Loading...
HomeMy WebLinkAboutBUSINESS PLAN 4/19/2007v;r -~ (HMMP) ;~. HAZARDOUS MATERIALS MANAGEMENT PLAN (UNIFIED PROGRAM CONSOLIDATED FORM) /~~ s. =.` a x%aRSrrs APPLICATION °~~. a>>~aRr ' r BUSNESS ONMER/OPQ2ATOR ®EIVi&ICATrON FORM ~.~ (HAZARDOUS MATERIALS FACILITY INFORMATION) BAKER$FIELD FIRE DEPT. Prevention Services 1600 Truxtun Ave., Suite 401 Bakersfield, CA 93301 Tel.: 661-326-3979 Fax: 661-852-2171 Page 1 of 2 ~~~1~ .1: FACILITY IDENTIFICATION . 1 ~ FACILnY ID N0. t Year Beginning too Year Ending ^ tOt BUSINESS NAME (Same as FACILITY N E or DBA- Doing Business As) 3 ~ BUSINESS PHONE 102 ' ~ ~ SITE AD RESSS~ ~ ~ ~ ~ /l/~~_- toa ~! CITY n,~, ~/ ~ toa ~~1~L1 CA Ip toe DUNN & BRADSTREET t ~I ODE 107 y (4 it COUNTY t08 OPERATOR NAME tog OPERATOR PHONE tt0 - :; - .,.. - II: OWNER'INFORMATION ; : • OWNER NAME t1t ~ ~ /~ "~ ~~~ ~ OWNER PHONE 112 - Cglg~ 2 . , . OWNER MAILING ADDRESS tt3 /'~ !/ 1 CITY tta ~~ STATE tte IP tts ,., .. IIL~ ENVIRONMENTAL CONTACT- CONTACT NAME tt7 ~~6L- ~ >~Af~4 CONTACT PHONE tte ~i S CONTACT MAILING ADDRESS ~/ ,/~ ~ J tta ~/' (S v~ C$~ rd f/~ 1 CITY t2o STATE 121 ~~ Zlp J 122 / ~/ .~ PRIIIAARY Iv. ~~:. - EMERGENCY CON , TACTS =SECONDARY- NAME ~ ~~ 123 NAME / r 128 l.+G.~ TITLE y (~ ~J 124 ~1- TITLE ~ p 129 Z Grp y BUSINESS PHONE r 125 BUSINESS PHONE ~ ~ ~ 130 ,~ 24-HOUR P~O~ ~ ~ 126 24-HOUR P~ / ~~ ~ ~~~ /} 131 PAGER NO. 127 PAGER NO. ~ 132 133 .: - , V. CERTIFICATION '` ''" Certification: Based on my inquiry of those individuals responsible for obtaining the information, I certify under penalty of law that I have personally examined and am familiar 't the information submitted in this inventory and believe the information is true, accurate, and complete. SIGNATURE OF SIGNER 136 D TE 134 NA OF DO U ENT P PARER 135 I G NAME OF OWNER/OP ( N RE & PRINT) e ~ 137 6 ~ 138 TLE OF OWN R/OPERATOR ~ f /y / ~ ( ~ ~~ ~ C~~~~. ~ ~~ ~ }~ ctrl ~i~~~~~ ~ ~N`~ ~~- ~o~V~ FD 2142 (Rev. 01 /0~ (Hazardous Materials IF~xcaIla~ Information - HMMP) _ = Business Owner/Operator Identification Please submit the Business Activities page, the Hazardous Materials Faci/itylnformation (HMMP) Business OwnerlOperator Identification Form, and Hazardo~ Materials Inventory Chemical Description Form for all hazardous materials inventory submissions. For the inventory to be considered, please complete this page, it must be signed by the appropriate individual. NOTE.' The numbering ofthe instructions fol%ws the data a%ment numbers that are on the Business Owner Operator Form page. These data a%ment numbe. are used fore%ctronic submission and are the same as the numbering used in 27 CCR, Appendix C, the Business Section ofthe Unified Program Data Dictionary. Piease numberall pages ofyoursubmittal. This he/ps our CUPA orAA identify whether the submitta/is comp/ete and ifany pages are separated. 1 FACILITY I.D. NUMBER -This number is assigned by the CUPA or AA. This is the unique number which identifies your facility. 3 BUSINESS NAME -Enter the full legal name of the business. 100 BEGINNING DATE -Enter the beginning year and date of the report. (YYYYMMDD) 101 ENDING DATE -Enter the ending year and date of the report. (YYYYMMDD) 102 BUSINESS PHONE -Enter the phone number, area code first, and any extension 103 BUSINESS SITE ADDRESS -Enter the street address where the facility is located. No post office box numbers are allowed. This information must provide a means to geographically locate the facility. 104 CITY- Enter the city or unincorporated area in which business site is located. 105 ZIP CODE -Enter the zip code of business site. The extra 4 digit zip may also be added. 106 DUNN & BRADSTREET -Enter the Dunn & Bradstreet number for the facility. The Dunn & Bradstreet number may be obtained by calling (610) 882- 7748 or by Internet. 107 SIC CODE -Enter the primary Standard Industrial Classification Code number for primary business activity. NOTE. /fcode is more than 4 digits, report oMy the first foul 108 COUNTY -Enter the county in which the business site is located. 109 BUSINESS OPERATOR NAME -Enter the name of the business operator. 110 BUSINESS OPERATOR PHONE -Enter business operator phone number, if different from business phone, area code first, and any extension. 111 OWNER NAME -Enter name of business owner, if different from business operator. 112 OWNER PHONE -Enter the business owner's phone number if different from business phone, area code first, and any extension. 113 OWNER MAILING ADDRESS -Enter the owner's mailing address if different from business site address. 114 OWNER CITY -Enter the name of the city for the owner's mailing address. i 15 OWNER STATE -Enter the 2 character state abbreviation for the owner's mailing address. 116 OWNER ZIP CODE -Enter the zip code for the owner's address. The extra 4 digit zip may also be added. 117 ENVIRONMENTAL CONTACT NAME -Enter the name of the person, if different from the Business Owner or Operator, who receives all environmental correspondence and will respond to enforcement activity. 118 CONTACT PHONE -Enter the phone number, if different from the Owner or Operator, at which the environmental contact can be contacted, area code first, and any extension. 119 CONTACT MAILING ADDRESS -Enter the mailing address where all environmental contact correspondence should be sent, if different from the site address. 120 CITY- Enter the name of the city for the environmental contact's mailing address. . 121 STATE -Enter the 2 character state abbreviation for the environmental contact's mailing address. 122 ZIP CODE -Enter the zip code of the environmental contact's mailing address. The extra 4 digit zip may also be added. 123 PRIMARY EMERGENCY CONTACT NAME -Enter the name of a representative that can be contacted in case of an emergency involving hazardou materials at the business site. The contact shall have FULL facility access, site familiarity, and authority to make decisions for the business regardin< incident mitigation. 124 TITLE -Enter the title of the primary emergency contact. 125 BUSINESS PHONE -Enter the business number for the primary emergency contact, area code first, and any extensions. 126 24HOUR PHONE - Enter a 24-hour phone number for the primary emergency contact. The 24-hour phone number must be one which is answered 24 hours a day. If it is not the contact's home phone number, then the service answering the phone must be able to immediately contact the individu, stated above. ._ 127 PAGER NUMBER -Enter the pager number for the primary emergency contact, if available. 128 SECONDARY EMERGENCY CONTACT NAME -Enter the name of a secondary representative that can be contacted in the event that the primary emergency contact is not available. The contact shall have FULL facility access, site familiarity, and authority to~make decisions for the business regarding incident mitigation. 129 TITLE -Enter the title of the secondary emergency contact. 130 BUSINESS PHONE -Enter the business telephone number for the secondary emergency contact, area code first, and any extension. 131 24-HOUR PHONE - Enter a 24-hour phone number for the secondary emergency contact. The 24-hour phone number must be one which is answered 24 hours a day. If it is not the contact's home phone number, then the service answering the phone must be able to immediately contact the Ind'+vidual stated above. 132 PAGER NUMBER -Enter the pager number for the secondary emergency contact, if available. 133 ADDITIONAL LOCALLY COLLECTED INFORMATION -This space may be used for CUPA's or AA's to collect any additional information necessan to meet the requirements of their individual programs. Contact your local agency for guidance. 134 DATE -Enter the date that the document was signed. (YYYYMMDD) 135 NAME OF THE DOCUMENT PREPARER (FULL PRINTED NAME) -Enter the full printed name of the person who prepared the inventory submittal information. 136 NAME OF DOCUMENT SIGNER (FULL PRINTED NAME) -Enter the full printed name of the person signing the page. The signer certifies to a familiarity with the information submitted and that based on the signer's inquiry of those individuals responsible for obtaining the information, all the information submitted is true, accurate and complete. 137 SIGNATURE OF OWNER/OPERATOR/OR DESIGNATED REPRESENTATIVE -The Business OwnedOperator, or officially designated representative of the Owner/Operator, shall sign in the space provided. This signature certifies that the signer is familiar with the signer's belief that the submitted information is true, accurate and complete. 138 TITLE OF OWNER/OPERATOR/OR DESIGNATED REPRESENTATIVE (SIGNER) -Enter the title of the person signing the page. Page 2 of 2 FD 2142 (Rev. 01/07) ;. . HAZARDOUS MATERIALS MANAGEMENT PLAN ~ =~: APPLICATION ~;}z-.: FOR SECTION DISCOVERY AND NOTIFICATION (FORMS) INSTRUCT{ONS 1. To avoid further action, return this form within 30 days of receipt. 2. TYPE/PRINT ANSWERS IN ENGLISH. 3. Answer the questions below for the business as a whole. ~ ~ 4. tie as nner ana concise as possloie. SECTION' 1 FI BUSINESS NAME (Same as FACILITY NAME or DBA -Doing Business As) ADDRESS (For local use only) ©•-~ FACILITY fD NO. . $ECTION 11.1:: DISC A LEAK DETECTION AND MONITORING PROCEDURES: ; p~ B. EMPLOYEE AND AGENCY NOTIFICATION: ~ / C. ENVIRONMENTAL RESPONSE MANAGEMENT: ~~ B. RELEASE CONTAINMENT AND/OR MITIGATION: G. CLEAN-UP AND RECOVERY PROCEDURES: B I;BRSFIB~I.D F1RB OL7 ARTMB T BAKERSFIEI.D FIRE I9EP~. Prevention Services 1600 Truxtun Ave., Ste. 401 Bakersfield, CA 93301 Tel.: 661-326-3979 Fax: 661-R52-2171 Page 1 of 2 DENTIFICATIQN . ~ ~~ ) V NOTI ~~~ ~~ ~~ ~ r~~Q~,~, ~ ~~saN ,,v c/~,e~~' ?~i~~.~'~j FD 2169 rRev_ avo~l Page 2 of 2` SECTION II 2 "RELEASE~RESPONSE~PLAN~=-CON'T `.~ --- UTILITY SHUT-OFFS (LOCATION OF SHUT-OFFS AT YOUR FACILITY) /~ ,, /'y~v ~ F ~J NATURALGASlPROPANE: C , ~ O pY b ~ !.- ELECTRICAL: C WATER: i; / SPECIAL: PRNATE FIRE PROTECTIONNVATERRVAILABILITY: 1 A. PRIVATE FIRE PROTECTION: ~!~- ~ ~ ~~/~~~1 (~~ B. WATER AVA0.ABILITY (FIRE HYDRANT): ~~ ~' 3ECTION`III: TRAINING~~ NUMBER OF EMPLOYEES: ~r ~~~~~vV MATERIAL SAFETY DATA SHEETS ON FILE: ~~ BRIEF SUMMARY OF TRAINING PROGRAM: CERTIFICATION: _ _: __.~:__ Based on my inquiry of those individuals responsible for obtaining the informafion, 1 certify under penalty of Taw that_I have p~lsonally_ examined and am familiar with t e information submitted and believe the information is true, accurate, an" SIGNATUR 0 / 0 TOR R, ESIGNATED REPRESENTATIVE DATE 477 NAME SIG ER (print) 478 ~~ ~ ~ TITLE OF S GN.ER pp = 479 ~ i I ~ ~ ~V`~ FD 2169 (Rev. ovo~> Page 2 of 5 Storage Location: Front Stockroom Hazard Physical Open Closed Days on Container Annual Class Chemical Name /Concentration CAS# State Storage System System Total Units Site Type ,Waste 000 C02 Scuba -Breathing Air n/a G P 400.0 0.0 0.0 400.0 Ibs 365 a: Cylinder 0.0 COMPRESSED GASES -Inert 000 Compressed Air (scuba tanks) /100 n/a G P 7000.0 0.0 0.0 7000.0 CF 365 Cylinder 0.0 COMPRESSED GASES -Inert Storage Location: Salesfloor - Camping Dept. Hazard Physical Open Closed Days on Container Annual Class Chemical Name /Concentration CAS# State Storage System System Total Units Site Type Waste 040 Camping Gas/Butane 106- 97-8 L M 18.0 0.0 0.0 18.0 Ibs 365 Cylinder 0.0 COMPRESSED GASES -Flammable IRRITANTS -- Liquids 140 NW Coleman Latern Fuel /100 68410- 97-9 L P 36.0 0.0 0.0 36.0 ga 365 Can 0.0 FLAMMABLE LIQUID -Class I-B IRRITANTS -- Liquids 130 Insect Repelant n/a L M 2.0 0.0 0.0 2.0 ga 365 Can 0.0 AEROSOL -Level II IRRITANTS -- Liquids 140 Isobutane/Propane Mix n/a G M 11.25 0.0 0.0 11.25 Ibs 365 Cylinder 0.0 COMPRESSED GASES -Flammable IRRITANTS -- Gases 000 Jetboil Jetpower Fuel .Mix n/a L M 1.5 0.0 0.0 1.5 Ibs 365 Can 0.0 'FLAMMABLE LIQUID -Class I-A IRRITANTS -- Liquids 240 MSR ISO PRO n/a G M 4.5 0.0 0.0 4.5 Ibs 365 Can 0.0 COMPRESSED GASES -Flammable IRRITANTS -- Liquids 210 Pepper Spray n/a L M 0.5 0.0 0.0 0.5 ga 365 Can 0.0 AEROSOL -Level II IRRITANTS -- Liquids 000 Primus Cartridge n/a G M 5.5 0.0 0.0 5.5 Ibs -365 Cylinder 0.0 file://C:\DOCUME~ 1 \rking\LOCALS~ 1 \Temp\TKSZ6W7E.htm 10/10/2006 Page 3 of 5 _ COMPRESSED GASES -Flammable IRRITANTS -- Gases 140 Propane /100 FLAMMABLE LIQUID -Class I-A IRRITANTS -- Liquids 74-98 L P 46.0 0.0 0.0 46.0 6 Ibs 365 Can 0.0 ,~ b Storage Location: Salesfloor -Team Sports Hazard Physical Open Closed Class Chemical Name /Concentration CAS# State Storage System System Total 000 Paint Balls n/a S M 150.0 0.0 0.0 150.0 *Non-Hazardous Storage Location: Salesfloor -Wat er Sports Hazard Physical Open Closed Class Chemical Name /Concentration CAS# State Storage System System Total 100 Cyanuric Acid/Pool Chemical 108 80-5 S M 24.0 0.0 0.0 24.0 IRRITANTS -- Solids 301 NW Hypochlorite Mixture/Pool Chemical /100 7778 S P 72.0 0.0 0.0 72.0 54-3 OXIDIZERS/SOLIDS -Class 3 UNSTABLE (REACTIVE) MATERIALS -Class 1 WATER-REACTIVE MATERIALS -Class 1 CORROSIVE MATERIALS/Bases -- Solids Storage Location: Stockiiroom Hazard Physical Open Closed Class Chemical Name /Concentration CAS# State Storage System System Total 000 Compressed Air-Stockroom /100 n/a G P 2616.0 0.0 0.0 2616.0 COMPRESSED GASES -Inert Storage Location: Stockroom -Upstairs Hazard Physical Open Closed Class Chemical Name /Concentration CAS# State Storage System System Total 000 Paint Balls n/a S M 60.0 0.0 0.0 .60.0 *Non-Hazardous file://C:\DOCUME~ 1 \rking\LOCALS~1 \Temp\TKSZ6W7E.htrn Days on Container Annual Units Site Type Waste Ibs 365 Box 0.0 Days on Container Annual Units Site Type `" Waste Plastic Ibs 365 bottles or 0.0 jugs Plastic Ibs 365 bottles or 0.0 jugs Days on Container Annual Units Site Type Waste CF 365 Other 0.0 Days on Container Annual Units Site Type Waste Ibs 365 Box 0.0 10/10/2006 ~ I . ~r SOUAREFOOTAGESUMMARY ~.~ ' ~ ~' ~~ ~ f `...~ ~ ~" ~: ~ ~;:_ , ~ : ~ ~ ~v ~ ; ~,%' ~ ~ ~; ~: ~ ~ ~' ~' GROSS SQUARE FOOTAGE: a2.e19 E i ft k{ NONSEIIING SQUARE FOOTAGE: 4 ~ ~ ~ [ I I E 'I ~ ~ ~ ~ ~ { ~ 1ST FLOOR: 11,7 Q29%) i f 1 i 1 !!I f '~ f f f f f MEZZANME: 8,614 I I 1 1 1 ~ I I I ~ I I I I I l '' 1 ! 77 ! f f f 1 t 1 9ElLWG 50UARE FOOTAGE: 91,110 f1 ~~ ~~ I I ~ i I I I I I DEPARTMENT ~__._._~_ i ~.._ I ( t f I I I __._.._..._;.i SUOMMARY OTAGE I r~ OnA Sport grkt 6he V CsrEe, CA 81071 S{w Pbnsr ACOpN 1.0~W ., ~ j I ~ I I ({ , l I 11 c 1 R i ~ f f 1 1 f ~ FREMBS ZS789 e ~ t : ({ i ' ~: I ' ~8 ~ i ~ ( ~ ~ ~ ' ~ I ~I w Ks~ s e.iio ... s"'z [mt~ :'t i<~~ ~::-_~ ~ ~~.. ~i 1 ! 1 ~O- 3 .!.: y •:" f ( ~~ ~ __ ~ SEASONAL 2:12, .... ... ? ~ ~ ;: m 91< ... 7 i ,,,a. ~rr ar ,.~. ~ ~ . :,; .: :; .. .:.: ~. °~~ .. :~ a s B° e~ m =~ '~ =~ e e e I GOLF%TEIVNIS Qy ? ~ I f ~ I g ~p [EE \... ~.. ~~ s --- ` [ "$' I E .~. ~~ ~~.. tea. 1 ® f 1 > ..., 7 .._~ _ ........... ~ -~ ~........._.... T~ i7 ~ "'OMENS 7 ~ € _ _ .. . „ _~ "wA`"""` _ t MENDS ~ ~ I i f.U -..iSHl !G~ ,~ ~ ~ E - n.- s ~.m / .. E3 ~~ .. ~=-~ E_=~ E E ' M' OF DI~PLAY SHHIY ~ .. .. .. ~~ j~ ~.. _. ..... .._. ,~.._ E f .. ..._. .. ...., OF ISYLAY 6HEhF ' _.. ;. F SITE SPECIFIC FIXTURE PLAN J W LL ® W Y Q m STORE LAYOUT APPROVAL t -22-2007 ~ slrE sPECIF7c FIXTURE PLAN FINAL VERSION-C CMiG Lee^.~iA._.,_ 'i?F AtdC:ER50N_._...~__. e..:.,. E:LEEtJ EWO'TT AF.N AR4:XFT F 1 LINC+h OEiF:FiME:Yi: F? L L- _~ Ph sical5tate: P =Pure S =Solid M =Mixture L =Liquid G =Gas SARA Class: Physical Hazards Health Hazards F =Fire I =Immediate (Acute) P =Sudden Pressure Release D =Delayed (Chronic) R =Reactivity Storage Location: Front Stockroom AGGREGATE PHYSICAL HAZARDS storage 1 COMPRESSED GASES -Inert 7000.0 1 COMPRESSED GASES -Inert 400.0 Storage Location: Salesfloor -Camping Dept. AGGREGATE PHYSICAL HAZARDS storage 2 AEROSOL -Level II 2.5 4 COMPRESSED GASES -Flammable 39.25 2 FLAMMABLE LIQUID - Class I-A 47.5 1 FLAMMABLE LIQUID -Class I-B 36.0 AGGREGATE HEALTH HAZARDS storage 2 IRRITANTS -- Gases 16.75 3 IRRITANTS -- Liquids 38.5 4 IRRITANTS -- Liquids 70.0 Storage Location: Salesfloor -Team Sports AGGREGATE PHYSICAL HAZARDS storage 1 *Non-Hazardous 150.0 Storage Location: Salesfloor -Water Sp orts AGGREGATE PHYSICAL HAZARDS storage 1 OXIDIZERS/SOLIDS -Class 3 72.0 1 UNSTABLE (REACTIVE) MATERIALS -Class 1 72.0 1 WATER-REACTIVE MATERIALS -Class 1 72.0 AGGREGATE HEALTH HAZARDS storage 1 CORROSIVE MATERIALS/Bases -- Solids 72.0 Use Open Use Closed Total 0.0 0.0 7000.0 CF 0.0 0.0 400.OIbs Use Open Use Closed Total 0.0 0.0 2.5 ga 0.0 0.0 39.251bs 0.0 0.0 47.5 Ibs 0.0 0.0 36.0 ga Use Open Use Closed Total 0.0 0.0 16.75 Ibs 0.0 0.0 38.5 ga 0.0 0.0 70.0 Ibs Use Open Use Closed Total 0.0 0.0 150.0 Ibs Use Open Use Closed . Total 0.0 0:0 72.0 Ibs 0.0 0.0 72.0 Ibs 0.0 0.0 72.0 Ibs Use Open Use Closed Total 0.0 0.0 72.0 Ibs Page 4 of 5 4. ~, ~ file://C:\DOCUME~ 1 \rking\LOCALS~ 1 \Temp\TKSZ6W7E.htm 10/10/2006 Page 5 of 5 ~, 1 IRRITANTS -- Solids Storage Location: Stockroom AGGREGATE PHYSICAL HAZARDS 1 COMPRESSED GASES -Inert Storage Location: Stockroom -Upstairs AGGREGATE PHYSICAL HAZARDS 1 *Non-Hazardous 24.0 0.0 0.0 24.OIbs Storage Use Open Use Closed Total 2616.0 0.0 0.0 2616.0 CF Storage Use Open Use Closed Total 60.0 0.0 0.0 60.OIbs ~: L' file://C:\DOCUME~ 1 \rking\LOCALS~ 1 \Temp\TKSZ6W7E.htm 10/10/2006 ;~ PRODUCT SAFETY DATA SHEET BUTANE AND A~IIXTURES 1. Product identification Specific risk :HIGHLY FLAMMABLE Vame Butane. Super butane. Butane-Propane mix Nature LPG Presentation Co%man~ Containers Gas contained Butane Su Butane But.