: Other Tests._ ....................... By Test Results' Final Evaluation- RELEASE (leak) EVALUATION PROCESS ACTION CHART . I V°lume GainI J Volume LossI 2 [burs 2 Hours >I Review Records Reconciliation /' 8 Bouts 8 Bouts ' . Reconciliation Notify Tank Ovner .. Notify Tank O~ner · .. Within Within ' i Qualified Person to[ 26Bouts 241tourS~Qualified Person to Reviev Record [< Reviev Record from last 0 Balance[ from last 0 Balance 2Days ' Facility for Evidence of Leak Check Calibration L ~ithin Nithin Check Calibration on Dispenser Heters[' 3Eay~ 3Bay~ on Dispenser Heters Within t Hydr°static Pressure [ 4 Days Test on Piping · if Possible *Steps may be implemented in sequence JPerform or at the same time, hoverer they must ' Tank Test be completed within the time frame Within specified. 51lays .Additional ~ Investigation if / Required SITE/FACILITY DIAGR~M FORM S NORTH SCALE: none BUSINESS N~%IE: 5-Minute Car Wash FLOOR: OF DATE:06/23/ 87FACILITY N~E: Same UNIT ~: OF (CHECK ONE) SITE DIAGRAM XXXX FACILI/"f DIAGR~u~ ~.¥ · I/ , ~ , I/ I , I I~1~1.~ I ~ //~~ I~l I.~1~1 ~l~'~ Inspector's Comments): -OFFICIAL USE ONLY- SI TE/FACI LI ~'Y DI AGRA FORM § NORTH SCALE': none BUSINESS NA%IE: 5-Minute Car Wash FLOOR: OF DATED6~23~87 FACILITY N~ME: Same UNIT .~: OF (CHECK ONE) SITE D[AGRk~4 FACILITY DIAGR~ XXXXXXX -- ~/. , , ,, /__ -- ~. Inspector's Comments): -OFFICIAL USE ONLY- ,I BUSINESS NAME 5 MINUTE CAR WAStt ID NUMBER 215-000-000301 LOCATION 920 34TH ST t{IGH HAZARD RATING 3 D . E~IPLO~rEE NOTIFICATION / EVACUATION LAST CttANGE 10/09/87 BY ESTER 3A SEC 2) VERBALL AND CALL 911 MITIGATION / PRE¥"ENT I ON / ABATEMENT LAST CHANGE 11/16/87 BY ESTER 3A SEC 1) STANDARD GAS STATION SAFETY EQUIPMENT. ON PUMPS; SHUT OFF, VAPOR SHIELD, ETC. ALL OTHER MATERIALS STORED IN SAFETY SEALED CONTAINERS. W__HE,.. F_N,V._!_R_Q_NM~._NTAL..~>- 1121 Oa.k. dale Rd. Ste. #6 Modesto Ca. 95355 4 12/16/88 12' HATERIAL SAFETY DATA SYSTENS, INC. (805) 648-6800 HAZARDOUS ~IALS INVENTORY ~ Farm and Agriculture ~Standard Business Page 1 of NON - TRADE SECRET BUSINESS N]~E:5 Minute Car Wash OWNER NAME: Char]P_~ FPnl~v Fnt_ NAME OF THIS FACILITY: R~kpr~fjpld _ LOCATION: 920 34~h Street ~D~SS: 1~2~ 0akdale Roa~ ~8 ST~D~ IND. CLASS CODE: 7~42 CITY, ZIP: uaKers~]ela, UA 933u1 CITY, Z~P: Modesto, CA 95355 DUN ~D B~ST~ET NUMBER/FEDE~ ID PHONE ~: (RO5) 2P2-q~7~ PHONE i: (enq) 577-~850 % ~ - 1 6 5 - 8 6 5 2 ~R ~ INS~U~IONS FOR PROPER ~DES 1 2 3 4 5 6 7 8 9 l0 1l 12 13 14 Trane ~e ~x Average ~nual Measure { Days Cont Cont Cont Uss Location Where % by N~s of Mlxture/Com~nents Code C~e ~t ~t ~t Units os Site ~ Press Temp Code Stored in Facility ~ See Instructions U { M {J2,00q 6,000~{00,000{ Gal { 365 {0{ { ~ { 6 {J9 m s/E corner Tank ~{ Ch~vrnn S,{nr~m~ Physical and H~lth Hazard C.A.S. Nu~er Component { i N~ & C.A.S. Nu~er 25 Toluene (Check all ~hat apply) ~08883 of Pressure H~lth H~lth Component { 3 Na~ & C.A.S. Nu~er 1634044 10 MTBE II { ~ {!~.00~ 6.000 ~70.000 {Gal' { 365 mo~ { ~ } 6 {lq{ S/E co~ne~ Tank ~2 Chevron Plus Unleaded e,,yo~ ,.u .~]=.....ru c.~.s..u~.r co.po...= ~ ~ ..., c.~.s. ,u~.r 25 To 1 uene' (Check all that apply) ~ Fire Hazard U] Sudden Releaae ~ Beac:tvlty ~ I~.dl,:e ~Dolay~ Componen~, ='..--, c.~.s. ,u~.~ 20 Xylene of Pressure Health H~lth Component , ~ N,~, C.~.S2 N.~.