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Home My WebLink AboutBUSINESS PLAN ~~ S r ., ~~ ~~ ~3-~~7~' ~ ii V t --_ ~--~ ~ ~. ,~ ~-is-~3~ ~ _ ins-~s1e. ,O~~,a~~u~.oa' ~- Q~x~-~-' L~`.c~-~`°~ ~ ~ C~ ~~ ~ ~ ~ ~ - ~~! a''"''~`~~,~ ~° ,ire. e.n~ -~.~ G . -?~ i LJ ______- _ r- ~ --•-----~ ~. .- - • • '_ ~ , _ F~ . . NLIB SiTF '';.'.GRAM !Required ::e~esi 1. address: [dents.°•;~ pcinciple buildint by the Street aumoers. 2. Street(s). Alle,s. Driveways, and Parking Areas adJacent to the property. Include the street noses. O. Storm Drains. Culverts. Yard Drains 4. Drainage Canals. Ditches. Creeks. S. Buildings a. Fraae construction b. Masonry construction c. Metal conscrncticn d. Access Door 6. Ctility Controls a. Gas b. Blectricity e. Mater T. Pire Suppression Systems: a. Fire Sydraata b. Pire Sprinkler Caanectloas e. Pire Standpipe Connsctloaa d. Mater Control valves for protection systeas s. Fire Puap 8. Pire Oepartaeat Aeeesa 9. LJCH Iket~x 10. MSDS Storage ?ax 11. Railroad Tracks 12. Fence or 9arriec a. Mtre b. Mnsonry c. Naod d. Gates 13. Poweriines 14. Guard Station _ I3. Storage Tanks: Identify the capacity la qal. a. Above Around b. IIndergzouad lE. Diking or Berm 1T. Bvaeaation Route 13. Eoacaatlon Arta: Idsetily the location where eaployees *ilI asst. l9. Oatside Hazardous Masts Storn¢e Z0. Ontsida Hazardow Material Storage 21. Oatsids Razardow Material Oss/Haadltn~ Z2. T9Ds of Hazardow Material/Haste Stored or Uaed (See Belowl TYPE OF gAZARIJOVS vATERIAL - P ~ Flnuable E ~ nz;.iosive L ~ Liquid R ~ Radioia¢1ca1' C ~ Corrosive 0 ~ Oxidizer G ~ Gas P ~ Poison M ~ Mater Reactive T ~ Tcxic S ~ Solid H ~ Crga¢enic D ~ Waste 8 ~ Etiological Exaaple: Flaasable Liquid - FL FACILITY 7IAGRAM (Required peas in addition to the above) 1. Risers for Sprinklers 8. P1re Escapes 2. Partitlona 9. Air Canditionia¢ Units 3. Stairways: Indicate the 10. Mindows leveia served Cros highest to lowest. 11. Inside Hazardous Naste Storage 4. Escalator: Indicate *.he level' served Cras 12. Inside Haznraous highest to lowest. !Interlala Storage 3. Elevator 13. Inside Hazardous Materials Useiriandling 8. Attic Access 14. Sewer 7raln Inlets - ~- 7. Skylioncs , ~; ~~~ ~ ~. - 't= I'I'~,~FaCI ~.ZTY l~I.~.GR~~I FOPtiI 5 J10RTri SC~.L~ : BGS I:rESS :iAti1E : ~ ~ ". = =00R : 7: ~f5 ~E~lP~/L ~7~.2.L/ pAT=:~.' ~ /~'j~FACiLiTF VA,~rF: r~ ~':~IT - OF ~.!%~~~ (C:-iEC~ OBE) SITE DIAGRA}I~_ FACILITY DIAG~~tii . 4 ~ ~'- ' ---~ ~r~k.r. ~-LS' - S' 1~° - ~ --- - ~~ - - - -- i a `i~ ~. 1' ~' I ~.: .,fit s ~.~ 1 ,~ ~~! i~ I rp ~1 r~ w (Inspector's Comments): -OFFICIAL CSc O~LY- ~~ ~ - ~~~~ G~~~i~- //jam s~~ o ~ - sa - • ~~ B E R S F" L D F//~E A l~ rM r January 17, 2002 FIRE CHIEF RON FRAZE ADMINISTRATIVE SERVICES 2101 "H" Street Bakersfield, CA 93301 VOICE (661) 326-3941 FAX (661) 395-1349 SUPPRESSION SERVICES 2101 °H° Street Bakersfield, CA 93301 VOICE (661) 326-3941 FAX (661) 395-1349 PREVENTION SERVICES 1715 Chester Ave. Bakersfield, CA 93301 VOICE (661) 326-3951 FAX (661) 326-0576 ENVIRONMENTAL SERVICES 1715 ChesterAve. Bakersfield, CA 93301 VOICE (661) 326-3979 FAX (661) 326-0576 TRAINING DNISION 5642 Victor Ave. Bakersfield, CA 93306 VOICE (661) 399-4697 FAX (661) 399-5763 IMPORTANT DO NOT DISCARD JOE' S REFRIGERATION 4145 PINEWOOD LAKE DRIVE BAKERSFIELD CA 93306 Deaz Business Owner: ~- ~Oop~ California Law requires that all Businesses, which at any time during the yeaz handle reportable quantities of hazardous materials, file a I-Iazaddous Materials Business plan, including inventory of hazardous materials, with the local administering agency. Your business has filed such a plan. This same regulation requires that these businesses review the business plan submitted to determine if revisions aze needed, and to certify to the administering agencies that the review was made and that any necessary changes were made to the plan. To facilitate this review we have enclosed a computer print-out of the plan you have submitted. Please review this plan in its entirety and make any necessary revisions on the print-out. When the review and revisions aze completed sign the first page of the plan in the appropriate space certifying that the plan is complete and correct. Return the business plan along with any revisions to this office within 30days of receiving these forms. If you have any questions or if we can be of any assistance please do not hesitate to ca11326-3979. Also, please call this office to reschedule an inspection as our inspector was unable to locate you at the time he went out. Sincerely yours, ~~ Ralph E. Huey Director, Office of Environmental Services ct; JPS~xit~ /fee ~o~rtij~~i~ .~o~ ~/e~a~ ~~ .~ (~c~fui~G~~ ~~~Q~ti D F.pt _ ~~~~ ~'' CITY OF BAI{F.RSFIEI.D FIRE DEPARTMENT ° _ ~ ~~ OFFICE OF ENVIRONMENTAL. SERVICES ~' ~"~ UNIFIED PROGRAIi'I II°~TSPECTION CIIECKI.IST ;ty ~gti,~!~~~ 1715 Chester Ave., 3rd floor, Bakersfield, CA 93301 FACILITY NAME t ah INSPECTION DATE t l' 7 (D ADDRESS ~ r2 . PHONE NO.f~3 y~ 6 f~0u FACILITY CONTACT_ BUSINESS ID NO. 15-210- pf~~l y ?~ INSPECTION TIME NUMBER OF EMPLOYEES Se ion 1: Routine Business Plan and Inventory Program ^ Combined ^ Joint Agency ^Mnlti-Agency ^ Complaint ^ Re-inspection OPERATION C COMMENTS Appropriate permit on hand Business plan contact information accurate Visible address Correct occupancy Verification of inventory materials Verification of quantities Verification of location Proper segregation of material Verification of MSDS availability Verification of Haz Mat training Verification of abatement supplies and procedures Emergency procedures adequate Containers properly labeled Housekeeping Fire Protection Site Diagram Adequate & On Hand C=Compliance V=Violation Any hazardous waste on site?: ^ Yes ^ No Explain: Questions regazding this inspection? Please call us at (661) 326-3979 5-~-~ I I ~.~s I Y~S~~ I ~ ~~ -rod c~.b~~ ~, t ~ ~a~u S -~m his r l O tom? e. ! t '~S S~~ S lh"t"t' Business Site Responsible Party White -Env. Svcs. Yellow -Station Copy Pink - Ausiness Copy Inspector: JOES REFRIGERATION SiteID: 015-021-001143 Manager BusPhone: (661) 834-6808 Location: 4145 PINEWOOD LAKE DR Map 123 CommHaz Minimal City BAKERSFIELD Grid: 14B FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 07 SIC Code: EPA Numb: DunnBrad: Emergency Contact / Title Emer ency Contact / Title PEARL BALDUC / MOTHER LOIS~ROSS / AUNT Business Phone: (661) 834-6808x Business Phone: (661) 832-5433x 24-Hour Phone (661) 834-6808x 24-Hour Phone (661) 832-5433x Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: Fire Press ImmHlth Contact :. ROBERT BALDUC - __ _ _ _Phone: (661) 834-6808x MailAddr: 4145 PINEWOOD LAKE DR State: CA City BAKERSFIELD Zip 93309 Owner ROBERT BALDUC Phone: (661) 834-6808x Address 4145 PINEWOOD LAKE DR State: CA City BAKERSFIELD Zip 93309 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: No Emergency Directives: ~ Hazmat Inventory One Unified List. ~ Alphabetical Order All Materials at Site ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP FREON G FT3 Min FREON F P IH G FT3 Min FREON R22 G 200.00 FT3 Low -1- 10/24/2001 .. • ~ . F DOES REFRIGERATION SiteID: 015-021-001143 ~ ~ Inventory Item 0001 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME FREON Days On Site FREON 409A 365 Location within this Facility Unit Map: Grid: IN VAN CAS# 75-71-8 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas Pure Above Ambient Ambient PORT. PRESS. CYLINDER -~ AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average FT3 FT3 I FT3 HAZARDOUS COMPONENTS $Wt. RS CAS# 100.00 Dichlorodifluoromethane - - No 75718 HAZARD ASSESSMENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Min ~ Inventory Item 0003 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME FREON Days On Site FREON HP81 .365 Location within this Facility Unit Map: Grid: IN VAN CAS# 75-71-8 STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas Pure Above Ambient Ambient PORT. PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average FT3 FT3 FT3 HAGAKllUUS COMPONENTS ~Wt. RS CAS# 100.00 Dichlorodifluoromethane No 75718 HAZARD ASSESSMENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Min -2- 10/24/2001 • F DOES REFRIGERATION SiteID: 015-021-001143 ~ Inventory Item 0002 ~ Facility Unit: Fixed Containers on Site COMMON NAME / CHEMICAL NAME ~ FREON R22 Days On Site 365 Location within this Facility Unit Map: Grid: IN VAN CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas Pure Ambient Ambient _METAL CONTAINR-NONDRUM AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 200.00 FT3 200.00 FT3 200.00 FT3 HAZARDOUS COMPONENTS ~Wt' RS CAS# 100.00 Freon ..22 _ __ _. _ __ _ No 75456 HAZARD ASSESSMENTS TSecret No RS No BioHaz No Radioactive/Amount No/ Curies EPA Hazards NFPA / / / USDOT# MCP Low -3- 10/24/2001 • F JOSS REFRIGERATION SiteID: 015-021-001143 ~ Fast Format ~ ~ Notif./Evacuation/Medical Overall Site ~ Hgency Notification Employee Notif./Evacuation 12/14/1999 EVACUATE BY DRIVING VAN OUT OF GARAGE. ~~ = YUD11C NOt1L./~VaCUatlon -4- 10/24/2001 • • F JOES REFRIGERATION SiteID: 015-021-001143 ~ ~ ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall-Site ~ Release Prevention 12/14/1999 PREVENTION - FIRE EXTINGUISHER. i I = xelease containment -~ -5- 10/24/2001 a • • F JOES REFRIGERATION SiteID: 015-021-001143 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ _, ,_ Special nazaras Utility Shut-Offs 12/14/1999 A) GAS - L SIDE OF CONDO BY GARAGE DOOR B) ELECTRICAL - L SIDE OF CONDO BY GARAGE DOOR C) WATER - R SIDE OF DRIVEWAY NEAR ST D) SPECIAL - NONE E) LOCK BOX - NO Fire Protec./Avail. Water 12/14/1999 PRIVATE FIRE PROTECTION-- -FIRE EXTINGUISHER. - - FIRE HYDRANT - OUTSIDE ENTRANCE TO CONDO COMPLEX. tsuiiaing occupancy Level -6- 10/24/2001 • F JOES REFRIGERATION SiteID: 015-021-001143 ~ Fast Format ~ ~ Training Overall Site ~ Employee Training 01/19/2000 I HAVE 0 EMPLOYEES AT THIS FACILITY. I DO HAVE MATERIAL SAFETY DATA SHEETS ON FILE. BRIEF SUMMARY OF TRAINING: ROBERT BALDUC 40 HRS HAZ MAT COURSE GIVEN BY CHEVRON CORP. `~ = rage L riela zor r~uture vse Bela ror Future Use -~' 10/24/2001 F JOES REFRIGERATION SiteID: 015-021-001143 ~ Full Format Type+Category+Sub-Category+Date2(ASC) Order One Unified List INSPECTIONS Reference Dates Summary Description NICHOLS BORJON BLAIR 11/05/1996 11/17/1995 07/28/1994 11/22/1988 OK OK OK OK `- --_ -- - - Reference Dates Summary Description DEFORD 10/02/1990 OK Reference Dates Summary Description MOORE 09/16/1993 OK Reference Dates Summary Description -8- 10/24/2001 _ ~ 6 F JOES REFRIGERATION SiteID: 015-021-001143 ~ Full Format Type+Category+Sub-Category+Date2(ASC) Order One Unified List Reference Dates Summary Description GEE 08/21/1992 OK -~ Reference Dates Summary Description GUSTIN GUSTIN 10/01/1991. 