-Prao .mix Campingaz 901 - 404 - 907 X Campingaz GT 106 (90 g) X Campingaz C 206 (190 g) X or X Coleman 190 (190 g) X Coleman CV I00 (97 g) X Coleman CV 250 (220 g) X Coleman CV 500 {440 g) X Campingaz CV 270 (230 g) X or X Campingaz CV 360 (52 g) X , Campingaz CV 470 (450 g) X or X Campingaz CG 1750 (170 g) X Campingaz CG 3500 (350 g) X Taymar-Campingaz T 1750 (170 g) X Taymar-Campingaz T 3500 (350 g) X Taymar-Campingaz RF 80 (185 g) X Taymar-Campingaz RF 89 (277 g) X Taymar-Campingaz RF 90 (350 X Supplier. APPLICATION DES GAZ, Route de Brignais, 69230 ST GENIS LAVAL - Tel. {33) (0~ 78 86 87 00 2 - Composition/Information on components Nature Preparation Description Hydrocarbon mixtures mainly coniaitting butanes, butenes, propane and propene, odorised by merraptan Butane :composition in compliance with French decree of 3/9/79 (Pressure at 50°C < 6.9 bar) - .Super butane :mixture of butanes, butenes and propane (approx. 20%) Butane-Propane mix :mixture of butanes,.butenes and propane (approx. 3U %) N° CAS (substance) 685 12 91 4 N° EINECS 270 990 9 3 -Risk factors: Butane and its mixtures are manufactured, stored, transported and distributed under pressure in liquefied form. In normal conditions, they remain in sealed systems up until their final destruction by combustion (use), and are therefore never handled directly. The continual confinement of there gases is of utmost importance. Nevertheless. certain special precautions are rewmmended to prevent or deal with their accidental release into the atmosphere, i.e. a leak. vs - wosn~s 4; Physical and chemical properties Highly flammable Co%mon~ In the e~~ent of a leak, as gas is hea~zer than air, it has a tendency, in the absence of ventilation, to accumulate at the lowest possible levels. The intense heating of a container can cause it to nrpture, allowing the product to escape; the ignition of vapour can give rise to deflagration or explosion. Health hazards !n gaseous state. breathing in highly concentrated vapours can cause drowsiness, imoxication, narcosis and, in extreme cases, coma through the rarefaction of oxygen. In liquid state, it can cause cold brans. Environmental hazards: Inapplicable in. normal use conditions. 4 - k~rst aid In the event of serious accidents, call a doctor or request emergency medical assistance. Inhalation: The subject should be taken outdoor and kept in a resting position. If suffering from respirator}- difficulties or loss of consciousness, call a doctor immediateh and administer respiratory assistance. Skin Rinse thoroughly with water. Eyes Rinse thoroughly with water, keep the eye protected and consult a specialist. Flammation of clothing: Hose down with water. 5 - )ire-fighting measares Extinguishing means: Recommended :powder, C02, spraying with water in certain cases. Ill-advised :hosing with a concentrnted stream of water Ineffective :foam Recommendations Incomplete combustion creates toxic CO the inhalation of which is particulazly hazardous. It is dangerous to put out a flame if the leak cannot be completety stopped Protection of stocks: As soon as a fire breaks out, .evacuate all exposed flammable materials and LPG containers. Thoronghly cool by spraying with water all containers that cannot be evacuated Do not hose down with a concemrated stream of water. Container fire: If a containez that is connected to an appliance catches fire, do not throw or turn it upstde- down, as this can only ecacerbate the problem (spilling of liquid gas or container rupture). Try to close the valve, protecting your hands and forearms with a wet cloth. If possible. take the container outside without lying it down. Keep people away. Never tip a comainer on fire. 6 -Measures to he takes in case of accidental dispersion Storage In case of unignited liquid or gas leaks - Thoroughly air out the room -Keep away from all sources of flammation; avoid all elearical switching. - Avoid contact of the liquefied gas with the skin - Block off all low-level openings in close proximity (vent holes, drain holes) - Keep people awn}• - Call on specialised emergency assistance vs - twos: tvva / / Container ff the leak cannot be stopped by moving the valve, take the container outdoor, avoidinn as}~ impact and dispose of it in a safe area without tenting it upsidedown. 7 -Handling and storage 1andling Follow the instructions indicated on the contamers. Use only in well ventilated areas ; do not smoke Use exclusively with suitable appliances (indication on containers}. Always tee the containers in the upright position. In workshops, avoid the build up of electrostatic charges. Never look for a leak with a naked flame. Only soapy water should be used Storage -Store in a well vemilated area, well away from all sources of heat and ignition. - Do not expose containers to a temperature greater than 5U°C - Do not store beioa• floor level (basement or cellar,. for example) - Store. away from low-level points where vapotus can accumulate - Do not store in a vehicle (heating by the sun) - Avoid contact with strong oxidizing agents and keep away from combustible materials. Observe the regulations is force far storing in large quantities. 8 -Control of e=posure Generally inapplicable - Odorisation allows a 0.5% gas content in the air to be detected - ff the smell of gas is detected, search for the leak with soapy water before using the appliance - Always use in a well ventilated area to allow for the evacuation of fumes and products of combustion (CO, C02) Follow the instntctions 'enclosed with the appliance and those indicated on the containers. 9 -Physical and chemical properties Physical state Colour Auto-ignition temperature Flaaunability limits Iower Flash pount Boiling T° under 1 atm Relative vapour pressure (bar) max. at 15°C.. max. at 50°C Density (liquid at 50°C) Densitylair (15°C latm} Liquid in the container Gaseous at atmospheric pressure Colourless Characteristic approximately 400°C approx. 1.R % Upper :approx.- 8.8% less than -50°C Butane Super butane Butane-Propane Mix _ approx. -5°C -20°C -25°C approx. 1.7 2.2 2.8 approx. 6.9 7.5 8.6 kg/1 min. 0.513 0.51 0.50 approx. 2.01 2 1.95 3!S - 72°yl9°E Co%man~ 10 - Staltility-reactivity 11 -Toxicology Severe toxicit<~ 12 -Ecological information 13 - Elimination of waste: Materials: 14 -Product transport Rona - Product stable in normal conditions of use - No known decomposition products - Explodes or catches fire when exposed to heat or a source of ignition - Combustion products include nitrogen, carbonic gas and water vapour - Carbon monoxide (to~zc! is released durine bad combustion Inapplicable. LPGs are kept in closed containers until their destruction by combustion and thus the greatest danger is the ignition of ~~apours in the air following an acadental leak Breathing in highly concentrated vapours could result in drowsiness, intoxication or narcosis and, in extreme cases, coma. In the event of incomplete combustion, the ensuing release of carbon monoxide can cause dizziness. headaches, Ioss of muscular mobility and coma. As they evaporate instantly and are only slightly soluble in water, LPGs present no known . environmental hazards. Gas accidentally released into the atmosphere is rapidly diluted and undergoes photochemical decomposition. t ~ - As containers of LPGs always contain flaaunable vapours, never pierce or burn a cartridge, even when empty. -Emptying a container from liquefied gas shall only be made by specially Lrained people and according adapted instructions. - Observe the regulations in farce on waste for the disposal of empty cartridges. CV 36U :aluminium Other cartridges :steel sheet Refillable cylinders :steel All containers meet the requirements of the transport regulations. For transporting large quantities, follow the applicable safety regulations (road, sea, air i. ADR Class 2 Enumeration UNO No. 8901,904,907 2°F 1965 . cartridges 5°F 2(337 Danger label: No. 3 , Vehicle transport: place the containers in the upright position and never pa=k in direct sunlight. Sea IIviDG Class UNO No. Page 8901,904,907 2 1965 2147 prtridges 2 2037 2175 Air IATA Class UNO No. Passenger plane 8901,904,907 2.1 ~ 1965 Prior agreement cartridges ?.1 2037 « Cargo plane y~ vex d/S - 12~05~1998 Co%man~ 15 -Regulatory information: Dangerous preparation labelling Domestic premises: Caravans: 16 -Additional i~ormation: Applicable to 1.4.97 Symbol F+ :highly flammable Phrase R12 : highly flammable Phrases S2 « keep out of reach of children z~, S9 « store in a ventilated place >- , S i G « Store away from all flames or sources of ignition. Do not smoke », S3 S « Avoid the build-up of electrostatic charges ». Contains butadiene 1-3 refer to national regulations refer to national regulations Only to be used for the applications and with the appliances indicated oa the containers. Containers in compliance with existing regulations. Never refill an empty container, Safety data sheet established in application of EEC directive 91/155 -All information contained in this sheet is based on o~u knowledge. Sis . wog ~tv9s N ate r i a l 6 a f e t y D a t a S h e e t LaaterA !'uel (Coleman) 1. CHENICAI~ PRODUCT AND COT!dPANY IDENTIFICATION Calumet Lubricants Campaay ZT8O Waterfront Pkwy E. Suite 200 Indisaapoiis, IN 46214 CaNPANX CONTACT: Jennifer Hall TELEFHON6 NUMBSR: (318y949-2421 El~R(4ENCY TSLEPH NUD®ERS Darwin Parker Calumet Lubricant (318y832-4Z3b Sam - 4pm Cst M-F. Chemtrec (800)424-9300 .After Susinees Hrs. PRODUCT NAP66: Calumet Lantern Fuel (Colemartj ~RODUC~r conz3: 010-00 GHE1dICAL NAR$a Light Hydrotreated Distillate CAS N[IIR8gR: 6$+410-97-9 CHEISICAI, FAIiILY: Petroleum Hydrocarbon Naphtha CZ~IdICAL FORMCILA: C5-C9 2. C01E4'OSITIONJINFORMATION ON INtiREDILNTB - _ CWiCENTRATION INGREDIENT NAFIE EXPOSURE LIMITS PERCENT. BY VOLUME light Hydrotreated Distillate Petroleum Distillate (Naphtha) 100.E CA5 1lUMBER: 6$410-97-9 TWA-400ppm 3. HASAKD6 IDENTIFICATION *.**************************** 811ER4ENCY QVSRVIEW *********te****************w** * WARNING: Flammable Liquid and Vapor. Harmful if inhaled and mad cause • * delayed lung injury. Caa cause nervous system depression. Aspiration * * hazard if swallowed - can enter lunge and cause damage. Neap sway from * heat, sparks, and flame. Avoid breathing vapor. Use veatilatiaa * adequate to keep vapor below reeo:®Ieaded exposers li~tits. Avoid contact * * with eyes, akin and clothing. Wash thoroughly after handling. *********w*******************,r***~**************,t******************~rr~*******,r* POTENTIAL REACTS SFFSCTS BINARY QUTE OF ENTRY S A. . EYES Tests on similar materials suggest acute irritation. SKIN Tests on similar materials indicate acute irritation upon short-term exposure and chronic dermatitis on prolvaged contact. INf3ESTI0li Acute aspiration hazard. Tests on similar materials indicate possibility of the following symptoms: headache, .nausea, drowsiness, fatigue, pneumonitis, pulmonary edema, central nervous system depression, convulsions, and loss of consciousness. INBa~TION Acute i citation. Tests an siatilar materials indicate the pogs9.bility of the following symptoms: headache, nasal and reapiratary irritation, nausea, drows#.nese, breathlessness, fatigue, central nervous system depression, convulsions, acad. loss of consciousness. e OPTIC I Prolonged and or repeated contact with this material may produce skirt and eye irritation. Carcinogen listed by National Toxicology Program (NO) Revision Date: 03/19j98 Paqe 1 of 6 M a t e r i a.l S a f e t y D a t a S h e e t Lantern Fuel (Coleman) 3. HASARDS IDENTIFICATION -Continued CHRONIC fCAI+TCL,R INFORMATION) - Continued I. A. R. C. {NOj OSHA {NO) ACGIH {ATO) This product does not require a cancer hazard warning in accordance with the USFiA Hazard Communication Standard. MEDICAL COI~IDITIONS At#(~RAVATED BY $ZPOSDRS Personnel-with pre-existing skin disorders should avoid contact with this product. 4.. FIRST -AID i[BA6URES SS Flush eyes immediately with water a minimum of 15 minutes occasionally lifting lower and upper lids. Get medical attention promptly. 8lC~ wash skin thoroughly with soap and water. Immediately remove contaminated clothing and launder before reuse. If irritation or rash develops, obtain medical assistance. INGESTION Call a physician immediately. Do not induce vomiting except at the instruction of a physician. Never give anything by mouth to an unconscious person. INHALATION RemovQ patient to fresh air and consult a physician. If breathing is difficult, give oxygen. If not breathing give artificial respiration. 5. FIRS FIG$TIN~i MSASUl0~5 FLAlR[ABLE PROPEit',IISS FLAS'8 Po7.11To c0°F ~-18°C Tag Closed Cup AUTOIGNITIONs n/av,°F n/av,°C FLA1QdA8ILITY CLA$5: IB LO~bt EIPLOSIVE LI1~IIT (~) : n/av. ~ (estimated) UPPER EXPLOSIVE LIMIT (~j: n/av. $ (estimated) FIRE AND EXPL ION HA1iARDS Can form amenable mixtures with air and flash at roam temperature. Explosion hazard in fire situation. Vapor heavier than air and may travel considerable distance to a source of ignition and flash back. EETINGUISHING MEDIA Dry Chemical, carbon dioxide, and foam. CA(FTIOH: Water stream may spread fire. GIRL FIaHT,~NG INSTRDCTIONS Uae water spray only to cool containers exposed to flames. Do not enter enclosed or a confined work space without proper protective equipment. .Fire fighting personnel should wear respiratos-~- protection {positive pressure if available). If leak or spill has not ignited, use water spray to disperse the vapors. Products of combustion include fumes, smoke and carbon monoxide. 6. ACCIDENTAL RELEASE MfdASDREB Notify emergency response personnel. Evacuate area and remove ignition Bootees. Build dike to contain flow. Remove free liquid. Shut off ignition source. Contain spill and keep from entering waterways or sewers. Use personal protective equipment. Advise EPA state agency if required. Absorb Revision Date: 03/19/98 Page Z of 5 !4 a t e r i a l S a f e t y D a t a S h e e t Lantern Fuel {+GOleman} 6. ACCIbSNTAL RELEASE 1dEASURES - Co~atiat~ed on inert material. Shovel, sweep or vacuum spill and place in closed container for disposal. 7. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTION5 Store as OSHA Class IB flammable liquid. Keep away from flames, sparks or hot surfaces. Never use a torch to cut or weld on or near container. Empty ail containers can contain explosive vapors. Wash thoroughly after handling. Do not store with strong oxidizers. Lab eamplea should be stored and handled in a lab hood. Use explosion proof ventilation equipment. STORAGE PRECAUTIONS Empty containers retain product dangerous. Do not pressurize. storage Temperatures ambient or Storage Pressure: atmospheric residue (liquid and vapor) and can be less tiPOR1C/HYGIENIC PRACTICES Wash hands with soap and water before eating, drinking, smoking or use of toilet facilities. Take a Qhower after work if general contact occurs. Remove oil-soaked Clothing and launder before reuse. Launder or discard contaminated shoes and leather. gloves. 8. SIPOSURE CAATROI+S/PERSONAL PROTECTION F~dINEERING CAI~ROLS Use adequate ventilation to keep ail mists of this material below applicable standard(s). see Section on occupational exposure limits. EYEjFALL_PROTSCTIOIQ Safety glasses, splash goggles, or face shield as appropriate. Have suitable eye water wash available. SKIN PROTECTION Avoid prolonged and/or repeated skin contact. If grolonged contact cannot be avoided, wear protective impervious gloves and clothing. Acceptable materials for gloves are neoprene; nitrite; vi,ton. RB6PIRATORY PROTECTION Up to 500 ppm hexane / 4000 m naphtha, half mask organic vapor respirator. Up to 2580 ppm hexane / 20,000 ppm naphtha, full face organic vapor respirator or full face supplied air respirator. Greater than 2500 ppm hexane / 20,000 ppm naphtha. fire fighting, or unknown concentration, self contained breathing apparatus with positive pressure. OTHER~GENSRA'[, PROTI~CIION If there is a likelihood of splashing, an oil resistant clothing should be worn. Never wear oil soaked clothing. Launder or dry clean before wearing. Discard oil soaked shoes. Affix warning labels on containers in accordance with 29 CFR 19I0.12a0 (Hazard Communication Standard). Maintain local or dilution ventilation to keep air concentration below 50 ppm hexane / 400 ppm naphtha. Loading, unloading, tank gauging, etc., remain upwind. Request assistance of safety and industrial hygiene personnel to determine air concentrations. 9. BSYSICAL Akin C~EdICAL PROPERTIES APPEARANCE Clear liquid. ODOR Petroleum Naphtha. Revision Date: 03/19/98 Page 3 of 6 N ate r i a l S a f e t y D a t a S h e e t Laate~rn Fuel (COlemaa) 9. PHYSICAL AND GHENICAL PROPERTIEg - Continued dDOR THRESSCI,D r N.D. BASIG PHYSICAL PROPERTIES PHYSICAL BTATS: Liquid 80ILING POI~iT: ISP x100°F I$P X38°C 1~LTING POINT: N[A°F N/A°C VAPOR PRESSURE: 518 mm @ bQ°F VAPOR aENSITY {AIR=1): 3 SPECIFIC GRAVITY: Q.69 Water = 1 PAC~INd aEWSITY: NfA SOLRT$ILITY {H.