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BUSINESS PLAN 3/29/2007
~: ,~ ~. ,; ~~ r--~ F CLEANSOUI2CE 5oq~kl Manager ~I Wt ~ U I $, ~CAlE~Zp L MANACs~IZ, Location: 6881 DISTRICT BLVD F City BAKERSFIELD CommCode: BFD STA 09 EPA Numb: SiteID: 015=021-000475 BusPhone: (661) 827-5300 Map 123 CommHaz High Grid: 16D FacUnits: 1 AOV: SIC Code: 5399 DunnBrad: Emergency Contact / Title Emergency Contact / Title JIM BUIS j GENERAL MANAGER $~nda L~.ugh~ 1 r1 / Opera-~-i0n5 Mana9 Business Phone: (661) 827-5300x5'313 Business Phone: ((v(~~ )gay -5~ ~53.~0 24-Hour Phone (661) 747-9106x 24-Hour Phone ([p(p~ )4~ -~(px Pager Phone ( ) - x Pager Phone ( ) - x .............. Hazmat Hazards: Fire React ImmHlth DelHltf~ .... Contact : cijfetrldq (.ciu9hlin, pperafions (Ylara~-~!' Phone: (661) 827-5300x5~~~ MailAddr: 6881 DISTRICT BLVD F State: CA City BAKERSFIELD Zip 93313 Owner CLEANSOURCE Phone: (408) 954-1234x Address 650 BRENNAN ST State: CA City SAN JOSE Zip 95131-1204 .............. Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: No ParcelNo: _.... Emergency Directives: PROG A - HAZMAT Based on my inquiry of those individuals ~N~t~ ,~p"~ r ~ ~~~ responsible for obtaining the information, I certify under penalty of law that I have personally examined and am familiar with the information submitted and believe the information is true, accurate, and complete. ~•~9.07 , i nature Date 9 -1- Ol/29/~007 f4- ~ F CLEANSOURCE SiteID: 015-021-0004'76 ~ ~ Hazmat Inventory By Facility Unit ~ ~ MCP+DailyMax Order Fixed Containers on Site ~ Hazmat Common Name... LIQUID BLEA H MOPPAC 2 BIG D LIQUID ODORANT GLASS PAC & 140 DEPOT PP. #1705 DEPOT PAC/ AIR FR SILICONE LUBE AERO L BORAX HAND SOAP COMET CLEANSER CHEM CHOR LOW SUDS DET C CONCRETE CLEANER PORTABLE TOILE ADDITIVE CLEAN SWEEP GO JO #9152 PA BATH HENER ENT S EPA Hazards Frm R IH DH L IH L F IH DH L IH L IH L F L S' DH S S IH DH S R IH L F DH S IH S DailyMax Unit 1`~+I~P _._.. 1356.00 GAL Hi 360.00 GAL Hi 388.00 GAL l~od 3 6 0. 0 0 GAL l~od 15 0. 0 0 GAL N1od 84.00 GAL I~od 1450.00 LBS Lew 94 5 . 0 0 LBS Lt~w 400.00 LBS Ldw 200.00 LBS Lnw 182.00 GAL Lnw 5250.00 LBS Ntn 2 5 . 0 0 LBS U1iR -2 - O1/29/~'007 -3- - O1/29/~007 F CLEANSOURCE SiteID: 015-021-000475 ~ ~ Inventory Item 0060 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME LIQUID BLEACH Days On Site 365 Location within this Facility Unit Map: Grid: S WALL CTR WHSE ~ CAS# 7681529 Liquid TMixtur~ AmbRient~E ~ AmbientT~E -~STOICTCONTAINERE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 1356.00 GAL 1356.00 GAL 1356.00 GAL t1AGHKLVUJ 1:V1~lYV1VL'1V7J %Wt. RS CAS# 5.20 Sodium Hypochlorite No 7681529 riAGE~tCL H~Si5~51~1L1V 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH DH / / / Hi ~ Inventory Item 0027 COMMON NAME / CHEMICAL NAME MOPPAC 2 Location within this Facility Unit CTRL WHSE STATE TYPE PRESSURE Liquid TMixture ~ Ambient Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: ... CAS# 141435 TEMPERATURE CONTAINER TYPE Ambient BAG AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 360.00 GAL 360.00 GAL 360.00 GAL ritiGKttL V u 7 ~.vlnrvlV J~,lv 1 a %Wt. RS CAS# 14.90 beta-Aminoethyl Alcohol No 111422 12.30 Butyl Cellosolve No 111762 8.20 Dipropylene Glycol Methyl Ether No 34590948 1.80 Ethyl Alcohol No 64175 t1tiGHiCL Ei~ JJJ.7.71~1t',1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / Hi -4- 01/29/2007 F CLEANSOURCE SiteID: 015-021-000476 ~ ~ Inventory Item 0025 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME ' BIG D LIQUID DEODORANT Days On Site 365 Location within this Facility Unit Map: Grid: --- W WALL N SIDE CAS# 141786 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE "" Liquid TMixture~Ambient ~ Ambient -~STIC CONTAINER ' AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 388.00 GAL 388.00 GAL 388.00 GAL riEiGHKLVUJ 1..V1~lYV1VL'1V1.7 %Wt. RS CAS# 35.00 Dipropylene Glycol Methyl Ether No 34590948 2.90 Ethyl Acetate No 1417$6 8.30 n-Amyl Acetate No 628537 4.30 Aromatic Hydrocarbon No 8030306 1.70 Diethylphthalate No 84562 1ZtiGtiRL tiJ JP~JJI~1J',1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ ~ Curies F IH DH / / / Mod ~ Inventory Item 0029 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME GLASS PAC & 1405 DEPOT PAC Days On Site 365 Location within this Facilit Unit Ma id G -- y p: r : NW BET OFFICE & RESTROOM CAS# 67630 STATE TYPE PRESSURE Liquid TMixtur~ Ambient TEMPERATURE ~ Ambient CONTAINER TYPE BAG AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 360.00 GAL 360.00 GAL .360.00 GAL HAZARD OUS COMPONENTS %Wt• RS CAS# 12.50 Isopropanol No 67530 ~itiG+t1RL L'iJ J ~ J J1.1L' LV 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies IH / / / Mod -5- 01/29/2007 F CLEANSOURCE SiteID: 015-021-000475 ~ ~ Inventory Item 0028 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME -" #1705 DEPOT PAC/5 AIR FRESHENER Days On Site 365 Location within this Facility Unit Map: Grid: CTRL WHSE CAS# 67630 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Liquid TMixtur~ Ambient ~ Ambient BAG AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 150.00 GAL 150.00 GAL 150.00 GAL • riti~r~tt~uu~ ~vi~irulv~lvl~ °&Wt . RS CAS# 7.60 Isopropanol No 67630 til~GY~tCL !-~S~.C;5J1~1L'1V15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MC1 No No No No/ Curies IH / / / Mod ~ Inventory Item 0088 COMMON NAME / CHEMICAL NAME SILICONE LUBE AEROSOL Location within this Facility Unit CTR ' STATE TYPE PRESSURE Liquid TMixture~ Ambient Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map : Grid : --- CAS# 64742-88-7 TEMPERATURE CONTAINER TYPE Ambient DRUM/BARREL-METALLI~ AMOUNTS AT THIS LOCATION Largest Con84i0ne0rG~ Daily M84100m GAL I Daily A84r00e GAL nl"l~ll"~~VUA7 L.U lYlr UlV lillV 11.7. %Wt. RS CAS# 95.00 Mineral Spirits No 8030306 riHGHKL Ei517~.7.71~1tS1V 1 7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCA? No No No No/ Curies F / / / Mod -6- O1/29/~007 l F CLEANSOURCE SiteID: 015-021-000476 ~ ~ Inventory Item 0085 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME BORAX HAND SOAP Days On Site 365 Location within this Facility Unit Map: Grid: -- CTR WHSE CAS# 1330434 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Solid TMixture ~ Ambient ~ Ambient BOX AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 1450.00 LBS 1450.00 LBS 1450.00 LBS IlEiGt?iCLVU.7 1..V1~lYV1V GIV 1.7 %Wt. RS CAS# 100.00 Sodium Borate No 133034 I11"1GK[CL Ei. 7.7~.7.7P7~1V1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCA? No No No No/ Curies / / / Low ~ Inventory Item 0058 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME COMET CLEANSER Days On Site 365 Location within this Facility Unit Map: Grid: CTR WHSE CAS# 7722-88-5 ~SolidE TMixtur~AmbRent~E ~ AmbientT~E -~STIOCTCONTAINERE AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 945.00 LBS 945.00 LBS 945.00 LBS HAZARDOUS COMPONENTS %Wt. RS CAS# 5.00 Tetrasodium Pyrophosphate No 7722$5 HAZARD ASSESSMENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MAP No No No No/ Curies I DH / / / Low -7- 01/29/2607 F CLEANSOURCE SiteID: 015-021-000475 ~ ~ Inventory Item 0063 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME CHEM CHOR LOW SUDS DETERGENT Days On Site 365 Location within this Facility Unit Map: Grid: - s WALL cAS# - ~SolidE TMixtur~Ambient~E ~ AmbientTURE BOX CONTAINER TYPE AMOUNTS AT THIS LOCATION "" Largest Container Daily Maximum Daily Average 400.00 LBS 400.00 LBS 400.00 LBS HAZARDOUS COMPONENTS owt. Rs cAS# Sodium Carbonate No 497138 Sodium Sesquicarbonate No 533960 Sodium Sulfate No 7757826 Sodium Metasilicate No 6834920 l1t~LiFiiCL ti. 7 J ~ J ~71"1P.~1V 1 J TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Ldvv ~ Inventory Item 0092 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME CONCRETE CLEANER Days On Site 365 Location within this Facility Unit Map: Grid: -- N WALL CAS# 6834-92-0 STATE T TYPE ~- PRESSURE TEMPERATURE ~~ CONTAINER TYPE ...... Solid I Mixture I Ambient ~ Amhi ent I l7RTTM/R~RRFT,-TTCIRTMRT~r. I AMOUNTS AT THIS LOCATION Largest Container Daily Maximum I Daily Average 200.00 LBS 200.00 LBS - 200.00 LBS rae~uracu~vv.~ ~.vrlrv1v1;1v 1 S cwt. Rs cAS# 100.00 Sodium Metasilicate No 6834920 r1t~LitiRL tiJ w7 L' J.71.1L'1V 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCF No No No No/ Curies IH DH / / / Lr~vu -8- O1/29/2n07 r, F CLEANSOURCE SiteID: 015-021-0004"76 ~ ~ Inventory Item 0046 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME PORTABLE TOILET ADDITIVE Days On Site 365 Location within this Facility Unit Map: Grid: S WALL CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE "" Liquid Mixture Ambient Ambient DRUM/BARREL-NONMETAL AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 182.00 GAL 182.00 GAL 182.00 GAL - nti~tucLUU~ ~.vlnruiv~ivl~ oWt. - RS CAS# 5.00 Dimethyl Benzyl Ammonium Chloride No~ 0 1.00 Nonylphenoxypolyethyleneoxyethanol No 26027383 tiHGKKL 1~55L' .>5i~1r,1V 15 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies R IH / / / Lwu ~ Inventory Item 0038 COMMON NAME / CHEMICAL NAME CLEAN SWEEP Location within this Facility Unit S WALL STATE TYPE PRESSURE Solid TMixture ~ Ambient Facility Unit: Fixed Containers on Site ~ Days On Site 365 Map: Grid: CAS# TEMPERATURE CONTAINER TYPE Ambient BAG AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 5250.00 LBS 5250.00 LBS 5250.00 LBS nE,c~t~cLUUa wl~irulv~ivl~ ~SWt. RS CAS# 20.00 Paraffin Solids No 8002742 80.00 Sand No 7631869 rs.~,~ruc1J yi ~ara~l~lr~lvl~ TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F DH / / / Mi -9- 01/29/~n07 F CLEANSOURCE SiteID: 015-021-000475 ~ ~ Inventory Item 0069 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME GO JO #9152 SPA BATH Days On Site 365 Location within this Facility Unit Map: Grid: N WALL CAS# 00151213 STATE T TYPE ~~ PRESSURE TEMPERATURE ~~ CONTAINER TYPE Solid I Mixture I Ambient ~ Ambient i PLASTIC CONTAINER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 25.00 LBS 25.00 LBS 25.00 LBS %Wt. RSA CAS# t1HGL-1ttL AJ,`SL"i551~1L"1V1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MC$ No No No No/ Curies IH / / / Ui~: HAZARDOUS COMPONENTS -10- 01/29/2007 F CLEANSOURCE SiteID: 015-021-000476 ~ Fast Format ~ ~ Notif./Evacuation/Medical Overall Site ~ ~ Agency Notification 10/22/1992 ~ EMPLOYEES ARE TO NOTIFY MANAGEMENT OF ALL SPILLS IMMEDIATELY. FIRE DEPARTMENT TO BE NOTIFIED IF ANY HAZARDOUS MATERIAL IS SPILLED CALL 911. ALL PERSONNEL ARE TO EVACUATE THE BUILDING IN THE EVENT OF LARGE SPILL Employee Notif./Evacuation 08/23/20176 IN THE EVENT OF LARGE SPILL, EMPLOYEES ARE TO IMMEDIATELY EVACUATE THE BUILDING TO DESIGNATED EVACUATION AREA LOCATED DIRECTLY ACROSS PARKING LOT IN FRONT OF BUILDING AT 6901 DISTRICT BLVD. Public Notif./Evacuation 08/23/2006 IN THE EVENT THAT THERE IS A CUSTOMER PRESENT AT TIME OF SPILL, CUSTOMER WILL BE NOTIFIED AND PROCEED WITH EMPLOYEES TO DESIGNATED EVACUATION AREA A't' 6901 DISTRICT BLVD, FRONT OF BUILDING DIRECTLY ACROSS PARKING LOT. Emergency Medical Plan 08/23/2006 SOUTHWEST URGENT CARE CENTER, 5397 TRUXTUN AVE -11- 01/29/2007 F CLEANSOURCE SiteID: 015-021-000475 ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall Site ~ ~ Release Prevention 08/23/2006 ~ ALL PRODUCTS, WHERE PRACTICAL, ARE KEPT IN ORIGINAL CARDBOARD SHIPPING CONTAINERS. PAILS AND DRUMS OF PRODUCTS ARE KEPT PALLETIZED, IF POSSIBLE. CLEANSOURCE DOES NOT RE-PACKAGE OR RE-BOTTLE OR MANUFACTURE ANY CHEMICAL AT' OUR WAREHOUSE FACILITY. Release Containment 08/23/2005 SACKS OF ABSORBENT MATERIAL ARE MAINTAINED ON PREMISES AT ALL TIMES TO SOAK UP ANY SPILLS. CLEANSOURCE ALSO MAINTAINS ON PREMISES AT ALL TIMES EMPTY PLASTIC CONTAINERS TO HOLD MATERIAL THAT HAS BEEN SOAKED UP. PRODUCTS CONTAINING ACID OR ACID BASE ARE STORED IN SEPARATE AREA FROM ALKALI BASED PRODUCTS. ALL ACID BASED PRODUCTS ARE KEPT IN ORIGINAL CONTAINERS AND BOXED. THESE CARTONS ARE THEN PLACED IN LARGE LEAK PROOF METAL PANS THAT ARE LARGE ENOUGH TO CONTAIN ANY SPILL.. Clean Up 08/23/2006 CLEAN-UP PERSONNEL WILL BE PROVIDED WITH ALL NECESSARY CLOTHING AND EQUIPMENT FOR THEIR PERSONAL PROTECTION. ABSORBENT MATERIAL WILL BE SPREAD ON SPILL. MATERIAL WILL BE SHOVELED INTO PLASTIC CONTAINERS. MATERIAL TO BE TAKEN TO HAZARDOUS MATERIAL DISPOSAL SITE. V1.11C 1. iCC .TV UI C:C HGl.1Vdl.1 Vi1 -12- 01/29/2007 ~~ - . -:. ~; F CLEANSOURCE SiteID: 015-021-000475 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ special riazaras Utility Shut-Offs 01/29/200'7 A) GAS - NONE B) ELECTRICAL - NEXT TO FRONT DOOR OF CLEANSOURCE SHOWROOM C) WATER - MASTER SHUT-OFF AT PARKWAY IN FRONT OF COMPLEX; NO SHUT-OFF FOR WATER IN CLEANSOURCE PORTION OF BLDG D) SPECIAL - FIRE ALARM AND SPRINKLER SHUT-OFF CTR PORTION OF BLDG E) LOCK BOX - LOCK BOX PLACED ON BLDG Fire Protec./Avail. Water 01/29/200'7 PRIVATE FIRE PROTECTION - SPRINKLERS WITH FIRE DEPT CONNECTION FOR PUMP HOOK-UP. THIS FACILITY HAS AUTOMATIC FIRE FANS FOR SMOKE EVACUATION. FIRE EXTINGUISHERS. FIRE HYDRANT- DISTRICT BLVD FRONT OF COMPLEX Building Occupancy Level 03/10/2005 hf ~hi~f 5_ n i g-- ~v~ vV~~h.c~u5-e- (~ ~12uc~ X12.1 v ~S ~ Dr~-y Vti/a~eh~ us-e. 5 p~t:ic~ ~,e5 ~~s ~ _5_~rn- "7~m rl:3o ~rn - -~[ P~'Yl ~~.3~ ~m - ~ Pn'1 Cl QYId Ou.~' CLut'~ rl 9 -13- 01/29/2007 ~' (`~_; r. .~ F CLEANSOURCE SiteID: 015-021-000476 ~ Fast Format ~ ~ Training Overall Site ~ ~ Employee Training 08/23/20(75 ~ MATERIAL SAFETY DATA SHEETS ON FILE BRIEF SUMMARY OF TRAINING PROGRAM: EMPLOYEES ARE INSTRUCTED TO USE PROTECTIVE GLOVES, MASKS, AND CLOTHING AROUND ANY HAZARDOUS MATERIAL ACCIDENTALLY OPENED CONTAINER. EMPLOYEES ARE MADE AWARE OF EVACUATION AREA IN THE EVENT OF LARGE SPILL, ETC. SAFETY MEETINGS. HELD AT REGULAR INTERVALS, WRITTEN MATERIAL DISPENSED AS NECESSARY, WRITTEN SAFETY PRECAUTIONS ON WEEKLY BASIS. rage n~lu iui ruuui~ use iaciu ivi t-u~.utc vac -14- Ol/29/~007 ~c Aisle 6 Aisle 5 Aisle 4 Aisle 3 Aisle 2 Aisle 1 Aisle 00 AN Aisle 6 Aisle 5 Aisle 4 Aisle 3 Aisle 2 Aisle 1 '~' S ~~ R~"',~, ~_ R 04~ (~15~~ d~ ~~ ~~~ ~~` ~~ ~~ n1 f 1`715TFZ1 CT' ~~vD ~'~ ~AK~IZSF~Lp CA .~~'~ ~~~ Product j Product Name Status ! EDI Code! UOM Bin Loc j Vendor.I Vendor Nme Vend Prod On Hand 020020 CLEANER BOWL GERMICIDAL S HM CS 0 10 bl 190188 SPARTAN CHEMICA 7102 ALT 20.34 020080 CLEANER BOWL SPARCLING S HM CS 02 13 bi 190188 SPARTAN CHEMICA 7108 ATL 20.91 020146 CLEANER BOWL NABC CONC S HM CS 02 11/A3 190188 SPARTAN CHEMICA 4716 19.75 020327 CLEANER PEROXIDE GE S HM CS 03 07 c2 20143 BEfCO 33647 1.25 040102 POOL-CHLOR ULTRA CLEAN o HM DR NO NS 220010 VALUE PRODUCTS 601-015 0.00 070191 CLEANSER CREME 5 HM CS 09 06 Di 130005 3M NM8612 34763 8.00 073215 DESTAINER ULTRA CLEAN S HM DR 00 28 220010 VALUE PRODUCTS 25-50-1-2305CL5 8.00 078005 BOOSTER ULTRA CLEAN S HM PL Ol 14 c3 220010 VALUE PRODUCTS 20-50-1-2307CLS 10.00 079005 DETERG DISH ULTRA CLEAN 5 HM PL 01 14 A4 220010 VALUE PRODUCTS 20-60-1-21000L5 5.00 090109 DEOD OCEAN BREEZE S HM CS 03 07 c6 20143 BETCO 23147 16.00 090124 DISINF DEOD DETERG AF315 S HM CS 03 07 b6 20143 BETCO 31547 2.25 090230 DEOD OCEAN BREEZE O HM CS NO NS K 20143 BETCO 23112 0.00 100060 DEGRSR BUTYL SC200 S HM GL 02 10 A6 190188 SPARTAN CHEMICA 2200 34.00 110231 CLEANER SURE BET FOAMING S HM CS 03 07 b4 20143 BETCO 32404 12.25 140141 STRIPPER FLOOR EXTREME S HM CS 03 03 Al 20143 BETCO 18404 167.00 140144 STRIPPER FLOOR EXTREME S HM PL 09 06 a1 20143 BETCO 18405 14.00 140181 CLEANER PH7 ULTRA S HM CS 03 03 B2 20143 BETCO 17847 9.00 145810 STRIPPER BOOR L.O.E. S HM PL 02 03 A5 190188 SPARTAN CHEMICA 0061 10.00 148150 STRIPPER FLOOR C2 815 S HM CS 02 02 Al 60060 R.0 KEM PRODUCT C2L 815 STRIPPER 17.50 148151 STRIPPER FLOOR C2 815 S HM CS 0 08 a2 60060 FLO KEM PRODUCT C2L 815 STRIPPER 48.00 160144 DEGRSR CITRUS CHISEL S HM CS 03 05 Al 20143 BETCO 16704 63.00 160148 DEGRSR CITRUS CHISEL 5 HM CS 03 O1 64 / 20143 BETCO 16747 11.25 170199 CLEANER GLASS CLE IMAGE S HM CS 03 05 C3 20143 BETCO 19947 10.50 227015 CLEANER 2L HD MULTI SURF S HM CS 05 O1 b3 130005 3M NM8612 19202 16.65 227025 CLEANER 4L BATHROOM S HM CS 05 09 El 130005 3M NM8612 19204 3.82 227030 CLEANER 5L UAT S HM CS 05 09 d1 130005 3M NM8612 23218 7.00 227075 CLEANER' 111 BONNET S HM CS 05 09 e6 130005 3M NM8612 25981 11.00 227080 CLEANER 13L FRESH DEOD S HM CS 05 11 d5 130005 3M NM8612 20121 5.49 227085 CLEANER 12L COUNTRY DAY S HM CS 05 11 d2 130005 3M NM8612 20119 12.00 227090 CLEANER 14L MTN SPICE S HM CS 05 0 a2 130005 3M NM8612 20120 10.00 227105 CLEANER 24H FLOOR 3IN 1 S HM CS 05 03 c6 130005 3M NM8612 23553 24.00 227110 STRIPPER 22H LO FLOOR 5 HM CS 05 O1 c5 130005 3M NM8612 23555 4.00 227225 CLEANER 25L HB AT DISI 5 HM CS 05/03 c3 130005 3M NM8612 23551 6.83 227227 CLEANER 25H HB UAT DISI S HM CS 05 03 ci 130005 3M NM8612 23550 6.67 240108 DETERG Mad DUAL ACID S HM CS 03 07 Bi 20143 BETCO 13504 5.50 243015 ULTRA CLEAN SOFT SOUR S HM DR 00 28 220010 VALUE PRODUCTS 25-50-1-2318CLS 3.00 243515 DETERG LAUNDRY ULTRA S HM DR 00 28 220010 VALUE PRODUCTS 25-50-3-2312CLS 8.00 350899 COMPOUND POLISH MARBLE S HM PL 06 05 a2 220030 ECOLAB 62725211 7.00 025225 CLEANER PORCELAIN TILE S HM CS O1 10 64 70030 GENLABS 2074 PRIVATE LABEL 15.33 060129 CLEANER CARPET ES STEAM O HM CS NO NS K 20143 BETCO 40204 0.00 060138 CLEANER CARPET PRE-SPRAY S HM CS 03 07 D2 20143 BETCO 40604 10.00 070120 DRAIN MAINT NEW PUSH 5 HM CS 09 O1 bl 20143 BETCO 13312 36.00 070177 CLEANER OVEN & GRILL S HM - GL 01 04 BS 70030 GENLABS 2057 PRIVATE LABEL 64.00 090147 DEOD AERO SNAPPY APPLE S HM CS 07 13 F4 3016fi CLAIRE MANUFACT CP161CLEAN P L 70.08 100180 CLEANER INSPECTORS CHOIC S HM GL 02 05 d4 190188 SPARTAN CHEMICA 3045 15.00 100380 DEGRSR NON BUTYL SN6130 S HM I 02 O1 b2 190188 SPARTAN CHEMICA 2130 27.00 Page 1 of 3 _- y, Product Product Name Status EDI Code ` UOM Bin Loc Vendor. Vendor Nme Vend Prod On Hand 110160 ALCOHOL 70% ISOPROPYL 5 HM GL 01 NNE L 301660 CHEMCOR CHEMICA CL17110160 38.00 140129 STRIPPER AX IT PLUS HDTV s HM CS 03 09 B4 20143 BETCO 15404 13.00 140132 AX II PLUS HDTY 5 HM PL 03 09 Ai 20143 BETCO 15405 8.00 141010 SEALER FLR C2 1010 0 HM PL no ns sto ck 60060 FLO KEM PRODUCT C2L1010 2 2.5GL P L 0.00 141160 SCRUBS HAND WIPE SANITIZ 5 HM CS 05 09 c4 120035 LAGASSE BROTHER DYM 90985 3.00 141250 FINISH FLR C2 1250 SUPER 0 HM PL NO NS K 60060 FLO KEM PRODUCT 1250 5G PL 0.00 145560 STRIPPER FLOOR EMULSIFIR 0 HM PL 02 O1 A4 190188 SPARTAN CHEMICA 0084 0.00 160020 DRAIN OPENER BLOCAID S HM CS 0 09 C3 190188 SPARTAN CHEMICA 7380 7.00 160139 CLEANER TOP FLITE DETERG 0 HM CS no ns toc k 20143 BETCO 15047 0.00 160150 DEGRSR CITRUS CHISEL DR 0 HM DR 00 28 20143 BETCO 16755 0.00 190121 DISINF DEOD DETERG AF315 S HM CS 03 03 Ci 20143 BET'CO 31537 6.00 226120 COATING FLOOR TOPLINE S HM CS 06 02 62 130005 3M NM8612 23762 10.00 227035 CLEANER 5H UAT DISINF S HM CS 05 06 c2 130005 3M NM8612 23219 3.00 227065 CLEANER 9H CARPET EXTRAC 0 HM CS no/ns toc k 130005 3M NM8612 20779 0.00 227070 CLEANER 10H CARPET PRE 0 HM CS NO NS K 130005 3M NM8612 19214 0.00 227115 CLEANER 23H UAT DISINF S HM CS 05 O1 c3 130005 3M NM8612 23552 2.68 243205 DESTAINER ULTRA CLEAN S HM PL 01/14 A6 220010 VALUE PRODUCTS 20-50-1-2305CLS 3.00 430105 DEGRSR ULTRA 2000 HDTV S HM CS 03 09 Bi 20143 BETCO 13604 27.00 430115 DEGRSR ULTRA 2000 5 HM DR 00 28 20143 BETCO 13655 1.00 025100 CLEANER PORCELAIN TILE S HM GL 01 08 Cl 70030 GENLABS 2074 PRIVATE (ABEL 32.00 100200 CLEANR INSPECTORS CHOICE 5 HM PL 02 05 A4 190188 SPARTAN CHEMICA 3045 3.00 141211 CLEANER C2 TILEMASTER 5 HM CS 02 08 Bi 60060 FLO KEM PRODUCT C2L210 4 1 13.75 143558 FINISH FLR SPANGLE 0 HM CS NO NS K 130005 3M NM8612 23558 0.00 160268 DEGRSR CITRUS CHISEL 0 HM CS 03 05 C5 20143 BETCO 16737 0.00 227228 CLEANER EXTRACTION 27H S HM CS 05 04 d4 130005 3M NM8612 34857 1.00 243005 ULTRA CLEAN SOFT SOUR S HM PL 01 14 c2 220010 VALUE PR0DUCT5 20-50-1-2318CLS 4.00 420144 SOAP SPA BATH 8< BODY S HM GL 05 07 d7 70095 GO-~0 INDUSTRIE 9155-04 4.00 020060 CLEANER BOWL M95 S HM CS 0 09 c5 190188 SPARTAN CHEMICA 7105 ALT 2.75 079001 DEIERG DISH ULTRA CLEAN S HM CS 01 14 65 220010 VALUE PRODUCTS 389-041 1.00 100080 DEGRSR BUM SC200 0 HM PL no ns toc k 190188 SPARTAN CHEMICA 2200 1.00 100460 DEGRSR ORANGE TOUGH 15 S HM CS 0 09 C3 190188 SPARTAN CHEMICA 2216 1.49 101198 DEGRSR VELOCITY CONC 0 HM CS NO NS K 20143 BETCO 19737 0.00 110228 DISINF FOREST 5 CLEANER 5 HM CS 03 13 C2 20143 BETCO 30712 48.00 140149 STRIPPER EXTREME ULTRA S HM CS 09 06 D5 20143 BETCO 19412 12.00 141400 CLEANER NEUTRAL C2 400 S HM CS 0 06 bl 60060 FLO KEM PRODUCT C2L400 2 2.5 3.25 160108 DEGRSR SUPER KEMITE 0 HM CS no ns otc k 20143 BETCO 10304 0.00 060144 CLEANER CARPET SPOTTER S HM CS 03 07 Di 20143 BETCO 41904 5.00 060732 CLEANER C2 CleanScrub HD o HM CS no ns toc k 60060 FLO KEM PRODUCT C2L0735 0.00 070105 DEGRSR FOAM SPRAY 0 HM CS NO NS C K 20143 BETCO 12604 0.00 226010 FINISH FLR UHS STELLAR S HM CS OS 01 D4 130005 3M NM8612 23563 5.00 020151 CLEANER NON ACID AF79 0 HM CS 03 05 C7 20143 BETCO 33137 0.00 074025 DEIERG ULTRA-CLEAN DISH 0 HM CS NO NS K 50094 ESSENTIAL INDUS 6139 PRIVATE LABEL 0.00 160107 CLNR AC114 ACID DELIMER 0 HM CS NO NS C K 20143 BETCO 11404 0.00 350907 PRE POLISH CERAMIC CTP1 0 HM PL NO NS K 220030 ECOLAB 62725603 0.00 090125 DISINF DEOD DETERG AF315 0 HM CS NO NS K 20143 BETCO 31512 0.00 145815 REMOVER FINISH FLR 0 HM PL NO NS K 190188 SPARTAN CHEMICA 3505 0.00 Page 2 of 3 ~" Rroduct (Product Name 'Status +EDI Code ~UOM 'Bin Loc ; Vendor. 'Vendor Nme (Vend Prod IOn Hand 160269 CLEANER DEEP BLUE GLASS O HM CS 03 03/c7 20143 BETCO 18143 0.00 190116 CLEANER SURE BET FOAMING 0 HM CS no ns k 20143 BETCO 32437 0.00 02445 DEOD AERO SMOKE ELIMINAT 0 HM CS NO NS K 120035 LAGASSE BROTHER DRK 94787 0.00 140111 CLEANER TILE FOAMING O HM CS NO NS K 20143 BETCO 11904 0.00 141500 CLEANER FLOOR C2 500 S HM CS 02 06 b2 60060 FLO KEM PRODUCT C2L 500 CLEANER 5.00 160183 REMOVER MILDEW BTB O HM CS no ns toc k 20143 BETCO 32112 0.00 070115 CLEANER DEEP FREEZE O HM CS NO NS K 20143 BETCO 13204 0.00 140142 CLEANER DAILY FLOOR GE S HM CS 09 06 B3 20143 BETCO 53647 1.00 141490 DEGRSR C2 AP490 CONC 0 HM CS no ns bock 60060 FLO KEM PRODUCT C2L490 2.5 0.00 160142 DEGRSR NATURAL FASTDRAW S HM CS 09 07 B4 20143 BETCO 21747 1.00 170197 CLEANER GLASS GE S HM CS 09 07 65 20143 BETCO 53547 1.00 160117 DEGRSR l1 UID CHISEL 0 HM CS NO NS /K 20143 BETCO 12704 0.00 090108 DEOD LEMON BEST SCENT 0 HM CS NO NS K 20143 BETCO 22612 0.00 141350 DEGRSR C2 HORSEPOWER 0 HM CS no ns toc k 60060 FLO KEM PRODUCT C2L350 2.5 0.00 170108 CLEANER DEEP BLUE RTU T O HM CS 09 Ol 82 20143 BETCO 10812 0.00 227125 CLEANER 52L TILE GROUT S HM CS 09 06 D6 130005 3M NM8612 26323 12.00 070108 DEGRSR FOAM SPRAY O HM PL NO/NS K 20143 BETCO 12605 0.00 070123 CLEANER OVEN JELL 0 HM CS NO NS K 20143 BETCO 13904 0.00 073081 CLEANER FOAMING ACID FP 0 HM PL no ns toc k 190188 SPARTAN CHEMICA 3081 0.00 100189 DEGRSR VELOCITY RTU NON 0 HM CS no ns toc k 20143 BETCO 18912 0.00 140067 STRIPPER EnduraSTRIP 0 HM CS no ns toc k 190188 SPARTAN CHEMICA 0067 0.00 160138 CLEANER TOP FLITS DETERG 0 HM DR NO N5 K 20143 BETCO 15055 0.00 160147 DEGRSR CITRUS CHISEL PL O HM PL NO N5 /K 20143 BETCO 16705 0.00 160165 DEGRSR CITRUSOLV CONC 0 HM CS NO NS K 20143 BETCO 20918 0.00 160263 CLEANER TOP FLUE HI PER 0 HM CS no ns c k 20143 BETCO 15043 0.00 170120 CLEANER DEEP BLUE CONC 0 HM CS NO NS K 20143 BETCO 28112 0.00 170200 CLEANER WINDOW CONC 0 HM GL 0 03 D6 190188 SPARTAN CHEMICA 3060 10.00 190113 DISINF 256 CLEANER 0 HM CS NO NS K 20143 BETCO 30643 0.00 226020 FINISH FLR CORNERSTONE O HM CS N ED BIN 130005 3M NM8612 25928 0.00 226060 STRIPPER FLOOR RINSE FRE 0 HM CS NO NS K 130005 3M NM8612 08778 0.00 227050 DEGRSR 7H FOOD SERVICE 0 HM CS no ns toc k 130005 3M NM8612 23346 0.00 227229 PRETREATMENT CARPET 28H 0 HM CS no ns toc k 130005 3M NM8612 34859 0.00 245041 DELIMfR ULTRA CLEAN 0 HM CS ne ed tob/in 220010 VALUE PRODUCTS 495041 0.00 350906 POLISH CERAMIC TILE CTP2 0 HM PL O6 05 A2 / 220030 ECOLAB 62725608 0.00 350909 COMPOUND POLISH MARBLE 0 HM PL NO NS K 220030 ECOLAB 62725212 0.00 Page 3 of 3 ~, Clean: ource .q .... THE CLEANING SUPRU;Y EXPERTS Trade Name: Multi Chior Chemical Family: Inorganic halogen compound rc # Material Safety Data Sheet (Prepared According to 29 CFR 1910, 1200) ULTRA-CLEAN DES~'AIl~TER Product Type: Formula: Boiling Point: 212°F Decomposes Specitic Gravity (H2O=1.0) 1.12-1.15 (±0.0005) pH: 11.0 L+OS) Vapor Pressure (mmg Hg.): I2.I mmHg @ 20°C (68°F) Vapor Density (AIR=I) NA Solubility In Water: Complete Evaporation Rate: Unknown Appearance and Odor: Clear, straw yellow liquid: Chlorine odor. Flash Point (T.C.C.): NA Upper Flammable Limits: NA Lower Flammable Limit: NA Fire Extinguishing Media: Not Combustible. Water Spray, dry chemical, Cot or foam may be used in areas where product is stored. Special Fire Fighting Procedures: Keep away from organic material. \ Unusual Fire and Explosion: None Stability: Stable Incompatibility (Materials to Avoid): Strong acids Hazardous Decomposltion~Products: Chlorine gas, hypochlorous acid. Hazardous Polymerization: Will Not Occur. Conditions to Avoid: Strong acids, ammonia, organic materials, elevated temperatures. Primary Routes of Exposure: Eyes, Skin, Inhalation & Ingestion Signs and Symptoms of Over-Exposure (Chronic): May be irritating to eyes and skin with some individuals. Signs and Symptoms ofOver-Exposure (Acute): May be irritating to eyes and skin with some individuals. Nausea if swallowed. Medical Conditions Aggravated by Over-Exposure:.Unknown Carcinogen or Suspect Carcinogen Ingredients: None Eyes: Flush with water for l5 minutes, while holding eyelids open. Contact a physician. Skin: Wash with water. Remove any contaminated clothing. Ingestion: Drink large quantities of water or milk. DO NOT induce vomiting. Get medical attention. Inhalation: Remove victim to fresh air. Respiratory Protection: None Ventilation Requirements: None. Protective Equiproent: Rubber Gloves & Safety Goggles. Other Protective Clothing: NA Steps to be Taken if Released or Spilled: Flood area where spill has occurred with large quantities of water. Waste Disposal Methods: Diluted product may be flushed into sanitary sewer system. Product may also be absorbed with sand or diatomaceous earth. Absorbed products must be disposed of in accordance with applicable Federal, State, and/or local regulations. Precautions to be Taken in Handling and Storage: Observe personal hygiene. Keep container closed when not in use. Store thisproduct in a cool, dry area, enz,utnw.nNe keep away from heat, light and flame to avoid deterioration. ~~ ^" o m 7-Modenw 2 0 ~' ~eLLm s°au. Date Prepared: ilnenool DISTRIBUTOR'S NAME: EMERGENCY TELEPHONE NUMBER: ~QD~ o„(~,__ J Clean Source 1-800-535-5053 1711 Rogers Avenue NUMBER FOR INFORMATION: j y~D ~L San Jose, CA 95112 I-800-436-1907 7 Clea~.so,;tc~ ~ IRy'3®~~ Material Safety Data Sheet (Prepared Arcordlnx l0 291;FR 1910. 1100) _. ... i i' J ~~J~rlr~~'/~~~±~ ~o~ ~31d_I.5 LD G ~k?7 0~ ~ifl15~-E l3lN 0~l_~8 I~SG~- I:I 1. ProdacCldeutlficadoa: ;.. MSDS q: 643 Trade Name: Soft/Sour (498) Product Type: Liquid SotYner/Sour Chemical Family: NA Formula: Mixture DISTRIBUTOR'S NAME: Clean Source 171 I Rogers Avenue San Jose, CA 95112 EMERGENCY TELEPHONE NUMBER: 1-800-535-5053 NUMBER FOR INFORMATION: t-800-436-1907 2. Haz~rdoua Ingredients:.::.; _ , 3. Physical Data:. Boiling Point: About 212°F Specific Gravity (H2O=1.0) 1.01 (±0.0005) pH: 2.0 L+OS) Vapor Pressure (mmg Hg.): Less than 1 Vapor Density (AIR=I) Less than 0.1 Solubility In Water: Complete Evaporation Rate: About the same Appearance and Odor: Yellow, semi-opaque Liquid, citrus odor. 4. Fire and Exp16s1oo Hazard Data:. , . Flash Point (T.C.C.): None to Boiling Upper Flammable Limits: NA Lower Flammable Limit: NA Fire Extinguishing Media: NA Special Fire Fighting Procedures: None Unusual Fire and Explosion: None _ .. S. Reactive DatA:. . Stability: Stabie Incompatibility (Materials to Avoid): Certain Metals. Hazardous Decomposition Products: Hydrogen gas upon contact with certain metals. 6. Healtd Hazai'dgi Threshold Limit Value-Product See Section 2 for Ingredients TLV: None Established Primary Routes of Exposure: Eyes, Skin ,Oral and Inhalation. Signs and Symptoms ofOver-Exposure (Chronic): Burning and wmeal damage to eyes. May cause burning and severe irritation to skin. Nausea and vomiting, if swallowed. Signs and Symptoms ofOver-Exposure (Acute): May cause brans to skin and eyes. Extremely irritating to mouth, if swallowed. Medicai Conditions Aggravated by Over-Exposure: Open sores, eye and skin allergies. Carcinogen or Suspect Carcinogen Ingredients: None 7. Emergcucy and First. A1d Proceduresi ., ` , ;. '. ;', ,.: Eyes: Flush with plenty of water for 15 minutes. Skin: Flush with plenty of water for I S minutes. Remove contaminated clothing. Ingestion: Give large quantities of water to dilute. DO NOT induce vomiting. Get medical attention. Inhalation: Remove to fresh air. 8. Special Protection Information:.. Respiratory Protection: Normal ventilation, NIOSH approved respirator ifTLV is exceeded. Ventilation Requirements: Local Exhaust. Protective Equipment: Rubber Gloves & Safety Goggles, Other Protective Clothing: None 9. Spil(or Leak Procedures: Steps to be Taken if Released or Spilled: Neutralize with mild alkali such as baking soda. Waste Disposal Methods: Sewer to water. Check all governmental regulations. 10. Storage and Handling Information: Precautions to be Taken in Handling and Storage: Keep from freezing. Keep out of reach of children. e~~ao aA~o ~~en.eap ... o r~~~ m x~rroaema ~ o i•sud. ~.,,~,~ o 0.4dpdtlCen .~,. Date Prepared: 11!29/2001 Clsrc # 243515 I Clean;'~ource 7nde1(fame~eterg''en'f (g88) , CAemlc~l Family: Liquid Laundrybetergent DISTRIBUTOR'S NaMF Clean Source 1711 Rogers Avenue San Jose-, eA 95112 Material Safety Data Shee (Prrpvrd Accordant 1° 29 CFR 1910. 1200) C 'L 7'I~. f ~ C'I f~~. t . ~ t LDC~T I DN ~}I SC.~" 8_//V ~i~.~~~ W ~U GL Product Typr: Non-bunt surfactant Formula: Proprietary F-.MERGENCY'fFLFPHONH NUMBF.N I-800-535-5053 NUMBER FUR INFUKMA'I IUN: I-800-436-1907 9oiliag Point: 212°F Specific Gravity (HZOn1.0) 1.042 (0.0005) pll: 9-10 (±OS) Vapor Pressure (mmg lag.): Unknown Vapor Dcnsiry (AIR=t) NA Solubility fn Water: Complete Ertporation Rate: Unknown Appearance and Odor: Clear, bloc viscous liquid, citrus odor. FIuY Polat (f.C.C.): None to Boiling Upper Flammable Limits: NA Lower Flammable Limit: NA FiK ExNagulshing Media: NA Special Fire Fighting Procedures: None Unusual Fire and Explosion: None Shblliry: Stable lncompatiblliry (Materials to Avoid): None Ffa>,rdous Decomposition Product: None lutown 71reaYold Limit Value-Product See Section 2 for Ingredients TLV: Not Applicable Prioary Routes of Exposure: Eyes and Skin Signs and Symptoms of Over-Exposure (Chronic): Unknown Slgw and Symptoms of Over-Exposure (Acute): Causes irritation to the. eyes and skin; damage with prolonged exposure, Nausea if:wallowed. Medial Conditions Aggravated by Over-Exposure: Unknown Carcinogen or Suspect Carcinogen Ingredients: None Eyes: Flesh with water for 15 minutes, while holding eyelids open. Contact a physician. Skin: Wash with water. Remove any contaminated clothing. [aiatioo: Drink large quantities of water to dilute. DO NOT induce vomiting. Get medical attention. Inhalation: Remove victim to fresh air. ' Raplntory Prottxtion: None Ventilstloo Requirement: None. ' lrroteetfve Equipment: lmpcrvious Rubber Gloves & Safcry Goggles. Other Protective Clothing: Rubber Apron end Boots i to be Taken if Relnsed or Spitted: Mop up, rinse with water. Waste Disposal Methods: Flush into sanitary sewer system. irtions to br Takes in Handling and Storage: Observe personal hygiene. container closed when not in use. Kccp away from heat and flame. N~z~eo a~nnc .~...~. ,.. 9 ~~~ 2~~ t o ~.y,~ .~,. f r. ~aC/~T BAN ~~ s~ ~~~~g~ .~ Clsrc # 43.Q1.0.5 5'S~t~ Material Safety Data Sheet WHMIS (Pictograms) WHMIS (( WHMIS CLASS E: Corrosive liquid. Y Section 1. Chemical Product and Company Identification Product Name/ Trade Ultra 2000 name Synonym Super Double Strength Degreaser Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Oh 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS HCS .HCS CLASS: Corrosive liquid. Code 136 CAS # Not applicable. Validation Date 8/11/2003 Print Date 8/13/2003 In case or Chemtrec (800) 424-9300 Emereencv Protective Clothing ~~ Section 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCs,JLDs° Weight 1) Water 7732-18-5 60-70 Not available. Not available. 2) 2-Butoxyethanol 111-76-2 5-10 TWA: 20 (ppm) from ORAL (LD50): Acute: 1746 ACGIH (TLV) [United mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States) 3) Potassium Metasilicate 1312-76-1 5-10 Not available. Not available. 4) Sodium Xylene Sulfonate 1300-72-7 5-10 Not available. ORAL (LD50): Acute: 650 mg/kg [Rat]. 5939 mg/kg [Mouse]. 5) Tetrasodium salt of 64-02-8 <2 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg [Rat]. 6) Sodium Orfhosilicate 13472-30-5 0-5 Not available. Not available. 7) Potassium Hydroxide 1310-58-3 0-5 Not available. Not available. 8) Anionic Surfactant 25155-30-0 0-5 Not available. Not available. 9) Nonionic Surfactant 90165-9 <2 Not available. Not available. 10) Perfume Oil 100-52-7 <1 Not available. Not available. 11) Dye N/A <1 Not available. Not available. Section 3. Hazards Identification Potential Acute Health Effects Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Potential Chronic Health Repeated or prolonged exposure to the substance can produce blood disorders. Repeated or Effects prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section.4. First Aid Measures Eye Contact Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor immediately for treatment advice. Skin Contact Rinse skin with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for further treatment advice. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions Non-flammable substance. Special Remarks on Fire Hazards No additional remark. Special Remarks on Explosion Hazards No additional remark. Section;-6. Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spi11 consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Avoid contact with skin and eyes. Incompatibility Strong acids. acids Storage Corrosive materials should be stored in a separate safety storage cabinet or room. Keep out of reach of children. For Institutional and Commercial Use Section 8. F~posure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Long Pants and Long Sleeves to avoid skin cotact. No additional special protective clothing is required. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) • • f7 Exposure Limits 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Consult local authorities for acceptable exposure limits. .Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Characteristic. Molecular Weight Not applicable. Taste Not available. pH 12.5 to 13.5 [Basic.] Color Green. Boiling/Condensation Point 215°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.08 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 80 VOC Not available. Evaporation Rate <1. compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits Not available. Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Presence of Various Substances Not applicable Section 10. Stability and Reactivity Data. Stability The product is stable. Incompatibility with Various Strong acids. aClds Substances Hazardous Decomposition Not available. Products Section 1 '1. Toxicological Information Routes of Entry Eye Contact Ingestion. INHALATION Skin contact. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). . Acute Effects on Humans Eyes Corrosive to skin and eyes on contact. Eye contact can result in corneal damage . Skin Skin contact may produce burns. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Inhalation Harmful if inhaled. Ingestion Irritating to mouth, throat and stomach. May cause headache, dizziness, nausea, vomiting and diarrhea. Chronic Effects on Humans Repeated or prolonged exposure to the substance can produce blood disorders. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. Special Remarks on Toxicity No additional remark. , to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Ecological Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks ou the Products of Biodegradation No additional remark. .Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Transportation Not available. Special Provisions for Not available. Transport Section 15. Other Regulatory Information and Pictograms WHNIIS (Classification) VVHMIS CLASS E: Corrosive liquid. Regulatory Lists SARA 313; 2-Butoxyethanol Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) .HCS CLASS: Corrosive liquid. USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide <1 ppm Massachusetts RTK: Ethylene Oxide SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard; Potassium Hydroxide: immediate health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) R35-Causes severe burns. International No products were found. Regulations Lists Hazardous Material * 3 National Fire Flammability Information System ~ , ~ '~~ protection ~ ~ ~~ Association (U.S.A.) Healtn 3 ;, , (J> tnstabibty Physical Hazard ' O The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE ~ Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product Section 16. Other Information Validated by CRushton on 8/11/2003. Verified by CRushton. Printed 8/13/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of ifs subsidiaries assumes any liability whatsoever far the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannatguarantee that these are the only hazards that exist Validated on 8/11/2003. U/tfa 2000 Page: 6/6 Continued on Next P~3ge 04/02/2003 14:45 9095900738 CHEMCOR PAGE 02/02 ttltzAaD~RAn14cs Irad>I xFPA Iraahh , , Fa. a s KaaadrBr o 0 ,,, d~.,.r p.:~-~ ~..: -. Clsrc # 110160 MAiTERIAL SEiFETY AiTA S EET ~[~cA-T~_o~ Product: Isopropyl Alcohol Item No: 110160 • Sermon l • Product IderdNlandon and Camps Info. Pradeot Name: Isopropyl Aloon PraduN rtenr Ne: ! 10180 laeedact Use: Cleaning compound O.rratal tnprrmanerr: (800) 247.7829 6npgsaey Itdorrnaeon: (800) 247-7829 CAS N0: Na - Mbaure ' $eatron II - Marardous Ingredaoma UmNe Fhtard Cam~aaeMa CAS ;Y PEL AC61N TLY tsopropytAlcoha 87-$3-0 400ppm 4OOppm Water 7732-i&85 $e0tlon [il • Prryercal eta PNYSt STATE: Ugpid DOOM: Snght Ethane APPFJIMNCE: !Sear YAPDR PRESSURE (mm rigl: ~ at 58°F BOWNG PAINT: c212a F pH: No Data 80LUBNITP IN WATEIL• 100% SPECIFIC QRAYITY (Ilf0=7):.7$9 a198°F FLABH POINT: 53° F YAPOfl DEI181TY (AIRat): >t(hsavkxthan air) EYAPOWITiON RATE (WATER=T): a I (faster than water) SexsN011 IV - FIrA AI'Id E~balOrr Data _ FtA~ 41TY: Yes ' ExrfNOUl8Ntx0 MEDIA: Water pt), fxDOn Dioxide (>n, Dry Chemical Qn, foam (1(), Other ( ) BPECIU PIKE HGNiiNO PROC®URES: water may be inetfecbve. water may ba used to keep flrb exposed cenainers cool untNflrbia art Wear a seY-comalned breathing apparefuawNh eful facepiece operated H the posigve pressure demand tnode whhappropriate rum-otrt gear and chemical realStard personal prtuedlva equipmad. UNUSUAL FII1F AND EXPLOSION xAZARDS:Vapasare hsavlerthan airaadnraylravdaimglhegraurul array bs moved by verNgatlon and ig16e0 by blot agars, Bata Hanes, sparks, heaters, smakirg, akcbla motes, static dtschatge, a other ipnltlm sources at IocaNons tl~a iron matedal hantOrrg Point.Mover Nseweldngactadnglach onaneutlrum (ev~nasrWty)becaus~prodwlUlaproductand productrssidus can igntte expbsivery titeotlon v • Peacttvlty Osto STAe1lfTY; 5tabk {NCOMPATIBILITY(MATERU/15T0AV010):Avddewaadwin: acetakiahyde, adds, ddodne, onrylene erode, isocyanatas, strong arddrdnq ageab. 0o not use whh aluminum equipmerd at temperatures above 120 degrees Fahrenheit, HAZARDOUS TttERMAL OECOatPOSmON PRODUCT8: CO, COr HAZARDOUS PDLYMEiBIATNNf: Wail mN occur CONDITIONS TO AVOID: Avail somas wadi open name, ignition souroas, and poa vantil7NOn Ssctlon VI - Flearih Maastrd Data & First Ala NDUTEB OF L91TRy: Inhalation: (x), Ingestion: pq, Demud: (x), Eye Correct QQ fr~cTS of ov,=rt rxrosunE: SKIN; May cause mild skin mitafltm. Pranged a repeated cartact may dry the skin. Symptans may include redness, bwninq, drying and cracking ofsklrr, and skin bums. Passage ofMis materlatimothe body Shrougn the skin is possible, but a is uNikety Mat this would resuh in hamrlul eNecls during safe harklNng and use. EYE8: Can cause eye irgwon. Symptoms inciuda s9nplm9, tearing, redness, and swelinq of eyes. INGESftON: Swallowing smaN amounts o1 this matanet during nomral harxtnnq is not likely tp coolie harmful eilecls. SYralbwing large amautMS may be harmNl. This matedal can get InW the lungs dudnq swaltowing a vomiting. Tats results in lung in9ammadon end oilier rung injury. INHALATION: Breathing of vapor a rots is possible. Breathing small amowd of this madadal during normal handling Is not likely to cause hamdui eNacta. &eaMlnp large amourds may be harmml. 5ymptams usuaAy occdr at air concentrations higher than Ma recanmentled exposure amps. CARCIND6ENTTY: NTP ND NUC MQ OSNA MO bistributol's Name & A~d~dre~ ~!N Ctraar- Source p~~n_n. el. 5800 Olympic Blvd. - ~ - -' CotTttTterce, CA 90022 ~ GL (t300) 247.7826 Soctlon V I -Health HamArd Data >ti First Aid cortPd. EMCYANO i7gSfWO PAGCEfNrRF$: OENFRAL: ft a khoern exposure occurs a is suspected and is detemdned to be a heahh Mrtu or n any symptoms persists, contact a physician, Mrs nearest hospital, a the nearest Poison Camrd Center. lntormtha parson contacted of Me type and extent oFMe exposure, describe the vktim's symptoms and loyow the adviu given, sION: Remove codaminated cloMing. Wash exposed area with soap and water, tt symptoms persists, seek medical atteNfon. Launder eWMinp txdbm, reuse. EYES: Nsymrxarts develop, Imrrtedtatey rtroye indhvdual awayftom totposrxe and b@o fresh air, l#rsh eyes gergly wlh were for a> least f 5 rrtimates whoa hdtFnp ayelidr apart; seek Imrrledrate medical attentlon. INSf87taN: Seek madicat atterruon. tF individual h drowsy a uncortsdous, de hilt give arryMing by mount; place individual on the kh side wtth the head down, Contact a physlaan, medical feciiiry, Or poison control corder for advice abap whether to induce uomifirtg. N possible, do not leave inNYldual unaBended, INHALATION: x symptoms develop, immediately move individual away from exposure and Imo Iresh air. Book Immediate medical aftemdon; keep person warm and quiet. tt person is nix breaMing, Degin ardfidal respiration. K breathing Is dtlTrcuR, administer oxygen. Section VII • Proeautlons for Sate Hondllrrg & Use W DISPOSAL ETHOD: Dispose orln eaordance with aY Local, Stale and Federal repWa6ons• PItECAUTI0N6 TO BE TAKEN Ht HMDUNG AND STOWNiE Containers ar rots meaertal may be hazardous Yvlrert erptied.5ince emptied contanere retain product residues (vapor, squid, andlar aaldl, all hazard precautlona gven In the data sheet must be observed. All five-gaAon pails end larger meat eattainere, irtchlding tank cars and tank rocks, &itaditl De grounded amtUa bonded when malarial la trans(erred. Warring. Sudden release oflwtorganlc chemicatvapors amistsframprocess equipment operitfing at elevated temperature and pressure, a sudden ingross d1 an tma vacuum equyrment, may resWt M ignitions wllfroul tree presence or obvious iprrltlar sources. Ppblsbed "auto-ignieon`a 'ipnttlon"temperature vabas cannot ba of me actual process oonditiuns. Any use of Mle product in aevatedtemptxatureprocesses shouktbethaougnryenduatedtoestabgsh andmaintainsafeoperating condttlons, 8TEP6 TD BE TAKEN IN CASE DF SPILL OR RELEASE Eliminate err igntliorl sources {flares, flames including pAot lights, electrical sparks). Parsons eat wearing protective equlpmerd shWid be excluded from area of snip unfgdean-up has peen completed. Stay sprit at source. Prevem from emeling drains, sewers, sUeams a otherbod~s of water, Prevem from speeding. ttrun orr occurs, notiy authorities ea required. Pump a vacuum transfer spilled product to dean containers for recovery. AbsoN unrecoverable product. Transfer contaminated absorbem, soil and atller matedals to cadalners for disposal. pergood@nvironrtrerdal manapemam practices, preventmn-orttosewers, straarns andolher Dodias of water. Stop sp11 at the source. Cover sewer grates and date the spit. Absorb spilled material an to aCecrberds. Shovel materiak Imo cwdalnrx, Cbae container tiahlN and dispose a propedT, Section VIiT - CoMro1 Aleasuree ttESPIRATONY PROTECTION (SPECIFIC TYPE): x workplace exposure Irmt(s) of product or any componem is exceeded , a NIOSWMSHA approved air supplied resplrata is advised In absence of proper ertwrortmental corrVd OSHA regulations also pemrit atha NIOSH/M5HA respirators (negative pressuretype) under"spetx'fied condidats (seeyourindustdalhyg'rerdst). Enginsefng aadministrallve contrds should be implememed to reduce exposure. YENTiLATION: Provide adequare vsrdnaban a ass mechanical devices. PFASDNAL PROTECTION EQU)PMEMT: Protactlve ctanhtq, PROTECTIVE GLOYEB: Wear roslstam groves (consrd[ your satiety eoulDment supp(er). Te preverd repeated a probngea skin cadad, wear irnpeMous Gothing and boats. EYE PROTECTION: Chemical splash goggles in c0mpliancs wlm OSHA requt~dana ua aovtsed: however, DSNA regWaSans also perms other;ype safety glasses. ConsuR your safety representative. OTHER PROTECTIVE CLOTNIND 011 EDUIPMIENT: Nava clean wadi available fa washing. irV0111(IHYDIENE PRACTICE: Avail acciderdal spills on skin, wash efts use. Wash contaminated clothing pea to reuse. SecNfOr IX -Tr'Aneporfatbn IntarmAUon __ PACKAGE SIZE: All Sizes Flamtnable squids, n.o.s., 8, UNTgg3, PG il, (ET{G# f28J (Contains Isopropanol) DOT IJi6t~ flansnabta PUCAI~: flammable (i0001bs. a mac) We believe me statements, technical krtomtailon and recommendatlons corltalned hasin ere rolieble, but May era givtm wigloot warerdy a quamdee of any bnq express a impped, and we sestina n0 responsibility fa any loss, damage, a expense, draet or consequealal, adslnq out of melr use, lievisfDn Date: Q6/21)02 f ~~ Material Safety Data Sheet G e n l a b s OSHA's Hazard Communication Standard U.S. Department of Labor 29 CFR 1910.1200 ~bzor~7 Clrsc # 070177 o~~Ely2ILL CLEANER Identity # 02057 Name OVEN & GRILL CLEANER Section 1 Manufacture's Name - Genlabs (Formerly General Chemical Corp.) Address - 5568 Schaefer Ave. Emergency Phone (Chemtrec) 1-(800)-424-9300 City -Chino State - CA Phone - (909) 591-8451 Contact Person - Solaiman Jonatan Date Prepared- 4/23/2001 Section 2 -Hazardous Ingredients/Identity Information Hazardous Components CAS# 2-Butoxv Ethanol ' 111762 Potassium Hydroxide 1310583 2-Amino-Ethanol 141435 Note: • A SARA 313 Chemipl VOC Content- 58.0 g/L Section 3 - PhysicaUChemical Characteristics OSHA PEL ACGIH TLV 25PPM 25PPM 2MG/M3 2MGlM3 3PPM 3PPM Boiling Point- >212 F Vapor Pressure -Not Tested Vapor Density -Not Tested Solubility In Water- 100% Appearance and Odor- AMBER, SOLVENT ODOR Section 4 -Fire and Explosion Hazard Data Flash Point- None LEL- Not Tested pH- 13-14 NFPA Hazard Rating - H F R (0- Least, 4 Extreme) 3 0 d Extinguishing Media- None Special Fire Fighting Procedures- NONE Specific Gravity- 1.16 Netting Point -Not Tested Evaporation Rate -Not Tested Weight% (Optional) Flammable Limits -Not Tested UEL- Not Tested DOT# NA1760 S HMIS Hazard Rating - H F R 0 3 0 0 Unusual Fire and Explosion Hazards- NONE Section 5 -Reactivity Date Stability -Stable Conditions to Avoid -None Incompatible Materials to Avoid- Strong Oxidizers, ACIDIC MATERIALS, ALUMINUM Hazardous Decomposition or Byproducts- CO, C02 Hazardous Polymerization- NONE Conditions to Avoid- None t~OCA•TI only ~o~ a~N ~o~~~~ ~? ~1... i - Section 6 -Health Hazard Data Routes of Entry Inhalation? -Possible Skin? -Possible Ingestion? -Possible Health Hazards -Same as Signs and Symptoms of Exposures Note -All Chemicals in this Product are Found on the TSCA Inventory List. OSHA Carcinogenicity? -None; NTP? -None; IARC Monographs? -None. Signs and symptons of over exposure: Eyes - Burning Sensation -SEVERE Skin- Severe Irritaton Ingestion- Severe Burning Irritation Inhalation- Dizziness, Headaches, Irritation Clrsc # 070177 OVEN & GRILL CLEANER # 02057 Medical Conditions Generally Aggraved by Exposure -Same as Signs and Symptoms of Over Exposure. Emergency and First Aid Procedures Eyes -Flush Wfth Water For 15 Minutes. If irritation Persists, Call Physician. Skin- Wash Otf With Soap 8. Water, Clean Underneath Fingernails, If Irritation Persists, Call Physician Ingestion- Drink large Amounts of Water, Call Physician Inhalation- Get Person to Fresh Air If Unconscious, Call Physician Section 7 -Precautions For Safe Handling and Use. Steps to be taken in case material is released or spilled - Soak up with inert, absorbent material. Scoop up and place in a proper waste disposal container. Waste Disposal Method -Dispose of in accordinance v~th state and local regulations. Precautions To Be Taken In Handling and Storing -Store in a cool, dry place, out of direct sunlight. Do not freeze, less then or equal to 32 F, or heat above 110 F. Other Precautions -Keep out of reach of children. Folbw directions on the container for proper use of this product, Section 8 -Control Measures Respiratory Protection -Open all doors and windows. "If there is an exposure, and tt is above the TLV or PEL, a NIOSH approved respirator equipped for the exposure or suitable respiratory protection per 29 CRF 1910.134, is required. Ventilation Local Exhaust - If Available Special -None Mechanical - It Available Other -None Protective Gloves- Plastic or Rubber, Chemical Resistant Eye Protection- Glasses, Goggles Other Protective Clothing or Equipment- Chemical Resistant Clothing Work Hygenic Practices -Use common sense and care around chemicals. Never mix chemicals. Consult your supervisor for other practices. All practices depend on your specific business. Directions for use are normally found on label which will dictate engineering and control measures. Other Special Requrfements Note: Genlatxy believes the data set forth are accurate, Genlabs makes no warranty with respects thereto and disclaims all liability for reliance thereon. Such data are offered solely for consideration, investigatbn and verification. Also, the data set forth is for the concentrated fnished product. All lab samples are for experimental purposes only and used at the customers discretion ~_, -~ 06W-1s hand C>amaugcatiort Stand~d Genlabs ""'~`'`°~ U.s. Departrnent of tabor C:Ir c-#-025.1.00 CLEAN & BRIGHT c----LO ~~->, o A,---- .~ zs CFx,s,o.,200 ~ oM6 No. ,2tti-0072 _o ~~~,~ Y # 02074 Name PORCELAIN TILE CLEANER Section 1 3 Z (1' L, Manufacture's Name - Geniabs (Fomtecf~r General Ctterrtical Corp.) Address - 5568 Sdiaefer Ave. Emergency Phone (Chertrtrec) • 1-(800}-4249300 City -Chino State - CA Phone - (909) 591-8451 Contact Person -Robert Manion Date Prepared- 3/16/98 Section 2 -Hazardous IngredientsJldentity Irrformatlon Hazardous ComporreMs CASs OSHA PEL ACGIH TLV We'ght96 Plwsohoric Acid ' .7664382 3n'K7/m3 3mp/m3 15 Note: ' A SARA 313 Chemical VOC CorrteM- <10 gA. Section S - PhysicaYCherr-icat Ctiaraderistlcs Point >212 F VaporPressure -Not Tested Vapor Density -Not Tested Sok~'rty In Water- 100% Appearance and Odor RED, CHERRY ODOR Section 4 - FMe and Exposion Hazard Data Flash Point- None LEL- Not Tested pH- LOW NFPA Hazard Rating - H F R S (0- Least, 4 Extreme 2 0 0 0 Extinguishing Media- None Special Fire Fighting Procedures NONE Unusual Fire and Explosion Hazards-NONE Section 5 -Reactivity Data Stability -.Stable Conditions to Avoid -None Specific Gravity- 1.09 Meltkg Point -Not Tested Evaporation Rate -Not Tested Flarrur-abie l.knits -Not 7este UEL- Not Tested t~TA ORM-0; NA1T60 Ir>compatible Materials to Avoid- Cationic Materrafs,Strong Ozid'¢ers Hazardous Decrompisition or Byproducts CO, C02 Hazardous Polymerization- NONE Conditions to Avoid- None .;~ Clrsc # 025100 CLEAN & BRIGHT tieakh thlarand t7afa Rouges of Entry inhalation? -Possible Skin? -Possible Ingestion? - Poss~le Headh Hazards -Same as Signs and Symptoms of Exposures Note - AA Chemicals ir-oorporated into ttris Product are Found on the TSCA Imrentory List. OSHA Carcinogenra'ty't -None: NTP? - None: IARC Monographs? -None. ~ 02074 Eyes - Buml+g Sensation Skin Severe Irritatbn Ingestion-t3uming Irritation, NAUSEA Medical Conditans Generally Aggraved by Exposure -Same as Sgns and Symptoms of Over Exposure. Emergency and First Aid Procedures Eyes -Flush With Water For 15 Minutes. ff Irritation Persists. Call Skin- Wash Off With Soap & Water, ff Irritation Persists, Cad Physician htgestion- prink Large Amounts of Water, Cad Physiran Inhalation- Get Person to Fresh Air ff Unconsdous, Cad Physidan Section 7 -Precautions For Safe Handling and Use. Soaps Zo betaken in case material is released or spilled -Soak up with inert, absorbant material. Scoop up and place h a proper waste disposal container. Waste Disposal Method -Dispose of in acoordinanoe with state and local regulations. Precrrtrtiorrs To tae Taken In HandPuig and Storing -Store in a cool, dry place, out of detect sunl'ght Do not freeze or heat above 110 F. ' - Keep out of reach of children. Folbw dlectbns on the container for proper use of this produc Section 8 -Control Measures Respiratory Protection -Open all doors and windows. H exposure is atxnre TLV or PEL, a NiOSH approved respirator equipped for the exposure or suitable respiratory protection per 29 Cf2F 1910.134, is requ'rced. Ventilation Local Exhaust - If Available Spedal -None Mechanical - If Available Other -None Protective Gloves- Plastic or Rubber, Chemical Resistant Eye Protect'an- Glasses, Goggles '~ Olher Protective Clothing or Equipment- None Work Hygenic Practices -Use common sense and care around chanicals. Never mbc dremicais. Consult your supervisor for other practices. Ad practices depend on your specific business. Oin:ctions for use are normally found on label whkh will dictate engineering and control measures. Other Special Requirements _ !~ Genlabs - 29 CFR 1910.1200 tii~tar suety cam sleet ~~~ U.S. Deparlrrrerd of Labor # 02074 Name PORCEWN TILE CLEANER Sectbn 1 Marwfadure's Name -Genlabs (Fomlerty General Chemical Corp.) Address - 5568 Schaefer Ave. Emergency Phone (Chemtrec) • 1 {800}4249300 City -Chino State - CA Phone - (909) 591-8451 Corrfac:t Person - Robert Manion Oate Prepared- 3/16/98 Section 2 -Hazardous Ingredientslldertlity Irrforrrration Hazardous Components CASaX OSHA PEL ACGIH TLV tAle'ght96 Phosphoric Acid ' 76&4382 3nK7/m3 3ny~/m3 15 Note: ' A SARA 313 Chemical VOC Content- <10 g2 Section 3 - PhyskaNCherr>ical Characteristics t8a'6rtg Point >212 F ~ ~~ 1.09 Vapor Pressure -Not Tested Melting Point -Not Tested Vapor gensity -Not Tested Ewaporatiort Rate -Nat Tested Soh~'ity In Water- 100% - Appearance and Odor RED, CHERRY ODOR Section 4 - Fke and E~losion Hazard Data Flash Point- None LEL- Not Tested pH- LOW NFPA Hazard Rating - H F R S (0-Least, 4 Extreme 2 0 0 0 Extinguishing Media- None Special Fue Fghting Procedures NONE Unusual Fire and Expbsbn Hazards-NONE Section 5 -Reactivity Data Flartvnable Limits -Not Teste UEL- Not Tested DOTrx ORM-0; NA1T60 StaWlity -Stable Conditions to Avoid -None Inoarnpatible Materials to Avoid- Cationb Materiats,Stnxig Oxidizers Hazardous Decompisition w Byproducts CO, C02 Hazardous Polymerization- NONE Conditions to Avoid- None Clrsc 0# 25225 CLEAN & BRIGHT 'LOG ~_T_l_o_l~~ guts No.121ti-0072 Q~ /I_v_/_~j~ f 1 SD G2T5 ~~ Clrsc # 025225 CLEAN & BRIGHT e hard Data Rou6es of Entry Inhafc#ion? - Poss>ble S1dn? -Possible Ingestion? - Possble Heakh Hazards -Same as Signs and Symptoms of Exposures Note - M Chemicals Incorporated into tt>is Product are Found on tfie TSCA inventory t3st. OSHA Cardnogen"rdh? -None; NTP? -None; IARC Monographs? -None. # 02074 Eyes - Burning Sensation Skin Severe Irritation Ingestion-Burning Irtitation, NAUSEA Inhitatior>- Irtitation Medical Conditions Generally Aggraved by Exposure -Same as Signs and Symptoms d Over Exposure. Emergency and Fast Aid Procedures Eyes -Flush With Water For 15 Minutes. ff irritation Persists, Call Skk-- Wash Off With Soap b Water, tf irritation Persists, Cab Physician htgestion- DriMc Large Anxwnts of Water, CaN Physician Inhalation- Get Person to Fresh Air If Unconscious, Cab Physican Sediort 7 -Precautions For Safe Handfirx~ and Use. Steps to be taken in case material is released or spilled -Soak up with ineR, absorbent material. Scoop up and place h a proper waste disposal corltalner. Waste Disposal Method - Dispose of in accordinance witi- state and local regulations. Pr~ecetdions To tae Taken In Handling and Storing -Store in a coot, dry ptace, out d direct sunight Do not freeze or heat above 110 F. Other Precautions -Keep out of reach of children. Folbw directions on the oontaher for proper use of this produc Section 8 -Control Measures Respiratory Protection -.Open all doors and windows. ff exposure is above TLV or PEI, a NIOSH approved respirator equipped for the exposure or suitable respiratory protection per 29 CRF 1910.134, is required. Vent~ation local Exhaust - if Avalable Special -None Mechanical - If Available Other -None Protective Gloves- Plastic or Rubber, Chemical Resistant Eye Protect'an- Glasses, Goggles `~ Other Protective Clothing or Equipment- None Work Hygenic Practices -Use corrurron sense and care around chemicals. Never ma dremicals. ConsuR your supervisor for other practices. All practices depend on your specific business. Oiredrons for use are normally found on label which will dilate engineering and control measures. Other Special Requirements ~,,. Clean ource THE CLEANING SUPPLY EXPERTS Material Safety Data Sheet (Prepared Actordiaa to 29 CFR 1910. 1200) Clsrc # ULTRA-CLEAN ~~~' ~~/ ~~/_~~ DISH MACHINE DE7['ER~EN~ o?5GL Trade Name: Dish Machine Detergent Product Type: Warewash Detergent Chemical Family: NA Formula: Proprietary DISTRIBUTOR'S NAME: EMERGENCY TELEPHONE NUMBER: Clean Source 1-800-535-5053 1711 Rogers Avenue NUMBER FOR INFORMATION: San Jose, CA 95112 1-800436-1907 Boiling Point: >212°F Specific Cravity (H2O=1.0) 1.34 (±0.0005) pH: 14.0 LOS) Vapor Pressure (mmg Hg.): NA Vapor Density (A[R~1) NA Solubility In Water: Complete Evaporation Rate (vs H2O): Unknown Appearance and Odor: Clear, colorless thin liquid, neutral odor. Flash Point (1'.C.C.): None to Boiling Upper Flammable Limits: NA Lower Flammable Limit: NA Fire Extinguishing Media: NA Special Fire Fighting Procedures: NA Unusual Fire aad Explosion: NA Stability; Stable Incompatibility (Materials to Avoid): Acids; Aluminum, Tin, Zinc; Nitro Carbons, Halo Carbons Hazardous Decomposition Products: Hydrogen gas by reaction with Aluminum, Tin or Zinc metals. Threshold Limit Value-Product See Section 2 for Ingredients TLV: None Established Primary Routes of Exposure: Eyes, Skin, Oral and Inhalation Signs and Symptoms of Over-Exposure (Chronic): Unknown Signs and Symptoms of Over-Exposure (Acute): Corrosive to all human tissue. Can cause burns. Ingestion may cause violent pain in throat and Damage gastro respiratory tract. Inhalation of mist may cause damage to upper respiratory tract with possible chemical pneumonia from severe exposure. Medical Conditions Aggravated by Over-Exposure: Unknown Carcinogen or Suspect Carcinogen Ingredients: None Eyes: Flush with water for 15 minutes. Contact a physician. Skin: Wash with large quantities of water Remove contaminated clothing. Ingestion: Drink plenty of water. DO NOT induce vomiting. Get medical attention at once. Inhalation: Remove to fresh air. If qualified, give oxygen or artificial respiration as necessary and/or seek medical help. Respiratory Protection: None normally required. Ventilation Requirements: Local Exhaust and Mechanical (To keep below any listed TLV's and/or for general good ventilation.). Protective Equipment: Rubber Gloves & Safety Goggles.Other Protective Clothing: Chemical Apron, rubber boots es appropri- ate to usage to prevent skin contact. Steps to be Taken 1f Released or Spilled: Neutralize with weak acid solution. Flush with large quantity of water. Waste Disposal Methods: Small diluted neutralized solutions may flush to sanitary sewer system. Check all govemmcntal regulations. Precautions to be Taken in Handling and Storage: Store away from acids, reactive metals and organics. Keep out of reach of children. Wash thoroughly after handling. HAZARD RATING 0{xln;ma w D 3-Fayb vm 2-lbae~u° 3 0 ~ xe.LLm 0 o-laslpdfipat ~ Data Prap°rod: 11/29/2001 Contains no substances subject to the reporting requirements of SARA 313 and 40 CFR Part 372. Material Safety Data Sheet (Prepared According to 29 CFR 1910. 