~ q 0 MTB E II I M lip nnnl 6.000 170' 0001 Gal I ~ I 16 1 91 S/F o~rn~r Tank ~ Ch~vrnn Ilnl~admd Physical and B~lth Hazard C.A.S. Nu~er Component 8 1 Na~ & C.A.S. Nu~er (Chack all tha~ apply) 25 Toluene Componen: ~ 2 Na~ & C.A.S. Nu~er ~ Fire Hazed ~ Sudden Release '~ R,cttvlty ~ I~edtate ~ Delayed 20 Xy 1 ene of Pressure Health Mealth Component ~ 3 Na~ & C.A.S. Nu~er ' 1~ MTRF u I IzSo I I .nnnl ]~ I ~R~ In7 I 1 ~ ~ Ila l N/~ co~ne~ ~enced a~ea C~] Sod~ ~. ,'10303 10 Physical and a~lth Hazard C.A.S. Nu~er Component , z ,~.~ c.~.s..~.~ 20 HydroQen Fluoride ,ch.=~.n~.pp,~, co=po~.9~~t c.~.s..~.= ~8 Sulfuric' Acid ~ Fire Haz=d ~ Sudden Release ~ Reactivity E~RGENCY CONTACTS. ~lPhi] Garner Manage~ (805) 393-~6A Na~ Title 24 ~. Phone N~e ' Tt~e~c - - ' ' --' ~24 Br ~hone Alarm Enmnsnv (RRB3 2erttftcation (~'~ ~D' SIGN AFTER COMPLETING ~L SECTIONS) [ certify ~der p~nlty of law that I hayer ~raonally ~tn~ and ~ f~11t~ with the tnfo~atton submitted tn ~hts ~d all attached d~enta and tha~ ~sed on ~ tn~t~ o[ thom individuals res~nslble for obtaining the tnfo~tton. I believe tha~ ~e au~tt~ed tnfo~atto~ Is ~e, acc~a~e, and c~ple~e. gAME AND OFFICI;tt TI~Iq,E OF O~R/OPERAqYIR OR Article 5. Re[ease Reporting Requirements Adopt new section: to read: 2050 Applicability (a) All unauthorized releases from the primary or secondary container shall be reported according to the requirements of the appropriate sections of Chapter 6.7 of Division 20 of the Health and Safety Code and this article. (b) Certain unauthorized releases to secondary containers, as described in Section 25294 of the Health and Safety Code, shall be recorded on the operator's monitoring reports according to Section 2651 of this article. No other report shall be required if the leak detection monitoring system in the space between the primary and secondary containers can be reactivated wlthin 8 hours. This provision shall be applicable only to new underground storage tank§ as defined in Article 2 of this subchapter. (c) All other unauthorized releases shall be reported within 24 hours after the release has been, or should have been, detected according to Section 2652 of this article. Adopt new section to read: 2651 Unauthorized Releases Requiring Recording (a) The report requlred by Subsection 2650 (b) of this article shall include: (1) List of type, quantities, and concentration of hazardous substances released. (2) Method of cleanup. · (3) Method and location of disposal of the released hazardous substances (indicate whether a haz- ardous waste manifest[s] ls utilized). (4) Method of future leak prevention or repair. If this involves a change as defined in Article 10, Section 2712, Subsection (a), of this subchapter, then appropriate reports pursuant to that article shall also be filed. (5) If the primary container is to continue to be used, then a description of how the monitoring system between the primary and secondary container has been reactivated. (6) Facility operator's name and telephone number. (7) The approximate costs for cleanup to be submitted voluntarily. (b) The local agency shall review the information submitted pursuant to Subsection (a) of this section and shall review the permit and may lnspect the underground storage tank pursuant to the provisions of Article lO, Section 2712, Subsections (g) and (h), of this subchapter. The local agency