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Home My WebLink AboutBUSINESS PLANi ~ PACIFIC WOOD PRESERVING I - - (. - - - - - - - --- - - -.. ----- _ 5601 DISTRICT BLVD.` - ~~ ~ ~~- PACIFIC WOOD PRESERVING/BAKERSFIE Manager RICK MCCULLOUGH Location: 5601 DISTRICT BLVD City BAKERSFIELD CommCode: BFD STA 13 EPA Numb: CAT000611145 SiteID: 015-021-000567 BusPhone: (661) 833-0429 Map 123 CommHaz High Grid: 15D FacUnits: 7 AOV: SIC Code:2491 DunnBrad:ll-881-0514 Emergency Contact / Title Emergency Contact / Title RICK MCCULLOUGH / PLANT MANAGER CASEY ZIEMER / ASST PLANT MGR Business Phone: (661) 833-0429x36 Business Phone: (661) 833-0429x38 24-Hour Phone (661) 201-3203x 24-Hour Phone (661) 979-3598x Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: RSs Fire Press React ImmHlth DelHlth Contact RICK MCCULLOUGH Phone: (661) 833-0429x36 MailAddr: 5601 DISTRICT BLVD State: CA City BAKERSFIELD Zip 93313 Owner RICHARD JACKSON Phone: (775) 832-5225x Address 668 TYNER WY State: NV City INCLINE VILLAGE Zip 89451 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: Yes ParcelNo: Emergency Directives: ENT'D A U G 01 X007 PROG A - HAZMAT PROG H - HAZ WASTE GEN PROG R - CAL ARP PROG T - ABOVEGROUND STORAGE TANK THIS IS AN RMP SITE AND REQUIRES A JOINT INSPECTION, CALL ENV SVGS TO SCHEDULE THIS INSPECTION. Pried on my inquiry of those individuals responsibie for obtaining the information, I certify under penalty ofi ia+~ that { have personally examined and am familiar with the information sut~mitted and be~oeve the information is true, accurate, and complete. " -Y -~~• o-, i~l~'rl ~ Signature Date -1- 07/13/2007 1 Y F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order CCA TANK FARM ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP CHROMIC ACID SOLUTION F R IH DH L 36096.00 GAL Hi WOLMANAC R CONCENTRATE - 60% IH L 5000.00 GAL Hi JPC DIESEL #2 F IH DH L 500.00 GAL Low -2- 07/13/2007 S c F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order DRI-CON STORAGE ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP CCA WASTE IH S 1500.00 LBS Hi HYDROGEN PEROXIDE 50% F P L 1000.00 LBS Hi DRI-CON FIRE RETARDANT S 44000.00 LBS Mod WASTE OIL F DH L 165.00 GAL Low PAC-BOR S 100000.00 LBS UnR -3- 07/13/2007 * c F PACIFIC WOOD PRESERVING/BAKERSFIE ~ Hazmat Inventory ~ MCP+DailyMax Order SiteID: 015-021-000567 ~ By Facility Unit ~ ACQ/PAC-BOR TANKS ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP AMMONIA SOLUTION E F IH L 36072.00 GAL Mod BORIC ACID S 8000.00 LBS Low DRICON FIRE RETARDENT WORK SOLU L 36096.00 GAL UnR PACBOR MIXTURE R L 29000.00 GAL UnR QUATERNARY AMMONIA COMPOUND F IH L 24000.00 LBS UnR ACQ-C L 6000.00 GAL UnR ACQ-CZ L 6000.00 GAL UnR -4- 07/13/2007 ~ 4 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order SW STORAGE AREA ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP DEGREASER -AROMATIC HYDROCARBON F L 110.00 GAL Mod -5- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order MAINTENANCE SHOP ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP ACETYLENE E F P IH G 420.00 FT3 Hi OXYGEN F P IH G 843.00 FT3 Low CHEVRON HYDRAULIC OIL 68 F DH L 110.00 GAL Low MOTOR OIL F DH L 110.00 GAL Min -6- 07/13/2007 -7- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0004 Facility Unit: CCA TANK FARM ~ COMMON NAME / CHEMICAL NAME CHROMIC ACID SOLUTION Days On Site CCA MIXTURE 365 Location within this Facility Unit Map: Grid: CCA TANK FARM CAS# 1333-82-0 Liquid TMixture I Ambient~E ~ AmbientT~E ABOVEOGROIUNDRTANKE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 36096.00 GAL 36096.00 GAL 36096.00 GAL HAZARDOUS COMPONENTS %Wt. RS CAS# 0.10 Chromic Acid No 1333820 0.20 Arsenic Pentoxide (EPA) No 1303282 0.10 Cupric Oxide No 1317380 I11iGH.iCL H aJP~J.71~1r,1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No No/ Curies F R IH DH / / / Hi ~ Inventory Item 0003 Facility Unit: CCA TANK FARM ~ COMMON NAME / CHEMICAL NAME WOLMANAC R CONCENTRATE - 60% Days On Site 365 Location within this Facility Unit Map: Grid: CCA TANK FARM CAS# Liquid TMixture ~ Ambient~E ~ AmbientT~E ABOVEOGROUNDRTANKE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 6400.00 GAL 5000.00 GAL 2000.00 GAL ru-lc,ruciv~J ~.vrlrvivr~lvtJ %Wt• RS CAS# 17.00 Arsenic Pentoxide (EPA) No 1303282 24.00 Chromic Acid, Solid No 1333820 9.00 Cupric Oxide No 1317380 rJ.t~L~riRL t1J JLiJ J1.1P~1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / Hi -8- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SitelD: 015-021-000567 ~ ~ Inventory Item 0002 Facility Unit: CCA TANK FARM ~ COMMON NAME / CHEMICAL NAME JPC DIESEL #2 Days On Site 365 Location within this Facility Unit Map: Grid: SW OF PLANT BEHIND ACQ TANK FARM CAS# 68476-34-6 Liquid TMixture ~ Ambient~E ~ AmbientT~E ABOVEOGROIINDRTANKE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 550.00 GAL 500.00 GAL 300.00 GAL HAZARDOUS COMPONENTS °sWt. RS CAS# 100.00 Diesel Fuel No. 2 No 68476302 tiHGt1KL xaar~aai~1L'~ly 1-5 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F IH DH / / / Low -9- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0005 Facility Unit: DRI-CON STORAGE ~ COMMON NAME / CHEMICAL NAME CCA WASTE Days On Site COPPER, CHROMIUM, ARSENATE COMPOUNDS SLUDGE WASTE 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# ~SolidE TWaste -~ Ambient~E ~ AmbientT~E DRUM/BARRELEMETALLI~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 600.00 LBS 1500.00 LBS 1000.00 LBS tll-~GL~ICLUUw~ lrU1~lYUlV~1Vl~7 sWt. RS CAS# 17.00 Arsenic Pentoxide (EPA) No 1303282 24.00 Chromic Acid, Solid No 1333820 9.00 Cupric Oxide No 1317380 t1HGHKL Yi5 51;JJ1~11;1V 1 ~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No No/ Curies IH j / / Hi ~ Inventory Item 0002 Facility Unit: DRI-CON STORAGE ~ COMMON NAME / CHEMICAL NAME HYDROGEN PEROXIDE 50% Days On Site H202 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# 7722-84-1 Liquid TMixture T Ambient~E ~ AmbientT~E DRUM/BARRELENONMETAL~ AMOUNTS AT THIS LOCATION - Largest Container Daily Maximum I Daily Average 3100.00 LBS 1000.00 LBS 500.00 LBS riLiGHKLV U.7 1.U1~lYUlV~1V 1.7 %Wt. RS CAS# 50.00 Hydrogen Peroxide No 7722841 nt~~tilcL ti~al~,~~lnl~,lvia TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No No/ Curies F P / / / Hi -10- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0006 Facility Unit: DRI-CON STORAGE ~ COMMON NAME / CHEMICAL NAME DRI-CON FIRE RETARDANT Days On Site 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# ~SolidE TMixture ~ Ambient~E ~ AmbientTURE BAG CONTAINER TYPE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 2000.00 LBS LBS 12000.00 LBS lYHGHKLVU.7 1.V1~1rV1VL" 1V 15 - %wt. Rs cAS# 27.00 Boric Acid No 10043353 4.00 Phosphoric Acid No 7664382 t11~GLiCCL HJAI~,~.~1~11;1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Mod ~ Inventory Item 0007 COMMON NAME / CHEMICAL NAME WASTE OIL Location within this Facility Unit BEHIND DRI-CHEM = Facility Unit: DRI-CON STORAGE ~ Days On Site 365 Map: Grid: CAS# l 1221 Liquid TWaste ~ AmbRent~E ~ AmbientT~E DRUM/BARRELEMETALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 GAL 165.00 GAL 110.00 GAL ri1~GL-~tCLVUa ~:V1nrVlvr.lyla %Wt. RS CAS# 100.00 Waste Oil, Petroleum Based No 0 I11~GEiKL E3b ~~5.71~1J;1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F~ DH / / / Low -11- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE ~ Inventory Item 0004 COMMON NAME / CHEMICAL NAME PAC-BOR BORATES Location within this Facility Unit SW CRNR PLANT STATE TYPE PRESSURE TEMPE Solid TMixture ~ Ambient ~ Ambie AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 1978.00 LBS 100000.00 LBS 100000.00 LBS HAZARDOUS COMPONENTS %Wt. RS CAS# t1HGL~tCL F~~~L' S~1~1~1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / UnR SiteID: 015-021-000567 ~ Facility Unit: DRI-CON STORAGE ~ Days On Site 365 p: Grid: CAS# RE CONTAINER TYPE BAG -12- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0001 Facility Unit: ACQ/PAC-BOR TANKS ~ COMMON NAME / CHEMICAL NAME AMMONIA SOLUTION Days On Site ACQ - AMMONIA COPPER QUAT 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# Liquid TMixture ~mbRient~E ~ A~PeRATURE ~OVEOGROUNDRTANKE AMOUNTS AT THIS LOCATION Largest~Container Daily Maximum Daily Average 36072.00 GAL 36072.00 GAL 3.6072.00 GAL r1H~Ktciluua ~ul~lruivlJivla %Wt. RS CAS# 15.00 Copper (II) Carbonate, Basic No 12069691 1.00 Ammonia (EPA) Yes 7664417 riAGHKL 1-~aaL" 5.'71~1L" 1V 1 ~J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No No/ Curies F IH / / / Mod ~ Inventory Item 0002 ~ COMMON NAME / CHEMICAL NAME BORIC ACID Facility Unit: ACQ/PAC-BOR TANKS ~ Days On Site 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# 10043-35-3 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Solid TPure Ambient ~ Ambient BAG AMOUNTS AT THIS LOCATION Largest Con55100rLBS Daily8000100m LBS I Daily4000r00e LBS nr~~r~cl~uua ~vrlrulv~lvla %Wt. RS CAS# 100.00 Boric Acid No 10043353 111~GHKL L~~.7C~~51~1J;1V1~7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Low -13- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE _ ~ Inventory Item 0007 COMMON NAME / CHEMICAL NAME DRICON FIRE RETARDENT WORK SOLUTION Location within this Facility Unit CCA TANK FARM STATE TYPE PRESSURE Liquid TMixture ~ Ambient SiteID: 015-021-000567 ~ Facility Unit: ACQ/PAC-BOR TANKS ~ Days On Site 365 Map: Grid: CAS# TEMPERATURE CONTAINER TYPE Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 36096.00 GAL 36096.00 GAL 36096.00 GAL ,- HAZARDOUS COMPONENTS °sWt . RSA CAS# t11jL,HtCL 1-~J~t',~Jl~ll~,1V 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / UnR ~ Inventory Item 0004 COMMON NAME / CHEMICAL NAME PACBOR MIXTURE 2.60 Location within this Facility Unit CCA TANK FARM STATE TYPE PRESSURE Liquid TMixture ~mbient Facility Unit: ACQ/PAC-BOR TANKS ~ Days On Site 365 Map: Grid: CAS# 12280-03-4 TEMPERATURE CONTAINER TYPE Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 29000.00 GAL 29000.00 GAL 29000.00 GAL HAZARDOUS COMPONENTS %Wt. RSI CAS# tll-~GL•itC1J E~551J~7.71~1J;1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R / / / UnR -14- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0003 Facility Unit: ACQ/PAC-BOR TANKS ~ COMMON NAME / CHEMICAL NAME QUATERNARY AMMONIA COMPOUND Days On Site 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# 7173-51-5 Liquid TMixtur~mbient~E ~ AmbientT~E OTHER NTSPECIFYYPE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 2000.00 LBS 24000.00 LBS 12000.00 LBS HAZARDOUS COMPONENTS oWt. RSI CAS# t11-~GE~tCL 1~~.7~bJ1~1~1V 1 ~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F IH / / / UnR ~ Inventory Item 0005 COMMON NAME / CHEMICAL NAME ACQ-C COPPER AMMONIUM CARBONATE SOLUTION Location within this Facility Unit SW CRNR PLANT STATE TYPE PRESSURE Liquid TMixtur~mbient Facility Unit: ACQ/PAC-BOR TANKS ~ Days On Site 365 Map: Grid: CAS# TEMPERATURE CONTAINER TYPE Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 6000.00 GAL 6000.00 GAL 6000.00 GAL HAZARDOUS COMPONENTS °sWt . RSI CAS# l1HGLi.tCL H. 7.7~.7.71~iL"1V1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / UnR -15- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0006 Facility Unit: ACQ/PAC-BOR TANKS ~ COMMON NAME / CHEMICAL NAME ACQ-CZ Days On Site AQUEOUS COPPER SOLUTION 365 Location within-this Facility Unit Map: Grid: SW CRNR PLANT CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixture Ambient ~ Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 6000.00 GAL 6000.00 GAL 6000.00 GAL HAZARDOUS COMPONENTS , %Wt. RSI CAS# riHL,Ktt1J H55r,J~1~1L'1V1~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / UnR -16- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0001 Facility Unit: SW STORAGE AREA ~ COMMON NAME / CHEMICAL NAME DEGREASER -AROMATIC HYDROCARBONS Days On Site 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# 71556 Liquid TMixture i Ambient~E ~ AmbientT~E DRUM/BARRELEMETALLI~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum ~ I Daily Average 55.00 GAL 110.00 GAL 40.00 GAL - t1AGE1KLUU~ 1,U1~lYV1VL' 1V 1 J %Wt. RS CAS# 40.00 Aromatic Naphtha No 8030306 rua~r-Lrc~ r35 51,aal~i~ly l TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F / / / Mod -17- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0003 Facility Unit: MAINTENANCE SHOP ~ COMMON NAME / CHEMICAL NAME ACETYLENE Days On Site 365 Location within this Facility Unit Map: Grid: E SIDE MAINT BLDG CAS# 74-86-2 ~GasATE TYPE T PRESSURE TEMPERATURE CONTAINER TYPE TPure I Above Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 145.00 FT3 420.00 FT3 350.00 FT3 t~u~~~ru~~ua ~vrirvlvlJiv l oWt. RS CAS# 100.00 Acetylene Yes 74862 riHGHl[L L~~ JJ1",571~1r,1V l5 TSecret - RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Hi ~ Inventory Item 0002 COMMON NAME / CHEMICAL NAME OXYGEN Location within this Facility Unit E SIDE MAINT BLDG Facility Unit: MAINTENANCE SHOP ~ Days On Site 365 Map: Grid: CAS# 7782-44-7 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas Pure Above Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 250.00 FT3 843.00 FT3 700.00 FT3 t1EiGEiKL V U .7 l.. Vl~lr V1V L" 1V 1 ~ %Wt. RS CAS# 100.00 Oxygen, Compressed No 7782447 !'11~LiHKL 1-~J.7J~J~~1~11;1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Low -18- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0001 Facility Unit: MAINTENANCE SHOP ~ COMMON NAME / CHEMICAL NAME CHEVRON HYDRAULIC OIL 68 Days On Site 365 Location within this Facility Unit Map: Grid: E SIDE MAINT SHOP CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE _ Liquid Pure Ambient ~ Ambient DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 GAL 110.00 GAL 55.00 GAL tiFlz,AttUUU~ 1:u1~lYU1Vr,;1V 15 %Wt. RS CAS# 100.00 Brake Fluid, Hydraulic (Diethylene Glycol Monob... No 0 riAGAtCiJ AJ51";~~l~lt'~1V"1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F DH / / / Low ~ Inventory Item 0004 COMMON NAME / CHEMICAL NAME MOTOR OIL Location within this Facility Unit E SIDE MAINT BLDG STATE TYPE PRESSURE Liquid TMixture ~ Ambient Map: Grid: CAS# Facility Unit: MAINTENANCE SHOP ~ Days On Site 365 TEMPERATURE CONTAINER TYPE _ Ambient DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 GAL 110.00 GAL 55.00 GAL ru-iatucLUU~ ~.ui~irutv~iv t ~ °sWt. RS CAS# 100.00 Motor Oil, Petroleum Based No 8020835 tltiGtitCL 1-~~J .7L.~7.71~1~1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F DH / / / Min -19- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ Fast Format ~ ~ Notif./Evacuation/Medical Overall Site ~ ~ Agency Notification 04/19/2006 ~ CALL 911 FOR EMERGENCY ASSISTANCE. REPORT HAZARDOUS MATERIAL SPILLS WHICH EQUAL OR EXCEED 42 GAL, 500 LBS, OR 200 CF, OR WHICH THREATEN LIFE, HEALTH, OR THE ENVIRONMENT IMMEDIATELY. CALL: BAKERSFIELD FIRE DEPT HAZMAT DIV 326-3979 AND CAOES 800-638-1821. SPILLS EQUAL TO OR EXCEEDING 1 POUND OF ARSENIC PENTOXIDE MUST ALSO BE REPORTED TO THE FEDERAL GOVERNMENT. CALL: NATIONAL RESPONSE CENTER 800-424-8802. Employee Notif./Evacuation 04/19/2006 ALL PERSONNEL, VISITORS, AND CONTRACTORS WILL EXIT THROUGH THE FRONT GATE. ALL PERSONS WILL BE ACCOUNTED .FOR BY THEIR IMMEDIATE SUPERVISOR. Public Notif./Evacuation VERBAL, PUBLIC IN OFFICE AREA ONLY. 02/22/2000 Emergency Medical Plan 02/22/2000 NEAREST HOSPITAL. -20- 07/13/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall Site ~ ~ Release Prevention 04/19/2006 ~ CLOSED SYSTEM FOR FILLING AND EMPTYING TREATMENT CYLINDERS. TANKS AND RETORT CYLINDERS HAVE HIGH LEVEL SHUT-OFF SWITCHES, VALVES OPERATE IN FAIL-SAFE POSITION IN THE EVENT OF LOSS OF AIR TO AIR-OPERATED VALVES. ALL PRESSURE VESSELS ARE EQUIPPED WITH PRESSURE-RELIEF VALVES. WRITTEN EMERGENCY CONTINGENCY PLAN OUTLINES PROCEDURES FOR RESPONSE TO EMERGENCY CONDITIONS. Release Containment 04/19/2006 A CONCRETE TANK DIRECTLY UNDER EACH WOOD TREATMENT CYLINDER IS CAPABLE OF HANDLING THE TOTAL CONTENTS OF ANY ONE TANK. EACH TANK IS IN A BLOCK WALL RETAINER OR CEMENT WALL RETAINER WHICH DRAINS TOWARDS THE CONCRETE PITS. PIPING FROM THE RAILCAR DESPENSING STATION IS PROTECTED WITH SECONDARY CONTAINMENT PIPE WHICH DRAINS INTO A CONTAINMENT BASIN. Clean Up 04/19/2006 ADVANCED CLEAN-UP TECHNOLOGIES 392-7765 HAS THE EQUIPMENT AND MEANS TO HANDLE ANY SPILL. V1.11C 1. LCCSV LLLUC L'iC.: l.1Vdl~1 V11 -21- 07/13/2007 4 ti F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ i7t.JCV1C1,1 ncl~cLiuS Utility Shut-Offs A) GAS - NW CRNR PROP B) ELECTRICAL - SW CRNR MAIN BLDG/SW CRNR TREATING BLDG C) WATER - N PERIMETER lOFT FROM CURB CTR OF LOT D) SPECIAL - NONE E ) LOCK BOX - NO F, ~~AS ' N~ COJt1GV ~~ IMF v~ c~~-~'iG~ 02/22/2007 Fire Protec./Avail. Water 02/05/2007 PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS, SMOKE ALARMS IN FRONT OFFICE BLDG WHICH CAN BE PICKED UP BY SECURITY ALARM SYSTEM (SONITROL) AFTER HOURS. NEAREST FIRE HYDRANT - 3 FIRE HYDRANTS IN MIDDLE OF PLANT PROP. Building Occupancy Level 30 EMPLOYEES 03/14/2006 -22- 07/13/2007 a` ~, - ~y i°' i. F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ Fast Format ~ ~ Training Overall Site ~ ~ Employee Training 11/27/2006 ~ MATERIAL SAFETY DATA SHEETS ON FILE. BRIEF SUNIMARY OF TRAINING PROGRAM: ALL EMPLOYEES ATTEND SAFETY AND MATERIAL TRAINING MEETINGS EVERY MONTH. THEY ARE TRAINED IN HOW TO HANDLE THE CHEMICALS PWPB HAS IN ITS INVENTORY, AS WELL AS INSTRUCTION OF MSDSS FOR THOSE SAME CHEMICALS. WRITTEN QUESTIONNAIRE USED TO MEASURE COMPREHENSION OF SAFETY TRAINING. WRITTEN RESPIRATOR TRAINING MANUAL OUTLINES MAINTENANCE AND USE OF RESPIRATORS. rayC ~ nciu LvL r u~.uLC U~c 17C1U LUL lul.uLC U.7-C -23- 07/13/2007 UNIFIED PROGRAM INSPECTION CHECKLIST 319M'S"'::r;.k'....!'