1700) Clean c~urce ULTRA-CLEAN .,~ . THE GIEANINt; SUPPtY EXPERTS DESTAIl~TER Trade Name: Multi Chtor Product Type: ~~+ A -T-~ 0 N~ Chemical Family: Inorganic halogen compound `' Formula: yl ~~~tE, B~~ DISTRIBUTOR'S NAME: EMERGENCY TELEPHONE NUMBER: Q~ J'~ / ~~ Clean Source 1-800-535-5053 / 1711 Rogers Avenue NUMBER FOR INFORMATION: 'r ~~ San Jose, CA 95112 1-800.436-1907 J Boiling Point: 212°F Decomposes Specific Gravity (H2O~1.0) 1.12-1.15 (±0.0005) pH: 11.0 L+OS) Vapor Pressure (mmg Hg.): 12.1 mmHg @ 20°C (68°F) Vapor Density (AIRml) NA Solubility In Water: Complete Evaporation Rate: Unknown Appearance and Odor: Clear, straw yellow liquid: Chlorine odor. Flash Point (T.C.C.): NA Upper Flammable Limits: NA Lower Flammable Limit: NA Fire Extinguishing Media: Not Combustible. Water Spray, dry chemical, Cot or foam may be used in areas where product is stored. Special Fire Fighting Procedures: Keep away from organic material. Unusual Fire and Explosion: None Stability: Stable Incompatibility (Materials to Avoid): SVong acids Hazardous Decompos)tion~Producta: Chlorine gas, hypochlorous acid. Hazardous Polymerization: Will Not Occur. Conditions to Avoid: Strong acids, ammonia, organic materials, elevated temperatures. Primary Routes of Exposure: Eyes, Skin, Inhalation & Ingestion Signs and Symptoms of Over•Exposure (Chronic): May be ircitating to eyes and skin with some individuals. Signs and Symptoms of Over-Exposure (Acute): May be ircitating to eyes and skin with some individuals. Nausea if swallowed. Medical Conditions Aggravated by Over-Exposure: Unknown Carcinogen or Suspect Carcinogen Ingredients: None Eyes: Flush with water for 15 minutes, while holding eyelids open. Contact a physician. Skin: Wash with water. Remove any contaminated clothing. Ingestion: Drink large quantities of water or milk. DO NOT induce vomiting. Oet medical attention. Inhalation: Remove victim to fresh air. Respiratory Protection: None Ventilation Requirements: None. Protective Equipment: Rubber Gioves & Safety Goggles. Other Protective Clothing: NA Steps to be Taken if Released or Spilled: Flood area where spill has occurred with large quantities of water. Waste Disposal Methods: Diluted product may be flushed into sanitary sewer system. Product may also be absorbed with sand or diatomaceous earth. Absorbed products must be disposed of in accordance with applicable Federal, State, and/or local regulations. Precautions to be Taken in Handling and Storage: Observe personal hygione. Keep container closed when not in use. Store thisproduct in a cool, dry area, x~z~ItoaArtKo keep away from heat, light and flame to avoid deterioration. ~~~ "° o m :-A,odna° 2 0 '' ~m Date Pnepered: I Inarzaol C,z~r~5~~,-~~ ~ o~gtx~- Clean ource hr..... THE CLEANING SUPPLY EXPERTS Trade Name: Dish Machine Detergent Chemical Family: NA DISTRIBUTOR'S NAME: Clean Source 1711 Rogers Avenue San Jose, CA 95112 Boiling Point: >212°F Vapor Pressure (mmg Hg.): NA Evaporation Rate (vs H=O): Unknown Flash Point (T.C.C.): None to Boiling Fire Extinguishing Media: NA src # Material Safety Data Sheet LOGgTIon! -] (Prepared According to 29 CFR 1910.1200) ULTRA-CLEAN _~.5~ DISH MACHINE ~ GL- DE'I'EIZGlE1o1rI' Product Type: Warewash Detergent Formula: Proprietary EMERGENCY TELEPHONE NUMBER: 1-800-535-5053 NUMBER FOR INFORMATION: 1-800.436-1907 Specific Gravity (H2O=1.0) 1.34 (±0.0005) pH: t4.0 (±OS) Vapor Density (AIR=I) NA Solubility In Water: Complete Appearance and Odor: Clear, colorless thir- liquid, neutral odor. Upper Flammable Limits: NA Lower Flammable Limit: NA Special Fire Fighting Procedures: NA Unusual Fire aad Explosion: NA Stability: Stable Incompatibility (Materials to Avoid): Acids; Aluminum, Tin, Zinc; Nitro Carbons, Halo Carbons Hazardous Decomposition Products: Hydrogen gas by reaction with Aluminum, Tin or Zinc metals. Threshold Limit Value-Product See Section 2 for Ingredients TLV: None Established Primary Routes of Exposure: Eyes, Skin, Oral and Inhalation Signs and Symptoms of Over-Exposure (Chronic): Unknown Signs and Symptoms ofOver-Exposure (Acute): Corrosive to all human tissue. Can cause burns. Ingestion may cause violent pain in throat and Damage gastro respiratory tract. Inhalation of mist may cause damage to upper respiratory tract with possible chemical pneumonia from severe exposure. Medical Conditions Aggravated by Over-Exposure: Unknown Carcinogen or Suspect Carcinogen Ingredients: None Eyes: Flush with water for 15 minutes. Contact a physician. Skin: Wash with large quantities of water. Remove contaminated clothing. Ingestion: Drink plenty of water. DO NOT induce vomiting. Get medical attention at once. Inhalation: Remove to fresh air. [f qualified, give oxygen or artificial respiration as necessary and/or seek medical help. Respiratory Protection: None normally required. Ventilation Requirements: Local Exhaust and Mechanical (To keep below any listed TLV's and/or for general good ventilation.). Protective Equipment: Rubber Gloves & Safety Goggles.Other Protective Clothing: Chemical Apron, rubber boots es appropri- ate to usage to prevent skin contact. Steps to be Taken 1f Released or Spilled: Neutralize with weak acid solution. Flush with large quantity of water. Waste Disposal Methods: Small diluted neutralized solutions may flush to sanitary sewer system. Check all governmental regulations. Precautions to be Taken in Handling and Storage: Store away from acids, reactive metals and organics. Keep out of reach of children. Wash thoroughly after handling. HAZARD RATING ~~ExYeme sw D 3~fiIZA °Y 3~M°deub 1 0 ~ ww.m 0.hdpdfkw ~ oue Prepued: r rn9noor Contains no substances subject to the reporting requirements of SARA 313 and 40 CFR Part 372. C t ea~so~ ~~ ~ .~. `{ 3 ~-~ ~S ~ 2~+3od5~ ~Z.p C A~_CI_D_ ,~r~ it ~., ~r, , ~. Material Safety Data Sheet ~ /~~ c~ C ~^~ (Prepared According to 39 CFR 1910. 1200) ~~ ! _. ~ ~! ~ ~ ~ _ r^1 >rlr ~ , f't ~. ~ J.s+ 1 / ~ J f J1 aDG~ ~~ L: Prodact Ideatiticatlon: MSDS #:643 Trade Name: SofUSour (498) Product Type: Liquid Softner/Sour Cbemica! Family: NA Formula: M(xture DISTRIBUTOR'S NAME: Clean Source 1711 Rogers Avenue San Jose, CA 95112 EMERGENCY TELEPHONE NUMBER: I-800-535-5053 NUMBER FOR INFORMATION: 1-800-436-1907 ,. 2.Hainrdousingredieuta: 3. Physic>tl Data: Boiling Point: About 212°F Specific Gravity (H20=1.0) 1.01 (±0.0005) pH: 2.0 L+OS) Vapor Pressure (mmg Hg.): Less than 1 Vapor Density (AIR=1) Less than 0.1 Solubility In Water: Complete Evaporation Rate: About the same Appearance and Odor: Yellow, semi-opaque liquid, citrus odor. 4: Fire apd Rzplo:ion Hazard Data: Flash Polat (T.C.C.): None to Boiling Upper Flammable Limits: NA Lower Flammable Liroit: NA Fire Extinguishing Media: NA Special Fire Fighting Procedures: None Unusual Fire and Explosion: None ;. S. Reactive l)atas , Stability: Stable Incompatibility (Materials to Avoid): Certain Metals. Hazardous Decomposition Products: Hydrogen gas upon contact with certain metals. ti. Health Hazards; Threshold Limit Value=Product See Section 2 for Ingredients TLV: None Established Primary Routes of Ezposure: Eyes, Skin, Oral and Inhalation. Signs and Symptoms ofOver-Exposure (Chronic): Burning and corneal damage to eyes. May cause burning and severe irritation to skin. Nausea and vomiting, if swallowed. Signs and Symptoms ofOver-Exposure (Acute): May cause burns to skin and eyes. Extremely irritating to mouth, if swallowed. Medical Conditions Aggravated by Over-Ezposure: Open sores, eye and skin allergies. Carcinogen or Suspect Carcnogen Ingredients: None ?. Emetlcocy and ~lr~t Aid Procedures: Eyes: Flush with plenty of water for IS minutes. Skin: Flush with plenty of water for I S minutes. Remove contaminated clottiing. Ingeatloa: Give large quantities of water to dilute. DO NOT induce vomiting. Get medical attention. Inhalation: Remove ro fresh air. 8. Special Protection InformaNou: , , Respiratory Protection: Normal ventilation, NTOSH approved respirator if TLV is exceeded. Ventilation Requirements: Local Exhaust. Protective Equipment: Rubber Gloves & Safety Goggles. Other Protective Clothing: None 9. Spill or Leak Proeedures: ,:. , Steps to be Taken if Released or Spilled: Neutralize with mild alkali such as baking soda. Waste Disposal Methods: Sewer to water. Check all governmental regulations. 10. Storage sad:[1AUdliag Information; Precautloas ro be Taken in Handling and Storage: Keep from freezing. Keep out of reach of children. x~zxnoturwa ~ ,°. u ~~~ m 2.t a o isa~a ,ATM o a~+od~a ..a,~ gatet4epaRd: nn9noot 0 Clean~urce THt i-LtANWC; tiUPPi ~ FkPFR'ti Trade Name: Booster (904) Chemical Family: NA DISTRIE3l;TUf<' ti.-,i.(1'.. Clean Source 171 I Rogers. Avenue San Jose, CA 951 12 Clsrc # 078005 Material Safety Data Sheet (Prepared Accordlna to r9 CFa 1910. 1300) 2 Product Type: Concentrated BuitderlBreak-~ ~~. ,it ~O„ 1 Formula: Proprietary G~VC.i'i w CIv1ERGGNi'1' "i-i:i_):PiiONL \i;Pvi[3i:Fc: ~U~-/ ~L f ~(~~ 1-S00-S~5-Sp51 , NUMBER FOR INFORMA 1lON: ~O / _L I -SOU-43G-I 9U7 l7 Boiling Point: >212°F Specific Gravity.(H2Oa1.0) 1.49 (±0.0005) pH: 13.5 (±OS) Vapor Pressure (mmg Hg.): NA Vapor Density (AIR=I) NA Solubility In Water: Complete Evaporation Rate (vs Hj0) :About the same Appearanee and Odor:. Moderately viscous, red liquid. Flasb Point (T.C.C.): None to Boiling Upper Flammable Limits: NA Lower Flammable Limit: NA Fin Extinguishing Media: NA Special Fire Fighting Procedures: none Unusual Fire and Explosion Hazards: None Stablllty: Stable Incompatibility (Materials to Avoid): Acids; Aluminum, Tin, Zinc; Nitro Carbons, Halo Carbons. Hazardous Decomposition Products: Hydrogen gas by reaction with Aluminum, Tin or Zinc metals. Threshold Limit Value•Product See Section 2 for Ingredients TLV: None Established Primary Routes of Exposure: Eyes, Skin ,Oral & Inhalation Signs and Symptoms of Over-Exposure (C'hronic): lJnknown Signs and Symptoms ofOver-Exposure (Acute): Corrosive to all human tissue. Can cause bums. Ingestion may cause violent pain in throat and damage , jiastro-respiratory tract. Medical Conditions Aggravated by Over-Exposure: Unknown Carcinogen or Suspect Carcinogen Ingredients: None Eya: Flush with water for I S minutes. Contact a physician. Skin: Wash with large.quantities of water. Remove contaminated clothing. Ingestion: Drink plenty of water. DO NOT induce vomiting. Call a physician at once. Inhalation: Unlikely occurrence. Remove to fresh air. Call a physician. Respiratory Proteetlon: None normally required Ventilation Requirements: Local Exhaust Protective Equipment: Rubber Gloves 8c Saftty Goggles. Othtr Protective Clothing: Chemical Rubber Apron and t3oots Steps to be Taken if Released or Spilled: Contain spill. Neutralize with weak acid solution. Flush with large quantity of water. Waste Disposal Methods: Small diluted neutralized solutions may flush to sanitary sewer system. Check all government regulations. Precautions to be Taken in Handling and Storage: Store away from acids; reactive metals and organics. Keep out of-reach of children. M~z~aoa~rn+G 3-iti~ r•~IOAere 7 I I-Slidt n Iwe Prepared 1 Inw2ool Contains no substances subject to the reporting requlremenls of SARA 313 and 40 CFR Part 372. Y f 1\~DS Document for SNB-130 ~ Spartan Chemical Company, Inc. Material Safety Data Sheet Spartan ~ SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label):Product Division: SNB-130 Product Number: 2130 Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee OH 43537 Janitorial Product/Technical Information: l-(800)-537-8990 Cisrc # 100380 _LOCATtoN~ gisc~ B/_N v_~ f o_r_/_e_2, 15 ~~ Medical Emergency:l-(888)-314-6171 (24 hours) Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24 hours) Emergency: Shipping Description:! Corrosive liquids, n.o.s., 8, UN 1760, II, (contains potassium hydroxide) ~ SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1 % or greater, carcinogens at 0.1 % or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z- 1 - A NTP, Chemical Name(s) % W - _ _ CAS GEEING mg/ Registry No. TWA mg/m3 STEL mg/m 3, m3 IARC or OSHA Carcinogen Sodium metasilicate 10-15 6834-92-0 Established Established Establ shed No Sodium tripolyphosphate 1-5 7758-29-4 Establ shed Established Established No Potassium hydroxide 1-5 1310-58-3 Established Establ shed 2 (NIOSH) No Phosphate ester 1-5 68130-47-2 Established Established Established No http://www.spartanchemicaLcon~/sfa/MSDSRep.nsf/18ce1...619f51/c88495eeb2510f8b852570260069c714!OpenDocument(1 of 6)7/26/2005 8:11:59 AM M.SDS Document for SNB-130 Appearance & Odor:' Clear purple liquid, no odor SECTION IV: FIRE & EXPLOSIVE HAZARD DATA ...~~_ w.. ,___ ~ ~..~.. ww._ ..~,.® ~w~~ .~_~.~ ~.~_.,~ ___-__v.~..~..~ ~~w _._ __ __~._ Flash Point• > 212°FMethod Used: ASTM-D56 Flammable Limits: N/A Flame Extension:: N/A Extinguishing Media: Product does not support combustion. Use extinguishing media appropriate for surrounding fire. _ .~,. Special Fire Fighting.; Wear NIOSH approved self-contained breathing apparatus and protective Procedures: clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive 'Combustion products are toxic. ~ Hazards: SECTION V: HEALTH HAZARD DATA __.._._...._. ._.v ..__._ _._... _.... __....~. ~ _..__ ~._.._.._.. __~..~._. .. ___.. _ ...__..__. ....._._ ._.~._.___.._.~_._._._ ~__m_ _.._ .~..v_..., ,_ .__~__ _. ~,.._...__~.. ._...._.. Threshold Limit Value: ~ Not Established Primary Routes of Inhalation, Skin Contact, Entry:, Eyes & Oral Effects of Overexposure- CORROSIVE: Conditions to Avoid: CAUSES EYE AND SKIN BURNS: Symptoms include chemical burns, pain, redness, swelling of the conjunctiva and tissue destruction. HARMFUL CONTACT MAY NOT CAUSE IMMEDIATE PAIN. HARMFUL IF SWALLOWED: Causes damage or chemical burns to esophagus and mucous membranes with symptoms of pain, nausea, vomiting and diarrhea. Aspiration of product into the lungs may occur during ingestion or vomiting, resulting in lung injury. HARMFUL IF INHALED: Breathing product vapor or mist may cause irritation or damage of the respiratory tract, with symptoms of nasal discomfort and discharge with chest pain and coughing. DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOTBREATHE { PRODUCT VAPOR OR MIST. DO NOT SWALLOW. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER http://www.spartanchemical.con>lsfa/MSDSRep.nsf/18ec1...619f51/c88495eeb2510f8b852570260069c714!OpenDocument (3 of 6)7/26/2005 8:11:59 AM MSDS Document for SNB-130 Eyes: Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin: Remove contaminated clothing and shoes. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing '. before reuse. Destroy contaminated shoes. Ingestion:; Call a poison control center or doctor immediately for treatment advice. Do not induce vomiting. Drink one or two glasses of water to dilute product. Do not give anything by mouth to an unconscious person. Inhalation: In case of respiratory irritation or dizziness; move person to fresh air. Get medical attention if irritation persists. http://wwwspartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/c88495eeb2510f8b8525'I0260069c714!OpenDocument (4 of 6)7/26/2005 8:11:59 AM MSDS Document for SNB-]30 R.r ~ SECTION VI: REACTIVITY DATA '~ SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Dike and contain spill with inert material (sand, earth, commercial absorbent, Material is Released or etc.) and transfer to containers for disposal. Rinse area with water and flush to Spilled: sanitary sewer.. Keep spill out of storm sewers and waterways. _. ~._ .. E Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. '~ SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection:': Not normally required when good general ventilation is provided. However if ` exposure limits are exceeded (see Section II) or if respiratory irritation occurs, the use of a NIOSH approved respirator suitable for the use-conditions and chemicals listed in Section II should be considered. Ventilation:.. Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. . Protective Gloves(Specify Solvent/alkali resistant gloves such as neoprene, nitrite or natural rubber/ latex Type): are recommended. Eye Protection(Specify ; Splash goggles are recommended to prevent eye contact. Type): Other Protective Equipment:: Solvent /alkali resistant boots, apron and other protective equipment is recommended when foot /body contact is likely. Eye wash stations and washing facilities should be readily accessible in areas where product is handled.. See 29 CFR 1910.132-138 for further guidance. ~ SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: _ Keep container tightly closed. Store in a cool, dry area. Do not freeze. Do not store above 120°F. Do not mix with other chemicals. _. ........ ........... . Other Precautions: Keep out of reach of children. © SCC 06/30/2005 Name: Ronald T. Cook Title: Manager, Regulatory Affairs http://wwwspartanchemicaLcom/sfa/MSDSRep.nsf/18ce1...619f51/c88495ee62510f8b852570260069c714!OpenDocument (5 of 6)7/26/2003 8:11:59 AM MSDS I?~ocument for SNB-130 ::- - SNB-130 Effective 06/30/2005 Supercedes: 09/27/2004 Date: Ref: 29 CFR 1910.1200 Changes: Update Section IX (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...6] 9f51/c88495ee62510f$b852570260069c714!OpenDocument (6 of 6)7/26/2005 8:11:59 AM ~. , E._= Clsrc # 148150 Flo-Kem, Inc. Rancho Dominguez, CA 90221 19402 Susana Rd. Emergency~80~0-255-3924 MATERIAL SAFETY DATA SHEET ~ 0~~ NAME: STRIPPER 815 Identity: Floor Stripper TOXICITY: 2 SECTION II Name 2-Butoxyethanol Ethanolamine SECTION I. IDENTIFICATION OF PRODUCT ~~~/ /Qa /~-~ MSDS Number: C2L815 1~ - Date: 6-3-99 ~,8 GL, FIRE: 0 REACTIVITY:O PROTECTION: C . HAZARDOUS INGREDIENTS/IDENTITY INFORMATION CAS Number PEL TLV 111-76-2 25 ppm 25 ppm (skin) (skin) 141-43-5 6 ppm 3 ppm STEL SECTION III. PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Specific Gravity: Vapor Pressure Melting Point: 212 F 1.026 (mm Hg.): ND ND Vapor Density: Evaporation: Water Solubility: pH @ 77 F: (Air =1): 1 (H2O=1): 1 Complete 13.85 Appearance and O dor: Clear Red Orange liquid; Scented. SECTION IV. FIRE AND EXPLOSION HAZARD DATA Flash Point (TCC): LEL: UEL: Flammable Limits: None NE NE NA Extinguishing Media: Appropriate to fire fuel source. Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None SECTION V. HEALTH HAZARD DATA Route(s) of Entry: INHALATION? No EYES? Yes SKIN? Yes INGESTION? Possible (Acute) Health Hazards: Eyes: Contact with eyes may cause damage. Skin: Contact with skin may cause irritant reaction. Ingestion: Swallowing may cause gastric distress. Inhalation: Breathing a mist may cause sneezing. (Chronic) Health Hazards: 2-butoxyethanol is readily absorbed through the skin where it exerts a toxic effect on the liver, kidneys, and hematopoietic systems. Signs and Symptoms of Exposure: Eyes: Burning. Skin: Wet Feeling. Ingestion: Nausea and vomiting. Inhalation: Sneezing if mist generated. Medical Conditions Generally Aggravated by Exposure: Preexisting disorders of the skin, liver, kidneys, and hematopoietic system. Emergency and First Aid Procedures: Eyes: Flush eyes with large amounts of water, lifting upper and lower eyelids. If irritation persists, obtain medical attention. Skin: Wash off with soap and water. Remove contaminated clothing and wash before reuse. If irritation persists, obtain medical attention. Ingestion: Obtain immediate medical attention. Inhalation: Remove to fresh air. If irritation persists, obtain medical attention. SECTION VI. TOXICITY DATA Carcinogenicity: NTP? NO IARC MONOGRAPHS? NO OSHA REGULATED? NO C2L815 ,~~: SECTION VII. REACTIVITY DATA Stability: Stable Hazardous Polymerization Will Not Occur Incompatibility (Materials to Avoid): Other cleaning agents may or may not react. Hazardous Decomposition Byproducts: Oxides of carbon and sulfur. SECTION VIII. PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be Taken in Case Material is Released or Spilled: Small Spills: Mop up. Large Spills: Dike area and absorb into neutral material or pump up. Disposal: As allowed by Federal State and Local requirements. Many jurisdictions allow small amounts into the sanitary sewer. Handling and Storing: Store in a cool, dry, well ventilated area. Keep container tightly closed when not in use. Other Precautions: Keep out of reach of children. For industrial and institutional use only. SECTION IX. CONTROL MEASURES Respiratory Protection: Not normally indicated Ventilation: Normal indoor ventilation Local Exhaust: Not normally indicated Mechanical (General): Not normally indicated Special: N/A Other: N/A Protective Gloves: Rubber or vinyl. Eye Protection: ANSI Z87 Other Protective Clothing or Equipment: Long pants and sleeves, WorWHygienic Practices: The recommendations described in this section are provided as general guidance For minimizing exposure when handling this product. Because use conditions Will vary, depending upon customer applications, specific safe handling procedures should be developed by persons knowledgeable of the intended use conditions and equipment. SECTION X. DOT INFORMATION #171 Compounds Cleaning Liquids (Amines),8, NA 1760,PGIII SECTION XI. MISCELLANEOUS INFORMATION SARA 313: Contains 2-butoxyethanol as noted above. Notice: All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from the manufacturer and/or recognized technical sources; however, manufacturer makes no warranty, representation or guaranty as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of the product. NA -Not Applicable S -May Be Absorbed Through Intact Skin ND - No Data Available C2L815 ~, ~t~ CS # 145810 Spartan Chemical Company, Inc. ~"f ~~ ~,~., ~~ } ~.. Material Safety Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: L.O.E. STR)iPPER Janitorial Product.Number:O061 ,.... ~~~. ~- ;~~~{ f~ (~L-~_~_-~ L_o,_c!~nv_~v~ Cv~ a ~6~' Spartan Chemical Company, Inc. Product/Technical Information: 1-(800}.537-8990 i 110 Spartan Drive Medical Emergency: 1-(888)-314-6171 {24 hours) ~ GL. Ntaumee OH 43537 Chemical LeaklSpil Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Descriptwn: Corrosive liquids, n.o.s., 8, UN 1760, II, (centains potassium hydroxide) NFPA Ratin s: HMIS Ratings: Health: 3 -Serious Health: '3 -Serious; Chronic Hazard Fire: 0 -Minimal Fire: 0 -Minimal Reactivity: 0 -Minimal Reactivty: 0 - Minimal Pers. Prot. Equip.: See Segion VIII SECTION 11: HAZARDOUS iNGREDtENTS (Listed when present at 196 or greater, carcinogens of 0.1 °~ ar greater) At{ component chem'xafs are fisted or exempted from fisting on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A CA5 R~ ry 1WA ' STEL ' CEILING ' NTP, IARC Chemical Name(s) °kWt No~ mglm mg/m mg/m or OSHA Cartdnogen 'Diethylene glywl monabutyl 20-30 112-34-5 Not Established Not Established Not Established No ether - - - - - - Monoethanolamine 5-10 141-43-5 6 15 (ACGIH) Not Established No Potassium hydroxide 1-5 1310-58-3 Not Established Not Established 2 {NIOSH) No Ethoxyiated alcohols phosphate 1-5 68130-47-2 Not Established Not Established Not Established No ester - - - - - - Comment: `This substance is sub)ect to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Acs of 1986 (SARA) and of 40 CFR 372. SECTION flh PHYSICAL DATA 8oiting Point: 2pp .F Vapor Pressure: Unknown Vapor Density (AIR = 1): Unknown Solubility En Water. Complete PH: 13.0-13.7 Specific Gravity {H,O=1): 1,02 Evaporation Rate (but.ace.=1}: e1 Percent Solid by Weight: 3 - 5 Physical State: Liquid Appearance & Odor: Clear light orange liquid, mild odor SECTION 1V: FIRE & EXPLOSIVE HAZARD DATA Method Used: Flash Point: > Extinguishing Media: Carbon dioxide, dry chemical, synthetic foam or water. Special Fire Fighting Procedures: Wear NtOSH approved self-contained breathfrrg apparatus and protective clothing. Cool fire~xposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. } S i. CS # 145810 SECTION V: HEALTH HAZARD DATA Tftreshold Limit Vatue: Nat Established ~ Primary Routes of Entry: Inhalation, Skin Contact, Eyes $ Orat Effects of Overexposure- GQRROSIVE: Conditions to Avoid: HARM{=UL TO EYES: Causes severe eye damage or initation with symptoms of pain, redness, sweNing of the conjunctiva and possible permanent corneal damage. HARMFUL TO StC1N: Causes severe skin damage or irritation with symptoms of pain, redness and chemical bums. Harmful contact may not cause immediate pain. Repeated contact may cause a dermatitis. Harmful If absorbed through the skin. HARMFUL OR FATAL IF SWALLOWEi7: Causes damage or chemical bums to esophagus and mucous membranes with symptoms of pain, nausea, vomiting and diarrhea. Aspiration of product into the fangs may occur during ingestion or vomiting, resulting in lung injury. HARMFUL IF INHALED: Breathing product vapor or mist may cause irritation or damage of the respiratory tract, with symptoms of nasal discomfort and discharge with chest pain and coughing. Contains monaethanofamfne which may cause fiver and kidney damage with repeated exposure. Do not get in eyes, on skM or clothing. Avoid breathing product vapor or mist. Do not swallow. Use with adequate ventilation. Wash thoroughly after handiing. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatNis. Emergency 8 First Aid Procedures: Eyes: Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact tenses. Call a poison control center or doctor far treatment advice. Skin: Immediately flush sfdn with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cait a poison control center or doctor for treatment advice. wash contaminated cbthing before reuse. Destroy contaminated shoes. ingestion: CaN a poison control center or doctor immediately for treatment advice. Do not induce vomiting. Drink one or two glasses of water to. dilute product. Do not give an~th(ng by mouth to an unconscious person, Inhalation: In case of respiratory irritation or dizziness; move person to fresh air. if not breathing; give artificial respiration. If breathing is difficult; give oxygen. Cali a poison control center or doctor for treatment advice. SECT{ON Vl: REACTIVITY DATA Stability: Stable ~ incompatible Materials: Strong adds and oxidizing agents Hazardous Decomposition Products: None known ~ Hazardous Polymerization: Will Noi Occur SECTION VII: SPILL OR t.EAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Contain large spills and transfer the material to appropriate containers far redamatiort or disposal. Absorb remaining material or small spiNs with an inert material and dispose of in accordance with federal, state and local regulations. Keep spNl out of sewers streams or other barites of water. Waste Disposal Method: Assure conformance with federal, stars and local regulations. SECTION Vili: SPECIAL PROTECTION iNFORMATtON Respiratory Protection: Nat normaNy required when good general ventilation is provided. However K exposure limits are exceeded (see Section II) or if respiratory irritation occurs, tt-e use of a NIOSH approved respirator suitable for the use-condNions and chemtcais tistedm Sectkm if shoukf be considered. Ventilation: Provide good genera{ ventilation.. Local exhaust veniNation may be. necessary for some operations. Protective Gloves{5pec'rfy Type): SoivenUaNcail resistant gloves such as neoprene, nitrite or natural rubber/ latex are recommended. Omer Protective Equipment: Solvent /alkali resistant boots are recommended. Use of impervious apron, face shield and other protective equipment should be considered in order to prevent or miMmize contact wflh this product. Eye wash stations arxi washing facilities should be reality accessible. See 29 CFR 1310.132-138. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & Storing: Keep container tightly closed. Store in a coat, dry area. Do riot freeze. Do not store above 120°F. Do not mix with other chemists. Other Pregutions: Keep out of reach of dtitdren. O SCC 411051200fi Name: Ronald T. Cook Tt~: Manager, Regulatory Affairs L.O.E. STRIPPER Effective Data: 01/05/2006 Supersedes: 06/30/2005 Ref: 29 CFR i91Q120t) (OSHA) Changes: update Sections tl, V, Vi! & VIII This document has been prepared using data from sauces considered technically reAabte. it does not constitute a warranty, express ~ implied, as to the accuracy of the information contained herein. Aauaf conditions of use and handling are beyond sellers control. t,sser is responsible to evaluate aN avaAable information when using product for any panicutar use and to comply with alt Federat, Slate and Local laws aced regulations. Clsrc # 170200 Spartan Chemical Company, Inc. I/t~CAr'7~7 ~N Material Safe Data Sheet ~~s~ '6 ~~ ty ~d.~_/v_31b~ SECTION I; PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: ~ ~ ~ L' CONCENTRATED WINDOW CLEANER Janitorial Product Number. 3060; 3061 Spartan Chemical Company, Inc. ProducUTechnical Information: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemipl LeaklSpii Emergency: CHEMTREC 1-(800) 424-9300 (24 hours) Shipping Description: Flammable liquids, n.o.s., 3, UN 1993, III, (contains isapropanol) NFPA Ratings: HMIS Ratings: Health: 2 -Moderate Health: 2 -Moderate Fire: 3 -Serious Fire: 3 -Serious Reacdvity: 0 -Minimal Reactivity: D -Minimal Pers. Prot. Equip.: See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1 % or greater, carcinogens at 0.1 °,6 or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A CAS Registry ~A = STEL _ GEILING `= NTP, IARC Chemical Name(s) %Wt No. mg/m mglm mglm or OSHA CarGnogen Isopropanol 10-20 67-63-0 980 1225 Not Established No Acetic Acid 1-5 64-19-7 25 3'~ Not Established No , Alkyl polyglycoside 1-5 13277$-08-6 Not Established Not Established Not Established No SECTION III: PHYSICAL DATA Boiling Point: 200 .F Vapor Pressure: Unkhown Vapor Density (AIR = 1): Unknown Solubility in Water: Complete pH; 2.3 Specific Gravity (H,O=1): 0.97 Evaporation Rate (but.ace =1): <1 Percent Solid by Weight: 1_5 Physical State: Liquid ~' Appearance 8 Odor: ,Clean, light blue,, Floral odor SECTION IV: FIRE 8 EXPLOSIVE HAZARD DATA Ftash Poirit: g5°F Flammable Limits: Not Established Method Used: ASTM-D3278 Extinguishing Media: Water, carbon dioxide or dry chemical, Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed containers with water spray. Unusual Fire 8 Explosive Hazards: Combustion products are toxic.: ;~_ _ ~ - Clsrc # 170200 SECTION V: HEALTH HAZARD DATA Threshold Limlt Value: Not established Primary Routes of Entry: Inhalation, Skin Contact, Eyes and Oral Effects of Overexposure- Causes eye and skin irritation: Symptoms may include pain, redness, swelling and tearing Conditions to Avoid: Harmful ii swalktwed: Symptoms may indude nausea, vomiting, pain and diarrhea. Inhalation of product vapors or mist may cause respiratory irritation: Symptoms may include coughing and difficulty breathing. Do not get in eyes, on skin, or on dothing. Do not taste or swallow. Avdd breathing product vapor or mist. Condttions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency 8 First Aid Procedures: -Eyes: Incase of contact; immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. If Irritation persists; seek medical attention. Skin: Remove rnnteminated clothing. Wash skin thoroughly with soap and water. Get medical attention if irritation persists. Wash contaminated dothing before reuse. Ingestion: Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth tp an unconscious parson. Inhalation: In case of respiratory irritation; move person to fresh air. SECTION VI: REACTIVITY DATA Stability: Stable SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Small spills of one gallon or less permitted by local sewer regulati to containers for recovery or SECTION VIII: SPECIAL PROTECTION INFORMATION incompatible Materials: None known Will Not Occur be flushed with plenty of water to sanitary sewer system (If Dike and contain large spills with inert material and transfer liquid and Respiratory Protection: Not normally required when good general ventilation is provided. However if exposure limits are exceeded (see Section il) or if respiratory irritatfon occurs, the use of a NIOSH approved respirator suitable for the use~onditions and chemicals listed in Section it should be considered. Ventilation: provide.good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Spedfy Type): Rubber or other waterproof gloves are recommended when handlino undiluted product. Outer Protective Equipment: For further guidance see 29 CFR 1910.132-138. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling 8 Storing: Flammable liquid and vapor. Do not use or store near heat, sparks and flame. Other Precautions: Keep out of reach of children. ® SCC 03/30/2004 Name: Ronald T. Cook Title: Manager, Regulatory Affairs CONCENTRATED WINDOW CLEANER Effective Date: 03!30!2004 Supercedes: 09/21/99 Ref: 29 CFR 1910.1200 (OSHA) Changes: Update Sections I, II, IV, V, VII, VIII 8 IX This document has bean prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. ~~a MSDS Document for INSPECTOR'S CHOICE Clsrc # 100200 Spartan Chemical Company, Inc. Material Safe Data Sheet (,_UC,~ oN ~~sc-E ~6iN SECTION I: PRODUCT INFORMATION ~~' l~5 /A Product Name or Number (as it appears on label):Product Division: INSPECTOR'S CHOICE Janitorial Product Number: 3045 Spartan Chemical Company, Inc. Product/Technical 1-(800)-537-8990 Information: !D G~ 1110 Spartan Drive Medical Emergency:l-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24 hours) Emergency: .~...,...,ti ...............~ ~ ~ ~~~.~m......~ ~. ~..~,...-.~..~a ~~.~., o. ~ ~ Shipping Description: Corrosive liquids, n.o.s., 8, UN 1760, III, (contains sodium hydroxide); f NFPA Ratings:,'.., , HMIS Ratings:;' Health ..._. .... .....: 3 -Serious Health 3 Serlous ., .. .. .................... ................ .........,.._,,~,,.__........,.,,.,....... .. ....... E .........................,......,.., ....... ...~.a F><re 0 -Minimal Fire:' 0 -Minimal Reactiv><ty '' 0 -Minimal Reachv><ty: 0 -Minimal ~ .. __ _ ' Pers. Prot. Equip.: ~ See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1 % or greater, carcinogens at 0.1 % or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. ~~ ~ Table Z- 1 - A NTP, ....__. ~~~---~ ~ - - IARC or ~~ CAS GEEING mg/ OSHA Chemical Name(s) ~ % W Registry No. `TWA mg/m3 STEL mg/m 3 m3 :Carcinogen f Not Not Not Sodium metasilicate ~ 1-5 6834-92-0 No Established Establlshed Established Tetrasodium ethylene ~ Not Not Not 1-5 64-02-8 No diaminetetraacetate ? Established ~ Established ~ Established Ethoxylated alcohols phosphate ester ~ 1-5 ~ 68130-47-2 Establ shed ~ Established ~ Established ( No ... ................... ... .... .....................«....,.. _.. ,.... ........,.....£ .......,,...,.....,... .. .,....,...... ,......., ~ ............,..... ..,......,....,..« v................... ...... ,. ,..f .. Alkylbenzene sulfonic 1-5 68081-81-2 Not Not Not No 'acid, sodium salt ~ Established Established `. Established http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/6bca235fc5bbOcfc85256f700061e1c4!OpenDocument (1 of 6)7/26/2005 5:27:15 AM ~~ MSDS Document for INSPECTOR'S CHOICE I Sodium hydroxide 1-5 1310-73-2 2 Establ shed Established No Sodium C 14-C 16 olefin Not Not Not sulfonate 1-5 68439-57-6 ~ Established ' Established ': Established No http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/6bca235fc5bbOcfc85256f700061e1c4!OpenDocument (2 of 6)7/26/2005 5:27:15 AM i• MSDS Document for INSPECTOR'S CHOICE SECTION III: PHYSICAL DATA Appearance & Odor `Clear light yellow liquid, soapy odor SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point > 212°F Method Used ASTM-D56 __ Flammable Llmrts N/A Flame Extension ' N/A Extinguishing Media:' Product does not support combustion. Use extinguishing media appropriate for t surrounding fire. Special Fire Fighting `; Wear NIOSH approved self-contained breathing apparatus and protective ~ Procedures:; clothing. Cool fire-exposed containers with water spray. Unusual Fire & Expl _ __ _ _~_.__ .. ~._...~......_ olive "Combustion products are toxic. ' Hazards:. i ~' SECTION V: HEALTH HAZARD DATA Threshold Limit Value::` Not Established ~~ Primary Routes of :Inhalation, Skin Contact, Entry: ~ Eyes & Oral Effects of Overexposure- (CORROSIVE: Conditions to Avoid:: Causes eye burns: Causes severe eye damage or irritation with symptoms of '; pain, redness, swelling of the conjunctiva and possible permanent corneal damage. Causes skin burns: Causes severe skin damage or irritation with symptoms of 'pain, redness and chemical burns. Harmful contact may not cause immediate Harmful if swallowed: Causes damage or chemical burns to esophagus and mucous membranes with symptoms of pain, nausea, vomiting and diarrhea. Harmful if inhaled: Breathing product vapor or mist may cause irritation or damage of the respiratory tract, with symptoms of nasal discomfort and discharge with chest pain and coughing. Do not get in eyes, on skin or on clothing. Do not breathe product vapors or mist. Do not swallow. Use with adequate ventilation. Wash thoroughly after http://www.spartanchemical.com/sfa/MSDSRep.nsf/I8ce1...619f51/6bca235fc5bbOcfc85256f700061e1c4!OpenDocument (3 of 6)7/26/2005 5:27:15 AM Eyes:' Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin:' Remove contaminated clothing and shoes. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Destroy contaminated shoes. ~ Ingestion: Call a poison control center or doctor immediately for treatment advice. Do not ? induce vomiting. Drink one or two glasses of water to dilute product. Do not give 3 ; .. _.M_... ___ ...._~_....... ~.. __ . anything by mouth to an unconscious person. ... _ .~__.__. _....... _ ...~..___ ,......___._ _._.... Inhalation: In case of respiratory irritation; move person to fresh air. Get medical attention '' immediately. http:/lwwwspartanchemical.comisfa/MSDSRep.nsf/18ce1...619f51/6bca235fc5bbOcfc85256f700061e1c4!OpenDocument (4 of 6)7126!2005 5:27:15 AM x~ ~. MSDS Document for INSPECTOR'S CHOICE SECTION VI: REACTIVITY DATA SECTION VII: SPILL OR LEAK PROCEDURES t Steps to be Taken in Case; Dike and contain spill with inert material (sand, earth, commercial absorbent, Material is Released or etc.) and transfer to containers for disposal. Rinse area with water and flush to Spilled:: sanitary sewer. Keep spill out of storm sewers and waterways. .._ ___ ~ Waste Disposal Method Dispose of m compliance with all federal, state and local laws and regulatlons. ___ . _ _ __. ___ __._ _. _...._ ~... _._._,, .. _ ...._...__ _.~..a SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection:' None expected to be required when good general ventilation is provided. i ` However if respiratory irritation occurs, a NIOSH approved respirator suitable for the use conditions and chemicals listed in Section II should be considered. Ventilation:; Provide good general ventilation. Local exhaust ventilation may be necessary for ~ : some operations. .__~...._.....~. ~....__ ~...~. ~.__r~. ~..,_ _.. ..~..... .. __~......._ ~_. . Protective Gloves(Specify Rubber or other impervious gloves are recommended. ~ TYpe) i Eye Protection(Specify ° Splash goggles are recommended to prevent eye contact. TYPe):' ~ Other Protective Equipment: = Use of impervious apron, face shield and other protective equipment should be ' considered in order to prevent or minimize contact with this product. Eye wash stations and washing facilities should be readily accessible. See 29 CFR 1910.132-138. SECTION IX: SPECIAL PRECAUTIONS NPrecautions; Handling & Keep container closed when not In use. Store in a cool, dry area. Do not mix with Storing. other chemicals. ~. [~" Other Precautions ;Keep out of reach of children. ,i .~ . _._.._ . a.....~._ ,...._ .~.~..~. © SCC 06!3012005 Name: Ronald T. Cook Title: Manager, Regulatory Affairs http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/6bca235fc5bbOcfc85256f700061e1c4!OpenDocument (5 of 6)7/26/2005 5:27:15 AM ~~ f ,,. MSDS Document for INSPECTOR'S CHOICE INSPECTOR'S CHOICE Effective 06/30/2005 Supercedes: 03/15/2005 Date: Ref: 29 CFR 1910.1200 Changes: Update Section IX (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/6bca235fc5bbOcfc85256f700061e1c4!OpenDocument (6 of 6)7/26/2005 5:27:15 AM ~ ~ MSDS Document for INSPECTOR'S CHOICE Spartan Chemical Company, Inc. ~ Material Safety Data Sheet ~~ ~ SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label):Product Division: INSPECTOR'S CHOICE Janitorial Product Number: 3045 Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee OH 43537 Shipping D~~ ~, p~ ~ .a ,n_s .. ~ .~ escrl tin Corrosive liquids, n o.s., 8, UN 1760, III, (contains sodium hydroxide):, NFPA Ratings: HMIS Ratmgs ~- .., . . Health:. 3 - Seri _- ~_. .. _ _ ~___ _. _ ..... _. ...._. ous ~ Health 3 -Serious .. ~. __ .. .. _ -Fire: 0 -Minimal Fire. 0 -Minimal __ ... Reactivity:. 0 -Minimal ~i Reactivity 0~-- Minimal Pers. Prot. Equip.: -See Section VIII ~ SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1 % or greater, carcinogens at 0.1 % or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency: Table Z- 1 - A NTP, _ IARC or CAS GEEING mg/ ; pSHA Chemical Name(s) % W Registry No. 'TWA mg/m3 STEL mg/m 3 m3 Carcinogen; Sodium metasilicate 1-5 6834-92-0 Estabi shed Established Established No Tetrasodium ethylene Not Not Not diaminetetraacetate 1-5 64-02-8 Established Established Established ' No Ethoxylated alcohols Not Not Not phosphate ester 1-5 68130-47-2 Established Established Established No Alkylbenzene sulfonic Not Not Not acid, sodium salt 1-5 68081-81-2 Established Established Established No Clsrc # 100180 ~,vc ~-n oly ~-~5~ ~~~ ~v_a-/o5/ ~ ~~ 1(o G~. Product/Technical l-(800)-537-8990 Information: Medical Emergency:l-(888)-314-6171 (24 hours) Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24 hours) Emergency: http://www.spartanchemicaLcon~/sfa/M SDSRep.nsf/ 18ce 1...619f51 /6bca235fc56bOcfc85256f100061 e 1 c4!OpenDocument (1 of 6)7/26/2005 5:27:15 AM MSDS Document for INSPECTOR'S CHOICE Sodium hydroxide 1-5 1310-73-2 '' 2 ' Established Established No Sodium C 14-C 16 olefin 1 5 68439-57-6 Not Not Not No sulfonate Established Established Established ~ , i, ... .............. ........ ... ........,. .. ._... ... .i ....,,,,...... .__..... ... .: ...... ._.... ...... ... ._...... ... .....,., ......,...._ ........: http://wwwspartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/6bca235fc5bbOcfc85256f700061e1c4!OpenDocument (2 of 6)7/26/20055:27:(5 AM ~ , MSDS Document for INSPECTOR'S CHOICE ~ SECTION III: PHYSICAL DATA __ Appearance & Odor: Clear light yellow liquid, soapy odor SECTION IV: FIRE & EXPLOSIVE HAZARD DATA ~.~ __.. ._~...w ..-Flash Point: > 212 F ~ Method~~~~~_.~ ... _o w_., Used: ~ASTM-D56 Flammable Limits: N/A Flame Extension: N/A F Extinguishing Media:: Product does not support combustion. Use extinguishing media appropriate for ' ~ 'surrounding fire. Special Fire Fighting Wear NIOSH approved self-contained breathing apparatus and protective `~ Procedures: clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive j Combustion products are toxic. Hazards: ° SECTION V: HEALTH HAZARD DATA _.... ..... ~... .~ .. .w....,~..._._. _ . ~~~ __ ....~ ._, _ _ .. ..m..,_ _.~._.__ _~...._.... Threshold Limit Value: Not Established Primary Routes of Inhalation, Skin Contact, Entry: Eyes & Oral Effects of Overexposure- CORROSIVE: Conditions to Avoid: Causes eye burns: Causes severe eye damage or irritation with symptoms of pain, redness, swelling of the conjunctiva and possible permanent corneal damage. Causes skin burns: Causes severe skin damage or irritation with symptoms of pain, redness and chemical burns. Harmful contact may not cause immediate pain. Harmful if swallowed: Causes damage or chemical burns to esophagus and mucous membranes with symptoms of pain, nausea, vomiting and diarrhea. Harmful if inhaled: Breathing product vapor or mist may cause irritation or damage of the respiratory tract, with symptoms of nasal discomfort and discharge with chest pain and coughing. Do not get in eyes, on skin or on clothing. Do not breathe product vapors or mist. Do not swallow. Use with adequate ventilation. Wash thoroughly after http://www.spartanchemicaLcomlsfa/MSDSRep.nsf/18ce1...619f51/6bca235fc5bbOcfc85256f700061e1c4!OpenDocument (3 of 6)7/26/20055:27:15 AM =r 4 MSDS Document for INSPECTOR'S CHOICE ~~ ` handling. Conditions Aggravated by ! Use of this product may aggravate preexisting skin; eye and respiratory disorders Use:; including asthma and dermatitis. Emergency & First Aid Procedures: ..r_.,_,..__._ ..__._ _~._ _._ .._..__. __~ ._ _._ ._ .~ ~ Eyes:' Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin:; Remove contaminated clothing and shoes. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Destroy contaminated shoes. Ingestion: Call a poison control center or doctor immediately for treatment advice. Do not ' induce vomiting. Drink one or two glasses of water to dilute product. Do not give anything by mouth to an unconscious person. Inhalation: In case of respiratory irritation; move person to fresh air. Get medical attention E immediately. http;//www.spartanchemical.com/sfa/MSDSRep.nsf/ 18ce 1...619f51 /6bca235fc5bbOcfc85256f700061 e I c4! OpenDocument (4 of 6)7/26/ZOOS 5:27:15 AM MSDS Document for INSPECTOR'S CHOICE ~ SECTION VI: REACTIVITY DATA ~ SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Dike and contain spill with inert material (sand, earth, commercial absorbent, Material is Released or ; etc.) and transfer to containers for disposal. Rinse area with water and flush to Spilled:! sanitary sewer. Keep spill out of storm sewers and waterways. Waste Disposal Method: Dispose of in compliance with all federal, state and local laws and regulations. ~ SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: ` None expected to be required when good general ventilation is provided. However if respiratory irritation occurs, a NIOSH approved respirator suitable for the use conditions and chemicals listed in Section II should be considered. Ventilation:'..; Provide good general ventilation. Local exhaust ventilation maybe necessary for some operations. Protective Gloves(Specify Rubber or other impervious gloves are recommended. Type):' Eye Protection(Specify ; Splash goggles are recommended to prevent eye contact. Type)::. Other Protective Equipment:: Use of impervious apron, face shield and other protective equipment should be considered in order to prevent or minimize contact with this product. Eye wash stations and washing facilities should be readily accessible. See 29 CFR 1910.132-138. ~ SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & E Storing:, _. Keep container closed when not in use. Store in a cool, dry area. Do not mix with other chemicals. .. _ ~~ Other Precautions: Keep out of reach of children. © SCC 06/30/2005 Name: Ronald T. Cook Title: Manager, Regulatory Affairs http://wa~~.spartanchemical.com/sfa/MSDBRep.nsf/ 18ce 1...619f51 /6bca235fc5bbOcfc85256f700061 e 1 c4!OpenDocument (5 of 6)7/26/2005 5:27:15 AM MSDS Document for INSPECTOR'S CHOICE INSPECTOR'S CHOICE Effective 06/30/2005 Supercedes: 03/15/2005 Date: Ref: 29 CFR 1910.1200 .Changes: Update Section IX (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. http://wwwspartanchemical.com/sfa/MSDSRep,nsf/18ceL..619f51/6bca235fe5bbOcfc85256f700061e1c4!OpenDocument (6 of 6)7/26/20055:27:15 AM M_ _ , ;~ ~- _ Clean Source San Jose, CA 95112 1711 Rogers Ave Emergency: 8000-25+ 5~39.2~4 ?~ ON~ MATERIAL SAFETY DATA SHEET L..c,J~. SECTION 1. IDENTIFICATION OF PRODUCT ~1~-E/~y~(3!/1Q/ ~ -~ Name: NEUTRAL CLEANER 400 ~~i~«P~C~_/..,/ Identity: Neutral Ftoor Cleaner MSDS Number: C2L400 date: 4/23/2004 Supersedes: 4123/2004 TOXICITY: 1 FIRE: 0 REACTIVITY: 0 PROTECTION: A SECTION II. HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Name CAS Number PEL TLV Quaternary Ammonium Chlorides Mixture NE NE SECTION III. PHYSICAL/CHE MICAL CHARACTERISTICS Boiling Point: Specific Gravity: Vapor Pressure Melting Point: 212E 1.001 (mm Hg.): Nb ND Vapor Density Evaporation Water Solubility: pH @ 77F: (Air = 1): ? (H20 = 1):1 Complete 10.00 +/- 0.5 VOCgm/L: 0 Appearance and Odor: Clear greenish-yellow liquid. Lemon odor SECTION IV. FIRE AND EXPLOSION HAZARD DATA Flash Point (TCC): % LEL: % UEL: Flammable Limits: None ND ND NA Extinguishing Media: Water fog, foam, carbon dioxide or dry chemical Special Fire Fighting Procedures: Prevent breathing vapors. Wear SCBA and protective clothing. Unusual Fire and None known SECTION V. HEALTH HAZARD DATA Route(s) of Entry: INHALATION? Yes EYES? Yes .SKIN? No INGESTION? Yes (Acute) Health Hazards: Eyes: May cause irritation, discomfort Skin: May cause dryness, irritation Ingestion: May cause gastric distress Inhalation: Not likely to cause ill effects (Chronic) Health Hazards: None Known Signs and Symptoms of Exposure: Eyes: Redness, irritation Skin: Not likely to cause ill-effects Ingestion: Abdominal discomfort. Inhalation: Not likely to be injurious Medical Conditions Generally Aggravated by Exposure: Pre-existing disorder at contact site. Emergency First Aid Procedures: Eyes: Flush eyes with large amounts of water, lifting upper and lower eyelids. If irritation persists, obtain medical attention. Skin: Wash off with soap and water. Remove contaminated clothing and wash before reuse. If irritation persists, obtain medical attention. Ingestion: Obtain immediate medical attention. Inhalation: Remove to fresh air. If irritation persists, obtain medical attention. C2L4OO FORM 4.4 K: 4/23/2004 Supersedes 4/23/2004 Revision No. 0 ~~ SECTION VI. TOXICITY DATA Carcinogenicity: NTP? No IARC No OSHA REGULATED? No SECTION VII. REACTIVITY DATA Stability: Stable Hazardous Polymerization Will Not Occur Incompatibility (Materials to Avoid: None known Hazardous Decomposition Byproducts: Oxides of carbon SECTION VIII. PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be Taken in Case Material is Released of Spilled: Small Spills: Mop up and put in empty container and cover Large Spills: Mop up or vacuum up Disposal: Meet Federal, State 8 Local Requirements Handling and Storage: Store in cool, dry well ventilated area. Keep container tightly closed when not in used. Other Precautions: Keep out of reach of children. FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY. SECTION iX. CONTROL MEASURES Respiratory Protection: Not normally indicated when used as directed Ventilation: Normal indoor Local Exhaust: Not indicated Explosion:Mechanical (Geheral):. Not normally indicated Protective Gloves: Latex, optional Eye Protection: Chemical safety goggles; optional Other Protective Clothing or Equipment: Long pants, sleeves, apron Work/Hygienic Practices: The recommendations described in this section are provided as general guidance for minimizing exposure when handling this product. Because use conditions will vary, depending upon customer applications, specific safe handling procedures should be developed by persons knowledgeable of the intended use conditions and equipment. SECTION X. DOT INFORMATION NOT REGULATED SECTION XI. MISCELLANEOUS INFORMATION SARA 313: NO Notice: All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from the manufacturer andlor recognized technical sources; however, manufacturer makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of the product. NA -Not S -May Be Absorbed Through Intact ND - No Data Supersedes: 4/23/2004 C2L400 FORM 4.4K: 4/23/2004 Supersedes 4/23/2004 Revision No. 0 `' Flo-Kem, 19402 Susana Road MATERIAL SAFETY DATA SHEET SECTION 1. IDENTIFICATION OF PRODUCT Name: CLEANE SOURCE 500 CLEANER Identity: Cleaner-Degreaser MSDS Number: C2L500 Date: 06/03/1999 TOXICITY: 2 FIRE: 0 REACTIVITY: 0 Clsrc # 141500 Rancho Dominguez, CA 90221 Emergency: 800-255-3924 LO CA'T1 on/~ ~}-/scc E3/N CD_oz GYPI Supersedes: 06/03/1999 PROTECTION: B SECTION II. HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Name CAS PEL TLV Ethanolamine 141-43-5 3 ppm 3 ppm Sodium Metasilicate 6834-29-0 NE NE SECTION III. PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Specific Gravity: Vapor Pressure ~ Melting Point: 212° F 1.041 (mm Hg.): ND ND Vapor Density Evaporation Water Solubility: pH @ 77F: (Air = 1): 1 (H20 = 1):1 Complete 12.25 VOCgm/L: 0 Appearance and Odor: Clear blue-green liquid, Scented SECTION IV. FIRE AND EXPLOSION HAZARD DATA Flash Point (TCC): % LEL: % UEL: Flammable Limits: >200F ND ND ND Extinguishing Media: Water fog, foam, carbon dioxide or dry chemical Special Fire Fighting Procedures: None Unusual Fire and Explosion: None SECTION V. HEALTH HAZARD DATA Route(s) of Entry: INHALATION? No EYES? Yes SKIN? Yes INGESTION? Yes (Acute) Health Hazards: Eyes: May cause stinging, pain, irritation Skin: Prolonged or repeated contact may cause irritation Ingestion: May cause headache, nausea, vomiting and abdominal distress Inhalation: Mist may irritate nasal passages (Chronic) Health Hazards: Prolonged or repeated skin contact may cause skin irritation. This product is not Isited as or anticipated to be a potential carcinogen by NTP or OSHA. Signs and Symptoms of Exposure: Eyes: Redness, irritation, blurring of vision Skin: Repeated or prolonged contact may result in irritation Ingestion: Severe irritation to digestive tract Inhalation: Irritation above exposure levels. Medical Conditions Generally Aggravated by Exposure: Pre-existing contact site disorders of the kidneys, liver, skin, and hematopoietic system Emergency First Aid Procedures: Eyes: Flush eyes with large amounts of water, lifting upper and lower eyelids. If irritaion persists, obtain medical attention. Skin: Wash off with soap and water. Remove contaminated clothing and wash before reuse. If irritation persists, get medical attention. Ingestion: Obtain immediate medical attention. Inhalation: Remove to fresh air. If irritation persists, obtain medical attention. ao G~ CZL5OO FORM 4.4K: 06/03/1999 Supersedes 06/03/1999 Revision No. 0 ~ , _. SECTION VI. TOXICITY DATA Carcinogenicity: NTP? No IARC MONOGRAPHS? No OSHA REGULATED? No SECTION VII. REACTIVITY DATA Stability: Stable Hazardous Polymerization Wiil Not Occur Incompatibility (Materials to Avoid): Cleaning agents may or may not react Hazardous Decomposition Byproducts: Oxides of carbon and sulfur SECTION VIII. PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be Taken in Case Material is Released of Spilled: Small Spills: Slippery. Contain with inert materials,sand or earth and transfer into containers for proper disposa Large Spills: Dike area and absorb into neutral material or pump up Disposal: Meet Federal, State 8~ Local Requirements Handling and Storage: Store in cool, dry well ventilateii area. Keep container tightly closed when not in used. Other Precautions: Keep out of reach of children. FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY. SECTION IX. CONTROL MEASURES Respiratory Protection: -Not normally indicated Ventilation: Normal indoor Local Exhaust: Not normally indicated Mechanical (General): Not normally indicated Protective Gloves: Impervious Eye Protection: ANSI Z87 Other Protective Clothing or Equipment: Long pants, sleeves, apron WorkfHygienic Practices: The recommendations described in this section are provided as general guidance for minimizing exposure when handling this product. Because use conditions will vary, depending upon customer applications, specific safe handling procedures should be developed by persons knowledgeable of the intended use conditions and equipment. SECTION X. DOT INFORMATION ;; NOT REGULATED SECTION X1. MISCELLANEOUS INFORMATION SARA 313: No Notice: All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from the manufacturer and/or recognized technical sources; however, manufacturer makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of the product. NA -Not Applicable S -May Be Absorbed Through Intact Skin ND - No Data Available Supersedes: 06/03/1999 C2L500 FORM 4.4K: 06/03/1999 Supersedes 06/03/1999 Revision No. 0 s `;i - Clsrc # 148151 Flo-Kem, Inc. Rancho Dominguez, CA 90221 19402 Susana Rd. Emergency: 800-255-3924 MATERIAL SAFETY DATA SHEET ~ (, e ~T/O A/5 ~~ NAME: STRIPPER 815 Identity: Floor Stripper TOXICITY: 2 SECTION II Name 2-Butoxyethanol Ethanolamine SECTION I. IDENTIFICATION OF PRODUCT CDo~~U 4 _A~-~ MSDS Number: C2L815 FIRE: 0 REACTIVITY: 0 . HAZARDOUS INGREDIENTS/IDENTITY I CAS Number PEL 111-76-2 25 ppm (skin) 141-43-5 Date: 6-3-99 ~~ GL PROTECTION: C vFORMATION TLV 25 ppm (skin) 6 ppm 3 ppm STEL SECTION III. PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Specific Gravity: Vapor Pressure Melting Point: 212 F 1.026 (mm Hg.): ND ND Vapor Density: Evaporation: Water Solubility: pH @ 77 F: (Air = 1): 1 (H2O=1): 1 Complete 13.85 Appearance and O dor: Clear Red Orange liquid; Scented. SECTION IV. FIRE AND EXPLOSION HAZARD DATA Flash Point (TCC): LEL: UEL: Flammable Limits: None NE NE NA Extinguishing Media: Appropriate to fire fuel source. Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazards: None SECTION V. HEALTH HAZARD DATA Route(s) of Entry: INHALATION? No EYES? Yes SKIN? Yes INGESTION? Possible (Acute) Health Hazards: Eyes: Contact with eyes may cause damage. Skin: Contact with skin may cause irritant reaction. Ingestion: Swallowing may cause gastric distress. Inhalation: Breathing a mist may cause sneezing. (Chronic) Health Hazards: 2-Butoxyethanol is readily absorbed through the skin where it exerts a toxic effect on the liver, kidneys, and hematopoietic systems. Signs and Symptoms of Exposure: Eyes: Burning. Skin: Wet Feeling. Ingestion: Nausea and vomiting. Inhalation: Sneezing if mist generated. Medical Conditions Generally Aggravated by Exposure: Preexisting disorders of the skin, liver, kidneys, and hematopoietic system. Emergency and First Aid Procedures: Eyes: Flush eyes with large amounts of water, lifting upper and lower eyelids. If irritation persists, obtain medical attention. Skin: Wash off with soap and water. Remove contaminated clothing and wash before reuse. If irritation persists, obtain medical attention. Ingestion: Obtain immediate medical attention. Inhalation: Remove to fresh air. If irritation persists, obtain medical attention. SECTION VI. TOXICITY DATA Carcinogenicity: NTP? NO IARC MONOGRAPHS? NO OSHA REGULATED? NO C2L815 Z !~ SECTION VII. REACTIVITY DATA Stability: Stable Hazardous Polymerization Will Not Occur Incompatibility (Materials to Avoid): Other cleaning agents may or may not react. Hazardous Decomposition Byproducts: Oxides of carbon and sulfur. SECTION VIII. PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be Taken in Case Material is Released or Spilled: Small Spills: Mop up. Large Spills: Dike area and absorb into neutral material or pump up. Disposal: As allowed by Federal State and Local requirements. Many jurisdictions allow small amounts into the sanitary sewer. Handling and Storing: Store in a cool, dry, well ventilated area. Keep container tightly closed when not in use. Other Precautions: Keep out of reach of children. For industrial and institutional use only. SECTION IX. CONTROL MEASURES Respiratory Protection: Not normally indicated Ventilation: Normal indoor ventilation Local Exhaust: Not normally indicated Mechanical (General): Not normally indicated Special: N/A Other: N/A Protective Gloves: Rubber or vinyl. Eye Protection: ANSI Z87 Other Protective Clothing or Equipment: Long pants and sleeves. WorWHygienic Practices: The recommendations described in this section are provided as general guidance For minimizing exposure when handling this product. Because use conditions Will vary, depending upon customer applications, specific safe handling procedures should be developed by persons knowledgeable of the intended use conditions and equipment. SECTION X. DOT INFORMATION #171 Compounds Cleaning Liquids (Amines),8, NA 1760,PGIII SECTION XI. MISCELLANEOUS INFORMATION SARA 313: Contains 2-butoxyethanol as noted above. Notice: All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from the manufacturer and/or recognized technical sources; however, manufacturer makes no warranty, representation or guaranty as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of the product. NA =Not Applicable S -May Be Absorbed Through Intact Skin ND - No Data Available C2L815 .-, 1 ~' ~~ l Z_I_I~~ 1 ~f l Z12 Clean Source San Jose, Ca 95112 1711 Rogers Ave. Emergency: B00-255-3924 MATERIAL SAFETY DATA SHEET C~jC~.