~O) : negligible pSRCSrrT vos.AZlLSS: ioo VOLATILE ORGANIC COl~dPOONDS (VOC) CQ2QTEI~iT: 100.0 ~ EVAPORATION RATE: n/aa. pR: essentially neutral VISCOSITY: n/an. Physical data may vary slightly to meet specifications. 30. 6TASILITY AND REACTIVITY STABILITY: Stable under normal conditions CONDITIONS TO AVOID (STABILITY} Sources of ignition. INCON~ATIELE iSATBRIALS strong oxidisers.. HASARDOUS DECOb~OSITION PRODUCTS Incomplete combustion may produce fumes, smoke, carbon monoxide and other asphyxiants. HAZARDOUS POLYAU~RISATION: will not occur 11. ToEICALOGICAL IN!'ORNATIOH ACUTE STUDIES EYE EFFECTS Irritation on contact. SKIN EFFECTS May cause irritation or dermatitis with prolonged and repeated contact. ACUTE ORAL EFFECTS Tests on similar materials indicate an order of saute oral toxicity. ACUTE INHALATION EFFECTS Acute. toxicity expected on inhalation. NEDICAL CONDITIONS A~IGRAVATBD BY OV8RS7CPOSIIRB Aer:nat it i s and _ Sens it ive aki:1. This product is not listed as carcinogenic or a potential carcinogen by the National Toxicology Program, b the I.A.R.C. monographs or by OSHA. Nevertheless, good industrial hygienic practices are recommended. ~, Revision Date: 03j19/98 Page 4 of 6 b a t e r i a l S a f e t y D a t a S h e e t Lantern Fuel (Coleman} 1s. Ecozocxlcaw INFOa~-Tiox No specific ecological data are available for this product. Please refer to Section 6 for information regarding accidental releases and Section 15 for regulatory reporting information. 13. ,DISPOSAL CONSIDERATIONS Follow federal, state and local regulations. It "used", RCRA criteria must be determined. Do not flush to drain/storm sewer. Contxact to authorized disposal service. If permitted incineration may, be practical. Recommend recycling. 14. TRANSPORT INP'ORb~tATIQN PROPER SHIPPING 1~iAldB: Petroleum Distillates, nos, Class 3, UN 1268, PC II HASARI} CLASB: Class 3 Flammable Liquid DOT IDEIATIFICATION NUHSSRs UN1268 DOT SHIPPING LASSL: DOT Hazardous Material 13. REGIILATORY IDIFORRATION U . S . CRY INP'ORI~ATIO~N SARA 302 Threshold P anning Quantity: not applicable sARA 301 Reportable Quantity not applicable SARA 313. Categorises Immediate (Acute) Health Effects -- N Delayed (Chronic} Health Effects -- Y Fire Hazard -- Y Sudden Release of Pressure Hazard-- N Reactivity Hazard -- N EPA/TSCA Inventory: The components of this product are listed on the EPA/TSCA inventory of chemicals. EPA Hazard Classification Code: NOT APPLICABLE Comprehensive Environmental Response, Compensation and Liability-Act (CERCLA).: No chemicals in-this product are subject to the reporting requirements of CERCLA Section 101(14)(F). When this product i$ used in a mixture, or as an ingredient in another product, or in a manufacturing operation, the petroleum exclusion may terminate and an accidental spill may require reporting to the National Response Center. SARA TITLL III NO'ZIFICATIOHS AIiD I1tFORlAATIt1N SARA TITLE III - IiAZAKD CLASSES: Chronic Health Hazard Fire Hazard SARA TITLE III - SECTI04i 313 SUPPLIER NOTIFICATION The following chemicals are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and reauthorization Act of 1985 and 40 CFR Part 372: Cyclohexane N-Hexane CAS ,~ 110-82-7 IIp to 15wt ~ CAS ~ 110-54-3 Op to 25wt ~ 16. OTSER INFORMATION NP`PA HAZARD RATING - E3EALT8: 1 Slfight - FIRE: 4 Extreme -.REACTIVITY: 0 Negligible~° PRSPABED BY: Jennifer Hall P80NE: 1318)949-2421 SUPERCBDSS REDS DATER: 04/O1/9b Revised: Revision Date: 03/19/98 Page 5 of E Is a t e r i a l S a f e t y D a t a 8 Lee t Eastern Fuel (Colemaa) I6. OTHER INFORMATION - Continued 9. Physical Properties 15. SARA Title III 12. Tscalagical Information 2. Composition D25CLAIMSR OF $BPRESSED AND IMPLIED ~A~R~1lj'PIES The information contained herein i8 based upon data believed to be reliable and reflects our best prvfessioaal judgement. Although reasonable care has been taken in the preparation of this document, we exter-d no warrantiee and make no representations as to the accuracy or completeness of the information contained therein and assume no responsibility regarding the suitab ility of this information for the user's intended purpose or for the consequence of its use. Each individual should make a determination as to the suitability of the information for his/her particular purpose(s}. P. Revision Date: 03J19j98 - Page 6 of 6 ....~ err ~~.~ Arch Chemicals, Inc. FOR ANY EMERGENCY, CALL 24 HOIIRS/7 DAYS: 1-800-654-6911 FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC°: 1-800-424-9300 FOR ALL MSDS QUESTIONS & REQUESTS, CALL MSDS CONTROL: 1-800-511-MSDS THE FOLLOWING MSDS IS A KIT. IT CONSISTS OF THE FOLLOWING FOUR COMPONENT MSDS: (1) HTH® STABILIZER AND CONDTTIONER (2) HTH® TEST STRIPS (3) HTH® RELIABLE CLEANING GRANULES CHLORINATOR (4) HTH®SHOCK'N SWIM PRODUCT NAME: HTH STABILIZER AND CONDITIONER SECTION 1 PRODIICT AND COMPANY IDENTIFICATION REVISION DATE: 05-24-2004 SUPERCEDES: 12-02-2002 MSDS NO: 00011-0059 - 61309 MANUFACTURER: Arch Chemicals, Inc. 501 Merritt 7 PO Box 5204 Norwalk, CT 06856-5204 SYNONYMS: Isocyanuric acid, Cyanuric acid CHEMICAL FAMILY: Isocyanurate FORMULA: (HCNO)\3 DESCRIPTION: Chlorine stabilizer for swimming pool use. OSHA HAZARD CLASSIFICATION: Skin and eye irritant SECTION 2 COMPONENT DATA PRODUCT COMPOSITION CAS or CHEMICAL NAME: Cyanuric acid CAS NUMBER: 108-80-5 PERCENTAGE RANGE: 90-99$ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Sulfuric acid CAS NUMBER: 7664-93-9 PERCENTAGE RANGE: 0-1$ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: OSHA(PEL) ACGIH (TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 1.0 1.0 CEILING: None None STEL: None 3.0 P CAS or CHEMICAL NAME: Water CAS NUMBER: 7732-18-5 HTH° Pop Up Pool Start Up & Maintenance Kit PERCENTAGE RANGE: 0-10% HAZARDOUS PER 29 CFR 1910.1200: No EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Ammelide CAS NUMBER: 645-93-2 PERCENTAGE RANGE: 0-0.5~ HAZARDOUS PER 29 CFR 1910.1200: No EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Ammeline CAS NUMBER: 645-92-1 PERCENTAGE RANGE.: 0-0.5% HAZARDOUS PER 29 CFR 1910.1200: No EXPOSURE STANDARDS: None Established SECTION 3 PRECAUTIONS FOR SAFE HANDLING AND STORAGE DO NOT TAKE INTERNALLY. AVOID CONTACT WITH SKIN, EYES, AND CLOTHING.. UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER. STORAGE CONDITIONS: Store in a cool, dry area. DO NOT STORE AT TEMPERATURES ABOVE: 60 Deg.C (140 Deg.F) PRODUCT STABILITY AND COMPATIBILITY SHELF LIFE LIMITATIONS: Unlimited INCOMPATIBLE MATERIALS FOR PACKAGING: None known INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT: None known SECTION 4 PHYSICAL DATA APPEARANCE: White granules or powder MELTING POINT: Sublimes at 320-330 Deg.C (608-626 Deg.F) BOILING POINT: Not Applicable DECOMPOSITION TEMPERATURE: Not Applicable SPECIFIC GRAVITY: 2.5 BULK DENSITY: 0.79-0.85(8/cc) pH: 3.8-4.0 VAPOR PRESSURE @ 25 DEG.C: Not Applicable SOLUBILITY IN WATER: 0.27% @ 25 Deg.C VOLATILES, PERCENT BY VOLUME: Not Applicable EVAPORATION RATE: Not Applicable VAPOR DENSITY:. Not Applicable MOLECULAR WEIGHT: 129.08 ODOR: None COEFFICIENT OF OIL/WATER DISTRIBUTION: Not Applicable SECTION 5 PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS PERSONAL PROTECTION FOR ROUTINE USE OF PRODUCT: RESPIRATORY PROTECTION: Respiratory protection not normally needed. If dusting occurs, wear a NIOSH approved dust respirator. VENTILATION: Use local exhaust ventilation to minimize dust levels. SKIN AND EYE PROTECTIVE EQUIPMENT: Wear gloves and chemical goggles to avoid skin and dye contact. EQUIPMENT SPECIFICATIONS: RESPIRATOR TYPE: Not normally needed GLOVE TYPE: Neoprene or chemically impermeable 91906 HTH® Pop Up Pool Start Up & Maintenance Kit SECTION 6 FIRE AND EXPLOSION HAZARD INFORMATION FLAMMABILITY DATA: FLAMMABLE: No COMBUSTIBLE: No PYROPHORIC: No FLASH POINT: Not Applicable AUTOIGNITION TEMPERATURE: Not Applicable FLAMMABLE LIMITS AT NORMAL ATMOSPHERIC TEMPERATURE AND PRESSURE (PERCENT VOLUME IN .AIR) Not Applicable NFPA RATINGS: Not Established HMIS RATINGS:_ Health: 1 Flammability: 0 Reactivity: 0 EXTINGUISHING MEDIA: Not Applicable FIRE FIGHTING TECHNIQUES AND COMMENTS: Use water to cool containers exposed to fire. Use extinguishing agent suitable for surrounding material. SECTION 7 REACTIVITY INFORMATION CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE: TEMPERATURES ABOVE: 330 Deg.C (626 Deg.F) MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE: No HAZARDOUS POLYMERIZATION: Will Not Occur INCOMPATIBLE MATERIALS: Oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, Carbon dioxide, Oxides of nitrogen, and cyanic acid. SUMMARY OF REACTIVITY: OXIDIZER: No PYROPHORIC: No ORGANIC PEROXIDE: No WATER REACTIVE:. No SECTION 8 FIRST AID EYES: Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Call a physician at once. SKIN: Immediately flush with water for 15 minutes. Wash the contaminated skin with soap and water. If irritation develops, call a physician. If clothing comes in contact with the product, the clothing should be removed immediately and it should be laundered before re-use. INGESTION: Immediately drink water to dilute. Consult a physician. INHALATION: If person expePriences nausea, headache or dizziness, person should stop work immediately and move to fresh air until these symptoms disappear. If breathing is difficult, administer oxygen, keep the person warm and at rest. Call 91906 HTH® Pop Up Pool Start Up & Maintenance Kit a physician. In the event that an individual inhales enough vapor to lose consciousness, person should be moved to fresh air at once and a physician should be called immediate) y. If breathing has stopped, artificial respiration should be given immediately. In all cases, ensure adequate ventilation and provide respiratory protection before the person returns to work. SECTION 9 TOXICOLOGY AND HEALTH INFORMATION ROUTES OF ABSORPTION Ingestion, skin and eye contact WARNING STATEMENTS AND WARNING PROPERTIES DO NOT TAKE INTERNALLY. MAY CAUSE MILD SKIN AND EYE IRRITATION. INHALATION OF DUST MAY CAUSE MILD MUCOUS MEMBRANE AND RESPIRATORY ' IRRITATION. HUMAN THRESHOLD RESPONSE DATA ODOR THRESHOLD: No Data IRRITATION THRESHOLD: No Data IMMEDIATELY DANGEROUS TO LIFE OR HEALTH: The IDLH concentration has not been established for this product. SIGNS, SYMPTOMS, AND EFFECTS OF EXPOSURE INHALATION Acute: No significant adverse effects to health would be expected to occur ~ from inhalation with normal use of this product. However, if dust is ~ created and inhaled, inhalation may cause mild irritation to the ~ throat, mucous membranes and upper respiratory tract. i CHRONIC: i None known or reported I 1 SKIN ~ ACUTE: Skin contact may cause a mild irritation consisting of transient I redness. This irritant effect would not be expected to result in permanent damage. ~ CHRONIC: I There are no known or reported effects from chronic exposure except for effects similar to those experienced from single exposure. EYE Contact with the eyes may cause a mild irritation consisting of ' redness, swelling and mucous membrane discharge to the conjunctiva. No corneal damage or visual impairment would be expected to occur. INGESTION ACUTE: j Ingestion may cause gastrointestinal discomfort with any or all of the following symptoms: nausea, vomiting, lethargy or diarrhea. CHRONIC: I ~° There are no known or reported effects from chronic exposure except for effects similar to those experienced from single exposure. 9,1906 HTH° Pop Up Pool Start Up & Maintenance Kit I MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None known or reported. INTERACTIONS WITH OTHER CHEMICALS WHICH ENHANCE TOXICITY None known or reported ANIMAL TOXICOLOGY ACUTE TOXICITY: Inhalation LC 50: No Data Dermal LD 50: > 2 g/kg (rabbit) Oral LD 50: > 5 g/kg (rat) Irritation: May cause mild eye and skin irritation ACUTE TARGET ORGAN TOXICITY: No organs known to be damaged from exposure to this product. May cause mild skin and eye irritation. CHRONIC TARGET ORGAN TOXICITY: Based on data from toxicological investigations, cyanuric acid does not result in direct target organ damage. Damage to the kidneys and .bladder has been observed in rats when these animals are provided a saturated solution (5375 ppm) of cyanuric acid for their drinking water. During excretion of high amounts by the kidney, stones of cyanuric acid can form (calculi) resulting in mechanical damage which is secondary to stone formation. This effect would not pose a risk to humans during manufacturing, use as a~disinfectant in swimming pools, and even consumption of dilute solutions (1-10 ppm) of cyanuric acid. cyanuric acid is excreted unchanged rapidly via the kidneys: It lacks the potential to bioaccumulate in the body. 'REPRODUCTIVE AND DEVELOPMENTAL TOXICITY: There are no known or reported effects on reproductive function or -fetal development from exposure to this product. Monosodium cyanurate (the sodium salt of cyanuric acid) has been tested b"y oral gavage in pregnant rats and rabbits. No teratogenic effects were. seen in the offspring of either species. Sulfuric acid aerosol (95.7$ purity) was tested in pregnant mice and rabbits exposed to concentrations of 0, 5 and 20 mg/cubic meter by inhalation on gestational days 6-15 and 6-18, respectively. No reproductive or developmental effects were seen in either species at any of the exposure concentrations utilized. CARCINOGENICITY: i This product is not known or reported to be carcinogenic by any reference source including IARC, OSHA, NTP or EPA. Laboratory toxicological studies in rats and mice (lifetime exposure) indicate that cyanuric acid is not carcinogenic. Sulfuric acid is not known or reported to be carcinogenic by any re~erence source including: IARC, OSHA, NTP, or EPA. IARC evaluated several epidemiology studies where individuals in a variety of industries had been exposed to a mixture of strong inorganic acid mists and concluded that there is sufficient evidence that 91906 HTH® Pop Up Pool Start Up & Maintenance Kit occupational exposure to a mixture of strong inorganic acid mists is carcinogenic to humans. Because cancer has not been observed in animals when they are exposed only to sulfuric acid mist, exposure to sulfuric acid by itself was not determined to be carcinogenic to humans. MUTAGENICITY: This product is not known or reported to be mutagenic. Cyanuric acid was determined to be non-mutagenic in the Ames assay, both with and without metabolic activation. Monosodium cyanurate (the sodium salt of Cyanuric acid) has been tested in a battery of mutagenicity/genotoxicity assays and no mutagenic or genotoxic activity was detected in any of these assays. AQUATIC TOXICITY: Cyanuric acid: Bluegill sunfish: 96 hr. LC50: > 2,100 mg/1 Fathead minnow: 96 hr. LC50: > 2,100 mg/1 Rainbow trout: 96 hr. LC50: > 2,100 mg/1 Daphnia magna: 48 hr. LC50: > 1,000 mg/1 Algae: 96 hr. EC50: 655 mg/1 Toxicity to wildlife: Monosodium cyanurate (sodium salt of Cyanuric acid): Mallard duck: 8 day dietary LC50: > 10,000 ppm Bobwhite quail: 8 day dietary LC50: > 10,000 ppm SECTION 10 TRANSPORTATION INFORMATION THIS MATERIAL IS NOT REGULATED AS A DOT HAZARDOUS MATERIAL. SECTION 11 SPILL AND LEAKAGE PROCEDURES FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC AT 800-424-9300. REPORTABLE QUANTITY: None Established (Per 40 CFR 302.4) SPILL MITIGATION PROCEDURES: Air Release - Not Applicable Water Release - this material is heavier than water. This material is very slightly soluble in water. Land Spill - Keep spill materials dry and free of all foreign matter. Containerize in a clean, dry container. SPILL RESIDUES: Dispose of per guidelines under Section XII, WASTE DISPOSAL. PERSONAL PROTECTION FOR EMERGENCY SPILL AND FIRE-FIGHTING SITUATIONS: No extra protection required beyond that listed in Section v (in case of fire, use normal fire fighting equipment), including a NIOSH approved self_contained breathing apparatus (SCBA). SECTION 12 WASTE DISPOSAL 91906 HTH® Pop Up Pool Start Up & Maintenance Kit If this product becomes a waste, it DOES NOT meet the criteria of a ha zardous" waste as defined under 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of Subpart C; nor is it listed as a hazardous waste under Subpart D. As a'nonhazardous solid waste it should be disposed of in accordance with local, state, and federal regulations by disposal in a secure chemical landfill. CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINAT ION FROM THE USE OF THIS MATERIAL. THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH-ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. SECTION 13 ADDITIONAL REGULATORY STATUS INFORMATION TOXIC SUBSTANCES CONTROL ACT: This substance is listed on the Toxic Sub- stances Control Act inventory. SUPERFUND AMENDMENT AND REAUTHORIZATION ACT TITLE 3: HAZARD CATEGORIES, PER 40 CFR 370.2: HEALTH: Immediate (Acute) PHYSICAL: None EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW, PER 40 CFR 355, APP. A: EXTREMELY HAZARDOUS SUBSTANCES - THRESHOLD PLANNING QUANTITY: None Established SUPPLIER NOTIFICATION REQUIREMENTS, PER 40 CFR 372.45: This mixture or tradename product contains a toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title 3 of the Superfund Ammendments and Reauthorization Act of 1986 and 40 CFR 372. (See Section 2 for Composition) CHEMICALS LISTED ARE: Sulfuric Acid SECTION 14 ADDITIONAL INFORMATION MSDS REVISION STATUS: 3 year review SECTION 15 MAJOR REFERENCES 1. Lusby, Andrea, F., et al., Variation in Mutagenicity of s- Triazine Compounds Tested on Four Salmonella Strains. Environmental Mutagenesis, Vol. 1, No. 3, pp. 287-290, 1979. 