?kiSe..+:t^£.Frv..... X.$.,[~..c..t :<:'-:~ifi .-, ::'Y": '" .: ~; :' .. ~.•_ .- ~~.,x .SECTION 1: Business Plan and Inventory Program • I/tI ~Rrr BAKERSFIELD FIRE DEPT Prevention Services 900 Truxtun Ave., Suite 210 Bakersfield, CA 93301 Tel.: (661) 326-3979 Fax: (661) 872-2171 FACILI Y NAME `A ~ - ~~V ~ ~ ~~ ~ NS`PgECTION DAT ~ ~~~~ NSPECC~TI~ON TIME ~ Vt ~~..~0 1 L v~'~ ' 1 1 ~ ~' ADDRESS ~ b01 ~~ 5`~'~t ~~ ~~ H0~3 ~ ©~ Z~ O~ EMPLOYEES v FACILITY CONTACT ~; ~ MSC. u lpv USINESS ID NUMBER ~s-oz~- po~~b 7 Section 1: Business Plan and Inventory Program ~ `~~ ROUTINE ^ COMBINED ^ -JOINT AGENCY ^ MULTI-AGENCY ^ COMPLAINT ^ RE-INSPECTION • C V ~ C=Compliance OPERATION V=Vblation COMMENTS - ^ APPROPRIATE PERMIT ON HAND . ^ BUSlflt?SS PLAN CONTACT INFORMATION ACCURATE ^ VISIBLE ADDRESS ^ CORRECT OCCUPANCY - i D~ C O 9 ~006 ^ VERIFICATION OF INVENTORY MATERIALS ^ . VERIFICATION OF QUANTITIES ^ VERIFICATION OF LOCATION ^ ^ ^ PROPER SEGREGATION OF MATERIAL VERIFICATION OF MSDS AVAILABILITY VERIFICATION OF HAZ MAT TRAINING -~ [ l ~~ ^ VERIFICATION OF ABATEMENT SUPPLIES AND ROCEDURES ~S ^ EMERGENCY PROCEDURES ADEQUATE ^ CONTAINERS PROPERLY LABELED ~1 ^ HOUSEKEEPING ,~ ^ FIRE PROTECTION ^ SITE DIAGRAM ADEQUATE 8 ON HAND ANY HAZAR~DQ US WASTE ON SITES ,~ YES`~~^ NO EXPLAIN: W~S~ ~ 1 ~ '~ C,,C,~ e$t.~-. '~~~ •OUE S REGARDING THIS INSPECTION? PLEASE CALL US AT (861) 326-3979 Inspector Ple Print) Fire Prevention / 1" In / Shift of Slte/Station # Business School She Responsible Perry (Please Print) White -Prevention Services Yellow -Station Copy Pink - Suainesa Copy FD2049 (Rev. 02105) l~~ ~L" Fri CITY OF BAKERSFIELD FIRE DEPARTMENT ~~~y ~~ OFFICE OF ENVIRONMENTAL SERVICES a ~ .y'r UNIFIED PROGRAM INSPECTION CHECKLIST .. • ~rr.E'~~ti~ 1715 Chester Ave., 3~d Floor, Bakersfield, CA 933Q1 ~ ~p 1 ~`"~~ Phone: 661 326-3979 Fax: 661 326-0576 ( ) ( ) FACILITY NAME ~Ot.i!%`C~ ~~ INSPECTION DATE Zi r2z~o:~ LOCATION S(oO l ~JtS-N~-~c->' PROGRAM LEVEL l n Section 7: California Accidental Release Program (CaIARP) Risk Management Plan ~~j'd'~ j ^ Routine V~. Combined ^ Joint Agency ^Muhi-Agency ^ Complaint ^ Re-inspection C=Compliance V=Violation Comments: r ~'~~ GkF~-C.iG. Sy+~l P ~ p~~ S~~n1S Or C~~.tCAC~_ .Inspector: W f ~~-~ Office of Environmental Services (661) 326-3979 RISK MANAGEMENT PLAN -PREVENTION PROGRAM C V COMMENTS Compliance Audits 5 Year Accident History Incident Investigation Emergency Response Program Hazard Assessment ~ $vnnp -~ t~.~4ToJE55 Safety Information Training Documentation Operating Procedures Maintenance Procedures - Mechanical Integrity - Management of Change - Pre-Start Up Review ' O - Employee Participation D - Hot Work Permit - Contractor Safety C Business ite Responsible Party White -Env. Svcs. Pink -Business Copy ~0ty` ~~z" CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES • ~' .y UNIFIED PROGRAM INSPECTION CHECKLIST tk~`' gti~~ 1715 Chester Ave., 3`d Floor, Bakersfield, CA 93301 FACILITY NAME ~l~G~~rG ~~ INSPECTION DATE < < ZZ ,~j Sectaon 4: Hazardous Waste Generator Program EPA ID # ~ ~ Oo0 (o l 11`f ~ ® Routine ~ Combined ^ 3oint Agency ~ Multi-Agency ~ ^ Complaint D Re-inspection C • OPERATION C V COMMENTS Hazardous waste determination has been made EPA ID Number Authorized for waste treatment and/or storage Reported release, fire, or explosion within 15 days of occurrence Established or maintains a contingency plan and training Hazardous waste accumulation time frames Containers in good condition and not leaking Containers are compatible with the hazardous waste Containers are kept closed when not in use P t_E/~~ t•(C6/' L, 45 u~J O2tJM Weekly inspection of storage area Ignitable/reactive waste located at least 50 feet from property line Secondary containment provided Conducts daily inspection of tanks Used oil. not contaminated with other hazardous waste ' r r!F Proper management of lead acid batteries including labels Proper management of used oil filters Transports hazardous waste with completed manifest Sends manifest copies to DTSC Retains manifests for 3 years Retains hazardous waste analysis for 3 years Retains copies of used oil receipts for 3 years Determines if waste is restricted from land disposal C=Compliance V=Violation Inspector: ~ ~ N ~ Office of Environmental Services (661) 326-3979 White -Env. Svcs. l ~' Business 'te Responsible Party Pink -Business Copy v a/~.. CITY OF BAKERSFIELD FIRE DEPARTMENT OFFICE OF ENVIRONMENTAL SERVICES UNIFIED PROGRAM INSPECTION CHECKLIST 1715 Chester Ave., 3rd Floor, Bakersfield, CA 93301 ~ f- "~ ~ ne: (661) 326-3979 Fax: (661) 326-0576 ~ ~O FACILITY NAME ~ 2~'`~'~t'JG INSPECTION DATE ~ Z ~ z ~0 3 LOCATION Sb o + n s ST2-tcT ~w~ P~pc rR~~l`~:F`[E~~ r f_-- r ., Section 7: California Accidental Release Program (CaIARP) Risk Management Plan ^ Routine Combined ^ Joint Agency ^Minti-Agency ^ Complaint ^ Re-i pection RISK MANAGEMENT PLAN -PREVENTION PROGRAM C V COMMENTS Compliance Audits / NK~s~(y~ ~2V S Y~-S 5 Year Accident History / i.J f ,fir Incident Investigation / n~~lk - i~J'r ;ykS ~ ,/ Emergency Response Program Hazard Assessment Safety Information ~/ Training Documentation Operating Procedures Por~i,/ciQt,~y ~2T! r~ Maintenance Procedures - Mechanical Integrity ~I~, P,~~ ~ ~,~ - Management of Change - Pre-Start Up Review ~ v- - Employee Participation - Hot Work Permit - Contractor Safety hiE,' ~ 5-299.2 Comments: ~'2o~'v1 Z /~ ~S C=Compliance V=Violation /~. ~ /8 Cep ~ • aL ~~ U ~~ °-'-- lJ~')') O ! 8 Inspector: W 1 NL--5 Office of Environmental Services (661) 326-3979 fN Business Site responsible Party White -Env. Svcs. Pink -Business Copy ya+ P ,~O~y4~ f~~ CITY OF BAKERSFIELD FIRE DEPARTMENT 'J~ ~`` ~ OFFICE OF ENVIRONMENTAL SERVICES ~' •y UNIFIED PROGRAM INSPECTION CHECKLIST `k•L,'~gti _____1715-Chester eve.,-"3'~FI6or, sfield, CA 93301 FACILITY NAME 1'~<<c- ~~ ..°•~~/~~` -- Section 4: Hazardous Waste Generator Prog-r m ~ 5~y INSPECTION DATE t z l a /n3 EPA ID # ~-~ 611 14S ^ Routine ~- Combined ^ Joint Agency ^Multl-Agency ^ Complaint ^ Re-inspection OPERATION C V COMMENTS Hazardous waste determination has been made t/ EPA ID Number (Phone: 916-324-1781 to obtain EPA ID #) AFC Authorized for waste treatment and/or storage Z0~ Reported release, fire, or explosion within 15 days of occurrence IJ ,!k Established or maintains a contingency plan and training / Hazardous waste accumulation time frames r/ Containers in good condition and not leaking Containers are compatible with the hazardous waste / Containets are kept closed when not in use Weekly inspection of storage area Ignitable/reactive waste located at least 50 feet from property line ,~l ~k Secondary containment provided l~,t~s ~./~c~ Conducts daily inspection of tanks / Used oil not contaminated with other hazardous waste / Proper management of lead acid batteries including labels ~ Proper management of used oil filters / Transports hazardous waste with completed manifest ,/ Sends manifest copies to DTSC ,/ Retains manifests for 3 years Retains hazardous waste analysis for 3 years / Retains copies of used oil receipts for 3 years Determines if waste is restricted from land disposal c;=c;ompuance v=vtotatton ~/ Inspector: ~ ~^~ ~ ~ ~`l//~ Office of Environmental Services (661) 326-3979 Business Sit espon ~ y- White -Env. Svcs. Pink -Business Copy BAKERSFIELD FIRE DEPT UNIFIED PROGRAM INSPECTION CHECKLIST; a A 1 D Prevention Services ~iiR~ 900 Truxtun Ave., Suite 210 ~.: ~,..;,,u ~~~~~,,.,-, :, , . ,. ~..:.... .:: ,.. .::.: >..:, -: :..1 ..,;, .,..-..: ,, . ARTA1 t Bakersfield, CA 93301 SECTION 1: Business Plan and Inventory Program Tel.: (661) 326-3979 Fax: (661) 872-2171 FACILITYNA~~~/~~ A ~ ~ ~~~ V NSPECTI~ DAT© I C .• INSPECTION TIME ~ ADDRESS ~Zno ~/~T12JGT ~1- -' ONE NO . 8~3-oL! O OF EMPLOYEES ~ FACILITY CONTACT / ~ C ~ /~ ~ ~ 1'l LL Df>CTtt7~" -- ~ ~/2.. USINESS ID NUMBER ~y 15-021- ~ / ~~ Section 1: Business Plan and Inventory Program ROUTINE ^ COMBINED ^ JOINT AGENCY ^ MULTI-AGENCY ^ COMPLAINT ^ RE-INSPECTION C V ~ C=Compliance OPERATION V=Violation COMMENTS ^ APPROPRIATE PERMIT ON HAND ^ BUSIIIeSS PLAN CONTACT INFORMATION ACCURATE ^ VISIBLE ADDRESS ^ CORRECT OCCUPANCY ^ VERIFICATION OF INVENTORY MATERIALS L ~ - / Lt:i ^ VERIFICATION OF QUANTITIES ^ VERIFICATION OF LOCATION ^ PROPER SEGREGATION OF MATERIAL -/ l~f ^ VERIFICATION OF MSDS AVAILABILITY ^ VERIFICATION OF HAZ MAT TRAINING ^ VERIFICATION OF ABATEMENT SUPPLIES AND PROC URES ^ EMERGENCY PROCEDURES AgEOUATE ^ CONTAINERS PROPERLY LABELED ^ HOUSEKEEPING ^ FIRE PROTECTION ^ SITE DIAGRAM ADEQUATE 8 ON HAND ANY HAZARDOUS WASTE ON SITE? EXPLAIN: ^ NO 2005 QUESTIONS REGARDING THIS INSPECTION? PLEASE CALL US AT (661) 326-3979 ,1'~ .V ~ ~~I~C~'Q~ pector (Please Print) Fire Prevention / 1s' In /Shift of Site/Station # Business Site/School i Responsible Party (Please Print) White -Prevention Services Yellow -Station Copy Pink -Business Copy FD2049 (Rev. 02/05) -E PACIFIC WOOD PRESERVING/BAKERSFIE Manager RICK MCCULLOUGH Location: 5601 DISTRICT BLVD City BAKERSFIELD CommCode: BFD STA 13 EPA Numb: CAT000611145 SiteID: 015-021-000567 BusPhone: (661) 833-0429 Map 123 CommHaz High Grid: 15D FacUnits: 7 AOV: SIC Code:2491 DunnBrad:ll-881-0514 Emergency Contact / Title Emergency Contact / Title RICK MCCULLOUGH / PLANT MANAGER CASEY ZIEMER / ASST PLANT MGR Business Phone: (661) 833-0429x36 Business Phone: (661) 833-0429x38 24-Hour Phone (661) 201-3203x 24-Hour Phone (661) 979-3598x Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: RSs Fire Press React ImmHlth DelHlth Contact RICK MCCULLOUGH Phone: (661) 833-0429x36 MailAddr: 5601 DISTRICT BLVD State: CA City BAKERSFIELD Zip 93313 Owner RICHARD JACKSON Phone: (775) 832-5225x Address 668 TYNER WY State: NV City INCLINE VILLAGE Zip 89451 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: Yes ParcelNo: Emergency Directives: PROG A - HAZMAT PROG H - HAZ WASTE GEN PROG R - CAL ARP PROG T - ABOVEGROUND STORAGE TANK THIS IS A RMP SITE AND REQUIRES A JOINT INSPECTION, CALL ENV SVCS TO SCHEDULE THIS INSPECTION. i3ased on my inquiry of these indivicfuais responsible for obtaining the information. I certify under penalty of law that I Nava personally examined and am familiar with the information submitted and believe the information ie true, accurate, and complete. 9 e Date ENT°D F E ~ 2 ~ ZO07 -1- 02/05/2007 -, F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order CCA TANK FARM ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP CHROMIC ACID SOLUTION F R IH DH L 36096.00 GAL Hi WOLMANAC R CONCENTRATE - 60°s IH L 5000.00 GAL Hi JPC DIESEL #2 F IH DH L 500.00 GAL Low -2- 02/05/2007 ~l ~ I F PACIFIC WOOD PRESERVING/BAKERSFIE ~ Hazmat Inventory ~ MCP+DailyMax Order SiteID: 015-021-000567 ~ By Facility Unit ~ DRI-CON STORAGE ~ Hazmat Common Name... SpecHaz EPA-Hazards Frm DailyMax Unit MCP CCA WASTE IH S 1500.00 LBS. Hi HYDROGEN PEROXIDE 50 o F P L ~ Zoe 1-@69~-9~8-LBS Hi DRI-CON FIRE RETARDANT S 44000.00 LBS Mod WASTE OIL F DH L 165.00 GAL Low PAC-BOR S 100000.00 LBS UnR -3- 02/05/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order ACQ/PAC-BOR TANKS ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP AMMONIA. SOLUTION E F IH L 36072.00 GAL Mod BORIC ACID S 8000.00 LBS Low PACBOR MIXTURE R L 29000.00 GAL UnR QUATERNARY AMMONIA COMPOUND F IH L 24000.00 LBS UnR -4- 02/05/2007 y,. F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order SW STORAGE AREA ~ Hazmat Common .Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP DEGREASER -AROMATIC HYDROCARBON F L 110.00 GAL Mod -5- 02/05/2007 ~1 '~ F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order MAINTENANCE SHOP ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP ACETYLENE E F P IH G 420.00 FT3 Hi OXYGEN F P IH G 843.00 FT3 Low CHEVRON HYDRAULIC OIL 68 F DH L 110.00 GAL Low MOTOR OIL F DH L 110.00 GAL Min -6- 02/05/2007 -7- 02/05/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0004 Facility Unit: CCA TANK FARM ~ COMMON NAME / CHEMICAL NAME CHROMIC ACID SOLUTION Days On Site CCA MIXTURE 365 Location within this Facility Unit Map: Grid: CCA TANK FARM CAS# 1333-82-0 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixtur~ Ambient ~ Ambient ABOVE GROUND TANK Largest Container 36096.00 GAL AMOUNTS AT THIS LOCATION Daily Maximum 36096.00 GAL Daily Average 36096.00 GAL t1E~G1-~KLVUJ 1:V1~lYV1Vt51V"1J °sWt. RS CAS# 0.10 Chromic Acid No 1333820 0.20 Arsenic Pentoxide (EPA) No 1303282 0.10 Cupric Oxide No 1317380 t1HGHKL 1-~J JL' aa1~111V 1a TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No Noj Curies F R IH DH / / / Hi ~ Inventory Item 0003 Facility Unit: CCA TANK FARM ~ AMOUNTS AT THIS LOCATION Largest C6400100rGAL Daily5000100m GAL I Daily2000r00e GAL riAGH2CLVUa 1:V1~lYV1VtS1Vla oWt. RS CAS# 17.00 Arsenic Pentoxide (EPA) No 1303282 24.00 Chromic Acid, Solid No 1333820 9.00 Cupric Oxide No 1317380 nr~~,titcl~ teal,aaril;lyta TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / Hi -8- 02/05/2007 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixture ~ Ambient ~ Ambient ABOVE GROUND TANK F PACIFIC WOOD PRESERVING/BAKERSFIE _ ~ Inventory Item 0002 COMMON NAME / CHEMICAL NAME JPC DIESEL #2 Location within this Facility Unit SW OF PLANT BEHIND ACQ TANK FARM STATE TYPE ~~ PRESSURE Liquid TMixture I Ambient Map: TEMPERATUR Ambient SiteID: 015-021-000567 ~ Facility Unit: CCA TANK FARM ~ Days On Site 365 Grid: CAS# 68476-34-6 E CONTAINER TYPE ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Co550100rGAL Daily 500100m GAL I Daily 300r00e GAL nr~~r~tcLwS wi~ir~iv~lv~t5 sWt. RS CAS# 100.00 Diesel Fuel No. 2 No 68476302 t1HGL~iC1J H5 5~J51~1~1V 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F IH DH / / / 'Low -9- 02/05/2007 .` F PACIFIC WOOD PRESERVING/BAKERSFIE SitelD: 015-021-000567 ~ ~ Inventory Item 0005 Facility Unit: DRI-CON STORAGE ~ COMMON NAME / CHEMICAL NAME CCA WASTE Days On Site COPPER, CHROMIUM, ARSENATE COMPOUNDS SLUDGE WASTE 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Solid TWaste ~ Ambient ~ Ambient DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 600.00 LBS 1500.00 LBS 1000.00 LBS ru-~~fuct~~u5 ~~1~irVlv1;1v1~ %Wt. RS CAS# 17.00 Arsenic Pentoxide (EPA) No 1303282 24.00 Chromic Acid, Solid No 1333820 9.00 Cupric Oxide No 1317380 ru~~tirc.v t~~ ~~aalnlJivla TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No No/ Curies IH / / / Hi ~ Inventory Item 0002 COMMON NAME / CHEMICAL NAME HYDROGEN PEROXIDE 50% H2O2 Location within this Facility Unit SW CRNR PLANT STATE TYPE PRESSURE Liquid TMixture T Ambient Facility Unit: DRI-CON STORAGE ~ Days On Site 365 Map: Grid: CAS# 7722-84-1 TEMPERATURE CONTAINER TYPE Ambient DRUM/BARREL-NONMETAL AMOUNTS AT THIS LOCATION Largest ContS~$rLBS Daily1000100m LBS I Daily 500r00e LBS 3t~o' riAGKKLVUS 1:V1~lYV1VL"1V1J %Wt. RS CAS# 50.00 Hydrogen Peroxide No 7722841 t1HGEiKL HbJr,J~1~1~1V1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No Noj Curies F P / / / Hi -10- 02/05/2007 ,' F PACIFIC WOOD PRESERVING/BAKERSFIE _ ~ Inventory Item 0006 COMMON NAME / CHEMICAL NAME DRI-CON FIRE RETARDANT Location within this Facility Unit SW CRNR PLANT STATE TYPE PRESSURE Solid TMixture Ambient SiteID: 015-021-000567 ~ Facility Unit: DRI-CON STORAGE ~ Days On Site 365 Map: Grid: CAS# TEMPERATURE CONTAINER TYPE Ambient BAG AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 2000.00 LBS 44000.00 LBS 12000.00 LBS ns~Gxtu~uu~ ~vlnrulvr~iv l ~ -- oWt. RS CAS# ' 27.00 Boric Acid No 10043353 4.00 Phosphoric; Acid No 7664382 t1HGE~1[L ti7a~~51~11:,1v1a TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Mod ~ Inventory Item 0007 Facility Unit: DRI-CON STORAGE ~ COMMON NAME / CHEMICAL NAME WASTE OIL Days On Site 365 Location within this Facility Unit Map: Grid: BEHIND DRI-CHEM CAS# 221 STATE TYPE PRESSURE TEMPERATURE Liquid TWaste ~ Ambient ~ Ambient CONTAINER TYPE _ DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum ~ Daily Average 55.00 GAL 165.00' GAL 110.00 GAL riEiGH1CLV u 5 1=V1~1rulV I;1V 1 a %Wt. RS CAS# 100.00 Waste Oil, Petroleum Based No 0 IlL'iGHtCL H. 7.725.7.7P71:,1V 1 ~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No. No No/ Curies F DH / / / Low -11- 02/05/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0004 Facility Unit: DRI-CON STORAGE ~ COMMON NAME / CHEMICAL NAME PAC-BOR ,Days On Site BORATES 365 Location within this Facility Unit Map: Grid: ~~: C.