~ pN~ SECTION 1. IDENTIFICATION OF PRODUCT GE t3l_ E}LS Name: TILE MASTER PLUS n ~Da ~~~ Identity: Tub & Tile Cleaner MSDS Number: C2L210 Date: 4/23/2004 S upersedes: 4 3/2004 TOXICITY: 3 FIRE: 0 REACTIVITY: 0 PROTECTION: D 5~ G(,,,, ~u SECTION Ii. HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Name CAS Number PEL TLV Phosphoric Acid 7664-38-3 1 mg/ a 1 mg! 3 15 SECTION Iil. PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point: Specific Gravity: Vapor Pressure Melting Point: 212° F 1.090 (mm Hg.): ND ND Vapor Density .Evaporation Water Solubility: pH @ 77F: (Air = 1): 1 (H20 = 1):1 Complete <1.00 VOCgmfL: 0 Appearance and Odor: Clear red liquid, Acrid odor SECTION IV. FIRE AND EXPLOSION HAZARD DATA Flash Point (TCC): % LEL: % UEL: Flammable Limits: None ND ND ND Extinguishing Media: Water fog, foam, carbon dioxide or dry chemical. Do not use stream of water. Special Fire Fighting Procedures: Prevent breathing vapors. Wear SCBA and impervious protective clothing. Unusual Fire and Contact with reactive metals may release hydrogen gas SECTION V. HEALTH HAZARD DATA Route(s) of Entry: 1NHALATiON? Yes EYES? Yes SKIN? Yes INGESTION? Yes (Acute) Health Hazards: Eyes: Corrosive. Causes eye burns. May cause permanent damage Skin: Corrosive. Causes skin burns. It may not produce an immediate burning sensation upon skin contact, delaying the awareness of worker that contact has occurred. Ingestion: May result in vomiting causing aspiration pneumonitis. Inhalation: May produce irritation of eyes, nose, or upper respiratory tract with coughing and sore throat. (Chronic) Health Hazards: None Known Signs and Symptoms of Exposure: Eyes: Immediate burning sensation Skin: Redness, pain, burns, skin blistering Ingestion: Harmful if swallowed. May cause nausea, vomiting and a burning sensation. Inhalation: Occasional mild irritation effects to nose and throat may occur. Medical Conditions Generally Aggravated by Exposure: Pre-existing contact site disorders. Emergency First Aid Procedures: Eyes: Immediately flush eyes with large amounts of water for about 15 minutes. Hold eyelids apart during the flushing to ensure thorough rinsing. Skin: Immediately flush all affected areas with large amount of running water for at least 15 minutes. Remove and discard contaminated clothing and shoes. Get medical attention. Ingestion: DO NOT INDUCE VOMITING. Do not give anything to drink. Obtain medical attention without delay. Inhalation: Remove to fresh air. If irritation persists, obtain medical attention. C2L210 i=ORM 4.4K: 4/23/2004 Supersedes 4/23/2004 Revision No. 0 ~„F_ r_ n SECTION VI. TOXICITY DATA Carcinogenicity: NTP? No IARC No OSHA REGULATED? No SECTION VII. REACTIVITY DATA Stability: Stable Hazardous Polymerization Will Not Occur Incompatibility (Materials to Avoid): Water reacts vigorously and violently with all common chemicals. Hazardous Decomposition Byproducts: Thermal decomposition may include toxic & corrosive fumes of ammonia SECTION VIII. PRECAUTIONS FOR SAFE HANDLING AND USE Steps to be Taken in Case Material is Released of Spilled: Small Spills: Neutralize with soda ash and mop up. Large Spills: Dike area and absorb into neutral material or pump up Disposal: Meet Federal, State & Local Requirements Handling and Storage: Store in cool, dry well ventilated area. Keep container tightly closed when not in used. Other Precautions: Keep out of reach of children. FOR INDUSTRIAL AND INSTITUTIONAL USE ONLY. SECTION IX. CONTROL MEASURES Respiratory Protection: NIOSH approved acid respirator Ventilation: Recommended if generating mist or vapors Local Exhaust: Not normally indicated when used as directed. Explosion:Mechanical (General): Not normally indicated unless mist is generated Protective Gloves: Rubber, vinyl Eye Protection: ANSI 287 Other Protective Clothing or Equipment: Long pants, sleeves, apron Work/Hygienic Practices: The recommendations described in this section are provided as general guidance for minimizing exposure when handling this product. Because use conditions will vary, depending upon customer applications, specific safe handling procedures should be developed by persons knowledgeable of the intended use conditions and equipment. SECTION X. DOT INFORMATION COMPOUNDS, CLEANING LIQUID (Phosphoric Acid), 8, NA 1760, PGIII SECTION XI. MISCELLANEOUS INFORMATION SARA 313: Phosphoric Acid Notice: All information, recommendations, and suggestions appearing herein concerning this product are based upon data obtained from the manufacturer and/or recognized technical sources; however, manufacturer makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user's responsibility to determine the safety, toxicity and suitability of his own use, handling and disposal of the product. NA -Not Supersedes: 4/23/2004 S -May Be Absorbed Through Intact ND - No Data C2L210 FORM 4.4K: 4/23/2004 Supersedes 4/23/2004 Revision No. 0 (~Ctsrc #"1-60020 ~ Spartan Chemical Company, Inc. ~ 0~ ~~ ~ "~-' Material Safe Data Sheet ~'l~LE g~A/ . o /_0_9 /_c-~ SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label): Product Division: ~~ ~+~ BLOC-AID Janitorial (~~ ~ Product Number: 7380; 7585 Spartan Chemical Company, Inc. PraducUTechnical tnfom'tation: 1-(800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil Emergency: CHEMTREC 1-(800j 424-9300 (24 hours) Shipping Description: Corrosive liquids, n.o.s., 8, UN 1760, II, (contains sodium hydroxide) NFPA Ratings: HMIS Ratings: He9fth: 4 -Extreme Health: 4 -Extreme Fire: 0 -Minimal Fire: 0 -Minimal Reactivity: 1-Slight Reactivity: 1-Slight Pers. Prot. Equip.: See Seaton VIII SECTION it: HAZARDOUS INGREDIENTS (Listed when present at 1 ~ or greater, carcinogens at 0.1 % or greater) All component chemicals are listed or exempted from listing on the 'TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z-1-A RC~ ~ ry TWAT STEL CEILING NTP, IARC Chemical Name(s) 9oWt No. mg/m mg/m mg/m or OSHA Carcinogen Sodium h droxide 30-40 1310-73-2 2 Not Established Not Established No SECTION III: PHYSICAL DATA Boiling Point: 255 °F Vapor Pressure: Unknown Vapor Density (AIR = 1): Unknown Solubility in Water. Complete pH: > 13.5 Specific Gravity (H,O=1): 1.38 Evaporation Rate (but.ace =1): <1 Percent Solid by Weight: 30-40 Physical State: Liquid Appearance 8 Odor: Clear red liquid, no odor SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point: > 255 °F Method Used: ASTM-D56 EMinguishing Media: Product does not support combustion. Use extinguishing media appropriate for surrounding fire. Special Fire Fighting Procedures: Wear N10SH approved self-contained breathing apparatus and protective clothing. Cool fire-exposed containers with water spray. Unusual Fire 13, Explosive Hazards: Products of combustion are toxic. Y~ Clsrc # 160020 SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Not Established ~ Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- CORROSIVE: Conditions to Avoid: Causes irreversible eye damage. Symptoms include pain, tissue destruction, swelling and chemical bums. Causes severe skin damage. Symptoms include pain, tissue destruction and chemical bums. Harmful or fatal if swallowed. Ingestion pn produce pain, irritation and damage to mouth, throat and gastrointestinal tract possibly leading to death. Product is considered to be a poison. Inhalation of product mist may cause respiratory system damage or irritation. Do not get in eyes on skin or clothing. Do not taste or swallow. Avoid breathing product mist. Wash thoroughly after handling. Conditions Aggravated by Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders including asthma and dermatitis. Emergency 8 F rst Aid Procedures: Eyes: Hold eye open and rinse slowly and gently withwaterfor i5-20 minutes. Remove contact lenses after the first 5 minutes then continue rinsing eye. Get immediate medical attention. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Get medical attention. Wash contaminated clothing before reuse. Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not Induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. NOTE TO PHYSICIAN: Probable mucosal damage may contraindipte the use of gastric lavage. Inhalation: Incase of respiratory irritation; move person to fresh air. Get medical attention if Irritation persists. SECTION VI: REACTNITY DATA Stability: Stable ~ Incompatible Materials: Strong oxidizers Hazardous Decomposition Products: CO, CO, ~ Hazardous Polymerization: Will Not Occur SECTION Vff: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Dike and wntain spill with inert material (sand ,earth, etc.) and transfer the liquid and solid separately to containers for recovery and disposal. Keep spill out of sewers and open bodies of water. Waste Disposal Method: Dispose of in compliance with all Federal, state and local laws and regulations. Incineration is the preferred method. SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section 11 should be considered. Ventilation: provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gioves(Spedfy Type): Rubber or neoprene gloves are recommended to prevQnt skin contact. Other Protective Equipment:' Eye wash stations and washing facilities should be readily accessible. See 29 CFR 1910.132-138 for further guidance. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling 8 Storing: Keep from freezing. Store at temperatures below 140 F. Keep containers closed until used. Do not contaminate drinking water; food or feed by storage or disposal. Other Precautions: Keep out of reach of children. ® SCC 03!30/2004 Name: Ronald T. Cook Title: Manager, Regulatory Affairs BLOC-Alt) Effective Date: 03/30/20D4 Supercedes: 09/21!99 Ref: 29 CFR 1910.1200 (OSHA) Changes: Update Sections I, III, IV, V, VII, VIII 8 IX This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as ~! to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Lop! laws and regulations. .~ ~ ti MSDS Document for ORANGE TOUGH IS Clsrc # 100460 Spartan Chemical Company, Inc. ty . ~~ Material Safe Data Sheet ~' SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label):Product Division: ORANGE TOUGH 15 Product Number: 2215; 2216 Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee OH 43537 Janitorial Product/Technical 1-(800)-537-8990 Information: ~~,(Z-5 Medical Emergency:l-(888)-314-6171 (24 hours) Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24 hours) Emergency: Shipping Descrlptlon ;Cleaning compounds, liquid, n.o.s. NFPA Ratings: ~ HMIS Ratings:'; _... _.~..... _.~ . ............. ~ _..._.. _..._ .. ~.. ~____....._., .~~ _............... ___v_... ~....~ .... ~_ Health:?.. 2 -Moderate ~ Health:; 2 -Moderate { ! Fire ~ 1 Slight ......._~. ~.. _.... ~ _ _ _......~~.....~ ....; ~ _ .........~....~. ~ Fire 1 Slight ...::......... ~_ . ~_._ .. ~_ ~ _ Reactivity:€ 0 -Minimal Reactivity:'. 0 -Minimal Pers. Prot Equip ;See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1 % or greater, carcinogens at 0.1 % or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z- 1 - A NTP, ~~~"""~~~ ~ IARC or CAS :GEEING mg/ £ OSHA ' Chemical Name(s) % W 'Registry No. TWA mg/m3 '' STEL mg/m 3 m3 `Carcinogen Triethanolamine Not Not Not dodecylbenzenesulfonate 5-10 27323-41-7 Established ' Established Established: No Dipropropylene glycol Not Not Not monobutyl ether 5-10 29911-28-2 ~ Established Established Established ? No Triethanolamine 1-5 102-71-6 ~ 5 (ACGIH) Not Not No Established Established ., ____ Soybean oil methyl esters 1-5 67784-80-9 Established ' Established s Established ' No ~ _ __... _r..... _..__.___~. ~ _____~ ~~ _ _- - --_ ......_._ ..~... ~. _ _ ._ ~_.~~_...r .... _ _. _ ~..~...~.~ __~..~.. Ct~~q_T_! oN va o_9~c-_3~ http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/addclcada4ed5d1785256efc006c9ce8!OpenDocument (1 of 6)7/26/2005 7:07:18 AM MSDS Document for ORANGE TOUGH 15 d-Limonene 1-5 ~ 5989-27-5 Not Not Not No Established Established Established ': Alcohol ethoxylate 1-5 34398-01-1 Not Not Established F Established Not Established No http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/addclcada4ed5d1785256efc006c9ce8!OpenDocument (2 of 6)7/26/2005 7:07:18 AM r MSDS Document for ORANGE TOUGH 15 SECTION III: PHYSICAL DATA Appearance & Odor Clear orange liquid, Orange fragrance SECTION IV: FIRE & EXPLOSIVE HAZARD DATA ~. __._._.p..~.~,..~ .~._- Flash Point ? 210°F Method Used ASTM-D56 Flammable Limits Not Established 'Flame Extension N/A Extinguishing Media•~IWater, carbon dioxide or dry chemical. Special Fire Fighting € Wear NIOSH approved self-contained breathing apparatus and protective Procedures: clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive :Combustion products are toxic. Hazards ~ SECTION V: HEALTH HAZARD DATA ( ~~~ Threshold Limit Value:' ~~ Not Established Primary Routes of ; Entry:; Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure-# Causes eye irritation: Symptoms may include pain, redness and swelling of the I Conditions to Avoid:: conjunctiva. Causes skin irritation: Symptoms may include redness, pain and swelling. '' Harmful if swallowed: Symptoms may include pain, nausea, vomiting and diarrhea. i' Breathing product vapors or mist may cause respiratory irritation: Symptoms may include nasal discomfort and coughing. ' Contains d-limonene and triethanolamine which may cause skin sensitization ~ with repeated contact. Repeated overexposure to triethanolamme may cause liver ': ' and kidney damage. I '' Avoid contact with eyes, skin and clothing. Avoid breathing product vapors j = or mists. Do not swallow. Use with adequate ventilation. Wash thoroughly = after handling. Conditions Aggravated by = Use of this product may aggravate preexisting skin; eye and respiratory disorders ', Uses= including asthma and dermatitis. http://www.spartanchemical.coin/sfa/MSDSRep.nsf/18ce1...619f51/addclcada4ed5d1785256efc006c9ce8!OpenDocument (3 of 6)7/26/2005 7:07:18 AM MSDS Document for ORANGE TOUGH 15 emergency ~ r><rst a><a rroceaures: Eyes ,Flush eyes with plenty of water for at least 15 minutes Remove contact lenses. Get medical attention Skin: } Remove contaminated clothing. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Ingestion:' Do not induce vomiting. Drink one or two glasses of water to dilute product. Get medical attention. Do not give anything by mouth to an unconscious person. .........~_ ~ _._~ ~..__.. ~._~_~._ .. ._r._.. _ _ Inhalation f irritation persists Move erson to fresh air. Get medical atten p __~_.. ~_~_._ _ -- - tioni _ _.._____..___ ___ _~~ http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/addclcada4ed5d1785256efc006c9ce8!OpenDocument (4 of 6)7/26/2005 7:07:18 AM M 5 a MSDS Document for ORANGE TOUGH 15 SECTION VI: REACTIVITY DATA SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case' Dike and contain spill with inert material (sand, earth, commercial absorbent, ` Material is Released or' etc.) and transfer to containers for disposal. Keep spill out of storm sewers and Spilled:'' waterways. ____ Waste Disposal Method Dispose of m compliance with all federal, state and local laws and regulations SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection:' Not normally required when good general ventilation is provided. However if i' exposure limits are exceeded (see Section II) or if respiratory irritation occurs, the use of a NIOSH approved respirator suitable for the use-conditions and chemicals listed in Section II should be considered. Ventilation:' Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify ',; Rubber or other impervious gloves. Type): Eye Protection(Specify Splash goggles are recommended to prevent eye contact. Type): Other Protective Equipment: See 29 CFR 1910.132-138 for further guidance. ; SECTION IX: SPECIAL PRECAUTIONS ~ _ __ Precautions; Handling & . .Storing: ... Keep container tightly closed. Store in a cool, dry area. Do not freeze. Do not store above 120°F. Do not mix with other chemicals. Other Precautions: ~.. _ _ .. Kee out of reach of children P _. _... _....v _...._ ~ ..... _ ....... ~...... ~....._.~ © 5CC 06/30/2005 Name: Ronald T. Cook Title: Manager, Regulatory Affairs ORANGE TOUGH 15 Effective 06/30/2005 Supercedes: 01/01/2005 Date: http://wwwspartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/addclcada4ed5d1785256efc006c9ce8!OpenDocument (5 of 6)7/26!2005 7:07:18 AM .. ~ MSDS Document for ORANGE TOUGH 15 Ref: 29 CFR 1910.1200 Changes: Update Section IX (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. http://wwwspartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/addclcada4ed5d1785256efc006c9ce8!OpenDocument (6 of 6)7/26/2005 7:07:18 AM _q ~MSDS Document for M*95 Spartan Chemical Company, Inc. ty ~~ ~~ Material Safe Data Sheet SECTION I: PRODUCT INFORMATION Product Name or Number (as it appears on label):Product Division: M*95 Product Number: 7115; 7495 Spartan Chemical Company, Inc. 1110 Spartan Drive Maumee OH 43537 Janitorial Product/Technical 1-(800)-537-8990 Information: Clsr_c_#_02006D t,.vC~T_I.O_IV Cd c~_/_O_9_l C_5 'Ll 8 ~, i S Medical Emergency:l-(888)-314-6171 (24 hours) Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24 hours) Emergency: SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1 % or greater, carcinogens at 0.1 % or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA Bolling Point (2~10~2`"12 °F #~``Va~por Pressure Undetermined ~..... ~. _._. ~ ._......_ ___ 1....... __.. _...... .....~_ . ....... __~ ~ ~.~ I ~ _~_ ...._... ~: ~... ~._.__ __ ... _ _. ~.._ ~..~... Vapor Density (AIR - 1) 'Unknown Solubility m Water., Complete ' 1 http://www.spartanchemical.coin/sfa/MSDSRep.nsf/18ce1...619f51/6f17ce39751bf4f~85256e71004f17bb!OpenDocument (1 of 5)7/26/2005 5:41:16 AM ~~~ MSDS Document for M*95 Appearance & Odor:' Opaque green liquid, pine fragrance http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/6fl7ce39751bf4fl785256e71004f17bb!OpenDocument (2 of 5)7/26/2005 5:41:16 AM ;., MSDS Document for M*95 SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Pomt ~~212°F Method Used:; ASTM-D56 Flammable Limits ~~Not Established ;Flame Extension. N/A Extinguishing Media: `' Product does not support combustion. Use extinguishing media appropriate for ,( surrounding fire. S ecial Fire Fi htm 'Wear NIOSH a roved self-contained breathin a aratus and rotective ~ P g g PP g Pp P Procedures:; clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive :Combustion products are toxic. Acid action on most metals may release Hazards: hydrogen, an explosive gas. SECTION V: HEALTH HAZARD DATA Threshold Limit Value ; - ___.u. , ..... Not Established ...... _.n.n~~..... Primary Routes of F Entry:, ....................... Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure-'; CORROSIVE. Conditions to Avoid:'. CAUSES IRREVERSIBLE EYE DAMAGE AND SKIN BURNS: Symptoms may include pain, redness, swelling and tissue damage. Harmful if absorbed ; through the skin. MAY BE FATAL IF SWALLOWED. Symptoms may include nausea, vomiting, pain and diarrhea. = INHALATION OF VAPORS OR MIST MAY CAUSE IRRITATION OR HARM TO THE RESPIRATORY TRACT. Breathing vapors or mist may cause coughing and difficulty breathing. Do not get in eyes on skin or clothing. Do not swallow. Avoid breathing ' product vapors or mist. Wash thoroughly with soap and water after handling. Conditions Aggravated by , Use of this product may aggravate preexisting skin; eye and respiratory disorders Use:' including asthma and dermatitis. Emergency & First Aid Procedures: Eyes:!: Flush eyes with water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin:' Remove contaminated clothing. Rinse skin immediately with plenty of water for at least 15 minutes. Get medical attention if irritation persists. Wash ' http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/6f17ce39751bf4f985256e71004f17bb!OpenDocument (3 of 5)7/26/2005 5:41:16 AM ;L ~.,ti MSDS Document for M*95 NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. SECTION VI: REACTIVITY DATA ~~~~~~~~~~~~~~~~~~~~~~ Stability:' Stable Incompatible ~ Strong alkalis; Materials: hypochlorites (bleach) ` ammonia; cyanides. ~ Hazardous Decomposition ~ Products: HCL, CO, C02 H Hazardous ~ Polymerization:; Will Not Occur } SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case; Small spills of one quart or less may be flushed with plenty of water to sanitary 3 Material is Released or ; sewer system (If permitted by local sewer regulations). Dike and contain larger 1 Spilled: spills with. inert material and transfer liquid to containers for recovery or disposal. Waste Disposal Method € Dispose of m compliance with all federal, state and local laws and regulations http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/6f17ce39751bf4t985256e71004f17bb!OpenDocument (4 of 5)7/26/2005 5:41:16 AM ~ i v MSDS Document for M"95 SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection:' Not normally required when good general ventilation is provided. However, if ~ = exposure limits (see Section II) are exceeded or respiratory irritation occurs, use I ' of a NIOSH approved respirator suitable for the use-conditions and chemicals in = ' Section II should be considered. ~ _ Ventilation: g g ntilation maybe necessary for Provide ood ener al ventilation. Local exhaust ve some operations Protective Gloves(Specify ; Rubber or neoprene gloves are recommended. TYPe): Eye Protection(Specify Splash goggles are recommended to prevent eye contact. . r. _._ q .p Other Protective E ui ment ; Acid resistant a rons and boots are. recommended where bod .or foot contac p Y t is likely. Eye wash stations and washing facilities should be readily accessible. See 29 CFR 1910.132-138. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & ~ Do not contaminate water, food or feed by storage or disposal. Keep from Storing:;. freezing. Do not use with other chemicals. Mixtures of this product with other chemicals, particularly those containing chlorine bleach or ammonia may result ( ' ~ . .....__...._...._._..... in the production of toxic gases, fire or explosion. _. v ._. .. .. _r__~___.... _...~~......__.__._v_____..._. ...... ~._~_.....__ ~... .; Other Precautions: s 4 _ Keep out of reach of children. © SCC 06/30/2005 Name: Ronald T. Cook Title: Manager, Regulatory Affairs M*95 Effective 06/30/2005 Supercedes: 04/09/2004 Date: Ref: 29 CFR 1910.1200 Changes: Update Section IX (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. http://www.spartanchemical.coin/sfa/MSDSRep.nsf/18ce1...619f51/6f17ce39751bf4f985256e71004f17bb!OpenDocument (5 of 5)7/26/2005 5:41:16 AM '~'MSDS Document for GERMICIDAL BOWL CLEANSE Appearance & Odor: Milky white liquid, acrid odor http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/a8de0bde0843c28f852570260059c98e!OpenDocument (2 of 5)7/26/2005 5:00:32 AM "~ °'MSDS Document for GERMICIDAL BOWL CLEANSE SECTION IV: FIRE & EXPLOSIVE HAZARD DATA ' FlFlash Point: (>~220°F~ i~(~Meth~od Used: (AS~TM~-D56 ~I _ I _... I,, ... ,._, ,.. I. , Flammable Limits:- Not Established "Flame Extension:° N/A Extinguishing Media:' Product does not support combustion. Use extinguishing media appropriate for surrounding fire. ~ Special Fire Fighting `Wear NIOSH approved self-contained breathing apparatus and protective Procedures:!: clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive ~ Combustion products are toxic. Acid action on most metals may release Hazards:; hydrogen, an explosive gas. SECTION V: HEALTH HAZARD DATA E Threshold Limit Value::. ~ Not Established Primary Routes of : Entry: ~ Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- CORROSIVE. Conditions to Avoid:: CAUSES IRREVERSIBLE EYE DAMAGE AND SKIN BURNS: Symptoms may include pain, redness, swelling and tissue damage. Harmful if absorbed through the skin. MAY BE FATAL IF SWALLOWED. Symptoms may include nausea, vomiting, pain and diarrhea. INHALATION OF SPRAY MIST MAY CAUSE RESPIRATORY HARM OR IRRITATION. Breathing spray mist may cause coughing and difficulty breathing. !' Do not get in eyes on skin or clothing. Do not swallow. Avoid breathing ` product mist. ~ .. _..r ,, ,., ~. .....___...v~.. _ Wash thoroughly with soap and water after handling. _ ~... _...._ _ .... ...... .._... _ . ........ _ ... ~... .. . Conditions Aggravated by Use of this product may aggravate preexisting skin; eye and respiratory disorders Use:' including asthma and dermatitis. Emergency & First Aid Procedures: ,._ ~..r.,....w~_~~a..~~,. __.. ~...~...~ ~~_._., _ k..~ Eyes:: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses after the first 5 minutes then continue rinsing eye. Call a ', poison control center or doctor for treatment advice. Skin: < Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Wash contaminated clothing before reuse. Ingestion: Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told '. to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. http://wwwspartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/a8de0bde0843c28f852570260059c98e!OpenDocument (3 of 5)7/26/2005 5:00:32 AM '-'; '~"' MSDS Document for GERMICIDAL BOWL CLEANSE Inhalation:' In case of respiratory irritation; move person to fresh air. If person is not breathing call 911 or an ambulance then give artificial respiration preferably ` mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. SECTION VI: REACTIVITY DATA Stability: Stable Incompatible Materials:: Strong alkalis; hypochlorites (bleach) ammonia; cyanides. Hazardous Decomposition Products: HCL, CO, C02 H Hazardous ; Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES n Steps to be Taken in Case': Dike and contain spill with inert material (sand, earth, commercial absorbent, Material is Released or ` etc.) and transfer to containers for disposal. Rinse area with water and flush to Spilled:; ~ sanitary sewer. Keep spill out of storm sewers and waterways. ( Waste Disposal Method ; Dispose of in compliance with all federal, state and local laws and regulations. httpa/www.spartanchemical.comisfaiMSDSRep.nsf/18ce1...619f51/a8de0bde0843c28f852570260059c98e!OpenDocument (4 of 5)7/26/2005 5:00:32 AM :~ ~' MSDS Document for GERMICIDAL BOWL CLEANSE SECTION VIII: SPECIAL PROTECTION INFORMATION s _ u m _ . ~. Respiratory Protection: Not normally required when good general ventilation is provided. However, if exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in ',~ Section II should be considered. ~ Ventilation:; Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. ~ Protective Gloves(Specify Rubber or neoprene gloves are recommended. Tie)' ~~ Eye Protection(Specify ' Splash goggles are recommended to prevent eye contact. Type): Other Protective Equipment: - Acid resistant aprons and boots are recommended where body or foot contact is likely. Eye wash stations and washing facilities should be readily accessible. See 29 CFR 1910.132-138. '" SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & 1 Do not contaminate water, food or feed by storage or disposal. Keep from Storing: , freezing. Do not use with other chemicals. Mixtures of this product with other ~ ` chemicals, particularly those containing chlorine bleach or ammonia may result ! f in the production of toxic gases, fire or explosion. ... .. ~- Other Precautions:,; Keep out of reach of children. © SCC 06/30/2005 Name: Ronald T. Cook Title: Manager, Regulatory Affairs GERMICIDAL BOWL CLEANSEEffective 06/30/2005 Supercedes: 06/01/2004 Date: Ref 29 CFR 1910.1200 Changes: Update Section IX (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/a8de0bde0843c28f852570260059c98e!OpenDocument (5 of 5)7/26/2005 5:00:32 AM "' ' MSDS Document for SPARCLING ~Clsrc #~0~2-00807 ~ Spartan Chemical Company, Inc. Material Safety Data Sheet ~O~A~-oN ~~"~ ~ ; ~~ISCE fj/i/t/ _ SECTION I: PRODUCT INFORMATION ~ I--~~-~I ~ ! A '~~ Product Name or Number (as it appears on label):Product Division: vZ. ~ 8 Q I S SPARCLING Janitorial Product Number: 7118; 7498 Spartan Chemical Company, Inc. Product/Technical 1-(800)-537-8990 Information: 1110 Spartan Drive Medical Emergency:l-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24 hours) Emergency: ~ Shipping Description:' Corrosive liquids, n.o.s., 8, UN 1760, III, (contains hydrochloric (muriatic) acid).; _ __ NFPA Ratings ~ HMIS Ratings. __ ~. Health ~ 3 Serious Health 3 - Serious ..... .. ...... _ _ . _ .... __... I....._. ._ ~ ...... Fire : 0 -Minimal Fire ~ 0 Minimal Reactivity: 0 -Minimal Reactivity: 0 -Minimal .. __ - - .Pers. Prot. Equip.:; See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1 % or greater, carcinogens at 0.1 % or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. ___ T __ __. ____ Table Z- 1 - A NTP, _~~.... «.. _. , ~ IARC or CAS ~ GEEING mg/ ` OSHA 'Chemical Name(s) % W Registry No. ~ TWA mg/m3 STEL mg/m 3 m3 Carcinogen' *Hydrochloric acid 5-10 7647-01-0 Established Establ shed 7 No Betaines, bis (hydroxyethyl)tallow 1-5 70750-46-8 Established Established Established No alk 1 y Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (SARA) and of 40 CFR 372. SECTION III: PHYSICAL DATA http://wwwspartanchemical.coin/sfa/MSDSRep.nsf/18ce1...619f51/36bdfae557db67c2852570260069f3fa!OpenDocument (1 of 5)7/26/2005 9:47:55 AM y. ~`~ MSDS Document for SPARCLING Appearance & Odor Green liquid, mint fragrance http://wwwspartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/36bdfae557db67c2852570260069f3fa!OpenDocument (2 of 5)7/26/2005 9:47:55 AM ~. MSDS Document for SPARCLING SECTION IV: FIRE & EXPLOSIVE HAZARD DATA ° ~ ethod Used: ` ASTM-D56 Flash Pomt. > 210 F ~~ .____ . ~ _ --- ---- Flammable Lime. -- ~...... .... __. _ its: Not Established ;Flame Extension: N/A `. - - Extinguishing Media:: Product does not support combustion. Use extinguishing media appropriate for `surrounding fire. Special Fire Fighting :Wear NIOSH approved self-contained breathing apparatus and protective Procedures: clothing. Cool fire-exposed containers with water spray. Unusual Fire & Explosive ;Combustion products are toxic. Acid action on most metals may release Hazards:; hydrogen, an explosive gas. E SECTION V: HEALTH HAZARD DATA __ _ _ Threshold Limit Value: j ,.... Not Established Primary Routes of ; Entry::' Inhalation, Skin Contact, Eyes & Oral Effects of Overexposure- CORROSIVE. Conditions to Avoid:' CAUSES IRREVERSIBLE EYE DAMAGE AND SKIN BURNS: Symptoms may include pain, redness, swelling and tissue damage. Harmful if absorbed ` through the skin. f HARMFUL IF SWALLOWED. Symptoms may include nausea, vomiting, ~ ; pain and diarrhea. INHALATION OF SPRAY MIST MAY CAUSE RESPIRATORY HARM OR IRRITATION. Breathing spray mist may cause coughing and difficulty '' breathing. Do not get in eyes on skin or clothing. Do not swallow. Avoid breathing product mist. Wash thoroughly with soap and water after handling. Conditions Aggravated by ' Use of this product may aggravate preexisting skin; eye and respiratory disorders Use: including asthma and dermatitis. Emergency & First Aid Procedures: E es: Hold e e o en and rinse slowl and entl with water fo ~, ~~ ~~~~~~~~~~~~~~~~~~~~ fr ~ y y p y ~~ g y~ r 15-20 minutes. Remove contact lenses after the first 5 minutes then continue rinsing eye. Calla '; poison control center or doctor for treatment advice. y Skin:" Take off contaminated clothing. Rinse skin immediately with plenty of water for '. F t 15-20 minutes. Call a poison control center or doctor for treatment advice. Wash contaminated clothing before reuse. Ingestion: ` Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by ~a poison control center or doctor. Do not give anything by mouth to an unconscious person. http://wwwspartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/36bdfae557db67c2852570260069f3fa!OpenDocument (3 of 5)7/26/2005 9:47:55 AM '`' IvISDS Document for SPARCLING Inhalation:: In case of respiratory irritation; move person to fresh air. If person is not breathing ca11911 or an ambulance then give artificial respiration preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. `~ NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. SECTION VI: REACTIVITY DATA . Stability:: Stable Incompatible Materials:';. Strong alkalis; hypochlorites (bleach) ammonia; cyanides. Hazardous Decomposition Products:' HCL, CO, C02 H Hazardous Polymerization: Will Not Occur SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Dike and contain spill with inert material (sand, earth, commercial absorbent, Material is Released or etc.) and transfer to containers for disposal. Rinse area with water and flush to Spilled:'; sanitary sewer. Keep spill out of storm sewers and waterways. i '~ Waste Disposal Method:' Dispose of in compliance with all federal, state and local laws and regulations. http://wwwspartanchemical.comJsfa/MSDSRep.nsf118ce1...619f51/36bdfae557dbb7c2852570260069f3fa!OpenDocument (4 of 5)7/26!2005 9:47:55 AM :-~, . ' NISDS Document for SPARCLING SECTION VIII: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normally required when good general ventilation is provided. However, if ` exposure limits (see Section II) are exceeded or respiratory irritation occurs, use of a NIOSH approved respirator suitable for the use-conditions and chemicals in Section II should be considered. Ventilation: ` Provide good general ventilation. Local exhaust ventilation may be necessary for some operations. Protectlve Gloves(Speclfy ; Rubber or neoprene gloves are recommended. TYPe)~' Eye Protection(Specify Splash goggles are recommended to prevent eye contact. Type): Other Protective Equipment: Acid resistant aprons and boots are recommended where body or foot contact is likely. Eye wash stations and washing facilities should be readily accessible. See 29 CFR 1910.132-138. SECTION IX: SPECIAL PRECAUTIONS © SCC 06/30/2005 SPARCLING Name: Ronald T. Cook Effective 06/30/2005 Date: Title: Manager, Regulatory Affairs Supercedes: 06/01 /2004 Ref: 29 CFR 1910.1200 Changes: Update Section IX (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with. all Federal, State and Local laws and regulations. Precautions; Handling & Do not contaminate water, food or feed by storage or disposal. Keep from Storing:: freezing. Do not use with other chemicals. Mixtures of this product with other chemicals, particularly those containing chlorine bleach or ammonia may result - in the production of toxic gases, fire or explosion. Other Precautions:. Keep out of reach of children. http://wwwspartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/36bdfae557db67c2852570260069f3fa!OpenDocument (5 of 5)7!26!2005 9:47:55 AM t ~ ~~ - CS # 020146 ,< , Spartan Chemical Company, Inc. _ ~'.. Material Safety Data Sheet ~ ~ _~-- f~~ C~~- SECTION 1: PRODUCT INFORMATION ~~Q~~"~~ ~~~ Product Name or Number (as it appears on label): Product [3ivision: ~ _~•- CLEAN ON THE GO NABC CONCENTRATE (l] Janitorial ~~~_/~,?/~! Product Number. 4716 a ~v aT's /:,`:;: "> Spartan Ghemical Company, Inc. Product/Technical Information: 1-{800)-537-8990 1110 Spartan Drive Medical Emergency: 1-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil Emer e g ncy: CHEMTREC 1-(800} 424-9300 (24 hours) Shipping 08scription: Disinfectants, liquid, n.o.s. NFPA Ratin s: HMIS Ratings: Health: 3 -Serious Health: 3 -Serious Fire: 0 -Minimal Fire: 0 -Minimal Reactivity: 0 -Minimal Reactivity: 0 -Minimal Pers. Prot. Equip.: See Section VIII SECTION Ii: HA7~4RDOUS INGREDIENTS (Listed when present at 1 % or greater, prcinogens at 0.196 or greater) Ail component chemicals are listed or exempted from listing on the "fSCA Inventory" of chemical substances maintained by the U.5. F~tvironmental Protection Agency. Table Z-1-A CA5 R~ TWA ' S7EL ' CEILING ' NTP, IARC Chemical Name(s) %Wt No ~ mg/m mg/m mg/m or OSHA Caranogen Alkyl dimethyi benzyl 01-05 68424-85-1 Not Established Not Establushed Not Established No ammonium chloride - - - - - - Nonyi phenol ethoxylate 01-OS 9016-45-9 Not Established Not Established Not Established No Isopropyl alcohol 01-05 67-63-0 980 1225 Not Established No Fragrance 01-05 Proprietary Not Established Not Established Not Established No SECTION IN; PHYSICAL DATA Boiling Point: 210 °F Vapor Pressure: Unknown Vapor Density (AiR = 1 }: Unknown Solubility in Water. Complete PH~ 5.0-6.0 Specific Gravity (H,O=1): 1.00 Evaporation Rate {but.ace.=1 }: <i Percent Solid by Weight: 5-10 Pttyslgf State: Liquid Appearance 8 Odor: glue liquid, floral fragrance SECTION lV: FIRE & EXPLOSIVE HAZARD DATA Flash Potnk > Method Used: Extinguishing Media: product does not support combustion. Use extinguishing media appropriate for surrounding fire. Special Firs Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus and protective clothing. Coo! fire-exposed containers with water spray. Unusual Fire & Explosive Hazards: Combustion products are toxic. ., CS # 020146 SECTION V: HEALTH HAZARD DATA Threshold Limit Value: Noi Established I Primary Routes of Entry: Inhalation, Skin Contact, Eyes & Orai Effects of Overexposure- CORROSIVE: Conditions to Avoid: CAUSES IRREVERSIBLE EYE DAMAGE: Symptoms may include pain, rednass, swelling of the conjunctiva and tissue damage. HARMFUL TO SK1N: Causes skin irritation with symptoms of pain, redness and possible chemical burns. Harmful rf absorbed through the skin. HARMFUL IF SWALLOWED: Symptoms may indude nausea, vomiting, pain and diarrhea. 1NHALATlON OF SPRAY MIST MAY CAUSE RESPIRATORY IRRITATION: Breathing spray mist may cause coughing and difficulty breathing. Do not get in eyes, on skin or clothing. Do not taste or swallow, Avoid inhalation of spray mist. Wash thoroughly with soap and wafer after handling. Conditions Aggravated try Use: Use of this product may aggravate preexisting skin; eye and respiratory disorders inducting asthma and dermatitis. Emergency & First Aid Procedures: Eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses after She first 5 minutes then continue rinsfng eye. Call a poison control center or doctor for treatment advice. Skin: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15.20 minutes. Call a bison control center or doctor for treatment advice. Wash contaminated dothing before reuse. Ingestion: Call a poison control center or dolor immediately for treatment advice. Have person sip a gtass of water if able to surallow, Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. inhalation: [n case of respiratory irritation; move person to fresh air. Gei medical attention if Irritation persists. NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric tavage. SECTION VI: REACTIVITY DATA Stability: Stable ~ Incompatible Materials: Strong oxidizers Hazardous Decomposition Products: CO, CO, ~ Hazardous Potymerization: Will Not Ocxur SECTION Vii: SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled: Small spiAs of one gallon or less may be flushed with plenty of water to sanitary sewer system (if permitted by local sewer regulations). Dike and contain large spills with inert material and transfer liquid to containers for recovery or disposal. Waste Disposal Method: Same as above. Container disposal; Triple rinse (or equivalent) then offer for recyding or reconditioning, or puncture and dispose of in a sanitary IandfiA, or incinerate, or if allowed by state and local authorities; bum. If burned, stay out of smoke. SECTION Vili: SPECIAL PROTECTION INFORMATION Respiratory Protection: Not normalty required when good general ventilation is provided. However, if respiratory irritation occurs, use of a NiOSH approved respirator suitable for the use-conditions and chemipis in Section ii should be consdered. Ventilation: provide good genera! ventilation. Local exhaust ventilation may be necessary for some operations. Protective Gloves(Specify Type): Rubber or other water-proof cloves are recommended. SECTION IX: SPECIAL PRECAtlTiONS Precautions; Handling & Storing: Keep from freezing. Other Precautions: Keep out of reach of children. ©SCC 12!14!2005 CLF1W ON THE GO NABC CONCENTRATE [t] Ref: 29 CFR 1910.1200 (OSHA) Name: Ronald T. Cook Title: Manager, Regulatory Affairs Effective Date: 12/t4l2005 Supercedes: 06/3012005 Changes: Update sh€pping description This document has been prepared using data from sources considered technicaNy reliable. It does not constitute a warranty, express or implied, as to itre accuracy of the information contained herein. Actual Condftions of use and handling are beYorici setie.rs control, Usef is responsible to evaluate aN available information when using product for sny particular use and to oompty with ail Federal, State and Local caws and reguiatioris. handled.. See 29 CFR 1910.132-138 for further guidance. M,~DS Document for SC-200 . Glsrc-# 1-00060 `:'` Spartan Chemical Company, Inc. Material Safety Data Sheet ~~~~~-~~ ~' G,c~ - - SECTION I: PRODUCT INFORMATION CQ~ ~~Q -1g1p~ Product Name or Number (as it appears on label):Product Division: ~~ ~~ SC-200 Janitorial Product Number: 2200 Spartan Chemical Company, Inc. Product/Technical 1-(800)-537-8990 Information: 1110 Spartan Drive Medical Emergency:l-(888)-314-6171 (24 hours) Maumee OH 43537 Chemical Leak/Spil CHEMTREC 1-(800) 424-9300 (24 hours) Emergency: .. ...~ ~..~ .~. ~~~~~~~~~~'~~~-~ 8, UN 1760, II, (contains sodium hydroxide) ~ Shlppmg Descrlprion Corrosive liquids, n o.s., NFPA Ratings: ~ HMIS Ratings:' W _........._._.... ___ ~~..._ * 3 Health. ~ 3 Serlous Health 3 -Serious Chronic Hazard: Fire: 0 -Minimal Fire:: 0 -Minimal Reachv><ty ; 0 -Minimal ~ ~Reachv><ty ' 0 -Minimal f ~ Pers. Prot. Equ><p ?See Section VIII SECTION II: HAZARDOUS INGREDIENTS (Listed when present at 1 % or greater, carcinogens at 0.1 % or greater) All component chemicals are listed or exempted from listing on the "TSCA Inventory" of chemical substances maintained by the U.S. Environmental Protection Agency. Table Z- 1 - A NTP, ...... _ IARC or CAS _ GEEING mg/ OSHA Chemical Name(s) % W Registry No ~ TWA mg/m3 ' STEL mg/m 3 m3 Carcinogen *2-Butoxyethanol 5-10 111-76-2 120 (skm) _ Not Not No Established Established Nonyl phenol ethoxylate 1-5 9016-45-9 ~ Not Not Not No Established Established Established Sodium xylene sulfonate ~ 1-5 1300-72-7 ', Establ shed Establ shed ~ Established No's Sodium hydroxide 1-5 1310-73-2 2 Not Not No Established: Established Comment: *This substance is subject to the reporting requirements of Section 313 of the Emergency Planning http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/536b66f54cfa5cbb852570260067f552!OpenDocument (1 of 6)7/26/2005 7:56:01 AM MSDS Do;,ument for SC-200 SECTION III: PHYSICAL DATA Appearance & Odor: Red liquid, glycol ether odor SECTION IV: FIRE & EXPLOSIVE HAZARD DATA Flash Point ~ > 210°F ~ Method Used: ASTM D56 -- 1 Flammable Limits: Not Established Flame Extension: N/A SECTION V: HEALTH HAZARD DATA Threshold Limit Value:: Not Established Primary Routes of :Inhalation, Skin Contact, Entry. E Eyes & Oral Effects of Overexposure-' CORROSIVE: Conditions to Avoid:' CAUSES EYE AND SKIN BURNS: Symptoms include chemical burns, pain, redness, swelling of the conjunctiva and tissue destruction. '' HARMFUL CONTACT MAY NOT CAUSE IMMEDIATE PAIN. HARMFUL IF SWALLOWED: Causes damage or chemical burns to esophagus and mucous membranes with symptoms of pain, nausea, vomiting and '' diarrhea. Aspiration of product into the lungs may occur during ingestion or vomiting, resulting in lung injury. HARMFUL IF INHALED: Breathing product vapor or mist may cause irritation or damage of the respiratory tract, with symptoms of nasal discomfort '' and discharge with chest pain and coughing. HARMFUL IF ABSORBED THROUGH SKIN: Contains 2-butoxyethanol which may cause central nervous system depression with symptoms such as headache; dizziness; nausea and drowsiness. Exposure to http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/536b66f54cfa5cbb852570260067f552!OpenDocument (3 of 6)7/26/2005 7:56:01 AM ,~ 4 MSDS Document for SC-200 1 may cause blood cell; liver and kidney damage based on animal data. DO NOT GET IN EYES, ON SKIN OR CLOTHING. DO NOT BREATHE PRODUCT VAPOR OR MIST. DO NOT SWALLOW. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. Conditions Aggravated by ;Use of this product may aggravate preexisting skin; eye and respiratory disorders Use:'' including asthma and fibrotic pulmonary disease. Emergency & First Aid Procedures: ___~__._....~..___._,_.,..__~__..~, Eyes:~ Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses. Get medical attention. Skin:' Remove contaminated clothing and shoes. Flush skin with water for at least 15 minutes. Get medical attention if irritation persists. Wash contaminated clothing before reuse. Destroy contaminated shoes Ingestion:'i, Call a poison control center or doctor immediately for treatment advice. Do not ' induce vomiting. Drink one or two glasses of water to dilute product. Do not give anything by mouth to an unconscious person. Inhalation:' In case of respiratory irritation or dizziness; move person to fresh air. If not breathing; give artificial respiration. If breathing is difficult; give oxygen. Get ' : medical attention if irritation persists. ' http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/536b66f54cfa5cbb852570260067f552!OpenDocument (4 of 6)7/26/2005 7:56:01 AM ~i J MSDS Da~CUment for SC-200 ;J. SECTION VI: REACTIVITY DATA SECTION VII: SPILL OR LEAK PROCEDURES Steps to be Taken in Case; Dike and contain spill with inert material (sand, earth, commercial absorbent, Material is Released or `etc.) and transfer to containers for disposal. Rinse area with water and flush to Spilled:; sanitary sewer. Keep spill out of storm sewers and waterways. W ~~ Waste Dis osal Method: Dispose of ~ ~_._ .... ..... .... .,_,,. ~__ _....._...... , __ ._ ~.. ... ' p in compliance with all federal, state and local laws and regulations SECTION VIII: SPECIAL PROTECTION INFORMATION r_..___._.._.~ ~_ __ ..~.~_ Respiratory Protection: } ~._ ~~... _ ____ _._______. _.~ __ Not normally required when good general ventilation is provided. However if ~ exposure limits are exceeded (see Section II) or if respiratory irritation occurs, 1 ' the use of a NIOSH approved respirator suitable for-the use-conditions and = __ _._... chemicals listed in Section II should be considered. ... ....... ____.... ...... ............ ..... µ... .... Ventilation: ~ E Provide good general ventilation. Local exhaust ventilation maybe necessary for ; ' some operations. Protective Gloves(Specify Solvent/alkali resistant gloves such as neoprene, nitrile or natural rubber. 3 Type):.: __...._y ~ _ _._..._.~...._ _ ......~~.._.... _..~_.. _._. Eye Protection(Specify ; Splash goggles are recommended to prevent eye contact. TYPe): Other Protective Equipment: Solvent /alkali resistant boots, apron and other protective equipment is ' recommended when foot /body contact is likely. Eye wash stations and washing ': facilities should be readily accessible in areas where product is handled.. See 29 CFR 1910.132-138 for further guidance. SECTION IX: SPECIAL PRECAUTIONS Precautions; Handling & ~ Keep container tightly closed. Store in a cool, dry area. Do not freeze. Do not Storing:; store above 120°F. Do not mix with other chemicals. i Other Precautions: Keep out of reach of children © SCC 06/30/2005 Name: Ronald T. Cook Title: Manager, Regulatory Affairs http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/536b66f54cfa5cbb852570260067f552!OpenDocument (5 of 6)7/26/2005 7:56:01 AM ~s MSDS Document for SC-200 ;r . sc-Zoo Ref: 29 CFR 1910.1200 Effective 06/30/2005 Date: Changes: Update Section IX Supersedes: 06/01/2004 (OSHA) This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained herein. Actual conditions of use and handling are beyond sellers control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State and Local laws and regulations. http://www.spartanchemical.com/sfa/MSDSRep.nsf/18ce1...619f51/536b66f54cfa5cbb852570260067f552!OpenDocument (6 of 6)7/26/2005 7:56:01 AM i ~~ LI,7,~dA CjISfCt'f lbU"14tf~ `~ Material Safe Data Sheet This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 ® E HCS CLASS: Corrosive liquid. WHMIS (Pictograms) WHMIS (Classification) HCS Section 1. Chemical Product and Company Identification Product Name/ Trade name Citrus Chisel Synonym Natural Citrus Cleaner/Degreaser Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL/ NDSL All components listed unless noted elsewhere on this MSDS Code 167 CAS # Not applicable. Validation Date 3/22/2004 Print Date 3/27/2004 In Case of Chemtrec (800) 424-9300 EmerQencv Protective Clothing Section 2.°Composition and Information on Ingredients Name CAS # % by Exposure Limits LCso/LDsn Weight 1) Sodium Metasilicate 6834-92-0 <10 Not available. Not available. 2) Nonionic Surfactant 9016-45-9 <2 Not available. Not available. 3) Cationic Surfactant 5197-80-8 <2 Not available. Not available. 4) Sodium Hydroxide 1310-73-2 1-5 TWA: 2 (mg/m3) from Not available. OSHA (PEL) [United States] 5) Tetrasodium salt of 64-02-8 1-5 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg (Rat]. Section 3: Hazards Identification Potential Acute Health Effects Corrosive to skin and eyes on contact. Skin contact may produce burns. May be irritating to the mucous membranes of the nose, throat and lungs. Potential Chronic Health Over-exposure by inhalation may cause respiratory irritation. Prolonged exposure may result in skin Effects burns and ulcerations. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact Corrosive to eyes and skin. Call a poison control center or doctor immediately for treatment advice. Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Skin Contact Remove contaminated clothing and shoes. Rinse skin with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for further treatment advice. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions Non-flammable substance. Special Remarks on Fire Hazards Not available. Special Remarks on Explosion Hazards No additional remark. Section 6. Accidental Re/ease:'Measures Small Spi11 and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spi11 and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. a Large Spill Section 7. Handling and Storage Precautions Keep locked up. Keep container dry. DO NOT ingest. Do not breathe gas, fumes, vapor or spray. Wear suitable protective clothing. If ingested; seek medical advice immediately and show the container or the label. Avoid breathing vapors or spray mists. Keep out of reach of children. For Institutional and Commercial Use Incompatibility Strong acids. acids Storage Keep out of reach of children. Corrosive materials should be stored in a separate safety storage cabinet or room. For Institutional and Commercial Use Not for use or storage in or around the home. ......Section 8. Exposure Controls/Personal Profection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Work uniform or laboratory coat. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) ~ o ".." Exposure Limits Not available. Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.06 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility _ 85 VOC 0.15% (By Weight) Evaporation Rate <1 compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: Non-flammable. Auto-ignition Temperature Not available. Flash Points None to Boiling (TCC) Flammable Limits Not Applicable Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of static discharge: Not available. Risks of explosion of the product in presence of mechanical impact: Not available. Section 10.-Stability and Reactivity Data Stability The product is stable. Incompatibility with Various Strong acids. acids Substances Hazardous Decomposition Not available. Products Section 71. Toxicological'... Information Routes of Entry Eye Contact Ingestion. INHALATION Skin contact. Toxicity to Auimats Acute oral toxicity (LD50): 3030 mg/kg [Rat]. (Tetrasodium EDTA). Acute Effects on Humans Eyes Corrosive to skin and eyes on contact. Eye contact can result in corneal damage . Skin Skin contact may produce burns. Inhalation Slightly irritating to the respiratory system. Ingestion Irritating to the mouth, throat, and gastrointestinal system. Large doses may cause vomiting and diarrhea. Irritating to mouth, throat and stomach. May cause burns to mouth, throat and stomach. May cause headache, dizziness, nausea, vomiting and diarrhea. Chronic Effects on Humans Over-exposure by inhalation may cause respiratory irritation. Prolonged exposure may result in skin burns and ulcerations. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Ecological Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal Considerations waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 15. Other'Regulatory Information and Pictograms WHNIIS (Classification) E Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS CLASS: Corrosive liquid. .T USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide < 1 ppm Massachusetts RTK: Ethylene Oxide SARA 311/312: Sodium Metasilicate SARA 313: No components were found. DSD (EEC) R35- Causes severe burns. International No products were found. Regulations Lists Hazardous Material ~~~ 3 National Fire ~/~ ,., .Flammability Information System ~~ rE 0 i Protection ~tJ~ r---~~ S.A. , ..~~..~~--. ~• ) ~` Association (iJ.S.A.) Health ' 3 O Instability Physical Hazard Q The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consuRed to determine any specific hazards, First Aid measures, and PPE associated with this produtk. Section 16. Other Information - Validated by CRushton on 3/22/2004. Verified by CRushton. Printed 3/27/2004. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever (or the accuracy or completeness of the information contained herein. Final determination ojsuitability ojany material is the sole responsibility ojthe user. A[1 materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Validated on 3/22/2004. Citrus Chisel Page: 5/5 Gontinued on Next Page '` ~ RI . ~N C~~f D ~ /~I___~ ,- 1 X07 ~- Clsrc # 1_4.0141 ~" ~ ~ ~ Material Safety Data Sheet oa I E WHMIS HCS HCS Class: Corrosive liquid. Section 7. Chemical Product and Company Identification Product Name/ Trade name Extreme Synonym High Power/High Speed No Rinse Floor Stripper Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419) 241-2156 TSCA TSCA Inventory: All components listed or are exempt from IisNng. DSL DSL : All components listed unless noted elsewhere on this MSDS Code 184 CAS # Not applicable. Validation Date 8/11/2003" Print Date 8/22/2003 in core or Chemtrec (800) 424-9300 Emereencv Protective Clothing ~~~ .Section 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCSdLDso Weight 1) Water 7732-18-5 55-60 Not available. Not available. 2) 2-Butoxyethanol 111-76-2 <21 TWA: 20 (ppm) from ORAL (LD50): Acute: 1746 ACGIH (TLV) [United mg/kg [Rat]. States} TWA: 50 (ppm) from OSHA (PEL) [United States] 3) Benzyl Alcohol 100-51-6 <10 TWA: 3 STEL: 6 (ppm) Not available. 4) Monoethanolamine 141-43-5 5-10 TWA: 3 (ppm) Not available. TWA: 6 (ppm) from OSHA (PEL) [United States} STEL:6 (ppm) 5) Sodium Xylene Sulfonate 1300-72-7 <5 Not available. Not available. 6) Perfume Oil 100-52-7 <1 Not available. Not available. 7) Nonionic Surfactant 9016-45-9 0-5 Not available. Not available. 8) Mixed Amphocarboxylates N/A 0-5 Not available. Not available. 9) Tetrasodium salt of 64-02-8 <1 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg [Rat]., 10) Dye N/A <1 Not available. Not available. Section 3. Hazards Identification Potential Acute Health Effects Corrosive to eyes and skin. Harmful if swallowed. Harmful if inhaled. Irritating to mouth, throat and stomach. Potential Chronic Health Asthma and related respiratory illness may be aggravated by exposure. Repeated or prolonged Effects exposure to the gas can produce lung damage. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. However, in light of good industrial hygiene, exposure to any chemical should be kept to a minimum. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact Immediately Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor immediately for treatment advice. Skin Contact Remove contaminated clothing and shoes. Rinse skin with plenty of water for 15 to 20 minutes. Call a poison contro{ center or doctor for further treatment advice. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media N/A and Instructions Special Remarks on Fire N/A Hazards Special Remarks on N/A Explosion Hazards .Section 6. Accidental Release Measures Small Spilt and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Prevent entry into sewers, basements or confined areas. Neutralize caustic ingredients with vinegar or acetic acid or use a basic spill kit. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Avoid breathing vapors or spray mists. Do not ingest: Good general ventilation should be sufficient to control airborne levels. Incompatibility Strong acids or oxidizers. Storage Keep out of the reach of children. Not for use or storage in or around the home. ' Section 8. F~rposure Controls/Personal Protection I Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Wear overalls or long sleeved shirt and long trousers, nitrite rubber or neoprene gloves, rubber boots. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Rubber gloves. Protective Clothing (Pictograms) ~ ^ .. Exposure Limits 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Moncethanolamine TWA: 3 (ppm) TWA: 6 (ppm) from OSHA (PEL) STEL:6 (ppm) Consult local authorities for acceptable exposure limits. `Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Aromatic. Ethereal. Molecular Weight Not applicable. Taste Not available. ' pH 11.8 to 12.8 [Basic.] Color Pale Green. Boiling/Condensation Point 214°F initlel Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 0.993 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density . >1 (Air = 1) Volatility 95 VOC 23 (%) Evaporation Rate <1 compared to Butyl acetate. Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: Non-flammable. Auto-iguitiou Temperature Not available. Flash Points Not available. Flammable Limits Not available. Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Not applicable Section 10.'°Stability and Reactivity Data Stability The product is stable. Incompatibility with Various Strong acids or oxidizers. Substances Hazardous Decomposition Will not occur. Products Section 11. Toxicological Information Routes of Entry Dermal contact. Eye contact. Inhalation. Ingestion. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). Acute Effects on Humans Eyes Severe eye irritant. Liquid and mist may damage the eyes causing corneal injury. Skin Corrosive. Skin contact may produce burns. Inha[arion Vapors may be irritating to the mucous membranes in the nose, throat, and lungs. High concentrations may cause headache, dizziness, and nausea. Ingestion Irritating to the mouth, throat, and gastrointestinal system. May cause dizziness, headache, nausea, vomiting, and diarrhea. Harmful if swallowed. Chronic Effects on Humans Asthma and related respiratory illness may be aggravated by exposure. Repeated or prolonged exposure to the gas can produce lung damage. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. However, in light of good industrial hygiene, exposure to any chemical should be kept to a minimum. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans S@CtiOn 1~. ECOIOgIGaI Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 75. Other Regulatory Information and Pictograms. WFINIIS (Classification) E Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS Class: Corrosive liquid. USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide < 1 ppm Massachusetts RTK: Ethylene Oxide SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) R22- Harmful if swallowed. R36/38-Irritating to eyes and skin. International No products were found. Regulations Lists Hazardous Material 3 National Fire ,~ Information System - ~ Protection < ll } ~a`°`°~~hty (U.S.A.) ~ ~,~,~ ~'7~:;, ~ ~/ ` tnstahtliry H <m 3 Associ ti U S A (~ ea , y ~ a on ( . . .) Ph ~s~cal Havrd The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE ~ Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product Section 96. Other Information Validated by CRushton on 8/11/2003. Verified by CRushton. Printed 8/22/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any Uabi[ity whatsoever for the accuracy or completeness ojthe information contained herein. Final determination of suitability of any material is the sole responsibility of the user. AU materials may pr¢sent unknown hazards and. should be used with caution. AUhough certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Validated on 8/11/2003. Extreme Page: 6/6 Continued on'Next Page C~ o c ~~ ~ on/ ~:-~- Co'~_~03 ~$~, ~ -~~ i o ;Q~._ CS # 140481 - SD G' ~-- ,. ~.- ,, ~~ ~ ~ ~~ `~ -li~at,erial Saf~~g~~ ~~~~ ~~~~;t ,This MSDS is;prepared irraccordance with OSHA 29 CFR 1910.1200 1M1il~tMlS ~LitSB C3-2: Pl{attarial causing attaertaxic effects. }{~$ CLA6S' Irritating subStartce. Wil€~1tS(Pirlv~rztiras) 11'It;vilS(Classification} ~t(CS ~~ Sectifln °~fi. Che~rtllcal Product and ~t~rr~pan~r ~d~r~cetlcrn ~ , Product Name/ pH7~ U~tP1 ~ ~ ~ ~ ~ ~ ~ ~ Code- ' ~ ~ 1 78 , Trade name Synonym ,, EloorCleaner ~ ~ - • 'CAS # ~ Not applicable:' Chemical Family N/A , Validation Date° `4/2912005 Chemical Formula .Not applicable. Print Date 4/29/2005 Manufacturer/Su Tier l~'~~, ,. ~ Cheintrec~. 800 424=9300'~`~ pn Betco Corporation ° ~me <~~ - ~ (- ) 1001- Brown Avenue. Toledo, Ohio 43607 (419) 241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing: DSL/ NDSL All components listed unless noted elsewhere on,this"MSDS '' Protective"Clothing .Section ?. Composition and lnformatian on ingrsdients '' 1+Ca~e CAS # °1o by laposnre Lirnits~ LCq,IL!)~ Weilht Nonionic su~`actant ~ ~ ' ~ 9016-45-9 ~ <10 Not avaiia#~6e. ~'~ Not available ~ etrasodiurri sa#t of- ~ 6402-8 ~ . ~, Notavailable:- ~: " ~ ~ . ORAt_ (1D50); Acute: ethylendiamir~tetcaacetic.acid ~ 3030 mg/kg (Ratj. $oditrm Xylene-Suiforrate 1300-72-Z <S ~ Not~~avaliable.:~ ~ C?RA!_(LD50): Acute. ~~ , 650 rnglkg [Ratj:: ~ 5939 mgfkg (Mousej: Section ~3. Hazardsldentltic~rt.#on P'olential Acute' Hei~ltli No specific in[ormaiion is availab~e iti tier database regarding the acute toxic etlacts of thin ~k:!'fects material for ht~nians. Potential C'hranir Fteaith. Repe$ted skin exposure can produce local skin,destruction; t3f dermatiti"s. Effects" Carcinogealc;Effet~fs. Not classified of 1'ISted by 1ARC, NTP; (OSHA, EU and ACGIH. Section 4. First Afd Measures Eye~ICont&Ct~ - This product is an eye irritant. In caseof cor,t~ct wilts eyes, rinse immediatelywith plenty o#. water. Seek medical attention. Skin Contact ~ Ririse'with plenty of running water:- Inhatatiore No speci#ic~dati3, ~ - Ingestion May be irritating ;tq, gastxointestinal system,:. mouth, ~roai, and esophag~is., Vomiting and-diarrhea exceed :with large doses. Have conscious person drint< several` glasses of water or. milk: Seek n'ti3digl atten#ion. ~~ Section 5. Fire. Fighting: Measures Products ofCombusfion Not available. Fire Fighting Media and Instructions: Non=flammable substance. Special Remarkson,,Fire Hazards No additional remark. Special Remarks on Explosion Hazards No additional remark.. ~ ~• CS # 140181 Section' 6. Accid~ntat Release Measures Smug Spill and L:euk flt~sorb with an lrierl material and place in an appropriate waste disposal container. 1`,arge Spill and I:~eak litssorb vi+th'an ne~t-mat~'rial~and pu(the sp{Ned material in an appropriate waste disposal. P!eesondl'Protec'tion,,in. Splash gaggles. Rill suit.Boots. ~Gltav~s. Suggested protective clathing might not be ~ ~~. C'~sce ofa t~trge_Spili StxffiCiertf; ConsuiE a s~eciellst BEFORE Ftandling this;product. ~ec>t~on ~ Handlfng and Starage Precntition~: Avoid conta~'wlth eyes. D(? NtJT ingest:, Inecympat'ib'rlity No incoimpatible produci,,according #o;our data-base.- Storage Keep out of reach-'ot chlldrerti: ;Keep container; tightly; closed :and dry; I'or lnsfitutional and CoCnmercial tJse . exposure L.ikriiits 'Not avtilable: Section 8. ~jaosure~c~ntrols/Fersc~nal Profectlon ~l:ngieeeri~ngControls .Good generalventilation should be sufficient to control airborne ]eveis. Persrfnal Protection E,yc~ Safety glasses. 8udy No Special protective 'clothing is: r$quired': R+~p~frr~lar,~;Nt~#~appl`tcaktle...:-. ~ ~ ~ ~~ ~ ; c . . -. <_. Hands' Gloves. Protective Gluttting (Ptctograms)- .. Secfion 9. Physical and Chemical Properties Physical State and Liquid. Appearance 1Vlolecular Weight Not applicable. , pN _. 7 to 8r5 lBasica t?dor Pleasant. Taste-.~ NoYavailable, Color Yellow... Boiling/Condensation 100°C (212°F) Point- _-. , . Melting/Freezing Point Not available: Critical Temperature Not available: Instability Temperature Not available. Specific Gravity 1 (Water = 1J ~ ~ ~ ~ , ' Vapor 1'ressurc 20,mm of Hg (@ 20°C) p , ,. Va or Density „. -. .. .. - >1 (Air = 1) _ ,. :Volatility _.. ~ . Not available. VOC 8.5077. (9~l)~ .Evaporation hate ~, ~ `- <1 Dispersion Properties See solubility iri'water: Solubility - `Soluble .., The Product is: May be combustible at high temperature. . Auto-ignition Temperature Not 8vailable. Flash Points None to Boiling (TGC) Flammable Limits N/A Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability. of this product; in presence of various materials. Explosion Hazards in Presence of Various .Substances No "specific information is available in our database regarding the product's risks of explosion in the presence of various materials. Sectior~~90. StabJJFty and l~eacfJ~it~r flat:3 Sc~~bitity Tie product is stable. Tncompatibitit}~ with No .incompatible product accordiC~g to our da#a base. Yiarinus Substances Hazardous;t~ci-mposition. None Known `Products Section 19. TaxicologicaJ lnformatian ~Ra~utes~of>EOtry Absor6edthrough skitt:• Eyecontaat, hgestion. Toxic to 'tY Animals Acuteoral toxicity (LD$O): 3030 rhgtlcgjRatj, (Tetrasodium EDTA). _.._ Acute EC[eets an Humans. E3~es This prodeJCt is an eye;irritant. Skid 'Sllghtty i'rtitating ~ ~ ~~ - ... InArti'lutlaar Nest:~aveil8bte. In~estian Irritant. Vomiting and t)iarrhea possible Cbrantc. EilFeiets: an Repe~t~d;skirt exposure can produce local skin destruction, or derrriati#(s.' tfu.-riur~s: ~ ~ - _ - . ~SpecintRertt~rks on, ~~; :Na additional7ema~ic., Toxicity to Animals 5tfeciat Remarks fln.x Nq additional remark. Chronic Ettiects nn Humans Section 72.. Ecolo ical Information Ecotoxiciry.