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BUSINESS PLAN (3)
UNIFIED PROGRAM INSPECTION CHECKLIST --. A F~r n F/RE SE-CTION ~1: -Business Plan-and Inventory Program aR"" Prevention Services 900 Truxtun Ave., Suite 2'10 Bakersfield, CA 93301 Tel.: (661) 326-3979 - Fax: (661) 872-2171 _ FACILITY .NAME ~ - - INSPECTION DATE INSPECTION TIME ~~ I~ ~' 1= 5i ~ - '~-~!~ O7 ~p~ - ADDRESS - PHONE O. NO OF EMPLOYEES ~ r . l.,t ~vtK~,/1 i~~3Z3-lZy' 30 FACILITY CONTACT BUSINESS ID NUMBER - 15-021- ~/~/-/~ ~ ~ ~ ~~ Section 1: Business Plan and Inventory Program ROUTINE ^ COMBINED ^ JOINT AGENCY ^ MULTI-AGENCY ^ COMPLAINT ^ - RE-INSPECTION C V ~ C=Compliance _ OPERATION V=Violation COMMENTS ^ APPROPRIATE PERMIT ON HAND ^ BUSIneSS PLAN CONTACT INFORMATION ACCURATE w ^ VISIBLE ADDRESS ^ CORRECT OCCUPANCY ^ VERIFICATION OF INVENTORY MATERIALS - ^ VERIFICATION OF QUANTITIES ^ VERIFICATION OF LOCATION ^ PROPER SEGREGATION OF MATERIAL ^ VERIFICATION OF MSDS AVAILABILITY ^ VERIFICATION OF HAZ MAT TRAINING ^ .VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES ^ EMERGENCY PROCEDURES ADEQUATE ^ CONTAINERS PROPERLY LABELED ^ HOUSEKEEPING ^ FIRE PROTECTION ^ SITE DIAGRAM ADEQUATE & ON HAND ANY HAZARDOUS WASTE ON SITE? I~ YES ^ NO EXPLAIN: ~~^ ' TK d 1 L QUESTIONS REGARD{NG THIS INSPECTION? PLEASE CALL US AT (661) 326-3979 Inspector (Please Print) Fire Prevention / 1~' In /Shift of Site/Station # /P° BLS ~i~~~~'le-~ Business Site /Responsible Party (Please Print) White -Prevention Services Yellow -Station Copy Pink -Business Copy FD 2155 (Rev. 09/05 ` ~ ~ ~~ ~. ~~r';YSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 Manager DEE SECARA BusPhone: (661) 323-6296 Location: 1233 E CALIFORNIA AVE Map 103 CommHaz Extreme City BAKERSFIELD Grid: 32C FacUnits: 1 AOV: CommCode: BFD STA 02 EPA Numb: CAL922854734 SIC Code:2086 DunnBrad: Emergency Contact / Title Emergency Contact / Title HARRY BARBA / QC SUPERVISOR DAVID WRIGHT / PROD MANAGER Business Phone: (661) 323-6296x Business Phone: (661) 323-6296x 24-Hour Phone (661) 823-1708x 24-Hour Phone (661) 836-1382x Pager Phone ( 6 61) 3 3 3 - 0117x Pager Phone (~ ~ ) ~'~ ~ -'~~ d'~ Hazmat Hazards: Fire Press React ImmHlth DelHlth Contact DEE SECARA Phone: (661) 323-6296x MailAddr: 1233 E CALIFORNIA AVE State: CA City BAKERSFIELD Zip 93307 Owner PETER GORDON Phone: (702) 942-0500x Address 501 WASHINGTON ST State: CA City CALISTOGA Zip 94515 Period to Preparers Certif'd: ParcelNo: Emergency Directives: PROG A - HAZMAT PROG H - HAZ WASTE GEN PROG R - CALARP PROG T - ABOVEGROUND STORAGE TANK TotalASTs: _ TotalUSTs: _ RSs: No ~N~`~~ ~! U ~ 1 ~ ~~0~' THIS IS AN RMP SITE WHICH REQUIRES A JOINT INSPECTION. CALL ENV SVGS TO SCHEDULE AN INSPECTION. Based on my inquiry of these individuals responsible for obtaining the information, I certify under penalty of lavr that I have personally ®xamined and am familiar with the information submitted and believe the information is true, accurate, and complete. Signature, - 0~ • ~~-~ ~ J Gall Gal -1- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order Fixed Containers on Site ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP ~ONIA, ANHYDROUS ~V ~ ~ ~~~ E F P IH G 110250.00 FT3 Ext P ` ~ E F P IH G 18158.00 FT3 Hi HYDROCHLORIC ACID E R IH L 250.00 GAL Hi ACETYLENE E F P IH G 130.00 FT3 Hi SODIUM HYPOCHLORITE R IH L 104.00 GAL Hi CAUSTIC (ALKALINE) R IH L 450.00 GAL Mod SANATOX DH S 300.00 LBS Mod ACID CLEANER LF3 R IH L 165.00 GAL Mod CHLORINATED FOAMER (A.LKACHLOR) R IH DH L 110.00 GAL Mod SAFETY KLEEN 105 SOLVENT F L 20.00 GAL Mod MALEIC ACID S 300.00 LBS Low OXYGEN F P IH G 251.00 FT3 Low WASTE OIL F DH L 55.00 GAL Low CARBON DIOXIDE F P IH G 420333.00 FT3 Min CITRIC ACID ANHYDROUS S 10000.00 LBS Min HOT MELT ADHESIVE S 800.00 LBS Min ASCORBIC ACID F R IH DH S 300.00 LBS Min ARGON WELDER F P IH G 155.00 FT3 Min NITROGEN F P IH G 142.00 FT3 Min PROPYLENE GLYCOL FOOD GRADE F L 2500.00 GAL UnR -2- 07/11/2007 -3- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ~ Inventory Item 0030 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME AMMONIA, ANHYDROUS Days On Site 365 Location within this Facility Unit Map: Grid: ENGR AREA SW CRNR W BLDG CAS# 7664-41-7 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas Mixtur~ Ambient ~ Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 110250.00 FT3 110250.00 FT3 110250.00 FT3 HAZARDOUS COMPONENTS %Wt. RS CAS# 100.00 Ammonia (EPA) Yes 7664417 t31-]GE1KL 11. 7.7 C, ~7.71~1~1V l ~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Ext ~ Inventory Item 0004 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME PROPANE Days On Site 365 Location within this Facility Unit Map: Grid: SE PARKING LOT CRNR CAS# 74-98-6 STATE T TYPE Gas I Pure CONTAINER TYPE _ FIXED PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 18158.00 FT3 18158.00 FT3 14550.00 FT3 rarac~ruurv~o ~.vi•irvlvnlvta oWt. RS CAS# 100.00 Propane Yes 74986 r1tiG~t]2CL tiw 7 w7~JJ1.1P~1V1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Hi = PRESSURE TEMPERATURE Above Ambient Ambient -4- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ~ Inventory Item 0034 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME HYDROCHLORIC ACID Days On Site 365 Location within this Facility Unit Map: Grid: ADJ TO ALLEY S SIDE W BLDG OUTSIDE CAS# 7647-01-0 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid Mixture Ambient Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 250.00 GAL 250.00 GAL 175.00 GAL ~„ ~,.,,.r,.,.,r,,.T.,,,, f11iGL3CCLVU~ 1.V1~1rV1VJ;1Vl~J owt. Rs cAS# Hydrogen Chloride Yes 7647010 t1E~GHttL AJ J 1".; J 51~1~1V 1 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Hi ~ Inventory Item 0010 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME ACETYLENE Days On Site 365 Location within this Facility Unit Map: Grid: SW CRNR SHOP STORAGE E BLDG CAS# 74-86-2 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas PureAbove Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 130.00 FT3 130.00 FT3 100.00 FT3 ritiGtittLVUJ L.V1~1rV1vL~lv17 %Wt. RS CAS# 100.00 Acetylene Yes 74862 IlE~GHKL ti~ J.7.C~.7.71~1~1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Hi -5- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD ~ Inventory Item 0024 COMMON NAME / CHEMICAL NAME SODIUM HYPOCHLORITE Location within this Facility Unit W SIDE INSIDE E BLDG STATE - TYPE PRESSURE Liquid Mixtur~mbient SiteID: 015-021-001418 ~ Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# 7681-52-9 TEMPERATURE CONTAINER TYPE Ambient ~ PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 52.00 GAL 104.00 GAL 52.00 GAL r1r~ZARDOUS COMPONENTS %Wt. RS CAS# 12.50 Sodium Hypochlorite No 7681529 1.00 Sodium Hydroxide No 1310732 L1tiL~tiRL t1J JP~J J1.1P~1V1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Hi ~ Inventory Item 0035 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME CAUSTIC (ALKALINE) Days On Site 365 Location within this Facility Unit Map: Grid: OUTSIDE W BLDG IN ALLEY S SIDE OF W BLDG CAS# 7647-01-0 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixture ~mbient ~ Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 450.00 GAL 450.00 GAL 250.00 GAL HAZ O RD US COMPONENTS oWt. RS CAS# Sodium Hydroxide No A 1310732 rlti[~ti1S.L HJ JL~J J1"1P~1V1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Mod -6- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ~ Inventory Item 0036 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME SANATOX Days On Site 365 Location within this Facility Unit Map: Grid: OUTSIDE TANK AREA CAS# ~SolidE TMixture ~ Ambient~E ~ AmbientT~E DRUM/BARRELENONMETAL~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 55.00 LBS 300.00 LBS 200.00 LBS rttiGtitcl~vua ~vl~irvlvlJly l a °sWt. RS CAS# 95.00 Bromochlorodimethylhydantoin No 126067 3.00 Boric Acid No 10043353 2.00 Sodium Chloride No 7647145 ri1~GHKL A7~t;~~1~iL';1V'1~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies DH / / / Mod ~ Inventory Item 0032 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME ACID CLEANER LF3 Days On Site 365 Location within this Facility Unit Map: Grid: W BLDG CIP ROOM AREA CAS# Liquid TMixtur~ Ambient~E ~ AmbientT~E DRUM/BARRELENONMETAL~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 55.00 GAL 165.00 GAL 100.00 GAL 111-~Gt1CC11VUJ I.VL~lYV1V1;1V 1.7 %Wt. RS CAS# Phosphoric Acid No 7664382 riHGtitClJ Li~ ~~~~1~1~1V1~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Mod -7- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD ~ Inventory Item 0018 COMMON NAME / CHEMICAL NAME CHLORINATED FOAMER (ALKACHLOR) Location within this Facility Unit INSIDE W BLDG E BLDG SiteID: 015-021-001418 ~ Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# Liquid TMixture Ambient~E ~ AmbientT~E DRUM/BARRELENONMETAL~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 GAL 110.00 GAL 55.00 GAL - t1H~tilcLVU~ wl~ir~iv~lvl~ %Wt. RS CAS# 25.00 Potassium Hydroxide No 1310583 t11~GHtCL H~:i.7L",.7w71~1C~1V 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH DH / / / Mod ~ Inventory Item 0028 COMMON NAME / CHEMICAL NAME SAFETY KLEEN 105 SOLVENT Location within this Facility Unit SHOP E BLDG STATE TYPE PRESSURE Liquid TMixtur~mbient Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# 64742-41-9 TEMPERATURE CONTAINER TYPE Ambient IN MACHINE/EQUIP AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 20.00 GAL 20.00 GAL 20.00 GAL nt~c~tucLVUa ~.vl~irvtv~lvt~ %Wt. RS CAS# 89.00 Mineral Spirits No 8030306 17t~GHtCL Hil.7L' ~~71"1L" 1V 1 w7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F / / / Mod -8- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SitelD: 015-021-001418 ~ ~ Inventory Item 0008 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME MALEIC ACID Days On Site 365 Location within this Facility Unit Map: Grid: BATCH AREA (W BLDG) CAS# 6915-15-7 ~SolidE TMixture ~ Ambient~E ~ AmbientTURE BAG CONTAINER TYPE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 50.00 LBS 300.00 LBS 150.00 LBS riEiGH1CLVUJ 1.V1~lYV1VtS1VlJ %Wt. RS CAS# 100.00 Malefic Acid No 110167 -- I11-1G1-1tCL HJJ~JJ1~1~1V1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Low ~ Inventory Item 0005 COMMON NAME / CHEMICAL NAME OXYGEN Location within this Facility Unit SHOP STORAGE AREA (E BLDG) STATE TYPE PRESSURE _ Gas TPure ~-Above Ambient Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# 7782-44-7 TEMPERATURE CONTAINER TYPE Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 251.00 FT3 251.00 FT3 251.00 FT3 - ru~uruc.uv~a ~.vrtrvlvr~LVtJ -- %Wt. RS CAS# 100.00 Oxygen, Compressed No 7782447 rltiutilCL tiJ JL~JJI"1LilV1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Low -9- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ~ Inventory Item 0037 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME WASTE OIL Days On Site 365 Location within this Facility Unit Map: Grid: CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE _ Liquid TWasteAmbient ~ Ambient DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 GAL 55.00 GAL 55.00 GAL HAZARDOUS COMPONENTS °~Wt. RS CAS# 100.00 Waste Oil, Petroleum Based No 0 riEiGHtCL E'i.7.7L" JJ1~1t51V 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F DH / / / Low ~ Inventory Item 0003 COMMON NAME / CHEMICAL NAME CARBON DIOXIDE Location within this Facility Unit BET E & W BLDG N SIDE STATE TYPE PRESSURE _ Gas TPure ~-Above Ambient Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# 124-38-9 TEMPERATURE CONTAINER TYPE Ambient FIXED PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest420333100rFT3 Dai420333100m FT3 I Dai242500r00e FT3 nric~s-u~LV~~ ~.vi~lrvlvaly 1 ~ gWt. RS CAS# 100.00 Carbon Dioxide No 124389 17t~GHiCL L'3.7 JP~.7A1"1P~1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Min -10- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SitelD: 015-021-001418 ~ ~ Inventory Item 0007 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME CITRIC ACID ANHYDROUS Days On Site 365 Location within this Facility Unit Map: Grid: BATCH AREA W BLDG CAS# 77-92-9 ~SolidE TMixture I AmbRient~E ~ AmbientTURE BAG CONTAINER TYPE AMOUNTS AT THIS LOCATION Largest Con50100rLBS Dai110000100m LBS I Daily4000r00e LBS t1AG1iL[LJV UJ wrir~iv~iv 1 $Wt. RS CAS# 100.00 Citric Acid No 77929 t1HGHtCL HJ SL" Jb1~1J~J1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Min ~ Inventory Item 0002 COMMON NAME / CHEMICAL NAME HOT MELT ADHESIVE Location within this Facility Unit PACKING AREA S BLDG Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# 92717 STATE TYPE PRESSURE Solid TMixture ~ Ambient AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 50.00 LBS _ 800.00_ LBS 400.00 LBS IIHGKCCLVU.7 1,U1~1rUlV~1V 1.7 %Wt. RS CAS# 100.00 PPO No 92717 riHGEiKL a'~.7.7L' .7.71~11•S1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Min TEMPERATURE CONTAINER TYPE Ambient BOX -11- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ~ Inventory Item 0025 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME ASCORBIC ACID Days On Site 365 Location within this Facility Unit Map: Grid: W SIDE OF W BLDG BATCH AREA CAS# 50-81-7 ~SolidE I Mixtures PRESSURE TEMPERATURE CONTAINER TYPE I Ambient ~ Ambient DRUM/BARREL-NONMETAL AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 LBS 300.00 LBS 175.00 LBS HAZARDOUS COMPONENTS oWt. RS CAS# 100.00 Ascorbic Acid No 50817 I1HGEiiCL 1~.7.7L~.7.71"1P~1V 1 .7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F R IH DH / / / Min ~ Inventory Item 0006 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME ARGON WELDER Days On Site 365 Location within this Facility Unit Map: Grid: SHOP STORAGE AREA E BLDG CAS# 7440-37-1 ~GasATE TPureE -~AboveSAmbEent AmbPeRATURE PORTCOPRESSERCYLINDER- AMOUNTS AT THIS LOCATION Largest Co155100rFT3 Daily M55100m FT3 I Daily A~5r00e FT3 ru~crruu~v~.~ ~.vt•lrvlv~ly t S _. oWt• RS CAS# 100.00 Argon No 7440371 rll]UtiRL 1"1J ~L1J i71.1P~1V1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Min -12- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD ~ Inventory Item 0013 COMMON NAME / CHEMICAL NAME NITROGEN Location within this Facility Unit W BLDG SW CRNR BATCH AREA STATE TYPE PRESSURE _ Gas TPure ~-Above Ambient SiteID: 015-021-001418 ~ Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# 7727-37-9 TEMPERATURE CONTAINER TYPE Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 142_00 FT3 142.00 FT3 70.00 FT3 I1tiGtiRLV V .7 l.VP7Y V1V t+1V 1 J %Wt. RS CAS# 100.00 Nitrogen No 7727379 I1L-~GriRL ti. 7.J P.~.7.71"1L~1V l A TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Min ~ Inventory Item 0031 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME PROPYLENE GLYCOL FOOD GRADE Days On Site 365 Location within this Facility Unit Map: Grid: ENGR AREA SE CRNR W BLDG CAS# 57-55-06 Liquid TYPE PRESSURE ~ TAE~MPeRATURE CONTAINER TYPE TMixtur~ Ambient IN MACHINE/EQUIP AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 2500.00 GAL 2500.00 GAL I 2500.00 GAL rl.lyc~ru~t~VV.7 L,V1•lYV1V81Vt.S %Wt. RS CAS# Propylene Glycol No ' 57556 i71i[~tiLCL tii J iJ P.~~J .71"1LilV 1 A TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F / / / UnR -13- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ Fast Format ~ ~ Notif./Evacuation/Medical Overall Site ~ ~ Agency Notification 10/05/2000 ~ CALL 911 AND THE STATE OFFICE OF EMERGENCY SERVICES WILL ALSO BE NOTIFIED AS REQUIRED. Employee Notif./Evacuation 10/26/2006 IN CASE OF A HAZARDOUS MATERIAL SPILL, THE PLANT MANAGER, UPON NOTIFICATION, WILL USE THE PAGING SYSTEM TO NOTIFY ALL EMPLOYEES TO EVACUATE THE FACILITY. EACH SUPERVISOR IS TO DIRECT THE EMPLOYEES IN HIS AREA TO THE SAFEST EXIT AND MAKE SURE THAT HIS AREA HAS BEEN VACATED BY ALL PERSONNEL. ALL EMPLOYEES EVACUATED WILL REPORT TO A DESIGNATED AREA OUTSIDE THE FACILITY. AFTER NORMAL HOURS NOTIFY THE FOLLOWING IN THIS ORDER: BOB HOFFERD 832-0453, IF HE CANNOT BE REACHED, CALL DAVID WRIGHT 836-1382, IF HE CANNOT BE REACHED, CALL DEE SECARA 340-0426, IF SHE CANNOT BE REACHED, CALL ARMANDO RAYO 324-1156. CALL ARMANDO RAYO IN THE EVENT OF ANY AMMONIA LEAK. Public Notif./Evacuation 10/26/2006 DURING A RELEASE, THE PLANT ENGINEER (MAINTENANCE MANAGER) WILL: STOP LEAKS, IF POSSIBLE, AND SUPERVISE THE USE OF SELF-CONTAINED BREATHING APPARATUS (SCBA). -14- 07/11/2007 P CRYSTAL GEYSER OF BAKERSFIELD SitelD: 015-021-001418 Fast Format ~ Notif./Evacuation/Medical Overall Site ~ Emergency Medical Plan 02/22/2007 EACH SUPERVISOR WILL BE TRAINED IN CPR AND FIRST AID. FOR MINOR INJURIES VERNON SORENSON MD WILL BE USED. FOR SERIOUS INJURY OR INJURY DUE TO HAZARDOUS MATERIAL, THE NEAREST HOSPITAL EMERGENCY ROOM WILL BE USED, AT THE DISCRETION OF AMBULANCE SERVICE. 9 -15- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 Fast Format ~ Mitigation/Prevent/Abatemt Overall Site ~ Release Prevention 10/05/2000 TO PREVENT THE RELEASE OR SPILL OF HAZARDOUS MATERIAL AT THIS FACILITY, ONLY INDIVIDUALS REQUIRED TO USE HAZARDOUS MATERIALS IN THE COURSE OF THEIR WORK WILL BE ALLOWED TO HANDLE THEM. EACH OF THESE INDIVIDUALS WILL BE TRAINED IN THE SAFE HANDLING AND USE PROCEDURES FOR EACH PRODUCT. 9 9 Release Containment 10/26/2006 PROCEDURES FOR CONTAINMENT WILL BE THOSE RECOMMENDED BY THE MANUFACTURER OF THE PRODUCT AS DESCRIBED IN THE MATERIAL SAFETY DATA SHEET. AMMONIA DIFFUSION SYSTEM LOCATED BETWEEN BUILDINGS, INSIDE CONTAINMENT WALL. IMPLEMENTATION OF SPILL PREVENTION AND CONTAINMENT PROGRAM DEVELOPED SPILL KITS LOCATED AT STRATEGIC AREAS FOR QUICK RESPONSE TO CHEMICAL SPILLS Clean Up 04/07/2006 PROCEDURES FOR CLEAN-UP WILL BE THOSE RECOMMEDED BY THE MANUFACTURER OF THE PRODUCT AS DESCRIBED IN THE MATERIAL SAFETY DATA SHEET. Other Resource Activation -16- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ .~Nc~.iai na~aiu~ Utility Shut-Offs 01/29/2007 A) GAS - MAIN SHUT-OFF INSIDE FENCE NEXT TO ALLEY BET E & W BLDG 300FT E OF ROBINSON ST B) ELECTRICAL - INSIDE SW CRNR OF E BLDG BOTH SIDES OF EXIT DOOR MAIN TRANSFORMER BET E BLDG C) WATER - ALLEY NEXT TO FENCE & SW CRNR OF W BLDG (DEPT HOOK-UP & AMMONIA DUMP SYSTEM VALVE CONTROL BOX OUTSIDE BLDG NEXT TO ALLEY) D) SPECIAL - NONE E) LOCK BOX - YES CALIFORNIA AVE OVER MAIN ENTR Fire Protec./Avail. Water 01/29/2007 PRIVATE FIRE PROTECTION - AUTOMATIC OVERHEAD SPRINKLERS MONITORED BY TEL-TEC SECURITY SYSTEMS AND FIRE EXTINGUISHERS. FIRE HYDRANT - N SIDE OF E CALIFORNIA AVE, 120FT W OF NW CRNR OF SITE. FIRE DEPT HOOK-UP TO MAIN SPRINKER SYSTEM RISER EXISTS IN ALLEY, 220FT W OF LAKEVIEW AVE. FIRE DEPT HOOK-UP FOR W BLDG 350FT E OF ROBINSON ST IN ALLEY. Building Occupancy Level 04/07/2006 32 EMPLOYEES -17- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ Fast Format ~ Training Overall Site -18- 07/11/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 Fast Format ~ Training Overall Site ~ Employee Training 01/29/2007 MATERIAL SAFETY DATA SHEETS ON FILE. BRIEF SUMMARY OF TRAINING PROGRAM: INCLUDES A LIST OF THOSE QUALIFIED IN S.C.B.A. EACH EMPLOYEE INVOLVED IN THE USE OF HAZARDOUS MATERIALS WILL BE GIVEN INSTRUCTION IN THE SAFE HANDLING AND USE OF EACH PRODUCT BEFORE THEY BEGIN USE. EACH EMPLOYEE WILL BE PROVIDED WITH SAFETY EQUIPMENT REQUIRED FOR EACH PRODUCT HANDLED. SAFETY PROCEDURES FOR SPILL CLEAN-UP OF HAZARDOUS MATERIALS WILL BE TAUGHT. NEW HAZARDOUS MATERIALS INTRODUCED INTO INVENTORY WILL BE REVIEWED WITH EACH INDIVIDUAL BEFORE USE. REFRESHER COURSES IN SAFE HANDLING OF HAZARDOUS MATERIAL WILL BE REQUIRED OF EACH EMPLOYEE INVOLVED IN THE USE OR HANDLING DURING THE YEAR. IN ACCORDANCE WITH YOUR REQUEST, WE SUBMIT THE FOLLOWING LIST OF INDIVIDUALS WHO HAVE BEEN TRAINED TO INITIATE AN EMERGENCY RESPONSE TO AN UNLIKELY INCIDENT. 1) ARMANDO RAYO, MAINTENANCE PERSON ARMANDO IS IN TRAINING AND IS GETTING EXPERIENCE IN ALL ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT-OFF VALVES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES AND HAS BEEN TRAINED IN THE USE OF OUR AMMONIA DIFFUSION SYSTEM. ALSO, ARMANDO HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. 2) ROBERT HOFFERD, SHIPPING/SAFETY SUPERVISOR ROBERT HAS BEEN TRAINED AND IS EXPERIENCED IN MOST ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT-OFF VALVES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES, AND BEING TRAINED IN THE USE OF OUR AMMONIA DIFFUSION SYSTEM. ALSO, ROBERT HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ALBE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. 3) RICHARD WEKLYCH, PLANT MANAGER RICHARD HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY ACCIDENT. 4) CHARLES WRIGHT, MAINTENANCE MECHANIC CHARLES IS IN TRAINING AND IS GETTING EXPERIENCE IN ALL ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT-OFF VALVES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA-SAFE HANDLING PRACTICES BEING TRAINED IN THE USE OF OUR AMMONIA DIFFUSION SYSTEMS. ALSO, CHARLES HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. -19- 07/11/2007 y c F.CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ,' Fast Format ~ ~ Training Overall Site ~ ~ Page 2 04/07/2006 ~ 5) DAVID WRIGHT - PRODUCTION MANAGER DAVID IS IN TRAINING AND IS GETTING EXPERIENCE IN MOST ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT-OFF VALVES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES AND BEING TRAINED IN THE USE OF OUR AMMONIA DIFUSION SYSTEM. 6) HARRY BARBA - QUALITY CONTROL TECH HARRY HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. ALL PLANT MANAGEMENT, MAINTENANCE PERSONNEL AND OTHER EMPLOYEES WHO WORK WITH LITTLE SUPERVISION WILL BE TRAINED IN FIRST AID AND CPR. nclu 1V1 t UI.UiC V.SC nc lu tVl L'UI.UtC VAC -20- 07/11/2007 ~~ CR~!~TAL GEYSER OF BAKERSFIELD - ~~=`~ ~, ~ SiteID: 015-021-00141 $~ Manager DEE SECARA BusPhone: (661) 323-6296 Location: 1233 E CALIFORNIA AVE Map 103 CommHaz Extreme City BAKERSFIELD Grid: 32C FacUnits: 1 AOV: CommCode: BFD STA 02 EPA Numb: CAL922854734 SIC Code:2086 DunnBrad: Emergency Contact / Title Emergency Contact / Title HARRY BARBA / QC SUPERVISOR DAVID WRIGHT / PROD MANAGER Business Phone: (661) 323-6296x Business Phone: (661) 323-6296x 24-Hour Phone (661) 823-1708x 24-Hour Phone (661) 836-1382x Pager Phone (661) 333-0117x Pager Phone ( ) - x ... Hazmat Hazards: Fire Press React ImmHlth DelHltli ............... Contact DEE SECARA Phone: (661) 323-6296x MailAddr: 1233 E CALIFORNIA AVE State: CA City BAKERSFIELD Zip 93307 Owner PETER GORDON Phone: (702) 942-0500x Address 501 WASHINGTON ST State: CA City CALISTOGA Zip 94515 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif~d: RSs: No ParcelNo: Emergency Directives: PROG A - HAZMAT PROG H - HAZ WASTE GEN PROG R - CALARP PROG T - ABOVEGROUND STORAGE TANK THIS IS A RMP SITE WHICH REQUIRES A JOINT INSPECTION. PL EASE CALL ENV SVGS TO SCHEDULE AN INSPECTION. Based on my inquiry of those individuals responsible for obtaining the i f F EB ~ ~ 2007 EN1'D n ormation, I certify under penalty of law thai I have person exami ll d a ne y and am familiar with the information submitted and believ e the information is true, accurate, and complete. Signature - Date -1- of j29/zoo? F CRYSTAL GEYSER OF BAKERSFIELD ~ SiteID: 015-021-001418 ~ ~ I~azmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order Fixed Containers on Site ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit 1WICP AMMONIA, ANHYDROUS E F P IH G 110250.00 FT3 Est PROPANE E F P IH G 18158.00 FT3 iii. HYDROCHLORIC ACID E R IH L 250.00 GAL Hi ACETYLENE E F P IH G 130.00 FT3 f-# SODIUM HYPOCHLORITE R IH L 104.00 GAL ~I CAUSTIC (ALKALINE) R IH L 450.00 GAL Mod SANATOX DH S 300.00 LBS Nod ACID CLEANER LF3 R IH L 165.00 GAL ~iod CHLORINATED FOAMER (ALKACHLOR) R IH DH L 110.00 GAL rvtod SAFETY KLEEN 105 SOLVENT F L 20.00 GAL Ntod MALEIC ACID S 300.00 LBS Low OXYGEN F P IH G 251.00 FT3 Low WASTE OIL F DH L 55.00 GAL Low CARBON DIOXIDE F P IH G 420333.00 FT3 lain CITRIC ACID ANHYDROUS S 10000.00 LBS lain HOT MELT ADHESIVE S 800.00 LBS Nan ASCORBIC ACID F R IH DH S 300.00 LBS 1'~In ARGON WELDER F P IH G 155.00 FT3 I'~n NITROGEN F P IH G 142.00 FT3 N[in PROPYLENE GLYCOL FOOD GRADE F L 2500.00 GAL U~iR I have enclosed copies of all new flavorings. msds says they are flammable and combustable so I am adding. NATURAL APPLE FLAVOR NATURAL APPLE JUICE LIME EXTRACT LEMON EXTRACT ORANGE EXTRACT ORANGE BERGAMONT FLAVOR VERY BERRY FLAVOR WONF WHITE WINE FLAVOR -2- 01/29/2007 LOOZ/6Z/Z4 -E- ~~a :, ~ CRY'°STAL GEYSER OF BAKERSFIELD ~ ,,. SiteID: 015-021-00141$ ~ ~ l~nventory Item 0030 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME AMMONIA, ANHYDROUS Days On Site 365 Location within this Facility Unit Map: Grid: ENGR AREA SW CRNR W BLDG CAS# 7664-41-7 ~GasATE TMixture I AmbRent~E ~ TAE~MPeRATURE PORTCOPRESSERCYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 110250.00 FT3 110250.00 FT3 110250.00 FT3 ---- nt~~tLrcl~vu5 wrir~lv~ly 15 °sWt . RS CAS# 100.00 Ammonia (EPA) Yes 7664417 riAGE1KL A~~r;~51~1r;1V'1'S TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MC1~ No No No No/ Curies F P IH / / / Est ~ Inventory Item 0004 ~ COMMON NAME / CHEMICAL NAME I PROPANE Facility Unit: Fixed Containers on Site ~ Days On Site 365 Location within this Facility Unit Map: Grid: SE PARKING LOT CRNR CAS# 74-98-6 ~GasATE TPureE ~-AboveSAmbEent AmbientT~E FIXEDOPRESSERCYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 18158.00 FT3 18158.00 FT3 14550.00 FT3 IltiGtiLCLVUJ 1~V1~lYV1V 1S1V 1.7 %Wt. RS CAS# 100.00 Propane Yes 745$6 I1HGEitCL H ~.7I;A~71~1J;1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCA No No No No/ Curies F P IH / / / Hi -4- 01/29/2007 ;~ F CRI~STAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ~ Inventory Item 0034 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME HYDROCHLORIC ACID Days On Site 365 Location within this Facility Unit Map: Grid: ~- ADJ TO ALLEY S SIDE W BLDG OUTSIDE CAS# 7647-01-0 Liquid TMixtur~ Ambient~E ~ AmbientT~E ABOVEOGROIUNDRTANKE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 250.00 GAL 250.00 GAL 175.00 GAL ru~.