~~T'=~Y ~.w G+Rt+I~ I~~isw•~- CAS# STATE TYPE ~- PRESSURE TEMPERATURE CONTAINER TYPE Solid Mixture I Ambient ~ Ambient BAG AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average ~9'7~6 i'6s Ste. ~~~ LBS 100000.00 LBS 100000.00 LBS HAZARDOUS COMPONENTS %Wt. RS CAS# ~ZARD AS SESSMENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / UnR -12- 02/05/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0001 Facility Unit: ACQ/PAC-BOR TANKS ~ 'i COMMON NAME / CHEMICAL NAME AMMONIA SOLUTION Days On Site ACQ - AMMONIA COPPER QUAT 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# STATE TYPE ~~ PRESSURE TEMPERATURE CONTAINER TYPE Liquid Mixture I Ambient ~ Ambient ABOVE GROUND TANK AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 36072.00 GAL 36072.00 GAL I 36072.00 GAL •--••-- ny,GHrcLVUa ~vrirviv~lv_1_~ %Wt. RS CAS# 15.00 Copper (II) Carbonate, Basic No 12069691 1.00 Ammonia (EPA) Yes 7664417 -- riHGtiKL H~ .7~.»1~1L' 1V 1 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No Yes No No/ Curies F IH / / / Mod ~ Inventory Item 0002 Facility Unit: ACQ/PAC-BOR TANKS ~ COMMON NAME / CHEMICAL NAME BORIC ACID Days On Site 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# 10043-35-3 ~SolidE TPureE ~ Ambient~E ~ A~PeRATURE BAG CONTAINER TYPE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 LBS 8000.00 LBS I 4000.00 LBS rill[-~riRLV V.~ L.V1"lt'V1V P~1V 1J %Wt. RS CAS# 100.00 Boric Acid No 10043353 riliL~L-!.[CL !-iJ J Li ~7.71•iL~1V 1 .7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Low -13- 02/05/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ I 0004 it F ilit U /PAC-BOR TANKS AC ~ nventory Item ac y n : ~ Q COMMON N ME / CHEMICAL NAME A PACBOR MIXTURE Days On Site ~ 2 . 6 0 365 ~'` hi hi ili i i i id M G Locat on w t n t s Fac ty Un t r : ap: CAS# ~.Cw ~-t--Q~~ ~4v~ 12280-03-4 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid T Mixture ~-Ambient ~ Ambient ~VE GROUND TANK _~ AMOUNTS AT THIS LOCATION - Largest Container Daily Maximum Daily Average 29000.00 GAL 29000.00 GAL 29000.00 GAL ,- HAZARDOUS COMPONENTS %Wt. RSI CAS# riHL,F1tCL 1~,7,JL" J51~1~1V 1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R / / / UnR ~ Inventory Item 0003 Facility Unit: ACQ/PAC-BOR TANKS ~ COMMON NAME / CHEMICAL NAME QUATERNARY AMMONIA COMPOUND Days On Site 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# 7173-51-5 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixture ~mbient ~ Ambient OTHER - SPECIFY AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 2000.00 LBS 24000.00 LBS 12000.00 LBS HAZARDOUS COMPONENTS , owt. RSA CAS# t11iGHL[L 1-~. 7,7L" .7.71~1L" 1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F IH / / / UnR -14- 02/05/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0001 Facility Unit: SW STORAGE AREA ~ COMMON NAME / CHEMICAL NAME DEGREASER -AROMATIC HYDROCARBONS Days On Site. 365 Location within this Facility Unit Map: Grid: SW CRNR PLANT CAS# 71556 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid Mixture Ambient Ambient DRUM/BARREL-METALLIC AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 GAL 110.00 GAL 40.00 GAL - HAZARDOUS COMPONENTS %Wt. RS CAS# 40.00 Aromatic Naphtha No 8030306 tiAGAttL A~ a~aJ1~1i51v 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F / / / Mod -15- 02/05/2007 r F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0003 Facility Unit: MAINTENANCE SHOP ~ COMMON NAME / CHEMICAL NAME ACETYLENE Days On Site 365 Location within this Facility Unit Map: Grid: E SIDE MAINT BLDG CAS# 74-86-2 ~GasATE T TYPE PRESSURE TEMPERATURE CONTAINER TYPE I Pure Above Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 145.00 FT3 420.00 FT3 350.00 FT3 - HAZARDOUS COMPONENTS %Wt. RS CAS# 100.00 Acetylene Yes 74862 t11jGH.ttL H.»1";~J1~i1;1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Hi ~ Inventory Item 0002 COMMON NAME / CHEMICAL NAME OXYGEN Location within this Facility Unit E SIDE MAINT BLDG Facility Unit: MAINTENANCE SHOP ~ Days On Site 365 Map: Grid: CAS# 7782-44-7 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas TPure Above Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Co250100rFT3 Daily 843100m FT3 I Daily AOOr00e FT3 ~- t1HG1-~KLU U .7 1:U1~1Y V1V iS1V 7 5 ~Wt. RS CAS# 100.00 Oxygen, Compressed No 7782447 ri1~GHK1J 1~JJl;b.`~1~1~1V 1 7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Low -16- 02/05/2007 :,' T F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item 0001 Facility Unit: MAINTENANCE SHOP ~ COMMON NAME / CHEMICAL NAME CHEVRON HYDRAULIC OIL 68 Days On Site 365 Location within this Facility Unit Map: Grid: E SIDE MAINT SHOP CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid ~ure ~mbient ~ Ambient DRUM/BARREL-METALLI~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average - 55.00 GAL 110.00 GAL 55.00 GAL tiHL,HKLVU.~ l:Vl"lYV1Vt;1V 1.7 sWt. RS CAS# 100.00 Brake Fluid, Hydraulic (Diethylene Glycol Monob... No 0 t1HGf1KL I~aJ1;a~1~11=,1V1J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F DH / / / Low ~ Inventory Item 0004 COMMON NAME / CHEMICAL NAME MOTOR OIL Location within this Facility Unit E SIDE MAINT BLDG Facility Unit: MAINTENANCE SHOP ~ Days On Site 365 Map: Grid:, CAS# Liquid TMixture ~ Ambient~E ~ AmbientT~E DRUM/BNARRELEMETALLI~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 55.00 GAL 110.00. GAL 55.00 GAL nr~~s~.rcl~vua ~vl~irvivl;ly l a oWt. RS CAS# 100.00 Motor Oil, Petroleum Based No 8020835 ISE~GH.tCL 1~~51=,J.71~1~1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F DH / / / Min -17- 02/05/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 Fast Format ~ Notif./Evacuation/Medical Overall Site ~ Agency Notification 04/19/2006 CALL 911 FOR EMERGENCY ASSISTANCE. REPORT HAZARDOUS MATERIAL SPILLS WHICH EQUAL OR EXCEED 42 GAL, 500 LBS, OR 200 CF, OR WHICH THREATEN LIFE, HEALTH, OR THE ENVIRONMENT IMMEDIATELY. CALL: BAKERSFIELD FIRE DEPT HAZMAT DIV 326-3979 AND CAOES 800-638-1821. SPILLS EQUAL TO OR EXCEEDING 1 POUND OF ARSENIC PENTOXIDE MUST ALSO BE REPORTED TO THE FEDERAL GOVERNMENT. CALL: NATIONAL RESPONSE CENTER 800-424-8802. 9 9 Employee Notif./Evacuation 04/19/2006 ALL PERSONNEL, VISITORS, AND CONTRACTORS WILL EXIT THROUGH THE FRONT GATE. ALL PERSONS WILL BE ACCOUNTED FOR BY THEIR IMMEDIATE SUPERVISOR. Public Notif./Evacuation VERBAL, PUBLIC IN OFFICE AREA ONLY. 02/22/2000 Emergency Medical Plan 02/22/2000 NEAREST HOSPITAL. -18- 02/05/2007 .; F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall Site ~ ~ Release Prevention 04/19/2006 ~ CLOSED SYSTEM. FOR FILLING AND EMPTYING TREATMENT CYLINDERS. TANKS AND RETORT CYLINDERS HAVE HIGH LEVEL SHUT-OFF SWITCHES, VALVES OPERATE IN FAIL-SAFE POSITION IN THE EVENT OF LOSS OF AIR TO AIR-OPERATED VALVES. ALL PRESSURE VESSELS ARE EQUIPPED WITH PRESSURE-RELIEF VALVES. WRITTEN EMERGENCY CONTINGENCY PLAN OUTLINES PROCEDURES FOR RESPONSE TO EMERGENCY CONDITIONS. Release Containment 04/19/2006 A CONCRETE TANK DIRECTLY UNDER EACH WOOD TREATMENT CYLINDER IS CAPABLE OF HANDLING THE TOTAL CONTENTS OF ANY ONE TANK. EACH TANK IS IN A BLOCK WALL RETAINER OR CEMENT WALL RETAINER WHICH DRAINS TOWARDS THE CONCRETE PITS. PIPING FROM THE RAILCAR DESPENSING STATION IS PROTECTED WITH SECONDARY CONTAINMENT PIPE WHICH DRAINS INTO A CONTAINMENT BASIN. Clean Up 04/19/2006 ADVANCED CLEAN-UP TECHNOLOGIES 392-7765 HAS THE EQUIPMENT AND MEANS TO HANDLE ANY SPILL. V1.11C 1. 2CC .5"V UI_C.:C LiV l~lVdl.1 V11 -19- 02/05/2007 a i, F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ ~ Special Hazards Utility Shut-Offs 02/05/2007 A) GAS - NW CRNR PROP ~~'fi ~ B) ELECTRICAL - SW CRNR MAIN BLDG/SW CRNR BLDG C) WATER - N PERIMETER lOFT FROM CURB CTR OF LOT D) SPECIAL - NONE E) LOCK BOX - NO Fire Protec./Avail. Water 02/05/2007 PRIVATE FIRE PROTECTION - FIRE EXTINGUISHERS, SMOKE ALARMS IN FRONT OFFICE BLDG WHICH CAN BE PICKED UP BY SECURITY ALARM SYSTEM (SONITROL) AFTER HOURS. NEAREST FIRE HYDRANT - 3 FIRE HYDRANTS IN MIDDLE OF PLANT PROP. Building Occupancy Level 30 EMPLOYEES 03/14/2006 -20- 02/05/2007 1' T F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ Fast Format ~ ~ Training Overall Site ~ ~ Employee Training 11/27/2006 ~ MATERIAL SAFETY DATA SHEETS ON FILE. BRIEF SUMMARY OF TRAINING PROGRAM: ALL EMPLOYEES ATTEND SAFETY AND MATERIAL TRAINING MEETINGS EVERY MONTH. THEY ARE TRAINED IN HOW TO HANDLE THE CHEMICALS PWPB HAS IN ITS INVENTORY, AS WELL AS INSTRUCTION OF MSDSS FOR THOSE SAME CHEMICALS. WRITTEN QUESTIONNAIRE USED TO MEASURE COMPREHENSION OF SAFETY TRAINING. WRITTEN RESPIRATOR TRAINING MANUAL OUTLINES MAINTENANCE AND USE OF RESPIRATORS. rage ~ na.iu ivi rut,uiC u~~ nalu iui r ul.uiC Use -21- 02/05/2007 F PACIFIC WOOD PRESERVING/BAKERSFIE SitelD: 015-021-000567 ~ ~ Inventory Item Facility Unit: ~ COMMON NAME / CHEMICAL NAME A C ,r -r C ~ ~PP~L (~+Yl1YlONli~yl C~~jONP'~ SO ~~1~~~ Days On Site Location within this Facility Unit Map: Grid: ~~DS STATE TYPE PRESSURE TEMPERATURE ~~ ~ CONTAINER TYPE ~~,~a~ r ~~ T ~ ~ ~(~~-~~1I ~7V T ~ ~-/dt /~ ~ ~~ I Hid/~ G20 /N4 ?'/4i~1~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum ~ Daily Average Co, OOO A1..S lo,G10D GA-t-S ~a, 000 A-~S HAZARDOUS COMPONENTS $Wt . SEE ~I-`~A~f,.~~ ~j S /~~ RS CAS# tiliGa°lkC1J A.55~~~P'1~N~1".5 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP ~ / / UnR .~ 5'1'til'~ $Wt. = TYPL -~-- PRESSURE TEMPERATURE - ~c ,C 7`y/L~ I G4-~i (fit L°~~ lq-~ -Ot ~~ AMOUNTS AT THIS LOCATION t Container Daily Maximum v G~5 0~ ~~s -. HAZARDOUS COMPONENTS CONTAINER TYPE ~t/~ [a2~ua0 ` Daily Average RSI CAS# riAGAKU AS~~SSM~N'1'S TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP / / / UnR F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item Facility Unit: ~ q F PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ ~ Inventory Item Facility Unit: ~ COMMON NAME j CHEMICAL NAME `C~Q~C~N ~I~~ ~~'r9-/LIJ~Ps' ~0/1.IL $OC.vrzv~! Days On Site J(~~" ~ Location within this Facility Unit Map: Grid: i, CC la- T~r/V L- ~-A~rVI cAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum ~ Daily Average ~~ ~ (v ~~a-c.~s 3l~ O cil~ ~s~GS ~!P OSIv ~5, HAZARDOUS COMPONENTS ti.AGAlUJ H~aL'"a7.'71~1r;1.V"1-.5 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP / / / UnR ~ PACIFIC WOOD PRESERVING/BAKERSFIE SiteID: 015-021-000567 ~ ~ Inventory Item Facility Unit: ~ ~ ~ COMMON NAME / CHEMICAL NAME Days On Site Location within this Facility Unit STATE i ~ Largest Container $Wt. Map: TEMPERATURE CAS# CONTAINER TYPE AMOUNTS AT THIS LOCATION Daily Maximum ~ Dai1v Average .. HAZARDOUS COMPONENTS TYPE --~-- PRESSURE HAZARD SESS Grid: RS I CAS# As r~,~~ ~.~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP / / / UriR. ::~:::: P. `~~ y CHEMICAL SPECIALTIES, INC. IVIH I CKIHL ~Hf C I Y DATA SHEET Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards PART I What is the material and what do I need to know in an emergency? 1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): ACQ-C CHEMICAL NAME/CLASS: Copper Ammonium Carbonate Solution TECHNICAL BULLETINS: Not Applicable PRODUCT. USE: Various Industrial Applications CHEMICAL NAME/CLASS: Aqueous Copper Solution SYNONYMS: Not Applicable PRODUCT USE: Wood Treatment SUPPLIER/MANUFACTURER'S NAME: CHEMICAL SPECIALTIES, Inc. ADDRESS: 200 East Woodlawn Road Charlotte, NC 28217 EMERGENCY PHONE: CHEMTREC: 800-424-9300 BUSINESS PHONE: 704-522-0825 MSDS REVISION DATE: March 24, 2000 2. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS # % v/v EXPOSURE LIMITS IN AIR ACGIH-TLV OSHA-PEL TWA STEL TWA STEL IDLH OTHER mg/m' mg/m' mg/m' mg/m' mg/m' Copper Ammonium Carbonate Proprietary 5-10 1 (Inhafable NE 1 NE 100 NIOSH REL: Complex Particulates) TWA =1 The folkrwing exposure limits are DFG MAKs: for Copper, dusts and mists TWA = 1 PEAK = 2•MAK 20 min., average value (Measured as the inhalable fraction of the aerosol) Ammonium Hydroxide 1336-21-6 8-15 17 24 NE 35 300 NIOSH RELs: (This substance forms a complex 27 ppm TWA = 18 with copper, but may be released (Vacated STEL = 27 under certain circumstances) 1989 DFG MAK The following exposure limits are PEL) TWA = 14 PEAK = 2•MAK 5 min., for ammonia. momentary value MAK Pregnancy Risk Grou Classification: C Water and other components. 7732-18-5 Balance None of the other components contribute significant additional hazards at the Each of the other components are concentrations present in this product. All pertinent hazard information has been present in less than 1 percent provided in this document, per the requirements of the Federal Occupational Safety and concentration (0.1 % concentration Health Administration Standard (29 CFR 1910.1200), U.S. State equivalent Standards for potential carcinogens, and Canadian Workplace Hazardous Materials Identification System Standards (CPR reproductive toxins, respiratory 4). tract sensitizers, and mutagens). NE =Not Established C =Ceiling Limit See Section 16 for Definitions of Terms Used. NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI 2400.1-1998 format. MSDS # C03M ACQ-C (PROPRIETARIn MSDS PAGE 1 OF 8 4. FIRST-AID MEASURES (Continued) INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Have victim rinse mouth with water, if conscious. Never induce vomiting or give diluents (milk or water) to someone who is unconscious. having convulsions. or unable to swallow. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing dermatitis, other skin -disorders, and respiratory diseases may be aggravated by overexposure to this product. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. Be observant for signs of pulmonary edema in the event of severe inhalation overexposures. 5. FIRE-FIGHTING MEASURES FLASH POINT: Not flammable. AUTOIGNITION TEMPERATURE: Not flammable. FLAMMABLE LIMITS (in air by volume, %): Lower (LEL): Not applicable. Ugger (UEU: Not applicable. NFPA RATING FIRE EXTINGUISHING MATERIALS: Water Sgray: YES Carbon Dioxide: YES N~~TM R~~r~r Foam: YES Drv Chemical: YES Halon: YES Other: Any "ABC" Class. UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is corrosive, and presents a contact hazard to fire-fighters. When involved in a fire, this material oT„~ may decompose and produce copper compounds, ammonia, and nitrogen See Section 16 for oxides. Explosion Sensitivity to Mechanical Impact: Not sensitive. Definition of Ratings Explosion Sensitivity to Static Discharge: Not sensitive. SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural fire fighters must wear Self-Contained Breathing Apparatus and full protective equipment. Chemical resistant clothing may be necessary. Move containers from fire area if they have not been exposed to heat and if it can be done without risk to personnel. If this product is involved in a fire, fire run-off water should be contained to prevent possible environmental damage. Rinse contaminated equipment thoroughly before returning to service. 6. ACCIDENTAL RELEASE MEASURES 'SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to 6y trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a large spill, clear the affected area, and protect people. For small releases, clean-up spilled liquid wearing gloves, goggles, faceshield, and suitable body protection. In the event of anon-incidental release, minimum Personal Protective Equipment should be Level B: triple-gloves (rubber gloves and nitrite gloves, over latex gloves), chemically resistant suit and boots, hard-hat, and Self Contained Breathing Apparatus). Neutralize residue with citric acid or other neutralizing agent for basic liquids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residue in a suitable container. Dispose of in accordance with applicable U.S. Federal, State, or local procedures, or appropriate Canadian standards (see Section 13, Disposal Considerations). PART III How can I prevent hazardous situations from occurring? 7. HANDLING and STORAGE WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash hands after handling this product. Do not eat, drink, smoke or apply cosmetics while handling this product. All work practices should minimize the generation of splashes and aerosols. Remove contaminated clothing immediately. STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. Avoid breathing vapors or mists generated by this product. Use in awell-ventilated location. Open containers slowly, on astable surtace. Containers of this product must be properly labeled. Empty containers may contain residual liquid or vapors therefore, empty containers should be handled with care. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Material should be stored in secondary containers, or in a diked area, as appropriate. Keep container tightly closed when not in use. Floors should be sealed to prevent absorption of this material. If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage; to ~t ;nsure containers are properly labeled and not damaged. If this product is transferred into another container, only use portable containers and dispensing equipment (faucet, pump, drip can) approved for corrosive, basic liquids. MSDS # C03M ACQ-C (PROPRIETARY) MSDS PAGE30F8 3. HAZARD IDENTIFICATION EMERGENCY OVERVIEW: This product is a dark blue, corrosive liquid with an ammonia odor. The primary health hazard associated with this product is moderate to severe irritation of skin, eyes, or other contaminated tissues. Burns may occur if contact is prolonged or concentrated. This product is not flammable or reactive. Emergency responders must wear the personal protective equipment suitable for the situation to which they are responding. ~t 5rnnr t vnn5 ur ~vtrctxr~5urct ttY Kau l t yr txr~~uKt: t ne primary routes of overexposure for the solution are via inhalation and HAZARDOUS MATERIAI..IDEMIFlCATION contact with skin and eyes. The following paragraphs describe the SYSTEM symptoms of overexposure, via route of exposure, to this material. INHALATION: This solution is corrosive; if vapors, mists, or sprays of H~L~ ~ 3 this product are inhaled moderate to severe irritation or bums to the nose, throat, and lungs may occur, depending on duration and concentration of exposure. Additional inhalation symptoms may include coughing and difficulty breathing. Severe inhalation over-exposures 0 can lead to chemical pneumonitis, pulmonary edema, and death. F~~B~ ~~ (r~rn Repeated low-level inhalation of mists or sprays may result in bronchitis or other adverse respiratory conditions. CONTACT WITH SKIN or EYES: Depending on the duration of overexposure, contact with the eyes will cause irritation, pain, R~C~~~ c~u-owl ~ reddening, and may result in blindness. Depending on the duration of skin contact, skin overexposures will cause reddening, discomfort, irritation, ulceration, and chemical bums. Repeated skin overexposures can result in dermatitis (inflammation and reddening of the skin). PROTECTIVE EQUIPMENT H SKIN ABSORPTION: Skin absorption is not a significant route of overexposure for the components of this product. ~s ~w,~v wN,os aoov INGESTION: If this product is swallowed, irritation and bums of the mouth, throat, esophagus, and other tissues of the digestive system will occur immediately upon contact. Symptoms of such overexposure can ~ ~~fONB `,' include drowsiness, confusion, difficulty swallowing, burning sensation in the esophagus and stomach, intense thirst, nausea, abdominal pain, For routine industrial applications vomiting, diarrhea, stomach pertoration, bloody stools or urine, convulsions, and collapse. Ingestion of large volumes of this product See Section 16 for Definition of Ratings may be fatal. INJECTION: Accidental injection of this product, via laceration or puncture by a contaminated object may cause pain and irritation in addition to the wound. HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lav Terms. In the event of overexposure, the following symptoms may be observed: ACUTE: This product is corrosive. Depending on the duration of contact, overexposures can moderately to severely irritate or bum the eyes, skin, mucous membranes, and any other exposed tissue. If inhaled, irritation of the respiratory system may occur, with coughing, and difficulty breathing. Skin contact may cause blisters and scars. Eye contact may cause blindness. Severe inhalation and ingestion overexposures may be fatal. CHRONIC: Prolonged or repeated low-level skin contact can lead to dermatitis. Repeated low-level inhalation of mists or sprays may result in bronchitis or other adverse respiratory conditions. See Section 11 (Toxicology Information) for additional data. TARGET ORGANS: Acute: Skin, eyes, respiratory system Chronic: Skin, respiratory system. P/4RT ~ ~ What should 1 do if a hazardous situation occurs? 4. FIRST-AID MEASURES Chemically contaminated personnel must be taken for medical attention. Rescuers should be taken for medical attention if necessary. Take copy of label and MSDS to physician or health-care professional with victim. SKIN EXPOSURE: If this product contaminates the skin, begin decontamination with running water for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Victim must seek immediate medical attention. EYE EXPOSURE: If liquid or vapors of this product enter the eyes, open victim's eyes while under gently running water. `Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek -immediate medical attention. INHALATION: If vapors, mists, or sprays of this product are inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers. MSDS # C03M ACQ-C (PROPRIETARY) MSDS PAGE20F8 7. HANDLING and STORAGE (Continued) PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or local procedures or applicable Canadian standards. 8. EXPOSURE CONTROLS -PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in Section 2 (Composition and Information on Ingredients); if applicable. Exhaust directly to the outside. Use local exhaust ventilation, and process enclosure if necessary, to control mist formation. Supply sufficient replacement air to make up for air removed by system. Ensure eyewash/safety shower stations are available near areas where this product is used. RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below exposure limits listed in Section 2 (Composition and Information on Ingredients). If respiratory protection is needed (i.e. air-purifying respirator with an acid-gas cartridge), use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the Canadian CSA Standard 294.4-93 and applicable standards of Canadian Provinces. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998). The following are NIOSH recommendations for Copper (Dusts and Mists), and are provided for further information: CONCENTRATION RESPIRATORY EQUIPMENT FOR COPPER DUSTS AND MISTS Up to 5 mg/m : Dust and mist respirator. Up to 10 mg/m3: Dust and mist respirator except single-use and quarter-mask respirator (if not present as a fume); or SAR. Up to 25 mg/m3: Powered air-purifying respirator with dust and mist filter(s); or SAR in a continuous-flow mode. Up to 50 mg/m3: Full-facepiece respirator with high-efficiency particulate filter(s); or full-facepiece SCBA; or full- facepiece SAR; or powered air-purifying respirator with tight-fitting facepiece and high- efficiency particulate filter. Up to 100 mg/m3: Positive pressure, full-facepiece SAR. Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Positive pressure, full-facepiece SCBA; or positive pressure, full-facepiece SAR with auxiliary positive pressure SCBA. Escape: Full-facepiece respirator with high-efficiency particulate filter(s); or escape-type SCBA. Note: The IDLH for copper dusts and mists is 100 mg/m3, as Cu. The following are NIOSH recommendations for Ammonia, and are provided for further information: CONCENTRATION RESPIRATORY EQUIPMENT FOR AMMONIA Up to 250 ppm: Any chemical cartridge respirator with cartridge(s) providing protection against the compound of concern. Substance reported to cause eye irritation or damage; requires eye protection, or any supplied-air respirator. Substance reported to cause eye irritation or damage; requires eye protection. Up to 300 ppm: Any supplied-air respirator operated in a continuous-flow mode. Substance reported to cause eye irritation or damage; requires eye protection, or any powered, air-purifying respirator with cartridge(s) providing protection against the compound of concern. Substance reported to cause eye irritation or damage; requires eye protection, or any chemical cartridge respirator with a full facepiece and cartridge(s) providing protection against the compound of concern, or any air-purifying, full-facepiece respirator (gas mask) with achin-style, front- or back-mounted canister providing protection against the compound of concern or any self-contained breathing apparatus with a full facepiece or any supplied-air respirator with a full facepiece. Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any self-contained breathing apparatus that has a full facepiece and is operated in apressure-demand or other positive-pressure mode, or any supplied-air respirator that has a full facepiece and is operated in apressure-demand or other positive-pressure mode in combination with an auxitiarysetf-contained breathing apparatus operated in pressure-demand or other positive-pressure mode. Escape: Any air-purifying, full-facepiece respirator (gas mask) with achin-style, front- or back-mounted canister providing protection against the compound of concern, or any appropriate escape-type, self-contained breathing apparatus Note: The IDLH for ammonia is 300 ppm. AYE PROTECTION: Splash goggles or safety glasses. Face shields recommended when using quantities of this product in excess of 1 gallon. MSDS # C03M ACQ-C (PROPRIETARY) MSDS PAGE 4 OF 8 8. EXPOSURE CONTROLS -PERSONAL PROTECTION (Continued) HAND PROTECTION: Wear Neoprene or Rubber gloves for routine industrial use. Use triple gloves for spill response, as stated ill Section 6 (Accidental Release Measures) of this MSDS. BODY PROTECTION: Use body protection appropriate for task. An apron, or other impermeable body protection is `suggested. Full-body chemical protective clothing is recommended for emergency response procedures. 9. PHYSICAL and CHEMICAL PROPERTIES VAPOR DENSITY: Not established EVAPORATION RATE (n-BuAc = 1): Similar to water. SPECIFIC GRAVITY CcD 15°C (59°F): 1.20 FREEZING POINT or RANGE: -5°C (23°F) SOLUBILITY IN WATER: Completely BOILING POINT: Not established. VAPOR PRESSURE: Not established. p~ 15°C (59°F): 9.9 ODOR THRESHOLD: Not applicable. LOG WATER/OIL DISTRIBUTION COEFFICIENT: Not available. APPEARANCE AND COLOR: This product is a dark blue, aqueous liquid with an ammonia odor. HOW TO DETECT THIS SUBSTANCE (wamina properties): The appearance and odor are distinguishing characteristics of this product. 10. STABILITY and REACTIVITY STABILITY: Stable. DECOMPOSITION PRODUCTS: Copper compounds, ammonia, and nitrogen oxides. MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong acids. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Extreme heat and contact with incompatible chemicals. PART IV Is there any other useful information about this material? 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: Toxicology data for the components of this product specifically listed in Section 2 (Composition and Information on Ingredients) and greater than 1 percent in concentration are provided below. COPPER AMMONIUM CARBONATE COMPLEX: AMMONIUM HYDROXIDE (continued): No to~ticology data are currently available for this component of the product LD Lo (oral, human) = 43 mg/kg AMMONIUM HYDROXIDE- LCLo (inhalation, human) = 5000 ppm Eye Irritancy (rabbit) = 1 mg/ 30 seconds! rinse; severe TCLo (inhalation, human) = 700 ppm; eye effects Eye Irritancy (rabbit) = 750 fig; severe TCLo (inhalation, human) =408 ppm; irritant effects Mutation in Microorganisms (Salmonella typhimurium) =10 ®Uplate LDS (oral, rat) =350 mglkg Mutation in Microorganisms (Escharichia con =10 l~Udisc LDLo (oral, cat) = 750 mg/kg LDLo (intravenous, rabbit) = 10 mg/kg SUSPECTED CANCER AGENT: The components of this product are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and CAUOSHA and therefore are not considered to be, nor suspected to be, cancer causing agents by these agencies. Copper compounds are listed as follows: EPA-D (Not Classifiable as a Human Carcinogen). IRRITANCY OF PRODUCT: This product is moderately to severely irritating to contaminated tissue. SENSITIZATION OF PRODUCT: This product contains no components known to be skin or respiratory sensitizers. REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components on the human reproductive system. MutaQenicity: This product is not reported to produce mutagenic effects in humans. Embrvotoxicity: This product is not reported to produce embryotoxic effects in humans. Teratogenicity: This product is not reported to cause teratogenic effects in humans. Rearoductive Toxicity: This product is not reported to cause reproductive toxicity effects in humans. A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate through generational lines. An embrvotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive process. ACGIH BIOLOGICAL EXPOSURE INDICES: Currently, there are no ACGIH Biological Exposure Indices (BEIs) ` determined for the components of this product. MSDS # C03M ACQ-C (PROPRIETARY) MSDS PAGE 5 OF 8 12. ECOLOGICAL INFORMATION ALL VVO,RK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: The components of this product are relatively stable under ambient, environmental conditions. Additional environmental data for compounds which can be released from this product are available as follows: AMMONIA: Water Solubility: 47% in water at OEC; 34% in water at 20EC; 28% in water at 31EC. BIOCONCENTRATION: Plants have a high affinity for gaseous ammonia when leaf stomata are open in daylight. BIODEGRADATION: Ammonia is rapidly converted to nitrate by nitrification. COPPER: Solubility: Insoluble. There is no evidence of any biotransformation for copper compounds. Copper is accumulated by all plants and animals. BCF Algae = 12; plants =1,000; invertebrate = 1,000, fish = 667 and fish = 200 (Soluble copper salts). EFFECT OF MATERIAL ON PLANTS or` ANIMALS: Copper Ammonium Carbonate (a component of this product) is a fungicide and bactericide; subsequently, plants contaminated with this product may be adversely affected or destroyed. Animals contaminated with this solution may be severely injured or killed. EFFECT OF CHEMICAL ON AQUATIC LIFE: A release of this product in a river or other body of water (especially in large volumes) may kill fish and other aquatic life. Additional aquatic toxicity data are available as follows: AMMONIUM HYDROXIDE: LCso (Lepomis maciochirus, bluegill) = 0.024-0.093 mg/U 48 hours LCso (Icta/urus puncfatus, channel catfish) = 0.974 mg/U 1 week/ pH 7.7/ 21.1 EC LCso (Ictalu-us punctatus, channel catfish) = 1.27 mg/U 1 week/ pH 7.8/ 21.7EC LCso (Ictalurus punctatus, channel catfish) = 1.41 mg/U 1 week/ pH 7.8/ 22.8EC LCso (Icta/urus punctatus, channel catfish) = 1.97 mg/U 1 week/ pH 8.0/ 22.8EC TLm (fathead minnow) = 8.2 mg/U 96 hours/ hard water LCso (Atlantic salmon smelt) = 5-8 mglU 24 hours LCso (perch) = 0.29 mg/U 7 days/ non-ionized NH3 TLm (bluegill) = 3.4 mg/U 96 hours/ hard water/ 20EC LCso (Daphnia magna} = 0.66 mg/U 48 hours/ 22EC TLm (diatom) = 420 mg/U 120 hours/ hard water and soft water/ 22EC; 50% growth reduction LCso (Sa/mo gairdnen) = 8 mg/mL NH3/ 24 hours TLm (goldfish) = 2-2.5 mg/U 2496 hours LCso (Coho salmon) = 0.45 mg/U 96 hours LCso (guppy, fry) = 74 mg/U 72 hours LCso (rainbow trout, alevin 0-50 days old) >3.58 mg/U 24 hours LCso (rainbow trout, fry 85 days old) = 0.068 mglU 24 hours AMMONIUM HYDROXIDE (continued): LCso (rainbow trout, adult) = 0.097 mg/U 24 hours LCso (walking catfish) = 0.28 mg/U 48 hours LCso (AUantic salmon smelt) = 0.02-0.08 mg/L NH3/ 24 hours/ freshwater LCso (Oncothynchus tshawytscha, Chinook salmon) = 0.36 mg/L NH3/ 24 hours/ freshwater LCso (Sa/mo clarki, cutthroat trout fry) = 0.5-0.8 mg/U 96 hours; 0.56 mglU 36 days LCso (rainbow trout, fertilized egg) >3.58 mg/U 24 hours LCso (Oncorhynchus tshawyfscha, Chinook salmon) = 2.2 mg of NH3/U 24 hours/ 9.6% salinity LCso (nauplius) = 3.58 mg/L NH3/ 24 hours/ total NH3; 0.29 mg/L NH3-N/ non-ionized LCso (mysis) =46.01 mg/L NH3-N/ 24 hours/ total NH3; 3.17 mg/L NH3-N/ non-ionized LCso (green sunfish) = 0.50 mg/L NH3/ pH 6.6; 1.06 mg/L NH3/ pH 7.2; 1.34 mg/L NH3/ pH 7.7; 1.73 mg/L NH3/ pH 8.7 LCso (Ru61us iutdus, roach) = 0.42 mg/U 24 hours/ non-ionized NH3 COPPER: LCso(fathead minnows) = 0.14 ppm in hard water LCso(bluegill) = 0.02 ppm in soft water LCs~(brook trout) = 0.09 ppm in soft water 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations, or the applicable standards of Canada and its Provinces. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. U.S. EPA WASTE NUMBER: Wastes of this product should be tested for D002 (CharacteristiGCorrosivity). 14. TRANSPORTATION INFORMATION THIS MATERIAL IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: Corrosive liquids, n.o.s. (Copper Ammonium Carbonate, Ammonium Hydroxide) HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive) UN IDENTIFICATION NUMBER: UN 1760 PACKING GROUP: II DOT LABEL(S) REQUIRED: Corrosive NORTH AMERICAN EMERGENCY RESPONSE GUIDE NUMBER (2000): 154 MARINE POLLUTANT: The components of this product are not designated by the DOT to be Marine Pollutants (49 CFR 172.101, Appendix B). TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is considered as dangerous goods, per regulations of Transport Canada. Use information on above U.S. DOT shipping for shipments into Canada. << MSDS # C03M ACQ-C MSDS PAGE60F8 ~~ 15. REGULATORY INFORMATION ADDITIONAL UNITED STATES REGULATIONS: U.S. SARA REPORTING REQUIREMENTS: This product is subject to the reporting requirements of Sections 302, 304 and 313 of Title 111 of the Superfund Amendments and Reauthorization Act., as follows: CHEMICAL NAME SARA 302 SARA 304 SARA 313 (40 CFR 355, Appendix (40 CFR Table 302.4) (40 CFR 372.65) A) '' AMMONIUM HYDROXIDE NO YES NO COPPER AMMONIUM NO YES (as a Copper YES (as a Copper CARBONATE COMPLEX Compound) Compound) U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any component of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs. (4,540 kg) therefore applies, per 40 CFR 370.20. U.S. CERCLA REPORTABLE QUANTITY (RQ): Ammonium Hydroxide = 1000 Ib (454 kg). Copper Ammonium Carbonate Complex =Not established for Copper Compounds as a generic class, although the class is a CERCLA Hazardous Substance. U.S. TSCA INVENTORY STATUS: The components of this material are listed on the TSCA Inventory. OTHER U.S. FEDERAL REGULATIONS: Not applicable. U.S. STATE REGULATORY INFORMATION: The components of this product are covered under the following specific State regulations: Alaska -Designated Toxic and Hazardous Minnesota -List of Hazardous Substances: Pennsylvania -Hazardous Substance List: Substances: Copper (fume, dust and mist). None. Ammonium Hydroxide, Copper. Califomia -Permissible Exposure Limits for Missouri - Employer Infomtation/Toxic Rhode Island -Hazardous Substance List Chemical Contaminants: Copper. Substance List: Copper. Copper (fume, dust, mist). Florida -Substance List: None. New Jersey -Right to Know Hazardous Texas -Hazardous Substance List: Copper Illinois -Toxic Substance List: Ammonium Substance List: Ammonium Hydroxide, (fume). Hydroxide, Copper Compounds. Copper. West Virginia -Hazardous Substance List: Kansas -Section 302/313 List: None. North Dakota -List of Hazardous Chemicals, Copper (fume). Massachusetts -Substance List: Copper. Reportable Quantities: Ammonium Wisconsin - Toxic and Hazardous Michigan -Critical Materials Register: None. Hydroxide, Copper. Substances: Copper (fume). CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT !PROPOSITION 65): No component of this product is on the Califomia Proposition 65 lists. ANSI LABELING (per 2129.1) (Precautionary Statements): DANGER! CORROSIVE. CAUSES BURNS AND IRRITATION TO SKIN, EYES RESPIRATORY SYSTEM. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing vapors or mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, face-shield, suitable body protection, and NIOSH approved respirator as necessary. FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If inhaled, remove to fresh air. If ingested, do not induce vomiting. Get medical attention. IN CASE OF FIRE: Use water fog, dry chemical, CO2, or °alcohol° foam. IN CASE OF SPILL: Absorb spill with inert material or neutralizing agent for acids. Place residue in suitable container. Consult Material Safety Data Sheet for additional information. ADDITIONAL CANADIAN REGULATIONS: CANADIAN DSL INVENTORY: The components of this material are listed on the DSL Inventory. OTHER CANADIAN REGULATIONS: Not applicable. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this product are not on the CEPA Priorities Substances Lists. CANADIAN WHMIS SYMBOLS: Class D26: Other Toxic Effects Class E: Corrosive Material o ~~ MSDS # C03M ACQ-C MSDS PAGE 7 OF 8 . ' _ 16.OTHER INFORMATION PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc. 9163 Chesapeake Drive, San Diego, CA 92123-1002 (858) 565 - 0302 - DATE OF PRINTING: February 15, 2001 The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Chemical Specialties Inc, assumes no responsibility for injury to the vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Chemical Specialties Inc. assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.. DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following: CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent. It is used for computer-related searching. EXPOSURE LIMITS IN AIR: ACGIH -American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits. TLV - Threshold Limit Value - an airborne concentration of a substance which represents conditions under which tt is generally believed that nearly all workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered. OSHA - U.S. Occupational Safety and Health Administration. PEL - Permissible Exposure Limit -This exposure value means exactly the same as a TLV, except that tt is enforceable by OSHA. The OSHA Penni§sible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 353.'38-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, "Vacated 1989 PEL," is placed next to the PEL which was vacated by Court Order. IDLH - Immediatety Dangerous to Life and Health -This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). NIOSH issues exposure guidelines called Recommended Exposure Levels (RELs). AIHA-WEEL is the American Industrial Hygiene Association Workplace Environmental Exposure Level Guides. When no exposure guidelines are established, an entry of NE is made for reference. HAZARD RATINGS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3 (severe acute exposure hazard; onetime overexposure can result in permanent injury and may be fatal); 4 (extreme acute exposure hazard; onetime overexposure can be fatal). Flammability Hazard: 0 (minimal hazard); 1 (materials that require substantial pre-heating before burning); 2 (combustible liquid or solids; liquids with a flash point of 38-93°C [100-200°F]); 3 (Class IB and IC flammable liquids with flash points below 38°C (100°F]); 4 (Class IA flammable liquids with flash points below 23°C [73°F) and boiling points below 38°C [100°F]. Reactivity Hazard: 0 (normalty stable); 1 (material that can become unstable at elevated temperatures or which can react slightly with water); 2 (materials that are unstable but do not detonate or which can react violentty with water); 3 (materials that can detonate when initiated or which can react explosively with water); 4 (materials that can detonate at normal temperatures or pressures). NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material that on exposure under fire condttions would offer no hazard beyond that of ordinary combustible materials); 1 (materials that ort exposure under fire conditions could cause irritation or minor residual njury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure causes death or major residual injury). NATIONAL FIRE PROTECTION ASSOCIATION (Continued): Flammability Hazard and Reactivity Hazard: Refer to definitions for "Hazardous Materials Identification System". FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ignitable mixture with air. AutoignRion Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL -the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL -the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. TOXICOLOGICAL INFORMATION: Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the results of studies with similar compounds are presented. Definttions of some terms used in this section are: LDw -Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LCso -Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m9 concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. Cancer Information: The sources are: IARC -the International Agency for Research on Cancer; NTP -the National Toxicology Program, RTECS -the Registry of Toxic Effects of Chemical Substances, OSHA and CAUOSHA. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 26, etc.) are also used. Other Information: BEI -ACGIH Biological Exposure Indices, represent the levels of determinants which are most tikety to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. Ecological Information: EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a substance will concentrate in lifeforms which consume contaminated plant or animal matter. Coefficient of OiUWater Distribution is represented by log K°,,,or log K°° and is used to assess a substance's behavior in the environment. REGULATORY INFORMATION: This section explains the impact of various laws and regulations on the material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is the U.S. Department of Transportation. SARA is the Supertund Amendments and Reauthorization Act. TSCA is the U.S. Toxic Substance Control Act. CERCLA (or Supertund) refers to the Comprehensive Environmental Response, Compensation, and Liability Act. Labeling is per the American National Standards Institute (ANSI Z129.1). CANADA: CEPA is the Canadian Environmental Protection Act. WHMIS is the Canadian Workplace Hazardous Materials Information System. TC is Transport Canada. DSL/NDSL are the Canadian Domestic/Non-Domestic Substances Lists. MSDS # C03M ACQ-C MSDS PAGE80F8 {~~~~fT~l IVIH I C KI/~-L CHI C 1 Y _.~.~r:.;:.:..:.:. DATA SHEET Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards ~q CHEMICAL SPECIALTIES, INC. PART I What is the material and what do I need to know in an emergency? 1. PRODUCT IDENTIFICATION TRADE NAME (AS LABELED): CHEMICAL NAME/CLASS: SYNONYMS: PRODUCT USE: SUPPLIER/MANUFACTURER'S NAME: ADDRESS: EMERGENCY PHONE: BUSINESS PHONE: MSDS REVISION DATE: ACQ-C2 Aqueous Copper Solution Not Applicable Wood Treatment CHEMICAL SPECIALTIES, Inc. 200 East Woodlawn Road, Suite 250 Charlotte, NC 28217 CHEMTREC: 800-424-9300 704-522-0825 March 27, 2000 2. COMPOSITION and INFORMATION ON INGREDIENTS CHEMICAL NAME CAS # % m/m EXPOSURE LIMITS tN AIR ACGIH- TLV OSHA-PEL OTHER TWA STEL TWA STEL IDLH m m3 m m' m m' m m3 m m3 m m' Amine Compound Proprietary 31 7.5 15 6 15 30 ppm NIOSH RELs: 8 (Vacated TWA = 8 (Vacated 1989 STEL = 15 1989 PEL) DFG MAKs: PEL) TWA = 5.1 PEAK = 2•MAK 5 min., momentary value Danger of Cutaneous Absorption MAK Pregnancy Risk Group Classification: C Copper Compound Proprietary < 9 1 (Inhalable NE 1 NE 100 NIOSH REL: The following exposure Particulates) TWA =1 limits are for "Copper, DFG MAKs: Dusts and Mists". TWA =1 PEAK = 2•MAK 20 min., average value (Measured as the inhalable fraction of the aerosol) NE =Not Established. See Section 16 for Definitions of Terms Used. NOTE (1 ): ALL WHMIS required information is included in appropriate sections based on the ANSI 2400.1-1998 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. MSDS # C04M ACQ-C2 MSDS (PROPRIETARI() PAGE 1 OF 10 2. COMPOSITION and INFORMATION ON INGREDIENTS (Continued) CHEMICAL NAME CAS # % m/m EXPOSURE LIM ITS IN AIR ACGI H-TLV OSHA-PEL TWA STEL TWA STEL IDLH OTHER m m3 m' m m' m m' m m3 Inorganic Carbon Proprietary 8 9000 54,000 9000 54,000 40,000 NIOSH RELs: Compound (1989 ppm TWA =9000 Vacated STEL =54,000 PEL) DFG MAK TWA = 9100 PEAK = 2•MAK 60 min., momentary value Danger of Cutaneous Absorption MAK Pregnancy Risk Group Classification: C Water and other components. Balance None of the other components contribute significant additional hazards at the concentrations present in Each of the other components are this product. All pertinent hazard information has been provided in this document, per the requirements present in less than 1 percent of the Federal Occupational Safety and HeaRh Administration Standard (29 CFR 1910.1200), U.S. concentration (0.1 % concentration State equivalent Standards and Canadian Workplace Hazardous Materials Identification System for potential carcinogens, Standards (CPR 4). reproductive toxins, respiratory tract sensitizers, and mutagens). NE =Not Established. See Section 16 for Definitions of Terms Used. NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI 2400.1-1998 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR. 3. HAZARD IDENTIFICATION t ( EMERGENCY OVERVIEW: This is a blue, corrosive, solution with a faint, ammonia-like odor. The primary health hazard associated with overexposure to this product is moderate to severe irritation of skin, eyes, or other contaminated tissues. Bums may occur if contact prolonged or concentrated. This solution would require substantial preheating before ignition would occur. The products of thermal decomposition include irritating vapors and toxic gases (including carbon monoxide, carbon dioxide, copper compounds, and nitrogen oxides). This product is not reactive under typical emergency circumstances. Emergency responders must wear personal protective equipment appropriate for the situation to which they are responding. SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The main routes of overexposure for this product would be via inhalation of mists or sprays of this product, as well as contact with skin or eyes. The symptoms of such overexposure are described in the following paragraphs. INHALATION: This solution is corrosive; if vapors, mists, or sprays of this product are inhaled moderate to severe irritation or bums to the nose, throat, and lungs may occur, depending on duration and concentration of exposure. Symptoms of such overexposure can include wheezing, shortness of breath, and breathing difficulties. Due to the presence of the Inorganic Carbon Compound, which is a powerful cerebral vasodilator, inhalation of high concentrations of vapors of this product may cause an increase in respiration and heart rate. Symptoms may include labored breathing, increased blood pressure, a feeling of slight choking, visual distufiances intoxication, mental disturbances and ringing in the ears. The Inorganic Carbon Compound component will initially stimulate respiration rate. Continued inhalation exposure will result in a depressed respiration rate; unconsciousness can occur if the level of Inorganic Carbon Compound reaches between 5 and 8%. Chronic inhalation overexposures to vapors of this product may result in liver and kidney disorders and adverse effects on the lungs. Severe inhalation over- exposures can lead to chemical pneumonitis, pulmonary edema, and death. Repeated low-level inhalation of mists or sprays may result in bronchitis or other adverse respiratory conditions. :ONTACT WITH SKIN or EYES: Depending