•° Not available. RODS and COD Not Available Products of Fossitily hazardous short" term degradation, products are not likely. However, long term Biodegradation degradation products.may arise.. " .. " Toxicity oCthe Products of Not available. Biodegradation Special Remarks on the No additional remark. , Products "of Biodegradation • Section °~3. Disposal Considerations 1~Va~stc tufortri~tion Vldastemust bedispos~ of in acct~rdance with federal, state and local environrnental ccsntxot .regulations.. . Waste Stream Nc>t available: " St:ctinn 75.Other Regulatory I»forrnatian and PJcfograms WHMIS"(Classificafion) WHMIS CLASS D-2: Material causing other toxic effects. T Regulatory Lists r N'o"products were found. "Other Regulations Not"aVailable. oi- of its ingredients Other Classifications HCS (U.S.A.) HCS CLASS', Irritating. substance, USA"Regulatory ". California prop. 65: This-product contains thefollowing ingredients,for Lists which the State of California has found to cause.:reproductve harm (female) which would require a warning under the statute; Ethylene Oxide,< 1 ppm California prop. 65: This product-.contains the following tngredtentsfor I whieh~tfi"e State of California has fountlao cause cancer which would require a warning under the.-statute: EthyleneOxide< 1 ppm• " ,~,; CS # 140181 - Massachusetts R~'K: Ethylene Oxide SARA 311/312:`Sodium xylene sulfonate; Nonionic Surfactant SARA 313: No components'found -0~1)~(EEC) This product is not classified according to`the EU regulations. ;Infernafional `tJo products were found. Regulations Lists 1`Iazardous Material ~` 1 National Fire Information S Stein ' 1P'~,i'~. u~''~"' O h'lammabilily Y , ' l) Protection U.S.A. - If CA It il~ ~ In5IN1)Illly ( ) ";Association . 1 `0 Physical Hazard Q , L___~ The Hazard Ranking systems presented on this M~~rovlde ony a quick referxnee for hazard Intormatlon: The ENTIRE Specific I lazard MSDS must be consuRed to determine any speciflc hazards,. First Aid measures, and,PPE'associated with this product. Section ~6. Other Informatfan Vutidstetti by Z)Thomas oti 4/29/Zt?t}S. Yt:t3liCd by DThafnas Printed 4R~f20tl5. ttifti!rmaNun ~onti~tt '8etco ~atporutia~a ; , ~1~0t~lBrown ~hv~nue~~. ~'iiieii~ C~hio~~60"7~ Nt?ti~ to l2eadrr Yp theh~rf~rf att~ ~knant~rftgr, !hr Imjnrrauti'nri ~ckNttntq~clhtr,~tn Lr arrrrrete. ftox~eti+er, rtc~Jthrr tha~akai•e nmmert srrp/~lfrr nut on}~ oj![c sub~tdiarJrsu,K.wmrs an>~ ttcttUtp rrhaLCOrvrrCur fhenrcttrrtrT or rn+rtplrr«tesx njttte infarrnattr~n rantaittNd h~rtJn. ~~7uaJ.drtrrrnlnullan uJxulraAitJtc• of an.~ ~raatertaf Lc Nec vr~Jt responsibtiftr nj'theuSRr. ~tlt malerJals mac ~resenrunkrtax•n harurds anJ,ehrsutd beused ev7rh t~uttYnn. /1Hhe~rr crrlalmhaaa~rCt art drserfAad hrrrAr, wa cwnnat =aarattre t, gtr A ttai these arc the ante. ha.arda that ex~i7. ~_ ~-OCATI o/1~ Q{SC.E~E~!/ ~3 /_o~ /c-~~ ~c CleanSource# 190121; ~BL~TERS Material Safety Data Sheet This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 /~ ~, Not controlled under WHMIS (Canada). WHMIS Z(Pl,~i„e/t/ograms) WHMIS (Classification) Section 1. Chemical Product and Company Identification Product Name/ Trade AF315 name Synonym Neutral pH Disinfectant/Deodorant/Detergent Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier BetCO Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL/ NDSL All components listed unless noted elsewhere on this MSDS HCS Class: Irritating substance. HCS coae 315 CAS # Not applicable. Validation Date 3/22/2004 Print Date 3/27/2004 m case or Emereencv Chemtrec (800) 424-9300 Protective Clothing d~ Section 2. Composition and7nformation on`ingi'edients Name CAS # % by Exposure Limits LCs°/LDs° Weight 1) Quaternary Ammonium Chloride 68424-85-1 2 Not available. Not available. 2) Isopropyl Alcohol 67-63-0 1-5 TWA: 400 (ppm) ORAL (LD50): Acute: TWA: 400 (ppm) from 16971 mg/kg [Rat]. OSHA (PEL) [United States] STEL: 500 (ppm) 3) Nonionic Surfactant 9016-45-9 1-5 Not available. Not available. Section'3. Hazards Identitcation Potential Acute Health Effects No specific information is available in our database regarding the acute toxic effects of this material for humans. Irritating to mouth, throat and stomach. This product is a severe eye irritant. This product may irritate eyes and skin upon contact. Potential Chronic Health Over-exposure by inhalation may cause respiratory irritation. Repeated skin exposure can produce Effects local skin destruction, or dermatitis. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First.Aid Measures Eye Contact Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek ' immediate medical attention. Skin Contact Wash gently and thoroughly the contaminated skin with running water and non-abrasive soap. Seek medical attention. Inhalation Allow the victim to rest in a well ventilated area. Ingestion Dilute with two glasses of water. Seek medical attention. _i ~ Sectian 5. Fire Fighting Measures can Qurce Products of Combustion Not available. Fire Fighting Media N/A and Instructions Special Remarks on Fire N/A Hazards Special Remarks on N/A Explosion Hazards Section 6. Accider-ta! Release Measures Small Spill and Leak Safety glasses recommended. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Incompatibility None known. Storage Keep out of the reach of children. Not for use or storage in or around the home. Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. PersonalProtecdon Eyes Safety glasses. Body No special recommendations. Respiratory Not applicable. Hands Gloves. Protective Clothing (Pictograms) Exposure Limits Isopropyl Alcohol TWA: 400 (ppm) TWA: 400 (ppm) from OSHA (PEL) STEL:500 (ppm) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Lemon like. Molecular Weight Not applicable. Taste Not available. pH 6.5 to 8.5 [Basic.] Color Yellow. (Light.) Boiling/Condensation Point 212°F initial Melting/Freezing Point Not available. 7 Critical Temperature Not available. CleanSoul'Ce# 190121 Instability Temperature Not available. Specific Gravity 1 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 90 VOC Not available. Evaporation Rate <1 Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points Not available. Flammable Limits Not available. Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Presence of Various Substances Not applicable Section 10. Stability and Reactivity. Data Stability The product is stable. Incompatibility with Various None known. Substances Hazardous Decomposition Will not occur. Products Section 11. Toxicological Information Routes of Entry Not available. Toxicity to Animals Acute oral toxicity (LD50): 4610 mg/kg [Rat]. (Nonionic Surfactant). Acute Effects on Humans Eyes Eye irritant. May cause redness and swelling of the conjunctiva. Skin Defatting to skih on repeated contact. Inhalation Slightly irritating to the respiratory system. Ingestion May be irritating to the gastrointestinal system. Vomiting and diarrhea expected with large doses. Chronic Effects on Humans Over-exposure by inhalation may cause respiratory irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Q Section 12.,Eeologica/lnformation ean` ours Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Not available. Biodegradation Special Remarks on the No additional remark. Products of Biodegradation Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section '75. -Other Regulatory Information and'Pictograms WHNIIS (Classification) Not controlled under VVHMIS (Canada). Regulatory Lists No products were found. Other Regulations Not available. or of its ingredients Other Classifications HCS (U.S.A.) HCS Class: Irritating substance. USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide < 1 ppm Massachusetts RTK: Ethylene Oxide SARA 311/312 MSDS distribution -chemical inventory -hazard identification: Isopropyl Alcohol: fire _~ DSD (EEC) Tl~i, ®~gl~~~~9~9cording to the EU regulations. International No products were found. Regulations Lists Hazardous Material 2 National Fire Flammability Information System ~.,4 tom! « ~ Protection (U.S.A.) '~ s Association (U.S.A.) Heattn ~~2 ~ ~ ~ lnstabifity Physcal Hazard ~~ Q The Hazard Ranking systems presented on this MSDS provide only a quick,reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 16. Other Information Validated by CRushton ou 3/22/2004. Verified by CRushton. Printed 3/27/2004. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best ojour knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of iu subsidiaries assumes any liability whatsoever (or the accuracy or completeness ojthe information contained herein. Final determination of suitability of any material rs the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. AUhough certain hazards are described herein, we cannot guarantee that these are the only hazards shat exist Validated on 3(22/2004. AF315 Page: 5/5 Continued on Next Page ~~ ` Co_3_Jo 5 I A-i '~~~'`'° 5 S G.L, ~Clsr~#c 160144 ,Ce.a~'~ f~ ~ ' c • Material Safety Data Sheet This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 E ~ a WHMIS (Pictograms) WHMIS (Classification) Section 1. Chemical Producf and Company Identification Product Name/ Trade Citrus Chisel name Synonym Natural Citrus Cleaner/Degreaser Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL/ NDSL All components listed unless noted elsewhere on this MSDS HCS CLASS: Corrosive liquid. HCS code 167 CAS # Not applicable. Validation Date 3/22/2004 Print Date 3/27/2004 In Case of Chemtrec (800) 424-9300 Emereencv Protective Clothing Section 2. Composition and Information on'Ingredients Name CAS # % by Exposure Limits LCso/LDso Weight 1) Sodium Metasilicate 6834-92-0 <10 Not available. Not available. 2) Nonionic Surfactant 9016-45-9 <2 Not available. Not available. 3) Cationic Surfactant 5197-80-8 <2 Not available. Not available. 4) Sodium Hydroxide 1310-73-2 1-5 TWA: 2 (mg/m') from Not available. OSHA (PEL) [United States] 5) Tetrasodium salt of 64-02-8 1-5 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraaceticaciti mg/kg [Rat]. Section 3. Hazards Identification Potential Acute Health Effects Corrosive to skin and eyes on contact. Skin contact may produce burns. May be irritating to the mucous membranes of the nose, throat and lungs. Potential Chronic Health Over-exposure by inhalation may cause respiratory irritation. Prolonged exposure may result in skin Effects burns and ulcerations. carcinogenic Effeets Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section'4. First Aid Measures Eye Contact Corrosive to eyes and skin. Call a poison control center or doctor immediately for treatment advice. Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Skin Contact Remove contaminated clothing and shoes. Rinse skin with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for further treatment advice. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5.'Fire'Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions Non-flammable substance. Special Remarks on Fire Hazards Not available. Special Remarks on Explosion Hazards No additional remark. Section 6. Acciden#al Release Measures Small Spi11 and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. a Large Spill Section 7. Handling and Storage Precautions Keep locked up. Keep container dry. DO NOT ingest. Do not breathe gas, fumes, vapor or spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Avoid breathing vapors or spray mists. Keep out of reach of children. For Institutional and Commercial-Use Incompatibility Strong acids. acids Storage Keep out of reach of children. Corrosive materials should be stored in a separate safety storage cabinet or room. For Institutional and Commercial Use Not for use or storage in or around the home. 'Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Work uniform or laboratory coat. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) 0 0 •• Exposure Limits Not available. Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.06 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density > 1 (Air = 1) Volatility 85 VOC 0.15% (By Weight) Evaporation Rate <1 compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: Non-flammable. Auto-ignition Temperature Not available. Flash Points None to Boiling (TCC) Flammable Limits Not Applicable Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of static discharge: Not available. Risks of explosion of the product in presence of mechanical impact: Not available. Section'10. Stabikty and Reactivity Dafa Stability The product is stable. Incompatibility with Various Strong acids. acids Substances Hazardous Decomposition Not available. Products Section 11. Toxicological Information Routes of Entry Eye Contact Ingestion. INHALATION Skin contact. Toxicity to Animals Acute oral toxicity (LD50): 3030 mg/kg [Rat]. (Tetrasodium EDTA). Acute Effects on Humans Eyes Corrosive to skin and eyes on contact. Eye contact can result in corneal damage . Skin Skin contact may produce burns. . Inhalation Slightly irritating to the respiratory system. Ingestion Irritating to the mouth, throat, and gastrointestinal system. Large doses may cause vomiting and diarrhea. Irritating to mouth, throat and stomach. May cause burns to mouth, throat and stomach. May cause headache, dizziness, nausea, vomiting and diarrhea. Chronic Effects on Humans Over-exposure by inhalation may cause respiratory irritation. Prolonged exposure may result in skin burns and ulcerations. i -,~ Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Ecological Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposa(Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 15. Other Regulatory Information and Pictograms WHMIS (Classification) E Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS CLASS: Corrosive liquid. ~.. i ~~-, ., USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide < 1 ppm . Massachusetts RTK: Ethylene Oxide SARA 311/312: Sodium Metasilicate SARA 313: No components were found. DSD (EEC) R35-Causes severe burns. International No products were found. Regulations Lists Hazardous Material fi__._.____ 3 National Fire Flammability Information System f) ' !~~,~~~ p Protection ~ (U.S.A.) --- Association (U.S.A.) Health 3 Q~ lnstabiGty Physical Nuard Q The Hazard Ranking systems preserrted on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consuked to determine any specific hazards, First Aid measures, and PPE associated with this product Section 96.>>Other Information - Validated by CRusbton on 3/22/2004. Verified by CRushton. Printed 3127/2004. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Obio 43607 Notice to Reader To the best of our knowledge, the injormatian contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Ahhough certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Validated on 3/2Z/2004. Citf us Chisel Page: 5/5 Continued on Next Page ~., j r~ [LD_C:RT_~on~~ o l-o~c 3 ,..~ ~~~ ~ C.IT~~s ~ ~Isrc # 170199 Material Safety Data Sh~ct S icto rams WHMIS Classification O WHMIS CLASS D-2: Material causing othertoxic effects. T Section 7. Chemical Product and Company ldentif;cation Product Name/ Trade Clear Image Concentrate name Synonym Non-Ammoniated Glass Cleaner Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS HCS HCS Class: Irritating substance. Code 199 CAS # Not applicable. Validation Date 8/11/2003 Print Date 8/13/2003 In Case of Chemtrec (800) 424-9300 Emereencv Protective Clothing ~~~ Section 2. Compositiomand Information on Ingredients Name CAS # % by Exposure Limits LCso/LDso Weight 1) Water 7732-18-5 55-60 Not available. Not available. 2) 2-Butoxyethanol 111-76-2 35-40 TWA: 20 (ppm) from ORAL (LD50): Acute: 1746 ACGIH (TLV) [United mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States] 3) Sodium Lauryl Sulfate 151-21-3 0-5 Not available. Not available. 4) Sodium Xylene Sulfonate 1300-72-7 0-5 Not available. Not available. 5) Tetrasodium salt of 64-02-8 0-5 Not available. ORAL (LD50): Acute: 3030 . ethylendiaminetetraacetic acid mg/kg [Rat]. 6) Perfume Oil N/A 0-5 Not available. Not available. 7) Dye N/A 0-5 Not available. Not available. 8) Nonionic Surfactant 66455-15-0 0-5 Not available. Not available. ' 'Section 3. Hazards Identification I I Potential Acute Health Effects Harmful if swallowed. Harmful if absorbed through the skin. Potential Chronic Health Over-exposure by inhalation may cause respiratory irritation. Repeated skin exposure can produce Effects local skin destruction, or dermatitis. Repeated or prolonged exposure to the substance can produce blood disorders. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. However, in light of good industrial hygiene, exposure to any chemical should be kept to a minimum. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. ~' Section 4. First Aid Measures Eye Contact Flush with large quantities of water. Seek medical attention if irritation persists. Skin Contact Flush with large quantities of water. Seek medical attention if irritation persists. Inhalation Get to fresh air. Seek medical attention if irritation persists. Ingestion INDUCE VOMITING by sticking finger in throat. Seek immediate medical attention. Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media N/A and Instructions Special Remarks on Fire N/A Hazards Special Remarks on N/A Explosion Hazards --_ Section 6. Accidental Release Measures Small Spill and Leak Safety glasses recommended. Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Avoid to runoff to sewers and waterways. Wear Protective Clothing. Absorb with inert Material. Contact you local Emergency planning commission for further instructions. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions Keep out of reach of children. Keep locked up. For Institutional and Commercial Use Incompatibility None known. Storage Keep out of the reach of children. Not for use or storage in or around the home. Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient for most conditions. Local exhaust ventilation may be necessary for some operations. Personal Protection Eyes Splash goggles. Body No special protective clothing is required. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves. Protective Clothing (Pictograms) ~ 0 •• Exposure Limits 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Consult local authorities for acceptable exposure limits. ~_ " Section 9. Physical and Chemical Properties. Physical State and Appearance Liquid. Odor Characteristic. Molecular Weight Not applicable. Taste Not available. pH 11 to 12 [Basic.] Color Blue. Boiling/Condensation Point 209°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 0.96 (Water = 1) Vapor Pressure 25mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 100 VOC 359.48 (g/I). Evaporation Rate >1 compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-igoition Temperature Not available. Flash Points Not available. Flammable Limits Not available. Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Presence of Various Substances Not applicable Section 10. Stability and Reactivity Dafa Stability ~ The product is stable. Incompatibility with Various None known. Substauces Hazardous Decomposition Will not occur. Products r., - ~~ a Section 11. Toxicological lnforrnation Routes of Entry Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). Acute Effects on Humans Eyes Eye irritant. Liquid and mists may damage the eyes causing corneal injury. Skin Skin irritant. May cause moderate redness and swelling. Inhalation Vapors may be irritating to mucous membranes of the nose, throat, and lungs. Ingestion May cause headache, dizziness, nausea, vomiting, and diarrhea. Chronic Effects on Humans Over-exposure by inhalation may cause respiratory irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated or prolonged exposure to the substance can produce blood disorders. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. However, in light of good industrial hygiene, exposure to any chemical should be kept to a minimum. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Ecological Information.. Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal Considerations Waste Information Any method in accordance with allapplicable local ,state, and federal regulations. Waste Stream Not available. Section 14. Transport Information_ DOT (U.S.A) (Pictograms) ~~ TDG Classification Not controlled under TDG (Canada). D [N UN, Proper Shipping Not applicable. ame, PG :t- ~- Transportation Not available. Special Provisions for Not applicable. Transport Section 15. Other Regulatory Irlformation and Pictograms WHNIIS (Classification) VVHMIS CLASS D-2: Material causing other toxic effects. O T Regulatory Lists Other Regulations Other Classifications HCS (U.S.A.) HCS Class: Irritating substance. USA Regulatory Lists SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) R22- Harmful if swallowed. R36/38-Irritating to eyes and skin. International No products were found. Regulations Lists Hazardous Material * 2 National Fire Information S stem Flammability Y krr~_~ j p Protection p (U.S.A.) Association (U.S.A.) Healtn < 1 (~ fnstabisty Physical Hazard j Q ` ~ Specific Hazazd The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product, Section 16. Other Information Validated by CRushton on 8/11/2003. Verified by CRushton. Printed 8/13/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any ojits subsidiaries assumes any liability whatsoever jor the accuracy or completeness ojthe information contained herein. Final determination of suitability of any material is the sole responsibility ojthe user. Al[ materials may present unknown hazards and should be used with caution. Ahhough certain hazards are described herein, we cannotguarantee that these are the only hazards that exist Validated on 8/11/2003. Clear Image Concentrate Page: 5/6 '~ L T_I_CY_~~ CD3^_7_D_z/~~ ~~ Clsrc # 240108 ~- DSL Material Safe Data Sheet ty ® I CLASS E: Corrosive liquid. b Section' 7. Chemical Proofuct and Company Identf~catfon Product Name/ Trade name M./~1,~. Synonym Mild Acid Detergent Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Beteo Corporation 1001 Brown Avenue Toledo, Oh 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. ,DSL DSL : All components listed unless noted elsewhere on this MSDS HCS HCS Class: Corrosive liquid. Code 135 CAS # Mixture. Validation Date 8/11/2003 Print Date 8/13/2003 -n case or Chemtrec (800) 424-9300 Emereencv Protective Clothing ~~~ Section 2. Composition and Information on ingredienfs Name CAS # % by Exposure Limits LCsi/LDS„ Weight 1) Water 7732-18-5 0-100 Not avai{able. Not available. 2) Phosphoric Acid 7664-38-2 30-35 TWA: 1 (mg/m') Not available. TWA: 1 (mg/m') from OSHA (PEL) [United States] STEL:3 (mglm') 3) Anionic Surfactant 27176-87-0 0-5 Not available. Not available. 4) Nonionic Surfactant 9016-45-9 0-5 Not available. Not available. 5) Nonionic Surfactant 61788-90-7 0-5 Not available. ORAL (LD50): Acute: 4610 mg/kg [Rat]. 6) Dye NIA 0-5 Not available. Not available. 7) Gluconic Acid 526-95-4 0-5 Not available. Not available. Section 3. Hazards. ldenti>rcation `' Potential Acute Health Effects Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Potential Chronic Health Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause Effects respiratory irritation. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. 'Section 4. First Aid Measures Eye Contact Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor immediately for treatment advice. Skin Contact Rinse skin with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for further treatment advice. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media N/A and Instructions Special Remarks on Fire N/A Hazards Special Remarks on N/A Explosion Hazards Section 6. Accidents! Re/ease Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Full suit. Boots. Gloves (impervious). Face shield. a Large Spill ' Section 7. Handling and Storage Precautions Ensure that eyewash station and safety shower is proximal to the work-station location. Avoid contact with skin and eyes Do not breathe gas/fumes/ vapor/spray. Incompatibility Strong alkalis, oxidizers, reactive metals. Storage Corrosive materials should be stored in a separate safety storage cabinet or room. Keep out of reach of children. This product should be stored AWAY from oxidizing materials and strong bases. Not for use or storage in or around the home. ` Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Long Pants and Long Sleeves to avoid skin cotact. Xespirarory Wear appropriate respirator when ventilation is inadequate. Ha~rds Gloves (impervious). Protective Clothing (Pictograms) p ^ •• Exposure Limits Phosphoric Acid TWA: 1 (mg/m') TWA: 1 (mg/m') from OSHA (PEL) [United States] Consult local authorities for acceptable exposure limits. Section 9. Physical `and Chemical Properties Physical State and Appearance Liquid. Odor Odorless. Molecular Weight Not applicable. Taste pH 1.5 to 2 [Acidic.] Color Yellow. Boiling/Condensation Point 218°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.18 (Water = 1) Vapor Pressure <20mm Hg @ 68°F Vapor Density > 1 (Air = 1) Volatility 60 VOC Not available. Evaporation Rate <1 compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points Not available. Flammable Limits Not available. Fire Hazards in Presence of Various Substances Not available. Explosion Hazards in Presence of Various Substances Not applicable Section 10. Stability and Reactivity Data Stabilih~ The product is stable. Incompatibilirr- with Various Strong alkalis, oxidizers, reactive metals. Substances Hazardous Decomposition not available Products ^{ Section 11. Toxicological lnforn-afion Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals Acute oral toxicity (LD50): 4610 mg/kg [Rat]. (Nonionic Surfactant). Acute EtTects on Humans Eyes Severe eye irritant. Liquid and mist may burn or injure the eyes. Skin Severe skin irritant. Prolonged or repeated contact can cause chemical burns or dermatitis. Iniraiarion May be irritating to mucous membranes of the nose, throat, and lungs. Ingestion May be irritating or corrosive to the mouth and throat. Can cause nausea and vomiting. Chronic Effects on Humans Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. Special Remarks on Toxicity Not available. to Animals Special Remarks on Chronic Not available. Effects on Humans Section 72. Ecological Information Ecotoxicity Not available. BODS and COD Will not occur Products of Biodegradation Not available. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation Not available. Section 93. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 15. Other Regulatory Information and Pictograms WHMIS (Classification) CLASS E: Corrosive liquid. Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS Class: Corrosive liquid. USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive harm (female] which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide <1 ppm Massachusetts RTK: Ethylene Oxide SARA 311/312 MSDS distribution -chemical inventory -hazard identification: Phosphoric Acid SARA 313 toxic chemical notification and release reporting: Phosphoric Acid DSD (EEC) R35-Causes severe burns. International No products were found. Regulations Lists Hazardous Material Information System ~ 3 I National Fire Flammability ;~ 6~! U° Protection (U.S.A.) , --- Association (U.S.A.) nealfn 3 ~ InstabiGry P i l H d ~ hys azar ca The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to determine any speck hazards, First Aid measures, and PPE associated with this product. Section 7ti. Ofher Information Validated by CRushton on 8/11/2003. Verified by CRushton. Printed 8/13/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader Tn the best of our knowledge, the injornratinn contained herein Ls accurate. However, neither the above named supplier nor any njiGS subsidiaries ass'unt¢S any liability whaLSn¢v¢r for the accuracy or completeness of the information contained herein. ' Fina[ determination nj.cuitabiliry njany material is the sole responsibility njthe user. All materials may present unknown hazards and should be used with wu6nn. Although certain hazards are described herein, we cannntguarantee that these are t/+e only hazards that exist Validated on 8/I 1/2003. M,,4.D, Page: 5/5 Gontinuecl on Next Page C ~O_GATI_o nl-~ A 15t.E 8/N -O3Io7_/~^ -_~ ~O (TL, Clsrc # 110231"] Material Safety Data Sheet WHMIS (Pictograms) WHMIS (Classification) WHMIS Class E: Corrosive liquid. WHMIS CLASS D-2: Material causing v;°°- O other toxic effects. Section 1. Chemical Product and Company Identification Product Name/ Trade Sure Bet name Synonym Foaming Shower/Restroom/Cleaner Chemical Family Not Applicable Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS HCS Class: Corrosive material Code 314 CAS # Not applicable. Validation Date 8/11/2003 Print Date 8/13/2003 In Case of Chemtrec (800)' 424-9300 Emereencv Protective Clothing ~~® Section_2. Composition andJnformation on Ingredients Name CAS # % by Exposure Limits LCso/LDso Weight 1) Water 7732-18-5 >53 Not available. Not available. 2) Phosphoric Acid 7664-38-2 <20 TWA: 1 (mg/m') Not available. TWA: 1 (mg/m') from OSHA (PEL) [United States] 3) Citric Acid 77-92-9 <11 Not available. Not available. 4) Nonionic Surfactant 61788-90-7 <11 Not available. ORAL (LD50): Acute: 4610 mg/kg [Rat]. 5) Quaternary Ammonium Chloride 68424-95-3 1.56 Not available. Not available. 6) Nonionic Surfactant 9016-45-9 <1.44 Not available. Not available. 7) Perfume Oil N/A <1 Not available. Not available. 8) Dye N/A <1 Not available. Not available. Section 3. Hazards Identification Potential Acute Health Effects Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Potential Chronic Health Over-exposure by inhalation may cause respiratory irritation. Repeated or prolonged contact with Effects spray mist may produce chronic eye irritation and severe skin irritation. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. {. ~: Section 4. First Aid Measures Eye Contact Causes severe eye and skin irritation. IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek immediate medical attention. Skin Contact Corrosive to eyes and skin. Wash gently and thoroughly the contaminated skin with running water and non abrasive soap for 15 minutes. Seek medical attention. Inhalation Evacuate the victim to a safe area as soon as possible. Seek medical attention. Ingestion DO NOT induce vomiting. Have conscious person drink several glasses of water or milk. Seek immediate medical attention. Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions Non-flammable substance. Special Remarks on Fire Hazards N/A Special Remarks on Explosion Hazards N/A Section 6. Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Prevent entry into sewers, basements or confined areas. Wear Protective Clothing. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions Avoid contact with skin and eyes. DO NOT ingest. Use only in well ventilated areas. Incompatibility acids oxidizing agents Storage Keep out of the reach of children. Not for use or storage in or around the home. Section 8. Exposure Contro/slPersonal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Lab coat. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) ~ ^ •• Exposure Limits Phosphoric Acid TWA: 1 (mg/m') from OSHA (PEL) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Pleasant. Molecular Weight Not applicable. Taste Not available. pH 1.5 to 2 [Acidic.] Color Green. Boiling/Condensation Point 88°C (190.4°F) Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.06 (Water = 1) Vapor Pressure <20 mm of Hg (@ 20°C) Vapor Density >1 (Air = 1) Volatility Not available. VOC Not available. Evaporation Rate <1 compared to Water Dispersion Properties See solubility in water. Solubility Soluble The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points None to Boiling (TCC) Flammable Limits Not available. Fire Hazards in Presence of various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Preseuce of Various Substances Not applicable Section 10. Stability;and Reactivity Data Stability The product is stable. Incompatibility with Various acids oxidizing agents Substances Hazardous Decomposition , Not available. Products r. Section 11. Toxicological Information Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals Acute oral toxicity (LD50): 4610 mg/kg [Rat]. (Nonionic Surfactant). Acute Effects on Humans Eyes Severe eye irritant. Liquid and mist may burn or injure the eyes. Skin Severe skin irritant. Prolonged or repeated contact can cause chemical burns or dermatitis. Inhalation May be irritating to mucous membranes of the nose, throat, and lungs. Ingesrion May be irritating to the mouth, throat, and gastrointestinal system. Nausea, vomiting, and diarrhea expected with large doses. May be fatal if swallowed. Chronic Effects on Humans Over-exposure by inhalation may cause respiratory irritation. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12.'Ecologica! Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section `13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. ' Section 14, Transport Information DOT (U.S.A) (Pictograms) TDG Classification 8 .~~ UN, Proper Shipping Shipping name: Corrosive liquids n.o.s. UNNA: 1760 PG: III ~, PG time Transportation Not available. -. Special Provisions for Not available. Transport Section 15. Other Regulafory Information and Pictograms WHNIIS (Classification) WHMIS Class E: Corrosive liquid. VVHMIS CLASS D-2: Material causing other toxic effects. ~. O Regulatory Lists All components Found on DSL Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) Class: Corrosive material USA Regulatory Lists SARA 311/312 MSDS distribution -chemical inventory -hazard identification: Phosphoric Acid SARA 313 toxic chemical notification and release reporting: Phosphoric Acid DSD (EEC) R35- Causes severe burns. International No products were found. Regulations Lists Hazardous Material Information System 3 National Fire Flamroabiliry ~~,~,,,~, ~; '~ Protection (U.S.A.) ~ / ~ ~ E>,SSOC1at10Il (LJ.S.A.) Health ~ 3 ~~ Instability Ph sical Haza d Q y r The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE ~ Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated wkh this product. °` "Section 16. Other Information Validated by CRushton on 8/11/2003. Verified by CRushton. Printed 8/13/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any Uability whatsoever jnr the accuracy nr completeness of [he information contained herein. Final determination njsuitability of any material is [he sole responsibility of the user. AU materials may present unknown hazards and should be used with caution. AUhough certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Validated on 8/11/2003. Sure Bet Page: 5/5 Continued on Next Page, ~~ ~- Ti oN --1 ~~9_D_/_a~ ~~%-D_7~~(p L_~~~ ~.~ ~ {, Il~~~s Material Safet Data Sheet y This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 ® WHMIS (Pictograms) Not controlled under WHMIS (Canada). WHMIS (Classification) Section 1. Ghemical Product and Company Idenfification Product Name/ Trade name AF315 Synonym Neutral pH Disinfectant/Deodorant/Detergent Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier getco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing DSL/ NDSL All components listed unless noted elsewhere on this MSDS HCS Class: Irritating substance. HCS coae 315 CAS # Not applicable. Validation Date 3/2/2007 Print Date 3/24/2007 In Case of Emeraency Chemtrec (800) 424-9300 Protective Clothing ~7 Section. 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCso/LDso Weight Isopropyl Alcohol 67-63-0 1 - 5 OSHA (United States). ORAL (LD50): Acute: TWA: 400 ppm 16971 mg/kg [Rat]. Nonionic Surfactant 9016-45-9 1 - 5 Not available. Not available. Quaternary Ammonium Chloride 68424-85-1 2 Not available. Not available. Section 3. Hazards Identification Potential Acute Health No specific information is available in our database regarding the acute toxic effects of this Effects material for humans. Irritating to mouth, throat and stomach. This product is a severe eye irritant. This product may irritate eyes and skin upon contact. Potential Chronic Health Over-exposure by inhalation may cause respiratory irritation. Repeated skin exposure can Effects produce local skin destruction, or dermatitis. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Sectiom'4. First Aid Measures Eye Contact Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention. Skin Contact Wash gently and thoroughly the contaminated skin with running water and non-abrasive soap. Seek medical attention. Inhalation Allow the victim to rest in a well ventilated area. Ingestion Dilute with two glasses of water. Seek medical attention. ~~ ~ Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions N/A Special Remarks on Fire Hazards N/A Special Remarks on Explosion Hazards N/A Section 6. Accidental Release Measures Small Spill and Leak Safety glasses recommended. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be Case of a Large Spill sufficient; consult a specialist BEFORE handling this product. Section` 7. Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Incompatibility None known. Storage Keep out of the reach of children. Not for use or storage in or around the home. Section 8. Exposure ControlsfPersonal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Safety glasses. Body No special recommendations. Respiratory Not applicable. Hands Gloves. Protective Clothing (Pictograms) Exposure Limits Isopropyl AlCOhol TWA: 400 (ppm) TWA: 400 (ppm) from OSHA (PEL) STEL: 500 (ppm) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Pleasant. (Strong.) Molecular Weight Not applicable. Taste Not available. pH 6.5 to 8.5 [Basic.] Color Blue. Boiling/Condensation Point 212°F initial Melting/Freezing Point Not available. Critical Temperature Not available. ~~ Instability Temperature Not available. Specific Gravity 1 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 90 VOC Not available. Evaporation Rate <1 Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points Not available. Flammable Limits Not available. Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Presence of Various Substances Not applicable Section 10. Stability and Reactivity Data Stability The product is stable. Incompatibility with None known. Various Substances Hazardous Decomposition Will not occur. Products Section 11. "Toxicological Information Routes of Entry Not available. Toxicity to Animals Acute oral toxicity (1.D50): 4610 mg/kg [RatJ. (Nonionic Surfactant). Acute Effects on Humans Eyes Eye irritant. May cause redness and swelling of the conjunctiva. Skin Defatting to skin on repeated contact. Inhalation Slightly irritating to the respiratory system. Ingestion May be irritating to the gastrointestinal system. Vomiting and diarrhea expected with large doses. Chronic Effects on Over-exposure by inhalation may cause respiratory irritation. Repeated skin exposure can Humans produce local skin destruction, or dermatitis. Special Remarks on No additional remark. Toxicity to Animals Special Remarks on No additional remark. Chronic Effects on Humans ;> Section 12. Ecolo ical Information Ecotoxicity Not available. BODS and COD Not available. Products of Possibly hazardous short term degradation products are not likely. However, long term Biodegradation degradation products may arise. Toxicity of the Products of Not available. Biodegradation Special Remarks on the No additional remark. Products of Biodegradation .Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 14. Transport Information DOT (U.S.A) (Pictograms) TDG Classification Not controlled under TDG (Canada). IN UN, Proper Shipping Not applicable. ame, PG aritime Transportation NOt available. Special Provisions for Not applicable. Transport Section 15. Other Regulatory Information and Pictograms WHMIS (Classification) Not controlled under WHMIS (Canada). Regulatory Lists No products were found. Other Regulations Not available. or of its ingredients Other Classifications HCS (U.S.A.) HCS Class: Irritating substance. USA Regulatory California prop. 65: This product contains the following ingredients for Lists which the State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide < 1 ppm Massachusetts RTK: Ethylene Oxide ,. ~. .,« SARA 311/312 MSDS distribution -chemical inventory -hazard identification: Isogroovl Alcohol: fire DSD (EEC) This product is not classified according to the EU regulations. International No products were found. Regulations Lists Hazardous Material 2 National Fire Flammability Information System ' p Protection ~ ~T J! i'~7~~~ Instabili ~'S"~'~ Physical Hazard O EISSOCIatiOn Health ?, Q ty (iJ.S.A.) The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 96. `Other'lnformation Validated by CRushton on 3/2/2007. Verified by CRushton. Printed 3/24/2007. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Readel To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Validated on 3/2/2007. AF315 Pa e: 5/5 Continued on Next Page _ t LD_3_l_0~//~/~ ~_~ JC GL Clsrc # 020327 -......, ~ `~ Material Safe Data Sheet ty This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 CLASS D-26: Material causing other toxic effects (TOXIC). CIaSS: Irritating substance. T WHMIS (Pictograms) WHMIS (Classification) Section 7. Chemical Product and Company Identification i Proanet Name/ Traae name Green Earth Peroxide Cleaner Synonym Hydrogen Peroxide Cleaner Chemical Family Not Applicable Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Oh 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from IisNng. DSL/ NDSL All components listed unless noted elsewhere on this MSDS HCS coae 336 CAS # Mixture. Validation Date 6/21/2004 Print Date 6/21/2004 to case or Chemtrec (800) 424-9300 Emereencv Protective Clothing W Section 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCso/LDso Weight 1) Hydrogen Peroxide 7722-84-1 1-5 Not available. Not available. 2) Sodium Lauryl Sulfate 151-21-3 1-5 Not available. Not available. 3) Hydrogen Peroxide Stabilizer N/A 1-5 Not available. Not available. 4) Alcohol Ethoxylate 68439-46-3 1-5 Not available. Not available. Section 3. Hazards Identification Potential Acute Health Effects Hazardous in case of eye contact (irritant). Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. Non-corrosive for skin. Non-sensitizer for skin. Non-permeator by skin. Non-corrosive to .the eyes. Potential Chronic Health Repeated or prolonged exposure is not known to aggravate medical condition. Effects Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact Avoid contact with eyes Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek medical attention. Skin Contact After contact with skin, wash immediately with plenty of water. Seek medical attention, if irritation persists. Inhalation Allow the victim to rest in a well ventilated area. Ingestion Do not induce vomiting. Have conscious person drink several glasses of water. Seek immediate medical attention. NEVER give an unconscious person anything to ingest. Section 5. Fire Fighting Measures Products of Combustion Oxygen Fire Fighting Media and Instructions SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks on Fire Hazards Not available. Special Remarks on Explosion Hazards Not available. Section 6. Accidental Release Measures Small Spill and Leak Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7°Handling and''Storage Precautions Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Avoid contact with eyes Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Incompatibility Slightly reactive with oxidizing agents, reducing materials Storage Keep away from direct sunlight or strong incandescent light. Keep away from heat, sparks and flame. Keep away from incompatibles. Use with adequate ventilation. Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Safety glasses. Body No special recommendations. Respiratory A respirator is not needed under normal and intended conditions of product use. Hands Gloves. Protective Clothing (Pictograms) ~~J V V Exposure Limits Not available. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Minty. Molecular Weight Not applicable. Taste Not available. pH 3.5 to 4.5 [Acidic.] Color Water White. BoiGng/Condensation Point 212 F Melting/Freezing Point Not available. Critical Temperature Not available. .~ Instability Temperature NOt available. Specific Gravity 1.002 (Water = 1) Vapor Pressure >1 Vapor Density >1 (Air = 1) Volatility Not available. VOC Not available. Evaporation Rate Not available. Dispersion Properties See solubility in water. Solubility Soluble in cold water, hot water. The Product is: May be combustible at high temperature. Auto-igniNon Temperature Not available. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits Not available. Fire Hazards in Presence of Various Substances Not available. Explosion Hazards in Presence of Various Substances Containers may explode when heated. Section 10, Stability and Reactivity Data Stability The product is stable. Incompatibility with Various ,Slightly reactive with oxidizing agents, reducing materials Substances Hazardous Decomposition Not available. Products Section 11. Toxicological Information Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals LD50: Not available. LC50: Not available. Acute Effects on Humans Eyes Hazardous in case of eye contact (irritant). Non-corrosive to the eyes. Skin Slightly hazardous in case of skin contact (irritant). Inhalation Slightly hazardous in case of inhalation. Ingestion Slightly hazardous in case of ingestion. Chronic Effects on Humans Repeated or prolonged exposure is not known to aggravate medical condition. Special Remarks on Toxicity NOt available. to Animals Special Remarks on Chronic Not available. Effects on Humans Section 12 Ecological Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation These products are carbon oxides (CO, C02) and water. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation Not available. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 15. Other Regulatory Information and Pictograms.. WHNIIS (Classification) CLASS D-2B: Material causing other toxic effects (TOXIC). T O Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) Class: Irritating substance. USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive effects which would require a warning under the statute: Ethylene Oxide <1 ppm California prop. 65: This product contains. the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide <1 ppm Massachusetts RTK: Ethylene Oxide <1 ppm SARA 311/312 MSDS distribution -chemical inventory -hazard identification: Nonionic Surfactant: immediate health hazard DSD (EEC) This product is not classified according to the EU regulations. International No products were found. Regulations Lists Hazardous Material 1 National Fire Flammability Information System ~~~ „~ ~ Protection ~~ , ~. ) Physical Hazard i Association (U.S.A.) Health < 1 ' Instability The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazazd MSDS must be consuked to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 16. Other Information Validated by CRushton on 6/21/2004. VeriSed by CRushton. Printed 6/21/2004. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader Tn the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any ojits subsidiaries assumes any liability whatsoever for the accuracy nr completeness njthe injnrmation contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Validated on 6/21/2004. Green Earth Peroxide Cleaner Page: 5/5 Continued on Next Page ~~ . . ~` ~~ 'L, IVlaterial Safety Data Sheet This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 WHMIS Class D-ZB: Material causing other toxic effects T (TOxlc). WHMIS (Pictograms) WHMIS (Classification) Section 1. Chemical Product and Company Identification Product Name/ Best Scent Ocean Breeze Trade name Synonym Highly Concentrated Odor Counteractant Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing DSL/ NDSL All components listed unless noted elsewhere on this, MSDS HCS Class: Irritating substance. HCS Code 231 CAS # Not applicable. Validation Date 3/2/2007 Print Date 3/24/2007 In Case of Emereency Chemtrec (800) 424-9300 Protective Clothing W :Section 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCsa/LDso Weight Nonionic Surfactant 9016-45-9 5 - 10 Not available. Not available. Ethanol 64-17-5 1 - 5 OSHA (United States). ORAL (LD50): Acute: TWA: 1000 ppm 3450 mg/kg [Mouse]. ACGIH (United States). 7060 mg/kg [Rat]. TWA: 1000 ppm NIOSH TWA: 1000 mg/m s Sodium Xylene Sulfonate 1300-72-7 1 - 5 Not available. ORAL (LD50): Acute: 650 mg/kg [Rat]. 5939 mg/kg [Mouse]. Malodor Counteractant N/A 1 - 2 Not available. Not available. Section 3. Hazards Identification Potential Acute Health Mildly irritating to the eyes. Vomiting and Diarrhea possible Effects Potential Chronic Health Repeated skin exposure can produce local skin destruction, or dermatitis. Effects Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact Flush eyes with large quantities of water. Seek medical attention if irritation persists. Skin Contact Flush with water. Seek medical attention if irritation persists. Inhalation N/A Ingestion Dilute with two glasses of water. Seek medical attention. Section `5. Fire Figh#ing Measures. Products of Combustion Not available. Fire Fighting Media and Instructions N/A , Special Remarks on Fire Hazards N/A Special Remarks on Explosion Hazards N/A ~ _ Section 6. Accidental Release Measures ~ Small Spill and Leak Large Spill and Leak Personal Protection in Case of a Large Spill Safety glasses recommended. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions No specific safety phrase has been found applicable for this product. Incompatibility None known. Storage Keep out of reach of children. For Institutional and Commercial Use Section 8. Exposure. Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Safety glasses. Body No special protective clothing is required. Respiratory No special protective clothing is required. Hands Gloves. Protective Clothing (Pictograms) Exposure Limits Not available. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. (Thin Liquid) , Odor Lemon like. (Strong.) Molecular Weight Not applicable. Taste Not available. pH 7 to 8 [Basic.] Color Yellow. Boiling/Condensation Point 212°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.0067 (Water = .1) Vapor Pressure Not Determined Vapor Density >1 (Air = 1) Volatility 90 VOC Not available. Evaporation Rate <1 Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits Not available. Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Presence of Various Substances Not applicable .....Section 10.; Stability and Reactivity. Data Stability The product is stable. Incompatibility with None known. Various Substances Hazardous Decomposition Will not occur. Products ,Section 11. Toxicological Information Routes of Entry Eye contact. Toxicity to Animals Acute oral toxicity (LD50): 650 mg/kg [Rat]. (Sodium Xylene Sulfonate). Acute toxicity of the gas (LC50): 20000 ppm 10 hour(s) [Rat]. (Ethanol). Acute Effects on Humans Eyes Eye irritant, May cause redness and swelling of the conjunctiva. Skin Defatting to skin on repeated contact. Inhalation N/A Ingestion May be irritating to the gastrointestinal system. Vomiting and diarrhea expected with large doses. Chronic Effects on Repeated skin exposure can produce local skin destruction, or dermatitis. Humans Special Remarks on No additional remark. Toxicity to Animals Special Remarks on No additional remark. Chronic Effects on Humans ~ . -. ;. Section' 12. Ecolo ical Information Ecotoxicity Not available. BODS and COD Not available. Products of Possibly hazardous short term degradation products are not likely. However, long term Biodegradation degradation products may arise. Toxicity of the Products of Not available. Biodegradation Special Remarks on the No additional remark. Products of Biodegradation Sectionl3. Disposal Considerations - Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 14: Transport lnformation DOT (U.S.A) (Pictograms) TDG Classification Not controlled under TDG (Canada). IN UN, Proper Shipping Not applicable. ame, PG aritime Transportation Not available. Special Provisions for Not applicable. Transport Section 15. Other Regulatory lnformation and Pictograms WHMIS (Classification) WHMIS Class D-26: Material causing other toxic effects (TOXIC). O T Regulatory Lists No products were found. Other Regulations Not available. or of its ingredients Other Classifications HCS (U.S.A.) HCS Class: Irritating substance. USA Regulatory California prop. 65: This product contains the following ingredients for Lists which the State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide < 1 ppm Pennsylvania RTK: Propylene Glycol Massachusetts RTK: Ethylene Oxide Y ., SARA 311/312 MSDS distribution -chemical inventory -hazard identification: Isooroovl Alcohol: fire DSD (EEC) This product is not classified according to the EU regulations. International No products were found. Regulations Lists Hazardous Material 1 National Fire Information System -- FtammabiL'ty :~„~ ~ 0 Protection ~ (U.S.A.) Physical Hazard 0 Association Health 1 O Instability (U.S.A.) The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section,16. Other Information Validated by CRushton on 3/2/2007. Verified by CRushton. Printed 3/24/2007. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Readel To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material, is the sole responsibility of the user. Al! materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Validated on 3/2/2007. Best Scent Ocean Breeze ~ Pa e: 5/5 Continued on Next Page.... CL.OC~TI oN .> 1~15tC r8/nJ D3 ~ o~ _D_I G~ Clsrc #-060144 ~~r ~~ ~ ~ ~ Material Safety Data Sheet WHMIS icto rams WHMIS WHMIS CLASS E: Corrosive liquid. a: Section ?. Chemical Product and Company Identification Product Name/ Trade name Fiber Pro Red and Brown Out Synonym Tannin Treatment and Debrowner Chemical Family Not Applicable Chemical Formula Not Applicable Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS HCS HCS CLASS: Corrosive liquid. Code 419 CAS # Mixture. Validation Date 4/29/2003 Print Date 7/28/2003 In Case of Chemtrec (800) 424-9300 Emereencv Protective Clothing ~~~ Section 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCso/LDso Weight 1) Water 7732-18-5 90-100 Not available. Not available. 2) Hydrochloric Acid 7647-01-0 1-2 STEL: 5 Not available. 3) Ammonium Bifluoride 1341-49-7 1-2 Not available. Not available. Section 3. Hazards Identification Potential Acute Health Effects Corrosive to skin and eyes on contact. Tissue Destruction Possible. Eye contact can result in corneal damage or blindness. Potential Chronic Health Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin Effects irritation. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention. Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Inhalation Evacuate the victim to a safe area as soon as possible. Seek IMMEDIATE medical attention. Ingestion DO NOT induce vomiting. Have conscious person drink several glasses of water or milk. Seek immediate medical attention. Section 5.'Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions Non-flammable substance. Special Remarks on Fire Hazards No additional remark. Special Remarks on Explosion Hazards No additional remark. Section 6.-Accidents! Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. IN CASE OF A LARGE SPILL Prevent entry into sewers, basements or confined areas. Personal Protection in Case of Full suit. Face shield. Boots. Full suit. Gloves (impervious). a Large Spill Section 7. Handling and Storage - - Precautions After handling, always wash hands thoroughly with soap and water. Avoid contact with skin and eyes. DO NOT ingest. Do not breathe gas, fumes, vapor or spray. Incompatibility alkalis metals Storage Corrosive materials should be stored in a separate safety storage cabinet or room. Keep out of reach of children. For Institutional and Commercial Use Section 8. Exposure Controls/Personal Protection Engineering Controls Good general.ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Long Pants and Long Sleeves to avoid skin cotact. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) ~ .. ^ Exposure Limits Hydrochloric Acid STEL: 5 Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid Odor Characteristic. Molecular Weight Not applicable. Taste Not available. pH 1 to 2 [Acidic.] Color Clear BoiGng/Condensation Point 100°C (212°F) Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1 (Water = 1) Vapor Pressure 20 mm of Hg (@ 20°C) Vapor Density > 1 (Air = 1) Volatility 90% (v/v). VOC 0 (g/I). Evaporation Rate <1 compared to Water Dispersion Properties Disperses Solubility Soluble in water The Product is: Non-flammable. Auto-ignition Temperature Not applicable. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits Not applicable. Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Not Applicable Section 10' Stability and Reactivity Data Stability Stable Incompatibility with Various alkalis metals Substances Hazardous Decomposition Ammonia; Chlorine Gas Products Section 11. Toxicological Information Routes of Entry Eye Contact Ingestion. INHALATION Skin contact. Toxicity to Animals Acute ora- toxicity (LD50): 5000 mg/kg [Rat]. (Propylene Glycol). Acute Effects on Humans Eyes Corrosive to eyes on contact. Skin Corrosive to skin and eyes on contact. Inhalarion Irritating to the mucous membranes of the nose, throat and lungs. Can be fatal if inhaled or ingested. Ingestion May cause burns to mouth, throat and stomach. Chronic Effects on Humans Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans r~l r. Section 12.'Ecological Information Ecotoxicity Not Available BODS and COD Not Available Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation as toxic as the original product. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal'Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 15 Other Regulatory Information and Pictograms WHMIS (Classification) VVHMIS CLASS E: Corrosive liquid. Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS CLASS: Corrosive liquid. USA Regulatory Lists DSD (EEC) International No products were found. Regulations Lists r~ f Hazardous Material 3 National Fire Information S stem _ .^ry. ~ '-- ~a11e1~itity Y 3~-~,~ ~ .~? , p Protection ~~. `U.S.A. ~.~~ .. . ` ) Physical Hazard ~ p Association (IJ.S.A.) nealth ~ ~ , ~ ~' Instability The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE ~ Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 16. Other Information Validated by CRushton on 4/29/2003. Verified by CRushton. Printed 7/28/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitbbility of any material is the sole responsibility of the user. A[[ materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exis4 validated on 4/29/2003. Fiber Pro Red and Brown Out Page: 5/5 Continued ort Next Page c.C ~6/N A~1 S D3-1--07 /_D~ ~„~ -~~ Clsrc # 060138 ~~~-- ~ ' ~~~~~ ~ `~ ~~ Material Safety Data Sheet WHMIS icto rams WI-IlVIIS WHMIS CLASS E: Corrosive liquid. of ° - Section 1. Chemical Product and Company Identification' Product Name/ Trade name Fiber Pro TLC Synonym Traffic Lane Cleaner/Prespray Chemical Family Not Applicable Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS HCS HCS CLASS: Corrosive liquid. Code 406 CAS # Mixture. Validation Date 4/29/2003 Print Date 7/28/2003 In case of Chemtrec (800) 424-9300 Emereencv Protective Clothing ~l0~~ Section 2. Composition and Information on_Ingredients Name CAS # % by Exposure Limits LCso/I,Dso Weight 1) Water 7732-18-5 0-100 Not available. Not available. 2) Sodium Orthosilicate 13472-30-5 0-5 Not available. Not available. 3) Sodium Silicate 1344-09-8 0-5 Not available. Not available. 4) Sodium Xylene Sulfonate 1300-72-7 0-5 Not available. Not available. 5) Sodium Tallate 61790-45-2 0-5 Not available. Not available. 6) 2-Butoxyethanol 111-76-2 0-5 TWA: 20 (ppm) from ORAL (LD50): Acute:- 1746 ACGIH (TLV) [United mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States] 7) Tetrasodium salt of 64-02-8 0-5 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg [Rat]. 8) Anionic Surfactant 25155-30-0 0-5 Not available. Not available. 9) Nonionic Surfactant 66455-15-0 0-5 Not available. Not available. 10) Nonionic Surfactant 61788-90-7 0-5 Not available. ORAL (LD50): Acute: 4610 mg/kg [Rat]. 11) Perfume Oil 100-52-7 0-5 Not available. Not available. Section 3. Hazards Identification - Potential Acute Health Effects Corrosive to eyes. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth: and respiratory tract. Potential Chronic Health Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin Effects irritation. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures' Eye Contact Flush eyes with a gentle stream of water holding eyelids open for at least 15 minutes. Seek medical attention. Skin Contact Wash gently and thoroughly the contaminated skin with running water and non abrasive soap. Seek medical attention. Inhalation Get to fresh air. Seek medical attention if irritation persists. Ingestion Do not induce vomiting. Drink large quantities of water. Seek medical attention immediately. Section 5. Fire Fighting Measures Products of Combustion Not Available Fire Fighting Media N/A and Instructions Special Remarks on Fire N/A Hazards Special Remarks on N/A Explosion Hazards Section 6. Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Call for assistance on disposal. Personal Protection in Case of Gloves (impervious). Splash goggles. Boots. ` Section 7. Handling and Storage. Precautions After handling, always wash hands thoroughly with soap and water. Avoid contact with skin and eyes. Incompatibility Strong acids. Storage Corrosive materials should be stored in a separate safety storage cabinet or room. Keep out of reach of children. For Institutional and Commercial Use Section 8. F~posure Controls/Persona! Protection Engineering Controls Good geheral ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Long Pants and Long Sleeves to avoid skin cotact. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) p Exposure Limits 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid Odor Pleasant. Molecular Weight Not applicable. Taste Not available. pH 12.5 to 13.5 [Basic.] Color Straw color. Boiling/Condensation Point 215°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.06 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 80 VOC Not available. Evaporation Rate (Water=1):<1 Dispersion Properties not available Solubility not available The Product is: Non-flammable. Auto-ignition Temperature N/A Rash Points None to boiling Flammable Limits Not Applicable Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Not Applicable 'Section 10. Stability and Reactivity Dafa Stability Stable Incompatibility with Various Strong acids. Substances Hazardous Decomposition Will not occur. Products Section 11.-,Toxicological Information Routes of Entry Eye Contact Ingestion. Skin contact. Toxicity to Animals Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute Effects on Humans Eyes Severe eye irritant. Liquid and mist may damage the eyes causing corneal injury. Skin Severe skin irritant. May cause moderate reddening, swelling, and possible skin damage. Inhalation Vapors may be irritating to mucous membranes in the nose, throat, and lungs. Ingestion Irritating to the mouth, throat, and gastrointestinal system. May cause headache, dizziness, nausea, vomiting, and diarrhea. Chronic Effects on Humans Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Ecological Information - Ecotoxicity Not available. BODS and COD Not Available Products of Biodegradation Not Available Toxicity of the Products of Biodegradation as toxic as the original product. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 95. Other Regulatory Information and Pictograms WHMIS (Classification) VVHMIS CLASS E: Corrosive liquid. Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS CLASS: Corrosive liquid. USA Regulatory Lists SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, de-ayed health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) International No products were found. Regulations Lists Hazardous Material * 3 National Fire Flammability Information System _ ~ Protection w;rr rtF "1;;-; , (U.S.A.) I bilit t i i ~/ ns y a on (U.S.A.) Health Assoc at 3 O h .P ysical Hazard ~ The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE ~~ Specific Hazazd MSDS must be consuRed to determine any specific hazards, First Aid measures, and PPE associated with this product Section 16. Other Information Validated by CRushton on 4/29/2003. Verified by CRushton. Printed 7/28/2003. Information Contact Betco Corporation _ 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy nr completeness of the injnrmatinn contained herein. Final determination ojsuitabi[tty of any material is the sole responsibility ojthe user. All materials may present unknown hazards and should be used with caulion. Although certain hazards are described herein, we cannot guarantee that these are [he only hazards that exist. Validated on 4/29/2003. F/b@r PCO TLC Page: 5/5 Continueal on Next Page ~~cVCI~ 1_I ~'v~ SC.E ~3~~1 3 oq/A_~ .: ~~~ l~O G~ ~Clsrc # 140132 ~'~- ~ Material Safety Data Sheet WHMIS icto rams WHNIIS Classification HCS E D-1B HCS CLASS: Corrosive liquid. ® ~„° v, Section 1. Chemical Product and Company Identification Product Name/ Trade ~(_~t PLUS name Synonym Very Aggressive No-Rinse Stripper Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS Code 154 CAS # Not applicable. Validation Date 7/30/2003 Print Date 8/13/2003 In Case of Chemtrec (800) 424-9300 Emereencv Protective Clothing ®~ ~ -_.. Section 2. Composition and Information on''ingredients; Name CAS # % by Exposure Limits LCsdLDsn Weight 1) Water 7732-18-5 >52 Not available. Not available. 2) 2-Butoxyethanol 111-76-2 <21 TWA: 20 (ppm) from ORAL (LD50): Acute: 1746 ACGIH (TLV) [United mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States] 3) Potassium Hydroxide 1310-58-3 <10 Not available. Not available. 4) Sodium Xylene Sulfonate 1300-72-7 <7 Not available. Not available. 5) Monoethanolamine 141-43-5 <5 TWA: 3 (ppm) Not available. TWA: 6 (ppm) from OSHA (PEL) [United States] STEL:6 (ppm) 6) Tetrapotassium Pyrophosphate 7320-34-5 <1 Not available. Not available. 7) Anionic Surfactant . 68130-47-2 <1 Not available. ORAL (LD50): Acute: 3950 mg/kg [Rat]. 8) Tetrasodium salt of 64-02-8 <1 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg [Rat]. 9) Triethanolamine 102-71-6 <1 Not available. ORAL (LD50): Acute: 4000 mg/kg [Rat]. 10) Perfume Oil N/A <1 Not available. Not available. Section 3. Hazards, ldentificafion Potential Acute Health Effects Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Potential Chronic Health May aggravate existing respiratory conditions such as asthma. Severe over exposure may cause Effects nervous system damage and kidney damage. Repeated or prolonged exposure to the substance may produce liver damage, blood disorders. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact Avoid contact with eyes Call a poison control center or doctor immediately for treatment advice. Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Skin Contact Rinse skin immediately with plenty of water for 15 to 20 minutes. Inhalation Move person to fresh air. 1f person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person `Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions Non-flammable substance. Special Remarks on Fire Hazards No additional remark. Special Remarks on Explosion Hazards No additional remark. Section 6. Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Corrosive liquid. Do not touch damaged container or spilled material. Isolate the area, do not attempt to clean-up spill, notify your manager for additional instructions. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7 .Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Do not breathe gas/fumes/ vapor/spray. Do not ingest. Good general ventilation should be sufficient to control airborne levels. Incompatibility acids ,oxidizing materials, metals Storage Corrosive materials should be stored in a separate safety storage cabinet or room. Handle and open container with care Keep out of the reach of children. Not for use or storage in or around the home. Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. . Body Wear overalls or long sleeved shirt and long trousers, nitrite rubber or neoprene gloves, rubber boots. Respiratory Wear appropriate respirator when ventilation is inadequate. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Hands Gloves (impervious). Protective Clothing (Pictograms) p __ o Limits 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Moncethanolamine TWA:3 (ppm) TWA: 6 (ppm) from OSHA (PEL) STEL:6 (ppm) Consult local authorities for acceptable exposure limits. `'-Section 9. Physical antl`'Chemical Properties Physical State and Appearance Liquid. (Liquid.) Odor Characteristic. Molecular Weight Not applicable. Taste Not available. pH 13.5 to 14 [Basic.] Color Colorless. Boiling/Condensation Point 214°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.04 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 90 VOC Not available. Evaporation Rate <1 compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points Not available. Flammable Limits Not available. Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Section 1 D. Stability and Reactivity Data Stability The product is stable. Incompatibility with Various acids ,oxidizing materials, metals Substances Hazardous Decomposition WIII not occur. Products Section 11. Toxicological Information Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). Acute Effects on Humans Eyes Corrosive to eyes on contact. Eye contact can result in corneal damage or blindness. Skin Corrosive to skin and eyes on contact. Tissue Destruction Possible. Skin contact may produce burns. Inhalation The product is a severe irritant for lungs and respiratory tract. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Ingestion Harmful if swallowed. Burns to mouth, throat and stomach. May be fatal if swallowed. Chronic Effects on Humans May aggravate existing respiratory conditions such as asthma. Severe over exposure may cause nervous system damage and kidney damage. Repeated or prolonged exposure to the substance may produce liver damage, blood disorders. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Eco%gcal Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation. products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal Considerations Waste Information Any method in accordance with applicable laws. Waste Stream Not available. ,: x .. Section 15. Other Regulatory Information and Pictograms WHMIS (Classification) E D-tB ®® Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS CLASS: Corrosive liquid. USA Regulatory Lists SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard; Potassium Hydroxide: immediate health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) R35-Causes severe burns. International No products were found. Regulations Lists Hazardous Material * 3 National Fire Information System '; 0 Protection ~ Flammabrhry (U S A ) . . . Association (iJ.S.A.) He~ltn < ~ O> tnstabiliry Physical Hazard ~ Q The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE ~~ Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 16. Other Information Validated by CRushton on 7/30/2003. Verified by CRushton. .Printed 8/13/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 S Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness ojthe information contained herein. - Fina/ determination of suitability of any material is the sole responsibility of the user. AU materials may present unknown hazards and should 6e used with caution. Ahhough certain hazards are described herein, we cannotguarnntee that these are the only hazards that exist Validated on 7/30/2003. AX-/t PIUS Page: 6/6 Continued on Next Page -' ~~. vc q.~i o n/ f}1 scE /~ Co3_/o_9_/_,~ ~ 3 ~ (~, Clsrc # 430 p ~'~~ Material Safety Data Sheet ,oa I WHMIS CLASS E: Corrosive liquid. Section 1. Chemical Product and Company Identification Product Name! Trade Ultra 2000 name Synonym Super.Double Strength Degreaser Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Oh 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS HCS .HCS CLASS: Corrosive liquid. Code 136 CAS # Not applicable. Validation Date 8/11/2003 Print Date 8/13/2003 In Case of Chemtrec (800) 424-9300 Emereencv Protective Clothing ®~~ Section 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCsdLDso Weight 1) Water 7732-18-5 60-70 Not available. Not available. 2) 2-Butoxyethanol 111.-76-2 5-10 TWA: 20 (ppm) from ORAL (LD50): Acute: 1746 ACGIH (TLV) [United mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States] 3) Potassium Metasilicate 1312-76-1 5-10 Not available. Not available. 4) Sodium Xylene Sulfonate 1300-72-7 5-10 Not available. ORAL (LD50): Acute: 650 mg/kg [Rat]. 5939 mg/kg [Mouse]. 5) Tetrasodium salt of 64-02-8 <2 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg [Rat]. 6) Sodium Orthosilicate 13472-30-5 0-5 Not available. Not available. 7) Potassium Hydroxide 1310-58-3 0-5 Not available. Not available. 8) Anionic Surfactant 25155-30-0 0-5 Not available. Not available. 9) Nonionic Surfactant 9016-45-9 <2 Not available. Not available. 10) Perfume Oil 100-52-7 <1 Not available. Not available. 11) Dye N/A <1 Not available. Not available. Section'3. Hazards Identificatior- Potential Acute Health Effects Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Potential Chronic Health Repeated or prolonged exposure to the substance can produce blood disorders. Repeated or Effects prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. Y - Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor immediately for treatment advice. Skin Contact Rinse skin with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for further treatment advice. ' Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5. Fire. Fighting `Measures Products of Combustion Not available. Fire Fighting Media and Instructions Non-flammable substance. Special Remarks on Fire Hazards No additional remark. Special Remarks on Explosion Hazards No additional remark. Section 6 Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Avoid contact with skin and eyes. Incompatibility Strong acids. acids Storage Corrosive materials should be stored in a separate safety storage cabinet or room. Keep out of reach of children. For Institutional and Commercial Use ' Section 8. Exposure Controls/Personal Protection I Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Long Pants and Long Sleeves to avoid skin cotact. No additional special protective clothing is required. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) ~ .. Exposure Limits 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Characteristic. Molecular weight Not applicable. Taste Not available. pH 12.5 to 13.5 [Basic.] Color Green. Boiling/Condensation Point 215°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.08 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 80 VOC Not available. Evaporation Rate <1 compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits .Not available. Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Presence of Various Substances .Not applicable Section 10: Stability and'Reactivity Data. Stability The product is stable. Incompatibility with Various Strong acids. acids Substances Hazardous Decomposition NOt available. Products Section 11. Toxicological Information Routes of Entry Eye Contact Ingestion. INHALATION Skin contact. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). Acute Effects on Humans Eyes Corrosive to skin and eyes on contact. Eye contact can result in corneal damage . Skin Skin contact may produce burns. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Inhalation Harmful if inhaled. Ingestion Irritating to mouth, throat and stomach. May cause headache, dizziness, nausea, vomiting and diarrhea. ' Chronic Effects on Humans Repeated or prolonged exposure to the substance can produce blood disorders. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 72. Ecological Information Ecotoxicity Not available. BODS and COD Not available. Products ofBiodegradadon Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 73. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. ~~ Transportation Not available. Special Provisions for Not available. Transport Section 15. Other Regulatory Information and Pictograms WHNIIS (Classification) WHMIS CLASS E: Corrosive liquid. Regulatory Lists SARA 313; 2-Butoxyethanol Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) .HCS CLASS: Corrosive liquid. USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm Galifornia prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide <1 ppm Massachusetts RTK: Ethylene Oxide SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard; Potassium Hydroxide: immediate health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) R35-Causes severe burns. International No products were found. Regulations Lists Hazardous Material Information System * 3 National Fire Flammability % " Protection ~~'' ~ ~_~ ~ 0 ~ (U.S.A.) ~> Instability t 0 Association (iJ.S.A.) Health `~ ~ Ph " ard i l H / y s ca az ~ Specific Hazazd The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE MSDS must be consulted to determine any speck hazards, First Aid measures, and PPE associated with this product Section 16. Other Information Validated by CRushton on 8/11/2003. Verified by CRushton. Printed 8/13/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best oJour knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever /or the accuracy or completeness oJthe information contained herein. Final determination of suitability of any material is the sole responsibility of the user. Alt materials may present unknown hazards and should be used with caution. Ahhough certain hazards are described herein, we cannot guarantee that these are the only hazards [hat exist -, Validated on 8/11/2003. UltCa 2000 Page: 6!6 Continued on Next Page ,~, t C~~-r_t oN_~ A-~sc~ 8 C~3/o9~u`f-~ Clscc-#1401-29 ~~ f ~= Material Safety Data Sheet WHMIS icto ams WHMIS E D-1B Y Section 7. Chemical Product and Company Identification Product Name/ Trade name ~(_~t PLUS Synonym Very Aggressive No-Rinse Stripper Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from GsHug. DSL DSL : AU components listed unless noted elsewhere on this MSDS HCS HCS CLASS: Corrosive liquid. Code 154 CAS # Not applicable. Validation Date 7/30/2003 Print Date 8/13/2003 to case or Chemtrec (800) 424-9300 Emereencv Protective Clothing ~~~ Section 2. Composition and lnformation'on'ingredients Name CAS # % by Exposure Limits LCsdl.Dso Weight 1) Water 7732-18-5 >52 Not available. Not available. 2) 2-Butoxyethanol 111-76-2 <21 TWA: 20 (ppm) from ORAL (LD50): Acute: 1746 ACGIH (TLV) [United mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States] 3) Potassium Hydroxide 1310-58-3 <10 Not available. Not available. 4) Sodium Xylene Sulfonate 1300-72-7 <7 Not available. Not available. 5) Monoethanolamine 141-43-5 <5 TWA: 3 (ppm) Not available. TWA: 6 (ppm) from OSHA (PEL) [United States] STEL:6 (ppm) 6) Tetrapotassium Pyrophosphate 7320-34-5 <1 Not available. Not available. 7) Anionic Surfactant 68130-47-2 <1 Not available. ORAL (LD50): Acute: 3950 mg/kg [Rat]. 8) Tetrasodium salt of 64-02-8 <1 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg [Rat]. 9) Triethanolamine 102-71-6 <1 Not available. ORAL (LD50): Acute: 4000 mg/kg [Rat]. 10) Perfume Oil N/A <1 Not available. Not available. Section 3- Hazards Identi>rcation Potential Acute Health Effects Corrosive to skin and eyes on contact. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, ~ or shortness of breath. Potential Chronic Health May aggravate existing respiratory conditions such as asthma. Severe over exposure may cause Effects nervous system damage and kidney damage. Repeated or prolonged exposure to the substance may produce liver damage, blood disorders. ;. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4._First,Aid,Measures Eye Contact Avoid contact with eyes Call a poison control center or doctor immediately for treatment advice. Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Skin Contact Rinse skin immediately with plenty of water for 15 to 20 minutes. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions Non-flammable substance. Special Remarks on Fire Hazards No additional remark. Special Remarks on Explosion Hazards No additional remark. Section 6. Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Corrosive liquid. Do not touch damaged container or spilled material. Isolate the area, do not attempt to clean-up spill, notify your manager for additional instructions. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Do not breathe gas/fumes/ vapor/spray. Do not ingest. Good general ventilation should be sufficient to control airborne levels. Incompatibility acids ,oxidizing materials, metals Storage Corrosive materials should be stored in a separate safety storage cabinet or room. Handle and open container with care Keep out of the reach of children. Not for use or storage in or around the home. ' Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Wear overalls or long sleeved shirt and long trousers, nitrite rubber or neoprene gloves, rubber boots. Respiratory Wear appropriate respirator when ventilation is inadequate. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Hands Gloves (impervious). Protective Clothing (Pictograms) ~ Exposure Limits 2-Butoxyethanol TWA: 25 (ppm) ' TWA: 50 (ppm) from OSHA (PEL) Moncethanolamine TWA:3 (ppm) TWA: 6 (ppm) from OSHA (PEL) STEL:6 (ppm) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. (Liquid.) Odor Characteristic. Molecular Weight Not applicable. Taste Not available. pH 13.5 to 14 [Basic.] Color Colorless. Boiling/Condensation Point 214°F initial Melting/Freeziag Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.04 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 90 VOC Not available. Evaporation Rate <1 compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points Not available. Flammable Limits Not available. Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Section 1 D. Stability and Reactivity Data Stability The product is stable. Incompatibility with Various acids ,oxidizing materials, metals Substances Hazardous Decomposition Will not occur. Products Section 19, Toxicological Information Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). Acute Effects on Humans Eyes Corrosive to eyes on contact. Eye contact can result in corneal damage or blindness. Skin Corrosive to skin and eyes on contact. Tissue Destruction Possible. Skin contact may produce burns. Inha[arion The product is a severe irritant for lungs and respiratory tract. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Ingestion Harmful if swallowed. Burns to mouth, throat and stomach. May be fatal if swallowed. Chronic Effects on Humans May aggravate existing respiratory conditions such as asthma. Severe over exposure may cause nervous system damage and kidney damage. Repeated or prolonged exposure to the substance may produce liver damage, blood disorders. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Ecological Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal 'Considerations Waste Information Any method in accordance with applicable laws. Waste Stream Not available. Section 75. Other Regulatory Information' and Pictograms WHNIIS (Classification) E D-18 O :t g. Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS CLASS: Corrosive liquid. USA Regulatory Lists SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard; Potassium Hydroxide: immediate health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) R35-Causes severe burns. International No products were found. Regulations Lists Hazardous Material * 3 National Fire Information S stem Y Flammability ~ p Protection ~ ~ (U.S.A.) ~~kT Association (U.S.A.) Health ~~ ~ O Instability Physical Hazard ~ The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to dete rmine any specific hazards, First Aid measures, and PPE associated with this product. Section '16. 'Other Information Validated by CRushton on 7130/2003. Verified by CRushton. Printed 8/13/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the injormation contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any Uability whatsoever jor the accuracy or completeness of the information contained herein. Final determination ojsuitability of any material is the sole responsibility of the user. AU materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist AX-It Plus Page: 6/6 Validated on 7/3012003. Continuetl on Next?Page L_ _O_~A~1 ON-~ a~ 1 22_B ~lsc.C-.f~rn1 :~ ~ 4 ~ ~s `~ Material Safety Data Sheet This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 WHMIS Class D-2B: Material causing other toxic effects HCS Class: Irritating substance. O (TOXIC). WHMIS (Pictograms) WHMIS (Classification) HCS Section 1. Chemical Product and Company Identification Product Name/ FOr@St 5 Trade name Synonym Cleaner/Degreaser/Deodorant Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier getco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing DSL/ NDSL All components listed unless noted elsewhere on this MSDS Code 307 CAS # Not applicable. Validation Date 3/2/2007 Print Date 3/24/2007 In case of Chemtrec (800) 424-9300 Emereency Protective Clothing ~~ Section 2. Composition and Information on ngredients Name CAS # % by Exposure Limits LCsdLDso Weight Tetrasodium salt of 64-02-8 0-5 Not available. ORAL (LD50): Acute: ethylendiaminetetraacetic acid 3030 mg/kg [Rat]. 2-Butoxyethanol 111-76-2 1-5 TWA: 20 (ppm) from ORAL (LD50): Acute: ACGIH (TLV) [United 1746 mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States] Alkyl (C12 68%, C14 32%) dimethyl 68956-79-6 0.105 Not available. Not available. ethylbenzyl ammonium chloride Alkyl (C14 60%, C16 30%, C12 5%, 68391-01-5 0.105 Not available. Not available. C18 5%) dimethyl benzyl ammonium chloride Section 3. Hazards Identification - Potential Acute Health This product may irritate eyes upon contact. Irritating to the mucous membranes of the nose, Effects thorat and lungs. Potential Chronic Health Repeated skin exposure can produce local skin destruction, or dermatitis. Effects Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. i Section 4.-First Aitl `Measures Eye Contact Call a poison control center or doctor immediately for treatment advice. Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Skin Contact Rinse skin with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for further treatment advice. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions N/A Special Remarks on Fire Hazards N/A Special Remarks on Explosion Hazards N/A Section 6. Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be Case of a Large Spill sufficient; consult a specialist BEFORE handling this product. Section;7._Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Avoid contact with skin and eyes. Incompatibility None known. Storage Keep out of reach of children. For Institutional and Commercial Use Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Long Pants and Long Sleeves to avoid skin cotact. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) Limits 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Consult local authorities for acceptable exposure limits. Section. 9. Physical and Chemical Properties Physical State and Appearance Liquid.. Odor Pleasant. Molecular Weight Not applicable. Taste Not available. pH 11.5 to 12.5 [Basic.] Color Straw color. Boiling/Condensation Point 213°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.01 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 90 VOC Not available. Evaporation Rate <1 compared to Water Dispersion Propertie's See solubility in water. Solubility Easily soluble in cold water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits Not available. Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Presence of Various Substances Not applicable Section 74. Sfability and Reactivity Data Stability The product is stable. Incompatibility with None known. Various Substances Hazardous Decomposition Will not occur. Products Section 1 ~. Toxicological Information Routes of Entry Eye Contact Ingestion. INHALATION Skin contact. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). Acute Effects on Humans Eyes Severe eye irritant. Liquid and mist may cause corneal injury. Skin Skin irritant. Prolonged or repeated exposure may cause moderate reddening or swelling. Inhalation Vapors may be irritating to mucous membranes of the nose, throat, and lungs. Ingestion May be irritating to the mouth, throat, esophagus, and gastrointestinal system. Vomiting and diarrhea expected with large doses. Chronic Effects on Repeated skin exposure can produce local skin destruction, or dermatitis. Humans Special Remarks on No additional remark. Toxicity to Animals Special Remarks on No additional remark. Chronic Effects on Humans Section 12 ,Ecolo ical Information Ecotoxicity Not Available BODS and COD Not available. Products of Possibly hazardous short term degradation products are not likely. However, long term Biodegradation degradation products may arise. Toxicity of the Products of Not available. Biodegradation Special Remarks on the No additional remark. Products of Biodegradation Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. 'Section 14. Transport Information DOT (U.S.A) (Pictograms) TDG Classification Not controlled under TDG (Canada). UN, Proper Shipping Not applicable. e, PG i _ ~• Transportation Not available. Special Provisions for Not applicable. Transport Section` 15. Other Regulatory Information and Pictograms WHMIS (Classification) WHMIS Class D-26: Material causing other toxic effects (TOXIC). O T Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS Class: Irritating substance. USA Regulatory Lists SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) International No products were found. Regulations Lists Hazardous Material Information System 2 National Fire Flammability r ~ ` ~ p Protection ~ ~~~ (U.S.A.) ld '~~ Health 2 O Instability ..Physical Hazara , p Association (U.S.A.) The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 16._Other Information Validated by CRushton on 3/2/2007. Verified by CRushton. Printed 3/24/2007. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Readei To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Validated on 3/2/2007. Forest 5 Pa e: 5/6 ~. [Clsrc # 227080 3M MATERIAL SAFETY DATA SHEET 3MT"*DEODORIZER -FRESH SCENT -CONCENTRATE (Product No. 13, Twist'n Fi11T"'S stem 08/12/2002 ,~_..,T_ ~.~~ W Material Safety Data Sheet _ ~oN 1 Sc.E- Pj//V i~ /~~ Copyright, 2002, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECT[ON I: PRODUCT AND COIVIPANYIDENTIFICATION PRODUCT NAME: 3MT'"DEODORIZER -FRESH SCENT -CONCENTRATE (Product No. 13, Twist'n Fi11T'"System) MANUFACTURER: 3M DIVISION: Commercial Care Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 08/12/2002 Supercedes Date: 07/28/2002 Document Group: 06-8475-3 Product Use: Specific Use: DEODORIZER SEC"i'ION 2: INGREDIENT'S InLredient POLYALKOXY ALCOHOLS FRAGRANCE 5413 (NTTSN 04499600-6517) WATER SORBITAN POLYETHOXY MONOLAURATE C.I. ACID BLUE 3 C.A.S. No. % by Wt 69013-18-9 30- 60 Trade Secret 10 - 30 7732-18-5 10- 30 9005-64-5 10- 30 3536-49-0 < 0.] -- 1 SECTION'S: HAZARDS IDENTIFICATI01 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear; dark blue color; strong fragrance General Physical Form: Liquid Immediate health, physical, and environmental hazards: 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: lof5 3M MATERIAL SAFETY DATA SHEET 3MT"iDEODORIZER -FRESH SCENT -CONCENTRATE (Product No. 13, Twist'n Fi11T"'S stem 08/12/2002 Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May Cause Allergic Skin Reaction: Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Single exposure may cause: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. 'SECTION 4: FIRST AID MEASURES _- -~ _~ 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. If signs/symptoms develop, get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. SECTION S: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=212 °F (Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available OSHA Flammability Classification: Class IIIB Combustible Liquid 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. -- SECTION 6: ACCIDENTAL RELEASE 1lIE ASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Ventilate the azea with fresh air. Contain spill. Working from azound the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient 2 of 5 3M MATERIAL SAFETY DATA SHEET 3MTMDEODORIZER -FRESH SCENT -CONCENTRATE (Product No. 13, Twist'n Fil1TMS stem 08/12/2002 absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND `STOR~GL 7.1 HANDLING This product is not intended to be used without prior dilution as specified on the product label. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contact with oxidizing agents. Keep out of the reach of children. 7.2 STORAGE Store away from oxidizing agents. Keep container in well-ventilated area. SECTION 8: EXPOSURh: CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS NOTE: When used as directed and diluted and dispensed with a TWIST'n FILLTMChemical Dispenser, special ventilation is not required. Use in awell-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FII.LTMChemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FILLTMChemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. 8.2.3 Respiratory Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FILLTMChemical Dispenser, respiratory protection is not required. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of vapors, mists or spray. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES None Established SECTION_9: PHYSICAL AND CHEMICAL PROPERTIES ~~~ Specific Physical Form: Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point Density Liquid Clear; dark blue color; strong fragrance Liquid No Data Available >=212 °F [Test Method: Tagliabue Closed Cup] No Data Available No Data Available Approximately 212 °F No Data Available 3 of 5 z 3M MATERIAL SAFETY DATA SHEET 3MT"rDEODORIZER -FRESH SCENT -CONCENTRATE (Product No. 13, Twist'n Fi11TMS stem 08/12/2002 Vapor Density Vapor Pressure Specific Gravity pH Melting point Solubility in Water Evaporation rate Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Viscosity No Data Available No Data Available Approximately 1 [RejStd: WATER=1] Approximately 7.4 Not Applicable Complete No Data Available 10 - 30 % [Test Method.• calculated per CARB title-2] 20-60% 10 - 30 % [Test Method: calculated per CARB title 2] <=100 centipoise i SUCTION 10: STABILITY AND REACTI.~'1TI' Stability: Stable. Materials and Conditions to Avoid: Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Condition During Combustion During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its com onents. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not Determined CHEMICAL FATE INFORMATION Not Determined SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since re ulations var consult a licable re ulations or authorities before dis osal. SECTION 14:TRANSPORT INFORMATION H) Number UPC ID Number UPC 70-0708-4013-0 00-48011-20121-9 70-0709-9001-8 4of5 =. -. 3M MATERIAL SAFETY DATA SHEET 3MTMDEODORIZER -FRESH SCENT -CONCENTRATE (Product No. 13, Twist'n Fi11T"'S stem 08/12/2002 70-0710-0973-5 00-48011-23896-3 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SEC."TION 15: RF.CULATORY INFORMATION ~ US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard =Yes Delayed Hazard - No CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. This MSDS has been re ared to meet the U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200. __ _ -- - - - SCCTION16: OTHERINFORNI~~TION ~; NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association Hazard Codes are designed for use by firefighters, sheriffs, or other emergency response teams who are concerned with the hazards of burning or exploding materials. These NFPA codes are not intended to address the hazards of this product other than in afire situation. HMIS Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Protection: X -See PPE section. HMIS codes are intended for use in everyday workplace settings to provide a rapid indication of the occupational hazards associated with chemicals used in the workplace. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IIvIPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com SofS Glsrc-# 22.7.01.5 MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2002, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. C3.OC.A_T_L0/V D_r~/o_~ /B3~ ~a ~~r~s DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand HEAVY DUTY MULTI-SURFACE CLEANER CONCENTRATE (Product No. 2, Twist 'n Fill (tm) System) ID NUMBER/U.P.C.: 70-0705-4313-0 00-48011-19202-9 70-0707-1407-9 00-48011-20795-2 70-0708-3990-0 00-48011-19202-9 70-0710-0959-4 00-48011-23901-4 ISSUED: January 07, 2002 SUPERSEDES: December 06, 2001 DOCUMENT: 06-1681-3 ----------------------------------------- 1. INGREDIENT ----------------------------------------- ------------- C.A.S. NO. ------------- ------ ------ ----------------- PERCENT ----------------- 1-METHOXY-2-PROPANOL .................... 107-98-2 40 - 70 WATER ................................... 7732-18-5 10 - 30 ETHANOLAMINE ............................ 141-43-5 10 - 30 HYDROXYALKYL AMINE OXIDES ............... 68478-65-9 7 - 13 ISOPROPYL ALCOHOL ....................... 67-63-0 1 - 5 DODECYLBENZENESULFONIC ACID ............. 27176-87-0 1 - 5 2-ETHYL-HEXYLOXYETHANOL ................. 1559-35-9 1 - 5 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-TO-Know Act of 1986 and 40 CFR Part 372: 2-ETHYL-HEXYLOXYETHANOL ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT :................. N/D VAPOR PRESSURE :................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY.IN WATER:........... complete SPECIFIC GRAVITY :.............. ca. 0.978 Water=l PERCENT VOLATILE :.............. ca. 95 °s Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HEAVY DUTY MULTI-SURFACE CLEANER CONCENTRATE (Product No. 2, Twist 'n Fill (tm) System) January 07, 2002 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- pH :............................ ca. 11.9 VISCOSITY :..................... ca. 10 centipoise MELTING POINT :................. N/A APPEARANCE AND ODOR: Liquid, colorless to light amber color, fresh scent ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT :................... ca. 105 F TCC FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam, Alcohol-type foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 2 FIRE: 2 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none OSHA FIRE HAZARD CLASS: Class II Combustible Liquid ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Oxidizing Agents. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. ----------------------------------------------------------------------------- Abbreviations; N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HEAVY DUTY MULTI-SURFACE CLEANER CONCENTRATE (Product No. 2, Twist 'n Fill (tm) System) January 07, 2002 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Irritant Vapors or Gases. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with absorbent material. Dilute in a large excess of water. Carefully, and with stirring, add appropriate dilute acid such as sulfamic acid or vinegar. Confirm neutrality. Collect using non-sparking tools. Clean up residue with water. Place in a polyethylene-lined metal container. Do not seal for 48 hours. RECOMMENDED DISPOSAL: Dispose of waste product in a hazardous waste facility. Disposal alternative: Incinerate in a permitted hazardous waste incinerator. ENVIRONMENTAL DATA: A Product Environmental Data Sheet (PED) is available. The use of this product is expected to have no significant environmental impact. All components will eventually degrade in the environment. REGULATORY INFORMATION: Volatile Organic Compounds: ca. 55 0. VOC Less H2O & Exempt Solvents: ca. 55 °s. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) TSCA: All chemicals used in the manufacture of this material are in compliance with the US TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HEAVY DUTY MULTI-SURFACE CLEANER CONCENTRATE (Product No. 2, Twist 'n Fill (tm) System) January 07, 2002 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Immediately flush skin with large amounts of water for at least 15 minutes in a chemical safety shower while removing contaminated clothing and shoes. Get immediate medical attention. Wash contaminated clothing before reuse. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION -------------------------=--------------------------------------------------- EYE PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Wear vented goggles. Wear full-face shield. SKIN PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber, neoprene, nitrile rubber. Use one or more of the following personal protection items as necessary to prevent skin contact: apron, coveralls. RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, special ventilation is not required. Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation at transfer points. If exhaust ventilation is not adequate, use appropriate respiratory protection. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HEAVY DUTY MULTI-SURFACE CLEANER CONCENTRATE (Product No. 2, Twist 'n Fill (tm) System) January 07, 2002 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and dispensed with a TwIST'n FILL (tm) Chemical Dispenser, respiratory protection is not required. Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: full-face organic vapor respirator. PREVENTION OF ACCIDENTAL INGESTION: Wash hands after handling and before eating. RECOMMENDED STORAGE: Store away from heat. Keep container in well-ventilated area. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: NOTE: when used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, container grounding and low static or grounded shoes are not required. Keep container tightly closed. Keep away from heat, sparks, open flame, and other sources of ignition. Prevent all sources of ignition. Ground containers securely when transferring contents. wear low static or properly grounded shoes. Combustible liquid and vapor. OTHER PRECAUTIONARY INFORMATION: NOTE: The above precautionary information presumes that this ready-to- use product has been diluted and dispensed from a TWIST'n FILL (tm) Chemical Dispenser. This product is not intended to be used without prior dilution as specified on the product label. HMIS HAZARD RATINGS: HEALTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7 EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* 1-METHOXY-2-PROPANOL ................. 100 PPM TWA ACGIH 1-METHOXY-2-PROPANOL ................. 150 PPM STEL ACGIH 1-METHOXY-2-PROPANOL ................. 100 PPM TWA OSHA 1-METHOXY-2-PROPANOL ................. 150 PPM STEL OSHA WATER ................................ NONE NONE NONE NONE ETHANOLAMINE ......................... 3 PPM TWA ACGIH ETHANOLAMINE ......................... 6 PPM STEL ACGIH ETHANOLAMINE ......................... 3 PPM TWA OSHA ETHANOLAMINE ......................... 6 PPM STEL OSHA ETHANOLAMINE ......................... 6 MG/M3 TWA OSHA HYDROXYALKYL AMINE OXIDES............ NONE NONE NONE NONE Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HEAVY DUTY MULTI-SURFACE CLEANER CONCENTRATE (Product No. 2, Twist 'n Fill (tm) System) January 07, 2002 PAGE 6 EXPOSURE LIMITS (continued) INGREDIENT VALUE UNIT TYPE AUTH SKIN* ------------ --------------------------------------------------------- ISOPROPYL ALCOHOL .................... 400 PPM -------- TWA ACGIH ISOPROPYL ALCOHOL .................... 500 PPM STEL ACGIH ISOPROPYL ALCOHOL .................... 400 PPM TWA OSHA ISOPROPYL ALCOHOL .................... 500 PPM STEL OSHA DODECYLBENZENESULFONIC ACID.......... NONE NONE NONE NONE 2-ETHYL-HEXYLOXYETHANOL .............. NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - OSHA: Occupational Safety and Health Administration NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA -------------------------------------------------=--------------------------- EYE CONTACT: Chemical Related Eye Burns (chemical corrosivity): signs/symptoms can include cloudy appearance of the cornea, chemical burns, pain, tearing, ulcers, impaired vision or loss of vision. SKIN CONTACT: Skin Burns (chemical corrosivity): signs/symptoms can include redness, swelling, itching, pain, blistering, ulceration, sloughing, and scar formation. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signsfsymptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended guidelines, may cause: Kidney Effects: signs/symptoms can include reduced urine volume, ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HEAVY DUTY MULTI-SURFACE CLEANER CONCENTRATE (Product No. 2, Twist 'n Fill (tm) System) January 07, 2002 PAGE 7 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- blood in urine and back pain. Liver Effects: signs/symptoms can include yellow skin (jaundice) and tenderness of upper abdomen. IF SWALLOWED: Ingestion is not a likely route of~exposure to this product. Ingestion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Aspiration Pneumonitis: signs/symptoms can include coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- INGREDIENTS SECTION CHANGED SINCE December 06, 2001 ISSUE ENVIRONMENTAL INFO. SECTION CHANGED SINCE December 06, 2001 ISSUE HEALTH HAZARD DATA SECTION CHANGED SINCE December 06, 2001 ISSUE Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit-for a particular purpose and suitable for user's method of use or application. Given. the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2001, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand NEUTRAL QUAT DISINFECTANT CLEANER CONCENTRATE ............. (Product No. 23, Twist ~n Fill (tm) System) ID NUMBER/U.P.C.: 70-0708-3105-5 00-48011-23552-8 70-0708-3143-6 00-48011-23583-2 70-0708-4022-1 00-48011-23552-8 70-0709-7764-3 00-48011-26056-8 70-0709-7765-0 00-48011-26057-5 70-0710-0728-3 00-48011-26056-8 70-0710-0729-1 00-48011-26057-5 70-0710-1485-9 00-48011-23890-1 ISSUED: April 09, 2001 SUPERSEDES: October 17, 2000 DOCUMENT: 08-5081-8 ~~ ~i~~~ ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- WATER ................................... DIDECYL DIMETHYL AMMONIUM CHLORIDE...... QUATERNARY AMMONIUM COMPOUNDS, ALKYLBENZYLDIMETHYL,CHLORIDES......... OCTYLDIMETHYLAMINE OXIDE ................ ETHYLENEDIAMINETETRAACETIC ACID......... ETHYL ALCOHOL ........................... SODIUM HYDROXIDE ........................ HYDROGEN PEROXIDE ....................... 7732-18-5 60 - 90 7173-51-5 9.22 8001-54-5 6.14 2605-78-9 1 - 5 60-00-4 1 - 5 64-17-5 1 - 5 1310-73-2 0.5 - 1.5 7722-84-1 < 0.02 ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT :................. ca. 212 F VAPOR PRESSURE :................ N/D VAPOR DENSITY:................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY: .............. ca. 1.0 Water=l PERCENT VOLATILE :.............. ca. 75 °s pH :............................ ca. 7.7 VISCOSITY :..................... < 100 centipoise MELTING POINT :................. N/A Clsrc_# 22.7_11-5 CLacA~T_7~ Ale ~~ C.~~ ~D5/o_ ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately s MSDS: 3M Brand NEUTRAL QUAT DISINFECTANT CLEANER CONCENTRATE .............. (Product No. 23, Twist 'n Fill (tm) System) April 09, 2001 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- APPEARANCE AND ODOR: Liquid, clear, dark green color, lemon odor. ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT :................... > 200 F TCC FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 3 FIRE: 1 REACTIVITY: 0 UNUSUAL REACTION HAZARD: corrosive 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: None known. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen Chloride. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand NEUTRAL QUAT DISINFECTANT CLEANER CONCENTRATE .............. (Product No. 23, Twist ~n Fill (tm) System) April 09, 2001 PAGE 3 ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with inorganic absorbent material. Collect spilled material. Clean up residue with water. Place in a closed container. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility in the presence of a combustible material. Combustion products will include HC1. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: 2 - 3 °s. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). TSCA: All components used in the manufacture of this material are in compliance with the US TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Immediately flush skin with large amounts of water. Remove contaminated clothing. If irritation persists,. call a physician. Wash contaminated clothing before reuse. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed, do NOT induce vomiting. Give victim two glasses of water. Call a physician immediately. Never give anything by mouth to an unconscious person. Note to physician: Probable mucosal damage may contraindicate the use ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand NEUTRAL QUAT DISINFECTANT CLEANER CONCENTRATE .............. (Product No. 23, Twist 'n Fill (tm) System) April 09, 2001 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- of gastric lavage. OTHER FIRST AID INFORMATION: Measures against circulatory shock, respiratory depression, and convulsion may be needed. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Wear vented goggles. Wear full-face shield. SKIN PROTECTION: NOTE: when used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber, neoprene, nitrile rubber. RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, special ventilation is not required. Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, respiratory protection is not required. Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contamination of food. RECOMMENDED STORAGE: Store away from areas where product may come into contact with food or pharmaceuticals. Do not store containers on their sides. Keep container closed when not in use. Keep out of the reach of children. Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand NEUTRAL QUAT DISINFECTANT CLEANER CONCENTRATE .............. (Product No. 23, Twist 'n Fill (tm) System) April 09, 2001 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. OTHER PRECAUTIONARY INFORMATION: Not intended for consumer sale or use. This product is not intended to be used without prior dilution as specified on the product label. Avoid creasing or impacting container side walls. HMIS HAZARD RATINGS: HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7 EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* ---------- --------------------------------------- WATER ................................ ------------------ NONE NONE -------- NONE -- NONE DIDECYL DIMETHYL AMMONIUM CHLORIDE... NONE NONE NONE NONE QUATERNARY AMMONIUM COMPOUNDS, ALKYLBENZYLDIMETHYL,CHLORIDES...... NONE NONE NONE NONE OCTYLDIMETHYLAMINE OXIDE ............. NONE NONE NONE NONE ETHYLENEDIAMINETETRAACETIC ACID...... NONE NONE NONE NONE ETHYL ALCOHOL ........................ 1000 PPM TWA ACGIH ETHYL ALCOHOL ........................ 1000 PPM TWA OSHA SODIUM HYDROXIDE ..................... 2 MG/M3 CEIL ACGIH SODIUM HYDROXIDE ..................... 2 MG/M3 CEIL OSHA SODIUM HYDROXIDE ..................... 2 MG/M3 TWA CMRG 15 MINUTES TWA HYDROGEN PEROXIDE .................... 1 PPM TWA ACGIH HYDROGEN PEROXIDE .................... 1 PPM TWA OSHA * SKIN NOTATION: Listed substances ind icated with 'Y' under SKIN refer to the potential contribution to the overa ll exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - CMRG: Chemical Manufacturer Recommen ded Exposure Guidelines - OSHA: Occupational Safety and Health Administration - NONE: None Established ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand NEUTRAL QUAT DISINFECTANT CLEANER CONCENTRATE .............. (Product No. 23, Twist 'n Fill (tm) System) April 09, 2001 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Chemical Related Eye Burns (chemical corrosivity): signs/symptoms can include cloudy appearance of the cornea, chemical burns, pain, tearing, ulcers, impaired vision or loss of vision. SKIN CONTACT: Severe Skin Irritation: signs/symptoms can include redness, swelling, itching, dryness, cracking, blistering, and pain. May be absorbed through the-skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Prolonged or repeated exposure may cause: Nervous System Effects: signs/symptoms can include emotional changes, lack of coordination, tremors and sensory loss. Lung Damage: signs/symptoms can include coughing, difficulty breathing, wheezing, tightness in chest, congestion, and coughing up of blood. IF SWALLOWED: Harmful or fatal if swallowed. Damage to Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, nausea, abdominal tenderness, burns of mouth, difficulty swallowing, blood in vomitus, blood in feces, and ulceration. CANCER: Note: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to.ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. OTHER HEALTH HAZARD INFORMATION: Note: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand NEUTRAL QUAT DISINFECTANT CLEANER CONCENTRATE .............. (Product No. 23, Twist 'n Fill (tm) System) April 09, 2001 PAGE 7 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: medical conditions, if any, known to be aggravated by exposure to this product are indicated in the appropriate portions of the Health Hazard Data section of this data sheet. CARCINOGENS: components of this product, if any, known to cause, or suspected of causing, cancer as determined by OHSA, IARC, OR NTP are described in the Health Hazard Data section of this data sheet in accord with the OHSA Hazard Communications Standard, 29 CFR 1910.1200 ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- PRECAUTIONARY INFO. SECTION CHANGED SINCE October 17, 2000 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly -from 3M. ~~ MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2001,.Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M BRAND FLOOR STRIPPER LO CONCENTRATE .............................. (Product No. 22, Twist 'n Fill (tm) System) ID NUMBER/U.P.C.: 70-0708-4021-3 00-48011-23555-9 70-0710-0980-0 00-48011-23889-5 ISSUED: February 12, 2001 SUPERSEDES: February 07, 2001 DOCUMENT: 11-9289-7 (~Cisrc # 227110 LaC1~T1~ ~ DI~G~S~ ~ ~~~~,5 ----------------------------------------- 1. INGREDIENT ----------------------------------------- ------------- C.A.S. NO. ------------- ------ ------ ----------------- PERCENT ----------------- BENZYL ALCOHOL .......................... 100-51-6 40 - 70 ETHANOLAMINE ............................ 141-43-5 30 - 60 POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER ................................. 60828-78-6 1 - 5 BENZENESULFONIC ACID DERIVATIVE......... 70191-75-2 1 - 5 ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT :................. > 300 F VAPOR PRESSURE :................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... apprec. SPECIFIC GRAVITY :.............. ca. 1.0 Water=l PERCENT VOLATILE :.............. ca. 95 °s pH :............................ ca. 11 (5o in water) VISCOSITY :..................... < 10 centipoise MELTING POINT :................. N/D APPEARANCE AND ODOR: Liquid, dark green. Chemical odor. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately q MSDS: 3M BRAND FLOOR STRIPPER LO CONCENTRATE .............................. (Product No. 22, Twist 'n Fill (tm) System) February 12, 2001 PAGE 2 ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT :................... > 200 F FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: Not determined. NFPA HAZARD CODES: HEALTH: 2 FIRE: 1 REACTIVITY: 0 UNUSUAL REACTION HAZARD: corrosive 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Acids, Strong Oxidizing Agents. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Oxides of Sulfur, Amine Compounds, Irritant Vapors or Gases. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with inorganic absorbent material. Collect spilled material. Clean up residue with an appropriate organic solvent. Read and follow safety precautions on the solvent label and MSDS. Place in a closed container. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND FLOOR STRIPPER LO CONCENTRATE .............................. (Product No. 22, Twist 'n Fill (tm) System) February 12, 2001 PAGE 3 ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION (continued) ----------------------------------------------------------------------------- RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility in the presence of a combustible material. Dispose of empty cans in a sanitary landfill. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: ca. 930.0 gms/liter calculated per GARB title 2 section 94507. VOC Less H2O & Exempt Solvents: ca. 937.0 gms/liter calculated per GARB title 2 section 94507. Since regulations vary, consult applicable regulations or authorities before disposal. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). TSCA: All components used in the manufacture of this material are in compliance with the U.S. TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Immediately flush skin with large amounts of water for at least 15 minutes in a chemical safety shower while removing contaminated clothing and shoes. Get immediate medical attention. Wash contaminated clothing before reuse. INHALATION: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is difficult, get immediate medical attention. IF SWALLOWED: If swallowed, do NOT induce vomiting. Give victim two glasses of water. Call a physician immediately. Never give anything by mouth to an unconscious person. Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately r, MSDS: 3M BRAND FLOOR STRIPPER LO CONCENTRATE .............................. (Product No. 22, Twist ~n Fill (tm) System) February 12, 2001 PAGE 4 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. Avoid eye contact with vapor, spray, or mist. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Wear unvented goggles during operations in which exposure is likely. Wear full-face shield. SKIN PROTECTION: NOTE: When used as directed and diluted and dispensed with a TwIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from. the following material(s) are recommended: butyl rubber, neoprene, nitrile rubber. RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and dispensed with a TWIST~n FILL (tm) Chemical Dispenser, special ventilation is not required. Do not use in a confined area or areas with little or no air movement. Use with appropriate local exhaust ventilation. Use in a well-ventilated area. Use with adequate dilution ventilation. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, respiratory protection is not required. Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. Select one of the .following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: full-face ammonia respirator, full- face methylamine respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. Do not ingest. RECOMMENDED STORAGE; Store away from areas where product may come into contact with food or pharmaceuticals. Store away from acids. Keep out of the reach of children, FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND FLOOR STRIPPER LO CONCENTRATE .............................. (Product No. 22, Twist 'n Fill (tm) System) February 12, 2001 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- OTHER PRECAUTIONARY INFORMATION: Not intended for consumer sale or use. This product is not intended to be used without prior dilution as specified on the product label. HMIS HAZARD RATINGS: HEALTH: 3 FLAMMABILITY: 1 REACTIVITY: 1 PERSONAL PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* - ----------------------------------------------------- BENZYL ALCOHOL ....................... 10 PPM ---------------------- - TWA AIHA ETHANOLAMINE ......................... 3 PPM TWA ACGIH ETHANOLAMINE ......................... 6 PPM STEL ACGIH ETHANOLAMINE .................:....... 3 PPM TWA OSHA ETHANOLAMINE ......................... 6 PPM STEL OSHA ETHANOLAMINE ......................... 6 MG/M3 TWA OSHA POLYETHYLENE GLYCOL TRIMETHYLNONYL ETHER .............................. NONE NONE NONE NONE BENZENESULFONIC ACID DERIVATIVE...... NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - AIHA: American Industrial Hygiene Assoc. Workplace Environmental Exposure Level Guideline - OSHA: Occupational Safety and Health Administration - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Chemical Related Eye Burns (chemical corrosivity): signs/symptoms can include cloudy appearance of the cornea, chemical burns, pain, tearing, ulcers, impaired vision or loss of vision. SKIN CONTACT: Skin Burns (chemical corrosivity): signs/symptoms can include redness, swelling, itching, pain, blistering, ulceration, sloughing, and scar formation. May be absorbed through the skin and produce effects similiar to ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND FLOOR STRIPPER LO CONCENTRATE .............................. (Product No. 22, Twist 'n Fill (tm) System) February 12, 2001 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. WHILE THE FOLLOWING EFFECTS ARE ASSOCIATED WITH ONE OR MORE OF THE INDIVIDUAL INGREDIENTS IN THIS PRODUCT AND ARE REQUIRED TO BE INCLUDED ON THE MSDS BY THE U.S. OSHA HAZARD COMMUNICATION STANDARD, THEY ARE NOT EXPECTED EFFECTS DURING FORESEEABLE USE OF THIS PRODUCT. Prolonged or repeated overexposure, above recommended guidelines, may cause: Kidney Effects: signs/symptoms can include reduced urine volume, blood in urine and back pain. Liver Effects: signs/symptoms can include yellow skin (jaundice) and tenderness of upper abdomen. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. Damage to Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, nausea, abdominal tenderness, burns of mouth, difficulty swallowing, blood in vomitus, blood in feces, and ulceration. Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, muscular weakness, incoordination, slowed reaction time, fatigue, blurred vision, slurred speech, giddiness, tremors and convulsions. OTHER HEALTH HAZARD INFORMATION: MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: medical conditions, if any, known to be aggravated by exposure to this product are indicated in the appropriate portions of the Health Hazard Data section of this data sheet. CARCINOGENS: components of this product, if any, known to cause, or suspected of causing, cancer as determined by OHSA, IARC, or NTP are described in the Health Hazard Data section of this data sheet in accord with the OHSA Hazard Communications Standard, 29 CFR 1910.1200 ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND FLOOR STRIPPER LO CONCENTRATE .............................. (Product No. 22, Twist 'n Fill (tm) System) February 12, 2001 PAGE 7 ----------------------------------------------------------------------------- 5ECTION CHANGE DATES ----------------------------------------------------------------------------- INGREDIENTS SECTION CHANGED SINCE February 07, 2001 ISSUE PRECAUTIONARY INFO. SECTION CHANGED SINCE February 07, 2001 ISSUE ---------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED T0, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 'f MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 1998, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. ID NUMBER/U.P.C.: DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M BRAND STELLAR(TM) UHS FLOOR FINISH 70-0708-3131-1 00-48011-23562-7 70-0708-3132-9 00-48011-23563-4 70-0708-3137-8 00-48011-23577-1 ISSUED: October 13, 1998 SUPERSEDES: May 07, 1998 DOCUMENT: 08-4512-3 ----------------------------------------- 1. INGREDIENT ----------------------------------------- ------------- C.A.S. NO. ------------- ------ ------ ----------------- PERCENT ----------------- WATER ..... ...............:............... 7732-18-5 60 - 90 STYRENE-ACRYLONITRILE POLYMER........... 9003-54-7 10 - 30 DIETHYLENE GLYCOL MONOMETHYL ETHER...... 