~,xtcLUU~ ~urirulv~iv l a ~Wt. RS CAS# Hydrogen Chloride Yes 7647t~10 riAGHKL A~5~JJ1~11',1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCA No No No No/ Curies R IH / / / Hi ~ Inventory Item 0010 ~ COMMON NAME / CHEMICAL NAME ACETYLENE Facility Unit: Fixed Containers on Site ~ Days On Site 365 Location within this Facility Unit Map: Grid: SW CRNR SHOP STORAGE E BLDG CAS# 74-86-2 ~GasATE TPureE -~AboveSAmbEent AmbPeRATURE PORTCOPRESSERCYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 130.00 FT3 130.00 FT3 100.00 FT3 HAZARDOUS COMPONENTS oWt. RS CAS# 100.00 Acetylene Yes 74$62 ns-~~rucL tia ~~~5i~ir,ly l a TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# M No No No No/ Curies F P IH / / / Hi -5- Ol/29/~007 :, F CRYFSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ ~ ~ inventory Item 0024 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME SODIUM HYPOCHLORITE Days On Site 365 Location within this Facility Unit Map: Grid: W SIDE INSIDE E BLDG CAS# 7681-52-9 ~ Liquid 1 Mixture~Ambient~E ~ AmbientT~E ~ PLASTOICTCONTAINERE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 52.00 GAL 104.00 GAL 52.00 GAL t1t~~tircl~uu5 uvrirulv~lvla %Wt. RS CAS# 12.50 Sodium Hypochlorite No 7681529 1.00 Sodium Hydroxide No 1310732 tiE1GH1CL 1-L75J;A 71~1L' 1V 1.J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCf No No No No/ Curies R IH / / / Hi ~ Inventory Item 0035 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME CAUSTIC (ALKALINE? Days On Site 365 Location within this Facility Unit Map: Grid: OUTSIDE W BLDG IN ALLEY S SIDE OF W BLDG CAS# 7647-O1-0 STATE - TYPE T PRESSURE TEMPERATURE CONTAINER TYPE Liquid Mixture ~ Ambient ~ Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 450.00 GAL 450.00 GAL 250.00 GAL ntic~rucl~vu~ ~.v1~1rv1vr,ly 1 ~ %Wt. RS CAS# Sodium Hydroxide No 1310732 I1HGL-1tC1J L» ~7 L' .7 ~71~1L' LV 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MC1~ No No No No% Curies R IH / / / Mod -6- 01/29/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ ~ ~ inventory Item 0036 Facility Unit: Fixed Containers on Site ~ COMMON NAME j CHEMICAL NAME SANATOX Days On Site 365 Location within this Facility Unit Map: Grid: OUTSIDE TANK AREA CAS# ~SolidE TMixture I AmbRent~E ~ AmbientT~E DRUM/BARRELENONMETAL~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 LBS 300.00 LBS 200.00 LBS • t1HG1~tCLVUS 1.V1~lYV1VL'1V15 %Wt. RS CAS# 95.00 Bromochlorodimethylhydantoin No 126057 3.00 Boric Acid No 10043353 2.00 Sodium Chloride No 7647145 riAGHKL AaJLJJ1~11;1V1~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies DH / / / Mod ~ Inventory Item 0032 COMMON NAME / CHEMICAL NAME ACID CLEANER LF3 Location within this Facility Unit W BLDG CIP ROOM AREA STATE TYPE PRESSURE Liquid TMixture Tmbient Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# TEMPERATURE .CONTAINER TYPE _ Ambient DRUM/BARREL-NONMETAL AMOUNTS AT THIS LOCATIONI Largest Con55100rGAL Daily M65100m GAL , Daily 100r00e GAL rifiGKt'CLV U.7 trV1~1rV1vLSly 1 J %Wt. RS CAS# Phosphoric Acid No 76643$2 tl!-~GH.KL Ha JL" 5J1~1J;1V-15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Mod -7- 01/29/zoo? :; F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-001418 ~ ~ Inventory Item 0018 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME CHLORINATED FOAMER (ALKACHLOR) Days On Site 365 Location within this Facility Unit Map: Grid: INSIDE W BLDG E BLDG CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE _ Liquid TMixtur~Ambient ~ Ambient DRUM/BARREL-NONMETAL AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 55.00 GAL 110.00 GAL 55.00 GAL ~- nt~~titcl~vu~ t_:vlnr~lv~lvl a %Wt. RS CAS# 25.00 Potassium Hydroxide No 13105$3 riHGHKL L~55L"~aJ1~1151V 1'S TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH DH / / / Mvt3. ~ Inventory Item 0028 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME SAFETY KLEEN 105 SOLVENT Days On Site 365 Location within this Facility Unit Map: Grid: --- SHOP E BLDG CAS# 64742-41-9 Liquid TMixture ~ AmbRient~E ~ AmbientT~E IN MAOCHINE/EQUIPPE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 20.00 GAL 20.00 GAL 20.00 GAL HAZARDOUS COMPONENTS ~Wt. RS CAS# 89.00 Mineral Spirits No 803006 ns-~c~titu.~ ti~5~~~ril,lvla TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F / / / Mod -8- 01/29/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141: ~ ~ $nventory Item 0008 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME MALEIC ACID Days On Site 365 Location within this Facility Unit Map: Grid: BATCH AREA (W BLDG) CAS# 6915-15-7 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Solid TMixture ~ Ambient ~ Ambient BAG AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 50.00 LBS 300.00 LBS 150.00 LBS tiAGHK.LVUS w1~1rV1vL"1v15 oWt. RS CAS# 100.00 Malefic Acid No 11017 riAGF~KL H55tS~51~1i51V 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MC1~ No No No No/ Curies / / / Lvw ~ Inventory Item 0005 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME OXYGEN Days On Site 365 Location within this Facility Unit Map: Grid: SHOP STORAGE AREA (E BLDG) CAS# 7782-44-7 ~GasATE TPureE ~-AboveSAmbient AmbPeRATURE PORTCOPRESSERCYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 251.00 FT3 251.00 FT3 251.00 FT3 nr.c,HtcLV u ~ ~vlnrvly lily t a %Wt. RS CAS# 100.00 Oxygen, Compressed No 7782447 nriatitct~ s~~~lJ~~lnlJlvta TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / LvW -9- Ol/29/~n07 ,; F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ ~ ~ Inventory Item 0037 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME WASTE OIL Days On Site 365 Location within this Facility Unit Map: Grid: CAS# Liquid TWaste ~ Ambient~E ~ AmbientT~E DRUM/BNARRELEMETALLI~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 GAL 55.00 GAL 55.00 GAL riHGH.tCL V U 5 lL Vl~lr V1V 1",1V l J °sWt. RS CAS# 100.00 Waste Oil, Petroleum Based No 0 t1AGHxL A55t;551~1t51v 1 a TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCA' No No No No/ Curies F DH / / / Lc7w ~ Inventory Item 0003 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME CARBON DIOXIDE Days On Site 365 Location within this Facility Unit Map: Grid: BET E & W BLDG N SIDE CAS# 124-38-9 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas TPure ~-Above Ambient Ambient FIXED PRESS. CYLINDER,,,..,,,.,. AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 420333.00 FT3 420333.00 FT3 242500.00 FT3 _ ns~ac~tcl~VUa ~.V1~irVlvl;lvl~ %Wt. RS CAS# 100.00 Carbon Dioxide No 124389 I11~GKtCL HJJL~.7J1~1L"1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# M~1 No No No No/ Curies F P IH / / / Miff -10- 01/29/2007 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ ~ ~ Inventory Item 0007 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME CITRIC ACID ANHYDROUS Days On Site 365 Location within this Facility Unit Map: Grid: BATCH AREA W BLDG CAS# 77-92-9 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Solid TMixture Ambient ~ Ambient BAG AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 50.00 LBS 10000.00 LBS 4000.00 LBS - ru~~tucL~u~ ~~l~ir~iv~ivla %Wt. RS CAS# 100.00 Citric Acid No 77929 riAGAtClJ 1~.~Ji5~~1~11'~1V 1 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / M:1i ~ Inventory Item 0002 COMMON NAME / CHEMICAL NAME HOT MELT ADHESIVE Location within this Facility Unit PACKING AREA S BLDG Facility Unit: Fixed Containers on Site ~ Map: Grid: STATE T TYPE ~~ PRESSURE Solid I Mixture I Ambient Days, On Site 365 CAS# 92717 TEMPERATURE CONTAINER TYPE _ Ambient BOX AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 50.00 LBS 800.00 LBS 400.00 LBS nric~tucl~vu~ ~.ulnrulvl,lvl~ oWt. RS CAS# 100.00 PPO No 92717 t11~G1~KL E~~51;J.71~1L"1V1~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Mi -11- O1/29/2b07 F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ ~ ~ Inventory Item 0025 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME ASCORBIC ACID Days On Site 365 Location within this Facility Unit Map: Grid: -- W SIDE OF W BLDG BATCH AREA CAS# 50-81-7 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE _ Solid TMixture ~ Ambient ~ Ambient DRUM/BARREL-NONMETAL AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 LBS 300.00 LBS 175.00 LBS ruiar~t~LVUJ ~.urlru1V1J1V t ~ %Wt. RS CAS# 100.00 Ascorbic Acid No 50817 r1.FiGtiiCL tiA J1:..7J1"1~1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCA No No No No/ Curies F R IH DH / / / M~1 ~ Inventory Item 0006 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME ARGON WELDER Days On Site 365 Location within this Facility Unit Map: Grid: --- SHOP STORAGE AREA E BLDG CAS# 7440-37-1 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas TPure -Above Ambient Ambient PORT. PRESS. CYLINDER.......".. AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 155.00 FT3 155.00 FT3 75.00 FT3 iicauruu.~vuJ \.V1•lrV1VJJ1VIJ °sWt. RS CAS# 100.00 Argon No 744071 rlti[~tiICL liJ ~J r,J.71~1L~1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCA No No No No/ Curies F P IH / / / M1i -12- Ol/29/~007 ;~ F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141 ~ ~ Inventory Item 0013 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME NITROGEN Days On Site 365 Location within this Facility Unit Map: Grid: ----- W BLDG SW CRNR BATCH AREA CAS# 7727-37-9 ~GasATE TPureE ~-AboveSAmbEent AmbPeRATURE PORTCOPRESSERCYLINDER~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 142.00 FT3 142.00 FT3 70.00 FT3 - HAZARDOUS COMPONENTS %Wt. RS CAS# 100.00 Nitrogen No 77273'79 lltiGtiiCL ti. 7~7L„7~71•1P.,1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# M~1 No No No No/ Curies F P IH / / / M11 ~ Inventory Item 0031 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME PROPYLENE GLYCOL FOOD GRADE Days On Site 365 Location within this Facility Unit Map: Grid: ENGR AREA SE CRNR W BLDG CAS# 57-55-06 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixture ~ Ambient ~ Ambient IN MACHINE/EQUIP Largest Container 2500.00 GAL AMOUNTS AT THIS LOCATION Daily Maximum 2500.00 GAL Daily Average 2500.00 GAL oWt izrac~rucLV~J L.V1.1rV1V riv 1.7 . RS CAS# Propylene Glycol No 57556 nr~c~ru~L s-~a ar~~~i~~alvt5 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MC1~ No No No No/ Curies F / / / U -13- O1/29/~007 ~~ ,~ F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ ~ Fast Format ~ ~ Notif./Evacuation/Medical Overall Site ~ ~ Agency Notification 10/05/20170 ~ CALL 911 AND THE STATE OFFICE OF EMERGENCY SERVICES WILL ALSO BE NOTIFIED AS REQUIRED. Employee Notif./Evacuation 10/26/2006 IN CASE OF A HAZARDOUS MATERIAL. SPILL, THE PLANT MANAGER, UPON NOTIFICATION, WILL USE THE PAGING SYSTEM TO NOTIFY ALL EMPLOYEES TO EVACUATE THE FACILITY: EACH SUPERVISOR IS TO DIRECT THE EMPLOYEES IN HIS AREA TO THE SAFEST EXIT AND MAKE SURE THAT HIS AREA HAS BEEN VACATED BY ALL PERSONNEL. ALL EMPLOYEES EVACUATED WILL REPORT TO A DESIGNATED AREA OUTSIDE THE FACILITY. AFTFR.NORMAL HOURS NOTIFY THE FOLLOWING IN THIS ORDER: _ BOB HOFFERD 903-0049 IF HE CANNOT BE REACHED, CALL DAVID WRIGHT 431-2403'• IF HE CANNOT BE REACHED, CALL DEE SECARP,'808=7686, IF SHE CANNOT bE REACHED, CALL ARMANI7t0 RAYO 324-1156. CALL ARMANDO RAYO IN THE EVENT OF ANY AMMONIA LEAK. Public Notif./Evacuation 10/26/201)6 DURING A RELEASE, THE PLANT ENGINEER (MAINTENANCE MANAGER) WILL: STOP LEAKS, IF POSSIBLE, AND SUPERVISE THE USE OF SELF-CONTAINED BREATHING APPARATUS (SCBA). -14- 01/29/2007 ~: F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ _ Fast Format ~ Notif./Evacuation/Medical Overall Site ~ Emergency Medical Plan 10/26/200)5 ,~T nv errpRR_VI-SOR WILL _ T'" '"D a INE_ D IN, CPR_ _ _AND FIRST AID . FOR MINOR INJURIES VERNON ~SORENSON' MD --~- WILL BE USED. FOR SERIOUS INJURY C7R INJURY DUE TO HAZARDOUS MATERIAL, THE NEAREST HOSPITAL EMERGENCY ROOM WILL BE USED, AT THE DISCRETION OF AMBULANCE SERVICE. 9 -15- Ol/29/~007 <' F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall Sits ~ ~ Release Prevention 10/05/2000 ~ TO PREVENT THE RELEASE OR SPILL OF HAZARDOUS MATERIAL AT THIS FACILITY, ONLY INDIVIDUALS REQUIRED TO USE HAZARDOUS MATERIALS IN THE COURSE OF THEIR WORK WILL BE ALLOWED TO HANDLE THEM. EACH OF THESE INDIVIDUALS WILL BE TRAINED IN THE SAFE HANDLING AND USE PROCEDURES FOR EACH PRODUCT. Release Containment 10/26/2006 PROCEDURES FOR CONTAINMENT WILL BE THOSE RECOMMENDED BY THE MANUFACTURER OF THE PRODUCT AS DESCRIBED IN THE MATERIAL SAFETY DATA SHEET. AMMONIA DIFFUSION SYSTEM LOCATED BETWEEN BUILDINGS, INSIDE CONTAINMENT WALL: IMPLEMENTATION OF SPILL PREVENTION AND CONTAINMENT PROGRAM DEVELOPED SPILL KITS LOCATED AT STRATEGIC AREAS FOR QUICK RESPONSE TO CHEMICAL SPILLS Clean Up 04/07/2005 PROCEDURES FOR CLEAN-UP WILL BE THOSE RECOMMEDED BY THE MANUFACTURER OF THE PRODUCT AS DESCRIBED IN THE MATERIAL SAFETY DATA SHEET. V1~11C1 1CC .7Vl.Li L:C til,:L1VCLL1V11 -16- 01/29/2007 .; F CR3YSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141:$ ~ Fast Format ~ ~ Site Emergency Factors Overall Sites ~ Special riazaras Utility Shut-Offs O1/29/20C1'7 A) GAS - MAIN SHUT-OFF INSIDE FENCE NEXT TO ALLEY BET E & W BLDG 300FT E 01 ROBINSON ST B) ELECTRICAL - INSIDE SW CRNR OF E BLDG BOTH SIDES OF EXIT DOOR MAIN TRANSFORMER BET E BLDG C) WATER - ALLEY NEXT TO FENCE & SW CRNR OF W BLDG (DEPT HOOK-UP & AMMONIA DUMP SYSTEM VALVE CONTROL BOX OUTSIDE BLDG NEXT TO ALLEY) D) SPECIAL - NONE E) LOCK BOX - YES CALIFORNIA AVE OVER MAIN ENTR Fire Protec./Avail. Water 01/29/2007 PRIVATE FIRE PROTECTION -.AUTOMATIC OVERHEAD SPRINKLERS MONITORED BY TEL-TEC SECURITY SYSTEMS AND FIRE EXTINGUISHERS. FIRE HYDRANT - N SIDE OF E CALIFORNIA AVE, 120FT W OF NW CRNR OF SITE. FIRE DEPT HOOK-UP TO MAIN SPRINKER SYSTEM RISER EXISTS IN ALLEY, 220FT W O' LAKEVIEW AVE. FIRE DEPT HOOK-UP FOR W BLDG 350FT E OF ROBINSON ST IN ALLEY: Building Occupancy Level 04/07/2006 32 EMPLOYEES -17- Ol/29/~007 :~ F CRYSTAL GEYSER OF BAKERSFIELD ,,, SiteID: 015-021-001418 ~ Fast Format ~ Training Overall Sits ~ -18- Ol/29/~007 •. F ~, F C~2YTSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ Fast Format ~ Training Overall Site ~ Employee Training Ol/29/20f17 MATERIAL SAFETY DATA SHEETS ON FILE. BRIEF SUMMARY OF TRAINING PROGRAM: INCLUDES A LIST OF THOSE QUALIFIED IN S.C.B.A. EACH EMPLOYEE INVOLVED IN THE USE OF HAZARDOUS MATERIALS WILL BE GIVEN INSTRUCTION IN THE SAFE HANDLING AND USE OF EACH PRODUCT BEFORE THEY BEGIN USE. EACH EMPLOYEE WILL BE PROVIDED WITH SAFETY EQUIPMENT REQUIRED FOR EAC~i PRODUCT HANDLED. SAFETY PROCEDURES FOR SPILL CLEAN-UP OF HAZARDOUS MATERIALS WILL BE TAUGHT. NEW HAZARDOUS MATERIALS INTRODUCED INTO INVENT012Y WILL BE REVIEWED WITH EACH INDIVIDUAL BEFORE USE. REFRESHER COURSES IN SAFE HANDLING OF HAZARDOUS MATERIAL WILL BE REQUIRED OF EACH EMPLOYEE INVOLVED I1:~T THE USE OR HANDLING DURING THE YEAR. IN ACCORDANCE WITH YOUR REQUEST, WE SUBMIT THE FOLLOWING LIST OF INDIVIDUALS WHO HAVE BEEN TRAINED TO INITIATE AN EMERGENCY RESPONSE TO AN UNLIKELY INCIDENT. 1) ARMANDO RAYO, MAINTENANCE , ARMANDO IS IN TRAINING AND IS GETTING EXPERIENCE IN ALL ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT-OFF VALVES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES AND HAS BEEN TRAINED IN THE USE OF OUR AMMONIA DIFFUSION SYSTEM. ALSO, ARMANDO HAS BEES TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. 2) ROBERT HOFFERD, SHIPPING/SAFETY SUPERVISOR ROBERT HAS BEEN TRAINED AND IS EXPERIENCED IN MOST ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT-OFF VALVES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES, AND BEING TRAINED IN THE USE OF OUR AMMONIA DIFFUSION SYSTEM. ALSO, ROBERT HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ALBE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. 3) RICHARD WEKLYCH, PLANT MANAGER RICHARD HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY ACCIDENT. 4) CHARLES WRIGHT, MAINTENANCE MECHANIC CHARLES IS IN TRAINING AND IS GETTING EXPERIENCE IN ALL ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT-OFF VALVES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA-SAFE HANDLING PRACTICES BEING TRAINED IN THE USE OF OUR AMMONIA DIFFUSION SYSTEMS. ALSO, CHARLES HAS BEEN TRAINED I1~ THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AI~I EMERGENCY RESPONSE TO ANY INCIDENT. -19- 01/29/2007 ~' 'b ~ ~ F CRYSTAL GEYSER OF BAKERSFIELD SiteID: 015-021-00141$ ~ Fast Format ~ ~ Training Overall Sites ~ ~ Page 2 04/07/2005 ~ 5) DAVID WRIGHT - PRODUCTION MANAGER AND MAINTENANCE MANAGER DAVID IS IN TRAINING AND IS GETTING EXPERIENCE IN MOST ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT-OFF VALVES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES AND BEING TRAINED IN THE USE OF OUR AMMONIA DIFUSION SYSTEM. 6) HARRY BARBA - QUALITY CONTROL TECH HARRY HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSCJ KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. ALL PLANT MANAGEMENT, MAINTENANCE PERSONNEL AND OTHER EMPLOYEES WHO WORK WITH LITTLE SUPERVISION WILL BE TRAINED IN FIRST AID AND CPR. n~iu Lc~r r uuure u~~ MIKE ROBERTSON QC MANAGER n~iu ic~i r uuure use -20- of/29/zoo? ~ .: T ~- Material Safety Data Sheet ;r~ ' ~'`~. ^\ ~,/ , r ~ ~ ~ ~°._~:~~ Erecting brans, suppartir.g brands. ~ 178256 NATURAL APPLE FLAVOR Version 1 Revision Date 03 24 2006 Print Date 03 27 2006 1. PRODUCT AND COMPANY IDENTIFICATION Product name NATURAL APPLE FLAVOR Product code 178256 Company Symrise ,Inc. 300 North Street Teterboro, NJ 07608 For information call 800-422-1559 or evenings, call: 973-256-2930 Emergency Phone Number Chemtrec 1-800-424-9300 or 1-703-527-3887 The emergency contact should only be used in the event of chemical emergencies involving a spill; leak, fire exposure or accident involving chemicals. 2. HAZARDS IDENTIFICATION The following evalutation is in compl iance with 29 CFR 1910.1200. This evaluation relates to individual ingredients in this product which are required for consideration. The induced or observed effect results are for single concentrated materials under experimental or prolonged exposure. We consider the identity of the ingredient(s) to be a trade secret. . Emergency Overview This product is liquid Water solubility completely miscible Odour characteristic Flash point 109 °F / 43 °C Flammability (DOT173) Flammable Liquid Flammability (OSHA) Combustible Liquid OSHA PHYSICAL HAZARD None. (OTHER): Acute Health Hazard Eyes Moderate eye irritant Skin Moderate skin irritant Inhalation Moderate Inhalation Irritant LD50 Oral Not Toxic LD50 Dermal Not Toxic LC50 Inhalation Not Toxic Chronic Health Hazard: 1 /6 4 Material' Safety Data Sheet ,~`~' ~''; sym.rie ~;f cr~acmg brands, s:uppurtirsg k~rands, 178256 NATURAL APPLE FLAVOR Version 1 Revision Date 03 24 2006 Print Date 03 27 2006 This mixture has not been found to contain materials that are considered to be carcinogenic per NTP. This mixture has not been found to contain materials that are considered to be carcinogenic per IARC. This mixture has not been found to contain materials that are considered to be carcinogenic per OSHA. Skin Based on Human Evidence Target Organs; various Symptoms of Overexposure: Severe III Effects Ingestion Based on Human Evidence Target Organs: Central nervous system, Gastrointestinal tract, Kidney, Liver, Reproductive System, various Symptoms of Overexposure: Neurological disorders, gastrointestinal disturbance, Kidney disorders, Liver disorders, Reproductive Effects, Severe III Effects Ingestion Based on Animal Evidence Target Organs: Gastrointestinal tract, Central nervous system Symptoms of Overexposure: gastrointestinal disturbance, Neurological disorders Inhalation Based on Human Evidence Target Organs: various Symptoms of Overexposure: Anesthetic Effects Inhalation Based on Animal Evidence Target Organs: various Symptoms of Overexposure: Anesthetic Effects This product must be used at ambient temperature. We do not recommend heating this product. However, if during handling or processing, heating is required, then appropriate respiratory protection must be provided i addition to the engineering controls through ventilation. We recommend consulting with a certified Industrial hygienist for appropriate action for the worker safety. 3. COMPOSITION/INFORMATION ON INGREDIENTS Product Type Mixture of Flavor Materials. 4. FIRST AID MEASURES Emergency and First Aid Procedures: Eye contact Irrigate thoroughly with plenty of water until discomfort is relieved. Consult a physician for proper medical care. Skin contact Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. Tf symptoms persist, call a physician. Inhalation If signs of dizziness and/or nausea occur, then remove the person immediately to fresh outside air. Ingestion If accidentally swallowed obtain immediate medical attention. 2/6 Material Safety Data Sheet ~- ~ '_~, crex€ing brsn~s, supparting brsnds. 178256 NATURAL APPLE FLAVOR Version 1 Revision Date 03 24 2006 Print Date 03 27 2006 5. FIRE-FIGHTING MEASURES Flash point 109 °F / 43 °C HMIS Rating Health: 2 0 =Insignificant Flammability: 2 1 =Slight Reactivity: 0 2 =Moderate 3 =Serious 4 =Severe. NFPA Classification Class II Flammability (OSHA) Combustible Liquid Suitable extinguishing media dry chemical carbon dioxide (C02) Unsuitable media Water may be ineffective. Special protective equipment Follow North American Emergency Guidebook 127. and precautions for fire- fighters Specific hazards arising from None. the chemical 6. ACCIDENTAL RELEASE MEASURES This product is liquid Water solubility completely miscible Odour characteristic Methods for cleaning up Cover with an inert absorbent material and remove to a disposal container. Mop up and then wash with soapy water. Disposal Considerations Dispose of in accordance with local regulations. Observe local, state and federal regulations. Incineration is the most recommended disposal method. Based on the UN Number Classifica tion, any spill or leak or file control procedure should follow the emergenc response guidebook (ERG) Guideline Number 127. 7. HANDLING AND STORAGE - Use only in well-ventilated areas. Handle in accordance with good industrial hygiene and safety practice. For industrial use only. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and flame. Flammability (OSHA) Combustible Liquid OSHA'PHYSICAL HAZARD None. (OTHER) 3/6 Material, Safety Data Sheet f~~, ~ ~ ,,~;, ; ~ ~ ~.: syr~r~~e craxtin~ Crsnds,support g brands. 