on the duration of overexposure, contact with the eyes will cause irritation, pain, reddening, and may result in blindness. (continued on following page) HAZARDOl1S MATERIAL IDENTIFlCATION SYSTEM HEALTH ~ 3 FLAMIUTABIUIY ~ o REACTIVITY ~-~- o PROTECTIVE EQUIPMENT H EYES RESPIRATORY HANGS BODY s~sECnoNS For routine industrial applications See Section 16 for Definition of Ratings MSDS # C04M ACQ-C2 MSDS (PROPRIETARY) PAGE 2 OF 10 3. HAZARD IDENTIFICATION (Continued) CONTACT' WITH SKIN or EYES (continued): Low vapor concentration from the Amine Compound component can cause a visual disturbance, known as "blue haze" or "halo vision".Vision may become foggy or blurred, with halos around lights. This condition normally clears within several days of exposure, unless eye exposure is intense, in which case the condition may take days to clear and may be accompanied by an abnormal sensitivity to light known as photophobia. Depending on the duration of skin contact, skin overexposures will cause reddening, discomfort, irritation, ulceration, and chemical bums. Depending on the duration of overexposure, chapping, flaking, and chemical bums may result. Repeated overexposure may lead to dermatitis (inflamed, dry skin). An allergic skin response (i.e. the development of rashes and welts) may occur in sensitive individuals. SKIN ABSORPTION: Skin absorption is a potential route of overexposure to the Amine Compound component of this product. Symptoms of such overexposure include those described under "Contact with Skin or Eyes". INGESTION: Ingestion is not anticipated to be a significant route of overexposure for this solution. If this product is swallowed, irritation and bums of the mouth, throat, esophagus, and other tissues of the digestive system will occur immediately upon contact. Symptoms of such overexposure may include gastric distress, nausea, vomiting, and diarrhea. Severe ingestion overexposures may be fatal. INJECTION: Injection of this product (via punctures with contaminated, sharp objects or pre-existing breaks in the skin) can produce redness and local swelling at the injection site. HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Tenms. Symptoms of overexposure to this solution may include the following: ACUTE: This product is corrosive. Depending on the duration of contact, overexposures can moderately to severely irritate or bum the eyes, skin, mucous membranes, and any other exposed tissue. If inhaled, irritation of the respiratory system may occur, with coughing, and difficulty breathing. Skin contact may cause blisters and scars. Eye contact may cause blindness. Eye contact can cause a temporary visual disturbance known as "halo vision" which causes foggy or distorted images and can cause sensitivity to light. Severe inhalation and ingestion overexposures may be fatal. CHRONIC: Prolonged or repeated skin overexposure may lead to dermatitis (inflamed, dry skin) and chapping: Repeated low-level inhalation of mists or sprays may result in bronchitis or other adverse respiratory conditions. An allergic skin response (i.e. the development of rashes and welts) may occur in sensitive individuals. Chronic inhalation overexposures may result in liver and kidney disorders and adverse effects on the lungs. See Section 11 (Toxicology Information) for additional information of this product. TARGET ORGANS: ACUTE: Skin, eyes, respiratory system. CHRONIC: Skin, respiratory system, liver, kidneys. ~ PART I I What should / do if a hazardous situation occurs? 4. FIRST-AID MEASURES Chemically contaminated personnel must be taken for medical attention. Rescuers should be taken for medical attention if necessary. Take copy of label and MSDS to physician or health-care professional with victim. SKIN EXPOSURE: If the product contaminates the skin, begin decontamination with running water. Minimum flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes. Contaminated personnel must seek medical attention. EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Contaminated personnel should seek medical attention. INHALATION: If aerosols, mists, or sprays of this product are inhaled, remove victim. to fresh air. If necessary, use artificial respiration to support vital functions. Remove or cover gross contamination to avoid exposure to rescuers. INGESTION: If this product is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Have victim rinse mouth with water, if conscious. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or unable to swallow. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin disorders may be aggravated by exposure to this product. Overexposures to aerosols, mists, or sprays of this product may aggravate respiratory conditions, liver disorders, and kidney problems. Additionally, any disorder involving the "Target Organs" may be aggravated by overexposures to this substance. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. In the event of ingestion exposures, probable mucosal damage may inhibit the use of gastric lavage. The following tests may be useful: Liver and kidney function tests. MSDS # C04M ACQ-C2 MSDS (PROPRIETARY) PAGE 3 OF 10 5. FIRE-FIGHTING MEASURES FLASH POINT: Not applicable. AUTOIGNITION TEMPERATURE: Not applicable. NFPA RATING FLAMMABLE LIMITS tin air by volume. %): Lower (LEL): Not applicable. Upper (UEL): Not applicable. FIRE EXTINGUISHING MATERIALS: This product is not flammable. Use fire extinguishing material appropriate for the surrounding area. H~~„+ R~~„~r Water Sprax: YES Carbon Dioxide: YES Foam: YES Drv Chemical: YES Halon: YES Other: Any "ABC" Class. UNUSUAL FIRE AND EXPLOSION HAZARDS: This solution severely irritates contaminated tissue and presents a contact hazard to firefighters. °TM~ When involved in a fire, this material may decompose and produce irritating vapors and. toxic gases (carbon monoxide, carbon dioxide, copper compounds, and nitrogen oxides). This product must be substantially pre- See Section 16 for heated before ignition can occur. Definition of Ratings Explosion Sensitivity to Mechanical Impact: Not sensitive. Explosion Sensitivity to Static Discharge: Not sensitive. SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Move fire-exposed containers if it can be done without risk to firefighters. If possible, firefighters should control run-off water to prevent environmental contamination. Decontaminate equipment with soapy water before returning to service. 6. ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned procedures. Proper protective equipment should be used. In case of a large spill, clear the affected area, and protect people. For small releases, clean-up spilled liquid wearing gloves, goggles, faceshield, and suitable body protection. In the event of anon-incidental release, minimum Personal Protective Equipment should be Level B: triple-gloves (rubber gloves and nitrite gloves, over latex gloves), chemically resistant suit and boots, hard-hat, and Self Contained Breathing Apparatus). Neutralize residue with citric acid or other neutralizing agent for basic liquids. Decontaminate the area thoroughly. Test area with litmus paper to ensure neutralization. Place all spill residue in a suitable container. Dispose of in accordance with applicable U.S. Federal, State, or local procedures, or appropriate Canadian standards (see Section 13, Disposal Considerations). PART III How can 1 prevent hazardous situations from occurring? 7. HANDLING and STORAGE WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash hands after handling this product. Do not eat, drink, smoke or apply cosmetics while handling this product. All work practices should minimize the generation of splashes and aerosols. Remove contaminated clothing immediately. STORAGE AND- HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely. Avoid breathing vapors or mists generated by this product. Use in awell-ventilated location. Open containers slowly, on astable surtace. Containers of this product must be properly labeled. Empty containers may contain residual liquid or vapors therefore, empty containers should be handled with care. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10, Stability and Reactivity). Material should be stored in secondary containers, or in a diked area, as appropriate. Keep container tightly closed when not in use. Floors should be seated to prevent absorption of this material. If appropriate, post warning signs in storage and use areas. Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. If this product is transferred into another container, only use portable containers and dispensing equipment (faucet, pump, drip can) approved for corrosive, basic liquids. Recommended storage temperature is 10-30°C (50-86°F). Transfer material into properly labeled containers. Periodically inspect tanks and other containers of this product for leaks or damage. Ensure that dikes and berms surrounding tanks of this product are in good condition. Empty tanks, containers, pipelines, or process equipment may contain residual liquid; therefore, they must be handled with care. PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and tagged-out safely. 4lways use this product in areas where adequate ventilation is provided. Decontaminate equipment before maintenance oegins. Collect all waste materials, including rinsates and dispose of according to applicable U.S. Federal, State, or local procedures, or those of Canada and its Provinces. MSDS # C04M ACQ-C2 MSDS (PROPRIETARY) PAGE 4 OF 10 8. EXPOSURE CONTROLS -PERSONAL PROTECTION VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided in Section 2 (Composition and Information on Ingredients), if applicable. Exhaust directly to the outside. Use local exhaust ventilation, and process enclosure if necessary, to control mist formation. Supply sufficient replacement air to make up for air removed by system. Ensure eyewash/safety shower stations are available near areas where this product is used. RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below exposure limits listed in Section 2 (Composition and Information on Ingredients). If respiratory protection is needed (i.e. air-purifying respirator with an acid-gas cartridge), use only protection authorized in the U.S. Federal OSHA Standard (29 CFR 1910.134), applicable U.S. State regulations, or the Canadian CSA Standard 294.4-93 and applicable standards of Canadian Provinces. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use of afull-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard (1910.134-1998). The following NIOSH guidelines for the Amine Compound component and are provided for further information. CONCENTRATION RESPIRATORY PROTECTION Up to 30 ppm: Chemical cartridge respirator with cartridge(s) to protect against this compound; or gas mask with canister to protect against this compound; or powered air-purifying respirator with cartridge(s) to protect against this compound; or Supplied Air Respirator (SAR); orfull-facepiece SCBA. Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Positive pressure, full-facepiece SCBA; or positive pressure, full-facepiece SAR with an auxiliary positive pressure SCBA. Escape: Gas mask with canister to protect against this compound; or escape-type SCBA. Note: The IDLH concentration for this compound is 30 ppm. EYE PROTECTION: Splash goggles or safety glasses. Face shields are recommended when operations for which this product are used can generate splashes, sprays, or mists. HAND PROTECTION: Wear rubber or nitrite gloves for routine industrial use. Use triple gloves for spill response, as stated in Section 6 (Accidental Release Measures) of this MSDS. BODY PROTECTION: Use body protection appropriate for task (i.e. apron, Tyvek suit). 9. PHYSICAL and CHEMICAL PROPERTIES RELATIVE VAPOR DENSITY (air = 1): > 1 EVAPORATION RATE (n-BuAc=1):Not available. SPECIFIC GRAVITY (water = 1): 1.22 MELTING~FREEZING POINT: Not available. SOLUBILITY IN WATER: Soluble. BOILING POINT: Not available. VAPOR PRESSURE. mm Hg CcD 20°C (68°F): Not available. ~H: 9-10 ODOR THRESHOLD: 3 ppm (Amine Compound) LOG of OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable. APPEARANCE. ODOR AND COLOR: Blue solution with a faint, ammonia-like odor. HOW TO DETECT THIS SUBSTANCE (warning properties): The odor and blue color may act as distinguishing characteristics of this product. 10. STABILITY and REACTIVITY STABILITY: Stable. DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, sodium oxides. MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong oxidizing agents, strong acids, and materials that are not compatible with water. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Avoid exposure to extreme temperatures and contact with incompatible chemicals. PART IV Is there any other useful information about this material? 11. TOXICOLOGICAL INFORMATION TOXICITY DATA: Additional toxicology data for components greater than 1 percent in concentration are provided below. INORGANIC CARBON COMPOUND: LCLo (Inhalation-Human) 9 pph/5 minutes LCLo (Inhalation-Mammal-species unspecified) 90000 ppm/5 minutes TCLo (Inhalation-Rat) 10000 ppm/24 hours/30 days-continuous: Blood: other changes INORGANIC CARBON COMPOUND (continued): TCLo (Inhalation-Rat) 6 pph/24 hours: female 10 day(s) after conception; Reproductive: Specific Developmental Abnormalities: musculoskeletal system, cardiovascular (circulatory) system, respiratory system INORGANIC CARBON COMPOUND (continued): TCLo (Inhalation-Rat) 6 pph/24 hours: female 10 day(s) after conception: Reproductive: Effects on Newborn: growth statistics (e.g. %, reduced weight gain) MSDS # C04M ACQ~2 MSDS (PROPRIETARY) PAGE 5 OF 10 11. TOXICOLOGICAL INFORMATION (Continued) TOXICITY DATA (continued): INORGANIC CARBON COMPOUND COPPER COMPOUND: COPPER COMPOUND (continued): (continued): TCLo (Inhalation-Rabbit) 27000 ppm/24 hours/30 TDLo (Oral-Human) 120 µg/kg: Gastrointestinal: TCLo (Inhalation-Mouse) 55 pph/2 hours: male 3 days-continuous: Behavioral: somnolence nausea or vomiting day(s) pre-mating: Reproductive: Paternal (general depressed activity) LDS (Intreperitoneal-mouse) 3500 µg/kg Effects: spermatogenesis (incl. genetic TDLo (Oral-rat) 152 mg/I~q: female 22 week(s) TDLo (Intrauterine-rat) 250 µg/kg: female 1 material, sperm morphology, motility, and pre-mating: fetoto~acity; Specific day(s) pre-mating: Reproductive: Maternal count) Developmental Abnormalties: Central Effects: uterus, cervix, vagina; female fertility TCLo (Inhalation-Mouse) 55 pph/4 hours: male 6 Nervous System index day(s) pre-mating: Reproductive: Fertility: TDLo (Oral-rat) 1520 µg/I~q: female 22 week(s) AMINE COMPOUND• male fertility index (e.g. # males impregnating pre-mating: Reproductive: Speck Skin Irritancy (rabbit) 505 mg moderate imtation. females per # males exposed to fertile non- Developmental Abnormalities: Eye irritation (rabbit) 0.763 mg severe irritation. pregnant females)TCLo (Inhalation-Mouse) 2 musculoskeletal system TDLo (oral -rat) = 500 mglkg (Teratogenic pphl8 hours: female 10 day(s) after TDLo (Oral-rat) 1210 µg/I~q: female 35 week(s) effect). conception: Reproductive: Fertility: post- pre-mating: Reproductive: Fertility: pre- LDS (oral -rat) = 1720 mg/I~y. implantation mortality (e.g. dead and/or implantation mortality, post-implantation LDS (intraperitoneal- rat) = 67 mg/kg. resorted implants per total number of mortality LDS (subcutaneous -rat) =1500 mg/l~y. implants), Reproductive: Specific TDLo (Intrapleural-rat) 100 mg/I~q: Tumorigenic: LDS (intravenous -rat) =225 mg/l~q. Developmental Abnormalities: equivocal tumorigenic agent; Lungs, Thorax, LDS (intramuscular -rat) =1750 mg/kg. musculoskeletal system or Respiration: fibrosis, focal LDso (oral -mouse) = 700 mg/kg. TCLo (Inhalation-Rabbit) 13 pph/4 hours: female (pneumoconiosis), tumors LDso (intraperitoneal -mouse) = SO mg/I~q. 5-12 day(s) after conception: Reproductive: Specific Deveopmental Abnormalities: LDS (skin -rabbit) = 1000 mg/kg musculoskeletal system SUSPECTED CANCER AGENT: This product's ingredients are not found on the following lists: U.S. FEDERAL OSHA Z LIST, NTP, IARC, CAUOSHA, and therefore are not considered to be, or suspected to be, cancer-causing agents by these agencies. IRRITANCY OF PRODUCT: This product is moderately to severely irritating to contaminated tissue. SENSITIZATION TO THE PRODUCT: The product can cause allergic skin reactions (i.e. rashes, welts) in sensitive individuals. REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its components on the human reproductive system. MutaQenicity: This product is not reported to produce mutagenic effects in humans. Embrvotoxicity: This product is not reported to produce embryotoxic effects in humans. ~' Teratogenicity: This product is not reported to cause teratogenic effects in humans. Reproductive Toxicity: This product is not reported to cause reproductive effects in humans. A m agen is a chemical which causes permanent changes to genefic material (DNA) such that the changes will propagate through generational lines. An embrvotoxin is a chemical which causes damage to a developing embryo (i.e. within the first eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratoaen is a chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is any substance which interferes in any way with the reproductive process. ACGIH BIOLOGICAL EXPOSURE INDICES (BEIs): Currently, there are no ACGIH Biological Exposure Indices (BEIs) determined for the components of this product. 12. ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION ENVIRONMENTAL STABILITY: The components of this product will slowly degrade in the environment to form a variety of organic and inorganic compounds. Specific environmental data for this product are presented below. INORGANIC CARBON COMPOUND: Food chain concentration potential: None. Biological Oxygen Demand: None. COPPER COMPOUND: Solubility: Insoluble. There is no evidence of any biotransformation for copper compounds. Copper is accumulated by all plants and animals. BCF Algae = 12; plants = 1,000; invertebrate = 1,000, fish =667 and fish = 20D (Soluble copper salts). AMINE COMPOUND: flow = -1.31 (est.) Water Solubility: Miscible. Bioconcentration: A bioconcentration factor (BCF) of was estimated for 2aminoethanol(MEA) based on a log Kow of -1.31. This BCF value and complete solubility of MEA in water suggest that this compound does not bioconcentrate significantly in aquatic organisms Biodegradation: Biological oxygen demand (BOD): 78%, 5 days; (theoretical) 0%, 5 days; 64%, 20 days. Persistence: Biodegrades at moderate rate. ' Terrestrial Fate: If released to soil, this compound is expected to biodegrade fairly rapidly following acclimatization, wdh a half-life on the order of days to week. This compound will leach in soil to groundwater. Volatilization is not a significant fate process from the soil. (continued on following page) MSDS # C04M ACQ-C2 MSDS (PROPRIETARY) PAGE 6 OF 10 • 12. ECOLOGICAL INFORMATION (Continued) ENVIRONMENTAL STABILITY (continued): AMINE COMPOUND (continued): Aquatic Fate: If released to water, this compound should undergo biodegradation. The half-life in water is expected to be from a few days to weeks, depending on the acclimatization in the aquatic system. f. Atmospheric Fate: If released to the atmosphere, this compound is expected to exist entirely in the vapor phase. The primary mechanism of removal from the s, atmosphere would be by reaction with photochemically generated hydroxyl radicals, with an expected half-life of 4 hours. The complete solubility if this compound suggests that lt will also be removed by precipitation. EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product may be harmful to contaminated plants or animals, especially if large volumes are released into the environment. Refer to Section 11 (Toxicology Information) for specific data on the product's components and their effects on test animals. The following information is available on the effects of copper on plants Several studies have indicated that growth was reduced in a variety of terrestrial plants grown in a copper sulfate solution at a concentration of less than 1 ppm. Growth in many plants was greatly reduced at concentrations of copper sulfate at 20 ppm or less. Tomato plants were seriousty damaged when sprayed once a week for 3 months with a 2.4 g/L cupric hydroxide solution. Among aquatic plants, the algae chlamydomonas, Scenedesmus quadricauda, and the dratom cyclotella meneghiniama showed growth reduction at 8 mglL. Scenedesmus quadricauda also showed phosphorus uptake inhibition after 45 minute exposure at 0.005 mg/L. Chlorella sp. showed lag in growth at 0.001 mg/L. Duckweed, L. minor, reported a 7 day ECso of 0.119 mg/L. PHYTOTOXICITY: AQUATIC PLANTS -COPPER COMPOUND: Lag ingrowth (Anabaena Alga strain 7120) Effect: at 0.064 mg/L ECso (Chlorella vulgaris Alga) 33-days = 0.18 mg/L Lag ingrowth (Chlorella pyrenoidosa Atga) = 0.001 mg/L ECso (Chlorela saccharophila Atga) 96-hours = 0.550 mg/L Lag ingrowth (Chlorella regu/aris Alga) = 0.02 mg/L ECso (Navicu/a incerta Diatom) 4-days = 10.45 mg/L Photosynthesis inhibited (Chbreda sp. Alga) = 0.0063 mglL ECso (Nrtzschia ~nearis Diatom) 5~tays = 0.795-0.815 mg/L Growth inhibition (Anabaena variabilis Alga) Effect: at 0.1 mg/L ECso (Myriophyllum spicatum Eurasian watermilfoil) 32-days (root weight) _ Growth inhibition (Anacysstis nidulans Alga) = at 0.1 mg/L 0.25 mg/L Growth reduction (Ankistrodesmus braunu Alga) = 0.640 mg/L ECso (Selenastrum capricomutum Green alga) 14-days = 0.085 mg/L Growth inhibition (Chlorela pyrenoidosa Alga) = 0.1 mg/L ECso (Lemna minor Duckweed) Effect: 7-day at 0.119 mg/L Growth inhibition (Chlorella vulgaris Alga) = 0.2 mg/L ECso inhibition of phosphorus uptake (Scenedesmus quadricauda Green Growth inhibtion (Eudorina ca6fomica Alga) = 5.0 mg/L alga) 45 minutes = 0.0051 mg/L Growth inhibition 75% (Anabaena flos-aqa Alga) = 0.2 mg/L 50% reduction in photosynthetic 02 production (Elodea canadensis Complete growth inhibition (Nitzschia pa/ea Diatom) = at 0.005 mg/L Macrophyte) Effect: at 0.15 mg/L ICso (Chlorella vulgaris Alga) 96-hours = 0.062 mg/L Incipient inhibition (Microcystis aeruginosa Blue alga) = 0.03 mg/L Growth reduction (Chiamydomonas sp. Alga) = 8.0 mg/L Incipient inhibition (Scenedesmus quadricauda Green alga) =1.1 mg/L Growth reduction (Chlorella vulgaris Alga) = 0.1-0.2 mg/L Inhibited growth (Haematococcus sp. Green algae) Duration: 96 hours = Growth reduction (Chmococcus pans Alga) = 0.1 mg/L 0.05 mg/L Growth reduction (Cyclotella meneghiniana Alga) = 8.0 mg/L Incipient inhibition (Scenedesmus quadricauda Green alga) 96 hours = 0.15 Growth reduction (Scenedesmus quadricauda Alga) = 8.0 mg/L mg/L ~~ Growth reduction (Se/enastrum capricomutum Green alga) = 0.05 mg/L Suppressed growth (Cladophora glomerate Alga)12 months = 0.12 mg/L 40% growth reduction (Scenedesmus acuminates Alga) = 0.3 mg/L Suppressed growth (Coreonels placentula) 12 months = 0.12 mg/L EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may be harmful or fatal to exposed aquatic life. Specific aquatic toxicity data for components of this product are as follows: INORGANIC CARBON COMPOUND: Lethal (trout) 1 hour = 240 mg/L Lethal (rainbow trout)12 hours =60-240 mg/L Lethal (rainbow trout) 96 hours = 35 mg/L Harmful to some species of aquatic life in concentrations less than 20 mg/L COPPER COMPOUND: LCso (fathead minnows) = 0.14 ppm in hard water LCso (bluegill) = 0.02 ppm in soft water LCso (brook trout) = 0.09 ppm in soft water LCso (Anguipa American eel) 96 hours = 6.4 MATC (Oncorhynctshawtsch Chinook salmon) = 0.0074 MATC (Sa/mo gairalneri brown trout) = 0.01901 NOAEL (Oncorhynctshawtsch Chinook salmon) = 0.0074 COPPER COMPOUND (continued): NOAEL (Salmo gairdneri brown trout) = 0.0114 LOAEL (Salmo gairdneri brown trout) = 0.0317 AMINE COMPOUND: Threshold Limits: 1,000 -10,000 ppm. Toxicity Threshold (cell multiplication inhibition test): ECo (bacteria) = 6300 mg/L; 16 hours ECo (alga) = 1.6 mg/L; 8 days ECo (green algae) = 0.75 mg/L; 7 days ECo (protozoa, Entosiphon sulcatum) =300 mg/L; 32 hours LDso (goldfish) = 190 mg/L, 24 hours LDso (goldfish) =170 mg/L, 96 hours LDso (goldfish) _ >5000 mg/L, 24 hours 13. DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal, State, and local regulations, or those of Canada and its Provinces. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local hazardous waste regulatory authority. U.S. EPA WASTE NUMBER: Wastes of this product should be tested for D002 (Characteristic/Corrosivity). MSDS # C04M ACQ~2 MSDS (PROPRIETARY) PAGE 7 OF 10 ' ~ 14. TRANSPORTATION INFORMATION THIS MATERIAL IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: Corrosive liquids, n.o.s. (Alkaline copper complex) ~ HAZARD CLASS NUMBER and DESCRIPTION: 8 (Corrosive) UN IDENTIFICATION NUMBER: UN 1760 PACKING GROUP: III DOT LABEL(S) REQUIRED: Corrosive NORTH AMERICAN EMERGENCY RESPONSE GUIDE NUMBER (2000): 154 TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This material is considered as dangerous goods, per regulations of Transport Canada. Use information on above U.S. DOT shipping for shipments into Canada. 15. REGULATORY INFORMATION ADDITIONAL U.S. REGULATIONS: U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act, as follows. CHEMICAL NAME SARA 302 SARA-304 '-' SARA 313 (40 CFR 355, Appendix A) (40 GFR Table 302.4) (~40 CER 372.65) COPPER (as a Copper NO NO YES; CATEGORY Compound) CODE N100 U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any component of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lbs. (4,540 kg) therefore applies, per 40 CFR 370.20. U.S_CERCLA REPORTABLE QUANTITY (RQ): 1001b (45.4 kg) for unlisted wastes of Characteristic Corrosivity. U.S. TSCA INVENTORY STATUS: The chemicals in this product are listed on the TSCA Inventory. OTHER U.S. FEDERAL REGULATIONS: Not applicable. U.S. STATE REGULATORY INFORMATION: Components in this product, specifically listed in Section 2 (Composition and Information on Ingredients), are covered under specific State regulations, as denoted below: Alaska -Designated Toxic and Hazardous Substances: Inorganic Carbon Compound, Copper Compound, Amine Compound. California -Permissible Exposure Limits for Chemical Contaminants: Inorganic Carbon Compound, Copper Compound, Amine Compound. Florida -Substance List: Inorganic Carbon Compound, Copper Compound, Amine Compound. Illinois - Toxic Substance List: Inorganic Carbon Compound, Amine Compound, Copper Compound Compounds. Kansas - Section 302/313 List: Copper Compound-based pesticides. Massachusetts - Substance List: Inorganic Carbon Compound, Copper Compound, Amine Compound. Michigan -Critical Materials Register: None. Minnesota -List of Hazardous Substances: Inorganic Carbon Compound, Copper Compound Fume Amine Compound. Missouri - Employer Information/Toxic Substance List: Inorganic Carbon Compound, Copper Compound, Amine Compound. New Jersey - Right to Know Hazardous Substance List: Inorganic Carbon Compound, Copper Compound Amine Compound. North Dakota -List of Hazardous Chemicals, Reportable Quarrtities: Copper Compound. Pennsylvania -Hazardous Substance List: Inorganic Carbon Compound, Copper Compound, Amine Compound. Rhode Island -Hazardous Substance List: Inorganic Carbon Compound, Copper Compound, Amine Compound. Texas -Hazardous Substance List: Inorganic Carbon Compound, Copper Compound Fume & Mist, Amine Compound. West Virginia -Hazardous Substance List: Inorganic Carbon Compound, Copper Compound Fume, Amine Compound. Wisconsin - Toxic and Hazardous Substances: Inorganic Carbon Compound, Copper Compound Fume, Amine Compound. CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT jPROPOSITION 65~: NO Component Of thlS prOdUCt IS On the California Proposition 65 lists. ANSI LABELING (Der 2129.1) (Precautionary Statements): DANGER! CORROSIVE. CAUSES BURNS AND IRRITATION TO SKIN, EYES RESPIRATORY SYSTEM. MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED. MAY CAUSE SKIN SENSITIZATION AND ALLERGIC REACTION. Do not taste or swallow. Do not get on skin or in eyes. Avoid breathing vapors or mists. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Wear gloves, goggles, face-shield, suitable body protection, and NIOSH approved respirator as necessary. FIRST-AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If inhaled, remove to fresh air. If ingested, do not induce vomiting. Get medical attention. IN CASE OF FIRE: Use water fog, dry chemical, CO2, or °alcohol° foam. IN CASE OF SPILL: Absorb spill with inert material or neutralizing agent for basics. Place residue in suitable container. Consun Material Safety Data Sheet for additional information. MSDS # C04M ACQ~2 MSDS (PROPRIETARY) PAGE 8 OF 10 15. REGULATORY INFORMATION (Continued) ADDITIONAL CANADIAN REGULATIONS: CANADIAN DSUNDSL INVENTORY STATUS: The components of this product are on the DSL Inventories. OTHER CANADIAN REGULATIONS: Not applicable. -`~ CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this product are not on the CEPA Priorities Substances Lists. CANADIAN WHMIS SYMBOLS: Class D2B: Other Toxic Effects-Skin Sensitization Class E: Corrosive Material o ~~ 16.OTHER INFORMATION PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc. 9163 Chesapeake Drive, San Diego, CA 92123-1002 858/565-0302 The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or the results to be obtained from the use thereof. Chemical Specialties Inc. assumes no responsibility for injury to the vendee or third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Chemical Specialties Inc. assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthem~ore, vendee assumes the risk in his use of the material. MSDS # C04M ACQ-C2 MSDS (PROPRIETARY) PAGE 9 OF 10 DEFINITIONS OF TERMS A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following: CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent. It is used for computer-related searching. EXPOSURE LIMITS IN AIR: ACGIH -American Conference of Governmental Industrial Hygienists, a professional association which establishes exposure limits. TLV - Threshold Limit Value - an airborne concentration of a substance which represents oonditiorts under which it is generally believed that Hearty al! workers may be repeatedly exposed without adverse effect. The duration must be considered, including the 8-hour Time Weighted Average (TWA), the 15-minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C). Skin absorption effects must also be considered. OSHA - U.S. Occupational Safety and Health Administration. PEL - Permissible Exposure Limit -This exposure value means exactty the same as a TLV, except that tt is enforceable by OSHA. The OSHA Permissible Exposure Limits are based in the 1989 PELs and the June, 1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: 40191). Both the current PELs and the vacated PELs are indicated. The phrase, "Vacated 1989 PEL," is placed next to the PEL which was vacated by Court Order. IDLH -Immediately Dangerous to Life and Health -This level represents a concentration from which one can escape within 30-minutes without suffering escape-preventing or permanent injury. The DFG - MAK is the Republic of Germany's Maximum Exposure Level, similar to the U.S. PEL. NIOSH is the National Institute of Occupational Safety and Health, which is the research arm of the U.S. Occupational Safety and Health Administration (OSHA). N10SH issues exposure guidelines called Recommended Exposure Levels (RELs). AIHA WEEL is the American Industrial Hygiene Association Workplace Environmental Exposure Level Guides. When no exposure guidelines are established, an entry of NE is made for reference. HAZARD RATINGS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight acute or chronic exposure hazard); 2 (moderate acute or significant chronic exposure hazard); 3 (severe acute exposure hazard; onetime overexposure can result in permanent injury and may be fatal); 4 (extreme acute exposure hazard; onetime overexposure can be fatal). Flammabilityy Hazard: 0 (minimal hazard); 1 (materials that require substantial pre-heating before burning); 2 (combustible liquid or solids; liquids with a flash point of 38~3°C [100.200°F]); 3 (Class IB and IC flammable liquids with flash points below 38°C [100°F]); 4 (Class IA flammable liquids with flash points below 23°C [73°Fj and boiling points below 38°C [100°F). Reactivity Hazard: 0 (nonnalty stable); 1 (material that can become unstable at elevated temperatures or which can react slightly with water); 2 (materials that are