08/22/1989 OK OK __ __ _ _ BUSINESS PLAN PROGRAM ROUTINE INSPECTION Reference Dates Summary Description WEBER 10/21/2000 LYNCH 12/03/1999 CAPRIOLI 10/21/1998 SUPPLY EXTINGUISHER FOR BORJON 11/06/1997 OK OK OK SPARE VEHICLE. OK -g- 10/24/2001 JOES REFRIGERATION SiteID: 215-000-001143 RF. Manager JA1~17 2000 Bu Phone: (661) 834-6808 Location: 4145 PINEWOOD LAKE D ~ Ma 123 CommHaz Minimal City BAKERSFIELD /j"~ Gr'd: 14B FacUnits: 1 AOV: /BY_-- CommCode: BAKERSFIELD STATION`0~7~ SIC Code: EPA Numb: DunnBrad: Emergency Contact / Title Emergency Contact / Title PEARL BALDUC / rn ,R~a~r+- LOIS GROSS / AvN'f Business Phone: (661) 834-6808x Business Phone: (661) 832-5433x 24-Hour Phone (661) 834-6808x 24-Hour Phone (661) 832-5433x Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: Fire Press ImmHlth Contact I~et~ff~" Ra~~a~ Phone: (661) 834-6808x MailAddr: 4145 PINEWOOD LAKE DR State: CA City BAKERSFIELD Zip 93309 Owner ROBERT BALDUC Phone: (661) 834-6808x Address 4145 PINEWOOD LAKE DR State: CA City BAKERSFIELD Zip 93309 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: No Emergency Directives: ~ Hazmat Inventory One Unified List ~ ~ MCP+DailyMax Order All Materials at Site ~ Hazmat Common Name... SpecHaz EPA Hazards Frm DailyMax Unit MCP FREON R22 G 200.00 FT3 Low FREON G FT3 Min FREON ~, ~~-'+~~ 93a~n~c- Do hereby certify t~at~ have G FT3 Min (type or print name) reviewed the attached hazardous materials ma^age- ment plan for ~o~§ R~~>z~~~r~,and that it along with c ~ ~ any corrections constitute a complete and correct man- agement plan for rey facility. a(,,,~ - /u -~ooo -1- 12/14/1999 i ~ F JOES REFRIGERATION SiteID: 215-000-001143 ~ ~ Inventory Item 0002 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME FREON R22 Days On Site 365 Location within this Facility Unit Map: Grid: IN VAN CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE Gas Pure Ambient Ambient METAL CONTAINR-NONDRUM AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average 200.00 FT3 200.00 FT3 200.00 FT3 HAZARDOUS COMPONENTS %Wt. 100.00 Freon 22 RS CAS# No 75456 r~~rucli f,5 S ~~a~~•~~~v I TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / ' Low ~ Inventory Item 0001 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME FREON ~~~ Days On Site FREON 409A 365 Location within this Facility Unit Map: Grid: IN VAN CAS# 75-71-8 STATE T TYPE PRESSURE TEMPERATURE CONTAINER TYPE ~GaS I Pure Above Ambient Ambient PORT.- PRESS. CYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average FT3 FT3 FT3 HAZARDOUS COMPONENTS %Wt, RS CAS# 100.00 Dichlorodifluoromethane No 75718 HAZARD ASSESSMENTS ,_ ~ ~..~ r._ __ _2_ 12/14/1999 F JOES REFRIGERATION SiteID: 215-000-001143 ~ ~ Inventory Item 0003 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME FREON ~ ~~ Days On Site FREON HP81 365 Location within this Facility Unit Map: Grid: IN VAN CAS# 75-71-8 ~GasATE TPureE ~AboveSAmbEent AmbientT~E PORTCOPRESSERCYLINDER AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average FT3 FT3 I FT3 HAZARDOUS COMPONENTS oWt. 100.00 Dichlorodifluoromethane RSI CAS# No 75718 11C~LIt1itL t9~ 7 ~.7 P~~7 ~71.1P~1V 1~7 -- TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies F P IH / / / Min -3- 12/14/1999 r F JOES REFRIGERATION SiteID: 215-000-001143 ~ Fast Format ~ ~ ~ Notif./Evacuation/Medical Overall Site ~ L"lllL.J1VYGG lYVl..11.~J.:IV Q\.. I.lQV1V11 EVACUATE BY DRIVING VAN OUT OF GARAGE. 14~ 1T.~ 1J J J ruolic NoLi=.~~vacuaLion emergency rieaical rlan -4- 12/14/1999 F JOSS REFRIGERATION SiteID: 215-000-001143 ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall Site ~ ~ Release Prevention 12/14/1999 ~ PREVENTION - FIRE EXTINGUISHER. Release Containment Clean Up Other Resource Activation -5- 12/14/1999 F JOES REFRIGERATION SiteID: 215-000-001143 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ -, - ~- _ ~P~c:idi nci~carus .Utility Shut-Offs 12/14/1999 = A) GAS - L SIDE OF CONDO BY GARAGE DOOR B) ELECTRICAL - L SIDE OF CONDO BY GARAGE DOOR C) WATER - R SIDE OF DRIVEWAY NEAR ST D) SPECIAL - NONE E) LOCK BOX - NO Fire Protec./Avail. Water 12/14/1999 = PRIVATE FIRE PROTECTION - FIRE EXTINGUISHER. FIRE HYDRANT - OUTSIDE ENTRANCE TO CONDO COMPLEX. -6- 12/14/1999 • F JOES REFRIGERATION SiteID: 215-000-001143 ~ Fast Format ~ ~ Training Overall Site ~ Employee Training 12/14/1999 I WE HAVE ?? EMPLOYEES AT THIS FACILITY. Pf DO YOU HAVE MATERIAL SAFETY DATA SHEETS ON FILE??????????? ~/ES~ BRIEF SUMMARY OF TRAINING: ~erogn.7 dAi-ouc.~ 4.o Nn.s l.~z rn~-i CounS~, ~.t ~~N (3y CE+~/a.aw Cr.a+P ~ ~4 ! rage ~ Held for Future Use Held for Future Use -7- 12/14/1999 6 • PO Information in this format is provided as a service to our customers and is intended only for their use. Others may use it at their own discretion and risk. The MSDS format adheres to U.S. standards and regulatory requirements and may not meet regulatory requirements in other locations. This information is based upon technical information DuPont believes to be reliable. It is subject to revision as additional knowledge and experience are gained. Please return to this website for the most current version. "SUVA" 409A 6129FR Revised 17-MAR-1999 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification "SUVA" is a registered trademark of DuPont. Formula CHCLF2/CHCLFCF3/CH3CCLF2 Molecular Weight 97.45 CAS Name FORANE (R) FX-56 GENETRON 409A Tradenames and Synonyms HCFC BLEND OF HCFC-22, HCFC-124 & HCFC-142b Company Identification MANUFACTURER/DISTRIBUTOR DuPont Chemicals 1007 Market Street Wilmington, DE 19898 PHONE NUMBERS Product Information Transport Emergency Medical Emergency 1-800-441-7515 CHEMTREC 1-800-424-9300 1-800-441-3637 COMPOSITION/INFORMATION ON INGREDIENTS • Components Material CAS Number o *CHLORODIFLUOROMETHANE (HCFC-22) 75-45-6 60 *1-CHLORO-l,l-DIFLUOROETHANE 75-68-3 15 (HCFC-142b) *ETHANE, 2-CHLORO-1,1,1,2-TETRAFLUORO 2837-89-0 25 (HCFC-124) * Disclosure as a toxic chemical is required under Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. HAZARDS IDENTIFICATION Potential Health Effects INHALATION: Immediate effects of overexposure may cause central nervous system depression with dizziness, confusion, incoordination, drowsiness or unconsciousness. Gross overexposure may cause: Irregular heart beat with a strange sensation in the chest, "heart thumping", apprehension, lightheadedness, feeling of fainting, dizziness, weakness, sometimes progressing to loss of consciousness and death. Other effects include: Suffocation, if air is displaced by vapors or fatality from gross over-exposure. Decomposition products are hazardous. SKIN CONTACT: Short-term overexposure may cause frostbite, if liquid or escaping vapor contacts the skin. Repeated and/or prolonged exposure may cause: Defatting of the skin with itching, redness or rash. EYE CONTACT: Contact with the vapor or aerosol may cause eye irritation with tearing, pain, blurred vision or "frostbite-like" effects. ADDITIONAL HEALTH EFFECTS: Increased susceptibility to the effects of this material may be observed in persons with pre-existing disease of the: central nervous system, cardiovascular system. Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than 0.1~ are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. FIRST AID MEASURES First Aid INHALATION If inhaled, immediately remove to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT Flush area with lukewarm water. Do not use hot water. If • frostbite has occurred, call a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION Ingestion is not considered a potential route of exposure. Notes to Physicians THIS MATERIAL MAY MAKE THE HEART MORE SUSCEPTIBLE TO ARRHYTHMIAS. Catecholamines such as adrenaline, and other compounds having similar effects, should be reserved for emergencies and then used only with special caution. FIRE FIGHTING MEASURES # Flammable Properties Flash Point Will not burn Flammable limits in Air, % by Volume LEL Not applicable UEL Not applicable Fire and Explosion Hazards: Cylinders may rupture under fire conditions. Decomposition may occur. Contact of welding or soldering torch flame with high concentrations of refrigerant can result in visible changes in the size and color of torch flames. This flame effect will only occur in concentrations of product well above the recommended exposure limit, therefore stop all work and ventilate to disperse refrigerant vapors from the work area before using any open flames. Potential combustibility: "Suva" 409A is not flammable at temperatures up to 100 deg C (212 deg F) at atmospheric pressure. However, mixtures of "Suva" 409A with high concentrations of air at elevated pressure can become combustible at ambient temperature. As the temperature of the mixture is increased, lower pressure (but still greater than atmospheric pressure) can create the same effect. Therefore, "Suva" 409A should not be mixed with air under pressure for leak testing or other purposes. In general, "Suva" 409A should not be used or allowed to exist with high concentrations of air above atmospheric pressure. Extinguishing Media Water Spray, Water Fog, CO2, Dry Chemical, Water. Fire Fighting Instructions Wear self-contained breathing apparatus (SCBA) and full protective equipment. Cool tank/container with water spray. Keep personnel removed and upwind of fire. Shut off source of fuel, if possible and without risk. Water runoff should be contained and neutralized prior to release. Hydrogen fluoride or hydrogen chloride fumes emitted during a fire can react with water to form hydrofluoric acid or hydrochloric acid. Wear neoprene gloves when handling refuse from fire. ACCIDENTAL RELEASE MEASURES # Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Accidental Release Measures Ventilate area using forced ventilation, especially in low or enclosed places where heavy vapors might collect. Remove open flames. Use self-contained breathing apparatus (SCBA) for large spills or releases. HANDLING AND STORAGE Handling (Personnel) Do not get in eyes, on skin or clothing. Do not breathe vapor or mist. Use with sufficient ventilation to keep employee exposure below recommended limits. Wash contaminated clothing prior to reuse. Handling (Physical Aspects) Keep away from heat, sparks and flames. Open container only in well-ventilated area. Storage Keep away from heat, sparks and flames. Store in a well ventilated area away from heat and sunlight. Close container after each use. Store below 120 deg F (49 deg C). EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Use only with adequate ventilation especially for enclosed and low area where vapors can accumulate. Personal Protective Equipment ~: EYE/FACE PROTECTION a Wear coverall chemical splash goggles. RESPIRATORS Wear NIOSH approved respiratory protection, as appropriate. PROTECTIVE CLOTHING Where there is potential for skin contact have available, and wear as appropriate, impervious gloves, apron, pants, and jacket. Lined butyl gloves should be used to avoid prolonged or repeated exposure. Exposure Guidelines Applicable Exposure Limits CHLORODIFLUOROMETHANE (HCFC-22) PEL (OSHA) None Established TLV (ACGIH) 1,000 ppm, 3,540 mg/m3, 8 Hr. TWA, A4 AEL * (DuPont) None Established 1-CHLORO-I,I-DIFLUOROETHANE PEL (OSHA) None Established TLV (ACGIH) None Established AEL * (DuPont) 1000 ppm, 8 Hr. TWA WEEL (AIHA) 1000 ppm, 8 Hr. TWA ETHANE, 2-CHLORO-1,1,1,2-TETRAFLUORO PEL (OSHA) None Established TLV (ACGIH) None Established AEL * (DuPont) 1000 ppm, 8 & 12 Hr. TWA WEEL (AIHA) 1000 ppm, 8 Hr. TWA * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. PHYSICAL AND CHEMICAL PROPERTIES Physical Data Boiling Point -31 F (-35 C) Vapor Density 3.36 (Air=1.0) Solubility in Water Negligible Specific Gravity 1.215 @ 70 F (21 C) Vapor Pressure 107 psia @ 70 F (21 C) Volatiles 100 0 Odor Faint, Ethereal, Ether. Form Liquified Gas. Color Clear, Colorless. STABILITY AND REACTIVITY Chemical Stability Stable. Conditions contributing to instability: Thermal decomposition due to exposure to heat (>800 deg F) or fire. • Conditions to Avoid Avoid flames, sparks, extremely hot metal, heating elements, pilot lights, static electricity, combustion engines, ignition sources, etc. Incompatibility with Other Materials Avoid contact with strong alkali or alkaline earth metals, finely powdered metals such as aluminum, magnesium or zinc and strong oxidizers since they may react with or accelerate decomposition of this material. Decomposition Thermal decomposition products include hydrogen fluoride, hydrogen chloride, carbon monoxide, carbon dioxide and chlorine and possibly carbonyl halides. These materials are toxic and irritating. Contact should be avoided. TOXICOLOGICAL INFORMATION Animal Data CHLORODIFLUOROMETHANE (HCFC-22) INHALATION: 4 hour, LC50, rat: 220,000 ppm Animal testing indicates this material is a slight eye and skin irritant, but not a skin sensitizer. INGESTION: Long-term exposure caused: No significant toxicological effects. Single exposure to high doses caused: Central nervous system depression. Inactivity or anaesthesia. Lung noise. Altered respiratory rate. Histopathological changes of the liver. Cardiac sensitization, a potentially fatal disturbance of heart rhythm associated with a heightened sensitivity to the action of epinephrine. Repeated exposure caused: No significant toxicological effects. Long-term exposure caused: Reduced weight gain. Increased adrenals, kidney, liver, pituitary weight. ADDITIONAL TOXICOLOGICAL EFFECTS: In chronic inhalation studies, HCFC-22, at a concentration of 50,000 ppm (v/v), produced a small, but statistically significant increase of late-occurring tumors involving salivary glands in male rats, but not female rats or male or female mice. In the same studies, no increased incidence of tumors was seen in either species at concentrations of 10,000 ppm or 1000 ppm (v/v). Animal data show developmental effects only at exposure levels producing other toxic effects in the adult animal. This material is not considered a unique developmental hazard to the conceptus. Reproductive data on male animals show: No change in reproductive performance. Specific studies to evaluate the effect on female reproductive performance have not been conducted; however, limited information obtained from studies on developmental toxicity do not indicate adverse effects on female reproductive performance. This material • produces genetic damage in bacterial cell cultures. In mammalian cell cultures and animals, this material has not produced genetic toxicity. In animal testing, this material has not caused permanent genetic damage in reproductive cells of mammals (has not produced heritable genetic damage). 1-CHLORO-l,l-DIFLUOROETHANE (HCFC-142b) - Inhalation 2 hour LC50: 447,642 ppm in rats The compound is untested for skin irritancy, is not an eye irritant, and is untested for animal sensitization. Inhalation: Toxic effects of single inhalation exposures include respiratory irritation, loss of reflexes, and unconsciousness. Cardiac sensitization was seen in dogs exposed to concentrations of 5o and higher. Exposure of dogs or monkeys to concentrations of 5 to 20$ for five minutes caused decreased blood pressure (hypotension). Repeated exposure produced only irritation of the lungs. Tests in animals demonstrate no carcinogenic, developmental, or reproductive toxicity. The compound does not produce genetic damage in animals or in bacterial and mammalian cell cultures. It does not produce heritable genetic damage. ETHANE, 2-CHLORO-1,1,1,2-TETRAFLUORO (HCFC-124) INHALATION: 4 hour, ALC, rat: 230,000 - 300,000 ppm. Single exposure caused: Cardiac sensitization, a potentially fatal disturbance of heart rhythm associated with a heightened sensitivity to the action of epinephrine. Lowest-Observed-Adverse-Effect-Level for cardiac sensitization: 25,000 ppm. Single exposure caused: the following temporary effects - Inactivity or anaesthesia. Low blood pressure. Repeated exposure caused: Decreased body weight. Altered clinical chemistry. These effects were reversible. Repeated exposure caused: the following temporary effects - Inactivity or anaesthesia. Lethargy. Incoordination. Altered respiratory rate. One study showed: Increased liver weight. CARCINOGENIC, DEVELOPMENTAL, REPRODUCTIVE, MUTAGENIC EFFECTS: In animal testing this material has not caused carcinogenicity, developmental toxicity. No animal data are available to define the following effects of this material: reproductive toxicity. Tests have shown that this material does not cause genetic damage in bacterial or mammalian cell cultures, or in animals. This material has not been tested for its ability to cause permanent genetic damage in reproductive cells of mammals (not tested for heritable genetic damage). ECOLOGICAL INFORMATION Ecotoxicological Information ! - AQUATIC TOXICITY: CHLORODIFLUOROMETHANE (HCFC-22) 48 hour EC50 - Daphnia magna: 433 mg/L DISPOSAL CONSIDERATIONS Waste Disposal Recycle or reclaim if possible. Reclaimed material may be incinerated but toxic and corrosive combustion products (HF and HCL) must be handled appropriately. Consult Federal, State or local authorities for proper disposal procedures. TRANSPORTATION INFORMATION Shipping Information DOT/IMO/IATA Proper Shipping Name Hazard Class UN No. DOT/IMO Label LIQUEFIED GAS, N.O.S. (CHLORODIFLUOROMETHANE, CHLOROTETRAFLUOROETHANE) . 