178256 NATURAL APPLE FLAVOR Version 1 Revision Date 03 24 2006 Print Date 03 27 2006 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Exposure Guidelines Although this trade secret mixture has not been tested for its exposure risks and no PEL/TWA/TLV has been developed, it contains ingredients which when present, have the following values for PEL/TWA/TLV. Type Value PEL 1,000 ppm 1,900 mg/m3 TWA 1,000 ppm 1,900 mg/m3 REL 1,000 ppm 1,900 mg/m3 TWA 1,000 ppm We recommend maximum achievable PEL/TWA/TLV by means of appropriate engineering controls. PPE as required must be provided to workers for protection. Respiratory protection Respirator with filter for organic vapour Ventilation protection Ensure adequate ventilation. Eye protection Chemical resistant goggles must be worn. Hand protection Wear suitable gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Form liquid Odour characteristic Flash point 109 °F / 43 °C Water solubility completely miscible 10. STABILITY AND REACTIVITY Chemical Stability Stable Possibility of Hazardous Will Not Occur reactions Conditions to avoid .` None. Materials to avoid None. Hazardous decomposition None. products 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Please refer to section 2 for toxicological information. Acute dermal toxicity Please refer to section 2 for toxicological information. Acute inhalation toxicity Please refer to section 2 for toxicological information. 4/6 Material Safety Data Sheet ,~'~, crsaung brsnds, su{~~urt~ag Frauds. 178256 NATURAL APPLE FLAVOR Version 1 Revision Date 03 24 2006 Print Date 03 27 2006 12. ECOLOGICAL INFORMATION There is currently no ecological information available at this time. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local regulations. Observe, local, state and federal regulations. Incineration is the most recommended disposal method. 14. TRANSPORT INFORMATION 49CFR Road - Not classified as dangerous in the meaning of transport regulations. IMDG UN Number 119.7 Description of the goods UN 1197 EXTRACTS, FLAVOURING, LIQUID ,3,PGIII,IMDG Class 3 Packaging group III ADR/RID-Labels _ 3 EmS Number 1 F-E EmS Number 2 S-D IATA-DGR UN Number 1197 Description of the goods Extracts, flavouring, liquid Class 3 Packaging group III Cargo \ Packing Instruction 310 Qty /Pkg. 220.00 L Passenger\Packing Instruction 309 Qty /Pkg. 60:00 L 15. REGULATORY INFORMATION ' Toxic Substances Control Act (TSCA) Inventory Status This product is for FDA regulated product use only. SARA Title III Section 313 This product contains no chemicals subject to the reporting requirements of section 313 of SARA. US. EPA CERCLA Hazardous Substances (40 CFR 302) In accordance with SARA CERCLA 302.4 Regulations, if a re{ease occurs in a quantity equal to or 5/6 ~ ,. ' ;, . Material Safety Data Sheet `~~' ~-`~, ,. cre2<in~ bands, suppurt~ng brands. 178256 NATURAL APPLE FLAVOR Version 1 Revision Date 03 24 2006 Print Date 03 27 2006 exceeding the reportable quantity, notification must be immediately made to the National Response Center at 800-424-8802. A release is considered any spilling, leaking, pumping, pouring, emitting, emptying, discharging, escaping, dumping or disposing into the environment. CERCLA Reportable Quantity 472 Ibs California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects or any other harm. 16. OTHER INFORMATION Further information These safety guidelines are based on information obtained from reliable sources. Prudent use and handling as part of good manufacturing practices is advised. Employees must be trained to handle material safely and wear recommended P.P.E. This new MSDS was created to conform with OSHA hazard communication standard 29CFR 1910.1200. Please discard previous form. This MSDS was prepared by the .Regulatory Affairs Department. 6/6 ., '` _ t, .. symrise creating brantls. supporting brands Sender Symrise ,Inc. 300 North Street Teterboro, NJ 07608 Company CRYSTAL GEYSER WATER CO. 1233 E. CALIFORNIA BAKERSFIELD CA 93307 30429201 01 21-Apr-2006 PLEASE FORWARD THIS IMPORTANT SAFETY INFORMATION TO THE APPROPRIATE PERSONNEL RESPONSIBLE FOR. WORKPLACE SAFETY. Please find attached the Material Safety Data Sheets for the products listed below. The MSDSs have been formatted according to the ANSI standard. Discard all previous versions of the MSDS. Please do not hesitate to call our Regulatory Affairs Department at 800-422-1559 or evenings, call 973-256-2930 if you have any questions. , APPLE JUICE FLAVOR NAT. (FTNJ) Material Safety Data Sheet symrise creating brands, supporting brands. 301216 APPLE .7UICE FLAVOR NAT. (FTN.7) .. Version 1 Revision Date 12/29/2005 Print Date 04/21 2006 1. PRODUCT AND COMPANY IDENTIFICATION Product name APPLE JUICE FLAVOR NAT. (FTNJ) Product code 301216 Company ~ Symrise ,Inc. 300 North Street Teterboro, NJ 07608 For information call 800-422-1559 or evenings, call: 973-256-2930 Emergency Phone Number Chemtrec i-800-424-9300 or 1-703-527-3887 The emergency contact should only be used in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals. 2. HAZARDS IDENTIFICATION The following evalutation is in compl iance with 29 CFR 1910.1200. This evaluation relates to individual ingredients in this product which are required for consideration. The induced or observed effect results are for single concentrated materials under experimental or prolonged exposure. We consider the identity of the ingredient(s) to be a trade secret. Emergency Overview This product is clear liquid -colorless Water solubility immiscible ' Odour characteristic Flash point 84 °F / 29 °C Flammability (DOT173) Flammable Liquid Flammability (OSHA) Flammable Liquid OSHA PHYSICAL HAZARD None. (OTHER); Acute Health Hazard Eyes Moderate eye irritant Skin Moderate skin irritant Inhalation Moderate Inhalation Irritant LD50 Oral Not Toxic LD50 Dermal Not Toxic LCSO Inhalation Not Toxic Chronic Health Hazard: 1/6 Material Safety Data Sheet , . sym rise croa:ing brands. supporting trrands. 301216 APPLE )DICE FLAVOR NAT. (FTN7) Version 1 Revision Date 12/29 2005 Print Date 04 21/2006 This mixture has not been found to contain materials that are considered to be carcinogenic per NTP. This mixture has not been found to contain materials that are considered to be carcinogenic per IARC. This mixture has not been found to contain materials that are considered to be carcinogenic per OSHA. Skin Based on Human Evidence Target Organs: various Symptoms of Overexposure: Severe III Effects Ingestion Based on Human Evidence Target Organs: Reproductive System, Central nervous system, Liver, Kidney, various Symptoms of Overexposure: Reproductive Effects, Neurological disorders, Liver disorders, Kidney disorders, Severe III Effects Ingestion Based on Animal Evidence Target Organs: Gastrointestinal tract, Central nervous system Symptoms of Overexposure: gastrointestinal disturbance, Neurological disorders ,Inhalation Based on Human Evidence Target Organs: various Symptoms of Overexposure: Anesthetic Effects Inhalation Based on Animal Evidence Target Organs: various Symptoms of Overexposure: Anesthetic Effects 3. COMPOSITION/INFORMATION ON INGREDIENTS 4. FIRST AID MEASURES Emergency. and First Aid Procedures: Eye contact Irrigate thoroughly with plenty of water until discomfort is relieved. Consult a physician for proper medical care. Skin contact Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water. If symptoms persist, call a physician. Inhalation If signs of dizziness and/or nausea occur, then remove the person immediately to fresh outside air. Ingestion If accidentally swallowed obtain immediate medical attention. 5. FIRE-FIGHTING MEASURES Flash point 84 °F / 29 °C HMIS Rating Health: 2 0 =Insignificant Flammability: 3 1 =Slight 2/6 _ Material Safety Data Sheet sym~rise creating brands. supporting brands 301216 APPLE ]DICE FLAVOR NAT.. (FTN]) Version 1 Revision Date 12/29/2005 Print Date 04/21 2006 Reactivity: 0 2 =Moderate 3 =Serious 4 =Severe NFPA Classification Class IC Flammability (OSHA) Flammable Liquid Suitable extinguishing media dry chemical carbon dioxide (C02) Unsuitable media Water may be ineffective. Special protective equipment Follow North American Emergency Guidebook 127. and. precautions for fire- fighters Specific hazards arising from None. the chemical 6. ACCIDENTAL RELEASE MEASURES This product is clear liquid -colorless Water solubility immiscible Odour characteristic Methods for cleaning up Cover with an inert absorbent material and remove to a disposal container. Mop up and then wash with soapy water. Disposal Considerations Dispose of in accordance with local regulations. Observe local, state and federal regulations. Incineration~is the most recommended disposal method, Based on the UN Number Classification, any spill or leak or file control procedure should follow the emergenc response guidebook (ERG) Guideline Number 127. 7. HANDLING AND STORAGE . Use only in well-ventilated areas. Handle in accordance with good industrial hygiene and safety practice. For industrial use only. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and flame. Flammability (OSHA) Flammable Liquid OSHA PHYSICAL HAZARD None. (OTHER) 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Exposure Guidelines Although this trade secret mixture has not been tested for its exposure risks and no PEL/TWA/TLV has been developed, it contains ingredients which when present, have the following values for PEL/TWA/TLV. 3/6 ", Material Safety Data Sheet symrise creating brands, wppor[ing Crands. 301216 APPLE ]DICE FLAVOR NAT. (FTN]) Version 1 Revision Date 12/29 2005 Print Date 04/21/2006 Type Value PEC 1,000 ppm 1,900 mg/m3 TWA 1,000 ppm 1,900 mg/m3 REL 1,000 ppm 1,900 mg/m3 TWA 1,000 ppm We recommend maximum achievable PEL/TWA/TLV by means of appropriate engineering controls. PPE as required must be provided to workers for protection. Respiratory protection Respirator with filter for organic vapour Ventilation protection Ensure adequate ventilation. Eye protection Chemical resistant goggles must be worn. Hand protection Wear suitable gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Form clear liquid Color colorless Odour characteristic Flash point 84 °F / 29 °C Water solubility immiscible Specific Gravity (range) ca.0.9564 - 0.9764 at 68 °F / 20 °C Note: relation to density of water at 4°C 10. STABILITY AND REACTIVITY Chemical Stability Stable Possibility of Hazardous Will Not Occur reactions Conditions to avoid None. Materials to avoid None. Hazardous decomposition None. products 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Please refer to section 2 for toxicological information. Acute dermal toxicity Please refer to section 2 for toxicological information. Acute inhalation toxicity Please refer to section 2 for toxicological information. 4/6 3' Material Safety Data Sheet • sym rise creating brands. supFOrt+ng brands 301216 APPLE ]DICE FLAVOR NAT. (FTN]) Version 1 Revision Date 12/29 2005 Print Date 04/21 2006 12. ECOLOGICAL INFORMATION There is currently no ecological information available at this time. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local regulations. Observe, local, state and federal regulations. Incineration is the most recommended disposal method. 14. TRANSPORT INFORMATION 49CFR Road UN-No 1197 Description of the goods "Extracts, flavoring, liquid Class 3 Packaging group III IMDG UN Number 1197 Description of the goods UN 1197 EXTRACTS, FLAVOURING, LIQUID ,3,PGIII,IMDG Class 3 Packaging group III ADR/RID-Labels 3 EmS Number 1 F-E EmS Number 2 S-D IATA-DG R - UN Number : 1197 Description of the goods Extracts, flavouring, liquid Class 3 Packaging group III Cargo \ Packing Instruction 310 Qty /Pkg. 220.00 L Passenger\Packing Instruction 309 Qty /Pkg. 60.00 L ~. 15. REGULATORY INFORMATION Toxic Substances Control Act (TSCA) inventory Status All components of this trade secret mixture are on TSCA Inventory. This product does not contain any TSCA export notifiable ingredients. SARA Title IiI Section 313 This product contains no chemicals subject to the reporting requirements of section 313 of SARA. 5/6 Material Safety Data Sheet sym rise creasing brands. supporting brands. 301216 APPLE 7UICE FLAVOR NAT. (FTN~) Version 1 Revision Date 12 29 2005 Print Date 04 21 2006 US. EPA CERCLA Hazardous Substances (40 CFR 302) In accordance with SARA CERCLA 302.4 Regulations, if a release occurs in a quantity equal to or exceeding the reportable quantity, notification must be immediately made to the National Response Center at 800-424-8802. A release is considered any spilling, leaking, pumping, pouring, emitting, emptying, discharging, escaping, dumping or disposing into the environment. CERCLA Reportable Quantity 349 Ibs California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer; birth defects or any other harm. 16. OTHER INFORMATION Further information These safety guidelines are based on information obtained from reliable sources. Prudent use and handling as part of good manufacturing practices is advised. Employees must be trained to handle material safely and wear recommended P.P.E. This new MSDS was created to conform with OSHA hazard communication standard 29CFR 1910.1200. Please discard previous form. This MSDS was prepared by the Regulatory Affairs Department. 6/6 International Flavors and Fragrances (~ OSHA Material Safety Data Sheet 800 Rose Lane Hazard Ratin¢ O=Least Union Beach,N.J.07735 Health 1 1=Slight Fire 1 2=Moderate For Emergency call CHEMTREC(800)424-9300 Reactivity 0 3=High For Information call IFF {732)264-4500 4=Extreme IFF MATERIAL SAFETY DATA SHEET for ....13571674 NATURAL GRAPEFRUIT WONF IFF Product Code ......................................... N. AP. Prepared For ..:............................................ CRYSTAL GEYSER WATER CO-BAKERSFIELD Customer Product # ......................................250813 II SECTION 1-Product Identification it Product Identifier ..........................:..............13571674 NATURAL GRAPEFRUIT WONF SECTION 2 -Hazardous HAZARDOUS INGREDIENTS . OSHA PEL ACGIH TLV ACETALDEHYDE 200 PPM 100 PPM. The specific chemical identities of the remaining ingredients of this mixture are considered by IFF to be Trade Secrets and are withheld in accordance with the provisions of 1910.1200 of Title 29 of the Code of Federal Regulations. ~~ SECTION 3 -Physical Data ~~ Boiling Point (Deg C) ....................................N. AV. Vapor Pressure (mm Hg) .............................. N. AV. Evaporation Rate .................N. AV. Melting Point (Deg C) .................................:. N. AP. Vapor Density (Air=1) ......... > 1 Solubility in Water ................:.......................N. AV. Specific Gravity ...................1.0.5 Odor Threshold ........:.:.................................N: AV. Percent Volatile Q 70 Deg. F..N. AV. Odor and A arance ....................................Flavorin Li uid SECTION 4 -Fire and Explosion Hazards Flashpoint (Deg. F) and Method .......................212 TCC Upper Flammable Limit (% by Volume) ............N. AV. Lower Flammable Limit (% by Volume)............N. AV. Extinguishing Media ...........:...................:......Carbon Dioxide, dry chemical, foam, or water. Hazardous Combustion Products ..................... Carbon Monoxide and unidentified organic compounds. Special Fire Fighting Procedures ...................... Self-contained breathing apparatus and protective clothing should be worn when fighting fires involving chemicals. Unusual Fire and Explosion Hazards .................None known to IFF. ~~ SECTION 5 -Reactivity Data ~~ Chemically Stable ......................................... ~ YES ~ If no, under which conditions? > N. AP Incompatibility with other substances ................ (NO (If so, which ones? > N. AP Reactivity, and under what conditions ...............This product presents no significant reactivity hazard. It is stable and will not reaM violently with water. Hazardous polymerization will not occur. Avoid contact or contamination with strong acids, alkalis, or oxidizing agents. ` Hazardous Decomposition Products ..............:...N. AV. SECTION 6 - Route of Entry ............................................. Skin Contact ~ X ~ Skin Absorption ~ ~ Eye Contact ~ X ~ Inhalation ~ X I Ingestion ~ x~ Exposure Limits ...........................................N. AV. This mixture has not been tested as a whole. It contains ingredients present at concentrations that exceed OSHA thresholds that undiluted and at ambient conditions could have the following health hazards. EFFECTS OF ACUTE EXPOSURE TO PRODUCT May be irritating to skin anti eyes. Irritating to respiratory system. Repeated contact may cause allergic skin reaction. EFFECTS OF CHROMC EXPOSURE TO PRODUCT Acetaldehyde has been reported to cause nasal tumors in rats at exposure levels well above the"irritation threshold and is listed as an experimental carcinogen by IARC. There is no evidence of carcinogenicity in humans. Acetaldehyde is a normal human metabolite and occurs naturally in the body in small amounts. It has been evaluated by the FDA and FEMA and determined to be GRAS for its intended use in food products in the U.S. Note: N.AV. =Information is Not Available; N.AP. =Information is Not Applicable Page <1> of <2> IFF Material Safety Data Sheet For 13571674 NATURAL GRAPEFRUIT WONF Customer Product f/: 250813 ~~ ~ SECTION 7 -Preventive Measures ~~ PERSONAL PROTECTIVE EQUIPMENT Respiratory Protection .......................:...........None generally required. If desired use NIOSH approved respirator. Ventilation .:................................................Local exhaust meeting ACGIH criteria as needed. Protective Gloves ..........................................Use chemical resistant gloves as needed to avoid prolonged or repeated contact. Eye Protection .....:.......................................Use goggles or face shield when eye contact might occur. OTHER PREVENTIVE MEASURES Leak and Spill Procedures ..............................Eliminate all ignition sources. Ventilate area. Contain spill and recover free product. Absorb remainder on vermiculite or other suitable absorbent material. Use of self-contained breathing apparatus is recommended for any major chemical spill. Report spill to appropriate authorities if required. Waste Disposal .............................................Place material and absorbent into sealed containers and dispose of in accordance with current applicable laws and regulations. Handling Procedures .....................................Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at the end of the work period..Contaminated clothing and shoes should be cleaned before re-use. Good manufacturing practices dictate that an eyewash fountain and/or safety shower should be available in the work area. Storage Requirements .........................:..........Store in a cool, dry, ventilated area away from any heat sources. Keep containers tightly closed and upright when not in use. SECTION 8 -First Aid Procedures Inhalation ...................................................Remove from the exposure to fresh air. Contact a physician as necessary. If breathing is irregular or has stopped start resuscitation, administer oxygen, if available. Eye Contact .................................................Flush immediately with clean water for at least 15 minutes. Contact a physician if irritation persists. Skin Contact .............................:..................Remove any contaminated clothing or shoes. Wash affected areas thoroughly with soap and water. If irritation persists, contact a physician. Ingestion .....................................................Give water to dilute. Contact a physician immediately. SECTION 9 -SARA Title III Data SECTION 312 HAZARD CATAGORIES Fire ~ ~ Sudden Release of Pressure ~ ~ Reactivity ~ ~ Immediate (Acute) ~~ X ~ Delayed (Chronic) ~ X ~ SECTION 313 TOXIC CHEMICAL NOTIFICATION This proprietary material contains the following toxic chemical(s) subject to the reporting requirements of Section 313 of Title HI of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: Generic Chemical Name Concentration (% by weight) ALDEHYDES ......................................... NOT MORE THAN 10% SECTION 10 -Preparation Date of MSDS ~ - Prepared by .................................................IFF Occupational Health & Safety Dept. For Information Call IFF ............................... (732) 264-4500 Date ..................................3/25/99 Disclaimer The information in this MSDS was obtained from current and reliable sources. However the. data is provided. without any warranty, expressed or implied, regarding its correctness or zccuracy. Since the conditions for use, handling, storage and disposal ofthis product are beyond IFF control, it is the responsibility of the user both to determine safe conditions for use of this product and to assume liability for loss, damage, or expense arising out of the product's improper use. No warranty expressed or implied regarding the product described herein shall be created by or inferred from any statement or omission in this MSDS. Various Federal, State or Provincial agencies may have specific regulations concerning the transportation, handling, storage, use,or disposal of this product which may not be reflected in this MSDS. The user should review these regulations to ensure full compliance. Page <2> of <2> Feb•22. 2006 1:36PM CLARENDON FLAVOR ENGINEERING No,6050 P• 2 ~~ MATERIAL SAFETY DATA SHEET 29 C.F.R. & 1900.1200 Date of preparation: February 28, 1989 z . Identity used on label (chemical and common name(s): LEMON EXTRACT C-311 II . Physical and chemical characteristics: _ Boiling point (degrees F} ................................. N/A Vapor pressure (mmHg.) (100mm) ................... N/A Vapor density (AIR - 1) ................................ . N/A Solubility in water .......................................... complete Specific gravity (H20 = 1.0) .................... ..... 0.896 +/-0.01 g/ml Percent, volatile by volume .....:......................... 100% Appearance & Aroma: A pale yellow liquid having a characteristic odor of lemon ITI. Physical hazards: * Flashpoints .........................................:......... 72°F Flammable limits ........................................... N/A Extinguishing media: Water, C02, alcohol foam, dry chemical Iv. Health hazards: Effects of overexposure: mild eye and nose irritation, headache, drowsiness, tremors, fatigue, dizziness, anorexia, nausea, narcosis, and mental confusion. reb.12. 2006 1;37PM CLARENDON FLAVOR ENGINEERING No.6050 P. 1 V. Primary route of entry; ~r Inhalation, skin-topical, and splashing in eye., VI. ~ a. OSHA permissible exposure limit: Inhalation 1000 parts per million, ' 8 hour time weighted average b. ACGIH threshold limit value: Inhalation 1000 parts per million, 8.hour time weighted average VII. Spill or teak procedures: • ~ Wash with water to sewer in accordance with focal statutes. VIII. Precautions for safe handling and use: a: Proper ventilation b. No smoking c. No flames or sparks IX. Reac#ivity data: Stabili ty .................................. stable Incompatibility (material to avoid; none known Hazardous decomposition produ none known Hazardous polymerization........, will not occur X: Emergency first aid procedures: a. Eye contact: irrigate with water b. Skin contact: flush with water c. Inhalation (excessive): immediate medical care d. Ingestion: immediate medical care XI. Name, address and telephone number of manufacturer: Clarendon Flavor Engineering 3300 Seventh Street Road Louisville, icY 40216 Phone (502) 634-9215 Fax (502) 634-1438 Page2of2 ~ International Flavors and Fragrances (1FF) OSHA Material Safety Data Sheet I5t5_Hwy 36 hazard Refine O=.Least ' ~-• Unior._Beach, :"x.7. 07735 Health I 1=Slight ;~`• Fire 3 2=Moderate For Emergency call CHEMTREC(80d)424-9300 Reactivity 0 3=High Por Information call IFF (908)264-4500 4=Extreme [FF MATERIAL SAFETY DATA SHEET for ....73566310 LEMON WONF EXTRACT ' ~ IFF Product Code .........................................73566310 . Prepared For ..........................:....................CRYSTAL GEYSER WATER CU II SECTION 1-Product Identification II SECTION 2 -Hazardous INGREDIENTS OSHA PEL ACGIII TLV . The specific chemical identities of We ingretlieafs of this mixture are considered by 1FF to be Trade Secrets and are withheld in accordance wiW We provisions of 1910.1200 of Titie 29 of the Code of Federal Regulations. fl SECTION 3 - Physical Data h Boilieb Poi>;t (Deg C) ....................................N, Al'. Vapor Pressure (mm IIg) ...............................N. AV. Melting Point (Deg C) ................................... N. AP. SolubiL'ty in Water ........................................N. AV. Odor Threshold ............................................N. AV. Evaporation Rate .................N. AV. Vapor llensity (Air=1).........> 1 Specific Gravity ...................0.88 Percent Volatile ®70 Deg. F..N. AV. ~~ SECTION 4 -Fire and Explosion Hazards ~~ Flammnble. Dond and grnw~d all containers. Flashpoint (Ueg. F) and McWod .......................60 TCC Upper Flammable Limit (% by Volume) ............N. AV. , Lower Flammable Limit (96 by Volume)............N. AV. Extingtdshing Media ......................................Carbon Dioxide, dry cLemical, or foam. ,,. hazardous Combustion Producfs ..................... Carbon Monoxide artd nuidmtified organic compowtds. Special I~rre Fighting Procedures ................:.....Sal!-contained breallwrg apparatus and protective clothing should be wont when fig66ng Cues involving chemicals. II SECTION 5 -Reactivity Data - II Chemically Stable ..........................:.............. ~ YFSj If no, under which conditions? > N. AI' Incompatibility witit other substances ................ ~ NOS If so, which ones? > N. AP Reactivity, and under what conditions ...............This product presents no significant reactivity hazard. It is stable and will not react violetttiy with water. Ilazardons polymerization will not occur. Avoid contact or contamination with strong acids, alkalis, or oxidizing agents. llazardaas Decomuosition Praducts ..................N, AV. SECTION 6 - T Route of Entry ............................................. Skin Contact' jXj Skin Ahsorptiiin ) ( Eye Contact jXj Inhalaion j R j bgestion j X j Exposure Limits ...........................................N. AV. This mixture bas not been tested as a whole. It contains ingredients present at concentrations that exceed OSIIA Wreshofds Wet undiluted and at ambient conditions could have We followurg hea1W hazards. EFFECTS OF ACUTE EXPOSURE TO PRODUCT May be irritating to skin, eyes, and respiratory system. May cause dermatitis after skin contact in sunlight. Repeated contact may cause allergic skin reaction. Inhalation may cause CNS effects, nausea, vomiting, headaches, artd diz~ness. EFFECTS OF ChRONIC EXPOSURE TO PRODUCT Chronic ingestion of excessive quantifies may cause liver damage. and reproductive effects, iucludutg fetal alcohol syndrome. These effects arc not likely to occur under occupational exposure conditions. Note: N.AV. =Information is Not Available; N.AP. =Information is Not Applicable Page • <1> of <2> - I ' ~ Material Safety llata Sheet For 73566310 LLl140N WONF EXTRACT Customer Product ~Y: 73566310 ,.~ . ~~' 1L - SECTION 7 -Preventive Measures PERSONAL PROTECTIVE EQUIPMENT ~ - Respiratory Protection .................................. . None generally required. If desired use NIOSIi approved respirator. Ventn~ation ................................................. . Local exhaust meeting ACGIIf criteria as needed. 'rotecUve Gloves............ ..... .Use chemical resistant gloves as needed to avoid prolonged or repealed contact. ... rye Protection ............................................ . Use goggles or face shield when eye contact might occur. OTIIER PREVENTIVE MEASURES Leak and Spi11 Procedures ..........:................. . Eliminate alI ignition sources. Ventilate area. Contain spill and recover tree product. Absorb remainder on vermiculite or other suitable absorbent material. Use of self-contained breaUung apparatus is recommended [or any mcSjor chemical spill. Report spill to appropriate authorities if required. Waste Disposal ............................................ .Place material and absorbent unto sealed containers and Dispose of in accordance with current applicable laws and regulations. Yandling Procedures .................................... . Avoid inhalation and contact with skin and eyes. Good personal hygiene practices should be used. Wash after any contact, before breaks and meals, and at We end of We work period. Contaminated clouting and shoes should be cleaned before ce-use. Good manufacturing practices dictate Wat as eyewash fountain and/or safety shower should be available in We work area. Storage Requirements ................................... .Store in a cool, dry, ventihtted area away from any heat sources. Keep containers tightly closed and ~ SECTION 8 -First Aid Procedures II Inhalation ...........................:.......................Remove from the exposure to fresh air. Contact a physician as necessary. If breatlwtg is irregular or • has stopped start resuscitation, adminisier oxygen, ii available. . Eye Contact .................................................Flash immediately with clean water for at least 15 mimtte;5. Contact a physician if irritation persists. Skin Contact ................................................Remove any contaminated clothing or shoes. Rash affected areas thoroughly with soap and water. If irritation persist., contact a physician. II SECTION 9 -SARA Title III Data II SECTION 312 IIAZARD CATAGORIES Fire IX~ . Sudden Release of Pressure ~ I Reactivity (~ Lnmediate (Acute) ~X~ llelayed (Chronic) ~X~ SECTION 313 TOXIC CIIEMICAL NOTIFICATION ~• This proprietary material contains We following toxic chemical(s) subject to We reporting requirements of Section 313 of Title III of We Superfuad '; lmendm~ts and Reauthorization Act of 1986 and 40 CFR Part 372: ` Geteric Chemical Name Concentration (% by weight) This prodoet does not contain say toxic chemccals ~~ SECTION 10 -Preparation Date of MSDS n - --------- Prepared by .................................................IFF Occupational IIea1W & Safety Dept. For Information Call IFF ............................... 908 264-4500 Date ..................................1/20/94 Disclaimer The information in this MSDS was obtained from current and reliable sources. However the data is provided without any warranty, expressed or implied, regarding its correctness or accuracy. Since We conditions for use, handling, storage and disposal ofthis product are beyond IFF control, it is the responsibility of the user both to determine safe conditions for use of thi4 product and to assume liahihly for lass, daruage, or expense arising out of the product's improper vse. No warranty expressed or implied regarding the pmduct described herein shall he created by or inferred from any slnlemeut or omission in this MSDS. Various Federal, State or Provincial ng~~cies may hove specific regulations concerning the tnutsporfalion, handling, storage, use,or disposal of U~is product which may not be reflected in this MSDS. The user should review these regulations to ensure full compliance. Page <2> of <2> ,, _ ~~~ ~' INTERNATIONAL FLAVORS & FRAGRANCES (IFF•R&D) 1515 H[GHWAY 36, UNJON BEACH, N.J. 07735 (908) 264.4500 CREATORS AND MANUFACTURERS OF FLAVORS, FRAGRANCES AND AROMA CHEMICALS CABLE: iNTEREFF NEW YORE; January 20, 1994 CRYSTAL GEYSER WATER CO 1233 E. CALIFORNIA AVE., BAKERSFIELD CA,93307 Dear Customer, Material Safety Data Slleet(s) for the IFF product(s) you recently ordered from us are enclosed. Please discard any existing MSDS(s) you may have for these products. This information is being provided to comply with the OSHA Hazard Communication Standard (29 CFR 1910.1200) and includes information needed to meet the requirements of the Superfund Amendment and Reauthorization Act(SARA). The issuance of this MSDS does not imply that any change has:been made in the product composition and does not represent a change in any prior safety assessnlenl furnished by II•T iu relation to the intended use of the producl. ' We urge you to make this information available as appropriate to your employees and any others witil wholll you arrange to handle tils (these) product(s). Please let us know if we can be of further assistance by calling (908) 264-4500 ext. 2516. Very truly yours, Occupational Health and Safety Department MSDS(s) enclosed: Description: _ IFF #: Cust. #: 73566310 LEMON WONT EXTRACT 73566310 73366310 ~eb.22~ 2006. 1~36PM CLARENDON FLAVOR ENGINEERING No~6050 P. 3 -~ <~`' t' ~ MATERIAL SAFETY DATA SHEET 29 C.F.R. & 1900.1200 Date of preparation: February 28, 1989 z . Identity used on label (chemical. and common name(s): LIME EXTRACT C-314 zi. Physical and chemical characteristics: Boiling point (degrees F) ............................. NJA Vapor pressure (mmHg.) (100mm) ...........:....... NIA Vapor density (AIR = 1) ...............................:.... N/A Solubility in water ... ................................... complete Specific gravity (H20 = 1.0) ............................. 0.916 +J-0.01gJml Percent, volatile by volume ............................... 100% Appearance & Aroma: ., A pate green liquid having a characteristic odor of lime zzz. Physical hazards: * Flashpoints ................ ........:...................... 73°F Flammable limits ........................................... N!A Extinguishing media: Water, C02, alcohol foam, dry chemical zv. Health hazards: Effects of overexposure: mild eye and nose irritation, headache, drowsiness, tremors, fatigue; dizziness, anorexia, nausea, narcosis, and mental confusion. reo.lt. zuuti ~~31NM CLARENDON FLAUOR ENGINEERING No.6050 P. 1 f, V. Primary route of entry: ~~ inhalation, skin-topical, bnd splashing in eye. VI. ~ a. OSHA permissible exposure limit: Inhaaatoor 1000 parts per million, . $ hour time weighted average b. ACG1H threshold limit value: lnhalatior 1000 parts -per million, 8.hour time weighted average VIl. Spill or leak procedures: Wash with water to sewer in accordance with local statutes. VIII. Precautions for safe handling and use: a. Proper ventilation b. No smoking c. No flames or sparks IX. Reactivity data: Stabi{ity ................................. stable Incompatibility (material to avoid; none known Hazardous decomposition produ none known Hazardous polymerization......... will not occur X. Emergency first aid procedures: a. Eye contac#: irrigate with water . . b. Skin contact: flush with water c. Inhalation (excessive): immediate medics( care . d. Ingestion: immediate medical care Xl. Name, address and telephone number of manufacturer: Clarendon Flavor Engineering 3300 Seventh Street Road Louisville, KY 4.0216 Phone (502) 634-9215 . Fax (502) 634-1438 Page 2 of 2 reb.'11. ZUU6 1~31i'M GLAKENDON FLAVOR ENGfNEERING r 'r J F~ ~ MATERIAL SAFETY DATA SHEET 29 C.F.R. ~ 1900.1200 Date of preparation: September 24, 2002 z. Identity used on label (chemical and common name(s): ORANGE EXTRACT C-3707 =s . Physical and chemical characteristics: No.6050. P. 5 Boiling point (degrees F) .............................. N/A Vapor pressure (mmHg.) (100mm) .................. N/A Vapor density (AIR = 1) ............................... N/A Solubility in water ....................................... complete Specific gravity (H20 = 1.0) ........................... 0.909 ± 0.01 g/ml .Percent, volatile by volume ......................... 100% Appearance & Aroma: CLEAR PALE ORANGE LIQUID WITH A MIXED CITRUS AROMA II2. Physical hazards: * Flashpoints ...................................... 73° F. Flammable limits .................................~.... N/A Extinguishing media: Water, C02, alcohol foam, dry chemical Iv. Health hazards: Effects of overexposure: mild eye and nose irritation, headache; drowsiness, tremors, fatigue, dizziness, anorexia, nausea, narcosis, and mental confusion. -__ - No ~ 6060 P.. 7 reu~cc~ cuuti ~;31NM CLARENflON FLAVOR ENGINEERING ~°" V. Primary route of entry: ~~ Inhalation, skin-topical, and splashing in eye. Vl. ~ a. OSHA permissible exposure limit: lnhalatior 1000 parts per million, .. ~ $ hour time weighted average b. ACGIH threshold limit value: lnhalatior 1000 parts per million, 8.hour time weighted average Vll. Spill or leak procedures: Wash with water to sewer in accordance with local statutes. Vf I1. Precautions for safe handling and use: a. Proper ventilation b. No smoking c. No flames or sparks IX. Reactivity data: Stability ................................. stable _ lncampatibility (material to avoid; none known Hazardous decomposition produ none known Hazardous polymerizat'~on......... will not occur X. Emergency first aid procedures: a. Eye contact: irrigate with water b. Skin contact: flush with water c. Inhalation (excessive): immediate medical care d. Ingestion: immediate medical care XI. Name, address and telephone number of manufacturer; Clarendon Flavor Engineering 3300 Seventh Street Road Louisville, KY 40216 Phone (502) 634-9215 Fax (502) 634-'1438 Page 2 of 2 ,~ . ~P' ~. Feb•22. 2D06 1~31PM CLARENDON FLAVOR ENGINEERING MATERIAL SAFETY DATA SHEET 29 C.F.R.- ~ '1900.1200 No•6050 P• 6 Date of prepara#ion: September 26, 2005 I. Identiity used on label (chemical and- common name(s): NATURAL ORANGE BERGAMOT FLAVOR C,4091 It. Physical and chemical characteristics: Boiling point {degrees F) .................................. N/A Vapor pressure {mmHg.) (100mm) .....:........ . N/A Vapor density (AIR = 1) .................................... N/A, Solubility in water ...............:.....:...................... complete Specific gravity (H20 =1.0) ............................. 0.876 ± 0.01 glml Percent, volatile by volume ............................... 100% Appearance & Aroma: Colorless, clear liquid with a strong citrus aroma 111. Physical hazards: * Flashpoints ................................................... 70° F Flammable limits ........................................... N/A Extinguishing media: Water, C02, alcohol foam, dry chemical IV. Health hazards: Effects of overexposure: mild eye and nose irritation, headache, drowsiness, tremors, fatigue, dizziness, anorexia, nausea, narcosis, and mental confusion. Page 1 of 2 Feb.22. 2006 1~37PM CLARENDON FLAVOR ENGINEERING ~r ;~. %~ V. Primary route of entry; Inhalation, skin-topical, and splashing in eye. VI. a. OSHA permissible exposure limit: Inhalation 1000 parts per million, 8 hour time weighted average b. ACGIH threshold limit value: Inhalatior 1000 pads per million, 8.hour time weighted average VII. Spill or leak procedures: No•6050 P• 1 Wash with water to sewer in accordance with focal statutes. VIII. Precautions for safe handling and use: a. Proper ventilation b. No smoking c. No flames or sparks IX. Reactivity data: Stability ................................. stable Incompatibility (material to avoid; none known Hazardous decomposition produ none known Hazardous polymerization.:....... will not occur X. Emergency first aid procedures: a. Eye contac#: irrigate with water b. Skin contact: flush with wafer c. Inhalation (excessive): immedia#e medical care d. .Ingestion: immediate medical care XI. Name, address and telephone number of manufacturer: Clarendon Flavor Engineering 3300 Seventh Street Road Louisville, KY 40216 Phone (502) 634-9215 Fax (502) 634-1438 Page 2 of 2 ~~G7 ~ ~i ~ cu•«: r.uvu ~rJll'~I I,LNtttIVUUIV rLAVUIi tNUINttKING MATERIAL SAFETY DATA SHEET 29 C.F.R. & 1940.1200 Date of preparation: June 29, 2000 z . Identity used on label (chemical and common name(s):- NAl'URAL VERY BERRY FLAVOR W~NF C-3128 No 6050 P 4 zz. Physical and chemical characteristics: Boiling point (degrees F) .....................:......:.... NIA Vapor pressure (mmHg.) (100mm) ................... N/A Vapor density (AfR = 1) .................................... N/A Solubility in water .......................................... complete Specific gravity (H20 =1.0) ............................. 1.037 +/- 0.01 glml Percent, volatile by volume ..........................:.,:. 100% Appearance & Aroma: Pale yellow liquid with a berry aroma TAY . Physicat hazards: * Flashpoints ................................................... >140°F Flammable limits ........................................... N/A - Extinguishing media: Water, C~2, alcohol foam, dry chemical zv, Health hazards: Effects of overexposure: mild eye and nose irritation, headache, drowsiness, tremors, fatigue, dizziness, anorexia, nausea, narcosis, and mental confusion. fCU~LL~ LUU~ 1;31!'M ~~HKt~VUU(v rLAVUfi tNUINkEHlNG No•6050 N' ~ V. Primary route of entry: ~• Inhalation, skin-Topical, `and splashing in eye. ~. ~~. VI. a. OSHA. permissible exposure limit:. Inhalatior 1000 parts per million, 8 hour time weighted average b. ACG1H threshold limit value: Inhalatior 1000 parts per million, , 8.hour time weighted average VII. Spill or leak procedures: Wash with water to sewer in accordance with local statutes. VIII. Precautions for safe handling and use: a. -Proper ventilation b. No smoking c. No flames or sparks IX. Reactivity data: Stability ................................. stable Incompatibility (material to avoid; none known Hazardous decomposition produ none known Hazardous polymerization......... will not occur H. Emergency first aid procedures: a. Eye contact: irrigate with water . b. Skin contact: flush with water c, Inha{ation (excessive): immediate medical care d. Ingestion: immediate medical care X1. Name, address and tetephone number of manufacturer: Clarendon Flavor Engineering 3300 Seventh Street Road _ Louisville, KY 40216 Phone (502) 634-9215 . . Fax X502) 634-1438 Page 2 of 2 ~~~ ~~~ \ symrise creating brands. supporting brands. Sender Symrise ,Inc. 300 North Street Teterboro, NJ 07608 Company CRYSTAL GEYSER WATER CO. 1233 E. CALIFORNIA BAKERSFIELD CA 93307 30434154 02 26-May-2006 PLEASE FORWARD THIS IMPORTANT SAFETY INFORMATION TO THE APPROPRIATE PERSONNEL RESPONSIBLE FOR WORKPLACE SAFETY. Please find attached the Material Safety Data Sheets for the products listed below. The MSDSs have been formatted according to the ANSI standard. Discard all previous versions of the MSDS. Please do not hesitate to call our Regulatory Affairs Department at 800-422-1559 or evenings, call 973-256-2930 if you have any questions. WHITE WINE FLAVOR NAT. JF-30487 Material Safety Data Sheet sym rise crsa:ing brands. supROrting brands. 298814 WHITE'WINE FLAVOR NAT: ;7F-30487 Version 1 Revision Date 01/09/2006 Print Date 05/26/2006 1. PRODUCT AND COMPANY IDENTIFICATION Product name WHITE WINE FLAVOR NAT. JF-30487 Product code 298814 Company Symrise ,Inc. 300 North Street Teterboro, NJ 07608 For information call 800-422-1559 or evenings, call: 973-256-2930 Emergency Phone Number Chemtrec 1-800-424-9300 or 1-703-527-3887 The emergency contact should only be used in the event of chemical emergencies involving a spill, leak, fire exposure or accident involving chemicals. 12. HAZARDS IDENTIFICATION The following evalutation is in compliance with 29 CFR 1910.1200. This evaluation relates to individual ingredients in this product which are required for consideration. The induced or observed effect results are for single concentrated materials under experimental or prolonged exposure. We consider the identity of the ingredient(s) to be a trade secret. Emergency Overview This product is Water solubility Odour Flash point Flammability (DOT173) Flammability (OSHA) OSHA PHYSICAL HAZARD (OTHER) Acute Health Hazard Eyes Skin Inhalation LD50 Oral LD50 Dermai LC50 Inhalation clear liquid -colorless completely miscible characteristic 72 °F / 22 °C Type: Tag closed cup Flammable Liquid Flammable Liquid None. Moderate eye irritant Mild Skin Irritant Mild Inhalation Irritant Not Toxic Not Toxic Not Toxic ,Material Safety Data Sheet sym rise • crea?ing Crands. suFPGrting brands. `298814 WHITE WINE FLAVOR NAT. JF-30487 `:. - . Version 1 Revision Date 01/09/2006 Print Date 05/26 2006 Chronic Health Hazard: This mixture has been found to contain the following materials that are considered to be carcinogenic according to NTP. NTP Carcinogen(s): Chemical Name CAS-No. Ethanol 64-17-5 Known carcinogen. This mixture has not been found to contain materials that are considered to be carcinogenic per IARC. This mixture has not been found to contain materials that are considered to be carcinogenic per OSHA. Ingestion Based on Human Evidence Target Organs: Central nervous system, Reproductive System, Liver, various Symptoms of Overexposure: Neurological disorders, Reproductive Effects, Liver disorders, vertigo, nausea, dizziness, vomiting Inhalation Based on Human Evidence Target Organs: various Symptoms of Overexposure: irritability, dizziness, vomiting, vertigo, nausea This product must be used at ambient temperature. We do not recommend heating this product. However, if during handling or processing, heating is required, then appropriate respiratory protection must be provided i addition to the engineering controls through ventilation, We recommend consulting with a certified Industrial hygienist for appropriate action for the worker safety. 3. COMPOSITION/INFORMATION ON INGREDIENTS Product Type Mixture of Flavor Materials. 4. FIRST AID MEASURES Emergency and First Aid Procedures: Eye contact Irrigate thoroughly with plenty of water until discomfort is relieved. Consult a physician for proper medical care. Skin contact Take off all contaminated clothing immediately. Wash off immediately with soap and plenty of water, If symptoms persist, call a physician. Inhalation If signs of dizziness and/or nausea occur, then remove the person immediately to fresh outside air. Ingestion If accidentally swallowed obtain immediate medical attention. 5. FIRE-FIGHTING MEASURES Flash point 72 °F / 22 °C Type: Tag closed cup • 2 /'6 Material Safety Data Sheet symrise creating brands. support;ng brands. ~ 298814 WHITE WINE-FLAVOR NAT. 7F-30487 Version 1 Revision Date OS 09/2006 Print Date 05/26/2006 ~~ HMIS Rating Health: 2 0 =Insignificant Flammability: 3 1 =Slight Reactivity: 0 2 =Moderate 3 =Serious 4 =Severe NFPA Classification Class IB Flammability (OSHA) Flammable Liquid Suitable extinguishing media dry chemical carbon dioxide (C02) Unsuitable media Water may be ineffective. Special protective equipment Follow North American Emergency Guidebook 127. and precautions for fire- fighters Specific hazards arising from None. the chemical 6. ACCIDENTAL RELEASE MEASURES This product is clear liquid -colorless Water solubility completely miscible Odour characteristic Methods for cleaning up Cover with an inert absorbent material and remove to a disposal container. Mop up and then wash with soapy water. Disposal Considerations Dispose of in accordance with local regulations. Observe local, state and federal regulations. Incineration is the most recommended disposal method. Based on the UN Number Classification, any spill or leak or file control procedure should follow the emergenc response guidebook (ERG) Guideline Number 127. 7. HANDLING AND STORAGE Use only in well-ventilated areas. Handle in accordance with good industrial hygiene and safety practice. For industrial use only. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat and flame. Flammability (OSHA) Flammable Liquid OSHA PHYSICAL HAZARD None. (OTHER) 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Exposure Guidelines _ . `3/6 Material Safety Data Sheet - symrise creating brands. supporting brands. 298814 WHITE WINE. FLAVOR NAT.-7F.-30487 Version 1 Revision Date 01/09/2006 Print Date 05/26 2006 Although this trade secret mixture has not been tested for its exposure risks and no PEL/TWA/TLV has been developed, it contains ingredi ents which when present, have the following values for PEL/TWA/TLV. Type Value PEL 1,000 ppm 1,900 mg/m3 TWA 1,000 ppm 1,900 mg/m3 REL 1,000 ppm 1,900 mg/m3 TWA 1,000 ppm We recommend maximum achievable PEL/TWA/TLV by means of appropriate engineering controls. PPE as required must be provided to workers for protection. Respiratory protection Respirator with filter for organic vapour Ventilation protection Ensure adequate ventilation. Eye protection Chemical resistant goggles must be worn. Hand protection Wear suitable gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Form clear liquid Color colorless Odour characteristic Flash point 72 °F / 22 °C Type: Tag closed. cup Water solubility completely miscible Specific Gravity (range) 0.8810 - 0.9210 at 68 °F / 20 °C Note: relation to density of water at 4°C 10. STABILITY AND REACTIVITY Chemical Stability Stable Possibility of Hazardous Will Not Occur reactions Conditions to avoid : None. Materials to avoid : None. Hazardous decomposition None. products 11. TOXICOLOGICAL INFORMATION Acute oral toxicity Please refer to section 2 for toxicological information. Acute dermal toxicity Please refer to section 2 for toxicological information. Acute inhalation toxicity Please refer to section 2 for toxicological information. 4L6 - .Material Safety Data Sheet sym rise creating brands. wFporting brands. 298814 WHITE WINE FLAVOR:NAT .7F-30487 Version 1 Revision Date 01!09 2006 Print Date 05/26/2006 12. ECOLOGICAL INFORMATION There is currently no ecological information available at this time. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local regulations. Observe, local, state and federal regulations. Incineration is the most recommended disposal method. 14. TRANSPORT INFORMATION 49CFR Road UN-No .1197 " Description of the goods "Extracts, flavoring, liquid Class 3 Packaging group II IMDG UN Number 1197 Description of the goods UN 1197 EXTRACTS, FLAVOURING, LIQUID ,3,PGII,IMDG Class 3 Packaging group II ADRJRID-Labe{S 3 EmS Number 1 F-E EmS Number 2 S-D IATA-DG R UN Number 1197 Description of the goods Extracts, flavouring, liquid Class 3 Packaging group II Cargo \ Packing Instruction 307 Qty /Pkg. 60.00 L Passenger\Packing Instruction 305 Qty /Pkg. 5.00 L 15. REGULATORY INFORMATION Toxic Substances Control Act (TSCA) Inventory Status This product is for FDA regulated product use only. SARA Title III Section 313 This product contains no chemicals subject to the reporting requirements of section 313 of SARA. 5./6 Material Safety Data Sheet , ~ ~~ symrise creating brands. supporting brands. '298814 WHITE WINE FLAVOR NAT. )F-30487 Version 1 Revision Date Ol 09j2006 Print Date 05/26/2006 US. EPA CERCLA Hazardous Substances (40 CFR 302) In accordance with SARA CERCLA 302.4 Regulations, if a release occurs in a quantity equal to or exceeding the reportable quantity, notification must be immediately made to the National Response Center at 800-424-8802. A release is considered any spilling, leaking, pumping, pouring, emitting, emptying, discharging, escaping, dumping or disposing into the environment. CERCLA Reportable Quantity 173 Ibs California Prop. 65 WARNING! This product contains achemical known in the State of California to cause cancer. Chemical Name CAS-No. No significant risk level: Ethanol 64-17-5 WARNING! This product contains a chemical known in the State of California to cause birth defects or other reproductive harm. Chemical Name CAS-No. No significant risk level: Ethanol 64-17-5 16. OTHER INFORMATION Further information These safety guidelines are based on information obtained from reliable sources. Prudent use and handling as part of good manufacturing practices is advised. Employees must be trained to handle material safely and wear recommended P.P.E. This new MSDS was treated to conform with OSHA hazard communication standard 29CFR 1910.1200. Please discard previous form. This MSDS was prepared by the Regulatory Affairs Department. '' 6/6 .. ~~ _ tt/~4; D F~ ~ 4< b .y tw,~""~ti.,~~` .~ ~~' ~~ CITY OF BAKERSFIEI.D FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3'd Floor, Bakersfield, CA 93301 FACILITY NAME SFa ~ ~i ~ N s.c./ ADDRESS E'- C ~n/- FACILITY CONTACT o ~ {~ INSPECTION TIME ? t-i D D Section 1: Business Plan and Inventory Program INSPECTION DATE ~ - 2 ~ -G ~ PHONE NO. - Z 9 ~ BUSINESS ID NO. 15-21 U- ~ ~ Nt1MBER OF EMPLOYEES •?, S - ~-~ v-~-nA~ ~.L, ~..~c~~ Cc~.~.~M c.'i' ~. ~A/r ~ t.~.~ JZltr, Hr Y331n- ~3Sa., ^ Routine Combined ^ Joint Agency ^MultI-Agency ^ Complaint ^ Re-inspection OPERATION C V COMMENTS Appropriate permit on hand Y Business plan contact information accurate Visible address }( Correct occupancy Verification of inventory materials Verification of quantities Verification of location Proper segregation of material Verification of MSDS availability Verification of Haz Mat training Verification of abatement supplies and procedures Emergency procedures adequate Containers properly labeled Housekeeping a L _~ Fire Protection Site Diagram Adequate & On Hand C=Compliance V=Violation Any hazardous waste on site?: '~ Yes ^ No Explain: D% ~I'J SSaa / o h l~r~ s« S Questions regarding this inspection? Please call us at (661) 326-3979 White -Env. Svcs. Yellow -Station Copy Pink -Business Copy Business Site R~s~ionsible Party Inspector: /~, -5 ,~rr,,Q,~ _~~ ~,o + CRYSTAL GEYSER OF BAKERSFIELD _______________________ SiteID: 015-021-001418 + Manager Location: 1233 E CALIFORNIA AVE City BAKERSFIELD CommCode: BFD STA 02 EPA Numb: CAL922854734 BusPhone: (661) 323-6296 Map 103 CommHaz Extreme Grid: 32C FacUnits: 1 AOV: SIC Code:2086 DunnBrad: Emergency Contact / 'T'itle Emergency Contact / Title HARRY BARBA / QC SUPERVISOR DAVID WRIGHT /PROD MAN.gGER Business Phone: (661) 32.3-6296x tusiness Phone: (661) 323-6296x 24-Hour Phone (661) 82.3-1708x 24-Hour Phone (661) `836-1382 Pager Phone (661) 333-0117x Pager Phone (661) Hazmat Hazards: Fire Press React ImmHlth DelHlth Contact DEE SECARA 661-34 0-0426 CELL Phone: (661) 323-6296x MailAddr: 1233 E CALIFORNIA AVE State: CA City BAKERSFIELD Zip 93307 Owner PETER GORDON _ Phone: (702) 942-OSOOx Address 501 WASHINGTON ,ST _ State: CA City CALISTOGA Zip 94515 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif~d: RSs: No ParcelNo: Emergency Directives: ~ PROG A PROG H PROG R PROG T - HAZMAT - HAZ WASTE GEN - CALARP - ABOVEGROUND STORAGE TANK THIS IS A RMP SITE WHICH REQUIRES A JOINT INSPECTION. PLEASE CALL ENV SVGS TO SCHEDULE AN INSPECTION.. Based on my inquiry of those individuals responsible for obtaining the information, 1 certify under penalty of law that I have personally examined and am #amiliar with the information submitted and believe the information is true, acc rate, and complete. Signature ~ ©~ Date -1- 03/08/2006 UNIFIED PROGRAM l :..SECTION CHECKLIST SECTION 1 Business Plan and Inventory Program Bakersfield Fire~ept Enironmental Services 1715 Chester Ave Bakersfield, CA 93301 Tel: (661)326-3979 FACILITY NAME Cr f'~a ( ~eyIar ' _ . - -- - INSPECTION DATE 6-.10-03 INSPECTION TIME /330 ADDRESS ---------- J _ - ------ ----- ---- ---- -- - --- - PHONE No. No. of Employees FACILITYCONTACT nn // [` l~abQ/ HO t {C'r~ Business ID Number p ~ 5-21- ~y ( O Section 1: Business Plan and Inventory Pn~gram ^ Routine ^ Combined Joint Agency ^Mnlti-Agency ^ Complaint ^ Re-inspection C V (v=Vbatlonncel OPERATION ) COMMENTS ~' ^ PERMIT ON HAND APPROPRIATE ^ BUSINESS PLAN CONTACT INFORMATION ACCURATE -~ ^ VISIBLE ADDRESS - ^ CORRECT OCCUPANCY D ~' ^ VERIFICATION OF INVENTORY MATERIALS '~ ^ VERIFICATION OF QUANTITIES - ]~ ^ VERIFICATION OF LOCATION ~I ^ PROPER SEGREGATION OF MATERIAL ~ ^ VERIFICATION OF MSDS AVAILABILITYE ^ VERIFICATION OF HAT MAT TRAINING '~ ^ VERIFICATION OF ABATEMENT SUPPLIES AND PROCEDURES ^ EMERGENCY PROCEDURES ADEQUATE ^ -- -- CONTAINERS PROPERLY LABELED leure /abel ------- --- - ---P- ----- ----- -I Q ~ 1 a~ovv~ to f ura~ rdo,N. - ~------._ _ ----- ~---- ---- . ----- ------- --------- ------ -~ --- ^ --- HOUSEKEEPING -~ ----- ---- ----CJt//N~,r1h~"l /n. ~J - GY~ /~ ~~ hP~~ -f Q{'/l,~I-/~ ----------------------- ^ --- ~ ----- FIRE PROTECTION - -------- - ------- ~u~ ~•.a~; ~c spy, ~, k 1 e~ _r ~~pr.. h P>° a~l ~ ~.-- t~l - ^ SITE DIAGRAM ADEOUATE Sr ON HAND ANY HAZARDOUS /W~A~STE "OfN" SITE: / YES ^ NO EXPLAIN: f^' ~ `/ ~ Q ~ 1 QUESTIONS REGARDING THIS INSPECTION? PLEASE CALL US AT ~66~ ~ 3Z6-3979 ~~ --- --- ~~ y----- ------------- _ __- - ~-- ~' - ~'~ I spectrf~rr~ Bad a No. Business Site Re 9 While -Environmental Services Yellow - Statwn Copy Pmk -Business Copy -- - ,. 1 ~~~~~, y i rr.. _ _~ + CRYSTAL GEYSER OF BAKERSFIELD _______________________ SiteID: 015-021-001418 + Manager BusPhone: (661) 323-6296 Location: 1233 E CALIFORNIA AVE Map 103 CommHaz Extreme City BAKERSFIELD Grid: 32C FacUnits: 1 AOV: CommCode: BFD STA 02 SIC Code:2086 EPA Numb: CAL922854734 DunnBrad: Emergency Contact / Title Emergency Contact / Title___ HARRY BARBA / QC SUPERVISOR DAVID WRIGHT /PROD MADi.&GER Business Phone: (661) 323-6296x Business Phone: (661) 323-6296x 24-Hour Phone (661) 82.3-1708x 24-Hour Phone (661) -'g 36-1382 Pager Phone (661) 333-0117x Pager Phone (661) 1 Hazmat Hazards: Fire Press React ImmHlth DelHlth Contact DEE SECARA 661-34 0-0426 CELL Phone: (661) 323-6296x MailAddr: 1233 E CALIFORNIA AVE State: CA City BAKERSFIELD Zip 93307 Owner PETER GORDON _ ~ Phone: (702) 942-0500x Address 501 WASHINGTON .ST State: CA City CALISTOGA Zip 94515 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: No ParcelNo: ~ Emergency Directives: ~ PROG A PROG H PROG R PROG T - HAZMAT - HAZ WASTE GEN - CALARP - ABOVEGROUND STORAGE TANK THIS IS A RMP SITE WHICH REQUIRES A JOINT INSPECTION. PLEASE CALL ENV SVGS TO SCHEDULE AN INSPECTION. Based on my inquiry of those individuals responsible for obtaining the information, I certify under penalty of law that I have personally examined and am familiar with the information submitted and believe the information is true, ac~ate, and complete. Signature Date -1- 03/08/2006 1 ~~ __.R- 9l V~ "AMERICA'S NATURAL BEVERAGE COMPANY" March 13, 2006 Ralph E. Huey Director Prevention Services 900 Truxtun Ave. # 210 Bakersfield, Ca 93301 Re: Fire Dept Inspection Concerns and Resolves 1. Ammonia system wired to outside source in case of emergency on weekends or holidays. This issue has been addressed, our in house automatic dialer will notify plant management Personnel in the event that any of our Manning Ammonia Sensors are activated. 2. The label on the laser gas cyclinder has been put on cylinder and vendor notified will not except cyclinders that are not marked. 3. Maintenance shop fire extinguisher has been serviced on 3/9!06. 4. The missing gauge will be installed on 3/15/06 on the Ammonia Dump Station. S. Our automatic dialer is already wired for the Ph meter for the wastewater system. If I can be of any further assistance, please don't hesitate to call. Sincerely, Robert Hofferd CRYSTAL GEYSER WATER COMPANY P.O. Box 304, 501 Washington Street, Calistoga, CA 94515-0304 (707) 942-0500 FAX (707) 942-0647 ~ ~ _,. ~ ~~f~~ INC 111.6 Pian Review and Modification All records concerning this RMP shall be kept for at least five years (Section 2755.1). Necessary revisions to the RMP will be made at least every five years (Section 2745.10 (a)(1). The RMP must be revised within 60 days of a modification that results in a significant increase in either the amount of regulated substance handled at the facility or in the risk of handling the regulated substance (Section 2745.11 (b)). All revisions to this RMP are to be recorded here. DATE OF CHANGE CHANGES/INPUTS MADE TO DOCUMENT PAGESI SECTION AFFECTED SIGNATURE/DATE 03/07/06 ENVIROMENTAL MANAGE. 18 03/07/06 INTERNAL NOTIFICATIO 38 D 03/07/06 - -- INCIDENT COMM. UPDAT 51 ,~ /~ 0~ 03/07/06 CHANGES RECORDES 69 3 /j D 03/07/p~ TRAINING ANALY. UPDA E 68P~ j O 03320012.001 69 03/07/06 CRYSTAL GEYSER OF BAKERSFIELD 215-000-001418 00 -Overall Site <G> Training <1> Page 1 WE HAVE 32 EMPLOYEES AT THIS FACILITY WE HAVE MATERIAL SAFETY DATA SHEETS ON FILE SUMMARY OF TRAINING INCLUDES A LIST OF THOSE QUALIFIED IN S.C.B.A. SUMMARY OF TRAINING: EACH EMPLOYEE INVOLVED IN THE USE OF HAZARDOUS MATERIALS WILL BE GIVEN INSTRUCTION IN THE SAFE HANDLING AND USE OF EACH PRODUCT BEFORE THEY BEGIN USE. EACH EMPLOYEE WILL BE PROVIDED WITH SAFETY EQUIPMENT REQUIRED FOR EACH PRODUCT HANDLED. SAFETY PROCEDURES FOR SPILL CLEAN-UP OF HAZARDOUS MATERIALS WILL BE TAUGHT. NEW ua~artnOUS MATERIALS INTRODUCED INTO INVENTORY WILL BE REVIEWED WITH EACH INDIVIDUAL BEFORE USE. REFRESHER COURSES IN SAFE HANDLING OF HAZARDOUS MATERIAL WILL BE REQUIRED OF EACH EMPLOYEE INVOLVED IN THE USE OF HANDLING DURING THE YEAR IN ACCORDANCE WITH YOUR REQUEST WE SUBMIT THE FOLLOWING LIST OF INDIVIDUALS WHO HAVE BEEN TRAINED OR ARE BEING TRAINED TO INITIATE AN EMERGENCY RESPONSE TO AN UNLIKELY INCIDENT. 1) ARMANDO RAYO -MAINTENANCE LEAD PERSON MR RAYO IS IN TRAINING AND IS GETTING EXPERIENCED IN ALL ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT OFF VAVLES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES AND BEING TRAINED IN THE USE OF OUR AMMONIA DIFUSION SYSTEM. ALSO, MR RAYO HAS BEEN TRAIlVED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. 2) CHARLES WRIGHT -MAINTENANCE MECHANIC MR WRIGHT IS IN TRAINING AND IS GETTING EXPERIENCED IN ALL ASPECTS OF OUR AMMONIA SYSTEM: PII'ING LAYOUT, LIQUID AMMONIA SHUT OFF VAVLES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES AND BEING TRAINED IN THE USE OF OUR AMMONIA DIF[JSION SYSTEM. ALSO, MR WRIGHT HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR F1RE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. 3) RICHARD WEKLYCH -PLANT MANAGER MR WEKLYCH HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. 4) ROBERT HOFFERD -SHIPPING /SAFETY SUPERVISOR MR HOFFERD HAS BEEN TRAINED AND IS EXPERIENCED IN MOST ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT OFF VAVLES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES AND BEING TRAINED IN THE USE OF OUR AMMONIA DIFUSION SYSTEM. ALSO, MR HOFFERD HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. 5) DAVID WRIGHT -PRODUCTION MANAGER MR. WRIGHT IS IN TRAINING AND IS GETTING EXPERIENCED IN MOST ASPECTS OF OUR AMMONIA SYSTEM: PIPING LAYOUT, LIQUID AMMONIA SHUT OFF VAVLES, COMPRESSOR MAINTENANCE AND RECORDS, AMMONIA SAFE HANDLING PRACTICES AND BEING TRAINED IN THE USE OF OUR AMMONIA DIFUSION SYSTEM. 6) HARRY BARBA -QUALITY CONTROL TECH MR BARBA HAS BEEN TRAINED IN THE PROPER USE OF OUR S.C.B.A. UNITS. HE IS ALSO KNOWLEDGEABLE OF OUR FIRE/EMERGENCY EVACUATION PLANS AND WOULD BE ABLE TO INITIATE AND HANDLE AN EMERGENCY RESPONSE TO ANY INCIDENT. ALL PLANT MANAGEMENT, MAINTENANCE PERSONNEL AND OTHER EMPLOYEES WHO WORK WITH LITTLE SUPERVISION WILL BE TRAINED IN FIRST AID AND CPR <2> HELD FOR FUTURE USE <3> HELD FOR FUTURE USE <4> HELD FOR FUTURE USE B. ENVIRONMENTAL MANAGEMENT SYSTEM Manufacturing Process Manager, Dee Secara, is responsible for the Bakersfield facility. Issues must go through the Manufacturing Process Manager for final approval before implementation. At the Crystal Geyser Bakersfield location, the Safety Coordinator, Robert Hofferd, will be the qualified individual and Environmental coordinator. The Evironmental Coordinator is responsible for all safety training of employees. The Emergency contact will be the Production Manager David Wright. Any emergency incidents that occur at the facility will be the emergency contact's responsibility. All supervisors will be responsible for the safety of the employees in their section.8 03320012.001 18 111.2 NOTIFICATIONS A. INTERNAL NOTIFICATIONS Facility personnel will report an accidental release or any other emergency condition to their supervisor. Supervisors will notify office personnel who will use the paging system to notify all employees to evacuate the facility. If emergency situation occurs after work hours, supervisor or lead person will use paging system to notify employees of evacuation. AFTER HOURS/WEEKENDS/HOLIDAYS NOTE: If an ammonia sensor is activated, our in house automatic dialer will start calling management personnel. Management will react as needed. Outside agencies will be notified if needed. 03320012.001 38 PAGE 1 INCIDENT COMMAND SYSTEM {ORGANIZATION} INCIDENT COMMANDER- DAVID WRIGHT COMMAND STAFF: INFORMATION OFFICER- ROBERT HOFFERD {ORGANIZATION & ASSISTANT - DEE SECARA MEDIA CONTACT} SAFETY OFFICER---- JOSE BALDEMAR {MONITOR SAFETY OF ALL ASSIGNED ASSISTANTS-------- JOSE MENDOZA PERSONNEL} Q.C. TECH (ON DUTY) MAINT. TECH (ON DUTY) LIAISON OFFICER---- ROBERT HOFFERD {ON SITE CONTACT ASSISTANT------- DEE SECARA FOR OUTSIDE AGENCY, O.E.S. FIRE DEPT. HAZMAT TEAM ETC.} PAGE 2 GENERAL STAFF OPERATIONS SECTION: CHIEF: DAVID WRIGHT DEPUTY'S: JOSE MENDOZA Q.C. TECH (ON DUTY) MAINT. TECH (ON DUTY) 1. DEVELOPE AND MANAGE THE OPERATIONS SECTIONS TO ACCOMPLISH THE INCIDENT OBJECTIVES. PLANNING /INTELLIGENCE AND LOGISTICS: CHIEF: ROBERT HOFFERD ASSISTANT: DEE SECARA 1. COLLECT, EVALUATE AND DISPLAY INFORMATION ABOUT THE INCIDENT. 2. DEVELOPE INCIDENT ACTION PLANS FOR EACH SHIFT. 3. MAINTAIN RESOURCE STATUS INFO ON ALL EQUIPMENT AND PERSONNEL ASSIGNED. 4. MAINTAIN INCIDENT DOCUMENTATION. FINANCE AND ADMINISTRATION ASSISTANT: DEE SECARA 1. TIME UNIT 2. PROCUREMENT UNIT 3. COMPENSATION /CLAIMS UNIT 4. COST UNIT COMMAND SYSTEM ., . , , -~-, ,. ` lE DI Commodil Chemuals`•Laboraior ServicesdPrbducfs-. ~ . Qo~S\e SlRjBG~ Mini•BulkDeliver S tems•,WaterTrealmenlC - ~ hemicals• ,.f.,. FifirationEgwpmenl&Media~FoodPracessingCompounds ~` s Chemical Cleaners-Chlorination;UV80zone {~ ~'OQuaoticoAve: Bakersfield CA 93301, ~ Phorte:661322-2222,. ,. ~~ . wrgo~argochem com~: ; , : ~ ~ Faz: 661322.2303: , ~.. ~. ~ ~ ~. ~~ .. - ~ , 'MATERIAL SAFETY ...DATA. SHEET ~, ~ .: ~ ~ , . . : , A1kaChlor F , 3 ~~ , ! . SECTION I -IDENTIFICATION. ,„ ~~ COMPANY~NAME:. .: Argo Chemical;-Inc: , EMERGENCY PHONE NUMBERi' (66P) 322'-2222 or;Chemtrec (800) 429-9300 ` ~~ TRADENAME.t ~ - _ ~.A1kaChlor F ~. ~ ~ ~ - ~ ~ ~ ' i°- OTHER 1VAMESr : Mixture-Water/phosphates/hydroxides/hypochlorite. COMPANY 'LD.. NO::~ . - ~ = , DO,T HAZARDOUS MATERIALS PROPER SHIPPING NAME: , > ,,o i Corrosive IJiquids; basic, inorganic, n.os:; 8; UN 3266; II, ERG .154. SECTION II -SUMMARY OF HAZARDS , i ,. PHYSICAL~~HAZARDS: ~ ~ ~ ~ .Corrosive ~: ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ :.. ;' .~. '~ ACUTE HELLTH EFFECTS: ~~ ~~ ~ ~ Can Cause irritation to body tissues. ~~ ~ ~~ ~ ~ ~. ~ ~ ~ ~ ~ . wri. , . ~ .. CHRONIC HEALTH EFFECTS: `None Kno ,, , HEALTH ~ 2 - _ ` REACTIVITYr ` 1. ~ - '~ ,• ..FIRE: 0 ,. PERSONAL: B , .~ ~. , , { , HMIS RATING (4=Severe, 3=Serous°, 2=Mod'e'rate, l=Slight, O=Insignificant) ~ ; } ~ ~ ~ ~. ~. ;' 's - ,, SECTION III - FIItE AND EXPLOSION HAZARD DATA ` ,~ FLASHPOINT (METHOD): None ~; - } AUTOIGNI,TION TEMP.: Unknown N/A ' ' 'FLAMMABLE LIMITS (%Volume in Air):: Lower - N/A Upper - N/A , FIRE. AND EXPLOSION HAZARD:. Offers,no fire hazard under normal conditions. Product is corrosive to mostmetals; releasing explosive hydrogen gas. ` .EXTINGUISHING MEDIA: Foam, Water Spray, C02, Dry Chemical, ,' ,' • SPECIAL FIREFIGHTING PROCEDURESi Keep containers cool, with water spray.. ` ' -,. SECTION IV -HEALTH HAZARD DATA INHALATION: No known effects from properly stored or us'e product.. Fumes from `spills can lie, irritating to ° . ~~ ~ , mucous membranes: ". ~ . t~;~ ~~ ~ `EY'E CONTACT: ~" ' ~ Can cause irritation, corrosive. ~~- SKIN ABSORPTION:. :Same as skin contact:.. _ .' ' . , . a SKIN IRRITATION: ~ Prolonged direct exposure,may cause skin irritation, defatting and reddening.: ,., INGESTION: Can cause severe irritation to membranes of the mouth, throat; and stoma~h~ SUMMARY OF CHRONIC HAZARDS AND SPECIAL HEALTH:. ° None Known. . _~ ~ - ;. ,. ,. ~.. .:. - i i _ ~~ ,. ,: ~ ~ ,, ,. SECTION V -PROTECTIVE' EQUIPMENT AND OTHER CONTROL MEASURES RESPIRATOR: With, proper ventilation none needed, however if misting applications put exposure above the " safe level {TLV); a 1VIdSH approved respirator is recommended. . . EYE: " Chemical Goggles, Face Shield. , SKING: Chemical Resistant Gloves. ENGINEERING CONTROLS: Adequate ventilation.- OTHER HYGIENIC AND WORK PRACTICES: Train employees in proper handling procedures in this section " before allowing them to work with this product. Clean up spills immediately. SECTION VI -OCCUPATIONAL EXPOSURE LIMITS ' ~ CAS No. EXPOSURE LIMITS IN AIR SUBSTANCE ACGIH (TLV) OSHA (PEL) OTHER Sodium Hypochlorite ~ ~ ~~ 7681-52-9 ~ ` none listed ~ ~ ~ ~ " - Tetrapotassium Pyrophosphate. 7320-34-5 lOmg/m3 15mg/m3 Potassium hydoxide 1310-58-3 2mg/rn3 , NOTE: This product contains no levels of listed substances; which the State, of California has found to cause cancer; birth defects or other reproductive harm, which would require a warning under the statute. ~, j SECTION VII -EMERGENCY AND FIRST AID EYE CONTACT: Flush with water for at least 1.5 minutes. Consult a physician. SKIN CONTACT: Wash exposed area. Remove contaminated clothing and wash before reuse. INGESTION: DO NOT INDUCE VOMITING. Drink large amounts of water. Call physician immediately. Never give anything to an unconscious person. _' SECTION VIII -SPILL AND DISPOSAL PRECAUTION IF MATERIAL IS SPILLED OR RELEASED: Stop leak. Dam up area of spill. Dry floor with absorbent, Shovel into metal or plastic lined containers. Keep area clear of traffic as the floor will be extremely slippery. Clean area with usual floor cleaner: WASTE DISPOSAL METHODS: DISPOSE ACCORDING TO .LOCAL, STATE & FEDERAL REGULATIONS. SECTION IX -COMPONENTS (This ma not be a com lete list of com onents) COMPONENT NAME CAS No. HAZARDOUS COMPONENT COMPOSITION AMOUNT-(WT) ADVISORY Sodium Hypochlorite 7681-52-9 ** G30% Tetrapotassium pyrophosphate 7320-34-5 none listed < 8% Potassium hydoxide 1310-58-3 4, *** <30% **RQ-100# (reportable quantities) *-SARA Title ***RQ-1000# (reportable quantities) ' #Listed by: 1=0SHA (air). 2=0SI3A (regulated substance) 3=NTP (carcinogens) " 4=ACGIH (chemicals). S=1ARC (human carcinogens) 6=DOT (hazardous materials) . 2 ,.. ',~ ^" ., ', ... .' , ~ ~' 1 - SECTION X -PHYSICAL AND CHEMICAL DATA BOILING POINT:'. >212°F " FREEZING POINT: 32°F SPECIFIC GRAVITY (H2O=1): 1..19 +/-0.5 " , SOLUBILITY IN WATER: Complete VISCOSITY UNITS, TEMP: (METHOD); N / AP ~ ' VAPOR PRESSURE: Unlrnown VAPOR DENSITY (Air=1 @60-90°F) Unlrnown " ' STABLE /UNSTABLE: Stable Phc >13.5 HAZARDOUS POLYMERIZATION:. Will. Not Occur EVAPORATION RATE: <Water APPEARANCE AND ODOR: `' Clear/amber liquid, chlorine -mild odor: . MATERIALS TO AVOH):. ~ Strong Oxidizing Agents. Acids. ' HAZARDOUS DECOMPOSITION: Carbon dioxide, Carbon Monoxide products. SECTION XI -ADDITIONAL PRECAUTIONS ' HANDLING, STORAGE AND DECONTAINATION PROCEDURES: Keep containers, closed when not in use to avoid"contamination. ~; ~ ~ ~ ~ ~. _.. DISCLAIMER OF LIABILITY: The information contained herein is based on the data available to us and is believed to be ' correct. However, Argo Chemical Inc., makes no expressed or implied warranty regarding the accuracy of this data or the results to be obtained from their use. The conditions or methods of handling, storage, use and disposal of the product are beyond our control' and may be beyond our knowledge. For this, Argo Chemical Inc. assumes no responsibility for injury from the use of the product described herein, and expressly disclaims liability for loss, damage or expense arising out of or in any way connected ~ with the handling storage, use or disposal of the product. ~ ~ Revision Date:. 3-1-2005 i 3 _ __ _ __ _. .. .. S\9lE DISrp~ • CommodityChemicals LaboratoiySeruicea&Producls,• Q°a BG~io Mim•BulkDeliverySysiems-WalerTrealmenlChemicals- '-` + FilfrafionEquipment&Media•FoodProcessingCompounds `~' y Chemical Cleaners•Chlorlnallon;UV&omne ~ " ~ h ', ' f ~' `'OOQuaoficoAve. Bakersfield CA 93301 ~ Phone; 661322-2222 . argo~argochi:m.com ~ Fax:661322.2303 :.MATERIAL SAFETY DATA SHEET. - ~ CHAIN LOBE H-1 ~ ~ ~ ~ ~ ~ ~. 'SECTION 1 -IDENTIFICATION ' COMPANY' NAME:` Argo Chemical",.Inc. ~ - EMERGENCY PHONE NUMBER: (661) 322-2222 or Chemtrec (800)429-9300 PRODUCT IDENTIFIER:.. Chain Lube H=1 " TRADE" NAME:. Chain Lubricant #209 H-? ' . OTHER NAMES: Mixture-Water/Surfactants/Soaps . SECTION II -SUMMARY OF HAZARDS. i PHYSICAL HAZARDS:. None Known ACUTE HEALTH EFFECTS: Eye and Skin irritant ~ " "CHRONIC HEALTH EFFECTS: None Known HMIS RATING: Flammability:. 