unstable but do not detonate or which can react violently with water); 3 (materials that can detonate when initiated or which can react explosively with water); 4 (materials that can detonate at normal temperatures or pressures). NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 (material that on exposure under frre conditions would offer no hazard beyond that of ordinary combustible materials); 1 (materials that on exposure under fire conditions could cause irritation or minor residual injury); 2 (materials that on intense or continued exposure under fire conditions could cause temporary incapacitation or possible residual injury); 3 (materials that can on short exposure could cause serious temporary or residual injury); 4 (materials that under very short exposure causes death or major residual injury). NATIONAL FIRE PROTECTION ASSOCIATION (Continued): Flammabil'~ Hazard and Reactivity Hazard: Refer to definitions for "Hazardous Materials Identification System". ' FLAMMABILITY LIMITS IN AIR: Much of the information related to fire and explosion is derived from the National Fire Protection Association (NFPA). Flash Point - Minimum temperature at which a liquid gives off sufficient vapors to form an ign'dable mbcture with air. Autoionttion Temperature: The minimum temperature required to initiate combustion in air with no other source of ignition. LEL -the lowest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. UEL -the highest percent of vapor in air, by volume, that will explode or ignite in the presence of an ignition source. TOXICOLOGICAL INFORMATION: Human and Animal Toxicology: Possible health hazards as derived from human data, animal studies, or from the results of studies wtth similar compounds are presented. Definitions of some terms used in this section are: LDS -Lethal Dose (solids & liquids) which kills 50% of the exposed animals; LCD -Lethal Concentration (gases) which kills 50% of the exposed animals; ppm concentration expressed in parts of material per million parts of air or water; mg/m~ concentration expressed in weight of substance per volume of air; mg/kg quantity of material, by weight, administered to a test subject, based on their body weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic effects. Cancer Information: The sources are: IARC -the International Agency for Research on Cancer; NTP -the National Toxicology Program, RTECS -the Registry of Toxic Effects of Chemical Substances, OSHA and CAUOSHA. IARC and NTP rate chemicals on a scale of decreasing potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 26, etc.) are also used. Other Infom~ation: BEI -ACGIH Biological Exposure Indices, represent the levels of determinants which are most likely to be observed in specimens collected from a healthy worker who has been exposed to chemicals to the same extent as a worker with inhalation exposure to the TLV. Ecological Infom~ation: EC is the effect concentration in water. BCF = Bioconcentration Factor, which is used to determine if a substance will concentrate in lifefomts which consume contaminated plant or animal matter. Coefficient of OiVWater Distribution is represented by log K°,,,or log IC°° and is used to assess a substance's behavior in the environment. REGULATORY INFORMATION: This section explains the impact of various laws and regulations on the material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is the U.S. Department of Transportation. SARA is the Superfund Amendments and Reauthorization Act. TSCA is the U.S. Toxic Substance Control Act. CERCLA (or Superfund) refers to the Comprehensive Environmental Response, Compensation, and Liability Act. Labeling is per the American National Standards Institute (ANSI Z129.1). CANADA: CEPA is the Canadian Environmental Protection Act. WHMIS is the Canadian Workplace Hazardous Materials Information System. TC is Transport Canada. DSLMDSL are the Canadian DomestiGNon-Domestic Substances lists. MSDS # C04M ACQ-C2 MSDS (PROPRIETARI~ PAGE 10 OF 10 MATERIAL SAFETY DATA SHEET DRICON~ FIRE RETARDANT SOLUTION December 1, 2002 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Identifier: Dricon®Fire Retardant Solution General Use: Fire retardant MANUFACTURER: EMERGENCY TELEPHONE NUMBERS: Arch Wood Protection, Inc. *CHEMTREC Assistance: 1-800-424-9300 3941 Bonsal Road *CANUTEC: 1-613-996-6666 Conley, Georgia 30288 ACEAN 24 hour Emg. Resp. 1-800-654-6911 MSDS Information 1-800-511-6737 *Use only during transportation emergencies 2. COMPOSITION /INFORMATION ON INGREDIENTS EXPOSURE LIMITS (mg/m'j HAZARDOUS PERCENT CAS # ACGIH - INGREDIENTS OSHA - PEL ACGIH - TLV STEL Boric Acid 2-6 10043-35-3 *None None None Guanylurea Phosphate 5-14 17675-60-4 *None None None Phosphoric Acid 0.0-0.2 7664-38-2 1 mg/m3 1 mg/m3 3 mg/m3 Water 80-93 3. HAZARDS IDENTIFICATION Inhalation: Occasional mild irritation effects to nose and throat may occur from inhalation of dust. Eye Contact: Moderately irritating. Skin Contact: May produce mild irritation. Ingestion: May produce mild gastrointestinal irritation. Swallowing large amounts may result in headache, drowsiness, or restlessness. 4. FIRST AID MEASURES Inhalation: Minimal effect should be observed in normal usage, however, if breathing difficulty should arise, remove person from exposure and seek medical aid. Eye Contact: Exposed eyes should be flushed with .large amounts of saline or water for at least 15 minutes, (greater than 1 liter per eye, minimum) using low pressure, taking care that the eyes remain open during this entire procedure. If wearing contact lenses, immediately flush eyes with water for a short period prior to removing contacts, then resume flushing procedures as described above. Immediately seek medical aid. Skin Contact: IMMEDIATELY wash affected skin areas thoroughly with soap and water. Remove and wash contaminated clothing thoroughly. If irritation develops, seek medical attention. Ingestion: IMMEDIATELY seek medical attention. Never give anything by mouth to an unconscious person. Call a physician or poison center at (800) 837-0496 (Outside the US call 1-404-616-9000). 5. FIRE FIGHTING MEASURES Flash Point N/A Lower Explosive Limit N/A Auto-Ignition N/A Upper Explosive Limit N/A Unusual Hazards: This product is not flammable, combustible, or explosive, therefore, is not a fire hazard. However, fire from a separate source may be intense enough to cause thermal decomposition, releasing toxic gases including oxides of carbon and nitrogen. No unusual hazards if involved in a fire. Dricon® Fire Retardant Solution December 1, 2002 5. FIRE FIGHTING MEASURES CONT'D Page 2 of 4 Extinguishing Agents: Use extinguishing media appropriate for surrounding fire. Personal Protective Equipment: Wear self-contained breathing apparatus (pressure-demand NIOSH/NFPA approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal Protection: During spill clean-ups of this material you may need to wear a NIOSH-approved dust/mist/particulate respirator. Wear protective clothing including Splash goggles, polyvinyl chloride (PVC), neoprene or natural rubber gloves. See SECTION 4, First Aid Measures and SECTION 8, Exposure Controls/Personal Protection for further information. Procedures: CAUTION: Keep spills and cleaning runoff out of municipal sewers and open bodies of water. Use inert absorbent (such as kitty litter) to pick up spills. Vacuum, shovel, or sweep land spills and place in containers for disposal in accordance with applicable state and local regulations. NOTE: Most spills that occur within containment in a treating plant can simply be flushed with water into a sump to be pumped back into the system. 7. HANDLING AND STORAGE Storage Conditions: Keep from freezing. Store in ambient temperature and atmospheric pressure. Handling Procedures: No special handling precautions are required. Good housekeeping procedures should be followed to minimize releases. 8. EXPOSURE CONTROLS /PERSONAL PROTECTION Respiratory Protection: None normally required. For conditions that exceed PEL, use a half or full-face respirator with HEPA/P100 cartridges. Eye Protection: Use splash goggles to prevent entry into the eyes. Hand Protection: Gloves in the following materials give adequate protection: polyvinyl chloride (PVC), neoprene or natural rubber. Rinse and remove gloves after use. Wash hands with soap and water. Other Protection: Use apron or other impervious clothing to avoid prolonged or repeated skin contact. Engineering Controls: Provide sufficient local and/or general exhaust ventilation to control airborne concentrations of this product below permissible exposure levels. Other Protective Equipment: Emergency eyewash and safety shower station for quick drenching or flushing. 9. PHYSICAL AND CHEMICAL PROPERTIES Color Clear to pale yellow Vapor Pressure N/A State Liquid Freezing Point Not Available Odor Characteristic Odorless Solubility in Water Soluble PH 2.5 - 4.5 Percent Volatility N/A Viscosity N/A Evaporation Rate (BAc =1) N/A Specific Gravity (Water = 1) 1.02 -1.10 Vapor Density (Air = 1) N/A 10. STABILITY AND REACTIVITY Instability: This material is considered stable under specified conditions of storage, shipment and/or use. The Boric Acid component is also stable on its own, however, when heated it loses water, first forming Metaboric Acid (HB02), and on further heating is converted into Boric Oxide (6203). Hazardous Decomposition Products: Oxides of carbon and nitrogen. Hazardous Polymerization: NA Incompatibility: The Boric Acid component reacts as a weak acid, which may cause corrosion of base metals. Reaction with strong reducing agents such as metal hydrides or alkali metals will generate hydrogen gas, which could create an explosive hazard. Dricon® Fire Retardant Solution December 1, 2002 Page 3 of 4 11. TOXICOLOGICAL INFORMATION Acute Data: Currently there is no data on Dricon® Fire Retardant Solution. Please refer to the Dricon® Fire Retardant MSDS for information. Carcinogenicity Data: Is not considered a carcinogen. Mutagenicity Data: Non-mutagenic in the Ames test. Reproductive/Teratology Data: Animal studies indicate that the component Boric Acid reduces or inhibits sperm production, causes testicular atrophy, and when given to pregnant animals during gestation may cause developmental changes. These feed studies were conducted under chronic exposure conditions leading to doses man times in excess of those that could occur through inhalation of dust in occupational settings. Sensitization Data: Is not a skin sensitizer. 12. ECOLOGICAL INFORMATION Environmental Toxicity: Currently there is no data on Dricon® Fire Retardant Solution. Please refer to the Dricon® Fire Retardant MSDS for information. Phytotoxicity: Although boron is an essential micronutrient for healthy growth of plants and is naturally occurring in the environment, it can be harmful to boron-sensitive plants in higher quantities. Boric Acid decomposes in the environment to natural borate. Plants and trees can be exposed by root absorption to toxic levels of boron in the form of water-soluble borate leached into nearby soil or waters. Care should be taken to minimize the amount of Dricon® Fire Retardant product released to the environment. Environmental Fate Data: Persistence/Degradation: Boron is naturally occurring and ubiquitous in the environment. Boric Acid is decomposed in the environment to natural borate. Soil Mobility: Boric Acid is soluble in water and is leachable through normal soil. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. 13. DISPOSAL CONSIDERATIONS Procedure: As of the date on this MSDS, this product is not classified as an US-EPA RCRA hazardous waste under 40 CFR 261. Under RCRA, it is the responsibility of the user of the product to determine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Check local and state regulations, as they may be more stringent. 14. TRANSPORT INFORMATION DOT Hazardous Materials Classification: This product is not an U.S. Department of Transportation (DOT) Hazardous Material and thus does not have a DOT Proper Shipping Name. 15. REGULATORY INFORMATION OSHA: This product is considered hazardous under the OSHA Hazard Communication Standard (29 CFR 1910.1200). CANADA: This product is not subject to regulation under the Canadian Pest Control Products Act (P.C.P. Act). SARA TITLE III Section 311/312 Categorizations (40 CFR 370): If a plant has stored 10,000 pounds or more of Dricon powder and solution during the previous year, it must be reported on the SARA Tier II form. Dricon® Fire Retardant Solution Page 4 of 4 December 1, 2002 15. REGULATORY INFORMATION CONT'D SARA TITLE III Section 313 Information (40 CFR 372): As of June, 2000, phosphoric acid was removed from the Section 313 required reporting list. As of the date on this MSDS, there are no ingredients requiring reporting. CERCLA Information (40 CFR 302.4): Not Applicable. Local and State Regulations may still require notification. Waste Classification (RCRA): As of the date on this MSDS, this product is not classified as an US-EPA RCRA hazardous waste under 40 CFR 261. Under RCRA, it is the responsibility of the user of the product to determine at the time of disposal, whether the product meets RCRA criteria for hazardous waste. Check local and state regulations, as they may be more stringent. FIFRA: This product is subject to regulation under the US Federal Insecticide, Fungicide and Rodenticide Act (FIFRA) and is therefore exempt from U.S. Toxic Substances Control Act (TSCA) Inventory listing requirements. NFPA: Health = 1, Flammability = 0, Reactivity = 0 HMIS: Health = 1, Flammability = 0, Reactivity = 0 16. OTHER INFORMATION CAS Chemical Abstracts Service / NOTICE: While the information and recommendations set forth herein are believed to be accurate as of the date hereof, Arch Wood Protection, Inc. makes no guarantee or warranty, expressed or implied, as to the accuracy, reliability, or completeness of the information. .' ABBREVIATIONS r OSHA Occupational Safety and Health Administration TLV Threshold Limit Value / NFPA National Fire Protection Association STEL ~ Short-Term Exposure Limit FIFRA Federal Insecticide, Fungicide and Rodenticide Aci RCRA Resource Conservation and Recovery Act CERCLA Comprehensive Environmental Response, ACGIH American Conference of Governmental Industrials Compensation, and Liability Act Hygienists SARA Superfund Authorization and Reauthorization Act NIOSH National Institute of Occupational Safety and Health PEL Permissible Exposure Limit TSCA Toxic Substances Control Act DOT Department of Transportation IARC International Agency for Research on Cancer NTP National Toxicology Program IBC International Building Code ~ CFR Code of Federal Regulations mg/m3 Milligrams per cubic meter ~ CWA Clean Water Act CAA Clean Air Act /~ /~ f `,. ~~ f 11 ~j: + PACIFIC WOOD PRESERVING/BAKERSFIE ___________________ SiteID: 015-021-000567 + Manager RICK MCCULLOUGH Location: 5601 DISTRICT BLVD City BAKERSFIELD CommCode: BFD STA 13 EPA Numb: CAT000611145 BusPhone: (661) 833-0429 Map 123 CommHaz High Grid: 15D FacUnits: 7 AOV: SIC Code:2491 DunnBrad:ll-881-0514 Emergency Contact / Title Emergency Contact / Title RICK MCCULLOUGH / PLANT MANAGER CASEY ZIEMER / ASST PLANT MGR Business Phone: (661) 833-0429x36 Business Phone: (661) 833-0429x38 24-Hour Phone (661) 201-3203x 24-Hour Phone (661) 979-3598x Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: RSs Fire Press React ImmHlth DelHlth Contact RICK MCCULLOUGH Phone: (661) 833-0429x36 MailAddr: 5601 DISTRICT BLVD State: CA City BAKERSFIELD Zip 93313 Owner- RICHARD JACKSON Phone: (775) 832-5225x Address 668 TYNER WY State: NV City INCLINE VILLAGE Zip 89451 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: Yes ParcelNo: Emergency Directives: PROG A PROG H PROG R PROG T - HAZMAT - HAZ WASTE GEN - CAL ARP - ABOVEGROUND STORAGE TANK THIS IS A RMP SITE AND REQUIRES A JOINT INSPECTION. PLEASE CALL ENV SVGS TO SCHEDULE THIS INSPECTION, Based on my inquiry of those individuals responsible for obtaining the information, i certify under penalty of law that I have personally examined and am familiar with the information submitted and believe the information is true, accurate, and c replete. ~~ ~ -~ . o~ Date Signature ENr~ A~~ z ~ coos -1- 03/14/2006