2. Canelli, Edmondo, Chemical, Bacteriological and Toxicological Properties of Cyanuric Acid and Chlorinated Isocyanurates as Applied to Swimming Pool Disinfection." American Journal of Public Health, Vol. 64, No. 2, pp. 155-162, February 1974. 3. Acute Toxicity of Cyanuric Acid to the Water Flea (Daphnia Magna). EG and G, Bionomics Aquatic Toxicology Laboratory, Wareham, MA. Study # ICG/T-78-076, October 1977. 4. Report to Monsanto Company, Four Day Static Aquatic Toxicity Studies with Monosodium Cyanurate, Lot #P-231291 in Rainbow Trout P and Blue Gils. Industrial Bio-Test Laboratories, Inc., Northbrook, IL. BTL #75-36, IBT #621-07227. September 5, 1975 91906 HTH~ Pop Up Pool Start Up & Maintenance Kit • Additional references are available upon request. PRODUCT NAME: HTH® SHOCK 'N SWIM SECTION 1 PRODIICT AND COMPANY IDENTIFICATION REVISION DATE: 03-04-2004 SUPERCEDES:02-18-2004 MSDS NO : 02410-9001 - 51113 Manufacturer: Arch Chemicals, Inc. 501 Merritt 7 PO Box 5204 Norwalk, CT 06856-5204 SYNONYMS: None CHEMICAL FAMILY: Hypochlorite Mixture FORMULA: Not Applicable/Mixture DESCRIPTION: Sanitizer and Oxidizer OSHA HAZARD CLASSIFICATION: Toxic by inhalation, corrosive to eyes and skin, skin and eye hazard, lung toxin SECTION 2 COMPONENT DATA PRODUCT COMPOSITION •CAS or CHEMICAL NAME: Calcium hypochlorite CAS NUMBER: 7778-54-3 PERCENTAGE RANGE: 40-55% HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: 1 mg/cubic meter (15 min. STEL - TWA) Arch chemicals Internal Exposure Standard CAS or CHEMICAL NAME: Sodium chloride CAS NUMBER: 7647-14-5 PERCENTAGE RANGE: 5-15$ HAZARDOUS PER 29 CFR 1910.1200: No EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Calcium chlorate CAS NUMBER: 10137-74-3 PERCENTAGE RANGE: 0-4~ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Calcium chloride CAS NUMBER: 10043-52-4 PERCENTAGE RANGE: 0-4$ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Calcium hydroxide CAS NUMBER: 1305-62-0 PERCENTAGE RANGE: 0-5~ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: e OSHA(PEL) ppm mg/cubic-meter ACGIH (TLV) ppm mg/cubic-meter 91906 HTH° Pop Up Pool Start Up & Maintenance Kit TWA: None CEILING: None STEL: None 5 None None CAS or CHEMICAL NAME: Calcium carbonate CAS NUMBER: 471-34-1 PERCENTAGE RANGE: 0-4% HAZARDOUS PER 29 CFR 1910.120.0: Yes EXPOSURE STANDARDS: OSHA (PEL) ACGIH (TLV) ppm mg/cubic-meter ppm mg/cubic-meter TWA: 15 (Total dust) 10 5 (Respirable fraction) CEILING: None None STEL: None None CAS or CHEMICAL NAME: Magnesium sulfate heptahydrate CAS NUMBER: 10034-99-8 (anhydrous 7487-88-9) PERCENTAGE RANGE: 25-350 HAZARDOUS-PER 29 CFR 1910.1200:.Yes EXPOSURE STANDARDS: None Established . CAS or CHEMICAL NAME: Water CAS NUMBER: 7732-18-5 PERCENTAGE RANGE: 17-22g HAZARDOUS PER 29 CFR 1910.1200: No EXPOSURE STANDARDS: None Established SECTION 3 PRECAUTIONS FOR SAFE HANDLING AND STORAGE DO NOT TAKE INTERNALLY. AVOID INHALATION OF DUST AND FUMES. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. STORAGE CONDITIONS: Keep product tightly sealed in original containers. Store product in a cool, dry, well-ventilated area. Store away from combustible or flammable products. Keep product packaging clean and free of all contamination, including, e.g., other pool treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. DO NOT STORE AT TEMPERATURES ABOVE: 52 Deg.C (125 Deg.F) In the event that the calcium hypochlorite were to separate from the blend, storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Also, the magnesium sulfate heptahydrate will begin to loose water of crystallization at approximately 150 Deg.C (302 Deg.F) Should all the water of crystallization be lost, the likelihood of rapid decomposition occurring, as above, would be increased. PRODUCT STABILITY AND COMPATIBILITY SHELF LIFE LIMITATIONS: Shelf life (that is, the period of time before the product goes below stated label strength) is determined by storage time and temperatures.PDo not store product at temperatures above 52 Deg.C (125 Deg.F) When stored under moderate temperature 91906 HTH® Pop Up Pool Start Up & Maintenance Kit conditions, product will• maintain stated label strength for approximately two years. Prolonged storage at 35 Deg.C (95 Deg.F) or above will significantly shorten the shelf life. Storage in a climate- controlled storage area or building is recommended in those-areas where extremes of high temperature occur. INCOMPATIBLE MATERIALS FOR PACKAGING: Product packaging must be clean and free of contamination by other materials, including, e.g., other pool .treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT: Do not allow product to come in contact with other materials, including, e.g., other pool treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. SECTION 4 PHYSICAL DATA APPEARANCE: White granules FREEZING POINT: Not Applicable BOILING POINT: Not Applicable DECOMPOSITION TEMPERATURE: Onset - Approx. 170-180 Deg.C (338-356 Deg :F) SPECIFIC GRAVITY: Not Applicable BULK DENSITY: 0.8 g/cc, loose pH @ 25 DEG.C: 10.0-10.8_(1 soln.) SOLUBILITY IN WATER: Approximately 18$ @ 25 Deg.C. (Product contains calcium hydroxide and calcium carbonate which will leave a residue.) VAPOR PRESSURE @ 25 DEG.C: Not Applicable VOLATILES, PERCENT BY VOLUME: Not Applicable EVAPORATION RATE: Not Applicable VAPOR DENSITY: Not Applicable MOLECULAR WEIGHT: 143 (Active ingredient) ODOR: Chlorine-like COEFFICIENT OF OIL/WATER DISTRIBUTION: Not Applicable SECTION 5 PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS PERSONAL PROTECTION FOR ROUTINE USE OF PRODUCT: RESPIRATORY PROTECTION: Wear a NIOSH approved respirator if dusts are created. VENTILATION: Use local exhaust ventilation to minimize dust and chlorine level where industrial use occurs. Otherwise, ensure good general ventilation. SKIN AND EYE PROTECTIVE EQUIPMENT: Wear gloves and safety glasses to avoid skin and eye contact. Where industrial use occurs, chemical goggles or full impermeable suit may be required. EQUIPMENT SPECIFICATIONS (WHEN APPLICABLE): RESPIRATOR TYPE: NIOSH approved full face piece air-purifying respirator with chlorine cartridges and dust/mist prefilter. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or in exposure levels which exceed 10X the PEL. 91906 HTH° Pop Up Pool Start Up & Maintenance Kit PROTECTIVE CLOTHING TYPE: Neoprene, Nitrile, Natural rubber (This includes: gloves, boots, apron protective-suit) SECTION 6 FIRE AND EXPLOSION HAZARD INFORMATION This product contains an ingredient which is both a strong oxidizer and is chemically-reactive with many substances. Strong oxidizers are capable of intensifying a fire once started. Because of this, any contamination of the product with other substances by spill or otherwise should be avoided. Also see section 3 FLAMMABILITY DATA: FLAMMABLE: No COMBUSTIBLE: No PYROPHORIC: No FLASH POINT:. Not Applicable AUTO2GNITION TEMPERATURE: Not Applicable FLAMMABLE LIMITS AT NORMAL ATMOSPHERIC TEMPERATURE AND PRESSURE (PERCENT VOLUME IN AIR) UEL - Not Applicable LEL - Not Applicable NFPA RATINGS: NFPA Oxidizer Class: Meets the criteria of an NFPA Class 1 Oxidizer HMIS RATINGS: Health: 3 Flammability: 0 Reactivity: 1 EXTINGUISHING MEDIA: Water only FIRE FIGHTING TECHNIQUES AND COMMENTS: Use water to cool containers exposed to fire. Also see Section 11. OTHER: Do not use dry extinguishers containing ammonium Compounds SECTION 7 REACTIVITY INFORMATION CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE: TEMPERATURES ABOVE: 170 Deg.C (338 Deg.F) MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE: NO HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBLE MATERIALS: This product is chemically reactive with many substances, including, e.g., other pool treatment products, acids, organics, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, corrosive, flammable or combustible materials. HAZARDOUS DECOMPOSITION PRODUCTS: Chlorine gas OTHER CONDITIONS TO AVOID: Storage at temperatures >125 Deg.F (52 Deg.C) Prevent ingress of humidity and moisture into container or package. Always close the lid. SUMMARY OF REACTIVITY: OXIDIZER: PYROPHORIC: ORGANIC PEROXIDE: WATER REACTIVE: (See also Section 6) No (Contains an oxidizer.- calcium hypochlorite) No NO No 91906 HTH® Pop Up Pool Start Up & Maintenance Kit OTHER: Arch calcium hypochlorite products meet the specifications of ASTM method E-487-74 as -set forth in 49 C. F. R. Sec. 173.21, Title 49-Code of-Federal Regs. (DOT Regs.) SECTION 8 FIRST AID EYES: Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Call a physician at once. SKIN: Immediately flush with water for at least 15 minutes. Call a physician. If clothing comes in contact with the product, the clothing should be removed immediately and should be laundered before re-use. INGESTION: Immediately drink large quantities of water. DO NOT induce vomiting. Call a physician at once. DO NOT give anything by mouth if the person is unconscious or if having convulsions. INHALATION: Remove victim to fresh air. Support respiration if needed. Call a physician. SECTION 9 TOXICOLOGY AND HEALTH INFORMATION ROUTES OF ABSORPTION Inhalation, skin and eye contact, ingestion WARNING STATEMENT AND WARNING PROPERTIES MODERATELY TOXIC IF SWALLOWED. AVOID BREATHING DUST OR FUMES. HARMFUL IF PRODUCT IS INHALED IN HIGH CONCENTRATIONS. CAUSES EYE, DIGESTIVE TRACT AND RESPIRATORY TRACT BURNS. DRY MATERIAL CAUSES MODERATE SKIN IRRITATION. WET MATERIAL CAUSES SKIN BURNS HUMAN RESPONSE DATA ODOR THRESHOLD: Approximately 2.0 mg/cubic-meter, based on odor threshold of chlorine.. IRRITATION THRESHOLD: Approximately 18-31 mg/cubic meter, based on the irritation threshold of chlorine. IMMEDIATELY DANGEROUS TO LIFE OR HEALTH: Approximately 63 mg/cubic-meter, based on IDLH concentration of chlorine. SIGNS, SYMPTOMS, AND EFFECTS OF EXPOSURE INHALATION 'ACUTE: Inhalation of dust or vapor from this product can be irritating to the nose, mouth, throat and lungs. In confined areas, mechanical agitation can result in high levels of dust, and reaction with incompatible materials (as listed in Section VII) can result in high concentrations of chlorine vapor, either of which may result in burns to the respiratory tract, producing lung edema, shortness of breath, wheezing, choking, chest pains, impairment of lung function and possible permanent lung damage. CHRONIC: Chronic (repeated) inhalation exposure may cause impairment of ~ ung function and permanent lung damage. EYE 91906 HTH° Pop Up Pool Start Up & Maintenance Kit Severe irritation and/or burns can occur following eye exposure. Contact may cause impairment of vision and corneal damage. SKIN ACUTE: Dermal exposure to dry material causes moderate skin irritation characterized by redness and swelling. Dermal exposure to wet material can cause severe irritation and/or burns characterized by redness, swelling and scab formation. Prolonged skin exposure may cause permanent damage. . CHRONIC: Effects from chronic skin exposure would be similar to those from single exposure. In. addition, chronic exposure to wet material may cause effects secondary to tissue destruction. INGESTION ACUTE: Irritation and/or burns can occur to the entire gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding and/or tissue ulceration. Significant exposure to this material can lead to serious health effects and/or death. CHRONIC: There are no known or reported effects from chronic exposure except for effects similar to those experienced from single exposure. The acute corrosivity of this product makes chronic ingestion of significant amounts unlikely MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Asthma, respiratory and cardiovascular disease INTERACTIONS WITH OTHER CHEMICALS WHICH ENHANCE TOXICITY None known or reported ANIMAL TOXICOLOGY ACUTE TOXICITY: Inhalation LC 50: >2.04 mg/1 (lhr,, rat); > 0.51 mg/1 (4 hr., rat) - extrapolated from inhalation toxicity studies using calcium hypochlorite Oral LD 50: Approximately 1200 mg/kg. (.rat) based on extrapolation from oral toxicity studies using calcium hypochlorite Dermal LD 50: > 2 g/kg. (rabbit) Irritation: Causes burns to eyes. Dry material causes skin irritation, wet material causes skin burns. ACUTE TARGET ORGAN TOXICITY: This product is corrosive to the eyes and upon inhalation may cause irritation to mucous membranes and respiratory tract. The dry material is irritating to the skin. However when wet, it will produce burns to the skin CHRONIC TOXICITY: There are no known or reported effects from repeated exposure except those secondary to burns. REPRODUCTIVE TOXICITY: ~ Calcium hypochlorite has been tested for teratogenicity in laboratory animals. Results of this study have shown that calcium hypochlorite is not a teratogen. 91906 HTH® Pop Up Pool Start Up & Maintenance Kit CARCINOGENICITY: This product is not known or reported to be carcinogenic by any reference source, including: IARC, OSHA, NTP or EPA. One hundred mice were exposed dermally 3 times a week for 18 months to .a solution of calcium hypochlorite. Histopathological examination failed to show an increased incidence of tumors. IARC (International Agency for Research on Cancer) reviewed studies conducted with several hypochlorite salts. IARC has classified .hypochlorite salts as having inadequate evidence for carcinogenicity to humans and animals. IARC therefore considers hypochlorite salts to be not classifiable as to their carcinogenicity to humans. (Group 3 substance). MUTAGENICITY: Calcium hypochlorite has been tested in the dominant lethal assay in male mice, and it did not induce a dominant lethal response. Calcium hypochlorite has been reported to produce mutagenic activity in two in vitro assays. It has, however, been shown to lack the capability to produce mutations in animals based on results from the micronucleus assay. In vitro assays frequently are inappropriate to judge the mutagenic potential of bactericidal chemicals due to a high degree of cellular toxicity. The concentration which produces mutations in these in vitro assays is significantly greater than the concentrations used for disinfection. Based on high cellular toxicity in in vitro assays and the lack of mutagenicity in animals, the risk of genetic damage to humans is judged not significant. AQUATIC TOXICITY: Bluegill, 96 hr. LC50: Approximately 0.12 mg/1 (nominal, static) based on extrapolation from studies using calcium hypochlorite Rainbow trout, 96 hr. LC50: 0.22 mg/1 (nominal, static) based on extrapolation from studies using calcium hypochlorite Daphnia magna, 48 hr. LC50: 0.15 mg/1 (nominal, static) based on extrapolation from studies using calcium hypochlorite TOXICITY TO WILDLIFE: Bobwhite quail, dietary LC50: > 7,000 ppm based on extrapolation from studies using calcium hypochlorite Mallard ducklings, dietary LC50: > 7,000 ppm based on extrapolation from studies using calcium hypochlorite Bobwhite quail, oral LD50: Approximately 4800 mg/kg. based on extrapolation from studies using calcium hypochlorite SECTION 10 TRANSPORTATION INFORMATION THIS MATERIAL IS REGULATED AS A DOT HAZARDOUS MATERIAL ONLY IF PACKING CONTAINS 10 POUNDS OR GREATER OF CALCIUM HYPOCHLORITE DOT DESCRIPTION FROM THE HAZARDOUS MATERIALS TABLE 49 CFR 172.101: Land (U.S. DOT): PACKING CONTAINS 10 POUNDS OR GREATER OF CALCIUM HYPOCHLORITE: RQ, Other Regulated Substances, Solid, NOS (Calcium Hypochlorite), 9, NA 3077, III e U.S. DOT Hazardous Substance (49 CFR 172.101, Appendix A) Yes; RQ = 10 Lbs. 91906 HTH~ Pop Up Pool Start Up & Maintenance Kit Hazard Label/Placards: Class 9 - Miscellaneous Hazardous Materials 2000 Emergency Response Guide# 171 Water (IMDG) Not Regulated Marine Pollutant: Not Listed Air(IATA/ICAO) Not Regulated 1) Inhalation toxicity data indicates product to be .toxic by inhalation, however, diameter of over 90~ of granules well exceed 10 micron limit. Particles cannot be inhaled through lungs. 2)Important: Product not regulated in transport for U.S. ground shipments, if package does not contain 10 Lbs. or greater of calcium hypochlorite. SECTION 11 SPILL AND LEAKAGE PROCEDURES FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC AT 800-424-9300. REPORTABLE QUANTITY: 10 lbs. (as Calcium hypochlorite) Per 40 CFR 302.4 SPILL MITIGATION PROCEDURES: Hazardous concentrations in air may be found in local spill area and immediately downwind. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. AIR RELEASE: Vapors may be suppressed by the use of a water fog. A11 water utilized to assist in fume suppression, decontamination or fire suppression may be contaminated and must be contained before disposal and/or treatment. WATER RELEASE: This material is heavier than water. This material is soluble in water. Monitor all exit water for available chlorine and pH. Advise local authorities of any contaminated water release. LAND SPILL: Contact at 1-800-6546-911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction which may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material. Using a clean broom or shovel, place all spilled product into plastic bags, and place those bags into a clean, dry disposal container, properly marked and labeled. Disposal containers made of plastic or metal are recommended. Do not seal disposal containers tightly. Immediately remove all product in disposal containers to an isolated area outdoors. Place all damaged packaging material in a disposal container of water to assure decontamination (i.e. removal of all product) before disposal. Place all undamaged packaging in a clean, dry container properly marked and labeled. Call for disposal procedures. SPILL RESIDUES: Dispose of per guidelines under Section 12, WASTE DISPOSAL. 91906 HTH° Pop Up Pool Start Up & Maintenance Kit This material may be neutralized for disposal; you are requested to contact ACEAN at 800-6546-911 before beginning any such operation. PERSONAL PROTECTION FOR EMERGENCY SPILL AND FIRE-FIGHTING SITUATIONS: Response to a large quantity spill (100 pounds or greater) or when dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air respirator or self contained breathing apparatus (SCBA), chemical resistant gloves, coveralls and boots. In case of fire, this personal protective equipment should be used in addition to normal fire fighter equipment. SECTION 12 WASTE DISPOSAL If this product becomes a waste, it DOES NOT meet the criteria of a hazardous waste as defined under 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of Subpart C, nor is it listed as a hazardous waste under Subpart D. As a nonhazardous waste, it should be disposed of in accordance with local, state and federal regulations. CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINAT ION FROM THE USE OF THIS MATERIAL. THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. SECTION 13 ADDITIONAL REGULATORY STATUS INFORMATION TOXIC SUBSTANCES CONTROL ACT: This substance is listed on the Toxic Substances Control Act inventory. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT TITLE 3: HAZARD CATEGORIES, PER 40 CFR 370.2: HEALTH: Immediate (Acute) PHYSICAL: None EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW, PER 40 CFR 355, APP.A: EXTREME HAZARDOUS SUBSTANCE - THRESHOLD PLANNING QUANTITY: None Established SUPPLIER NOTIFICATION REQUIREMENTS, PER 40 CFR 372.45: None Established SECTION 14 ADDITIONAL INFORMATION REGULATED UNDER FIFRA, USDA & FDA MSDS REVISION STATUS: Section 11 revised SECTION 15 MAJOR REFERENCES Additional references are available upon request. PRODUCT NAME: HTA~ TEST STRIPS 91906 HTH~ Pop Up Pool Start Up & Maintenance Kit SECTION 1 PRODUCT AND COMPANY IDENTIFICATION REVISION DATE: 12-02-2002 SUPERCEDES:05-24-2001 MSDS No : 02142-0001 - 30651 MANUFACTURER: Arch ChemiC81S, Inc. 501 Merritt 7 PO Box 5204 Norwalk, CT 06856-5204 SYNONYMS: None CHEMICAL FAMILY: Not Applicable FORMULA: Not Applicable/Mixture USE DESCRIPTION: Test Strips OSHA HAZARD CLASSIFICATION: This product is not considered to be hazardous under 29 CFR 1910.1200. SECTION 2 COMPONENT DATA PRODUCT COMPOSITION This product is considered to be an article under OSHA 29 CFR 1910.1200. SECTION 3 PRECAUTIONS FOR SAFE HANDLING AND STORAGE DO NOT TAKE INTERNALLY. STORAGE CONDITIONS: NO SPECIAL STORAGE REQUIREMENTS ARE NECESSARY. PRODUCT STABILITY AND COMPATIBILITY SHELF LIFE LIMITATIONS: No Data INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT: Strong oxidizers SECTION 4 PHYSICAL DATA APPEARANCE: Test strips FREEZING POINT: Not Applicable BOILING POINT: Not Applicable DECOMPOSITION TEMPERATURE: Not Applicable SPECIFIC GRAVITY: No Data BULK DENSITY: No Data pH @ 25 DEG.C: Not Applicable VAPOR PRESSURE @ 25 DEG.C: Not Applicable SOLUBILITY IN WATER: Insoluble VOLATILES, PERCENT BY VOLUME: Not Applicable EVAPORATION RATE: Not Applicable VAPOR DENSITY: Not Applicable MOLECULAR WEIGHT: Not Applicable ODOR: None COEFFICIENT OF OIL/WATER DISTRIBUTION: Not Applicable SECTION 5 PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS Not Applicable - Product is an article. SECTION 6 FIRE AND EXPLOSION HAZARD INFORMATION c FLAMMABILITY DATA: 91906 HTH° Pop Up Pool Start Up & Maintenance Kit EXPLOSIVE: No FLAMMABLE: No COMBUSTIBLE: Not Applicable PYROPHORIC: No FLASH POINT: Not Applicable AUTOIGNITION TEMPERATURE: No Data FLAMMABLE LIMITS AT NORMAL ATMOSPHERIC TEMPERATURE AND PRESSURE (PERCENT VOLUME IN AIR) LEL - Not Applicable UEL - Not Applicable EXTINGUISHING MEDIA: Carbon dioxide, Dry chemical, Water spray FIRE FIGHTING TECHNIQUES AND COMMENTS: No special instructions, same as for wood or paper. Use water to cool containers exposed to fire. SECTION 7 REACTIVITY INFORMATION CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE: TEMPERATURES ABOVE: No Data MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE: No HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBLE MATERIALS: Strong oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide, smoke SECTION 8 FIRST AID EYES: SKIN: Product is an article. - Not an eye irritant. Product is an article. - Not a skin irritant. Washing any substance off the skin with water is a good safety practice. INGESTION: Product is an article. - Not a likely route of exposure. INHALATION: Product is an article. - Not a likely route of exposure. SECTION 9 TOXICOLOGY AND HEALTH INFORMATION ROUTES OF ABSORPTION This product is an article and would not be expected to exert a significant adverse effect to health from any route of exposure. WARNING STATEMENTS AND WARNING PROPERTIES DO NOT TAKE INTERNALLY. SECTION 10 TRANSPORTATION INFORMATION THIS MATERIAL IS NOT REGULATED AS A DOT HAZARDOUS MATERIAL. e SECTION 11 SPILL AND LEAKAGE PROCEDURES If the product is spilled, dispose of as normal household waste. 91906 d HTH° Pop Up Pool Start Up & Maintenance Kit SECTION 12 WASTE DISPOSAL Not Applicable - Product is an article. SECTION 13 ADDITIONAL REGULATORY STATUS INFORMATION TOXIC SUBSTANCES CONTROL ACT: Product is an article. SECTION 14 ADDITIONAL INFORMATION Manufactured by: Environmental Test Systems, Inc MSDS REVISION STATUS: First Issue SECTION 15 MAJOR REFERENCES Joe Sweazy Technical Services, Environmental Test Systems, Inc., P.O. Box 4659, 23575 County Road 106, Elkhart, IN 46514 Phone (219) 262-2060 (Letter to Mr. Len Gober, Arch Chemicals, .Inc.) PRODUCT NAME: HTH® RELIABLE CLEANING GRANULES CHLORINATOR SBCTION 1 PRODIICT AND COMPANY IDENTIFICATION REVISION DATE: 03-04-2004 SUPERCEDES:02-18-2004 MSDS N0: 02410-0002 - 21110 Manufacturer: Arch Chemicals, Inc. 501 Merritt 7 PO Box 5204 Norwalk, CT 06856-5204 SYNONYMS: None CHEMICAL FAMILY: Hypochlorite Mixture FORMULA: Not Applicable/Mixture DESCRIPTION: Sanitizer and Oxidizer OSHA HAZARD CLASSIFICATION: Toxic by inhalation, corrosive to eyes and skin, skin and eye hazard, lung toxin SECTION 2 COMPONENT DATA PRODUCT COMPOSITION CAS or CHEMICAL NAME: Calcium hypochlorite CAS NUMBER: 7778-54-3 PERCENTAGE RANGE: 40-55% HAZARDOUS PER 29 CF12 1910.1200: Yes EXPOSURE STANDARDS: 1 mg/cubic meter (15 min. STEL - TWA) Arch chemicals Internal Exposure Standard CAS or CHEMICAL NAME: Sodium chloride CAS NUMBER: 7647-14-5 PERCENTAGE RANGE: 5-15~ P HAZARDOUS PER 29 CFR 1910.1200: No EXPOSURE STANDARDS: None Established CAS or CHEMICAL-NAME: Calcium chlorate 91906 HTH~ Pop Up Pool Start Up & Maintenance Kit CAS NUMBER: 10137-74-3 PERCENTAGE RANGE: 0-4$ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Calcium chloride CAS NUMBER: 10043-52-4 PERCENTAGE RANGE: O-4$ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Calcium hydroxide CAS NUMBER: 1305-62-0 PERCENTAGE RANGE: 0-5$ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: OSHA(PEL) ppm mg/cubic-meter TWA: None CEILING: None STEL: None ACGIH (TLV) ppm mg/cubic-meter 5 None None CAS or CHEMICAL NAME: Calcium carbonate CAS NUMBER: 471-34-1 PERCENTAGE RANGE: 0-4$ HAZARDOUS PER 29 CFR 1910.1200: Yes EXPOSURE STANDARDS: OSHA(PEL) ppm mg/cubic-meter TWA: 15 (Total dust) 5 (Respirable fraction) CEILING: None STEL: None ACGIH (TLV) ppm mg/cubic-meter 10 None None CAS or CHEMICAL NAME: Magnesium sulfate heptahydrate CAS NUMBER: 10034-99-8 (anhydrous 7487_-88-9) PERCENTAGE RANGE: 25-35$ HAZARDOUS PER 29 CFR 1910.1200:.Yes EXPOSURE STANDARDS: None Established CAS or CHEMICAL NAME: Water CAS NUMBER: 7732-18-5 PERCENTAGE RANGE: 17-22$ HAZARDOUS PER 29 CFR 1910.1200: No EXPOSURE STANDARDS: None Established SECTION 3 PRECAUTIONS FOR SAFE HANDLING AND STORAGE DO NOT TAKE INTERNALLY. AVOID INHALATION OF DUST AND FUMES. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. UPON CONTACT WITH SKIN OR EYES, WASH OFF WITH WATER. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. STORAGE CONDITIONS: Keep product tightly sealed in original containers. Store product in a cool, dry, well-ventilated area. Store away from combustible or flammable products. Keep product packaging clean and free of all contamination, including, e.g., other .pool treatment products, acids, organic materials, nitrogen-containing compounds, dry 91906 HTH° Pop Up Pool Start Up & Maintenance Kit (•` powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. DO NOT STORE AT TEMPERATURES ABOVE: 52 Deg.C (125 Deg.F) In the event that the calcium hypochlorite were to separate from the blend, storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Also, the magnesium sulfate heptahydrate will begin to loose water of crystallization at approximately 150 Deg.C (302 Deg.F) Should all the water of crystallization be lost, the likelihood of rapid decomposition occurring, as above, would be increased. PRODUCT STABILITY AND COMPATIBILITY SHELF LIFE LIMITATIONS: Shelf life (that is, the period of time before the product goes below stated label strength) is determined by storage time and temperatures. Do not store product at temperatures above 52 Deg.C (125 Deg.F) When stored under moderate temperature conditions, product will maintain stated label strength for approximately two years. Prolonged storage at 35 Deg.C (95 Deg.F) or above will significantly shorten the shelf life. Storage in a climate-controlled storage area or building is recommended in those areas where extremes of high temperature occur. INCOMPATIBLE MATERIALS FOR PACKAGING: Product packaging must be clean and free of contamination by other materials, including, e.g., other pool treatment products, acids, organic materials, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. INCOMPATIBLE MATERIALS FOR STORAGE OR TRANSPORT: Do not allow product to come in contact with other materials, including, e.g., other pool .treatment products, acids, organic materials, nitrogen-containing compounds, dry. powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. SECTION 4 PHYSICAL DATA APPEARANCE: White granules FREEZING POINT: Not Applicable BOILING POINT: Not Applicable DECOMPOSITION TEMPERATURE: Onset - Approx. 170-180 Deg.C (338-356 Deg.F) SPECIFIC GRAVITY: Not Applicable BULK DENSITY: 0.8 g/cc, loose pH @ 25 DEG.C: 10.0-10.8 (1% soln.) SOLUBILITY IN WATER: Approximately 18$ @ 25 Deg.C. (Product contains calcium hydroxide and calcium carbonate which will leave a residue.) VAPOR PRESSURE @ 25 DEG.C: Not Applicable VOLATILES, PERCENT BY VOLUME: Not Applicable EVAPORATION RATE: Not Applicable VAPOR DENSITY: Not Applicable MOLECULAR WEIGHT: 143 (Active ingredient) ODOR: Chlorine-like COEFFICIENT OF OIL/WATER DISTRIBUTION: Not Applicable SECTION 5 PERSONAL PROTECTIVE EQUIPMENT REQUIREMENTS `~ 91906 HTH° Pop Up Pool Start Up & Maintenance Kit PERSONAL PROTECTION FOR ROUTINE USE OF PRODUCT: RESPIRATORY PROTECTION: Wear a NIOSH approved respirator if dusts are created. VENTILATION: Use local exhaust ventilation to minimize dust and chlorine level where industrial use occurs. Otherwise, ensure good general ventilation.. SKIN AND EYE PROTECTIVE EQUIPMENT: Wear gloves and safety glasses to avoid skin and eye contact. Where industrial use occurs, chemical goggles or full impermeable suit may be required. EQUIPMENT SPECIFICATIONS (WHEN APPLICABLE): RESPIRATOR TYPE: NIOSH approved full face piece air-purifying respirator with chlorine cartridges and dust/mist prefilter_ Air purifying respirators should not be used in oxygen ' deficient or IDLH atmospheres or in exposure levels which exceed lOX the PEL. PROTECTIVE CLOTHING TYPE: Neoprene, Nitrile, Natural rubber (This includes: gloves, boots, apron protective suit) SECTION 6 FIRE AND EXPLOSION HAZARD INFORMATION This product contains an ingredient which is both a strong oxidizer and is chemically reactive with many substances. Strong oxidizers are capable of intensifying a fire once started. Because of this, any contamination of the product with other substances by spill or otherwise should be avoided. Also see section 3 FLAMMABILITY DATA: FLAMMABLE: No COMBUSTIBLE: No PYROPHORIC: No FLASH POINT: Not Applicable AUTOIGNITION TEMPERATURE: Not Applicable FLAMMABLE LIMITS AT NORMAL ATMOSPHERIC TEMPERATURE AND PRESSURE (PERCENT VOLUME IN AIR) UEL - Not Applicable LEL - Not Applicable NFPA RATINGS: NFPA Oxidizer Class: Meets the criteria of an NFPA Class 1 Oxidizer HMIS RATINGS: Health: 3 Flammability: 0 Reactivity: 1 EXTINGUISHING MEDIA: Water only FIRE FIGHTING TECHNIQUES AND COMMENTS: Use water to cool containers exposed to fire. Also see Section 11. OTHER: Do not use dry extinguishers containing ammonium compounds SECTION 7 REACTIVITY INFORMATION e CONDITIONS UNDER WHICH THIS PRODUCT MAY BE UNSTABLE: TEMPERATURES ABOVE: 170 Deg.C (338 Deg.F} 91906 HTH° Pop Up Pool Start Up & Maintenance Kit MECHANICAL SHOCK OR IMPACT: No ELECTRICAL (STATIC) DISCHARGE: No HAZARDOUS POLYMERIZATION: Will not occur INCOMPATIBLE MATERIALS: This product is chemically reactive with many substances, including, e.g:, other pool treatment products, acids, organics, nitrogen-containing compounds, dry powder fire extinguishers (containing mono-ammonium phosphate), oxidizers, corrosive, flammable or combustible materials. HAZARDOUS DECOMPOSITION PRODUCTS: .Chlorine-gas OTHER CONDITIONS TO AVOID: Storage at temperatures >125 Deg.F (52 Deg.C) Prevent ingress of humidity and moisture into container or package. Always close the lid. SUMMARY OF REACTIVITY: (See also Section 6) OXIDIZER: No (Contains an oxidizer - calcium hypochlorite) PYROPHORIC: No ORGANIC PEROXIDE: No WATER REACTIVE: No OTHER: Arch calcium hypochlorite products meet the specifications of ASTM method E-487-74 as set forth in 49 C. F. R. Sec. 173.21, Title 49-Code of Federal Regs. (DOT Regs.) SECTION 8 FIRST AID EYES: Immediately flush with large amounts of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Call a physician at once. SKIN: Immediately flush with water for at least 15 minutes. Call a physician. If clothing comes in contact with the product, the clothing should be removed immediately and should be laundered before re-use. INGESTION: Immediately drink large quantities of water. DO NOT induce vomiting. Call a physician at once. DO NOT give anything by mouth if the person is unconscious or if having convulsions. INHALATION: Remove victim to fresh air. Support respiration if needed. Call a physician. SECTION 9 TOXICOLOGY AND HEALTH INFORMATION ROUTES OF ABSORPTION Inhalation, skin and eye contact, ingestion WARNING STATEMENT AND WARNING PROPERTIES MODERATELY TOXIC IF SWALLOWED. AVOID BREATHING DUST OR FUMES. HARMFUL IF PRODUCT IS INHALED IN HIGH CONCENTRATIONS. CAUSES EYE, DIGESTIVE TRACT AND RESPIRATORY TRACT BURNS. DRY MATERIAL CAUSES MODERATE SKIN IRRITATION. WET MATERIAL CAUSES SKIN BURNS HUMAN RESPONSE DATA ODOR THRESHOLD: Approximately 2.0 mg/cubic-meter, based on odor threshold of chlorine. e IRRITATION THRESHOLD: Approximately 18-31 mg/cubic meter, based on the irritation threshold of chlorine. IMMEDIATELY DANGEROUS TO LIFE OR HEALTH: Approximately 63 91906 HTH° Pop Up Pool Start Up & Maintenance Kit mg/cubic-meter, based on IDLH concentration of chlorine. SIGNS, SYMPTOMS, AND EFFECTS OF EXPOSURE INHALATION ACUTE: Inhalation of dust or vapor from this product can be irritating to the nose, mouth, throat and lungs. In confined areas, mechanical agitation can result in high levels of dust, and reaction with incompatible materials (as listed in Section.VlI) can result in high concentrations of chlorine vapor, either of which may result in burns to the respiratory tract, producing lung edema, shortness of breath, wheezing, choking, chest pains, impairment of lung function and possible permanent lung damage. CHRONIC: Chronic (repeated) inhalation exposure may cause impairment of lung function and permanent lung damage. EYE Severe irritation andjor burns can occur following eye exposure. Contact may cause impairment of vision and corneal damage. SKIN ACUTE: Dermal exposure to dry material causes moderate skin irritation characterized by redness and swelling. Dermal exposure to wet material can cause severe irritation and/or burns characterized by redness, swelling and scab formation. Prolonged skin exposure may cause permanent damage. CHRONIC: Effects from chronic skin exposure would be similar to those from single exposure. In addition, chronic exposure to wet material may cause effects secondary to tissue destruction. INGESTION ACUTE: Irritation and/or burns can occur to the entire gastrointestinal tract, including the stomach and intestines, characterized by nausea, vomiting, diarrhea, abdominal pain, bleeding and/or tissue ulceration. Significant exposure to this material-can lead to serious health effects and/or death. CHRONIC: There are no known or reported effects from chronic exposure except for effects similar to those experienced from single exposure. The acute corrosivity of this product makes chronic ingestion of significant amounts unlikely MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE Asthma, respiratory and cardiovascular disease INTERACTIONS WITH OTHER CHEMICALS WHICH ENHANCE TOXICITY None known or reported ANIMAL TOXICOLOGY ACUTE TOXICITY: P. Inhalation LC 50: >2.04 mg/1 (lhr., rat); > 0.51 mg/1 (4 hr., rat) - extrapolated from inhalation toxicity studies-using calcium hypochlorite Oral LD 50: Approximately 1200 mg/kg. (rat) based on extrapolation from oral toxicity studies using calcium hypochlorite 91906 HTH° Pop Up Pool Start Up & Maintenance Kit Dermal LD 50: > 2 g/kg. (rabbit) Irritation: Causes burns to eyes. Dry material causes skin irritation, wet material causes skin burns. ACUTE TARGET ORGAN TOXICITY: This product is corrosive to the eyes and upon inhalation may cause irritation to mucous membranes and respiratory tract. The dry material is irritating to the skin. However when wet, it will produce ,burns to the skin CHRONIC TOXICITY: There are no known or reported effects from repeated exposure except those secondary to burns. REPRODUCTIVE TOXICITY: Calcium hypochlorite has been tested for teratogenicity in laboratory animals. Results of this study have shown that calcium hypochlorite is not a teratogen. CARCINOGENICITY: This product is not known or reported to be carcinogenic by any reference source, including: IARC, OSHA, NTP or EPA,. One hundred mice were exposed dermally 3 times a week for 18 months to a solution of calcium hypochlorite. Histopathological examination fai-led to show an increased incidence of tumors. IARC (International Agency for Research on Cancer) reviewed studies conducted with several hypochlorite salts. IARC has classified hypochlorite salts as having inadequate evidence for carcinogenicity to humans and animals. IARC therefore considers hypochlorite salts to be not classifiable as to their carcinogenicity to humans. (Group 3 substance). MUTAGENICITY: Calcium hypochlorite has been tested in the dominant lethal assay in male mice, and it did not induce a dominant lethal response. Calcium hypochlorite has been reported to produce mutagenic activity in two in vitro assays. It has, however, been shown to lack the capability to produce mutations in animals based on results from the micronucleus assay. In vitro assays frequently are inappropriate to judge the mutagenic .potential of bactericidal chemicals due to a high degree of cellular toxicity. The concentration which produces mutations in these in vitro assays is significantly greater than the concentrations used for disinfection. Based on high cellular toxicity in in vitro assays and the lack of mutagenicity in animals, the risk of genetic damage to humans is judged not significant. AQUATIC TOXICITY: Bluegill, 96 hr. LC50: Approximately 0.12 mg/1 (nominal, static) based on extrapolation from studies using calcium hypochlorite Rainbow trout, 96 hr. LC50: 0.22 mg/1 (nominal, static) based on extrapolation from studies using calcium hypochlorite Daphnia magna, 48 hr. LC50: 0.15 mg/1 (nominal, static) based on extrapolation from studies using calcium hypochlorite TOXICITY TO WILDLIFE: Bobwhite quail, dietary LC50: > 7;000 ppm based on extrapolation-from studies using calcium hypochlorite Mallard ducklings, dietary LC50: > 7,000 ppm based on 91906 HTH~ Pop Up Pool Start Up & Maintenance Kit extrapolation from studies using calcium hypochlorite Bobwhite quail, oral LD50: Approximately 4800 mg/kg. based on extrapolation from studies using calcium hypochlorite SECTION 10 TRANSPORTATION INFORMATION THIS MATERIAL IS REGULATED AS A DOT .HAZARDOUS MATERIAL ONLY IF PACKING CONTAINS 10 POUNDS OR GREATER OF CALCIUM HYPOCHLORITE DOT DESCRIPTION FROM THE HAZARDOUS MATERIALS TABLE 49 CFR 172.101: Land (U.S. DOT): PACKING CONTAINS 10 POUNDS OR GREATER OF CALCIUM HYPOCHLORITE: RQ, Other Regulated Substances, Solid, NOS (Calcium Hypochlorite), 9, NA 3077, III U.S. DOT Hazardous Substance (49 CFR 172.101, Appendix A) Yes; RQ = 10 Lbs. Hazard Label/Placards: Class 9 - Miscellaneous Hazardous Materials 2000 Emergency Response Guide# 171 Water (IMDG) Not Regulated Marine Pollutant: Not Listed Air(IATA/ICAO) Not~Regulated 1) Inhalation toxicity data indicates product to be toxic by inhalation, however, diameter of over 90~ of granules well exceed 10 micron limit. Particles cannot be inhaled through lungs. 2)Important: Product not regulated in transport for U.S. ground shipments, if package does not contain 10 Lbs. or greater of calcium hypochlorite. SECTION 11 SPILL AND LEAKAGE PROCEDURES FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC AT 800-424-9300. REPORTABLE QUANTITY: 10 lbs. (as Calcium hypochlorite) Per 40 CFR 302.4 SPILL MITIGATION PROCEDURES: Hazardous concentrations in air may be found in local spill area and immediately downwind. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. AIR RELEASE: Vapors may be suppressed by the use of a water fog. All water utilized to assist in fume suppression, decontamination or fire suppression-may be contaminated and must be contained before disposal and/or treatment. WATER RELEASE: This material is heavier than water. This material is soluble in water. Monitor all exit water for available chlorine and pH. Advise local authorities of any contaminated water release. B LAND SPILL: Contact at 1-800-6546-911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical 91906 HTH® Pop Up Pool Start Up & Maintenance Kit reaction which may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material. Using a clean broom or shovel, place all spilled product into plastic bags, and place those bags into a clean, dry disposal container, properly marked and labeled. Disposal containers made of plastic or metal are recommended. Do not seal disposal containers tightly. Immediately remove all product in disposal containers to an isolated area outdoors. Place all damaged packaging material in a disposal container of water to assure decontamination (i..e. removal of all product) before disposal. Place all undamaged packaging in a clean, dry container properly marked and labeled. Call for disposal procedures. SPILL RESIDUES: Dispose of per guidelines under Section 12, WASTE DISPOSAL. , This material may be neutralized for disposal; you are requested to contact ACEAN at 800-6546-911 before beginning any such operation. PERSONAL PROTECTION FOR EMERGENCY SPILL AND FIRE-FIGHTING SITUATIONS: Response to a large quantity spill (100 pounds or greater) or when dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air respirator or self contained breathing apparatus (SCBA), chemical resistant gloves, coveralls and boots. In case of fire, this personal protective equipment should be used in addition to normal fire fighter equipment. SECTION 12 WASTE DISPOSAL If this product becomes a waste, it DOES NOT meet the criteria of a hazardous waste as defined under 40 CFR 261, in that it does not exhibit the characteristics of hazardous waste of Subpart C, nor is it listed as a hazardous waste under Subpart D. As a nonhazardous waste, it should be disposed of in accordance with local, state and federal regulations. CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINAT ION FROM THE USE OF THIS MATERIAL. THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. SECTION 13 ADDITIONAL REGULATORY STATUS INFORMATION TOXIC SUBSTANCES CONTROL ACT: This substance is listed on the Toxic Substances Control Act inventory. SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT TITLE 3: HAZARD CATEGORIES, PER 40 CFR 370.2: HEALTH: Immediate (Acute) ~ PHYSICAL: None 91906 HTH° Pop Up Pool Start Up & Maintenance Kit EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW, PER 40 CFR 355, APP.A: EXTREME HAZARDOUS SUBSTANCE - THRESHOLD PLANNING QUANTITY: None Established SUPPLIER NOTIFICATION REQUIREMENTS, PER 40 CFR 372.45: Nome Established SECTION 14 ADDITIONAL INFORMATION REGULATED UNDER FIFRA, USDA & FDA' MSDS REVISION STATUS: Section it revised SECTION 15 MAJOR REFERENCES Additional references are available upon request. THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION INTHIS MSDS SHOULD BE PROVIDEDTO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT TI' IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT. Arch Chemicals, Inc. MSDS Control 501 Merritt 7 PO Box 5204 Norwalk, CT 06856-5204 B 91906 HTH° Pop Up Pool Start Up & Maintenance Kit Page 1 of 5 . Hazardous Materials Inventory Statement PART A -Declaration Business Name: Sport Chalet Phone: Fax: E-mail _ Street Address: . City:. . _ State: CA Postal Code: _County: County:. Country: USA Technical Contact:. Title: Facilities Manager Phone: 818-949-~ E-mail: Emergency (24hr) Contact(s) Name: (Title:) E-mail: 24hour Phone Number Principal Contact Titte: Phone: E-mail: Property Owner: Title: Phone: E-mail: Principal Business Activity: Sporting Goods Retail Sales Fire Hazard: 3 - 4 - 0 - No Water Latitude: Longitude: Number of Employees: Number of Shifts: 0 Hours of Operation: SIC Code: Other ID Numbers _ EPA ID #: D&B #: I certify that the information above and on the following parts is true and correct to the best of my knowledge Signature: Date: Print Name: Date: (Must be signed b owner/operator or designated representative) PART B -Hazardous Materials Inven ory Statement file://C:\DOCUME~1\rking\LOCALS~1\Temp\TKSZ6W7E.htm 10/10/2006 Spectrum Hazardous Maternal Identification Division of United Industries Corp. Isystem-(HMIl9) P.O. Box 142642 St. LOUIS,.MO 63114-0642 HEALTH - 1 REACTIVITY 0 Material. Safety Data Sheet FLAMMABILITY - 3 PERSONAL -None Complies with OSHA's Hazard Communication Standard, 29 CFR 1910.1200 I Trade Names Unscented Cutter Outdoorsman Insect Repellent n nsec epe en eroso n m nm r. orm a nm r: - EPA Registration Number Mannfaelurer Emergency Telephone No. ChemSICO For Chemical Emergency: 1-800-633-2873 121-66 8494 Chapin Industrial Dr. For Information: 1-800-332-5553 St. Louis, MO 63114 Prepared by: H.L. Pauls Date Prepared: October 4, 1994 II Hazardous Ingredients/Identity Information III Physical and Chemical Characteristics Chemical % OSHA PEL ACGIH TLV Appearance and Odor: Clear, colorless or pale yellow liquid with N,N-diethyl-m- 28.5 NA NA ethanollic odor. 7oluamide (DEFT) Boiling Point: 75°C CAS # 134-62-3 Vapor Pressure: 43mm @ 20°C SDA-40 Ethanol 20 NA 1000 ppm Specific Gravity: 0.885 @ 72°F (Hz0=1) CAS #64-17-5 Vapor Density: 1.6 Isobutane 10 NE NE % Volatile (by vol.): 30 CAS #75-28-5 Solubility in Water: Not known Evaporation Rate: Approx. 1 (Bu0Ac=1) IV Fire and Explosion Hazard Data V ,Reactivity Dats Flash Point: 55°F (TCC) Stability: Stable Flame Extension: 18" (Level 2 Aerosol) Polymerization: Will not occur Flammable Limits: Lower: 3.3% Upper: 19.0% Conditions to Avoid: None Autoignition Temp.: 793°F Incompatible Materials: May soften or damage some Fire Extinguishing Media: COz,-Foam, or Dry Chemical synthetics such as rayon. May Decomposition Temp.: N/A damage leather. Special Fire-Fighting Procedures: For small fires: Use COz or dry Hazardous Decomposition chemical extinguisher. For large fires: Use copious amounts or Byproducts: None of water. Unusual fire and Explosion Hazards: See secfion VII VI Health Hazard Dsta VII Precautions for ISafe Handling and Use Ingestion (Swallowing): Harmful if swallowed. First Aid: Consult a Steps to be Taken in Case Material is Released or Spilled: physician or poison control. Flammable material. Remove all possible ignition sources. Wipe Eye Contact: May cause eye injury. First Aid: Immediately flush up with absorbent material. Wash small quantities away with eyes with plenty of water. Get medical attention. soapy water. Prevent bulk quantities from entering open sewers Skin Contact: If skin reaction occurs, wash with soap and water. and waterways. Get medical "attention if irritation persists. Waste Disposal: Inhalation Toxicity: Avoid breathing spray mist or using in This material is flammable and must be disposed of in enclosed places. First Aid: Remove to fresh air. accordance with Local, State and Federal regulations. Do not Special Notes: Apply only to skin or clothing, do not ingest. Keep puncture or incinerate empty container; dispose of properly. out of eyes. Frequent reapplication or saturation is Handling ~ Storage Precautions: unnecessary. Keep away from heat, sparks or open flame. Do not expose Health Conditions Aggravated by Exposure: None Known treated skin to fire sparks or flame until liquid has dried. Ingredients listed by NTP, OSHA or IARC as Carcinogens or potential carcinogens: None VIII Control Measures IX Transportation Data Read and follow label directions. They are your best guide to DOT Shipping Name -Consumer Commodity using this product effectively, and give necessary safety DOT Hazard Class - ORM-D ' precautions to protect your health. The information dud statements herein are believed to be reliable but are not to be construed as warranty or representation forwhich we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. MSDS Number: C0418 Effective Date: 09/20/97 MSDS MATERIAL SAFETY DATA SHEET CHEMTREC: 800-424-9300 (USA) 202-483-7616 From: Mallinckrodt Baker, Inc. (Outside USA & CANADA) 222 Red School Lane CANUTEC: 613-996-6666 Phillipsburg, NJ 08865 NOTE: Use CHEMTREC and CANUTEC Emergency Telephone Number: 908-859-2151 phone numbers only in the event of a chemical emergency. All non-emergency questions should be directed to Customer Service (1-800-582-2537) for assistance. J.T.BAKER Calcium Hypochlorite 1. Product Identification Synonyms: Hypochlorous Acid, Calcium Salt; Losantin; Calcium Hypochloride; Chlorinated lime CAS No: 7778-54-3 Molecular Weight: 142.98 Chemical Formula: CaC1202 Product Codes: 1378 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous Calcium Hypochlorite 7778-54-3 100% Yes 3. Hazards Identification Emergency Overview DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED. WATER REACTIVE. J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your convenience) Health Rating: 2 -Moderate Flammability Rating: 0 -None Reactivity Rating: 3 -Severe (Oxidizer) Contact Rating: 2 -Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Yellow (Reactive) Potential Health Effects Inhalation: Corrosive. Extremely destructive to tissues of the mucous membranes and upper respiratory tract. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting. Inhalation may be fatal as a result of spasm inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema. Ingestion: Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach. Can cause sore throat, vomiting, diarrhea. Skin Contact: Corrosive. Symptoms of redness, pain, and severe burn can occur. Eye Contact: Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns. Chronic Exposure: Repeated exposures to calcium hypochlorite may cause bronchitis to develop with cough and/or shortness of breath. Aggravation of Pre-existing Conditions: No information found. 4. First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. ' Ingestion: If swallowed, D.O NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Thermally . unstable; at higher temperatures, may undergo accelerated decomposition with release of heat and oxygen. Explosion: Sealed containers may rupture when heated. An explosion can occur if either a carbon tetrachloride or a dry ammonium compound fire extinguisher is used to extinguish a fire involving calcium hypochlorite. Sensitive to mechanical impact. Fire Extinguishing Media: Use flooding quantities of water as fog or spray. Use water spray to keep fire-exposed containers cool. Avoid direct contact with water; reacts with water releasing chlorine gas. Fight fire from protected location or maximum possible distance. Do not use dry chemical fire extinguishers containing ammonium compounds. Do not use carbon tetrachloride fire extinguishers. Do not allow water runoff to enter sewers or waterways. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Remove all sources of ignition. Keep water away from spilled material. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Pick up spill for recovery or disposal and place in a closed container. Do not seal tightly. 7. Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area: Protect against physical damage and moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, "Industrial Ventilation, A Manual of Recommended Practices", most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to the dust or mist is apparent, a half-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use afull-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Eye Protection: Use chemical safety goggles and/or a full face shield where splashing. is possible. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Boiling Point: White or grayish-white powder. No information found. Odor: Melting Point: Chlorine-like odor. Decomposes above 177C (350F), releasing oxygen. Solubility: Vapor Density (Air=1): Soluble in water; reacts, 6.9 releasing chlorine gas. Specific Gravity: Vapor Pressure (mm Hg): 2.35 @ 20C Not applicable. pH: Evaporation Rate (BuAc=1): No information found. No information found. Volatiles by volume @ 21C (70F): 0 10. Stability and Reactivity Stability: Rapidly decomposes on expsure to air. May decompose violently if exposed to heat or direct sunlight. Thermally unstable; decomposes at 177C (350F). Hazardous Decomposition Products: Calcium hypochlorite gives off oxygen, chlorine and chlorine monoxide. Hazardous Polymerization: Will not occur. Incompatibilities: Calcium hypochlorite is a strong oxidizer. Reacts with water and acids giving off chlorine gas. Forms explosive compounds with ammonia and amines. Incompatable with organic materials, nitrogen compounds and combustible materials. Conditions to Avoid: Heat, flame, moisture, dusting, sources of ignition and shock, and incompatibles. 11. Toxicological Information Calcium hypochlorite: LD50 oral rat 850 mgfkg. Investigated as a tumorigen and mutagen. Cancer Lists NTP Carcinogen Ingredient Known Anticipated IARC Category Calcium Hypochlorite (7778-54-3) No No 3 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Domestic (Land, D.O.T.) Proper Shipping Name: CALCIUM HYPOCHLORITE, DRY Hazard Class: 5.1 UN/NA: UN1748 Packing Group: II Information reported for product/size: 2.SKG International (Water, I.M.O.) Proper Shipping Name: CALCIUM HYPOCHLORITE, DRY Hazard Class: 5.1 UN/NA: UN1748 Packing Group: II Information reported for product/size: 2.SKG International (Air, I.C.A.O.) Proper Shipping Name: CALCIUM HYPOCHLORITE, DRY Hazard Class: 5.1 UN/NA: UN2208 Packing Group: III Information reported for product/size: 2.SKG 15. Regulatory Information Chemical Inventory Status -Part 1 Ingredient TSCA EC Japan Australia Calcium Hypochlorite (7778-54-3) Yes Yes Yes Yes Chemical Inventory Status -Part 2 Canada Ingredient Korea DSL NDSL Phil. Calcium Hypochlorite (7778-54-3) Yes Yes No Yes Federal, State & International Regulations -Part 1 -SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg. Calcium Hypochlorite (7778-54-3) No No No No Federal, State & International Regulations -Part 2 -RCRA- -TSCA- Ingredient CERCLA 261.33 8(d) Calcium Hypochlorite (7778-54-3) 10 No No Chemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312:. Acute: Yes Chronic: Yes Fire: Yes Pressure: No Reactivity: Yes (Pure /Solid) Australian Hazchem Code: 2PE Poison Schedule: SS WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. P 16. Other Information NFPA Ratings: Health: 3 Flammability: O Reactivity: l Other: Oxidizer Label Hazard Warning: DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED. WATER REACTIVE. Label Precautions: Keep from contact with clothing and other combustible materials. Store in a tightly closed container. Remove and wash contaminated clothing promptly. Do not store near combustible materials. Do not get in eyes, on skin, or on clothing. Do not breathe dust or vapor. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Do not contact with water. Label First Aid: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air: If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases get medical attention immediately. Product Use: Laboratory Reagent. Revision Information: MSDS Section(s) changed since last revision of document include: 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 14, 15, 16. Disclaimer: Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy: This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. Prepared by: Strategic Services Division Phone Number: (314) 539-1600 (U.S.A.) C0418 ~'"ia~ ~ ~~ {~~3~} Its ?i the Ctair~t t~` LB.S: ~ t1 ~aEy eri . ~i~ P+st ' ' tip ~fr~ ~~~-~~~ ~~'R i~C3;'I?~. ~u#sttt tJ'.S: ~ matte ~ i~rf~on y~~~~s,. Ft~isc t~ &~ t~3 dt ttei~ ~ocuf~~tkt Tian' ~c~ts ~t~esr end ~~tisr~sk; F'Rt?1'~tl~'i': ~~ ~~. S'1"~e€t;3~11(~t+~IS: ~Sti~~tl~#`t~,~8(t@ RAixtul~ ~"F~t'~bt~~T' ~' lE: ~'ti ~C~fl14~1Y: ~t~CpW P'EB~C ~J~A, Inc. AE~~F~: 4~7~4 t~ver~ 1~~~ eke C~~r~. ~ .87Q3~ ~~3St~+i~~ PEE (a~3) '7`~-~3 ~Ni~E~~f PN~Rt~ ~'. ~Stti 5~~ag53 ~~~ r w rtc+r~a~ ~~ nv ~,. r~ ~. aa~~~~ ~ 3 tt~ ~? ' two ~ ~o t~~ ~ ~ ~xa ; ~ ~=a~. ~~ t~~t3 ~t3~~il~F~~#~~C3!' ~I~t4?YQ~f~RVlf- W 4 ~ F~~C~1t ~+G1~P'T~t)1~: tatiess, liq~"i~s# ~ ~rt"sxtasre with ~ t~i~ hytir~ac~rtauri t~dor. i ~#~1~T~ ~k~: ~3t~~: ca~eester pr~:s~°t'tt~ rf'rn~~1ir~'1~ hem haza~rK~: T~t~ nrt~t~ is. a~ tttia~ ~ 1~~~ i ~~sc~~. FIRS i~lf+~©S. ~1T1m i~ ~ebChine: IiI~CTfi~l~Y ~~15; its ~ ~~~ r3~Cit~Pta_ ~ ~iY~Ra #;. t~,t~?".:~4FlE ~~ t~~at~i tct b~ ~~ ~' ~t ~~ aarrr~n~ 3e~tria! ~ ~get~C a ;. ~'~'ES: t~~ ur~s~l ~ ~' . ~ ~ni~~g~ c~t~~r n~rcn~l r.~ ~f cat l~~r~g. 4n ~ ur~C~ky ~r~ ~h~e ~~: Mitt: g'~Y tir~€ s, t€:ci~~ss ini~t~ ~ s~sr. S~C1t~. l~ ~n~s~i ~kir~ ii~rti~n is ~~i~ ~ac~r ~~~ patio l~' €~r ling. 1~ t~tt~ik~e~ them ~.~. t~r~t~ct Ott plttr ~~~ gas, c~dnt ir~it~ armor air. ~i~;,.~'T"'lt?l~; ~~ inY~~tl~ttic~tt ~ ~ gas role ~ moo, ~arrta~ ~a~Eer ~ ttc~t a~rp~ed tca c~c si~n~ir ~~lth €~f~. Homer, wt alt pct~dtrc~ c~ntatst~g 9~ mi;~~; this pub ~rtrulc# be ~ns#t ih t and tam in tl ~r~s't~il~ ~~riro~~#. t~il~elat~cu~ of large ~~ Gf p 's g~5 {`~ told t ~ ~at~y ra~r,~ ntgtus~e ~ ~Y tad ~zt+rirc~r~~t} trey t~u~t Ott ~~ ~ Sri tliS~~Etc~'t~~tnt a~ad . t~rat rtt3n+c~ras yst~tt~ ~: S~C~. ing~o~ , nt~f ~atfi~p~td tta l ~ ~ri~nt of ~urr~, 11`~~l'1'1flrl~E ~bta~n fc~i ~r ~~~~ t~151" ve~~~< nc. '[Q 1t+~G11%~,AIW: lll.~'~~ a: ~r #~t ~'~~ E ~r~ ~t ~ttp~ ~1#~ra~r a~ tr~bc~:rc a R1~xP"t~l'~SE 'T+~ ~ #~Ctd1=1~'t"~ Rl~>E~ ~~..~ ~~ ~.~~ ~l~i~~ ire S g~a rnt~"t~c3 ~ Ce~r ~i( ~~e~tl~ u~t . areas ~ i~n~ly ~r~R ~p~riaie ~~~ p~-~+nr~ei; ~' nec~~r. ~5d,~~ eu~c~4c_ ~~d ti~ c~u~ x 1~ ~sers~ar~nel. l~e~de~s m w~s~€r '" f rid l~r~ltii~tg '~p~~u~ ~~n rye ~i~s mew ir~dic~ l~s v~~ars t~iv~a ~ c~~ tl ~L {S~e ~+~+o~ 9. l~ys~c~l prc4~~tti~~ 1~ ~tri~y ~rs[~1 ~d ~eri~ti~tf~#t~ ~fi>~. l~ttt~'i tt't ~'td~ca~it~ ~~3s rtf ~tp~r~errts ~t~ ~l a !ice ~~n ~ ~~~~~~'; ~r~d tt'f~a~rm~c~ sit in~di~~s} end ~c~ +~ ~itr~ 1:3°a~+ ~fs~re the r~~r~se ~~ ~r~~~ie~d ~p~~. ~~"~~11~l.. ~1~1~1~ PRC?~tfiJRE~ 1`t1~t Alm R~1.~J4~1q ~1~a,~ X11 t~ cal'' ignl~~ l~s resla. ~.~. ~._ 1.3L113ita 1EGt~ ~13A"~'"!t~>'~[5: ~ trot :spa ~r~ ~f~ ~rpdu~, !~-vz l~fia~l~.ism ~ m~urc. l:~s~ ;in v~rell-»ventll~~~d ~t~a_ rto~ purts~ur+~ cta~ti~tisaet' P. ~STC~t1~E ~~~~~~5 fit prod~tt' ~~" ~ uracaa~tro!l Sfl~lt ~ ~1~11w, ~ ,~ ~~` l€3t3 St3~tE~. ~e r9~', raga ~t~ hbe t~~r# ~ ~ ~~NG," E ~# ~ori~ainer~ Std ~r ecl: ire flhi~ pa~ot~u~ ~~ art ira~rr~a~ik~e €fi~mic~s (~i~ ~iu~n 1~. ~a~"11 ~~ l~r~aif~`~ ~ ~ fi~~`~n ~~a. m~ea~~l ~ end ii~r tra +~ somas. .~ tN~l'~-1. Nit P~t~l~t. _ ,~,...~ _., f ~~~t~~:~l41t~ ~G~~L `~~ ~~~ci ~~~ a~ ris~in^r'ialty l'~a~~t~# Vicar TQ!r~t~~ t ~ttd ~:~ t~'~!a% ~3nt3t~uc~t. E,1~ ~7i~ ~ar~iud i~ x~ri~n#~la~ errvi~ronrat. ~i;~~Ft;~t3i3f' ~'~"~~'t'f~; ~t~ne flab ~n~ar cc~uti~e ~r€ or .sue. S~ t~ri ~sc~d :~rr~:a~etg ~~~a~st~. ~t~ tie win d~r~~g emee~ , t~s i~ rta~ s~ta~,s; orrn s in h~ch ~h~ c~rg~;n l+~vel 't 9~' t~ ~s. ~~t:~:~CT~~~f; ~tan~ tao~ly r~~et~.. 8?~'Y#}yy~~q'~fi~'~~^E "tt~~~tilyr: ~i+~r}~~~I~~ n~sr{m~t~y n~f=/) . ~y.ry /~ry~ ~~I c~te~ s~~ieci; tyre fcEft~€in~ irr"#aacman-is `fit t~ut~ ~e ~a'r~t ca~rt~n~ c~~~~ ~i~~ ~nPxti.~re. C3~ C)I~ P~= ~t3E~T"l1tiiG ~'~fi~°C: Gas ~~~ ~;a~nt, roman NA ~.C1~ ~~CE~..E~ ~~A ~.L-~: ,~:. U~'~, ~`~ LIB' ~:~: ~~ ~t~~ E~~t~SS~.: +45:4 SCi~ GRASf~ (~AT~R = 1 ~: l~A ~~TE~ tl.~Bt~.1TY; 1i~ _~ ~ ,~~er Tim ~Y.~~ ~,A?~:~`1C`~ ' RC> 7~'~A"C'4:iR~'S ~3 Pr~5~RE5-~: Nr~rm~ ~«l~r. ~ii~1: :~~€~li~' 1~CtS1Tf P~RC~~T~. ~# p~trw ~t7t'~'!C'?t+~S T~5 A~tC3i~~ :A.voi~d c~rt~~c~ w~ unr~t€c~ll~ i~itis~3 ~u at~9 i~advt~pa~+~ t~as~s~~_ CA~~#~lt~r~~~"t"Y ~'t"1~E~: T» i~l~_~sbl~ sr~crtma~ ~~~` ~~ir ft~r :~ha .carp~ast~ ~ pst: ~~ .°t t~~: ~1`~~e ~nc+~ ~ s~ ~~# t~ be. yr ~+tecf t,c-`b~; a ~n~s~~~ b~,r tare mot. N~ ~C7 ~~a 1~C+ ~ ~ ~~ a~4~ty ~~. ~~ ~~~~ ~~ ~t~ ~~ ~t~ ~~ }E'FtQ~U~ ~~~G~ t~F~-t~N~AT iuctx is nat'kn~ t~ ~ ~~y atl~a ~~ ~n °~ h ~~~ :sgr~t~. eta rxnn~ar~etrt ~ ~~rt to t~ a mu~g~n; tt~t~e~. ~- r~~r~-dcti~v~ tire.. TG~~!Lflw~~' E'~~-TA; Tt~e fcyti~r~r"~ i~ ~ s~ttrraasy ~~ ~rtn~~~c~#~ dat8 s~a~t~e fc~t '~ ca~rnp~tr~rt~ c~` this ~~~ ~ L~ ~in3g3~~D9t•t~t}; S! pp~t9smirts T~ '(~t8ltslti, ~ 1t~~; ~~; ~.~~ o ~:~ah~or, s;~~~ 141 ~,~ ~ ~~ "~,...... ~s ..c c _ ~ .w , . '1"~3;`~C~~~~:L.Y` S~E~tCx~'t'`~~ ~*a~~ Nang ~.. &~~RE:E i~~ 1#~TJ~"Ctfll~ ~i: rtc~rr~~1y r~it~[t~n~g. ~{Gpy~rllF~p~~Wq yirP~i~~y~/#^ ~~i ~,y~~y~1 ~gy~ryEgA~y~~~,y~~ry ~ivwi~ +~$~ ~i~W {tl77xf~R9irid Vf~$S Y:~iP' -biRA:il ~A01~$iTX1 "~'~$.'Vl'. ~i 1V#`N11~'f i~II~~~jYlLt~ ~~ Rt~~ 'wt/~~+1 ~7.~4Ji,~.. 1t`~'~atic p~;~#~#~~ m# b+~ drret~~d ~t ~. sill. $~E}# ' 1 ~~tt~~t c~art~iirt~: ~`t9~I~"'f ~'C9 TE~~~F.:S~~A~. L~lFE: I1 to `~~ ~rta~lt prtctd vc~#u~'a>~P t~4 uns~6 ~ffedh ~n tsar" #~ ire ar~~idpat~d. i"C~XtCi"" TO A~~A~~ ~.1~~ Dui tt~ #h~ smatt product r~rstu~~, rya un~rsual effects ~ ~~qu~ii~ t~f~* ~ ~~i~Cp~ltt~tl. RtiL3B~tT`Y'~ E~~;iS`l~t+GE,,A~J~ t~EG.Af3~~ ~ gases ~~ dsss~~afe rrm~rd#y to ~ at~sptar~, ~iio~AC~tJtld(U~ATtt~tt 11i? Bi~-?~#CE!`~"RA'Ttt P~3'T~tt7ALs ~ is rtcat stxtici~ ~ ~i~ ~~ud ~a4+11~ b~s~xxrr~trldte tsse aconat~e si~eitrrtty in this erga€norenL '~t`ASTE t,t+1.,.1~ E~,~C~tVIMEI[~}A"E'~~1~5 ~~, ", ~..~~, az~rt ~ii~~ v~ se pad~t~ ~~~ii~g tc +~6 ~,Q{~~~Gt?~!w ~~, ~,'~. ~t£', ~.,~.e'~'..~1~'P.C~it"ti~~id~, k"xT'~~'1~'~1~?~kC•F~ 1~~'i~itB~l~Ii~1'•" 1"#'d~: "~: !.~'IiTi~f ~Llt~ prat `re~uta~ lJ~~i" ~~ i~" ~"~'" t~$'. ftallc~W. ttTe ~~* '~t~4'~dS ~~Sp~~icat~~e tCs ~SCft.lS~~IE}~ 1Az~5~~5~ .~ " ~S3 ~ MIF~PiNG ~t~U TfC~ltiiS. ~r~act- rm~ts~act~€~et ftyr tt~fr€s~an.. N'IARIME P!t7tt;~t.t'~'A~t"~" STATtJ~,; . z~rrnter~t. ~ ~~eted GC3T i~~rine ~'ut~ttt. ~~~ t~P~'3~C"A~Tf' t,t,~~. Ftl,~Ti4NS C~C4 !~` E3~t~Of~~1~ ~'ot ~pptteat~e. ~A~ ~~'C3']`IN+Ca i~ttt~fl'C';:~. '~~ ~ rep~rtin reirom~rtts f~' tie ddst~r~~ecl Sri +~ ~~A "Y"'~le Ctt ~ ~P~te tt~ ~e ~t"t~orte€a~t~ ztf t:~5 uc~. ~:cu: s~~'s~tu'~a SE+c~nc~~N ~~~,.~c~ra ~ tease MCA htt? ~C~ .~ ~~~a rte ~~ a ~A~A ~EC`t"ti~~l 3'3113t2;FC~R PRt~t]t~G't`M F°tre; Ptsr~re. ~~~1~~ SAFE<CN141t~lG iA,'Ft AC's' ~'R+~1~CtS~?~' ~ S'i"A'~US: Nc~ ~mpont of tii ~rcdtix~t is k~ t~ State of Ca(i1'onni~a t~ +r.~cts~ t~rr~~ ~~-r>ter re~rrc~tfut~ive h~rtm~. P t.~J~lt ~liH~fA3S +~i~'tSS~~tC~F'~'1+a-i~: ~ ~rt~p~'~~; E~'! ~~'t~:~ tas rs....~.. w ..r ~. _..... f . ~~ 5asatl~` std h~ ~a~` z~ ~a ~r ga~cl ~ ~ t c~ ?a~ ar;~;r ~' ~:~s Tli!~. ~s ~'axr~~~s ~ 6~ c~ ~~ ~x a~ ~+'a'!~ ` ' an<i sl ire c+~, ttaa~ ~r~ sat+? a~' iee f a~a3 e~rz~:t ~. ~Il~~l"i~~ tom' "~~ ~-BR~~A'T~C3t5 A1.L. SEC1fNbN~; CAA' t3.S. Eeda chi S~t`~y att. ~atth SE~:'TIK~ ~; .: L~ ~'•11,d Kiragclrrra~. ~~afermi Ftepubt'i~ cf ,artica~^art ~ Ga~a~ E4ut#~f. ~e~~~ ~~ u~, Car~°a ~t'~ iie k~fi ~r~de~, ~~ ~ t b~~d.. F~~ ~ Nit Go~bte. ~L~N # .gym' pct 5 t by t Arta ~~m :,~ to utfk~4~t ~ ~ r~+~a~i~I.. ;~ ~tci~rs ~ v~ Caer~d l1~t3~shi~it ?~y~g~t~sEs; ~: T~st~e :,~. ~zruea ~ w~rrk t~~ry3: ,~S'~L; ,..ffiha~ "I"erra~ urn `~t5 csd ~ ,,,,.,..~iin `4fi~er~ ~' ~ttti ~., f IG' :~~"8~$S~ awl .~~` ~Ii'~~Ae ~%. 9.lt7sii '' ~fl ~ ~ ~ - - ... Ise ~ ~ ~ ~@it~Car#1e~+_ '.~';:_ ~ ~ ~ 3iil~tlr ,~,,, ilflffF61 osx~c iEr~. lit~~-}: ~En~st ~ts~FllG~ate r~ ~4iass~ &~~fi~ty ~exf ~4 1't... ~P,dC~tl1'R93i~~9 £ i.A~ I~t,~t. ItlCt~C~~~ - ~~D~~.1~~AYB~ ~~~ ~ _ Cam.. ~~~d.~Bn ~€1,i~L~~jY- ~~~~H. i~4i~l1'~ ask ++.~zi t#sa e~~ ,p#`~a P~ by ~ 1. CsS i-~4 rn<iy ~tsft~ctae t1 ~ ~ duels ~ "E~ d cl~,. br~t~t lls€e ~ ~~ fed le~rele sr~ p~sersi~f t`ot the s3gcltrri~nt~ C ~: ~it~tr ~ tn~ez•:. ~pc`; Mlilo{~csP Cpe[Ilele~ pe~C,`tn Fem. ~"j~: This "sit et c~ ~ tS: yt- t~ ~.~t anra tt~aEt+, herds bcr ata7ie~el t ~tn~ ~f I+ta~o~eai Paid Cad ~a~ri.:f.3 ~ Fka ~~mllk~~l`ISxar~l. 1' li~~. f ~~:~tA~~'-+t~~ Li'3"Y ~,;~,fii' ,~'1`"tC?1+1: t~tF~~4 eat ~mirti. #~.~,~ a~~ h~l~c~j Mitt (~~ ~ ~Ci~' (~ttittetEt aK c~strth ql, Glace. lam. ~d,®. #aels~a T3°~ 1#f~ ~* 'll~: ~ : i~l.f'. 't~}C~t arad- BI' ati c~ ~'i~ 'EGG"F ~ IG:. f~i.P_ at or 73^l= ar~d m~ at ~l~rr~ tt7Cs"1=: ~l; ~ 1rt:F+, ~: •mt~e_°ttl;l"P: ~ i+43'F_ IdtJ?i:~ ~.~?. ~t ar a ~~F ~ b ~t°F, i~:1;~'. t~! tx' plbo:+ °~. Iti~FPA ~i841~C}d3tl~~'ItAI.S TINS: 'I'ttiri i~ ~ raei<^te ~ t~ .nrrrcc mradr rtFi tam iCt ~"tre*'i~~t~±t~i. Q AHD "b"id ~1- .i +~ ~@. :'~ ~~C.~A PP3~$~ TES` : SAY` C]ls,TA ~1~ ra...... ~ ~~ .. ~ ~` ~.- ~ppp ,. ~~ ry; '7+~VV ~~ ~ - ~ - Awai iSA h~~'~'lY~ i~7't~1i+~3L1. eta: A ~v ;. ,~~ae - ~ ~ t ~~,~ttr: She ,' L~Gt~t.~-.~5 ,. ~ vVax~ dog: xla~d t'~, ` : ~ ~, ': ~s~+C'I its - R~~II)~+€"~`AL LE t~?~ ~+~a tic +~~cnps~ ,~wa~ del Sosorct~ asf ' fta atGt 1det1 sttstczfat.:s teak if wit~xa~ p~ v~ ~rrII~i ~ atsr-~: K~ Z ~ ~ a : 7EY~trav~~ 5Qas~es ~ " ' '~'atez s t'~+i - i3L~i' ,~ dh'~ STS; 5 and rn acc~a . s~rith att ~, astd Ctaa ate ~ it:5: C3S~3A: ~' ~R 1910;1 1{!_ p farm . Lrte ssa c ~~ ~, ~'~' = 8~• "fi ~";~"~i. ~ ~.. C3a~er' .~. - .r' gip. 21 3~ :,~~ '" '~` 'j"}'9Xl i~65.k• e a~ ~r~. ~i ~W' ~rA eR'~ w..k ~M'. ^. ~' #~~ x,",14. .~ _..... ~4t 'kell ~tirt~ ~~'" ~ El+~ryinr~r ~°ll~lits~.. w~.-.. ~.. ., 1~;, ~ ~ ~: mow: ~1. P ~1 _ ''•, ~. 1~r~rss e~ars.~r~e A P°'-Comrany. MATERIAL SAFETY DATA SHEET Identity (Product Name): PAINTBALLS -Oil Based Date Prepared: December 14, 2005 Section I. Identification: Manufacturers Name Brass Eagle LLC. Address 4251 Doniphan Dr.. Neosho , M0.64850 Emergency Telephone Number (479) 464-6616 Information Telephone Number (479) 464-8700 =----------------------------------------------------------------------------------------------------- Section II. Hazardous Ineredients: Common Name: OSHA PEL ACGIH TLV None NA NA Section II. a Non -Hazardous Ingredients: Common Name: Fill Material: Gelatin Shell: Processed Vegetable Oil Gelatin Pork skin Glycerin Water Water Glycerin Sorbitol Special Dyes (FD&C Yellow #5, Red #40, Yellow #6, Pink Dispersion) Section III. Physical /Chemical Characteristics: Boiling Point NA Vapor Pressure NA Vapor Density NA Specific Gravity NA pH NA Solubility in water Low Appeard`nce Solid Round Odor None to Vanilla to Spearmint Page 2 (Paintballs) Section IV. Fire and Exulosion Hazard-Data: Non -Flammable or combustible material. Flash Point: >200 F. Section V. Reactivity Data: Stable. Store at room temperature. Incompatibility with other chemicals does not apply with this material. Section VI. Health Hazard Data: None Section VII. Precautions for Safe Handling and Use: Spill or leak procedures: Normal clean up and wash down with water. Dispose of following pertinent federal, state, or Local regulations. Section VIII. Control Measures: First Aid Procedures: Eyes Flush eyes immediately with water for 15 minutes. Skin NA Ingestion Ingest large quantities of fluid, preferably water. Induce vomiting if large amounts are ingested. Contact the Poison Control Center for additional information if required. Respiratory NA Protective Clothing Layered clothing while playing for added protection. Eye Protection Appropriate approved playing Goggles for Paintball. Storage Store in a cool, dry place and protect from physical damage. Keep containers closed tightly. Information given herein is offered in good faith as accurate, but without guarantee. Conditions of use and suitability of the product for particular uses are beyond our control: All risks of use of the product are therefore assumed by the user and WE EXPRESSLY DISCLAIM ALL WARRANTIES OF EVERY KIND AND NATURE INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE IN RESPECT TO THE USE OR SUITABILITY OF THE PRODUCT. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users. Material Safety Data -Sheet sABRE c~„~~~an Mav be used to rnmnly with OSHA's Hazard Communication Standard Quick Identifief 29 CFR 1910. 1200. Standard must be reviewed for specific requirements. 1/1/2006 (SECTION 1 -CHEMICAL PRODUCT & COMPANY IDENTIFICATION Manufacturers nr~~ m~T~i rr~i t~r~~~rwiT r+~r~r~~n ATI~~I Emergency Phone ~ non nnc Henn Name: vwvw i i ~~,cvir rvi~w ~ vviv viv-~ i lulu Number. vvv-.~~.~-u.war address: 330 SUN VALLEY CIRCLE ~ o~ne~ceus: 636-343-0200 ary, scale, zlP FENTON, MO 63026 Fax "umber: 636-343-1318 cnemr~aiName: Oleoresin Capsicum (OC) and Orthochlorobenzalmalononitrile (CS Tear Gas) Trade Name: SABRE Civilian Series Model#'s: ( ) PEN-14, KR-14, HC-14; SPKC-14, P-22, P-22J, CY-35, M-60, M-120L, M-120FT SECTION 2 -HAZARDOUS INGREDIENTS /IDENTITY Hazardous Component(s) (chemical & common name(s) Content(s) OSHA PEL ACGIH TLV Carcinigen (Yes / No) Orthochlorobenzalmalononitrile (CS) 1 % N/A N/A No Oleoresin Capsicum: 1 % N/A N/A No Scoville Heat Units 2,000,000 N/A N/A No Major Capsaicinoids 0.13% N/A N/A No Capsaicin CAS #404-86-4 Nordihydrocapsaicin CAS #19408-84-5 Dihydrocapsaicin CAS #28789-35 HFC 134a is the exclusive propellant. Major Capsaicinoids are determined via A.O.A.C. Method 995.03. Other ingredients are trade secrets as defined in Hazard Communications ACT 29 CFR 1910.1200 Para 1 (1) end Appendix D to CFR 1910.1200. SECTION 3 -HAZARD IDENTIFICATION SEVERE SKIN AND EYE IRRITANT. CONTENTS UNDER PRESSURE. KEEP OUT OF THE REACH OF CHILDREN. DO NOT PUNCTURE OR INCINERATE CAN. DO NOT EXPOSE TO HEAT OR STORE ABOVE 120° F. DO NOT USE AFTER CANISTER'S EXPIRATION DATE. HMIS Ratings: Health: 2 Fire: 1 Reactivity: 0 Signs 8~ Symptoms Of Exposure: Ingredients-cause irritation through all routes of entry. EYE: Liquid or vapors may cause redness, burning, tearing, swelling and/or pain. SKIN: Frequent or repeated contact with skin may cause skin irritation and dermatitis. INGESTION: Ingestion may cause nausea, vomiting, and/or diarrhea. INHALATION: May cause irritation of the respiratory tract. MEDICAL CONDITIONS AGRAVATED: May cause more severe, temporary, effects on those persons who are asthmatics or suffer from emphysema. Page 1 of 4 SECTION 4 -FIRST AID MEASURES Remove victim from contaminated area and remove contaminated clothing. EmergenoyBFirstaidProoeedures: Provide fresh air, irrigate with copious amounts of cool water. Obtain medical advice is symptoms persist. 