111-77-3 3 - 7 ACRYLATE COPOLYMER ...................... 63744-68-3 1 - 5 TRI(BUTOXYETHYL) PHOSPHATE .............. 78-51-3 1 - 5 MALEIC ANHYDRIDE-PROPYLENE POLYMER...... 25722-45-6 1 - 5 ZINC AMMONIA CARBONATE COMPLEX..:....... 38714-47-5 0.5 - 1.5 DIBUTYL PHTHALATE ....................... 84-74-2 0.1 - 1.0 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. The components of this product are in compliance with the chemical notification requirements of TSCA. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372: DIETHYLENE GLYCOL MONOMETHYL ETHER TRI(BUTOXYETHYL) PHOSPHATE ZINC AMMONIA CARBONATE COMPLEX DIBUTYL PHTHALATE Clsrc_# 226010 A./SAE _ 8 i/ c_o~/a~-~~~f ~ Z G~ ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND STELLAR(TM) UHS FLOOR FINISH October 13, 1998 PAGE 2 ---------------- 2. PHYSICAL DATA BOILING POINT :................. ca. 212 F VAPOR PRESSURE :................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY :.............. ca. 1.0 Water=l PERCENT VOLATILE :.............. ca. 78 pH :............................ 8 - 9 VISCOSITY :..................... < 10 centipoise MELTING POINT :................. N/A APPEARANCE AND ODOR: Liquid, opaque white, mild ammonia odor ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT :................... N/A FLAMMABLE LIMITS - LEL:........ N/A FLAMMABLE LIMITS - UEL:........ N/A AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Not applicable UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. NFPA HAZARD CODES: HEALTH: 0 FIRE: 0 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none ------------------ 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Protect from freezing. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND STELLAR(TM) UHS FLOOR FINISH October 13, 1998 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Irritant Vapors or Gases. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled material. Clean up residue with water. Place in a closed container. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility in the presence of a combustible material. Dispose of empty cans in a sanitary landfill. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: ca. 4.1 0. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). TSCA: All components used in the manufacture of this material are in compliance with the U.S. TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND STELLAR(TM) UHS FLOOR FINISH October 13, 1998 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact with vapor, spray, or mist. Wear unvented goggles during operations in which exposure is likely. SKIN PROTECTION: Avoid prolonged or repeated skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber. RECOMMENDED VENTILATION: Do not use in a confined area or areas with little or no air movement. Use in a well-ventilated area. Use with adequate dilution ventilation. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: half-mask organic vapor respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. RECOMMENDED STORAGE: Store away from areas where product may come into contact with food or pharmaceuticals. Store at temperatures above 32 degrees F (O degrees C). Keep container dry. Keep container closed when not in use. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND STELLAR(TM) UHS FLOOR FINISH October 13, 1998 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ~ OTHER PRECAUTIONARY INFORMATION: Not intended for consumer sale or use. HMIS HAZARD RATINGS: HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENT --------------------------------------- VALUE -------- UNIT -------- TYPE --------- AUTH SKIN* ------------- WATER ................................ NONE NONE NONE NONE STYRENE-ACRYLONITRILE POLYMER........ NONE NONE NONE NONE DIETHYLENE GLYCOL MONOMETHYL ETHER... 30 PPM TWA CMRG ACRYLATE COPOLYMER ................... NONE NONE NONE NONE TRI(BUTOXYETHYL) PHOSPHATE........... NONE NONE NONE NONE MALEIC ANHYDRIDE-PROPYLENE POLYMER... NONE NONE NONE NONE ZINC AMMONIA CARBONATE COMPLEX....... NONE NONE NONE NONE DIBUTYL PHTHALATE .................... 5 MG/M3 TWA ACGIH DIBUTYL PHTHALATE .................... 5 MG/M3 TWA OSHA * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by bhe cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - OSHA: Occupational Safety and Health Administration - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Mild Eye Irritation: signs/symptoms can include redness, swelling, pain, and tearing. SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, and itching. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND STELLAR(TM) UHS FLOOR FINISH October 13, 1998 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Prolonged or repeated exposure may cause: Irritation .(upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. Ingestion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. REPRODUCTIVE/DEVELOPMENTAL TOXINS:' REPRODUCTIVE STUDIES: 1. DIETHYLENE GLYCOL MONOMETHOL ETHER (111-7 7- 3) has been shown to reduce number of viable liters, number of 1 ive pups/liter and number of pups surviving over 1-3 days using an in vivo mouse screening bioassay. Reduced weights and increase in maternal mortality was also noted. 2. TERATOGEN STUDY: Teratogenicity of diethylene glycol monomethyl ether was evaluated in pregnant rabbits dermally exposed at levels of 0, 50, 250,-750 mg/kg/day. In high dose group: decreased maternal weight gain, increased mild fore limb flexure and dilated renal pelvis, increased retrocaval ureter , delayed ossification of sternebrae were seen in rabbit pups. In high to mid-dose groups: delayed ossification of hyoid skull and cervical vertebrae spur were also seen in rabbit pups. 3. Hardin et al. (1986) dosed rats orally on days 7-16 of gestation with 720 a nd 2165 mg/kg. Neither dose was maternally toxic, but rib and heart malformations were increased. DIBUTYL PHTHALATE (84-74-2) is a potential reproductive hazard causing embryotoxic, teratogenic and male reproductive effects by the oral route. of exposure in laboratory animals. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEADING SECTION CHANGED SINCE May 07, 1998 ISSUE INGREDIENTS SECTION CHANGED SINCE May 07, 1998 ISSUE PRECAUTIONARY INFO. SECTION CHANGED SINCE May 07, 1998 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND STELLAR(TM) UHS FLOOR FINISH October 13, 1998 PAGE 7 The information in this Material Safety Data Sheet (MSDS) is believed tc be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. -o~~7a90 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'n Fill (tm) Svsteml 07/27/2005 y-, C~_.i-~ ~i; Material Safety Data Sheet 0~0 UTE~S Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND CO~I~IPAVY IDE\TIFICATION PRODUCT NAME: 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist 'n Fill (tm) System) MANUFACTURER: 3M DIVISION: Commercial Care Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or 651 737-6501 24 hours Issue Date: 07/27/2005 Supercedes Date: 08/12/2002 Document Group: 06-8476-1 Product Use: Specific Use: DEODORIZER - -_- -- SECTION 2: ItiGREDIE~ITS Ingredient C.A.S. No. % by Wt POLYALKOXY ALCOHOLS 69013-18-9 30 - 60 FRAGRANCE (NJTSN 04499600-6518) Trade Secret 10 - 30 WATER 7732-18-5 10 - 30 SORBITAN POLYETHOXY MONOLAURATE 9005-64-5 7 - 13 1-METHOXY-2-PROPANOL 107-98-2 1 - 5 SECTIO\ 3: HAZ.aRDS IDENTIIr IC.ITION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear; dark green color; strong spicy fragrance General Physical Form: Liquid Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. May cause severe eye irritation. May cause allergic skin reaction. May cause target organ effects. Page 1 of 9 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'n Fill tm S stem 07/27/2005 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTIO~1 ~: FIRST AID 1TEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SFC~1'IO\ 5: FIRE SIGH"I'INC I~~IEASL?RES 5.1 FLAMMABLE PROPERTIES Page 2 of 9 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'n Fill tm S stem 07/27/2005 Flash Point > 200 °F [Test Method: Closed Cup] OSHA Flammability Classification: Class lIIB Combustible Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and aself-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Not applicable.. Closed containers exposed to heat from fire may build pressure and explode. Vapors may travel long distances along the ground or floor to an ignition source and flash back. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Ca113M- HELPS line (1-800-364-3577) for more information on.handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local state and federal re ulations. SECTION 7: H.~~~NDLINU AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors, mists or spray. Keep out of the reach of children. Avoid contact with oxidizing agents. This product is not intended to be used without prior dilution as specified on the product label. Avoid skin contact: Keep container closed when not in use. 7.2 STORAGE Keep container in well-ventilated area. Store away from oxidizing agents. SECTION 8: EtPOSCIRE CO\TROLS/PERSONAL. YRD~hECTION 8.1 ENGINEERING CONTROLS Use in awell-ventilated area. NOTE: When used as directed and diluted and dispensed with a TWIST'n FII.L(TM) Chemical Dispenser, special ventilation is not required. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) Page 3 of 9 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'n Fill tm S stem 07/27/2005 8.2.1 Eye/Face Protection Avoid eye contact. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FII.L(TM) Chemical Dispenser, eye contact with the concentrate is not expected to occur. If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is recommended: Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. NOTE: When used as directed and diluted and dispensed with a TWIST'n FII-L(TM) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl Rubber. The following protective clothing material(s) are recommended: Apron - Neoprene. 8.2.3 Respiratory Protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of vapors, mists or spray. NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL(TM) Chemical Dispenser, respiratory protection is not required. If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air- purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES InEredient 1-METHOXY-2-PROPANOL 1-METHOXY-2-PROPANOL 1-METHOXY-2-PROPANOL 1-METHOXY-2-PROPANOL CADMIUM DUST CADMNM DUST COPPER COMPOUNDS COPPER COMPOUNDS MANGANESE COMPOUNDS MANGANESE, INORGANIC COMPOUNDS MERCURY NON-ALKYL, VAPOR MERCURY NON-ALKYL, VAPOR MERCURY, ARYL & INORGANIC COMPOUNDS MERCURY, INORGANIC COMPOUNDS Authori Type Limit Additional Information ACGIH TWA 100 ppm ACGIH STEL 150 ppm OSHA TWA 100 ppm Table Z-lA OSHA STEL 150 ppm Table Z-lA OSHA TWA, as dust 0.2 mg/m3 Table Z-2 OSHA CEIL, as dust 0.6 mg/m3 Table Z-2 ACGIH TWA, as Cu dust or 1 mg/m3 mist OSHA TWA, as dust or mist 1 mg/m3 Table Z-]A OSHA CEIL, as Mn 5 mg/m3 Table Z-lA ACGIH TWA, as Mn 0.2 mg/m3 ACGIH TWA, as Hg 0.05 mg/m3 Skin Notation* OSHA TWA, as Hg 0.05 mg/m3 Skin Notation*; Table Z-lA OSHA CEIL, as Hg 0.1 mg/m3 Skin Notation*; Table Z-lA ACGIH TWA, as Hg 0.025 mglm3 Skin Notation*; Table A4 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. Page 4 of 9 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'n Fill tm S stem 07/27/2005 SOURCE OF EXPOSURE LIMTT DATA: ACG1H: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration A1HA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL A\D CHEI~TICAL PROPERTIES Specific Physical Form: Odor, Color, Grade: General Physical Form: Flash Point Boiling point Vapor Pressure Specific Gravity pH Solubility in Water Volatile Organic Compounds VOC Less H2O & Exempt Solvents Viscosity Liquid Clear; dark green color; strong spicy fragrance Liquid > 200 °F [Test Method: Closed Cup] Approximately 212 °F <=27 psia [@ 131 °FJ 1 [Ref Std: WATER=1] 6.5 - 8.5 Complete I 1 - 35 % [Test Method: calculated per CARB title 2] 300 - 500 g/1 [Test Method: calculated per CARB title 2] < 100 centipoise SECTION I0: STABILITI~ AND RE~CTI~~ITY Stability: Stable. Materials and Conditions to Avoid: Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Irritant Vapors or Gases Condition During Combustion During Combustion During Combustion _~ SECTION ll: TO~ICOLOGIC.~~L INk~ORti~IATION J Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its com onents. -- - SECT10\ I?: ECOLOCIC~L Iti~rORl~~IATION Page 5 of 9 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'u Fill tm S stem 07/27/2005 ECOTOXICOLOGICAL INFORMATION A 3M Product Environmental Data Sheet (PED) is available. CHEMICAL FATE INFORMATION A 3M Product Environmental Data Sheet (PED) is available. SECTION l3: DISPOSAL CONSIDERATIONS _~~ Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since re ulations va consult a licable re ulations or authorities before dis osal. - -- - - - jSECTION 14:TR~INSI'OR~1' INHOR:I~IATION ID Number UPC ID Number UPC 70-0708-4014-8 00-48011-20120-2 70-0710-1410-7 00-48011-23897-0 70-0711-9213-5 00-48011-20120-2 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFOR?~~IATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard -Yes Delayed Hazard - No STATE REGULATIONS CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EIIVECS. The components of this material are in compliance with the new chemical notification requirements for the Korean Existing Chemicals Inventory. The components of this product are listed on the Australian Inventory of Chemical Substances. All the components of this product are listed on China's Inventory of Chemical Substances. The components of this product are in compliance with notification requirements in the Philippines. Page 6 of 9 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'n Fill tm S stem 07/27/2005 The components of this product are listed on the Canadian Domestic Substances List. INTERNATIONAL REGULATIONS This MSDS has been re ared to meet the U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200. --- -- SECTLON 16: OTHER IVrOR~~1~ITION NFPA Hazard Classification Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 1 Reactivity: 0 Protection: X -See PPE section. Hazardous Material Identification System (HMIS®) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint and Coatings Association (NPCA). Revision Changes: Section 16: NFPA hazard classification heading was modified. Section 16: HMIS hazard classification heading was modified. Copyright was modified. Section 4: First aid for eye contact -decontamination -was modified. Section 4: First aid for eye contact -medical assistance -was modified. Section 3: Potential effects from eye contact was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 3: Potential effects from ingestion information was modified. Section 5: Extinguishing media information was modified. Section 5: Fire fighting procedures information was modified. Section 5: Unusual fire and explosion hazard information was modified. Section 6: Release measures information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Engineering controls information was modified. Section 8: Eye/face protection phrase was modified. Section 8: Skin protection phrase was modified. Section 8: Respiratory protection information was modified. Section 13: Waste disposal method information was modified. Section 15: 311/312 hazard categories heading was modified. Section 4: First aid for ingestion (swallowing) -decontamination -was modified. Section 4: First aid for ingestion (swallowing) -medical assistance -was modified. Section 10: Hazardous polymerization heading was modified. Section 14: ID Number(s) and/or UPC(s) was modified. Section 2: Ingredient table was modified. Page 7 of 9 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'u Fill tm S stem 07/27/2005 Section 16: HMIS explanation was modified. Section 16: NFPA explanation was modified. Section 15: 311/312 Delayed Hazard score was modified. Section 15: Inventories information was modified. Section 12: Ecotoxicological information heading was modified. Section 12: Chemical fate information heading was modified. Section 5: Flash point information was modified. Section 9: Property description for optional properties was modified. Section 9: Specific gravity information was modified. Section 9: pH information was modified. Section 16: NFPA hazard classification for special hazards was modified. Section 9: Flash point information was modified. Section 8: Eye/face protection comment was added. Section 8: Skin protection comment was added. Section 8: Respiratory protection comment was added. Section 3: Other potential health effects heading was added. Section 8: Exposure guidelines data source legend was added. Section 3: Immediate skin hazard(s) was added. Section 3: Immediate eye hazard(s) was added. Section 3: Immediate physical hazard(s) was added. Section 3: Immediate other hazard(s) was added. Section 3: Other health effects information was added. Section 8: Exposure guidelines ingredient information was added. Section 8: Exposure guideline note was added. Section 2: Ingredient phrase was added. Section 12: Ecotoxicological phrase was added. Section 12: Chemical Fate phrase was added. Section 8: Eye/face protection information was deleted. Section 8: Eye/face protection text was deleted. Section 12: Ecotoxicological ecotox article information was deleted. Section 9: Density information was deleted. Section 9: Vapor density value was deleted. Section 5: Flammable limits (UE) information was deleted. Section 5: Flammable limits (LEL) information was deleted. Section 5: Autoignition temperature information was deleted. Section 9: Melting point information was deleted. Section 8: Exposure guidelines information -none -was deleted. Section 12: Ecotoxicological ecofate information was deleted. Section 9: Flammable limits (LEL) information was deleted. Section 9: Flammable limits (UEL) information was deleted. Section 9: Autoignition temperature information was deleted. Section 8: Eye/face protection information -punctuation -was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABII.ITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as cun'ent as the information in the MSDS available directly from 3M. Page 8 of 9 ,. 3M MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER -MOUNTAIN SPICE -CONCENTRATE (Product No. 14, Twist'u Fill tm S stem 07/27/2005 3M MSDSs are available at www.3M.com Page 9 of 9 \ ~ MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2002, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) ID NUMBER/U.P.C.: 70-0708-3103-0 00-48011-23550-4 70-0708-3104-8 00-48011-23551-1 70-0708-3141-0 00-48011-23581-8 70-0708-3142-8 00-48011-23582-5 70-0709-9003-4 00-48011-29618-5 70-0710-0694-7 00-48011-23550-4 70-0710-0695-4 00-48011-23551-1 70-0710-0726-7 00-48011-23581-8 70-0710-0727-5 00-48011-23582-5 ISSUED: January 07, 2002 SUPERSEDES: April 09, 2001 DOCUMENT: 08-6408-2 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- WATER ................................... ALKYL (68% C12, 32% C14) DIMETHYL ETHYLBENZYL AMMONIUM CHLORIDE......... ALKYL (60% C14, 30% C16, 5% C12, 5% C18) DIMETHYL BENZYL AMMONIUM CHLORIDE ETHOXYLATED NONYLPHENOL, BRANCHED....... TETRASODIUM ETHYLENEDIAMINETETRAACETATE. ETHYL ALCOHOL ........................... SODIUM HYDROXIDE ........................ 7732-18-5 40 - 70 68391-01-5 13.2 68956-79-6 13.2 127087-87-0 5 - 10 64-02-8 3 - 7 64-17-5 1 - 5 1310-73-2 < 0.2 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. The components of this product are in compliance with the chemical notification requirements of TSCA. ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT :................. N/D VAPOR PRESSURE :................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... complete ~-Clsrc #-Z27227~ ~ocA n o ~-~ A~1~FE 3~ ci ~o_~/~ ~a ~,;~~s Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately r MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 2 ----------------=------------------------------------------------------------ 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- SPECIFIC GRAVITY :.............. ca. 1.03 Water=l PERCENT VOLATILE :.............. ca. 61 pH :............................ ca. 13 VISCOSITY :..................... ~ 100 centipoise MELTING POINT :................. N/A APPEARANCE AND ODOR: Liquid, clean, light amber color, mild odor. ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT :................... ca. 133 F TCC FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA N Water, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Use fresh air respirator. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 3 FIRE: 2 REACTIVITY: 0 UNUSUAL REACTION HAZARD: corrosive OSHA FIRE HAZARD CLASS: Class II Combustible Liquid ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Highly alkaline material. Avoid mixing with strongly acidic materials. Rapid heating and spattering of mixture may result. ----------------------------------------------------------------------------- Abbreviations:'N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen Chloride. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with inorganic absorbent material. Dilute in a large excess of water. Carefully, and with stirring, add appropriate dilute acid such as sulfamic acid or vinegar. Confirm neutrality. Collect using non-sparking tools. Clean up residue with water. Place in a polyethylene-lined metal container. Do not seal for 48 hours. RECOMMENDED DISPOSAL: Incinerate in a permitted hazardous waste incinerator. Combustion products will include HC1. ENVIRONMENTAL DATA: This product is a disinfectant; it is toxic to microorganisms. Care must be taken to avoid improper disposal or release to the environment. When properly handled, use of this product is expected to have minimal environmental impact. Most components of this product will eventually degrade in the environment. REGULATORY INFORMATION: Volatile Organic Compounds: 3 - 5 0. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) D002 (Corrosive) TSCA: All components used in the manufacture of this material are in compliance with the US TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately T MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n~Fill(tm) System) January 07, 2002 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water for at-least 15 minutes. Get immediate medical attention. SKIN CONTACT: Immediately flush skin with large amounts of water for at least 15 minutes in a chemical safety shower while removing contaminated clothing and shoes. Get immediate medical attention. Wash contaminated clothing before reuse. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed,.do NOT induce vomiting. Give victim two glasses of water. Call a physician immediately. Never give anything by mouth to an unconscious person. Note to physician: Probable mucosal damage may contraindicate the use of gastric lavage. OTHER FIRST AID INFORMATION: Measures against circulatory shock, respiratory depression, and convulsion may be needed. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION EYE PROTECTION: NOTE: When used.as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Wear vented goggles. Wear full-face shield. SKIN PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber, neoprene, nitrile rubber. Use one or more of the following personal protection items as necessary to prevent skin contact: apron, coveralls. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, special ventilation is not required. Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL {tm) Chemical Dispenser, respiratory protection is not required. Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. Do not ingest. Avoid contamination of food. RECOMMENDED STORAGE: Store away from areas where product may come into contact with food or pharmaceuticals. Do not store containers on their sides. Store out of direct sunlight. Keep container closed when not in use. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. Keep away from heat, sparks, open flame, and other sources of ignition. Combustible liquid and vapor. OTHER PRECAUTIONARY INFORMATION: NOTE: The above precautionary information presumes that this ready-to- use product has been diluted and dispensed from a TWIST'n FILL (tm) Chemical Dispenser. This product is not intended to be used without prior dilution as specified on the product label. Avoid creasing or impacting container side walls. HMIS HAZARD RATINGS: HEALTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7 EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* WATER ................................ NONE NONE NONE NONE ALKYL (68% C12, 32% C14) DIMETHYL ETHYLBENZYL AMMONIUM CHLORIDE...... NONE NONE NONE NONE ALKYL (60% C14, 30% C16, 5% C12, Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 6 EXPOSURE LIMITS (continued) INGREDIENT VALUE UNIT TYPE AUTH SKIN* --------- --------------------------------------------------------- 5% C18) DIMETHYL BENZYL AMMONIUM ----------- CHLORIDE ........................... NONE NONE NONE NONE ETHOXYLATED NONYLPHENOL, BRANCHED.... NONE NONE NONE NONE TETRASODIUM ETHYLENEDIAMINETETRAACETATE........ NONE NONE NONE NONE ETHYL ALCOHOL ........................ 1000 PPM TWA ACGIH ETHYL ALCOHOL ........................ 1000 PPM TWA OSHA SODIUM HYDROXIDE ..................... 2 MG/M3 CEIL ACGIH SODIUM HYDROXIDE ..................... 2 MG/M3 CEIL OSHA SODIUM HYDROXIDE ..................... 2 MG/M3 TWA CMRG 15 MINUTES TWA * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - OSHA: Occupational Safety and Health Administration - NONE: None Established --------------------------------------------------------- 8. HEALTH HAZARD DATA --------------------------------------------------------- -------------------- -------------------- EYE CONTACT: Chemical Related Eye Burns (chemical corrosivity): signs/symptoms can include cloudy appearance of the cornea, chemical burns, pain, tearing, ulcers, impaired vision or loss of vision. SKIN CONTACT: Skin Burns (chemical corrosivity): signs/symptoms can include redness, swelling, itching, pain, blistering, ulceration, sloughing, and scar formation. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 7 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- soreness of the nose and throat, coughing-and sneezing. Prolonged or repeated exposure may cause: Nervous System Effects: signs/symptoms can include emotional changes, lack of coordination, tremors and sensory loss. Lung Damage: signs/symptoms can include coughing, difficulty breathing, wheezing, tightness in chest, congestion, and coughing up of blood. IF SWALLOWED: Harmful or fatal if swallowed. Damage to Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, nausea, abdominal tenderness, burns of mouth, difficulty swallowing, blood in vomitus, blood in feces, and ulceration. REPRODUCTIVE/DEVELOPMENTAL TOXINS: WARNING: This product contains ethanol. Ethanol is listed under Proposition 65 as a reproductive hazard through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Ethanol in alcoholic beverages can cause birth defects or other reproductive harm. OTHER HEALTH HAZARD INFORMATION: Note: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEADING SECTION CHANGED SINCE April 09, 2001 ISSUE PRECAUTIONARY INFO. SECTION CHANGED SINCE April 09, 2001 ISSUE HEALTH HAZARD DATA SECTION CHANGED SINCE April 09, 2001 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately U MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 8 The information in this Material Safety Data Sheet (MSDS) is believed tc be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED T0, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. T Clsr-c-#-227225 MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2002, Minnesota Mining and Manufacturing Company. . All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) ID NUMBER/U.P.C.: 70-0708-3103-0 00-48011-23550-4 70-0708-3104-8 00-48011-23551-1 70-0708-3141-0 00-48011-23581-8 70-0708-3142-8 00-48011-23582-5 70-0709-9003-4 00-48011-29618-5 70-0710-0694-7 00-48011-23550-4 70-0710-0695-4 00-48011-23551-1 70-0710-0726-7 00-48011-23581-8 70-0710-0727-5 00-48011-23582-5 ISSUED: January 07, 2002 SUPERSEDES: April 09, 2001 DOCUMENT: 08-6408-2 t_rx_A--r~J c.~1_--~ ~~~ 8~~ _o r3~G~ ~~ LI ~/~S ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT WATER ................................... ALKYL (68o C12, 32o C14) DIMETHYL ETHYLBENZYL AMMONIUM CHLORIDE......... ALKYL (60°s C14, 30% C16, 5°s C12, 5% C18) DIMETHYL BENZYL AMMONIUM CHLORIDE ETHOXYLATED NONYLPHENOL, BRANCHED....... TETRASODIUM ETHYLENEDIAMINETETRAACETATE. ETHYL ALCOHOL ........................... SODIUM HYDROXIDE ........................ 7732-18-5 40 - 70 68391-01-5 13.2 68956-79-6 13.2 127087-87-0 5 - 10 64-02-8 3 - 7 64-17-5 1 - 5 1310-73-2 < 0.2 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. The components of this product are in compliance with the chemical notification requirements of TSCA. ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT :................. N/D VAPOR PRESSURE :................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... complete Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately r ~~ Clsrc # 227225 MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- SPECIFIC GRAVITY :.............. ca. 1.03 Water=l PERCENT VOLATILE :.............. ca. 61 pH :............................ ca. 13 VISCOSITY :..................... < 100 centipoise MELTING POINT :................. N/A APPEARANCE AND ODOR: Liquid, clean, light amber color, mild odor. 3. FIRE AND EXPLOSION HAZARD DATA --------------------------------- FLASH POINT :................... ca. 133 F TCC FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: water, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Use fresh air respirator. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 3 FIRE: 2 REACTIVITY: 0 UNUSUAL REACTION HAZARD: corrosive OSHA FIRE HAZARD CLASS: Class II Combustible Liquid ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Highly alkaline material. Avoid mixing with strongly acidic materials. Rapid heating and spattering of mixture may result. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately Clsrc # 227225 MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen Chloride. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with inorganic absorbent material. Dilute in a large excess of water. Carefully, and with stirring, add appropriate dilute acid such as sulfamic acid or vinegar. Confirm neutrality. Collect using non-sparking tools. Clean up residue with water. Place in a polyethylene-lined metal container. Do not seal for 48 hours. RECOMMENDED DISPOSAL: Incinerate in a permitted hazardous waste incinerator. Combustion products will include HC1. ENVIRONMENTAL DATA: This product is a disinfectant; it is toxic to microorganisms. Care must be taken to avoid improper disposal or release to the environment. When properly handled, use of this product is expected to have minimal environmental impact. Most components of this product will eventually degrade in the environment. REGULATORY INFORMATION: Volatile Organic Compounds: 3 - 5 °s. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable), D002 (Corrosive) TSCA: All components used in the manufacture of this material are in compliance with the US TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately Clsrc # 227225 MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Immediately flush skin with large amounts of water for at least 15 minutes in a chemical safety shower while removing contaminated clothing and shoes. Get immediate medical attention. Wash contaminated clothing before reuse. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed, do NOT induce vomiting. Give victim two glasses of water. Call a physician immediately. Never give anything by mouth to an unconscious person. Note to physician: Probable mucosal damage may contraindicate the use of gastric lavage. OTHER FIRST AID INFORMATION: Measures against circulatory shock, respiratory depression, and convulsion may be needed. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, eye contact with the concentrate is not . expected to occur. Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Wear vented goggles. Wear full-face shield. SKIN PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber, neoprene, nitrile rubber. Use one or more of the following personal protection items as necessary to prevent skin contact: apron, coveralls. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately Clsrc # 227225 MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, special ventilation is not required. Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, respiratory protection is not required. Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. . PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. Do not ingest. Avoid contamination of food. RECOMMENDED STORAGE: Store away from areas where product may come into contact with food or pharmaceuticals. Do not store containers on their sides. Store out of direct sunlight. Keep container closed when not in use. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. Keep away from heat, sparks, open flame, and other sources of ignition. Combustible liquid and vapor. OTHER PRECAUTIONARY INFORMATION: NOTE: The above precautionary information presumes that this ready-to- use product has been diluted and dispensed from a TWIST'n FILL (tm) Chemical Dispenser. This product is not intended to be used without prior dilution as specified on the product label. Avoid creasing or impacting container side walls. HMIS HAZARD RATINGS: HEALTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7 EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* WATER ................................ NONE NONE NONE NONE ALKYL (68o C12, 32°s C14) DIMETHYL ETHYLBENZYL AMMONIUM CHLORIDE...... NONE NONE NONE NONE ALKYL (60°s C14, 30°s C16, 5°s C12, Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately Clsrc # 227225 MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n,Fill(tm) System) January 07, 2002 PAGE 6 EXPOSURE LIMITS (continued) INGREDIENT VALUE UNIT TYPE AUTH SKIN* ----------------------------------------------------------------------------- 5a C18) DIMETHYL BENZYL AMMONIUM CHLORIDE ........................... NONE NONE NONE NONE ETHOXYLATED NONYLPHENOL, BRANCHED.... NONE NONE NONE NONE TETRASODIUM ETHYLENEDIAMINETETRAACETATE........ NONE NONE NONE NONE ETHYL ALCOHOL ........................ 1000 PPM TWA ACGIH ETHYL ALCOHOL ........................ 1000 PPM TWA OSHA SODIUM HYDROXIDE ..................... 2 MG/M3 CEIL ACGIH SODIUM HYDROXIDE ..................... 2 MG/M3 -CEIL OSHA SODIUM HYDROXIDE .......:............. 2 MG/M3 TWA CMRG 15 MINUTES TWA * SKIN NOTATION: Listed substances indicated with~'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - OSHA: Occupational Safety and Health Administration - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA EYE CONTACT: Chemical Related Eye Burns (chemical corrosivity): signs/symptoms can include cloudy appearance of the cornea, chemical burns, pain, tearing, ulcers, impaired vision or loss of vision. SKIN CONTACT: Skin Burns (chemical corrosivity): signs/symptoms can include redness, swelling, itching, pain, blistering, ulceration, sloughing, and scar formation. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately Clsrc # 227225 MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 7 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- soreness of the nose and throat, coughing and sneezing. Prolonged or repeated exposure may cause: Nervous System Effects: signs/symptoms can include emotional changes, lack of coordination, tremors and sensory loss. Lung Damage: signs/symptoms can include coughing, difficulty breathing, wheezing, tightness in chest, congestion, and coughing up of blood. IF SWALLOWED: Harmful or fatal if swallowed. Damage to Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, nausea, abdominal tenderness, burns of mouth, difficulty swallowing, blood in vomitus, blood in feces, and ulceration. REPRODUCTIVE/DEVELOPMENTAL TOXINS: WARNING: This product contains ethanol. Ethanol is listed under Proposition 65 as a reproductive hazard through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Ethanol in alcoholic beverages can cause birth defects or other reproductive harm. OTHER HEALTH HAZARD INFORMATION: Note: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEADING SECTION CHANGED SINCE April 09, 2001 ISSUE PRECAUTIONARY INFO. SECTION CHANGED SINCE April 09, 2001 ISSUE HEALTH HAZARD DATA SECTION CHANGED SINCE April 09, 2001 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately C Clsrc # 227225 MSDS: 3M Brand HB QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 25, Twist 'n Fill(tm) System) January 07, 2002 PAGE 8 The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED T0, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. :~~ ~4 MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) x.37-6501 (24 hours) Copyright, 2002, Minnesota Mining and Man~lfacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. 70-0710-0981-8 00-48011-23914-4 ISSUED: January 09, 2002 SUPERSEDES: January 17, 2001 DOCUMENT: 08-4516-4 DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill (tm) System ID NUMBER/U.P.C.: 70-0708-3106-3 00-48011-23553-5 70-0708-3144-4 00-48011-23584-9 70-0708-4006-4 00-48011-23553-5 70-0709-9336-8 - - - -------------------------------------- 1. INGREDIENT -------------------------------------- ----------------- C.A.S. NO. ----------------- ---- ---- ------------------ PERCENT ------------------ POLYOXYETHYLENE TRIDECYL ETHER........ .. 24938-91-8 30 - 70 2-ETHYL-HEXYLOXYETHANOL ............... .. 1559-35-9 10 - 30 WATER ................................. .. 7732-18-5 5 - 10 DIETHYLENE GLYCOL MONO(2-ETHYLHEXYL) ETHER ............................... .. 1559-36-0 1 - 5 FRAGRANCE ............................. .. Unknown 0.5 - 1.5 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. The components of this product are in compliance with the chemical notification requirements of TSCA. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-TO-Know Act of 1986 and 40 CFR Part 372: 2-ETHYL-HEXYLOXYETHANOL DIETHYLENE GLYCOL MONO(2-ETHYLHEXYL) ETHER C~-# 22.7_1Q5 1..0~~'TI O/v o $ Ja_3_/_c~ ~f8~r~~Zs ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately s. MSDS: 3M Brand 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill (tm) System January 09, 2002 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT :.......:......... N/D VAPOR PRESSURE :................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY :.............. ca. 0.95 Water=l PERCENT VOLATILE :.............. ca. 10 °s pH :............................ 7 - 8 VISCOSITY :..................... < 100 centipoise MELTING POINT :................. N/D APPEARANCE AND ODOR: Liquid, dark blue. Citrus odor. 3. FIRE AND EXPLOSION HAZARD DATA --------------------------------- FLASH POINT :................... > 200 F FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water spray, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: Not determined. NFPA HAZARD CODES: HEALTH: 2 FIRE: 1 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Bases, Strong Oxidizing Agents. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill (tm) System January 09, 2002 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled material. Clean up residue with water. Place in a closed container. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility. ENVIRONMENTAL DATA: -Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: ca. 1 °s. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). TSCA: All components used in the manufacture of this material are in compliance with the US TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately r MSDS: 3M Brand 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill (tm) System January 09, 2002 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. Wear unvented goggles during operations in which exposure is likely. SKIN PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber. RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, special ventilation is not required. Use in a well-ventilated area. -Use with adequate dilution ventilation. RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, respiratory protection is not required. Avoid prolonged breathing of vapors. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: half-mask organic vapor respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not ingest. RECOMMENDED STORAGE: Keep container closed when not in use. Keep out of the reach of children. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill (tm) System January 09, 2002 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. May form explosive peroxides. OTHER PRECAUTIONARY INFORMATION: This product is not intended to be used without prior dilution as specified on the product label. HMIS HAZARD RATINGS: HEALTH: 1 FLAMMABILITY: 1 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN* -------- - -------------------------------------- POLYOXYETHYLENE TRIDECYL ETHER....... --------- NONE -------- NONE --------- NONE - --- NONE 2-ETHYL-HEXYLOXYETHANOL .............. NONE NONE NONE NONE WATER ................................ NONE NONE NONE NONE DIETHYLENE GLYCOL MONO(2- ETHYLHEXYL) ETHER .................. NONE NONE NONE NONE FRAGRANCE ............................ NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Moderate Eye Irritation: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision. SKIN CONTACT: Moderate Skin Irritation: signs/symptoms can include redness, swelling, itching, and dryness. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single exposure may cause: Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately ~~~ ^~ MSDS: 3M Brand 3-IN-1 FLOOR CLEANER CONCENTRATE (Product No. 24, Twist 'n Fill (tm) System January 09, 2002 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- Prolonged or repeated exposure may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. Ingestion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. Aspiration Pneumonitis: signs/symptoms can include coughing, difficulty breathing, wheezing, coughing up blood and pneumonia, which can be fatal. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEADING SECTION CHANGED SINCE January 17, 2001 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. +~ ¢ t 7228 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) EXTRACTION CLEANER (CONCENTRATE) (Product No. 27, Twist ... _ , .k ,. F `' 1..v ;.J ~[_;~ I_..; Material Safety Data Sheet l 2 ~-I T~~S Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. - - SECTION l: PRODUC rh A1~D COMP ai\ 1' IDENTIFIC ~~"TION --- - PRODUCT NAME: SCOTCHGARD(TM) EXTRACTION CLEANER (CONCENTRATE) (Product No. 27, Twist 'n Fill(tm) System) MANUFACTURER: 3M DIVISION: Commercial Care Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or 651) 737-6501 24 hours Issue Date: 09/16/2003 Supercedes Date: 06/06/2003 Document Group: 18-3962-0 Product Use: Specific Use: Carpet Cleaning SECTION 2: INGREDIENTS ~ ~, Ingredient WATER SODIUM TRIPOLYPHOSPHATE ETHOXYLATED C12-C15 ALCOHOLS 2-BUTOXYETHANOL SODIUM XYLENE SULFONATE C.A.S. No. % by Wt 7732-18-5 60- 90 7758-29-4 3 - 7 68131-39-5 3 - 7 111-76-2 3 - 7 1300-72-7 1 - 5 ~ECT[ON-3: HAZARDS IDEi~TIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear, colorless liquid with honeysuckle fragrance General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause target organ effects. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. C~51o_~ /o-~ 1 of 6 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) EXTRACTION CLEANER (CONCENTRATE) (Product No. 27, Twist 'n Fill tm S stem 09/16/2003 May be absorbed through skin and cause target organ effects. Inhalation: Single exposure, above recommended guidelines, may cause: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Target Organ Effects: Single exposure, above recommended guidelines, may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get medical attention. Skin Contact: Immediately flush skin with large amounts of water. If signs/symptoms develop, get medical attention. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention, `SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Not Applicable Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL NotApplicable OSHA Flammability Classification: Not Applicable 5.2 EXTINGUISHING MEDIA Material will not burn. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Nonflammable. Unusual Fire and Explosion Hazards: Not applicable. SE'CTI0~1 6: ACC[DENT:IL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Ca113M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazazd azea. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. Working from around the edges of the spill 2of6 r~ 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) EXTRACTION CLEANER (CONCENTRATE) (Product No. 27, Twist 'n Fill tm S stem 09/16/2003 inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING This product is not intended to be used without prior dilution as specified on the product label. Avoid eye contact with vapors, mists, or spray. Avoid skin contact. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep out of the reach of children. 7.2 STORAGE Keep container in well-ventilated area. SECTION 8: EXPOSURE CONTROLS/PERSONAL NRO'TECTION 8.1 ENGINEERING CONTROLS NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL(TM) Chemical Dispenser, special ventilation is not required. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FII.L(TM) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact with vapors, mists, or spray. 8.2.2 Skin Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL(TM) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. 8.2.3 Respiratory Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FII.L(TM) Chemical Dispenser, respiratory protection is not required. Avoid breathing of vapors, mists or spray. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ineredient Authori Tune Limit Additional Information 2-BUTOXYETHANOL ACGIH TWA 20 ppm Table A3 2-BUTOXYETHANOL OSHA TWA, 25 ppm Skin Notation* Vacated 2-BUTOXYETHANOL OSHA TWA 50 ppm Skin Notation*; Table Z-1 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. VAC Vacated PEL:Vacated Permissible Exposure Limits [PEL] are enforced as the OSHA PEL in some states. Check with your local regulatory agency. 3 of 6 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) EXTRACTION CLEANER (CONCENTRATE) (Product No. 27, Twist 'o Fill tm S stem 09/16/2003 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration ' AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) --- - - - -- '.SECTION '9: PHYSICAL AN D CHEMIC' AL PROPERTIES Specific Physical Form: Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point Density Vapor Density Vapor Pressure Specific Gravity pH Melting point Solubility in Water Evaporation rate Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Viscosity Liquid Clear, colorless liquid with honeysuckle fragrance Liquid Not Applicable Not Applicable Not Applicable Not Applicable > 200 °F No Data Available No Data Available No Data Available Approximately 1.1 [Ref Std: WATER=1] 7-9 Not Applicable Complete No Data Available < 10 % [Test Method: calculated per CARB title 2] 63-97% 250 - 1000 g/1 [Test Method: calculated per CARB title 2] < 50 centipoise SECTION 10: '.STABILITY Alm REACTIVITY Stability: Stable. Materials and Conditions to Avoid; None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition: Under recommended usage conditions, hazardous decomposition products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material. - - - SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its com onents. SECTION 12: ECOLOGICAL INFORMATION' ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. --- - _ SECTION 13: ll1SYOSAL CONS1llE1ZA`PIONS 4of6 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) EXTRACTION CLEANER (CONCENTRATE) (Product No. 27, Twist 'n Fill tm S stem 09/16/2003 Waste Disposal Method: Discharge spent solutions and small quantities (less than 5 gal.(19 L)) to a wastewater treatment system..As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since re ulations var consult a licable re ulations or authorities before dis osal. -- - - ~ECTION 14:TRANSPORT IN ~OR~ti1~~TIONT ID Number UPC ID Number UPC 70-0711-6285-6 00-48011-34857-0 70-0711-6299-7 00-48011-34867-9 Not regulated per U.S. DOT, IATA or IMO. These transportation classifications areprovided as a customer service. As the shipper YOU remain responsible jor complying with all applicable laws and regulations, includingproper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3Mpolicies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3Mpackage is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory `SE'CTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard -Yes Delayed Hazard - No Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt 2-BUTOXYETHANOL (GLYCOL ETHERS) 111-76-2 3 - 7 CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. This MSDS has been re ared to meet the U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200. SECTIOlti 16: OTHER INTFORMATLON NFPA Hazard Classification Health: 2 Flammability: 0 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazazd ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 0 Reactivity: 0 Protection: X -See PPE section. Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mazk of the National Paint and Coatings Association (NPCA). 5of6 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) EXTRACTION CLEANER (CONCENTRATE) (Product No. 27, Twist 'v Fill(tml Svsteml 09/16/2003 DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com 6of6 MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2001, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) ID NUMBER/U.P.C.: 70-0707-2960-6 00-48011-23218-3 70-0707-2961-4 00-48011-23219-0 70-0708-3993-4 00-48011-23218-3 70-0708-3994-2 00-48011-23219-0 70-0710-0962-8 00-48011-23884-0 70-0710-0964-4 00-48011-23904-5 ISSUED: December 03, 2001 SUPERSEDES: July 16, 2001 DOCUMENT: 06-1685-4 ~(~ Lr~ 5 ----------------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT ----------------------------------------------------------------------------- WATER ................................... BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM CHLORIDES ............................. OCTYLDECYLDIMETHYLAMMONIUM CHLORIDE..... BRANCHED-NONYLPHENOL, ETHOXYLATE........ ETHYL ALCOHOL ...................:....... DIDECYLDIMETHYLAMMONIUM CHLORIDE........ TETRASODIUM ETHYLENEDIAMINETETRAACETATE. DIOCTYL DIMETHYL AMMONIUM CHLORIDE...... SODIUM METASILICATE ..................... 7732-18-5 60 - 90 68424-85-1 8.68 32426-11-2 6.51 68412-54-4 5 - 10 64-17-5 1 - 5 7173-51-5 3.906 64-02-8 1 - 5 5538-94-3 2.604 6834-92-0 1 - 5 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT :................. ca. 212 F VAPOR PRESSURE :................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY :.............. ca. 1.00 Water=l PERCENT VOLATILE :.............. 65 - 80 °s pH :............................ ca. 12.6 Clsrc #_22.7.0.3.5 ~~ ~ ~.}~5~ B LD_5lD!~ -~~ Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- VISCOSITY :..................... < 100 centipoise MELTING POINT :................. N/A APPEARANCE AND ODOR: Liquid, clear, green color, pleasant odor. ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT :................... 133 F TCC FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 3 FIRE: 2 REACTIVITY: 0 UNUSUAL REACTION HAZARD: corrosive OSHA FIRE HAZARD CLASS: Class II Combustible Liquid 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Acids. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen Chloride. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 3 ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with inorganic absorbent material. Dilute in a large excess of water. Carefully, and with stirring, add appropriate dilute acid such as sulfamic acid or vinegar. Confirm neutrality. Collect using non-sparking tools. Clean up residue with water. Place in a polyethylene-lined metal container. Do not seal for 48 hours. RECOMMENDED DISPOSAL: Incinerate in a permitted hazardous waste incinerator. Combustion products will include HC1. ENVIRONMENTAL DATA: A Product Environmental Data Sheet (PED) is available. This product is a disinfectant; it is toxic to microorganisms. Care must be taken to avoid improper disposal or release to the environment. when properly handled, use of this product is expected to have minimal environmental impact. Most components of this product will eventually degrade in the environment. REGULATORY INFORMATION: Volatile Organic Compounds: < 60 gms/liter calculated per CARB title 2 section 94507. vOC Less H2O & Exempt Solvents: < 200 gms/liter calculated per CARB title 2 section 94507. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) D002 (Corrosive) TSCA: All components used in the manufacture of this material are in compliance with the US TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. ~ SKIN CONTACT: Immediately flush skin with large amounts of water for at least 15 minutes in a chemical safety shower while removing contaminated clothing and shoes. Get immediate medical attention. Wash contaminated clothing before reuse. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed, do NOT induce vomiting. Give victim two glasses of water. Call a physician immediately. Never give anything by mouth to an unconscious person. Note to physician: Probable mucosal damage may contraindicate the use of gastric lavage. OTHER FIRST AID INFORMATION: Measures against circulatory shock, respiratory depression, and convulsion may be needed. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Wear vented goggles. Wear full-face shield. SKIN PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber, neoprene, nitrile rubber. Use one or more of the following personal protection items as necessary to prevent skin contact: apron, coveralls. Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, special ventilation is not required. Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, respiratory protection is not required. Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contamination of food. RECOMMENDED STORAGE: Store away from areas where product may come into contact with food or pharmaceuticals. Do not store containers on their sides. Keep container closed when not in use. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. Keep away from heat, sparks, open flame, and other sources of ignition. Combustible liquid and vapor. . OTHER PRECAUTIONARY INFORMATION: This product is not intended to be used without prior dilution as specified on the product label. Avoid creasing or impacting container side walls. HMIS HAZARD RATINGS: HEALTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENT ---------- VALUE UNIT TYPE AUTH SKIN* ----------------------------- WATER ................................ -------- NONE -------- NONE --------- NONE ------------- NONE BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM CHLORIDES ................. NONE NONE NONE NONE OCTYLDECYLDIMETHYLAMMONIUM CHLORIDE ........................... NONE NONE NONE NONE BRANCHED-NONYLPHENOL, ETHOXYLATE..... NONE NONE NONE NONE ETHYL ALCOHOL ........................ 1000 PPM TWA ACGIH ETHYL ALCOHOL ........................ 1000 PPM TWA OSHA Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 6 EXPOSURE LIMITS (continued) INGREDIENT VALUE UNIT TYPE AUTH SKIN* --------------------------=-------------------------------------------------- DIDECYLDIMETHYLAMMONIUM CHLORIDE..... NONE NONE NONE NONE TETRASODIUM ETHYLENEDIAMINETETRAACETATE........ NONE NONE NONE NONE DIOCTYL DIMETHYL AMMONIUM CHLORIDE... NONE NONE NONE NONE SODIUM METASILICATE .................. NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists -OSHA: Occupational Safety and Health Administration - NONE: None Established ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Chemical Related Eye Burns (chemical corrosivity): signs/symptoms can include cloudy appearance of the cornea, chemical burns, pain, tearing, ulcers, impaired vision or loss of vision. SKIN CONTACT: Skin Burns (chemical corrosivity): signs/symptoms can include redness, swelling, itching, pain, blistering, ulceration, sloughing, and scar formation. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Prolonged or repeated exposure may cause: Lung Damage: signs/symptoms can include coughing, difficulty breathing, wheezing, tightness in chest, congestion, and coughing up of blood. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 7 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- IF SWALLOWED: Harmful or fatal if swallowed. Damage to Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, nausea, abdominal tenderness, burns of mouth, difficulty swallowing, blood in vomitus, blood in feces, and ulceration. REPRODUCTIVE/DEVELOPMENTAL TOXINS: WARNING: This product contains ethanol. Ethanol is listed under Proposition 65 as a reproductive hazard through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Ethanol in alcoholic beverages can cause birth defects or other reproductive harm. OTHER HEALTH HAZARD INFORMATION: Note: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEALTH HAZARD DATA SECTION CHANGED SINCE July 16, 2001 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 8 The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. :- = *=~i ~Clsrc # 42014 * : ,. ~ Date: ~ 7 April 2003 ~~~~~ ~ Supersedes: 15 October 2001 a LUCA-T1 D MATERIAL SAFETY DATA SHEET RlS~~ 8/N IN CASE OF EMERGENCY CALL CHEMTREC AT 1-800-424-9300 ~ G~. 1. PRODUCT IDENTIFICATION AND COMPANY IDENTIFICATION: Product Name: GOJO®SPA BATH® BODY & HAIR SHAMPOO 2. 3. Company Name & Address Emergency Phone: Non-Emergency Phone: MSDS Request Phone: GOJO Industries, Inc. One GOJO Plaza, Suite 500 Akron, OH 44311 1-800-424-9300 CHEMTREC (330) 255-6000 (330) 255-6000 x8804 INFORMATION ON INGREDIENTS: HAZARDOUS INGREDIENTS CAS NUMBER OSHA PEL ACGIH TLV % RANGE None Other ingredient(s) with notification requirements: CAS NUMBER List Sodium Lauryl Sulfate 151-21-3 CN 1 Ammonium Chloride 12125-02-9 PA 1 HAZARDS IDENTIFICATION: EMERGENCY OVERVIEW When used according to instructions, the product applicable to this MSDS is safe and presents no immediate or long-term health hazard. However, abnormal entry routes, such as gross ingestion, may require immediate medical attention. Potential Health Effects: HMIS: Health 1 Flammability 0 Reactivity 0 Personal Protection None Eye Contact: May cause eye irritation. Skin Contact: No irritation or reaction expected. Inhalation: Not applicable. ingestion: May cause upset stomach, nausea (Abnormal entry route). Carcinogenicity: Not listed as a carcinogen by NTP, IARC, OSHA or ACGIH. 4. FIRST AID MEASURES: Eye Contact: Do not rub eyes. Flush eyes thoroughly with water for 15 minutes. If condition worsens or irritation persists, contact physician. Skin Contact: Not applicable. Inhalation: Not applicable. Ingestion: Do not induce vomiting. Contact a physician or Poison Control Center. 4 'r 3-~ GOJOO SPA BATH® BODY 8 HAIR SHAMPOO 5. FIRE FIGHTING MEASURES: NFPA: Health 0 Fire 0 Reactivity 0 Page 2 of 2 Flashpoint °F/°C (PMCC method): Not determined. Unusual Fire and Explosion Hazards: None known. Special Fire Fighting Procedures: None known. Extinguishing Media: X Water Fog X Alcohol Foam X CO2 X Dry Chemical Other 6. ACCIDENTAL RELEASE MEASURES: No special requirements. Water clean up and rinse. CAUTION -WILL CAUSE SLIPPERY SURFACES. 7. HANDLING AND STORAGE: Store at normal room temperature away from reach of small children. Keep containers sealed. Use older containers first. Avoid freezing conditions. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION: Eye Protection: Skin Protection: Respiratory Protection: Ventilation: Protective Equipment or Clothing None required under normal conditions. None required under normal conditions. None required under normal conditions. None required under normal conditions. None required under normal conditions. 9. PHYSICAL AND CHEMICAL PROPERTIES: Appearance and Odor Rose clear liquid, pleasant fragrance pH (undiluted): 4.5 - 8.0 VOC , %: 0 10. STABILITY AND REACTIVITY: Stable/Non reactive product. 11. TOXICOLOGICAL INFORMATION: No acute or chronic toxic effects expected when used according to directions. 12. ECOLOGICAL CONSIDERATIONS: No ecological or special considerations when used according to directions. Not considered environmentally harmful from normal dilution, expected usage and typical drainage to sewers, septic systems and treatment plants. 13. DISPOSAL CONSIDERATIONS: No special considerations when disposed according to local, state and Federal regulations. 14. TRANSPORT INFORMATION: Not classified as a hazardous material. 15. REGULATORY AND OTHER INFORMATION: Complies with current FDA regulations for cosmetic and/or over-the-counter drug products. Notice: The information herein is based on data considered to be accurate as of the date of preparation of this material safety data sheet. However, no warranty or representation, expressed or implied, is made as to the accuracy or completeness of the foregoing data and safety information. The user assumes all liability for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices or from any hazards inherent in the nature of the product. Document: 9150-502 A-i_sc~ ~i~v Co_SLo_9_/_~_~ ~3cs Material Safety Data Sheet fIlVIIS® May be used to comply with OSHA's HEALTH 1 Hazard Communication Standard, 29 CFR 1910.1200. Standard must be FLAMMABILITY 2 consulted for specific requirements. Clsrc # 141160 REACTIVITY PERSONAL PROTECTION NONE Identity (As Used on Label and List) Nate: Blank spaces are not permitted. /J any item is not appucabte, or no information is available, the space must 6e marked to indicate that. 90901, 90985 HAND SANITIZER SCRUBS® SECTION I Manufacturer's Name Emergency Telephone Number ITW D mon 1-800-535-5053 Address (Number, Street, City, State, and ZIP Code) Telephone Number for Information 805 EAST OLD 56 HIGHWAY 1-913-397-9889 Date Prepared OLATHE, KANSAS 66061 Aril 3, 2000 Signature of Preparer (Optional) Re lato De t. SECTION II - Hazardous Ingredients/Identity Information Hazardous Components (Specific Other Limits Chemical Identity, Common Name(s)) CAS No. OSHA PEL ACGIH-TLV Recommended %(Opt.) Ethanol 64-17-5 1000 ppm 1000 ppm < 1 This product is not known to contain any compound listed and in quantities requiring reporting under SARA Title III Section 313. TSCA: All ingredients are on the TSCA inventory or are not required to be listed on the TSCA inventory. Any substance listed as hazardous by the States of California, Florida, Illinois, Michigan, New Jersey, Ohio, Pennsylvania or Texas is described above if known present in regulated concentrations. SECTION III Ph sical/Chemical Characteristics Boiling Point Specific Gravity (H O =. 