0 Health: 1 Reactivity: 0 Personal Protection:. B '. (4= Extreme, 3= High, 2= Moderate, 1=Slight, 0=dnsignificant) , '' ~ SECTION III. ~- FtRE AND EXPLOSION FLASHPOINT/METHOD:" NONE (Boils @ 220°F) FIRE AND EXPLOSION HAZARD.: N/A ' ~ AUTOIGNITION TEMPERATURE: Unknown N/A FIRE EXTINGUISHING MEDIA:. N/A FLAMMABLE LIMITS (%Yolume in air):; Lower: N/A, Upper: N/A SPECIAL FIREFIGHTING PROCEDURES: NIA SECTION IV -HEALTH HAZARDS INHALATION..: Not expected to Occur. , EYE CONTACT:- Can cause irritation as any foreign body. Can cause eyes to sting or burn. SKIN ABSORPTION: Not expected. to occur SKIN IRRITATION: Repeated and prolonged exposure to skin contact may cause some .irritation in individuals.. INGESTION: Can cause nausea and diarrhea. ' SUMMARY OF CHRONIC HAZARDS AND SPECIAL HEALTH EFFECTS: None Known. SECTION V -PROTECTIVE EQUIPMENT AND OTHER CONTROL MEASURES RESPIRATORY:. N/A EYE:" Chemical goggles, Face Shield. . SKIN,: Chemical Resistant Gloves ENGINEERING CONTROLS: N/A OTHER HYGIENIC AND WORK PRACTICES:. Train, employees in proper handling procedures in this section before, allowing them to work with this product. Clean up spills immediately. Floors become slippery with even small amounts spilled. SECTION VI -OCCUPATIONAL EXPOSURE LIMITS CAS NO. EXPOSURE LIMITS IN AIR SUBSTANCE ACGIH(TLV) OSHA(PEL) OTHER ~`~ Proplylerie Glycol " 57-556 NONE LISTED Phosphate ester 51811-79-1 NONE LISTED Tetrasodium EDTA 64-02-8 NONE LISTED Potassium Soaps 143-18-0 NONE LISTED -Chain Lube H-1 1 Revised' 6-20-05 ., SECTION VI1 .- EMERGENCY AND FIRST AID INHALATION: No Know effects - EYE CONTACT: Flush with water for, at least'15 minutes. If irritation persists consult a physician.. , SKIN. CONTACT:. Wash exposed area. Remove contaminated clothing and wash before reuse. INGESTION: Do not give liquids if victim is unconscious or very drowsy.. Otherwise, give no more than 2 glasses of water and induce vomiting by giving 2 TBS. Syrup of Ipecac: If this: is unavailable induce vomiting by touching finger to back of victims throat. Call physician. ~ . SECTION VIII -SPILL AND DISPOSAL PRECAUTION IF MATERIAL IS SPILLED OR RELEASED: Stop leak.. Dam up area of spill., -Dry floor with absorbent. Shover into metal or plastic lined containers. Keep area clear of traffic, .as. the floor will be extremely slippery. Clean area with usual floor cleaner. WASTE DISPOSAL METHOD: Dispose according to Local, State & Federal regulations. `.SECTION IX - COMPONENTS COMPONENT NAME CAS No. HAZARDOUS SUBSTANCE # COMPOSITION 1 ADVISORY AMOUNT -. (Wt.) Propylene; Glycol 57-55-6 1-10% Phosphate ester 51811-79-1 1-10% Tetrasodium EDTA 64-02-8 1-10% Potassium Soaps 143-18-0 10-25% ,NOTE; 'This product contains .no levels of listed substances, which the State of California has. found to cause ~ cancer, birth defects or other reproductive harm, which would require a warning under the statute: #Listed by: .1=0SHA (air) 2=0SHA (regulated substance) 3=NTP (carcinogens) 4=ACGIH (chemicals) 5=1ARC (human carcinogens) SECTION X -PHYSICAL AND CHEMICAL DATA BOILING POINT: >220°F VISCOSITY UNITS, TEMP. (METHOD): N / AP FREEZING POINT: 32°F VAPOR PRESSURE: Unknown. SPECIFIC GRAVITY (H2O=1): 1.056 VAPOR DENSITY (Air=1@60-90°F): Unknown STABILITY: Stable SOLUBILITY IN WATER: Complete pH=concentrate 10.5+/-0.5 pH-dilute 8.0-10.0 HAZARDOUS POLYMERIZATION: Will not occur. EVAPORATION RATE: <water APPEARANCE AND ODOR: Amber viscous liquid, mild odor. • ' MATERIALS TO AVOID: Strong, Oxidizing Agents. ' HAZARDOUS DECOMPOSITION: Carbon Monoxide, Carbon Dioxide SECTION XI -ADDITIONAL, PRECAUTIONS HANDLING, STORAGE AND DECONTAMINATION PROCEDURES: Do`not allow the product to freeze. Keep ' the container closed to avoid contamination. The information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,, expressed or implied, regarding its correctness.. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. -For this and other reasons, Argo Chemical Inc. does not assumes responsibility and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with the handling storage, use or disposal of the product. Chain Lube H-1 2 Revised 6-20-05 . - oas\~~ ~ISrRieG _ ~ t ~ CommgdityChemicals•taboratoryServices&Praducts• c ro Mini-BulkDeliverySystems•Water'freaimeniChemicals- ' .~` FilfrationEquipmenf$I~edia•FoodProcessingCompou~ds ~ ~ . ti ChemlcalCleaners~CNorlnaflon,UVrrOzone ` `OQuanticoAve., BakersfieldCA 93301 .; ~ ~ Phone: 661322-2222 ` argo~argochem.com " Fax: 661' 322.2303 -` ~ MATERIAL SAFETY DATA SHEET , . ,.. .CHAIN LOBE H-2 .. SECTION I - .IDENTIFICATION "COMPANY. NAME. Argo Chemical, Inc...° " - ' EMERGENCY PHONE NUMBER: (661) 322-2222 or Chemtrec (800)429-9300. PRODUCT IDENTIFIER: Chain Lube H-2 TRADE NAME: Chain Lubricant #210.H-2 ~ , ,OTHER NAMES::' Mixture-Water/Surfactants /Soaps '. SECTION II' ,-' SUMMARY OF HAZARDS. ~~ ~ ~, PHYSICAL HAZARDS: ~ ~ None Kriown~ ~ ~ ~ ~ ~. ~ ~~~ ACUTE HEALTH EFFECTS: Eye and Skin irritant, ' CHRONIC HEALTH EFFECTS: None Known ' HMIS RATING: Flammability: 0 Health: 1 Reactivity: 0 Personal Protection: B (4= Extreme,. 3= High,. 2= Moderate, 4= Slight; 0= Insignificant) " ~~ `° SECTION III -FIRE' AND EXPLOSION r ,.~ ~ - FLASHPOINT/METHOD; NONE (Boils @ 220°F) ~ FIRE AND EXPLOSION HAZARD: N/A . AUTOIGNITION TEMPERATURE: Unknown N/A FIRE EXTINGUISHING MEDIA: N/A ' FLAMMABLE LIMITS (% Volume~in air): Lower: N/A, Upper: N/A " SPECIAL FIREFIGHTING PROCEDURES: N/A SECTION IV -HEALTH HAZARDS IN'H'ALATION: Not expected to Occur. EYE CONTACT:. Can cause irritation as any foreign body. Can cause eyes to sting or burn. SKIN ABSORPTION: Not expected to occur SKIN. IRRITATION: Repeated and prolonged, exposure to skin contact may cause some irritation in individuals. - INGESTION: Can cause nausea and diarrhea. SUMMARY OF CHRONIC HAZARDS. AND SPECIAL HEALTH. EFFECTS: None Known. SECTION V -PROTECTIVE EQUIPMENT AND OTHER CONTROL MEASURES RESPIRATORY:. N/A ' , > EYE:. ° . Clemical goggles, Face Shield. SKIN.:. Chemical Resistant Gloves ENGINEERING CONTROLS: N/A OTHER HYGIEN1C AND WORK PRACTICES: Train employees in proper handling procedures in this, section ' " , before allowing them to work with this product.` Clean up spills immediately. Floors become slippery with even small amounts spilled: . SECTION VI -OCCUPATIONAL EXPOSURE LIMITS CAS NO. EXPOSURE LIMITS IN AIR ' . ,4 SUBSTANCE " ACGIH(TLV) OSHA(PEL) OTHER Tetrasodium EDTA 64-02-8 NONE LISTED Potassium $oa s 143-18-0 NONE LISTED p ' ~ Chain Lube H-2 MSDS ~ 1. Revised 6-2005 ~I • ~" 100 Quantico Ave. Bakersfield, CA 93307 Phone: (661) 322.2222 Fax: (661) 322-2303 .. j' . '~ SECTION -VII -EMERGENCY AND FIRST AID INHALATION: No Know effects EYE CONTACT: Flush with water for at least 15 minutes. If irritation persists consult a physician. SKIN CONTACT: Wash exposed area". Remove contaminated clothing and wash before reuse. INGESTION:, Do not give liquids if victim is unconscious or very drowsy. Otherwise, give no more than 2 glasses of water and induce vomiting by' giving 2 TBS. Syrup of Ipecac. If this is unavailable induce vomiting by touching finger to back of victims throat. Call ,physician. SECTION VIII "- SPILL AND DISPOSAL PRECAUTION IF MATERIAL IS SPILLED OR RELEASED: Stop leak. Dam up area of spill. Dry floor with absorbent. Shovel into metal or plastic lined containers. Keep area clear of traffic as the floor will be extremely slippery. Clean area with usual. floor cleaner. WASTE DISPOSAL METHOD: Dispose according to Local,, State & Federal: regulations. SECTION IX -COMPONENTS COMPONENT NAME CAS No. HAZARDOUS SUBSTANCE # COMPOSITION. ADVISORY AMOUNT - (Wt.) Tetrasodium EDTA 64-02-8 1-1.0% Potassium Soaps 143-18-0 10-25%. NOTE: -This product contains no levels of listed substances, which the State of California has found to cause" cancer, birth defects or other"reproductive harm, which would require a warning under the statute. " #Listed by: 1=0SHA (air) 2=0SHA (regulated substance) 3=NTP (carcinogens)` 4=ACGIH (chemicals) 5=1ARC (human carcinogens) . SECTION X -PHYSICAL AND CHEMICAL DATA BOILING POINT: >220°F VISCOSITY UNITS, TEMP. (METHOD): N / AP FREEZING POINT: 32°F VAPOR PRESSURE:. Unknown SPECIFIC GRAVITY (H2O=1): 1.056 VAPOR DENSITY (Air=1@60-90°F): Unknown STABILITY:. Stable SOLUBILITY IN WATER: Complete pH-concentrate 10.5+/-0.5 pH-dilute 8.0-10.0 HAZARDOUS POLYMERIZATION: Will not occur.. EVAPORATION RATE: <water APPEARANCE AND ODOR:. Amber viscous liquid.,, mild odor. MATERIALS TO AVOID: Strong, Oxidizing Agents. HAZARDOUS DECOMPOSITION: Carbon Monoxide, Carbon Dioxide SECTION XI -ADDITIONAL PRECAUTIONS HANDLING, STORAGE AND DECONTAMINATION PROCEDURES: Do not allow the product to freeze. Keep the container closed to avoid contamination. The information in this MSDS was obtained from sources which we believe are reliable. however, the information is provided without any ~`... warranty, expressed or implied, regarding .its correctness. The conditions or methods of handling, storage, use and disposal of the product are . beyond our control and may be beyond our knowledge. For this and other reasons, Argo Chemical Inc. does not assumes responsibility and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with the handling storage, use or disposal of the product. ' Chain Lube H-2 MSDS 2 Revised 6-2005 100 Quantico Ave. Bakersfield, CA 93307 Phone: (661) 322-2222. Fax: (661)-322-2303 " ~ QaS~gIE DISIR~BG _ ~ _ . . CommodilyChemicals-LaboralorySeruices&Products• ~ ro Mini-BulkDeliverySyslems-WaterTreaimehiChemicals- FillralionEquipmentiiMedia•Food Processing Compounds ~ e . s ChemlcalCleaners•Chlorinatlon,UVrKOzone " ~' 'OOQuanticoAve.. Bakersfield CA 93307 ~ Phone: 661322.2222 " ergo~argocfiem.com ~ Faz:661322.2303 MATERIAL SAFETY DATA SHEET Bromine Tablets . 1. CHEMICAL PRODUCT AND COMPANY LDENTIFICATION ~ PRODUCT NAME: Bromine Tablets CHEMICAL FAMILY: Halogenated hydantoin DISTRIBUTOR:, Argo Chemical, Inc. 1.00 Quantico Ave. Bakersfield, CA 93307 " 661 322-2222 ( ) ' 24 HR. EMERGENCY TELEPHONE NUM'B'ERS: . ` CHEMTREC (Transportation,) (800') 424-9300 ' ` Poison Control Center (Medical)(877) 800-5553 ' COMMENTS: EPA Registration Number: 5185-420 2. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS# Wt.% 1-bromo-3-chloro-5,5-dimethylhydantoin 1 6079-88-2 96 ~_ ~ COMMENTS: Available Bromine: 63.5% /Available Chlorine: 28.2% " +' . ' 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW- PHYSICAL APPEARANCE: White tablets with halogen odor. IMMEDIATE CONCERNS: DANGER: Highly Corrosive: Causes skin and eye damage. May be fatale if swallowed". Do not get in eyes, on skin,. or on clothing.. Wear goggles or safety glasses and rubber gloves when handling this product. Irritating to nose and throat. Avoid breathing dust and fumes. Remove contaminated clothing and wash before reuse. POTENTIAL HEALTH EFFECTS EYES: DANGER: Highly Corrosive. Causes eye damage. Do not get in eyes. SKIN: DANGER: Highly Corrosive. Causes skin damage. Do not get on skin: INGESTION: May be fatal if swallowed. INHALATION: Irritating to nose and throat. Avoid breathing dust or fumes. 'MEDICAL CONDITIONS AGGRAVATED: Existing dermatitis may be aggravated by exposure. ROUTES OF ENTRY: Skin Contact, Inhalation, Ingestion, Eye Contact. COMMENTS HEALTH: There are no known chronic hazards. 4. FIRST AID MEASURES "EYES:. If contact with eyes occurs: Immediately flush with cold water for at least 15 minutes. Then get ~~ - immediate medical attention. SKIN: If contact with skin: Brush off excess chemical and flush skin with. cold water for at least 15 minutes. If irritation persists, get medical attention. l .. ~, INGESTION: If swallowed: Drink large amounts of water: Do not induce vomiting. Avoid alcohol. NEVER . . ~ GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Call a physician or poison '~ control center immediately.: ' INHALATION: If, inhaled: Remove to fresh air. If breathing is difficult, have trained person admihister oxygen. tf not breathing, give artificial respiration. Call a physician immediately. NOTES TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. i - 5. FIRE FIGHTING MEASURES GENERAL HAZARD; In.large fires fueled by other materials, this product may smolder for prolonged periods emitting a dense black smoke. Any spilled, material should be considered contaminated. Neutralize to anon-oxidizing material. for safe disposal': Material which appears. undamaged ',except for being.. damp on the. outside, should be opened and. inspected immediately: If the material is damp, if should be neutralized to anon-oxidizing material forsafe disposal. EXTINGUISHING MEDIA: In case of fire or smoke, call.the fire department. Do not attempt to extinguish the fire'without aself-contained .breathing apparatus (SCBA). Do not let the fire burn. Flood with copious amounts of water. DO NOT use ABC or other dry chemical extinguishers since there is the potential for a violent reaction. ~ • EXPLOSION HAZARDS: A dust explosion severity determination was performed using the Hartmann Dust Explosibility Bomb designed at the U.S: Bureau of Mines. The .product was determined not to be ignitable. •. FIRE FIGHTING., PROCEDURES: ~ Fires .fueled by other materials may release. hydrogen bromide, ,, bromine, hydrogen chloride or chlorine. Wear ,self-contained breathing apparatus. Ammonium phosphate (ABC) fire extinguishers should.not be used. 6. ~4CCIDENTAL RELEASE MEASURES `GENERAL PROCEDURES:. STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: ~_ Using appropriate protective clothing and safety equipment, contain spilled material. Do not add water to spilled material. Using clean dedicated equipment, sweep and scoop all spilled material, contaminated. soil, and other contaminated. material and place into clean dry. containers for disposal. Do not use floor-sweeping compounds to clean up spills. Do not. close containers containing wet or damp material. They should be left open to disperse any hazardous gases that may form. Do-not .transport wet or damp material.. Keep product out of sewers, watersheds and water systems. Do not contaminate water, food, or feed by storage, disposal. or cleaning of equipment. Dispose of according. to local, state and federal regulations. 7. HANDLING AND STORAGE ~~ ~ ~ ~ ~ ~ ~ ~ . HANDLING: STRONG OXIDIZING AGENT: Do not mix with other chemicals.. Mix only with water. Never add water to product. Always add product to large quantities of water. Use clean dry utensils. Do not add this product to any dispensing device containing remnants of any other product. Such use. may. cause a violent reaction leading. to fire, or explosion. Contamination with moisture, organic matter or other chemicals will start. a chemical reaction and generate heat, hazardous gas, possible fire and explosion. Incase of contamination or decomposition, do not reseal container. If possible, ,isolate -container in open air or well ventilated area. Flood area with large volumes of water. , STORAGE:. Keep this product in original tightly closed container when not in use. Store in a cool, dry, well ventilated area away from heat or open flame. Moisture may decompose .this product and cause a violent reaction leading to fire and explosion. In case of decomposition, isolate container if ,possible and flood area with large amounts of water to dissolve all materials before discarding this container. Do not contaminate food or feed by storage or disposal. Do not reuse container, but place in trash collection. Rinse thoroughly before discarding in trash. 8. EXPOSURE CONTROLS /PERSONAL PROTECTION ~, EXPOSURE GUIDELINES: OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) 2 II .. ,. ( ~ ` +Y~ .. i .F. EXPOSURE LIMITS OSHA PEL ACGIH TLV SUPPLIER OEL ~' ppm" mg%ms ppm mg/ms ppm mg/ma 1-bromo-3-chloro-5,5-dimethylhydantoin TWA N/EhI N/E OSHA TABLE COMMENTS: 1. N/E =Not Established ENGINEERING CONTROLS: General room ventilation plus local exhaust should 'be used to minimize exposure to dust/vapors. PERSONAL PROTECTIVE EQUIPMENT: EYES-AND FACE: Wear goggles or safety glasses with side shields when, handling this product. SKIN: ,Wear rubber gloves when handling this product. Avoid contact with skin. RESPIRATORY: A respiratory protection program. that meets OSHA 1910.134 and ANSI 288.2 ` requirements must be followed whenever workplace conditions warrant a respirator's use: ` WORK HYGIENIC PRACTICES: Remove and wash contaminated clothing before reuse. OTHER USE PRECAUTIONS: Facilities storing `or -utilizing this material should be equipped with an eyewash and. safety shower. 9. PHYSICAL AND CHEMICAL PROPERTIES ~ , PHYSICAL STATE:. Solid , ~ ODOR: Faint halogen odor: APPEARANCE: Tablet COLOR: White pH: 4.5(0.1 % solution in DI water), VAPOR PRESSURE: Not Applicable , - VAPOR DENSITY: Not Determined BOILING POINT: Not Applicable MELTING POINT: With Decomposition THERMAL DECOMPOSITION: 145°C to 150°C SOLUBILITY IN WATER: 0.15g/100g water DENSITY: 60.1 Ib/ft3 10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: High temperature. Poor ventilation. Contamination. Moisture/high humidity. STABILITY: This product is stable under normal conditions: "" ~~ POLYMERIZATION: Hazardous polymerization will not occur under normal conditions: HAZARDOUS DECOMPOSITION PRODUCTS: Hydrogen bromide, bromine, hydrogen chloride; - ~ ~~ chlorine. ~ INCOMPATIBLE MATERIALS: Avoid contact with water on concentrated material in the container. Avoid contact with easily oxidizable material; ammonia, urea, or similar nitrogen containing compounds; inorganic reducing compounds; floor sweeping compounds;. calcium hypochlorite; other swimming pool/spa chemicals in their concentrated form; alkalis. Avoid contact with all other chemicals. ~ ~~ ~ ~ ~ ~~ 11. TOXICOLOGICAL INFORMATION. ACUTE EYES: Toxicological studies indicate this product to be corrosive to eyes., ' DERMAL LDso: The dermal LD50 is greater than 2.0 g/kg (rabbit): The primary skin irritation index " is 6.1 and the product is considered corrosive to skin. ORAL LDso: 578 mg/kg (rat). . CARCINOGENICITY: This product is not listed as a carcinogen by IARC. This product is not listed as a carcinogen by NTP. This product is not listed as a carcinogen by OSHA. 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION:. This pesticide is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into lakes, streams, ponds or estuaries, oceans, or their waters unless in accordance with the requirements of a National Pollutant Discharge Elimination " System (NPDES) permit and the permitting authority has been notified in writing prior to ' discharge. Do not discharge effluenf containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. 3 ":' ,:'' _ -~'•: ' 13. DISPOSAL CONSIDERATIONS . ~ DISPOSAL. METHOD: Pesticide- wastes are toxic. Improper disposal of excess pesficide or rinsate is a" ~ : , ; ,violation of Federal Law. If these wastes cannot be disposed of by use according; to label instructions, contact your State Pesticide 'or Environmental Control Agency or the Hazardous -" Waste Representative at the nearest EPA Regional Office for guidance.' Do not contaminate-. : „ - . water, food, oc feed by storage or disposal or cleaning of equipment. Do not put. product; spilled• ,product; or filled or"partially filled containers into the trash or waste compactor. Contact with. incompatible materials, could cause a reaction or fire: EMPTY CONTAINER: Do not reuse container'. Rinse thoroughly before discarding, in trash: ` 14. TRANSPORT INFORMATION. „ DOT (DEPARTMENT OF TRANSPORTATION) . ` PROPER SHIPPING NAME: Oxidizing Solid, N.O.S. (Bromo-chloro-dimethylhydantoin) PRIMARY HAZARD CLASS/DIVISION: 5,1 , UN/NA NUMBER: 1479 " PACKING GROUP: II . " " ~. ~ ' 15: REGULATORY INFORMATION , . UNITED STATES SARA TITLE Ill (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) ~ '. 313 REPORTABLE INGREDIENTS:. This product or its components are not listed: . CERCLA (COMPREHENSIVE RESPONSE; COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: This product or its components are not listed. ~ ~""- TSCA (TOXIC SUBSTANCE CONTROL ACT) ~" TSCA REGULATORY: This product or its components are not subject to export notification.. TSCA STATUS: This product or its components are listed on the TSCA Inventory.. OSHA HAZARD COMM. RULE: Product is hazardous by definition of the Hazardous Communication Standard.- i CLEAN WATER ACT: Not Listed. ' FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): This product is a i~ registered pesticide.. SDWA (SAFE DRINKING WATER ACT): Not listed. . CLEAN AIR ACT 40 CFR PART 68=RISK MANAGEMENT FOR CHEMICAL ACCIDENT RELEASE PREVENTION: Not listed. STATE REGULATIONS .PROPOSITION 65 STATEMENT: This product oc .its components are not listed on any Proposition 65 lists of carcinogens or reproductive toxicants. 16. OTHER INFORMATION NFPA CODES HEALTH: 3FIRE: 1REACTIVITY: 1 - ' NFPA STORAGE CLASSIFICATION: NFPA Oxidizer Class. 2 - HMIS CODES HEALTH: 3 FIRE: 1 ,REACTIVITY: 1 PROTECTION.: B DISTRIBUTOR'S DISCLAIMER: ' " IMPORTANT: This information is given without a warranty, or guarantee. No suggestions for use are intended or shall be construed as a recommendation to infringe any existing 'patents 'or violate any Federal, State or local laws. Safe handling and use is the responsibility of the customer: Read the label before using this product. -This information is true and accurate to the best of our knowledge. . 4 ,: , ,.. u tip, . ' ~ oaS\glE DISTipjBG - A CommodilyChemicals-LaboratoryServicesBProducts- Q ro Mini-aulk0eliveryliystems WaterTrealmeniChemicals- ~ FilfrationEquipmenl&Media•foodProcessingCompounds ~' ~ . m ChemlcalCleaners•Chlarinallan,UV80mne ~'~ '90QuanticoAve. Bakersfield CA 93301 ~ Phone: 661322.2222 ' argo~argochem.com Falc:661322.2303 ., MATERIAL SAFETY DATA SHEET CfP -ACLD - P . General Information Distributor's Name: ARGO CHEMICAL, INC. . Distributor's Address: 100 QUANTICO AVE., BAKERSFIELD, CA 93307 " Distributor's Emergency Ph #: (661) 322-2222 CH EMTREC: 800-424-9300 Distributor's Info Ph #: (661) 322-2222 i Ingredients/Identity Information - . ~: ( Proprietary: MIXTURE Ingredients: PHOSPHORIC ACID (SARA III) <40% ~~ Surfactants Water N1OSH "(RTECS) Number: TB6300000 CAS Number: 7664-38-2 OSHA PEL: 1 MG/M3 ACGIH TLV: 1 MG/M3/3 STEL; 9394 Other Recommended Limit: NONE RECOMMENDED i Physical/Chemical Characteristics , Appearance And Odor: CLEAR; COLORLESS TO STRAW COLORED, SYRUPY LIQUID - NO ODOR Boiling Point: <275F',135C Melting Point: " >OF,-18C Vapor Pressure (MM Hg/70 F): UNKNOWN Vapor Density (Air=1): UNKNOWN Specific Gravity:. 1.12 Decomposition Temperature: UNKNOWN Evaporation Rate And Ref: UNKNOWN Solubility In Water: 100% ' Viscosity: UNKNOWN pH: 2 (1%) '' Corrosion. Rate (IPY): UNKNOWN 1.. ` -- ` . ~ p+ MATERIAL SAFETY ®ATA SHEET '~ ~ ~ ~ .. . " ~ ~ ~ ~ ~-CIP~-ACID - P. ~ ~ , Fire and Explosion Hazard Data' Flash Point: NONE ' Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL FOR SURROUNDING FIRE. USE WATER, SPRAY TO COOL FIRE EXPOSED CONTAINERS. . Special Fire,. Fighting Procedures: WEAR FIRE- FIGHTING PROTECTIVE EQUIPMENT SUCH AS GLOVES, HOOD$,. SUITS, RUBBER BOOTS AND ,A, NIOSH-APPROVED FULL-FACE SELF CONTAINED BREATHING APPARATUS. Unusual. Fire And Explosion Hazards: CAN REACT WITH. COMMON METALS TO~ LIBERATE,- FLAMMABLE VE HYDR EN GAS'.. MAY FORM: HAZARDOUS FUMES SUCH AS AND 'POTENTIALLY EXPLOSJ OG -PHOSPHORUS OXIDE. ; Reactivity Data " Stability: YES , Conditions To Avoid' (Stability):. MOISTURE ' Materials To Avoid: STRONG ALKALIES, METALS, WATER Hazardous Decomposition Products: TOXIC FUMES.OF PHOSPHORUS PENTOXIDE Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT " Health Hazard Data LD50-LC50 Mixture: LD50 (ORAL, RAT) IS 1530 MG/KG, Route Of Entry -Inhalation: NO Route Of Entry -Skin: NO' Route Of Entry'-ingestion: YES Health Hazard Acute And Chronic:, ACUTE- EYE CONTACT. MAY CAUSE SEVERE IRRITATION. & BURNS. MAY CAUSE PERMANENT EYE ..DAMAGE.. CORROSIVE TO SKIN. INHALING MISTNAPORS MAY CAUSE RESPIRATORY IRRITATION. INGESTION MAY CAUSE SEVERE IRRITATION. & BURNS TO THE MOUTH, THROAT & DIGESTIVE TRACT. CHRONIC- UNKNOWN. TARGET ORGANS:. SKIN, EYES, RESPIRATORY & GI TRACTS. Carcinogenicity - NTP: NO Carcinogenicity - IARC: NO Carcinogenicity -OSHA: NO Explanation Carcinogenicity: NONE Signs/Symptoms Of Overexposure: SEVERE EYES, SKIN, RESPIRATORY AND' DIGESTIVE TRACTS IRRITATION AND BURNS, DIFFICULTY IN BREATHING, PAIN, NAUSEA, VOMITING Medical Conditions Aggravated By Exposure: SKIN IRRITATION MAY BE AGGRAVATED IN PERSONS WITH EXISTING SKIN LESIONS. MISTS MAY AGGRAVATE ACUTE OR CHRONIC ASTHMA OR' OTHER RESPIRATORY DISEASES. IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD EYELIDS OPEN. INHALED: REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED: ORAL:. DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK SEVERAL GLASSES OF WATER/MILK. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. .2 ..Precautions for Safe Handling and. Use Steps If Material Released/Spill: WEAR PROTECTIVE EQUIPMENTS INCLUDdNG RESPIRATOR FOR ACID MISTS. DIKE SPILL WITH SAND OR CLAY 70 KEEP IT OUT OF SEWER SYSTEM. NEUTRALIZE WITH SODA ASH. REQUIRES GOOD VENTILATION. AS C02 IS PRODUCED. PLACE. NEUTRALIZED SPILL IN DOT APPROVED CONTAINER: - ' . Neutralizing, Agent:, SODA ASH ` Waste Disposal Method: DISPOSAL- SHOULD BE MADE IN ACCORDANCE .WITH. ALL APPLICABLE , FEDERAL; STATE-AND LOCAL LAWS AND REGULATIONS. REPORTABLE QUANTITY (RQ) 1S 5000 ' . ~ ' LBS. NATIONAL RESPONSE CENTER PHONE #: 800-424=8802. THIS- MATERIAL IS A RCRA ~, -. HAZARDOUS WASTE D002, CORROSIVE. " Precautions-Handling/Storing: STORE IN CLOSED CONTAINERS AWAY FROM HEAT & INCOMPATIBLE ' - . MATERIALS: STORAGE, ,AREA SHOULD HAVE ADEQUATE DRAINAGE.; DO NOT REUSE CONTAINERS. . „ Other Precautions: KEEP OUT OF "REACH OF CHILDREN. DO NOT GET IN EYES,. ON SKIN OR ON ' CLOTHING. AVOID BREATHING MISTS OR VAPORS. WASH THOROUGHLY AFTER .HANDLING. DO NOT INGEST: ~~ ~ ~ Confrol~ Measures Respiratory.Protection: USE A iVIOSH-APPROVED RESPIRATOR FOR ACID MISTS WHEN HANDLING ~! SPILLS, LEAKS OR WHEN AIRBORNE CONCENTRATIONS EXCEED EXPOSURE LIMITS. Ventilation: PROVIDE SUFFICIENT GENERAL OR LOCAL EXHAUST VENTILATION TO CONTROL INHALATION EXPOSURES BELOW OSHA'S PEL. Protective Gloves: NEOPRENE OR RUBBER .Eye Protection: SAFETY GOGGLES & FACE SHIELD Other Protective Equipment: EYE WASH STATION & EMERGENCY SHOWER SHOULD BE IN CLOSE ' PROXIMITY. 'USE OF RUBBERIZED COVERALLS & RUBBER SHOES SUGGESTED. ' ` Work-Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED ' PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Transportation Data DOT"Proper Shipping Name: PHOSPHORIC ACID , DOT Class: 8 DOT ID Number: UN1805 DOT Pack Group: III DOT.Label: CORROSIVE., FOOT NOTES: The information contained herein is based on the data available to us and is believed to be correct. However, Argo Chemical Inc.; ;, 'makes no expressed or implied warranty regarding the accuracy of this data or the results to be obtained from their use. Argo Chemical Inc. assumes no responsibility for injury from the use of the product described herein ' Revised 6-2005" . 3 g~BIE DIST,p/ CommodilyChemicals-LaboralorySerrices6Producfs• ~°a BG~io Mini-BulkDeliverySystems-Waler3ealmentChemicals- ~ ~~ ~, Flllratlon Equipment $ Media • Food Processing Compounds ~ e . s Chemical Cleaners • Chlorlnalion, UVfl Done • ,~ ~"9QuanlicoAue. Bakersfield CA 93307 ~ Phone: 661322.2222 ` .,go(~argochem.com Faz:661322.2303 MATERIAL SAFETY DATA SHEET SAFE DEGREASER GENERAL INFORMATION i Company's Name: Argo Chemical, Inc. Company's Address: ,10.0 Quantico Ave.., Bakersfield, CA 93307 Company's Information Phone: 661 322-2222 Emergency Phone; CHEMTREC 800 424-9300 HMiS Information: Health: 1 Flammability: 0 Reactive: 1 Protection: B '. INGREDIENTS /IDENTITY INFORMATION Ingredient: Water Proprietary: No Percent: 50 - 80 NIOSH (RTECS) Number: ZC0110000 i CAS #:. 7732=18-5 OSHA PEL: Not Established, ACGIH-TLV: Not Established Other Recommended Limit: None Specified ' Ingredient: Dipropylene Glycol, Monomethyl Ether: (Dipropylene Glycol Methyl Ether) ~ P,% `ietary: No Pte, ,ant: 5 -15 N10SH (RTECS) Number:. JM1575000 '; CAS #: 34'590-94-8 OSHA PEL: S, 100 PPM - ACGIH TLV: S; 100 PPM%150 STEL:95 Other Recommended Limit: 100 PPM Ingredient: Sodium Metasilicate ~ . Proprietary:. No ~ . Percent: 2 =10 3 CAS #: 6834-92-0 ACGIH TLV: 2 MG/M3 Ingredient:, Sodium Tripolyphosphate Proprietary:.No ~, Percent: 2' -10 ' CAS #: 7758-29-4 ACGIH TLV: Not Established Ingredient: Diammonium EDTA Proprietary: No Percent: ' 4 -10 , ' • CAS #: 20824-56-0 ACGIH TLV: Not Established. Ingredient: Lauramine Oxide Proprietary: No Percent: 4 - 10 ` CP ~ #: N/A A~~. =1 TLV: Not Established NIOSH (RTECS) Number:.W9275000 OSHA PEL: Not Established. Other Recommended Limit: None Specified NIOSH (RTECS) Number: YK4570000 OSHA PEL: Not Established Other Recommended Limit: None Specified NIOSH (RTECS) Number: OSHA PEL: Not Established Other Recommended Limit: None Specified NIOSH (RTECS) Number: OSHA PEL: Not Established Other Recommended Limit: None Specified Safe Degreaser MSDS 1 Revised 4-2004 100 Quantico Ave. Bakersfield, CA 93307 Phone: (661) 322-2222 Fax: (661) 322.2303 k `" ~ PHYSICAL/ CHEMICAL CHARACTERISTICS Appearance and Odor:. C{ear Red Liquid, Mild Odor Boiling Point: 215°F, 102°G Vapor Pressure (MM Hg/70° F): ~ 17.0 @ 20° C . Vapor Density (Air=1): NA ,Evaporation Rate and. Ref: >1' (Butyl-Acetate) Speciflc.Gravity: 1.1 Percent Volatifes by Volume: ,75%~ Solubility in Water: Complete FIRE AND EXPLOSION HAZARD DATA " Flash Point: None Lower Explosive Limit: N/A - Upper Explosive Limit: N/A Extinguishing Media:. C02, Foam, Dry Chemicals Special Fire Fighting Proc: Use NIOSH/MSHA approved SCBA & full protective equipment. Unusual Fire and Explosive Hazards: None REACTIVITY DATA Stability: Yes • Conditions to Avoid: Nane Specified 'Materials to Avoid: Petroleum Solvents and Concentrated Acids ! Hazardous Decomposition Products: CO, S02, with incomplete combustion. Hazardous Poly Occur: No • HEALTH HAZARD DATA __ R~~ ,''of Entry: Inhalation: Yes -Skin: No ingestion: Yes " '. Healfh Hazards Acute and' Chronic: Acute: Defats skin, may irritate eyes. Prolonged eye contact may cause eye damage. Chronic: Same as acute. Carcinogenicity-NTP: No Carcinogenicity - IARC: No . Carcinogenicity - OSHA:. No Explanation Carcinogenicity: Not Relevant ` Signs/Symptoms of Overexposure: Irritation, possible vomiting and diarrhea. ~ Medical Conditions Aggravated by Exposure: Sensitive skin .and eyes ' t Emergency/First Aid Procedures: Inhalation: Remove to Fresh Air ~. Eyes: Flush thoroughly with fresh water, for at least 15 minutes. Get medical attention. Skin: Flush with fresh water, wash with soap and water, remove contaminated clothes and shoes. Ingestion: ,Give water, do not induce vomiting., Get medical attention. Never give anything by mouth to an unconscious person,. PRECAUTIONS FOR SAFE HANDLING AND USE ;Steps if material released/spilled; Wipe up small amounts or flush to drain; collect and return large amounts to container. Neutralizing Agent:. None specified. ,Waste Disposal Method: pH adjustment: Contains phosphates. Use until <1 inch remains in container, empty container. Triple rinse with water, dispose to industrial/sanitary sewer. Remove/deface label before disposing of container. ;Precautions -Handling/Storing: Keep container closed when not in use. Keep from freezing. Do not pressurize container to - empty. O~ Precautions: DOT Class: Not regulated. Safe Degreaser MSDS 2 Revised 4-2004 100 Quantico Ave. Bakersfield, CA 93307 Phone: (661) 322-2222 Fax: (661) 322-2303 ' i ~ j~ . ~1 ` °~ CONTROL MEASURES -~ Respiratory Protection:; None. NIOSH/MSHA approved respirator appropriate for exposure of concern. , Ventilation: Mechanical normal air dilution. Protective Gloves: Rubber of chemical resistant. Eye Protection: ANSI approved chemical workers goggles. Other Protective Equipment: Eye wash fountain and deluge shower which meet ANSI design criteria. Work Hygienic Practices: Keep food away. Wash hands and face before eating. Supplemental. Safety & Health Data: Waste disposal method: Disposal must be in accordance with Federal, State and Local ' regulations. ' TRANSPORTATION DATA . DISPOSAL DATA ~~ Disposal must tie in accordance with Federal, State and Local regulations. i LABEL DATA i Label Required: Yes Label Status: G ', Common Name: Degreaser Chronic Hazard: Yes Signal Word: WARNING! Acute Health Hazard -Moderate Contac Hazard.- Moderate Fire Hazard -None Reactivity Hazard -None Special Hazard Precautions: Acute: Defats skin, may irritate eyes. Prolonged eye contact may cause eye damage. Chronic: Sa-*?e as acute.. P~ :t Eyes: ~ Y Protect Skin:. Y Protect Respiratory: Y Label Name: Safe Soap . ' Label City: Bakersfield, CA 93307 Label Emergency Number: CHEMTREC 800 424-9300 i To actual knowledge, the information contained herein is accurate as of the date of this document. However, neither Argo Chemical, Inc. or-its affiliates or employees makes wa ,express or implied, or accepts any liability in connection with this information or its use. This information is for use by technically skilled persons at their own discretion and r and ~„es not relate to the use of this material in combination with any other substance or process. This is not a license under any patent or proprietary right. The user alone must fins determine suitability of any information or material for any contemplated use, the manner of use and whether any patents or intellectual property rights are infringed: Safe Degreaser MSDS 3 Revised 4-2004 100 Quantico Ave. Bakersfield, CA 93307 Phone: (661) 322-2222 Fax: (661) 322-2303 03/13/2006 12:50 6613876807 MELO'S GAS & GEAR /~' ~AIR LIQ~UIDEI N.'1 - MATERIAL SAFETY PAGE 01 ~- ~ , f _, } DATA SHEET Prepared !a U.S. OSHA, CMA, ~41VSt and Canadian WNMlS S'tandard's 1. PROQUCT r4ND COMPANY INFORMATION CHEMICAL NAIVIE; CLASS: NON-FLA~UlMABLE CAS MIXTURE LASAL iV~IXTURES~ 150. P154, 15,154, 155 Containing Hydrogen (~ 4%), Carbon Monoxide rL 5%), Carbon Dioxld~e (6-9%), Nitrogen ('12-18%) and Heliumi (Balance) SYNONYMS: Not Applicable . CHEMICAL f=A,MILY: Not Applicable FORMULA: Not Applicable taSAL (The Perfeck Combination) The Pertect'Combinatian oFlaser equipmaflt and ggs is the secret Of your succ~. lasing gas conin'hules to the power of your laser and stablized th® beam, allowing you tc tap your !seer's toll potenlisl while minimizing the risk bf damage to your equipment !~ASAL is a range of research-backed gases that will help °ur ~ustomera achlEVe a superior return on invastrnent. SpeGally blended, appUcation- proven, L./1SAL gases are manufactured to the same precision standards ss laser devices. L14SAL, gases help asswre maximum power output and deem sia0ntry wru~e mcreasing the Ure t7I OpDGB Bt1U eleCWOaS. .PRODUCT USE: MANUFACTURED/SUPPLIED FOR: ADDRESS: 'EMERGENCY PHONE: .BUSINESS PHONE: pocument Number: 10053 For use in laser operations. ASR LIC~lJIDE 2700 Post Oak Drive Houston, TX 77056-$223 CHEMTREC: 1-800-4249300 General MSDS Information 1-713!866-Z8g6 Faxon Demand: 1 ~800l231 ~ 1366 ~ASw GP S _~_r__ LASAL MIXTURES 150, P150, 152,154,155 (10053) MSDS EFFECrNE DATE: AUGUST 31, 2005 PAGE 1 Of+ 10 03/13/2006 12:50 6613876807 MELO'S GAS & GEAR PAGE 02 2. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: This is a colorless, nonflammable gas mixture which is odorless or which has an acrid odor (due to the presence of Carbon Dioxide). Exposure to Carbon Monoxide (a componenk of this gas mixture} is harmful in relatively low concentrations, and severe over-exposures can cause headaches, nausea, collapse, and death. Other potential h®alth hazards associated with this gas mixture include oxygen deprivation and over-exposure to Carbon Dioxide (which can result in dizziness, breathing rate increase, nausea, dizzlness, headache, mental confusion, increased blood pressure and respiratory rate}. Carbon Monoxide is a reproductive toxin. A cylinder rupture hazard exists when this gas mixture, which is under pressure, is sub)ect to heat or flames. SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The most significant mute of over-exposure for this gas mixture is by inhalation. The following paragraphs describe the symptoms of exposure, via route of entry. INHALATION: One of the most significant hazards associated with this gas mixture is the potential for over- exposure to Carbon Monoxide. Inhalation of Carbon Monoxide can be harmful in relatively low concentrations. Severe over-exposures may be fatal. Effects of exposure to Carbon Monoxide can be summarized as follows: CARBON MONOXIDE CONCENTRATION SYMPTOM OF EXPOSURE All exposure levels: Overexposure to Carbon Monoxide can be indicated by the IilJ.s and fingernails turning red. 200 ppm: Slight symptoms (headache, discomfort) after several hours of exposure. 400 ppm: Headache and discomfort experienced within 2-3 hours of exposure. 1,000 -2000 ppm: Within 30 minutes, slight palpitations of the heart occurs. Within 1.5 hours, there is a tendency to stagger. V1Fthin Z hours, there is mental confusion, headaches, and nausea. 200-2500 ppm: Unconsciousness within 30 minutes. >2500 ppm: Potential for collapse and death before warning symptoms are pt'vduced. Carbon Dioxide, another component of this gas mixture, is an asphyxiant and a powerful cerebral vasodilator. If the ooncentra6on of Carbon Dioxide reaches 10°!0 or more, suffocation can occur within minutes. At concentrations between 2 and 10%, Carbon bioxide can cause nausea, dizziness, headache, mental confusion, increased blood pressure and respiratory rate. Carbon Dioxide initially stimulates respiration and Then causes respiratory depression. High concentrations result in narcosis. Repeated inhalation of low concentrations (3-5%) have no known permanent harmful effects. This gas mixture can also cause symptoms of oxygen deprivation (asphyxiation) when present in high enough concentrations to significantly lower oxygen concentration. Individuals breathing such an atmosphere may experience symptoms which include headaches, ringing in ears, dizziness, drowsiness, unconsciousness, nausea, vomiting, and depression of all the senses. It should be noted that before adverse health affects or suffocation could occur the effects of overexposure to Carbon Monoxide or Carbon Dioxide may be felt. OTWER POTENTIAL HEALTH EFFECTS: Moisture in the air could lead to the formation of carbonic acid from the Carbon Dioxide present in this gas mixture, which can be irritating to the eyes. HEAI.TW EFFECTS OR RISKS FROM EXPOSURE: An Explanatia» in Lay Terms. Over-exposure to this gas mixture may cause the following health effects. ACUTE: Inhalation of this gas mixture can be harmful or fatal. Symptoms of over-exposure can include respiratory difficulty, headaches, shortness of breath, wheezing, headache, dizziness, indigestion, nausea, and Ilps and fingernails turning cherry red. At high concentrations, unconsciousness or death may obcur. Contact with rapidly expanding gases (which are released under high pressure) may cause frostbite. CHRONIC: Carbon Monoxide is a reproductive taxis. Refer tv Section 11 (Toxicological Infomtaflon) of this MSOS for further information. TARGET ORGANS: ACUTE: Respiratory system, blood system, cardiovascular system. CHRONIC; Reproductive system. I,ASAL MIXTURES 150, P150,152,154,155 (10053 MSDS I;FFECT'IVE DATE: AUOUS7 31, 2005 PAGE 2 OF 10 03/13/2006 12:50 6613876807 MELO'S GAS & GEAR PAGE 03 3. COMPQSITION and IMFORIIII,ATIDN ON IP+IGREC~IENTS CHEMICAI. NAME CAS # mole ~/° EXPOSURE LIMITS IN AIR ACGIH OSHA NIOSH OTHER T>,v STEL PEL STEL IDLH m m m m m m Flydrogen 1333-T4.0 ~ 4°,6 There are no spaafio exposure limits far Hydrogen; it is a simple asphyxiant (SA). Oxygen levels should be maintained above 19,5%. Carbon Monoxide 630-08-0 < 5% 25 NE 50 200 (ceiling} 1200 NIQSH REL: 35 (vacated TWA ~ 35 (Vacated 7989 PEL} STEL = 200 (ceilins1 1989 PEL) bFG MAK,4: TWA = 30 PEAK = 2•MAK 30 min., avers a value Carbon D(oxide 124.9&9 8.9~/° 500D 30,000 5D00 4D.D00 NIOSH REL: 10.040 30,000 TWA = 5000 (Vacated (Vacated STEL = 30,000 (coiling) 1989 PEL) 1989 PEL} bFG-MAK: TWA = 540D PEAR = 2.MAK 10 min., momentary value Nitrogen 7727-37-9 1Z-18rye There Are no specific exposure limits for Nitrog®n; it is a slmpla asphyxiant (SA). Oxygen levels should be maintained above 19,5%, Helium 7440.59-7 Balance Th®re are no speclilc oxposure limito for Helium. hlelium i5 a simple asphyxiant (SA). Oxygen levels should be maintained above 19.5, This nnlaterial is classified as hazardous under OSHA regulations in khe Uniked States and the WHMIS in Canada. NE = Not Eatabliahsd. See Section 16 for Definitions of Tenns Used. NOTE (1): ALL WHMIS n?quired information is included in appropriate sections based on the ANSI 2400.1.2004 format. This product has bean classlfled In accordance with the hazard cri#eria of the CPR and the MSbS contains ail the information required by the CPR. 4 FIRST-AID MEASURES RESCUERS SHOULD NOT ATTEMPT TO RETRIEVE VICTIMS pl= EXP05URE TD THIS GAS MIXTURE WITHOUT ADEQUATE PERSONAL PROTECTIVE EQUIPMENT. At a minimum, Self Contained Breathing Apparatus must be worn. Remove victim(s) to fresh air as quickly as possible. Only trained personnel should administer supplemental oxygen and/or cardio-pulmonary resuscitation, ii necessary, Victim(s) must be taken for medical attention. Rescuers should be taken for medical attention if necessary. Take copy of label and MSDS to physician or other healti, professional with victim{s). MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing respiratory or cardiovascular conditions may b® aggravated by overexposure to this product RECOMMENDATIpNS TO PHYSICIANS: Administer oxygen, if necessary; treat sympt~ims; eliminate exposure. Treat for Carbon Monoxide poisoning as necessary. 5. FIRE-FIGHTING MEASURES FLASH POINT; Not applicable. AUTO1Gf~lITION TEMPERATURE: Not applicable. FLAMMABLE LIMITS (In air py volum®, %); Lower (LEL1: Not applicable. UtiDer (UELl: Not applicable, FIRE EXTINGUISHING MATERIALS: Use extinguishing media appropriate for surrounding tire. UNUSUAL FIRE AND EXPt,pSION iiA7.ARDS: This gas mixture do®s not bum; however, containers, when involved in fire, may rupture or burst in the heat of the fire. F~p(osion Sensitivity to Mechanical Imaact: Not sensitive, Ex~.losion Sensitlvliy to Static Discharge: Not sensitive. SPECfAL FIRI~-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus and full protective equipment If necessary, increase ventilation to prevent concentration of Garbon Dioxide. Evacuation may be necessary. Refer to the North American Emergency Response guidebook for additional information. LASAL MI3CTURES 150, P150, 152, 154, 155 (10D53) MSDS EFFECTIVE DATE: AUGUST 31, 2D05 PAGE30F10 03/13/2006 12:50 6613876807 MELO'S GAS & GEAR PAGE 04 ~ 6. ,ACCIDENTAL RE~,EASE MEASURES ~ 4FJ1K RESPONSE: Evacuate immediate area. Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equlpment should be used. Minimum Personal Protective Equipment should be Level B: Self Contained Breathing Apparatus. Locate and seal the source of the leaking gas. Allow the'gas to dissipate. Monitor the surrounding area for the level of Carbon Monoxide, Carbon Dioxide and oxygen. Carbon Monoxide and Carbon Dioxide levels must be below the exposure level listed In Section 2 (Composition and Information on Ingredients) and the atmosphere must have at least 19.5 percent oxygen before personnel can be allowed in the area without Self-Contained &eathing Apparatus. Attempt to close the main source valve prior to entering the area. If this does not stop the release (or if it is not possible to reach the valve), allow the gas to release in place or remove it to a safe area, away front sources of ignition, and allow the gas to be released there. If gas is leaking incidentally from the cylinder or Its valve, contact your supplier. 7. t~ANDLING AND STORAGE _~ WORK PRACTICES AND WYGIENE PRACTICES; Be aware of any signs of dimness or fatigu®; exposures to fatal concentrations of this gas mixture could occur v~ithout any significant warning symptoms (due to oxygen deficiency). STORAGE AND HANDLING PRACTICES: Cylinders should be stored upright (with valve-protection cap in place) and firmly secured to prevent falling or being knocked oust, Cylinders can be stored in the open, but in such cases, should be protected against extremes of weather and from the dampness of the ground to prevent rusting. Cylinders should be stored in dry, well-ventilated areas away Pram sources of heat, ignition, and direct sunlight. Keep storage area clear of materials that can bum. Do not allow area where cylinders are stored to exceed 52°C (125°F). Store containers away from heavily trafficked areas and emergency exits. Store away from process and gas production areas, elevators, building and room exits, or main aisles leading fio exits. Protect cylinders againsk physical damage. Keep the smallest amount on-site as is necessary. Full and erripty cylinders should be segregated. Use afirst-in, first out inventory system to prevent full containers from being stored for long periods of time. Use a check valve in the discharge line to prevent hazardous backfiow. Never tamper with pressure relief devices in valves and cylinders. SPECIAL PRECAUTIONS FOR HANDLING GAS CYLINDERS: Compressed gases can present significant safety hazards. The following rules are applicable to work situations fn which cylinders are being used: Before Use: Move cylinders with a suitable hand-truck. Do not drag, slide or roll cylinders. Do not drop cylinders or permit them to strike each other. Secure cylinders firmly. Leave the valve protection cap (where provided} in place until cylinder is ready for use. During Use: Use designated CGA fittings and other support equipment. Do not use 2dapters. Use piping and equlpment adequately designed to withstand pressures to be encountered. Do not heat cylinder by any means to increase the discharge rate of the gas mixture from the cylinder. Do not use oils or grease on gas-handling fittings yr equipment. Leak check system with leak detection solufion, never with flame. Immediately contact the supplier if there are any difficulties associated with operating cylinder valve. Never insert an object (e.g., wrench, screwdriver, pry bar, etc.) into valve cap openings. Doing so may damage valve, casing a leak to occur. Use an adjustable strap wrench to remove overly tight or rusted caps. Never strike an arc on a compressed gas Cylinder or make a cylinder part of an electric circuhk .After Use: Close main cylinder valve. Valves should be closed tightly. Reinstall gas-tight dust cap on the cylinder outlet. Replace valve protection cap. Mark empty eyllnders "EMPTY". STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA: Use the proper CC'+A connections, DO NOT USE ADAPTERS: THREAbED: CGA 350 PIN-INDEXE.A YOKE: Not applicable. ULTRA HIGH INTEGRITY; Not assigned. NOTE: Use only DOT or ASME code cylinders designed for compressed gas storage. Close valve after each use and when empty. Cylinders must not be recharged except by or with the consent of ownet. PROTECTIVE PRACTICES pURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out safety. Purge gas handling equipment with inert gas before attempting repairs. Always u5o this gas mixture in areas where adequa#e ventilation is provided. LASAL MIXTURES 150, P150, 152, 154,155 (10053) I~SDS EFFECTIVE DAVE: AUGUST 31, 2005 PAGE 4 of 10 03/13/2006 12:50 6613876807 MELO'S GAS & GEAR PAGE 05 ., 8~ EXPOSURE CONTROLS - PE~2SONAL P120TECT~ON __ VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. local exhaust ventilation is preferred, because it prevents chemical dispersion Into the work place by eliminating it at its source. If appropriate, install automaEic monitoring equipment to detect the levels of Carbon Monoxide, Carbon Dioxide and Oxygen. RESPIRATORY PROTECTION: Maintain Carbon Monoxide and Carbon Dioxide exposures below levels lisfed in Section 2 (Composition and information on Ingredients} and oxygen levels above 19.59'° in the workplace. Use supplied air respiratory protection if oxygen levels are below 19.5% (air-purifying respirators will oat function) ,or during emergency response to a release of this gas mixture. During an emergency situation, before entering the area, check for oxygen-detleient atmospheres. If tesplratary protection is needed, use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the Canadian C5A Standard 294.4-93. Oxygen levels below 99.v9'o are considered IDLH by OSHA. In such atmospheres, use of a full- facepiece pressureldemand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHAs Respiratory Protection Standard (1910.134-1996). The following are NI05H recommendations for Carbon Monoxide (the toxic component of this gas mixture) concentrations in afr, which are provided for additional guidance in respirator selection: COHI_CENTRATION RESPIRATORY EQUI MENT Up to 350 ppm: Supplied Air Respirator (SAR). Up to 875 ppm: SAR operated in a continuous flow mode. Up to 1200 ppm: Gas mask with canister to protect against carbon monoxide; or 'Full-facepiece Self- Contained Breathing Apparatus (SCBA}; or full-facepiece BAR. Emergency or Planned Entry into Unknown Concentration or IDLH Conditions: Positivta pressure, full~facepiece SCBA; or positive pressure, full-facepiece SAR with an auxiliary pasitlve pressure SCBA. Escape: Gas mask with canister to protect against carbon monoxide; or escape~type SCBA. NOTE,: End of Service Life Indicator (ESLIj required for gas masks. The IDLH concentration for Carbon Monoxide is 1200 ppm. EYE PROTECTION: Safety glasses, If necessary, refer to U.S. OSHA 29 CFR 1910.133, or Canadian Standards. HAND PROTECTION: Wear gloves when handling cylinders of this gas mixture. Otherwise, wear glove protection appropriate to the specific operation for which this gas mixture is used_ if necessary, refer to U,S. OSHA 29 CFR 1910,138 or appropriate Standards of Canada, BODY PROTECTION: Us® body protection appropriate for task. Safety shoes are recommended when handling cylinders. If a hazard of injury to the feet exists due to falling objeMs> rolling objects, where objects may pierce the sales of the feet or where employee's feet maybe exposed to electrical hazards, use foot protection, as described.in U.S. OSHA 29 CFR. 9. PHYSICAL and CHE~AICAL PROPERTIES The following information is far Helium, a main comport®nt of this gas mixture. GAS DENSITY @ 0°C {32°F) and 1 aim: 0.0103 Its/cu R (0.165 kglm3) FREEZINGIMEI,TING POINT (@ 10 psig): Not applicable. ROILING POINT: -452.1 °F {-268,9°C) SPECIFIC GRAVITY (air ~ 1) Cp3 21.1°C (70°F): 0.1381 pH: Not applicable, SOLUBILITY IN WATER vol/vol ~ 0°C {32°F) and 1 atm: 0.0094 MOLECULAR WEIGHT: 4.00 EVAPORATION RATE {nBuAC = 1): Not applicable. EXPANSION RATIO: Not applicable. OpOIZ THRESHOLD: Not applicable. Odorless. SPECIFIC VOLUME {ft311b): 96,7 VAPOR PRESSURE @ 21.1°C (70°~ {psig): Nat applicable. COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable. The follawing information 1s for Nitrogen, a main component of this gas mixtnr®. GAS pENSITY @ 0°C (32°F) and 1 atm: 0.072 Ibslcu ft {1.153 kglm3) FREEZlNGIMELTING POINT (@ 10 psig) ,210°C (-345.8°F) BOILING POINT: -195.8°C (-320.4°F) SPEClF(C GRAVITY (air=1) @ 21.1°C (7o°F): 0.906 pH: Not applicable. SOI.UBILYiY IN WATER vollvoi at °0 C (32°F) and 1 atm: 0.023 MOLECULAR WEIGHT: 28.01 EVAPORATION RATE (nBuAc = 1): Not applicable. ~CPANSION RATIO; Not applicable. ODOR THRESHOLD: Not applicable. Odorless. SPECIFIC VOLUME (fta/lh): 13.8 VAPOR PRESSURE @ 21.1°C {70°F) psig: Not applicable, COEFFICIENT WATER/01L DISTRIBUTION: Not applicable The following information is for this gas mixture. APPEARANCE AND COLOR: This is a colorless, nonflammable gas mixture which is odorless or which has an acrid odor (due to the presence of Garton Dioxide). HOW TO DETECT THIS SUBSTANCE (warning properties): There are no distinct warning properties of this gas mixture. In terms of leak detection, fittings and joints can be painted with a soap solution to detect leaks, which will be indicated by a bubble formation. I.ASAL MIXTURES 150, P150,152, 154,155 {10053) MSDS EFFECTIVE DAtE: AUGUST 31, 2005 -PAGE 5 OF 10 r 03/1312006 12:50 6613876807 MELO'S-GAS & GEAR PAGE 06 1~. STABILITY and REACTIVITY STABILITY: Normally stable. DEGOMI'OSITION PRODUCTS: The components of this product do not decompose, per se, but may react with other Compounds in the heat of a flre_ The Nitrogen and Helium components of this gas mixture are inert. MATERIALS WITH WHICH SUBSTAhICE IS INCOMPAT113LE: Due to the presence of carbon Dioxide, this gas mixture would be incompatible with powdered metals such as beryllium, cerium and alloys, thorium, titanium, uranium, and zirconium. Carbon Dioxide will react with alkaline materials to form carbonates and bicarbonates. Due to the presence of Carbon Monoxide, this gas mixture would also be incompatible with strong vxldiiers C.e. chlorine, bromine pentafluoride, oxygen, oxygen drtluoride, and nitrogen trit1raoride), Carbon Monoxide is also mildly corrosive to nickel and iron (especially at high temperatures and pressures). IiAZARDOU5 POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Cylinders. exposed to high temperatures or direct flame can rupture or burst. ~ 11. TOXICOLOGICAL INFORMATION ~ TaXICITY DATA: The following toxi concentrations greater than or equal to CARSON DIOXIDE LCLo (Inhalation-Human) 9 pph15 minutes LCLo (MhalaUon-Mammal-species unspecified) 90000 ppmf5 minutes TCLo (tnhalatton-Ra#) 10000 ppml24 hours/days~ontinuous: Blood: other changes TCLo (Inhalation-Ratj 6 pph/24 hours; femal® 10 day(s) after conception: R®productive: Specific developmental Abnormalities: musouloskeletal system, cardiovascular (circulatory) system, respiratory system TC-..a (InhalatiarrRabblt) 27,000 ppml24 hoursl30 days-continuous Behaviorel: somnolence (general depressed activity) TCLo {Inhalation-Rat) 8 pphf2a hours; tomato 10 day(s) after conception: Repraduct+ve: Effects on Newborn: growth atatisUcs (e.g.4f,, reduced weight gain) TCLa (Inhalation-Rabbit) 13 pphl4 hours: female g-1~ day(s) after conception: Reproductive: Specific Developmental Abnomra-iUas: musculoskelatal system TCLo {Inhalation-Mou,9a) 55 pptrl2 hours: male 3 day(s) pre-mating: Reproductive; Patamal Effects: spermatogenesis (nat. genetic material, sperm morphology, motility, and count) TCIa {InhataNon•Mouse) 55 pph/4 hours: male 8 day(s) pro-mating: Reproductive: FertUfty: male fertility Index (e.g. # males impregnating females per # males exposed to terUle non-pregnant females) TCLo (Inhalation-Mouse) 2 pph/8 hours: female 10 day(s) sitar conception: Reproductive: Fertility: post-implantation mortal(ty (e,g. dead andlor resorted implants per total number of Implants); Specific oevelapmerrtal Atxrormali6as: musruloskeletal system cARaaN MoNOxIDa (onntfnuecq; TCLo (InhelatiorrRat) 150 ppml24 hours; female 1-22 day{s) aRer conception: Reproductive: Spadflc Developmental Abnormalities: cardlavascutar (arcxtlatory} system TCt.o (inhalation-Rat} 150 ppml24 hours; female 1-22 day(sj after conception: Reproductive: Effects on Newbom: growth statistics (9.g.°/n, rpdueed weigrrt gain), behavioral TCLo (Innalatlon•Rat) 75 ppml24 hours: female D-20 day(s) agar conception: Reproductlve:. speefiic Devebpmentgt cology data are available for the components of this gas mixture present in 1 mole %. CAR80N MOM~XIDE: LC,~ (inhalation-Rat)1t347 ppm14 hours l,C,~ (Inhalation•Mouse) 2444 ppml4 hours LCrt, (InlSalatlon-Guinea Plg) 5718 ppm/4 hours LCs° (lnhalallon~wild bircl species)1334 ppm TULa (Subcutanaous•Rat} 5983 mglkg/18 uvaaks•intenniitant: Blood: dianges in seerm composition (e.g. TP, bilirubin, cho(esterolJ LCLo (InhalaUon•Human} 4 mg/m°/12 hours; Behavioral: coma; Vascular: BP lowering not characterized In autonornlc secUion; Blood; methemogkrbinamia- c:arboxyhemoglobin LCLo (Inhalation-Man} 4000 ppm/30 minutes LCLo (inhalation-Wuman) 5000 ppm/6 minutes LCLo (Inhalation•Dog) 4400 ppml46 minutes LCLo (Inhalation•Rabbit} 4000 ppm LCLo (Inha~laUorr~Mammal-species unspecllled} 5000 ppml5 minutes Tt/--o (Inhalation-Human) 800 mg/ms110 minutes: eehavloral:headache TCLo (Inhalation•Man) 850 ppml45 minutes: Biaod: methernagtobtntsmia- carboxyhemogtabin: Behavioral: d~anges in psychophyaiologlcal testa TCLo {Inhalation-Rat) 1800 ppm/l hour/i4 days-intermittent; Cardiac: other chang®s TCLo (InnalaUon-Rat) 30 mglms/s hours/10 weaksdntermi)tent: Brain and Coverings: other degenerative changes; Behavioral: muscle coritracUon or spastielly TCLo (Inhalation•Rat) 98 ppml24 hours190 days•conGnuous; Broad: pigmented or nucleated red blood cells, other changes cholesterol) CARBON MONOXIDE (continued): TCLo (Inhalation-Rai} 250 pprn/5 hoursl24 d9ys-tntermittenC: Blood :pigmented or nucleated red blood Fella, changes in other cell count (unspecified), changes in erythrocyte (RBC} count TCLo (lnhaldtion•Mouse) 50 ppm/30 d~ys- intermittent Lungs, Thorax, or Respiration; structural or funcflonal change In trachea or bronrhi TCLa (Inhalation-Mpnkey) 200 ppml24 hoursl90 days-continuous: t3lood: plgmerrted or nuole9tad red blood cells, okher changes TCLo (Inhalation•Rabbli) 200 mg/m='!3 hours/t9 waekalntermtttent: Brain and Coverings: other degenerative changes; Cardiac: other changes; Blood; hemorrhage TCLo (Inhalation-Rabbit) 50 ppnU24 hourslB weeks-cr,,ntinuous; Blood: changes in platelet count TCLo (lnhalAUon•Guinea Plg) 20D mglm'/5 froura/4 weeks-intermltlent: Endocrine: hypergtyhemia TCLo (lnhalaUan-Guinea Pig) 200 mg/m'!5 hoursl30 weeks-continuous; Cardiac; arrhythnflas (including changes in conducdon), >=KG changes not dlagnastlc of specified effects, pulaa rate increase, wlthoutfgll in BP TCLo (lnhalation•Guinea Plg) 20o ppm/2a hours/90 days-continuous: Bland: pigmented or nucleated red blood cells, ocher changes TCLO {Inhalation-Rat) 75 ppml24 hours: female t7-20 day(s) after conception: Reproductive: Maternal C-ffeata: other effects; Bifects on Newbom: behavioral Abnonnalfies: immune and reticuloendolhelial syatgrn tCLo (Intv~laUon-Rat) t rng/ma~4 hours; female 72 day(s) pre-mating; Reproductive; Matemal Effects: menstrual cycle changes or dlsoNers, parturition; FerSility: female fertility index {e.g, females pregnant por # sperm positive females; # females pregnant per females mated) CARBON MONOXIDE (continued); TCI.o (Inhdlation-oat) 150 ppml24 hours: female 0.70 day(s) after conception: Reprodactiva: Eirecka on Newborn: behavioral TCLo (Inhalation•Mouse) 85 ppml24 hours; female 7-16 day(9) after conception; Reproductive: Etfecta on Newbom: behavidl'al TCLo (Inhalation-Mouse) 250 ppml7 hours: female 6-15 day(s) after conception: Reproductive; Fertility. poet-implantation mortality (e,g. dead and/or resorted imptantB per total number of Implants}; LASAL MIXTURES 150, P150,152, 95,4, 155 (90053) AtISDS EFFECTIVE RATE: AUG=UST 31, 2005 PAG>w 6 OF 10 03/13/2006 12:50 ;. 6613876807 MELO'S GAS & GEAR. PAGE 07 Speaflc Developmental Abnormalities; musculaskeletalaystem 7CLo Qnhalat+an•Mouse) 125 ppml24 hcur: female T-1B day(s} 8fter conception: Reproductive: {"treats on E,m6ryo or Fetus: fetotoxicity {excepf death, e,g., stunted fetus) TCLo (Inhalation-Mouse) 9 pph/1 hour. f~amale 8 day(s) after conception: Reproductive: Fertility, fitter size (e.g. # fetuses per litl~er; measured before birth); Effects on Embryo or Fetus; fetotoxiclry (except death, e,g., stunted fetus), fetal death CARBON MONOXIpE (continued): TCLo (Inhalation-Mouse) S pphll hour. female 8 day(s) attar conception: Reproducin+e: Specific Developmental Abnormalities: Central Nervous 5yslem TCLo (lnhalation•Rabbit) 1 BO ppml2A hours: female 1-3D day(s) after conception; Repnxlucthre; Effects on Newborn: stillbirth, viability index (e,g„ # alive at day 4 per # born alive) Micronucleus Teet (Inhalatian•Mouse)1500 ppm110 minutes Sister Ghromafid Exchange (Inhalation- Mouae) 2500 ppm/f 0 minutes H1=Ul1M: There ar® no sp¢citlc toxicology data for Helium. Helium Is a simple asphyxiant {SA), which acts tc displace oxygen in the environment. " HYDROGEN: 1"hera are no specfic toxicology data for Hydnx~en. Hydrogen is a simple asphyxiant (5A), which acts to displace oxygen fi the environment, NITROGEN: There are no specifie toxicology data far Nitrogen. Nitrogen Is a simple asphyxiant (SA), which acts to displace oxygen in the environment SUSPECTED CANCER AGENT: The components of this gas mixture ere not found on the following lists: FEDERAL OSHA Z LIST, NTP, CAUOSHA, and IARC and therefore, they are net considwred to be, nor suspected to be, cancer-causing agents by these agencies. IRRITANCY OF PRODUCT: This gas mixture may be irritating to the eyes. SENSITIL4TION TO THE PRODUCT: The components of this gas mixture are not knowh to be skin or respiratory sensitizers. REPRODUCTNiw TOXICITY INFORMATION: Lis#ed below is information concerning ills effects of this gas mixture and its components on the human reproductive system. Mutagenicity: This gas mixture is not expected to cause mutagenic effects in humans. Animal mutagenic data are available for the Carbon Monoxide component of this gas mixture; these da#a were obtained during clinical studies on specific animal tissues exposed to relatively high doses of this gas. E>Zlbrvotoxicity: This gas mixture is not expected t'o cause embryoloxiC effects in humans. Teratogeniclty: This gas mixture is not expected to cause teratogenlc effects in humans. Animal teratogenit; data are available for the Carbon Dioxide and Carbon Monoxide components of this gas mixture; these data were obtained during clinical studies on specific animal tissues exposed to relatively high doses of this gas. In general, maternal symptoms are an indicator of the potential risk to the fetus since Carbon Monoxide is toxic to the mother before it is toxic to ~-e fetus. Reproductive Toxicity: This gas mixture is not expected #o cause adverse reproductive effects in humans. Animal reproductive date are available for the Carbon L]ioxide and Carbon Monoxide components of this gas mixture; these data were obtained during clinical studies on specific animal tissues exposed to reiatively high doses of these gases, A m en Is a chemical which causes pemrart~+nt changes fo genetic material (DIVA) such that the changes wi!! propagate through generation lines. An embrvoto in is a chemical which causes damage to a developing embryo (i.e. within the fast eight weeks of pregnancy in humans), but the damage does not prolagate across generational lines. A fe en is a cf'-emica! which causes damage to a developing fetus, but the d2~mage doss not propagate across generational lines, A rrSruroductive toxin is any substance which inferleres in any way with the reproductive process. BIOLOGICAL EXPOSURE INDICES (BEIs}: Biological Exposure Indices (BEIs) haven been deten'nined for the components of this gas mixture, as fot(ows: CARBON MONOXIDE • Carboxyhemoglobin in blood • End of shift • 3,596 of hemoglobin • Carbon monoxide in end-exhaled air • End of shift • 20 ppm LASAL MIKTURES 150, P150, 152,15+1,155 (10053) MSDS EFFECTIVE DATE: AUGUST 31, 2005 PAGE 7 OF 10 03/13/2006 12:50 6613876807 MEl_0 ' S GAS & GEAR PAGE @8 12. ECOLOGICAL, INFORMATION ENVIRONMENTAL STABILITY: The gas will be dissipated rapidly in well-ventilated areas. The following environmental data are applicable to the components oFthis gas mixture, CARSON MONOxIDE: Water solubility = 3.3 mV10U cc ai 0°C, 2,3 ml ~t 20°C. NITROGI_N; Water SolubiAiy ~ 2.4 volumes Nitrogen/100 volume6 water at 0°C and 1.8 volum~a Nitrngan/100 v4lumea water at 20°C. EFFECT OF MATERIAL ON PLANTS or ~-NIMALS: No evidence is currently available on this gas mixture's effects on plant and animal life. Carbon Monoxide, a component of this gas mixture, can be deadly to exposed anima( life, producing symptoms similar to those experienced by humans, Carbon Monoxide may also be harmful to plant life. EFFECT OF CHEMICAL. ON AQUATIC LIFE: No evidence is currently available on thifi gas mixture's efrects on aquatic life. The presence of more than a pace of Carbon Monoxide (a component of this gas mixture) in water is a hazard to fish. 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate F®deral, Slate, and local regulations. Retum cylinders with any residual gas mixture to Alr lJquide. Do not dispose of locally. For emergency disposal, secure the cylinder and slowly discharge the gas to the atmosphere in swell-ventilated area or ou#doors, away from all sources of ignition. 14. TRANSPORTATION INFORMATION THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY 'THE 11.S. DEPARTMENT OF TRANSPaRTAT10N. PROPER SWIPPINC NAME: Compressed gases, n,os. (Nitrogen, Helium) HAZARD CLASS NUMBER and DESCRIPTION: 2.2 (Non-Flammable Gas) UN IDENTIFICAtION NUMBER: l1N 1956 PACKING CROUP: Not Applicable DOT LABEL(S) REQUIRED: Non~Flammable Gas NORTH AMERICAN EMERGENCX RESPONSE GUIDEBOOK NUMBER (2000): 126 MARINE POLLUTANT: The components of this gas mixture are not classified by the GOT as Marine Pollutants (as defined by 49 CI=R 172.101, Appendix L3). SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, In swell-ventilated vehicle. The transportation of compressed gas cylinders in automobiles or in closed-body vehicles present serious safety hazards and should be discouraged. NOTE: Shipment of compressed gas cylinders which have not been filled with the owners consent is a violation of Federal law (49 CFR, Part 173.301 (b}. TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS Rf=GULATIONS: This material is considered as dangerous goods, per regulations of Transport Canada. Use the above U.S. DOT information for the preparation of Canadian Shipments. 75. REGULATORY INFORMATION ADDITIONAL V.S. REGUU4TIONS: U.S. SARA RL:PORTING R13QUIREMENTS: The components of this gas mixture are not subject to the reporting requirements of Sections 302, 304, and 313 of Title I!I of the Superfund Amendments and Reauthorization Act. U.S. SARA 1"HRESHOL„D PLANNING QUANTITY: There are no specific Threshold planning Quantities for any component of this product. The default Federal MSDS submission and inventory requirement fling threshold of 10,0001b (4,540 kg) therefore applies, per 40 CFR 370.20. U.S, CERCLA REPORTABLE QUANTITIES (RQ): Not applicable. U.S. TSCA INVENTORY STATUS: The components of this gas mixture are listed on the TSCA inventory. OTHER U,S. FEDERAL REGULATIONS: • Carbon Dioxide and Carbon Monoxide are subject to the reporting requirements of CFR 291910.1000. • This gas mixture does not contain any Class I of Class 11 ozone depleting chemicals (40 CFR part 82}. • No component of this gas mixture is subject to the reporting requiremen#s of section 112(x) of the Clean Alr Act. • The regulations of the Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119) are not applicable to this gas mixture. OTF#IwR U.S. FEDERAL. REGULATIONS (confiinued): • Carbon Dioxide, Helium, and Nitrogen are not listed as Regulated Substances, per 4A CFR, Part 68, of the Risk Management for Chemical Releases. Carbon Monoxide is fisted under this regulation in Table 3 as a Regulated Substance (Flammable Substance}, in quantities of 10,000 ibs (4,553 kg} or greater. LASAL MIXTURES 150, P15o, 152,154, 155 (10053) MSl]S EFFECT1vE DATE:. AUGUST 39, 20x5 PAGE S OF / 0 03f13/2006 12:50 6613876807 _ _ htELO' S GAS & GEAR PAGE 09 15, REGUI..ATORY iNFORMA,TION ~Continuled~ U.S. STATE REGULATORY INI=ORMATION: The components of Phis gas mixture are covered under the following specific State regulations: Alaska • Designated Toxic and Hazardous Michigan - CriGCaf Materials Register No. Pennsyivanls -Hazardous Substance Lisle: Substances: Garl~or+ Dioxide, Carbon Minnesaiaii - List of Hazardous Substances: Carbon Diwllde, Carbon Monoxide, Kellum, Monoxide, Helium, Nitrogen, Carbon Dioxide, Carbon Monoxide, W¢Ilum. Nitrogen. California - Renmisslble Exposure Limits Missouri - Emptay®r InforrnatlonlPoxic Rhode Island - Hazardous Substance List: for Cfirsmical Contaminants: Carbon Substance List: Carbon Dioxide. Carbon Carron Dioxide, Carbon Monoxide, Wellum, Dioxide, Carbon Monoxide, Helium. Monoxide, Helium, Nitrogen. PloNda • Substance List: Carbon Dioxide, New Jf3rst;y - Right to Know Naaardoua Texas -Hazardous Substance List: Carbon Carbon Monoxide, Helium, Nitrogen. Substance Llst: Carbon Dioxide, Carbon Dioxide, Carbon Monoxide. tllfrtol9 -Toxic Substarce List: Carbon Monozida, Helium, Nitrogen. (Nest Virginia -Hazardous Substance list: Dioxide, Carbon Monoxide, Helium. North Dakota List of Hazardous Carbon Dioxide, Carbon Monoxide, Kansas - Section 302!313 List:. No. Chemicals, Reportable Quantities: No, Wisconsin - Toxic and Hazardous Massachusetts -Substance List: Cariwn Substances: Carbon Dioxids', Caton Dioxide, Carbon Monozlde, Helium, Monoxide, Nrtrogen. CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): The Carbon Monoxide component of this gas mixture is on the California Proposition 65 lists, WARNIMIG: This product contains a chemical known to the. State of California to cause birth defects or other reproductive harm. OTHER CANADIAN R~EGUI-ATIONS: CANADIAN DSUNDSL iNVt=NTORY STATUS: The components of this mixture are listed on the Canadian DSL Inventory. CANADIAN ENVIRdNMENTAL PROTECTION ACT ~C<=pA) PRIORITIES SUBSTANCES L[STS: The components of this gas mixture are not on the CEPA Priorities Substances Lists. CANADIAN WWMIS REGULATIONS: This gas m%xture is Categol'ized as a Controlled Product, Hazard Classes A, D1A, and D2A, as per the Controlled Product Regulations. 16.OTWER INFORMATION IVFPA RATING HEALSH ~~ Rt?AC~r+nTY H+ATIIFDOUS I~AATEIbA1.IDEMIHCATI4N SYSTEM HEALTH tom, , MIXTURES: When two ar more gases or liquefied gases are mixed, their hazardous properties may combine to create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture, Consult an Industrial Hygienist or other trained person when you make your safety evaluation of the end product. Remember, gases and liquids have properties which can cause serious injury or des#h . FLAMMABILITY t~~ REACT'111I'T'lt rYO.La~+q o PROTECTIVE EQUIPMENT B 6YE5 Rea~waoRr NMDS txxrr s~ suction s For ratline industrial applications I.ASAL MIXTURES 150, P150, 152, 154, 155 (1D053) MSDS EFFECTIVE BATE: AUGUST 31, X005 PAGE 9 OF 10 03!13/2006 12:50 6613876807 MELD'S GAS & GEAR PAGE 10 ~~; 16. OTHER INFORMATION (Continued) Further information about gas mixtures can be found in the following pamphlets published by: Compressed Gas Association Inc. (CGA), 4221 Walney Road 5~' floor, Chantilly, VA 20151-2923. Telephone: (703) 788-2700. P-1 "Safe Handling of Compressed Gases in Containers" AV-9 "Safe Handling and Storage of Compressed Gases" "Handbook of Compressed Gases" PREPARED BY: CHEMICAL. SAFETY ASSOCIATES, Inr:. 9163 Chesapeake Drive, San diego, CA 921231002 8581565.0302 Faxon Demand: 1-8t)~/231-1366 AIR LIQ~J~DE This Material Safety Dala Sheet Is offered pursuant to OSHA's Hazard Communication Standard, 2fl CFR, 19117.1200, Other government regulations must b$ reviewed for applieablllty to this product. To the best of Air Llquide's knowledge, the information cor~iained herein Is reliable and accurate as of this date; however, accuracy, suitability or completeness are not guaranteed and no warranties of any type, either express or implied, ere provided. The information contained herein relales only to this speelflc product. If thi9 product is combined with other material9, all component properties must be considarod. osta may ba changed from lime io time. Be sure to consult the 19teat edition. r LASA,L MIXTURES 150, P150, 15Z, 154,155 (10053) MSDS EFFECTIVE DATE: AUGUST 31, 2005 PAGE 10 OF 10 F/RE ARTM RONALD J. FRAZE FIRE CHIEF Gary Hutton, Senior Deputy Chief Administration 326-3650 Deputy Chief Dean Clason • Operations/Training 326-3652 June 5, 2006, Ms. Dee Secara, Manufacturing Process Manager Crystal Geyser -Bakersfield Office 1233 E. California Avenue Bakersfield, CA 93307 Re: Administrative Enforcement Order, Docket No.: 20..0.6-07 '~ Dear Ms. Secara: i Deputy Chief Kirk Blair ~ I am in receipt of your letter of June 2, 2006, requesting a 30 day Fire Safety/I'revention Services extension to complete the requirements of the "Order on Consent 326-3653 Agreement." We are aware that Crystal Geyser is working to fulfill the Agreement and, therefore, an extension would be appropriate. 2101 "H" Street Bakersfield, CA 93301 OFFICE: (661) 326-3941 FAX: (661) 852-2170 RALPH E. HLTEY, DIRECTOR PREVENTION SERVICES FlRE SAFETY SERVICES • ENVIRONMENTAL SERVICES 900 Truxtun Avenue, Suite 210 Bakersfield, CA 93301 OFFICE: (661) 326-3979 FAX: (661) 852-2171 David Weirather Fire Plans Examiner 326-3706 Howard H. Wines, 111 Hazardous Materials Specialist 326-3649 This letter will act as the approval of a 30 day extension to complete the requirements of "Order on Consent Agreement, Docket No.: 2006-07," until July 8, 2006. If you have any questions, please don't hesitate to call. Sincerely, Ra ey, DIR TOR OF PREVENTION SERVICES REH:db cc: Howard Wines; City of Bakersfield-Prevention Services "Sertving the Community Foy~lore ~ianA Century"