shall find that the containment and monitoring standards Of Article 3 of this subchapter can continue to be achieved or the local agency shalI revoke the permit until appropriate modifications are made to allow compliance with the standards. (c) Deterioration of the secondary container is likely when any of the following conditions exist: (1) The secondary container Will have some loss of integrity due to ~ontact with the stored haz- ardous substances~ ' (2) The mechanical means used to cleanup the released hazardous substance could damage the secondary container; or (3) Hazardous substances, other than those stored in the primary container, are added to the second- ary container for treatment or neutralization of the released hazardous substance as part of the cleanup process. ~d) If a recordable unauthorized release becomes a reportable unauthorized release due to initially un- anticipated facts, the release shall immediately be treated as a reportable release pursuant to Section 2632 of this article. Authority: H&SC 25299.3 Reference: H&SC 25294 Article 5. Release Reporting Requirements Adopt new section as follows: 2652. Unauthorized Releases Requiring Reporting (a) All other unauthorized releases shall be reported as specified in this section. (b) Within 24 hours after the release has been detected, or should have been detected, using required monitoring, the operator shall notify the local'agency and the State Office of Emergency Services or the regional board.~ (c) Within 5 working days of detecting the release, the operator or permittee shall submit to the local agency a full written report to include all of'the following information which is known at the time of filing the report: (1) List of type, quantity, and concentration of hazardous substances released. (2) The results of all investigations completed at that time to determine the extent of soil or ground water or surface water contamination due to the release. (3) Method of cleanup implemented to date, proposed cleanup actions, and approximate cost of actions taken to date. (4) Method and location of disposal of the released hazardous substance and any contaminated soils or ground water or surface water (indicate whether a hazardous waste manifest[s] is utilized). (5) Proposed method of repair or replacement of the primary and secondary containers. If this involves a change as defined in Subsection 2712(a) of Article 10 of this subchapter, then appropriate reports pursuant to that article shall also be filed. (6) Facility operator's name and telephone number. (d) Until cleanup is complete, the operator or permittee shall submit reports to the local agency and the regional board every 3 months or at a more frequent interval specified by a responsible agency. The reports shall include the information requested in Subsections (c)(2), (c)(3),'and (c)(4) of this section. (e) The reporting requirements of this section are in addition to any reporting requirements specified by Sectlon 13271 of Division 7 of the Water Code and other laws and regulations. Authority: H&SC 25288.2 Reference: H&SC 25284.4 ~ COUNTY OF KERN AIR POLLUTION CONTROL DISTRICT AB2588 AIR TOXICS INVENTORY PLAN Application Form F-1 Facility ID # 10134 Facility Name: 5-MINUTI~ CAR WASH Facility SIC # (if available): Number of Employees (approximately): 30 Street Address: 920 34th Str~t City/State/Zip: 8aker~;field, CA. 93301 JI Contact pers°n (C°mpany Official): M~k~ Fe01~¥ , .Telephone Number: (209) 577-1855, ,t, ~ Signature of Company Official~ ..