2.2 UN 3163 NONFLAMMABLE GAS OTHER INFORMATION NFPA, NPCA-HMIs NPCA-HMIs Rating Health 1 Flammability 0 Reactivity 1 The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS DuPont Chemicals Address Engineering & Product Safety > P.O. Box 80709, Chestnut Run > Wilmington, DE 19880-0709 Telephone (302) 999-4946 # Indicates updated section. End of MSDS • U PO Information in this format is provided as a service to our customers and is intended only for their use. Others may use it at their own discretion and risk. The MSDS format adheres to U.S. standards and regulatory requirements and may not meet regulatory requirements in other locations. This information is based upon technical information DuPont believes to be reliable. It is subject to revision as additional knowledge and experience are gained. Please return to this website for the most current version. "SUVA" HP81(R402B) 6000FR Revised 24-MAR-1999 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification "SUVA" is a registered trademark of DuPont. Corporate MSDS Number DU005603 Company Identification MANUFACTURER/DISTRIBUTOR DuPont 1007 Market Street Wilmington, DE 19898 PHONE NUMBERS Product Information Transport Emergency Medical Emergency 1-800-441-9442 CHEMTREC: 1-800-424-9300 1-800-441-3637 COMPOSITION/INFORMATION ON INGREDIENTS ---- Components Material CAS Number o ETHANE, PENTAFLUORO- (HFC-125) 354-33-6 38 *METHANE, CHLORODIFLUORO- (HCFC-22) 75-45-6 60 PROPANE 74-98-6 2 r~ * Disclosure as a toxic chemical is required under Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. HAZARDS IDENTIFICATION Potential Health Effects Inhalation of high concentrations of vapor is harmful and may cause heart irregularities, unconsciousness, or death. Intentional misuse or deliberate inhalation may cause death without warning. Vapor reduces oxygen available for breathing and is heavier than air. Liquid contact can cause frostbite. HUMAN HEALTH EFFECTS: Overexposure to the vapors by inhalation may include temporary nervous system depression with anesthetic effects such as dizziness, headache, confusion, incoordination, and loss of consciousness. Higher exposures to the vapors may cause temporary alteration of the heart's electrical activity with irregular pulse, palpitations, or inadequate circulation. Fatality may occur from gross overexposure. Skin contact with the liquid may cause frostbite. Individuals with preexisting diseases of the central nervous or cardiovascular system may have increased susceptibility to the toxicity of increased exposures. Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than 0.1~ are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. FIRST AID MEASURES First Aid INHALATION If inhaled, immediately remove to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT Flush area with lukewarm water. Do not use hot water. If frostbite has occurred, call a physician. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION Not a probable route. However, in case of accidental ingestion, call a physician. Notes to Physicians THIS MATERIAL MAY MAKE THE HEART MORE SUSCEPTIBLE TO ARRHYTHMIAS. Catecholamines such as adrenaline, and other compounds having similar effects, should be reserved for emergencies and then used only with special caution. FIRE FIGHTING MEASURES # Flammable Properties Flash Point Will not burn Flammable limits in Air, ~ by Volume LEL Not applicable UEL Not applicable Fire and Explosion Hazards: Cylinders may rupture under fire conditions. Decomposition may occur. Contact of welding or soldering torch flame with high concentrations of refrigerant can result in visible changes in the size and color of torch flames. This flame effect will only occur in concentrations of product well above the recommended exposure limit, therefore stop all work and ventilate to disperse refrigerant vapors from the work area before using any open flames. Potential combustibility: "Suva" HP81 is not flammable at temperatures up to 100 deg C (212 deg F) at atmospheric pressure. However, mixtures of "Suva" HP81 with high concentrations of air at elevated pressure can become combustible at ambient temperature. As the temperature of the mixture is increased, lower pressure (but still greater than atmospheric pressure) can create the same effect. Therefore, "Suva" HP81 should not be mixed with air under pressure for leak testing or other purposes. In general, "Suva" HP81 should not be used or allowed to exist with high concentrations of air above atmospheric pressure. Extinguishing Media As appropriate for combustibles in area. Fire Fighting Instructions Keep cylinders cool with water spray or fog. Self-contained breathing apparatus (SCBA) is required if cylinders rupture and contents are released under fire conditions. Water runoff should be contained and neutralized prior to release. ACCIDENTAL RELEASE MEASURES Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Accidental Release Measures Remove open flames. Use self-contained breathing apparatus (SCBA) for large spills or releases. HANDLING AND STORAGE Handling (Personnel) Avoid breathing vapors. Avoid liquid contact with skin or eyes. Use with sufficient ventilation to keep employee exposure below the recommended limits. Avoid prolonged or repeated exposure. Wash thoroughly after handling. Storage Clean, dry area. Do not heat above 52 deg C (125 deg F). EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Refrigerant concentration monitors may be necessary to determine vapor concentrations in work areas prior to use of torches or other open flames, or if employees are entering enclosed areas. Use with sufficient ventilation to keep employee exposure below the recommended exposure limit. Local exhaust should be used if large amounts are released. Mechanical ventilation should be used in low or enclosed places. Personal Protective Equipment Impervious gloves should be used to avoid prolonged or repeated exposure. Chemical splash goggles should be available for use as needed to prevent eye contact. Under normal manufacturing conditions, no respiratory protection is required when using this product. Self-contained breathing apparatus (SCBA) is required if a large release occurs. Exposure Guidelines Applicable Exposure Limits ETHANE, PENTAFLUORO- (HFC-125) PEL (OSHA) None Established TLV (ACGIH) None Established AEL * (DuPont) 1000 ppm, 8 & 12 Hr. TWA WEEL (AIHA) 1000 ppm, 4900 mg/m3, 8 Hr. TWA METHANE, CHLORODIFLUORO- (HCFC-22) PEL (OSHA) None Established TLV (ACGIH) 1,000 ppm, 3,540 mg/m3, 8 Hr. TWA, A4 AEL * (DuPont) None Established PROPANE PEL (OSHA) 1,000 ppm, 1,800 mg/m3, 8 Hr. TWA TLV (ACGIH) 2500 ppm, 8 Hr. TWA AEL * (DuPont) None Established * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. PHYSICAL AND CHEMICAL PROPERTIES Physical Data Boiling Point Vapor Pressure $ Volatiles Evaporation Rate Solubility in Water Odor Form Color Density . -47.4 C (-53.3 F) Average 179.6 Asia at 25 deg C (77 deg F) 100 WT$ (CC14 = 1) Greater than 1 Not determined Slight ethereal Liquefied gas Clear, colorless 1.14 gm/cc at 25 deg C (77 deg F) - Liquid STABILITY AND REACTIVITY Chemical Stability Material is stable. However, avoid open flames and high temperatures. Incompatibility with Other Materials Incompatible with alkali or alkaline earth metals - powdered A1, Zn, Be, etc. Decomposition Decomposition products are hazardous. "SUVA" HP81 can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrochloric and hydrofluoric acids and possibly carbonyl halides. These materials are toxic and irritating. Contact should be avoided. Polymerization Polymerization will not occur. TOXICOLOGICAL INFORMATION Animal Data The blend is untested. ETHANE, PENTAFLUORO Inhalation 4 hour ALC: > 709,000 ppm in rats Single, high inhalation exposures caused lethargy, decreased activity, labored breathing and weight loss. Weak cardiac sensitization effect, a potentially fatal disturbance of heart rhythm caused by a heightened sensitivity to the action of epinephrine. Lowest-Observed-Adverse-Effects-Level for cardiac sensitization: 100,000 ppm. i Repeated exposure caused: No significant toxicological effects. No-Observed-Adverse-Effect-Level(NOAEL): 50,000 ppm No animal data are available to define carcinogenic, developmental or reproductive hazards. In animal testing this material has not caused developmental toxicity. HFC-125 does not produce genetic damage in bacterial or mammalian cell cultures or when tested in animals (not tested for heritable genetic damage). METHANE, CHLORODIFLUORO Inhalation 4-hour LC50: 220,000 ppm in rats The compound is a skin irritant and a slight eye irritant, but is not a skin sensitizer in animals. Effects from single high exposures include central nervous system depression, anesthesia, rapid breathing, lung congestion and microscopic liver changes. Cardiac sensitization occurred in dogs at 50,000 ppm or greater from the action of exogenous epinephrine. No toxic effects or abnormal histopathological observations occurred in rats repeatedly exposed to concentrations ranging from 10,000 to 50,000 ppm (v/v). Long-term exposures to 50,000 ppm (v/v) of vapors produced organ weight increases and a decrease in body weight gain, but no increased mortality or adverse hematological effects. In chronic inhalation studies, HCFC-22, at a concentration of 50,000 ppm (v/v), produced a small, but statistically significant increase of late-occurring tumors involving salivary glands in male rats, but not female rats or male or female mice. In the same studies, no increased incidence of tumors was seen in either species at concentrations of 10,000 ppm or 1000 ppm (v/v). Long-term administration in corn oil produced no effects on body weight or mortality. HCFC-22 was mutagenic in some strains of bacteria in bacterial cell cultures, but not mammalian cell cultures or animals. It did not cause heritable genetic damage in mamma 1 s . A slight, but significant increase in developmental toxicity was observed at high concentrations (50,000 ppm) of HCFC-22, a concentration which also produced toxic effects in the adult animal. Based on these findings, and other negative developmental studies, HCFC-22 is not considered a unique hazard to the conceptus. Studies of the effects of HCFC-22 on male reproductive performance have been negative. Specific studies to evaluate the effect on female reproductive performance have not been conducted, however, limited information obtained from studies on developmental toxicity do not indicate adverse effects on female reproductive performance at concentrations up to 50,000 ppm. PROPANE Toxicity in animals occurring only with inhalation exposures • at high concentrations (10~ or greater) include cardiac sensitization, analgesia, irregular respiration and hypotension. No animal test reports are available to define carcinogenic, developmental, or reproductive hazards. Tests in bacteria cell cultures demonstrate no mutagenic activity. ECOLOGICAL INFORMATION Ecotoxicological Information Aquatic Toxicity: HCFC-22 48 hour EC50 - Daphnia magna: 433 mg/L DISPOSAL CONSIDERATIONS Waste Disposal Comply with Federal, State, and local regulations. Reclaim by distillation or remove to a permitted waste disposal facility. TRANSPORTATION INFORMATION Shipping Information DOT/IMO Proper Shipping Name Hazard Class UN No. DOT/IMO Label Shipping Containers Tank Cars. Cylinders Ton Tanks LIQUEFIED GAS, N.O.S. (CHLORODIFLUOROMETHANE AND PENTAFLUOROETHANE) . 2.2 3163 NONFLAMMABLE GAS REGULP,TORY INFORMATION U.S. Federal Regulations TSCA Inventory Status Reported/Included. TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 Acute Yes Chronic No Fire No Reactivity No Pressure Yes HAZARDOUS CHEMICAL LISTS SARA Extremely Hazardous Substance: No CERCLA Hazardous Substance No Y ~ • SARA Toxic Chemical - See Components Section OTHER INFORMATION NFPA, NPCA-HMIS NPCA-HMIS Rating Health 1 Flammability 0 Reactivity 1 Personal Protection rating to be supplied by user depending on use conditions. Additional Information MEDICAL USE: CAUTION: Do not use in medical applications involving permanent implantation in the human body. For other medical applications see DuPont CAUTION Bulletin No. H-50102. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS DuPont Chemicals Address Engineering & Product Safety > P.O. Box 80709, Chestnut Run > Wilmington, DE 19880-0709 Telephone (302) 999-4946 # Indicates updated section. End of MSDS 4Y b • Information in this format is provided as a service to our customers and is intended only for their use. Others may use it at their own discretion and risk. The MSDS format adheres to U.S. standards and regulatory requirements and may not meet regulatory requirements in other locations. This information is based upon technical information DuPont believes to be reliable. It is subject to revision as additional knowledge and experience are gained. Please return to this website for the most current version. "FREON" 12 2022FR Revised 7-OCT-1996 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification "FREON" is a registered trademark of DuPont. Corporate MSDS Number DU001065 Formula CC12F2 Tradenames and Synonyms 000112 Company Identification MANUFACTURER/DISTRIBUTOR DuPont 1007 Market Street Wilmington, DE 19898 PHONE NUMBERS Product Information Transport Emergency Medical Emergency 1-800-441-9442 CHEMTREC: 1-800-424-9300 1-800-441-3637 COMPOSITION/INFORMATION ON INGREDIENTS 1 Components Material * *METHANE, DICHLORODIFLUORO- ("FREON" 12) CAS Number o 75-71-8 100 * Disclosure as a toxic chemical is required under Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 -- and 40 CFR part 372. HAZARDS IDENTIFICATION Potential Health Effects Inhalation of high concentrations of vapor is harmful and may cause heart irregularities, unconsciousness, or death. Intentional misuse or deliberate inhalation may cause death without warning. Vapor reduces oxygen available for breathing and is heavier than air. Liquid contact can cause frostbite. May cause eye irritation. HUMAN HEALTH EFFECTS: Human health effects of overexposure by eye contact with the vapor may include eye irritation with discomfort, tearing, or blurring of vision. Skin contact with the liquid may cause frostbite. Inhalation of the vapors may cause temporary nervous system depression with anesthetic effects such as dizziness, headache, confusion, incoordination, and loss of consciousness; temporary alteration of the heart's electrical activity with irregular pulse, palpitations, or inadequate circulation, or the effects of exclusion of oxygen with grossly excessive exposures. Individuals with preexisting diseases of the central nervous or cardiovascular system may have increased susceptibility to the toxicity of excessive exposures. Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than O.lo are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. FIRST AID MEASURES First Aid INHALATION If high concentrations are inhaled, immediately remove to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT In case of contact, flush skin with water. Treat for frostbite if necessary by gently warming affected area. EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. s 2 ` ~ • .> INGESTION Ingestion is not considered a potential route of exposure. Notes to Physicians ' Because of a possible disturbance of cardiac rhythm, catecholamine drugs, such as epinephrine, should only be used with special caution in situations of emergency life support. FIRE FIGHTING MEASURES Flammable Properties Flash Point Will not burn Flammable limits in Air, $'by Volume LEL Not applicable UEL Not applicable Autoignition >750 C (>1382 F) Fire and Explosion Hazards: Cylinders may rupture under fire conditions. Decomposition may occur. Extinguishing Media As appropriate for combustibles in area. Fire Fighting Instructions Use water spray or fog to cool containers. Self-contained breathing apparatus (SCBA) is required if cylinders rupture and contents are released under fire conditions. Water runoff should be contained and neutralized prior to release. ACCIDENTAL RELEASE MEASURES Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Accidental Release Measures Ventilate area, especially low or enclosed places where heavy vapors might collect. Remove open flames. Use self-contained breathing apparatus (SCBA) for large spills. HANDLING AND STORAGE Handling (Personnel) Use with sufficient ventilation to keep employee exposure below recommended limits. Storage Clean, dry area. Do not heat above 52 deg C (125 deg F). 3 • EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Normal ventilation for standard manufacturing procedures is generally adequate. Local exhaust should be used when large amounts are released. Mechanical ventilation should be used in low or enclosed places. Personal Protective Equipment Impervious gloves and chemical splash goggles should be used when handling liquid. Under normal manufacturing conditions, no respiratory protection is required when using this product. Self-contained breathing apparatus (SCBA) is required if a large release occurs. # Exposure Guidelines Applicable Exposure Limits METHANE, DICHLORODIFLUORO- ("FREON" 12) PEL (OSHA) 1,000 ppm, 4,950 mg/m3, 8 Hr. TWA TLV (ACGIH) 1,000 ppm, 4,950 mg/m3, 8 Hr. TWA, A4 AEL * (DuPont) None Established * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. PHYSICAL AND CHEMICAL PROPERTIES Physical Data Boiling Point -29.8 C (-21.6 F) Vapor Pressure 94.5 psia at 25 deg C (77 deg F) Vapor Density 4.26 (Air = 1.0) at 25 deg C (77 deg F) °s Volatiles 100 WTa Solubility in Water 0.028 WT$ @ 25 C (77 F) at 1 atm pH Neutral Odor Slight ethereal Form Liquified gas Color Clear, colorless Density 1.315 g/cc at 25 deg C (77 deg F) - Liquid STABILITY AND REACTIVITY Chemical Stability Material is stable. However, avoid open flames and high temperatures. Incompatibility with Other Materials Incompatible with alkali or alkaline earth metals- powdered Al, Zn, Be, etc. Decomposition 4 ~- ! Decomposition products are hazardous. "Freon" 12 can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrochloric and hydrofluoric acids, and possibly carbonyl halides. These materials are toxic and irritating. Contact should be avoided. Polymerization Polymerization will not occur. TOXICOLOGICAL INFORMATION Animal Data Inhalation 30-minute LC50: 800,000 ppm in rats Oral ALD >1,000 mg/kg in rats Effects in animals from single high exposure by inhalation include anesthesia and irregular heartbeat (cardiac arrythmias). Repeated inhalation exposures produced altered respiratory function. Long-term studies showed no significant clinical, blood chemistry or pathological effects following repeated exposures. The effects in animals from long-term ingestion of this material include slight alterations in blood chemistry and body weight gain. No other clinical, biochemical or pathological signs of toxicity have been observed. Tests in animals demonstrate no carcinogenic activity and no developmental or reproductive toxicity. The compound does not produce heritable genetic damage in animals or genetic damage in bacterial and mammalian cell cultures. ECOLOGICAL INFORMATION Ecotoxicological Information AQUATIC TOXICITY: "FREON" 12: 48 hour EC50 - Daphnia magna: 95 mg/L. DISPOSAL CONSIDERATIONS Waste Disposal Comply with Federal, State, and local regulations. Reclaim by distillation or remove to a permitted waste facility. TRANSPORTATION INFORMATION Shipping Information DOT/IMO Proper Shipping Name Hazard Class UN No. DOT/IMO Label Shipping Containers DICHLORODIFLUOROMETHANE . 