1. Innalarion: provide fresh air. Only exposed subject or EMS should remove subject's contact lenses. 2. Eyes: ~IJ~S ~ u'~ 1 Irri ate with cool water at least 15 minutes, or until relieved: u'u 1 3. skrn: Flush with cool water. Wash with mild soap and water. Rinse mouth with water. Ingest milk or water. Obtain medical 4. Ingestion: advice immediately. SECTION 5 -FIRE-FIGHTING MEASURES Flammability Classification 16 CFR 15oo.as: Non-Flammable; DO NOT USE with Electronic Immobilization Device Flash Point: > 106° C (228° F) Auto-lgndion Extinguishing Temperature: > 228° C (442° F) Media: Halon, Carbon Dioxide, Dry Chemical or Water Special Fire Fighting Wear respirator or self-contained breathing apparatus. Procedures: Unusual Fire and Explosion Smoke would be irritating to eyes and mucous membranes. Hazards: SECTION 6 -ACCIDENTAL RELEASE MEASURES Steps tofollowifmaterialisspilledor Wipe up small spills with absorbent material. With large spills, use released: respiratory equipment, to avoid irritation, and collect absorbent materials. Ifinside: Ventilate area and after absorbent process, wash area with soap and cold water Ifoutside: Stay UPWInd SECTION 7 -HANDLING AND STORAGE Store upright in a cool, dry area. Avoid direct light and heat. Precautions to be taken in handeling asr"raga: DO NOT expose to temperatures over 120 degrees F. DO NOT puncture or incinerate container. ornerPrecaurions: Assure can is in a secure place to prevent accidental rupture. SECTION 8 -EXPOSURE CONTROLS AND PERSONAL PROTECTION. RespiretoryProrection: Not required under normal conditions of use. Ventilation: Yeg ProreotiveGloves: -Suggested (not required) EyeProredion: Yes. Exposure without protection in training environment is acceptable. other Protective Clothing or Not re wired Equipment: q Work/HygienicPrectices: Normal SECTION 9 - PHYSICAL ~ CHEMICAL PROPERTIES Appearance & Physical State: odor: Orange/Yellow in color. Odor is pungent Liquid Boiling Point: ° ° Specific Gravity (H20 230 C (446 F) . ~~ 0.95 @ 20° C Page 2 of 4 $olubilityin Wafer: Vapor Pressure: Insoluble 100 PSI SECTION 10 -STABILITY AND REACTIVITY - Stability Conditions To Incompatibility (Materials To Avoid) Alt A -"-"'-'~ Avoid ' "' Stable X Hazardous May Occur Hazardous Decomposition Products: N/A Polymerization: Will Not Occur X Conditions To Avoid SECTION 11 -TOXICOLOGICAL INFORMATION Standard Draize Test: Severity: Moderately Irritating Skin, rabbit, 500 mg Standard Draize Test: Severity: Moderately Irritating Eye, rabbit, 100 mg ACUTE INHALATION LC50 (rat): > 201.9 mg/L SECTION 12 -ECOLOGICAL INFORMATION This product has not been tested for environmental effects. SECTION 13 -DISPOSAL CONSIDERATIONS Consult Federal, State, and Local Regulations Waste Disposal Methods: Evacuate contents in a safe area, & dispose of container. SECTION 14 -TRANSPORT INFORMATION DOT HM-181 INFORMATION GROUND AIR Proper Shipping Name: Consumer Commodity Consumer Commodity Hazzard Class or Division: ORM-D Class 9 Identification Number: none ID-8000 Packaging Group: none none Label(s) Required: none Class 9 Miscellaneous INTERNATIONAL TRANSPORTATION REGULATIONS GROUND AIR OCEAN Proper Shipping Name: Consumer Commodity Consumer Commodity Aerosols, Non-Flammable Hazzard Class or Division: ORM-D Class 9 2.2 Identification Number: none ID-8000 UN1950 Packaging Group: none none none Label(s) Required: ~ none Class 9 Miscellaneous Class 2 SECTION 15 -REGULATORY INFORMATION TOXIC SUBSTANCES CONTROL ACT: This product is in compliance with the U.S. Toxic Substances Control Act (TSCA) inventory requirements. SARA TITLE III, SECTION 313: Not Listed CLEAN AIR ACT (CAA): Not Listed P CLEAN WATER ACT (CWA): Not Listed CALIFORNIA PROPOSITION 65: Not Listed Page 3 of 4 SECTION 76 -OTHER INFORMATION Format and Preparation Complies with ANSI 2400.1-1993 Revision Date: 01-01-2006. Supercedes any prior versions. DISCLAIMER: The information contained herein is based upon data provided to us by our suppliers, and reflects our best judgement. However, no warranty of merchantability, fitness for any use, or any other wan'anty is expressed or immplied regarding the accuracy of such data, or the results to be obtained from the use thereof. Since the information contained herein may be applied under conditions beyond our controland with which we may be unfamiliar, we do not assume any responsibility for the results of such application. The information is furnished upon the condition that the persons receiving it shall make their own determination of the suitability of the material for any particular purpose. Page 4 of 4 ,?~.~l. C'}.'y. ~;..;3F~ _tt"IL!`~.-iB -~ k3 !~bta r~2.,-C';`+5 S~i~;~°i3. ~` 1. lE~~'~'3CI+G~-"I'I~?Pd C~$'"~'~ 9L~'~.'~i'L~1P A`~E?1~' 3 C~I~' ", ~~~~~~T . `. ~'cr~duet come; ~txppii~r^: P'rimras A$~,8~ 13f6s 5~-~7~. ~ a~~~; ~v~nt. 1r~ ~z ~me~~ ;si;t3c~ac ~t1e~.se; Ball tl~l6~ 210 ~~ az~it£ol ' t~a~ crQ t~se ~src~uc~. ~. t~f7~~--+11P""+G~~I"~~11~+T/Il'~`C~~T~T ~1'~' ~~I~'~t'~~ ~n~rdiecrE ~~~. ~'bu~~7 ~u^~rse I5 ~6 85 °~'~ ~o1F~i+augE. S oast ;~'kCtt Gr~ra~snmpt!n~tz is in~i~itrus i~'d~ s tit 'fie ~i~` s ~i~g~it~ cH t~bi~ v~iccia~ 1 ~,~~ce~ tt~ ~t _w+31. lea ~ ~xsc~ar ~ Y~ ~~' ~.~o~ 'fought out sir end tt~txaed with oz ~;e°t:ial tit~x. ~ ~edic~l rt~r ~d tie ~~acttx~ed r~r ca~~esd apt s~thout ciol~r, °, ~,s ~ 1t~ve been fist-bi~oz~ s~a~d'~~ rtrly~ ~v~sd a~ v~rit~ bod~r tertcporez! water, ~~ war cyr x~al~bigg of tic ~v^~ta~~ tie age. He~are~ r.~itrieig shoIc~ ~ ~~ad ~o~ ~ ~crts ~f'wao~t: t~f i.s~ue; ~'7:C~4.~ ~"rc~d name: Primt ca~~cxi+~~e 2~Q7 ~.~~~ 'SSae ss~a cif pro~~ "'~~ .~ P~~ aaesi mar ~~iro cq~~ ~~;;~^ .. wk~er~ ~ ~ P~~P~e- The be ~t~.;r it ~+a~~~ peiat. ~-~ ~~ . , a~~ pyre ~~~ iterng~ ~ >~O C~ ~. ~[e~ ~F~ ~~ e~~~ ,~ - I~,Z vs~l- C~-~idlE~ixsg ~ix~a~+ertes St+~m.:~rrr~s~ '~~ :~t1 a btu. ~~r I3e~ ~~~ Ct;S ~~~~~ " Sts1e ~~;~ ~ ~m d tie ! c~;~ ~ ~~ll,~esi. L~s~tc vF as~€~c, ~1r~,~ pct ~~e: ~t~s ~,dgcs ~Cl7` ~~ ,;;~w.. t C s€ . i; ~ b : a ~, )-~+t jt'0.1`: s BEY -3tro ...r~ Cx.~'"t.~,~° t? • «~^~'~ '~ . ,~±'..1. «a... Nr~ ~c~3I _ ~ ac~~~ +~" pia ~3ate ist~~ue: 9?.~4..~3 ~'rttsct x~me. ~t~ ~d~e 2197 - ~~~ ~3 ./iA rn*^ ,. ,.n . ~ a . mod' i .i Qe ~ESe~+PI . L.~difE3+; ~~ ~.~~ 5e~t~~ ~ ~uu~sl~~r's N~~~: #tie~~~, C3n~ ~ibe~ #~ ie~ri ~ r~i#~L": X44768 24 Ht'ae ~~~~e~~ T~t~aphot~~ I!~tebet°, ~It~Tt~ ~ ~~:~ ~313~ T~t~p~hcatte Nuar Il~r tr~4orrrt~cra ii~`~'~~'-'~~ Irtte~ IPr~~r~: f~'tt93; it'~ti~c~s I~i~®~ C~7~'t~t1i111~~6~ ~~z~~~lt~u Coeer~rt~e 13r~par~~ ~~'~-9-~ ~un~ tirt~i A~G~H -. 4~1~~~1 ~ ltttt~ ~phy~#artt td~r~4ty intacreEa~€©r+. Cti~~niµ~i dame ~r ~~etoriy~. Lgt~e~i~ Pet~rl~ur~t 4~as adY=~r~i:,al ~orrr~u~~: ~' ~ ~rop~r Shp~lr~t7 ~~~: I:~l~~fl Pt~tt~leuet- ~ M =~~rrfoa~s G~~s~~fi~~tit~~: ~~t~mm~b#~ C~'~ [3i«7~' 1e1~~'tifi::afiCSrt:1~~1 1417 ~b~lfs} R~:~ri~~~; I~mert~ t~~rs, ~~~ t SPA "i~aa~rd 1ti ~~ H~~h ~€c:ti~it Nit ~ --- ~ilcac#te i~dtlr-~ Pt~~-t ~°I= tf~prs~ F~~re~~ur~~ ;2113 ps~g ~rrtaat~ 't~!I~ "F V~pt~ lt?eets~ty {1~~r :~ '~~* y.52 Soul~it[ty I~ W~t~r: Siht~y Ligsai~l #~ 1St I~x~r~~~ion Ratisal~7Cl tlatil~s, °~ !sy Y~+luret 1 ... ~~: c tar~v~t~ (i~~~ = '~~; Q.5'I M~tl>'~g ~int< NfA a~~n~e er~~- t~c~r. Gear, un~~~l~t ca€~c-r sirr~"i4a~ t~ ~aMlc etdc~r~ef-lay - tyl ht9€:r~pt~n} ~itlar W~ifitz +;+ 11°il Paint --168 °IF ~~~ t~t~1~Uo~~a I~P't~+~ture~ ~°~ :~~ t~L1~,43"f~. I~x#tngt~~t~~n~ ~Il~tfia: ~ry Ct~emtcs~ Cuss 1a~-~~ ~i3~'V41'~~~ ~~t~y ~~' i~lt~ ~P~cira~ Pire.lFlght#~g Fttec~due~ S~vp fits of ~. U~~ wrtaa ~F~I~xpc~~~d cs~~ltalne~ t~+~6. tls~' Witter spay t~ ~~~~ unir~it~d ~ zee ~r t~&~ self-~r~~t~tt~d ~are~#hi ~-~t~tu i~ c~at~'~~~-r~ a~. ~~t~~f~ ue~ti~ has dlssi~t~~ ~oro~~lete~l'y. ~e°1SLir~~ ~~$ ~ ~1C~l~t3~tl{~.FI~~'S.' ~~~~~~~~~ ~~~tJ~{I C~~{#.~~~3 ~t~~f pt+~~S~9 1~~' II~~ ~xgktaslve ~~~~~w ~J~t~ alr: Gr~nt~i~ expc~~ed t~ i=ii ~~ axce~siv~ h~~t trr euptur~ ~xpl~~ivl ~~ SUUNTO SI~Uf'S1'~"Ci t)5A ~~~1 #~ts P~tlr~~~ Qr~ve ~~i~ba~, C,A, ~Z!]t~9 {~~~i~~ 1~;l~~'1f~Tt~ ~~'~t~ 81f-~11ff&7f i-~ ~I~~ i-~ 1"'Y~7`w7s . ~' U~°1~r 1~~ ~iic~uvict ~~ ~e MST sheets fcxr Primus f~ei. Pi~~ !~ m~-know i~ ~rou nod ~c~di~iona~ inforrr~~~is~n. T'i~~rtic Yc~u, ~ritany ~'Je~~ [~~air 5ervsr~ Rep iC~-5~3-~~.~!~ ~2 soon S~.c m 'fh~ f~allos~stir~g irtif~rmation may b~e useft~# irr eampiyir~g a~t~ various state at~d faders! iar~rs ~tpa# tiulatl~ns rrr~~er var~rus ~nvir~r~me~rtef tute,~ ~tepar?~die Qwl~t~tt#~ {~Q}~ ~P~ t~~iula~ion ~tt1 CFR ~~2 (Gercla S+e~GEirbTt fQ2}: IVc~ RC} fray prosi~rc-fir ~rty~ +~onstituent ~t'eatet Chart 1®J~ ter t}.7 °JQ ~aarcinrac~er~)~ ~'hreshciid Plar~riittg Quant'ttjr.{7"i~~}, SPA Fie~ulatiort 4t9 Fit 3S5 {SRA~~t,timns 9tt'l~ti~4~= ~4 T~t~ fctr prcduat ter any Cr{~G`la~~i~CC~n'~ ~r~,c~„~Prr~~°ic`~~'1 "~°d''ii t3i'{~~'~'~J~'~~r~~'Li~{{C~C,~!'i~~. Tosiic Cherrtlcai itleleeae R~p~a-nrrrg, ~PA;F~euTstirart 4Q GF~;37~ (-i~~~or~,~i~k tea #c~xic ~~eri~~:1 [s pra~~nt graatertt~an ~m~a or.ti:!°!p jcaresirtc3~ett~. Nazardr~u~ Cher~icr~! Fte~art~rig. EI'A Rt~gut~tlorr~~4~ ~R 37th ~RA.S+~c!lans 39'1-~'~~ ;Ares Firms l~resa~are EPA ~~ard C6a~t#i~~l~n Ccac~e: ~sa~ ~t~Kt tfa~errt i~~ett~re ~la~asd Ptot ~pplic~+ble t~SNtk i~axartl:~Q3errrtinatiort: This materiel is hazardous r~s deffrsed by ~SN~4's F~azafcl Cc+mm~n~c~tlon'Stan~ard, ~9~~~ ~1a:'l2~t~ RCFi~t; ~`hls product !~ not subject?to the 4A MFR Parf~68.3t! !arid iaan ~n the ~lisprwoaal of ceri~in,hazart[c~us wast~:s, "tt~i~ pr~du~t d~e~ nest ~art~~atr~ ~FG's, ~FG`~. r~r cath~:r ~zzc~n~ c~~pl~ting c~trlp~aurtd c~~t'in~~ by #1tF~ thy! raet'c~ptart !s the preferred werrsirtg agent tc-r pr~,pane. 7hie !s beoattse, !n additinra tg m~etirtg lVFP~t #58 gu6delir~es for ~dt~ri-~.ti~cs ~f Lk~i®ases, its tiquid~g~ squlitbriucn pryparties mere cl~ssrty m;~t~h fh$t ref pmparE, and' it has ~ hi~t~er r~dor lntenstty at ivv~er cdn~sentratlon~ wtren cc~~tpered tc~ other ~ic#©riain~ agents, th~l mercaptat~ was first chs~aen as a+~iabin warrtlrtg~ agent to a study by the US> a~rtdau of t~lnes in ~3~~'t,-and F~tar c~inftrmed Ir1 indepen+ent studies by 4h+e ~~~ ~nsrgy t~+~search and C~evelapment r~tinir°trt~r~r~ {~l~t~A~ ire ~g77 t~Ithaugia ~#hyi m+st~s€;ptan ~ ex~ce!lent w~~mlr~~ Pt~sp+arti~~, NFAI~ #58~ A1-~1 dates "it ie rec~agnizsed ttla4xt~. oda~rartt iii! ~e +cc~rnpdete-y effectly® ~ vwarning ag~arrt ir- e+,~ery cir~urrtstan~.~" 54udles con~fi~tci€~d by Gas ~iesea~roh lnst~tute {~t~!}t institute ofi_Cas Techno(agy~it"}, ir3artieavitie iwn+~r~yTechnsaio~y C~"t1t~'Pk t~iatura! t3stoi`t2ing, -nc., anti s~tfiers i~ightight tr48tar1Ces +arfi~ere odt~rar-ts trt~ not tae as +~ft'ectiv~, Ft~T ~~:af~plc~, it has bin reiaotted that odor #a~ling caused byr chemical rixir~etiart', absc-f~ton, artcf adscrptlc~n can occur !n ssels arrd dist~'it~utit~n sj~st~ms carrying +~d'c~ri~d ~+r~pana, in an undergrcurtd lesi~, the rrdc~nt traay tie adsorbed gar aasc~rtied by cerkal~t scslis ~s the-gas passes thnbugh-the sc~l! tts t1~~: surisae. !n al~tsernen#, the r~d~t'~tCtt rrray be a~isart~eci car ~bsartted by, mess~rnry surfaces. ~xtre~ne cr~ld ~a~atf'~er may alac~ reduce the ~~fectiu~rta~~s a~` the rc~rar€t. it tea aisc~ bt~err r~epr~rte~#' that being pc~,seti tt- odor fc~r a period of time rn~r' aff+~+ct ~ p~eraon'a ~t~ility to datedt tha#. c-tlvr, ether c-ds~r'~ in ari-area, sur~h as a musty baeementx r~tay mask r~r c~ever up the LP-gs~ ad~r. ~s~ ~i~ti~esi That ever- a taint sm~ii. of flricrra;tt ~auls~ intiidate a cier~tgerous sttu~tloa, " GH~l+r1l~Ai. C3XIdA`C!C'~l~i, tWor'itaCt with atrioxygen~,,~st, ~r~ther crxiaet~~-n ~gent~ o~rer>a pe~r°]~rtl at t~r~e care result rn.~dofant #adtng: ChBry'tiC~ raxidstattn is !'T1~'St ii~ly tca CfCCU~' iC1 ttBW~~(fr~$#~tlsd t~~s rrti r'~rsty, wet; ar irTtplt}pE'r!y pT1e~par'Btt ~+~r1~C~s. Ft3r',tt'!l~ f~~i4Gr'i ~'~:t,~'~r1'If~~y.~tn}~C11"~~t'Mt 'f0~" piI'~3i3~111~' ~IliC~ ~t7 ~~: t°C~~Tt'i~JI` ~3t1r"~9d, espeGiaiiy when ttte tank is new or has teen allowed ttt rv~r empty, thus $libwing potential air ~rwat~r Gti~t'C3n1:ln~$IiDt1, "the intr~r,ti~n in Chia MSC~~ vktas cat~tat~rt ~rr~rn sc~u~es ~vh~c eve betl~ aCe c~ii~hte. l~iJ~~ttlE~i,'C~tE ~l'd>=~}AlViA1'it7N- IS PR~ttla~.lAtlT~itt)E)T lLtVY' Wi4~RAl~P'PY, ~CPA~,SS €~J~ #~l~Li~ R~t~illt~t~IC.~ 4'i~ ~C~~i~G {'~tE. The candltlc~ns or rr~thc+~s +af hattrlltrtg, storage, use end dis~sai.af the prc~+~~lGt ate tr~-n~ ovr carltr~at and may:ae k~eyrr-rtd' cur`kracr+~rladge;.F'C1i~i`'I'H!~ A~N€~ C)THEt f~FAS~i'rla, IN`E t~C> 3`~t~" l~~ttt~'~ F~~ ai~'C`~NF~t~»I'i•1' ~'~it3 ~xPR~~L'i~ l~i~elh~ Ll~l~ll..iT't' ~t?R i~t7SS, t~AIVUAiiw C1R ~F~i+t~E ARlSit~i~ ~tlT ~F ~~ i'~J1 A,fi~Y VVAY cc~~vr~l=~r~l~ 1T~ zH~ HAltitl~E.lN~, S7~-RA~E, U~~, air piSP€as~L of T~tl~ Pt~CC~au~'l: Chr~ani+E< M8x8rad ~~ n 'stat~t#ity: Stabte ~ondltlQns tc~ ~-u~ld: Flew sparks, fterm~ and 6uild•up cf static ele~et~'f~Iy. i~r+~u~~tt v~,pt~r' iart~utati~at~ ~rr~csmpatltlill#y:(h+iafi~ri~l~ t+d !t'~r",dl: l~trcxrtg t~xldize~ Hazardraus l~eco~tasltlon ~a' Byp~rodct~: Carbon Pvlchr~xide Hacticws P+?l`ipri~:atit~ri~ W ail td,,,._..~t Occur Sf+~iQri 1rK~ ~ ~tasat#l~ ~1~ pa~~ Aautim(s) cif Entc~< Sklr~ ~ i/r#as#it~,~~rimary~ Lungs ..l~hatic~n ~l?rlrr~ary~ In~d~#i~ - ~,~ Ne~atfh I•iszsrrls {~lcufa.artd Cl~rr~o,~ Classiflad a~ a simple asp~Y~lattt; miri~i't`l1 t~tcygert ~~-tlt~nt .ahce~td ~a ~~e~~~~ by vnlurns under normal a~tm~c~spl~cric ccndlti~ns (ACCIH): Central ne+u~ s~y~ta~ d~r~sant. l'~a~t ~caus~ anemia snd irregular I•teart riiyrthrn, Cerain+og~rnicltyw Nar~ycaricinogerllc NTP: R#tA IAFiC Niop~agcaph~ IYt~ C1SH~ ii~~cla#ed, ht1~ ~igra~ and ~ymptcros tt# ~xposura: NPgh con~centraticsn carp lead tv s~rrnptrams ranging frarn dizziness .tc~ arye~thesia acid respirat©ry arrest if inhaled. Eyes can bs tttaderat~ly Irrltatecl. i~lecti~~l Cra~tdltlCtrts ~,e~~rally~ +~ig~raaa#e~d ~r+~'po~ure: a~tlvr~ is ractarnn~e~tSetl fir persr~rtrlel with pr~~xlutir~g centres ne~r~rus s~rsfem or chronic raspiratbry dta$asas. IE:rn~enc~r at~d First did Pr>ciures: ~iernt~ue tt~ fredll`adr. If nc-t b~raathin~, administer aic, oxygch car ~F'R~ Skin i~eep:~#ectd are~w~ren and.s~brnerg+~ in`lukevuarm w~iter_ i=~t~h eyes imm~c#iat~l~ ~ttt1~ water; . ~ S~"ctic~n °°4riil =--Prac.~~tf~i;as #o~r ;~+~ I~~i~t~lir~ tad. Us+~ • "~rainxng: Iri the ir#terest crt safety, ail pereons employed In ha~rilir4~ prc~~sane gas must ue trained Itt proper har-diing and t-perating pra~edures. This trairiir~g siaould also l~ dcscumer#ted; ;steps tc Se'T~ik~n 1n Case iUi~tQri~l` is ~el+~ased or Spiiied: I~ee p~zblip aver.. phut aff.g~-sulapl~ ~ll~'ilrtate sources cf ignltie~n: Ventilate area; t7ilspet"se writh water`.spray: Con#act' hsetweer~ skin end liquid pr~apane car} caua~e fs~ezing of tissue. . W~.aie Disp~vssi ettl#iad Gat~trc~llatl l~uri~ting tti cpmpllanca with ~app~llc~abia codee end lavvst :~or~tact s~u:ppl darecautivns t~ l3e'I'elc~n Ire Handling and Stor[riq heap cc~ntalnars awsty frcrrr'heat ac-urces a~r~d ~to~e`zt~tttalr~ers its ~aprigirt position. Containers sl~t3uiti nQt be rfropp+~~I.-Cvc~cairier temperature sh~uid neat exc »it1 °~ ~;~»~ ~); t~tiler Pr~c~~atic~i#~; Glc~se ~co~tainer s~srvice valve uvhen r~ct In tt~e send r~rhen arrip~ty, lnstati ~r~t~xctiv~a c~~ wrl~et~ r~cit connected fir use, Containers, even those-that [gave teen em~rtled-,.can ocnte,ira expl~aeive va~aare: ~cr nc,t cu#, drill, grind, Meld crr parfQrrt~ simila~operatic~ris can car near cantaitters, tlCi'T G~ilnders: Ctt~" sped#Icati~n cyilnste~mut3t be periaclMcally taqusllfletfi or they must he rsrncrvad frcrn service, Store anti use cylrndcrs with relief YBEiY~ Irt the containers' vaparspace, Respir~ts~ry PrRrtectimn: Oise NICi'SH or Iv1Si~A apprc+vecl equipment wtrera airtac~rr'[e ezpv~su~ limits are exuded; llerrtileti~rt: Frcrvlcle adequate vt~~tiliitt~ort~arl~ettrt this prrarlc~ct is used to ri~e8t 7'l.V'requlramants are to leap cvracentratic~r~ In air hetc~w 25~'a cif the ~.;~.~.. Mecttar~lcai vents{atoms must Wiest Nom. requirements ft~r being expioslc~n prop#~ ~rtatective ~I~as: Itt'ipervious plaatlc ar rlenprette-c~s~ated canvas. e ~~ prctl±~n: Face shield r~r chemical gt~ggies whelf changing values; hc~s8s, fittings or performing t1't~.lntenancefservic+s vpgrdt;ipna Iri tlquid p~apar~e service. tiger Proteetitr~.G~+~thing.rsr ggtrfpra~entr E~itA worRiHy~iergi~ Pract9cas: Avnict braatl~ingga~, secure atgd evacuate area If gas. is,srnel(ed.