///~_~'/~.~.J4/~ ~. Plan Preparer: d~m Mc Kay Telephone Number: (209) 576-0381 Signature of Plan Preparer: If you want your mailing' address/and company name different from the one used above, please print new mailing address/name below in the spaces provided. Facility Name: Charles Fenley EntErprises ,. Mailing Address: P.0. Box 577200 City/State/Zip Code: Modest0, CA. 95357-7200 FUEL FACILITY FORM FORM F-1 NAME OF FACILITY 5-MINUTE CAR WASH LOCATION 920 34th Stro. ot Bakersfield. CA. 93301 TANK · Typ~ of TANK TANK PRODUCT TANK NUMBER DISPENSER PERMIT TO PRODUCt ABO~NDER CAPACITY THROUGHPUT VAPOR DISPENSERS VAPOR OPERATE GROUND (GAL) ( GAL/YR ) CONWROL (PER TANK) CONTROL (IF AVAIls) A/U .' (Yin) (Y/N) SUPREME I UNLEADED UNDERGROUND 12,000 154 000 Y 6 8204001 (U) ' y .REGULAR UNLEADED UND~uR~ROUND"~ 12,000 139,8z17 y 3 y 8204003 REGULAR 3 LEADED UNDERGROUND 12,000 2,992 y 3 (U) y 8204005 4 See Example in the back of Form F-1 [Duplicate As Needed] THIS FORM MUST BE FILLED OUT BY ALL FUEL HANDLERS PARER , DATE .. Flow Diagram for Facility The District has provided you with three typical flow diagrams. Review each diagram and choose the one that best describes your facility. Examples of '"Best Fit" Facilities are given below: CHECK THE BOX THAT MOST CLOSELY DESCRIBES YOUR FACILITY AND USE THAT FLOW DIAGRAM. PLEASE FILL OUT AND SIGN THE DIAGRAM THAT YOU CHOOSE. Fuel Dispensinq only (Fuel Pumps, but no Service Bays, i.e. convenience store with gas pumps). Use Figure i Flow Diagram. Gasoline Service Station (Fuel Dispensing & Service Bays) Use Figure 2 Flow Diagram. Automotive Service FaCility (No Dispensing of Fuel). Use Figure 3 Flow Diagram. Facilities may send a copy of their blue print if none of' the Flow Diagrams in this package are good representations. The flow diagram must include all devices within a facility, either permitted or not permitted, that serve as a possible source of toxic emissions. Include in the diagram all stacks, vents, exhaust sites, incinerators, etc. ' FUEL DISPI?,NSING FLOW DIAGRAM Complete thi,~ Diagram ff your Facility serves as a Fueling Station only. Jif your Facility has a service baY, go on to the next flow diagram example. Vehicle Vapors [~_ProdUct _~~ Gasoline Vapor~ 1 2 Gasoline Vapors Vapor Lin oduct Line Ti)Iai · of Tanks 3 ~ Gasoline Vapors Vapors~ Prod~act Tanker ~ Is an Incinerator Present? ~Yes g~ { Indn~to~ ~r~ fomd Si e *f Preparer Date Only ou l~t & I~_~h Sy~m ) Fill in the number of Tanks &. Pumps at your Facility in the designated boxes 13~ you wish to calc_u!ate your own Facilities cmte~ions? ff yes, go on to thc calculations in Apl~ndix Z If no, go on to the oover page of the Form ,?~DL & DEG to se~ if theae forms apply to your Facility. [] Yes ~ No FORM F-1 FIELD- PROGRAMMABLE SET-UP PARAMETERS MATCH TLS-250 TO YOUR STATION REQUIREMENTS TLS-250 can be field-profiled to match station operat- SPECIFICATIONS lng and layout requirements. Tank setup pararneters Performance specifications listed below represent values include product label, tank capacities at ~,~, ~, 3/,~ and that could be expected from a TLS-250 system if a per- full levels, diameter, tilt and manifolding information. In fectly cylindrical, calibrated (10' diameter, 10,000 gal- addition, limits for high water, overfill, Iow inventory andIon) tank was used. theft can be entered for each tank. System setup parameters let you set three auto- Height of fuel -+ 0.1" matic inventory printout times, set start and stop times for automatic leak detect, and establish an external Volume of fuel _+ 15 gallons interface secudty code to prevent tampering. ^ security Leak detect mode - 0.1 gallon key lock lets you select "normal" operation, "setup' to Fuel temperature _+ 1¥2°F enter or change system and tank parametem, or "diagnostics' to check the system's hardware and Time _+ I minute/week software. And TLS "Remembem' Your System Parameters. TO ORDER After initial profiling, your individual system setup When ordering a TLS-250 system, you need only to spec- remains in CMOS memorywith battery backup. Tilt, vol- ify the probe length ("A" in dimension diagram below) and ume, manifolded tanks, alarm limits, three automatic whether you desire the optional printer. See the TLS-250 report print times, automatic leak detect start/stop price list for part numbers. times, pdnt header, tank labels, security code, and tank All other operating requirements are field-pro- configuration are permanently stored until you decide to grammed and need not be specified at the time of change them. purchase. CONSOLE DIMENSIONS MOUNTING HOLES (4) .. ; A = LENGTH OF PROBE 8' (2.44 m} -~ 18.25" ~__ 4" 9' (2.74 m) 10' (3.05m) - 19.75" SIDE 10'6" (3.20 m) -- 11' (3.35m) FRONT 12' (3.66 m) YEEDER-ROOTII A SURSIOIARY OF WESTERN PACIFIC INDUSTRIES m ~m PETROLEUM PRODUCTS 10011 70 SARGEANT STREET, HARTFORD, CT 06102 (203) 527-7201 A12 "~":.:'; 84 STEP AHEAD IN INVENTORY MANAGEMENT AND ENVIRONM£NTAL' PROTECTION! TLS Systems meet the needs of 'LOSS DETECTION = IDEAL FOR RETAIL today's station management with ENVIRONMENTAL AND PRIVATE FUELING automatic inventory information. PROTECTION OPERATIONS And they look to the future by being TLS not only addresses the need for Automated, continuous monitoring able to integrate with other devices tight inventory control for effective of fuel stored underground and the )to form .sophisticated management station management, but also pro- ability to spot leaks quickly has systems, vides a means of meeting environ- become Critically important because TLS can interface with elec- mental concerns over underground of the high cost of fuel inventories tronic cash registers, point-of-sale leaks, and the growing concern for environ- terminals, and/or data processing Unexplained inventory losses, mental protection. This is true not systems to provide detailed informa- even small ones, may be leaks only for traditional retail fuel tion on fueling transactions and that can cause severe environmen- dealers, but also for the increasing inventories, tal damage. Inventory control rec- number of private fueling operations Information from TLS can also ords from TLS are the first step in in commercial, corporate and gov- be transmitted via existing telecom- spotting them. Then you can switch emment fleets. Typical users of TLS- munications networks to central immediately to "Leak Detect' for a 250 would be: management headquarters. This is closer look. If the test confirms your especially important for multi-loca- suspicions, you.can take action fast! · Major oil companies tion convenience store chains, oil TLS-250 is a permanently · Oil jobbers jobbers, major oil companies and installed, continuous monitoring · Convenience stores dispensing fuel. unattended fueling sites where device for underground fuel storage · Commercial, pdvate and govern- the convenience of remote polling, tanks. Unlike one-time tank tests ment fleet operators' the speed of data collection and the that give you a status report on your · Other operations such as rail- reliability of information is of great tanks for only the day of the test, roads and airports where fuel may significance. TLS provides inventory information · ' be stored in underground tanks Using this information, you are as well as leak detection year round able to analyze station operations, and at your convenience. In addi- For complete information on plan fuel allocations and set bulk tion, while you pay hundreds of dol- TLS-250, contact your nearest delivery schedules with greater ~nd efficiency, ease lars for a one-time test only to end Veeder-Root Distributor. Or call up with a single report, the money Veeder-Root at (203) 527-7201. spent on TLS is a capital investment adding value to your operation while returning much-used operating infor- mation on a continual basis. 'qry. A TLS-250 probe is mounted permanently in operates on a capacitance principle to sense fuel height, and requfres only a simple two-wire connection to the console· Probes are available · A thermistor sensor measures fuel tempera- ture to provide temperature-compensated - inventory data--for use by the leak detect ~ BY turning a key, you select a TLS operating mode ·.. "Normal" to monitor inventory or detect leaks· "Setup" to enter or review system and tank parame- ters. "Diagnostics" to check 4~ Six hardware diagnostic LEDs hardware and software. ~ mounted internally allow service "Alarm Reset" to reset an people to check the system's status a/arm indication· at a glance. An easy-to-,r, ead 6 digit The 20 column TLS printer is simple to load, LCD shows, covered for paper protec- · time tion. A variety of printed · fuel and water height reports speeds shift · fuel volume changes, documents · fuel temperature invento~ confirms delive- An electronic label identi- ties each display, selected ~ ries, shows setup parame- ,~ ters, and provides leak by the function button. ' detection data. A three-stage filter helps to · ensure mea- surement accu- racy in all fuel tanks by separating Front-panel pushbuttons let you Through an RS-232 port, TLS- water from the profile TLS-250 with tank and sys- 250 interfaces with sophisticated tern parameters and revise them as electronic point-of-sale terminals to product. ~ you need. The buttons also provide form an integrated station manage- .~i~ 1'C.". the means to review all inventory ment system. And it can communi- · information, tank-by-tank, and call cate to a headquarters location via /.~ gO,,//,/~ c 7'~z~ .,~-. · , for printed reports, telecommunications networks for .~_. /~ x.,l .~'J"- " fast inventory reporting and auto- matic reconciliation of station totals. THEFT ALARM START LEAK MONITOR REGULAR UNLEADED Station Name Station Name NOV 10, 1984 Street Name Street Address 3:46 AM City, State~ Zip City, State zip Telephone Number Telephone Number NOV 10, 1984 NOV 'i 0,1984 LEAK ALARH 6:30 AN I1:00 PM REGULAR UNLEADED PRE:MI UN UNLEADED PRENI UN UNLEADED -4.32 GAL~.ONS/HOUR 5487 GAI"LONS FUEL DIESEL 5487 GALLONS FUEL :2.65 GALLONS/HOUR 51.36 INCHES FUEL 51.36 INCHES FUEL 0.0 INCHES 'WATER 0.0 INCHES I,~IATER 5U'3 55.3 DEGREES F DEGREES F LAR UNLEADED '---OVERFILL ALARM--- 14695 C~ALLONS FUEL REGULAR UNLEADED '.up to 8 tanks NOV 10,1984 3:46 AM TEST HOURS 1 - 6 TNK1 TNK2 TNK3 TNK4 DEGREES F 55.2 59.0 53.5 60.1 ---LOW LIMIT ALARM--- PREMIUM UNLEADED GA'LLONS REGULAR UNLEADED INVENTORY INCREASE NOV. 10, 1984 0.0 0.0 -0.3 .0.0 3:46 AM NOV 10, 1984 -0.1 0.0 -0.7 0.1 3:38 PM -0..1 0.0 -1.0 0.1 709 GALLONS FUEL -0.1 0.1 -1.3 0.0 *--HIGH WATER ALARM--- 56.7 DEGREES F -0.2 0.0 -1.8 0.0 NOV 10, 1984 -0.2 0.0 -2.1 0.1 REGULAR UNLEADED 3a1~9 pM NOV 10, 1984 3:46 AM .~685 GALLONS FUEL STOP LEAK MONITOR 60.4 DEGREES F NOV 11, 1984 4976 NET INCREASE 6:30 AM CORPORATION and 111 Series Manholes POMECO MODEL NO, 111 SPILL PROTECTION MANHOLE 16237 WLLINOIS AVENUE · PARAMOUNT, CALIFORNIA 90723 TELEPHONE (213) 633-5515 RAIN-T,TE MANHOLE LID & RING ADAPTOR & COVER BY CUSTOMER il MACHINED SURFACE ~ NIPPLE PLUG /-'-" TACK WELD DRAIN TO STORAGE TANK PIPE COUPLING ~ PARTIAL SECTION (PATENT PENDING) Sp;ll Protect,on Manholes 1 11 Standard Spill Protection Manhole 1 11-A Same as Model 11 except machined nipple length is adjusted for use with a vapor return value 11 I-B Sa,,me as Model 111 except no drain assembly is supplied 111-C Spill Protection Manhole designed for use with Hytrel type material FEATURES Double seal arrangement with "machined nipple" to form a positive liquid seal while providing ade- quate flexibility between the manhole and fill riser. {~oa-N seals are Teflon coated to reduce friction and to provide protection against swelling due to sure'to gasoline or other toxic chemicals where the Model 111 may be required. Seals are well protected against possible damage by containment in seal rings. Rain-tite lid and manhole ring design provides protection against floating gasoline or other toxic chemicals which may be contained in the "bucket" to ground level. A drain assembly is available for ease of. draining gasoline or chemicals back to the underground tank. The flexible hose used in the drain assembly is a woven stainless steel-teflon configuration. The exterior of Models 1t 1, 111-^, and. 111-B are epoxy coated for cOrrosion resistance. Capacity of the Model 111 series is approximately 5 gallons. The Models 111, 111-A and 111-B are preassembled for ease of installation. 920 3&TH 9:11 AM TANK PRODUCT GALLONS INCHES WATER OEG F ULLAGE i SUPREME UNLEADED 2957 27.95 5.E 89.1 E~3,5 Z PLUS UNLEADED 3594 32.59 0.2 Bg.a 3 REGULAR UNLEADED 2428 24.57 0.0 9C.& 9412 WASW30270 270 ;--M'MiiTC CAR WASH 920 34TH STREET BAKERSFIELD CA 933~~ 8~5-323-927~ TANK PRODUCT GALLONS iNCHES ~ATER DEG F 2 SUPREME UN~-AumJ 3006 28.63 0.0 ~9.£ £ PLU~ UNLEADED 3593 32.59 O.O 89.2 3 REGULAR UNLEADED 2443 24.67 '2.0 90.5 9397 WASH30280 280 S-MINUTE ~A,< WASH ~EO 3£TH STREET 805-323-,u?~ ~ ~u:3O TANK . ~uuwC, ~~ ,NCHES WATER D-~:~ ~- ULLAGE i SUPREME UNLEADED 3006 28.63 O.O 89.Z 8834 2 PLUS UNLEADED 359& 32.59 O.O 89.3 8246 290 S-MINUTE CAR' WASH 920 3&TH STREET BAKERSFIELD CA 93301 805-323-9072 8:00 AM TANK PROOWCT GALLONS INCHES WATER DEG F ULLAGE ........... ,,a=_.::__, !i,]27 2.z . =,.7. Z . _ ~ REGULAF~ UNLEADED 2t4~ 2£.