2.2 1028 NONFLAMMABLE GAS 5 • Tank Cars. Cylinders Ton Tanks Reportable Quantity 5,000 lbs./2,270 kg. REGULATORY INFORMATION U.S. Federal Regulations TSCA Inventory Status Reported/Included. TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 Acute Yes Chronic No Fire No Reactivity No Pressure Yes HAZARDOUS CHEMICAL LISTS SARA Extremely Hazardous Substance - No CERCLA Hazardous Substance - Yes SARA Toxic Chemical - See Components Section Superfund reportable discharge = 5000 lb. OTHER INFORMATION NFPA, NPCA-HMIS NPCA-HMIS Rating Health 1 Flammability 0 Reactivity 1 Personal Protection rating to be supplied by user depending on use conditions. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS DuPont Chemicals Address Engineering & Product Safety > P.O. Box 80709, Chestnut Run > Wilmington, DE 19880-0709 Telephone (302) 999-4946 # Indicates updated section. End of MSDS 6 4 . , r UPO , Information in this format is provided as a service to our customers and is intended only for their use. Others may use it at their own discretion and risk. The MSDS format adheres to U.S. standards and regulatory requirements and may not meet regulatory requirements in other locations. This information is based upon technical information DuPont believes to be reliable. It is subject to revision as additional knowledge and experience are gained. Please return to this website for the most current version. "FREON" 22 2008FR Revised 5-OCT-1996 CHEMICAL PRODUCT/COMPANY IDENTIFICATION Material Identification Corporate MSDS Number DU000025 Formula CHC1F2 Molecular Weight 86.47 CAS Name "FREON" 22 Tradenames and Synonyms CHLORODIFLUOROMETHANE HCFC-22 000335 Company Identification MANUFACTURER/DISTRIBUTOR DuPont 1007 Market Street Wilmington, DE 19898 PHONE NUMBERS Product Information Transport Emergency Medical Emergency 1-800-441-9442 CHEMTREC: 1-800-424-9300 1-800-441-3637 COMPOSITION/INFORMATION ON INGREDIENTS 1 Components i Material CAS Number *METHANE, CHLORODIFLUORO- (HCFC 22) 75-45-6 100 * Disclosure as a toxic chemical is required under Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. HAZARDS IDENTIFICATION Potential Health Effects Inhalation of high concentrations of vapor is harmful and may cause heart irregularities, unconsciousness or death. Intentional misuse or deliberate inhalation may cause death without warning. Vapor reduces oxygen available for breathing and is heavier than air. Liquid contact can cause frostbite. HUMAN HEALTH EFFECTS: Skin contact with the liquid may include frostbite. Prolonged overexposure may cause defatting or dryness of the skin. Eye contact with liquid may include eye irritation with discomfort, tearing, or blurring of vision. Inhalation may include temporary nervous system depression with anesthetic effects such as dizziness, headache, confusion, incoordination, and loss of consciousness. Higher exposures may lead to temporary alteration of the heart's electrical activity with irregular pulse, palpitations, or inadequate circulation. Fatality may occur from gross overexposure. Individuals with preexisting diseases of the central nervous or cardiovascular system may have increased susceptibility to the toxicity of excessive exposures. Carcinogenicity Information None of the components present in this material at concentrations equal to or greater than 0.1$ are listed by IARC, NTP, OSHA or ACGIH as a carcinogen. FIRST AID MEASURES First Aid INHALATION If inhaled, immediately remove to fresh air. Keep person calm. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT In case of contact, flush area with lukewarm water.- Do-not use hot water. If frostbite has occurred, call a physician. 2 ti • f EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION Ingestion is not considered a potential route of exposure. Notes to Physicians Because of possible disturbances of cardiac rhythm, catecholamine drugs, such as epinephrine, should only be used with special caution in situations of emergency life support. FIRE FIGHTING MEASURES Flammable Properties Flash Point : Will not burn Autodecomposition 632 C (1170 F) Other burning materials may cause HCFC-22 to burn weakly. Chlorodifluoromethane is not flammable at ambient temperatures and atmospheric pressure. However, chlorodifluoromethane has been shown in tests to be combustible at pressures as low as 60 psig at ambient temperature when mixed with air at concentrations of 65 volume $ air. Experimental data have also been reported which indicate combustibility of "FREON" 22 in the presence of certain concentrations of chlorine. Fire and Explosion Hazards: Cylinders may rupture under fire conditions. Decomposition may occur. Extinguishing Media As appropriate for combustibles in area. Extinguishant for other burning material in area is sufficient to stop burning. Fire Fighting Instructions Use water spray or fog to cool containers. Self-contained breathing apparatus (SCBA) is required if cylinders rupture or contents are released under fire conditions. Water runoff should be contained and neutralized prior to.release. ACCIDENTAL RELEASE MEASURES Safeguards (Personnel) NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up. Accidental Release Measures 3 • Ventilate area, especially low or enclosed places where heavy vapors might collect. Remove open flames. Use self-contained breathing apparatus (SCBA) for large spills or releases. HANDLING AND STORAGE Handling (Personnel) Use with sufficient ventilation to keep employee exposure below recommended limits. "FREON" 22 should not be mixed with air for leak testing. In general, it should not be used or allowed to be present with high concentrations of air above atmospheric pressure. Contact with chlorine or other strong oxidizing agents should also be avoided. Storage Clean, dry area. Do not heat above 52 C (125 F). EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Normal ventilation for standard manufacturing procedures is generally adequate. Local exhaust should be used when large amounts are released. Mechanical ventilation should be used in low or enclosed places. Personal Protective Equipment Impervious gloves and chemical splash goggles should be used when handling liquid. Under normal manufacturing conditions, no respiratory protection is required when using this product. Self-contained breathing apparatus (SCBA) is required if a large release occurs. # Exposure Guidelines Applicable Exposure Limits METHANE, CHLORODIFLUORO- (HCFC 22) PEL (OSHA) ~ None Established TLV (ACGIH) 1,000 ppm, 3,540 mg/m3, 8 Hr. TWA, A4 AEL * (DuPont) None Established * AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence. PHYSICAL AND CHEMICAL PROPERTIES Physical Data Boiling Point Vapor Pressure Vapor Density Volatiles Evaporation Rate Solubility in Water pH 4 -40.8 C (-41.4 151 psig @ 25 3.03 (Air=1.0) 100 WT°s 0.3 WT$ @ 25 C Neutral F) C (77 F) @ 25 C (77 F) (77 F) • Odor Slight ethereal Form Liquified Gas. Color Clear, Colorless. Liquid Density 1.194 g/cm3 @ 25 C (77 F) STABILITY AND REACTIVITY Chemical Stability Material is stable. However, avoid open flames and high temperatures. Incompatibility with Other Materials Incompatible with alkali or alkaline earth metals--powdered Al, Zn, Be, etc. Decomposition Decomposition products are hazardous. HCFC-22 can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming hydrochloric and hydrofluoric acids, and possibly carbonyl halides. These materials are toxic and irritating. Contact should be avoided. Polymerization Polymerization will not occur. TOXICOLOGICAL INFORMATION Animal Data INHALATION: 4 hour, LC50, rat: 220,000 ppm. The compound is a skin irritant and a slight eye irritant, but is not a skin sensitizer in animals. Effects from single high exposures include central nervous system depression, anesthesia, rapid breathing, lung congestion and microscopic liver changes. Cardiac sensitization occurred in dogs at 50,000 ppm or greater from the action of exogenous epinephrine. No toxic effects or abnormal histopathological observations occurred in rats repeatedly exposed to concentrations ranging from 10,000 to 50,000 ppm (v/v). Long-term exposures to 50,000 ppm (v/v) of vapors produced organ weight increases and a decrease in body weight gain, but no increased mortality or adverse hematological effects. In chronic inhalation studies, HCFC-22, at a concentration of 50,000 ppm (v/v), produced a small, but statistically significant increase of late-occurring tumors involving