1) 2 190 F 70 F 0.957 Vapor Pressure (mm-Hg @ 70 F) Melting Point No Data No Data Vapor Density (AIR = 1) Greater than Evaporation Rate (Butyl Acetate = 1) one 1 No Data Solubility in Water pH Complete 7.75+ 0.5 Appearance and Odor - Colorless translucent liquid with an alcohol -floral scent towel. SECTION IV -Fire and Explosion Hazard Data -- Flash Point (Method Used) Flammable Limits LEL UEL 107° F (TCC) No Data No Data No Data Extinguishing Media - Use carbon dioxide, dry chemical, foam or fog. Do not use water as it may froth and cause the fire to spread. Special Fire Fighting Procedures - Keep containers cool and vapors down with water spray. Prevent runoff from entering sewers and public waterways. Wear SCBA in chemical fires. Unusual Fire and Explosion Hazards - Combustible liquid on a polypropylene towel. .~ 90901, 90985 April 3, 2000 SECTION V - Reactivit Data Stability Unstable Conditions to Avoid - Do not use near open flame, sparks, static electricity, welding arcs, etc. Do not smoke while using. Stable I X Incompatibility (Materials to Avoid) - Strong oxidizing agents such as acetyl chloride, nitric acid, and hydrogen peroxide. Hazardous Decomposition or Byproducts - Carbon dioxide, carbon monoxide, formaldehyde, nitrous oxides, ammoniacal vapors, smoke, soot and various organic oxidation by- Hazardous Ma Occur Conditions to Avoid -None known Polymerization Will Not Occur X SECTION VI -Health Hazard Data Route(s) of Entry ~ Eyes? Yes ~ Inhalation? Yes ~ Skin? No ~ Ingestion? No Health Hazards (Acute and Chronic) -WARNING. Causes eye irritation. Maybe harmful if swallowed. Prolonged skin exposure may lead to dermatitis. Deliberate concentration and inhalation of vapors may cause central nervous system effects. Follow good chemica] hygiene practices to avoid these hazards. Carcinogenicity: I NTP? I IARC Monographs? I OSHA Regulated? None known No No No Signs and Symptoms of Exposure - Redness, tearing or burning in eyes. Redness, drying or cracking skin. Swallowing may cause nausea, diarrhea, drowsiness, dizziness, fatigue, or loss of coordination. Medical Conditions Generally Aggravated by Exposure - Pre-existing skin or gastrointestinal disorders may be adversely affected. Follow good chemical hygiene practices to avoid these hazards. Emergency and First Aid Procedures: -Eyes -Flush with plenty of water for at least 15 minutes lifting eyelids to insure complete removal. See a physician immediately. Ingestion - Call a physician or poison control center. Not a likely route of overexposure. Inhalation -Get to fresh air. If breathing has stopped, qualified personnel should administer artificial respiration. Skin -Wash with soap and water. If irritation persists, call physician. SECTION VII -Precautions for Safe Handling and Use Steps to be Taken in Case, Material is Released or Spilled -CAUTION. Slip hazard. Wipe up small spills promptly. For large spills, isolate area. Dike area to prevent spreading. Stay upwind. Eliminate ignition sources. Pick up on absorbent material. Put in suitable container Waste Disposal Method - Consult local, state, and federal regulations. Triple rinse empty container then offer for recycling, reuse, or reconditioning. Precautions to be Taken in Handling and Storing - Do not get in eyes. Do not swallow. Avoid prolonged skin contact. Keep containers. tightly sealed when not in use: Store indoors in a dry area. Keep from freezing. Use from original container only. Do not store with fertilizers, seeds, insecticides or fungicides. Other Precautions -Follow label directions carefully. Keep out of reach of children. Keep container tightly sealed when not in use. Do not contaminate water, food or feed by use or storage. Do not smoke while using. SECTION VIII -Control Measures Respiratory Protection (Specify Type) - Not usually necessary. Use with adequate ventilation. Use NIOSH/MSHA approved respirator if PELs or TLVs are exceeded. Ventilation I Local Exhaust I rvocusua~ryneeae° I Special chanical (General) I Yes I Other I None Protective Gloves - Eye Protection - Not usually necessary. Only for packaging. Not usually necessary. Avoid direct contact. Other Protective Clothing or Equipment - Not usually needed. For prolonged contact wear any necessary protective gear. Work/Hygienic Practices - Normal. Wash hands after use and before eating, drinking, smoking, using restrooms, etc. G: Thc uro ofmu praducr Va neynnd the sonuol of IM manufxnuer; mertfow, w guanmee, eaprawd or implreQ it madc u ro rbe eflzcb of rush or the ruuW to be ahreimd if awl urM N assoMantt with dvavimu m cNeblirhW wfe u. The u+er maul o.ume JI ropwvribiliry, inclWing injury m dmuge, rcrWling R.nn iu mir~ne vs such, m m cambinwioo wim Omer wlmiab. Tlw nunu(acrma wamnu ~mty rhn mia pmAslmav me manufasi Yr rpccifcadure fur nwM1 p~vdmr.THIS WARRANiV ISMLIEU OF ALL OTHER WARMNTIES.EXPRESS OR IMPLIED. AS TO DE5CR0'TION,QUALf1Y, MERCHANTABRJTY. FfiNF5S F00. ANY PA0.TCUTA0. PURPOSE, PRODURIVENESS, OR ANY OTNER MATER, OF THI$ PRODUCT. THE MANUFACTU0.ER SHALL BE IN NO WAV RESPONSIBLE FOR THE P0.0PE0. USE OF TIII$ PRODUCT. The rolc aM czslurive renudy agairel me menufasmrt fur Mewh n(wamnry Dull be wimbmaemem ofmc pvwhaw prise afrhepmdun in me avcm tNladeftttive ronNYan ofrhepmdun shall be fmudbeun NOOTHER REMEDY ILNCLDDING BUT NOT LIMITED TOINCIDENTAL Oft CONSEQUENTIAL DAMAOE$FOR MRIRY TO PERSON OR PROPERTY OR ANY OTNER MCmEMAL OR CONSEQUENTAL LOSSI SHALL BE AVAHARLE. MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 2001, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy-nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) ID NUMBER/U.P.C.: 70-0707-2960-6 00-48011-23218-3 70-0707-'8961-4 00-48011-23219-0 70-0708-3993-4 00-48011-23218-3 70-0708-3994-2 00-48011-23219-0 70-0710-0962-8 00-48011-23884-0 70-0710-0964-4 00-48011-23904-5 ISSUED: December 03, 2001 SUPERSEDES: July 16, 2001 DOCUMENT: 06-1685-4 Clsrc # 227030 L,OCG~'n o~J~ 05/O_9_~D_I ~~ ~- i~~S ----------------------------------------- 1. INGREDIENT ~ ----------------------------------------- ------------- C.A.S. N0. ------------- ------ ------ ----------------- PERCENT ----------------- WATER ................................... 7732-18-5 60 - 90 BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM CHLORIDES ............................. 68424-85-1 8.68 OCTYLDECYLDIMETHYLAMMONIUM CHLORIDE..... 32426-11-2 6.51 BRANCHED-NONYLPHENOL, ETHOXYLATE........ 68412-54-4 5 - 10 ETHYL ALCOHOL ........................... 64-17-5 1 - 5 DIDECYLDIMETHYLAMMONIUM CHLORIDE........ 7173-51-5 3.906 TETRASODIUM ETHYLENEDIAMINETETRAACETATE. 64-02-8 1 - 5 DIOCTYL DIMETHYL AMMONIUM CHLORIDE...... 5538-94-3 2.604 SODIUM METASILICATE ..................... 6834-92-0 1 - 5 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. ----------------------------------------------------------------------------- 2. PHYSICAL DATA ----------------------------------------------------------------------------- BOILING POINT :................. ca. 212 F VAPOR PRESSURE :................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE:.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY :.............. ca. 1.00 Water=l PERCENT VOLATILE :.............. 65 - 80 0 pH :............................ ca. 12.6 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA (continued) ----------------------------------------------------------------------------- VISCOSITY :..................... < 100 centipoise MELTING POINT :................. N/A APPEARANCE AND ODOR: Liquid, clear, green color, pleasant odor. ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT :................... 133 F TCC FLAMMABLE LIMITS - LEL:........ N/D FLAMMABLE LIMITS - UEL:........ N/D AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: water, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. Closed containers exposed to heat from fire may build pressure and explode. NFPA HAZARD CODES: HEALTH: 3 FIRE: 2 REACTIVITY: 0 UNUSUAL REACTION HAZARD: corrosive OSHA FIRE HAZARD CLASS: Class II Combustible Liquid ----------------------------------------------------------------------------- 4. REACTIVITY DATA ----------------------------------------------------------------------------- STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Strong Acids. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen Chloride. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 3 ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. ventilate area. Extinguish all ignition sources. Contain spill. Evacuate unprotected personnel from hazard area. Cover with inorganic absorbent material. Dilute in a large excess of water. Carefully, and with stirring, add appropriate dilute acid such as sulfamic acid or vinegar. Confirm neutrality. Collect using non-sparking tools. Clean up residue with water. Place in a polyethylene-lined metal container. Do not seal for 48 hours. RECOMMENDED DISPOSAL: Incinerate in a permitted hazardous waste incinerator. Combustion products will include HC1. ENVIRONMENTAL DATA: A Product Environmental Data Sheet (PED) is available. This product is a disinfectant; it is toxic to microorganisms. Care must be taken to avoid improper disposal or release to the environment. when properly handled, use of this product is expected to have minimal environmental impact. Most components of this product will eventually degrade in the environment. REGULATORY INFORMATION: Volatile Organic Compounds: < 60 gms/liter calculated per CARB title 2 section 94507. VOC Less H2O & Exempt Solvents: < 200 gms/liter calculated per CARB title 2 section 94507. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = D001 (Ignitable) D002 (Corrosive) TSCA: All components used in the manufacture of this material are in compliance with the US TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: Yes PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Immediately flush skin with large amounts of water for at least 15 minutes in a chemical safety shower while removing contaminated clothing and shoes. Get immediate medical attention. Wash contaminated clothing before reuse. INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: If swallowed, do NOT induce vomiting. Give victim two glasses of water. Call a physician immediately. Never give anything by mouth to an unconscious person. Note to physician: Probable mucosal damage may contraindicate the use of gastric lavage. OTHER FIRST AID INFORMATION: Measures against circulatory shock, respiratory depression, and convulsion may be needed. ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact. The following should be worn alone or in combination, as appropriate, to prevent eye contact: Wear vented goggles. Wear full-face shield. SKIN PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber, neoprene, nitrile rubber. Use one or more of the following personal protection items as necessary to prevent skin contact: apron, coveralls. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- RECOMMENDED VENTILATION: NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL (tm) Chemical Dispenser, special ventilation is not required. Use in a well-ventilated area. Provide sufficient ventilation to maintain emissions below recommended exposure limits. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: NOTE: When used as directed and diluted and dispensed with a TWIST~n FILL (tm) Chemical Dispenser, respiratory protection is not required. Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contamination of food. RECOMMENDED STORAGE: Store away from areas where product may come into contact with food or pharmaceuticals. Do not store containers on their sides. Keep container closed when not in use. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. Keep away from heat, sparks, open flame, and other sources of ignition. Combustible liquid and vapor. OTHER PRECAUTIONARY INFORMATION: This product is not intended to be used without prior dilution as specified on the product label. Avoid creasing or impacting container side walls. HMIS HAZARD RATINGS: HEALTH: 3 FLAMMABILITY: 2 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7.) EXPOSURE LIMITS INGREDIENT --------------- - - VALUE UNIT TYPE AUTH SKIN* - -- ------------------ WATER ................................ --------- NONE -------- NONE --------- NONE ------------- NONE BENZYL-C12-16-ALKYLDIMETHYL AMMONIUM CHLORIDES ................. NONE NONE NONE NONE OCTYLDECYLDIMETHYLAMMONIUM CHLORIDE ........................... NONE NONE NONE NONE BRANCHED-NONYLPHENOL, ETHOXYLATE..... NONE NONE NONE NONE ETHYL ALCOHOL ........................ 1000 PPM TWA ACGIH ETHYL ALCOHOL ........................ 1000 PPM TWA OSHA Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately c• MSDS: 3M .Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product~No. 5, Twist ~n Fill (tm) System) December 03, 2001 PAGE 6 EXPOSURE LIMITS (continued) INGREDIENT VALUE UNIT - TYPE AUTH SKIN* -------- ----------------------------- --------------------------- DIDECYLDIMETHYLAMMONIUM CHLORIDE..... NONE NONE ------------ NONE NONE TETRASODIUM ETHYLENEDIAMINETETRAACETATE........ NONE NONE NONE NONE DIOCTYL DIMETHYL AMMONIUM CHLORIDE... NONE NONE NONE NONE SODIUM METASILICATE .................. NONE NONE NONE NONE * SKIN NOTATION: Listed substances indicated with 'Y~ under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - OSHA: Occupational Safety and Health Administration - NONE: None Established --------------------------------------------------------- 8. HEALTH HAZARD DATA --------------------------------------------------------- -------------------- -------------------- EYE CONTACT: Chemical Related Eye Burns (chemical corrosivity): signs/symptoms can include cloudy appearance of the cornea, chemical burns, pain, tearing, ulcers, impaired vision or loss of vision. SKIN CONTACT: Skin.Burns (chemical corrosivity): signs/symptoms can include redness, swelling, itching, pain, blistering, ulceration, sloughing, and scar formation. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction time, slurred speech, giddiness and unconsciousness. Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Prolonged or repeated exposure may cause: Lung Damage: signs/symptoms can include coughing, difficulty breathing, wheezing, tightness in chest, congestion, and coughing up of blood. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 7 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- IF SWALLOWED: Harmful or fatal if swallowed. Damage to Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, nausea, abdominal tenderness, burns of mouth, difficulty swallowing, blood in vomitus, blood in feces, and ulceration. REPRODUCTIVE/DEVELOPMENTAL TOXINS: WARNING: This product contains ethanol. Ethanol is listed under Proposition 65 as a reproductive hazard through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. Ethanol in alcoholic beverages can cause birth defects or other reproductive harm. OTHER HEALTH HAZARD INFORMATION: Note: This product contains ethanol. In IARC published Monograph No. 44, entitled, "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this product. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- HEALTH HAZARD DATA SECTION CHANGED SINCE July 16, 2001 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M Brand QUAT DISINFECTANT CLEANER CONCENTRATE (Product No. 5, Twist 'n Fill (tm) System) December 03, 2001 PAGE 8 The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. o'~/_~~ 3;`I MATERIAL SAFETY DATA SHEET 3M(TMj BATIIROO~l DISINFECTANT CLEANER (CONCENTRATE) (Product Na. 4, Twist 'nFit[(tmjSvstem) t!2l17/20U1i L1T~i~, j ~~ ~~ , ~' :~'laterial Safety Data Sheet Copyright, 2UU6, 3M Company. All rights reserved. Copying andior downloading of this information for the purpose of properly utilizing 3M products is allowed provided that; { I }the information is copied in ftr[l with no changes unless prior written agreement is obtained from 3M, and (2) neither the ciipy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. `s~c~oN ~. ~'R(JDI.ICT AND Ct)~~~At~'Z' IDE~~"I'LFICATIC)l~' -. _ _ .;_ _ _ _ P. RODUCT NAME: 3M(TM} BATHROOM DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, Twist 'n Fill(tm} System) MANUFACTURER: 3141 DIVISION: Commercial Care Division AllDRESS: 3M Center St. Paul, MN X5144-1000 EMERGENCY PHONE: 1.-8U0-364-35 77 or (651 j 737-6501 (24 hours) Issue Date: 02' l 7/2006 Supersedes Date: 07/21/20U5 Document Group: OG-1683-9 Product Use: Specific Use: IV1ild acid cleaner removes soap scum and scale from bathroom surfaces including plastic, porcelain, ceramic, fiberglass, floors anal fixtures. SECTIt?N 2: Y;~3~GRELIIENT'S' Ini:redient C.A.S. No. 1-OCTYL-2-I'YRROI,IDINONE 2687-94-7 HYDROXYACE'fIC ACID 79-14-1 WATER 7732-! 8-5 1viALIC ACID 6915-15-7 FRAGRANCE Trade Secret BENZYL-C12-1.6-ALKYLDIMF,THYI. AMMONit;ivf CHI.OR.IDES 68424-85-1 G"CHYL ALCOHOL G4-17-5 OCTYLDBC,I'LDIMETHYLA,'vtiVlOl~ttU;~i CHLORIDE 32426-11-2 D1DF.CYI. DIYtETHYL A:~4MUtitUM CHLORIDE 71?3-51-5 DIUCTYL DI'v1ETt"IYI. AMMONICIIvI CHLORIDE SS38A4-3 METHOXYAC'ETIC ACID 62S-4S-6 N-NlT1t.OSOD[4tETHYi_AJviiNE 62-75-9 %bvWr 10 - 30 10 - 30 I0. 30 10 - 30 <3 2.UU O,S - 1.S 1.50 0.90 0.60 0. I - 1 < U.OS ~ 5EC'TI(JN 3: H:~Z~-RD5 IllE1~'I'IFIC~,TT~O~T 3.1 EMERGF,NCY OVERVIEVY CleanSource 227025 Page i of 9 3M1t M1IATERIAL SAFETY BATA SHEET 3A1.{TAT) BATHROO;Vt DtSttV;F'ECTANT Cl,EA!VER (COiV~:ENTRATE) (Product tio. 4, Twist 'n Fill{tm) System} 02/17/2006 Specific Physical i~orm: Liquid Odor, Color, Grade: Green color with floral fragrance. General Physical Form: Liquid immediate health, physical, and environmental hazards: May cause chemical eye burns. May cause allergic skin reaction. May cause chemical skin burns. May cause chemical gastrointestinal burns. Contains a chemical or chemicals which can cause cancer. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. 3.2 POTENTIAL, HEAL7`N EFFECTS Eve Contact: Corrosive {Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical bums, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Skin Contact: Corrosive (Skin. Bums): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Allergic Skin Reaction (non-photo induced): SignsJsyrnptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signsisymptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Corrosion: Signsisymptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. May be absorbed following ingestion and cause target organ effects. "t"arget Organ Effects: Central Nervous System {CNSj Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, sltuTed speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause: Liver Effects: Sigttsisymptoms may include loss of appetite,, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Kidneyr'"E3ladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen {BL~N}, blood in urine, and painful urination. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. CleanSource 227025 Page 2 of 9 311 ~-IATERIAL SAFETY DATA SH.E:ET 3R7(T~7) t3ATt1R(]biVi DISINFECTANT CLEANER (CONCENTRATE) (Product No. 4, i Twist 'n Fitl(tm) System) U2/17/20tt6 NOTE: This product contains ethanol. In TARC published Monograph No. 44, entitled. "Alcohol Drinking", the carcinogenicity of ethanol was determined based on chronic exposure to ethanol through human consumption of alcoholic beverages. This is not an expected effect during the foreseeable use of this prodtict. ln~redient C.A.S. No. Class Description Re};alation E"rHYL ALCOHOL in-17-~ Group I lntemational Agency for Research on Cancer ?~-NITROSf)Dl;IgETHYLAM[NE 62-?j-9 Group 2A lnternational Agency for Research on Cancer N-NITROSOI)iMETHYLAMINE b2-?5-9 Anticipated human carcinogen i~iational Toxicology Progrmt Carcinogens iv-NrrROSODL~vtET}tYLAMt?~;E (i2-?S-9 Canner hazard OSHA Carcinogens 3.3 POTENTIAL ENVIRONMENTAL EFFECTS A 3M Product Environmental Data Sheet (PED) is available. A conservative assessment indicates this product presents a low environmental risk. Components released to the envirottment through use and. disposal are expected to have insignificant environmental impacts. ~ECTI©z1.-~: ~'~~~' t~YD ~1''IEi~1S.URES-._..~__-- ----- --~-- __ 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumptionYhat appropriate personal and industrial hygiene practices are fol}owed. Eye Contact: Lmmediately flush eyes with large amounts of water for at least 15 minutes. Get i.mtnediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin. with large amounts of water for at least l~ minutes. Get immediate medical attention_ Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs(symptoms develop, get medical attention. if Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. 4.2 NOTE TO PHYSICIANS Measures against circulatory shock, respiratory depression, and convulsion may be needed. Probable mucosal damage may contraindicate the use of gastric lavage. SEC`T'ION S: FIRE.E[C~ITINC;' ~1EA,S'tIRES ~_ 5.1 FLAM.MASLE PROI'ER7'TES Flash Point Nn/,4pplicable OSH;1 Flammability Classification: I~TOt Applicable 5.2 EXTINt;UISIIING MEDIA CleanSource 227025 Page 3 of 9 3n1 11ATERIAL SAFETY' 17:1TA SHEET 3~1('fA9} BATHROOM I)ISINFEC'TANT CLEANER. (CQNCENTRATE) (Product No. A, Twist 'n Fill(tm) Svstem) 02/t9l2006 Material will not burn. 5.3 PROTEC"PION OF FIRE FIGHTERS Special Fire Fighting Procedures: Nonflammable. Unusual Fire and Explosion Hazards: Material will nat bum. T ... - -- -___._-__ -~..-- SECTiC)?V >~: ~.~~~~' ~T~L REL.E~,SE'3V~~ASURES Accidental Release Aleasures: Refer to other sections of this MSDS for information retarding physical and health hazards, respiratory protection. ventilation, and personal protective equipment. Call 3M-IlELPS line (i-800-364377} for more information on handling and managing the spill., )~vacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. For large spills, if necessary, get assistance from professional spill clean up team. Par small spills, carefully cover the spill with soda ash (sodium carbanatej or sodium bicarbonate. Work from around the perimeter inward. Avoid splashing.' Add enough water to ease mixing and stir. Continue stirring and adding water and neutralizing agent until the reaction stops. Let cool before collecting. Or use a commercially available 'Acid spill' clean-up kit. Fotiow the kit directions exactly, as specified. Working from around th.e edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sutticient absorbent until it appears dry. Remember, adding an absorbent material does nat remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Clean up residue with a dilute solution (approximately 1 to 5%) of soda ash (sodium carbanatej or baking soda (sodium bicarbonate) in water. Collett the resulting residue containing solution. Place in a metal container approved for use-n transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal r ulations. ___ _ _ - ___ _ mm T SEC1`iON 7: I3?~'VDLiN~C; ,~~~ STQR~G~ - ~ °~~ 7.1 HANDLING Keep out of the reach of children. This product is not intended to be used without prior dilution as specified on the produce label. Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Do not eat, drink or smoke when using this product. Wash exposed. areas thoroughly with soap and water. Do not use on marble. 7.2 STnRaGE Do nat store containers on their sides. Store away from areas where product may come into contact with fond or pharmaceuticals. Store away from strong bases. SEC'I`iC3~~ S: EXP(~SI1R~ ~U~'~T'i`R()LS%P~RSO?`v ~I, PRQTECTO~ti y ~ _- -__ y S.1 ENGINEERII\'G CONTROLS i}se in awell-ventilated. area. NOTE: Vl'hen used as directed and diluted and dispensed with a TWIST 'n PILL(TMj Chemical Dispenser, special ventilation is not required. $.Z PERSONAL PROTECTIVE EQUIPiVIENT (PPE} 8.2.1 EVelFace Protection .Avaid eye contact with vapors, mists, or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) CleanSource 227025 Page 4 of 9 3iV1 M.AT.Ei2IAL SAFETY DATA SHEET 3M(TM) BAT}11200;•9 DISINFECTA.N7' CLEANER {CO\CENTRATE) (Product No. 4, Twist 'n Fill(tm) System) ozn~tzoob Chemical Dispenser. eye contact with the concentrate is not expected to occur. if the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is recommended: Indirect Vented Goggles, Full Face Shield. 8.2.2 Skin Protection Avoid skin contact. NOTE: When used as directed and diluted and dispensed with a TWIST'n FI:LL(TM) Chemical Dispenser, skin contact ~+-ith the concentrate is not expected to occur. Tf the product is not used with the Twist'n Fill system or if there is an accidental release, select and use gloves and/or protective clothing to prevent skin contact based on the results oI' an exposure assessment. Consult with your glove and~`or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material is recommended: Butyl Rubber, Nitrile. 8.2.3 Resp'trator-,y Protection Avoid breathing of vapors, mists or spray. NOTE: When used as directed and diluted and dispensed with a T1~4'1ST'n FILL(TM) Chemical Dispenser, respiratory protection is not required. II'the prod.uet is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following N10SH approved respirators based on airborne concentration of contaminants and in accordance with OSIi.A regulations: Fullface air- purifying respirator with organic vapor; acid gas cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Vb'ash exposed areas thoroughly with soap and water. 83 EXPOSURE GLIDELINES Ingredient Authority Tyae Limit Additional information ETHYL ALCOHOL ACGIH TWA 1000 ppm Table A4 ETHYL ALC:ONOL USHA TWA 1000 ppm Table 7-1 tIY"DROXYAC.ETTC ACID CMRG TWA 10 mg,'mi N-NITROSOUIMEI'IiYLAlV1INE ACGI]-i T'R'A No exposure No Exposure Should be Allowed; Skin Notation*;Table A3 ' Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorpiion_ SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CN1RG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) . "SEC'I'~Oi1T ~: ~'~TYSICAi. ~N>73 CHE?VLICAL FR~PERT'IES Specific Fhysical Form: Odor, Color, Grade: General Physical Form: Flash Point Boiling point Liquid Green color with floral tiagrance. Liquid Not ApplicobCe >95"F CleanSource 227025 Page ~ of 9 3i~~i DtATE12IAL SAFETY DATA SHEET 3M(Tbt) BATTIROOM DISINFEC:TA~JT CLEANER (COtVCEiVTRATE) {Product No. 4, Twist'n Fitt{tm) System) 0?l17i2006 Vapor Pressure Specific Gravity pH Solubility in V1'ater Hazardous Air Pollutants Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Viscosity t ~ psia - 40 psia [rid 131 "FJ Approximately 1.12 [ReJ:Std: WATER=1] Approximately 0.9 - 1.~ Complete ~Yi~ Data Available. l °:u - 5 °io [Test .Method: calculated per GARB title 2] A4> Duia Available 12.18 g/1 - 62.88 grl [Test Method: calculated per GARB title 2] Approximately I00 centipoise Stability: Stable. Materials and Conditions to Avoid: Strong bases Additional Information: DO NOT C,;SF.. ON MARBLE OR MARBLE PRODUCTS. Hazardous Polymerisation: Hazardous polymerization will not occur. Hazardous Decomposition: Under recommended usage conditions, hazardous decomposiiion products are not expected. Hazardous decomposition products may occur as a result of oxidation, heating, or reaction with another material. SECTIC}~T l.l: TQ~:ICOL4G~CAL INFORMATIO~_' ~---___-- -__ Please contact the address listed on the first page of the MSDS for Toxicoloarical Information on this material andror its -~----- --~---Y-< -- ---- _ - -------- { _S~CT~4~' 12 I?C~JLOGiC~I; I}YF4~,~11.=~'I`~t)lti _ ECOTOXICOLOGICAL INFORMATION A 3M Product .Environmental Data Sheet (PED} is available. ?trot determined. CHEMICAL FATE INFORMATION A 3M Product Environmental Data Sheet (PEDj is available. I~TOt determined. T^--_ _ _ _ _ _ _ _ ----- - --, CleanSource 227025 Page b or 9 3;VI M1IATERIAL SAFETY DATA SttEET 3i\1(TIt1) BAT1IR00!\I DISINFECTANT CLE;\1VEti (CONCENTRATE) (Product No. ~t, Twist'n Fi11 trnl Svstem 02/172006 Waste Disposal Method: Dispose of waste product in a permitted hazardous waste facility. EPA Hazardous Waste Number (RCR:\): D002 (Corrosive} Since regulations vary, consult applicable regulations or authorities before disposal. SECTLQ~T 14.TNSP(~RT ~1~1Ff~~A,TION. j ID Number UPC 1D Number UPC 70-0701-2685-3 00-48011-19154-1 70-0705-2686-I 00-48011-19155-8 70-0705-4315-5 00-48011-19204-3 70-0705-43IG-3 00-48011-19205-0 70-0705-4904-G 00-48011-19308-8 70-0705-8964-6 00-48011-19967-7 70-0707-1409-5 00-480I1-20797$ 7U-0708-3905-8 00-48011-23903-8 70-0708-3992-6 00-48011-I9204-3 70-0709-9000-0 UO-4801}-29GI5-4 70-0710-0961-0 00-48011-23903-8 70-0711-6337-5 00-480}1-34887-7 70-0711-9216-8 00-48011-19204-3 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. f`sFCT~oti is: RE+~~t,A~ro~~ ~~~oR~~.~rio~ __.~: US FEDERAL .REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Trttmediate Hazard -Yes Delayed Hazard -Yes STATE REGULATIONS CALIFORNIA PROPOSITION 65 lneredient C.A.S. No. Classification N-NITROSODI;vfETHYLA:r1INE 62-75-9 **C'arcinogen *'~ W ARN1NCi: contains a chemical which can cause cancer. CHEM1~IICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of"Existing Chemica! Substances (EIIVBCS}, or are exempt polymers whose monomers are listed on EINECS_ CleanSource 227025 Page 7 of 9 3M lt1ATERIAL SAFETl` DATA SIf.F.ET 3n4(Tl~f) BATll.lt00:~7 D[STRFEC7 :aRT CLEARER (CONCER'TRATE) (Product No. 4, Twist 'n Fill(tm} System} 021t7/2006 The components of this material are in compliance with the new chemical notification requirements for the Korean Existing Chemicals Inventory. The components of this product are listed on the Australian Inventory of Chemical Substances. All the components ot'this product are listed on China's inventory of Chemical Substances. The components of this product are listed on the Canadian Domestic Substances List. IN'CERNATIONAL REGULATIONS This MSDS has been re ared to meet the U.S. OSHA 1Eiazard Communication Standard, 29 CFR 191.0.] 200. -- -----------x--------------, S~CT'TOti ~,~ O7~H~R ~'~~3~ORMATIUN - NFPA Hazard Classification Health: 3 Flammability: 0 Reactivity; U Special Hazards: None AcidlBase: Acid Corrosive: Yes National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significvrt quantities. HM1S Hazard Classification Health: 3 Flammability: 0 Reactivity: 0 Protection: X -See PPE section- Hazardous Material Identification System (HMIS<~) hazard ratings are desigmed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of nomuzl use and are not intended for use in emergency situations. HMIS~~ ratings are to be used with a fully implemented. HM1.SG program. HMIS~~ is a registered mark of the National Paini and Coatings Association (NPCA.). ...................................................................................................................... Revision Changes: Sectian l: Product use infonttation was modified. Copyright was modified. Section 6; Release measures information was modified. Section 7: Storage information was modified. Section (i: Engineering controls i.nfonnatian was modified. Section 13: ~~raste disposal method information was modified. Section 3: Carcinogenicity phrase wac modified. Section 2: Ingredient table was modified. Section 3: Other health effects infonmation was modified. Section 9: Property description for optional properties was moditied. DISCLAIMER: The information in this Material Safety Data Sheet (1ViSDS) is believed to be correct as of the date issued. 3M MAKF.,S NO WARRANTIES, EXPRESSED OR IMPLIED, INCLL'D1NCi, BUT NOT L.Ilv11TED TU, A.NY IMPLIED WARRANTY CleanSource 227025 Page 8 of 9 311 MATERIAL SAFETY DATA SHEET 3di(TM) BATHROOM DISINFECTANT CLEANER (CONCEN'I'RATE) (Product No. 4, Twist 'n Fill{tm) Svstem) 02/1712l1t)6 ~F MERCHANTAI31LlT1' OR FITNESS FOR A PARTICULAR PURPOSE ©R COURSF. OP pERFQRMAN~:E OR USAGE OF TRADE. User is responsible for deterrnininf; whether the 3M product is fit for a particular purpose and suitable for user's method of tie or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely wuhin the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether if is fit for a particular purpose and suitable for user's method of use or application. 3~M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic: transfer may bane resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. hr addition, information obtained from a database may not be as current as the information i.n the MSDS available duectly tiom 3119. 3M MSDSs are available at www.3i1~1.com CleanSource 227025 Yabe 9 of 9 ±.~ _ [ Clsrc # 22707_5 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) BONNET CLEANER (CONCENTRATE) (Product No. 11, Twist'n Fill tm S stem 06/06/2003 '~ ' ~ _ LSC.~ 8/N ~ Material Safety Data Sheet ~S~r~Er~s Copyright, 2003, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. -- SECTION l : PRODUCT AND COMPANh IDEN'TIrICAT10N PRODUCT NAME: SCOTCHGARD(TM) BONNET CLEANER (CONCENTRATE) (Product No. 11, Twist 'n Fill(tm) System) MANUFACTURER: 3M DIVISION: Commercial Care Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 06/06/2003 Supercedes Date: 08/17/2001 Document Group: 09-2557-8 Product Use: Specific Use: Carpet cleaning `SECTION 2: INGREDIENTS Insredient WATER 1-PROPOXY-2-PROPANOL STYRENE MALEIC ANHYDRIDE COPOLYMER, AMMONIUM SALT SODIUM DODECYLBENZENE SULFONATE SODIUM DECYL SULFATE C.A.S. No. % by Wt 7732-18-5 60- 100 1569-01-3 3 - 7 143496-13-3 1- 5 25155-30-0 0.1 - 1.5 142-87-0 0.1 - 1 SECTION 3: HAZARDS IDENTIFICATIOlti 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear, colorless to light amber color. General Physical Form: Liquid Immediate health, physical, and environmental hazards: Pleasant fragrance. Combustible liquid and vapor. May cause target organ effects. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. 1 of 6 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) BONNET CLEANER (CONCENTRATE) (Product No. 11, Twist'n Fill tm S stem 06/06/2003 May be absorbed through skin and cause target organ effects. Inhalation: Single exposure, above recommended guidelines, may cause: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. Target Organ Effects: Single exposure, above recommended guidelines, may cause: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. 3.3 POTENTIAL ENVIRONMENTAL EFFECTS A 3M Product Environmental Data Sheet (PED) is available. A conservative assessment of this product indicates that its use and proper disposal are likely to present a low environmental risk. Potential use and misuse are unlikely to cause components to enter the environment in quantities or by routes that could cause adverse environmental impacts. SECTION 4: FIRST AID .MEASURES __~ 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get medical attention. Skin Contact: Immediately flush skin with large amounts of water. If signs/symptoms develop, get medical attention. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point Approximately 148 °F [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available OSHA Flammability Classification: Class IIIA Combustible Liquid 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for 2of6 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) BONNET CLEANER (CONCENTRATE) (Product No. 11, Twist'n Fill tm S stem 06/06/2003 exposed areas of the head. Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES , Accidental Release Measures: Observe precautions from other sections. Ca113M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. - --, SECTION 7: HANDLING AND STORAGE 7.1 HANDLING This product is not intended to be used without prior dilution as specified on the product label. Avoid eye contact with vapors, mists, or spray. Avoid skin contact. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Avoid contact with oxidizing agents. Keep out of the reach of children. 7.2 STORAGE Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. SECTION 8: -EXPOSURE CONTROLS/PERSONAL PROTFCTIO _' _ _ 8.1 ENGINEERING CONTROLS NOTE: When used as dn•ected and diluted and dispensed with a TWIST'n FII.L(TM) Chemical Dispenser, special ventilation is not required. Use in awell-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL(TM) Chemical Dispenser, eye contact with the concentrate is not expected to occur. Avoid eye contact with vapors, mists, or spray. The following'eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FILL(TM) Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Nitrile Rubber, Polyvinyl Chloride. 8.2.3 Respiratory Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FiLL(TM) Chemical Dispenser, respiratory protection is not required.. Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 3of6 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) BONNET CLEANER (CONCENTRATE) (Product No. 11, Twist'n Fill tm S stem 06/06/2003 8.2.4 Prevention of Swallowing Do not ingest. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES None Established - -- - - ~SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point Density Vapor Density Vapor Pressure Specific Gravity pH Melting point Solubility in Water Evaporation rate Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Viscosity Liquid Clear, colorless to light amber color. Pleasant fragrance. Liquid No Data Available Approximately 148 °F [Test Method: Tagliabue Closed Cup] No Data Available No Data Available Approximately 212 °F 1.01 g/cm3 [Ref Std: WATER=1] No Data Available No Data Available Approximately 1.01 [RejStd.• WATER=1] 8-9 Not Applicable Complete Approximately 1 [Ref Std: WATER=1] 3 - 7 % [Test Method: calculated per CARB title 2] 63-100% 640 - 670 g/1 [Test Method: calculated per GARB title 2] < 100 centipoise SECTION 10: STABILITY AND REACTIVITI' Stability: Stable. Materials and Conditions to Avoid: Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Hydrogen Sulfide Oxides of Sulfur Condition During Combustion During Combustion During Combustion During Combustion - _ _ ---- SE'('1'ION lI TO~:ICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its SECTION 12: ECOLOC:ICALINFORII.~"PION 4of6 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) BONNET CLEANER (CONCENTRATE) (Product No. 11, Twist'n Fill tm S stem 06/06/2003 ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS _ -~ Waste Disposal Method: Discharge spent solutions and small quantities (less than 5 gal.(19 L)) to a wastewater treatment system. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since re ulations var consult a licable re ulations or authorities before dis osal. --- - SECTION 14:TRANSPORT INFORMATION H) Number UPC ID Number UPC 70-0708-4011-4 00-48011-25981-4 70-0709-6203-3 00-48011-25981-4 70-0709-6204-1 00-48011-25982-1 70-0710-0971-9 00-48011-25982-1 70-0711-6304-5 00-48011-25981-4 70-0711-6305-2 00-48011-25982-1 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 1 ~: lll{,GULATORY INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard -Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard -Yes Delayed Hazard - No CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. This MSDS has been re ared to meet the U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200. __ _ _- i-SECTION 16: OTHER 1NFORMATION - -__ __ _-- -J NFPA Hazard Classification Health: 2 Flammability: 2 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazazd ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 2 Reactivity: 0 Protection: X -See PPE section. Hazazdous Material Identification System (HMIS(r)) hazazd ratings are designed to inform employees of chemical hazazds in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA). DISCLAIlI~R: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY Sof6 r -~ s 3M MATERIAL SAFETY DATA SHEET SCOTCHGARD(TM) BONNET CLEANER (CONCENTRATE) (Product No. 11, Twist'n Fill tm S stem 06/06/2003 OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com 6of6 ;T. T Clsr_c_# 22.7.0.85 3M MATERIAL SAFETY DATA SHEET 3MTMDEODORIZER -COUNTRY DAY SCENT -CONCENTRATE (Product No. 12, Twist 'n FiIIT^'Svsteml 08/12/2002 :E ~- Material Safety Data Sheet ~~ ~~ Lt 1 ~~5 Copyright, 2002, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. -- - -- __ SECTIOlS' 1: PRODUCT AND COMPANI' 1DENrh1RIC'A"TION PRODUCT NAME: 3MTMDEODORIZER -COUNTRY DAY SCENT -CONCENTRATE (Product No. 12, Twist 'n FiI1TMSystem) MANUFACTURER: 3M DIVISION: Commercial Care Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 24 hours Issue Date: 08/12/2002 Supercedes Date: 08/01/2002 Document Group: 06-8477-9 Product Use: Specific Use: DEODORIZER ---_--- SECTION 2: 1 NGREDIENTS Ingredient POLYALKOXY ALCOHOLS FRAGRANCE 5312 (NJTSN 004499600-6516) WATER SORBITAN POLYETHOXY MONOLAURATE 1-METHOXY-2-PROPANOL C.A.S. No. % by Wt 69013-18-9 30 - 60 Trade Secret 10 - 30 7732-18-5 10- 30 9005-64-5 7- 13 107-98-2 3 - 7 SECTIOn 3: HAZARDS IDEN1'1FICATION J. 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Clear; dark red color; strong floral fragrance General Physical Form: Liquid Immediate health, physical, and environmental hazards: 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: _ May Cause Allergic Skin Reaction: Signs/symptoms may include redness, swelling, blistering, and itching. 1 of 5 3M MATERIAL SAFETY DATA SHEET 3MTMDEODORIZER -COUNTRY DAY SCENT -CONCENTRATE (Product No. 12, Twist 'n Fil1T"'S stem 08/12/2002 Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Single exposure may cause: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. SECTION ~: I{:IRST AlD 1YlEAS~UI2ES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. Get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get immediate medical attention. -- _-- - - SECTION~S: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >= 212 °F [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available OSHA Flammability Classification: Class IIIB Combustible Liquid 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL;,IZELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Ventilate the area with fresh air. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue. Place in a closed container 2of5 3M MATERIAL SAFETY DATA SHEET 3MT"iDEODORIZER -COUNTRY DAY SCENT -CONCENTRATE (Product No. 12, Twist 'n Fi11T"'S stem 08/12/2002 approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. j ~ECTIOi~,T 7: HANllLING ANI) STORAGE 7.1 HANDLING This product is not intended to be used without prior dilution as specified on the product label. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contact with oxidizing agents. Keep container closed when not in use. Keep out of the reach of children. 7.2 STORAGE Store away from oxidizing agents. Keep container in well-ventilated area. ,.SECTION 8: E\POSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS NOTE: When used as directed and diluted and dispensed with a TWIST'n FILLT"'Chemical Dispenser, special ventilation is not required. Use in awell-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. NOTE: When used as directed and diluted and dispensed with a TWIST'n FILLT"'Chemical Dispenser, eye contact with the concentrate is not expected to occur. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n.FILLT'"Chemical Dispenser, skin contact with the concentrate is not expected to occur. Avoid skin contact. 8.2.3 Respiratory Protection NOTE: When used as directed and diluted and dispensed with a TWIST'n FILLT"'Chemical Dispenser, respiratory protection is not required. Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. Avoid breathing of vapors, mists or spray. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES None Established - --- ___ SECTION 9: PHYSICAL,AND CHEMICAL PROPERTIES Specific Physical Form: Odor, Color, Grade: General Physical Form: Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point Density Vapor Density Liquid Clear; dark red color; strong floral fragrance Liquid No Data Available >= 212 °F [Test Method: Tagliabue Closed Cup] No Data Available No Data Available Approximately 212 °F No Data Available No Data Available 3of5 3M MATERIAL SAFETY DATA SHEET 3MT"+DEODORIZER -COUNTRY DAY SCENT -CONCENTRATE (Product No. 12, Twist 'n Fi11T"'Svsteml 08/12/2002 Vapor Pressure Specific Gravity pH Melting point Solubility in Water Evaporation rate Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Viscosity No Data Available Approximately 1 [Ref Std.• WATER=1] Approximately 7.55 Not Applicable Complete No Data Available 13 - 37 % [Test Method: calculated per CARB title 2] 23-67% 13 - 37 % [Test Method. calculated per CARB title 2] <=100 centipoise SEC'T'ION 10: S`I'ABL11'Y AND REACTI~'I'1,1' Stability: Stable. Materials and Conditions to Avoid: Strong oxidizing agents Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Carbon monoxide Carbon dioxide Irritant Vapors or Gases Condition During Combustion During Combustion During Combustion - - - -- .SECTION 11: TOXICOLOGICAL INFORIVIAT,IUN Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its com onents. SECTION 12: ECOLOGICAL INFOR~VIATION ECOTOXICOLOGICAL INFORMATION Not Determined CHEMICAL FATE INFORMATION Not Determined SECTION 1 ~: DISPOS ~L CONSIDERATIONS Waste Disposal Method: Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since re ulations va consult a licable re ulations or authorities before dis osal. -- SEC1'ION 14:TRANSPORT INFORMATION ~, ID Number UPC ID Number UPC 70-0708-4012-2 00-48011-20119-6 70-0710-0972-7 00-48011-23895-6 4of5 A: r 3M MATERIAL SAFETY DATA SHEET 3MT"iDEODORIZER -COUNTRY DAY SCENT -CONCENTRATE (Product No, 12, Twist 'n FiIIT"'S stem 08/12/Z002 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECT01'v 15: REGULATORY INFORMATION. _ _ _ _ _ _ _ _ ~~, US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard -Yes Delayed Hazard -Yes CHEMICAL INVENTORIES All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. The components of this product are in compliance with the chemical notification requirements of TSCA. This MSDS has been re ared to meet the U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200. :SECTION :I6: O"I'H ER_liti FORib1ATI0'.~' NFPA Hazard Classification Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association Hazazd Codes are designed for use by firefighters, sheriffs, or other emergency response teams who aze concerned with the hazards of burning or exploding materials. These NFPA codes aze not intended to address the hazards of this product other than in afire situation. HMIS Hazard Classification Health: 2 Flammability: 1 Reactivity: 0 Protection: X -See PPE section. HMIS codes are intended for use in everyday workplace settings to provide a rapid indication of the occupational hazards associated with chemicals used in the workplace. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com SofS 4R Clsrc # 226120 MATERIAL SAFETY 3M DATA SHEET 3M Center St. Paul, Minnesota 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Copyright, 1998, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. 70-0708-3555-1 00-48011-23760-2 70-0708-3556-9 00-48011-23761-4 70-0708-3557-7 00-48011-23762-1 ISSUED: October 13, 1998 SUPERSEDES: May 07, 1998 DOCUMENT: 08-5787-0 TRADE NAME: 3M BRAND TOPLINE(TM) FLOOR COATING ID NUMBER/U.P.C.: DIVISION: COMMERCIAL CARE DIVISION v_c~~_o~/.~ C-~ /_oa%~g~ ~ 35 G,~. ----------------------------------------- 1. INGREDIENT ----------------------------------------- ------------- C.A.S. NO. ------------- ------ ------ ----------------- PERCENT ----------------- WATER ................................... 7732-18-5 60 - 90 STYRENE-ACRYLONITRILE POLYMER........... 9003-54-7 10 - 30 DIETHYLENE GLYCOL MONOMETHYL ETHER...... 111-77-3 5 - 10 TRI(BUTOXYETHYL) PHOSPHATE .............. 78-51-3 1 - 5 ZINC AMMONIA CARBONATE COMPLEX.......... 38714-47-5 1 - 5 MALEIC ANHYDRIDE-PROPYLENE POLYMER...... 25722-45-6 0.5 - 1.5 DIBUTYL PHTHALATE ....................... 84-74-2 0.1 - 1.0 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24 HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH THIS PRODUCT. The components of this product are in compliance with the chemical notification requirements of TSCA. This product contains the following toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Emergency Planning and Community Right-TO-Know Act of 1986 and 40 CFR Part 372: DIETHYLENE GLYCOL MONOMETHYL ETHER TRI(BUTOXYETHYL) PHOSPHATE ZINC AMMONIA CARBONATE COMPLEX DIBUTYL PHTHALATE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND TOPLINE(TM) FLOOR COATING October 13, 1998 PAGE 2 ----------------------------------------------------------------------------- 2. PHYSICAL DATA BOILING POINT :................. ca. 212 F VAPOR PRESSURE:................ N/D VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY :.............. ca. 1.0 Water=l PERCENT VOLATILE :.............. ca. 73 °s pH :............................ 8 - 9 VISCOSITY :..................... < 10 centipoise MELTING POINT :................. N/A APPEARANCE AND ODOR: Liquid, opaque white, mild ammonia odor. ----------------------------------------------------------------------------- 3. FIRE AND EXPLOSION HAZARD DATA ----------------------------------------------------------------------------- FLASH POINT :................... N/A FLAMMABLE LIMITS - LEL:........ N/A FLAMMABLE LIMITS - UEL:........ N/A AUTOIGNITION TEMPERATURE:...... N/D EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, Foam SPECIAL FIRE FIGHTING PROCEDURES: Not applicable UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section for products of combustion. NFPA HAZARD CODES: HEALTH: 0 FIRE: 0 REACTIVITY: 0 UNUSUAL REACTION HAZARD: none ------------------ 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID: Protect from freezing. HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: 3M BRAND TOPLINE(TM) FLOOR COATING October 13, 1998 PAGE 3 ----------------------------------------------------------------------------- 4. REACTIVITY DATA (continued) ----------------------------------------------------------------------------- HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Irritant Vapors or Gases. ----------------------------------------------------------------------------- 5. ENVIRONMENTAL INFORMATION ----------------------------------------------------------------------------- SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled material. Clean up residue with water. Place in a closed container. RECOMMENDED DISPOSAL: Incinerate in an industrial or commercial facility in the presence of a combustible material. ENVIRONMENTAL DATA: Not determined. REGULATORY INFORMATION: Volatile Organic Compounds: ca. 5.5 0. VOC Less H2O & Exempt Solvents: N/D. Since regulations vary, consult applicable regulations or authorities before disposal. In the event of an uncontrolled release of this material, the user should determine if the release qualifies as a reportable quantity. U.S. EPA Hazardous Waste Number = None (Not U.S. EPA Hazardous). TSCA: All components used in the manufacture of this material are in compliance with the U.S. TSCA inventory. EPCRA HAZARD CLASS: FIRE HAZARD: No PRESSURE:~NO REACTIVITY: No ACUTE: Yes CHRONIC: Yes ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID ----------------------------------------------------------------------------- EYE CONTACT: Immediately flush eyes with large amounts of water. Get immediate medical attention. SKIN CONTACT: Flush skin with large amounts of water. If irritation persists, get medical attention. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately r~ MSDS: 3M BRAND TOPLINE(TM) FLOOR COATING October 13, 1998 PAGE 4 ----------------------------------------------------------------------------- 6. SUGGESTED FIRST AID (continued) ----------------------------------------------------------------------------- INHALATION: If signs/symptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION ----------------------------------------------------------------------------- EYE PROTECTION: Avoid eye contact with vapor, spray, or mist. Wear unvented goggles during operations in which exposure is likely: SKIN PROTECTION: Avoid prolonged or repeated skin contact. Wear appropriate gloves when handling this material. A pair of gloves made from the following material(s) are recommended: butyl rubber. RECOMMENDED VENTILATION: Do not use in a confined area or areas with little or no air movement. Use in a well-ventilated area. Use with adequate dilution ventilation. If exhaust ventilation is not adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or spray. Avoid breathing of airborne material. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: half-mask organic vapor respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Wash hands after handling and before eating. RECOMMENDED STORAGE: Store away from areas where product may come into contact with food or pharmaceuticals. Store at temperatures above 32 degrees F (O degrees C). Keep container dry. Keep container closed when not in use. Keep out of the reach of children. FIRE AND EXPLOSION AVOIDANCE: Keep container tightly closed. ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately ~- MSDS: 3M BRAND TOPLINE(TM) FLOOR COATING October 13, 1998 PAGE 5 ----------------------------------------------------------------------------- 7. PRECAUTIONARY INFORMATION (continued) ----------------------------------------------------------------------------- OTHER PRECAUTIONARY INFORMATION: Not intended for consumer sale or use. HMIS HAZARD RATINGS: HEALTH: 0 FLAMMABILITY: 0 REACTIVITY: 0 PERSONAL PROTECTION: X (See precautions, section 7 EXPOSURE LIMITS INGREDIENT VALUE UNIT ----- TYPE --------- AUTH SKIN* ------------- -------------------------------------- WATER ................................ --------- NONE --- NONE NONE NONE STYRENE-ACRYLONITRILE POLYMER........ NONE NONE NONE NONE DIETHYLENE GLYCOL MONOMETHYL ETHER... 30 PPM TWA CMRG TRI(BUTOXYETHYL) PHOSPHATE........... NONE NONE NONE NONE ZINC AMMONIA CARBONATE COMPLEX....... NONE NONE NONE NONE MALEIC ANHYDRIDE-PROPYLENE POLYMER... NONE NONE NONE NONE DIBUTYL PHTHALATE .................... 5 MG/M3 TWA ACGIH DIBUTYL PHTHALATE .................... 5 MG/M3 TWA OSHA * SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: American Conference of Governmental Industrial Hygienists - OSHA: Occupational Safety and Health Administration - CMRG: Chemical Manufacturer Recommended Exposure Guidelines - NONE: None Established 8. HEALTH HAZARD DATA ----------------------------------------------------------------------------- EYE CONTACT: Mild Eye Irritation: signs/symptoms can include redness, swelling, pain, and tearing. SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swelling, and itching. May be absorbed through the skin and produce effects similiar to those caused by inhalation and/or ingestion. INHALATION: Single overexposure, above recommended guidelines, may cause: Central Nervous System Depression: signs/symptoms can include headache, dizziness, drowsiness, incoordination, slowed reaction ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately -, .x MSDS: 3M BRAND TOPLINE(TM) FLOOR COATING October 13, 1998 PAGE 6 ----------------------------------------------------------------------------- 8. HEALTH HAZARD DATA (continued) ----------------------------------------------------------------------------- time, slurred speech, giddiness and unconsciousness. Prolonged or repeated exposure may cause: Irritation (upper respiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. IF SWALLOWED: Ingestion is not a likely route of exposure to this product. Ingestion may cause: Irritation of Gastrointestinal Tissues: signs/symptoms can include pain, vomiting, abdominal tenderness, nausea, blood in vomitus, and blood in feces. REPRODUCTIVE/DEVELOPMENTAL TOXINS: REPRODUCTIVE STUDIES: 1. DIETHYLENE GLYCOL MONOMETHOL ETHER (111-7 7- 3) has been shown to reduce number of viable liters, number of 1 ive pups/liter and number of pups surviving over 1-3 days using an in vivo mouse screening bioassay. Reduced weights and increase in maternal mortality was also noted. 2. TERATOGEN STUDY: Teratogenicity of diethylene glycol monomethyl ether was evaluated in pregnant rabbits dermally exposed at levels of 0, 50, 250, 750 mg/kg/day. In high dose group: decreased maternal weight gain, increased mild fore limb flexure and dilated renal pelvis, increased retrocaval ureter , delayed ossification of sternebrae were seen in rabbit pups. In high to mid-dose groups: delayed ossification of hyoid skull and cervical vertebrae spur were also seen in rabbit pups. 3. Hardin et al. (1986) dosed rats orally on days 7-16 of gestation with 720 a nd 2165 mg/kg. Neither dose was maternally toxic, but rib and heart malformations were increased. DIBUTYL PHTHALATE (84-74-2) is a potential reproductive hazard causing embryotoxic, teratogenic and male reproductive effects by the oral route of exposure in laboratory animals. ----------------------------------------------------------------------------- SECTION CHANGE DATES ----------------------------------------------------------------------------- PRECAUTIONARY INFO. SECTION CHANGED SINCE May 07, 1998 ISSUE ----------------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately . :,- MSDS: 3M BRAND TOPLINE(TM) FLOOR COATING October 13, 1998 PAGE 7 The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. '~;~ -r. (~C1s"rc #/350899 ~ MATERIAL SAFETY DATA SHEET STONEMEDIC® MARBLE P-O-L-ISHING COMPOUND Section I ~~~Tt O/l~ Manufactured for: C('(p_ ,Q 5~~A VIC INTERNATIONAL CORP. Telephone Number for Information: 865/947-2882 231 E. Emory Rd. Emergency Telephone Number: I-800-424-9300 ~~ ~~ Powell, TN 31849 Date Prepared: January, 2002 Section 2 -Hazardous Ingredients/Identity Information Ingredients are protected under the "Trade Secrets" provision of the 29 [FR 1910.1200 subpart 2(i) Section 3 -Physical/chemical Data BOILING POINI: N/A VAPORPRESSURE(mbar} 0 VAPOR DENSIiI((AIR = Ir 0 SOLUBIUTYINWATER: N/A SPKIFICGRAVIiY(H2O=1) 1,65 ~volnnLEBVVOI.uME N/A EVAPORATION RATE (n-butylacetate = I) 0 pppANpOpOR Amber powder; Citrus Section 4 -Fire and Explosion Hazard Data FUISNPOINi(METHODUSEDk None FLAMMABU:UMITS: EXi1NGU15HINGMEDIA: None SPECUlLFlREFIGHTINGPROCEDURES: Self-contained breathing apparatus and protective clothing should be worn in fighting fires . involving chemicals. UNUSUALFlREANDEXPLASN)NHAIARDS: None Section 5 -Health Hazard Data THRESHOU) UMRVAUIE: EFFECROFOVEREXPOSURE Contact with eye may be irritant. Prolonged skin contact may result in toxic effects from skin absorption. EMERGENCVANDFIRSTAIDPROCEDURES: E e contact: Irrigate immediately and thoroughly with water for at least IS minutes and get medical attention of an eye physician. Skin Contact: Flush immediately and thoroughly with water and mild soap. Inhalation: Remove from exposure, treat symptomatically and get medical attention. Ineestion: Seek medical attention immediately, drink water and sodium carbonate. Section 6 -Reactivity Data sTaslllrr: Stable HAIARDOUSPOLYMERIZATION: Will not occur CONDRIONSTOAVOID: N/A CONDR1011STOAVOID: High temperatures INCOMPATIBILITY(rnateriaktoavoi~: Concentrated acids HAIARDOUSDKOMPOSTiTONPRODUCTS: Combustion will produce carbon dioxide ~~ (CONTINUED) Section 7 -Spill or Leak Procedures STONEMEDIC® MARBLE POLISHING COMPOUND Page 2 of 2 SiEPSTOBETAKENINCASEMATERIALISREI.EASEDORSPIt1FD: Spills maybe collected with absorbent material. Neutralize in all cases with sodium carbonate or slaked lime up to pH 6. Dilute with plenty of water. WASfEDISPOSALMETHOD: Dispose of in accordance with Federal, State and Local regulations concerning health and pollution. Section 8 -Special Protection Information RESt1RATORYPROTECiION: User should wear a NIOSH/MBAR approved respirator for potassium oxalate. VENi1tATN)N: LOCALEXHAUSi Provide good ventilation MEt}W~BfAL Use in confined areas SPEOAL Ol}®t PROTECTIVEGL0YE5: Acid resistant rubber EYEPROfECIION: Acid resistant safety glasses must be worn OTHERPROTECIIVEEQUIPMENE Overalls/aprons should be worn Section 9 -Special Precautions PRECAUiIONSTOBETAKENINHANDIINGANDSTORING: Material is a harmful powder. Avoid eye and skin contact. Keep out of reach of children. OTHERPRECAUTIONS: Hazardous product residue may remain after the product has been removed from its container. Do not reuse "empty" container. Avoid contact with metals. As always, keep out of reach of children. Section (0 -Shipping Information Proper Shipping Name:Toxic Solid, Organic, n.o.s. Technical Name: (Contains Potassium Oxalate) Hazard Class: 6.I UN Number: 2811 Packing Group: III Hazard Label: Keep away from food/poison. Emergency Response Guide#: IS4 Depends on mode of transportation. Section II -National Fire Protection Association (NFPA) Ratings Health: I Flammability: O Reactivity:0 Special: Acid The information contained herein is furnished without warranty of any kind. Employers should use this information only as a supple- ment to other information gathered by them and must make independent determinations of suitability and completeness of information from all sources to assure proper use of these materials and the safety and health of employees. ,° ~~ - Page 1 MATERIAL SAFETY DATA SHEET MSDS826 161161 (MSDS) Clsrc # 090147 ITEM NUMBER: 161- CLEAN APPLE AIR FRESHENER 1002 C ~}T~QN f VERSION 3 EFFECTIVE DATE: 01/01/05 SUPERCEDES: 04/22/98 PREPARED BY: Regulatory Compliance ~ ~N Section(s) Revised: HMIS. II. III, IV, V, VI, VII. VIII, 1X CO~ / ~ 3 /~~~~ IDENTITY (As Used On Label and List): CLEAN APPLE AIR FRESHENER 1602 ------------------------------------------------------------------------------------------------------------------------ ~~ G~nS E M E R G E N C Y M E D I C A L Telephone# 1-866-836-8855 (24 Hrs) Outside of the U.S.A. Call 952-852-4646 PRODUCT HAZARD RATINGS (HMIS ): Health = *2. Fire = 4, Reactivity = 0 Protective Equipment m A (Rating Legend: - 4 =Extreme, 3 = Serious, 2 =Moderate, 1 = Slight. 