~ u.~ LEAK MONITOS REPORT TEST START: &:O0 PM SEP~z,~' 199t TEST STATUS: OFF TANK i SLiPR~MI: UNL~ ~NDING T=MP:~ 89.~? DSG F LEAK RATF:_ 2.0~ ~A~ .... ~ ~ mNS/HOU~' CWMULA~ IV~ HOURLY VO'~,u~=,i ~HAN~_ (GALLONS): O.O 0.2 0.2 O.1 -0.0 O.O O.i 0.1 O.i ~.! 0.2 0.0 ~ i,J~ ,J~=~iu 0.20 GALl_ON/HOUR T~ST START TEMP: 89 .... 2 O=~ F START VOLwME: 352~ ~A~=~NS~''' r, ~ ~N~ING TEMP: 89.a OEG F LEAK R~T=: -0 06 CUMULATIVE.~n',~,,~'o~ v, VOLUME CHANGE (GALLONS): -0.! -0.~ -0.3 -0.3' -O.a -0.5 -0.~ -0.6 -0.7' -0 TANI< 3 REGULAR UNLEADED '0.20 GALLON/HOUR TEST PASSED START TEMP: 90.5 DEG F START VOLUME: 239a GALLONS ENDING TEMP: 90.50EG F LEAK RATE: -~.02 GALLONS/HOUR CUMULATIVE HOUR'~Y VOLUME CHANGE (GALLONS): -0 . 'I -O . 2 -0 . 2 -0.3 -0 . & -0 . 3 -0 . & -0 . & -~ . WASHSC2i~ ALARM HISTORY ~E90~T TANK 1 SUPREME UNLEADED LEAK ALARM: JAN 17, 199a I0:00 PM NOV 2~, 199~ l:OO AM APR 27) 1989 lO:O0 OVERFILL: MAY 31, 1990 !:57 AM MAY 1, 1990 ~:55 AM MAY 15,. ~'98~ 9:n~. .mM LOW LiMiT: JUN 29, ~99~ ~:37 PM JUN 3~ 199~ i0:t5 AM MAY i~ 199~ IO:~. AM W~:T A_i~M: JAN i7, 199i lO:OS AM JAN 16, 199i 9:57 PM NOV 19~ 1993 ~:2! PM LEAK ALARM: JAN 18~ 199t ~ :00 AM NOV 2D~ ~ I:~ AM APR =77., ~9~9 ~:DD PM OVERFILL: FEB 2~, 19B9 3:3& AM JAN A~ i~9 ~:37 AM DEC 20~ ~=== AM NOV 20, 1993 12:09 AM wAN 17, 199~ 1'0:14 AM JAN 16~ i994 !O:l& PM TANK 3 REGULAR UNLEADED ~mA,x ALARM: wAN 17~ ~.994 !0:00 PM 'AN 17~ 1994 ~°:00 AM NOV 20, 1993 12:00 AM OV=R, iLL: MAR 22, 1989 2:24 AM FEB 17, 1989 3:47 AM ?ER 4~ 1989 2:27 AM LOW =iNIT: OCT 2, !993 i:4~ PM SEP · ~ 1992 9:42 AM MAY 12,~1992 3:10 PM ~w--~ ' ~ : =AN 17, i,:~r , A,_AmM ., 1994 8:32 PM JAN 16, 1994 8:44 PM NOV 26, 1993 11:00 PM WASHD0250 250 DELIVERY REPORT TANK I SUPREME UNLEADED START TiME/DATE GALLONS' OEG,m STOl= m~/DATE,-,,,- ~AL~ONS' OEG F ~NCR=.,~' '-~ 11:27 PM AUG 22 2615 93.0 12:06 AM AUG 23 5927 87 0 3312 2:14 AM AUG 6 3956 90.8 2:52 AM AUG 6 6464 88 0 250~ 3:01 AM JUl_ 26 401& 90.4 3:39 AM JUL 26 6539 86 7 Z52~ lO:4n PM ~ - ~w= ~3 2985 89.0 11:22 PM JUL 13 73~3 88 1 8:51 PM JUN 29 1996 86.4 9:35 PM .iL.iN 29 6018 8& 2 4022 1:37 AM JUN 13 2738 82 I o AM · ~:l& JUN 13 6u~? 80 3 327~ ~:40 AM JUN = i471 80.8 3:19 AM JUN 5 4423 77 1 2952 9:54 PM MAY IS 3746 75.2 !0:30 PM MAY 15 57!6 74 2 i97E ii:00 PM MAY 3 1552 73.6 'i1:44 PM MAY 3 6015 71 i 4463 TANK 2 PLUS UNLEADED START T!ME/OATE GALLONS DEG F STOP -IMC~n^~=.._,~,~ GALLONS OEG F INCREASE 3:30 AM SE? 4 3724 '92.0 4:07 AM SEP ! 5691 86 8 1967 11:34 PM AUG 22 4297 92.4 12:09 AM AUG 23 5317 90 5 1020 2:05 AM AUG 6 36i7 91.4 2:57 AM AUG 6 6574 88 3 2957 3:14 AM JUL 26 1724 92.9 3:54 AM JUL 26 4975 85 6 3251 8:52 PM JUN 29 36!9 86,0 9:30 PM JUN 29 5627 85 8 2008 1:45 AM JUN 13 4990 81.4 2:19 AM JUN 13 6B06 81 i 1016 37 AM JUN 5 3730 80.7 3:16 AM JUN 5 6249 77 6 2519 S~ ~M MAY 15 ~037 76.6 10:34 PM MAY I~ 6562 74 5 3:04 AM APR 18 2295 73.1 3:47 AM APR 18 ~568 &9 9 4273 10:17 OM MAR 17 310~ && 2 l!:OO PM MAR START TIME/DA TM · , .~E GALLONB DEG F STOP TiME/mA~= ~^i , r, Mc :03 AM JUL 26 £~, 92 8 Si&7 AM ~U~ 7562 87 8:59 PM JUN 29 350& 87 & 9:39 PM .JUN 29 &214 87 2 271[ i:35 AM JUN 13 3851 83 i Z:18 AM JUN 13 83£9 2:&5 AM jUN 5 2&&7 82 8 3:2~ AM JUN 5 5737 79 7 327[