salivary glands in male rats, but not female rats or male or female mice. In the same studies, no increased incidence of tumors was seen in either species at concentrations of 10,000 ppm or 1,000 ppm (v/v). Long-term administration in corn oil produced no effects on 5 L body weight or mortality. HCFC-22 was mutagenic in some strains of bacteria in bacterial cell cultures, but not mammalian cell cultures or animals. It did not cause heritable genetic damage in mamma 1 s . A slight, but significant increase in developmental toxicity was observed at high concentrations (50,000 ppm) of HCFC-22, a concentration which also produced toxic effects in the adult animal. Based on these findings, and other negative developmental studies, HCFC-22 is not considered a unique hazard to the conceptus. Studies of the effects of HCFC-22 on male reproductive performance have been negative. Specific studies to evaluate the effect on female reproductive performance have not been conducted, however, limited information obtained from studies on developmental toxicity do not indicate adverse effects on female reproductive performance at concentrations up to 50,000 ppm. ECOLOGICAL INFORMATION Ecotoxicological Information Aquatic Toxicity: HCFC-22 48 hour EC50 - Daphnia magna: 433 mg/L DISPOSAL CONSIDERATIONS Waste Disposal Comply with Federal, State, and local regulations. Reclaim by distillation or remove to a permitted waste disposal facility. TRANSPORTATION INFORMATION Shipping Information DOT/IMO Proper Shipping Name CHLORODIFLUOROMETHANE Hazard Class 2.2 UN No. 1018 DOT/IMO Label NONFLAMMABLE GAS Shipping Containers Tank Cars. Tank Trucks. Cylinders. REGULATORY INFORMATION U.S. Federal Regulations TSCA Inventory Status Reported/Included. TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312 6 ,- ~_ Acute Yes Chronic No Fire No Reactivity No Pressure Yes HAZARDOUS CHEMICAL LISTS SARA Extremely Hazardous Substance: No CERCLA Hazardous Substance : No SARA Toxic Chemical - See Components Section OTHER INFORMATION -- NFPA, NPCA-HMIS NPCA-HMIS Rating Health 1 Flammability 0 Reactivity : 1 Personal Protection rating to be supplied by user depending on use conditions. ---------------------------------------------------------------------- The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. Responsibility for MSDS DuPont Chemicals Address Engineering & Product Safety > P.O. Box 80709, Chestnut Run > Wilmington, DE 19880-0709 Telephone (302) 999-4946 - # Indicates updated section. End of MSDS 7 .: ~ • JOES REFRIGERATION SiteID: 215-000-001143 Manager Location: 4145 PINEWOOD LAKE DR City BAKERSFIELD BusPhone: (805) 834-6808 Map 123 CommHaz Minimal Grid: 14B FacUnits: 1 AOV: CommCode: BAKERSFIELD STATION 07 EPA Numb: SIC Code: DunnBrad: Emergency Contact / Title Emergency Contact / Title PEARL BALDUC / ~3~.(-(o~o~ LOIS GROSS / Business Phone: (805)lx Business Phone: (805) 832-5433x 24-Hour Phone (805) 834-6808x~ 24-Hour Phone (805) 832-5433x Pager Phone ( ) - x Pager Phone ( ) - x Hazmat Hazards: Contact Phone: ( ) - x MailAddr: 4145 PINEWOOD LAKE DR State: CA City BAKERSFIELD Zip 93309 Owner R6 DPr~t 3~i~oP~.c~ Phone: (805) 834-6808x Address 4145 PINEWOOD LAKE DR State: CA City BAKERSFIELD Zip 93309 Period to TotalASTs: = Gal Preparers TotalUSTs: = Gal Certif'd: RSs: No .Emergency Directives: ~ Hazmat Inventory One Unified List ~ ~ Alphabetical Order All Materials at Site ~ Hazmat Common Name... ISpecHazIEPA Hazards) Frm I DailyMax IUnitIMCPI FREON R22 ~~- Qc ~••rl P S I ~~f Q ev'se 200 FT3 Lowl 3o rti ;~:,5 30 ~h J~~ -1- 08/12/1999 • • F DOES REFRIGERATION Site ID: 215-000-001143 ~ ~ Inventory Item 0001 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME FREON R-12 Days On Site Location within this Facility Unit Ma : Grid p : IN VAN CAS# STATE TYPE TPure ~ PRESSURE TEMPERATURE CONTAINER TYPE ~ METAL CONTAINR-NONDRUM AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average FT3 285.00 FT3 I FT3 11AL.,ri[<LVI./,7 ~,vl•lrvlvr,ly t ~ %Wt. RS CAS# 100.00 Freon 12 No 75718 rJtic,tiRL ti. 7.7L',,7.71•1L',ly 1.7 TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Min ~ Inventory Item 0002 Facility Unit: Fixed Containers on Site ~ COMMON NAME / CHEMICAL NAME FREON R22 Days On Site Location within this Facility Unit Map: Grid: IN VAN CAS# STATE TYPE PRESSURE TEMPERATURE CONTAINER TYPE TPure ~ ~ METAL CONTAINR-NONDRUM AMOUNTS AT THIS LOCATION Largest Container Daily Maximum Daily Average - FT3 200.00 FT3 FT3 HAZARDOUS COMPONENTS , %Wt. 100.00 Freon 22 HAZ RS CAS# No 75456 ARD AS SESSMENTS TSecret RS BioHaz Radioactive/Amount EPA Hazards NFPA USDOT# MCP No No No No/ Curies / / / Low -2- 08/12/1999 • • F DOES REFRIGERATION SiteID: 215-000-001143 ~ Fast Format ~ ~ Notif./Evacuation/Medical Overall Site ~ EVACUATE BY DRIVING VAN OUT OF GARAGE Public Notif./Evacuation emergency rieaical rlan -3- 08/12/1999 ~ Employee Notif./Evacuation 10/09/1990 ~ • • F JOES REFRIGERATION SiteID: 215-000-001143 ~ Fast Format ~ ~ Mitigation/Prevent/Abatemt Overall Site ~ ~ Release Prevention 02/01/1993 ~ PREVENTION - FIRE EXTINGUISHER r-~ ---- ^---~--------~ ~, l,lCclil U~J Other Resource Activation -4- 08/12/1999 . • F JOES REFRIGERATION SiteID: 215-000-001143 ~ Fast Format ~ ~ Site Emergency Factors Overall Site ~ = Special tiazaras Utility Shut-Offs 10/09/1990 A) GAS - LEFT SIDE OF CONDO BY GARAGE DOOR B) ELECTRICAL - SAME AS GAS C) WATER - RIGHT SIDE OF DRIVEWAY NEAR STREET D) SPECIAL - NONE E) LOCK BOX - NO Fire Protec./Avail. Water 10/09/1990 PRIVATE FIRE PROTECTION - FIRE EXTINGUISHER FIRE HYDRANT - OUTSIDE ENTRANCE TO CONDO COMPLEX tsuilaing occupancy Level -5- 08/12/1999 • F DOES REFRIGERATION SiteID: 215-000-001143 ~ ~ Fast Format ~ ~ Training Overall Site ~ ~ Employee Training 10/09/1990 ~ WE HAVE ?? EMPLOYEES AT THIS FACILITY DO YOU HAVE MATERIAL SAFETY DATA SHEETS ON FILE? BRIEF SUMMARY OF TRAINING: rage ~ vela =or r~uLUre use _, r_ neiu =or suture use -6- 08/12/1999 CUST~E & NO. ~~ 3 ~~JC MISCELLANEOUS RECEIVABLES ADJUSTMENT. DATE - S~' - NEW ACCOUNT ADDRESS CHANGE CLOSE ACCT FINANCE CHARGE OTHER ADJ CUSTOMER NAME ~ ~ ~~~` ~ E? (' 0. I ~ .MAILING ADDRESS ~} ~~~ ~~ne~~ ~ ~E D~ CITY ~ ~.I~e~S~~~e~~ STATE ~:~ ZIP CODE Q~30 I SITE ADDRESS PARCEL NUMBER (IF APPIICABL~ ADJUSTMENT CHG DATE CHARGE CODE ADJUSTMENT AMOUNT APPROVED BY , HTE3294 ~` Account Number ACCOUNTS RECENABLE ADJUSTMENT January 12, 1996 Date New Address Esther Duran Close Account From Service Cha e Other Ad ustments X Fire Department -Hazardous Materials Division Department/Division JOES REFRIGERATION Billing Name 4145 PINEWOOD LAKE DR Billing Address Site Address Parcel # (if Applicable) Landlord Name ~ Address (If Applicable) ADJUSTMENT Last Billed Correct Billing Adjustment to Billing Effective Date of Change 123.00 73.00 <50.00> 01-01-96 Ap v Remarks: THIS HAZ MAT HANDLER GOES TO THE FIRE STATION FOR HIS INSPECTION. WE HAVE WAIVED HIS FEE IN THE PAST AND SHOULD DO SO AGAIN. • ACCOUNTS RECENABLE ADJUSTMENT April 13, 1995 Date Esther Duran From Fire Department -Hazardous Materials Division Department/Divisfon HM465001 Account=Numbor New Address Close Account Service Chan e Other Ad ustments X DOES REFRIGERATION Billing Name 4145 PINEWOOD LAKE DR Bllling Address Site Address Parcel # (If Applicable) Landlord Name & Address (if Applicable) ADJUSTMENT Last Billed Correct Billing AdJustmeM to Effective Date of Bllling Change <50.50> 04-01-95 A ro d By Remarks: WE NEED TO REVERSE THE INSPECTION FEE ($50.00) PLUS THE FINANCE CHARGE ACCRUED ON 4-1-95 FOR THIS BUSINESS. THE FIRE DEPARTMENT DOES NOT GO OUT AND INSPECT HIM. HE DRIVES TO THE FIRE STATION FOR HIS INSPECTION. `~~ ~ `~ HM455001 ~ _ Account Number ACCOUNTS RECENABLE ADJUSTMENT .February 16, 1994 Date New Address Esther Duran Close Account From Service Chan e Other Ad ustments X Fire Department -Hazardous Materials Division DepartmeM/Division JOE'S REFRIGERATION Billing Name 4145 PINEWOOD LAKE DR Billing Address Site Address Paroel # (if Applicable) Landlord Name & Address (If Applicable) ADJUSTMENT Last Billed Correct Billing Adjustment to Billing Effective Date of Change 123.00 73.00 <50.00> 01-01-94 - : "~. Ap ro By:. Remarks: WE HAVE AGREED TO WAIVE THE INSPECTION FEE ($50.00) SINCE HE DRIVES TO THE FIRE STATION FOR HIS INSPECTION. _ S~ Utilities General Account Maintenance PUTLS801 Acct Nbr: 455001 Bill Stat: NO Transfer-from: Page 1 of 6 Cyc Stat: CL Acct Cyc Stat: CL Transfer-to: Due: 123.00 1. Customer Name: JOES REFRIGERATION 2. Social Sec Nbr: 3. Telephone: 805-834-6808 4. Service Address: 4145 PINEWOOD LAKE DR 5. Service City: BAKERSFIELD 6. State: CA 7. Zip: 93309 8. Parcel ID: 9. 5 20. Water Bill Cycle: Svc Class: 10. . Route Nbr: 11. Comments WAIVE INSP FEE 12. Prev Acct: HM01143 23. Misc Services: 23.1 FO1 HAZ MAT HANDLING 13. Service Date: 12/04/87 23.2 F99 NOT IN BUSINESS 14. Fund no: 23.3 15. Billto Ad1:4145 PINEWOOD LAKE DR 23.4 16. Billto Ad2: 24. Closing Date: 17. Bill-to City: BAKERSFIELD 18. State: CA 19. Zip: 93309 Enter Save(S), Cancel(XX), Next Page(/), or Field # to Change HAZARDOUS MATE~LS INSPECTION erstield Fire Dept. Ha dous Materials Division Date Completed ~ Z~ I" ~ ~~ ~uslness Name. • Location: `T 1'~ ~ Y t N~(it1 ~ L~ ~~~ Business Identification No. 215-000 ~ // ~.3 (Top of Business Plan) Station No. Shift ~ Inspector K~ R~ I ~ Arrival Time: ~~~0 Departure Time: ~~ ~~ Inspection Time: ~~- ~h/Nr~~ Verification of Inventory Materials Verification of Quantities Verification of Location Proper Segregation of Material Comments: Verification of MSDS Availability Number of Employees: Verification of Haz Mat Training Comments: Verification of Abatement Supplies & Procedures Comments: Emergency Procedures Posted ~ ^ Containers Properly Labeled ~ ^ Comments: Verification of Facility Diagram ^ Special Hazards Associated with this Facility: Violations: -- ~ ~ I Ou i ZJ~ ~8~t i nr , i _ /I i _ . ...n OE ~G~ I All Items O.K [~' Business OwnedManager PRINT NAME SIGNATURE Correction Needed ^ ~_ N White-Haz Mat Div Yellow-Station Copy Pink-Business Copy o Adequate Inadequate Q~ ^ d ^ o'. ^ mo L'_7 ^ ^ d o RECEIVE® ~~.~~ ~ ~ 1994 HA7_. N1AT. DIV. P ~jr `^ ; ~ ~ TJE ~1 TIME ~ AM ~~ PM H O ~/ REA CODE NO N ~ . EXT. ~(j E E M E s s ~ M ~ O E _ _ ~~ SIGN PHONED ggCK CALL RNED ~ SEE YOUR ^ AGAIN ALL ^, yy SIN URGENT I i i i i I I 4 .rr . .a _-_; ~ r 01/12/93 JOES REFRIGERATION 215-000-00114 Overall Site with 1 Fac. Unit General Information ~-=-, w~ l ~;, _ JAN 2 7 1993 ~j ~ ge 1 By Location: 4145 PINEWOOD LAKE DR Map: 123 Hazard: Minimal Community: BAKERSFIELD STATION 07 Grid:. 14B F/U: 1 AOV: 0.0 Contact Name Title Business Phone 24-Hour Phone PEARL BALDUC (805) 327-5401 x (805) 834-6808 LOIS GROSS (805) 832-5433 x (805) 832-5433 Administrative-Data Mail Addrs: 4145 PINEWOOD LAKE DR D&B Number: City: BAKERSFIELD State: CA Zip: 93309- Comm Code: 215-007 BAKERSFIELD STATION 07 SIC Code: Owner: JOE BALDUC Phone: (805) 834-6808 Address: 4145 PINEWOOD LAKE DR State: CA .City: BAKERSFIELD Zip: 93309- Summary ,~ a- ~- ~3 ~, ~ Jo hereby certify that !have (TYPE or petit nMne) reviewe:l the atta~~~, y ~.. , .. -._..r.~~c~~a~as materials manage- msnt plan t~~,~~~,_~1~~~~u: that it along with any corrections cor~~~iu-e ~ ~~~~~~sip ana corre~~ man- apemant plan for my facility. ~~ ~ /-~~ • 01/12/93 JOES REFRIGERATION 215-000-001143 Page 2 02 - Fixed Containers on Site Hazmat Inventory Detail in Reference Number Order 02-0.01 FREON R-12 ? 285 Minimal ~ FT3 CAS #: Trade Secret: No Form: Unknown Type: Pure Days: Use: COOLING Daily Max FT3 Daily Average FT3 Annual Amount FT3 - 285 -~ 0.00 ~ 2,672.00 METAL CONTAINR-NONDRUM Press T Temp IN VAN Location - Conc Components MCP uide 100.0 Freon 12 Minimal ~ 12 02-002 FREON R22 ? 200 Low ~ FT3 CAS #: Trade Secret: No Form: Unknown Type: Pure Days: Use: COOLING Daily Max FT3 Daily Average FT3 Annual Amount~FT3 - 200 ~ 0.00 ~ 1,600.00 METAL CONTAINR-NONDRUM Press ~ Temp IN VAN Location - Conc Components MCP Guide 100.0 Freon 22 Low ~ 12 - • • 01/12/93 JOES REFRIGERATION 215-000-001143 Page 3 00 - Overall Site <D> Notif./Evacuation/Medical <1> Agency Notification <2> Employee Notif./Evacuation EVACUATE BY DRIVING VAN OUT OF GARAGE <3> Public Notif./Evacuation r <4> Emergency Medical Plan m • • 01/12/93 JOES REFRIGERATION 215-000-001143 Page 4 00 - Overall Site <E> Mitigation/Prevent/Abatemt I <1> Release Prevention PREVENTION - SIRE EXTINGUISHER I <2> Release Containment I <3> Clean Up I <4> Other Resource Activation ~. ~ ~ . • 01/12/93 JOES REFRIGERATION 215-000-001143 Page 5 00 - Overall Site / <F> Site Emergency Factors <1> Special Hazards I <2> Utility Shut-Offs A) GAS - LEFT SIDE OF CONDO BY GARAGE DOOR B) ELECTRICAL - SAME AS GAS C) WATER - RIGHT SIDE OF DRIVEWAY NEAR STREET D) SPECIAL - NONE E) LOCK BOX - NO <3> Fire Protec./Avail. Water PRIVATE FIRE PROTECTION - FIRE EXTINGUISHER FIRE HYDRANT - OUTSIDE ENTRANCE TO CONDO COMPLEX <4> Building Occupancy Level 01/12/93 JOES REFRIGERATION 215-000-001143 Page 6 00 - Overall Site <G> Training <1> Page 1 WE HAVE ?? EMPLOYEES AT THIS FACILITY DO YOU HAVE MATERIAL SAFETY DATA SHEETS ON FILE? BRIEF SUMMARY OF TRAINING: ~ <2> Page 2 as needed <3> Held for Future Use <4> Held for Future Use ~' -= ID= U~~~~~ ESI\ESS, K~A.~tE HAZARDOUS MATERI ALS BUSINESS PLAN AS A WH O L E FORM 2 A INSTRUCTIONS :_ _ _ _-_ _ ~~ ~~Gr ~ 1. To avoid further action, return this form by 2. TYPEiPRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. 4. Be as brief and concise as possible. A. BUSINESS NAME: SECTION 2: E:-iERGENCY yOTIFICATIONS In case of an emergency involving the release or threatened release of a hazardous material, call 911 and 1-800-852-7530 or 1-916-X27-341. This will notify your local fire department and the State Office of Emergency Services~as req~zired by 13•r.. - - -. TO--\OTIFY--IN CASE -OF EMERGENCY: ~/~~°Se Jive N~'~ -~~`~~'~t~~~r~` - -_ _._ NAME A`'D TITLE DURING BUS . HRS . AFTER B1;S . HRS . A. ~~4.~1' ;~f'LDJ.7G. Ph=y'~~ ~ ~~l~ / Ph= ~~~ ~AD`~ B . `.~! ~-r.P~i :S':C' Ph- c~~- SS~3~ Ph ~~d?--~~~3~ SECTION 3: LOCATION OF UTILITY SHUT-OFFS FOR BUSINESS AS A WHOLE A. NAT. G B. ELECTR E. -LOCK BOY:'.YES C. WATER: D. SPECIA.,. IF YES, LOCaTIO:~: IF YES, DOES IT CO\TAI` SLTc PLa\S? FLOOR PLA`S? ~ ~ Z 3a - 2a - ~'~ _ ~' ,i ~"~ --- ~f.; BAKERSFIELD CITY FIRE DEPARTMENT ;~ _. - 2130 "G° sTREET = ~ RECEIVED BAKERSFIELD, CA 93301 DEC 0 4 1987 (805) 326-3979 t a3 t ~ ~ Ans'd......-- ~ -'IVSP ~] .... OFFICIAL I;SG 0\LY YES ! VO `~SDSS? lc'ES ! VO YES ! ~0 KEYS? YES ! ~0 B . LOCATION / STREET ADDRESS : _ ~J~OD ~~~~5' ~[~ `~'~`i~ CITY: ,~~~~i~G/L~~D ZIP: ~•3~(~~ BUS.PHO\E: (~4~) ~5~7'~-G~~4~ . _ ~ :- _ ,\ SECTIOY ~: PRIVATE RESPONSE TEAK FOR BUSINESS AS :~ WHOLE /VON~ SECTION 5: LOCAL EMERGENCY MEDICAL ASSLSTA~CE FOR YOUR BUSINESS AS A WHOLE I'i I Gc~/~i T .lit/ j~%~~ ~ ~'i5~~ ~,~./%v~~. SECTION 6: TRAINING ~ ~ ~~~~ ~~:/~~ ~~~~~ E~IPT_OYERS ARE REQLIRED TO HAVE A PRCGRA~I tdHICH PROVIDES EMPLOYEES WITH INITIAL ~1ND REFRESHER TRAI\iVG I~' THE FOLLOWING AREAS. CIRCLE YES OR \0 ~ ItITIaL REFRESHER A. METHODS FOR SAFE HA.iDLIVG OF HAZARDOUS !~~TERIaLS :.........................:............. ~ NO YES NO B. PROCEDURES FOR COORDINATING ACTIVITIES WITH RESPO\SE AGENCIES :.......................... YES ~ YES ti0 C. PROPER L'SE OF SAFETY EQUIPME\T :.................. S' VO -YES NO D. E~IERGE~iCY EVACUATION PROCEDURES :.................~'... SO YES NO £ . Da ~T13U ?4AI???'.alu £?I~LOY£E' TRAM I~1~ I2£CO~DS :....... ~-...S N0 -'~' YES ..:1'0 ~- ":-~`~_ SECTION ?: HAZARDOUS MATERIAL DOES YOtiR BCSI`ESS HANDLE HAZARDOUS ~LATERIAL Iti QUA\TITIES LESS THA\ X00 POti' OF A SOLiD, 55 GALLONS OF A LIQUID, OR 200 CUBIC FEET OF a COMPRESSED GAS:..... YES t0 I, Off' f~.4Gd~U~ certify that the above information is accurate. I understand that this information will be used to fulfill my firm's obliEations under the new California Health and Safety code on Hazardous Materials (Div. 20 Chapter 6.95 Sec. 25500 Et A1.) and that inaccurate information constitutes perjury. SiGNATLR TITLE DATE ~- _ ~o _ r~~:_ BAKERSFIELD CITY FIRE DEPART~iE~T 2130 "G" STREET- BAKERSFIELD, CA 93301 IDT BUSINESS `:\~'F • _ _ _ _ - _ BUSINESS PLAN SINGLE FACILITY UNI T _ FORM 3A INSTRUCTION'S 1. To avoid further action, this form must be returned hy: 2. T~"PE:'PR?~;T YOGR A\SS~FRS IV ENGLISH. 3. Ans~.aer the questions bPlo~+ fer THE F:~CII.ITY _(~IT LISTED 2EI_OW __ __~l - - - -_- - - - -4. "Be as-BRIEr and CO~C?SE as possible.' _- -- - - -- - n FACILIT`I UNITS -` FACILITY L1VIT NA.~tE: ~~~~;~I%~[J~d/I. SECTION 1: ~SITIGATIOV, PREVEV";ION, ABATE;IE~'T PROCEDURES ~~~ !~ ~~ ~ ion/ --- ~2~ ~x-T,~/~~vs' _ SECTION 2: `OTIFiCATION AFD EVACL'ATIOti PROCEDURES AT THIS L'~IT 0\LY ~~~ ~- _ • -.,a- _, _~;, i ~. r SECTION 3: HA?.ARDOi;S KATERIALS FOR THIS CNIT ONLY A. Does this Facility Lnit contain ~iaz:~rdous ~[aterials?...... 'YES ~0 If YES, see B. ~ If N0, continue with SECTIO\ =1. I B. Are any of the hazardous materials a bona fide Trade Secret YESr~'0 `. _ ; If No, complete a separate hazardous materials inventory form marked: \ON-TRADE SECRETS OSI,Y (tvhite form ==1A-1) -- If Yes, complete a hazardous materials inventory form marked: TRADE SECRETS 0\LY (yellow form ~~,~-2) in addition to the nor-trade secret form. List oily the trade secrets on-form 4A-2. SECTION 4~-:-PRIVATE FIRE PROTECTIO\ __ . SECTION 5: LOCATION OF WATER SUPPLY FOR USE BY EMERGENCY RESPONDERS SECTION 6: LOr_.ATIO` OF UTILITY SHLT-OFFS AT THIS UNIT ONLY. B. ELECTRICAL: -- C. jtiaTcR: ~ ~~ D. SPFCIaL: E . L oox 13n~ : ~-~ s `o _ IF YES, SITE FLOOR f YES , LCC.aTIO`; PLANS? YES / ~0 tiISDSs? YES ~ \0 PL A\S? YES .% ti0 KEYS? YES ;' \0 - 3° - _ _, ~~ `~ -~ ~ ~ I I .~ v: _ C < ~1 C; Z U < .:I I ~: .. Lz7 L } ta] ~ I F ~. < . Z C ?' U F ~ < .~ U Z <' Li. Z ~. C ZI `~ Li. I zl N E. OI ~ I = ~1 ~I of U U~ I 4 ~_~ ~ C J z . =i~. .~ ~ ,~_~ , w r ~'1 . _ F Z ~~ ~ - - C - Lilt t! V Fa = ~ - _ - UN r W ~ ,. ~ ~ ~ e- V` - ~U~Q ~ t ° z { ~ e x I ; a H cz H Z~~~ F{-' N r 1~1 ~k C . L9 ~ Li] ~ N z z r 11~~ r _ = ~ C r ~ = . z } r I o<JLL ~cE- w~ r ~ 1 Y ^ r < 0 r G:. U - Z0 = Li.l n I i ~ C ~~ Q L ~~ C U: ~~ _~ N _ E- tvl. Z .I ~:=~1 ~ F ~1 r Z~ ~ ~1 < z . _ t^ Z .. ~ Vii; z z~ Si c <~ I- I --- I X f -~ J I c• .. . . i c~ < 4 _ ._ _ _ - _ _ _~ :, :,I ~ j ~~~ ~ tti, - i ~ ~ 'V.\ I ~ a I I i ': ~ I ~ ~ 11, I '~ ~ i ~ ~ I ~~~ ~I I { ~: a '~ ~ to I I ~ ~ ~F -~ ~, ~~~ I ~ iii ~~ C .. .. ` C .. ~ .. C ~ C rn ~ C . ~ ~ cn ~ v: ~ L. ~ L L: C C M Li] M ail Er E-' Li] Li. k7 Ls. z c z c 0 0 `a ~~~~~ ~~ E~ z ~j 0 .I~~~ Liz L~ ("` ["~ F F I I 1 I- I .. L' I I 1 ~ .,: I I I IF I C 1 ~\ _ ~ } ~; ~ ~F ~ ~> ~ I ~ ~ ~ < ~:~ ~ o~ ~ .. .. I I I E- E- c .. ~ -_ 1 I ~ . Z r rr .~ ~ iI I ~ ~ I ~ I I ~~~ ~_ i V~ I ~b- ~ ~ i I i '- = _ ~ `, ~ . _ "u /0 ~ ~ p `- .~.