0 = Minimal, * = Chronic Hazard) ------------------------------------------------------------------------------------------------------------------------ *-*-*-*-*-*-*-*-*-*-*-*-* SECTION I -*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-* CLEAN SOURCE/SAN JOSE TELEPHONE NUMBER FOR INFORMATION CALL 24HRS 408-501-3216 D 650 BRENNAN STREET DATE PRINTED 2/14/05 NAME OF PREPARER REGULATORY COMPLIANCE SAN JOSE CA 95131 *-*-*-*-*-*-*-*-*-*-*-*-* SECTION II - HAZARDOUS INGREDIENTS / IDENTITY INFORMATION -*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-* Chemical Names (CAS #) SARA ACGIH OSHA % By Wt. -------------------------------- SEC 313 ---------------------- TLV-TWA/STEL PEL ---------------------------- -TWA/STEL ------------ -------- ---- ------------- Acetone (67-64-1) No 500 ppm/ 750 ppm 1000 ppm/ NE 60- 80 Apple Fragrance (Proprietary) No NE / NE NE / NE 1- 2 Liquefied Petroleum Gas Mixture (68476-86-8) No See below ingredient data 20- 40 Propane (74-98-6) No 1000 ppm/ NE 1000 ppm/ NE (48- 55) n-Butane (106-97-8) No 1000 ppm/ NE NE / NE (45- 49) Isobutane (75-28-5) No 1000 ppm/ NE NE / NE (0:5-2 .0) *-*-*-*-*-*-*-*-*-*-*-*-* SECTION III - PHYSICAL CHARACTERISTICS Boiling Point: NA Vapor Pressure (psig)(± 5 psig): 103 @ 130°F / 53 @ 70°F Specific Gravity -calculated (H2O=1): 0.6952 ± 0.005 pH: NA Solubility/Water: Completely Vapor Density (AIR=1): ND Evaporation Rate (Ether=1): ND Appearance and Odor: Clear, colorless aerosol spray with apple odor. *-*-*-*-*-*-*-*-*-*-*-*-* SECTION IV - FIRE AND EXPLOSION HAZARD DATA _*-*_*_*_*_*_*_*_*_*_*-*_*_*_*_*-*_* Aerosol Flammability: Product is to be labeled as flammable as described in 16 CFR 1500.3 and 1500.45. Flashpoint: <0°F (Propellant): -4°F (Concentrate) Flammable Limits - % Volume In Air (Propellant): LEL: 1.9 UEL: 9.5 Extinguishing Media: Carbon dioxide, water spray, foam. or dry chemical. Special Fire Fighting Procedures: Containers should be cooled with water to prevent vapor pressure build up. Use equipment or shielding. as required, to protect personnel from bursting, rupturing or venting containers. Unusual Fire and Explosion Hazards: Fire fighters and others who may be exposed to the products of Combustion should be equipped with NIOSH-approved positive pressure self-contained breathing apparatus (SCBA) and full protection clothing. At elevated temperatures (over 54C-130F) containers exposed to direct flame or heat contact should be cooled with water to prevent weakening of container structure. SJn Page 2 Continuing SECTION IV - FIRE AND EXPLOSION HAZARD DATA *-*-*-*-*-*-*-*-*-*-*-*-* SECTION V - REACTIVITY DATA CLEAN APPLE AIR FRESHENER 1602 161 161 Stability: Stable Hazardous Polymerization: NA Incompatibility (Materials to Avoid): Oxidizing agents, bases. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Conditions to Avoid: Keep away from heat. sparks, and fames. Dropping of containers may cause bursting. *-*-*-*-*-*-*-*•*-*-*-*-* SECTION VI - HEALTH HAZARD DATA -*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-* Route(s) of Entry: Inhalation: Y Eyes: Y Skin: Y Ingestion: N HAZARDS IDENTIFICATION: EYES: May cause severe irritation. SKIN: Prolonged or repeated contact may dry or defat the skin and lead to inflammation (i.e. dermatitis). INHALATION: Irritating to eyes, nose and respiratory tract. Nausea, vomiting and stomach upset can occur. Under misuse or intentional misuse, product may cause asphyxiation. INGESTION: Exposure by ingestion is unlikely since an. aerosol, but if ingested, the following may occur: May be harmful if swallowed. Possible aspiration hazard - may cause inflammation of the lungs. AGGRAVATED MEDICAL CONDITIONS: May aggravate pre-existing eye, skin. respiratory conditions. TARGET ORGANS AFFECTED: Nervous system. Eyes. Skin. EMERGENCY AND FIRST AID PROCEDURES: EYES: Immediately flush with plenty of water for at least 15 minutes. Get prompt medical attention. SKIN: Wash with soap and plenty of water. INHALATION: Remove to fresh air. If symptoms develop, seek immediate medical attention. If not breathing, give artificial respiration. INGESTION: In the unlikely event of swallowing: Get immediate medical attention. Do NOT induce vomiting unless directed by medical personnel. Rinse mouth with water and give another cupful to drink. Never give anything by mouth to an unconscious person. CARCINOGENICLTY: ACGIH IARC NTP OSHA Acetone A4 No No No TOXICITY INFORMATION: Acetone: After prolonged or repeated exposure, development of cataracts has been reported in laboratory animals. LD50 Oral (Rat): 9750 mg/kg LD50 Dermal (Rabbit): 20.000 mg/kg LC50 Inhalation (Rat): 16.000 ppm/4hr *-*-*-*-*-*-*-*-*-*-*-*-* SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE -*-*-*-*-*-*-*-*-*-*-*-*-*-*_*_*_*_* Releases or Spills: Remove all sources of ignition and ventilate area. Soak up spill with an inert absorbent and place into a designated disposal container. Consult local regulatory agency for proper disposition of material. Waste Disposal Method: Do nct puncture or incinerate containers. When contents are depleted continue to Depress button until all gas is expelled. Dispose of container in accordance with local, state, and federal regulations. Disposal regulations may be different for each state and/or locality. Handling And Storing: Avoid breathing vapor. Keep away from heat, sparks and flame. Use with adequate ventilation. Do not puncture_or incinerate containers. Do not expose to direct sunlight or store at temperatures above 120°F (48.9°C). Store as Level 3 Aerosol (NFPA ?OB). Other Precautions: Please read and follow the directions on the product label; they are your best guide to using this product in the most effective way, and give the necesszry safety precautions to protect your health. ~ ~ __ _ __ _ i - Page 3 Continuing SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE CLEAN APPLE AIR FRESHENER 1602 161 161 *-*-*-*-*-*-*-*-*-*-*-*-* SECTION VIII - EMPLOYEE PROTECTION -*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-*-* Respiratory Protection (Type): None required if good ventilation is maintained. If exposure exceeds Occupational exposure limits (Sec. II). use a NIOSH approved respirator to prevent overexposure. ~ Ventilation: General ventilation is adequate under normal conditions: mechanical ventilation is optional. Protective Gloves: Chemical resistant gloves are optional -consult glove manufacturer to determine the proper type fora specific operation. Eye Protection: Safety glasses are recommended. Other Protective Clothing or Equipment: Wearing of impervious clothing to prevent skin Contact is optional. Work/Hygienic Practices: Ensure strict sanitary conditions are conformed to when working around chemicals. Protective clothing and equipment should be in accordance with 29 CFR 1910.132 and CFR 1910.133. *-*-*-*-*-*-*-*-*-*-*-*-* Section IX-Other Regulatory Controls -*-*-*-*-*-*-*-*-*-*-*•*- ` FEDERAL: Toxic Substance Control Act (TSCA): Ingredients of this product are listed on the EPA/TSCA Inventory of Chemical Substances. STATE RIGHT-70-KNOW: Pennsylvania/New Jersey Right-To-Know (Chemical and CAS No.): Refer to Section II. CANADA: Domestic Substances List: Ingredients of this product are listed. *-*-*-*-*-*-*-*-*-*-*-*-* Section X-Transportation (D.O.T. Classification) -*-*-*-*-*-*-*-*-*-*-*•* Proper Shipping Name: Consumer Commodity Hazard Class: ORM-D NG - Negligible . NA-- Not Applicable NE-- Not Established UN-- Unavailable ND-- Not Determined While the information set forth herein is believed to be accurate as of the date hereof, the Company makes no warranty or guarantee, express or implied, and disclaims all liability arising out of the use of this information. EFFECTIVE DATE: 01/01/05 SUPERCEDES: 04/22/98 PREPARED BY: Regulatory Compliance ~, ~~ CBETC(J ~i+ oc~~n o %~ ~ts_L~ _bi n~ Cry q X01 _/_8_i 72 ~ i 5 ,cisrc #~0~0~~20~ _Material Safety D as Sheet WHMIS (Pictograms) WHMIS (Classification) O WHMIS CLASS D-2: Material causing other toxic effects. T Section. 7. Chemical Producf and Company /dentification Product Name/ Trade name PUSh Synonym Liquid Bacteria /Digester/Spotter Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419) 241-2156 TSCA TSCA Inventory: All components listed or arc exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS HCS HCS Class: Irritating substance. Code 133 CAS # Not applicable. Validation Date 7/22/2003 Print Date 7/28/2003 In Case of Emereencv Chemtrec (800) 424-9300 Protective Clothing ~'l7 ~lol N Section 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCs,JLDs„ Weight 1) Water 7732-18-5 75-85 Not available. Not available. 2) Live Bacteria Dispersion N/A 5-10 Not available. Not available. 3) Isopropyl Alcohol 67-63-0 0-5 TWA: 400 (ppm) ORAL (LD50): Acute: TWA: 400 (ppm) from 16971 mg/kg [Rat]. OSHA (PEL) [United States] STEL:500 (ppm) 4) Tetrasodium salt of 64-02-8 0-5 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg [Rat]. 5) Opacifier N/A 1-5 Not available. . Not available. 6) Nonionic Surfactant 9016-45-9 0-5 Not available. Not available. 7) Nonionic Surfactant 61788-90-7 0-5 Not available. ORAL (LD50): Acute: 4610 mg/kg [Rat]. 8) Perfume Oil 8007-02-1 <1 Not available. Not available. Section 3. Hazards Identification Potential Acute Health Effects This product is an eye irritant. EYE CONTACT MAY RESULT IN INFECTION. Potential Chronic }icalth There is no known effect from chronic exposure to this product. Effects Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact May Infect Eyes.Check for and remove any contact lenses. DO NOT use an eye ointment. Seek medical attention. Skin Contact Avoid contact with skin and eyes. Irritant. May infect open wounds Rinse with plenty of running water. Seek medical attention. Inhalation Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Ingestion May be irritating to gastrointestinal system, mouth, throat, and esophagus. Vomiting and diarrhea expected with large doses. Have conscious person drink several glasses of water or milk. Seek medical attention. Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions DO NOT use water jet. Use DRY chemicals, C02, water spray or foam. Special Remarks on Fire Hazards No additional remark. Special Remarks on Explosion Hazards No additional remark. :Section 6; Accidental Release Measures Small Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spilt consult a specialist BEFORE handling this product. Section 7. Handiing and Storage Precautions DO NOT ingest. Do not breathe gas, fumes, vapor or spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Incompatibility Do not use in the presence of disinfectants or bleach. Storage Keep out of reach of children. Keep container tightly closed. Not for use or storage in or around the home. Section 8. Exposure ConfrolslPersonal Profection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Long Pants and Long Sleeves to avoid skin cotact. Respiratory Wear appropriate respirator when ventilation is inadequate. Hnnds Gloves. Protective Clothing (Pictograms) ~ a Exposure Limits Isopropyl Alcohol TWA: 400 (ppm) TWA: 400 (ppm) from OSHA (PEL) STEL: 500 (ppm) Consult local authorities for acceptable exposure limits. Section 9. Physicai and Chemical Properties Physical State and Appearance Liquid. Odor Pleasant. Molecular weight Not applicable. Taste Not available. pH 7 to 8 [Basic.) Color White. Boiling/Condensation Point 100°C (212°F) Melting/Frcezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1 (Water = 1) Vapor Pressure 20 mm of Hg (@ 20°C) Vapor Density >1 (Air = 1) Volatility Not available. vOC 2.5% By Weight Evaporation Rate <1 compared to Water Dispersion Properties Not available. Solubility Not available. The Product is: Non-flammable. Auto-ignition Temperature Not available. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits .Not available. Fire Hazards in Presence of various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Presence of Various Substances Drums Heated 8y Fire Can explode Section 10. Stability and Reactivity Data Stability The product is stable. Incompatibility with various Do not use in the presence of disinfectants or bleach. Substances Hazardous Decomposition Not available. Products Section 11. Toxicological Informatior- Routes of Entry Absorbed through skin. Eye contact. Inhalation. Toxicity to Animals Acute oral toxicity (LD50): 4610 mg/kg [Rat]. (Nonionic Surfactant). Acute Effects on Humans Eyes Hazardous in case of eye contact (irritant). This product may infect eyes. Skin Slightly hazardous in case of skin contact (irritant, sensitizer). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. May infect open wounds. Inhalation Hazardous in case of inhalation. I,:gesrio,e Hazardous in case of ingestion. Irritating to mouth, throat and stomach. Chronic Effects on Humans There is no known effect from chronic exposure to this product. Special Remarks on Toxicity No additional remark. Io Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Ecological Information Ecotoxicity Not available. BODS and COD Will not occur Products of $iodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. ~' Section 14. Transport Information DOT (U.S.A) (Pictograms) TDG Classification Not controlled under TDG (Canada). J 'IN UN, Proper Shipping Not applicable. Vamc, PG Maritime Transportation Not available. Special Provisions for Not applicable. Transport :~ Section 95. Other RegWatory Information and Pictograms WHMIS (Classification) WHMIS CLASS D-2: Material causing other toxic effects. O T Regulatory Lists No products were found. Other Regulations The following ingredients are NOT listed on he Canadian Domestic Substances List (DSL): Live Bacteria Dispersion Other Classifications HCS (U.S.A.) HCS Class: Irritating substance. USA Regulatory California prop. 65: This product contains the following ingredients, for which the Lists State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide <1 ppm Massachusetts RTK: Ethylene Oxide SARA 311/312: Isopropyl Alcohol; Bacteria Dispersion SARA 313: No components found DSD (EEC) This product is not classified according to the EU regulations. International No products were found. Regulations Lists Hazardous Material Information System __ _ 2 National Fire ! Flammability p Protection (U.S.A.) -Association (U.S.A.) Health < 7 ~ Instability _. Physical Hazard ~ ~ 9 ~ The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 16. Other'Information Validated by CRushton on 7/22/2003. Verified by CRushton. Printed 7/28/2003. Information Contact Betco Corporation 1001 Brown Aveuue Toledo, Ohio 43607 Notice to Reader Tn the best njnur knowledge, the infornmtinn contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accurag~ nr completeness of the injornmtinn contained herein. Final determination of suitability of any material is the sole responsibility ajthe user. A[I materials may present unknown hazards and shnu(d be used with caution. Al[hnugh certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Validated on 7/22/2003. PUSh Page: 5/5 Cgntinued~~ori Nezt~Page .~ WHMIS (Pictograms) ai °~ E L.OCA-n o ~~~~ ~tS~E ~1~1 _ C.Isr_c_# 140144 ~O ~-S Material Safety Data Sheet Section 1. Chemical Product and Company Identification Product Name/ Trade Extreme name Synonym ~ High Power/High Speed No Rinse Floor Stripper Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL DSL : All components listed unless noted elsewhere on this MSDS HCS HCS Class: Corrosive liquid. Code 184 CAS # Not applicable. Validation Date 8/11/2003 Print Date 8/22/2003 In Caseot Chemtrec (800) 424-9300 Emereencv Protective Clothing Section 2. Composition and Information on°lrrgredients Name CAS # % by Exposure Limits LCsi/LDsn Weight 1) Water 7732-18-5 55-60 Not available. Not available. 2) 2-Butoxyethanol 111-76-2 <21 TWA: 20 (ppm) from ORAL (LD50): Acute: 1746 ACGIH (TLV) [United mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States] 3) Benzyl Alcohol 100-51-6 <10 TWA: 3 STEL: 6 (ppm) Not available. 4) Monoethanolamine 141-43-5 5-10 TWA: 3 (ppm) Not available. TWA: 6 (ppm)' from OSHA (PEL) [United States] STEL:6 (ppm) 5) Sodium Xylene Sulfonate 1300-72-7 <5 Not available. Not available. 6) Perfume Oil 100-52-7 <1 Not available. Not available. 7) Nonionic Surfactant 9016-45-9 0-5 Not available. Not available. 8) Mixed Amphocarboxylates N/A 0-5 Not available. Not available. 9) Tetrasodium salt of 64-02-8 <1 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraaceticaciti mg/kg [Rat]. 10) Dye N/A <1 Not available. Not available. Section 3. Hazards7denti>rcation Potential Acute Health Effects Corrosive to eyes and skin. Harmful if swallowed. Harmful if inhaled., Irritating to mouth, throat and stomach. Potential Chronic Health Asthma and related respiratory illness may be aggravated by exposure. Repeated or prolonged Effects exposure to the gas can produce lung damage. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. However, in light of good industrial hygiene, exposure to any chemical should be kept to a minimum. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4.,FirstAid Measures Eye Contact Immediately Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor immediately for treatment advice. Skin Contact Remove contaminated clothing and shoes. Rinse skin with plenty of water for 15 to 20 minutes. Call a poison control center or doctor for further treatment advice. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Call a poison control center or doctor for further treatment advice. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person ......Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media N/A and Instructions Special Remarks on Fire N/A Hazards Special Remarks on N/A Explosion Hazards Section 6. Accidental Re/ease Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Prevent entry into sewers, basements or confined areas. Neutralize caustic ingredients with vinegar or acetic acid or use a basic spill kit. Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions After handling, always wash hands thoroughly with soap and water. Avoid breathing vapors or spray mists. Do not ingest. Good general ventilation should be sufficient to control airborne levels. Incompatibility Strong acids or oxidizers. Storage Keep out of the reach of children. Not for use or storage in or around the home. Section 8. Exposure-Controls/Personal Protection.. Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Splash goggles. Body Wear overalls or long sleeved shirt and long trousers, nitrite rubber or neoprene gloves, rubber boots. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Rubber gloves. Protective Clothing (Pictograms) ~ 0 . Exposure Limits 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Moncethanolamine TWA:3 (ppm) TWA: 6 (ppm) from OSHA (PEL) STEL:6 (ppm) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Aromatic. Ethereal. Molecular Weight Not applicable. Taste Not available. pH 11.8 to 12.8 [Basic.] Color Pale Green. Boiling/Condensation Point 214°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 0.993 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 95 VOC 23 (%) Evaporation Rate <1 compared to Butyl acetate. Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: Non-flammable. Auto-ignition Temperature Not available. Flash Points Not available. Flammable Limits Not available. Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Not applicable Section 10. Stability and Reaefivity Data Stability The product is stable. Incompatibility with Various Strong acids or oxidizers. Substances Hazardous Decomposition Will not occur. Products Section 11. Toxicological Information Routes of Entry Dermal contact. Eye contact. Inhalation. Ingestion. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. ' Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). Acute Effects on Humans Eyes Severe eye irritant. Liquid and mist may damage the eyes causing corneal injury. Skin Corrosive. Skin contact may produce burns. Inhalation Vapors may be irritating to the mucous membranes in the nose, throat, and lungs. High concentrations may cause headache, dizziness, and nausea. Ingestion Irritating to the mouth, throat, and gastrointestinal system. May cause dizziness, headache, nausea, vomiting, and diarrhea. Harmful if swallowed. Chronic Effects on Humans Asthma and related respiratory illness may be aggravated by exposure. Repeated or prolonged exposure to the gas can produce lung damage. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. However, in light of good industrial hygiene, exposure to any chemical should be kept to a minimum. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic No additional remark. Effects on Humans Section 12. Ecological Information Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation No additional remark. Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 15. Other Regulatory Information and Pictograms WHIVIIS (Classification} E Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS CIesS: Corrosive liquid. USA Regulatory California prop. 65: This product contains the following ingredients for which the Lists State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide < 1ppm Massachusetts RTK: Ethylene Oxide SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) R22- Harmful if swallowed. R36/38- Irritating to eyes and skin. International No products were found. Regulations Lists Hazardous Material ~ * 3 National Fire Information S stem - ~a""a~ility Y f„~L~ , , , p; Protection (U.S.A.) -Association (i1.S.A.) Health ~~ fnstabisty -Physical Ha:~rd. ~, Q i `~~ The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE ~ Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product r ~~ 3 ,; Section ?6. Other,lnformation Validated by CRushton on 8/11/2003. Verified by CRushton. Printed 8/22/2003. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best ojour knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever (or the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Ahhough certain hazards ore described herein, we connotguarant¢e that these are the only hazards that exist validates on 8/11/2003. Extreme Page: 6/6 Continued'on Next Page - ~ - LOC_RTt~~N-~ ~ 1 ~C? I ~~-~ A-lSc..E gl~ ~ ~09_/_0~ /~33_~ '`~' ~~° ~~ SLI~~Material Safe Data Sheet ty This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 Not controlled under WHMIS (Canada). WHMIS Class D-2B: HCS Class: Irritating Substance. T Material causing other toxic effects (TOXIC). WHMIS (Pictograms) WHMIS (Classification) HCS Section 7. Chemical Product and Company Identification Product Name/ Green Earth Daily Floor Cleaner Trade name Synonym Neutral Cleaner Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (800) 333-2156 TSCA TSCA Inventory: All components listed or are exempt from listing DSL/ NDSL All components listed unless noted elsewhere on this MSDS Code 536 CAS # Not applicable. Validation Date 3/2/2007 Print Date 3/23/2007 In Case of Chemtrec (800) 424-9300 Emer¢ency Protective Clothing d~ Section'2. Composition and Information on Ingredients Name CAS # % by Weight . Exposure Limits LCsu/LDso Alcohol Ethoxylate Blend N/A 1-5 Not available. Not available. Section 3. Hazards Identification'' Potential Acute Health This product is an eye irritant. May cause mild irritation to the skin. Effects Potential Chronic Health There is no known effect from chronic exposure to this product. Effects Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. FirstAid Measures Eye Contact Mildly irritating to the eyes. In case of contact with eyes, rinse immediately with plenty of water. Seek medical attention. Skin Contact NO known EFFECT on skin contact; rinse with water for a few minutes. If irritation persists, seek medical attention. Inhalation N/A Ingestion May be irritating to gastrointestinal system, mouth, throat, and esophagus. Vomiting and diarrhea expected with large doses. Seek immediate medical attention. Section 5. Fire Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions N/A Special Remarks on Fire Hazards N/A Special Remarks on Explosion Hazards N/A Section 6. Accidental Release. Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be Case of a Large Spill sufficient; consult a specialist BEFORE handling this product. 'Section 7. Handling and 'Storage Precautions Avoid contact with eyes. Incompatibility None known. Storage Keep out of reach of children. Keep container tightly closed. For Institutional and Commercial Use Secfion 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Safety glasses. Body No special protective clothing is required. Respiratory Not applicable. Hands Gloves. Protective Clothing (Pictograms) Exposure Limits Not available. Section 9. Physical and Chemical Properties. Physical State and Appearance Liquid. Odor Characteristic. Molecular Weight Not applicable. Taste Disagreeable. (Slight.) pH 7 to 8.5 [Basic.] Color Yellow. (Light.) Boiling/Condensation Point 212°F initial Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1 (Water = 1) Vapor Pressure 20mm Hg @ 68°F Vapor Density >1 (Air = 1) Volatility 90 VOC 0 (g/I). (0 lbs. Gal) Evaporation Rate <1 compared to Water Dispersion Properties See solubility in water. Solubility Easily soluble in cold water. The Product is: Non-flammable. Auto-ignition Temperature Not available. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits Not available. Fire Hazards in Presence of Various Substances Non-flammable. Explosion Hazards in Presence of Various Substances Not applicable Section 10. Stability ar-d Reactivity Data Stability The product is stable. Incompatibility with None known. Various Substances Hazardous Decomposition Will not occur. Products Section 11: Toxicological Information Routes of Entry Not available. Toxicity to Animals Acute oral toxicity (LD50): 3030 mg/kg [Rat]. (Tetrasodium EDTA). Acute Effects on Humans Eyes Eye irritant. May cause redness and swelling of the conjunctiva. Skin Defatting to skin on repeated contact. Inhalation N/A Ingestion May be irritating to the gastrointestinal system. Vomiting and diarrhea expected with large doses. Chronic Effects on There is no known effect from chronic exposure to this product. Humans Special Remarks on No additional remark. Toxicity to Animals Special Remarks on No additional remark. Chronic Effects on . Humans ~~ :.• Section 72, Esolo ical Information Ecotoxicity Not available. BODS and COD Not available. Products of Possibly hazardous short term degradation products are not likely. However, long term Biodegradation degradation products may arise. Toxicity of the Products of Not available. Biodegradation Special Remarks on the No additional remark. Products of Biodegradation Section 13. Disposal Considerations Waste Information Any method in accordance with applicable laws. Waste Stream Not available. Section 75, Other Regulatory Information and Pictograms WHMIS (Classification) Not controlled under WHMIS (Canada). WHMIS Class D-26: Material causing other toxic effects (TOXIC). O 'r Regulatory Lists No products were found. Other Regulations Not available. or of its ingredients Other Classifications HCS (U.S.A.) HCS Class: Irritating substance. USA Regulatory California prop. 65: This product contains the following ingredients for Lists which the State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide <1 ppm Massachusetts RTK: Ethylene Oxide DSD (EEC) This product is not classified according to the EU regulations. It International No products were found. Regulations Lists Hazardous Material ~.:,< 1 National Fire Information System ~ ~: ~~~~ ; ~ Flammability p Protection S.A. ~ ~~ `' Health Instability ~' ~ Physical Hazard ~ 0 Association 0 ~ (U.S.A.) The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 16. Other Information Validated by CRushton on 3/2/2007. Verified by CRushton. Printed 3/23/2007. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Validated on 3/2/2007. Green Earth Dail Floor Cleaner Pa e: 5/5 Continued,on Next Page` 1' 13M MATERIAL SAFETY DATA SHEET 3M(TM) Creme Cleanser Ready-To-Use 10/14/2002 _ I ... Cc~9_/_0 ~ /off Material Safety Data Sheet ~(Q Q ~ 5 Copyright, 2002, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION;1; PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Creme Cleanser Ready-To-Use MANUFACTURER: 3M DNISION: Commercial Care Division ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or 651 737-6501 24 hours Issue Date: 10/14/2002 Supercedes Date: 09/25/2002 Document Group: 18-1501-8 Product Use: Specific Use: Cleaner SECTION`2: INGItGDIENTS Ingredient C.A.S. No. % by Wt WATER 7732-18-5 30 - 60 QUARTZ SILICA 14808-60-7 15 - 40 NONYLPHENOL POLYETHYLENE OXIDE 9016-45-9 1 - 5 DODECYLBENZENE SULFONIC ACID 27176-87-0 1 - 5 METHYL SALICYLATE 119-36-8 < 1 SECTIOn 3: HAZARDS IDENTII+'1C;ATION ~ 3.1 EMERGENCY OVERVIEW Specific Physical Form: Liquid Odor, Color, Grade: Greyish white, light mint fragrance General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause severe eye irritation. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. 1 of 6 3M MATERIAL SAFETY DATA SIIEET 3M M Creme Cleanser Read -To-Use 10/14/2002 Inhalation: Single exposure, above recommended guidelines, may cause: Upper Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure, above recommended guidelines, may cause: Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease. While the above effect is associated with one of the individual ingredients in this product and is required to be included on the MSDS by the U.S. OSHA Hazard Communication Standard, it is not expected effects during forseeable use of this product. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, nausea, diarrhea and vomiting. SECTION 4: FIRST AID .MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: If signs/symptoms develop, remove person to fresh air. If signs/symptoms persist, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION ~: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature Not Applicable Flash Point Not Applicable Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable OSHA Flammability Classification: Not Applicable 5.2 EXTINGUISHING MEDIA Material will not burn. 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Nonflammable. Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. --- - - SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Ventilate the area with fresh air. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material.. Mix in sufficient 2of6 3M MATERIAL SAFETY DATA SHEET 3M Creme Cleanser Read -To-Use 10/14/2002 absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Clean up residue with water. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal re ulations. - _ -- -- __ SECTIOl`J 7: HANDLING AND STORAGE 7.1 HANDLING Avoid eye contact. Avoid prolonged or repeated skin contact. Avoid breathing of vapors, mists or spray. Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid contact with oxidizing agents. Keep away from aluminum and zinc. Keep out of the reach of children. Keep away from bleach and ammonia products. 7.2 STORAGE Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTIOPJ 8.1 ENGINEERING CONTROLS Use in awell-ventilated area. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact. The following eye protection(s) are recommended: Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Neoprene, Nitrile Rubber. 8.2:3 Respiratory Protection Avoid breathing of vapors, mists or spray. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Insredient Authori Tvue Limit Additional Information QUARTZ SII.ICA ACGIH TWA - 0.05 mg/m3 Table A2 respirable QUARTZ SILICA OSHA TWA - 0.1 mg/m3 Table Z-lA respirable SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) j>SECTION 9: PHYSICAL ANll CHEMICAL PROPERTIES ~, Specific Physical Form: Odor, Color, Grade: Liquid Greyish white, light mint fragrance 3of6 ~~ 3M MATERIAL SAFETY DATA SHEET 3M M Creme Cleanser Read -To-Use 10/14/2002 General Physical Form: Autoignition temperature Flash Point Flammable Limits - LEL Flammable Limits - UEL Boiling point Density Vapor Density Vapor Pressure Specific Gravity pH Melting point Solubility in Water Evaporation rate Volatile Organic Compounds Percent volatile VOC Less H2O & Exempt Solvents Liquid Not Applicable Not Applicable Not Applicable Not Applicable 216 °F No Data Available > 1 [Ref Std: AIR=1] No Data Available 1.3 [Ref Std: WATER=1] Approximately 2.2 Not Applicable Moderate <1 < 1 % [Test Method: calculated per CARB title 2] 30-60% < 1 % [Test Method: calculated per CARB title 2] -- - ~ SECTION 10; STABILITY :AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Alkali and alkaline earth metals; Strong oxidizing agents; Bleach and ammonia products Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Not applicable. During Combustion - _ _ SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL 1NFORMATION ECOTOXICOLOGICAL INFORMATION Not Determined CHEMICAL FATE INFORMATION Not Determined - _ _ ---_ SECTIONI3: DISPOSAL CONSIDERATIONS Waste Disposal Method: Since regulations vary, consult applicable regulations or authorities before disposal. EPA Hazardous Waste Number (RCRA): Not regulated Since re ulations var consult a licable re ulations or authorities before dis osal. `SECTION.I4:TRANSPORT INFORMATION -- -- -~ 4of6 3M MATERIAL SAFETY DATA SHEET 3M M Creme Cleanser Read -TaUse 10/14/2002 H) Number UPC ID Number UPC 70-0711-5624-7 00-48011-34763-4 Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3Mpolicies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3Mpackage is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory SECTIOl'~' 1S: REGULATORI" INFORMATION US FEDERAL REGULATIONS 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard -Yes Delayed Hazard - No CHEMICAL INVENTORIES All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. The components of this product are in compliance with the chemical notification requirements of TSCA. This MSDS has been re ared to meet the U.S. OSHA Hazard Communication Standard 29 CFR 1910.1200. - - - - - __ SECTION 16: OTHER 1NF0It~ti1ATION NFPA Hazard Classification Health: 2 Flammability: 0 Reactivity: 0 Special Hazards: None Acid/Base: Acid National Fire Protection Association (NFPA) hazazd ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similaz emergencies. Hazard ratings aze primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 0 Reactivity: 0 Protection: X -See PPE section. Hazardous Material Identification System (HMIS(r)) hazard ratings are designed to inform employees of chemical hazazds in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS(r) ratings are to be used with a fully implemented HMIS(r) program. HMIS(r) is a registered mark of the National Paint and Coatings Association (NPCA). DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. Sof6 3M MATERIAL SAFETY DATA SHEET 3M M Creme Cleanser Read -To-Use 10!14/2002 3M MSDSs are available at www.3M.com 6of6 y, f LO_GAT!_O_!~/-~ ~~ lyl0~c~~~ ;~ .. ` _ - ~ ~ ~~~A '~--~~ /-0~-X05-_. ~~~ ~-' ~-~ ~' `~`~ ~~ !a ~s Material Safet Data Sheet y This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 CLASS E: Corrosive liquid. ~` WHMIS Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). WHMIS (Pictograms) WHMIS (Classification) Section 1. Chemical Product and Company Identification Product Name/ Trade name Extreme Ultra Synonym Floor Stripper Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 (419)241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing, DSL/ NDSL All components listed unless noted elsewhere on this MSDS HCS CLASS: Corrosive liquid. HCS Class: Combustible liquid IIIA having a flash point between 60.0°C (140°F) and 93.3°C (200°F). HCS Code 194 CAS# NA Validation Date 3/2/2007 Print Date 3/24/2007 In Case of Chemtrec (800) 424-9300 Emereencv Protective Clothing ~~~ :Section' 2. Composition and Information on Ingredients Name CAS # % by Exposure Limits LCso/LDso Weight Benzyl Alcohol 100-51-6 50-55 TWA: 3 STEL: 6 (ppm) Not available. Monoethanolamine 141-43-5 20-25 TWA: 3 (ppm) Not available. TWA:6 (ppm) from OSHA (PEL) [United States] STEL:6 (ppm) 2-Butoxyethanol 111-76-2 15-20 TWA: 20 (ppm) from ORAL (LD50): Acute: ACGIH (TLV) [United 1746 mg/kg [Rat]. States] TWA: 50 (ppm) from OSHA (PEL) [United States] Tall Oil 61790-12-3 0-5 Not available. Not available. Nonionic Surfactant 9016-45-9 1-5 Not available. Not available. Dispersion of Fluorochemicals in N/A 0-5 Not available. Not available. Water Section`3 Hazards Identification Potential Acute Health Extremely hazardous in case of eye contact (irritant). Very hazardous in case of skin contact Effects (corrosive, irritant), of ingestion, of inhalation. Eye contact can result in corneal damage or blindness. Potential Chronic Health Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation Effects ~ may cause respiratory irritation. Repeated or prolonged exposure to the substance can produce blood disorders. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section'4. First Aid'Measures Eye Contact Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Skin Contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Inhalation Evacuate the victim to a safe area as soon as possible. Seek medical attention. Ingestion Have conscious person drink several glasses of water or milk. Do not induce vomiting. Seek immediate medical attention. Section 5. Fire Fighting'Measures Products of Combustion Not available. Fire Fighting Media and Instructions SMALL FIRE: Use DRY chemicals, C02, water spray or foam. LARGE FIRE: Use water spray, fog or foam. DO NOT use water jet. Special Remarks on Fire Hazards No additional remark. Special Remarks on Explosion Hazards No additional remark. Section' 6.'Accidental Release Measures '' Small Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. If necessary: Neutralize the residue with a dilute solution of acetic aci Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Personal Protection in Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be Case of a Large Spill sufficient; consult a specialist BEFORE handling this product. Section 7. Handling and Storage Precautions Keep locked up. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. DO NOT ingest. Do not breathe gas, fumes, vapor or spray. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Incompatibility acids alkalis Storage Corrosive materials should be stored in a separate safety storage cabinet or room. Keep out of the reach of children. Not for use or storage in or around the home. Section 8. Exposure Controls/Personal Protection Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Personal Protection Eyes Splash goggles. Body Wear overalls or long sleeved shirt and long trousers, nitrite rubber or neoprene gloves, rubber boots. Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves (impervious). Protective Clothing (Pictograms) _ _ 0 •~ 0 Exposure Limits Benzyl AlCOhol TWA: 3 STEL: 6 (ppm) Monoethanolamine TWA:3 (ppm) TWA: 6 (ppm) from OSHA (PEL) STEL:6 (ppm) 2-Butoxyethanol TWA: 25 (ppm) TWA: 50 (ppm) from OSHA (PEL) Consult local authorities for acceptable exposure limits. .Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Aromatic. Molecular Weight Not applicable. Taste Not available. pH 11 to 12 [Basic.] Color Clear Boiling/Condensation Point Not available. Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.01 (Water = 1) Vapor Pressure Not available. Vapor Density >1 (Air = 1) Volatility 88% (w/w). VOC 88 (%) Evaporation Rate Not available. Dispersion Properties Not available. Solubility Not available. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points CLOSED CUP:93.333°C (200°F). (TCC). Flammable Limits Not available. Fire Hazards in Presence of Various Substances No specific information is available in our database regarding the flammability of this product in presence of various materials. Explosion Hazards in Not applicable Presence of Various Substances Section'10. Stability and Reactivity Data Stability The product is stable. Incompatibility with acids alkalis Various Substances Hazardous Decomposition Not available. Products Section''11. Toxicological Information Routes of Entry Absorbed through skin.- Eye contact. Inhalation. Ingestion. Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1746 mg/kg [Rat]. (2-Butoxyethanol). Acute toxicity of the gas (LC50): 926 ppm 4 hour(s) [Mouse]. (2-Butoxyethanol). Acute Effects on Humans Eyes Eye contact can result in corneal damage or blindness. Skin Corrosive to skin and eyes on contact. Skin contact may produce burns. Inhalation Harmful if inhaled. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Ingestion Very hazardous in case of ingestion. Chronic Effects on Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation Humans may cause respiratory irritation. Repeated or prolonged exposure to the substance can produce blood disorders. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce liver damage. Repeated or prolonged exposure to the substance can produce nervous system damage. Special Remarks on No additional remark. Toxicity to Animals Special Remarks on No additional remark. Chronic Effects on Humans Section 12. Ecolo ical information Ecotoxicity Not available. BODS and COD Not available. Products of Possibly hazardous short term degradation products are not likely. However, long term Biodegradation degradation products may arise. Toxicity of the Products of Not available. Biodegradation Special Remarks on the No additional remark. Products of Biodegradation ~- Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 14. Transport Information DOT (U.S.A) (Pictograms)° TDG Classification Class 8: Corrosive material PIN UN, Proper Shipping Shipping name: CORROSIVE LIQUIDS, N.O.S. UNNA: UN1760 PG: III name, PG Maritime Transportation Not available. II Special Provisions for Not available. I Transport Section 15. Other''Regulatory lnformation'and Pictograms WHMIS (Classification) CLASS E: Corrosive liquid. WHMIS Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) HCS CLASS: Corrosive liquid. HCS Class: Combustible liquid IIIA having a flash point between 60.0°C (140°F) and 93.3°C (200°F). USA Regulatory California prop. 65: This product contains the following ingredients for Lists which the State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide < 1 ppm California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Ethylene Oxide < 1 ppm Massachusetts RTK: Ethylene Oxide SARA 311/312 MSDS distribution -chemical inventory -hazard identification: 2-Butoxyethanol: immediate health hazard, delayed health hazard SARA 313 toxic chemical notification and release reporting: 2-Butoxyethanol DSD (EEC) This product is not classified according to the EU regulations. International No products were found. Regulations Lists Hazardous Material Information System * ~ 3 National Fire ,~~~~~~ - 1 Flammability I Protection (U.S.A.) ASSOC1at10n Health 3 O Instability. Physical Hazard ., Q (U.S.A.) The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE SpeciTic Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section 16. Other'Information Validated by CRushtoa on 3/2/2007. Verified by CRushton. Printed 3/24/2007. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist Validated on 3/2/2007. Extreme Ultra Pa e: 6/6 Continued on Next Page I'; ,~~ 'r = _ MATERIAL SAFETY DATA SHEET __ - - _` /~ ~ ~~~N A-ts3~~-r3 ~/~ 1-800-364-3577 or (651) 737-6501 (2~4-hot~:r ~~ Q o7~f 4T~25 227125 3M 3M Center~~ St. Paul, Minnesota 55144-1000 Copyright, 2001, Minnesota Mining and Manufacturing Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: 1) the information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. DIVISION: COMMERCIAL CARE DIVISION TRADE NAME: 3M Brand TILE, GROUT & BOWL CLEANER CONCENTRATE .................... . ..(Product No. 52, Twist 'n Fill(tm) System) ID NUMBER/U.P.C.: ?0-0709-8534-9 00-48011-26323-1 70-0710-0948-7 00-48011-26323-1 TSSUED: January 17, 2001 SUPERSEDES: January O8, 2001 DOCUMENT: 09-5355-4 ---------------------------------------------------------------------- 1. INGREDIENT C.A.S. NO. PERCENT WATER ................................... 7732-18-5 60 - 90 HYDROCHLORIC ACID....... ................ 7647-01-0 15 - 40 POLYOXYETHYLENE TALLOW AMINE:........... 61791-26-2 1 - 5 IN CASE OF EMERGENCY: THE NUMBERS AT THE TOP OF THIS PAGE PROVIDE 24. HOUR RESPONSE FROM ANY PHONE FOR ALL EMERGENCIES WITH.THIS PRODUCT. The components of this product are in compliance with the chemical notification requirements of TSCA. 70-0709-8537-2 00-48011-2 6326-2 70-0710-0949-5 00-48011-2 6326-2 Page ~ .' 227125 This product contains the following toxic chemical or chemicals subjec t to the reporting requirements of Section 313 of Title I,II of the Emergenc Y Planning, and Community Right-To-Know Act of 1986 and 40 CFR Part 372: HYDROCHLORIC ACID 2. PHYSICAL DATA ---------------------------------------------------------------------- BOILING POINT :................. ca. 225 F VAPOR PRESSURE :................ ca. 190 mmHg ® 25 C (77 F) VAPOR DENSITY :................. N/D EVAPORATION RATE :.............. N/D SOLUBILITY IN WATER:........... complete SPECIFIC GRAVITY :.............. 1.19 Water=l PERCENT VOLATILE :.............. ca. 98 ~ pH :................... ....... < 0.1 ---------------------------------------------------------------------- Abbreviations: N/D - Not Determined N/A - Not Applic-able CA - Approx imately 0 MSDS: 3M Brand TILE, GROUT & BOWL CLEANER CONCENTRATE ................ .. (Product No. 52, Twist 'n Fill(tm) System) January 17, 2001 PAGE 2 2. PHYSICAL DATA (continued) VISCOSITY: ....... ........... < 300 centipoise MELTING POINT :................. N/D APPEARANCE AND ODOR: Page 2. ~~ ., c,o_c~to_N_-__-] ~~s~ ,Big _ _ Material Safety Data Sheet This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 O CLASS D-2B: Material causing other toxic effects (TOXIC). T WHMIS (Pictograms) WHMIS (Classification) Section 1. Chemical Product and Company Identification Product Name/ Trade Green Earth Natural Degreaser name Synonym Degreaser Concentrate Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/ Supplier Betco Corporation 1001 Brown Avenue Toledo, Oh 43607 (419) 241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing. DSL/ NDSL All components listed unless noted elsewhere on this MSDS Class: Irritating substance. HCS Code 2 ~ 7 CAS # Mixture. Validation Date 3/26/2004 Print Date 3/27/2004 In Case of Emereencv Chemtrec (800) 424-9300 Protective Clothing C10 Section 2. Composition-:and Information on Ingredients Name CAS # % by Exposure Limits LCso~LDso Weight 1) Alcohol Polyether 68551-12-2 5-10 Not available. Not available. 2) Propylene Glycol NButyl Ether 5131-66-8 0.1-5 Not available. Not available. 3) Alkylpolyglucosides 68515-73-1 0.1-5 Not available. Not available. 4) Tripropylene Glycol Methyl Ether 25498-49-1 1-2 Not available. Not available. 5) Tetrasodium salt of 64-02-8 1-2 Not available. ORAL (LD50): Acute: 3030 ethylendiaminetetraacetic acid mg/kg [Rat]. 6) Tall Oil 61790-12-3 0.1-1 Not available. Not available. 7) Coconut Soap 8001-31-8 0.01-0.1 Not available. Not available. -- Section 3. Hazards ldenti~cation Potential Acute Health Effects Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Non-corrosive for skin. Potential Chronic Health Repeated or prolonged exposure to the substance can produce nervous system damage. Prolonged Effects exposure may produce anesthetic or narcotic effects. May aggravate existing respiratory conditions such as asthma. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact In case of contact with eyes, rinse immediately with plenty of water. Seek medical attention. Skin Contact After contact with skin, wash immediately with plenty of water. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Ingestion Have conscious person drink 1 Pint of lukewarm water. NEVER give an unconscious person anything to ingest. Seek immediate medical attention. :~ Section 5. Fire'Fighting Measures Products of Combustion Not available. Fire Fighting Media and Instructions SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks on Fire Hazards Vapor may travel considerable distance to source of ignition and flash back. Special Remarks on Explosion Hazards No additional remark. Section 6. Accidental Release Measures Small Spill and Leak Absorb with an inert material and place in an appropriate waste disposal container. Large Spill and Leak Absorb with DRY earth, sand or other non-combustible material. Vacuum or sweep up material and place in a designated labeled waste container. Personal Protection in Case of Gloves..Splash goggles. Wear appropriate respirator when ventilation is inadequate. a Large Spill Section 7. Handling and Storage.. - Precautions Avoid breathing vapors or spray mists. Keep away from incompatibles. Keep away from sources of ignition. Keep out of the reach of children. Incompatibility Incompatible with some strong acids. oxidizing agents Storage Keep out of the reach of children. Not for use or storage in or around the home. Keep away from heat, sparks and flame. Keep away from incompatibles. Keep away from sources of ignition. Section 8. Exposure Controls/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Safety glasses. Body No special recommendations. , Respiratory A respirator is not needed under normal and intended conditions of product use. Wear appropriate respirator when ventilation is inadequate. Hands Gloves. Protective Clothing (Pictograms) Exposure Limits Not available. ~ Boiting/Condensation Point 100°C (212°F) Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 1.01 (Water = 1) Vapor Pressure Not available. Vapor Density >1 (Air = 1) Volatility 84% (w/w). VOC 70.602 (g/I). Evaporation Rate <1 compared to Butyl acetate. Dispersion Properties See solubility in water. Solubility Easily soluble in cold water, hot water. The Product is: May be combustible at high temperature. Auto-ignition Temperature Not available. Flash Points CLOSED CUP: >98.889°C (210°F). Flammable Limits Not available. Fire Hazards in Presence of Various Substances Not available. Explosion Hazards in Presence of Various Substances Containers may explode when heated. Section 10. Stability and Reactivity Data Stability The product is stable. Incompatibility with Various Incompatible with some strong acids. oxidizing agents Substances Hazardous Decomposition Not available. Products Section 11, rToxicological Information Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals Acute oral toxicity (LD50): 3030 mg/kg [Rat]. (Tetrasodium salt of ethylendiaminetetraacetic acid). Acute Effects on Humans Eyes Slightly hazardous in case of eye contact (irritant). Skin Sensitization of the product: Not available. Slightly hazardous in case of skin contact (irritant). Non-corrosive for skin. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Inhalation Slightly hazardous in case of inhalation. Ingestion Slightly hazardous in case of ingestion. Chronic Effects on Humans Repeated or prolonged exposure to the substance can produce nervous system damage. Prolonged exposure may produce anesthetic or narcotic effects. May aggravate existing respiratory conditions such as asthma. Special Remarks on Toxicity Not available. to Animals Special Remarks on Chronic Not available. Effects on Humans 5 ~` Section 12. Ecological Information : Ecotoxicity Not available. BODS and COD Not available. Products of Biodegradation Not available. Toxicity of the Products of Biodegradation Not available. Special Remarks on the Products of Biodegradation Not available. Section''13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. Section 15. Other Regulatory Information and Pictograms WHNIIS (Classification) CLASS D-2B: Material causing other toxic effects (TOXIC). O T Regulatory Lists No products were found. Other Regulations OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications HCS (U.S.A.) Class: Irritating substance. USA Regulatory This product does not contain ingredients at levels known to the state of California Lists to cause cancer or reproductive harm. Pennsylvania RTK: Dipropylene Glycol ; Propylehe Glycol SARA 311/312 MSDS distribution -chemical inventory -hazard identification: Propylene Glycol NButy! Ether: fire, immediate health hazard, delayed health hazard DSD (EEC) This product is not classified according to the EU regulations. International No products were found. Regulations Lists ru ;~. . Hazardous Material ~ 1 National Fire ~larnmanuity Information System _, ~,~„~ ~ Protection (iJ.S.A.) 'Association (U.S.A.) Health ., l ~' O~ fnscanility Physical Hazard (] The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Huard MSDS must be consulted to determine any speck hazards, First Aid measures, and PPE associated with this product Section 16. Other Information Validated by CRushton on 3/26/2004. Verified by CRushton. Printed 3/27/2004. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio 43607 , Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever (or the accuracy or completeness of the injormation contained herein. Final determination ojsuitabi[ity of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with cautfon. Although certain hazards are described herein, we cannot guarantee that these ore the only hazards that exist ~ Validated on 3/z6izooa. Green Earth Natural Degreaser Page; 5/5 Continued. on Next Page '~ / • ~~~y Material Safety Data Sheet This MSDS is prepared in accordance with OSHA 29 CFR 1910.1200 ®® WHMIS CLASS D-2: Material causing other toxic effects. WHMIS Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). WHMIS (Pictograms) WHMIS (Classification) Section 1. Chemical Producf and Company Identification Product Name/ Trade name Green Earth Glass Cleaner Synonym Not available. Chemical Family Not available. Chemical Formula Not applicable. Manufacturer/Supplier Betco Corporation 1001 Brown Avenue Toledo, Oh 43607 (419) 241-2156 TSCA TSCA Inventory: All components listed or are exempt from listing DSL/ NDSL I All components listed unless noted elsewhere on this MSDS Class: Irritating substance. HCS Class: Combustible liquid having a flash point between 37.8°C (100°F) and 93.3°C (200°F). HCS Code 535 CAS # Mixture. Validation Date 3/2/2007 Print Date 3/23/2007 In Case of Chemtrec (800) 424-9300 Emereencv Protective Clothing W Section 2. Composifion and Information on Ingredients Name CAS # % by Exposure Limits LCsdLDso Weight Propylene Glycol NButyl Ether 5131-66-8 20-25 Not available. ORAL (LD50): Acute: 3200 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mg/kg [Rabbit]. 2-Propoxyethanol 2807-30-9 10-15 Not available. Not available. Sodium Lauryl Sulfate 151-21-3 1-5 Not available. Not available. Sodium Xylene Sulfonate 1300-72-7 1-5 Not available. ORAL (LD50): Acute: 650 mg/kg [Rat]. 5939 mg/kg [Mouse]. Alkylpolyglucosides 68515-73-1 1-5 Not available. Not available. Section-3. Hazards Identification Potential Acute Health This product is an eye irritant. Harmful if swallowed. Effects Potential Chronic Health Repeated skin exposure can produce local skin destruction, or dermatitis. This product may Effects aggravate exisiting skin conditions such as dermatitis. May aggravate existing respiratory conditions such as asthma. Over-exposure by inhalation may cause respiratory irritation. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce blood disorders. Carcinogenic Effects Not classified or listed by IARC, NTP, OSHA, EU and ACGIH. Section 4. First Aid Measures Eye Contact Hold eye open and rinse slowly and thoroughly with water for 15 to 20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Seek immediate medical attention. Skin Contact Seek medical attention. Inhalation Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration., preferably mouth to mouth if possible. Ingestion Call a poison control center immediately for treatment advice. Have person sip a glass of water if able to swallow. Do NOT induce vomiting unless instructed to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person Section 5. Fire Fighting Measures.. Products of Combustion Not available. Fire Fighting Media SMALL FIRE: Use DRY chemical powder. and Instructions LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks on Fire Vapor may travel considerable distance to source of ignition and flash back. FLAMMABLE. Hazards When mixed with air and exposed to ignition source, vapors can burn in open or explode if confined. Fine powder forms flammable and explosive mixtures in air. (Propylene Glycol NButyl Ether) Special Remarks on Not available. Explosion Hazards 'Section 6. Accidenfal Release Measures Small Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Large Spill and Leak Personal Protection in Case of a Large Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Butyl gloves. Splash goggles. Boots. Section 7. Handling and Storage. Precautions Avoid contact with skin and eyes Avoid breathing vapors or spray mists. Incompatibility alkalis acids oxidizing agents heat Storage Keep out of the reach of children. Combustible materials should be stored away from extreme heat and away from strong oxidizing agents. Not for use or storage in or around the home. Section 8. Exposure Contro/s/Personal Protection Engineering Controls Good general ventilation should be sufficient to control airborne levels. Personal Protection Eyes Safety glasses. Body No additional special protective clothing is required. Respiratory A respirator is not needed under normal and intended conditions of product use. Wear appropriate respirator when ventilation is inadequate. Hands No additional special protective clothing is required. Protective Clothing (Pictograms) Exposure Limits Not available. Section 9. Physical and Chemical Properties Physical State and Appearance Liquid. Odor Characteristic. Molecular Weight Not applicable. Taste Not available. pH 7.5-9.0 [Basic.] Color Blue. Boiling/Condensation Point 100°C (212°F) Melting/Freezing Point Not available. Critical Temperature Not available. Instability Temperature Not available. Specific Gravity 0.98174 (Water = 1) Vapor Pressure Not available. Vapor Density >1 (Air = 1) Volatility >85% VOC Not available. Evaporation Rate Not available. Dispersion Properties Not available. Solubility Not available. The Product is; COMBUSTIBLE. Auto-ignition Temperature Not available. Flash Points Closed cup: 61.111 °C (144°F). Flammable Limits Not available. Fire Hazards in Presence of Various Substances Not available. Explosion Hazards in Presence of Various Substances Containers may explode when heated. Section 10., Stability antl'Reactivity Data Stability The product is stable. Incompatibility with alkalis acids oxidizing agents heat Various Substances Hazardous Decomposition Not available. Products Section 11. Toxicological Information Routes of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Toxicity to Animals LD50: Estimated Oral (Rat) >5000 mg/kg Acute Effects on Humans Eyes Mildly irritating to the eyes. Skin Non-irritant for skin. Inhalation Slightly hazardous in case of inhalation. Ingestion Slightly hazardous in case of ingestion. Chronic Effects on Repeated skin exposure can produce local skin destruction, or dermatitis. This product may Humans aggravate exisiting skin conditions such as dermatitis. May aggravate existing respiratory conditions such as asthma. Over-exposure by inhalation may cause respiratory irritation. Repeated or prolonged exposure to the substance can produce kidney damage. Repeated or prolonged exposure to the substance can produce blood disorders. Special Remarks on Not available. Toxicity to Animals Special Remarks on Not available. Chronic Effects on Humans Section 12. Ecolo ical. Information Ecotoxicity Estimated to have low aquatic toxicity. BODS and COD Not available. Products of Not available. Biodegradation Toxicity of the Products of Not available. Biodegradation Special Remarks on the Not available. Products of Biodegradation Section 13. Disposal Considerations Waste Information Waste must be disposed of in accordance with federal, state and local environmental control regulations. Waste Stream Not available. ' Section 14. Transport'lnformation I DOT (U.S.A) (Pictograms) TDG Classi5cation TDG Class 3: Flammable liquid. D [N UN, Proper Shipping 1993 Flammable liquid n.o.s. ame, PG (For Shipment By Air) (This product is not regulated under the US DOT HMR in quantities less than 119 Gallons) ., ~,. _ . Transportation Not available. Special Provisions for Not applicable. Transport Section 15. Other Regulatory Information and Pictograms. WHMIS (Classification) WHMIS CLASS D-2: Material causing other toxic effects. WHMIS Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C (200°F). Regulatory Lists No products were found. Other Regulations Not available. or of its ingredients Other Classifications HCS (U.S.A.) Class: Irritating substance. HCS Class: Combustible liquid having a flash point between 37.8°C (100°F) and.93.3°C (200°F). USA Regulatory Lists .' SARA 311/312 MSDS distribution -chemical inventory -hazard identification: Propylene Glycol NButyl Ether: fire, immediate health hazard, delayed health hazard SARA 313 toxic chemical notification and release reporting: 2-Propoxyethanol DSD (EEC) This product is not classified according to the EU regulations. International No products were found. Regulations Lists Hazardous Material Information S stem Y 2 National Fire O Flammability .~ 0 Protection (U.S.A.) ~ Association Health 2 O Instability Physical Hazard ', 0 (U.S.A.) The Hazard Ranking systems presented on this MSDS provide only a quick reference for hazard information. The ENTIRE Specific Hazard MSDS must be consulted to determine any specific hazards, First Aid measures, and PPE associated with this product. Section` 76. Other Information Validated by CRushton on 3/2/2007. Verified by CRushton. Printed 3/23/2007. Information Contact Betco Corporation 1001 Brown Avenue Toledo, Ohio. 43607 Notice to Readel To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. Al[ materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist